r/EPA
                              United States
                              Environmental Protection
                              Agency
                                    EPA/600/9-90/003
                                    February 1990
Request for Applications
                    PC1-90
                              The  Role  of Sediments in  the
                              Transport and Fate of
                              Pollutants in  Freshwater and
                              Estuaries
Background
  This is a request for grant applications to conduct research
on the physical, chemical and biological processes controlling
contaminant transport and transformation near the sediment-
water interface of aquatic systems.
  It is believed that pollutants previously deposited in bottom
sediments are contributing to the degraded water  quality
conditions which exist in many  aquatic  systems.  The Great
Lakes, Chesapeake Bay, Long Island Sound  and many near
shore areas  of the  ocean  are  viewed  as being seriously
affected by these deposited pollutants. For the Environmental
Protection Agency  (EPA) to establish suitable management
programs for these  systems the relative  importance of
pollutants  in  sediments must be identified. Because of the
differences between  aquatic systems, a general methodology
must be developed to address questions concerning exposure
to pollutants from contaminated sediments.

Scope
  Bottom sediments  become  contaminated with toxic
substances which have entered  the aquatic system  through
processes which include sorption by viable  and  non-viable
suspended solids and settling from the water column. Other
processes such as resuspension due  to wave action or
currents,  biological benthic activity, and diffusion of dissolved
species can result  in fluxes of contaminants across the
sediment-water interface, thus providing a source of exposure
to toxic substances.  To make  site-specific predictions of
exposure level, subsequent biological uptake  and foodchain
bioconcentration, and downstream ecosystem contamination
resulting  from  these fluxes  will  require  a  thorough
understanding of all the processes involved and how they are
linked to result in one or more exposure pathways.

  The relative contributions of physical resuspension, activity
of benthic organisms, and molecular diffusion in causing flux of

        L-,3. Environmental Protection Agency
        Region 5, Library (PL-12J)
        77  West Jackson Boulevard, 12th  Floor
       Chicago,  It,  606Q4-3590
                      contaminants at the sediment-water interface must be known
                      as a function of environmental conditions. Research is needed
                      to identify the hydrologic factors and sediment properties that
                      govern the frequency and severity of resuspension events. The
                      behaviour of fine-grained  sediments  including  resuspension
                      deposition and flocculation  is of particular importance because
                      of their large capacity for  adsorbing contaminants.  Resulting
                      relationships must be quantified so that  the transport  of
                      particulate  and  dissolved phase contaminants within the
                      sediments and across the sediment-water  interface can be
                      modeled and the models parameterized.
                         An important class of processes relate to the interaction  of
                      dissolved contaminants with particulate matter which may alter
                      the phase and/or speciation of the contaminants, and does alter
                      their transport regime. The adsorption or uptake of  pollutants
                      by sediment material can  affect the rates and extent of their
                      biochemical transformation and  biotic  accumulation thus
                      altering their environmental  effects.  Research  is needed  to
                      provide information  describing  the rate  and extent to  which
                      nutrients, metals, metalloids and organics undergo phase and/
                      or speciation changes in response to the  environmental factors
                      that control aquatic systems.
                         The projects being sought should relate to the information
                      and/or techniques  needed to predict the  exposure  of
                      environmental receptors to contamination from sediments  in
                      freshwater and estuarine systems.


                      Mechanism of Support
                         Assistance under this RFA will be  provided by a  research
                      grant,  administered through  EPA's investigator-initiated
                      research grants program. The applicant will be responsible for
                      the planning, direction and execution of the proposed research.
                      Support under this  program is  limited to non-profit
                      organizations and educational institutions.
                         Approximately 1.0 million dollars will be available from fiscal
                      1990 funds and  it is estimated that 4 to 6 projects will be

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supported. This RFA is for a single competition with a deadline
of April 13,1990.


The Application
   Each  application  will consist of  APPLICATION FOR
FEDERAL ASSISTANCE forms (standard forms 424 and 424A),
separate sheets providing the  budget breakdown for each year
of the project, curriculum vitae for the principal investigator,
abstract of  the  proposed project,  and a project narrative. All
certification (drug free work-place, etc.) forms must be signed
and included with the application. Attachments, appendices or
other materials  included in addition to  those identified above
will not be forwarded  to the reviewers. Application  forms,
instructions, and other  pertinent information are contained in
the EPA grant application kit obtainable from:

             Research Grants Staff (RD-675)
             U.S. Environmental Protection Agency
             Washington, DC 20460


or by calling (202) 382-7445.

Special  Instructions
1. The project narrative or proposal must not exceed 25 single
   sided 8-1/2 by 11  inch pages. Typeface must be standard
   10-12 characters per inch.
2. CVs or resumes must not exceed 2 pages and should focus
   on education, positions held and most recent publications.
3. Project periods should not exceed three years. Third year
   funding for a three year project will require submission of a
   continuation application.
                                 4. Applications in response to this RFA must be identified by
                                   printing "RFA PC1-90" in the upper right hand corner of the
                                   EPA assistance  application  form. The  absence of  this
                                   identifier from  an  application  absolves  EPA of  any
                                   responsibility if it is not reviewed along with the other
                                   applications responding to this RFA.

                                 Application Review
                                   All  applications  in response  to  this solicitation will be
                                 reviewed  at a single meeting of a scientific peer panel which
                                 will evaluate and rank each proposal according to it's scientific
                                 merit  as  a basis  for  recommending  agency approval or
                                 disapproval. The panel will consider:

                                   "quality of research plan (including theoretical and/or
                                    experimental design, originality, and creativity),
                                   "qualifications of  the research team, and
                                   "availability and adequacy of facilities and equipment.

                                 Application Submission
                                   The original and eight copies of the application must be
                                 received no later than the close of business, April 13, 1990, to
                                 be considered. The applications must be sent to:

                                              Grants Operations Branch (PM-216F)
                                              Grants Administration Division
                                              U.S.  Environmental Protection Agency
                                              Washington, DC 20460

                                 Staff  Contact
                                   Questions relating to this solicitation may  be directed to
                                 Louis  Swaby by telephone on (202) 382-7445.
 United States
 Environmental Protection
 Agency
     Center for Environmental Research
     Information
     Cincinnati OH 45268
 Official Business
 Penalty for Private Use $300

 EPA/600/9-90/003
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