EPA-600/9-88-005
xvEPA
           United States
           Environmental Protection
           Agency
             EPA/600/9-88/005
             March 1988
Research Program
Description

Ground-Water
Research


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                           Ground-Water Research

                            Program Description and Plans
                                     Prepared for the

                              Office of Research and Development
              Office of Environmental Engineering and Technology Demonstration
                            U.S. Environmental Protection Agency
                                  Washington, D.C. 20460

                                  John H. Skinner, Director
                               James V. Basilico, Project Officer
                               Performed under Subcontract to
                                    JACA Corporation
                                 Fort Washington, PA 19043


                         Environmental Management Support"
                                    9514 Mid wood Road
                               Silver Spring, Maryland 20910
                                     (301)589-5318

                                     January, 1988
f  -   -   --mental Protection
        ,  Library  (5PL-16)
.    •'"  £,(  .born Street, Room 1670
Chicago, IL   60604

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                      NOTICE

This document has been reviewed in accordance with
U.S. Environmental Protection Agency policy and
approved for publication.   Mention of trade names
or commercial products does not constitute endorse-
ment or recommendation for use.

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                                        PREFACE

   This plan describes the ground-water research program conducted by EPA's Office of Research
and Development (ORD).  The research program is carried out by the Offices of Environmental
Processes and Effects Research (OEPER), Acid Deposition, Environmental Monitoring and Quality
Assurance (OADEMQA), Environmental Engineering and Technology Demonstration (OEETD), and
Exploratory Research (OER).   Of the  16 ORD laboratories, four  have  lead responsibilities and
base budgets in ground water:   Robert S.  Kerr  Environmental Research Laboratory in  Ada,
Oklahoma; Environmental Research  Laboratory in  Athens, Georgia; Environmental  Monitoring
Systems Laboratory in Las Vegas, Nevada; and Hazardous Waste Engineering Research Laboratory
in Cincinnati, Ohio.

   The overall program is coordinated  by the ORD  Matrix Manager for  Ground-Water Research.
The current matrix manager  is John Skinner, Director of  the Office of Environmental Engineering
and Technology Demonstration.

   Five of the six functional areas  within  the ground-water  research  program are  covered  in
this plan:  monitoring, fate and transport,  aquifer reclamation, source  control, and technology
transfer and technical  assistance.  Health effects research of drinking  water exposure, conducted
by laboratories in Research Triangle  Park, North Carolina and Cincinnati, Ohio, is not specific to
ground water and is treated elsewhere.

   Base funding for ground-water research  comes from  Budget Subactivities D109  (Hazardous
Waste), Y105 (Superfund), C104 (Drinking Water), and E104 (Pesticides).  Appendix A in this plan
lists the associated planned program activities (PPAs).

   Further information may be obtained by contacting the directors of the following ORD facilities:

             Director                            Facility                FTS Phone
             Calvin O. Lawrence                 CERI-Cin              684-7391
             Michael Callahan                   EAG                  475-8909
             Steven Lutkenhoff (Acting)          ECAO-Cin             684-7531
             Robert Snelling (Acting)             EMSL-LV             545-2525
             Rosemary C. Russo                 ERL-Athens           250-3134
             Thomas Hauser                     HWERL-Cin           684-7418
             Clinton W. Hall                     RSKERL-Ada         743-2224
             Francis T. Mayo                    WERL-Cin             684-7951

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                                  GROUND-WATER RESEARCH
                                        CONTENTS

INTRODUCTION	    1
   Background	    1
   Research Needs	    2

PROGRAM OVERVIEW	    3
   Structure and Areas of Emphasis	    3
   Strategy to Meet Needs	    4
   Relationship to Other R&D Activities	    8

PROGRAM DIRECTION	    9
   Current Program	    9
   Future  Program	    9

REVIEWS AND PUBLICATIONS	   11
   Scientific and Technical Reviews	   11
   Publications and Presentations	   12

APPENDIX A.  ORD GROUND-WATER RESEARCH BUDGET	   13

APPENDIX B.  SUMMARY OF OUTPUTS FROM GROUND-WATER RESEARCH PROJECTS .    15
   Monitoring	    15
   Fate and transport	    18
   Aquifer Reclamation	   29
   Source  Control	   30
   Technology Transfer and Technical Assistance	   35

APPENDIX C:  RECENT GROUND-WATER PUBLICATIONS	   39

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                                      OFFICE OF RESEARCH AND DEVELOPMENT
                                          U.S. Environmental Protection Agency
                                                      Assistant Administrator
                                                             Deputy
         Office of Exploratory Research
                    (OER)
 Office of Acid Deposition,
Environmental Monitoring,
  and Quality Assurance
      (OADEMQA)
      Environmental
      Monitoring Support
      Laboratory
      Research Triangle
      Park, NC
      Environmental
      Monitoring Systems
      Laboratory
      Las Vegas, NV
      Environmental
      Monitoring Systems
      Laboratory
      Cincinnati, OH
      Atmospheric
      Sciences Research
      Laboratory
      Cincinnati, OH
                                                                Office of Technology Transfer
                                                               and Regulatory Support (OTTRS)
                                                                                                 Center for Environmental
                                                                                                 Research Information
                                                                                                 Cincinnati, OH
 Office of Environmental
     Engineering and
Technology Demonstration
        (OEETD)
     Air and Energy
     Engineering Research
     Laboratory
     Research Triangle
     Park, NC
     Hazardous Waste
     Engineering
     Research
     Laboratory
                                  Cincinnati, OH
     Water Engineering
     Research Laboratory
                                  Cincinnati, OH
       Environmental
       Research Laboratory
                                    Gulf Breeze, FL
Office of Environmental
 Processes and Effects
       Research
       (OEPER)
   R.S. Kerr Environ-
   mental Research
   Laboratory
   Ada, OK
   Environmental
   Research Laboratory
                                                               Athens, GA
                                  Environmental
                                  Research Laboratory
                                  Corvallis, OR
                                  Environmental
                                  Research Laboratory
                                                               Narragansett, Rl
   Environmental
   Research Laboratory
                                  Duluth, MN
Office of Health
   Research

    (OHR)
 Health Effects
 Research
 Laboratory
 Research Triangle
 Park, NC
Office of Health and
  Environmental
    Assessment
      (OHEA)
  Environmental
  Criteria and
  Assessment Office
  Cincinnati, OH
                         Environmental
                         Criteria and
                         Assessment Office
                                                       Research Triangle
                                                       Park, NC
                                                       Exposure Assess-
                                                       ment Group
                                                       Carcinogen
                                                       Assessment Group
                          Reproductive
                          Effects Assess-
                          ment Group
                                                                                      Headquarters

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                                     GROUND-WATER RESEARCH
INTRODUCTION

   Ground water  is a vital  natural resource in
the United  States, supplying about 25%  of all
fresh  water used.   Over 50% of the American
public--117 million people—obtain all or part of
their drinking water from ground water, and  95%
of rural Americans depend on it.  As recently as
10  years  ago,   ground  water   was   generally
considered a pristine resource:   pure  and ever-
available.   It  was used, and sometimes abused,
without being fully understood.   In the  1970s,
synthetic  organic  chemicals  were discovered in
ground-water-supplied drinking water sources in
several  states.  Currently, 40 states have  docu-
mented   instances  of   serious   ground-water
contamination.

Background

   While  EPA  has no  single  authority  under
which it  is  charged  to  protect  ground  water,
virtually  every  major piece  of  legislation  that
governs the Agency's mission addresses the need
to protect ground water,  including   the Clean
Water Act (CWA), the Comprehensive Environmen-
tal  Response, Compensation, and  Liability  Act
(CERCLA or Superfund), the Safe Drinking Water
Act  (SDWA),  the Resource Conservation  and
Recovery Act (RCRA),  the  Federal  Insecticide,
Fungicide, and Rodenticide Act (FIFRA), and the
Toxic  Substances   Control  Act,  together  with
their amendments.  However, this broad spectrum
of  statutory  authority  within the Agency  also
contributed to a  fragmentation of ground-water
issues, priorities, and regulations.

   As a result of a growing concern among Con-
gress  and top managers  within EPA, the Office
of Ground-Water Protection established a compre-
hensive,   agencywide  Ground-Water  Protection
Strategy   in  1984.   The  main   tenets  of  the
strategy are:

 • Short-term buildup of institutions  at the state
level.

 • Assessment of  problems that  may exist from
unaddressed   sources   of   contamination--in
particular, leaking underground  storage  tanks,
surface impoundments, and landfills.

 • Guidelines for EPA decisions affecting ground-
water  protection  and  cleanup.   EPA's  ground-
water strategy classifies  aquifers  on the basis of
use or potential use, with drinking-water supplies
afforded the most stringent protection.

 • Strengthening   of  EPA's   organization  for
ground-water  management  at  the headquarters
and Regional levels, and strengthening  of  EPA's
cooperation with federal and state agencies.

   While it is important to develop and implement
national  ground-water policies, protection pro-
grams must be geographically specific because of
the complexities  of the  hydrologic cycle.   For
this  reason,  state  and  local  governments  are
assuming primary responsibility for assessing and
controlling ground-water problems, while working
in partnership with EPA, which provides national
drinking water standards,  general  program goals,
research, information, and technical assistance.

   EPA   Ground-water   research  reflects  the
diverse  priorities  among  eight  program  office
clients (Drinking Water, Ground-Water Protection,
Solid  Waste, Emergency and Remedial Response,
Waste   Programs   Enforcement,   Underground
Storage   Tanks,   Toxic  Substances,  Pesticide
Programs), ten Regions, and a number  of  cross-
media offices  and task  forces.    The  overall
research  program  is guided by  a complex rela-
tionship   involving  three   research  committees
(Water,  Solid  Waste and  Superfund,  Pesticides),
four Office of Research and Development (ORD)
offices  (Atmospheric Deposition,  Environmental
Monitoring, and Quality Assurance; Environmental
Processes  and  Effects Research;  Environmental
Engineering   and   Technology   Demonstration;
Exploratory Research), and  four lead  laboratories
(Robert S. Kerr Environmental Research Labora-
tory in Ada, Oklahoma [RSKERL-Ada]; Environ-
mental Research  Laboratory in  Athens, Georgia
[ERL-Athensj; Environmental Monitoring Systems
Laboratory in Las Vegas, Nevada [EMSL-LV]; and
Hazardous Waste Engineering Research Laboratory
in Cincinnati, Ohio [HWERL-Cin]).

   The  research  program  is  divided  into six
functional areas, reflecting the primary concerns
of the client offices:

 • Monitoring.   The placement  and  spacing of
monitoring  wells,   together   with  acceptable
procedures for sample collection and preservation
and   quality   assurance  and   quality  control
procedures (QA/QC), is a fundamental requirement
for credible decisions on ground-water protection.
ORD's monitoring research program is  developing,
evaluating,  and   adapting   geochemical   and
geophysical monitoring techniques to  meet the

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                                     GROUND-WATER RESEARCH
needs  of EPA  and  the regulated  community;
evaluating existing  site characterization methods
for improved monitoring well network design; and
refining  existing methods  and developing  new
procedures for data reduction and interpretation.
The  lead laboratory  in monitoring  research  is
EMSL-LV.

 • Source Control.   A  major source of ground-
water contamination is the  improper disposal  of
hazardous  wastes.    Contamination  may occur
from such sources as landfills, surface  impound-
ments,  or  injection  wells.    ORD's  research
program in source control  addresses all aspects
of  the  technology  and  operational  strategies
associated with  reducing the  risk of contamina-
tion  by treating  or containing wastes—component
development and evaluation;  system design and
construction;  removal  actions;  and   remedial
actions.  The lead  laboratory  for source control
research is HWERL-Cin.

 • Fate  and Transport.  Predicting  contaminant
behavior in  the subsurface is  one of the most
difficult—and important—tasks for ground-water
protection programs.   EPA's research into trans-
port and fate phenomena and prediction considers
both the physical movement of ground water in
the  unsaturated and   saturated zones  and  the
change in  ground-water quality through natural
or enhanced degradation or  differential separation
of constituents.   The  lead  laboratories involved
in fate and  transport  research are ERL-Athens
and  RSKERL-Ada.

 • Aquifer  Reclamation.   Restoring a polluted
aquifer  is  generally  an  extremely  expensive
process, if it  can be done  at all.  Until a range
of   inexpensive, effective  cleanup  methods  is
developed, managers who must  decide whether to
restore an  aquifer face  a  series  of difficult
decisions.     ORD's   reclamation   research  is
examining ways to make  restoration  techniques
less  expensive,  and  assessing  case  histories  of
reclamation   efforts   to    identify   factors
contributing to their success or failure.  RSKERL-
Ada is the lead  laboratory in this area.

 • Health Effects.   The major route of exposure
to ground-water contaminants is through drinking
water; illness attributed to ground-water contam-
ination accounts for  28% of all reported water-
borne diseases.    While not  specific  to ground
water, research  on the health effects  of particular
pollutants  is  very important  to the  ability  of
decisionmakers  to  establish  credible  drinking-
water standards and to demonstrate to the public
that  the  standards  are  based on  sound  data.
ORD's  drinking-water  health-effects  research
program emphasizes the effects of exposure  to
contaminants found in drinking-water  supplies.
Since  health  effects  caused  by  contaminant
exposure are the same  regardless of the pathway,
research  on  health  effects   is  not  addressed
separately for ground water, and is not considered
further in this plan.

 • Technical Assistance and Technology Transfer.
To be  effective, research results must target and
be disseminated to operational personnel, program
managers, and decisionmakers in a timely manner.
Field personnel in EPA Regions, states, and local
government agencies must deal with an extremely
broad and complex range of data and information,
and  deserve close support  from  scientists and
engineers in ORD laboratories.  While there is  no
ORD  technical  assistance  line item  specific  to
ground water, ground-water issues are becoming
a major focus of technical requests  from  client
offices.   ORD's lead in technology  transfer  is
the Center for Environmental Research Informa-
tion (CERI),  although all  laboratories  routinely
conduct technology transfer and offer  technical
assistance.

 • Treatment Technology.  Information on treat-
ment technologies is also being developed by the
drinking water research  program.  This program
provides  attainability  and  cost  data  on  the
available  technologies.  It is focused  on removal
of volatile and non-volatile organics, inorganics,
metals, and microbes.   ORD is supporting  the
pending revision of the  National Drinking Water
Standards, but this  is not  a  formal part of the
ground-water research  program and will not  be
further discussed. The Water Engineering Research
Laboratory  (WERL) is the lead laboratory in this
program.

Research Needs

   Responding in  part to  a  recommendation of
the   Science  Advisory  Board,   the  Assistant
Administrator  for  Research  and  Development
created  a  matrix  manager  for  ground-water
research  early  in  1986,  whose   responsibility
included  cross-office,  cross-research-committee
coordination among  competing  priorities.  The
matrix manager  chaired two  landmark meetings
(October  8, 1986, and March 27, 1987) in which
representatives  from  all program  offices with
ground-water concerns and a number of Regions

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                                     GROUND-WATER RESEARCH
participated.  These meetings focused on program
office   priorities   and   cross-media   research
communications in monitoring research, fate and
transport, and aquifer reclamation.  The meetings
also  considered earlier recommendations  of  the
Science Advisory Board's July, 1985, review  of
the ground-water research program and Hazardous
Waste Ground-Water Task Force (January, 1986)
recommendations.   The outcome of  this process
was  a  consolidated,  ranked   list  of  program
priorities in each area  of  ground-water  research,
which   formed  the   basis  for  present  ORD
directions in ground water.

   In between  these  meetings, program office
and  ORD  technical  specialists  and  managers
participated  in presentations  of the  fate  and
transport and aquifer reclamation programs (Ada,
Oklahoma) and monitoring  program  (Las  Vegas,
Nevada) to review research priorities and outputs,
and to recommend  to  the full Committee where
research focus should be adjusted.
PROGRAM OVERVIEW

   EPA's   ground-water   research  program  is
divided among  five  major  areas,  each with  a
number  of  projects:    monitoring,   fate  and
transport, aquifer reclamation, source control, and
technology  transfer  and  technical  assistance.
The  program  has base funding in four budget
subactivities  and  29  separate planned  program
activities  (PPAs).   The  FY87 research budget
consists of over $30 million and 130 work years.
About 30% of the FY87 budget is in monitoring,
47%   is   in  fate  and   transport   and  aquifer
reclamation, and 23% is in source control.

Structure  and Areas of Emphasis

   As a result of continuing coordination between
ORD and the program offices, a series of  high
priority research  areas receive greatest attention.
Past  research has  emphasized  transport  and fate
phenomena, but recent recommendations from the
Science Advisory Board,  the Hazardous  Waste
Ground-Water Task Force, and the ground-water
coordinating committee  have resulted in a gradual
increase  in  monitoring  and   QA/QC.   Source
control  activities, once  dominated by  research
into  land  covers  and landfill  liners, are moving
more towards supporting the underground storage
tank, underground injection control, and Super-
fund  programs.   Fate  and  transport  research
continues  to emphasize the development and vali-
dation  of  mathematical  models  to  accurately
predict  subsurface  flow and  the  physiochemical
interaction  between  the  contaminants  and  the
aquifer.   Aquifer  reclamation  research, closely
tied  to  the fate and  transport work,  is concen-
trating on biodegradation.

   Monitoring

   To  make  good  decisions on  well  placement,
sampling frequency, and placement of  monitoring
devices  in  the  unsaturated  zone,  a  site  must be
sufficiently   characterized   in    terms   of  its
hydrological, meteorological, geological, hydrogeo-
chemical, biological, and demographic data.  The
information collected during site characterization
is   used  to   design  adequate  environmental
monitoring  networks  and to evaluate  existing or
proposed waste  management engineering designs
to  assure the protection of human health and the
environment.  In the monitoring  area, there  are
six priority research areas:

 • Develop  methods  for extracting samples of
ground  water that are truly representative of the
source; samples with less loss or  chemical conver-
sion  and less cross-contamination;  and  statistically
valid sampling and  analytical methods.

 • Develop methods and guidance on site charac-
terization,  to  include such  methods  as aquifer
testing,   core   sampling,   and   collection  and
interpretation of existing information.

 • Demonstrate  the application of site character-
ization  information  for  determining  sampling
frequency and monitoring well network design.

 • Evaluate and provide guidance on techniques
for  monitoring in  the vadose  zone  that  can
provide early warning of leaking contaminants.

 • Establish a list of  critical indicator  parameters
that   will  provide  reliable  and  cost-effective
indication of ground-water contamination, specifi-
cally  to detect leakage from  hazardous  waste
disposal  facilities,  over-application of pesticides,
leachate  migration from  municipal  solid  waste
landfills, and  other potential sources  of aquifer
contamination.

 • Evaluate and improve existing methods for the
collection and analysis of hydrogeologic  informa-
tion  at the sampling point.

   In addition, an  initiative has  been proposed to

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                                     GROUND-WATER RESEARCH
determine the range of agricultural chemicals in
surface waters and develop  appropriate ground-
water  monitoring  strategies based  on critical
areas susceptible to contamination.  This initiative
is being coordinated with the Office of Pesticide
Programs.

   Fate and Transport

   The fate and transport research  priorities are:

 • Develop  methods  and models  to predict the
change in pollutant behavior in ground water due
to  physical  and  chemical  processes,  such  as
sorption, hydrolysis, reduction, precipitation, and
volatilization.

 • Determine  how biological processes affect the
fate and  transport of organic substances in the
subsurface environment through biodegradation.

 • Develop  methods to improve the prediction of
three-dimensional flow of contaminants in ground
water.

 • Develop  standardized models  for  evaluating
and predicting releases  from  hazardous  waste
disposal  sites,  and  the  fate  and transport of
constituents through the unsaturated zone.

    Aquifer Reclamation

    Aquifer  reclamation research  is  often  inter-
twined with fate and  transport  research; research
is conducted  by  the  same  laboratories often in
joint  projects.   Its  priority is  to evaluate and
develop cost-effective methods  for in situ aquifer
cleanup, including biodegradation.

    Source Control

    Source control  (engineering) research focuses
on technologies to reduce  risk by containing  or
treating  wastes and contaminants  at the surface.
The priorities include:

  • Develop underground injection controls (lead
laboratory is RSKERL-Ada).

  • Develop  and  evaluate   tank   leak  detection
devices and tank testing equipment.

  • Evaluate,  improve,  and field-verify   land-
disposal  containment  systems,  such as landfill
covers and  flexible membrane and soil liners for
landfills and surface impoundments.
 • Evaluate technologies  for treating  wastes to
   reduce toxicity and leachability.

   Technology Transfer and Technical Assistance

   Information dissemination  is a key element in
the research program. While technology transfer
and technical  assistance is an integral part of all
laboratory  activities, the priority  is to  develop
timely  and  effective methods  of  transferring
technical  information  to  appropriate  federal,
state,   local,   and  general  public  organizations
through publications, workshops, training courses,
and other communication mechanisms.

Strategy to Meet Needs

   Not  unexpectedly,   ground-water   technical
information needs are often common to  more
than  one of  the five primary program  office
clients (Solid  Waste,  Superfund,  Drinking Water,
Ground-Water Protection, Pesticides). In practice,
research activities must  be attributed to specific
budget elements, even though  the  results  have
broader  applicability.  For planning   purposes,
and  to eliminate overlap  and  redundancy, the
research priorities discussed  above  are  grouped
according to budget element.  In FY88, the  ORD
RCRA budget in ground-water research (D109) is
$15.5  million; Superfund (Y105) is $6.6 million;
Drinking Water  (C104)  is  $5.9  million;  and
Pesticides (E104) is $0.95 million.

   The following sections  summarize  the major
research  needs,  by functional  area,   of  the
Program and  Regional Offices and states.

   Monitoring

   Hazardous Waste (RCRA)

 1. Develop and evaluate ground-water monitoring
methods and strategies for RCRA hazardous waste
sites   and  to satisfy the  RCRA  land  disposal
regulations.

  • Develop   statistically   valid   sampling  and
   analytical  methods.

  • Develop methodologies  and  guidance  on well
   spacing  and  sampling  depths that  will  result
   in accurate interception of contaminant plumes.

  • Develop guidance on proper sampling frequency
   for  ground-water   monitoring,  considering

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                                     GROUND-WATER RESEARCH
   seasonal and spatial variables.

 • Evaluate and  provide guidance  on different
   techniques  for  monitoring  the  unsaturated
   zone  that  could  provide  early warning of
   leaking contaminants.

 • Establish a short list of parameters that will
   provide  a reliable  indication of ground-water
   contamination.

 • Develop improved  methods that provide better
   or lower cost hydrogeologic information  using
   geophysical and borehole logging techniques.
 • Develop   a  monitoring   quality   assurance
   program to determine performance criteria for
   monitoring  equipment;  test  protocols   for
   equipment; set procedures  for  equipment use;
   and perform field audits based  on protocols.

2.  Develop  methods  for external leak detection
at underground storage tank sites.

 • Establish  network designs  for placement of
   leak detectors  around  tanks   for  vapor and
   ground-water monitoring.

 • Develop   guidelines  for  data  analysis  to
   determine when  a system is leaking.

 • Establish   performance  tests   for  external
   petroleum leak detection devices.

   Suoerfund (CERCLA/SARA)

3.  Provide monitoring techniques  and  procedures
for Superfund site and situation assessments.

 • Develop  remote  sensing methods for analysis
   of present and  historical  site  operations and
   conditions.

 • Evaluate the  role of geographical information
   systems in the remedial investigation/feasibility
   study process for the  storage, analysis, and
   presentation of site information.

 • Develop  application  of near-surface  seismic
   reflection technology to  hazardous waste  sites.

 • Produce  practical  guidance  on aquifer test
   analysis.

4.  Provide   technical  support   on  Superfund
settlement agreements, especially  to enforcement
programs in Regions and states.
 • Conduct   sampling  and  analytical  quality
   assurance.

 • Review monitoring plans, QA/QC  materials,
   ground-water sampling and network designs.

 • Conduct  on-site  laboratory  reviews for  the
   Contract  Laboratory Program.

5.  Develop  and  evaluate  new  field-monitoring
techniques and systems that are rapid, inexpen-
sive, and more sensitive.

 • Develop  new  screening  methods  for  single
   compounds or for classes of  compounds using
   immunoassays.

 • Accelerate  the development of emerging field-
   portable systems,  such as fiber-optic sensors.

   Drinking Water (SDWA1

6.  Provide the scientific data base  and methods
for  regulatory,  enforcement,  and  management
decisions  concerning  protection  of ground-water
resources.

 • Develop  methods for extracting representative
   samples of ground water with an emphasis on
   minimizing sampling error.

 • Assess the utility of geophysical methods  to
   determine  movement  of  contaminants  from
   underground injection wells.

 • Develop   in  situ  monitoring  methods   for
   detecting contaminants from  leaking injection
   wells.

 • Develop  monitoring  strategies  for wellhead
   protection areas.

7.  Develop   uniform  standards,   policy,   and
guidance for collecting and storing ground-water
data, including standard record formats.

 • Determine  key  data  that must  be collected
   and stored  by EPA.

 • Provide a user-friendly environment for users
   of STORET and other data bases.

 • Develop  guidance  in  the use  of  analytical
   tools  for the manipulation of ground-water-
   related data, including  geographic information

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                                     GROUND-WATER RESEARCH
   systems.

   Fate and Transport

   Hazardous Waste (RCRA/HSWA)

1.  Provide field-evaluated  methods and data to
predict  concentrations  of   waste  organic   and
metal constituents  that  escape  or  are released
into  the subsurface environment from  the treat-
ment, storage, or disposal of hazardous  wastes.

 • Investigate   important   processes   such   as
   dispersion, sorption, complexation, speciation,
   biodegradation, hydrolysis,  volatilization,  and
   clay  alterations  that govern  the   transport
   rates, transformations, and  fates  of  hazardous
   waste constituents in the subsurface.

 • Evaluate,   and   demonstrate  through  field
   experiments,  available  mathematical models
   that  describe solute transport in the subsur-
   face.

 • Provide  assistance to  the  Office   of  Solid
   Waste  on   decision  models  and  to  permit
   writers on ACL determinations.

2.  Provide integrated (multimedia)  methods  and
data for implementing the RCRA Land Disposal
Banning Rule,  including the waiver process,  and
for evaluating  waste management and treatment
needs based on potential health and environmental
impacts.

 • Develop screening level and more site-specific
   multimedia   exposure-assessment  models  for
   organic pollutants and heavy metals.

 • Develop  probabilistic techniques  to address
   uncertainty.

 • Produce  a  manual  for   the  Office of Solid
   Waste  on  the Organics  Multimedia Human
   Exposure model.

 • Study  the  kinetics  of  sorption,  desorption,
   and  other  dominant  speciation reactions of
   metals in subsurface environments.

3. Provide  techniques and  data to predict the
rate and extent of movement  and transformation
of 2,3,7,8-tetrachlorodibenzene-P-dioxin in  soils
and  ground water.

   Superfund (CERCLA/SARA)
4.  Evaluate abilities  of natural and  engineered
microorganisms to biodegrade hazardous substances
in  support of Superfund remedial actions.

 • Evaluate  naturally  occurring  and  improved
   microorganisms  for  ground-water  and  soil
   cleanup.

 • Develop methods for application of biodegrada-
   tion organisms  and  evaluate  their  potential
   ecological risk.

   Drinking Water  (SDWA)

5.  Develop   methods   to   predict   subsurface
contaminant   concentrations   to   support   risk
analysis and source control.

 • Identify   characteristics   of  chemicals  (or
   pathogens)   that    have   similar   transport
   behavior,  and   characteristics  of  subsurface
   materials,  to  predict   pollutant  impact  in
   specific locations.

 • Determine  physical  and  chemical  processes
   affecting dispersion.

 • Predict microbial contaminant concentrations.

 • Predict    biotransformation   of   subsurface
   contaminants.

 • Determine subsurface microbial activity.

6.  Develop methods  to determine  the effects of
underground injection, and develop safer injection
technologies  to support underground  injection
control.
   Develop   methods   for   determining
   mechanical integrity of injection wells.
the
 • Assess  the  impact   of  Class   I  wells  on
   subsurface geological materials.

 • Assess the effectiveness of  drilling mud  as a
   plugging agent in abandoned oil or gas wells.

 • Produce a  report  on Class V  injection-well
   practices in the United States.

 7. Evaluate models and management strategies in
 support  of  state  wellhead-protection  programs
 mandated by SDWA.

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                                     GROUND-WATER RESEARCH
 • Develop methods for wellhead protection.

 • Assess   ground-water  models   for   wellhead
   protection area (WHPA) delineation.

   Pesticides (FIFRA)

8.  Determine how  pesticides contaminate ground
water and identify the processes involved and
those remedial  actions necessary to alleviate the
problem.

 • Characterize  pesticide processes in  soils and
   ground water.

 • Determine spatial  variability   in  subsurface
   soils.

 • Investigate   leaching   factors  controlling
   contamination and explore agricultural manage-
   ment   practices   that  could   help   prevent
   percolation to ground water.

 • Assess methods and  models at field  scale to
   ensure  integrity  and  the  incorporation  of
   appropriate management practices.

9. Develop information and techniques, including
mathematical models,   on  pesticide  transport,
degradation, residuals,  and fate for Agency use
and  provide direct  technical support and guidance
to OPP.

 • Develop information on such  parameters  as
   sorption kinetics in sediments, abiotic pesticide
   transformations, and volatility.

 • Study mechanisms and rates of degradation by
   natural microbial organisms.

 • Develop  comprehensive,  linked unsaturated-
   saturated  zone models and exposure concentra-
   tion estimates.

   Aquifer Reclamation

   Drinking  Water (SDWA)

Develop  new methods for in situ aquifer restora-
tion  and  provide  cost  and  feasibility  data  to
support corrective action decisions.

 • Study   laboratory and  field  evaluations  of
   methods for  in situ aquifer  restoration.

 • Assess    microbial   response   to   aquifer
   contamination and reactivation.

   Source Control

   Hazardous Waste (RCRA/HSWA)

1.  Develop  and field-verify  improved  design,
operation, and  closure procedures  for  hazardous
and nonhazardous landfills, surface impoundments,
waste  piles,  and underground  storage  facilities
used to  contain  wastes  and reduce  the risk  of
contaminant migration to ground water.

 • Continue  design  studies on cover systems,
   single  and composite soil/flexible membrane
   liner   systems,  leak  detection,  and   waste
   solidification and stabilization.

 • Develop  expert systems to provide consistent,
   cost-effective approaches to evaluating RCRA
   permits.

 • Produce updated Technical Resource Documents
   for Office of Solid  Waste  on cover systems,
   modeling,   waste  solidification/stabilization,
   construction,   operation,   and   closure   of
   hazardous waste management  facilities.

2. Identify  and  evaluate improved  practices to
prevent  releases  from new/existing underground
storage tanks and detect and measure leak rates
from underground storage  tanks and  associated
piping.

3. Demonstrate new  or  improved approaches for
stopping releases from a leaking tank system and
preventing associated environmental damages.

4. Determine the applicability and cost-effective-
ness  of  in   situ  reclamation  techniques  to
unsaturated-zone and ground-water contamination
resulting from  leaking underground storage tanks
and  other hazardous waste sources.

 • Provide guidance on  corrective actions.

 • Evaluate leak detection methods.

 • Develop   improved   techniques  for  in  situ
   cleanup of contaminated ground water.

5. Develop  a comprehensive technical data base
on   new  and   existing  technologies  for  land
treatment   of   hazardous   wastes   for   which
incineration or  land disposal are  inappropriate.

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                                     GROUND-WATER RESEARCH
   Suoerfund (CERCLA/SARA)

6.  Provide  response  technologies  to  support
cleanup actions  for contaminated ground water
and soils.

 • Evaluate on-site and in situ treatment proces-
   ses from pilot- through full-scale field tests.

7.  Provide  engineering   support  for  site  and
situation assessments of ground-water resources
at  uncontrolled hazardous waste sites.

   Technology Transfer and Technical Assistance

   Hazardous Waste (RCRA/HSWA1

1.  Develop more timely  and  effective  methods
for   transferring   technical   information   to
appropriate federal, state,  local,  and  general
public   organizations    through    publications,
workshops,    training    courses,    and    other
communications mechanisms.

   Suoerfund (CERCLA/SARA)

2.  Provide  best  available  technical  evidence,
   testimony,  and information to Regions, states,
   and the Department of Justice.

 • Establish a clearinghouse  for information on
   ground-water remedial action technologies.

 • Establish a ground-water  technology  transfer
   center for training Superfund Regional staff
   and to serve  as an information clearinghouse.

   Drinking Water (SDWA)

3. Develop and transfer improved methods  for
measuring subsurface parameters that influence
contaminant behavior.

 • Maintain a  clearinghouse  for  ground-water
   models and a national library for  ground-water
   information.

 • Develop  procedures  on  selecting  sampling
   methods for  determining oxygen  concentration
   in the saturated and unsaturated  zones.

 • Develop and disseminate improved methods for
   sampling subsurface microbial populations.

   Other Research and Development Programs
   The Exposure Assessment Group (EAG), part
of ORD's Office  of Health and Environmental
Assessment,   conducts  a  research  program  to
develop means to predict  human exposure risks
from  hazardous  materials.   EAG's  multimedia
exposure assessment  activities  are assisting  the
Superfund  office  and  EPA's  Regions  in  the
selection of appropriate ground-water models and
in evaluating remedial and regulatory alternatives
to clean up contaminated ground water.  Current
activities that are related to ground water are:

 • Characterization of contaminant dispersion in
ground water using data from recent field experi-
ments to develop a realistic approach  to modeling
dispersive transport in exposure assessments.

 • Criteria  for  the  selection of mathematical
models  that can be applied to exposure assess-
ments.   Use of  the  criteria will help eliminate
the use  of  inappropriate  models for estimating
contaminant migration in ground  water.

 • A  technical  support  document  to  help  select
ground-water fate and transport models for quick
assessments as well as for detailed analyses.

 • Experimental  studies   to    investigate   the
migration characteristics of concentrated organics
in ground water for use in developing two-phase
transport models.
Relationship to Other R&D Activities

   In addition to the obvious need  to coordinate
research programs within the Agency, EPA scien-
tists  in all  involved  laboratories  are  working
with  counterparts   in  other  federal   agencies,
universities,    and    professional    and   trade
associations,  such  as  the American Society  for
Testing  and  Materials  and the  Electric Power
Research Institute.

   The  greatest  federal ground-water  research
effort is managed by  the U.S. Geological Survey
(USGS), Department of  the Interior.   EPA  and
USGS  signed a Memorandum of Understanding
(MOU)  in August,  1981, providing an umbrella
under which each agency's programs are coordina-
ted.  A second MOU was  signed in June, 1985,
to  coordinate  ground-water data  collection  and
technical assistance.  In addition, EPA  and USGS
regularly   exchange   visiting   scientists   and
participate in each  other's  technical meetings on
ground-water.  RSKERL-Ada has  a cooperative

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                                     GROUND-WATER RESEARCH
agreement with the Department of Agriculture to
develop  geostatistical  methods  for  reducing
variance  in  data by  properly locating sampling
wells  at ground-water contamination sites.  EPA
is  also conducting joint  ground-water  research
projects  with the U.S. Air  Force,  U.S. Army,
U.S. Coast Guard, U.S. Navy, Nuclear Regulatory
Commission,  Department  of Energy, National
Research  Council, and  the  Tennessee  Valley
Authority.

   EPA is  a major sponsor of  the  International
Ground Water Modeling Center (IGWMC) at Butler
University in Indianapolis, Indiana,  the National
Center for Ground-Water Research (NCGWR), and
the National Ground  Water  Information Center
(NGWIC) at  the National  Water Well Association
in Dublin, Ohio.

   The IGWMC is a  clearinghouse  for technical
information on the exchange and use  of mathema-
tical  models  and  software, offers  regular  short
courses and seminars,  and carries out a  research
program   supporting   the  Center's   technology
transfer  and educational  activities   in  ground-
water  subjects.    The two major   tasks  of the
clearinghouse are the dissemination of information
regarding  ground-water   model  selection   and
application and  the distribution and support of
modeling software. IGWMC produces a periodic
newsletter.

   EPA  established  the  NCGWR in  1979  as a
consortium of Rice University,  Oklahoma  State
University,  and  the   University  of  Oklahoma.
Part  of  EPA's Centers of Excellence Program,
NCGWR is charged with developing and conducting
a  long-range exploratory research  program to
help anticipate and solve  emerging ground water
problems.  Base  funding  is  provided by EPA's
Office of Exploratory Research.  The major  areas
of responsibility for NCGWR are: (1) development
of methods  for  ground-water quality investiga-
tions;  (2)  transport   and  fate of  subsurface
pollutants; (4) characterization of the  subsurface
environment  with respect  to pollutant transport;
and (4) technology transfer.

   The NGWIC  houses a computerized  ground-
water information base that  can be accessed  by
subscription.  The data base, comprised of about
120 technical and trade journals and newsletters
from  around  the world, is constantly updated by
qualified specialists in ground-water development,
quality, monitoring and  protection,  restoration,
law, and  water-well  technology.    Over  50,000
citations are now in the data base, with about
500 new items added per month.

   The  Center for Exposure Assessment Modeling
was  established  at the Environmental Research
Laboratory-Athens in 1987.  The Center facilitates
state-of-the-art  model applications  to  ground-
water (and other) threat assessments  and remedial
action evaluations involving organic and metallic
hazardous wastes and pesticides.
PROGRAM DIRECTION

   The  ground-water research program  supports
the regulatory and enforcement objectives of the
various   statutes  that  EPA   administers.    In
addition, ORD and the Program Offices identify
emerging  or  potential  issues  that,  while  not
directly  mandated  by  statute,  require  basic
developmental or evaluative research in  order to
position  the  Agency  for  the  future  or  to
anticipate future Congressional action.

Current Program

   The   ground-water  research   program   is
organized into five functional areas, excluding
health effects: monitoring; fate  and transport;
source control; aquifer reclamation;  and  technol-
ogy   transfer  and   technical   assistance.    The
Program Overview section  established  the objec-
tives  and structure  of the overall ground-water
research program within this framework based
upon  regulatory  and enforcement needs  among
the client   offices.   The  FY87-FY89  ground-
water research budgets are itemized by  PPA in
Appendix A.

   Expected accomplishments, which include work
supported from earlier years  and new  activities
are shown  in  Appendix  B,  which represents the
best estimates for FY87  and  FY88;  the resources
for FY89 have been expanded to reflect some of
the anticipated  resources  stemming  from  the
reauthorizations of Superfund, SDWA, and HSWA.

Future Program

   Although the research  program is  designed
primarily  to  respond to  current  and   specific
Agency requirements, a number of  identified or
emerging   priorities  should   be  expanded  or
accelerated.    Future  research  activities  span
monitoring,  fate  and  transport, source  control,
and technology transfer and technical training.

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                                     GROUND-WATER RESEARCH
                                                                                                  10
   Monitoring

   Research concerning RCRA Subtitle D facilities
is  critical to the success of numerous state  and
local  agencies'  ground-water  management  pro-
grams.  In proposed  revisions to the solid waste
disposal  criteria under  Subtitle D,  owners  and
operators  would be  encouraged  to  characterize
their  own sites.  However, states need guidance
to  characterize  the  spatial  variability   of  the
subsurface directly beneath and around the site.

   Consistent  and comprehensive implementation
of the proposed revisions will require considerable
guidance and  technology transfer to the owners,
operators, permit applicants,  and state and  local
regulatory personnel.  Some of this would be  done
through the development of guidance  documents
and expert systems.

   Research  for Subtitle  D facilities  will focus
on the special monitoring needs of wet environ-
ments, where subsurface flows differ considerably
from dryer  areas.   This research  will  entail
surface water and  biota monitoring.  Other  Sub-
title  D  research  will  include  evaluating  and
developing fracture trace  and lineament analysis
of aerial photographs  for  site  characterization
and developing ground-water monitoring strategies
for facilities in karst terrains.

    Recent  amendments  to  the Safe  Drinking
Water Act include the establishment of wellhead
protection  areas  to  protect   the   quality  of
subsurface  drinking water  supplies.   Research
will  focus  on  developing monitoring  strategies
for wellhead protection  areas.

    New and continuing monitoring research under
Superfund will be supported through the Advanced
Field Monitoring  Methods  Program.   This has
been established to  address the  need  for rapid,
low-cost  field  methods  to  support  hazardous
waste  site   monitoring   and   characterization
activities anticipated  under  SARA.    Specific
program objectives and  organization are discussed
in the management plan.

    Fate and Transport

    Information necessary to understand subsurface
contaminant behavior subsurface can be  divided
into  three categories:   aqueous phase  transport;
facilitated transport;  and complex wastes.
   In aqueous phase transport it is important that
the roles  of  such things as organic carbon, Eh,
pH,  and solubility  be understood.  There is still
much to be understood before adequate predictive
capabilities can be developed and  relied upon.

   Facilitated transport is a  newly recognized
phenomenon  and consequently there  is much  to
be done.   It is  now believed that many of the
questions  in  this area can  be grouped  into flow
through macropores and fractures, water miscible
solvents,  and  transport  on  dissolved organic
carbon.   Particular attention is  directed toward
transport  by  sorption on suspended particles and
micelles.

   The newest area of  research,  with respect  to
contaminant  transport,  concerns  complex wastes.
Although some  work   has  been done,  this  is
proving to be an important area, particularly with
respect to waste sites.  The residual saturation
of the  immiscible  phase,  its effect on sorption,
and  methods for  its  removal   are  of greatest
interest in this  area.   In  addition, considerable
work is required concerning  the  weathering and
compositional changes of the wastes.

   The   processes   driving  transformation   of
subsurface   contaminants  can    essentially   be
considered   abiotic  or  biotic.      In  abiotic
transformations,  there  is a  need  to develop
methods for  measuring Eh and pH in the subsur-
face as well  as an  understanding  of the effect  of
these  parameters  on  process  kinetics. Mineral
surface catalysis  is another area requiring further
research.

   Research  in  biotic  transformations  must deal
with developing a better  understanding on the
native  microbial  population particularly   with
respect to density, activity, and  distribution.  In
addition, work  is required on the effects  of the
contaminant  on the microbial community as well
as  degradability   when dealing   with  complex
wastes.

   There continues to be a great  need to conduct
research  in  the  abiotic  processes  area.    The
general  effects  of  Eh and  pH  need  further
investigation; in fact, methods for making these
measurements   in   situ  need   to   be  further
developed.  In addition, mineral  surface catalysis
investigations   are   required    in   terms   of
contaminant  transformations.

   Subsurface pesticide transport is governed  by

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                                     GROUND-WATER RESEARCH
the same processes  that  control  all of  solute
transport.  However,  due to  the  diversity and
complex  structures  of many  pesticides compared
to  solvent  and  hydrocarbon  wastes,  complex
interactions   may   arise  that   affect   pesticide
transport.   Since  protection  of ground   water
from  agricultural chemicals  is  a major  concern,
additional research is needed  to understand  the
fate of pesticides and nitrates in  the  saturated
and unsaturated zones.

   Aquifer Reclamation

   Although  all of the research  discussed  above
under  Fate  and  Transport  applies equally  to
aquifer reclamation, there are additional research
needs  specific to  this  remediation  technology.
From the standpoint of hydrogeology, the effects
of low and variable  permeability must be under-
stood  along  with  proper well  placement and
pumping rates in order to maximize the efficiency
of pumping.

   A  great  deal  of research needs remain with
respect to the kinetics of sorption and desorption.
In this regard, special attention must be given to
problems associated with the  residual saturation
of the immiscible phase.  Obviously,  to make  the
pump  and treat  option of  aquifer  remediation
more promising,  it will be necessary to develop
means of enhanced  desorption including the  use
of water miscible solvents and  surfactants.

   Considerable work  remains in  the  research,
development, and demonstration of  enhanced in
situ contaminant degradation--both  abiotic and
biotic.      Abiotic   processes   involved   the
investigation  of  free  radical  generation and
hydrogen peroxide oxidations.  It is also important
to  continue   research  into  the  amendment  of
biotic systems using (for example) the addition of
alkanes and hydrogen peroxide.  These investiga-
tions  must include the development of methods
which allow  an estimation of the demand of the
amendment  chemicals;  ways  to determine  the
effects of these chemicals and enhanced  processes
on aquifer characteristics; and develop methods
to efficiently deliver the amendment  chemicals to
the aquifer and properly monitor the system.

   Source Control

   As  states  address ground-water  contamination
problems, more information  on control technolo-
gies is needed to define the  feasibility and cost-
effectiveness of protection and cleanup methods.
   Research on  full-scale  application of in situ
treatment methods for aquifer remediation must
be accelerated.

   Technology Transfer and Training

   As new research tools and  methods are devel-
oped,  programs  that  transfer  this  information
must be  expanded, coordinated, and  upgraded to
offer the newest computer-assisted technologies.

   Training needs to be further emphasized, and
deserves  a stable budget.  EPA regional and state
personnel experience a significant turnover rate,
and  new staff  must  have  the opportunity  to
become familiar with  new technologies, policies,
and  practices.   States  will need to  have  their
personnel trained in many developing aspects  of
ground-water management and protection.

   EMSL-LV, in conjunction with the Office  of
Emergency and Remedial Response, is establishing
a Superfund Ground-Water Technology Transfer
Center  to  collect and disseminate  information,
provide on-site instruction, and offer an technical
assistance hotline. The first year's effort (FY88)
will develop the courses, to be taught by EMSL-
LV staff augmented by experts from other federal
agencies  and the private  sector.  The first  year
will also include plans for a monitoring  clearing-
house and the technical assistance hotline.
REVIEWS AND PUBLICATIONS

Scientific and Technical Reviews

   The Science Advisory Board issued a compre-
hensive review of  EPA's ground-water research
program in July, 1985.   Among its major recom-
mendations were the creation of a strong central
direction   for  the   research   effort,  greatly
increased resources  for  training and  technology
transfer,  proactive   research  on  ground-water
contamination sources not addressed by  specific
mandates,  and expedited ground-water sampling
and  analytical methods  and   QA/QC.  Increases
or initiatives were  also recommended in  specific
ground-water research  areas:  monitoring;  basic
transport   and  fate;  containment  techniques;
remedial methods in fractured geologic formations;
and  identification of suitable geologic environ-
ments  for  isolating hazardous wastes in injection
wells.

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                                     GROUND-WATER RESEARCH
                                                                                               12
   As a component of their overall evaluation of
the RCRA Subpart F  Ground-Water Monitoring
Program submitted to the Assistant Administrator
for Solid  Waste and Emergency Response in
January,   1986,  the  Hazardous  Waste  Ground-
Water Task Force considered technical problems
in ground-water monitoring  technology.   They
identified six technological gaps:   (1) insufficient
understanding  of  the behavior  of  individual
contaminants and contaminant  classes, and no
defined  sampling strategy   for  each  class;  (2)
uncertainties about plume dispersion  as  a basis
for horizontal spacing, screen depth, and length;
(3) identification of  sampling  equipment  and
techniques  best  suited for  specific  hydrologic
settings or monitoring purpose; (4) estimation of
the effect  of interactive sample-contact surfaces
on the monitoring  data;  (5) selection  of key
indicators  for  contaminant   classes according to
geological   setting;  and  (6)  establishment of
analytic    methods    for    certain    hazardous
constituents.

   As  a  result of the October,  1986, meeting
sponsored by EPA's ground-water  research matrix
manager,  three technical  reviews were held on
Monitoring Research and Fate and Transport and
Aquifer   Reclamation  Research.    The  panels
consisted  of representatives  from each  of the
interested Program Offices (OSWER, OW, OPTS),
together    with   several  regions.     Technical
specialists  from  ORD laboratories discussed the
scientific   results  of  the  ongoing  research in
context  of the  programmatic,  regulatory,  and
enforcement priorities of the client offices.

   The fate and transport and aquifer reclamation
panel (Ada, OK, December 9-10, 1986) emphasized
the  need  for  guidance  on  how to  determine
vulnerable   aquifers   factoring   in   transport
mechanisms and modeling;  use of chemical and
biological   fate   and  transport   processes  in
developing and modeling closure standards; and
where to  set  ACLs   for hazardous  waste  sites.
The Regions  identified strong needs  for  "Best
Management Practices" for  the  use of agricul-
tural  chemicals  that  consider  ground-water
protection, especially  linking transport and fate
of ground-water pollutants with field application
practices,  and  for  improved methods  to  predict
ground-water transport in  fractured rock.   Other
priorities that emerged included guidance on fate
and transport mechanisms incorporating biotrans-
formation and  biodegradation  of contaminants,
types  of  models that should be  used to define
wellhead  area,  predict multiple-source, multiple-
contaminant pollutant  transport,  and differential
transport.

   The   monitoring   panels   (Las   Vegas,   NV,
December 16-17, 1986 and Atlanta, GA, February
18-19,  1987)  recognized  a  pressing  need  for
standard methods and  guidance in saturated  zone
monitoring and  sampling  protocols;  well spacing,
construction  and  installation;   well-completion
depths;  and  sampling  frequency.   They noted
that,  while guidance  exists  for  unsaturated  zone
monitoring, the number of installations and the
regulatory  emphasis  are greater  in  the saturated
zone for which no guidance exists.

   In November, 1986, the Ground-Water Moni-
toring Research Program at EMSL-LV underwent
peer  review.  The peer  panel report, issued  in
January,  1987,  identified   virtually  the  same
technical issues  stressed by the monitoring group
of  Program  Office   and  Regional  technical
specialists.

   Each year,  ORD   laboratories  host technical
program reviews in  concert with the  budget
cycle.   The  FY87  hazardous  waste/Superfund
laboratory  reviews were at EMSL-LV (including
EMSL-RTP and EMSL-Cin) on March 18-19 for
monitoring, HWERL (including CERI)  on April 20
for control technologies and technology transfer,
and at Headquarters for the RSKERL-Ada, ERL-
Athens,  and exploratory research  programs  on
April 16-17.

Publications and Presentations

   The  EPA ground-water research program has
produced major  reports and  technical assistance
documents for  nearly  20  years.   In March, 1987,
ORD produced the Technical  Assistance Directory
for Ground Water Research  (EPA/600/9-87/008)
that  includes an annotated   bibliography of  68
essential  references   for  permitting  or  other
regulatory  personnel  involved  in  ground-water
protection  and  treatment.    The  references are
organized into seven functional categories.

   Appendix C  lists  reports  from  the last  three
years that were produced under the EPA  ground-
water research  program.   EPA  scientists  and
engineers  have  made  frequent  presentations at
professional  meetings  and  EPA  symposia,  and
extramural  investigators  additionally  have made
numerous  presentations  and produced  several
hundred additional publications.

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GROUND-WATER RESEARCH
13
Appendix A. ORD Ground-Water Research Budget
Program Elements
PPAs
Monitoring System & Quality Assurance (OADEMQA)
HW 112: Evaluate/Validate Methods (EMSL-LV)
HW 115: Field Methods of Subsurface Monitoring (EMSL-LV)
HW R62: UST Leak Monitoring (EMSL-LV)
Subtotal
SF A04: Site & Situation Assessment (EMSL-LV)
SF F06: Technical Support/Geophysical Survey (EMSL-LV)
Subtotal
GW F81: GW-DW Quality Assurance (EMSL-LV)
Subtotal
OADEMQA Subtotal
Environmental Processes & Effects (OEPER)
HW C25: Prediction of Env. Concern of Haz. Waste (Ada)
HW C28: LandDisp. Ban Assess/Eval. Other Mgmt. Sys. (Ath)
HW D54: Mvmt. & Persist. Dioxin in Soil & GW (Ada/ Ath)
HW L44: Land Treatment of Hazardous Waste (Ada)
HW R64: UST Correct. Action Models/ Biodegradation (Ada)
Subtotal
SF B02: Subsurface Biodegradation (Ada/ GB)
SF F22: Enforcement & Technical Support (Ada)
Subtotal
.GW F82: Methods for GW Investigation (Ada)
GW F83: Prediction of Contaminant Concentrations (Ada)
GW F84: In-Situ Aquifer Restoration (Ada)
GW F87: GW Research with China (Ada)
GW F88: Support UIC Reg. & Implementation (Ada)
GW F89: Wellhead Protection (Ada)
Subtotal
PE D07: Validate Predictive Techniques (Ath/ HQ)
PE DOS: Predictive Techn. for Environ. Exposure (Ath)
Subtotal
OEPER Subtotal
Environ. Engineering & Technology Demonstration (OEETD)
HW A41: Waste Modification (One-Third) (HWERL)
HW L42: HW Land Disposal (One-Half) (HWERL)
HW L45: Subtitle D (One-Half) (HWERL)
HW R63: Prevent & Control Leaking USTs (HWERL)
Subtotal
SF B01: Control Technology Evaluation (HWERL)
Subtotal
OEETD Subtotal

FTE

1.5
9.8
3.2
14.5
5.0
3.2
8.2
5.2
5.2
27.9

18.0
10.8
1.6
5.3
2.7
38.4
1.0
3.4
4.4
2.0
13.3
5.0
4.0
2.5
26.8
3.0
2.6
5.6
75.2

0.0
10.4
1.5
9.0
20.9
6.1
6.1
27.0
FY 1987
S&E

90.0
806.0
204.6
1,100.6
425.7
272.4
698.1
166.3
166.3
1,965.0

958.9
569.5
86.9
287.8
147.3
2,050.4
64.0
217.6
281.6
95.0
604.8
306.0
105.0
200.7
150.0
1,461.5
189.4
164.3
353.7
4,147.2

0.0
447.7
76.3
510.6
1,034.6
423.1
423.1
1,457.7

R&D

300.0
2,916.0
1,152.8
4,368.8
999.0
1,073.9
2,072.9
800.1
800.1
7,241.8

1,922.4
2,538.0
212.8
480.2
201.4
5,354.8
1 00.0
706.0
806.0
600.0
1,063.9
900.0
20.0
730.0
160.0
3,473.9
600.0
600.0
10,234.7

200.0
596.9
290.0
2,103.1
3,190.0
1,666.7
1,666.7
4,856.7

FTE

1.5
9.8
3.5
14.8
5.0
3.1
8.1
4.7
4.7
27.6

23.3
13.7
1.6
2.4
41.0
1.0
3.4
4.4
1.1
14.0
5.0
0.0
4.0
2.5
26.6
30
3.5
6.5
78.5

0.0
3.5
1.5
10.0
15.0
54
54
20.4
FY 1988
S&E

90.0
971.0
323.0
1,384.0
470.5
291.7
762.2
274.6
274.6
2,420.8

1,532.5
735.5
86.5
129.8
2,484.3
84.1
286.0
370.1
55.7
735.1
253.2
105.0
202.6
126.6
1,478.2
152.1
177.7
329.8
4,662.4

0.0
200.9
76.5
621.8
899.2
407.0
407.0
1,306.2

R&D

300.0
2,436.7
1,060.5
3,797.2
1,555.7
1,211.0
2,766.7
524.5
524.5
7,088.4

2,295.7
2,444.0
110.0
106.1
4,955.8
250.0
700.0
950.0
350.0
1,264.1
900.0
20.0
730.0
160.0
3,424.1
455.0
455.0
9,784.9

200.0
148.6
350.0
1,301.2
1,999.8
1,333.3
1,333.3
3,333.1

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                                        GROUND-WATER RESEARCH
                                                                                                                       14
Appendix A. (Continued)
Program Elements
PPAs
Exploratory Research (OER)
Research Center
OER Subtotal
Hazardous Waste Total
Superfund Total
Ground Water (DW) Total
Pesticides Total
University Center Total


FTE


0.0
738
18.7
32.0
5.6
0.0
FY 19X7

S&E


0.0
4,185.6
1,402.8
1,627.8
353.7
0.0


R&D

650.0
650.0
12,913.6
4,545.6
4,274.0
6000
6500


FTE


0.0
708
17.9
31.3
6.5
00
FY 1988

S&E


0.0
4,767 5
1,5393
1,752.8
329.8
00


R&D

540.0
540.0
10,7528
5,050.0
3,948.6
455.0
540.0
Grand Total
                                                     130 1
                                                                7,569.9
22,983.2
                                                                                           126.5
                                                                                                      8,389.4
20,746.4

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                                    GROUND-WATER RESEARCH                                  15
   APPENDIX B. SUMMARY OF OUTPUTS FROM GROUND-WATER RESEARCH PROJECTS
                                 (R&D Resources in Thousands)

                                                                      FY87    FY88   Outvear
Monitoring

   Hazardous Waste (RCRA)

Develop and evaluate ground-water monitoring methods and strategies for  $3,216.0 $2,736.7   $2,736.7
RCRA hazardous waste sites and to satisfy RCRA Land Disposal Regula-
tions (PPA 115, 116).

   Internal Report--Bibliography of Ground-Water Sampling Methods.     09/87

   Internal Report—Ground-Water Sampling Chart.                                02/88

   Internal Report--Results of First  Field  Testing  of Eight Ground-    06/87
   Water Sampling Methods.

   Project Report on Field Comparison of Six Ground-Water Sampling                       10/89
   Methods at Hazardous Waste Sites.

   Journal Article on Protocol for Testing Ground-Water Samplers.                            07/90

   Project Report on Nature and Hydrologic Significance of Fracture             07/88
   Trace  and Lineament Related Structures  with Application  to the
   Design and Placement of Ground-Water Monitoring Wells.

   Internal Report on  Monitoring Strategies  for Subtitle  D  Facilities             09/88
   located in Karst Terrains.

   Internal Report on the Comparison of Water Samples  from Side-by-             12/88
   Side, Teflon-, PVC-, and  Stainless-Steel-Cased Wells.

   Project Report on the  Optimization  of Sampling  Frequency  at             06/88
   Hazardous Waste Sites.

   Journal  Article  on  Conceptual  Design  of  Adaptive  Monitoring     10/86
   Strategies.

   Journal Article on a Comparison of Ground-Water  Monitoring  Data    12/86
   from CERCLA and RCRA Sites.

   Journal Article on Results of Testing the Volatile Organic Scan  as an            12/87
   Indicator Parameter.

   Journal Article on  Organic Contamination of  Ground  Water  near    06/87
   Hazardous Waste Disposal  Sites:  A Synoptic Overview.

   Internal Report on  Evaluation of Control Chart Methodologies  for            01/88
   RCRA Waste  Sites.

   Project Report on Geostatistics for Ground-Water Monitoring.                             12/88

   Project Report on Multi-Dimensional Kriging.                                 12/87

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                                    GROUND-WATER RESEARCH                                  16
        Appendix B.  Summary of Outputs from Ground-Water Research Projects (Continued)

                                                                      FY87    FY88  Outvear

   User's Guide on Monitoring Statistics.                                                   12/89

   Internal Report on a Case Study on Soil Gas Sampling Field Testing.              12/87

   Internal Report on Performance Evaluation of Interpolation Methods.                      12/88

   Project Report on Feasibility of Using Control Chart Strategies  for                      12/88
   Detecting Trends in Ground-Water Pollutants.

Develop methods  for external  leak  detection at underground  storage $1,152.8 $1,060.5  $1,060.5
tank sites  (PPA R62).

   Technical Report  on Available Methods for Detecting Underground    06/87
   Storage Tank Leaks.

   Technical Report on  Soil Gas Sensing for Detecting and Mapping    03/87
   Volatile Organic Compounds.

   Guidance Manual  for Network Design of* External Leak Detection             09/88
   Systems.

   Results of Long-Term Monitoring at Three UST Sites.                                    12/88

   Computer Modeling of Vapor Phase  Movement in Relation  to UST             02/88
   Leak Detection.

   Report on Results of Real World Data Collection at UST Sites.                   04/88

   Report on Commercial External Leak Detection Devices.                         03/88

   Performance  Test  Procedures for  Out-of-Tank  Leak  Detection             09/88
   Systems.

   Internal Report  on Indirect  Pore-Liquid Vadose  Zone  Monitoring             01/88
   Equipment:    Standardized   Testing   Procedures  and  Performance
   Standards.

   Super fund CCERCLA/SARA)

Provide monitoring techniques  and procedures for  Superfund site  and    $999.0 $1,555.7  $1,555.7
situation assessments (PPA A04).

Provide technical support on Superfund settlement agreements, especially  $1,073.9 $1,211.0  $1,211.0
to enforcement programs in  Regions and states (PPA F06).

Develop and evaluate new field-monitoring techniques and systems that
are rapid, inexpensive, and more sensitive (PPA H03, SOI).

   Project Report  on Application of Borehole Geophysics to Waste  Site                       10/89
   Monitoring.

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                                    GROUND - WATER RESEARCH                                   17
       Appendix B.  Summary of Outputs from Ground-Water Research Projects (Continued)

                                                                      FY87    FY88   Outvear

   Conference  Proceedings  Article  on  Hydrologic  Interpretation  of            07/88
   Borehole Geophysical Data.

   Internal Report  on  Field  Validation Study for  the  Fiber Optics   09/87
   Sensor.

   Internal Report on In Situ Monitoring at Superfund Sites with Fiber                 11/87
   Optics. II. Plan for Development.

   Journal Article on  Fiber  Optics  Systems Development for In Situ            06/88
   Monitoring.

   Internal Report on Development and Demonstration of Immunoassay            10/87
   Detection System for Rapid Screening at Superfund Sites.

   Internal Performance  Report  on Field Test  of Martin   Marietta            04/88
   Portable X-ray Fluorescence (XRF) Unit.

   Internal Report on  Comparison  of  Commercially  Available  and            06/88
   Prototype Portable  XRF Systems for Hazardous Waste Investigations.

   Internal Report  on Methods  for XRF  Field Analysis and  Sample                      03/89
   Preparation.

   Project Report on Portable  XRF for  Characterization  of Hazardous                      12/89
   Waste Sites.

   Drinking Water (SOWA)

Provide the scientific data base and methods for regulatory, enforcement,   $800.1    $524.5    $524.5
and management decisions concerning protection of ground-water resour-
ces (PPA F81).

   Journal Article on Drilling and Constructing Monitoring Wells with    06/87
   Hollow-Stem Augers.

   Project Report on Handbook  of  Suggested Practices  for the Design                      10/88
   and Installation of  Ground-Water Wells.

   Project  Report  on  Fiber  Optics  for  Monitoring   Ground-Water            12/87
   Contaminants.

   Use  of  Geophysical  Methods  to  Determine  the   Movement  of                      12/88
   Contaminants from UIC Class  I Injection Wells.

   Journal  Article on the Design  of a  Monitoring-Well Network for                      03/88
   Investigation of Seasonal Variability of Ground-Water  Contamination.

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                                    GROUND-WATER RESEARCH                                  18
        Appendix B.  Summary of Outputs from Ground-Water Research Projects (Continued)

                                                                       FY87    FY88  Outvear

Fate and transport

   Hazardous Waste

Provide field-evaluated  methods and data to predict the concentrations $1,922.4 $2,295.7  $2,295.7
of wastes that escape or are released  into the environment  from the
treatment, storage, and disposal of hazardous wastes (PPA C25).

   Report on Evaluation of Land Treatability Decision Models.                                 3/89

   Report on Impact of Sensitive  RITZ Model Parameters.                           5/88

   Interim  Report (Internal) - Predictive Models for Describing  Fate of                       12/88
   Residual Organics in Contaminated Soils.

   Final Report (Internal) - Predictive Models  for Describing  Fate of                       12/90
   Residual Organics in Contaminated Soils.

   Article  on Comparison of Steady-State Solutions for Transport of                       10/88
   Contaminants in Leaky Aquifers.

   Report on Reliability of Ground-Water Solute Transport Models and              3/88
   Applications of Stochastic Theories.

   Internal  Report  on  the  Feasibility  of a Ground-Water Database             11/87
   Clearinghouse.

   Report on characterization of Physical Aquifer Models.                                    11/88

   Article on Nitrate Contamination Studies.                                                  5/90

   Report on Implementation of a Ground-Water Database Clearinghouse.                       11/88

   Internal  Report on Issues Related to Field Application  of Ground-     8/87
   Water Models.

   Briefing on Issues Related to Field Application of Ground-Water     8/87
   Models.

   Report   on  Validation  of   Existing  Saturated  and   Unsaturated              1/88
   Contaminant Transport Models.

   Report  on Field Validation of Solute Transport  Model for Prediction                       10/88
   of Waste Concentration in Ground Water.

   Report on the Use of Ground-Water Models for Regulatory Purposes.                        6/89

   Article  on  Developed Solutions  to Second  Order  Transformations                       10/89
   Including Advection and Dispersion Terms.

   Report on Use of Microcosms for Transport and Fate Parameters.        10/86

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                                 GROUND-WATER RESEARCH
     Appendix B.  Summary of Outputs from Ground-Water Research Projects (Continued)

                                                                    FY87    FY88  Outvear

Report on Factors Affecting the Mobility of Trace and Toxic Metals     5/87
in Ground-Water and Subsurface Soils.

Report on Subsurface Characteristics  Contributing to Heavy Metal              4/88
Contamination of Ground-Water at Hazardous Waste Sites.

Article Describing Mechanisms of Multiphase Transport.                6/87

Report on Immiscible Flow Processes.                                          10/87

Publication on Immiscible Chemical Transport.                         10/86

Article  on Facilitated Transport of  Contaminants in a Sandy Soil    10/86
Column with Dissolved Organic Materials.

Article on Influence of Miscible Solvents on Leaching of Hydrophobic     6/87
Organics.

Article  on Transport of Hydrophobic Organic Chemicals  in Multi-                       12/90
Solvent Systems.

Article  on Leaching of  Soluble Aromatics from Fuel-Contaminated    4/87
Aquifer.

Article on Toluene Mobility in Fuel-Contaminated Aquifer Material.             10/87

Report on Criteria for Selection of Potential Field Sites.                11/86

Report   on  Determining  Hydrologic   Properties   of  Subsurface                       12/89
Environments.

Report   on  the  Feasibility  of   Conducting  Large  Scale  Field    12/86
Experiments.

Report  on  Characterization  of  Spatial  Variability  of Hydrologic              4/88
Properties in a Coastal Aquifer.

Report on Techniques for Handling Spatial Variability of the Physical,                       12/89
Chemical, and Biological Properties of Subsurface Environments.

Report on Demonstration Project.                                      6/87

Report on Computer Graphics Demonstration of DRASTIC.                     10/87

Report on Land Treatability of Listed Hazardous Wastes--Volume I.             12/87

Report  on Land Treatability of PCP and Creosote Wastes.                                   1/89

Report  on Land Treatability of Listed Hazardous Wastes--Volume II.              9/88

Report on Land Treatability of Listed Hazardous Wastes—Volume III.             9/88

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                                    GROUND-WATER RESEARCH                                   20
        Appendix B.  Summary of Outputs from Ground-Water Research Projects (Continued)

                                                                       FY87    FY88  Outvear

   User Friendly Program for Land Treatment Decision Models.            11/87

   Report on Field Evaluation of RITZ Model.                                               12/88

   Report on  Fate  and Transport  of Residual Matrix  Constituents in                       9/89
   Soil.

   Report on Case Studies for Selected Subtitle D Wastes.                                     7/89

Provide  integrated, multimedia methods and data for implementing the $2,538.0 $2,444.0  $2,444.0
land disposal banning rule, including the waiver process.  Evaluate waste
management and treatment needs based on potential human health and
environmental  impacts (PPA C28).

   Journal  Article  on  Use of Standard  Reference  Compounds  in    3/87
   Transformation Rate  Constants Measurements.

   Third Report on Hydrolysis Rate Constants for Land Banning Decision              4/88
   Rule.

   Third Report on  Partition  Coefficients for Land  Banning Decision              4/88
   Rule.

   Second  Report on Hydrolysis   Rate  Constants  for  Land Banning     5/87
   Decision Rule.

   Second Report on  Partition Coefficients for Land Banning Decision     5/87
   Rule.

   Interim Protocol for Measurement of Hydrolysis Rate Constants.                   3/88

   Third "Report on Partition Coefficients for Land Disposal Assessment.              4/88

   Report  on  Hydrolysis Rate  Constants  for  Enhancing  Property-                       6/89
   Reactivity Correlations.

   Interim  Protocol  for  Measuring  Microbial  Transformation  Rate             11/87
   Constants for Suspended Populations.

   Report on  Microbial  Transformation  Rate Constants for  Suspended             12/87
   Populations.

   Report  on  Correlation of  Molecular Spectroscopic  Properties with              5/88
   Microbial Transformation Rates.

   Journal  Article  on   Preclusion  of  Microbial  Transformations  of              3/88
   Pollutants by High Pollutant Concentrations.

   Report on  Criteria for Evaluating the  Reliability of Literature Data     7/87
   on Environmental Process Constants.

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                                 GROUND-WATER RESEARCH                                  21
     Appendix B.  Summary of Outputs from Ground-Water Research Projects (Continued)

                                                                    FY87    FY88   Outvear

Report  on Effectiveness  of  Literature  Evaluation  Techniques for                       3/89
Chemical Hydrolysis Rate  Constants.

Journal  Article  Describing Metal-Microbial  Interactions:  Role  of                      12/88
Microbial  Species and Life Stage on Metals Sorption.

Journal  Article  on Distribution Coefficients for Sorption  of Metal             7/88
Complexed by Soils, Sediments, and Aquifer Materials.

Report  on Distribution Coefficients  of Metals Sorbed  to  Aquifer     1/87
Substrates.

Interim  Report to  OSW Describing Mathematical Formalism of Initial     2/87
Sorption Model to  be Employed for Adding Metal Sorption Capability
to the OSW Transport Model.

Interim  Report to  OSW Including Summarized Input  Data for Use  in     9/87
Implementing the Initial Sorption Model in Re-Listing Scenarios to be
Proposed  for November 1987.

Final Report on  Mathematical Form of Proposed  Sorption  Model                      12/89
Incorporating Revisions Due  to the  Availability of New  Data and
Results  of Public Comments.

Final Report on  Input  Data Distributions  for  Implementing the                      12/89
Sorption Model  in OSW Rule-Making Scenarios.

Development of First-Pass Generic Leachate Recipe  and  Compilation             10/87
of MINTEQ Formatted  Thermodynamic Database Using  Readily
Available Data.

Interim Report on Preliminary Leachate Analyses and Proposed List of                       6/89
Compounds for  Detailed Analysis of Equilibrium Constants.

Final Report of Formatted Database  of Equilibrium  Constants for                       6/90
Reactions of all  13  OSW Metals with  Compounds  in the Generic
Mixture with Complexing Ability.

Report  on Analyses for Part I: Analytical Data Report to  OSW.                   12/87

Report  on Interpretation of Test Results for  Part III: Mixture-specific                       2/88
MINTEQ Datasets for OSW.

Final Report on MINTEQ Bench Scale Testing.                                          12/88

Journal  Article  on  Feasibility  of  Predicting  Metal  Distribution                       5/89
Coefficients  on  Humic and Microbial Surfaces.

Report  on Prediction of  Sorption Based on Chemical Behavior and              7/88
Distribution  of Metal Reactive Phases.

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                                  GROUND-WATER RESEARCH                                   22
     Appendix B.  Summary of Outputs from Ground-Water Research Projects (Continued)

                                                                    FY87    FY88   Outvear

Journal Article on Kinetics of Sorption and Desorption of Metals  in                        7/89
Subsurface Environments.

Journal Article Describing Metal Sorption on Mineral Surfaces.                    9/87

Internal Report on Metal Interactions with Humic Materials.                      2/88

Internal Report on Metal Interactions with Metal Surfaces.                        2/88

Journal Article  on Tested Model for  Predicting Metal  Distribution                       10/89
Coefficients in Environmental Samples.

Journal Article  Describing Role of Competitive  Ion Character  on              9/88
Metal Speciation.

Journal Article Describing Kinetics of Complexation Phenomenon for                        7/89
Metals in  Aqueous Systems.

Report  on Computer Simulation  of Metal  Speciation in Presence  of             10/87
Naturally  Occurring Organics.

Journal Article  Defining  Specific  Complexation/Chelation Sites  in                        3/89
Humic and Fulvic  Substances.

Report on Laser Spectrometry Applied to Metal-Organic Speciation  in    12/86
Water.

Report on Metal Binding to Humic-Fulvic Materials.                    8/87

Internal Report  on Speciation and Fate of Toxic  Metals in Aquatic              6/88
Environments.

Journal Article on  Microbial   Transformation  Kinetics of  High     4/87
Concentrations of Hazardous Chemicals.

Journal Article on Predicting the Rate of  Trace Organic Compound    12/86
Removal by Natural Biofilms.

Report on Environmental Factors  Affecting Anaerobic Biodegradation.              6/88

Internal Report on  Protocol for Obtaining Microbiological Transforma-     1/87
tion Rate  Data for Chemicals in the Soil Subsurface.

Journal Article on  Implications of Multiphasic Kinetics for Predictive              1/88
Models.

Journal  Article  on  Preclusion  of  Microbial Transformation  of              3/8$
Pollutants by Higher Concentrations of the  Pollutants.

Journal  Article  on  Environmental   Factors  Affecting  Microbial     8/87
Transformation Rates of Pollutants.

-------
                                GROUND-WATER RESEARCH
     Appendix B. Summary of Outputs from Ground-Water Research Projects (Continued)

                                                                 FY87    FY88   Outvear

Journal  Article  on  Aerobic  Biodegradation of  Complex  Organic    4/87
Mixtures.

Report on Equations for Predicting Anaerobic Transformations Within                     11/89
the Saturated Zones.

Testing and Evaluation of OTS-SESOIL Model.                        3/87

Users Manual Describing Appropriate MINTEQ Code Implemented on             7/88
Microcomputer.

Users Manual for Metal Speciation Modeling--MINTEQ.                3/87

Interim Report on Sensitivity Analysis and Simplified MINTEQ.                  8/88

Final Report on Monte Carlo Version of MINTEQ.                                      10/88

Report on MINTEQ Predictions for Part II for OSW  and CB.                     1/88

MINTEQ Tapes with Thermodynamic Data Bases, Including SB and CN             1/88
Reactions.

Documentation on the Antimony and Cyanide Data Bases.                        7/88

Updated MINTEQ-A1 Code and PRODEF-A1  Preprocessor Code.       3/87

Raw, Interim Numeric Results from MINTEQ Provided to OSW.                  3/88

Interim  Report to  OSW  on  Model  Predictions  Using  Interim             6/88
Methodology  for Implementation of Re-Listing Scenarios.

Report on Organic Multimedia Human Exposure Model.                5/87

Journal Article  on  Anaerobic  Degradation  of  Dichlorophenols in             9/87
Freshwater Pond Sediments.

Internal Report on Microbiological Process Research Highlights.                            8/88

Report  on  Risk  Assessment Methodology for  Hazardous  Waste                      10/88
Management.

Project Report  on  Components  of Multimedia Environmental and             8/88
Human Exposure Modeling.

Report on Procedures for Estimating Indoor-Outdoor Exposures.                  8/88

Report  on   Risk   Uncertainty  and  Assessment  Data   Collection                       6/89
Optimization.

Project Report on Performance Test of  OSW  Modeling Using Field             2/88
Data.

-------
                                 G ROUND - WATER RESEARCH                                  24
     Appendix B.  Summary of Outputs from Ground-Water Research Projects (Continued)

                                                                   FY87    FY88   Outvear

Report on the  Impact of Uncertainty in Leachate Tests and  ADI              8/88
Data on Overall Uncertainty in OSW Evaluations.

Report on Impact of Treated Waste Forms  on Exposure/Risk from                        6/89
Land Disposal of Hazardous Waste.

Project  Report on Uncertainty Analysis of Multimedia, Transient-     9/87
Finite Source Land Disposal Model.

Journal  Article  on  Simulation of  Solute Transport in  Aggregated     1/87
Media—Numerical Solution.

User's Manual for Multimedia, Transient, Land Disposal Model.                   2/88

Journal  Article on Kinetic Studies of Aromatic Azo Compounds in    12/86
Anaerobic Sediment/Water Systems.

Journal  Article on the Role of Soils in Mediating the  Hydrolysis of                       1/89
Organic Compounds.

Journal  Article on the Scope  of Hydrolysis of Organic Compounds in            12/87
Soil Systems.

Journal Article on Abiotic Redox Reactions in Sediment-Soil Systems.    10/86

Report  Describing  the Kinetics  of Redox  Reactions  in Soil-Water                       4/89
Environment.

Initial Estimates  of Groundwater Redox Distributions  Provided to            12/87
AERL.

Report  on Selection of Redox Parameters and Redox Potential Distri-              8/88
butions.

Internal Report on the Fate  of Organic Pollutants in the Subsurface              5/88
Environment.

Journal  Article  on  Abiotic Transformation  Processes in Water,                       6/89
Sediments, and Soils.

Journal Article on Sorption of Ionic Organic Compounds on Sediments.              1/88
Users Manual for Sarah 2.                                                      5/88

Report  on Sorption Kinetics of Ionic Species on Aggregated Media.                1/88

Journal Article on the Fate  of Synthetic Dyestuffs in Natural Waters              9/87
and Sediments.

Internal Report on Fate of Textile Dyes in the Aquatic  Environment.               8/88

Journal Article on  Use and  Expected Behavior  of Chemicals (Dyes,              6/88
etc.) used in Textile Industry.

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                                    GROUND-WATER RESEARCH                                  25
        Appendix B.  Summary of Outputs from Ground-Water Research Projects (Continued)

                                                                       FY87     FY88   Outvear
   Journal Article Describing Algorithms for Estimating Hydrolytic Rate             7/88
   Constants.

   Journal Article on Estimating PKAs of Organic Acids and Bases.                 4/88

   Journal  Article  on Techniques  for Using  Chemical  Properties to             6/88
   Estimate Photochemical Rate Constants.

   Internal Report on Expert System  to Estimate Reactivity Parameters             7/88
   (Rate  Constants, Equilibrium  Constants) for the Transformation of
   Organic Pollutants.

Provide techniques and data to predict the rate  and extent of movement   $212.8   $110.0    $110.0
and transformation of 2,3,7,8-tetrachlorodibenzene-P-dioxin in soils and
ground water (PPA  D54).

   Internal Report  on Mobility  of  Other Selected  Dioxin Isomers in    11/86
   Soils.

   Article on Desorption of 2,3,7,8-TCDD from  Soil into Water/Methanol    11/86
   and Methanol Liquid Phases.

   Report on Mobility of Dioxins in Soils.                                         3/88

   Internal Report on Enhanced Degradation of 2,3,7,8-TCDD.                      1/88

   Report on Enhanced Degradation of Dioxin Isomers.                                      10/88

   Report on Photodegradation  Evaluation of Dioxin (2,3,7,8-TCDD) in             8/88
   Soils.

   Published Paper  on Environmental  Chemistry of 2,3,7,8-TCDD.          3/87

   Journal  Article  on Octachlorodibenzodioxin Dechlorination on Soil                      11/89
   Surfaces.

   Internal Report on Application of the Multimedia Exposure Assessment     6/87
   Model to Estimate  Downgradient Concentrations of Dioxin.

   Super fund

Evaluate  abilities of natural and engineered microorganisms for biodegra-   $100.0   $250.0    $250.0
dation of hazardous substances in support of Superfund remedial actions
(PPA B02).

   Journal Article on Enhanced  Biorestoration of Contaminated Ground                       1/89
   Water.

   Development of Procedures  for  Biological  Cleanup  of  Trichloro-             9/89
   ethylene-Contaminated Hazardous Waste Areas.

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                                     GROUND-WATER RESEARCH                                  26
        Appendix B.  Summary of Outputs from Ground-Water Research Projects (Continued)

                                                                        FY87    FY88   Outvear

   Article  on Bench-Scale  Demonstration  of Feasibility for  In  Situ    9/87
   Biodegradation of Trichloroethylene.

   Feasibility of Bioremediation of TCE-Contaminated Waste:  Bacterial                       1/90
   Characterization and Degradation Factors.


   Pesticides

Determine how pesticides contaminate ground waters, identify  processes   $600.0    $455.0     $455.0
involved, and those remedial actions  necessary to  alleviate the problem
PPA D07).

   Feasibility Report for Unsaturated-Saturated Zone Pesticide  Model.              11/87

   Users  Manual  for   Exposure   Assessment   Model   of   Pesticide              6/88
   Contamination of Ground Water.

   Journal Article on Spatial Variability of Pesticide Application.           11/86

   Journal Article on Results of  Field Studies of  PRZM  and PESTANS            12/87
   Leaching Models for Coastal Plain Soils.

   Interim  Report on  Validation Status of Pesticide  Leaching  and              8/88
   Ground-Water Transport Models.

   Ground-Water  Pesticides/Assessment  Manual  for  OPP, States,  and                       6/89
   County Extension Professionals.

   Analyses  of  Pesticide Residues in the Unsaturated  and  Saturated    Continuing
   Zones at a Selected Site in the Dougherty Plain Area of Georgia.

   Report   on  Spatial   Variability  of  Soil  Release   Characteristics     3/87
   (Dougherty Plain Site) for Use in PRZM (Testing).

   Dougherty Plain Annual  Report.                                        9/87

   Dougherty Plain Annual  Report.                                                 9/88

   Report Describing Pesticide Ground-Water Threat Test Results.                             9/89

   Final Dougherty Plain Report Including Pesticide Groundwater Threat                       9/89
   Assessment Methodology Test Results.

   Journal  article  on  Method  for   developing  Joint  Probability     6/87
   Distributions of Soil-Water Retention Characteristics.

   Journal Article  on a Simulation Procedure for Groundwater Quality              9/87
   Assessments of Pesticides.

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                                    G ROUND - WATER RESEARCH                                   27
        Appendix B.  Summary of Outputs from Ground-Water Research Projects (Continued)

                                                                       FY87    FY88   Outvear

   Internal Report on the  Validation Status  of Pesticide Leaching and              8/88
   Groundwater Transport Models.

Develop information  and techniques, including  mathematical models, on      $0.0     $0.0      $0.0
pesticide transport, degradation, residuals, and fate for  agency use and
provide  direct technical support and guidance to OPP (PPA  DOS).

   Report on Mechanisms of Biodegradation of Pesticides in Sediments.                        12/90

   Role of Microbial Biomass in the Enhanced Degradation of Pesticide      9/87
   Products in Sediment.

   Report  on Characterization of  Pesticide Biodegradation  Products  in                       12/91
   Estuarine Sediments.

   Report  on Sensitivity Analysis  and  Testing, Temik Contamination              8/88
   Potential.

   Feasibility Report for Unsaturated-Saturated Zone Pesticide Model.        1/87

   Report on Linking Saturated Zone Model to Unsaturated  Zone Code.             11/87

   Users   Manual   for  Exposure  Assessment   Model of Pesticide              6/88
   Contamination of Ground Water.

   Journal  Article on  Abiotic  Transformations  of Pesticides  in  the              7/88
   Hydrosphere.

   Article   on  Sorption of  Water  Soluble-Ionic   Pesticides  to  Soils                        4/89
   Sediments.

   Journal  Article  on  Pesticide  Transformations on  Environmental                        5/89
   Surfaces.


   Drinking Water

Develop  methods  to  predict subsurface contaminant concentrations  to  $1,063.9  $1,264.1   $1,264.1
support risk analysis and source control (PPA F83).

   Article   Evaluating  the  Potential  of Ground-Water  Colloids  to              4/88
   Facilitate Organic Pollutant Transport.

   Article  on Abiotic Transformation Kinetics  of Selected Contaminants                        2/89
   in the Subsurface.

   Article  on Mineral Surface Effects on Abiotic Transformation Rates.      2/87

   Article  on Haloalkane Reduction by  Ferrous and Sulfide  Ions.                    12/87

   Describing  Movement  of Non-Polar  Compounds  Associated  with      2/87
   Dissolved Organic Carbon.

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                                 GROUND-WATER RESEARCH                                  28
     Appendix B.  Summary of Outputs from Ground-Water Research Projects (Continued)

                                                                    FY87     FY88   Outvear


Article on Methods for Characterizing Subsurface DOC.                          6/88

Article on Spatial and Temporal Gradients of Redox Conditions in an             11/87
Aquifer.

Article on Metal Complexation by Organic Materials in Ground Water.             11/87

Article on Diffusion of Oxygen and Volatile  Organics Through Well             10/87
Tubing.

Article on Electrode  Measurement of Redox Potential.                           10/87

Article on Relationship of Redox Potential to Chemical Constituents                      10/88
of Aquifer Systems.

Article on Evaluating the Redox State of Anaerobic Aquifers.                             10/88

Article on Organic Cation Effects  on the  Retention of Metals and             11/87
Neutral Organic Compounds on Aquifer Materials.

Article on Co-Solute Effects on Solute Retardation.                              6/88

Article on Fate of Norwalk Agent in Ground  Water.                                      12/88

Article on Fate of Rotavirus in Ground  Water.                                           12/88

Behavior of Hepatitis A Virus in Unsaturated Zone.                                      10/88

Report on Predictive Model for Viruses  in the Unsaturated Zone.                          12/89

Article  on  Adaption  of  Subsurface  Microbes to Degrade Organic     1/87
Pollutants.

Article on Minimum Concentrations of Selected Waste Components to             10/87
Support Microbial Transformations.

Article on Kinetics of Microbial Adaptation to Organic Contamination             12/87
at Field Scale.

Report  on  Anaerobic Biotransformation  of Contaminants in  the                      10/89
Subsurface.

Article  on Anaerobic  Biotransformation of  Aromatic Compounds in             12/87
the Subsurface.

Article on Sequential Reduction of Halogenated Organic Compounds.             10/87

Article on Microbial Ecology of a Shallow Unconfined Ground-Water              9/87
Aquifer Polluted by  Municipal Landfill  Leachate.

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                                    GROUND-WATER RESEARCH                                  29
        Appendix B.  Summary of Outputs from Ground-Water Research Projects (Continued)

                                                                       FY87     FY88   Outvear

Develop methods to determine the fate of underground injected wastes   $730.0    $730.0    $730.0
and  develop  safer  technologies in  support  of underground  injection
control (PPA F88).

   Conduct Agency Briefing on Cement Bonding of Injection Wells.        12/86

   Report on Cement Bonding of Injection Wells.                          5/87

   Report on Field Tested Methods for Determining Mechanical Integrity             10/87
   of Injection Wells.

   Report on Methods for Evaluating Cement Bonding Behind Steel and                       12/88
   Fiberglass Casing.

   Report on Laboratory Research on Interaction of Fluids with Geologic             11/87
   Materials--Class I Wells.

   Report  on  the  Physical Hydrology of a Saline Aquifer  Used  for             10/87
   Disposal of  Wastes.

   Report on Physical Hydrology and Hydrochemical Characterization of              7/88
   a Saline Aquifer Used for Disposal of Wastes.

   Report on Effectiveness of Drilling Mud in Research Wells.                                 1/90

   Report  on  Methods  for  Regional Evaluation  of Confining  Bed                       12/88
   Integrity.

   State-of-the-Art Report on Class V Injection Well Practices.                               10/88

   Report on Options  for Improving Class V  Injection  Well Practices.                          10/89

 Evaluate models and management strategies in support  of State wellhead    $160.0    $160.0    $160.0
 protection  programs mandated by  the Safe Drinking Water Act Amend-
 ments of 1986  (PPA F89).

   In-House Report Reviewing and Evaluating Ground-Water Flow, Fate,     6/87
   and Transport  Models  Applicable for  Wellhead  Protection Area
   Delineation.

   Technical Resource Document Concerning Management Strategies for                       10/88
   Wellhead Protection.

 Aquifer Reclamation

   Drinking Water

 Develop new methods for the restoration of contaminated aquifers  and    $900.0    $900.0     $900.0
 provide cost and feasibility  data  to support corrective action decisions
 (PPA F84).

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                                    GROUND-WATER RESEARCH                                   30
        Appendix B.  Summary of Outputs from Ground-Water Research Projects (Continued)

                                                                       FY87    FY88   Outvear

   Report on  In Situ Restoration  of an  Aquifer Contaminated with             10/87
   Halogenated Organic Contaminants.

   Report on Criteria for In Situ Restoration of an Aquifer Contaminated                        6/89
   with Halogenated Organic Concentrations.

   Report on  Monitoring of Subsurface Microbial Populations During              9/88
   Bioreclamation Activities.

   Journal Article Describing Expert System for Estimation of Parameters                       10/89
   for Operating Aquifer Restoration Models.

   Internal Report on Full-Scale Treatment  Design for TCE in  Ground-                        3/89
   Water Design, Criteria, and Economics.

   Computer Code  and Appropriate Documentation for Attenuation of             10/87
   Ground Water Contaminants Due to Natural  Processes.

   Article on Field  Validation of Model.                                           12/87


Source Control

   Hazardous  Waste

Develop  and  field-verify improved  design,  operation,  and closure    $596.9    $200.9     $200.9
procedures for hazardous  and  nonhazardous landfills, surface impound-
ments, waste  piles, and underground storage facilities used to contain
wastes and  reduce  the  risk of contaminant migration  to ground  water
(PPA L42).

   Report on  field  verification of  landfill cover system construction to             12/87
   provide hydrologic isolation.

   Report on maintenance free vegetation systems for landfill covers.                4/88

   Technical Resource Document on design, construction, and evaluation      9/87
   of clay liners, revised to incorporate public comments.

   Report on effects of organic materials on clay soil liners.                 9/87

   Report on effective porosity of geologic materials.                               12/87

   Report on determination of effective porosity of soil materials.                   12/87

   Report  on effects  of  hydraulic  gradient  and   field  testing   on                       12/89
   measurement of  hydraulic conductivity of soils.

   Report on  influence of aggressive permeant liquids on bentonite  soil             05/88
   liners.

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                                  G ROUND - WATER RESEARCH                                   31
     Appendix B.  Summary of Outputs from Ground-Water Research Projects (Continued)

                                                                     FY87    FY88   Outvear

Technical Resource  Document on batch-type adsorption procedures              6/88
for estimating soil attenuation of chemicals, revised to incorporate
public comments.

Technical Resource Document update on flexible membrane liners.                09/88

Report on the chemical resistance of flexible membrane liners.            6/87

Report evaluating the use  of cohesive energy  density numbers for
determining chemical resistance.                                        9/87

Report on the use of synthetic liner physical properties in design.         4/87

Report evaluating  the  relevance  of  chemical resistance  data in             10/87
determining the service life of FMLs.

Report on the inspection procedures and  criteria for installation of     6/87
liners.

Report on development of automated  systems  to assist in decisions              8/88
concerning hazardous-waste facilities.

User  support  for the  HELP  model  at  hazardous waste disposal              1/88
facilities.

Report  on  the  use  of expert systems  for  determining flexible     9/87
membrane liner compatibility with waste chemicals.

Report on waste analysis plan evaluation system of RCRA  permits.                         12/88

Report on field verification of rate-of-release model.                    9/87

Report on  development of criteria and  standards  for  design and              1/88
evaluation of stabilization and solidification processes.

Report on expert system to  evaluate closure plans.                                9/88

Report and  software to develop a method for FML reliability.                              12/89

Report comparing the batch and column leaching methods.                        4/88

Technical Resource  Document on surface impoundments.                                    9/90

Technical Resource  Document  update on  chemically stabilized and                        9/90
solidified waste.

Report on  evaluation  and assessment of  stabilization  processes to                       10/88
determine extent of fixation.

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                                    GROUND-WATER RESEARCH                                  32
        Appendix B.  Summary of Outputs from Ground-Water Research Projects (Continued)

                                                                      FY87    FY88   Outvear

   Report on treatment technology for major hazardous waste streams.                        12/89

Identify  and Evaluate Improved  Practices  to Prevent  Releases  from $2,103.1  $1,301.2   $1,301.2
New/Existing Underground Storage Tanks and Detect and Measure Leak
Rates from  Underground Storage Tanks and  Associated Piping (PPA
R63).

   Report on Tank Equipment Installation Practices and Environmental    12/86
   Factors on Tank Life.

   State  of  the  Art  Report  on  Repair  Techniques  Effective   for             9/88
   Preventing Releases from USTs.

   State  of  the  Art  Report  on Secondary  Containment Systems  and             9/88
   Liners for USTs.

   Evaluation of "Prevention Methods" Over Long-Term Operation.                            9/89

   Report on the Effectiveness of Cathodic Protection for New/Existing                       9/90
   USTs and Development of Guidelines for  Inspecting, Testing, and
   Maintaining Cathodic Protection Systems.

   Guidelines for Retrofitting Existing UST Installations  with Secondary                       9/91
   Containment Systems.

   Evaluation Report on Leak Detection Methods  for Petroleum Storage            12/87
   Tanks Interim Report.

   Evaluation Report on Leak Detection Methods  for Petroleum Storage             9/88
   Tanks Interim Report Final Report.

   Evaluation Report on Leak Detection Methods for Chemical Storage                      12/88
   Tanks Interim Report.

   Evaluation Report on Leak Detection Methods for Chemical Storage                       9/89
   Tanks Final Report.

   Evaluation Report on  Product  Level Monitoring Devices  Interim              1/88
   Report.

   Evaluation Report on Product Level Monitoring Devices Final Report.              1/88

   Development of New/Improved Leak Detection Methods.                                  9/91

 Demonstrate New/Improved Approaches  for Stopping Releases from  a     $0.0   $950.0   $2,100.0
 Leaking Tank System and Preventing Associated Environmental Damages
 (PPA R63).

   Interim Guidance on Corrective  Actions for Leaking Underground     2/87
   Storage Tanks.

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                                    GROUND-WATER RESEARCH                                  33
       Appendix B. Summary of Outputs from Ground-Water Research Projects (Continued)

                                                                      FY87    FY88  Outvear

  Report on Case Studies  of  Past and  Ongoing Corrective  Actions  at              2/88
  UST Sites.

  Corrective Action Guidance Document  for Application to Leaking                       2/89
  UST  Situations 5/8erim Report  on the Performance  Evaluation  of
  LUST Corrective Action Technologies.

  Development of a Technology Transfer Seminar on LUST Corrective                       9/89
  Action Technology.

  Report on Tank  Equipment Installation Practices and Environmental                       12/88
  Factors on Tank Life.

  State  of  the  Art  Report  on  Repair  Techniques  Effective  for              9/88
  Preventing Releases from USTs.

  State  of  the  Art Report  on Secondary Containment  Systems and              9/88
  Liners for USTs.

  Evaluation of "Prevention Methods" Over Long-Term Operation.                           9/89

  Report on the  Effectiveness of Cathodic Protection for New/Existing                       9/90
  USTs  and Development of Guidelines for Inspecting, Testing, and
  Maintaining Cathodic Protection Systems.

  Guidelines for Retrofitting Existing UST Installations with Secondary                       9/91
  Containment Systems.

Determine the applicability and cost-effectiveness of in situ reclamation    $201.4   $106.1    $106.1
techniques to unsaturated-zone and ground-water contamination resulting
from  leaking underground storage  tanks (UST)  and  other  hazardous
waste sources (PPA R64).

  Report  on Hydrogeological Approaches for  Mobilizing  Immiscible              9/88
  Wastes for Corrective Actions.

  Report on Improved Techniques for In situ UST Corrective Actions.                       10/89

  Report on In  situ Treatment Process for Water Contaminated with      8/88
  Wastes from UST Releases.

  State-of-the-Art  Report  for  Existing  In situ  Corrective  Action     10/86
  Techniques Applicable to UST.

Develop a comprehensive technical data base  on new and existing tech-    $480.0      $0.0      $0.0
nologies for land treatment of hazardous wastes  for which incineration
or conventional land disposal are inappropriate, infeasible, or ineffective
(PPA L44).  (This PPA no  longer exists)

  Internal Report on Pilot Plant.                                         10/86

  Technical Resource Document on Selection Procedures.                   2/87

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                                    GROUND-WATER RESEARCH                                   34
        Appendix B.  Summary of Outputs from Ground-Water Research Projects (Continued)

                                                                       FY87    FY88  Outvear


   Article on Evaluation of RITZ Model Using Project Data Base.           1/87

   Journal Article on  Mathematical Modeling for Pesticides Behavior in    12/86
   Soil Using Soil Treatability Study Data.

   Report on Land Treatability of Selected Hazardous Wastes, Vol. I.                 12/87

   Report on Land Treatability of Hazardous Wastes, Vol. II.                         9/88

   Report on Land Treatability of Selected Hazardous Wastes, Vol. III.                9/88

   Internal Report on Land Treatability Evaluation  for Selected Subtitle     4/87
   D Wastes.

   Report on Land Treatability of PCP and Creosote Wastes.                                   1/89

   Report on Bench/Pilot Scale Land Treatability of PCP and Creosote     4/87
   Wastes.

   Users Guide for Land Treatability Decision Models.                                         6/89

   Report on Evaluation of Land Treatability Decision Models.                                 3/89

   Report on Soil Fate and Effects Literature Assessment.                   3/87

   Computerized Data Bank on Fate and Effects  of Hazardous Organics     6/87
   in Soil.

   Report on Impact of Sensitive RITZ Model Parameters.                           5/88

   Report on  Computerized Literature  Search  on Fate and  Effects of    12/86
   Appendix VIII Organics in Soil.

   User-Friendly Program for Land Treatment Decision Models.             9/87

   Report on Field Evaluation of RITZ Model.                                               12/88

   Report on Fate  and Transport  of  Residual  Matrix Constituents in                        4/89
   Soil at Closed Sites.

   Report on Land  Treatment  Case  Studies for  Selected Subtitle D                        2/89
   Wastes.

   Super fund

Provide Response Technologies to Support Cleanup Actions for Contam- $1,666.7 $1,333.3  $1,333.3
inated Ground Water and Soils at Uncontrolled Waste Sites (PPA B01).

   Handbook on Leachate Treatment Techniques.                               12/86

   Report on Utilization of Plants for Organic Uptake from Soil.                     4/88

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                                    GROUND-WATER RESEARCH                                   35
       Appendix B. Summary of Outputs from Ground-Water Research Projects (Continued)

                                                                      FY87    FY88   Outvear


   Report on Sorption Technology.                                                         08/89

   Report on Slurry Wall and Grout Systems.                              4/87

   Report on Freezing Techniques.                                                          9/89

   Reports  on the Uses of Hydrofracturing and Horizontal Drilling in             4/88
   Innovative In situ Recovery Processes.

   Report on Commercial Point-of-Entry Water Treatment for Superfund             6/88
   Applications.

   Report on Support Aerated Biofilms for Biodegradation  of Organics.                        08/90

   Report on Gene-Engineered  Yeast for Biodegradation of Wastes.                           09/89

   Report on Flow-Through Processes for Treatment of Contaminants in                      10/91
   Soils.

   Report on the Use of Surfactants as Additives for Aqueous Extraction                      10/89
   of Organics in Soils.

   Report on Transportable System for Biodegrading Leachate/Extract             4/88      9/89
   from Soil.

   Handbook on In-Situ Treatment of Hazardous Waste  Contaminated                      09/90
   Soils.

Provide Engineering Support for Site and  Situation  Assessments of
Ground-Water Resources at Uncontrolled Hazardous Waste Sites (PPA
A31).

   Report on Biodegradation of Environmental Pollutants.                                     5/90

   Report and Paper on Measurement of Liquid Travel time through Soil             7/88
   Barriers.

   Report and Paper on Characterization of Landfill Leachates Potential                      10/90
   to NPL Sites.

   Report on Use of Geosynthetics to  Stabilize Covers.                                       10/90

Technology  Transfer and Technical Assistance

Develop  timely  and  effective  methods  of  transferring  technical  $1,300.0 $1,300.0   $1,300.0
information to  appropriate  federal,  state,  local,  and general  public
groups through  publications, workshops, training courses, and other
communication  mechanisms.

   EMSL-LV/RSKERL Subsurface Monitoring Symposium.                11/86

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                                GROUND-WATER RESEARCH
                                                                                         36
     Appendix B. Summary of Outputs from Ground-Water Research Projects (Continued)

                                                                  FY87    FY88   Outvear

                                                                  05/87
  Outdoor Action Conference on  Aquifer  Restoration, Ground-Water
  Monitoring, and Geophysical Methods.

  Transport  and  Fate  of  Contaminants  in  the  Subsurface (2-day
  Workshops).

  Continuing  Compliance  Guidelines for  Treatment,  Storage,  and
  Disposal Facilities.

  Application of Geophysical Methods to  Ground Water.

  Handbook on  Evaluating the Design, Construction, and Operation of
  Hazardous Waste Disposal Facilities.

  Seminars on Corrective Action:  Procedures, Technologies, and Costs.

  Handbook on  Installation, Construction, and Maintenance of Flexible
  Membrane Liners.

  Seminars on Land Disposal Restriction Program Implementation.

  Two-Day  Seminars  on  Alternative  Treatment   Technologies  for
  Superfund Waste Sites.

  Publication on Lessons Learned from Remedial Response Case Studies.

  Tenth Annual Ground-Water Research Symposium--Fate and Transport.

  Advanced Field Monitoring Instrumentation Conference.

  Drinking Water

Develop and   transfer improved  methods  for measuring subsurface
parameters that influence contaminant behavior (PPA F82).

  Training Manual on Ground Water Contaminant Modeling.

  Training Course Document on Conducting GW Investigation.

  Development of a Slide Tape Program.

  Report on Existing  Ground-Water Models.

  Proceedings on Workshop  and Symposia on Microbial  Problems  in
  Ground Water.

  Development  of a  National  Library Center  for  Ground  Water
  Information Data Base.
                                                                            2/88


                                                                                    10/88


                                                                                     9/89

                                                                                     1/89


                                                                            6/88

                                                                            9/88


                                                                            9/88

                                                                            3/88


                                                                            7/88

                                                                   4/87     4/88

                                                                   5/87     5/88



                                                                  $600.0  $350.0     $350.0


                                                                   7/86

                                                                  12/86
                                                                            6/88
                                                                                     10/88
                                                                   6/87
                                                                   Continuing
Conduct Technology Workshops.
                                                                     Continuing

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                                    GROUND-WATER RESEARCH                                  37
        Appendix B. Summary of Outputs from Ground-Water Research Projects (Continued)

                                                                      FY87    FY88   Outvear

   Report on Vertical Distribution and  Movement of Volatile Organic             1/88
   Compounds in the Subsurface.

Joint U.S.-Peoples Republic of China Environmental Protection Protocol    $20.0    $20.0      $0.0
supporting joint research on  the impact of  wastewater  land  treatment
on ground-water supplies (PPA F87).

   Final Report on Chinese - EPA Cooperative Land Treatment Research             3/88
   Project - Rapid Infiltration.

   Super fund

Provide Superfund enforcement and response programs with rapid access   $706.0    $700.0    $700.0
to the  best available technical information,  evidence,  and  testimony
(PPA F22).

   Establish Clearinghouse for Information on Ground Water Remedial             8/88
   Action Technologies.

   Internal  Report on  Technical  Support to Region III  to Develop            11/87
   Methods  for  Assessing  the  Effectiveness  of  Soil  Removal  as  a
   Remedial Action.

   Technology  Transfer  Document  on Use  of Assessment Models for                       1/89
   Remedial Action.

   Internal  Report on Regional Ground  Water  Modeling Information                      10/88
   Needs and Assistance as Provided.

   Users Manual on Use  of Geostatistical Models for Managing Soil and                      12/89
   Water Contamination.

   Technology Transfer  Seminar Publication entitled  "Transfer and Fate                      12/88
   of Contaminants in the Subsurface."

   Ground-Water Technology Workshops.                                                  12/88

   Technology Transfer  Document on Evaluation of Bioremediation as a                       1/89
   Remedial Action Technology.

   Report on  Technical  Support to  Regions for  Multimedia Exposure             8/88
   Assessments Related to Remedial Actions.

   Report on  Technical  Support to  Regions for  Multimedia Exposure                      11/88
   Assessments Related to Remedial Actions.

   Report on Procedure for Relative Risk Assessment and Ranking for                       2/89
   Action Among Listed  Sites and RCRA Closure  Activities.

   Report on  Identification  of Unlisted  Chemicals for Evaluation  as             8/88
   Drinking Water Contaminants.

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                                 GROUND-WATER RESEARCH                                  38
     Appendix B.  Summary of Outputs from Ground-Water Research Projects (Continued)

                                                                   FY87    FY88  Outvear

Report on Environmental Factors Affecting Anaerobic Biodegradation.              6/88

Report on Equations for Predicting Anaerobic Transformations within                       11/89
the Saturated Zones.

Report  on Applicable Methods  for  Estimating  the Magnitude and                       9/90
Areal Extent of Ecological Risks at Marine Superfund Sites.

Report  on   Integrated  Assessment   Methods  and  Strategies  for                       12/92
Estimating and Reducing Risks at Marine Superfund Sites.

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                                    GROUND-WATER RESEARCH                                  39
                  APPENDIX C:  RECENT GROUND-WATER PUBLICATIONS

   EPA publications in the 600 and 625 series (ORD) and 540 series (OERR) may be obtained by
   calling FTS 684-7562 (513-569-7562).  Publications in the 530 series (OSW) may be obtained by
   calling FTS 382-4646 or 800-424-9346.


General

EPA Ground-Water Research Programs.  EPA/600/8-86/004, PB86 212-552, April 1986.

Protection of Public Water Supplies from Ground-Water Contamination. EPA/625/4-85/016, PB86 168-358
September, 1985.

Handbook: Ground Water.  EPA/625/6-87/016, March  1987.


Monitoring

Underground Tank Leak Detection Methods:  A State-of-the-Art Review.  EPA/600/2-86/001, PB86 137-
155, January 1986.

Practical Guide for Ground-Water Sampling.  EPA/600/2-85/104, PB86 137-304, September 1985.

"Sorption  of Organics by Monitoring Well Construction Materials."  A.L. Sykes,  R.A. McAllister, and
J.B. Homolya, Ground Water Monitoring Review, 6(4):44-47, Fall 1986.

"Underground Storage Tank Monitoring:  Observation Well Based Systems." R.A. Scheinfeld, J.B.
Robertson, and T.G.  Schwendeman, Ground Water Monitoring  Review, 6(4):49-55, Fall 1986.

"The Effect of Sampling Frequency on Ground Water Quality Characterization."  R. Rajagopal, Ground
Water Monitoring Review, 6(4):65-73, Fall 1986.

"The Use  of Industrial Hygiene Samplers for Soil-Gas Surveying." H.B. Kerfoot and C.L. Mayer.
Ground Water Monitoring Review, 6(4):74-78, Fall  1986.

A Guide to  the Selection of Materials for Monitoring Well Construction and Ground-Water Sampling.
MJ. Barcelona, J.P. Gibb, and R.A. Miller, Illinois  State Water Survey Contract Report 327, 1983.

"In Situ Monitoring at Superfund Sites with Fiber Optics."  L.A. Eccles, S.J. Simon, and S.M. Klainer.
EPA/600/X-87/156,  1987.

"Shallow-Probe Soil-Gas Sampling for Indication of Ground-Water Contamination by Chloroform."  Int.
J. Environmental Analytical Chem. 30:167-168, 1987.

Soil Gas Measurement for Detection of Subsurface Organic  Contamination. H.B. Kerfoot and L.J.
Barrows.  EPA/600/2-87/027, 1987.

Field Methods for Locating Abandoned Wells--A Comprehensive Summary for Fiscal Years 1983 through
1987. E.N. Koglin, J.J. van Ee, and A.M. Pitchford.  EPA/600/X-87/168, June 1987.

"Remote Detection of Organochlorides with a Fiber Optic Based Sensor. II.  Dedicated Portable
Fluorimeter." Analytical Instrumentation, 15(4), December  1986.

"Techniques  for Delineating Subsurface Organic Contamination: A Case Study."  In, Detection, Control,
and Renovation  of Contaminated Ground  Water,  ASCE, April 1987.

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"Performance of a Prototype Field-Portable X-Ray Fluorescence System."  G.A. Raab et al. Presented at
OSW Symposium, Washington, DC, July  1987.

"Use of Borehole Geophysics to Define Hydrologic Conditions—A Field Example."  K. Taylor and S.
Wheatcraft.  NWWA Conf. Proc. on Surface and Borehole Geophysical Methods and Ground-Water
Instrumentation, October 1986.

Processes Affecting Subsurface Transport of Leaking Underground Storage Tank Fluids. S.W. Tyler et
al.  EPA/600/6-87/005, 1987.

"Strategy for Detecting Subsurface Organic Contaminants."  In, NWWA Conf. Proc. on Petroleum
Hydrocarbons and Organic Chemicals in Ground Water, November 1986.


Fate and Transport and Aquifer Reclamation

Modeling Remedial Actions at Uncontrolled Hazardous Waste  Sites.  EPA/540/2-85/001, PB85  211-357,
April 1985.

Users Manual for the Pesticide Root Zone Model (PRZM).  EPA/600/3-84/109. December 1984.

Leaching Evaluation of Agricultural Chemicals (LEACH) Handbook.  EPA/600/3-84/068, PB84 236-413,
June 1984.

MEXAMS--The Metals Exposure Analysis  Modeling System.  EPA/600/3-84/031, PB84 157-155, February
1984.

MINTEQ--A Computer Program for Calculating Aqueous Geochemical Equilibria.  EPA/600/3-84/032,
PB84 157-148, February 1984.

DRASTIC:   A Standardized System for Evaluating Ground Water Pollution Potential Using
Hydrogeological Settings.  EPA/600/2-85/018, PB85 228-146, May 1985.

Groundwater Transport:  Handbook of Mathematical Models.  I. Javandel, C. Doughty, and C.F. Tsang,
Amer. Geophysical Union, Water Resources Monograph 10, 1984.

Groundwater Management:  The Use of Numerical Models (Second Edition). P. van der Heijde, Y.
Bachmat, J. Bredehoeft, B. Andrews, D. Holtz, and S.  Sebastian, Amer. Geophysical Union, Water
Resources Monograph 5,  1985.

"Evolving Concepts of Subsurface Contaminant Transport."  J.F. Keely, M.D. Piwoni, and J.T. Wilson, J.
Water  Pollution Control Fed.  58(5):349-357, May 1986.

Ground-Water Modeling.   J.W. Mercer and C.R. Faust, National Water Well Assoc., 1981.

"In-Situ Biorestoration as a Ground Water Remediation Technique." J.T. Wilson, L.E. Leach, M. Henson,
and J.N. Jones, Ground Water Monitoring Review, 6(4):56-64, Fall 1986.


Source Control

The Hydrologic Evaluation of Landfill Performance (HELP) Model: Volume I.  EPA Technical Resource
Document EPA/530/SW-84/009, PB85 100-840, June 1984.

The Hydrologic Evaluation of Landfill Performance (HELP) Model: Volume II.  EPA Technical Resource

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                                   GROUND-WATER RESEARCH                                 4I
Document EPA/530/SW-84/010, PB85 100-832, June 1984.

Review of In-Place Treatment Techniques for Contaminated Surface Soils: Volume I, Technical
Evaluation. Remedial Action Handbook, EPA/540/2-84/003a, PB85 124-881, September 1984.

Review of In-Place Treatment Techniques for Contaminated Surface Soils: Volume II, Background
Information for In-Situ Treatment.  Remedial Action Handbook, EPA/540/2-84/003b, PB85 124-899,
November 1984.

Slurry Trench Construction for Pollution Migration Control.  Remedial Action Handbook, EPA/540/2-
84/001, PB84 177-831, February 1984.

Covers for Uncontrolled Hazardous  Waste Sites.  Remedial Action Handbook, EPA/540/2-85/002, PB86
119-483, September 1985.

Leachate Plume Management.  Remedial Action Handbook, EPA/540/2-85/004, PB86 122-330, November
1985.

Handbook for Stabilization/Solidification of Hazardous Wastes. R'emedial Action Handbook, EPA/540/2-
86/001, June 1986.

Handbook for Remedial Action at Waste Disposal Sites (Revised).  Remedial Action Handbook,
EPA/625/6-85/006, October 1985.

Underground Storage Tank Corrective Action Technologies.  EPA/625/6-87/015, January 1987.

Design and Construction of a Mobile Activated Carbon Regenerator System.  EPA/600/2-86/015, PB86
156-486, January 1986.

Treatment of Contaminated Soils with Aqueous Surfactants.  EPA/600/2-85/129, PB86  122-561, November
1985.

Batch-Type Adsorption Procedures  for Estimating Soil Attenuation of Chemicals:  Public Comment Draft
Technical Resource Document.  EPA/530-SW-87-006, PB 87-146155, June 1987.

Design, Construction, and Evaluation of Clay Liners for Waste Management  Facilities:  Public Comment
Draft Technical  Resource Document.  EPA/530-SW-86-007, PB 86-184496,  May 1986.

Technical Guidance Document:  Construction Quality Assurance for Hazardous Waste Land Disposal
Facilities, EPA/530-SW-86-031, PB 87-132825, October  1986.

Engineering Guidance for the Design, Construction, and  Maintenance of Cover Systems for Hazardous
Waste.  EPA/600/2-87-039, PB 87-191656, May 1987.


 Risk Assessment

 "Health Risk Comparison Between Groundwater Transport Models and Field  Data."  Environmental
 Progress, 5(1):66-70, February 1986.

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