Progress  in  Water Quality:
        An Evaluation of the National Investment
            in  Municipal Wastewater Treatment
^                              Prepared by:
^                             Tetra Tech, Inc.
^j                              Fairfax, VA
^                               and
                          Andrew Stoddard & Associates
                               Hamilton, VA
                               Prepared for:

                         U.S. Environmental Protection Agency
                          Office of Wastewater Management
                              Washington, DC

                               June, 2000
                       U.S. Environmental Protection Agency
                       Region 5, Library (PL-12J)
                       77 West Jackson Boulevard, 12th Ftoflf
                       Chicago. IL 60604-3590

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                     Dedication
    This effort to document the water quality benefits associated with
the federal funding provided through the Construction Grants Program
and Clean Water State Revolving Fund (CWSRF) Program  to help
plan,  design and construct publicly owned treatment works  (POTWs)
was initiated at the request of Michael J.  Quigley  while he served as
Director of the Office of Municipal Pollution Control. It is dedicated to
the many hardworking and conscientious individuals—including  the
program advocates and critics  alike—who help manage,  direct (or in
some  cases redirect),  and implement the Construction Grants and
CWSRF Programs, which are among the Nation's largest public works
programs, in a highly professional and effective manner.  They  include
many EPA and state program managers and staff and local wastewater
authority managers and staff, as well as  the many  highly qualified
consultants and contractors who help the local authorities conduct  the
necessary studies, develop the required facilities plans and project design
documents, and construct and operate the treatment facilities that were
established or upgraded with funding from these highly successful public
works programs.
    The document could not have been written without the extensive
water quality monitoring efforts across the country undertaken by a legion
of highly qualified field staff and researchers for many local authorities,
state and federal agencies, and colleges and universities.  Their efforts
produced the extensive water quality data available in the  STORET
database system and local reports, as well as  the water quality models
and local assessments that served as the basis for the analyses undertaken
and reported on in this document.

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Contents
   Foreword	     ix
   Acknowledgments	     xi
   Acronyms	     xiii

Executive Summary	  ES-1

Chapter 1—Introduction	    1-1
   Background	     1-2
   Study Approach	     1-4
   The First Leg: An Examination of BOD Loadings Before and After the CWA	     1-5
   The Second Leg: An Examination of "Worst-Case" DO in Waterways
       Below Point Sources Before and After the CWA	     1-6
   The Third Leg: Case Study Assessments of Water Quality	   1-12
   The Audience For This Report	   1-13
   References	   1-14

Chapter 2—An Examination of BOD Loadings Before and After the CWA	    2-1
   A.  Historical Consequences of Ignoring the Wastewater Treatment Component
       of the Urban Water Cycle	    2-2
        Impacts on Water  Supply Users and "The Great Sanitary Awakening"	    2-3
        Impacts on Water  Resource Users	    2-5
   B.  Evolution of Wastewater and the Use of DO and BOD as Indicators of Water Quality	    2-7
        Primary Treatment	    2-7
        Dissolved Oxygen as an Indicator of Water Quality	    2-7
        Secondary Treatment	    2-9
        Biochemical Oxygen Demand (BOD)  as a Measure of Organic Wasteload Strength	   2-10
   C.  The Federal Role in Implementing Secondary Treatment in the Nation's POTWs	   2-11
        The  Federal Role  in Secondary Treatment Before the Clean  Water Act	   2-11
        The  Federal Role  in Secondary  Treatment After the Clean Water Act	   2-18
   D.  Nationwide Trends in BOD Loading Based on Population and POTW Treatment Design	   2-26
        Types of BOD Reported in This Trends Analysis	   2-28
        Trends in  POTW Inventory	   2-31
        Trends in  Population and Influent Wastewater Flow to POTWs	   2-32
        Trends in  Influent  BOD Loading to POTWs	   2-35
        Trends in  Effluent BOD Loading from POTWs	   2-38
        Trends in  BOD  Removal Efficiency	   2-43
        Future Trends in BOD Effluent Loading	   2-45
   E.  Comparison of Contemporary BOD5 Loadings From POTWs and Other Point and Nonpoint
     Sources Based on Estimates of Actual Loadings	   2-48
        Pollutant Loading  From Sources Other Than  POTWs	   2-49
        Estimates  of Contemporary (ca.  1995) BOD  Loading Using the National Water
           Pollution Control Assessment Model (NWPCAM)	   2-53
        Comparison of Point and Nonpoint Sources of BOD5 at the National  Level	   2-63
   F.  Investment Costs for Water Pollution Control Infrastructure	   2-63
        The  Construction  Grants Program	   2-63

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         Other Investment Cost for Water Pollution Control Infrastructure	   2-66
         Future Infrastructure Needs	   2-67
   G.  Summary, Conclusions, and Future Trends	   2-68
         Key Points of the Background Sections	   2-68
         Key Points of the BOD Loading Analysis Sections	   2-69
         Key Points of the Investment Costs Section	   2-71
         Conclusions and Future Trends	   2-72
   References	   2-73

Chapter 3—An Examination of "Worst-Case" DO in Waterways Below Point Sources
              Before and After the CWA	    3-1
   A.  Background	    3-2
         Sources of DO Data	    3-3
         "Worst Case" Conditions as a Screening Tool	    3-5
         The Role of Spatial Scale in  This Analysis	   3-12
   B.  DataMining	   3-13
         Step 1—Data Selection Rules	   3-13
         Step 2—Data Aggregation Rules  From a  Temporal Perspective	   3-14
         Step 3—Calculation of the Worst-Case DO Summary Statistic Rules	   3-14
         Step 4—Spatial Assessment Rules	   3-15
         Step 5—Data Aggregation Rules  From a Spatial Perspective	   3-18
         Step 6—Development of the Paired Data  Sets (at each spatial scale)	   3-19
   C.  Comparison of Worst-Case DO in Waterways Below Point Source Discharges
        Before and After the CWA at Three Spatial  Scales	   3-20
         Reach Scale	   3-20
         Catalog Unit Scale	   3-25
         Comparison of the Change in Signal Between the Reach and Catalog Unit Scales
            Using the Upper White River Basin (Indiana) as an Example	   3-33
         Major River Basins	   3-38
   D.  Summary and Conclusions	   3-43
         Key Points of the Background Section	   3-43
         Key Points of the Data Mining Section	   3-44
         Key Points of the Comparative Analysis Section	   3-45
         Conclusions	   3-47
   References	   3-51
Chapter 4—Case Study Assessments of Water Quality	   4-1
   A.  Background	    4-2
   B.  Selection of Case Study Waterways	    4-4
   C.  Before and After CWA	    4-6
   D.  Policy Scenarios for Municipal Effluent Discharges	    4-8
   E.  Discussion and Conclusions	  4-10
   References	  4-12

Chapter 5—Connecticut River Case Study	   5-1
   Background	    5-1
   Physical Setting and Hydrology	    5-2
   Population, Water, and Land Use Trends	    5-4
   Historical Water Quality Issues	    5-5
   Legislative and Regulatory History	    5-6
   Impacts of Wastewater Treatment: Pollutant Loading and Water Quality Trends	    5-6
VI

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    Impacts of Wastewater Treatment: Recreational and Living Resources Trends	    5-9
    Summary and Conclusions	   5-10
    References	   5-11

Chapter 6—Hudson-Raritan Estuary Case Study	    6-1
    Background	    6-1
    Physical Setting and Hydrology	    6-2
    Population, Water, and Land Use Trends	    6-4
    Historical Water Quality Issues	    6-6
    Legislative and Regulatory History	    6-9
    Impact of Wastewater Treatment: Pollutant Loading and Water Quality Trends	   6-10
    Impact of Wastewater Treatment: Recreational and Living Resources Trends	   6-20
    Summary and Conclusions	   6-25
    References	   6-27

Chapter 7—Delaware Estuary Case Study	    7-1
    Physical Setting and Hydrology	    7-2
    Population, Water, and Land Use Trends	    7-4
    Historical Water Quality Issues	    7-6
    Legislative and Regulatory History	    7-7
    Impact of Wastewater Treatment: Pollutant Loading and Water Quality Trends	    7-8
    Evaluation of Water Quality Benefits Following Treatment Plant Upgrade	   7-13
    Impact of Wastewater Treatment: Recreational and Living Resources Trends	   7-17
    Summary and Conclusions	   7-21
    References	   7-23

Chapter 8—Potomac Estuary Case Study	    8-1
    Physical Setting and Hydrology	    8-3
    Population, Water, and Land Use Trends	    8-4
    Historical Water Quality Issues	    8-5
    Legislative & Regulatory History	    8-5
    Impact of Wastewater Treatment: Pollutant Loading and Water Quality Trends	    8-6
    Evaluation of Water Quality Benefits Following Treatment Plant Upgrades	    8-8
    Impact of Wastewater Treatment: Recreational and Living Resources Trends	   8-11
    Designated Uses & Bacterial Trends	   8-11
    Submerged Aquatic Vegetation, Fishery, and Waterfowl Resources	   8-12
    Trends In Suspended Solids Load and Water Clarity	   8-13
    SAV and Ecological Resources	   8-18
    Summary and Conclusions	   8-18
    References	   8-18

Chapter 9—James River Estuary Case  Study	    9-1
    Physical Setting and Hydrology	    9-1
    Population Trends	    9-3
    Historical Water Quality Issues	    9-5
    Legislative and Regulatory History	    9-5
    Impact of Wastewater Treatment: Pollutant Loading and Water Quality Trends	    9-6
    Evaluation of Water Quality Benefits Following Treatment Plant Upgrades	   9-11
    Impact of Wastewater Treatment: Recreational and Living Resources Trends	   9-13
    Summary and Conclusions	   9-14
    References	   9-15
                                                                                               VII

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Chapter 10—Upper Chattahoochee River Case Study	   10-1
    Physical Setting and Hydrology	   10-2
    Population, Water, and Land Use Trends	   10-4
    Historical Water Quality Issues	   10-6
    Legislative and Regulatory History	   10-7
    Impact of Wastewater Treatment: Pollutant Loading and Water Quality Trends	   10-9
    Impact of Wastewater Treatment: Recreational and Living Resources Trends	  10-12
    Summary and Conclusions	  10-13
    References	  10-14

Chapter 11—Ohio River Case Study	   11-1
    Physical Setting and Hydrology	   11-2
    Population, Water, and Land Use Trends	   11-4
    Historical Water Quality Issues	   11-5
    Legislative and Regulatory History	   11-5
    Impact of Wastewater Treatment: Pollutant Loading and Water Quality Trends	   11-7
    Impact of Wastewater Treatment: Recreational and Living Resources Trends	  11-10
    Summary and Conclusions	  11-12
    References	  11-12

Chapter 12—Upper Mississippi River Case Study	   12-1
    Physical Setting and Hydrology	   12-2
    Population, Water, and Land Use Trends	   12-5
    Historical Water Quality Issues	   12-6
    Legislative and Regulatory History	  12-10
    Impact of Wastewater Treatment: Pollutant Loading and Water Quality Trends	  12-12
    Evaluation of Water Quality Benefits Following Treatment Plant Upgrades	  12-20
    Impact of Wastewater Treatment: Recreational and Living Resources Trends	  12-23
    Summary and Conclusions	  12-26
    References	  12-29

Chapter 13—Willamette River Case Study	   13-1
    Physical Setting and Hydrology	   13-2
    Population, Water, and Land Use Trends	   13-4
    Historical Water Quality Issues	   13-5
    Legislative and Regulatory History	   13-6
    Impact of Wastewater Treatment: Pollutant Loading and Water Quality Trends	   13-7
    Impact of Wastewater Treatment: Recreational and Living Resources Trends	   13-9
    Summary and Conclusions	  13-11
    References	  13-11

Appendix A—Summary of Peer Review Team Comments and Study Authors' Responses
Appendix B—National Municipal Wastewater Inventory and Infrastructure, 1940 to 2016
Appendix C—National Public and Private Sector Investment in Water Pollution Control
Appendix D—Before and After CWA Changes in  10th Percentile Dissolved Oxygen and 90th Percentile
   BOD5 at the Catalog  Unit Level
Appendix E—Before and After  CWA Changes in  10th Percentile Dissolved Oxygen at the RF1 Reach Level

Glossary
VIII

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 Foreword
     This document was prepared under the sponsorship of several programs in the EPA Office of Water
primarily to document the water quality benefits associated with the more than 16,000 publicly owned
treatment works (POTWs) across the country. It emphasizes the role of the Construction Grants Program,
which provided $61.1 billion in federal grants to local authorities from 1972 through 1995 to help support
the planning, design, and construction of POTWs to meet the minimum treatment technology requirements
established by the secondary treatment regulations or water quality standards (where applicable). The
program has also provided more than $ 16 billion under the Clean Water State Revolving Fund (CWSRF)
Loan Programs as capitalization grants to the states since 1988 to support a wide range of water quality
improvement projects. The document was subjected to a formal peer review process that included detailed
reviews and input from NO AA, USGS, AMSA, NRDC, NRC/NAS, NWRI, University of North Caro-
lina, Johns Hopkins University, University of Alabama, states, consultants, local authorities, and others.
     The document contains an executive summary and 13 chapters, including a background chapter, and
chapters addressing BOD loadings before and after the Clean Water Act, the "worst case" dissolved
oxygen (DO) levels in waterways downstream of point sources before and after the CWA, and nine case
study assessments of water quality changes associated with POTW discharges.
     The report presents the results of a unique, three-way approach for addressing such frequently asked
questions as:
    1.   Has the CWA regulation of POTW discharges been a success?
    2.   How does the Nation's water quality before the 1972 FWPCA Amendments compare with the
        water quality conditions after secondary and better treatment was implemented?
    3.   Has the reduction of biochemical oxygen demand (BOD) loadings to surface waters from POTWs
        resulted in improved water quality in the Nation's waterways? If so, to what extent?
     By examining the numbers and characteristics of POTWs, their populations served, and BOD loadings
on a nationwide basis before and after the CWA, we were able to document changes in the number of
people served by POTWs and the level of treatment provided, the amount of BOD discharged to the
Nation's waterways, and the aggregate BOD removal efficiencies of the POTWs, while providing insight
into the likely impact of future discharges if treatment efficiencies aren't improved to accommodate eco-
nomic growth and expansions in service population.
    We examined the "worst case" historical DO levels in waterways located downstream of point sources
before and after the CWA in a systematic manner. By identifying water quality station records that related
to the water quality impact of point source discharges from the "noise" of millions of historical records
archived in STORET, and using DO as our indicator of water quality responses to long-term changes in
BOD loadings from POTWs, we evaluated changes in DO for only those stations on receiving waters
affected by point sources over time under comparable worst-case low-flow conditions (during July-Sep-
tember in 1961 -1965 for before CWA and 1986-1990 for after CWA) using only surface (within 2 meters
of the surface) DO data. We documented significant improvements in worst-case summer DO conditions at
three different spatial scales,  in two-thirds of the reaches, catalog units and major river basins.
                                                                                         IX

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     Case study assessments were also completed on nine urban waterways with historically documented
water pollution problems. These case study sites included the Connecticut River, Hudson-Raritan Estuary,
Delaware Estuary, Potomac Estuary, James Estuary, Chattahoochee River, Ohio River, Upper Mississippi
River, and Willamette River. Most of the these waterways were sites of interstate enforcement cases from
1957 to 1972, were listed as potential waterways for which state-federal enforcement conferences were
convened in 1963, or were the subjects of water quality evaluation reports prepared for the National
Commission on Water Quality. Two sites were on a 1970 list of the top 10 most polluted rivers. The case
study sites did not include, however, any of the 25 river reaches with the greatest before versus after CWA
improvements in DO found in our study. The case studies characterized long-term trends in population,
point source loadings, ambient water quality, environmental resources, and recreational uses. Validated
water quality models for the Delaware, Potomac, and James estuaries and the Upper Mississippi River
were used to quantify water quality improvements achieved by upgrading POTWs to secondary and higher
levels of treatment. The case study assessments document that tremendous progress has been made in
improving water quality, restoring valuable fisheries and other biological resources, and creating extensive
recreational opportunities (angling, hunting, boating, bird-watching, etc.) in all nine case study sites. At
many of the sites there have been significant increases in species diversity and abundance—returned or
enhanced populations of valuable gamefish (e.g., bass, bluegill, catfish, perch, crappies, sturgeon, etc.) and
migratory fish populations, waterfowl and fish-eating bird populations, opened shellfish beds and more.
Some of the sites have seen a return of abundant mayflies and other pollution-sensitive species, as well as
dramatic increases in recreational boating and fishing. Water quality improvements associated with BOD,
suspended solids, coliform bacteria, heavy metals, nutrients, and algal biomass have been linked to reduc-
tions in municipal and industrial point source loads for many of the case studies.
     The unique, three-way approach undertaken by this study quantitatively supports the hypothesis that
the 1972 CWA's regulation of wastewater treatment processes at POTWs has achieved significant suc-
cess—success in terms of reduction of effluent BOD from POTWs, worst-case (summertime, low-flow)
DO improvement in waterways, and overall water quality improvements in urban case study areas with
historically documented water pollution problems. However, the study also points out that without contin-
ued investments and improvements in our wastewater treatment infrastructure, future population growth will
erode away many of the CWA achievements in effluent loading reduction.
                                                 Robert K. Bastian
                                                 Senior Environmental Scientist
                                                 Office of Wastewater Management (4204)
                                                 U.S. Environmental Protection Agency
                                                 Washington, DC

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Acknowledgments
     Principal authors of the report include Andrew Stoddard of Andrew Stoddard & Associates and
Jon Harcum, James Pagenkopf, and Jonathan Simpson of Terra Tech, Inc. The authors gratefully acknowl-
edge the encouragement and support of our Project Officer, Robert K. Bastian, of EPA-OWM. The
authors also gratefully acknowledge the support of Karen Klima, Virginia Kibler, and Dr. Mahesh Podar
(EPA's Office of Water) who contributed to this research effort with their often challenging questions. This
project was funded under the following contracts with the U.S. Environmental Protection Agency: EPA-68-
C3-0303, EPA-68-C1-0008, and EPA Purchase Order No. 7W-0763-NASA.
     We gratefully acknowledge the efforts of Alexander Trounov of Terra Tech, Inc. for his expert assis-
tance in the extraction and processing of data from EPA's mainframe databases (STORET, Reach File
Version 1, Permit Compliance System, Clean Water Needs Survey) andUSGS streamflow databases.
Patrick Solomon of Terra Tech, Inc. is acknowledged for his expert assistance in transforming numerous
geographically-based data sets into maps that are works of art. Timothy Bondelid of Research Triangle
Institute is acknowledged for his invaluable contributions of point and nonpoint source loading data, includ-
ing the Reach File Version 1 transport routing database that was developed as part of RTFs National Water
Pollution Control Assessment Model (NWPCAM).  With a professional government career in water
pollution investigations that began during the early 1960s, our former colleague at Terra Tech, Inc., Phill
Taylor, is acknowledged for his invaluable insight stimulated by our frequent questions about historical data
archived in STORET. Phill's "corporate memory" and his personal library of reports documenting water
pollution conditions during the 1950s and 1960s were instrumental in the completion of this research effort.
     Several state and local agency officials reviewed the case study reports for accuracy and complete-
ness. The authors want to specifically acknowledge the invaluable contributions provided by Alan Stubin
and Tom Brosnan for the Hudson-Raritan estuary case study, Cathy Larson for the Upper Mississippi River
case study, Tyler Richards for the Chattahoochee River case study, Ed Santoro and Richard Albert for the
Delaware estuary case study, and Virginia Carter and Nancy Rybicki for the Potomac estuary case study.
The authors acknowledge the contributions of the late Ralph Sullivan in preparing material on the legislative
and regulatory history of the Federal Water Pollution Control Act. Jim Fitzpatrick (Hydro Qual, Inc.) and
Winston Lung (Enviro Tech, Inc.) are acknowledged for providing water quality model simulation results for
case studies of the Potomac, Delaware, and James estuaries and the Upper Mississippi River. The late Bob
Reimold and his colleagues at Metcalf & Eddy Engineers are acknowledged for their contributions to the
case study of the Connecticut River. The authors also wish to acknowledge the efforts of the Peer Review
Team, whose insight and often critical observations undoubtedly increased the value and credibility of the
study's results. The Peer Review Team includes:
          •  Mr. Leon Billings
          •  Mr. Tom Brosnan, National Oceanic and Atmospheric Administration
          •  Mr. Michael Cook, U.S. Environmental Protection Agency
          •  Mr. John Dunn, U.S. Environmental Protection Agency
          •  Dr. Mohammad Habibian, Washington Suburban Sanitation Commission
          •  Dr. Leo Hetling, Public Health and Environmental Engineering, New York State Department
             of Environmental Conservation (retired)
             Dr. Russell Isaacs, Massachusetts Department of Environmental Protection
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          •   Dr. Norbert Jaworski, U.S. Environmental Protection Agency (retired)
          •   Dr. William Jobin, Blue Nile Associates
          •   Mr. Ken Kirk, American Metropolitan Sewerage Association
          •   Mr. John Kosco, U.S. Environmental Protection Agency
          •   Mr. Rich Kuhlman, U.S. Environmental Protection Agency
          •   Mr. Joseph Lagnese
          •   Ms. Jessica Landman, Natural Resource Defense Council
          •   Mr. Kris Lindstrom, K.P. Lindstrom, Inc.
          •   Mr. Ronald Linsky, National Water Research Institute
          •   Dr. Berry Lyons, University of Alabama
          •   Dr. Alan Mearns, National Oceanic and Atmospheric Administration
          •   Dr. Daniel Okun, University of North Carolina
          •   Mr. Steve Parker, National Research Council
          •   Mr. Richard Smith, U.S. Geological Survey
          •   Mr. Phill Taylor, U.S. Environmental Protection Agency and Tetra Tech, Inc. (retired)
          •   Dr. Red Wolman, Johns Hopkins University
     The ad hoc case study peer reviewers include:
          •   Mr. Richard Albert, Delaware River Basin Commission
          •   Mr. Tom Brosnan, National Oceanic and Atmospheric Administration
          •   Dr. Virginia Carter, U. S. Geological Survey
          •   Ms. Linda Henning, St. Paul Metropolitan Council Environmental Services
          •   Ms. Cathy Larson, St. Paul Metropolitan Council Environmental Services
          •   Dr. Nancy Rybicki, U.S. Geological Survey
          •   Mr. Alan Stubin, New York City Department of Environmental Protection
          •   Mr. Ed Santoro, Delaware River Basin Commission
          •   Ms. Pat Stevens, Atlanta Regional Commission
          •   Mr. Peter Tennant, Ohio River Valley Sanitation Commission
     Finally, we recognize the cheerful cooperation and expert editing and graphic arts and document
production efforts of Marti Martin, Robert Johnson, Kelly Gathers, Krista Carlson, Emily Faalasli, Elizabeth
Kailey, Melissa DeSantis, and Debby Lewis of Terra Tech, Inc. in Fairfax, Virginia.
XII

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Acronyms
             7Q10
             AMSA
             ASIWPCA
             AWT
             BOD
             BOD5
             BODu
             C:DW
             CBOD
             CSO
             CTDEP
             cu
             CWA
             CWNS
             CWSRF
             DMR
             DO
             FR
             FWPCA
             FWQA
             FY
             GAO
             GICS
             gpcd
             HUC
             ICPRB
             IFD
             mgd
             MPN
             MSA
             mt/day
             MWCOG
             N
             NAS
             NBOD
             NCWQ
             NH3-N
             NO2-N
             NO3-N
             NOAA
             NPDES
             NPS
             NRC
10-year, 7-day minimum flow
American Metropolitan Sewerage Association
Association of State and Interstate Water Pollution Control Administration
Advanced wastewater treatment
Biochemical oxygen demand
5-day biochemical oxygen demand
Ultimate biochemical oxygen demand
Carbon-to-dry weight ratio
Carbonaceous biochemical oxygen demand
Combined sewer overflow
Connecticut Department of Environmental Protection
Catalog unit
Clean Water Act
Clean Water Needs Survey
Clean Water State Revolving Fund
Discharge monitoring report
Dissolved oxygen
Federal Register
Federal Water Pollution Control Act/Administration
Federal Water Quality Administration
Fiscal Year
General Accounting Office
Grants Information and Control System
gallons per capita per day
Hydrologic unit catalog
Interstate  Commission on Potomac River Basin
Industrial  Facilities Discharge File
Million gallons per day
Most probable number
Metropolitan Statistical Area
Metric tons per day (1,000 kg per day)
Metropolitan Washington Council of Governments
Nitrogen
National Academy of Sciences
Nitrogenous biochemical oxygen demand
National Commission on Water Quality
Ammonia nitrogen
Nitrite nitrogen
Nitrate nitrogen
National Oceanic and Atmospheric Administration
National Pollutant Discharge Elimination System
Nonpoint  source; also National Park Service
National Research Council
                                                                                        XIII

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              NRDC        Natural Resources Defense Council
              NURP        National Urban Runoff Project
              NWPCAM    National Water Pollution Control Assessment Model
              NWRI        National Water Research Institute
              O             Oxygen
              O&M         Operation and Maintenance
              ODEQ        Oregon Department of Environmental Quality
              OTA          Office of Technology Assessment
              OWM         EPA Office of Wastewater Management
              P             Phosphorus
              PCS          Permit Compliance System
              PE            Population equivalent
              PL            Public Law
              PO4-P         Phosphate phosphorus
              POC          Particulate organic carbon
              POM         Particulate organic matter
              POTW        Publicly  owned treatment works
              QA/QC       Quality assurance/quality control
              RF1           Reach File 1
              SAV          Submersed aquatic vegetation
              SIC           Standard Industrial Classification
              STORET      EPA's STORage and RETrieval database
              TKN          Total kj eldahl nitrogen
              TN           Total nitrogen
              TOC          Total Organic Carbon
              TP            Total phosphorus
              TPC          Typical Pollutant Concentration
              TSS           Total suspended solids
              USAC         U.S. Army Corps of Engineers
              USCB         U.S. Census Bureau
              USDA        U.S. Department of Agriculture
              USDOC       U.S. Department of Commerce
              USDOI       U.S. Department of Interior
              USEPA       U.S. Environmental Protection Agency
              USGS         U.S. Geological Survey
              USPHS       U.S. Public Health Service
              WEF          Water Environment Federation
              WIN          Water  Infrastructure Network
              WPCF        Water Pollution Control Federation
XIV

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Progress in Water Quality:
An Evaluation of the National Investment in Municipal Wastewater Treatment
Executive  Summary
       The  existence  of  serious  water
       pollution problems  in  the United
       States, first recognized during the 1920s
and 1930s and increasingly well  documented
during the 1940s through 1960s, led to the rec-
ognition that  the practice of discharging raw
sewage and the use of only primary treatment
in publicly owned treatment works (POTWs)
were generally inadequate technologies  for
wastewater disposal.
Excessive  loading of organic
matter, nutrients,  sediment,
pathogens, and other pollutants
into surface waters, combined
with natural hydrologic (low-
flow) conditions, frequently ac-
counted for incidences of dis-
solved oxygen (DO) depletion,
fish kills, nuisance algal blooms,
and bacterial contamination in
rivers, lakes, and  estuaries.
Many of the United States' most
famous water bodies, including
Lake Erie, New York Harbor,
and the Hudson, Upper Mississippi, Potomac,
Chattahoochee, Delaware,  and Ohio rivers fell
victim  to these symptoms.
In 1948 the 80th Congress encapsulated its frus-
tration with the situation when it declared that

   "... The pollution  of our  water resources by
   domestic and industrial wastes has become
   an increasingly serious problem for the rapid
   growth of our cities and  industries. ... Pol-
   luted waters menace the public health through
   the contamination of water and food sup-
   plies, destroy fish and game life, and rob us
   of other benefits of our natural resources."

          - Senate Report No. 462, 1948
 For the first half of
  the 20th century,
   pollution in the
   Nation's urban
waterways resulted in
frequent occurrences
   of low dissolved
  oxygen, fish kills,
    algal blooms,
    and bacterial
   contamination.
An Increased Federal
Policy Role in the Control
of Water Pollution

National policy for water pollution control has
been legislated primarily in the Federal Water
Pollution Control Act. First passed in 1948, the
act has been amended numerous times (in 1956,
1961,1965,1966,1970,1972,1977,1981 and
              1987) to gradually expand the
              authority of the federal govern-
              ment in regulating pollutant
              discharges from  point sources
              to surface waters. Until enact-
              ment of the 1972 (PL 92-500)
              and more recent amendments,
              now known as the Clean Wa-
              ter Act (CWA), the primary au-
              thority and responsibility for
              water pollution control was at
              the state level.
              Unfortunately, there was a great
              diversity among the states in
              terms of ability and willingness
to pay the costs of building and upgrading
POTWs and to enforce pollution control laws.
Lack of local water quality standards, monitor-
ing data, and penalties for violators exacerbated
the situation. Despite 49 joint state-federal en-
forcement conferences that were convened af-
ter the 1965 Amendments to abate critical water
pollution problems, national progress in  im-
proving water  quality was  hindered, in part,
because unless a state formally requested inter-
vention by the  federal government, federal au-
thority for regulating discharges was  restricted
to interstate and coastal  waters.

Public awareness of nationwide water pollution
problems served as a political catalyst to shift
increased authority and responsibility for  the
regulation of water pollution control from the
The 1972 CWA
shifted primary
 authority for
water pollution
 control from
  the states to
  the federal
 government.
                                                                                                   ES-1

-------
                          states to the federal government. Establishment
                          of a national policy requiring secondary treatment
                          of municipal wastewater as the minimum accept-
                          able technology supplemented by more stringent
                          water quality-based effluent controls on a site-spe-
                          cific, as-needed basis was a key provision of the
                          1972 act. This mandate, coupled with an in-
                          crease  in funding assistance to municipalities
                          through the Construction Grants Program, led
                          to a dramatic increase in the number of POTWs
                          with secondary and advanced treatment capa-
                          bilities. Congress assumed that these actions
                          would directly support the long-term goal of
                          the CWA, the national attainment of "fishable
                          and swimmable" waters.
Figure 1  -----	—--,—	-	--   - ..  . --
Annual funding provided by USEPA's Construction Grants
and CWSRF Programs to local municipalities for improve-
ments in water pollution control infrastructure from 1970 to
1999. Costs reported in current year dollars. (Data from
USER4 G/CS database and CWSRF Program.)
c:
.o
o
o
"c
0)
8

7-

6-

5-
     0
                                    Construction Grants
                                    CWSRF

                                  III
      1970     1975     1980     1985     1990     1995     2000
                                 Year
T/ie National Investment In
Municipal  Wastewater
Treatment

A total of $61.1 billion ($96.5 billion as con-
stant 1995 dollars) was distributed to munici-
palities through USEPA's Construction Grants
Program  in the 25-year period from 1970 to
1995 in support of the CWA's municipal waste-
water treatment program (Figure 1). An addi-
tional $16.1 billion (capitalization) was also dis-
tributed to the states through the Clean Water
State Revolving Fund (CWSRF) Program from
1988 through 1999. Including the state contri-
butions and loan repayments, the CWSRF loan
program assets have grown to over $30 billion
since 1988 and are funding about $3 billion in
water quality projects each year.
In terms  of promoting the  minimum accept-
able technology-based standard of secondary
treatment nationwide, this investment was an
outstanding success. By 1996 the number of
POTWs offering less than secondary treatment
dwindled to less than 200 (down from 2,435 in
1968 and 4,278  in  1978). Correspondingly,
there was a dramatic increase in the number of
facilities offering secondary treatment or greater
(from 10,052 facilities in 1968 to 13,816 facili-
ties in 1996).

       In 1968, 72 percent of the
     Nation's POTWs were providing
   secondary treatment and less than
    1  percent were providing greater
    than secondary treatment (out of
     14,051 facilities). By 1996, 59
   percent of the Nation's POTWs were
   providing secondary treatment and
    27 percent were providing greater
    than secondary treatment (out of
           16,024 facilities).
ES-2
                                                                                                Executive Summary

-------
The success of these national investments is also
demonstrated by the increase in the number of
people served by POTWs, which shifted dra-
matically between 1968 (before-CWA) and
1996 (after-CWA), as shown in Figure 2. The
story told in Figure 2 is summarized below.

   •   The overall number of people served by
      POTWs increased from 140.1 million in
      1968 to 189.7million in 1996(a 35
      percent increase).
   •   The number of people relying on POTWs
      with less than secondary treatment
      dropped rapidly after passage of the 1972
      CWA. In  1968 about 39 percent (54.2
      million) of the 140.1 million people
      served by POTWs received less than
      secondary treatment (raw and primary).
      By 1996 this percentage was reduced to
      about 9 percent (17.2 million) of the
      189.7 million people served by POTWs.
      This 9 percent includes approximately
      5.1 million people currently served by
      POTWs with CWA Section 301(h)
      waivers allowing the discharge of less
      than secondary treated effluent to deep,
      well-mixed ocean waters.
   •   While the number of people served by
      POTWs with secondary treatment
      remained fairly constant between 1968
      and 1996 (a slight decrease of 3.7
      million people or about 4 percent of the
      population), the number of people
      provided with greater than secondary
      treatment increased significantly (from
      0.3 million people in 1968 to 82.9
      million people in 1996). Stated another
      way, the U.S. population served by
      POTWs with secondary or greater
      treatment almost doubled between 1968
      and 1996from 85.9 million people in
      1968 to 164.8 million people in 1996!
                   .„„,.„„ „__„„„,^__,™~,	„.,.„,—	  Figure 2
                        Population served by  POTWs in 1968 (before th<
                    CWA) and in 1996 (after the CWA) by treatment type
                         (Data from U.S. Public Health Service municipa
                       wastewater inventories; USEPA Clean Water Need;
                                Surveys; USDOI, 1970; USEPA, 1997.
Raw1 • < Secondary   D Secondary   D > Secondary   i_' No Discharge

     200n
 •$.  180-
 .§  160-
 J.  140-
 "g  120-
 o>  100
      80-
      60-
      40-
      20-
       0-
o
I
Q.
O
Q.
           Before the CWA (1968)
                                      After the CWA (1996)
 Raw discharges were eliminated by 1996.
 Data for the "no-discharge" category were unavailable for 1968.
Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
                                                             ES-3

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                         Was the Public's Investment In POTWs Worth It?
                         Questions concerning the environmental ben-
                         efits, as well as the cost-effectiveness, of the na-
                         tional investment in municipal wastewater treat-
                         ment have been raised by Congress and by spe-
                         cial interest, environmental, and business ad-
                         vocacy groups. In the 25 years after the enact-
                         ment of the CWA, studies have attempted  to
                         evaluate progress in achieving the goals of the
                         CWA by documenting  (a)  administrative ac-
                         tions (e.g., numbers  of discharge permits and
                         enforcement actions) and programmatic evalu-
                         ations (see Adler et al., 1993); (b) trends  in na-
                         tional wastewater infrastructure (e.g., popula-
                         tion served by secondary or greater treatment
                         levels, effluent loading rates); (c) state and na-
                         tional inventories of waterways meeting  desig-
                         nated uses (e.g., 305(b) reports); and (d) changes
                         in water quality following wastewater treatment
                         plant upgrades for specific waterways.
            Evaluations of water quality conditions in the
            United States include a pre-CWA national water
            quality analysis of conditions from the 1940s
            through the 1960s (Wolman, 1971; USEPA,
            1974) and post-CWA assessments of the national
            effectiveness of the 1972 CWA (e.g., Smith et
            al., 1987a, 1987b). Assessments of local (Isaac,
            1991; GAO, 1986), regional (Patricketal., 1992),
            and national water quality conditions (Smith et
            al., 1992) have demonstrated improvements in
            some water quality constituents following up-
            grades to secondary or greater levels of wastewa-
            ter treatment at municipal facilities.
            There is, however, no study that has attempted
            a national-scale comprehensive evaluation of the
            effectiveness of the CWA's technology- and wa-
            ter quality-based effluent control policies in
            achieving the "fishable and swimmable" goals
            of the act (Mearns, 1995).
                         STUDY OVERVIEW:  The "Three-Legged Stool" Approach
                         This  study  takes a unique,
                         three-pronged approach for an-
                         swering the prima facie ques-
                         tion—Has the Clean Water Act's
                         regulation of wastewater treat-
                         ment processes at POTWs been
                         a success? Or posed more di-
                         rectly, How  have the Nation's
                         water quality conditions changed
                         since  implementation of the
                         1972 CWA's mandate for sec-
                         ondary treatment as the mini-
                         mum  acceptable technology for
                         POTWs?
  This study takes a
unique three-pronged
approach to evaluate
 nationwide progress
   in water quality
  conditions since
  the enactment of
   the 1972 CWA.
The three-pronged  approach
described below (and presented
in the companion document,
USEPA, 2000) was developed
so that each study phase could
provide cumulative support
regarding the success, or failure,
of the CWA-mandated POTW
upgrades to secondary  and
greater than secondary treat-
ment. Using the analogy  of a
three-legged stool,  the study
authors  believed that each leg
must contribute support to the
premise of CWA success. If one
or more legs fail in this objec-
tive, the stool will be unable to
"stand up."
ES-4
                                       Executive Summary

-------
The  First  Leg:  An
examination of BOD
loadings before and
after the  CWA

As increasing numbers of people hooked into
more and upgraded POTWs, there was a corre-
sponding rise in influent BOD1 loading nation-
wide to these facilities. Figure  3 presents the
amount of influent BOD loading to "less than
secondary," secondary, and "greater than second-
ary" facilities for 1968 and 1996 (years repre-
senting before and after  the  CWA). BOD
loadings are shown both as BOD5 (carbona-
ceous BOD, i.e., oxygen demand from  the de-
composition of organic carbon) as well as BODU
(ultimate BOD, which includes nitrogenous
BOD,  i.e., oxygen demand from the decom-
position of ammonia and organic nitrogen, in
addition to carbonaceous BOD).

As shown, total influent loading of BOD in-
creased by about 35 percent, from 18,814 to
25,476 metric tons per day. Similarly, total in-
fluent loading of BODy increased by about 35
percent, from 34,693 to 46,979 metric tons per
day. Fortunately, this situation was counteracted
by the  CWA wastewater treatment mandates,
which resulted in rising BOD removal efficien-
cies (Figure 3).

In 1968 the national aggregate removal efficien-
cies stood at about 63 percent and 39 percent for
BOD5andBODu, respectively. By 1996national
aggregate removal efficiencies had risen to nearly
85 percent and 65 percent, respectively!
  BOD, or" biochemical oxygen demand" is a
  measure of the oxygen-consuming organic
  matter and ammonia-nitrogen in wastewater.
  The higher the BOD loading, the greater the
  depletion of oxygen in the waterway.
                        	 - 	  -- -—	~		.—  Figure ;
                       Influent and effluent loading of BOD to and from POTW
                       in 1968 (before the CWA) and in 1996 (after the CWA
                            by treatment type and associated BOD aggregati
                          removal efficiencies. (Data from U.S. Public Healtl
                       Service municipal wastewater inventories; USEPA Cleai
                         Water Needs Surveys; USDOI, 1970; USEPA, 1997.
                   I < Secondary  D Secondary  LJ > Secondary
   I
   O)
   c
   Q
   O
   m
          XX
            Before the     After the
           CWA (1968)    CWA (1996)
Before the
CWA (1968)
 After the
CWA (1996)
Consequently, the net result was decreasing lev-
els of effluent BOD loading to the Nation's wa-
terways (Figure 3). In 1968 the total effluent
loadings for BOD5 and BODU stood at about
6,932 and 21,281 metric tons per day, respec-
tively. By 1996 these amounts had dropped to
3,812 metric tons per day for BOD5 (a 45 per-
cent decline)  and 16,325 metric tons per day
for BODy (a 23 percent decline), despite a cor-
responding 35 percent increase in influent BOD
loadings! Since many POTWs operate at  even
higher BOD removal efficiencies, these design-
based effluent load reductions are understated,
compared to actual data reported in the Permit
Compliance System (PCS),  which may  vary
somewhat from year to year.
Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
                                                                ES-;

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Figure 4
Projections of design-based, national effluent BODU loadings
through 2025 using middle-level U.S. population projections.
(Population projection data from U.S. Census, 1996.)
Assumptions:
  Influent flow is a constant 165 gallon/capita-day1 with a BODU of 396.5 mg/L
Projection Results:
Population served (millions)
Percent of total population
Design removal efficiency (BODJ
Effluent BOD,, (metric tons/day)
                             1968   1972   1978   1996  2016   2025
           140.1
            71%
            39%
141.7
 69%
 41%
155.2
 70%
 52%
189.7
 72%
 65%
                                                         275.0  295.0
                                        71%
                                               71%
          21,280 20,831  19,147  16,325  19,606 21,090
    80,000
    70,000 -
  Influent BODu
  Effluent BODu
Q Removal Efficiency
          1940 1950 1962 1968 1972 1978 1982 1988 1992 1996
                                   Year
                                                         2016 2025
1 165 gal/capita-day is based on the mean of population served and wastewater flow
  data in the Clean Water Needs Surveys for 1978 through 1986 and accounts for
  residential, commercial, industrial, stormwater, and infiltration and inflow compo-
  nents.
                                                                             be similar to loading
                                                                             rates experienced in
                                                                            the mid-1970s, only a
                                                                             few years after the
                                                                                    CWA!
                   Based on middle-level
                        population
                    projections, effluent
                       loading rates of
                   BOD v in 2016 would
The  dynamic
relationship be-
tween influent
BOD loading,
BOD design re-
moval efficien-
cy, and effluent
BOD loading creates an important model for
planning new investments in wastewater treat-
ment infrastructure (Figure 4). Based on the data
reported in the 1996 Clean Water Needs Sur-
vey Report to Congress (USEPA, 1997), the
overall design BOD removal efficiency is likely
to increase somewhat because there is an appar-
ent trend toward a  higher  proportion of ad-
vanced (greater than secondary) POTWs. In the
next 20 years, however, the proportion of the
U.S. population served by POTWs is also likely
to increase as the urban population of the na-
tion increases.

Using the assumptions listed in Figure 4, and
using middle-level population growth projec-
tions from  the Census Bureau (U.S. Census,
1996), it was estimated that by 2016 nearly 275
million people will be served by POTWs that
discharge to surface waters. Assuming a 165 gal/
capita-day influent flow and 396.5 mg/L con-
centration of influent BODjj, this growth
(1996-2016) would result in a 45 percent in-
crease in influent BODy loading  to POTWs
(68,030 metric tons per day) and a 20 percent
increase in effluent  BODy loading to surface
waters (19,606 metric tons per day). These pro-
jected 2016 effluent BOD[J loadings are similar
to levels that existed in the mid-1970s, only a few
years after the CWA! Projecting further into the
future, effluent BOD^, loadings in 2025 (21,090
metric tons per day) would be similar to load-
ing rates experienced in 1968 (21,280 metric
tons per day), when they had reached a historic
maximum level!
ES-6
                                                                                      Executive Summary

-------
These types of projections underscore the im-
portance of the need to continually invest in
improvements to wastewater treatment infra-
structure in order to maintain and improve pol-
lutant removal efficiencies. Without these im-
provements, many of today's achievements in wa-
ter pollution control will be overwhelmed by
tomorrow's demand from urban population
growth. A recent report by the Water Infrastruc-
ture Network (WIN, 2000) also documents the
risk of reversing the environmental gains of the
last three decades.

Although POTWs are often  the dominant
source of BOD effluent loading in major urban
areas, other sources affect waterways on a na-
tional scale. To put POTW effluent loading in
perspective, USEPA's National Water Pollution
Control Assessment Model (NWPCAM) and
input data from  USEPA's Permit Compliance
System (PCS) and the Clean Water Needs Sur-
vey (CWNS) were used to examine current
BOD5 loading (ca. 1995) for several key point
and nonpoint sources (Bondelid et al., 1999).

From a national perspective, it was found that
currently (ca. 1995) POTW BOD5 loadings ac-
count for only about 38 percent of total point
source loadings and  only 21 percent of total
loadings  (point and nonpoint). Industrial fa-
cilities (major and minor) currently account for
about 62 percent of total point source BOD?
loadings  and 34  percent of total BOD5 load-
ings.  Clearly, continued improvement in the
water quality conditions of the Nation's water-
ways will require an integrated strategy to ad-
dress all pollutant sources, including both point
and nonpoint sources.

The first leg of the three-legged stool approach
focused on the Nation's investment in building
and upgrading POTWs to achieve at least sec-
ondary treatment. Based on this historical BOD
                   .,  .- - ,,„ —	 „	-,_——„-,„,„,,—,	  Figure !
                   Percent changes in population served, influent BOD loading
                      and effluent BOD5 and BODL loading before and after thi
                    1972 CWA (1968 to 1996). (Data from U.S. Public Hea/ti
                       Service municipal wastewater inventories; USEPA Cleat
                         Water Needs Surveys; USDOI, 1970; USEPA, 1997.
        50-r-
   I
   o
   i
    c
    co
    o>
    
    c
    CO
    .c
    O
    c
    0)
    0)
    Q.
 25	
-25--
       -50
              Population -
                Served
                 35%
                      Influent
                       Load
                        35%
                       BOD5
                       and
                       BODy
Effluent
 Load
  -45%
Effluent
 Load
  -23%
                                     BODS
loading analysis, it is clear that the CWA's
mandate for secondary treatment as the
minimum acceptable treatment technol-
ogy, supplemented by more stringent wa-
ter quality-based effluent controls on a site-
specific basis, combined with financial as-
sistance from the Construction Grants and
CWSRF Programs, resulted in a dramatic
nationwide decrease in effluent loading of
BOD from POTWs into the Nation's wa-
terways (see Figure 5).

The 45 percent nationwide reduction in
effluent BOD? loading and the 23 percent
reduction in effluent BODU loading was
achieved during a period when total popu-
lation served and influent loading of BOD
both increased by 35 percent!
                                        Conclusion
                                      of the first leg
                                        of the stool
                                    There was a dramatic
                                   nationwide decrease in
                                    BOD effluent loading
                                    from POTWs after the
                                     1972 CWA despite a
                                    significant increase in
                                     population served!
Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
                                                                ES-7

-------
    A systematic, peer-
  reviewed approach was
developed to identify water
quality station records that
encode the "signal" related
    to the water quality
  impact of point source
discharges from the "noise"
  of millions of historical
    records archived in
        STORET.
The Second Leg:  An
examination of "worst-
case" DO in waterways
below point sources before
and after the  CWA

The second leg follows up on the first leg with
the question Has the CWA'spush to reduce BOD
loading resulted in improved water quality in the
Nations waterways? And,  if so,  to what extent?
The key phrase in the question is "to what ex-
tent?"  Earlier studies by Smith et al. (1987a,
1987b) and Knopman and Smith (1993) con-
clude that any improvements in DO conditions
in the Nation's waterways are detectable only
within relatively local spatial scales downstream
of wastewater discharges.
Because of the ecological significance of DO and
its well-known causal relationship with the de-
        composition of organic carbon (car-
        bonaceous BOD)  and the decompo-
        sition of organic nitrogen and ammo-
        nia (nitrogenous BOD) from  waste-
        water discharges, historical DO
        records provide an  excellent environ-
        mental  indicator  for characterizing
        water quality responses to long-term
        changes in wastewater loading. A con-
        siderable amount of historical  data is
        archived, and readily accessible, in
        STORET, USEPA's  national water
        quality database.
         The inherent difficulty in evaluating
         the effectiveness of reductions in point
         source loading is  the need to  isolate
the water quality impact of discharges from the
impacts caused by other confounding factors
such as nonpoint sources, as well as the natural
influence of streamfiow and water temperature.
In this assessment, a systematic, peer-reviewed
approach has been designed to identity water
quality station records that encode the "signal"
related to the water quality impact of point
source discharges  from the overwhelming
"noise" of millions of historical records archived
in STORET.

With DO as the key water quality indicator, and
keeping in mind the need to evaluate the change
in the DO "signal" over time (before and after
CWA) as well as over different spatial scales (i.e.,
river reaches [which average 10 miles in length],
catalog units, and major river basins), the fol-
lowing "rules" for data analysis were used in a
six-step data mining process to create before -
and after-CWA data sets of "worst case" DO to
be used in an unbiased comparison analysis of
downstream  water quality conditions. The
screening rules associated with each phase are
listed below:

Step 1—Data Selection Rules
  •  DO data were extracted only for
     summer (July-September).
  •  Only surface DO data (within 2 meters
     of the surface) were used.
Step 2—Data Aggregation Rules From a
Temporal Perspective
  •  1961-1965 served as the "time-block" to
     represent persistent dry weather before
     the CWA, and 1986-1990 served as the
     time-block to represent persistent dry
     weather after the CWA. These time-
     blocks were selected based on an
     analysis of long-term mean summer
     streamfiow.
  •  DO data must come from a station in a
     catalog unit that had at least 1 dry year
     out of the 5 years in each before- and
     after-CWA time-block.
   ES-8
                                                                       Executive Summary

-------
Step 3—Calculation of the Worst-case
DO Summary Statistic Rules
   *   For each water quality station, the 1 Oth
      percentile of the DO data distribution
      from the before-CWA time period (July
      through September, 1961-1965) and the
      1 Oth percentile of the DO data distribu-
      tion from the after-CWA time period
      (July through September, 1986-1990)
      were used as the DO "worst-case"
      statistic for the comparison analysis.
   •   A station must have a minimum of
      eight DO measurements within each of
      the 5-year time-blocks.
Step 4—Spatial Assessment Rules
   *   Only water quality stations on streams
      and rivers affected by point sources were
      included in the before- and after-CWA
      comparison analysis. Stations affected
      only by nonpoint sources were ex-
      cluded. Out of 64,902 river reaches in
      the contiguous United States, 12,476
      are downstream of a point source. Also,
      out of 2,111 catalog units, 1,666 have
      river reaches that are downstream of a
      point source.
Step 5—Data Aggregation Rules From  a
Spatial Perspective
   •   For each data set and time-block, the
      1 Oth percentile value from each eligible
      station was  aggregated within the spatial
      hydrologic unit. (Since the scales are
      hierarchical, a station's summary
      statistic was effectively assigned to a
      reach and a catalog unit.) A summary
      statistic was then calculated and as-
      signed to the spatial unit for the
      purpose of characterizing its worst-case
      DO. If a spatial unit had only one
      monitoring station within its borders
      meeting the screening criteria, the 10th
      percentile DO value from that station
      simply served as the unit's worst-case
      summary statistic. If, however, there
      were two or more stations within a
      spatial unit's borders, the 10th percen-
      tile values for all the eligible stations
      were averaged, and this value used to
      characterize worst-case DO for the unit.

Step 6—Development of the Paired
Data Sets  (at each spatial scale)
  •   To be eligible for the paired (before vs.
      after) comparison analysis, a hydrologic
      unit must have both a before-CWA and
      an after-CWA summary statistic
      assigned to it.

The comparative before- and after-CWA analy-
sis of worst-case DO data derived using the
screening criteria described above and aggregated
by three scales of spatial hydrologic units (reach,
catalog unit, and major river basin) yielded the
following results.
                                  Only water quality
                                  stations on streams
                                and rivers affected by
                                  point sources were
                                included in the before-
                                   and after-CWA
                                 comparison analysis.
Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
                                                                  ES-S

-------
                   Reach Scale Analysis
                      •   69 percent of the reaches evaluated showed
                         improvements in worst-case DO after the
                         CWA (311 reaches [out of a possible
                         12,476 downstream of point sources]
                         survived the data screening process with
                         comparable before- and after-CWA DO
                         summary statistics. The number of
                         reaches available for the paired analysis
                         was limited by the historical data
                         archived for the 1961-1965 period).
                      •   These 311 evaluated reaches represent
                         a disproportionately high amount of
                         urban/industrial population centers,
                         with approximately 13.7 million
                         people represented (7.2 percent of the
                         total population served by POTWs in
                         1996). As shown in Figure 6, the top 25
                         improving reaches  saw their worst-case
                         DO concentrations increase by 4.1 to
                         7.2 mg/L!
The number of evaluated reaches
characterized by worst-case DO below
5 mg/L was reduced from 167 to 97
(from 54 to 31 percent).
The number of evaluated reaches
characterized by worst-case DO above
5 rng/L increased from 144 to 214
(from 46 to 69 percent).
      Key finding at the
        reach scale: 69
     percent of the paired
        reaches showed
        worst-case DO
      improvements after
          the CWA!
ES-10
                       Executive Summary

-------
i
f
 a'
                                                          Before the CWA


                                                          After the CWA
              0.0
                   12345678  910111213141516171819202122232425



                                     River Reach Ranking
                                                                      M
 rn
 c/i
         Figure 6


         Location map and distribution chart of the 25 RFl reaches identified with greatest after-CWA improvements in

         10th percentlle DO, 1961-1965 vs. 1986-1990. Reaches are ranked by greatest before- and after-CWA improvements.

-------
   Key finding at the
  catalog unit scale: 68
  percent of the paired
  catalog units showed
     worst-case DO
   improvements after
       the CWA!
               Catalog Unit Scale Analysis
                  •   68 percent of the catalog units evaluated
                     showed improvements in worst-case DO
                     after the CWA (246 catalog units [out of
                     a possible 1,666 downstream of point
                     sources] survived the data screening
                     process with comparable before- and
                     after-CWA DO summary statistics).
                  •   The number of evaluated catalog units
                     characterized by worst-case DO below
                     5 mg/L was reduced from 115 to 65
                     (from 47 to 26 percent). The number of
                     evaluated catalog units characterized by
                     worst-case DO above 5 mg/L increased
                     from 131  to 181 (from 53  to 74 per-
                     cent).
                 As shown in Figure 7, 53 of the 167
                 improving catalog units (32 percent)
                 improved by 2 mg/L or more while only
                 10 of 79 degrading catalog units (13
                 percent) degraded by 2 mg/L or more.
                 These 246 evaluated catalog units
                 represent a disproportionately high
                 amount of urban/industrial population
                 centers  (see Figure 8), with approxi-
                 mately 61.6  million people represented
                 (32.5 percent of the total population
                 served by POTWs in 1996).
Figure 7  	-	-.—,..„	,		,			.,	
Frequency distribution of the mean 10th percentlle DO for 246 catalog units that
improved (n = 167) and degraded (n = 79) after the CWA. (Source: USEPA STORET.)
  O)
  o
  re
  <->
  to
  O
  c
  Q.
  O
  O)
  (0
  4->
  0)
  2
  V
  0.
             (n) = number of catalog units
7 to 8 6 to 7  5 to 6  4 to 5 3 to 4  2 to 3  1to2  Oto1
                               (a)
                    Magnitude of Decrease in
              Worst-Case DO (mg/L) after the CWA
Oto1  1to2  2to3  3to4 4to5  5to6  6to7 7to8
                                                                 (b)
                                                       Magnitude of Increase in
                                                Worst-Case DO (mg/L) after the CWA
ES-12
                                                                                        Executive Summary

-------
I
a
                                                                     Before the CWA
                                                                     After the CWA
                                              34567
                                                  Catalog Unit Ranking
Catalog units with improved 10th percentile DO
Catalog units with degraded 10th percentile DO
               Figure 8
               Location map of the 246 catalog units that improved or degraded in terms of 10th percentile DO after the CWA, 1961-1965 vs. 1986-
               1990. The 10 catalog units with the greatest after-CWA improvements are highlighted and presented in a distribution chart.
               (Source: USEPA STORET.)

-------
                           Major River Basin Scale Analysis
                              •   A total of 11 out of 18 major river
                                 basins had sufficient reach-aggregated
                                 worst-case DO data for a before- and
                                 after-CWA comparison.
                              •   Based on two statistical tests, 8 of these 11
                                 major river basins can be characterized as
                                 having statistically significant improve-
                                 ment in worst-case DO Levels after the
                                 CWA! The three basins that did not
                                 statistically improve under either test
                                 also did not have statistically significant
                                 degradation (Table 1).
When all the 311 paired (i.e., before vs.
after) reaches were aggregated and the
statistical tests run on the contiguous
states as a national whole, worst-case
DO also showed significant improve-
ment.
       Key finding at the
    hydrologic region scale:
    8 of the 11 major river
   basins with sufficient data
   had statistically significant
   improvement in worst-case
   DO levels after the CWA!
Table 1: Statistical Significance of Trends in Mean 10th Percentile (Worst-Case)
Before vs. After the CWA (1961-1965 vs. 1986-1990)



River Basin
All USA (01-18)
01 - New England Basin
02 - Middle Atlantic Basin
03 - South Atlantic-Gulf
04 - Great Lakes Basin
05 - Ohio River Basin
06 - Tennessee River Basin
07 - Upper Mississippi Basin
08 - Lower Mississippi Basin
09 - Souris-Red Rainy Basin
10 - Missouri River Basin
11 - Arkansas-Red — White Basin
12 - Texas-Gulf Basin
13 - Rio Grande Basin
14 - Upper Colorado River Basin
15 - Lower Colorado River Basin
16 - Great Basin
17 - Pacific Northwest Basin
18 - California Basin
Paired t-test: 95% confidence - 2-sidec
Insufficient data for analysis


No. of Paired
(before vs. after)
Reaches
311
1
17
61
26
66
19
48
25
2
10
7
2
0
1
0
2
17
7
. (Source:


Paired
t-test
Yes
*
Yes
Yes
Yes
Yes
Yes
Yes
No
*
No
No
*
*
*
*
*
Yes
Yes
USEPA STOREI)

Kolmogorov
Smirnov
test
Yes
*
Yes
Yes
Yes
Yes
No
Yes
No
*
No
No
*
*
*
*
*
No
Yes
test. Kolmogorov Smirnov test: 90% confidence, 2-sided






DO by Major River Basin

Worst-
Case DO
(mg/L)
1961-65
4.56
4.30
2.80
4.10
3.85
5.40
4.08
3.80
3.79
5.65
5.76
5.36
5.77
-
4.88
-
7.45
7.61
5.61
test



Worst-
Case DO
(mg/L)
1986-90
5.53
6.90
4.94
4.73
6.06
6.04
5.23
5.31
3.94
6.75
6.53
4.60
4.37
-
7.22
--
6.10
8.21
7.58



ES-14
                                                                                                      Executive Summary

-------
The second leg of the three-legged stool ap-
proach focused on assessing the change in the
point source discharge/downstream worst-case
DO signal over progressively larger spatial scales.
The results of this analysis show that there were
significant after-CWA improvements in worst-
case summer DO conditions in  two-thirds  of
the hydrologic units at all three spatial data ag-
gregation scales, from the small subwatersheds
of Reach File Version 1 river reaches (mean
drainage area of 115 mi2) to the very large wa-
tersheds of major river basins (mean area  of
434,759 mi2).

These results provide strong evidence that the
CWA's requirements for municipal wastewater
treatment using secondary treatment as the
minimum acceptable technology, supplemented
by more stringent water quality-based effluent
controls on a site-specific basis, yielded broad
as well as localized benefits!
            Conclusion of
           the second leg
             of the stool
          There were significant
        after-CWA improvements
        in worst-case summer DO
         conditions in two-thirds
        of the hydrologic units at
         all three spatial scales!
The Third Leg:  Case
Study Assessments of
Water  Quality

The national-scale evaluation of long-term
trends in water quality conditions associated
with the second leg of the three-legged stool
identified numerous waterways characterized
by substantial improvements in DO after the
CWA. The uniqueness of each waterway and
the activities surrounding it requires an inves-
tigation to go beyond STORET to identify,
quantify, and document in detail the specific
actions that have resulted in water quality im-
provements and associated  benefits to water
resource users.

Nine urban waterways were selected for closer
examination of the factors that caused improve-
ment in local water quality and environmental
resources (Figure 9).  Note that the case study
site selection was made prior to completion of
the DO trend analysis described in the second
study leg.

Most of the case study waterways were  sites
of interstate enforcement cases from  1957 to
1972, were listed as potential waterways to con-
vene state-federal enforcement conferences in
1963, or were subjects of water quality evalua-
tion reports prepared for the National Com-
mission on Water Quality. Two sites (Ohio
River and tributaries to the Hudson-Raritan
estuary) were on a 1970 list of the top  10 most
polluted rivers. Yet,  interestingly, these  case
study waterways included none of the 25 river
reaches with the greatest before- versus after-
CWA improvements in DO found in the sec-
ond leg  of this study (see Figure 6).

These case study waterways represent heavily ur-
banized areas with historically documented wa-
ter pollution problems. A variety of data sources,
including the  scientific literature, USEPA's na-
Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment

-------
Figure 9 —- -	-			
Location map of case study waterways and distribution chart of their before- and after-CWA mean 10th
percentile DO for case study RF1 reaches: 1961-1970 vs. 1986-1995. (Source: USEPA STORET.)
                                                                                  2. Hudson-Rantan
                                                                                    estuary
                                                               3. Delaware estuary
                                                                                        1. Connecticut River
             9. Willamette River
                                                               4. Potomac estuary
                                     8. Upper Mississippi River
                                                                                     6. Chattahoochee River
                                           Before the CWA
                                           After the CWA
                   234567
                      Case Study Waterway Number
                            tional water quality database, and federal, state,
                            and local agency reports, were used to character-
                            ize long-term trends in population, point source
                            effluent loading rates, ambient water quality, en-
                            vironmental resources, and recreational uses. Ad-
                            ditional information was obtained from validated
water quality models for the Delaware, Potomac,
and James estuaries and Upper Mississippi River
case studies to quantify the water quality improve-
ments achieved by upgrading municipal facili-
ties to secondary and greater levels of treatment
as mandated by the 1972 CWA.
ES-16
                             Executive Summary

-------
Key findings from the nine case studies are high-
lighted below.

   •   In each of the case study urban areas,
      significant investments were made in
      expansions and upgrades to POTWs
      with commensurate increases in popula-
      tion served.
   •   Before the CWA, during the 10-year
      period from  1961 to 1970, "worst-case"
      DO levels fell in the range of 1 to
      4 mg/L for most of the case study sites;
      after the CWA, during the 10-year
      period from  1986 to 1995, worst-case
      DO levels improved to levels of almost
      5 to 8 mg/L.
   •   Water quality improvements associated
      with BOD5,  suspended solids, coliform
      bacteria, heavy metals, nutrients, and
      algal biomass have been linked to
      reductions in municipal and industrial
      point source loads for many of the case
      study waterways.
   •   Tremendous progress has been made in
      improving water quality, restoring
      valuable fisheries and other biological
      resources, and creating extensive water-
      based recreational opportunities (an-
      gling, hunting, boating, bird-watching,
      etc.) in all case study waterways.
The results of the third leg of the three-legged
stool approach revealed that  the significant in-
vestments made in municipal wastewater treat-
ment  resulted in dramatic improvements in re-
storing water quality and biological resources and
in supporting thriving water-based recreational
uses in all the case study areas.

Although significant progress has been achieved
in eliminating noxious water pollution condi-
tions,  remaining problems with nutrient enrich-
ment, sediment contamination, heavy metals,
and toxic organic chemicals continue to pose
threats to human health and aquatic organisms
for these case study waterways. Serious ecologi-
cal problems remain to be solved for many of the
Nation's waterways, including the sites of these
case studies.
             Conclusion of
              the third leg
              of the stool
           Tremendous progress
           has been achieved in
          improving water quality,
            restoring valuable
           biological resources,
            and creating recre-
          ational opportunities  in
         all the case study areas!
Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
                                                                ES-17

-------
                         Conclusion
                         The three-legged stool approach to answering
                         the question Has the Clean Water Act's regula-
                         tion ofwastewater treatment processes at POTWs
                         been a success? was developed
                         so that each of the legs could
                         provide cumulative support
                         regarding the success or fail-
                         ure of the CWA-mandated
                         POTW upgrades to at least
                         secondary treatment. Exam-
                         ining the results of each of
                         the study legs, the conclu-
                         sion is overwhelming that
                         the stool does indeed "stand
                         up"!
                    Conclusion of
                  the three-legged
                   stool approach
                         At  both broad and local
                         scales, the water pollution
                         control policy decisions
                         of  the  1972  CWA have
                         achieved significant suc-
                         cesses nationwide in terms
                         of  reduction  of effluent
                         BOD  from  POTWs,
                         worst-case (summertime,
                         low-flow)  DO improve-
                         ment in waterways, and overall water quality
                         improvements in urban case study areas.
                  Each leg of the stool
               cumulatively and quantita-
                tively supports the theory
              that the 1972 CWA's regula-
                tion of wastewater treat-
               ment processes at POTWs
                 has been a significant
                        success!
long-term trends in signals for water quality
parameters other than DO  (e.g., suspended
solids, nutrients, toxic chemicals, pathogens) to
                 develop new performance
                 measures to track the effec-
                 tiveness of watershed-based
                 point source and nonpoint
                 source controls.

                 As new monitoring data are
                 collected, it is crucial for the
                 success of future perfor-
                 mance measure evaluations
                 of pollution control policies
                 that the data be submitted,
                 with appropriate QA/QC
                 safeguards, to  accessible
                 databases. If the millions
                 of  records archived in
                 STORET  had not been
                 readily accessible, it would
                 have  been impossible to
                 conduct this national analy-
                 sis of DO changes over the
                 last quarter century.
              Manu challenges
          remain. We must maintain
     and enhance the progress alreadq
        i      i -      -'-  T
      achieved in municipal wastewater
     pollution control as well as address
    other pollution sources and problems
          in the Nation's waterways.
The data mining and statisti-
     cal  methodologies de-
       signed for this study
          can potentially be
            used to detect
                  Importantly,  this study
provides the first national-scale comprehensive
evaluation of the  effectiveness of the CWA's
technology- and water quality-based effluent
control policies in achieving the "fishable and
swimmable"  goals of the act. Population
growth and expansion of urban development,
however, threaten to erase these achievements
unless  improvement in wastewater treatment
and pollution control continues.

    With the newer watershed-based strategies
    for managing pollutant loading from point
     and nonpoint sources detailed in USEPA's
     Clean Water Action Plan (USEPA, 1998),
      the Nation's state-local-private partner-
       ships will continue to work to attain the
       original "fishable and swimmable" goals
       of the 1972 CWA for all surface waters
       of the United States.
ES-18
                                                        Executive Summary

-------
REFERENCES

Adler, R.W., J.C. Landman, and D.M. Cameron.
    1993.  The Clean Water Act: 20 Years Later. Is-
    land Press, Washington, DC.

Bondelid.T., C. Griffiths, andG. van Houten. 1999.
   A National Water Pollution Control Assessment
   Model. Draft tech. report prepared by RTI, Re-
    search Triangle Park, NC, for U.S. Environmen-
    tal Protection Agency, Office of Science & Tech-
   nology, Washington, DC.

Chase, N. 1995. A river reborn. Letter to the Editor,
    Washington Post, Washington, DC. January, 15.

GAO. 1986. Water Quality: An Evaluation Method
   for the Construction Grants Program-Case Stud-
    ies. Report to the Administrator, U.S. General
   Accounting Office, Program, Evaluation and
    Methodology Division, U.S.  Environmental
    Protection Agency, Washington, DC.  Vol. 1,
    GAO/PMED-87-4B.  December.

Isaac, R.A. 1991. POTW improvements raise wa-
    ter quality. Water Env. & Tech. June, pp. 69-72.

Knopman, D.S., and R.A. Smith. 1993. Twenty
   Years of the Clean Water Act: Has U.S. Water
    Quality Improved? Environment 35(1): 17-41.

Mearns, A. 1995. "Ready..Shoot...Aim! The Future
   of Water." Editorial. WEF  Water Env. Res.
    67(7): 1019.

Patrick,  R., F. Douglass, D.M. Palavage, and P.M.
    Stewart.  1992. Surface Water Quality: Have the
    Laws Been Successful? Princeton University Press,
    Princeton, NJ. July.

Smith, RA, R.B. Alexander, and M.G. Wolman. 1987a.
   Analysis and Interpretation of Water Quality Trends
    m Major U.S. Rivers, 1974-81. Water-Supply Pa-
   per 2307. U.S. Geological Survey, Reston, VA.

Smith, R.A., R.B. Alexander, and M.G. Wolman.
    1987b. Water quality trends in the Nation's riv-
   ers. Science 235 (27 March 1987):1607-1615.

Smith, R.A., R.B. Alexander, and K.J. Lanfear. 1992.
   National Water Summary 1990-91. Stream Water
    Quality: Stream Water Quality in the Contermi-
    nous United States-Status and Trends of Selected
   Indicators During the 1980s. USGS Water Sup-
   ply Paper 2400, U.S. Geological Survey, Reston,
   VA.
U.S. Bureau of the Census. 1996. Population pro-
   jections of the United States by age, sex, race, and
   Hispanic origin: 1995-2050. Current Population
   Reports Series pp. 25-1130. Population Divi-
   sion, U.S. Bureau of the Census, Washington,
   DC.

USDOI. \970.MunicipalWasteFacilities in the'U.S.
   Statistical Summary: 1968 Inventory.  Federal Wa-
   ter Quality  Administration, U.S. Department
   of the  Interior, Washington, DC.

USEPA (STORET).  STOrage  and RETrieval Wa-
   ter Quality Information System. Office of Wet-
   lands,  Oceans, and  Watersheds, U.S. Environ-
   mental Protection Agency,  Washington, DC.

USEPA. 1974.  National Water Quality Inventory,
   1974305(b) Report to Congress. Vol.  1. EPA 440/
   9-74-001. Office  of Water Planning and Stan-
   dards,  U.S.  Environmental Protection Agency,
   Washington, DC.

USEPA. 1997. 1996. Clean Water Needs Survey, Con-
   veyance,  Treatment, and Control of Municipal
   Wastewater,  Combined Sewer Overflows and
   Stormwater Runojf. Summaries of Technical Data.
   Office  of Water Program Operations, U.S. Envi-
   ronmental Protection Agency, Washington, DC.

USEPA. 1998.  Clean Water Action Plan: Restoring
   and Protecting America's Waters. U.S. Environ-
   mental Protection Agency, Washington, DC.

USEPA. 2000. Progress in Water Quality: An Evalu-
   ation of the National Investment in Municipal
   Wastewater Treatment.  U.S. Environmental Pro-
   tection Agency, Washington, DC.

WIN. 2000. Clean and Safe Water for the 21st  Cen-
   tury: A Renewed National Commitment to Water
   andWastewater Infrastructure. Water Infrastructure
   Network, Washington, DC. April.

Wolman,  A.  1971. The  Nation's Rivers.  Science
   174:905-917.
Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment

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ES-20                                                                                                          Executive Summary

-------
     Chapter  1
 Introduction
                          / think there is no sense in forming an opinion
                       when there is no evidence to form it on. If you
                       build a person without any bones in him he may
                       look fair enough to the eye, but he will be
                       limber and cannot stand up; and I consider
                       that evidence is the bones of an opinion,

                          Mark  Twain
                          in Personal Recollections of Joan of Arc
       Today a student writing a paper on the Federal Water Pollution Control Act
       Amendments of 1972 (Public Law 92-500, later to be known as the Clean
       Water Act or CWA) would be hard-pressed to find a public official who
would say the legislation was not a success. Vice President Gore's remarks in
October 1997 celebrating the 25th anniversary of the act are representative of the
good feelings people have about the CWA (USEPA, 1997a; WEF, 1997).
     In his speech the Vice President lauded the cooperative efforts of federal,
state, tribal, and local governments in implementing the act's pollution control
provisions. He reported that the quality of rivers, lakes, and bays has "improved
dramatically." He related success stories involving water-based commerce,
agriculture, tourism, fisheries, and quality of life for a variety of locations, includ-
ing Alaska's St. Paul Harbor, the Chesapeake Bay, Cleveland's Cuyahoga River,
the Long Island Sound, and the Houston Ship Channel. With cheers like that
ringing in people's ears, it's no wonder that the prevailing public opinion is one of
success. But what if the paper-writing student were to inquire skeptically about
the "bones" of this opinion? What scientific evidence could she cite to back up
this claim? Was the Nation indeed able to buy water quality success with the
approximately $200.6 billion in capital costs and $210.1 billion in operation
and maintenance costs (current year dollars) invested from 1972 to 1994 by
public and private authorities in point source water pollution control?
                                                                                       1 -1

-------
Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
                              A centerpiece of the CWA was a dramatic increase in federal support for
                         upgrading publicly owned treatment works (POTWs). From 1970 to 1999,
                         $77.2 billion in federal grants and contributions through the U.S. Environmental
                         Protection Agency's (USEPA's) Construction Grants and Clean Water State
                         Revolving Fund (CWSRF) programs was distributed to municipalities and states
                         for this activity. A 1995 editorial in the Water Environment Federation's research
                         journal noted that no comprehensive national study has ever been done to docu-
                         ment whether this investment has paid off in terms of improved water quality
                         (Mearns, 1995). Who could blame the student, then,  if she applied Mark Twain's
                         logic and concluded that the public's opinion concerning the success of the CWA
                         was "limber" and could not "stand up."
                              The purpose of this study is to provide that student with the "bones" to form
                         an opinion that will stand up. Specifically, it was designed to examine whether
                         "significant" water quality improvements (in the form of increased dissolved
                         oxygen [DO] levels) have occurred downstream from POTW discharges since
                         the enactment of the CWA.
                          Background
                              The framers of the CWA, drawing on the experience of the Ohio River
                          Sanitation Commission, recognized that two basic sets of users depend on the
                          chemical, physical, and biological integrity of the Nation's waterways.
                              1.    Water supply users, people who take delivery of and use water drawn
                                   from various surface and ground water sources. Whether intentionally
                                   or not, these users usually contaminate the water they receive with
                                   pollutants such as organic matter, sediments, nutrients, pathogens, and
                                   heavy metals. Contaminated water (wastewater) is then collected,
                                   transported away from the site,  treated, and returned back to a natural
                                   waterbody, where it can be withdrawn and cycled again by the same or
                                   another water supply system. Figure 1-1 illustrates this process, known
                                   as the urban  water cycle.
                              2.    Water resource users, people such as fishermen, boaters, and swim-
                                   mers who use water in its natural settings—lakes, streams, rivers, and
                                   estuaries. This category might even be assumed to encompass the fish,
                                   waterfowl, and other living things that depend on clean water to live,
                                   reproduce, and thrive. These users can be directly affected by the
                                   return flow  of wastewater from water supply users.
                               Meeting the needs of water supply and water resource users has been a
                          problem that has vexed public officials for centuries. Only in the latter part of the
                          20th century did it become clear that the secret for keeping both sets of users
                          satisfied is to have all components of the cycle in place and functioning properly.
                          This fundamental concept played a pivotal role in the development of the CWA.
                               By the mid-1900s it  was becoming more and more apparent that the weak
                          link in  the urban water cycle was the wastewater treatment component. Many
                          communities were effectively short-circuiting the cycle by allowing raw or nearly
                          raw sewage to flow directly into lakes, streams, rivers, estuaries, and marine
                          waters. The organic matter contained in this effluent triggered increased growths
                          of bacteria and corresponding decreases in DO levels. This situation, in turn,
 1 -2

-------
                                                                           Chapter 1: Introduction
                                                                         Figure 1-1
                                                                         Simplified urban water
                                                                         cycle.
                                Water supply
                     3.
                   Delivery
                 Water  Supply
                       Side
                     1.
               Water withdrawal
                     A
Wastewater
  Disposal
     Side
                                                                            Water resource
     Freshwater Sources
     Lakes, Streams, and  Estuaries
negatively affected the life functions offish, shellfish, and other aquatic organ-
isms. In addition, pathogens, nutrients, and other pollutants present in wastewater
made body contact unsafe, increased the growth of algae and rooted aquatic
plants, and reduced the potential for recreation and other uses. In sum, this weak
link in the urban water cycle was greatly affecting the lives and livelihoods of
water resource users downstream from POTWs.
    Through the 1972 CWA, Congress aimed to remedy this situation by estab-
lishing a national policy requiring secondary treatment of municipal wastewater
as the minimum acceptable technology, supplemented by more stringent water
quality-based effluent controls on a site-specific, as-needed basis. At that time
approximately 4,859 systems in the country serving 56.8 million people were
providing only raw discharge or primary treatment of wastewater,  a method that
uses physical processes of gravitational settling to  separate settleable and float-
able solids from raw sewage. Secondary treatment, in contrast, yields a much
cleaner effluent because it uses biological processes to break down much of the
organic matter contained in the wastewater before allowing the wastewater to
leave the facility.
                                                                                           1 -3

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment


                              Between 1970 and 1995 a total of $61.1 billion (in current year dollars,
                          equivalent to $96.5 billion as constant 1995 dollars) was allocated by Congress
                          through USEPA's Construction Grants Program for the purpose of building new,
                          and upgrading old, POTWs. An additional $16.1 billion in federal contributions
                          was also distributed to states through the CWSRF from 1988 through 1999. In
                          addition to this federal expenditure, state and local governments and private
                          industry made significant investments to comply with regulations of the CWA and
                          other state and local environmental legislation. On a nationwide basis, actual
                          expenditure data compiled by the U.S. Department of Commerce, Bureau of
                          Economic Analysis, in the annual Pollution Abatement Cost Expenditures
                          documents a cumulative public and private sector capital expenditure of approxi-
                          mately $200.6 billion and an additional $210.1 billion as operating expenditures
                          (current year dollars) for water pollution control activities during the period from
                          1972 through 1994 (Vogan,  1996). In this context, the Construction Grants Pro-
                          gram provided federal grant support to local municipalities that  amounted to
                          almost one-half of the public sector costs  and about one-third of the total public
                          and private sector capital investment for water pollution control.
                          Study  Approach
                              For years, members of Congress, as well as citizens and special interest,
                          environmental, and business groups, have been quizzing the USEPA about the
                          benefits gained from the Nation's extraordinary public and private investment in
                          wastewater treatment (GAO, 1986a, 1986b, 1986c; USEPA, 1988). Addressing
                          their questions is a difficult task because environmental systems are very com-
                          plex—so complex, in fact, that researchers can't even agree what "stick" to use
                          to measure success.  Consequently, a number of tools have been applied in an
                          attempt to measure the  success of water pollution control efforts. These include
                              •    Reporting the number of discharge permits issued, enforcement actions
                                  taken, and other administrative actions and programmatic evaluations
                                  (Adler et al.,  1993).
                              •    Reporting on the number of POTWs built or upgraded, population
                                  served by  various treatment levels, effluent loading rates, and other
                                  trends in the  construction and use  of wastewater infrastructure
                                  (USEPA,  1997b).
                              •    Inventorying  state and national waterways meeting designated uses
                                  (e.g., reports  prepared by states to comply with CWA section 305(b),
                                  USEPA's 305(b) summary reports  to Congress) (ASIWPCA, 1984;
                                  USEPA, 1995a, 1995b).
                              •    Investigating changes in specific waterways following wastewater
                                  treatment  plant upgrades (GAO, 1978,  1986c; Leo et al., 1984; Patrick
                                  et al., 1992).
                              •    Investigating the statistical significance of national-scale changes in
                                  water quality following the  1972 CWA (GAO, 1981; Knopman and
                                  Smith, 1993;  Smith etal., 1987a, 1987b).
1 -4

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                                                                           Chapter 1: Introduction
     Although each of the above approaches provides some evidence of the
accomplishments of municipal wastewater treatment under the CWA, none could
be considered a comprehensive assessment of national progress in meeting the
CWA's main goal of maintaining, or restoring, fishable and swimmable waters.
Clearly, a fresh measuring stick is needed—one that is simple enough to provide
nonscientists with evidence of the overall success or failure of the act, yet
rigorous enough to stand up to the scrutiny of people who make their living
analyzing water quality data trends.
     This study takes a unique, three-pronged approach for answering the prima
facie question—Has the Clean Water Act's regulation of wastewater  treatment
processes at POTWs been a success? Or posed more  directly, How have the
Nation's water quality conditions changed since implementation of the 1972
CWA's mandate for secondary treatment as the minimum acceptable technol-
ogy for POTWs?  The three-pronged approach described below was developed
so that each study phase  could provide cumulative support regarding the success,
or failure, of the CWA-mandated POTW upgrades to at least secondary treat-
ment. Using the analogy  of a three-legged stool, the study authors believed that
each leg must contribute support to the premise of CWA success. If one or more
legs fail in this objective, the stool will, in the words of Mark Twain, be "limber"
and unable to  "stand up."
                     The First  Leg:
                     An  Examination  of BOD
                     Loadings Before and After
                     the  CWA (Chapter 2)
     Biochemical oxygen demand (BOD) is a measurement that allows scientists
to compare the relative polluting strength of different organic substances. The
widest application of the BOD test, however, is for measuring waste load concen-
trations to (influent load) and discharged from (effluent load) POTWs and other
facilities and evaluating the BOD-removal efficiency of these treatment systems.
From 1970 to 1999, $77.2 billion (as current year dollars) in federal grants and
contributions through USEPA's Construction Grants and CWSRF programs was
distributed to municipalities and states to upgrade POTWs and, among other
objectives, to increase their BOD-removal efficiency. Did this investment pay
off in terms  of decreasing BOD effluent loadings to the Nation's waterways?
The purpose of the first leg of this study is to examine nationwide trends in both
influent and effluent BOD loadings before and after the CWA.
     Chapter 2 begins with some background discussions to help the reader
better understand the significance of the wastewater component of the urban
water cycle and the pivotal role the 1972 CWA played in establishing the national
policy requiring secondary treatment as the minimum acceptable technology for
this component. Specifically, Sections A and B trace some historical conse-
quences of not incorporating the wastewater treatment component of the urban
water cycle. Beginning with ancient Athenians and moving through time, societies
around the world suffered the results of releasing raw or inadequately treated
sewage into waterways, including outbreaks of disease and the destruction of
  This study takes a
unique three-pronged
approach to evaluate
   in water quality
  conditions since
  the enactment of
   the 1072 CWA.
                                                                                          1 -5

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment


                        fragile aquatic ecosystems.  Sparked by the Lawrence (Massachusetts) Experi-
                        ment Station's discovery of the trickling filter method in 1892 and the development
                        of the BOD test in the 1920s, many states subsequently adopted water quality
                        standards and encouraged the use of secondary treatment for the purpose of
                        protecting their waterways and water supply and water resource users.  Unfortu-
                        nately, rapidly growing urban populations and uneven applications of wastewater
                        treatment funding and technology caused conditions to deteriorate in many highly
                        populated watersheds in the first two-thirds of the 20th century. Section C of this
                        chapter traces the evolution of the federal government's role in water pollution
                        control during this time period. Key legislation is highlighted to document its
                        movement from passive advisor through to the passage of the 1972 CWA, the
                        decisive legislation that transferred authority for directing and defining water
                        pollution control policy and initiatives from the states to USEPA. Post-1972
                        legislation and regulations continue to refine water pollution control goals and
                        objectives and authorize the funding and policies necessary to meet them.
                             Twenty-five years after the passage of the CWA, the number of people
                        served by POTWs has increased from about 140 million in 1968 to 189.7 million in
                        1996. In spite of this population  increase  (and corresponding increases in
                        the amount of BOD flowing  into  these facilities), has there been a significant
                        decline in BOD loading  to the Nation's waterways ? Section D examines
                        trends in influent and effluent BOD loading from 1940 to 1996 based on popula-
                        tion served and BOD removal rates associated with various treatment levels.
                             Section  E helps put POTW effluent BOD loading into national perspective
                        by examining rates  and spatial distribution of BOD loadings associated with other
                        point and nonpoint sources of BOD in addition to municipal loadings. Using
                        USEPA's National Water Pollution Control Assessment Model (NWPCAM)
                        (Bondelid et al.,  1999), loading estimates were derived for urban and rural runoff,
                        combined sewer overflows, and industrial wastewater discharges, in addition to
                        municipal discharges. Comparison of these sources at a national level provides
                        insight on how total BOD loading is distributed among sources in various regions
                        of the United States. Section F presents  a discussion of the investment costs
                        associated with water pollution control infrastructure over the time period  1970 to
                        1999 and summarizes projections of future wastewater infrastructure needs into
                        the 21st century.


                                             The Second Leg:  An

                                             Examination of  "Worst-Case"

                                             DO in  Waterways  Below

                                             Point  Sources Before  and

                                             After the CWA (Chapter 3)

                             Professionals in the water resource field use many different parameters to
                        characterize water quality. If one's interest centers on protecting fish and other
                        aquatic organisms, however, DO concentration is a key parameter to focus on.
                        This interest  is articulated in section 101 of Title I of the Clean Water Act in the
1 -6

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                                                                                    Chapter 1: Introduction
   Table 1-1. USEPA water quality criteria for dissolved oxygen concentration
                                  Cold-water biota
                               Early life      Other life
                               stages3"      stages
  Warm-water biota
Early life     Other life
stages"      stages
30-day mean
7-day mean
7-day mean minimum
1-day minimum"
NAC
9.5 (6.5)
NA
8.0 (5.0)
6.5
NA
5.0
4.0
NA
6.0
NA
5.0
5.5
NA
4.0
3.0
   a  Recommended water column concentrations to achieve the required intergravel dissolved
     oxygen concentrations shown in parentheses. The figures in parentheses apply to species
     that have early life stages exposed directly to the water column.
   b  Includes all embryonic and larval stages and all juvenile forms to 30 days following hatching.
   0  NA—not applicable
   d  All minima should be considered instantaneous concentrations to be achieved at all times.
     Further restrictions apply for highly manipulative discharges.
form of a national goal for fishable waters. Fish kills are the most visible symptom
of critically low levels of DO. Some species of fish can handle low levels of
oxygen better than others. Cold-water fish (salmon, trout) require higher DO
concentrations than warm-water fish (bass, catfish). Early life stages usually
require higher DO concentrations than adult stages. Table 1-1 presents USEPA's
water quality criteria for DO for cold-water and warm-water biota for four
temporal categories. The reader should note that a DO concentration of 5 mg/L
has been adopted in this study as a general benchmark threshold for defining
desirable versus undesirable levels of DO (i.e., the minimum concentration to be
achieved at all times for early life stages of warm-water biota).
      The concentration of DO in a stream fluctuates according to many natural
factors, including water temperature, respiration by algae and other plants,
nitrification by autotrophic nitrifying bacteria, and atmospheric reaeration. By far
the biggest factor in determining DO levels in most waterbodies receiving waste-
water discharges, however, is the amount of organic matter being decomposed by
bacteria and fungi. Twenty-five years after the passage of the CWA, the Nation's
investment in upgrading POTWs to secondary or greater levels of treatment
resulted in significant reductions in BOD loadings. Has the CWA'spush to
reduce BOD loading resulted in improved water quality in the Nation's
waterways ?
      The challenge in evaluating the effectiveness of point source BOD loading
reductions is the need to isolate their impacts on downstream DO from impacts
caused by urban stormwater runoff and rural nonpoint sources and the natural
seasonal influences of streamflow and water temperature. An innovative ap-
proach was developed to reduce these confounding factors and screen for water
quality station records that inherently contain a "signal" linking point source
discharges with downstream DO. It includes the following steps:
     •   Developing before- and after-CWA data sets of DO summary statistics
         derived from monitoring stations that were screened for worst-case
         conditions (i.e., conditions that inherently contain the sharpest signal).
                                                                                                     1 -7

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment


                               •    Assigning the worst-case DO summary statistic to each station for
                                   each before- and after-CWA time period and then aggregating station
                                   data at sequentially larger spatial scales.
                               •    Conducting a "paired" analysis of spatial units that have both a before-
                                   and an after-CWA worst-case DO summary statistic and then docu-
                                   menting the direction (improvement or degradation) and magnitude of
                                   the change.
                               •    Assessing how the point source discharge/downstream worst-case DO
                                   signal changes over progressively larger spatial scales.
                               The hierarchy of spatial scale plays an especially important role in this
                          second leg of the three-legged stool approach for examining water quality condi-
                          tions before and after the CWA. Three spatial scales are addressed in this portion
                          of the study: reach, catalog unit, and major river basin.
                               Reaches are segments of streams, rivers, lakes, estuaries, and coastlines
                          identified in USEPA's Reach File  1 (RF1). In this system, a reach is defined by
                          the confluence  of a tributary upstream and a tributary downstream. Reaches in
                          RF1 average about 10 miles in length and have a mean drainage area of 115
                          square miles. Created in 1982, RF1 contains information for 64,902 reaches in the
                          48 contiguous states, covering 632,552 miles of streams. Figure 1-2 is a map of
                          the stream reach network in the Chesapeake Bay drainage area.
Figure 1-2
Reach File Version 1
stream reach network in
the Chesapeake Bay
drainage  area.
 1 -8

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                                                                                 Chapter 1: Introduction
     An individual reach in the RF1 system is identified by an 11-digit number.
This number carries much spatial information. It identifies not only the reach
itself, but also the hierarchy of watersheds to which the reach belongs. The first
eight digits of the identification number are the hydrologic unit catalog (HUC)
code. Originally developed by the U.S. Geological Survey (USGS), the HUC code
identifies four scales of watershed hierarchy. The highest scale, coded  in the first
two digits of the identification number, is the hydrologic region (commonly re-
ferred to a major river basin). Hydrologic regions represent the largest river
basins in the country (e.g., the Missouri River Basin and the Tennessee River
Basin). Subregions are identified by the next two numbers. These are followed by
the accounting unit and the cataloging unit, the smallest scale in the hierarchy.
Figures 1-3 and 1-4 display the 18 hydrologic regions and the 2,111 cataloging
units in the contiguous  48  states.
                                                                                    Figure 1-3
                                                                                    The 18 major river
                                                                                    basins (hydrologic
                                                                                    regions) of the
                                                                                    48 contiguous states.
Rio Grande River I T  T^xas-Gulf
                                                                                   Figure 1-4
                                                                                   The 2,111 hydrologic
                                                                                   catalog units of the 48
                                                                                   contiguous  states.
                                                                                                  1 -9

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
                                 Table 1-2.  Station and reach identification codes: Reach File Version 1
                                            (RF1)

                                   Agency ID:	21 MINN
                                   Station ID:	MSU-815-BB15E58
                                   Station  Location:	Mississippi R ©Lock & Dam#2 at Hastings
                                   Major river basin name:	Upper Mississippi River
                                   Major river basin ID:	07
                                   Subbasin  ID:	0701
                                   Accounting Unit ID:	070102
                                   Catalog Unit ID:	07010206
                                   Reach ID:	07010206001
                                   Station  milepoint on reach	UM 815.5
                                   Reach length (miles)	33.1
                                   Upstream milepoint of  reach (Minnesota R)	UM 844.7
                                   Downstream milepoint of reach (St. Croix R)	UM 811.6
                               Developers of RF1 extended the 8-digit HUC code by three digits for the
                          purpose of identifying the reaches within the cataloging unit. Table 1-2 is an
                          example of the RF1 identification codes for a reach of the Upper Mississippi
                          River near Hastings, Minnesota. This 33.1-mile reach is defined by the
                          confluence of the Minnesota River (upstream) and the St. Croix River (down-
                          stream).
                               Many engineering studies have documented the impact of BOD loading on
                          the DO budget in reaches immediately below municipal outfalls. Consequently,
                          one would expect to find a sharp signal linking point source discharges with
                          worst-case DO in those reaches. The key aspect of this investigation,  therefore,
                          was to see how the signal changed (or if it could be detected at all) as one
                          aggregated worst-case DO data at increasingly larger spatial scales and then
                          compared summary statistics associated with time periods before and  after the
                          CWA. Detection of a statistically significant signal at the catalog unit and major
                          river basin scales would provide evidence that the CWA mandates to upgrade to
                          secondary treatment and greater levels of wastewater treatment yielded broad as
                          well as localized benefits.
                               Figure 1-5 illustrates signal and noise relationships over the range of spatial
                          scales (reach, catalog unit, and major river basin) using the Upper Mississippi
                          River near Hastings, Minnesota, as an  example. The line graphs in the left side of
                          the figure display DO data collected at monitoring stations from 1953 to 1997
                          aggregated by spatial unit. The bar graphs on the right side of the figure compare
                          worst-case DO (mean 10th percentile) for designated time periods before and
                          after the CWA and are produced as the final step of the comparison analysis
                          process described in Chapter 3. The summary statistics they present are derived
                          from station data that have been selected, aggregated, and spatially assessed so
                          that they might have the best chance  of inherently containing a "signal" linking
                          point source discharges  with downstream DO.
 1 -10

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                                                                                          Chapter 1: Introduction
Figure 1-5
Line graphs of DO observations for the Upper Mississippi River from 1953 to  1997 and bar charts of worst-case DO
before and after the CWA for (a) reach scale, (b) catalog unit scale, and (c) major river basin scale.
Source: USEPA STORET for (a) RF1 reach 07010206001 (UM 811.6-844.7), (b) catalog unit 07010206 (UM 811.6-
879.8), and (c) major river basin (07).
(a) Reach scale
    25
    1950  1955  1960   1965  1970  1975  1980  1985  1990  1995  2000
                               Year
(b) Catalog unit scale
    25-r
    1950  1955  1960  1965  1970  1975  1980  1985  1990  1995  2000
                               Year
(c) Major river basin scale
    25
    1950  1955  1960  1965  1970  1975  1980  1985  1990  1995  2000

                              Year
                                                                    o
                                                                    0)
                                                                                     25
                 4~ Benchmark
                 for determining
                 undesirable versus
                 desirable levels of
                 worst-case DO
234567
 Worst-Case DO  (mg/L)
                                                                    o
                                                                    0)

                                                                    •§
                                                                    m
                 4~ Benchmark
                  for determining
                  undesirable versus
                  desirable levels of
                  worst-case DO
234567

 Worst-Case DO  (mg/L)
                                                                    I
                                                                    o
                                                                    £
           38
4~ Benchmark
 for determining
 undesirable versus
 desirable levels of
 worst-case DO
234567
 Worst-Case DO  (mg/L)
                                                                                                           1 -11

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
                             Examining the line graphs in Figure 1-5, one can see that each broader
                         spatial scale aggregation of station data yields a "noisier" data pattern. The bar
                         chart for the reach scale (the finest scale) displays the greatest improvement in
                         worst-case DO, increasing 3.5 mg/L from before to after the CWA. At the
                         broader scales, an improvement is detected, but it is not as large (a before and
                         after difference of 1.7 mg/L at the catalog unit scale and 1.5 mg/L at the major
                         river basin scale). This is because the larger spatial units contain stations both
                         near and far from point source outfalls. In spite of the unavoidable introduction of
                         data noise, however, the signal linking point source discharge to downstream DO
                         is still detectable at the broader scales using the data mining and statistical
                         methodology developed by the study authors. Readers should note that in this
                         example, the worst-case DO concentration was below the benchmark threshold
                         of 5.0 mg/L at all three scales before the CWA and above the threshold at all
                         three scales after the CWA.
                             Section A of Chapter 3 provides background on the relationship between
                         BOD loading and stream water quality and discusses the two key physical
                         conditions (high temperature and low flow) that create "worst case" conditions
                         for DO. Section B describes the development and application of a set of screen-
                         ing rules to select, aggregate, and spatially assess before- and after-CWA worst-
                         case DO data drawn from USEPA's STORET database.  Section C presents the
                         results of the comparison analysis of worst-case DO from before and after the
                         CWA for reach, catalog unit, and major river basin scales.
                                              The Third  Leg:
                                              Case Study Assessments
                                              of Water Quality
                                              (Chapters  4 through 13)
                              The second leg of this study focused on the use of large national databases
                         and statistical methods to examine temporal and spatial trends in DO conditions
                         nationwide. However, the uniqueness of each waterway and the activities sur-
                         rounding it requires an investigation to go beyond STORET to identify, quantify,
                         and document in detail the specific actions that have resulted in water quality
                         improvements and associated benefits to water resource users.
                              In the third and final leg of this study nine urban waterways have been
                         selected to characterize changes in population, point source effluent loading,
                         water quality, and environmental resources before and after the CWA:

                             •  Connecticut River            •  Chattahoochee River
                             •  Hudson-Raritan estuary        • Ohio River
                             •  Delaware estuary             • Upper Mississippi River
                             •  Potomac estuary              • Willamette River
                             •  James estuary
1 -12

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                                                                               Chapter 1: Introduction
     These waterways were selected to represent heavily urbanized areas with
historically documented water pollution problems. A variety of data sources,
including the scientific literature, USEPA's national water quality database
(STORET), and federal,  state, and local agency reports, were used to character-
ize long-term trends in population, point source effluent loading rates, ambient
water quality, environmental resources, and recreational uses. Additional informa-
tion was obtained from validated water quality models for the Delaware,
Potomac, and James estuaries and Upper Mississippi River case studies to
quantify the water quality improvements achieved by upgrading municipal facili-
ties to secondary and better levels of treatment as mandated by  the 1972 CWA.
     Chapter 4 presents  an overview of the case study assessment approach and
provides background on previous efforts that have used case studies to examine
long-term changes in water quality conditions in the United States. Chapter 4 also
summarizes the overall findings for the nine urban waterways; detailed  assess-
ments are provided for each in Chapters 5 through 13.


The  Audience  For This   Report

     This study was designed with two broad groups in mind. The primary
audience are the technical scientists and engineers who try to understand and
evaluate cause-effect relationships  of pollutants, their sources, and the fate of
these pollutants in receiving waters. Understanding these relationships is crucial
for developing appropriate (cost-effective and environmentally protective) pollu-
tion control measures. This same audience is often tasked with the responsibility
of developing and carrying out large-scale monitoring programs  whose purpose is
to gage the performance of various  policy decisions related to pollution source
control.
     The secondary audience is Congress, regulatory/policy professionals, and
the informed public who have often questioned the effectiveness of major pollu-
tion control programs directed at the national level. It may benefit future decisions
makers to know if major public works programs (i.e., the CWA Construction
Grants and CWSRF programs) accomplished what they were designed to do—
namely reduce effluent BOD loads  from municipal and industrial sources and
improve dissolved oxygen in many previously degraded waterways of the Nation.
These same groups also need to understand that water pollution  control  efforts
are never ending. The 1972 CWA did not "solve" the problem. In fact, waste
materials are generated continuously and effluent removal efficiencies must
increase in the future  to compensate for population growth. Planning for O&M
expenditures as well as capital expenditures for replacement of obsolete facilities
and upgrades to maintain adequate levels/efficiency of wastewater removal is an
ongoing requirement. A projection  analysis presented in Chapter 2 demonstrates
that many of the gains in national water quality improvements may be lost if
future wastewater infrastructure investments and capacity does  not keep pace
with expected urban population growth.
                                                                                              1 -13

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
                         References

                         Adler, R.W., J.C. Landman, and D.M. Cameron. 1993. The Clean Water Act: 20
                           years later. Island Press, Washington, DC.
                         ASIWPCA.  1984. America's clean water: The states' evaluation of progress
                           1972-1982. Executive Summary and Technical Appendix. Association of
                           State and Interstate Water Pollution Control Administrators, Washington, DC.
                         Bondelid, T., C. Griffiths, and G. Van Houten. 1999. A national water pollution
                           control assessment model. Draft technical report prepared by Research
                           Triangle Institute, Durham, NC, for U.S. Environmental Protection Agency,
                           Office of Science and Technology, Washington, DC.
                         GAO.  1978. Secondary treatment of municipal wastewater in the St. Louis
                           Area: Minimal impact expected. GAO/CED-78-76. U.S. General Accounting
                           Office, Program, Evaluation and Methodology Division, Washington, DC.
                         GAO.  1981. Better monitoring techniques are needed to assess the quality of
                           rivers and streams. Vol.#l. Report to Congress. GAO/CED-81-30. U.S.
                           General Accounting Office, Program, Evaluation and Methodology Division,
                           Washington, DC.
                         GAO.  1986a. The  Nation's water: Key unanswered questions about the
                           quality of rivers and streams. Vol. 1. GAO/PMED-86-6. U.S. General
                           Accounting Office, Program, Evaluation and Methodology Division, Washing-
                           ton, DC.
                         GAO.  1986b. Water quality: An  evaluation method for  the  Construction
                           Grants Program—methodology. Vol. 1. Report to the Administrator. GAO/
                           PMED-87-4A. U.S. General Accounting Office,  Program, Evaluation and
                           Methodology Division, Washington, DC.
                         GAO.  1986c. Water quality: An  evaluation method for  the  construction
                           grants program-case studies. Vol.  1. Report to the Administrator. GAO/
                           PMED-87-4B. U.S. General Accounting Office,  Program, Evaluation and
                           Methodology Division, Washington, DC.
                         Knopman, D.S. and R.A. Smith. 1993. Twenty years of the Clean Water Act:
                           Has U.S.  water quality improved? Environment 35(1):17-41.
                         Leo, W.M.,  R.V. Thomann, and T.W. Gallagher. 1984. Before and after case
                           studies:  Comparisons of water quality following municipal treatment plant
                           improvements. EPA430/9-007. Technical report prepared by HydroQual, Inc.,
                           for U.S. Environmental Protection Agency, Office of Water Programs, Wash-
                           ington, DC.
                         Mearns, A.  1995. "Ready...shoot...aim! The future of water." Editorial. WEF
                            Water Env. Res. 67(7):1019.
                         Patrick, R.,  F. Douglass, D.M. Palavage, and  P.M. Stewart. 1992. Surface water
                            quality: Have the laws been successful? Princeton University Press,
                            Princeton, NJ.
                         Smith, R.A., R.B. Alexander, and M.G. Wolman. 1987a. Analysis and interpre-
                            tation of water  quality trends in major  U.S. rivers,  1974-81. Water-Supply
                            Paper 2307. U.S. Geological Survey, Reston, VA.
                         Smith, R.A., R.B. Alexander, and M.G. Wolman. 1987b. Water quality trends in
                            the Nation's rivers. Science 235 (27 March  1987): 1607-1615.
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                                                                            Chapter 1: Introduction
USEPA.  1995a. National water quality inventory:  1994 report to Congress.
   EPA841-R-95-005. U.S. Environmental Protection Agency, Office of Water,
   Washington, DC.
USEPA.  1995b. National water quality inventory:  1994 report to Congress.
   Appendices. EPA841-R-95-006. U.S. Environmental Protection Agency,
   Office of Water, Washington, DC.
USEPA.  1997a. The Clean Water Act: A snapshot of progress in protecting
   America's waters. Vice President Al Gore's remarks on the 25th Anniversary
   of the CWA. U.S. Environmental Protection Agency, Washington, DC.
USEPA.  1997b. 7996 Clean  Water Needs Survey:  Conveyance,  treatment,
   and control of municipal wastewater, combined sewer overflows and
   stormwater runoff. Summaries of technical data. U.S. Environmental
   Protection Agency, Office of Water Program Operations, Washington, DC.
USEPA.  1988. POTW's and water quality: In search of the big picture: A
   status  report on EPA's ability to address several questions of ongoing
   importance to the Nation's municipal pollution control program. U.S.
   Environmental Protection Agency, Office of Water, Office of Municipal
   Pollution Control, Washington, DC.
Vogan, C.R. 1996.  Pollution  abatement and control expenditures, 1972-94.
   Survey of current business. Vol. 76, No. 9, pp. 48-67. U.S. Dept. of Com-
   merce, Bureau of Economic Analysis.
WEF. 1997. Profiles in water quality: Clear success, continued challenge.
   Water Environment Federation, Alexandria, VA.
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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
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    Chapter  2
                           An  Examination  of  BOD
                           Loadings  Before and
                           After the  CWA
      Chapter 1 introduced the "three-legged stool" approach to assess the
      success of the CWA's mandate for POTW upgrades to secondary and
      greater than secondary wastewater treatment. The premise is that each
"leg" of the approach must provide cumulative support for the stool to stand up
firmly and success to be declared. Chapter 2 presents the results of the first leg.
Specifically, this chapter focuses on whether there was a significant reduction in
the discharge of oxygen-demanding materials from POTWs to the Nation's
waterways after implementation of the 1972 CWA.
    To help put this analysis into perspective, Chapter 2 begins with a back-
ground discussion of the historical consequences of ignoring the wastewater
treatment component of the urban water cycle on the aquatic ecosystem
(Section A) and then explains how scientists and engineers eventually harnessed
the power of decomposers and developed the process now known as secondary
treatment (Section B). Section C traces the legislative and regulatory history of
the federal role in water pollution control and how the 1972 CWA accelerated the
national trend of upgrading POTWs to at least secondary treatment. Section D
presents national trends in influent BOD loading (BOD entering POTWs) and
effluent BOD loading (BOD discharged from POTWs into surface waters) for
select years between 1940 and 1996, as well as effluent loading projections into
the 21 st century.
    During the mid-1990s (ca.  1995), pollutant loading from municipal wastewa-
ter treatment facilities accounted for only about one-fifth of the estimated total
national point and nonpoint source load of BOD discharged to surface waters.
Section E presents comparative  estimates of the remaining four-fifths of the total
national load accounted for by industrial wastewater dischargers, combined sewer
overflows (CSOs), and nonpoint (rural and urban1)  sources. Section F examines
the national public and private investment costs associated with water pollution
control. Section G provides a summary,  conclusions, and a perspective on future
trends for municipal wastewater loads.
 For the purposes of this comparison, urban "nonpoint" sources include areas within the National
 Pollutant Discharge Elimination System (NPDES) stormwater permit program that meet the legal
 definition of a "point" source in section 502(14) of the CWA.
                                                                                2-1

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment


                        A.  Historical  Consequences  of  Ignoring

                             the Wastewater  Treatment Component

                             of  the  Urban  Water Cycle

                             The urban water cycle can be divided into a water supply side and a
                        wastewater disposal side (see Figure 1-1). The basic technological framework
                        for the water supply side began as far back as 5,000 years ago when people from
                        the Nippur of Sumeria, a region of the Middle East, built a centralized system to
                        deliver water into populated areas (Viessman and Hammer, 1985). The Minoans
                        at Knossos, some 1,000 years later, improved on the concept with the installation
                        of a system of cisterns and stone aqueducts designed to provide a continuous flow
                        of water from the surrounding hills to dwellings in the central city. Basic concepts
                        and instructions related to purity of water, cleanliness, and public sanitation are
                        also recorded in the  books of Leviticus and Deuteronomy (23:12-13) in the Old
                        Testament. Talmudic public sanitation laws were enacted in Palestine to protect
                        water quality in the  centuries before and after the early Christian era ca. 200
                        B.C. to 400 A.D.  (Barzilay et al., 1999).
                             The ancient Athenians were some of the first people to develop the waste-
                        water disposal side  of the urban water cycle. The Greeks moved sanitary wastes
                        away from their central city through a system of ditches to a rural collection
                        basin. The wastewater was then channeled through brick-lined conduits for
                        disposal onto orchards and agricultural fields. In the ancient world, though, the
                        Roman Empire attained the highest pinnacle for developing the knowledge and
                        technology to select the best water supplies and to construct far-reaching net-
                        works of aqueducts to bring water supplies to Rome for distribution through pipes
                        to wealthy homes and public fountains. The Romans also built large-scale public
                        sanitation projects for collecting and controlling sewage and stormwater drainage.
                        The great Roman sewer Cloaca Maximum still drains the Forum in Rome today
                        after 2,000 years of operation.
                             In expanding their empire throughout North Africa and Europe, the Romans
                        introduced the technologies needed to develop water supplies and to construct
                        aqueducts and urban drainage systems to promote rudimentary standards of
                        public sanitation. With the collapse of the Roman Empire, however, the public
                        sanitation  infrastructure was neglected and the technology was lost and forgotten
                        for a thousand years as the "Dark Ages" descended on the western world. Filth,
                        garbage, excrement in the streets, polluted water sources, disease, plague, and
                        high mortality rates  were common consequences of the dismal public sanitary
                        conditions that persisted well into the 19th century (Barzilay et al., 1999).
                             Throughout history, two components of the urban water cycle were absent:
                        wastewater treatment and the transport of treated wastewater for discharge back
                        to natural  waterbodies. For towns situated near coastal areas, estuaries, or large
                        rivers, short-circuiting the cycle caused no immediate consequences because
                        these waterbodies had some capacity to assimilate raw sewage without causing
                        water pollution problems. For many inland communities, however, water pollution
                        problems were more acute. As populations increased, even coastal towns were
                        forced to reckon with the consequences of ignoring the wastewater treatment
                        component of the urban water cycle (see Rowland and Heid, 1976).
2-2

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                                     Chapter 2:  An Examination of BOD Loadings Before and After the CWA
     Much of the blame for incomplete urban water cycles up until the middle of
the 19th century can be traced to a general ignorance about the consequences of
allowing untreated wastewater to flow into surface waters used for drinking
water downstream. As the relationship between this practice and its effects on
public health became better understood, however, a community's refusal to adopt
effective wastewater treatment in its cycle was more often based in politics and
economics, rather than a lack of technological knowledge (see Rowland and Heid,
1976). No matter the reason, bypassing the wastewater treatment side of the
urban water cycle affected both water supply and water resource users.


Impacts on Water Supply Users and  "The  Great
Sanitary Awakening"

     The introduction of household piped water in the mid-19th century was the
key technological development that cemented the two sides of the urban water
cycle—water supply and wastewater disposal. Unfortunately, although piped
water supply systems gave urban dwellers more convenient access to water,
people were also held hostage to the water supply source chosen by the local
water company. For many city dwellers, drinking piped water became hazardous
to one's health as massive epidemics of waterborne diseases such as cholera and
typhoid fever broke out in many cities in Great Britain and the United States
(Table 2-1).
  Table 2-1.  Pathogens and their associated diseases. (Adapted from Metcalf and Eddy, 1991)
  Pathogen
Disease
Effects
  Bacteria
    Escherichia coli
    Legionella pneumophila
    Leptospira sp.
    Salmonella typhi
    Salmonella sp.
    Shigella sp.
    Vibrio cholerae
    Yersinia enterolitica
Gastroenteritis
Legionellosis
Leptospirosis
Typhoid fever
Salmonellosis
Shigellosis
Cholera
Yersinosis
Vomiting, diarrhea, death in susceptible populations
Acute respiratory illness
Jaundice, fever (Weil's disease)
High fever, diarrhea, ulceration of the small intestine
Diarrhea, dehydration
Bacillary dysentery
Heavy diarrhea, dehydration
Diarrhea
  Protozoa
    Balantidium coli
    Cryptosporidium sp.
    Entamoeba histolytica
    Giardia lamblia
    Naegleria fowleri
Balantidiasis
Cryptosporidiosis
Amedbiasis
Giardiasis
Amoebic
meningoencephalitis
Diarrhea, dysentery
Diarrhea
Diarrhea w/bleeding, abscesses on liver, small intestine
Mild to severe diarrhea, nausea, indigestion
Fatal disease; brain inflammation
  Viruses
   Adenovirus (31 types)
   Enteroviruses (67 types)
   Hepatitis A
   Norwalk agent
   Reovirus
   Rotavirus
Respiratory disease
Gastroenteritis
Infectious hepatitis
Gastroenteritis
Gastroenteritis
Gastroenteritis
Heart anomalies, meningitis
Jaundice, fever
Vomiting, diarrhea
Vomiting, diarrhea
Vomiting, diarrhea
                                                                                                2-3

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment


                               Dr. John Snow, physician to England's Queen Victoria, was one of the first
                          to scientifically link waterborne diseases to contaminated source water supplies.
                          Examining records of some 14,600 Londoners who had died in an 1854 cholera
                          epidemic, Snow found that people who had received water from an intake
                          downstream of London's sewage outlets in the lower Thames River had a much
                          higher death rate (8.5 times higher) than those receiving Thames River water
                          from an intake upstream of the sewage discharges (Snow,  1936). The threat of
                          contaminated water sources did little, however, to quell the construction boom of
                          new water supply systems in the second half of the 19th century, especially in the
                          United  States. In 1850 there were about 83 water systems in the United States.
                          By 1870, the count had risen to 243 systems (Fuhrman, 1984).
                               Like Londoners, American city dwellers with piped water faced an in-
                          creased risk of waterborne diseases. Beginning in 1805, the New York City
                          Council had the authority and responsibility for sanitary conditions in the city.
                          Despite this early recognition of governmental responsibility for public health,
                          epidemics of typhoid fever broke out in 1819, 1822,1823, and 1832 and cholera
                          ravaged workers on the Erie Canal (Rowland and Heid, 1976). Between 1832
                          and 1896, cities  in North America and Europe suffered four devastating outbreaks
                          of cholera that were spread by polluted urban water supply systems (Garret!,
                          1994). Cholera epidemics in New York City in 1832 and 1849 claimed 3,500 and
                          5,000 lives, respectively. In 1891 typhoid fever caused the deaths of 2,000 people
                          in Chicago (Fair et al., 1971). Hundreds more succumbed to typhoid in Atlanta
                          and Pittsburgh in the 20-year period between 1890 and 1910 (Bulloch, 1989). The
                          importance of an unpolluted source water for public drinking water was clearly
                          shown in the earliest public health studies of waterborne diseases and drinking
                          water supplies. Typhoid death rates in 61 cities of the United States during 1902-
                          1906, for example, ranged from a high of 120 per 100,000 for a run-of-river
                          supply  for Pittsburgh, Pennsylvania, to a low of 15 per 100,000 for the upland
                          watershed supply of New York City (Okun,  1996).
                               This trend would have certainly continued for a few more decades if not for
                          the discovery of a new purification technology: chlorination of drinking water. As
                          a disinfecting agent, chlorine gained widespread use in the years  1908-1911, soon
                          bringing typhoid fever and cholera outbreaks under control in virtually all commu-
                          nities that adopted chlorination. Detailed mortality records and public water supply
                          records compiled by the Commonwealth of Massachusetts, for example, clearly
                          illustrate the link between the introduction of filtration and disinfection of public
                          water supplies and the sharp reduction in typhoid fever deaths (Figure 2-1) from a
                          peak of 125 per 100,000 in 1860 to less than 5 per 100,000 by 1920 and essentially
                          zero from 1940 to the present time (Fair et al., 1971; J. Higgins, Massachusetts
                          DEP, personal communication, September 1998; USCB, 1975).
                               Influenced by the Enlightenment and democratic movements of the late 18th
                          century in Britain, France, and the new United States, the concept that a govern-
                          ment had the moral and ethical responsibility to protect the general welfare of its
                          citizens, including public health, arose in Britain and the United States during the
                          first half of the 19th century. Motivated by the bleak urban conditions chronicled
                          by Charles Dickens, Chadwick's  (1842) Report on the Sanitary Condition of
                          the Labouring Population of Great Britain marked the beginning of the "Great
                          Sanitary Awakening" (Okun, 1996). Chadwick's report directly influenced
                          passage of Great Britain's Public Health Act of 1848 and its formation of the
2-4

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                                     Chapter 2: An Examination of BOD Loadings Before and After the CWA
                                           Typhoid deaths
                                           % of population
                                           served by public
                                           water suppliers
                                           1940
1960
                                                                    TJ
                                                                    (D
                                                               100  8
    90
    80
  -70
  -60
  -50
  -40
  -30
  -20
  -10
   O
1980
 S,
 !•»
 (D
 TJ
 O
•o
 5T
 5'
 3

 (D
                                                                    TO
                                                                    O
                         Figure 2-1
                         Comparison of the death
                         rate due to typhoid and the
                         percentage of population
                         served by public water
                         suppliers in Massachu-
                         setts from 1860 to 1970.
                         Source: Fair et al., 1971;
                         USCB, 1975.
General Board of Health, and, in the United States, the creation of the Massachu-
setts State Board of Health in 1869 (Okun, 1996) and the New York State Board
of Health in 1880 (Rowland and Heid, 1976).
     The technological impacts of the "Great Sanitary Awakening" on the origins
of drinking water treatment and water pollution control systems are well docu-
mented in the records of a series of international sanitary conferences held from
1851 through 1938. The conferences addressed scientific issues related to public
health, the environment, and the need to control diseases spread by contaminated
food and water. The conferences highlighted serious public health and environ-
mental issues that have since evolved as the foundation of the numerous state,
local, federal, and international environmental laws and programs enacted in the
latter half of the 20th century (Howard Jones, 1975).


Impacts on  Water Resources  Users

     Sewer is an Old English word meaning "seaward." As the name suggests,
from the  1500s through mid-1800s, London's sewers were nothing more than
open ditches draining wastewater seaward via the Thames River. The year 1858,
also known as the year of "The Great Stink," brought  matters to a head. That
summer the stench  from the Thames drove people out of the city by the thou-
sands. The windows of the Parliament building had to be draped with curtains
soaked in chloride of lime. By the end of the summer session,  even the most
traditional members had to agree: something had to be done about wastewater.
     In response, London officials abolished cesspools and made the use of water
closets, drainage pipes, and centralized sewer collection systems mandatory. Over
in the United States, city officials were also feeling the pressure of a populace
weary of the noxious conditions associated with open sewers. In 1910 about 10
percent of the urban population was serviced by centralized collection systems
                                                                                              2-5

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
                          (FWPCA, 1969). This number increased steadily in the following decades; by
                          1940, 70.5 million persons (53 percent of the population) were served by them.
                               Unfortunately, treating drinking water with chlorine and developing efficient
                          sewage collection systems did little to help water resources users. Raw sewage
                          deposited into streams, lakes, and estuaries  was still raw sewage, whether it was
                          discharged through an engineered wastewater collection system or through an
                          open ditch. Collection systems just made the dumping more efficient and com-
                          plete. And though chlorine proved to be a godsend for public health, it treated only
                          a pollution symptom, not the cause. Its success, unfortunately, tended to divert
                          attention away from installing wastewater treatment as a means of protecting
                          public health (Bulloch, 1989).
                               Several studies conducted around the turn of the century documented
                          increasingly noxious conditions in several well-known rivers receiving untreated
                          urban discharges. These included the Merrimack River (1908), Passaic River
                          (1896), Chicago Ship and Sanitary Canal (1900), and Blackstone River (1890).
                          Looking beyond water quality, scientists also began to examine the effect urban
                          discharges were having on stream biota. Studies were conducted in places like
                          the Sangamon River in Illinois (1929) (Eddy, 1932), the Potomac River (1913-
                          1920), and the  Shenandoah River (1947-1948) (Henderson, 1949). These and
                          other early investigations are an invaluable starting point for assessing long-term
                          trends in the surface water environment.
                               At the turn of the century, public officials focused most of their attention on
                          water supply users. The users demanded and received the two services most
                          important to them: the delivery of clean water and the collection and removal of
                          wastewater. Support for water resources users, on the other hand, was minimal.
                          Generally these users captured the attention of city  leaders only when conditions
                          reached crisis levels. Then, in most cases, the response was to deal with ways to
                          alleviate the symptom rather than the cause of water pollution.
                               In Chicago, for example, officials became concerned about the increasing
                          amount of urban water pollution flowing into their backyard water supply source,
                          Lake Michigan. In response, they built the Chicago Drainage Canal, which
                          diverted sewage away from the lake and directed it to the Des Plaines River, a
                          tributary that emptied into the Mississippi River.
                               After the canal opened in 1900, officials in the downstream city of St. Louis
                          fumed. They quickly initiated proceedings in the Supreme Court of the United
                          States against the state of Illinois and the Sanitary District of Chicago. Though St.
                          Louis eventually lost its case because the city could not prove direct harm to its
                          water supply from its upstream neighbor, the episode underscored the fact that
                          effective wastewater treatment was a critical component in the modern urban
                          water cycle.
2-6

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                                   Chapter 2: An Examination of BOD Loadings Before and After the CWA
B.    Evolution  of Wastewater and the Use

       of DO and  BOD as Indicators of

       Water Quality

     European history as far back as 400 years ago tells of sewage being col-
lected, dewatered, and transported as "night soil" away from population centers.
In 1857 a British royal commission, in response to noxious conditions in the
Thames, directed Lord Essex to report on alternative ways to dispose of urban
wastewater. Essex concluded that applying wastewater to crops would be
preferable to the current practice of draining it into the river. Wastewater treat-
ment technology has progressed tremendously since those times. Today's facilities
employ a variety of sophisticated physical, chemical, and biological processes to
reduce domestic and industrial wastewater to less harmful by-products.


Primary  Treatment

     The march toward effective wastewater treatment began in the late 1800s
when municipalities began to build facilities for the purpose of physically separat-
ing out solids and floating debris from wastewater before releasing it to a water-
body (Rowland and Heid,  1976). In many cases, this construction was promoted
by city officials and entrepreneurs, who were rapidly learning that unsightly urban
debris and a delightful growing phenomenon, tourists with leisure dollars to spend,
did not mix. By no coincidence, one of the first of these treatment facilities was
constructed in 1886 next to New York's famous Coney Island beaches. Other
cities with prominent  waterfront areas followed suit, and by 1909 about 10
percent of the  wastewater  collected by municipal sewer systems underwent some
form of physical separation process, now known as primary treatment (OTA,
1987).
     The practice of physically screening and settling out solids and floating
debris was a critical first step in incorporating the wastewater treatment compo-
nent into the urban water cycle. Even though primary treatment facilities were
simple in concept, they reduced the concentrations of contaminants entering urban
waterways.


Dissolved Oxygen as an Indicator  of Water Quality

     In 1900 the United States was primarily an agrarian society, with  the
majority of the population living in rural areas (Figure 2-2). In the 1920s and
1930s, a combination  of population growth, the Great Depression, and the rise of
urban industries with the increased employment opportunities they afforded
caused the rural/urban population balance to shift in favor of cities. The increasing
volumes of wastewater generated by this influx of people soon overwhelmed the
primary treatment capacity of POTWs, many of which had been underdesigned
from the start. Consequently, the modest water quality gains achieved in many
cities by primary treatment technology were soon overwhelmed by greater
volumes of sewage.
                                                                                         2-7

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                                     Chapter 2: An Examination of BOD Loadings Before and After the CWA
addition to the carbon cycle of production and decomposition, the nitrogen cycle
also influences DO through a series of sequential reactions wherein organic
nitrogen compounds are hydrolyzed into ammonia and ammonia is oxidized to
nitrite and nitrate (nitrification) by autotrophic nitrifying bacteria, with DO con-
sumed as part of these sequential reactions.
     The amount of oxygen water can hold at any one time is limited, however,
by the saturation concentration of oxygen. The saturating amount of oxygen gas
from the atmosphere that can be dissolved in water is limited by water tempera-
ture, salt content, and pressure (elevation above sea level). In a sense, then, all
the aerobic aquatic life in a waterbody is in competition for that limited amount of
oxygen. In natural streams there are usually no losers because dissolved oxygen
is continuously replenished from the atmosphere at about the same rate at which
it is used up by aquatic organisms. A problem arises, however, when large
amounts of organic material from sewage or other pollution sources enter the
water and  the decomposer population (especially bacteria) explodes in response.
These organisms have the potential to lower, or even completely exhaust, oxygen
in the water. When this occurs, life that depends on the presence of oxygen
(aerobic) in the waterbody dies or, where possible, the biota moves on to waters
with higher oxygen levels.
     In the absence of oxygen in water,  anaerobic bacteria further break down
organic matter. These organisms obtain energy from oxygen bound into other
substances such as sulfate compounds. Anaerobic processes are much slower
than aerobic decomposition, however, and their end products, such as hydrogen
sulfide, are usually noxious.


Secondary  Treatment

     Harnessing the power of decomposers to break down organic matter in
wastewater is at the heart of a treatment process now known as secondary
treatment.  Two distinct methods of this treatment type evolved around the turn of
the century. The Lawrence Experiment Station in Massachusetts pioneered the
first method in 1892. Called the trickling filter method, it involves spraying waste-
water onto a column of crushed stone on which a community of bacteria, fungi,
protozoa, and insects resides.  The organisms take in a portion of the organic
matter and break it down. Some of the breakdown products, such as carbon
dioxide, escape to the atmosphere. Others, like nitrate, remain in solution. Still
other products are absorbed into the organisms themselves. This latter material is
eventually collected in settling tanks as sludge after the organisms die or is
otherwise  detached from the stone.
     A second method of secondary treatment was advanced around 1913 by the
Lawrence  Experiment Station and Ardem and Lockett in England. Known as
activated sludge treatment, it follows the  same principles as the trickling filter but
instead of  cultivating decomposers on the surface of rocks, organisms are simply
suspended in a tank by a continuous flow of wastewater.
     Both methods of secondary treatment result in discharges with substantially
less organic matter than is produced by primary treatment. City officials having
problems with litigious neighbors downstream were especially eager to adopt this
new technology into their urban water cycles. One of the first trickling filter
facilities in the Nation was constructed in the city of Gloversville, New York, in
                                                                                               2-9

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
                         1907. The motivation was not so much citizen demands in Gloversville for a
                         cleaner river as it was the need to respond to a riparian rights suit filed by the
                         downstream city of Johnstown. Chicago officials also grew tired of their ongoing
                         battle with St. Louis and in 1916 constructed the first activated sludge treatment
                         plant in the Nation (Metcalf and Eddy, 1991).
                              Officials in most other U.S. cities, however, did not have neighbors like
                         Johnstown or St. Louis forcing them to upgrade their wastewater treatment
                         capabilities. Consequently, they were content to embrace a theme reflected in a
                         leading textbook of the time, Sewage Disposal. The authors of the 1919 publica-
                         tion argued that municipal dollars were much better spent on health programs than
                         on sewage purification, and they chided sewage treatment proponents for being
                         unrealistic in their demands.


                         Biochemical Oxygen  Demand (BOD) as  a Measure
                         of Organic  Wasteload Strength

                              One reason communities were slow to adopt secondary treatment into their
                         urban water cycle was perception. There was no way to articulate the link
                         between the organic  wastes in wastewater and DO levels in natural waters. In
                         the 1920s these relationships became clearer with the development of an indicator
                         called the biochemical oxygen demand (BOD). Performed in a laboratory, the
                         BOD test measures the molecular oxygen used during a specific incubation period
                         for the biochemical degradation of organic material, the oxidation of ammonia by
                         nitrification, and the oxygen used to oxidize inorganic chemical compounds such
                         as sulfides and ferrous iron.
                              Historically, the BOD was determined using an incubation period of 5 days
                         at 20 degrees Celsius (QC). For domestic  sewage and many industrial wastes,
                         about 70-80 percent of the total BOD is decomposed within the first five days at
                         this temperature (Metcalf and Eddy,  1991). Because of the incubation period,
                         BOD has been adopted as the shorthand notation for this measurement in the
                         literature. Expressed as a concentration, the BOD5 measurement allows scientists
                         to compare the relative pollution "strength" of different wastewaters and natural
                         waters. The widest application of the BOD5 test, however, is for measuring the
                         strength and rates of wastewater loadings to and from POTWs and evaluating the
                         BOD5 removal efficiency of the treatment system.
                              Because of widespread problems with oxygen depletion in many urban
                         rivers, several states, especially those in the more populated Northeast, Midwest,
                         and far West, took a leadership role in the 1930s to encourage municipalities to
                         upgrade from primary to secondary treatment. By  1950, 3,529 facilities, or about
                         one-third of the 11,784 municipal treatment plants existing at that time, provided
                         secondary treatment for 32 million people. At the same time, however, 35 million
                         people were still connected to systems that discharged raw sewage and 25 million
                         people were provided only primary treatment (USPHS, 1951). Increasing the
                         number of facilities that provided at  least secondary treatment became a national
                         issue as the technology was seen as a solution to the pervasive problem of low
                         levels of DO.
 2-10

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                                   Chapter 2: An Examination of BOD Loadings Before and After the CWA
 C.   The  Federal  Role  in  Implementing

       Secondary Treatment  in the  Nation's

       POTWs

     The story of federal involvement in water pollution control, and specifically
 the secondary treatment issue, is best told in two parts—before and after the
 passage of the Federal Water Pollution Control Act Amendments of 1972, also
 known as the Clean Water Act (CWA). Before 1972 regulatory authority for
 water pollution control rested with the states. Federal involvement was limited to
 cases involving interstate waters. Unfortunately, there was a great diversity
 among the states in terms of willingness to pay the costs of building and upgrading
 POTWs and to enforce pollution control laws.
     At the center of the problem was the idea that water pollution could be
 controlled by setting ambient water quality standards and that states would go
 after dischargers who caused those standards to be violated. In retrospect, this
 approach was an enforcement nightmare for several reasons (WEF, 1997):
     •    The enforcing agency had to prove a particular discharger was causing
         a waterbody to be in violation of the ambient water quality standard.
         This was difficult because waste loads were allocated among all
         dischargers based on methods that were often open to interpretation.
     •    Most of the time, data with which to support the case against a dis-
         charger had to come from the discharger itself. Usually there were no
         independent monitoring programs.
     •    Many waterbodies lacked water quality standards.
     •    There were few civil or criminal penalties that could be levied against
         dischargers who caused water quality standards to be violated.
     As the state-led water quality standards approach continued to fail and
 water quality conditions continued to spiral downward, both water supply and
 water resource users looked to the federal government for leadership and relief.
 The CWA was designed to turn the water pollution  control tables around com-
 pletely, and it did. The following two subsections describe the federal role before
 and after passage of the CWA.


 The Federal Role In  Secondary Treatment Before
 the Clean Water Act

     The public's concern about raw sewage in the Nation's waterways was not
 entirely lost on the U.S. Congress before the turn of the century. Because of the
 U.S. Constitution, however, they felt powerless to act on any water resource
 issue unless it dealt in some way with interstate commerce. Accordingly, the first
 federal legislation dealing with the abatement of water pollution was tied to the
 fact that pollution sometimes got so bad that it impeded navigation. The Rivers
 and Harbors Act of 1890 specifically prohibited the discharge of any refuse or
 filth that would impede navigation in interstate waters. Unfortunately, this act was
greatly "watered down" with the passage of the amended Rivers and Harbors
Act in 1899. It conveniently exempted "refuse flowing from streets and sewers
                                                                                        2-11

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment


                          and passing therefrom in a liquid state" from the navigation impedance prohibition.
                          After the Rivers and Harbors Act of 1899, the Public Health Service Act of 1912
                          authorized the federal government to investigate waterborne disease and water
                          pollution. In 1924 the Oil Pollution Act was enacted to control discharges of oil
                          causing damage to coastal waters.
                              The next few decades were lean ones in terms of federal involvement in
                          water pollution control—but not for lack of effort. Between 1899 and 1948 more
                          than 100 bills about water pollution were introduced. Most languished and died in
                          the halls of Congress. One, sponsored by Senator Alben W. Barkley and Repre-
                          sentative Fred M. Vinson (later Chief Justice of the Supreme Court), actually
                          made it to the President's desk. It, however, received a presidential veto because
                          of budgetary concerns. The 80th Congress finally broke the impasse and enacted
                          The Water Pollution Control Act of 1948. This act, along with five amendments
                          passed between 1956 and 1970, shaped the national vision and defined the federal
                          role regarding the treatment of wastewater in the United States. It also set the
                          stage for passage of the landmark Water Pollution Control Amendments of 1972.
                          Figure 2-4 summarizes the key legislation enacted between 1948 and 1971.

                          The Water Pollution Control Act of 1948, PL 80-845

                              The Water Pollution Control Act of 1948 was significant on three accounts.
                          For the first time Congress accomplished the following:
                              •     Expressed a national interest in abating water pollution for the benefit
                                   of both water supply and water resource customers.
                                   "The pollution of our water resources by domestic  and industrial
                                   wastes has become an increasingly serious problem due to the
                                   rapid growth of our cities and industries. Large  and increasing
                                   amounts of varied wastes must be disposed of from these concen-
                                   trated areas.  Polluted waters menace the public health through the
                                   contamination of water and food supplies, destroy fish and game
                                   life, and rob  us of other benefits of our natural resources."
                                                       — Senate Report No. 462 of the 80th Congress
                                                     Report on the Water Pollution Control Act of 1948

                              •     Established the view that states were primarily responsible for the
                                   control of water pollution and that the federal government's role would
                                   be to provide  financial aid  and technical assistance—a policy concept
                                   that has continued to the present.
                                   "That in connection with  the exercise  of jurisdiction over the
                                   waterways of the Nation  and in consequence of the benefits result-
                                   ing to the public health and  welfare by the abatement of stream
                                  pollution, it is hereby declared to be the policy of Congress to
                                   recognize, preserve, and protect the primary responsibilities and
                                   rights of the  States in controlling water pollution . . . and to pro-
                                   vide . .  . financial aid to  State and interstate agencies and to
                                   municipalities, in the formulation and execution of their stream
                                   pollution programs"
                                                — The Water Pollution Control Act of 1948 (PL 80-845)
2-12

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                                              Chapter 2: An Examination of BOD Loadings Before and After the CWA
Figure 2.4
Timeline of federal water pollution control acts,  1948 -1971.
                         1
   Water  Pollution Control Act of 1948
   The Water Pollution Control Act of 1948 authorized
   the US Public Health Service to develop comprehen-
   sive basin plans for water pollution control and to
   encourage the adoption of uniform state laws. $100
   million of loans annually to municipalities were
   authorized, but no appropriation for treatment
   facilities under this act was ever  made. However,
   the act influenced the states to apply more control
   over the discharge of pollutants into  their waters.
   Water Pollution Control Act of 1961
   Comprehensive programs and plans for water
   pollution abatement and control were still required.
   Grants were limited to 30% of the cost of construc-
   tion or $600,000, whichever was less, or $2.4
   million for multiple municipal plants. At least half of
   the appropriation was to go to cities of 125,000 or
   less. The Congress advocated 85% removal of
   pollutants in the hearings.
                         1
  Clean Water  Restoration  Act of 1966
  The requirements for state water quality standards
  were continued. Each state planning agency
  receiving a grant was to develop an effective,
  comprehensive pollution control plan for a basin.
  The Federal Water Pollution Control Administration,
  in a guideline,  attempted to require states to
  conform to a national uniform standard of second-
  ary treatment or its equivalent. This action was
  challenged and the guideline was not  enforced.
  Secretary Udall stated at House hearings that the
  states had agreed to the requirement for secondary
  treatment. Grants for POTWs are set at 30% with
  an increase to 40% if the state paid 30%. The
  maximum could be increased to 50% if the state
  agreed to pay  25%. A grant could be increased by
  10% if it conformed to a comprehensive plan for the
  metropolitan area. The limitation of $1.2 million and
  $4.8 million for grants was waived if the state
  matched equally all federal grants. At least 50% of
  the first $100 million in annual appropriations had to
  be directed to municipalities of <125,000 people.
1969
              Water Pollution Control Act of 1956
              Grants for assisting in the construction of municipal
              treatment works were authorized and, for the first
              time, funded with federal appropriations. The
              Surgeon General was directed to prepare compre-
              hensive programs for pollution control in interstate
              waters in cooperation with states and municipali-
              ties, and the state was to prepare plans for
              prevention and control of water pollution  If there
              was no approved plan, no grant was to be  made
              for constructing treatment facilities. $50 million
              annually in  grants was authorized. Grants  were
              limited to 30% of the cost of construction, or
              $250,000, whichever was smaller. Legislation in the
              states increasingly required  secondary treatment
              for polluted waters.
              Water Quality Act of 1965
              For the first time, each state, to receive grants, was
              required to have water quality  standards, ex-
              pressed as water quality criteria applicable to
              interstate waters.  If the state did not develop
              standards, the FWPCA was required to do so. To
              comply with these standards and  criteria, second-
              ary treatment was increasingly necessary.
              Construction grants were  raised to 30%  of
              reasonable costs, and an additional 10%  was
              allowed where the project conformed with a
              comprehensive plan for a metropolitan area. At
              least 50% of the first $100 million in appropriations
              had to go to municipalities of less than 125,000
              population. Individual grants were limited to $1.2
              million, with a limit of $4.8 million for multiple
              municipalities.
                                     1
Water Quality Improvement  Act of 1970
The Water Quality Improvement Act of 1970 did not
contain  any new provisions regarding required
standards. The requirements for state water  quality
standards were continued. However, in  hearings
for the act, the authority of EPA to require uniform
treatment limitations for discharges, such as
secondary treatment,  was questioned.
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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment


                                   Developed activities that required states and the federal government to
                                   work as partners in solving pollution problems in interstate waters.
                               The act set forth a loan program designed to provide  up to $ 100 million per
                          year for states, municipalities, and interstate agencies to construct needed waste-
                          water treatment works. Each loan was not to exceed $250,000 and was to bear
                          an interest rate of 2 percent. Unfortunately, the loan program never saw the light
                          of day because the program was never funded.
                               More successful, however, were the partnership programs developed
                          between the states and the U.S. Public Health Service. The act required the
                          Surgeon General to
                               •    Work with states and municipalities to prepare and adopt comprehen-
                                   sive programs for eliminating or reducing the pollution of interstate
                                   waters and improving the sanitary conditions of surface and under-
                                   ground waters.
                               •    Encourage the enactment of uniform state laws relating to the preven-
                                   tion and control of water pollution.
                               •    Take action against polluters of interstate waters, with the consent of
                                   the  affected state.
                               In 1952 the Congress acknowledged that these partnership efforts were
                          paying off and passed Public Law 82-579, which extended the activities autho-
                          rized by the 1948 act for another 4 years. In 1955 the  Senate issued a report that
                          stated that the act caused more than half the states to improve their pollution
                          control  legislation and programs to better protect their water resources (Sen. Rep.
                          No. 543, 84th Congress). The report also noted that some states were establishing
                          water quality standards so stringent that they left municipalities with no choice but
                          to implement secondary treatment at their facilities.

                          The Water Pollution Control  Act of 1956, PL 84-660

                               This act was significant because it authorized a grant program for the
                          construction of wastewater treatment facilities—and then actually funded it. A
                          total of $150 million was earmarked over the life of the program with a provision
                          that no more than $50 million could be spent per year.  Individual grants were not
                          to exceed 30  percent of the reasonable cost of construction, or $250,000, which-
                          ever was smaller. There was one important caveat to obtaining a grant, however:
                          to be funded, the project must be in conformity with a plan prepared by the  state
                          water pollution control agency and approved by the Surgeon General.
                                Though language in the act emphasized that the law should not be "con-
                          strued as impairing or in any manner affecting any right or jurisdiction of the
                          States with respect to the waters (including boundary waters) of such States," the
                          requirement for federal approval of a state's water pollution control plan nonethe-
                          less established a new leadership role for the federal government. If a state did
                          not follow an approved plan, grant payments could be held up pending an appeal
                          to a federal court.
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                                     Chapter 2: An Examination of BOD Loadings Before and After the CWA
The Federal Water Pollution Control Act of 1961, PL 87-88

     Only a few changes were made in the 1961 amendment to the Federal
Water Pollution Control Act. Congress's basic intent with this legislation was to
extend the act through to  1967. Construction grants were authorized to the states
in the total amount of $60 million for FY 1962, $90 million for FY 1963, and $100
million for each of the fiscal years 1964 through 1967.
     A grant to a municipality was limited to $600,000 or 30 percent of the
reasonable costs, whichever was less, with a limit of $2.4 million when the project
would  serve more than one municipality. At least one-half of the funds appropri-
ated for projects were to go to cities of 125,000 population or less. The require-
ments for comprehensive pollution control programs and plans were carried over
from the  act of 1956.
     Perhaps the most interesting development concerning federal involvement in
water pollution control appeared not in the act itself, but in language contained in
the accompanying Senate report. Here, for the first time, the Senate mentioned its
desire to  see secondary treatment used in municipal waste treatment plants. The
same document also presented a vision for the future and an expression of hope
for completion of the urban water cycle:
     "There is every reason to believe that a vigorous research attack
    on waste treatment problems would lead to breakthroughs and new
    processes which will make it possible to handle ever-increasing
    wasteloads,  and even to restore streams to a state approaching
    their original natural purity . . . If all waste or all water deteriorat-
    ing  elements could be removed  by treatment, a region's water
    supply  could be used over and over. "
                                — Senate Report No. 353, 87th Congress
                        Report on the Water Pollution Control Act of 1961

The Water Quality Act of 1965, PL 89-234

     Two important elements were established with the passage of the Water
Quality Act of 1965. First, it created the Federal Water Pollution Control Adminis-
tration (FWPCA) as a separate entity in the Department of Health, Education and
Welfare.  FWPCA did not  reside there  long, however. In 1966 it was transferred
to the Department of the Interior. Then, in  1970, its functions were folded into the
new United  States Environmental Protection Agency (USEPA).
     Second, the act required each state desiring a grant to file a letter of intent
with the FWPCA committing the state to establishing, before June 30, 1967,
water quality criteria applicable to interstate waters and submitting a plan for the
implementation and enforcement of water quality criteria. If the state  chose not to
do this, the FWPCA would do it for the state.
     The state's criteria and plan were to be the water quality standards for its
interstate waters  and tributaries. The act mandated that these standards must
protect the public health or welfare and enhance the quality of water.  Consider-
ation was also to  be given to the use and value of public water supplies, propaga-
tion offish and wildlife, recreational purposes, and agricultural, industrial, and
other legitimate needs.
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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment


                              The construction grants program was continued in this act. The federal
                          contribution was raised to 30 percent of the reasonable costs, plus an additional 10
                          percent when the project conformed with the comprehensive plan for a metropoli-
                          tan area. The authorized amounts for construction grants were set at $150 million
                          for FY 1966 and FY 1967, with at least 50 percent of the first $100 million
                          appropriated in those years used for grants for municipalities of 125,000 people or
                          less. Grants to municipalities were limited to $1.2 million, with $4.8 million set as
                          the limit when two or more municipalities were served by the same facility.

                          The Clean Water Restoration  Act of 1966, PL 89-753

                              Basin planning was a key focus of the  Clean Water Restoration Act of 1966.
                          Each state planning agency receiving a grant had to develop an effective compre-
                          hensive pollution control and abatement plan for basins. A basin was defined as
                          rivers and their tributaries, streams, coastal waters, sounds, estuaries, bays, lakes,
                          and portions thereof, as well as the lands drained thereby. Congress mandated
                          that the plan must:
                              •     Be consistent with water quality standards.
                              •     Recommend effective and economical treatment works.
                              •     Recommend maintenance and improvement of water quality standards
                                   within the basin, as well as methods for financing necessary facilities.
                              Grants for wastewater treatment facilities were set at 30 percent of the
                          reasonable cost, which could be increased to 40 percent if the state agreed to pay
                          not less than 30 percent of the reasonable costs. This maximum could be in-
                          creased to 50 percent if the state agreed to pay not less than 25 percent of the
                          estimated reasonable costs of all such grants. A grant could also be increased by
                          10 percent of the amount of a grant if it was in conformance with a plan devel-
                          oped for the metropolitan area. To be eligible for any grant a project must be
                          included in a comprehensive water pollution program and the state water pollution
                          control plan. Grants were again limited to $1.2 million for individual projects and
                          $4.8 million for multi-municipal projects. This limitation was waived, however, if
                          the state agreed to match equally all federal grants made for the project.
                              Authorized amounts for grants gradually increased from a total of $550
                          million for FY 1968 to $ 1.250 billion for FY  1971. The total of $2 billion was
                          authorized for FY 1972 by the Extensions of Certain Provisions of the Federal
                          Water Pollution Control Act of 1971, PL 92-240.

                          The Water Quality Improvement Act of 1970, PL 91-224

                               On March 18, 1968, FWPCA announced that the water quality standards of
                          28 states had been approved, and all of the  states were expected to have ap-
                          proved standards by June. Soon afterwards, however, FWPCA attempted to
                          cause states to amend their standards to include an effluent limitation of "best
                          practicable treatment" or its equivalent for all discharges:
                              'Wo standards shall be approved which allow any waste amenable
                              to treatment or control to  be discharged into any interstate water
                              without  treatment or control regardless of the water quality criteria
                              and water use or uses adopted.
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                                     Chapter 2: An Examination of BOD Loadings Before and After the CWA
     Further, no standard will be approved which does not require all
     wastes, prior to discharge into any interstate water,  to receive the
     best practicable treatment or control unless it can be demonstrated
     that a lessor degree of treatment or control will provide for water
     quality and  enhancement commensurate with proposed present  and
    future water uses."
                                            —FWPCA Guideline,  1968
     People questioned what authority the FWPCA thought they had to  set "best
practicable treatment" as the minimum level of treatment and what they  meant by
that term. In House hearings leading up to the Water Quality Improvement Act of
1970, Secretary Udall explained that "in practice, this guideline usually, but not
always, means secondary treatment of municipal wastes . . . generally the States
have agreed with  us with regard to the requirement of secondary treatment." A
number of officials from different states begged to differ with Secretary  Udall
and FWPCA's guideline. Not surprisingly, states offered up legal opinions that
bluntly concluded that the FWPCA had no authority to set discharge limitations.
     Against this backdrop, the Water Quality Improvement Act of 1970 was
passed. The act continued the authority of the states to set standards of  water
quality and the authority of the FWPCA to approve such standards. Congress,
however, chose not to include any new provisions regarding standards or treat-
ment levels.
     Deciding that the battle for secondary treatment in municipal wastewater
plants would be best fought on another stage, the FWPCA stepped back and
issued a new construction grant regulation (36 FR  13029) in July  1971 that called
for primary treatment as the minimum level of treatment:
     "To be eligible for a grant, a project must be designed to result  in
     an operable  treatment works, or part thereof, which  will treat or
     stabilize sewage or industrial wastes of a liquid nature in order to
     abate, control, or  prevent water pollution .  . . such treatment or
     stabilization  shall consist of at least primary treatment, or its
     equivalent, resulting in the substantially complete removal of
     settleable solids."
                              — FWPCA Construction Grant Regulation
                                               July 1971 (36 FR 13029)
     After the FWPCA was reorganized  out of existence, USEPA aggressively
picked up the secondary treatment torch. In June 1972, prior to the passage  of the
Federal Water Pollution Control Act of 1972 in October, the Agency issued
regulations that required grant projects to conform to secondary treatment
requirements that  included the removal of 85 percent of BOD5 from POTW
influent.
     The Agency ruled that secondary treatment could be waived only for
projects that:
    •    Discharged wastes to open ocean waters through an ocean outfall if
         such discharges would not adversely affect the open ocean waters and
         adjoining shores, and receive primary treatment before discharge.
    •    Treated or controlled combined sewer overflows if such projects were
         consistent with river basins or metropolitan plans to meet approved
        water quality standards.
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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment


                          The  Federal Role in Secondary  Treatment After the
                          Clean  Water Act

                              Enactment of the 1972 Amendments to the Federal Water Pollution Control
                         Act, now popularly known as the Clean Water Act (CWA), by the 92nd U.S.
                         Congress redirected national policy for water pollution control onto a new path.
                         Sparked by publication of Rachel Carson's Silent Spring in 1962 (Carson, 1962),
                         national publicity about environmental issues during the 1960s led to public
                         awareness of the existence of nationwide air and water pollution problems and
                         political demands by the "Green Movement" for governmental action to address
                         pollution problems (Zwick and Benstock, 1971; Jobin, 1998).
                              On October 18,  1972, a new era for POTWs began when the 1972 Amend-
                         ments to the Federal Water Pollution Control Act (PL 92-500) were unanimously
                         passed by the U.S. Congress and, despite a veto by President Richard M. Nixon,
                         who thought that the $24 billion investment over 5 years was "excessive and
                         needless overspending," the act became law (Knopman and Smith, 1993). The
                         act established a new national policy that firmly rejected the historically accepted
                         use of rivers, lakes, and harbors as receptacles for inadequately treated wastewa-
                         ter. Congress's objective was clear. They wanted to "restore and maintain the
                         chemical, physical and biological integrity of the nation's waters" and to attain
                         "fishable and swimmable" waters throughout the Nation. With PL 92-500, the
                         federal government took control of directing and defining the Nation's water
                         pollution control programs. This commitment led to the completion of the urban
                         water cycle in many communities across the United States.
                              Congress recognized that success or failure of PL 92-500's lofty objectives
                         hinged on a combination of money, compliance, and enforcement. Consequently,
                         the basic framework of the act included the following.
                             •    Establishment of the National Pollutant Discharge Elimination System
                                  (NPDES), a program that requires that every point source discharger
                                  of pollutants obtain a permit and meet all the applicable requirements
                                  specified in regulations issued under sections 301 and 304 of the act.
                                  These permits are enforceable  in both federal and state courts,  with
                                  substantial penalties  for noncompliance.
                             •    Development of technology-based effluent limits, which serve as
                                  minimum treatment  standards to be met by dischargers.
                             •    An ability to impose more stringent water quality-based effluent limits
                                  where technology-based limits are inadequate to meet state water
                                  quality standards or objectives.
                             •    Creation of a financial assistance program to build and upgrade
                                  POTWs. PL 92-500 authorized $5.0 billion in federal spending for fiscal
                                  year 1973, $6.0 billion for fiscal year 1974, and $7.0 billion for fiscal
                                  year 1975. In contrast, the year before the act was passed, a total of
                                  $1.25 billion (federal dollars) was spent. Under the construction grants
                                  program, the federal share was 75 percent of cost from fiscal years
                                  1973 to 1983 and 55 percent thereafter. Additional funds were made
                                  available for projects using innovative and alternative treatment pro-
                                  cesses.
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                                     Chapter 2: An Examination of BOD Loadings Before and After the CWA
     The story of the Clean Water Act and its evolution from 1972 to the present
 day is richly complicated. The purpose of this section is not to summarize all
 aspects of this landmark act. Rather, the objective is to focus on the role it played
 in implementing secondary treatment in the Nation's POTWs. Other sources,
 such as The Clean Water Act, 25th Anniversary Edition, published by the
 Water Environment Federation (WEF, 1997), should be consulted for a complete
 overview of the act. Figure 2-5 summarizes the key amendments and regulations
 that occurred from 1972 to the present.

 The Water Pollution Control Act Amendments of 1972 (PL 92-
 500) and Secondary Treatment Information (38 FR 22298-
 22299), published in final on August 17,1973

     After debating the merits of secondary treatment for the better part of two
 decades, Congress finally put the issue to rest in the Federal Water Pollution
 Control Act Amendments of 1972. Section 301 required POTWs to achieve
 effluent limitations based on secondary treatment.
     A simple, aggressive schedule was set to meet this requirement. By July 1,
 1977, all existing POTWs and all facilities approved for construction before
 June 30,  1974, must incorporate secondary treatment. Then, by July 1, 1983,
 POTWs must meet an additional level of treatment described in the act as "best
 practicable wastewater treatment."
     While developing the  1972 Amendments, Congress understood that the term
 secondary treatment needed to be carefully researched and clearly articulated
 before regulations could be  drafted. At the time, several "working" definitions
 existed, including one offered by Congressman Vanik in the House debate on the
 amendment.  He defined secondary treatment as a process that removes 80  to 90
 percent of all harmful wastes from POTW influent.
     Section 304(d)(l) directed USEPA to investigate and publish in the Federal
 Register "information, in terms of amounts of constituents and chemical, physical
 and biological characteristics of pollutants, on the degree of effluent reduction
 attainable through the application of secondary treatment." USEPA assembled a
 work group the next year to accomplish this task and invited outside commenta-
 tors and contractors to participate.
     Early on, the group decided that the effluent limitations to be used to define
 secondary treatment needed to include concentrations of key parameters as well
 as percent reduction limits. Also weighing in on the minds of the group was  a
 congressional and public concern that if percent removal  targets were set too
 high, incremental environmental benefits would not be worth the cost. Conse-
 quently, economic considerations became an important part of the decision-
 making process. Figure 2-6  is an example of how costs were analyzed in relation
 to percent removal targets for BOD5. The graph shows that costs rise rapidly
 beyond the 85 to 88 percent removal level. Analyses such as these helped the
 work group put technical capabilities in a practical (i.e., economical) context.
    In April 1973 USEPA published a proposed regulation based on the group's
report. After comments were addressed, the Agency issued its final regulation on
August 17, 1973. It defined  secondary treatment effluent concentration limits for
the following parameters:
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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
Figure 2.5: Timeline of federal water pollution control acts, 1972 -1996
   Federal  Water Pollution  Control Act Amend-
   ments of 1972
   The Federal Water Pollution Control Act of 1972
   (later to be renamed the Clean Water Act)
   contained the first statutory requirement for a
   minimum of secondary treatment by all POTWs.
   The act also established the National Pollutant
   Discharge Elimination System (NPDES), under
   which every discharger of pollutants was  required
   to obtain a permit. Under the permit each POTW is
   to discharge only effluent that had received
   secondary treatment. EPA defined secondary
   treatment in a regulation as attaining an effluent
   quality of at least 30 mg/L BOD5, 30 mg/L TSS, and
   85% removal of these pollutants, in a period of 30
   consecutive days.
   Clean Water Act Amendments of 1981,  PL 97-
   117
   The Clean Water Act Amendments of 1981
   amended the Clean Water Act to the effect that
   "such biological treatment facilities as oxidation
   ponds, lagoons and ditches and trickling filters
   shall be  deemed the equivalent of secondary
   treatment." EPA is directed to provide guidance on
   design criteria for such facilities, taking into
   account  pollutant removal  efficiencies and
   assuring that water quality will  not be adversely
   affected  (Sec. 304(d)(4)). Regulations to this
   effect were published in final on September 20,
   1984. Also, a notice was issued to solicit public
   comments on "problems related to meeting the
   percent removal requirements and on five options
   EPA was considering for amending the percent
   removal  requirements.
                        I
   Secondary Treatment  Regulations,
   January 27, 1989
   This secondary treatment regulation allows
   adjustments for dry weather periods for POTWs
   serving combined sewers.
Clean Water Act Amendments of 1977
The Clean Water Act Amendments of 1977 created
the 301 (h) program, which waived the secondary
treatment requirement for POTWs discharging to a
marine environment if they could show that the
receiving waters  would not be  adversely affected.
Extensive requirements had to be met before such
a waiver could be issued.
                                                                                           1
 National Municipal Policy, January 30, 1984
 The EPA National Municipal Policy was published
 on January 30, 1984. It was designed to ensure
 that all POTWs met the compliance deadlines for
 secondary or greater treatment of discharges. The
 key to the policy is that it provides for POTWs that
 had not complied by the July 1,1988, deadline to be
 put on enforceable schedules. The  policy has
 been outstandingly successful and  has resulted in
 significant increases in compliance.
Secondary  Treatment  Regulations,  June 3,
1985
The secondary treatment regulation published in
final on June 3, 1985, revised the previous
regulations published in Title 40, Part  133, of the
Code of Federal Regulations  Specifically, on a
30-day average, the achievement of not less than
85% removal of BOD5, CBOD5 and suspended
solids for  conventional secondary treatment
processes was required.  However,  for  those
treatment  processes designated  by the Congress
as  being equivalent to secondary treatment (such
biological treatment facilities as oxidation ponds,
lagoons, and ditches, and trickling filters), at least
65% pollution removal was required,  provided that
water quality was  not adversely affected. Waste
stabilization  ponds were given separate sus-
pended solids  limits. Special consideration was
provided for various influent conditions and
concentration limits.
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                                    Chapter 2: An Examination of BOD Loadings Before and After the CWA
           36.5
               70
                         BODs Removal Efficiency (%)
     •    5-day biochemical oxygen demand (BOD5). Average value for
         BOD5 in effluent samples collected in a period of 30 consecutive days
         shall not exceed 30 milligrams per liter (mg/L). The average value for
         BOD5 in effluent samples collected in a period of 7 consecutive days
         shall not exceed 45 mg/L.
     •    Total suspended solids (TSS). Average value for TSS in effluent
         samples collected in a period of 30 consecutive days shall not exceed
         30 milligrams per liter (mg/L). The average value for TSS in effluent
         samples collected in 7 consecutive days shall not exceed 45 mg/L.
     •    Fecal coliform bacteria. Geometric  mean of fecal coliform bacteria
         values for effluent samples collected in a period of 30 consecutive days
         shall not exceed 200 per milliliter (mL). The geometric mean of fecal
         coliform bacteria values for effluent samples collected in a period of 7
         consecutive days shall not exceed 400 per milliliter (mL).
     •    pH. Effluent values for pH shall remain within the limits of 6.0 and 9.0.
     Also included were percent removal limits for BOD5and TSS. Specifically,
average values for BOD5 and TSS in effluent samples collected in 30 consecutive
days may not exceed 15 percent of the mean of influent samples collected at
approximately the same times during the same period (85 percent removal).
     The BOD and TSS limits were chosen based on an assumption that the
wastewater entering a POTW (influent) contains about 200 mg/L of BOD5 and
TSS. Knowing this assumption did not hold true in every case, USEPAmade a
couple of allowances. Specifically, the Agency allowed a POTW to have higher
BOD5 and TSS concentrations in its effluent if the facility received more than 10
percent of its design flow from industrial facilities for which less stringent effluent
limitations had been promulgated.
     Special consideration was also given, on a case-by-case basis, to treatment
works served by combined storm and sanitary sewer systems where increased
flows during wet weather prevented the attainment of the defined minimum level
of secondary treatment. Of chief concern was the 85 percent removal require-
                                                                           Figure 2-6
                                                                           Cost versus BOD5
                                                                           removal efficiency of
                                                                           a new 1  million gallon
                                                                           per day POTW.
                                                                           Source: USEPA,  1973.
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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment


                         merit. In stormy weather, storm water runoff dilutes the normal volume of influ-
                         ent, lowering BOD5 and TSS concentrations. Expecting to reduce already re-
                         duced concentrations by 85 percent was beyond the means of many facilities.
                              Two subsequent amendments to the secondary treatment information were
                         promulgated on July 26, 1976 (41 FR 30788) and October 7, 1977 (42 FR 5665).
                         These changes provided for:
                              •   Deletion of the fecal  coliform bacteria limitations and clarification of
                                  the pH requirement.
                              •   Special consideration for the TSS effluent limitations applicable to
                                  waste stabilization ponds with wastewater flows of less than 2 million
                                  gallons per day (mgd).
                              Publishing the regulation defining the minimum level of secondary treatment
                         to be implemented by POTW facilities by 1977 was a major accomplishment for
                         USEPA. On the horizon, however, loomed the prospect of developing a second,
                         more stringent, level of requirements for implementation by July 1,1983. Con-
                         gress fortunately realized that this second set of requirements, or best practicable
                         treatment, might not be needed. Section 315(b) of PL 92-500 established a
                         national study commission to help them make this determination. Composed of
                         five Senators, five Representatives, and five members of the public, the commis-
                         sion was given 3 years to accomplish this task. In the end, the group issued
                         several general recommendations, one of which was that the secondary  treatment
                         effluent limits  developed for the 1977 deadline not be changed for the 1983
                         deadline. Essentially, the commission determined that secondary treatment was
                         the best practicable treatment  for POTWs. Thus, the headaches associated with
                         setting a second level of requirements were avoided.

                         The Clean Water Act Amendments of 1977 (PL 95-217)

                               The tight timetable Congress established for implementing secondary
                         treatment proved to be unrealistic for many municipalities. In fact, only about 30
                         percent of major POTWs (those processing 1 million (or more) gallons of waste-
                         water per day) were in compliance when the July 1, 1977, deadline rolled around.
                         In many cases, upgrade schedules were slowed due to delays in receiving federal
                         funds. The Clean Water Act Amendments of 1977 (PL 95-217) responded to this
                         situation by allowing time extensions for municipalities encountering funding
                         problems.
                               Time extensions aside, probably the most significant aspect of PL 95-217 in
                         terms of secondary treatment  was the fact that Congress backed off from PL 92-
                         500's original  objective of having all POTWs implement secondary treatment as a
                         minimum technology-based standard. Municipalities discharging into ocean waters
                         had been arguing that the benefits associated with their upgrading to secondary
                         treatment were not worth the cost. The vastness of the marine environment, they
                         said, effectively dilutes and incorporates wastes into the water and sea bottom
                         without harming uses or the environment.
                               Congress agreed and added Section 301(h) to the Clean Water Act, allowing
                         marine dischargers to apply for a waiver of secondary treatment requirements.
                         EPA would subsequently review the application and issue modified NPDES
                         permits to POTWs that met certain environmental criteria and received state
                         concurrence. These criteria  included


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                                    Chapter 2: An Examination of BOD Loadings Before and After the CWA
    •    Existence of and compliance with water quality standards.
    •    Protection and propagation of a balanced indigenous population of fish,
         shellfish, and wildlife.
    •    Allowance of recreational activities.
    •    Establishment of a monitoring program.
    •    Satisfactory toxics control programs, including an approved industrial
         pretreatment program.
    •    No additional treatment requirements for other sources.
    •    Acceptable discharge volume and pollutant limits.
    •    Protection of public water supplies (desalinization plants).

Municipal Wastewater Treatment Construction Grants
Amendments of 1981  (PL 97-117) and Secondary Treatment
Regulations (49 FR 36986-37014), published in final on
September 20, 1984

     When the decade of the 1980s dawned, the goal of implementing secondary
treatment in the Nation's POTWs seemed a long way off. About half of the
20,000 municipal discharges, including more than 100 larger cities, were still not in
compliance with the 1977 deadline. Construction projects were bogged down with
funding problems, complicated regulatory procedures, and lack of staff at state
and federal agencies. To address these and other problems, Congress passed the
Construction Grants Amendments of 1981. Section 301(i) recognized that funding
issues were still holding up secondary treatment  compliance and therefore
extended the implementation deadline to July 1,  1988, on a case-by-case basis.
     PL 97'-117 and its companion regulations also addressed another concern
involving USEPA's definition of secondary treatment effluent requirements. In
theory, the requirements were not intended to favor one treatment process  over
another, yet they did. As it turned out, activated sludge facilities were the only
ones that could consistently meet the requirement of 85 percent removal of BOD5
and TSS limits. This situation caused an immediate problem for the many smaller
communities that had invested in trickling filters,  waste stabilization ponds, and
other types of biological wastewater treatment. Even when their facilities per-
formed as designed, they were in noncompliance according to USEPA's standards
for secondary treatment.
     Upgrading or replacing these facilities was  an expensive proposition. Many
questioned whether environmental benefits gained would be worth the cost.
Congress agreed and PL 97-117 and its companion regulations included the
following:
    •    Introduced the concept of "equivalent  of secondary treatment" to
         describe facilities that use a trickling filter or waste stabilization pond as
         a principal treatment process and which were not meeting the second-
         ary treatment requirements as promulgated by USEPA in 1973.
    •    Lowered the minimum level of effluent quality to be achieved by those
         facilities during a 30-day period as an  average value not to exceed 45
         mg/L for BOD5 and TSS, an average 7-day value for BOD5 and TSS of
         not to exceed 65 mg/L, and a percentage removal of those constituents
         of not less than 65 percent (30-day average).
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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
                             •   Required that NPDES permit adjustments for "equivalent to secondary
                                 treatment" facilities reflect the performance or design capabilities of
                                 the facility and ensure that water quality is not adversely affected.

                         National Municipal Policy (49 FR 3832-3833), published on
                         January 30,1984

                              Continually pushing back the deadline for implementation of secondary
                         treatment in POTWs created confusion. The 1972 Amendments had set the
                         original deadline for compliance for 1977. For some municipalities, it was extended
                         to 1983 by PL 95-217 and then to 1988 by PL 97-117. The USEPA National
                         Municipal Policy, published in the Federal Register on January 30, 1984, was
                         designed to eliminate this confusion and ensure that all POTWs would comply
                         with the statutory requirements and compliance deadlines in the Clean Water Act.
                         It also established that where there were extraordinary circumstances that
                         precluded compliance by the July 1,1988, deadline, POTWs would be put on
                         enforceable schedules designed to achieve timely compliance. The policy de-
                         scribed EPA's intentions to focus its efforts on
                             •   POTWs that previously received federal funding assistance and are not
                                 in compliance.
                                 Other POTWs.
                             •   Minor POTWs (less than 1 mgd capacity) that are contributing signifi-
                                 cantly to impairment of water quality.
                              This municipal treatment policy has been outstandingly successful, with over
                         90 percent compliance achieved to date for  major POTWs (1 mgd or over).

                         Secondary Treatment Regulations, published in final on
                         June  3,1985

                              The secondary treatment requirement  of 85 percent removal of BOD5 and
                         TSS continued to present problems for POTWs receiving diluted influent waste-
                         water. Whether it was a secondary treatment facility (85 percent removal) or an
                         equivalent of secondary treatment facility (65 percent removal), to stay in compli-
                         ance a facility had to install advanced technology, even if it consistently met its
                         concentration limits. Recognizing this problem, USEPA on November 16, 1983,
                         published a Federal Register notice soliciting public comment on a number of
                         options for amending the percent removal requirements.
                              Based on the public comments received, the Agency proposed and then
                         finalized a revised Secondary Treatment Regulation. Published in final on June 3,
                         1985, it authorized USEPA to lower the percent removal requirement, or substi-
                         tute a mass limit for the percent removal requirement, for certain POTWs. The
                         Agency would make this determination on  a case-by-case basis based on the
                         removal capability of the treatment plant, the influent wastewater concentration,
                         and the infiltration and inflow situation.
                              Treatment plants could apply for a permit adjustment in its percent removal
                         limit only if
                                  The treatment plant is meeting or will consistently meet its other permit
                                  effluent concentration limitations, but its percent removal requirements
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                                    Chapter 2: An Examination of BOD Loadings Before and After the CWA
         cannot be met due to less concentrated influent wastewater for sepa-
         rated  sewers.
         To meet the percent removal requirement, the treatment works would
         have to meet significantly more stringent concentration-based limita-
         tions.
     •    The less concentrated influent wastewater to the treatment works was
         not a result of excessive infiltration and inflow.
     The concentration limits in the permit would remain unchanged, and in no
case was a permit to be adjusted if the permitting authority determined that
adverse water quality impacts would result from a change in permit limits.

Amendment to the Secondary Treatment Regulation, published
in final on January 27,1989 in the Federal Register

     The Secondary Treatment Regulation published in June 1985 addressed the
problem POTWs with  separate sewers had in meeting percent reduction stan-
dards due to the dilution of influent wastewater by wet weather conditions. The
city of New York also had a problem. Its combined sewer system delivered
diluted influent to city POTWs, even during dry weather. Consequently, the city
petitioned to be eligible for adjustments of percent removal requirements, too,
arguing that nonexcessive infiltration can dilute the influent wastewater of treat-
ment works served by  combined sewers just as it does for treatment works
served by separate sewers. USEPA agreed with this position and published an
amendment to the regulation on January 27, 1989, to allow for percent removal
adjustments during dry weather periods for POTWs with combined sewers. To
obtain this adjustment the treatment works had to satisfy three conditions:
         It must consistently meet its permit effluent concentration limitations,
        but the percent removal requirements cannot be met due to less
        concentrated influent wastewater.
     •    Significantly more stringent effluent concentration than those required
        by the concentration-based standards must be met to comply with the
        percent removal requirements.
     •   The less concentrated influent wastewater must not result from either
        excessive infiltration or clear water industrial discharges to the system.
     Regarding the last condition, the regulation established that if the average
dry weather base flow (i.e., the total of the wastewater flow plus infiltration) in a
combined sewer system is less than 120 gallons per day per capita (gpcd) thresh-
old value, infiltration is assumed to be nonexcessive. However, sewer systems
with average dry weather flows greater than 120 gpcd might also have
nonexcessive infiltration if this is demonstrated on a case-by-case basis. An
applicant, therefore, has an opportunity to demonstrate that its combined sewer
system is not subject to excessive infiltration even if the average total dry weather
base flow exceeds  the 120 gpcd threshold value.
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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment


                         D.   Nationwide Trends  in  BOD Loading

                               Based  on  Population  and  POTW

                              Treatment Design

                             From 1940 to the present day, the combination of advancing wastewater
                         treatment technology, increased public concern, various state wastewater treat-
                         ment regulations, and, finally, the 1972 CWA secondary treatment mandate
                         resulted in an increased number of POTWs with at least secondary and, in many
                         cases,  greater than secondary levels of treatment. Table 2-2 presents descriptions
                         of the six major types of treatment found at POTWs along with their correspond-
                         ing design-based BOD5 removal efficiency1 (expressed as percent removal).
                             The total population in the United States grew rapidly in the latter half of the
                         20th century, increasing from around 140 million people in 1940 to about 270
                         million in 1996 (see Figure 2-2). This population growth meant POTWs not only
                         had to upgrade their treatment processes to increase pollutant removal efficiency,
                         but they had to accomplish it while dealing with increasing influent wastewater
                         loads. This section examines trends concerning the Nation's expansion and
                         upgrades of POTWs and analyzes how increased use of secondary and greater
                         than secondary treatment after the 1972 CWA affected the rate of effluent BOD
                         loading to the Nation's waterways. Specifically examined are the following:
                             •    The inventory of POTWs in the United States.
                             •    The number of people served by those POTWs and the amount of
                                 wastewater flow they generated.
                                 The rate of BOD entering POTWs (influent loading).
                             •    The rate of BOD discharged by POTWs into receiving waterways
                                 (effluent loading).
                             •    BOD removal efficiency of POTWs
                             •    Proj ections of effluent BOD loading into the 21 st century.
                             The information sources for this study include municipal wastewater inven-
                         tories published by the U.S. Public Health Service from 1940 through 1968
                         (USPHS, 1951; NCWQ,  1976; USEPA, 1974) and USEPA's Clean Water Needs
                         Surveys (CWNS) conducted from 1973 through 1996 (USEPA, 1976, 1978, 1980,
                         1982, 1984, 1986, 1989, 1993, 1997). Many of these sources categorize their
                         information by the six types of wastewater treatment described in Table 2-2.
                         Some sources, however, combine primary and advanced primary data and report
                         it simply as "less than secondary" treatment data. Similarly, data for advanced
                         secondary and advanced wastewater treatment are combined and reported as
                         "greater than secondary" treatment data. To keep the categories consistent, this
                         convention was followed in the analyses presented in this  section.
                            Designed-based BOD5 removal efficiencies are minimum requirements typically assigned by
                            NPDES permits according to the treatment process and treatment plant design assumptions
                            (Metcalf and Eddy, 1991). Generally, they represent conservative estimates of BOD5 removal
                            efficiencies. Many modern POTWs report a higher rate of BOD5 removal than their permitted
                            rate. This study, however, focuses on designed-based BOD5 removal efficiencies because it is
                            assumed that these conservative rates would provide a more effective and consistent
                            comparison of BOD5 removal over the entire historical period of record used in the analysis.
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                                         Chapter 2:  An Examination of BOD Loadings Before and After the CWA
 Table 2-2.  Six levels of municipal wastewater treatment.


  Treatment          Design BODS
    Type          Removal Efficiency  Description
     Raw
                   0%
Wastewater is collected and discharged to surface waters without treatment,
or removal, of pollutants from the influent stream.
   Primary
                   35%
Incorporates physical processes of gravitational settling to separate settleable
and floatable solids material from the raw wastewater. The removal of
settleable solids results in the removal of pollutants associated with solid
particles such as organic matter, nutrients, toxic chemicals, heavy metals, and
pathogens. Other physical processes such as fine screens and filters can also
be used.
  Advanced
   Primary
                   50%
Enhancement of the primary clarification process using chemical
coagulants such as metal salts and organic polyelectrolytes.
  Secondary
    Activated sludge
    Waste stabilization
     ponds

   •  Trickling filters
Advanced Secondary
                   85%          Biological processes are added to break down organic matter in the primary
                                effluent by oxidation and production of bacterial biomass. Biological waste
                                treatment systems, based on bacterial decomposition of organic matter, can be
                                classified as activated sludge, waste stabilization ponds (suspended bacterial
                                growth), and trickling filters (attached bacterial growth). 84 to 89 percent
                                removal of TSS and 30 mg/L effluent concentration for BOD5 and TSS.
                                Involves the use of bacteria to decompose suspended solids in the sewage so
                                that they can be settled out. Oxygen to speed the bacteriological process is
                                generated by mechanical aeration or by the infusion of additional oxygen. The
                                solids produced (sludge) by the biological action are settled out and removed,
                                except for a portion of the bacteria-rich sludge that is returned to the head of
                                the secondary treatment process to activate the biological processes to treat
                                sewage. This is the standard method of treatment for medium and large cities.
                                Pools in which mechanical aeration is used to supply oxygen to
                                the bacteria. In other processes, oxygen is supplied by natural surface aeration
                                or by algae photosynthesis with no  mechanical aeration.
                                Employs a bed of highly permeable media such as crushed stone or plastic to
                                which are attached microcosms for treating sewage sprayed on the media by a
                                mechanical arm.
                   90%          The conventional secondary treatment process incorporates chemically
                                enhanced primary clarification and/or innovative biological treatment processes
                                to increase the removal efficiency of suspended solids, BOD, and total
                                phosphorus. Sludge production is typically increased overall as a result of the
                                chemical enhancement of primary clarification and biological processes.
                                Effluent concentrations of BOD5 range from 10 to 30 mg/L and processes
                                included to remove ammonia and phosphorus in excess of effluent levels
                                typical for secondary treatment.
Advanced Wastewater     95%
Treatment
                                Advanced wastewater treatment (AWT), or tertiary treatment, facilities
                                are designed to achieve high rates of removal of nutrients (nitrogen or phos-
                                phorus), BOD, and suspended solids. Nitrogen removal is achieved by en-
                                hancement of the biological processes to incorporate nitrification (ammonia
                                removal) and denitrification (nitrate removal). Phosphorus removal is accom-
                                plished by either chemical or biological processes. Addition of high doses of
                                metal salts removes phosphorus while biological processes are dependent on
                                the selection of high-phosphorus microorganisms. Additional removal of
                                nutrients and organic carbon can be accomplished using processes such as
                                high lime, granular activated carbon, and reverse osmosis. Effluent BOD5 is
                                generally less than 10 mg/L, and total-N removal is more than 50 percent.
  Note:
Readers desiring more technical details about these processes should review standard engineering reference texts
(e.g., Metcalf & Eddy, 1991) or technical reports on wastewater treatment (e.g., NRC, 1993). Effluent removal effi-
ciency and concentrations are from the 1978 USEPA Needs Survey (USEPA, 1978).
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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
Figure 2-7
Relationship between the
carbonaceous,
nitrogenous, and total
BOD.
Source: Thomann and
Mueller, 1987.
                         Types of BOD Reported in  This  Trends Analysis

                             BOD5 is the most widely used measurement of BOD. In spite of its popular-
                         ity, there are important limitations of this measurement. The subscript "5" refers
                         to the laboratory incubation period of 5 days at 20 QC. Many biochemical reactions
                         that determine the ultimate consumption of DO in both wastewater and natural
                         waters are not completed within the 5-day limit, however. Therefore, an estimate
                         of "ultimate" BOD (BODJ of a sample requires consideration of all the bio-
                         chemical processes that consume DO over a longer time scale. Figure 2-7
                         presents the relationships among the components of BOD .
                             Familiar to most environmental engineers is the oxygen demand associated
                         with the bacterial decomposition of carbonaceous organic matter under aerobic
                         conditions. Through respiration, organic matter is broken down and oxygen is
                         consumed. Parameters in Figure 2-7 relating to carbonaceous BOD are:
                             •    CBOD5—BOD at 5 days that includes only the carbonaceous compo-
                                 nent of oxygen consumption.
                             •    CBOD—BOD at an unspecified time that includes only the carbon-
                                 aceous component of oxygen consumption.
                             •    CBOD —Ultimate BOD of carbonaceous component of oxygen
                                 consumption at completion of decomposition process.
                             Along with the decomposition of carbonaceous matter is an additional
                         oxygen demand associated with nitrification, the process that converts ammonia
                         to nitrate. Nitrogen in wastewater generally appears as organic nitrogen com-
                         pounds (urea, proteins, etc.) and ammonia. Over time, the nitrogen compounds
                         are hydrolyzed and are converted to ammonia. Autotrophic bacteria of the genus
                         Nitrosomonas convert the ammonia to nitrite, using oxygen in the process. Nitrite,
                         in turn, is converted to nitrate by bacteria of the genus Nitrobacter, consuming
                         additional oxygen in the process. Parameters in Figure 2-7 relating to nitrogenous
                         BOD are
                             •    NBOD—BOD at an unspecified time that includes only the nitrogenous
                                 component of oxygen consumption from nitrification.
                             •    NBODu—Ultimate BOD of the nitrogenous component of oxygen
                                 consumption at completion of nitrification process.
Total BOD
                         BOD
                     BOD,,
                                                                                   CBOD
                                                                           Incubation time, days
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                                     Chapter 2: An Examination of BOD Loadings Before and After the CWA
      In Figure 2-7, carbonaceous and nitrogenous BOD components combine to
 yield the following parameters:
     •   BOD5—BOD at 5 days that includes the carbonaceous and nitrog-
         enous components of oxygen consumption.
     •   Total BOD—BOD at an unspecified time that includes the carbon-
         aceous and nitrogenous components of oxygen consumption.
     •   BODu—Ultimate BOD of the carbonaceous and nitrogenous compo-
         nents of oxygen consumption at completion of both the carbonaceous
         decomposition and nitrification processes.
      The length of time needed to reach the "ultimate" endpoints of the carbon-
 aceous and nitrogenous components designated in Figure 2-7 (CBODu and
 NBODu) depends on several factors, including the composition of the wastewater
 and the corresponding rate of decomposition for its components. For predomi-
 nately labile fractions of organic carbon that are easy for bacteria to decompose
 (e.g., mostly sugars, short chain molecules), decomposition can be completed
 within about 20 to 30 days. In contrast, for refractory organic matter that is
 strongly resistant to bacterial decomposition (e.g., mostly cellulose, long chain
 molecules such as pulp and paper waste), complete decomposition might require
 an incubation period of anywhere from 100 to 200 days. Decomposition rates for
 a sample of wastewater effluent from a POTW with secondary treatment,
 consequently, tend to be lower than rates from raw wastewater because the
 easily decomposed sugars have already been removed by the treatment process.
     Timing of the nitrification process is also dependent on several factors.
 These include the ratio of organic nitrogen compounds to ammonia and the lag
 time necessary to hydrolyze and convert the compounds to ammonia, the pres-
 ence of adequate numbers of nitrifying bacteria in the water to begin the nitrifica-
 tion process, alkaline pH levels, and the presence of sufficient oxygen for bacte-
 rial respiration. The net effect of these factors is to inhibit nitrification immediately
 downstream from POTW outfalls (Chapra,  1997). Similarly, in a laboratory
 sample if a "seed" population is not available for nitrification during the 5-day
 incubation period, the measured BOD5 will reflect only the carbonaceous compo-
 nent (i.e., CBOD5). If, however, factors are sufficient for nitrification to occur in
 the laboratory sample, the measured BOD5 will reflect both the carbonaceous and
 nitrogenous components (see Hall and Foxen, 1984).
     Is incorporating the nitrogenous component and using BODu important
 enough to eschew the more  familiar carbonaceous CBOD5 when presenting BOD
 information? The answer is yes. Chapra (1997) calculates that the oxygen
 consumed in nitrification is about 30 percent of the oxygen consumed in carbon-
 aceous oxidation of pure organic matter. If this finding was not persuasive enough
 for the inclusion of nitrification in an analysis of BOD, he also presents evidence
that concentrations of NBOD and CBOD are actually nearly equivalent in
untreated wastewater. Chapra theorizes that the discrepancy between calculated
and the actual concentrations may be attributed to the fact that not all organic
matter might be decomposable under the conditions of the BOD test and that
nitrogen in wastewater might not all come from organic matter. Fertilizers and
other sources likely add to the nitrogen pool, increasing the significance of NBOD
in the environment.
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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
                              In sum, the true measure of the long-term oxygen demand of influent and
                         effluent BOD loading and its effect on water quality in streams and rivers can be
                         determined only if both the carbonaceous and nitrogenous components of BOD
                         are combined and analyzed as BODu. Since it is impractical for most monitoring
                         programs and laboratories to extend the incubation period beyond the traditional
                         5 days associated with the determination of BOD5, other surrogate methods must
                         be used to determine CBOD , NBOD and BOD .  Discussed below are the
                                                   u '        u         u
                         methods used in this study to determine these parameters.

                         Determination of CBOD5 and CBODu

                              BOD loading data for municipal and industrial wastewater dischargers are
                         most often reported in NPDES permit limits and Discharge Monitoring Reports
                         (DMRs) as either BOD5 or CBOD5. Unfortunately, in analyzing historical loading
                         trends of municipal effluent it is impossible to determine if BOD5 data compiled
                         by various data sources included the suppression of possible nitrification during
                         the laboratory analysis. In compiling long-term BOD loading trends, therefore, it is
                         frequently assumed that BOD5 is approximately equal to CBOD5  (see Lung,
                         1998). This report makes the same assumption. Consequently, for the purposes of
                         this study all  BOD5 data  reported to the USEPA are considered to be CBOD5.
                              Leo et al. (1984) and Thomann and Mueller (1987) point out that conversion
                         ratios for estimating CBODu concentrations based on either BOD5 or CBOD5
                         concentrations are dependent on the level of wastewater treatment. The propor-
                         tion of easily  degraded (labile) organic matter in the effluent declines as the
                         efficiency of wastewater treatment is improved by upgrading a facility. In an
                         analysis of effluent data from 114 primary to advanced municipal wastewater
                         treatment plants, Leo et al.  (1984) determined mean values of 2.47 and 2.84 for
                         the CBODu/BOD5 and CBODu/CBOD5 ratios, respectively. The differences in
                         the two ratios reflect the oxygen demand from nitrification associated with the
                         BOD5 data (see Hall and Foxen, 1984).
                              The assumption in this study that all BOD5 concentrations reported to
                         USEPA are actually CBOD5 concentrations reduces the  focus to only CBODu/
                         CBOD5 ratios as they relate to various levels of municipal wastewater treatment.
                         Table 2-3 presents conversion ratios for four wastewater treatment types—raw,
                         less than secondary, secondary, and greater than secondary. The formula for this
                         conversion is:

                              CBOD  =  CBOD, [CBOD /CBOD, ratio]                      Eq. (2.1)
                            Table 2-3. CBODu/CBOD5 conversion ratios. Source: Thomann and Mueller,
                            1987; Leo et al., W84)
                                   |	  Municipal Wastewater Treatment Type
                                                  Less than                  Greater than
                                      Raw	Secondary3     Secondary    Secondary13
                                       1.2            1.6           2.84           2.9
                             a Primary and advanced primary wastewater treatment
                             b Advanced secondary and advanced wastewater treatment
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                                    Chapter 2: An Examination of BOD Loadings Before and After the CWA
Determination of NBODu
     Recall that nitrogen in wastewater generally appears as organic nitrogen
compounds and ammonia and that the organic nitrogen fraction can be
remineralized to ammonia and contribute to the oxygen demand in a receiving
water. NBOD, therefore, is defined as the oxygen equivalent of the sum of
organic nitrogen and ammonia. Conveniently, total Kjeldahl nitrogen (TKN) is
defined as the sum of organic nitrogen and ammonia-nitrogen and can be used
with the stoichiometric equivalent oxygen:nitrogen ratio (O2:N). A total of 4.57 g
oxygen per 1 g nitrogen consumed in the nitrification process provides the basis
for estimating the NBODu of a sample. The formula for converting TKN to
NBODU concentration is:
             y = 4.57 [TKN]                                    Eq. (2.2)

Determination of BODu
     The ultimate biochemical oxygen demand is determined by simply adding the
carbonaceous and nitrogenous components.
       BODy -  [CBODJ  +  [NBODu ]                         Eq. (2.3)


Trends  in POTW Inventory
     USPHS municipal wastewater inventories and the USEPA Clean Water
Needs Surveys were the primary data sources used to document the inventory of
POTWs in the United States before and after the CWA. Table 2-4 presents the
national inventory for select years from 1940 to 1996 organized by treatment type.
Figure 2-8 is a column chart displaying the POTW inventory data. The "No
Discharge" category (data available beginning in 1972) refers to facilities that do
not discharge their effluent to surface waters. Most facilities that fall into this
category are oxidation/stabilization ponds designed for evaporation and/or infiltra-
tion of effluent. Other examples of "No Discharge" facilities include recycling,
reuse, and spray irrigation systems.
     Key observations from Table 2-4 and Figure 2-8 include the following:
    •    The  total number of POTWs in the Nation increased by about 36
         percent between 1950 and 1996.
    •    POTWs providing only raw and less than secondary treatment de-
         creased in proportion to facilities providing secondary and greater than
         secondary treatment during the 1950-1996 time period. In 1950, only 30
        percent of POTWs nationwide (3,529 of 11,784 facilities) provided
         secondary treatment. In 1968, 4 years before the CWA, 72 percent of
        the POTWs (10,052  of 14,051 facilities) had secondary treatment or
        greater. By 1996, 24 years after the 1972 CWA, 99 percent of the
        Nation's 16,024 POTWs were providing either secondary treatment or
        greater or were  no discharge facilities.
    •   In 1968, 72 percent of the Nation's POTWs were providing secondary
        treatment and less than  1 percent were providing greater than second-
        ary treatment. By 1996, 59 percent of POTWs were providing second-
        ary treatment and 27 percent had greater than secondary treatment.
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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
  Table 2-4.  Inventory of POTWs by wastewater treatment type, 1940 - 1996. Source: U.S. Public Health Service
  Municipal Wastewater Inventories and USEPA Clean Water Needs Surveys.
                                                  	TREATMENT TYPE --
   Inventory of POTWs
                 Total
                Raw
             Less than
             Secondary
             Secondary
            Greater than
             Secondary
                                                                               -I
                No
            Discharge
  1940
  1950
  1962
  1968
  1972
  1978
  1982
  1988
  1992
  1996
   NA
11,784
11,698
14,051
19,355
14,850
15,662
15,708
15,613
16,024
  NA
5,156
2,262
1,564
2,265
  91
  237
  117
    0
    0
2,938
3,099
2,717
2,435
2,594
4,278
3,119
1,789
  868
  176
 2,630
 3,529
 6,719
10,042
 9,426a
 6,608
 7,946
 8,536
 9,086
 9,388
    0
    0
    0
   10
  461
2,888
2,760
3,412
3,678
4,428
  NA
  NA
  NA
  NA
  142
  985
1,600
1,854
1,981
2,032
    This total excludes 4,467 oxidation ponds and 142 land application facilities classified as secondary treatment facilities in
    EPA's 1972 inventory of municipal wastewater facilities (USEPA, 1972). They were excluded because (1) EPA did not
    categorize oxidation  ponds as secondary treatment facilities in any other year covered in this analysis and (2) land
    application facilities are classified as "no discharge" facilities in subsequent years and therefore (to be consistent) they
    were included in the no discharge facilities category for 1972.
Figure 2-8
Number of POTWs
nationwide for select years
between 1940 and 1996
organized by wastewater
treatment type.
Source: U.S. Public Health
Service Municipal
Wastewater Inventories
and USEPA Clean Water
Needs Surveys.
                                         1940 1950 1962 1968 1972 1978  1982 1988 1992 1996
                                                                 Year
                          Trends in Population and Influent Wastewater Flow
                          to POTWs

                               USPHS municipal wastewater inventories and the USEPA Clean Water
                          Needs Surveys were the primary data sources used to document the population
                          served by POTWs and the rate of influent wastewater flow to them between
                          1940 and 1996. Actual influent wastewater flow data were available from reports
                          prepared for 1978, 1980, 1982, 1984, and 1986. For the years in which these data
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                                    Chapter 2: An Examination of BOD Loadings Before and After the CWA
were not available, influent wastewater flow data were estimated based on the
population served and an assumed constant normalized flow rate of 165 gallons
per capita per day (gpcd). The influent wastewater flow rate of 165 gpcd is based
on the mean of the total population served and wastewater flow data compiled in
the USEPA Clean Water Needs Surveys for the five years  for which actual
wastewater flow data were reported (data ranged from 160 to 173  gpcd).
     Influent wastewater includes residential (55 percent),  commercial and
industrial (20 percent), stormwater (4 percent), and infiltration and inflow (20
percent) sources of wastewater flow (AMSA, 1997). The constant per capita
flow rate of 165 gpcd used in this study is identical to the typical U.S. average
within the wide range (65 to 290 gpcd) of municipal water use that accounts for
residential, commercial and industrial, and public water uses in the United States
(Metcalf and Eddy, 1991).
     Table 2-5 presents the population served by POTWs and the rate of influent
wastewater flow to POTWs nationally for select years from 1940 to 1996. Figure
2-9 is a column chart displaying the population data.
     Key observations from Table 2-5 and Figure 2-9 include the following:
    •    The population served by POTWs in the Nation increased significantly,
         from about 91.8 million people in 1950 to about 140.1 million in 1968
         (four years before the 1972 CWA). By 1996, 189.7 million people were
         connected to POTWs, a 35 percent increase from 1968.
    •   The number of people relying on POTWs with less than secondary
        treatment dropped rapidly after passage of the 1972 CWA. In 1968 (4
        years before the CWA), about 39 percent of the 140.1 million people
        were served by POTWs providing only raw or less than secondary
        wastewater treatment. By 1996 (24 years after the  1972  CWA), this
        percentage was reduced to about 9 percent; only 17.2 million people of
        the 189.7 million served by POTWs received less than secondary
        wastewater treatment.
        Stated another way, the U.S. population served by POTWs  with
        secondary or greater treatment almost doubled between  1968 and
         1996 from 85.9 million people in 1968 to  164.8 million people  in
         1996! (It is noted that 5.1 million of the 17.2 million people served by
        less than secondary facilities in  1996 were connected to 45 POTW
        facilities granted CWA Section 301(h) waivers (9 pending final waiver
        decision as of November 1998), which allow the discharge of primary
        or advanced primary effluent to deep, well-mixed ocean waters.)
    •   Although the number of people served by POTWs with secondary
        treatment remained fairly constant between 1968 and 1996 (a slight
        decrease of 3.7  million people or about 4 percent  of the population), the
        number of people provided with greater than secondary treatment
        increased significantly (from 0.3 million people in 1968 to 82.9 million
        people in 1996). This is consistent with the trend since 1968 in increas-
        ing numbers of POTWs providing greater than secondary treatment, as
        shown in Table 2-4.
                                                                                             2-33

-------
Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
Table 2-5. Population served by and influent
1940-1996.
.
1
| Population Served by POTWs (millions) ^^^
Total Raw
1940 70.5 32.1
1950 91.8 35.3
1962 118.3 14.7
1968 140.1 10.1
1972 141.7 4.9
1978 155.2 3.6
1982 163.5 1.9
1988 177.5 1.4
1992 180.6 0.0
1996 189.7 0.0
• Influent Wastewater Flow to POTWs (mod) m

Year Total Raw
1940 11,682 5,313
1950 15,141 5,819
1962 19,520 2,409
1968 23,117 1,667
1972 23,384 815
1978 26,800 601
1982 27,203 310
1988 29,294 226
1992 29,801 0
1996 31,302 0
wastewater flow

_ 	 	 TDI
	 — ___ | |^|
Less than
Secondary
18.4
24.6
42.2
44.1
51.9
44.1
33.6
26.5
21.7
17.2

Less than
Secondary
3,053
4,059
6,963
7,277
8,560
7,152
5,301
4,370
3,583
2,834
to POTWs by wastewater treatment type,

EATMENTTYPE

Secondary
20.0
31.9
61.5
85.6
76.3
56.3
67.6
78.0
82.9
81.9


Secondary
3,317
5,263
10,148
14,124
12,585
10,139
11,010
12,863
13,680
13,521



f^rpofAr than
\Jtt COICI LI 101 1
Secondary
0.0
0.0
0.0
0.3
7.8
49.1
56.3
65.7
68.2
82.9

Greater than
Secondary
0
0
0
50
1,288
8,545
10,092
10,832
11,258
13,683

I
	 __i
MO
t^HJ
Discharge
NA
NA
NA
NA
0.8
2.2
4.2
6.1
7.8
7.7

No
Discharge
NA
NA
NA
NA
136
363
491
1,003
1,281
1,264
Figure 2-9
Population served by
POTWs nationwide for
select years between 1940
and 1996 organized by
wastewater treatment type.
Source: U.S. Public Health
Service  Municipal
Wastewater Inventories
and USEPA Clean Water
Needs Surveys.
to
.8
•o
Q)
0)
CO
                                  O.
                                  O
                                 Q.
200-j

180-

160-

140

120-

100-

 80

 60

 40

 20

  0
             H No Discharge
             D > Secondary
             H Secondary
             M < Secondary
             • Raw
                                          1940 1950 1962 1968 1972  1978 1982 1988 1992 1996
                                                                 Year
2-34

-------
                                   Chapter 2: An Examination of BOD Loadings Before and After the CWA
Trends in  Influent BOD  Loading to POTWs

     Table 2-6 presents nationwide influent loading of CBOD5, CBODu, NBODu,
and BODu organized by wastewater treatment type for select years from 1940 to
1996.

Data Sources and  Calculations

     The USEPA Clean Water Needs Surveys were the primary data source
used to estimate the nationwide rate of influent CBOD5 loading to POTWs.
Actual influent CBOD5 loading data were reported for 1978, 1980, 1982, 1984,
and 1986. For the years for which data were not available, per capita influent
loading was assumed to be 0.296 Ib CBOD5 per person per day. This rate was
based on an estimated constant normalized flow rate of 165 gallons per capita per
day and an influent CBOD5 concentration of 215 mg/L. The use of 215 mg/L as
the influent CBOD5 concentration is consistent with several other estimates of
raw wastewater strength (e.g., AMSA, 1997; Tetra Tech, 1999; Metcalf and
Eddy, 1991). It also is the mean nationally aggregated ratio of the total influent
CBOD5 loading rate normalized to total wastewater flow reported in the USEPA
Clean Water Needs  Surveys for the 5 years that actual wastewater flow data
were reported (range from 209 to 229 mg/L). Sources of influent BOD include
residential, commercial and industrial, and infiltration and inflow contributions.
     Some readers might note that an influent loading rate of 0.296 Ib CBOD5
per person per day is almost twice the typical "textbook" value of 0.17 Ib CBOD5
per person per day, sometimes referred to as the "population equivalent" (PE)
rate. Textbook values, however, usually account for only the average per capita
residential load contributed by combined stormwater and domestic wastewater.
The industrial and commercial components are excluded (see Fair et al., 1971).
To provide a more complete characterization of influent BOD loading inclusive of
all sources, the higher figure was used in this study.
      CBODu data were determined using CBOD5 data and Equation 2.1 as
follows:
         CBODu - CBOD5 [1.2]                                 Eq. (2.4)

          where: 1.2 = CBOD /CBOD, ratio associated with raw wastewater
                           u      5
     The USEPA Clean Water Needs Surveys were the primary data source
used to estimate the nationwide rate of influent NBODu loading to POTWs.
Actual influent TKN loading data were reported for 1978, 1980, 1982, 1984, and
1986. For the years for which wastewater flow data were not available, per
capita influent loading was assumed to be 0.191 Ib NBOD per person per day.
This rate was based on an estimated constant normalized flow rate of 165 gallons
per capita per day and an influent TKN concentration of 30.3 mg/L, a level
derived from an analysis of about 100 wastewater facilities (AMSA, 1997). In-
fluent NBOD loading was determined using influent TKN data and Equation 2.2.

Trends in Influent CBOD5 and BODu  Loading to POTWs

     Figure 2-10 is a column chart that compares total influent CBOD5 and
BODu loading from 1940 to 1996. Figures 2-11 (a) and (b) display influent CBOD5
and BODu loading data,  respectively, organized by wastewater treatment type.
                                                                                         2-35

-------
Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
Table 2-6. Influent BOD loading to POTWs by wastewater treatment type, 1 940 - 1 996.

[ Influent CBOD5 Loading (metric tons per day)
Year
1940
1950
1962
1968
1972
1978
1982
1988
1992
1996
Total
9,508
12,323
15,886
18,814
19,032
21,253
21,170
23,841
24,254
25,476
Raw
4,324
4,736
1,961
1,356
663
489
252
184
0
0
• Influent CBODu Loading (metric tons per day)
Year
1940
1950
1962
1968
1972
1978
1982
1988
1992
1996
Total
11,409
14,787
19,063
22,576
22,838
25,503
25,405
28,609
29,105
30,571
Raw
5,189
5,683
2,353
1,628
796
587
302
220
0
0
• Influent NBODu Loading (metric tons per day) 1
Year
1940
1950
1962
1968
1972
1978
1982
1988
1992
1996
Total
6,123
7,936
10,232
12,117
12,257
14,047
14,259
15,355
15,621
16,408
Raw
2,785
3,050
1,263
874
427
315
162
118
0
0
• Influent BOD Loading (metric tons per day) m

Year
1940
1950
1962
1968
1972
1978
1982
1988
1992
1996

Total
17,532
22,723
29,295
34,693
35,095
39,551
39,663
43,964
44,726
46,979
••••^^^^^^^^^^^^^^^^^
Raw
7,974
8,734
3,615
2,501
1,223
901
465
339
0
0
l_p
-------
                                      Chapter 2: An Examination of BOD Loadings Before and After the CWA
Figure 2-10
Total influent BODu and
CBOD5 loading, 1940 to
1996.
Source: U.S. Public Health
Service  Municipal
Wastewater Inventories
and USEPA Clean Water
Needs Surveys.
_^  50,000

-g  45,000

j|  40,000

    35,000

    30,000

    25,000
o>

O)
•a
o   20,000

g   15,000
m
~   10,000
0)
2.    5,000
V|—

~       0
                                            1940  1950 1962  1968 1972  1978 1982  1988 1992  1996
                                                                     Year
Figure 2-11
Influent loading of
(a) CBOD5 and (b) BODu
to POTWs nationwide for
select years between 1940
and 1996 organized by
wastewater treatment type.
Source: U.S. Public Health
Service  Municipal
Wastewater Inventories
and USEPA Clean Water
Needs Surveys.
                           (a)
                                               1940 1950  1962  1968  1972  1978  1982  1988  1992 1996
                                                                      Year
                           (b)
                                    1
                                    I
                                    O)
                                    c
                                    '•&
                                    OS
                                    O
                                    Q
                                    O
                                    m
                                    0»
                                                1940  1950  1962  1968  1972  1978  1982  1988  1992  1996
                                                                      Year
                                                                                                  2-37

-------
Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment


                             Key observations from Table 2-6 and Figures 2-10 and 2-11 include the
                         following:
                             •    Influent BOD loading to the Nation's POTWs more than doubled from
                                 1940 to 1996, reflecting population growth, increases in the number of
                                 facilities, and expanding service areas.
                             •    Influent CBOD5 loading increased from 9,508 metric tons per day in
                                 1940 to 18,814 metric tons per day in 1968. By 1996, influent CBOD5
                                 loading stood at 25,476 metric tons per day, a 35 percent increase from
                                 1968.
                             •    Influent BODu loading increased from 17,532 metric tons per day in
                                 1940 to 34,693 metric tons per day in 1968. By 1996, influent BODu
                                 loading stood at 46,979 metric tons per day, a 35 percent increase from
                                 1968.
                             •    In 1940, 72 percent of influent BODu loading nationwide was being
                                 treated by facilities with less than secondary treatment (12,555 of
                                 17,532 metric tons per day of BODJ. By 1968, 39 percent of influent
                                 BODu loading nationwide was being treated by facilities with less than
                                 secondary treatment (13,422 of 34,693  metric tons per day of BODu).
                                 Twenty-four years after the 1972 CWA, only 9 percent of influent
                                 BODu loading was being treated by facilities with less than secondary
                                 treatment (4,254 of 46,979 metric tons per day of BODu).


                         Trends in  Effluent BOD  Loading from  POTWs

                             Table 2-7 presents nationwide effluent loading of CBOD5, CBODu, NBODu,
                         and BOD organized by wastewater treatment type for select years from 1940 to
                         1996.

                         Data  Sources and  Calculations

                             Effluent CBOD5 loading rates were estimated based on influent CBOD5
                         loading rates and CBOD5 removal efficiencies (expressed as a percentage)
                         associated with each type of municipal wastewater treatment (see Table 2-2). In
                         keeping with the convention of combining primary and advanced primary treat-
                         ment and designating the result as "less than secondary" treatment, CBOD5
                         removal efficiencies for these two categories were averaged to derive a "less
                         than secondary" treatment removal efficiency of 42.5 percent. Likewise, CBOD5
                         removal efficiencies assigned to advanced secondary treatment (90 percent) and
                         advanced wastewater treatment (95 percent) were averaged to derive a "greater
                         than secondary" treatment removal efficiency of 92.5 percent. Table 2-8 presents
                         CBOD5 removal efficiencies by municipal wastewater treatment type and
                         corresponding effluent CBOD5 concentrations.
                             Recall that the CBOD5 removal efficiencies used in this study are percent-
                         ages typically assigned to NPDES permits according to the treatment process and
                         POTW design assumptions (USEPA,  1978; Metcalf and Eddy, 1991). Use  of
                         "design-based" removal efficiencies may, in some cases, result in a conservative
                         (i.e., high) estimate of effluent CBOD5 loading. USEPA's Clean Water Needs
                         Surveys for the years 1976, 1978 and 1982, for example, report 41  and 64 percent
2-38

-------
Chapter 2: An Examination of BOD Loadings Before and After the CWA
Table 2-7. Effluent BOD loading from POTWs by wastewat
I 	 _ T


|| Effluent CBOD5 Loading (metric tons per day)
Year
1940
1950
1962
1968
1972
1978
1982
1988
1992
1996
Total
6,344
7,526
6,883
6,932
6,768
5,510
4,380
4,460
4,034
3,812
Raw
4,324
4,736
1,961
1,356
663
489
252
184
0
0
• Effluent CBODu Loading (metric tons per day)
Year
1940
1950
1962
1968
1972
1978
1982
1988
1992
1996
Total
8,922
10,943
11,765
12,689
12,558
11,621
9,582
9,869
9,418
9,232
Raw
5,189
5,683
2,353
1,628
796
587
302
220
0
0
• Effluent NBODu Loading (metric tons per day) I
Year
1940
1950
1962
1968
1972
1978
1982
1988
1992
1996
Total
5,146
6,475
7,514
8,591
8,273
7,526
7,168
7,327
7,205
7,093
Raw
2,785
3,050
1,263
874
427
315
162
118
0
0
• Effluent BOD Loading (metric tons per day)U

Year
1940
1950
1962
1968
1972
1978
1982
1988
1992
1996

Total
14,068
17,419
19,278
21,281
20,831
19,147
16,750
17,196
16,623
16,325
^^^^^^^^^^^^•^^^^^^^^
Raw
7,974
8,734
3,615
2,501
1,223
901
465
339
0
0

Less than
Secondary
1,615
2,147
3,684
3,849
4,501
2,654
1,975
2,045
1,677
1,326
Less than
Secondary
2,584
3,436
5,894
6,159
7,201
4,246
3,160
3,272
2,683
2,122
Less than
Secondary
1,248
1,660
2,847
2,975
3,500
2,924
2,167
1,787
1,465
1,159

Less than
Secondary
3,832
5,095
8,740
9,134
10,701
7,171
5,327
5,059
4,147
3,281
er treatment typ
REATMENTTYPI

Secondary
405
642
1,239
1,724
1,536
1,596
1,539
1,570
1,670
1,651

Secondary
1,150
1,825
3,518
4,897
4,363
4,533
4,371
4,460
4,743
4,688

Secondary
1,113
1,765
3,404
4,738
4,222
3,401
3,693
4,315
4,589
4,536


Secondary
2,262
3,590
6,922
9,635
8,585
7,934
8,064
8,774
9,332
9,224
e, 1940-1996.

Greater than
Secondary
0
0
0
2
68
771
614
661
687
835
Greater than
Secondary
0
0
0
6
198
2,255
1,749
1,918
1,993
2,422
Greater than
Secondary
0
0
0
4
125
886
1,145
1,107
1,151
1,399

Greater than
Secondary
0
0
0
11
322
3,141
2,894
3,025
3,144
3,821
I
............... I

On-Site
NA
NA
NA
NA
0
0
0
0
0
0

On-Site
NA
NA
NA
NA
0
0
0
0
0
0

On-Site
NA
NA
NA
NA
0
0
0
0
0
0


On-Site
NA
NA
NA
NA
0
0 1
0 1
0 1
0 1
— LI
                                                     2-39

-------
Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
                            Table 2-8. CBOD5 removal efficiencies by municipal wastewater treatment type
                            and corresponding effluent CBOD5 concentrations.

                                                       I	Municipal Wastewater Treatment Type	1
                                                          Raw
 Less than
Secondary3
           Greater than
Secondary   Secondary11
CBOD5 removal efficiency (%)
CBOD5 cone, in effluent (mg/L)
0.0
21 5C
425
123.6
85.0
32.3
92.5
16 1
                             a  Primary and advanced primary wastewater treatment.
                             b  Advanced secondary and advanced wastewater treatment.
                             c  Equivalent to CBOD  cone, in (untreated) influent
                          CBOD5 removal efficiency for primary and advanced primary facilities, respec-
                          tively. These same reports present removal efficiencies for secondary (82 to 86
                          percent), advanced secondary (89-92 percent), and advanced wastewater
                          treatment (87 to 94 percent) either in the range or very near to the range of
                          design-based removal efficiencies. The design-based CBOD5 removal efficien-
                          cies were chosen for use in this study over actual reported efficiencies because it
                          was assumed that a conservative approach would provide a more effective and
                          consistent comparison of trends for POTW BOD removal over the entire period
                          of record analyzed.
                               Effluent CBODu loading  rates were estimated for each category of waste-
                          water treatment from effluent CBOD5 loading rates and the corresponding
                          CBODu/CBOD5 ratio (see Table 2-3) using Equation 2.1. CBODu removal
                          efficiencies for each  treatment category were then  computed from the influent (I)
                          and effluent (E) loading as:
                               Percent Removal Efficiency =
                                                              (I-E)
    x 100
               Eq. (2.5)
                          Table 2-9 presents the calculated CBODu removal efficiencies by municipal
                          wastewater treatment type and corresponding effluent CBODu concentrations.
                               Effluent NBODu loading rates were estimated based on influent NBODu
                          and NBOD  removal efficiencies reported for TKN (expressed as a percentage)
                             Table 2-9.  CBODu removal efficiencies by municipal wastewater treatment type
                             and corresponding effluent CBODu concentrations.

                                                        I	Municipal Wastewater Treatment Type	1
                                                          Raw
  Less than              Greater than
Secondary3   Secondary   Secondary11
CBODU removal efficiency (%)
CBODU cone, in effluent (mg/L)
0.0
258°
233
197.8
64.5
91.6
81.9
46.8
                             a Primary and advanced primary wastewater treatment.
                             b Advanced secondary and advanced wastewater treatment.
                             c
                               Equivalent to CBODu cone, in (untreated) influent
2-40

-------
                                     Chapter 2: An Examination of BOD Loadings Before and After the CWA
  Table 2-10. TKN and NBODu removal efficiencies by municipal wastewater
  treatment type and corresponding effluent TKN and NBODu concentrations.

                             I	Municipal Wastewater Treatment Type	1
                                 Raw
 Less than            Greater than
Secondary3  Secondary Secondary13
TKN & NBODu removal efficiency (%)
TKN cone, in effluent (mg/L)
NBODu cone, in effluent (mg/L)
0.0
30.3
138.5°
22.0
23.6
108.0
36.0
19.4
88.6
80.5
5.9
27.0
  a  Primary and advanced primary wastewater treatment.
  b  Advanced secondary and advanced wastewater treatment.
  c  Equivalent to NBOD  cone, in (untreated) influent
  Table 2-11. BODu removal efficiencies by municipal wastewater treatment type
  and corresponding effluent BODu concentrations.

                             I	Municipal Wastewater Treatment Type	1
                                         Less than             Greater than
                               Raw     Secondary8   Secondary   Secondaryb
BODu removal efficiency (%)
BODU cone, in effluent (mg/L)
0.0
396. 5C
22.9
305.8
54.5
180.2
81.4
73.8
   a  Primary and advanced primary wastewater treatment.
   b  Advanced secondary and advanced wastewater treatment.
   c  Equivalent to BODuconc in (untreated) influent.
associated with each category of wastewater treatment. Removal efficiencies for
TKN were based on data compiled in Gunnerson et. al (1982) for primary
facilities, AMSA (1997) for secondary facilities, and AMSA (1997) and
MWCOG (1989) for advanced wastewater treatment  facilities. Since NBODuis
estimated from TKN and the constant stoichiometric ratio of 4.57 g O2 (gN)"1,
removal efficiencies for TKN and NBOD  have the same value for the various
                                     u
categories of wastewater treatment. Table  2-10 presents TKN removal efficien-
cies and effluent concentrations as TKN and NBODu.
     The effluent BODu loading rates were determined by adding the calculated
CBOD and NBOD loading rates.  BODu removal efficiencies for each treat-
ment category were then computed from the influent (I) and effluent (E) BODu
loading rates according to Equation 2.4. Table 2-11 presents the calculated BODu
removal efficiencies by municipal wastewater treatment type and corresponding
effluent BOD  concentrations.
            u

Trends in Effluent CBOD5 and BODu  Loading  From POTWs

     Figure 2-12 is a chart that compares effluent CBOD5 and BODu loading
over the same time period. Figures 2-13(a) and 2-13(b) display effluent CBOD5
and BODu loading data organized by wastewater treatment type.
                                                                                              2-41

-------
Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
Figure 2-12
Total effluent BODu and
CBOD5 loading, 1940 to
1996.
Source: U.S. Public Health
Service  Municipal
Wastewater Inventories
and USEPA Clean Water
Needs Surveys.
Figure 2-13
Effluent loading of (a)
CBOD5 and (b) BODu from
POTWs nationwide for
select years between 1940
and 1996 organized by
wastewater treatment type.
Source: U.S. Public Health
Service  Municipal
Wastewater Inventories
and USEPA Clean Water
Needs Surveys.
                           (a)
                           (b)
I
I
o>

'•&
te
o

Q
O
m
+J
0)
_3
it
111
 I
 c
 -
 I
 D)
 C
 '•V
 (O
 o
 O
 O
 CD
 O
 £
 o>
                                  f
                                  o
                                  •I
                                  (D
                                  £:_
                                  O)
                                  '•B
                                  to
                                  o
                                   3
                                  Q
                                  O
                                  m
                                  LU
                                             1940  1950 1962  1968  1972  1978  1982 1988  1992  1996
                                                                       Year
                                             1940 1950 1962 1968 1972 1978 1982 1988 1992 1996

                                                                    Year
            1940 1950 1962  1968  1972  1978  1982  1988 1992 1996

                                   Year
2-42

-------
                                   Chapter 2: An Examination of BOD Loadings Before and After the CWA
     Key observations from Table 2-7 and Figures 2-12 and 2-13 include the
following:
     •   Effluent BOD loading by POTWs was significantly reduced between
         1968 and 1996. In 1968, 4 years before the 1972 CWA, effluent
        CBOD5 and BODu loadings were 6,932 and 21,281 metric tons per day,
        respectively. By 1996 CBOD5 and BODu loadings were reduced to
        3,812 and 16,325 metric tons per day, respectively. This represents a 45
        percent decline in CBOD5 and a 23 percent decline in BODu between
         1968 and 1996. Notably, these declines were achieved even though
        influent CBOD5 and BODu loading to POTWs each increased by 35
        percent during the same time period!
     •   The proportion of effluent CBOD5 loading attributable to raw and less
        than secondary wastewater treatment was reduced from about 94
        percent in 1940 to 35 percent in 1996 (see Figure 2-13(a)). The propor-
        tion of effluent BODu loading attributable to raw and less than second-
        ary wastewater treatment was reduced from about 84 percent in 1940
        to 20 percent in 1996 (see Figure 2-13(b)).


Trends  in BOD  Removal Efficiency

     The rate of effluent BOD loading from a POTW is determined by two main
factors, the rate of influent BOD loading and the BOD removal efficiency of the
facility. Influent BOD loading, in turn, is determined by the number of people
connected to the system  and the rate at which they generate and export BOD in
their wastewater flow. The analysis above indicates that tremendous progress
was achieved between 1968 and 1996 in reducing effluent BOD loading from
POTWs into the Nation's waterways. Notably, this reduction occurred at the
same time the number of people served by POTWs was increasing rapidly.
Figures 2-14 and 2-15 present influent and effluent loadings and removal efficien-
cies for CBOD5 and BODu, respectively.
     Key observations from Figures 2-14 and 2-15 include the following:
     •   BOD removal efficiency nationwide significantly increased between
        1940 and 1996. In 1940 the aggregate national removal efficiency stood
        at about 33 percent for CBOD5 and 20 percent for BODu. By  1968
        removal efficiencies had increased to 63 percent for CBOD5 and 39
        percent for BODu. By 1996 they had further increased to nearly 85
        percent for CBOD5 and 65 percent for BODJ
     •   The BOD removal efficiency increased substantially between 1972 and
        1978, the 6-year period after the passage of the CWA (from 64 to 74
        percent for CBOD5  and from 41 to 52 percent for BOD ). Between
        1978 and 1996  removal efficiency increased an additional 11 percent
        for CBOD5 and 13 percent for BODu. Those larger increases in BODu
        removal efficiency reflect the ever-increasing role of greater-than-
        secondary POTWs over this time  period.
                                                                                         2-43

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
Figure 2-1 4
Total POTW influent and
effluent CBOD5 loading
and corresponding CBOD5
removal efficiency for
select years between 1940
and 1996.
Source: U.S. Public Health
Service  Municipal
Wastewater Inventories
and USEPA Clean Water
Needs Surveys.
CD
•§

-8
.o
u>
                            s
                            o
                            m
                            o
                     Influent CBOD,
                     Effluent CBOD
                                        1940  1950 1962  1968  1972  1978  1982  1988  1992  1996
                                                                 Year
Figure 2-15
Total POTW influent and
effluent BODu loading and
corresponding BODu
removal efficiency for
select years between 1940
and 1996.
Source: U.S. Public Health
Service  Municipal
Wastewater Inventories
and USEPA Clean Water
Needs Surveys.
                                                                                                 100
I
I
£
I
O)
                            0=
                            O
                            m
                     Influent BODU
                     Effluent BODU
                 O  Removal Efficiency
                                        1940  1950  1962  1968  1972  1978  1982  1988  1992  1996
                                                                 Year
                                Figure 2-16, a three-dimensional graph of the population data presented
                           earlier in Table 2-5 and Figure 2-9, is useful for visualizing the trends in population
                           served by POTW treatment type. The population served by secondary treatment
                           facilities declined sharply between 1968 (85.6 million) and 1978 (56.3 million) and
                           then leveled off at about 82 million in the 1990s. In contrast, the number of people
                           served by greater than secondary treatment surged between 1968 and 1978 (0.3
                           to 49.1 million) and then increased steadily to about 82.9 million in 1996. Unlike
                           secondary treatment, advanced wastewater treatment enhances biological
                           processes to incorporate nitrification (ammonia removal) and denitrification
                           (nitrate removal), thus reducing the NBOD  fraction of effluent BODu loading.
2-44

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                                    Chapter 2: An Examination of BOD Loadings Before and After the CWA
       Raw

< Secondary,
Secondary^
h 90
II 80
1 70
/
I 60
1 50
I 40
I 30

20
10
0

•o
o
•o
c
si
o'
i?
I
(D
a
<

                                                                           Figure 2-16
                                                                           Population served by
                                                                           POTWs  nationwide for
                                                                           select years between  1940
                                                                           and 1996 organized by
                                                                           wastewater treatment  type.
                                                                           Source:  U.S.  Public Health
                                                                           Service  Municipal
                                                                           Wastewater Inventories
                                                                           and USEPA Clean Water
                                                                           Needs Surveys.
Future Trends in BOD  Effluent Loading

     The data presented in the previous sections indicate that the increase in
BOD removal efficiency between 1940 and 1996 resulted in significant reductions
in BOD effluent loading to the Nation's waterways even though the number of
people served by POTWs greatly increased. Given that the population served
by POTWs is projected to continue to increase well into the 21st century, will
the trend of effluent BOD loading reductions also continue into the future?
A preliminary examination of estimated influent and effluent BOD loadings based
on USEPA projections of facility inventory and population served for the year
2016 indicates that the answer might be "no."
     Table 2-12 presents a summary of the population served, wastewater flow,
influent and effluent BOD loading rates, and BOD removal efficiencies for 1996
and corresponding projections for 2016 and 2025. Figure 2-17 is a column chart
that extends the influent and effluent BODu loading totals and POTW removal
efficiencies originally presented in Figure 2-15 into the 21st century by adding
columns for the years 2016 and 2025 to the chart. These projections are based on
the following assumptions:
         USEPA Clean Water Needs Survey (USEPA,  1997) estimates that 275
         million people will be served by POTWs in the year 2016. This figure is
         based on middle-level population projections from the Census Bureau
         (USBC, 1996) and the assumption that 88 percent of the population will
         be served  by POTWs in 2016. Assuming that 88 percent of the popula-
         tion projected for 2025 is also served by POTWs, about 295 million
         people will be served by POTWs.
         Design-based BODu removal efficiency will increase from a nation-
         wide average of 65 percent in 1996 to 71 percent by 2016 based on
         projections of population served by the different categories of POTWs.
         This removal efficiency is assumed to remain at that level through
         2025.
    •    Influent wastewater flow will remain a constant 165 gpcd and influent
        BODu concentration will remain a constant 396.5 mg/L for the projec-
        tion period from 1996 to 2025.
                                                                                           2-45

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
Table 2-1 2. 1 996 estimates and 201 6 and 2025 projections of POTW infrastructure and influent and
effluent BOD loading.
!,_ TDC ATIUICMT TVDC 1
1
Inventory of POTWs
Population of U.S. (millions)
Population served (millions)
Percent of population served
Influent wastewater flow (mgd)
Unit flow (gallons/person/day)
Influent CBOD5 loading (metric tons/day)
Influent CBODu loading (metric tons/day)
Influent NBODu loading (metric tons/day)
Influent BODu loading (metric tons/day)
Effluent CBOD5 loading (metric tons/day)
Effluent CBODU loading (metric tons/day)
Effluent NBODu loading (metric tons/day)
Effluent BODu loading (metric tons/day)
CBOD5 percent removal
CBODu percent removal
NBODu percent removal
BODu percent removal
E3H
Inventory of POTWs
Population of U.S (millions)
Population served (millions)
Percent of population served
Influent wastewater flow (mgd)
Unit flow (gallons/person/day)
Influent CBOD5 loading (metric tons/day)
Influent CBODu loading (metric tons/day)
Influent NBODu loading (metric tons/day)
Influent BODu loading (metric tons/day)
Effluent CBOD5 loading (metric tons/day)
Effluent CBODU loading (metric tons/day)
Effluent NBODu loading (metric tons/day)
Effluent BODU loading (metric tons/day)
CBOD5 percent removal
CBODu percent removal
NBODU percent removal
BODU percent removal
E?ffEl Totals Only
Inventory of POTWs
Population of U.S. (millions)
Population served (millions)
Percent of populaton served
Influent wastewater flow (mgd)
Unit flow (gallons/person/day)
Influent CBOD5 loading (metric tons/day)
Influent CBODu loading (metric tons/day)
Influent NBODu loading (metric tons/day)
Influent BODU loading (metric tons/day)
Total
16,024
263.4
189.7
72%
31 ,302
165
25,476
30,571
16,408
46,978
3,812
9,232
7,093
16,325
85%
70%
57%
65%
Total
18,303
311.5
274.7
88%
45,329
165
36,892
44,270
23,760
68,030
4,025
10,995
8,611
19,607
89%
75%
64%
71%
Total
335.1
295.5
88 2%
48,760
165
39,684
47,620
25,558
73,179
Less than Greater than
Raw Secondary Secondary Secondary On-Site
0 176 9,388 4,428 2,032
0 172 81 9 82.9 77
0 2,834 13,521 13,683 1,264
0 2,307 11,004 11,136 1,029
0 2,768 13,205 13,363 1,235
0 1,486 7,087 7,172 663
0 4,254 20,292 20,536 1,897
0 1,326 1,651 835
0 2,122 4,688 2,422
0 1,159 4,536 1,399
0 3,281 9,224 3,821
42% 85% 92%
23% 64% 82%
22% 36% 80%
23% 54% 81%

0 61 9,738 6,135 2,369
0 5.5 1023 152.7 14.2
0 910 16,883 25,200 2,337
0 740 13,740 20,509 1,902
0 888 16,489 24,611 2,282
0 477 8,850 13,209 1,225
0 1,365 25,338 37,819 3,507
0 426 2,061 1,538
0 681 5,853 4,461
0 372 5,664 2,576
0 1,053 11,517 7,036
42% 85% 92%
23% 64% 82%
22% 36% 80%
23% 54% 81%

Effluent CBOD5 loading (metric tons/day)
Effluent CBODu loading (metric tons/day)
Effluent NBODu loading (metric tons/day)
Effluent BODU loading (metric tons/day)
CBOD5 percent removal
CBODu percent removal
NBODu percent removal
BODU percent removal
Total
4,330
1 1 ,827
9,263
21,090
89%
75%
64%
71%
2-46

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                                     Chapter 2: An Examination of BOD Loadings Before and After the CWA
Figure 2-17.  POTW influent and effluent BODu loading and removal efficiency for select years between 1940 and 1996
and 2016 and 2025.  Source: U.S. Public Health Service Municipal Wastewater Inventories, USEPA Clean Water Needs
Surveys and U.S. Census Population Projections.
         80,000
                              Influent BODu
                              Effluent BODu
                           O Removal  Efficiency
                 1940 1950 1962 1968 1972 1978 1982 1988 1992  1996
                                                 Year

     Key observations from Figure 2-17 include the following:
    •    Population growth from 1996 to 2016 will increase influent BODu
         loading nationwide to 68,030 metric tons per day, an increase of 45
         percent. By 2025 influent loading will be about 73,057 metric tons per
         day, a 56 percent increase  from 1996.
    •    In spite of a projected national increase in BOD removal efficiency
         from 65 to 71 percent by 2016 (a 9 percent increase), it is estimated
         that the trend of decreasing effluent BODu loadings experienced in the
         24 year period from 1968 to 1996 will be reversed. It is predicted that
         effluent BODu loadings will increase from 16,325 metric tons per day
         in 1996 to 19,606 metric tons per day in 2016, an increase of 20 per-
         cent. The effluent BODu loading rate estimated for 2016 is about equal
         to effluent loading rates that existed in the mid-1970s, only a few years
         after the CWA was enacted!
         By 2025 the projected effluent BODu loading will be 21,090 metric tons
         per day, an increase of 29 percent from 1996. This rate is about equal
         to effluent loading rates experienced in 1968 (21,280 metric tons per
         day), the year when the discharge of oxygen-demanding material from
         POTWs had reached its historical peak!
2016 2025
                                                                                              2-47

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment


                            •    By 2016, when the projected needs for wastewater treatment are
                                expected to be met (USEPA, 1997), the overall BODu removal effi-
                                ciency of 71 percent and increases in population will result in a 20
                                percent increase of effluent loads relative to the 1996 loading rate. To
                                maintain an effluent BODu loading rate comparable to 1996 conditions
                                through 2016 (i.e., "running in place"), the national aggregate removal
                                efficiency would have to be increased from 71 to 76 percent. This
                                would need to be accomplished by shifting the projected population
                                served from secondary to advanced secondary and advanced waste-
                                water treatment facilities.
                            The estimated projections of increasing effluent loading rates of BOD over
                        the next quarter-century underscore the importance of continually investing in
                        improvements to wastewater treatment infrastructure to maintain and improve
                        pollutant removal efficiencies. Without these improvements many of the environ-
                        mental successes of the water pollution control efforts over the past three de-
                        cades may be overwhelmed by the future demand from population growth. The
                        very real risk of losing the environmental gains achieved by federal (Construction
                        Grants Program), state, and local water pollution control efforts under the technol-
                        ogy and water quality-based effluent limit regulations of the 1972 CWA is also
                        documented by Jobin (1998) and the  Water Infrastructure Network (WIN, 2000).


                        E.   Comparison of Contemporary  BOD5

                        Loadings From POTWs and Other

                        Point and Nonpoint Sources  Based

                        on Estimates  of Actual Loadings

                            The primary purpose of Chapter 2 is to examine whether there was a
                        significant reduction in effluent BOD loading to  the Nation's waterways after the
                        technology-based and water quality-based treatment  provisions of the CWA were
                        implemented. To fully address this subject, however, it is important to recognize
                        the following:
                            •    Effluent BOD loading comes from several  point and nonpoint sources
                                in addition to POTWs.
                            •    BOD is only one of several contaminants that have the potential to
                                affect aquatic resources and the lives and livelihoods of water resource
                                users. Table 2-13 presents some of the concerns and conditions associ-
                                ated with several types of water pollutants.
                            This section is divided into two subsections. The first subsection briefly
                        describes non-POTW sources of BOD loading, including industrial wastewater
                        treatment facilities, combined sewer overflows (CSOs), urban stormwater runoff,
                        and rural nonpoint sources1 of pollution. For the purposes of this comparison,
                          Nonpoint source (NFS) pollution sources are sources of pollution not defined by statute as
                          point sources. NPS pollution results from the transport of pollutants into receiving waters via
                          overland flow runoff in a drainage basin. Because NPS pollution is diffuse, its specific sources
                          can be difficult to identify.
2-48

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                                    Chapter 2: An Examination of BOD Loadings Before and After the CWA
Table 2-1 3. Pollutant grc
Pollutant Group
Nutrients
(nitrogen and
phosphorus)
Metals and Toxics
Organic Matter
Pathogens
Sediment
Hazardous materials
ups and related water resource issues.
Water Quality Conditions
Eutrophication
Ammonia toxicity
Anoxia/ hypoxia; oxygen depletion
Water clarity/transparency
Reduced diversity/trophic structure
Fish body burden
Shellfish body burden
Mammals body burden
Anoxia/hypoxia; oxygen depletion
Adsorption/desorption of toxic chemicals
Shellfish bed closure
Recreational beach closure
Anoxic sediments
Damage to benthic biota
Oil spills
Chemical spills
and Concerns
Nuisance algal blooms
Toxic algal blooms
Fish kills
Shellfish bed closure/loss
Loss of seagrass beds/habitat
Birds body burden
Sediment contamination
Drinking water supply
Fish kills
Drinking water supply
Habitat destruction/fish spawning
Water clarity/ transparency
Fish kills
urban stormwater runoff includes areas both outside (termed "nonpoint source")
and within (meeting the legal definition of a point source in section 502(14) of the
CWA) the NPDES stormwater permit program.
     The second subsection introduces the National Water Pollution Control
Assessment Model (NWPCAM) (Bondelid et al.,  1999), a tool that can be used
to estimate the water quality impact of current (ca. 1995) BOD5 effluent loadings
from point and nonpoint sources nationwide. The primary purpose of this exercise
is to compare BOD5 effluent loadings from POTWs with BOD5 effluent loadings
from other point and nonpoint sources.


Pollutant Loading  From  Sources Other Than
POTWs

Industrial Wastewater Treatment Facilities

     Many industrial facilities discharge treated wastewater directly to surface
waters. Similar to municipal wastewater treatment, industrial wastewater treat-
ment consists of a sequence of physical, biological, and chemical processes
designed to remove pollutants that are specific to an industrial facility's manufac-
turing operations. USEPA's effluent guidelines, prepared for specific categories of
industrial groups, prescribe effluent limits in terms of the industry's output produc-
tion rate (e.g., n kilograms of pollutant discharged per 1,000 kilograms of factory
production). Table 2-14 presents median effluent concentrations  for conventional
and nonconventional pollutants for the industrial categories that account for the
largest contributions to effluent loading rates for BOD5.
                                                                                           2-49

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
Table 2-14. Effluent characteristics for select major industry groups. Source: Tetra Tech, 1999; NOAA, 1994.
Inorganic Organic Food Iron Pulp
Parameter Chemical Chemical and and Petroleum and
(mg/L) Products Products Feedlots Beverages Steel Refining Paper
BOD5
TOC
NH3-N
Total-N
Total-P
TSS
DO
No. of Facilities
Average Median
Major Facilities
Minor Facilities
6.5
9.4
1.3
1.9a
0.4
10.6
N/A
273
Design Flow
2.9
0.2
6.3
11.2
1.2
33.4a
N/A
11.8
N/A
232
(mgd)
2.3
1.7
6.0
N/A
0.7
28.5a
1.4
13.1
7.7
32
N/A
0.3
Note: The table presents the median value of effluent data extracted from
indicated by a, which indicates that Typical Pollutant Concentration
11.8
N/A
0.6
17.9a
6.7a
12.0
N/A
62
0.3
0.1
6.0
N/A
1.0
2.9a
N/A
9.9
6.6
186
3.9
0.2
8.8
12.0
2.0
N/A
N/A
12.9
N/A
203
3.0
0.3
24.5
N/A
1.2
1.4a
0.6
29.4
5.8
309
5.0
0.8
PCS for the period 1991 to 1998 except where
(TPC) effluent data compiled by NOAA (1994) are used.
                               In contrast to direct industrial dischargers, industrial facilities can also
                          discharge wastewater to sanitary sewer systems, where it mixes with domestic
                          sources of wastewater (indirect industrial dischargers). This wastewater often
                          contains a variety of metals, organic chemicals, and oily wastes that are not
                          common to domestic  sources of wastewater. Because of the high degree of
                          variability, most municipal treatment systems are not designed to treat a vast array
                          of industrial wastes. Consequently, these wastes can interfere with the operation
                          of treatment plants, contaminate receiving waterbodies, threaten worker health
                          and safety, and increase the cost and risks of sludge treatment and disposal.
                          Using proven pollution control technologies and practices that promote the reuse
                          and recycling of material, however, industrial facilities can provide "pretreatment"
                          by removing pollutants from their wastewater before discharging to the municipal
                          wastewater system. In addition to the categorical standards for pretreatment
                          established as part of the industrial effluent guideline process, local pretreatment
                          limits are enforced by various municipal facilities to protect treatment processes,
                          worker health and safety, and equipment. USEPA's National Pretreatment
                          Program, a cooperative effort of federal, state, and local officials, is fostering this
                          practice nationwide.
2-50

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                                      Chapter 2: An Examination of BOD Loadings Before and After the CWA
Combined Sewer Overflows

     In many older cities of the United States, urban sewer systems were
originally designed to convey both raw sewage and storm water runoff collected
during rainstorms. These combined sewer overflow systems were also explicitly
designed to discharge (overflow) the mixture of raw  sewage and storm water into
the river if a heavy rainstorm exceeded the hydraulic capacity of the combined
sewer system. As a vestige of public works practices from approximately 1850 to
1900, about 880 cities mostly in the central and northeastern states have combined
sewer systems that continue to function in this manner (USEPA, 1997). Table
2-15 presents characteristic discharge concentrations of conventional and
nonconventional pollutants in combined sewer overflows (CSOs).
     In addition to raw sewage, a CSO system can discharge pretreated indus-
trial waste and street debris washed off during a storm. Although pollutant loading
from CSO systems is intermittent, occurring only under heavy rainstorm condi-
tions, the high loading rates of sewage from CSO outlets frequently result in the
closure of recreational beaches and shellfish beds to protect public health. Dis-
charges from CSOs also are associated with depressed oxygen levels in poorly
flushed waterbodies, accumulation of organics in sediments, and generally noxious
conditions and odors.
     National assessments show that the relative significance of annual loading of
BOD5 from CSO systems is about the same as the effluent loading from second-
  Table 2-15. Effluent characteristics of urban runoff and CSOs.
Parameter
BOD5 (mg/L)
CBODu/BOD6
TSS (mg/L)
TKN (mg/L)
NH3-N (mg-N/L)
NO2-N +NO3-N (mg-N/L)
Total N (mg-N/L)
Total P (mg-P/L)
Total Lead (mg/L)
Total Conforms (MPN/100 m/L)
Urban Runoff
Range"'"
10-13
ND
141-224
1.68-2.12
ND
0.76-0.96
3-10
0.37-0.47
161-204
103-108
CSO
Range0" (event mean)
60-200 (115)
ND (1.4)e
100-1100 (370)
ND (6.5)
ND (1.9)
ND (1.0)
3-24 (7.5)
1-11 (10)
ND (370)
10M07 (ND)
   NOTES: ND = Nodata
   a Range of urban runoff concentrations reflects variability of coefficient of variation of
    event mean concentrations for median urban sites. Data from USEPA (1983) presented in
    Novotny and Olem (1994) (Table 1.3, p.36).
   b Range of urban runoff concentrations for total N and total conforms from Novotny and
    Olem (1994) (Table 1.3, p. 36).
   0 Range of CSO concentrations for BOD5, TSS, total N and total conforms from Novotny and
    Olem (1994) (Table 1.3, p36).
   " Mean CSO concentrations of BOD5, TSS, and total lead from USEPA (1978) presented in
    Novotny and Olem (1994); median CSO concentrations of nitrogen constituents from
    Driscoll (1986); mean CSO concentration of total phosphorus from Ellis (1986).
   8 CBOD,/BOD5 ratio from Thomann and Mueller, 1987.
                                                                                                2-51

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment


                          ary wastewater treatment facilities in the same urban area. In contrast to BOD5,
                          annual loading of suspended solids and lead is about 15 times greater from CSO
                          systems than from secondary wastewater treatment facilities. Annual loading
                          rates of total nitrogen and phosphorus from CSOs, however,  are only about one-
                          fourth (total N) and one-seventh (total P) of the annual loads contributed by
                          secondary facilities (Novotny and Olem, 1994).

                          Urban and Rural Nonpoint Sources

                               Organic and inorganic materials, both naturally occurring and related to
                          human activities, are transported to waterbodies within a drainage basin by
                          surface runoff over the land as nonpoint, or diffuse, sources of pollutants. The
                          magnitude and the timing of nonpoint pollutant loads are dependent on many
                          complex, and interacting, processes within a drainage basin.  In contrast to the
                          relatively continuous input of pollutants from point sources, the timing of loading
                          from diffuse sources is highly variable with intermittent loading related primarily to
                          meteorological events (storms and snowmelt). The magnitude of pollutant loads is
                          dependent on the area of the drainage basin, the characteristics of land uses,
                          including ground cover, and distribution of the volume of precipitation between
                          infiltration into shallow aquifers and surface runoff into streams and rivers.
                               Within a watershed undisturbed by human activities, naturally occurring
                          biogeochemical processes account for the continual cycles of organic and inor-
                          ganic materials (as uncontrollable nonpoint source loads)  transported from the
                          land to rivers, lakes, and estuaries, with eventual discharge of these materials to
                          the coastal ocean. Since it is the uses of the land and the  associated activities that
                          occur on the land within a drainage basin that contribute anthropogenic organic
                          and inorganic materials to surface waters, nonpoint source loading rates have
                          been related to the type of land use (Table 2-16). The most critical factor, how-
                          ever, in understanding the management of nonpoint source loading is characteriz-
                          ing the transition from one land use to another (e.g., forest to agriculture, agricul-
                          ture to suburban/urban).
Table 2-16. Nonpoint s<
Parameter
BOD5ab
TSS a'b
Total N b'c
Total P b'c
Durce runoff export
Urban
34-90
3,360-672
7.8-11.2
1.6-3.4
coefficients for g
Agriculture
26
1,600
16.5
1.1
eneral land uses
Forest
5
256
2.9
0.2
Units are kg/hectare-year
a Export coefficients for BOD5 and TSS for agriculture and forest categories from Thomann
and Mueller (1987).
b Range of export coefficients for urban land use categories I, II, and III from PLUARG
studies (Marsalek, 1978) presented by Novotny and Olem (1994) (Table 8.2, p. 449).
0 Mean export coefficients for total N and total P for mixed agricultural and forest land uses
from Reckhow et al. (1980).
2-52

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                                    Chapter 2: An Examination of BOD Loadings Before and After the CWA
     Beginning with the four natural land classifications (arid lands, prairie,
wetland, and woodland), the transformation of a watershed's land uses progresses
over many years through several intermediate stages of development to a fully
developed urban-industrial watershed (Novotny and Olem, 1994). With the
irreversible transformation to the endpoint of urban-industrial land uses of a
watershed, the emphasis in water quality management needs to incorporate
strategies for control of both nonpoint sources of runoff and the point source
discharges within the "urban-industrial" water cycle. In contrast to the control
strategy for point sources (build a wastewater treatment facility) as the most
effective technology for removal of pollutants from a point source waste dis-
charge, the reduction of nonpoint source loading of pollutants is focused on the
design and implementation of "best management practices" to control, and
manage, land use activities and surface runoff. As with urban runoff control
measures, the technical aspects of the numerous practices available for control-
ling nonpoint source runoff from forest, agricultural, and other rural land uses are
presented in detail by Novotny and Olem (1994).
     As part of its public works infrastructure, practically every town and city in
the nation has an urban stormwater sewer system designed to collect and  convey
water runoff from rainstorms and snowmelt. Depending on the development
characteristics of an urban area, stormwater runoff can result in significant
intermittent loading of pollutants to surface waterbodies. Based on findings from
the National Urban Runoff Project (NURP) conducted by USEPA from 1978 to
1983, USEPA (1983) concluded that urban runoff accounted for significant wet
weather loading to the Nation's surface waters of pathogens, heavy metals, toxic
chemicals, and sediments. The origins of the diffuse discharges of these pollutants
include contaminants contained in wet and dry atmospheric deposition, erosion of
pervious lands, accumulation of debris on streets, traffic emissions, and washoff
of contaminants from impervious land surfaces. Table 2-15 presents typical
discharges of conventional and nonconventional pollutants in urban runoff.


Estimates  of Contemporary (ca.   1995)  BOD5
Loading Using  the National Water  Pollution
Control  Assessment Model (NWPCAM)

     The NWPCAM is a national-scale water quality model designed to link point
and nonpoint source loadings and resultant calculated in-stream concentrations of
CBOD5, CBODu, DO, TKN, total suspended solids, and fecal coliform bacteria
with a "water quality ladder" of beneficial uses (Carson and Mitchell, 1983). The
framework for the model is EPA's Reach File Version  1 (RF1) national database
of streams, rivers, lakes, and estuaries and uses mean summer streamflow data to
characterize the steady-state loading, transport, and fate of water quality constitu-
ents. Presented for comparison purposes is current (ca. 1995) BOD5 loading
information derived using available NWPCAM national data for municipal and
industrial discharges, CSOs, and urban1 and rural nonpoint sources.
1   For purposes of this comparison, urban stormwaler runoff includes areas both outside (termed
   "nonpoint sources") and within (meeting the legal definition of a point source in section 502(14)
   of the CWA) the NPDES stormwater permit program.
                                                                                            2-53

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
                          BOD5 Loading from Municipal and Industrial Sources

                              The input data used to estimate municipal and industrial effluent loading of
                          BOD5 within the NWPCAM come from USEPA's Permit Compliance System
                          (PCS), the Clean Water Needs Survey (CWNS) databases,  and default assump-
                          tions derived from the literature. The PCS database contains discharge monitoring
                          data for major POTWs and industrial dischargers (facilities with a discharge
                          greater than 1 mgd). The CWNS database provides a more  comprehensive
                          database of all POTWs and generally reliable population, flow, and treatment level
                          information. Less confidence is placed on the effluent concentration data reported
                          in the  CWNS database. Therefore, when actual discharge data were available
                          from PCS, those data were used. PCS data were also used to develop default
                          effluent concentrations to apply when a facility's actual concentration was not
                          available or was outside normal ranges expected for a given level of treatment.

                          Municipal

                              Table 2-17 presents a compilation of characteristic effluent concentrations
                          of conventional and nonconventional pollutants used in NWPCAM for different
                          types of municipal POTWs.  The data sets extracted from USEPA's PCS and
                          CWNS databases are supplemented by influent and effluent data taken from the
                          literature (e.g., AMSA, 1997; Metcalf and Eddy, 1991; Clark et al., 1977; Leo et
                          al.; 1984; Thomann and Mueller, 1987).
                              A total of 1,632 of the 2,111  hydrologic catalog units in the contiguous United
                          States are subject to municipal effluent loading. Figure 2-18 presents distributions
                          of municipal BOD5 loading by percentile of catalog units with nonzero municipal
                          loads according to (a) loading rate and (b) fraction of total municipal loading.
                          Figure 2-19 presents a map showing the magnitude of municipal effluent loading
                          of BOD5 aggregated for the 1,632 catalog units with nonzero municipal loads.
                          Figure 2-20 displays the proportion of the total nonpoint and point sources load
                          contributed by municipal waste loads.
                               Key observations from Figures 2-18 through 2-20 include the following:
                              •   Less than 1 percent of the 1,632 catalog units subject to municipal
                                  loading receive effluent BOD5 loading at a rate greater than 25 metric
                                  tons/day (Figure 2-18a). About 20 percent of the catalog units account
                                  for about 90 percent of the total municipal BOD5 loading to the
                                  Nation's waterways (Figure 2-18b).
                                  Relatively low municipal BOD5 loading rates (less than 0.5 metric ton/
                                  day) characterize many of the catalog units within the western and
                                  central portions of the contiguous 48 states.
                                  Higher rates  of municipal loading (0.5 to 5 metric tons/day) are charac-
                                  teristic of the Mississippi River valley and the Northeast, Midwest, and
                                   Southeast. The highest loading  rates (> 25 metric tons/day) are for
                                   major urban  centers, including New York, Boston, Los Angeles, San
                                   Diego, Dallas-Ft. Worth, Detroit, and San Francisco.
2-54

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                                       Chapter 2: An Examination of BOD Loadings Before and After the CWA
Table 2-17.  Effluent characteristics for POTWs.
 Parameter
  (mg/L)
(Influent)
  Raw
Primary
Advanced
 Primary
Secondary
              Advanced
Advanced  Wastewater
Secondary   Treatment
 BOD.
   Mean
   % Removal
   Reference/Notes
  205.0
    0
   a,/
 143.5
   30
   b
  102.5
    50
    C
   16.4
    92
     a
    6.2
    97
    a,d
4.1
98
a, d
CBODJCBOD5
Mean
Reference/Notes
TSS (mg/L)
Mean
% Removal
Reference/Notes
NH3-N (mg-N/L)
Mean
% Removal
Reference/Notes
TKN (mg-N/L)
Mean
% Removal
Reference/Notes
Total N (mg-N/L)
Mean
% Removal
Reference/Notes
Total P (mg-P/L)
Mean
% Removal
Reference/Notes
DO (mg/L)
Mean
Reference/Notes
Total Organic Carbon (mg/L)
Mean
% Removal
Reference/Notes

1.2
e

215
0
a,/

18.0
0
a

30.0
0
a

30.0
0
9

6
0
a

4.1
/

148.6
0
9

1.6
f

107.5
50
b

14.4
20
b

23.4
22
b

23.4
22
h

5.2
13
b

4.3
y

107.5
28
b, k

1.6
f

64.5
70
c

14.4
20
b

23.4
22
b

23.4
22
h

5.2
13
b

4.3
1

76.8
48
/f

2.84
f

17.2
92
a

12.2
32
a

16.5
45
a

18.3
39
a

2.5
58
a

6.6
/

21.8
85
b,k

2.84
f

6.5
97
a,d

3.4
81
a,d

12.9
57
a,d

18.4
39
a,d

0.4
94
a,d

6,6
y

8.2
94
k

3.0
f

4.3
98
a,d

2.0
89
a,d

3.6
88
a, of

14.4
52
a,d

0.4
94
a,d

7.1
y

5.8
96
/r
References/Notes
a. AMSA, 1997. Influent concentration, percent removal, and TKN:TN, NH3:TKN, and P04:TP ratios for secondary, advanced
secondary, and advanced wastewater treatment,  b. Gunnerson et al., 1982. c. NRC, 1993. Percent removal for advanced
primary with "low dose chemical addition." rf. MWCOG,  1989. Percent removal and TKN:TN, NH3:TKN, and PO4:TP ratios for
advanced secondary, and advanced wastewater treatment,  e. Thomann and Mueller, 1987.  f. Leo et al., 1984. g. Metcalf
and Eddy, 1991. TKN:TN, NH3:TKN, and PO4:TP ratios of influent concentration for "medium" strength wastewater, raw TOC
influent concentration based on BOD6, CBOD^BOD,, oxygen:carbon, and ratios of C:DW. h. ICPRB, 1991. TKN.TN, NH3:TKN,
and P04:TP ratios of effluent concentration for primary, advanced primary, and secondary treatment.  I. Assume 50 percent
saturation at 25 °C and 50 mg/L chlorides at sea level. ]. Tetra Tech, 1999. Mean effluent oxygen concentrations based on
PCS database for primary, secondary, and advanced treatment. Mean influent concentrations for BOD5 (207 mg/L) and TSS
(209 mg/L) from CWNS database consistent with influent data from AMSA (1997).  k. Effluent TOC concentration computed
from effluent BODS, CBODU:BOD6, oxygenxarbon ratio and assumption that 80 percent of organic carbon is accounted for by
BOD6 measurement. Removal efficiencies computed for primary and secondary treatment are  consistent  with data from
Gunnerson et al., 1982.
                                                                                                      2-55

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
Figure 2-18
Distribution of municipal
BOD5 loading by percentile
of catalog units subject to
municipal loading
(N=1,632) as (a) metric
tons/day and (b) fraction of
total municipal  loading
rate.
Source: Bondelid et al.,
1999.
(a)
           -§   300-
           ^/5

           S   250 H
           ,§_  200-1

           O>
           i   150-1
           re
           o
           10
           Q
           O
           CD
                                      a>
                                      3
                                      E
                                      LLJ
100-
                                           50-
    0   0.5   1    1.5   2    2.5    3    3.5
                 Percentile of Catalog Units
                                                                4.5
                           (b)
           0)
           O)
           re
           £
           0)
           H
           0)
           0.
           •o
           re
           o
           in
           Q
           O
           CO
                                     o>
                                     i
                                                        10    15    20   25   30   35   40   45
                10
                                                          Percentile of Catalog Units
                                    The municipal wastewater component of total point and nonpoint
                                    source load of BOD5 tracks closely with the results of the loading
                                    magnitude calculation. The municipal wastewater component is highest
                                    around major urban centers and lowest in the western and central
                                    portions of the contiguous 48 states.
2-56

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                                         Chapter 2: An Examination of BOD Loadings Before and After the CWA
                                                                                 IfGBVD
                                                                                 CZDO metric tens/d£y
                                                                                 Bi 0- 0.5 metrictonsWay
                                                                                 	0.5-5matrictonsWay
                                                                                 I   15-10 mstrictons'day
                                                                                    10-25 metric tons'day
                                                                                 ^•> 25 metric tore/day
Figure 2-19
Municipal wastewater
loading of BOD5 ca. 1995
by catalog unit (metric tons
per day).
Source: Bondelid et al.,
1999.
Figure 2-20
Municipal wastewater
component of total point
and nonpoint source
loading of BOD5 ca. 1995
by catalog unit (percent of
total).
Source: Bondelid et al.,
1999.
                                                                                                        2-57

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
                         Industrial

                              Similar to the two municipal maps, Figure 2-21 presents the magnitude of the
                         industrial effluent loading of BOD5 aggregated for a total of 1,504 catalog units
                         with nonzero industrial loads. Figure 2-22 displays the proportion of the total
                         nonpoint and point sources load accounted for by industrial waste loads.
                              Key observations include the following:
                              •    Relatively low industrial BOD5 loading rates (< 0.5 metric ton/day)
                                  characterize many of the catalog units in the western and central
                                  portions of the 48 states.
                              •    Higher rates of industrial loading (0.5 to 5 metric tons/day) are charac-
                                  teristic of the Mississippi River valley, the Northeast, Midwest, and
                                  Southeast. The highest loading rates (> 25 metric tons/day) are indi-
                                  cated for major urban industrial watersheds including Austin-Oyster in
                                  Texas, East-Central in Louisiana, Buffalo-San Jacinto and Galveston
                                  Bay, and the Locust River, Upper Black Warrior, and Middle Coosa
                                  basins in Alabama.
                              •    Industrial loads are the dominant component (>75 percent) of the total
                                  point and nonpoint source load in many catalog units associated with
                                  major urban-industrial areas, particularly in the Southeast. Although not
                                  shown, the frequency distributions of industrial BOD5 loads (as a
                                  percentile of catalog units with nonzero industrial loads) are very similar
                                  to those presented for municipal BOD5 loads.

                         BOD5 Loading From CSOs

                              Effluent loadings for CSOs were based on an analysis performed in support
                         of the  1992 Clean Water Needs Survey (CWNS) (Tetra Tech,  1993) and subse-
                         quently adopted for the NWPCAM. During this 1992 CWNS, it was estimated
                         that there were approximately 1,300  CSO facilities in the United States (USEPA,
                         1993). The number of facilities was substantially reduced to 880 during the 1996
                         CWNS.
                              The effluent loading for CSOs used in the NWPCAM is based on comput-
                         ing a pulse load based on the runoff volume and pollutant load associated with a
                         5-year, 6-hour storm event.  Runoff was computed as a function of the combined
                         sewer  system's population,  service area, and imperviousness. For the purposes of
                         the NWPCAM, the pollutant loading used in the model was estimated to  yield a
                         national BOD5 loading of 15 metric tons/day (Bondelid et al., 1999). As expected,
                         most of the CSO loading is  accounted for by older cities in the  New England,
                         Middle Atlantic, Great Lakes, Ohio River, and Upper Mississippi basins.
2-58

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                                         Chapter 2: An Examination of BOD Loadings Before and After the CWA
                                                                                 l£GBf)
                                                                                 CHOmeWc tens/day
                                                                                 • 0- 0.5 metrictoiWday
                                                                                 ESBjaS-SmetictonsftJay
                                                                                 [H]5-10mB(ric1cns*Jay
                                                                                    10-25 metric tons/day
                                                                                    I > 25 nBlric tore/day
Figure 2-21
Industrial wastewater
loading of BOD,
by catalog unit (metric tons
per day).
Source: Bondelid et al.,
1999.
Figure 2-22
Industrial wastewater
component of total point
and nonpoint source
loading of BOD5 ca. 1995
by catalog unit (percent of
total).
Source: Bondelid et al.,
1999.
                                                                                                         2-59

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment


                          BOD5 Loading From Urban Stormwater Runoff and Rural
                          Nonpoint Sources

                               Nonpoint source BOD5 loading data were developed on a county-level basis
                          by Lovejoy (1989) and Lovejoy and Dunkelberg (1990), with urban Stormwater
                          runoff and rural runoff loadings reported separately. These values were con-
                          verted into loadings allocated to each catalog unit in the contiguous 48 states
                          based on the proportion of a county's area in a given catalog unit. For the
                          NWPCAM, the rural loadings were disaggregated based on stream  length in a
                          given county while urban loadings were disaggregated based on stream length and
                          population associated with a given stream.
                               Using the loading data compiled for the NWPCAM, the national catalog
                          unit-based distributions of urban Stormwater and rural BOD5 loading are pre-
                          sented in Figures 2-23 and 2-24 (urban) and Figures 2-25 and 2-26 (rural). The
                          map sets present both the magnitude of the loading rate (as metric tons per day)
                          and the percentage of the total point and nonpoint source load accounted for by
                          the urban and rural runoff contributions, respectively.
                               Key observations include the following:
                               •    With the exception of urban areas on  the west coast and in the Mid-
                                   west and Northeast, low loading rates (< 0.5  metric tons/day) charac-
                                   terize most of the Nation's watersheds for urban runoff loads.
                               •    In urban areas, loading rates are typically less than 5 metric tons/day,
                                   accounting for about 25 to 75 percent of the total point and nonpoint
                                   source BOD5 load discharged to a catalog unit.
                               •    Rural loading rates of BOD5 are characterized by a distinctly different
                                   geographic distribution, with the highest rates (> 25 metric tons/day)
                                   estimated for the upper Missouri basin. Intermediate loading rates of 5
                                   to 25 metric tons/day of BOD5 characterize rural runoff in the Mis-
                                   souri, Upper Mississippi, and Ohio river basins. The lowest rates (< 0.5
                                   metric tons/day) are estimated for the coastal watersheds of the east
                                   coast and Gulf of Mexico  and the arid areas  of the western states.
                               •    Rural nonpoint source loads of BOD5 are the dominant component
                                   (> 75 percent) of total point and nonpoint source loads in vast areas of
                                   the Nation, principally west of the Mississippi River and in the Ohio
                                   River Basin.
                               •    The geographic distribution of relatively low contributions of rural
                                   runoff (< 25 percent) is consistent with the locations of large urban-
                                   industrial areas (e.g., New York, Boston, Miami, New Orleans, Chi-
                                   cago, Seattle, San Francisco, Los Angeles).
                          1  For purposes of this comparison, urban Stormwater runoff includes areas both outside (termed
                             "nonpoint sources") and within (meeting the legal definition of a point source in section 502(14)
                             of the CWA) the NPDES Stormwater permit program.


2-60

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                                         Chapter 2: An Examination of BOD Loadings Before and After the CWA
                                                                                   IEGBJD
                                                                                   I   10 metric tons/day
                                                                                   •H 0- 0.5 metric tonsfaay
                                                                                       05 - 5 metrictonsWay
                                                                                   I   l5-10metrictonsMay
                                                                                       10 -25 metric tore/day
                                                                                      I > 25 metric tons/day
Figure 2-23
Urban  nonpoint loading of
BOD5 ca. 1995 by catalog
unit (metric tons per day).
Source: Bondelid et at.,
1999.
                           Note: Urban stormwater runoff includes areas both outside and within the
                                 NPDES stormwater permit program.
Figure 2-24
Urban nonpoint
component of total point
and  nonpoint source
loading of BOD5 ca.  1995
by catalog unit (percent of
total).
Source: Bondelid et  ai,
1999.
Note: Urban stormwater runoff includes areas both outside and within the
     NPDES stormwater permit program.
                                                                                                           2-61

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
                                                                                   LEG00J
                                                                                   dUO metric tens/day
                                                                                   Has 0- 0.5 metric taWday
                                                                                      0.5 - 5 metrictonsWay
                                                                                   I   15-10 metric tons/day
                                                                                   EZ3 10-25 metric tons/day
                                                                                   M> 25 metric tors/day
Figure 2-25
Rural nonpoint loading of
BOD5 ca. 1995 by catalog
unit (metric tons per day).
Source: Bondelid et al.,
1999.
Figure 2-26
Rural nonpoint component
of total point and nonpoint
source loading of BOD5 ca.
1995 by catalog unit
(percent of total).
Source: Bondelid et al.,
1999.
2-62

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                                   Chapter 2: An Examination of BOD Loadings Before and After the CWA
Comparison of Point and Nonpoint Sources  of
BODK at the National Level
      i)
     From a national perspective, BOD5 loading from municipal facilities cur-
rently (ca. 1995) accounts for only about 38 percent of total point source loadings
and only 21 percent of total loadings (point and nonpoint). Industrial facilities
(major and minor) account for about 62 percent of total point source BOD5
loadings and 34 percent of total BOD5 loadings. Rural nonpoint source loads
account for about 40 percent of the total BOD5 loading rate. Urban stormwater
runoff and CSOs, although significant in most urban waterways, account for a
small share (5 percent) of the total nationwide load (Bondelid et al.,  1999).
     Based on this analysis of contemporary sources of loading of BOD5,
continued maintenance and improvement of water quality conditions of the
Nation's surface waters will clearly require an integrated, watershed-based
strategy, such as that presented in the USEPA's (1998) Clean  Water Action
Plan, including the appropriate management of point and nonpoint sources of
BOD5 and other pollutants (e.g., nutrients, suspended solids, toxic chemicals,
pathogens).
F.    Investment Costs for  Water Pollution

       Control  Infrastructure

     The analysis presented in Section D indicates that nationwide effluent BODu
loadings from POTWs were reduced by 23 percent between 1968 and 1996.
Examination of historical trends in industrial wastewater loads also suggests
substantial declines in BOD loads from industrial point sources have been
achieved since the early 1970s (see Luken et al., 1976). Declines can be credited
to industrial pretreatment programs, upgrades of industrial wastewater treatment
as required by the NPDES permit program, abandonment of obsolete manufactur-
ing facilities in the Midwest and Northeast "rustbelt" (Kahn, 1997), and improved
efficiency in industrial water use (Solley et al., 1998). The purpose of this section
is to provide an overview of the costs of implementing public and private water
pollution control programs.

The Construction Grants Program
     The Water Pollution Control Act of 1956 was significant because it both
established and funded a grant program for the construction of POTWs for the
purpose of ensuring the implementation of adequate levels of municipal waste
treatment as a national policy for water pollution control. Following the 1956
Amendments, however, federal funding ($5.1 billion allotted from 1957 to 1972)
accounted for only a small portion of the total construction costs for municipal
facilities (FWPCA, 1970). The CWA made it a national policy to provide federal
grants to assist in the upgrade and construction of municipal wastewater facilities.
The 1972 act authorized $5.0 billion in federal spending for fiscal year 1973, $6.0
billion for fiscal year 1974, and $7.0 billion for fiscal year 1975. Under the re-
vamped Construction Grants Program, the federal share was 75 percent of cost
from fiscal years 1973 to 1983, and 55  percent thereafter.
                                                                                         2-63

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
                               USEPA's Grants Information and Control System (GICS) database is the
                          central repository of Construction Grants Program data. For the following finan-
                          cial analysis, grant awards in the GICS database were indexed to constant 1995
                          dollars using the Chemical Engineering Plant Cost Index (CE, 1995) for the
                          purpose of providing a suitable indicator of the inflation of wastewater treatment
                          facility construction costs.

                          National Summary

                               During the 25-year period from 1970 to 1999, the Construction Grants
                          Program distributed a total of $61.1 billion in federal contributions ($96.5 billion as
                          constant 1995 dollars) to municipalities for new construction and upgrades of
                          POTWs to secondary and greater levels of wastewater treatment (Figure 2-27).
                          An additional $16.1 billion (capitalization) in federal contributions was also distrib-
                          uted to the states through the Clean Water State Revolving Fund (CWSRF)
                          Program from 1988 through  1999 (Figure 2-27). Additional state match, state-
                          leveraged bonds, loan repayments, and fund earnings increased CWSPvF assets
                          by $18.4 billion. Since 1988, therefore, the CWSRF loan program assets have
                          grown to over $30 billion, and they are funding about $3 billion in water quality
                          projects each year.
Figure 2-27
Annual funding provided by
USEPA's Construction
Grants and CWSRF
programs to local
municipalities for
improvements  in water
pollution control
infrastructure as  (a) annual
allotments for each
program and (b)
cumulative funding from
both programs from 1970
to 1999.
Source: USEPA GICS
database and CWSRF
Program.
                           (a)
                                      n
                                     o
                                     O
                                     0>
7-

6-

5-

4-

3-

2-

1-

0
                                                                   Construction Grants
                                                                   CWSRF

 1970    1975    1980    1985    1990    1995
                        Year
                                                                                       2000
-v 70-
c
.0
§ 60-
•Q
^ 50-
0 40-
S 30-
8 20-
- 10-
n

• Construction Gr?
m CWSRF
nts



,ll
llll
..llllll

-
-


^


S


                                          1970    1975    1980    1985    1990    1995
                                                                 Year
                                                                                       2000
05
05
O5

                                                                                                <5
                                                                                                   
                                                                                                §1
                                                                                                O  o
                                                                                                I I
                                                                                                o =
                                                                                                05-°
                                                                                                05 i-
                                                                                                O
2-64

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                                      Chapter 2: An Examination of BOD Loadings Before and After the CWA
                    0   10   20  30   40  50   60   70  80   90   100
                               Percentile of Catalog Units
                                                                              Figure 2-28
                                                                              Cumulative funding of
                                                                              Construction Grants
                                                                              Program awards as a
                                                                              percentile of  2,111  catalog
                                                                              units.
                                                                              Source: USEPA GICS and
                                                                              reach file Version 1 (RF1)
                                                                              databases.
Summaries by Catalog Unit

     Awards data extracted from the GICS database were assigned to each of
the 2,111 catalog units of the 48 contiguous states by matching city names and
counties with corresponding catalog units. Of the total amount of funding awards
in the GICS database ($61.1 billion), only a small fraction (less than 1 percent) of
the awards could not be assigned to a specific catalog unit. In addition, approxi-
mately 2 percent of the GICS funding was awarded to watersheds located outside
the 48 contiguous states. (This accounts for the discrepancy between a total
national investment of $61.1 billion and the investment of $59.2 billion that was
allocated to  the 48 contiguous states.)
     Figure 2-28 presents the cumulative distribution of the GICS funding awards
(total $59.2 billion) as a percentile of the 2,111 catalog units within the contiguous
48 states. Twenty percent of the catalog units account for about 88 percent of the
funding. There is also a relationship between the municipal BOD5 loading rate
(ca. 1995) and the Construction Grants award allocated to each catalog unit.
Increased municipal loading rates related to larger facilities resulted in increased
grant awards from the Construction Grants Program (Figure 2-29).
  _-  10,000,000
  10   1,000,000-
  O)            J
CO
•o
c
LL.
in


O
o
  o
  O
        100,000-

         10,000-

         1,000-

           100-

            10
1         10        100      1,000     10,000    100,000   1,000,000
      Municipal BODs Loading for Catalog Unit (kg/day)
                                                                Figure 2-29
                                                                Relationship of municipal
                                                                BOD5 loading rate ca. 1995
                                                                and EPA Construction
                                                                Grants Program awards by
                                                                catalog unit.
                                                                Source:  USEPA GICS
                                                                database and Bondelid et
                                                                al.,  1999.
                                                                                                 2-65

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment


                          Other Investment  Costs for Water Pollution  Control
                          Infrastructure

                              In addition to the federal expenditures through the Construction Grants
                          Program, state and local governments and private industries have made significant
                          investments to comply with the water pollution control requirements of the CWA
                          and other state and local environmental legislation. On a nationwide basis, actual
                          expenditure data compiled by the U.S.  Department of Commerce, Bureau of
                          Economic Analysis in the annual Pollution Abatement Cost Expenditures
                          (Vogan, 1966) document a cumulative public and private sector capital expendi-
                          ture of approximately $200.6 billion and an additional $210.1 billion as operating
                          expenditures  (capital and operation and maintenance costs as current year
                          dollars) for water pollution control activities during the period from 1972 through
                          1994 (Figure  2-30).
                              As shown in Table 2-18, current year dollars compiled in the annual survey
                          have been indexed to constant 1995  dollars using the Chemical Engineering
                          Plant Cost Index for capital costs and the consumer-based Gross Domestic
                          Product for operating costs as appropriate indices. The Construction Grants
                          Program provided federal grant support to local municipalities that amounted to
                          almost one-half of the public sector costs and about one-third of the total public
                          and private sector capital investment  for water pollution control.
Figure 2-30
Annual water pollution control expenditures (as current year dollars) by the public and private sectors for capital and
operations and maintenance costs from 1972 through 1994.  Source: Vogan (1996).
            35-,
                             D O & M - Private
                               Capital - Private
                               O & M - Public
                               Capital - Public
               1972  1974  1976  1978  1980  1982  1984  1986  1988  1990  1992  1994
                                                    Year
2-66

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                                      Chapter 2: An Examination of BOD Loadings Before and After the CWA
  Table 2-18.  National public and private sector investment in water pollution control infrastructure, 1956-1994.

                              EPA                 EPA         Public       Private   Public + Private
                      Construction Grants         CWSRF        Sector       Sector       Sectors
                   (1956-1972)   (1970-1995)   (1988-1999)    (1972-1994)   (1972-1994)   (1972-1994)
   Current Year Dollars
    Capital             $5.1          $61.1          $16.2         $132.4        $68.2        $200.6
    O&M              n/a           n/a           n/a          $121.2        $88.9        $210.1
          Totals       $5.1          $61.1          $16.2         $253.6       $157.1        $410.7
   Equivalent as Constant 1995 Dollars
    Capital            $14.3         $96.5          n/a          $178.9         $93.5        $272.4
    O&M              n/a           n/a           n/a          $175.5       $128.1        $303.6
          Totals      $14.3         $96.5          n/a          $354.4       $211.6        $576.0

  Sources:
    1. EPA Construction Grants Program (1956-1972): data obtained from EPA-OWM files compiled by R.K. Bastian, March 1992.
    2. EPA Construction Grants Program (1970-1995): data obtained from EPA GICS database, August 1995.
    3. EPA Clean Water State Revolving Fund (CWSRF) (1988-1999): data from EPA-OWM files by  R.K. Bastian, April 2000.
    4. Public and private sector (1972-1994): Data from Vogan (1996). Data obtained from T. Gilliss, EPA-OPPE, 1997.
    5. Current year dollars adjusted to equivalent constant 1995 dollars. Plant Cost Index obtained from Chemical Engineering
      (CE, 1995) for capital expenditures. Gross Domestic Product for O&M costs obtained from Council of Economic Advisors
      (1997).
Future Infrastructure Needs

     USEPA (1997) estimates that by 2016 approximately 2,400 new facilities
with secondary or greater than secondary levels of treatment will be needed to
service an additional 85 million people (a 45 percent increase of total population).
Further, during that time period the Agency estimates that 115 of the approxi-
mately 176 POTWs currently providing less than secondary treatment will
upgrade their facilities to meet the minimum technology requirements of second-
ary treatment under the CWA. USEPA estimates  the costs for POTW construc-
tion and upgrades to be $75.9 billion (indexed to constant 1996 dollars).
     Further, USEPA plans to put more emphasis on "wet weather" sources of
pollution, including CSOs and storm water drainage from agricultural, silvicultural,
city, and suburban lands. USEPA (1997) has estimated these associated federal
costs to include the following:
     •    $44.7 billion (indexed to constant 1996 dollars) to meet infrastructure
         needs associated with  CSOs.
     •    $7.4 billion  (indexed to 1996 dollars) to meet the Clean Water State
         Revolving Fund (CWSRF)-eligible portion of the costs that the munici-
         pal separate storm sewer systems are expected to incur for the devel-
         opment and implementation of a stormwater management program in
         response to  the Phase  I NPDES stormwater program regulations.
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                                  $3.8 billion (indexed to 1996 dollars) to meet the CWSRF-eligible
                                  projects related to cropland, pastureland, and rangeland.
                                  $2.1 billion (indexed to 1996 dollars) to meet the CWSRF-eligible
                                  projects related to confined animal facilities with fewer than 1,000
                                  animal units.
                                  $3.5 billion (indexed to 1996 dollars) to meet the CWSRF-eligible
                                  projects related to silviculture.


                         G.   Summary, Conclusions, and  Future

                                Trends

                              The purpose of this chapter is to address the first leg of the three-legged
                         stool approach for answering the question posed in Chapter 1—Has the Clean
                         Water Act's regulation of waste-water  treatment processes at POTWs been a
                         success? Recall that the basic goal of this first leg is to examine the extent to
                         which the Nation's investment in building and upgrading POTWs to secondary
                         and greater than secondary wastewater treatment resulted in a decrease in
                         effluent BOD loading to the Nation's waterways. If evidence showed that these
                         investments achieved significant reductions in the discharge of oxygen-demanding
                         organic wasteload to the Nation's waterways, the first leg of the investigation
                         could add cumulative support for the conclusion that the CWA's mandates were
                         successful.
                              This section summarizes the key points  presented in Sections A through F
                         of Chapter 2, discusses conclusions, and addresses future trends in wastewater
                         infrastructure requirements.

                         Key  Points of the Background Sections

                              Specifically discussed in Sections A and B is the significance of water
                         supply and wastewater treatment in the urban water cycle, the invention of
                         secondary treatment, and the use of biochemical oxygen demand (BOD) as a
                         measure of the pollutional strength of organic wasteloads. Section C focuses on
                         the roles the federal government and the CWA played in establishing, and funding,
                         secondary and greater than secondary treatment in the Nation's POTWs.
                              Key points made in Sections A through C include the following:
                             •   All components of the urban water  cycle must be in place and function-
                                 ing properly to satisfy the needs of both water supply and water
                                 resource users.
                                 In the "Great Sanitary Awakening"  in the late 19th and early 20th
                                 centuries, public infrastructure investment was focused primarily on the
                                 water supply side of the urban water cycle and sewage collection
                                  systems for the control of waterborne diseases and protection of public
                                 health.
                             •   Increasing urban populations  in the first half of the 20th century exac-
                                 erbated water quality problems associated with the discharge of
                                 inadequately treated sewage in urban waterways.
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                                    Chapter 2: An Examination of BOD Loadings Before and After the CWA
        Secondary treatment proved to be a breakthrough discovery in treating
        wastewater; by 1930 several cities, especially in the Northeast, Mid-
        west, and far West, had incorporated the technology into their waste-
        water treatment systems.
        Before 1972 and the passage of the CWA, municipal and industrial
        wastewater discharges were regulated by  individual states based on
        state ambient water quality standards. The federal government's
        authority for water pollution control was restricted to interstate water-
        ways under the Commerce clause of the U.S. Constitution.
        The passage of the CWA resulted in the federal government's assum-
        ing a greater role in directing and defining  water pollution control
        programs in the Nation. The states' water quality-based approach for
        regulating wastewater discharges was replaced by the CWA's two-
        pronged approach—a mandatory technology-based approach supple-
        mented by a water quality-based approach on an  as-needed basis—and
        enforced under the National Pollutant Discharge Elimination System
        permit program.
        Section 301 of the CWA required POTWs to achieve effluent
        limitations based on secondary treatment as the minimum level of
        technology.


Key Points of the BOD  Loading Analysis Sections

     Establishing a national policy requiring secondary treatment of municipal
wastewater as the minimum acceptable technology supplemented by more
stringent water quality-based effluent controls on a site-specific, as-needed basis
was a key provision of the 1972 CWA. This mandate, coupled with an increase in
funding assistance to municipalities through the Construction Grants Program, led
to a dramatic increase in the number of POTWs with secondary and greater than
secondary treatment capabilities.
     Section D examines several national POTW trends, including the population
they serve, influent and effluent BOD loadings, and BOD removal efficiencies.
Key findings include the following:
     •   The U.S.  population served by POTWs  with secondary or greater
        treatment almost doubled between 1968 and 1996 from 85.9
        million people in 1968 to 164.8 million  people  in 1996!
     •   BOD  loading to POTWs (influent loading) increased significantly.
        In 1968 influent BODu loading was 34,693 metric tons per day. By
        1996 influent BODu loading stood at 46,979 metric tons per  day, a 35
        percent increase from 1968! The same  trend was seen for influent
        BOD5 loading to POTWs.
     •   Effluent BOD  loading discharged by POTWs  was significantly
        reduced. In 1968 effluent BODu loading was 21,281 metric tons per
        day. By 1996 effluent BODu loading stood at 16,325 metric  tons per
        day, a 23 percent decrease from 1968! Effluent BOD5 loading was also
        significantly reduced (by 45 percent)  over the same time period.
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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment


                                   BOD removal efficiency increased significantly. In 1940 the aggre-
                                   gate national removal efficiency stood at about 33 percent for BOD5
                                   and 20 percent for BODu. By 1968 removal efficiencies had increased
                                   to 63 percent for BOD5 and 39 percent for BODu. By 1996 these had
                                   increased to nearly 85 percent for BOD5 and 65 percent for BODJ
                              •    Increasing numbers of people served  by POTWs in the  21st cen-
                                   tury will likely reverse the trend established between 1968 and
                                   1996 of decreasing effluent BOD loading to the Nation's water-
                                   ways. Assuming that national aggregate design-based BODu removal
                                   efficiency will increase to 71 percent, influent wastewater flow will
                                   remain a constant 165 gpcd, and influent BODu concentrations will
                                   remain a constant 396.5 mg/L, population projections indicate that by
                                   2016 effluent BODu loading will increase by 20 percent to 19,606
                                   metric tons per day, equivalent to the rate in the mid-1970s. It is
                                   projected that by 2025 the effluent BODu loading will be 21,280 metric
                                   tons per day, a rate approximately equal to that observed in 1968 when
                                   the discharge of oxygen-demanding material from POTWs reached its
                                   historical peak!
                              •    By 2016, when the projected needs for wastewater treatment are
                                   expected to be met (USEPA, 1997),  the overall BODu removal
                                   efficiency of 71 percent and increases in population will result in a
                                   20 percent increase of effluent loads  relative to the 1996 loading
                                   rate. To maintain an effluent BODu loading rate comparable to 1996
                                   conditions through 2016 (i.e., "running in place"), the national aggregate
                                   removal efficiency would have to be increased from 71 to  76 percent.
                                   This would need to be accomplished by shifting the projected population
                                   served from secondary to advanced secondary and advanced waste-
                                   water treatment facilities.
                               Section E presents a national "snapshot" comparison of contemporary (ca.
                          1995) BOD5 loadings from POTWs and other point and nonpoint sources based
                          on available data from PCS and the Clean Water Needs  Survey. Using the
                          NWPCAM (Bondelid et al., 1999), BOD5 loadings were estimated for municipal
                          (POTW) and industrial point sources (major and minor), CSOs, and rural and
                          urban1 nonpoint sources. Loading data for each category were aggregated by
                          catalog units and major river basins. The inclusion of other loading sources in this
                          modeling exercise helps put the municipal loading component in perspective with
                          total nationwide BOD5 loading from all sources. Key findings include the follow-
                          ing:
                              •    Of the  2,111 catalog units in the contiguous United States, 1,632
                                   receive municipal discharges.
                              •    Twenty percent of catalog units account for 90 percent of the total
                                   municipal BOD5  loading. Highest rates of municipal loading of BOD5
                                   occurred in the Mississippi  River Valley and the Northeast and
                                   Midwest.
                          1   For purposes of this comparison, urban stormwater runoff includes areas both outside (termed
                             "nonpoint sources") and within (meeting the legal definition of a point source in section 502(14)
                             of the CWA) the NPDES stormwater permit program.
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                                    Chapter 2: An Examination of BOD Loadings Before and After the CWA
    •   Municipalities (POTWs) are the dominant source of the BOD}
        component in catalog units associated with major urban areas.
        Several urban areas had rates greater than 25 metric tons per day.
    •   Municipal BOD; loadings account for about 38 percent of total
        point source loadings and 21 percent of total loadings  (point and
        nonpoint).
    •   Industrial (major and minor) BOD5  loadings account for  about 62
        percent of total point source loadings and 34 percent of total
        loadings  (point and nonpoint).
    •   Urban stormwater  and CSOs account for about 5 percent of total
        nonpoint  source loadings and 2 percent of total loadings (point
        and nonpoint).
    •   Rural nonpoint source BOD} loadings account for  about  95
        percent of total nonpoint source loadings and 43 percent  of total
        loadings.
     Clearly, continued improvement in water quality conditions of the Nation's
waterways will require an integrated strategy to address all pollutant sources,
including both point and nonpoint sources.

Key Points  of  the Investment Costs  Section

     Section F focuses on investment costs associated with water pollution
control. It includes a discussion of the Construction Grants Program and provides
summaries of program spending for new construction and upgrades of POTWs.
Also included in this section are  summaries of public and private investment totals
in point source water pollution control. Key findings include the following:
    •   From 1970  to 1995 the Construction Grants Program has distrib-
        uted $61.1 billion (as current year dollars)  to municipalities for
        POTW building and upgrades. The federal share was 75 percent of
        total costs from fiscal  years 1973 to 1983, and 55 percent thereafter.
        From 1988  to 1999 an additional $16.1 billion (capitalization) in
        federal contributions  was also distributed to the states through the
        Clean Water State Revolving Fund.
    •   From 1972  to 1994 approximately $200.6 billion in capital costs
        and $210.1  billion  in operation and maintenance costs  (as current
        year dollars) were  spent by the public and private sectors for point
        source water pollution control. Based on these figures, the  Construc-
        tion Grants Program has contributed almost one-half of the public
        sector costs and about one-third of the total public and private sector
        capital investment for point source water pollution control.
    •   Excluding combined sewer systems and urban stormwater controls,
        EPA estimates $75.9 billion (1996 dollars) will  be required to meet
        traditional wastewater treatment plant (and sewer)  needs  through
        the year 2016 (USEPA, 1997).
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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
      Conclusion of
        the first leg
        of the stool
    There was a dramatic
   nationwide decrease in
    fromPOTWs after the
     1972 CWA despite a
     population served!
Conclusions  and Future Trends

     Based on the results of the analyses presented in this chapter, the study
authors propose the following conclusion regarding the first leg of the three-
legged stool approach concerning the Nation's investment in building and upgrad-
ing POTWs to achieve at least secondary treatment: The CWA's mandated
POTW upgrades to  at least secondary  treatment, combined with financial
assistance from the  Construction Grants Program and Clean Water State
     Revolving Fund,  resulted in a dramatic decrease in effluent BOD
     loading from POTWs to the Nation's waterways. This decrease  was
     realized in spite of significant increases in influent BOD loading that oc-
     curred due to increases in the population served by POTWs.
          Based on  needs data submitted by  the states, EPA projects that by the
     year 2016,18,303 POTWs in the United  States will be serving a population
     of 274.7 million (USEPA, 1997). Excluding combined sewer systems and
     storm water controls, the Agency estimates that $75.9 billion (1996 dollars)
     will be required to meet traditional wastewater treatment plant  and sewer
     needs at this projected level of service. Based on these projections, influent
     BODu loading in 2016 is estimated to be  about 68,030 metric tons per day, a
     45 percent increase in influent BODu loading from 1996 (see Section D).
     Assuming a BODu removal efficiency of 71 percent based on the effluent
     loads contributed by different categories of POTWs (USEPA, 1997),
     effluent BODu loading in 2016 would be about 19,606 metric tons per day.
          The projected effluent BODu loading of 19,606 metric tons per day in
     2016 is a concern. Directly and indirectly due to the implementation of the
     CWA, there was a downward trend of effluent BODu loading rates begin-
     ning in the early 1970s through at least 1996 (the endpoint year  of this
     study). The highest effluent BODu loading rate, 21,281 metric tons per day,
     was estimated to have occurred in 1968, four years before the passage of
     the CWA, and the lowest, 16,325 metric  tons per day, in 1996. The 2016
     effluent BODu loading estimate reverses the downward trend, with a 20
percent increase in effluent loading over the 20-year period from 1996 to 2016.
This level of loading  is equivalent to the effluent BODu  loading rates in the mid-
1970s. Further, effluent loading rates projected to 2025  reveal that the Nation may
experience loading rates similar to those occurring in 1968, a time when the
symptoms of water pollution were especially acute.
     These findings underscore the importance of incorporating pollutant loading
estimates and corresponding water quality improvements into POTW needs
surveys. Projected large increases in service population have the potential to
overwhelm the gains made to date in effluent BOD loading reductions due to the
CWA. To continue the downward trend in effluent BOD loading to the Nation's
waterways, further improvements need to be made in technologies and actions
that decrease influent BOD loading to POTWs (through conservation methods)
and increase BOD removal efficiency in the Nation's POTWs (through more
advanced wastewater treatment methods).
     In the 25 years  since the passage of the CWA, a majority of the national
water pollution control efforts have focused on controlling pollutants from
POTWs and other point sources. National standards ensure that every discharger
meets or beats the performance of the best technology available. Continuing the
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                                    Chapter 2: An Examination of BOD Loadings Before and After the CWA
success achieved to date in reducing BOD and other pollutants, however, will
require additional investment as older facilities wear out and increasing population
pressures demand that existing facilities expand and new facilities be constructed.
If these investments are not made and treatment services do not keep pace with
growth, many of the gains achieved by the effluent loading reductions that have
occurred in the years after the CWA will be lost (WIN, 2000). If this occurs, the
wastewater treatment component of the urban water cycle will again  assume
"weak link" status, with corresponding detrimental consequences to water
resource users.
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                             Standards, Washington, DC.
                        USEPA. 1976. 1976 NEEDS survey, conveyance and treatment of municipal
                             wastewater: Summaries  of technical  data. U.S. Environmental Protection
                             Agency,  Office of Water Program Operations, Washington,  DC.
                        USEPA. 1978. 1978 NEEDS survey, conveyance and treatment of municipal
                             wastewater: Summaries  of technical  data. U.S. Environmental Protection
                             Agency,  Office of Water Program Operations, Washington,  DC.
                        USEPA. 1980. 1980 NEEDS survey, conveyance and treatment of municipal
                             wastewater: Summaries  of technical  data. U.S. Environmental Protection
                             Agency,  Office of Water Program Operations, Washington,  DC.
                        USEPA. 1982. 1982 NEEDS survey,  conveyance, treatment, and control of
                             municipal wastewater, combined sewer overflows and stormwater
                             runoff: Summaries of technical data.  U.S. Environmental  Protection
                             Agency,  Office of Water Program Operations, Washington,  DC.
                        USEPA. 1984. 1984 NEEDS survey,  conveyance, treatment, and control of
                             municipal wastewater, combined sewer overflows and stormwater
                             runoff: Summaries of technical data.  U.S. Environmental  Protection
                             Agency,  Office  of Water Program Operations, Washington,  DC.
                        USEPA. 1986. 1986 NEEDS survey,  conveyance, treatment, and control of
                             municipal wastewater, combined sewer overflows and stormwater
                             runoff: Summaries of technical data.  U.S. Environmental  Protection
                             Agency,  Office  of Water Program Operations, Washington,  DC.
2-76

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                                   Chapter 2: An Examination of BOD Loadings Before and After the CWA
USEPA. 1989. 1988 NEEDS survey,  conveyance, treatment, and control of
    municipal wastewater, combined sewer overflows and stormwater
    runoff: Summaries of technical data. U.S. Environmental Protection
    Agency, Office of Water Program Operations, Washington, DC.
USEPA. 1993. 7992 Clean Water Needs Survey (CWNS), conveyance,
    treatment, and control of municipal wastewater, combined sewer over-
    flows and stormwater runoff:  Summaries of technical data. EPA-832-R-
    93-002. Office of Water Program  Operations, U.S. Environmental Protection
    Agency, Washington, DC.
USEPA. 1997. 1996 Clean Water Needs Survey (CWNS), conveyance,
    treatment, and control of municipal wastewater, combined sewer over-
    flows and stormwater runoff:  Summaries of technical data. EPA-832-R-
    97-003. Office of Water Program  Operations, U.S. Environmental Protection
    Agency, Washington, DC.
USPHS. 1951. Water pollution in the United States. A  report on the polluted
    conditions of our waters and what  is needed to restore their quality.
    U.S. Federal Security Agency, Public Health Service, Washington, DC.
Viessman, W., and MJ. Hammer. 1985.  Water supply and pollution control.
    4th ed. Harper & Row, New York, NY.
Vogan, C.R. 1996. Pollution  abatement  and control expenditures, 1972-94.
    Survey of current business. Vol. 76,  No. 9, pp. 48-67. U.S. Dept. of
    Commerce, Bureau of Economic Analysis, Washington, DC.
WEE 1997. The clean water act. 25th Anniversary ed. Water Environment
    Federation, Alexandria, VA.
WIN. 2000. Clean and safe water for the 21st century: A renewed national
    commitment to water and wastewater infrastructure. Water Infrastructure
    Network, Washington, DC.
Zwick, D., and M. Benstock. 1971. Ralph Nader's study group report on water
    pollution: Water wasteland.  Grossman Publishers and Bantam Books, New
    York, NY.
                                                                                          2-77

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
2-78

-------
   Chapter  3
                   An Examination of "Worst-
                   Case" DO  in Waterways
                   Below Point  Sources
                   Before and After the  CWA
     Chapter 2 discussed the evolution of the BOD measurement, the impact
     of BOD loadings on DO levels in natural waters, and the massive
     amount of public and private money invested in municipal wastewater
treatment to meet the mandates of the CWA. Key conclusions from the first leg
of the three-legged stool approach are:
   •   The Nation's investment in building and upgrading POTWs significantly
       reduced BOD effluent loading to the Nation's waterways.
   •   This reduction occurred in spite of a significant increase in influent
       BOD loading caused by an increase in population served by POTWs.
    The second leg follows up on the first leg with another question—Has the
CWA's push to reduce BOD loading resulted in improved water quality in the
Nation's waterways? And, if so, to what extent? The key phrase in the question
is "to what extent?" Earlier studies by Smith et al. (1987a, 1987b) and Knopman
and Smith (1993) conclude that any improvements in DO conditions in the
Nation's waterways are detectable only within relatively local spatial scales
downstream of wastewater discharges.
    "Perhaps the most noteworthy finding from national-level monitor-
    ing is that heavy investment in point-source pollution control has
    produced no statistically discernible pattern of increases in
    water's dissolved oxygen content during the last 15 years [1972-
    87]. . . .  The absence of a statistically discernible pattern of
    increases suggests that the extent of improvement in dissolved
    oxygen is limited to a small percentage of the nation's total stream
    miles. This is notable because  the major focus of pollution control
    expenditures under the act [CWA] has been on more complete
    removal of oxygen-demanding wastes from plant effluents"
                             — Knopman and Smith, 1993
                                                                     3-1

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment


                               The purpose of the second leg of this investigation is to examine evidence
                          that may show that the CWA's municipal wastewater treatment mandates ben-
                          efited water quality on a broad scale, as well as in reaches immediately down-
                          stream from POTW discharges. The systematic, peer-reviewed approach used in
                          this investigation includes the following steps:
                                   Developing before- and after-CWA data sets composed of DO sum-
                                   mary statistics derived from monitoring stations that were screened for
                                   worst-case conditions. The purpose of the screening exercise is to mine
                                   data that inherently contain a response "signal" linking point source
                                   discharges with downstream water quality.
                              •    Calculating a worst-case DO  summary statistic for each station for
                                   each before- and after-CWA time period and then aggregating station
                                   data at sequentially larger spatial scales (reaches, catalog units, and
                                   major river basins).
                              •    Conducting an analysis of spatial units that have before- and after-
                                   CWA worst-case DO summary  statistics and then documenting the
                                   direction (improvement or degradation) and magnitude of the changes
                                   in worst-case DO concentration.
                              •    Assessing how the point source discharge/downstream DO signal
                                   changes over progressively larger spatial scales.
                               Section A of this chapter provides background on the relationship between
                          BOD loading and stream water quality and discusses the two key physical
                          conditions (high temperature and low flow) that create "worst-case" conditions
                          for DO. Section B describes the development and application of a set of screen-
                          ing rules to select, aggregate, and spatially assess before- and after-CWA DO
                          data drawn from USEPA's STORET database. Section C presents the results of
                          the comparison analysis of worst-case DO from before and after the CWA for
                          reach, catalog unit, and major river basin scales. The chapter concludes with
                          Section D, which provides the summary and conclusions for the second leg of
                          this investigation.
                          A.   Background
                               In both terrestrial and aquatic ecosystems, the continuous cycle of produc-
                          tion and decomposition of organic matter is the principal process that determines
                          the balance of organic carbon, nutrients, carbon dioxide, and DO in the biosphere.
                          Plants (autotrophs) use solar energy, carbon dioxide, and inorganic nutrients to
                          produce new organic matter and, in the process, produce DO by photosynthesis.
                          Bacteria and animals (heterotrophs) use the organic matter as an energy source
                          (food) for respiration and decomposition, and in these processes, consume DO,
                          liberate carbon dioxide, and recycle organic matter back into the ecosystem as
                          simpler inorganic nutrients. Water quality problems, such as depleted levels of
                          DO, nutrient enrichment, and eutrophication (overproduction of aquatic plants),
                          occur when the aquatic cycle of production and decomposition of organic matter
                          becomes unbalanced from excessive amounts of anthropogenic inputs of organic
                          carbon and inorganic nutrients from wastewater discharges and land use-influ-
                          enced watershed runoff.
3-2

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  Chapter 3: An Examination of "Worst-Case" DO in Waterways Below Point Sources Before and After the CWA


     DO is the most meaningful and direct signal relating municipal and industrial
discharges to downstream water quality responses over a wide range of temporal
and spatial  scales. In addition to DO's significance as a measure of aquatic
ecosystem health, there are several other practical reasons for choosing DO as
the signal for assessing changes in water quality, including the following:
         Historical records go as far back as the early 20th century for many
         major waterbodies. New York City, for example, began monitoring DO
         in New York Harbor in 1909 and records exist for the Upper Missis-
         sippi River beginning in 1926, the Potomac estuary in 1938, and the
         Willamette River in 1929 (see Wolman, 1971).
     •    Basic testing procedures for measuring DO have introduced few biases
         over the past 90 years, thereby providing the analytical consistency
         needed for comparing historical and modern data (Wolman, 1971).
     This section provides background on sources of DO data, the relationship
between BOD loading, downstream DO levels, and the two key physical condi-
tions (high  temperature and low flow) that create "worst-case" DO conditions.
As will be explained, DO data collected under worst-case conditions inherently
contain the  sharpest signal of the point source discharge/downstream DO rela-
tionship.


Sources of  DO Data

     Key to this analysis is the existence of DO data with which a before- and
after-CWA  comparison can be made. Fortunately, systematic water pollution
surveillance of many of the Nation's waterways began in 1957 in response to the
1956 Amendments to the Federal Water Pollution Control Act. Figure 3-1 is a
map developed by Gunnerson (1966) displaying minimum DO concentrations
throughout  the United States using data collected from 1957  through 1965. It
illustrates both the spatial extent of historical data and the poor DO conditions
found in many of the Nation's waterways in the late 1950s and early 1960s.
     O > 6.5 mg/L
     ® 4.1 to 6.5 mg/L
     O 0.5 to 4.0 mg/L
     • < 0.5 mg/L
                                                                             Figure 3-1
                                                                             Location of sample
                                                                             stations and minimum DO
                                                                             concentrations in the
                                                                             contiguous 48 states from
                                                                             1957 to 1965.
                                                                             Source: Gunnerson, 1966.
                                                                                                3-3

-------
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                                                                                                                                          i

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  Chapter 3: An Examination of "Worst-Case" DO in Waterways Below Point Sources Before and After the CWA


 "Worst-Case" Conditions  as a Screening Tool

     The first step in developing the before- and after-CWA data sets was to
analyze the relationship between point source BOD loading and downstream DO
levels. As the reader will see in Section B, the rules subsequently adopted and
applied to screen out noisy data were based on eliminating physical factors that
interfered with,  or confounded, the point source discharge/downstream DO signal.
As it turned out, the DO data that contained the strongest signal were the data
collected under  conditions that yielded the lowest DO levels (high water tempera-
ture and low flow). The purpose of this subsection is to explain the physical
processes and spatial characteristics that make worst-case conditions the appro-
priate screening tool for developing the before- and after-CWA data  sets.

Worst-Case  Conditions From a Temporal Perspective
     In an unpolluted stream, DO concentrations in most of the water column are
typically at or near saturation. Saturation, however, varies inversely with water
temperature and elevation. At typical winter water temperatures of about 10 °C,
the solubility of oxygen is about 11.3 mg/L at sea level. At a higher summer
temperature of 25 °C, the solubility is only about 8.2 mg/L. This high water
temperature-low solubility relationship makes hot weather an especially critical
period for aquatic organism survival. Higher water temperatures mean a lower
reserve of oxygen is available to buffer against any additional oxygen demands
made by wastewater effluent discharges.
     Wastewater effluent typically has an oxygen deficit (a DO concentration
below saturation). Therefore, its initial entry into a waterway causes an immedi-
ate drop in stream DO near the outfall. The effluent becomes diluted as it mixes
with the stream water and moves down the channel. The BOD of the stream
water thus becomes the discharge-weighted average BOD of the effluent and the
stream above the discharge.  The volume of streamflow (the dilution factor),
therefore, is a critical variable in determining the concentration of oxygen-
demanding waste. Consequently, periods of low flow in the stream channel yield
the highest concentration of BOD.
     The combination of unnaturally high levels of BOD inputs, high water
temperature, and low stream flow creates worst-case DO levels in streams  and,
in turn, the most critical conditions for the survival of aquatic organisms; that is,
conditions of increased oxygen demand, low oxygen solubility, and low dilution
potential. Fortunately, worst-case conditions do not occur all the time. Although
the BOD loading component tends to remain relatively stable over the course of a
year, there are usually distinct seasonal variations in temperature and  rainfall
(directly related to flow). On an annual basis in the contiguous United States, the
highest water temperatures and minimal flow levels usually occur from early
summer to late fall. Therefore, the months of July through September are gener-
ally considered  "worst-case" months for DO.
     Observations of year-to-year variations in climate reveal that many areas on
the earth, including the United States, experience runs of wet and dry years, a
phenomenon known as persistence. The short time frame of historical record-
keeping makes it difficult for scientists to predict exactly when these  wet and dry
year cycles will  occur; however, more than 100 years of rainfall data have proven
that they are not uncommon. Importantly, persistence tends to have a cumulative
                                                                                              3-5

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment


                          effect on stream conditions. Therefore, the worst-case scenario for DO in
                          waterways from a temporal perspective can be further refined to include the
                          months of July through September (worst-case months) during a run of dry years
                          (worst-case persistence).
                               Defining the periods of years before and after the CWA to represent worst-
                          case persistence was accomplished in three steps. In the first step, USGS flow
                          data taken from approximately 5,000 gages with over 20 years of record during
                          the period from 1951 to 1980 were classified into "dry," "normal," and "wet"
                          years. Normalized ratios of summer (July to September) streamflow to long-term
                          summer mean were computed for each gage for each year. Years with ratios less
                          than 0.75 were considered dry; normal years had ratios from 0.75 to 1.5, and wet
                          years were defined as having ratios greater than 1.5.
                               Figure 3-3 illustrates how widely mean summer flow can vary over time.
                          The figure displays USGS gage data from the Upper Mississippi River at St. Paul,
                          Minnesota, for the years  1960 through 1995. The scale on the left Y axis is
                          streamflow measurements as thousands of cubic feet per second (cfs). The scale
                          on the right Y axis is the  interannual-to-long-term mean (10,658 cfs) streamflow
                          ratio. Note that the benchmark ratio of 0.75 (which distinguishes dry from normal
                          years) is represented by the dashed horizontal  line. This graph shows that dry
                          summers with low flow occurred in St. Paul in the years 1961, 1970, 1976, 1980,
                          and 1987-1989. The data from this gage also show the enormous wet conditions
                          that occurred primarily in response to the "Great Flood of 1993." That year the
                          mean summer flow was about 4.5 times greater than the normal mean summer
                          flow.
                               For the second step, a sliding window methodology was used as an algo-
                          rithm to weight and interpolate normalized streamflow ratios for multiple gages
                          within a catalog unit. The outcome was a weighted streamflow ratio assigned to
                          each catalog unit for each year from 1961  through  1995. Similar to the gage-scale
                          streamflow ratio, the catalog unit-scale streamflow ratio was used to classify
                          catalog units into dry (< 0.75), normal (0.75-1.5), and wet (> 1.5) years.
                               The third and final step used to define the periods of worst-case dry persis-
                          tence before and after the CWA involved grouping the 35-year period from 1961
                          to  1995 into consecutive  5-year "time-blocks." Then for each catalog unit, the
                          number of years within each time-block during which the catalog unit scale
                          streamflow ratio was below 0.75 (i.e., dry) was determined. Rather than using the
                          seemingly obvious 5-year time-block of 1966-1970 to characterize water quality
Figure 3-3
Time series of mean
summer (July-September
1960-1995) streamflow
and ratio of mterannual to
long-term (1951-1980)
summer mean.
(Data  from USGS Gage
05331000 on the Upper
Mississippi River near
Minneapolis-St. Paul,
Minnesota)
                                                                                      0.00
                                        1960   1965  1970  1975  1980   1985   1990  1995
3-6

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  Chapter 3: An Examination of "Worst-Case" DO in Waterways Below Point Sources Before and After the CWA
conditions "before" the 1972 CWA, 1961-1965 was selected instead to represent
conditions "before" the CWA while 1986-1990 was used to characterize condi-
tions "after" the CWA.
     Widespread drought conditions, a critical factor for "worst-case" water
quality conditions, occurred in the Northeast, Middle Atlantic, Midwest, and
Central states during both of these "before and after" 5-year time-blocks of
record (i.e., 1961-1966 and 1987-1988). The widespread extent of drought
conditions during the "before and after" time-blocks is shown in Figure 3-4 with
maps of normalized  streamflow ratios computed for each catalog unit for 1963
and 1988.
     For the 5-year  time-block of 1961-1965, selected to represent before-CWA
conditions, 1,923 (91 percent) of the 2,111 catalog units of the 48  contiguous states
were characterized by  at least one year of "dry" streamflow conditions. Similarly
for the 5-year time-block of 1986-1990 "after" the CWA, 1,776 (84 percent) of
the 2,111 catalog units of the 48 contiguous states were characterized by at least
one year  of "dry" streamflow conditions. For the catalog units characterized as
"dry," low flow conditions occurred for a mean period of 2.5 years during 1961-
1965 and 2.7 years during 1986-1990 (Figure 3-5). Hydrologic conditions for the
summers of 1963 and 1988 are shown to illustrate the similarity of the spatial
extent of drought conditions within the 48 contiguous states during the before- and
after-CWA time-blocks. Using this station selection approach based on  summer
streamflow ratios, trends identified for "before versus after" changes in DO can
then be correctly attributed to changes in pollutant loadings (under comparable
"dry" streamflow conditions) rather than to differences in hydrologic conditions.

Worst-Case Conditions from a Spatial Perspective
     In a clean river, upstream of any wastewater inputs, DO levels are typically
near saturation. Downstream of an effluent discharge, however, measurements of
DO lower than saturation exhibit a characteristic  spatial pattern influenced by the
loss of oxygen from  degradation of organic matter and nitrification and the
replenishment of oxygen transferred from the atmosphere into the river (see
Thomann and Mueller, 1987; Chapra, 1997). An understanding of the spatial
pattern of DO in rivers was critical for the design of the screening methodology
used to detect "worst-case" conditions from a spatial perspective. Using river
miles from a downstream confluence as a measure of distance along the river,
Figure 3-6 illustrates spatial patterns of carbon (CBOD), nitrogen (organic-N,
NH3-N, and NO2-N  + NO3-N), and DO in zones  identified as "clean," "degrada-
tion," "active decomposition," and "recovery" that are upstream and downstream
of a POTW discharge.
     In streams and rivers, DO levels are maintained near saturation by the
continuous transfer of atmospheric oxygen into solution in a thin surface layer of
the river.  The rate of transfer of atmospheric oxygen into the river (i.e., mixing of
oxygen as a gas from the air into solution in the water) depends on how fast the
river is running, how deep the water is, how "bubbly" the river appears to be, the
water temperature, and how much oxygen is already in solution in the river. The
less oxygen that is in solution in the river, the faster more oxygen can be trans-
ferred from the air into the water. In the "degradation" zone, more oxygen is
being consumed by decomposition than can be replenished from the atmospheric
supply of oxygen and DO levels quickly drop. In the "active decomposition" zone,
                                                                                                3-7

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
Figure 3-4

Hydrologic conditions during July-September of (a) 1963 and (b) 1988.
Summer streamflow ratio estimated for each
catalog unit as a percentage of long-term mean
summer streamflow (July-September,  1951-1980).
Hydrologic conditions characterized as dry (0%-75%)
normal (75%-150%), and wet (greater than 150%)
                                                                                  Streamflow Ratio
                                                                                     Less than 50
                                                                                     SO-75
                                                                                     75-100
                                                                                     100-150
                                                                                     150-200
                                                                                     Greater than 200
                                                                                     Data Not Availabe
3-8

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  Chapter 3: An Examination of "Worst-Case" DO In Waterways Below Point Sources Before and After the CWA
    Figure 3-5
    "Dry" hydrologic conditions during July- September of (a)  1961-1965 and (b) 1986-1990.
                                                                                   "Dry" Streanticw
                                                                                       O Years "Dry1'
                                                                                   I   I 1-2 Years'Dry"
                                                                                   CD 3-5 Years "Dry"
Summer streamflow ratio estimated for each
catalog unit as a percentage of long-term mean
summer streamflow (July-September, 1951-1980).
Hydrologic conditions characterized  as dry (0%-75%)
normal (75%-150%), and wet (greater than 150%).
                                                                                                         3-9

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
Figure 3-6
Spatial distribution of
(a) organic carbon
(CBOD), (b) nitrogen
(organic nitrogen,
ammonia,  nitrite, and
nitrate), and (c) DO
downstream of a waste-
water discharge into a
river.
Source: Adapted from
Chapra, 1997 and
Thomann and Mueller,
1987.
                                               Wastewater discharge
(a)
               Clean water
            -60
Degra-        Active
dation    decomposition
Recovery
                      -50
    -40       -30        -20       -10
 Distance From Confluence (miles)
                                                   -50        -40        -30        -20        -10

                                                         Distance From Confluence (miles)
                             (b)
                                                   -50        -40        -30        -20        -10

                                                         Distance From Confluence (miles)
                            (C)
                                        10
                                     O)
                                        6-
                                     •a  4
                                     0)
                                     <«   2
                                     5
                                                                           Oxygen saturation (7.8 mg/L)
                                                                             Oxygen standard (5 0 mg/L)
                                                            t
                                                       Critical location
                                          -60       -50       -40       -30       -20       -10

                                                         Distance From Confluence (miles)
3-10

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  Chapter 3: An Examination of "Worst-Case" DO in Waterways Below Point Sources Before and After the CWA
more oxygen is gained by the mixing of oxygen from the air into the water than is
lost by the continued decomposition of a diminishing amount of carbon (CBOD)
and nitrogen (NBOD) and oxygen gradually increases. In the "recovery" zone,
the rate of atmospheric replenishment of oxygen greatly exceeds the oxygen lost
due to  small levels of CBOD and NBOD remaining in the river and oxygen
returns to the saturation level.
     Immediately downstream from the POTW, the carbon concentration
(CBOD) jumps from the low upstream level to a much higher flow-weighted
CBOD concentration as the effluent load is diluted with the ambient upstream
load (Figure 3-6(a)). Bacterial decomposition of the carbon results in a steady
decrease of in-stream CBOD and a steep drop in oxygen in the "degradation"
zone followed by a continued decline of CBOD with a gradual increase in oxygen
in the "active decomposition" zone.
     As shown in Figure 3-6(b) for the spatial patterns of nitrogen, organic
nitrogen (Organic-N) and ammonia nitrogen (NH3-N) both jump from a low
upstream level following mixing of the wastewater load with the ambient up-
stream load. As organic nitrogen declines by hydrolysis, the nitrification process
begins (if a sufficient "seed" population of nitrifying bacteria is present), ammonia
is oxidized to nitrite, and nitrite is quickly oxidized to nitrate. In the figure, nitrite
and nitrate are shown combined as the sum (NO2-N + NO3-N) of these two
inorganic forms of the nitrogen cycle. As the sequential reactions of the nitrogen
cycle proceed downstream, the concentration of total nitrogen (Total-N) remains
unchanged to maintain the mass balance of the reactions between the organic and
inorganic forms of nitrogen. In these sequential oxidation reactions of nitrification,
the nitrogenous oxygen demand (NBOD) consumes oxygen faster than it can be
replenished by atmospheric reaeration and oxygen drops.
     The combined effect of the decomposition of carbon and nitrogen causes a
characteristic critical low DO zone identified by a "sag" in the spatial distribution
of oxygen (Figure 3-6(c)). Two key features of the "oxygen sag" curve are
especially important for the purposes of this study:
     •    The magnitude of the minimum DO concentration.
     •    The distance downstream from a waste discharge affected by "degra-
         dation" and "active decomposition."
     In designing the screening methodology to detect the "worst case" for
oxygen from a spatial perspective, it is important to recognize that water quality
monitoring stations located immediately downstream of wastewater inputs will
most likely be within the  zones of "degradation" or "active decomposition" but not
necessarily at the minimum, or critical, location of the sag. For monitoring stations
located considerably farther downstream from a wastewater discharge location, it
is less likely that the station will be within the "degradation" or "active decomposi-
tion" zones of the river. It is more likely, rather, that the station(s) will be located
in the "recovery" zone. For any stream or river, the actual locations that mark the
beginning and end of these zones are highly variable. The spatial pattern of
oxygen shown in Figure 3-6(c) is dependent on a number of factors, including
streamflow and river velocity (travel time), depth, water temperature, the type
and makeup of effluent discharged, the magnitude of the wastewater discharge
load, and the degree of turbulent mixing. Rather than attempting to select stations
that are located in the exact sag zone, which would undoubtedly show the sharp-
est downstream DO  signal but in the smallest area of the waterbody, the opposite

                                                                                              3-11

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment


                          approach was taken. That is, location of the station relative to the sag zone is
                          purposely not controlled or selected, thereby allowing representation of far larger
                          spatial areas but at the possible sacrifice of the downstream DO signal strength.
                               The question originally posed in Chapter 1 is broad-based: How have the
                          Nation's water quality conditions changed since implementation of the 1972
                          CWA 's mandate for secondary treatment as the minimum acceptable technol-
                          ogy for POTWs? The focus of the analysis is on detecting improvements  in
                          water quality conditions downstream of POTWs in the Nation as a whole, not just
                          areas immediately below outfalls. Consequently,  when the term "worst-case DO
                          data" is used in this document, it should be taken to refer to data collected
                          primarily during times of high water temperature and low flow conditions (i.e.,
                          "worst-case" from a temporal perspective). Spatially, no screens were developed
                          for selecting monitoring stations located at the deepest part of the sag curve, nor
                          even for stations in the sag curve itself. The only screening rule applied was that
                          the water quality station had to be downstream from a point source. Thus, a
                          station might be anywhere from within a few yards to hundreds of miles below
                          any particular outfall. As a result, the data sets developed for the comparative
                          before- and after-CWA analysis contain a mix of DO data from within and
                          outside DO sag curves.


                          The Role  of Spatial  Scale in This Analysis

                               Recall that the objectives for this portion of the study are as follows:
                              •    Develop before-  and after-CWA data sets made up of DO summary
                                   statistics derived from monitoring stations that inherently contain a
                                   response "signal" linking point source discharges with downstream
                                   water quality.
                              •    Calculate a DO summary statistic (10th percentile) for each station for
                                   each before- and after-CWA time period and  then aggregate station
                                   data at sequentially larger spatial scales (reaches, catalog units, and
                                   major river basins).
                              •    Conduct an analysis of all spatial units  having both a before- and an
                                   after-CWA summary  statistic and then  document the direction and
                                   magnitude of the changes in worst-case (summer, mean  1 Oth percen-
                                   tile) DO concentration.
                              •    Assess the change in the point source discharge/downstream DO
                                   signal over progressively larger spatial  scales.
                               The use of spatial scale is a key attribute of this analysis. Detection  of
                          positive change in signal at large (river basin) as  well as small (stream reach)
                          scales would provide evidence that the CWA's technology and water quality-
                          based controls yielded broad as well as localized  benefits (i.e., reaches both within
                          and beyond the immediate sag  curve have benefited from the CWA). If true,
                          therefore, the second leg of the three-legged stool approach would provide further
                          support for the claim that the CWA was a broad success.
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  Chapter 3: An Examination of "Worst-Case" DO in Waterways Below Point Sources Before and After the CWA
B.  Data Mining
     As discussed in the previous section, the key objective in the data mining
process was to screen out data collected under conditions or factors that might
interfere with, or confound, the point source discharge/downstream DO  signal.
This section presents the six-step, peer-reviewed data mining process the study
authors developed and implemented to develop the before- and after-CWA data
sets to be used in the comparison analysis.


Step 1—Data Selection Rules

     The data selection step incorporated three screening rules:
     •    DO, expressed as a concentration (mg/L), will function as the signal
         relating municipal and industrial discharges to downstream water
         quality responses.
     •    DO data will be extracted only from the July-September (summer
         season) time period.
     •    Only surface DO data (DO data collected within 2 meters of the water
         surface) will be used.

DO  Concentration (mg/L) as the Water Quality Indicator
     The rationale for selecting DO as the water quality indicator for this study
was discussed earlier in this chapter and in Chapter 2. The only question remain-
ing was how this parameter should be expressed in the analysis—by concentra-
tion or by percent of DO saturation. The latter measurement has some advan-
tages because it would reduce the noise introduced by changes in temperature.
However, DO expressed as mg/L concentration was ultimately selected because
it is more intuitive to a broader audience. For example, USEPA has established a
DO concentration of 5.0 mg/L as the minimum concentration to be achieved at all
times for early life stages of warm-water biota (see Table 1-1). For this reason,
this level of DO is used as a benchmark for assessing acceptable versus
nonacceptable conditions. In contrast, it is somewhat more difficult to compre-
hend whether a DO saturation of 50, 60, or 70 percent is protective.

DO  From the Time Period  of July to September
     Summer and early fall (July through September) is usually the best time for
evaluating worst-case impacts of wastewater loading on water quality in general
and DO in particular. Typically, this is when water temperatures are highest and
flow is the lowest (i.e., lowest oxygen solubility and lowest dilution potential).
Selecting DO data from only this time period screens out noise introduced by
seasonal variations in temperature, precipitation, and flow. In addition, BOD
loadings from nonpoint sources of pollution are reduced during low precipitation
periods thus minimizing this contribution to DO signals.

DO from  Surface  Waters
     In lakes, reservoirs, estuaries, coastal waters, and deep rivers, scientists
typically measure DO at several depths in the water column.  Often these mea-
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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment


                         surements reveal significant differences between surface and bottom DO con-
                         centrations because of thermal stratification and the lack of reaeration of the
                         bottom layer. By limiting DO data selection to the top 2 meters of a waterway,
                         one can screen out much of the noise associated with the physical, chemical, and
                         biological processes that occur in the lower layers and maintain some level of
                         comparability between shallow streams and deeper waters.


                         Step 2—Data  Aggregation  Rules  From  a  Temporal
                         Perspective

                              The data aggregation from a temporal perspective step incorporated the
                         following rules:
                                  1961-1965 will serve as the time-block to represent persistent dry
                                  weather before the CWA and 1986-1990 will serve as the time-block to
                                  represent persistent dry weather after the CWA.
                             •    To remain eligible for the  before- and after-CWA comparison, DO data
                                  must come from a station residing in a catalog unit that had at least 1
                                  year classified as dry (streamflow ratio < 0.75) out of the 5 years in
                                  each before- and after CWA time-block.
                              An analysis of catalog units revealed that 1,923 (91 percent) of the 2,111
                         catalog units in the contiguous United States experienced at least one dry summer
                         in the 1961-1965 time-block. Further, a total of 1,475 catalog units (70 percent)
                         experienced at least two dry summers and 886 catalog units (42 percent) experi-
                         enced at least three dry summers in the before-CWA time-block. Of the  catalog
                         units that remained eligible for the comparison analysis (note that only 188 were
                         screened out), low flow conditions remained for an average of 2.5 years. In the
                         1986-1990 time-block, 1,776 (84 percent) of the 2,111 catalog units in the contigu-
                         ous United States experienced at least one dry summer. A total of 1,420 catalog
                         units (64 percent) experienced at least two dry summers and 1,073 catalog units
                         (51 percent) experienced at least three dry summers in the after-CWA time-
                         block. Of the catalog units that remained eligible for the comparison analysis (335
                         were screened out), low flow conditions remained for an average of 2.7 years.

                         Step 3—Calculation  of  the Worst-Case  DO
                         Summary Statistic  Rules

                              The calculation of the worst-case DO summary statistic step incorporated
                         the following rules:
                             •    For each water  quality station, the 1 Oth percentile of the DO data
                                  distribution from the before-CWA time-block (July through September,
                                  1961-1965) and the 10th percentile of the DO data distribution from the
                                  after-CWA time-block (July through September, 1986-1990) will be
                                  used as the DO worst-case statistic for the comparison analysis.
                             •    To remain eligible for the  before- and after-CWA comparison, a station
                                  must have a minimum of eight DO measurements within each of the 5-
                                  year time-blocks.
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  Chapter 3: An Examination of "Worst-Case" DO in Waterways Below Point Sources Before and After the CWA
     Typically, the mean or median statistic is used to summarize a distribution of
data because it describes the central tendency of the distribution. In this study,
however, the emphasis is on worst-case (low) DO. Consequently, a summary
statistic describing the lowest DO measurements of the data distribution was
needed because these data would inherently carry a sharper point source dis-
charge/downstream water quality signal. In other words, the objective was to
characterize the worst of the DO data collected under the worst-case physical
conditions (high temperature and low flow).
     Because simply choosing the minimum measurement might introduce
anomalous results, the 10th percentile, a more robust statistic (i.e., one that
conveys information under a variety of conditions and is not overly influenced by
data values at the extremes of the data distribution) was selected as the appropri-
ate summary statistic to characterize the worst DO of a station's range of DO
measurements within a time-block. An example of how one might interpret a 10th
percentile value for a station is to say that 90 percent of the values collected at
that station were higher than the  10th percentile value. To minimize statistical
errors associated with calculating extreme percentiles, the requirement was added
that a station must have a minimum of eight observations within the 5-year time-
block to remain eligible for the before- and  after-CWA comparison.


Step 4—Spatial Assessment  Rules

     The spatial assessment step incorporated one screening rule:
     •    Only water quality stations on portions of streams and rivers affected
         by point sources will be included  in the before- and after-CWA com-
         parison analysis.
     The objective was to develop before-  and after-CWA data sets that contain
data that inherently contain a response signal linking point source discharges with
downstream water quality.  Consequently,  a screening rule reflecting the need to
ensure that DO data came  from  stations located downstream, rather than up-
stream, from point sources was required.  As noted in Section A of this chapter,
the distance downstream was not relevant for the screening rule; the only require-
ment was that the station was somewhere in the downstream network.
     Although the focus of this study is on effluent loading from POTWs,
changes in DO are tied to industrial discharges as well. Estimates of current (ca.
1995) BOD5 loading using the NWPCAM indicate that industrial loads are the
dominant component of total point and nonpoint source loading in many catalog
units associated with major urban-industrial areas (see Section E in Chapter 2).
For this reason, and because of the fact that it is not always possible to satisfacto-
rily distinguish between industrial and POTW outfalls because of their close
proximity in many areas, this leg of the study defines "point source discharges" to
include both industrial and municipal dischargers.
     The upstream/downstream  relationship between point source discharges and
water quality monitoring stations was established using USEPA's Reach File,
version 1 (RF1). RF1 is a computerized network of 64,902 river reaches in the 48
contiguous states,  covering 632,552 miles of streams (see Figure  1-2). Using this
system, one can traverse stream networks and establish relative positions along
the river basin network of both free-flowing  and tidally-influenced rivers.
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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
Figure 3-7
Reach File version 1 stream reach network of the 48 contiguous states with point source inputs discharging to a reach.
                               A list of point source dischargers was developed from EPA's Permit Com-
                          pliance System (PCS), Clean Water Needs Survey (CWNS), and Industrial
                          Facilities Discharge File (IFD). Spatially integrating the dischargers with RF1
                          resulted in identifying 12,476 reaches that are downstream of point source
                          dischargers (Figure 3-7) (Bondelid et al., 1999). These reaches, in turn, reside in
                          1,666 out of a total of 2,111 catalog units in the contiguous United States.

                          Example Application of the Screening Rules on DO Data From
                          a Single Water Quality Monitoring Station
                               Figure 3-8 illustrates how the above screening rules were applied to monitor-
                          ing station data to obtain worst-case DO data for the before- and after-CWA
                          comparison analysis. A station located on the Upper Mississippi River at Lock
                          and Dam No. 2 at Hastings, Minnesota, is used in this example. Figure 3-8(a)
                          displays a time series of the entire historical record (225 observations) of raw
                          ambient DO  measurements for the station from 1957 to 1997. Note that DO
                          concentrations fluctuate from close to zero to slightly over 15 mg/L. The apparent
                          noise (rapid up and down movement of the DO line) is due to many factors,
                          including seasonal streamflow-water temperature and the time scale of the
                          graphic. Long-term interannual changes, on the other hand, might be due to
                          persistent dry or wet weather or changes in pollutant loading from the St. Paul
                          METRO wastewater facility.
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 Chapter 3: An Examination of "Worst-Case" DO in Waterways Below Point Sources Before and After the CWA
(a)
                                     Figure 3-8
                                     Application of the screen-
                                     ing rules for station 21
                                     MINN MSU-815-BB15E58
                                     located in the Upper
                                     Mississippi River: (a) time
                                     series of historical DO
                                     observations from 1957-
                                     1997, (b) before- and after-
                                     CWA frequency
                                     distribution, and (c) 10th
                                     percentile values.
                                     Source:  USEPASTORET
          1950  1955  1960  1965  1970  1975  1980  1985  1990  1995  2000
                            STORET7TYPA/AMBNT7STREAM
(b)
                            Before (1961-1985)

                            After (1986-1990)
             0%   10%   20%   30%   40%   50%   60%   70%   80%   90%  100%
                                        Percentile
(c)
         Before
          After
4.2
                              Mean 10%ile Dissolved Oxygen (mg/L)
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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment


                               In the data selection step, the study authors extracted from the raw data set
                          surface measurements collected at the station during the summer season (52
                          observations). Then, in the data aggregation step, they grouped the data in 5-year
                          time-blocks and focused in on the data from the before- and after-CWA persis-
                          tent dry weather time-blocks of 1961-1965 (10 observations) and 1986-1990 (15
                          observations). Because (1) the catalog unit in which the station resides had at
                          least one dry year in each of the before- and after-CWA time-blocks (streamflow
                          ratios: 1961 [0.31]; 1964 [0.65]; 1987 [0.59]; 1988 [0.22]; and 1989 [0.40]) and
                          (2) the number of observations for each grouping was confirmed to be greater
                          than eight, the groupings remained eligible for the next phase.
                               Distributions were made for each group and the 10th percentile determined.
                          Figure 3-8(b) displays the before- and after-CWA DO frequency distribution.
                          Figure 3-8(c) is a bar chart comparing the 10th percentile DO values of the
                          before- and after-CWA time-blocks. Note that the 10th percentile statistic
                          associated with the before-CWA period is below the USEPA's minimum concen-
                          tration of 5 mg/L, the level the Agency requires to be achieved at all times for
                          early life stages of warm-water biota.
                               Finally, the spatial assessment phase confirmed that the monitoring station
                          where the DO data were collected was on the Upper  Mississippi River down-
                          stream of the St.  Paul METRO water pollution control plant. Therefore, the
                          station remained eligible for the comparison analysis.


                          Step  5—Data  Aggregation Rules From a Spatial
                          Perspective

                               The data mining steps described above were used to develop before- and
                          after-CWA sets of monitoring station data. Recall that
                               •    The before- and after-CWA data sets are collections of DO summary
                                   statistics  that characterize worst-case DO at individual water quality
                                   monitoring stations across  the United States for the 1961-1965 and
                                   1986-1990 time-blocks, respectively (one DO summary statistic per
                                   station per time-block).
                               •    The summary  statistic used to characterize worst-case DO at a station
                                   is the 10th percentile value of a data distribution of actual DO measure-
                                   ments taken at the station during the specified time-block and recorded
                                   in STORET. For the station to be eligible for inclusion in the data set,  at
                                   least eight measurements had to have been taken during the 5-year
                                   time-block.
                               The purpose of the data aggregation from a spatial perspective step was to
                          assign a worst-case DO summary statistic to every eligible spatial unit defined at
                          the reach and hydrologic unit scales  for the before- and after-CWA time-blocks.
                          This task was accomplished in two steps. First, for each data set and time-block,
                          the mean 10th percentile value from  each eligible station was computed within the
                          spatial unit. (Since the scales are hierarchical, a station's summary statistic was
                          effectively assigned to a reach and a catalog  unit.) Second, the mean 10th
                          percentile summary statistic was calculated and assigned to the spatial unit for the
                          purpose of characterizing its worst-case DO.  If a spatial unit had only one
                          monitoring station within its borders  meeting the screening criteria, the 10th


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  Chapter 3: An Examination of "Worst-Case" DO in Waterways Below Point Sources Before and After the CWA


percentile DO value from that station simply served as the unit's worst-case
summary statistic. If, however, there were two or more stations within a spatial
unit's borders, the 10th percentile values for all the eligible stations were aver-
aged, and this mean value used to characterize worst-case DO for the unit. This
averaging process reduced the correlation between stations that were located
near each other. (Increased correlation reduces the effective sample size and
complicates statistical comparisons. Averaging across larger spatial scales tends
to reduce the correlation the most. As demonstrated later in this section, the
results from the different spatial scales are generally consistent and the impact of
spatial correlation is believed to be minimal.)


Step  6—Development of the Paired Data Sets (at
each  spatial scale)

     The purpose of the sixth and final step was to prepare the before- and after-
CWA data sets for the comparison analysis to be conducted at each of the three
sequentially larger hydrologic scales (RF1 reach, catalog unit, and major river
basin). The screening rule associated with this step was as follows
     •    To be eligible for the paired (i.e., before vs. after) comparison analysis,
         a hydrologic unit must have both a before-CWA and an after-CWA
         summary statistic assigned to it.
     After  each eligible reach and catalog unit was assigned a worst-case DO
summary statistic for the appropriate before- and after-CWA time-blocks, a
check was made to see which spatial units had both a before- and an after-CWA
summary statistic. For many reaches and catalog units, factors such as the
absence of dry flow conditions, station removal or changes in station location, or
water quality  sampling over time (see Figure 3-2) caused a summary statistic to
be available for one time-block but not the other. In this case, the spatial unit was
removed from the analysis.
     Implementation of this final step of the data mining process yielded the
following results:
     •    Of the 12,476 reaches identified as being downstream from point
         sources, 311 reaches had  both  before- and after-CWA worst-case  DO
         summary statistics.
     •    Of the 1,666 catalog units  identified as being impacted by point sources,
         246 units had both before- and after-CWA worst-case DO summary
         statistics.
     •    The 311 reach-aggregated DO summary statistics were pooled by the
         18 major river basins in the contiguous United States. Using the statisti-
         cal requirements to conduct a paired Mest as a criterion,  11 of the 18
         major river basins had sufficient reach-aggregated worst-case DO data
         to conduct the comparison analysis at the river basin level.
     •    The number of reaches  and catalog units with both before- and after-
         CWA DO data was constrained by the limited availability of station
         records for the 1961-1965 before-CWA period  (see Figure 3-2).
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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment


                       C.    Comparison of Worst-Case DO in

                              Waterways Below  Point Source

                              Discharges  Before and  After the

                              CWA at Three Spatial Scales

                           This section presents the  comparative before- and after-CWA analysis of
                       worst-case DO data derived using the screening criteria described in Section B
                       and then aggregated by spatial  units defined by three scales (reach, catalog unit,
                       and major river basin). In the discussion that follows, the term "worst-case DO"
                       should be interpreted to mean the average 10th percentile DO statistic computed
                       for the corresponding spatial level unless specifically noted otherwise. Also, the
                       reader should note that a worst-case DO concentration of 5 mg/L has been
                       adopted in this report as a general benchmark threshold for defining "desirable"
                       versus "undesirable" levels of worst-case DO. This benchmark value was chosen
                       primarily because USEPA has established it as the minimum concentration to be
                       achieved at all times for early life stages of warmwater biota (see Table 1-1).


                       Reach Scale

                           A total of 311 river reaches had monitoring stations with both before- and
                       after-CWA data and thus were eligible for comparison. Notably, these 311
                       evaluated reaches represent a disproportionately high amount of urban/industrial
                       population centers, with approximately 13.7 million people represented (7.2
                       percent of the total population served by POTWs in 1996). Of this total, 215
                       reaches (69 percent) showed improvements in worst-case DO after the CWA.
                       Figure 3-9 presents a frequency distribution of the before- and after-CWA data.
Figure 3-9
Frequency distribution
comparing worst-case DO
concentration of evaluated
reaches before and after
the CWA.
Source: USEPA STORET
                            30
I
£
CO
0
                         0)
25 -
    20
(n) = number of RF1 reaches
• 1961-1965 (Before CWA)
W\ 1986-1990 (After CWA)
                         «  15
                         n
                         Q.
                         x—
                         O
                         0)
                         O)
                         (B
                         +j
                         V
                         £
                         0)
                         Q.
                                                               <	Desirable levels
               Undesirable levels	>
                                                 Worst-Case DO (mg/L)
3-20

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  Chapter 3: An Examination of "Worst-Case" DO in Waterways Below Point Sources Before and After the CWA


     Key observations from Figure 3-9 include the following:
         The percentage of evaluated RF1 reaches characterized by "very low"
         worst-case DO (< 2 mg/L) was reduced from 15 to 4 percent. Before
         the CWA, 48 reaches had very low worst-case DO. After the CWA,
         only 13 reaches had very low worst-case DO.
     •    The percentage of evaluated reaches characterized by undesirable
         worst-case DO (below the 5 mg/L threshold) was reduced from 54 to
         31 percent. Before the CWA, 167 reaches had undesirable levels of
         worst-case DO. After the CWA, 97 reaches had undesirable levels of
         worst-case DO.
     •    The percentage of evaluated reaches characterized by desirable worst-
         case DO (above the 5 mg/L threshold) increased from 46 to 69 per-
         cent. Before  the CWA, 144 reaches had desirable levels of worst-case
         DO. After the CWA, 214 reaches had desirable levels of worst-case
         DO.
     By tracking individual reaches, it was revealed that 85 of the 167 reaches
characterized by undesirable worst-case DO before the CWA improved  to
greater than 5 mg/L after the act. On the flip side, only 15 of the 144 reaches
characterized by desirable worst-case DO before the CWA dropped below the 5
mg/L benchmark after the act. Thus, the net change was 70 reaches moving from
undesirable levels of worst-case DO to desirable levels of worst-case DO.
     Figure 3-10 is a column graph that breaks down the 85 reaches that had
undesirable DO levels  before the CWA and then improved past the benchmark
threshold of 5 mg/L after the act according to their before-CWA worst-case  DO
concentration.
                  (n) = number of RF1 reaches
                 0 to 1       1 to 2      2 to 3      3 to 4      4 to 5
                    Worst-Case DO Before the CWA (mg/L)
Figure 3-10
Frequency distribution of
worst-case DO levels
before the CWA for the 85
evaluated reaches that
were < 5 mg/L before the
CWA and > 5 mg/L after
the CWA.
Source: USEPA STORET
                                                                                             3-21

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment


                              Key observations from Figure 3-10 include the following:
                              •    Approximately 48 percent of the evaluated reaches (41 out of 85) that
                                  had undesirable worst-case DO levels before the CWA and then
                                  improved past the benchmark threshold of 5 mg/L after the act had
                                  before-CWA worst-case DO in the 4-5 mg/L range.
                                  Approximately 16 percent of the evaluated reaches (14 out of 85) that
                                  had undesirable worst-case DO levels before the CWA and then
                                  improved past the benchmark threshold of 5 mg/L after the act had
                                  very low worst-case DO (< 2 mg/L) before the CWA.
                              Of the 311 evaluated reaches with paired before- and after-CWA data, 215
                          reaches (69  percent) had increased  worst-case DO and 96 (31 percent) had
                          decreased worst-case DO after the CWA. Parts (a) and (b) of Figure 3-11
                          display the magnitude of degradation and improvement, respectively. Key obser-
                          vations from Figure 3-11 include the following:
                              •    Approximately 36 percent of the evaluated reaches that had increases
                                  in worst-case DO (78 of the 215 improving reaches) increased by 2
                                  mg/L or more.
                              •    Approximately 15 percent of the evaluated reaches that had decreases
                                  in worst-case DO (14 of 96 degrading reaches) decreased by 2  mg/L
                                  or more.
                              •    Approximately 41 percent of all evaluated reaches either stayed the
                                  same or improved or degraded by 1 mg/L or less (129 of the 311
                                  reaches).

Figure 3-11
Frequency distribution of worst-case DO for  evaluated RF1 reaches that (a) decreased in concentration (n = 96)
and (b)  increased in concentration (n = 215)  after the CWA. Source: USEPA STORET
 (A
 0)
£
 U
 re
 0)
ft
•a
"5
 0>
 0)
 o
 0)
 0.
   (n) = number of RF1 reaches
7to8 6to7 5to6  4to5  3to4  2to3 1to2 Oto1
                             (a)
                  Magnitude of Decrease in
                Worst-Case DO after the CWA
Oto1  1to2 2to3  3to4  4to5 5to6 6to7  7to8
                 (b)
       Magnitude of Increase in
    Worst-Case DO after the CWA
3-22

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  Chapter 3:  An Examination of "Worst-Case" DO in Waterways Below Point Sources Before and After the CWA
Reaches with Greatest Improvements
     Table 3-1 lists the 25 river reaches with the greatest before- and after-CWA
improvements in worst-case DO. Figure 3-12 presents a location map of these
reaches along with a stacked column graph that shows their before- and after-
CWA worst-case DO data. Key observations from Table 3-1 and Figure 3-12
include the following:
         All but one of the top 25 river reaches with the greatest before- and
         after-CWA improvements had before-CWA worst-case DO levels
         below the benchmark threshold of 5 mg/L. Five reaches had a before-
         CWA worst-case DO concentration of 0 mg/L.
         For 20 of the 24 reaches with before-CWA worst-case DO levels
         below the threshold value of 5 mg/L, after-CWA worst-case DO
         improved to levels greater than 5 mg/L.
     •    The four reaches that did not break the threshold value of 5 mg/L
         after the CWA all had a before-CWA worst-case DO concentration
         of 0 mg/L.
     •    Worst-case DO in the top 10 improving river reaches typically im-
         proved by about 4 to 7 mg/L (from about 0-3 mg/L in the 1961-1965
         time-block to about 6-8 mg/L in the 1986-1990 time-block).
Table 3-1 . Twenty-five RF1 river reaches with greatest improvements in worst-case (mean 1 0th percen-
tile) DO after the CWA. Source: USEPA STORET
Worst- Worst- No. of


Rank
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25


Reach ID
10170203037
04100002001
04110002001
05030103007
07070002034
05120201004
05080002008
07120004018
07090001004
05020006031
04040002005
02040201011
04030101012
03170006007
06010102004
08030203006
04040003001
04030104002
08030205018
05050008006
04120102002
03050109053
07120004002
05120201013
03050103037

River Reach
Name
Big Sioux R.
River Raisin
Cuyahoga R.
Mahoning R.
Wisconsin R.
White R.
Great Miami R.
Du Page R., E Br.
Rock R.
Casselman R.
Root R.
Neshaminy R.
Manitowoc R.
Pascagoula R.
Holston R, S Fk.
Enid L.
Milwaukee R.
Oconto R.
Grenada L.
Kanawha R.
Cattaraugus Cr.
Reedy R.
Des Plains R.
White R.
Catawba R.

Catalog Unit
Name
Lower Big Sioux, IA
Raisin, MI-OH
Cuyahoga, OH
Mahoning, OH-PA
Lake Dubay, Wl
Upper White, IN
Lower Great Miami, IN
Des Plaines, IL
Upper Rock, IL
Youghiogheny, MD
Pike-Root, IL
Crosswicks-Neshammy
Manitowoc-Sheboygan, Wl
Pascagoula, MS
South Fork Holston,
Yocona, MS
Milwaukee, Wl
Oconto, Wl
Yalobusha, Ml
Lower Kanawha, WV
Cattaraugus, NY
Saluda, SC
Des Plaines, IL
Upper White, IA
Lower Catawba, NC
case DO
1961-1965
(mg/L)
0.0000
1 .6000
0.2950
1 .0900
0.8800
0.6900
0.2000
0.5750
2.7600
2.9600
0.9400
2.6000
5.9500
0.0000
1.6000
0.0000
2.1800
0.5000
0.0000
0.0000
3.3000
1 .9500
1.7620
2.2267
1 .6780
case DO
1986-1990
(mg/L)
7.2200
8.3400
6.4967
7.1600
6.8400
6.4240
5.8600
5.9200
8.0500
8.0000
5.9400
7.5600
10.9000
4.9200
6.4800
4.8673
6.9567
5.2000
4.6160
4.5667
7.6000
6.2270
6.0000
6.3750
5.8000
DO
Change
(mg/L)
7.2200
6.7400
6.2017
6.0700
5.9600
5.7340
5.6600
5.3450
52900
5.0400
5.0000
4.9600
4.9500
4.9200
4.8800
4.8673
4.7767
4.7000
4.6160
4.5667
4.3000
4.2770
4.2380
4.1483
4.1220
Stations
1961-
1965
1
2
2
1
1
5
1
4
1
1
1
1
1
1
1
1
2
1
1
2
1
4
2
3
5
1986-
1990
1
2
24
1
1
1
1
3
1
1
1
1
1
7
2
3
3
1
4
3
2
10
1
2
1
                                                                                           3-23

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GO
 i
ro
Figure 3-12
Location map and distribution chart of the 25 RF1  reaches with the greatest after-CWA improvements in worst-case DO. Source: USEPA STORET
     12.5-r
     10.0-
         I
         o
         Q
  O
  %
  o
      7.5---
      5.0-
      0.0

n

n

n
n
n
_




n



\


„
_

n

n
_
n
After the CWA

n

n

-i_n
            \
          12345678 910111213141516171819202122232425

                  RF1 Reach Ranking (largest to smallest)
                                                                                                                      Catawba River  \
                                                                                                                                                O
                                                                                                                                                I
                                                                                                                                                •f

                                                                                                                                                3
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                                                                                                                                                       1

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  Chapter 3: An Examination of "Worst-Case" DO in Waterways Below Point Sources Before and After the CWA


Catalog Unit Scale

     Figures 3-13 and 3-14 are maps that display the locations and worst-case
DO concentrations of catalog units potentially eligible for the paired analysis for
the 1961-1965 and 1986-1990 time-blocks, respectively. The before-CWA data
set contained a total of 333 catalog units. The after-CWA data set had 905
catalog units.
     In the before-CWA map (Figure 3-13),
     •    45 of the 333 catalog units (14 percent) have worst-case DO less than
         2.5 mg/L.
     •    102 of the catalog units (31 percent) have levels from 2.5 to 5 mg/L.
     •    186 of the catalog units (56 percent) are characterized by worst-case
         DO greater than 5 mg/L.
     In comparing these results with the historical data from the FWPCA
surveillance network (see Figure 3-2 in Section A of this chapter), many of the
catalog units characterized by poor DO conditions (DO less than 5 mg/L)  in 1961-
1965 correspond to the areas represented by many of the  stations compiled by
Gunnerson (1966) with minimum DO less than 0.5 and minimum DO between 0.5
and 4 mg/L in the 1957-1965 data set (see Figure 3-1).
     In the after-CWA map (Figure 3-14),
     •    49 of the 905 catalog units (5 percent) have worst-case DO less than
         2.5 mg/L.
     •    252 of the catalog units (28 percent) have levels from 2.5 to 5 mg/L.
     •    604 of the catalog units (67 percent) are characterized by worst-case
         DO greater than 5 mg/L.
     Undesirable levels of worst-case DO (less than 5 mg/L) are still quite
prevalent after the  CWA in some midwestern and southeastern watersheds, with
a pattern of moderately low worst-case DO (2.5 to 5 mg/L) that appears to be
characteristic of the Atlantic coastal plain from Florida to New Jersey. Higher
worst-case DO (5 to 7.5 mg/L) characterizes the Piedmont region and the
watersheds of the Appalachian Mountains and is likely due to cooler water
temperatures. The coastal plain pattern of moderately low worst-case DO most
likely reflects natural factors such as wanner summer temperatures, higher
decomposition rates, and relatively long residence times within sluggish rivers and
tidal waters rather than municipal or industrial point source loading within these
watersheds.
     Overlaying the 333 eligible catalog units in the before-CWA data set with
the 905 eligible units in the after-CWA data set yielded a total of 246 intersecting
catalog units that had both before- and after-CWA data. Notably, these 246
evaluated catalog units represent a disproportionately high amount of urban/
industrial population centers, with approximately 61.6 million people represented
(32.5 percent of the total population served by POTWs  in 1996). Figure 3-15
presents maps that display the locations and worst-case DO concentrations of the
evaluated catalog units. Figure 3-15(a) displays the catalog units that had im-
provement in worst-case DO after the CWA.  Figure 3-15(b) displays the catalog
units that had degradation in worst-case DO after the CWA. Figure 3-16 presents
a frequency  distribution of the  before- and after-CWA data.
                                                                                                3-25

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
                                                                               Dissolved Oxygen (irgfL)
                                                                               • 0-2.5
Figure 3-13
Locations and worst-case
DO concentrations of
catalog units potentially
eligible for the paired
analysis for the 1961-1965
time-block (before-CWA).
N = 333 catalog units.
Source: USEPA STORET
                                                                                OsstAed Oxygen (n&L)
                                                                                • 0- 2.5
Figure 3-14
Locations and worst-case
DO concentrations of
catalog units potentially
eligible for the paired
analysis for the 1986-1990
time-block (after-CWA).
N = 905 catalog units.
Source: USEPA STORET
3-26

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  Chapter 3: An Examination of "Worst-Case" DO in Waterways Below Point Sources Before and After the CWA
Figure 3-15
Locations and change in worst-case DO concentrations of evaluated catalog units where (a) shows improving units
(N = 167) and (b) shows degrading units (N = 79) before (1961-1965) versus after (1986-1990) the CWA.
Source: USEPA STORET
(a)
(b)
                                                                                                 3-27

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
Figure 3-16
Frequency distribution
comparing worst-case DO
concentration of evaluated
catalog units before and
after the CWA. N = 246
catalog units.
Source: USEPA STORET
                                30 -
25 -
20 -
O>
15
13
O
•a
0)
'I  15
a.
                            O)
                            I
                            
                            Q_
                                10 -
(n) = number of catalog units
• 1961-1965 (Before CWA)
E 1986-1990 (After CWA)
                                     0 to 1   1 to 2   2 to 3   3 to 4   4 to 5 I  5 to 6   6 to 7   7 to 8    > 8
                                    <-	 Undesirable levels	>|<	 Desirable levels	>
                                                        Worst-Case DO (mg/L)
                               Key observations from Figures 3-15 and 3-16 include the following.
                               •     167 (68 percent) of the 246 evaluated catalog units had increases in
                                    worst-case DO after the CWA; 79 (32 percent) of the catalog units
                                    had decreases in worst-case DO after the CWA.
                               •     The percentage of evaluated catalog units characterized by "very low"
                                    worst-case DO (< 2 mg/L) was reduced from 11 to 2 percent. Before
                                    the CWA, 26 catalog units had very low worst-case DO; after the
                                    CWA, only 6 catalog units had very low worst-case DO.
                               •     The percentage of evaluated catalog units characterized by undesirable
                                    worst-case DO (below the 5 mg/L threshold) was reduced from 47 to
                                    26 percent. Before the CWA, 115 catalog units had undesirable levels
                                    of worst-case DO; after the CWA, 65 catalog units had  undesirable
                                    levels of worst-case DO.
                               •     The percentage of evaluated catalog units characterized by desirable
                                    worst-case DO (above the 5 mg/L threshold) increased  from 53 to 74
                                    percent.  Before the CWA, 131 catalog units had desirable levels of
                                    worst-case DO; after the CWA, 181 catalog units had desirable levels
                                    of worst-case DO.
                               Figure 3-17 is a column graph that describes the changes in worst-case DO
                           that occurred after the CWA for the 246 evaluated catalog units in relation to the
                           5 mg/L threshold. Key observations from this figure include the following:
                               •     67 percent of the evaluated catalog units (166 out of 246 units) re-
                                    mained either above (47 percent) or below (20 percent) the 5 mg/L
                                    worst-case DO threshold.
3-28

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 Chapter 3: An Examination of "Worst-Case" DO in Waterways Below Point Sources Before and After the CWA
    O)
    o
    re
    4-1
    re
    O
    re
    Q.
    14-
    O
    0)
    O)
    re
    4-1
    U
    £
    0)
    a.
                                           (n) = number of catalog units
             Remained < 5   Remained >5     <5to>5       >5to<5
                 Change in Worst-Case DO After the CWA (mg/L)
Figure 3-17
Frequency  distribution of
changes in worst-case DO
levels after the CWA using
5 mg/L as the threshold
value. N = 246 catalog
units.
Source: USEPA STORET
         Of the 115 catalog units that had worst-case DO concentrations below
         the threshold of 5 mg/L before the CWA, 57 percent (65 catalog units)
         increased to above the threshold after the CWA.
    •    Of the 131 catalog units that had worst-case DO concentrations above
         the benchmark threshold of 5 mg/L before the CWA, only 11 percent
         (15 catalog units) fell below the threshold after the CWA.
     Of the 246 evaluated catalog units with paired before-  and after-CWA data,
167 catalog units (68 percent) had increased worst-case DO and 79  (32 percent)
had decreased worst-case DO after the CWA. Sections (a) and (b) of Figure 3-
18 display the magnitude of degradation and improvement, respectively. Key
observations from Figure 3-18 include the following:
    •    Approximately 32 percent of the evaluated catalog units that had
         increases in worst-case DO (53 of the 167 improving catalog units)
         increased by 2 mg/L or more.
    •    Approximately 13 percent of the evaluated catalog units that had
         decreases in worst-case DO (10 of 76 degrading catalog units) de-
         creased by 2 mg/L or more.
    •    Approximately 44 percent of all evaluated catalog  units either stayed
         the same or improved or degraded by 1 mg/L or less (108  of the 246
         catalog units).
                                                                                              3-29

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
Figure 3-18
Frequency distribution of change in worst-case DO for evaluated catalog units that (a) decreased in concentration
(n = 79) and (b) increased in concentration (n = 167) before and after the CWA.  Source: USEPA STORET
  +-   30-
  O)
  o
  re
  +j
  re
  O
25-
20-
  75   15-
   0)
   O)
   re
   *->
   0)
   H
   0)
   a.
       10-
 5-
             (n) = number of catalog units
     (0)   (0)   (0)   (1)   (1)
           7to8  6to7 5to6 4to5 3to4  2to3  1to2  Oto1
                               (a)
                    Magnitude of Decrease in
                  Worst-Case DO After the CWA
                                                  Oto1 1to2  2to3  3to4  4to5  5to6 6to7 7to8
                                                                    (b)
                                                         Magnitude of Increase in
                                                       Worst-Case DO After the CWA
                          Catalog Units with Greatest Improvements
                               Table 3-2 lists the 25 catalog units with the greatest before- and after-CWA
                          improvements in worst-case DO. Figure 3-19 presents a location map of the top
                          10 of these units along with a stacked column graph that shows their before- and
                          after-CWA worst-case DO concentration. Key observations from Table 3-2 and
                          Figure 3-19 include the following:
                                  All of the top 25 catalog units with the greatest before- and after-CWA
                                  improvements had before-CWA worst case DO levels below the
                                  benchmark threshold of 5 mg/L. Four catalog units had a before-CWA
                                  worst-case DO concentration of 0.0 mg/L.
                                  For 20 of the 25 catalog units, after-CWA worst-case DO improved to
                                  levels greater than 5 mg/L.
                              •   The five catalog units that did not break the threshold value of 5 mg/L
                                  after the CWA all had concentrations of 0.6 mg/L or less in the before-
                                  CWA time-block.
3-30

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Chapter 3: An Examination of "Worst-Case" DO in Waterways Below Point Sources Before and After the CWA
Table 3-2. Twenty-five catalog units with greatest improvements in worst-case (mean 10th percentile) DO
after the CWA.
Source: USEPA STORET
Worst- Worst-
case DO case DO DO
Catalog Unit 1961-65 1986-90 Change
Rank Reach ID Name (mg/L) (mg/L) (mg/L)
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
04030204
04120102
04110002
17010307
07070002
18060005
02050306
04030104
05080002
08030204
10170203
04040002
08030203
04040003
06010104
08030205
06010205
02040204
04100002
11070207
04040001
18090208
07120007
07130011
04100009
Lower Fox, Wl
Cattaraugus, NY
Cuyahoga, OH
Lower Spokane, WA
Lake Dubay, Wl
Salinas, CA
Lower Susquehanna, MD
Oconto, Wl
Lower Great Miami, IN
Coldwater, MS
Lower Big Sioux, IA
Pike-Root, IL
Yocona, MS
Milwaukee, Wl
Holston, TN
Yalobusha, MS
Upper Clinch, TN
Delaware Bay, NJ
Raisin, MI/OH
Spring, KS/MO
Little Calumet-Galie
Mojave, CA
Lower Fox, IL
Lower Illinois, IL
Lower Maumee, OH
0.1600
1 .3230
0.2950
3.5000
0.8800
3.1800
0.8800
0.5000
1.1850
0.0000
0.0000
0.9400
0.0000
2.1800
0.1570
0.0000
1.6140
0.5300
4.0588
1 .6000
0.5700
4.0200
3.7800
1 .9400
2.0676
7.2050
7.6000
6.5008
9.7000
6.6833
8.7500
6.1960
5.8000
6.4675
5.2082
5.1433
5.9400
4.8543
6.9567
4.8686
4.6295
6.0819
4.9100
8.3400
5.6250
4.5553
7.9767
7.5764
5.7225
5.8471
7.0450
6.2770
6.2058
6.2000
5.8033
5.5700
5.3160
5.3000
5.2825
5.2082
5.1433
5.0000
4.8543
4.7767
4.7116
4.6295
4.4679
4.3800
4.2812
4.0250
3.9853
3.9567
3.7964
3.7825
3.7795
                                                                                       3-31

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oo

ro
Figure 3-19
Location map and distribution chart of the 10 catalog units with the greatest before versus after-CWA improvements in worst-case DO. Source: USEPA STORET
                                                     Before the CWA
                                                     After the CWA
                                      3456789    10

                                          Catalog Unit Ranking
                                                                                                                                                      I
                                                                                                                                                      m


                                                                                                                                                      "*•
                                                                                                                                                      3'
                                                                                                                                                      f

                                                                                                                                                      I
                                                                                                                                                      to

                                                                                                                                                      I
                                                                                                                                                      !
                                                                                      Catalog units with improved worst-case DO
                                                                                      Catalog units with degraded worst-case DO

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  Chapter 3: An Examination of "Worst-Case" DO in Waterways Below Point Sources Before and After the CWA


 Comparison of the Change in Signal Between the
 Reach and Catalog Unit Scale Using the  Upper
 White River Basin (Indiana) as an  Example

     Recall that the underlying objective of the second leg of the three-legged
 stool approach of this study was to measure the change in the response "signal"
 linking point source discharges with downstream water quality before and after
 the CWA at sequentially larger aggregations of spatial scales (reach, catalog unit,
 and major river basin). The theory is that if a signal change can be detected at
 sequentially larger scales, this would provide evidence that the CWA's technology-
 and water quality-based effluent control requirements yielded broad as well as
 localized benefits (that is, stream reaches both within and beyond the immediate
 sag curve have benefited from the CWA).
     The purpose of this subsection is to provide a practical comparison of reach
 and catalog unit signals using worst-case DO from monitoring stations in the
 Upper White River Basin (CU #05120201), the catalog unit in which the city of
 Indianapolis, Indiana, and several smaller municipalities reside.

 Background
     In the 1960s the citizens of the city of Indianapolis depended on primary
 treatment. Secondary treatment was added in the 1970s, and in 1983  the city
 further upgraded its POTWs to advanced  wastewater treatment (AWT) to
 achieve compliance with water quality standards for DO. Two municipal facilities,
 designed to treat up to 379 cfs (245 mgd), currently discharge effluent to the
 White River. The base flow of the river is low; the 10-year, 7-day minimum
 (7Q10) flow is about 50 cfs in the channel upstream of the two POTWs. Conse-
 quently, under these low-flow conditions, Indianapolis's wastewater effluent
 accounts  for about 88 percent of the downstream flow.
     In addition to Indianapolis, the 2,655-square-mile drainage area  of the Upper
 White River Basin contains several smaller municipalities that also discharge
 municipal wastewater into the White River network. Population centers upstream
 from Indianapolis include Muncie, Anderson, and Noblesville. Waverly, Centerton,
 and Martinsville are towns located downstream of the  city. Land use  in the basin
 includes agricultural uses (65 percent) and  urban-industrial uses (25 percent), with
 other uses accounting for the remaining 10 percent (Crawford and Wangness,
 1991).
     Using point and nonpoint source loading estimates of BOD5 for  contempo-
 rary conditions (16.3 metric tons/day ca. 1995) compiled for the NWPCAM
 (Bondelid et al, 1999), municipal loads in the basin are estimated to account for
 50 percent of the  total loading to basin waterways. The remaining one-half of the
 total BOD5 load is contributed by major and minor industrial sources (11 percent),
 rural runoff (24 percent), urban runoff (13  percent), and CSOs (2 percent).
     In a pre-AWT (1978-1980) and post-AWT (1983-1986) study of changes in
 water quality of the White River following  completion of the upgrade to AWT
 from secondary activated sludge facilities for the city of Indianapolis, Crawford
 and Wangness (1991) concluded that there were statistically significant improve-
ments in ambient levels of DO, BOD5, and ammonia-nitrogen downstream of the
upgraded municipal wastewater facilities. DO, in particular, improved by about 3
mg/L  as a result of reductions in carbonaceous (BOD5) and nitrogenous (ammo-

                                                                                           3-33

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment


                          nia) oxygen demands. For this study, Crawford and Wangness (1991) selected
                          monitoring stations located about 10 and 15 miles downstream of Indianapolis's
                          outfalls to collect data within the critical oxygen sag location of "degradation" and
                          "active decomposition" (Waverly) and the "recovery" zone (Centerton) (see
                          Figure 3-6).
                              During the before-CWA period from 1961 to 1965, streamflow conditions in
                          the Upper White River Basin were characterized as dry, with persistent drought
                          conditions for three consecutive summers from 1963 through 1965. During these
                          three summers, streamflow ratios ranged from 40 to 63 percent of the long-term
                          summer mean flow (see Figure 3-4(a) for 1963). Similarly, during the after-CWA
                          period of 1986-1990, the  Upper White River Basin was affected by the severe
                          drought conditions of 1988 (streamflow ratio of only 34 percent of mean summer
                          flow) that extended over  large areas of the Midwest, Northeast, and upper
                          Midwest (see Figure 3-4(b)). The hydrologic conditions of the White River are
                          particularly critical in assessing before and after changes in DO because the
                          municipal effluent flow of the upgraded AWT facilities (after 1983) accounted for
                          about 88 percent of the river flow downstream of Indianapolis under low-flow
                          conditions of the White River.

                          The Catalog-Level Signal
                              The analysis of before- and after-CWA worst-case DO data for the Upper
                          White River catalog unit revealed that this catalog unit improved by 1.75 mg/L,
                          from 3.80 mg/L (mean value of worst-case DO from 37 stations) before the
                          CWA to 5.55 mg/L (mean value of worst-case DO from 14 stations) after the
                          CWA. This level of improvement ranked it 64th out of the 246 catalog units with
                          before and after data sets (see Appendix D). A companion examination of BOD5
                          revealed that worst-case (90th percentile) loading in the catalog unit was reduced
                          from 34.8 mg/L before the CWA (1961-1965) to 6.9 mg/L after the CWA (1986-
                          1990).
                              The signal change detected provides evidence that
                              •    The signal linking point source discharges with downstream water
                                  quality inherently resides in the before- and after-CWA worst-case DO
                                  data collected at stations throughout the Upper White River catalog
                                  unit.
                              •    The signal is strong enough to  be detected using a catalog unit scale
                                   summary statistic (mean of 10th percentile worst-case DO measure-
                                  ments for stations within the catalog unit).
                              •    Improved wastewater treatment by the city of Indianapolis, as well as
                                  upgrades of wastewater treatment  from small municipal facilities
                                  throughout the basin, resulted in broad water quality improvements in
                                  the Upper White River  after the CWA.

                          The Reach-Level Signals
                              The POTW discharge/downstream water quality signal detected at the
                          catalog unit scale is, in reality, a statistical aggregation of signals associated with
                          all the monitored point source-influenced reaches in the Upper White River
                          watershed. If one breaks  the catalog unit down and examines the before- and
3-34

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  Chapter 3: An Examination of "Worst-Case" DO in Waterways Below Point Sources Before and After the CWA
after-CWA summary statistics for individual reaches, one would expect to find
that the reaches in the "degradation" and "active decomposition" zones have
more pronounced DO changes than reaches located outside those zones. An
examination of reaches in the Upper White River catalog unit revealed this theory
to be true. Figure 3-20 includes the locations and before- and after-CWA bar
charts for each of the seven reaches in the Upper White River that have paired
worst-case DO data. Figure 3-21 provides information regarding changes in
worst-case (90th percentile) BOD5  concentrations  for the  same reaches.
     Key observations include the following:
     •    The reach with the greatest reduction of BOD5 and greatest improve-
         ment in DO was the reach located immediately downstream of India-
         napolis (05120201004) in the vicinity of Waverly. DO in this reach,
         which ranked sixth out of 311 reaches with before and after DO data
         nationwide (see Table 3-1), moved from 0.7 to 6.4 mg/L, an increase of
         5.7 mg/L. In this same reach, the 90th percentile BOD5 concentration
         declined from 58.1 mg/L to 4.3 mg/L.
     •    Reaches located immediately upstream of Indianapolis showed little
         change in before-  and after-CWA DO conditions (Eagle Creek
         05120201032; White River 05120201007,05120201009; and Fall Creek
         05120201006). BOD5, however, decreased from 20.6 to 7.0 mg/L in
         reach 05120201007 and from 12.4 to 3.0 mg/L in reach 05120201009.
         The decline in BOD5 levels most likely reflects upgrades in municipal
         facilities for the small towns upstream of Indianapolis.
     •    Farther upstream, in the vicinity of Muncie and Anderson, greater
         improvements in DO were detected (along with decreasing trends in
         90th percentile BOD5 concentrations). In reach 05120201013
         (Muncie), DO in the White River improved by 4.2 mg/L, from 2.2 mg/L
         before the CWA to 6.4 mg/L after the act. In the  compilation of 311
         reaches with the greatest before and after improvements in DO, this
         reach ranked 24th. For the reach in the vicinity of Anderson
         (05120201011), located downstream of Muncie, DO improved by 2.8
         mg/L, from 3.4 mg/L to 6.2 mg/L. This reach ranked 44th in the
         nationwide ranking of stream reaches with DO improvements.
     •    The Lower White River catalog unit is located downstream from the
         Upper White River unit. Before and after station records from the most
         upstream reach of the basin reflect the impact of the wastewater
         discharges from the small towns of Centerton and Martinsville, as well
         as the recovery zone of the sag curve associated  with the Indianapolis
         point source inputs. In this recovery reach of the White River
         (05120202031), DO improved by 1.9 mg/L, from 3.4 mg/L to 5.3 mg/L.
     The aggregation of worst-case before- and after-CWA  station records at
the reach scale produced a variety of signals. As expected, the signal linking point
source discharges with downstream water quality is most pronounced in reaches
located immediately below point source discharges (in the critical portion of the
sag zone). The signal became weaker farther downstream;  however, in most
reaches it was detectable,  especially in the recovery zone of the sag curve
associated with the Indianapolis discharges.
                                                                                             3-35

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Chapter 3:  An Examination of "Worst-Case" DO in Waterways Below Point Sources Before and After the CWA
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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment


                          Major  River Basins

                              The  stations comprising the 311 reach-aggregated worst-case DO data
                          were pooled by the 18 major river basins of the contiguous United States for
                          statistical  analyses of the significance of changes in DO concentration before and
                          after the CWA. These analyses were limited to the 311 evaluated reaches to
                          improve the assurance that the data were collected from the same sample
                          population.
                              Table 3-3 presents the number of observations, the results of the paired t-
                          test (95 percent confidence level), and the mean of the pooled before and after
                          worst-case DO data. The null hypothesis assumes that there is not a significant
                          difference between the mean concentrations for the before and after periods. The
                          means of  the pooled worst-case DO data are presented as column graphs in
                          Figure 3-22.
Table 3-3. Statistical significance of trends in mean 1 0th percentile (worst-case) DO by major river basin:
before vs. after CWA (1 961 -1 965 vs. 1 986-1 990). Source: USEPA STORET.
Worst- Worst-

River Basin
All USA (01 -18)
01 - New England Basin
02 - Middle Atlantic Basin
03 - South Atlantic-Gulf
04 - Great Lakes Basin
05 - Ohio River Basin
06 - Tennessee River Basin
07 - Upper Mississippi Basin
08 - Lower Mississippi Basin
09 - Souris-Red Rainy Basin
10 - Missouri River Basin
11 - Arkansas-Red — White Basin
12 - Texas-Gulf Basin
13 - Rio Grande Basin
14 - Upper Colorado River Basin
15 - Lower Colorado River Basin
16 - Great Basin
17 - Pacific Northwest Basin
18 - California Basin
Paired f-test: 95% confidence - 2-sided test
Kolmogorov Smirnov test: 90% confidence,
'insufficient data for analysis
No. of
Paired
Reaches
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1
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61
26
66
19
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Yes
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Yes
Yes
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Yes


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Smirnov
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Yes
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Yes
Yes
Yes
Yes
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Yes
No
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No
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Yes


case DO
1961-1965
(mg/L)
4.56
4.30
2.80
4.10
3.85
5.40
4.08
3.80
3.79
5.65
5.76
5.36
5.77
-
4.88
-
7.45
7.61
5.61


case DO
1986-1990
(mg/L)
5.53
6.90
4.94
4.73
6.06
6.04
5.23
5.31
3.94
6.75
6.53
4.60
4.37
-
7.22
-
6.10
8.21
7.58


3-38

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  Chapter 3: An Examination of "Worst-Case" DO in Waterways Below Point Sources Before and After the CWA
Figure 3-22
Before vs. after trends in worst-case DO for major river basins: 1961-1965 vs. 1986-1990.
Source: USEPA STORET
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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
Figure 3-23
Statistical significance of the difference between before- and after-CWA worst-case DO mean values for the 18 major
river basins in the 48 contiguous states.  Source: USEPA STORET
  Shading indicates if there is a statistically  x/"~~\ }
  significant difference between the basin's        \(
  before- and after-CWA worst-case DO mean
  values.

    |U Yes, a statistically significant difference

    Q No, not a statistically significant difference
    |	| Insufficient data for analysis
                                Figure 3-24 presents the before and after worst-case DO frequency distri-
                           butions for the mid-Atlantic, Great Lakes, Tennessee, and Upper Mississippi
                           major river basins. It is important to note that not only has the mean changed, but
                           the distribution has also changed. The frequency distributions shown in the figure
                           suggest that there have been improvements at the lower percentile levels of DO
                           (the 10th and 20th percentiles) for these river basins. Before the CWA in the
                           1961-1965 time block, worst-case DO was at 1 mg/L or lower. After the act,
                           worst-case conditions had improved to levels of about 3 to 5 mg/L.
                                The Kolmogorov-Smirnov test was used to statistically compare whether the
                           before and after distributions are significantly different. The Kolmogorov-Smirnov
                           test is a goodness of fit test that compares the empirical distributions from the two
                           time periods. Figure  3-24, showing the empirical cumulative distribution functions
                           of DO from the before and after periods, can be used to visualize what the
                           Kolmogorov-Smirnov test is comparing on a statistical basis. The vertical axis
                           presents the DO concentration corresponding to a given percentile on the horizon-
                           tal  axis.  Referring to the mid-Atlantic basin, for example, it can be seen that about
3-40

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       Figure 3-24

       Before- and after-CWA frequency distributions of worst-case DO aggregated by major river basin for reaches with paired before and after data sets:

       (a) Middle Atlantic, (b) Great Lakes, (c) Tennessee River, and (d) Upper Mississippi River basins.   Source: USEPA STORET.
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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
                           70 percent of the observations from the before period were less than 4 mg/L,
                           whereas in the after period only 30 percent of the observations were less than 4
                           mg/L. The Kolmogorov-Smirnov test is a statistical comparison of the maximum
                           distance between these curves. The results from the Kolmogorov-Smirnov test
                           are provided in Table 3-3.
                                Based on the two different statistical tests, and discounting the 7 river basins
                           with limited data, 8 of the 11 remaining river basins can be characterized by a
                           statistically significant improvement in worst-case DO using at least one of the
                           two tests. Mixed results (yes and no) were obtained for two basins with the
                           Kolmogorov-Smirnov test indicating no significant improvement for the Tennessee
                           (6) and the Pacific Northwest (17) basins, whereas the paired t-test indicated
                           significant improvements (yes) in these basins. Overall, there is a statistically
                           significant improvement in worst-case DO trends using both statistical tests at 6
                           out of 11 river  basins with sufficient  data. Of the five basins with at least one
                           "nonsignificant" change, three basins ( Missouri River, Arkansas Red-White, and
                           Pacific Northwest) had a mean worst-case pooled DO level greater than 5 mg/L
                           in the before time period and were less likely to be targeted for improved point
                           source pollution control.  It is also noteworthy that in the 25-year interval between
                           the before- and after-CWA periods, there were no statistically significant condi-
                           tions of degradation of worst-case DO for any of the major river basins. It is also
                           noteworthy that when all 311 paired  reaches are analyzed together, both tests
                           indicate significant increases in worst-case DO (see Figure  3-25 and top row (All
                           US A) of Table 3-3  ).
                                        12
Figure 3-25
Before- and after-CWA
frequency distributions of
worst-case DO aggregated
over all major river basins
for the 311 reaches with
paired before and after
data sets.
Source: USEPA STORET.
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3-42

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  Chapter 3: An Examination of "Worst-Case" DO in Waterways Below Point Sources Before and After the CWA


D.   Summary and  Conclusions

     The purpose of this chapter is to address the second leg of the three-legged
stool approach for answering the question posed in Chapter 1—How has the
Nation's  water quality changed since implementation of the 1972  CWA's
mandate for secondary treatment as the minimum  acceptable technology for
POTWs?  Recall that the basic goal of the second leg was to determine the extent
to which water quality improvements could be linked to the CWA's push for
secondary and greater levels of treatment in the Nation's POTWs. If evidence
showed that worst-case DO concentrations improved at broad, as well as local-
ized spatial  scales, the second leg of the investigation could add cumulative
support for  the conclusion that the CWA's mandates were successful. The
following objectives were established to guide this part of the study:
    •    Develop before- and after-CWA data sets composed  of DO summary
         statistics derived from monitoring stations screened for worst-case
         conditions.
    •    Develop a worst-case DO summary statistic for each station for each
         before- and  after-CWA time period and then aggregate these data by
         sequentially larger spatial scales (reaches, catalog units, and major river
         basins).
    •    Conduct an analysis of the  spatial units having both a before- and after-
         CWA summary statistic  and assess the magnitude of worst-case DO
         change between the two time periods.
    •    Assess the change in the point source discharge/downstream DO
         signal over the progressively larger spatial scales.


Key  Points of the Background Section

     Section A provided background concerning the  source of DO data used in
this study, why worst-case conditions are an appropriate screening tool for
developing  the before- and after-CWA data sets, and  the role spatial scale played
in the second leg of this study. Key points include the following:
    •    The sharpest signal linking point source loading and downstream DO
         inherently resides in data collected in worst-case (high temperature and
         low flow) conditions. These worst-case conditions typically occur in the
         summer months (July through September) during consecutive runs of
         dry years  (persistent drought).
    •    Widespread persistent drought was most pronounced in the summers in
         1961-1965 (before the CWA) and 1986-1990 (after the CWA). These
         time-blocks were used to define the before- and after-CWA time
         periods for the comparison analysis.
    •    From a spatial perspective, worst-case critical, or minimum, DO below
         a  point source occurs in the "degradation" or "active decomposition"
         zone of the oxygen sag curve. However, screening rules were not
         developed to select monitoring stations located within these zones
         because the  goal of this second leg is to examine changes in the point
                                                                                            3-43

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment	


                                  source discharge/downstream DO at broad scales as well as localized
                                  scales. Consequently, the only screening rule regarding location of
                                  stations eligible for the before- and after-CWA analysis is that the
                                  station must be somewhere downstream and therefore potentially
                                  influenced by a point source.


                         Key  Points of the Data Mining  Section

                              Section B presented the six-step data mining process used to create the
                         before- and after-CWA data sets to be used in the comparison analysis. The
                         screening rules associated with each step are listed below:

                         Step 1—Data Selection Rules
                             •    DO, expressed as a concentration (mg/L),  will function as the signal
                                  relating point source discharges to downstream  water quality re-
                                  sponses.
                             •    DO data are extracted only from the July-September (summer season)
                                  time period.
                             •    Only surface DO data (DO data collected within 2 meters of the water
                                  surface)  are used.

                         Step 2—Data Aggregation Rules From a  Temporal Perspective
                             •    1961-1965 serves as the time-block to represent persistent drought
                                  before the CWA and  1986-1990 serves as the time-block to represent
                                  persistent drought after the CWA.
                                  To remain eligible for the before- and after-CWA comparison, DO data
                                  must come from a station residing in a catalog unit that had at least one
                                  year classified as dry (streamflow ratio 75 percent of summer mean)
                                  out of the 5 years in each before- and after-CWA time-block.

                         Step 3—Calculation of the Worst-case DO Summary Statistic
                         Rules
                                  For each water quality station, the 10th percentile of the DO data
                                  distribution from the before-CWA time period (July through September,
                                  1961-1965) and the 10th percentile of the DO data distribution from the
                                  after-CWA time period (July through September, 1985-1990) are used
                                  as the station's DO worst-case statistics for the comparison analysis.
                             •    To remain eligible for the before- and after-CWA statistical compari-
                                  son, a station must have a minimum of eight DO measurements within
                                  each  of the 5-year time-blocks.

                         Step 4—Spatial Assessment Rules
                             •    Only water quality stations on streams and rivers affected by point
                                  sources are included  in the before- and after-CWA comparison  analy-
                                  sis.
3-44

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  Chapter 3: An Examination of "Worst-Case" DO in Waterways Below Point Sources Before and After the CWA


Step 5—Data Aggregation Rules From a Spatial Perspective
         The before- and after-CWA data sets are collections of DO summary
         statistics that characterize worst-case DO at individual water quality
         monitoring stations across the United States for the 1961-1965 time-
         block and the 1986-1990 time-block, respectively (one DO summary
         statistic per station per time-block).
    •    For each data set and time-block, the 10th percentile value from each
         eligible station is aggregated within the spatial hydrologic unit. (Since
         the scales are hierarchical, a station's summary statistic is effectively
         assigned to a reach and a catalog unit.) A summary statistic is then
         calculated and assigned to the spatial unit for the purpose of character-
         izing its worst-case DO. If a spatial unit has only one monitoring station
         within its borders that meets the screening criteria, the 10th percentile
         DO value from that station simply serves as the unit's worst-case
         summary statistic. If, however, there are two or more stations within a
         spatial unit's borders, the 10th percentile values for all the eligible
         stations are averaged and this value is used to characterize worst-case
         DO for the unit.
    •    The mean  1 Oth percentile value is computed from the eligible station's
         10th percentile values  for the before- and after-CWA periods.

Step 6—Development of the Paired Data Sets (at each  spatial
scale)
    •    To be eligible for the paired comparison analysis, a hydrologic unit must
         have both  a before-CWA and an after-CWA summary statistic as-
         signed to it.


Key  Points of the Comparison Analysis  Section

     Section C presented the results of the comparative before- and  after-CWA
analysis of worst-case DO data derived using the screening criteria described in
Section B and aggregated by spatial units defined by three scales (reach, catalog
unit, and major river basin). Listed below are key observations for each spatial
scale.

Reach  Scale
    •    Sixty-nine percent of  the reaches evaluated showed improvements
         in  worst-case DO after the CWA. [Three hundred eleven  reaches (out
         of a possible 12,476 downstream of point sources) survived the data
         screening process with comparable before- and after-CWA DO
         summary statistics. The number of reaches available for the paired
         analysis was limited by the historical data for the 1961-1965 period].
    •    These 311  evaluated reaches represent a disproportionately high
         amount of urban/industrial population centers, with approximately 13.7
         million people represented (7.2 percent of the total population served by
         POTWs in 1996). The top 25 improving reaches saw their worst-
         case DO increase by anywhere from 4.1 to 7.2 mg/L!


                                                                                             3-45

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment


                              •   The number of evaluated reaches characterized by worst-case DO
                                  below 5 mg/L was reduced from 167 to 97 (from 54 to 31 percent).
                              •   The number of evaluated reaches characterized by worst-case DO
                                  above 5 mg/L increased from 144 to 214 (from 46 to 69 percent).

                          Catalog  Unit Scale
                              •   Sixty-eight percent of the catalog units  evaluated showed  improve-
                                  ments in worst-case DO after the CWA. [Two hundred forty-six
                                  catalog units (out of a possible 1,666 downstream of point sources)
                                  survived the data screening process with comparable before-  and  after-
                                  CWA DO summary statistics].
                                  The number of evaluated catalog units characterized by worst-case
                                  DO below 5 mg/L was reduced from 115 to 65 (from 47 to 26 per-
                                  cent). The number of evaluated catalog units characterized by worst-
                                  case DO above 5 mg/L increased from  131 to 181 (from 53 to 74
                                  percent).
                              •   Fifty-three of the 167 improving catalog units (32 percent) improved by
                                  2 mg/L or more while only 10 of 79 degrading catalog units (13 per-
                                  cent) degraded by 2 mg/L or more.
                              •   These 246 evaluated catalog units represent a disproportionately high
                                  amount of urban/industrial population centers, with approximately 61.6
                                  million people represented (32.5 percent of the total population served
                                  byPOTWsin 1996).

                          Major River Basin Scale
                              •   A total of 11 out of 18 major river basins had sufficient reach-aggre-
                                  gated worst-case DO data for a before- and after-CWA comparison
                                  analysis.
                              •   Based on two statistical tests, 8 of the 11 major river basins can be
                                  characterized as having statistically significant improvement in worst-
                                  case DO levels after the CWA. The three  basins that did not statisti-
                                  cally improve under either test also did not have statistically significant
                                  degradation.
                              •   When all the 311 paired (i.e., before vs. after) reaches were aggre-
                                  gated and the  statistical tests run on all  18 of the major river basins of
                                  the contiguous states as a whole, worst-case DO also showed signifi-
                                  cant improvement.
3-46

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  Chapter 3: An Examination of "Worst-Case" DO in Waterways Below Point Sources Before and After the CWA
Conclusions

     The statistical analyses developed for this study are not ideal. One
major concern is the potential bias introduced in the ambient monitoring
programs used to collect the data archived in STORET. It is believed that
the analysis of data sets with data in the before and after time periods
alleviates some of these concerns and that results are generally comparable
for the two different statistical tests. Based on the systematic, peer-re-
viewed approach designed to identify and evaluate the national-scale
distribution of water quality changes that have occurred since the 1960s, this
study has compiled strong evidence that the technology- and water quality-
based policies of the CWA for point source effluent controls have been
effective in significantly improving DO. In this retrospective analysis, DO
was used as the key indicator because the reduction of organic carbon and
nitrogen (BODu) loading from municipal and industrial point sources was
one of the major goals of the CWA's technology-based policy, which re-
quired industrial effluent limits and a minimum level of secondary treatment
for municipal facilities. Based on ambient DO records, significant before and
after improvements in many rivers and streams have been identified over
national, major river basin, catalog unit, and reach-level spatial scales.
     The "signal" of downstream water quality responses to upstream
wastewater loading and the changes in this signal since the 1960s has been
successfully decoded from the "noise" of millions of archived water quality
records. Given the very large spatial scale of the major river basins, it is remark-
able to observe statistically significant before and after DO improvements as
detected using the systematic methodology described herein. Previous evaluations
of the effectiveness of the CWA (e.g., Smith et al., 1987a, 1987b, 1992; Knopman
and Smith, 1993) were not able to report conclusively significant improvements in
DO. In these earlier studies, however, the methodologies used were not specifi-
cally designed to separate the signal of downstream water quality response from
the noise within large national databases. Using appropriate data screening rules
and spatial aggregations, it has been demonstrated that improvements in water
quality, as measured by improvements in worst-case DO, have been achieved
since the 1960s.
     The findings of this national-scale water quality assessment demonstrate
three important points:
     •    As new monitoring data are collected, it is crucial for the success of
         future performance measure evaluations of pollution control policies
         that the data be submitted,  with appropriate QA/QC safeguards, to
         accessible databases.  If the millions of records archived in STORET
         had not been readily accessible, it would have been impossible to
         conduct this analysis to identify the signals of water quality improve-
         ments that have been achieved  over the past quarter-century.
     •    Significant after-CWA improvements in worst-case summer DO
         conditions have been quantitatively documented with credible statistical
         techniques in this study over different levels of spatial data aggregation
         from the small subwatersheds of Reach File Version 1 river reaches
         (mean drainage area of approximately 115 mi2) to the very large
         watersheds of major river basins (mean area of 434,759 mi2).
    Conclusion of
  There were significant
 after-CWA improvements
in worst-case summer DO
conditions in two-thirds of
the hydrologic units at all
                                                                                              3-47

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment


                              •    The data mining and statistical methodologies designed for this study
                                   can potentially be used to detect long-term trends in signals for water
                                   quality parameters other than DO (e.g., suspended solids, nutrients,
                                   toxic chemicals, pathogens) to develop new performance measures to
                                   track the effectiveness of watershed-based point source and nonpoint
                                   source controls. The key element needed to apply the data mining
                                   methodology to other water quality parameters is the careful specifica-
                                   tion of rules for data extraction that reflect a thorough understanding of
                                   the various processes that influence the spatial and temporal distribu-
                                   tions of a water quality constituent, as well as the relevant sources of
                                   associated pollutants.

                          Population Affected by Reaches With Improved DO
                               To monetize environmental benefits derived from various environmental
                          policy decisions, USEPA developed the NWPCAM model (Bondelid et al., 1999),
                          which includes a link between 1990 population and RF1 reaches. As discussed in
                          Section E, this model does not include all estuarine and coastal waters, and as a
                          result, does not account for the entire US population. It  is estimated that about
                          one-third of the U.S. population is not accounted for in the model. At the same
                          time if a person is located near two rivers, that person is counted twice since he
                          or she can derive a benefit from environmental improvements in either river.
                               Recognizing this accounting procedure, the model accounts for 197.7 million
                          people in 23,821 reaches. In the 311 reaches analyzed here (1.3 percent of
                          reaches in the model), the model accounts for 13.7 million people (6.9 percent of
                          the population in the model). The ratio of the percent population to percent
                          reaches in the model demonstrates that the screening  process developed for this
                          analysis is reasonably successful in finding reaches with data near urban centers,
                          although 57 of the 311 reaches did not have population associated with them. Of
                          the 13.7 million people represented by the 311 reaches, 11.8 million of them (86
                          percent) are associated with reaches that have an increased worst-case DO from
                          before to after the CWA. Almost one-half (45 percent) of the selected population
                          are associated with reaches that went from worst-case  DO below 5 mg/L before
                          the CWA to greater than 5 mg/L after the CWA. Although it is unfortunate that
                          more reaches are not considered in  the current analysis (mainly because of
                          limitations in available monitoring data for the before-CWA periods), it is helpful to
                          consider that the corresponding 246 catalog units include 61.6 million (31.2
                          percent) of the 197.7 million people accounted for in the model. And three-fourths
                          (46.5 million) of the 61.6 million people are in catalog units that had an increase in
                          worst-case DO  between the before to after time period.

                          Sensitivity to Using DO versus Percent Saturation
                               The beginning of this chapter describes the physical processes associated
                          with atmospheric reaeration, oxygen demand, and dilution, as well as the impact
                          of changing water temperatures and elevation. During the initial development of
                          the screening methodology, considerable effort was spent evaluating various
                          indicators for water quality. Ultimately, DO was selected. Another strong candi-
                          date was DO expressed as percent  saturation. Use of percent saturation would
                          effectively normalize the DO data to account for geographic differences in
3-48

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  Chapter 3: An Examination of "Worst-Case" DO in Waterways Below Point Sources Before and After the CWA
elevation, chlorides, and water temperature. Saturation levels of DO decrease
with higher elevations, increasing chloride content, and warmer water tempera-
tures (Chapra, 1997). Correcting for elevation would improve spatial comparisons
such as those in Figures 3-13 through 3-15, and correcting for chlorides and water
temperature would account for some of the unexplained variability that might exist
between the before and after time periods.
     To evaluate the impact that selection of DO over DO as percent saturation
might have on the analysis, two scatter plots with data aggregated to the reach
level were compared. Figure 3-26(a) presents the DO after the CWA as a
function of DO before the CWA. Figure 3-26(b) presents the DO (percent
saturation) after the CWA as a function of DO (percent saturation) before the
CWA aggregated to the reach level. The values for DO (percent saturation) were
computed using the same procedure used for DO. Points above the diagonal line
in either figure indicate that the DO or DO (percent saturation) increased.
Although the two figures use different scales, a visual comparison suggests that
there would be little difference if DO (percent saturation) were adopted over DO.
Given that the public has  a more intuitive understanding of DO measured as
concentration, the analysis in this chapter uses DO concentration rather than
percent saturation.
                                                                                                3-49

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
Figure 3-26
(a) Comparison of the 10th
percentile DO before the
CWA as a function of the
10th percentile DO after
the CWA. (b) comparison
of the 10th percentile DO
(percent saturation) before
the CWA as a function of
the 10th percentile  DO
(percent saturation) after
the CWA.
Source: USEPA STORET.
                             (a)
                                                      DO Before the CWA (mg/L)
                                 (b)
                                                 DO Before the CWA (% Saturation)
3-50

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  Chapter 3: An Examination of "Worst-Case" DO in Waterways Below Point Sources Before and After the CWA
References

Ackerman, W.C., Harmeson, R.H., and Sinclair, R.A. 1970. Some long-term
    trends in water quality of rivers and lakes. Transactions of the American
    Geophysical Union, vol. 51, page 516-522.
Bondelid, T., C. Griffiths, and G. van Houten. 1999. A national water pollution
    control assessment model. Draft tech. report prepared by Research Tri-
    angle Park, NC for U.S. Environmental Protection Agency, Office of
    Science and Technology, Washington, DC.
Chapra, S.C.  1997. Surface Water Quality Modeling. McGraw Hill, Inc. New
    York, NY.
Crawford, C.G., and D.J. Wangness. 1991. Effects of advanced wastewater
    treatment on the quality of White River, Indiana. Water Resources Bulletin
    27(5): 769-779.
Gunnerson, C.G. 1966. An atlas of water pollution surveillance in the United
    States, Otober 1, 1957 to September 30, 1965. Water Quality Activities,
    Division of Pollution Surveillance, Federal Water Pollution Control
    Adminstration, U.S. Department of the Interior, Cincinnati, OH.
Knopman, D.S. and R.A. Smith. 1993. Twenty years of the Clean Water Act:
    Has U.S. water quality improved? Environment 35(1): 17-41.
Smith, R.A., R.B. Alexander, and M.G. Wolman. 1987a. Analysis and interpre-
    tation of water quality trends in major U.S. rivers, 1974-81. Water-
    Supply Paper 2307, U.S. Geological Survey,  Reston, VA.
Smith, R.A., R.B. Alexander, and M.G. Wolman.  1987b. Water quality trends in
    the Nation's rivers. Science 235 (27 March 1987):1607-1615.
Thomann, R.V., and J.A. Mueller.  1987.  Principles of surface water quality
  modeling and control. Harper & Row, New York,  NY.
USEPA. STOrage and RETrieval Water Quality Information System. U.S.
    Environmental Protection Agency, Office of Wetlands, Oceans, and Water-
    sheds, Washington, DC.
USEPA. 1974. National  water quality  inventory, 1974. EPA-440/9-74-001.
    U.S. Environmental Protection Agency, Office of Water Planning and
    Standards, Washington, DC.
Wolman, A. 1971. The Nation's rivers. Science 174:905-918.
                                                                                            3-51

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 Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
3-52

-------
    Chapter  4
                        Case Study Assessments
                        of Water  Quality
    In the previous chapter, the national-scale evaluation of long-term trends in
    water quality conditions identified numerous waterways that were character-
    ized by substantial improvements in worst-case DO after the CWA (from
1961-1965 to 1986-1990). The signals of worst-case DO improvements that have
been detected from the "noise" of the STORET database document the tremen-
dous progress that has been achieved as a result of implementation of the CWA in
1972. Having identified numerous watersheds and RF1 reaches, however, the
inquisitive reader could easily list a number of questions to fill in the information
needed to tell a more complete history about environmental management and
water pollution control decisions in these watersheds.
    Typical questions might include the following: What are the population
trends?  Are point or nonpoint sources the largest component of pollutant loading?
What have been the long-term trends in effluent loading from municipal and
industrial sources over the past 25-50 years? Has industrial wastewater loading
declined because obsolete manufacturing facilities have been abandoned?  What
have been the long-term trends in key water quality parameters over the past 25-
50 years? Have reductions in wastewater loads had any impact on biological
resources or recreational activities?
    This third leg of the three-legged stool approach focuses on answering these
types of questions. The uniqueness of each watershed requires an investigator to
go beyond STORET and other centralized databases to identify, obtain, and
compile sufficient historical data to answer these questions and others. By
necessity, the selection of specific waterways based on case studies has often
been used as an appropriate technique for policy evaluations of the environmental
effectiveness of water pollution control decisions. That technique is used in
Chapters 5  through 13 of this document.
                                                                                4-1

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
                         A. Background
                              Less than a decade after enactment of the 1972 CWA, Congress and the
                         public began to raise policy questions about the national-scale effectiveness of the
                         technology-based controls of the CWA. In attempting to provide some answers to
                         these questions, case studies of water pollution control and water quality manage-
                         ment were compiled for a number of streams, rivers, lakes, and estuarine water-
                         bodies. To meet a variety of objectives, both anecdotal and quantitative data and
                         information have been collected for case studies evaluating water quality condi-
                         tions.
                              Anecdotal accounts of historical water pollution problems and changes in the
                         water quality of streams, rivers, estuaries, and coastal waters that had been
                         achieved by the early 1980s were reported by state agencies and compiled by
                         USEPA (1980) and the Association of State and Interstate Water Pollution
                         Control Administrators (ASIWPCA, 1984). Twenty-five years after enactment of
                         the 1972 CWA, USEPA (1997) and the Water Environment Federation (WEF,
                         1997) reported on the substantial water quality improvements that had been
                         achieved in rivers, lakes, estuaries, and coastal waters. Based on anecdotal
                         evidence, these reports concluded that the CWA had produced substantial gains in
                         water quality. No quantitative data  were presented, however, in either of these
                         reports to support the conclusion that the goals of the CWA were being achieved.
                              In a 1988 quantitative synthesis of before-and-after studies, USEPA (1988)
                         compiled the results of 27 case studies to document water quality changes that
                         had resulted from upgrades to municipal wastewater treatment facilities (primary
                         to secondary, or secondary to advanced treatment). With the exception of only a
                         few cases (e.g., Potomac estuary near Washington, DC, and Hudson River near
                         Albany, New York), most of the 27 cases accounted for both minor and major
                         facilities (< 0.1 to 30 mgd) discharging to small receiving waters with 7Q10 low
                         flows ranging from < 1 cfs to 100 cfs. Based on pollutant loading and water
                         quality data sets, 23 of the 27 case studies were characterized by at least moder-
                         ate improvements in water quality conditions after upgrades of the POTWs.
                         Included in USEPA's 1988 synthesis were the well-documented before-and-after
                         findings of Leo et al. (1984), based on 13 case studies of water quality changes
                         that were linked to upgrades from secondary to advanced treatment. Also
                         included in USEPA's synthesis were four case studies prepared by GAO (1986a)
                         of municipal upgrades for rivers in Pennsylvania: Lehigh River, Allentown (30
                         mgd); Neshaminy Creek, Lansdale  (2.36 mgd); Little Schuykill River, Tamaqua
                         (1.09 mgd); and Schuykill River, Hamburg (0.46 mgd).
                               A number of case studies other than those presented in this report have
                         documented trends in improvements in water quality conditions and biological
                         resources following site-specific upgrades. Estuarine case studies of pollutant
                         loading, water quality trends, fisheries, and other biological resources have been
                         prepared for Narragansett Bay (Desbonnet and Lee, 1991), Galveston Bay
                         (Stanley, 1992a), the Houston Ship  Channel (EESI, 1995), and Pamlico-Albemarle
                         Sound (Stanley, 1992b).
                               For Lake Washington in Seattle, Edmondson (1991) documented the long-
                         term ecological impact of the diversion during the mid-1960s of municipal waste-
                         water on cultural eutrophication and recovery of a large urban lake. The rejuve-
4-2

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                                                   Chapter 4: Case Study Assessments of Water Quality
nation of Lake Erie, declared "dead" during the 1960s, is positive evidence that
the regulatory controls of the 1972 Clean Water Act and the 1972 Great Lakes
Water Quality Agreement between Canada and the United States, designed to
mitigate bottom water hypoxia and cultural eutrophication by reducing pollutant
loads of organic matter and phosphorus, have been successful in greatly improv-
ing water quality (Burns, 1985; Charlton et al., 1995; Sweeney, 1995) and ecologi-
cal conditions (Krieger et al., 1996; Koonce et al., 1996; Makarewicz and
Bertram, 1991) in this once ecologically devastated lake. The Cuyahoga River, a
major tributary to Lake Erie at Cleveland, Ohio, sparked national attention when
the river caught fire in 1969, helping to push the U.S. Congress to pass the Clean
Water Act in  1972 (NGS, 1994). Three decades after the infamous fire, although
some water quality problems remain to be solved (e.g., urban runoff and CSOs),
water quality is greatly improved. Tourist-related businesses and recreational uses
along the riverfront are thriving, as are populations of herons, salmon, walleye,
and smallmouth bass (Hun, 1999; Brown and Olive, 1995).
     In freshwater river systems, Isaac (1991) presented long-term trends (1969-
1980) of DO in the Blackstone, Connecticut, Hoosic, and Quinebaug rivers in
Massachusetts to document water quality improvements after upgrades of
municipal facilities to secondary treatment. Using a wealth of historical data
compiled for New England, Jobin (1998) presents a number of case studies
documenting long-term trends in pollutant loading and water quality for freshwater
rivers (e.g., Neponset, Charles, Taunton, Blackstone) and estuarine systems (e.g.,
Boston Harbor, Narragansett Bay). In the Midwest, Zogorski et al. (1990)
prepared a case study of the Upper Illinois River basin to evaluate the availability
and suitability of water quality and effluent loading data as a demonstration of the
methodology for use in national assessments of water quality trends. Zogerski et
al. concluded that although a large amount of the required data is available from
national and  state databases, "the suitability of the existing data to accomplish
the objectives of a national water-quality assessment is limited."
     In another midwestern river, a statistical before-and-after analysis of water
quality in the White River near Indianapolis, Indiana, clearly showed improve-
ments in DO, ammonia, and BOD5 after an upgrade from secondary to advanced
treatment  (Crawford and Wangness, 1991). (See discussion in Chapter 3.) Similar
water quality improvements have also been documented for the Flint River in
Georgia and the  Neches River in Texas (Patrick et al., 1992). Becker and Neitzel
(1992) have compiled case studies of the impacts from water pollution and other
human activities on water quality, fisheries, and biological resources for a number
of major North American rivers. Another success story in the Pacific Northwest
has documented both water quality and economic benefits achieved by water
pollution control in the Boise River in Idaho (Hayden et al., 1994; Noah, 1994).
                                                                                                4-3

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
                         B.   Selection  of Case Study Waterways

                              Following the precedent established by these earlier before-and-after
                         assessments of changes in water quality that can be attributed, in part, to the
                         CWA, a number of freshwater and estuarine waterbodies were  selected as case
                         studies for this report. Criteria for the selection of case study sites included the
                         following:
                              •    The major river or estuarine system was identified in the 1960s as
                                  having gross water pollution problems.
                              •    The major river or estuarine system lies in a major urban-industrial
                                  region.
                                  Municipal wastewater is a significant component of the point source
                                  pollutant load to the system.
                              •    Water quality models were available to evaluate the water quality
                                  impact of simulated primary, secondary, and actual effluent scenarios
                                  for municipal dischargers.
                              •    Historical data were readily available.
                              Table 4-1 provides the 1996 population for the Metropolitan Statistical Areas
                         (MSAs) and counties included in the case study, and the types of data and
                         information compiled for each river or estuarine waterbody selected as a case
                         study. The population of the case study MSAs (43.2 million) accounted for 16
                         percent of the Nation's total population in 1996 (265.2 million) (USDOC, 1998).
                         Figure 4-1 shows the location of the case study watersheds. In contrast  to some
                         of the other case study assessments discussed previously, the case studies in this
                         report were specifically selected because they represent large cities located on
Table 4-1. Case study assessments of trends in water quality and environmental resources.
(Source: USDOC, 1998)
Case Study
Connecticut
River
Hudson-
Raritan Estuary
Delaware
Estuary
Potomac
Estuary
James Estuary
Upper
Chattahoochee
River
Ohio River
Upper
Mississippi
River
Willamette
River
1996 Study Area
Population
(millions)
1.109
16.991
5.973
4.635
2.237
3.528
3.779
2.760
2.149
Information Presented
Population
/
/
/
/
/
/
/
/
/
Pollutant
Loads
/
/
/
/
/
/
/
/
/
Water
Quality
/
/
/
/
/
/
/
/
/
Environmental
Resources
/
/
S
/
/
/
/
/
/
Recreational
Uses
/
/
/
/
/
/
/
/
/
Water Quality
Model


/
/
/


/

4-4

-------
                                                   Chapter 4: Case Study Assessments of Water Quality
                                                                          2. Hudson-Rantan
                                                                            estuary
                                  8. Upper Mississippi River j
                                                                             6. Chattahoochee River
Figure 4-1.  Location of case study watersheds.
major waterways known to have been plagued by serious water pollution prob-
lems during the 1950s and 1960s (Table 4-2). Many of the case study waterways
either were the sites of interstate enforcement conferences from 1957 to 1972 or
were listed by the federal government as being potential waterways to convene
state-federal enforcement conferences in 1963 (Zwick and Benstock, 1971). Two
of the case studies, the Ohio River and tributaries to New York Harbor (Passaic
River and Arthur Kill), were identified by the federal government in 1970 in a list
of the top 10 most polluted rivers (Zwick and Benstock, 1971). The Department
of the Interior identified all the estuarine case study sites as waterways suffering
from either low oxygen levels or bacterial contamination in a national study of
estuarine water quality (USDOI,  1970). All but two of the case study areas were
the subject of water quality evaluation reports prepared for the National Commis-
sion on Water Quality (NCWQ) to provide baseline data to track the effective-
ness of the technology-based effluent controls required under the newly enacted
1972 CWA (see Mitchell, 1976).
     For all the case studies, data have been compiled to characterize long-term
trends (more than 50 years) beginning in 1940 for population, upgrades to munici-
pal wastewater facilities, effluent loading, water quality, environmental resources,
and recreational uses. Additional  data have been obtained from validated water
quality models for the Upper Mississippi River, Potomac estuary, Delaware
estuary, and James estuary to quantify improvements in water quality achieved by
municipal upgrades from primary to secondary or  advanced treatment levels.
Data sources include published scientific and technical literature, USEPA's
STORET database, and unpublished technical reports ("grey"  literature) prepared
by consultants and state, local, and federal agencies.
                                                                                                4-5

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
      Table 4-2.    Identification of gross water pollution problems for case study waterways in government
                  documents. Sources: Zwick and Benstock, 1971; USDOI, 1970; and Mitchell, 1976.
Case Study
Connecticut River
Hudson-Raritan estuary
Delaware estuary
Potomac estuary
James estuary
Chattahoochee River
Ohio River
Upper Mississippi River
Willamette River
Potential
Enforcement
Conference
1963
•
•

•

•
•
•

Enforcement
Conference
1957-72
•
•

•

•
•
•

Top 10
Polluted
Waterways
1970

•




•


NCWQ
Case
Studies
1976
•
•
•
•

•
•
•

National
Estuarine
Pollution Study
1970
•
•
•
•
•




                         C. Before and After CWA

                              Using water quality data extracted from USEPA's STORET database (as
                         described in Chapter 3), before-and-after conditions for summer (July-Septem-
                         ber), 10th percentile DO levels in RF1 reaches selected from the  case study
                         watersheds (Figure 4-1) clearly demonstrate dramatic improvements during the
                         period after the CWA from 1986-1995 for all the case study sites  (Figure 4-2).
                         Before the CWA, during the 10-year period from 1961 to 1970, "worst-case" DO
                         levels were in the range of 1 to 4 mg/L for most of the case study sites. After the
                         CWA, worst-case DO levels had improved substantially to levels of about 5 to 8
                         mg/L during 1986-1995, with the worst-case oxygen levels of less than 2 mg/L
                         before the CWA improving to 5 mg/L or higher after the CWA. Great progress
                         has been achieved in improving DO conditions in New York Harbor, the
                         Chattahoochee River, the Delaware River, and the Potomac River.
                              Water quality improvements in other constituents, including BOD5, sus-
                         pended solids, coliform bacteria, heavy metals, nutrients, and algal biomass, have
                         also been linked to reductions in municipal and industrial point source loads for
                         many of the case studies. Figure 4-3 correlates long-term trends in the reduction
                         of effluent loads of BOD5 with improvements in summer DO in the Upper
                         Potomac estuary (Washington, DC), the Upper Mississippi River (Minneapolis-St.
                         Paul, MM), and the Willamette River (Portland, OR). Finally, improvements in
                         water quality have also been linked to the post-CWA restoration of important
                         biological resources (e.g., fisheries and submersed  aquatic vegetation in the
                         Potomac estuary)  and increased recreational  demand and aesthetic values of
                         waterways once considered extremely unsightly (e.g., Upper Mississippi River).
4-6

-------
                                                     Chapter 4: Case Study Assessments of Water Quality
Figure 4-2
Location map of case study waterways and distribution chart of their before- and after-CWA mean 10th percentile DO
for case study RF1 reaches: 1961-1970 vs. 1986-1995. Source: USEPA STORET.
                                                             3. Delaware estuary
                                                                                     1. Connecticut River
             9. Willamette River |
                                                             4. Potomac estuary
                                    8. Upper Mississippi River |
                                                                                    5. James estuary I
                                                                                 6. Chattahoochee River
                                         Before the CWA
                                         After the CWA
                   234567

                     Case Study Waterway Number
                                                                                                   4-7

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
Figure 4-3. Long-term trends of improvements in ambient DO and declines in effluent BOD5 loading for (a) Upper
Potomac estuary, (b) Upper Mississippi River, and (c) Willamette River. Sources: Larson, 1999; Gleeson, 1972;
Jaworksi, 1990; MWCOG, 1989; ODEQ,  1970; USEPA STORET.
                      (a)
                        Upper Potomac Estuary
                               Washington DC
                                                                100
                                               1970
                                                     1980
                                                           1990
(b)
Upper Mississippi River
 Minneapolis-St. Paul, Minnesota
    10
     5-










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s
s
s
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s
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•
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/
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                                        150
                                        100
                                        50
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                                                   I
                                                   in
     1940	1950	1960	1970   1980	1990
Lower Willamette River
      Portland, Oregon









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                         D. Policy  Scenarios for Municipal  Effluent

                         Discharges

                             Before the 1972 CWA, state officials made waterbody-dependent decisions
                         about the required level of municipal wastewater treatment needed to attain
                         compliance with ambient water quality criteria or standards. After the 1972 CWA,
                         the USEPA implemented a technology-based policy to regulate pollutant loading
                         from municipal and industrial point sources. Under the 1972 CWA, municipalities
                         were required to achieve at least a minimum level of secondary treatment to
                         remove approximately 85 percent of the oxygen-demanding material from  waste-
                         water. In cases where the minimum level of secondary treatment was not suffi-
                         cient to meet water quality criteria or standards, ambient criteria were used to
                         determine a water quality-based level of wastewater treatment greater than
                         secondary treatment. From a policy and planning perspective, the key question for
                         water quality management decision makers is: What level of municipal wastewa-
                         ter treatment is needed to ensure compliance with water quality criteria or
                         standards under critical conditions?
4-8

-------
                                                      Chapter 4:  Case Study Assessments of Water Quality
     For the Delaware, Potomac, James, and Upper Mississippi case studies,
validated water quality models have been used to provide quantitative answers to
evaluate the changes in water quality conditions achieved as a result of either
actual or hypothetical upgrades to municipal wastewater treatment facilities.
Effluent loading rates for the primary and secondary loading scenarios were
based on existing population served and effluent flow data with typical effluent
concentrations characteristic of primary and secondary treatment facilities;
existing loading rates were used to define the better-than-secondary (actual)
scenario. Receiving water streamflow was based on the existing "dry" summer
streamflow measurements used to validate the models. The water quality models
were used to simulate the impact of the primary, secondary, and actual better than
secondary loading scenarios on the spatial distributions of DO, BOD5, nitrogen,
phosphorus, and algal biomass.
     Figure 4-4 shows the key results for the model simulations for dissolved
oxygen simulated at the worst-case critical oxygen sag location along the length
 (a)
  OJ
  O)
  >
  X
 O
 •o
 _
 o
 (A
 in
      Delaware Estuary Model
   July 1976 conditions, river mile 96
                 5.0 mg/L (benchmark for defining
                 desirable vs. undesirable levels of DO
03)              Potomac Estuary Model
         September 1983 conditions, river mile 105
                                                         10-1
 (c)
 Primary       Secondary      >Secondary
      Municipal Effluent Scenario

       James Estuary Model
September 1983 conditions, river mile 90
(d)
Primary        Secondary      >Secondary
     Municipal Effluent Scenario

     Upper Mississippi Model
 August 1988 conditions,  river mile 830
           Primary        Secondary      >Secondary
                Municipal Effluent Scenario
                                                      Primary       Secondary      >Secondary
                                                           Municipal Effluent Scenario
Figure 4-4. Model simulation of DO under summer "dry" streamflow conditions at the critical oxygen sag location for
primary, secondary and better-than-secondary effluent scenarios for case studies of (a) Delaware estuary,
(b) Potomac estuary, (c) James estuary, and (d) Upper Mississippi River. Sources: Clark et a/., 1978; Fitzpatrick et a/,,
1991; HydroQual, 1986; Lung, 1998; Lung and Larson,  1995; Lung and Testerman, 1989.
                                                                                                    4-9

-------
Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
      Conclusion of
        of the stool
                         of each river. As shown in these results, the primary effluent scenario results in
                         extremely poor conditions with DO levels of less than 1 mg/L for the Potomac,
                         James, and Upper Mississippi cases and 2 mg/L for the Delaware. The model
                         results for the primary scenario of severe oxygen depletion are, in fact, consistent
                         with historical oxygen data recorded for these rivers during the 1960s. Simulating
                         an upgrade to secondary treatment,  as mandated by the 1972 CWA for municipal
                         facilities, DO conditions are improved but are still less than the benchmark
                         concentration of 5 mg/L often used  to describe compliance with water quality
                         standards. As demonstrated with the models, and actually achieved, better-than-
                         secondary levels of municipal treatment are needed to exceed a benchmark of 5
                         mg/L for DO. In contrast to the poor water quality  conditions common in these
                         rivers during the 1960s, the occurrence of low DO levels has been effectively
                         eliminated, even under severe drought conditions, as a result of upgrades beyond
                         primary treatment to better-than-secondary levels  of waste treatment.


                         E.  Discussion and  Conclusions

                              In  developing a methodology  to evaluate the effectiveness of USEPA's
                         Construction Grants Program, GAO (1986b) posed four questions to evaluate the
                         water quality benefits obtained from upgrading municipal wastewater treatment
                         facilities:
    Tremendous progress
    has been achieved In
   improving water quality,
      restoring valuable
    biological resources,
   ami creating recreational
      opportunities In all
    the case study areas!
      1. Did upgrading the POTW decrease the amount of pollutants dis-
        charged?
      2. Did water quality improve downstream from the POTW?
      3. Is there a relationship between changes in a plant's effluent and
        changes in stream water-quality indicators?
      4. Can other reasonable explanations of a stream's water quality be
        excluded?
          Although many of the case studies in this report (Chapters 5 through
      13) include a mix of multiple municipal and industrial wastewater dis-
      charges and might not be applicable to the methodology developed by GAO
      (1986b), the dramatic improvements that have been documented  for
      effluent loading, water quality, environmental resources, and recreational
      uses clearly suggest that the answer to the questions raised by GAO
      (1986b) for all nine case studies is an overwhelming "yes."
          In addition to the case study questions posed by GAO, the national
      policy questions raised by Congress and the public can be modified slightly
      to use for evaluations of the case study waterways: Has water quality
      improved as  a  result of public and private capital improvement expen-
      ditures for water pollution control? Has the waterbody achieved the
      "fishable  and swimmable" goals set forth  in the CWA ?  Has the CWA
      worked?
     For all the case study waterways, tremendous progress has been made in
improving water quality, restoring valuable biological resources, and creating
thriving water-based recreational uses of the waterways that contribute to the
local economies. Although significant progress has been achieved in eliminating
noxious water pollution conditions, nutrient enrichment, and sediment contamina-
4-10

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                                                   Chapter 4:  Case Study Assessments of Water Quality
tion, heavy metals and toxic organic chemicals continue to pose threats to human
health and aquatic organisms. Serious ecological problems remain to be solved for
many of the Nation's waterways, including the case study sites. The evidence is
overwhelming, however, that the national water pollution control policy decisions
of the 1972 CWA have achieved significant successes in many waterways. With
the new watershed-based strategies for managing pollutant loading from point and
nonpoint sources detailed in USEPA's Clean Water Action Plan (USEPA,  1998),
the Nation's state-local-private partnerships will continue to work to attain the
original "fishable and swimmable" goals of the 1972 CWA for all surface waters
of the United States.
                                                                                              4-11

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
                         References

                         ASIWPCA. 1984. America's clean water:  The stares evaluation of progress
                             1972-1982. Association of State and Interstate Water Pollution Control
                             Administrators, Washington, DC.
                         Becker, C.D., and D.A. Neitzel, eds. 1992.  Water quality in North American
                             river systems. Battelle Press, Columbus, OH.
                         Brown, B.J., and J.H. Olive. 1995. Diatom communities in the Cuyahoga River
                             (USA): Changes in species composition between 1974 and 1992 following
                             renovations in wastewater management. Ohio Journal of Science 95(3):
                             254-260.
                         Burns, N. M. 1985. Erie, the lake that survived.  Rowman & Allanheld Publishers,
                             Div. of Littlefield, Adams & Co., Totowa, NJ.
                         Charlton, M.N. S. L'ltalien, E.S. Millard, R.W.  Bachmann, J.R. Jones, R.H.
                             Peters, and D.M. Soballe, eds.,  1995. Recent changes in Lake Erie water
                             quality. Annual International Symposium of the North American Lake
                             Management Society, Toronto, Ontario, Canada, 6-11 November 1995. Lake
                             Reservoir Management 11(2): 125.
                         Clark, L.J., R.B. Ambrose, and R.C. Grain. 1978. A  water quality modelling
                             study of the Delaware Estuary. Technical  Report 62. USEPA Region 3,
                             Annapolis Field Office, Annapolis, MD.
                         Crawford, C.G., and D.J. Wangness. 1991.  Effects of advanced wastewater
                             treatment on the quality of White River, Indiana. Water Resources Bulletin
                             27(5): 769-779.
                         Desbonnet, A., and V. Lee. 1991. Historical trends: Water  quality and fisher-
                             ies in Narragansett Bay. Rhode Island Sea Grant, University of Rhode
                             Island, Narragansett, RI, and U.S.  Department of Commerce, National
                             Oceanic and Atmospheric Administration, Coastal Ocean Office, National
                             Ocean Pollution Program, Rockville, MD.
                         Edmondson, W.T. 1991. The uses of ecology,  Lake Washington, and beyond.
                             University of Washington Press, Seattle, WA.
                         EESI. 1995. The Houston Ship Channel: An environmental success story?
                             Proceedings of workshop, May 18-19, 1995, Energy & Environmental
                             Systems Institute, Rice University, Houston, TX. Publ. No. EESi-01.
                         Fitzpatrick, J.P., et al. 1991. Calibration and verification of an updated
                             mathematical model of the eutrophication of the Potomac estuary.
                             Prepared by HydroQual, Inc.,  for Metropolitan Washington Council of
                             Governments, Washington, DC.
                         Forstall, R.L. 1995. Population by counties by decennial census: 1900 to  1990.
                             U.S. Bureau of the Census, Population  Division, Washington, DC.
                             .
                         Frost, J. 1991. MWCC St. Paul Metro population served, plant effluent flow and
                             BOD5loading data, 1940 to 1990. Personal communication, Minnesota
                             Pollution Control Agency, St. Paul, MN.
                         GAO.  1986a.  The nation's water: Key unanswered questions about the
                             quality of rivers and streams. GAO/PMED-86-6. U.S. General Accounting
                             Office, Program, Evaluation and Methodology Division, Washington, DC.
4-12

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                                                  Chapter 4:  Case Study Assessments of Water Quality
GAO. 1986b.  Water quality: An evaluation method for the Construction
     Grants Program—methodology. Report to the Administrator, U.S. Environ-
     mental Protection Agency. Vol. 1, GAO/PMED-87-4A. U.S. General
     Accounting Office, Program, Evaluation and Methodology Division, Wash-
     ington, DC.
Gleason, G.W.  1972. The return of a river,  the Willamette River, Oregon.
     Oregon State University, Corvallis, OR.
Hayden, D.F.G., J.L. Peter, W.C. Peterson, and D.A. Ball. 1994. Valuation of
     non-market goods: A methodology for public policy; making a social fabric
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     Boise State University, College of Business, Boise, Idaho.
Hun, T. 1999. Cuyahoga no longer burns. Water Environment & Technology
     11(6): 31-33.
HydroQual, Inc. 1986. Water quality analysis of the James and Appomattox
     Rivers. Report prepared for Richmond Regional Planning District Commis-
     sion, June 1986.
Isaac, R.A. 1991. POTW improvements raise water quality. Water Environment
     and Technology June: 69-72.
Jaworski, N.A. 1990. Retrospective study of the water quality issues of the
     Upper Potomac estuary. Reviews in Aquatic Science 3(2): 11-40.
Jobin, W. 1998. Sustainable management for dams and waters. Lewis Publish-
     ers, Washington, DC.
Koonce, J.F., W.D.N. Busch, and T. Czapla.  1996. Restoration of Lake Erie:
     Contribution of water quality and natural resource management. Can. J.
     Fish. Aquat. Sci. 53  (Supplement 1): 105-112.
Krieger, K.A., D.W.  Schloesser, B.A. Manny, C.E. Trisler, S.E. Heady, J.J.H.
     Ciborowski, and K.M. Muth. 1996. Recovery of burrowing mayflies
     (Ephemeroptera: Ephemeridae: Hexagenia) in western Lake Erie. J. Great
     Lakes Research 22(2): 254-263.
Larsen, C.E. 1999. Metropolitan Council Environmental Services, St. Paul,
     Minnesota. Personal communication, March 12, 1999.
Leo, W.M, R.V. Thomann and T.W. Gallagher. 1984. Before and after case
     studies: Comparisons of water quality following municipal treatment
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     Agency, Office  of Water, Program Operations, Washington, DC.
Lung, W.S.  1998. Trends in BOD/DO modeling for waste load allocations. ASCE
     J. Environ. Eng. 124(10):  1004-1007.
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     River and Lake Pepin. ASCE J. Environ. Eng. 121(10): 691-699.
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     the James estuary. J. Envir. Eng., ASCE 115(5): 978-991.
Makarewicz, J.C., and P. Bertram. 1991. Evidence for the restoration of the Lake
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     issues in the Washington metropolitan area. Annual  report. Metropolitan
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                                                                                            4-13

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
                         NCWQ.  1976. Public Law 92-500. Water quality analysis and environmental
                              impact assessment: Technical report. NTIS No. PB252298. National
                              Commission on Water Quality, Washington, DC.
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                              East Carolina University, Greenville, NC.
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                              Environmental Protection Agency, Office of Water, Office of Municipal
                              Pollution Control, Washington, DC. April.
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                              America's waters. Vice President Al Gore's Clean Water Act remarks on
                              the 25th Anniversary of the CWA. U.S. Environmental Protection Agency,
                              Washington, DC.
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                                                   Chapter 4: Case Study Assessments of Water Quality
USEPA.  1998. Clean water action plan: Restoring and protecting America's
     waters. U.S. Environmental Protection Agency, Office of Water, Washing-
     ton, DC.
USGS, 1999. Streamflow data downloaded from the United States Geological
     Survey's National Water Information System (NWIS)-W. Data retrieval for
     historical streamflow daily values, .
WEF. 1997. Profiles in  water quality: Clear success, continued challenge.
     Water Environment Federation, Alexandria, VA.
Zogorski, J.S., S.F. Blanchard, R.D. Randal and F.A. Fitzpatrick. 1990. Availabil-
     ity and suitability of municipal wastewater information for use in a
     national water-quality assessment: A  case study of the Upper Illinois
     River Basin in Illinois, Indiana and Wisconsin. Open File Report 90-375.
     U.S. Geological Survey, Urbana, IL.
Zwick, D., and M.  Benstock. 1971. Water wasteland. Ralph Nader's Study
     Group Report on Water Pollution. Grossman Publishers, New York, NY.
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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
4-16

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    Chapter  5
Connecticut River
Case  Study
      The New England Basin (Hydrologic Region 1),
      covering a drainage area of 64,071 square
      miles from Maine to southwestern Connecticut,
includes some of the major rivers in the continental United
States. The Connecticut River, the largest river in New
England, originates from a series of small lakes just south of
the Canadian border and flows 400 miles south over a
drainage area of 11,250 square miles through Vermont,
New Hampshire, Massachusetts, and Connecticut to Long
Island Sound (Figure 5-1). An estimated 1.1 million people
lived in the Lower Connecticut River basin in 1996.
Densely populated urban centers border the river from
Springfield, Massachusetts, downstream to Middletown,
Connecticut. The major urban centers along the river are
Holyoke-Chicopee-Springfield, Massachusetts, and Hartford,
Connecticut. A diverse mix of manufacturing, trade, finance,
agriculture, recreation, and tourism forms the economic base of the
basin.
    Figure 5-2 highlights the location of the Lower Connecticut River
case study watersheds (catalog units) identified in this major river basin
as a major urban-industrial area affected by severe water pollution
problems during the 1950s and 1960s (see Table 4-2). In this chapter,
information is presented to characterize long-term trends in population,
municipal wastewater infrastructure and effluent loading of pollutants, ambient
water quality, environmental resources, and uses of the Lower Connecticut River.
Data sources include USEPA's national water quality database (STORET),
published technical literature, and unpublished technical reports ("grey" literature)
obtained from local agency sources.


Background

    Although the Connecticut River has been characterized as one of the
Nation's most scenic rivers, the river was so grossly polluted in the 1960s that it
was classified as suitable only for transportation of sewage and industrial wastes.
The deplorable condition of the river discouraged development along the water-
front and adjacent shorelands over long reaches of the lower river. In recent
     Connecticut
     River Basin
     Hydrologic
     Region 1
Figure 5-1
Hydrologic Region 1  and
the Connecticut River
Basin.
                                                                                    5-1

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
Figure 5-2
Location map for Lower
Connecticut River Basin.
(River miles shown are
distances from Long
Island Sound.)
                                                73
                         years, amazing improvements in the river's water quality have resulted in the
                         Lower Connecticut River's becoming a popular place for boating and recreation.
                         Perhaps most telling of all, the shorelines of the Connecticut River are now under
                         the new threat of suburban development. The historic turnaround in the quality of
                         the river can be correlated with the enactment of the 1972 CWA, which resulted
                         in the construction and upgrading of wastewater treatment plants along the length
                         of the river, including three major treatment plants serving the Hartford area.


                         Physical  Setting  and  Hydrology

                              The Connecticut River forms the border between Vermont and New
                         Hampshire and bisects west-central Massachusetts and central  Connecticut. The
                         topography of the Connecticut River's 11,250-square-mile watershed varies from
                         the rugged terrain of the White Mountains in New Hampshire and the rounded
                         hills and mountains in Vermont and Massachusetts to the lowlands of the flood-
                         plains along the river's banks in Massachusetts and Connecticut. Rising in the
                         semimountainous area of northern New Hampshire, the Connecticut River drops
                         more than half of its 2,650 feet in elevation in the first 30 miles of its course. The
                         river is tidally influenced from Hartford to Long Island Sound (Figure 5-2).
5-2

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                                                              Chapter 5: Connecticut River Case Study
                                                                            Figure 5-3
                                                                            Monthly trends of mean,
                                                                            10th, and 90th percentile
                                                                            streamflow for the
                                                                            Connecticut River at
                                                                            Thompsonville, CT (USGS
                                                                            Gage 01184000), 1951-
                                                                            1980.
                                                                            Source: USGS, 1999.
                    ONDJFMAMJJAS
     Long-term trends in summer streamflow from the USGS gage at
Thompsonville, Connecticut, shown in Figure 5-3, illustrate the interannual vari-
ability of discharge during the critical summer months. Seasonal flow conditions
reflect the long, cold winters and the relatively short summers characteristic of
New England. High flows are generally experienced in the spring (March-May),
corresponding to large snowmelt events (Figure 5-4). Low flows occur during the
summer months.  In the past, flow regulation for hydropower production at
Holyoke Dam (Massachusetts) periodically reduced flows in the Connecticut
River to a minimum of near zero, but minimum release requirements have been
established to maintain the  summer low flow at a higher level. Currently the flow
is regulated by a number of headwater lakes and reservoirs, as well as power
plants, with a combined usable capacity of 107 billion cubic feet (USGS, 1989) at
Thompsonville, Connecticut. The 7-day, 10-year low flow (7Q10) discharge at
Thompsonville is 2,200 cubic feet per second (cfs). The minimum recorded daily
discharge was 519 cfs on September 30, 1984, below the Holyoke Dam and 968
cfs on October 30, 1963, at Thompsonville, Connecticut (USGS,  1989).
           40
                     1950
1960
1970
1980
1990
                                                               0.0
                                                                            Figure 5-4
                                                                            Long-term trends in mean,
                                                                            10th, and 90th percentile
                                                                            streamflow in summer
                                                                            (July-September) for the
                                                                            Connecticut River at
                                                                            Thompsonville, CT (USGS
                                                                            Gage 01184000).
                                                                            Source: USGS,  1999.
                 - - • 90%ile
                  mean & ratio
                                                                                               5-3

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Progress in Water Quality: An Evaluation of the National Investment In Municipal Wastewater Treatment
                         Population,  Water,  and Land  Use  Trends

                              The population density in the Connecticut River Basin generally increases
                         from the north to the south. Approximately 85 percent of the river basin's resi-
                         dents live in Massachusetts and Connecticut. Approximately 1.1 million people
                         live in Connecticut municipalities adjacent to the river; the largest city, Hartford,
                         had a 1990 estimated population of 139,739 (CSDC, 1991).
                              The Connecticut River case study area includes a number of counties
                         identified by the Office of Management and Budget (OMB, 1999) as Metropoli-
                         tan Statistical Areas (MSAs) or Primary Metropolitan Statistical Areas (PMSAs).
                         The Hartford, Connecticut, MSA and three Connecticut counties, Fairfield,
                         Middlesex, and Tolland, are included in this case study. Figure 5-5 presents long-
                         term population trends  (1940-1996) for the three counties. From 1940 to 1996, the
                         population in the Connecticut River case study area about doubled (Forstall, 1995;
                         USDOC, 1998).
                              The first European settlements in the Connecticut River Basin were cen-
                         tered around Hartford in the 1630s. During the initial 100 years of development,
                         the water and lands of the Connecticut River Valley provided a transportation
                         route to the interior, as  well as food and vast quantities of timber for shelter and
                         fuel. Timber  exploitation from 1700 to 1850 removed about three-fourths of the
                         basin's forest cover. Following the timber-cutting era, cleared land was used for
                         raising sheep and goats. The farm economy dwindled by the 1850s, and the land
                         began to revert back to its forested condition.
                              The upper basin in New Hampshire and Vermont has retained a more rural
                         character, although suburbanization is replacing traditional farm areas in some
                         locations as the small northern towns expand. The 52-mile-long tidal section of the
                         river in Connecticut between Long Island Sound and Hartford has traditionally
                         supported shipbuilding and has been used as a major route for waterborne  com-
                         merce, mostly petroleum products. Land use in this lower basin includes large-
                         scale industrial and commercial development in Hartford. In the past, major
Figure 5-5
Long-term trends in
population in the Lower
Connecticut River Basin.
Sources: Forstall, 1995;
USDOC, 1998.
                                   O.i
                                           1940   1950   1960   1970  1980   1990   1996
5-4

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                                                              Chapter 5: Connecticut River Case Study
industries in the Hartford area included woolen mills, paper mills, and machine tool
factories. In recent decades, the economy of the lower basin has shifted from
manufacturing toward a service economy. Hartford has been deemed "the
insurance capital of the world." Beginning with the Hartford Fire Insurance
Company in 1794, insurance has become a multibillion-dollar industry.
     The Connecticut River is not currently used as a public water supply in the
state of Connecticut. Most of the Connecticut River water used by agriculture in
the Connecticut River Valley is used to irrigate tobacco, vegetable crops, fruits,
and nursery stock. In  1980 approximately 11,500 acres of the 33,922 acres of
harvested cropland in Hartford County were irrigated with water from the
Connecticut River or Farmington River (a major tributary just north of Hartford)
(USACE, 1981).


Historical Water Quality  Issues

     Water quality problems in the Hartford area of the Connecticut River date
back to the  late 1800s. In July  1914, the level of DO in the Connecticut River
near Hartford was 2 to 3 mg/L lower than levels during the late 1980s (7.4 to 7.9
mg/L in 1988) (CTDEP, 1982,  1988). Early in the river's history, the construction
of dams for hydropower had significantly exacerbated water quality problems due
to stagnation and the creation of faunal barriers. By 1872, Atlantic salmon had
been completely exterminated from the river system because of poor water
quality as well  as the construction of physical barriers that prohibited the migration
of anadromous fish (Center for Environment and Man, 1975).
     In 1955, the New England Interstate Water Pollution Control Commission
classified the Connecticut River from Holyoke Dam in Massachusetts to
Middletown, Connecticut, as a Class D waterway suitable for "transportation of
sewage and industrial wastes without nuisance and for power, navigation, and
certain industrial uses" (Kittrell, 1963). Severe water pollution problems in this
reach of the Connecticut River have resulted from two sources, industrial effluent
and municipal sewage disposal. One of the major industries responsible for
degradation of water quality has been paper  mills. Before the late 1970s, paper
mills in the  Massachusetts segment of the river discharged effluent with high
concentrations  of BOD5 and suspended solids into the river (Center for Environ-
ment and Man, 1975). Downstream of the paper mills in Holyoke, Massachusetts,
it was reported that the river flowed different colors depending on the dye lot
used at the paper mill that day.
     In 1963 it was reported that in the stretch of river from central Massachu-
setts to south of Hartford, Connecticut, 9 of the 22 jurisdictions responsible for
discharge of sewage provided no wastewater treatment. Twelve of the 22
provided only primary treatment, and 1 provided secondary treatment (Kittrell,
1963). Large discharges of municipal and industrial wastes caused a steady
depletion of DO downstream of the Holyoke Dam in Massachusetts. Minimum
DO levels reached nearly zero  during a low flow survey in 1966, and DO levels
of less than  2 mg/L were recorded in 1971. Connecticut River data collected in
the summer of 1971 documented other forms of pollution with a minimum density
of coliform bacteria of 75,000 colonies/100 mL and a maximum of over 1 million
colonies/100 mL (Center for Environment and Man, 1975).
                                                                                              5-5

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment


                        Legislative and Regulatory History

                             On the basis of reports indicating that pollution in this reach of the Connecti-
                        cut River was endangering the health and welfare of persons in Connecticut, the
                        Secretary of Health, Education and Welfare convened a conference under
                        Section 8 of the Federal Water Pollution Control Act (33 U.S.C. 466g et seq.) in
                        1963 to investigate the pollution of the Connecticut River in Massachusetts and
                        Connecticut. This conference documented the appalling water quality of the
                        Connecticut River and initiated strategies to begin to clean up the river (Kittrell,
                        1963). By the early 1960s, the steadily increasing public concern regarding water
                        pollution issues resulted in organized planning for implementation of primary and
                        secondary wastewater treatment in several municipalities including Hartford,
                        Connecticut.
                             Since 1963 USEPA's Construction Grants Program has been responsible for
                        elimination of vast amounts of untreated or partially treated wastewater entering
                        the Connecticut River. The process of reducing the loadings and substantially
                        improving the quality of the Connecticut River was significantly influenced by the
                        1972 CWA. Subsequent to the enactment of this legislation, 125  new or upgraded
                        treatment plants were constructed along the Connecticut River at a cost of nearly
                        $900 million (Conniff, 1990). From 1972 through 1984 eligible projects were
                        funded 75 percent by federal grants, 15 percent by state grants, and 10 percent by
                        local financing; prior to 1972 the federal share was 55  percent (CTDEP, 1982).
                        Three secondary wastewater treatment plants in the Hartford area (Hartford,
                        East Hartford, and Rocky Hill) were completed by the mid-1970s (Gilbert, 1991).
                             One of the major problems still facing this important New England water-
                        way, however, is combined sewer overflows (CSOs). Overflows during storm
                        events can still cause discharge of untreated sewage into the Connecticut River
                        between Springfield, Massachusetts, and Middletown, Connecticut. CSO prob-
                        lems are the principal reason the Connecticut River does not consistently meet the
                        Class B fishable/swimmable standard for fecal coliform in northern Connecticut
                        (above Middletown) (Mauger, 1991).


                        Impact of Wastewater  Treatment:

                        Pollutant Loading  and Water Quality

                        Trends

                             As a result of implementation of municipal and industrial wastewater
                        treatment in the Connecticut River Basin,  total pollutant loading has decreased
                        substantially in the past 30 to 40 years. The approximate total population served
                        by the 22 sewer systems in the Connecticut and Massachusetts portions of the
                        river basin in 1963 was 734,265 people; of these, 282,590 (38 percent) resided in
                        East Hartford and Hartford, Connecticut (Kittrell, 1963). In 1990 the sewered
                        population of the greater Hartford metropolitan area was 366,574, served by the
                        Hartford, East Hartford, and Rocky Hill facilities. The largest of these, the
                        Hartford water pollution control plant, currently has secondary treatment with
                        upgrades from 60 mgd to 80 mgd by  1993 (Gilbert, 1991).
5-6

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                                                                Chapter 5:  Connecticut River Case Study
     Since implementation of the 1972 CWA, substantial reductions in point
source loads of oxidizable materials have been achieved as a result of technology-
and water quality-based effluent controls on municipal and industrial dischargers
in the Connecticut River watershed. Nonpoint source runoff, driven by the land
uses and hydrologic characteristics of the watershed, also  contributes a pollutant
load to the Connecticut River that must be considered in a complete evaluation of
the impact of regulatory policy and controls on long-term water quality trends. To
evaluate the relative significance of point and nonpoint source pollutant loads,
inventories of NPDES point source dischargers, land uses, and land use-depen-
dent export coefficients (Bondelid et al., 1999) have been used to estimate catalog
unit-based point (municipal, industrial, CSOs) source and nonpoint (rural, urban1)
source loads of BOD5 for contemporary (ca. 1995) conditions in the case study
area (Figure 5-6). Municipal facilities contribute 42 percent (10.5 metric tons/day)
of the total estimated BOD5 load, while industrial dischargers account for 10
percent (2.4 metric tons/day) of the total BOD5 load. Nonpoint sources  of BOD5
account for a total of 47 percent, with rural runoff contributing 13 percent (3.3
metric tons/day) and urban land uses accounting for 34 percent (8.5 metric tons/
day) of the total load (Figure 5-6).
     Oxygen depletion and high BOD5 levels historically have been documented
downstream from the major wastewater discharges in the Massachusetts and
Connecticut segments of the river. Prior to upgrading publicly owned treatment
works (POTWs) in the southern Massachusetts sections of the river, water
quality monitoring data near the Connecticut/Massachusetts border documented
that DO concentrations in the river violated the Massachusetts state standard (5
mg/L for non-low-flow periods) 22 percent of the days recorded in the early
1970s (June-October) (Isaac, 1991). Minimum recorded DO levels  reached
nearly 0 mg/L in a 1966 survey and less than 2.0 mg/L in 1971 (NCWQ, 1975) in
Massachusetts.  After POTW upgrades, by 1974 violations had dropped to only 6
percent of the days of record with DO less than 5 mg/L (Isaac, 1991) (Figure 5-
7).
         RURAL-NPS
         URBAN-NPS
              CSO
        IND.MAJ+MIN
         MUNICIPAL
                 Figure 5-6
                 Comparison of point and
                 nonpoint source loads of
                 BOD5(ca. 1995) for the
                 Lower Connecticut River
                 Basin.
                 Source: Bondelid et al.,
                 1999.
                                5              10
                              BODS Load (metric tons/day)
15
  1 For purposes of this comparison, urban stormwater runoff includes areas both outside (termed
   "nonpoint sources") and within (meeting the legal definition of a point source in section 502(14)
   of the CWA) the NPDES stormwater permit program.
                                                                                                  5-7

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
Figure 5-7
Trends in violations of DO
standard (DO < 5 mg/L) in
summer (July-September)
for the Connecticut River
before (1969-1973) and
after (1974-1980) con-
struction and upgrade of
municipal wastewater
treatment facilities at
Agwam, MA.
Source: Isaac, 1991.
I
&
75-
50-
25-
oH


6

27
:<
I
I

wi

1
i*

K)
=X
sS
^
%



12
1969 1970 1971 1972 1973
Before (1969-73)



0
1974







0


23
1







0



15
1975 1976 1977' 1978 1979 1980
After (1974-80)
: i
r tn
V
E a
1 1
ys Violatio
Q
^p
o^
rO%
                                              Days of Record
                                  % Days of Violation
                               The average summer DO concentrations in the Lower Connecticut River in
                          northern Connecticut (Hartford to Windsor) have also improved steadily since the
                          mid-1960s (Figure 5-8). Corresponding to the increase in DO shown has been a
                          progressive decline in ambient BOD5 that reflects upgrades to Hartford area
                          wastewater treatment facilities (Figure 5-9). Since the early 1970s, the average
                          summer (July to September) DO levels in the Lower Connecticut River from
                          Haddam to Middletown have remained above 7 mg/L (Figure 5-10). In a Septem-
                          ber 1988 intensive survey of water quality in the Lower Connecticut River, the
                          DO concentrations ranged from 7.3 to 7.9 mg/L for all 10 stations sampled from
                          the Massachusetts/Connecticut border to near the mouth of the river (CTDEP,
                          1988). The improvement in water quality in the Lower Connecticut River as a
                          result of the significant reductions in oxidizable pollutant loading over the past 30
                          years has been substantial.
Figure 5-8
Long-term trends in DO for
the Lower Connecticut
River from Hartford to
Windsor, CT (RF1-
01080205029, miles 50.3-
57.3).
Source: USEPA (STORET).
                                           Mean	Mm  	Max
    1940       1950       1960      1970       1980
                     Hartford-Windsor CT (Mile 50.3-57.3)
                                                                                       1990
5-8

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                                                          Chapter 5: Connecticut River Case Study
         1940
1950
1960      1970      1980
 Windsor-Rocky Hill CT
1990
                Mean	Mm  	Max
                                                                        Figure 5-9
                                                                        Long-term trends in BOD5
                                                                        in the Lower Connecticut
                                                                        River from Windsor to
                                                                        Rocky Hill, CT.
                                                                        Source: Reimold, 1991.
                                                     Figure 5-10
                                                     Long-term trends in DO
                                                     for the Lower Connecticut
                                                     River from Haddam to
                                                     Middletown, CT. (RF1-
                                                     01080205021, miles 16.3-
                                                     21.6).
                                                     Source: USEPA (STORET).
                                                      W
Impacts of Wastewater Treatment:

Recreation  and Living Resources  Trends

     Information on biotic populations in the Connecticut River is scarce for most
of the period previous to 1975 (Center for the Environment and Man, Inc., 1975).
The precolonial salmon population was very large and supplied Native Americans
and, later, early colonists with an abundant food supply. A long absence of
Atlantic salmon in the river was noted between 1874 and the late 1970s. An
Atlantic salmon caught in 1977 was the first documented occurrence of the fish in
the river since 1874 (USEPA, 1980).
     The absence of salmon can be attributed partially to dam construction,
which prevented the fish from migrating upstream to spawn, and partially to water
pollution. The first dam across the river was constructed in 1798 at Turners Falls,
Massachusetts (Jobin, 1998). Fish ladders were built around dams when people
began to understand that the dams prevented migration, yet 200,000 hatchery
salmon placed in the river between 1968 and the early 1970s failed to return to
the river to spawn, presumably because of the poor water quality (USEPA, 1980).
Efforts  to clean up the river began after passage of the 1972 CWA, and the return
of the salmon in the late 1970s can be attributed to improved water quality.
     Another anadromous fish species historically important to commercial and
recreational fishing on the Connecticut River is the American shad. Shad had a
precarious existence in the river before 1975 (Center for Environment and Man,
                                                                                         5-9

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
Figure 5-11
Long-term trends of shad
relative abundance for the
Lower Connecticut River.
Source: Savoy and Shake,
1991.
                                      1960
                                              1965
                                                      1970
                                                              1975
                                                                      1980
                                                                             1985
                                                                                     1990
                         Inc., 1975), but their population increased afterward (Figure 5-11). The estimated
                         mean population for the years 1975-1989 was 841,265 (Savoy, 1991). The 1990
                         estimated population was 654,885, lower than the previous 14-year mean but
                         considered by the Connecticut Department of Environmental Protection
                         (CTDEP) to be stable.
                              Other indices lead to the conclusion that the shad population is faring well in
                         the Connecticut River. The 1990 commercial catch of shad in the river
                         (x = 9687, adjusted for angler effort) was nearly twice the 1989 catch (x = 5243)
                         and reversed a general declining trend that lasted from 1986 to  1989 (Savoy,
                         1991). Similarly, juvenile shad had strong relative abundances from 1987 to 1990
                         (Figure 5-11), indicating good reproductive success (Savoy, 1991). Juvenile fish
                         are generally less tolerant than adults of low DO concentrations, so an improve-
                         ment in reproductive success is a good indicator of improving water quality.
                          Summary and  Conclusions

                              The federal, state, and local funding for construction of municipal wastewa-
                          ter treatment facilities in the Connecticut River Basin has led to significant
                          improvement in water quality since the 1960s. A river basin that during the early
                          1970s was considered a flowing sewer is now a popular recreational area. One
                          measure of the improvement in the fishable/swimmable quality of the river is
                          documented by the U.S. Fish and Wildlife Service. Dramatic improvements in
                          water quality, along with the installation offish ladders to eliminate physical
                          barriers to migration, have resulted in the successful return of Atlantic salmon to
                          the Connecticut River.
                              Concentrations of total nitrogen and total phosphorus in the Connecticut
                          River case study area since the CWA have followed the national trends—
                          phosphorus and ammonia-N have  decreased with associated increases in nitrate-
                          N and total-nitrogen, indicating that improved wastewater treatment has improved
                          water quality (Garabedian et al., 1998). In its report Water Quality in the Con-
                          necticut, Housatonic,  and Thames River Basins, Connecticut,  Massachusetts,
                          New Hampshire,  New  York,  and Vermont, 1992-95, the U.S. Geological Survey
                          concluded that increasing nitrate concentrations may contribute to eutrophication
                          in Long Island Sound.
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                                                             Chapter 5: Connecticut River Case Study
References

Bondelid, T., C. Griffiths, and G. Van Houten.  1999. A national water pollution
    control assessment model. Draft technical report prepared for U.S. Envi-
    ronmental Protection Agency, Office of Science and Technology, Washing-
    ton, DC, by Research Triangle Institute, Durham, NC.
Center for Environment and Man.  1975.  Environmental impact assessment.
    Water quality analysis.  Connecticut River.  Prepared for the National
    Commission on Water Quality, Washington, DC. Report No. NCWQ 75/51.
    National Technical Information Service No. PB-250 924. April.
Conniff, R. 1990. The transformation of a river from sewer to suburbs in 20
    years. Smithsonian 21(l):71-84.
CSDC.  1991.   1990 Census population by municipality. State of Connecticut
    Office of Policy and Management, Connecticut State Data Center, Hartford,
    CT.
CTDEP.  1982. The Connecticut River—worth the cost! Connecticut Depart-
    ment of Environmental Protection, Water Compliance Division.
CTDEP.  1988.  Connecticut River intensive survey, September 7-8, 1988.
    Connecticut Department of Environmental Protection, Water Compliance
    Division.
Forstall, R.L. 1995. Population by counties by decennial census: 1900 to 1990.
    U.S. Bureau of the Census, Population Division, Washington, DC. .
Garabedian, S.P., J.F. Coles, S.J. Grady, E.C.T. Trench, and M.J. Zimmerman.
    1998.  Water quality in the Connecticut, Housatonic,  and Thames River
    Basins,  Connecticut, Massachusetts, New Hampshire, New York, and
    Vermont, 1992-1995. U.S. Geological Survey Circular 1155. U.S. Geologi-
    cal Survey, Reston, VA.
Gilbert, P.  1991. Metropolitan District Commission, Hartford, CT.  Personal
    communication.
Isaac, R.A. 1991. POTW improvements raise water quality.  Water Environ-
    ment and Technology 3(6):69-72.
Jobin, W.R.  1998.  Sustainable management for dams and waters. CRC
    Press, Boca Raton, FL.
Kittrell, F.W.   1963.  Report to the conference in the matter of pollution of the
    interstate waters of the Connecticut River,  Massachusetts-Connecticut.
    U.S. Department of Health, Education and Welfare. December.
Mauger, A. 1991. Water Compliance Division, State of Connecticut Department
    of Environmental Protection, Hartford, CT. Personal communication.
NCWQ.  1975. Environmental impact assessment, water quality analysis -
    Connecticut River. National Commission on Water Quality, Washington,
    DC.
OMB.  1999. OMB Bulletin No. 99-04. Revised statistical definitions of Metro-
    politan Areas (MAs) and Guidance on uses of MA definitions. U.S. Census
    Bureau, Office of Management and Budget, Washington, DC. .
                                                                                            5-11

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment


                         Reimold, R.  1991. Metcalf & Eddy, Inc., Boston, MA. Personal communication.
                         Savoy, T.   1991.  Sturgeon status in Connecticut waters.  Completion Report.
                             Project No. AFC-18. State of Connecticut, Department of Environmental
                             Protection, Division of Marine Fisheries, Waterford, CT. June.
                         Savoy, T., and D. Shake.   1991.  Population dynamics studies of American
                             shad, Aloosa sapidissima in  the Connecticut River. U.S.  Department of
                             Commerce, National Oceanic and Atmospheric Administration, National
                             Marine Fisheries Service. June 30.
                         USAGE.  1981.  Water resources development in Connecticut 1981. U.S.
                             Army Corps of Engineers, New England Division, Waltham, MA.
                         USDOC.  1998.  Census of Population and Housing.   Prepared by U.S.
                             Department of Commerce, Economics and Statistics Administration, Bureau
                             of the Census - Population Division, Washington, DC.
                         USEPA.  1980.  National accomplishments in pollution control: 1970-1980.
                             Some case histories.  The Connecticut River: salmon are caught again.
                             U.S. Environmental Protection Agency, Office of Planning and Evaluation,
                             Program Evaluation Division. December.
                         USEPA (STORE!). STOrage and RETrieval Water Quality Information System.
                             U.S. Environmental Protection Agency, Office of Wetlands, Oceans,  and
                             Watersheds, Washington, DC.
                         USGS. 1989.  Water resources data, Connecticut water year 1988. USGS
                             Water-Data Report CT-88-1.  U.S. Geological Survey,  Hartford, CT.
                         USGS. 1999. Streamflow data downloaded from the U.S. Geological Survey's
                             National Water Information System (NWIS)-W Data retrieval for historical
                             streamflow daily values, .
5-12

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   Chapter  6
Hudson-Raritan
Estuary  Case
Study
     The Mid-Atlantic Basin (Hydrologic Region 2),
     covering a drainage area of 111,417 square
     miles, includes some of the major rivers in
the continental United States. Figure 6-1 highlights
the location of the basin and the Hudson-Raritan
Estuary, the case study watershed profiled in this
chapter.
    With a length of 306 miles and a drainage
area of 13,370 square miles, the Hudson River
ranks 71st among the 135 U.S. rivers that are more
than 100 miles in length. On the basis of mean annual
discharge (1941-1970), the Hudson ranks 26th (19,500 cfs) of
large rivers  in the United States (Iseri and Langbein, 1974). Urban-
industrial areas in the watershed caused severe water pollution
problems during the 1950s and 1960s (see Table 4-2). This chapter
presents long-term trends in population, municipal wastewater
infrastructure and effluent loading of pollutants, ambient water quality,
environmental resources, and uses of the Hudson-Raritan Estuary. Data
sources include USEPA's national water quality database (STORET), published
technical literature, and unpublished technical reports ("grey" literature) obtained
from local agency sources.
       Hudson-
        Raritan
        Estuary
Background
Figure 6-1
Hydrologic Region 2 and
Hudson-Raritan estuary
watershed.
    The Hudson-Raritan Estuary, with its rich and diverse populations of birds,
fish, and shellfish, is unmatched in terms of the historical abundance of its natural
resources. New York City, in fact, owes its existence as a major urban center to
the bounty of the estuary (Trust for Public Lands, 1990). The estuarine and
                                                                          6-1

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
                         coastal waters around New York City support significant fish and wildlife re-
                         sources (Sullivan, 1991). For example, the extensive wetland systems along the
                         Arthur Kill on northwest Staten Island, adjacent to one of the most industrialized
                         corridors in the northeastern United States, has recently been colonized by several
                         species of herons, egrets, and ibises (Trust for Public Lands, 1990). Current heron
                         populations represent up to 25 percent of all nesting wading birds along the coast
                         from Cape May, New Jersey, to the Rhode Island line (HEP, 1996). Today,
                         despite mounting pressures for industrial and residential development, there is a
                         growing awareness of the estuary's unique ecological function and a new appre-
                         ciation of its almost limitless potential as a recreational, cultural, and aesthetic
                         resource (Trust for Public Lands, 1990).
                              For more than 300 years, New York  Harbor and the New York metropolitan
                         region have been a focal point of urban development, transportation, manufactur-
                         ing, and commerce. New York City has been characterized by tremendous
                         population increases and economic growth and has traditionally been a  major
                         Harbor. As a large estuary with vast wetlands  and marsh areas, New York
                         harbor offered an abundance of natural resources that supported a commercially
                         important shellfish industry until its decline in the early 1900s. With a relatively
                         deep protected estuary that was ideal for navigation, the harbor developed as a
                         key shipping and transportation link for commerce and passenger traffic between
                         the inland states and Europe.


                         Physical  Setting and  Hydrology

                              New York Harbor is  formed by a network of interconnected tidal water-
                         ways along the shores  of New York and northern New Jersey; it is bounded by
                         the Hudson River to the north, Long Island Sound to the east, and the Atlantic
                         Ocean to the south  (Figure 6-2). Freshwater tributaries discharging into the
                         estuary drain an area of 16,290 square miles and contribute approximately 81
                         percent of the total freshwater inflow to the harbor. The remainder of  the  fresh-
                         water input is contributed  by wastewater (15 percent); urban runoff (4 percent);
                         CSOs (1 percent); and industrial discharges, landfill leachate, and precipitation
                         (0.5 percent) (Brosnan and O'Shea,  1996a).  Fresh water is also imported into the
                         New York City water supply system from the combined watershed areas of the
                         Delaware and Catskills mountains with eventual discharge via the wastewater
                         drainage system into the harbor.
                               Seasonal and  interannual variation of streamflow of the Hudson River
                         recorded at Green Island, New York, near Troy (USGS gage 01358000) is
                         characterized by high flow during March through May, with the monthly mean
                         peak flow of 32,719 cfs observed in April  (Figures 6-3 and 6-4). Fligh spring
                         flows result from spring snowmelt and runoff over the mountainous drainage
                         basin. Low-flow conditions occur during July through September, with the mean
                         monthly minimum  of 5,797 cfs observed during August. In dramatic contrast to
                         the long-term (1951-80) summer (July-September) mean of 6,396 cfs, during the
                         extreme drought conditions of 1962-1966, mean summer flow was only 49 to 70
                         percent of the long-term mean summer flow. The driest conditions occurred
                         during the summer of 1964 with a mean flow of 3,104 cfs and a minimum  flow of
                         only  1,010 cfs (Bowman and Wunderlich, 1977; O'Connor et al., 1977). Inspec-
6-2

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                                                     Chapter 6: Hudson-Raritan Estuary Case Study
                       74°30'
73°45'
40°30'~
                                                     14 Miles
                                                             40°30'
                                                                          Figure 6-2
                                                                          Location map of the
                                                                          Hudson-Raritan Estuary.
                                                                          (River miles shown are
                                                                          distances from  Sandy
                                                                          Hook-Rockaway transect
                                                                          of Atlantic Ocean.)
                       74°30'
                                                 73°45'
                                                                          Figure 6-3
                                                                          Monthly trends of mean,
                                                                          10th, and 90th percentile
                                                                          streamflow for the Hudson
                                                                          River at Green Island, NY
                                                                          (USGS Gage 01358000),
                                                                          1951-1980.
                                                                          Source: USGS, 1999.
          ONDJ   FMAMJ   JAS
                                                                                              6-3

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
Figure 6-4
Long-term trends in mean,
10th, and 90th percentile
streamflow in summer
(July-September) for the
Hudson River at Green
Island, NY (USGS Gage
01358000).
Source: USGS,  1999.
                                25
                                 5-	c
                                 ?940     1950      1960
1970
1980
1990
                                          90%ile
          mean & ratio
                         tion of the long-term trend data (1947-1995) for summer streamflow clearly
                         shows the persistent drought conditions of the 1960s, as well as the high-flow
                         conditions recorded a decade later (Figure 6-4).


                         Population,  Water, and  Land  Use Trends

                             In 1628 New York City was a small village of 270 settlers; today it is an
                         urban metropolis of 16 million (Figure 6-5). The physical environment of the New
                         York region has contributed greatly to its enormous growth and economic devel-
                         opment. The natural port of the harbor has made commerce and shipping a major
                         component of the economy since the colonial era. The Watchung and Ramapo
                         mountains, west and northwest of the city, also focused growth around the harbor
                         by constraining transportation routes and land development patterns. In 1810 New
                         York emerged as the largest city in the new nation, surpassing Boston and
Figure 6-5
Long-term trends in
population for the New
York-Northern New Jersey-
Long Island CMSA
counties for the Hudson-
Rantan Estuary
metropolitan region.
Source: Forstall, 1995;
USDOC, 1998.
                                          1940   1950   1960  1970  1980  1990   1996
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                                                          Chapter 6: Hudson-Raritan Estuary Case Study
Philadelphia. New transportation routes—the Erie Canal in 1825 and railroad
connections between New York and Philadelphia in 1839—strengthened the city's
link to Europe and the Nation's interior. During the massive European immigration
period of the mid-1800s to the early 1900s, immigrants to the United States
passed through Ellis Island in New York Harbor, a main port of entry. Many
chose to remain and contribute to the growth of the city.
     The Hudson-Raritan Estuary case study area includes a number of counties
identified by the Office of Management and Budget (OMB) as Metropolitan
Statistical Areas (MSAs) or Primary Metropolitan Statistical Areas (PMSAs).
Table 6-1 lists the MSA and counties included in this case study. Figure 6-5
presents long-term population trends (1940-1996) for the counties listed in Table
6-1. From 1940 to 1996, the population in the Hudson-Raritan Estuary case study
area increased by 34 percent from 12.6 million in 1940 to 17,0 million in 1996
(Forstall, 1995;USDOC, 1998).
     Because of the proximity to shipping and other transportation routes, manu-
facturing and industrial development evolved as a major component of the
region's industrial economy and a major contributor to the environmental decline
of the area's once bountiful wetlands. New Jersey, the most densely populated
state in the Nation, is second only to California in industrialization, and most of the
industrial activity of New Jersey is centered around New York Harbor. Within
New York City, economic growth has depended on manufacturing, services,
world trade, and the city's position as a national and international center for banks,
finance, culture, and the arts. Since the turn of the century, and particularly since
the development of the automobile and highways,  progressive suburban develop-
ment radiating from the city has transformed the once agricultural region into a
densely populated metropolitan area. At a distance of about 60 miles from New
York City, however, farmland, rural lands, and low-density suburban towns still
characterize the outer fringes of the metropolitan region.
  Table 6-1. Metropolitan Statistical Area (MSA) counties in the Hudson-Raritan
  Estuary case study. Source: OMB, 1999.
           Fairfield County, CT
           Litchfield County, CT
           New Haven County, CT
           Bergen County, NJ
           Essex County, NJ
           Hudson  County, NJ
           Hunterdon County, NJ
           Middlesex County, NJ
           Monmouth County, NJ
           Morris County, NJ
           Ocean County, NJ
           Passaic County, NJ
           Somerset County, NJ
           Sussex County, NJ
Union County, NJ
Warren County, NJ
Bronx County, NY
Dutchess County, NY
Kings County, NY
New York County, NY
Orange County, NY
Putnam County, NY
Queens County, NY
Richmond County, NY
Rockland County, NY
Westchester County, NY
Pike County, PA
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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment


                              Despite intense development and the loss of wildlife habitat due to wetland
                         conversion, the New York/New Jersey Harbor and the New York Bight do
                         contain significant fish and wildlife resources. Water uses of the Hudson River
                         and New York Harbor include public water supply of the freshwater river up-
                         stream of Poughkeepsie, New York, municipal and industrial wastewater disposal,
                         commercial shipping and navigation, recreational boating, swimming, and commer-
                         cial and recreational fishing. Although commercial fishing was once a significant
                         component of the New York-New Jersey regional economy, the abundance of
                         commercially important fish and shellfish has declined considerably during the
                         past century.  The loss  of once abundant fishery resources has been attributed to
                         disease, overfishing, loss of habitat, and poor water quality conditions. Despite the
                         significant reductions in  fishery resources, commercial fishing of more than 60
                         species of seafood contributed approximately $500 million to the regional econo-
                         mies of New York and New Jersey during the mid-1990s (Schwartz and Porter,
                         1994). Recreational fishing in the New York Harbor, Long Island Sound, and New
                         York Bight is also quite important, accounting for more than $ 1 billion annually in
                         economic activity for New York and New Jersey during the mid-1990s (Schwartz
                         and Porter, 1994).


                         Historical Water Quality Issues

                              Waste disposal issues in New York did not emerge only recently. Contempo-
                         rary residents of the New York metropolitan  area would be surprised to learn that
                         public policy debates related to waste disposal and water pollution issues began
                         only a few decades after colonial settlers arrived in the New World. The early
                         settlers' practice of simply dumping pails of sewage and other refuse into the
                         harbor became such a problem that in 1680 the Governor ordered that a common
                         sewer be constructed in  Lower Manhattan. In 1683 the Common Council decreed
                         "that none doe cast any dung, drought,  dyrte or any  other thing to fill up or
                         annoy the mould or Dock  or the neighborhood near the same, under the
                         penalty of twenty skill"  (Gross, 1976). Construction of a sewer and wastewater
                         collection  system in New York City began in 1696, with many sewers in lower
                         and central Manhattan constructed two centuries later between 1830 and 1870
                         (O'Conner, 1990). Pollution problems existed, however, in both New York City
                         and Newark, New Jersey, because the harbor received untreated  wastewater
                         from the sewers.
                              In  1868 unsanitary conditions were described as "poisoning the water and
                         contaminating the air" (Suszkowski, 1990).  During the 1920s the overpowering
                         stench of hydrogen sulfide from polluted water in the Passaic River near Newark,
                         New Jersey,  forced excursion boat passengers to seek refuge in the cabins
                         (Cleary, 1978). During that period, all the regional New York and New Jersey
                         communities discharged raw sewage into  the harbor  "to conduct  by the cheap-
                         est route to  the nearest waterway, giving no  thought  whatever to its effect on
                         the waterway and on adjacent waters" (Franz, 1982).  In the  1920s New York
                         City discharged approximately 600 mgd of raw sewage into the harbor (Brosnan
                         andO'Shea, 1996a).
                              The earliest water  pollution surveys of New York Harbor began with the
                         formation  of the Metropolitan Sewerage Commission of New York in 1906. In a
                         1910 report on conditions of the harbor, the Commission stated that "Bathing in

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                                                         Chapter 6:  Hudson-Raritan Estuary Case Study
New York Harbor above the Narrows is dangerous to health, and the oyster
industry must soon be entirely given up." The Commission further noted that a
number of tributaries and tidal channels in the harbor "have become little else
than open sewers. Innumerable local nuisances exist along the waterfront of
New York and New Jersey where the sewage of the cities located about the
harbor is discharged . . .  ." Finally, the commission concluded that "the water
which flows in the main  channels of the harbor . .  . is more polluted than
considerations of public  health and welfare should allow'" (Suszkowski,
1990). As  with many other urban areas around the turn of the century, develop-
ment of a  combined drainage network for storm water and sewage collection
evolved to address public health problems resulting from inadequate methods of
waste disposal that created a nuisance in the streets and contaminated ground
water supplies (Fuhrman,  1984).
     With vast marshlands, embayments, and interconnecting tidal channels, New
York Harbor once supported abundant populations offish, shorebirds, and shellfish
that were important local food resources and essential to certain commercial
activities.  The progressive decline of the once thriving oyster industry provides an
important  ecological indicator of the trends in environmental quality of New York
Harbor. Commercially important oyster beds were harvested during the  1800s in
Raritan Bay, the Kill Van Kull, Jamaica Bay, and Newark Bay, and in the
Shrewsbury River. By the turn of the century, waste disposal from industries and
towns began to seriously affect the survival of seed beds. In addition to industrial
waste and  sewage discharges, dredging and disposal of dredge spoils, illegal
dumping of cellar dirt, street sweepings, and refuse all contributed to the demise
of this once valuable estuarine resource.
     Although a century of pollution, disruption of habitat, and mismanagement of
seed beds  all contributed to the decline of oyster abundance, bacterial contamina-
tion from  raw sewage disposal was the catalyst for the death of the commercial
oyster industry. As early as 1904, typhoid cases were linked to consumption of
contaminated oysters. By 1915, 80 percent of the city's 150 typhoid cases were
attributed  to contaminated oysters harvested from the harbor. In 1924 and 1925
another major outbreak occurred, even though many of the beds had been closed
in 1921 because of public health reasons (Franz,  1982). More than three decades
later, consumption of sewage-contaminated hard clams from Raritan Bay again
resulted in serious public health problems with an outbreak of infectious  hepatitis
in 1961.
     Oysters, however, were not the only natural resource to suffer serious
depletion of once-abundant stocks. In the closing decades of the 19th century,
pollution and habitat destruction had begun to seriously degrade water quality and
affect the  abundance of marine resources. A century-long record of commercial
fishery landings for New York and New Jersey clearly documents the adverse
impact of water pollution and habitat destruction on the rich natural resources of
the estuary (Esser, 1982). Combined landings of important estuarine and anadro-
mous  species such as shad, alewifc, striped bass, sturgeon, American oyster, hard
clam,  and  bay scallop have declined 90 percent over the past century from 58
million pounds in 1887 to 6.6 million pounds in 1996(McHughetal., 1990;
Wiseman,  1997) (Figure 6-6). In interpreting this long-term trend, it is important to
realize that even a century ago resource abundance was already considered
depleted in comparison to reports of abundance recorded through 1850.  Contem-
                                                                                                6-7

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
Figure 6-6
Long-term trend of
commercial landings of
major anadromous and
estuarine species in New
York Harbor.
Source: McHugh et al,,
1990; Wiseman,  1997.
                                     75
c
o
§,
"5
   50-
                                  *  25-
                                  o
                                     o
                                     1890 1900 1910  1920  1930  1940  1950 1960 1970 1980 1990  2000
              -t-
                            -t-
                                      -t-
                                           -t-
                                                     -t-
                          porary degradation of the resources of the estuary, marked by successive anthro-
                          pogenic assaults and incremental improvements in wastewater treatment, is
                          believed to have begun as early as 1870 (Carriker et al., 1982).
                               The connection between raw sewage disposal and the decline of the oyster
                          beds in the lower Hudson River eventually led to the creation of the New York
                          Bay Pollution Commission in 1903 and the Metropolitan Sewerage Commission in
                          1906 (Franz, 1982). Routine water pollution surveys have been conducted in New
                          York Harbor since 1909. This unique data set represents the longest historical
                          record of water quality in the Nation and one of the longest historical records in
                          the world (O'Connor, 1990; Bronsand and O'Shea,  1996a). Historically, water
                          quality problems in the harbor have included severe oxygen depletion and closure
                          of shellfish beds and recreational beaches due to bacterial contamination. More
                          recently, nutrient enrichment, algal blooms, heavy metals, sediment contamination,
                          and bioaccumulation of toxics such as PCBs in striped bass (Faber,  1992;
                          Thomann et al., 1991) and bald eagles (Revkin, 1997) have also become areas of
                          concern.
                               By the 1920s summer oxygen within much of the harbor had deteriorated to
                          critical levels of less than 20 percent  saturation (Brosnan and O'Shea, 1996a).
                          Along with oyster industry records, long-term DO records document a progres-
                          sive decline in the environmental quality of the harbor from 1910 through about
                          1930 as a result of increased population growth and raw sewage loading to the
                          harbor (Brosnan and O'Shea, 1996a; Wolman, 1971). Following a period of very
                          low oxygen saturation from about 1920 through 1950, the subsequent increasing
                          trend generally corresponds chronologically to incremental improvements in
                          construction and upgrades of sewage treatment plants beginning in 1938 (Brosnan
                          and O'Shea, 1996a).
                               With the completion of New York City's last two sewage treatment plants in
                          1986-1987, one of the major remaining water pollution problems in the harbor
                          results from  combined sewer overflows that discharge raw sewage and street
                          debris. Following storm overflows, high bacteria levels require the closing of
                          shellfish beds and bathing beaches. Although an aggressive industrial pretreat-
                          ment program reduced the total industrial metal contribution  to New York City
                          plants from 3,000 Ib/day in 1974 to 227 Ib/day in 1991 (Brosnan et al., 1994), early
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                                                        Chapter 6:  Hudson-Raritan Estuary Case Study
ambient data still suggested violations of state water quality ;
in many locations of the harbor. More recent investigations c
auspices of the NY/NJ Harbor Estuary Program (HEP) indie
lower metal concentrations, with harborwide  exceedances fo
cury. Current monitoring and modeling efforts have greatly r
waters suspected to be in violation of standards  for nickel, le
(Stubin, 1997).
     Additional toxic chemical problems in the harbor are as
contamination of sediments and striped bass and other marine orga:
from the discharge from two General Electric plants upstrear
1940s through the mid-1970s (Thomann et al., 1991). With a c
ban imposed because of PCB contamination (Faber, 1992), the
population is thriving to the extent that the abundance of contaminated
caught in nets and then returned to the estuary is actually ere
hardship for the commercial shad fishery (Suszkowski, 1990
of-the-art monitoring and analysis technologies  have detecte<
trations of PCBs in regional sewage treatment plant effluent;
down programs, again initiated under the auspices of HEP, se
sources of these PCB contributions to the municipal waste stream
                                                      :andards for metals
                                                      >nducted under the
                                                      ited significantly
                                                      nd only for mer-
                                                      duced the extent of
                                                      d, and copper
                                                       ociated with PCB
                                                          misms resulting
                                                      i of Albany from the
                                                      ommercial fishing
                                                        striped bass
                                                              bass
                                                       ting an economic
                                                       . More recent state-
                                                       trace level concen-
                                                       , Current track-
                                                       jk to determine the
Legislative and  Regulatory  History
     Responding to the increasingly polluted conditions of th
New York State legislature directed the city of New York to :
                                                       estuary, in 1906 the
                                                      orm the Metropoli-
tan Sewerage Commission of New York. This commission was charged with the
dual tasks of investigating the extent of water pollution in the
ing a plan to improve city sanitary conditions. In addition to re
                                                      larbor and formulat-
                                                      commendations for
upgrades of waste treatment, which eventually were implemented beginning in the
1930s, the Commission also recommended that outfalls be relocated from
nearshore to a central diffuser in the Lower Bay. A central diffuser system,
however, was never adopted (Suszkowski, 1990).
     Construction of primary wastewater treatment plants in
estuary began with Passaic Valley, New Jersey, coming on lin
by Yonkers, New York, in 1933. During the construction of tl
plants in the 1930s and 1940s in New York City, the New Yo
of Public Works maintained an active role in research and de
treatment processes, particularly in the area of biological wa;
Although the federal government's primary role was to provi
through the Public Health Service, the Roosevelt Administrati
federal public works funding for sewage treatment plant con;
                                                      the Hudson-Raritan
                                                       in 1924 followed
                                                      e first treatment
                                                      k City Department
                                                      ^elopment of waste
                                                      te treatment.
                                                      e technical advice
                                                       n did provide
                                                      truction as a relief
program during the Great Depression (O'Connor, 1990). Because of the regional
nature of water pollution problems, New York, New Jersey, and Connecticut
established the Interstate Sanitation Commission (ISC) to develop water quality
standards and to report on progress in water pollution control in the harbor.
     Following the passage of the Federal Water Pollution Control Act and
amendments in 1948 and 1956, the federal government began to  assume a larger
role in funding for water pollution control. Beginning in 1956 and continuing on a
much larger scale with the 1972 CWA, the Construction Grants Program has
provided funding for construction of municipal wastewater treatment plants (see
                                                                                              6-9

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment


                        Chapter 2). Following the 1965 Federal Water Pollution Control Act, federal
                        funding through the Public Health Service and the Federal Water Pollution Control
                        Administration was also available to provide technical assistance in monitoring
                        and analysis to investigate water quality management issues (FWPCA, 1965,
                         1969). Under the 1972 CWA, areawide 208 studies were conducted to evaluate
                        regional water quality management solutions related to waste treatment facility
                        needs (Hazen and Sawyer, 1978; O'Connor and Mueller, 1984). Authorization for
                        New York City Department of Environmental Protection (NYCDEP) to oversee
                        its own industrial pretreatment program for corrosion control in 1987 has led to
                        significant reductions in heavy metal loadings (Brosnan et al., 1994). A citywide
                        CSO Abatement Program is under way to comply with USEPA's national CSO
                        strategy. New York City has allocated $1.5 billion for construction of CSO
                        abatement facilities over the next 10 years and is proceeding with water quality
                        studies and facility planning. In the meantime, the city implemented the "Nine
                        Minimum Controls" issued by USEPA as part of the 1994 National CSO Control
                        Policy, with significant improvements in water quality conditions (Brosnan and
                        Heckler, 1996; Heckler et al., 1998). Since enactment of the 1965 amendments to
                        the Federal Water Pollution Control Act, $7.5 billion has been invested by federal,
                        state, and local governments to upgrade 11 of 12 water pollution control plants and
                        to construct and upgrade the North River and Red Hook plants (Adamski  and
                        Deur, 1996).
                             With limited open land area, sludge disposal has always been a major
                        problem for the New York-New Jersey region. In 1924 New York City began
                        routine ocean disposal of sewage sludge at a dump site 12 miles south of
                        Rockaway off Long Island. Over the following five decades, New Jersey and
                        Westchester County also used ocean dumping to disposal of sewage sludge. By
                         1979, 5.4 million metric tons of sewage sludge solids (5 percent) had been
                        dumped into the shallow (30-m) site (Mueller et al., 1982). Because of the
                        ecological effects, and the resulting political and public controversy (NACOA,
                         1981), ocean dumping at the 12-mile site was abandoned in 1985. Sludge disposal
                        was then moved to a deepwater site 106 miles offshore until this practice was
                        ended in 1992. New York City has subsequently constructed eight sludge dewa-
                        tering facilities and is relying on private contractors to handle its sewage sludge.
                        Long-range plans for the year 1998 called for direct application of dewatered
                        sludge for beneficial land use (Schwartz and Porter, 1994).


                         Impact of Wastewater Treatment:

                         Pollutant  Loading and Water Quality

                        Trends

                             Beginning with decisions by local authorities to construct an organized
                         sewage collection system in Lower Manhattan as early as 1696, a complex
                        network of stormwater and sewage collection systems and wastewater treatment
                        plants has evolved over the past 300 years, initially to minimize nuisances and
                         protect public health, and most recently to restore and protect the estuarine
                         environment. In 1886 the first wastewater treatment plant was constructed to
                         protect bathing beaches at Coney Island. Following recommendations of a 1910
6-10

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                                                         Chapter 6:  Hudson-Raritan Estuary Case Study
master plan for sewage treatment by the Sanitary Commission, New York City,
Passaic Valley, New Jersey, and Yonkers, New York, initiated construction
programs, beginning in the mid-1920s at Passaic Valley, for wastewater plants
(O'Connor, 1990).
     Following a master plan from the Metropolitan Sewerage Commission, the
City of New York began construction of the first modern wastewater treatment
facility at Coney Island in 1935 and three plants  discharging to the East River in
1938. Other locations also constructed municipal wastewater treatment plants at
that time. Modern treatment plants went on-line  in 1938 at North and South
Yonkers, New York, designed for a combined discharge of 130 mgd into the
Hudson River; Passaic Valley, New Jersey, first  constructed a plant in  1924 and
upgraded it in 1937 to 250-mgd capacity. By 1952 a total of 11 water pollution
control facilities were operational in New York City. Upgrades to seven of the
existing facilities during the 1950s and 1960s gradually resulted in improvements in
water quality within the harbor. By  1967 the largest New York City plant, Newton
Creek, came on-line discharging 310 mgd into the East River, with New York
City's wastewater treatment facilities accounting for a total effluent discharge of
approximately 1,000 mgd.
     Driven by the regulatory controls of the 1972 Clean Water Act, public works
programs in New York City, New Jersey, Connecticut, and Westchester County
during the 1970s and 1980s upgraded municipal treatment facilities to full second-
ary treatment. In 1986 completion of the North River water pollution control plant
ended the discharge of 170 mgd of raw sewage into the Hudson River from
Manhattan, with secondary treatment attained in 1991. In 1987 completion of the
Red Hook water pollution control plant abated the discharge of 40 mgd of raw
sewage into the Lower East River from Brooklyn, with secondary treatment
attained in 1988. An additional 0.7 mgd of previously unsewered discharge was
captured beginning in 1993 when wastewater from Tottenville, Staten Island, was
connected to the 40-mgd Oakwood Beach water pollution control plant. Since the
completion of the North River plant  in 1986 and Red Hook plant in 1987, all
wastewater collected in the total sewered area of about 2,000 square miles
(Figure 6-7) in the New York metropolitan region has been treated before dis-
charge into the estuary. Within the New York-New Jersey metropolitan region,
municipal sewage treatment plants serve approximately 16 million people and
discharge about 2,500 mgd (Brosnan and O'Shea, 1996a).
      2500
      2000-
                 | Combined Sewer    Separate Sewer  |  | No Sewer
               1880 1890 1900 1910 1920 1930 1940 1950 1960 1970 1980
Figure 6-7
Long-term trend of sewage
collection in the Hudson-
Raritan Estuary
metropolitan region, 1880-
1980.
Source: Suskowski,  1990,
                                                                                              6-11

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
Figure 6-8
Long-term trend in
untreated sewage
discharges to New York
Harbor.
Source: Brosnan and
O'Shea,  1996b.
                                     1200-
1930    1940 ..... 1950
1960
1970
                                                                                  1990   2000
                               From 1979 to 1994, 13 of the 14 municipal water pollution control plants
                          operated by the city of New York were upgraded to full secondary treatment, as
                          defined by the 1972 Clean Water Act (Schwartz and Porter, 1994). The North
                          River (170 mgd) and Red Hook (45 mgd) plants, originally on line in 1986-1987 as
                          advanced primary facilities, were upgraded to full secondary plants in 1991 and
                          1989, respectively (Brosnan and O'Shea, 1996a). The Newton Creek water
                          pollution control plant is expected to be upgraded to full secondary treatment by
                          2007 (Schwartz  and Porter, 1994). As a result of upgrades to existing plants and
                          construction of the North River and Red  Hook plants, the discharge of raw
                          sewage has been reduced from 1,070 mgd in 1936 to less than 1 mgd by 1993
                          (Figure 6-8). Intermittent raw discharges, caused by malfunctions or
                          construction bypasses, have been reduced from 3.8 mgd in 1989 to 0.85 mgd by
                          1995 (O'Shea and Brosnan, 1997; Brosnan and O'Shea, 1996b).
                               The locations of municipal water pollution control plant (WPCP) discharges
                          (> 10 mgd) into  the Hudson-Raritan estuary are shown  in Figure 6-9. The
                          Hudson-Raritan  Estuary receives pollutant loads from a number of different
                          sources in the drainage basin. Table 6-2 illustrates that the relative significance of
                          different sources is dependent on the pollutant considered. Combined sewer
Table 6-2. Pollutant loadings to the Hudson-Raritan Estuary (in percent).3 Source: Brosnan and O'Shea, 1996a.











Parameter
Flow
Fecal Coliform
BOD
TSS
Nitrogen
Phosphorus


Tributary
81
2
16
80
29
16

Municipal
Effluents
15
<0.1
58
11
63
75
Combined
Sewer
Overflow
1
89
19
5
2
4

Storm
Water
4
9
5
3
2
4


Other"
<0.5
<0.1
2
1
4
<0.5


Total Load
765 m3 s'1
2.1 X1016d'1
5.7X105kgd'1
2.4X106kgd'1
2.8X105kgd'1
2.3X105kgd1









a Modified from HydroQual (1991) based on data from the late 1980s. Values across may not equal
100% due to rounding.
b Other = industrial discharges, landfill leachate, and direct atmospheric deposition combined.
6-12

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                                            Chapter 6: Hudson-Raritan Estuary Case Study
Figure 6-9
Location of harbor survey sampling sites and municipal water pollution control plants in New York Harbor.
Source: Brosnan and O'Shea, 1996b.
   NYC WATER POLL. CONTROL PLANTS *
      North River (183 mgd)
      Wards Island (267 mgd)
      Bowery Bay (128 mgd)
      Hunts Point (146 mgd)
      Tallman Island (59 mgd)
      Newtown Creek (286 mgd)
      Red Hook (45 mgd)
      Owls Head (128 mgd)
   03 Coney Island (104 mgd)
      26th Ward (72 mgd)
      Jamaica (77 mgd)
      Rockaway (23 mgd)
      Port Richmond (41 mgd)
      Oakwood Beach (27 mgd)
   * Flows represent 1/93 -11/93
     averages, (total flows)
   • Other WPCP's >10 mgd.
WESTCHESTER
   COUNTY
                      s
                  Long
                  Island
                  Sound
                                                      QUEENS
   NEW JERSEY
                                      BROOKLYN
                 STATEN
                  ISLAND
                                                 ATLANTIC OCEAN
                                                                          6-13

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment

Table 6-3. Distribution of
HydroQual, 1991; O'Shea
Waterway
Hudson River
East River
Upper New York Bay
Jamaica Bay
Lower New York Bay
Arthur Kill
Kill van Kull
Raritan River
Hackensack River
Passaic River
Total
wastewater flows into New York
and Brosnan, 1997.
WPCPsa
(2,500 mgd)
Flow (mgd)
375
1,050
375
300
125
100
50
<25
100
0
2,500
% Total
15
42
15
12
5%
4%
2%
<1%
4%
0%

Harbor waterways. Sources:
Direct Industrial Discharges
(52 mgd)
Flow (mgd)
3.1
0.0
1.0
0.0
0.0
40.0
0.0
2.1
4.2
1.0
51.4
% Total
6%
0%
2%
0%
0%
78
0%
4%
8%
2%

a Some municipal dischargers (WPCPs) include industrial dischargers.

                          overflows, for example, account for only 1 percent of the total freshwater input to
                          the harbor but contribute 89 percent of the total loading of fecal coliform bacteria
                          (Brosnan and O'Shea, 1996a). Effluent from water pollution control plants
                          contributes about one-half to three-quarters of the total load of BOD5 and nutri-
                          ents, while watershed runoff via tributaries accounts for 80 percent of the total
                          suspended solids (TSS) load. Table 6-3 presents a summary of the distribution of
                          effluent flows from municipal (WPCPs) and industrial point source discharges to
                          New York Harbor waterways. As presented in Table 6-3, approximately 2,500
                          mgd of treated wastewater was discharged in 1995 from 81 water pollution
                          control facilities located in New York City, six New Jersey coastal counties, two
                          coastal Connecticut counties, and Westchester and Rockland counties in New
                          York (O'Shea and Brosnan, 1997).  Of the total 2,500 mgd, facilities operated by
                          the city of New York accounted for 1,490 mgd in 1995.
                              With the construction and upgrade of WPCPs, the relative contributions of
                          effluent flow and BOD5 loading shifted from less-than-secondary to secondary
                          point sources. Figure 6-10 shows the contributions of raw, primary, and secondary
                          facilities to the effluent flow trend of approximately 2,500 mgd from 1970 through
                          1987. Less than 500 mgd (approximately 20 percent) was accounted for by less-
                          than-secondary dischargers by 1987. With the upgrade of the Coney Island plant
                          to full secondary in 1994, effluent flow from less-than-secondary facilities has
                          been abated completely. Trends in the reduction of effluent BOD5 loading to the
                          harbor (Figure 6-11) show that total BOD5 loads from municipal WWTPs have
                          been reduced from approximately 962 metric tons/day in 1970-1974 to 369 metric
                          tons/day by 1987. With the exception of the Newton Creek facility, all municipal
                          facilities in New York City had been upgraded to secondary treatment by 1994-
                          1995. Effluent BOD5 loading from municipal facilities discharging to the Hudson-
                          Raritan estuary was further reduced to 214 metric tons/day by 1994-1995
                          (HydroQual, 1999). Most of this substantial reduction is attributed to the elimina-
6-14

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                                                          Chapter 6:  Hudson-Raritan Estuary Case Study
         3000
         25001
         2000-
       O)

       I
       EL
1500-
                       1970-74
                            1979-80
            1987
        Raw
                              Primary
I Secondary mj| Industrial
          1200
                       1970-74
                            1979-80
            1987
                                                                     Figure6-10
                                                                     Long-term trends in the
                                                                     source contribution of point
                                                                     source effluent flow to New
                                                                     York Harbor.
                                                                     Source: HydroQual, 1991.
                                                                              Figure 6-11
                                                                              Long-term trends in the
                                                                              source contributions of
                                                                              point source effluent BOD5
                                                                              loads to New York Harbor.
                                                                              Source: HydroQual, 1991.
tion of raw sewage discharges on the west side of Manhattan (North River plant)
and Brooklyn (Red Hook plant) and upgrades to full secondary treatment. Based
on an empirical relationship of BOD5 loading and observed DO saturation records
in the Lower East River (Suszkowski, 1990), historical trends in effluent BOD5
loading have been estimated for the Lower East River (Figure 6-12). The in-
crease in BOD5 loading from 1910 to 1930 is attributed to population growth and
an expanding sewage collection system (see Figure 6-7), while the reduction in
loading from 1930 to 1940 resulted from the construction of three primary treat-
ment plants during the 1930s. After the mid-1960s, the progressive decline in
BOD5 loading was driven by upgrades to full secondary treatment and the
elimination of raw sewage discharges from Brooklyn with construction of the Red
Hook facility as an advanced primary plant in 1987.
     The long-term trend (1880-1980) of historical loading of copper and lead to
New York Harbor (Figure 6-13) reflects increasing urbanization and uncontrolled
wastewater discharges from industrial activity in the metropolitan region from
1880 through 1970. The reduction in loading of these metals after 1970, resulting
from the industrial pretreatment program, corrosion controls, and effluent controls
on industrial discharges, corresponds to a decrease in sediment levels of copper
                                                                                                6- 15

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
                          and lead in the Hudson estuary (Figure 6-14). Studies conducted at Columbia
                          University have documented a 50 to 90 percent reduction from the 1960s and
                          1970s in most trace metals and chlorinated organic compounds in fine-grained
                          sediments of the Hudson River (Chillrud, 1996). Sediment toxicity, however, has
                          been identified for the Upper East River, Arthur Kill, Newark Bay, and Sandy
                          Hook Bay. The observed distribution of sediment toxicity appears to be most
                          strongly related to polynuclear aromatic hydrocarbons (PAHs) rather than trace
                          metals (Wolfe et al., 1996). Historical point and nonpoint source loading estimates
                          for the Hudson-Raritan estuary are presented elsewhere for other trace metals,
                          PCBs, total suspended solids (HydroQual, 1991), total organic carbon (Swaney et
                          al., 1996; Howarth et al., 1996) and nutrients (HydroQual, 1991, 1999; Carpenter,
                          1987). Using a steady-state toxics model, the New York-New Jersey Harbor
                          Estuary Program has also developed mass balance analyses for copper, nickel,
                          and lead and a preliminary mass balance for mercury and PCBs (HydroQual,
                          1995b).
                               Long-term water quality records for most locations in the estuary clearly
                          illustrate degradation from population growth and inadequate sewage treatment
                          through the mid-1960s and gradual improvement following construction of waste-
                                   600
Figure 6-12
Long-term trends of BOD5
loads to the Lower East
River.
Source: Suskowski, 1990.
                                     0
                                     1910   1920   1930   1940  1950   1960  1970  1980   1990
Figure 6-13
Long-term trend of copper
and lead loads to New
York Harbor.
Source: Suskowski, 1990.
                                       1880 1
                                                                                        1990
—- Lead
^g Copper
6-16

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                                                          Chapter 6:  Hudson-Raritan Estuary Case Study
                                                                              Figure 6-14
                                                                              Time history of copper and
                                                                              lead in sediment core in
                                                                              the low-salinity reach of the
                                                                              Hudson estuary.
                                                                              Source: Valette-Silver,
                                                                              1993.
            1950  1955  1960  1965  1970  1975  1980  1985  1990  1995
water treatment plants and implementation of secondary treatment. Using histori-
cal data collected at 40 stations in the harbor from 1968 to 1993, an analysis of
harborwide long-term trends clearly documents more than an order-of-magnitude
improvement in total coliform and fecal coliform concentrations (Figure 6-15).
The dramatic decline in bacterial levels is attributed to water pollution control
infrastructure improvements that eliminated raw sewage discharges and upgraded
all water pollution control plants to include disinfection by chlorination (O'Shea
and Brosnan, 1997). Other improvements, reductions of approximately 50 percent
in bacterial levels for most areas of the harbor, are attributed to increased surveil-
lance and maintenance of the entire sewage distribution system, including the
capture of combined sewage during rain events (Brosnan and O'Shea,  1996b).
     Long-term summer DO saturation records, collected almost continuously
since 1909 at a station in the Hudson River near 42nd Street on the west side of
Manhattan (Figure 6-16) and stations at Baretto Point and 23rd Street in the
Upper and Lower East River (Figure 6-17), clearly document the beneficial
impact of upgrading water pollution control facilities to full secondary treatment.
Over a 40-year period from the  1920s through the 1960s, summer  oxygen satura-
tion levels were only about 35 percent to 50 percent at the surface and 25 percent
to 40 percent in bottom waters. As a result of significant reductions in biochemi-
cal oxygen demand loading (see Figures 6-11  and 6-12), DO saturation levels
increased to about 90 percent at the surface and greater than 60 percent in the
bottom waters (Brosnan and O'Shea, 1996a). DO concentrations have increased
significantly since the 1980s harborwide (Brosnan and O'Shea, 1996a; Parker and
O'Reilly, 1991). In many waterways, the greatest oxygen and BOD5 improve-
ments were recorded between 1968 and 1984, coinciding with the  greatest
WPCP construction and upgrading activity (O'Shea and Brosnan,  1997).  Analysis
of data for stations from 1968 to 1995 documents reductions in ammonia-nitrogen
(Figure 6-18) and decreases in BOD5 (Figure 6-19) throughout New York
Harbor; exceptions to these decreasing trends include stations in Jamaica Bay
and scattered stations in Lower New York Bay  and the Upper East River
(O'Shea and Brosnan, 1997).
     Although not generally appreciated, the poor water quality conditions,
particularly low DO levels, that characterized New York Harbor for most of the
20th century actually had a beneficial effect for  shipping activities  because
                                                                                               6-17

-------
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                                                                                                                                                             I
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         m
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                                                                        Oxygen (% Saturation)
                                                                                       O)    CO
                                                                       Dissolved Oxygen (mg/L)
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                                                    00

-------
                                                          Chapter 6: Hudson-Raritan Estuary Case Study
wooden pilings and other submerged wooden structures were not destroyed by
pollution-intolerant marine borers. During the 19th century before water quality
had deteriorated in the harbor, abundant populations of shipworms (teredos) and
gribbles (limnorid) quickly devoured driftwood (naturally occurring) and wooden
pilings (man-made). This natural ecological activity probably kept the harbor clear
of driftwood, but it created severe problems for commercial shipping interests
because untreated wooden pilings needed to be replaced after only about 7-10
years (Port Authority of New York, 1988). As water pollution problems increased
in the harbor, populations of marine borers declined to such a level that, ironically,
wooden pilings and other submerged wooden structures were preserved for many
years while submerged in the noxious, oxygen-depleted waters laden with oil,
bilge waste, and toxic chemicals. The dramatic improvements in water quality
conditions in New York Harbor, as well as other east and west coast harbors,
have resulted in a resurgence of thriving populations of marine borers since the
mid-1980s  (Gruson, 1993) (Figure 6-20). The population boom of marine borers
has resulted in severe infestation and rapid deterioration and collapse of wooden
                                                                              Figure 6-18
                                                                              Long-term trend in
                                                                              summer mean inorganic
                                                                              nitrogen.  Data represent
                                                                              harborwide composite of
                                                                              40 stations monitored
                                                                              since at least  1970.
                                                                              Source: O'Shea and
                                                                              Brosnan,  1997.
               70       1975      1980      1985       1990       1995
                          • NH3-N
                                     	NO3-N+NO2-N
                                                                              Figure 6-19
                                                                              Long-term trend in
                                                                              summer mean BOD5. Data
                                                                              represent harborwide
                                                                              composite of 40 stations
                                                                              monitored since at least
                                                                              1970.
                                                                              Source: O'Shea and
                                                                              Brosnan,  1997.
                      1975       1980       1985       1990       1995
	 Surface 	
Bottom
                                                                                                6-19

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Progress in Wafer Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment


                        pilings and other submerged wooden structures in New York Harbor from JFK
                        International Airport to New Jersey, including Brooklyn, Staten Island, and the
                        east and west sides of Manhattan (Randolph, 1998; Abood et al, 1995; Metzger
                        andAbood, 1998;  Schwartz and Porter, 1994).
                            Over the past several years, state-of-the-art coupled hydrodynamic and
                        water quality models have been developed for water quality management studies
                        of the harbor, including New York City's Harbor-Wide Eutrophication Model and,
                        most recently, the System-Wide Eutrophication Model (SWEM) (HydroQual,
                        1995a, 1996, 1999). Earlier models, developed for USEPA's 208 Study of the
                        harbor (Hazen and Sawyer,  1978; Higgins et al., 1978; Leo et al., 1978; O'Connor
                        and Mueller, 1984), have been used to assess the impact of secondary treatment
                        requirements on DO in the harbor. The more recent New York City models,
                        employing improved loading estimates and state-of-the-art hydrodynamics
                        (Blumberg et al., 1997), are being used to determine the feasibility and effective-
                        ness of management alternatives for New York City point sources of nitrogen.
                        For example, SWEM will enable New York City to evaluate options as part of the
                        facility planning for the Newton Creek WPCP, the last remaining plant operated
                        by the city of New York to be upgraded to secondary treatment (HydroQual,
                        1999). This model is further assisting the New York-New Jersey Harbor Estuary
                        Program in understanding the complex relationships between physical transport
                        processes, nitrogen loading, algal biomass, and DO in New York Harbor, the New
                        York Bight, and Long Island Sound (HEP, 1996).


                        Impact of Wastewater Treatment:

                        Recreation  and  Living  Resources  Trends

                            Since 1968 the New York City Council has required the New York City
                        Department of Public Health to notify the Department of Parks of beaches that
                        pose a potential health risk to the public.  Such beaches were traditionally posted
                        with wet weather advisories, following occurrences of heavy or prolonged
Figure 6-20
Trends in marine borer
activity in Upper New York
Harbor.
Source: Port Authority of
New York, 1988.
16 sites including Port Newark
                                  1970
       1975
1980
1985
                                                                                    1990
-*- Limnoria -»
Teredo
6-20

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                                                         Chapter 6: Hudson-Raritan Estuary Case Study
rainstorms. These postings have long been replaced with seasonal wet weather
advisory postings. The advisories are based on the occurrence of high fecal
coliform bacteria concentrations, which may indicate the presence of raw or
partially treated sewage and the likely presence of waterborne pathogens.
Diseases associated with recreational swimming waters include typhoid fever,
gastroenteritis, swimmer's itch, swimmer's ear, and some viral infections such as
infectious hepatitis (NJDEP, 1990).
     The most important source of pollution, contributing about 89 percent of the
total fecal coliform bacteria load to the harbor, is wet weather CSOs (Brosnan
and O'Shea, 1996a). Large volumes of water generated during rainstorm events,
when combined with the regular volume of sewage, overwhelm the capacity of
the collection system and discharge the mixture of storm runoff and raw waste-
water directly into the harbor. During wet weather events, water quality may be
seriously degraded.
     Before 1900 untreated wastewater caused severe outbreaks of  disease
associated with exposure pathways such as shellfish consumption and recre-
ational swimming. Conditions improved somewhat as sewage treatment plants
adopted primary treatment as a practice to settle out the solids in wastewater
before discharge to the harbor. Pathogen reduction was further enhanced by
upgrading water pollution control facilities to secondary treatment with chlorina-
tion of the effluent for disinfection. Improvements in municipal wastewater
treatment practices have significantly reduced the incidence of waterborne
disease outbreaks. Typhoid fever, once a serious swimming-related disease, for
example, has not been reported in the last 30 to 40 years (NJDEP, 1990).
     During the 1970s and 1980s significant efforts were made to construct and
upgrade WPCPs in the Hudson-Raritan Estuary to attain secondary levels of
wastewater treatment as mandated by the 1972 Clean Water Act. With upgrades
and chlorination of effluent, the discharge of raw wastewater has been reduced
from 450 mgd in 1970 to less than 5 mgd by 1988  and essentially zero by 1993
(see Figure 6-8). The most dramatic improvement in bacterial conditions in the
harbor occurred in 1986 with the completion of the North River WPCP in Man-
hattan. Before construction of the primary facility, 170 mgd of raw sewage was
discharged into the Hudson River from 50 outfalls on the west side of Manhattan
(Brosnan and O'Shea, 1996a). Treatment of the raw sewage and year-round
disinfection resulted in a dramatic decline in fecal coliform concentrations. The
1986 data revealed a 78 percent decrease in the fecal coliform concentrations in
the Hudson river compared to values  measured in 1985 before the primary plant
came on-line. When the 45-mgd Red  Hook WPCP went on-line in 1987 in
Brooklyn, abating the raw sewage discharge from 33 outfalls, fecal coliform
concentrations in the East and Lower Hudson Rivers declined by 69 percent
within 2 years. Continued improvements in water quality and decreases in fecal
coliform bacterial concentrations on the order of 50 percent from 1989 to 1995
are attributed to improved maintenance and surveillance of the sewage treatment
system. Management actions that have contributed to these improvements in
water quality include abatement of illegal connections, reduced raw sewage
bypasses, and increased capture of combined sewage during rain events (Brosnan
and O'Shea, 1996b).
     "Snapshots" of the distribution of total coliform bacteria from 1972 to 1995
in surface  waters of the harbor (Figure 6-21) clearly document the significant
                                                                                              6-21

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
                          reductions in bacterial concentrations that resulted from implementation of
                          controls to reduce water pollution in the harbor. Following completion of the North
                          River and Red Hook WPCPs in 1986 and 1987, respectively, total coliform
                          distributions in 1988 demonstrated significant improvements compared to 1985
                          before these two plants came on-line. The improvements attributed to CSO
                          controls are also quite apparent: total coliform levels in the harbor declined by
                          more than  50 percent at 45 of 52 stations in 1995 and compliance with water
                          quality standards improved from 87 percent in 1989 to 98 percent in 1995
                          (Brosnan and Heckler, 1996).
                               Historically, many public bathing beaches in Lower New York Harbor have
                          been closed to swimming to protect public health because of high bacterial levels
                          that consistently violated water quality standards for primary contact. As a result
                          of the construction and upgrade of water pollution control plants in the harbor, the
                          significant harborwide reductions in coliform bacteria levels (see Figure 6-16)
                          allowed the reopening of public beaches that had been closed for decades. In
                          1988 Seagate Beach on Coney Island was opened to swimming for the first time
                          in 40 years. South Beach and Midland Beach on Staten Island, closed since the
                          early 1970s, were opened for swimming in 1992. In addition to beach closings
                          because of high bacterial levels, recreational beaches are also closed because of
                          strandings of floatable garbage, including medical waste, on the beaches. As a
                          result of increased abatement and control of discharges of floatable debris, beach
                          closings in New York and New Jersey have been greatly reduced. As of 1996, no
                          beaches in New York City had been closed because of floatables since  1989;
                          New Jersey beaches had not been closed since 1991 (Brosnan and Heckler,
                          1996).
                               In addition to closing bathing beaches, the presence of pathogens and
                          pathogenic indicator organisms directly affects shellfish resources. Because
                          pathogen levels were significantly reduced by improved wastewater treatment
                          and year-round chlorination, 67,864 acres of shellfish beds in the estuary have
                          been upgraded since 1985, including removal of seasonal restrictions for 16,000
                          acres in the New York Bight in  1988, and 13,000 acres in Raritan Bay in 1989
                          (Gottholm et al., 1993; NJDEP,  1990). Additionally, 1,000 acres of shellfish waters
                          in the Navesink River are being considered for upgrading to a "seasonally ap-
                          proved" classification (HEP, 1996). Shellfishing resources to a greater extent than
                          finfish populations are directly related to improvements in wastewater treatment
                          (Sullivan, 1991).
                               Although the long-term trends in the abundance of fish such as American
                          shad and striped bass in coastal waters may be the result of degraded water
                          quality, the National Marine Fisheries Service has indicated that overfishing,
                          rather than changes in water quality, is probably the most significant cause of
                          present changes in resource abundance for many species (Sullivan, 1991). The
                          principal commercial fishery of the lower Hudson River estuary is for American
                          shad. Shad landings from 1979  to 1989 were maintained, whereas landings of
                          whiting, red hake, scup, and weakfish decreased during the last decade
                          (Woodhead, 1991). Improved water quality has expanded the spawning area
                          available for American shad (Sullivan, 1991). The prevalence of fin rot in winter
                          flounder declined tenfold in the New York Bight region between 1973 and 1978
                          for reasons that are not clear (Swanson et al., 1990). Although the causes of fin
                          rot are not well understood, it tends to be more prevalent in shallow inshore
6-22

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                                                     Chapter 6: Hudson-Raritan Estuary Case Study
Figure 6-21

Total coliform trends in surface waters of New York Harbor. Summer geometric means for 1972, 1985, 1988, and 1995.

Source: O'Shea and Brosnan, 1997.
        1972
      Pre-WPCP Upgrades
            NORTH
              N
          W
     NEW JERSEY
                                ATLANTIC OCEAN
                Itotai toy
   1985
Post-WPCP Upgrade,
Pre-North River and
Red Hook WPCP's
                                                NEW JERSEY
        1988
      Post-North River (1986)
      and Red Hook (1987)
     NEW JERSEY
   1995
improvements from the
Nine Minimum
CSO Controls
WESTCHESTER
  COUNTY
        w^f'
        .  aa
        0 tound
NEW JERSEY ^>
                                                                           ATlAtmC OCEAN
                                                           fertattay
    KEY: UNIT=MPN/100ML

    D < 70           D  71-2400      m 2401 -10000  •  > 10000       D NOT MEASURED
    JTSS?1^"1* * TO MPH/100lnl * SA(Shellftehlnfl); 70 - 2,400 MPN/IOOml = SB(B«thlng); 2,400 -10,000 MPN/100ml = l(Fl«hinfl)
    (NOTE: This analysis does not necessarily imply compliance.)
    VOR fm«o»v»n«.«£»Tcn3»iB*»*Tc««»6j»»* mom
                                                                                        6-23

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment


                          waters receiving municipal effluents, and therefore the decline in the incidence of
                          fin rot lesions might reflect improvements at wastewater treatment plants
                          (Sullivan, 1991).
                               Populations of some birds in the Hudson Raritan Estuary have historically
                          been influenced by many aspects of this complex urban ecosystem other than
                          water quality. Notable among these factors is the decimation of local bird popula-
                          tions in the latter half of the 19th century by the hunting and milliner's trade
                          (Sullivan,  1991). Before the passage of federal protective legislation, such as the
                          1913 Migratory Bird Treaty, annual catches for food and feathers totaled more
                          than a million birds per year. Even small songbirds, such as robins, were sought
                          for sale in commercial markets. By 1884 the once abundant populations of
                          common terns, least terns, and piping plovers, formerly present between Coney
                          Island and Fire Island, had been reduced to but a few individuals. Populations of
                          common and roseate terns, herons, snowy egrets, and many other species were
                          similarly affected by hunting.
                               Populations gradually recovered over the next several decades until develop-
                          ment and associated draining and spraying of wetlands for mosquito control
                          encroached on, and degraded, waterfowl habitat. Between the late 1940s and its
                          ban in  1972, DDT was heavily applied to the salt marshes of Long Island and
                          New Jersey; the New Jersey marshes received the heaviest applications for the
                          longest period of time. The DDT was transferred up the food chain to fish and
                          shellfish, which are an important food source for many coastal birds in the harbor.
                          DDT accumulated in bird tissues and contributed to the decline in reproductive
                          success by affecting eggshell thickness. The osprey was  probably the species
                          most affected in the Hudson-Raritan Estuary area, although bald eagles and
                          herons were also  affected.
                               Recent concerns for shorebirds include the high concentrations of industrial
                          chemicals  such as PCBs measured in mallards, black ducks, scaup, and osprey.
                          Due to the many factors contributing to the abundance of shorebirds and the fact
                          that they can be exposed to more than one geographic area through migration,
                          there is only a tenuous linkage between improved water pollution control efforts
                          and bird populations. Overwintering populations of waterfowl, however, have
                          generally remained stable since the 1980s (Sullivan, 1991). For example, the
                          Canada goose populations of New Jersey increased from about 6,000 in 1975 to
                          23,200 in 1981 to  124,000 in  1990, a record high for the state. This increase is
                          most likely the result of displacement of geese  from other states, particularly
                          Maryland.
                               Most remarkable among bird population recoveries is the return of herons to
                          the heavily industrialized and highly polluted northwestern portion of Staten Island
                          along the Arthur Kill and Kill Van Kull waterways. In the urban wetlands, un-
                          daunted by nearby oil refineries and chemical manufacturing plants, herons and
                          other wading birds are making a comeback. The Harbor Herons Complex, first
                          documented in the industrial Arthur Kill waterway in the 1970s,  has become a
                          regionally significant heron and egret nesting rookery (HEP, 1996). In 1974 snowy
                          egrets, cattle egrets, and black-crowned night-herons began nesting on Shooters
                          Island; in 1978 nesting  snowy egrets and cattle egrets were found on Frail's
                          Island, a 88-acre high marsh that in the past had served as a disposal site for
                          dredged spoils. By 1981 these birds were joined by glossy ibises, great egrets, and
                          black-crowned night-herons.  In 1989 snowy egrets, glossy ibises, cattle egrets,
6-24

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                                                        Chapter 6: Hudson-Raritan Estuary Case Study
black-crowned night-herons, yellow-crowned night-herons, little blue herons, and
great egrets were found on the nearby Isle of Meadows. Ospreys, now nesting in
portions of the harbor core area where they had been absent for decades (prima-
rily because of bioaccumulation of DDT), have rapidly become so numerous as to
be considered a nuisance by boaters and fishermen. Ten percent of the east coast
population of the federally endangered peregrine falcon is located in the Hudson-
Raritan Estuary metropolitan area (HEP,  1996).
     Fish-eating bird populations have thrived despite the fact that sluggish
circulation and urban runoff and municipal and industrial wasteloads characterize
these waterways (Hydroqual, Inc., 1991). The Arthur Kill waterway is possibly
one of the sites of poorest water quality in New York Harbor. Summer mean DO
concentrations in the Arthur Kill, ranging from less than 1 mg/L to about 3 mg/L
from 1940 to the mid-1970s, however, steadily improved during the 1970s to
concentrations above 5 mg/L by the mid-1980s (Figure 6-22) (Keller et al., 1991;
O'Shea and Brosnan, 1997). Average summer concentrations of DO at Shooters
Island in the Kill Van Kull further reflect this trend of improvements, increasing
from 30 percent in 1974 to near 60 percent saturation in 1995 (O'Shea and
Brosnan, 1997). Improvements in DO concentrations, as well as habitat protection
efforts by the New York City Audubon Society, may have contributed to the
success of populations of herons that feed on pollution-intolerant young fish in the
Arthur Kill and its associated tidal creeks and wetlands. A 1988-1989 census of
wading bird breeding populations indicated approximately 900-1,200 pairs of
breeding herons, egrets, and ibises that constitute possibly the largest colonial
waterbird rookery complex in New York State (Trust for Public Lands, 1990).


Summary  and Conclusions

     In the three centuries since the Governor of New York ordered a sewer
system to be constructed in Lower Manhattan, New York City has made  consid-
erable progress in protecting public health and improving the water quality of the
harbor. Since the  early 1900s when the city of New York instituted one of the
Nation's first long-term water quality monitoring programs in New York Harbor,
                                                                           Figure 6-22
                                                                           Long-term trend in
                                                                           summer (July-September)
                                                                           mean, minimum, and
                                                                           maximum DO in the Arthur
                                                                           Kill (RF1-02030104003).
                                                                           Source: USEPA (STORET).
          1940
19ST
1960
1970
1980
T990
                             Mean	Min  	Max
                                                                                            6-25

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment


                          the city's efforts to improve the waters of New York have included constructing,
                          maintaining, and upgrading the infrastructure for wastewater collection and
                          treatment, pollution prevention and remediation, water quality monitoring, and
                          programs to protect the natural resources of the estuary and restore disrupted
                          natural drainage patterns to mitigate urban runoff problems.
                              Although construction and upgrades of municipal wastewater treatment
                          facilities resulted in some water quality improvements beginning in the 1950s, the
                          greatest strides in improving ecological conditions in the harbor can be attributed
                          to new construction and upgrades of municipal wastewater plants in the Hudson-
                          Raritan metropolitan region during the 1970s, largely stimulated by the regulatory
                          requirements of the 1972 CWA. Based on assessments of long-term water quality
                          monitoring data and other environmental indicators, the ecological and water
                          quality conditions of New York Harbor are the best they have been since the
                          early 1900s (NYCDEP, 1999).
                              Biological indicators of environmental improvement in New York Harbor
                          include the reestablishment of breeding populations of waterfowl (e.g., peregrine
                          falcons, ospreys, herons) in many areas of the estuary, the recovery of Hudson
                          River shortnose sturgeon to record populations, the decline of PCBs in striped
                          bass, and a relaxation of New York State advisories for human consumption of
                          striped bass in parts of the Hudson River. Marine organisms long absent from the
                          waters of the harbor because of poor water quality conditions are now thriving as
                          a result of the cleanup of the harbor. The resurgence of pollution-intolerant
                          benthic organisms in Lower New York Bay and the heavy reinfestation of
                          submerged wooden pilings by marine borers throughout the Hudson-Raritan
                          estuary are strong evidence of the improvement in the ecological condition of the
                          harbor.
                              Water quality indicators of environmental improvement in the harbor that
                          can be attributed to upgrades of wastewater treatment facilities include significant
                          declines  in total and fecal coliform bacteria, dramatic improvements in dissolved
                          oxygen levels, and declines in ammonia-nitrogen and BOD5 in most areas of the
                          Hudson-Raritan estuary. Controls on releases of heavy metals and toxic chemi-
                          cals have resulted in a 50-90 percent reduction relative to peak levels of trace
                          metals and chlorinated organic compounds associated with fine-grained sediments
                          in the Hudson River. The 1972 federal ban on lead in gasoline has resulted in
                          declines  in lead in the sediments  in New York Harbor and many other waterways
                          (O'Shea and Brosnan,  1997).
                              Resource use indicators of environmental improvements in the harbor
                          include the bacteria-related upgrading of the status of 68,000 acres of shellfish
                          beds, including the lifting of restrictions on harvesting shellfish in 30,000 acres in
                          Raritan Bay and off the Rockaways in the late 1980s. As a result of the dramatic
                          declines in coliform bacterial levels, all New York City beaches, historically closed
                          to swimming since the 1950s, have been open since 1992 and wet-weather
                          swimming advisories have been lifted for all but three beaches (NYCDEP,  1999).
                          These bacteria-related improvements in public and commercial uses of the harbor
                          can be attributed to the continued construction and upgrading of the city's munici-
                          pal water pollution control plants, the elimination of raw and illegal waste dis-
                          charges, and the increased efficiency of the combined sewer system (Brosnan
                          and O'Shea, 1996b; Brosnan and Heckler, 1996).
6-26

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                                                        Chapter 6: Hudson-Raritan Estuary Case Study
     As a result of the clean-up efforts to date in the harbor, the public has
enjoyed greatly increased opportunities for recreational uses such as swimming,
boating, and fishing. The improvements in water quality also provide substantial
benefits to the local economy through commercial fishing and other water-based
revenue-generating activities. Although tremendous ecological improvements
have resulted from water pollution control efforts implemented since the 1970s, a
number of environmental problems remain to be solved for the Hudson-Raritan
Estuary. Some contemporary concerns and issues include, for example, contami-
nation of sediments and restrictions on dredge spoil disposal, remaining fish
advisories for human consumption, episodic low dissolved oxygen, the occurrence
of nuisance algal blooms and effluent controls on nitrogen discharged to the
estuary, and increasing nonpoint source runoff from overdevelopment in the
drainage basin of the estuary (NYCDEP, 1999). The success of continued water
pollution control efforts to remedy these concerns in the Hudson-Raritan Estuary
will require financial support from all levels of government, enhanced public
awareness about the resource value of the estuary, and strong public stakeholder
support for regional coordination of environmental control programs throughout
the entire Hudson-Raritan watershed.
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                                                                                           6-29

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment


                         McHugh, J.L., R.R. Young, and W.M. Wise.  1990. Historical trends in the
                             abundance and distribution of living marine resources in the system. In
                             Cleaning up our coastal waters: An unfinished agenda,  ed. K. Bricke,
                             and R.V. Thomann (co-chairmen), Regional Conference cosponsored by
                             Manhattan College and the Management Conferences for the Long Island
                             Sound Study (LISS), the New York-New Jersey Harbor Estuary Program
                             (HEP), and the New York Bight Restoration Plan (NYBRP), March 12-14,
                             1990.
                         Metzger, S.G., and K.A. Abood. 1998.  The Linmoria has landed! In Ports '98,
                             ed. M.A. Knott, Proc. Conf. Tampa, FL. American Society of Civil Engi-
                             neers, New York.
                         Mueller, J.A., T.A. Gerrish, and M.C. Casey.  1982.  Contaminant inputs to  the
                             Hudson-Raritan Estuary. NOAA Tech. Mem. OMPA-21. Boulder,  CO.
                         NACOA.  1981.  The role of the ocean in a waste management strategy.
                             Special Report to the President and Congress. January. National Advisory
                             Committee on Oceans and Atmospheres, Washington, DC.
                         NJDEP.   1990.  Characterization of pathogen contamination in the NY-NJ
                             Harbor estuary. Prepared by the New Jersey Department of Environmental
                             Protection Pathogen Workshop. (Also included was a February 6,  1992,
                             addendum.)
                         NYCDEP. 1999.  1998 New York Harbor water quality regional summary. New
                             York City Dept. Environmental Protection, New York, NY. .
                         O'Connor, D.J. 1990. A historical perspective: engineering and scientific. In
                             Cleaning up our coastal waters:  an unfinished agenda,  ed. K. Bricke,
                             and R.V. Thomann (co-chairmen), pp. 49-67. Regional conference cospon-
                             sored by Manhattan College and the Management Conferences for the Long
                             Island Sound Study (LISS), the New York-New Jersey Harbor Estuary
                             Program (HEP), and the New York Bight Restoration Plan (NYBRP),
                             March 12-14, 1990.
                         O'Connor, D.J., and J.A. Mueller.  1984.  Water quality analysis of the New York
                             Harbor complex. ASCE, Jour. Environ. Eng. Div.  110(6):  1027-1047.
                         O'Connor, D.J., R.V. Thomann, and H.J. Salas. 1977. Water quality. MESA
                             New York Bight Atlas Monograph 27. New York Sea Grant Institute,
                             Albany, NY.
                         OMB.  1999. OMB Bulletin No. 99-04. Revised statistical definitions of Metro-
                             politan Areas (MAs) and Guidance on uses of MA definitions. U.S. Census
                             Bureau, Office of Management and Budget, Washington, DC. .
                         O'Shea, M.L.,  and T.M. Brosnan.  1997.  New York Harbor water quality
                             survey. Main report and appendices 1995. New York Department of
                             Environmental Protection, Bureau of Wastewater Pollution Control, Division
                             of Scientific Services, Marine Sciences Section, Wards Island, NY.
                         Parker, C.A., and J.E. O'Reilly. 1991. Oxygen depletion in Long Island Sound:
                             A historical perspective. Estuaries 14(3): 248-264.
                         Port Authority of New York. 1988. Meeting of the Marine Borer Research
                             Committee of the New York Harbor/East Coast Commission on Marine
                             Barriers, November  10, 1988, World Trade Center, New York, NY.
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                                                        Chapter 6: Hudson-Raritan Estuary Case Study
Randolph, E.  1998, January 26. Terror of the Hudson River is back. The Los
    Angeles Times, p. A-5.
Revkin, A.C.  1997, September 17.  High PCB level is found in a Hudson bald
    eagle. The New York Times, p. B-4.
Schwartz, J.J., and K.S. Porter.  1994.  The state of the city's waters: 1994. the
    New York Harbor Estuary. Prepared by the New York State Water Re-
    sources Institute, Center for the Environment, Cornell University, Ithaca, NY.
Stubin, A. 1997. New York City Department of Environmental Protection,
    Marine Sciences Section, Wards Island, NY. Personal communication,
    October 1, 1997.
Sullivan, J.K.  1991.  Fish and wildlife populations and habitat status and
    trends in the New York Bight.  A report to the Habitat Workgroup for the
    New York Bight Restoration Plan.
Suszkowski, D.J.  1990.  Conditions in the New York/New Jersey harbor estuary.
    In Cleaning up our coastal waters: An unfinished agenda, ed. K. Bricke,
    and R.V.  Thomann (co-chairmen), pp.  105-131. Regional conference co-
    sponsored by Manhattan College and the Management Conferences for the
    Long Island Sound Study, the New York-New Jersey Harbor Estuary
    Program, and the New York Bight Restoration Plan, March 12-14, 1990.
Swaney, D.P, D. Sherman, and R.W. Howarth.  1996. Modeling water, sediment
    and organic carbon discharges  in the Hudson-Mohawk Basin: Coupling of
    terrestrial sources. Estuaries 19(4): 833-847.
Swanson, R.L., Bell, T.M., Kahn, J. and J. Olha.  1990.  Use impairments and
    ecosystem impacts of the New York Bight. In  Cleaning up our coastal
    waters: An unfinished agenda, ed. K. Bricke,  and R.V. Thomann (co-
    chairmen). Regional conference cosponsored by Manhattan College and the
    Management Conferences for the Long Island Sound Study, the New York-
    New Jersey Harbor Estuary Program, and the New York Bight Restoration
    Plan, March 12-14, 1990.
Thomann, R.V., J.A. Mueller, R.P. Winfield, and C. Huang. 1991. Model of fate
    and accumulation of PCB homologues in Hudson Estuary. Journal of
    Environmental Engineering 117(2): 161-178.
Trust for Public Lands.  1990.  The Harbor Herons report: A strategy for
    preserving a unique urban wildlife habitat and wetland resource in
    northwestern Staten Island. Published by the Trust for Public Land in
    conjunction with the New York City Audubon Society, New York, NY.
USDOC.  1998.   Census of population  and housing. Prepared by U.S. Depart-
    ment of Commerce, Economics and Statistics Administration, Bureau of the
    Census - Population Division, Washington, DC.
USEPA (STORET). STOrage and RETrieval Water Quality Information System.
    U.S. Environmental  Protection Agency, Office of Wetlands, Oceans, and
    watersheds, Washington, DC.
USGS. 1999. Streamflow data downloaded from U.S. Geological Survey, United
    States National Water Information System (NWIS)-W Data retrieval for
    historical streamflow daily values, .
Valette-Silver, N.J. 1993. The use  of sediment cores to reconstruct historical
    trends in contamination of estuarine and coastal sediments. Estuaries
    16(3B):577-588.
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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
                         Wiseman, W. 1997. State University of New York at Stony Brook, Marine
                             Sciences Research Center, Stony Brook, NY. Personal communication,
                             December 23, 1997.
                         Wolfe, D.A, E.R. Long, and G.B. Thursby.  1996.  Sediment toxicity in the
                             Hudson-Raritan estuary: Distribution and correlations with chemical contami-
                             nation. Estuaries 19(4): 901-912.
                         Wolman, M.G.  1971. The Nation's rivers. Science 174: 905-917.
                         Woodhead, P.M.J.  1991.  Inventory and characterization of habitat and fish
                             resources,  and assessment  of information on toxic effects on the New
                             York-New Jersey Harbor Estuary. A report to the New York-New Jersey
                             Harbor Estuary Program.
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    Chapter  7
 Delaware   Estuary
 Case  Study
      The Mid-Atlantic Basin (Hydrologic Region 2),
      covering a drainage area of 111,417 square
      miles, includes some of the major rivers in the
continental United States. Figure 7-1 highlights the
location of the basin and the Delaware estuary, the case
study watershed profiled in this chapter.
    With a length of 390 miles and a drainage area of
11,440 square miles, the Delaware River ranks 17th
among the 135 U.S. rivers that are more than 100
miles in length. On the basis of mean annual dis-
charge (1941-1970), the Delaware ranks 28th
(17,200 cfs) of large rivers in the United States
(Iseri and Langbein, 1974). Urban-industrial areas
in the watershed caused severe water pollution
problems during the 1950s and 1960s (see Table 4-2).
This chapter presents long-term trends in population,
municipal wastewater infrastructure and effluent loading of pollut-
ants, ambient water quality, environmental resources, and uses of the
Delaware Estuary. Data sources include USEPA's national water
quality database (STORET), published technical literature, and unpub-
lished technical reports ("grey" literature) obtained from local agency sources.
    The Delaware River, formed by the confluence of its east and west
branches in the Catskill Mountains near Hancock, New York, on the
Pennsylvania-New York state line, becomes tidal at Trenton, New Jersey (Figure
7-2). The first 86 miles of the tidal river are the Delaware River estuary, which
flows by Trenton, New Jersey; Philadelphia, Pennsylvania; Camden, New Jersey
and Wilmington, Delaware. This major urban-industrial area has a tremendous
impact on the water quality of the river. In this area, the Delaware River estuary
flows along the boundary between the Piedmont Plateau and the Atlantic Coastal
Plain. A large number of municipal and industrial wastewater facilities discharge
to the Delaware River, with municipal water pollution control plants accounting
for the largest component of BOD5 loading. In general, water quality is good at
the head of the tide at Trenton (RM 134.3), but it begins to deteriorate down-
stream.
Figure 7-1
Hydrologic Region 2 and
Delaware estuary
watershed.
                                                                                 7-1

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
                                               76
Figure 7-2
Location map of the Lower
Delaware River-Delaware
Bay. (River  miles shown
are distances from the
Cape May, NJ, to Cape
Henlopen, DE,  transect.)
                                              76
                              From the 1930s through the 1970s, water quality conditions were very poor.
                         Depleted DO levels were recorded in the region from Torresdale (RM 110.7) to
                         Eddystone (RM 84.0) as a result of wastewater loading from Philadelphia (RM
                         110-93). Since the mid-1980s water quality conditions in the estuary have im-
                         proved significantly.


                         Physical  Setting and  Hydrology

                              The Delaware River originates in the south-central area of New York State
                         and flows 390 miles in a southerly direction to the Atlantic Ocean, separating
                         New Jersey on its eastern bank from Pennsylvania and Delaware on its west.
                         The total drainage area at the mouth of the river at Listen  Point on Delaware Bay
                         is  11,440 square miles, of which 6,780 square miles lie above the gaging station at
                         Trenton, New Jersey (Iseri and Langbein, 1974). The major tributary to the
                         Delaware Estuary is the Schuylkill River, which joins the main stream in the
                         vicinity of Philadelphia, Pennsylvania. The Schuylkill has a drainage area of 1,890
                         square miles at the Fairmount Dam, 8 miles above the mouth. In addition to the
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                                                               Chapter 7: Delaware Estuary Case Study
Schuykill River, the other major tributaries to the Delaware estuary include
Assunpink Creek, Crosswicks Creek, Rancocas Creek, Neshaminy Creek,
Cooper River, Chester Creek, the Christina River, and the Salem River. Figure 7-3
presents long-term statistics of summer streamflow from the USGS gaging station
at Trenton, New Jersey, from 1940 to 1995. The extreme drought conditions of
the mid-1960s are quite apparent in the long-term record (1962-1966). Seasonal
variation of freshwater flow of the Delaware River is characterized by high flow
from March through May, with a peak flow of 21,423 cfs in April. Low-flow
conditions typically occur from July through October, with the monthly minimum
flow of 5,830 cfs recorded during September (Figure 7-4). From July  through
October, low-flow in the river is typically augmented by releases from reservoirs.
During dry conditions, reservoir releases, regulated to maintain a minimum flow of
2,500-3,000 cfs at Trenton, can be  greater than 60 percent of the inflow to the
estuary (Albert, 1997).
          o
          £
                                     197?
1980
1990
20o8'°
                                Figure 7-3
                                Long-term trends in mean,
                                10th, and 90th percentile
                                streamflow in summer
                                (July-September) for the
                                Delaware River at Trenton,
                                NJ (USGS Gage
                                01463500).
                                Source: USGS, 1999.
                   	90%ile
    mean & ratio
                                                                             Figure 7-4
                                                                             Monthly trends of mean,
                                                                             10th, and 90th percentile
                                                                             streamflow  for the
                                                                             Delaware River at Trenton,
                                                                             NJ (USGS Gage
                                                                             01463500), 1951-1980.
                                                                             Source: USGS, 1999.
                    ONDJFMAMJJAS
                                                                                                7-3

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
                              The Delaware River-Delaware Bay system is one of the major coastal plain
                         estuaries of the east coast of the United States. The tidal river and estuary extend
                         a distance of 134 miles from the fall line at Trenton, New Jersey, to the ocean
                         mouth of Delaware Bay along an 11-mile section from Cape May, New Jersey, to
                         Cape Henlopen, Delaware (Figure 7-1). Because Philadelphia is a major east
                         coast port, a navigation channel is maintained to a depth of 12 meters (39 feet)
                         from the entrance to the bay upstream to Philadelphia. From Philadelphia to
                         Trenton, the channel is maintained at a depth of 8 meters (26 feet) (Galperin and
                         Mellor,  1990). The semidiurnal tide has a mean range of 1.5 meters (4.9 feet) at
                         the mouth of the bay and propagates upstream  on the incoming tide to Trenton in
                         approximately 7 hours; typical tidal currents are approximately  1.5 meter sec"'
                         (Galperin and Mellor, 1990). Approximately 25 miles downstream from Philadel-
                         phia, tidal currents near the Tacony-Palmyra Bridge (RM 107) are characterized
                         by vigorous vertical mixing and a marked current reversal with currents of
                         approximately 1.0 meter sec"1 (Thomann and Mueller, 1987).
                              The Delaware estuary  can be characterized as three distinct hydrographic
                         regimes based on distributions of salinity, turbidity, and biological productivity:
                         (1) tidal freshwater, (2) transition zone, and (3) Delaware Bay zone. The tidal
                         fresh river extends about 55 miles from the head of tide at Trenton, New Jersey
                         (RM 134) to Marcus Hook,  Pennsylvania (RM 79). Under mean freshwater flow
                         conditions, salinity intrusion in the tidal fresh section of the river generally extends
                         upstream to the reach between the Delaware Memorial Bridge at Wilmington
                         (RM 68.7) and Marcus Hook (RM 79.1). During drought periods (e.g., 1962-
                         1966), salinity intrusion is a concern because industrial water withdrawals are less
                         desirable and recharge areas of the South Jersey aquifers serving the Camden
                         metropolitan area are potentially threatened (DRBC,  1992). During drought
                         conditions, the Delaware River Basin Commission requires releases from the
                         upper basin reservoirs to prevent critical salinity concentrations from intruding
                         farther upstream than Philadelphia at RM 98 (DRBC, 1992). The transition zone,
                         extending about 26 miles from Marcus Hook (RM 79) to Artificial Island, New
                         Jersey (RM 53), is characterized by low salinity levels, high turbidity, and rela-
                         tively low biological production (Marino et al., 1991). The estuarine region extends
                         downstream of Artificial Island about 53 miles to the mouth of Lower Delaware
                         Bay; salinity in this region varies from approximately 8 ppt upstream to approxi-
                         mately 28 ppt at the mouth of the bay (Marino et al.,  1991).


                         Population, Water, and  Land  Use Trends

                              Four densely populated metropolitan areas have developed along a 50-mile
                         industrialized section of the Delaware River from Philadelphia, Pennsylvania, and
                         Trenton and Camden, New Jersey, to Wilmington, Delaware. From 1880 to 1980,
                         urban growth accounted  for most of the 236 percent increase in total population
                         of the region. The urban proportion of the population increased from approxi-
                         mately 64 percent at the turn of the century to  approximately 80 percent in 1980
                         (Marino et al., 1991). During the period after World War II from 1950 through
                         1980, development in the region was characterized by urban and suburban sprawl:
                         urban land use area increased from 460 square miles in 1950 to 3,682  square
                         miles by 1980 while population density declined from 8,000 to 3,682 persons per
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                                                                Chapter 7:  Delaware Estuary Case Study
square mile (Marino et al., 1991). Much of this development occurred by convert-
ing agricultural lands in close proximity to the major metropolitan areas to subur-
ban land uses.
     The Delaware River case study area includes 14 counties identified by the
Office of Management and Budget (1995) as the Philadelphia-Wilmington-
Atlantic City, PA-NJ-DE-MD Metropolitan Statistical Area (CMSA) (Table 7-1).
Long-term population trends from 1940 through 1996 for these counties are
presented in Figure 7-5. Population in these counties has increased by 162 percent
from 3.67 million in 1940 to 5.97 million by 1996 (Foretell, 1995;USDOC, 1998).
     The city of Philadelphia withdraws water for domestic water supply at the
Torresdale  intake upstream  of the salt front. The city of Trenton also withdraws
water for public water supply from the Delaware River. In addition to these cities,
Camden, the Delaware County Sewer Authority, and Wilmington are among more
than 80 dischargers of municipal wastewater directly to the estuary or the tidal
portions of its tributaries. Historical water use data are not readily available at the
county level of aggregation to assess the contribution of the Delaware estuary
  Table 7-1. Metropolitan Statistical Area (MSA) counties in the Delaware Estuary
  case study. Source: OMB, 1999.
     Philadelphia-Wilmington-
     Atlantic City, PA-NJ-DE-
     MD CMS A
Atlantic, NJ
Cape May, NJ
Burlington, NJ
Camden,  NJ
Gloucester,  NJ
Salem, NJ
Bucks, PA
Chester, PA
Delaware, PA
Montgomery, PA
Philadelphia, PA
Cumberland, NJ
New Castle, DE
Cecil, MD
                                                                              Figure 7-5
                                                                              Long-term trends in
                                                                              population for the
                                                                              Philadelphia-Wilmington-
                                                                              Atlantic City MSA counties
                                                                              of the Lower Delaware
                                                                              River-Delaware Bay.
                                                                              Source: Forstall, 1995;
                                                                              USDOC,  1998.
                 1940   1950   1960   1970   1980   1990   1996
                                                                                                 7-5

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment


                         region. However, long-term trends for municipal and industrial water withdrawals
                         have been compiled by the USGS for the entire Middle-Atlantic Basin from 1950
                         to 1995 (e.g., Solley et al., 1998). The natural resources (plankton, fisheries,
                         marshes, and shorebirds), human uses (waste disposal, transportation and dredg-
                         ing, beach development), and management issues of the Delaware estuary are
                         presented in Bryant and Pennock (1988).


                          Historical Water Quality  Issues

                              In reports sent back to Europe, Captain Thomas Young, one of the early
                         explorers of the Delaware estuary,  noted that  "the river ctboundeth with  bea-
                         vers, otters  and other meaner furrs .  . . I think few rivers of America have
                         more . . . the quantity offowle is so great as hardly can be believed. Offish
                         heere is plentie, but especially sturgeon. " Early  colonial advertising copy like
                         this, circulated widely in Europe, presumably inspired Old World colonists to
                         emigrate to the Delaware Valley (Sage  and Pilling, 1988). The estuary was
                         abundant with striped bass, sturgeon, shad, oysters, and waterfowl.
                              Beginning with the Industrial Revolution and the development of the Dela-
                         ware Valley as a major industrial and manufacturing center in the 19th  century,
                         waste disposal from increasing population and industrial activities resulted in
                         progressive  degradation of water quality and loss of the once-abundant natural
                          resources of the estuary. By the  turn of the century, the American shad popula-
                          tion had collapsed. By 1912-1914, low DO conditions were all too common in the
                          Philadelphia and Camden area of the river (Albert, 1997). Sanitary surveys
                          conducted in 1929 and 1937 documented poor water quality conditions in the
                          nontidal reaches of the Delaware from Port Jervis, New York, to Easton, Penn-
                          sylvania. During high-flow conditions, black water from the Lehigh River-Easton
                          area would result  in closing of the water supply intakes at Trenton, New Jersey
                          (Albert, 1982).
                              In the tidal river between Trenton and Philadelphia, the discharge of raw
                          sewage from Philadelphia, Trenton, Camden, Wilmington, and other communities,
                          along with untreated industrial wastewater discharges, resulted in gross water
                          pollution of the estuary. Peak densities of approximately 6,000-8,000 MPN/100
                          mL were recorded during the late 1960s and early 1970s in the vicinity of the
                          Philadelphia Navy Yard (RM 90) (Patrick et al., 1992; Marino  et al., 1991). Fecal
                          coliform bacteria levels were high as a result of raw or inadequately treated
                          wastewater discharges from the large municipalities. Acidic conditions from
                          industrial waste discharges were observed in the river near the Pennsylvania-
                          Delaware border; pH levels ranged from approximately 6.5 to 7.0 during 1968-
                          1970 in the  section of the river from Paulsboro (RM 89) to the Delaware Memo-
                          rial Bridge (RM 68) (Marino et al.,  1991). During the summer months  in the
                          1940s,  1950s, and 1960s, DO levels were typically approximately 1 mg/L or less
                          over a 20-mile section of the river from the Ben Franklin Bridge in Philadelphia
                          (RM 100) to Marcus Hook (RM 79). Under these anoxic and hypoxic  conditions,
                          the urban-industrial river ran black, and the foul stench of hydrogen sulfide gas
                          was a  common characteristic (Patrick, 1988). Dock workers and sailors were
                          often overcome by the stench of the river near Philadelphia, and ships suffered
                          corrosion damage to their hulls from the polluted waters. Aircraft pilots landing in
7-6

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                                                             Chapter 7:  Delaware Estuary Case Study
Philadelphia reported smelling the Delaware estuary at an altitude of 5,000 feet.
Water quality conditions were so bad that President Roosevelt ordered a study in
1941 to determine whether water pollution in the river was affecting the U.S.
defense buildup (Albert, 1982; CEQ, 1982).


Legislative  and Regulatory History

     Water pollution in the Delaware reached its peak in the  1940s. The source
of the pollution was raw sewage (350 mgd from Philadelphia alone), along with
untreated industrial wastewater of all kinds. In response to steadily increasing
pollution, the Interstate Commission on the Delaware River Basin (INCODEL)
launched a basinwide water pollution control program in the late 1930s. Following
a delay due to the war, the abatement program was finally completed by the end
of the 1950s. During that time the  number of communities with adequate sewage
collection and treatment facilities rose from 63 (approximately 20 percent) to 236
(75 percent) (Albert, 1982). Concurrent success was not achieved in abating
industrial pollution.
     The first generation of water pollution control efforts, largely completed by
1960, resulted in secondary treatment levels at most treatment plants above
Philadelphia. Primary treatment was considered adequate in the estuary below
Philadelphia. Although most areas built the required facilities, some treatment
facilities from the first-generation effort were not completed until the  1960s or
1970s.
     In 1961 INCODEL became incorporated into a more powerful interstate
regulatory agency, the Delaware River Basin Commission (DRBC). The DRBC,
created as a result of federal and state legislation, has broad water  resources
responsibilities, including water pollution control. The Commission developed a
clean-up program based on a 6-year $1.2 million Delaware Estuary Comprehen-
sive Study (DECS) conducted by the U.S. Public Health Service. Nearly 100
municipalities and industries were  found to be discharging harmful amounts of
waste into the river. The DRBC calculated the river's natural ability to assimilate
oxidizable wastewater loads and established allocations for each city and industry
(Thomann, 1963; Thomann and Mueller, 1987). The objective of the DRBC
wasteload allocation program and the corollary programs of Pennsylvania, New
Jersey, Delaware, and the federal government was to upgrade the somewhat
improved water quality of 1960 to more acceptable levels.
     For the purposes of water quality management, the Delaware estuary has
been divided into six water quality zones. Zone 1  is above the fall line at Trenton,
New Jersey. Zones 2 through 6 are in the tidal Delaware, which is water quality-
limited. Here, more stringent effluent limits are required, based on allocations of
assimilative capacity, to achieve water quality standards. Based on the DECS
model, the DRBC in 1967 adopted new, higher water quality standards and then in
1968 issued wasteload allocations  to approximately 90 dischargers to the estuary.
These required treatment levels were more stringent than secondary treatment as
defined by EPA in the 1972 Clean Water Act.
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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment


                         Impact of Wastewater Treatment:

                         Pollutant Loading  and  Water  Quality

                         Trends

                             The Delaware River from Trenton, New Jersey, to Listen Point is one of the
                         most heavily industrialized sections of a waterway in the United States. Four
                         major cities and a large number of oil refineries and chemical manufacturing
                         plants are located along the river. The effect of the DRBC wasteload allocation
                         program and the related water pollution control programs of Pennsylvania, New
                         Jersey, Delaware, and the federal government on the Delaware Estuary is best
                         demonstrated by the substantial reduction of ultimate CBOD loading from munici-
                         pal and industrial dischargers that has been achieved since the late 1950s (Figure
                         7-6). Ultimate CBOD loadings to the estuary have been reduced by 89 percent
                         from 1,136,000 Ib/day in 195 8 (Patrick etal., 1992) to 128,277 Ib/day by 1995
                         (HydroQual, 1998). Major wastewater treatment facilities that upgraded to
                         secondary treatment and better to meet the wasteload allocations include Phila-
                         delphia NE (1985), Philadelphia SE (1986), Philadelphia SW (1980), CCMUA
                         (1989), Trenton (1982), Bordentown MUA (1991), and Lower Bucks MA (1980).
                         A complete listing of the 34 municipal and 26 industrial point sources discharging
                         to the Delaware estuary between Trenton  and Liston Point is presented by
                         HydroQual (1998). In addition to reductions of pollutant loading from direct
                         dischargers to the estuary, the cleanup of major tributaries to the Delaware has
                         also contributed to water quality improvements in the Delaware estuary (Albert,
                         1982).
                             Since implementation of the 1972 CWA, reductions in point source loads of
                         oxidizable materials have been achieved as a result of technology- and water
                         quality-based effluent controls on municipal and industrial dischargers in the
                         Delaware River watershed. Nonpoint source runoff,  driven by the land uses and
                         hydrologic characteristics of the watershed, also contributes a pollutant load that
                         must be considered in a complete evaluation of the impact of regulatory policy
                         and controls on long-term water quality trends. To evaluate the relative signifi-
Figure 7-6
Long-term trends in
ultimate CBOD loading
from municipal and
industrial wastewater
dischargers to the
Delaware estuary.
Sources: HydroQual, 1998;
Patrick et al, 1992.

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a
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1
III
                                        1940    1950    1960    1970    1980   1990    2000
                                                      Municipal |   | Industrial
7-8

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                                                               Chapter 7: Delaware Estuary Case Study
cance of point and nonpoint source pollutant loads, inventories of NPDES point
source dischargers, land uses, and land use-dependent export coefficients
(Bondelid et al., 1999) have been used to estimate catalog unit-based point source
(municipal, industrial, and CSOs) and nonpoint source (rural and urban)1 loads of
BOD5 for mid-1990s conditions in the catalog units of the Delaware River case
study area (see Figure 7-2). The point source load of 105.4 metric tons/day
accounts for 89 percent of the total estimated BOD5 load of 117.1 metric tons/day
from point and nonpoint sources. Municipal facilities contribute 57.3 metric tons/
day (49 percent) while industrial dischargers account for 47.5 metric tons/day (40
percent) of the total point and nonpoint source BOD5 load (Figure 7-7). Nonpoint
sources of BOD5 account for 12.6 metric tons/day; rural runoff contributes
approximately 8 percent and urban  land uses account for approximately 5  percent
of the total point and nonpoint load of 117.1 metric tons/day (Figure 7-7).
     One of the major trends indicative of water quality improvement in the
estuary has been that for DO. A comparison of mean summer DO levels be-
tween 1968-1972,1975-1979,1981-1985, and 1988-1994 (Figure 7-8) clearly
shows the water quality improvements achieved as a result of the point source
loading reductions of ultimate BOD5 (Figure 7-6). Mean summer DO concentra-
tions have increased by approximately 1 mg/L between River Mile 110 and River
Mile 55 (DRBC Zones 3, 4, and 5) between 1957-1961 and 1981-1985 (Brezina,
1988).  DO concentrations have increased from less than 2 mg/L to 5 mg/L at the
critical DO sag point at the mouth of the Schuylkill River in Philadelphia (RM 92)
during the period from 1968-1972 to 1988-1994. DO concentrations increased
steadily farther downstream of Philadelphia (RM 83), reaching a level of approxi-
mately 5.5 mg/L during  1988-1994.
     The historical summer DO spatial transects data (Figure 7-8) show that
wastewater discharges from the Philadelphia area result in minimum DO condi-
tions between the Ben Franklin Bridge (RM 100), the Philadelphia Navy Yard
(RM 93), and Marcus Hook (RM 78). Figure 7-9 shows long-term summer (July-
        URBAN-NPs4%

              cso|i%


       IND:MAJ+MIN


        MUNICIPAL
            Figure 7-7
            Point and nonpoint source
            loads of BOD5 (ca. 1995)
            for the Lower Delaware
            River-Delaware Bay case
            study area.
            Source: Bondelid et al.,
            1999.
                                 25               50
                                BODS Load (metric tons/day)
75
  1 For purposes of this comparison, urban stormwater runoff includes areas both outside (termed
   "nonpoint sources") and within (which meet the legal definition of a point source in section
   502(14) of the CWA) the NPDES stormwater permit program.
                                                                                                7-9

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
Figure 7-8
Long-term trends of the
spatial distribution of
summer DO in the
Delaware estuary.
Source: Patrick et a/.,
1992; Scally,  1997.
                                  -150      -125      -100      -75        -50       -25
                                              River Miles from Cape May-Cape Henlopen
                          September) trends in DO measured at stations within the reach from the Ben
                          Franklin Bridge to the Philadelphia Navy Yard. The long-term trend documents
                          improvements in oxygen during the 1980s and 1990s from the water pollution
                          control efforts initiated during the 1970s. Most dramatic, however, is the progres-
                          sive improvement in the minimum oxygen levels during the 1980s and early 1990s.
                          Summer minimum values increased from approximately 1 mg/L or less in the
                          1960s and 1970s to approximately 4-5 mg/L during 1990-1995. Although oxygen
                          conditions improved tremendously between the 1960s and the early 1990s, a
                          continued trend of further improvements during the 1990s has not been recorded.
                          Minimum oxygen concentrations still can approach 4 mg/L near Chester, Pennsyl-
                          vania (River Mile 84) and can drop lower than 4 mg/L in the 10-mile oxygen sag
                          reach between River Mile 95 and River Mile 85 (HydroQual, 1998).
                               Spatial water quality trends recorded during the late 1960s, 1970s, 1980s,
                          and 1990s include documentation of temporal declines in BOD5 (Figure 7-10),
                          ammonia-N (Figure 7-11), total nitrogen (Figure 7-12), and total phosphorus
                          (Figure 7-13). Effluent reductions of oxygen-demanding loads from industrial and
Figure 7-9
Long-term trends of
summer (July-September)
DO in the Delaware
estuary near Philadelphia,
PA (RF1-02040202030,
mile 100-80).
Source: USEPA (STORET).
                                     T940
1950
  1960      1970     1980     1990     2000
Philadelphia PA [River Mile 100-80]
                                                        Mean	Mm  	Max
7-10

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                                                            Chapter 7: Delaware Estuary Case Study
 8005
("19/0
    6

    5

    4

    3

    2

    1


    o-l
      40
  YEAR
                 80   100   120   MO  160   180   200   220

                           River Kilometer

               1968-1970     	1978-1980     	1988-1990
                                                                  Figure 7-10
                                                                  Long-term trends of the
                                                                  spatial distribution of BOD5
                                                                  in the Delaware estuary
                                                                  (mean of data from 1968-
                                                                  1970, 1978-1980, and
                                                                  1988-1990).
                                                                  Source: Marino et al.,  1991.
NH3-N
(mg/i)
  1.6
  1,5
  1,4
  1.3
  1.2
  l.l-
  1.0
  0.9
  0.8
  0.7
  0.6
  0.5
  0.4
  0.3
  0.2
  0
    1
  o.o-
      1—
      40
—1—
 60
—I—
 80
—I—
 100
  YEAR
               1968-1970
'	1	'	1	'	1	•
  120   140   160

River Kilometer

  	 1978-1980
—1	.	1	,	1-

 180   200   220
                                                	 1988-1990
                                                                  Figure 7-11
                                                                  Long-term trends of the
                                                                  spatial distribution of
                                                                  ammonia-nitrogen in the
                                                                  Delaware estuary (mean of
                                                                  data from  1968-1970,
                                                                  1978-1980, and 1988-
                                                                  1990).
                                                                  Source: Marino et al., 1991.
 To». N
(mg/l)
     5
    3


    2'


    1
    Oi
      40    60    80   100   120   140   160   180   200   220

                          River Kilometer

  YEAR   	  1968-1970     	  1978-1980     	 1988-1990
                                                                 Figure 7-12
                                                                 Long-term trends of the
                                                                 spatial distribution of total
                                                                 nitrogen  in the Delaware
                                                                 estuary (mean of data from
                                                                 1968-1970, 1978-1980,
                                                                 and 1988-1990).
                                                                 Source: Marino et al.,  1991.
                                                                                               7-11

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
Figure 7-13
Long-term trends of the
spatial distribution of total
phosphorus in the
Delaware estuary (mean of
data from 1968-1970,
1978-1980, and 1988-
1990).
Source: Marino et a/., 1991.
                                   TPhos
0.50

0.45
0.40
0.35'
0.30
0.25
0.20
0.15H
0.10
0.05
0.00
                                        40    60    80   100  120   140   160   180   200   220

                                                            River Kilometer

                                          	  1968-1970    	  1978-1980     	 1988-1990
                          municipal sources have resulted in significant declines in ambient levels of BOD5
                          and ammonia-N. An interannual temporal trend for ambient ammonia-N (Figure
                          7-14) at a station near Marcus Hook (RM 78) shows a considerable improvement
                          in water quality, with a steep decline from approximately 1.4 mg N/L during the
                          late 1960s to approximately 0.5 mg N/L by the late 1970s, followed by relatively
                          unchanging ambient concentrations (approximately 0.15 mg N/L) recorded during
                          the mid-1980s through the mid-1990s (Santoro, 1998). The decline in ambient
                          ammonia-N during this 30-year period has been shown to correspond to a concur-
                          rent increase in nitrate-N from the mid-1970s through the mid-1980s as a result of
                          nitrification (Santoro, 1998; Marino et al., 1991). Reflecting deforestation, agricul-
                          tural practices, fossil fuel combustion, and the increase in human population of an
                          increasingly urbanized drainage basin over the much longer time scale of a
                          century, ambient nitrate and chloride levels (Figure 7-15) have steadily increased
                          by approximately 400 percent to 500 percent since measurements were first
                          recorded in 1905 at a water supply intake near Philadelphia (Jaworksi and
                          Hetling, 1996). Similar patterns of long-term increasing trends in ambient nitrate
Figure 7-14
Long-term trends of
summer ammonium-N
and total phosphorus at a
station in the Delaware
estuary near Marcus Hook
(mile 78)  (computed as 4-
year moving averages for
July from DRBC boat run
records).
Source: Santoro, 1998.
                                     1965   1970   1975   1980   1985   1990   1995   2000
7-12

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                                                            Chapter 7: Delaware Estuary Case Study
                              -Chlorides-
                                       -N03
    32.0
                                                                1.60
                                                                1.40
     0.0
                                                                0.00
                                  Years
and chlorides have also been recorded at other east coast water supply intakes
for the Merrimack, Connecticut, Hudson, Schuykill, and Potomac rivers (Jaworksi
and Hetling, 1996). Total phosphorus has also declined from peak levels of
approximately 0.45 mg P/L during 1968-1970 to much lower levels of approxi-
mately 0.15 mg P/L by 1988-1990 near River Mile 100 (Figure 7-13). An
interannual time series of total phosphorus (Figure 7-14) for a station near Marcus
Hook (River Mile 78) exhibits a trend similar to that of ammonia-N with a sharp
decline from approximately 0.8 mg P/L in the late 1960s to approximately 0.3 mg
P/L by the late 1970s, followed by relatively unchanging concentrations (approxi-
mately 0.1 mg P/L) from the mid-1980s through the mid-1990s. The decline of
ambient levels of total phosphorus has been attributed to the detergent phosphate
ban of the early 1970s (Jaworski,  1997), reductions of effluent loads from waste-
water facility upgrades (Sharp, 1988), and changes in partitioning of dissolved and
soluble phases of phosphorus and  changes in solubility of phosphate (Lebo and
Sharp, 1993).


Evaluation  of Water Quality Benefits

Following Treatment  Plant  Upgrade

     From a policy and planning perspective, the central question related to the
effectiveness of the secondary treatment requirement of the 1972 CWA is simply
Would water quality standards for DO be attained if primary treatment levels
were considered acceptable?  In addition to the qualitative assessment of
historical data, water  quality models can provide a quantitative approach to
evaluate improvements in DO and other water quality parameters achieved as a
result of upgrades in  wastewater treatment. Since the early 1960s, four classes of
water quality models, developed from the 1960s, through the 1990s, have been
applied to determine waste load allocations for municipal and industrial discharg-
ers to meet the needs for water quality management decisions for the Delaware
estuary (Mooney et al., 1998).
Figure 7-15
Long-term trends of
chlorides and nitrate-N at a
water supply intake in the
tidal Delaware River near
Philadelphia.
Source: Jaworski and
Hetling, 1996; Jaworski,
1997.
                                                                                          7-13

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment


                              During the 1960s, one-dimensional estuarine water quality models of DO
                         and carbonaceous and nitrogenous BOD were developed by Thomann (1963),
                         O'Connor et al., (1968), Pence et al. (1968), Jeglic and Pence (1968), and Feigner
                         and Harris (1970). DRBC used a 1960s era model, known as the Delaware
                         Estuary Comprehensive Study (DECS) model, to establish waste load allocations
                         for ultimate CBOD and nitrogenous BOD for the six zones of the Delaware.
                              With funding available from the CWA Section 208 program during the 1970s,
                         Clark et al. (1978) upgraded the kinetics of the water quality model to incorporate
                         nitrification and denitrification in a nitrogen cycle represented by organic nitrogen,
                         ammonia, and nitrate+nitrite as state variables. The oxygen contribution by algal
                         production and respiration was included as an empirical input term dependent on
                         chlorophyll observations. Transport was provided to the water quality model with
                         one-dimensional link-node hydrodynamics, and the 1970s-era model was identified
                         as the Dynamic Estuary Model (DEM) (Mooney et al., 1998).
                              As a result of industrial and municipal waste treatment plant upgrades from
                         primary to secondary levels of treatment during the late 1970s and early 1980s,
                         the water quality model used for waste load allocations was once again upgraded
                         to reflect the reduced waste loads and improvements in water quality conditions
                         (Mooney et al., 1998). The model was upgraded from a one-dimensional (longitu-
                         dinal) to a two-dimensional representation (longitudinal and lateral) variation of
                         water quality and transport in the Delaware estuary. A two-dimensional hydrody-
                         namic model was coupled with a water quality model that retained the kinetic
                         framework of the one-dimensional model with kinetic coefficients adjusted to
                         reflect changes in pollutant loading (LTI, 1985).  The upgraded  1980s-era two-
                         dimensional model (DEM-2D) was used to conduct a toxics analysis (Ambrose,
                          1987) and to reevaluate the waste load allocations developed with the earlier
                         models  (DRBC, 1987).
                              Following the completion of the Delaware Estuary Use Attainability (DEL
                         USA) Project (DRBC, 1989), a technical review of the two-dimensional DEM
                         model recommended that a new time-variable model be developed to incorporate
                         state-of-the-art advances, with a three-dimensional hydrodynamic model coupled
                         to an advanced eutrophication model framework (HydroQual, 1994). Using
                         revised  kinetic coefficients to reflect reductions in waste loads and improvements
                         in water quality, the kinetics of the water quality framework were expanded to
                         include  a eutrophication submodel, nitrogen and phosphorus cycles, labile and
                         refractory organic carbon, and particulate and dissolved fractions of organic
                         carbon and nutrients (HydroQual, 1998; Mooney et al., 1999). Unlike the
                         eutrophication model developed for the Chesapeake Bay (Cerco and Cole, 1993),
                         internal coupling of particulate organic matter's deposition with sediment oxygen
                         demand and benthic nutrient  fluxes was not included in the upgraded framework;
                         benthic  fluxes were assigned as model input on the basis of monitoring data
                         (HydroQual,  1998).
                              To evaluate the incremental improvements in water quality conditions that
                         can be achieved by upgrading municipal wastewater facilities from primary to
                         secondary and better-than-secondary levels of waste treatment, Lung (1991)  used
                         the 1970s-era one-dimensional DEM model (Clark et al., 1978) to demonstrate
                         the water quality benefits attained by the  secondary treatment requirements of the
                          1972 CWA. Using the model, Lung used existing population and municipal and
                         industrial wastewater flow and effluent loading data  (ca. 1976) to compare water
7-14

-------
                                                               Chapter 7: Delaware Estuary Case Study
quality for summer flow conditions simulated with three management scenarios
for municipal facilities: (1) primary effluent, (2) secondary effluent, and (3)
existing wastewater loading. Water quality conditions for these alternatives were
calibrated (Figure 7-16) using data for 1976, a year characterized by average
summer flow of the Delaware River (see Figure 7-3). Freshwater flow at Tren-
ton, New Jersey, was 7,700 cfs; flow in the Schuykill River, a major tributary to
the Delaware estuary, was 1350 cfs for the 1976 calibration. Flow conditions
during the summer of 1976 were 120 percent higher than the long-term (1951-
1980) summer (July-September) mean streamflow of 5,986  cfs recorded at
Trenton. Upstream of Trenton, flow releases from several impoundments along
the free-flowing Delaware River are regulated to maintain the guideline for a
minimum summer streamflow of 2,500 to 3,000 cfs at Trenton (Mooney et al.,
1998).
(a)
(b)
(C)
(d)
          140   130   120   110    100   90    80    70   60    50    4-0
          140    130   120   110    100   90    80    70   60    50    40
          140    130   120   110    100   90    80    70   60    50    40
         10

      < 8
       £ 6
      X-**
      § *
          140   130   120   110    100   90    80    70    60    50    40
                              River Miles from Mouth
           Legend:   $ Observed Data (Avg. and Range)  	Model Results
Figure 7-16
Model vs. data comparison
for calibration of the 1 -D
Dynamic Estuary Model
(DEM) for the Delaware
estuary to July 1976
conditions for:
(a) ammonia, (b) nitrate,
(c) CBOD5, and (d) DO.
Source: Lung, 1991.
                                                                                               7-15

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
                               Under the primary effluent assumption, water quality is noticeably deterio-
                          rated in comparison to the 1976 calibration results. DO concentrations are at a
                          minimum about 35 miles downstream of Trenton, the traditional region of mini-
                          mum DO levels. Under the primary scenario, an oxygen sag of 2 mg/L is com-
                          puted by the model under summer (28EC), low-flow 7Q10 conditions (2,500 cfs
                          for the Delaware at Trenton and 285 cfs for the Schuykill River at Philadelphia)
                          (Figure 7-17).
                               Using the secondary effluent assumption, the reduction in ultimate CBOD
                          loading significantly improves DO downstream of Philadelphia at the critical
                          oxygen sag location (RM 96). In comparison to the primary scenario, minimum
                          oxygen levels increased to almost 4 mg/L from approximately 2 mg/L under the
Figure 7-17
Comparison of simulated
water quality impact of
primary, secondary, and
existing (1976) wastewater
loading conditions on
(a) ammonia, (b) nitrate,
(c) CBOD5, and (d) DO in
the Delaware Estuary,  July
1976 conditions.
Source: Lung, 1991.
(a)
(b)
                            (c)
                            (d)
  3.0
O2.5
 |"2.0
Vt5
 11.0
10.5
  0.0
                                  J>.0

                                  £2.0
                                   l_
                                  •+->
                                  21.0
                                    0.0
                                     10
                                   8
          140   130   120   110    100   90    80    70   60    50    40
        5.0
                                      140   130   120   110   100    90   80    70    60   50    40
                                      HO   130    120   110   100   90   80    70    60    50   40
                                      140   130   120    110   100   90    80   70    60    50   40
                                                           River Miles from Mouth
                                  Legend:  	Primary Treatment	Secondary Treatment 	 1976 Loads
7-16

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                                                            Chapter 7: Delaware Estuary Case Study
          10
          5-
                      2.0
                    Primary       Secondary     Existing 1976
                            Municipal Effluent Scenario
Figure 7-18
Model simulation of DO
under July 1976 "normal"
streamflow conditions at
the critical oxygen sag
location (mile 96) in the
Delaware estuary for
primary, secondary and
existing (1976) effluent
loading scenarios.
Source: Lung, 1991.
secondary effluent scenario (Figure 7-18). To achieve compliance with a water
quality standard of 5 mg/L, advanced waste treatment is required (Albert, 1997).
As shown with the historical water quality data sets, the implementation of
secondary and better-than-secondary levels of wastewater treatment has resulted
in major improvements in the DO, BOD5, ammonia, and total phosphorus of the
estuary (Figures 7-8 through 7-14). As demonstrated with the model, better-than-
secondary treatment is required to achieve compliance with the water quality
standard of 5 mg/L for DO downstream of Philadelphia. In contrast to the 1950s
and 1960s, the historical occurrence of persistent and extreme low DO conditions
has essentially been eliminated from the upper Delaware estuary. Improvements
in suspended solids, heavy metals, and fecal coliform bacteria levels have also
been achieved as a result of upgrades in municipal and industrial wastewater
treatment.


Impact  of  Wastewater Treatment:

Recreational and  Living Resources

Trends

     With vast tidal marshes and freshwater tributaries providing spawning and
nursery grounds for abundant fishery resources, the coastal plain of the Delaware
estuary provided a cornucopia of fishery and waterfowl resources important for
sustenance to both Native American villages and colonial settlements. Historically,
the estuary produced an enormous quantity of seafood from the early colonial era
(ca. 1700s) through the early 20th century. Colonial reports suggest schools of
herring and sheepshead thick enough to walk on in a stream (Price et al., 1988).
Rich harvests of American shad and shortnose sturgeon provided important
sustenance to the growing population of the Delaware valley for about 200 years.
     Since the mid-1900s, however, the abundance of these, and other, species
has declined dramatically as a result of urbanization and industrialization of the
drainage basin. Deterioration in water quality (e.g., severe oxygen depletion),
                                                                                          7-17

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment


                          overfishing, construction of dams, and habitat destruction have all contributed to
                          the decline of the river's fisheries resources beginning around the turn of the
                          century (Majumdar et al, 1988). Massive fish kills were a frequent occurrence
                          along the river from about 1900 through 1970 (Albert, 1988). Former wetlands
                          and tributaries, critical to the spawning success of anadromous species, have been
                          converted into docks, wharves, industrial sites, and oil refineries (Stutz, 1992).
                               Decades of discharge of untreated municipal and industrial  waste resulted in
                          severe declines in the once-abundant fishery resources of the Delaware estuary.
                          In 1836 commercial landings of the American shad (Alosa sapidissima), an
                          important anadromous fish that spawns in the Upper Delaware River, were
                          estimated at 10.5 million pounds. By the turn of the century, the average annual
                          harvest of shad was 12-14 million pounds (Frithsen et al., 1991). Historically, the
                          commercial shad harvest from the Delaware River fishery was the largest of any
                          river system along the Atlantic coast (Frithsen et al., 1991). Primarily as a
                          consequence of overfishing, water pollution and low levels of DO that created a
                          "dead zone," construction of dams, and other obstructions in the river, shad
                          populations declined drastically in the early  1900s (Frithsen et al., 1991).
                               In a pattern similar to that for shad, annual commercial landings of striped
                          bass (Morone saxatilis) have also dropped  from hundreds of thousands of
                          pounds per year in the early 1900s to only thousands of pounds per year by 1960.
                          In 1969 a fishery survey showed a complete absence of striped bass larvae and
                          eggs along the Philadelphia-Camden waterfront, which had been an important
                          spawning and nursery area for striped bass; by 1980 there was no commercial
                          catch of striped bass (Himchak, 1984).
                               The historical abundance of shortnose sturgeon (Acipenser brevirostrum),
                          once prized for caviar that rivaled imported  Russian caviar, also followed the
                          same precipitous decline as shad as overfishing and water pollution took their toll
                          on this once-thriving fishery. Historically, the range of the shortnose sturgeon was
                          from the lower Delaware Bay as  far upstream as New Hope, Pennsylvania (RM
                          149) (Frithsen et al., 1991). Historical records from 1811  to 1913  document 1,949
                          sturgeon captured, primarily as a bycatch of the shad gill net fishery. During the
                          period from 1913 through 1954, no  documented catches of sturgeon were re-
                          ported. From 1954 through 1979,  37 sturgeon were reported in fishery and
                          ecological surveys. From 1981 to 1984, 1,371 sturgeon were collected between
                          Philadelphia and Trenton (Frithsen et al., 1991). Using data collected from the
                          early 1980s surveys, Hastings et al. (1987) have estimated populations of approxi-
                          mately 6,000 to 14,000 adult shortnose sturgeon in the upper tidal river near
                          Trenton, with a smaller population estimated for the section of the river near
                          Philadelphia (Frithsen et al., 1991).
                               Although it is difficult to assess the relative importance  to these species of
                          each of the major industrialization factors that contributed to the declines, Sum-
                          mers and Rose (1987) identified a connection between water quality, especially
                          DO concentrations, and wastewater loading and shad population levels. Using
                          records collected during the 20th  century from the Delaware, Potomac, and
                          Hudson estuaries, historical fluctuations in American shad populations have been
                          strongly correlated with wastewater discharges that increased biochemical
                          oxygen demand levels and depleted oxygen resources (Summers and Rose,
                          1987). Albert (1988) and Sharp and Kraeuter (1989) also noted the importance of
                          good oxygen concentrations to successful shad migrations. Little correlation
7-18

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                                                                Chapter 7: Delaware Estuary Case Study
between water quality and striped bass populations was found, but Summers and
Rose (1987) noted that larval survival for both shad and striped bass is tied to DO
and other water quality factors.
     Beginning in the mid- 1970s, however, the water pollution control efforts of
the 1970s and 1980s have paid off with a dramatic recovery of once moribund
fishery resources. Estimates of the American shad population fluctuated from a
low of 106,202 in 1977 to a high of 882,600 in 1992 (Santoro, 1998) (Figure 7-19).
As a result of improvements in water quality conditions, the spawning area used
by shad has increased by 100 miles in the estuary (Albert, 1997). Annual shad
festivals are now celebrated in the spring along the Delaware River, and the
recreational shad fishery is considered to be a multimillion-dollar industry (Frithsen
et al., 1991). As a result of water pollution control efforts and a well-regulated
fishery, populations of striped bass in the Delaware River are also showing
evidence of a resurgence of once-depleted populations (Santoro, 1998). Assess-
ments of commercial harvest statistics for American shad (Figure 7-20), striped
I.UV
^ n -7CL
n Method)(n
3 C
?....?
ion (Peterse
3 C
*. . . .8:
£
nnn.



ihlil







1












                                                                               Figure 7-19
                                                                               Long-term trends in
                                                                               population estimates of
                                                                               adult American shad in the
                                                                               Delaware estuary.
                                                                               Source: Santoro, 1998.
                  1975 '  '  ' i960
i98'5 '  '  '  1990 '  '  '  1'995
                                                                               Figure 7-20
                                                                               Trends in catch efficiency
                                                                               for American shad in the
                                                                               Delaware estuary.
                                                                               Source: Weisberg et al.,
                                                                               1996.
           1980
                            1985
        1990
                                                                1995
                                                                                                 7-19

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
                           bass (Figure 7-21), and white perch (Figure 7-22) clearly document significant
                           increases in the catch-per-unit effort of these species from 1985 to 1993, corre-
                           lated with improvements in water quality (Weisberg et al., 1996). Trends in catch
                           efficiency are also reported by Weisberg et al. (1996) for blueback herring and
                           alewives. Studies of the distribution and abundance of the shortnose sturgeon,
                           listed as an endangered species (Price et al.,  1988), suggest that populations may
                           be recovering from the historical decimation of this species during the 20th
                           century from water pollution and overfishing (Fristhsen et al., 1991).
                                In addition to pelagic fishery resources, the Delaware estuary has histori-
                           cally provided important harvests of American oysters, blue crabs, horseshoe
                           crabs, hard clams, and American lobsters. Following a pattern identified in New
                           York Harbor, a sharp decline in the harvest of oysters during the  1950s has been
                           attributed to overfishing, sediment runoff and industrialization of the watershed,
                           industrial and municipal wastewater discharges, oil spills, and spraying of marshes
                           with DDT for mosquito control (Frithsen et al.,  1991). In 1957 a parasitic organ-
                           ism (MSX) infected the oyster beds, drastically reducing abundance for decades.
Figure 7-21
Trends in catch efficiency
for striped bass in the
Delaware estuary.
Source: Weisberg et al.,
1996.
                                      10.0
                                      0.0^
                                        1980
                                                          1985
                                                                           1990
1995
Figure 7-22
Trends in catch efficiency
for white perch in the
Delaware estuary.
Source: Weisberg et al.,
1996.
                                                          1985
                                                                            1990
                                                                                             1995
7-20

-------
                                                              Chapter 7:  Delaware Estuary Case Study
       o
       0)


       I
          0.0
                                                                            Figure 7-23
                                                                            Long-term trends of
                                                                            commercial blue crab
                                                                            catch in the Delaware
                                                                            estuary (New Jersey and
                                                                            Delaware totals).
                                                                            Source: Patrick et al.,
                                                                            1992.
           1940
1950
1960
1970
1980
1990
2000
With the decline of the oyster harvest, the blue crab catch has accounted for most
of the shellfish catch of the Delaware estuary. During the late 1800s through the
1930s few blue crabs were harvested commercially. Since the 1930s, commercial
landings have increased substantially, particularly during the 1980s (Figure 7-23),
although large interannual variability in the Delaware estuary is characteristic of
this species sensitive to water temperature (Frithsen et al., 1991). More detailed
reviews of historical trends for the shellfish and fishery resources of the Dela-
ware estuary are given by Price et al. (1988), Patrick (1988), Patrick et al.
(1992), and Frithsen et al. (1991).


Summary and  Conclusions

     During the 1940s, 1950s and 1960s, the Delaware estuary was character-
ized by severe water quality problems, including the foul stench of hydrogen
sulfide gas caused by anoxic conditions in sections of the river near Philadelphia.
Uncontrolled wastewater discharges and destruction of habitat from urban and
industrial growth in the Delaware watershed were responsible, along with over-
fishing, for the collapse of many historically important fisheries in the Delaware
estuary such as American shad, striped bass, shortnose sturgeon, and American
oysters.  Desirable amenities such as parks, walking trails, or cafes along the
riverfront were not considered for urban development because of the noxious
conditions of the Delaware River.
     As a result of water pollution control efforts implemented since the late
1960s in the Delaware  estuary, dramatic reductions in municipal and industrial
effluent discharges of ultimate CBOD, ammonia-N, total phosphorus, and fecal
coliform bacteria have been achieved by upgrading wastewater treatment facili-
ties to secondary and better-than-secondary  levels of treatment. Municipal and
industrial loading of ultimate CBOD to the river, for example, was reduced by 89
percent during the period from 1958 to 1995.
     New construction and upgrades of municipal and industrial water pollution
control facilities have resulted in significant improvements in water quality, the
resurgence of important commercial and recreational fishery resources, and a
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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment


                          renewal of economic vitality to once abandoned urban waterfronts along the
                          Delaware River.
                              Assessment of long-term trends of historical water quality data at critical
                          locations clearly documents great improvements in DO, ammonia-nitrogen, total
                          phosphorus, and fecal coliform bacteria. DO, for example, has improved from
                          typical summer minimum levels of less than 1 mg/L during the 1960s and 1970s
                          along a 10-mile section of the river downstream from Philadelphia to minimum
                          levels  of 4 mg/L and higher during the 1990s. Ambient ammonia concentrations
                          near Marcus Hook have declined by an order of magnitude from late 1960s levels
                          of approximately 1.4 mg N/L to mid-1990s levels of approximately 0.15 mg N/L.
                          Total phosphorus has exhibited a trend similar to ammonia's with late 1960s levels
                          of approximately 0.8 mg P/L dropping almost an order of magnitude to approxi-
                          mately 0.1 mg P/L during the mid-1990s.
                              A number of indicators of environmental resources  of the Delaware estuary
                          have also demonstrated tremendous improvements that can be attributed to the
                          water pollution control efforts and associated public awareness of the importance
                          of environmental quality initiated by the 1972 CWA. The  recovery of the Ameri-
                          can shad population during the mid-1980s, for example, is a remarkable achieve-
                          ment.  The restoration of this important fishery resource to populations that can
                          support an extensive recreational and commercial fishery is a remarkable success
                          story. Highly popular annual shad festivals now celebrate  the  seasonal migration
                          of this fish from the ocean into the estuary as a rite of spring.
                              Although the restoration of valuable fishery resources is important from an
                          economic and ecological perspective, the recreational benefits achieved by the
                          cleanup of the Delaware River far exceed the benefits attributed to fishery
                          improvements. Riverfront development for commercial uses and public parks,
                          increases in sailing and boating, and numerous other economic benefits have
                          occurred along the Delaware River. Most remarkable is that  the city centers of
                          Philadelphia, Wilmington, and Trenton, after decades of urban development
                          activity retreating inland, are now moving back toward the riverfront.  Investments
                          in urban development along the river would simply not be feasible without the
                          aesthetic qualities of clean water (Albert, 1997). Urban waterfront and riverfront
                          development activity has also been booming in many other cities (e.g., New York
                          Harbor; Cleveland, Ohio; Boise, Idaho; Portland, Oregon; Atlanta, Georgia;
                          Richmond, Virginia) that have successfully cleaned up polluted rivers, lakes, and
                          harbors, making their urban waterways assets and sources of civic pride rather
                          than disgraceful liabilities.
                              Despite the remarkable environmental improvements achieved by invest-
                          ments in water pollution control infrastructure since initiation of the 1972 CWA,
                          challenges remain for the next generation. Water quality  and resource manage-
                          ment problems recognized only since the mid-1980s must be  addressed. Contami-
                          nation of the water column and sediments by heavy metals such as mercury,
                          chromium, lead, copper, and zinc has been identified in urban-industrial areas of
                          the river.  Probable sources of heavy metals include natural geochemical pro-
                          cesses, industrial and municipal dischargers, stormwater runoff, and atmospheric
                          deposition (Santoro, 1998). Toxic chemicals such as PCBs, PAHs, and pesticides
                          have also contaminated the water column and sediments of the estuary, resulting
                          in bioaccumulation in benthic organisms. Fish consumption advisories were issued
                          in 1989 by New Jersey  and Pennsylvania and in 1996 by Delaware (Santoro,
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                                                              Chapter 7:  Delaware Estuary Case Study
1998). Acute sediment toxicity appears to be more widespread in the estuary than
previously documented, with the highest areas of sediment toxicity identified in the
heavily urbanized and industrialized region between Torresdale and Marcus Hook.
Chronic toxicity was also identified in the water column under particular condi-
tions of streamflow and effluent discharges (Santoro, 1998). The design and
construction of facilities to control and treat combined sewer overflow discharges
of raw sewage to the tidal river during heavy rainstorms is an ongoing project.
Finally, the allocations of wastewater loads for ultimate CBOD from municipal
and industrial dischargers that have evolved since 1968 will need to be revised to
ensure that the water  quality improvements  achieved since the  1970s can con-
tinue to be maintained as population and industrial activity grow during the 21st
century (Mooney et al.,  1999; HydroQual, 1998).
     In  1973 a USEPA study concluded that the Delaware River would never
achieve designated uses defined by "fishable standards."  More than 25 years
after that pessimistic  pronouncement, the fishery resources of the Delaware
estuary are thriving. The restoration of the vitality of the estuary is a direct result
of water pollution control efforts and strong public awareness of the importance
of supporting federal, state, and local environmental regulations and policies.


References

Albert, R.C.  1982.   Cleaning up the Delaware River. Status and progress
    report prepared under the auspices of Section 305(b) of the Federal Clean
    Water Act. Delaware River Basin Commission, West Trenton, NJ.
Albert, R,C. 1988. The historical context of water quality management for the
    Delaware estuary. Estuaries 11(2): 99-107.
Albert, R.C. 1997. Delaware River Basin Commission, West Trenton, NJ.
    Personal communication, July 31,1997.
Ambrose, R.B. 1987. Modeling volatile organics in the Delaware estuary. Jour.
    Environ. Eng. ASCE 113(4): 703-721.
Bondelid, T., C. Griffiths, and G. Van Houten.  1999.  A national water pollution
    control assessment model. Draft technical report prepared for U.S. Envi-
    ronmental Protection Agency, Office of Science & Technology, Washington,
    DC, by Research Triangle Institute (RTI), Research Triangle Park, NC.
Brezina, E.R.  1988.  Water quality issues in the Delaware River Basin.
    In Ecology and  restoration of the Delaware River Basin, ed. S.K.
    Majumdar, E.W.  Miller, and L.E. Sage, pp. 30-38. Pennsylvania Academy of
    Science, Philadelphia, PA.
Bryant, T.L., and J.R. Pennock.   1988.  The Delaware  estuary:  Rediscovering
    a forgotten resource. University of Delaware Sea Grant College Program,
    Newark, DE. Philadelphia Press, Burlington, NJ.
CEQ. 1982.  Environmental quality 1982.  13th Annual Report of the  Council
    on Environmental Quality. Executive Office of the President, Council on
    Environmental Quality, Washington, DC.
Cerco, C., and T. Cole.  1993. Three-dimensional eutrophication model of
    Chesapeake  Bay. Jour.  Environ. Eng. ASCE 119(6): 1006-1025.
Clark, L.J., R.B. Ambrose, and R.C. Grain.   1978.  A water quality modelling
    study of the  Delaware Estuary. Technical Report 62. U.S. Environmental
    Protection Agency, Region 3, Annapolis Field Office, Annapolis, MD.

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 Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment


                          DRBC.  1987. Recalibration/verification of the Dynamic Estuary Model for
                              current conditions in the Delaware estuary. DEL USA Project Element 19.
                              Delaware River Basin Commission, West Trenton, NJ.
                          DRBC.  1989.  Delaware estuary use attainability project: Final report. DEL
                              USA Project. Delaware River Basin Commission, West Trenton, NJ.
                          DRBC.  1992.  Delaware River and Bay water quality assessment 1990-1991
                              305(b) report. Delaware River Basin Commission, West Trenton, NJ.
                          Feigner, K. and H.S. Harris.  1970.  Documentation report on FWQA Dynamic
                              Estuary Model. U.S. Department of the Interior. Annapolis, MD.
                          Forstall, R.L. 1995. Population by counties by decennial census: 1900 to 1990.
                              U.S. Bureau of the Census, Population Division, Washington, DC. .
                          Frithsen, J.B., K. Killam, and M. Young. 1991.  An assessment of key biologi-
                              cal resources in the Delaware River estuary. Prepared for the  Delaware
                              Estuary Program, U.S.  Environmental Protection Agency,  Region 2, New
                              York, NY, by Versar, Inc, Columbia, MD.
                          Galperin, B., and G.L. Mellor. 1990. A time-dependent, three-dimensional model
                              of the Delaware Bay and River system. Part 1: Description of the model and
                              tidal analysis. Est. Coast. Shelf Sci. 31: 231-253.
                          Hastings, R.W, F.C. O'Herron, II, K. Schick, and M.A. Lazzari.  1987. Occur-
                              rence and distribution of shortnose sturgeon, Acipenser brevirostrum, in the
                              upper tidal Delaware River. Estuaries 10(4): 337-341.
                          Himchak, P.J. 1984.  Monitoring of the striped bass population in  New
                              Jersey. Final report covering the period from December 1, 1983, through
                              September 30, 1984. New Jersey Department of Environmental Protection,
                              Division of Fish, Game and Wildlife, Bureau of Marine Fisheries.
                          HydroQual.  1994.  Review of the Delaware River DEM Models. Tech. Report
                              prepared for Delaware River Basin Commission, West Trenton, NJ, by
                              HydroQual, Inc., Mahwah, NJ.
                          HydroQual.  1998.  Development of a hydrodynamic and water quality model
                             for the Delaware River. Tech. Report prepared for Delaware River Basin
                              Commission, West Trenton, NJ. by HydroQual, Inc., Mahwah, NJ. May 29.
                          Iseri, K.T., and W.B. Langbein.  1974.  Large rivers of the  United States.
                              Circular No. 686. U.S. Department of the Interior, U.S. Geological Survey.
                          Jaworski, N.  1997.  Total nitrogen (TN) and phosphorus (TP)  loadings and
                              TN:TP molar ratios for the estuaries  of the Middle Atlantic and North-
                              east U.S.A. during the last century. Estuarine Research Foundation
                              Conference, 1997.
                          Jaworski, N., and L. Hetling. 1996.  Water quality trends of the Mid-Atlantic and
                              Northeast watersheds over the past 100 years. In Proceedings Watershed
                              '96: A National Conference on Watershed Management, pp. 980-983.
                              Baltimore, MD, June 8-12, 1996. Water Environment Federation, Alexan-
                              dria, VA.
                          Jeglic, J.M., and G.D. Pence. 1968. Mathematical simulation of the estuarine
                              behavior and its application. Socio-Econ. Plan. Sci. 1: 363-389.
                          Lebo, M.E., and J.H. Sharp.  1993. Distribution of phosphorus  along the Dela-
                              ware, an urbanized coastal plain estuary. Estuaries 16(2): 290-301.
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                                                             Chapter 7:  Delaware Estuary Case Study
LTI.  1985.  Two-dimensional DEM model of the Delaware estuary. Technical
    report prepared for Delaware River Basin Commission, West Trenton, NJ,
    by LimnoTech, Inc., Ann Arbor, MI.
Lung, W.  1991.  Trends in BOD/DO modeling for waste load allocations of
    the Delaware River estuary.  Tech. Memorandum prepared for Tetra Tech,
    Inc., Fairfax, VA, by Enviro-Tech, Inc., Charlottesville, VA.
Majumdar, S.K., E.W. Miller, L.E. Sage (eds.). 1988.  Ecology and restoration
    of the Delaware River Basin. The Pennsylvania Academy  of Science.
    Easton, Pennsylvania.
Marino, G.R., J. L. Di Lorenzo, H.S. Litwack, T.O. Najarian, and M.L. Thatcher.
    1991.  General water quality assessment and trend analysis of the
    Delaware Estuary, Part One: Status and trends.  Prepared  for Delaware
    Estuary Program and Delaware River Basin Commission, West Trenton, NJ,
    by Najarian & Associates, Eatontown, NJ.
Mooney, K.G., T.W. Gallagher, and H.J.  Salas. 1998.  A review of thirty years
    of water quality modeling of the Delaware  estuary. Paper presented at
    XXVI Congress Inter Americano de Ingenieria Sanitaria Y Ambiental-
    Associacion Inter Americano de Ingenieria  Sanitaria  Y Ambiental
    (AIDIS), November 1-5, 1998, Lima, Peru.
Mooney, K.G., P.J. Webber and T.W. Gallagher.  1999.  A new total maximum
    daily load (TMDL) model for the Delaware River. Paper presented at
    WEFTEC'99, 1999 annual conference of the Water Environment Federation,
    New Orleans, LA. Water Environment Federation, Alexandria, VA.
O'Connor, D.J., J.P. St. John, and D.M. Di Toro.  1968.  Water quality analysis of
    the Delaware River Estuary.  J. Sanit. Eng. Div., ASCE 94(SA6):
    1225-1252.
OMB.  1999.  OMB Bulletin No. 99-04. Revised statistical definitions of Metro-
    politan Areas (MAs) and Guidance on uses of MA definitions. U.S. Census
    Bureau, Office of Management and Budget, Washington, DC. .
Patrick, R.  1988.  Changes in the chemical and biological characteristics of the
    Upper Delaware River estuary in response to environmental laws. In:
    Ecology and Restoration of the Delaware River Basin, ed. S.K.
    Majumdar, E.W. Miller, and L.E. Sage, pp. 332-359. Pennsylvania Academy
    of Science, Philadelphia, PA.
Patrick, R., F. Douglass, D.M. Palarage,  and P.M. Stewart.  1992. Surface
    water quality: Have the laws been successful? Princeton University
    Press, Princeton, NJ.
Pence, G.D., J.M. Jeglic, and R.V. Thomann.  1968. Time-varying DO model. J.
    Sanit. Eng. Div, ASCE 94(SA4): 381-402.
Price,  K.S., R.A. Beck, S.M. Tweed, and C.E. Epifanio.  1988.  Fisheries. In The
    Delaware Estuary: Rediscovering a forgotten resource, ed. T.L. Bryant
    and J. R.  Pennock,  pp. 71-93. Univ.  Delaware Sea Grant College Program,
    Newark, DE. Philadelphia Press, Burlington, NJ.
Sage, L.E., and F.B. Pilling.  1988.  The development of a nation: the Delaware
    River. Chapter 14 in Ecology and restoration of the Delaware River
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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment


                             Basin, ed. S.K. Majumdar, E.W. Miller, and L.E. Sage, pp. 217-233. The
                             Pennsylvania Academy of Science, Philadelphia, PA.
                         Santoro, E.  1998.  Delaware  estuary monitoring report. Report prepared for
                             Delaware Estuary Program, U.S. Environmental Protection Agency, Region
                             2, New York, NY, by Delaware River Basin Monitoring Coordinator in
                             cooperation with the Monitoring Implementation Team of the Delaware
                             Estuary Program.
                         Scally, P.  1997. Delaware River Basin Commission, West Trenton, NJ. Personal
                             communication, August 1997.
                         Sharp, J.H. 1988. Trends in nutrient concentrations in the Delaware Estuary. In
                             Ecology and restoration  of the Delaware River Basin, ed. S.K.
                             Majumdar, E.W. Miller, and L.E. Sage, pp. 77-92. The Pennsylvania Acad-
                             emy of Science, Philadelphia, PA.
                         Sharp, J.H., and J.N. Kraeuter. 1989.  The state  of the Delaware Estuary.
                             Summary report of a workshop held on October 19. Scientific  and Technical
                             Advisory Committee, Delaware Estuary Program.
                         Solley, W.B., R.R. Pierce, and H.A. Perlman.  1998. Estimated use of water in
                             the United States, 1995. USGS Circular 1200. U.S. Geological Survey,
                             Reston, VA.
                         Stutz, B.  1992.  The Delaware: Portrait of a river. Nature Conservancy, May/
                             June.
                         Summers, J.K., and K.A. Rose. 1987. The role of interactions among environ-
                             mental conditions in controlling historical fisheries variability. Estuaries 10(3):
                             255-266.
                         Thomann, R.V.  1963. Mathematical model for DO. J. Sanit. Eng. Div., ASCE
                             89(SA5): 1-30.
                         Thomann, R.V, and J.A. Mueller.  1987. Principles of surface water quality
                             modeling and control.  Harper & Row, New York, NY.
                         USDOC.  1998. Census of population and housing. U.S. Department of
                             Commerce, Economics and Statistics Administration, Bureau of the Census -
                             Population Division, Washington, DC.
                         USEPA (STORET). STOrage and RETrieval Water Quality Information System.
                             U.S. Environmental Protection Agency, Office of Wetlands, Oceans, and
                             Watersheds, Washington,  DC.
                         USGS.  1999. Streamflow data downloaded from  the United States Geological
                             Survey's National Water Information System (NWIS)-W. Data retrieval for
                             historical streamflow daily values, .
                         Weisberg, S., P. Himchak, T. Baum, H.T. Wilson, and R. Allen.  1996.  Temporal
                             trends in abundance offish in the tidal Delaware River. Estuaries 19(3):
                             723-729.
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    Chapter  8
 Potomac   Estuary
 Case   Study
      The Mid-Atlantic Basin (Hydrologic Region 2),
      covering a drainage area of 111,417 square   potomac
      miles, includes some of the major rivers in the Estuary^
continental United States. Figure 8-1 highlights the
location of the basin and the Potomac estuary, the
case study watershed profiled in this chapter.
    With a length of 340 miles and a drainage area of
14,670 square miles, the Potomac River ranks 48th
among the 135 U.S. rivers that are more than 100 miles
in length (Iseri and Langbein, 1974). Urban-industrial
areas in the watershed caused severe water pollution
problems during the 1950s and 1960s (see Table 4-2). This
chapter presents long-term trends in population, municipal wastewater
infrastructure and effluent loading of pollutants, ambient water quality,
environmental resources, and uses of the Potomac estuary. Data
sources include USEPA's national water quality database (STORET),
published technical literature, and unpublished technical reports ("grey"
literature) obtained from local agency sources.
    With a combined drainage area of 14,670 square miles, the freshwater
and estuarine Potomac River basin is the second largest watershed in the Middle
Atlantic region. The freshwater Upper Potomac River flows more than 220 miles
from the headwaters of the North Branch in the eastern Appalachian Mountains
to the fall line at Little Falls, Virginia, near Washington, DC. Tidal influences in the
Potomac extend 117 miles from the fall line at Little Falls to the confluence with
Chesapeake Bay at Point Lookout, Virginia (Figure 8-2).
    In this 117-mile reach, the Potomac River is classified into three distinct
hydrographic regions—tidal river, transition zone, and estuary. The tidal river,
extending 38 miles from the fall line to Quantico, Virginia, is characterized as
freshwater (salinity < 0.5 ppt) with net seaward flow from surface to bottom.
This section of the Potomac River receives the effluent discharge from the major
municipal wastewater treatment facilities in the Washington, DC, metropolitan
Figure 8-1
Hydrologic Region 2 and
the Potomac estuary
watershed.
                                                                                 8-1

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
Figure 8-2
Location map of Middle
and Lower Potomac River.
(River miles shown are
distances from the
confluence of the Lower
Potomac River with the
Chesapeake Bay.)
                                           78
40°
                                39°
                                38C
                                                                   77°
                          area. The transition zone, extending 29 miles from Quantico, Virginia, to the Route
                          301 bridge in Maryland, is characterized by variable salinity (0.5-10 ppt) and
                          significant mixing of freshwater and saltwater from Chesapeake Bay. In the
                          mesohaline estuary region, extending 50 miles from the Route 301 bridge to
                          Chesapeake Bay at Point Lookout, Virginia, salinity varies from 5 to 18 ppt, with
                          estuarine circulation characterized as partially mixed (Haramis and Carter, 1983).
                               During much of the past century, the Potomac estuary has been character-
                          ized by severe water pollution problems—bacterial contamination, oxygen deple-
                          tion, and nuisance algal blooms—resulting from population growth in the Washing-
                          ton, DC, area and inadequate levels of waste treatment. Historical DO data
                          provide an excellent indicator to characterize long-term trends in the ecological
                          status of the Potomac estuary.  The water quality benefits attributed to implemen-
                          tation of secondary and advanced waste treatment by Washington, DC, area
                          wastewater dischargers to the Potomac estuary represent a major national
                          environmental success story.
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                                                        Chapter 8: The Potomac Estuary Case Study
Physical Setting and  Hydrology

     The Upper Potomac River, which has a drainage area of 11,560 square
miles, is the major freshwater inflow to the estuary. Based on long-term (1931-
1981) USGS data at Little Falls near the fall line, the mean annual daily flow is
11,406 cfs, with extreme discharge conditions of 374 cfs recorded during the
drought of 1966 and 483,802 cfs recorded during the flood of 1936 (MWCOG,
1989). The long-term (1931-1988) mean 7-day, 10-year low flow (7Q10) at Little
Falls is 628 cfs. Low-flow conditions typically occur from July through September,
with the minimum monthly flow of 4,126 cfs recorded during September (Figure
8-3). The long-term (1951-1980) mean summer (July-September) flow for the
Potomac River at Little Falls was 4,428 cfs (Figure 8-4).
                                                                         Figure 8-3
                                                                         Monthly trends of mean,
                                                                         10th, and 90th percentile
                                                                         streamflow for the
                                                                         Potomac River at Little
                                                                         Falls, VA (USGS Gage
                                                                         01646500), 1951-1980.
                                                                         Source: USGS, 1999.
                 ONDJ  FMAMJ  JAS
                                                                        Figure 8-4
                                                                        Long-term trends in mean,
                                                                        10th, and 90th percentile
                                                                        streamflow in summer
                                                                        (July-September) for the
                                                                        Potomac River at Little
                                                                        Falls, VA (USGS Gage
                                                                        01646500).
                                                                        Source: USGS, 1999.
            T946	1956
                   90%ile
                                           mean & ratio
                                                                                          8-3

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
                           Table 8-1. Metropolitan Statistical Area (MSA) counties in the Potomac Estuary
                           case study. Source: OMB, 1999.
                                Calvert County, MD
                                Charles County, MD
                                Frederick County, MD
                                Montgomery County, MD
                                Prince George's County, MD
                                Arlington County, VA
                                Clarke County, VA
                                Culpepper County, VA
                                Fairfax County, VA
                                Fauquier County, VA
                                King George County, VA
                                Loudoun County, VA
Prince William County, VA
Spotsylvania County, VA
Stafford County, VA
Warren County, VA
Alexandria City, VA
Fairfax City, VA
Falls Church City, VA
Fredericksburg City, VA
Manassas City, VA
Manassas Park City, VA
Berkeley County, WV
Jefferson  County, WV
                          Population, Water, and  Land  Use  Trends
                              In 1996 more than 4.5 million people lived in the Washington, DC, metropoli-
                          tan area in the vicinity of the tidal river. The Potomac estuary case study area
                          includes a number of counties identified by the Office of Management and
                          Budget as Metropolitan Statistical Areas (MSAs) or Primary Metropolitan
                          Statistical Areas (PMSAs). Table 8-1 lists the MSA and counties included in this
                          case study. Figure 8-5 presents long-term population trends (1940-1996) for the
                          counties listed in Table 8-1. From 1940 to 1996, the population in the Potomac
                          Estuary study area nearly quadrupled (Forstall, 1995; USDOC, 1998).
Figure 8-5
Long-term trends in
population of Washington,
DC, metropolitan area.
Source: Forstall, 1995;
USDOC,  1998.
                                           1940   1950   1960   1970   1980   1990   1996
8-4

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                                                         Chapter 8: The Potomac Estuary Case Study
     Within the Potomac basin, land use is characterized as forested (55 percent),
agricultural (40 percent), and urban (5 percent) (Jaworski, 1990). A rapid transi-
tion from agricultural land use to suburban land use has occurred since the 1960s
in the Washington, DC, metropolitan area. In contrast to other major metropolitan
areas, industrial activities are a negligible component of the regional economy
(and wastewater loading). Upstream of the fall line, the free-flowing Potomac is
used for five municipal water supply diversions with a total mean withdrawal (ca.
1986) of 386 mgd (MWCOG, 1989). As a result of major improvements in water
quality over the past decade, boating and recreational and commercial fishing
have become important resource uses of the Potomac estuary.


Historical Water Quality  Issues

     As in many other urban areas centered around rivers and harbors, water
pollution problems have been documented in the tidal river since the turn of the
century (e.g., Newell, 1897). In the late 1950s  USPHS officials described the
Potomac near Washington,  DC, as "malodorous . . .  with gas bubbles from
sewage sludge over wide expanses of the  river .  . . and coliform content
estimated as equivalent to  dilution of 1 part  raw sewage to as little as 10
parts clean water." Dissolved oxygen levels near Washington, DC, were
typically less than 1 mg/L during summer low-flow conditions, and nuisance algal
blooms and fish kills were commonplace during the 1940s, 1950s, and 1960s.
Between 1955 and 1960 the stock  abundance of American shad in the Potomac
River dropped precipitously despite favorable hydrographic conditions for spawn-
ing and development. American shad in northeastern estuaries such as the
Potomac River, although influenced by spawning success, may be influenced to a
larger extent by mortality suffered  by young fish as they pass seaward through
regions of poor water quality (Summers and Rose, 1987).


Legislative and  Regulatory History

     Following generally accepted engineering practices a century ago,  a sewage
collection system was constructed in Washington, DC, in 1870, with wastewater
collected and discharged without treatment into the Potomac River. By 1913
USPHS surveys documented severely polluted  conditions resulting from the
discharge of raw sewage. Following the recommendations of city officials in  1920
and a study conducted in the early 1930s, the Blue Plains facility began operation
in 1938 as a primary plant to serve 650,000 people. An unforeseen population
influx related to World War  II quickly exceeded the capacity of the new treatment
plant.
     In response to the continuing degradation of water quality in the  Potomac,
the  1956 Federal Water Pollution Control Act, and subsequent amendments,
served as the mechanism for establishing cooperative federal, state, and local
remedial action plans for wastewater treatment. For more than two decades,
federal, state, and local officials have cooperated in developing regional water
quality management plans and implementing recommended effluent limits.
                                                                                            8-5

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 Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment


                       Impact of Wastewater Treatment:

                       Pollutant Loading and  Water Quality

                       Trends

                          In the Washington, DC, region, 13 wastewater treatment plants currently
                       discharge effluent into the Potomac estuary. As of 1990 nine major plants
                       (Table 8-2) served about 4 million people and discharged a total of about 615
                       mgd (ICPRB, 1990). The 370-mgd discharge of the Blue Plains plant, which
                       serves the population of Washington, DC, accounts for about 75 percent of the
                       total effluent discharge to the Potomac estuary during low-flow conditions
                       (Figure 8-6).
Table 8-2. Effluent flow in 1 990 from major tidal
Potomac River municipal wastewater treatment plants
(mgd). Source: ICPRB, 1990.
Alexandria
Arlington
Blue Plains
Dale City
Little Hunting Creek
Lower Potomac
Mattawoman
H.L. Mooney
Piscataway
Total
54
40
370
4
6.6
72
15
24
30
616.6
                             500
Figure 8-6
Long-term trends in
effluent flow rate of
municipal wastewater
facilities.

Source: MWCOG, 1989.
                              1940
1950
1960
1970
1980
                                                                            1990
8-6

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                                                            Chapter 8: The Potomac Estuary Case Study
                                                               200
                                                               150
                                                             --100
                                                                   S1
                                                                   p
                                                                  IT)
                                                                  Q
                                                                  §
                                                        Figure 8-7
                                                        Long-term trends of BOD5,
                                                        total nitrogen, and total
                                                        phosphorus effluent loads
                                                        from municipal
                                                        wastewater.
                                                        Source: Jaworski, 1990;
                                                        Nemura,  1992.
             1940
1950
1960
1970
1980
     Over the past 50 years, trends in BOD5 and nutrient loading have reflected a
growing population and increasing levels of wastewater treatment. The reduction
in BOD5 loading resulted from the implementation of secondary treatment at Blue
Plains in 1959 and at the other facilities from 1960 to 1980. Beginning in the early
1970s, the dramatic drop in phosphorus loading by 1986 resulted from phosphorus
controls implemented at all the major wastewater treatment facilities to minimize
eutrophication in the Potomac estuary. Nitrogen loading, however, has increased
with population in the absence of controls on effluent nitrogen levels (Figure 8-7).
     DO,  influenced by temperature, wastewater loading, and freshwater flow, is
characterized by seasonal and spatial variations, with minimum levels observed
during the high-temperature, low-flow conditions of summer. Historical DO data
are available to characterize long-term changes in the spatial distribution of
oxygen during the summer (July-September) over a distance of approximately 55
miles from Chain Bridge to Mathias Point. These historical data sets clearly show
the significant problem with oxygen depletion during the 1960s (1960-1964,1966)
with recorded concentrations of less than 2 mg/L downstream  of the Blue Plains
wastewater treatment plant (located at about River Mile 106) (Figure 8-8).
        20
         15-
         10-
         5-
                     Summer Mean (July-September)
                     Chain Bridge-Mathias Ffoint
          -120      -110      -100       -90        -80
                             River Mile from Point Lookout
                                    -70
                                    -60
                                                        Figure 8-8
                                                        Long-term trends in
                                                        summer DO levels at
                                                        Chain Bridge-Mathias
                                                        Point.
                                                        Sources: Davis,  1968;
                                                        Thomann and Fitzpatrick,
                                                        1982; Fitzpatrick et ai,
                                                        1991.
                                                                                                 8-7

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
Figure 8-9
Long-term trends in
summer DO levels on the
Potomac River near the
Wilson Bridge (mile 95).
(Data for 1940-1986 from
MWCOG averaged from
June-September, data for
1987-1995 from STORE!
averaged from July-
September.)
Source: MWCOG, 1989;
USEPA  (STORET).
                                            1950
1960
1970
1980
1990
2000
                             Mean summer (June-September) oxygen records obtained from stations
                        directly influenced by the wastewater discharge from Blue Plains near the
                        Woodrow Wilson Bridge (RM 95) clearly show long-term trends in the ecological
                        condition of the estuary from 1940 to 1990 (Figure 8-9). The decline from 1945 to
                        1960 reflects substantial increases in population and related raw and primary
                        effluent loading from the Washington, DC, region. Low oxygen levels recorded in
                        the mid-1960s (1 to 2 mg/L) reflect the reduction of freshwater available for
                        dilution because of drought conditions (see Figure 8-4) rather than any increase of
                        pollutant load. The water quality standard for DO of 5 mg/L was typically violated
                        during the 1960s and 1970s. Compliance was attained for the summer average
                        condition only after all the regional wastewater treatment plants achieved second-
                        ary treatment by 1980; minimum summer levels, however, continued to periodi-
                        cally be less than 5 mg/L (MWCOG, 1989).


                        Evaluation of Water Quality

                        Benefits  Following  Treatment

                        Plant Upgrades

                             From a policy and planning perspective, the central question related to the
                        effectiveness of the secondary treatment requirement of the 1972 CWA is simply
                        Would water quality standards for dissolved oxygen be  attained if primary
                        treatment levels were considered acceptable?
                             In addition to the qualitative assessment of historical data, water quality
                        models can provide a quantitative approach to evaluate improvements in water
                        quality achieved as a result of upgrades in wastewater treatment. The Potomac
                        Eutrophication Model (PEM) (Thomann and Fitzpatrick, 1982; Fitzpatrick et al.,
                        1991) has been used in this study to demonstrate the water quality benefits
                        attained by the technology- and water-quality-based requirements of the 1972
                        CWA for municipal wastewater facilities.
8-8

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                                                           Chapter 8: The Potomac Estuary Case Study
     The Potomac Estuary Model (PEM) was calibrated using observed data
sets collected from 1983 through 1985. In the summer of 1983, an anomalous
bloom of the blue-green alga Microcystis aeruginosa formed a dense, brilliant
green scum-like mat on the surface that extended over a distance of about 20
miles in the central estuary and embayments. Peak chlorophyll levels in the main
river were ~300 ug/L, and dense concentrations as high as  -800 ug/L were
recorded in the embayments (Thomann and Mueller, 1987). During the peak of
the bloom in September 1983, dissolved oxygen levels computed with PEM were
in reasonable agreement with the observed monthly mean data (Figure 8-10);
concentrations of ~6 mg/L were observed and simulated in the vicinity of the Blue
Plains wastewater treatment plant (RM 105) (Fitzpatrick et al., 1991).  The rapid
increase from ~6 mg/L to observed (~10-16 mg/L) and computed (~12 mg/L)
levels of dissolved oxygen ~5-10 miles downstream from Blue Plains is caused by
high rates of phytoplankton primary productivity associated with peak algal
biomass levels of ~150-250 ug/L (as chlorophyll a) in the vicinity of the Woodrow
Wilson Bridge (RM 95). Further downstream in the transition zone of the
Potomac estuary, observed and computed dissolved oxygen levels decline to -5-7
mg/L in the vicinity of Indian Head (RM 85) to Maryland Point (RM 65) as a
result of the attenuation of the Microcystis bloom by nitrogen limitation and the
effects of salinity toxicity (Fitzpatrick et al., 1991). As documented by Fitzpatrick
et al. (1991), dissolved oxygen, algal biomass, nutrients, BOD5, inorganic carbon,
pH, and salinity, the Potomac Estuary Model is considered well calibrated to the
observed data for the period from 1983 through  1985.
     Using data to describe effluent flow, pollutant loading, and hydrologic
conditions during the lower-than-average flow conditions of September 1983, the
calibrated model was used to evaluate the water quality impact of two  regulatory
control scenarios based on an assumption of (a) primary treatment and (b)
secondary treatment compared to the existing (ca.  1983) effluent loading for all
the municipal facilities in the Washington, DC, region (Fitzpatrick, 1991) (Figure
8-10). Water quality conditions for these scenarios were simulated using freshwa-
ter flow data for 1983, a year characterized by summer flow (2,333 cfs) that was
about 53 percent of the  long-term summer mean flow of the Potomac River (see
                 -110
 -100       -90       -80
River Miles from Point Lookout
-70
-60
                                                                             Figure 8-10
                                                                             Potomac Estuary Model
                                                                             comparison of simulated
                                                                             DO for primary, secondary,
                                                                             and greater than
                                                                             secondary effluent loading
                                                                             scenarios (observed data
                                                                             is for September, 1983
                                                                             calibration).
                                                                             Source: Fitzpatrick, 1991;
                                                                             Fitzpatrick et al.,  1991.
                                                                                               8-9

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment


                          Figure 8-4). Other than the effluent characteristics, the ratio of ultimate-to-5-day
                          BOD and the oxidation rate for CBOD (Kd) were the only parameters changed in
                          the simulations to reflect differences in the proportion of refractory and labile
                          organic carbon for the different levels of wastewater treatment (Fitzpatrick, 1991;
                          Lung, 1996,1998; Thomann and Mueller, 1987).
                               For the primary simulation, a value of Kd = 0.21 day1, obtained from the
                          original PEM (Thomann and Fitzpatrick, 1982), is typical of wastewater effluent
                          characterized by the high CBOD concentrations typical of primary treatment
                          conditions observed during the 1960s. For the secondary simulation, a value of Kd
                          = 0.16 day1, obtained from the original PEM (Thomann and Fitzpatrick, 1982), is
                          typical of wastewater effluent characterized by the intermediate CBOD concen-
                          trations typical of secondary treatment conditions observed during the late 1970s.
                          For the advanced (actual 1983) loading scenario, a value of Kd = 0.10 day1,
                          obtained from calibration of the updated PEM (Fitzpatrick et al., 1991), is typical
                          of wastewater effluent characterized by the low CBOD concentrations of
                          advanced secondary and tertiary treatment conditions observed during the mid-
                          1980s.
                               Under the primary effluent assumption, water quality is noticeably deterio-
                          rated in comparison to the 1983 calibration results. As a result of the effluent
                          loading from the Blue Plains treatment plant, DO concentrations in the vicinity of
                          Washington, DC (RJVI 10-15) are computed to be ~1 mg/L under the primary
                          effluent scenario. With minimum levels less than 1 mg/L in the vicinity of the Blue
                          Plains discharge (RM 106), the simulated  results for the primary effluent scenario
                          are remarkably similar to the historical data recorded for 1960-1964 and 1966
                          during the drought conditions of the  1960s (see Figure 8-8).
                               Under the secondary effluent assumption, the significant reduction in CBOD
                          loading significantly improves dissolved oxygen near Washington, DC. In compari-
                          son to the primary scenario, minimum monthly-averaged oxygen levels increased
                          to almost 3.5 mg/L from approximately 0.2 mg/L under the secondary effluent
                          scenario. When compared to the model results for the existing 1983 conditions,
                          the results of the secondary effluent simulation shows somewhat poorer water
                          quality conditions for dissolved oxygen. The reason for the failure to achieve
                          compliance with the 5 mg/L water quality  standard for dissolved oxygen over only
                          a few miles (RM 104-106) is that under the existing loading scenario for 1983, the
                          370-mgd Blue Plains facility (the largest wastewater discharger to the Potomac
                          River) has instituted advanced secondary  treatment with greater removal of
                          BOD, ammonia, and phosphorus than is represented in the secondary effluent
                          scenario (Fitzpatrick, 1991).
                               As shown with both observed data and state-of-the-art model simulations,
                          the implementation of secondary and better treatment has resulted in significant
                          improvements in the DO status of the estuary. As demonstrated with the model
                          (and actually attained) better than secondary treatment is required to achieve
                          compliance with the water quality standard of 5 mg/L for DO at the critical
                          location downstream of Blue Plains (see Figure 8-10). In contrast to the 1950s
                          and 1960s, the occurrence of low oxygen conditions has been virtually eliminated
                          in the Upper Potomac estuary (see Figure  8-8). Additional improvements in
                          Potomac water quality, in  terms of reduced algal biomass and increased water
                          clarity still greater improvements in dissolved oxygen levels, have been achieved
                          as a result of advanced secondary and tertiary levels of wastewater treatment for
                          the Upper Potomac estuary.

8-10

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                                                        Chapter 8: The Potomac Estuary Case Study
Impact of Wastewater Treatment:

Recreational  and Living Resources

Trends

     In addition to public water supply withdrawals (from the free-flowing river)
and wastewater disposal from a number of municipalities, the uses of the Upper
Potomac estuary include recreational and commercial fishing, boating and naviga-
tion, bird-watching, and secondary contact water-based recreation (e.g., wind-
surfing). Although recreational opportunities were severely limited during the
1940s, 1950s, and 1960s because of water pollution, the improvements in water
quality during the 1980s have resulted in a significant increase in a variety of
recreational uses of the river by the urban population of Washington, DC. Boat-
ing; windsurfing; walking, running, and bicycling on trails along the riverbanks; and
recreational fishing are now extremely popular activities in the tidal river in the
vicinity of Washington, DC.


Designated  Uses and  Bacterial  Trends

     Unlike the uses of many other major urban waterways, swimming, because
of limited access from the shoreline and a lack of public bathing beaches, is not
considered a major use of the Upper Potomac estuary. Most of the Potomac
River from the upper freshwater reaches near Point of Rocks, Maryland, to the
estuarine waters near Point Lookout, Maryland, is designated for primary contact
recreational uses (swimming). In the vicinity of Washington, DC, however, the
waters of the tidal Potomac are designated for secondary contact recreational
uses such as boating or windsurfing. The estuarine portions of the Potomac
downstream of Smith Point, Maryland, have been designated for shellfish harvest
and must comply with more stringent bacteria level standards than those set for
primary or secondary contact recreational uses. To protect public health from
risks resulting from direct contact with the waters of the Potomac or ingestion of
shellfish from the estuary, water quality standards have been established by the
state of Maryland, the District of Columbia, and the state of Virginia for the
maximum log mean fecal coliform bacteria levels (as most probable number
(MPN) per lOOmL) as follows:
    •   Primary contact < 200 MPN/100 mL
    •   Secondary contact < 1000 MPN/100 mL
    •   Shellfish harvest < 14 MPN/100 mL
     Based on long-term historical water quality data from measurements taken
downstream of the Blue Plains discharge, it is apparent that the introduction of
effluent chlorination in 1968 resulted in dramatic improvements in bacterial con-
tamination of the tidal Potomac (Figure 8-11). Prior to chlorination of wastewater
effluent, summer coliform levels, typically on the order of 105 to 106 MPN/100 mL
from 1940 to the mid-1960s, consistently were in violation of the secondary contact
standard of 1,000 MPN/100 mL. Even  with the dramatic reductions, summer
bacteria levels still exceeded water quality standards during the 1970s. As bacteria
loadings from the Washington area municipal wastewater plants continued to
                                                                                        8-11

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
Figure 8-11
Long-term trends in total
coliform densities in the
Potomac River down-
stream of the Blue Plains
POTW near Gunston Cove,
VA
Source: USEPA (STOHET).
                                    10000000=
O- 1000000:
E
8
5   looooo:
I
I
CD
                                          1940
                1950
1960
1970
1980
1990
                        decrease during the 1980s, summer bacteria densities began to be in compliance
                        with the water quality standard for both primary and secondary contact. Since the
                        1980s periodic violations of bacteria level standards in the tidal Potomac have
                        usually been related to storm event discharges from combined sewer overflows in
                        the District of Columbia and Alexandria, Virginia (MWCOG, 1989).
                             Since the passage of the 1965 Water Quality Act, well-planned and coordi-
                        nated water pollution control programs in the Washington metropolitan region
                        have succeeded in achieving substantial reductions in pollutant discharges to the
                        Potomac estuary. Despite the remarkable improvements in the bacteria levels of
                        the tidal Potomac, it is unlikely that President Johnson's 1965 pledge to "reopen
                        the Potomac for swimming" will be fulfilled because of the lack of beaches
                        along the shoreline and access for swimming.

                        Submersed  Aquatic  Vegetation, Fishery,

                        and Waterfowl Resources

                             In numerous accounts of the early colonists, the natural abundance of
                        waterfowl and fishery resources of the Potomac basin was considered an impor-
                        tant factor in attracting new colonists to the region. Like many freshwater and
                        marine environments, the shallow littoral areas of the tidal Potomac River near
                        Washington, DC, were characterized by extensive beds  of a variety of species of
                        aquatic macrophytes, or submersed aquatic vegetation (SAV), during the late
                         1800s  and early 1900s (Carter et al., 1985). Detailed maps in 1904 and 1916, for
                        example, showed extensive "grass" beds in Gunston Cove and shallow areas of
                        the Maryland and Virginia sides of the river. In addition to the direct effect on the
                        survival and condition offish populations due to low DO concentrations caused by
                        high organic loadings, fish populations are indirectly influenced by SAV abun-
                        dance, necessary to provide nursery habitat for juvenile  fish (Fewlass, 1991).
8-12

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                                                         Chapter 8:  The Potomac Estuary Case Study
     Increased municipal wastewater loading from the Washington area and the
resulting poor water quality was most likely responsible for the disappearance of
SAV from the tidal Potomac River (Carter et al., 1985; Carter and Paschal,
1981), first noticed in 1939. During the 1940s and 1950s, widespread losses of
SAV were common, not only in the Potomac, but also throughout the Chesapeake
Bay basin (Carter et al., 1985). Although the SAV beds were severely diminished
by the late 1930s, periodic nuisance "invasions" of submersed aquatic vegetation
were recorded in the tidal Potomac during the 1930s (water chestnut) and from
1958 through 1965 (Eurasian watermilfoil) (Jaworski, 1990).


Trends  in  Suspended Solids  Load and

Water  Clarity

     By the late 1970s, SAV in the Washington, DC, area had effectively disap-
peared from the tidal Potomac (Carter et al., 1985). The loss of SAV in the
Potomac, and elsewhere in Chesapeake Bay region, has been attributed to the
decreased availability of light in the littoral zone resulting from increased turbidity
from the discharge of suspended solids and nutrients to the estuary (Carter et al.,
1985). High levels of algae reduced light penetration and inhibited the growth of
SAV. The natural abundance of fish and waterfowl of the Potomac, documented
by the early colonists, was in fact directly related to the abundance and distribu-
tion of SAV in the shallow areas of the river. Redhead ducks, canvasbacks, and
migrating widgeons and gadwalls feed on SAV, and other ducks such as mergan-
sers feed on juvenile fish that depend on SAV for spawning and development
(Forsell, 1992). The absence of SAV during the 1940s through 1970s resulted in a
loss of habitat and food resources for fish and waterfowl dependent on the
presence of the SAV beds.
     The long-term ecological effects of the dramatic reductions of municipal
wastewater loading of phosphorus (Figure 8-7) and suspended solids (Figure 8-
12) to the estuary that began during  the 1970s became  apparent in the early
             150-
             100-
              50-
                    1970
1975
                                           J
            III!
           • •••I
1980
1985
1990
                                            Figure 8-12
                                            Long-term trends in
                                            municipal wastewater
                                            loading of suspended
                                            solids in the tidal Potomac
                                            River.
                                            Source: Nemura, 1992.
                                                                                          8-13

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
                           1980s with the surprising reappearance of SAV beds in the tidal Potomac
                           (Carter and Rybicki, 1990). The return of the SAV beds was directly related to
                           improvements in the clarity of the water (Figure 8-13), resulting from reductions
                           in suspended solids and phosphorus loading from municipal wastewater dis-
                           charges to the estuary and subsequent reductions in ambient phosphorus and
                           algal biomass (Figure 8-14) (Carter and Rybicki, 1990; Jaworski, 1990; Carter
                           and Rybicki, 1994). The presence of the SAV beds, in turn, has further enhanced
                           water quality by physical settling of particulate solids, filtering of nutrients by
                           plant uptake, and reduction of algal production in the water column (Figure 8-15).
                           The reemergence of SAV beds in the tidal Potomac has resulted in dramatic
                           increases in the diversity, abundance, and distribution of waterfowl (Figures 8-16
                           and 8-17).
Figure 8-13
Long-term trends in SAV
and water transparency in
the tidal  Potomac River.
Sources: Carter and
Rybicki,  1990;  Nemura,
1992; USEPA (STORET).

i
c 3000-
o
^
1 2000-
D


0-



A
* *-^ 4
* ^* " *^ * ^^ A
v \ r\
X it v--^
V

nil
1970 1975 1980

r-l



,



1

r-i



...
.


985

p



• -
k ,'






Ai
^
-













1









990
-u.u




-0.6

-0.8

'
                                                                                         CO
                                               I SAV
c • water transparency
Figure 8-14
Long-term trends in algal
biomass and total
phosphorus in the tidal
Potomac  River.
Source: USEPA, 1992.
                                                                                          0.5
                                          1965-69  1970-74  1975-79  1980-84  1985-89  1990-91
^| Algae
-*- Total-P
                                                                                          0.0
8-14

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                                                    Chapter 8:  The Potomac Estuary Case Study
                            Submersed Aquatic Vegetation
               20
   40        60
Density of SAV: Increase
                                             80
                                 100
                                                 Figure 8-15
                                                 Conceptual relationship of
                                                 SAV abundance and water
                                                 clarity.
                                                 Source: Carter and
                                                 Rybicki,  1990,  1994;
                                                 Kemp et ai, 1984.
10000-
             Chain Bridge to Wicomico River
         1956-60 1961-65 1966-70 1971-75 1976-80 1981-85 1986-90 1991-92
              I Canada Geese
                                  Canvasback Ducks
                                                  Figure 8-16
                                                  Long-term trends of
                                                  waterfowl in the upper
                                                  Potomac  River.
                                                  Observation from
                                                  Washington, DC, to Route
                                                  301 bridge.
                                                  Source: Forsell,
                                                  Unpublished data.
   50%
   40%-|
3
£  30%-
             Upper Chesapeake Bay: 1958-75
             Percentage of North American Flyway Population
                 100      200       300       400
                      Relative Abundance of SAV  	»
                                                      500
                                                  Figure 8-17
                                                  SAV and waterfowl
                                                  abundance in Upper
                                                  Chesapeake Bay (1958-
                                                  1975).
                                                  Source: Kemp et al., 1984.
                                                                                           8-15

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
Figure 8-18
SAV abundance and
fishery resources in the
Choptank River.
Source: Kemp et al., 1984.
                                                   No SAV                Dense SAV
                                                        Density of SAV: Increase  	0
                               Fish surveys documented significant increases in species diversity and
                          abundance from 1984 to 1986 (MWCOG, 1989) that are consistent with the SAV
                          and fisheries abundance data reported for the Choptank River on the eastern
                          shore of Maryland (Kemp et al., 1984) (Figure 8-18).
                               Before the disappearance of the SAV beds, waterfowl populations (ca.
                          1929-1930) were about an  order of magnitude greater than after the disappear-
                          ance of SAV during the 1950s, when the annual average waterfowl census was
                          6,547 birds. Historical data from the Upper Chesapeake Bay (1958-1975) are
                          useful to illustrate the relationship between the availability of SAV, fisheries, and
                          waterfowl populations (Figures 8-17 and 8-18). The importance of SAV in the
                          overall biological health of the tidal Potomac is clearly demonstrated with recent
                          observations of a doubling of waterfowl abundance and an increase in the
                          diversity of species (MWCOG, 1989). In 1972 only 9 species of ducks wintered
                          in the Potomac tidal river and transition zone (represented by more than one
                          individual observed in winter transect counts); by 1992  the number of species
                          had increased to 17 (Forsell, 1992). Fall-migrating, SAV-eating widgeons and
                          gadwalls, absent from the estuary in winter for 15 years, have lengthened their
                          stay in the Potomac, possibly encouraged by recent warmer winters and more
                          plentiful food supplies. Populations offish-eating mergansers, increasing since
                          the  1970s, may be responding to increasing fish habitat available since the
                          reemergence of SAV beds.  Populations of Canada geese, tundra swans, and
                          mallards, although not directly linked to SAV, are also increasing in the tidal
                          Potomac, this trend has also been observed in  other areas of the northeast.
                               Fishery surveys in the tidal Potomac, and  elsewhere in the Chesapeake Bay,
                          clearly document an increase in abundance and  diversity offish species. Juvenile
                          fish survey data, collected between 1965 and 1987 at Indianhead and Fenwick in
                          the tidal river, were analyzed using the Index of Biotic Integrity (IBI) (Figure 8-
                          19). The IBI, developed by Karr (1981) for use in midwestern streams, has been
                          adapted for use in other areas. This index is a composite  of 12 ecological at-
                          tributes offish communities, including species richness, indicator taxa (both
                          intolerant and tolerant), trophic guilds, fish abundance, and incidence of hybridiza-
8-16

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                                                             Chapter 8: The Potomac Estuary Case Study
                                                                              Figure 8-19
                                                                              Long-term trends in fishery
                                                                              resources of the Potomac
                                                                              estuary based on Index of
                                                                              Biotic Integrity (IBI).
                                                                              Source: Jordan,
                                                                              Unpublished data.
tion, disease, and abnormalities (Karr et al., 1986). IBI scores range from a low
of 12 to a high of 60. A score of 12 is assigned to conditions where no fish are
present even after repeated sampling; a score of 60 is assigned to conditions
comparable to the best habitats without human disturbance (Karr et al., 1986).
The trend in the IBI at Indianhead (Jordan, 1992, unpublished data) shows that
the river quality for fish increased from poor, indicating an impaired or restricted
habitat (IBI scores in the 20 to 30 range), to fair, indicating slightly impaired
habitat (IBI scores in the 40 to 50 range). These data indicate that in the late
1960s and early 1970s the fish community at Indianhead was dominated by a few
tolerant species, with few fish present at all in some  years. In the last 20 years, a
general upward trend in river quality for fish has been observed, evidenced by
increasing numbers of pollution-intolerant species and a species mix suitable to
provide for a reasonably balanced trophic structure. Indicator variables currently
measured at Indianhead are at about two-thirds of their expected level in undis-
turbed habitats. The rise in the IBI at Indianhead, where a wastewater treatment
plant discharge is located, is in contrast to stable or declining trends observed at
other locations that lack wastewater treatment plant outfalls (Jordan, 1992,
unpublished data).
     In addition to the direct effect on the survival and condition offish popula-
tions due to low DO concentrations due to high organic loadings (Tsai, 1991), fish
populations are indirectly influenced by SAV abundance, necessary to provide
nursery habitat for juvenile fish (Fewlass, 1991). The quality of river habitat for
fish has increased with the resurgence of SAV habitat in comparison to areas
characterized by the absence of SAV beds. During 1984-1986, years character-
ized by a rapid increase in the distribution of SAV beds (primarily Hydrillo) (see
Figure 8-13), fishery surveys near Washington, DC, clearly showed an increase in
species diversity; abundance increased from 79 to 196 fish per net haul over the
same 2-year period (MWCOG, 1989). The relationship of SAV and fishery data
from the tidal Potomac is consistent with data reported by Kemp et al. (1984) for
the Choptank River on the eastern shore of Maryland (see Figure 8-18).
                                                                                                8-17

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
"...in the 1950s and 1960s
the Potomac was a flowing
cesspool...It was a dis-
grace, it was so polluted. If
you fell in the river, it was
recommended you go ti
the hospital for examina-
tion. Now the river is much
better. Pollution controls
are higher and the fish
population's are mostly
solid. But the people still
think of it as the old river.
So people don't under-
stand how good the fishing
is here."
       Travel Section,
       Washington Post,
       August 30, 1998
       (Tidwell, 1998).
SAV and  Ecological  Resources

     The evidence is clear from observations in Chesapeake Bay and the tidal
Potomac River that the presence of SAV beds is critical for a healthy and diverse
aquatic ecosystem. The presence of SAV beds has the following positive impacts:
    •   Increases habitat and food resource availability
    •   Increases species diversity and abundance
    •   Increases fishery resources
    •   Increases waterfowl populations
    •   Increases recreational opportunities (fishing, hunting, bird-watching)
    •   Enhances water quality
    •   Removes nutrients
    •   Allows particulate material to settle out
    •   Reoxygenates water column by photosynthesis


Summary and  Conclusions

     Water quality and biological resources data clearly illustrate the cause-effect
relationship of reductions in wastewater loading of BODs, nutrients, and sus-
pended solids and improvements in the ecological resources of the tidal Potomac.
As a result of the significant improvements in water quality, the Potomac estuary
emerged during the 1990s as one of the top-ranked largemouth bass sport fisher-
ies supporting increasingly popular recreational fishing activities, including profes-
sional fishing guide services and several Bassmasters fishing tournaments. One of
the earliest professional guides, Ken Penrod of Outdoor Life Unlimited in
Beltsville, Maryland, now has one of the largest freshwater fishing guide services
in the nation. Guides like Penrod have reported that since 1982 every year has
been better than the previous year in terms of the quantity and quality offish that
have returned to the waters  of the tidal Potomac (Soltis, 1992). The quality of
river habitat for fish has increased with the resurgence of SAV habitat in com-
parison to areas characterized by the absence of SAV beds. The Potomac River
was selected as an American Heritage River  in 1998, acknowledging the substan-
tial improvements in water quality and ecological conditions.  In addition, some
300 people took part in the  1999 Bassmasters Fishing Tournament on the
Potomac (Fishing Tournament Marks a River's Rebound, 1999).

References

Carter, V., and J.E. Paschal. 1981. Biological factors affecting the distribution
    and abundance of submerged aquatic vegetation in the tidal Potomac River,
    Maryland and Virginia. Estuaries 4(3):  300.
Carter, V, J.E. Paschal, and N. Bartow.   1985.  Distribution and abundance of
    submersed aquatic vegetation in the tidal Potomac River and estuary,
    Maryland and Virginia, May  1978 to  November 1981. Water-Supply
    Paper 2234-A. U.S. Geological Survey, Reston, VA.
Carter, V, and N.B. Rybicki.  1990. Light attenuation and submersed macrophyte
    distribution in the tidal Potomac River and estuary. Estuaries 13(4): 441-452.
8-18

-------
                                                           Chapter 8: The Potomac Estuary Case Study
Carter, V.  and N.B. Rybicki.  1994. Role of weather and water quality in
    population dynamics of submersed macrophytes in the tidal Potomac River.
    Estuaries 17(2): 417-426.
Davis, R.K.  1968.  The range of choice in water management: A study of
    dissolved oxygen  in the Potomac Estuary. Published for Resources for the
    Future, Inc. by The Johns Hopkins Press, Baltimore, MD.
Fewlass, L.  1991.  Statewide fisheries survey and management study V:
    Investigations of largemouth bass populations inhabiting Maryland's
    tidal waters. Maryland Department of Natural Resources, Tidewater
    Administration, Annapolis, MD.
Fitzpatrick, J.P. 1991.  HydroQual, Inc., Mahwah, NJ. Personal communication,
    September 18, 1991.
Fitzpatrick, J.P., et al.  1991.  Calibration and verification of an updated
    mathematical model of the eutrophication of the Potomac estuary.
    Prepared for Metropolitan Washington Council of Governments, Washington,
    DC, by HydroQual, Inc.
Forsell, D. Unpublished data. U.S. Fish and Wildlife Service.
Forsell, Doug. 1992. U.S. Fish and Wildlife Service. Personal communication,
    October 22, 1992.
Forstall, R.L.  1995. Population by counties by decennial census: 1900 to 1990.
    U.S. Bureau of the Census, Population Division, Washington, DC. .
Haramis, G.M., and V. Carter.  1983.  Distribution of submersed aquatic macro-
    phytes in the tidal Potomac River.  Aquatic Botany 15(1983): 65-79.
ICPRB.  1990.  The healing of a river, The Potomac: 1940-1990.  Interstate
    Commission on the Potomac River Basin, Rockville, MD.
Iseri,  K.T., and W.B.Langbein. 1974. Large rivers of the United States. Circular
    No. 686, U.S. Department of the Interior, U.S. Geological Survey.
Jaworski, N.A. 1990.  Retrospective study of the water quality issues of the
    Upper Potomac estuary. Reviews  in Aquatic  Science 3(2): 11-40.
Jordan, S. Unpublished data. Potomac River Fisheries Commission.
Karr, J.R.  1981. Assessment of biotic integrity using fish communities. Fisheries
    6(6): 21-27'.
Karr,  J.R., K.D. Fausch, PL. Angermeier, PR. Yant, and I.J. Schlosser. 1986.
    Assessing biological integrity in running waters: A method and its
    rationale. Special Publication 5. Illinois Natural History Survey, Champaign,
    IL.
Kemp, W.M, W.R. Boynton, R.R. Twilley, J.C. Stevenson, and L.G. Ward.  1984.
    Influences of submersed vascular plants on ecological processes in Upper
    Chesapeake Bay.  In The estuary as a filter, ed. VS. Kennedy, pp. 367-394.
    Academic Press, New York.
Lung, W. 1996. Postaudit of Upper Mississippi River BOD/DO Model. Jour.
    Environmental Engineering, 122(5):350-358.
Lung, W. 1998. Trends in BOD/DO Modeling for Waste Load Allocation. Jour.
    Environmental Engineering, 124(10):1004-1007.
MWCOG.  1989.  Potomac River water quality, 1982 to 1986: Trends and
    issues in the metropolitan Washington area. Metropolitan Washington
    Council of Governments, Department of Environmental Programs,  Washing-
    ton, DC.
                                                                                             8-19

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment


                         Nemura, A. 1992. Metropolitan Washington Council of Governments, Depart-
                             ment of Environmental Programs, Washington, DC. Personal communication,
                             March 3, 1992.
                         Newell, F.H.  1897.  Pollution of the Potomac River. National Geographic
                             (December 1997): 346-351.
                         OMB.  1995. OMB Bulletin No. 99-04. Revised statistical definitions of Metro-
                             politan Areas (MAs) and Guidance on uses of MA definitions. U.S. Census
                             Bureau, Office of Management and Budget, Washington, DC. .
                         Soltis, S.  1992.  Rebirth of an American river.  Washington Flyer Magazine
                             (March/April): 22-25.
                         Summers, K.J., and K.A. Rose.  1987.  The role of interactions among environ-
                             mental conditions in controlling historical fisheries variability. Estuaries 10(3):
                             255-266.
                         Thomann, R.V., and J.P. Fitzpatrick.  1982.  Calibration and verification of a
                             mathematical model of the eutrophication  of the Potomac estuary.
                             Prepared for Department of Environmental Services, Government of the
                             District of Columbia, Washington, DC, by HydroQual, Inc.
                         Thomann, R.V., and J.A. Mueller. 1987. Principles  of surface water quality
                             modeling and control. Harper & Row, Inc., New York, NY.
                         Tidwell, M.  1998. Where is this man fishing? The Washington Post, Travel
                             Section, Page El, E8-E10, August 30.
                         Tsai, Chu-Fa.  1991. Rise and fall of the Potomac River striped bass stock: a
                             hypotheiss of the role of sewage.  Trans. Amer.  Fish. Soc.  120(1): 1-22.
                         USDOC.  1998. Census of population and  housing.  U.S. Department of
                             Commerce, Economics and Statistics Administration, Bureau of the Census -
                             Population Division, Washington, DC.
                         USEPA.  1992.  Water quality goals for living resources: Role in the Chesa-
                             peake Bay nutrient reevaluation, summary and preliminary results.
                             USEPA Chesapeake Bay Program, Annapolis, Maryland.
                         USEPA (STORET). STOrage and RETrieval Water Quality Information System.
                             U.S. Environmental Protection Agency, Office of Wetlands, Oceans, and
                             watersheds, Washington, DC.
                         USGS.  1999.  Streamflow data downloaded from the U.S. Geological Survey's
                             National Water Information System (NWIS)-W. Data retrieval for historical
                             Streamflow daily values, .
8-20

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    Chapter  9
The  James
Estuary  Case
Study
    Figure 9-1 highlights the location of the James
estuary case study watershed (catalog units) identified as
one of the urban-industrial waterways affected by
severe water pollution problems during the 1950s and
1960s (see Table 4-2). The James River basin, at the
southern boundary of the Mid-Atlantic Basin, is one of
the most important water resources in the Common-
wealth of Virginia (Figure 9-2).
    As the largest river in the state, the James River
extends more than 400 miles from its mouth at the
Chesapeake Bay to its headwaters near the West
Virginia state line. The river is a recognized asset to
the surrounding residential and metropolitan areas,
providing recreational opportunities such as boating and
fishing.
    The James River is known for its annual national
Bassmasters fishing tournaments, and it has exceptional Class IV
white water rapids in the drop between the riverine and estuarine
portions of the river in Richmond, Virginia. The river is also an asset to
commerce and industry,  serving as an important water supply and, as such, a
catalyst for economic growth.


Physical Setting  and Hydrology

    The James River is a typical coastal plain estuary draining to the Chesa-
peake Bay. The variation of depth, cross-sectional area, and tidal velocity in the
James River from Richmond to the Chesapeake Bay is significant. For example,
the cross-sectional average depths vary from about 10 feet in areas with shallow
side embayments to 25 to 30 feet in the deepwater channel. The river generally
widens in the downstream direction, although natural constrictions occur at
Figure 9-1
Hydrologic Region 2 and
the James estuary
watershed.
                                                                           9-1

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 Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
 Figure 9-2
 Location map of the James River basin.  River miles shown are distances from Chesapeake Bay at the mouth of the
 James River.
        79°
78°
                                                               77°
     38C
     37°
                                                                                             38°
                                                                                            37°
                                  78°
                          77°
                          several locations. Cross-sectional area varies markedly, from the deep, narrow
                          channel in the upstream section to broad, shallower profiles downstream.
                               Upstream freshwater flow to the study area is monitored at the USGS
                          gaging station near Richmond, Virginia, on the James River. The freshwater flow
                          to the James River is contributed by runoff from 6,758 square miles of woodland
                          and agricultural areas upstream of the city of Richmond. A relatively small
                          additional flow enters the study area via the Kanawha Canal, bypassing the
                          USGS gage near Richmond. The combined average annual flow in the river at the
                          gage is 6,946 cfs (1937-1998). A relatively small intervening drainage area
                          provides a nominal increase in in-stream flow between Richmond and the
                          confluence with the Appomattox River. Water is withdrawn from the James River
                          for both municipal and  industrial purposes and then returned to the river. Treat-
                          ment is provided by all users except those who use the water solely for cooling
                          purposes. Long-term interannual and mean monthly trends in streamflow for the
                          James River near Richmond, Virginia, are shown in Figures 9-3 and 9-4.
9-2

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                                                               Chapter 9: James Estuary Case Study
                                                                           Figure 9-3
                                                                           Trends of mean, 10th, and
                                                                           90th percentile statistics
                                                                           computed for summer
                                                                           (July-September)
                                                                           streamflow for the James
                                                                           River (USGS Gage
                                                                           02037500 near Richmond,
                                                                           Virginia).
                                                                           Source: USGS, 1999.
                                                     1990
               - - - 90%ile
mean & ratio
                                                                           Figure 9-4
                                                                           Monthly trends in
                                                                           streamflow for the James
                                                                           River. Monthly mean, 10th,
                                                                           and 90th  percentile
                                                                           statistics  computed for
                                                                           1951-1980 (USGS Gage
                                                                           02037500 near Richmond,
                                                                           Virginia).
                                                                           Source: USGS, 1999.
                 ONDJFMAMJJAS
Population  Trends
     The James estuary case study area includes a number of counties identified
by the Office of Management and Budget as Metropolitan Statistical Areas
(MSAs) or Primary Metropolitan Statistical Areas (PMSAs). Table 9-1 lists the
MSAs and counties included in this case study. Figure 9-5 presents long-term
population trends (1940-1996) for the counties listed in Table 9-1. From 1940 to
1996, the population in the James estuary case study area more than tripled
(Forstall, 1995;USDOC, 1998).
                                                                                             9-3

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 Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
                              Table 9-1.  Metropolitan Statistical Area (MSA) counties in the James estuary case
                              study. Source: OMB, 1999.
                                    Norfolk-Virginia Beach-Newport News,
                                    VA-NC MSA
                                      Currituck County, NC
                                      Gloucester County, VA
                                      Isle of Wight County, VA
                                      James City County, VA
                                      Mathews County, VA
                                      York County, VA
                                      Chesapeake City, VA
                                      Hampton City, VA
                                      Newport News City, VA
                                      Norfolk City, VA
                                      Poquoson City, VA
                                      Portsmouth City, VA
                                      Suffolk City, VA
                                      Virginia Beach City, VA
                                      Williamsburg City, VA
Richmond-Petersburg,  VA MSA
  Charles City County, VA
  Chesterfield County, VA
  Dinwiddie County, VA
  Goochland County, VA
  Hanover County, VA
  New Kent County, VA
  Powhatan County, VA
  Prince George County, VA
  Colonial Heights City, VA
  Hopewell City, VA
  Petersburg City, VA
  Richmond City, VA
Figure 9-5
Long-term trends in
population in the James
estuary basin.
Sources: Forstall, 1995;
USDOC, 1998.
                                       OJ
                                                1940   1950   1960   1970   1980   1990   1996
9-4

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                                                               Chapter 9: James Estuary Case Study
Historical Water Quality Issues

     The estuarine system starts near Richmond, where the fall line is located,
and extends approximately 100 miles from the mouth of the river. The historical
water quality concerns in the estuarine system have been dissolved oxygen and
increased nutrient loads. DO is affected by the carbon and nitrogen components
of the wastewater effluents. It is also influenced indirectly by the phosphorus
content of these sources insofar as the latter stimulates phytoplankton growth.
     In 1947 the 14-mile stretch of the James River east of Richmond was
described as  "dead." In 1963 conditions had not improved despite growing public
concern. The Richmond News Leader described the river as a sewer. After
powerboat tour of the river, the editor described the river as green with algae,
septic, and laden with dead and dying fish. Even the hardy catfish, which normally
tolerates severely polluted waters, was observed gasping for its last breath. The
only birds in sight were circling turkey vultures, attracted by the floating offal. At
that time, the sewage collection system for Richmond was only partially opera-
tional and only 58 percent of the design flow of the city's sewage treatment plant
was being used. Raw sewage was being discharged into the James through Gillies
Creek, and it seemed doubtful that the river would ever meet the minimum
standard of 4.0 mg/L of dissolved oxygen required to permit recreational river
uses (Richmond News Leader, 1963).


Legislative  and Regulatory  History

     Concern over the severely degraded conditions in the James River prompted
the General Assembly to establish the State Water  Control Board (SWCB) in
1946.  The Board used its authority to put pressure on the city of Richmond to
expand its treatment facilities and on industries to cease their discharges into the
river (Richmond News Leader, 1963). Although the city responded favorably and
hopes were raised that the river could be fishable again within 10 years, a brief
inspection of the river in 1963 revealed that the expectations of the  Game and
Inland Fisheries Commission had been overoptimistic. The river was as dead as it
had been in 1947.
    The most significant impetus for change came with the passage of the
federal Clean Water Act in 1972. This legislation forced states and localities to
clean up municipal discharges and provided federal and state money with which
to do it. Richmond upgraded its sewage treatment plant in 1974 to remove as
much  as 80 percent of the suspended solids (secondary treatment)  (Richmond
Times-Dispatch, 1992). Later upgrades included a 500-million-gallon storm
overflow basin in 1983, a $73 million filtering system in 1990, and an agreement in
1992 to spend $82 million for more improvements scheduled for completion in
1998 (Richmond Times-Dispatch,  1992).
    Water supply and wastewater treatment facilities have been developing at a
rate commensurate with growth in the James River basin over the past few
decades. As a result, the James River, including the Appomattox River, has
received increased quantities of treated effluent from both municipal and industrial
sources. The  Virginia SWCB realized the necessity of planning for waste  treat-
ment requirements many years ago. Between 1960 and 1962, several water
                                                                                            9-5

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment


                        quality studies were conducted to document the water quality conditions in the
                        James River. These studies were among the earliest to quantitatively evaluate the
                        natural assimilation capacity of the James River in the Hopewell and Richmond
                        areas and to estimate the effect on stream quality of local industrial waste
                        discharges.
                             Recognizing that proper planning must be implemented on a regional basis to
                        protect the river system from impairment of its numerous desirable uses, SWCB
                        entered into an agreement with the USEPA in 1971, under section 3(c) of the
                        Federal Water Pollution Control Act of 1965, to study the James River. A princi-
                        pal outcome of this effort, completed in 1974, was the development of a James
                        River ecosystem model by the Virginia Institute of Marine Science (VIMS). The
                        SWCB used this model for wasteload allocations in the James River. Following
                        the 3(c) study, the Richmond-Crater 208 study was funded and a second detailed
                        water quality management model, the James Estuary Model (JEM), was devel-
                        oped for the upper James River estuary. This model was found to be inconsistent
                        with the VIMS model, and a review of both models was conducted by
                        HydroScience, Inc. The VIMS model was modified, and the revised James River
                        model (JMSRV) was recalibrated for use in updating wasteload allocations
                        (Hydroscience, 1980). The SWCB staff used the latter model to develop
                        wasteload allocations, i.e., the Upper James River Wasteload Allocation Plan, in
                        1982 (SWCB, 1982).
                             Nutrient reduction has also been considered, and control measures have
                        been implemented as part of the effort to clean up the Chesapeake Bay. The
                        1987 Virginia General Assembly took action to reduce nutrient enrichment by
                        enacting a phosphate detergent ban. The next step was taken in March 1988
                        when the Virginia SWCB adopted the Policy for Nutrient-Enriched Waters and a
                        water quality standard designating certain waters as nutrient-enriched. Under the
                        policy, municipal and industrial wastewater treatment plants with flows higher
                        than 1 mgd are required to remove phosphorus to meet a 2-mg/L limit. Facilities
                        are given up to 3 years to complete plant modifications to meet this requirement.


                        Impact of Wastewater Treatment:

                        Pollutant  Loading and Water Quality

                        Trends

                             Pollutant loads from POTWs have been reduced significantly over the past
                        two decades. In 1971 a large number of the municipal wastewater treatment
                        plants provided primary treatment. By 1984 there were more than 20 major point
                        source (municipal and industrial) discharges in the James River estuary from
                        Richmond to the mouth of the Chesapeake Bay. Table 9-2 lists the major munici-
                        pal and industrial treatment facilities discharging to the James River during 1983.
                        Figure 9-6 illustrates the locations of these point sources. Some of the municipal
                        facilities were consolidated to  form regional treatment plants. In the early 1980s
                        all POTWs achieved secondary treatment levels except the Lambert's Point
                        plant, which was considered at an advanced primary level (with phosphorus
                        removal). Since the early 1980s, waste load allocation studies have been prepared
                        to recommend further reductions of the BOD loads in the upper estuary. Some of
9-6

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                                                                 Chapter 9: James Estuary Case Study
Table 9-2. Major point source
Source: Lung and Testerman,

loads to the James
1989.

Discharger River Mile'
Richmond
DuPont
Falling Creek
Proctors Creek
Reynolds Metals
VEPCO
American Tobacco
ICI
Philip Morris
Allied-Chester
Allied-Hopewell
Stone Container
Hopewell
Williamsburg
James River
Boat Harbor
Nansemond
Army Base
Lambert's Points
Petersburg2
97.8
92.7
92.2
86.9
86.9
86.7
81.5
80.6
79.8
78.5
77.2
76.8
76.1






88.9
estuary in September

Flow
(mgd)
56.5
6.9
7.2
3.1
0.1
0.08
0.07
0.06
0.0

0.0
-13.5
35.8
9.2
12.5
16.1
6.8
12.1
20.2

1983.

CBOD,
(Ib/day)
4512
202
714
2602
1
0
84.8
8.9
83.2
3859
4809

16200
229
436
410
770
413
21893

1 Distance from the Chesapeake Bay.
2 10.8 miles from the James River



              Richmond
  Richmond WTP,
     DuPont
  Falling Ck WT

Proctoat Ck WTP
  Am. Tob.
  ICI Am.
  Phil. Mor./Ald ehtrdd
   Appomattox
Chlckahomlny River
           Aid. Hopewell ' •-'••:':..
           Hopewell WTP
                       Hopewefl
                                 Figure 9-6

                                 Locations of major point
                                 source discharges to the
                                 James estuary.

                                 Source: Lung and
                                 Testerman, 1989.
                                                                 •vWilliomsburg WTP
                                                                                        Checopeoke
                                                                                            Boy
                                                                                                  9-7

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
Table 9-3. Effect of phosphate detergent ban: Hampton
Roads Sanitation District. Source: Lung and Testerman,
1989.
Time Period
Pre-Ban
Transition
Post-Ban
Reduction
Influent
(mg/L)
7.4
5.6
4.9
34%
Effluent
(mg/L)
5.3
3.7
2.5
53%
                         them, such as those in the Hampton Roads Sanitation District, achieved BOD5
                         concentrations in the effluent much lower than 30 mg/L.
                              A study by the Virginia SWCB showed that the phosphate detergent ban
                         has resulted in reductions of total phosphorus concentrations of 34 percent for
                         POTW influent and 50 percent for effluent (SWCB, 1990). The SWCB's analysis
                         was based on the data collected from the POTWs operated in the Hampton
                         Roads Sanitation District, which operates nine POTWs in the James River basin.
                         The total phosphorus concentrations measured during different periods of the
                         study are shown in Table 9-3.
                              It should be pointed out that the analysis shown in Table 9-3 was based on
                         the POTWs that did not have phosphorus removal. The phosphate detergent ban
                         would have no effect  on the effluent phosphorus concentration from the POTWs
                         that remove phosphorus. Eventually, when the POTWs remove phosphorus to
                         meet the 2-mg/L requirement, the ban will reduce the costs of phosphorus
                         removal by reducing the influent concentrations.
                              The upstream boundaries and tributaries  the watershed of the estuary
                         account for approximately 94 percent of the drainage area measured below  the
                         confluence of the James and Chickahominy rivers. The area adjacent to the
                         Appomattox and James rivers below Richmond is thus a small fraction of the total
                         area drained by this system. Runoff from the contiguous drainage area during the
                         low-flow summer months represents a small fraction of the total river flow and
                         has a negligible effect on the water quality in the watershed. The importance of
                         the upstream pollutant loads was reported by HydroQual Inc. (1986). For ex-
                         ample, in the James, the upstream ultimate BOD  load is larger than any point
                         source load,  and the nitrogenous BOD (NBOD) is nearly equal in magnitude to
                         several of the largest point source  inputs. Similarly, the Appomattox River bound-
                         ary load is significant relative to the Petersburg wastewater treatment plant
                         discharge, the only significant point source input  to this river. Further, the three
                         point source inputs, the Richmond and Hopewell  treatment plants and Allied-
                         Hopewell, account for the major portion of the point source loads to the James.
                         The nonpoint source runoff load was shown to be relatively small in comparison
                         to the other inputs to the system (HydroQual, Inc.,  1986).
                              It should be pointed out that  CSO loads might be significant inputs to the
                         river system during wet weather conditions and might also be a factor in the
                         sediment interactions. In view of the purpose of this study, CSOs are not included
9-8

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                                                                Chapter 9: James Estuary Case Study
in this analysis. The CSO impacts are indirectly incorporated into the modeling
analysis to the degree that they are a component in the sediment oxygen demand
rates determined by HydroQual (1986).
     Figure 9-7 shows historical data of DO concentrations in the James estuary.
The June 1971  survey shows that the river reach from Richmond to Hopewell
was dominated by the waste discharges from and near Richmond. During that
survey, the river was under a moderately high temperature and high flow. Conse-
quently, the DO sag was carried downstream far enough (about 35 miles from
Richmond) to merge with the Hopewell area discharges. Downstream from
Hopewell, the DO concentrations started a slow recovery. In the lower estuary
from Mulberry Island (river mile 27) to Old Point Comfort (milepoint 0), there
were a number of large waste discharges. As a result of the strength of the tidal
(a)
(b)
(c)
(d)
      I
      s_x
      o
      Q
16

12
10
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      O
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      o
      o
 4
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  110
16
14
12
10
 8
 6
 4
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 0
  110
16
14
12
10
 8
 6
 4
 2
 0
  110
16
14
12
10
 8
 6
 4
 2
 0
i Q; =
Jx *
i 1 *
§
° °«B 0
•

a: ?
£ 1
'E 1
-S *
g •
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June 1971
m
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0 5


               100   90   80   70   60    50   40    30    20
                                               10
    Figure 9-7
    Spatial distribution of DO
    for the James estuary
    (a) June 1971, (b)
    September 1971, (c) July
    1976, and (d) July 1983.
    Sources: HydroQual, 1986;
Q   Lung, 1986; Lung and
                                  September  1971
               100   90    80   70   60    50   40   30    20   10    0
                                     July 1976
                                           I  I
                100   90    80   70    60   50    40   30    20   10    0
•^..i   i*
                                     July 1983
          110   100   90    80   70    60   50    40   30    20    10    0
                                River Miles from Mouth
                                                                            Testerman, 1989.
                                                                                              9-9

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment


                          action combined with the massive amount of dilution water available, a rather
                          steady DO level was measured. The DO levels seldom fell below 5.5 mg/L under
                          the worst conditions, and the depression of DO due to waste stabilization by
                          biological oxidation was usually less than 1 mg/L (Engineering Science, 1974).
                               The second survey in Figure 9-7 was conducted in September 1971, show-
                          ing even lower DO concentrations below Richmond, compared with the data from
                          the June 1971 survey. The  DO sag was below 4 mg/L near milepoint 89, which
                          was followed by a slow recovery. Also shown in Figure 9-7 is the DO profile
                          measured in July 1976. The DO sag level (below Richmond) improved slightly
                          from the 1971 condition although the sag was still below 5 mg/L. A mild recovery
                          occurred until the wastes from the Hopewell area entered the river and depressed
                          the DO concentration again, resulting in a second DO sag in the river. Such a
                          two-sag DO profile has been consistently observed since the late 1970s. The low
                          DO gradually increased downstream for a full recovery.
                               The DO condition observed in July 1983 is also presented in Figure 9-7.
                          With continuing treatment  upgrades beyond the secondary treatment for carbon
                          removal, the DO condition in the James estuary continued to improve in the
                          1980s. The data indicate that the minimum DO level was above 6 mg/L in
                          September 1983, a sign of continuing improvement of the water quality. The
                          impact from the Richmond area discharges has been significantly reduced
                          following the treatment plant upgrades.
                               Although the reduction of BOD5 loads from the POTWs was measured in
                          the last 20 years, no appreciable reduction of nutrient loads was detected until the
                          phosphate detergent ban in 1988.  Prior to the Virginia phosphate detergent ban,
                          Lung (1986) conducted a modeling  study assessing the water quality benefit of
                          point source phosphorus control in the James River basin. The model results are
                          summarized in Figure 9-8, showing the peak phytoplankton chlorophyll levels
                          predicted in the upper James estuary for various control alternatives ranging from
                          a phosphate detergent ban  to phosphorus removal. The model suggests that the
                          reduction of chlorophyll in the water column due to the phosphate detergent ban
                          would be minimal while phosphorus removal at POTWs would offer reasonable
                          reductions in phytoplankton biomass in the upper estuary.
Figure 9-8
Projected impact of point
source phosphorus
controls.
Source: Lung and
Testerman, 1989.
IUU
X"-N
"oiSO
Y 60
1 40
o
Q.
n


Present Loads
P
D
laeph
stergi
1 15% Load Reduction
d
sn
:e
t Bans

25% Load Reduction
Phosphorus Removal

1

? rMi
                                                     Control Alternative
9-10

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                                                             Chapter 9: James Estuary Case Study
Evaluation of Water Quality  Benefits

Following Treatment  Plant Upgrades

     From a policy and planning perspective, the central question in water
pollution control is simply Would water quality standards be attained if primary
treatment levels were considered acceptable?  In addition to the qualitative
assessment of historical data, water quality models can provide a quantitative
approach to judge improvements in water quality achieved as a result of upgrades
in wastewater treatment. The James River Model (JMSRV), originally developed
by Hydroscience (1980) and subsequently enhanced by HydroQual (1986), Lung
(1986), and Lung and Testerman (1989), and calibrated using data for September
1983 conditions (Figure 9-9), has been used to demonstrate the water quality
benefits attained by the secondary treatment requirement of the 1972 CWA
    25
f«
O
00  ,
o  5
                                  0.5

                                <0.4
                              0.
                               00.2
                              "c
                               §•0.1
                              O
 0 I	—-H	.—i	.	,	1   •  i	1	1   0.0        .__....
  110 TOO 90 80 70 60 50 40 30 20 TO  0     1TO TOO 90 80 70 60 50 40 30 20 TO 0
2.0 i	•	>	•—i	1	•—•	.	1	—,   0.5
                                    2
I
                                                 *e
                                  r
                                  J.0.3
                                  Q.
                                  I 0.2
                                  O
                                  I0'1
   0.0 '—H—'—<—i	1—i—i  i   i—i—I   0.0
     110 100 90 80 70 60 50 40 30 20  TO 0    1
                                       100 90 80 70 60 50 40 30 20  10 0
   2.0
  !0.5
   0.0
                                    50
                                O 30

                                | 20
                                o
                                | TO
                                6  „
    1.5
   110 TOO 90 80 70 60 50 40 30 20 TO 0    1TO 100 90 80 70 60 50 40 30 20 10 0
                                  12

                                  TO

                                 ? 8

    1.0
   0.5
  "0.0
                                >§  6
                                8  41
                                   2
     110 TOO 90 80 70 60 50 40 30 20 TO 0    1 TO TOO 90 80 70 60 50 40 30 20  TO 0
          River Miles from Mouth              River Miles from Mouth
         Legend:   } Observed Data (Avg. and Range) 	Model Results
                                                                       Figure 9-9
                                                                       James River model
                                                                       calibrations for September
                                                                       1983.
                                                                       Source: Lung, 1991.
                                                                                       9-11

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment


                          (Lung, 1991). Using the model, existing population and wastewater flow data (ca.
                          1983) were used to compare water quality for summer low-flow and 7Q10 low-
                          flow conditions simulated with three management scenarios: (1) primary effluent,
                          (2) secondary effluent, and (3) existing wastewater loading. Water quality condi-
                          tions for these alternatives were simulated using freshwater and wastewater flow
                          data for 1983, a year characterized by 66 percent of the summer average flow
                          (see Figure 9-3) of the James River (Figure 9-10).
                               Using the primary effluent assumption, under summer low-flow conditions,
                          water quality is noticeably deteriorated in comparison to the 1983 calibration
                          results. DO concentrations downstream of Richmond (RM 90) are computed to
                          be near zero under the primary scenario. Using the secondary assumption, the
                          significant reduction in BOD5 loading significantly improves DO between Rich-
                          mond and Hopewell, Virginia. In comparison to the primary scenario, minimum
Figure 9-10
Comparison of simulated
impact of primary,
secondary and existing
1983 effluent levels on DO:
(a) summer 1983
conditions and (b) 7Q10
low-flow conditions.
Source: Lung,  1991.
                             (a)
                              (b)
12
   11
   10
j  9
x.
E  8
«^_^

I  ?
I"  6
o

"I  4
en
•-  T
Q  3
   2
    1
                                        O
                                        -o  5
                  1983 Loads
                  Secondary Treatment
                  Primary Treatment
                                           110  100  90  80   70  60   50  40   30  20   10
                                                           River Miles from Mouth
                   1983 Loads
                   Secondary Treatment
                   Primary Treatment
                                           110  100  90   80  70   60  50   40  30   20  10
                                                           River Miles from Mouth
9-12

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                                                              Chapter 9: James Estuary Case Study
monthly averaged oxygen levels increase to almost 3.5 mg/L from less than 0.5
mg/L under the secondary effluent scenario. As shown with both observed data
(Figure 9-9) and state-of-the-art model simulations (Figure 9-10), the implementa-
tion of secondary and better treatment has resulted in significant improvements in
the DO status of the estuary.
     As demonstrated with the model, better-than-secondary treatment is re-
quired to achieve compliance with the water quality standard of 5 mg/L under
extreme 7Q10 low-flow conditions (Figure 9-10) for DO downstream of Rich-
mond. In contrast to the 1950s and 1960s, the occurrence of low-oxygen condi-
tions has been virtually eliminated within the upper James River estuary. Addi-
tional improvements in water quality, in terms of reduced algal biomass and still
greater improvements in DO levels, have been achieved as a result of advanced
secondary levels of wastewater treatment for the Upper James River.


Impact of  Wastewater Treatment:

Recreational and  Living  Resources

Trends

     Upgrades of wastewater treatment plants to secondary treatment in the
1970s and continued commitment to water quality-based pollution controls
throughout the 1980s and 1990s have achieved a dramatic recovery for the James
River. Instead of turkey vultures, residents of Richmond currently gaze at blue
herons, bald eagles, and ospreys as they circle overhead (Epes,  1992). Although
passage of the Clean Water Act in 1972 was the most significant factor contribut-
ing to the comeback of the James, other factors contributing to improvements in
wildlife habitat included the creation of a flood control reservoir in the early 1980s
to stabilize flow, the ban of the insecticide DDT, and floods and hurricanes in the
1960s and 1970s.
     The ban on DDT allowed certain birds affected by egg shell thinning,
including eagles and ospreys, to recover. The floods and hurricanes contributed to
habitat improvement by punching holes in several of the dams in the river, allow-
ing migrating fish to pass through once more (Epes, 1992). Those holes and
subsequent man-made fish ladders have allowed fish to swim farther upstream to
spawn again.
     Above the falls, the return of smallmouth bass has made the upper James
one of the best smallmouth bass fisheries in the country. Below Richmond,
abundant largemouth bass attract the national Bassmasters fishing tournaments.
Striped bass, an anadromous (saltwater-to-freshwater migrating) fish, has re-
turned to the James due in part to a state harvesting moratorium in effect for
several years in the Chesapeake Bay. In fact, a 25-pound striped bass was caught
in 1992 near Williams Dam in Richmond (Epes, 1992).
     Fish-eating birds have also recently returned to the James. In the 1970s
there were no bald eagles or ospreys nesting on the James River. In 1992 three
pairs of bald eagles and six pairs of ospreys had reclaimed their historical nesting
sites on the James (Bradshaw, 1992). Great blue herons boast about 200 pairs
(Bradshaw, 1992). Birds began to return in the mid-1980s (Table 9-3). Cattle
egrets and double-crested cormorants extended their ranges to colonize the James
                                                                                          9-13

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
                         possibly due to reduction in available habitat elsewhere. In 1992, there were about
                         250 pairs of each overwintering in the region from Richmond to the Benjamin
                         Harris bridge (Bradshaw, 1992). Cattle egrets eat reptiles and eels, and double-
                         crested cormorants eat fish. These birds are no doubt responding to the increase
                         in the stream quality for fish and other aquatic life now that organic and nutrient
                         loads to the James have been controlled.


                         Summary  and Conclusions

                              An analysis of the existing water quality data for the James River estuary
                         has been conducted to document the historical changes in waste loads and the
                         water quality improvement in the estuary from 1971 to the mid-1990s. The latest
                         water quality model for the upper James estuary was modified to include the
                         lower portion of the estuary. This modified model was calibrated and verified
                         using three sets of water quality data. Finally, the verified model was used to
                         evaluate the water quality improvement due to the treatment upgrades from
                         primary to secondary at the POTWs. Altogether, six simulation scenarios, incor-
                         porating different ambient environmental conditions and waste load levels, were
                         developed for evaluation.
                              The analysis of POTW waste loads indicated significant reduction of BOD5
                         discharged into the James estuary starting in the early 1970s. By the mid-1980s,
                         many POTWs had achieved high degrees of carbon removal with treatment
                         levels beyond secondary. Nutrient reduction did not start until  1988, when the
                         phosphate detergent ban became effective.
                              A review of the historical water quality data showed the improvement of
                         DO conditions in the James estuary from a DO sag of much lower than 5 mg/L in
                         1971 to levels consistently above 5 mg/L in the 1980s. Nutrient concentrations in
                         the water column of the James estuary have  remained  quite stable over the past
                         20 years. The model results showed a clear, progressive rise in DO levels in the
                         estuary from primary treatment to secondary treatment, and to treatment beyond
                         secondary at the POTWs. Based on the analyses of historical waste load data,
                         water quality data, and model results, it can be concluded that the treatment
                         upgrades from primary to secondary and better  levels  of treatment at POTWs
                         provided significant water quality improvement in the James River basin. With the
                         cleanup of the James River, visitors to Richmond, Virginia, can enjoy a riverboat
                         dinner cruise or a stroll along the refurbished 2-mile  canal walk. More adventur-
                         ous visitors can challenge themselves by rafting and kayaking on the only Class
                         IV white water located in an urban river in the country (McCulley, 1999). Birds
                         and fish are also making a remarkable recovery in the James River basin in
                         response to water quality improvements.
9-14

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                                                               Chapter 9: James Estuary Case Study
References

Bradshaw, Dana. 1992. Virginia Department of Game and Inland Fisheries.
    Personal communication, November 4, 1992.
Engineering Science.  1974.  Lower James River basin comprehensive water
    quality management plan. Planning Bulletin 217-B. Final report prepared
    for Virginia State Water Control Board by Engineering Science Co.
Epes,  C. 1992, June 15. Honk if you spot a brown pelican. Richmond Times-
    Dispatch. Richmond, VA.
Forstall, R.L.  1995. Population by counties by decennial census: 1900 to
    1990. U.S.  Bureau of the Census, Population Division, Washington, DC.
    .
HydroQual, Inc. 1986.  Water quality analysis of the James and Appomattox
    Rivers. Report prepared for Richmond Regional Planning District Commis-
    sion. June.
Hydroscience, Inc.   1980.  Water quality analysis of the upper James River
    estuary. Report prepared for Virginia Water Control Board. April.
Lung, W.S. 1986. Assessing phosphorus control in the James River basin. Jour.
    Envir.  Eng., ASCE 112(1): 44-60.
Lung, W.S.  1991.   Trends in BOD/DO modeling for wasteload allocations of
    the James River estuary. Technical memorandum prepared under sub-
    contract for Tetra Tech, Inc., Fairfax, VA, by Envirotech, Inc.,
    Charlottesville, VA.
Lung, W.S., and N. Testerman. 1989. Modeling fate and transport of nutrients in
    the James estuary. J. Envir. Eng., ASCE  115(5): 978-991.
McCulley, C. 1999,  October 17. Rapids transit. The Sun. Section R. Baltimore,
    MD.
OMB. 1995. OMB Bulletin No. 99-04. Revised statistical definitions of Metro-
    politan Areas (MAs) and Guidance on uses of MA definitions. U.S. Census
    Bureau, Office of Management and Budget, Washington, DC. .
Richmond News Leader.  1963, October 8.  Neglected asset: the James.
Richmond Times-Dispatch.   1992. Editorial.
SWCB.  1982.  Upper James River estuary wasteload allocation plan.  Final
    report prepared for Richmond Regional Planning District Commission by
    Virginia State Water Control Board, Richmond, VA.
USDOC.  1998. Census of population and housing. U.S. Department of
    Commerce, Economics and Statistics Administration, Bureau of the Census -
    Population Division, Washington, DC.
USEPA (STORET). STOrage and RETrieval Water Quality Information System.
    U.S. Environmental Protection Agency, Office of Wetlands, Oceans, and
    Watersheds, Washington, DC.
USGS.  1999. Streamflow data downloaded from the U.S. Geological Survey's
    National Water Information System (NWIS)-W Data retrieval for historical
    streamflow daily values, .
                                                                                           9-15

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
9-16

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   Chapter  10
 Upper
 Chattahoochee
 River  Case
 Study
    The Southeast Basin (Hydrologic Region
3), covering a drainage area of 278,523 square
miles, includes the Chattahoochee-Flint-Apalachicola
River, which has a length of 524 miles and a drainage
area of 19,600 square miles (Iseri and Langbein, 1974).
On the basis of a mean annual discharge (1941-1970) of
24,700 cfs, the Chattahoochee-Flint-Apalachicola River ranks
23rd of the large rivers of the United States (Iseri and Langbein,
1974). Figure 10-1 highlights the location of the Upper Chattahoochee
River case study watersheds (catalog units) and the city of Atlanta,
Georgia, identified in this river basin as one of the urban-industrial
waterways affected by severe water pollution problems during the
1950s and 1960s (see Table 4-2). In this chapter, information is pre-
sented to characterize long-term trends in population, municipal wastewa-
ter infrastructure and effluent loading of pollutants, ambient water quality,
environmental resources, and uses of the Upper Chattahoochee
River. Data sources include USEPA's national water quality data-
base (STORET), published technical literature, and unpublished
technical reports ("grey" literature) obtained from local agency
sources.
    The Chattahoochee River Basin constitutes almost 40 percent
of the Chattahoochee-Flmt-Apalachicola River Basin (Figure 10-2),
which discharges into the Gulf of Mexico. The Chattahoochee River
flows from northeast Georgia through metropolitan Atlanta to West
Point Dam. From there the river forms the Georgia-Alabama border
and, for a short distance, the Georgia-Florida border. Near the
southern border of Georgia the Flint River joins the Chattahoochee
River to form the Apalachicola River. Major urban centers in the
Figure 10-1
Hydrologic Region 3 and
the Chattahoochee-Flint-
Apalachicola River Basin.
                                                                          10-1

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
Figure 10-2
Location map of Upper
Chattahoochee Basin.
River miles shown are
distances from Gulf of
Mexico.
                                                 85°30'
                                     34°00'
                                    32°30'
                                                                                 40 Miles
                                                                                        34°00'
                                                                                        32°30'
                                              85°30'
                                                                     84°00'
                          Upper Chattahoochee River Basin include Atlanta, Gainesville, Marietta, Cornelia,
                          and Alpharetta, Georgia. The Atlanta region represents only 3.6 percent of
                          Georgia's total land area but contains one-third of the state's population (ARC,
                          1984). The large volume of wastewater discharged in the Atlanta area has a far-
                          reaching effect on water quality conditions in receiving waters. The Upper
                          Chattahoochee River is by far the largest river in the Atlanta region. Other streams
                          in the region include Sweetwater Creek, South River, Flint River, Yellow River,
                          Peachtree Creek, and Line Creek.
                              The Chattahoochee River is Atlanta's major water supply source and
                          receptacle for wastewater disposal. The Upper Chattahoochee River  Basin
                          provides numerous recreational areas and fish and wildlife habitats. Lake Sidney
                          Lanier, for example, is a nationally popular water resort area. The area from
                          Buford Dam to Peachtree Creek  has been under intensive development pressures
                          that threaten the water quality of the Chattahoochee River.


                          Physical  Setting   and  Hydrology

                              The Upper Chattahoochee River Basin covers  10,130 square miles from the
                          southern slopes of the Blue Ridge mountains, in northeast Georgia, to the West
                          Point Dam at the Georgia-Alabama state line. The flow length of this section is 250
                          river miles, generally to the southwest. The basin is narrow in relation to its length,
                          the average width being less than 40 miles. Elevations in the Upper Chattahoochee
10-2

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                                                     Chapter 10: Upper Chattahoochee River Case Study
Basin range from approximately 4,000 feet at the headwaters to approximately 635
feet at West Point Lake. Air temperature tends to be cooler in the mountains and
wanner in the southern areas of the basin; the annual air temperature averages
about 16 °C. Average annual rainfall in the basin is about 54 inches over the basin
area of 3,440 square miles. The rainfall tends to be greatest in upland areas and in
the southern region of the basin (Cherry et al., 1980; Lium et al., 1979).
     Flow in the river is dependent on rainfall and regulation by the hydroelectric
generating facilities at Buford Dam and Morgan Falls Dam. High-flow conditions
usually occur in the spring and low-flow conditions in late autumn (Figure 10-3).
The most pronounced changes in regulated flow have occurred as a result of the
construction and operation of the Buford Dam since 1957. In the mid-1960s, the
city of Atlanta and the Georgia Power Company modified the Morgan Falls Dam
and Reservoir, just upstream of Atlanta, to provide a minimum flow of 750 cfs
from Morgan Falls. Since 1965 minimum streamflows have been higher and more
consistent as a result of those modifications (Figure 10-4). The average flow at
                                                                              Figure 10-3
                                                                              Monthly trends in
                                                                              streamflow for the
                                                                              Chattahoochee River.
                                                                              Monthly mean, 10th, and
                                                                              90th percentile statistics
                                                                              computed for 1951-1980
                                                                              (USGS Gage #02336000
                                                                              at Atlanta, Georgia).
                                                                              Source: USGS, 1999.
                    ONDJ  FMAMJ  JAS
           10000
         •e
                                              Figure 10-4
                                              Long-term trends in mean,
                                              10th, and 90th percentile
                                              statistics computed for
                                              summer (July-Septem-ber)
                                              streamflow for the
                                              Chattahoochee River
                                              (USGS Gage #02336000
                                              at Atlanta, Georgia).
                                              Source: USGS, 1999.
                       1950
1960
1970
1980
                                                         1990
                   --  90%ile
                                                 mean & ratio
                                                                                                10-3

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
                            Table 10-1. Metropolitan Statistical Area (MSA) counties in the Upper
                            Chattahoochee Basin case study.  Source: OMB, 1999.
                                         Barrow
                                         Bartow
                                         Carroll
                                         Cherokee
                                         Clayton
                                         Cobb
                                         Coweta
                                         DeKalb
                                         Douglas
                                         Fayette
Forsyth
Fulton
Gwinnett
Henry
Newton
Paulding
Pickens
Rockdale
Spalding
Walton
                         Buford Dam, based on 35 years of record, is 2,168 cfs. The average flow near
                         Atlanta, based on 43 years of record, is 2,603 cfs. Regulations for minimum
                         streamflow volumes set in 1974 require a minimum release of 1,100 cfs from
                         Morgan Falls, further increasing minimum streamflows near Atlanta (Cherry et
                         al, 1980; Liumetal., 1979).


                         Population, Water,  and Land  Use  Trends

                             The Upper Chattahoochee River case study area includes several counties
                         that are defined by the Office of Management and Budget as Metropolitan
                         Statistical Areas (MSAs) or Primary Metropolitan Statistical Areas (PMSAs).
                         Table 10-1 lists the MS A and counties included in this case study. Figure 10-5
                         presents long-term population trends (1940-1996) for the counties listed in Table
                         10-1.
                             From 1940 to 1996 the population in the Upper Chattahoochee River case
                         study area increased dramatically (rising from 0.41 million in 1940 to 3.53 million
                         in 1996). The U.S. Bureau of the Census reported the 1970 population of the
Figure 10-5
Long-term trends in
population in the Upper
Chattahoochee River
basin.
Sources: Forstall, 1995;
USDOC, 1998.
                                          1940  1950   1960  1970   1980   1990   1996
10-4

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                                                     Chapter 10:  Upper Chattahoochee River Case Study
Atlanta area to be 1.7 million. By 1990 this number had risen to 2.95 million
(Forstall, 1995; USDOC, 1998). During the 1950s through the 1970s, population in
the Atlanta region increased by 34 percent to 39 percent; the greatest growth
rates were recorded in 1950-1960 (39 percent) and 1970-1980 (38 percent).
During the 1980s and 1990s, the rate of growth slowed down considerably: the
population increased by 22 percent from 1980 to 1990 and by only 19 percent
from 1990 to 1996 (Forstall, 1995; USDOC, 1998). During the 1970s, population
density in the area varied by about an order of magnitude from approximately 40
persons per square mile in the rural, headwater areas of the basin to 492 persons
per square mile in the urban environs of Atlanta (Faye et al., 1980).
     Land in the Upper Chattahoochee Basin, upstream and downstream of
Atlanta, is predominantly forest. The Atlanta area of the basin is predominantly
residential. Agricultural activity is fairly evenly distributed through the basin. Table
10-2 shows the major land uses in the basin (Cherry et al., 1980; Lium et al.,
1979; Stamer et al.,  1979). Agricultural activities above the Buford Dam are
concentrated in stream valleys  and on the lower slopes. Crops and pastures
occupy a significant portion of the agricultural areas, but poultry operations are
the economically dominant agricultural activity. Urban areas are predominantly
residential, but industrial activities are significant. Industrial activities include
automobile assembly, food processing, and light manufacturing. Intense industrial
land use dominates the area downstream of Interstate Highway 75 (Mauldin and
McCollum, 1992).
     Power generation, water supply, water-quality maintenance, and recreation
are activities currently supported along the Chattahoochee River. Six power-
generating facilities use the resources of the Chattahoochee River. The Buford
Dam and Morgan Falls Dam are peak-power hydroelectric generating facilities.
The other four are fossil-fuel thermoelectric power plants. The six plants have a
combined generating capacity of approximately 3.8 million kilowatts. Two fossil-
fuel plants near Atlanta discharge nearly  1000 cfs of cooling water to the river.
     As of 1998, 29 public water treatment plants process water withdrawn from
rivers and lakes in the Atlanta region and 3 new treatment facilities were proposed
for the Atlanta area.  The largest water treatment plants in the region are operated
by the city of Atlanta (Hemphill & Chattahoochee, design capacity 201 mgd),
Dekalb County (Scott Candler, 128 mgd), Gwinnett County (Lake Lanier, 120 mgd),
and Atlanta-Fulton County (Atlanta-Fulton County, 90 mgd). The Chattahoochee
River and Lake Lanier are their main sources of raw water. The total capacity of
Table 10-2. Land use in the Upper Chattahoochee River Basin.
Area I 	 Percentage Breakd
Location (mi2) Urban Agriculture
Above Buford Dam
Buford Dam - Atlanta
Atlanta - Fairburn
Fairburn - Whitesburg
Whitesburg - West Point Dam
1,040
410
610
370
1010
4
22
40
6
4
16
18
12
17
17

Forest
81
60
49
77
79
                                                                                               10-5

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
                         the public water supply withdrawals from the 14 largest water treatment plants is
                         770.5 mgd (ARC, 1998). As of the late 1990s, approximately 443 mgd was with-
                         drawn from water sources in the Upper Chattahoochee, primarily from surface
                         water sources (ARC, 1998). During the mid-1970s, water use was estimated at 180
                         mgd with an increase in demand to 484 mgd fairly accurately projected for the year
                         2000 (Lium et al., 1979). Providing about 85 percent of the region's water supply,
                         the Chattahoochee River and Lake Lanier system and the Etowah River and
                         Allatoona Lake system are the most important sources of public water. As  of the
                         late 1990s, residential and commercial water uses accounted for 54 percent and 23
                         percent of the total water demand, respectively. Government activities accounted
                         for 6 percent and manufacturing uses for only 4 percent; approximately 14 percent
                         could not be accounted for (Kundell and DeMeo, 1999). By the year 2020, regional
                         water demand is expected to increase by approximately 46 percent of the with-
                         drawals ca. 1998. The projected increase in water demand and the limited availabil-
                         ity of surface water and ground water supply sources in northern Georgia are a key
                         factor in the need for regional cooperation to meet the challenges posed by water
                         supply and water quality problems in the Atlanta region (Kundell and DeMeo,
                         1999).
                              Water-based recreational activities are abundant all along the
                         Chattahoochee River. The headwaters are popular for trout fishing, camping, and
                         hunting. Lake Sidney Lanier maintains numerous boat launches, campgrounds,
                         marinas,  yacht clubs, and cottages. The reach from Buford Dam to Atlanta
                         supports  fishing, canoeing, and rafting. The reach between Morgan Falls and
                         Peachtree Creek, one of the most scenic on the river, is the site for an annual raft
                         race that draws thousands of participants and onlookers to the area. West Point
                         Lake, at the base of the Upper Chattahoochee River Basin, is  an impoundment
                         created by the construction of West Point Dam in 1974. This lake is widely used
                         for fishing, boating, camping, and swimming.


                         Historical  Water Quality  Issues

                              The poet Sidney Lanier, who praised the Chattahoochee in his "Song  of the
                         Chattahoochee," would not have been so inspired during the 1940s, 1950s, and
                         1960s. The Chattahoochee River was characterized by poor water quality for a
                         reach of 70 miles below Atlanta. The first 40 miles were described as "grossly
                         polluted," and responsibility was attributed to inadequately treated wastewater,
                         particularly from Atlanta's R.M. Clayton sewage treatment plant, at the mouth of
                         Peachtree Creek (EPD, 1981). Figure 10-6 shows the effect Atlanta's wastewater
                         discharges historically have had on the water quality of the Chattahoochee  River,
                         with DO levels drastically depleted downstream of Atlanta near SR-92 (RM 280).
                         At Fairburn, an average of 13 percent of the river flow consisted of wastewater
                         (Stamer et al., 1979). From July through October heat and low flow placed the river
                         in near septic conditions, with DO below 4 mg/L 64 percent of the time. During the
                         period from 1968 to 1974, DO concentrations were 64 percent less in the summer
                         months than in January and minimum DO levels were consistently below 1  mg/L
                         (EPD, 1981). In 1973 DO concentrations dropped to zero during September. As of
                         1972 the R.M. Clayton plant was still releasing large quantities of wastewater
                         receiving only primary treatment. Fecal coliform densities, ammonia, BOD5, and
10-6

-------
                                                    Chapter 10: Upper Chattahoochee River Case Study
Dissolved Oxygen (mg/L)
3 K> *» O) CX) C





„*-,
."...«-.?:<
8


**•!
•-S^HHTV1^"
f.ajr3. >****.'
¥ .
. 	 	 ' 	 - -A_.
I,V',
/ 1
^ : Seconder
	 ;"!/ 	
t**..* .;'...
Atlanta Water Intake
' RM 299.3
SR92 R
k Campbel
/ Treatment

A 280.3
on Ferry
On-line

                                                                            Figure 10-6
                                                                            Long-term trends of DO
                                                                            concentration upstream
                                                                            and downstream of Atlanta
                                                                            wastewater discharges.
                                                                            Source: EPD, 1981.
             1960     1965     1970     1975     1980     1985     1990
              Intake /Avg
RM 280 /Avg - a- - Intake /Mm  -* • RM 280 /Win
suspended solids concentrations continued to be high above and below the discharge
at Peachtree Creek. Fish kills caused by discharges of raw sanitary sewage and
industrial chemicals were commonplace before 1976 (Mauldin and McCollum,
1992).
     Rainfall in the area results in overflows from combined sewer systems
(CSOs) and large amounts of urban runoff, contributing to large dissolved and
suspended constituent loads to the river. Twelve CSOs have been identified in the
watershed (Mauldin and McCollum, 1992). Low-flow periods result in less dilution
of wastewater, resulting in low DO concentrations, high BOD5, high fecal
coliform densities, and other problems.
     A severe drought in 1988 caused the DO level to dip below 4 mg/L in the
study region from April to August (Mauldin and McCollum, 1992). A major fish
kill occurred during October of 1988 due to an unidentified agent (Mauldin and
McCollum, 1992). The many impoundments along the river and releases of
cooling water from fossil fuel plants, in excess of 1,000 cfs, contribute to water
temperature increases, further reducing the waste assimilation capabilities of the
river. Atlanta's population is served by 27 water pollution control plants, with
designated flows greater than 0.01 mgd, located along the river and its tributaries.
The 12 largest water pollution control plants in the Atlanta region have a total
design capacity  of 404 mgd. The largest facility, the R.M. Clayton plant, is
operated by the  city of Atlanta and has a capacity of 120 mgd. More than half of
the total volume of wastewater enters the river near river mile 301  downstream
of the city of Atlanta's water intake (Mauldin and McCollum, 1992).


Legislative  and  Regulatory History

     Concern for the coordination of water and sewer facility planning and
operation has existed in Atlanta since the early 1930s. Construction of the metro-
politan sewer system began in 1944 as a cooperative effort between Atlanta local
governments. From 1950 to 1952 a major functional consolidation, The Plan of
Improvement, was prepared to better define service functions between the city of
Atlanta and Fulton County. Atlanta was the primary provider of sewage treatment
at that time. During the 1960s the near septic conditions in the river concerned
                                                                                             10-7

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Progress In Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
                          many people. Utility of the waters was greatly reduced, threatening water
                          supplies, recreation, and aquatic habitats. Studies were conducted to identify
                          problems and needs. Technology was available to remedy many of the problems
                          identified, but funding was unavailable.
                               The Georgia Water Quality Control Act (enacted 1964, amended) was the
                          first major state law to be applied to water quality management. The act gives the
                          Georgia Environmental Protection Division (EPD) power to control all types of
                          pollution in the state's waters from both point and nonpoint sources. In the late
                          1960s the Atlanta Region Metropolitan Planning Commission (now the Atlanta
                          Regional Commission or ARC) prepared several reports on the consolidation of
                          water and sewer services.  The Preliminary Water and Sewer Report, issued in
                          1968, provided elements of an Administrative Plan for water and sewers in the
                          Atlanta region. The report called for a basinwide water/sewer authority, represent-
                          ing nine counties, to oversee water quality management on a basinwide scale.
                          Unfortunately, local officials did not support the plan because of the large esti-
                          mated cost (Hammer et al., 1975).
                               The next state-level move toward regulation was the  Metropolitan River
                          Protection Act  (MRPA) (enacted 1973, amended), which allows the ARC to
                          advise local governments when proposed developments violate the Chattahoochee
                          Corridor Plan. The plan establishes standards for development based on the
                          carrying capacity of the land within 2,000 feet of impoundments or riverbank of
                          the Chattahoochee or within the  100-year floodplain, whichever is greater (ARC,
                          1984). The Soil Erosion Act of 1975 also created controls over the effects of
                          development in the area. This act requires local counties and municipalities to
                          adopt and enforce local ordinances to control soil erosion from land-disturbing
                          activities within their jurisdiction.
                               The 1972 CWA resulted in significant improvement of the water quality in the
                          Upper Chattahoochee River Basin. Funding was provided under the CWA in the
                          form of the Construction Grants Program. The state of Georgia received $117
                          million in 1976 under this program, but funding decreased steadily. Only $41 million
                          was provided in 1983, despite the fact that Georgia reported needs of $300 million in
                          1983 (Lawler et al., 1989). Beginning in 1988 funding for the Construction Grants
                          Program was reallocated to the State Revolving Fund (SRF) as a mechanism for
                          providing financial assistance to municipalities. The CWA established secondary
                          treatment as the minimum allowable level for municipal plants. The National
                          Pollutant Discharge Elimination System (NPDES), a national permit program that
                          regulates polluted discharges and requires permittees to monitor effluent quality, is
                          also included in the CWA. States were called upon to develop water quality stan-
                          dards, water use classification, and effluent limits based on water quality criteria
                          established by USEPA.
                               Attempts were made to improve water quality in the Chattahoochee River
                          by regulating flow. The EPD set requirements for minimum flow of 750 cfs
                          upstream of Atlanta (Cherry et al., 1980). A regulatory dam downstream from
                          Buford Dam has been proposed and modeled. The dam would ensure Atlanta's
                          water supply into the 21st century and aid in regulating river flow. The require-
                          ment for minimum releases from Buford Dam would be eliminated. It is not
                          possible to greatly affect flow since there is a limited amount of water available
                          and water supply demands and wastewater flows continue to increase.
10-8

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                                                Chapter 10:  Upper Chattahoochee River Case Study
Impact of Wastewater Treatment:

Pollutant  Loading  and  Water Quality

Trends

    Major improvements in water quality occurred in the Chattahoochee Basin
during the 1970s and early 1980s, resulting from implementation of secondary
treatment. The effects of the increasing load of wastewater were diminished by
better treatment technology. Figure 10-7 shows the increasing trends of effluent
discharge rates for the area's larger wastewater treatment plants. By 1974 all
Atlanta-area waste treatment facilities had been upgraded to provide secondary
levels of treatment. Before implementation of secondary treatment, DO levels
were severely reduced by wastewater discharges from Atlanta (Figure 10-8).
Figures 10-6 and 10-8 show dramatic improvements beginning in 1974. The
        D
        03
        §
                                           Figure 10-7
                                           Long-term trends of
                                           wastewater flow for major
                                           wastewater treatment
                                           plants in the Atlanta area.
                                           Sources: ARC,  1984;
                                           USEPA, 1971; USPHS,
                                           1963; Woodward,  1949;
                                           Richards,  1999.
                    1950
1960
1970
1980
1990
                                                          2000
               South R & Intrench -«- R.M. Clayton    -a- - Utoy Creek
                    1950      1960      1970  '   1980
                          River Mile 280-290 near Atlanta GA
                            1990
                                                                      Figure 10-8
                                                                      Long-term trends of mean,
                                                                      minimum, and maximum
                                                                      summer DO in the
                                                                      Chattahoochee River near
                                                                      Atlanta, Georgia (RF1-
                                                                      03130002066) (mile 280-
                                                                      290).
                                                                      Source: USEPA (STORET).
                            Mean	Mm  	Max
                                                                                      10-9

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
                          effects of secondary treatment on DO concentrations are particularly notable
                          during the summer months (Figure 10-9). Water quality has improved despite a
                          doubling of Atlanta's population over the period from 1970 to 1996 (Figure 10-5).
                               Many advances in improving water quality since 1974 can be attributed to
                          continually improving operation and maintenance procedures. Figure 10-10
                          indicates improvements in suspended solids concentrations and BOD5 in the
                          effluent waste water from the R.M. Clayton plant, the largest in the Atlanta
                          region. These improvements resulted primarily from improved operator training
                          and upgrading of the solids-handling facility. Similar changes took place at other
                          area plants during this time. The R.M. Clayton plant operated at a primary level
                          of treatment from the late 1930s to the mid-1960s. For much of this time the
                          capacity of the plant exceeded the design flow and treatment was below design
                          level. When  the plant was upgraded to provide secondary treatment, around  1968,
                          the design flow was also increased to 120 mgd. A portion of the wastewater flow
                          continued to receive only primary treatment into the early 1970s, when further
Figure 10-9
Comparison of January
and July mean dissolved
oxygen below Atlanta
wastewater discharges
before and after upgrade to
secondary treatment.
Source: EPD, 1981.
                                                    January
                                                    Before: 1964-68 r    After. 1975-80
Figure 10-10
Performance of the
R.M. Clayton
wastewater treatment
plant.
Sources: ARC, 1984;
USEPA, 1971; USPHS,
                                                                                         Q
                                       1970 '  ' 1975 '  ' 1980 '  ' 1985     1990     1995     2000
—- NH3-N -A
• TSS
 10-10

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                                                     Chapter 10:  Upper Chattahoochee River Case Study
improvements were made. In 1974 the R.M. Clayton Plant was providing second-
ary treatment to 100 percent of the plant's wastewater flow. In the early 1980s
operating and maintenance improvements further lowered BOD5 concentration in
the effluent wastewater. The R.M. Clayton plant was upgraded to advanced
secondary with ammonia removal in 1988. By December 2000, the R.M. Clayton
plant, the Utoy plant, and the South River plant will have state-of-the-art effluent
filters, biological phosphorus removal, ultraviolet disinfection, and new headworks
(Richards, 1999). Decreases in the BOD5 loading of effluent at the R.M. Clayton
Plant as a result of upgrading levels of treatment are shown in Figure 10-11.
     All of the larger wastewater treatment plants in the Atlanta region must
meet treatment requirements more stringent than secondary treatment. Phospho-
rus removal and restrictions on phosphates in detergents, for example, have
resulted in a decline of ambient phosphorus concentrations downstream of Atlanta
from approximately 1.0-1.2 mg/L in the early 1980s to approximately 0.1 mg/L a
decade later (ARC, 1998). Land application of treated wastewater is also being
used at several facilities in the region, with treated wastewater sprayed on
forestland, golf courses, or other landscaped areas. At the 4,000-acre E.L. Huie
Land Application site, the Clayton Water Authority operates the largest site,
treating 18 mgd by reclaiming the treated effluent for its water supply since the
water percolates through the soil and back to the raw water source (ARC, 1998).
     A combined sewer system, originally constructed in Atlanta ca. 1900-1940,
has historically contributed to water pollution in the Chattahoochee River. State
legislation adopted in 1990 required the elimination or control of the CSO system.
As of 1998, 7  of the  10 CSOs in Atlanta were associated with wastewater
treatment plants for solids removal and disinfection.  Two sites had been com-
pletely eliminated by separation of storm water and sewage collection systems,
and additional projects were planned to continue the separation of storm water
and sanitary sewage (e.g., Utoy Creek sewage separation project).
         125
                                            Figure 10-11
                                            Long-term trends of
                                            effluent BOD5 for the R.M.
                                            Clayton wastewater treat-
                                            ment plant. Data for calcu-
                                            lated BOD5 based on efflu-
                                            ent flow data, 200  mg/L
                                            influent BOD5, and removal
                                            rates of 35 percent
                                            (primary), 85 percent
                                            (secondary), and  95
                                            percent (tertiary).
                                            Sources: ARC, 1984;
                                            USEPA, 1971; USPHS,
                                            1963; Woodward, 1949,
                                            Richards,  1999.
                 Estimated Load
Load
-»• Concentration
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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment


                         Impact  of Wastewater Treatment:

                         Recreational and  Living Resources

                         Trends

                             Historical records offish population in the Chattahoochee River below
                         Atlanta are very limited. Conditions downstream of Atlanta's wastewater
                         discharge were unsuitable for fish survival during the 1970s, and no fish surveys
                         could be collected (Mauldin and McCollum, 1992). Shelton and Davies (1975)
                         conducted a preimpoundment survey of the area to be flooded by the West Point
                         Dam. The survey lasted from January 1972 to May 1974. The station closest to
                         Atlanta on the Chattahoochee was at Franklin, Georgia. During the early 1970s
                         study period, the Chattahoochee River was described as carrying a high organic
                         load from municipal wastes, a high suspended solids load from agricultural and
                         construction practices, and high chemical concentrations from industrial efflu-
                         ents. The relatively poor water quality in the Chattahoochee River affected the
                         distribution and  abundance of fish species sampled in the main stem versus the
                         tributaries.  Seventeen species of fish were collected in the Chattahoochee River
                         at Franklin, which is less than half the number of species expected for Georgia
                         rivers of similar  size.
                             A fish survey of the Chattahoochee River conducted between July 1990
                         and June 1992 revealed the return offish in great numbers to the portion of the
                         river below the city of Atlanta. The number of species collected ranged from 14
                         or 15 at the sites in the  direct vicinity of the wastewater treatment plant to  18 to
                         22 at the sampling sites located 63 and 23 km downstream, respectively. The
                         diverse species collected represented a considerable improvement from condi-
                         tions in the early 1970s, when only 17 species were sampled at Franklin, about
                         100 km downstream from the wastewater treatment plant, and no fish were
                         present downstream of Atlanta's water supply intake (Mauldin and McCollum,
                         1992).  The recent survey collected 12 gamefish species compared to 8 collected
                         by Shelton and Davies  (1975); the most abundant of game species by weight
                         were largemouth bass, bluegill, and channel catfish. Samples were analyzed
                         using the Index  of Biotic Integrity (IBI) (Karr, 1981; Karr et al., 1986). IBI
                         scores  for the four sampling sites  (located 1 km upstream of the discharge, 1 km
                         downstream of the discharge, 23 km downstream, and 63 km downstream)
                         ranged from 22  to 32, which is 37 percent to 53 percent of the maximum score
                         of 60. Scores in the 21 to 30 range indicated poor stream quality for fish and a
                         population dominated by omnivorous, pollutant-tolerant forms. The
                         Chattahoochee River below Atlanta's wastewater treatment plant  discharge had
                         a disproportionate segment of carp (75 percent), a higher proportion of bluegill to
                         redbreast sunfish than is common in Georgia streams, and fewer gamefish than
                         expected. A score of 32 measured 23 km downstream from the discharge
                         indicated fair stream quality for fish. Overall, the fish sampled appeared to be
                         healthy. Neoplasms were not observed in bluegill  specimens, nor were gross
                         external abnormalities observed in catfish.
                             The results of the 1990 to 1992 sampling show that water quality has
                         improved immensely since 1972 when the river below Atlanta was described as
                         "in near septic condition for a reach of 35 miles" (GADNR, 1991). The improve-
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                                                   Chapter 10: Upper Chattahoochee River Case Study
Table 10-3. Fish kills due to municipal waste discharges in the greater Atlanta region. Source: Mauldin and
McCollum, 1992.
Location
Chattahoochee River, Atlanta
Proctor Creek, Atlanta
Chattahoochee River, Atlanta
Nancy Creek, Chamblee
Marsh Creek, Sandy Springs
Little Nancy Creek, Atlanta
Date of
occurrence
8/13/64
7/18/76
7/29/76
7/24/81
9/3/81
9/28/84
Duration
1 day
1 day
12 hours
12 hours
1 day
Unknown
Severity
Moderate
Moderate
Moderate
Severe
Moderate
Moderate
Length of
Stream
Affected
(miles)
6
5
15
3
1
1
Game
Species
(%)
70
3
75
87
37
63
ment is due to enhanced wastewater treatment (Mauldin and McCollum, 1992).
Combined efforts of the state, communities, and industries and USEPA grants for
municipal wastewater treatment systems have put the Upper Chattahoochee
River on the road to recovery. Fish kills have not been commonplace since 1976,
except for one caused by an unidentified agent in 1988 (Mauldin and McCollum,
1992) (Table 10-3). Bloodworm-infested sludge beds no longer float in the
shallows below Atlanta, sportfish populations are recovering, there is more DO in
the water, macroinvertebrate fauna is more diverse, and fecal coliform bacteria
levels dropped 82 percent in only 4 years (USEPA,  1980). The number of water
quality violations has dropped dramatically since the 1970s even though standards
have increased. Water-based and contact recreation are now fully supported
along the Chattahoochee River reach from Buford Dam to  Peachtree  Creek.
Fishing is generally supported along the entire river (GADNR, 1991). As a result
of the investments to upgrade water pollution control facilities in the Atlanta
metropolitan region, the natural ecological balance of the river is beginning to be
restored.


Summary  and  Conclusions

     Results of legislation and regulations have been positive due to active
enforcement on all levels. Water quality monitoring by the EPD and under the
NPDES  program helps to evaluate progress and indicate violations. Water quality
in the Upper Chattahoochee River, particularly in the vicinity of Atlanta, has
improved dramatically with implementation of secondary waste treatment.
Chemical, physical, and biological data all indicate a great improvement in water
quality when compared to data from investigations done in the 1940s, 1950s,
1960s, and 1970s (Lawler, Matusky, and Skelly Engineers, 1989). Although total
loading of pollutants to the Chattahoochee River, such as BOD5, suspended solids,
and phosphorus, have been reduced significantly as a result of major capital
improvements to the wastewater and water pollution control infrastructure of the
Atlanta region during the 1970s and 1980s, the dramatic improvements in water
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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment


                          quality of the river tended to level out during the 1990s. Contemporary degrada-
                          tion of water quality is attributed to rapid urban development, the expanding area
                          of the outer suburbs of Atlanta, and nonpoint source loading from stormwater
                          runoff. The Georgia DNR listed more than 600 stream miles in the Atlanta area
                          as impaired in the 1994-1995 305(b) report, with less than 20 percent of the
                          degradation in stream miles attributed to point source pollution. As a result of
                          increased sediment loading from watershed runoff to the Chattahoochee River
                          and the reservoirs, water supply intakes are routinely shut down during and after
                          rainstorms. Contemporary water resource issues for Atlanta include the degrada-
                          tion of water  quality in rivers and streams, the adverse impact of storm water
                          runoff on public water supplies and recreational lakes, and probable limits on
                          future water supply allocations under the tristate river compacts that have
                          sparked "water wars" between Georgia, Alabama, and Florida (Kundell and
                          DeMeo,  1999). Despite the successes of past water pollution control efforts
                          during the 1970s and 1980s, the Atlanta region is now confronted with serious
                          water supply  and water quality issues that will affect the future economic viability
                          of the Atlanta metropolitan region. To achieve the solutions to contemporary
                          water quality problems required by state and federal agencies, regional coopera-
                          tion is needed for watershed management (Kundell and Demeo, 1999).


                          References

                          ARC.  1984. Status of water pollution control  in the Atlanta region. Atlanta
                              Regional Commission, Atlanta, GA.
                          ARC.  1998. Water resources of the Atlanta region. Atlanta Regional Commis-
                              sion, Atlanta, Georgia, January, .
                          Cherry,  R.N., R.E.  Faye, J.K. Stamer, and R.L. Kleckner. 1980. Summary of
                              the  river-quality assessment of the  Upper Chattahoochee River basin,
                              Georgia. U.S. Geological Survey, Reston, VA.
                          EPD.  1981. Statement for the public hearing  of the investigation and
                              oversight subcommittee of the  Public Works and Transportation  Com-
                              mittee of the  U.S. House of Representatives, May 18, 1981. Environmen-
                              tal Protection Division, Georgia Department of Natural Resources, Atlanta,
                              GA.
                          Faye, R.E., W.P. Carey, J.K. Stamer, and R.L. Kleckner.  1980.  Erosion,
                              sediment discharge, and channel morphology in the Upper
                              Chattahoochee River basin, Georgia. U.S.  Government  Printing Office,
                              Washington, DC.
                          Forstall, R.L. 1995.  Population by counties by decennial census: 1900 to
                              1990. U.S. Bureau of the Census,  Population Division, Washington, DC.
                              .
                          GADNR.  1991. Rules and regulations for water  quality control. Georgia
                              Department of Natural Resources, Georgia Environmental Protection
                              Division, Atlanta, GA.
                          Hammer, Siler, George Associates.  1975. Regional assessment study of the
                              Chattahoochee-Flint-Apalachicola Basin. National Commission on Water
                              Quality, Washington, DC. NTIS No. PB-252-318.
                          Iseri, K.T., and W.B.  Langbein.  1974. Large rivers of the United States. U.S.
10-14

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                                                    Chapter 10:  Upper Chattahoochee River Case Study
     Department of Interior, U.S. Geological Survey Circular No. 686, Washing-
     ton, DC.
Karr, J.R.  1981. Assessment of biotic integrity using fish communities. Fisheries
     6(6): 21-27.
Karr, J.R., K.D. Fausch, PL. Angermeier, P.R. Yant, and I.J. Schlosser.  1986.
     Assessing biological integrity in running waters: A method and its
     rationale. Special Publication 5. Illinois Natural History Survey, Champaign,
     IL.
Kundell, J.E., and T. DeMeo.  1999. Cooperative regional water management
     alternatives for metropolitan Atlanta: A report of the Regional Water
     and Sewer Study Commission. Prepared for the Atlanta Regional Commis-
     sion, Atlanta, Georgia, by the University of Georgia, The Carl Vinson Insti-
     tute of Government.
Lawler, Matusky, and Skelly  Engineers.  1989. Technical assistance for the
     development of a  defensible water quality  model of the Chattahoochee
     River. Georgia Department of Natural Resources, Environmental Protection
     Division, Atlanta, GA.
Lium, B.W., J.K. Stamer, T.A. Ehlke, R.E. Faye, and R.N. Cherry. 1979.
     Biological and microbiological assessment of the  Upper Chattahoochee
     River basin, Georgia. U.S. Geological Survey, Reston, VA.
Mauldin, A.C.,  and J.C. McCollum.  1992.  Status of the Chattahoochee River
    fish population downstream of Atlanta, Georgia.  Georgia Department of
     Natural Resources, Game and Fish Division, Atlanta, GA.
OMB.  1999. OMB Bulletin No. 99-04. Revised statistical definitions of Metro-
     politan Areas (MAs) and Guidance on uses of MA definitions. U.S. Census
     Bureau, Office of Management and Budget, Washington, DC. .
Richards, T.  1999.  R.M. Clayton wastewater treatment plant, Atlanta, GA,
     Personal communication. November 24, 1999.
Shelton, W.L., and W.D. Davies. 1975. Preimpoundment survey of fishes in the
     West Point Reservoir Area (Chattahoochee River, Alabama and  Georgia).
     Georgia Academy  of Science 33: 221-230.
Stamer, J.K., R.N. Cherry, R.E. Faye, and R.L. Kleckner.  1979.  Magnitudes,
     nature and effects of point and nonpoint discharges  in the
     Chattahoochee River basin, Atlanta to West Point Dam, Georgia. U.S.
     Government Printing Office, Washington, DC.
USDOC.  1998. Census  of population and housing. U.S.  Department of
     Commerce, Economics and Statistics Administration, Bureau of the Census -
     Population Division, Washington, DC.
USEPA.  1971. Inventory of municipal waste facilities, Region IV: Alabama,
     Florida, Georgia,  Kentucky, Mississippi, North Carolina,  South  Caro-
     lina and Tennessee. U.S. Environmental Protection Agency,  Washington,
     DC.
USEPA.  1980. National accomplishments in pollution control: 1970-1980,
     some case histories. U.S. Environmental Protection Agency, Office of
     Planning and Management, Program Evaluation Division, Washington, DC.
USEPA (STORET). STOrage  and RETrieval Water Quality Information  System.
     U.S. Environmental Protection Agency, Office of Wetlands, Oceans, and
     watersheds, Washington,  DC.
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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment


                         USGS.  1999.  Streamflow data downloaded from U.S. Geological Survey, United
                              States National Water Information System (NWTS)-W. Data retrieval for
                              historical streamflow daily values, .
                         USPHS.  1963.  Inventory  of municipal waste facilities, Region IV: Alabama,
                              Florida, Georgia, Kentucky, Mississippi,  South Carolina,  and Tennes-
                              see. U.S. Public Health Service, Washington, DC.
                         Woodward, R.L.  1949. Flow requirements for pollution abatement below
                              Atlanta, Georgia. U.S.  Public Health Service, Environmental Health Center,
                              Cincinnati, OH.
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    Chapter  11
Ohio  River
Case  Study
     The Ohio River Basin, covering a
drainage area of 204,000 square miles,
extends 1,306 miles from the headwaters of
the Alleghany River in Potter County,
Pennsylvania, to the confluence of the Ohio
River with the Mississippi River at Cairo,
Illinois. With a length of 981 miles from the
confluence of the Alleghany and Monangahela
rivers with the Ohio River at Pittsburgh, Pennsyl-
vania, to Cairo, Illinois, and a drainage area of
192,200 square miles, the Ohio River is the largest single
tributary to the Mississippi River. In the United States, the Ohio
River ranks 10th in length and 3rd in mean annual discharge (258,000
cfs) (Iseri and Langbein, 1974).
     Figure 11-1 highlights the location of the Ohio River case study
watersheds (catalog units) identified along the Ohio River as major
urban-industrial areas (e.g., Cincinnati, Ohio, and Louisville, Kentucky)
affected by severe water pollution problems during the 1950s and 1960s
(see Table 4-2). In this chapter, information is presented to characterize
long-term trends in population, municipal wastewater infrastructure and
effluent loading of pollutants, ambient water quality, environmental resources, and
uses of the Ohio River. Data sources include USEPA's national water quality
database (STORET), published technical literature, and unpublished technical
reports ("grey" literature) obtained from the Ohio River Valley Sanitation Com-
mission (ORSANCO) and other local agency sources.
     The ORSANCO district encompasses three-quarters of the basin, account-
ing for 155,000 square miles of the Ohio River watershed. The district contains
nearly one-tenth of the Nation's population in one-twentieth of the Nation's
continental area. Ten percent of the people in the watershed receive their water
supply from the Ohio River. Population densities in the ORSANCO district range
from less than 50 people per square mile in the southwest to more than 600 in the
Figure 11-1
Hydrologic Region 5 and
the Ohio River Basin.
                                                                                   11-1

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment


                          eastern urban centers. Land use in the area is primarily agricultural, but concen-
                          trations of industry, coal mining, and oil and gas drilling are present throughout the
                          region. In addition to agricultural and industrial uses, the Ohio River supports fish
                          and wildlife habitats, water-based recreation, navigation, and power generation.
                              Utility of the Ohio River had significantly declined by the 1930s as the result
                          of rising discharges of raw sewage and untreated industrial waste. Widespread
                          public concern was spurred by drought-induced epidemics in 1930 and continually
                          high levels of bacterial pollution. Citizens of the Ohio River Valley proposed a
                          regional  approach to water quality management in the form of an interstate
                          compact. Eight states joined the Ohio River Valley Sanitation Commission in 1948,
                          setting a precedent for cooperation among state, local, and private interests and
                          the federal government for unifying waste management within individual water-
                          sheds. The benefits of pollution control standards implemented through this
                          region-wide compact have been significant to the overall condition of waterways
                          in the Ohio River Basin.


                          Physical  Setting  and  Hydrology

                              Nineteen major tributaries discharge to the Ohio River (Figure 11-2). The
                          155,000-square-mile ORSANCO district originates on the western slopes of the
                          Appalachian Mountains, with the Allegheny River flowing into the Ohio River
                          from the northwest and the  Monangahela River from the south. The southwestern
                          portion of the district is characterized by rolling hills and wide valleys, and the
                          northwest is level or gently rolling. The elevation of the Ohio's riverbed drops 429
                          feet from the headwaters to the mouth at the confluence with the Mississippi
                                               87
Figure 11-2
Location of Upper, Middle,
and Lower Ohio River
watersheds. River miles
shown are distances from
confluence of Ohio River
with Mississippi River at
Cairo, Illinois.
                                                                                        81°
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                                                                     Chapter 11: Ohio River Case Study
River, with flow in the drainage basin generally toward the southwest. The
ORSANCO district is approximately 700 miles long and has an average width of
220 miles. Rainfall in the basin averages 45 inches, and the average annual
discharge of the Ohio River into the Mississippi River is 260,000 cfs. Variations in
rainfall, temperature, vegetation coverage, and snow storage have historically
caused wide ranges of runoff and streamflows. Low-flow conditions usually
occur in July through November; the monthly average, taken at Louisville, Ken-
tucky, ranges from 33,853 cfs in September to 239,613 cfs in March. Figures 11-3
and 11-4 show summer average flows (July-September)  and monthly average
flows over the 55-year period from 1940 to 1995.
     Canalization of the entire Ohio River and some of its tributaries was
achieved by 1929, converting the river into a series of backwater pools. The
original system of submergible wicket dams has been almost completely replaced
by high-lift permanent dams (Tennant, 1998).
           300
£ „ 200:
^Si w
   §
 1
CO
looiT'r:	
             ?9'4d	i&d	I'jjdd	VgVd	I'dsd"
6.5
6.0
5.5
5.0
4.5.o
4.0 £
3.5 |
S.Of
2.5 «
2.0 55
1.5
1.0
0.5
0.0
                                                                             Figure 11-3
                                                                             Long-term trends in mean,
                                                                             10th, and 90th percentile
                                                                             statistics computed for
                                                                             summer (July-September)
                                                                             streamflow in the Ohio
                                                                             River. (USGSGage
                                                                             03294500 at Louisville,
                                                                             Kentucky.)
                                                                             Source: USGS, 1999.
                 --• 90%ile
                                          mean & ratio
           500
S  c    •
H
$  f  200!
55       ;
                                                                             Figure 11-4
                                                                             Monthly trends in
                                                                             streamflow for the Ohio
                                                                             River. Monthly mean, 10th,
                                                                             and 90th percentiles
                                                                             computed for 1951-1980.
                                                                             (USGS Gage 03294500 at
                                                                             Louisville, Kentucky.)
                                                                             Source: USGS, 1999.
                    ONDJFMAMJJAS
                                                                                               11 -3

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
                         Population,  Water,  and  Land  Use Trends

                              The Ohio River Basin continues to be one of the most important agricultural
                         and industrial centers of the Nation. Population in the ORSANCO district has
                         increased steadily over the past few decades, and use of the water resources has
                         increased with the development of the basin. More than 3,700 municipalities, more
                         than 1,800 industries, and three major cities—Louisville, Cincinnati, and Pitts-
                         burgh—depend on the Ohio River Valley. The Ohio River case study area
                         includes a number of counties identified by the Office of Management and
                         Budget (OMB) as Metropolitan Statistical Areas (MSAs) or Primary Metropoli-
                         tan Statistical Areas (PMSAs). Table 11-1 lists the MSAs and counties included
                         in this case study. Figure 11-5 presents long-term population trends (1940-1996)
                         for the counties listed in Table 11-1. From 1940 to 1996, the population in the Ohio
  Table 11-1.  Metropolitan Statistical Area (MSA) counties in the Ohio River Basin case study. Source: OMB, 1999.
  Wheeling, WV-OH MSA
    Belmont County, OH
    Marshall County, WV
    Ohio, WV
  Steubenville-Weirton,  OH-WV MSA
    Jefferson County, OH
    Brooke County, WV
  Huntington-Asland, WV-KY-OH
  MSA
    Boyd County, KY
    Carter County, KY
    Greenup County, KY
    Lawrence  County, OH
    Cabell County, WV
    Hancock County, WV
    Wayne County, WV
Cincinnati-Hamilton, OH-KY-IN
CMSA
  Dearborn County, IN
  Ohio County, IN
  Boone County, KY
  Campbell County, KY
  Kenton County, KY
  Pendleton County, KY
  Brown County, OH
  Clermont County, OH
  Hamilton County, OH
  Warren County, OH
  Butler County, OH
Louisville, KY-IN MSA
  Clark County,  IN
  Floyd County,  IN
  Harrison County, IN
  Scott County, IN
  Bullitt County,  KY
  Jefferson County, KY
  Oldham County, KY
Evansville-Henderson, IN-KY MSA
  Posey County, IN
  Vanderburgh County, IN
  Warrick County, IN
  Henderson County, KY
Figure 11-5
Long-term trends in
population in the Ohio
River Basin.
Sources: Forstall, 1995;
USDOC, 1998
                                            1940   1950   1960   1970   1980   1990  1996
11 -4

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                                                                   Chapter 11: Ohio River Case Study
River case study area increased by more than 50 percent (Forstall, 1995;
USDOC, 1998). Agriculture continues to be the dominant land use in the area
although extensive mining is conducted in the watershed; 70 to 80 percent of
the national total amount of bituminous coal and a significant amount of natural
gas and oil are present in the basin.
     The Ohio River supports navigation, power generation, industrial cooling and
processing, warm-water aquatic habitats, public water supplies, and recreation.
Because the river serves as a water source to industries, agricultural lands, and
more than 3.5 million people, and as a waste receptacle for far larger numbers,
the river's environment has been placed in a fragile balance.


Historical Water Quality  Issues

     Growing concern for the deteriorating environmental conditions in the Ohio
River peaked in the early 1930s when serious drought turned many slackwater
pools into virtual cesspools and a series of epidemics plagued cities along the Ohio
River. Costs of water treatment increased dramatically from 1921 to 1934 as a
result of an estimated 80-fold increase in the bacteria levels present in the river.
In 1936 Congressman Brent Spence testified at a congressional hearing on the
pollution of navigable waters that "the Ohio River is a cesspool." At the same
hearing the  State Health Commissioner of Kentucky added that "the Ohio River,
from Pittsburgh to Cairo, is an open sewer." In 1939 the city of Marietta, Ohio,
was  forced to change its water supply source from the Ohio River to wells and
the Muskingum River as pollution levels in the river became untreatable. In 1951
only 39 percent of the sewered population was served by community treatment
facilities. Sections of the Ohio River still suffered oxygen depletion so severe that
aquatic life could not survive and pollution, bacteria levels, taste, and odor made
large sections of the Ohio River unsuitable for most uses.


Legislative  and Regulatory History

     Large-scale action was delayed by the need for cooperation throughout the
basin to achieve significant improvements in water quality. In 1908 the Ohio state
legislature adopted the Bense Act which, exempted every Ohio village and
municipality from installing sewage treatment works until similar facilities were
provided by all municipalities upstream from it. This attitude endured until 1924
when the Ohio River Valley Negotiating Committee reported an agreement
between industries and state health commissioners to cooperate in carrying out a
policy for the conservation of interstate  streams. Congress authorized the states
to negotiate the compact in 1936 and approved the resulting document in  1940. In
June of 1948 the Federal Water Pollution Control Act (Public Law 80-845) was
passed and the ORSANCO Compact was signed by Illinois, Indiana, Kentucky,
New York, Ohio, Pennsylvania, Virginia, and West Virginia, setting a precedent
for cooperation among federal agencies,  state governments, municipalities, and
industries. Soon after, wastewater treatment standards were enacted for the
Cincinnati pool. Bacterial quality objectives for the Ohio River were established in
1951, and an assessment of potential health hazards from trace constituents in
wastewaters was initiated. By 1954 municipal wastewater treatment standards
                                                                                            11-5

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment


                          for the Ohio River had been established. In relation to the industrial dischargers, a
                          resolution adopted in 1959 placed responsibility on industries for reporting spills
                          and accidental discharges to state agencies.
                               Following the 1965 Federal Water Quality Act, ORSANCO adopted stream
                          water quality recommendations. In 1970 ORSANCO Pollution Control Standard
                          1-70 revised the pollution control standards established in 1954, making secondary
                          treatment the  minimum requirement for wastewater treatment plants and estab-
                          lishing equivalent treatment requirements for industry. From 1957 to 1965,
                          $82,786,500 in federal aid was allocated to 638 projects in the Ohio Valley. The
                          communities matched every federal dollar with $2.50 of local funds for a total of
                          $282,966,000 spent on improving conditions. The majority of treatment works,
                          both in place and under construction during this time, were equipped for second-
                          ary treatment. For 3 years before federal aid was offered, Pennsylvania provided
                          incentives for smaller communities to upgrade their treatment by offering funds to
                          communities upon compliance with standards. Although the population served by
                          municipal facilities has increased greatly under these programs (Figure 11-6),
                          increasingly high water quality criteria and limited funds have caused a sharp
                          increase in population served by facilities classified as inadequate between 19.65
                          and 1990.
Figure 11-6
Long-term  trends in
population  served by
municipal wastewater
treatment plants in  the
ORSANCO District.
Sources: ORSANCO,
1978, 1988.
                               8-
                                       1950
 1960
1970
1980
1990
                                          Raw
|   | Pri+AdvPri $%% Sec
                 Advanced
11-6

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                                                               Chapter 11:  Ohio River Case Study
Impact of Wastewater Treatment:

Pollutant  Loading and Water

Quality  Trends

     Following the 1948 advances in cooperative management, water quality
conditions in the Ohio River began to improve. A dramatic decrease occurred in
the discharge of raw sewage from 1950 to 1963 (Figure 11-6). As a result of the
stringent permit requirements on dischargers and improvements in wastewater
treatment facilities implemented in the late 1960s and 1970s, even more advances
have been made to upgrade wastewater treatment plants.  Levels of BOD5
effluent loading have decreased significantly, even as the influent loading contin-
ues to increase as population increases (Figure 11 -7). Corresponding to the
decreasing levels of pollutant loading is the increased amount of DO available to
support aquatic organisms. Figure 11-8 shows the typical oxygen sag curve
                                                       3000
                                                            LU
            1950
1960
1970
1980
1990
                         Flow
                I Effluent BODS
Figure 11-7
Long-term trends of
wastewater flow, influent
and effluent BOD5 for the
ORSANCO District. Data
based on population
served with 165 gallons
per person per day, influent
BOD6 of 215 mg/L, and
removal efficiencies of 36
percent (primary), 85
percent (secondary), and
95 percent (tertiary).
Sources: ORSANCO, 1978,
1987.
                    Cincinna OH  (River Mile 46 )-470)
          0
          450     460     470    480     490     500     510     520
                      •^—  River Miles from Cairo IL
                                                 Figure 11-8
                                                 Spatial distribution of DO
                                                 along the Ohio River
                                                 downstream of Cincinnati:
                                                 Oct.-Nov. 1963.
                                                 Source:  HydroScience,
                                                 1969.
                                                                                       11-7

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment


                          observed during the mid-1960s downstream from Cincinnati, Ohio, and indicates
                          the sampling locations shown in Figures 11-9, 11-10, and 11-11. These data clearly
                          illustrate an overall increase in oxygen following the 1972 CWA requirement for
                          secondary treatment. A remarkable improvement in oxygen concentration occurs
                          in the critical minimum occurring near North Bend/Fort Miami (milepoint 490) and
                          at the pool formed by Markland Lock/Dam (milepoint 449-453). During the 1988
                          drought, for example, levels of DO continued to meet standards near Cincinnati
                          and Louisville in contrast to the mid-1960s when consistent low-flow conditions
                          resulted in DO concentrations below water quality standards (see Figures 11-9
                          and 11-13). Using the data compiled for trends in DO near Cincinnati (Figure 11-
                          9) and Louisville (Figure 11-12), the mean summer 10th percentile level of DO
                          significantly improved after the CWA (1986-1995) in comparison to conditions
                          before the CWA (1961-1970) (Figure 11-13).
                              Water quality data collected since the 1950s indicate increased compliance
                          with federal and ORSANCO criteria for DO, BOD5, turbidity, pH, and many
                          other water quality factors (Cleary, 1978; Wolman,  1971). ORSANCO (1979)
Figure 11-9
Long-term trends of DO
near Cincinnati, Ohio
(miles 460-470) (RF1-
05090203002).
Source: USEPA (STORET).
                                     10
8-
6-
                                      4-
                                      2-
                                      ?940      1950      1960       1970       1980
                                                      Cincinnati OH [River Mile 460-470]
                                                 1990
                                                        Mean	Min  	Max
Figure 11-10
Long-term trends of DO at
North Bend/Ft. Miami, Ohio
(RF1-05090203012) (mile
490).
Source: USEPA (STORET).
                                                                                       1990
                                                     N.Bend/Ft.Miami OH [River Mile 490]
-A- Mean 	
Min
11-8

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                                                                 Chapter 11: Ohio River Case Study
   10!
|  8+-


§  6- -
1
a   2-
       )
                     Markland Pool [River Mile 449-453]
-A- Mean 	
Min
                                                             1990
                                                                          Figure 11-11
                                                                          Long-term trends of DO at
                                                                          Markland Lock & Dam,
                                                                          Kentucky (miles 449-453)
                                                                          (RF1-05140101010).
                                                                          Source: USEPA  (STORET).
   1940
             1950
   1960       1970
Louisville KY [River Mile 364-388]
1990
                                                                          Figure 11-12
                                                                          Long-term trends of DO at
                                                                          Louisville, Kentucky (miles
                                                                          364-388) (RF1-0514010
                                                                          1001).
                                                                          Source: USEPA (STORET).
                      Mean	Mm  	Max
       Louisville [RF1 05140101001]
       Cincinnati [RF1 05090203002]
                                                                          Figure 11-13
                                                                          Before and after
                                                                          comparison of summer
                                                                          mean  10th percentile DO
                                                                          near Louisville, Kentucky
                                                                          (miles 364-368) and
                                                                          Cincinnati, Ohio (miles
                                                                          460-470) during 1961-70
                                                                          and 1986-95.
                                                                          Source: USEPA (STORET).
                  1961-70
                                          1986-95
                      Louisville |    j Cincinnati
                                                                                             11 -9

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
Figure 11-14
Long-term  trends in fish
diversity in the Ohio River.
Source: ORSANCO, 1982.
                                2.00-
                              .1
                              Q





65' ' ' ' 19
• • . —

n
o
. D .
5
70' ' ' '1C
	
k
J

(75 ' ' ' '19
• • —
•- ^


80' ' ' '19




85
                                            Lower River A Middle River n  Upper River
                        reports greater than 98.8 percent compliance for 15 out of 20 examined stream
                        quality criteria. In 1990 ORSANCO published a statistical analysis of data
                        resulting from water quality monitoring conducted over an 11-year period. De-
                        creasing trends at individual sampling points were reported for a majority of the
                        contaminants examined, and overall improving trends are indicated for total
                        phosphorus, ammonia, nitrogen, copper, lead, and zinc. An indication of the
                        improving water quality in the Ohio River is the marked increase in diversity of
                        fish species with the greatest  improvement seen in the upper reaches of the river
                        (Figure 11-14). Increases are primarily noted in sport and commercially valuable
                        species, which tend to be more pollution-sensitive than other fish species.


                        Impact of  Wastewater  Treatment:

                        Recreational and  Living  Resources

                        Trends

                             There is little long-term information on biological trends in the Ohio River
                        (Pearson, 1992). Information  on plants, invertebrates, and plankton is scarce or
                        nonexistent. The only historical population data are for mussels, which were
                        diverse and abundant in the 1800s but are less so now, even with water quality
                        improvements in the river.
                             Data on fish populations in the middle section of the Ohio River have been
                        collected since the 1950s and indicate that the populations have responded more
                        positively than mussels to improved water quality (Figure 11-15). The first com-
                        prehensive fish population study on the Ohio River was done by ORSANCO in
                        1957, and the study has continued almost yearly since then. The study reports fish
                        data according to section of the river—upper, middle, and lower. Louisville and
                        Cincinnati are located in the middle section of the river. Changes in fish diversity
                        since the study began have been most dramatic in the upper river, where a 40
11 -10

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                                                                     Chapter 11: Ohio River Case Study
                    1957-60
1967-70
1974-80
1981-85
                              I Cincinnati Bl Louisville
                                                                             Figure 11-15
                                                                             Long-term trends in Ohio
                                                                             River fish abundance at
                                                                             Cincinnati and Louisville.
                                                                             Source: Pearson, 1992.
percent increase has been measured, but diversity has increased by 13 percent in
the middle section as well (ORSANCO, 1982). Numbers of species and overall
fish biomass are still increasing in the middle section of the river though they have
not returned to their original levels. ORSANCO attributes the improvements to
increased DO concentrations and pH, and to decreased levels of toxic materials
in the river (ORSANCO, 1982).
     Other studies also indicate continuing improvements in the quality of the
Ohio River habitat. Studies by Geo-Marine conducted in the early 1980s near
North Bend, Ohio (about 30 miles downstream of Cincinnati) found increasing
numbers of species of larval fish, a life stage generally sensitive to DO levels
(Geo-Marine, 1986).  A trend toward a more even distribution of the numbers of
individuals among the species captured was found as well, indicating improved
habitat quality. The Ohio EPA has also conducted fish studies along the river.
Their studies have found an Index  of Biotic Integrity  (IBI) near North Bend
between 46 and 48 (OEPA, 1992).  This is a fair to good rating, indicating habitats
where tolerant and intolerant benthic species are both found. Benthos are particu-
larly good indicators  of long-term trends in water quality because the species are
generally sedentary and have long life spans. For pollution studies, benthos are
divided into three categories, and intolerant species are indicative of good water
quality because of their inability to survive in, or intolerance of, low DO concen-
trations. Ohio EPA's sampling at North Bend in 1991  found a total of 23 species,
with one intolerant species among them (Sanders, 1992a, 1992b; Plafkin et al.,
1989).
     Water quality improvements in the Ohio River have benefited both commer-
cial and sport fisheries (Figure 11-15). Sportfishing, important recreationally and
for tourism, began returning to the  river in the mid-1980s. In 1982 the Bass
Anglers Sportsman's Society held the Bass Champs Invitational at Cincinnati
because of the reported bass  catch in the river (ORSANCO, 1981). Such con-
tests are now commonly held along the river.
                                                                                              11-11

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment


                         Summary and  Conclusions

                              Significant improvements have been accomplished throughout the Ohio
                         River Basin through the combined efforts of federal, state, and local governments.
                         The last half century has seen a reversal of the previous trend of river degrada-
                         tion. As of the mid-1990s nearly 94 percent of the Ohio River Basin's sewered
                         population was served by at least secondary treatment. This accomplishment, on
                         such a large scale, has shown what regional cooperation can achieve. The Ohio
                         River now supports many uses that had previously been seriously impaired.
                         Support of use for public water supply and aquatic habitat is maintained along the
                         entire river. Sportfishing has returned, and the dramatic improvement in water
                         quality is reflected in the increasing number of fishing tournaments along the river,
                         including the 1983 Bass Masters Classic at Cincinnati.
                              Much progress has been made,  but there is a recognizable need for further
                         action. Water-based recreation continues to be impaired by high bacteria levels in
                         the river. As of 1988 contact recreation was not supported on 59 percent of the
                         river and was fully supported on only 6.5 percent of the river.  Fish consumption
                         advisories were still in effect for Kentucky, Ohio, Pennsylvania, and West Virginia
                         in 1989 due to high levels of PCBs and chlordane found in fish tissues
                         (ORSANCO 1989a). Certain metals,  organic compounds, cyanide, phenol, copper,
                         zinc, oxygen, and temperature also continue to pose a problem. ORSANCO is
                         considering to address these and other stream quality impairments by addressing
                         nonpoint source pollution controls (Norman, 1991), combined sewer overflow
                         controls (Tennant et al., 1990), control of toxic chemicals (Vicory and Tennant,
                         1994), and control of ecological effects of hydropower development. Continued
                         improvements are seen in monitoring, detection, and regulation, as well  as treat-
                         ment and spill response (Vicory and Tennant, 1993). The combination of present
                         efforts with past achievements has put the Ohio River Basin on the road to
                         recovery.


                         References

                         Cleary, E.J. 1978. Perspective on river quality diagnosis. J. WPCF 50(5): 825-
                              832.
                         Forstall, R.L.  1995.  Population by counties by  decennial census: 1900 to
                              1990. U.S. Bureau of the Census, Population Division, Washington, DC.
                              http://< www.census.gov/population/www/censusdata/cencounts.html>.
                         Geo-Marine.  1986.  1985 Ohio River Ecological Research Program. Adult
                              and Juvenile Fish  and Ichthyoplankton Studies. December. Prepared for
                              Ohio Edison Company, Ohio Valley Electric Corporation.
                         HydroScience.  1969.  Water quality analysis for the Markland Pool of the
                              Ohio  River. Technical report prepared for Malcolm Pirnie Engineers,
                              Westwood, NJ.
                         Iseri, K.T., and W.B. Langbein.  1974.  Large rivers of the  United States.
                              Circular No. 686. U.S. Department of the Interior, U.S. Geological Survey,
                              Washington, DC.
                         Norman, C.G.  1991.  Urban runoff effects on Ohio River water quality. Water
                              Environ. Tech. 3(6): 44-46.
 11-12

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                                                                   Chapter 11:  Ohio River Case Study
OEPA.  1992.  Ohio Environmental Protection Agency Water Quality Plan-
     ning and Assessment Fish Information System (FINS): Fish survey data.
     Ohio Environmental Protection Agency.
OMB. 1999.  OMB Bulletin No. 99-04. Revised statistical definitions of Metro-
     politan Areas (MAs) and Guidance on uses of MA definitions. U.S. Census
     Bureau, Office of Management and Budget, Washington, DC. .
ORSANCO.  1978.  ORSANCO in review. Ohio River Valley Sanitation Com-
     mission, Cincinnati, OH.
ORSANCO.  1979.  ORSANCO in review. Ohio River Valley Sanitation Com-
     mission, Cincinnati, OH.
ORSANCO.  1981. Annual report. Ohio River Valley Sanitation Commission,
     Cincinnati, OH.
ORSANCO.  1982. Annual report. Ohio River Valley Sanitation Commission,
     Cincinnati, OH.
ORSANCO.  1985. Annual report. Ohio River Valley Sanitation Commission,
     Cincinnati, OH.
ORSANCO.  1986. Annual report. Ohio River Valley Sanitation Commission,
     Cincinnati, OH.
ORSANCO.  1987. 7957 status of wastewater facilities. Ohio River Valley
     Sanitation Commission, Cincinnati, OH.
ORSANCO.  1988. ORSANCO: Forty years of service. Ohio River Valley
     Sanitation Commission, Cincinnati, OH.
ORSANCO.  1989a.  Water quality of the Ohio River, Biennial assessment:
     1988-1989. Ohio River Valley Sanitation Commission, Cincinnati, OH.
ORSANCO.  1989b. Annual report. Ohio River Valley Sanitation Commission,
     Cincinnati, OH.
ORSANCO.  1990.  Water quality trends, Ohio River and its  tributaries.
     Statistical analyses of data resulting from water quality  monitoring
     conducted by ORSANCO. Ohio River Valley Sanitation Commission,
     Cincinnati, OH.
Pearson, W.D. 1992.  Historical changes in water quality and fishes of the Ohio
     River. In Water quality in North American river systems,  ed. C.D. Becker
     and D.A. Neitzel, pp. 207-231. Batelle Press, Columbus, OH.
Plafkin, J.L., M.T. Barbour, K.D. Porter, S.K. Gross, and R.M. Hughes. 1989.
     Rapid bioassessment protocols for use in streams  and rivers. Benthic
     macroinvertebrates and fish. Results of pilot studies in Ohio and Or-
     egon. EPA 444/4-89/001. U.S. Environmental Protection Agency, Office of
     Water, Assessment and Watershed Protection Division. Washington, DC.
Sanders, R.E.  1992a. Day versus night electrofishing catches from near-shore
     waters of the Ohio and Muskingum Rivers. Ohio J. of Science 92(3): 51-59.
Sanders, R.E.  1992b. Ohio's near-shore fishes of the Ohio River:  1991-
     2000. (Year One: 1991  results). Prepared for the Ohio Department of
     Natural Resources, Division of Wildlife, Ohio Nongame & Endangered
     Wildlife Program. Columbus, OH.
Tennant, Peter. 1998. Ohio River Valley Sanitation Commission. Personal
     communication, August 21,1998.
Tennant, P., C. Norman, and P. McConocha.  1990.  Toxic-substance control for
     the Ohio  River. Water Environ. Tech. 2(10): 59-63.
                                                                                           11 -13

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment


                         USDOC.  1998.  Census  of population and housing. Prepared by U.S. Depart-
                             ment of Commerce, Economics and Statistics Administration, Bureau of the
                             Census - Population Division, Washington, DC.
                         USEPA (STORET). STOrage and RETrieval Water Quality Information System.
                             U.S. Environmental Protection Agency, Office of Wetlands, Oceans, and
                             watersheds, Washington, DC.
                         USGS. 1999. Streamflow data downloaded from the U.S. Geological Survey's
                             National Water Information System (NWIS)-W. Data retrieval for historical
                             Streamflow daily values, .
                         Vicory, A.H., Jr., and P.A.  Tennant.  1993. The Ohio River Valley Water Sanita-
                             tion Commission and its activities. Ohio J. of Science 93(2): 11.
                         Vicory, A.H., Jr., and P.A.  Tennant.  1994. A strategy for monitoring the impacts
                             of combined sewer overflows on the Ohio River. Water Quality Interna-
                             tional '94.  Part 1:  Combined Sewer Overflows and  Urban Storm Drain-
                             age. Biennial Conference of the International Association on Water Quality,
                             July 24-30,1994, Budapest, Hungary.
                         Wolman, M.G. 1971. The Nation's rivers. Science (174): 905-915.
11 -14

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    Chapter  12
 Upper
 Mississippi
 River  Case
 Study
    The upper and lower watersheds of the Mississippi
River extend 2,340 miles from the headwaters in Lake Itasca,
Minnesota, to the Gulf of Mexico. With a drainage basin of 1.15
million square miles, the Mississippi River, known as the "Father of
Waters," drains 40 percent of the continental United States and
discharges an annual average flow of 640,000 cfs into the Gulf of
Mexico. On the basis of drainage area and mean annual discharge, the
Mississippi is the largest river in the United States (Iseri and Langbein,
1974) and is ranked by annual discharge as the sixth largest river in the
world (Berner and Berner, 1996). Figure 12-1 highlights the location of
the seven catalog units of Accounting Unit 070102 for the Upper
Mississippi River case study in the vicinity of Minneapolis-St. Paul in
Minnesota. The Twin Cities are one of the Nation's many major urban
areas characterized by water pollution problems during the 1950s and
1960s (FWPCA, 1966; USPHS, 1951; 1953). Federal enforcement
conferences were convened in 1964 and 1967 to investigate water
pollution problems in the Minnesota and Wisconsin sections of the
Upper Mississippi River (Zwick and Benstock, 1971).
    In this chapter, data and information are presented to characterize
long-term trends in population, municipal wastewater infrastructure and effluent
loading of pollutants, ambient water quality conditions, environmental resources,
and uses of the Upper Mississippi River in the vicinity of the Twin Cities. Data
sources included STORET, EPA's national water quality database, USGS
streamflow records (USGS, 1999a), published literature, unpublished data, news-
letters, and technical reports obtained from the Metropolitan Council Environmen-
tal Services (MCES) in St. Paul and from other state, local, and federal agencies.
Data have also been obtained from a validated water quality model of the Upper
Mississippi River (Lung and Larson, 1995) to identify the progressive improve-
ments in dissolved oxygen and other water quality parameters attributed to
upgrades of the Metropolitan Wastewater Treatment Plant in St. Paul from
primary to secondary and advanced secondary with nitrification (Lung, 1998).
Figure 12-1
Hydrologic Region 7 and
the Upper Mississippi
River basin near
Minneapolis-St. Paul,
Minnesota.
                                                                                12-1

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
                              The Twin Cities of Minneapolis and St. Paul are the major urban centers for
                         more than 1,100 miles along the Mississippi River upstream of St. Louis, Missouri.
                         About one-third of the population and a majority of the commercial and industrial
                         activity of Minnesota are located within the Twin Cities metropolitan region.
                         Outside the Twin Cities, the Upper Mississippi watershed is primarily rural and
                         forested with the population dispersed in small towns and farms. The glaciated
                         topography of the watershed provides extensive habitat for fish and wildlife and
                         also supports an economy historically based on agriculture and wood products. In
                         addition to these economic sectors, industrial and manufacturing activities have
                         become significant components of the overall economy.


                         Physical  Setting  and  Hydrology

                              The Upper Mississippi River basin (Hydrologic Region 7) covers a drainage
                         area of 171,500 square miles over a reach of 1,170 miles from the headwaters in
                         Lake Itasca to the confluence of the Missouri River with the Mississippi River at
                         Alton, Illinois, just upstream of St. Louis, Missouri (Iseri and Langbein, 1974)
                         (Figure 12-1). The water quality of the Upper Mississippi River has historically
                         been dominated by wastewater loading from the Twin Cities,  as well as sedi-
                         ments, nutrients, pesticides, oxidizeable materials, and other pollutants from the
                         Minnesota River basin, the watershed of the Upper Mississippi River basin
                         (Catalog Unit 07010206) described in this case study includes a drainage area of
                         8,520 square miles extending 83 miles from the confluence of the Crow River
                         (UM milepoint 894) in Morrison County upstream of Anoka, Minnesota (Upper
                         Mississippi milepoint 871) to the confluence of the St. Croix River downstream of
                         Lock and Dam No. 2 at Prescott, Wisconsin (UM milepoint 811) (Figure 12-2).
                              96'
Figure 12-2
Location map of Upper
Mississippi River
(Accounting Unit 070102)
near Minneapolis-St. Paul,
Minnesota. River miles
shown are distances from
confluence of Mississippi
River with Ohio River at
Cairo, Illinois.
                           45
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                                                        Chapter 12:  Upper Mississippi River Case Study
     Characterized by rolling hills and plains with numerous lakes, the basin
topography reflects the effects of successive glacial advances over the region.
Upstream of the Twin Cities, the major tributaries to the Upper Mississippi are the
Minnesota River, the Rum River at Anoka, and the Crow River. Within the portion
of the watershed influenced by wastewater loading from the Twin Cities, five
locks and dams have been constructed for flood control, navigation, and hydro-
power purposes. Because of the flow-regulating nature of the series of locks and
dams, the river essentially flows as a series of controlled backwater pools with
relatively constant surface elevations. Over the 69-mile reach from Coon Rapids
Dam upstream of Minneapolis (UM river mile 866) to Lock and Dam No. 3 at
Red Wing, Minnesota (UM river mile 797), the river drops from an elevation of
830 feet to 661 feet above mean sea level (Hydroscience,  1979).
     The series of locks and dams, supplemented by dredging, maintain a 9-foot-
deep navigation channel for commercial barge traffic. The navigation channel
was authorized by the U.S. Congress in 1928, and the locks and dams were
authorized in 1930. The U.S. Army Corps of Engineers is conducting a controver-
sial environmental study is assessing the impact of the lock and dam system on
the  ecological integrity of the Upper Mississippi River. In addition to the ecological
effects of the  flow control structures, the Great Flood of 1993 (Wahl et al., 1993)
has generated investigations of the role that artificial drainage and flood-control
structures might have played in actually increasing the extent of severe flooding in
some areas of the watershed.
     On  a seasonal basis, streamflow of the Upper Mississippi River reflects
peak precipitation during late spring snowmelt and early summer with severe
subfreezing winter conditions (Figure 12-3). Although the minimum flow occurs
during winter due to a reduction in watershed runoff as precipitation changes
from rain to snow and ice, the critical period for water quality problems is during
the  low-flow, summer months. On the river itself, winter ice cover is intermittent,
varying considerably both spatially and temporally. Ponded areas of the Upper
Mississippi River, such as Lower Pool 2 and Lake Pepin (Pool 4), have perma-
nent ice cover for about 3 months during the winter; the more riverine reaches
freeze over only during extended periods  of severe cold. DO levels are generally
                                                                             Figure 12-3
                                                                             Monthly mean, 10th, and
                                                                             90th percentile streamflow
                                                                             (1951-1980) at St. Paul,
                                                                             Minnesota, USGS Gage
                                                                             05331000.
                                                                             Source: USGS, 1999a.
                 O  N  D  J   FMAMJJAS
                                                                                              12-3

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment


                         high during winter because of very low water temperature and open water
                         conditions that allow oxygen exchange across the air-water interface. Reliable
                         streamflow records from a USGS gage 300 feet upstream of the Roberts Street
                         Bridge in St. Paul (UM milepoint 839.3) are available from 1892 to the present to
                         characterize long-term monthly, annual, and extreme flow statistics over a drain-
                         age area of 36,800 square miles (USGS, 1999a). Based on the historical data
                         recorded for water years 1892-1998, monthly flow ranges from a maximum of
                         26,060 cfs in April to a winter minimum of 4,544 cfs during February and a
                         summer low of 8,060 cfs during  September. Over the period of record from 1892
                         to 1998, annual average discharge of the Upper Mississippi River at St. Paul has
                       •  been 11,630 cfs, with the lowest  daily mean flow of 632 cfs recorded on August
                         26, 1934, and the highest daily mean flow of 171,000 cfs observed on April 16,
                          1965 (USGS, 1999a). Using historical records from  1936-1979 to represent
                         streamflow variability after the series of locks and dams were constructed on the
                         Upper Mississippi River, the 7-day, 10-year flow (7Q10) for summer conditions
                         (June-September) at St. Paul is reported as  1,633 cfs (MPCA, 1981).
                              The long-term (1940-1995) interannual variation of mean, 10th, and 90th
                         percentile summer (July-September)  streamflow is shown in Figure 12-4. The
                         historical record exhibits pronounced year-to-year variability of summer
                         streamflow. Based on data from  1951-1980, the long-term mean summer
                         (July-September) flow of 10,659 cfs is used to compute a normalized streamflow
                         ratio for each summer from 1940 to 1995 as dry (< 0.75), normal (0.75-1.50) or
                         wet(> 1.50). For example, the summers of 1962,1972,1978-79, 1983, 1985-86,
                          1991, and 1993-95 were all characterized by wet conditions, where the flow was
                         greater than 150  percent of the long-term summer mean. The summers of
                          1960-61,1964,1967,1870-71,1973-74,1976-77,1980, and 1987-89, in contrast,
                          were characterized by dry conditions, where the flow was less than 75 percent of
                         the long-term summer mean. The extreme droughts of 1976 (1,725 cfs, 16
                          percent of summer mean) and 1988 (2,334 cfs, 22 percent of summer mean) and
                          the Great Flood of 1993 (47,789 cfs, 450 percent of summer mean) are particu-
                          larly noticeable in the  55 years of historical records  for the Upper Mississippi
                          River at St. Paul.
Figure 12-4
Long-term trends of
summer (July-
September) mean,  10th,
and 90th percentile
streamflow at St. Paul,
Minnesota, USGS Gage
05331000.
01	111	ni	
1940    1950    1960    1970
1980
                                                                             1990
                                                                                       0.0
2000
                                         	90%ile
                                                                        mean & ratio
 12-4

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                                                       Chapter 12:  Upper Mississippi River Case Study
Population,  Water,  and  Land  Use Trends

     Beginning in 1838 when the Twin Cities area was first opened for settle-
ment, the abundant land and water resources attracted homesteaders. The
confluence of the Minnesota River and the Upper Mississippi River served as an
important transportation link between military and trading posts and the growing
towns and cities along the Mississippi River. St. Anthony's Falls provided a natural
source of power for lumber and grist mills. The fertile soil supported an agricul-
tural economy, and the vast forests provided resources for a growing wood
products industry. Uses for the Upper Mississippi River have included municipal
and industrial water supply, commercial navigation, log transport, commercial
fishing, hydropower, and water-based recreational activities. Beginning with the
construction of an urban sewer system in 1871, the Upper Mississippi River has
also been used for wastewater disposal.
     As a component of the Lake Pepin Phosphorus Study, conducted from 1994
to 1998, historical records of land uses, agricultural practices (e.g., manure
applications  and commercial fertilizer uses), and wastewater discharges, compiled
beginning ca. 1860, were used to correlate long-term changes in land uses in the
watersheds of the Upper Mississippi River, the Minnesota River, and the St.  Croix
River with long-term changes in sediment and phosphorus loading to Lake Pepin
(Mulla et al., 1999). As of the mid-1990s, the USGS (1999b) had classified about
60 percent of the watershed (Upper Mississippi River, Minnesota River, and St.
Croix River) as agriculture and 23 as forest. The remaining 17 percent of the
drainage basin was classified as urban and suburban (5 percent), water (5
percent), and wetlands (7 percent) (USGS, 1999b).
     The Upper Mississippi River case study area includes a number of counties
identified by OMB (1999) as a Metropolitan Statistical Area (MSA) (Table 12-1).
Long-term trends in the population of the 13-county Minneapolis-St. Paul MSA
are shown in Figure 12-5. Resident population in this MSA increased by 150
percent from 1.1 million in 1940 to 2.76 million in 1996. After a small increase of
population from 1940 to 1950, the greatest rate of growth occurred during the
1950s and 1960s, when population increased by 23-27 percent. The rate of
population growth then declined during the 1970s to 8.5 percent, with an increase
to 15 percent during the 1980s. During the period from  1990 to 1996, population
increased by 9 percent (Forstall, 1995; USDOC, 1998). Reflecting population
growth in the Twin Cities area, the population served by the Metro plant increased
from 1.04 million in 1962 to 1.68 million in 1997. By 2020, the plant is expected to
provide service to 1.94 million people (Larson, 1999).
   Table 12-1.  Metropolitan Statistical Area (MSA) counties in the Upper Mississippi
   River case study. Source: OMB, 1999.

                 Anoka                       Scott
                 Carver                       Sherburne
                 Chicago                      Washington
                 Dakota                       Wright
                 Hennepin                     Pierce
                 Isanti                        St. Croix
                 Ramsey
                                                                                             12-5

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
Figure 12-5
Long-term trends in
population for the
Minneapolis-St. Paul, MN-
Wl MSA counties for the
Upper Mississippi  River
case study area.
Sources: Forstall, 1995;
USDOC, 1998.
                                              1940   1950   1960   1970   1980   1990   1996
                          Historical Water Quality  Issues

                              As with many other urban areas of the United States, the Upper Mississippi
                          River was grossly polluted early in the 20th century because of growing urban
                          populations and inadequately treated municipal and industrial wastewater dis-
                          charges. Municipal officials simply relied on the natural flushing of rivers to dilute
                          the human and industrial waste products of the growing metropolitan areas. City
                          sewers, first constructed in 1871 in the Twin Cities, collected storm water and
                          sewage and discharged them directly into the river. By the early 1900s, the Upper
                          Mississippi River was unable to biologically assimilate the untreated wastewater
                          collected from the Twin Cities (MWCC, 1988).
                              Before construction  of a lock and dam in Minneapolis in 1917, annual peak
                          spring flows maintained a minimally acceptable degree of water quality by the
                          physical removal of raw sewage and other waste materials accumulated during
                          the previous year in the Twin Cities area. Construction of the lock and dam,
                          however, drastically altered this natural cycle by slowing the current of the river
                          and reducing the flushing  effect of the peak spring flows. By 1920, 3  million cubic
                          yards of sewage sludge had accumulated in the pool created by the lock and dam.
                          Water quality was severely degraded by depletion of dissolved oxygen from
                          decomposition of the sludge bed. Bacteria levels were extremely high, sewage
                          sludge mats floated on the surface, and the river was noxious from hydrogen
                          sulfide gas caused by septic conditions during the warm summer months. The
                          Upper Mississippi River was grossly polluted for a distance of 30 miles from St.
                          Anthony's Falls in Minneapolis to the St. Croix River at Prescott, Wisconsin
                          (MWCC,  1988).
                              A 1928 joint report by the Minnesota and Wisconsin State Boards of Health
                          stated that "a zone of heavy pollution  extends from Minneapolis  to the mouth
                          of the St.  Croix."  The state report pronounced  "the river in this zone .  . . unfit
                         for use as a water supply . . . fish life has been exterminated. "  The report
                          stated that the river was  "a potential danger from a health standpoint. "
                          Beginning with a river survey in 1926, the State Board of Health documented DO
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                                                        Chapter 12: Upper Mississippi River Case Study
levels of less than 1 mg/L over a 25-mile reach from St. Paul to Hastings, Minne-
sota, that could not support a healthy aquatic ecosystem, including pollution-
tolerant carp (Mockavak, 1990). From 1926 to 1937, minimum DO levels of 1 to 2
mg/L indicated less than 10 percent of oxygen saturation over a 20- to 25-mile
reach downstream from St. Paul (Wolman,  1971). Bacteria levels were also
extremely high, with total coliform concentrations of 105 to 106 MPN/100 mL
measured  downstream of St. Paul (MRI, 1976). The extent of the public health
risk incurred from the discharge of raw sewage by the Twin Cities was made
painfully clear in 1935 when a failure of the chlorination units at the public water
supply plant resulted in a serious typhoid epidemic with 213 cases and 7 deaths
(USPHS,  1953).
     In adopting the 1928 Board of Health recommendations, the Twin Cities
became the first major city on the Mississippi River  to implement primary treat-
ment and chlorination for its municipal water pollution control plant in 1938. Water
quality quickly improved dramatically as the floating mats of sludge disappeared,
and DO levels increased to better than 3 mg/L from 1942 through 1955
(Mockovak, 1990; Wolman, 1971). Within 2 years fish returned and anglers
reported catching walleye and other game fish in parts of the river that had been
devoid of game fish prior to 1938. Maurice Robbins, a former deputy administra-
tor of the Metropolitan Waste Control Commission (MWCC), recalled that  "The
impact [of waste treatment] on the river was tremendous . .  . no more dead
fish, no more sewage smell" (MWCC,  1988).
     With increasing population (Figure 12-5), growth eventually overwhelmed
the capacity of the river to assimilate the wastewater discharge from the primary
Metro plant during the mid-1950s through the mid-1960s. Water quality once
again deteriorated to conditions reminiscent of the 1920s and 1930s. During the
summer of 1964, the Federal Water Pollution Control Administration (FWPCA)
conducted a water pollution survey of the Upper Mississippi River that docu-
mented severe degradation of water quality (FWPCA, 1966). In contrast to an
average of about 30,000 MPN/100 mL near St. Paul during the 1950s, total
coliform densities ranged from 460,000 to 17,000,000 MPN/100 mL 9 miles
downstream of St. Paul. Minimum DO levels of less than 1 mg/L were also
recorded for 15 miles downstream of St. Paul. The biological health of the river
abruptly changed, with a zone of degradation and decay extending 20 miles from
St. Paul to Lock and Dam No.  2 at Hastings, Minnesota. The river bottom, thick
with sewage sludge, was found to be devoid of the benthic organisms usually
associated with clean waters (FWPCA, 1966; WRE, 1975).
     In 1966 the Metro plant was upgraded to secondary treatment using the
activated sludge process. Water quality once again improved, surpassing the 1928
guidelines. The rapidly growing suburban population, however, tended to generate
more residual waste load than could be removed by  upgrading the plant to sec-
ondary treatment. Regardless of the Metro plant upgrades, annual high spring
flows caused flooding of the plant, resulting in the discharge of raw sewage into
the river. During the late 1960s, only 4 of the 33 suburban treatment plants
provided adequate levels of treatment, thus contributing to the overall pollution
loading of the river. Minneapolis and St. Paul further contributed to periodic
pollution loading to the river through a network of combined storm water and
sewage collection sewers that discharged raw sewage during rainstorms.
                                                                                              12-7

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
                              In 1984 the Metro plant was upgraded once again to advanced secondary
                         treatment with nitrification, designed to reduce effluent levels of ammonia. After
                         implementation of secondary and advanced secondary waste treatment for the
                         wastewater treatment plants of the Twin Cities area by the mid-1980s, water
                         quality of the Upper Mississippi River routinely has been in compliance with
                         water quality standards for dissolved oxygen and un-ionized ammonia. In contrast
                         to the record of compliance for oxygen and un-ionized ammonia, turbidity levels
                         have exceeded water quality objectives as a result of nonpoint source runoff of
                         sediment from the Minnesota River basin (MWCC, 1994). Because the land uses
                         of the Minnesota River basin are dominated by agricultural row crops and the
                         fine-textured soils further contribute to sediment losses, the annual mean (1976-
                         1996) sediment yield of 134 Ib/acre-yr from the Minnesota River watershed is
                         almost five times greater than the annual mean sediment yield of 28 Ib/acre-yr
                         estimated for the Upper Mississippi River basin upstream of Lock & Dam No. 1
                         (Meyer and Schellhaass, 1999). Fecal coliform levels also remained high and
                         often violated state water quality standards through the mid-1980s because of
                         combined sewer overflows during rainstorms. Fecal coliform bacteria samples are
                         in compliance with Minnesota water quality standards if the monthly geometric
                         mean is less than 200 MPN/100 mL and any individual sample does not exceed
                         2000 MPN/100 mL.
                              In 1984 it was estimated that 4.6 billion gallons per year of raw sewage and
                         storm water were discharged to the Upper Mississippi River. In response to this
                         water quality problem and public pressure, the Twin Cities implemented an
                         aggressive $320 million (1996 dollars) construction program from 1985 to 1995
                         intended to accelerate the completion of the ongoing project to separate the
                         combined sewers (MCES,  1996). As a result of the separation of storm water
                         and raw sewage from the combined sewer system, fecal coliform bacteria levels
                         have declined considerably, and compliance with state water quality standards has
                         improved greatly at stations monitored at Lock and Dam No.l, St. Paul, Grey
                         Cloud Island, and Pool 2 (Buttleman and Moore, 1999). Figure 12-6 shows the
                         reduction in bacteria levels and the corresponding improvement in compliance
                         with water quality standards. The monitoring station at St. Paul exhibits the
                         greatest improvement, with compliance achieved at the 71 percent level for
                         samples collected from 1996 to 1998. High bacteria levels, however, do occasion-
                         ally occur in the heavily urbanized area upstream of Lock and Dam No. 1; the
                         high levels apparently are associated with urban storm water runoff (Buttleman
                         and Moore, 1999).
                              To remedy the periodic flooding of the Metro plant that resulted in the
                         discharge of raw sewage to the river, flood protection projects were completed in
                         1975 and effluent pumps were installed in 1977. The pumps allowed the Metro
                         plant to treat wastewater during the annual spring floods. The success of the
                         flood control efforts at the Metro plant was dramatically demonstrated during the
                         flood events of 1993 and 1997 when the plant recorded 100 percent compliance
                         with NPDES permit limits during these two extreme events. Many other water
                         pollution control plants in the region were forced to bypass waste treatment as a
                         result of these extraordinary floods (Larson, 1999). In addition to their use for
                         flood control, the effluent pumps are used during low-flow conditions when DO
                         levels are depressed to aerate the effluent to increase ambient oxygen levels in
                         the river.
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                                                          Chapter 12:  Upper Mississippi River Case Study
            100%
                           494
                                                             500
                        1976-85
                                    1986-95
1996-98
                       |   | % compliance ^ #/100 mL
Figure 12-6
Pre- and post-CSO
separation project trends
in fecal coliform bacteria
for the Upper Mississippi
River at St. Paul. State
standard for fecal coliform
bacteria is 200 MPN/100
ml  based  on  monthly
geometric mean from May
to October.
Source: Buttleman and
Moore, 1999.
     Responding to federal industrial pretreatment requirements promulgated in
1979, the Twin Cities initiated a program to reduce discharges of heavy metals to
the Upper Mississippi River. A comprehensive strategy was adopted in 1981 to
reduce the discharge of heavy metals from municipal water pollution control
plants contributed by sanitary sewer discharges from industrial sources. By 1992,
a decade after beginning the program, the loading of heavy metals to the river had
been reduced by an average of 82 percent, with declines in ambient levels of
heavy metals. Using sediment cores collected in Lake Pepin, Balogh et al. (1999)
have reconstructed historical loading rates of mercury from ca. 1800 to 1996 from
the Upper Mississippi River watershed to Lake Pepin (Figure 12-7). Averaging
the sediment core data by 10-year intervals, Balogh et al. estimated a loading rate
of 3 kg/yr to characterize naturally occurring deposition of mercury under pristine
conditions before European settlement began ca.  1830. Mercury deposition
progressively increased during the 19th and 20th centuries, with about one-half of
the total mercury load deposited from  1940 to 1970 and the peak accumulation
rate of 357 kg/yr identified during the 1960s. As a result of decreasing the
discharges of mercury from municipal and industrial wastewater plants, the
2000.
1980!
1960'
1940!
1920!
1900!
1880!
1860!
1840!
1820;
1800"


^_^^
S^^~
M

•

1
•























                       100
                  400
                                                                               Figure 12-7
                                                                               Historical mercury loading
                                                                               rates in the Upper
                                                                               Mississippi River
                                                                               reconstructed from
                                                                               sediments of Lake Pepin.
                                                                               Sediment core data
                                                                               averaged at 10-year
                                                                               intervals from 1800-1810
                                                                               through 1980-1989 and
                                                                               1990-1996.
                                                                               Source: Balogh et al.,
                                                                               1999.
                            Mercury Accumulation (kg/yr)
                                                                                                  12-9

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
                         deposition rate in Lake Pepin has declined by almost 70 percent from the maxi-
                         mum loading during the 1960s to 110 kg/yr during 1990-1996. Although the
                         investment in water pollution control has been very successful in reducing mer-
                         cury in the Upper Mississippi River, ambient levels of mercury are still 30 times
                         greater than the pristine conditions of the early 1800s (MCES, 2000). As of the
                         late 1990s, the MCES is actively working to monitor and reduce even further the
                         remaining sources of heavy metals, including mercury discharges to the river by
                         wastewater treatment plants (MCES, 2000).
                              During the 1950s and 1960s, the depletion of dissolved oxygen in Pool 2 of
                         the Upper Mississippi River near St. Paul adversely affected pollution-intolerant
                         fish and other aquatic organisms. Studies during the early 1960s, for example,
                         documented  that burrowing mayflies (Hexagenio), an aquatic organism that is
                         very sensitive to low DO conditions, were very scarce or absent from Pools 2 and
                         3 and Lake Pepin (Pool 4) of the river (Fremling, 1964). With the restoration of
                         healthy levels of dissolved oxygen beginning in the mid-1980s, an abundance of
                         mayflies once again colonized suitable habitats in the Upper Mississippi River
                         from St. Paul to Lake Pepin after a 30-year absence from the river (Fremling and
                         Johnson, 1990; MDNR, 1988). The resurgence of mayflies, significant improve-
                         ments in ambient levels of DO and fecal coliform bacteria in Pool 2, and the
                         reduction of mercury loading to the sediments of Lake Pepin demonstrate the
                         successes of the water pollution control efforts implemented beginning in the
                         1980s. The Metro plant was upgraded to advanced secondary treatment with
                         nitrification in 1984; the industrial pretreatment program was begun in 1982; and
                         the accelerated CSO separation project, initiated in 1985 to jump-start an ongoing
                         sewer separation project, was completed in 1995.
                         Legislative and  Regulatory  History

                              The Minnesota State Legislature passed an act in 1885 to prevent the
                         pollution of rivers and other water supply sources. For the next 60 years, the
                         Minnesota Board of Health had responsibility for water pollution problems. By
                         1907 the State Board of Health realized that consumption of drinking water
                         contaminated by raw sewage discharges posed a serious public health threat.
                         Without any authority, the Board of Health attempted to pressure the Twin Cities
                         communities to install wastewater treatment facilities. In 1917 the State Board of
                         Health adopted regulations requiring towns to submit plans for sewers and
                         wastewater treatment plants prior to construction. The Board also conducted
                         water pollution surveys and made various recommendations for controlling
                         pollution. Letters to the city councils of the Twin Cities urging action on controlling
                         the discharge of raw sewage went unanswered in 1923 and 1925. At the request
                         of the State Board of Health, the U.S. Public Health Service conducted the first
                         water pollution survey of the Upper Mississippi River from the Twin Cities to
                         Winona, Minnesota, in 1926.
                              During the 1920s the Izaak Walton League, the Engineers Society of St.
                         Paul, the Engineering Club of Minneapolis, and other private groups lobbied for
                         immediate action on the problem of raw waste disposal into the river. In 1926 the
                         Minneapolis Sanitary Commission was created to study "the condition of the
                         river and the problems of sewage disposal" (MWCC, 1988). In 1927, when
12-10

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                                                         Chapter 12: Upper Mississippi River Case Study
the Metropolitan Drainage Commission was formed, raw sewage was discharged
through 84 outfalls over a network of 1,125 miles of sewers (MWCC, 1988).
Maurice Robbins, a former deputy administrator of MWCC, remembering his
experiences sampling the river during those years, stated that "It could get pretty
awful down by the river. There were floating feces, dead fish and a  terrible
sewer smell" (MWCC,  1988).
     In 1927 the State Board of Health was given the authority and the responsi-
bility to administer and enforce all laws related to water pollution in Minnesota.
The legislature directed the State Board of Health to form a Metropolitan Drain-
age Commission. The legislature, however, did not provide any substantial basis
for managing waste disposal. In 1933, a decade after the Minnesota State Board
of Health had begun to document the pollution problems of the Upper Mississippi
River, the Minneapolis-St. Paul Sanitary District was finally created to oversee
construction of the first primary wastewater treatment plant in the Twin Cities
region. The primary treatment plant, located near Pig's Eye Lake in St. Paul, went
online in 1938.
     In 1945 the legislature passed the Water Pollution Control Act to establish
the Water Pollution Control Commission for the regulation of the emerging
problems of water pollution. The Minnesota Act, amended in 1951, 1959, and
1963, was regarded as one of the better water pollution control acts in the United
States (FWPCA, 1966). The main mission of the new Water Pollution Control
Commission was to direct the construction of primary wastewater treatment
plants for the smaller municipalities in the Twin Cities metropolitan area.
     In 1967 the state legislature formed the Metropolitan Council as a regional
coordination agency. In 1969 the Metropolitan Waste Control Commission
(MWCC) was given the regional responsibility for wastewater collection and
treatment systems for 33 plants within 200 political jurisdictions of the seven-
county Twin Cities area. In 1967 the legislature also created the Minnesota
Pollution Control Agency (MPCA) to replace the Water Pollution Control Com-
mission. The new agency was soon given authority to regulate and enforce
effluent limits for municipal and industrial treatment plants. The establishment of
the U.S. Environmental Protection Agency and the enactment of the  1972 Clean
Water Act further strengthened the regulatory powers for requiring uniform
effluent limits for wastewater dischargers. In July 1994 the MWCC and transit
services were merged with the Metropolitan Council. The responsibility for
operating municipal wastewater treatment plants was delegated to the Environ-
mental Services Division of the Metropolitan Council (MCES).
     Following the 1972 Clean Water Act, the MWCC, with federal (75 percent)
and state (15 percent) funding assistance, spent more than $350 million to dra-
matically improve the technology of the Metro plant, upgrade other facilities, and
build interceptor sewer systems (MWCC, 1988). During the 1970s and 1980s,
MWCC phased out or upgraded old plants or constructed new plants for many of
the suburban communities in the Twin Cities region. MCES now operates the
Metro plant and eight other treatment plants in the Twin Cities area. The Metro
plant and three other wastewater treatment plants discharge to the Upper Missis-
sippi River; three plants discharge effluent to the Minnesota River; and the St.
Croix River and the Vermilion River each receive effluent discharges from one
municipal plant.
                                                                                              12-11

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
Figure 12-8
Long-term trends in
population served and
effluent flow for the Metro
plant in St. Paul.
Source: Larson, 1999.
                        Impact of  Wastewater  Treatment:

                        Pollutant Loading  and Water  Quality

                        Trends

                             During the 1960s and 1970s, effluent loading from the Metro plant ac-
                        counted for more than three-quarters of the total point source load of BOD5 in the
                        section of the Upper Mississippi River from the Twin Cities to the St. Croix River.
                        Because this one wastewater treatment plant, the Metro plant, accounted more
                        than 75 percent of the total point source load, historical effluent data from the
                        Metro plant can serve as an indicator to demonstrate the success of public
                        investments to upgrade the plant in improving water quality in the Upper Missis-
                        sippi River. Figures 12-8 through 12-11 present time-series trend data for popula-
                        tion served, effluent flow, BOD,., total suspended solids (TSS), total Kjeldahl
                        nitrogen (TKN), and ammonia loading for the Metro plant (Larson,  1999).
                             During the early 1960s, the Metro plant served 1.05 million people and
                        discharged 158 mgd to the Upper Mississippi River. By 1997 the population
                        served by Metro had grown to 1.7 million with a corresponding increase in the
                        effluent discharge rate to 225 mgd (Figure 12-8). Since enactment of the Clean
                        Water Act in 1972, effluent BOD5 loading  from the Metro plant has been reduced
                        greatly from the peak loading period of the mid-1960s. Before upgrading the
                        Metro plant, effluent BOD5 loading peaked at about 330,000 Ib/day in 1968. After
                        upgrading to secondary in 1966, effluent loading dropped to 114,000 Ib/day by
                        1970 and 77,000 Ib/day in 1973. Since the 1980s, effluent loading of BOD5 has
                        continued to decline as a result of additional upgrades (e.g., advanced secondary
                        in 1984) and replacement, or abandonment, of 21 of the 33 suburban wastewater
                        treatment plants that existed in 1969 when MWCC assumed responsibility for
                        plant operations. BOD5 loading from Metro declined again to 40,000 Ib/day by
                        1980 and to 27,000 Ib/day by 1990 (Figure 12-9). Over a 30-year period, upgrades
                        and improvements to the Metro plant have reduced effluent BOD5 loading by 95
                        percent from the historical peak loading of 330,000 Ib/day in 1968 to only 17,000
                        Ib/day in 1998. Over the same period, the effluent concentration of BOD5 has
                        been reduced from 184 mg/L in 1968 to 9.7 mg/L in 1998.
                                  ?960' ' 1965' ' 1970' ' 1975' ' ^80
                                              Flow
-•• • Population Served
12-12

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                                                         Chapter 12:  Upper Mississippi River Case Study
     Upgrades and improvements to the Metro plant have also resulted in large
reductions in effluent loading of suspended solids and nitrogen. TSS loading has
dropped by 95 percent from the peak loading rate of 219,000 Ib/day in 1968 to
10,000 Ib/day by 1998; effluent concentration declined from 122 mg/L in 1968 to
5.7 mg/L by 1998 (Figure 12-10). Based on effluent data from monitoring that
began in  1971, TKN loading has dropped by 78 percent from the peak loading
rate of 36,500 Ib/day in 1982 to 7,800 Ib/day by 1998; effluent concentration has
been reduced from 21 mg/L in 1982 to 4.5 mg/L by 1998 (Figure 12-11). Prior to
the upgrade to advanced secondary with nitrification, toxicity-based water quality
standards for the un-ionized portion of ammonia were frequently violated in the
Upper Mississippi River. After upgrading the plant to nitrification with ammonia
removal in 1984, effluent discharges of ammonia declined considerably. Using
effluent data collected since 1975, ammonia nitrogen (NH3-N) loading has
dropped by 90 percent from the peak loading rate of 25,500 Ib/day in 1982 to
2,600 Ib/day by 1998. The effluent concentration of ammonia has been reduced
from 14.7 mg/L in 1982 to 1.5 mg/L by 1998 (Figure 12-11).
   400:
~ 350:
£     '-
|  300;
8  250^
5" 200;
§  150!
§  1003
                                                    200

                                                    175

                                                    150'

                                                    125;

                                                    100]

                                                    75
                                                               50
                                                              :25
?960' ' 1&5 ' ' WO' '  1975
                                  ' 1985 '
                                                      1995 ' ' 20o8
                                                                              Figure 12-9
                                                                              Long-term trends in
                                                                              effluent loading of BOD5 for
                                                                              the Metro plant in St. Paul.
                                                                              Source: Larson, 1999.
                      BODS Load
                              	BODS Concentration
                                                               125
                                                                  UJ
                                                                              Figure 12-10
                                                                              Long-term trends in
                                                                              effluent loading of TSS for
                                                                              the Metro plant in St. Paul.
                                                                              Source: Larson, 1999,
                      TSS Load
                              	TSS Concentration
                                                                                               12-13

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
Figure 12-11
Long-term trends in
effluent loading of TKN and
ammonia-N for the  Metro
plant in St. Paul.
Source: Larson, 1999.
                                    1960   1965   1970   1975   1980   1985   1990   1995
                                       • TKN Load -» • NH3 Load
                                 TKN Cone. -* • NH3 Cone.
                              Beginning in the 1920s through the 1970s, the major water quality issues for
                         the Upper Mississippi River have been bacterial contamination and depletion of
                         DO from sewage discharges and combined sewer overflows. Historical DO data
                         sets collected since 1926 illustrate the dramatic change in long-term trends in the
                         spatial distribution of DO recorded 5 miles downstream of the confluence with the
                         Minnesota River near St. Paul (UM milepoint 840) to Lock and Dam No. 3 at
                         Red Wing, Minnesota (UM milepoint 797) (Figure 12-12). These historical data
                         sets clearly illustrate the adverse impacts of wastewater loading and the effec-
                         tiveness of upgrades in wastewater treatment implemented in 1938, 1966, and the
                         early 1970s at the Metro plant. Because of the hydraulic characteristics of the
                         Upper Mississippi River, minimum DO levels have been consistently observed in a
                         zone 5 to 15 miles downstream of the Metro plant discharge, within the oxygen
                         sag region from Newport (UM milepoint 820) to Grey Cloud (UM milepoint 830).
                              Using historical data available from EPA's STORE! water quality database,
                         the long-term trend of summer DO and BOD5 (1940-1995) has been compiled
                         from monitoring station records extracted for RF1 reach 07010206001 from the
                         Minnesota River (UM milepoint 844.7) to the St. Croix River (UM milepoint 811).
 Figure 12-12
 Spatial trends of August
 DO in the Upper
 Mississippi River from
 1926 to 1988-96 from St.
 Paul (UM milepoint 840) to
 Lock & Dam No. 3 at
 Redwing (UM milepoint
 797).
 Sources: Larson, 1999;
 Mockovak, 1990; MWCC,
 1989; Johnson and Aasen,
 1989.
                                   10
    5-
1
                                    0 ~l i i T~I i i i r i i i i i i i i i i I" i i i i i i i i i i r i i i i i i i i i i ri i i i i i i i i
                                    -850      -840       -830      -820      -810      -800
                                                       Upper Mississippi River Mile
                                                            -790
 12-14

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                                                        Chapter 12: Upper Mississippi River Case Study
Although DO is characterized by a high degree of interannual variability because
of temporal variability in streamflow and the spatial gradient over this 34-mile-long
reach, there has been a definite improvement in this long reach between the
1960s when summer mean oxygen levels ranged from approximately 4 to 7 mg/L
to the period from the mid-1970s through the mid-1990s when summer mean
oxygen levels consistently ranged from approximately 7 to 8 mg/L even during the
drought conditions of 1987-1988 (Figure 12-13). The trend of improvement in DO
during the 1980s and 1990s is consistent with the long-term trend of improvement
in ambient BOD5 extracted for the same reach (Figure 12-14). During the 1960s
and 1970s, summer mean BOD5 ranged from approximately 4 to 8 mg/L. During
the 1980s mean BOD5 ranged from approximately 2.5 to 4.5 mg/L. In the period
1990-1995, mean ambient BOD5 declined even further to levels ranging from
approximately 2 to 3.5 mg/L as a result of upgrading the Metro plant to advanced
secondary with nitrification in the late 1980s.
     In interpreting  the year-to-year variability of the long-term DO data from
1940 through 1995, it is important to understand the influence of streamflow on
summer oxygen levels under the peak effluent loading conditions of the 1960s and
                                                                             Figure 12-13
                                                                             Long-term trends of mean,
                                                                             10th percentile, and 90th
                                                                             percentile summer  DO in
                                                                             the Upper Mississippi
                                                                             River for RF1 reach
                                                                             07010206001 from the
                                                                             Minnesota River (DM
                                                                             milepoint 844.7) to the St.
                                                                             Croix River (DM milepoint
                                                                             811).
                                                                             Source: USEPA (STORET).
          1940     1950     1960     1970     1980     1990     2000
                      St. Croix R-Minnesota R [DM 811-844.7]
         10

         1940     1950      1960     1970     1980     1990
                      St. Croix R-Minnesota R [UM 811-844.7]
                                                                mean
                                                                90%ile
2000
                Figure 12-14
                Long-term trends of mean,
                10th percentile, and 90th
                percentile summer BOD5
                in the Upper Mississippi
                River for RF1 reach
                07010206001 from the
                Minnesota River (UM
                milepoint  844.7) to the St.
                Croix River (UM milepoint
                811).
                Source: USEPA (STORET).
                                                                                              12-15

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
                          early 1970s compared to the greatly reduced effluent loading conditions that have
                          characterized the Twin Cities area since the mid-1970s. Under conditions of
                          similar effluent loading rates, DO decreases during low-flow conditions in contrast
                          to a relative increase during higher summer flow conditions. Over years of
                          comparable effluent BOD5 loading, the interannual cycles that appear to show
                          trends of either "improvement" or "degradation" in DO (Figure 12-13) are caused
                          primarily by year-to-year variability of summer streamflow (see Figure 12-4). An
                          accurate evaluation of the long-term trend in improvement of DO is possible only
                          by filtering the time series of oxygen records to extract only those summers that
                          are characterized by dry streamflow conditions.
                               Figure 12-15 shows long-term trends in DO conditions for "dry" summers
                          for a  subreach of the RF1 reach 07010206001 for the critical oxygen sag location
                          from Newport (UM milepoint 820) to Grey Cloud (UM milepoint 830). The time
                          series record of DO data in Figure 12-15 is extracted to highlight the trend in
                          improvement for summers of comparable "dry" streamflow conditions when the
                          flow  at the St. Paul USGS gage was less than 75 percent of the long-term (1951-
                          1980) summer mean. During the  1960s, low-flow summer mean DO levels
                          violated water quality standards with concentrations as low as less than 1  mg/L in
                          1961  to approximately 4 mg/L in 1964. After the upgrade of the Metro plant to
                          advanced secondary with nitrification in the late 1980s, mean summer DO levels
                          in the critical subreach had improved to levels as high as approximately 6 to 7 mg/
                          L even during the extreme drought conditions of 1987-1988. Using before and
                          after  data in a postaudit model applied  to the low-flow summers of 1976 and 1988,
                          Lung (1996a)  has clearly demonstrated that the improvements in DO can be
                          directly related to upgrades of the Metro plant.
                               As shown by the historical records for fecal coliform bacteria (Figure  12-6),
                          DO (Figure 12-15), and levels of sediment mercury in Lake Pepin (Figure 12-7),
                          investments in water pollution control programs of the 1970s and 1980s have
                          succeeded  in improving water quality conditions for these historical problems of
                          the 1950s,  1960s, and 1970s in the Upper Mississippi River.  During the 1980s and
                          1990s, water quality and comprehensive ecological investigations in the Upper
                          Mississippi River have identified a number of contemporary chemical and
                                   10
Figure 12-15
Long-term trends of mean
summer DO in the  Upper
Mississippi River for years
characterized by "dry"
streamflow conditions less
than 75 percent of long-
term  (1951-1980) summer
mean streamflow. Data
extracted for subreach
from Newport to Grey
Cloud (UM milepoint 820-
830).
Source: USEPA (STORET).
5-
                                          40 41 48 49 50 58 59 6061 64 67 70 71 73 74 76 7780 87 88 89 90
                                                   Dry Years (Flow <75% summer mean)
12-16

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                                                         Chapter 12: Upper Mississippi River Case Study
 nonchemical problems in the basin. Nonchemical issues identified as threats to the
 ecological processes of the river and floodplain ecosystem include, for example,
 loss of habitat and wetlands and man-made alterations from flood control and
 navigation projects. Contemporary chemical problems include inputs of nutrients,
 sediments, heavy metals, pesticides, and other toxic chemicals.
     For example, the loading of phosphorus and suspended solids influences
 water quality in Lake Pepin, a natural impoundment located about 50 miles
 downstream of St. Paul.  Lake Pepin is eutrophic, with high annual mean concen-
 trations of total phosphorus (0.16 mg/L) and soluble reactive phosphorus (SRP)
 (0.07 mg/L) (James et al., 1996) recorded at the inlet  to the lake (UM milepoint
 797) during the average flow years of 1994-1996. Eutrophic conditions in the lake
 are caused by excessive loading of nutrients from point and nonpoint sources in
 the watershed. When physical and hydrological conditions  are favorable, such as
 during low-flow summers, nuisance algal blooms (i.e., viable chlorophyll a greater
 than 30 ug/L) occur. Concerns related to  the need for controls on phosphorus
 loading arose after severe algal blooms and fish kills in Lake Pepin occurred
 under the drought conditions of 1987-1988 (Johnson, 1999).
     The Lake Pepin Phosphorus Study, conducted from 1994-1998, compiled
 historical and contemporary data sets to evaluate the human impact on (1) long-
 term records of sediment and phosphorus loading to Lake Pepin and (2) the
 corresponding water quality responses to changes in loading to the lake. Since
 European settlement ca.  1830s, the contemporary (1990-1996) annual input of
 approximately 850,000 metric tons/year of sediment is about ten times greater
 than the loading  rates estimated for the pre-settlement era.  Analysis of data from
 the three basins included in the study, the  Upper Mississippi River, the Minnesota
 River and the St. Croix River, indicates that 90 percent of the increased sediment
 load to Lake Pepin is contributed by erosion of fine-textured soils from the
 Minnesota River basin. The record of sediment deposition in Lake Pepin also
 indicates that the most rapid rates of sediment input to the lake occurred during
 the 1940s  and  1950s. If current sedimentation rates continue from erosion in the
 Minnesota River basin, Lake Pepin could be completely filled in about 340 years (
 EngstromandAlmendinger, 1998).
     Over the  past two centuries, phosphorus concentrations in the sediments of
 Lake Pepin have increased twofold while water column concentrations (inferred
 from diatom assemblages in the sediments) appear to have  increased by a factor
 of 4 since European settlement ca. 1830s. Increased phosphorus levels in  the
 sediments and  water column are the result of an increase in phosphorus loads to
 Lake Pepin by a  factor of 5 to 7 since the 1830s to  the contemporary estimated
 loading rate of approximately 4,000-5,000 metric tons/year  for 1990-1996. Waste-
 water discharges and agricultural applications  of manure and commercial fertilizer
 are most likely the key factors controlling historical phosphorus loads to Lake
 Pepin, and the  statewide ban on phosphates in detergents contributed to a reduc-
tion in phosphorus loading from municipal wastewater plants by approximately 40
percent over the period from 1970 to 1980.  Since the  1830s era, the progressive
increase in phosphorus loading has resulted in a shift in assemblages of diatoms
from clear water benthic algae and mesotrophic water column species in the pre-
 settlement era to  planktonic species exclusively characteristic of highly eutrophic
conditions in the  1990s (Engstrom and Almendinger, 1998).
                                                                                             12-17

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment


                               In evaluating strategies to reduce phosphorus loads to Lake Pepin, the
                          significant differences in the relative contributions of point and nonpoint sources
                          of flow, solids, and nutrient loads under a range of flow conditions need to be
                          considered over a time scale of decades. Point and nonpoint source loading data
                          for suspended solids and total phosphorus have been compiled for low-flow
                          (1988), average-flow (1994-1996) and high-flow (1993) conditions for the Upper
                          Mississippi River (upstream of Lock and Dam No. 1), the Minnesota River, and
                          the St. Croix River (Meyer and Schellhaass, 1999). Based on 21 years of data
                          (1976-1996), the mean yield of total phosphorus from the agriculturally dominated
                          Minnesota River (0.33 Ib/acre-yr) is twice as great as the mean yield from the
                          Upper Mississippi River basin upstream of Lock and Dam No. 1 (0.16 Ib/acre-yr)
                          and the St. Croix River basin (0.14 Ib/acre-yr). Figure 12-16 presents a compari-
                          son of the magnitude of point source loads and nonpoint source loads of total
                          phosphorus from the Upper Mississippi River, Minnesota River, and St. Croix
                          River basins for 1988 (drought), 1993 (flood) and 1994-1996 (average conditions)
                          (Meyer and Schellhaass, 1999).
                               Under the extreme flood conditions of 1993, nonpoint source loadings of
                          total phosphorus from the Minnesota River and the Upper Mississippi River
                          watersheds have been shown to account for 58  percent and 15 percent, respec-
                          tively, of the total phosphorus load of 6,030 metric tons/yr estimated for 1993
                          while point sources from the Metro plant accounted for 15 percent of the total
                          phosphorus load. During the severe drought conditions of 1988, the total phospho-
                          rus load of 1,900 mt/yr was only about one-third of the 1993 load. Under the
                          drought conditions, the Metro plant accounted for 47 percent of the total phospho-
                          rus load and nonpoint source loading from the Minnesota River and the Upper
                          Mississippi River contributed only 6 percent and 3 percent, respectively, of the
                          total phosphorus load of 1,900 mt/yr. During the average flow conditions of 1994-
                          1996, the total phosphorus load of 3,800 mt/yr was two times greater than the
                          1988 drought load. Under average flow conditions, the Metro plant accounted for
                          28 percent of the total phosphorus load and nonpoint source loading from the
                          Minnesota River and the Upper Mississippi River contributed 38 percent and 14
                          percent, respectively, of the total phosphorus load of 3,800 mt/yr.
                                    eooor
Figure 12-16
Comparison of total
phosphorus loadings from
nonpoint sources (NPS) in
the Upper Mississippi
River (UM, to Lock & Dam
No. 1), Minnesota River
(Ml), and St. Croix River
(SC) basins and point
source (PS) loadings from
the Metro plant and other
facilities in the three river
basins.
Source: Meyer and
Schellhaass, 1999.
                          Other-PS

                          Metro-PS

                          SC-NPS
                          S3
                          UM-NPS
                          •
                          MI-NPS
                                                1988
1993
1994-96
12-18

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                                                         Chapter 12: Upper Mississippi River Case Study
     Meyer and Schellhaass (1999) have used this data set to develop summary
budgets of the relative contributions of point source and nonpoint source loadings
of total phosphorus to the three river basins during 1988,1993, and 1994-1996.
Under the drought conditions of 1988, the contribution from point sources (88.5
percent) dominated the total inputs of phosphorus compared to the 11.5 percent
accounted for by nonpoint sources. During the extreme flood conditions of 1993,
nonpoint source loads accounted for about three-quarters (74.5  percent) of the
total input of phosphorus, with point sources accounting for about one-quarter
(25.5 percent). During the average flow conditions of 1994-1996, the relative
contribution of point sources (56.2 percent) and nonpoint sources (43.8 percent)
was almost comparable.
     These point source loading and nonpoint source loading data sets for sus-
pended sediments and phosphorus and a number of other field studies (e.g.,
James  et al.,  1999) have been used to support the development  of an advanced
model  of sediment transport and eutrophication for the Upper Mississippi River
and Lake Pepin (HydroQual, 1999a,  1999b). As of 2000 the MCES is using the
model  to evaluate the effectiveness of alternative strategies to control point and
nonpoint phosphorus loading to the Upper Mississippi River to achieve the water
quality objectives established for Lake Pepin. Evaluations of sediment loading
contributed primarily from agricultural runoff in the Minnesota River basin have
also been a key issue in  the Minnesota River  Assessment Project (MPCA, 1994).
     On the much larger scale of the entire Mississippi River basin, nitrogen
loading from the Mississippi River has been identified as a major cause of the
algal blooms and hypoxia that occur over a 16,000-square-kilometer area of the
inner Gulf of Mexico known as the "Dead Zone" (Christen, 1999; Malakoff,  1998;
Moffatt, 1998; Rabelais et al., 1996; Vitousek et al., 1997). Based on technical
assessments of the "Dead Zone" problem, a U.S.  EPA and NOAA Action Plan,
expected to be released in August 2000, will most likely recommend that efforts
be undertaken to reduce  inputs of nitrogen from wastewater treatment plants and
agricultural land uses (e.g., fertilizer applications and confined animal feedlots)
over the entire Mississippi River basin, which drains 40 percent of the land area
of the continental United States (Christen,  1999).
     The series of locks  and dams and maintained navigation channel have been
an integral physical feature of the Upper Mississippi River since the early 1930s
when the U.S. Congress  authorized the U.S. Army Corps of Engineers to main-
tain the river for navigation purposes. Concerns have been raised about the
disposal of dredged sediments, often contaminated with heavy metals and toxic
chemicals, to maintain the navigation channel and the loss of ecologically critical
backwater habitats to sediment deposits. The devastation caused by the Great
Flood of 1993 (Wahl et al., 1993) in the upper Midwest has also triggered debates
about the failure of flood control measures intended to protect river communities
from floods. As the key federal agency responsible for inland waterways, the
U.S. Army Corps of Engineers has initiated controversial studies to evaluate the
ecological impact of maintenance dredging, flood control structures, and widening
the series of locks and dams (Phillips, 1999).
                                                                                             12-19

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment


                         Evaluation of  Water  Quality  Benefits

                         Following  Treatment Plant  Upgrades

                             From a policy and planning perspective, the central question related to the
                         effectiveness of the secondary treatment requirement of the 1972 CWA is simply
                         Would water quality standards for DO be attained if primary treatment levels
                         were considered acceptable? In addition to the qualitative assessment of
                         historical data, water quality models can provide a quantitative approach to
                         evaluate improvements in dissolved oxygen and other water quality parameters
                         achieved as a result of upgrades to secondary and greater levels of wastewater
                         treatment. Since the 1970s, increasingly complex models have been developed to
                         determine wasteload allocation requirements for municipal and industrial discharg-
                         ers to meet the needs of decision-makers for the Upper Mississippi River.
                             During the mid-1970s the National Commission on Water Quality (see
                         NCWQ, 1976) funded Water Resources Engineers (WRE) to develop a steady-
                         state, one-dimensional water quality model (QUAL-II) of DO, BOD5, nutrients,
                         and fecal coliform bacteria using data collected in the Upper Mississippi River in
                         1964-1965 (FWPCA, 1966). The model was applied to evaluate the effectiveness
                         of the technology-based requirements of the 1972 Clean Water Act for municipal
                         and industrial dischargers. With funding available from the CWA Section 208
                         program, Hydroscience (1979) developed a water quality model (AESOP) of DO,
                         BOD5, nutrients, algae, and bacteria using data collected in 1973, 1976 and 1977.
                         The model, further validated by the Minnesota Pollution Control Agency using
                         data obtained in  1980, was used for a wasteload allocation study of the Metro
                         plant's impact on DO and un-ionized ammonia in Pool 2 (MPCA, 1981).
                             As a result of the severe algal blooms and fish kills that occurred in Lake
                         Pepin during the extreme drought of 1988, a time-variable water quality model
                         (WASP5-EUTRO5) of DO, BOD5, nutrients, and algae was developed using data
                         collected during  1988 (MWCC,  1989), 1990, and 1991 (EnviroTech, 1992,1993;
                         Lung and Larson, 1995). The validated model was used to evaluate alternatives
                         for phosphorus controls at the Metro plant and to perform a post-audit of the
                         Hydroscience (1979) AESOP model using low-flow data collected during 1988
                         (Lung,  1996a). The model was also applied to track the fate and transport of
                         phosphorus and the relative impact of the point and nonpoint sources on eutrophi-
                         cation in Lake Pepin (Lung, 1996b).
                              Following completion of the model by EnviroTech (1992,1993), a number of
                         uncertainty issues were identified related to (1) fate and transport of phosphorus
                         from point and nonpoint sources; (2) interaction of suspended solids with phospho-
                         rus transport; and (3) interaction of nonpoint source phosphorus inputs generated
                         under low-flow and high-flow hydrologic conditions with interannual variation in
                         the benthic release of phosphorus. To address these issues, a three-dimensional
                         hydrodynamic, sediment transport, and advanced eutrophication model was
                         developed and calibrated using data collected over 12 years from 1985 through
                         1996 (Garland et al., 1999; HydroQual, 1999a,  1999b). The calibrated model was
                         used to simulate the long-term (24-year) water quality response in the Upper
                         Mississippi River and Lake Pepin  to a number of alternative control scenarios
                         over a range of hydrologic (e.g., dry and wet years) and loading conditions for
                         point source and nonpoint source discharges of phosphorus.
12-20

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                                                        Chapter 12:  Upper Mississippi River Case Study
     To evaluate the incremental improvements in water quality conditions that
have been achieved by upgrading municipal wastewater plants from primary to
secondary and from secondary to advanced secondary levels of waste treatment,
Lung (1998) used the WASP5-EUTRO5 model developed by EnviroTech (1992,
1993) to demonstrate the water quality benefits attained by the secondary treat-
ment requirements of the 1972 CWA. Using the model, municipal and industrial
wastewater flow and effluent loading data were used with boundary flow and
loading data describing the Upper Mississippi River and Minnesota River to
compare water quality conditions for three summers (1964,  1976, and 1988)
characterized by comparable low-flow conditions and primary (1964), secondary
(1976), and advanced secondary (1988) levels of wastewater treatment at the
Metro plant. The model was applied to evaluate the water quality impact of three
different treatment levels for Metro and the other municipal plants: (1) primary,
(2) secondary, and (3) advanced secondary with nitrification. CBOD oxidation
rates were calibrated for each of these three different data  sets  to reflect differ-
ences in the proportion of labile and refractory oxidizeable material discharged
from the Metro plant.
     A comparison of the results of the model runs and observed data sets is
presented in Figure 12-17. Spatial distributions of CBOD-ultimate, ammonia-N,
nitrate+nitrite-N, algal chlorophyll, and DO are presented from St. Paul (UM
milepoint 840) to Lock & Dam No. 2 (UM milepoint 815) for 1964 (primary),
1976 (secondary), and 1988 (advanced secondary with nitrification). The upgrade
of the Metro plant from primary to secondary and the  corresponding reduction of
effluent BOD5 loading (see Figure 12-9) is reflected in the decrease in ambient
CBOD from a peak of approximately 20 mg/L in 1964 to approximately 7 to 8
mg/L in 1976 at UM milepoint 835 near the Metro plant. As shown in the simula-
tion results, the distributions of ammonia-N and nitrate+nitrite-N are similar under
the primary and secondary treatment scenarios because upgrading from primary
to secondary treatment does not change the effluent concentration of ammonia.
The progressive reduction in ambient ammonia-N and corresponding increase in
ambient nitrate+nitrite-N for the 1988 simulation, however, reflect the impact of
the upgrade from secondary to advanced secondary with nitrification and the drop
in effluent loading of ammonia-N at the Metro plant (see Figure  12-11). During
the 1960s when Metro discharged primary effluent, a large section of the river
was hypoxic or anoxic, with the worst conditions (< 2  mg/L) observed over
approximately 15 miles from UM milepoint 820 to UM milepoint 835. The ob-
served data and the model results indicate the elimination of anoxic conditions and
a nominal improvement in DO conditions under the extreme low-flow conditions
of August 1976. The minimum DO level is increased from approximately 0.5
mg/L in 1964 to approximately 2 mg/L in 1976 as a result of the  upgrade from
primary to secondary treatment. Even with secondary treatment at Metro,
however, compliance with the water quality standard for dissolved oxygen of 5
mg/L was not achieved and a distinct oxygen sag  is observed in  the 1976 data set.
Compliance with the DO standard was finally achieved, even under the extreme
drought conditions of 1988, after Metro was upgraded from secondary to ad-
vanced secondary treatment with nitrification.
     The model results demonstrate very clearly the progressive increase in DO
levels in the river following the upgrades at Metro to secondary and advanced
secondary treatment. The model results also demonstrate the ability of a well-
                                                                                             12-21

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
 25

' 15
 10
  S
         Primary Treatment
            Kd - 0.35 day''

            Xunfiltered
      0  835  830  825  820  815
*"••% *?.u
>2.5
1,2.0
f IS
| 1-0
? 0.5





°'$40 835 830 825 820 81
?2'5
E 2.0
S'-5
f 1.0
S-jO.5
i i j S

I It;
3

°A40 835 830 825 820 81
^200
oWO
I S0
> n

/~
—~-*~^

     40  835  830  825  820   815
    H
       Flow - 2170 cfs (August 1984)
       Temp - 25 .5 C
~    Secondary Treatment
| 20
                                                                      ^ .. Secondary w/ Nitrification
                                     -.J-1
                                     ~i
C
5-
i


i i • * *
I ^
i ^
I f
o
o
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4


a
                                     V50
                                     3/200
                                     2°150
                                     "100
                                       50 .
                                         40   835   830  825  820  815
                                              -*-
                                         140  835  830  825  820  815
                                     14
                                   ~ 12
                                     8
         835  830  825  820   815
                                        2
                                        $40
                                           835  830  825  820  815
      Upper Mississippi River Miles                Upper Mississippi River Miles
       Legend: { Observed Data (Average and Range)     —'— Model Results
                                       $40  835   830   825   820   815
                                            Upper Mississippi River Miles
Figure 12-17
Improvement in ultimate
CBOD, ammonia-N, and
DO levels in the Upper
Mississippi  River related to
Metro treatment plant
upgrades from  primary to
secondary and advanced
secondary with nitrification.
Source: Lung,  1998.
                         calibrated model to match observed water quality distributions that are directly
                         related to changes in effluent loading from Metro under the three different
                         treatment levels. The data used to define the effluent flow and loading character-
                         istics for the primary, secondary, and advanced secondary treatment levels for the
                         1964,1976, and 1988 simulations are given in Lung (1998). The data used to
                         define effluent flow and loads from the other municipal and industrial point
                         sources and the boundary inputs from the Upper Mississippi River and the
                         Minnesota River are summarized by WRE (1975) for 1964 and by EnviroTech
                         (1992,1993) for the 1976 and 1988 simulations. In generating the simulation
                         results for the three different treatment scenarios, all model coefficients, except
                         the CBOD oxidation rate, are based on the same numerical values for each of the
                         three model runs. The in-stream oxidation rate for CBOD is assigned different
                         values for primary (0.35 day1),  secondary (0.25 day"1), and advanced secondary
                         with nitrification (0.07 day1) since this kinetic reaction rate is dependent upon
                         stabilization of the effluent and the quantity of labile and refractory components of
                         oxidizeable organic matter in the effluent (Chapra, 1997; Thomann and Mueller,
12-22

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                                                    Chapter 12: Upper Mississippi River Case Study
1987). Using effluent loading rates that are representative of the three different
treatment levels for Metro, the model results confirm that the improvement in
water quality observed in the Upper Mississippi River can be attributed to invest-
ments in upgrading the Metro plant.
Impact of Wastewater Treatment:

Recreational and  Living  Resources

Trends

     Long-term trends in recreational uses, private investments along the
riverfront, and biological resources dependent on the integrity of aquatic ecologi-
cal conditions are meaningful nonchemical indicators of water quality conditions in
the Upper Mississippi River. One very simple indicator is the use of the river for
recreational boating. If water quality conditions are very poor, as was the case
during the 1950s and 1960s, the noxious conditions are not desirable for boating as
a recreational activity. If water quality is not degraded, the river might be consid-
ered desirable for boating. As shown in the long-term trend of recreational boat
traffic through Locks 1 through 4 of the river (Figure 12-18), annual recreational
vessel usage of the river ranged from approximately 25,000 vessels to approxi-
mately 30,000 vessels from the mid-1970s through the mid-1980s. Beginning in
the mid-1980s, the improvements in water quality in the Upper Mississippi River
suggest a strong correlation with the dramatic increase in annual recreational
vessel traffic on the river to approximately 45,000 to approximately 53,000 boats
(Erickson, 2000), with the recreational vessel traffic in Locks 1 through 4 increas-
ing by about two-thirds between 1986 and 1998 (Figure 12-18). Note that traffic
in 1993 dropped by about one-half because of the extreme flood conditions of that
year.
           60}
                  nun nil li
                1975
1980
                    Lock #1
1985
     Lock #2 [
1990
       Lock #3 j
1995
2000
         Lock #4
                                                                       Figure 12-18
                                                                       Recreational vessel traffic
                                                                       in Locks 1  through 4 of the
                                                                       Upper Mississippi River.
                                                                       Source: Erickson, 2000.
                                                                                      12-23

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
Figure 12-19
Recreational permit
applications  for Wabasha,
Dakota, Washington,
Goodhue, Pierce, and
Pepin counties along the
Upper Mississippi  River.
Source: Erickson, 2000.
    Docks
E3  Beach Improvement
El  Wildlife Improvement
D  Marinas
    Boat Houses
    Boat Ramps
D
                                         •81  '82   '83   '84  '85  '86   '87  '88  '89   '90  '91
                                                                Year
                               Recreational boats require marina space, and in 1990 about 2,700 new
                          marina slips were in various planning stages—enough to double marina capacity.
                          The number of permit applications received by the St. Paul District U.S. Army
                          Corps of Engineers for docks, marinas, boathouses, boat ramps, and beach and
                          wildlife improvements soared from only 3 in 1981 to 22 by 1989 (Figure 12-19). In
                          the late 1970s, nobody would have considered investing in a marina in Pool 2
                          because of poor water quality conditions in the vicinity of St. Paul. Apparently
                          related to improvements in water quality conditions, several marinas were pro-
                          posed and constructed for this area of the river beginning in the mid-1980s. Lake
                          City, located on Lake Pepin, for example, obtained a permit for a new marina in
                          1984; within a year, several hundred spaces were added for sailboats.
                               Increases in recreational uses of the river prompted eight agencies to form a
                          partnership agreement in 1990 to study recreational trends and resolve conflicts
                          over river and parkland use. The agencies included two park services, three state
                          DNRs, the U.S. Fish and Wildlife Service, the U.S. Army Corps of Engineers,
                          and the Minnesota-Wisconsin Boundary Area Commission.  They conducted a
                          study to sort out the issues, uses, and resource management conflicts related to
                          the rediscovery of the delights of a cleaned-up river by boaters, fishermen, and
                          hikers (MPCA, 1993).
                               Partly because of the ban on DDT, the establishment of wildlife reserves,
                          and reduced loadings of industrial pollutants from the pretreatment program,
                          populations of water birds have increased in the Upper Mississippi River. Per-
                          egrine falcons, bald eagles, mallard ducks, and great blue herons have been
                          observed in the Minneapolis-Saint Paul metropolitan area and in the floodplain
                          wetlands located on the Upper Mississippi River near the Metro plant. Black
                          crowned night herons have been observed feeding below the Ford Dam (Galli,
                          1992). Animals sensitive to the bioaccumulation of PCBs in their aquatic food,
                          such as fish-eating mink, are also making a comeback (Smith, 1992). The number
                          of great egrets and great blue herons nesting in Pig's  Eye Lake has increased
                          since the late 1970s and early 1980s, and cormorants  has been observed nesting
                          in the lake since 1983 (Galli, 1992) (Figure 12-20).
 12-24

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                                                         Chapter 12:  Upper Mississippi River Case Study
1 UUU -


800 -

600 -


400 -



200 -


n
- I -







[H Great Blue Herons

- D






i
•^
^
c
Great Egrets
H Cormorants



























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. , ...i— ..

I i
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KB
m
i
Bs
               63  64 65  73 78  79 80 81  82 83 84 86  87 88  91  92
                                        Year
in the lake since 1983 (Galli, 1992) (Figure 12-20).
     Electrofishing samples from Spring Lake, a backwater area affected by the
Metro plant, were collected in 1981, 1986, and 1991. These samples showed an
increase in the species diversity and the abundance of certain species (Gilbertson,
1992). The ecological quality of Spring Lake, as expressed by the Index of Biotic
Integrety (IBI) (Karr, 1981), has improved since the mid-1980s (Figure 12-21).
Species that have returned to Pool 2 include blue sucker and paddle fish; this is
particularly noteworthy because paddle fish had not been observed in Pool 2 since
the 1950s.
     As in many other urban waterways of the United States, detectable levels of
PCBs, a toxic organic chemical that adsorbs to sediment particles, have been
identified in fish tissue and sediments as a result of contamination from industrial
sources, transport of contaminated sediments, atmospheric deposition, storm
water runoff, and wastewater discharges. In 1975 PCB residues found in corn-
                                                                              Figure 12-20
                                                                              Colonial  bird nest counts
                                                                              for Pig's  Eye Lake.
                                                                              Source: Galli, 1992,
                                                                              Figure 12-21
                                                                              Fish survey results for
                                                                              Spring Lake, backwater to
                                                                              Pool 2, which receives
                                                                              discharges from the Metro
                                                                              wastewater treatment
                                                                              plant.
                                                                              Source: Gilbertson, 1992.
                    1981
1986
1991    Stream Quality
                                                                                               12-25

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
Figure 12-22
Lipid-normalized median
PCB concentrations in fillet
tissue (skin on) of 20-24.9-
inch carp from Pool  2 and
Pool 4 (Lake Pepin) of the
Upper Mississippi River,
1973-1988.
Source: Biedron and
Helwig, 1991.
1 -
Tissue PC
, , . S
w
s -
1 "
n-
































|^
I
1
1





n r
                                           1973-74 1975-76 1977-78 1979-80 1981-82 1983-84 1986-86 1987-88
                                                I Pool 2
|   | Pool 4 (Lake Pepin)
                         mon carp and other fish species taken from the Upper Mississippi River exceeded
                         the FDA action level of 5 mg/kg. The Minnesota Department of Health issued
                         fish consumption advisories for a number of species including common carp,
                         catfish, walleye, and smallmouth buffalo (MDH, 1998). Since the ban on produc-
                         tion of PCBs in 1979, the level of PCBs in fish tissue in the Upper Mississippi
                         River,  as well as in many other rivers and lakes in the United States, has been
                         declining. In the Upper Mississippi River, median PCB levels in common carp and
                         walleye dropped by over 80 percent during the period between 1975-1979 and
                         1988-1995. Dramatic decreases have been recorded in fish tissue levels of PCBs
                         from common carp collected in Pool 2 and Pool 4 (Lake Pepin) of the river. Lipid-
                         normalized median PCB concentrations have declined in Pool 2 from 121 ug/g in
                         1975-1976 to 18 ug/g in 1987-1988 and in Lake Pepin from 62 ug/g in 1973-1974
                         to 16 ug/g in 1987-1988 (Biedron and Helwig,  1991) (Figure 12-22). Low levels of
                         PCBs still persist, however, in fish tissue and other chemical pathways in the
                         aquatic environment, despite the PCB ban (Lee and Anderson,  1998).


                         Summary and Conclusions

                              As a result of strong state, local, and federal  legislative actions with over-
                         whelming public support, the cleanup of the Upper Mississippi River in the Twin
                         Cities  area is a national environmental success story. Comprehensive water
                         pollution surveys dating back to 1926 documented the magnitude of the problems
                         and provided the technical basis for the implementation of effective engineering
                         proposals for abatement of water pollution in the river. Since enactment of the
                         Clean Water Act in 1972, Minnesota has increased the water quality standard for
                         DO to 5 mg/L and invested in upgrades to obtain better-than-secondary levels of
                         wastewater treatment for the Metro plant and the other wastewater treatment
                         plants  operated by the MCES.
                              In contrast to the excessive effluent loading from the Metro plant during the
                         1960s, the investment in upgrades to the Metro plant during the 1980s, including
                         nitrification, have succeeded in reducing effluent discharges of BOD5 from 1968
12-26

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                                                        Chapter 12:  Upper Mississippi River Case Study
to 1998 by 95 percent (Figure 12-9), suspended solids from 1968 to 1998 by 95
percent (Figure 12-10) and ammonia-nitrogen from 1982-1998 by 90 percent
(Figure 12-11). As a direct result of these upgrades, compliance with water
quality standards for DO has been achieved even under the low-flow conditions
of the drought of 1988 (Lung, 1998). The accelerated program to separate storm
water and sanitary flow succeeded in achieving compliance with state standards
(200 MPN/100 mL monthly geometric mean and 2000 MPN/100 mL for indi-
vidual samples) for fecal coliform bacteria at the 71 percent level for samples
collected during 1996-1998. As a result of the industrial waste pretreatment
program initiated in 1982, the discharge of heavy metals to the Metro plant (and
the Upper Mississippi River) has been reduced by about 90 percent (MCES,
1999) and mercury loading from the Upper Mississippi River to Lake Pepin in
1990-1996 declined by almost 70 percent since the  1960s (Balogh et al., 1999).
Despite these significant improvements, MCES has targeted toxic chemicals (e.g.,
PCBs) and heavy metals (e.g., mercury) as contaminants of concern for monitor-
ing, identification of sources, and reduction of the load discharged to the river.
     In contrast to the degraded environmental conditions during the 1950s
through 1970s, the Upper Mississippi River is no longer a place to avoid. Parks,
trails, and marinas have been developed along, the river in areas where no one
would have considered making such investments in the 1970s. A thriving
riverfront corridor increases the value of both commercial and residential proper-
ties along the waterfront. The city of St.  Paul, for example, through the St. Paul
Riverfront Corporation, has invested nearly $500 million (as of the mid-1990s) for
land acquisitions and infrastructure development along the riverfront (Donlan et
al., 1995). In the late 1980s private developers began to respond to riverfront
infrastructure investments by obtaining more  than $7 million in tax increment
financing for development along the riverfront (Donlan et al., 1995). In addition to
private development, in December 1999 the Science Museum of Minnesota
completed a new museum along the riverfront in  St. Paul that features exhibits on
the Upper Mississippi River.
     The record clearly shows that the Clean Water Act of 1972 profoundly
affected every community in Minnesota, including the Twin Cities. The CWA
accelerated the cleanup of the Upper Mississippi River by providing federal funds
for the construction of new wastewater collection and treatment systems and the
upgrading of existing sewage treatment plants. Since the mid-1980s, the resur-
gence of mayflies and the record of greatly improved compliance with water
quality standards for dissolved oxygen and fecal coliform bacteria are key indica-
tors of the effectiveness of the water pollution control efforts accomplished by
state, federal, and local governments in the Twin Cities.
     By the end of 2005, the Metro plant will have implemented biological
removal of phosphorus to meet an annual effluent level of 1 mg/L for phosphorus
(MCES, 1998a). As of 1999 "BioP" had been successfully implemented in a
portion of the Metro plant and at suburban plants discharging to the Minnesota
River. Under the Metro Environment Partnership, the control of urban and rural
runoff will be addressed by a $7.5 million commitment from the MCES to reduce
pollution from the seven-county Twin Cities metropolitan region (MCES,  1998a).
State-of-the-art technology for solids processing, approved in July 1998, will
reduce mercury emissions by 70 percent along with other pollutants and odors
(MCES, 1998a). Further reductions in mercury discharges to the river from the
                                                                                             12-27

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment


                          Metro plant will be accomplished as a result of a partnership between the MCES
                          and the Minnesota Dental Association to test and evaluate new technologies to
                          filter dental amalgam from wastewater (MCES,  1998b, 2000).
                               Although significant accomplishments have been made to improve water
                          quality and ecological conditions in the Upper Mississippi River, continued invest-
                          ments are needed to address contemporary issues for continued restoration and
                          maintenance of the ecological integrity of the river. The designation of the Upper
                          Mississippi River as an American Heritage River in July 1998 recognizes both the
                          significant environmental improvements that have been accomplished and the
                          continuing need to address the key ecological issues identified in the 1990s. The
                          key water quality and resource management issues identified for the Upper
                          Mississippi River (USGS, 1999b) for the 21 st century include the following:
                                  Point and nonpoint source loading of nutrients, sediments, heavy metals,
                                  and toxic chemicals in the Minnesota River and Upper Mississippi
                                  River from agricultural and urban land uses.
                              •   Point and nonpoint source loading of nutrients and pesticides to aquifer
                                  systems from agricultural land uses.
                              •   Contamination of ground water with toxic chemicals from industrial
                                  activities and leachate from landfills.
                              •   Contamination of surface waters and  ground water in areas character-
                                  ized by rapid urbanization.
                              •   Degradation of biological communities by riparian and bottom habitat
                                  losses, river channel modifications, construction of locks and dams,
                                  increasing backwater sedimentation rates and loss of wetlands, effects
                                  of reservoir operations on fisheries, and eutrophication.
                              •   Contamination of bottom sediments in the river with toxic chemicals
                                  and subsequent benthic  release and bioaccumulation of toxic sub-
                                  stances within the aquatic food chain.
                               Water quality in the Upper Mississippi River, as measured by indicators
                          presented in this chapter  such as DO, ammonia, fecal coliform bacteria, and
                          sediment levels of mercury, has improved greatly since the 1960s and 1970s as a
                          result of upgrades to wastewater treatment plants required by the 1972 CWA.
                          Despite these improvements, contaminant loading from municipal (nutrients) and
                          industrial (heavy metals,  toxic chemicals) dischargers and  runoff from urban
                          (heavy metals) and agricultural (nutrients, pesticides, sediments) watersheds
                          continue to adversely affect the ecological integrity of the Upper Mississippi
                          River. In addition to chemical inputs to the river, the Upper Mississippi River
                          Conservation Committee has warned that the ecosystem of the Upper Mississippi
                          River is threatened by structural alterations of the river such as  continued stream
                          channelization, flood control levees that separate the river from the floodplain, and
                          the proposed expansion of the commercial navigation infrastructure (UMRCC,
                          1994). If the current ecological benefits are to be maintained and degraded
                          ecological conditions restored, an ongoing effort will be needed to maintain
                          environmental monitoring and research programs to document the status and
                          trends of the Upper Mississippi River to provide the scientific data needed for
                          effective resource management decisions (USGS, 1998).
12-28

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                                                       Chapter 12: Upper Mississippi River Case Study
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Berner, E.K., and R.A. Berner.   1996.  Global environment water, air and
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                                                                                            12-31

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment


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                              and conflict. The Washington Post, Business Section, pp. H1-H8.
                         Rabelais, N., R.E. Turner, D. Justic, Q. Dortch, W.J. Wiseman, Jr., and B.K. Sen
                              Gupta. 1996.  Nutrient changes in the Mississippi River and system re-
                              sponses on the adjacent continental shelf. Estuaries 19: 386-407.
                          Smith, S. 1992. U.S. Fish and Wildlife Service, Fort Snelling Office. Personal
                              communication, September 14,1992.
                         Thomann, R.V., and J.A. Mueller.  1987.  Principles of surface water quality
                              modeling and control. Harper & Row Publishers, New York, NY.
                          Vitousek, P. et al.  1997. Human alterations of the global nitrogen cycle:  sources
                              and consequences. Ecol.  Applic. 7(3): 737
                          UMRCC.  1994.  Facing the threat: An  ecosystem management strategy for
                              the Upper Mississippi River system. Upper Mississippi River Conservation
                              Committee, Rock Island, IL. January.
                          USDOC.  1998.  Census of population and  housing. U.S. Department of
                              Commerce, Economics and Statistics Administration, Bureau of the Census -
                              Population Division, Washington, DC.
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                                                       Chapter 12: Upper Mississippi River Case Study
USEPA (STORET), STOrage and RETrieval Water Quality Information System.
     U.S. Environmental Protection Agency, Office of Wetlands, Oceans, and
     watersheds, Washington, DC.
USGS.  1998.  Ecological status and trends of the Upper Mississippi River
     System 1998: A  report of the Long Term Resource Monitoring Program.
     Press release "Old Man River Gets Health Checkup." U.S. Geological
     Survey, Biological Resources Division, Upper Midwest Environmental
     Sciences Center. .
USGS. 1999a. Mississippi River at St. Paul, MN (05331000). U.S. Geological
     Survey, National Water Information Service (NWIS-W).  Daily flow data,
     Minnesota NWIS-S. . Summary statistics of
     streamflow from USGS Water Resources in Minnesota. <:http://
     wwwmn.cr.usgs.gov/umis/descript 1 .html>.
USGS.  1999b. Upper Mississippi River National Water Quality Assessment
     Study, Study Unit Description, General Information. U.S. Geological
     Survey. USGS Water Resources in Minnesota, .
USPHS.   1951.  Upper Mississippi drainage basin: A  cooperative state-
    federal report  on water pollution. NTIS No. PB-215-584. Federal Secu-
     rity Agency, U.S. Public Health Service, Chicago, IL.
USPHS.   1953.  Upper portion Upper Mississippi River drainage basin:  A
     cooperative State-Federal report on water pollution. NTIS No. PB-215-
     864.  Water Pollution Series No. 57, U.S. Public Health Service, Chicago,
     IL.
Wahl, K.L., K.C.Vining, and GJ.Wiche. 1993. Precipitation in the Upper Missis-
     sippi River Basin, January 1 through July 31,1993: Floods in the Upper
     Mississippi River Basin, 1993. U.S. Geological Survey Circular 1120-B,  U.S.
     Department of the Interior, U.S. Geological Survey, Denver, CO.
Wolman, M.G. 1971. The Nation's rivers. Science 174: 905-917.
WRE.  1975.  Water  quality analysis of the Upper Mississippi River Basin.
     NTIS No. PB-250-982, Tech. Report prepared by Water Resources Engi-
     neers for National Commission on Water Quality, Washington, DC.
Zwick, D., and M. Benstock.  1971. Water wasteland: Ralph Nader's Study
     Group report on Water Pollution. Grossman Publishers, New York, NY.
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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
 12-34

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  Chapter  13
Willamette
River
Study
    The Pacific Northwest
basin, covering a drainage
area of 277,612 square miles,
includes the "mighty" Columbia
River. Based on its annual discharge
(262,000 cfs, 1941 -1970), the Columbia is
the second largest river in the continental United
States (Iseri and Langbein, 1974). With a length of 270
miles, a drainage area of 11,200 square miles, and a mean
annual discharge of 35,660 cfs (1941-1970), the Willamette River
is the 15th largest waterway in the United States ranked on the basis
of annual discharge (Iseri and Langbein, 1974). Figure 13-1 highlights
the location of the Willamette River case study watersheds (catalog
units) identified in the Pacific Northwest basin as major urban-industrial
areas affected by severe water pollution problems during the 1950s and
1960s (see Table 4-2). In this chapter, information is presented to charac-
terize long-term trends in population, municipal wastewater infrastructure and
effluent loading of pollutants, ambient water quality, environmental resources, and
uses of the Willamette River. Data sources include USEPA's national water
quality database (STORET), published technical literature, and unpublished
technical reports ("grey" literature) obtained from local agency sources.
    The Willamette River extends for 270 miles from its headwaters in the
southern Cascade Mountains in Douglas County, Oregon, to the city of Portland,
Oregon, where it meets the tidal Columbia River (Figure 13-2) (Iseri and
Langbein, 1974). More than two-thirds of Oregon's population lives within the
major urban centers that have developed in the valley. The basin provides exten-
sive natural habitat for fish and wildlife and supports a prosperous economy based
on agriculture, timber and wood products, and recreation.
Figure 13-1
Hydrologic Region 17 and
Willamette watersheds.
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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
                                        124°
                                                        123°
                                                                       122°
Figure 13-2
Location map of
Willamette River Basin.
River miles shown are
distances from the
confluence of the
Willamette River with the
Columbia River at
Portland, OR.
46°
                                   45°
                                   44C
                                              IN
                                             A
                                                    46°
                                                                                      45°
                                                                                       44°
                                       124°
                                                        123°
                                                                        122°
                              The Willamette River was once one of the Nation's most grossly polluted
                         waterways because of raw sewage discharges and inadequate levels of municipal
                         and industrial waste treatment. Since the late 1920s, when a survey found that
                         nearly half of the citizens of Portland were in favor of antipollution laws, public
                         opinion in Oregon has strongly favored regulatory controls on waste discharges to
                         clean up the Willamette River. As a result of strong legislative actions with
                         overwhelming public support, the cleanup has become a major national environ-
                         mental success. In particular, Oregon's legislative actions mandating a minimum
                         level of secondary waste treatment have played an important role in restoring the
                         ecological balance of the Willamette.


                         Physical  Setting and  Hydrology

                              With a watershed of 11,200 square miles, the Willamette River basin in
                         northwestern Oregon is bounded by the Coast (west) and Cascade (east) moun-
                         tain ranges which have a north-south length of 150 miles and an east-west width
                         of 75 miles (Figure 13-2). Elevations range from less than 10 feet at the mouth
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                                                             Chapter 13:  Willamette River Case Study
Table 13-1. Physical characteristics of Willamette River at 6,000 cfs.
Source: Rickert et ai, 1976.
Reach
Upstream
Newberg Pool
Tidal
Length
(miles)
135.0
25.5
26.5
Average
Velocity
(cm/sec)
60
8
3
Travel
Time
(days)
2.8
3.9
10.0
near the Columbia River to 450 feet in the valley near Eugene to greater than
10,000 feet in the headwaters of the Cascade mountain range. Physical transport
in the river can be described in terms of three distinctive physiographic reaches
and characterized by the key physical parameters that strongly influence water
quality—length, summer low-flow velocity, and travel time (Table 13-1). The
longer travel time in the tidal portion of the Willamette River (10 days) can lead to
decreased  water quality.
     Seasonal variation in the river flow is the result of the region's heavy winter
rains and spring snowmelt from November through March. Low-flow conditions
occur during the summer months of July through September, with the seasonal
minimum occurring during August. Based on data from 1940-1990, monthly
average flows range from 6,246 cfs in August to 48,060 cfs in January (Figure
13-3). Before 1953, the natural summer low flow ranged from 2,500 cfs to 5,000
cfs at Salem. Since  1953 flow augmentation by 14 U.S. Army Corps of Engineers
(USAGE) reservoirs has been used to maintain a summer low flow of about 6,000
cfs at Salem (Mines et al.,  1976) (Figure 13-4).
                                                                           Figure 13-3
                                                                           Monthly variation of flow of
                                                                           the Willamette River at
                                                                           Salem, Oregon (Gage
                                                                           #14191000), 1951-1980.
                                                                           Source: USGS, 1999.
                       ONDJFMAMJJAS
                                                                                             13-3

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
Figure 13-4
Long-term trends of
summer flow of the
Willamette River at Salem,
Oregon (Gage
#14191000), July-
September.
Source: USGS, 1999.
                                                                                        2.00
                                -1.50
                                     CO
                                     DC
                                              1950
1960      1970     1980     1990
                                -1.00
                                                                                       -0.50
                                                                                        0.00
                                          	90%ile
                  mean & ratio
                          Population, Water, and  Land  Use  Trends

                              Because of abundant natural resources, the river has played a key historical
                          role in the agricultural and industrial development of the valley. The Willamette
                          River, a major source for the basin's municipal (20 cities) and industrial (600
                          facilities) water supply, also provides irrigation water for the rich fruit and veg-
                          etable farms of the valley. Other major uses include commercial navigation,
                          hydroelectric power production, commercial and recreational fisheries, and water-
                          based recreational activities, including aesthetic enjoyment of the  Greenway Trail
                          along the length of the river. As the region has grown, the river has also been
                          used—and misused—for municipal and industrial waste disposal, including the
                          disposal of wastewater generated by the pulp and paper industry since the 1920s.
                              Oregon's three largest cities—Salem, Portland, and Eugene—with a total
                          population of 1.8 million (nearly 70 percent of the state's population) are within
                          the Willamette River basin. The population of the basin has steadily increased
                          since World War II. With a significant wood products and agricultural economy,
                          the Willamette basin accounts for about 70 percent of the total industrial produc-
                          tion of Oregon. Industrial production, like the population of the basin, has steadily
                          increased over the past several decades.
                              The Willamette River case study area includes a number of counties identi-
                          fied by the Office of Management  and Budget (OMB) as Metropolitan Statistical
                          Areas (MSAs) or Primary Metropolitan Statistical Areas (PMSAs). Table 13-2
                          lists the MSAs and counties included in this case study. Figure 13-5 presents long-
                          term population trends (1940-1996) for the counties listed in Table 13-2. From
                          1940 to 1996 the population in the area more than tripled (Forstall, 1995; USDOC,
                          1998).
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                                                              Chapter 13: Willamette River Case Study
   Table 13-2.  Metropolitan Statistical Area (MSA) counties in the Willamette River
   case study. Source: OMB, 1999.
         Portland-Salem, OR-WA CMSA
          Clackmas,  OR
          Columbia, OR
          Multnomah, OR
          Washington, OR
          Yamhill, OR
Clark, WA
Marion, OR
Polk, OR

Corvallis, OR MSA
 Benton, OR
           2,
                                                                            Figure 13-5
                                                                            Long-term trends in
                                                                            population in the
                                                                            Willamette River Basin.
                                                                            Sources: Forstall, 1995;
                                                                            USDOC, 1998.
           0.'
                   1940   1950   1960   1970   1980   1990   1996
Historical  Water  Quality Issues

     In the early 1920s, the Oregon Board of Health determined that the Lower
Willamette River near Portland was grossly polluted as a result of raw waste
discharges from municipal and industrial sources. In 1927, the Portland City Club
declared the Willamette "ugly and filthy" with "intolerable" conditions. The first
comprehensive water quality survey in 1929 found severely declining oxygen
levels downstream of Newberg with an estimated concentration of 0.5 mg/L at
the confluence with the Columbia River. Not surprisingly, bacteria levels were
also found to be significantly increased downstream of each major city along the
river. Industrial disposal from pulp and paper mills had resulted in extensive
bottom sludge deposits that frequently surfaced during summer low-flow condi-
tions as noxious, unsightly floating mats of sludge. By 1930 the municipal waste
from the 300,000 inhabitants of Portland flowed untreated into Portland Harbor,
resulting in severe oxygen depletion during the summer (Oregon State Sanitary
Authority, 1964;Gleeson, 1972).
     During the 1950s Kessler Cannon, a state official, described the Willamette
River from Eugene to the Columbia River as the "filthiest waterway in the
Northwest and one of the most polluted in the Nation." Gross water pollution
conditions resulted in high bacteria counts, oxygen depletion, and fish kills (e.g.,
Gleeson and Merryfield, 1936; Merryfield et al., 1947; Merryfield and Wilmot,
1945). Cannon recounted the noxious conditions in the Willamette: "As the
                                                                                             13-5

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment


                         bacteria count rose, oxygen levels dropped—to near zero in some places. Fish
                         died. The threat of disease put a stop to safe swimming. Rafts of sunken sludge,
                         surfacing in the heat of summer, discouraged water-skiing and took the pleasure
                         out of boating" (Starbird and Georgia, 1972). In 1967 the Izaak Walton League
                         described the Lower Willamette River as a "stinking slimy mess, a menace to
                         public health, aesthetically offensive, and a biological cesspool" (USEPA, 1980).


                         Legislative and  Regulatory  History

                              After more than a decade of public concern about the polluted conditions of
                         the Willamette River, the citizens of Oregon passed a referendum in 1938 setting
                         water quality standards and establishing the Oregon State Sanitary Authority.
                         With the establishment of the Sanitary Authority, it became Oregon's public policy
                         to restore and maintain the natural purity of all public waters. As a result of
                         regulatory actions by the Sanitary Authority, all municipalities discharging into the
                         Willamette implemented primary treatment during the period from 1949 to 1957,
                         with all costs borne by the municipalities. Beginning in 1952 industrial waste
                         discharges from the pulp and paper mills were  controlled by required lagoon
                         diversions during summer months. In 1953 the new USAGE dams began to
                         operate, resulting in augmentation of the natural summer low flow. Although not
                         originally planned for water quality management, summer reservoir releases have
                         become a significant factor in maintaining water quality and enabling salmon
                         migration during the fall.
                              Although tremendous accomplishments had been made in controlling water
                         pollution in the Willamette basin, large increases in industrial production and in the
                         population served by municipal wastewater plants exceeded the assimilative
                         capacity of the river. By 1960 the Sanitary Authority required that all municipali-
                         ties discharging to the Willamette River achieve a minimum of secondary treat-
                         ment (85 percent removal of BOD5). In 1964 the pulp and paper mills were
                         directed to implement primary treatment, with secondary treatment during the
                         summer months. In 1967, industrial secondary treatment was required on a year-
                         round basis. The Sanitary Authority had thus established a minimum policy of
                         secondary treatment for all municipal and industrial waste dischargers with the
                         option of requiring tertiary treatment if needed to maintain water quality. The state
                         initiated the issuance of discharge permits for  wastewater plants in 1968, 4 years
                         before the 1972 CWA established the National Pollutant Discharge Elimination
                          System (NPDES). The policy adopted in 1967 remains  the current water pollution
                         control policy of the state of Oregon for the Willamette River (ODEQ,  1970).
                              In response to the 1965 Federal Water Quality Act, Oregon established
                         intrastate and interstate water quality standards in 1967 that were among the first
                         new state water quality standards to be approved by the federal government. The
                          1972 CWA provided even further authority for Oregon  to issue discharge permits
                          limiting the pollutant loading of municipal and industrial facilities.
                              From 1956 to 1972, Federal Construction Grants to Oregon totaled $33.4
                         million for municipal wastewater facilities (CEQ, 1973). Since 1974 the cities of
                          Salem, Corvallis, and Portland have received Construction Grants under the 1972
                          CWA to  build and upgrade secondary waste treatment facilities.
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                                                           Chapter 13:  Willamette River Case Study
Impact of Wastewater Treatment:

Pollutant  Loading and  Water

Quality  Trends

     As a result of the stringent regulatory requirements for municipal and
industrial waste treatment, total pollutant loading has decreased substantially over
the past 30-40 years (Figure 13-6) while total wastewater flow has increased
over the same period. By 1972, when the CWA was passed, the total oxygen
demand of wastewater discharges to  the Willamette had been decreased to 25
percent of the demand of the pollutant load discharged in 1957 (CEQ, 1973).
Following the implementation of basinwide secondary treatment for municipal and
industrial wastewater sources, water quality model budgets have shown that
about 46 percent of the oxygen demand in the Willamette River during the critical
summer months results from upstream nonpoint source loads from rural tributary
basins. The remaining half of the total oxygen demand is accounted for by
municipal (22 percent) and industrial (32 percent) point source loads (Rickert and
Mines, 1978).
     Severe summer oxygen depletion has been the key historical water quality
problem in the Willamette River. Over the past 20 years, however, summer
oxygen levels have increased significantly as a result of (1) the implementation of
basinwide secondary treatment for municipal and industrial point sources and
(2) low flow augmentation from reservoir releases. Based on data obtained from
the earliest water quality survey in 1929 to the most recently available monitoring
programs, the dramatic improvements in summer oxygen levels in the river are
clearly shown in the  spatial distribution of oxygen from Salem to Portland Harbor
(Figure 13-7) and the long-term historical trend for oxygen in the lower Willamette
River near Portland Harbor (Figure 13-8). These historical data sets document
the grossly polluted water quality conditions that existed prior to implementation of
a minimum level of secondary treatment for municipal and industrial discharges to
the river.
       700
         1940
                                 Year
                     I Municipal
Mun + Industrial
                                                                        Figure 13-6
                                                                        Long-term trends in
                                                                        municipal and industrial
                                                                        effluent BOD5 loading to
                                                                        the Willamette River.
                                                                        Source: Gleeson, 1972;
                                                                        ODEQ, 1970.
                                                                                        13-7

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
Figure 13-7
Long-term trends in the
spatial distribution of DO in
the Willamette River.
Source: Rickert, 1984.
-80
                                                           -60        -40
                                                        Miles from Columbia River
-20
Figure 13-8
Long-term trends  in
summer DO in the Lower
Willamette River at
Portland, OR, for RF reach
17090012017 (mile 0-
15.7).
Source:  USEPA (STORET).
                                               '1950' ' " ' ' 'I'g'eb'	1970      1980
                                                     Portland - Milwaukie OR (Mile 0-15.7)
                                      1990
                               Although the current status of the river is visibly much improved and water
                          contact sports and salmon migration are once again possible in most of the river,
                          there are still concerns about the levels of toxic contamination. Oregon's 1990
                          water quality status assessment report (ODEQ, 1990a) classified the river as
                          "water quality limited" as a result of seven contaminants exceeding USEPA draft
                          sediment guidelines (arsenic, chromium, lead, zinc, and DDT), state water quality
                          standards (arsenic), or both (2,3,7,8-TCDD). Surveys have found levels of toxic
                          chemicals in water, sediments, and fish tissue at various locations in the river
                          basin (ODEQ, 1994). Surveys conducted by ODEQ in 1994 indicated that levels
                          of metals (arsenic, barium, cadmium, chromium, copper, lead, mercury, nickel,
                          silver, and zinc), pesticides (chlordane and DDT), other organic chemicals (carbon
                          tetrachloride, creosote, dichloroethylene, dioxin, PAHs, PCBs, phenol, pentachlo-
                          rophenol, phenanthrene, phthalates, trichloroethane, trichloroethylene, and
                          trichlorophenol), and bacteria exceed regulatory or guidance criteria for the
                          protection of aquatic life and human health in at least one location of the river.
                               As a result of these findings, in 1990 the Oregon legislature directed ODEQ
                          to develop a comprehensive study that would generate a technical and regulatory
                          understanding and an information base on the river system that could be used to
                          protect and enhance its water quality. To meet this directive, ODEQ developed
                          and implemented a comprehensive, multiphase investigation known as the
                          Willamette River Basin Water Quality Study (WRBWQS) (ODEQ, 1990b; Tetra
                          Tech, 1995).
 13-8

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                                                             Chapter 13: Willamette River Case Study
 Impact of Wastewater Treatment:

 Recreational  and Living  Resources

 Trends

     The first comprehensive study of the Willamette River biota was conducted
 by Dimick and Merryfield (1945) in the summer of 1944. Their study was specifi-
 cally intended to assess the impact of water pollution on fish and benthic inverte-
 brates in the river. Benthos are particularly good indicators of long-term trends in
 water quality because most benthic species are sedentary and have long life
 spans. Their state of health is therefore a gauge of both past and present water
 quality. Reactions to even occasional toxic discharges are measurable as vari-
 ances in the species assemblages of benthic invertebrates. For pollution studies,
 benthos are divided into three categories: (1) intolerant species (e.g., stoneflies,
 mayflies, caddisflies) are indicative of good water quality because of their inability
 to survive in or tolerate low DO concentrations; (2) facultative species are
 indicative of a transition between good and poor water quality because they can
 survive under a wide range of DO conditions; and  (3) tolerant species (e.g.,
 sludgeworms), which are adapted to low DO levels, become dominant where
 poor water quality is prevalent.
     Dimick and Merryfield (1945) found very different biological conditions in
 different stretches of the river. Upstream of Salem, where pollutant sources to the
 river were few, they found an abundance of healthy fish and populations of
 intolerant caddisfly, mayfly, and stonefly nymphs (Figure 13-9). From below
 Salem to Portland, where pollutant loadings to the river were greatest, they found
 few to no fish, dead fish in or on the banks of the river, and a total absence of
 stoneflies and mayflies. They further noted that the biomass of insect larvae
 downstream of Salem was less than that upstream, and that largemouth bass
 collected below Salem were generally smaller than  normal and in poor physical
 condition. Both of these conditions are indicative of poor water quality.
                                                                          Figure 13-9
                                                                          Spatial distribution of
                                                                          tolerant and  intolerant
                                                                          benthic organisms in the
                                                                          Willamette River upstream
                                                                          and downstream of
                                                                          municipal waste
                                                                          discharges in 1945.
                                                                          Source: Dimick and
                                                                          Merryfield, 1945.
                         SB    WF     NE    OC
                         Location on Willamette River
PO
SA=Salem (1 mile above city); SB=Salem (2 miles below city); WF=Wheatland Ferry; NE=Newberg
(0.8 miles above city); OC=Oregon City (above and below Willamette Falls); PO=Portland (0.3 miles
upstream of Sellwood Bridge)
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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment


                              Dimick and Merryfield attributed the poor biological condition below Salem
                          to the effects of pollution, but it is uncertain whether fish were directly affected or
                          whether their populations were diminished because of the lack of their inverte-
                          brate foodstuffs (Dimick and Merryfield, 1945). Regardless, the study demon-
                          strated that pollution was a major factor in the decline of the river's commercial
                          and sport fisheries.
                              In 1983 the study was repeated to assess the changes that had occurred in
                          the river since its cleanup began. Hughes and Gammon (1987) sampled the same
                          sites that Dimick and Merryfield had sampled in 1944. Although the 1983 study
                          showed some signs of a pollution-stressed river below Salem, the differences
                          between the findings of the studies demonstrated a marked improvement in water
                          quality. Where Dimick and Merryfield had found only tolerant species associated
                          with sluggish, warm water and muddy or sandy substrates, Hughes and Gammon
                          found many intolerant species suited to fast-moving, cold water and rubble and
                          gravel bottoms.
                              The improvements in the fish communities of the Willamette River between
                          1944 and 1983  (Figure  13-10) were not solely due to water quality improvements.
                          Historically, the river provided important spawning and nursery grounds for
                          salmon and steelhead, but dams built along the river prevented these fish from
                          reaching their spawning grounds.  Corrections to this situation have accompanied
                          water quality improvements. Fish ladders have been built at dams, and four large
                          fish hatcheries have been put into operation, producing 3.8 million salmon per year
                          (Bennett, 1991). The dams also provide flow augmentation during autumn low-
                          flow periods, thereby providing faster moving, oxygenated water to running fall
                          chinook salmon (Starbird and Georgia, 1972).
                              Water quality has  nevertheless played an important role in the survival and
                          return of both natural-born and hatchery-reared salmon in the Willamette River. In
                          1965 only 79 chinook salmon were counted in the fall run. That number increased
                          to 5,000 in 1971 (Starbird and Georgia, 1972). A record high of 106,300 spring
                          chinook salmon were counted in the 1990 run, up 30 percent from the 1985-1989
                          average of 81,900. The 1990 catch of chinook salmon of 27,700 was 39 percent
                          greater than the 1980-1989 average of 20,000 (Bennett, 1991). With the recent
                          and continuing  population growth in the Portland area (where most of the salmon
                          are caught) and water quality improvements, interest in angling in the river has
                          increased dramatically.  The Willamette River is once again able to support
                          important commercial and recreational fisheries.
Figure 13-10
Long-term trends of spring
chinook salmon runs.
Source: Bennett, 1991.
• Annual Catch  	10-Year Average

                                                          1960      1970       1980       1990
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                                                              Chapter 13:  Willamette River Case Study
Summary  and  Conclusions

     The cleanup of the Willamette River has been accomplished because of
overwhelming public support; strong commitment by federal, state, and local
governments; comprehensive water quality studies that documented the extent of
the problems; and the implementation of sound engineering proposals for control-
ling water pollution. Public pressure and responsive political leadership have
resulted in the basinwide implementation of secondary treatment requirements
with a minimum of legal actions needed to ensure compliance with the regula-
tions. Water quality studies of the Willamette (e.g., Rickert,  1984; Rickert et al.,
1976) have demonstrated the importance of the minimum requirement of second-
ary waste treatment for municipal and industrial dischargers, as well as the
significance of background water quality and summer low-flow augmentation
from USAGE reservoirs, in achieving Oregon's water quality goals.
     Vast improvements in the water quality of the Willamette River, facilitated
by stringent regulatory controls, have led to remarkable improvements in the
integrity of the river's biological communities. Of major importance, both
recreationally and economically, is the continuing recovery of the fisheries.
Salmon and steelhead on their migratory spawning runs are no longer precluded
from reaching their spawning grounds in the Willamette River basin because of
severely depressed or nonexistent concentrations of DO. Recreational anglers are
once again able  to enjoy pursuing these valuable gamefish as the fish make their
way up the river to their spawning grounds. Another significant improvement is
the return of viable populations of resident species of gamefish, including bass,
catfish, perch, sturgeon, and crappies.
     Although the severe water quality problems that have plagued the
Willamette River in the past are clearly gone, there are  still reasons for concern
about the river's overall health (Tetra Tech, 1995). Until the continued presence
of toxic contaminants in the water and sediments, the loads of suspended sedi-
ment and nutrients, and the alteration of the habitat can be abated, the overall
ecological conditions of the Willamette River will continue to suffer.
     For four decades beginning in the 1920s the Lower Willamette River near
Portland, Oregon, was considered one of the most polluted urban-industrial rivers
in the United States. In 1927 the Portland City Club declared the Willamette River
"ugly and filthy...with intolerable conditions."  During the 1950s the Willamette
River was described as the "filthiest waterway in the Northwest and one of the
most polluted in the Nation." In 1967 the Izaak Walton League described the river
as a "stinking slimy mess, a menace to public health, aesthetically offensive and a
biological cesspool."
     Three decades after enactment of strict water pollution control regulations
by the state of Oregon in the late 1960s and the federal Clean Water Act in 1972,
the remarkable improvements in water quality and the ecological health of the
river now provide important recreational and commercial benefits to the citizens
of the Willamette valley. Salmon and steelhead fisheries, once blocked by dams
without fish ladders and constrained by low dissolved oxygen conditions, are now
sustained by migratory populations that can safely reach upriver spawning
grounds. The local economies of major cities on the Willamette River are thriving,
and upscale developments are attracted to riverfront locations by the aesthetics of
a clean river that was once considered noxious with an unsightly riverfront.
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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment


                         Although the gross water pollution problems of the first half of the 20th century
                         have been eliminated, nutrient enrichment, sediment loading, and the lingering
                         presence of toxic chemicals in the river, sediment bed, and biota are ecological
                         problems that remain. Hopefully, they will be addressed in the early decades of
                         the 21 st century.


                          References

                         Bennett, D.E.  1991.  1990 Willamette River spring Chinook salmon  run.
                              Oregon Department of Fish and Wildlife, Columbia River Management.
                              November.
                         CEQ.  1973. Chapter 2 in Cleaning up the Willamette. Fourth annual report on
                              environmental quality. Council on Environmental Quality, Washington, DC.
                         Dimick, R.E., and F. Merryfield.  1945. The fishes of the Willamette River
                              system in relation to pollution. Oregon State College Engineering Experi-
                              ment Station. Bulletin Series No. 20. June.
                         Forstall, R.L.  1995. Population by counties by decennial census: 1900 to
                              1990. Population Division, U.S. Bureau of the Census, Washington, DC.
                              .
                          Gleeson, G.W.  1972.  The return of a river, the Willamette River, Oregon.
                              Oregon State University, Corvallis, OR.
                          Gleeson, G.W., and F. Merryfield. 1936.  Industrial and domestic wastes of the
                              Willamette Valley. Engineering Experiment Station Bulletin No. 7.  Oregon
                              State Agricultural College, Corvallis, OR.
                          Hines, W.G., D.A. Rickert, and S.W. McKenzie.  1976.  Hydrologic analysis
                              and river quality data programs. U.S. Geological Survey Circular 715-D.
                              U.S. Department of the Interior, Arlington, VA.
                          Hughes, R.M., and J.R. Gammon.  1987.  Longitudinal changes in fish  assem-
                              blages and water quality in the Willamette River, Oregon. Trans. Am. Fish.
                              Soc. 116: 196-209.
                          Iseri, K.T., and W.B. Langbein.  1974.  Large rivers of the  United States.
                              Circular No. 686. U.S. Department of the Interior, U.S. Geological Survey,
                              Arlington, VA.
                          Merryfield, F., and W.G. Wilmot.  1945. 7945 progress report on pollution in
                              Oregon streams. Engineering Experiment Station Bulletin No. 19. Oregon
                              State University, Corvallis, OR.
                          Merryfield, F., W.B. Bollen, and F.C. Kachelhoffer.  1947.  Industrial  and city
                              wastes. Engineering Experiment Station Bulletin No. 22. Oregon State
                              University, Corvallis, OR.
                          ODEQ.  1970.   Water quality  control in Oregon. December. Oregon Depart-
                              ment of Environmental Quality, Portland, OR.
                          ODEQ.  1990a.  Oregon 1990 water quality status assessment report:  305(b)
                              report. Prepared for U.S. Environmental Protection Agency by Oregon
                              Department of Environmental Quality, Portland, OR.
                          ODEQ.  1990b.  Willamette River basin water quality study: Rationale for a
                              draft work plan. Oregon Department of Environmental Quality, Portland,
                              OR.
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                                                             Chapter 13: Willamette River Case Study
ODEQ.  1994.  Oregon's 1994 water quality status assessment report: 305
    (b)  report. Prepared for U.S. Environmental Protection Agency by Oregon
    Department of Environmental Quality, Portland, OR.
OMB. 1999.  OMB Bulletin No. 99-04. Revised statistical definitions of Metro-
    politan Areas (MAs) and Guidance on uses of MA definitions. U.S. Census
    Bureau, Office of Management and Budget, Washington, DC. .
Oregon  State  Sanitary Authority.  1964.  Report on water quality and waste
    treatment needs for the Willamette River. Division of the State Board of
    Health, Portland, OR. May.
Rickert,  D.A.  1984.  Use of dissolved oxygen modeling results in the manage-
    ment of river quality. J.  WPCF 56(1): 94-101.
Rickert,  D.A., W.G. Mines, and S.W. McKenzie.  1976.  Methodology for river
    quality assessment with application to the  Willamette River Basin,
    Oregon. U.S. Geological Survey Circular 715-M. U.S. Department of the
    Interior, Arlington, VA.
Rickert,  D.A., and W.G. Hines.  1978. River quality assessment: Implications of
    a prototype project. Science 200 (June 9, 1978): 1113-1118.
Starbird, E.A., and L.J. Georgia.  1972. A river restored: Oregon's Willamette.
    National Geographic 141(6):  816-835.
Terra Tech.  1995.  Willamette River basin water quality study: Summary and
    synthesis of study findings. Prepared for Oregon Department of Environ-
    mental Quality, Water Quality Division, Portland, OR, by Terra Tech, Inc.,
    Redmond, WA.
USDOC.  1998.  Census of population and housing. U.S.  Department of
    Commerce, Economics and Statistics Administration, Bureau of the Census -
    Population Division, Washington, DC.
USEPA.  1980.  National accomplishments  in pollution control: 1970-1980.
    U.S. Environmental Protection Agency, Office of Planning and Evaluation,
    Washington, DC.
USEPA  (STORET). STOrage and RETrieval Water Quality Information System.
    U.S. Environmental Protection Agency, Office of Wetlands,  Oceans, and
    watersheds, Washington, DC.
USGS.  1999. Streamflow data downloaded from the U.S. Geological Survey's
    National  Water Information System (NWIS)-W Data retrieval for historical
    streamflow daily values, .
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   Appendix A
Summary of Peer  Review
Team Comments and Study
Authors'  Responses
  The Peer Review Team consisted of the following individuals.
           Mr. Leon Billings
           Mr. Tom Brosnan, National Oceanic and Atmospheric Administration
           Mr. Michael Cook, U.S. Environmental Protection Agency
           Mr. John Dunn, U.S. Environmental Protection Agency
           Dr. Mohammad Habibian, Washington Suburban Sanitation Commission
           Dr. Leo Hetling, Public Health and Environmental Engineering, New York State Department
           of Environmental Conservation (retired)
           Dr. Russell Isaacs, Massachusetts Department of Environmental Protection
           Dr. Norbert Jaworski, U.S. Environmental Protection Agency (retired)
           Dr. William Jobin, Blue Nile Associates
           Mr. Ken Kirk, American Metropolitan Sewerage Association
           Mr. John Kosco, U.S. Environmental Protection Agency
           Mr. Rich Kuhlman, U.S. Environmental Protection Agency
           Mr. Joseph Lagnese
           Ms. Jessica Landman, National Resource Defense Council
           Mr. Kris Lindstrom, K.P. Lindstrom, Inc.
           Mr. Ronald Linsky, National Water Research Institute
           Dr. Berry Lyons, University of Alabama
           Dr. Alan Mearns, National Oceanic and Atmospheric Administration
           Dr. Daniel Okun, University of North Carolina
           Mr. Steve Parker, National Research Council
           Mr. Richard Smith, U.S. Geological Survey
           Mr. Phill Taylor, U.S. Environmental Protection Agency and Tetra Tech, Inc. (retired)
           Dr. Red Wolman, Johns Hopkins University
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                    Appendix A: Summary of Peer Review Team Comments and Study Authors' Responses


 EPA Instructions to  Peer Review Team for  Evaluation  of
 Draft Report Dated October  18,1998

     •   Feedback on accuracy and historical context of statements in the report.
     •   Evaluation of the reliability of the statistical techniques used to document "before and after" trends
        in dissolved oxygen.
     •   Have we overlooked any significant work in the literature relevant to the study?
     •   Have we missed anything in interpretations of "before and after" data in relation to the historical
        context of water pollution control activities in the United States?
     •   Has the study met the stated objective of identifying national-scale progress in water quality
        achieved as a result of EPA's investment in water pollution control infrastructure?
     The following key issues were identified in the responses received from 21 members of the Peer Review
 Team.  For each key issue, a summary of the major points raised by the members of the Peer Review Team is
 presented along with our responses  to  the issue and where the relevant information is presented in the final
 report.


 Key Issues Identified by Peer Review Team
     1.  Target audience
     2.  Title of final report and objectives of the study
     3.  Executive Summary
     4.  Use of oxygen as key indicator for "before and after" trends
     5.  Availability of monitoring data in STORET
     6.  How representative is oxygen data used for "before and after" trends?
     7.  Statistical methods
     8.  Geographic representation of case study sites
     9.  Cost versus benefits analysis
     10 . Editing for final  report
Issue 1: Target Audience
Reviewers:
   Linsky, Okun, Wolman, Hetling, Jobin, Isaacs, Parker, Billings , and Habibian
Comment summary:
     Who is the audience for the report? How can the report provide useful information to policy makers,
legislators,  regulatory agencies, and the general public? What is the overall message? How can the report be
structured to provide guidance for future water quality management programs? The report can be more than a
history; it can be an instrument for beneficial change. The report needs to clearly articulate the interrelat-
edness of the CWA and SDWA for water pollution control and water quality management in relation to both
public health (drinking water) and ecological quality of rivers and streams. The CWA and the secondary treatment

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment


requirement have demonstrated some water quality success over 25 years. Future and continued successes for the
next 25 years, however, are not a given unless national policies are based on a sustainable strategy driven by citizen
stakeholder groups (Jobin). O&M costs are high and it is very important (but not politically highly visible) to main-
tain levels of funding as are replacement costs of obsolete POTWs. Jobin discusses three "traps" that have
hampered long-term sustainability of past water pollution control efforts. He points out the need to present
strong conclusions as well as recommendations to guide future efforts.

Response:

     A discussion on the report audience has been included in Chapter 1 of the document. The primary
audience is the technical scientists and engineers who try to evaluate cause-effect relationships of pollutant
load and ambient water quality responses. The secondary audience is Congress, regulatory/policy profession-
als, and the informed public, who need to understand that a major public works program (the CWA Construc-
tion Grants and CWSRF programs) accomplished what it was designed to do—reduce BOD effluent loads from
municipal and industrial sources and improve dissolved oxygen in many previously degraded waterways of the
Nation. These same groups also need to understand that water pollution control efforts never end. The 1972 CWA
did not "solve" the problem; in fact, waste materials are generated continuously and effluent removal efficiencies
must increase in the future to compensate for population growth. Planning for O&M expenditures, as well as  capital
expenditures for replacement of obsolete facilities and upgrades to maintain adequate levels/efficiency of wastewa-
ter removal is an ongoing requirement. Chapter 2 and the Executive Summary include a projection analysis that
demonstrates that many of the gains in national water quality improvements may be lost if future wastewater
infrastructure capacity does not keep pace with expected urban population growth.
Issue 2: Title of Final Report and Objectives of Study

Reviewers:

     Landman, Hetling, Mearns, Kosco

Comment  summary:

     The title of the report, Progress in  Water Quality: An Evaluation of the Benefits of the 1972 Clean
Water Act, is too broad and implies too large a scope of study (i.e., we address all issues of the CWA). The
title needs to be changed to be more representative of the data presented in the study. The authors need to
state more clearly up-front that the study was designed to evaluate the effectiveness of investments in POTW
upgrades on improving oxygen levels in previously degraded waterways and nothing more. The caveat for the
analysis is that POTW sources are only one component of many possible sources of oxygen-demanding loads
to waterways. It is important to  get across the concept that improvements to POTWs alone are not sufficient
to restore and maintain water quality as a national goal. The study has demonstrated that upgrades to POTWs
had the expected result of improving oxygen levels in waterways once characterized by low levels. Can
changes in oxygen be isolated to the impact of POTW inputs alone? In this study the important contribution is
the findings of improvements in oxygen that are linked to POTW upgrades and investments—not the method-
ology.

Response:

      The title has been changed to Progress in Water Quality: An Evaluation of the  National Investment
in Municipal Wastewater Treatment. The objectives of the study are now clearly stated in Chapter 1 and the
Executive Summary. Also, Chapter 2 includes a section that compares POTW sources of BOD loading  to
other major source categories (industrial point sources,  CSOs, and urban and rural nonpoint sources) based on
EPA's NWPCAM. Statements have been added to stress that continued improvement in the Nation's water
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                     Appendix A: Summary of Peer Review Team Comments and Study Authors' Responses
quality conditions will require control of all major pollution sources, of which POTWs are only a portion.
(POTWs contribute about 21 percent of all point and nonpoint BOD sources nationwide.) In this document
both the findings and the data analysis methodology are given equal emphasis. A complete presentation of the
methodology allows the scientist or statistician to assess the level of rigor of the analysis, as well as demon-
strate the potential application of the methodology to other water pollution control performance measures.

Issue 3:  Executive Summary

Reviewers:

     Cook, Kirk, Landman, Dunn, Linsky, Brosnan, Kuhlman

Comment  summary:

     The Executive Summary is too long with too much defense of the methodology used for the analysis.
Most people, especially policy, regulatory, and general public, will read only the Executive Summary and not
care at all about (or understand) the technical details of how the analysis was performed. The key findings
need to be made very clear in a concise summary that in turn can be boiled down to a press release of a few
pages (which in turn can be boiled down to a "sound bite" and a "headline"). The Executive Summary needs a
discussion of the status of water quality nationwide in relation to all sources (synopsis of most recent national
water quality report to Congress?) The sequence of material presented in the Executive Summary should
follow the sequence presented in the main report. One suggestion is to publish only the Executive Summary
and put all the technical documentation of the main report on the EPA web site. The authors  need to present
strong conclusions (Isaacs, Hetling) as well as solid recommendations (Hetling).

Response:

     The Executive Summary has been entirely rewritten  as a high-quality, "stand-alone" document that
presents the key findings of the study succinctly and in the same sequence as the main report. Also, the main
body of the report has been reorganized and streamlined and includes an introductory chapter (Chapter 1,
which is a road map to the rest of the report) as well as a  summary and conclusions section at the end of each
chapter.

Issue 4:  Use of Dissolved Oxygen as Key Water Quality  Indicator for "Before and
After" Trends

Reviewers:

     Hetling, Parker, Linsky, Jobin, Dunn, Smith, Jaworski

Comment  summary:

     Some reviewers, but not all, agreed that oxygen was most appropriate for questions posed for the study.
One reviewer suggested that dissolved oxygen saturation should have been used as the indicator rather than
dissolved oxygen concentration.  The same reviewer also  brought up a variety of statistical questions about
the approach and the validity of the techniques used for the analysis of dissolved oxygen trends. The  review-
ers' consensus was that a more detailed rationale for the selection of dissolved oxygen as the key water
quality indicator used for the study was needed in the final report. The reviewers also recommended that a
better explanation of water quality standards for dissolved oxygen and the choice of 5 mg/L as  a benchmark
concentration for comparison of "before and after" conditions be included in the final report.  Some
reviewers suggested combining the discussion of factors affecting dissolved oxygen in rivers with the discus-
sion of pollutant loading.
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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment


Response:

     Dissolved oxygen is a key chemical measure that has been used for many decades to characterize the
overall health of aquatic ecosystems.  High concentrations (~5 mg/L) greater than about 60 percent saturation
levels are generally indicative of a healthy aquatic ecosystem whereas low concentrations (< 3 mg/L) less than
about 40 percent saturation may be indicative of a stressed ecosystem.  A large historical database with
generally reliable measurements is available with records for a few waterways since the 1920s and 1930s.
There is a well-understood causal relationship between municipal and industrial wastewater loading of oxidiz-
able carbonaceous and nitrogenous materials (BOD), receiving waters' streamflow, and ambient concentra-
tions of dissolved oxygen.  Excessive depletion of dissolved oxygen as a result of poorly treated wastewater
discharges was one of the major water pollution problems in many rivers and estuaries during the 1940s
through the 1960s. The technology of secondary treatment, required as a minimum technology for municipal
facilities  by the 1972 CWA, is designed primarily to reduce the loading of BOD to improve dissolved oxygen
conditions in streams, rivers, and estuaries.
     This issue is discussed in the Executive Summary and in Chapters 2 and 3 in  the final report.

Issue 5: Availability of Monitoring  Data in STORET

Reviewers:
     Wolman, Hetling, Kirk, Lagnese

Comment summary:

     The fact that the "before and after" trends analysis was based on an apparently limited data set of only
246 catalog units out of a total of 1,666 catalog units with reaches impacted by point source discharges
implies a significant problem with the availability and use of national-scale monitoring data from STORET
for "performance evaluations" of point and nonpoint source pollution control measures. The apparent lack of
a consistent and reliable water quality database on a national scale is a significant issue and needs to be
discussed in more detail in the final report. The reviewers asked if the final report could present recommen-
dations and conclusions about water quality monitoring programs that would provide guidance for future
policy decisions or analysis efforts.
Response:
     National-scale assessments of "performance evaluations"  of the impact of water pollution control
policies ideally should be based on a database large enough to provide a reliable sample of the effectiveness
of implementation of regulatory policy. The objective of the study was a quantitative assessment of how
much water quality has improved since the 1972 CWA. The purpose was to evaluate whether the national
investment of $61  billion (current year dollars) that was targeted toward upgrading municipal wastewater
treatment plants to secondary and better-than-secondary levels of treatment was, in fact, an effective regula-
tory policy for the Nation. As discussed under Issue 4, dissolved oxygen was selected as the key water
quality indicator for the evaluation. To characterize long-term trends in oxygen, data sets needed to be com-
piled to represent "before" conditions prior to the 1972 CWA for comparison to "after" conditions. Persistent
drought conditions were widespread in large areas of the  northeast, middle Atlantic, and central United States
during both the early 1960s (1962-1966) and the late 1980s (1987-1988). Early in the study, 1961-1965 and
1986-1990 were selected as the 5-year blocks of time to represent "before and after" conditions. The choice
of  1961-1965 to represent conditions "before" the CWA was based, in part, on the availability of
national-scale dissolved oxygen data compiled from 1957-1965 by the FWQA (Gunnerson,  1965) from an early
monitoring program funded under the 1956 Amendments  to the Federal Water Pollution Control Act.
      After the "before and after" analysis was completed, an inventory of the availability of oxygen and other
water quality parameters in STORET from 1941-1995 was compiled. The  limited availability of data for the
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                      Appendix A: Summary of Peer Review Team Comments and Study Authors' Responses
"before" period constrained the sample size of the data sets that could be compiled for the "before and after"
comparison. Nationwide, only 5,185 stations with 125,772 observations of oxygen were available for the
1961-1965 "before" period compared to 17,656 stations with 955,123 observations for the 1986-1990 "after"
years.  The largest abundance of stations were monitored after passage of the 1972 CWA with 34,052 stations
and 749,125 observations recorded during 1971-1975.  A considerably larger sample would most likely have
been available for the "before and after" trend analysis if the 5-year period of 1966-1970 (16,972 stations) or
1971-1975 (34,052 stations) had been selected as the "before" period rather then the period of much more
limited data availability, 1961-1965 (5,185 stations).  Selection of 1961-1965 thus resulted in the analysis
being based on only about one-third of the data available in 1966-1970 and only about one-sixth of the data
available during the peak monitoring activity years of 1971-1975. Final selection of "before and after" data
sets is based on comparable "dry" hydrologic characteristics as a "filter" for the analysis.
     Even with the limited data set available for the "before and  after" analysis, the results clearly document
statistically significant improvements in dissolved oxygen with data sets aggregated over all spatial scales
from the relatively small RF1 reach to the catalog unit and the major river basin. The methodology  can be
applied using 1966-1970 or 1971-1975 as  the "before" period to enhance the robustness of the "before and
after" analysis for dissolved oxygen trends. The methodology can also be applied for other water quality
parameters for trend assessments  of nutrients and TSS, for example, to evaluate the effectiveness of point and
nonpoint source control programs on these parameters.

Recommendations on monitoring programs:
    •    Sufficient federal funding to state and local government agencies should be made available for long
         time periods (5- to  10-year programs) to ensure support for continuous operation of a national-scale
         monitoring network and data collection efforts.
    •    Adequate federal funding must be made available to state and local governments to ensure the
         continuation of state-local-federal data submission and data management activities, including ar-
         chives of historical water quality data, with STORET designated as the centrally accessible data-
         base for water quality data and information.
    •    State and local government agencies and university research groups receiving federal funds to
         support water quality monitoring programs should be required to submit all data subjected to   QA/
         QC procedures in electronic format specified by EPA to STORET as the designated national
         database repository for  water quality data.  All water quality data records submitted to STORET
         should be required to be cross-referenced to geographic identifier codes defined  for the Reach File
         and the National Hydrography Database.
    •    Interagency coordination for joint sharing of water quality data and submission of data to  STORET
         should be established as standard operating procedure for all federal agencies involved in collecting
         water quality data for monitoring, research, or other programmatic purposes in freshwater and
         marine environments. Water quality data and information are collected by many federal agencies
         other than EPA; USGS, NOAA, NPS, USDA, USAGE, U.S. Navy, and U.S. Coast Guard all collect
         water quality data for a variety of geohydrologic, limnological, and oceanographic purposes.  Comprehen-
         sive national-scale assessments of the effectiveness of regulatory policies can be most successful only if
         all available data are shared (subject to national security clearance constraints imposed by the
         U.S. Navy) and pooled in a centrally accessible database designed to adhere to rigorous QA/QC proce-
         dures.
    •    Adequate federal funding must be made available to ensure the development  of state-of-the-art
         software "tools" with up-to-date computer technology for the user community to be able to conduct
         credible statistical analyses to evaluate the status and trends of key water quality parameters.  Raw
         data extracted from STORET and software "tools"  should be made available on-line through EPA's
         Office of Water web site.
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Issue 6:  How Representative is Oxygen Data Used for "Before and After" Trends?

Reviewers:

    Wolman, Hetling, Kirk, Lagnese, Parker, Lindstrom, Isaacs, Smith, Habibian

Comment summary:

     Some reviewers thought that the "before and after" results were not particularly impressive as a basis to
proclaim national-scale improvements in dissolved oxygen. Other reviewers did, however, think the "before
and after" results were impressive and that the report presented solid evidence for documenting improvements
in oxygen that were undoubtedly significant. Some reviewers pointed out that NFS loads, even in reaches
impacted by point sources, probably confounded the analysis and contributed to "before and after" trends
where big improvements were not identified. Some reviewers  suggested that the final report present data
showing (a) "before and after" oxygen trends for RF1  reaches impacted only by NFS under "dry" and "wet"
conditions; (b) "before and after" oxygen data for RF1 reaches showing the worst degradation using the point
source-impacted "dry" criteria; and (c) "before and after" BOD5 trends to correlate with the oxygen data. The
issues raised by the reviewers are twofold: (1) revise the report to present results to clearly document that
RF1 reaches with "before and after" improvements probably represent a significant portion of the US popula-
tion and municipal wastewater loads, and (2) show that the data filtering methodology for "dry" point source-
dominated reaches accurately represents the "worst-case" conditions response of ambient oxygen to changes
in waste loads.

Response:

     Although the "before and after" evaluation of oxygen is based on data compiled from only 246 catalog
units and 311 RF1 reaches, the waterways included in the analysis accounted for about 62 million people
living in the 246 catalog units characterized by improvements in dissolved oxygen. The population repre-
sented in the "before and after" analysis thus accounts for about 31 percent of the total continental US
population of 197 million recorded in the 1990 census. During both the "before" and "after" periods, "dry"
hydrologic conditions (< 75 percent summer mean streamflow) were recorded in about 90 percent of all
catalog units for at least 1 of the 5 years of record with "dry" conditions persisting for an average of 2.5 years
during 1961-1965 and 2.7 years during 1986-1990. Filters used in the "before and after" analysis included
specification of hydrologic conditions as "dry,"" normal," or "wet" and  selection of RF1 reaches defined by
the impact of nonpoint source and point source pollutant loads  as "only PS impacted," "only NPS impacted,"
or "PS and NPS impacted."  The results presented in  the report emphasized the worst-case findings for "only
PS impacted" reaches under "dry" hydrologic conditions.  The complete listing of the "before and after" data
for dissolved oxygen and BOD5 for the 246 catalog units with  "before and after" data is presented in Appen-
dix D of this report.  "Before  and after" BOD5 data were correlated with "before and after" dissolved oxygen
data in the discussion of catalog unit and RF1 reach scale trends for the Upper White River catalog unit in
Indiana. The data tables  identify the waterways ranked by the "before and after" change in oxygen and BOD5
from the greatest improvement to the worst degradation.
     In response to a reviewer's suggestion, the  "before and after" analysis  was performed for RF1 reaches
impacted only by NPS loads  under "dry" flow conditions. The  results indicated that (a) very little "before and
after" data was available to characterize trends for reaches impacted only by NPS and (b) oxygen conditions
in NPS  reaches were not characterized by the significant improvements identified for PS impacted reaches.
Selection of "dry" hydrologic conditions for at least 1 of 5 years for "only NPS impacted"  reaches resulted  in
extraction of a small sample  of only 37 catalog units with sufficient "before and after" data sets.  The greatest
improvement was characterized by oxygen increasing from 3.0 mg/L during 1961-1965 to 6.2 mg/L during
1986-1990 in the Lower Dan River watershed in North Carolina.
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                      Appendix A: Summary of Peer Review Team Comments and Study Authors' Responses


Issue 7: Statistical Methods

Reviewer:

    Smith

Comment  summary:

     DO deficit data should be used instead of DO concentration data to account for possible differences in
temperature during the before and after periods. Discussions of the statistical effect of data aggregation should
be clarified, It should be stressed that pooling reach data at the national level enhances the ability to distinguish
signal from noise and obtain statistically significant results. More discussion is needed on uncertainty, particu-
larly where results are based on limited data. Some assessment should be made of the degree of statistical
dependence of DO concentration between reach-level results, to ensure there is no bias due to "clustering" of
monitoring stations in adjacent or nearby reaches.
Response:

     Discussion has been added in Chapter 3 to address the selection of DO concentration over DO satura-
tion or DO deficit (see also Issue #4). The authors  have adopted the wording  "data aggregation" in conjunc-
tion with "spatial scale" in the description of the statistical methods and results. Discussion has also been
included in Chapter 3 to address uncertainty. Since the study authors found similar results in before versus
after DO concentration changes at all three data aggregation scales (i.e., two-thirds of hydrologic units at the
reach, catalog unit, and major river basin scales), additional analysis on spatial clustering of monitoring stations
was not performed.

Issue 8:  Geographic  Representation of Case Studies

Reviewers:

     Lagnese, Parker, Kirk, Okun

Comment  summary:

     A few reviewers pointed out the lack of geographic diversity of case study sites. At least one case study
should have been selected to represent the western arid region. Other reviewers commented that the case
studies really presented a good documentation of improvements in water quality although how these were
related to the CWA was not always clearly explained.
Response:

     The discussion on the study authors' logic for case study site selection has been expanded in Chapter 4.
Geographic diversity was not a priority in the selection process; instead, selection focused on heavily urban-
ized, highly populated waterways with a history of water quality problems related to municipal wastewater
treatment discharges. The case study chapters have been expanded to clarify  the relationship of observed
water quality conditions to actions related to the CWA.
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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment


Issue 9: Cost versus Benefit Analysis

Reviewers:

     Lagnese, Parker, Linsky, Okun

Comment  summary:

     Not enough explanation is provided of how cost and benefit data were compiled for the three case
studies (Potomac, Upper Mississippi, and Willamette Rivers) presented in the Executive Summary and
Chapter 4 (overview of cases). A cost/benefit analysis is a major issue for the evaluation of the effectiveness
of the CWA. The cost/benefit data were, in fact, knowingly included in the Executive Summary without any
explanation at all.

Response:

     The study authors agree that cos^enefit is a major issue for evaluation of the effectiveness of the
CWA. The original scope of this study was never intended to include cost versus benefit analysis of pollution
controls, but rather was to focus on national trends in population, wastewater treatment plant design capacity,
and water quality conditions in receiving waters. The cost versus benefit data provided for the three case
study sites was prepared under a separate study and does not extend to the other six case studies or nationally.
The study authors have chosen to remove the cost versus benefits data and information completely from the
document to avoid confusion or presentation of incomplete analyses since this is a national-scale study.

Issue  10: Editing for final report

Reviewers:

     Wolman, Landman, Kirk

Comment  summary:

     Eliminate all self-congratulatory phrases claiming "success" or what a wonderful methodology and
study this is, etc. Edit out redundant material presented in several chapters. The tone of the report is "biased"
and "not objective." Provide a clear summery and conclusions sections where appropriate throughout the
document.

Response:
     The  document has been extensively revised and rewritten since the peer review. The study authors have
attempted to remove wherever possible any redundancy or biased statements. A summary and conclusions
section has been added at the end of each chapter. The entire study is based on factual information that speaks
for itself, allowing the readers  to draw their own conclusions.
A-10

-------
   Appendix  B
National Municipal  Wastewater
Inventory and Infrastructure,
1940 to 2016
Table                                                               Page
 B-1   POTW facility inventory	   B-3
 B-2   Resident population served by POTWs	   B-3
 B-3   Wastewater flow	   B-3
 B-4   Influent wastewater flow normalized to population served	   B-4
 B-5   Influent CBOD5 load	   B-4
 B-6   Effluent CBOD5 load	   B-4
 B-7   CBOD5 removal efficiency	   B-5
 B-8   Influent CBOD5 load normalized to population served	   B-5
 B-9   Influent CBOD5 concentration	   B-5
B-10  Effluent CBOD5 concentration	   B-6
B-11   Influent CBODU load	   B-6
B-12  Effluent CBODU load	   B-6
B-13  CBODy removal efficiency	   B-7
B-14  Effluent CBODU concentration	   B-7
B-15  Influent NBOD load	   B-7
B-16  Effluent NBOD load	   B-8
B-17  NBOD removal efficiency	   B-8
B-18  Effluent NBOD concentration	   B-8
B-19  Influent BODU load	   B-9
B-20  Effluent BODy load	   B-9
B-21   Removal efficiency BODU	   B-9
B-22  Effluent BODU concentration	  B-10
B-23  Influent TSS load	  B-10
B-24  Effluent TSS load	  B-10
B-25  TSS removal efficiency	  B-11
B-26  Effluent TSS concentration	  B-11
B-27  Influent POC load	  B-11
B-28  Effluent POC load	  B-12
B-29  POC removal efficiency	  B-12
B-30  Effluent POC concentration	  B-12
B-31   Influent and effluent characteristics for CBOD5, CBOD^ TKN, andBODu	  B-13
B-32  Influent and effluent characteristics for TSS and POC	  B-15
B-33  Middle population projections of POTW loads of CBOD5, CBODy, NBOD and BODU, 1996-2050  B-16
                                                                   B-1

-------
Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
Table                                                                                         Page

B-34  Inventory of POTW facilities in 1972 in the United States	   B-17
B-35  Population served (millions) by POTW facilities in 1972 in the United States	   B-18
B-36  Data sources for trends in municipal wastewater treatment, 1940-2016	   B-19
B-37  Municipal wastewater treatment categories presented in Appendix B tables	   B-20
 Note: Values of -9.0 in the tables indicate that data was not available for the particular year and category of
       waste treatment.
B-2

-------
Appendix B: National Municipal Wastewater Inventory and Infrastructure, 1940 to 2016
Table
Year
1940
1950
1962
1968
1972
19V3
1974
1976
1978
1980
1982
1984
1986
1988
1992
1996
2016
Table


Year
1940
1950
1962
1968
1972
1973
1974
1976
1978
1980
1982
1984
1986
1988
1992
1996
2016
Table


Year
1940
1950
1962
1968
1972
1973
1974
1976
1978
1980
1982
1984
1986
1988
1992
1996
2016
B-1 . POTW facility inventory (Count)
No
Total
-9.0
11784.0
11698.0
14051.0
19355.0
-9.0
-9.0
-9.0
14850.0
15522.0
15662.0
15580.0
15541.0
15708.0
15613.0
16024.0
18303 0
Discharge
-9.0
0.0
0.0
0.0
142.0
-9.0
-9.0
-9.0
985.0
1361.0
1600.0
1726.0
1762.0
1854.0
1981.0
2032.0
2369.0
Raw
-9.0
5156.0
2262.0
1564.0
2265.0
1532.0
-9.0
-9.0
91.0
272.0
237.0
202.0
149.0
117.0
0.0
0.0
0.0
Primary
2938.0
3099.0
2717.0
2435.0
2530.0
2723.0
3032.0
-9.0
1306.0
1043.0
1036.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
Advanced
Primary
0.0
0.0
0.0
0.0
64.0
-9.0
-9.0
-9.0
2972.0
2300.0
2083.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0


Secondary
2630.
3529.
6719.
10042.
13893.
16015.
16987.
2838.
6608.
7852.
7946.
8070.
8403.
8536.
9086.
9388.
9738
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Advanced
Secondary
0.0
0.0
0.0
0.0
0.0
-9.0
-9.0
-9.0
2187.0
2443.0
2529.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
Advanced
Treatment
0.0
0.0
0.0
10.0
461.0
795.0
992.0
2719.0
701.0
251.0
231.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9 0
Less
than
Secondary
2938.0
3099.0
2717.0
2435.0
2594.0
-9.0
-9.0
2451.0
4278.0
3343.0
3119.0
2617.0
2112.0
1789.0
868.0
176.0
61 0
Greater
than
Secondary
0.0
0.0
0.0
10.0
461.0
-9.0
-9.0
-9.0
2888.0
2694.0
2760.0
2965.0
3115.0
3412.0
3678.0
4428.0
6135.0
B-2. Resident population served by POTWs


Total
70800000.0
91762001.0
118300000.0
140100000.0
141722242.0
-9.0
-9.0
-9.0
155227000.0
158337000.0
163525000.0
170643000.0
163319000.0
177536335.0
180614290.0
189710899.0
274722315.0

No
Discharge
0.0
0.0
0.0
0.0
825000.0
-9.0
-9.0
-9.0
2197000.0
3599000.0
4172000.0
5514000.0
5679000.0
6079611.0
7764363.0
7660876.0
14163722.0
B-3. Wastewater flow


Total
11682.0
15140.7
19519.5
23116.5
23384.2
-9.0
-9.0
-9.0
26799.5
25510.0
27202.7
27305.0
27956.8
29293 5
29801 4
31302.3
45329.2

No
Discharge
0.0
0.0
0.0
0.0
136.1
-9.0
-9.0
-9.0
362.5
438.3
490.9
600 0
608.0
1003.1
1281.1
1264.0
2337.0


Raw
32200000.0
35268437.0
14600000.0
10100000.0
4939928.0
3200000.0
-9.0
-9.0
3640000.0
2307000.0
1876000.0
1273000.0
1605000.0
1367172.0
0.0
0.0
0.0


Primary
18500000.0
24599743.0
42200000.0
44100000.0
50502813.0
54600000.0
-9.0
-9.0
18747000.0
19101714.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0

Advanced
Primary
0.0
0.0
0.0
0.0
1376059.0
-9.0
-9.0
-9.0
25333000.0
18214286.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0




Secondary
20100000.
31893821.
61500000.
85600000.
76270812.
105000000.
-9.
32523000.
56256000.
62680000.
67609000.
70656000.
72285000.
77954544
82907949.
81944349.
102321429
0
.0
0
0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0

Advanced
Secondary
0.0
0.0
0.0
0.0
2257101.0
-9.0
-9.0
-9.0
30937000.0
47518000.0
50853000.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0

Advanced
Treatment
0.0
0.0
0.0
300000.0
5550529.0
2700000.0
-9.0
45733000.0
18117000.0
4917000.0
5411000.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
Less
than
Secondary
18500000.0
24599743.0
42200000.0
44100000.0
51878872.0
-9.0
-9.0
40271000.0
44080000.0
37316000.0
33604000.0
33675000.0
28815000.0
26484096.0
21712715.0
17177492.0
5513147.0
Greater
than
Secondary
0.0
0.0
0.0
300000.0
7807630.0
-9.0
-9.0
-9.0
49054000.0
52435000.0
56264000.0
59525000.0
54935000.0
65650912.0
68229263.0
82928182.0
152724017.0
(million gallons per day)


Raw
5313.0
5819.3
2409.0
1666.5
815.1
528 0
-9.0
-9.0
600.6
380.7
309.5
210.0
264.8
225.6
0 0
0 0
0 0


Primary
3052.5
4059.0
6963.0
7276.5
8333.0
9009.0
-9.0
-9.0
3415.0
3035.4
2474.5
-9 0
-9.0
-9.0
-9 0
-9 0
-9.0

Advanced
Primary
0.0
0.0
0.0
0.0
227.0
-9.0
-9.0
-9.0
3737.4
2895.1
2825.4
-9.0
-9.0
-9 0
-9.0
-9.0
-9.0




Secondary
3316.
5262
10147
14124
12584
17325
-9
5437
10138
9882
11009
11047
12140
12862
13679
13520
16883
.5
.5
.5
.0
.7
.0
.0
.5
.7
.1
.5
0
.0
.5
8
8
0

Advanced
Secondary
0.0
0.0
0.0
0.0
372.4
-9.0
-9.0
-9.0
4732.1
8654.9
9377.5
-9.0
-9 0
-9 0
-9.0
-9.0
-9.0

Advanced
Treatment
0.0
0.0
0.0
49.5
915.8
445.5
-9.0
7545.9
3813.2
751.6
714.7
-9 0
-9.0
-9.0
-9.0
-9 0
-9 0
Less
than
Secondary
3052.5
4059.0
6963.0
7276.5
8560.0
-9.0
-9.0
12653.6
7152.4
6157.1
5300.6
5335.0
4580.0
4369 9
3582.6
2834.3
909 7
Greater
than
Secondary
0.0
0.0
0.0
49.5
1288.3
-9.0
-9.0
7007.1
8545.3
8651.8
10092.2
10113 . 0
10364. 0
10832 4
11257 8
13683 . 1
25199 5
                                                                          B-3

-------
Progress in Water Quality: An Evaluation of the National Investment in
Table

Year
1940
1950
1962
1968
1972
1973
1974
1976
1978
1980
1982
1984
1986
1988
1992
1996
2016
Table


Year
1940
1950
1962
1968
1972
1973
1974
1976
1978
1980
1982
1984
1986
1988
1992
1996
2016
Table


Year
1940
1950
1962
1968
1972
1973
1974
1976
1978
1980
1982
1984
1986
1988
1992
1996
2016
Municipal
Wastewater Treatment
B-4. Influent wastewater flow normalized to population served (gallons per person per day, default- 165)
Less Greater

Total
165.0
165.0
165.0
165.0
165.0
-9.0
-9.0
-9.0
172.6
161.1
166.4
160.0
171.2
165.0
165.0
165.0
165.0
No
Discharge
-9.0
-9.0
-9.0
-9.0
165 0
-9.0
-9.0
-9.0
165.0
121.8
117.7
108.8
107.1
165.0
165.0
165.0
165.0
B-5. Influent CBOD5


Total
9507.5
12322.5
15886.2
18813.6
19031.5
-9.0
-9.0
-9.0
21252.8
20528.9
21170.4
23395.3
23927.4
23840.8
24254.2
25475.7
36891.7

Kb
Discharge
0.0
0.0
0.0
0.0
110.8
-9.0
-9.0
-9.0
295.0
356.7
399.5
488.3
494.8
816.4
1042.7
1028.8
1902.0
B-6. Effluent CBOD5


Total
6343.7
7525.8
6882.9
6931.9
6767.9
-9.0
-9.0
-9.0
5509.8
5188.3
4379.9
3943.9
3923.5
4460.0
4033.7
3812.2
4024.9

No
Discharge
0.0
0.0
0.0
0.0
0.0
-9.0
-9.0
-9.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0

Raw
165.0
165.0
165.0
165.0
165.0
165.0
-9.0
-9.0
165.0
165.0
165.0
165.0
165.0
165.0
-9.0
-9.0
-9.0

Primary
165.0
165.0
165.0
165.0
165.0
165.0
-9.0
-9.0
182.2
158.9
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
Advanced
Primary
-9.0
-9.0
-9.0
-9.0
165.0
-9.0
-9.0
-9.0
147.5
158.9
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9 0

Secondary
165.0
165.0
165.0
165.0
165.0
165.0
-9.0
167.2
180.2
157.7
162.8
156.3
167.9
165.0
165.0
165.0
165.0
Advanced
Secondary
-9.0
-9.0
-9.0
-9.0
165.0
-9.0
-9.0
-9.0
153.0
182.1
184.4
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
Advanced
Treatment
-9.0
-9.0
-9.0
165.0
165.0
165.0
-9.0
165.0
210.5
152.9
132.1
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
than
Secondary
165.0
165.0
165.0
165.0
165.0
-9.0
-9.0
314.2
162.3
165.0
157.7
158.4
158.9
165.0
165.0
165.0
165.0
than
Secondary
-9.0
-9.0
-9.0
165.0
165.0
-9.0
-9.0
-9.0
174.2
165.0
179.4
169.9
188.7
165.0
165.0
165.0
165.0
load (metric tons per day)


Raw
4324.0
4736.1
1960.6
1356.3
663.4
429 7
-9.0
-9.0
488.8
309.8
251.9
170.9
215.5
183.6
0.0
0.0
0.0


Primary
2484 3
3303.4
5666.9
5922.1
6781.9
7332.1
-9.0
-9.0
2511.0
4700.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0

Advanced
Primary
0.0
0.0
0.0
0.0
184.8
-9.0
-9.0
-9.0
3210.0
2356.2
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0


Secondary
2699.2
4282.9
8258.7
11495.0
10242.2
14100.1
-9.0
3764.0
8222.0
7810.0
8623.0
9448.0
10378.0
10468.3
11133.5
11004.1
13740.4

Advanced
Secondary
0.0
0.0
0 0
0.0
303.1
-9.0
-9.0
-9.0
3419.0
6498.0
7030.0
-9 0
-9.0
-9.0
-9.0
-9.0
-9.0

Advanced
Treatment
0.0
0.0
0.0
40.3
745.4
362.6
-9.0
6141.4
3107.0
598.0
586.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
Less
than
Secondary
2484.3
3303.4
5666.9
5922.1
6966.7
-9.0
-9.0
10177.0
5721.0
5011.1
4280.0
4917.0
4325.0
3556.5
2915.7
2306.7
740.3
Greater
than
Secondary
0.0
0.0
0.0
40.3
1048.5
-9.0
-9.0
5392.0
6526.0
7041.3
7616.0
8371.0
8514.0
8816.1
9162.3
11136.2
20508.9
load (metric tons per day)


Raw
4324.0
4736.1
1960.6
1356.3
663.4
429.7
-9.0
-9.0
488.8
309.8
251.9
170.9
215.5
183.6
0.0
0.0
0.0


Primary
1614.8
2147.2
3683.5
3849.3
4408.2
4765.8
-9.0
-9.0
1487.0
2316.0
-9.0
-9 0
-9.0
-9.0
-9.0
-9.0
-9.0

Advanced
Primary
0.0
0.0
0.0
0.0
92.4
-9.0
-9.0
-9.0
1167.0
1178.1
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0


Secondary
404.9
642.4
1238.8
1724.2
1536.3
2115.0
-9.0
518.0
1596.0
1469.0
1539.0
1135.0
1279.0
1570.2
1670.0
1650.6
2061.1

Advanced
Secondary
0.0
0.0
0.0
0.0
30.3
-9.0
-9.0
-9.0
362.0
752.0
582.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0

Advanced
Treatment
0.0
0.0
0.0
2.0
37.3
18.1
-9.0
307.1
409.0
75.0
32.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
Less
than
Secondary
1614.8
2147.2
3683.5
3849.3
4500.6
-9.0
-9.0
4360.0
2654.0
2881.4
1975.0
2030.0
1834.0
2045.0
1676.5
1326.4
425.7
Greater
than
Secondary
0.0
0.0
0.0
2.0
67.6
-9.0
-9.0
324.0
771.0
528.1
614.0
608.0
595.0
661.2
687.2
835.2
1538.2
B-4

-------
Appendix B: National Municipal Wastewater Inventory and Infrastructure, 1940 to 2016
Table B-7.

Year
Default:
1940
1950
1962
1968
1972
1973
1974
1976
1978
1980
1982
1984
1986
1988
1992
1996
2016
Table B-8.


Year
1940
1950
1962
1968
1972
1973
1974
1976
1978
1980
1982
1984
1986
1988
1992
1996
2016
Table B-9.


Year
1940
1950
1962
1968
1972
1973
1974
1976
1978
1980
1982
1984
1986
1988
1992
1996
2016
CBOD5

Total

33.3
38.9
56.7
63.2
64.4
-9.0
-9.0
-9.0
74.1
74.7
79.3
83.1
83.6
81.3
83.4
85.0
89.1
Influent


Total
0.296
0.296
0.296
0.296
0.296
-9.000
-9.000
-9.000
0.302
0.286
0.285
0.302
0.323
0.296
0.296
0.296
0.296
Influent


Total
215.0
215.0
215.0
215.0
215.0
-9.0
-9.0
-9.0
209.5
212.6
205.6
226.3
226.1
215.0
215.0
215.0
215.0
removal efficiency (Percent)
No
Discharge
100%
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
100.0
-9.0
100.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
CBOD5

Kb
Discharge
-9.000
-9.000
-9.000
-9.000
0.296
-9.000
-9.000
-9.000
0.296
0.219
0.211
0.195
0.192
0.296
0.296
0.296
0.296
CBOD5

No
Discharge
-9.0
-9.0
-9.0
-9.0
215.0
-9.0
-9.0
-9.0
215.0
215.0
215 0
215.0
215.0
215.0
215.0
215.0
215.0

Raw
0%
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
0.0
-9.0
0.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0

Primary
35%
35.0
35.0
35.0
35.0
35.0
35.0
-9.0
-9.0
40.8
50.7
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
Advanced
Primary
50%
-9.0
-9.0
-9.0
-9.0
50.0
-9.0
-9.0
-9.0
63 6
50.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0

Secondary
85%
85.0
85.0
85.0
85.0
85.0
85.0
-9.0
86.2
80.6
81.2
82.2
88.0
87.7
85.0
85.0
85.0
85.0
Advanced
Secondary
90%
-9.0
-9.0
-9.0
-9.0
90.0
-9.0
-9.0
-9.0
89.4
88.4
91.7
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
Advanced
Treatment
95%
-9.0
-9.0
-9.0
95.0
95.0
95.0
-9.0
95.0
86.8
87.5
94.5
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
Less
than
Secondary
42.5%
35.0
35.0
35.0
35.0
35.4
-9.0
-9.0
57.2
53.6
42.5
53.9
58.7
57.6
42.5
42.5
42.5
42.5
Greater
than
Secondary
92.5%
-9.0
-9.0
-9.0
95.0
93.6
-9.0
-9.0
94.0
88.2
92.5
91.9
92.7
93.0
92.5
92.5
92.5
92.5
load normalized to population served (Ibs CBODg per person per day, default = 0.296)


Raw
0.296
0.296
0.296
0.296
0.296
0.296
-9.000
-9.000
0.296
0.296
0.296
0.296
0.296
0.296
-9.000
-9.000
-9.000
concentration


Raw
215.0
215.0
215.0
215.0
215.0
215.0
-9 0
-9.0
215.0
215.0
215.0
215.0
215.0
215.0
-9.0
-9.0
-9.0


Primary
0.296
0.296
0.296
0.296
0.296
0.296
-9.000
-9.000
0.295
0.542
-9.000
-9.000
-9.000
-9.000
-9.000
-9.000
-9.000
(mg/L,


Primary
215.0
215.0
215.0
215.0
215.0
215.0
-9.0
-9.0
194.2
409.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0

Advanced
Primary
-9.000
-9.000
-9.000
-9.000
0.296
-9.000
-9.000
-9.000
0.279
0.285
-9.000
-9.000
-9.000
-9.000
-9.000
-9.000
-9.000
default =

Advanced
Primary
-9.0
-9.0
-9 0
-9.0
215.0
-9.0
-9.0
-9.0
226.9
215.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0


Secondary
0.296
0.296
0.296
0.296
0.296
0.296
-9.000
0.255
0.322
0.275
0.281
0.295
0.317
0.296
0.296
0.296
0.296
215.0 mg/L)


Secondary
215.0
215.0
215.0
215.0
215.0
215.0
-9.0
182.9
214.2
208.8
206.9
225.9
225.8
215.0
215.0
215.0
215.0

Advanced
Secondary
-9.000
-9.000
-9.000
-9.000
0.296
-9.000
-9.000
-9.000
0.244
0.301
0.305
-9.000
-9.000
-9.000
-9.000
-9.000
-9.000


Advanced
Secondary
-9.0
-9.0
-9.0
-9.0
215.0
-9.0
-9.0
-9.0
190.9
198.3
198.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0

Advanced
Treatment
-9.000
-9.000
-9.000
0.296
0.296
0.296
-9.000
0.296
0.378
0.268
0.239
-9.000
-9.000
-9.000
-9.000
-9.000
-9.000


Advanced
Treatment
-9 0
-9.0
-9.0
215.0
215.0
215.0
-9.0
215.0
215.2
210.2
216.6
-9.0
-9.0
-9 0
-9.0
-9.0
-9.0
Less
than
Secondary
0.296
0.296
0.296
0.296
0.296
-9.000
-9.000
0.557
0.286
0.296
0.281
0.322
0.331
0.296
0.296
0.296
0.296

Less
than
Secondary
215.0
215.0
215.0
215.0
215.0
-9.0
-9.0
212.5
211.3
215.0
213.3
243.5
249.5
215.0
215.0
215.0
215.0
Greater
than
Secondary
-9.000
-9.000
-9.000
0.296
0 296
-9.000
-9.000
-9.000
0.293
0.296
0.298
0.310
0.342
0.296
0.296
0.296
0.296

Greater
than
Secondary
-9.0
-9.0
-9.0
215.0
215.0
-9.0
-9.0
203.3
201.7
215.0
199.4
218.7
217.0
215.0
215.0
215.0
215.0
                                                                         B-5

-------
Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
Table B-10.  Effluent CBOD5 concentration [mg/L]


Year


Total
Default;
1940
1950
1962
1968
1972
1973
1974
1976
1978
1980
1982
1984
1986
1988
1992
1996
2016
Table


Year
1940
1950
1962
1968
1972
1973
1974
1976
1978
1980
1982
1984
1986
1988
1992
1996
2016
Table


Year
1940
1950
1962
1968
1972
1973
1974
1976
1978
1980
1982
1984
1986
1988
1992
1996
2016
143.5
131.3
93.2
79.2
76.5
-9.0
-9.0
-9.0
54.3
53.7
42.5
38.2
37.1
40.2
35.8
32.2
23.5

Kb
Discharge
0.0
-9.0
-9.0
-9.0
-9.0
0.0
-9.0
-9.0
-9.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
B-11. Influent CBODU


Total
11409.0
14786.9
19063.4
22576.3
22837.8
-9.0
-9.0
-9.0
25503.4
24634.7
25404.5
28074.3
28712.8
28609.0
29105.0
30570.9
44270.0

Kb
Discharge
0.0
0.0
0.0
0.0
132.9
-9.0
-9.0
-9.0
354.0
428.1
479.4
586.0
593.8
979.7
1251.2
1234.5
2282.4
B-12. Effluent CBODu


Total
8922.4
10943.4
11764.5
12689.4
12558.1
-9.0
-9.0
-9.0
11620.7
10685.4
9581.9
8439.7
8550.9
9869.3
9418.1
9232.0
10995.2

Kb
Discharge
0.0
0.0
0.0
0.0
0.0
-9.0
-9.0
-9.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0


Raw Primary
215.0 139.75
215.0 139.8
215.0 139.8
215.0 139.8
215.0 139.8
215.0 139.8
215.0 139.8
-9.0 -9.0
-9.0 -9.0
215.0 115.0
215.0 201.6
215.0 -9.0
215.0 -9.0
215.0 -9.0
215.0 -9.0
-9.0 -9.0
-9.0 -9.0
-9.0 -9.0

Advanced
Primary
107.5
-9.0
-9.0
-9.0
-9.0
107.5
-9.0
-9.0
-9.0
82 5
107.5
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0


Secondary
32.25
32.3
32.3
32.3
32.3
32.3
32.3
-9.0
25.2
41.6
39.3
36.9
27.1
27.8
32.3
32.3
32.3
32.3

Advanced
Secondary
21.5
-9.0
-9.0
-9.0
-9.0
21.5
-9.0
-9.0
-9.0
20.2
23.0
16.4
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0

Advanced
Treatment
10.75
-9.0
-9.0
-9.0
10.8
10.8
10.8
-9.0
10.8
28.3
26.4
11.8
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
Less
than
Secondary
123 . 63
139.8
139.8
139.8
139.8
138.9
-9.0
-9.0
91.0
98.0
123.6
98.4
100.5
105.8
123.6
123.6
123.6
123.6
Greater
than
Secondary
15.12
-9.0
-9.0
-9.0
10.8
13.9
-9.0
-9.0
12.2
23.8
16.1
16.1
15.9
15.2
16.1
16.1
16.1
16.1
load [metric tons per day]


Raw Primary
5188.9 2981.2
5683.3 3964.1
2352.7 6800.3
1627.6 7106.5
796.0 8138.2
515.7 8798.5
-9.0 -9.0
-9.0 -9.0
586.6 3013.2
371.8 5640.0
302.3 -9.0
205.1 -9.0
258.6 -9.0
220.3 -9.0
0.0 -9.0
0.0 -9.0
0.0 -9.0

Advanced
Primary
0.0
0.0
0.0
0.0
221.7
-9.0
-9.0
-9.0
3852.0
2827.5
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0


Secondary
3239.0
5139.5
9910.4
13794.0
12290.6
16920.2
-9.0
4516.8
9866.4
9372.0
10347.6
11337.6
12453.6
12561.9
13360.2
13204.9
16488.5

Advanced
Secondary
0.0
0.0
0.0
0.0
363.7
-9.0
-9.0
-9.0
4102.8
7797.6
8436.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0

Advanced
Treatment
0.0
0.0
0.0
48.3
894.4
435.1
-9.0
7369.6
3728.4
717.6
703.2
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
Less
than
Secondary
2981.2
3964.1
6800.3
7106.5
8360.0
-9.0
-9.0
12212.4
6865.2
6013.3
5136.0
5900.4
5190.0
4267.8
3498.9
2768.1
888.4
Greater
than
Secondary
0.0
0.0
0.0
48.3
1258.2
-9.0
-9.0
6470.4
7831.2
8449.6
9139.2
10045.2
10216.8
10579.3
10994.8
13363.4
24610.6
load [metric tons per day]


Raw Primary
5188.9 2583.7
5683.3 3435.6
2352.7 5893.6
1627.6 6158.9
796.0 7053.1
515.7 7625.4
-9.0 -9.0
-9.0 -9.0
586.6 2379.2
371.8 3705.6
302.3 -9.0
205.1 -9.0
258.6 -9.0
220.3 -9.0
0.0 -9.0
0.0 -9.0
0.0 -9.0

Advanced
Primary
0.0
0.0
0.0
0.0
147.8
-9.0
-9.0
-9.0
1867.2
1885.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0


Secondary
1149.8
1824.5
3518.2
4896.9
4363.2
6006.7
-9.0
1471.1
4532.6
4172.0
4370.8
3223.4
3632.4
4459.5
4742.9
4687.7
5853.4

Advanced
Secondary
0.0
0.0
0.0
0.0
86.1
-9.0
-9.0
-9.0
1028.1
2135.7
1652.9
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0

Advanced
Treatment
0.0
0.0
0.0
6.0
111.8
54.4
-9.0
921.2
1227.0
225.0
96.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
Less
than
Secondary
2583.7
3435.6
5893.6
6158.9
7201.0
-9.0
-9.0
6976.0
4246.4
4610.2
3160.0
3248.0
2934.4
3272.0
2682.5
2122.2
681.1
Greater
than
Secondary
0.0
0.0
0.0
6.0
197.9
-9.0
-9.0
939.6
2255.1
1531.5
1748.9
1763.2
1725.5
1917.5
1992.8
2422.1
4460.7
B-6

-------
Appendix B: National Municipal Wastewater Inventory and Infrastructure, 1940 to 2016
Table B-13. CBODU removal efficiency [Percent]

Year
Defaul t
1940
1950
1962
1968
1972
1973
1974
1976
1978
1980
1982
1984
1986
1988
1992
1996
2016
Table


Year
Defaul t
Default
1940
1950
1962
1968
1972
1973
1974
1976
1978
1980
1982
1984
1986
1988
1992
1996
2016
Table


Year
1940
1950
1962
1968
1972
1973
1974
1976
1978
1980
1982
1984
1986
1988
1992
1996
2016

Total

21.8
26.0
38.3
43.8
45.0
-9.0
-9.0
-9.0
54.4
56.6
62.3
69.9
70.2
65.5
67.6
69.8
75.2
No
Discharge
100%
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
100.0
-9.0
100.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
B-14. Effluent CBOD


Total
CBOD0:CBOD

201.8
190.9
159.2
145.0
141.9
-9.0
-9.0
-9.0
114.5
110.7
93.1
81.7
80.8
89.0
83.5
77.9
64.1

1*5
Discharge
0.0
0.0
-9.0
-9.0
-9.0
-9.0
0.0
-9.0
-9.0
-9.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
o.o
B-15. Influent NBOD


Total
6123.3
7936.3
10231.5
12116.9
12257.2
-9.0
-9.0
-9.0
14047.4
13371.5
14258.8
14312.4
14654.1
15354.7
15620.9
16407.7
23760.1

No
Discharge
0.0
0.0
0.0
0.0
71.4
-9.0
-9.0
-9.0
190.0
229.7
257.3
314.5
318.7
525.8
671.5
662.6
1225.0

Raw
0%
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
0.0
-9.0
0.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0

Primary
13.3%
13.3
13.3
13.3
13.3
13.3
13.3
-9.0
-9.0
21.0
34.3
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
Advanced
Primary
33.3%
-9.0
-9.0
-9.0
-9.0
33.3
-9.0
-9.0
-9.0
51.5
33.3
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0

Secondary
64.5%
64.5
64.5
64.5
64.5
64.5
64.5
-9.0
67.4
54.1
55.5
57.8
71.6
70.8
64.5
64.5
64.5
64.5
u concentration [mg/L; CBODU - BODS A


Raw
1.2
258.0
258.0
258.0
258.0
258.0
258.0
258.0
-9.0
-9.0
258.0
258.0
258.0
258.0
258.0
258.0
-9.0
-9.0
-9.0
load [metric


Raw
2784.9
3050.3
1262.7
873.5
427.2
276.8
-9.0
-9.0
314.8
199.5
162.3
110.1
138.8
118.2
0.0
0.0
0.0


Primary
1.6
223 . 60
223.6
223.6
223.6
223.6
223.6
223.6
-9.0
-9.0
184.0
322.5
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0

Advanced
Primary
1.6
172.0
-9.0
-9.0
-9.0
-9.0
172.0
-9.0
-9.0
-9.0
132.0
172.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0


Secondary
2.84
91.59
91.6
91.6
91.6
91.6
91.6
91.6
-9.0
71.5
118.1
111.5
104.9
77.1
79.0
91.6
91.6
91.6
91.6
Advanced
Secondary
76.3%
-9.0
-9.0
-9.0
-9.0
76.3
-9.0
-9.0
-9.0
74.9
72.6
80.4
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
Advanced
Treatment
87.5*
-9.0
-9.0
-9.0
87.5
87.5
87.5
-9.0
87.5
67.1
68.6
86.3
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
Less
than
Secondary
23.3%
13.3
13.3
13.3
13.3
13.9
-9.0
-9.0
42.9
38.1
23.3
38.5
45.0
43.5
23.3
23.3
23.3
23.3
Greater
than
Secondary
81.9%
-9.0
-9.0
-9.0
87.5
84.3
-9.0
-9.0
85.5
71.2
81.9
80.9
82.4
83.1
81.9
81.9
81.9
81.9
'.(CBODjBOD,)]

Advanced
Secondary
2.84
61.06
-9.0
-9.0
-9.0
-9.0
61.1
-9.0
-9.0
-9.0
57.4
65.2
46.6
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0

Advanced
Treatment
3.0
32.25
-9.0
-9.0
-9.0
32.3
32.3
32.3
-9.0
32.3
85.0
79.1
35.5
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
Less
than
Secondary
1.6
197.80
223.6
223.6
223.6
223.6
222.2
-9.0
-9.0
145.6
156.8
197.8
157.5
160.8
169.3
197.8
197.8
197.8
197.8
Greater
than
Secondary
2.9
46.76
-9.0
-9.0
-9.0
32.3
40.6
-9.0
-9.0
35.4
69.7
46. 8
45.8
46.1
44.0
46.8
46.8
46.8
46.8
tons per day; NBOD = 4.57 x TKN]


Primary
1600.0
2127.6
3649.8
3814.1
4367.9
4722.2
-9.0
-9.0
1790.1
1591.1
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0

Advanced
Primary
0.0
0.0
0.0
0.0
119.0
-9.0
-9.0
-9.0
1959.0
1517.5
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0


Secondary
1738.4
2758.4
5319.0
7403.4
6596.5
9081.2
-9.0
2850.2
5314.4
5179.9
5770.8
5790.5
6363.4
6742.1
7170.5
7087.2
8849.5

Advanced
Secondary
0.0
0.0
0.0
0.0
195.2
-9.0
-9.0
-9.0
2480.4
4536.6
4915.4
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0

Advanced
Treatment
0.0
0.0
0.0
25.9
480.1
233.5
-9.0
3955.3
1998.8
394.0
374.6
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
Less
than
Secondary
1600.0
2127.6
3649.8
3814.1
4486.9
-9.0
-9.0
6632.6
3749.1
3227.4
2778.4
2796.4
2400.7
2290.5
1877.9
1485.6
476.8
Greater
than
Secondary
0.0
0.0
0.0
25.9
675.3
-9.0
-9.0
-9.0
4479.2
4535.0
5290.0
5300.9
5432.5
5678.0
5901.0
7172.3
13208.8
                                                                        B-7

-------
Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
TableB-16. Effluent NBOD

Year
1940
1950
1962
1968
1972
1973
1974
1976
1978
1980
1982
1984
1986
1988
1992
1996
2016
TableB-17


Year
Default:
1940
1950
1962
1968
1972
1973
1974
1976
1978
1980
1982
1984
1986
1988
1992
1996
2016
Table B-18


Year
Defaul t :
1940
1950
1962
1968
1972
1973
1974
1976
1978
1980
1982
1984
1986
1988
1992
1996
2016

Total
5145.5
6475.2
7513.7
8591.1
8273.3
-9.0
-9.0
-9.0
7525.8
6916.3
7167.8
7030.9
7143.3
7327.0
7204.6
7093.2
8611.3
No
Discharge
0.0
0.0
0.0
0.0
0.0
-9.0
-9.0
-9.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
. NBOD removal


Total

16.0
18.4
26.6
29.1
32.5
-9.0
-9.0
-9.0
46.4
48.3
49.7
50.9
51.3
52.3
53.9
56.8
63.8

No
Discharge
100%
-9.0
-9 0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
100.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
. Effluent NBOD


Total

116.4
113.0
101.7
98.2
93.5
-9.0
-9.0
-9.0
74.2
71.6
69.6
68.0
67.5
66.1
63.9
59.9
50.2

No
Discharge
0.0
-9.0
-9.0
-9.0
-9.0
0.0
-9.0
-9.0
-9.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
load [metric tons per day; NBOD = 4.57 x TKN]

Raw
2784.9
3050.3
1262.7
873.5
427.2
276.8
-9.0
-9.0
314.8
199.5
162.3
110.1
138.8
118.2
0.0
0.0
0.0

Primary
1248.0
1659.5
2846.8
2975.0
3406.9
3683.3
-9.0
-9.0
1396.2
1241.0
-9.0
-9 0
-9.0
-9.0
-9.0
-9.0
-9.0
Advanced
Primary
0.0
0.0
0.0
0.0
92.8
-9.0
-9.0
-9.0
1528.0
1183.7
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0

Secondary
1112.6
1765.4
3404.2
4738.1
4221.8
5812.0
-9.0
1824.1
3401.2
3315.1
3693.3
3705.9
4072.6
4315.0
4589.1
4535.8
5663.7
Advanced
Secondary
0.0
0.0
0.0
0.0
42.9
-9.0
-9.0
-9.0
545.7
998.1
1081.4
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
Advanced
Treatment
0.0
0.0
0.0
4.4
81.6
39.7
-9.0
672.4
339.8
67.0
63.7
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
Less
than
Secondary
1248.0
1659.5
2846.8
2975.0
3499.8
-9.0
-9.0
5173.4
2924.3
2517.4
2167.2
2181.2
1872.5
1786.6
1464.7
1158.8
371.9
Greater
than
Secondary
0.0
0.0
0.0
4.4
124.6
-9.0
-9.0
-9.0
885.5
884.3
1145.1
1033.7
1059.3
1107.2
1150.7
1398.6
2575.7
efficiency [Percent]


Raw
0%
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
0.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0


Primary
22%
22.0
22.0
22.0
22.0
22.0
22.0
-9.0
-9.0
22.0
22.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
concentration [mg/L;


Raw
138.47
138.5
138.5
138.5
138.5
138.5
138.5
-9 0
-9.0
138.5
138.5
138.5
138 5
138.5
138.5
-9.0
-9.0
-9.0


Primary
10S.O
108.0
108.0
108.0
108.0
108.0
108.0
-9.0
-9.0
108.0
108.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0

Advanced
Primary
22%
-9.0
-9.0
-9.0
-9.0
22.0
-9.0
-9.0
-9.0
2.2.0
22.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
NBOD =

Advanced
Primary
108.0
-9.0
-9.0
-9.0
-9.0
108 0
-9.0
-9.0
-9.0
108.0
108.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0


Secondary
36%
36.0
36.0
36.0
36 0
36.0
36.0
-9.0
36.0
36.0
36.0
36.0
36.0
36.0
36.0
36.0
36.0
36.0

Advanced
Secondary
78%
-9.0
-9.0
-9.0
-9.0
78.0
-9.0
-9.0
-9.0
78.0
78.0
78.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0

Advanced
Treatment
83%
-9.0
-9.0
-9.0
83.0
83.0
83.0
-9.0
83.0
83.0
83.0
83.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
Less
than
Secondary
22%
22.0
22.0
22.0
22.0
22.0
-9.0
-9.0
22.0
22.0
22.0
22.0
22.0
22.0
22.0
22.0
22.0
22.0
Greater
than
Secondary
80. 5%
-9.0
-9.0
-9.0
83.0
81.6
-9.0
-9.0
-9.0
80.2
80.5
78.4
80.5
80.5
80.5
80.5
80.5
80.5
4.57 x TKN]


Secondary
88. 62
88.6
88.6
88.6
88.6
88.6
88.6
-9.0
88.6
88.6
88.6
88.6
88.6
88.6
88.6
88.6
88.6
88.6

Advanced
Secondary
30.46
-9.0
-9.0
-9.0
-9.0
30.5
-9.0
-9.0
-9.0
30.5
30.5
30.5
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0

Advanced
Treatment
23.54
-9.0
-9.0
-9.0
23.5
23.5
23.5
-9.0
23.5
23.5
23.5
23.5
-9 0
-9.0
-9.0
-9.0
-9.0
-9.0
Less
than
Secondary
108.0
108.0
108.0
108.0
108.0
108.0
-9.0
-9.0
108.0
108.0
108.0
108.0
108.0
108.0
108.0
108.0
108.0
108.0
Greater
than
Secondary
27.0
-9.0
-9.0
-9.0
23.5
25.5
-9.0
-9.0
-0.3
27.4
27.0
30.0
27.0
27.0
27.0
27.0
27.0
27.0
B-8

-------
Appendix B: National Municipal Wastewater Inventory and Infrastructure, 1940 to 2016
Table B-19. Influent BODU load [metric tons per day; BODU = CBODU + NBOD]

Year
1940
1950
1962
1968
1972
1973
1974
1976
1978
1980
1982
1984
1986
1988
1992
1996
2016
Table


Year
1940
1950
1962
1968
1972
1973
1974
1976
1978
1980
1982
1984
1986
1988
1992
1996
2016
Table


Year
Default
1940
1950
1962
1968
1972
1973
1974
1976
1978
1980
1982
1984
1986
1988
1992
1996
2016

Total
17532.4
22723.2
29294.9
34693.3
35095.0
-9.0
-9.0
-9.0
39550.8
38006.2
39663.3
42386.8
43366.9
43963.7
44725.9
46978.5
68030.1
No
Discharge
0.0
0.0
0.0
0.0
204.3
-9.0
-9.0
-9.0
544.0
657.8
736.7
900.5
912.5
1505.5
1922.7
1897.1
3507.4
B-20. Effluent BODy


Total
14067.9
17418.6
19278.2
21280.5
20831.4
-9.0
-9.0
-9.0
19146.5
17601.7
16749.8
15470.6
15694.2
17196.3
16622.7
16325.2
19606.6

No
Discharge
0.0
0.0
0.0
0.0
0.0
-9.0
-9.0
-9.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0

Raw
7973.8
8733.6
3615.4
2501.1
1223.3
792.4
-9.0
-9.0
901.4
571.3
464.6
315.2
397.4
338.6
0.0
0.0
0.0

Primary
4581.2
6091.7
10450.1
10920.6
12506.1
13520.7
-9.0
-9.0
4803.3
7231.1
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
Advanced
Primary
0.0
0.0
0.0
0.0
340.8
-9.0
-9.0
-9.0
5811.0
4345.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0

Secondary
4977.4
7897.9
15229.4
21197.3
18887.1
26001.4
-9.0
7367.0
15180.8
14551.9
16118.4
17128.1
18817.0
19304.1
20530.7
20292.1
25338.1
load [metric tons per day; BODU = CBOD


Raw
7973.8
8733.6
3615.4
2501.1
1223.3
792.4
-9.0
-9.0
901.4
571.3
464.6
315.2
397.4
338.6
0.0
0.0
0.0
B-21 . Removal efficiency BODy


Total

19.8
23.3
34.2
38.7
40.6
-9.0
-9.0
-9.0
51.6
53.7
57.8
63.5
63.8
60.9
62.8
65.2
71.2

fto
Discharge
100%
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0


Raw
0%
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0


Primary
3831.7
5095.1
8740.4
9133.9
10460.1
11308.7
-9.0
-9.0
3775.4
4946.6
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
[Percent]


Primary
16.4%
16.4
16.4
16.4
16.4
16.4
16.4
-9.0
-9.0
21.4
31.6
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0

Advanced
Primary
0.0
0.0
0.0
0.0
240.7
-9.0
-9.0
-9.0
3395.2
3068.6
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0


Advanced
Primary
29.4%
-9.0
-9.0
-9.0
-9.0
29.4
-9.0
-9.0
-9.0
41.6
29.4
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0


Secondary
2262.4
3589.9
6922.3
9635.0
8584.9
11818.6
-9.0
3295.2
7933.8
7487.1
8064.1
6929.3
7704.9
8774.4
9332.0
9223.5
11517.1



Secondary
54.5%
54.5
54.5
54.5
54.5
54.5
54.5
-9.0
55.3
47.7
48.5
50.0
59.5
59.1
54.5
54.5
54.5
54.5
Advanced
Secondary
0.0
0.0
0.0
0.0
558.9
-9.0
-9.0
-9.0
6583.2
12334.2
13351.4
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
Advanced
Treatment
0.0
0.0
0.0
74.3
1374.5
668.6
-9.0
11325.0
5727.2
1111.6
1077.8
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
Less
than
Secondary
4581.2
6091.7
10450.1
10920.6
12846.9
-9.0
-9.0
18845.0
10614.3
9240.6
7914.4
8696.8
7590.7
6558.3
5376.8
4253.7
1365.2
Greater
than
Secondary
0.0
0.0
0.0
74.3
1933.4
-9.0
-9.0
-9.0
12310.4
12984.6
14429.2
15346.1
15649.3
16257.3
16895.8
20535.7
37819.4
u + NBOD]

Advanced
Secondary
0.0
0.0
0.0
0.0
129.0
-9.0
-9.0
-9.0
1573.8
3133.7
2734.3
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0


Advanced
Secondary
76.9%
-9.0
-9.0
-9.0
-9.0
76.9
-9.0
-9.0
-9.0
76.1
74.6
79.5
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0

Advanced
Treatment
0.0
0.0
0.0
10.5
193.4
94.1
-9.0
1593.6
1566.8
292.0
159.7
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0


Advanced
Treatment
85.9%
-9.0
-9.0
-9.0
85.9
85.9
85.9
-9.0
85.9
72.6
73.7
85.2
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
Less
than
Secondary
3831.7
5095.1
8740.4
9133.9
10700.8
-9.0
-9.0
12149.4
7170.7
7127.5
5327.2
5429.2
4806.9
5058.6
4147.2
3281.0
1053.0

Less
than
Secondary
22.9%
16.4
16.4
16.4
16.4
16.7
-9.0
-9.0
35.5
32.4
22.9
32.7
37.6
36.7
22.9
22.9
22.9
22.9
Greater
than
Secondary
0.0
0.0
0.0
10.5
322.4
-9.0
-9.0
-9.0
3140 6
2415.8
2893.9
2796.9
2784.8
3024.7
3143.5
3820.7
7036.4

Greater
than
Secondary
81.4%
-9.0
-9.0
-9.0
85.9
83.3
-9.0
-9.0
-9.0
74.5
81.4
79.9
81.8
82.2
81.4
81.4
81.4
81.4
                                                                         B-9

-------
Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
Table

Year
B-22. Effluent BODU concentration [mg/L;

Total
Defaul t :
1940
1950
1962
1968
1972
1973
1974
1976
1978
1980
1982
1984
1986
1988
1992
1996
2016
Table


Year
1940
1950
1962
1968
1972
1973
1974
1976
1978
1980
1982
1984
1986
1988
1992
1996
2016
Table


Year
1940
1950
1962
1968
1972
1973
1974
1976
1978
1980
1982
1984
1986
1988
1992
1996
2016
318.1
303.9
260.9
243.2
235.3
-9.0
-9.0
-9.0
188.7
182.3
162.7
149.7
148.3
155.1
147.4
137.8
114.3
No
Discharge
0.0
-9.0
-9.0
-9.0
-9.0
0.0
-9.0
-9.0
-9.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
B-23. Influent TSS load


Total
9507.5
12322.5
15886.2
18813.6
19031.5
-9.0
-9.0
-9.0
21811.1
20761.6
22139.2
22222.5
22753.0
23840.8
24254.2
25475.7
36891.7

No
Discharge
0.0
0.0
0.0
0.0
110.8
-9.0
-9 0
-9.0
295.0
356.7
399.5
488.3
494.8
816.4
1042.7
1028.8
1902.0
B-24. Effluent TSS load


Total
5782.1
6730.4
5454.7
5237.7
4953.1
-9.0
-9.0
-9.0
3628.7
3133.7
2934.9
2832.7
2707.8
2664.0
2286.0
2081.4
1908.1

tfo
Discharge
0.0
0.0
0.0
0.0
0.0
-9.0
-9.0
-9.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0

Raw Primary
396.5 331.6
396.5 331.6
396.5 331.6
396.5 331.6
396.5 331.6
396.5 331.6
396.5 331.6
-9.0 -9.0
-9.0 -9.0
396.5 292.1
396.5 430.5
396.5 -9.0
396.5 -9.0
396.5 -9.0
396.5 -9.0
-9.0 -9.0
-9.0 -9.0
-9.0 -9.0
BODU = CBODU + NBOD]
Advanced
Primary
280.0
-9.0
-9.0
-9.0
-9.0
280.0
-9.0
-9.0
-9.0
240.0
280.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0

Secondary
180.2
180.2
180.2
180.2
180.2
180.2
180.2
-9.0
160.1
206.7
200.1
193.5
165.7
167 7
180.2
180.2
180.2
180.2
Advanced
Secondary
91.5
-9.0
-9.0
-9.0
-9.0
91.5
-9.0
-9.0
-9.0
87.9
95.7
77.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
Advanced
Treatment
55.8
-9.0
-9.0
-9.0
55.8
55.8
55.8
-9.0
55.8
108.5
102.6
59.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
Less
than
Secondary
305.8
331.6
331.6
331.6
331.6
330.2
-9.0
-9.0
253.6
264.8
305.8
265.5
268.8
277.3
305.8
305.8
305.8
305.8
Greater
than
Secondary
73. 8
-9 0
-9.0
-9.0
55.8
66.1
-9.0
-9.0
-0.3
97.1
73.8
75.8
73.1
71.0
73.8
73.8
73.8
73.8
[metric tons per day]


Raw Primary
4324.0 2484.3
4736.1 3303.4
1960.6 5666.9
1356.3 5922.1
663.4 6781.9
429.7 7332.1
-9.0 -9.0
-9.0 -9.0
488.8 2779.4
309.8 2470.4
251.9 -9.0
170.9 -9.0
215.5 -9.0
183.6 -9.0
0.0 -9.0
0.0 -9 0
0.0 -9.0

Advanced
Primary
0.0
0.0
0.0
0.0
184.8
-9.0
-9.0
-9.0
3041.7
2356.2
-9.0
-9.0
-9.0
-9 0
-9.0
-9.0
-9.0


Secondary
2699.2
4282.9
8258.7
11495.0
10242.2
14100.1
-9.0
4425.4
8251.5
8042.7
8960.2
8990.7
9880.3
10468.3
11133.5
11004.1
13740.4

Advanced
Secondary
0.0
0 0
0.0
0.0
303.1
-9.0
-9.0
-9.0
3851.3
7043.9
7632.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0

Advanced
Treatment
0.0
0.0
0.0
40.3
745.4
362.6
-9.0
6141.4
3103.4
611.7
581.6
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
Less
than
Secondary
2484.3
3303.4
5666.9
5922.1
6966.7
-9.0
-9.0
10298.3
5821.1
5011.1
4314.0
4341.9
3727.5
3556.5
2915.7
2306.7
740.3
Greater
than
Secondary
0.0
0.0
0.0
40.3
1048.5
-9.0
-9.0
-9.0
6954.7
7041.3
8213.6
8230.6
8434.9
8816.1
9162.3
11136.2
20508.9
[metric tons per day]


Raw Primary
4324.0 1242.2
4736.1 1651.7
1960.6 2833.5
1356.3 2961.0
663.4 3390.9
429.7 3666.0
-9.0 -9.0
-9.0 -9.0
488 8 1389.7
309.8 1235.2
251.9 -9.0
170.9 -9.0
215.5 -9.0
183.6 -9.0
0.0 -9.0
0.0 -9.0
0.0 -9.0

Advanced
Primary
0.0
0.0
0.0
0.0
55.4
-9.0
-9.0
-9.0
912.5
706.9
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0


Secondary
215.9
342.6
660.7
919.6
819.4
1128.0
-9.0
354.0
660.1
643.4
716.8
719.3
790.4
837.5
890.7
880.3
1099.2

Advanced
Secondary
0.0
0 0
0.0
0.0
9.1
-9.0
-9.0
-9.0
115.5
211.3
229.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0

Advanced
Treatment
0.0
0.0
0.0
0.8
14.9
7.3
-9.0
122.8
62.1
12.2
11.6
-9.0
-9.0
-9.0
-9 0
-9.0
-9.0
Less
than
Secondary
1242.2
1651.7
2833.5
2961.0
3446.4
-9.0
-9.0
4119.3
2302.2
2004.4
1725.6
1736.8
1491.0
1422.6
1166.3
922.7
296.1
Greater
than
Secondary
0.0
0.0
0.0
0.8
24.0
-9.0
-9.0
-9.0
177.6
176 0
240.6
205.8
210.9
220.4
229.1
278.4
512.7

B-10

-------
Appendix B: National Municipal Wastewater Inventory and Infrastructure, 1940 to 2016
Table

Year
B-25. TSS

Total
Defaul t :
1940
1950
1962
1968
1972
1973
1974
1976
1978
1980
1982
1984
1986
1988
1992
1996
2016
Table


Year
39.2
45.4
65.7
72.2
74.0
-9.0
-9.0
-9.0
83.4
84.9
86.7
87.3
88.1
88.8
90.6
91.8
94.8
removal efficiency [Percent]
No
Discharge
100%
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
100.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0

Raw
0%
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
0.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0

Primary
50%
50.0
50.0
50.0
50.0
50.0
50.0
-9.0
-9.0
50.0
50.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
B-26. Effluent TSS concentration [mg/L;


Total
Default;
1940
1950
1962
1968
1972
1973
1974
1976
1978
1980
1982
1984
1986
1988
1992
1996
2016
Table


Year
1940
1950
1962
1968
1972
1973
1974
1976
1978
1980
1982
1984
1986
1988
1992
1996
2016
130.8
117.4
73.8
59.9
56.0
-9.0
-9.0
-9.0
35.8
32.5
28.5
27.4
25.6
24.0
20.3
17.6
11.1

No
Discharge
0.0
-9.0
-9.0
-9.0
-9.0
0.0
-9.0
-9.0
-9.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
B-27. Influent POC load


Total
3137.5
4066.4
5242.4
6208.5
6280.4
-9.0
-9.0
-9.0
7197.6
6851.3
7305.9
7333.4
7508.5
7867.5
8003.9
8407.0
12174.2

No
Discharge
0.0
0.0
0.0
0.0
36.6
-9.0
-9.0
-9.0
97.4
117.7
131.8
161.1
163.3
269.4
344.1
339.5
627.7


Raw
215.0
215.0
215.0
215.0
215.0
215.0
215.0
-9.0
-9.0
215.0
215.0
215.0
215.0
215.0
215.0
-9.0
-9.0
-9.0
[metric


Raw
1426.9
1562.9
647.0
447.6
218.9
141.8
-9.0
-9.0
161.3
102.2
83.1
56.4
71.1
60.6
0.0
0.0
0.0


Primary
107.5
107.5
107.5
107.5
107.5
107.5
107.5
-9.0
-9.0
107.5
107.5
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
Advanced
Primary
70%
-9.0
-9.0
-9.0
-9.0
70.0
-9.0
-9.0
-9.0
70.0
70.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0

Secondary
92%
92.0
92.0
92.0
92.0
92.0
92.0
-9.0
92.0
92.0
92.0
92.0
92.0
92.0
92.0
92.0
92.0
92.0
default Influent TSS

Advanced
Primary
64.5
-9.0
-9.0
-9.0
-9.0
64.5
-9.0
-9.0
-9.0
64.5
64.5
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
tons per day; POC


Primary
819.8
1090.1
1870.1
1954.3
2238.0
2419.6
-9.0
-9.0
917.2
815.2
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0

Advanced
Primary
0.0
0.0
0.0
0.0
61.0
-9.0
-9.0
-9.0
1003.8
777.5
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0


Secondary
17.2
17.2
17.2
17.2
17.2
17.2
17.2
-9.0
17.2
17.2
17.2
17.2
17.2
17.2
17.2
17.2
17.2
17.2
Advanced
Secondary
97%
-9.0
-9.0
-9.0
-9.0
97.0
-9.0
-9.0
-9.0
97.0
97.0
97.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
Advanced
Treatment
98%
-9.0
-9.0
-9.0
98.0
98.0
98.0
-9.0
98.0
98.0
98.0
98.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
Less
than
Secondary
60%
50.0
50.0
50.0
50.0
50.5
-9.0
-9.0
60.0
60.5
60.0
60.0
60.0
60.0
60.0
60.0
60.0
-60.0
Greater
than
Secondary
57.5%
-9.0
-9.0
-9.0
98.0
97.7
-9.0
-9.0
-9.0
97.4
97.5
97.1
97.5
97.5
97.5
97.5
97.5
97.5
= 21 5.0 mg/L]

Advanced
Secondary
6.45
-9.0
-9.0
-9.0
-9.0
6.5
-9.0
-9.0
-9.0
6.5
6.5
6.5
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
= TSS x (POM:TSS)


Secondary
890.7
1413.4
2725.4
3793.3
3379.9
4653.0
-9.0
1460.4
2723.0
2654.1
2956.9
2966.9
3260.5
3454.5
3674.0
3631.3
4534.3

Advanced
Secondary
0.0
0.0
0.0
0.0
100.0
-9.0
-9.0
-9.0
1270.9
2324.5
2518.6
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0

Advanced
Treatment
4.3
-9.0
-9.0
-9.0
4.3
4.3
4.3
-9.0
4.3
4.3
4.3
4.3
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
x (C:DW)]

Advanced
Treatment
0.0
0.0
0.0
13.3
246.0
119.6
-9.0
2026.6
1024.1
201.9
191.9
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
Less
than
Secondary
86.0
107.5
107.5
107.5
107.5
106.4
-9.0
-9.0
86.0
85.0
86.0
86.0
86.0
86.0
86.0
86.0
86.0
86.0

Less
than
Secondary
819.8
1090.1
1870.1
1954.3
2299.0
-9.0
-9.0
3398.4
1921.0
1653.6
1423.6
1432.8
1230.1
1173.6
962 2
761.2
244.3
Greater
than
Secondary
5.38
-9.0
-9.0
-9.0
4.3
4.9
-9.0
-9.0
-0.3
5.5
5.4
6.3
5.4
5.4
5.4
5.4
5.4
5.4

Greater
than
Secondary
0.0
0.0
0.0
13.3
346.0
-9.0
-9.0
-9.0
2295.0
2323.6
2710.5
2716.1
2783.5
2909.3
3023.6
3674.9
6767.9

                                                                        B-11

-------
Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
Table B-28.  Effluent POC load [metric tons per day; POC = TSS x (POM:TSS) x (C:DW)]
Year
1940
1940
1950
1962
1968
1972
1973
1974
1976
1978
1980
1982
1984
1986
1988
1992
1996
2016
Table B-29


Year
Default:
1940
1950
1962
1968
1972
1973
1974
1976
1978
1980
1982
1984
1986
1988
1992
1996
2016
Table B-30
Total
3137.5
1944.0
2266.9
1876.1
1799.8
1724.5
-9.0
-9.0
-9.0
1244.1
1069.0
994.5
955.5
902.8
883.6
747.4
668.1
564.3
. POC


Total

38.0
44.3
64.2
71.0
72.5
-9.0
-9.0
-9.0
82.7
84.4
86.4
87.0
88.0
88.8
90.7
92.1
95.4
No
Discharge Raw
0.0
0.0
0.0
0.0
0.0
0.0
-9.0
-9.0
-9.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
removal

No
Discharge
100*
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
100.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
. Effluent POC
1426
1426
1562
647
447
218
141
-9
-9
161
102
83
56
71
60
0
0
0
.9
.9
.9
.0
.6
.9
.8
.0
.0
.3
.2
.1
.4
.1
.6
.0
.0
.0
Primary
819.8
453.4
602.9
1034.2
1080.8
1237.7
1338.1
-9.0
-9.0
507.2
450.8
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
Advanced
Primary
0.0
0.0
0.0
0.0
0.0
20.2
-9.0
-9.0
-9.0
333.1
258 0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
Secondary
890.7
63.7
101.1
194.9
271.3
241.7
332.8
-9.0
104.4
194.7
189.8
211.5
212.2
233.2
247.1
262.7
259.7
324.3
Advanced
Secondary
0.0
0.0
0.0
0.0
0.0
2.7
-9.0
-9.0
-9.0
34.1
62.3
67.5
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
Advanced
Treatment
0.0
0.0
0.0
0.0
0.2
3.3
1.6
-9.0
27.0
13.7
2.7
2.6
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
Less
than
Secondary
819.8
453.4
602.9
1034.2
1080.8
1257.9
-9.0
-9.0
1503.5
840.3
731.6
629.8
633.9
544.2
519.2
425.7
336.8
108.1
Greater
than
Secondary
0.0
0.0
0.0
0.0
0.2
6.0
-9.0
-9.0
-9.0
47.7
45.3
70.1
53.0
54.3
56.7
59.0
71.7
132.0
efficiency [Percent]




Raw

-9
-9
-9
-9
-9
-9
-9
-9
-9
-9
0
-9
-9
-9
-9
-9
-9
0%
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
concentration


Primary
44.7%
44.7
44.7
44.7
44.7
44 7
44.7
-9.0
-9.0
44.7
44.7
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0

Advanced
Primary
66.8%
-9.0
-9.0
-9.0
-9.0
66.8
-9.0
-9.0
-9.0
66.8
66.8
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0


Secondary
92.8%
92.8
92.8
92.8
92.8
92.8
92.8
-9.0
92.8
92.8
92.8
92.8
92.8
92.8
92.8
92.8
92.8
92.8

Advanced
Secondary
97.3%
-9.0
-9.0
-9.0
-9.0
97.3
-9.0
-9.0
-9.0
97.3
97.3
97.3
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0

Advanced
Treatment
58.7*
-9.0
-9.0
-9.0
98.7
98.7
98.7
-9.0
98.7
98.7
98.7
98.7
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
Less
than
Secondary
55.8*
44.7
44.7
44.7
44.7
45.3
-9.0
-9.0
55.8
56.3
55.8
55.8
55.8
55.8
55.8
55.8
55.8
55.8
Greater
than
Secondary
98.0%
-9.0
-9.0
-9.0
98.7
98.3
-9.0
-9.0
-9.0
97.9
98.0
97.4
98.0
98.0
98.0
98.0
98.0
98.0
[mg/L; POC = TSS x (POM:TSS) x (C:DW);
default effluent POC = 70.95 mg/L;


Year


Total

No
Discharge
Default POM: TSS (mg/mg) 0.00
Default Effluent POC
1940
1950
1962
1968
1972
1973
1974
1976
1978
1980
1982
1984
1986
1988
1992
1996
2016
44.0
39.6
25.4
20.6
19.5
-9.0
-9.0
-9.0
12.3
11.1
9.7
9.2
8.5
8.0
6.6
5.6
3.3
(mg/L) 0.0
-9.0
-9.0
-9.0
-9.0
0.0
-9.0
-9.0
-9.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0




Raw
0.
75
70.95
71
71
71
71
71
71
-9
-9
71
71
71
71
71
71
-9
-9
-9
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0


Primary
0.83
39.24
39.2
39.2
39.2
39.2
39.2
39.2
-9.0
-9.0
39.2
39.2
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
C:DW=0.44 mg C/mg DW]

Advanced
Primary
0.83
23.54
-9.0
-9.0
-9.0
-9.0
23.5
-9.0
-9.0
-9.0
23.5
23.5
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0


Secondary
0.67
5.07
5.1
5.1
5.1
5.1
5.1
5.1
-9.0
5.1
5.1
5.1
5.1
5.1
5.1
5.1
5.1
5.1
5.1

Advanced
Secondary
0,67
1.90
-9.0
-9.0
-9.0
-9.0
1.9
-9.0
-9.0
-9.0
1.9
1.9
1.9
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0

Advanced
Treatment
0.50
0.95
-9.0
-9.0
-9.0
0.9
0.9
0.9
-9.0
0.9
0.9
0.9
0.9
-9.0
-9.0
-9.0
-9.0
-9.0
-9.0
Less
than
Secondary
0.83
31.39
39.2
39.2
39.2
39.2
38.8
-9.0
-9.0
31.4
31.0
31.4
31.4
31.4
31.4
31.4
31.4
31.4
31.4
Greater
than
Secondary
0.585
1.38
-9.0
-9.0
-9.0
0.9
1.2
-9.0
-9.0
-0.3
1.5
1.4
1.8
1.4
1.4
1.4
1.4
1.4
1.4

B-12

-------
                     Appendix B: National Municipal Wastewater Inventory and Infrastructure, 1940 to 2016
Table B-31.  Influent and effluent characteristics for CBOD5, CBODU, TKN, and BODy
5-day Carbonaceous BOD (CBOD )

Type Category
1. No Discharge
2 . Raw
3 . Primary
4 . Advanced Primary
5 . Secondary
6 . Advanced Secondary
7 . Advanced Treatment
8. Secondary (No. 6 + No. 7)
Ultimate Carbonaceous BOD (CBODu)

Type Category
1. No Discharge
2. Raw
3 . Primary
4 . Advanced Primary
5 . Secondary
6 . Advanced Secondary
7 . Advanced Treatment
8. Secondary (No. 6 + No . 7 )
Influent
mg/L
215.00
215.00
215.00
215.00
215.00
215.00
215.00
215.00
215.00
Effluent
mg/L
0.00
215.00
139.75
107.50
32.25
21.50
10.75
123.63
16.12
Removal
Percent
100.0
0.0
35.0
50.0
85.0
90.0
95.0
42.5
92.5
Conversion
Factor
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
Conversion Factor =CBODU:BODS ratios
Influent
mg/L
258.00
258.00
258.00
258.00
258. 00
258.00
258.00
258. 00
258.00
Effluent
mg/L
0.00
258.00
223.60
172.00
91.59
61.06
32.25
197.80
46.76
Removal
Percent
100.0
0.0
13.3
33.3
64.5
76.3
87.5
23.3
81.9
Conversion
Factor
1.000
1.200
1.600
1.600
2.840
2.840
3.000
1.600
2.900
Total Kjedhal Nitrogen (TKN) Organic-N + NH3-N

Type Category
1. No Discharge
2. Raw
3 . Primary
4 . Advanced Primary
5 . Secondary
6 . Advanced Secondary
7 . Advanced Treatment
8. Secondary (No. 6 + No. 7)
Influent
mg/L
0.30
30.30
30.30
30.30
30.30
30.30
30.30
30.30
30.30
Effluent
mg/L
0.00
30.30
23.63
23.63
19.39
6.67
5.15
23.63
5.91
Removal
Percent
100.0
0.0
22.0
22.0
36.0
78.0
83.0
22.0
80.5
Conversion
Fact
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000

                                                                                       B-13

-------
Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
Nitrogenous BOD NBOD = 4.57x TKN Conversion

Type Category
1. No Discharge
2 . Raw
3 . Primary
4 . Advanced Primary
5 . Secondary
6 . Advanced Secondary
7 . Advanced Treatment
8. Secondary (No. 6 +
Ultimate BOD (BOD} CBODu

Type Category
1. No Discharge
2 . Raw
3 . Primary
4 . Advanced Primary
5 . Secondary
6 . Advanced Secondary
7 . Advanced Treatment
8. Secondary (No. 6 +
Influent
mg/L
138.47
138.47
138.47
138.47
138.47
138.47
138.47
No. 4) 138.47
No. 7) 138.47
+ NBOD
Influent
mg/L
396.47
396.47
396.47
396.47
396.47
396.47
396.47
No. 4) 396.47
No. 7) 396.47
factor = 4. 75 mg
Effluent
mg/L
0.00
138.47
108.01
108.01
88.62
30.46
23.54
108.01
27.00

Effluent
mg/L
0.00
396.47
331.61
280.01
180.21
91.52
55.79
305.81
73.76
O2pergN
Removal
Percent
100.0
0.0
22.0
22.0
36.0
78.0
83.0
22.0
80.5

Removal
Percent
100.0
0.0
16.4
29.4
54.5
76.9
85.9
22.9
81.4

Conversion
Factor
4.570
4.570
4.570
4.570
4.570
4.570
4.570
4.570
4.570

Conversion
Factor
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
B-14

-------
                     Appendix B: National Municipal Wastewater Inventory and Infrastructure, 1940 to 2016
Table B-32.  Influent and effluent characteristics for TSS and POC
Total Suspended Solids (TSS)   TSS - Volatile SS + Non-volatile SS (fixed) = Organic SS + Inorganic SS
Influent
Type Category mg/L
1.
2.
3.
4.
5.
6.
7.
8.
9.
No Discharge
Raw
Primary
Advanced Primary
Secondary
Advanced Secondary
Advanced Treatment
Secondary (No. 6 + No . 7 )
215.
215.
215.
215.
215.
215.
215.
215.
215.
00
00
00
00
00
00
00
00
00
Effluent
mg/L
0
215
107
64
17
6
4
86
5
.00
.00
.50
.50
.20
.45
.30
.00
.38
Removal Conversion
Percent Fact
100.
0.
50.
70.
92.
97.
98.
60.
97.
0
0
0
0
0
0
0
0
5
1
1
1
1
1
1
1
1
1
.000
.000
.000
.000
.000
.000
.000
.000
.000
Paniculate Organic Carbon (POC)
POC = TSS x [(POM:TSS) x C:DW)]
POM:TSS = fraction of Particulate Organic Matter (Volatile SS:TSS)
C:DW = Carbon: Dry Weight = 0.44 mg C per mg DW
Conversion Factor = (POM:TSS) x (C:DW)
Type Category POM:
1.
2.
3.
4.
5.
6.
7.
8.
9,
No Discharge
Raw
Primary
Advanced Primary
Secondary
Advanced Secondary
Advanced Treatment
Secondary (No . 6 + No . 7 )
0
0
0
0
0
0
0
0
0
TSS
.00
.75
.83
.83
.67
.67
.50
.83
.58
Influent Effluent
mg / L mg / L
70
70
70
70
70
70
70
70
70
.95
.95
.95
.95
.95
.95
.95
.95
.95
0
70
39
23
5
1
0
31
1
.00
.95
.24
.54
.07
.90
.95
.39
.38
Removal Conversion
Percent Factor
100
0
44
66
92
97
98
55
98
.0
.0
.7
.8
.8
.3
.7
.8
.0
0
0
0
0
0
0
0
0
0
.330
.330
.365
.365
.295
.295
.220
.365
.257
                                                                                          B-15

-------
Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
Table B-33. Middle population projections of POTW loads of CBOD5, CBODU, NBOD and BOD^ 1996-2050
Population
Served
Year
1940
1950
1962
1968
1972
1978
1982
1988
1992
1996
1991
1998
1999
2000
2001
2002
2003
2004
2005
2006
2007
2008
2009
2010
2011
2012
2013
2014
2015
2016
2017
2018
2019
2020
2021
2022
2023
2024
2025
2026
2027
2028
2029
2030
2031
2032
2033
2034
2035
2036
2037
2038
2039
2040
2041
2042
2043
2044
2045
2046
2047
2048
2049
2050
Population
132164569
151325798
NA
NA
NA
219555000
230075000
227258220
246928467
NA
267645000
270002000
272330000
274634000
276918000
279189000
281452000
283713000
285981000
288269000
290583000
292928000
295306000
297716000
300157000
302624000
305112000
307617000
310134000
312658000
315185000
317711000
320231000
322742000
325239000
327720000
330183000
332626000
335050000
337454000
339839000
342208000
344560000
346899000
349227000
351544000
353853000
356157000
358457000
360756000
363056000
365358000
367666000
369980000
372303000
374636000
376981000
379339000
381713000
384106000
386522000
388962000
391431000
393931000
Percent
53.
60.



70.
71.
78.
73.

72.
73.
74.
75.
75.
76.
77.
78
79.
80
80
81.
82
83.
84
84
,5%
6%
NA
NA
NA
.7%
7%
.1%
,1%
NA
.6%
,4%
,3%
, 1%
,9%
,7%
,5%
.4%
.2%
.0%
8%
.6%
.5%
,3%
.1%
.9%
85.7%
86
87.
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
88
.6%
.4%
.2%
.2%
.2%
.2%
.2%
.2%
.2%
.2%
.2%
.2%
.2%
.2%
.2%
.2%
.2%
.2%
.2%
.2%
.2%
.2%
.2%
.2%
.2%
.2%
.2%
.2%
.2%
.2%
.2%
.2%
.2%
.2%
.2%
.2%
.2%
Effluent
CBOD5
mt/day -,
6344
7526
6883
6932
6768
5510
4380
4460
4034
3812
3853
3877
3899
3919
3938
3954
3970
3983
3996
4006
4016
4025
4032
4037
4042
4045
4046
4046
4044
4040
4073
4106
4138
4171
4203
4235
4267
4298
4330
4361
4391
4422
4452
4483
4513
4543
4573
4602
4632
4662
4691
4721
4751
4781
4811
4841
4871
4902
4933
4964
4995
5026
5058
5090
Load Effluent
CBOL\ CBODu
^ Removal
33.
38.
56.
63.
64.
74.
79.
81.
83.
85.
85.
85.
85.
85.
86.
86.
86.
86.
86.
87.
87.
87.
87.
87.
88.
88.
88.
88.
88.
89.
89.
89.
89.
89.
89.
89.
89.
89.
89.
89.
89.
89.
89.
89.
89.
89.
89.
89.
89.
89.
89.
89.
89.
89.
89.
89.
89.
89.
89.
89.
89.
89.
89.
89.
3%
9%
7%
2%
4%
1%
3%
3%
4%
0%
2%
4%
6%
8%
0%
3%
5%
7%
9%
1%
3%
5%
7%
9%
1%
3%
5%
7%
9%
1%
1%
1%
1%
1%
1%
1%
1%
1%
1%
1%
1%
1%
1%
1%
1%
1%
1%
1%
1%
1%
1%
1%
1%
1%
1%
1%
1%
1%
1%
1%
1%
1%
1%
1%
mt/day !
8922
10943
11765
12689
12558
11621
9582
9869
9418
9232
9375
9478
9579
9678
9774
9868
9960
10050
10139
10226
10313
10398
10482
10566
10648
10730
10809
10887
10963
11037
11126
11215
11304
11393
11481
11569
11656
11742
11827
11912
11996
12080
12163
12246
12328
12410
12491
12573
12654
12735
12816
12897
12979
13060
13142
13225
13308
13391
13475
13559
13644
13731
13818
13906
Load
CBODu
fc Removal
21.
26.
38.
43.
45.
54.
62.
65.
67.
69.
70.
70.
70.
70.
71.
71.
71.
71.
72.
72.
72.
73.
73.
73.
73.
74.
74.
74.
74.
75.
75.
75.
75.
75.
75.
75.
75.
75.
75.
75.
75.
75.
75.
75.
75.
75.
75
75.
75.
75.
75.
75.
75.
75.
75
75.
75
75
75.
75
75
75
75
75
8%
0%
3%
8%
0%
4%
3%
5%
6%
8%
1%
3%
6%
9%
1%
4%
7%
9%
2%
5%
8%
0%
3%
6%
8%
1%
4%
6%
9%
2%
2%
2%
2%
2%
2%
.2%
2%
2%
2%
2%
.2%
2%
.2%
.2%
2%
.2%
2%
.2%
.2%
.2%
.2%
.2%
.2%
.2%
.2%
.2%
.2%
.2%
.2%
.2%
.2%
.2%
.2%
.2%
Effluent
NBOD
mt/day «
5146
6475
7514
8591
8273
7526
7168
7327
7205
7093
7208
7294
7378
7460
7541
7620
7698
7775
7851
7926
8000
8074
8148
8221
8294
8366
8437
8507
8576
8644
8714
8784
8853
8923
8992
9060
9129
9196
9263
9330
9396
9461
9526
9591
9655
9719
9783
9847
9910
9974
10037
10101
10165
10229
10293
10358
10422
10488
10553
10619
10686
10754
10822
10891
Load
NBOD
; Removal
16.0%
18.4%
26.6%
29.1%
32.5%
46.4%
49.7%
52.3%
53.9%
56.8%
57.1%
57.5%
57.8%
58.2%
58.5%
58.9%
59.2%
59.6%
59 9%
60.3%
60.6%
61.0%
61.3%
61.7%
62.0%
62.4%
62.7%
63.1%
63.4%
63.8%
63.8%
63.8%
63.8%
63.8%
63 8%
63.8%
63.8%
63.8%
63.8%
63.8%
63.8%
63.8%
63.8%
63.8%
63.8%
63.8%
63.8%
63.8%
63.8%
63.8%
63.8%
63 8%
63.8%
63.8%
63.8%
63.8%
63.8%
63.8%
63.8%
63.8%
63.8%
63.8%
63.8%
63.8%
Effluent
BODu
mt/day ?
14068
17419
19278
21281
20831
19147
16750
17196
16623
16325
16583
16772
16957
17138
17315
17489
17658
17825
17990
18152
18313
18472
18631
18787
18942
19096
19247
19395
19540
19681
19840
19999
20158
20316
20473
20629
20784
20938
21090
21242
21392
21541
21689
21836
21983
22129
22274
22419
22564
22709
22853
22998
23144
23289
23435
23582
23730
23878
24028
24178
24331
24484
24640
24797
Load
BODu
i Removal
19.8%
23.3%
34.2%
38.7%
40.6%
51.6%
57.8%
60.9%
62.8%
65.2%
65.5%
65.8%
66.1%
66.4%
66.7%
67.0%
67.3%
67.6%
67.9%
68.2%
68.5%
68.8%
69.1%
69.4%
69.7%
70.0%
70.3%
70.6%
70.9%
71.2%
71.2%
71.2%
71.2%
71.2%
71.2%
71.2%
71.2%
71.2%
71.2%
71.2%
71.2%
71.2%
71.2%
71.2%
71.2%
71.2%
71.2%
71.2%
71.2%
71.2%
71.2%
71.2%
71.2%
71.2%
71.2%
71.2%
71.2%
71.2%
71.2%
71.2%
71.2%
71.2%
71.2%
71.2%

B-16

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                      Appendix B: National Municipal Wastewater Inventory and Infrastructure, 1940 to 2016
Table B-34. Inventory of POTW facilities in 1972 in the United States (USEPA, 1972)
                                                          Flow Range (MGD)
Facility Type
None (Raw)
Minor
Primary
Settling tank (no details)
Septic tank
Imhoff tanks
Mechanical cleaned tanks474
Plain, hop-bottom tanks48
Unknown
Intermediate
Secondary
Other
Activated sludge
Extended aeration
High rate trickling filter
Standard rate trickling filter
Intermediate sand filter
Land application
Oxidation pond
Unknown filter
Unknown
Tertiary
Unknown category
0-1
141
17
1523
92
252
624
264
3
33
18
10839
547
1151
1568
1231
1414
483
70
3638
249
488
373
18
1-5
9
4
312
16
3
19
59
0
7
21
1220
19
306
44
417
201
4
6
115
37
71
44
21
5-10
0
3
60
0
0
1
1
0
0
4
172
4
80
4
37
22
1
1
6
7
10
6
4
10-25
0
0
1
0
0
0
60
3
0
0
2
0
1
1
0
0
0
0
0
0
0
1
0
>25
4
0
76
6
1
2
40
2
4
14
156
3
82
4
36
8
0
0
3
2
18
5
14
Unknown
2111
20
558
17
394
36
898
56
69
7
1646
285
123
102
77
93
77
65
705
39
80
32
7
Total
2265
44
2530
131
650
682


113
64
14035
858
1743
1723
1798
1738
565
142
4467
334
667
461
64
 TOTAL
                                    12911
                                              1610
                                                        245
                                                                          255
                                                                                  4374
                                                                                          19399
                                                                                           B-17

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
Table B-35.  Population served (millions) by POTW facilities in 1972 in the United States (USEPA, 1972)
                                                           Flow Range (MGD)
Facility Type
None (Raw)
Minor
Primary
Settling tank (no details)
Septic tank
Imhoff tanks
Mechanical cleaned tanks
Plain, hop-bottom tanks
Unknown
Intermediate
Secondary
Other
Activated sludge
Extended aeration
High rate trickling filter
Standard rate trickling filter
Intermediate sand filter
Land application
Oxidation pond
Unknown filter
Unknown
Tertiary
Unknown category
TOTAL
0-1
0.
0.
3.
0.
0.
1.
1.
0.
0.
0.
22.
0.
4.
1.
4.
4,
0.
0.
4.
0.
1.
0,
0
26.
,2
,1
5
.2
.2
1
.7
,2
.1
.1
.0
.3
,1
.4
,9
.4
.3
.1
.7
.6
.2
.5
.1
.4
1
0
0
5
0
0
0
4
0
0
0
19
0
5
0
7
2
0
0
1
0
1
0
0
26
-5
.2
.1
.4
.3
.1
.2
.5
.2
.1
.4
.2
.2
.4
.5
.0
.9
.1
.1
.3
.7
.0
.7
.4
.0
5-10
0.
0.
2.
0.
0.
0.
2.
0.
0.
0.
8.
0.
4.
0.
1.
1.
0.
0.
0.
0.
0.
0.
0.
11.
0
2
6
0
0
0
6
0
0
2
6
1
0
6
7
0
1
1
2
3
5
2
2
8
10-25
0
0
0
0
0
0
0
0
0
0
1
0
0
1
0
0
0
0
0
0
0
0
0
1
.0
.0
.2
.0
.0
.0
.2
.0
.0
.0
.4
.0
.3
.1
.0
.0
.0
.0
.0
.0
.0
.2
.0
.8
>25 Unknown
1.
0.
21.
1.
0.
0.
16.
1.
2.
5.
46.
0.
29.
0.
4.
0.
0.
0.
0.
2.
7.
1.
5.
75.
8
0
8
0
4
5
1
8
0
1
.1
.2
.1
4
.8
.7
.0
0
.3
,8
.8
.1
.1
.9
3.
0.
12.
0.
0.
0.
4.
0,
6.
0.
5.
1,
0.
0,
1.
0.
0,
0.
0.
0
0.
0
0
21
.1
.7
,4
,6
.4
.1
.7
.0
,6
.1
.0
.4
.4
.1
.2
.3
.1
.2
.8
.1
.4
.1
.1
.4
Total
5
1
45
2
1
1
29
2
8
5
102
2
43
4
19
9
0
0
7
4
10
2
5
163
.3
.1
.9
.1
.1
.9
.8
.2
.8
.9
.3
.2
.3
.1
.6
.3
.6
.5
.3
.5
.9
.8
.9
.3
B-18

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                        Appendix B:  National Municipal Wastewater Inventory and Infrastructure, 1940 to 2016


Table B-36.  Data sources for trends in municipal wastewater treatment, 1940-2016

1940      Population served data from FWPCA (1970). Inventory of municipal wastewater facilities from NCWQ (1976).
          Data not available for no-discharge category;  assumed zero for calculation of totals.
1950      Population served data and inventory of municipal wastewater facilities from USPHS (1951). Data not available
          for no-discharge category; assumed zero for calculation of totals.

1962      Population served data and inventory of municipal wastewater facilities from USEPA(1974). Data not available
          for no-discharge category; assumed zero for calculation of totals.
1968      Population served data and inventory of municipal wastewater facilities from USEPA (1974) and USDOI (1970).
          Data not available for no-discharge category;  assumed zero for calculation of totals.

1972      Population served data from ASIWPCA( 1984). Inventory of municipal wastewater facilities from EPA (1972).
          Significant differences in population served data between USEPA (1972) (102.3 million) and ASIWPCA (1984)
          (76.3 million) for secondary treatment.  USEPA (1972) includes population served by oxidation ponds (7.5
          million, 4467 facilities) and land application (0.5 million, 142 facilities) in the total population served of 102.3
          million for "secondary" treatment. ASIWPCA (1984) reports 76.2 million served by secondary with no break-
          down of categories of facilities given. To be consistent with trends in population served by secondary plants
          reported for 1968 (85.6 million) and  1978 (56.3 million), the population served data from ASIWPCA (1984) is
          used to estimate wastewater flow, influent and effluent loading of BOD5  for 1972.

1973      Population served data and inventory of municipal wastewater facilities from USEPA (1974). Data not available
          for no-discharge category; assumed zero for calculation of totals.

1974      Inventory of municipal wastewater facilities from NCWQ (1976). Population served data not available for any
          category.

1976      Population served data and inventory of municipal wastewater facilities from USEPA (1976). Data not available
          for raw population served and effluent flow. Data not available for no-discharge category; assumed zero for
          calculation of totals.

1978      Population served data, inventory of municipal wastewater facilities, wastewater effluent flow (as 1000 m3/
          day), influent and effluent BOD loading data from USEPA (1978). Effluent flow from USEPA (1978) converted
          from 1000 mVday to mgd using conversion factor of 0.2642. Population served by raw discharge reported as
          364,000 persons in Table 10 of the EPA (1978) Needs Survey. To be consistent with trends in population served
          by raw discharge for data reported for 1968 (10.1 million), 1972 (4.9 million), 1980 (2.3 million) and 1982 (1.9
          million), the value for 1978 given in Table 10 appears to be in error by factor of 10. The population served by
          raw discharge for 1978 is increased by a factor of 10 to 3.64 million  for this study. Data reported in USEPA
          (1978) for effluent flow, influent and effluent BOD loading for raw discharge, computed from erroneous
          population served data, is not used.  The number of facilities reported in USEPA (1978) as raw discharge
          systems (n=91) is not consistent with trend of 2,265 raw facilities reported for 1972 and 237 raw facilities
          reported for 1982. There is a possible factor of 10 error in Needs Survey data table since n=910 raw facilities
          would be consistent with the decreasing trend in the number of raw facilities from 1972 to 1982.

1980      Population served data, inventory of municipal wastewater facilities, wastewater effluent flow (as 1000 m3/
          day), influent and effluent BOD loading data and percent BOD  removal from USEPA (1980). Effluent flow from
                                     5                          5
          USEPA (1980) converted from 1000 mVday to mgd by conversion factor of 0.2642. Data not available for raw
          effluent flow.

                                                                                                      B- 19

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment


1982     Population served data, inventory of municipal wastewater facilities, wastewater effluent flow (as 1000 m3/
         day), influent and effluent BOD loading data, and percent BOD removal from USEPA( 1982). Effluent flow
                                     5                           5
         from USEPA(1982) converted from 1000 mVday to mgd by conversion factor of 0.2642. Data not available for
         raw effluent flow.

1984     Population served data, inventory of municipal wastewater facilities, wastewater effluent flow (as mgd),
         influent and effluent BOD loading data, and percent BOD removal from USEPA (1984). Data not available for
                                5                            5
         raw effluent flow.

1986     Population served data, inventory of municipal wastewater facilities, wastewater effluent flow (as mgd),
         influent and effluent BOD loading data, and percent BOD removal from USEPA (1986). Data not available for
                                5                            5
         raw effluent flow.

1988     Population served data and inventory of municipal wastewater facilities from USEPA (1989).

1992     Population served data and inventory of municipal wastewater facilities from USEPA (1993).

1996     Population served data and inventory of municipal wastewater facilities from USEPA (1997).

2016     Projection of population served and inventory of municipal wastewater facilities for the year 2016 from USEPA
         (1997).
Table B-37.  Municipal wastewater treatment categories presented in Appendix B tables

  Total                  Sum of all treatment categories
  No Discharge          Municipal wastewater treatment facilities that do not discharge effluent to surface waters;
                        most no-discharge facilities are oxidation or stabilization ponds designed for evaporation and
                        or infiltration; no discharge also includes facilities designed for recycling and reuse or spray
                        irrigation systems.
  Raw                  Collection system only; no treatment provided; effluent = influent
  Primary               Primary treatment
  Advanced Primary      Advanced primary treatment
  Secondary           Greater than secondary is the sum of advanced secondary + advanced treatment
B-20

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                        Appendix B: National Municipal Wastewater Inventory and Infrastructure, 1940 to 2016
Data Sources
The primary data sources for the analysis of POTW wastewater trends included the municipal wastewater inventories
published by the USPHS from 1940 through 1968 (USPHS, 1951; NCWQ, 1976; USEPA, 1974) and USEPA' s Clean Water
Needs Surveys (CWNS) conducted from 1973 through 1996 (USEPA, 1976,1978,1980,1982,1984,1986,1989,1993,1997).
Each data source reported the number of municipal wastewater treatment plants and the population served by raw,
primary, advanced primary, secondary, advanced secondary and advanced treatment levels of wastewater treatment.

Where data was available to differentiate primary from advanced primary and advanced secondary from advanced
treatment, the data was added to define "less than secondary" and "greater than secondary" categories. For some of the
USEPA Needs Surveys, facility  inventories and population served data was compiled as "less than secondary" and
"better than secondary"; data was not available to differentiate primary and advanced primary or advanced secondary
and advanced treatment levels of wastewater treatment.  The USEPA Clean Water Needs Surveys also compiled effluent
flow, influent and effluent loading, and percent removal of BOD in the reports for 1978,1980,1982,1984,and  1986. For
the years in which this data was not available, wastewater effluent flow, influent and effluent BOD5, CBODu, TKN, NBOD,
BODu, TSS, and POC loading data was estimated based on (a) population served; (b) constant normalized flow rate of 165
gallons per capita per day (gpcd); (c) influent BOD5 of 215 mg/L and effluent BOD5 removal efficiencies; (d) effluent ratios
of CBODu: BOD5; (e) influent TKN of 30.3 mg/L and effluent TKN removal efficiencies; (f) influent TSS of 215 mg/L and
effluent TSS removal efficiencies; and (g) effluent ratios of the particulate organic fraction of TSS and a constant ratio of
carbon:dry weight (C:DW).

Constant Per Capita Flow Rate
The constant per capita flow rate of 165 gpcd is based on the mean (n=5) of the total population served and total waste-
water flow data compiled in the USEPA Clean Water Needs Surveys for 1978 through 1986 (see Table B-4). The rate of
per capita flow, ranging from 160 to 173 gpcd, includes residential (55 percent), commercial and industrial (20 percent),
stormwater (4 percent) and infiltration and inflow (20 percent) components of wastewater flow (see AMSA, 1997). The
constant per capita flow rate of 165 gpcd used in this study to estimate trends of municipal wastewater flow and loading is
identical to the typical United States average (165 gpcd) within the wide range (65-290 gpcd) of municipal water use that
accounts for residential, commercial and industrial, and public water uses in the United States (see Metcalf and Eddy,
1991).  Public wastewater flow, obviously related to public water withdrawals, can range from 70 to 130 percent of the rate
of water withdrawal with a reasonable assumption being that wastewater flow is approximately equal to withdrawals by
water supplies (Steel, 1960).

Influent BOD.
             D
The influent BOD5 concentration of 215 mg/L, consistent with many other estimates of raw wastewater strength (e.g.,
AMSA, 1997; Tetra Tech, 1999;  Metcalf and Eddy, 1991), is based on the mean (n=5) nationally aggregated ratio of the
total influent BOD5 loading rate  normalized to total wastewater flow reported in the USEPA Clean Water Needs Surveys
for 1978 through 1986 (see Table B-9). The influent concentration, ranging from 209 to 229 mg/L for these years, includes
the residential, commercial and industrial and infiltration and inflow contributions to the total influent BOD5 load to
municipal wastewater treatment plants. Using the influent BOD5 concentration of 215 mg/L and the normalized flow rate of
165 gpcd, the normalized influent BOD5 loading rate (0.296 Ib BOD5 per person per day) accounts for the nationally
aggregated mixture of domestic,  commercial and industrial and infiltration and inflow components of wastewater. The
loading rate used in this analysis is almost a factor of two greater than the typical textbook value for the "population
equivalent" (PE) of 1 PE = 0.17 Ib BOD5 per person per day. Typical textbook values account for only the average per
capita residential load contributed by combined stormwater and domestic wastewater; the industrial and commercial
component is not included (Fair et al., 1971).
                                                                                                     B-21

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment

Effluent BOD,
The effluent BOD5 loading rates, estimated using removal efficiencies typically assigned for NPDES permit limits and
wastewater treatment plant design assumptions, are based on an influent concentration of 215 mg/L and removal efficien-
cies (as percentage) assigned to each level of treatment.  The BOD5 removal efficiencies assumed for primary (35 percent),
advanced primary (50 percent), and less than secondary (42.5 percent), although somewhat lower than removal efficien-
cies reported for primary (41 percent), advanced primary (64 percent), and less than secondary (54-57 percent) based on
PCS data compiled for the USEPA Clean Water Needs Surveys for 1976, 1978, and 1982, are consistent with typical
textbook values reported for BOD5 removal efficiency for primary treatment plants (see Metcalf and Eddy, 1991).

The BOD5 removal efficiencies assumed for secondary (85 percent), advanced secondary (90 percent), advanced waste
treatment (95 percent), and better than secondary (92.5 percent) are comparable to removal efficiencies for  secondary (82-
86 percent), advanced secondary (89-92 percent), advanced waste treatment (87-94 percent), and better than secondary
(94 percent) based on PCS data compiled in the Clean Water Needs Surveys for 1976,1978, and 1982. The removal
efficiencies for secondary, advanced secondary and advanced waste treatment used in this study,  consistent with
textbook design values, are based on an influent concentration of 215 mg/L and the ranges of removal efficiencies and
effluent concentrations of BOD5 used to define these treatment categories  in the USEPA Clean Water Needs Survey for
1978 (USEPA, 1978).

Secondary treatment was defined in the 1978 Needs Survey by a BOD5 effluent concentration of 30 mg/L with the removal
efficiency ranging from 84 to 89 percent (USEPA, 1978). Advanced secondary was defined by an effluent BOD5 range of
10-30 mg/L, and advanced waste treatment was defined by an effluent BOD5 concentration less than, or equal to, 10 mg/L
(USEPA, 1978). Assuming a mean influent concentration of 215 mg/L, a mid-range effluent concentration of 20 mg/L for
advanced secondary, and 10 mg/L for advanced waste treatment, BOD5 removal efficiencies were assigned as 90 percent
for advanced secondary and 95 percent for advanced waste treatment.

Ultimate BOD
Influent and effluent loading rates of the ultimate carbonaceous BOD (CBODu) were estimated from the BOD5  loads and
conversion ratios of ultimate to 5-day BOD (CBODu:CBOD5) defined for each level of municipal treatment (Leo et al., 1984;
Thomann and Mueller, 1987).  Since it is impossible to determine whether historical BOD effluent loads included the
                                                                             5
suppression of nitrification (see Hall and Foxen, 1984), it is assumed that BOD5 is approximately equal to CBOD5 (see
Lung, 1998).
Loading rates for the nitrogenous component of oxygen demand (NBOD) are  estimated from the influent concentration
and removal efficiencies of oxidizable nitrogen (TKN) for each level of treatment and the oxygen: nitrogen ratio of 4.57 g O2
pergN. Removal efficiencies for TKN are based on data compiled by: (a) Gunnerson et al. (1982) for primary (22
percent); (b) advanced primary (22 percent) assumed the same  as primary, and (c) secondary (36 percent). TKN removal
efficiencies assigned for (d) advanced secondary (78 percent);  and (e) advanced treatment (83 percent) are within the 25*
and 75th percentile ranges of data compiled for advanced secondary (72-92 percent) and advanced treatment (79-95
percent) from AMSA (1997).  Less than secondary removal efficiencies are assigned as the mean of primary and advanced
primary removal percentages. Better than secondary removal  efficiencies are assigned as the mean of advanced second-
ary and advanced treatment removal percentages.

The total ultimate BOD (BODu) load is calculated as the sum of the ultimate carbonaceous (CBODJ and nitrogenous
(NBOD) components of the effluent load of oxygen demanding substances. Table B-31 summarizes the influent and
effluent concentrations and removal efficiencies assumed for calculation of the loads of BOD5, CBODu, TKN, NBOD and
BOD.
B-22

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                        Appendix B: National Municipal Wastewater Inventory and Infrastructure,  1940 to 2016


Projection of Effluent Load Trends from 1996-2050
Projections of effluent loading trends for ultimate BOD are based on (a) U.S. Census Bureau "middle" population projec-
tions from 1996-2050 (U.S. Census, 1996); (b) constant wastewater inflow rate of 165 gpcd; (c) constant BODu influent
concentration of 396.5 mg/L;  and (d) linear extrapolations of the percentage of projected population served by POTWs
and removal efficiencies for BOD5, CBODu, NBOD and BODu estimated for 1996 and 2016 using data obtained from the
1996 Clean Water Needs Survey (USEPA, 1997). It is assumed that the estimated design BODu removal efficiency (65
percent in 1996 and 71 percent in 2016) and the proportion of the United States population served by POTWs (72 percent
in 1996 and 88 percent in 2016) can be extrapolated linearly from 1996 to 2016.  After 2016 it is assumed that these percent-
ages remain constant over time from 2016 to 2050 as 71 percent removal efficiency for BODu and 88 percent of the pro-
jected population served by POTWs.

Influent TSS and POC
The influent TSS concentration of 215 mg/L, consistent with other estimates of raw wastewater strength (e.g., Tetra Tech,
1999; Metcalf and Eddy, 1991), is based on the mean influent concentration from 60 wastewater facilities reported in
AMSA (1997). The influent concentration of POC (70.95 mg/L) was estimated from the particulate organic matter (POM)
(volatile suspended solids) fraction of influent TSS (POM:TSS=0.75) for "medium" strength raw wastewater and  a C:DW
ratio of 0.44 mg C (mg DW)'1 (Metcalf and Eddy, 1991).

Effluent TSS and POC
Removal efficiencies for TSS are based on data compiled by (a) Gunnerson et al. (1982) for primary (50 percent); (b) NRC
(1993)  for advanced primary (70 percent); and mean removal efficiencies computed from data reported by AMSA  (1997)
for (c)  secondary (92 percent); (d) advanced secondary (97 percent); and (e) advanced treatment (98 percent). Less than
secondary removal efficiencies are assigned as the mean of primary and advanced primary removal percentages.  Better
than secondary removal  efficiencies are assigned as the mean of advanced secondary and advanced treatment removal
percentages. Effluent concentrations of POC are estimated from particulate organic matter (volatile suspended solids)
fractions of TSS  for primary and advanced primary (0.83), secondary and advanced secondary (0.67) obtained from Clark
et al. (1977). Data was not available to define the organic matter fraction of TSS for effluent from advanced treatment; a
value of 0.5 was assumed as a reasonable characterization of the organic matter fraction of effluent TSS. The organic
component of effluent TSS was converted to POC using a constant C:DW ratio of 0.44 mg C . (mg DW)'1 (Metcalf and
Eddy, 1991). Table B-32 summarizes the influent and effluent concentrations and removal efficiencies assumed for
calculation of the loads of TSS and POC.
                                                                                                    B-23

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
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AMSA. 1997. The AMSA financial survey. American Metropolitan Sewerage Association, Washington, DC.
ASIWPCA.  1984.  America's clean water: The states evaluation of progress 1972-1982. Association of State and
    Interstate Water Pollution Control Administrators (ASIWPCA), Washington, DC. Executive Summary and Technical
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    category and influent and effluent BOD5 loading for 1972 and 1982.
Clark, J.W., W. Viessman, and M.J. Hammer. 1977. Water supply and pollution control. 3rd ed. Harper & Row Publishers,
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Fair, G.M., J.C. Geyer, and D. A. Okun. 1971. Elements of water supply and wastewater disposal, 2nd ed. John Wiley &
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FWPCA. 1970. The economics of clean water. Vol. I, Detailed analysis. U.S. Department of the Interior, Federal Water
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MWCOG .1989. Potomac River water quality, trends and issues in the Washington Metropolitan Area, 1982-1986,
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Steel, E.W. 1960. Water supply and sewerage, 4th ed. McGraw-Hill, New York, NY.
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    Tetra Tech, Inc., Fairfax, VA.
Thomann, R.V, and J.A. Mueller. 1987. Principles of surface water quality modeling and control. Harper & Row, Inc.,
    New York, NY
U.S. Census. 1996. Population projections of the United States by age, sex, race and Hispanci origin: 1995-2050.
    Current Population Reports, Population Division, U.S. Bureau of Census, Washington, DC.
USDOI. 1970. Municipal waste facilities in the U.S.: Statistical summary, 1968 inventory. U.S. Department of the
     Interior, Federal Water Quality Administration (FWQA), Washington DC. Publication No. CWT-6.
USEPA. 1972. Working file notes from EPA Office of Municipal Pollution Control, Washington, DC. Handwritten tables
     compiled from November 1972 EPA STORET data extraction and tabulation of population served and facilities
     inventory for raw, primary, intermediate (advanced primary), secondary and tertiary treatment. Detailed types of
     waste treatment facilities are compiled. Secondary treatment category (total of 14,035 facilities serving 102.3 million
     persons) included the following subcategories: other; activated sludge; extended aeration; high rate trickling filters;
     standard rate trickling filter; intermediate sand filtration; land application; oxidation pond; unknown filter; and
     unknown. Primary  data sources reproduced in Table B-34 and Table B-35.


B-24

-------
                        Appendix B: National Municipal Wastewater Inventory and Infrastructure, 1940 to 2016


USEPA.  1974. National water quality inventory, 1974.  Report to Congress. Office of Water Planning and Standards,
    U.S. Environmental Protection Agency, Washington, DC. EPA-440/9-74-001, Vol. I and Vol. II. Population served and
    number of facilities for raw, primary, secondary and tertiary for 1962,1968, and 1973 compiled on p. 278. Data from
    1962 and 1968 is from USPHS Municipal Waste Inventories. Data for 1973 is from STORE! database.
USEPA.  1976. 1976 NEEDS survey, conveyance and treatment of municipal wastewater. Summaries of technical data.
    Water Program Operations, U.S. Environmental Protection Agency, Washington, DC. Data not available for popula-
    tion served by no discharge, raw discharges or tertiary treatment. Data not available for facilities inventory.
USEPA.  1978. 1978 NEEDS survey, conveyance and treatment of municipal wastewater. Summaries of technical data.
    Water Program Operations, U.S. Environmental Protection Agency, Washington, D.C. Data not available for raw
    effluent flow.
USEPA.  1980. 1980 NEEDS survey, conveyance and treatment of municipal wastewater. Summaries of technical data.
    Office of Water Program Operations, U.S. Environmental Protection Agency, Washington, DC. Data not available for
    raw effluent flow.
USEPA.  1982. 1982 NEEDS survey, conveyance, treatment, and control of municipal wastewater, combined sewer
    overflows and stormwater runoff. Summaries of technical data. Office of Water Program Operations, U.S. Environ-
    mental Protection Agency, Washington, DC. Data not available for raw effluent flow.
USEPA.  1984. 1984 NEEDS survey, conveyance, treatment, and control of municipal wastewater, combined sewer
    overflows and stormwater runoff. Summaries of technical data. Office of Water Program Operations, U.S. Environ-
    mental Protection Agency, Washington, DC. Data not available for raw effluent flow.
USEPA.  1986. 1986 NEEDS survey, conveyance, treatment, and control of municipal wastewater, combined sewer
    overflows and stormwater runoff. Summaries of technical data. Office of Water Program Operations, U.S. Environ-
    mental Protection Agency, Washington, DC. Data not available for raw effluent flow.
USEPA.  1989. 1988 NEEDS survey, conveyance, treatment, and control of municipal wastewater, combined sewer
    overflows and stormwater runoff. Summaries of technical data. Office of Water Program Operations, U.S. Environ-
    mental Protection Agency, Washington, DC.
USEPA.  1993. 1992 NEEDS survey, conveyance, treatment, and control of municipal wastewater, combined sewer
    overflows and stormwater runoff. Summaries of technical data. Office of Water Program Operations, U.S. Environ-
    mental Protection Agency, Washington, DC. EPA-832-R-93-002.
USEPA.  1997. 1996 NEEDS survey, conveyance,  treatment, and control of municipal wastewater, combined sewer
    overflows and stormwater runoff. Summaries of technical data. Office of Water Program Operations, U.S. Environ-
    mental Protection Agency, Washington, DC. EPA-832-R-97-003.
USPHS.  1951. Water Pollution in the United States. A Report on the Polluted Conditions of our Waters and What is
    Needed to Restore their Quality. U.S. Federal Security Agency, Public Health Service, Washington, DC. NTIS No.
    PB-218-308/BA. Population served and facilities inventory data for raw, primary and secondary treatment compiled
    for 1950 (pp. 31-33) by major river basins.
                                                                                                    B-25

-------
Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
B-26

-------
  Appendix C
National Public and
Private Sector Investment
in Water Pollution Control
Table
C-1

C-2
C-3
CM
U.S. Environmental Protection Agency Construction Grants Program and Clean Water
State Revolving Fund expenditures for municipal water pollution control	
Water pollution control abatement, current year-dollar	
Water pollution control abatement, constant-dollar	
Gross domestic product index and plant construction index used for inflation adjustment of
O&M and capital expenditures	
C-3
C^
C-4

C-5
                                                    C-1

-------
Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
C-2

-------
                           Appendix C: National Public and Private Sector Investment in Water Pollution Control
Table C-1. U.S. Environmental Protection Agency Construction Grants Program and Clean Water State Revolving
Fund expenditures for municipal water pollution control
Year
1970
1971
1972
1973
1974
1975
1976
1977
1978
1979
1980
1981
1982
1983
1984
1985
1986
1987
1988
1989
1990
1991
1992
1993
1994
1995
1996
1997
1998
1999
2000





Annual
CURRENT
($1000)
139
31
132080
3043502
2519179
4343443
4598985
7272400
2832399
5112276
3807997
3605439
2250355
3988124
4565966
2129228
2319335
2442281
3062053
1295664
945677
279960
284006
118912
105055
11065
0
0
0
0
0





	 Constructii
Cumulative
CURRENT
($1000)
139
170
132250
3175752
5694931
10038374
14637359
21909759
24742158
29854434
33662431
37267870
39518225
43506349
48072315
50201543
52520878
54963159
58025212
59320876
60266553
60546513
60830519
60949431
61054486
61065551
61065551
61065551
61065551
61065551
61065551
1321677
587221
59156653
0
61065551
DH urants— •
Annual
1995$
($1000)
512
100
364950
8006876
5774008
9027401
9075865
13507911
4907498
8119248
5526847
4602088
2716928
4770899
5363493
2481372
2761491
2859376
3389277
1382068
1002530
293754
300577
125501
108193
11065
0
0
0
0
0





	 J
Cumulative
1995$
($1000)
512
612
365562
8372438
14146446
23173847
32249712
45757623
50665121
58784369
64311216
68913304
71630232
76401131
81764624
84245996
87007487
89866863
93256140
94638208
95640738
95934492
96235069
96360570
96468763
96479828
96479828
96479828
96479828
96479828
96479828
1962605
842962
93674326
-65
96479828
L 	 wicc
Annual
CURRENT
($1000)
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
252227
1153764
1368882
1971827
1891382
1890597
1270191
1318463
1714318
792498
1240294
1299931
0
Grants data matched
III VVQLC7I UIUIW 1 n
Cumulative
CURRENT
($1000)
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
252227
1405991
2774873
4746700
6638082
8528678
9798870
11117332
12831650
13624148
14864442
16164373
16164373
to River Basins >
Annual
1995$
($1000)
0

0
0
0
0

0

0
0


0
0
0
0
0
279181
1230703
1451183
2068972
2001739
1995337
1308148
1318463
NA
NA
NA
NA
NA
18
Cumulative
1995$
($1000)
0
g
Q
g
Q
g
g
Q
Q
g
g
Q
g
Q
g

g
Q
279181
1509883
2961067
5030039
7031778
9027115
10335264
11653726
NA
NA
NA
NA
NA

Grants data not matched to any CU
Grants data matched
Rounding error
Grants data for all
to River Basins 1

grants, USA total
-18





 Sources: Construction Grants Program expenditures extracted August,  1995  from USEPA  "GICS" database, Clean water State Revolving
 Fund (CWSRF)  expenditures  obtained  from USEPA Office  of Wastewater  Management,  CWSRF Program, April, 2000
                                                                                                              C-3

-------
Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
Table C-2.  Water pollution control abatement, current year-dollar (million $) Source: Vogan (1996)
Year

1972
1973
1974
1975
1976
1977
1978
1979
1980
1981
1982
1983
1984
1985
1986
1987
1988
1989
1990
1991
1992
1993
1994
1995
private
cap
P e
1,501
1,770
1,765
2,145
2, 607
2,827
2, 683
2, 873
2,795
2,848
2,937
2,422
2, 730
2, 670
2, 534
2, 614
2, 581
3, 196
4,430
4,666
4,532
4,335
4,720
0
private
o&m
p&e
789
972
1, 188
1,409
1,726
2, 064
2,357
2,788
2, 985
3,210
3,466
3,753
4, 052
4,350
4,741
5, 088
5, 427
5,767
6,492
6,223
6,522
6, 513
7,057
0
private

2 ,290
2, 742
2,953
3,554
4,333
4,891
5,040
5,661
5,780
6, 058
6, 403
6,175
6,782
7,020
7,275
7,702
8,008
8,963
10,922
10,889
11,054
10,848
11,777
0
public public
capital capital

2,260
2,534
3,105
3,762
4,082
4,287
4, 992
5, 945
6, 592
6,404
5,851
5,735
5, 794
6,193
6, 884
7,803
8,322
8, 350
8,730
9,015
9,589
5,126
0
0

29
22
29
32
36
52
63
81
61
57
86
73
54
63
40
37
28
49
77
64
14
11
10
0
public
capital

2,289
2,556
3,134
3,794
4, 118
4,339
5,055
6,026
6,653
6,461
5, 937
5, 808
5,848
6,256
6, 924
7, 840
8,350
8,399
8,807
9,079
9,603
5,137
10
0
public public ]
o&m o&m
sewer elec ut
1,125
1,308
1,567
1, 838
2, 156
2,553
2,977
3,399
3,915
4, 556
5, 168
5,643
6,057
6,554
7,201
7,792
8,363
9,325
10,262
10, 995
11,929
6,220
0
0
3
4
5
7
9
10
10
12
13
18
17
19
20
10
10
13
12
11
8
14
10
11
10
0
public public
o&m o&m
other tot O&M
0 1,128
1 1,313
1 1,573
0 1, 845
1 2,166
0 2,563
1 2,988
1 3,412
0 3,928
1 4,575
2 5,187
2 5,664
2 6,079
3 6,567
3 7,214
3 7, 808
3 8,378
3 9,339
3 10,273
3 11,012
3 11,942
3 6,234
3 13
0 0
public
cap+o&m
tot pub
3,416
3,869
4, 706
5,639
6,283
6,902
8, 043
9,438
10, 581
11, 035
11,123
11,472
11,927
12,823
14,138
15,648
16,727
17, 737
19, 080
20, 091
21,545
11,371
23
0
Pub+Priv
cap+o&m
Tot-Point
5,706
6, 611
7 , 659
9,193
10,616
11,793
13, 083
15, 099
16,361
17,093
17,526
17,647
18,709
19,843
21,413
23,350
24,735
26, 700
30, 002
30, 980
32,599
22,219
11, 800
0
Table C-3.  Water pollution control abatement, constant-dollar (1995$ GDP index for O&M; PCI for capital)
           (million $)
Year
1972
1973
1974
1975
1976
1977
1978
1979
1980
1981
1982
1983
1984
1985
1986
1987
1988
1989
1990
1991
1992
1993
1994
1995
private
cap
p&e
4, 147
4, 657
4, 045
4,458
5, 145
5,251
4, 649
4, 563
4, 057
3, 635
3,546
2,897
3,207
3,112
3,017
3,060
2,857
3,409
4,696
4, 896
4,796
4,575
4, 861
0
private
o&m
p&e
2, 642
3,057
3,437
3,720
4,287
4, 796
5, 078
5, 521
5,408
5,285
5,373
5, 591
5, 784
5, 986
6,356
6, 609
6, 785
6,904
7,443
6, 874
7,008
6, 851
7,270
0
private public
capital
tot sewer
6,789
7,714
7,482
8, 178
9,432
10,047
9,726
10,084
9,465
8, 920
8, 919
8,488
8, 991
9, 097
9, 373
9, 670
9, 642
10,314
12,140
11,770
11,804
11, 426
12,131
0
6,243
6,666
7, 116
7, 819
8,055
7,962
8,649
9,442
9,567
8, 174
7, 063
6, 860
6, 807
7,217
8, 196
9,136
9,211
8, 906
9,255
9,459
10, 148
5, 410
0
0
public public publi
elec
80
58
66
67
71
97
109
129
89
73
104
87
63
73
48
43
31
52
82
67
15
12
10
0
ut tot K sewe
6,323
6,724
7, 182
7,885
8, 126
8, 058
8,758
9,570
9,655
8,246
7, 167
6, 947
6,870
7,291
8,243
9, 179
9,242
8, 959
9,337
9,526
10, 163
5, 422
10
0
3,765
4, 114
4, 532
4,851
5,354
5, 933
6, 412
6,730
7,093
7,500
8,010
8, 406
8,645
9, 018
9, 653
10,122
10,455
11, 164
11, 766
12, 144
12, 817
6,542
0
0
c public public public public Pub+Priv
m o&m o&m o&m cap + o&m cap+o&m
r elec ut other tot O&M tot pub Tot-Point
10
12
15
20
23
24
22
25
26
33
28
29
29
14
13
17
15
13
9
16
11
11
10
0
0
3
3
0
3
0
2
2
0
2
3
3
3
4
4
4
4
4
3
3
3
3
3
0
3,775
4, 130
4, 550
4, 871
5, 380
5,956
6,437
6, 757
7, 118
7, 535
8, 042
8,438
8,677
9,036
9,670
10, 142
10,474
11, 180
11, 778
12, 163
12,831
6,557
13
0
10, 098
10, 854
11, 732
12,757
13, 505
14, 015
15, 195
16, 327
16, 774
15,781
15,209
15,385
15, 547
16, 326
17, 914
19, 321
19,715
20, 139
21, 115
21, 690
22,994
11,978
23
0
16, 887
18,568
19,214
20,935
22, 937
24,062
24, 921
26, 411
26,238
24,701
24, 128
23, 874
24, 538
25,424
27,287
28, 991
29,357
30,453
33,254
33,459
34,798
23,404
12, 154
0
Total  93537
C-4

-------
                       Appendix C: National Public and Private Sector Investment in Water Pollution Control
Table C-4. Gross Domestic Product Index and Plant Cost Index used for inflation adjustment of O&M
          and capital expenditures. Source: Council of Economic Advisors (1997) and CE (1995).
FY
1955
1956
1957
1958
1959
1960
1961
1962
1963
1964
1965
1966
1967
1968
1969
1970
1971
1972
1973
1974
1975
1976
1977
1978
1979
1980
1981
1982
1983
1984
1985
1986
1987
1988
1989
1990
1991
1992
1993
1994
1995
O&M
GDP


25
26
26
26
27
27
28
29
30
31
33
35
37
38
41
44
49
52
55
60
65
71
78
83
87
91
94
96
100
103
108
113
117
120
123
126
129


.6
.0
.3
.9
.2
.7
.4
.4
.3
.8
.4
.2
.1
.8
.3
.9
.2
.3
.9
.3
.6
.7
.9
.8
.2
.0
.4
.9
.0
.9
.5
.3
.6
.9
.5
.1
.9
Capital
PCI















137.
144.
165.
182.
192.
204.
218.
238.
261.
297.
314.
316.
322.
325.
318.
323.
342.
355.
357.
361.
358.
359.
368.
379.















2
1
4
4
1
1
8
7
2
0
0
9
7
3
4
8
5
4
6
3
2
2
1
1
                                                                                             C-5

-------
Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
References

CE. 1995. Economic indicators: Chemical engineering plant cost index. Chemical Engineering, The McGraw
    Hill Companies, Vol. 102,No.7pp. 192.
Council of Economic Advisors. 1997. Table B-3, Chain Type price indexes for gross domestic product, 1959-
    96, Appendix B, Statistical Tables Relating to Income, Employment and Production. In: Economic Report
    to the President, Transmitted to the Congress, February, 1997 together with the Annual Report of the
    Council of Economic Advisors, U.S. Government Printing Office, Washington, DC.
Vogan, C.R. 1996.  Pollution abatement and control expenditures,  1972-94. Survey of current business.
    Vol. 76, No. 9,  pp. 48-67. U.S. Dept. of Commerce, Bureau of Economic Analysis, Washington, DC.
C-6

-------
  Appendix D
Before and After CWA Changes
in 10th Percentile Dissolved
Oxygen and 90th Percentile
BOD5 at the Catalog Unit Level
Table                                   Page
D-1  Before and After CWA Changes in 10th Percentile Dissolved Oxygen at the Catalog Unit Level  D-3
D-2  Before and After CWA Changes in 90th Percentile BOD5 at the Catalog Unit Level	 D-7
                                     D-1

-------
Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
D-2

-------
Appendix D: Before and After CWA Changes in DO and BODS at the Catalog Unit Level
Table D-1 . Before and After CWA Changes in 1 0th Percentile Dissolved Oxygen (mg/L) at the Catalog Unit


Rank
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67

Catalog
Unit No.
04030204
04120102
04110002
17010307
07070002
18060005
02050306
04030104
05080002
08030204
10170203
04040002
08030203
04040003
06010104
08030205
06010205
02040204
04100002
11070207
04040001
18090208
07120007
07130011
04100009
04130003
06010102
05050008
02040203
04110001
07090001
03010106
07130006
07120004
06010105
05030103
05080001
02040202
03100204
14010005
05090101
05050003
07010204
04030101
07140201
02040201
03170006
09020301
03100101
02070003
05030101
05030202
07130001
05090202
07120006
07090004
01080205
02070008
17050115
06010207
18070203
04090001
05090201
05120201
08020401
07060005
03050109

Catalog Unit
Name
LOWER FOX. WISCONSIN
CATTARAUGUS . NEW YOR
CUYAHOGA. OHIO.
LOWER SPOKANE. WASHI
LAKE DUBAY. WISCONSI
SALINAS. CALIFORNIA.
LOWER SUSQUEHANNA. M
OCONTO. WISCONSIN.
LOWER GREAT MIAMI . I
COLDWATER. MISSISSIP
LOWER BIG SIOUX. IOW
PIKE-ROOT. ILLINOIS
YOCONA. MISSISSIPPI.
MILWAUKEE. WISCONSIN
HOLSTON. TENNESSEE.
YALOBUSHA. MISSISSIP
UPPER CLINCH. TENNES
DELAWARE BAY. NEW JE
RAISIN. MICHIGAN OHI
SPRING. KANSAS MISSO
LITTLE CALUMET-GALIE
MQJAVE. CALIFORNIA.
LOWER FOX. ILLINOIS.
LOWER ILLINOIS. ILLI
LOWER MAUMEE . OHIO .
LOWER GENESEE . NEW Y
SOUTH FORK HOLSTON.
LOWER KANAWHA. WEST
SCHUYLKILL. PENNSYLV
BLACK-ROCKY. OHIO.
UPPER ROCK. ILLINOIS
ROANOKE RAPIDS. NORT
UPPER SANGAMON. ILLI
DES PLAINES. ILLINOI
UPPER FRENCH BROAD.
MAHONING. OHIO PENNS
UPPER GREAT MIAMI . I
LOWER DELAWARE . NEW
ALAFIA. FLORIDA.
COLORADO HEADWATERS-
RACCOON-SYMMES . OHIO
GREENBRIER. WEST VIR
CROW. MINNESOTA.
MANITOWOC-SHEBOYGAN .
UPPER KASKASKIA. ILL
CROSSWICKS-MESHAMINY
PASCAGOULA. MISSISSI
SANDHILL-WILSON. MIN
PEACE. FLORIDA.
CACAPON-TCWN. MARYLA
UPPER OHIO. OHIO PEN
UPPER OHIO-SHADE. OH
LOWER ILLINOIS-SENAC
LITTLE MIAMI . OHIO .
UPPER FOX. ILLINOIS
SUGAR. ILLINOIS WISC
LOWER CONNECTICUT. C
MIDDLE POTOMAC-CATOC
MIDDLE SNAKE-PAYETTE
LOWER CLINCH. TENNES
SANTA ANA. CALIFORNI
ST. CLAIR. MICHIGAN.
OHIO BRUSH-WHITEOAK.
UPPER WHITE. INDIANA
LOWER ARKANSAS . ARKA
APPLE-PLUM. ILLINOIS
SALUDA. SOUTH CAROLI
Mean
Before
CWA
0.160
1.323
0.295
3.500
0.880
3.180
0.880
0.500
1.185
0.000
0.000
0.940
0.000
2.180
0.157
0.000
1.614
0.530
4.059
1.600
0.570
4.020
3.780
1.940
2.068
1.043
2.623
1.463
3.830
1.688
2.760
1.423
0.000
1.477
4.100
2.627
3.533
1.298
2.598
4.880
3.200
3.233
4.200
5.010
3.260
3.446
2.266
4.100
4.030
4.600
4.530
3.765
4.174
4.005
4.595
5.900
4.300
5.100
6.470
5.260
3.833
5.213
4.400
3.802
5.650
3.946
2.645
Mean
After
CWA
7.205
7.600
6.501
9.700
6.683
8.750
6.196
5.800
6.468
5.208
5.143
5.940
4.854
6.957
4.869
4.629
6.082
4.910
8.340
5.625
4.555
7.977
7.576
5.722
5.847
4.710
6.183
5.013
7.367
4.910
5.980
4.608
3.130
4.605
7.033
5.540
6.443
4.172
5.387
7.560
5.835
5.720
6.680
7.490
5.700
5.815
4.541
6.347
6.250
6.800
6.702
5.830
6.186
5.999
6.550
7.800
6.163
6.937
8.300
7.081
5.633
7.000
6.170
5.552
7.390
5.582
4.270
# Stations
Differ-
ence
7.045
6.277
6.206
6.200
5.803
5.570
5.316
5.300
5.282
5.208
5.143
5.000
4.854
4.777
4.712
4.629
4.468
4.380
4.281
4.025
3.985
3.957
3.796
3.783
3.780
3.668
3.560
3.550
3.537
3.222
3.220
3.186
3.130
3.128
2.933
2.913
2.909
2.874
2.789
2.680
2.635
2.487
2.480
2.480
2.440
2.369
2.275
2.247
2.220
2.200
2.172
2.065
2.012
1.994
1.955
1.900
1.863
1.837
1.830
1.821
1.800
1.787
1.770
1.750
1.740
1.636
1.625
Before
CWA
1
3
2
1
1
4
1
1
6
1
1
1
1
2
1
1
1
1
17
1
2
2
2
1
8
4
3
3
1
6
1
4
1
18
1
6
3
16
4
1
1
3
1
3
6
7
5
2
4
1
1
2
9
2
2
1
1
1
1
2
6
6
1
37
2
5
6
After
CWA
6
2
25
1
3
1
10
2
4
11
9
1
16
3
5
11
7
8
2
4
11
3
11
20
7
2
10
7
9
6
8
6
21
49
7
2
4
24
3
2
3
1
2
5
11
4
13
3
2
1
39
3
14
15
39
2
7
14
1
4
9
1
3
14
2
6
68
Level
# Q years
Before
CWA
2
4
5
1
2
4
4
1
4
2
3
2
2
3
2
3
3
5
4
2
2
4
3
3
5
4
2
3
4
5
4
3
2
3
1
5
4
4
2
2
4
4
3
1
3
4
2
2
3
5
5
4
3
3
3
2
4
5
1
1
5
4
3
3
2
2
14
After
CWA
3
2
1
2
3
4
1
3
1
3
2
1
4
1
2
4
2
3
1
2
1
4
1
3
1
1
3
2
1
1
1
3
2
1
2
1
1
1
4
3
3
1
3
1
3
1
2
3
4
2
1
3
1
1
1
1
1
2
3
3
3
1
3
1
4
2

                                                                   D-3

-------
Progress in Water Quality: An Evaluation of the National Investment In Municipal Wastewater Treatment
Rank
68
69
70
71
72
73
74
75
76
77
78
79
80
81
82
83
84
85
86
87
88
89
90
91
92
93
94
95
96
97
98
99
100
101
102
103
104
105
106
107
108
109
110
111
112
113
114
115
116
117
118
119
120
121
122
123
124
125
126
127
128
129
130
131
132
133
134
135
136
137
138
139
140
Catalog
Unit No.
17060107
02040205
07010206
07070003
03050103
10190006
10200203
05120114
03180004
04140203
05020002
17080005
05030203
07120005
07030005
06010108
070900Q6
07010207
17020006
05040005
18080003
06030005
18020103
03170008
14070006
11070103
06030001
11140208
07140106
05010009
08050003
03170001
05050002
02070007
05120202
08090203
07040001
03140305
02050103
17110013
08030100
05130108
05120103
17060110
17080001
05120111
11110207
04090005
11110104
06020001
08040303
17110007
17010305
08040304
03050208
17110019
10190007
17110011
07090005
05050005
07130002
10190018
04110003
10200101
17020015
07070005
04110004
04080204
08040302
08030206
07130003
07120003
05120106
Catalog Unit
Name
LOWER SNAKE-TUCANNON
BRANDYWINE-CHRISTINA
TWIN CITIES . MINNESO
CASTLE ROCK. WISCONS
LOWER CATAWBA. NORTH
BIG THOMPSON. COLORA
SALT. NEBRASKA.
LITTLE WABASH. ILLIN
LOWER PEARL . LOUISIA
OSWEGO. NEW YORK.
WEST FORK. WEST VIRG
LOWER COWLITZ . WASH!
LITTLE KANAWHA. WEST
UPPER ILLINOIS . ILLI
LOWER ST. CROIX. MIN
NOLICHUCKY. NORTH CA
KISHWAUKEE. ILLINOIS
RUM. MINNESOTA.
OKANOGAN. WASHINGTON
WILLS. OHIO.
HONEY-EAGLE LAKES. C
PICKWICK LAKE. ALABA
SACRAMENTO-LOWER THO
ESCATAWPA. ALABAMA M
LOWER LAKE POWELL. A
MIDDLE VERDIGRIS. KA
GUNTERSVILLE LAKE. A
SALINE BAYOU. LOUISI
BIG MUDDY. ILLINOIS.
LOWER ALLEGHENY. PEN
TENSAS. LOUISIANA.
CHUNKY-OKATIBBEE. MI
MIDDLE NEW. VIRGINIA
SHENANDOAH. VIRGINIA
LOWER WHITE . INDIANA
EASTERN LOUISIANA CO
RUSH-VERMILLION. MIN
ESCAMBIA. ALABAMA FL
OWEGO-WAPPASENING. N
DUWAMISH. WASHINGTON
LOWER MISSISSIPPI -GR
CANEY. TENNESSEE.
MISSISSINEWA. INDIAN
LOWER SNAKE. WASHING
LOWER COLUMBIA-SANDY
MIDDLE WABASH-BUSSER
LOWER ARKANSAS-MAUME
HURON. MICHIGAN.
ROBERT S . KERR RESER
MIDDLE TENNESSEE-CHI
DUGDEMONA. LOUISIANA
LOWER SKAGIT. WASHIN
UPPER SPOKANE. IDAHO
LITTLE. LOUISIANA.
BROAD-ST. HELENA. SO
PUGET SOUND. WASHING
CACHE LA POUDRE. COL
SNOHOMISH. WASHINGTO
LOWER ROCK. ILLINOIS
GAULEY. WEST VIRGINI
VERMILION. ILLINOIS.
LOWER SOUTH PLATTE.
ASHTABULA-CHAGRIN. 0
MIDDLE PLATTE-BUFFAL
LOWER CRAB. WASHINGT
LOWER WISCONS IN. WIS
GRAND. OHIO.
FLINT. MICHIGAN.
CASTOR. LOUISIANA.
UPPER YAZOO. MISSISS
LOWER ILLINOIS-LAKE
CHICAGO. ILLINOIS IN
TIPPECANOE. INDIANA.
Mean
Before
CWA
7.600
4.600
3.851
5.000
2.273
5.443
3.750
2.340
3.777
4.300
5.325
7.564
4.403
5.077
5.731
5.580
5.000
5.800
6.460
4.220
6.820
4.800
8.385
2.078
6.380
5.010
4.850
4.160
2.290
6.060
3.100
4.433
5.000
5.260
4.725
4.550
4.857
5.120
6.080
6.001
5.100
4.200
5.840
7.170
7.800
5.100
6.360
5.000
5.620
4.340
3.000
9.420
7.200
3.250
2.287
8.043
6.391
8.360
5.253
7.090
3.775
6.220
5.225
6.800
6.680
6.365
5.665
5.400
3.440
5.520
4.078
3.416
6.135
Mean
After
CWA
9.200
6.126
5.373
6.515
3.771
6.901
5.195
3.754
5.185
5.700
6.691
8.930
5.743
6.412
7.057
6.900
6.280
7.080
7.725
5.480
8.040
5.968
9.550
3.232
7.500
6.117
5.935
5.240
3.366
7.132
4.168
5.500
6.066
6.307
5.750
5.548
5.853
6.100
7.047
6.957
6.020
5.110
6.715
8.030
8.625
5.892
7.140
5.750
6.367
5.071
3.725
10.117
7.895
3.938
2.970
8.720
7.038
8.987
5.866
7.685
4.370
6.800
5.793
7.305
7.180
6.830
6.120
5.850
3.870
5.948
4.489
3.824
6.525
# Stations
Differ-
ence
1.600
1.526
1.522
1.515
1.498
1.458
1.445
1.414
1.408
1.400
1.366
1.366
1.340
1.334
1.326
1.320
1.280
1.280
1.265
1.260
1.220
1.168
1.165
1.153
1.120
1.107
1.085
1.080
1.076
1.072
1.068
1.067
1.066
1.047
1.025
0.998
0.996
0.980
0.967
0.956
0.920
0.910
0.875
0.860
0.825
0.792
0.780
0.750
0.747
0.730
0.725
0.697
0.695
0.688
0.683
0.677
0.647
0.627
0.613
0.595
0.595
0.580
0.568
0.505
0.500
0.465
0.455
0.450
0.430
0.428
0.412
0.407
0.390
Before
CWA
1
1
23
1
13
8
2
1
7
1
4
5
6
4
9
1
1
1
2
1
1
1
4
6
1
1
2
1
1
1
1
3
2
1
2
1
10
2
1
9
1
1
1
1
1
1
2
2
1
15
1
2
2
4
4
7
12
2
3
1
2
3
5
1
3
2
3
3
1
1
5
13
2
After
CWA
1
23
64
4
22
11
20
11
4
1
2
4
6
10
7
2
12
3
2
3
1
5
2
12
1
4
13
1
36
19
5
1
7
3
3
4
6
1
3
7
1
1
6
1
2
23
7
2
3
34
2
3
11
2
11
1
6
3
23
5
4
1
3
2
1
2
3
2
2
5
14
19
2
# Q years
Before
CWA
1
4
3
2
2
2
3
3
1
4
4
2
4
3
3
1
4
3
2
4
3
1
3
2
1
2
1
4
3
4
3
4
3
5
3
2
3
2
4
2
3
1
3
3
2
3
2
4
4
1
4
3
1
4
1
1
2
3
3
4
2
1
5
3
1
2
5
4
4
2
3
2
3
After
CWA
2
1
3
3
2
1
1
2
1
2
2
2
2
1
3
2
1
3
3
3
4
4
2
2
1
3
3
4
2
1
4
3
2
2
1
2
2
2
1
3
4
3
1
3
1
1
4
1
3
3
4
3
2
3
2
2
1
4
1
2
2
1
i
1
2
2
1
1
4
4
2
1
1
D-4

-------
Appendix D: Before and After CWA Changes in DO and BODS at the Catalog Unit Level
Rank
141
142
143
144
145
146
147
148
149
150
151
152
153
154
155
156
157
158
159
160
161
162
163
164
165
166
167
168
169
170
171
172
173
174
175
176
177
178
179
180
181
182
183
184
185
186
187
188
189
190
191
192
193
194
195
196
197
198
199
200
201
202
203
204
205
206
207
208
209
210
211
212
213
Catalog
Unit No .
03050202
14080105
04030108
07080209
10270205
10200202
18030012
05020006
18040005
06010103
10180009
05080003
04080206
08040207
05050007
08070205
03040201
02070001
17020011
05070101
07020012
05140101
03180005
03050205
17090003
05120112
02070004
03160203
05050006
09030004
05020003
05020001
07090003
06030002
05070204
02070010
03040204
05050001
08040301
07140204
07040007
10240011
17110008
03050101
02080206
04080201
04030202
07080208
08050002
08040202
05120105
08080203
05020004
06040006
05070102
07040006
10300101
07040002
07020007
07010203
05120104
17100103
03040202
03160106
07140101
03050105
07050005
04030105
10170101
05120108
08040206
05010006
03050207
Catalog Unit
Name
SOUTH CAROLINA COAST
MIDDLE SAN JUAN. ARI
MENOMINEE. MICHIGAN
LOWER IOWA. IOWA.
LOWER BIG BLUE. KANS
LOWER PLATTE. NEBRAS
TULARE-BUENA VISTA L
YOUGHIOGHENY. MARYLA
LOWER COSUMNES-LOWER
WATAUGA. NORTH CAROL
MIDDLE NORTH PLATTE-
WHITEWATER. INDIANA
SAGINAW. MICHIGAN.
LOWER OUACHITA. LOUI
ELK. WEST VIRGINIA.
TANGIPAHOA. LOUISIAN
LOWER PEE DEE. NORTH
SOUTH BRANCH POTOMAC
WENATCHEE. WASHINGTO
UPPER GUYANDOTTE . WE
LOWER MINNESOTA. MIN
SILVER-LITTLE KENTUC
BOGUECHITTO. LOUISI
EDISTO. SOUTH CAROLI
UPPER WILLAMETTE. OR
EMBARRAS. ILLINOIS.
CONOCOCHEAGUE-OPEQUO
LOWER TAMBIGBEE . ALA
UPPER KANAWHA. WEST
UPPER RAINY. MINNESO
UPPER MONONGAHELA. P
TYGART VALLEY. WEST
PECATONICA. ILLINOIS
WHEELER LAKE . ALABAM
BIG SANDY. KENTUCKY
MIDDLE POTOMAC-ANACO
LITTLE PEE DEE . NORT
UPPER NEW. NORTH CAR
LOWER RED. LOUISIANA
LOWER KASKASKIA. ILL
BLACK. WISCONSIN.
INDEPENDENCE-SUGAR .
STILLAGUAMISH. WASHI
UPPER CATAWBA. NORTH
LOWER JAMES . VIRGINI
TITTABAWASSEE. MICHI
WOLF. WISCONSIN.
MIDDLE IOWA. IOWA.
BAYOU MACON. ARKANSA
LOWER OUACHITA-BAYOU
MIDDLE WABASH-DEER.
UPPER CALCASIEU. LOU
CHEAT. PENNSYLVANIA
LOWER TENNESSEE. KEN
LOWER GUYANDOTTE . WE
LA CROSSE-PINE. MINN
LOWER MISSOURI-CROOK
CANNON. MINNESOTA.
MIDDLE MINNESOTA. MI
CLEARWATER-ELK. MINN
EEL. INDIANA.
UPPER CHEHALIS . WASH
LYNCHES . NORTH CAROL
MIDDLE TOMBIGBEE-LUB
CAHOKIA- JOACHIM. ILL
UPPER BROAD. NORTH C
LOWER CHIPPEWA. WISC
PESHTIGO. WISCONSIN.
LEWIS AND CLARK LAKE
MIDDLE WABASH-LITTLE
BAYOU D'ARBONNE. ARK
MIDDLE ALLEGHENY-RED
SALKEHATCHIE . SOUTH
Mean
Before
CWA
3.553
4.790
6.440
6.540
5.880
6.900
7.240
7.197
8.460
6.095
7.000
6.880
4.899
4.000
6.400
6.200
4.120
6.300
9.300
6.400
5.439
3.400
6.000
4.006
7.657
5.080
6.040
5.988
7.050
7.200
6.325
7.028
5.500
5.486
5.720
4.340
3.686
5.973
5.450
4.130
7.450
5.420
8.675
4.667
6.140
6.035
7.205
3.827
3.700
2.635
6.860
4.590
6.886
5.400
6.387
6.740
5.150
7.260
6.803
6.200
7.000
7.900
4.917
5.520
4.490
6.700
5.980
6.240
7.500
6.800
2.880
8.000
3.805
Mean
After
CWA
3.932
5.160
6.750
6.845
6.170
7.173
7.500
7.446
8.700
6.333
7.233
7.100
5.117
4.200
6.577
6.353
4.270
6.450
9.450
6.545
5.580
3.530
6.100
4.053
7.699
5.102
6.060
5.967
6.990
7.135
6.250
6.926
5.388
5.368
5.550
4.160
3.480
5.734
5.200
3.864
7.180
5.125
8.360
4.321
5.774
5.660
6.825
3.445
3.287
2.220
6.435
4.162
6.432
4.930
5.850
6.200
4.586
6.662
6.197
5.541
6.290
7.185
4.189
4.776
3.658
5.867
5.100
5.300
6.548
5.802
1.867
6.977
2.770
# Stations
Differ-
ence
0.379
0.370
0.310
0.305
0.290
0.273
0.260
0.249
0.240
0.238
0.233
0.220
0.218
0.200
0.177
0.153
0.150
0.150
0.150
0.145
0.141
0.130
0.100
0.047
0.042
0.022
0.020
-0.020
-0.060
-0.065
-0.075
-0.102
-0.112
-0.119
-0.170
-0.180
-0.205
-0.240
-0.250
-0.266
-0.270
-0.295
-0.315
-0.345
-0.366
-0.375
-0.380
-0.382
-0.413
-0.415
-0.425
-0.428
-0.454
-0.470
-0.537
-0.540
-0.564
-0.598
-0.607
-0.660
-0.710
-0.715
-0.728
-0.744
-0.832
-0.833
-0.880
-0.940
-0.952
-0.998
-1.013
-1.023
-1.035
Before
CWA
3
1
1
1
1
1
1
11
2
2
1
1
19
2
1
2
19
1
1
2
17
1
2
5
6
1
1
8
2
1
6
6
1
2
1
1
9
3
1
1
1
1
2
3
1
2
2
6
2
4
1
6
8
1
3
1
1
1
6
1
1
2
17
1
1
1
3
1
1
3
1
2
2
# Q years
After Before
CWA CWA
9
1
2
2
2
2
2
5
1
3
8
1
3
1
7
3
39
1
2
4
8
5
2
7
7
15
14
15
2
4
19
4
6
13
2
81
11
17
2
19
3
2
1
36
20
3
2
6
3
7
1
5
4
4
2
2
5
6
3
18
2
2
18
7
16
29
1
1
3
7
3
26
7
2
2
1
2
2
2
3
4
3
1
2
3
4
4
4
3
2
4
1
3
2
2
2
1
1
3
5
2
3
1
4
4
2
1
3
5
2
1
4
3
2
3
3
1
3
3
1
2
3
4
2
4
4
3
3
3
3
2
3
3
3
2
2
2
2
1
4
1
1
3
3
4
1
After
CWA
3
1
3
2
1
1
4
1
3
3
2
1
1
4
2
2
3
1
4
1
3
1
2
3
1
2
2
2
2
2
2
2
2
3
4
2
3
2
1
4
3
2
3
2
3
1
3
2
4
4
2
3
2
2
3
2
1
3
3
3
1
1
3
4
4
3
3
3
3
2
3
1
3
                                                                   D-5

-------
Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
Rank
214
215
216
217
218
219
220
221
222
223
224
225
226
227
228
229
230
231
232
233
234
235
236
237
238
239
240
241
242
243
244
245
246
Catalog
Unit No.
11140202
05070201
05030204
10270207
05020005
05120101
10240008
10240006
05090203
03040205
16050101
03050201
16050102
08050001
05140202
12010004
08090201
05030201
08030201
08080202
04120103
08010100
04010302
07080202
05140206
04030201
05120113
03060101
12010005
03060106
05110003
11140203
11140304
Catalog Unit
Name
MIDDLE RED-COUSHATTA
TUG. KENTUCKY VIRGIN
HOCKING. OHIO.
LOWER LITTLE BLUE . K
LOWER MONONGAHELA. P
UPPER WABASH. INDIAN
BIG NEMAHA. KANSAS N
LITTLE NEMAHA. NEBRA
MIDDLE OHIO-LAUGHERY
BLACK. SOUTH CAROLIN
LAKE TAHOE. CALIFORN
COOPER. SOUTH CAROLI
TRUCKEE. CALIFORNIA
BOEUF. ARKANSAS LOUI
HIGHLAND-PIGEON. IND
TOLEDO BEND RESERVOI
LIBERTY BAYOU-TCHEFU
LITTLE MUSKINGUM-MID
LITTLE TALLAHATCHIE.
MERMENTAU. LOUISIANA
BUFFALO-EIGHTEENMILE
LOWER MISSISSIPPI -ME
BAD-MONTREAL. MICHIG
SHELL ROCK. IOWA MIN
LOWER OHIO. ILLINOIS
UPPER FOX. WISCONSIN
LOWER WABASH . ILLINO
SENECA. NORTH CAROLI
LOWER SABINE . LOUISI
MIDDLE SAVANNAH. GEO
MIDDLE GREEN. KENTUC
LOGGY BAYOU. ARKANSA
CROSS BAYOU. ARKANSA
Mean
Before
CWA
7.
6.
4.
7.
7
6.
7
6.
5.
3.
7
6.
7
4,
5,
4
6.
7.
4.
2.
1.
5.
7.
8.
5.
6.
4.
7.
6.
8.
5.
5
6.
.120
.173
860
.330
.937
.450
.340
.820
.400
.950
.190
.045
.780
.347
.140
.960
.400
.100
.810
.260
.880
.800
.460
.100
.800
.760
.990
.920
.580
.210
.850
.300
.640
Mean
After
CWA
6.050
5.100
3.717
6.070
6.661
5.173
6.060
5.520
4.043
2.581
5.818
4.566
6.264
2.629
3.388
3.200
4.620
5.301
3.006
0.430
0.000
3.830
5.463
6.080
3.642
4.400
2.550
5.416
3.836
4.957
1.942
1.006
1.253
# Stations
Differ-
ence
-1
-1
-1
-1
-1
-1
-1
-1
-1
-1
-1
-1
-1
-1
-1
-1
-1.
-1
-1
-1.
-1
-1
-1
— P
-2.
-2
-2.
-2.
-2
-3.
-3
-4
-5
.070
.073
.143
.260
.275
.277
.280
.300
.357
.369
.372
.479
.516
.717
.753
.760
.780
.799
.804
.830
.880
.970
.997
.020
.158
.360
.440
.504
.744
.253
.908
.294
.387
Before
cm
2
3
1
1
3
3
1
1
1
2
1
1
3
3
1
1
2
1
2
2
2
1
2
1
1
1
1
1
2
1
6
2
2
After
CrtA
2
1
4
2
31
8
1
1
6
17
4
7
13
14
4
1
2
10
5
2
1
1
4
1
5
1
3
21
6
13
4
5
3
# Q years
Before
CWA
4
3
4
1
4
3
2
2
2
2
2
2
3
4
5
4
2
4
3
1
3
3
3
2
3
2
4
1
3
1
5
3
4
After
CWA
3
2
2
1
1
1
1
1
2
2
4
3
4
4
1
4
2
3
4
1
3
3
3
3
4
2
1
4
1
3
4
3
2
D-6

-------
Appendix D: Before and After CWA Changes in DO and BOD5 at the Catalog Unit Level
Table


Rank
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
69
D-2. Before and

Catalog
Unit No.
03050109
03050103
10270205
10190006
05120201
03170008
04100002
05050008
04110001
04040002
05120104
07040006
02040204
07010207
07040001
07010206
04030104
04080206
04090005
02070007
05070204
05120103
05090202
05030103
03050208
08040301
08020401
16050102
04030204
05070201
05010009
10190007
05050006
07070002
05140202
02040203
02040202
05120101
05050002
05090203
11110207
07030005
03160203
03040202
07080202
07010203
03050205
03140305
07020007
03100204
08040202
03080103
07020012
04030101
16020204
11110104
03050105
07060005
17080001
09030004
09020301
04110002
17090003
03040205
04080201
05090101
05140101
03160106
05140206
After CWA Changes in

Catalog Unit
Name
SALUDA. SOUTH CAROLI
LOWER CATAWBA. NORTH
LOWER BIG BLUE. KANS
BIG THOMPSON. COLORA
UPPER WHITE. INDIANA
ESCATAWPA. ALABAMA M
RAISIN. MICHIGAN OKI
LOWER KANAWHA. WEST
BLACK-ROCKY. OHIO.
PIKE-ROOT. ILLINOIS
EEL. INDIANA.
LACROSSE-PINE. MINN
DELAWARE BAY. NEW JE
RUM. MINNESOTA.
RUSH-VERMILLION. MIN
TWIN CITIES . MINNESO
OCONTO. WISCONSIN.
SAGINAW. MICHIGAN.
HURON. MICHIGAN.
SHENANDOAH. VIRGINIA
BIG SANDY. KENTUCKY
MISSISSINEWA. INDIAN
LITTLE MIAMI . OHIO .
MAHONING. OHIO PENNS
BROAD-ST. HELENA. SO
LOWER RED. LOUISIANA
LOWER ARKANSAS . ARKA
TRUCKEE. CALIFORNIA
LOWER FOX. WISCONSIN
TUG. KENTUCKY VIRGIN
LOWER ALLEGHENY . PEN
CACHE LA POUDRE. COL
UPPER KANAWHA. WEST
LAKE DUBAY. WISCONSI
HIGHLAND-PIGEON. IND
SCHUYLKILL. PENNSYLV
LOWER DELAWARE. NEW
UPPER WABASH. INDIAN
MIDDLE NEW. VIRGINIA
MIDDLE OHIO-LAUGHERY
LOWER ARKANSAS-MAUME
LOWER ST. CROIX. MIN
LOWER TAMBIGBEE . ALA
LYNCHES . NORTH CAROL
SHELL ROCK. IOWA MIN
CLEARWATER-ELK. MINN
EDISTO . SOUTH CAROLI
ESCAMBIA. ALABAMA FL
MIDDLE MINNESOTA. MI
ALAFIA. FLORIDA.
LOWER OUACHITA-BAYOU
LOWER ST. JOHNS. FLO
LOWER MINNESOTA. MIN
MANITOWDC-SHEBOYGAN .
JORDAN. UTAH.
ROBERT S . KERR RESER
UPPER BROAD. NORTH C
APPLE-PLUM. ILLINOIS
LOWER COLUMBIA-SANDY
UPPER RAINY. MINNESO
SANDHILL-WILSON. MIN
CUYAHOGA. OHIO.
UPPER WILLAMETTE . OR
BLACK. SOUTH CAROLIN
TITTABAWASSEE. MICHI
RACCOON-SYMMES . OHIO
SILVER-LITTLE KENTUC
MIDDLE TOMBIGBEE-LUB
LOWER OHIO. ILLINOIS
90th Percentile
Mean
Before
CWA
64.105
48.153
43.400
36.303
34.823
21.990
21.440
13.663
16.406
12.400
8.300
9.400
5.200
9.000
6.779
10.143
6.860
10.876
9.780
6.490
5.100
8.240
7.500
9.600
7.900
6.620
6.610
5.500
9.660
4.693
4.470
8.192
2.450
8.840
4.970
5.840
5.792
7.763
7.550
6.100
5.300
4.238
2.969
5.781
16.890
5.000
3.916
2.935
7.733
2.693
4.500
3.340
8.272
5.550
16.843
6.300
4.200
5.896
1.480
1.560
4.955
8.400
2.345
3.130
4.000
1.600
2.880
2.520
1.990
BOD6 (mg/L)
Mean
After
CWA
4.848
8.831
6.510
5.700
6.869
1.880
6.240
2.550
8.000
6.100
2.100
3.745
0.038
4.340
2.160
5.580
2.450
6.560
5.500
2.500
1.180
4.337
3.605
5.740
4.122
3.210
3.230
2.317
6.543
1.612
1.780
5.700
0.000
6.430
2.660
3.587
3.580
5.562
5.350
3.945
3.366
2.340
1.251
4.326
15.500
3.650
2.720
2.050
6.850
1.810
3.773
2.642
7.810
5.290
16.594
6.060
3.980
5.700
1.300
1.390
4.830
8.300
2.283
3.208
4.100
1.700
3.000
2.700
2.230
at the Catalog Unit
Level
# Stations
Differ-
ence
-59.257
-39.322
-36.890
-30.603
-27.955
-20.110
-15.200
-11.113
-8.406
-6.300
-6.200
-5.655
-5.162
-4.660
-4.619
-4.563
-4.410
-4.316
-4.280
-3.990
-3.920
-3.903
-3.895
-3.860
-3.778
-3.410
-3.380
-3.183
-3.117
-3.081
-2.690
-2.492
-2.450
-2.410
-2.310
-2.253
-2.211
-2.201
-2.200
-2.155
-1.934
-1.898
-1.718
-1.456
-1.390
-1.350
-1.196
-0.885
-0.883
-0.883
-0.727
-0.698
-0.462
-0.260
-0.249
-0.240
-0.220
-0.196
-0.180
-0.170
-0.125
-0.100
-0.062
0.078
0.100
0.100
0.120
0.180
0.240
Before
CWA
4
8
1
8
19
6
1
3
5
1
1
1
1
1
6
21
1
14
2
1
1
1
1
6
1
1
1
1
1
3
1
10
2
1
1
1
16
3
2
1
1
5
8
13
1
1
5
2
5
3
1
1
16
3
7
1
1
5
1
1
2
2
6
2
1
1
1
1
1


# Q years
After Before After
CWA
58
15
2
2
14
1
1
1
2
1
1
2
8
1
1
5
2
2
2
2
1
3
2
1
11
1
2
7
3
1
1
2
1
3
2
3
19
5
2
2
7
1
9
17
1
2
6
1
3
2
3
26
2
2
25
2
26
4
1
4
2
6
6
16
2
2
2
1
1
CWA
1
2
2
2
3
2
4
3
5
2
3
3
5
3
3
3
1
4
4
5
3
3
3
5
1
4
2
3
2
3
4
2
3
2
5
4
4
3
3
2
2
3
2
2
2
3
1
2
3
2
4
1
2
1
2
4
1
2
2
1
2
5
1
2
3
4
2
2
3
CWA
4
2
1
1
1
2
1
2
1
1
1
2
3
3
2
3
3
1
1
2
4
1
1
I
2
I
4
4
3
2
1
1
2
3
1
1
1
1
2
2
4
3
2
3
3
3
3
2
3
4
4
4
3
1
1
3
3
2
1
2
3
1
1
2
1
3
1
4
4
                                                                   D-7

-------
Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
Rank
70
71
72
73
74
75
76
77
78
79
80
81
82
83
84
85
86
87
88
89
90
91
92
93
94
95
96
97
Catalog
Unit No.
04090001
05030101
04030108
03050201
06020001
03060101
03040204
05120113
02040201
05030202
02070010
05110003
02070004
02070008
05050001
07080209
03040201
07040002
05120111
02050306
03050207
05090201
07070003
10240011
10300101
05120202
10200203
07120003
Catalog Unit
Name
ST. CLAIR. MICHIGAN.
UPPER OHIO . OHIO PEN
MENOMINEE. MICHIGAN
COOPER. SOUTH CAROLI
MIDDLE TENNESSEE-CHI
SENECA. NORTH CAROLI
LITTLE PEE DEE. NORT
LOWER WABASH. ILLINO
CROSSWICKS-NESHAMINY
UPPER OHIO-SHADE . OH
MIDDLE POTOMAC-ANACO
MIDDLE GREEN. KENTUC
CONOCOCHEAGUE-OPEQUO
MIDDLE POTOMAC-CATOC
UPPER NEW. NORTH CAR
LOWER IOWA. IOWA.
LOWER PEE DEE NORTH
CANNON. MINNESOTA.
MIDDLE WABASH- BUSSER
LOWER SUSQUEHANNA . M
SALKEHATCHIE . SOUTH
OHIO BRUSH-WHITEOAK.
CASTLE ROCK WISCONS
INDEPENDENCE-SUGAR.
LOWER MISSOURI-CROOK
LOWER WHITE. INDIANA
SALT. NEBRASKA.
CHICAGO ILLINOIS IN
Mean
Before
CWA
3
3
2
2
1
3.
3.
5
4
1.
3.
2.
2.
3.
2.
6
3.
2.
5
2
4.
1.
3
3
6
7.
9
7
.707
.200
.760
.540
.692
.720
.487
.540
.527
.900
.880
236
.200
.580
073
550
979
410
970
980
475
900
000
000
500
000
900
922
Mean
After
cm
4
3
3
3
2
4
5
7
6
3
5
4
4
5
4
9.
6
5
9
6.
9.
6
8.
8.
12.
13 .
20
19.
.000
.700
.420
.239
.455
.739
.054
.170
.215
.640
.762
.154
.200
.607
.251
.000
731
255
640
.800
.056
810
470
750
278
293
000
000
# Stations
Differ-
ence
0.293
0.500
0.660
0.699
0.763
1.019
1.566
1.630
1.688
1.740
1.882
1.918
2.000
2.027
2.178
2.450
2.753
2.845
3.670
3 820
4.581
4.910
5 470
5.750
5 .778
6.293
10 100
11.078
Before After
CW& CWA
6
1
1
1
11
1
7
1
7
1
1
5
1
1
3
2
18
1
1
1
2
1
1
1
1
1
2
13
1
2
1
6
6
14
11
1
4
2
38
2
2
14
11
1
36
2
1
2
5
2
3
1
5
3
1
6
# Q years
Before
CWA
4
5
1
2
1
1
2
4
4
4
5
5
5
5
1
2
2
2
3
4
1
3
2
3
3
3
3
2
After
CWA
1
1
3
3
3
4
3
1
1
3
2
4
2
2
2
2
3
3
1
1
3
3
3
2
1
1
1
1
D-8

-------
  Appendix E
Before and After CWA Changes
in 10th Percentile Dissolved
Oxygen at the RF1 Level
Table
E-1  Before and After CWA Changes in 10th Percentile Dissolved Oxygen at the RF1 Level
E-3
                                  E-1

-------
Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
E-2

-------
Appendix E: Before and After CWA Changes in DO at the Rf1 Reach Level
Table D-1 . Before and


Rank
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68

Rfl
Unit No.
10170203037
04100002001
04110002001
05030103007
07070002034
05120201004
05080002008
07120004018
07090001004
05020006031
04040002005
02040201011
04030101012
03170006007
06010102004
08030203006
04040003001
04030104002
08030205018
05050008006
04120102002
03050109053
07120004002
05120201013
03050103037
03170006025
18090208001
06010104007
04130003001
18020103014
02040202045
07010206001
07140201014
07120007006
02040205007
03050109068
02040202035
03180004009
05080001019
05090101004
07120003006
03100204003
02040202043
05120201011
04100009001
03100204001
02040202027
08030204015
07120004010
02040201004
18070203005
05090202001
07130001005
02040202085
01080205033
04100009005
07140201013
06010205001
03040201049
07060005028
02040202030
06010105021
07120006001
06020001020
04110001004
02040203002
05090201001
04040001010
After CWA Changes in 10th Percentile

Rfl
Name
BIG SIOUX R
RIVER RAISIN
CUYAHOGA R
MAHONING R
WISCONSIN R
WHITE R
GREAT MIAMI R
DU PAGE R, E BR
ROCK R
CASSELMAN R
ROOT R
NESHAMINY R
MANITOWOC R
PASCAGOULA R
HOLSTON R, S FK
ENID L
MILWAUKEE R
OCONTO R
GRENADA L
KANAWHA R
CATTARAUGUS CR
REEDY R
DBS PLAINS R
WHITE R
CATAWBA R
ESCATAWPA R
MOJAVE R
CHEROKEE L
GENESEE R
SACRAMENTO R
DELAWARE R
MISSISSIPPI R
KASKASKIA R
FOX R
BRANDYWINE CR, E BR
SALADA R
DELAWARE R
PEARL R
GREAT MIAMI R
OHIO R
LITTLE CALUMET R
ALAFIA R
DELAWARE R
WHITE R
MAUMEE R
ALAFIA R
DELAWARE R
COLDWATER R
DBS PLAINS R
DELAWARE R
SANTA ANA R
LITTLE MIAMI R
ILLINOIS R
DELAWARE R
CONNECTICUT R
MAUMEE R
KASKASKIA R
CLINCH R
JEFFRIES CR
MISSISSIPPI R
DELAWARE R
FRENCH BROAD R
FOX R
TENNESSEE R
BLACK R
WASSAHICKON CR
OHIO R
*B
Mean
Before
CWA
0.0000
1.6000
0.2950
1.0900
0.8800
0.6900
0.2000
0.5750
2.7600
2.9600
0.9400
2.6000
5.9500
0.0000
1.6000
0.0000
2.1800
0.5000
0.0000
0.0000
3.3000
1.9500
1.7620
2.2267
1.6780
0.0000
4.0200
0.1570
1.0425
5.9200
1.2000
2.5246
2.8933
4.4000
4.6000
0.5200
0.7000
2.0000
3.5000
3.2000
0.0000
2.7400
1.6000
3.3800
0.9835
2.4550
0.2000
0.0000
0.3000
2.8800
4.1400
4.0050
3.1900
0.4000
4.3000
4.0690
2.7400
1.6140
2.4400
3.3450
0.5000
4.1000
3.6600
3.2200
1.3775
3.8300
4.4000
0.5700
Dissolved Oxygen (mg/L) at the
Mean
After
CWA
7.2200
8.3400
6.4967
7.1600
6.8400
6.4240
5.8600
5.9200
8.0500
8.0000
5.9400
7.5600
10.9000
4.9200
6.4800
4.8673
6.9567
5.2000
4.6160
4.5667
7.6000
6.2270
6.0000
6.3750
5.8000
4.0983
7.9767
4.1007
4.7100
9.5500
4.7000
5.9924
6.2000
7.6800
7.7800
3.6925
3.8600
5.0000
6.4800
6.1600
2.9214
5.6000
4.4500
6.2200
3.8000
5.2600
3.0000
2.7990
3.0600
5.6300
6.8500
6.6800
5.8500
3.0300
6.8980
6.6660
5.3367
4.1965
5.0100
5.8900
3.0000
6.6000
6.1591
5.7067
3.8400
6.2750
6.8400
3.0056
RF1 Level
# Stations
Differ-
ence
7.2200
6.7400
6.2017
6.0700
5.9600
5.7340
5.6600
5.3450
5.2900
5.0400
5.0000
4.9600
4.9500
4.9200
4.8800
4.8673
4.7767
4.7000
4.6160
4.5667
4.3000
4.2770
4.2380
4.1483
4.1220
4.0983
3.9567
3.9437
3.6675
3.6300
3.5000
3.4678
3.3067
3.2800
3.1800
3.1725
3.1600
3.0000
2.9800
2.9600
2.9214
2.8600
2.8500
2.8400
2.8165
2.8050
2.8000
2.7990
2.7600
2.7500
2.7100
2.6750
2.6600
2.6300
2.5980
2.5970
2.5967
2.5825
2.5700
2.5450
2.5000
2.5000
2.4991
2.4867
2.4625
2.4450
2.4400
2.4356
Before
cm
1
2
2
1
1
5
1
4
1
1
1
1
1
1
1
1
2
1
1
2
1
4
2
3
5
1
2
1
4
1
2
13
3
1
1
1
1
2
1
1
1
2
1
3
4
2
1
1
3
3
2
2
2
1
1
3
2
1
2
4
2
1
1
2
4
1
1
2
After
CWA
1
2
24
1
1
1
1
3
1
1
1
1
1
7
2
3
3
1
4
3
2
10
1
2
1
6
3
3
2
2
1
26
2
4
1
4
2
1
1
1
7
1
1
1
2
1
1
1
4
1
2
1
2
1
1
5
3
2
2
1
3
1
11
3
2
2
1
5
                                                          E-3

-------
Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
Rank
69
70
71
72
73
74
75
76
77
78
79
80
81
82
83
84
85
86
87
88
89
90
91
92
93
94
95
96
97
98
99
100
101
102
103
104
105
106
107
108
109
110
111
112
113
114
115
116
117
118
119
120
121
122
123
124
125
126
127
128
129
130
131
132
133
134
135
136
137
138
139
140
141
142
143
144
145
146
147
148
149
Rfl
Unit No.
03180004027
07130006003
03040201045
14010005007
03010106018
03170001001
06010207003
09020301004
Q7140106002
07120005013
05030103001
07040001001
11070207018
07120004017
03050101086
07040001012
05120202031
05140101002
05030101014
07090004004
03050208037
07120004019
07120004007
08020401001
05080001001
02040202048
05030203050
07130001025
17110013003
02040201002
03050103013
06020001030
17080005007
17110013004
07120004012
07140201004
17090003063
04080204005
07090006003
06010108010
05140202016
07130001026
02070007003
04140203001
06010102018
17080005002
04030101020
10190006002
07030005018
11110207005
07120005001
04030101008
03040202022
05020003026
03040204015
18040005002
18080003022
02050306013
03040201038
03040201005
03010106001
05120114001
05010009001
05020003016
11140208006
03180005003
05020002007
05050002030
07070003013
08080203011
10190007003
07020012013
03140305004
07130003018
03100101010
17110011002
05120103010
05130108022
03170008001
10200203040
03040202014
Rfl
Name
BOGUE LUSA CR
SANGAMON R
BIG BLACK CR
COLORADO R
ROANOKE R
OKATIBBEE CR
CLINCH R
RED R
BIG MUDDY R
ILLINOIS R
MAHONING R
MISSISSIPPI R
*A
DU PAGE R
CROWDERS CR
VERMILLION R
WHITE R
OHIO R
OHIO R
SUGAR R
SANDERS BR
DU PAGE R, W BR
CHICAGO SHIP CANAL
ARKANSAS R
MAD R
DELAWARE R
LITTLE KANAWHA R
ILLINOIS R
ELLIOT BAY
DELAWARE R
CANE CR
TENNESSEE R
COWLITZ R
DUWAMISH WATERWAY
DBS PLAINS R
L SHELBYVILLE
WILLAMETTE R
FLINT R
KISHWAUKEE R
NOLICHUCKY R
OHIO R
ILLINOIS R
SHENANDOAH R
OSWEGO R
S HOLSTON L
COWEMAN R
SHEBOYGAN R
THOMPSON R
ST CROIX R
ARKANSAS R
ILLINOIS R
E TWIN R
LITTLE LYNCHES R
MONONGAHELA R
LITTLE PEE DEE R
MOKELUMNE R
SUSAN R
SUSQUEHANNA R
BLACK CR
PEE DEE R
ROANOKE R
LITTLE WABASH R
ALLEGHENY R
MONONGAHELA R
SALINE BAYOU
BOGUE CHITO R
WEST FORK R
NEW R
CASTLE ROCK FLOWAGE
CALCASIEU R
CACHE LA POUDRE R
MINNESOTA R
ESCAMBIA R
ILLINOIS R
PEACE R
SNOHOMISH R
MISSISSINEWA R
CUMBERLAND R, CANEY
ESCATAWPA R
SALT CR
LYNCHES R
Mean
Before
cm
4
0
2
4
0
3
5
4
2
3.
1
3
1
4
1.
4
3.
3.
4
5.
1.
2.
0
5.
2
3
5.
4
4.
2 .
0
3.
8.
5
2.
5.
7
4
5.
5.
5
1.
5
4
3 .
5
4 .
5
5
6.
5
4.
4 .
5
4.
7 .
6
0
4.
4.
4
2
6.
6.
4
6
4.
5.
5.
4.
6
5.
5.
4
4
8.
5.
4
1
4.
5
.1333
0000
.1000
.8800
.3633
.3000
.2600
.1000
.2900
.9320
.9225
.9390
.6000
.0000
.9000
.2205
.4200
.4000
.5300
.9000
.9167
9333
0250
6500
8200
3100
1400
2700
3500
8400
0000
9000
1800
6940
1500
4000
5200
2350
0000
5800
1400
2000
2600
3000
7380
9900
5000
6500
7580
2000
2170
5800
6417
8100
6400
4800
8200
8800
5350
6133
6000
3400
0600
3000
1600
0000
8000
7000
0000
3200
2578
6690
1200
3920
1300
3600
8400
2000
5800
4000
5825
Mean
After
CWA
6
2
4
7
2
5
7
6
4
6
3
5
3
5
3
6
5
5
6
7
3
4
1
7.
4 .
5
6
5
5.
4
1
5.
9
7
3.
6.
8
5.
6.
7
6.
2 .
6
5.
5
7
5
6.
7
7
6.
5.
5
7 .
5.
8
8.
2.
5.
5
5
3 .
7 .
7.
5
7.
5
6
6
5.
7 .
6
6
5.
5
9.
6
5.
2
5 .
6.
.5600
.3875
.4500
.2200
.5700
.5000
.4390
.2600
.3988
.0400
.9200
.9000
.5000
.8620
.7600
.0800
.2700
.2500
.3760
.7000
.7033
7033
.7800
.3900
.5400
.0000
8250
.9000
.9600
.4200
.5800
.4717
.7300
2400
.6835
9100
9800
.6800
.4225
0000
.5400
.6000
6600
7000
1150
3400
8200
9620
0500
4900
4800
.8300
8850
0480
8600
TOOO
0400
0700
7100
7800
7600
5000
1850
4120
2400
0000
8000
7000
0000
3200
.2500
6600
1000
3650
0800
3000
7800
1100
4900
3007
4600
# Stations
Differ-
ence
2
2
2
2
2
2
2
2
2
2
1
1
1
1
1
1
1
1
1
1
1
1
1
1.
1
1
1.
1
1
1.
1.
1
1.
1
1
1.
1.
1.
1
1.
1
1
1.
1.
1
1.
1
1
1
1.
1.
1
1.
1.
1
1
1.
1.
1
1
1.
1.
1.
1
1.
1.
1
1.
1.
1
0
0
0.
0.
0.
0
0.
0.
0
0
0.
.4267
.3875
.3500
.3400
.2067
.2000
.1790
.1600
.1088
.1080
.9975
.9610
.9000
.8620
.8600
.8595
.8500
.8500
.8460
.8000
.7866
7700
.7550
.7400
7200
6900
.6850
6300
6100
.5800
.5800
5717
.5500
5460
5335
5100
.4600
4450
4225
4200
4000
4000
4000
4000
3770
3500
3200
3120
2920
2900
2630
2500
2433
2380
2200
2200
2200
1900
1750
1667
1600
1600
1250
1120
0800
0000
0000
0000
0000
0000
9922
9910
9800
9730
9500
9400
9400
9100
9100
9007
8775
Before After
CWA CWA
3
1
1
1
3
2
2
2
1
1
4
2
1
2
1
2
1
1
1
1
3
3
1
2
1
2
1
1
2
2
1
1
1
5
1
1
3
2
1
1
1
1
1
1
1
2
1
3
2
1
2
1
3
1
2
1
1
1
2
3
1
1
1
1
1
2
1
1
1
2
9
1
2
2
1
2
1
1
3
1
2
1
4
1
1
1
1
2
1
8
2
1
2
1
5
2
1
1
1
5
1
3
9
2
2
1
2
4
2
1
1
1
11
2
3
2
2
1
1
2
1
1
1
2
1
2
1
1
5
1
2
3
1
2
3
1
1
1
1
1
1
1
2
14
1
1
1
1
2
1
1
1
1
1
2
1
1
1
1
8
9
1
E-4

-------
Appendix E: Before and After CWA Changes in DO at the Rf1 Reach Level
Rank
150
151
152
153
154
155
156
157
158
159
160
161
162
163
164
165
166
167
168
169
170
171
172
173
174
175
176
177
178
179
180
181
182
183
184
185
186
187
188
189
190
191
192
193
194
195
196
197
198
199
200
201
202
203
204
205
206
207
208
209
210
211
212
213
214
215
216
217
218
219
220
221
222
223
224
225
226
227
228
229
230
231
232
233
Rfl
Unit No.
05020002001
17060110001
17010305001
03040202012
07120004009
03040201008
18070203008
07120006007
05120113006
10190006001
07130002001
07020012001
17110019081
04110003008
03050202006
08040304014
08030206007
03040204018
17090003058
05030202005
17020011001
04080201001
05120201032
08090203007
17110007006
04110003005
08040304013
17020015001
03040204016
05120101004
04110004001
03160203006
07010207005
08040302001
03050103018
07010206002
05020003003
03050205015
04010302018
03040201039
08070205005
11110207011
04030108001
05050005005
07040007002
06030002052
18030012014
06030005051
03160203007
06010103019
03050103021
03050205021
04080206001
03050202011
10190007004
06020001032
06020001001
05120106002
07040001008
02070001001
17080005011
05020006024
03040202015
17090003009
09030004013
05020004001
05050001044
05120108018
10180009016
08030201005
02070010033
05020005030
03160203015
06020001033
03170008002
05070204034
05010006005
07030005003
08050001011
03050207015
04010302002
07050005019
08040301020
05120201007
Rfl
Name
WEST FORK R
SNAKE R
SPOKANE R
LYNCHES R
CHICAGO SHIP CANAL
PEE DEE R
SANTA ANA R
FOX R
WABASH R
THOMPSON R
VERMILION R
MINNESOTA R
*W
ASHTABULA R
ASHLEY R
LITTLE R
BLACK CR
LITTLE PEE DEE R
WILLAMETTE R
OHIO R
WENATCHEE R
TITTABABASSEE R
EAGLE CR
INTRACOASTAL WATERWA
SKAGIT R
CHAGRIN R
LITTLE R
CRAB CR
LITTLE PEE DEE R
WABASH R
GRAND R
TOMBIGBEE R
RUM R
CASTOR CR
CATAWBA R
MISSISSIPPI R
MONONGAHELA R
POLK SWAMP
MONTREAL R
BLACK CR
TANGIPAHOA R
ARKANSAS R
MENOMINEE R
GAULEY R
BLACK R
TENNESSEE R
KINGS R
WILSON L
TOMBIGBEE R
WATAUGA R
TWELVEMILE CR
EDISTO R
SAGINAW R
ASHLEY R
CACHE LA POUDRE R
TENNESSEE R
TENNESSEE R
TIPPECANOE R
MISSISSIPPI R
POTOMAC R, S BR
TOUTLE R
CASSELMAN R
LITTLE FORK CR
WILLAMETTE R
RAINY R
CHEAT R
NEW R
WABASH R
H PLATTE R
SARDIS L
POTOMAC R
DUNKARD CR
TOMBIGBEE R
TENNESSEE R
ESCATAWPA R
BIG SANDY R
ALLEGHENY R
ST CROIX R
BOEUF R
LEMON CR
WHITE R
CHIPPEWA R
RED R
WHITE R
Mean
Before
CWA
6
7
7.
5
0
5
3
5
4
6
3
4
8
5
3
3
5
4
7
5
9
6
4
4
9
5
3
6
3
6
5
5
5
3
4
4
5
3.
7
3
6
6
6
7
7.
5
7
4
6
6.
3
5
4
3
6.
4
4
6
5
6
8.
8.
6.
8.
7
6
6
6
7.
3 .
4.
7.
6
4
5
5.
7
5.
4.
3.
7.
5 .
5 .
5
7200
.1700
.2000
.1833
4460
7250
6267
.5300
.9900
.2400
7750
. 7316
.0429
.1517
.7200
2400
5200
.7300
.2700
7000
.3000
0350
.7600
.5500
4200
3350
.5200
.6800
4320
.3400
6650
6040
.8000
.4400
6725
4700
.5400
.3000
.8000
5450
2000
.5200
.4400
.0900
.4500
4790
2400
8000
.2400
.0950
7600
4000
8989
.6200
.7900
.4000
.6140
1350
5850
3000
.8000
.6100
.0933
.3600
2000
5033
6000
5000
0000
4200
3400
7100
8200
4400
3700
7200
2000
4125
1600
8050
1200
3400
4500
5271
Mean
After
CWA
7.5820
8 0300
8 0587
6 0100
1.2650
6.5400
4 4333
6.3343
5 7800
7.0000
4 .4750
5 4257
8 7200
5.7700
4.3300
3.8500
6.1100
5 3000
7.8400
6.2600
9 8600
6.5800
5 2967
5.0750
9.9350
5 8400
4 0250
7 1800
3 .9187
6.8050
6.120C
6 048C
6.2400
3.8700
5.1000
4 8606
5 9000
3 6500
8.1500
3.8888
6 5400
6 8600
6.7500
7.4000
7.7400
5.7500
7 5000
5 0500
6 4850
6.3333
3.9900
5 6200
5 1167
3 8350
6.9960
4.6000
4.8067
6 3000
5 7467
6 4500
8.9200
8.7200
6.1567
8.4000
7 2333
6 5300
6.5700
6.4700
6 9500
3 .3680
4.2520
7.6000
6 6950
4 .3000
5 2250
5.5500
7 0290
5.2200
3 9560
3.5950
6.8800
5 1000
5 2000
5 2750
# Stations
Differ-
ence
0.8620
0 8600
0 8587
0.8267
0.8190
0.8150
0 8066
0.8043
0 7900
0.7600
0.7000
0.6941
0 6771
0.6183
0.6100
0.6100
0 5900
0 5700
0.5700
0.5600
0 5600
0 5450
0.5367
0.5250
0.5150
0.5050
0 5050
0.5000
0.4867
0 .4650
0 4550
0 4440
0.4400
0.4300
0 4275
0 3906
0 3600
0.3500
0.3500
0 3438
0 3400
0.3400
0.3100
0.3100
0 2900
0 2710
0 2600
0 2500
0.2450
0 2383
0 2300
0 2200
0 2178
0 2150
0.2060
0.2000
0 1927
0 1650
0 1617
0 1500
0.1200
0.1100
0.0634
0.0400
0.0333
0 0267
-0 0300
-0.0300
-0.0500
-0.0520
-0.0880
-0.1100
-0.1250
-0 1400
-0.1450
-0 1700
-0.1710
-0.1925
-0.2040
-0.2100
-0.2400
-0.2400
-0.2500
-0 2521
Before After
CWA CWA
1
1
2
3
2
4
3
1
1
1
2
9
7
3
1
1
1
1
1
1
1
2
1
1
2
2
1
3
5
1
3
5
1
1
2
5
2
1
1
3
2
1
1
1
1
1
1
1
1
2
1
1
19
1
3
1
3
2
4
1
1
2
3
1
1
3
1
1
1
1
1
1
2
1
1
1
1
4
1
2
1
1
1
7
1
1
3
2
2
1
3
3
1
1
2
7
1
2
1
1
4
1
1
1
1
1
3
2
2
1
1
1
4
2
3
5
1
2
1
36
1
1
1
8
1
2
2
1
1
1
2
2
2
3
2
1
3
2
5
1
3
1
3
1
1
1
3
1
3
2
1
1
1
1
5
1
2
1
2
2
10
1
2
2
1
1
2
2
                                                          E-5

-------
 Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
Rank
234
235
236
237
238
239
240
241
242
243
244
245
246
247
248
249
250
251
252
253
254
255
256
257
258
259
260
261
262
263
264
265
266
267
268
269
270
271
272
273
274
275
276
277
278
279
280
281
282
283
284
285
286
287
288
289
290
291
292
293
294
295
296
297
298
299
300
301
302
303
304
305
306
307
308
309
310
311
Rfl
Unit No.
10190018001
05050006007
03050105019
06040006017
17110008007
06020001019
02080206006
05050007001
08080203008
03050202010
05120105009
07020007002
07080208002
05120101006
08090201013
05030204009
04090005001
05070102002
05120201009
05120201006
03050205016
03050201018
03060101024
03050109075
06010102009
08040202006
03040202024
05020001027
05120104001
08050002003
06030002001
03040201003
04030105002
03050103054
08050001024
12010005005
05020001001
03050101007
11140202005
05020006001
05070201010
05020005001
03160106031
05120101003
03050205009
08080203001
08050001026
10240006001
16050102006
05020004003
05030201007
07090005004
16050101004
05020003001
03050208004
08050003005
05120108005
05020005006
12010004010
05010006001
07120003002
05030203014
08080202035
08040202002
03040202004
03040205003
10270207005
03050101005
07090005006
07140204001
05120112010
08030201003
03060106055
05120111 001
17110013005
11140203012
03040201050
11140304013
Rfl
Name
S PLATTE R
KANAWHA R
BROAD R
TENNESSEE R
STILLAGUAMISH R
TENNESSEE R
JAMES R
ELK R
CALCASIEU R
ASHLEY R
WABASH R
MINNESOTA R
L MCBRIDE
WABASH R
TCHEFUNCTA R
HOCKING R
HURON R
GUYANDOTTE R
WHITE R
FALL CR
EDISTO R
COOPER RIVER W BR
GOLDEN CR
GEORGES CR
BOONE L
BAYOU DE LOUTRE
HANGING ROCK CR
TYGART VALLEY R
EEL R
BAYOU MACON
TENNESSEE R
CATFISH CR
PESHTIGO R
ROCKY CR
BAYOU LAFOURCHE
SABINE R
TYGART VALLEY R
CATAWBA R
RED R
YOUGHIOGHENY R
BIG SANDY R, TUG FK
MONONGAHELA R
TOMBIGBEE R
WABASH R
EDISTO R
CALCASIEU R
BAYOU BOEUF
LITTLE NEMAHA R
TRUCKEE R
CHEAT R
OHIO R
ROCK R
L TAHOE
MONONGAHELA R
ASHEPOO R
TENSAS R
WABASH R
MONONGAHELA R
TOLEDO BEND RES
ALLEGHENY R
CHICAGO SAN SHIP CA
LITTLE KANAWHA R
MERMENTAU R
OUACHITA R
LYNCHES R
BLACK R
LITTLE BLUE R
L WYLIE
ROCK R
KASKASKIA R
EMBARRAS R, N FK
LITTLE TALLAHATCHIE
SAVANNAH R
WABASH R
GREEN R
BAYOU DORCHEAT
JEFFRIES CR
*B
Mean
Before
CUR
7 0600
7.0500
6 7000
5.4000
8 6750
5.0460
6 1400
6 4000
6 0000
3 3200
6.8600
6 9480
3 2840
7 0000
6.4000
4.8600
5 0000
6. 6200
4 6700
5.9600
4.9000
6 0450
7 9200
7 5500
2.5300
1.5000
4 9800
7 2500
7 0000
3 7000
5.4940
2 4900
6 2400
2 9950
3.6800
6.5800
8 1000
4 8000
7 1200
8 1200
6.2500
7 6000
5 5200
6 0100
4 6000
3.4500
5.2000
6.8200
7 7050
7 0800
7 1000
7 0600
7.1900
7 6000
3 4000
3 1000
7 0000
8.5000
4.9600
8.8000
6 4122
5 3900
2 2600
3 7700
6.0400
4 7000
7 3300
7 3000
5 5000
4 1300
5.0800
6.2000
8 2100
5 1000
8 4200
5 3000
4 6200
6 6400
Mean
After
CWA
6 8000
6 7800
6.4200
5 1133
8 3600
4 7300
5 7930
6 0500
5.6000
2 9000
6 4350
6 5200
2.8525
6 5600
5 9600
4 3850
4 5000
6 1000
4 1400
5.4250
4 3500
5 4650
7.3400
6.9250
1 9000
0 8600
4 3067
6.5500
6 1300
2 8300
4 6000
1.5575
5.3000
2 .0087
2 6670
5 5400
7 0513
3 .7500
6.0500
7 0400
5 1000
6 4060
4.3000
4.7650
3 3350
2 1700
3 .9000
5 5200
6.3852
5.7500
5 7500
5 7000
5 8175
6.2260
1.9600
1.6400
5 4640
6 8383
3.2000
7 0150
4.6180
3 5800
0 3200
1 7900
4.0367
2.6890
5.3000
5.1025
3 1250
1 7150
2 6600
3 6400
5 6150
2 5000
5 6300
2 4300
0 4300
0 6300
# Stations
Differ-
ence
-0 2600
-0.2700
-0.2800
-0 2867
-0 3150
-0.3160
-0.3470
-0 3500
-0 4000
-0 4200
-0.4250
-0 4280
-0 4315
-0 4400
-0 4400
-0.4750
-0.5000
-0 5200
-0 5300
-0 5350
-0.5500
-0 5800
-0 5800
-0 6250
-0.6300
-0.6400
-0 6733
-0 7000
-0 8700
-0.8700
-0.8940
-0 9325
-0 9400
-0 9863
-1 0130
-1.0400
-1.0487
-1 0500
-1 0700
-1 0800
-1.1500
-1.1940
-1 2200
-1 2450
-1 2650
-1.2800
-1.3000
-1 3000
-1 3198
-1 3300
-1 3500
-1.3600
-1.3725
-1.3740
-1.4400
-1 4600
-1 5360
-1 6617
-1.7600
-1.7850
-1 7942
-1 8100
-1 9400
-1 9800
-2.0033
-2.0110
-2.0300
-2.1975
-2 3750
-2 4150
-2 .4200
-2 5600
-2 .5950
-2 .6000
-2 7900
-2 8700
-4 1900
-6 0100
Before
CWA
1

1
1
2
1
1
1
2
1
1
1
5
1
2
1
2
1
1
1
1
1
1
1
1
2
2
1
1
2
1
2
1
2
1
1
1
1
2
1
1
1
1
1
1
2
1
1
2
2
1
1
1
1
1
1
1
1
1
1
5
1
2
2
1
1
1
1
1
1
1
1
1
1
1
2
1
2
After
CWA
1
1
I
3
1
2
1
1
1
1
1
1
4
1
1
2
1
1
1
2
1
2
2
2
1
1
3
1
1
2
1
6
1
4
2
1
3
2
2
1
1
9
1
1
2
2
1
1
5
1
1
2
4
5
1
1
1
6
1
4
10
2
1

3
5
1
4
4
2
2
1
3
1
2
1
2
2
E-6

-------
Glossary
10th Percentile
90th Percentile
Activated sludge
Advanced primary treatment
Advanced secondary treatment
Advanced wastewater treatment
(AWT)
Aerobic
Algae
A low end statistic based on ranking a data set from the minimum to
the maximum value. The 10th percentile defines the value for which
10% of the ranked data set is less than the statistic and 90% of the
data set is greater than the statistic. Used in this study to define
"worst-case" conditions for evaluation of "before and after" trends of
dissolved oxygen.

A high end statistic based on ranking a data set from the minimum to
the maximum value. The 90th percentile defines the value for which
90% of the ranked data set is less the statistic and 10% of the data
set is greater than the  statistic. Used in this study to define "worst-
case" conditions for evaluation of "before and after" trends of
BOD5.

A secondary wastewater treatment process that removes organic
matter  by mixing air and recycled sludge bacteria with sewage to
promote decomposition.

Waste  treatment process  that incorporates primary sedimentation of
suspended solids with chemical addition and flocculation to increase
the overall removal of organic solids. Advanced primary treatment
typically achieves about 50% removal of suspended solids and BOD.

Biological or chemical treatment processes added to a secondary
treatment plant including a conventional activated sludge to increase
the removal of solids and BOD. Typical removal rates for advanced
secondary plants are on the order of 90% removal of solids and
BOD.

Wastewater treatment process that includes combinations of physical
and chemical operation units designed to remove nutrients, toxic
substances, or other pollutants. Advanced, or tertiary, treatment
processes treat effluent from secondary treatment facilities using
processes such as nutrient removal (nitrification, denitrification),
filtration, or carbon adsorption. Tertiary treatment plants typically
achieve about 95% removal of solids and BOD in addition to removal
of nutrients or other materials.

Environmental conditions characterized by the presence of dissolved
oxygen; used to describe biological or chemical processes that occur
in the presence of oxygen.

Any organisms of a group of chiefly aquatic microscopic nonvascular
plants;  most algae have chlorophyll as the primary pigment for carbon
fixation. As primary producers, algae serve as the base of the aquatic
food web, providing food for zooplankton and fish resources. An
overabundance of algae in natural waters is known as eutrophication.
                                                                                       Glossary -1

-------
Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
Algal bloom



Ambient water quality



Ammonia


Ammonia toxicity


Anadromous

Anaerobic


Anoxic

Anthropogenic
Assimilative capacity
Bacterial decomposition
Base flow
Benthic
Biochemical oxygen demand (BOD)
Rapidly occurring growth and accumulation of algae within a body of
water. It usually results from excessive nutrient loading and/or
sluggish circulation regime with a long residence time. Persistent and
frequent bloom can result in low oxygen conditions.

Natural concentration of water quality constituents prior to mixing of
either point or nonpoint source load of contaminants. Reference
ambient concentration is used to indicate the concentration of a
chemical that will not cause adverse impact to human health.

Inorganic form of nitrogen; product of hydrolysis of organic nitrogen
and denitrification. Ammonia is preferentially used by phytoplankton
over nitrate for uptake of inorganic nitrogen.

Under specific conditions of temperature and pH, the un-ionized
component of ammonia can be toxic to aquatic life. The un-ionized
component of ammonia increases with pH and temperature.

Characteristic of fish that live in the ocean but spawn in freshwater.
Example: Salmon and steelhead.

Environmental condition characterized by zero oxygen levels. De-
scribes biological and chemical processes that occur in the absence
ofoxygen.

Aquatic environmental conditions containing zero or little dissolved
oxygen. See also anaerobic.

Pertains to the [environmental] influence of human activities.

The amount of contaminant load (expressed as mass per unit time)
that can be discharged to a specific stream or river without exceeding
water quality standards or criteria.  Assimilative capacity is used to
define the ability of a waterbody to naturally absorb and use waste
matter and organic materials without impairing water quality or
harming aquatic life.

Breakdown by oxidation, or decay, of organic matter by heterotrophic
bacteria. Bacteria use  the organic carbon in organic matter as the
energy  source for cell synthesis.

Sustained, low flow discharge rate in a stream derived from ground-
water discharge into the stream channel. During extended periods of
low precipitation, baseflow may account for most, or all, of the
streamflow.

Refers to material, especially sediment, at the bottom of an aquatic
ecosystem. It can be used to describe the organisms that live on, or
in, the bottom of a waterbody.

The amount of oxygen per unit volume of water required to bacteri-
ally or chemically oxidize (stabilize) the oxidizable matter in water.
Biochemical oxygen demand measurements are usually conducted
over specific time intervals (5,10,20,30 days). The term BOD5
generally refers to standard 5-day BOD test.
Glossary  -2

-------
                                                                                           Glossary
Carbonaceous


Carbonaceous BOD


Chlorophyll




Coliform bacteria



Combined sewer overflows (CSOs)



Commercial water use


Concentration



Confluence


Constituent



Construction Grants Program
Consumptive use




Contamination


Conventional pollutants
Pertaining to or containing organic carbon derived from plant and
animal residues.

Biochemical oxygen demand accounted for by decomposition of
organic carbon derived from plant and animal residues.

A group of green photosynthetic pigments that occur primarily in the
chloroplast of plant cells. The amount of chlorophyll-a, a specific
pigment, is frequently used as a measure of algal biomass in natural
waters.

A group of bacteria that normally live within the intestines of mam-
mals, including humans. Coliform bacteria are used as an indicator of
the presence of sewage in natural waters.

A combined sewer carries both  wastewater and stormwater runoff.
CSOs discharged to receiving water can result in contamination
problems that may prevent the attainment of water quality standards.

Water used for motels, hotels, restaurants, office buildings, and other
commercial  operations.

Mass amount of a substance or material in a given unit volume of
solution. Usually measured in milligrams per liter (mg/1) or parts per
million (ppm).

The physical location where a lower order stream or river flows into
a higher order stream  or river as a tributary. See mouth.

A chemical or biological substance in water, sediments, or biota that
can be measured by an analytical method (e.g., nitrate-N, organic
carbon, or chlorophyll).

Federal funding authorized by amendments (1956 through 1987) to
1948 Federal Water Pollution Control Act to provide technical
assistance and construction money to aid municipalities in building and
upgrading sewerage collection systems and municipal wastewater
treatment plants. After 1972 amendments, $61.1 billion (current year
dollars) in federal funding provided under Clean Water Act to
upgrade municipal wastewater facilities to a minimum of secondary
treatment.

That part of  water withdrawn that is evaporated, transpired, or
incorporated into a manufactured product, or consumed by humans or
animals, or otherwise removed from the immediate waterbody
environment.

Act of polluting or making impure; any indication of chemical, sedi-
ment, or biological impurities.

As specified under the Clean Water Act, conventional contaminants
include suspended solids, coliform bacteria, biochemical oxygen
demand, pH, and oil and grease.
                                                                                        Glossary - 3

-------
Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
Decay




Decomposition



Denitrification



Dilution


Discharge




Discharge permits (NPDES)
Dispersion
Dissolved oxygen (DO)
Diurnal
Domestic wastewater
Domestic water use
Drainage basin
Gradual decrease in the amount of a given substance in a given
system due to various loss/sink processes including chemical and
biological transformation, dissipation to other environmental media, or
deposition into storage areas.

Metabolic breakdown of organic materials; the by-products formation
releases energy and simple organics and inorganic compounds, (see
also respiration)

Describes the decomposition of ammonia compounds, nitrites, and
nitrates (by bacteria) that results in the eventual release of nitrogen
gas into the atmosphere.

Addition of a volume of less concentrated liquid (water) that results in
a decrease in the original concentration.

The volume of water that passes a given point within a given period
of time. It is an all-inclusive outflow term, describing a variety of
flows such  as from a pipe to a stream, or from a stream to a lake or
ocean.

A permit issued by the U.S. EPA or a state regulatory agency that
sets specific limits  on the type and amount of pollutants that a munici-
pality or industry can discharge to a receiving water; it also includes a
compliance schedule for achieving those limits. It is called the
NPDES because the permit process was established under the
National Pollutant Discharge Elimination System, under provisions of
the Federal Clean  Water Act.

The turbulent mixing and spreading of chemical or biological constitu-
ents, including pollutants, in various directions from a point source, at
varying velocities depending on the differential instream flow charac-
teristics.

The amount of oxygen gas that is dissolved in water. It also refers to
a measure of the amount of oxygen available for biochemical activity
in water body, and as indicator of the quality of that water.

Actions or processes having a period or a cycle of approximately one
tidal-day or are completed within a 24-hour period and which recur
every 24 hours.

Also called sanitary wastewater, consists of wastewater discharged
from residences and from commercial, institutional, and similar
facilities.

Water used for household purposes such as drinking, food prepara-
tion, bathing, washing clothes and dishes, watering lawns and gar-
dens, flushing toilets etc. Also called residential water use.

A part of the land area enclosed by a topographic divide from which
direct surface runoff from precipitation normally drains by gravity into
a receiving water.  Also referred to as watershed, river basin, or
hydrologicunit.
Glossary  - 4

-------
                                                                                             Glossary
Dynamic model

Dynamic simulation

Ecosystem


Effluent


Enforcement conferences
Estuary


Eutrophication




Factor of Safety


Fecal coliform bacteria



Flocculation



Flushing characteristics



Frequency analysis



Freshwater
A mathematical formulation describing the physical behavior of a
system or a process and its temporal variability.

Modeling of the behavior of physical, chemical, and/or biological
phenomena and their variation over time.

An interactive system that includes the organisms of a natural
community association together with their abiotic physical, chemical,
and geochemical environment.

Municipal sewage or industrial liquid waste (untreated, partially
treated, or completely treated) that flows out of a treatment plant,
septic system, pipe, etc.

Joint State-Federal water pollution conferences convened by U.S.
Public Health Service under authority of 1956 amendments to the
1948 Federal Water Pollution Control Act. Federal regulatory author-
ity restricted to enforcement of water pollution problems only in
interstate  waters because of the Commerce clause of the U.S.
Constitution.  Fifty-one enforcement conferences were convened
from 1957-1972.

Brackish-water areas influenced by  the ocean tides where the mouth
of the river meets the sea.

Enrichment of an aquatic ecosystem with nutrients (nitrogen,
phosphorusnitrates, phosphates) that accelerate biological productivity
(growth of algae, periphyton and macrophytes/weeds) and an unde-
sirable accumulation of plant algal biomass.

Coefficient used to account for uncertainties in representing, simulat-
ing, or designing a system.

Coliform bacteria that are present in the intestines or feces of warm-
blooded animals including humans. They are often used as indicators
of the sanitary quality of water. See  Coliform bacteria.

The process by which suspended colloidal or very fine particles are
assembled into larger masses or flocules that eventually  settle out of
suspension.

Measure of the displacement of water  from a riverine or estuarine
system as  controlled by the combined actions of freshwater inflow
and tidal mixing and exchange.

A numerical determination of the distribution of values for a param-
eter within a data set.  See 10th percentile, median and 90th percen-
tile.

Water that contains less than 1000 mg/L of dissolved solids. Water
that contains more than 500 mg/L of dissolved solids is undesirable
for drinking water and many industrial  uses.
                                                                                          Glossary - 5

-------
Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
Gaging station
"Grey" literature
Hydrologic Accounting Unit
Hydrologic Catalog Unit
Hydrologic cycle
Hydrologic Region
Hydrologic Sub-Region
 In situ
A specific location on a stream, river, canal, lake or reservoir where
systematic measurements of hydrologic data such as stage height and
streamflow are collected. The USGS maintains and operates a
network of stream gaging stations to collect hydrologic data for many
streams and rivers. Historical streamflow and stage height data is
available from the USGS streamflow database
(www.waterdata.usgs.gov/nwis-w). Earliest records are available
from the  late  19th century for some rivers.

Unpublished technical reports and memoranda, data reports, or other
documents prepared by academic researchers, Federal, state or local
agencies or other institutions and organizations. Typically limited
distribution makes it difficult to obtain except from agency or institu-
tional sources.

Geographical sub-division of watersheds within each Hydrologic Sub-
Region. There are a total of 352 Accounting Units in the United
States with 334 Accounting Units located in the 48 states. Account-
ing Units are identified by a 6-digit code where the first 2-digits
identify the Hydrologic Sub-region as the larger hydrologic units.
Example: 070102 is the Accounting Unit for the Platte-Spunk basin of
the Upper Mississippi River basin.

Geographical sub-division of watersheds within each Hydrologic
Accounting Unit. There are a total of 2150  Catalog Units in the
United States with 2111 Catalog  Units located in the 48 states.
Catalog Units are identified by an 8-digit code where the first 2-digits
identify the Hydrologic Accounting Unit. Example: 07010206 is the
Catalog Unit  for the Twin Cities  area of the Upper Mississippi River.

The representation of the cycle of water on earth based on all
hydrologic processes and the interactions of water between the
atmosphere, surface waters, polar ice, glaciers, and groundwater.

Largest geographical sub-division of the United States into a hierar-
chal succession of hydrologic units based on drainage area. There are
a total of 21 Hydrologic Regions in the United States with 18 Hydro-
logic Regions located within the 48 states. Hydrologic regions are
identified by a 2-digit numerical code from 01-21. Example: 07 is the
Hydrologic Region for the Upper Mississippi River basin.

Geographical sub-division of watersheds within each Hydrologic
Region. There are a total of 222  Sub-Regions in the United States
with 204 Sub-Regions located in the 48 states. Sub-regions are
identified by a 4-digit code with the first 2-digits used to identify the
larger Hydrologic Region. Example: 0701 is the Hydrologic Sub-
region for the Mississippi Headwaters of the Upper Mississippi River
basin.

Latin word for "in place"; in situ measurements consist of measure-
ment of component or processes in a full-scale system or a field
rather than in a laboratory.
Glossary - 6

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                                                                                           Glossary
Industrial water use
Influent


Inorganic


Loading, Load, Loading rate



Low-flow (7Q10)




Major river basin

Margin of Safety (MOS)



Mass balance



Mathematical model
Mean
Median (50th Percentile)
Milligrams per liter (mg/L)
Water used for industrial purposes such as fabricating, processing,
washing and cooling. Industries that use water include steel, chemical
and allied products, paper and allied products, mining and petroleum
refining.

Water volume flow rate or mass loading of a pollutant or other
constituent into a water body or wastewater treatment plant.

Pertaining to matter that is neither living nor immediately derived
from living matter.

The total amount of material (pollutants) entering the  system from
one or multiple sources; measured as a rate in weight (mass) per unit
time.

Low-flow (7Q10) is the 7-day average low flow occurring once in  10
years; this probability-based statistic is used in determining stream
design flow conditions and for evaluating the water quality impact of
effluent discharge limits.

alternative terminology for Hydrologic Region.

A required component of the TMDL that accounts for the uncer-
tainty about the relationship between the pollutant load and the quality
of the receiving waterbody.

An equation that accounts for the flux of mass going into a defined
area and  the flux of mass leaving the defined area. The flux in must
equal the flux out to achieve a mass balance.

A system of mathematical expressions that describe the spatial and
temporal distribution of water quality constituents resulting from fluid
transport and the one, or more, individual processes and interactions
within some prototype aquatic ecosystem. A mathematical water
quality model is used as the basis for waste load allocation evalua-
tions.

The numerical average of a set of observations; computed as the sum
of the observations divided by the number of observations in the data
set.

A middle statistic based on ranking a data set from the minimum to
the maximum value. The median  value divides the data set into so
that one-half of the values are lower than the median and one-half of
the values are greater than the median. The median is also defined as
the 50th percentile value.

A unit of measurement expressing the concentration of a constituent
in solution as the weight (mass) of solute (1 milligram) per unit
volume (1 liter) of water; equivalent to 1 part per million (ppm) for a
water density ~1 g cm-3. 1 mg/L  = 1000 ug/L;  1 g/L = 1000 mg/L.
                                                                                         Glossary - 7

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Waste/water Treatment
Million gallons per day (mgd)
Mineralization
Mixing characteristics
Most probable number (mpn)
Municipal wastewater inventory
N/P ratio
Natural waters
Needs Survey
Nitrate (NO3) and Nitrite (NO2)


Nitrification



Nitrifier organisms


Nitrobacter

Nitrogenous BOD (NBOD)


Nitrosomonas
Rate of water volume discharge representing a volume of 1 million
gallons of water passing across a given location in a time interval of 1
day. A flow rate of 1 mgd = 1.54723 cubic feet per second (cfs) =
0.04381 cubic meters per second (cms).

The transformation of organic matter into a mineral or an inorganic
compound.

Refers to the tendency for natural waters to blend; i.e. for dissolved
and particulate substances to disperse into adjacent waters.

Measure of concentration, or abundance, of total and fecal coliform
bacteria based on incubation results and a statistical interpretation of
the results.

US Public Health Service compilations of inventory of municipal
wastewater plants,  population served and influent flow by different
categories of municipal wastewater treatment facilities. Inventories
compiled in 1950,1962 and 1968.

The ratio of nitrogen to phosphorus in an aquatic system. The ratio is
used as an indicator of the nutrient limiting conditions for algal
growth; also used as indicator for the analysis of trophic levels of
receiving waters.

Flowing waterbody within a physical system that has developed
without human intervention, in which natural processes continue to
take place; streams, rivers, lakes, bays, estuaries and coastal and
open ocean are examples of natural waters.

USEPA Clean Water Needs Surveys (CWNS) compiled from 1976
through 1996 at 2 to 4 year intervals. Needs Surveys document
inventory of wastewater plants, population served,  influent flow and
effluent load of BODS and TSS by 6 different categories of municipal
wastewater treatment facilities. Information is compiled for existing
conditions (e.g., 1996) and 20-year projections (e.g., 2016).

Oxidized nitrogen  species. Nitrate is the form of nitrogen used by
aquatic plants for photosynthesis.

Biologically mediated process of the oxidation of ammonium salts to
nitrites (via Nitrosomonas bacteria) and the further oxidation of nitrite
to nitrate via Nitrobacter bacteria.

Bacterial organisms that mediate the biochemical oxidative processes
ofnitrification.

Type of bacteria responsible for the conversion of nitrite to nitrate.

Refers to the biochemical oxygen demand associated with the
oxidation of ammonia to nitrite and nitrate.

Type of bacteria responsible for the oxidation of ammonia to  the
intermediate product nitrite.
 Glossary - 8

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                                                                                            Glossary
Nonpoint source
Numerical model
Nutrient
Organic matter
Organic nitrogen

Outfall


Oxidation
Oxygen demand


Oxygen depletion

Oxygen sag
Oxygen saturation
Parameters


Parts per million (ppm)
 Pollution that is not released through pipes but rather originates from
 multiple sources over a relatively large drainage area. Nonpoint
 sources can be divided into source activities related to either land or
 water use including failing septic tanks, improper animal-keeping
 practices, forest practices, and urban and rural runoff from a drain-
 age basin.

 Models that approximate a solution of governing partial differential
 equations which describe a natural process. The approximation uses
 a numerical discretization of the space and time components of the
 system or process.

 A primary element necessary for the growth of living organisms.
 Carbon dioxide, nitrogen, and phosphorus, for example, are required
 nutrients for phytoplankton (algae) growth.

 The organic fraction that includes plant and animal residue at various
 stages of decomposition, cells and tissues of soil organisms, and
 substances synthesized by the soil population. Commonly determined
 as the amount of organic material contained in a soil or water sample.

 Organic form of nitrogen bound to organic matter.

 Location point where wastewater or stormwater flows from a
 conduit, stream, or drainage ditch into natural waters.

 The chemical union of oxygen with metals or organic compounds
 accompanied by a removal of hydrogen or another atom. It is an
 important factor for soil formation and permits the release of energy
 from cellular  fuels.

 Measure of the dissolved oxygen used by a system (microorganisms)
 and or chemical compounds in the oxidation of organic matter.  See
 also biochemical oxygen demand.

 Deficit of dissolved oxygen in a natural waters system due to oxida-
 tion of natural and anthropogenic organic matter.

 Description of characteristic spatial trend of the concentration of
 dissolved oxygen in a stream or river downstream of high loading rate
 of oxygen-demanding materials from tributaries, municipal or indus-
 trial wastewater dischargers, or urban stormwater and combined
 sewer overflow systems.

 The maximum amount of oxygen gas that can be dissolved in natural
 waters by transfer of oxygen from the atmosphere across the air-
 water interface. The concentration of oxygen saturation is greatly
 influenced by water temperature, salinity or chlorides concentration
 and elevation above mean sea level, and other water characteristics.

 Constituents measured in water quality monitoring programs. Ex-
amples: dissolved oxygen, BOD5, TSS, water temperature.

Measure of concentration of 1 part solute to 1  million parts water (by
weight). See milligrams per liter.
                                                                                         Glossary - 9

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
Parts per thousand (ppt)
Pathogens
Per-capita use
Phosphorus


Photosynthesis
Phytoplankton


Plankton



Point source
Pollutant
Pretreatment
Primary productivity
Measure of concentration of 1 part solute to 1000 parts water (by
weight). See milligrams per liter.

a microorganism capable of producing disease. Pathogens are of
great concern to protect human health relative to drinking water,
swimming beaches and shellfish beds.

The quantity of water used per person per day averaged over a time
interval of 1 day; expressed as gallons per capita per day (gpcd).

A measure of acidity indicated by the logarithm of the reciprocal of
the hydrogen ion concentration (activity) of a solution. pH values less
than 7 are acidic; values greater than 7 are basic; pH of 7 is neutral.
pH of natural waters typically ranges from -6-8.

A nutrient essential for plant growth that can play a key role in
stimulating the growth of aquatic plants in streams, rivers and lakes.

The biochemical synthesis of carbohydrate based organic compounds
from water and carbon dioxide using light energy in the presence of
chlorophyll. Photosynthesis occurs in all plants, including aquatic
organisms such as algae and macrophytes.  Photosynthesis also
occurs in primitive bacteria such as blue-green algae.

A group of generally unicellular microscopic plants characterized by
passive drifting within the  water column. See Algae.

Group of generally microscopic plants and animals passively floating,
drifting or swimming weakly. Plankton include the phytoplankton
(plants) and zooplankton (animals).

Pollutant loads discharged  at a specific location from pipes, outfalls,
and conveyance channels from either municipal wastewater treat-
ment plants or industrial waste treatment facilities. Point sources can
also include pollutant loads contributed by urban stormwater systems
or tributaries to the main receiving water stream or river.

A contaminant in a concentration or amount that adversely alters the
physical, chemical, or biological properties of a natural environment.
The term include pathogens, toxic metals, carcinogens, oxygen
demanding substances, or  other harmful substances.

The treatment of wastewater to remove or reduce contaminants prior
to discharge into another municipal treatment system or a receiving
water.

A measure of the rate at which new organic matter is formed and
accumulated through photosynthesis and chemosynthesis activity of
producer organisms (chiefly, green plants). The rate of primary
production is estimated by measuring the amount of oxygen released
(oxygen method) or the amount of carbon assimilated by the plant
(carbon method)
Glossary -10

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                                                                                           Glossary
Primary treatment plant
Publicly Owned Treatment Works
(POTW)
Public-supply withdrawals
Range


Raw  sewage
Reach (of a river)


Reach File Version 1 (RF1)
Reach File Version 3
Reaction rate coefficient
Reaeration


Removal efficiency




Receiving waters




Residential water use
Wastewater treatment process where solids are removed from raw
sewage primarily by physical settling. The process typically removes
about 25-35% of solids and related organic matter (BOD5).

Municipal wastewater treatment plant owned and operated by a
public governmental entity such as a town or city.

Water withdrawn from surface water or groundwater by public or
private water suppliers for use within a community. Water is used for
domestic, commercial, industrial and public water uses such  as fire
fighting.

Statistical measure expressing the difference between the minimum
and maximum values recorded for a given constituent in time and
space.

Untreated municipal sewage.

A linear or  longitudinal section of a stream or river defined by the
upstream and downstream locations of lower stream order tributaries
flowing into a higher stream.

US EPA hydrologic database designed to define the downstream
hydraulic routing of a connecting network of streams, rivers, lakes
and reservoirs, bays and tidal waters. Version 1 of the Reach File
(Rfl) includes a network of 64,902 Rfl reaches that includes 632,552
miles of waterbodies in the 48 states. Rfl reaches are indexed using
an 11 -digit  code.

US EPA hydrologic database that defines the downstream hydraulic
routing of a more complex connecting network of streams, rivers,
lakes and reservoirs, bays and tidal waters than the Rfl database.
Version 3 of the Reach File  (Rf3) includes a network of 1,821,245
Rf3 reaches that includes about 3.5 million miles of waterbodies in
the 48 states.  Rf3 reaches are indexed using a 17-digit code.

Coefficient describing the rate of transformation of a substance in an
environmental medium characterized by a set of physical, chemical,
and biological conditions such as temperature and dissolved oxygen
level.

The net flux of oxygen transferred occurring from the atmosphere to
a body of water with a free surface.

A measure  of how much of a pollutant is removed from raw sewage
prior to discharge into a receiving water after completion of waste-
water treatment processes. Expressed as percentage calculated as
Removal % = [(influent - effluent) /(influent)] x 100.

Creeks, streams, rivers, lakes, estuaries, groundwater formations, or
other bodies of water into which surface water and/or treated or
untreated wastewater are discharged, either naturally or in man-made
systems.

See domestic water use.
                                                                                       Glossary -11

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
Respiration
River basin
Rotating biological contactors (RBCs)
Salinity
SAV
Secchi depth
Secondary treatment plant
Sediment
Sediment oxygen demand (SOD)
Significance level

Stabilization pond

Standard Industrial Classification
(SIC) codes
Biochemical process by means of which cellular fuels are oxidized
with the aid of oxygen to permit the release of the energy required to
sustain life; during respiration oxygen is consumed and carbon dioxide
is released.

see  watershed

A wastewater treatment process consisting of a series of closely
spaced rotating circular disks of polystyrene or polyvinyl chloride.
Attached biological growth is promoted on the surface of the disks.
The rotation of the disks allows contact with the wastewater and the
atmosphere to  enhance oxygenation.

The total amount of dissolved salts, measured by weight as parts per
thousand (ppt). Salinity concentrations range from -0.5-1 ppt for tidal
fresh waters; ~20-25 ppt for estuarine waters; ~ 30 ppt for coastal
waters to ~35 ppt for the open ocean.

Submersed or submerged aquatic vegetation. SAV describes rooted
aquatic plants that grow in shallow clear water.

A measure of the light penetration into the water column. Light
penetration is influenced by turbidity.

Waste treatment process where oxygen-demanding organic materials
(BOD) are removed by bacterial oxidation of the waste  to carbon
dioxide and water. Bacterial synthesis of wastewater is  enhanced by
injection of oxygen.

Particulate organic and inorganic matter that accumulates in a loose,
unconsolidated form on the bottom of natural waters.

The solids discharged to a receiving water are partly organics, and
upon settling to the bottom, they decompose anaerobically as well as
aerobically, depending on conditions.  The amount of oxygen con-
sumed in the sediment bed during aerobic decomposition of detrital
organic carbon deposited on the bottom of a waterbody; represents
another dissolved oxygen loss/sink for the waterbody.

A statistical measure of the certainty  that can be associated with the
results of a statistical analysis.

Large earthen basins that are used for the treatment of wastewater
by natural processes involving the use of both algae and bacteria.

Four-digit codes established by the Office of Management and
Budget (OMB) to classify commercial and manufacturing establish-
ments by the principal type of activity. Example: 4952 = municipal
wastewater treatment plant.
Glossary  -12

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                                                                                            Glossary
State Revolving Fund (SRF)
Station (monitoring)
Passed under the Amendments to the Clean Water Act (CWA) in
1987, the Clean Water State Revolving Fund (CWSRF) program
replaced the long-running federal Construction Grants program.
Under the CWSRF program, each state and Puerto Rico created
revolving loan funds to provide independent and permanent sources
of low-cost financing for a range of environmental water quality
projects. As payments are made on loans, funds are recycled to fund
additional water protection projects. While traditionally used to build
or improve wastewater treatment plants, loans are used increasingly
for agricultural, rural, and urban runoff control; wet weather flow
control, including storm water and sewer overflows; alternative
treatment technologies; small decentralized systems; brownfields
remediation; and estuary improvements projects.

Funds to establish SRF programs are provided through federal
government grants (83 percent of total capitalization) and state
matching funds (17 percent of total capitalization). To augment the
federal and state capitalization, states may use the assets of the fund
to support the issuance of bonds. At their option some states choose
to transfer some Construction Grant funds into their CWSRF.

From the beginning of capitalization in 1988 through 1999, federal
contributions to the CWSRF program grew to $ 16.1 billion. Additional
state match, state leveraged bonds, loan repayments and fund
earnings increased CWSRF assets  to over $30 billion since 1988.

Specific location in a waterbody chosen to collect water samples for
the measurement of water quality constituents. Stations are identified
by an alphanumeric code identifying the agency source responsible
for the collection of the data and a unique identifier code designating
the location. Station measurements can be recorded from either
discrete grab  samples or continuous automated data acquisition
systems. Station locations are typically sampled by state, federal or
local agencies at periodic intervals (e.g., weekly, monthly, annual
etc.) as part of a routine water quality monitoring program to track
trends. Station locations can also be sampled only for a period of time
needed to collect data for an intensive survey or a special monitoring
program.
Stoichiometric ratio

STORE!
Mass-balance-based ratio for nutrients, organic carbon, dry weight
and algae (e.g., nitrogen-to-carbon ratio).

U.S. Environmental Protection Agency (EPA) national water quality
database for STORage and RETrieval (STORET). Mainframe water
quality database that includes millions of data records of physical,
chemical, and biological data measured in waterbodies throughout the
United States.
                                                                                        Glossary -13

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
Storm runoff
Stream order
Streamflow
Surface waters
Suspended solids or load
Tertiary treatment
Total Kjeldahl Nitrogen (TKN)
Total Maximum Daily Load (TMDL)
Total coliform bacteria
Toxic substances
Transport of pollutants (in water)
Tributary
Rainfall that does not evaporate or infiltrate into the ground because
of impervious land surfaces or a soil infiltration rate lower than
rainfall intensity, but instead flows onto adjacent land or waterbodies
or is routed into a drain or sewer system.

A ranking, developed by Straher, of the relative size of streams and
rivers within a watershed based on the network of tributaries. The
smallest, headwater stream is classified as an Order 1 stream. The
stream formed by the confluence of two or more Order 1 streams is
classified as an Order 2 stream. In the United States, the Mississippi
River is an Order 10 river.

Discharge that occurs in a natural channel. Although the term
"discharge"  can be applied to the flow of a canal, the word
"streamflow" uniquely describes the discharge in a surface stream
course. The  term streamflow is more general than "runoff as
streamflow may be applied to discharge whether or not it is affected
by diversion or regulation.

Water that is present above the substrate or soil surface. Usually
refers to natural waterbodies such as streams, rivers, lakes and
impoundments, and estuaries and coastal ocean.

Organic and inorganic particles (solids/sediment) suspended in and
carried by a fluid (water). The  suspension is governed by the upward
components of turbulence, currents, or colloidal suspension.

Waste treatment processes designed to remove or alter the forms of
nitrogen or phosphorus compounds contained in domestic sewage.

The sumtotal of organic and ammonia nitrogen in a sample, deter-
mined by the Kjeldahl method.

The sum of the individual wasteload allocations and load allocations.
A margin of safety is included with the two types of allocations so
that any additional loading, regardless of source, would not produce a
violation of water quality standards.

A particular group of bacteria that are used as indicators of possible
sewage pollution.

Those chemical substances, such as pesticides, plastics, heavy
metals, detergent, solvent, or any other material that are poisonous,
carcinogenic, or otherwise directly harmful to human health and biota
the environment.

Transport of pollutants in water involves two main process: (1)
advection, resulting from the flow of water, and (2) diffusion, or
transport due to turbulence mixing in the water.

A lower order stream compared to a receiving waterbody. "Tributary
to" indicates the largest stream into which the reported stream or
tributary flows.
Glossary  -14

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                                                                                            Glossary
Trickling filter
Turbidity
Ultimate Biochemical Oxygen
Demand (UBOD or BOD0)
Urban drainage
Waste load allocation (WLA)
Wastewater
Wastewater treatment
Water pollution


Water quality


Water quality criteria (WQC)
Water quality standard (WQS)
Watershed
Zooplankton
A wastewater treatment process consisting of a bed of highly
permeable medium (e.g., gravel or stones) to which microorganisms
are attached and through which wastewater is percolated or trickled
over the biofilm that forms on the media.

Measure of the amount of suspended material in water.

Long term oxygen demand required to completely stabilize organic
carbon and ammonia in wastewater or natural waters; defined as the
sum of ultimate carbonaceous BOD and nitrogenous BOD.

Water derived from surface runoff or shallow groundwater discharge
from urban land use areas.

The portion of a receiving water's total maximum daily load that is
allocated to one of its existing or future point sources of pollution.

Usually refers to effluent from an industrial or municipal sewage
treatment plant. See also domestic wastewater.

Chemical, biological, and mechanical processes applied to an indus-
trial or municipal discharge or to any other sources of contaminated
water in order to remove, reduce, or neutralize contaminants prior to
discharge to a  receiving water.

Any condition of a waterbody that reflects unacceptable water
quality or ecological conditions. Water pollution is usually the result of
discharges of waste material from human activities into a waterbody.

Numerical description of the biological, chemical, and physical
conditions of a water body. It is a measure of a water body to
support beneficial uses.

Water quality criteria include both numeric and narrative criteria.
Numeric criteria are scientifically derived ambient concentrations
developed by EPA or States for various pollutants of concern to
protect human health and aquatic life. Narrative criteria are state-
ments that describe the desired water quality goal.

A water quality standard is a law or regulation that consists of the
beneficial designated use or uses of a waterbody, the numeric and
narrative water quality criteria that are necessary to protect the use
or uses of that  particular waterbody, and an antidegradation state-
ment.

See  drainage  basin.

Very small animals (protozoans, crustaceans, fish embryos, insect
larvae) that live in a waterbody and are moved passively by water
currents and wave action.
                                                                                        Glossary -15

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Progress in Water Quality: An Evaluation of the National Investment in Municipal Wastewater Treatment
                                  U.S. Environmental Protection Agency
                                  Region 5, Library (Pf,. J2J)
Glossary -16

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                   A River Reborn
     "Time has been good to  the Potomac River—at least the
last 25 years have been .  . .  . A generation ago (1960s and
1970), when we had gone to  the Potomac for thrills,  the river
was ugly and almost frightening in its decay. The water was an
opaque red-brown sludge, smelly and foaming with unknown
chemical pollutants. The shore was littered with the rotting
carcasses  of carp and with slime-covered tires,  cans, glass and
other filth.
    But as we sat talking this  time, the water was clear—really
clear—as though we were in the countryside far from a big city.
We could see right to the sandy bottom.  The shoreline was free of
debris, and the air smelled fresh.
    Best of all were the birds. Mallards swooped overhead,
heading toward the water.  Despite  the season, some songbirds
still darted through the trees. And far out in the channel, close to
Virginia, a huge flock of birds circled round and round a cluster
of rocks.  They seemed to be feeding  out there (on what type of
freshwater creature?), and the sun glistened off their wings....
     Who are the stewards of the Potomac? Who is responsible
for the amazing rebirth of a beautiful river? To all, I extend a
hearty thanks..."
                 —Letter to the editor of The Washington Post,
                             January 15, 1995 (Chase, 1995)

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