PB89-195200
600-2-89-026
U.S. Environmental Protection Agency
Great Lakes National Program Office
GLNPO Library
REMOVAL AND FATE OF RCRA AND CERCLA
TOXIC ORGANIC POLLUTANTS IN WASTEWATER
TREATMENT
University of Cincinnati
Cincinnati, OH
Jun 89
U.S. DEPARTMENT OF COMMERCE
National Technical Information Service
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PB89-195200
EPA/600/2-89/026
June 1989
-4 REMOVAL AND FATE OF RCRA AND CERCLA TOXIC ORGANIC
POLLUTANTS IN WASTEWATER TREATMENT
by
Sanjoy K. Bhattacharya and Rao V. R. Angara
Department of Civil and Environmental Engineering
University of Cincinnati
Cincinnati, Ohio 45221
Dolloff F. Bishop, Jr., Richard A. Dobbs
and Barry M. Austern
U.S. Environmental Protection Agency
Cincinnati, Ohio 45268
Contract No. 68-03-4038
Technical Project Monitor
Sidney A. Hannah
Water and Hazardous Waste Treatment Research Division
Risk Reduction Engineering Laboratory
Cincinnati, Ohio 45268
RISK REDUCTION ENGINEERING LABORATORY
OFFICE OF RESEARCH AND DEVELOPMENT
U.S. ENVIRONMENTAL PROTECTION AGENCY
CINCINNATI, OHIO 45268
U.S. Environrr v;on
Region 5, Libr;
77 West Jackson -\ i oth r,
Chicago, IL 60604-3590" Fl°°r
REPRODUCED BY
U.S. DEPARTMENT OF COMMERCE
NATIONAL TECHNICAL INFORMATION SERVICE
SPRINGFIELD, VA. 22161
Great Lakes
GLNPO Library
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TECHNICAL REPORT DATA
(rU-ase rcau Instructions un the rocrse before complaint)
1. REPORT NO.
EPA/600/2-89/026
3. RECIPIENT'S ACCESSIONNO
ACCESSION NO.
1952007AS
TITLE AND SUBTITLE
Removal and Fate of RCRA and CERCLA Toxic
Organic Pollutants in Wastewater Treatment
5. REPORT DATE
June 1989
6. PERFORMING ORGANIZATION CODE
7. AUTHORIS) 1
Sanjoy K. Bhattacharya and Rao V. Angara , Dolleff F.
Bishop, Jr., Richard A. Dobbs, Barry M. Austern^
8. PERFORMING ORGANIZATION REPORT NO.
9. PERFORMING ORGANIZATION NAME AND ADDRESS
University of Cincinnati, Cinti., OH 45221
2U.S. EPA, RREL, Cincinnati, OH 45268
10. PROGRAM ELEMENT NO.
11. CONTRACT/GRANT NO.
68-03-4038
12. SPONSORING AG.ENCY NAVE AND.ADDRESS „. „,
Risk Reduction Engineering Laboratory - Cincinnati, OH
Office of Research and Development
U.S. Environmental Protection Agency
Cincinnati, OH 45268
13. TYPE OF REPORT AND PERIOD COVERED
Complete
14. SPONSORING AGENCY CODE
EPA-600/14
15. SUPPLEMENTARY NOTES
Sidney A. Hannah (513-684-2621 - FTS and commercial)
16. ABSTRACT
Two separate studies were conducted to investigate the removal and
fate of 28 selected RCRA compounds (0.25 mg/L of each compound) and 19
selected CERCLA compounds (0.5 mg/L of each compound) in conventional
activated sludge treatment. In each study, two pilot-scale (35 gpm)
activated sludge systems (SRT: 4 days for RCRA study and 8 days for CERCLA
study) were operated in parallel at the U.S. EPA Test and Evaluation Facility
in Cincinnati, Ohio. One system was spiked continuously with either RCRA
or CERCLA toxics to produce an acclimated biomass; the other was spiked
intermittently with the same toxics and sampled to determine performance
under unacclimated conditions. The selected RCRA or CERCLA compounds did
not cause any adverse effects on COD and SS removals. The concentrations
of organics (RCRA study) in air emissions indicated that the chlorinated
aliphatic solvents were essentially volatilized into the plant air emission
stream, whereas the aromatic volatile benzenes were substantially degraded.
Additional work is planned to attempt to reduce the analytical variability
encountered in these studies.
7.
KEY WORDS AND DOCUMENT ANALYSIS
DESCRIPTORS
b.IDENTIFIERS/OPEN ENDED TERMS c. COSATI Field/Croup
8. DISTRIBUTION STATEMENT
19. SECURITY CLASS (Tins Keportl
21. NO. OF PAGES
20. SECURITY CLASS (Timpage)
22. PRICE
EPA Form 2220-1 (R.v. X-77) PREVIOUS EDITION is OBSOLETE
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DISCLAIMER
This material has been funded wholly or in part by the United States
Environmental Protection Agency under Contract No. 68-03-4038. It has
been subject to the Agency's review and it has been approved for
publication as an EPA document. Mention of trade names or commercial
products does not constitute endorsement or recommendation for use.
n
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FOREWORD
Today's rapidly developing and changing technologies and industrial
products and practices frequently carry with them the increased
generation of materials that, if improperly dealt with, can threaten
both public health and the environment. The U.S. Environmental
Protection Agency is charged by Congress with protecting the Nation's
land, air, and water systems. Under a mandate of national environmental
laws, the agency strives to formulate and implement actions leading to a
compatible balance between human activities and the ability of natural
systems to support and nurture life. These laws direct the EPA to perform
research to define our environmental problems, measure the impacts, and
search for solutions.
The Risk Reduction Engineering Laboratory is responsible for
planning, implementation, and management of research, development, and
demonstration programs to provide an authoritative, defensible
engineering basis in support of the policies, programs, and regulations
of the EPA with respect to drinking water, wastewater, pesticides, toxic
substances, solid and hazardous wastes, and Superfund-related activities.
This publication is one of the products of that research and provides a
vital communication link between the researcher and the user community.
It contains the results from two pilot scale studies conducted to
investigate the removal and fate of 28 RCRA toxic compounds and 19 CERCLA
toxics by conventional activated sludge. Related work is underway to
measure removals of these and similar toxics by other aerobic and
anaerobic processes and results will be presented in subsequent
publications.
E. Timothy Oppelt, Director
Risk Reduction Engineering Laboratory
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ABSTRACT
Two separate studies were conducted to investigate the removal and
fate of 28 selected RCRA compounds (0.25 mg/L of each compound) and 19
selected CERCLA compounds (0.5 mg/L of each compound) in conventional
activated sludge treatment. In each study, two pilot-scale (35 gpm)
activated sludge systems (SRT: 4 days for RCRA study and 8 days for CERCLA
study) were operated in parallel at the U.S. EPA Test and Evaluation Facility
in Cincinnati, Ohio. One system was spiked continuously with either RCRA
or CERCLA toxics to produce an acclimated biomass; the other was spiked
intermittently with the same toxics and sampled to determine performance
under unacclimated conditions. The selected RCRA or CERCLA compounds did
not cause any adverse effects on COD and SS removals. The concentrations
of organics (RCRA study) in air emissions indicated that the chlorinated
aliphatic solvents were essentially volatilized into the plant air emission
stream, whereas the aromatic volatile benzenes were substantially degraded.
Additional work is planned to attempt to reduce the analytical variability
encountered in these studies.
IV
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CONTENTS
Page
Foreword iii
Abstract iv
Figures vi
Tables vii
Introduction 1
Experimental System and Testing Approach 1
Operations Approach 4
Sampling and Analytical Methodology for Organics 7
RCRA Offgas Sampling and Analysis 7
Quality Control 9
RCRA Liquid and Sludge Sample Analysis 9
Volatiles 9
Semi-Volatiles 10
CERCLA Liquid and Sludge Sample Analysis 11
Removal and Fate-In-Treatment 12
Overview of Results 26
Appendices 28
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FIGURES
Number Page
1 Simplified schematic diagram of pilot systems 3
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TABLES
Number Page
1 RCRA and CERCLA Toxic Organic Pollutants 2
2 Nominal Operating Conditions and Design
Characteristics of the Pilot Systems 5
3 Average Concentrations of RCRA Organics in Wastewater
and Sludges from the Acclimated System 14
4 Average Concentrations of RCRA Organics in Air Samples
from the Acclimated System 15
5 Average Percent Removals of RCRA Organics by the
Acclimated System 16
6 Average Percent Removal of RCRA Organics by Treatment
Mechanism for the Acclimated System 17
7 Average Masses in Grams of RCRA Organics in
Wastewaters and Sludges from the Unacclimated Systems. 18
8 Average Masses of RCRA Organics in Air Samples from
the Unacclimated System 19
9 Average Percent Removals of RCRA Organics by
Unacclimated System .... 20
10 Average Percent Removal of RCRA Organics by Treatment
Mechanism for the Unacclimated System 21
11 Average Concentrations of CERCLA Organics in
Wastewater and Sludges from the Acclimated System . . 22
12 Average Percent Removals and Partitioning of CERCLA
Organics for the Acclimated System 23
13 Average Masses in Grams of CERCLA Organics in
Wastewater and Sludges from the Unacclimated System . 24
14 Average Percent Removals and Partitioning of CERCLA
Organics for the Unacclimated System 25
VII
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INTRODUCTION
The Risk Reduction Engineering Laboratory has evaluated the removal and
fate of selected RCRA and CERCLA toxic organic pollutants (Table 1) during
pilot-scale primary-activated sludge treatment of municipal wastewater at the
Agency's Test and Evaluation Facility in Cincinnati, Ohio. This report
summarizes the results of the removal and fate-in-treatment of the selected
volatile and semivolatile organic compounds. The pilot treatment systems,
chosen as a representative POTW design, consisted of primary clarifi-
cation followed by conventional plug-flow activated sludge treatment and
secondary sedimentation. Two parallel 2.2 liters/second (L/S) (35 gpm)
pilot plants were used and are shown in Figure 1. Screened and degritted
raw wastewater from the Cincinnati Mill Creek Wastewater Treatment Plant
was the wastewater feed for the studies. The selected RCRA and CERCLA
toxics were spiked into the raw wastewater in two sequential test periods.
The first test (RCRA) period from October 1987 through March 1988 evaluated
the removal and fate during treatment of selected volatile and semi-
volatile organic toxics. The second test (CERCLA) period from June 1988
through August 1988 evaluated the removal and fate of semivolatile organic
toxics.
EXPERIMENTAL SYSTEM AND TESTING APPROACH
The primary clarifiers in the pilot treatment systems were 2.95 m in
diameter and had a sidewater depth (SWD) of 3.6 m. At 2.2 L/S wastewater
flow, the overflow rate in the center feed clarifier was 28 m^/m^ day.
The activated sludge aeration basins were 5.4 m long, 3 m wide and had a
SWD of 3.6 m. At a flow of 2.2 L/S, the hydraulic residence time in the
basins was 7.5 hrs. Conventional coarse bubble diffusers were used in
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TABLE 1. RCRA AND CERCLA TOXIC ORGANIC POLLUTANTS
RCRA Study Period
CERCLA Study Period
acetone
cyclohexanone
furfural
2-butanone
4-methyl-2-pentanone
tetrahydrofuran
carbon tetrachloride
chlorobenzene
chloroform
1,2-di ch1oroethane
1,2-dichloropropane
methylene chloride
tetrach1oroethy1ene
trichloroethylene
1,1,1-trichloroethane
1,1,2-tr i chloroethane
ethylbenzene
toluene
total xylenes
bis(2-ethylhexyl) phthalate
butyl benzyl phthalate
1,4-di chlorobenzene
2,4-dimethylphenol
2,4-dinitrophenol
naphthalene
nitrobenzene
4-nitrophenol
phenol
1,2-di chlorobenzene
1,3-dichlorobenzene
1,4-di chlorobenzene
1,2,4-trichlorobenzene
nitrobenzene
1,3-dinitrobenzene
2,6-dinitrotoluene
p-cresol
4-chloroaniline
hexachloroethane
hexachlorobutadiene
dimethyl phthalate
diethyl phthalate
dibutyl phthalate
butyl benzyl phthalate
bis(2-ethylhexyl) phthalate
naphthalene
lindane
dieldrin
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Raw Wastewater
DETENTION TANKS
Return Activated
Sludge Pump
o
Spike
WAS
Return Activated
Sludge Pump
Figure 1. SIMPLIFIED SCHEMATIC DIAGRAM OF PILOT SYSTEMS
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the basins. The center feed secondary clarifiers were 3.6 m in diameter
and had a SWD of 3.6 m. At a 2.2 L/S flow, the overflow rate in the
rlarifipr was 1R.4 rn^/nr Hay. Thp nominal operatinQ conditions anH Hesion
characteristics for the two identical systems used in the study are given
in Table 2 in English units. A nominal operational sludge retention time
(SRT) of 4 days was employed in the RCRA study period. In the CERCLA
study period, the nominal SRT was 8 days.
In order to sample the air space above the primary clarifier, a cover
was fabricated with approximately an inch opening around the unit. The cover
was vented through a duct to the roof. An air sweep equivalent to a 5 km
per hour wind was maintained over the surface of the clarifier by exhausting
air at 14,000 liters/min. The aeration basin was fitted with an air
tight cover and the offgas was also vented to the roof. Air flow in the
aeration basins averaged 5,600 liters/min and maintained a dissolved
oxygen level of at least 2.0 mg/L.
Operations Approach and Conventional Pollutant Removals
The evaluation of the removal and fate during treatment of the spiked
RCRA and CERCLA toxic organics in the large pilot-scale primary-
activated sludge treatment systems was performed at two steady-flow
operational conditions; operation with a continuous feed of spike
toxic cocktail in one pilot train under steady operating conditions
and operation of the parallel pilot train under the same steady conditions
except with intermittent spiking of the toxic cocktail. The operation
with continuous feeding of the spiking cocktail produced "acclimated"
biomass. In the operation with intermittent spiking of the cocktail,
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TABLE 2. NOMINAL OPERATING CONDITIONS AND DESIGN
CHARACTERISTICS OF THE PILOT SYSTEMS
I. Design Flow, Qd = 35 gpm
= 50,400 gpd
II. Primary Clarifiers - Diameter = 9'-8"
Weir Diameter = 9'-l"
SWD = 12'-0" ?
Surface Area = 73.4 ft
Surface Overflow Rate = 687 gpd/ft
III. Aeration Basins - L:W:D = 17'-7":1Q'-0":12'-0"
Surface Area = 175.8 ft.
Volume = 2,110 ftj
= 15,780 gal.
Hydraulic Residence Time (Qd) = 7.5 hrs.
IV. Secondary Clarifiers - Diameter = 11'-11"
SWD = 12'-0"
Surface Area = 111.5 ft*
Surface Overflow Rate = 452 gpd/ft
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spike was added at steady nominal concentrations of toxic organics equal
to that in the continuously spiked train for a 24 hour period after every
3 SRT periods of unspiked operation. During the spiking episodes, the
intermittently spiked train provided removal and fate-in-treatment data
for the toxic organics intermittent loading ("unacclimated") operation.
The intermittent spiked treatment train also provided conventional pollutant
performance control data during unspiked operation for comparison to the
conventional pollutant performance of the continuously spiked train.
The pilot treatment trains were operated at a 4-day (4 ^.3) SRT with
a nominal spike of 0.25 mg/L of each individual toxic organic during the RCRA
study period. The pilot treatment trains were operated at an 8-day (8 +1 day)
SRT with a nominal spike of 0.5 mg/L of each individual toxic organic during
the CERCLA spiking period. The overall performance of the parallel treatment
systems were characterized for removal of chemical oxygen demand (COD),
suspended solids (SS), ammonia (NHs-N), and for the removal and fate-in-
treatment of the individual toxic organics using automated analytical
procedures for the conventional pollutants and Agency GC/MS procedures
for the toxic organic compounds.
Average removals of conventional pollutants in the pilot systems
during both study periods ranged 81 to 88 percent for the COD and 94 to
97 percent for SS. In the RCRA study period at the nominal 4-day SRT and
with a nominal toxic spike of 0.25 mg/L of each individual organic, nitri-
fication occurred in the activated sludge processes with average N^-
N reductions ranging 76 to 81 percent for the two spiked pilot treatment
trains. In the CERCLA study period at a nominal 8-day SRT and with a
nominal spike of 0.5 mg/L of each individual organic, complete nitrification
usually occurred in the intermittently spiked activated
6
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sludge process but frequent interference with nitrification was observed
in the continuously spiked system. The NH--N reductions during the
CERCLA study averaged 98 percent for the intermittently spiked system and
88 percent for the continuously spiked system. Data tables showing
removals of the conventional pollutants are included in Appendix 3. As
an overview of the operational performance, the pilot treatment represents
effective performance for control of conventional pollutants. The presence
of the spiked toxic organics in the wastewater produced no significant
adverse effects on the treatment of conventional pollutants except on
ammonia removal during continuous spiking with the CERCLA compounds.
SAMPLING AND ANALYTICAL METHODOLOGY
RCRA Offgas Sampling and Analysis
The sampling system used to collect each offgas sample consisted of
a 33 liter stainless steel polished canister, a pneumatic flow controller
and nickel sample tubing. Previous studies have shown that the canisters
are well suited for collecting air samples for VOC analysis and that VOC
levels do not deteriorate in the canisters during reasonable holding
times.
Canisters and flow controllers were cleaned and prepared for
sampling by repeated high-pressure purging with ultrapure zero air. The
canisters were then pressurized, and blank checked by gas
chromatography/mass spectrometry (GC/MS). After blank checking, clean
canisters were evacuated to 28 inches of Hg for sample collection. The
nickel tubing was cleaned by heating the tubing to 150°C and flushing
with purified nitrogen for 2 hours.
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Samples were collected by attaching the nickel tubing to the
canister and extending the free end into the offgas duct. The canister
vacuum was recorded, the valve opened, and the canister allowed to fill
at a constant rate during the sampling event. The canister valve was
then closed, sample tubing disconnected, and a final pressure reading
recorded at the conclusion of sampling. When the collected samples
arrived at the Laboratory they were allowed to equilibrate, then a
pressure reading was taken using a mercury manometer before any other
manipulations of the sample. The final pressure reading was recorded
along with the date, temperature, and barometric pressure. From these
data, the sample volume was calculated.
Canister samples were analyzed on a Finnigan Model OWA 1050 GC/MS
system with a quadrupole mass spectrometer. This system is equipped
with a Tekmar Model 5000 cryogenic concentration and sample introduction
system. The GC/MS interface consists of a quartz jet separator. The MS
is scanned from 40 to 260 m/z (mass charge ratio) every 2 seconds.
Samples were analyzed by withdrawing 0.1 liter or 0.5 liter from a
canister using the system mass flow controller. The volatile organics
were concentrated on a cryogenic trap and then desorbed to the GC column
for component separation and mass spectral analysis. The GC/MS system
was calibrated in units of ng of RCRA organic on column and results were
recalculated to yield ug/liter in air sample as collected. From these
data, masses of each RCRA organic stripped during the sampling event were
calculated. The method used was the contractor's standard operating
procedure for canister analysis, SOP No. 09-002-00.
8
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Quality control
The analytical standard was prepared from the neat compounds and
internal audits were analyzed for each test series and the results
included with the data. The audit gases were obtained from Scott
Speciality Gases as Certified Mixtures in Nitrogen (±5 percent). The
audit compounds were 1,1,1-trichloroethane, carbon tetrachloride,
trichloroethene, toluene, and tetrachloroethene.
Since duplicate field samples were analyzed with good precision and
calibration precision was excellent, duplicate analyses on the same
canister were not run.
Blanks were analyzed and met the method QC criteria before samples
were analyzed on each analysis day. In addition, if a highly
concentrated sample was analyzed, blanks were run until the system met
the QC blank criteria before proceeding with sample analysis. In all
cases, it was found that carry-over was not extensive and this is documented
in the Canister QC files. Calibration criteria and other QC procedures
follow the SOP.
RCRA Liquid and Sludge Sample Analysis
Sludge and liquid samples were analyzed by gas chromatography/mass
spectrometry (GC/MS) according to the methods outlined in the USEPA
Methods for Evaluating Solid Waste, SW846, 3rd edition, November 1986.
Volatiles
Samples to be analyzed for volatile organic compounds were collected
by filling one 40 ml volatile organic analysis (VOA) bottle at each sample
interval from each sampling point during the sampling event. The first
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step in analyzing these samples involved compositing the individual VOA
samples from each sample point into one composite sample for each sample
point. Samples to be composited were stored chilled at 4°C. Precleaned
glassware were also chilled to this temperature. During the compositing
step, the samples were poured down the side of the mixing flask to avoid
agitation. After all samples were added, the composite was stirred with
a chilled glass stirring rod. Agitation was avoided wherever possible.
Two 40 ml composites were then collected and stored at 4 C in headspace-
free vials until analysis.
The volatile fractions were analyzed on Finnigan DWA and Extrel
ELQ400 GC/MS systems using Method 8240 (Purge and Trap). In this method,
5 ml of sample or an aliquot of sample diluted to 5 ml is purged with
an inert gas (helium) in a specially designed purge vessel. Volatile
organic compounds are partitioned into the gaseous phase and swept by the
purge gas onto a multi-phase sorbent trap. After the purge cycle is
complete, the flow of carrier gas is reversed, and the trap is heated
rapidly. Volatile organic compounds are thermally desorbed from the trap
into the gas chromatograph where the individual components are separated.
Identification and quantitation were done by mass spectrometry.
Semi-Volatiles
Semi-volatile (extractable) compounds were extracted from the
samples according to Method 3520 (continuous liquid-liquid extraction).
This method outlines procedures for the isolation of acidic and
base/neutral organic compounds from aqueous samples. One liter of
10
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sample, or an aliquot of sample diluted to one liter is pH adjusted to
greater than pH 11. It is then mixed with an organic solvent (methylene
chloride in this project). Base/neutral organic compounds have greater
solubility in the organic phase and are concentrated there. After the
base/neutral extract has been removed, the pH of the sample is re-
adjusted to less than pH 2. A second extraction is then performed to
remove acidic compounds. The organic extracts are then concentrated to
one ml. Portions of the acidic and base/neutral extracts from a sample
were mixed and an aliquot was injected into the GC/MS for analysis.
Samples were analyzed on Finnigan 5100 and Extrel ELQ 400 GC/MS
systems in accordance with Method 8270. This method specified GC/MS analysis
of organic extracts using a fused silica capillary column, with mass
spectrometry for detection and quantitation.
CERCLA Liquid and Sludge Sample Analysis
Liquid and sludge samples in the CERCLA study were collected for
either 24 or 48 hours and composited for analysis. The CERCLA compounds
were all classified as semivolatiles and were analyzed following EPA
Extraction Method 1625.
All samples were spiked with a mixture of deuterated or -^C-
labeled priority pollutant organics to represent the priority pollutants
spiked into the wastewater feed. Analytical results for the nonlabeled
priority pollutant organics were corrected automatically for the
recoveries of the labeled priority pollutant organics. The isotopically
labeled compounds were used as internal standards for the corresponding
priority pollutants. Furthermore, percent recovery of the labeled
11
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compounds, and by inference, of their corresponding natural-isotope analogs,
was measured as a function of an internal standard added just before gas
chromatography/mass spectrometry (GC/MS) analysis. Anthracene-d^g was
used for Method 1625. A capillary column was used in the GC/MS procedure.
Both instruments were attached to a computer data system. To ensure
precision, duplicate analyses of individual collected samples and
analyses of samples collected and processed in duplicate were performed.
REMOVAL AND FATE-IN TREATMENT
Five sample events were performed during the RCRA study period to
evaluate the removal and fate-in treatment of the spiked toxic organics.
In this study period, the removals and fate of the toxic organics were
characterized by GC/MS analyses of the influent to and all discharges
from the two treatment systems, i.e., in the raw wastewater, the primary
influent, the primary effluent, the secondary effluent, the primary sludge,
the waste activated sludge, and the air emissions from both primary clari-
fication and the activated sludge process. In the first two sample events
of the RCRA study period, the air samples proved to be too small for the
GC/MS sensitivity. With larger samples, precise and quantitatively accurate
data were generated on the volatile organic compounds in the primary and
activated sludge air emissions from the pilot systems for the last three
sample events. In the CERCLA study, eleven sample events on the continuously
spiked (acclimated) pilot train and 4 sample events on the intermittently
spiked pilot train have been included in the summary tables of average
toxic organic removal and toxic organic fate-in-treatment performance of
the pilot systems.
12
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The removal and fate-in-treatment performance for the RCRA study
period on both volatile and semivolatile organics are summarized in Tables
3 through 10 for "acclimated" and "unacclimated" operation. The performance
data for the continuously spiked (acclimated) treatment system are based on
24-hour composite samples with average concentrations reported for the
various plant discharges (Tables 3 and 4) including air emissions and removals
reported (Tables 5 and 6) across the treatment processes and by treatment
mechanism. In the intermittently spiked ("unacclimated") pilot trains, the
episodal spiking lasted 24 hours but the sampling composite was extended to
48 hours to permit measurement of the gradual washout of the organic toxics.
Thus, the performance data for the unacclimated operation are reported for
the toxic organics in the discharges (Tables 7 and 8) as average masses in
grams rather than as concentration units. The masses in grams are then
used to calculate the removals (Tables 9 and 10) across the treatment
processes and in the removal mechanisms. The raw data for the individual
sample events are included in the Appendix 1.
The removal and fate-in-treatment performance for the CERCLA study
period on semivolatile toxic organics is summarized in Tables 11 through
14. Since only semivolatile organics were employed, air emission
sampling was not performed. As in the RCRA study period described above,
the performance data for continuously spiked operation ("acclimated")
were based on 24-hour composite samples with average toxic organic
concentrations reported in the various plant discharges. For intermittently
spiked ("unacclimated") operation, the performance data are reported as
masses of toxic organics because of the 24-hour spiking episode and the 48-
hour composite sampling for organic washout. While air stripping of
organics was expected to be an insignificant removal mechanism and air
13
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TABLE 3. AVERAGE CONCENTRATIONS OF RCRA ORGANICS IN WASTEWATER
AND SLUDGES FROM THE ACCLIMATED SYSTEM
NAME
Acetone
Cyclohexanone
Furfur»l
2-lutanone
4-Methyl-2-Pentanone
Tetrahydrofuran
Carbon Tctrachlorfde
Chlorobentene
Chtorofora
1.2-Dlchloroethane
1,2-Dichtoropropane
Nethylcne Chloride
Tetrachloroethylent
Trlchloroethylene
1,1,1-Trlchloroethane
1.1.2-Trlchloroethane
Ethylbeniene
Toluene
Total Xytenei
• 1 •- <2- ethylhexy I ) -phthat ate
•utytbeniylphtlialate
1,4-dfchlorobeniene
Z,4-DlMthylpheno|
2,4-Dlnltrophanol
Naphthalene
Nltrobeniene
4-Nltrophenol
Phenol
|| UASTEUA1ER FEED || PRIMARY EFHUENT | (SECONDARY Ef FLUENT || PRIMARY SLUDGE || SECONDARY SLUDGE ||
II II II II II II
| (AVERAGE STANDARD | (AVERAGE STANDARD | (AVERAGE STANDARD | (AVERAGE STANDARD | (AVERAGE STANDARD ||
|| DEVIATION || DEVIATION || DEVIATION || DEVIATION || DEVIATION ||
|| ug/L || ug/l || ug/L || ug/L || ug/L ||
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
H*7
134
238
199
260
255
255
JM
228
434
211
201
260
216
196
2M
175
120
62
102
144
129
295
1313 ||
II
II
88 ||
187 ||
' II
111 ||
33 II
83 ||
33 II
50 ||
H6 ||
*« II
57 II
61 ||
49 ||
"II
28 ||
35 ||
33 ||
26 ||
33 II
II
II
61 ||
" II
II
80 ||
1082
68
162
225
247
238
242
323
212
398
194
186
233
202
192
295
163
95
33
95
1)3
122
290
839 ||
II
II
91 ||
26 ||
25 II
110 ||
60 ||
98 ||
18 ||
n ||
167 ||
66 ||
" ||
88 ||
66 ||
" II
100 ||
59 ||
2* II
' II
37 ||
II
II
52 II
38 ||
II
106 ||
29
5
3
128
3
3
39
140
54
107
10
5
5
97
3
3
2
4
5
5
5
5
5
23 II
II
II
o II
3 II
114 ||
1 II
1 II
1* II
<2 ||
20 ||
62 ||
3 II
2 II
5 II
'* II
0 II
1 II
0 II
1 II
0 II
0 II
II
II
0 II
0 II
II
1 II
1241
63
105
146
163
259
289
378
210
163
254
273
191
246
329
190
730
447
133
228
65
287
241 ||
II
II
62 ||
128 ||
111 ||
189 ||
217 ||
254 ||
88 ||
180 ||
II
153 ||
209 ||
259 ||
165 ||
201 ||
276 ||
179 ||
321 ||
119 ||
113 ||
II
II
87 ||
30 ||
II
15 ||
127
5
6
171
5
3
44
129
43
48
6
3
97
3
10
3
142
5
6
5
7
5
127 ||
II
II
0 II
1 II
266 ||
2 II
1 II
46 ||
175 1)
68 ||
II
73 II
* II
1 II
130 ||
2 II
« II
2 II
128 ||
0 II
* II
II
II
0 II
* II
II
o II
-------
TABLE 4. AVERAGE CONCENTRATIONS OF RCRA ORGANICS IN AIR
SAMPLES FROM THE ACCLIMATED SYSTEM
NAME
Acetone
Cyclohexanone
Furfural
2-but*none
4-*>ethyl-2*pentanone
Tetrahydrofuran
Carbon Tetrachloride
Chloretenzene
Chtorofona
1,2-dieMoroethane
1 ,2-diehloropropane
Methylene Chloride
Tet rich I oroethy I ene
Trichloroethylene
1,1,1-trichloroethine
1,1,2-trfehloroethane
Ethylbenzene
Toluene
Total Xylenes
bis-(2-ethylhexyl)-phthalate| |
Butylbenzylphthalate
1 ,4-df cholorobenzene
2,4-diMttiylphenol
2,4-dinitroph«nol
Naphthalene
Nitrobenzene
4-nitrophenol
Phenol
|| PRIMARY
II
| | AVERAGE
II
II
,i i
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
•1 1
1 1
it
ii
n
ii
n
n
ii
ug/L
0.13
0.03
0.03
0.02
0.26
0.24
0.20
0.18
0.19
0.34
0.20
0.20
0.26
0.10
0.19
0.29
0.1B
•••*«•••»*
AIR
STANDARD
DEVI AT I OK
0.06
0.01
0.00
0.02
O.OS
0.13
0.01
0.04
0.03
0.07
0.01
0.01
O.OS
0.01
0.03
0.03
0.04
immmmmmmm mmm •••»••*•• mmmm
|| AERATION AIR ||
II II
| | AVERAGE STANDARD | |
II
II
.. I 1 _-
1 1
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
DEVIATION] |
ug/L
0.20
0.01
0.02
0.34
8.00
2.37
6.10
3.72
5.50
7.19
7.68
5.84
7.35
3.22
0.94
1.92
1.73
II
0.20 ||
II
II
0.00 ||
0.02 ||
0.05 ||
0.62 ||
1.33 l|
0.82 ||
0.54 ||
0.44 ||
2.12 ||
1.42 ||
0.66 ||
0.73 ||
0.52 ||
0.10 I)
0.60 ||
0.55 ||
II
II
II
II
II
II
II
II
15
-------
TABLE 5. AVERAGE PERCENT REMOVALS OF RCRA ORGANICS
BY THE ACCLIMATED SYSTEM
|| PR HURT TREATMENT
TOTAL TREATMENT ||
NAME
| | REMOVAL STANDARD 11 REMOVAL STANDARD 11
|| DEVIAT ION|| DEVIATION)|
II «> II «' II
Acttone
Cyclohexanone
Furfural
2-lutanon*
4-M«thyl-2-Pentanor»
Tetrahydrofuran
Carbon T*trachlor
-------
'TABLE 6. AVERAGE PERCENT REMOVAL OF RCRA ORGANICS BY
TREATMENT MECHANISM FOR THE ACCLIMATED SYSTEM
NAME
Acetone
Cyclohexanone
Furfural
2-Butanone
4-Methyl-2-Pentanone
T et rahydrof uran
Carbon Tetrachloride
Chlorobenzene
Chloroform
1,2-Dichloroethane
1 , 2 • D i ch I oropropane
Methylene Chloride
Tetrachloroethytene
Trichloroethylene
1,1,1-Triehloroethane
1,1,2-Trichloroethane
Ethyl benzene
Toluene
Total Xylenes
|| REMOVED IN SLUDGE || STRIPPI
II II
|| REMOVAL STANDARD || REMOVAL
|| (X) DEVIATION || (X)
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
Bis(2 ethylhexyUphthalatej |
Butylbenzylphthalate
1 , A -Oi Chlorobenzene
2,4-Dtmethylphenol
2,4-Dinitrophenol
Naphthalene
Nitrobenzene
4-Nitrophenol
Phenol
II
II
II
II
II
II
II
II
2
1
1
3
1
1
2
3
2
1
1
1
2
1
1
1
11
11
2
2
1
1
1 II
II
II
o II
2 II
* II
1 II
1 II
1 II
2 II
1 II
II
2 II
1 II
1 II
2 II
1 II
1 II
1 II
8 II
6 II
1 II
II
II
1 II
1 II
II
0 II
3
1
2
6
139
38
104
67
97
124
129
103
122
56
22
25
32
G || BICOEGRADATION ||
II II
STANDARD || REMOVAL STANDARD ||
DEVIATION || (X) DEVIAT!ON| |
1 II
1 II
1 II
11 II
9 II
12 ||
11 II
9 II
40 ||
22 ||
H II
15 II
9 II
3 II
» II
10 ||
II
II
II
II
II
92
94
95
28
-42
60
-21
-17
•25
•35
-6
•25
•6
76
72
66
85
81
93
94
93
97
5 II
II
II
1 II
e II
52 ||
12 ||
9 II
32 ||
12 ||
II
23 ||
12 ||
17 II
24 ||
3 II
8 II
9 II
8 II
9 II
3 II
II
II
2 II
° II
17
-------
TABLE 7. AVERAGE MASSES IN GRAMS OF RCRA ORGANICS IN WASTEWATERS
AND SLUDGES FROM THE UNACCLIMATED SYSTEM
CO
NAME
Acetone
Cyclohexanone
Furfural
2-lutanone
4-Nethyl-2-Pentanone
Tetrehydrofuren
Carbon Tetrechlorlde
Chlorobensene
CMoroforai
1,2-Olchloroethene
1 , 2 -0 1 ch I oropropene
Methyl ene Chloride
TetrccMoroethyter*
Trlchloroethylene
1,1.1-Trlchloroethane
1 , 1 ,2-Trlchloroethene
Ethylbeniene
Toluene
Total Xy tenet
|| UASTEUATER FEED || PRIMARY EFFLUENT || SECONDARY EFFLUENT || PRIMARY SLUDGE || SECONDARY SLUDGE ||
It It II II II II
|| AVERAGE STANDARD || AVERAGE STANDARD | (AVERAGE STANDARD || AVERAGE STANDARD | (AVERAGE STANDARD ||
|| DEVIATION || DEVIATION || DEVIATION || DEVIATION) | DEVIATION) |
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
tU-(2-ethy1hexyl)-phthalate||
Butylbeniylphthalate
1,4-Dlchlorofaeniene
2.4-Dl*ethylphenol
2,4-Olnltrophenol
Naphthalene
Nltrofaeniene
4-Nltrophenol
Phenol
II
II
II
II
II
II
II
II
167.3
15.7 •
36.6
24.5
34.6
40.5
44.6
40.6
32.3
32.9
78.8
31.9
31.2
41.2
36.1
30.4
50.0
35.0
18.9
8.4
24.7
20.8
21.7
26.8 *
52.1
58.5 ||
II
II
4.5 ||
20.6 ||
1.6 ||
2.8 ||
7.8 ||
5.6 ||
1.1 ||
0.6 ||
25.2 ||
9.0 ||
1.9 ||
5.5 ||
3.6 ||
2.8 ||
12.3 ||
6.6 ||
6.2 ||
5.3 ||
9.2 ||
II
II
7.4 ||
9.0 ||
II
31.2 ||
188.6
13.4 •
36.8
20.6
36.8
27.4
38.7
28.8
25.8
24.8
77.0
26.1
25.0
30.6
26.8
21.1
46.3
25.3
9.1
3.0
22.1
21.2
20.3
30.4 •
50.3
51.4 ||
II
It
1.3 ||
10.4 ||
5.4 ||
11.4 ||
21.4 1)
9.1 ||
11.0 ||
10.1 ||
33.4 ||
11. ||
7- II
14. ||
»- II
»• II
23.1 ||
7.2 ||
0.8 ||
1.0 ||
8.3 ||
II
II
8.4 ||
13.2 ||
II
38.0 ||
7.6
1.9 •
1.9 •
2.1
36.5
0.9
3.1
5.7
12.3
9.0
23.3
3.1
2.5
1.7
19.0
2.0
1.1
2.1
1.9
1.9
5.3
1.9
6.5
9.5 •
1.9
6.6 ||
II
II
II
0.3 ||
1.6 ||
0.4 ||
1.7 ||
2.3 ||
2.6 ||
2.8 ||
2.0 ||
1.4 ||
1.5 ||
0.5 ||
5.3 ||
0.6 ||
0.4 ||
1.6 ||
0.0 ||
0.0 ||
1.6 ||
II
II
0.0 ||
4.8 ||
II
0.0 ||
4.3
0.1 •
0.4
0.6
0.7
0.3
0.5
0.6
0.4
O.S
0.4
0.4
0.5
0.5
0.3
0.8
0.3
0.7
0.2
0.3
0.3
0.1
0.1 •
O.S
3.6 ||
II
II
0.5 ||
0.3 ||
0.9 ||
0.2 ||
0.4 ||
0.5 ||
0.3 ||
0.4 ||
II
0.3 1)
0.4 ||
0.4 ||
0.4 ||
0.3 ||
0.6 ||
0.3 ||
0.6 ||
0.4 ||
0.0 ||
II
II
0.2 ||
0.1 ||
II
0.8 ||
3.5
0.0 •
0.0
0.0
0.0
0.0
0.0
0.1
0.2
0.1
0.1
0.0
0.0
0.2
0.3
0.3
0.3
0.3
0.0
0.2
0.0
0.0
0.2 *
0.0
~~T — - 1 1
5.5 ||
II
II
0.0 ||
0.0 )(
0.0 ||
0.0 (1
o.o n
0.1 ||
0.1 I)
0.1 ||
II
0.0 ||
0.0 ||
0.0 ||
0.2 I)
0.5 ||
0.4 ||
0.5 ||
0.3 ||
0.0 ||
0.0 ||
II
II
0.0 ||
0.0 ||
II
0.0 ||
* Only one data point available.
-------
TABLE 8. AVERAGE MASSES OF RCRA ORGANICS IN AIR SAMPLES
FROM THE UNACCLIMATED SYSTEM
|| PRIMARY AIR || SECONDARY AIR ||
NAME || || ||
|| AVERAGE STANDARD | | AVERAGE STANDARD ||
|| DEVIATION || DEVIATION ||
| |mass (gni) ||IMSS (gm) ||
Acetone [ |
Cyclohexanone ||
Furfural 1 1
2-butanone | |
4-methyl-2-pentanone ||
Tetrahydrofuran | |
Carbon Tetrachloride | |
Chtorobenzene ||
Chloroform | |
1,2-dichloroethane ||
1,2-dichtoropropane ||
Methylene Chloride | |
Tetrachloroethylene | |
Trichloroethylene ||
1,1,1-trichloroethene ||
1,1,2-trichloroethane ||
Ethylbenzene | |
Toluene ||
Total Xylenes ||
bis-(2-ethylhexyl)-phthalate| |
Butylbenzylphthalate | |
1,4-dicholorobenzene ||
2,4-dimethylphenol ||
2,4-dinitrophenol ||
Naphthalene | |
Nitrobenzene ||
4-nitrophenol ||
Phenol 1 1
5.6
0.2 *
0.9
1.0
0.4
8.1
10.3
7.7
3.8
4.1
12.3
8.2
7.9
8.6
3.7
4.2
12.6
4.1
4.5 ||
II
II
1.0 ||
0.3 ||
0.6 ||
0.2 ||
5.4 ||
0.9 ||
0.5 ||
0.0 ||
4.1 ||
0.0 ||
0.5 ||
0.7 ||
0.4 ||
0.2 ||
3.7 ||
0.0 ||
II
II
II
II
II
II
II
II
II
2.8
0.1 •
0.1
0.0
2.7
56.9
34.4
43.0
23.0
35.7
50.7
63.1
47.1
64.6
22.1
31.7
31.6
22.8
3.5 ||
II
II
II
0.1 ||
1.0 ||
21.9 ||
6.9 ||
12.9 ||
5.6 ||
13.4 ||
23.5 ||
22.1 ||
15.5 ||
26.9 ||
4.5 ||
12.6 ||
12.7 ||
10.4 ||
II
II
II
II
II
II
II
II
II
• Only data point available.
19
-------
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II »-l
II rsi
II s-i
II s-i
II s-6
II n
II z-s
II z-6
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II 8V
II 1-6
II o-»
II S'»
II o-i
II Q-O
II rzi
II ro
II
II
II o-z
O'So II S'6l
0'S9 ||
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0-9- II
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-------
TABLE 10. -AVERAGE PERCENT REMOVAL OF RCRA ORGANLCS BY TREATMENT
MECHANISM FOR THE UNACCLIMATED SYSTEM
NAME
Acetone
Cyclohexanone
Furfural
2-Butanone
4-Methyl -2-Pentanone
Tetrahydrofuran
Carbon Tetrachloride
Ch 1 orobenzene
Chloroform
1 ,2-Dichloroethane
1,2-Dichloropropane
Methylene Chloride
Tetrachloroethylene
Trichloroethylene
1,1, 1 -Trichloroethane
REMOVED IN SLUDGE 1 1 STRIPPING | | BIOOEGRADATION [ |
II II II
REMOVAL STANDARD || REMOVAL STANDARD | | REMOVAL STANDARD ||
(X) DEVIATION || (X) DEVIATION || (X) DEVIATION) |
*
1 •
1
2
1
1
2
2
1
2
1
1
1,1,2-Trichloroethane || 2
Ethylbenzene || 2
Toluene || 2
Total Xylenes || 2
Bis(2 ethylhexyl)phthalate|| 5
Butylbenzytphthalate 1 1 3
1, 4 -Dich I orobenzene ||
2.4-Dimethylphenol ||
2,4-Dinitrophenol ||
Naphthalene || 1
Nitrobenzene || 1
4-Nitrophenol || 1 •
Phenol 1 1 1
3 II
II
II
1 II
II
3 II
1 II
1 II
1 II
1 II
1 II
II
2 II
1 II
1 II
2 II
2 II
3 II
2 II
* II
5 II
II
II
II
1 II
1 II
II
1 II
3
0 •
1
2
5
135
75
100
55
84
104
138
115
136
54
66
40
45
3 II
II
II
1 II
1 II
1 II
46 ||
14 ||
28 ||
13 ||
28 ||
40 ||
M ||
33 ||
48 ||
10 ||
21 II
11 II
13 II
II
II
II
II
II
II
II
II
II
88
87 •
93
81
-13
-38
17
-16
4
-12
-51
-25
-41
-8
24
56
48
84
67
76
89
73
64 *
96
3 II
II
II
1 II
16 ||
3 II
46 ||
13 II
25 ||
7 II
27 ||
II
40 ||
33 ||
48 ||
16 ||
21 II
12 II
13 II
2 II
19 ||
2 II
II
II
3 II
13 II
II
2 II
tmnmrnmrnm
Only one data point available.
21
-------
TABLE 11. AVERAGE CONCENTRATIONS OF CERCLA ORGAN1CS IN WASTEWATER
AND SLUDGES FROM THE ACCLIMATED SYSTEM
|| UASTEUATER FEED
II
II
Ccnpounds .| (AVERAGE STANDARD
|| DEVIATION
|| UG/L
M
II
IDICHLOROBENZENE, PROBABLY 1,2 || 368.2 49.2
IDICHLOROBENZENE, PROBABLY 1,3 || 375.4 41.5
IOICHLOROBENZEHE, PROBABLY 1,4 || 390. e 31.6
(1.2.4-TRICHLOROBENZENE || 655.0 206.6
(NITROBENZENE || 447.3 78.8
| 1,3-DINITROBENZENE || 263.7 41.4
|2,6-DINITROTOLUENE || 405.6 50. 5
IP-CRESOL || 547.3 78.7
(4-CHLOROANILINE || 393.3 180.4
IHEXACHLOROETHANE || 345.9 41.9
IHEXACHLOROBUTADIENE || 398.0 33.4
(DIMETHYL PNTHALATE || 576.3 345.9
IDIETHVL PHTHALATE || 497.4 39.2
IDIBUTYL PHTHALATE || 427.9 23.4
(BUTYL BENZYL PHTHALATE || 398.4 22.7
|BIS(2-ETNYLHEXYL)PHTHALATE || 1072.0 361.5
(NAPHTHALENE || 431.4 73.4
ILINOANE || 424.7 63.2
(DIELDRIN || 605.6 3U.B
1 II
PRIMARY EFFLUENT
AVERAGE STANDARD
DEVIATION
UG/L
307.8 19.2
318.6 45.1
344.0 30.4
458.9 91.5
415.0 84.8
59.4 33.1
310.9 91.5
578.1 123.1
269.2 87.9
222.8 40.6
238.6 55.3
560.3 357.7
479.7 57.7
271.6 46.6
223.8 43.6
556.1 294.5
383.7 40.4
349.3 52.2
264.5 120.2
SECONDARY EFFLUENT
AVERAGE STANDARD
DEVIATION
UG/L
22.7 18.8
41.4 18.7
18.8 22.3
89.1 34.4
31.9 12.5
7.8 7.1
124.5 53.0
173.5 125.5
34.2 55.5
9.9 8.3
14.8 17.3
12.9 16.0
11.9 8.4
16.7 15.4
12.4 15.6
386.4 185.5
8.9 5.0
177.9 184.1
98.7 59.5
PRIKARY SLUDGE
AVERAGE STANDARD
DEVIATION
UG/L
11716 5282
10485 6194
11278 5264
39392 17807
377 808
716 561
78 163
1534 623
854 639
98 133
41586 20151
484 164
1040 397
25709 9874
29667 10940
79811 49454
10227 6567
15719 5866
16549 18119
SECONDARY SLUDGE
AVERAGE STANDARD
DEVIATION
UG/L '
233 174
373 223
120 134
2709 1736
152 152
1101 411
1460 2570
85 64
93 57
269 304
1962 1385
68 92
105 HO
566 447
596 501
35915 36469
108 112
1919 1620
13538 7180
* Only one data point available
-------
TABLE 12. AVERAGE PERCENT REMOVALS AND PARTITIONING OF CERCLA
ORGANICS FOR THE ACCLIMATED SYSTEM
ro
OJ
COMPOUNDS
PRIMARY TREATMENT) TOTAL TREATMENT | REMOVED IN SLUDGE) BIODEGRADATION |
REMOVAL STANDARD
1
IDICHLOROBENZENE, PROBABLY 1,2 |
X DEVIATION
I
| 15.1 11.7
(DICHLOROBENZENE, PROBABLY 1,3 || is.o 9.9
IDICHLOROBENZENE, PROBABLY 1,4 |
[1,2,4-TRICHLOROBENZENE |
INITROBENZENE |
1,3-DINITROBENZENE |
| 11.3 11.6
| 27.2 15.0
| 6.9 12.8
| 79.0 9.8
|2,6-DINITROTOLUENE || 23.3 18.5
P-CRESOL |
4-CHOLOROANILINE |
HEXACHLOROETHANE |
HEXACHLOROBUTADIENE |
DIMETHYL PHTHALATE ' |
DIETHYL PHTHALATE |
| -5.2 11.3
21.4 35.2
34.3 16.2
39.8 13.6
3.5 6.2
3.6 7.8
DIBUTYL PHTHALATE || 36.5 10.7
BUTYL BENZYL PHTHALATE || 43.6 11.3
BIS(2-ETHYLHEXYL)PHTHALATE
NAPHTHALENE
LINDANE |
| 49.8 12.7
| 9.9 9.6
| 18.7 8.0
DIELDRIN || 54.0 15.2
I
I
I I I
I I
REMOVAL STANDARD (REMOVAL STANDARD (REMOVAL STANDARD
% DEVIATION
93.4 4.3
88.9 5.1
95.3 5.2
85.1 7.8
92.8 2.6
96.7 3.7
68.2 15.3
73.9 21.9
87.6 23.1
97.1 2.5
96.2 4.5
98.1 1.5
97.6 1.6
96.1 3.7
96.9 3.9
63.3 14.4
97.9 1.3
55.9 39.2
81.4 9.1
X DEVIATION
20.0 8.9
15.8 9.9
17.1 9.4
37.0 11.6
0.9 1.3
11.8 15.3
1.? 0.8
1'.9 0.8
0.0 *
50.1 16.1
0.7 0.3
1.5 0.5
41.5 10.4
49.0 12.1
71.5 23.8
14.2 8.7
27.5 10.0
48.1 18.5
% DEVIATION
72.9 9.9
72.1 10.5
78.8 10.0
48.1 13.9
91.3 3.4
57.1 38.3
69.0 20.6
78.2 27.7
99.7 *
47.2 16.5 ||
97.4 1.5 ||
96.2 1.8 ||
53.6 9.9 ||
47.0 12.3 ||
-13.2 22.0 ||
83.6 8.4 ||
28.5 38.3 ||
35.9 24.0 ||
I
* Only one data point available
-------
TABLE 13.
ro
AVERAGE MASSES IN GRAMS OF CERCLA ORGAN1CS IN WASTLWATER
AND SLUDGES FROM THE UNACCLIMATED SYSTEM
|| UASTEUATER FEED
II
II
Compounds || AVERAGE STANDARD
|| DEVIATION
II
II
II
(DICHLOROBENZENE. PROBABLY 1,2 || 93.0 26.2
(DICHLOROtENZENE. PROBABLY 1,3 || 104.8 35.4
IDICHLOROBENZENE, PROBABLY 1,4 || 96.6 26.0
(1,2,4-TRICHLOROBENZENE || 164.4 37.0
(NITROBENZENE || 113.3 33.7
|1,3-OINITROBEHZENE || 61.7 14.7
(2,6-DINITROTOLUm || 96.0 18.8
IP-CRESOL || 152.5 37.9
(4-CHLOROANIIINE ||
(HEXACHLOROETHANE || 56.5 16.3
IHEXACHLOROBUTADIENE || 75.7 25.5
(DIMETHYL PHTHALATE || 72.3 19.3
IDIEIHYL PHTHALAIE || no.a 30.6
IDIBUIYL PHTHALATE || 102.7 16.7
(BUTYL BENZYL PHTHALATE || BO. 5 19.5
|BIS(2-ETHYLHEXYL)PHTHALATE ||
(NAPHTHALENE || 120.7 30.2
ILINOAHE || 87.9 20.9
IDIELDRIN || 189.4 125.5
1 II
PRIMARY EFFLUENT
AVERAGE STANDARD
DEVIATION
76.8 16.2
85.2 20.3
78.8 14.7
124.2 7.7
105.3 31.8
8.4 2.0
73.5 34.2
109.7 73.3
31.8 10.0
36.0 12.7
61.8 24.4
112.4 28.3
80.4 26.7
49.1 13.0
109.7 34.6
73.0 16.0
99.6 97.0
(SECONDARY EFFLUENT
AVERAGE STANDARD
DEVIATION
13.8 5.9
14.8 4.1
11.2 3.5
20.2 4.0
44.1 16.3
8.4 6.7
12.7 5.8
5.8 8.6
0.0 0.0
1.7 0.4
2.2 1.2
3.6 1.1
3.8 1.2
2.0 0.5
6.1 5.1
39.7 18.3
10.1 11.6
| PRIMARY SLUDGE
AVERAGE STANDARD
DEVIATION
9.6 9.4
9.3 10.7
7.9 7.6
56.0 55.9
0.7 0.7
0.9 1.0
15.8 31.5
6.0 4.6
28.2 48.1
5.4 5.0
16.8 23.7
13.2 25.1
28.8 48.3
15.1 11.3
10.5 16.9
5.2 2.5
4.0 5.2
SECONDARY SLUDGE
AVERAGE STANDARD
DEVIATION
2.2 2.9
2.5 3.4
1.6 2.4
13.2 14.4
1.4 2.5
2.1 1.6
0.0 0.0
0.0 0.0
0.0 0.0
5.7 7.9
0.0 0.0
0.1 0.1
0.8 0.5
0.6 0.5
0.5 0.4
9.2 11.6
10.2 10.5
-------
TABLE 14. AVERAGE PERCENT REMOVALS AND PARTITIONING OF CERCLA
ORGANICS FOR THE UNACCLIMATED SYSTEM
ro
CJ1
| (PRIMARY
Conpounds
IDICHLOROBENZENE. PROBABLY 1.2
IOICHLOROBENZENE, PROBABLY 1,3
IDICHIOROBENZENE, PROBABLY 1.4
|1,2,«-TRICHLOROBENZENE
INITROBENZENE
|1,3-DINUROBEMZENE
I2.6-OIN1TROTOLUENE
IP-CRESOL
[4-CHLOROANILINE
IHEXACHLOROETHANE
IHEXACHLOROBUTADIENE
[DIMETHYL PHTHALATE
IDIETHYL PHTHALATE
IDIBUTYL PHTHALATE
BUTYL BENZYL PHTHALATE
|BIS(2-ETKYLHEXYL)PHTHALA1E
[NAPHTHALENE
LIHOANE
OIELDRIN
II
II
| (REMOVAL
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
X
20
17
17
22
17
88
31
20
43
50
10
4
22
39
13
16
43
TREATMENT
TOTAL
1
1
STANDARD (REMOVAL
DEVIATION)
10
7
6
15
6
2
24
43
8
16
36
12
19
3
3
15
31
X
84
85
88
87
58
86
86
97
100
98
96
97
96
97
95
52
95
TREATMENT
STANDARD
DEVIATION
8
7
4
6
20
11
9
4
0
0
1
2
1
1
1
4
26
3
REMOVAL
REMOVAL
X
11
9
9
19
2
6
30
11
1
7
26
19
18
19
IN SLUDGE IBIODEGRADATION + ||
STANDARD
DEVIATION
8
8
7
6
2
*
»
14
0
*
11
26
10
13
STRIPPING ||
REMOVAL
X
74
75
79
66
50
94
66
85
96
88
71
79
28
78
II
STANDARD ||
DEVIATION) |
II
II
II
7 II
5 II
6 II
1 II
18 ||
II
II
* II
II
II
» II
10 1)
1 II
* II
10 (1
II
25 ||
19 ||
16 ||
II
* Only one data point avaitable.
-------
emissions were not measured for the semi volatile organics, the removal
mechanisms during the CERCLA study period are reported in Table 14 as
removal in sludge and the combined biodegradation + stripping. The raw
data on the individual sample events in the CERCLA study period are also
included in Appendix 2.
OVERVIEW OF THE RESULTS
Substantial variability occurs in the reported results because some
compounds, especially in the RCRA study period, were not satisfactorily
identified in the analytical tests. In the RCRA study five spiked toxics,
two volatile polar solvents (cyclohexanone and furfural) and three phenols
(2,4-dimethyl phenol, 2,4-dinitrophenol, and 4-nitrophenol) were not
satisfactorily identified by the analytical methodology. In the CERCLA
study, all of the tested toxics were measurable by the analytical procedures,
but in the small data base for the unacclimated operation, two compounds,
4-chloroaniline and bis(2-ethylhexyl) phthalate, were not satisfactorily
identified by the analytical tests.
The concentrations or masses of the organics in the various samples
from the treatment systems revealed good results in the air samples from
the RCRA study and reasonable results in the secondary effluents for both
studies. The analytical methodology used by the contractor laboratory
for the RCRA study period produced poor results on the concentrations or
masses of organics in the samples on raw, primary and sludge streams.
The contractor laboratory did not use the stable-labelled isotopes in
their analytical procedures. In the CERCLA study period, the in-house
U.S. EPA laboratory used stable-labelled isotopes in the analytical procedures.
The results were generally improved for the raw and primary wastewater
26
-------
samples compared to the RCRA study period. However, even with the stable-
labelled isotopes in the procedure, the amounts of organics found in the
complex sludge samples are substantially lower than the measured removals
across the primary process. There is a strong indication that organics
quantitation by available methods is not reliable in a sludge matrix,
and, as a result, mass balance closure in these studies is generally
poor.
Appendix 4 provides a quality assurance summary of the RCRA and CERCLA
data. Included are analytical recoveries, percent of collected data
usable for removal and fate calculations and relative percent differences
between collected duplicate samples. There is also a discussion of the
process used to retain or exclude data.
The overall organic removals reasonably correspond with overall
removals for these organic compounds in other studies. The concentrations
of organics in the air emissions generally indicate that the chlorinated
aliphatic solvents are essentially volatilized into the plant air emission
stream, whereas the aromatic volatile benzenes (toluene, xylenes,
chlorobenzenes) are substantially degraded. Pesticides and phthalates
are removed by both sorption on sludges and by biodegradation. These air
emission results qualitatively confirm results from earlier bench scale
studies which had superior analytical reliability but without the real
world sampling and wastewater matrix effects. Unfortunately, the
variability in the results does not reliably permit calibration of a
mechanistic model which is being developed through other treatability
studies. Additional work is planned to attempt to reduce the analytical
variability encountered in these studies.
27
-------
APPENDIX 1. RCRA STUDY PERIOD
28
-------
CONCENTRATIONS OF RCRA ORGANICS IN WASTEUATER, SLUDGE ANO AIR
SAMPLES - ACCLIMATED SYSTEM EVENT 3
NAME
Acetone
Cyclohexanone —
Furfural
2-butanona
4-methyl-2-pantanon*
Tttrahydrofuran
Carbon Tetrachloride
Chlorobenztne
Chloroform
1,2-dichloroethane
1,2-dtchloropropane
Methylene CMoridt
Tetrachloroethylene
Trichloroethylene
1,1,1-trichloroethane
1,1,2-trichloroethane
Ethylbenzene
Toluene
Total xylenei
bis-(2-ethylhexyl)-phthal«te
Butylbenzylphthalate
1,4-diehotorobenzene
2,4-dlmethylphenol
2,4-dinitrophenol
Naphthalene
Nitrobenzene
4-nitrophenol
Phenol
mmmmmmmmm
II «i
II INF
II
II ug/L
i i ••«••••
I i «»*»»»«
|| 3400
II
II
II
II
II 218
II
II 283
II WO
II 314
II
II 660
II 257
II 255
II
II 254
II 238
II 313
II 1»
II 120
II 52
II 130
II
II
II
|| 170
II
II 350
PR I
INF
(DUP)
Ug/L
2500
170
360
290
320
340
260
503
250
250
300
230
250
310
140
130
41
130
210
180
370
PR I
EFF
Ug/L
2700
210
300
260
290
310
230
450
220
220
240
210
230
380
120
93
22
130
190
170
320
PR I
EFF
(DUP)
Ug/L
1400
190
310
260
280
310
240
455
213
216
250
220
230
400
120
90
30
130
190
150
340
••»*«•*•
SEC
EFF
Ug/L
50
150
2.5
4
34
110
40
60
9
2.5
2.5
100
2.5
2.5
2.5
5
5
5
5
5
5
SEC
WAS
Ug/L
260
10
5
5
34
5
5
10
7
5
25
5
10
5
160
5
5
5
5
5
PRI
WAS
ug/L
800
150
110
300
330
300
250
150
360
280
220
300
400
160
1100
740
230
340
29
320
PRI
UAS
(OOP)
Ug/L
2200
200
105
300
340
330
240
160
350
260
210
370
410
190
760
320
200
250
69
320
PRI
AIR
Ug/L
0.10
0.00
0.23
0.17
0.18
0.13
0.15
0.27
0.19
0.19
0.23
0.09
0.15
0.25
0.13
»•••••••
AERTN
AIR
Ug/L
0.00
0.32
7.31
1.50
5.20
3.33
4.99
4.86
6.05
5.11
6.56
2.67
0.83
1.46
1.10
29
-------
9
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1 Ul U.
1 M Ul
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23
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-------
REMOVAL AMP PARTITIONING OF RCRA ORGANICS DURING
TREATMENT - ACCLIMATED SYSTEM EVENT 3
NAME
|| X X X IN X IN X IN X X ||
II II
||PRIHART TOTAL PRIMARY AERATION TOTAL ADSORBED BIODEGRADED ||
11REMOVAL REMOVAL AIR AIR AIR +CHEM. TRANS. 11
Acetone -
Cyelohexanone
Furfural
2-butanone
4-mthyl-2-pcntamn*
Tetrahydrofuran
Carbon TetracMoride
Chlorobenzene
Chloroform
1,2-dichloroethane
1,2-dichloropropane
Methylene Chloride
Tetrachloroethylene
Trichloroethylene
1,1,1 -trichIoroethane
1,1,2-trichloroethane
Ethylbenzene
Toluene
Total Xylenes
bis-(2-ethylhexyl)-phthalate
ButylbenzyIphthaIate
1,4-dicholorobenzene
2,4-dimethylphenol
2,4-dinitrophenol
Naphthalene
Nitrobenzene
4-nitrophenol
Phenol
31
98
-3
15
9
14
5
10
22
15
U
18
11
6
37
11
27
44
0
10
9
23
99
99
90
66
89
90
97
99
99
59
99
100
98
96
89
96
98
97
0
9
6
7
5
6
9
7
7
8
4
6
8
4
5
119
24
83
54
81
70
97
83
101
44
13
19
16
5
128
30
90
59
87
80
104
91
109
47
19
26
20
1
1
1
2
1
2
1
2
2
1
2
2
2
12
U
2
2
0
16
-31
68
-2
6
-11
-8
7
-12
10
79
71
76
84
76
94
95
97
98
31
-------
CONCENTRATIONS OF RCSA ORGANICS IN UASTEVATER. SLUDGE AW AIR
SAMPLES - ACCLIMATED SYSTEM - EVENT 4
NAME
Acetone -
Cyclohexanone
Furfural
2-Butanone
4-*ethyt-2-Pentanone
Tetrahydrofuran
Carbon Tetrachloride
ChIorobenzene
Chloroform
1,2-Oichloroethane
1,2 • 0 i ch I oropropane
Methylene Chloride
Tetrachloroethylene
Trichloroethylene
1,1,1-Trichloroethane
1,1,2-Triehloroethane
Ethylbenzene
Toluene
Total Xylenes
8is-(2-ethylhexyO-phthalate
Butylbenzytphthalate
1,4-dicholorobenzene
2,4-Oimethylphenol
2,4-Oinitrophenol
Naphthalene
Nitrobenzene
4-Mitrophenol
Phenol
mmmmmmmmm
II wi
II I»
-------
MASSES IN GRAMS OF RCRA ORGAN ICS III UASTEUATER, SLUDGE AND
AIR STREAMS - ACCLIMATED SYSTEM EVENT 4
NAME
Acetone -
Cyclohexanone
Furfural
2-Butanone
4-MethyI-2-Pentanone
Tetrahydrofuran
Carbon Tetrachloride
Chlorobenzene
Chloroform
1,2-Dichloroethane
1,2-Oichloropropane
Methylene Chloride
Tetrachloroethylene
Triehloroethylene
1,1,1-Trichloroethane
1,1,2-Triehloroethane
Ethylbenzene
Toluene
Total Xylenes
Bis-(2-ethylhcxyl)-phthalate
Butylbenzylphthalate
1,4-dicholorobenzene
2,4-Dimethylphenol
2,4-Oinitrophenol
Naphthalene
Nitrobenzene
4-«itrop*ienol
Phenol
*»
II
II
II
II
1 tl
1 1
II
1
1
1
1
1
11
fl
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
11
II
nswBv
RUU
169.1
40.7
0.0
0.0
0.0
3.1
1.9
0.0
0.0
18.8
24
.O
0.0
6.2
0.0
3.9
36.6
10.1
9.4
1.9
1.9
2.2
1.9
zsaxnai
PR I
INF
200.7
74.8
40.4
74.0
107.2
98.1
102.6
106.8
96.5
164.4
ft1 T
01 • J
80. 5
111.0
94.2
74.0
109.1
76.3
57.2
35.1
42.0
49.6
49.6
BBSSKH
PR I
EFF
230.8
58.0
54.6
85.8
120.2
108.7
118.3
127.8
103.0
202.2
en E
TJ.J
91.6
120.2
99.2
89.7
116.4
87.8
45.8
16.4
37.8
45.8
45.8
PRIM
AIR
7.4
1.1
1.1
0.4
11.1
7.4
7.4
7.4
7.4
14.8
7.4
11.1
3.7
7.4
11.1
7.4
PRIM
AIR
COUP)
7.4
1.9
1.1
1.1
11.1
7.4
7.4
7.4
7.4
14.8
7.4
11.1
3.7
7.4
11.1
7.4
PR1
WAST
4.
0.
0.
1.
1.
2.
2.
2.
1.
1.
2.
1.
1.
2.
1.
1.
1.
0.
0.
0.
7
5
9
1
7
1
4
0
7
8
5
6
8
6
7
7
4
0
6
2
SEC
EFF
8.8
.9
.9
.9
.1
.0
16.0
47.3
22.9
48.1
2.7
3.1
50.4
1.0
1.9
0.8
1.9
1.9
1.9
1.9
1.9
SEC
EFF
(DUP)
1S.3
1.9
1.9
1.9
2.3
1.0
25.9
81.6
35.5
87.4
5.0
12.2
1.0
1.5
1.0
1.9
1.9
1.9
1.9
1.9
SEC
WAST
0.9
0.0
0.0
4.0
0.1
0.0
0.8
2.1
1.0
1.1
0.1
0.0
2.1
0.0
0.2
0.0
0.0
0.0
0.0
0.0
0.0
AERTN
AIR
6.2
0.1
0.5
4.7
132.4
26.5
98.1
63.9
88.8
120.0
130.9
93.5
124.6
51.4
15.6
26.5
31.2
II
II
II
II
II
II
35.2 122.1 141.2
1.2
1.9 1.9
0.0
33
-------
REMOVAL AND PARTITIONING OF RCRA ORGANICS OUR INC
1 TREATMENT - ACCLIMATED SYSTEM EVENT 4
NAME
II -
II
| [PRIMARY
| | REMOVAL
-.———..——»—•——— ———g—»^— »~——^——^~ 1 I =— — ==— as=aa
Acetone
Cyclohexanone
Furfural
2-3utanone
4-Methyl -2-Pentanene
Tetrahydrofuran
Carbon Tetrachloride
CUorcbeniene
Chloroform
1 , 2-0 i eh I oroe thane
1 ,2-Oich loropropane
Methylene Chloride
Tetrachloroethylene
Trichloroethylene
1 , 1 , 1 -T ri ch I oroe thane
1 , 1 ,2-Tri ehloroethane
Ethylbenzene
To I uene
Total Xytenes
Bis-(2-ethylhexyl)-phthalate
Butylbenzylphthalace
1 ,4-dicholorobenzene
2,4-Dimethylphenol
2,4-Oinitrophenol
Naonthalene
N i trobenzene
4-1itrcpnenol
Phenol
II
II
II
II
II
II
11
11
II
II
II
11
li
II
11
II
II
II
•II
II
II
II
II
11
II
11
II
11
-15
22
-35
-16
-12
-11
-15
-20
-7
-23
-15
-14 '
-8
-5
-21
-7
-15
20
53
10
8
a
-16
S3S33XS3:
TOTAL
REMOVAL
94
97
95
97
98
99
80
40
70
59
94
98
96
67
99
98
99
97
95
95
96
96
98
X IN
PRIMARY
AIR
2
1
1
- 1
12
8-
8
8
8
15
8
8
11
4
a
9
7
X IN
AERATION
AIR
2
0
1
5
139
27
102
67
93
118
135
98
127
54
16
22
30
X IN X
TOTAL ADSORBED
AIR
4
1
2
6
151
35
110
75
101
133
143
106
138
58
24
31
37
3
1
2
7
2
2
3
4
3
3
2
2
4
2
3
2
3
4
0
1
0
1
5
BIOOEG3AOEO
+CHEM. TRAMS,
87
95
91
84
-55
62
-33
-39
-34
-52
-10
-44
5
73
64
60
94
91
95
95
96
97
II
II
II
• II
._ I 1
"11
II
II
II
11
II
II
11
II
II
II
II
11
11
II
II
II
11
II
II
II
11
11
II
II
II
II
11
II
34
-------
CONCENTRATIONS OF RCRA ORGANICS IN UASTEUATER, SLUDGE AND AIR
SAMPLES - ACCLIMATED SYSTEM EVENT 5
ACCLIMATED SYSTEM
HAME
Acatona
Cyclohaxanona
Furfural
2-buttnont
4-mathyl-2-pantanona
Tetrahydrofuran
Carbon Tatraehlon'da
Chlorobanzana
ChIorofona
1,2-dichloroathana
1,2•dichIoropropant
Methylana CMorida
Tatrachtoroathylana
T r i chIoroathyIana
1,1,1-tri chloroathana
1,1,2-trtchloroathana
Ethytbanzana
Totuana
Total Xylana*
bis-(2-athylhtxyl)-phthalata
Butylbanzylphthalata
1,4-dichlorobanzana
2,4-dimathyIphenol
2,4-dinitrophanol
Naphthalana
Nitrobanzana
4-nitrophanol
Phenol
imm*999t
PHI
INF
ug/L
1100
63
420
220
160
230
170
180
330
180
150
200
170
160
270
200
94
62
60
91
82
270
»••••«*•
PR I
INF
(DUP)
Ug/L
630
81
320
200
120
210
160
160
250
150
130
180
150
140
240
180
77
30
71
91
140
!•••••*«
PR1
EFF
Ug/L
590
24
180
250
120
170
130
130
210
120
100
140
130
110
190
140
73
30
56
89
85
170
IXBBMMVI
SEC
EFF
Ug/L
5
5
1
230
3
2.5
28
46
83
a
5
2.5
110
2.5
2.5
2
2.5
5
5
5
5
6
SEC
WAS
Ug/L
5
5
5
42
2.5
2.5
4
2.5
2
1
2.5
17
1
1
2
300
5
6
5
18
5
SEC
WAS
(DUP)
Ug/L
11
5
7
5
2.5
2.5
4
2.5
2
1
2.5
18
1
1
2
220
5
7
5
5
5
I •»••••!
PR!
WAS
Ug/L
1200
19
14
24
8
24
16
15
14
14
16
15
15
23
19
900
500
180
260
100
290
** * *«*•* a
PHI
AIR
(Ug/L)
0.10
0.02
0.03
0.04
0.20
0.40
0.20
0.20
0.30
0.20
0.20
0.20
0.10
0.20
0.30
0.20
(•••MX**
AERTH
AIR
(Ug/L)
0.20
0.005
0.005
0.40
8.20
3.90
6.80
5.80
9.00
8.60
6.40
7.50
3.70
1.00
2.60
2.10
35
-------
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-------
REMOVAL AND PARTITIONING OF RCRA ORGAMICS DURING
TREATMENT - ACCLIMATED SYSTEM EVENT 5
ACCLIMATED SYSTEM
NAME
Action*
Cyclohtxcnon*
Furfuril
2 -but anon*
4-Mthyl-2-p*ntanon*
Tctrihydrofurwi
Carbon TetracMorid*
Chlorob*nt«n*
Chloroform
1 ,2-dlcMoro*th*n*
1 1 . rli l-h 1 nrnnrrmmnm
i t £ Qicnioroprop*n*
M*thyl*n* Chlorid*
Tttraehloro*thyl*n*
Triehloro*thyt*n*
1 ,1 , 1 -triehtoro*th*n*
1,1,2-tr1chloro*thm*
Ethylb*nz*n*
Tolucn*
Total Xyl*n*«
bi«-<2-*thylh*xyO-phthtt«t*
Butytb*nzylphth*ltt*
1,4-dichlorob*nz*n*
2,4-din»thytphtnol
2,4-d
-------
CONCENTRATIONS OF RCRA ORGANICS IN UASTEUATER, SLUDGE AND AIR
SAMPLES - UNACCLIHATED SYSTEM EVENT 3
CO
CD
|| RUU
NAME ||
II
II U«/l
«"««««
Acetone | | 830
Cyclohexanone ||
Furfural | |
2-butanone ||
4-»ethyl-2-pentanone || 30
Tetrahydrofuran | |
Carbon Tetrachloride ||
Chlorobenzene 1 1 12
Chloroform 1 1 8
1,2-dichloroethane ||
1,2-dichloropropane ||
Methylene Chloride || 66
Tetrachloroethylene 1 1 6
Trlchloroethylene ||
1.1,1-trlchloroethane || 11
1,1.2-trichloroethane ||
Ethyl benzene || 9
Toluene | | 67
Total Xylenes || 17
bls-(2-«thylhexyl)-phthalate || U
Butylbenzylphthalate ||
1.4-dlchotorobenzene ||
2.4-diMethylphenol ||
2,4-dinltrophenol ||
Naphthalene | | 18
Nitrobenzene ||
4-nitrophenot , ' ||
Phenol | | 195
PRI
INF
Ufl/L
990
160
150
220
220
200
140
160
340
96
130
160
180
150
170
190
86
31
150
130
140
120
410
PRI
INF
(DUP)
ug/L
1100
190
150
120
150
210
140
140
330
96
130
160
180
150
170
190
93
34
130
130
130
120
380
PRI
EFF
Ug/L
970
110
130
57
72
72
52
52
220
49
63
57
62
44
82
69
37
11
110
120
140
120
370
PRI
EFF
UB/L
34
5
92
2.5
14
23
42
34
53
13
12
6
68
7
4
11
5
5
22
5
40
25
5
PRI
EFF
(OOP)
Ug/L
45
5
93
4
12
21
37
30
80
12
10
6
62
7
4
10
5
5
12
5
24
25
5
MIXED
LIQUOR
0 MRS
Ug/L
17
5
11
2.5
3
2
2.5
2.5
22
2.5
2.5
2.5
2.5
2.5
39
2
30
5
5
5
5
25
28
MIXED
LIQUOR
48 HRS
Ug/L
15
5
35
2.5
1
2
4
2
43
1
2.5
2.5
11
1
3
1
69
5
5
5
5
25
5
SEC
WAS
Ug/L
1200
5
5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
46
110
86
110
37
5
20
5
6
25
6
PRI
WAS
Ug/L
1500
190
300
64
160
200
120
130
130
120
100
130
100
240
19
170
120
51
73
5
25
140
PRI
WAS
(DUP)
Ug/L
1300
150
210
71
170
200
110
120
130
140
130
130
100
270
200
250
140
73
100
54
25
380
PRI.
AIR
Ug/L
0.01
0.02
0.00
0.19
0.15
0.16
0.08
0.10
0.20
0.20
0.18
0.23
0.08
0.11
0.22
0.10
|AERTN.|
AIR |
1
ug/L |
1
0.01 |
I
I
I
0.00 |
0.12 |
2.81 |
1.55 |
2.07 |
1.05 |
1.69 |
1.82 |
3.01 |
2.39 |
3.07 |
1.19 |
1.58 |
1.56 |
1.22 |
1
1
1
1
1
1
1
1
1
=======
II
-------
NAME
Action* -
Cyclohexanone
Furfural
2-butanon*
4-methyl-2-pentanone
Tetrahydrofuren
Carbon Tetrachloride
Chlorobtnzen*
Chloroform
1,2-dichloroethane
1,2-dichloropropan*
Hethylene Chloride
Tetrachlorocthylene
Triehloroethytene
1,1,1-trichloroethane
1,1,2-trichloroethane
Ethylbenzene
Toluene
Total Xylenes
bis-(2-ethylhexyl)-phthalatt
Butylbenzylphthalate
1,4-dicholorobenzene
2,4-dimathylphanol
2,4-dinitropnenol
Naphthalene
Nitrobenzene
4-nitrophenol
Phenol
MASSES IN GRAMS OF RCRA ORGANICS IN UASTEUATER, SLUDGE AND AIR
STREAMS - UNACCLIMATED SYSTEM EVENT 3
RUU PRI
PR I
PRI PRI PRI
PR I AERTN SEC
SEC
SEC MIXED
INF INF EFF AIR WAS WAS AIR EFF EFF WAS LieUOR jj
II
(DUP)
COUP)
COUP)
II™
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
185.3
6.7
0.0
0.0
2.7
1.8
0.0
0.0
14.7
1.3
0.0
2.5
0.0
2.0
15.0
3.8
3.1
0.0
0.0
4.0
0.0
0.0
43.5
221.0
35.7
33.5
49.1
49.1
44.6
31.2
35.7
75.9
21.4
29.0
35.7
40.2
33.5
37.9
42.4
19.2
6.9
33.5
29.0
31.2
26.8
91.5
245.5
42.4
33.5
26.8
33.5
46.9
31.2
31.2
73.7
21.4
29.0
35.7
40.2
33.5
37.9
42.4
20.8
7.6
29.0
29.0
29.0
26.8
84.8
246.1
27.9
33.0
14.5
18.3
18.3
13.2
13.2
55.8
12.4
16.0
14.5
15.7
11.2
20.8
17.5
9.4
2.8
27.9
30.4
3S.5
30.4
93.9
0.4
0.8
0.0
7.8
6.2
6.6
3.3
4.1
8.2
8.2
7.4
9.5
3.3
4.5
9.0
4.1
7.7
1.0
1.5
0.3
0.8
1.0
0.6
0.7
0.7
0.6
0.5
0.7
0.5
1.2
0.1
0.9
0.6
0.3
0.4
0.0
0.1
0.7
6.7
0.8
1.1
0.4
0.9
1.0
0.6
0.6
0.7
0.7
0.7
0.7
0.5
1.4
1.0
1.3
0.7
0.4
0.5
0.3
0.1
2.0
0.2
0.0
2.0
47.9
26.4
35.3
17.9
28.8
31.0
51.3
40.7
52.3
20.3
26.9
26.6
20.8
13.0
1.9
35.1
1.0
5.3
8.8
16.0
13.0
20.2
5.0
4.6
2.3
25.9
2.7
1.5
4.2
1.9
1.9
8.4
1.9
15.3
9.5
1.9
17.2
1.9
35.5
1.5
4.6
8.0
14.1
11.4
30.5
4.6
3.8
2.3
23.7
2.7
1.5
3.8
1.9
1.9
4.6
1.9
9.2
9.5
1.9
9.8
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.4
0.9
0.7
0.9
0.3
0.0
0.2
0.0
0.0
0.2
0.0
-0
0
1
0
-0
0
0
0
1
-0
0
0
1
•0
-2
•0
2
0
0
0
0
0
-1
39
-------
REMOVAL AMD PARTITIONING OF RCRA ORGANICS DURING
TREATMENT - UNACCLIMATEO SYSTEM EVEMT 3
X IN
X IN X IN
NAME
II II
I(PRIMARY TOTAL PRIMARY AERATION TOTAL ADSORBED BIODEGRADED ||
||REMOVAL REMOVAL AIR AIR AIR +CHEM. TRANS.||
Acetone _
Cyclohexanone
Furfural
2-butanone
4-methyl-2-penttnone
Tetrahydrofuran
Carbon Tetrachloride
Chlorobenzene
Chloroform
1,2-dichloroethane
1,2-dichloropropane
Methylene Chloride
Tetrachloroethylene
Trichloroethylene
1,1,1-trichloroethene
1,1,2-trichloroethane
Ethyl benzene
Toluene
Total Xylenes
bis-<2-ethylhexyl)-phth«lat«
Butylbenzylphthalate
1,4-dieholorobenzene
2,4-diinethylphenol
2,4-dinitropftenol
Naphthalene
Nitrobenzene
4-nitrophenol
Phenol
,,».
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
•6
29
2
62
56
60
SB
61
25
42
45
59
61
67
45
59
53
61
11
94
95
-5
97
88
82
52
64
66
78
86
94
38
92
96
91
91
74
79
0
1
0
16
12
13
7
9
12
16
16
18
7
9
9
7
0
0
4
100
49
69
38
60
46
97
85
97
43
51
26
37
0
1
4
117
61
82
44
69
58
112
101
115
50
59
35
45
7
2
4
1
2
2
2
2
3
2
2
3
4
5
3
7
9
2
""*" 1 1
86 ||
II
II
11
92 ||
•15 ||
-21 ||
25 ||
-3 II
5 II
-7
•38
•18
•23
-H
28
58
43
81 |
65 |
n I
•5
-18
-13
-7
93
59
65
98
92
59
64
98
40
-------
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-------
REMOVAL AMD PARTITIONING OF ROU ORGAN1CS DURING
TREATMENT - UNACCLIMATED SYSTEM EVENT 4
NAME
Acetone —
Cyelotraxanont
Furfuril
2-Buttnom
4-M«thyl-2-Pent«ncne
Tetrihydrofurin
Carbon Tetrichloride
Chtorobenzene
Chlorofom
1,2-Dichloroethene
1,2-Oichloropropene
Mcthyicnc Chloride
Tet rich loroethy I ene
Triehloroethyten*
1,1,1-Trichloroethene
1 , 1 ,2-Trichloroethene
Ethyl benzene
Toluene
Total Xylent*
Bis-(2-ethylhexyl)-phthalite
Butylbenzylphthalete
1,4-Oicholorobenzene
2,4-OiMthylphtnol
2,4-Dinitrophenol
Naphthalene
Nitrobenzene
4-Nitrophtnol
Phenol
II «
II
| | PRIMARY
1 1 REMOVAL
II -17
II 15
II
II 8
II -n
II
II 10
II *
II 16
II °
II 5
II "9
II 8
II 7
II 10
II 1
II 4
II -5
II 2
II 61
II "
II "
II
II
II o
II «
II
II 30
X
TOTAL
REMOVAL
98
88
95
77
99
93
90
70
77
78
94
95
97
49
94
98
97
92
87
77
90
77
95
X IN
PRIMARY
AIR
4
0
1
3
17
16
16
9
9
24
16
17
15
9
8
11
6
X IN
AERATION
AIR
3
0
0
0
171
73
116
61
107
111
173
136
175
57
84
42
52
X IN
TOTAL
AIR
7
0
1
3
188
89
132
70
116
135
189
153
190
66
92
53
58
X
ADSORBED
4
1
2
4
1
2
2
3
2
1
2
2
3
1
2
1
7
0
3
2
1
0
x II
II
BIODEGRADED | |
+CHEM. TRANS. ||
>••*••••••••••••• 1 I
87 ||
87 ||
||
92 ||
70 ||
| |
-90 ||
2 II
-44 ||
-3 II
-41 | |
II
-96 ||
-60 ||
-95 ||
-20 ||
1 II
43 ||
38 II
85 ||
87 ||
74 ||
||
II
88 ||
76 ||
||
W ||
************
43
-------
CONCENTRATIONS OF RCRA ORGANICS IN UASTEUATER, SLUDGE AND AIR
SAMPLES - UMACCLIMATED SYSTEM EVENT 5
UNACCUNATED SYSTEM || RUU
II
II
NAME || 09/1
»mm«mmBmmm«am •* **»*•»••••»»» 1 1 •••»••*
Acetone || 420
Cyclohexenone 1 1
Furfural | |
2-but«nooe jj 55
4-Mthyt-2-pent«none ||
Tetrehydrofuren || 17
C*rbon Tetrechlorlde || 2
Chtorobenzene | | 61
Chlorofom 1 1 6
1,2-dfchloroethene || 5
1,2-dichloroprofMne ||
Methylcne Chloride ||
Tetrachloroethylene 1 1 6
Trichloroethytene || 1
1.1.1-trfcbloroeth«ne || 11
1.1.2-trichloroethane ||
Ethytbenzene || 4
Toluene | | 130
Total Xylenes || 10
bU-(2-ethylhexyl)-phtheUte || 15
•utylbenzylphthcUte 1 1
1.4-dicMorofaenzene ||
2.4-dl«etbylph«not 1 1
2.4-dlnltrophenoO ||
Nephthalene | | 8
Nitrobenzene ||
4-nitrophenol ||
Phenol | | 71
PRI
INF
Ug/L
530
160
160
170
220
150
UO
HO
230
160
140
170
UO
120
260
130
55
17
65
55
150
PRI
INF
Ug/L
560
UO
220
260
160
150
150
270
170
150
200
160
130
300
UO
PRI
EFF
Ug/L
590
150
160
130
240
130
130
120
230
130
120
UO
120
97
260
110
29
7
57
52
130
PRI
iff
(OUP)
Ug/L
570
150
160
120
130
130
120
240
120
110
140
120
91
260
too
35
10
54
47
130
SEC
EFF
Ug/L
21
5
100
3
5
12
32
19
53
6
5
4
38
5
2
4
5
5
5
5
5
SEC
EFF
(OOP)
Ug/L
5
5
97
2
4
12
31
IB
59
6
4
3
38
2.5
2.5
2.5
5
5
5
5
5
MIXED
LIQUOR
0 MRS
Ug/L
41
5
5
2.5
3
2.5
3
2.5
10
2.5
2.5
2.5
2.5
2.5
2
2.5
5
5
5
5
| NIXED
LIQUOR
48 MRS
Ug/l
53
5
14
2.5
2.5
2.5
2.5
2.5
160
2.5
2.5
2.5
2.5
2.5
2
2.5
5
5
5
5
5
SEC
IMS
Ug/L
62
5
5
2.5
2.5
21
22
10
9
3
2.5
2.5
3
5
2.5
5
5
5
5
5
PRI
IMS
Ug/L
46
5
a
3
14
5
2.5
5
5
4
6
5
5
12
7
5
5
5
5
5
PRI
AIR
Ug/L
0.20
0.005
0.02
0.20
0.40
0.20
0.10
0.10
0.30
0.20
0.20
0.20
0.09
0.10
0.40
0.1
IAERTN ||
AIR ||
II
ug/i ||
6.09 ||
II
II
0.005 ||
II
0.20 ||
2.40 ||
2.30 ||
2.10 ||
1.30 ||
1.60 ||
2.60 ||
2.90 ||
2.10 ||
2.70 ||
1.10 ||
1.30 ||
1.30 ||
0.80 ||
II
II
II
II
II
II
II
II
II
-------
MASSES IN GRAMS OF RCRA ORGAN ICS IN UASTEUATER, SLUDGE AND AIR
STREAMS - UNACCLIMATED SYSTEM EVENT 5
UNACCLIMATED SYSTEM |
I
NAME
Acetone |
Cyclohexanone |
Furfural |
2-butenone |
4-ncthyl-2-pentanane |
Tetrahydrofuran |
Carbon Tetrachloride |
Chlorobenzene |
Chloroform |
1,2-dichloroethane |
1,2-dichloropropane |
Methylene Chloride |
Tetraehloroethylene |
Triehloroethylene |
1,1,1-triehloroethane |
1,1,2-trichloroethane |
Ethylbenztne |
Toluene
Total Xylenea
bis-(2-ethylhexyl)-phthalate
Butylbenzylphthalate
1,4-dichlorobenzene
2,4-dimethylphenol
2,4-dinitrophenol |
Naphthalene |
Nitrobenzene |
4-nitrophenol |
Phenol |
| RUU PRI
| INF
1
1
!»•»»>«»»»>«•
93.7 118.
12.3 35.
| 3.8 35.
0.4 37.
13.6 49.
| 1.3 33.
1.1 31.
| 0.0 31.
I 51.
| 1.3 35.
| 0.2 31.
| 2.5 37.
| 0.0 31.
| 0.9 26.
29.0 58.
2.2 29.
3.3 12.
0.0 3.
1.8 14.
0.0 12.
1
| 15.8 33.
3
7
7
9
1
5
2
2
3
7
2
9
2
8
0
0
3
8
5
3
5
PRI
INF
COUP)
125.0
31.2
49.1
58.0
35.7
33.5
33.5
60.3
37.9
33.5
44.6
35.7
29.0
67.0
31.2
PRI
EFF
149.7
38.1
40.6
33.0
60.9
33.0
33.0
30.4
58.4
33.0
30.4
35.5
30.4
24.6
66.0
27.9
7.4
1.8
14.5
13.2
33.0
PRI
EFF
COUP)
144.6
38.1
40.6
30.4
33.0
33.0
30.4
60.9
30.4
27.9
35.5
30.4
23.1
66.0
25.4
8.9
2.5
13.7
11.9
33.0
PRI
AIR
8.2
0.2
0.8
8.2
16.4
8.2
4.1
4.1
12.3
8.2
8.2
8.2
3.7
4.1
16.4
4.1
PRI
UAS
0.2
0.0
0.0
0.0
0.1
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.1
0.0
0.0
0.0
0.0
0.0
0.0
AERTN
AIR
1.5
0.1
3.4
40.9
39.2
35.8
22.2
27.3
44.3
49.4
35.8
46.0
18.8
22.2
22.2
13.6
SEC
EFF
8.0
1.9
38.2
1.1
1.9
4.6
12.2
7.2
20.2
2.3
1.9
1.5
14.5
1.9
0.8
1.5
1.9
1.9
1.9
1.9
1.9
SEC
EFF
(DUP)
1.9
1.9
37.0
0.8
1.5
4.6
11.8
6.9
22.5
2.3
1.5
1.1
14.5
1.0
1.0
1.0
1.9
1.9
1.9
1.9
1.9
•**•••*«!
SEC
UAS
0.5
0.0
0.0
0.0
0.0
0.2
0.2
0.1 |
I
0.1 |
0.0 |
0.0 |
0.0 ||
0.0 ||
0.0 |
0.0 |
0.0 |
0.0 |
II
II
II
0.0 ||
0.0 ||
II
0.0 II
45
-------
REMOVAL AND PARTITIONING OF RC8A ORGANICS DURING
TREATMENT - UttACCLIMATED SYSTEM EVENT 5
UNACCLIMATED SYSTEM
NAME
X IN
X IN
Acatont
Cyclohe
Furfural
2-butanone
4-n»thyl-2-ptnta
Tetrahydrofuran
Carbon Tctrachloride
Chlorobenzene
Chlorofom
1,2-d-phthalat»
autylbenzylphthalate
1,4-dfchlorobenzanc
2,4-dfa»thylphenol
2,4-dtnitrophenol
Naphthalene
Nitrobwutna
4-nitrophtnol
Phenol
PRIMARY
REMOVAL
-21
-U
3
-2
TOTAL
REMOVAL
PRIMARY AERATION
AIR AIR
X IN
TOTAL
AIR
ADSORBED BIODECRADED| |
+CHEM. THAN | |
96
87
85
94
92
94
•14
27
37
5
-2
6
-7
14
10
14
9
15
-6
11
34
43
-5
98
97
87
63
78
62
94
95
97
57
95
99
96
85
50
1
17
22
16
8
9
26
16
17
15
8
8
14
8
5
84
52
70
44
57
93
97
74
87
39
44
19
25
6
101
74
86
52
66
119
113
91
102
47
52
33
33
0
0
0
1
1
0
0
0
0
0
0
0
0
0
0
-11
-3
23
0
10
12
-19
4
•5
10
43
66
63
85
50
87
85
94
46
-------
APPENDIX 2. CERCLA STUDY PERIOD
47
-------
CONCENTRATIONS OF CERCLA ORGANICS IN WASTEWATER AND
---- SLUDGE SAMPLES - ACCLIMATED SYSTEM DATA SET 1
Compounds .
~
IDICHLOROBENZENE, PROBABLY 1,2
IDICHLOROBENZEME, PROBABLY 1,3
IDICHLOROBENZENE, PROBABLY 1,4
(1,2,4-TRICHLOROBENZENE
| NITROBENZENE
(1,3-OINITROBENZENE
(2,6-DINITROTOLUENE
IP-CRESOL
|4-CHOLOROANILINE
| HEXACHLOROETHANE
| HEXACHLOROBUTAO 1 ENE
(DIMETHYL PHTHALATE
IDIETHYL PHTHALATE
IDIBUTYL PHTHALATE
| BUTYL BENZYL PHTHALATE
|BIS(2-ETHYLHEXYL)PHTHALATE
[NAPHTHALENE
ILINOANE
IOIELORIN
CONCENTRATION
RUW
UG/L
10
11
10
3
2
0
71
7
0
19
5
18
37
41
29
20
66
.2
.5
.0
.9
.8
.0
.5
.9
.0
.8
.9
.9
.6
.0
.3
.5
.7
PR I
INF
UG/L
451.7
450.6
426.3
483.7
272.2
446.9
600.1
337.5
378.1
432.6
500.6
510.3
436.7
436.2
563.2
457.1
636.0
PR I
INF
(DUP)
UG/L
462.5
466.7
451.3
508.3
283.6
451.8
632.4
359.8
434.2
445.6
515.2
525.5
481.6
440.9
635.2
521.3
1068.3
PRt
EFF
UG/L
325
331
332
374
21
266
621
331
181
147
455
451
208
157
446
306
280
.2
.3
.9
.2
.5
.0
.9
.4
.0
.9
.1
.4
.0
.4
.7
.3
.6
OF TOXICS
SEC
EFF
UG/L
24.8
49.7
7.9
31.9
3.0
132.0
244.9
0.0
0.0
7.6
7.1
7.3
5.8
3.9
7.1
307.9
60.2
SEC
EFF
(DUP)
UG/L
21.1
47.7
3.5
28.8
2.0
125.0
567.2
0.0
3.0
5.9
0.9
1.1
6.1
2.7
1.2
307.1
69.0
SEC
WAS
UG/L
147
296
40
46
325
206
28
99
0
821
0
83
255
191
61
2784
12178
SEC
WAS
-------
MASSES OF CERCLA ORGANICS IN WASTEWATER AND SLUDGE
STREAMS - ACCLIMATED SYSTEM DATA SET 1
1
1
1
j Compounds
i
i
i
i
IDICHLOROBENZENE, PROBABLY 1,2
IDICHLOROBENZENE, PROBABLY 1,3
IDICHLOROBENZENE, PROBABLY 1,4
| 1 ,2,4-TRICHLOROBENZENE
(NITROBENZENE
|1,3-DINITROBENZENE
|2,6-DINITROTOLUENE
IP-CRESOL
(4-CHOLOROANILINE
IHEXACHLOROETHANE
IHEXACHLOROBUTADIENE
(DIMETHYL PHTHALATE
(DIETHYL PHTHALATE
|D I BUTYL PHTHALATE
| BUTYL BENZYL PHTHALATE
|BIS(2-ETHYLHEXYL)PHTHALATE
(NAPHTHALENE
ILINDANE
(DIELDRIN
PR I
INF
CMS
|172.3
(171.9
(162.7
I
(184.5
(103.8
(170.5
(228.9
(128.8
(144.3
(165.1
(191.0
(194.7
(166.6
(166.4
I
(214.9
(174.4
(242.6
PR I
INF
(DUP)
CMS
176
178
172
193
108
172
241
137
165
170
196
200
183
168
242
198
407
.5
.1
.2
.9
.2
.4
.3
.3
.7
.0
.6
.5
.7
.2
.4
.9
.6
PR I
EFF
CMS
124.1
126.4
127.0
142.8
8.2
101.5
237.3
126.4
69.1
56.4
173.6
172.2
79.4
60.1
170.4
116.8
107.1
MASS OF TOXICS
SEC SEC SEC
EFF EFF WAS
(DUP)
CMS CMS CMS
9.4
19.0
3.0
12.2
1.1
50.3
93.4
0.0
0.0
2.9
2.7
2.8
2.2
1.5
2.7
117.5
23.0
8.0
18.2
1.4
11.0
0.8
47.7
216.4
0.0
1.1
2.3
0.3
0.4
2.3
1.0
0.5
117.2
26.3
0.6
1.2
0.2
0.2
1.3
0.8
0.1
0.4
0.0
3.4
0.0
0.3
1.0
0.8
0.3
11.4
49.8
SEC
WAS
(DUP)
CMS
0
1
0
0
1
0
0
0
0
3
0
0
1
0
0
10
123
.6
.1
.1
.2
.6
.0
.1
.4
.0
.2
.0
.3
.0
.9
.2
.8
.4
PR I
WAS
CMS
16.
15.
13.
0.
1.
0.
2.
1.
0.
40.
0.
1.
29.
34.
18.
23.
0.
0
2
1
2
1
0
6
6
0
6
9
7
2
2
7
1
0
49
-------
REMOVAL AND PARTITIONING OF CERCLA ORGANICS DURING
""-TREATMENT - ACCLIMATED SYSTEM DATA SET 1
1
1
1
| Compounds
1
1
1
1
IDICHLOROBENZENE, PROBABLY 1,2
IDICHLOROBENZENE, PROBABLY 1,3
IDICHLOROBENZENE, PROBABLY 1,4
| 1 , 2 , 4 • TR 1 CHLOROBENZENE
(NITROBENZENE
|1,3-D [NITROBENZENE
(2,6-DINITROTOLUENE
IP-CRESOL
(4-CHOLOROANILINE
IHEXACHLOROETHANE
IHEXACHLOROBUTADIENE
| DIMETHYL PHTHALATE
IDIETHYL PHTHALATE
|D I BUTYL PHTHALATE
(BUTYL BENZYL PHTHALATE
|BIS(2-ETHYLHEXYL)PHTHALATE
(NAPHTHALENE
ILINDANE
IDIELDRIN
I
x
PRIMARY
REMOVAL
28.9
27.8
24.1
24.6
92.2
40.8
-0.9
4.9
55.4
66.3
10.4
12.8
54.7
64.1
25.5
37.4
67.1
I
X
TOTAL
REMOVAL
95.0
89.4
98.7
93.9
99.1
71.4
34.1
100.0
99.6
98.5
99.2
99.2
98.7
99.2
99.3
37.1
92.4
X
ADSORBED
9.5
9.3
7.9
*
*
*
1.1
1.5
*
*
0.5
1.0
*
*
8.3
18.3
26.6
II
II
X II
II
BIO+STRIP||
+CHE.TRAN||
II
II
85.5 ||
80.0 ||
90.8 ||
II
* II
* II
* II
33.0 ||
98.5 ||
* II
* II
98.8 | |
98.2 ||
* II
* II
II
91.0 ||
18.8 ||
65.8 ||
II
Partitioning not calculated because of inconsistent data
50
-------
CONCENTRATIONS OF CERCLA ORGANICS IN WASTEWATER AND
SLUDGE SAMPLES - ACCLIMATED SYSTEM DATA SET 2
Compounds
_
IDICHLOROBENZENE, PROBABLY 1,2
IDICHLOROBENZENE, PROBABLY 1,3
IDICHLOROBEMZENE, PROBABLY 1,4
| 1 ,2,4-TRICHLOROBENZENE
(NITROBENZENE
|1,3-OINITROBENZENE
|2,6-DINITROTOLUENE
IP-CRESOL
(4-CHOLORQANIL1NE
IHEXACHLOROETHANE
| HEXACHLOROBUTAD I ENE
(DIMETHYL PHTHALATE
IDIETHYL PHTHALATE
IDIBUTYL PHTHALATE
| BUTYL BENZYL PHTHALATE
| BI SC2-ETHYLHEXYL )PHTHALATE
(NAPHTHALENE
(LINDANE
CONCENTRATION
RUU
PR I
INF
UG/L
1.
6.
7.
9.
0.
49.
13.
14.
0.
5.
13.
15.
26.
706.
11.
0.
(DIELDRIN |
I
6
0
7
8
0
9
5
9
0
5
9
5
0
4
0
0
UG/L
291.
433.
410.
368.
610.
491.
372.
401.
474.
504.
399.
405.
944.
493.
472.
8
9
9
1
8
7
0
2
8
7
2
0
5
8
9
PR I
INF
(DUP)
UG/L
416.3
334.0
430.9
517.1
483.8
519.5
347.4
415.1
447.4
478.5
413.1
439.7
786.0
472.9
576.7
OF TOXICS
PR I
SEC
EFF
UG/L
314.
288.
372.
516.
328.
592.
311.
207.
261.
428.
480.
234.
199.
355.
420.
448.
7
5
2
4
4
5
5
6
0
4
4
4
1
6
4
5
EFF
UG/L
70
49
66
51
68
0
0
16
11
15
16
9
6
187
13
.0
.6
.3
.6
.6
.0
.0
.8
.2
.3
.2
.2
.1
.9
.4
492.6
SEC
WAS
UG/L
102
215
36
155
0
126
0
0
1133
0
18
79
0
3184
24
3007
PR I
WAS
UG/L
12475
0
7679
2655
0
984
2145
0
36258
397
760
20701
24400
39206
18048
16770
51
-------
MASSES OF CERCLA ORGANICS IN WASTEWATER AND SLUDGE
STREAMS - ACCLIMATED SYSTEM DATA SET 2
1 1
1 1
| Compounds | PR I
1 • 1 INF
1 - 1
1 1 »S
1
1
IDICHLOROBENZENE, PROBABLY 1,2
IDICHLOROBENZENE, PROBABLY 1,3
IDICHLOROBENZENE. PROBABLY 1,4
(1,2,4-TRICHLOROBENZENE
(NITROBENZENE
|1,3-OINITROBENZENE
|2,6-DINITROTOLUENE
IP-CRESOL
|4-CHOLOROANiLiNE
IHEXACHLOROETHANE
| HEXACHLOROBUTAO I ENE
IDINETHYL PHTHALATE
IOIETHYL PHTHALATE
|D 1 BUTYL PHTHALATE
| BUTYL BENZYL PHTHALATE
| B I S<2-ETHYLHEXYL )PHTHALATE
(NAPHTHALENE
ILINDAHE
IDIELDRIN
1
55
82
78
70
116
93
71
76
90
96
76
77
180
94
90
.7
.8
.4
.2
.5
.8
.0
.5
.6
.3
.1
.3
.2
.2
.2
MASS OF TOXICS
PR I PR I SEC
INF EFF EFF
(OUP)
CMS CMS CMS
79
63
82
98
92
99
66
79
85
91
78
83
149
90
110
.4
.7
.2
.6
.3
.1
.3
.2
.3
.3
.8
.9
.9
.2
.0
60.
55.
71.
98.
62.
113.
59.
39.
49.
81.
91.
44.
38.
67.
0
0
0
5
6
0
4
6
a
7
6
7
0
8
80.2
85.
6
13
9
12
9
13
0
0
3
2
2
3
1
1
35
2
94
.3
.5
.6
.8
.1
.0
.0
.2
.1
.9
.1
.8
.2
.8
.6
.0
SEC
UAS
CMS
0.
0.
0.
0.
0.
0.
0.
0.
2.
0.
0.
0.
0.
2
4
1
3
0
3
0
0
3
0
0
2
0
6.5
0.0
6.
1
PR I
WAS
CMS
14.4
0.0
8.9
3.1
0.0
1.1
2.5
0.0
42.0
0.5
0.9
24.0
28.3
45.4
20.9
19.4
52
-------
REMOVAL AND PARTITIONING OF CERCLA ORGANICS DURING
TREATMENT - ACCLIMATED SYSTEM DATA SET 2
Compounds
_
IDICHLOROBENZENE, PROBABLY 1,2
JDICHIOROBENZENE, PROBABLY 1,3
IDICHLOROBENZENE, PROBABLY 1,4
1 1 ,2,4-TRICHLOROBENZENE
(NITROBENZENE
|1,3-DINITROBENZENE
|2,6-DINITROTOLUENE
IP-CRESOL
(4-CHOLOROANILINE
IHEXACHLOROETHANE
| HEXACHLOROBUTAD I ENE
(DIMETHYL PHTHALATE
IDIETHYL PHTHALATE
IDIBUTYL PHTHALATE
(BUTYL BENZYL PHTHALATE
|BIS(2-ETHYLHEXYL)PHTHALATE
(NAPHTHALENE
(LINDANE
(DIELDRIN
I
X
PRIMARY
REMOVAL
24.4
7.8
13.9
-11.3
22.9
3.0
38.4
42.3
36.1
7.1
2.3
42.3
52.9
58.9
13.0
14.5
X
TOTAL
REMOVAL
83.2
84.1
84.7
88.9
83.9
100.0
100.0
95.3
97.2
96.7
96.7
97.7
98.5
78.3
97.2
6.1
X
ADSORBED
18.5
0.7
10.9
3.8
*
*
*
*
56.9
0.5
1.0
31.1
35.1
*
22.7
25.5
I
X
BICHSTRIP |
i-CHE.TRANl
64.7
83.4
73.8
II
85.1 ||
*
*
*
*
40.3
96.2
95.7
66.6
63.5
*
74.5
-19.4
Partitioning not calculated because of inconsistent data
53
-------
CONCENTRATIONS OF CERCLA ORGANICS IN WASTEWATER AND
StUOGE SAMPLES - ACCLIMATED SYSTEM DATA SET 3
1
1
1
| Compounds
1
1
1
1
1
JDICHLOROBENZENE, PROBABLY 1,2
IOICHLOROBENZENE, PROBABLY 1,3
IOICHLOROBENZENE, PROBABLY 1.4
1 1 ,2,4-TRICHLOROBENZENE
(NITROBENZENE
| 1,3-D (NITROBENZENE
|2,6-DINITROTOLUENE
IP-CRESOL
(4-CHOLOROANILINE
IHEXACHLOROETHANE
| HEXACHLOROBUTADIENE
| DIMETHYL PHTHALATE
IDIETHYL PHTHALATE
IDIBUTYL PHTHALATE
| BUTYL BENZYL PHTHALATE
|BIS(2-ETHYLHEXYL)PHTHALATE
(NAPHTHALENE
ILINDANE
IDIELDRIN
I
CONCENTRATION OF
RUU
UG/L
2.
8.
2.
121.
0.
0.
65.
Q.
0.
7.
11.
34.
44.
33.
15.
0.
5
2
9
7
0
0
9
0
0
6
4
6
0
7
1
0
0.0
PR I
INF
UG/L
410.
315.
416.
583.
621.
458.
714.
787.
353.
394.
444.
479.
404.
378.
5
4
5
3
2
3
5
5
4
8
3
1
7
8
475.5
384.
9
338.4
PR!
EFF
SEC
UG/L
261.
222.
273.
330.
539.
323.
887.
208.
143.
174.
383.
412.
211.
176.
358.
297.
137.
2
0
0
0
7
0
3
8
1
0
0
0
1
7
1
3
8
EFF
UG/L
24.
13.
59.
80.
52.
138.
196.
0.
17.
8.
12.
15.
14.
6.
4
0
9
4
8
7
9
0
2
9
3
6
8
6
10.8
320.8
68.3
TOXICS
SEC
WAS
UG/L
145
222
34
1662
177
0
218
0
0
1138
10
0
220
155
39
3770
13031
SEC
WAS
(OUP)
UG/L
159
140
30
1906
86
0
118
0
282
1450
0
64
520
546
0
2928
22626
PR I
WAS
UG/L
6259
4870
5891
13372
0
0
845
0
409
18362
451
536
17740
21064
0
10980
26555
54
-------
MASSES OF CERCLA ORGANICS IN WASTEWATER AND SLUDGE
STREAMS - ACCLIMATED SYSTEM DATA SET 3
Compounds
DICHLOROBENZENE, PROBABLY 1,2
D1CHLOR08EMZEME, PROBABLY 1,3
DICHLOROBENZENE, PROBABLY 1,4
1,2,4-TRICHLOROBENZENE
NITROBENZENE
1,3-DINITROBENZENE
2,6-DINITROTOLUENE
P-CRESOL
4-CHOLOROANILINE
HEXACHLOROETHANE
HEXACHLOROBUTADIENE
DIMETHYL PHTHALATE
DIETHYL PHTHALATE
D I BUTYL PHTHALATE
BUTYL BENZYL PHTHALATE
BI SC2-ETHYLHEXYL )PHTHALATE
NAPHTHALENE
LINDANE
DIELDRIN
I
PR I
INF
CMS
78.3
60.2
79.5
111.3
118.5
87.4
136.3
150.2
67.4
75.3
84.8
91.4
77.2
72.3
90.7
73.4
64.6
MASS
PR I
EFF
CMS
49.8
42.3
52.1
63.0
103.0
61.6
169.3
39.8
27.3
33.2
73.1
78.6
40.3
33.7
68.3
56.7
26.3
OF TOXICS
SEC
EFF
CMS
4.7
2.5
11.4
15.3
10.1
26.5
37.6
0.0
3.3
1.7
2.3
3.0
2.8
1.3
2.1
61.2
13.0
SEC
WAS
CMS
0.3
0.5
0.1
3.4
0.4
0.0
0.4
0.0
0.0
2.3
0.0
0.0
0.4
0.3
0.1
7.7
26.6
SEC
VMS
(DUP)
CMS
0.3
0.3
0.1
3.9
0.2
0.0
0.2
0.0
0.6
3.0
0.0
0.1
1.1
1.1
0.0
6.0
46.2
PR I
WAS
CMS
7.2
5.6
6.8
15.5
0.0
0.0
1.0
0.0
0.5
21.3
0.5
0.6
20.5
24.4
0.0
12.7
30.8
55
-------
REMOVAL AND PARTITIONING OF CERCLA ORGANICS DURING
TREATMENT - ACCLIMATED SYSTEM DATA SET 3
1
1
| Compounds
1
1
1
1
1
IDICHLOROBENZENE, PROBABLY 1,2
IDICHLOROBENZENE, PROBABLY 1,3
IDICHLOROBENZENE, PROBABLY 1,4
| 1 , 2 , 4 - TR I CNLOROBENZENE
(NITROBENZENE
|1,3-DINITROBENZENE
|2,6-DINITROTOLUENE
IP-CRESOL
(4-CHOLOROANILINE
IHEXACHLOROETHANE
IHEXACHLOROBUTADIENE
(DIMETHYL PHTHALATE
(DIETHYL PHTHALATE
(DIBUTYL PHTHALATE
(BUTYL BENZYL PHTHALATE
|BIS(2-ETHYLHEXYL)PHTHALATE
(NAPHTHALENE
(LINDANE
IDIELDRIN
I
X
PRIMARY
REMOVAL
36.4
29.6
34.5
43.4
13.1
29.5
-24.2
73.5
59.5
55.9
13.8
14.0
47.8
53.3
24.7
22.8
59.3
X
TOTAL
REMOVAL
94.1
95.9
85.6
86.2
91.5
69.7
72.4
100.0
95.1
97.8
97.2
96.7
96.3
98.3
97.7
16.7
79.8
X
ADSORBED
*
*
*
*
0.2
*
1.0
*
*
31.7
0.6
0.8
27.6
34.8
ft
26.6
*
II
* II
II
II
BIO+STRIP||
+CHE.TRANJI
II
II
* II
* II
* II
* II
91.3 ||
II
* II
71.5 ||
*
*
66.0
96.6
96.0
68.7
63.5
* II
-10.0 ||
* II
II
* Partitioning not calculated because of inconsistent data
56
-------
CONCENTRATIONS OF CERCLA ORGANICS IN WASTEWATER AND
SLUDGE SAMPLES - ACCLIMATED SYSTEM DATA SET 4
COMPOUNDS
—
IDICHLOROBENZENE, PROBABLY 1,2
IDICHLOROBENZENE, PROBABLY 1,3
IDICHLOROBENZENE, PROBABLY 1,4
| 1 ,2, 4 -TRICHLOROBENZENE
| NITROBENZENE
|1,3-D1NITROBENZENE
|2.6-DINITROTOi.UENE
IP-CRESOL
|4-CHLOROANILINE
IHEXACHLOROETHANE
| HEXACHLOROBUT AD I ENE
[DIMETHYL PHTHALATE
IDIETHYL PHTHALATE
IDIBUTYL PHTHALATE
| BUTYL BENZYL PHTHALATE
| BI SC2-ETHYLHEXYL )PHTHALATE
| NAPHTHALENE
ILINDANE
IOIELDRIN
I
CONCENTRATION
RUW
PR I
INF
UG/L
4
5
3
110
1
0
0
52
11
0
.0
.5
.5
.6
.1
.0
.0
.8
.8
.0
10.8
4
13
29
31
495
11
13
48
.1
.3
.9
.3
.8
.0
.4
.5
UG/L
368.
377.
387.
527.
379.
195.
386.
558.
334.
264.
383.
451.
468.
421.
399.
668.
432.
425.
311.
7
0
3
7
7
8
9
5
1
5
2
3
1
1
5
4
1
8
6
PR I
EFF
UG/L
318.
273.
337.
406.
416.
245.
477.
92.
252.
282.
459.
394.
285.
239.
313.
372.
355.
0
2
6
1
7
0
5
6
9
7
0
2
6
2
5
9
5
SEC
EFF
UG/L
41.9
89.2
16.3
179.0
35.9
20.3
246.2
60.1
0.0
0.7
66.3
1.6
2.9
59.2
58.1
343.8
15.1
83.4
OF TOXICS
SEC
WAS
UG/L
6
6
2
42
0
0
0
15
0
0
47
7
8
10
0
215
6
71
486
SEC
WAS
(DUP)
UG/L
7
6
5
43
0
0
0
8
0
11
35
7
7
11
0
224
4
66
222
PR I
WAS
UG/L
12960
12656
11771
31291
151
35
126
2181
905
0
36081
544
1105
24226
31380
51994
11673
19154
0
PR I
WAS
(DUP)
UG/L
11145
10730
10173
29845
102
435
0
1764
744
0
31838
408
955
19782
26108
47068
9961
15861
0
57
-------
MASSES OF CERCLA ORGANICS IN WASTEWATER AND SLUDGE
STREAMS - ACCLIMATED SYSTEM DATA SET 4
COMPOUNDS
-
1
IDICHLOROBENZENE, PROBABLY 1,2
IDICHLOROBENZENE, PROBABLY 1,3
IDICHLOROBENZENE, PROBABLY 1,4
(1,2,4-TRICHLOROBENZENE
(NITROBENZENE
|1,3-D1NITROBENZENE
2,6-DlNlTROTOLUENE
IP-CRESOL
I4-CHI.OROANILINE
IHEXACHLOROETHANE
| HEXACHLOROBUTAO I ENE
(DIMETHYL PHTHALATE
IDIETHYL PHTHALATE
IDIBUTYL PHTHALATE
| BUTYL BENZYL PHTHALATE
|BIS(2-ETHYLHEXYL)PHTHALATE
| NAPHTHALENE
LINDANE
IDIELDRIN
I
PR I
INF
CMS
70.3
71.9
73.9
100.7
72.4
37.4
73.8
106.5
63.7
50.5
73.1
86.1
89.3
80.3
76.2
127.5
82.4
81.2
59.4
PR I
EFF
CMS
60.
52.
64.
77.
79.
46.
91.
17.
48.
53.
87.
75.
54.
45.
59.
71.
67.
7
1
4
5
5
7
1
7
2
9
6
2
5
6
8
1
8
SEC
EFF
CMS
8.
17.
3.
34.
6.
3.
47.
11.
0.
0.
12.
0.
0.
11.
11.
65.
2.
0.
15.
0
0
1
2
8
9
0
5
0
1
6
3
5
3
1
6
9
0
9
SEC
WAS
CMS
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
0
0
0
1
0
0
0
0
0
0
1
0
0
0
0
4
0
1
0
SEC
WAS
(DUP
CMS
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
)
0
0
0
1
0
0
0
0
0
0
1
0
0
0
0
5
0
1
5
PR I
WAS
CMS
15.0
14.7
13.6
36.2
0.2
0.0
0.1
2.5
1.0
0.0
41.8
0.6
1.3
28.1
36.3
60.2
13.5
22.2
0.0
PR I
WAS
(DUP)
CMS
12.9
12.4
11.8
34.6
0.1
0.5
0.0
2.0
0.9
0.0
36.9
0.5
1.1
22.9
30.2
54.5
11.5
18.4
0.0
58
-------
REMOVAL AND PARTITIONING OF CERCLA ORGANICS DURING
^TREATMENT - ACCLIMATED SYSTEM DATA SET 4
COMPOUNDS
I I
(PRIMARY TOTAL ADSORBED BIO*STRIP|
(REMOVAL REMOVAL +CHE.TRAN|
1
1
(DICHLOROBENZENE, PROBABLY 1,2
(DICHLOROBENZENE, PROBABLY 1,3
(DICHLOROBENZENE, PROBABLY i,«
| 1 ,2,4-TRICHLOROBENZENE
(NITROBENZENE
(1,3-DINITROBENZENE
|2,6-DINITROTOLUENE
IP-CRESOL
(4-CHLOROANiLiNE
(HEXACHLOROETHANE
IHEXACHLOROBUTADIENE
(DIMETHYL PHTHALATE
(DIETHYL PHTHALATE
(DIBUTYL PHTHALATE
(BUTYL BENZYL PHTHALATE
|BIS(2-ETHYLHEXYL)PHTHALATE
(NAPHTHALENE
(LINDANE
(DIELDRIN
I
13.8
27.5
12.8
23.1
-9.7
36.7
14.5
72.3
4.4
26.2
-1.7
15.8
32.2
40.1
53.1
13.7
16.5
88.6
76.3
95.8
66.1
90.6
89.6
36.4
89.2
100.0
99.7
82.7
99.6
99.4
85.9
85.5
48.6
96.5
73.2
19.9
18.8
17.2
35.2
0.2
*
*
2.2
*
0.0
*
0.7
1.4
31.7
43.7
45.3
15.2
*
*
68.8
57.5
78.6
30.8
90.4
*
*
87.1
«
99.7
*
99.0
98.0
54.2
41.8
3.2
81.3
*
*
Partitioning not calculated because of inconsistent data
59
-------
CONCENTRATIONS OF CERCLA ORGANICS IN WASTEWATER AND
SLUDGE SAMPLES - ACCLIMATED SYSTEM DATA SET 5
Compounds
-
IDICHLOROBEKZENE, PROBABLY 1,2
(DICHLOROBENZENE, PROBABLY 1,3
IDICHLOROBENZENE, PROBABLY 1,4
| 1 , 2 , 4 - TR I CH LOROBENZENE
INITROBENZENE
1 1, 3-D I NITROBENZENE
|2,6-DINITROTOLUENE
IP-CRESOL
|4-CHOLOROANIL1NE
IHEXACHLOROETHANE
| HEXACHLOROBUT AD I ENE
[DIMETHYL PHTHALATE
|D I ETHYL PHTHALATE
IDIBUTYL PHTHALATE
| BUTYL BENZYL PHTHALATE
IBISCZ-ETHYLHEXYDPHTHALATE
(NAPHTHALENE
ILINOANE
IDIELDRIN
I
CONCENTRATION
RUW
PR I
INF
PR I
INF
PR I
EFF
OF TOXICS
SEC
EFF
SEC
WAS
PR I
WAS
(DUP)
UG/L
12.4
15.9
11.9
163.3
0.0
234.2
0.0
33.6
3.9
0.0
40.8
0.0
8.0
24.7
23.9
19. r
12.0
166.6
UG/L
383
386
398
556
385
327
395
505
333
333
413
422
476
441
461
504
451
324
.1
.3
.1
.3
.0
.5
.8
.4
.7
.5
.9
.2
.2
.7
.3
.4
.6
.6
UG/L
351.
355.
350.
470.
409.
311.
398.
493.
305.
310.
341.
412.
433.
493.
365.
447.
397.
260.
7
5
1
7
2
7
5
2
2
1
3
8
2
6
1
7
9
9
UG/L
331.
326.
334.
379.
342.
111.
270.
539.
326.
198.
180.
421.
423.
243.
190.
441.
326.
150.
1
2
1
4
9
2
8
4
8
6
6
2
0
0
2
8
5
4
UG/L
16.
35.
5.
78.
25.
9.
125.
203.
0.
1.
7.
4.
5.
1
7
9
4
1
9
6
3
0
0
3
6
5
5.8
2.9
4.8
328.
7
33.6
UG/L
95
219
22
1490
48
1581
243
31
61
18
804
24
42
195
180
20
2160
9785
UG/L
3721
3370
3154
13487
43
988
15
1156
507
0
14089
311
539
9729
11237
4451
5012
3831
60
-------
MASSES OF CERCLA ORGANICS IN WASTEWATER AND SLUDGE
STREAMS - ACCLIMATED SYSTEM DATA SET 5
Compounds
(DICHLOROBENZENE, PROBABLY 1,2
IDICHLOROBENZENE, PROBABLY 1,3
IDICHLOROBENZENE, PROBABLY 1,4
(1,2.4-TRlCHLOROBENZENE
| NITROBENZENE
| 1 ,3-DINITROBENZENE
(2.6-DINITROTOLUENE
IP-CRESOL
(4-CHOLOROANILINE
IHEXACHLOROETHANE
IHEXACHLOROBUTAOIENE
(DIMETHYL PHTHALATE
IDIETHYL PHTHALATE
IOIBUTYL PHTHALATE
| BUTYL BENZYL PHTHALATE
|BIS(2-ETHYLHEXYL)PHTHALATE
(NAPHTHALENE
ILINDANE
(DIELDRIN
I
I
| PRI
| INF
I
| CMS
.1
1
(146
.2
(H7.4
1151
(212
(146
1 4-57
|124
1151
(192
1127
.9
.2
.9
.0
.8
.3
(127.2
1157
(161
(181
(168
(176
I
(192
1172
|123
.9
.1
.7
.5
.0
.5
.3
.9
PRI
INF
-------
REMOVAL AND PARTITIONING OF CERCLA ORGANICS DURING
TREATMENT - ACCLIMATED SYSTEM DATA SET 5
Compounds
(PRIMARY TOTAL ADSORBED BIO+STRJP||
|REMOVAL REMOVAL +CHE.TRAM||
1
IDICHLOROBENZENE, PROBABLY 1,2
IDICHLOROBENZENE, PROBABLY 1,3
IDICHLOROBENZENE. PROBABLY 1,4
| 1 , 2 , 4 - TR I CHLOROBENZENE
(NITROBENZENE
|1,3-DINITROBENZENE
|2,6-DINITROTOLUENE
IP-CRESOL
(4-CHOLOROANILINE
IHEXACHLOROETHANE
IHEXACHLOROBUTADIENE
(DIMETHYL PHTHALATE
IDIETHYL PHTHALATE
IDIBUTYL PHTHALATE
| BUTYL BENZYL PHTHALATE
|BIS(2-ETHYLHEXYL)PHTHALATE
(NAPHTHALENE
(LINOANE
(DIELDRIN
I
9.
12.
10.
26.
13.
65.
31.
-8.
-2.
38.
52.
-0.
7.
48.
54.
7.
23.
48.
9
0
7
1
6
2
8
0
3
3
2
9
0
1
0
2
1
6
95
90
98
84
93
96
68
59
100
99
98
98
98
98
99
99
22
88
.6
.4
.4
.7
.7
.9
.4
.3
.0
.7
.1
.9
.8
.8
.3
.0
.6
.5
6.
6.
5.
19.
0.
*
*
1.
1.
*
4
0.
0.
•
*
5.
12.
43.
4
1
2
1
2
5
2
5
8
7
6
8
89
84
93
65
93
57
98
98
98
93
10
44
.2
.2
.2
.7
.5
*
*
.8
.8
*
*
.4
.0
*
it
.3
.0
.8
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
Partitioning not calculated because of inconsistent data
62
-------
CONCENTRATIONS OF CERCLA ORGANICS IN WASTEWATER AND
SLUDGE SAMPLES - ACCLIMATED SYSTEM DATA SET 6
| | CONCENTRATION
COMPOUNDS
II
|| RWU
II
II
| | UG/L
II
DICHLOROBEHZENE, PROBABLY 1,2
DICHLOROBENZENE, PROBABLY 1,3
OICHLOROBENZENE, PROBABLY 1,4
1 , 2 , 4 - TR I CHLOROBENZENE
NITROBENZENE
1,3-OINITROBENZENE
(2.6-DINITROTOLUENE
P-CRESOL
4-CHLOROANILINE
IHEXACHLOROETHANE
HEXACHLOROBUTADIENE
[DIMETHYL PHTHALATE
IDIETHYL PHTHALATE
D I BUTYL PHTHALATE
BUTYL BENZYL PHTHALATE
BIS(2-ETHYLHEXYL)PHTHALATE
NAPHTHALENE
LINDANE
D1ELDRIN
II
II 1-
II 3.
II 7.
||137.
II 0-
II o.
II o.
II 46.
II *•
II 0-
II 5.
II 13-
II 21.
II 38.
II 35.
II
|| 13.
II 6.
II o.
8
8
9
5
0
0
0
5
9
0
7
5
7
7
8
1
6
0
PR1
INF
UG/L
377.5
385.6
380.7
573.0
417.7
258.3
397.1
506.1
314.7
344.4
412.3
431.3
437.9
409.7
393.5
448.0
439.1
1272.5
PR I
INF
(DUP)
UG/L
344.9
341.2
351.3
531.2
396.2
268.6
393.3
472.1
302.5
324.1
363.1
420.5
425.0
394.1
349.5
389.8
409.9
1209.2
PR I
EFF
UG/L
307.3
313.7
313.6
410.2
358.9
62.8
258.9
542.1
312.6
206.5
215.1
444.6
440.6
257.2
206.7
391.5
347.8
243.0
OF TOXICS
SEC
EFF
UG/L
21.
41.
8.
81.
23.
5.
128.
238.
134.
2.
7.
8.
10.
11.
8.
5.
276.
70.
8
8
4
3
8
6
7
7
7
9
8
3
0
3
6
3
1
4
SEC
EFF
(DUP)
UG/L
17.1
36.7
4.5
75.8
20.4
6.6
125.4
93.6
3.5
5.0
1.3
2.8
7.8
6.5
1.2
261.8
63.4
SEC
WAS
UG/L
639
592
201
2927
151
881
492
100
242
288
2428
125
169
786
707
129
4417
29762
SEC
WAS
(DUP)
UG/L
264
492
91
2800
84
1162
445
20
162
0
2326
39
95
649
548
68
4279
13776
PR I
WAS
UG/L
I
I
19838 |
18109 |
16626
63363
120
0
86
1084
1289 |
28 |
60516 1
444 |
1070
35944 |
38555 |
17363 |
25606
0
63
-------
MASSES OF CERCLA ORGANICS IN WASTEWATER AND SLUDGE
STREAMS - ACCLIMATED SYSTEM DATA SET 6
1
1
| COMPOUNDS
1
1
1
1
1
IDICHLOROBENZENE, PROBABLY 1,2
IDICHLOROBENZENE, PROBABLY 1,3
IDICHLOROBENZENE, PROBABLY 1,4
(1,2,4-TRICHLOROBENZENE
(NITROBENZENE
|1,3-DINITROBENZENE
|2,6-D1NITROTOLUENE
IP-CRESOL
|4-CHLOROANIL1NE
IHEXACHLOROETHANE
| HEXACHLOftOBUTAD I ENE
IDIMETHYL PHTHALATE
|D I ETHYL PHTHALATE
IOIBUTYL PHTHALATE
| BUTYL BENZYL PHTHALATE
|BIS(2-ETHYLHEXYL)PHTHALATE
(NAPHTHALENE
ILINDANE
IDIELDRIN
II
II
II
II
II
II
(I
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
PR
IN
Q
72
73
72
109
79
49
75
96
60
65
78
82
83
78
75
85
83
242
I
f
MS
.0
.6
.6
.3
.7
.3
.8
.5
.0
.7
.7
.3
.5
.2
.1
.5
.8
.7
PR I
INF
(DUP)
CMS
65.8
65.1
67.0
101.3
75.6
51.2
75.0
90.1
57.7
61.8
69.3
80.2
81.1
75.2
66.7
74.4
78.2
230.7
HASS OF
PR I
EFF
CMS
58.6
59.8
59.8
78.3
68.5
12.0
49.4
103.4
59.6
39.4
41.0
84.8
84.1
49.1
39.4
74.7
66.3
46.4
TOXIC
SEC
EFF
CMS
4.2
8.0
1.6
15.5
4.5
1.1
24.5
45.5
25.7
0.6
1.5
1.6
1.9
2.2
1.6
1.0
52.7
13.4
S
SEC
EFF
(DUP)
CMS
3.3
7.0
0.9
14.5
3.9
1.3
23.9
17.8
0.7
1.0
0.2
0.5
1.5
1.2
0.2
49.9
12.1
SEC
WAS
CMS
1.3
1.2
0.4
6.0
0.3
1.8
1.0
0.2
0.5
0.6
5.0
0.3
0.3
1.6
1.4
0.3
9.0
60.8
SEC
WAS
(DUP
GM
0.
1.
0.
5.
0.
2.
0.
0.
0.
0.
4.
0.
0.
1.
1.
0.
8.
28.
)
S
5
0
2
7
2
4
9
0
3
0
8
1
2
3
1
1
7
2
II
II
PR! ||
WAS ||
I
QMS ||
II
II
23.0 ||
21.0 ||
19.3 ||
73.4
0.1
0.0
0.1
1.3
1.5
0.0
70.1
0.5
1.2
41.6
44.6
20.1
29.7 |
0.0 |
64
-------
REMOVAL AND PARTITIONING OF CERCLA ORGANICS DURING
TREATMENT - ACCLIMATED SYSTEM DATA SET 6
1
1
| COMPOUNDS
1
1
1
1
1
IDICHLOROBENZENE, PROBABLY 1,2
IDICHLOROBENZENE, PROBABLY 1,3
IDICHLOROBENZENE, PROBABLY 1,4
| 1 , 2 , 4 - TR I CHLOROBENZENE
| NITROBENZENE
|1,3-DINITROBENZENE
|2,6-DINITROTOLUENE
IP-CRESOL
(4-CHLOROANILINE
IHEXACHLOROETHANE
| HEXACHLOROBUT AD I ENE
(DIMETHYL PHTHALATE
|DI ETHYL PHTHALATE
IOIBUTYL PHTHALATE
| BUTYL BENZYL PHTHALATE
|BIS(2-ETHYLHEXYL)PHTHALATE
(NAPHTHALENE
ILINDANE
IDIELDRIN
I
I
I *
(PRIMARY
(REMOVAL
I
| U.9
13.7
U.3
25.7
11.8
76.2
34.5
-10.8
-1.3
38.2
44. 5
-4.4
-2.1
36.0
44.4
6.5
18.1
80.4
X
TOTAL
REMOVAL
94.6
89.2
98.2
85.8
94.6
97.7
67.9
75.6
63.0
99.0
98.3
98.9
98.5
97.6
98.0
99.2
36.6
94.6
X
ADSORBED
34.7
31.9
28.0
*
0.5
*
*
1.5
3.2
*
*
0.8
1.8
56.2
64.8
25.4
47.6
*
I
X I
I
I
BIO+STRIP)
+CHE.TRAN)
59.9
57.4
70.2
*
94.1
*
*
74.1
59.8
*
*
98.0
96.7 |
41.4 |
33.2 |
I
73.8 |
-10.9 |
• I
I
* Partitioning not calculated because of inconsistent data
65
-------
CONCENTRATIONS OF -CERCLA ORGANICS IN WASTEWATER AND
SLUDGE SAMPLES - ACCLIMATED SYSTEM DATA SET 7
COMPOUNDS
IOICHLOROBENZENE, PROBABLY 1,2
IOICHLOROBENZENE, PROBABLY 1,3
IDICHLOROBENZENE, PROBABLY 1.4
1 1 ,2,4-TRICHLOROBENZENE
| NITROBENZENE
11.3-OINITROBENZENE
|2,6-DINITROTOLUENE
IP-CRESOL
|4-CHLOROANIL!NE
IHEXACHLOROETHANE
IHEXACHLOROBUTAOIENE
| DIMETHYL PHTHALATE
IDIETHYL PHTHALATE
|DI BUTYL PHTHALATE
| BUTYL BENZYL PHTHALATE
|BIS(2-ETHYLHEXYL)PHTHALATE
(NAPHTHALENE
ILINOANE
(DIELDRIN
II
II
II RUU
II
II
|| UG/L
II
II
II
II 20
II 23
II 205
II
II
II 55
I
I
I 16
I W
I
I 15
II 38
II 22
II
II 26
II
II 389
.7
.6
.4
.8
.7
.7
.4
.9
.0
.6
.2
PR I
INF
UG/L
356.3
340.3
489.8
288.5
298.5
350.0
479.8
443.4
387.3
365.5
604.2
CONCENTRATION OF TOXICS
PR I SEC SEC PR I
EFF EFF WAS WAS
UG/L UG/L UG/L UG/L
344
368
409
261
239
250
517
310
252
391
227
.3
.3
.7
.7
.6
.4
.7
.7
.8
.9
.3
44
10
82
136
18
13
16
17
11
11
137
.7
.9
.5
.5
.7
.1
.0
.5
.1
.3
.0
475
79
2314
6051
701
3119
85
408
275
101
21153
11160
14340
39545
159
224
61744
1225
29614
39012
14294
8045
PR I
WAS
(DUP)
UG/L
16731
17359
40792
0
0
68713
1694
34765
40347
16256
9784
II
II
II
I
I
I
I
II
I
66
-------
MASSES OF.CERCLA ORGANICS IN WASTEWATER AND SLUDGE
STREAMS - ACCLIMATED SYSTEM DATA SET 7
II
1
II wi
COMPOUNDS || INF
II
II GHS
II
II
|D I CHLOROBENZENE, PROBABLY 1,2 ||
IDICHLOROBENZENE, PROBABLY 1,3
|D I CHLOROBENZENE, PROBABLY 1,4
| 1 , 2 , 4 - TR I CHLOROBENZENE
| NITROBENZENE
|1,3-DINITROBENZENE
|2,6-DINITROTOLUENE
IP-CRESOL
K-CHLOROANILINE
IHEXACHLOROETHANE
IHEXACHLOROBUTADIENE
IDINETHYL PHTHALATE
IDIETHYL PHTHALATE
|D I BUTYL PHTHALATE
| BUTYL BENZYL PHTHALATE
| B I S(2-ETHYLHEXYL )PHTHALATE
NAPHTHALENE
ILINDANE
IOIELDRIN
68.0
64.9
93.4
55.0
56.9
66.8
91.5
84.6
73.9
69.7
|115.3
MASS
PR I
EFF
CMS
65.7
70.3
78.2
49.9
45.7
47.8
98.8
59.3
48.2
74.8
43.4
OF TOXICS
SEC
EFF
CMS
8.5
2.1
15.7
26.0
3.6
2.5
3.1
3.3
2.1
2.1
26.1
SEC
WAS
CMS
1.0
0.2
4.7
12.4
1.4
6.4
0.2
0.8
0.6
0.2
43.2
PR I
WAS
CMS
12.9
16.6
45.8
0.2
0.3
71.5
1.4
34.3
45.2
16.6
9.3
PR I
WAS
(DUP)
CMS
19.4
20.1
47.2
0.0
0.0
79.6
2.0
40.3
46.7
18.8
11.3
67
-------
REMOVAL AND PARTITIONING OF CERCLA ORGANICS DURING
TREATMENT - ACCLIMATED SYSTEM DATA SET 7
1
COMPOUNDS |
1
1
1
1
IDICHLOROBENZENE, PROBABLY 1,2 |
IDICHLOROBENZENE, PROBABLY 1,3 |
IDICHLOROBENZENE, PROBABLY 1,4 |
|1,2.4-TRICHLOROBENZENE |
(NITROBENZENE
|1,3-DINITROBENZENE
|2,6-D1NITROTOLUENE
IP-CRESOL
|4-CHLOROANiLiNE
IHEXACHLOROETHANE
| HEXACHLOROBUTADIENE
IDIHETHYL PHTHALATE
IDIETHYL PHTHALATE
| DI BUTYL PHTHALATE
(BUTYL BENZYL PHTHALATE
|BIS(2-ETHYLHEXYL)PHTHALATE
| NAPHTHALENE
(LINDANE
(DIELDRIN
I
I
I «
i
1
1
(PRIMARY
(REMOVAL
1
1 3.3
| -8.2
| 16.4
9.3
19.7
28.5
-7.9
29.9
34.7
-7.2
62.4
X X
TOTAL ADSORBED
REMOVAL
87.5 *
96.8 *
83.1 *
52.7 22.6
93.7 •
96.2
96.7 2.0
96.1 45.1
97.1 •
96.9 *
77.3 *
I
* 1
1
B I CM-STRIP |
+CHE.TRANJ
1
1
1
" 1
* 1
* 1
1
1
30.0 |
1
1
• 1
* 1
1
94.6 (1
51.0 ||
* II
II
• II
II
• II
I!
* Partitioning not calculated because of inconsistent data
68
-------
CONCENTRATIONS OF CERCLA ORGANICS IN WASTEWATER AND
SLUDGE SAMPLES - ACCLIMATED SYSTEM DATA SET 8
COMPOUNDS
DICHLOROBENZENE, PROBABLY 1,2
IDICHLOROBENZENE, PROBABLY 1,3
DICHLOROBENZENE, PROBABLY 1,4
1.2.4-TRICHLOROBENZENE
NITROBENZENE
1,3-DINITROBENZENE
2,6-DINITROTOLUENE
P-CRESOL
4-CHLOROANILINE
HEXACHLOROETHANE
HEXACHLOROBUTAD I ENE
DIMETHYL PHTHALATE
D I ETHYL PHTHALATE
D I BUTYL PHTHALATE
BUTYL BENZYL PHTHALATE
RWU
UG/L
4
15
9
249
3
0
0
31
7
0
5
4
11
31
26
BIS(2-ETHYLHEXYL)PHTHALATE ||7003
NAPHTHALENE | | 22
LINDANE || 9
OIELDRIN || 21
II
.5
.1
.6
.0
.1
.0
.0
.0
.9
.0
.6
.3
.2
.7
.4
.4
.3
.6
.2
PR I
INF
UG/L
335.
393.
386.
688.
415.
244.
375.
485.
191.
373.
364.
466.
499.
392.
359.
1675.
344.
403.
354.
5
8
7
3
1
7
0
1
5
9
1
6
0
6
8
1
7
5
6
CONCENTRATION
PRI PRI
INF EFF
(DUP)
UG/L
384.
443.
435.
728.
460.
316.
531.
197.
399.
484.
525.
418.
365.
1096.
382.
432.
4
3
4
2
0
0
3
3
2
5
7
8
2
6
7
0
UG/L
313.8
367.7
357.8
527.3
383.0
58.4
276.2
565.0
222.0
219.3
222.0
481.6
533.0
255.2
209.0
955.2
314.8
339.6
207.4
OF TOXICS
SEC SEC
EFF WAS
UG/L
11.2
33.7
5.7
76.7
25.8
8.2
140.9
227.7
116.5
6.2
8.3
7.8
11.4
9.9
5.7
378.5
5.3
12.6
107.0
UG/L
147
381
68
1987
0
1214
0
0
42
0
1813
0
62
594
324
60475
77
148
5471
SEC
WAS
(DUP)
UG/L
94
277
51
2063
0
1387
0
0
40
0
1826
0
0
932
863
46800
74
366
9756
PRI
UAS
UG/L
14040
13713
11974
46986
182
1287
0
1837
493
205
45308
420
1252
31584
34843
81647
11462
18066
15963
69
-------
MASSES OF CERCL'A ORGANICS IN WASTEWATER AND SLUDGE
STREAMS - ACCLIMATED SYSTEM DATA SET 8
1
1
| COMPOUNDS
1
1
1
1
1
IDICHLOROBENZENE, PROBABLY 1,2
IDICHLOROBENZENE, PROBABLY 1,3
IDICHLOROBENZENE, PROBABLY 1,4
| 1,2,4-TRICHLOROBENZENE
(NITROBENZENE
(1,3-DINITROBENZENE
| 2,6-DINITROTOLUENE
IP-CRESOL
(4-CHLOROANILINE
IHEXACHLOROETHANE
| HEXACHLOROBUTAD I ENE
(DIMETHYL PHTHALATE
(DIETHYL PHTHALATE
(DIBUTYL PHTHALATE
| BUTYL BENZYL PHTHALATE
|BIS(2-ETHYLHEXYL)PHTHALATE
(NAPHTHALENE
ILINDANE
IDIELDRIN
I
II
II
II IMF
II
II «
II
II
II 64.
II 75.
II 73.
||131.
II 79.
II ".
II 71.
II 92.
II 36.
II 71.
II 69.
II 89.
II 95.
II 74.
II 68.
| (319.
II 65.
II 77.
II 67.
II
MASS OF
PRI PRI
INF EFF
(DUP)
S CMS CMS
0
1
8
3
2
7
5
5
5
3
5
0
2
9
6
6
8
0
6
73.
84.
83.
138.
87.
60.
101.
37.
76.
92.
100.
79.
69.
209.
73.
82.
3
6
1
9
8
3
4
6
2
4
3
9
7
2
0
4
59
70
68
100
73
11
52
107
42
41
42
91
101
48
39
182
60
64
39
.9
.2
.3
.6
.1
.1
.7
.8
.3
.8
.3
.9
.7
.7
.9
.2
.0
.8
.6
TOXICS
SEC
EFF
CMS
2
6
1
14
4
1
26
43
22
1
1
1
2
1
1
72
1
2
20
.1
.4
.1
.6
.9
.6
.9
.4
.2
.2
.6
.5
.2
.9
.1
.2
.0
.4
.4
SEC
WAS
CMS
0.3
0.8
0.1
4.1
0.0
2.5
0.0
0.0
0.1
0.0
3.7
0.0
0.1
1.2
0.7
123.6
0.2
0.3
11.2
SEC
WAS
(DUP)
CMS
0.2
0.6
0.1
4.2
0.0
2.8
0.0
0.0
0.1
0.0
3.7
0.0
0.0
1.9
1.8
95.7
0.2
0.7
19.9
II
II
PRI ||
WAS ||
II
CMS ||
II
16.3 ||
15.9 ||
13.9 ||
54.4 ||
0.2
1.5
0.0
2.1
0.6
0.2
52.5
0.5
1.4
36.6
40.3
94.5
13.3
20.9
18.5
70
-------
REMOVAL AND PARTITIONING OF CERCLA ORGANICS DURING
TREATMENT - ACCLIMATED SYSTEM DATA SET 8
COMPOUNDS
"_
[DICHLOROBENZENE, PROBABLY 1.2
IOICHLOROBENZENE, PROBABLY 1,3
IDICHLOROBENZENE, PROBABLY 1,4 |
|1,2,4-TR1CHLOROBENZENE |
(NITROBENZENE
|1,3-D1NITROBENZENE
|2,6-OIN1TROTOLUENE
IP-CRESOL
14-CHLOROANILINE
| HEXACHLOROETHANE
| HEXACHLOROBUTAD I ENE
(DIMETHYL PHTHALATE
IDIETHYL PHTHALATE
(DIBUTYL PHTHALATE
(BUTYL BENZYL PHTHALATE
|BIS(2-ETHYLHEXYL)PHTHALATE
(NAPHTHALENE
ILINDANE
IDIELDRIN
1
1
X
1
1
(PRIMARY
(REMOVAL
1
1
12.8
12.1
| 13.0
| 25.5
12.5
79.2
26.3
-11.2
-U.2
41.3
41.8
-1.3
-4.0
37.1
42.3
31.1
13.5
18.7
41.5
X
TOTAL
REMOVAL
96.9
92.0
98.6
89.2
94.1
97.1
62.4
55.2
40.1
98.4
97.8
98.4
97.8
97.6
98.4
72.7
98.5
97.0
69.8
X
ADSORBED
24.0
20.7
17.8
43.3
0.3
*
*
2.2
1.8
•
*
0.5
1.5
49.3
60.1
77.2
19.4
26.9
50.3
I
« I
I
I
BIO+STRIP)
+CHE.TRAN)
I
72.9
71.2
80.8
45.8
93.9
*
*
53.0
38.3
*
*
97.8
96.2
48.3
38.3
-4.5
79.2
70.1 ||
19.5 ||
II
Partitioning not calculated because of inconsistent data
71
-------
CONCENTRATIONS OF CERCLA ORGANICS IN WASTEWATER AND
• -SUJDGE SAMPLES - ACCLIMATED SYSTEM DATA SET 9
1
| COMPOUNDS
|
|
I
i
1
IDICHLOROBENZENE, PROBABLY 1,2
IDICHLOROBENZENE, PROBABLY 1,3
IDICHLOROBENZENE, PROBABLY 1,4
|1,2,4-TRtCHLOROBENZENE
[NITROBENZENE
|1,3-D1NITROBENZENE
|2,6-DINITROTOLUENE
IP-CRESOL
[4-CHLOROANILINE
IHEXACHLOROETHAME
IHEXACHLOROBUTAOIENE
IDIMETHYL PHTHALATE
(DIETHYL PHTHALATE
(DIBUTYL PHTHALATE
| BUTYL BENZYL PHTHALATE
|BIS(2-ETHYLHEXYL)PHTHALATE
(NAPHTHALENE
ILINDANE
CONCENTRATION
RWU
RWU
PR I
INF
UG/L
28
34
27
945
39
26
15
93
8
15
91
97
46
31
IDIELORIN |471
I I
.6
.2
.5
.6
.9
.4
.6
.0
.4
.1
.3
.9
.9
.7
.0
UG/L
28.8
30.0
29.3
929.4
25.0
46.2
15.3
92.3
9.9
16.5
89.2
93.8
52.0
32.4
203.08
UG/L
310.
428.
399.
833.
508.
498.
380.
426.
1604.
550.
433.
423.
396.
476.
387.
5
6
7
7
3
2
7
8
8
7
5
6
1
2
3
PR I
INF
(OUP)
UG/L
326.3
339.7
389.2
690.3
486.2
484.4
333.6
412.9
1506.9
538.3
399.8
402.1
383.9
430.8
OF TOXICS
PR I
EFF
UG/L
300.6
305.5
374.1
525.5
541.1
548.1
257.9
291.3
1574.5
533.5
315.2
291.6
365.5
378.6
234.72
SEC
EFF
UG/L
15.4
36.5
11.8
90.0
25.3
196.9
18.6
13.1
53.9
19.5
16.4
13.5
11.5
18.1
57.26
SEC
WAS
UG/L
436
668
339
3730
50
71
0
3806
44
140
997
1144
274
535
4654
PR I
WAS
UG/L
10470
10854
9661
35593
161
1721
0
32523
537
1115
24084
27174
9225
15499
37408
PR I
WAS
(DUP)
UG/L
12350
12885
11437
42202
236
1874
204
39463
649
1393
28646
32748
10929
17491
72
-------
MASSES'OF CERCLA ORGANICS IN WASTEWATER AND SLUDGE
STREAMS - ACCLIMATED SYSTEM DATA SET 9
COMPOUNDS
DICHLOROBENZENE, PROBABLY 1,2
DICHLOR08ENZENE, PROBABLY 1,3
DICHLOROBENZENE, PROBABLY 1,4
1,2,4-TRICHLOROBENZENE
NITROBENZENE
1,3-DINITROBENZENE
2,6-DINITROTOLUENE
P-CRESOL
4-CHLOROANILINE
HEXACHLOROETHANE
HEXACHLOROBUTADIENE
PR I
INF
PR I
INF
(DUP)
CMS
59.
81.
76.
159.
97.
95.
72.
81.
DIMETHYL PHTHALATE |306.
01 ETHYL PHTHALATE (105.
D I BUTYL PHTHALATE | 82.
BUTYL BENZYL PHTHALATE | 80.
BIS(2-ETHYLHEXYL)PHTHALATE |
NAPHTHALENE | 75.
LINDANE | 90.
DIELDRIN | 73.
2
8
3
0
0
0
6
4
1
1
7
8
6
8
9
CMS
62
64
74
131
92
92
63
78
287
102
76
76
73
82
.2
.8
.3
.7
.8
.4
.6
.8
.5
.7
.3
.7
.2
.2
MASS OF TOXICS
PR I SEC SEC
EFF EFF WAS
CMS
57.3
58.3
71.4
100.2
103.2
104.6
49.2
55.6
300.4
101.8
60.1
55.6
69.7
72.2
44.8
CMS
2.9
7.0
2.3
17.2
4.8
37.6
3.5
2.5
10.3
3.7
3.1
2.6
2.2
3.5
10.9
CMS
0.9
1.4
0.7
7.6
0.1
0.1
0.0
7.8
0.1
0.3
2.0
2.3
0.6
1.1
9.5
PR I
WAS
CMS
12.
12.
11.
41.
0.
2.
0.
37.
0.
1.
27.
31.
10.
17.
43.
1
6
2
2
2
0
0
7
6
3
9
5
7
9
3
PR I
WAS
(DUP)
CMS
14
14
13
48
0
2
0
45
0
1
33
37
12
20
.3
.9
.2
.9
.3
.2
.2
.7
.8
.6
.2
.9
.7
.3
73
-------
REMOVAL AND PARTITIONING OF CERCLA ORGANICS DURING
TREATMENT - ACCLIMATED SYSTEM DATA SET 9
1
1
| COMPOUNDS
1
1
1
1
1
IDICHLOROBENZENE, PROBABLY 1,2
IDICHLOROBENZENE, PROBABLY 1,3
IDICHLOROBENZENE, PROBABLY 1.4
(1,2,4-TRICHLOROBENZENE
(NITROBENZENE
|1,5-DINITROBENZENE
|2,6-DINITROTOLUENE
IP-CRESOL
(4-CHLOROANILINE
IHEXACHLOROETHANE
| HEXACHLOROBUTAD I ENE
(DIMETHYL PHTHALATE
IDIETHYL PHTHALATE
IDIBUTYL PHTHALATE
| BUTYL BENZYL PHTHALATE
|BIS(2-ETHYLHEXYL)PHTHALATE
(NAPHTHALENE
(LINDANE
IOIELDRIN
I
x
PRIMARY
REMOVAL
5.6
20.5
5.2
31.0
-8.8
-11.6
27.8
30.6
-1.2
2.0
24. A
29.4
6.3
16.5
39.4
X
TOTAL
REMOVAL
95.2
90.5
97.0
88.2
94.9
59.9
94.8
96.9
96.5
96.4
96.1
96.7
97.0
96.0
85.2
X
ADSORBED
23.2
20.6
17.2
36.2
0.3
2.4
*
61.8
0.3
1.7
41.0
47.0
16.4
23.3
71.5
I
X
BIO+STRIP)
+CHE.TRAN)
72.0
69.9
79.9
52.0
94.6
57.5
*
35.1
96.3
94.8
55.1
49.7
80.6
72.7
13.7
* Partitioning not calculated because of inconsistent data
74
-------
CONCENTRATIONS OF CERCLA ORGANICS IN WASTEWATER AND
SLUDGE SAMPLES - ACCLIMATED SYSTEM DATA SET 10
1
| COMPOUNDS
1
1
1
1
1
IDICHLOROBENZENE, PROBABLY 1,2
IDICHLOROBENZENE, PROBABLY 1,3
IDICHLOROBENZENE, PROBABLY 1,4
| 1 , 2 , 4 - TR I CHLOROBENZENE
[NITROBENZENE
|1,3-DINITROBENZENE
| 2,6-DINITROTOLUENE
IP-CRESOL
|4-CHLOROANILINE
IHEXACHLOROETHANE
| HEXACHLOROBUTAD I ENE
[DIMETHYL PHTHALATE
IDIETHYL PHTHALATE
IDIBUTYL PHTHALATE
| BUTYL BENZYL PHTHALATE
|BIS(2-ETHYLHEXYL)PHTHALATE
(NAPHTHALENE
ILINDANE
IDIELDRIN
I
CONCENTRATION
RUU
RWU
PR I
INF
PR I
EFF
(DUP)
UG/L
3
8
3
210
26
0
27
23
4
5
21
40
43
1861
13
7
148
.8
.1
.8
.7
.3
.0
.1
.6
.3
.1
.8
.0
.0
.1
.8
.4
.1
UG/L
5.
10.
5.
229.
9.
0.
3.
23.
14.
0.
21.
48.
52.
1845.
15.
7.
183.
3
1
1
5
0
0
5
3
2
3
8
7
1
1
1
6
5
UG/L
293.2
392.5
353.6
607.4
339.8
453.0
457.1
334.7
369.1
516.9
540.6
439.7
395.5
1368.6
349.7
285.9
831.7
UG/L
282.6
367.2
353.7
590.6
330.0
417.4
270.4
267.7
484.1
522.3
325.5
243.1
769.4
337.3
259.0
397.9
OF TOXICS
PR I
EFF
(DUP)
UG/L
319.1
367.8
373.0
618.0
326.2
556.9
425.0
273.1
283.7
489.4
571.3
353.8
272.1
431.0
352.3
271.4
348.4
SEC
EFF
UG/L
18
33
15
70
36
67
28
20
14
23
29
27
14
635
15
15
128
.2
.5
.4
.1
.4
.0
.7
.7
.1
.5
.6
.3
.0
.4
.6
.0
.9
SEC
WAS
UG/L
276
432
166
3297
469
437
0
603
1821
246
506
1026
331
32907
170
183
15842
PR I
WAS
UG/L
10898
11145
18547
48367
0
0
1682
0
61127
464
977
34655
36779
148862
0
15457
19250
75
-------
MASSES OF CERCLA ORGANICS IN WASTEWATER AND SLUDGE
STREAMS - ACCLIMATED SYSTEM DATA SET 10
1
1
| COMPOUNDS
1
1
1
1
1
IOICHLOROBENZENE, PROBABLY 1,2
IDICHLOROBENZENE, PROBABLY 1,3
IDICHLOROBENZENE, PROBABLY 1,4
| 1 , 2 , 4 - TR I CHLOROBENZENE
(NITROBENZENE
|1,3-D1NITROBENZENE
|2,6-DINITROTOLUENE
IP-CRESOL
|4-CHLOROANILINE
IHEXACHLOROETHANE
| HEXACHLOROBUTAOIENE
(DIMETHYL PHTHALATE
PR I
INF
CMS
55
74
67
115
64
86
87
63
70
98
IDIETHYL PHTHALATE |ios
|0 I BUTYL PHTHALATE
83
| BUTYL BENZYL PHTHALATE | 75
|BIS(2-ETHYLHEXYL)PHTHALATE |261
(NAPHTHALENE | 66
ILINDANE ( 54
(DIELDRIN (158
.9
.9
.5
.9
.8
.4
.2
.9
.4
.6
.1
.9
.4
.1
.7
.5
.7
MASS OF TOXICS
PR I PR I SEC
EFF EFF EFF
(OUP)
CMS
53
70
67
112
63
79
51
51
92
99
62
46
146
64
49
75
.9
.0
.5
.7
.0
.6
.6
.1
.3
.6
.1
.4
.8
.4
.4
.9
CMS
60.9
70.2
71
117
62
106
81
52
54
93
109
67
51
82
67
51
66
.2
.9
.2
.2
.1
.1
.1
.4
.0
.5
.9
.2
.2
.8
.5
CMS
3
6
2
13
6
12
5
3
2
4
5
5
2
121
3
2
24
.5
.4
.9
.4
.9
.8
.5
.9
.7
.5
.6
.2
.7
.2
.0
.9
.6
SEC
WAS
CMS
0.6
0.9
0.3
6.7
1.0
0.9
0.0
1.2
3.7
0.5
1.0
2.1
0.7
67.3
0.3
0.4
32.4
PR I
WAS
CMS
12
12
21
56
0
0
1
0
70
0
1
40
42
172
0
.6
.9
.5
.0
.0
.0
.9
.0
.8
.5
.1
.1
.6
.4
.0
17.9
22
.3
76
-------
REMOVAL AND PARTITIONING OF CERCLA ORGANICS DURING
TREATMENT - ACCLIMATED SYSTEM DATA SET 10
COMPOUNDS
I
I I
(PRIMARY TOTAL ADSORBED BIO+STRIP)
(REMOVAL REMOVAL +CHE.TRAN|
D I CHLOROBENZENE, PROBABLY 1,2
01 CHLOROBENZENE, PROBABLY 1,3
D I CHLOROBENZENE, PROBABLY 1,4
1,2, 4 -TR I CHLOROBENZENE
NITROBENZENE
1,3-DINITROBENZENE
2,6-DINITROTOLUENE
P-CRESOL
4-CHLOROANILINE
HEXACHLOROETHANE
HEXACHLOROBUTAOIENE
DIMETHYL PHTHALATE
D I ETHYL PHTHALATE
D I BUTYL PHTHALATE
BUTYL BENZYL PHTHALATE
BIS(2-ETHYLHEXYL)PHTHALATE
NAPHTHALENE
LINDANE
DIELDRIN
-2.6
6.4
-2.7
0.5
3.4
-23
7.8
18.8
25.3
5.8
-1.1
22.7
34.9
56.1
1.4
7.2
55.1
93.8
91.5
95.6
88.5
89.3
85.2
93.7
93.8
96.2
95.5
94.5
93.8
96.5
53.6
95.5
94.7
84.5
23.6
18.4
32.3
54.2
1.5
1.0
2.2
*
*
1.1
2.1
50.3
57.4
91.8
0.5
33.5
*
70.2
73.1
63.3
34.3
87.8
84.2
91.5
*
*
94.4
92.4
43.4
39.1
-38.2
95.0
61.2
*
Partitioning not calculated because of inconsistent data
77
-------
CONCENTRATIONS OF CERCLA ORGANICS IN WASTEWATER AND
•SLUDGE SAMPLES - ACCLIMATED SYSTEM DATA SET 11
1
1
1
| COMPOUNDS
1
1
1
1
1
IDICHLOROBENZENE, PROBABLY 1,2
IDICHLOROBENZENE, PROBABLY 1,3
IOICHLOROBENZENE, PROBABLY 1,4
(1,2,4-TRICHLOROBENZENE
| NITROBENZENE
|1,3-OINITROBENZENE
|2,6-DINITROTOLUENE
IP-CRESOL
I4-CHLOROANILINE
IHEXACHLOROETHANE
IHEXACHLOROBUTAOIENE
IOIHETHYL PHTHALATE
IOIETHYL PHTHALATE
IDIBUTYL PHTHALATE
| BUTYL BENZYL PHTHALATE
|BIS(2-ETHYLHEXYL)PHTHALATE
(NAPHTHALENE
ILINOANE
IOIELDRIN
I
CONCENTRATION
RUW
UG/L
2
4
3
875
0
50
0
40
3
.0
.2
.1
.1
.0
.0
.0
.1
.0
0.0
2
0
15
26
19
9
0
31
.7
.0
.1
.1
.4
.4
.0
.6
RWU
(DUP)
UG/L
10.3
13.3
13.4
1017.7
12.3
74.2
0.0
54.7
12.2
0.0
20.0
22.0
49.8
62.9
52.7
20.3
27.6
118.2
PR I
INF
UG/L
329.0
383.7
381.4
1235.4
447.4
258.3
438.2
531.2
361.8
389.1
462.3
505.6
566.0
453.8
431.0
415.3
423.3
775.0
PR I
INF
(OUP)
UG/L
329.7
375.5
386.9
1065.8
420.2
232.1
415.8
524.0
335.0
412.5
470.8
507.5
537.0
428.4
369.0
368.8
409.1
OF TOXICS
PR I
EFF
UG/L
305.6
365.2
357.1
537.9
348.8
43.2
322.4
585.9
347.4
273.0
323.8
468.7
544.5
327.2
281.4
372.9
364.1
526.0
SEC
EFF
UG/L
10.2
29.7
2.4
62.8
15.0
0.0
65.0
1.9
9.3
3.7
6.3
0.7
1.5
6.2
4.8
1.9
13.5
341.2
SEC
EFF
(DUP)
UG/L
11.0
33.2
3.1
69.8
13.0
0.0
67.4
5.1
8.1
4.6
8.6
2.9
5.0
10.0
9.6
2.6
15.5
139.8
SEC
WAS
UG/L
545
743
401
2888
21
1124
0
78
84
0
4560
0
92
1403
1665
348
648
15813
PR I
WAS
UG/L
19548
19556
17144
57977
615
525
1062
3079
1080
441
67210
1205
2177
38279
42946
16557
20011
44698
PR1
WAS
(DUP)
19564
20573
17123
60656
111
2120
0
2682
675
0
70940
597
1482
40274
49645
17266
22629
62436
78
-------
MASSES OF CERCLA ORGANICS IN WASTEWATER AND SLUDGE
----STREAMS - ACCLIMATED SYSTEM DATA SET 11
1
| COMPOUNDS
1
1
1
1
I
IDICHLOROBENZENE, PROBABLY 1,2
IDICHLOROBENZENE, PROBABLY 1,3
IDICHLOROBENZENE, PROBABLY 1,4
| 1 ,2,4-TRICHLOROBENZENE
(NITROBENZENE
1 1,3-DINITROBENZENE
|2,6-DINITROTOLUENE
IP-CRESOL
(4-CHLOROANILINE
IHEXACHLOROETHANE
IHEXACHLOROBUTADIENE
(DIMETHYL PHTHALATE
IDIETHYL PHTHALATE
IDIBUTYL PHTHALATE
| BUTYL BENZYL PHTHALATE
|BIS(2-ETHYLHEXYL)PHTHALATE
(NAPHTHALENE
(LINDANE
MASS OF TOXICS
PR I
INF
CMS
62
73
72
235
85
49
83
101
69
74
88
96
108
86
82
79
80
IDIELDRIN |147
I I
.8
.2
.7
.7
.4
.3
.6
.3
.0
.2
.2
.4
.0
.6
.2
.2
.8
.8
PR I
INF
(DUP)
CMS
62.9
71.6
73.8
203.3
80.2
44.3
79.3
100.0
63.9
78.7
89.8
96.8
102.4
81.7
70.4
70.3
78.0
PR I
EFF
CMS
58.3
69.7
68.1
102.6
66.5
8.2
61.5
111.8
66.3
52.1
61.8
89.4
103.9
62.4
53.7
71.1
69.5
100.3
SEC
EFF
CMS
1.9
5.7
0.5
12.0
2.9
0.0
12.4
0.4
1.8
0.7
1.2
0.1
0.3
1.2
0.9
0.4
2.6
65.1
SEC
EFF
(DUP)
CMS
2.1
6.3
0.6
13.3
2.5
0.0
12.9
1.0
1.6
0.9
1.6
0.6
1.0
1.9
1.8
0.5
3.0
26.7
SEC
UAS
CMS
1
1
0
5
0
2
0
0
0
0
9
0
0
2
3
0
1
32
.1
.5
.8
.9
.0
.3
.0
.2
.2
.0
.3
.0
.2
.9
.4
.7
.3
.3
PR I
UAS
CMS
22.
22.
19.
67.
0.
0.
1.
3.
1.
0.
77.
1.
2.
44.
49.
19.
23.
51.
6
6
9
1
7
6
2
6
3
5
8
4
5
3
7
2
2
8
PR I
WAS
(DUP)
CMS
22.7
23.8
19.8
70.2
0.1
2.5
0.0
3.1
0.8
0.0
82.1
0.7
1.7
46.6
57.5
20.0
26.2
72.3
79
-------
REMOVAL AND PARTITIONING OF CERCLA ORGANICS DURING
TREATMENT - ACCLIMATED SYSTEM DATA SET 11
COMPOUNDS
'_
IDICHLOROBENZENE, PROBABLY 1,2
IDICHIOROBENZENE, PROBABLY 1,3
IDICHLOROBENZENE, PROBABLY 1,4
|1.2,4-TRICHLOROBENZENE
| NITROBENZENE
|1,3-DINITROBENZENE
|2,6-DINITROTOLUENE
IP-CRESOL
(4-CHLOROANILINE
IHEXACHLOROETHANE
| HEXACHLOROBUTADIENE
(DIMETHYL PHTHALATE
IDIETHYL PHTHALATE
IDIBUTYL PHTHALATE
| BUTYL BENZYL PHTHALATE
|BIS(2-ETHYLHEXYL)PHTHALATE
(NAPHTHALENE
ILINDANE
IDIELDRIN
1
x
PRIMARY
REMOVAL
7.2
3.8
r.o
53.3
19.6
62.4
24.5
-11.1
0.3
31.9
30.6
7.5
1.3
25.8
29.6
4.9
12.5
32.1
X
TOTAL
REMOVAL
96.8
91.7
99.3
94.2
96.8
100.0
84.5
99.3
97.5
99.0
98.4
99.6
99.4
98.2
98.2
99.4
96.5
69.0
X
ADSORBED
*
*
*
34.0
*
*
*
3.5
1.8
*
*
1.1
2.2
*
«
*
32.8
*
I
* I
I
I
BIOSTRIP)
*CHE.TRAN|
I
I
* I
* I
* I
60.3 |
* I
* I
* I
95.9 |
95.7 |
* I
* I
98.6 |
97.2 |
* I
* I
I
* I
63.7 |
* I
I
Partitioning not calculated because of inconsistent data
80
-------
CONCENTRATIONS OF CERCLA ORGANICS IN WASTEWATER AND
SLUDGE SAMPLES - UNACCLIMATED SYSTEM DATA SET 1
Compounds
-
OICHLOROBENZENE, PROBABLY 1,2
OICHLOROBENZENE, PROBABLY 1,3
DICHLOROBENZENE, PROBABLY 1,4
1,2.4-TRICHLOROBENZENE
NITROBENZENE
1,3-DINITROBENZENE
2,6-DINtTROTOLUENE
P-CRESOL
4-CHLOROANILINE
HEXACHLOROETHANE
HEXACHLOROBUTADIENE
DIMETHYL PHTHALATE
01 ETHYL PHTHALATE
01 BUTYL PHTHALATE
BUTYL BENZYL PHTHALATE
BISC2-ETHYLHEXYDPHTHALATE
NAPHTHALENE
LINDANE
DIELORIN
CONCENTRATION OF
RWU
UG/L
0
0
0
141
0
6
0
72
0
0
5
60
18
0
7
13
35
.0
.0
.0
.8
.0
.6
.0
.3
.0
.3
.3
.3
.5
.0
.6
.1
.1
RUU
COUP)
UG/L
0.0
0.0
3.4
352.9
2.9
0.0
0.0
75.1
0.0
0.0
5.5
77.1
32.3
0.0
28.7
0.0
14.5
PR I
INF
UG/L
225.
252.
237.
320.
303.
157.
275.
505.
100.
116.
117.
379.
268.
136.
303.
164.
290.
1
5
7
5
2
1
2
5
0
3
9
6
6
8
1
2
6
PR I
EFF
UG/L
233.0
257.7
229.1
326.8
260.3
17.4
193.4
73.2
88.5
157.7
296.9
179.2
84.3
124.6
PR I
EFF
(OUP)
UG/L
170.4
190.5
184.0
277.7
255.8
14.3
176.0
47.6
74.8
101.1
291.5
168.2
80.1
265.4
131.7
114.3
TOXICS
SEC
EFF
UG/L
38.3
40.6
41.1
64.9
160.2
41.6
38.5
40.9
0.0
4.0
7.9
12.8
10.9
4.7
35.6
80.6
13.7
MIXED
LIQUOR
(48hr)
UG/L
0.0
11.5
5.8
301.3
0.0
53.0
0.0
0.0
0.0
68.1
0.0
0.0
0.0
0.0
6.4
210.6
600.7
SEC
WAS
UG/L
219
267
244
1241
72
105
0
0
0
420
0
0
50
0
174
719
1229
PR I
WAS
UG/L
2611
2593
2356
5498
51
166
0
3855
0
5040
208
467
3380
4081
2743
3653
0
81
-------
.--.MASSES OF CERCLA ORGANICS IN WASTEWATER AND SLUDGE
STREAMS - UNACCLIMATED SYSTEM DATA SET 1
1
1
1
1
| „ Compound*
1
1
1
1
IDICHLOROBENZENE, PROBABLY 1,2
IDICHLOROBENZENE, PROBABLY 1,3
IDICHLOROBENZENE, PROBABLY 1,4
|1,2,4-TRICHLOR08ENZENE
(NITROBENZENE
|1,3-DINITROBENZENE
|2,6-OINITROTOLUENE
IP-CRESOL
IHEXACHLOROETHANE
IHEXACHLOROBUTADIENE
(DIMETHYL PHTHALATE
IOIETHYL PHTHALATE
IDIBUTYL PHTHALATE
| BUTYL BENZYL PHTHALATE
|BIS(2-ETHYLHEXYL)PHTHALATE
(NAPHTHALENE
ILINDANE
(OIELDRIN
I
PR I
INF
CMS
85.
96.
90.
122.
115.
59.
105.
192.
38.
44.
45.
144.
102.
52.
115.
62.
110.
9
3
7
3
7
9
0
9
1
4
0
8
5
2
6
6
9
PR I
EFF
CMS
88.
98.
87.
124.
99.
6.
73.
27.
33.
60.
113.
68.
32.
47.
9
3
4
7
3
6
8
9
8
2
3
4
2
5
MASS OF
PR I
EFF
(DUP)
CMS
65.0
72.7
70.2
105.9
97.6
5.5
67.1
18.2
28.5
38.6
111.2
64.2
30.5
101.3
50.3
43.6
TOXICS
SEC
EFF
CMS
14.6
15.5
15.7
24.8
61.1
15.9
14.7
15.6
0.0
1.5
3.0
4.9
4.2
1.8
13.6
30.8
5.2
IN GRAMS
MIXED
LIQUOR
(48hr)
CMS
0.0
0.7
0.3
17.6
0.0
3.1
0.0
0.0
0.0
4.0
0.0
0.0
0.0
0.0
0.4
12.3
35.0
SEC
WAS
CMS
0
1
1
5
0
0
0
0
0
1
0
0
0
0
0
2
5
.9
.1
.0
.1
.3
.4
.0
.0
.0
.7
.0
.0
.2
.0
.7
.9
.0
PR I
WAS
CMS
6.
6.
5.
12.
0.
0.
0.
8.
0.
11.
0.
1.
7.
9.
6.
8.
0.
0
0
5
7
1
4
0
9
0
7
5
1
8
5
4
5
0
82
-------
REMOVAL AND PARTITIONING OF CERCLA ORGANICS DURING
"TREATMENT - UNACCLIMATED SYSTEM DATA SET 1
1
1
1
1
| _ Compounds
1
1
1
1
IDICHLOROBENZENE, PROBABLY 1,2
IDICHLOROBENZENE. PROBABLY 1,3
IDICHLOROBENZENE, PROBABLY 1.4
| 1 ,2,4-TRICHLOROBEMZENE
| NITROBENZENE
|1,3-DINITROBENZENE
|2,6-OINITROTOLUENE
IP-CRESOL
|4-CHLOROANiLiNE
IHEXACHLOROETHANE
IHEXACHLOROBUTADIENE
(DIMETHYL PHTHALATE
IDIETHYL PHTHALATE
(OIBUTYL PHTHALATE
| BUTYL BENZYL PHTHALATE
| BI S(2-ETHYLHEXYL )PHTHALATE
(NAPHTHALENE
ILINOANE
(DIELDRIN
I
X
PRIMARY
REMOVAL
10.4
11.2
13.1
5.7
14.9
89.9
32.9
39.6
29.8
-9.7
22.5
35.3
39.9
12.4
19.8
58.9
X
TOTAL
REMOVAL
83.0
83.9
82.7
79.7
47.2
73.5
86.0
91.9
100.0
96.6
93.3
96.6
95.9
96.6
88.3
50.9
95.3
II
X X |
ADSORBED BIO+STRIP |
+CHE. TRAN ||
II
I
8.1 74.9 |j
7.4 76.5 | |
7.1 75.6 |j
14.6 65.2
0.4 46.8
* •
* *
* *
* *
30.2 66.4
1.1 92.3
• *
* *
18.1 78.5
* *
18.2 32.7
* *
Partitioning not calculated because of inconsistent data
83
-------
CONCENTRATIONS OF CERCLA ORGANICS IN WASTEWATER AND
SLUDGE SAMPLES - UNACCL1MATED SYSTEM DATA SET 2
Coopounds
—
IDICHLOROBENZENE, PROBABLY 1,2
IDICHLOROBENZENE, PROBABLY 1,3
IOICNLOROBENZENE, PROBABLY 1,4
|1,2,4-TRICHLOROBENZENE
| NITROBENZENE
|1,3-DUITROBENZENE
|2,6-DINITROTOLUENE
IP-CRESOL
|4-CHLOROANILINE
IHEXACHLOROETHANE
IHEXACHLOROBUTADIENE
(DIMETHYL PHTHALATE
IOIETHYL PHTHALATE
IOIBUTYL PHTHALATE
| BUTYL BENZYL PHTHALATE
|BIS(2-ETHYLHEXYL>PHTHALATE
| NAPHTHALENE
JLINDANE
IDIELDRIN
I
CONCENTRATION
RUU
UG/L
0.0
0.0
0.0
H1.8
0.0
6.6
0.0
0.0
0.3
5.3
60.3
18.5
0.0
7.6
13.1
35.1
RWW
(OUP)
UG/L
0.0
0.0
3.4
352.9
2.9
0.0
0.0
0.0
0.0
5.5
77.1
32.3
0.0
28.7
0.0
H.5
PR I
INF
UG/L
345.3
410.5
352.6
502.5
414.5
204.9
304.9
162.3
280.2
197.7
381.6
331.2
254.1
430.6
288.8
795.1
PR I
EFF
UG/L
243.6
296.1
260.0
337.8
366.9
24.4
285.9
77.5
138.5
243.1
399.1
302.8
164.0
387.2
217.2
641.3
SEC
EFF
UG/L
35.2
35.6
29.5
46.2
111.1
28.0
24.5
0.0
4.4
9.0
10.7
12.7
6.8
12.2
81.0
11.7
OF TOXICS
MIXED
LIQUOR
UG/L
27.3
41.8
27.9
1233.4
0.0
330.5
0.0
0.0
0.0
0.0
0.0
186.6
121.5
28.8
167.7
161.8
MIXED
LIQUOR
(0 hr)
UG/L
2.9
3.6
2.7
121.9
1.0
27.6
5.8
0.0
0.0
0.0
3.5
18.7
17.4
4.3
4.2
13.2
MIXED
LIQUOR
(48hr)
UG/L
101.4
210. 5
39.9
3251.8
0.0
1019.9
0.0
0.0
1354.1
0.0
0.0
327.8
246.5
45.1
3485.8
8456.4
SEC
WAS
UG/L
1739
2251
1528
8841
1281
1049
0
0
5349
0
62
329
253
296
7878
8454
SEC
WAS
COUP)
UG/L
1400
1393
978
5502
1140
1022
0
0
3087
0
56
331
156
198
4919
4028
PR I
WAS
UG/L
9093
9617
7357
46002
237
885
24339
32319
1221
19542
19631
39076
12248
0
1422
1469
84
-------
MASSES OF CERCLA ORGANICS IN WASTEWATER AND SLUDGE
STREAMS - UNACCLIMATED SYSTEM DATA SET 2
Compounds
—
D1CHLOROBENZENE, PROBABLY 1,2
DICHLOROBENZENE, PROBABLY 1,3
DICHLOROBENZENE, PROBABLY 1,4
1.2,4-TRICHLOROBENZEK
NITROBENZEME
1,3-DINITROBENZENE
2,6-OtNITROTOLUENE
P-CRESOL
4-CHLOROANILINE
HEXACHLOROETHANE
HEXACHLOROBUTADIENE
DIMETHYL PHTHALATE
01 ETHYL PHTHALATE
D I BUTYL PHTHALATE
BUTYL BENZYL PHTHALATE
B1S(2-ETHYLHEXYL)PHTHALATE
NAPHTHALENE
LINDANE
DIELORIN
PR
IN
CM
131
156
134
191
158
78
116
61
106
75
145
126
96
164
110
303
I
f
S
.7
.6
.5
.7
.2
.2
.3
.9
.9
.4
.6
.4
.9
.3
.2
.4
PR I
EFF
CMS
92.
113.
99.
128.
140.
9.
109.
29.
52.
92.
152.
115.
62.
147.
82.
244.
9
0
2
9
0
3
1
6
8
7
3
5
6
7
9
7
f
SEC
EFF I
CMS
13.4
13.6
11.2
17.6
42.4
10.7
9.4
0.0
1.7
3.4
4.1
4.8
2.6
4.7
30.9
4.5
IASS OF T
MIXED H
IOUOR I
<
CMS
1.6
2.4
1.6
71.9
0.0
19.3
0.0
0.0
0.0
0.0
0.0
10.9
7.1
1.7
9.8
9.4
OXICS I
IXED
IQUOR
0 hr)
CMS
0.2
0.2
0.2
7.1
0.1
1.6
0.3
0.0
0.0
0.0
0.2
1.1
1.0
0.2
0.2
0.8
N GRAMS
MIXED
LIQUOR
(48hr)
CMS
5.9
12.3
2.3
189.6
0.0
59.5
0.0
0.0
78.9
0.0
0.0
19.1
14.4
2.6
203.2
493.0
SEC
WAS
CMS
7.2
9.4
6.4
36.7
5.3
4.4
0.0
0.0
22.2
0.0
0.3
1.4
1.1
1.2
32.7
35.1
SEC
WAS
(DUP)
CMS
5.8
5.8
4.1
22.9
4.7
4.2
0.0
0.0
12.8
0.0
0.2
1.4
0.6
0.8
20.4
16.7
PR I
WAS
CMS
23.5
24.9
19.1
119.1
0.6
2.3
63.0
83.7
3.2
50.6
50.8
101.2
31.7
0.0
3.7
3.8
85
-------
REMOVAL AND PARTITIONING OF CERCLA ORGANICS DURING
TREATMENT - UNACCLIMATED SYSTEM DATA SET 2
Conpounds
DICHLOROBENZENE, PROBABLY 1,2
DICHLOROBENZENE, PROBABLY 1,3
DICHLOROBENZENE, PROBABLY 1,4
1,2, 4- TRICHLOROBENZEME
NITROBENZENE
1,3-DINITROBENZENE
2,6-DINITROTOLUENE
P-CRESOL
4-CHLOROANILINE
IHEXACHLOROETHANE
! HEXACHLOROBUTAD I ENE
DIMETHYL PHTHALATE
IDIETHYL PHTHALATE
IDIBUTYL PHTHALATE
| BUTYL BENZYL PHTHALATE
|BIS(2-ETHYLHEXYL)PHTHALATE
[NAPHTHALENE
ILINDANE
DIELDRIN
X
PRIMARY
REMOVAL
29
28
26
33
11
88
6
52
51
-23
-5
9
35
10
25
19
X
TOTAL
REMOVAL
90
91
92
91
73
86
92
100
98
95
97
96
97
97
72
99
X X
ADSORBED BIO+STRIP
i-CKE. TRAM
23 67
21 71
18 74
* *
4 70
* •
* *
* *
* *
* *
* *
* *
34 64
1 97
27 44
10 89
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
Partitioning not calculated because of inconsistent data
86
-------
CONCENTRATIONS OF CERCLA ORGANICS IN WASTEWATER AND
SLUDGE SAMPLES - UNACCLIMATED SYSTEM DATA SET 3
1
1
1
| Cowpxxndt
1
1
1
1
IDICHLOROBENZENE, PROBABLY 1,2
IDICHLOROBENZENE, PROBABLY 1,3
IDICHLOROBENZENE. PROBABLY 1,4
|1,2,4-TRICHLOROBENZENE
{NITROBENZENE
|1,3-DINITROBENZENE
{2,6-DINITROTOLUENE
IP-CRESOL
|4-CHOUOROANILINE
IHEXACHLOROETHANE
IHEXACNLOROBUTADIENE
{DIMETHYL PHTHALATE
IOIETHYL PHTHALATE
IDIBUTYL PHTHALATE
| BUTYL BENZYL PHTHALATE
|BIS(2-ETHYLHEXYL)PHTHALATE
{NAPHTHALENE
ILINDANE
IDIELDRIN
I
CONCENTRATION
RUU
UG/L
4.9
9.3
8.2
296.2
6.1
92.5
0.0
71.3
0.0
2.1
0.0
14.7
27.9
22.7
18.1
23.4
10.9
RUU
(OOP)
UG/L
3.2
7.2
7.2
283.8
8.8
68.9
0.0
66.2
0.0
0.0
0.0
13.6
25.5
23.0
19.8
24.5
10.1
PRI
INF
UG/L
196.2
232.6
222.2
469.6
265.7
172.7
234.4
385.1
182.1
198.5
204.9
252.5
243.3
224.8
251.4
258.7
143.1
PRI
EFF
UG/L
159.2
201.1
190.7
341.6
207.1
31.2
107.2
429.3
103.4
97.1
179.3
260.6
148.5
136.4
213.7
194.3
131.6
PRI
EFF
COUP)
UG/L
158.0
201.8
183.6
331.8
199.0
20.3
417.6
120.6
99.0
241.4
135.9
124.7
205.5
191.0
112.2
SEC
EFF
UG/L
17.3
26.7
18.7
46.8
60.1
26.7
18.4
0.0
0.0
3.9
4.5
9.2
6.0
4.5
5.3
79.4
6.8
OF TOXICS
SEC
EFF
(OOP)
UG/L
16.4
25.7
18.2
47.8
58.3
9.3
17.3
0.0
0.0
3.0
0.0
8.1
5.0
3.5
4.9
78.3
10.0
NIXED
LIQUOR
(Ohr)
UG/L
28.8
39.6
34.4
314.6
77.8
390.8
0.0
0.0
0.0
15.1
0.0
0.0
142.9
127.7
38.1
119.4
343.7
NIXED
LIQUOR
(48hr)
UG/L
68.4
77.7
63.3
182.9
0.0
450.8
0.0
0.0
0.0
148.3
0.0
0.0
249.6
258.0
58.8
378.0
569.6
SEC
WAS
UG/L
233
219
0
1125
0
702
0
0
0
403
0
103
266
312
78
827
962
SEC
WAS
(DUP)
UG/L
ISO
156
0
1094
0
409
0
0
0
365
0
0
0
251
52
825
1034
PRI
WAS
UG/L
1825
1947
1865
13840
90
348
13
3053
632
0
5727
199
405
4292
12510
2153
4223
PR]
WAS
(DUP)
UG/L
1999
2148
2130
14105
148
413
0
3417
0
0
6539
216
357
5102
14892
2453
4573
87
-------
MASSES OF CERCLA ORGANICS IN WASTEWATER AND SLUDGE
STREAMS - UNACCLIMATED SYSTEM DATA SET 3
1 1
1
1 1 PHI
| Compouxto |. INF
1 "- 1
1 1 CHS
1 1
1
IDICHLOROBENZENE, PROBABLY 1,2
IOICHLOROBENZEHE, PROBABLY 1,3
IDICHLOROBENZENE, PROBABLY 1,4
74.9
88.7
84.8
|1,2,4-TRICHLOR08ENZENE (179.2
INITROBENZEHE (101.4
|1,3-D1NITROBENZENE
|2,6-DINITROTOLUENE
IP-CRESOL
(4-CHOLOROANIL1NE
IHEXACHLOROETHANE
IHEXACHLOROBUTAOIENE
| DIMETHYL PHTHALATE
|0 (ETHYL PHTHALATE
IDIBUTYL PHTHALATE
| BUTYL BENZYL PHTHALATE
| B I S( 2 - ETHYLHEXYL )PHTHALATE
(NAPHTHALENE
ILINDANE
(DIELORIN
I
I
65.9
89.4
146.9
69.5
75.7
78.2
96.3
92.8
85.8
95.9
98.7
54.6
MASS OF TOXICS
PR I
EFF
CMS
60.7
76.7
72.8
130.3
79.0
11.9
40.9
163.8
39.4
37.0
68.4
99.4
56.6
52.1
81.6
74.1
50.2
PR I
EFF
(DUP)
CMS
60.3
77.0
70.0
126.6
75.9
7.8
159.3
46.0
37.8
92.1
51.8
47.6
78.4
72.9
42.8
SEC
EFF
CMS
6.6
10.2
7.1
17.9
22.9
10.2
7.0
0.0
0.0
1.5
1.7
3.5
2.3
1.7
2.0
30.3
2.6
SEC
EFF
(DUP)
CMS
6.3
9.8
6.9
18.3
22.3
3.5
6.6
0.0
0.0
1.1
0.0
3.1
1.9
1.3
1.9
29.9
3.8
MIXED
LIQUOR
(Ohr)
CMS
1.7
2.3
2.0
18.3
4.5
22.8
0.0
0.0
0.0
0.9
0.0
0.0
8.3
7.4
2.2
7.0
20.0
MIXED
LIQUOR
(48hr)
CMS
4.0
4.5
3.7
10.7
0.0
26.3
0.0
0.0
0.0
8.6
0.0
0.0
14.6
15.0
3.4
22.0
33.2
SEC
WAS
CMS
1.0
0.9
0.0
4.7
0.0
2.9
0.0
0.0
0.0
1.7
0.0
0.4
1.1
1.3
0.3
3.4
4.0
SEC
WAS
(DUP)
CMS
0.6
0.6
0.0
4.5
0.0
1.7
0.0
0.0
0.0
1.5
0.0
0.0
0.0
1.0
0.2
3.4
4.3
PR]
WAS
CMS
4.7
5.0
4.8
35.8
0.2
0.9
0.0
7.9
1.6
0.0
14.8
0.5
1.0
11.1
32.4
5.6
10.9
PR1
WAS
(DUP)
CMS
5.2
5.6
5.5
36.5
0.4
1.1
0.0
8.8
0.0
0.0
16.9
0.6
0.9
13.2
38.5
6.3
11.8
88
-------
REMOVAL AND PARTITIONING OF CERCLA ORGANICS DURING
TREATMENT - UNACCLIMATED SYSTEM DATA SET 3
_ Compounds
-
IDICHLOROBENZENE, PROBABLY 1,2
IDICHLOROBENZENE, PROBABLY 1,3
IDICHLOROBENZENE, PROBABLY 1,4
|1,2,4-TRICHLOROBENZENE
(NITROBENZENE
|1,3-DINITROBENZENE
|2,6-OIN1TROTOLUENE
IP-CRESOL
|4-CHOLOROANILINE
(HEXACHLOROETHANE
IHEXACHLOROBUTADIENE
[DIMETHYL PHTHALATE
IDIETHYL PHTHALATE
IDIBUTYL PHTHALATE
| BUTYL BENZYL PHTHALATE
|BIS(2-ETHYLHEXYL)PHTHALATE
(NAPHTHALENE
ILINDANE
IDIELDRIN
I
X
PRIMARY
REMOVAL
19
13
16
28
24
85
54
-10
38
51
12
1
42
42
17
26
15
X
TOTAL
REMOVAL
91
89
92
90
77
85
92
100
100
98
98
96
98
98
98
69
95
X
ADSORBED
8
7
6
23
*
*
•
6
*
*
20
1
*
*
37
*
28
I
I
X I
I
BIO+STRIPj
+CHE.TRAN|
84
82
85
67
*
"
*
94
*
*
78
96
*
*
61
*
67 ||
II
Partitioning not calculated because of inconsistent data
89
-------
CONCENTRATIONS OF CERCLA ORGANICS IN WASTEWATER AND
SLUDGE SAMPLES - UNACCLIMATED SYSTEM DATA SET 4
Compounds
-
IDICHLOROBENZENE, PROBABLY 1,2
IDICHLOROBENZEME, PROBABLY 1,3
IDICHLOROBEMZEME, PROBABLY 1,4
| 1 , 2 , 4 - TR I CHLOROBENZENE
(NITROBENZENE
|1,3-DINITROBENZENE
|2,6-DINITROTOLUENE
IP-CRESOL
(4-CHOLOROAN1LINE
(HEXACHLOROETHANE
IHEXACHLOROBUTADIENE
IOIMETHYL PHTHALATE
IDIETHYL PHTHALATE
IDIBUTYL PHTHALATE
| BUTYL BENZYL PHTHALATE
|BIS(2-ETHYLHEXYL)PHTHALATE
[NAPHTHALENE
ILINOANE
IDIELORIN
I
CONCENTRATION
RWU
U6/L
10
11
10
3
2
0
71
19
5
18
37
41
29
20
66
.2
.5
.0
.9
.8
.0
.5
.8
.9
.9
.6
.0
.3
.5
.7
PR I
INF
UG/L
219.7
214.9
211.1
190.5
109.8
183.4
309.3
222.4
230.9
229.6
261.2
245.0
281.3
226.1
888.8
PR)
INF
(DUP)
UG/L
196.5
192.2
189.4
218.8
114.5
200.3
307.2
174.6
243.1
234.3
206.9
212.2
279.1
192.8
625.4
PR I
EFF
UG/L
171.4
172.1
151.7
59.4
96.1
233.7
223.9
138.0
223.6
162.0
OF TOXICS
SEC
EFF
UG/L
54.3
52.3
28.7
132.2
0.0
52.3
4.4
5.
3.
5.
10.
5.
11.1
176.0
71.9
MIXED
LIQUOR
(Ohrs)
UG/L
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
211.1
0.0
0.0
0.0
0.0
MIXED
LIQUOR
(48hrt>
UG/L
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
130.4
0.0
0.0
0.0
0.0
SEC
WAS
UG/L
107
142
74
27
340
0
13
467
21
31
248
110
43
875
1388
PR I
WAS
UG/L
195
305
380
0
0
0
494
0
55
74
1081
1380
0
624
0
PR I
WAS
(DUP)
UG/L
2680
396
1072
1242
0
0
0
5100
96
177
3034
3985
0
1594
563
90
-------
MASSES OF CERCLA ORGANICS IN WASTEWATER AND SLUDGE
STREAMS - UNACCLIMATED SYSTEM DATA SET 4
Compounds
IDICHLOROBENZENE, PROBABLY 1,2
IDICHLOROBENZENE, PROBABLY 1,3
IDICHLOROBENZENE, PROBABLY 1,4
|1,2,4-TRICHLOROBENZENE
| NITROBENZENE
| 1,3-DINITROBENZENE
|2,6-DINITROTOLUENE
IP-CRESOL
|4-CHOLOROANILINE
IHEXACHLOROETHANE
| HEXACHLOROBUTAOIENE
IOIHETHYL PHTHALATE
IDIETHYL PHTHALATE
|DI BUTYL PHTHALATE
| BUTYL BENZYL PHTHALATE
|BIS(2-ETNYLHEXYL)PHTHALATE
PR I
INF
CMS
83
82
80
72
41
70
118
84
88
87
99
93
(NAPHTHALENE |107
ILINDANE | 86
IOIELDRIN (339
.8
.0
.5
.7
.9
.0
.0
.9
.1
.6
.7
.5
.3
.2
.1
PR I
INF
(DUP)
CMS
75.0
73.3
72.3
83.5
43.7
76.4
117.2
66.6
92.7
89.4
78.9
81.0
106.5
73.5
238.6
PR I
EFF
CMS
65.
65.
57.
22.
36.
89.
85.
52.
85.
61.
4
7
9
6
7
2
4
7
3
8
MASS OF TOXICS
SEC MIXED MIXED SEC
EFF LIQUORLIQUOR WAS
(Ohrs)(48hrs)
CMS
20.7
20.0
10.9
50.5
0.0
19.9
1.7
2.1
1.4
2.2
4.1
2.3
4.3
67.1
27.4
CMS
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
12.3
0.0
0.0
0.0
0.0
CMS
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
7.6
0.0
0.0
0.0
0.0
CMS
0.4
0.6
0.3
0.1
1.4
0.0
0.1
1.9
0.1
0.1
1.0
0.5
0.2
3.6
5.8
PR I
WAS
CMS
0.5
0.8
1.0
0.0
0.0
0.0
1.3
0.0
0.1
0.2
2.8
3.6
0.0
1.6
0.0
PR I
WAS
(DUP)
6.9
1.0
2.8
3.2
0.0
0.0
0.0
13.2
0.2
0.5
7.9
10.3
0.0
4.1
1.5
91
-------
REMOVAL AND PARTITIONING OF CERCLA ORGANICS DURING
TREATMENT - UNACCLIMATEO SYSTEM DATA SET 4
1
1
1
| Compounds
1
1
1
1
IDICHLOROBENZENE, PROBABLY 1,2
IDICHLOROBENZENE, PROBABLY 1.3
IDICHLOROBENZEME, PROBABLY 1.4
(1,2,4-TRICHLOROBENZENE
(NITROBENZENE
|1,3-DINITROBENZENE
|2,6-OINITROTOLUENE
IP-CRESOL
|4-CHOLOROANILIHE
IHEXACHLOROETHANE
| HEXACHLOKOBUT AD I ENE
(DIMETHYL PHTHALATE
IOIETHYL PHTHALATE
IDIBUTYL PHTHALATE
| BUTYL BENZYL PHTHALATE
|BIS(2-ETHYLHEXYL)PHTHALATE
(NAPHTHALENE
ILINOANE
(DIELDRIN
I
X
PRIMARY
REMOVAL
16
H
51
70
59
-1
4
40
-7
79
X
TOTAL
REMOVAL
74
74
86
35
100
73
99
97
98
98
95
97
96
16
90
X
ADSORBED
5
2
3
2
*
*
*
*
*
1
7
*
*
8
*
II
II
X II
II
BIO+STRIP||
+CHE.TRAN||
II
II
69 ||
72 ||
83 ||
II
33 ||
• II
• II
* II
II
II
* II
* II
97 ||
88 ||
* II
II
• II
8 II
* II
II
Partitioning not calculated because of inconsistent data
92
-------
APPENDIX 3. CONVENTIONAL POLLUTANT DATA
93
-------
RCRA PILOT STUDY
94
-------
TOTAL SUSPENDED SOLIDS (mg/L) - ACCLIMATED SYSTEM
DATE
(DD-MM)
01-Feb
02-Feb
03-Feb
04-Feb
05-Feb
06-Feb
07-Feb
08-Feb
09-Feb
10-Feb
11-Feb
12-Feb
13-Feb
14-Feb
15-Feb
16-Feb
17-Feb
18-Feb
19-Feb
20-Feb
21-Feb
22-Feb
23-Feb
24-Feb
25-Feb
26-Feb
27-Feb
28-Feb
29-Feb
PRI
INF
252
128
188
216
260
256
220
252
252
124
192
324
348
188
224
176
172
220
220
172
PRI
EFF
204
96
104
210
172
164
112
32
148
72
124
176
180
164
108
100
48
152
112
32
SEC
EFF
0
3
4
7
7
1
6
6
3
1
3
11
7
5
8
4
21
6
13
2
MIX
LIQ
3250
2030
1920
1730
1810
1940
2100
1920
2120
2030
1990
2250
2010
3700
2470
2010
2250
2310
2280
2090
SEC
WAS
10170
9500
7590
7330
6750
8280
6140
7350
8210
6210
6240
6380
5420
6860
5950
7370
7350
7590
7710
8360
*
PRI X
SLU Remov
1.5
3.5
2.7
4.6
2.9
3.3
0.7
2.0
2.8
1.1
3.8
0.7
1.9
2.1
100
98
98
97
97
100
97
98
99
99
98
97
98
97
96
98
88
97
94
99
* Percent Total Solids
95
-------
TOTAL'SUSPENDED SOLIDS (mg/L) - ACCLIMATED SYSTEM
DATE
(DD-MM)
01 -Mar
02-Mar
03 -Mar
04 -Mar
OS-Mar
06-Mar
07-Mar
08-Mar
09-Mar
10-Mar
11 -Mar
1Z-Mar
13-Mar
14-Mar
15-Mar
16-Mar
17-Mar
18-Mar
19-Mar
20-Mar
21 -Mar
22-Mar
23-Mar
24-Mar
25-Mar
26-Mar
27-Mar
28-Mar
29-Mar
30-Mar
31 -Mar
AVERAGE AND
AVERAGE
DEVIATION
PR I
INF
292
164
52
144
124
204
248
224
148
176
212
208
224
228
232
260
240
252
308
224
228
204
156
112
240
128
580
228
PR I
EFF
152
108
84
80
80
76
156
160
72
120
196
104
228
80
184
200
76
132
124
120
88
136
80
52
116
100
410
104
SEC
EFF
11
4
0
2
0
4
9
7
1
4
50
6
5
29
14
2
11
4
4
1
11
0
5
1
8
4
7
16
ST. DEVIATION FOR
217
77
128
63
7
8
MIX
LIQ
2370
2260
2490
2140
2520
2670
2390
1260
2710
2320
2200
2180
1900
1900
2210
1840
1530
2130
2120
1870
1800
1910
2300
2100
1900
2230
1670
THE SPIKE
2152
394
SEC
WAS
8600
7600
9140
7560
9000
9260
8390
10340
2750
7940
7160
7800
7980
7510
7240
7660
7120
7350
7690
6860
6910
7840
6970
7950
7410
7440
7780
5480
PERIOD
7489
1244
*
PR I
SLU
1.5
1.3
1.3
1.4
0.8
0.9
0.8
2.1
0.7
1.1
1.6
1.9
3.0
2.2
0.9
0.7
0.8
0.7
0.8
0.5
0.5
0.7
1.7
1.0
X
Remov
96
98
100
99
100
98
96
97
99
98
76
97
98
87
94
99
95
98
99
100
95
100
97
99
97
97
99
93
97
4
* Percent Total Solids
96
-------
COO/SCOO DATA - ACCLIMATED SYSTEM
Date
01-Feb
02-Feb
03-Feb
04-Feb
05-Feb
06-Feb
07-Feb
08-Feb
09-Feb
10-Feb
11-Feb
12-Feb
13-Feb
14-Feb
15-Feb
16-Feb
17-Feb
18-Feb
19-Feb
20-Feb
21-Feb
22-Feb
23-Feb
24-Feb
25-Feb
26-Feb
27-Feb
28-Feb
29-Feb
TOTAL
PRI PRI
INF EFF
mg/L mg/L
249 230
243 276
596 234
418 368
897 488
370 329
513 555
393 349
516 413
571 483
714 278
625 761
COO
SEC X
EFF Remov
mg/L
46 82
45 81
55 91
58 86
134 85
85 77
131 74
95 76
54 90
109 81
SOLUBLE
PRI PRI
INF EFF
mg/L mg/L
46 88
71 66
207 99
193 198
309 274
61 54
297 156
370 150
229 216
211 97
136 78 |
COD
SEC X
EFF Remov
mg/L
38 17
24 66
31 85
53 73
190 39
0 100
117 61
70 81
100
124 41
97
-------
CCO/SCOO DATA - ACCLIMATED SYSTEM
TOTAL COD
SOLUBLE COD
Date
01 -Mar
02-Mar
03-Mar
04 -Mar
OS-Mar
06-Mar
07-Mar
08-Mar
09-Mar
10-Mar
11 -Mar
12-Mar
13-Mar
14-Mar
15-Mar
16-Mar
17-Mar
18-M«r
19-Mar
20-Mar
21 -Mar
22-Mar
23-Mar
24-Mar
25-Mar
26-Mar
27-Mar
28-Mar
29-Mar
30-Mar
31 -Mar
PRI PRI SEC X
INF EFF EFF Remov
mg/L rog/L mg/L
455 446 95 79
259 228 62 76
460 423 96 79
562 482 166 70
577 546 0 100
586 529 91 84
387 359 55 86
553 510 57 90
PRI PRI SEC X
INF EFF EFF Remov
mg/L mg/L mg/L
144 172 77 47
80 82 46 43
174 204 68 61
193 186 42 78
125 135 0 100
461 350 0 100
203 177 73 64
194 201 58 70
114 142 57 50
AVERAGE AND ST. DEVIATION FOT THE SPIKE PERIOD
AVERAGE | 497 414 83 82 | 194 160 59 67
I I
DEVIATION) 157 132 40 7 | 105 72 46 23
98
-------
NITROGEN DATA : ACCLIMATED SYSTEM
Date
(DD-MM)
01-Feb
02-Feb
03-Feb
04-Feb
05-Feb
06-Feb
07-Feb
08-Feb
09-Feb
10-Feb
11-Feb
12-Feb
13-Feb
14-Feb
15-Feb
16-Feb
17-Feb
18-Feb
19-Feb
20-Feb
21-Feb
22-Feb
23-Feb
24-Feb
25-Feb
26-Feb
Z7-Feb
28-Feb
29-Feb
AMMONIA-N
PR1 PRI SEC X
INF EFF EFF Remov
mg/L mg/L mg/L
4.6 5.1 0.4 91
12.6 12.4 5.6 55
9.4 9.5 3.7 60
23.7 24.0 12.6 47
26.4 25.6 14.7 44
17.7 18.5 9.6 46
14.4 12.6 2.7 81
23.1 24.6 5.3 77
16.6 20.8 6.1 63
24.6 23.8 0.0 100
24.4 22.6 0.6 98
19.7 4.0 0.0 100
31.4 21.3 3.6 89
NITRATE-N
PRI PRI SEC
INF EFF EFF
mg/L mg/L mg/L
7.76 7.93 7.8
1.72 0.71 5.5
0.92 0.32 8.2
0.53 0.21 5.6
0.26 0.20 5.2
0.26 8.6
0.07 0.05 8.0
0.25 0.23 8.1
0.17 0.13 16.8
0.44 0.11
0.24 0.15 14.9
0.22 11.50
0.24 0.21 7.9
99
-------
NITROGEN DATA : ACCLIMATED SYSTEM
Date
(DD-MM)
01 -Mar
02-Mar
03-Mar
04-Mar
OS-Mar
06-Mar
07-Mar
08-Mar
09-Mar
10-Mar
11 -Mar
12-Mar
13-Mar
14-Mar
15-Mar
16-Mar
17-Mar
18-Mar
19-Mar
20-Nar
21 -Mar
22-Mar
23-Mar
24-Mar
25 -Mar
26-Mar
27-Mar
28-Mar
29-Mar
30-Mar
31 -Mar
AMMONIA-N
PRI PRI SEC X
INF EFF EFF Ranov
mg/L mg/L mg/L
17.1 20.0 1.0 94
7.7 6.8 0.4 95
22.6 20.4 0.9 96
21.5 21.2 2.4 89
23.8 24.2 4.4 81
32.8 33.8 14.8 55
12.3 13.7 4.7 61
27.5 26.6 6.4 77
NITRATE-N
PRI PRI SEC
INF EFF EFF
mg/L mg/L mg/L
0.20 0.15 14.4
1.32 0.90 6.9
0.19 0.14 10.2
0.20 0.15 12.6
0.28 0.22 9.4
0.20 0.11 7.7
0.00 0.00 2.9
0.10 1.41 8.8
0.17 0.00
AVERAGE AND ST .DEVIATION FOR THE SPIKE PERIOD
I I I
AVERAGE | 19.7 18.6 4.8 76 | 0.71 0.67 9.1 |
I I I
DEVIATION | 7.4 7.6 4.5 19 | 1.59 1.70 3.4 |
100
-------
TOTAL SUSPENDED SOLIDS (mg/L) - UNACCLIMATED SYSTEM
---. DATE
CDD-MH)
01-Feb
02-Feb
03-Feb
04-Feb
05-Feb
06-Feb
07-Feb
08-Feb
09-Feb
10-Feb
11-Feb
12-Feb
13-Feb
U-Feb
15-Feb
16-Feb
17-Feb
18-Feb
19-Feb
20-Feb
21-Feb
22-Feb
23-Feb
24-Feb
25-Feb
26-Feb
27-Feb
28-Feb
29-Feb
PR I
INF
276
156
232
228
188
248
184
192
276
176
264
348
292
148
248
244
216
216
230
204
180
236
PR I
EFF
144
84
96
104
188
260
116
104
136
136
124
128
200
120
264
72
108
212
290
136
124
140
SEC
EFF
23
5
8
12
6
5
6
0
3
1
7
6
5
26
5
1
0
8
7
2
5
8
MIX
LIQ
3100
1800
1700
1590
1710
1920
1820
1960
2010
2770
1940
2110
1840
920
1890
1760
1860
2200
1960
1890
2170
1870
SEC
WAS
7950
5210
5100
5720
5760
6810
5830
6440
6740
6690
4270
6400
5840
6480
5980
6290
6290
6210
4610
6230
6530
9800
*
PRI X
SLU Remov
0.6
0.3
0.7
0.9
0.9
0.6
1.8
0.7
1.4
0.8
1.8
1.8
1.4
2.5
4.0
3.7
1.5
0.8
0.5
92
97
97
95
97
98
97
100
99
99
97
98
98
82
98
100
100
96
97
99
97
97
* Percent Total Solids
101
-------
TOTAL SUSPENDED SOLIDS
-------
CQO/SCOO DATA - UNACCLIMATED SYSTEM
Date
(DD-MM)
01-Feb
02-Feb
03-Feb
04-Feb
05-Feb
06-Feb
07-Feb
08-Feb
09-Feb
10-Feb
11-Feb
12-Feb
13-Feb
14-Feb
15-Feb
16-Feb
17-Feb
18-Feb
19-Feb
20-Feb
21-Feb
22-Feb
23-Feb
24-Feb
25-Feb
26-Feb
27-Feb
28-Feb
29-Feb
TOTAL COO
PRI PRI SEC X
INF EFF EFF Remov
mg/L mg/L mg/L
247 245 51 79
247 236 36 86
636 176 46 93
221 49 78
1180 553 76 94
874 563 181 79
360 327 93 74
587 499 108 82
524 339 100 81
532 554 71 87
610 504 108 82
710 683 142 80
659 495 128 81
SOLUBLE COO
PRI PRI SEC X
INF EFF EFF Remov
mg/L mg/L mg/L
62 67 34 46
67 68 43 36
89 185 43 52
206 208 50 76
452 238 43 90
308 331 176 43
80 65 35 56
405 198 174 57
189 136 47 75
228 217 48 79
268 247 63 76
103
-------
COO/SCOO DATA - UNACCLIMATED SYSTEM
Date
(DO -MM)
01 -Mar
02-Mar
03-Mar
04-Mar
05-Mar
06-Mar
07-Mar
08-Mar
09-Mar
10-Mar
11 -Mar
12-Mar
13 -Mar
K-Mar
15-Mar
16-Mar
17-Mar
18-Mar
19-Mar
20-Mar
21 -Mar
22-Mar
23-Mar
24 -Mar
25 -Mar
26-Mar
27-Mar
28-Mar
29-Mar
30-Mar
31 -Mar
TOTAL COO
PRI PRI SEC X
INF EFF EFF Remov
mg/L mg/L mg/L
507 464 169 67
252 239 53 79
419 444 39 91
615 589 126 80
525 0
662 586 84 87
587 579 98 83
218 562 89 59
572 577 107 81
SOLUBLE COO
PRI PRI SEC X
INF EFF EFF Remov
mg/L mg/L mg/L
149 167 78 48
86 86 0 100
290 300 0 100
201 289 55 73
81 103 0 100
513 416 0 100
215 188 92 57
219 191 60 73
121 139 68 44
I
I
I
I
AVERAGE AND ST. DEVIATION FOR THE SPIKE PERIOD
AVERAGE | 534 464 89 81 | 211 192 55 69
I I
DEVIATION | 230 141 44 8 | 128 92 47 21
104
-------
NITROGEN DATA : UNACCLIMATED SYSTEM
Date
(DD-MM)
01-Feb
02-Feb
03-Feb
04-Feb
05-Feb
06-Feb
07-Feb
08-Feb
09-Feb
10-Feb
11-Feb
12-Feb
13-Feb
14-Feb
15-Feb
16-Feb
17-Feb
18-Fcb
19-Feb
20-Feb
21-Feb
22-Feb
23-Feb
24-Feb
25-Feb
26-Feb
27-Feb
28-Feb
29-Feb
AMMONIA-N
PRI PRI SEC X
INF EFF EFF Remov
mg/L mg/L mg/L
4.8 5.4 0.2 97
12.4 12.8 1.2 90
9.5 9.4 0.2 98
23.1 7.1
26.1 25.3 12.1 54
15.7 18.2 5.7 64
14.6 13.2 0.4 98
23.6 24.8 4.7 80
16.9 20.1 6.0 64
23.8 23.8 4.7 80
25.9 24.4 2.5 90
20.1 17.9 0.8 96
31.2 21.9 3.6 88
NITRATE-N
PRI PRI SEC
INF EFF EFF
mg/L mg/L mg/L
1.81 7.49 9.6
1.64 0.80 10.1
0.98 0.67 8.1
0.21 7.96
0.25 0.20 5.8
2.87 0.12 8.7
0.05 0.05 10.3
0.24 0.17 7.6
0.33 0.16 12.8
0.14 0.04 17.0
0.52 0.26 11.2
0.15 0.02 13.6
0.21 0.41 9.1
105
-------
NITROGEN DATA : UNACCLIMATED SYSTEM
Date
(DD-MM)
01 -Mar
02-Mar
03-Mar
04-Mar
05-Mar
06-Mar
07-Mar
08-Mar
09-Mar
10-Mar
11 -Mar
12-Mar
13-Mar
14-Mar
15-Mar
16-Mar
17-Mar
18-Mar
19-Mar
20-Mar
21 -Mar
22-Mar
23-Mar
24 -Mar
25-Mar
26-Mar
27-Mar
28-Mar
29-Mar
30-Mar
31 -Mar
AMMONIA-N
PRI PRI SEC X
INF EFF EFF Remov
mg/L mg/L mg/L
18.1 19.3 5.0 73
8.3 7.1 0.2 98
22.4 20.2 0.9 96
22.4 21.2 1.1 95
23.0 26.4 1.5 93
'
32.1 36.8 6.5 80
28.4 32.4 16.8 41
9.4 14.3 5.0 47
NITRATE-N
PRI PRI SEC
INF EFF EFF
mg/L mg/L rog/L
0.26 0.19 9.3
1.30 0.62 6.8
0.13 0.13 10.3
0.18 0.16 13.9
0.22 0.22 12.5
0.16 0.14 13.7
0.09 0.10 4.9
0.00 0.00 7.6
AVERAGE AND ST. DEVIATION FOR THE SPIKE PERIOD
I I I
AVERAGE | 20 19 3.9 81 | 0.56 0.95 10 |
I I I
DEVIATION | 7 8 4.2 18 | 0.73 2.21 3 \
106
-------
EFFECT OF RCRA TOXICS ON COD REMOVAL
l<
I
o
o
o
100 -
90 -
80 -
70 -
60 -
50 -
40 -
30 -
20 -
10 -
n -
— — — —
A
j
I
20
t
• UN ACCLIMATED
Indleote Intermittent spike 'days.
TIME (days)
40
ACCLIMATED
t
60
-------
EFFECT OF RCRA TOXICS ON NITRIFICATION
100
o
CD
• UNACCUMATEO
Arrows Indicate intermittent spike days.
ACCLIMATED
-------
CERCLA PILOT STUDY
109
-------
TOTAL SUSPENDED SOLIDS (mg/L) - ACCLIMATED SYSTEM
DATE
(DD-MM)
01-Jun
02-Jun
03-Jun
04-Jun
OS-Jun
06-Jun
07-Jun
08-Jun
09-Jun
10-Jun
11-Jun
12-Jun
13-Jun
U-Jun
15-Jun
16-Jun
17-Jun
18-Jun
19-Jun
20-Jun
21-Jun
22-Jun
23-Jun
24-Jin
25-Jun
26-Jun
27-Jun
28- Jin
29-Jun
30-Jun
PR I
INF
272
352
352
278
312
364
200
336
408
287
483
166
390
452
312
420
443
322
427
352
338
341
312
285
382
PR I
EFF
80
68
68
106
80
124
44
100
112
95
243
74
220
140
108
108
95
68
107
140
94
61
100
89
58
SEC
EFF
1
15
15
4
9
8
4
6
8
12
8
7
18
12
4
8
8
6
10
11
12
12
16
15
8
MIX
LIQ
4130
3390
3390
3180
2980
2840
5380
3010
2099
3463
2012
3580
3328
2900
3510
2803
3132
3325
3030
3122
1531
2040
2945
1722
SEC
WAS
10450
13040
13040
6250
11340
11670
5500
11270
11199
11483
12162
11160
10950
11480
11650
11733
10972
11265
8810
8122
10601
11220
10565
10252
«•
PR I
SLU f
2.6
2.7
2.7
2.0
1.3
2.2
1.2
1.5
3.5
2.7
2.9
4.0
2.8
2.2
3.6
3.7
3.6
2.8
3.3
2.2
2.5
3.3
3.7
X
iemov
100
96
96
99
97
98
98
98
98
96
98
96
95
97
99
98
98
98
98
97
96
96
95
95
98
* Percent Total Solids
110
-------
TOTAL SUSPENDED SOLIDS (mg/L) - ACCLIMATED SYSTEM
DATE
(DD-MM)
01-Jul
02-Jul
03-Jul
04-Jul
05-Jul
06-Jul
07-Jul
08-Jul
09-Jul
10-Jul
11-Jul
12-Jul
13-Jul
14-Jul
15-Jul
16- Jut
17-Jul
18-Jul
19-Jul
20-Jul
21-Jul
22-Jul
23-Jul
24- Jut
25-Jul
26-Jul
27-Jul
28-Jul
29-Jul
30-Jul
31-Jul
PR I
INF
255
287
355
216
268
326
360
438
263
296
278
285
452
116
183
236
207
273
352
304
216
247
236
348
318
487
241
226
303
217
195
PR I
EFF
107
99
75
84
84
74
90
94
91
104
62
113
152
112
75
108
81
101
108
124
76
139
100
104
114
127
125
130
127
181
147
SEC
EFF
8
12
6
7
13
7
10
8
10
10
4
11
16
20
8
11
14
12
14
11
9
9
16
17
4
14
32
17
13
10
12
MIX
LIQ
3059
2873
2689
2770
2700
2392
3520
2742
3053
2830
2838
3281
1734
2230
3123
2960
3221
3120
2780
2880
2779
3344
2960
3462
4339
2751
3742
2129
2821
2875
SEC
WAS
9899
9823
9409
9160
8580
8952
9760
10742
11463
10160
14178
10701
5764
10670
10073
9520
9981
11481
7080
9540
10020
9979
9664
9200
10999
11121
11882
9589
9761
9695
*
PR I
SLU R
3.1
2.7
3.0
0.9
2.0
3.0
1.4
2.3
1.7
2.8
6.0
2.5
1.3
3.2
3.3
3.1
2.5
2.6
2.4
3.3
2.2
3.2
1.2
2.3
1.7
X
emov
97
96
98
97
95
98
97
98
96
97
99
96
96
83
96
95
93
96
96
96
96
96
93
95
99
97
87
92
96
95
94
* Percent Total Solids
111
-------
TOTAL SUSPENDED SOLIDS (mg/L) - ACCLIMATED SYSTEM
DATE
(DD-MM)
01-Aug
02-Aug
03-Aug
04-Aug
05-Aug
06-Aug
07-Aug
08-Aug
09-Aug
10-Aug
11-Aug
12-Aug
13-Aug
14-Aug
15-Aug
16-Aug
17-Aug
18-Aug
19-Aug
20-Aug
21-Aug
22-Aug
23-Aug
24-Aug
25-Aug
26-Aug
27-Aug
28-Aug
29-Aug
30-Aug
31-Aug
AVERAGE
DEVIATION
PR I
INF
195
212
340
290
292
262
325
266
260
209
226
252
140
192
268
184
176
208
212
160
212
228
308
212
228
228
308
184
256
285
81
PR I
EFF
147
88
108
126
128
78
125
162
92
165
98
132
96
104
156
100
92
124
104
80
112
120
124
104
168
108
128
76
152
109
33
SEC
EFF
12
13
13
11
14
15
16
10
11
12
12
18
7
15
14
35
13
11
10
12
15
21
20
13
17
12
15
10
6
12
5
MIX
LIQ
2875
2380
2780
3418
3530
2962
2881
2772
2880
2571
3458
2490
2880
2764
4340
2820
3960
3630
3430
2510
2720
2900
2550
3030
2400
2720
3160
2550
2510
2972
585
SEC
WAS
9695
8880
9440
9298
9850
9322
9161
8502
10640
9361
9098
8180
10570
9924
12660
11560
11660
11060
10090
8720
8950
11100
9170
12940
9910
11720
11320
9080
10152
1584
PR I
SLU
2.7
0.8
1.5
2.6
2.9
0.5
2.6
2.9
1.8
2.9
2.2
6.1
6.6
3.2
1.7
3.2
2.9
2.9
1.7
2.1
2.3
2.6
0.7
1.3
1.0
1.6
2.6
1.1
X
Remov
94
94
96
96
95
94
95
96
96
94
95
93
95
92
95
81
93
95
95
92
93
91
94
94
93
95
95
95
98
95
3
* Percent Total Solids
112
-------
COO/SCOT DATA - ACCLIMATED SYSTEM
Date
(MM-DD)
01-Jun
02-Jun
03-Jun
04-Jun
05-Jun
06-Jun
07-Jun
08-Jun
09-Jun
10-Jun
11-Jun
12-Jun
13-Jun
14-Jun
15-Jun
16-Jun
17-Jun
18-Jun
19-Jun
20-Jun
21-Jun
22-Jun
23-Jun
24-Jun
25-Jun
26-Jun
27-Jun
28-Jun
29-Jun
30-Jun
TOTAL
PRI PR!
INF EFF
mg/L mg/L
394 535
742 537
802 584
782 647
905 536
745 547
594 645
677 461
711 386
765 375
461 605
696 492
COO | SOLUBLE COD
1
SEC X | PRI PRI SEC X
EFF Removj INF EFF EFF Remov
mg/L |mg/L mg/L mg/L
121 69
114 85
134 83
75 92
80 89
100 83
88 87
73 90
80 90
89 81
85 88
326 327
307 290
326 343
337 369
198 211
322 217
270 259
326 303
300 284
386 390
253 233
273 291
113 65
54 82
76 77
44 78
69 79
72 73
65 80
78 74
106 73
70 72
76 72
113
-------
COO/SCOO DATA - ACCLIMATED SYSTEM
Date
(MM-DD)
01-Jul
02-Jul
03-Jul
04-Jul
05-Jul
06-Jul
07-Jul
08-Jul
09-Jul
10-Jul
11-Jul
12-Jul
13-Jul
14-Jul
15-Jul
16-Jul
17-Jul
18-Jul
19-Jul
20-Jul
21-Jul
22-Jul
23-Jul
24-Jul
25-Jul
26-Jul
27-Jul
28-Jul
29-Jul
30- Jut
31-Jul
PR I
INF
mg/L
702
486
770
769
471
659
547
692
350
774
805
814
585
TOTAL
PRI
EFF
mg/L
469
346
596
634
364
385
480
361
210
543
462
532
402
COO
SEC
EFF
mg/L
90
70
96
87
50
58
52
89
55
72
94
90
61
% | PRI
Removj INF
I mg/L
87
86
88
89
89
91
91
87
84
91
88
89
90
266
133
320
308
173
327
327
231
121
276
335
264
283
SOLUBLE COO
PRI SEC %
EFF EFF Remov
mg/L mg/L
274
81
337
314
177
379
317
180
129
270
314
283
276
76
47
75
76
43
61
78
73
51
51
72
68
64
71
65
77
75
75
81
76
68
58
82
79
74
77
114
-------
COO/SCOO DATA - ACCLIMATED SYSTEM
Date
(MM-DD)
01-Aug
02-Aug
03-Aug
04-Aug
05-Aug
06-Aug
07-Aug
08-Aug
09-Aug
10-Aug
11-Aug
12-Aug
13-Aug
14-Aug
15-Aug
16-Aug
17-Aug
18-Aug
19-Aug
20-Aug
21-Aug
22-Aug
23-Aug
24-Aug
25-Aug
26-Aug
27-Aug
28-Aug
29-Aug
30-Aug
31-Aufl
AVERAGE
DEVIATION
PR I
INF
mg/L
576
907
506
695
742
575
600
557
569
591
975
836
999
720
681
149
TOTAL
PR I
EFF
mg/L
404
463
525
756
579
424
478
438
410
454
509
742
493
495
110
COD
SEC
EFF
mg/L
74
62
67
66
77
69
68
60
85
72
84
92
78
69
80
18
SOLUBLE COD
X | PRI
Remov) INF
87
93
87
91
90
88
89
89
85
88
91
89
92
90
88
4
mg/L
273
312
255
299
329
285
278
300
269
276
465
202
315
285
62
PRI
EFF
mg/L
225
283
285
311
289
305
284
286
251
368
379
165
283
278
68
SEC
EFF
mg/L
40
60
51
47
68
56
52
60
63
69
72
46
65
65
15
X
Remov
85
81
80
84
79
80
81
80
77
75
85
77
79
76
6
115
-------
NITROGEN DATA (mg/L) - ACCLIMATED SYSTEM
Date
(DD-MH)
01-Jun
02-Jun
03-Jun
04-Jun
05-Jun
06-Jun
07-Jun
08-Jun
09-Jun
10-Jun
11-Jun
12-Jun
13-Jun
PR I
INF
mg/L
25
32
21
27
14-Jun
15-Jun
16-Jun
17-Jun
18-Jun
19-Jun
20-Jun
21-Jun
22-Jun
23-Jun
24-Jun
25-Jun
26-Jun
27-Jun
28-Jun
29-Jun
30-Jun
33
23
25
40
36
31
31
AMMONIA
PR I
EFF
mg/L
30
29
22
28
32
24
30
35
36
30
24
-N
SEC X
EFF Remov
mg/L
0.6 98
3.6 89
0.5 97
4.4 84
11.9 64
0.6 98
14.3 42
6.8 83
5.1 86
1.9 94
0.7 98
NITRATE-N
PRI PRI
INF EFF
mg/L rog/L
0.00
0.29
0.21
0.24
0.12
0.00
0.00
0.22
0.18
0.23
0.28
0.00
0.61
0.23
0.19
0.09
0.00
0.00
0.17
0.17
0.24
0.24
SEC
EFF
mg/L
22
11
6
6
5
10
8
12
16
20
17
116
-------
NITROGEN DATA (mg/L) - ACCLIMATED SYSTEM
Date
(DD-MM)
01-Jul
02-Jul
03-Jul
04-Jul
05-Jul
06-Jul
07-Jul
08-Jul
09-Jul
10-Jul
11-Jul
12-Jul
13-Jul
14-Jul
15-Jul
16-Jul
17-Jul
18-Jul
19-Jul
20-Jul
21-Jul
22-Jul
23-Jut
24-Jul
25-Jul
26-Jul
27-Jul
28-Jul
29-Jul
30-Jul
31-Jul
PR I
INF
mg/L
18
13
30
22
32
40
25
23
9
27
40
48
28
AMMONIA-N
PR I SEC X
EFF EFF Remov
mg/L mg/L
21
14
27
22
31
38
26
19
9
28
41
40
27
0.5 97
1.9 85
5.8 81
9.7 55
9.5 70
11.3 72
1.3 95
0.7 97
0.3 96
6.0 78
10.0 75
11.2 76
0.4 98
NITRATE-N
PRI PRI
INF EFF
mg/L mg/L
0.21
0.10
0.22
0.21
0.11
0.21
0.10
0.10
0.00
0.00
0.10
0.09
0.00
0.14
0.96
0.23
0.22
0.11
0.18
0.09
0.00
0.00
0.11
0.10
0.00
0.00
SEC
EFF
mg/L
12
14
6
4
11
9
11
15
10
5
22
9
11
117
-------
NITROGEN DATA (mg/L) - ACCLIMATED SYSTEM
Date
CDD-MM)
01-Aug
02-Aug
03-Aug
04-Aug
05-Aug
06-Aug
07-Aug
08-Aug
09-Aug
10-Aug
11-Agg
12-Aug
13-Aug
14-Aug
15-Aug
16-Aug
17-Aug
18-Aug
19-Aug
20-Aug
21-Aug
22-Aug
23-Aua
24-Aug
25-Aug
26-Aug
27-Aug
28-Aug
29-Aug
30-Aug
31-Aug
AVERAGE
DEVIATION
PR I
INF
mg/L
28
35
24
25
33
25
23
26
30
28
26
28
8
AMMONIA-N
PR I
EFF
mg/L
29
33
25
33
30
25
24
27
28
28
28
7
SEC X
EFF Remov
mg/L
1.6 94
1.4 96
1.1 95
0.6 98
0.6 98
1.5 94
0.6 98
0.5 98
0.6 98
1.8 93
1.1 96
3.7 88
4.1 14
NITRATE-N
PR I
INF
mg/L
0.09
0.11
0.00
0.10
0.11
0.10
0.00
0.11
0.00
0.10
0.12
0.09
PR I
EFF
mg/L
0.00
0.00
0.00
0.10
0.00
0.00
0.11
0.00
0.30
0.14
0.19
SEC
EFF
mg/L
23
19
15
22
15
12
20
17
15
17
13
5
118
-------
TOTAL SUSPENDED SOLIDS (mg/L) - UNACCLIHATED SYSTEM
DATE
CMM-DD)
01-Jun
02-Jun
03-Jun
04-Jun
05-Jun
06-Jun
07-Jun
08-Jun
09-Jun
10-Jun
11-Jun
12-Jun
13-Jun
14-Jun
15-Jun
16-Jun
17-Jun
18-Jun
19-Jun
20-Jun
21-Jun
22-Jun
23-Jun
24- Jim
25-Jun
26-Jun
27-Jun
28-Jun
29-Jun
30-Jun
PR I
INF
196
344
316
276
428
260
316
272
642
223
440
241
530
336
269
437
392
286
662
371
414
347
401
279
334
PR I
EFF
108
72
96
52
68
52
112
116
86
79
120
105
60
188
53
109
80
64
118
131
50
177
121
83
94
SEC
EFF
19
4
8
9
6
5
7
12
12
11
9
15
13
24
22
17
13
12
9
12
8
9
11
10
4
NIX
LIQ
3900
5520
3830
3740
2820
4030
4240
4182
3429
4240
4849
5660
5070
3471
4221
4394
4082
4012
3599
3417
1985
1959
1012
SEC
WAS
10020
10710
9290
10820
11590
9920
13790
10860
11062
11229
9900
12589
11620
11080
10881
10881
10514
11102
10712
11449
10082
9237
10365
10279
11632
P
S
2
2
1
2
2
1
1
2
2
2
2
3
2
2
2
2
2
2
2
2
3
1
•X
RI
LU
.4
.0
.6
.2
.2
.5
.9
.6
.6
.1
.4
.0
.3
.8
.0
.6
.5
.6
.7
.9
.6
.9
X
Reroov
90
99
97
97
99
98
98
96
98
95
98
94
98
93
92
96
97
96
99
97
98
97
97
96
99
* Percent Total Solids
119
-------
TOTAL SUSPENDED SOLIDS (mg/L) - UNACCLIHATED SYSTEM
DATE
(MM-DD)
01-Jul
02-Jut
03-Jul
04-Jul
05-Jul
06-Jul
07- Jut
08- Jut
09-Jul
10-Jut
11-Jul
12-Jul
13-Jul
14-Jul
15-Jul
16-Jul
17-Jul
18-Jul
19-Jul
20-Jul
21-Jul
22-Jul
23-Jul
24-Jul
25-Jul
26-Jul
27-Jul
28-Jul
29-Jul
30-Jut
31-Jul
PR I
INF
329
263
392
234
272
224
243
322
295
325
300
293
332
258
197
288
193
199
305
256
132
254
248
253
338
294
224
259
296
310
223
PR I
EFF
109
71
132
78
164
112
143
110
103
93
140
113
144
126
91
112
49
107
93
92
80
130
68
61
106
118
100
91
104
210
119
SEC
EFF
4
6
7
7
9
6
12
8
3
13
10
12
21
11
9
6
10
10
8
5
9
10
17
21
65
102
60
12
10
MIX
LIO
3621
3483
3600
3362
3540
3730
2537
4032
3899
3940
3941
3460
3258
2933
3530
4081
4263
3501
3680
3740
3472
3200
4921
3182
3098
4100
2919
3350
3538
3305
SEC
WAS
11571
12053
11520
11762
14040
11980
6647
13392
13979
11577
9640
11341
10480
7788
12563
12520
11501
9783
11301
11760
11940
11942
11780
9361
6798
9080
10480
11398
9975
PR I
SLU f
4.3
6.0
8.1
0.7
5.3
7.8
3.2
8.6
6.7
3.6
2.5
5.2
0.8
4.4
3.1
4.7
4.9
3.2
4.0
3.5
7.7
3.6
1.5
2.7
2.8
X
iemov
99
98
98
97
97
97
95
98
99
96
97
96
92
94
97
97
95
97
97
96
96
96
93
94
71
61
80
96
96
* Percent Total Solids
120
-------
TOTAL SUSPENDED SOLIDS (mg/L) - UNACCLIMATED SYSTEM
DATE
(MM-DD)
01-Aug
02-Aug
03-Aug
04-Aug
05-Aug
06-Aug
07-Aug
08-Aug
09-Aug
10-Aug
11-Aug
12-Aug
13-Aug
14-Aug
15-Aug
16-Aug
17-Aug
18-Aug
19-Aug
20-Aug
21-Aug
22-Aug
23-Aug
24-Aug
25-Aug
26-Aug
27-Aug
28-Aug
29-Aug
30-Aug
31-Aug
AVERAGE
DEVIATION
PR I
INF
252
253
292
276
262
323
307
271
242
205
254
272
184
76
182
216
184
296
76
236
268
292
228
240
236
252
200
286
93
PR I
EFF
112
105
132
128
142
75
167
227
134
133
86
140
72
68
122
76
84
124
64
88
100
104
108
96
100
104
76
105
34
SEC
EFF
11
8
10
32
38
7
8
11
10
8
6
14
6
15
12
7
13
11
12
20
19
6
13
59
10
13
9
14
15
MIX
LIQ
5660
4211
4040
4670
3468
3183
3219
3363
3422
4171
5418
2360
3820
4034
4742
3550
3650
5410
5090
4580
4660
3670
6150
5720
5290
5670
6230
3891
992
SEC
WAS
13940
9080
8858
10103
9819
9963
12802
11621
11238
12230
11940
12964
15682
13680
9300
17280
15510
12760
13900
12040
16440
20930
13040
14040
16220
11607
2226
P
S
2
3
1
3
3
3
3
3
1
4
2
6
8
8
6
5
6
3
3
3
2
1
3
0
3
3
2
*
RI
LU
.3
.3
.5
.1
.5
.0
.1
.5
.7
.0
.1
.2
.8
.7
.8
.8
.9
.9
.7
.7
.4
.0
.0
.4
.5
.6
.0
X
Remov
96
97
97
88
85
98
97
96
96
96
98
95
97
80
93
97
93
96
84
92
93
98
94
75
96
95
95
94
6
* Percent Total Solids
121
-------
COO/SCOO DATA - UNACCLlMATED SYSTEM
Date
(MM-DD)
01-Jun
02-Jun
03-Jun
04-Jun
05-Jun
06-Jun
07-Jun
08-Jun
09-Jun
10-Jun
11-Jun
12-Jun
13-Jun
14-Jun
15-Jun
16-Jun
17-Jun
18-Jun
19-Jun
20-Jun
21-Jun
22-Jun
23-Jun
24-Jun
25-Jun
26-Jun
27-Jun
28-Jun
29-Jun
30-Jun
PR I
INF
mg/L
381
767
780
950
859
730
415
751
641
741
566
629
TOTAL
PRI
EFF
mg/L
495
456
548
799
424
532
452
462
358
395
395
449
COO
SEC
EFF
mg/L
107
97
83
79
57
86
291
73
64
83
72
80
X
Remov
72
87
89
92
93
88
30
90
90
89
87
87
PRI
INF
mg/L
309
307
351
319
304
149
323
241
401
290
268
SOLUBLE
PRI SEC
EFF EFF
mg/L mg/L
302
245
286
325
165
260
296
268
327
215
263
114
71
51
61
96
104
56
68
87
60
66
COO
X
Remov
63
77
85
81
68
30
83
72
78
79
75
122
-------
COD/SCOD DATA - UNACCLIMATED SYSTEM
Date
(MM-DD)
01-Jul
02-Jul
03-Jul
04-Jut
05-Jul
06-Jul
07-Jul
08-Jul
09-Jul
10-Jul
11-Jul
12-Jul
13-Jul
14-Jul
15-Jul
16-Jul
17-Jul
18-Jul
19-Jul
20-Jul
21-Jul
22-Jul
23-Jul
24-Jul
25-Jul
26-Jul
27-Jul
28-Jul
29-Jul
30-Jul
31-Jul
PR I
INF
mg/L
679
766
824
675
520
442
579
526
310
680
769
728
532
TOTAL
PR I
EFF
mg/L
482
295
601
551
370
384
480
419
258
536
462
502
415
COD
SEC
EFF
mg/L
79
46
68
71
37
47
45
55
55
60
70
180
95
x |PRI
Remov|INF
I mg/L
88
94
92
89
93
89
92
90
82
91
91
75
82
230
123
292
216
124
330
309
180
118
240
294
303
253
SOLUBLE COD
PRI SEC X
EFF EFF Remov
mg/L mg/L
261
84
340
259
166
363
303
176
119
267
271
260
250
61
31
67
52
35
52
65
48
37
85
56
50
49
73
75
77
76
72
84
79
73
69
65
81
83
81
123
-------
COO/SCOO DATA - UNACCLIMATED SYSTEM
1
Date |
| PR!
(MM-DD) | INF
|mg/L
1
01-Aug | 533
02-Aug |
03-Aug 620
04-Aug
05-Aug 646
06-Aug
07-Aug
08-Aug
09-Aug
10-Aug
11-Aug
12-Aug
13-Aug
14-Aug
15-Aug
16-Aug
17-Aug
18-Aug
19-Aug
20-Aug
21-Aug
22-Aug
23-Aug
24-Aug
25-Aug
26-Aug
27-Aug
28-Aug
29-Aug
30-Aug
31-Aug
AVERAGE
DEVIATION
804
662
509
551
498
446
589
679
702
517
896
638
144
TOTAL
PR I
EFF
mg/L
381
444
482
585
556
416
462
448
384
408
493
492
384
692
465
98
COD
SEC
EFF
mg/L
63
56
77
56
59
62
51
67
59
86
83
59
72
80
77
42
SOLUBLE COD
I
X PRI
RemovjINF
I mg/L
88 237
91 247
88 329
93 255
91 299
88 226
91
87
87
85
88
92
86
91
87
10
272
250
227
234
369
182
246
256
78
PRI
EFF
mg/L
218
242
264
274
268
238
264
285
225
261
397
160
252
249
71
SEC
EFF
mg/L
43
46
51
39
57
69
45
53
53
62
70
37
93
64
21
X
Remov)
82
81
84
85
81
69
83
79
77
74
81
80
62
74
11
124
-------
NITROGEN DATA (mg/L) - UNACCLIHATED SYSTEM
Date
(DD-HM)
01-Jun
02-Jun
03-Jun
04-Jun
05-Jun
06-Jun
07-Jun
08-Jun
09-Jun
10-Jun
11-Jun
12-Jun
13-Jun
14-Jun
15-Jun
16-Jun
17-Jun
18-Jun
19-Jun
20-Jun
21-Jun
22-Jun
23-Jun
24-Jun
25-Jun
26-Jun
27-Jun
28-Jun
29-Jun
30-Jun
AMHONIA-N
PRI PRI SEC X
INF EFF EFF Remov
mg/L mg/L mg/L
27 30
33 31
37 34
21 22
27 27
32 32
27 32
37 34
37 36
28 32
32 23
0.5 98
0.4 99
1.4 96
0.5 98
0.3 99
0.3 99
0.3 99
0.4 99
0.3 99
0.6 98
0.3 99
NITRATE-N
PRI PRI SEC
INF EFF EFF
mg/L mg/L mg/L
0.00 0.00
0.29 0.18
0.30 0.27
0.28 0.22
0.23 0.19
0.12 0.00
5.76 0.00
0.13 0.00
0.21 0.17
0.19 0.17
0.25 0.24
0.29 0.23
27
22
20
13
19
19
9
25
31
31
35
17
125
-------
NITROGEN DATA (mg/L) - UNACCLIMATED SYSTEM
Date
(DD-MM)
01-Jul
02-Jul
03-Jul
04-Jul
05-Jul
06-Jul
07-Jul
08- Jut
09-Jul
10-Jul
11-Jul
12-Jul
13-Jul
14-Jul
15-Jul
16-Jul
17-Jul
18-Jul
19-Jul
20-Jul
21-Jul
22-Jul
23-Jul
24-Jul
25-Jul
26-Jul
27-Jul
28-Jul
29-Jul
30-Jul
31-Jul
PR I
INF
mg/L
19
14
30
21
29
42
25
25
9
28
40
47
27
AMHONIA-N
PR I SEC
EFF EFF
mg/L mg/L
20
12
28
22
32
36
25
23
9
28
39
40
27
0.2
0.5
0.6
0.5
0.4
0.6
0.3
0.3
0.1
4.9
0.8
0.6
0.4
X
Remov
99
97
98
97
99
99
99
99
98
82
98
99
99
NITRATE-N
PRI PRI SEC
INF EFF EFF
mg/L mg/L mg/L
0.16
0.16
0.26
0.21
0.16
0.18
0.16
0.00
0.10
0.10
0.15
0.11
0.09
0.14
0.09
0.24
0.19
0.12
0.14
0.11
0.00
0.00
0.00
0.00
0.00
0.10
14
17
14
13
22
20
16
16
10
6
27
19
11
126
-------
NITROGEN DATA (mg/L) - UNACCLIMATED SYSTEM
Date
(DD-MH)
01-Aug
02-Aug
03-Aug
04-Aug
05-Aug
06-Aug
07-Aug
08-Aug
09-Aug
10-Aug
11-Aug
12-Aug
13-Aug
14-Aug
15-Aug
16-Aug
17-Aug
18-Aug
19-Aug
20-Aug
21-Aug
22-Aug
23-Aug
24-Aug
25-Aug
26-Aug
27-Aua
28-Aug
29-Aug
30-Aug
31-Aug
AVERAGE
DEVIATION
AHMONIA-N
PRI PRI SEC X
INF EFF EFF Remov
mg/L mg/L mg/L
28 29 0.5 98
33 33 0.6 98
29 31 0.5 98
32 31 0.7 98
24 23 0.6 97
22 25 0.5 98
25 27 0.5 98
29 30 0.4 99
25 28 0.4 98
28 28 0.6 98
7 6 0.8 3
NITRATE-N
PRI PRI SEC
INF EFF EFF
mg/L mg/L mg/L
0.17 0.10 24
0.18 0.11 20
0.00 0.00 17
0.13 0.12 26
0.14 0.00 22
0.00 0.00 20
0.10 0.10 26
0.14 0.00 14
0.10 0.00 19
0.11 0.00 20
0.31 0.09 19
0.94 0.09 6
127
-------
ro
00
I
a
8
EFFECT OF CERCLA TOXICS ON COD REMOVAL
100
• UNACCLIMATED
Arrows Indicate Intermittent tplke days.
ill ill j-t n TTi-riT|'T»tTT f rrryi ri i t i i i i-| i-ri riTrr«-|Tt i i i rrri p i n i m-r|-i
31 41 51
TIME (days)
61 71
+ ACCLIMATED
61
91
-------
EFFECT OF CERCLA TOXICS ON NITRIFICATION
100 -p*-*--A-^Ff.
90 -, V
80 -i
d 60 -
i !
K 3 50 J
vo tc.
30 -J
I
20 -j
!
i
10
TIME (days)
• ACCLIMATED + UNACCLJMATED
Arrows indicate intermittent spike days.
0 •'j i i i rr r?-rrp-rrl n T-rrjTT'm rt 11 11 11 i i i i i i | i i ITT-I i I i | rr ri ~t rri-ryrr-r i rii rrj i rrrrt rr-»-|T-rr n tt-rrp
1 11 21 31 41 51 61 71 81 91
-------
TOTAL SUSPENDED SOLIDS
-------
TOTAL SUSPENDED SOLIDS (mg/L) - UNACCLlHATED SYSTEH
DATE
(MM-DD)
01-Aug
02-Aug
03-Aug
04-Aug
05-Aug
06-Aug
07-Aug
08-Aug
09-Aug
10-Aug
11-Aug
12-Aug
13-Aug
14-Aug
15-Aug
16-Aug
17-Aug
18-Aug
19-Aug
20-Aug
21-Aug
22-Aug
23-AU9
24-Aug
25-Aug
26-Aug
27-Aug
28-Aug
29-Aug
30-Aug
31-Aug
AVERAGE
DEVIATION
PR I
INF
252
253
292
276
262
323
307
271
242
205
254
272
184
76
182
216
184
296
76
236
268
292
228
240
236
252
200
286
93
PR I
EFF
112
105
132
128
142
75
167
227
134
133
86
140
72
68
122
76
84
124
64
88
100
104
108
96
100
104
76
105
34
SEC
EFF
11
8
10
32
38
7
8
11
10
8
6
14
6
15
12
7
13
11
12
20
19
6
13
59
10
13
9
14
15
MIX
LIO
5660
4211
4040
4670
3468
3183
3219
3363
3422
4171
5418
2360
3820
4034
4742
3550
3650
5410
5090
4580
4660
3670
6150
5720
5290
5670
6230
3891
992
SEC
WAS
13940
9080
8858
10103
9819
9963
12802
11621
11238
12230
11940
12964
15682
13680
9300
17280
15510
12760
13900
12040
16440
20930
13040
14040
16220
11607
2226
P
S
2
3
1
3
3
3
3
3
1
4
2
6
8
8
6
5
6
3
3
3
2
1
3
0
3
3
2
fc
RI
LU
.3
.3
.5
.1
.5
.0
.1
.5
.7
.0
.1
.2
.8
.7
.8
.8
.9
.9
.7
.7
.4
.0
.0
.4
.5
.6
.0
X
Remov
96
97
97
88
85
98
97
96
96
96
98
95
97
80
93
97
93
96
84
92
93
98
94
75
96
95
95
94
6
* Percent Total Solids
131
-------
COO/SCOO DATA - UNACCLIMATED SYSTEM
Date
(MM-DD)
01-Jun
02-Jun
03-Jun
04-Jun
05-Jun
06-Jun
07-Jun
08-Jun
09-Jun
10-Jun
11-Jun
12-Jun
13-Jun
14-Jun
15-Jun
16-Jun
17-Jun
18-Jun
19-Jun
20-Jun
21-Jun
22-Jun
23-Jun
24-Jun
25-Jun
26-Jun
27-Jun
28-Jun
29-Jun
30-Jun
TOTAL COD
PRI PRI SEC %
INF EFF EFF Remov
mg/L mg/L mg/L
381 495 107 72
767 456 97 87
780 548 83 89
950 799 79 92
859 424 57 93
730 532 86 88
415 452 291 30
751 462 73 90
641 358 64 90
741 395 83 89
566 395 72 87
629 449 80 87
SOLUBLE COD
PRI PRI SEC %
INF EFF EFF Remov
mg/L mg/L mg/L
309 302 114 63
307 245 71 77
351 286 51 85
319 325 61 81
304 165 96 68
149 260 104 30
323 296 56 83
241 268 68 72
401 327 87 78
290 215 60 79
268 263 66 75
132
-------
COO/SCOO DATA - UNACCLIMATED SYSTEM
Date
(MM-DD)
01-Jul
02-Jul
03-Jul
04-Jul
05-Jul
06-Jul
07-Jul
08-Jul
09-Jul
10-Jul
11-Jul
12-Jul
13-Jul
U-Jul
15-Jul
16-Jul
17-Jul
18-Jul
19- Jut
20-Jul
21-Jul
22-Jul
23-Jul
24-Jul
25-Jul
26-Jul
27-Jul
28-Jul
29-Jul
30- Jut
31-Jul
PR!
INF
mg/L
679
766
824
675
520
442
579
526
310
680
769
728
532
TOTAL COD
PR! SEC
EFF EFF
mg/L mg/L
482
295
601
551
370
384
480
419
258
536
462
502
415
79
46
68
71
37
47
45
55
55
60
70
180
95
% |PRI
Remov | INF
| mg/L
88
94
92
89
93
89
92
90
82
91
91
75
82
230
123
292
216
124
330
309
180
118
240
294
303
253
SOLUBLE
PR I SEC
EFF EFF
mg/L mg/L
261
84
340
259
166
363
303
176
119
267
271
260
250
61
31
67
52
35
52
65
48
37
85
56
50
49
COD
%
Remov
73
75
77
76
72
84
79
73
69
65
81
83
81
133
-------
. COD/SCOD DATA - UNACCLIMATED SYSTEM
Date
(MM-DD)
01-Aug
02-Aug
03-Aug
04-Aug
05-Aug
06-Aug
07-Aug
08-Aug
09-Aug
10-Aug
11-Aug
12-Aug
13-Aug
14-Aug
15-Aug
16-Aug
17-Aug
18-Aug
19-Aug
20-Aug
21-Aug
22-Aug
23-Aug
24-Aug
25-Aug
26-Aug
27-Aug
28-Aug
29-Aug
30-Aug
31-Aug
AVERAGE
DEVIATION
TOTAL COO |
PR I
INF
mg/L
533
620
646
804
662
509
551
498
446
589
679
702
517
896
638
144
PR I
EFF
mg/L
381
444
482
585
556
416
462
448
384
408
493
492
384
692
465
98
SEC
EFF
mg/L
63
56
77
56
59
62
51
67
59
86
83
59
72
80
77
42
x |PRI
RemovjINF
88
91
88
93
91
88
91
87
87
85
88
92
86
91
87
10
mg/L
237
247
329
255
299
226
272
250
227
234
369
182
246
256
78
SOLUBLE
PR I
EFF
mg/L
218
242
264
274
268
238
264
285
225
261
397
160
252
249
71
SEC
EFF
mg/L
43
46
51
39
57
69
45
53
53
62
70
37
93
64
21
COO
%
Remov
82
81
84
85
81
69
83
79
77
74
81
80
62
74
11
134
-------
NITROGEN DATA (mg/L) - UNACCLIMATED SYSTEM
Date
(DD-MH)
01-Jun
02-Jun
03-Jun
04-Jun
05-Jun
06-Jun
07-Jun
08-Jun
09-Jun
10-Jun
11-Jun
12-Jun
13-Jun
U-Jun
15-Jun
16-Jun
17-Jun
18-Jun
19-Jun
20-Jun
21-Jun
22-Jun
23-Jun
24-Jun
AMHONIA-N
PRI PRI SEC X
INF EFF EFF Remov
mg/L mg/L mg/L
27 30
33 31
37 34
21 22
27 27
32 32
27 32
37 34
37 36
25-Jun |
26-Jun
27-Jun 28 32
28-Jun |
29-Jun
30-Jun
32 23
0.5 98
0.4 99
1.4 96
0.5 98
0.3 99
0.3 99
0.3 99
0.4 99
0.3 99
0.6 98
0.3 99
NITRATE-N
PRI PRI
INF EFF
mg/L mg/L
0.00 0.00
0.29 0.18
0.30 0.27
0.28 0.22
0.23 0.19
0.12 0.00
5.76 0.00
0.13 0.00
0.21 0.17
0.19 0.17
0.25 0.24
0.29 0.23
SEC
EFF
mg/L
27
22
20
13
19
19
9
25
31
31
35
17
135
-------
NITROGEN DATA (mg/L) - UNACCLIMATED SYSTEM
Date
(DD-MM)
01-Jul
02-Jul
03-Jul
04-Jul
05-Jut
06-Jul
07-Jul
08-Jul
09-Jul
10-Jul
11-Jul
12-Jul
13-Jul
14-Jul
15-Jul
16-Jul
17-Jul
18-JuL
PR I
INF
mg/L
19
14
30
21
29
42
25
25
19-Jul
20-Jul 9
21-Jul
22-Jul 28
23-Jul
24-Jul
25-Jul 40
26-Jul
27-Jul 47
28-Jul
29- Jut 27
30-Jul
31-Jul
AMMONIA-N
PR I SEC
EFF EFF
mg/L mg/L
20
12
28
22
32
36
25
23
9
28
39
40
27
0.2
0.5
0.6
0.5
0.4
0.6
0.3
0.3
0.1
4.9
0.8
0.6
0.4
%
Remov
99
97
98
97
99
99
99
99
98
82
98
99
99
NITRATE-N
PRI PRI
INF EFF
mg/L mg/L
0.16
0.16
0.26
0.21
0.16
0.18
0.16
0.00
0.10
0.10
0.15
0.11
0.09
0.14
0.09
0.24
0.19
0.12
0.14
0.11
0.00
0.00
0.00
0.00
0.00
0.10
SEC
EFF
mg/L
14
17
14
13
22
20
16
16
10
6
27
19
11
136
-------
NITROGEN DATA (mg/L) - UNACCLIMATED SYSTEM
Date
(DD-MM)
01-Aug
02-Aug
03-Aug
04-Aug
05-Aug
06-Aug
07-Aug
08-Aug
09-Aug
10-Aug
11-Aug
12-Aug
13-Aug
14-Aug
15-Aug
16-Aug
17-Aug
18-Aug
19-Aug
20-Aug
21-Aug
22-Aug
23-Aug
24-Aug
25-Aug
26-Aug
27-Aug
28-Aug
29-Aug
30-Aug
31-Aua
AVERAGE
DEVIATION
AMMONIA-N
PRI PRI SEC X
INF EFF EFF Remov
mg/L mg/L mg/L
28 29 0.5 98
33 33 0.6 98
29 31 0.5 98
32 31 0.7 98
24 23 0.6 97
22 25 0.5 98
25 27 0.5 98
29 30 0.4 99
25 28 0.4 98
28 28 0.6 98
7 6 0.8 3
NITRATE-N
PRI PRI SEC
INF EFF EFF
mg/L mg/L mg/L
0.17 0.10 24
0.18 0.11 20
0.00 0.00 17
0.13 0.12 26
0.14 0.00 22
0.00 0.00 20
0.10 0.10 26
0.14 0.00 14
0.10 0.00 19
0.11 0.00 20
0.31 0.09 19
0.94 0.09 6
137
-------
00
o
o
o
EFFECT OF CERCLA TOXICS ON COD REMOVAL
100
90 -
80 -
70 -
60 -
50 -
40 -
30 -
20 -
10 -
0
(Revised)
'"' i'"'''''' 11''' 111111111111111* 111111111111111111111111111 /11111111111111
11 21 31 41 51 61 71 81 91
• ACCLIMATED
Arrows indicate intermittent spike days.
TIME (days)
+ UNACCLIMATED
-------
EFFECT OF CERCLA TOXICS ON NITRIFICATION
3
a
K
O
20 H
10-i
rl f
A
0 "ji i iTTirrTfrrrl ft TTifrTTTT Tt I i | i I m r r i i [ i i i T-rn 11'| 11 ri T rm-jTrr r n i rrj i rrrrt rr-iynT r-i tT-rrp)
1 11 21 31 41 51 61 71 81 91
TIME (days)
• ACCLIMATED + UNACCUMATED
Arrows indicate intermittent spike days.
-------
APPENDIX 4. QUALITY ASSURANCE SUMMARY
140
-------
Appendix 4. QA/QC Overview
This report combines results from two projects "RCRA Pilot Scale Study of
Toxics Removal" and "CERCLA Pilot Scale Study of Toxics Removal." Each project
spiked municipal wastewater with mixtures containing multiple organic toxic
chemicals having different physical, chemical and biological properties. These
properties affected the overall removals and partitioning of the chemicals as
well as the reliability of analytical results. Data for each chemical must be
evaluated separately since broad generalizations do not apply.
Major changes were necessary in the planned QA for the RCRA project.
Analytical work was transferred from in-house to a contractor where different
methodology was used in the work assignment. Stable labeled isotopes were not
used and measured concentrations could not be corrected for recoveries, although
recoveries were measured for samples spiked in the laboratory with surrogate
toxics.
Poor closure of material balances around the process units was observed
and was caused at least partially by lack of recovery corrections. Fractions
of volatile toxics in air emissions had to be based on actual toxics fed to the
wastewater rather than on measured influent concentrations. If measured influent
concentrations were used, analytical recoveries of essentially 100% from air
coupled with the lower recoveries from liquid samples resulted in apparent
fractions of some volatile compounds in air approaching 200%.
It was necessary to exclude by inspection some concentration values which
did not "fit" the data set. For example, where concentrations of a single
chemical in duplicate field samples were quite different, the concentration
values were compared to concentrations from preceding and following sample points
in the same sample event, to concentrations at the same sample point from other
sample events and if necessary to calculated feed concentrations to decide which
duplicate to exclude or if all data were highly variable to simply average the
two duplicates. If concentrations of all organics in one sample were much higher
or lower than in comparable samples, then a decision was made to exclude or
retain an entire sample rather than just individual chemical concentrations.
In effluent samples where concentrations were generally quite low, large relative
differences between samples were generally not significant since the associated
masses of chemicals represented only a small fraction of the total mass of
chemical added. Therefore most effluent concentrations were retained despite
high relative percent differences between duplicates.
Of 29 RCRA toxics in the spike, valid data were reported for only 25
compounds. Table 4-1 shows percent recoveries of laboratory-spiked surrogates
and relative percent differences between laboratory-spiked duplicates. Table
4-2 shows the percent of RCRA sampling events providing usable data and Tables
4-3 and 4-4 show a summary of relative percent differences for duplicate field
samples.
141
-------
In the CEr ~|_A project, data collection generally proceeded as planned using
the in-house laboratory. Stable labeled isotopes of each spiked chemical were
added to every sample and measured analytical values were corrected for
recoveries obtained for the labeled compounds. Despite the improved analytical
methodology, some chemicals still did not appear to be quantitatively measured
in sludge samples, either because of poor separation from the sludge and
wastewater matrix or because of degradation before analysis. Where sludge data
showed major discrepancies with removal data based on the wastewater analyses,
the sludge data were excluded from partitioning calculations.
Of 22 CERCLA toxics in the spike, valid data were reported for 19
compounds. Table 4-5 shows the percent of CERCLA sampling events providing
usable data and Tables 4-6 and 4-7 show a summary of relative percent differences
for duplicate field samples.
142
-------
TABLE 4-1. SUMMARY OF RCRA RESULTS - PERCENT RECOVERIES OF LABORATORY - SPIKED
SURROGATES AND RELATIVE PERCENT DIFFERENCES (RPD) BETWEEN LABORATORY
SPIKED DUPLICATES.
Event 3
Volatiles
Semivolatiles
Event 4
Volatiles
Semivolatiles
Event 5
Volatiles
Semivolatiles
All 3 Events
Volatiles
Semivolatiles
Recoveries* RPD Range
19 out of 159: outside of QC limits 3-5
63 out of 216: outside of QC limits 0-39
Recoveries RPD Range
6 out of 165: outside of QC limits 0-18
34 out of 162: outside of QC limits 0-30
Recoveries RPD Range
1 out of 102: outside of QC limits 2-5
51 out of 192: outside of QC limits 0-9
Recoveries
26 out of 426: outside of QC limits (6%)
148 out of 570: outside of QC limits (26%)
*Range of acceptable recoveries was 61% - 145% for volatiles and 9% - 131% for
Semivolatiles.
143
-------
TABLE 4-2. PERCENT OF SAMPLING EVENTS PROVIDING DATA USABLE FOR
CALCULATION OF TOTAL REMOVAL AND PARTITIONING OF 25
RCRA TOXICS FROM THREE ACCLIMATED EVENTS AND THREE
UNACCLIMATED EVENTS
RCRA Toxic
Acetone
Cyclohexanone
2-butanone
4-methy 1 -2-pentanone
Tetrahydrofuran
Carbon tetrachloride
Chlorobenzene
Chloroform
1 ,2-di chl oroethane
1 , 2-di chl oropropane
Methylene chloride
Tetrach 1 oroethy 1 ene
Tri chl oroethy 1 ene
1,1,1-tri chl oroethane
1,1,2-tri chl oroethane
Ethyl benzene
Toluene
Total xylenes
Bis (2-ethylhexyl) phthalate
Butyl benzyl phthalate
1 , 4-di ch 1 orobenzene
Naphthalene
Nitrobenzene
4-nitrophenol
Phenol
Accl
Removal
100
0
67
67
100
100
100
100
67
100
100
100
100
100
100
100
100
100
100
100
100
100
100
0
100
i mated
Partitioning
100
0
67
67
100
100
100
100
67
100
*
100
100
100
100
100
100
100
100
100
100
100
100
0
100
Unaccl
Removal
100
33
67
67
67
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
67
100
100
33
100
i mated
Partitioning
100
33
67
67
67
100
100
100
100
100
*
100
100
100
100
100
100
100
100
100
67
100
100
33
100
*Methylene chloride used as preservative in sludge samples.
144
-------
TABLE 4-3. SUMMARY OF RELATIVE PERCENT DIFFERENCES FOR RCRA DATA - ACCLIMATED SYSTEM
RCRA Toxic/Event
Acetone
Cyclohexanone
Furfural
2-butanone
4-methyl -2-pentanone
Tetrahydrofuran
Carbon tetrachloride
Chlorobenzene
Chloroform
1,2-dichloroethane
1,2-dichloropropane
Methylene chloride
Tetrachl oroethyl ene
Trichloroethyl ene
1,1,1-trichloroethane
1,1,2-trichloroethane
Ethyl benzene
Toluene
Total Xylenes
Bis (2-ethylhexyl) phthalate
Buryl benzyl phthal ate
1 ,4-dicholorobenzene
2, 4-dimethyl phenol
2,4-dinitrophenol
Naphthalene
Nitrobenzene
4-nitrophenol
Phenol
Primary Influent
3 5
31 54
25
27
25 10
29
2 9
6 6
8
12
27 14
3 18
3 14
11
10 13
5 13
1 12
8 11
8 20
24 70
0 17
0
6
6 63
Primary
Effluent
3
63
10
3
0
4
0
4
1
3
2
4
5
0
5
0
3
31
0
0
13
6
Secondary
Effluent
4
54
0
0
0
67
0
47
53
43
52
15
48
122
0
22
22
0
0
0
0
0
0
Primary
Sludge
3
93
29
5
0
3
10
4
6
3
7
5
21
2
17
37
79
14
31
82
0
Secondary
Sludge
5
75
0
33
157
0
0
0
0
0
0
0
6
0
0
0
31
0
15
0
113
0
Primary
Air
4
0
50
0
100
0
0
0
0
0
0
0
0
0
0
0
0
0
-------
TABLE 4-4. SUMMARY OF RELATIVE PERCENT DIFFERENCES FOR RCRA DATA - UNACCLIMATED SYSTEM
RCRA Toxic/Event
Acetone
Cyclohexanone
Furfural
2-butanone
4-methyl -2-pentanone
Tetrahydrofuran
Carbon tetrachloride
Chlorobenzene
Chloroform
1,2-dichloroethane
1,2-dichloropropane
Methyl ene chloride
Tetrachl oroethyl ene
Trichloroethylene
1,1,1-trichloroethane
1,1,2-trichloroethane
Ethyl benzene
Toluene
Total xylenes
Bis (2-ethylhexyl ) phthalate
Butyl benzyl phthalate
1,4-dichlorobenzene
2 ,4-dimethyl phenol
2,4-dinitrophenol
Naphthalene
Nitrobenzene
4-nitrophenol
Phenol
Raw
Waste-
water
4
0
8
0
0
51
15
0
10
6
57
37
0
0
0
0
10
Primary
Influent
3 4 5
11 7 6
16
2 13
17 7
0
59 3 26
38 10 17
5 22 6
0 2 7
13 4 7
3 16
049
087
0 0 16
0 7 13
098
0 7 14
067
8 18
9 8
14 16
0 9
7 17
0
8 31
Primary
Effluent
3 5
28 3
0
0
1 0
46 8
15
9 0
13 0
13 0
41 4
8 8
18 9
0 0
9 0
0 6
0 0
10 10
0 19
0 35
59
0 5
50 10
0
0 0
Secondary
Effluent
5
123
0
3
40
22
0
3
5
11
0
22
29
0
67
22
46
0
0
0
0
0
Primary
Sludge
3
14
24
35
10
6
0
9
8
0
15
26
0
0
12
165
38
15
35
31
166
0
92
Secondary
Sludge
4
0
0
0
0
0
0
34
0
6
40
0
0
5
29
29
0
186
0
5
0
67
0
Oi
-------
TABLE 4-5. PERCENT OF SAMPLING EVENTS PROVIDING DATA USABLE
FOR CALCULATION OF TOTAL REMOVAL AND PARTITIONING
OF 19 CERCLA TOXICS FROM 11 ACCLIMATED EVENTS AND
4 UNACCLIMATED EVENTS
CERCLA Toxic
Dichlorobenzene, probably 1,2
Dichlorobenzene, probably 1,3
Dichlorobenzene, probably 1,4
1 , 2, 4-Tri chl orobenzene
Nitrobenzene
1,3-Di nitrobenzene
2,6-Dinitrotoluene
p-cresol
4-Choloroaniline
Hexachl oroethane
Hexachl orobutad i ene
Dimethyl phthalate
Diethyl phthalate
Di butyl phthalate
Butyl benzyl phthalate
Bis (2-ethylhexyl) phthalate
Naphthalene
Lindane
Dieldrin
Acclimated Unacclimated
Removal Partitioning Removal Partitioning
91
100
100
82
91
55
91
91
73
100
100
91
100
100
100
36
100
82
91
73
73
73
55
73
0
18
82
45
9
27
91
100
73
64
27
73
82
36
100
100
100
75
100
100
100
75
0
75
100
100
100
100
100
0
100
100
100
100
100
100
50
75
0
0
25
0
0
25
50
50
25
50
0
50
75
50
147
-------
TABLE 4-6. SUMMARY OF RELATIVE PERCENT DIFFERENCES FOR CERCLA DATA - ACCLIMATED SYSTEM
CERCLA Toxic/Event
Dichlorobenzene, probably 1,2
Dichlorobenzene, probably 1,3
Dichlorobenzene, probably 1,4
1,2,4-Trichlorobenzene
Nitrobenzene
1,3-Di nitrobenzene
2,6-Dinitrotoluene
p-cresol
4-Choloroaniline
Hexachloroethane
Hexachloro butadiene
Dimethyl phthalate
Diethyl phthalate
Di butyl phthalate
Butyl benzyl phthalate
Bis (2-ethylhexyl) phthalate
Naphthalene
Lindane
Dieldrin
Raw
9
0
13
4
2
46
56
5
1
22
13
2
4
10
0
80
Wastewater
10 11
22
22
22
9
97
0
148
4
111
200
0
20
19
1
7
0
22
133
106
125
15
200
39
0
32
120
0
148
200
108
83
94
76
200
115
1 2
2
3 13
6 1
5 23
4
1 27
5
6 6
14 7
3 4
3 6
3 5
10 3
1 8
18
12 4
13 20
51
Primary
5
8
8
13
17
6
5
1
2
9
7
19
2
9
11
23
12
13
22
Infl
6
9
12
8
8
5
4
1
7
4
6
13
2
3
4
12
14
7
5
uent
8
13
12
12
6
10
25
9
3
9
4
5
6
1
42
10
7
9
5
23
3
19
4
3
13
3
6
2
8
5
3
10
11
0
2
2
15
6
11
5
1
8
6
2
0
5
6
16
12
3
Pri.
Eff.
10
12
0
5
4
1
2
1
6
1
9
9
11
56
4
5
13
Secondary
Effluent
1 6 11
17 26 10
4 13 10
67 46 40
6 11
10 18 14
40 15 0
533
79 57
0 36 12
200 29 22
29 46 40
150 156 100
150 108 86
0 32 50
29 25 67
150 133 40
0 5 13
14 11 51
00
Continued next page
-------
TABLE 4-6. (CON'T)
SUMMARY OF RELATIVE PERCENT DIFFERENCES FOR CERCLA DATA -
ACCLIMATED SYSTEM
10
CERCLA Toxic/Event
Dichlorobenzene, probably 1,2
Dichlorobenzene, probably 1,3
Dichlorobenzene, probably 1,4
1 ,2,4-Trichlorobenzene
Nitrobenzene
1 ,3-Dinitrobenzene
2,6-Dinitrotoluene
p-cresol
4-Choloroaniline
Hexachloroethane
Hexac hi oro butadiene
Dimethyl phthalate
Di ethyl phthalate
Di butyl phthalate
Butyl benzyl phthalate
Bis (2-ethylhexyl ) phthalate
Naphthalene
Lindane
Dieldrin
4
15
16
15
5
39
170
200
21
20
0
12
29
15
20
18
10
16
19
0
Primary
7
40
19
3
200
200
11
32
16
3
13
20
Sludge
9
16
17
17
17
38
9
200
19
19
22
17
19
17
12
11
0
5
0
5
139
121
200
14
46
200
5
67
38
5
14
4
12
33
1
3
6
16
19
18
200
38
8
0
3
0
21
1
9
9
5
85
Secondary SI
3 4
9
45
13
14
69
0
60
0
200
24
200
200
81
112
200
25
54
15
0
86
2
0
0
0
61
0
200
29
0
13
10
0
4
40
7
75
udge
6
83
18
75
4
57
28
10
133
40
200
4
105
56
19
25
62
3
73
8
31
32
29
4
0
13
0
0
5
0
1
0
200
27
91
25
4
85
56
-------
TABLE 4-7.'SUMMARY OF RELATIVE PERCENT DIFFERENCES FOR CERCLA DATA - UNACCLIMATED SYSTEM
Raw Wastewater
CERCLA Toxic/Event 1 2 3
Dichlorobenzene, probably 1,2 0 0 50
DichTorobenzene, probably 1,3 0 0 25
Di.chlorobenzene, probably 1,4 200 200 13
1,2,4-Trichlorobenzene 85 85 4
Nitrobenzene 200 200 40
1,3-Di nitrobenzene 200 200 30
2,6-Dinitrotoluene 000
p-cresol 4 7
4-Choloroaniline
Hexachloroethane 000
Hexachlorobutadiene 0 0 200
Dimethyl phthalate 000
Diethyl phthalate 25 25 7
Dibutyl phthalate 51 52 7
Butyl benzyl phthalate 000
Bis (2-ethylhexyl ) phthalate
Naphthalene 114 114 11
Lindane 200 200 8
Dieldrin 80 80 10
Pri.
Inf.
4
11
11
11
14
4
9
1
24
5
2
23
14
1
16
35
Primary
Effluent
1 3
31 1
30 0
22 4
19 3
2 4
19 43
9
3
41 16
17 2
44
2 8
16 9
5 7
4
2
9 16
Sec.
Eff.
3
6
4
6
2
3
100
6
0
0
29
200
11
17
25
0
1
35
Primary
Sludge
3 4
9 173
10 26
13 95
2
49 200
17 0
200 0
11 200
200
0 200
13 54
8 82
13 95
17 97
1,2, 0
13 87
8 200
Secondary
Sludge
2 3
22 43
47 34
44 0
47 3
12 0
3 53
0 0
0
0 0
54 10
0 0
10 200
1 200
47 22
40 40
46 0
71 7
01
o
------- |