PB89-195200
600-2-89-026
                                          U.S. Environmental Protection Agency
                                          Great Lakes National Program Office
                                                    GLNPO Library
   REMOVAL AND FATE OF RCRA  AND CERCLA
   TOXIC ORGANIC POLLUTANTS  IN WASTEWATER
   TREATMENT
   University  of Cincinnati
   Cincinnati,  OH
   Jun 89
                 U.S. DEPARTMENT OF COMMERCE
              National Technical Information Service

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                                                                        PB89-195200

                                                                      EPA/600/2-89/026
                                                                      June 1989
-4                         REMOVAL AND  FATE  OF  RCRA AND CERCLA TOXIC ORGANIC


                                  POLLUTANTS IN  WASTEWATER TREATMENT
                                                   by
                             Sanjoy K. Bhattacharya  and  Rao V.  R.  Angara
                          Department of Civil  and  Environmental  Engineering
                                       University  of Cincinnati
                                       Cincinnati, Ohio   45221

                               Dolloff F. Bishop,  Jr., Richard  A.  Dobbs
                                         and Barry M. Austern
                                 U.S. Environmental  Protection  Agency
                                       Cincinnati, Ohio   45268
                                       Contract No. 68-03-4038
                                      Technical Project Monitor

                                           Sidney A. Hannah
                        Water and Hazardous Waste Treatment  Research Division
                                Risk Reduction Engineering Laboratory
                                       Cincinnati, Ohio  45268
                                RISK REDUCTION ENGINEERING LABORATORY
                                  OFFICE OF RESEARCH AND DEVELOPMENT
                                 U.S. ENVIRONMENTAL PROTECTION AGENCY
                                       CINCINNATI, OHIO  45268
                                                        U.S. Environrr          v;on
                                                        Region 5, Libr;
                                                        77 West Jackson        -\  i oth r,
                                                        Chicago, IL  60604-3590"      Fl°°r
                                  REPRODUCED BY
                                  U.S. DEPARTMENT OF COMMERCE
                                  NATIONAL TECHNICAL INFORMATION SERVICE
                                  SPRINGFIELD, VA. 22161
                                                        Great Lakes
                                                                   GLNPO Library

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                                    TECHNICAL REPORT DATA
                            (rU-ase rcau Instructions un the rocrse before complaint)
 1. REPORT NO.
    EPA/600/2-89/026
                                                            3. RECIPIENT'S ACCESSIONNO
           ACCESSION NO.
           1952007AS
  TITLE AND SUBTITLE
   Removal  and Fate of RCRA and  CERCLA Toxic
   Organic  Pollutants in Wastewater  Treatment
5. REPORT DATE
   June 1989
                                                            6. PERFORMING ORGANIZATION CODE
7. AUTHORIS)                                   1
   Sanjoy K.  Bhattacharya and Rao  V.  Angara ,  Dolleff F.
   Bishop,  Jr.,  Richard A. Dobbs,  Barry  M.  Austern^
8. PERFORMING ORGANIZATION REPORT NO.
9. PERFORMING ORGANIZATION NAME AND ADDRESS

   University of Cincinnati, Cinti., OH   45221

  2U.S.  EPA,  RREL, Cincinnati, OH  45268
10. PROGRAM ELEMENT NO.
11. CONTRACT/GRANT NO.
                                                             68-03-4038
12. SPONSORING AG.ENCY NAVE AND.ADDRESS           „.           „,
   Risk  Reduction Engineering Laboratory  -  Cincinnati, OH
   Office of Research and Development
   U.S.  Environmental Protection Agency
   Cincinnati,  OH  45268
13. TYPE OF REPORT AND PERIOD COVERED
 Complete
14. SPONSORING AGENCY CODE
                                                                EPA-600/14
15. SUPPLEMENTARY NOTES
  Sidney A.  Hannah (513-684-2621 - FTS and  commercial)
16. ABSTRACT
         Two  separate studies were conducted  to investigate the removal  and
    fate of 28  selected RCRA compounds  (0.25  mg/L of each compound) and  19
    selected  CERCLA compounds (0.5 mg/L of  each compound) in conventional
    activated sludge treatment.  In each study, two pilot-scale (35 gpm)
    activated sludge systems (SRT: 4 days for RCRA study and 8 days for  CERCLA
    study) were  operated in parallel  at the U.S.  EPA Test and Evaluation  Facility
    in Cincinnati,  Ohio.  One system was spiked continuously with either  RCRA
    or CERCLA toxics to produce an acclimated biomass; the other was spiked
    intermittently  with the same toxics and sampled to determine performance
    under unacclimated conditions.  The selected  RCRA or CERCLA compounds  did
    not cause any adverse effects on COD and  SS removals.  The concentrations
    of organics  (RCRA study) in air emissions indicated that the chlorinated
    aliphatic solvents were essentially volatilized into the plant air emission
    stream, whereas  the aromatic volatile benzenes were substantially degraded.
    Additional  work  is planned to attempt to  reduce the analytical variability
    encountered  in  these studies.
 7.
                                KEY WORDS AND DOCUMENT ANALYSIS
                  DESCRIPTORS
                                               b.IDENTIFIERS/OPEN ENDED TERMS  c.  COSATI Field/Croup
 8. DISTRIBUTION STATEMENT
                                               19. SECURITY CLASS (Tins Keportl
                                                                          21. NO. OF PAGES
                                               20. SECURITY CLASS (Timpage)
                                                                         22. PRICE
EPA Form 2220-1 (R.v. X-77)   PREVIOUS EDITION is OBSOLETE

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                               DISCLAIMER
     This material has been funded wholly or in part by the United States
Environmental Protection Agency under Contract No. 68-03-4038.  It has
been subject to the Agency's review and it has been approved for
publication as an EPA document.  Mention of trade names or commercial
products does not constitute endorsement or recommendation for use.
                                    n

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                                 FOREWORD
     Today's rapidly developing and changing technologies and industrial
products and practices frequently carry with them the increased
generation of materials that, if improperly dealt with, can threaten
both public health and the environment.  The U.S. Environmental
Protection Agency is charged by Congress with protecting the Nation's
land, air, and water systems.  Under a mandate of national environmental
laws, the agency strives to formulate and implement actions leading to a
compatible balance between human activities and the ability of natural
systems to support and nurture life.  These laws direct the EPA to perform
research to define our environmental problems, measure the impacts, and
search for solutions.

     The Risk Reduction Engineering Laboratory is responsible for
planning, implementation, and management of research, development, and
demonstration programs to provide an authoritative, defensible
engineering basis in support of the policies, programs, and regulations
of the EPA with respect to drinking water, wastewater, pesticides, toxic
substances, solid and hazardous wastes, and Superfund-related activities.

     This publication is one of the products of that research and provides a
vital communication link between the researcher and the user community.
It contains the results from two pilot scale studies conducted to
investigate the removal and fate of 28 RCRA toxic compounds and 19 CERCLA
toxics by conventional activated sludge.  Related work is underway to
measure removals of these and similar toxics by other aerobic and
anaerobic processes and results will be presented in subsequent
publications.
                                      E. Timothy Oppelt,  Director
                                      Risk Reduction Engineering Laboratory

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                                 ABSTRACT


     Two separate studies were conducted to investigate the removal and
fate of 28 selected RCRA compounds (0.25 mg/L of each compound) and 19
selected CERCLA compounds (0.5 mg/L of each compound) in conventional
activated sludge treatment.  In each study, two pilot-scale (35 gpm)
activated sludge systems (SRT: 4 days for RCRA study and 8 days for CERCLA
study) were operated in parallel at the U.S. EPA Test and Evaluation Facility
in Cincinnati, Ohio.  One system was spiked continuously with either RCRA
or CERCLA toxics to produce an acclimated biomass; the other was spiked
intermittently with the same toxics and sampled to determine performance
under unacclimated conditions.  The selected RCRA or CERCLA compounds did
not cause any adverse effects on COD and SS removals.  The concentrations
of organics (RCRA study) in air emissions indicated that the chlorinated
aliphatic solvents were essentially volatilized into the plant air emission
stream, whereas the aromatic volatile benzenes were substantially degraded.
Additional work is planned to attempt to reduce the analytical variability
encountered in these studies.
                                     IV

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                                 CONTENTS
                                                                  Page

Foreword	iii
Abstract	iv
Figures   	vi
Tables    	vii

     Introduction 	  1
     Experimental System and Testing Approach 	  1
          Operations Approach 	  4
     Sampling and Analytical Methodology for Organics 	  7
          RCRA Offgas Sampling and Analysis 	  7
               Quality Control  	  9
          RCRA Liquid and Sludge Sample Analysis  	  9
               Volatiles  	  9
               Semi-Volatiles 	 10
          CERCLA Liquid and Sludge Sample Analysis  	 11
     Removal and Fate-In-Treatment	12
     Overview of Results	26

Appendices                                                        28

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                                 FIGURES
Number                                                              Page
  1        Simplified schematic diagram of pilot systems 	   3

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                                  TABLES


Number                                                              Page

  1          RCRA and CERCLA Toxic Organic Pollutants 	  2

  2          Nominal Operating Conditions and Design
             Characteristics of the Pilot Systems 	  5

  3          Average Concentrations of RCRA Organics in Wastewater
             and Sludges from the Acclimated System	14

  4          Average Concentrations of RCRA Organics in Air Samples
             from the Acclimated System	15

  5          Average Percent Removals of RCRA Organics by the
             Acclimated System  	 16

  6          Average Percent Removal of RCRA Organics by Treatment
             Mechanism for the Acclimated System  	 17

  7          Average Masses in Grams of RCRA Organics in
             Wastewaters and Sludges from the Unacclimated Systems. 18

  8          Average Masses of RCRA Organics in Air Samples from
             the Unacclimated System  	 19

  9          Average Percent Removals of RCRA Organics by
             Unacclimated System  .... 	 20

 10          Average Percent Removal of RCRA Organics by Treatment
             Mechanism for the Unacclimated System  	 21

 11          Average Concentrations of CERCLA Organics in
             Wastewater and Sludges from the Acclimated System  . . 22

 12          Average Percent Removals and Partitioning of CERCLA
             Organics for the Acclimated System 	 23

 13          Average Masses in Grams of CERCLA Organics in
             Wastewater and Sludges from the Unacclimated System  . 24

 14          Average Percent Removals and Partitioning of CERCLA
             Organics for the Unacclimated System 	 25
                                   VII

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INTRODUCTION
     The Risk Reduction Engineering Laboratory has evaluated the removal and
fate of selected RCRA and CERCLA toxic organic pollutants (Table 1) during
pilot-scale primary-activated sludge treatment of municipal wastewater at the
Agency's Test and Evaluation Facility in Cincinnati, Ohio.  This report
summarizes the results of the removal and fate-in-treatment of the selected
volatile and semivolatile organic compounds.  The pilot treatment systems,
chosen as a representative POTW design, consisted of primary clarifi-
cation followed by conventional plug-flow activated sludge treatment and
secondary sedimentation.  Two parallel 2.2 liters/second (L/S) (35 gpm)
pilot plants were used and are shown in Figure 1.  Screened and degritted
raw wastewater from the Cincinnati Mill Creek Wastewater Treatment Plant
was the wastewater feed for the studies.  The selected RCRA and CERCLA
toxics were spiked into the raw wastewater in two sequential test periods.
The first test (RCRA) period from October 1987 through March 1988 evaluated
the removal and fate during treatment of selected volatile and semi-
volatile organic toxics.  The second test (CERCLA) period from June 1988
through August 1988 evaluated the removal and fate of semivolatile organic
toxics.
EXPERIMENTAL SYSTEM AND TESTING APPROACH
     The primary clarifiers in the pilot treatment systems were 2.95 m in
diameter and had a sidewater depth (SWD) of 3.6 m.  At 2.2 L/S wastewater
flow, the overflow rate in the center feed clarifier was 28 m^/m^ day.
The activated sludge aeration basins were 5.4 m long, 3 m wide and had a
SWD of 3.6 m.  At a flow of 2.2 L/S, the hydraulic residence time in the
basins was 7.5 hrs.  Conventional coarse bubble diffusers were used in

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            TABLE 1.  RCRA AND CERCLA TOXIC ORGANIC POLLUTANTS
        RCRA Study Period
         CERCLA Study Period
acetone
cyclohexanone
furfural
2-butanone
4-methyl-2-pentanone
tetrahydrofuran
carbon tetrachloride
chlorobenzene
chloroform
1,2-di ch1oroethane
1,2-dichloropropane
methylene chloride
tetrach1oroethy1ene
trichloroethylene
1,1,1-trichloroethane
1,1,2-tr i chloroethane
ethylbenzene
toluene
total xylenes
bis(2-ethylhexyl) phthalate
butyl benzyl phthalate
1,4-di chlorobenzene
2,4-dimethylphenol
2,4-dinitrophenol
naphthalene
nitrobenzene
4-nitrophenol
phenol
1,2-di chlorobenzene
1,3-dichlorobenzene
1,4-di chlorobenzene
1,2,4-trichlorobenzene
nitrobenzene
1,3-dinitrobenzene
2,6-dinitrotoluene
p-cresol
4-chloroaniline
hexachloroethane
hexachlorobutadiene
dimethyl phthalate
diethyl phthalate
dibutyl phthalate
butyl benzyl phthalate
bis(2-ethylhexyl) phthalate
naphthalene
lindane
dieldrin

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Raw Wastewater
                          DETENTION  TANKS
                                                                                                 Return Activated
                                                                                                  Sludge Pump
                                                                                                    o
        Spike
                                                                              WAS
Return Activated
 Sludge Pump
                  Figure 1.   SIMPLIFIED SCHEMATIC DIAGRAM OF PILOT SYSTEMS

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the basins.  The center feed secondary clarifiers were 3.6 m in diameter
and had a SWD of 3.6 m.  At a 2.2 L/S flow, the overflow rate in the
rlarifipr was 1R.4 rn^/nr Hay.  Thp nominal operatinQ conditions anH Hesion
characteristics for the two identical systems used in the study are given
in Table 2 in English units.  A nominal operational  sludge retention time
(SRT) of 4 days was employed in the RCRA study period.  In the CERCLA
study period, the nominal SRT was 8 days.
     In order to sample the air space above the primary clarifier, a cover
was fabricated with approximately an inch opening around the unit.  The cover
was vented through a duct to the roof.  An air sweep equivalent to a 5 km
per hour wind was maintained over the surface of the clarifier by exhausting
air at 14,000 liters/min.  The aeration basin was fitted with an air
tight cover and the offgas was also vented to the roof.  Air flow in the
aeration basins averaged 5,600 liters/min and maintained a dissolved
oxygen level of at least 2.0 mg/L.

Operations Approach and Conventional Pollutant Removals

     The evaluation of the removal and fate during treatment of the spiked
RCRA and CERCLA toxic organics in the large pilot-scale primary-
activated sludge treatment systems was performed at two steady-flow
operational conditions; operation with a continuous feed of spike
toxic cocktail in one pilot train under steady operating conditions
and operation of the parallel pilot train under the same steady conditions
except with intermittent spiking of the toxic cocktail.  The operation
with continuous feeding of the spiking cocktail produced "acclimated"
biomass.  In the operation with intermittent spiking of the cocktail,

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           TABLE 2.  NOMINAL OPERATING CONDITIONS AND DESIGN
                     CHARACTERISTICS OF THE PILOT SYSTEMS
  I.   Design Flow, Qd = 35 gpm
                      = 50,400 gpd
 II.   Primary Clarifiers - Diameter              = 9'-8"
                           Weir Diameter         = 9'-l"
                           SWD                   = 12'-0" ?
                           Surface Area          = 73.4 ft
                           Surface Overflow Rate = 687 gpd/ft

III.   Aeration Basins - L:W:D               = 17'-7":1Q'-0":12'-0"
                        Surface Area        = 175.8 ft.
                        Volume              = 2,110 ftj
                                            = 15,780 gal.
              Hydraulic Residence Time (Qd) = 7.5 hrs.
 IV.   Secondary Clarifiers - Diameter              = 11'-11"
                             SWD                   = 12'-0"
                             Surface Area          = 111.5 ft*
                             Surface Overflow Rate = 452 gpd/ft

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spike was added at steady nominal concentrations of toxic organics equal
to that in the continuously spiked train for a 24 hour period after every
3 SRT periods of unspiked operation.  During the spiking episodes, the
intermittently spiked train provided removal and fate-in-treatment data
for the toxic organics intermittent loading ("unacclimated") operation.
The intermittent spiked treatment train also provided conventional pollutant
performance control data during unspiked operation for comparison to the
conventional pollutant performance of the continuously spiked train.
     The pilot treatment trains were operated at a 4-day (4 ^.3) SRT with
a nominal spike of 0.25 mg/L of each individual toxic organic during the RCRA
study period.  The pilot treatment trains were operated at an 8-day (8 +1 day)
SRT with a nominal spike of 0.5 mg/L of each individual toxic organic during
the CERCLA spiking period.  The overall performance of the parallel treatment
systems were characterized for removal of chemical oxygen demand (COD),
suspended solids (SS), ammonia (NHs-N), and for the removal and fate-in-
treatment of the individual toxic organics using automated analytical
procedures for the conventional pollutants and Agency GC/MS procedures
for the toxic organic compounds.
     Average removals of conventional pollutants in the pilot systems
during both study periods ranged 81 to 88 percent for the COD and 94 to
97 percent for SS.  In the RCRA study period at the nominal 4-day SRT and
with a nominal toxic spike of 0.25 mg/L of each individual organic, nitri-
fication occurred in the activated sludge processes with average N^-
N reductions ranging 76 to 81 percent for the two spiked pilot treatment
trains.  In the CERCLA study period at a nominal 8-day SRT and with a
nominal spike of 0.5 mg/L of each individual organic, complete nitrification
usually occurred in the intermittently spiked activated
                                      6

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 sludge process but frequent interference with nitrification was observed
 in the continuously spiked system.   The NH--N reductions during the
 CERCLA study averaged 98 percent for the intermittently spiked system and
 88 percent for the continuously spiked system.   Data tables showing
 removals of the conventional  pollutants are included in Appendix 3.  As
 an overview of the operational  performance, the pilot treatment represents
 effective performance for control  of conventional  pollutants.   The presence
 of the spiked  toxic organics  in the  wastewater  produced no  significant
 adverse effects on the treatment of  conventional  pollutants except on
 ammonia removal  during continuous spiking  with  the  CERCLA compounds.

 SAMPLING AND ANALYTICAL METHODOLOGY

 RCRA  Offgas  Sampling  and  Analysis
      The sampling  system  used to collect each offgas  sample consisted of
 a  33  liter  stainless  steel  polished  canister, a  pneumatic flow  controller
 and nickel  sample  tubing.   Previous  studies  have shown  that  the  canisters
 are well  suited  for collecting  air samples  for  VOC  analysis  and  that  VOC
 levels  do not  deteriorate  in the canisters  during reasonable holding
 times.
      Canisters and  flow controllers  were cleaned and  prepared for
 sampling  by  repeated high-pressure purging with ultrapure zero air.   The
 canisters were then pressurized, and blank checked  by gas
 chromatography/mass spectrometry (GC/MS).  After blank checking, clean
 canisters were evacuated to 28 inches of Hg  for sample collection.  The
 nickel tubing was cleaned by heating the tubing to  150°C and flushing
with  purified nitrogen for 2 hours.

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     Samples were collected by attaching the nickel tubing to the
canister and extending the free end into the offgas duct.  The canister
vacuum was recorded, the valve opened, and the canister allowed to fill
at a constant rate during the sampling event.  The canister valve was
then closed, sample tubing disconnected, and a final pressure reading
recorded at the conclusion of sampling.  When the collected samples
arrived at the Laboratory they were allowed to equilibrate, then a
pressure reading was taken using a mercury manometer before any other
manipulations of the sample.  The final pressure reading was recorded
along with the date, temperature, and barometric pressure.  From these
data, the sample volume was calculated.

     Canister samples were analyzed on a Finnigan Model OWA 1050 GC/MS
system with a quadrupole mass spectrometer.   This system is equipped
with a Tekmar Model 5000 cryogenic concentration and sample introduction
system. The GC/MS interface consists of a quartz jet separator.  The MS
is scanned from 40 to 260 m/z (mass charge ratio) every 2 seconds.

     Samples were analyzed by withdrawing 0.1 liter or 0.5 liter from a
canister using the system mass flow controller.  The volatile organics
were concentrated on a cryogenic trap and then desorbed to the GC column
for component separation and mass spectral analysis.  The GC/MS system
was calibrated in units of ng of RCRA organic on column and results were
recalculated to yield ug/liter in air sample as collected.  From these
data, masses of each RCRA organic stripped during the sampling event were
calculated.  The method used was the contractor's standard operating
procedure for canister analysis, SOP No. 09-002-00.
                                      8

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 Quality control
      The analytical  standard was  prepared  from  the  neat  compounds  and
 internal audits  were analyzed for each  test  series  and the  results
 included with  the data.   The audit gases were obtained from Scott
 Speciality  Gases as  Certified Mixtures  in  Nitrogen  (±5 percent).   The
 audit compounds  were 1,1,1-trichloroethane,  carbon  tetrachloride,
 trichloroethene, toluene,  and tetrachloroethene.
      Since  duplicate field samples were analyzed with good  precision  and
 calibration precision was  excellent, duplicate  analyses  on  the  same
 canister were  not run.
      Blanks were analyzed  and met the method QC criteria before samples
 were  analyzed  on each analysis day.  In addition, if a highly
 concentrated sample  was  analyzed,  blanks were run until  the  system met
 the QC  blank criteria before  proceeding with sample analysis.   In  all
 cases,  it was  found  that carry-over was not extensive and this  is  documented
 in the  Canister  QC files.   Calibration  criteria and other QC procedures
 follow  the  SOP.
 RCRA  Liquid  and  Sludge Sample  Analysis
      Sludge  and  liquid samples were analyzed by gas chromatography/mass
 spectrometry (GC/MS)  according to  the methods outlined in the USEPA
 Methods  for  Evaluating Solid Waste, SW846,  3rd edition,  November 1986.
 Volatiles
     Samples to be analyzed for volatile organic compounds were collected
by filling one 40 ml volatile organic analysis (VOA) bottle at each sample
 interval from each sampling point during the sampling event.  The first

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step in analyzing these samples involved compositing the individual VOA



samples from each sample point into one composite sample for each sample



point.   Samples to be composited were stored chilled at 4°C.  Precleaned



glassware were also chilled to this temperature.  During the compositing



step, the samples were poured down the side of the mixing flask to avoid



agitation.  After all  samples were added, the composite was stirred with



a chilled glass stirring rod.  Agitation was avoided wherever possible.



Two 40 ml composites were then collected and stored at 4 C in headspace-



free vials until analysis.



     The volatile fractions were analyzed on Finnigan DWA and Extrel



ELQ400 GC/MS systems using Method 8240 (Purge and Trap).  In this method,



5 ml of sample or an aliquot of sample diluted to 5 ml is purged with



an inert gas (helium)  in a specially designed purge vessel.  Volatile



organic compounds are partitioned into the gaseous phase and swept by the



purge gas onto a multi-phase sorbent trap.  After the purge cycle is



complete, the flow of carrier gas is reversed, and the trap is heated



rapidly.  Volatile organic compounds are thermally desorbed from the trap



into the gas chromatograph where the individual components are separated.



Identification and quantitation were done by mass spectrometry.







Semi-Volatiles





     Semi-volatile (extractable) compounds were extracted from the



samples according to Method 3520 (continuous liquid-liquid extraction).



This method outlines procedures for the  isolation of acidic and



base/neutral organic compounds from aqueous samples.  One liter of
                                    10

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sample, or an aliquot of sample diluted to one liter is pH adjusted to
greater than pH 11.  It is then mixed with an organic solvent (methylene
chloride in this project).  Base/neutral organic compounds have greater
solubility in the organic phase and are concentrated there.  After the
base/neutral extract has been removed, the pH of the sample is re-
adjusted to less than pH 2.  A second extraction is then performed to
remove acidic compounds.  The organic extracts are then concentrated to
one ml.  Portions of the acidic and base/neutral extracts from a sample
were mixed and an aliquot was injected into the GC/MS for analysis.
Samples were analyzed on Finnigan 5100 and Extrel ELQ 400 GC/MS
systems in accordance with Method 8270.  This method specified GC/MS analysis
of organic extracts using a fused silica capillary column, with mass
spectrometry for detection and quantitation.
CERCLA Liquid and Sludge Sample Analysis
     Liquid and sludge samples in the CERCLA study were collected for
either 24 or 48 hours and composited for analysis.  The CERCLA compounds
were all classified as semivolatiles and were analyzed following EPA
Extraction Method 1625.
     All samples were spiked with a mixture of deuterated or -^C-
labeled priority pollutant organics to represent the priority pollutants
spiked into the wastewater feed.  Analytical results for the nonlabeled
priority pollutant organics were corrected automatically for the
recoveries of the labeled priority pollutant organics.  The isotopically
labeled compounds were used as internal standards for the corresponding
priority pollutants.  Furthermore, percent recovery of the labeled
                                    11

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compounds, and by inference, of their corresponding natural-isotope analogs,
was measured as a function of an internal standard added just before gas
chromatography/mass spectrometry (GC/MS) analysis.  Anthracene-d^g was
used for Method 1625.  A capillary column was used in the GC/MS procedure.
Both instruments were attached to a computer data system.  To ensure
precision, duplicate analyses of individual collected samples and
analyses of samples collected and processed in duplicate were performed.

REMOVAL AND FATE-IN TREATMENT

     Five sample events were performed during the RCRA study period to
evaluate the removal and fate-in treatment of the spiked toxic organics.
In this study period, the removals and fate of the toxic organics were
characterized by GC/MS analyses of the influent to and all discharges
from the two treatment systems, i.e., in the raw wastewater, the primary
influent, the primary effluent, the secondary effluent, the primary sludge,
the waste activated sludge, and the air emissions from both primary clari-
fication and the activated sludge process.  In the first two sample events
of the RCRA study period, the air samples proved to be too small for the
GC/MS sensitivity.  With larger samples, precise and quantitatively accurate
data were generated on the volatile organic compounds in the primary and
activated sludge air emissions from the pilot systems for the last three
sample events.  In the CERCLA study, eleven sample events on the continuously
spiked (acclimated) pilot train and 4 sample events  on the intermittently
spiked pilot train have been included in the summary tables of average
toxic organic removal and toxic organic fate-in-treatment performance of
the pilot systems.
                                    12

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     The removal and fate-in-treatment performance for the RCRA study
period on both volatile and semivolatile organics are summarized in Tables
3 through 10 for "acclimated" and "unacclimated" operation.  The performance
data for the continuously spiked (acclimated) treatment system are based on
24-hour composite samples with average concentrations reported for the
various plant discharges (Tables 3 and 4) including air emissions and removals
reported (Tables 5 and 6) across the treatment processes and by treatment
mechanism.  In the intermittently spiked ("unacclimated") pilot trains, the
episodal spiking lasted 24 hours but the sampling composite was extended to
48 hours to permit measurement of the gradual washout of the organic toxics.
Thus, the performance data for the unacclimated operation are reported for
the toxic organics in the discharges (Tables 7 and 8) as average masses in
grams rather than as concentration units.  The masses in grams are then
used to calculate the removals (Tables 9 and 10) across the treatment
processes and in the removal mechanisms.  The raw data for the individual
sample events are included in the Appendix 1.
     The removal and fate-in-treatment performance for the CERCLA study
period on semivolatile toxic organics is summarized in Tables 11 through
14.  Since only semivolatile organics were employed, air emission
sampling was not performed.  As in the RCRA study period described above,
the performance data for continuously spiked operation ("acclimated")
were based on 24-hour composite samples with average toxic organic
concentrations reported in the various plant discharges.  For intermittently
spiked ("unacclimated") operation,  the performance data are reported as
masses of toxic organics because of the 24-hour spiking episode and the 48-
hour composite sampling for organic washout.  While air stripping of
organics was expected to be an insignificant removal mechanism and air
                                    13

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TABLE 3.  AVERAGE CONCENTRATIONS OF RCRA ORGANICS IN WASTEWATER
          AND SLUDGES FROM THE ACCLIMATED SYSTEM
NAME

Acetone
Cyclohexanone
Furfur»l
2-lutanone
4-Methyl-2-Pentanone
Tetrahydrofuran
Carbon Tctrachlorfde
Chlorobentene
Chtorofora
1.2-Dlchloroethane
1,2-Dichtoropropane
Nethylcne Chloride
Tetrachloroethylent
Trlchloroethylene
1,1,1-Trlchloroethane
1.1.2-Trlchloroethane
Ethylbeniene
Toluene
Total Xytenei
• 1 •- <2- ethylhexy I ) -phthat ate
•utytbeniylphtlialate
1,4-dfchlorobeniene
Z,4-DlMthylpheno|
2,4-Dlnltrophanol
Naphthalene
Nltrobeniene
4-Nltrophenol
Phenol
|| UASTEUA1ER FEED || PRIMARY EFHUENT | (SECONDARY Ef FLUENT || PRIMARY SLUDGE || SECONDARY SLUDGE ||
II II II II II II
| (AVERAGE STANDARD | (AVERAGE STANDARD | (AVERAGE STANDARD | (AVERAGE STANDARD | (AVERAGE STANDARD ||
|| DEVIATION || DEVIATION || DEVIATION || DEVIATION || DEVIATION ||
|| ug/L || ug/l || ug/L || ug/L || ug/L ||

II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II

H*7


134
238
199
260
255
255
JM
228
434
211
201
260
216
196
2M
175
120
62
102


144
129

295

1313 ||
II
II
88 ||
187 ||
' II
111 ||
33 II
83 ||
33 II
50 ||
H6 ||
*« II
57 II
61 ||
49 ||
"II
28 ||
35 ||
33 ||
26 ||
33 II
II
II
61 ||
" II
II
80 ||

1082


68
162
225
247
238
242
323
212
398
194
186
233
202
192
295
163
95
33
95


1)3
122

290

839 ||
II
II
91 ||
26 ||
25 II
110 ||
60 ||
98 ||
18 ||
n ||
167 ||
66 ||
" ||
88 ||
66 ||
" II
100 ||
59 ||
2* II
' II
37 ||
II
II
52 II
38 ||
II
106 ||

29


5
3
128
3
3
39
140
54
107
10
5
5
97
3
3
2
4
5
5


5
5

5

23 II
II
II
o II
3 II
114 ||
1 II
1 II
1* II
<2 ||
20 ||
62 ||
3 II
2 II
5 II
'* II
0 II
1 II
0 II
1 II
0 II
0 II
II
II
0 II
0 II
II
1 II

1241


63
105
146
163
259
289
378
210

163
254
273
191
246
329
190
730
447
133


228
65

287

241 ||
II
II
62 ||
128 ||
111 ||
189 ||
217 ||
254 ||
88 ||
180 ||
II
153 ||
209 ||
259 ||
165 ||
201 ||
276 ||
179 ||
321 ||
119 ||
113 ||
II
II
87 ||
30 ||
II
15 ||

127


5
6
171
5
3
44
129
43

48
6
3
97
3
10
3
142
5
6


5
7

5

127 ||
II
II
0 II
1 II
266 ||
2 II
1 II
46 ||
175 1)
68 ||
II
73 II
* II
1 II
130 ||
2 II
« II
2 II
128 ||
0 II
* II
II
II
0 II
* II
II
o II

-------
TABLE 4.   AVERAGE  CONCENTRATIONS OF  RCRA ORGANICS  IN  AIR
             SAMPLES  FROM THE ACCLIMATED SYSTEM
           NAME
Acetone
Cyclohexanone
Furfural
2-but*none
4-*>ethyl-2*pentanone
Tetrahydrofuran
Carbon Tetrachloride
Chloretenzene
Chtorofona
1,2-dieMoroethane
1 ,2-diehloropropane
Methylene Chloride
Tet rich I oroethy I ene
Trichloroethylene
1,1,1-trichloroethine
1,1,2-trfehloroethane
Ethylbenzene
Toluene
Total  Xylenes

bis-(2-ethylhexyl)-phthalate| |
Butylbenzylphthalate
1 ,4-df cholorobenzene
2,4-diMttiylphenol
2,4-dinitroph«nol
Naphthalene
Nitrobenzene
4-nitrophenol
Phenol
|| PRIMARY
II
| | AVERAGE
II
II
,i i
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
•1 1
1 1
it
ii
n
ii
n
n
ii

ug/L
0.13
0.03
0.03
0.02
0.26
0.24
0.20
0.18
0.19
0.34
0.20
0.20
0.26
0.10
0.19
0.29
0.1B








•••*«•••»*
AIR
STANDARD
DEVI AT I OK

0.06
0.01
0.00
0.02
O.OS
0.13
0.01
0.04
0.03
0.07
0.01
0.01
O.OS
0.01
0.03
0.03
0.04








immmmmmmm mmm •••»••*•• mmmm
|| AERATION AIR ||
II II
| | AVERAGE STANDARD | |
II
II
.. I 1 _-
1 1
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
DEVIATION] |
ug/L
0.20
0.01
0.02
0.34
8.00
2.37
6.10
3.72
5.50
7.19
7.68
5.84
7.35
3.22
0.94
1.92
1.73








II
0.20 ||
II
II
0.00 ||
0.02 ||
0.05 ||
0.62 ||
1.33 l|
0.82 ||
0.54 ||
0.44 ||
2.12 ||
1.42 ||
0.66 ||
0.73 ||
0.52 ||
0.10 I)
0.60 ||
0.55 ||
II
II
II
II
II
II
II
II
                                       15

-------
TABLE  5.  AVERAGE  PERCENT REMOVALS  OF RCRA ORGANICS
           BY THE  ACCLIMATED  SYSTEM
                       || PR HURT TREATMENT
                      TOTAL TREATMENT   ||
         NAME
| | REMOVAL   STANDARD 11  REMOVAL    STANDARD 11
||          DEVIAT ION||           DEVIATION)|

II   «>            II   «'            II
Acttone
Cyclohexanone
Furfural
2-lutanon*
4-M«thyl-2-Pentanor»
Tetrahydrofuran
Carbon T*trachlor

-------
'TABLE  6.   AVERAGE  PERCENT REMOVAL OF  RCRA  ORGANICS BY
             TREATMENT MECHANISM FOR THE  ACCLIMATED  SYSTEM
NAME
Acetone
Cyclohexanone
Furfural
2-Butanone
4-Methyl-2-Pentanone
T et rahydrof uran
Carbon Tetrachloride
Chlorobenzene
Chloroform
1,2-Dichloroethane
1 , 2 • D i ch I oropropane
Methylene Chloride
Tetrachloroethytene
Trichloroethylene
1,1,1-Triehloroethane
1,1,2-Trichloroethane
Ethyl benzene
Toluene
Total Xylenes
|| REMOVED IN SLUDGE || STRIPPI
II II
|| REMOVAL STANDARD || REMOVAL
|| (X) DEVIATION || (X)
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
Bis(2 ethylhexyUphthalatej |
Butylbenzylphthalate
1 , A -Oi Chlorobenzene
2,4-Dtmethylphenol
2,4-Dinitrophenol
Naphthalene
Nitrobenzene
4-Nitrophenol
Phenol
II
II
II
II
II
II
II
II
2


1
1
3
1
1
2
3
2

1
1
1
2
1
1
1
11
11
2


2
1

1
1 II
II
II
o II
2 II
* II
1 II
1 II
1 II
2 II
1 II
II
2 II
1 II
1 II
2 II
1 II
1 II
1 II
8 II
6 II
1 II
II
II
1 II
1 II
II
0 II
3


1
2
6
139
38
104
67
97
124
129
103
122
56
22
25
32









                                                G       ||  BICOEGRADATION   ||
                                                        II                 II
                                                STANDARD || REMOVAL  STANDARD ||
                                               DEVIATION ||   (X)    DEVIAT!ON| |
                                                      1  II
                                                      1  II
                                                      1  II
                                                     11  II
                                                      9  II
                                                     12  ||
                                                     11  II
                                                      9  II
                                                     40  ||
                                                     22  ||
                                                     H  II
                                                     15  II
                                                      9  II
                                                      3  II
                                                      »  II
                                                     10  ||
                                                        II
                                                        II
                                                        II
                                                        II
                                                        II
                                                               92
 94
 95
 28
-42
 60
-21
-17
•25

•35
 -6
•25
 •6
 76
 72
 66
 85
 81
 93
 94
 93

 97
 5 II
   II
   II
 1 II
 e II
52 ||
12 ||
 9 II

32 ||
12 ||
   II
23 ||
12 ||
17 II
24 ||
 3 II
 8 II
 9 II
 8 II
 9 II
 3 II
   II
   II
 2 II
 ° II
                                  17

-------
                               TABLE  7.  AVERAGE MASSES IN GRAMS OF RCRA ORGANICS IN WASTEWATERS
                                         AND SLUDGES  FROM THE UNACCLIMATED SYSTEM
CO
NAME

Acetone
Cyclohexanone
Furfural
2-lutanone
4-Nethyl-2-Pentanone
Tetrehydrofuren
Carbon Tetrechlorlde
Chlorobensene
CMoroforai
1,2-Olchloroethene
1 , 2 -0 1 ch I oropropene
Methyl ene Chloride
TetrccMoroethyter*
Trlchloroethylene
1,1.1-Trlchloroethane
1 , 1 ,2-Trlchloroethene
Ethylbeniene
Toluene
Total Xy tenet
|| UASTEUATER FEED || PRIMARY EFFLUENT || SECONDARY EFFLUENT || PRIMARY SLUDGE || SECONDARY SLUDGE ||
It It II II II II
|| AVERAGE STANDARD || AVERAGE STANDARD | (AVERAGE STANDARD || AVERAGE STANDARD | (AVERAGE STANDARD ||
|| DEVIATION || DEVIATION || DEVIATION || DEVIATION) | DEVIATION) |

II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
tU-(2-ethy1hexyl)-phthalate||
Butylbeniylphthalate
1,4-Dlchlorofaeniene
2.4-Dl*ethylphenol
2,4-Olnltrophenol
Naphthalene
Nltrofaeniene
4-Nltrophenol
Phenol
II
II
II
II
II
II
II
II

167.3
15.7 •

36.6
24.5
34.6
40.5
44.6
40.6
32.3
32.9
78.8
31.9
31.2
41.2
36.1
30.4
50.0
35.0
18.9
8.4
24.7


20.8
21.7
26.8 *
52.1

58.5 ||
II
II
4.5 ||
20.6 ||
1.6 ||
2.8 ||
7.8 ||
5.6 ||
1.1 ||
0.6 ||
25.2 ||
9.0 ||
1.9 ||
5.5 ||
3.6 ||
2.8 ||
12.3 ||
6.6 ||
6.2 ||
5.3 ||
9.2 ||
II
II
7.4 ||
9.0 ||
II
31.2 ||

188.6
13.4 •

36.8
20.6
36.8
27.4
38.7
28.8
25.8
24.8
77.0
26.1
25.0
30.6
26.8
21.1
46.3
25.3
9.1
3.0
22.1


21.2
20.3
30.4 •
50.3

51.4 ||
II
It
1.3 ||
10.4 ||
5.4 ||
11.4 ||
21.4 1)
9.1 ||
11.0 ||
10.1 ||
33.4 ||
11. ||
7- II
14. ||
»- II
»• II
23.1 ||
7.2 ||
0.8 ||
1.0 ||
8.3 ||
II
II
8.4 ||
13.2 ||
II
38.0 ||

7.6
1.9 •

1.9 •
2.1
36.5
0.9
3.1
5.7
12.3
9.0
23.3
3.1
2.5
1.7
19.0
2.0
1.1
2.1
1.9
1.9
5.3


1.9
6.5
9.5 •
1.9

6.6 ||
II
II
II
0.3 ||
1.6 ||
0.4 ||
1.7 ||
2.3 ||
2.6 ||
2.8 ||
2.0 ||
1.4 ||
1.5 ||
0.5 ||
5.3 ||
0.6 ||
0.4 ||
1.6 ||
0.0 ||
0.0 ||
1.6 ||
II
II
0.0 ||
4.8 ||
II
0.0 ||

4.3
0.1 •

0.4
0.6
0.7
0.3
0.5
0.6
0.4
O.S

0.4
0.4
0.5
0.5
0.3
0.8
0.3
0.7
0.2
0.3


0.3
0.1
0.1 •
O.S

3.6 ||
II
II
0.5 ||
0.3 ||
0.9 ||
0.2 ||
0.4 ||
0.5 ||
0.3 ||
0.4 ||
II
0.3 1)
0.4 ||
0.4 ||
0.4 ||
0.3 ||
0.6 ||
0.3 ||
0.6 ||
0.4 ||
0.0 ||
II
II
0.2 ||
0.1 ||
II
0.8 ||

3.5
0.0 •

0.0
0.0
0.0
0.0
0.0
0.1
0.2
0.1

0.1
0.0
0.0
0.2
0.3
0.3
0.3
0.3
0.0
0.2


0.0
0.0
0.2 *
0.0
~~T — - 1 1
5.5 ||
II
II
0.0 ||
0.0 )(
0.0 ||
0.0 (1
o.o n
0.1 ||
0.1 I)
0.1 ||
II
0.0 ||
0.0 ||
0.0 ||
0.2 I)
0.5 ||
0.4 ||
0.5 ||
0.3 ||
0.0 ||
0.0 ||
II
II
0.0 ||
0.0 ||
II
0.0 ||
                                     * Only one data point available.

-------
TABLE 8.   AVERAGE MASSES OF  RCRA ORGANICS  IN  AIR  SAMPLES
           FROM THE UNACCLIMATED  SYSTEM
|| PRIMARY AIR || SECONDARY AIR ||
NAME || || ||
|| AVERAGE STANDARD | | AVERAGE STANDARD ||
|| DEVIATION || DEVIATION ||
| |mass (gni) ||IMSS (gm) ||
Acetone [ |
Cyclohexanone ||
Furfural 1 1
2-butanone | |
4-methyl-2-pentanone ||
Tetrahydrofuran | |
Carbon Tetrachloride | |
Chtorobenzene ||
Chloroform | |
1,2-dichloroethane ||
1,2-dichtoropropane ||
Methylene Chloride | |
Tetrachloroethylene | |
Trichloroethylene ||
1,1,1-trichloroethene ||
1,1,2-trichloroethane ||
Ethylbenzene | |
Toluene ||
Total Xylenes ||
bis-(2-ethylhexyl)-phthalate| |
Butylbenzylphthalate | |
1,4-dicholorobenzene ||
2,4-dimethylphenol ||
2,4-dinitrophenol ||
Naphthalene | |
Nitrobenzene ||
4-nitrophenol ||
Phenol 1 1
5.6
0.2 *

0.9
1.0
0.4
8.1
10.3
7.7
3.8
4.1
12.3
8.2
7.9
8.6
3.7
4.2
12.6
4.1









4.5 ||
II
II
1.0 ||
0.3 ||
0.6 ||
0.2 ||
5.4 ||
0.9 ||
0.5 ||
0.0 ||
4.1 ||
0.0 ||
0.5 ||
0.7 ||
0.4 ||
0.2 ||
3.7 ||
0.0 ||
II
II
II
II
II
II
II
II
II
2.8
0.1 •

0.1
0.0
2.7
56.9
34.4
43.0
23.0
35.7
50.7
63.1
47.1
64.6
22.1
31.7
31.6
22.8









3.5 ||
II
II
II
0.1 ||
1.0 ||
21.9 ||
6.9 ||
12.9 ||
5.6 ||
13.4 ||
23.5 ||
22.1 ||
15.5 ||
26.9 ||
4.5 ||
12.6 ||
12.7 ||
10.4 ||
II
II
II
II
II
II
II
II
II
                       • Only data point available.
                           19

-------
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II  1-6
II  o-»
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II  o-i
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II  rzi
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           O'So    II S'6l
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           rti    II I'ZE
           0*06    II 0'»
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-------
TABLE 10.  -AVERAGE PERCENT  REMOVAL OF RCRA ORGANLCS  BY TREATMENT
            MECHANISM FOR THE  UNACCLIMATED SYSTEM
NAME

Acetone
Cyclohexanone
Furfural
2-Butanone
4-Methyl -2-Pentanone
Tetrahydrofuran
Carbon Tetrachloride
Ch 1 orobenzene
Chloroform
1 ,2-Dichloroethane
1,2-Dichloropropane
Methylene Chloride
Tetrachloroethylene
Trichloroethylene
1,1, 1 -Trichloroethane
REMOVED IN SLUDGE 1 1 STRIPPING | | BIOOEGRADATION [ |
II II II
REMOVAL STANDARD || REMOVAL STANDARD | | REMOVAL STANDARD ||
(X) DEVIATION || (X) DEVIATION || (X) DEVIATION) |

*
1 •

1

2
1
1
2
2
1

2
1
1
1,1,2-Trichloroethane || 2
Ethylbenzene || 2
Toluene || 2
Total Xylenes || 2
Bis(2 ethylhexyl)phthalate|| 5
Butylbenzytphthalate 1 1 3
1, 4 -Dich I orobenzene ||
2.4-Dimethylphenol ||
2,4-Dinitrophenol ||
Naphthalene || 1
Nitrobenzene || 1
4-Nitrophenol || 1 •
Phenol 1 1 1

3 II
II
II
1 II
II
3 II
1 II
1 II
1 II
1 II
1 II
II
2 II
1 II
1 II
2 II
2 II
3 II
2 II
* II
5 II
II
II
II
1 II
1 II
II
1 II

3
0 •

1
2
5
135
75
100
55
84
104
138
115
136
54
66
40
45










3 II
II
II
1 II
1 II
1 II
46 ||
14 ||
28 ||
13 ||
28 ||
40 ||
M ||
33 ||
48 ||
10 ||
21 II
11 II
13 II
II
II
II
II
II
II
II
II
II

88
87 •

93
81
-13
-38
17
-16
4
-12

-51
-25
-41
-8
24
56
48
84
67
76


89
73
64 *
96

3 II
II
II
1 II
16 ||
3 II
46 ||
13 II
25 ||
7 II
27 ||
II
40 ||
33 ||
48 ||
16 ||
21 II
12 II
13 II
2 II
19 ||
2 II
II
II
3 II
13 II
II
2 II
tmnmrnmrnm
                     Only one data point available.
                                   21

-------
TABLE 11.  AVERAGE  CONCENTRATIONS OF CERCLA  ORGAN1CS IN WASTEWATER
                    AND SLUDGES FROM THE ACCLIMATED SYSTEM
|| UASTEUATER FEED
II
II
Ccnpounds .| (AVERAGE STANDARD
|| DEVIATION
|| UG/L
M
II
IDICHLOROBENZENE, PROBABLY 1,2 || 368.2 49.2
IDICHLOROBENZENE, PROBABLY 1,3 || 375.4 41.5
IOICHLOROBENZEHE, PROBABLY 1,4 || 390. e 31.6
(1.2.4-TRICHLOROBENZENE || 655.0 206.6
(NITROBENZENE || 447.3 78.8
| 1,3-DINITROBENZENE || 263.7 41.4
|2,6-DINITROTOLUENE || 405.6 50. 5
IP-CRESOL || 547.3 78.7
(4-CHLOROANILINE || 393.3 180.4
IHEXACHLOROETHANE || 345.9 41.9
IHEXACHLOROBUTADIENE || 398.0 33.4
(DIMETHYL PNTHALATE || 576.3 345.9
IDIETHVL PHTHALATE || 497.4 39.2
IDIBUTYL PHTHALATE || 427.9 23.4
(BUTYL BENZYL PHTHALATE || 398.4 22.7
|BIS(2-ETNYLHEXYL)PHTHALATE || 1072.0 361.5
(NAPHTHALENE || 431.4 73.4
ILINOANE || 424.7 63.2
(DIELDRIN || 605.6 3U.B
1 II
PRIMARY EFFLUENT
AVERAGE STANDARD
DEVIATION
UG/L
307.8 19.2
318.6 45.1
344.0 30.4
458.9 91.5
415.0 84.8
59.4 33.1
310.9 91.5
578.1 123.1
269.2 87.9
222.8 40.6
238.6 55.3
560.3 357.7
479.7 57.7
271.6 46.6
223.8 43.6
556.1 294.5
383.7 40.4
349.3 52.2
264.5 120.2

SECONDARY EFFLUENT
AVERAGE STANDARD
DEVIATION
UG/L
22.7 18.8
41.4 18.7
18.8 22.3
89.1 34.4
31.9 12.5
7.8 7.1
124.5 53.0
173.5 125.5
34.2 55.5
9.9 8.3
14.8 17.3
12.9 16.0
11.9 8.4
16.7 15.4
12.4 15.6
386.4 185.5
8.9 5.0
177.9 184.1
98.7 59.5

PRIKARY SLUDGE
AVERAGE STANDARD
DEVIATION
UG/L
11716 5282
10485 6194
11278 5264
39392 17807
377 808
716 561
78 163
1534 623
854 639
98 133
41586 20151
484 164
1040 397
25709 9874
29667 10940
79811 49454
10227 6567
15719 5866
16549 18119

SECONDARY SLUDGE
AVERAGE STANDARD
DEVIATION
UG/L '
233 174
373 223
120 134
2709 1736
152 152
1101 411
1460 2570
85 64
93 57
269 304
1962 1385
68 92
105 HO
566 447
596 501
35915 36469
108 112
1919 1620
13538 7180

               * Only one data point available

-------
                     TABLE 12.  AVERAGE PERCENT REMOVALS AND PARTITIONING OF CERCLA
                                        ORGANICS FOR THE ACCLIMATED SYSTEM
ro
OJ

COMPOUNDS

PRIMARY TREATMENT) TOTAL TREATMENT | REMOVED IN SLUDGE) BIODEGRADATION |


REMOVAL STANDARD

1
IDICHLOROBENZENE, PROBABLY 1,2 |
X DEVIATION
I
| 15.1 11.7
(DICHLOROBENZENE, PROBABLY 1,3 || is.o 9.9
IDICHLOROBENZENE, PROBABLY 1,4 |
[1,2,4-TRICHLOROBENZENE |
INITROBENZENE |
1,3-DINITROBENZENE |
| 11.3 11.6
| 27.2 15.0
| 6.9 12.8
| 79.0 9.8
|2,6-DINITROTOLUENE || 23.3 18.5
P-CRESOL |
4-CHOLOROANILINE |
HEXACHLOROETHANE |
HEXACHLOROBUTADIENE |
DIMETHYL PHTHALATE ' |
DIETHYL PHTHALATE |
| -5.2 11.3
21.4 35.2
34.3 16.2
39.8 13.6
3.5 6.2
3.6 7.8
DIBUTYL PHTHALATE || 36.5 10.7
BUTYL BENZYL PHTHALATE || 43.6 11.3
BIS(2-ETHYLHEXYL)PHTHALATE
NAPHTHALENE
LINDANE |
| 49.8 12.7
| 9.9 9.6
| 18.7 8.0
DIELDRIN || 54.0 15.2
I
I
I I I
I I
REMOVAL STANDARD (REMOVAL STANDARD (REMOVAL STANDARD
% DEVIATION
93.4 4.3
88.9 5.1
95.3 5.2
85.1 7.8
92.8 2.6
96.7 3.7
68.2 15.3
73.9 21.9
87.6 23.1
97.1 2.5
96.2 4.5
98.1 1.5
97.6 1.6
96.1 3.7
96.9 3.9
63.3 14.4
97.9 1.3
55.9 39.2
81.4 9.1

X DEVIATION
20.0 8.9
15.8 9.9
17.1 9.4
37.0 11.6
0.9 1.3

11.8 15.3
1.? 0.8
1'.9 0.8
0.0 *
50.1 16.1
0.7 0.3
1.5 0.5
41.5 10.4
49.0 12.1
71.5 23.8
14.2 8.7
27.5 10.0
48.1 18.5

% DEVIATION
72.9 9.9
72.1 10.5
78.8 10.0
48.1 13.9
91.3 3.4

57.1 38.3
69.0 20.6
78.2 27.7
99.7 *
47.2 16.5 ||
97.4 1.5 ||
96.2 1.8 ||
53.6 9.9 ||
47.0 12.3 ||
-13.2 22.0 ||
83.6 8.4 ||
28.5 38.3 ||
35.9 24.0 ||
I
                                          * Only one data point available

-------
                  TABLE 13.
ro
                             AVERAGE MASSES IN GRAMS OF CERCLA ORGAN1CS IN WASTLWATER
                                     AND SLUDGES FROM THE UNACCLIMATED SYSTEM
|| UASTEUATER FEED
II
II
Compounds || AVERAGE STANDARD
|| DEVIATION
II
II
II
(DICHLOROBENZENE. PROBABLY 1,2 || 93.0 26.2
(DICHLOROtENZENE. PROBABLY 1,3 || 104.8 35.4
IDICHLOROBENZENE, PROBABLY 1,4 || 96.6 26.0
(1,2,4-TRICHLOROBENZENE || 164.4 37.0
(NITROBENZENE || 113.3 33.7
|1,3-OINITROBEHZENE || 61.7 14.7
(2,6-DINITROTOLUm || 96.0 18.8
IP-CRESOL || 152.5 37.9
(4-CHLOROANIIINE ||
(HEXACHLOROETHANE || 56.5 16.3
IHEXACHLOROBUTADIENE || 75.7 25.5
(DIMETHYL PHTHALATE || 72.3 19.3
IDIEIHYL PHTHALAIE || no.a 30.6
IDIBUIYL PHTHALATE || 102.7 16.7
(BUTYL BENZYL PHTHALATE || BO. 5 19.5
|BIS(2-ETHYLHEXYL)PHTHALATE ||
(NAPHTHALENE || 120.7 30.2
ILINOAHE || 87.9 20.9
IDIELDRIN || 189.4 125.5
1 II
PRIMARY EFFLUENT
AVERAGE STANDARD
DEVIATION


76.8 16.2
85.2 20.3
78.8 14.7
124.2 7.7
105.3 31.8
8.4 2.0
73.5 34.2
109.7 73.3

31.8 10.0
36.0 12.7
61.8 24.4
112.4 28.3
80.4 26.7
49.1 13.0

109.7 34.6
73.0 16.0
99.6 97.0

(SECONDARY EFFLUENT
AVERAGE STANDARD
DEVIATION


13.8 5.9
14.8 4.1
11.2 3.5
20.2 4.0
44.1 16.3
8.4 6.7
12.7 5.8
5.8 8.6

0.0 0.0
1.7 0.4
2.2 1.2
3.6 1.1
3.8 1.2
2.0 0.5

6.1 5.1
39.7 18.3
10.1 11.6

| PRIMARY SLUDGE
AVERAGE STANDARD
DEVIATION


9.6 9.4
9.3 10.7
7.9 7.6
56.0 55.9
0.7 0.7
0.9 1.0
15.8 31.5
6.0 4.6

28.2 48.1
5.4 5.0
16.8 23.7
13.2 25.1
28.8 48.3
15.1 11.3

10.5 16.9
5.2 2.5
4.0 5.2

SECONDARY SLUDGE
AVERAGE STANDARD
DEVIATION


2.2 2.9
2.5 3.4
1.6 2.4
13.2 14.4
1.4 2.5
2.1 1.6
0.0 0.0
0.0 0.0

0.0 0.0
5.7 7.9
0.0 0.0
0.1 0.1
0.8 0.5
0.6 0.5

0.5 0.4
9.2 11.6
10.2 10.5


-------
                       TABLE 14. AVERAGE PERCENT REMOVALS AND PARTITIONING OF CERCLA
                                          ORGANICS  FOR  THE UNACCLIMATED  SYSTEM
ro
CJ1
| (PRIMARY


Conpounds



IDICHLOROBENZENE. PROBABLY 1.2
IOICHLOROBENZENE, PROBABLY 1,3
IDICHIOROBENZENE, PROBABLY 1.4
|1,2,«-TRICHLOROBENZENE
INITROBENZENE
|1,3-DINUROBEMZENE
I2.6-OIN1TROTOLUENE
IP-CRESOL
[4-CHLOROANILINE
IHEXACHLOROETHANE
IHEXACHLOROBUTADIENE
[DIMETHYL PHTHALATE
IDIETHYL PHTHALATE
IDIBUTYL PHTHALATE
BUTYL BENZYL PHTHALATE
|BIS(2-ETKYLHEXYL)PHTHALA1E
[NAPHTHALENE
LIHOANE
OIELDRIN
II
II


| (REMOVAL
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II

X

20
17
17
22
17
88
31
20

43
50
10
4
22
39

13
16
43
TREATMENT
TOTAL
1
1
STANDARD (REMOVAL
DEVIATION)


10
7
6
15
6
2
24
43

8
16
36
12
19
3

3
15
31
X

84
85
88
87
58
86
86
97

100
98
96
97
96
97

95
52
95
TREATMENT


STANDARD
DEVIATION


8
7
4
6
20
11
9
4
0
0
1
2
1
1
1

4
26
3
REMOVAL


REMOVAL

X

11
9
9
19
2


6


30
11
1
7
26

19
18
19
IN SLUDGE IBIODEGRADATION + ||


STANDARD
DEVIATION


8
8
7
6
2


*


»
14
0
*
11

26
10
13
STRIPPING ||

REMOVAL

X

74
75
79
66
50


94


66
85
96
88
71

79
28
78
II
STANDARD ||
DEVIATION) |
II
II
II
7 II
5 II
6 II
1 II
18 ||
II
II
* II
II
II
» II
10 1)
1 II
* II
10 (1
II
25 ||
19 ||
16 ||
II
                                         * Only one data point avaitable.

-------
emissions were not measured for the semi volatile organics, the removal
mechanisms during the CERCLA study period are reported in Table 14 as
removal in sludge and the combined biodegradation + stripping.  The raw
data on the individual sample events in the CERCLA study period are also
included in Appendix 2.
OVERVIEW OF THE RESULTS
     Substantial variability occurs in the reported results because some
compounds, especially in the RCRA study period, were not satisfactorily
identified in the analytical tests.  In the RCRA study five spiked toxics,
two volatile polar solvents (cyclohexanone and furfural) and three phenols
(2,4-dimethyl phenol, 2,4-dinitrophenol, and 4-nitrophenol) were not
satisfactorily identified by the analytical methodology.  In the CERCLA
study, all of the tested toxics were measurable by the analytical procedures,
but in the small data base for the unacclimated operation, two compounds,
4-chloroaniline and bis(2-ethylhexyl) phthalate, were not satisfactorily
identified by the analytical tests.
     The concentrations or masses of the organics in the various samples
from the treatment systems revealed good results in the air samples from
the RCRA study and reasonable results in the secondary effluents for both
studies.  The analytical methodology used by the contractor laboratory
for the RCRA study period produced poor results on the concentrations or
masses of organics in the samples on raw, primary and sludge streams.
The contractor laboratory did not use the stable-labelled isotopes in
their analytical procedures.  In the CERCLA study period, the  in-house
U.S. EPA laboratory used stable-labelled isotopes in the analytical procedures.
The results were generally improved for the raw and primary wastewater

                                    26

-------
samples compared to the RCRA study period.  However, even with the stable-
labelled  isotopes  in the procedure, the amounts of organics found in the
complex sludge samples are substantially lower than the measured removals
across the primary process.  There is a strong indication that organics
quantitation by available methods is not reliable in a sludge matrix,
and, as a result, mass balance closure in these studies is generally
poor.
     Appendix 4 provides a quality assurance summary of the RCRA and CERCLA
data.  Included are analytical recoveries, percent of collected data
usable for removal and fate calculations and relative percent differences
between collected duplicate samples.  There is also a discussion of the
process used to retain or exclude data.
     The overall organic removals reasonably correspond with overall
removals for these organic compounds in other studies.  The concentrations
of organics in the air emissions generally indicate that the chlorinated
aliphatic solvents are essentially volatilized into the plant air emission
stream, whereas the aromatic volatile benzenes (toluene, xylenes,
chlorobenzenes) are substantially degraded.  Pesticides and phthalates
are removed by both sorption on sludges and by biodegradation.  These air
emission results qualitatively confirm results from earlier bench scale
studies which had superior analytical reliability but without the real
world sampling and wastewater matrix effects.   Unfortunately, the
variability in the results does not reliably permit calibration of a
mechanistic model  which is being developed through other treatability
studies.   Additional  work is planned to attempt to reduce the analytical
variability encountered in these studies.
                                    27

-------
APPENDIX 1.  RCRA STUDY PERIOD
               28

-------
                                CONCENTRATIONS OF RCRA ORGANICS IN WASTEUATER, SLUDGE ANO AIR
                                               SAMPLES - ACCLIMATED SYSTEM EVENT 3
             NAME
Acetone
Cyclohexanone              —
Furfural
2-butanona
4-methyl-2-pantanon*
Tttrahydrofuran
Carbon Tetrachloride
Chlorobenztne
Chloroform
1,2-dichloroethane
1,2-dtchloropropane
Methylene CMoridt
Tetrachloroethylene
Trichloroethylene
1,1,1-trichloroethane
1,1,2-trichloroethane
Ethylbenzene
Toluene
Total xylenei
bis-(2-ethylhexyl)-phthal«te
Butylbenzylphthalate
1,4-diehotorobenzene
2,4-dlmethylphenol
2,4-dinitrophenol
Naphthalene
Nitrobenzene
4-nitrophenol
Phenol
mmmmmmmmm
II «i
II INF
II
II ug/L
i i ••«••••
I i «»*»»»«
|| 3400
II
II
II
II
II 218
II
II 283
II WO
II 314
II
II 660
II 257
II 255
II
II 254
II 238
II 313
II 1»
II 120
II 52
II 130
II
II
II
|| 170
II
II 350
PR I
INF
(DUP)
Ug/L
2500
170
360
290
320
340
260
503
250
250
300
230
250
310
140
130
41
130
210
180

370
PR I
EFF

Ug/L
2700
210
300
260
290
310
230
450
220
220
240
210
230
380
120
93
22
130
190
170

320
PR I
EFF
(DUP)
Ug/L
1400
190
310
260
280
310
240
455
213
216
250
220
230
400
120
90
30
130
190
150

340
••»*«•*•
SEC
EFF

Ug/L
50
150
2.5
4
34
110
40
60
9
2.5
2.5
100
2.5
2.5
2.5
5
5
5
5
5

5
SEC
WAS

Ug/L
260
10
5
5
34
5
5

10
7
5
25
5
10
5
160
5
5
5
5

5
PRI
WAS

ug/L
800
150
110
300
330
300
250

150
360
280
220
300
400
160
1100
740
230
340
29

320
PRI
UAS
(OOP)
Ug/L
2200
200
105
300
340
330
240

160
350
260
210
370
410
190
760
320
200
250
69

320
PRI
AIR

Ug/L
0.10
0.00
0.23
0.17
0.18
0.13
0.15
0.27
0.19
0.19
0.23
0.09
0.15
0.25
0.13







»•••••••
AERTN
AIR

Ug/L
0.00
0.32
7.31
1.50
5.20
3.33
4.99
4.86
6.05
5.11
6.56
2.67
0.83
1.46
1.10







                                                       29

-------
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-------
                                 REMOVAL AMP PARTITIONING OF RCRA ORGANICS  DURING
                                   TREATMENT - ACCLIMATED SYSTEM EVENT 3
             NAME
||    X       X      X IN    X  IN   X  IN    X          X          ||
II                                                               II
||PRIHART   TOTAL   PRIMARY AERATION TOTAL ADSORBED  BIODEGRADED   ||
11REMOVAL  REMOVAL    AIR     AIR     AIR            +CHEM. TRANS. 11
Acetone                   -
Cyelohexanone
Furfural
2-butanone
4-mthyl-2-pcntamn*
Tetrahydrofuran
Carbon TetracMoride
Chlorobenzene
Chloroform
1,2-dichloroethane
1,2-dichloropropane
Methylene Chloride
Tetrachloroethylene
Trichloroethylene
1,1,1 -trichIoroethane
1,1,2-trichloroethane
Ethylbenzene
Toluene
Total Xylenes
bis-(2-ethylhexyl)-phthalate
ButylbenzyIphthaIate
1,4-dicholorobenzene
2,4-dimethylphenol
2,4-dinitrophenol
Naphthalene
Nitrobenzene
4-nitrophenol
Phenol
                                     31
                                             98
-3
15
9
14
5
10
22
15
U
18
11
6
37
11
27
44
0
10
9
23
99
99
90
66
89
90
97
99
99
59
99
100
98
96
89
96
98
97
0
9
6
7
5
6
9
7
7
8
4
6
8
4





5
119
24
83
54
81
70
97
83
101
44
13
19
16





5
128
30
90
59
87
80
104
91
109
47
19
26
20





1
1
1
2
1
2

1
2
2
1
2
2
2
12
U
2
2
0
16
-31
68
-2
6
-11

-8
7
-12
10
79
71
76
84
76
94
95
97
                                                                                    98
                                                  31

-------
                                 CONCENTRATIONS OF RCSA ORGANICS IN UASTEVATER. SLUDGE AW AIR
                                            SAMPLES  - ACCLIMATED SYSTEM - EVENT 4
             NAME
Acetone                 -
Cyclohexanone
Furfural
2-Butanone
4-*ethyt-2-Pentanone
Tetrahydrofuran
Carbon Tetrachloride
ChIorobenzene
Chloroform
1,2-Oichloroethane
1,2 • 0 i ch I oropropane
Methylene Chloride
Tetrachloroethylene
Trichloroethylene
1,1,1-Trichloroethane
1,1,2-Triehloroethane
Ethylbenzene
Toluene
Total Xylenes
8is-(2-ethylhexyO-phthalate
Butylbenzytphthalate
1,4-dicholorobenzene
2,4-Oimethylphenol
2,4-Oinitrophenol
Naphthalene
Nitrobenzene
4-Mitrophenol
Phenol
mmmmmmmmm
II wi
II I»
-------
                                       MASSES IN GRAMS OF RCRA ORGAN ICS III UASTEUATER,  SLUDGE AND
                                              AIR STREAMS - ACCLIMATED SYSTEM EVENT 4
             NAME
Acetone            -
Cyclohexanone
Furfural
2-Butanone
4-MethyI-2-Pentanone
Tetrahydrofuran
Carbon Tetrachloride
Chlorobenzene
Chloroform
1,2-Dichloroethane
1,2-Oichloropropane
Methylene Chloride
Tetrachloroethylene
Triehloroethylene
1,1,1-Trichloroethane
1,1,2-Triehloroethane
Ethylbenzene
Toluene
Total Xylenes
Bis-(2-ethylhcxyl)-phthalate
Butylbenzylphthalate
1,4-dicholorobenzene
2,4-Dimethylphenol
2,4-Oinitrophenol
Naphthalene
Nitrobenzene
4-«itrop*ienol
Phenol
*»
II
II
II
II
1 tl
1 1
II
1
1
1
1
1
11
fl
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
11
II
nswBv
RUU



169.1


40.7
0.0
0.0
0.0
3.1
1.9
0.0
0.0
18.8
24
.O
0.0
6.2
0.0
3.9
36.6
10.1
9.4
1.9
1.9


2.2
1.9

zsaxnai
PR I
INF


200.7


74.8
40.4
74.0
107.2
98.1
102.6
106.8
96.5
164.4
ft1 T
01 • J
80. 5
111.0
94.2
74.0
109.1
76.3
57.2
35.1
42.0


49.6
49.6

BBSSKH
PR I
EFF


230.8


58.0
54.6
85.8
120.2
108.7
118.3
127.8
103.0
202.2
en E
TJ.J
91.6
120.2
99.2
89.7
116.4
87.8
45.8
16.4
37.8


45.8
45.8

PRIM
AIR


7.4


1.1
1.1
0.4
11.1
7.4
7.4
7.4
7.4
14.8
7.4
11.1
3.7
7.4
11.1
7.4








PRIM
AIR

COUP)
7.4


1.9
1.1
1.1
11.1
7.4
7.4
7.4
7.4
14.8
7.4
11.1
3.7
7.4
11.1
7.4








PR1
WAST


4.


0.
0.
1.
1.
2.
2.
2.
1.

1.
2.
1.
1.
2.
1.
1.
1.
0.


0.
0.





7


5
9
1
7
1
4
0
7

8
5
6
8
6
7
7
4
0


6
2

SEC
EFF


8.8


.9
.9
.9
.1
.0
16.0
47.3
22.9
48.1
2.7
3.1
50.4
1.0
1.9
0.8
1.9
1.9
1.9


1.9
1.9

SEC
EFF

(DUP)
1S.3


1.9
1.9
1.9
2.3
1.0
25.9
81.6
35.5
87.4

5.0
12.2
1.0
1.5
1.0
1.9
1.9
1.9


1.9
1.9

SEC
WAST


0.9


0.0
0.0
4.0
0.1
0.0
0.8
2.1
1.0

1.1
0.1
0.0
2.1
0.0
0.2
0.0
0.0
0.0
0.0


0.0
0.0

AERTN
AIR


6.2


0.1
0.5
4.7
132.4
26.5
98.1
63.9
88.8
120.0
130.9
93.5
124.6
51.4
15.6
26.5
31.2








II
II
II
II
II
II
                                  35.2  122.1  141.2
                                                                      1.2
                                                                             1.9    1.9
                                                                                           0.0
                                                       33

-------
REMOVAL AND PARTITIONING OF RCRA ORGANICS OUR INC
     1 TREATMENT - ACCLIMATED SYSTEM EVENT 4
NAME
II -
II
| [PRIMARY
| | REMOVAL
-.———..——»—•——— ———g—»^— »~——^——^~ 1 I =— — ==— as=aa
Acetone
Cyclohexanone
Furfural
2-3utanone
4-Methyl -2-Pentanene
Tetrahydrofuran
Carbon Tetrachloride
CUorcbeniene
Chloroform
1 , 2-0 i eh I oroe thane
1 ,2-Oich loropropane
Methylene Chloride
Tetrachloroethylene
Trichloroethylene
1 , 1 , 1 -T ri ch I oroe thane
1 , 1 ,2-Tri ehloroethane
Ethylbenzene
To I uene
Total Xytenes
Bis-(2-ethylhexyl)-phthalate
Butylbenzylphthalace
1 ,4-dicholorobenzene
2,4-Dimethylphenol
2,4-Oinitrophenol
Naonthalene
N i trobenzene
4-1itrcpnenol
Phenol
II
II
II
II
II
II
11
11
II
II
II
11
li
II
11
II
II
II
•II
II
II
II
II
11
II
11
II
11
-15


22
-35
-16
-12
-11
-15
-20
-7
-23
-15
-14 '
-8
-5
-21
-7
-15
20
53
10


8
a

-16
S3S33XS3:
TOTAL
REMOVAL
94


97
95
97
98
99
80
40
70
59
94
98
96
67
99
98
99
97
95
95


96
96

98
X IN
PRIMARY
AIR
2


1
1
- 1
12
8-
8
8
8
15
8
8
11
4
a
9
7









X IN
AERATION
AIR
2


0
1
5
139
27
102
67
93
118
135
98
127
54
16
22
30









X IN X
TOTAL ADSORBED
AIR
4


1
2
6
151
35
110
75
101
133
143
106
138
58
24
31
37










3


1
2
7
2
2
3
4
3

3
2
2
4
2
3
2
3
4
0


1
0

1
5
BIOOEG3AOEO
+CHEM. TRAMS,
87


95
91
84
-55
62
-33
-39
-34

-52
-10
-44
5
73
64
60
94
91
95


95
96

97
II
II
II
• II
._ I 1
"11
II
II
II
11
II
II
11
II
II
II
II
11
11
II
II
II
11
II
II
II
11
11
II
II
II
II
11
II
                  34

-------
                                CONCENTRATIONS OF RCRA ORGANICS  IN  UASTEUATER,  SLUDGE  AND  AIR
                                       SAMPLES -  ACCLIMATED  SYSTEM  EVENT  5
      ACCLIMATED SYSTEM
             HAME
Acatona
Cyclohaxanona
Furfural
2-buttnont
4-mathyl-2-pantanona
Tetrahydrofuran
Carbon Tatraehlon'da
Chlorobanzana
ChIorofona
1,2-dichloroathana
1,2•dichIoropropant
Methylana CMorida
Tatrachtoroathylana
T r i chIoroathyIana
1,1,1-tri chloroathana
1,1,2-trtchloroathana
Ethytbanzana
Totuana
Total Xylana*
bis-(2-athylhtxyl)-phthalata
Butylbanzylphthalata
1,4-dichlorobanzana
2,4-dimathyIphenol
2,4-dinitrophanol
Naphthalana
Nitrobanzana
4-nitrophanol
Phenol
imm*999t
PHI
INF

ug/L
1100
63
420
220
160
230
170
180
330
180
150
200
170
160
270
200
94
62
60
91
82
270
»••••«*•
PR I
INF
(DUP)
Ug/L
630
81
320
200
120
210
160
160
250
150
130
180
150
140
240
180
77
30
71
91

140
!•••••*«
PR1
EFF

Ug/L
590
24
180
250
120
170
130
130
210
120
100
140
130
110
190
140
73
30
56
89
85
170
IXBBMMVI
SEC
EFF

Ug/L
5
5
1
230
3
2.5
28
46
83
a
5
2.5
110
2.5
2.5
2
2.5
5
5
5
5
6
SEC
WAS

Ug/L
5
5
5
42
2.5
2.5
4
2.5

2
1
2.5
17
1
1
2
300
5
6
5
18
5
SEC
WAS
(DUP)
Ug/L
11
5
7
5
2.5
2.5
4
2.5

2
1
2.5
18
1
1
2
220
5
7
5
5
5
I •»••••!
PR!
WAS

Ug/L
1200
19
14
24
8
24
16
15

14
14
16
15
15
23
19
900
500
180
260
100
290
** * *«*•* a
PHI
AIR

(Ug/L)
0.10
0.02
0.03
0.04
0.20
0.40
0.20
0.20
0.30
0.20
0.20
0.20
0.10
0.20
0.30
0.20






(•••MX**
AERTH
AIR

(Ug/L)
0.20
0.005
0.005
0.40
8.20
3.90
6.80
5.80
9.00
8.60
6.40
7.50
3.70
1.00
2.60
2.10






                                                    35

-------
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-------
REMOVAL AND PARTITIONING OF RCRA ORGAMICS DURING
     TREATMENT - ACCLIMATED SYSTEM EVENT 5
ACCLIMATED SYSTEM

NAME
Action*
Cyclohtxcnon*
Furfuril
2 -but anon*
4-Mthyl-2-p*ntanon*
Tctrihydrofurwi
Carbon TetracMorid*
Chlorob*nt«n*
Chloroform
1 ,2-dlcMoro*th*n*
1 1 . rli l-h 1 nrnnrrmmnm
i t £ Qicnioroprop*n*
M*thyl*n* Chlorid*
Tttraehloro*thyl*n*
Triehloro*thyt*n*
1 ,1 , 1 -triehtoro*th*n*
1,1,2-tr1chloro*thm*
Ethylb*nz*n*
Tolucn*
Total Xyl*n*«
bi«-<2-*thylh*xyO-phthtt«t*
Butytb*nzylphth*ltt*
1,4-dichlorob*nz*n*
2,4-din»thytphtnol
2,4-d
-------
                                                    CONCENTRATIONS OF RCRA ORGANICS IN UASTEUATER, SLUDGE AND AIR

                                                                SAMPLES - UNACCLIHATED SYSTEM EVENT 3
CO
CD
|| RUU
NAME ||
II
II U«/l
«"««««
Acetone | | 830
Cyclohexanone ||
Furfural | |
2-butanone ||
4-»ethyl-2-pentanone || 30
Tetrahydrofuran | |
Carbon Tetrachloride ||
Chlorobenzene 1 1 12
Chloroform 1 1 8
1,2-dichloroethane ||
1,2-dichloropropane ||
Methylene Chloride || 66
Tetrachloroethylene 1 1 6
Trlchloroethylene ||
1.1,1-trlchloroethane || 11
1,1.2-trichloroethane ||
Ethyl benzene || 9
Toluene | | 67
Total Xylenes || 17
bls-(2-«thylhexyl)-phthalate || U
Butylbenzylphthalate ||
1.4-dlchotorobenzene ||
2.4-diMethylphenol ||
2,4-dinltrophenol ||
Naphthalene | | 18
Nitrobenzene ||
4-nitrophenot , ' ||
Phenol | | 195
PRI
INF
Ufl/L
990



160
150
220
220
200
140
160
340
96
130
160
180
150
170
190
86
31
150


130
140
120
410
PRI
INF
(DUP)
ug/L
1100



190
150
120
150
210
140
140
330
96
130
160
180
150
170
190
93
34
130


130
130
120
380
PRI
EFF
Ug/L
970



110
130
57
72
72
52
52
220
49
63
57
62
44
82
69
37
11
110


120
140
120
370
PRI
EFF
UB/L
34



5
92
2.5
14
23
42
34
53
13
12
6
68
7
4
11
5
5
22


5
40
25
5
PRI
EFF
(OOP)
Ug/L
45



5
93
4
12
21
37
30
80
12
10
6
62
7
4
10
5
5
12


5
24
25
5
MIXED
LIQUOR
0 MRS
Ug/L
17



5
11
2.5
3
2
2.5
2.5
22
2.5
2.5
2.5
2.5
2.5
39
2
30
5
5


5
5
25
28
MIXED
LIQUOR
48 HRS
Ug/L
15



5
35
2.5
1
2
4
2
43
1
2.5
2.5
11
1
3
1
69
5
5


5
5
25
5
SEC
WAS
Ug/L
1200



5
5
2.5
2.5
2.5
2.5
2.5

2.5
2.5
2.5
46
110
86
110
37
5
20


5
6
25
6
PRI
WAS
Ug/L
1500



190
300
64
160
200
120
130

130
120
100
130
100
240
19
170
120
51


73
5
25
140
PRI
WAS
(DUP)
Ug/L
1300



150
210
71
170
200
110
120

130
140
130
130
100
270
200
250
140
73


100
54
25
380
PRI.
AIR
Ug/L
0.01



0.02
0.00
0.19
0.15
0.16
0.08
0.10
0.20
0.20
0.18
0.23
0.08
0.11
0.22
0.10









|AERTN.|
AIR |
1
ug/L |
	 1
0.01 |
I
I
I
0.00 |
0.12 |
2.81 |
1.55 |
2.07 |
1.05 |
1.69 |
1.82 |
3.01 |
2.39 |
3.07 |
1.19 |
1.58 |
1.56 |
1.22 |
1
1
1
1
1
1
1
1
1
=======
                                                                                                                                                 II

-------
             NAME
Action*                   -
Cyclohexanone
Furfural
2-butanon*
4-methyl-2-pentanone
Tetrahydrofuren
Carbon Tetrachloride
Chlorobtnzen*
Chloroform
1,2-dichloroethane
1,2-dichloropropan*
Hethylene Chloride
Tetrachlorocthylene
Triehloroethytene
1,1,1-trichloroethane
1,1,2-trichloroethane
Ethylbenzene
Toluene
Total Xylenes
bis-(2-ethylhexyl)-phthalatt
Butylbenzylphthalate
1,4-dicholorobenzene
2,4-dimathylphanol
2,4-dinitropnenol
Naphthalene
Nitrobenzene
4-nitrophenol
Phenol
                                      MASSES IN GRAMS OF RCRA ORGANICS IN UASTEUATER, SLUDGE AND AIR
                                              STREAMS - UNACCLIMATED SYSTEM EVENT 3
                                    RUU    PRI
                                                  PR I
                                                         PRI   PRI   PRI
                                                                            PR I   AERTN   SEC
                                                                                                 SEC
                                                                                                        SEC  MIXED
                                           INF    INF    EFF   AIR   WAS    WAS    AIR    EFF    EFF    WAS  LieUOR  jj
                                                                                                                     II
                                                 (DUP)
                                                                           COUP)
                                                                                                COUP)
II™
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
185.3


6.7
0.0
0.0
2.7
1.8
0.0
0.0
14.7
1.3
0.0
2.5
0.0
2.0
15.0
3.8
3.1
0.0
0.0
4.0
0.0
0.0
43.5
221.0


35.7
33.5
49.1
49.1
44.6
31.2
35.7
75.9
21.4
29.0
35.7
40.2
33.5
37.9
42.4
19.2
6.9
33.5
29.0
31.2
26.8
91.5
245.5


42.4
33.5
26.8
33.5
46.9
31.2
31.2
73.7
21.4
29.0
35.7
40.2
33.5
37.9
42.4
20.8
7.6
29.0
29.0
29.0
26.8
84.8
246.1


27.9
33.0
14.5
18.3
18.3
13.2
13.2
55.8
12.4
16.0
14.5
15.7
11.2
20.8
17.5
9.4
2.8
27.9
30.4
3S.5
30.4
93.9
0.4


0.8
0.0
7.8
6.2
6.6
3.3
4.1
8.2
8.2
7.4
9.5
3.3
4.5
9.0
4.1







7.7


1.0
1.5
0.3
0.8
1.0
0.6
0.7

0.7
0.6
0.5
0.7
0.5
1.2
0.1
0.9
0.6
0.3
0.4
0.0
0.1
0.7
6.7


0.8
1.1
0.4
0.9
1.0
0.6
0.6

0.7
0.7
0.7
0.7
0.5
1.4
1.0
1.3
0.7
0.4
0.5
0.3
0.1
2.0
0.2


0.0
2.0
47.9
26.4
35.3
17.9
28.8
31.0
51.3
40.7
52.3
20.3
26.9
26.6
20.8







13.0


1.9
35.1
1.0
5.3
8.8
16.0
13.0
20.2
5.0
4.6
2.3
25.9
2.7
1.5
4.2
1.9
1.9
8.4
1.9
15.3
9.5
1.9
17.2


1.9
35.5
1.5
4.6
8.0
14.1
11.4
30.5
4.6
3.8
2.3
23.7
2.7
1.5
3.8
1.9
1.9
4.6
1.9
9.2
9.5
1.9
9.8


0.0
0.0
0.0
0.0
0.0
0.0
0.0

0.0
0.0
0.0
0.4
0.9
0.7
0.9
0.3
0.0
0.2
0.0
0.0
0.2
0.0
-0


0
1
0
-0
0
0
0
1
-0
0
0
1
•0
-2
•0
2
0
0
0
0
0
-1
                                                            39

-------
                                REMOVAL AMD PARTITIONING OF RCRA ORGANICS DURING
                                    TREATMENT -  UNACCLIMATEO SYSTEM EVEMT 3
                                                  X IN
                                                          X IN   X IN
             NAME
II                                                               II
I(PRIMARY   TOTAL  PRIMARY  AERATION  TOTAL ADSORBED   BIODEGRADED   ||
||REMOVAL  REMOVAL    AIR     AIR     AIR             +CHEM.  TRANS.||
Acetone                   _
Cyclohexanone
Furfural
2-butanone
4-methyl-2-penttnone
Tetrahydrofuran
Carbon Tetrachloride
Chlorobenzene
Chloroform
1,2-dichloroethane
1,2-dichloropropane
Methylene Chloride
Tetrachloroethylene
Trichloroethylene
1,1,1-trichloroethene
1,1,2-trichloroethane
Ethyl benzene
Toluene
Total Xylenes
bis-<2-ethylhexyl)-phth«lat«
Butylbenzylphthalate
1,4-dieholorobenzene
2,4-diinethylphenol
2,4-dinitropftenol
Naphthalene
Nitrobenzene
4-nitrophenol
Phenol
,,».
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
•6



29
2
62
56
60
SB
61
25
42
45
59
61
67
45
59
53
61
11
94



95
-5
97
88
82
52
64
66
78
86
94
38
92
96
91
91
74
79
0



1
0
16
12
13
7
9
12
16
16
18
7
9
9
7



0



0
4
100
49
69
38
60
46
97
85
97
43
51
26
37



0



1
4
117
61
82
44
69
58
112
101
115
50
59
35
45



7



2
4
1
2
2
2
2

3
2
2
3
4
5
3
7
9
2
""*" 1 1
86 ||
II
II
11
92 ||
•15 ||
-21 ||
25 ||
-3 II
5 II
-7

•38
•18
•23
-H
28
58
43
81 |
65 |
n I
       •5
      -18
      -13
       -7
93
59
65
98
92
59
64
98
                                                 40

-------
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-------
REMOVAL AMD PARTITIONING OF ROU ORGAN1CS DURING
    TREATMENT -  UNACCLIMATED SYSTEM EVENT 4

NAME


Acetone —
Cyelotraxanont
Furfuril
2-Buttnom
4-M«thyl-2-Pent«ncne
Tetrihydrofurin
Carbon Tetrichloride
Chtorobenzene
Chlorofom
1,2-Dichloroethene
1,2-Oichloropropene
Mcthyicnc Chloride
Tet rich loroethy I ene
Triehloroethyten*
1,1,1-Trichloroethene
1 , 1 ,2-Trichloroethene
Ethyl benzene
Toluene
Total Xylent*
Bis-(2-ethylhexyl)-phthalite
Butylbenzylphthalete
1,4-Oicholorobenzene
2,4-OiMthylphtnol
2,4-Dinitrophenol
Naphthalene
Nitrobenzene
4-Nitrophtnol
Phenol
II «
II
| | PRIMARY
1 1 REMOVAL
II -17
II 15
II
II 8
II -n
II
II 10
II *
II 16
II °
II 5
II "9
II 8
II 7
II 10
II 1
II 4
II -5
II 2
II 61
II "
II "
II
II
II o
II «
II
II 30
X

TOTAL
REMOVAL
98
88

95
77

99
93
90
70
77
78
94
95
97
49
94
98
97
92
87
77


90
77

95
X IN

PRIMARY
AIR
4
0

1
3

17
16
16
9
9
24
16
17
15
9
8
11
6









X IN

AERATION
AIR
3
0

0
0

171
73
116
61
107
111
173
136
175
57
84
42
52









X IN

TOTAL
AIR
7
0

1
3

188
89
132
70
116
135
189
153
190
66
92
53
58









X

ADSORBED

4
1

2
4

1
2
2
3
2

1
2
2
3
1
2
1
7
0
3


2
1

0
x II
II
BIODEGRADED | |
+CHEM. TRANS. ||
>••*••••••••••••• 1 I
87 ||
87 ||
||
92 ||
70 ||
| |
-90 ||
2 II
-44 ||
-3 II
-41 | |
II
-96 ||
-60 ||
-95 ||
-20 ||
1 II
43 ||
38 II
85 ||
87 ||
74 ||
||
II
88 ||
76 ||
||
W ||
                                                          ************
               43

-------
CONCENTRATIONS OF RCRA ORGANICS IN UASTEUATER, SLUDGE AND AIR
         SAMPLES - UMACCLIMATED SYSTEM EVENT 5
UNACCUNATED SYSTEM || RUU
II
II
NAME || 09/1
»mm«mmBmmm«am •* **»*•»••••»»» 1 1 •••»••*
Acetone || 420
Cyclohexenone 1 1
Furfural | |
2-but«nooe jj 55
4-Mthyt-2-pent«none ||
Tetrehydrofuren || 17
C*rbon Tetrechlorlde || 2
Chtorobenzene | | 61
Chlorofom 1 1 6
1,2-dfchloroethene || 5
1,2-dichloroprofMne ||
Methylcne Chloride ||
Tetrachloroethylene 1 1 6
Trichloroethytene || 1
1.1.1-trfcbloroeth«ne || 11
1.1.2-trichloroethane ||
Ethytbenzene || 4
Toluene | | 130
Total Xylenes || 10
bU-(2-ethylhexyl)-phtheUte || 15
•utylbenzylphthcUte 1 1
1.4-dicMorofaenzene ||
2.4-dl«etbylph«not 1 1
2.4-dlnltrophenoO ||
Nephthalene | | 8
Nitrobenzene ||
4-nitrophenol ||
Phenol | | 71

PRI
INF
Ug/L

530


160

160
170
220
150
UO
HO
230
160
140
170
UO
120
260
130
55
17



65
55

150

PRI
INF

Ug/L

560


UO


220
260
160
150
150
270
170
150
200
160
130
300
UO










PRI
EFF
Ug/L

590


150

160
130
240
130
130
120
230
130
120
UO
120
97
260
110
29
7



57
52

130

PRI
iff
(OUP)
Ug/L

570


150

160
120

130
130
120
240
120
110
140
120
91
260
too
35
10



54
47

130

SEC
EFF
Ug/L

21


5

100
3
5
12
32
19
53
6
5
4
38
5
2
4
5
5



5
5

5

SEC
EFF
(OOP)
Ug/L

5


5

97
2
4
12
31
IB
59
6
4
3
38
2.5
2.5
2.5
5
5



5
5

5

MIXED
LIQUOR
0 MRS
Ug/L

41


5

5
2.5
3
2.5
3
2.5
10
2.5
2.5
2.5
2.5
2.5
2
2.5

5



5
5

5

| NIXED
LIQUOR
48 MRS
Ug/l

53


5

14
2.5
2.5
2.5
2.5
2.5
160
2.5
2.5
2.5
2.5
2.5
2
2.5
5
5



5
5

5

SEC
IMS
Ug/L

62


5

5
2.5
2.5
21
22
10

9
3
2.5
2.5
3
5
2.5
5
5



5
5

5

PRI
IMS
Ug/L

46


5

a
3
14
5
2.5
5

5
4
6
5
5
12
7
5
5



5
5

5

PRI
AIR
Ug/L

0.20


0.005

0.02
0.20
0.40
0.20
0.10
0.10
0.30
0.20
0.20
0.20
0.09
0.10
0.40
0.1










IAERTN ||
AIR ||
II
ug/i ||

6.09 ||
II
II
0.005 ||
II
0.20 ||
2.40 ||
2.30 ||
2.10 ||
1.30 ||
1.60 ||
2.60 ||
2.90 ||
2.10 ||
2.70 ||
1.10 ||
1.30 ||
1.30 ||
0.80 ||
II
II
II
II
II
II
II
II
II


-------
MASSES IN GRAMS OF RCRA ORGAN ICS IN  UASTEUATER,  SLUDGE  AND  AIR
           STREAMS - UNACCLIMATED SYSTEM EVENT  5
UNACCLIMATED SYSTEM |
I

NAME
Acetone |
Cyclohexanone |
Furfural |
2-butenone |
4-ncthyl-2-pentanane |
Tetrahydrofuran |
Carbon Tetrachloride |
Chlorobenzene |
Chloroform |
1,2-dichloroethane |
1,2-dichloropropane |
Methylene Chloride |
Tetraehloroethylene |
Triehloroethylene |
1,1,1-triehloroethane |
1,1,2-trichloroethane |
Ethylbenztne |
Toluene
Total Xylenea
bis-(2-ethylhexyl)-phthalate
Butylbenzylphthalate
1,4-dichlorobenzene
2,4-dimethylphenol
2,4-dinitrophenol |
Naphthalene |
Nitrobenzene |
4-nitrophenol |
Phenol |
| RUU PRI
| INF
1
1
!»•»»>«»»»>«•
93.7 118.


12.3 35.

| 3.8 35.
0.4 37.
13.6 49.
| 1.3 33.
1.1 31.
| 0.0 31.
I 51.
| 1.3 35.
| 0.2 31.
| 2.5 37.
| 0.0 31.
| 0.9 26.
29.0 58.
2.2 29.
3.3 12.
0.0 3.



1.8 14.
0.0 12.
1
| 15.8 33.




3


7

7
9
1
5
2
2
3
7
2
9
2
8
0
0
3
8



5
3

5
PRI
INF

COUP)
125.0


31.2


49.1
58.0
35.7
33.5
33.5
60.3
37.9
33.5
44.6
35.7
29.0
67.0
31.2









PRI
EFF


149.7


38.1

40.6
33.0
60.9
33.0
33.0
30.4
58.4
33.0
30.4
35.5
30.4
24.6
66.0
27.9
7.4
1.8



14.5
13.2

33.0
PRI
EFF

COUP)
144.6


38.1

40.6
30.4

33.0
33.0
30.4
60.9
30.4
27.9
35.5
30.4
23.1
66.0
25.4
8.9
2.5



13.7
11.9

33.0
PRI
AIR


8.2


0.2

0.8
8.2
16.4
8.2
4.1
4.1
12.3
8.2
8.2
8.2
3.7
4.1
16.4
4.1









PRI
UAS


0.2


0.0

0.0
0.0
0.1
0.0
0.0
0.0

0.0
0.0
0.0
0.0
0.0
0.1
0.0
0.0
0.0



0.0
0.0

0.0
AERTN
AIR


1.5


0.1

3.4
40.9
39.2
35.8
22.2
27.3
44.3
49.4
35.8
46.0
18.8
22.2
22.2
13.6









SEC
EFF


8.0


1.9

38.2
1.1
1.9
4.6
12.2
7.2
20.2
2.3
1.9
1.5
14.5
1.9
0.8
1.5
1.9
1.9



1.9
1.9

1.9
SEC
EFF

(DUP)
1.9


1.9

37.0
0.8
1.5
4.6
11.8
6.9
22.5
2.3
1.5
1.1
14.5
1.0
1.0
1.0
1.9
1.9



1.9
1.9

1.9
•**•••*«!
SEC
UAS


0.5


0.0

0.0
0.0
0.0
0.2
0.2
0.1 |
I
0.1 |
0.0 |
0.0 |
0.0 ||
0.0 ||
0.0 |
0.0 |
0.0 |
0.0 |
II
II
II
0.0 ||
0.0 ||
II
0.0 II
                    45

-------
                                        REMOVAL AND PARTITIONING OF RC8A ORGANICS DURING
                                           TREATMENT  - UttACCLIMATED SYSTEM EVENT 5
     UNACCLIMATED SYSTEM
             NAME
                                                           X  IN
                                                                      X  IN
Acatont
Cyclohe
Furfural
2-butanone
4-n»thyl-2-ptnta
Tetrahydrofuran
Carbon Tctrachloride
Chlorobenzene
Chlorofom
1,2-d-phthalat»
autylbenzylphthalate
1,4-dfchlorobenzanc
2,4-dfa»thylphenol
2,4-dtnitrophenol
Naphthalene
Nitrobwutna
4-nitrophtnol
Phenol
                                   PRIMARY
                                   REMOVAL
                                    -21
-U
  3
 -2
           TOTAL
           REMOVAL
         PRIMARY     AERATION
          AIR         AIR
                                                                                  X  IN
TOTAL
 AIR
ADSORBED   BIODECRADED| |
           +CHEM. THAN | |
                                                  96
87
85

94
                                                                                                             92
                                                                         94
•14
27
37
5
-2
6
-7
14
10
14
9
15
-6
11
34
43
-5
98
97
87
63
78
62
94
95
97
57
95
99
96
85
50
1
17
22
16
8
9
26
16
17
15
8
8
14
8


5
84
52
70
44
57
93
97
74
87
39
44
19
25


6
101
74
86
52
66
119
113
91
102
47
52
33
33


0
0
0
1
1
0

0
0
0
0
0
0
0
0
0
-11
-3
23
0
10
12

-19
4
•5
10
43
66
63
85
50
                           87
                           85

                           94
                                                         46

-------
APPENDIX 2.  CERCLA STUDY PERIOD
               47

-------
CONCENTRATIONS OF CERCLA ORGANICS  IN WASTEWATER AND
---- SLUDGE SAMPLES - ACCLIMATED SYSTEM DATA SET 1


Compounds .
~

IDICHLOROBENZENE, PROBABLY 1,2
IDICHLOROBENZEME, PROBABLY 1,3
IDICHLOROBENZENE, PROBABLY 1,4
(1,2,4-TRICHLOROBENZENE
| NITROBENZENE
(1,3-OINITROBENZENE
(2,6-DINITROTOLUENE
IP-CRESOL
|4-CHOLOROANILINE
| HEXACHLOROETHANE
| HEXACHLOROBUTAO 1 ENE
(DIMETHYL PHTHALATE
IDIETHYL PHTHALATE
IDIBUTYL PHTHALATE
| BUTYL BENZYL PHTHALATE
|BIS(2-ETHYLHEXYL)PHTHALATE
[NAPHTHALENE
ILINOANE
IOIELORIN
CONCENTRATION
RUW




UG/L
10
11
10

3
2
0
71
7
0
19
5
18
37
41

29
20
66
.2
.5
.0

.9
.8
.0
.5
.9
.0
.8
.9
.9
.6
.0

.3
.5
.7
PR I
INF

UG/L
451.7
450.6
426.3

483.7
272.2
446.9
600.1
337.5
378.1
432.6
500.6
510.3
436.7
436.2

563.2
457.1
636.0
PR I
INF
(DUP)
UG/L
462.5
466.7
451.3

508.3
283.6
451.8
632.4
359.8
434.2
445.6
515.2
525.5
481.6
440.9

635.2
521.3
1068.3
PRt
EFF


UG/L
325
331
332

374
21
266
621
331
181
147
455
451
208
157

446
306
280
.2
.3
.9

.2
.5
.0
.9
.4
.0
.9
.1
.4
.0
.4

.7
.3
.6
OF TOXICS
SEC
EFF

UG/L
24.8
49.7
7.9

31.9
3.0
132.0
244.9
0.0
0.0
7.6
7.1
7.3
5.8
3.9

7.1
307.9
60.2
SEC
EFF
(DUP)
UG/L
21.1
47.7
3.5

28.8
2.0
125.0
567.2
0.0
3.0
5.9
0.9
1.1
6.1
2.7

1.2
307.1
69.0
SEC
WAS

UG/L
147
296
40

46
325
206
28
99
0
821
0
83
255
191

61
2784
12178
SEC
WAS

-------
MASSES OF CERCLA ORGANICS IN WASTEWATER AND SLUDGE
      STREAMS - ACCLIMATED SYSTEM DATA SET 1
1
1
1
j Compounds
i
i
i
i
IDICHLOROBENZENE, PROBABLY 1,2
IDICHLOROBENZENE, PROBABLY 1,3
IDICHLOROBENZENE, PROBABLY 1,4
| 1 ,2,4-TRICHLOROBENZENE
(NITROBENZENE
|1,3-DINITROBENZENE
|2,6-DINITROTOLUENE
IP-CRESOL
(4-CHOLOROANILINE
IHEXACHLOROETHANE
IHEXACHLOROBUTADIENE
(DIMETHYL PHTHALATE
(DIETHYL PHTHALATE
|D I BUTYL PHTHALATE
| BUTYL BENZYL PHTHALATE
|BIS(2-ETHYLHEXYL)PHTHALATE
(NAPHTHALENE
ILINDANE
(DIELDRIN
PR I
INF
CMS

|172.3
(171.9
(162.7
I
(184.5
(103.8
(170.5
(228.9
(128.8
(144.3
(165.1
(191.0
(194.7
(166.6
(166.4
I
(214.9
(174.4
(242.6
PR I
INF
(DUP)
CMS

176
178
172

193
108
172
241
137
165
170
196
200
183
168

242
198
407

.5
.1
.2

.9
.2
.4
.3
.3
.7
.0
.6
.5
.7
.2

.4
.9
.6
PR I
EFF
CMS

124.1
126.4
127.0

142.8
8.2
101.5
237.3
126.4
69.1
56.4
173.6
172.2
79.4
60.1

170.4
116.8
107.1
MASS OF TOXICS
SEC SEC SEC
EFF EFF WAS
(DUP)
CMS CMS CMS

9.4
19.0
3.0

12.2
1.1
50.3
93.4
0.0
0.0
2.9
2.7
2.8
2.2
1.5

2.7
117.5
23.0

8.0
18.2
1.4

11.0
0.8
47.7
216.4
0.0
1.1
2.3
0.3
0.4
2.3
1.0

0.5
117.2
26.3

0.6
1.2
0.2

0.2
1.3
0.8
0.1
0.4
0.0
3.4
0.0
0.3
1.0
0.8

0.3
11.4
49.8
SEC
WAS
(DUP)
CMS

0
1
0

0
1
0
0
0
0
3
0
0
1
0

0
10
123

.6
.1
.1

.2
.6
.0
.1
.4
.0
.2
.0
.3
.0
.9

.2
.8
.4
PR I
WAS
CMS

16.
15.
13.

0.
1.
0.
2.
1.
0.
40.
0.
1.
29.
34.

18.
23.
0.

0
2
1

2
1
0
6
6
0
6
9
7
2
2

7
1
0
                           49

-------
REMOVAL AND PARTITIONING OF CERCLA ORGANICS DURING
    ""-TREATMENT - ACCLIMATED SYSTEM DATA SET 1
1
1
1
| Compounds
1
1
1
1
IDICHLOROBENZENE, PROBABLY 1,2
IDICHLOROBENZENE, PROBABLY 1,3
IDICHLOROBENZENE, PROBABLY 1,4
| 1 , 2 , 4 • TR 1 CHLOROBENZENE
(NITROBENZENE
|1,3-D [NITROBENZENE
(2,6-DINITROTOLUENE
IP-CRESOL
(4-CHOLOROANILINE
IHEXACHLOROETHANE
IHEXACHLOROBUTADIENE
| DIMETHYL PHTHALATE
IDIETHYL PHTHALATE
|D I BUTYL PHTHALATE
(BUTYL BENZYL PHTHALATE
|BIS(2-ETHYLHEXYL)PHTHALATE
(NAPHTHALENE
ILINDANE
IDIELDRIN
I


x

PRIMARY
REMOVAL


28.9
27.8
24.1

24.6
92.2
40.8
-0.9
4.9
55.4
66.3
10.4
12.8
54.7
64.1

25.5
37.4
67.1
I


X

TOTAL
REMOVAL


95.0
89.4
98.7

93.9
99.1
71.4
34.1
100.0
99.6
98.5
99.2
99.2
98.7
99.2

99.3
37.1
92.4



X

ADSORBED



9.5
9.3
7.9

*
*
*
1.1
1.5
*
*
0.5
1.0
*
*

8.3
18.3
26.6

II
II
X II
II
BIO+STRIP||
+CHE.TRAN||
II
II
85.5 ||
80.0 ||
90.8 ||
II
* II
* II
* II
33.0 ||
98.5 ||
* II
* II
98.8 | |
98.2 ||
* II
* II
II
91.0 ||
18.8 ||
65.8 ||
II
Partitioning not calculated because of inconsistent data
                            50

-------
CONCENTRATIONS OF CERCLA ORGANICS IN WASTEWATER AND
   SLUDGE SAMPLES -  ACCLIMATED SYSTEM DATA SET 2

Compounds

_

IDICHLOROBENZENE, PROBABLY 1,2
IDICHLOROBENZENE, PROBABLY 1,3
IDICHLOROBEMZENE, PROBABLY 1,4
| 1 ,2,4-TRICHLOROBENZENE
(NITROBENZENE
|1,3-OINITROBENZENE
|2,6-DINITROTOLUENE
IP-CRESOL
(4-CHOLORQANIL1NE
IHEXACHLOROETHANE
| HEXACHLOROBUTAD I ENE
(DIMETHYL PHTHALATE
IDIETHYL PHTHALATE
IDIBUTYL PHTHALATE
| BUTYL BENZYL PHTHALATE
| BI SC2-ETHYLHEXYL )PHTHALATE
(NAPHTHALENE
(LINDANE
CONCENTRATION
RUU
PR I

INF


UG/L
1.
6.
7.

9.

0.
49.
13.
14.
0.
5.
13.
15.
26.
706.
11.
0.
(DIELDRIN |
I

6
0
7

8

0
9
5
9
0
5
9
5
0
4
0
0




UG/L

291.
433.

410.

368.
610.
491.
372.
401.
474.
504.
399.
405.
944.
493.
472.



8
9

9

1
8
7
0
2
8
7
2
0
5
8
9


PR I
INF
(DUP)
UG/L
416.3
334.0
430.9

517.1

483.8

519.5
347.4
415.1
447.4
478.5
413.1
439.7
786.0
472.9
576.7


OF TOXICS
PR I
SEC
EFF


UG/L
314.
288.
372.

516.

328.
592.
311.
207.
261.
428.
480.
234.
199.
355.
420.
448.


7
5
2

4

4
5
5
6
0
4
4
4
1
6
4
5


EFF


UG/L
70
49
66

51

68
0
0
16
11
15
16
9
6
187
13
.0
.6
.3

.6

.6
.0
.0
.8
.2
.3
.2
.2
.1
.9
.4
492.6




SEC
WAS

UG/L
102
215
36

155

0
126
0
0
1133
0
18
79
0
3184
24
3007


PR I
WAS

UG/L
12475
0
7679

2655

0
984
2145
0
36258
397
760
20701
24400
39206
18048
16770


                             51

-------
MASSES OF CERCLA ORGANICS IN WASTEWATER AND SLUDGE
      STREAMS - ACCLIMATED SYSTEM DATA SET 2
1 1
1 1
| Compounds | PR I
1 • 1 INF
1 - 1
1 1 »S
1
1
IDICHLOROBENZENE, PROBABLY 1,2
IDICHLOROBENZENE, PROBABLY 1,3
IDICHLOROBENZENE. PROBABLY 1,4
(1,2,4-TRICHLOROBENZENE
(NITROBENZENE
|1,3-OINITROBENZENE
|2,6-DINITROTOLUENE
IP-CRESOL
|4-CHOLOROANiLiNE
IHEXACHLOROETHANE
| HEXACHLOROBUTAO I ENE
IDINETHYL PHTHALATE
IOIETHYL PHTHALATE
|D 1 BUTYL PHTHALATE
| BUTYL BENZYL PHTHALATE
| B I S<2-ETHYLHEXYL )PHTHALATE
(NAPHTHALENE
ILINDAHE
IDIELDRIN
1


55
82

78

70
116
93
71
76
90
96
76
77
180
94
90



.7
.8

.4

.2
.5
.8
.0
.5
.6
.3
.1
.3
.2
.2
.2

MASS OF TOXICS
PR I PR I SEC
INF EFF EFF
(OUP)
CMS CMS CMS

79
63
82

98

92

99
66
79
85
91
78
83
149
90
110


.4
.7
.2

.6

.3

.1
.3
.2
.3
.3
.8
.9
.9
.2
.0


60.
55.
71.

98.

62.
113.
59.
39.
49.
81.
91.
44.
38.
67.

0
0
0

5

6
0
4
6
a
7
6
7
0
8
80.2
85.

6


13
9
12

9

13
0
0
3
2
2
3
1
1
35
2
94


.3
.5
.6

.8

.1
.0
.0
.2
.1
.9
.1
.8
.2
.8
.6
.0

SEC
UAS
CMS

0.
0.
0.

0.

0.
0.
0.
0.
2.
0.
0.
0.
0.


2
4
1

3

0
3
0
0
3
0
0
2
0
6.5
0.0
6.

1

PR I
WAS
CMS

14.4
0.0
8.9

3.1

0.0
1.1
2.5
0.0
42.0
0.5
0.9
24.0
28.3
45.4
20.9
19.4

                               52

-------
REMOVAL AND PARTITIONING  OF  CERCLA  ORGANICS  DURING
     TREATMENT -  ACCLIMATED  SYSTEM  DATA  SET  2


Compounds
_

IDICHLOROBENZENE, PROBABLY 1,2
JDICHIOROBENZENE, PROBABLY 1,3
IDICHLOROBENZENE, PROBABLY 1,4
1 1 ,2,4-TRICHLOROBENZENE
(NITROBENZENE
|1,3-DINITROBENZENE
|2,6-DINITROTOLUENE
IP-CRESOL
(4-CHOLOROANILINE
IHEXACHLOROETHANE
| HEXACHLOROBUTAD I ENE
(DIMETHYL PHTHALATE
IDIETHYL PHTHALATE
IDIBUTYL PHTHALATE
(BUTYL BENZYL PHTHALATE
|BIS(2-ETHYLHEXYL)PHTHALATE
(NAPHTHALENE
(LINDANE
(DIELDRIN
I

X

PRIMARY
REMOVAL
24.4
7.8
13.9

-11.3

22.9
3.0
38.4
42.3
36.1
7.1
2.3
42.3
52.9
58.9
13.0
14.5


X

TOTAL
REMOVAL
83.2
84.1
84.7

88.9

83.9
100.0
100.0
95.3
97.2
96.7
96.7
97.7
98.5
78.3
97.2
6.1


X

ADSORBED

18.5
0.7
10.9

3.8

*
*
*
*
56.9
0.5
1.0
31.1
35.1
*
22.7
25.5

I
X

BICHSTRIP |
i-CHE.TRANl
64.7
83.4
73.8
II
85.1 ||

*
*
*
*
40.3
96.2
95.7
66.6
63.5
*
74.5
-19.4

Partitioning not calculated because of inconsistent data
                             53

-------
CONCENTRATIONS OF CERCLA ORGANICS IN WASTEWATER AND
   StUOGE SAMPLES - ACCLIMATED SYSTEM DATA SET  3
1
1
1
| Compounds
1
1
1
1
1
JDICHLOROBENZENE, PROBABLY 1,2
IOICHLOROBENZENE, PROBABLY 1,3
IOICHLOROBENZENE, PROBABLY 1.4
1 1 ,2,4-TRICHLOROBENZENE
(NITROBENZENE
| 1,3-D (NITROBENZENE
|2,6-DINITROTOLUENE
IP-CRESOL
(4-CHOLOROANILINE
IHEXACHLOROETHANE
| HEXACHLOROBUTADIENE
| DIMETHYL PHTHALATE
IDIETHYL PHTHALATE
IDIBUTYL PHTHALATE
| BUTYL BENZYL PHTHALATE
|BIS(2-ETHYLHEXYL)PHTHALATE
(NAPHTHALENE
ILINDANE
IDIELDRIN
I
CONCENTRATION OF
RUU




UG/L

2.
8.
2.
121.
0.

0.
65.
Q.
0.
7.
11.
34.
44.
33.

15.
0.

5
2
9
7
0

0
9
0
0
6
4
6
0
7

1
0
0.0
PR I
INF




UG/L

410.
315.
416.
583.
621.

458.
714.
787.
353.
394.
444.
479.
404.
378.


5
4
5
3
2

3
5
5
4
8
3
1
7
8

475.5
384.
9
338.4
PR!
EFF

SEC


UG/L

261.
222.
273.
330.
539.

323.
887.
208.
143.
174.
383.
412.
211.
176.

358.
297.
137.

2
0
0
0
7

0
3
8
1
0
0
0
1
7

1
3
8
EFF



UG/L

24.
13.
59.
80.
52.

138.
196.
0.
17.
8.
12.
15.
14.
6.


4
0
9
4
8

7
9
0
2
9
3
6
8
6

10.8
320.8
68.3
TOXICS
SEC
WAS

UG/L

145
222
34
1662
177

0
218
0
0
1138
10
0
220
155

39
3770
13031

SEC
WAS
(OUP)
UG/L

159
140
30
1906
86

0
118
0
282
1450
0
64
520
546

0
2928
22626

PR I
WAS

UG/L

6259
4870
5891
13372
0

0
845
0
409
18362
451
536
17740
21064

0
10980
26555
                             54

-------
MASSES OF CERCLA ORGANICS IN WASTEWATER AND SLUDGE
      STREAMS - ACCLIMATED SYSTEM DATA SET 3

Compounds



DICHLOROBENZENE, PROBABLY 1,2
D1CHLOR08EMZEME, PROBABLY 1,3
DICHLOROBENZENE, PROBABLY 1,4
1,2,4-TRICHLOROBENZENE
NITROBENZENE
1,3-DINITROBENZENE
2,6-DINITROTOLUENE
P-CRESOL
4-CHOLOROANILINE
HEXACHLOROETHANE
HEXACHLOROBUTADIENE
DIMETHYL PHTHALATE
DIETHYL PHTHALATE
D I BUTYL PHTHALATE
BUTYL BENZYL PHTHALATE
BI SC2-ETHYLHEXYL )PHTHALATE
NAPHTHALENE
LINDANE
DIELDRIN
I

PR I
INF

CMS
78.3
60.2
79.5
111.3
118.5

87.4
136.3
150.2
67.4
75.3
84.8
91.4
77.2
72.3

90.7
73.4
64.6

MASS
PR I
EFF

CMS
49.8
42.3
52.1
63.0
103.0

61.6
169.3
39.8
27.3
33.2
73.1
78.6
40.3
33.7

68.3
56.7
26.3

OF TOXICS
SEC
EFF

CMS
4.7
2.5
11.4
15.3
10.1

26.5
37.6
0.0
3.3
1.7
2.3
3.0
2.8
1.3

2.1
61.2
13.0


SEC
WAS

CMS
0.3
0.5
0.1
3.4
0.4

0.0
0.4
0.0
0.0
2.3
0.0
0.0
0.4
0.3

0.1
7.7
26.6


SEC
VMS
(DUP)
CMS
0.3
0.3
0.1
3.9
0.2

0.0
0.2
0.0
0.6
3.0
0.0
0.1
1.1
1.1

0.0
6.0
46.2


PR I
WAS

CMS
7.2
5.6
6.8
15.5
0.0

0.0
1.0
0.0
0.5
21.3
0.5
0.6
20.5
24.4

0.0
12.7
30.8

                             55

-------
 REMOVAL  AND  PARTITIONING  OF  CERCLA  ORGANICS  DURING
      TREATMENT  -  ACCLIMATED  SYSTEM  DATA  SET  3
1
1
| Compounds
1
1
1
1
1
IDICHLOROBENZENE, PROBABLY 1,2
IDICHLOROBENZENE, PROBABLY 1,3
IDICHLOROBENZENE, PROBABLY 1,4
| 1 , 2 , 4 - TR I CNLOROBENZENE
(NITROBENZENE
|1,3-DINITROBENZENE
|2,6-DINITROTOLUENE
IP-CRESOL
(4-CHOLOROANILINE
IHEXACHLOROETHANE
IHEXACHLOROBUTADIENE
(DIMETHYL PHTHALATE
(DIETHYL PHTHALATE
(DIBUTYL PHTHALATE
(BUTYL BENZYL PHTHALATE
|BIS(2-ETHYLHEXYL)PHTHALATE
(NAPHTHALENE
(LINDANE
IDIELDRIN
I
X


PRIMARY
REMOVAL


36.4
29.6
34.5
43.4
13.1

29.5
-24.2
73.5
59.5
55.9
13.8
14.0
47.8
53.3

24.7
22.8
59.3
X


TOTAL
REMOVAL


94.1
95.9
85.6
86.2
91.5

69.7
72.4
100.0
95.1
97.8
97.2
96.7
96.3
98.3

97.7
16.7
79.8
X


ADSORBED



*
*
*
*
0.2

*
1.0
*
*
31.7
0.6
0.8
27.6
34.8

ft
26.6
*
II
* II
II
II
BIO+STRIP||
+CHE.TRANJI
II
II
* II
* II
* II
* II
91.3 ||
II
* II
71.5 ||
*
*
66.0
96.6
96.0
68.7
63.5

* II
-10.0 ||
* II
II
* Partitioning not calculated because of inconsistent data
                               56

-------
CONCENTRATIONS OF CERCLA ORGANICS IN WASTEWATER AND
   SLUDGE SAMPLES - ACCLIMATED SYSTEM DATA SET 4

COMPOUNDS


—
IDICHLOROBENZENE, PROBABLY 1,2
IDICHLOROBENZENE, PROBABLY 1,3
IDICHLOROBENZENE, PROBABLY 1,4
| 1 ,2, 4 -TRICHLOROBENZENE
| NITROBENZENE
|1,3-D1NITROBENZENE
|2.6-DINITROTOi.UENE
IP-CRESOL
|4-CHLOROANILINE
IHEXACHLOROETHANE
| HEXACHLOROBUT AD I ENE
[DIMETHYL PHTHALATE
IDIETHYL PHTHALATE
IDIBUTYL PHTHALATE
| BUTYL BENZYL PHTHALATE
| BI SC2-ETHYLHEXYL )PHTHALATE
| NAPHTHALENE
ILINDANE
IOIELDRIN
I
CONCENTRATION
RUW
PR I

INF


UG/L
4
5
3
110
1
0
0
52
11
0
.0
.5
.5
.6
.1
.0
.0
.8
.8
.0
10.8
4
13
29
31
495
11
13
48
.1
.3
.9
.3
.8
.0
.4
.5


UG/L
368.
377.
387.
527.
379.
195.
386.
558.
334.
264.
383.
451.
468.
421.
399.
668.
432.
425.
311.
7
0
3
7
7
8
9
5
1
5
2
3
1
1
5
4
1
8
6
PR I

EFF


UG/L
318.
273.
337.
406.
416.

245.
477.
92.
252.
282.
459.
394.
285.
239.
313.
372.
355.

0
2
6
1
7

0
5
6
9
7
0
2
6
2
5
9
5

SEC
EFF

UG/L
41.9
89.2
16.3
179.0
35.9
20.3
246.2
60.1
0.0
0.7
66.3
1.6
2.9
59.2
58.1
343.8
15.1

83.4
OF TOXICS
SEC
WAS

UG/L
6
6
2
42
0
0
0
15
0
0
47
7
8
10
0
215
6
71
486
SEC
WAS
(DUP)
UG/L
7
6
5
43
0
0
0
8
0
11
35
7
7
11
0
224
4
66
222
PR I
WAS

UG/L
12960
12656
11771
31291
151
35
126
2181
905
0
36081
544
1105
24226
31380
51994
11673
19154
0
PR I
WAS
(DUP)
UG/L
11145
10730
10173
29845
102
435
0
1764
744
0
31838
408
955
19782
26108
47068
9961
15861
0
                            57

-------
MASSES OF CERCLA ORGANICS IN WASTEWATER AND SLUDGE
      STREAMS - ACCLIMATED SYSTEM DATA SET 4
COMPOUNDS


-
1
IDICHLOROBENZENE, PROBABLY 1,2
IDICHLOROBENZENE, PROBABLY 1,3
IDICHLOROBENZENE, PROBABLY 1,4
(1,2,4-TRICHLOROBENZENE
(NITROBENZENE
|1,3-D1NITROBENZENE
2,6-DlNlTROTOLUENE
IP-CRESOL
I4-CHI.OROANILINE
IHEXACHLOROETHANE
| HEXACHLOROBUTAO I ENE
(DIMETHYL PHTHALATE
IDIETHYL PHTHALATE
IDIBUTYL PHTHALATE
| BUTYL BENZYL PHTHALATE
|BIS(2-ETHYLHEXYL)PHTHALATE
| NAPHTHALENE
LINDANE
IDIELDRIN
I
PR I
INF

CMS
70.3
71.9
73.9
100.7
72.4
37.4
73.8
106.5
63.7
50.5
73.1
86.1
89.3
80.3
76.2
127.5
82.4
81.2
59.4

PR I
EFF

CMS
60.
52.
64.
77.
79.

46.
91.
17.
48.
53.
87.
75.
54.
45.
59.
71.
67.






7
1
4
5
5

7
1
7
2
9
6
2
5
6
8
1
8


SEC
EFF

CMS
8.
17.
3.
34.
6.
3.
47.
11.
0.
0.
12.
0.
0.
11.
11.
65.
2.
0.
15.





0
0
1
2
8
9
0
5
0
1
6
3
5
3
1
6
9
0
9

SEC
WAS

CMS
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.





0
0
0
1
0
0
0
0
0
0
1
0
0
0
0
4
0
1
0

SEC
WAS
(DUP
CMS
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.



)

0
0
0
1
0
0
0
0
0
0
1
0
0
0
0
5
0
1
5

PR I
WAS

CMS
15.0
14.7
13.6
36.2
0.2
0.0
0.1
2.5
1.0
0.0
41.8
0.6
1.3
28.1
36.3
60.2
13.5
22.2
0.0

PR I
WAS
(DUP)
CMS
12.9
12.4
11.8
34.6
0.1
0.5
0.0
2.0
0.9
0.0
36.9
0.5
1.1
22.9
30.2
54.5
11.5
18.4
0.0

                              58

-------
REMOVAL AND PARTITIONING OF CERCLA ORGANICS  DURING
     ^TREATMENT - ACCLIMATED SYSTEM DATA SET  4
       COMPOUNDS
                       I                           I
                       (PRIMARY  TOTAL  ADSORBED BIO*STRIP|
                       (REMOVAL REMOVAL        +CHE.TRAN|
1
1
(DICHLOROBENZENE, PROBABLY 1,2
(DICHLOROBENZENE, PROBABLY 1,3
(DICHLOROBENZENE, PROBABLY i,«
| 1 ,2,4-TRICHLOROBENZENE
(NITROBENZENE
(1,3-DINITROBENZENE
|2,6-DINITROTOLUENE
IP-CRESOL
(4-CHLOROANiLiNE
(HEXACHLOROETHANE
IHEXACHLOROBUTADIENE
(DIMETHYL PHTHALATE
(DIETHYL PHTHALATE
(DIBUTYL PHTHALATE
(BUTYL BENZYL PHTHALATE
|BIS(2-ETHYLHEXYL)PHTHALATE
(NAPHTHALENE
(LINDANE
(DIELDRIN
I


13.8
27.5
12.8
23.1
-9.7

36.7
14.5
72.3
4.4
26.2
-1.7
15.8
32.2
40.1
53.1
13.7
16.5




88.6
76.3
95.8
66.1
90.6
89.6
36.4
89.2
100.0
99.7
82.7
99.6
99.4
85.9
85.5
48.6
96.5

73.2



19.9
18.8
17.2
35.2
0.2
*
*
2.2
*
0.0
*
0.7
1.4
31.7
43.7
45.3
15.2
*
*



68.8
57.5
78.6
30.8
90.4
*
*
87.1
«
99.7
*
99.0
98.0
54.2
41.8
3.2
81.3
*
*

 Partitioning not calculated because  of inconsistent data
                          59

-------
CONCENTRATIONS OF CERCLA ORGANICS IN WASTEWATER AND
   SLUDGE SAMPLES - ACCLIMATED SYSTEM DATA SET 5

Compounds


-
IDICHLOROBEKZENE, PROBABLY 1,2
(DICHLOROBENZENE, PROBABLY 1,3
IDICHLOROBENZENE, PROBABLY 1,4
| 1 , 2 , 4 - TR I CH LOROBENZENE
INITROBENZENE
1 1, 3-D I NITROBENZENE
|2,6-DINITROTOLUENE
IP-CRESOL
|4-CHOLOROANIL1NE
IHEXACHLOROETHANE
| HEXACHLOROBUT AD I ENE
[DIMETHYL PHTHALATE
|D I ETHYL PHTHALATE
IDIBUTYL PHTHALATE
| BUTYL BENZYL PHTHALATE
IBISCZ-ETHYLHEXYDPHTHALATE
(NAPHTHALENE
ILINOANE
IDIELDRIN
I
CONCENTRATION
RUW
PR I
INF
PR I
INF


PR I
EFF


OF TOXICS
SEC
EFF


SEC
WAS
PR I
WAS
(DUP)
UG/L
12.4
15.9
11.9
163.3
0.0
234.2
0.0
33.6
3.9
0.0
40.8
0.0
8.0
24.7
23.9

19. r
12.0
166.6
UG/L
383
386
398
556
385
327
395
505
333
333
413
422
476
441
461

504
451
324
.1
.3
.1
.3
.0
.5
.8
.4
.7
.5
.9
.2
.2
.7
.3

.4
.6
.6
UG/L
351.
355.
350.
470.
409.
311.
398.
493.
305.
310.
341.
412.
433.
493.
365.

447.
397.
260.
7
5
1
7
2
7
5
2
2
1
3
8
2
6
1

7
9
9
UG/L
331.
326.
334.
379.
342.
111.
270.
539.
326.
198.
180.
421.
423.
243.
190.

441.
326.
150.
1
2
1
4
9
2
8
4
8
6
6
2
0
0
2

8
5
4
UG/L
16.
35.
5.
78.
25.
9.
125.
203.
0.
1.
7.
4.
5.
1
7
9
4
1
9
6
3
0
0
3
6
5
5.8
2.9


4.8
328.
7
33.6
UG/L
95
219
22
1490
48
1581
243
31
61
18
804
24
42
195
180

20
2160
9785
UG/L
3721
3370
3154
13487
43
988
15
1156
507
0
14089
311
539
9729
11237

4451
5012
3831
                        60

-------
MASSES OF CERCLA ORGANICS IN WASTEWATER AND SLUDGE
      STREAMS - ACCLIMATED SYSTEM DATA SET 5
Compounds

(DICHLOROBENZENE, PROBABLY 1,2
IDICHLOROBENZENE, PROBABLY 1,3
IDICHLOROBENZENE, PROBABLY 1,4
(1,2.4-TRlCHLOROBENZENE
| NITROBENZENE
| 1 ,3-DINITROBENZENE
(2.6-DINITROTOLUENE
IP-CRESOL
(4-CHOLOROANILINE
IHEXACHLOROETHANE
IHEXACHLOROBUTAOIENE
(DIMETHYL PHTHALATE
IDIETHYL PHTHALATE
IOIBUTYL PHTHALATE
| BUTYL BENZYL PHTHALATE
|BIS(2-ETHYLHEXYL)PHTHALATE
(NAPHTHALENE
ILINDANE
(DIELDRIN
I
I
| PRI
| INF
I
| CMS
.1
1
(146

.2
(H7.4
1151
(212
(146
1 4-57
|124
1151
(192
1127
.9
.2
.9
.0
.8
.3
(127.2
1157
(161
(181
(168
(176
I
(192
1172
|123
.9
.1
.7
.5
.0

.5
.3
.9
PRI
INF

-------
REMOVAL AND PARTITIONING OF CERCLA  ORGANICS DURING
     TREATMENT - ACCLIMATED SYSTEM  DATA SET 5
       Compounds
                       (PRIMARY  TOTAL   ADSORBED BIO+STRJP||
                       |REMOVAL  REMOVAL         +CHE.TRAM||
1
IDICHLOROBENZENE, PROBABLY 1,2
IDICHLOROBENZENE, PROBABLY 1,3
IDICHLOROBENZENE. PROBABLY 1,4
| 1 , 2 , 4 - TR I CHLOROBENZENE
(NITROBENZENE
|1,3-DINITROBENZENE
|2,6-DINITROTOLUENE
IP-CRESOL
(4-CHOLOROANILINE
IHEXACHLOROETHANE
IHEXACHLOROBUTADIENE
(DIMETHYL PHTHALATE
IDIETHYL PHTHALATE
IDIBUTYL PHTHALATE
| BUTYL BENZYL PHTHALATE
|BIS(2-ETHYLHEXYL)PHTHALATE
(NAPHTHALENE
(LINOANE
(DIELDRIN
I
9.
12.
10.
26.
13.
65.
31.
-8.
-2.
38.
52.
-0.
7.
48.
54.

7.
23.
48.
9
0
7
1
6
2
8
0
3
3
2
9
0
1
0

2
1
6
95
90
98
84
93
96
68
59
100
99
98
98
98
98
99

99
22
88
.6
.4
.4
.7
.7
.9
.4
.3
.0
.7
.1
.9
.8
.8
.3

.0
.6
.5
6.
6.
5.
19.
0.
*
*
1.
1.
*
4
0.
0.
•
*

5.
12.
43.
4
1
2
1
2


5
2


5
8



7
6
8
89
84
93
65
93


57
98


98
98



93
10
44
.2
.2
.2
.7
.5
*
*
.8
.8
*
*
.4
.0
*
it

.3
.0
.8
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
 Partitioning not  calculated because of inconsistent data
                           62

-------
CONCENTRATIONS OF CERCLA ORGANICS IN WASTEWATER AND
   SLUDGE SAMPLES - ACCLIMATED SYSTEM DATA SET 6
| | CONCENTRATION

COMPOUNDS


II

|| RWU
II
II


| | UG/L
II
DICHLOROBEHZENE, PROBABLY 1,2
DICHLOROBENZENE, PROBABLY 1,3
OICHLOROBENZENE, PROBABLY 1,4
1 , 2 , 4 - TR I CHLOROBENZENE
NITROBENZENE
1,3-OINITROBENZENE
(2.6-DINITROTOLUENE
P-CRESOL
4-CHLOROANILINE
IHEXACHLOROETHANE
HEXACHLOROBUTADIENE
[DIMETHYL PHTHALATE
IDIETHYL PHTHALATE
D I BUTYL PHTHALATE
BUTYL BENZYL PHTHALATE
BIS(2-ETHYLHEXYL)PHTHALATE
NAPHTHALENE
LINDANE
D1ELDRIN
II
II 1-
II 3.
II 7.
||137.
II 0-
II o.
II o.
II 46.
II *•
II 0-
II 5.
II 13-
II 21.
II 38.
II 35.
II
|| 13.
II 6.
II o.
8
8
9
5
0
0
0
5
9
0
7
5
7
7
8

1
6
0

PR1
INF

UG/L
377.5
385.6
380.7
573.0
417.7
258.3
397.1
506.1
314.7
344.4
412.3
431.3
437.9
409.7
393.5

448.0
439.1
1272.5

PR I
INF
(DUP)
UG/L
344.9
341.2
351.3
531.2
396.2
268.6
393.3
472.1
302.5
324.1
363.1
420.5
425.0
394.1
349.5

389.8
409.9
1209.2

PR I
EFF

UG/L
307.3
313.7
313.6
410.2
358.9
62.8
258.9
542.1
312.6
206.5
215.1
444.6
440.6
257.2
206.7

391.5
347.8
243.0
OF TOXICS


SEC
EFF



UG/L
21.
41.
8.
81.
23.
5.
128.
238.
134.
2.
7.
8.
10.
11.
8.

5.
276.
70.
8
8
4
3
8
6
7
7
7
9
8
3
0
3
6

3
1
4

SEC
EFF
(DUP)
UG/L
17.1
36.7
4.5
75.8
20.4
6.6
125.4

93.6
3.5
5.0
1.3
2.8
7.8
6.5

1.2
261.8
63.4

SEC
WAS

UG/L
639
592
201
2927
151
881
492
100
242
288
2428
125
169
786
707

129
4417
29762

SEC
WAS
(DUP)
UG/L
264
492
91
2800
84
1162
445
20
162
0
2326
39
95
649
548

68
4279
13776

PR I
WAS

UG/L
I
I
19838 |
18109 |
16626
63363
120
0
86
1084
1289 |
28 |
60516 1
444 |
1070
35944 |
38555 |

17363 |
25606
0
                       63

-------
MASSES OF CERCLA ORGANICS IN WASTEWATER AND SLUDGE
      STREAMS - ACCLIMATED SYSTEM DATA SET 6
1
1
| COMPOUNDS
1
1
1
1
1
IDICHLOROBENZENE, PROBABLY 1,2
IDICHLOROBENZENE, PROBABLY 1,3
IDICHLOROBENZENE, PROBABLY 1,4
(1,2,4-TRICHLOROBENZENE
(NITROBENZENE
|1,3-DINITROBENZENE
|2,6-D1NITROTOLUENE
IP-CRESOL
|4-CHLOROANIL1NE
IHEXACHLOROETHANE
| HEXACHLOftOBUTAD I ENE
IDIMETHYL PHTHALATE
|D I ETHYL PHTHALATE
IOIBUTYL PHTHALATE
| BUTYL BENZYL PHTHALATE
|BIS(2-ETHYLHEXYL)PHTHALATE
(NAPHTHALENE
ILINDANE
IDIELDRIN
II
II
II
II
II
II
(I
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
PR
IN
Q

72
73
72
109
79
49
75
96
60
65
78
82
83
78
75

85
83
242
I
f
MS

.0
.6
.6
.3
.7
.3
.8
.5
.0
.7
.7
.3
.5
.2
.1

.5
.8
.7
PR I
INF
(DUP)
CMS

65.8
65.1
67.0
101.3
75.6
51.2
75.0
90.1
57.7
61.8
69.3
80.2
81.1
75.2
66.7

74.4
78.2
230.7
HASS OF
PR I
EFF
CMS

58.6
59.8
59.8
78.3
68.5
12.0
49.4
103.4
59.6
39.4
41.0
84.8
84.1
49.1
39.4

74.7
66.3
46.4
TOXIC
SEC
EFF
CMS

4.2
8.0
1.6
15.5
4.5
1.1
24.5
45.5
25.7
0.6
1.5
1.6
1.9
2.2
1.6

1.0
52.7
13.4
S
SEC
EFF
(DUP)
CMS

3.3
7.0
0.9
14.5
3.9
1.3
23.9

17.8
0.7
1.0
0.2
0.5
1.5
1.2

0.2
49.9
12.1
SEC
WAS
CMS

1.3
1.2
0.4
6.0
0.3
1.8
1.0
0.2
0.5
0.6
5.0
0.3
0.3
1.6
1.4

0.3
9.0
60.8
SEC
WAS
(DUP
GM

0.
1.
0.
5.
0.
2.
0.
0.
0.
0.
4.
0.
0.
1.
1.

0.
8.
28.
)
S

5
0
2
7
2
4
9
0
3
0
8
1
2
3
1

1
7
2
II
II
PR! ||
WAS ||
I
QMS ||
II
II
23.0 ||
21.0 ||
19.3 ||
73.4
0.1
0.0
0.1
1.3
1.5
0.0
70.1
0.5
1.2
41.6
44.6

20.1
29.7 |
0.0 |
                         64

-------
 REMOVAL AND PARTITIONING OF CERCLA ORGANICS DURING
      TREATMENT -  ACCLIMATED SYSTEM DATA SET 6
1
1
| COMPOUNDS
1
1
1
1
1
IDICHLOROBENZENE, PROBABLY 1,2
IDICHLOROBENZENE, PROBABLY 1,3
IDICHLOROBENZENE, PROBABLY 1,4
| 1 , 2 , 4 - TR I CHLOROBENZENE
| NITROBENZENE
|1,3-DINITROBENZENE
|2,6-DINITROTOLUENE
IP-CRESOL
(4-CHLOROANILINE
IHEXACHLOROETHANE
| HEXACHLOROBUT AD I ENE
(DIMETHYL PHTHALATE
|DI ETHYL PHTHALATE
IOIBUTYL PHTHALATE
| BUTYL BENZYL PHTHALATE
|BIS(2-ETHYLHEXYL)PHTHALATE
(NAPHTHALENE
ILINDANE
IDIELDRIN
I
I
I *


(PRIMARY
(REMOVAL
I

| U.9
13.7
U.3
25.7
11.8
76.2
34.5
-10.8
-1.3
38.2
44. 5
-4.4
-2.1
36.0
44.4

6.5
18.1
80.4


X


TOTAL
REMOVAL

94.6
89.2
98.2
85.8
94.6
97.7
67.9
75.6
63.0
99.0
98.3
98.9
98.5
97.6
98.0

99.2
36.6
94.6


X


ADSORBED


34.7
31.9
28.0
*
0.5
*
*
1.5
3.2
*
*
0.8
1.8
56.2
64.8

25.4
47.6
*

I
X I
I
I
BIO+STRIP)
+CHE.TRAN)

59.9
57.4
70.2
*
94.1
*
*
74.1
59.8
*
*
98.0
96.7 |
41.4 |
33.2 |
I
73.8 |
-10.9 |
• I
I
* Partitioning not calculated because of inconsistent data
                         65

-------
CONCENTRATIONS OF -CERCLA ORGANICS IN WASTEWATER AND
   SLUDGE SAMPLES - ACCLIMATED SYSTEM DATA SET 7
COMPOUNDS

IOICHLOROBENZENE, PROBABLY 1,2
IOICHLOROBENZENE, PROBABLY 1,3
IDICHLOROBENZENE, PROBABLY 1.4
1 1 ,2,4-TRICHLOROBENZENE
| NITROBENZENE
11.3-OINITROBENZENE
|2,6-DINITROTOLUENE
IP-CRESOL
|4-CHLOROANIL!NE
IHEXACHLOROETHANE
IHEXACHLOROBUTAOIENE
| DIMETHYL PHTHALATE
IDIETHYL PHTHALATE
|DI BUTYL PHTHALATE
| BUTYL BENZYL PHTHALATE
|BIS(2-ETHYLHEXYL)PHTHALATE
(NAPHTHALENE
ILINOANE
(DIELDRIN
II
II
II RUU
II
II
|| UG/L
II
II
II
II 20
II 23
II 205
II
II
II 55
I
I
I 16
I W
I
I 15
II 38
II 22
II
II 26
II
II 389


.7
.6
.4


.8


.7
.7

.4
.9
.0

.6

.2
PR I
INF
UG/L


356.3
340.3
489.8


288.5


298.5
350.0

479.8
443.4
387.3

365.5

604.2
CONCENTRATION OF TOXICS
PR I SEC SEC PR I
EFF EFF WAS WAS
UG/L UG/L UG/L UG/L


344
368
409


261


239
250

517
310
252

391

227


.3
.3
.7


.7


.6
.4

.7
.7
.8

.9

.3


44
10
82


136


18
13

16
17
11

11

137


.7
.9
.5


.5


.7
.1

.0
.5
.1

.3

.0


475
79
2314


6051


701
3119

85
408
275

101

21153


11160
14340
39545


159


224
61744

1225
29614
39012

14294

8045
PR I
WAS
(DUP)
UG/L


16731
17359
40792


0


0
68713

1694
34765
40347

16256

9784











II
II
II

I
I
I
I
II
I
                          66

-------
MASSES OF.CERCLA ORGANICS IN WASTEWATER AND SLUDGE
      STREAMS - ACCLIMATED SYSTEM DATA SET 7
II
1

II wi
COMPOUNDS || INF
II
II GHS
II
II
|D I CHLOROBENZENE, PROBABLY 1,2 ||
IDICHLOROBENZENE, PROBABLY 1,3
|D I CHLOROBENZENE, PROBABLY 1,4
| 1 , 2 , 4 - TR I CHLOROBENZENE
| NITROBENZENE
|1,3-DINITROBENZENE
|2,6-DINITROTOLUENE
IP-CRESOL
K-CHLOROANILINE
IHEXACHLOROETHANE
IHEXACHLOROBUTADIENE
IDINETHYL PHTHALATE
IDIETHYL PHTHALATE
|D I BUTYL PHTHALATE
| BUTYL BENZYL PHTHALATE
| B I S(2-ETHYLHEXYL )PHTHALATE
NAPHTHALENE
ILINDANE
IOIELDRIN
68.0
64.9
93.4


55.0


56.9
66.8

91.5
84.6
73.9

69.7

|115.3
MASS

PR I
EFF

CMS

65.7
70.3
78.2


49.9


45.7
47.8

98.8
59.3
48.2

74.8

43.4
OF TOXICS

SEC
EFF

CMS

8.5
2.1
15.7


26.0


3.6
2.5

3.1
3.3
2.1

2.1

26.1

SEC
WAS

CMS

1.0
0.2
4.7


12.4


1.4
6.4

0.2
0.8
0.6

0.2

43.2

PR I
WAS

CMS

12.9
16.6
45.8


0.2


0.3
71.5

1.4
34.3
45.2

16.6

9.3

PR I
WAS
(DUP)
CMS

19.4
20.1
47.2


0.0


0.0
79.6

2.0
40.3
46.7

18.8

11.3
                          67

-------
 REMOVAL AND PARTITIONING OF CERCLA ORGANICS DURING
      TREATMENT - ACCLIMATED SYSTEM DATA SET 7
1
COMPOUNDS |
1
1
1
1
IDICHLOROBENZENE, PROBABLY 1,2 |
IDICHLOROBENZENE, PROBABLY 1,3 |
IDICHLOROBENZENE, PROBABLY 1,4 |
|1,2.4-TRICHLOROBENZENE |
(NITROBENZENE
|1,3-DINITROBENZENE
|2,6-D1NITROTOLUENE
IP-CRESOL
|4-CHLOROANiLiNE
IHEXACHLOROETHANE
| HEXACHLOROBUTADIENE
IDIHETHYL PHTHALATE
IDIETHYL PHTHALATE
| DI BUTYL PHTHALATE
(BUTYL BENZYL PHTHALATE
|BIS(2-ETHYLHEXYL)PHTHALATE
| NAPHTHALENE
(LINDANE
(DIELDRIN
I
I
I «
i
1
1
(PRIMARY
(REMOVAL

1
1 3.3
| -8.2
| 16.4


9.3


19.7
28.5

-7.9
29.9
34.7

-7.2

62.4
X X

TOTAL ADSORBED
REMOVAL


87.5 *
96.8 *
83.1 *


52.7 22.6


93.7 •
96.2

96.7 2.0
96.1 45.1
97.1 •

96.9 *

77.3 *
I
* 1
1
B I CM-STRIP |
+CHE.TRANJ
1
1
1
" 1
* 1
* 1
1
1
30.0 |
1
1
• 1
* 1
1
94.6 (1
51.0 ||
* II
II
• II
II
• II
I!
* Partitioning not calculated because of inconsistent data
                         68

-------
CONCENTRATIONS OF CERCLA ORGANICS IN WASTEWATER AND
   SLUDGE SAMPLES - ACCLIMATED SYSTEM DATA SET 8
COMPOUNDS

DICHLOROBENZENE, PROBABLY 1,2
IDICHLOROBENZENE, PROBABLY 1,3
DICHLOROBENZENE, PROBABLY 1,4
1.2.4-TRICHLOROBENZENE
NITROBENZENE
1,3-DINITROBENZENE
2,6-DINITROTOLUENE
P-CRESOL
4-CHLOROANILINE
HEXACHLOROETHANE
HEXACHLOROBUTAD I ENE
DIMETHYL PHTHALATE
D I ETHYL PHTHALATE
D I BUTYL PHTHALATE
BUTYL BENZYL PHTHALATE
RWU
UG/L
4
15
9
249
3
0
0
31
7
0
5
4
11
31
26
BIS(2-ETHYLHEXYL)PHTHALATE ||7003
NAPHTHALENE | | 22
LINDANE || 9
OIELDRIN || 21
II
.5
.1
.6
.0
.1
.0
.0
.0
.9
.0
.6
.3
.2
.7
.4
.4
.3
.6
.2

PR I
INF
UG/L
335.
393.
386.
688.
415.
244.
375.
485.
191.
373.
364.
466.
499.
392.
359.
1675.
344.
403.
354.

5
8
7
3
1
7
0
1
5
9
1
6
0
6
8
1
7
5
6

CONCENTRATION
PRI PRI
INF EFF
(DUP)
UG/L
384.
443.
435.
728.
460.
316.

531.
197.

399.
484.
525.
418.
365.
1096.
382.
432.


4
3
4
2
0
0

3
3

2
5
7
8
2
6
7
0


UG/L
313.8
367.7
357.8
527.3
383.0
58.4
276.2
565.0
222.0
219.3
222.0
481.6
533.0
255.2
209.0
955.2
314.8
339.6
207.4

OF TOXICS
SEC SEC
EFF WAS
UG/L
11.2
33.7
5.7
76.7
25.8
8.2
140.9
227.7
116.5
6.2
8.3
7.8
11.4
9.9
5.7
378.5
5.3
12.6
107.0

UG/L
147
381
68
1987
0
1214
0
0
42
0
1813
0
62
594
324
60475
77
148
5471

SEC
WAS
(DUP)
UG/L
94
277
51
2063
0
1387
0
0
40
0
1826
0
0
932
863
46800
74
366
9756

PRI
UAS
UG/L
14040
13713
11974
46986
182
1287
0
1837
493
205
45308
420
1252
31584
34843
81647
11462
18066
15963

                   69

-------
MASSES OF CERCL'A ORGANICS IN WASTEWATER AND SLUDGE
      STREAMS - ACCLIMATED SYSTEM DATA SET 8
1
1
| COMPOUNDS
1
1
1
1
1
IDICHLOROBENZENE, PROBABLY 1,2
IDICHLOROBENZENE, PROBABLY 1,3
IDICHLOROBENZENE, PROBABLY 1,4
| 1,2,4-TRICHLOROBENZENE
(NITROBENZENE
(1,3-DINITROBENZENE
| 2,6-DINITROTOLUENE
IP-CRESOL
(4-CHLOROANILINE
IHEXACHLOROETHANE
| HEXACHLOROBUTAD I ENE
(DIMETHYL PHTHALATE
(DIETHYL PHTHALATE
(DIBUTYL PHTHALATE
| BUTYL BENZYL PHTHALATE
|BIS(2-ETHYLHEXYL)PHTHALATE
(NAPHTHALENE
ILINDANE
IDIELDRIN
I
II
II
II IMF
II
II «
II
II
II 64.
II 75.
II 73.
||131.
II 79.
II ".
II 71.
II 92.
II 36.
II 71.
II 69.
II 89.
II 95.
II 74.
II 68.
| (319.
II 65.
II 77.
II 67.
II
MASS OF
PRI PRI
INF EFF
(DUP)
S CMS CMS

0
1
8
3
2
7
5
5
5
3
5
0
2
9
6
6
8
0
6

73.
84.
83.
138.
87.
60.

101.
37.

76.
92.
100.
79.
69.
209.
73.
82.


3
6
1
9
8
3

4
6

2
4
3
9
7
2
0
4


59
70
68
100
73
11
52
107
42
41
42
91
101
48
39
182
60
64
39

.9
.2
.3
.6
.1
.1
.7
.8
.3
.8
.3
.9
.7
.7
.9
.2
.0
.8
.6
TOXICS
SEC
EFF
CMS

2
6
1
14
4
1
26
43
22
1
1
1
2
1
1
72
1
2
20

.1
.4
.1
.6
.9
.6
.9
.4
.2
.2
.6
.5
.2
.9
.1
.2
.0
.4
.4
SEC
WAS
CMS

0.3
0.8
0.1
4.1
0.0
2.5
0.0
0.0
0.1
0.0
3.7
0.0
0.1
1.2
0.7
123.6
0.2
0.3
11.2
SEC
WAS
(DUP)
CMS

0.2
0.6
0.1
4.2
0.0
2.8
0.0
0.0
0.1
0.0
3.7
0.0
0.0
1.9
1.8
95.7
0.2
0.7
19.9
II
II
PRI ||
WAS ||
II
CMS ||
II
16.3 ||
15.9 ||
13.9 ||
54.4 ||
0.2
1.5
0.0
2.1
0.6
0.2
52.5
0.5
1.4
36.6
40.3
94.5
13.3
20.9
18.5
                       70

-------
REMOVAL AND PARTITIONING OF CERCLA ORGANICS DURING
     TREATMENT -  ACCLIMATED SYSTEM DATA SET 8


COMPOUNDS

"_



[DICHLOROBENZENE, PROBABLY 1.2
IOICHLOROBENZENE, PROBABLY 1,3
IDICHLOROBENZENE, PROBABLY 1,4 |
|1,2,4-TR1CHLOROBENZENE |
(NITROBENZENE
|1,3-D1NITROBENZENE
|2,6-OIN1TROTOLUENE
IP-CRESOL
14-CHLOROANILINE
| HEXACHLOROETHANE
| HEXACHLOROBUTAD I ENE
(DIMETHYL PHTHALATE
IDIETHYL PHTHALATE
(DIBUTYL PHTHALATE
(BUTYL BENZYL PHTHALATE
|BIS(2-ETHYLHEXYL)PHTHALATE
(NAPHTHALENE
ILINDANE
IDIELDRIN
1
1
X
1
1
(PRIMARY
(REMOVAL
1
1
12.8
12.1
| 13.0
| 25.5
12.5
79.2
26.3
-11.2
-U.2
41.3
41.8
-1.3
-4.0
37.1
42.3
31.1
13.5
18.7
41.5


X


TOTAL
REMOVAL


96.9
92.0
98.6
89.2
94.1
97.1
62.4
55.2
40.1
98.4
97.8
98.4
97.8
97.6
98.4
72.7
98.5
97.0
69.8


X


ADSORBED



24.0
20.7
17.8
43.3
0.3
*
*
2.2
1.8
•
*
0.5
1.5
49.3
60.1
77.2
19.4
26.9
50.3

I
« I
I
I
BIO+STRIP)
+CHE.TRAN)
I

72.9
71.2
80.8
45.8
93.9
*
*
53.0
38.3
*
*
97.8
96.2
48.3
38.3
-4.5
79.2
70.1 ||
19.5 ||
II
 Partitioning not calculated  because  of  inconsistent  data
                         71

-------
CONCENTRATIONS OF CERCLA ORGANICS IN WASTEWATER AND
  • -SUJDGE SAMPLES - ACCLIMATED SYSTEM DATA SET 9
1
| COMPOUNDS
|
|
I
i
1
IDICHLOROBENZENE, PROBABLY 1,2
IDICHLOROBENZENE, PROBABLY 1,3
IDICHLOROBENZENE, PROBABLY 1,4
|1,2,4-TRtCHLOROBENZENE
[NITROBENZENE
|1,3-D1NITROBENZENE
|2,6-DINITROTOLUENE
IP-CRESOL
[4-CHLOROANILINE
IHEXACHLOROETHAME
IHEXACHLOROBUTAOIENE
IDIMETHYL PHTHALATE
(DIETHYL PHTHALATE
(DIBUTYL PHTHALATE
| BUTYL BENZYL PHTHALATE
|BIS(2-ETHYLHEXYL)PHTHALATE
(NAPHTHALENE
ILINDANE
CONCENTRATION
RWU
RWU
PR I

INF


UG/L
28
34
27
945
39


26

15
93
8
15
91
97

46
31
IDIELORIN |471
I I
.6
.2
.5
.6
.9


.4

.6
.0
.4
.1
.3
.9

.9
.7
.0

UG/L
28.8
30.0
29.3
929.4
25.0


46.2

15.3
92.3
9.9
16.5
89.2
93.8

52.0
32.4
203.08


UG/L
310.
428.
399.
833.
508.


498.

380.
426.
1604.
550.
433.
423.

396.
476.
387.
5
6
7
7
3


2

7
8
8
7
5
6

1
2
3
PR I
INF
(OUP)
UG/L
326.3
339.7
389.2
690.3
486.2


484.4

333.6
412.9
1506.9
538.3
399.8
402.1

383.9
430.8

OF TOXICS
PR I
EFF

UG/L
300.6
305.5
374.1
525.5
541.1


548.1

257.9
291.3
1574.5
533.5
315.2
291.6

365.5
378.6
234.72
SEC
EFF

UG/L
15.4
36.5
11.8
90.0
25.3


196.9

18.6
13.1
53.9
19.5
16.4
13.5

11.5
18.1
57.26
SEC
WAS

UG/L
436
668
339
3730
50


71

0
3806
44
140
997
1144

274
535
4654
PR I
WAS

UG/L
10470
10854
9661
35593
161


1721

0
32523
537
1115
24084
27174

9225
15499
37408
PR I
WAS
(DUP)
UG/L
12350
12885
11437
42202
236


1874

204
39463
649
1393
28646
32748

10929
17491

                      72

-------
MASSES'OF CERCLA ORGANICS IN WASTEWATER AND SLUDGE
      STREAMS - ACCLIMATED SYSTEM DATA SET 9
COMPOUNDS

DICHLOROBENZENE, PROBABLY 1,2
DICHLOR08ENZENE, PROBABLY 1,3
DICHLOROBENZENE, PROBABLY 1,4
1,2,4-TRICHLOROBENZENE
NITROBENZENE
1,3-DINITROBENZENE
2,6-DINITROTOLUENE
P-CRESOL
4-CHLOROANILINE
HEXACHLOROETHANE
HEXACHLOROBUTADIENE
PR I
INF
PR I
INF
(DUP)
CMS
59.
81.
76.
159.
97.


95.

72.
81.
DIMETHYL PHTHALATE |306.
01 ETHYL PHTHALATE (105.
D I BUTYL PHTHALATE | 82.
BUTYL BENZYL PHTHALATE | 80.
BIS(2-ETHYLHEXYL)PHTHALATE |
NAPHTHALENE | 75.
LINDANE | 90.
DIELDRIN | 73.
2
8
3
0
0


0

6
4
1
1
7
8

6
8
9
CMS
62
64
74
131
92


92

63
78
287
102
76
76

73
82

.2
.8
.3
.7
.8


.4

.6
.8
.5
.7
.3
.7

.2
.2

MASS OF TOXICS
PR I SEC SEC
EFF EFF WAS
CMS
57.3
58.3
71.4
100.2
103.2


104.6

49.2
55.6
300.4
101.8
60.1
55.6

69.7
72.2
44.8
CMS
2.9
7.0
2.3
17.2
4.8


37.6

3.5
2.5
10.3
3.7
3.1
2.6

2.2
3.5
10.9
CMS
0.9
1.4
0.7
7.6
0.1


0.1

0.0
7.8
0.1
0.3
2.0
2.3

0.6
1.1
9.5
PR I
WAS
CMS
12.
12.
11.
41.
0.


2.

0.
37.
0.
1.
27.
31.

10.
17.
43.
1
6
2
2
2


0

0
7
6
3
9
5

7
9
3
PR I
WAS
(DUP)
CMS
14
14
13
48
0


2

0
45
0
1
33
37

12
20

.3
.9
.2
.9
.3


.2

.2
.7
.8
.6
.2
.9

.7
.3

                       73

-------
 REMOVAL  AND  PARTITIONING  OF  CERCLA  ORGANICS  DURING
      TREATMENT  -  ACCLIMATED  SYSTEM  DATA  SET  9
1
1
| COMPOUNDS
1
1
1
1
1
IDICHLOROBENZENE, PROBABLY 1,2
IDICHLOROBENZENE, PROBABLY 1,3
IDICHLOROBENZENE, PROBABLY 1.4
(1,2,4-TRICHLOROBENZENE
(NITROBENZENE
|1,5-DINITROBENZENE
|2,6-DINITROTOLUENE
IP-CRESOL
(4-CHLOROANILINE
IHEXACHLOROETHANE
| HEXACHLOROBUTAD I ENE
(DIMETHYL PHTHALATE
IDIETHYL PHTHALATE
IDIBUTYL PHTHALATE
| BUTYL BENZYL PHTHALATE
|BIS(2-ETHYLHEXYL)PHTHALATE
(NAPHTHALENE
(LINDANE
IOIELDRIN
I

x


PRIMARY
REMOVAL


5.6
20.5
5.2
31.0
-8.8


-11.6

27.8
30.6
-1.2
2.0
24. A
29.4

6.3
16.5
39.4

X


TOTAL
REMOVAL


95.2
90.5
97.0
88.2
94.9


59.9

94.8
96.9
96.5
96.4
96.1
96.7

97.0
96.0
85.2

X


ADSORBED



23.2
20.6
17.2
36.2
0.3


2.4

*
61.8
0.3
1.7
41.0
47.0

16.4
23.3
71.5
I
X


BIO+STRIP)
+CHE.TRAN)


72.0
69.9
79.9
52.0
94.6


57.5

*
35.1
96.3
94.8
55.1
49.7

80.6
72.7
13.7
* Partitioning not calculated because of inconsistent data
                         74

-------
CONCENTRATIONS OF CERCLA ORGANICS IN WASTEWATER AND
   SLUDGE SAMPLES -  ACCLIMATED SYSTEM DATA SET 10
1
| COMPOUNDS
1
1
1
1
1
IDICHLOROBENZENE, PROBABLY 1,2
IDICHLOROBENZENE, PROBABLY 1,3
IDICHLOROBENZENE, PROBABLY 1,4
| 1 , 2 , 4 - TR I CHLOROBENZENE
[NITROBENZENE
|1,3-DINITROBENZENE
| 2,6-DINITROTOLUENE
IP-CRESOL
|4-CHLOROANILINE
IHEXACHLOROETHANE
| HEXACHLOROBUTAD I ENE
[DIMETHYL PHTHALATE
IDIETHYL PHTHALATE
IDIBUTYL PHTHALATE
| BUTYL BENZYL PHTHALATE
|BIS(2-ETHYLHEXYL)PHTHALATE
(NAPHTHALENE
ILINDANE
IDIELDRIN
I
CONCENTRATION
RUU


RWU


PR I
INF
PR I
EFF
(DUP)
UG/L
3
8
3
210
26

0
27

23
4
5
21
40
43
1861
13
7
148
.8
.1
.8
.7
.3

.0
.1

.6
.3
.1
.8
.0
.0
.1
.8
.4
.1
UG/L
5.
10.
5.
229.
9.

0.
3.

23.
14.
0.
21.
48.
52.
1845.
15.
7.
183.
3
1
1
5
0

0
5

3
2
3
8
7
1
1
1
6
5
UG/L
293.2
392.5
353.6
607.4
339.8

453.0
457.1

334.7
369.1
516.9
540.6
439.7
395.5
1368.6
349.7
285.9
831.7
UG/L
282.6
367.2
353.7
590.6
330.0


417.4

270.4
267.7
484.1
522.3
325.5
243.1
769.4
337.3
259.0
397.9
OF TOXICS
PR I
EFF
(DUP)
UG/L
319.1
367.8
373.0
618.0
326.2

556.9
425.0

273.1
283.7
489.4
571.3
353.8
272.1
431.0
352.3
271.4
348.4
SEC
EFF


UG/L
18
33
15
70
36

67
28

20
14
23
29
27
14
635
15
15
128
.2
.5
.4
.1
.4

.0
.7

.7
.1
.5
.6
.3
.0
.4
.6
.0
.9
SEC
WAS

UG/L
276
432
166
3297
469

437
0

603
1821
246
506
1026
331
32907
170
183
15842
PR I
WAS

UG/L
10898
11145
18547
48367
0

0
1682

0
61127
464
977
34655
36779
148862
0
15457
19250
                      75

-------
MASSES OF CERCLA ORGANICS IN WASTEWATER AND SLUDGE
      STREAMS - ACCLIMATED SYSTEM DATA SET 10
1
1
| COMPOUNDS
1
1
1
1
1
IOICHLOROBENZENE, PROBABLY 1,2
IDICHLOROBENZENE, PROBABLY 1,3
IDICHLOROBENZENE, PROBABLY 1,4
| 1 , 2 , 4 - TR I CHLOROBENZENE
(NITROBENZENE
|1,3-D1NITROBENZENE
|2,6-DINITROTOLUENE
IP-CRESOL
|4-CHLOROANILINE
IHEXACHLOROETHANE
| HEXACHLOROBUTAOIENE
(DIMETHYL PHTHALATE
PR I
INF
CMS
55
74
67
115
64

86
87

63
70
98
IDIETHYL PHTHALATE |ios
|0 I BUTYL PHTHALATE
83
| BUTYL BENZYL PHTHALATE | 75
|BIS(2-ETHYLHEXYL)PHTHALATE |261
(NAPHTHALENE | 66
ILINDANE ( 54
(DIELDRIN (158
.9
.9
.5
.9
.8

.4
.2

.9
.4
.6
.1
.9
.4
.1
.7
.5
.7
MASS OF TOXICS
PR I PR I SEC
EFF EFF EFF
(OUP)
CMS
53
70
67
112
63


79

51
51
92
99
62
46
146
64
49
75
.9
.0
.5
.7
.0


.6

.6
.1
.3
.6
.1
.4
.8
.4
.4
.9
CMS
60.9
70.2
71
117
62

106
81

52
54
93
109
67
51
82
67
51
66
.2
.9
.2

.2
.1

.1
.1
.4
.0
.5
.9
.2
.2
.8
.5
CMS
3
6
2
13
6

12
5

3
2
4
5
5
2
121
3
2
24
.5
.4
.9
.4
.9

.8
.5

.9
.7
.5
.6
.2
.7
.2
.0
.9
.6
SEC
WAS
CMS
0.6
0.9
0.3
6.7
1.0

0.9
0.0

1.2
3.7
0.5
1.0
2.1
0.7
67.3
0.3
0.4
32.4
PR I
WAS
CMS
12
12
21
56
0

0
1

0
70
0
1
40
42
172
0
.6
.9
.5
.0
.0

.0
.9

.0
.8
.5
.1
.1
.6
.4
.0
17.9
22
.3
                        76

-------
REMOVAL AND PARTITIONING OF CERCLA  ORGANICS  DURING
     TREATMENT - ACCLIMATED SYSTEM  DATA SET  10
         COMPOUNDS
                         I
                         I                           I
                         (PRIMARY  TOTAL  ADSORBED BIO+STRIP)
                         (REMOVAL REMOVAL        +CHE.TRAN|

D I CHLOROBENZENE, PROBABLY 1,2
01 CHLOROBENZENE, PROBABLY 1,3
D I CHLOROBENZENE, PROBABLY 1,4
1,2, 4 -TR I CHLOROBENZENE
NITROBENZENE
1,3-DINITROBENZENE
2,6-DINITROTOLUENE
P-CRESOL
4-CHLOROANILINE
HEXACHLOROETHANE
HEXACHLOROBUTAOIENE
DIMETHYL PHTHALATE
D I ETHYL PHTHALATE
D I BUTYL PHTHALATE
BUTYL BENZYL PHTHALATE
BIS(2-ETHYLHEXYL)PHTHALATE
NAPHTHALENE
LINDANE
DIELDRIN

-2.6
6.4
-2.7
0.5
3.4

-23
7.8

18.8
25.3
5.8
-1.1
22.7
34.9
56.1
1.4
7.2
55.1

93.8
91.5
95.6
88.5
89.3

85.2
93.7

93.8
96.2
95.5
94.5
93.8
96.5
53.6
95.5
94.7
84.5

23.6
18.4
32.3
54.2
1.5

1.0
2.2

*
*
1.1
2.1
50.3
57.4
91.8
0.5
33.5
*

70.2
73.1
63.3
34.3
87.8

84.2
91.5

*
*
94.4
92.4
43.4
39.1
-38.2
95.0
61.2
*
 Partitioning  not calculated because of inconsistent data
                           77

-------
CONCENTRATIONS OF CERCLA ORGANICS IN WASTEWATER AND
  •SLUDGE SAMPLES - ACCLIMATED SYSTEM DATA SET 11
1
1
1
| COMPOUNDS
1
1
1
1
1
IDICHLOROBENZENE, PROBABLY 1,2
IDICHLOROBENZENE, PROBABLY 1,3
IOICHLOROBENZENE, PROBABLY 1,4
(1,2,4-TRICHLOROBENZENE
| NITROBENZENE
|1,3-OINITROBENZENE
|2,6-DINITROTOLUENE
IP-CRESOL
I4-CHLOROANILINE
IHEXACHLOROETHANE
IHEXACHLOROBUTAOIENE
IOIHETHYL PHTHALATE
IOIETHYL PHTHALATE
IDIBUTYL PHTHALATE
| BUTYL BENZYL PHTHALATE
|BIS(2-ETHYLHEXYL)PHTHALATE
(NAPHTHALENE
ILINOANE
IOIELDRIN
I
CONCENTRATION
RUW




UG/L
2
4
3
875
0
50
0
40
3
.0
.2
.1
.1
.0
.0
.0
.1
.0
0.0
2
0
15
26
19

9
0
31
.7
.0
.1
.1
.4

.4
.0
.6
RWU

(DUP)
UG/L
10.3
13.3
13.4
1017.7
12.3
74.2
0.0
54.7
12.2
0.0
20.0
22.0
49.8
62.9
52.7

20.3
27.6
118.2
PR I
INF

UG/L
329.0
383.7
381.4
1235.4
447.4
258.3
438.2
531.2
361.8
389.1
462.3
505.6
566.0
453.8
431.0

415.3
423.3
775.0
PR I
INF
(OUP)
UG/L
329.7
375.5
386.9
1065.8
420.2
232.1
415.8
524.0
335.0
412.5
470.8
507.5
537.0
428.4
369.0

368.8
409.1

OF TOXICS
PR I
EFF

UG/L
305.6
365.2
357.1
537.9
348.8
43.2
322.4
585.9
347.4
273.0
323.8
468.7
544.5
327.2
281.4

372.9
364.1
526.0
SEC
EFF

UG/L
10.2
29.7
2.4
62.8
15.0
0.0
65.0
1.9
9.3
3.7
6.3
0.7
1.5
6.2
4.8

1.9
13.5
341.2
SEC
EFF
(DUP)
UG/L
11.0
33.2
3.1
69.8
13.0
0.0
67.4
5.1
8.1
4.6
8.6
2.9
5.0
10.0
9.6

2.6
15.5
139.8
SEC
WAS

UG/L
545
743
401
2888
21
1124
0
78
84
0
4560
0
92
1403
1665

348
648
15813
PR I
WAS

UG/L
19548
19556
17144
57977
615
525
1062
3079
1080
441
67210
1205
2177
38279
42946

16557
20011
44698
PR1
WAS
(DUP)

19564
20573
17123
60656
111
2120
0
2682
675
0
70940
597
1482
40274
49645

17266
22629
62436
                       78

-------
MASSES OF CERCLA ORGANICS IN WASTEWATER AND SLUDGE
   ----STREAMS - ACCLIMATED SYSTEM DATA SET 11
1
| COMPOUNDS
1
1
1
1
I
IDICHLOROBENZENE, PROBABLY 1,2
IDICHLOROBENZENE, PROBABLY 1,3
IDICHLOROBENZENE, PROBABLY 1,4
| 1 ,2,4-TRICHLOROBENZENE
(NITROBENZENE
1 1,3-DINITROBENZENE
|2,6-DINITROTOLUENE
IP-CRESOL
(4-CHLOROANILINE
IHEXACHLOROETHANE
IHEXACHLOROBUTADIENE
(DIMETHYL PHTHALATE
IDIETHYL PHTHALATE
IDIBUTYL PHTHALATE
| BUTYL BENZYL PHTHALATE
|BIS(2-ETHYLHEXYL)PHTHALATE
(NAPHTHALENE
(LINDANE
MASS OF TOXICS
PR I
INF


CMS


62
73
72
235
85
49
83
101
69
74
88
96
108
86
82

79
80
IDIELDRIN |147
I I


.8
.2
.7
.7
.4
.3
.6
.3
.0
.2
.2
.4
.0
.6
.2

.2
.8
.8
PR I
INF
(DUP)
CMS


62.9
71.6
73.8
203.3
80.2
44.3
79.3
100.0
63.9
78.7
89.8
96.8
102.4
81.7
70.4

70.3
78.0

PR I
EFF

CMS


58.3
69.7
68.1
102.6
66.5
8.2
61.5
111.8
66.3
52.1
61.8
89.4
103.9
62.4
53.7

71.1
69.5
100.3
SEC
EFF

CMS


1.9
5.7
0.5
12.0
2.9
0.0
12.4
0.4
1.8
0.7
1.2
0.1
0.3
1.2
0.9

0.4
2.6
65.1
SEC
EFF
(DUP)
CMS


2.1
6.3
0.6
13.3
2.5
0.0
12.9
1.0
1.6
0.9
1.6
0.6
1.0
1.9
1.8

0.5
3.0
26.7
SEC
UAS


CMS


1
1
0
5
0
2
0
0
0
0
9
0
0
2
3

0
1
32


.1
.5
.8
.9
.0
.3
.0
.2
.2
.0
.3
.0
.2
.9
.4

.7
.3
.3
PR I
UAS


CMS


22.
22.
19.
67.
0.
0.
1.
3.
1.
0.
77.
1.
2.
44.
49.

19.
23.
51.


6
6
9
1
7
6
2
6
3
5
8
4
5
3
7

2
2
8
PR I
WAS
(DUP)
CMS


22.7
23.8
19.8
70.2
0.1
2.5
0.0
3.1
0.8
0.0
82.1
0.7
1.7
46.6
57.5

20.0
26.2
72.3
                      79

-------
REMOVAL AND PARTITIONING OF CERCLA ORGANICS DURING
     TREATMENT -  ACCLIMATED SYSTEM DATA SET 11


COMPOUNDS

'_


IDICHLOROBENZENE, PROBABLY 1,2
IDICHIOROBENZENE, PROBABLY 1,3
IDICHLOROBENZENE, PROBABLY 1,4
|1.2,4-TRICHLOROBENZENE
| NITROBENZENE
|1,3-DINITROBENZENE
|2,6-DINITROTOLUENE
IP-CRESOL
(4-CHLOROANILINE
IHEXACHLOROETHANE
| HEXACHLOROBUTADIENE
(DIMETHYL PHTHALATE
IDIETHYL PHTHALATE
IDIBUTYL PHTHALATE
| BUTYL BENZYL PHTHALATE
|BIS(2-ETHYLHEXYL)PHTHALATE
(NAPHTHALENE
ILINDANE
IDIELDRIN
1

x


PRIMARY
REMOVAL

7.2
3.8
r.o
53.3
19.6
62.4
24.5
-11.1
0.3
31.9
30.6
7.5
1.3
25.8
29.6

4.9
12.5
32.1

X


TOTAL
REMOVAL

96.8
91.7
99.3
94.2
96.8
100.0
84.5
99.3
97.5
99.0
98.4
99.6
99.4
98.2
98.2

99.4
96.5
69.0

X


ADSORBED


*
*
*
34.0
*
*
*
3.5
1.8
*
*
1.1
2.2
*
«

*
32.8
*
I
* I
I
I
BIOSTRIP)
*CHE.TRAN|
I
I
* I
* I
* I
60.3 |
* I
* I
* I
95.9 |
95.7 |
* I
* I
98.6 |
97.2 |
* I
* I
I
* I
63.7 |
* I
I
 Partitioning not calculated because of inconsistent data
                        80

-------
CONCENTRATIONS OF CERCLA ORGANICS IN WASTEWATER AND
 SLUDGE SAMPLES - UNACCLIMATED SYSTEM DATA SET 1


Compounds
-

OICHLOROBENZENE, PROBABLY 1,2
OICHLOROBENZENE, PROBABLY 1,3
DICHLOROBENZENE, PROBABLY 1,4
1,2.4-TRICHLOROBENZENE
NITROBENZENE
1,3-DINITROBENZENE
2,6-DINtTROTOLUENE
P-CRESOL
4-CHLOROANILINE
HEXACHLOROETHANE
HEXACHLOROBUTADIENE
DIMETHYL PHTHALATE
01 ETHYL PHTHALATE
01 BUTYL PHTHALATE
BUTYL BENZYL PHTHALATE
BISC2-ETHYLHEXYDPHTHALATE
NAPHTHALENE
LINDANE
DIELORIN

CONCENTRATION OF
RWU




UG/L
0
0
0
141
0
6
0
72

0
0
5
60
18
0

7
13
35

.0
.0
.0
.8
.0
.6
.0
.3

.0
.3
.3
.3
.5
.0

.6
.1
.1

RUU
COUP)

UG/L
0.0
0.0
3.4
352.9
2.9
0.0
0.0
75.1

0.0
0.0
5.5
77.1
32.3
0.0

28.7
0.0
14.5

PR I

INF


UG/L
225.
252.
237.
320.
303.
157.
275.
505.

100.
116.
117.
379.
268.
136.

303.
164.
290.

1
5
7
5
2
1
2
5

0
3
9
6
6
8

1
2
6

PR I
EFF

UG/L
233.0
257.7
229.1
326.8
260.3
17.4
193.4


73.2
88.5
157.7
296.9
179.2
84.3



124.6

PR I
EFF
(OUP)
UG/L
170.4
190.5
184.0
277.7
255.8
14.3
176.0


47.6
74.8
101.1
291.5
168.2
80.1

265.4
131.7
114.3

TOXICS
SEC
EFF

UG/L
38.3
40.6
41.1
64.9
160.2
41.6
38.5
40.9

0.0
4.0
7.9
12.8
10.9
4.7

35.6
80.6
13.7


MIXED
LIQUOR
(48hr)
UG/L
0.0
11.5
5.8
301.3
0.0
53.0
0.0
0.0

0.0
68.1
0.0
0.0
0.0
0.0

6.4
210.6
600.7


SEC
WAS

UG/L
219
267
244
1241
72
105
0
0

0
420
0
0
50
0

174
719
1229


PR I
WAS

UG/L
2611
2593
2356
5498
51
166
0
3855

0
5040
208
467
3380
4081

2743
3653
0

                   81

-------
.--.MASSES  OF  CERCLA ORGANICS IN WASTEWATER AND SLUDGE
        STREAMS -  UNACCLIMATED SYSTEM DATA SET 1
1
1
1
1
| „ Compound*
1
1
1
1
IDICHLOROBENZENE, PROBABLY 1,2
IDICHLOROBENZENE, PROBABLY 1,3
IDICHLOROBENZENE, PROBABLY 1,4
|1,2,4-TRICHLOR08ENZENE
(NITROBENZENE
|1,3-DINITROBENZENE
|2,6-OINITROTOLUENE
IP-CRESOL
IHEXACHLOROETHANE
IHEXACHLOROBUTADIENE
(DIMETHYL PHTHALATE
IOIETHYL PHTHALATE
IDIBUTYL PHTHALATE
| BUTYL BENZYL PHTHALATE
|BIS(2-ETHYLHEXYL)PHTHALATE
(NAPHTHALENE
ILINDANE
(OIELDRIN
I

PR I
INF

CMS

85.
96.
90.
122.
115.
59.
105.
192.
38.
44.
45.
144.
102.
52.

115.
62.
110.







9
3
7
3
7
9
0
9
1
4
0
8
5
2

6
6
9


PR I
EFF

CMS

88.
98.
87.
124.
99.
6.
73.

27.
33.
60.
113.
68.
32.



47.







9
3
4
7
3
6
8

9
8
2
3
4
2



5

MASS OF
PR I
EFF
(DUP)
CMS

65.0
72.7
70.2
105.9
97.6
5.5
67.1

18.2
28.5
38.6
111.2
64.2
30.5

101.3
50.3
43.6

TOXICS
SEC
EFF

CMS

14.6
15.5
15.7
24.8
61.1
15.9
14.7
15.6
0.0
1.5
3.0
4.9
4.2
1.8

13.6
30.8
5.2

IN GRAMS
MIXED
LIQUOR
(48hr)
CMS

0.0
0.7
0.3
17.6
0.0
3.1
0.0
0.0
0.0
4.0
0.0
0.0
0.0
0.0

0.4
12.3
35.0


SEC
WAS

CMS

0
1
1
5
0
0
0
0
0
1
0
0
0
0

0
2
5







.9
.1
.0
.1
.3
.4
.0
.0
.0
.7
.0
.0
.2
.0

.7
.9
.0


PR I
WAS

CMS

6.
6.
5.
12.
0.
0.
0.
8.
0.
11.
0.
1.
7.
9.

6.
8.
0.







0
0
5
7
1
4
0
9
0
7
5
1
8
5

4
5
0

                              82

-------
 REMOVAL AND PARTITIONING OF CERCLA ORGANICS DURING
   "TREATMENT - UNACCLIMATED SYSTEM DATA SET 1
1
1
1
1
| _ Compounds
1
1
1
1
IDICHLOROBENZENE, PROBABLY 1,2
IDICHLOROBENZENE. PROBABLY 1,3
IDICHLOROBENZENE, PROBABLY 1.4
| 1 ,2,4-TRICHLOROBEMZENE
| NITROBENZENE
|1,3-DINITROBENZENE
|2,6-OINITROTOLUENE
IP-CRESOL
|4-CHLOROANiLiNE
IHEXACHLOROETHANE
IHEXACHLOROBUTADIENE
(DIMETHYL PHTHALATE
IDIETHYL PHTHALATE
(OIBUTYL PHTHALATE
| BUTYL BENZYL PHTHALATE
| BI S(2-ETHYLHEXYL )PHTHALATE
(NAPHTHALENE
ILINOANE
(DIELDRIN
I

X

PRIMARY
REMOVAL


10.4
11.2
13.1
5.7
14.9
89.9
32.9


39.6
29.8
-9.7
22.5
35.3
39.9

12.4
19.8
58.9


X

TOTAL
REMOVAL


83.0
83.9
82.7
79.7
47.2
73.5
86.0
91.9

100.0
96.6
93.3
96.6
95.9
96.6

88.3
50.9
95.3

II
X X |

ADSORBED BIO+STRIP |
+CHE. TRAN ||
II
I
8.1 74.9 |j
7.4 76.5 | |
7.1 75.6 |j
14.6 65.2
0.4 46.8
* •
* *
* *

* *
30.2 66.4
1.1 92.3
• *
* *
18.1 78.5

* *
18.2 32.7
* *

Partitioning not calculated because of inconsistent data
                      83

-------
CONCENTRATIONS OF CERCLA ORGANICS IN WASTEWATER AND
 SLUDGE SAMPLES - UNACCL1MATED SYSTEM DATA SET 2


Coopounds

—
IDICHLOROBENZENE, PROBABLY 1,2
IDICHLOROBENZENE, PROBABLY 1,3
IOICNLOROBENZENE, PROBABLY 1,4
|1,2,4-TRICHLOROBENZENE
| NITROBENZENE
|1,3-DUITROBENZENE
|2,6-DINITROTOLUENE
IP-CRESOL
|4-CHLOROANILINE
IHEXACHLOROETHANE
IHEXACHLOROBUTADIENE
(DIMETHYL PHTHALATE
IOIETHYL PHTHALATE
IOIBUTYL PHTHALATE
| BUTYL BENZYL PHTHALATE
|BIS(2-ETHYLHEXYL>PHTHALATE
| NAPHTHALENE
JLINDANE
IDIELDRIN
I
CONCENTRATION
RUU


UG/L
0.0
0.0
0.0
H1.8
0.0
6.6
0.0


0.0
0.3
5.3
60.3
18.5
0.0

7.6
13.1
35.1
RWW
(OUP)

UG/L
0.0
0.0
3.4
352.9
2.9
0.0
0.0


0.0
0.0
5.5
77.1
32.3
0.0

28.7
0.0
H.5
PR I
INF

UG/L
345.3
410.5
352.6
502.5
414.5
204.9
304.9


162.3
280.2
197.7
381.6
331.2
254.1

430.6
288.8
795.1
PR I
EFF

UG/L
243.6
296.1
260.0
337.8
366.9
24.4
285.9


77.5
138.5
243.1
399.1
302.8
164.0

387.2
217.2
641.3
SEC
EFF

UG/L
35.2
35.6
29.5
46.2
111.1
28.0
24.5


0.0
4.4
9.0
10.7
12.7
6.8

12.2
81.0
11.7
OF TOXICS
MIXED
LIQUOR

UG/L
27.3
41.8
27.9
1233.4
0.0
330.5
0.0


0.0
0.0
0.0
0.0
186.6
121.5

28.8
167.7
161.8
MIXED
LIQUOR
(0 hr)
UG/L
2.9
3.6
2.7
121.9
1.0
27.6
5.8


0.0
0.0
0.0
3.5
18.7
17.4

4.3
4.2
13.2
MIXED
LIQUOR
(48hr)
UG/L
101.4
210. 5
39.9
3251.8
0.0
1019.9
0.0


0.0
1354.1
0.0
0.0
327.8
246.5

45.1
3485.8
8456.4
SEC
WAS

UG/L
1739
2251
1528
8841
1281
1049
0


0
5349
0
62
329
253

296
7878
8454
SEC
WAS
COUP)
UG/L
1400
1393
978
5502
1140
1022
0


0
3087
0
56
331
156

198
4919
4028
PR I
WAS

UG/L
9093
9617
7357
46002
237
885
24339


32319
1221
19542
19631
39076
12248

0
1422
1469
                   84

-------
MASSES OF CERCLA ORGANICS IN WASTEWATER AND SLUDGE
     STREAMS - UNACCLIMATED SYSTEM DATA SET 2
Compounds
—
D1CHLOROBENZENE, PROBABLY 1,2
DICHLOROBENZENE, PROBABLY 1,3
DICHLOROBENZENE, PROBABLY 1,4
1.2,4-TRICHLOROBENZEK
NITROBENZEME
1,3-DINITROBENZENE
2,6-OtNITROTOLUENE
P-CRESOL
4-CHLOROANILINE
HEXACHLOROETHANE
HEXACHLOROBUTADIENE
DIMETHYL PHTHALATE
01 ETHYL PHTHALATE
D I BUTYL PHTHALATE
BUTYL BENZYL PHTHALATE
B1S(2-ETHYLHEXYL)PHTHALATE
NAPHTHALENE
LINDANE
DIELORIN
PR
IN
CM
131
156
134
191
158
78
116


61
106
75
145
126
96

164
110
303
I
f
S
.7
.6
.5
.7
.2
.2
.3


.9
.9
.4
.6
.4
.9

.3
.2
.4
PR I
EFF
CMS
92.
113.
99.
128.
140.
9.
109.


29.
52.
92.
152.
115.
62.

147.
82.
244.


9
0
2
9
0
3
1


6
8
7
3
5
6

7
9
7
f
SEC
EFF I
CMS
13.4
13.6
11.2
17.6
42.4
10.7
9.4


0.0
1.7
3.4
4.1
4.8
2.6

4.7
30.9
4.5
IASS OF T
MIXED H
IOUOR I
<
CMS
1.6
2.4
1.6
71.9
0.0
19.3
0.0


0.0
0.0
0.0
0.0
10.9
7.1

1.7
9.8
9.4
OXICS I
IXED
IQUOR
0 hr)
CMS
0.2
0.2
0.2
7.1
0.1
1.6
0.3


0.0
0.0
0.0
0.2
1.1
1.0

0.2
0.2
0.8
N GRAMS
MIXED
LIQUOR
(48hr)
CMS
5.9
12.3
2.3
189.6
0.0
59.5
0.0


0.0
78.9
0.0
0.0
19.1
14.4

2.6
203.2
493.0
SEC
WAS
CMS
7.2
9.4
6.4
36.7
5.3
4.4
0.0


0.0
22.2
0.0
0.3
1.4
1.1

1.2
32.7
35.1
SEC
WAS
(DUP)
CMS
5.8
5.8
4.1
22.9
4.7
4.2
0.0


0.0
12.8
0.0
0.2
1.4
0.6

0.8
20.4
16.7
PR I
WAS
CMS
23.5
24.9
19.1
119.1
0.6
2.3
63.0


83.7
3.2
50.6
50.8
101.2
31.7

0.0
3.7
3.8
                       85

-------
 REMOVAL AND PARTITIONING OF CERCLA ORGANICS DURING
    TREATMENT - UNACCLIMATED SYSTEM DATA SET 2
Conpounds

DICHLOROBENZENE, PROBABLY 1,2
DICHLOROBENZENE, PROBABLY 1,3
DICHLOROBENZENE, PROBABLY 1,4
1,2, 4- TRICHLOROBENZEME
NITROBENZENE
1,3-DINITROBENZENE
2,6-DINITROTOLUENE
P-CRESOL
4-CHLOROANILINE
IHEXACHLOROETHANE
! HEXACHLOROBUTAD I ENE
DIMETHYL PHTHALATE
IDIETHYL PHTHALATE
IDIBUTYL PHTHALATE
| BUTYL BENZYL PHTHALATE
|BIS(2-ETHYLHEXYL)PHTHALATE
[NAPHTHALENE
ILINDANE
DIELDRIN

X
PRIMARY
REMOVAL

29
28
26
33
11
88
6


52
51
-23
-5
9
35

10
25
19

X
TOTAL
REMOVAL

90
91
92
91
73
86
92


100
98
95
97
96
97

97
72
99

X X
ADSORBED BIO+STRIP
i-CKE. TRAM

23 67
21 71
18 74
* *
4 70
* •
* *


* *
* *
* *
* *
* *
34 64

1 97
27 44
10 89

II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
II
Partitioning not calculated because of inconsistent data
                       86

-------
CONCENTRATIONS OF CERCLA ORGANICS  IN  WASTEWATER  AND
 SLUDGE SAMPLES - UNACCLIMATED SYSTEM DATA  SET 3
1
1
1
| Cowpxxndt
1
1
1
1
IDICHLOROBENZENE, PROBABLY 1,2
IDICHLOROBENZENE, PROBABLY 1,3
IDICHLOROBENZENE. PROBABLY 1,4
|1,2,4-TRICHLOROBENZENE
{NITROBENZENE
|1,3-DINITROBENZENE
{2,6-DINITROTOLUENE
IP-CRESOL
|4-CHOUOROANILINE
IHEXACHLOROETHANE
IHEXACNLOROBUTADIENE
{DIMETHYL PHTHALATE
IOIETHYL PHTHALATE
IDIBUTYL PHTHALATE
| BUTYL BENZYL PHTHALATE
|BIS(2-ETHYLHEXYL)PHTHALATE
{NAPHTHALENE
ILINDANE
IDIELDRIN
I
CONCENTRATION

RUU


UG/L


4.9
9.3
8.2
296.2
6.1
92.5
0.0
71.3

0.0
2.1
0.0
14.7
27.9
22.7

18.1
23.4
10.9


RUU

(OOP)
UG/L


3.2
7.2
7.2
283.8
8.8
68.9
0.0
66.2

0.0
0.0
0.0
13.6
25.5
23.0

19.8
24.5
10.1


PRI
INF

UG/L


196.2
232.6
222.2
469.6
265.7
172.7
234.4
385.1

182.1
198.5
204.9
252.5
243.3
224.8

251.4
258.7
143.1


PRI
EFF

UG/L


159.2
201.1
190.7
341.6
207.1
31.2
107.2
429.3

103.4
97.1
179.3
260.6
148.5
136.4

213.7
194.3
131.6


PRI
EFF
COUP)
UG/L


158.0
201.8
183.6
331.8
199.0
20.3

417.6

120.6
99.0

241.4
135.9
124.7

205.5
191.0
112.2


SEC
EFF

UG/L


17.3
26.7
18.7
46.8
60.1
26.7
18.4
0.0

0.0
3.9
4.5
9.2
6.0
4.5

5.3
79.4
6.8

OF TOXICS

SEC
EFF
(OOP)
UG/L


16.4
25.7
18.2
47.8
58.3
9.3
17.3
0.0

0.0
3.0
0.0
8.1
5.0
3.5

4.9
78.3
10.0


NIXED
LIQUOR
(Ohr)
UG/L


28.8
39.6
34.4
314.6
77.8
390.8
0.0
0.0

0.0
15.1
0.0
0.0
142.9
127.7

38.1
119.4
343.7


NIXED
LIQUOR
(48hr)
UG/L


68.4
77.7
63.3
182.9
0.0
450.8
0.0
0.0

0.0
148.3
0.0
0.0
249.6
258.0

58.8
378.0
569.6


SEC
WAS

UG/L


233
219
0
1125
0
702
0
0

0
403
0
103
266
312

78
827
962


SEC
WAS
(DUP)
UG/L


ISO
156
0
1094
0
409
0
0

0
365
0
0
0
251

52
825
1034


PRI
WAS

UG/L


1825
1947
1865
13840
90
348
13
3053

632
0
5727
199
405
4292

12510
2153
4223


PR]
WAS
(DUP)
UG/L


1999
2148
2130
14105
148
413
0
3417

0
0
6539
216
357
5102

14892
2453
4573

                      87

-------
MASSES OF CERCLA ORGANICS IN WASTEWATER AND SLUDGE
     STREAMS - UNACCLIMATED SYSTEM DATA SET 3
1 1
1
1 1 PHI
| Compouxto |. INF
1 "- 1
1 1 CHS
1 1
1
IDICHLOROBENZENE, PROBABLY 1,2
IOICHLOROBENZEHE, PROBABLY 1,3
IDICHLOROBENZENE, PROBABLY 1,4
74.9
88.7
84.8
|1,2,4-TRICHLOR08ENZENE (179.2
INITROBENZEHE (101.4
|1,3-D1NITROBENZENE
|2,6-DINITROTOLUENE
IP-CRESOL
(4-CHOLOROANIL1NE
IHEXACHLOROETHANE
IHEXACHLOROBUTAOIENE
| DIMETHYL PHTHALATE
|0 (ETHYL PHTHALATE
IDIBUTYL PHTHALATE
| BUTYL BENZYL PHTHALATE
| B I S( 2 - ETHYLHEXYL )PHTHALATE
(NAPHTHALENE
ILINDANE
(DIELORIN
I
I
65.9
89.4
146.9

69.5
75.7
78.2
96.3
92.8
85.8

95.9
98.7
54.6
MASS OF TOXICS
PR I
EFF

CMS
60.7
76.7
72.8
130.3
79.0
11.9
40.9
163.8

39.4
37.0
68.4
99.4
56.6
52.1

81.6
74.1
50.2
PR I
EFF
(DUP)
CMS
60.3
77.0
70.0
126.6
75.9
7.8

159.3

46.0
37.8

92.1
51.8
47.6

78.4
72.9
42.8
SEC
EFF

CMS
6.6
10.2
7.1
17.9
22.9
10.2
7.0
0.0

0.0
1.5
1.7
3.5
2.3
1.7

2.0
30.3
2.6
SEC
EFF
(DUP)
CMS
6.3
9.8
6.9
18.3
22.3
3.5
6.6
0.0

0.0
1.1
0.0
3.1
1.9
1.3

1.9
29.9
3.8
MIXED
LIQUOR
(Ohr)
CMS
1.7
2.3
2.0
18.3
4.5
22.8
0.0
0.0

0.0
0.9
0.0
0.0
8.3
7.4

2.2
7.0
20.0
MIXED
LIQUOR
(48hr)
CMS
4.0
4.5
3.7
10.7
0.0
26.3
0.0
0.0

0.0
8.6
0.0
0.0
14.6
15.0

3.4
22.0
33.2
SEC
WAS

CMS
1.0
0.9
0.0
4.7
0.0
2.9
0.0
0.0

0.0
1.7
0.0
0.4
1.1
1.3

0.3
3.4
4.0
SEC
WAS
(DUP)
CMS
0.6
0.6
0.0
4.5
0.0
1.7
0.0
0.0

0.0
1.5
0.0
0.0
0.0
1.0

0.2
3.4
4.3
PR]
WAS

CMS
4.7
5.0
4.8
35.8
0.2
0.9
0.0
7.9

1.6
0.0
14.8
0.5
1.0
11.1

32.4
5.6
10.9
PR1
WAS
(DUP)
CMS
5.2
5.6
5.5
36.5
0.4
1.1
0.0
8.8

0.0
0.0
16.9
0.6
0.9
13.2

38.5
6.3
11.8
                   88

-------
REMOVAL AND PARTITIONING OF CERCLA ORGANICS DURING
   TREATMENT - UNACCLIMATED SYSTEM DATA SET 3



_ Compounds
-

IDICHLOROBENZENE, PROBABLY 1,2
IDICHLOROBENZENE, PROBABLY 1,3
IDICHLOROBENZENE, PROBABLY 1,4
|1,2,4-TRICHLOROBENZENE
(NITROBENZENE
|1,3-DINITROBENZENE
|2,6-OIN1TROTOLUENE
IP-CRESOL
|4-CHOLOROANILINE
(HEXACHLOROETHANE
IHEXACHLOROBUTADIENE
[DIMETHYL PHTHALATE
IDIETHYL PHTHALATE
IDIBUTYL PHTHALATE
| BUTYL BENZYL PHTHALATE
|BIS(2-ETHYLHEXYL)PHTHALATE
(NAPHTHALENE
ILINDANE
IDIELDRIN
I


X

PRIMARY
REMOVAL
19
13
16
28
24
85
54
-10

38
51
12
1
42
42

17
26
15


X

TOTAL
REMOVAL
91
89
92
90
77
85
92
100

100
98
98
96
98
98

98
69
95


X

ADSORBED

8
7
6
23
*
*
•
6

*
*
20
1
*
*

37
*
28
I
I
X I
I
BIO+STRIPj
+CHE.TRAN|
84
82
85
67
*
"
*
94

*
*
78
96
*
*

61
*
67 ||
II
Partitioning not calculated because of inconsistent data
                      89

-------
CONCENTRATIONS OF CERCLA ORGANICS IN WASTEWATER AND
 SLUDGE SAMPLES - UNACCLIMATED SYSTEM DATA SET 4


Compounds
-

IDICHLOROBENZENE, PROBABLY 1,2
IDICHLOROBENZEME, PROBABLY 1,3
IDICHLOROBEMZEME, PROBABLY 1,4
| 1 , 2 , 4 - TR I CHLOROBENZENE
(NITROBENZENE
|1,3-DINITROBENZENE
|2,6-DINITROTOLUENE
IP-CRESOL
(4-CHOLOROAN1LINE
(HEXACHLOROETHANE
IHEXACHLOROBUTADIENE
IOIMETHYL PHTHALATE
IDIETHYL PHTHALATE
IDIBUTYL PHTHALATE
| BUTYL BENZYL PHTHALATE
|BIS(2-ETHYLHEXYL)PHTHALATE
[NAPHTHALENE
ILINOANE
IDIELORIN
I
CONCENTRATION
RWU




U6/L
10
11
10

3
2
0
71


19
5
18
37
41

29
20
66
.2
.5
.0

.9
.8
.0
.5


.8
.9
.9
.6
.0

.3
.5
.7
PR I
INF

UG/L
219.7
214.9
211.1

190.5
109.8
183.4
309.3


222.4
230.9
229.6
261.2
245.0

281.3
226.1
888.8
PR)
INF
(DUP)
UG/L
196.5
192.2
189.4

218.8
114.5
200.3
307.2


174.6
243.1
234.3
206.9
212.2

279.1
192.8
625.4
PR I
EFF

UG/L

171.4
172.1




151.7


59.4
96.1
233.7
223.9
138.0


223.6
162.0
OF TOXICS
SEC
EFF

UG/L
54.3
52.3
28.7

132.2
0.0
52.3
4.4


5.
3.
5.
10.
5.

11.1
176.0
71.9
MIXED
LIQUOR
(Ohrs)
UG/L
0.0
0.0
0.0

0.0
0.0
0.0
0.0


0.0
0.0
0.0
211.1
0.0

0.0
0.0
0.0
MIXED
LIQUOR
(48hrt>
UG/L
0.0
0.0
0.0

0.0
0.0
0.0
0.0


0.0
0.0
0.0
130.4
0.0

0.0
0.0
0.0
SEC
WAS

UG/L
107
142
74

27
340
0
13


467
21
31
248
110

43
875
1388
PR I
WAS

UG/L
195
305
380

0
0
0
494


0
55
74
1081
1380

0
624
0
PR I
WAS
(DUP)
UG/L
2680
396
1072

1242
0
0
0


5100
96
177
3034
3985

0
1594
563
                    90

-------
MASSES OF CERCLA ORGANICS IN WASTEWATER AND SLUDGE
     STREAMS - UNACCLIMATED SYSTEM DATA SET 4
Compounds

IDICHLOROBENZENE, PROBABLY 1,2
IDICHLOROBENZENE, PROBABLY 1,3
IDICHLOROBENZENE, PROBABLY 1,4
|1,2,4-TRICHLOROBENZENE
| NITROBENZENE
| 1,3-DINITROBENZENE
|2,6-DINITROTOLUENE
IP-CRESOL
|4-CHOLOROANILINE
IHEXACHLOROETHANE
| HEXACHLOROBUTAOIENE
IOIHETHYL PHTHALATE
IDIETHYL PHTHALATE
|DI BUTYL PHTHALATE
| BUTYL BENZYL PHTHALATE
|BIS(2-ETNYLHEXYL)PHTHALATE
PR I
INF
CMS
83
82
80

72
41
70
118


84
88
87
99
93

(NAPHTHALENE |107
ILINDANE | 86
IOIELDRIN (339
.8
.0
.5

.7
.9
.0
.0


.9
.1
.6
.7
.5

.3
.2
.1
PR I
INF
(DUP)
CMS
75.0
73.3
72.3

83.5
43.7
76.4
117.2


66.6
92.7
89.4
78.9
81.0

106.5
73.5
238.6
PR I
EFF
CMS

65.
65.




57.


22.
36.
89.
85.
52.


85.
61.

4
7




9


6
7
2
4
7


3
8
MASS OF TOXICS
SEC MIXED MIXED SEC
EFF LIQUORLIQUOR WAS
(Ohrs)(48hrs)
CMS
20.7
20.0
10.9

50.5
0.0
19.9
1.7


2.1
1.4
2.2
4.1
2.3

4.3
67.1
27.4
CMS
0.0
0.0
0.0

0.0
0.0
0.0
0.0


0.0
0.0
0.0
12.3
0.0

0.0
0.0
0.0
CMS
0.0
0.0
0.0

0.0
0.0
0.0
0.0


0.0
0.0
0.0
7.6
0.0

0.0
0.0
0.0
CMS
0.4
0.6
0.3

0.1
1.4
0.0
0.1


1.9
0.1
0.1
1.0
0.5

0.2
3.6
5.8
PR I
WAS
CMS
0.5
0.8
1.0

0.0
0.0
0.0
1.3


0.0
0.1
0.2
2.8
3.6

0.0
1.6
0.0
PR I
WAS
(DUP)

6.9
1.0
2.8

3.2
0.0
0.0
0.0


13.2
0.2
0.5
7.9
10.3

0.0
4.1
1.5
                       91

-------
REMOVAL AND PARTITIONING OF CERCLA ORGANICS DURING
   TREATMENT - UNACCLIMATEO SYSTEM DATA SET 4
1
1
1
| Compounds
1
1
1
1
IDICHLOROBENZENE, PROBABLY 1,2
IDICHLOROBENZENE, PROBABLY 1.3
IDICHLOROBENZEME, PROBABLY 1.4
(1,2,4-TRICHLOROBENZENE
(NITROBENZENE
|1,3-DINITROBENZENE
|2,6-OINITROTOLUENE
IP-CRESOL
|4-CHOLOROANILIHE
IHEXACHLOROETHANE
| HEXACHLOKOBUT AD I ENE
(DIMETHYL PHTHALATE
IOIETHYL PHTHALATE
IDIBUTYL PHTHALATE
| BUTYL BENZYL PHTHALATE
|BIS(2-ETHYLHEXYL)PHTHALATE
(NAPHTHALENE
ILINOANE
(DIELDRIN
I
X

PRIMARY
REMOVAL



16
H




51


70
59
-1
4
40


-7
79

X

TOTAL
REMOVAL


74
74
86

35
100
73
99


97
98
98
95
97

96
16
90

X

ADSORBED



5
2
3

2
*
*
*


*
*
1
7
*

*
8
*

II
II
X II
II
BIO+STRIP||
+CHE.TRAN||
II
II
69 ||
72 ||
83 ||
II
33 ||
• II
• II
* II
II
II
* II
* II
97 ||
88 ||
* II
II
• II
8 II
* II
II
Partitioning not calculated because of  inconsistent data
                       92

-------
APPENDIX 3.  CONVENTIONAL POLLUTANT DATA
                93

-------
RCRA PILOT STUDY
       94

-------
 TOTAL SUSPENDED SOLIDS (mg/L) - ACCLIMATED SYSTEM
DATE
(DD-MM)
01-Feb
02-Feb
03-Feb
04-Feb
05-Feb
06-Feb
07-Feb
08-Feb
09-Feb
10-Feb
11-Feb
12-Feb
13-Feb
14-Feb
15-Feb
16-Feb
17-Feb
18-Feb
19-Feb
20-Feb
21-Feb
22-Feb
23-Feb
24-Feb
25-Feb
26-Feb
27-Feb
28-Feb
29-Feb
PRI
INF
252
128

188


216
260

256
220
252
252


124
192
324
348
188

224
176
172
220

220
172

PRI
EFF
204
96

104


210
172

164
112
32
148


72
124
176
180
164

108
100
48
152

112
32

SEC
EFF
0
3

4


7
7

1
6
6
3


1
3
11
7
5

8
4
21
6

13
2

MIX
LIQ
3250
2030

1920


1730
1810

1940
2100
1920
2120


2030
1990
2250
2010
3700

2470
2010
2250
2310

2280
2090

SEC
WAS
10170
9500

7590


7330
6750

8280
6140
7350
8210


6210
6240
6380
5420
6860

5950
7370
7350
7590

7710
8360

*
PRI X
SLU Remov





1.5
3.5

2.7


4.6



2.9
3.3
0.7
2.0

2.8
1.1
3.8
0.7

1.9
2.1

100
98

98


97
97

100
97
98
99


99
98
97
98
97

96
98
88
97

94
99

*  Percent Total  Solids
                    95

-------
TOTAL'SUSPENDED SOLIDS (mg/L) - ACCLIMATED SYSTEM
DATE
(DD-MM)
01 -Mar
02-Mar
03 -Mar
04 -Mar
OS-Mar
06-Mar
07-Mar
08-Mar
09-Mar
10-Mar
11 -Mar
1Z-Mar
13-Mar
14-Mar
15-Mar
16-Mar
17-Mar
18-Mar
19-Mar
20-Mar
21 -Mar
22-Mar
23-Mar
24-Mar
25-Mar
26-Mar
27-Mar
28-Mar
29-Mar
30-Mar
31 -Mar
AVERAGE AND

AVERAGE
DEVIATION
PR I
INF
292

164
52
144
124
204

248
224
148
176
212
208
224
228
232
260
240
252
308
224
228
204
156
112
240
128
580
228
PR I
EFF
152

108
84
80
80
76

156
160
72
120
196
104
228
80
184
200
76
132
124
120
88
136
80
52
116
100
410
104
SEC
EFF
11

4
0
2
0
4

9
7
1
4
50
6
5
29
14
2
11
4
4
1
11
0
5
1
8
4
7
16
ST. DEVIATION FOR

217
77

128
63

7
8
MIX
LIQ
2370

2260
2490
2140
2520
2670

2390
1260

2710
2320
2200
2180
1900
1900
2210
1840
1530
2130
2120
1870
1800
1910
2300
2100
1900
2230
1670
THE SPIKE

2152
394
SEC
WAS
8600

7600
9140
7560
9000
9260

8390
10340
2750
7940
7160
7800
7980
7510
7240
7660
7120
7350
7690
6860
6910
7840
6970
7950
7410
7440
7780
5480
PERIOD

7489
1244
*
PR I
SLU
1.5

1.3
1.3
1.4
0.8


0.9
0.8
2.1
0.7
1.1
1.6
1.9
3.0

2.2
0.9
0.7
0.8

0.7
0.8
0.5
0.5
0.7





1.7
1.0
X
Remov
96

98
100
99
100
98

96
97
99
98
76
97
98
87
94
99
95
98
99
100
95
100
97
99
97
97
99
93


97
4
*  Percent Total  Solids




                    96

-------
COO/SCOO DATA -  ACCLIMATED  SYSTEM
Date
01-Feb
02-Feb
03-Feb
04-Feb
05-Feb
06-Feb
07-Feb
08-Feb
09-Feb
10-Feb
11-Feb
12-Feb
13-Feb
14-Feb
15-Feb
16-Feb
17-Feb
18-Feb
19-Feb
20-Feb
21-Feb
22-Feb
23-Feb
24-Feb
25-Feb
26-Feb
27-Feb
28-Feb
29-Feb
TOTAL
PRI PRI
INF EFF
mg/L mg/L
249 230

243 276

596 234


418 368



897 488


370 329

513 555

393 349


516 413

571 483

714 278


625 761
COO
SEC X
EFF Remov
mg/L
46 82

45 81

55 91


58 86



134 85


85 77

131 74

95 76


54 90

109 81




SOLUBLE
PRI PRI
INF EFF
mg/L mg/L
46 88

71 66

207 99


193 198



309 274


61 54

297 156

370 150


229 216



211 97


136 78 |
COD
SEC X
EFF Remov
mg/L
38 17

24 66

31 85


53 73



190 39


0 100

117 61

70 81


100



124 41



               97

-------
           CCO/SCOO  DATA  - ACCLIMATED  SYSTEM
                 TOTAL  COD
                                       SOLUBLE   COD
Date
01 -Mar
02-Mar
03-Mar
04 -Mar
OS-Mar
06-Mar
07-Mar
08-Mar
09-Mar
10-Mar
11 -Mar
12-Mar
13-Mar
14-Mar
15-Mar
16-Mar
17-Mar
18-M«r
19-Mar
20-Mar
21 -Mar
22-Mar
23-Mar
24-Mar
25-Mar
26-Mar
27-Mar
28-Mar
29-Mar
30-Mar
31 -Mar
PRI PRI SEC X
INF EFF EFF Remov
mg/L rog/L mg/L
455 446 95 79

259 228 62 76




460 423 96 79

562 482 166 70




577 546 0 100




586 529 91 84



387 359 55 86




553 510 57 90

PRI PRI SEC X
INF EFF EFF Remov
mg/L mg/L mg/L
144 172 77 47

80 82 46 43




174 204 68 61

193 186 42 78


125 135 0 100

461 350 0 100




203 177 73 64

194 201 58 70

114 142 57 50






          AVERAGE AND ST. DEVIATION FOT THE SPIKE PERIOD
AVERAGE  |  497   414    83   82 |  194   160    59   67
         I                       I
DEVIATION)  157   132    40    7 |  105    72    46   23
                       98

-------
NITROGEN DATA :  ACCLIMATED SYSTEM
Date
(DD-MM)
01-Feb
02-Feb
03-Feb
04-Feb
05-Feb
06-Feb
07-Feb
08-Feb
09-Feb
10-Feb
11-Feb
12-Feb
13-Feb
14-Feb
15-Feb
16-Feb
17-Feb
18-Feb
19-Feb
20-Feb
21-Feb
22-Feb
23-Feb
24-Feb
25-Feb
26-Feb
Z7-Feb
28-Feb
29-Feb
AMMONIA-N
PR1 PRI SEC X
INF EFF EFF Remov
mg/L mg/L mg/L
4.6 5.1 0.4 91

12.6 12.4 5.6 55

9.4 9.5 3.7 60


23.7 24.0 12.6 47

26.4 25.6 14.7 44

17.7 18.5 9.6 46


14.4 12.6 2.7 81

23.1 24.6 5.3 77

16.6 20.8 6.1 63


24.6 23.8 0.0 100

24.4 22.6 0.6 98

19.7 4.0 0.0 100


31.4 21.3 3.6 89
NITRATE-N
PRI PRI SEC
INF EFF EFF
mg/L mg/L mg/L
7.76 7.93 7.8

1.72 0.71 5.5

0.92 0.32 8.2


0.53 0.21 5.6

0.26 0.20 5.2

0.26 8.6


0.07 0.05 8.0

0.25 0.23 8.1

0.17 0.13 16.8


0.44 0.11

0.24 0.15 14.9

0.22 11.50


0.24 0.21 7.9
            99

-------
           NITROGEN DATA :  ACCLIMATED SYSTEM

Date

(DD-MM)

01 -Mar
02-Mar
03-Mar
04-Mar
OS-Mar
06-Mar
07-Mar
08-Mar
09-Mar
10-Mar
11 -Mar
12-Mar
13-Mar
14-Mar
15-Mar
16-Mar
17-Mar
18-Mar
19-Mar
20-Nar
21 -Mar
22-Mar
23-Mar
24-Mar
25 -Mar
26-Mar
27-Mar
28-Mar
29-Mar
30-Mar
31 -Mar
AMMONIA-N

PRI PRI SEC X
INF EFF EFF Ranov
mg/L mg/L mg/L
17.1 20.0 1.0 94

7.7 6.8 0.4 95




22.6 20.4 0.9 96

21.5 21.2 2.4 89




23.8 24.2 4.4 81




32.8 33.8 14.8 55



12.3 13.7 4.7 61




27.5 26.6 6.4 77

NITRATE-N

PRI PRI SEC
INF EFF EFF
mg/L mg/L mg/L
0.20 0.15 14.4

1.32 0.90 6.9




0.19 0.14 10.2

0.20 0.15 12.6




0.28 0.22 9.4




0.20 0.11 7.7

0.00 0.00 2.9

0.10 1.41 8.8




0.17 0.00

AVERAGE AND ST .DEVIATION FOR THE SPIKE PERIOD

          I                       I                  I
AVERAGE   |  19.7  18.6   4.8   76 | 0.71  0.67   9.1  |
          I                       I                  I
DEVIATION |   7.4   7.6   4.5   19 | 1.59  1.70   3.4  |
                      100

-------
TOTAL SUSPENDED SOLIDS (mg/L) - UNACCLIMATED SYSTEM
---. DATE
CDD-MH)
01-Feb
02-Feb
03-Feb
04-Feb
05-Feb
06-Feb
07-Feb
08-Feb
09-Feb
10-Feb
11-Feb
12-Feb
13-Feb
U-Feb
15-Feb
16-Feb
17-Feb
18-Feb
19-Feb
20-Feb
21-Feb
22-Feb
23-Feb
24-Feb
25-Feb
26-Feb
27-Feb
28-Feb
29-Feb
PR I
INF
276


156
232

228
188

248
184
192
276


176
264
348
292
148

248
244
216
216
230
204
180
236
PR I
EFF
144


84
96

104
188

260
116
104
136


136
124
128
200
120

264
72
108
212
290
136
124
140
SEC
EFF
23


5
8

12
6

5
6
0
3


1
7
6
5
26

5
1
0
8
7
2
5
8
MIX
LIQ
3100


1800
1700

1590
1710

1920
1820
1960
2010


2770
1940
2110
1840
920

1890
1760
1860
2200
1960
1890
2170
1870
SEC
WAS
7950


5210
5100

5720
5760

6810
5830
6440
6740


6690
4270
6400
5840
6480

5980
6290
6290
6210
4610
6230
6530
9800
*
PRI X
SLU Remov




0.6

0.3
0.7


0.9
0.9
0.6


1.8
0.7
1.4
0.8
1.8

1.8
1.4
2.5
4.0
3.7
1.5
0.8
0.5
92


97
97

95
97

98
97
100
99


99
97
98
98
82

98
100
100
96
97
99
97
97
  *  Percent Total  Solids
                   101

-------
TOTAL SUSPENDED SOLIDS 
-------
CQO/SCOO  DATA  - UNACCLIMATED SYSTEM
Date
(DD-MM)
01-Feb
02-Feb
03-Feb
04-Feb
05-Feb
06-Feb
07-Feb
08-Feb
09-Feb
10-Feb
11-Feb
12-Feb
13-Feb
14-Feb
15-Feb
16-Feb
17-Feb
18-Feb
19-Feb
20-Feb
21-Feb
22-Feb
23-Feb
24-Feb
25-Feb
26-Feb
27-Feb
28-Feb
29-Feb
TOTAL COO
PRI PRI SEC X
INF EFF EFF Remov
mg/L mg/L mg/L
247 245 51 79

247 236 36 86

636 176 46 93


221 49 78

1180 553 76 94

874 563 181 79


360 327 93 74

587 499 108 82

524 339 100 81


532 554 71 87

610 504 108 82

710 683 142 80


659 495 128 81
SOLUBLE COO
PRI PRI SEC X
INF EFF EFF Remov
mg/L mg/L mg/L
62 67 34 46

67 68 43 36

89 185 43 52


206 208 50 76

452 238 43 90

308 331 176 43


80 65 35 56

405 198 174 57

189 136 47 75


228 217 48 79



268 247 63 76



            103

-------
           COO/SCOO DATA - UNACCLIMATED SYSTEM
Date
(DO -MM)
01 -Mar
02-Mar
03-Mar
04-Mar
05-Mar
06-Mar
07-Mar
08-Mar
09-Mar
10-Mar
11 -Mar
12-Mar
13 -Mar
K-Mar
15-Mar
16-Mar
17-Mar
18-Mar
19-Mar
20-Mar
21 -Mar
22-Mar
23-Mar
24 -Mar
25 -Mar
26-Mar
27-Mar
28-Mar
29-Mar
30-Mar
31 -Mar
TOTAL COO
PRI PRI SEC X
INF EFF EFF Remov
mg/L mg/L mg/L

507 464 169 67

252 239 53 79




419 444 39 91

615 589 126 80




525 0




662 586 84 87

587 579 98 83

218 562 89 59




572 577 107 81

SOLUBLE COO
PRI PRI SEC X
INF EFF EFF Remov
mg/L mg/L mg/L

149 167 78 48

86 86 0 100




290 300 0 100

201 289 55 73


81 103 0 100

513 416 0 100




215 188 92 57

219 191 60 73

121 139 68 44



I
I
I
I
           AVERAGE AND ST.  DEVIATION FOR THE SPIKE  PERIOD
  AVERAGE |  534   464    89   81  |   211    192    55    69
          I                       I
DEVIATION |  230   141    44    8  |   128     92    47    21
                         104

-------
NITROGEN  DATA  : UNACCLIMATED SYSTEM
Date
(DD-MM)
01-Feb
02-Feb
03-Feb
04-Feb
05-Feb
06-Feb
07-Feb
08-Feb
09-Feb
10-Feb
11-Feb
12-Feb
13-Feb
14-Feb
15-Feb
16-Feb
17-Feb
18-Fcb
19-Feb
20-Feb
21-Feb
22-Feb
23-Feb
24-Feb
25-Feb
26-Feb
27-Feb
28-Feb
29-Feb
AMMONIA-N
PRI PRI SEC X
INF EFF EFF Remov
mg/L mg/L mg/L
4.8 5.4 0.2 97

12.4 12.8 1.2 90

9.5 9.4 0.2 98


23.1 7.1

26.1 25.3 12.1 54

15.7 18.2 5.7 64


14.6 13.2 0.4 98

23.6 24.8 4.7 80

16.9 20.1 6.0 64


23.8 23.8 4.7 80

25.9 24.4 2.5 90

20.1 17.9 0.8 96


31.2 21.9 3.6 88
NITRATE-N
PRI PRI SEC
INF EFF EFF
mg/L mg/L mg/L
1.81 7.49 9.6

1.64 0.80 10.1

0.98 0.67 8.1


0.21 7.96

0.25 0.20 5.8

2.87 0.12 8.7


0.05 0.05 10.3

0.24 0.17 7.6

0.33 0.16 12.8


0.14 0.04 17.0

0.52 0.26 11.2

0.15 0.02 13.6


0.21 0.41 9.1
         105

-------
             NITROGEN DATA : UNACCLIMATED SYSTEM
Date
(DD-MM)
01 -Mar
02-Mar
03-Mar
04-Mar
05-Mar
06-Mar
07-Mar
08-Mar
09-Mar
10-Mar
11 -Mar
12-Mar
13-Mar
14-Mar
15-Mar
16-Mar
17-Mar
18-Mar
19-Mar
20-Mar
21 -Mar
22-Mar
23-Mar
24 -Mar
25-Mar
26-Mar
27-Mar
28-Mar
29-Mar
30-Mar
31 -Mar
AMMONIA-N
PRI PRI SEC X
INF EFF EFF Remov
mg/L mg/L mg/L
18.1 19.3 5.0 73

8.3 7.1 0.2 98




22.4 20.2 0.9 96

22.4 21.2 1.1 95




23.0 26.4 1.5 93



'
32.1 36.8 6.5 80

28.4 32.4 16.8 41

9.4 14.3 5.0 47






NITRATE-N
PRI PRI SEC
INF EFF EFF
mg/L mg/L rog/L
0.26 0.19 9.3

1.30 0.62 6.8




0.13 0.13 10.3

0.18 0.16 13.9




0.22 0.22 12.5




0.16 0.14 13.7

0.09 0.10 4.9

0.00 0.00 7.6






          AVERAGE AND ST. DEVIATION FOR THE SPIKE  PERIOD
          I                       I                      I
AVERAGE   |   20    19   3.9   81  |   0.56   0.95      10 |

          I                       I                      I
DEVIATION |    7     8   4.2   18  |   0.73   2.21       3 \
                         106

-------
EFFECT OF RCRA TOXICS ON  COD REMOVAL



l<
I
o
o
o



100 -
90 -
80 -
70 -
60 -
50 -
40 -
30 -
20 -
10 -
n -
— — — 	 —
A




j

                  I
                  20
                                      t
 •  UN ACCLIMATED

Indleote Intermittent spike 'days.
                      TIME (days)
                            40
                                ACCLIMATED
                                          t
60

-------
             EFFECT  OF  RCRA TOXICS ON  NITRIFICATION
          100
o
CD
     •   UNACCUMATEO

Arrows Indicate intermittent spike days.
                                           ACCLIMATED

-------
CERCLA PILOT STUDY
       109

-------
TOTAL SUSPENDED SOLIDS (mg/L) - ACCLIMATED SYSTEM
DATE
(DD-MM)
01-Jun
02-Jun
03-Jun
04-Jun
OS-Jun
06-Jun
07-Jun
08-Jun
09-Jun
10-Jun
11-Jun
12-Jun
13-Jun
U-Jun
15-Jun
16-Jun
17-Jun
18-Jun
19-Jun
20-Jun
21-Jun
22-Jun
23-Jun
24-Jin
25-Jun
26-Jun
27-Jun
28- Jin
29-Jun
30-Jun
PR I
INF
272
352
352
278
312
364
200
336
408



287
483
166
390
452
312

420
443
322
427
352
338
341
312

285
382
PR I
EFF
80
68
68
106
80
124
44
100
112



95
243
74
220
140
108

108
95
68
107
140
94
61
100

89
58
SEC
EFF
1
15
15
4
9
8
4
6
8



12
8
7
18
12
4

8
8
6
10
11
12
12
16

15
8
MIX
LIQ
4130
3390
3390
3180
2980
2840

5380
3010



2099
3463
2012
3580
3328
2900

3510
2803
3132
3325
3030
3122
1531
2040

2945
1722
SEC
WAS
10450
13040
13040
6250
11340
11670
5500

11270



11199
11483
12162
11160
10950
11480

11650
11733
10972
11265
8810
8122
10601
11220

10565
10252
«•
PR I
SLU f
2.6
2.7
2.7
2.0
1.3
2.2
1.2

1.5



3.5
2.7
2.9

4.0
2.8

2.2
3.6
3.7
3.6
2.8
3.3
2.2
2.5

3.3
3.7
X
iemov
100
96
96
99
97
98
98
98
98



96
98
96
95
97
99

98
98
98
98
97
96
96
95

95
98
* Percent Total  Solids
                 110

-------
TOTAL SUSPENDED SOLIDS (mg/L) -  ACCLIMATED SYSTEM
DATE
(DD-MM)
01-Jul
02-Jul
03-Jul
04-Jul
05-Jul
06-Jul
07-Jul
08-Jul
09-Jul
10-Jul
11-Jul
12-Jul
13-Jul
14-Jul
15-Jul
16- Jut
17-Jul
18-Jul
19-Jul
20-Jul
21-Jul
22-Jul
23-Jul
24- Jut
25-Jul
26-Jul
27-Jul
28-Jul
29-Jul
30-Jul
31-Jul
PR I
INF
255
287
355
216
268
326
360
438
263
296
278
285
452
116
183
236
207
273
352
304
216
247
236
348
318
487
241
226
303
217
195
PR I
EFF
107
99
75
84
84
74
90
94
91
104
62
113
152
112
75
108
81
101
108
124
76
139
100
104
114
127
125
130
127
181
147
SEC
EFF
8
12
6
7
13
7
10
8
10
10
4
11
16
20
8
11
14
12
14
11
9
9
16
17
4
14
32
17
13
10
12
MIX
LIQ
3059
2873
2689
2770
2700
2392
3520
2742
3053
2830
2838
3281
1734
2230
3123
2960
3221

3120
2780
2880
2779
3344
2960
3462
4339
2751
3742
2129
2821
2875
SEC
WAS
9899
9823
9409
9160
8580
8952
9760
10742
11463
10160
14178
10701
5764
10670
10073
9520
9981
11481
7080
9540
10020
9979
9664
9200

10999
11121
11882
9589
9761
9695
*
PR I
SLU R

3.1

2.7
3.0
0.9
2.0
3.0
1.4
2.3
1.7
2.8
6.0
2.5
1.3
3.2
3.3



3.1
2.5
2.6
2.4
3.3
2.2

3.2
1.2
2.3
1.7
X
emov
97
96
98
97
95
98
97
98
96
97
99
96
96
83
96
95
93
96
96
96
96
96
93
95
99
97
87
92
96
95
94
 *  Percent Total  Solids
                  111

-------
TOTAL SUSPENDED SOLIDS (mg/L) - ACCLIMATED SYSTEM
DATE
(DD-MM)
01-Aug
02-Aug
03-Aug
04-Aug
05-Aug
06-Aug
07-Aug
08-Aug
09-Aug
10-Aug
11-Aug
12-Aug
13-Aug
14-Aug
15-Aug
16-Aug
17-Aug
18-Aug
19-Aug
20-Aug
21-Aug
22-Aug
23-Aug
24-Aug
25-Aug
26-Aug
27-Aug
28-Aug
29-Aug
30-Aug
31-Aug
AVERAGE
DEVIATION
PR I
INF
195
212
340
290
292
262
325
266
260
209
226
252
140
192
268
184
176
208
212
160
212
228
308
212
228
228
308
184
256


285
81
PR I
EFF
147
88
108
126
128
78
125
162
92
165
98
132
96
104
156
100
92
124
104
80
112
120
124
104
168
108
128
76
152


109
33
SEC
EFF
12
13
13
11
14
15
16
10
11
12
12
18
7
15
14
35
13
11
10
12
15
21
20
13
17
12
15
10
6


12
5
MIX
LIQ
2875
2380
2780
3418
3530
2962
2881
2772
2880
2571
3458
2490
2880
2764
4340
2820
3960
3630
3430
2510
2720
2900
2550
3030
2400
2720
3160
2550
2510


2972
585
SEC
WAS
9695
8880
9440
9298
9850
9322
9161
8502
10640
9361
9098
8180
10570
9924
12660
11560
11660
11060
10090
8720
8950
11100
9170
12940
9910

11720
11320
9080


10152
1584
PR I
SLU
2.7
0.8
1.5
2.6
2.9
0.5
2.6
2.9
1.8
2.9
2.2
6.1
6.6
3.2
1.7
3.2
2.9
2.9
1.7
2.1
2.3
2.6
0.7
1.3
1.0
1.6





2.6
1.1
X
Remov
94
94
96
96
95
94
95
96
96
94
95
93
95
92
95
81
93
95
95
92
93
91
94
94
93
95
95
95
98


95
3
*  Percent Total Solids
                 112

-------
COO/SCOT DATA - ACCLIMATED SYSTEM
Date
(MM-DD)
01-Jun
02-Jun
03-Jun
04-Jun
05-Jun
06-Jun
07-Jun
08-Jun
09-Jun
10-Jun
11-Jun
12-Jun
13-Jun
14-Jun
15-Jun
16-Jun
17-Jun
18-Jun
19-Jun
20-Jun
21-Jun
22-Jun
23-Jun
24-Jun
25-Jun
26-Jun
27-Jun
28-Jun
29-Jun
30-Jun
TOTAL
PRI PR!
INF EFF
mg/L mg/L

394 535


742 537

802 584

782 647


905 536

745 547

594 645


677 461

711 386

765 375


461 605

696 492

COO | SOLUBLE COD
1
SEC X | PRI PRI SEC X
EFF Removj INF EFF EFF Remov
mg/L |mg/L mg/L mg/L

121 69


114 85



134 83


75 92

80 89

100 83


88 87

73 90

80 90


89 81

85 88


326 327


307 290

326 343

337 369


198 211

322 217

270 259


326 303

300 284

386 390


253 233

273 291


113 65


54 82



76 77


44 78

69 79

72 73


65 80

78 74

106 73


70 72

76 72

           113

-------
COO/SCOO  DATA  - ACCLIMATED SYSTEM
Date
(MM-DD)
01-Jul
02-Jul
03-Jul
04-Jul
05-Jul
06-Jul
07-Jul
08-Jul
09-Jul
10-Jul
11-Jul
12-Jul
13-Jul
14-Jul
15-Jul
16-Jul
17-Jul
18-Jul
19-Jul
20-Jul
21-Jul
22-Jul
23-Jul
24-Jul
25-Jul
26-Jul
27-Jul
28-Jul
29-Jul
30- Jut
31-Jul
PR I
INF
mg/L
702


486

770

769


471

659

547


692

350

774


805

814

585


TOTAL
PRI
EFF
mg/L
469


346

596

634


364

385

480


361

210

543


462

532

402


COO
SEC
EFF
mg/L
90


70

96

87


50

58

52


89

55

72


94

90

61


% | PRI
Removj INF
I mg/L
87


86

88

89


89

91

91


87

84

91


88

89

90


266


133

320

308


173

327

327


231

121

276


335

264

283


SOLUBLE COO
PRI SEC %
EFF EFF Remov
mg/L mg/L
274


81

337

314


177

379

317


180

129

270


314

283

276


76


47

75

76


43

61

78


73

51

51


72

68

64


71


65

77

75


75

81

76


68

58

82


79

74

77


            114

-------
COO/SCOO  DATA  - ACCLIMATED SYSTEM

Date

(MM-DD)

01-Aug
02-Aug
03-Aug
04-Aug
05-Aug
06-Aug
07-Aug
08-Aug
09-Aug
10-Aug
11-Aug
12-Aug
13-Aug
14-Aug
15-Aug
16-Aug
17-Aug
18-Aug
19-Aug
20-Aug
21-Aug
22-Aug
23-Aug
24-Aug
25-Aug
26-Aug
27-Aug
28-Aug
29-Aug
30-Aug
31-Aufl
AVERAGE
DEVIATION


PR I
INF
mg/L
576

907

506


695

742

575


600

557

569


591

975

836


999

720
681
149
TOTAL

PR I
EFF
mg/L
404

463

525


756

579

424


478

438




410

454

509


742

493
495
110
COD

SEC
EFF
mg/L
74

62

67


66

77

69


68

60

85


72

84

92


78

69
80
18
SOLUBLE COD

X | PRI
Remov) INF

87

93

87


91

90

88


89

89

85


88

91

89


92

90
88
4
mg/L
273

312

255


299

329

285


278

300

269




276

465


202

315
285
62

PRI
EFF
mg/L
225

283

285


311

289

305


284

286

251




368

379


165

283
278
68

SEC
EFF
mg/L
40

60

51


47

68

56


52

60

63




69

72


46

65
65
15

X
Remov

85

81

80


84

79

80


81

80

77




75

85


77

79
76
6
             115

-------
NITROGEN  DATA  (mg/L) - ACCLIMATED SYSTEM
Date
(DD-MH)
01-Jun
02-Jun
03-Jun
04-Jun
05-Jun
06-Jun
07-Jun
08-Jun
09-Jun
10-Jun
11-Jun
12-Jun
13-Jun
PR I
INF
mg/L

25


32



21


27
14-Jun
15-Jun
16-Jun
17-Jun
18-Jun
19-Jun
20-Jun
21-Jun
22-Jun
23-Jun
24-Jun
25-Jun
26-Jun
27-Jun
28-Jun
29-Jun
30-Jun
33

23


25

40

36


31

31

AMMONIA
PR I
EFF
mg/L

30


29



22


28

32

24


30

35

36


30

24

-N
SEC X
EFF Remov
mg/L

0.6 98


3.6 89



0.5 97


4.4 84

11.9 64

0.6 98


14.3 42

6.8 83

5.1 86


1.9 94

0.7 98

NITRATE-N
PRI PRI
INF EFF
mg/L rog/L

0.00


0.29



0.21


0.24

0.12

0.00


0.00

0.22

0.18


0.23

0.28


0.00


0.61



0.23


0.19

0.09

0.00


0.00

0.17

0.17


0.24

0.24

SEC
EFF
mg/L

22


11



6


6

5

10


8

12

16


20

17

            116

-------
NITROGEN  DATA  (mg/L) - ACCLIMATED  SYSTEM
Date
(DD-MM)
01-Jul
02-Jul
03-Jul
04-Jul
05-Jul
06-Jul
07-Jul
08-Jul
09-Jul
10-Jul
11-Jul
12-Jul
13-Jul
14-Jul
15-Jul
16-Jul
17-Jul
18-Jul
19-Jul
20-Jul
21-Jul
22-Jul
23-Jut
24-Jul
25-Jul
26-Jul
27-Jul
28-Jul
29-Jul
30-Jul
31-Jul
PR I
INF
mg/L
18


13

30

22


32

40

25


23

9

27


40

48

28


AMMONIA-N
PR I SEC X
EFF EFF Remov
mg/L mg/L
21


14

27

22


31

38

26


19

9

28


41

40

27


0.5 97


1.9 85

5.8 81

9.7 55


9.5 70

11.3 72

1.3 95


0.7 97

0.3 96

6.0 78


10.0 75

11.2 76

0.4 98


NITRATE-N
PRI PRI
INF EFF
mg/L mg/L
0.21


0.10

0.22

0.21


0.11

0.21

0.10


0.10

0.00

0.00


0.10

0.09

0.00


0.14


0.96

0.23

0.22


0.11

0.18

0.09


0.00

0.00

0.11


0.10

0.00

0.00


SEC
EFF
mg/L
12


14

6

4


11

9

11


15

10

5


22

9

11


            117

-------
NITROGEN DATA  (mg/L) - ACCLIMATED SYSTEM

Date

CDD-MM)

01-Aug
02-Aug
03-Aug
04-Aug
05-Aug
06-Aug
07-Aug
08-Aug
09-Aug
10-Aug
11-Agg
12-Aug
13-Aug
14-Aug
15-Aug
16-Aug
17-Aug
18-Aug
19-Aug
20-Aug
21-Aug
22-Aug
23-Aua
24-Aug
25-Aug
26-Aug
27-Aug
28-Aug
29-Aug
30-Aug
31-Aug
AVERAGE
DEVIATION


PR I
INF
mg/L
28

35

24


25

33

25


23

26

30


28

26







28
8
AMMONIA-N

PR I
EFF
mg/L
29

33

25


33

30

25


24

27




28

28







28
7

SEC X
EFF Remov
mg/L
1.6 94

1.4 96

1.1 95


0.6 98

0.6 98

1.5 94


0.6 98

0.5 98

0.6 98


1.8 93

1.1 96







3.7 88
4.1 14
NITRATE-N

PR I
INF
mg/L
0.09

0.11

0.00


0.10

0.11

0.10


0.00

0.11

0.00




0.10







0.12
0.09

PR I
EFF
mg/L
0.00

0.00

0.00


0.10

0.00

0.00


0.11

0.00






0.30







0.14
0.19

SEC
EFF
mg/L
23

19

15


22

15

12


20

17

15




17







13
5
              118

-------
TOTAL SUSPENDED SOLIDS (mg/L) - UNACCLIHATED SYSTEM
DATE
CMM-DD)
01-Jun
02-Jun
03-Jun
04-Jun
05-Jun
06-Jun
07-Jun
08-Jun
09-Jun
10-Jun
11-Jun
12-Jun
13-Jun
14-Jun
15-Jun
16-Jun
17-Jun
18-Jun
19-Jun
20-Jun
21-Jun
22-Jun
23-Jun
24- Jim
25-Jun
26-Jun
27-Jun
28-Jun
29-Jun
30-Jun
PR I
INF
196
344

316
276
428
260
316
272


642
223
440
241
530
336
269

437
392
286
662
371

414
347
401
279
334
PR I
EFF
108
72

96
52
68
52
112
116


86
79
120
105
60
188
53

109
80
64
118
131

50
177
121
83
94
SEC
EFF
19
4

8
9
6
5
7
12


12
11
9
15
13
24
22

17
13
12
9
12

8
9
11
10
4
NIX
LIQ
3900
5520

3830
3740
2820

4030
4240


4182
3429
4240
4849
5660
5070
3471

4221
4394
4082
4012
3599


3417
1985
1959
1012
SEC
WAS
10020
10710

9290
10820
11590
9920
13790
10860


11062
11229
9900
12589
11620
11080
10881

10881
10514
11102
10712
11449

10082
9237
10365
10279
11632
P
S
2
2

1
2
2
1

1


2
2
2
2

3


2
2
2
2
2

2
2
2
3
1
•X
RI
LU
.4
.0

.6
.2
.2
.5

.9


.6
.6
.1
.4

.0


.3
.8
.0
.6
.5

.6
.7
.9
.6
.9
X
Reroov
90
99

97
97
99
98
98
96


98
95
98
94
98
93
92

96
97
96
99
97

98
97
97
96
99
   * Percent  Total  Solids
                    119

-------
TOTAL SUSPENDED SOLIDS (mg/L) - UNACCLIHATED SYSTEM
DATE
(MM-DD)
01-Jul
02-Jut
03-Jul
04-Jul
05-Jul
06-Jul
07- Jut
08- Jut
09-Jul
10-Jut
11-Jul
12-Jul
13-Jul
14-Jul
15-Jul
16-Jul
17-Jul
18-Jul
19-Jul
20-Jul
21-Jul
22-Jul
23-Jul
24-Jul
25-Jul
26-Jul
27-Jul
28-Jul
29-Jul
30-Jut
31-Jul
PR I
INF
329
263
392
234
272
224
243
322
295
325
300
293
332
258
197
288
193
199
305
256
132
254
248
253
338
294
224
259
296
310
223
PR I
EFF
109
71
132
78
164
112
143
110
103
93
140
113
144
126
91
112
49
107
93
92
80
130
68
61
106
118
100
91
104
210
119
SEC
EFF
4
6
7
7
9
6
12
8
3

13
10
12
21
11
9
6
10
10
8
5
9
10
17
21

65
102
60
12
10
MIX
LIO
3621
3483
3600
3362
3540
3730
2537
4032
3899

3940
3941
3460
3258
2933
3530
4081
4263
3501
3680
3740
3472
3200
4921
3182
3098
4100
2919
3350
3538
3305
SEC
WAS
11571
12053
11520
11762
14040
11980
6647
13392
13979
11577
9640
11341
10480
7788
12563
12520
11501
9783
11301
11760
11940
11942
11780
9361

6798
9080

10480
11398
9975
PR I
SLU f

4.3

6.0
8.1
0.7
5.3
7.8
3.2
8.6
6.7
3.6
2.5
5.2
0.8
4.4
3.1



4.7
4.9
3.2
4.0
3.5
7.7

3.6
1.5
2.7
2.8
X
iemov
99
98
98
97
97
97
95
98
99

96
97
96
92
94
97
97
95
97
97
96
96
96
93
94

71
61
80
96
96
  *  Percent Total Solids
                    120

-------
TOTAL SUSPENDED SOLIDS (mg/L) - UNACCLIMATED SYSTEM
DATE
(MM-DD)
01-Aug
02-Aug
03-Aug
04-Aug
05-Aug
06-Aug
07-Aug
08-Aug
09-Aug
10-Aug
11-Aug
12-Aug
13-Aug
14-Aug
15-Aug
16-Aug
17-Aug
18-Aug
19-Aug
20-Aug
21-Aug
22-Aug
23-Aug
24-Aug
25-Aug
26-Aug
27-Aug
28-Aug
29-Aug
30-Aug
31-Aug
AVERAGE
DEVIATION
PR I
INF
252
253
292
276
262
323
307
271
242
205
254
272
184
76
182
216
184
296
76

236
268
292
228
240
236
252
200



286
93
PR I
EFF
112
105
132
128
142
75
167
227
134
133
86
140
72
68
122
76
84
124
64

88
100
104
108
96
100
104
76



105
34
SEC
EFF
11
8
10
32
38
7
8
11
10
8
6
14
6
15
12
7
13
11
12

20
19
6
13
59
10
13
9



14
15
MIX
LIQ
5660
4211
4040
4670
3468
3183
3219
3363
3422
4171
5418
2360
3820
4034
4742
3550
3650
5410
5090

4580
4660
3670
6150
5720
5290
5670
6230



3891
992
SEC
WAS


13940
9080
8858
10103
9819
9963
12802
11621
11238
12230
11940
12964
15682
13680
9300
17280
15510

12760
13900
12040
16440
20930
13040
14040
16220



11607
2226
P
S
2
3
1
3
3
3
3
3
1
4
2
6
8
8
6
5
6
3
3

3
2
1
3
0
3





3
2
*
RI
LU
.3
.3
.5
.1
.5
.0
.1
.5
.7
.0
.1
.2
.8
.7
.8
.8
.9
.9
.7

.7
.4
.0
.0
.4
.5





.6
.0
X
Remov
96
97
97
88
85
98
97
96
96
96
98
95
97
80
93
97
93
96
84

92
93
98
94
75
96
95
95



94
6
   * Percent  Total  Solids
                    121

-------
COO/SCOO  DATA  - UNACCLlMATED SYSTEM
Date
(MM-DD)
01-Jun
02-Jun
03-Jun
04-Jun
05-Jun
06-Jun
07-Jun
08-Jun
09-Jun
10-Jun
11-Jun
12-Jun
13-Jun
14-Jun
15-Jun
16-Jun
17-Jun
18-Jun
19-Jun
20-Jun
21-Jun
22-Jun
23-Jun
24-Jun
25-Jun
26-Jun
27-Jun
28-Jun
29-Jun
30-Jun
PR I
INF
mg/L


381


767

780

950


859

730

415


751

641

741


566

629

TOTAL
PRI
EFF
mg/L


495


456

548

799


424

532

452


462

358

395


395

449

COO
SEC
EFF
mg/L


107


97

83

79


57

86

291


73

64

83


72

80

X
Remov


72


87

89

92


93

88

30


90

90

89


87

87

PRI
INF
mg/L


309


307

351

319


304



149


323

241

401


290

268

SOLUBLE
PRI SEC
EFF EFF
mg/L mg/L


302


245

286

325


165



260


296

268

327


215

263



114


71

51

61


96



104


56

68

87


60

66

COO
X
Remov


63


77

85

81


68



30


83

72

78


79

75

            122

-------
COD/SCOD  DATA - UNACCLIMATED SYSTEM
Date
(MM-DD)
01-Jul
02-Jul
03-Jul
04-Jut
05-Jul
06-Jul
07-Jul
08-Jul
09-Jul
10-Jul
11-Jul
12-Jul
13-Jul
14-Jul
15-Jul
16-Jul
17-Jul
18-Jul
19-Jul
20-Jul
21-Jul
22-Jul
23-Jul
24-Jul
25-Jul
26-Jul
27-Jul
28-Jul
29-Jul
30-Jul
31-Jul
PR I
INF
mg/L
679


766

824

675


520

442

579


526

310

680


769

728

532


TOTAL
PR I
EFF
mg/L
482


295

601

551


370

384

480


419

258

536


462

502

415


COD
SEC
EFF
mg/L
79


46

68

71


37

47

45


55

55

60


70

180

95


x |PRI
Remov|INF
I mg/L
88


94

92

89


93

89

92


90

82

91


91

75

82


230


123

292

216


124

330

309


180

118

240


294

303

253


SOLUBLE COD
PRI SEC X
EFF EFF Remov
mg/L mg/L
261


84

340

259


166

363

303


176

119

267


271

260

250


61


31

67

52


35

52

65


48

37

85


56

50

49


73


75

77

76


72

84

79


73

69

65


81

83

81


            123

-------
COO/SCOO  DATA - UNACCLIMATED SYSTEM
1
Date |
| PR!
(MM-DD) | INF
|mg/L
1
01-Aug | 533
02-Aug |
03-Aug 620
04-Aug
05-Aug 646
06-Aug
07-Aug
08-Aug
09-Aug
10-Aug
11-Aug
12-Aug
13-Aug
14-Aug
15-Aug
16-Aug
17-Aug
18-Aug
19-Aug
20-Aug
21-Aug
22-Aug
23-Aug
24-Aug
25-Aug
26-Aug
27-Aug
28-Aug
29-Aug
30-Aug
31-Aug
AVERAGE
DEVIATION


804

662

509


551

498

446


589

679

702


517

896
638
144
TOTAL

PR I
EFF
mg/L

381

444

482


585

556

416


462

448

384


408

493

492


384

692
465
98
COD

SEC
EFF
mg/L

63

56

77


56

59

62


51

67

59


86

83

59


72

80
77
42
SOLUBLE COD
I
X PRI
RemovjINF
I mg/L

88 237

91 247

88 329


93 255

91 299

88 226


91

87

87


85

88

92


86

91
87
10


272

250

227




234

369


182

246
256
78

PRI
EFF
mg/L

218

242

264


274

268

238


264

285

225




261

397


160

252
249
71

SEC
EFF
mg/L

43

46

51


39

57

69


45

53

53




62

70


37

93
64
21

X
Remov)


82

81

84


85

81

69


83

79

77




74

81


80

62
74
11
             124

-------
NITROGEN  DATA (mg/L) - UNACCLIHATED  SYSTEM
Date
(DD-HM)
01-Jun
02-Jun
03-Jun
04-Jun
05-Jun
06-Jun
07-Jun
08-Jun
09-Jun
10-Jun
11-Jun
12-Jun
13-Jun
14-Jun
15-Jun
16-Jun
17-Jun
18-Jun
19-Jun
20-Jun
21-Jun
22-Jun
23-Jun
24-Jun
25-Jun
26-Jun
27-Jun
28-Jun
29-Jun
30-Jun
AMHONIA-N
PRI PRI SEC X
INF EFF EFF Remov
mg/L mg/L mg/L

27 30


33 31

37 34

21 22


27 27

32 32




27 32

37 34

37 36


28 32

32 23


0.5 98


0.4 99

1.4 96

0.5 98


0.3 99

0.3 99




0.3 99

0.4 99

0.3 99


0.6 98

0.3 99

NITRATE-N
PRI PRI SEC
INF EFF EFF
mg/L mg/L mg/L

0.00 0.00


0.29 0.18

0.30 0.27

0.28 0.22


0.23 0.19

0.12 0.00

5.76 0.00


0.13 0.00

0.21 0.17

0.19 0.17


0.25 0.24

0.29 0.23


27


22

20

13


19

19

9


25

31

31


35

17

               125

-------
NITROGEN DATA  (mg/L) - UNACCLIMATED SYSTEM
Date
(DD-MM)
01-Jul
02-Jul
03-Jul
04-Jul
05-Jul
06-Jul
07-Jul
08- Jut
09-Jul
10-Jul
11-Jul
12-Jul
13-Jul
14-Jul
15-Jul
16-Jul
17-Jul
18-Jul
19-Jul
20-Jul
21-Jul
22-Jul
23-Jul
24-Jul
25-Jul
26-Jul
27-Jul
28-Jul
29-Jul
30-Jul
31-Jul
PR I
INF
mg/L
19


14

30

21


29

42

25


25

9

28


40

47

27


AMHONIA-N
PR I SEC
EFF EFF
mg/L mg/L
20


12

28

22


32

36

25


23

9

28


39

40

27


0.2


0.5

0.6

0.5


0.4

0.6

0.3


0.3

0.1

4.9


0.8

0.6

0.4


X
Remov
99


97

98

97


99

99

99


99

98

82


98

99

99


NITRATE-N
PRI PRI SEC
INF EFF EFF
mg/L mg/L mg/L
0.16


0.16

0.26

0.21


0.16

0.18

0.16


0.00

0.10

0.10


0.15

0.11

0.09


0.14


0.09

0.24

0.19


0.12

0.14

0.11


0.00

0.00

0.00


0.00

0.00

0.10


14


17

14

13


22

20

16


16

10

6


27

19

11


                126

-------
NITROGEN DATA  (mg/L) - UNACCLIMATED  SYSTEM

Date

(DD-MH)

01-Aug
02-Aug
03-Aug
04-Aug
05-Aug
06-Aug
07-Aug
08-Aug
09-Aug
10-Aug
11-Aug
12-Aug
13-Aug
14-Aug
15-Aug
16-Aug
17-Aug
18-Aug
19-Aug
20-Aug
21-Aug
22-Aug
23-Aug
24-Aug
25-Aug
26-Aug
27-Aua
28-Aug
29-Aug
30-Aug
31-Aug
AVERAGE
DEVIATION
AHMONIA-N

PRI PRI SEC X
INF EFF EFF Remov
mg/L mg/L mg/L
28 29 0.5 98

33 33 0.6 98




29 31 0.5 98

32 31 0.7 98

24 23 0.6 97


22 25 0.5 98

25 27 0.5 98

29 30 0.4 99




25 28 0.4 98







28 28 0.6 98
7 6 0.8 3
NITRATE-N

PRI PRI SEC
INF EFF EFF
mg/L mg/L mg/L
0.17 0.10 24

0.18 0.11 20

0.00 0.00 17


0.13 0.12 26

0.14 0.00 22

0.00 0.00 20


0.10 0.10 26

0.14 0.00 14

0.10 0.00 19




0.11 0.00 20







0.31 0.09 19
0.94 0.09 6
               127

-------
ro
00
       I
       a
       8
             EFFECT OF  CERCLA  TOXICS ON COD  REMOVAL
            100
                     •   UNACCLIMATED

                Arrows Indicate Intermittent tplke days.
                              ill ill j-t n TTi-riT|'T»tTT f rrryi ri i t i i i i-| i-ri riTrr«-|Tt i i i rrri p i n i m-r|-i

                                 31     41     51


                                     TIME (days)
     61     71



+  ACCLIMATED
61
91

-------
           EFFECT  OF  CERCLA TOXICS ON  NITRIFICATION

             100 -p*-*--A-^Ff.

             90 -, V

             80 -i
       d    60 -
       i        !
K      3    50 J
vo      tc.
             30 -J
                 I

             20 -j
                 !
                 i
             10
                                        TIME (days)
                       •   ACCLIMATED            +   UNACCLJMATED
                Arrows indicate intermittent spike days.
              0 •'j i i i rr r?-rrp-rrl n T-rrjTT'm rt 11 11 11 i i i i i i | i i ITT-I i I i | rr ri ~t rri-ryrr-r i rii rrj i rrrrt rr-»-|T-rr n tt-rrp
                1     11      21     31     41     51     61     71     81     91

-------
TOTAL SUSPENDED SOLIDS 
-------
TOTAL SUSPENDED SOLIDS (mg/L) - UNACCLlHATED SYSTEH

DATE
(MM-DD)
01-Aug
02-Aug
03-Aug
04-Aug
05-Aug
06-Aug
07-Aug
08-Aug
09-Aug
10-Aug
11-Aug
12-Aug
13-Aug
14-Aug
15-Aug
16-Aug
17-Aug
18-Aug
19-Aug
20-Aug
21-Aug
22-Aug
23-AU9
24-Aug
25-Aug
26-Aug
27-Aug
28-Aug
29-Aug
30-Aug
31-Aug
AVERAGE
DEVIATION

PR I
INF
252
253
292
276
262
323
307
271
242
205
254
272
184
76
182
216
184
296
76

236
268
292
228
240
236
252
200



286
93

PR I
EFF
112
105
132
128
142
75
167
227
134
133
86
140
72
68
122
76
84
124
64

88
100
104
108
96
100
104
76



105
34

SEC
EFF
11
8
10
32
38
7
8
11
10
8
6
14
6
15
12
7
13
11
12

20
19
6
13
59
10
13
9



14
15

MIX
LIO
5660
4211
4040
4670
3468
3183
3219
3363
3422
4171
5418
2360
3820
4034
4742
3550
3650
5410
5090

4580
4660
3670
6150
5720
5290
5670
6230



3891
992

SEC
WAS


13940
9080
8858
10103
9819
9963
12802
11621
11238
12230
11940
12964
15682
13680
9300
17280
15510

12760
13900
12040
16440
20930
13040
14040
16220



11607
2226

P
S
2
3
1
3
3
3
3
3
1
4
2
6
8
8
6
5
6
3
3

3
2
1
3
0
3





3
2
fc
RI
LU
.3
.3
.5
.1
.5
.0
.1
.5
.7
.0
.1
.2
.8
.7
.8
.8
.9
.9
.7

.7
.4
.0
.0
.4
.5





.6
.0

X
Remov
96
97
97
88
85
98
97
96
96
96
98
95
97
80
93
97
93
96
84

92
93
98
94
75
96
95
95



94
6
   *  Percent Total  Solids
                    131

-------
COO/SCOO DATA - UNACCLIMATED SYSTEM
Date
(MM-DD)
01-Jun
02-Jun
03-Jun
04-Jun
05-Jun
06-Jun
07-Jun
08-Jun
09-Jun
10-Jun
11-Jun
12-Jun
13-Jun
14-Jun
15-Jun
16-Jun
17-Jun
18-Jun
19-Jun
20-Jun
21-Jun
22-Jun
23-Jun
24-Jun
25-Jun
26-Jun
27-Jun
28-Jun
29-Jun
30-Jun
TOTAL COD
PRI PRI SEC %
INF EFF EFF Remov
mg/L mg/L mg/L


381 495 107 72


767 456 97 87

780 548 83 89

950 799 79 92


859 424 57 93

730 532 86 88

415 452 291 30


751 462 73 90

641 358 64 90

741 395 83 89


566 395 72 87

629 449 80 87

SOLUBLE COD
PRI PRI SEC %
INF EFF EFF Remov
mg/L mg/L mg/L


309 302 114 63


307 245 71 77

351 286 51 85

319 325 61 81


304 165 96 68



149 260 104 30


323 296 56 83

241 268 68 72

401 327 87 78


290 215 60 79

268 263 66 75

            132

-------
COO/SCOO  DATA - UNACCLIMATED SYSTEM
Date
(MM-DD)
01-Jul
02-Jul
03-Jul
04-Jul
05-Jul
06-Jul
07-Jul
08-Jul
09-Jul
10-Jul
11-Jul
12-Jul
13-Jul
U-Jul
15-Jul
16-Jul
17-Jul
18-Jul
19- Jut
20-Jul
21-Jul
22-Jul
23-Jul
24-Jul
25-Jul
26-Jul
27-Jul
28-Jul
29-Jul
30- Jut
31-Jul
PR!
INF
mg/L
679


766

824

675


520

442

579


526

310

680


769

728

532


TOTAL COD
PR! SEC
EFF EFF
mg/L mg/L
482


295

601

551


370

384

480


419

258

536


462

502

415


79


46

68

71


37

47

45


55

55

60


70

180

95


% |PRI
Remov | INF
| mg/L
88


94

92

89


93

89

92


90

82

91


91

75

82


230


123

292

216


124

330

309


180

118

240


294

303

253


SOLUBLE
PR I SEC
EFF EFF
mg/L mg/L
261


84

340

259


166

363

303


176

119

267


271

260

250


61


31

67

52


35

52

65


48

37

85


56

50

49


COD
%
Remov
73


75

77

76


72

84

79


73

69

65


81

83

81


          133

-------
.  COD/SCOD DATA - UNACCLIMATED SYSTEM

Date

(MM-DD)

01-Aug
02-Aug
03-Aug
04-Aug
05-Aug
06-Aug
07-Aug
08-Aug
09-Aug
10-Aug
11-Aug
12-Aug
13-Aug
14-Aug
15-Aug
16-Aug
17-Aug
18-Aug
19-Aug
20-Aug
21-Aug
22-Aug
23-Aug
24-Aug
25-Aug
26-Aug
27-Aug
28-Aug
29-Aug
30-Aug
31-Aug
AVERAGE
DEVIATION
TOTAL COO |

PR I
INF
mg/L
533

620

646


804

662

509


551

498

446


589

679

702


517

896
638
144

PR I
EFF
mg/L
381

444

482


585

556

416


462

448

384


408

493

492


384

692
465
98

SEC
EFF
mg/L
63

56

77


56

59

62


51

67

59


86

83

59


72

80
77
42

x |PRI
RemovjINF

88

91

88


93

91

88


91

87

87


85

88

92


86

91
87
10
mg/L
237

247

329


255

299

226


272

250

227




234

369


182

246
256
78
SOLUBLE

PR I
EFF
mg/L
218

242

264


274

268

238


264

285

225




261

397


160

252
249
71

SEC
EFF
mg/L
43

46

51


39

57

69


45

53

53




62

70


37

93
64
21
COO

%
Remov

82

81

84


85

81

69


83

79

77




74

81


80

62
74
11
              134

-------
NITROGEN  DATA  (mg/L) - UNACCLIMATED  SYSTEM
Date
(DD-MH)
01-Jun
02-Jun
03-Jun
04-Jun
05-Jun
06-Jun
07-Jun
08-Jun
09-Jun
10-Jun
11-Jun
12-Jun
13-Jun
U-Jun
15-Jun
16-Jun
17-Jun
18-Jun
19-Jun
20-Jun
21-Jun
22-Jun
23-Jun
24-Jun
AMHONIA-N
PRI PRI SEC X
INF EFF EFF Remov
mg/L mg/L mg/L

27 30


33 31

37 34

21 22


27 27

32 32




27 32

37 34

37 36
25-Jun |
26-Jun
27-Jun 28 32
28-Jun |
29-Jun
30-Jun
32 23


0.5 98


0.4 99

1.4 96

0.5 98


0.3 99

0.3 99




0.3 99

0.4 99

0.3 99


0.6 98

0.3 99

NITRATE-N
PRI PRI
INF EFF
mg/L mg/L

0.00 0.00


0.29 0.18

0.30 0.27

0.28 0.22


0.23 0.19

0.12 0.00

5.76 0.00


0.13 0.00

0.21 0.17

0.19 0.17


0.25 0.24

0.29 0.23

SEC
EFF
mg/L

27


22

20

13


19

19

9


25

31

31


35

17

                135

-------
NITROGEN DATA  (mg/L) - UNACCLIMATED SYSTEM
Date
(DD-MM)
01-Jul
02-Jul
03-Jul
04-Jul
05-Jut
06-Jul
07-Jul
08-Jul
09-Jul
10-Jul
11-Jul
12-Jul
13-Jul
14-Jul
15-Jul
16-Jul
17-Jul
18-JuL
PR I
INF
mg/L
19


14

30

21


29

42

25


25
19-Jul
20-Jul 9
21-Jul
22-Jul 28
23-Jul
24-Jul
25-Jul 40
26-Jul
27-Jul 47
28-Jul
29- Jut 27
30-Jul
31-Jul
AMMONIA-N
PR I SEC
EFF EFF
mg/L mg/L
20


12

28

22


32

36

25


23

9

28


39

40

27


0.2


0.5

0.6

0.5


0.4

0.6

0.3


0.3

0.1

4.9


0.8

0.6

0.4


%
Remov
99


97

98

97


99

99

99


99

98

82


98

99

99


NITRATE-N
PRI PRI
INF EFF
mg/L mg/L
0.16


0.16

0.26

0.21


0.16

0.18

0.16


0.00

0.10

0.10


0.15

0.11

0.09


0.14


0.09

0.24

0.19


0.12

0.14

0.11


0.00

0.00

0.00


0.00

0.00

0.10


SEC
EFF
mg/L
14


17

14

13


22

20

16


16

10

6


27

19

11


               136

-------
NITROGEN  DATA  (mg/L) - UNACCLIMATED SYSTEM

Date

(DD-MM)

01-Aug
02-Aug
03-Aug
04-Aug
05-Aug
06-Aug
07-Aug
08-Aug
09-Aug
10-Aug
11-Aug
12-Aug
13-Aug
14-Aug
15-Aug
16-Aug
17-Aug
18-Aug
19-Aug
20-Aug
21-Aug
22-Aug
23-Aug
24-Aug
25-Aug
26-Aug
27-Aug
28-Aug
29-Aug
30-Aug
31-Aua
AVERAGE
DEVIATION
AMMONIA-N

PRI PRI SEC X
INF EFF EFF Remov
mg/L mg/L mg/L
28 29 0.5 98

33 33 0.6 98




29 31 0.5 98

32 31 0.7 98

24 23 0.6 97


22 25 0.5 98

25 27 0.5 98

29 30 0.4 99




25 28 0.4 98







28 28 0.6 98
7 6 0.8 3
NITRATE-N

PRI PRI SEC
INF EFF EFF
mg/L mg/L mg/L
0.17 0.10 24

0.18 0.11 20

0.00 0.00 17


0.13 0.12 26

0.14 0.00 22

0.00 0.00 20


0.10 0.10 26

0.14 0.00 14

0.10 0.00 19




0.11 0.00 20







0.31 0.09 19
0.94 0.09 6
                  137

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00
       o
       o
       o
             EFFECT OF  CERCLA TOXICS  ON  COD  REMOVAL
            100
90 -




80 -




70 -




60 -




50 -




40 -




30 -




20 -




10 -
             0
                                      (Revised)
                         '"' i'"'''''' 11''' 111111111111111* 111111111111111111111111111 /11111111111111

                     11     21     31     41    51     61     71     81     91
        •  ACCLIMATED


   Arrows indicate intermittent spike days.
                                     TIME (days)
                                              +  UNACCLIMATED

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    EFFECT  OF CERCLA TOXICS  ON  NITRIFICATION
3
a
K
O
      20 H
      10-i
                rl f
                                     A
0 "ji i iTTirrTfrrrl ft TTifrTTTT Tt I i | i I m r r i i [ i i i T-rn 11'| 11 ri T rm-jTrr r n i rrj i rrrrt rr-iynT r-i tT-rrp)
  1      11     21     31     41     51     61     71     81     91

                        TIME  (days)
        •  ACCLIMATED           +   UNACCUMATED
  Arrows indicate intermittent spike days.

-------
APPENDIX 4.  QUALITY ASSURANCE SUMMARY
              140

-------
Appendix 4. QA/QC Overview

      This report combines results from two projects "RCRA Pilot Scale Study of
Toxics Removal" and "CERCLA Pilot Scale Study of Toxics  Removal."  Each project
spiked  municipal  wastewater with  mixtures containing  multiple  organic toxic
chemicals having different physical, chemical and biological  properties.  These
properties affected the  overall  removals  and partitioning of the chemicals as
well as the reliability  of analytical results.  Data for each chemical must be
evaluated separately since broad generalizations do not apply.

      Major changes  were necessary  in the  planned  QA  for  the  RCRA project.
Analytical work was transferred  from in-house to a contractor where different
methodology was used in  the work assignment.  Stable labeled isotopes were not
used and measured concentrations could not be corrected for recoveries, although
recoveries were  measured for samples spiked  in  the laboratory  with surrogate
toxics.

      Poor closure of  material balances around  the process units was observed
and was caused at  least  partially  by lack of recovery  corrections.   Fractions
of volatile toxics in air emissions had to be based on actual toxics fed to the
wastewater rather than  on measured influent concentrations.  If measured influent
concentrations were used,  analytical recoveries of essentially  100% from air
coupled with  the  lower  recoveries from  liquid  samples resulted  in apparent
fractions of some volatile compounds in air approaching 200%.

      It was necessary to exclude by  inspection some concentration values which
did not  "fit"  the data  set.   For  example,  where concentrations of  a  single
chemical in  duplicate field samples  were quite different,  the  concentration
values were compared to concentrations from preceding and  following sample points
in the same sample event, to  concentrations at the  same  sample point from other
sample events and if necessary to calculated feed concentrations to decide which
duplicate to exclude or  if all data were highly variable to simply average the
two duplicates.   If concentrations of all organics in one  sample were much higher
or lower than  in comparable samples,  then a decision  was made to  exclude or
retain an  entire  sample  rather than just  individual chemical  concentrations.
In effluent samples where concentrations were generally quite low, large relative
differences between samples were  generally not significant  since the associated
masses of  chemicals  represented only  a small fraction of the total mass of
chemical added.  Therefore most  effluent  concentrations were retained despite
high relative percent differences between  duplicates.

      Of 29  RCRA toxics  in  the  spike, valid data were reported for only 25
compounds.   Table 4-1 shows percent recoveries of laboratory-spiked surrogates
and relative percent differences between  laboratory-spiked duplicates.   Table
4-2 shows the percent of RCRA sampling events providing  usable data and  Tables
4-3 and 4-4 show a summary of relative percent differences for duplicate field
samples.
                                  141

-------
      In the CEr ~|_A project, data collection generally proceeded as planned using
the in-house laboratory.  Stable labeled isotopes of each spiked chemical were
added  to every  sample  and  measured  analytical  values  were corrected  for
recoveries obtained for the labeled compounds.  Despite the improved analytical
methodology, some chemicals still did not appear to be quantitatively measured
in  sludge samples,  either because  of poor  separation from  the  sludge  and
wastewater matrix or because of degradation before analysis.  Where sludge data
showed major discrepancies with removal data based on the wastewater analyses,
the sludge data were excluded from partitioning calculations.

      Of  22 CERCLA  toxics  in  the  spike,  valid data  were  reported  for  19
compounds.  Table  4-5 shows  the  percent  of CERCLA  sampling  events providing
usable data  and Tables 4-6 and 4-7 show a summary of relative percent differences
for duplicate field samples.
                                   142

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TABLE 4-1.  SUMMARY OF RCRA RESULTS - PERCENT RECOVERIES OF LABORATORY - SPIKED
            SURROGATES AND RELATIVE PERCENT DIFFERENCES (RPD) BETWEEN LABORATORY
            SPIKED DUPLICATES.
Event 3
Volatiles
Semivolatiles

Event 4
Volatiles
Semivolatiles

Event 5
Volatiles
Semivolatiles

All 3 Events
Volatiles
Semivolatiles
 Recoveries*                               RPD Range

 19 out of 159: outside of QC limits         3-5
 63 out of 216: outside of QC limits         0-39
Recoveries                                 RPD Range

6 out of 165:  outside of QC limits          0-18
34 out of 162: outside of QC limits          0-30
Recoveries                                 RPD Range

1 out of 102:  outside of QC limits          2-5
51 out of 192:  outside of QC limits         0-9
Recoveries

26 out of 426:  outside of QC limits (6%)
148 out of 570: outside of QC limits (26%)
*Range of acceptable recoveries was 61% - 145% for volatiles and 9% - 131% for
Semivolatiles.
                                 143

-------
      TABLE 4-2.   PERCENT OF SAMPLING EVENTS PROVIDING DATA USABLE  FOR
                  CALCULATION OF TOTAL REMOVAL  AND PARTITIONING  OF  25
                  RCRA TOXICS FROM THREE  ACCLIMATED EVENTS AND THREE
                  UNACCLIMATED EVENTS
RCRA Toxic
Acetone
Cyclohexanone
2-butanone
4-methy 1 -2-pentanone
Tetrahydrofuran
Carbon tetrachloride
Chlorobenzene
Chloroform
1 ,2-di chl oroethane
1 , 2-di chl oropropane
Methylene chloride
Tetrach 1 oroethy 1 ene
Tri chl oroethy 1 ene
1,1,1-tri chl oroethane
1,1,2-tri chl oroethane
Ethyl benzene
Toluene
Total xylenes
Bis (2-ethylhexyl) phthalate
Butyl benzyl phthalate
1 , 4-di ch 1 orobenzene
Naphthalene
Nitrobenzene
4-nitrophenol
Phenol
Accl
Removal
100
0
67
67
100
100
100
100
67
100
100
100
100
100
100
100
100
100
100
100
100
100
100
0
100
i mated
Partitioning
100
0
67
67
100
100
100
100
67
100
*
100
100
100
100
100
100
100
100
100
100
100
100
0
100
Unaccl
Removal
100
33
67
67
67
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
67
100
100
33
100
i mated
Partitioning
100
33
67
67
67
100
100
100
100
100
*
100
100
100
100
100
100
100
100
100
67
100
100
33
100
*Methylene chloride used as preservative in sludge samples.
                                   144

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TABLE 4-3.  SUMMARY OF RELATIVE PERCENT DIFFERENCES FOR RCRA DATA - ACCLIMATED SYSTEM
RCRA Toxic/Event
Acetone
Cyclohexanone
Furfural
2-butanone
4-methyl -2-pentanone
Tetrahydrofuran
Carbon tetrachloride
Chlorobenzene
Chloroform
1,2-dichloroethane
1,2-dichloropropane
Methylene chloride
Tetrachl oroethyl ene
Trichloroethyl ene
1,1,1-trichloroethane
1,1,2-trichloroethane
Ethyl benzene
Toluene
Total Xylenes
Bis (2-ethylhexyl) phthalate
Buryl benzyl phthal ate
1 ,4-dicholorobenzene
2, 4-dimethyl phenol
2,4-dinitrophenol
Naphthalene
Nitrobenzene
4-nitrophenol
Phenol
Primary Influent
3 5
31 54


25
27
25 10
29
2 9
6 6
8
12
27 14
3 18
3 14
11
10 13
5 13
1 12
8 11
8 20
24 70
0 17


0
6

6 63
Primary
Effluent
3
63




10
3
0
4
0
4
1
3
2
4
5
0
5
0
3
31
0


0
13

6
Secondary
Effluent
4
54


0
0
0
67
0
47
53
43
52
15

48
122
0
22
22
0
0
0


0
0

0
Primary
Sludge
3
93




29
5
0
3
10
4

6
3
7
5
21
2
17
37
79
14


31
82

0
Secondary
Sludge
5
75


0
33
157
0
0
0

0

0
0
0
6
0
0
0
31
0
15


0
113

0
Primary
Air
4
0


50
0
100
0
0
0
0
0
0
0
0
0
0
0
0
0










-------
           TABLE  4-4.   SUMMARY OF RELATIVE  PERCENT DIFFERENCES FOR RCRA DATA - UNACCLIMATED SYSTEM
RCRA Toxic/Event
Acetone
Cyclohexanone
Furfural
2-butanone
4-methyl -2-pentanone
Tetrahydrofuran
Carbon tetrachloride
Chlorobenzene
Chloroform
1,2-dichloroethane
1,2-dichloropropane
Methyl ene chloride
Tetrachl oroethyl ene
Trichloroethylene
1,1,1-trichloroethane
1,1,2-trichloroethane
Ethyl benzene
Toluene
Total xylenes
Bis (2-ethylhexyl ) phthalate
Butyl benzyl phthalate
1,4-dichlorobenzene
2 ,4-dimethyl phenol
2,4-dinitrophenol
Naphthalene
Nitrobenzene
4-nitrophenol
Phenol
Raw
Waste-
water
4
0


8



0
0


51
15

0

10
6
57
37
0
0


0
0

10
Primary
Influent
3 4 5
11 7 6
16

2 13
17 7
0
59 3 26
38 10 17
5 22 6
0 2 7
13 4 7
3 16
049
087
0 0 16
0 7 13
098
0 7 14
067
8 18
9 8
14 16


0 9
7 17
0
8 31
Primary
Effluent
3 5
28 3


0
0
1 0
46 8
15
9 0
13 0
13 0
41 4
8 8
18 9
0 0
9 0
0 6
0 0
10 10
0 19
0 35
59


0 5
50 10
0
0 0
Secondary
Effluent
5
123


0

3
40
22
0
3
5
11
0
22
29
0
67
22
46
0
0



0
0

0
Primary
Sludge
3
14



24
35
10
6
0
9
8

0
15
26
0
0
12
165
38
15
35


31
166
0
92
Secondary
Sludge
4
0
0

0
0

0
0
34
0
6

40
0
0
5
29
29
0
186
0
5


0
67

0
Oi

-------
TABLE 4-5.  PERCENT OF SAMPLING EVENTS PROVIDING DATA USABLE
            FOR CALCULATION OF TOTAL REMOVAL AND PARTITIONING
            OF 19 CERCLA TOXICS FROM 11 ACCLIMATED EVENTS AND
            4 UNACCLIMATED EVENTS
CERCLA Toxic
Dichlorobenzene, probably 1,2
Dichlorobenzene, probably 1,3
Dichlorobenzene, probably 1,4
1 , 2, 4-Tri chl orobenzene
Nitrobenzene
1,3-Di nitrobenzene
2,6-Dinitrotoluene
p-cresol
4-Choloroaniline
Hexachl oroethane
Hexachl orobutad i ene
Dimethyl phthalate
Diethyl phthalate
Di butyl phthalate
Butyl benzyl phthalate
Bis (2-ethylhexyl) phthalate
Naphthalene
Lindane
Dieldrin
Acclimated Unacclimated
Removal Partitioning Removal Partitioning
91
100
100
82
91
55
91
91
73
100
100
91
100
100
100
36
100
82
91
73
73
73
55
73
0
18
82
45
9
27
91
100
73
64
27
73
82
36
100
100
100
75
100
100
100
75
0
75
100
100
100
100
100
0
100
100
100
100
100
100
50
75
0
0
25
0
0
25
50
50
25
50
0
50
75
50
                             147

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            TABLE  4-6.   SUMMARY OF RELATIVE  PERCENT DIFFERENCES FOR CERCLA DATA - ACCLIMATED SYSTEM
CERCLA Toxic/Event
Dichlorobenzene, probably 1,2
Dichlorobenzene, probably 1,3
Dichlorobenzene, probably 1,4
1,2,4-Trichlorobenzene
Nitrobenzene
1,3-Di nitrobenzene
2,6-Dinitrotoluene
p-cresol
4-Choloroaniline
Hexachloroethane
Hexachloro butadiene
Dimethyl phthalate
Diethyl phthalate
Di butyl phthalate
Butyl benzyl phthalate
Bis (2-ethylhexyl) phthalate
Naphthalene
Lindane
Dieldrin
Raw
9
0
13
4
2
46


56

5
1
22
13
2
4

10
0
80
Wastewater
10 11
22
22
22
9
97

0
148

4
111
200
0
20
19
1
7
0
22
133
106
125
15
200
39
0
32
120
0
148
200
108
83
94

76
200
115
1 2
2
3 13
6 1

5 23
4
1 27
5
6 6
14 7
3 4
3 6
3 5
10 3
1 8
18
12 4
13 20
51
Primary
5
8
8
13
17
6
5
1
2
9
7
19
2
9
11
23

12
13
22
Infl
6
9
12
8
8
5
4
1
7
4
6
13
2
3
4
12

14
7
5
uent
8
13
12
12
6
10
25

9
3

9
4
5
6
1
42
10
7

9
5
23
3
19
4


3

13
3
6
2
8
5

3
10

11
0
2
2
15
6
11
5
1
8
6
2
0
5
6
16

12
3

Pri.
Eff.
10
12
0
5
4
1


2

1
6
1
9
9
11
56
4
5
13
Secondary
Effluent
1 6 11
17 26 10
4 13 10
67 46 40
6 11
10 18 14
40 15 0
533
79 57
0 36 12
200 29 22
29 46 40
150 156 100
150 108 86
0 32 50
29 25 67

150 133 40
0 5 13
14 11 51
00
                                                                                             Continued next page

-------
          TABLE  4-6.   (CON'T)
SUMMARY OF RELATIVE PERCENT DIFFERENCES FOR CERCLA DATA -
ACCLIMATED SYSTEM
10
CERCLA Toxic/Event
Dichlorobenzene, probably 1,2
Dichlorobenzene, probably 1,3
Dichlorobenzene, probably 1,4
1 ,2,4-Trichlorobenzene
Nitrobenzene
1 ,3-Dinitrobenzene
2,6-Dinitrotoluene
p-cresol
4-Choloroaniline
Hexachloroethane
Hexac hi oro butadiene
Dimethyl phthalate
Di ethyl phthalate
Di butyl phthalate
Butyl benzyl phthalate
Bis (2-ethylhexyl ) phthalate
Naphthalene
Lindane
Dieldrin
4
15
16
15
5
39
170
200
21
20
0
12
29
15
20
18
10
16
19
0
Primary
7

40
19
3


200


200
11

32
16
3

13

20
Sludge
9
16
17
17
17
38


9

200
19
19
22
17
19

17
12

11
0
5
0
5
139
121
200
14
46
200
5
67
38
5
14

4
12
33
1
3
6
16

19
18
200
38
8
0
3
0
21
1
9

9
5
85
Secondary SI
3 4
9
45
13
14
69

0
60
0
200
24
200
200
81
112

200
25
54
15
0
86
2
0
0
0
61
0
200
29
0
13
10
0
4
40
7
75
udge
6
83
18
75
4
57
28
10
133
40
200
4
105
56
19
25

62
3
73
8
31
32
29
4
0
13
0
0
5
0
1
0
200
27
91
25
4
85
56

-------
           TABLE 4-7.'SUMMARY OF RELATIVE PERCENT DIFFERENCES  FOR  CERCLA  DATA  -  UNACCLIMATED  SYSTEM
Raw Wastewater
CERCLA Toxic/Event 1 2 3
Dichlorobenzene, probably 1,2 0 0 50
DichTorobenzene, probably 1,3 0 0 25
Di.chlorobenzene, probably 1,4 200 200 13
1,2,4-Trichlorobenzene 85 85 4
Nitrobenzene 200 200 40
1,3-Di nitrobenzene 200 200 30
2,6-Dinitrotoluene 000
p-cresol 4 7
4-Choloroaniline
Hexachloroethane 000
Hexachlorobutadiene 0 0 200
Dimethyl phthalate 000
Diethyl phthalate 25 25 7
Dibutyl phthalate 51 52 7
Butyl benzyl phthalate 000
Bis (2-ethylhexyl ) phthalate
Naphthalene 114 114 11
Lindane 200 200 8
Dieldrin 80 80 10
Pri.
Inf.
4
11
11
11

14
4
9
1


24
5
2
23
14

1
16
35
Primary
Effluent
1 3
31 1
30 0
22 4
19 3
2 4
19 43
9
3

41 16
17 2
44
2 8
16 9
5 7

4
2
9 16
Sec.
Eff.
3
6
4
6
2
3
100
6
0

0
29
200
11
17
25

0
1
35
Primary
Sludge
3 4
9 173
10 26
13 95
2
49 200
17 0
200 0
11 200

200
0 200
13 54
8 82
13 95
17 97

1,2, 0
13 87
8 200
Secondary
Sludge
2 3
22 43
47 34
44 0
47 3
12 0
3 53
0 0
0

0 0
54 10
0 0
10 200
1 200
47 22

40 40
46 0
71 7
01
o

-------