SEPA
          United States
          Environmental Protection
          Agency
                Office of Air and Radiation
                Washington D.C. 20460
Assessing the Risks of
Trace Gases That Can
Modify the Stratosphere
EPA 400/1-87/001H
December 1987
          Volume VIII:
          Technical Support Documentation
          Ozone Depletion And Plants

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  Current Risks and Uncertainties of
 Stratospheric Ozone Depletion Upon
                  Plants
               Volume VIII
Technical Support Documentation for Assessing
 the Risks of Trace Gases That Can Modify the
               Stratosphere
              December 1987
                      U.S. Environmental Protection Agency
                      Region 5, Library (5PL-16)
                      250 S, Dearborn Street,  Room 1670
                      Chicago, *1L  60604

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                              ACKNOWLEDGEMENTS
    This paper was written by Alan H. Teramura,  Department of Botany,
University of Maryland, College Park, Maryland  20737.

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                                     Ill


                              TABLE OF CONTENTS

                                                                       Page

PREFACE 	  iv

1.   INTRODUCTION 	    1

2.   ISSUES AND UNCERTAINTIES IN ASSESSING THE EFFECTS OF UV-B
    RADIATION ON PLANTS 	    2
    2.A.  Issues concerning UV dose and current action spectra for
              UV-B impact assessment 	    2
    2.B.  Issues concerning natural plant adaptations to UV radiation..    9
    2.C.  Issues associated with the extrapolation of data from
              controlled environments into the field 	    11
    2.D.  Uncertainties associated with crop breeding as a means
              of limiting UV-B impacts 	    15
    2.E.  Uncertainties in our current knowledge of UV-B effects on
              terrestrial ecosystems and plant growth forms 	    19
    2.F.  Uncertainties in the ability to extrapolate effects of
              UV-B radiation on plants to the ecosystem level 	    24
    2.G.  Uncertainties with the ability to extrapolate knowledge
              to higher ambient C0_ environment 	     24
    2.H.  Uncertainties in the ability to extrapolate knowledge to
              include other atmospheric pollutants 	    27

3.   RISKS TO CROP YIELD RESULTING FROM AN INCREASE IN SOLAR UV-B
    RADIATION 	    28
    3.A.  Direct effects on total yield 	    28
    3.B.  Risks to yield due to a decrease in quality 	    42
    3.C.  Risks to yield due to possible increases in disease or
              pest attack 	    43
    3.D.  Risks to yield due to competition with other plants 	    48
    3.E.  Risks to yield due to changes in pollination and flowering ..    51
    3.F.  Risks to yield due to structural plant changes affecting
              harvestability 	    54

4.   SUMMARY AND CONCLUSIONS 	    59

5.   RECOMMENDATIONS 	    63

6.   LITERATURE CITED 	    67

APPENDICES
      A.  Action spectra and their key role in assessing biological
              consequences of solar UV-B radiation change 	    79
      B.  Stratospheric chemistry and the nature of ozone 	   105
      C.  Effects of UV-B radiation on the growth and yield of
              crop plants 	   117

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                                      IV
                                   PREFACE

    Since the discovery of ultraviolet radiation by J.W.  Ritter in 1801,  the
ecological consequences of solar UV has only recently come to the forefront of
public attention due to possible stratospheric ozone depletion resulting from
anthropogenic pollutants.  Although during the past decade our knowledge of
the effects of UV-B radiation has grown prodigiously, we still lack sufficient
information for realistic appraisals of risks and uncertainties.   This is
principally due to an absence of standardization in experimental procedures
and the paucity or virtual void of research in key areas.  The data we do
possess, however, provide a rough basis for understanding some consequences of
enhanced solar UV radiation.  On this premise, I have evaluated the possible
risks and uncertainties concerning stratospheric ozone depletion and its
impact on plants.

    The first section addresses the risk to crop yield resulting from both
direct and indirect effects of enhanced solar UV-B radiation.  In the second
section, the uncertainties associated with the effectiveness of UV-B radiation
are presented, and the last section deals with recommendations for
standardization of experimental procedures and future research priorities.

    I thank Ms. Joan Jeschelnik of the Department of Botany, University of
Maryland, and ICF Incorporated, Washington, B.C., for their excellent
assistance in typing this manuscript and to Drs. Martyn Caldwell, N.S. Murali,
and John Hoffman for their suggestions in the organization of this work.

    I would very much appreciate receiving any comments or suggestions to make
this report an accurate and complete assessment of our current state of
knowledge.


                              Alan H. Teramura
                              College Park, Maryland
                              October 25, 1984

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1.  INTRODUCTION

    In terms of biological response, ultraviolet (UV) radiation spans a
considerable portion of the electromagnetic spectrum.  Therefore for
convenience, it has arbitrarily been partitioned into three wavebands.  The
shortest waveband (UV-C) extends between 200-280 nm and is well known for its
germicidal effects.  The middle UV region (UV-B) contains radiation between
280-320 nm and produces erythema or sunburn in humans.  The longest waveband
is UV-A, which includes radiation from 320-400 nm.   Although not visible to
the human eye, UV-A radidation is important to insect vision.  All three are
natural components of the solar spectrum; however,  due to the large absorption
by the earth's atmosphere, most of this radiation is greatly attenuated prior
to reaching the earth's surface.  The primary attenuator of UV radiation is
stratospheric ozone, which efficiently absorbs nearly all wavelengths shorter
than 290 nm.  Therefore, only the UV-B and UV-A wavebands naturally occur at
the earth's surface.  Since UV-B radiation contains much more energy than
UV-A, it has extremely important biological consequences.

    The protective ozone layer is located at an altitude of between 15 and
40 km in the stratosphere and periodically undergoes natural variations in
concentration, which results in substantial fluctuations in UV reaching the
earth's surface.  For example, ozone concentrations may vary as much as 30%
within the continental United States along latitudinal gradients.
Furthermore, ozone concentrations vary temporally,  such as with the passage of
regional weather systems, as well as seasonally and annually.  In addition to
these natural variations, recent attention has focused primarily upon changes
in ozone concentration resulting from man-made atmospheric pollutants (NAS
1979, 1984; NRC 1982).  Presently, there are some 50 molecular species
involved in over 150 chemical reactions known to involve ozone.  Thus, our
current concentration of stratospheric ozone depends upon a dynamic balance
between chemical reactions that create and destroy ozone (see Appendix B,
Stratospheric Chemistry and the Nature of Ozone).   Increasing releases of
these chemical pollutants tend to favor ozone destruction and reduce
stratospheric ozone concentrations, thereby allowing more UV to penetrate to
the earth's surface.  For example, the photodisassociation of
chlorofluoromethane (CFM), principally from spray propellants, refrigerants,
and foam-blowing agents, contributes a substantial chloride (CIO ) source.
CFMs are so inert in the lower atmosphere that they are not readily removed by
the normal atmospheric cleansing action of precipitation.  Instead, they
slowly migrate into the upper stratosphere where they eventually become
photodisassociated by high energy radiation, releasing free chlorine atoms.
Once they reach the stratosphere, these and other chemicals have a long
residence time during which they participate in catalytic reactions that
destroy ozone.  For example, each chlorine atom at 30 km destroys an average
of 10,000 ozone molecules.  Since stratospheric dynamics are so slow, there is
a century lag between the time these compounds are released at ground level
until the period when equilibrium ozone reductions become established.
Therefore, those atmospheric pollutants being released now, will continue to
affect stratospheric ozone concentrations for the next 100 years.

    This report examines all of the published and unpublished material
currently available to assess the likely impact of projected increases in UV-B
radiation upon global crop productivity and the distribution and abundance of

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plants in natural ecosystems.  The limitations to this assessment are
formidable, particularly due to a paucity of experimental data and the slow
development of appropripate technology.  Therefore actual risks may be far
greater or somewhat less than current knowledge indicates.

2.  ISSUES AND UNCERTAINTIES IN ASSESSING THE EFFECTS OF UV-B
    RADIATION ON PLANTS

    In assessing the impacts of a potential increase in global UV-B radiation
on plants,  experiments ideally should be designed to develop a data base that
perfectly simulates future conditions for all plant species.  Such idealized
experimental designs should include all direct effects in addition to all the
possible significant combinations of effects (interactions).  For example, it
is projected that in addition to increases in the level of UV-B radiation,
atmospheric levels of CCL (carbon dioxide) will also sharply rise during the
next century.  Therefore, experiments should examine both effects
independently, as well as the product of their interaction.  Of course, one
also needs to know how these would change under conditions of drought, mineral
deficiency, etc.  After such a perfect simulation, accounting for all possible
occurrences, it would not be difficult to assess the potential impacts of
global UB-B radiation increases with high precision.  Unfortunately, such
ideal circumstances rarely, if ever, occur.  In reality, we must make
assessments based upon imperfect experimental designs, with only very
selective and sometimes unrealistic growing conditions, and based on only a
few representative plant species.  Therefore, our existing data base for this
assessment can lead only to possible, not conclusive, scenarios.

2.A.  Issues concerning UV dose and current action spectra for UV-B impact:
      assessment

    Total global UV-B irradiance is dependent on a number of factors,
including solar angle, latitude and altitude, stratospheric ozone
concentration, atmospheric turbidity, and degree of cloud cover.
Additionally, the earth-sun distance and minor solar fluctuations also
contribute to annual variations in irradiance (Caldwell 1971).  Because of
diurnal and seasonal variations in many of these factors, the spectral
composition of solar radiation also varies substantially.  Solar UV-B
irradiance varies diurnally, peaking at solar noon.  Annually, UV-B irradiance
is maximum during summer and minimum during winter.  Experiments evaluating
the effectiveness of UV-B radiation on plants typically do not account for
such changes because of practical difficulties in monitoring and supplementing
UV-B radiation.  Generally,  supplemental UV-B radiation is provided using
filtered sunlamps as a squarewave function by using timers.  Such a system
provides a proportionately greater UV  irradiance during morning and late
afternoons than would be anticipated outdoors.  Furthermore, supplemental
radiation  is provided even during cloudy and overcast skies, when the  level of
ambient UV-B may be less than 50% of clear sky irradiances due to the  absence
of the direct beam component.  Thus, supplemental UV-B radiation provided by
investigators in most studies is an unrealistic simulation of the natural
patterns of  solar UV radiation.  Caldwell et al.  (1983) have designed  a
modulated  system to monitor  ambient UV-B and provide  the desired supplemental
UV-B dose.   This system provides a more realistic simulation of anticipated
ozone depletion, since it modulates lamp output in  accordance with actual

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levels of incoming solar UV radiation.  Because of the cost of installation,
it has not been widely adopted (see Section 5, Recommendations).

    Another major limitation with most UV-B studies is that the UV-B dose is
based upon the concentration of ozone during the summer solstice or other
specific day with a fixed ozone depletion.  In reality, ozone concentrations
are highly variable,  being maximum in the late winter and early spring and
minimum during late summer and autumn.  Since a fixed ozone reduction will
result in large differences in UV irradiances during different seasons,  the
assumption of a fixed level of ozone depletion further adds uncertainty in the
evaluation of UV-B dose.

    Photon absorption is the primary event in a biological response to
radiation.  Since photon absorption is a resonance phenomenon, its probability
is strongly wavelength dependent; hence, the effectiveness of radiation in
producing a biological response will also be wavelength dependent.  The
relative effectiveness of UV radiation for a given biological response can be
expressed using a function E(A),  normalized to unity at the most effective
wavelength.  Such a function is known as the action spectrum for the given
biological response.   Action spectra are essential for 1) comparing the
biological effectiveness produced by sources with different spectral
irradiance, 2) evaluating the relative increase of solar UV radiation due to
possible stratospheric ozone depletion, and 3) evaluating the present natural
gradients of solar UV irradiance on the earth.  A brief description of these
points is presented below with more specific details given in Appendix -A
(Action Spectra and their Key Role in Assessing Biological Consequences of
Solar UV-B Radiation Change).

    The source of UV-B radiation most commonly used in plant effects research
is the fluorescent sunlamp, which emits radiation principally in the UV-B
region.  This sunlamp is a low-pressure mercury vapor lamp containing a
phosphor that fluoresces primarily in the UV-B region, and emits some UV-C and
UV-A radiation.  Although the energy emitted comes principally from the
fluorescing phosphor, some emission from mercury vapor is superimposed upon
this, producing distinct lines in the spectrum.  The spectral energy
distribution emitted from various types of lamps varies considerably.
Therefore, to compare different lamps for biological effectiveness, a
weighting function is absolutely essential.  This can be illustrated using two
hypothetical sources, A and B, with a spectral irradiance in the range 280-
300 nm and 300-320 nm, respectively (see Figure 1) .  The total unweighted
irradiance, which is the area under each line, is identical and equal to 100
for the two sources.   Line C represents an assumed biological action spectrum.
The biologically effective irradiance (IRT7) is given by the following
relationship:

                               :BE  =  TX EX dA
where I.  is the lamp spectral irradiance, and E  is the relative effectiveness
of the energy to produce a response at wavelength A.  Thus, the biologically
effective irradiance is the product of the action spectrum and the spectral
irradiance at each wavelength.  The weighted spectral irradiance for the two
sources are shown in curves D and E:  for source A and B the effective
irradiances are 83.3 and 16.7, respectively.  This illustrates the point that

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    10.0
     7.5
 LU
 U
     5.0  •
 on
     2.5
    0.0
                                                       1.0
        280
290       300        310


  WAVELENGTH  (nm)
                                                    - 0.75
                                                    - 0.5
                                                    - 0.25
   0

320
                                            TO
                                            m
                                            m
                                            TI
                                            TI
                                            m
                                            r>
                                                              <
                                                              m

                                                              m
Fig. 1. Two hypothetical sources, A and B, were weighted with action spectrum

       C,  resulting in a five-fold difference in the integrated weighted

       irradiance (area under curves D and E).

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although the two sources have the same total unweighted irradiance, their
biological effectiveness differs by five-fold.

   Several UV action spectra have been developed using monochromatic radiation
(Figure 2).  All these share the common feature of decreasing effectiveness as
wavelength increases but have considerable variation in the rate of this
decrease.  Most of the published UV action spectra to date were determined
with isolated organelles,  membranes, microorganisms, etc., rather than with
intact higher plants.  Caldwell (1971) has developed a generalized plant
damage spectrum based upon the combined responses of a number of different
plant species.  The effects of UV-B radiation on a specific characteristic in
an isolated organelle can differ considerably from an intact plant due to
cellular shielding effects in the plant and inherent repair mechanisms.  For
instance, it is now well documented that the effects of UV-B radiation can be
altered by visible radiation.  UV-B radiation has a greater damaging effect
under low levels of visible radiation than under high levels (Teramura et al.
1980; Mirecki and Teramura 1984; Warner and Caldwell 1983).  Thus, an action
spectrum developed on intact plants under polychromatic radiation would be
preferable, and enable a more realistic assessment of the biologically
effective increases in solar UV-B radiation.   Caldwell et al. (1986) have
recently attempted to develop such an action spectrum, and although there are
experimental limitations,  they were able show that it is technologically
possible.

    Another essential reason for developing appropriate action spectra is for
the evaluation of radiation amplification factors (RAF), i.e.,  the relative
increase in biologically effective UV-B radiation associated with a specific
ozone reduction.  RAF is a complex function taking initial ozone layer
thickness,  percent ozone layer reduction,  latitude,  season, and biological
weighting function into consideration (NAS 1979).  The increase in solar UV-B
radiation as a result of ozone reduction becomes appropriate only when the
biological effectiveness of this radiation is known.  Without calculating an
RAF,  the absolute increase of total solar UV-B radiation resulting from even
an appreciable ozone reduction is so small that it is insignificant.  RAF
values for a 16% ozone reduction at three latitudes  during the  time of maximum
solar radiation (summer solstice for temperature and polar latitudes)  are
presented in Table 1.  For the same change in ozone  concentration, the
increase in biologically effective UV-B radiation is significantly greater at
higher than at lower latitudes.   Table 1 additionally illustrates that RAF
also varies with different action spectra.

    Since solar spectral irradiance increases by orders of magnitude with
increasing wavelength in the UV-B region,  the tails  of the action spectra have
a profound effect on the net RAF.   Figure 3 shows the calculated RAF values
for different ozone column thicknesses according to  various action spectra.
The RAF values are much higher for those with steeper slopes than for  those
shallow slopes.   Thus,  the computed biological effectiveness of solar
radiation could either be  underestimated or overestimated if the action
spectra are not realistic  of true plant responses.

    There is a natural latitudinal gradient of solar UV-B radiation due to
differences in the prevailing solar angle and total  ozone column thickness
(Caldwell 1981,  Caldwell et al.  1980).   Such  a natural gradient in UV-B

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             I
             o
             O  -4 -
280     290
                               300     310     320

                                  WAVELENGTH Inm)
                                                    330     340
Fig. 2. Weighting functions in current use for biological UV effects.
        (NAS  1979)

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Table 1.  Comparison of RAFs Calculated from Three Different Action
          Spectra for a 16Z Ozone Depletion (from Caldwell 1981)
Latitude
20°
40°
70°
Setlow
(1974)
46.3
47.5
49.4
Caldwell
(1971)
32.0
35.0
44.0
Jones and Kok
(1966)
2.2
2.3
2.3

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     3.0
    2.0
 u.
 <
 cr
      .0
                             damage
            0.192      0.224    0.256     0.288     0.320
                             Ozone Column   (cm)
Fig.  3.  Radiation amplification factors calculated for different ozone column
        thickness, relative to 0.32 cm, and a solar angle from the zenith of
        33.6°  calculated according to the action spectra shown in Fig. 2.  The
        dashed line represents a case of 2% increase in biologically effective
        radiation for a 1% decrease of ozone.  The model of Green et al.
        (1980) was used to calculate the solar spectral irradiance (direct
        beam + diffuse) used for those RAF values (from Caldwell et al. 1986)

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radiation provides an opportunity to study plant responses to enhanced
levelsof solar UV-B radiation.  Correlations between this latitudinal UV
gradient and skin cancer have been used to calculate future increases of human
skin cancer anticipated from a given ozone reduction (NAS 1984).  Such
correlations between latitude and plant responses are more difficult to make
due to gross climatic and edaphic variations.  However, growth  chamber studies
with species from different latitudes can provide some limited  information.
The steepness of the latitudinal gradient of solar UV-B irradiance depends
upon the action spectrum used.  If the spectrum has a shallow slope, there
will effectively be only a very small latitudinal solar UV-B gradient, while a
steep slope will show a wide latitudinal gradient.

    It is evident from the above discussion that a more realistic action
spectrum is needed for a proper assessment of the possible consequences of
enhanced UV-B radiation due to ozone depletion.  An under- or overestimation
of UV-B effectiveness would result if inappropriate action spectra are used.

2.B.  Issues concerning natural plant adaptations to UV

    There exists tremendous variability in plant species sensitivity to UV-B
radiation (Krizek 1978, Van et al.  1976, Hashimoto and Tajima 1980, Tevini et
al. 1981 and 1982, Tevini and Iwanzik 1982, Teramura 1983).  Some species
show sensitivity to current day ambient levels of UV-B radiation (Teramura et
al. 1980, Bogenrieder and Klein 1978, Sisson and Caldwell 1976) while others
are apparently unaffected by rather massive UV enhancements (Becwar et
al.1982, Ambler et al.  1978).   Confusing this issue further are reports of
equally large response differences among cultivars within a species (Biggs et
al. 1981, Dumpert and Boscher 1982,  Murali and Teramura 1986a,b, Murali et al.
1986).  At present, the basis or mechanisms responsible for these inherent
species and cultivar differences have not been well documented.  For example,
earlier investigators speculated that the apparent difference frequently
observed between monocotyledonous and dicotyledonous plants may be due to
differences in plant growth form (Van and Garrard 1975).   Grasses have erect
leaves while most herbaceous species generally have horizontally displayed
leaves.  More recently, however,  Caldwell (1981,  1982)  has concluded from
computer simulation studies that leaf orientation probably has little
effectiveness in UV avoidance due to the high proportion of the diffuse
component in the global UV-B radiation flux.

    There are apparently at least three main categories of natural UV
protective mechanisms (Beggs et al.  1986),  which may explain in part the great
range of species response differences.   The first includes mechanisms whereby
UV-induced damage is repaired.   Photoreactivation is a light-activated (UV-A
and blue light primarily),  enzyme-mediated process whereby pyrimidine dimers
produced as a consequence of UV absorption by DNA are split (Rupert 1984).
Although this has not yet specifically been demonstrated in plant tissues,
numerous examples of indirect evidence exist (Beggs et al. 1986, Tanada and
Hendricks 1953,  Bridge  and Klarman 1973),  suggesting that it is a widespread
phenomenon in plants.   Excision repair is the process whereby potentially
deleterious photoproducts of UV absorption are removed and replaced by new,
correct DNA sequences.   This has  clearly been documented in plant tissues
(Howland et al.  1975,  Soyfer 1983)  and is also a widespread phenomenon in
animals.   Postreplication repair  involves the replication and combination of

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                                      10
intact DNA strands in exchange for damaged ones,  but is yet unknown in plant
tissues.  Finally, quenching and free radical scavenging of oxygen singlets
produced by photo-oxidation may be a means of alleviating some types of
UV-induced damage.  The importance and extent of these processes in
alleviating UV damage in plants has not yet been well documented.

    The second category of protective mechanisms are those that tend to
minimize the damaging effects of UV-B radiation (Beggs et al.  1986).  Probably
the most important of these mechanisms in plants is growth delay.   If cell
division stops or is slowed upon UV irradiation,  then the other repair
mechanisms alluded to above could come into play and help to ameliorate the
damage before it became lethal to the plant.  Although many plants show a
growth inhibition upon UV-B radiation exposure (for example, see Teramura
1983), it is not clear whether this inhibition is the direct effect of the
damage done to the plant, or due to the activation of this protective
mechanism.  For example, Dickson and Caldwell (1978) found that UV-B radiation
altered the pattern of cell division early in the ontogeney of Rumex
pat Lent La.  Specifically, cell expansion was unaffected and it was the rate
and not the duration of cell division that was affected.  Despite these
changes, Rumex appears to be a plant that is highly sensitive to UV-B
radiation-induced damage (Sisson and Caldwell 1976, 1977).

    The third category of protective mechanisms involves those that
effectively reduce the amount of UV radiation actually reaching sensitive
plant targets.  These mechanisms include structural attenuation by the cuticle
and cell wall, which seem to play only a minor role since they offer little UV
absorption (Caldwell et al.  1983a, Steinmuller and Tevini 1985).  The
principal mechanism in this category is probably the selective absorption of
UV radiation by pigments located in outer tissue layers.  The most attractive
biochemical candidates appear to be flavonoids and other related phenolic
compounds that occur in the vacuoles of epidermal cells and have high UV
absorption coefficients but are nearly transparent in the visible region of
the spectrum  (Caldwell et al. 1983).  A large number of investigators have
shown that flavonoid concentrations in plant leaves substantially increase
upon UV exposure  (Wellman 1982, Murali and Teramura 1985a and 1986a,
Robberecht and Caldwell 1978, Tevini et al. 1981 and 1983, Flint et al. 1985).
However, it has not been established how many plant species increase leaf
flavonoid biosynthesis in response to increasing levels of UV-B radiation, nor
whether such  an increase is sufficient to completely attenuate the damaging
effects of UV radiation.  Some studies suggest that despite a large increase
in flavonoid  concentration produced in leaves, UV-sensitive targets, such as
the photosynthetic machinery contained in chloroplasts, are still adversely
affected  (Sisson  1981, Teramura et al. 1984a, Mirecki and Teramura 1984).

    Although  much of the attention concerning natural plant adaptations to
enhanced levels of UV-B radiation has been recently focused upon UV
attenuation by flavonoids, knowledge of total leaf flavonoid concentrations
alone do not  account for the range of responses observed  in species
sensitivity.  For example, total leaf flavonoid levels  found in UV-B
irradiated soybeans were less than those found in cucumber given the same UV-B
dose, yet cucumber was found to be much more sensitive  to UV (Murali and
Teramura 1986a,c).  Therefore, the inherent range of plant species sensitivity
to UV-B radiation is probably the product of a number of UV-protective

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                                      11
 mechanisms acting in concert within the plant.   We currently need more
 specific information concerning plant adaptations to UV-B radiation before we
 can further refine our estimates of the ability of natural plant protective
 mechanisms to compensate for the projected increases in solar UV-B radiation.

 2.C.  Issues associated with the extrapolation of data from controlled
       environments into the field

     By far, the bulk of our understanding of the impacts of UV-B radiation
 comes from studies conducted in artifically controlled environments (Teramura
 1983) .   Because environmental conditions within growth chambers or greenhouses
 are unlike those found in nature,  plant responses under such conditions may
 neither quantitatively nor qualitatively resemble field responses.  For
 instance,  it is now widely known that plants grown in growth chambers appear
 to be more sensitive to a given UV dose than field-grown plants (Caldwell
 1981, Bennett 1981,  Teramura 1982a, Mirecki and Teramura 1984).  The basis for
 this difference in sensitivity comes from the fact that in artificial
 environments (growth chambers and greenhouses)  a single factor is generally
 manipulated, while all other factors are either kept constant or are optimized
 for growth.  Such single-factor stresses are rarely experienced by
 plants outdoors.  Instead, under actual conditions, plants would commonly
 experience simultaneous, multiple stresses.  For example, plants receive their
 maximum daily UV-B irradiance during the period of maximum air temperatures
 and evaporative demand for water.   Furthermore, unlike plants in growth
 chambers where nutrient solutions may be applied daily, most native crops and
 many agricultural crops grow in soils that are  low or deficient in nutrients.
 In addition to these differences in physical factors, artificial environments
 almost always exclude biotic factors, such as the interactions between other
 plants, insects, diseases, etc.

     Weighed against these shortcomings of controlled-environment studies are
 the enormous complexities associated with field studies.  Here, daily
 fluctuations in environmental factors are superimposed upon longer-scale
 seasonal and annual fluctuations making interpretation extremely difficult and
 necessitating multiyear experimental designs.  Both temporal and spatial
 variability often result in inconsistencies in plant responses between one
 year and the next (for examples see Biggs et al. 1984, Gold and Caldwell 1983,
 Teramura 1981, Lydon et al. 1986).

     One potentially useful approach in attempting to understand the effects of
 UV-B radiation on plants under more realistic conditions has been the study of
 the interactions between UV and other, commonly experienced plant stresses
 such as water stress, nutrient deficiency, and low visible light stress (Table
 2).  As such, these studies are not attempts simply to mimic field conditions
 under artificial environments.  Instead, they were expressly designed to test
 specific factor interactions to develop a better understanding of the effects
 of UV-B radiation on plants.

    Currently, five studies have assessed the combined effects of water stress
and UV-B radiation on plants.  In the first two  (Teramura et al. 1983 and Tevini
et al. 1983), cucumber and radish seedlings were grown in a factorial
combination of two UV-B irradiances and three levels of water stress.  These
studies revealed that exposure to enhanced levels of UV radiation may affect the

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                                      12
      Table 2.  Studies Examining the Interaction Between UV-B Radiation
                and Other Environmental Stresses
 UV-B Radiation and
    Water Stress
    UV-B Radiation and
    Mineral Deficiency
   UV-B Radiation and
        Low PPFD*
Teramura et al. 1983

Tevini et al.  1983

Teramura et al. 1984a

Teramura et al. 1984b

Murali and Teramura,
  1986c
Bogenrieder and Doute 1982

Murali and Teramura 1985a

Murali and Teramura 1985b
Bartholic et al. 1975

Van et al.  1976

Sisson and Caldwell 1976

Teramura 1980

Teramura et al. 1980

Warner and Caldwell 1983

Mirecki and Teramura 1984
*PPFD = Photosynthetic Photon Flux Density

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                                       13
susceptibility of some crops, like cucumber, to water stress.  Furthermore,
water stress appeared to alter the sensitivity of radish to UV radiation by
inducing flavonoid (UV-absorbing pigments) biosynthesis.  Two studies (Teramura
et al. 1984a and Teramura et al. 1984b) examined the effects of UV irradiation
on the photosynthetic recovery from water stress and on the various components
of internal water relations in soybean.  Plants were grown in greenhouses under
two levels of UV-B radiation and two watering prehistories (water-stressed and
well-watered).   The results from these studies indicated that UV-B radiation
and water stress produced an additive, deleterious effect on photosynthesis.
Therefore, this combination of stresses was more deleterious than either stress
alone.  At present, the mechanism responsible for this effect is unknown, since
UV radiation had no affect on the internal water relations of soybean (Teramura
et al. 1984b).

    The most recent study (Murali and Teramura 1986c) assessed the effects of
mild water stress and UV-B enhancement under field conditions.   The results
revealed no additional deleterious effects of UV-B radiation when combined with
water stress.  It was hypothesized that changes in leaf anatomy, increased
flavonoid production, and reduced growth induced by water stress masked the
effects of increased levels of UV-B radiation.

    To date, three studies have focused on the interactions between UV-B and
mineral deficiency.  Bogenrieder and Doute (1982) compared the effects of UV-B
on the growth and photosynthesis of lettuce (Lactuca sativa) and alpine sorrel
Rumex alpinus)  grown hydroponically under four mineral concentrations.
They concluded that plant productivity (accumulation of dry matter) became more
sensitive to UV-B radiation as total mineral supply decreased.   Murali and
Teramura (1985a,b) hydroponically grew soybean in four levels of phosphorous
(P) under two levels of UV-B radiation.  Surprisingly, they found that on a
relative basis, plant sensitivity (dry weight basis) to UV-B radiation
decreased as P level decreased.   This suggests that the greatest impact of UV-B
enhancement might appear in well-fertilized (agricultural) regions, rather than
in areas of low fertility.  This unexpected response was at least partly due to
an increase in the production of UV-absorbing pigments in the leaves of
nutrient-deficient plants.

    One of the most obvious differences between growth chamber and field
environments is the level of visible radiation available to the plants during
growth.  Since most growth chambers supply visible radiation using a
combination of incandescent and fluorescent lamps,  visible irradiances are
typically quite low,  usually ranging from 10% to 40% of average midday
irradiances.  The concern over this difference stems from the knowledge that
many of the deleterious effects  of UV radiation may be ameliorated by exposures
to longer wavelengths.   If this  is the case,  then experiments conducted in such
growth chambers would substantially overestimate the impact of UV effectiveness
in the field.  At least seven studies have addressed this question and the
germain conclusions of each are  summarized in Table 3.  Despite the fact that
these data include a wide diversity of plant species and growth conditions,  a
clear trend emerges:   plants grown in higher levels of visible  radiation, more
closely approximating field conditions, are less sensitive to the deleterious
effects of UV-B radiation.  A corollary to this conclusion is that plant
sensitivity to  UV-B radiation is strongly influenced by the level of visible

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                                                       14
      Table 3.   Percentage Change from Mylar Controls  for Photosynthesis  or Growth  by UV-B Radiation  at  Differer.
                Photosynthetic Photon Flux Densities  (PPFDs).
                Values in Parentheses are Changes  Resulting from Concomitant PPFDs
         Species
                                                             -2 -1
                                            Peak  PPFD  (jjinol ra  s  )
                               2000   1600    1400
                                                     800-     400-
                                                     900      500     200
                                                                            70
                                                                                        Reference
Phaseolus vulgaris L.
Zea mays L.
Brassica oleracea
var. capitata L.
Brassica oleracea
var. acephala L.
Avena sativa L.

Rumex patientia L.
 +5
 +7
Lycopersicon esculentum L.      -22
Pisum sativura L.
Glycine max (L.) Merr.
                                        -6
                                       -14
                                              -18
                                              -29
-38
  +5



 +12



 -19


 -58


 -65


 -20
(-20)
  -5
(-17)

  -6

 -10


  -5


 -30
                                                             -24
                                                              +4
                                                             -23
                                                             -59
                                     -16



                                     -33

                                     -33

                                     -35
                                                                    -52
                                                                    -33
                                                                    -27
                                     -24
                                                                             -25
                                                                            (-10)
                                                             -38
Bartholic et al 1975


Bartholic et al 1975

Van et al 1980

Bartholic et al 1975

Van et al 1980

Bartholio et al 1975

Van et al 1980


Teramura et al 1980
                                                      Teramura 1980
                                                      Merecki  and Teramura 1984
                                                      Merecki  and Teramura 1984
                                                      Warner  and Caldwell 1983
                                                      Warner  and Caldwell 1983
                                                      Van et  al 1980
                                                                                     Van et  al 1980
                                                      Van et al 1980
                                                                                     Sisson and Caldwell 1976

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                                       15
radiation available during growth and development,  and that shaded environments
maximize this sensitivity.

    Two studies (Lydon et al.  1986 and Teramura and Murali 1986) have
specifically examined the differences in UV-B radiation response between field-
and greenhouse-grown soybean.   Six soybean cultivars were grown in an unshaded
greenhouse under either no UV-B radiation or a level simulating a 16% ozone
depletion (at College Park, Maryland, 39°N) during the summer solstice based
upon the generalized plant weighting function (Caldwell 1971).   These same
cultivars were also grown in the field and received either ambient levels of
UV-B or levels simulating a 16% ozone depletion.   In both cases, supplemental
UV was applied via cellulose-acetate-filtered FS-40 sunlamps.  Cultivar
sensitivity ranking was based upon a combined plant response that included
changes in total plant dry weight, leaf area, and plant height.  A summary of
those data is presented in Table 4.  Taken as a whole, the relative ranking for
UV-B sensitivity based on vegetative growth observed in the greenhouse was
quite similar to that found in the field.  The major difference was that UV-B
radiation produced a substantially larger (between a two- and ten-fold) effect
on greenhouse-grown plants compared with field-grown plants.  However, in
specific instances, quite different conclusions could be drawn from the
individual data sets.  For example, cultivar James might be considered rather
sensitive, while York was resistant to UV-B radiation based upon experimental
greenhouse data.  In the field, however, these cultivars demonstrated the
opposite response.  Therefore, if controlled environment-to-field
extrapolations are necessary,  they must be done with the utmost caution.  At
best, general trends may be implied, but specific or quantitative
extrapolations do not yet seem plausible.  Part of the reason for qualitative
and quantitative differences between controlled environment and field responses
to enhanced levels of UV radiation may be due to confounding factor
interactions about which we still have relatively little information.

2.D.  Uncertainties associated with crop breeding as a means of limiting
      UV-B impacts

    Table 5 is a summary of reports that have specifically examined the effects
of UV-B radiation on numerous crop cultivars.  The table is not intended to be
exhaustive, but rather representative of the general nature of cultivar
responses.  Despite the great range of experimental growth conditions and UV
doses utilized throughout these studies, large individual variation between
cultivars was shown in response to UV-B radiation.   Therefore,  the potential
for ameliorating the impacts of projected increases in solar UV radiation may
be present in our current crop germplasm by selecting for UV tolerance.  A
pivotal concern must be acknowledged with this possibility, however:  To date,
we have little experimental evidence to indicate the mechanisms responsible for
these cultivar differences.  Since most crop cultivars are the descendants of a
relatively small number of original genotypes, they are all rather closely
genetically related.  Differences in UV-B susceptibility then are not simply
the result of gross morphological or structural differences such as those found
between different plant species or growth forms such as grasses, herbs, shrubs
and trees.  Nor are they due to gross biochemical or physiological differences
such as those known to occur between plants with different photosynthetic
pathways (C-j, C^ or CAM).  Therefore, these cultivar response differences must
be due to more subtle character differences.  Before crop breeding for UV

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                                      16
Table 4.  Relative Ranking of Cultivars Based Upon a Combined Growth Index.
          Plants Received a UV-B Dose Equivalent to a 16% Ozone Depletion
          (based upon generalized plant response function for College Park,
          Maryland, 39°N) during the summer solstice (data from Lydon et al.
          1986)
Cultivar
Essex
Williams
Bay
James
York
Forrest
Greenhouse*
-113
-104
-101
-79
+15
+253
Field
-75
-41
-37
-27
-6
+29
    *   Relative ranking according to cultivar sensitivity was based upon the
        following:

       (dw UV-B - dw control           leaf area UV-B -  leaf area control
             dw control            +           leaf area control

                                   +          ht UV-B -  ht control
                                                  ht control       ) x 100

        (dw = dry weight,  ht = height)

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                                            17
Table 5.   A Summary of Studies Examining Cultivar Differences in UV-B Radiation Sensitivity
Crop
Glycine max









Phaseolus vulgaris




Brassica oleracea

Cucumis sativus




Tritium aestivum


Zea mays


Oryza sativa

Number of Growth
Cultivars Condition a/ Conclusions b/
19 G.C. 20% tolerant
60% intermediate
20% sensitive
2 G.H. Cultivar Altona more
sensitive than Bragg
23 G.H. 8% tolerant
33% unaffected
59% sensitive
5 F 20% sensitive
80% unaffected
2 G.H.& G.C. BBL 290 more
sensitive than Astro
3 G.H. Maxidor sensitive
Saxa, Favorit
tolerant
2 G.H.& G.C. no difference
2 G.C. (?)
5 G.H. 20% tolerant
80% sensitive
2 G.H. Poinsett extremely
sensitive, Ashley
slightly sensitive
4 G.H. no difference (?)
7 G.C. no difference
2 F no difference
4 G.C. 25% extremely
sensitive
75% sensitive
5 G.C. 60% tolerant
40% sensitive
Basis of
Comparison c_/ Reference
d.w. Biggs et al. 1981


d.w. Vu et al. 1978

d.w. Teramura and Murali 1986


seed d.w.

leaf resistance Bennett (1981)

Dumpert and Boscher (1982)


p.s, & d.w. Van et al, (1976)
Garrard et al. (1976)
d.w. Murali and Teramura (1986a)

d.w. Krizek (1978)


d.w. Dumpert and Boscher (1982)
d.w. Biggs and Kossuth (1978)
d.w. Biggs et al. (1984)
d.w. Biggs and Kossuth (1978)


d.w. Biggs and Kossuth (1978)


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                                                        18
             Table 5.   A Summary of Studies Examining  Cultivar   Differences  in UV-B  Radiation  Sensitivity
                                                     (continued)
Crop
Hordeum vulgare


Spinacia oleracea
Gossypium hirsutum
Pennisetum glaucum
Cucurbita pepo
Number of
Cultivars
it

3
2
2
2
3
Growth
Condition a/
G.H.

G.C.
G.H.
G.H.
G.C.
G.C.
Conclusions b/
25% tolerant
75% sensitive
no difference
both sensitive
no difference
no difference
no difference
Basis of
Comparison £/

d.w.
d.w.
d.w.
d.w.
d.w.
d.w.
Reference

Dumpert and Boscher (1982)
Biggs and Kossuth (1978)
Dumpert and Boscher (1982)
Ambler et al. (1975)
Biggs and Kossuth (1978)
Biggs and Kossuth (1978)
a/ G.H. = greenhouse; G.C.  = growth chamber;  F = field

b/ If data presented, sensitive means UV-B radiation reduced d.w.  by at least 10% over control plants.   Tolerant
   indicates that UV-B resulted in less than 10% reduction in growth.   In some cases,  tolerant plants were even
   stimulated by UV-B radiation.

£/ d.w. = total plant dry weight;  p.s.  = net photosynthesis.

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                                       19
tolerance can be attempted experimentally, we must understand the genetic bases
for these response differences.  Otherwise, if tolerance to UV-B radiation
werelinked (in a genetic sense) to a suite of less desirable, or totally
undesirable,  characteristics, then crop breeding may not ameliorate, and could
possibly exacerbate, the impacts of UV-B enhancement.  In conclusion, there
appears to be promising evidence that tolerant genotypes already exist in our
current crop germplasm, supporting the notion that breeding may limit the
deleterious impacts of increased solar UV radiation.  However, a large degree
of uncertainty still remains in connection with its implementation due to the
absence of any information concerning the genetic bases for these differences.

2.E.  Uncertainties in our current knowledge of UV-B effects on
      terrestrial ecosystems and plant growth forms

    Table 6 is a survey showing the 10 major terrestrial plant ecosystems in
the world and their relative importance in terms of net primary productivity
(NPP) and area covered.  The effectiveness of UV-B radiation on plant growth
has been  examined in plants representing only 4 of these 10 ecosystems,  and
collectively these only account for 27% of global NPP.  In two of these
terrestrial plant ecosystems, temperate forests and temperate grasslands, only
very limited preliminary data are currently available.  The vast majority of
our knowledge of the biological effects of increasing solar UV radiation stems
from research focused upon agricultural crops, which account for less than 8%
of global NPP.

    A survey of UV-B studies by major plant growth forms is presented in
Table 7.  Of the 25 categories listed, in only 8 (32%) has the effectiveness of
UV-B radiation on some component of plant growth (dry weight, photosynthesis,
leaf area, height, etc.) been examined.  Only very limited data exist for
large, woody perennial plants (trees).  There are virtually no data on the
effects of UV-B radiation on lianas or vines, small woody shrubs, epiphytes, or
lower vascular plants (ferns, lichens, mosses, and liverworts).  Some data on
the effects of UV-C (254 nm) radiation on lower vascular plants do exist, but
since plant responses to UV-C radiation differ quantitatively as well as
qualitatively from UV-B effects (Nachtwey 1975), these studies have been
omitted from this analysis.

    Of the 314 plant families in the world (Cronquist 1981),  the effects  of
UV-B radiation have been examined in relatively few (Table 8).  In
approximately half these plant families where some knowledge of UV effects are
known, the effectiveness of UV-B radiation on plant growth and development was
not addressed.  Instead, these studies focused upon epidermal transmission to
UV or pollen germination.   Therefore, in terms of utility for calculating the
potential impacts of increasing levels of solar UV radiation on global
productivity, relevant growth information exists for only about 19 families (6%
of total).  Of these 19 families,  only 7 include representative species in
which harvestable yield was examined (see Section 3.A, Direct Effects on Total
Yield).

    In conclusion, very little information exists on the effectiveness of UV-B
radiation on native plant species.   In fact,  only a very small fraction of
plant families and plant growth forms have actually been extensively examined

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                                      20
              Table 6.   Survey of UV Studies by Major Terrestrial
                        Plant Ecosystems  (after Whittaker  1975)
Ecosystem
Tropical forest
Temperate forest
Savanna
Boreal forest
Agricultural area
Woodland and shrub land
Temperate grassland
Swamp and marsh
Desert and semidesert
Tundra and alpine areas
Global NPP-'
(109 ton/yr)
49.4
14.9
13.5
9.6
9.1
6.0
5.4
4.0
1.7
1.1
Total
Area
(106 km2)
24.5
12.0
15.0
12.0
14.0
8.5
9.0
2.0
42.0
8.0
Included in
UV Study b/
no
yes
no
no
yes
no
yes
no
no
yes
a/ NPP = net primary productivity.

b/ Only studies examining some aspect of growth.

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                                       21
          Table  7.   Survey of UV Studies by Major  Plant Growth Forms
       Plant Growth Form
Included in
UV Study *
 Family
Large (>3 m tall) perennial plants
   Needle-leaved trees
   Broad-leaved evergreen trees
   Evergreen-sclerophyll trees
   Broad-leaved decidious trees

   Thorn-trees
   Rosette trees
   Bamboos

Lianas or vines

Small (<3 m tall) perennial plants
   Needle-leaved shrub
   Broad-leaved evergreen shrub
   Evergreen-sclerophyll shrub
   Broad-leaved deciduous
   Thorn-shrubs
   Rosette shrubs
   Stem succulents
   Suffrutescent shrubs
   Dwarf shrub
    yes
    yes
    no
    yes

    no
    no
    no

    no
    no
    no
    yes
    no
    no
    no
    no
    no
    no
Pinaceae
Rutaceae

Aceraceae,  Betulaceae
  Oleaceae
Ericaceae
Epiphytes
    no

-------
                                       22
           Table  7.   Survey of UV  Studies by Major  Plant Growth Forms
                                  (continued)
       Plant Growth Form
Included in
UV Study*
  Family
Herbaceous plants
   Ferns
   Gramminoids
   Rosette plants

   Forbs
    yes
    yes
    Yes

    yes
Thallophytes
   Lichens
   Mosses
   Liverworts
    no
    no
    no
Lemnaceae
Poaceae
Polygonaceae
  Plantaginaceae
Amaranthaceae
  Asteraceae
  Chenopodiaceae
  Cruciferae
  Cucurbitaceae
  Euphorbiaceae
  Fabaceae
  Liliaceae
  Malvaceae
  Onagraceae
  Polygonaceae
  Rosaceae
  Scrophulariaceae
  Solanaceae
  Umbelliferae
* Only studies examining UV effects on some aspect of growth.

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                                      23
                  Table 8.  A Survey of UV Studies by Plant Family
Family
Aceraceae
Amaranthaceae
Asteraceae
Betulaceae
Bignoniaceae
Boraginaceae
Cactaceae
Capporidaceae
Chenopodiaceae
Commelinaceae
Cruciferae
Cucurbitaceae
Cyperaceae
Ericaceae
Eupho rb i a c e ae
Fabaceae
Geraniaceae
Hippocastanaceae
Hydrocharitaceae
Lemnaceae
Liliaceae
Linaceae
Malvaceae
Oleaceae
Onagraceae
Oxalidaceae
Papaveraceae
Pinaceae
Plantaginaceae
Poaceae
Polygonaceae
Portulacaceae
Rosaceae
Rutaceae
Salicaceae
Saxifragaceae
Scrophulariaceae
Solanaceae
Umbelliferae
No Species
Examined
1
1
13
1
1
1
1
2
3
1
9
6
1
3
1
14
4
1
1
1
5
1
3
1
1
1
1
8
2
23
7
1
3
1
1
1
2
5
5
Native or
Crop Species a/
N
N
C/N
N
N
N
N
N
C/N
H
C/N
C
N
C,N
H
C/N
N
N
N
N
C/N
N
C
N
N
N
N
N
N
C/N
C/N
N
N
C
N
N
N
C
C
Type of Study b/
C
C
G , C , F*
C
F
F
F
P,F
G,F*
P
G,C,F*
G,F*
G
G,F
G
G,F*
P,F
F
G
G
G,F
F
G,F
C
G,F
G
P
G
G,C
G , C , F*
G.C.F
F
C,F
G
F
F
C,P
G*
G,F
a/ C = crop; H = horticultural;  N = native.
b/ C = competition study; F = epidermal transmittance study;
   study; P = pollination.
*Included yield studies.
growth

-------
                                       24
even in a cursory fashion.  To address the larger question of the potential
impact of enhanced levels of UV-B radiation on global terrestrial plant
communities and ecosystems, we must currently make the unlikely assumption that
perennial woody trees and shrubs respond in a fashion analogous to the responses
of herbaceous annual agricultural species.  Furthermore, we are completely
lacking any experimental data on the interaction among various ecosystem levels
and components under UV enhancement.  Clearly, much more data would be necessary
before any realistic estimates of this nature could be made.

2.F.  Uncertainties in the ability to extrapolate effects of UV-B radiation
      on plants to the ecosystem level

    Ecosystem composition and function is dependent upon the influence of
various biotic and abiotic factors.  Changes in these factors can lead to
alterations in species composition and proportion depending on the extent of
change, initial species diversity, and genetic variability in resistance to
change.  Various plants and microorganisms show large genetic variation in UV
resistance.  In microorganisms particularly, such resistance can evolve rapidly.
In higher plants, however, it is not yet known whether such evolution can occur
within the timeframe in which the changes in UV-B radiation are anticipated.
Therefore, it is presently not possible to predict the future evolutionary
response to increases in UV-B radiation because of insufficient information on
the inter- and intra-specific differences to UV-B radiation.

    However, it could be generalized that if changes in UV-B radiation are large
(by more than 100%) and the rate of change is rapid (occurring over a period of
decades rather than centuries),  then there will occur a large number of
extinctions and extensive changes in ecosystem composition function due to
differential sensitivity and response rates.  If, on the other hand, change is
small and occurs more gradually, there may be considerable evolutionary
accommodation (Antonovics 1975).  There is evidence that the evolution of UV
resistance has been influential in the early history of life, and that species
have developed protective mechanisms when exposed to higher levels of UV-B
radiation (see Section 2.B, Issues Concerning Natural Plant Adaptations to UV
Radiation).  This genetic variation in UV resistance indicates that plants have
the potential to evolve UV resistance.  However, we still have only very
preliminary data on the consequences of subtle shifts in species interactions,
such as changes in competitive ability, upon future community and ecosystem
composition.  For example, Caldwell (unpublished report, 1985) has reported
changes in competitive interactions between wheat and wild oats that may be
associated with increased UV levels.  Without a more complete understanding of
such changes, further assessment on this area is currently not possible.

2.G.  Uncertainties with the ability to extrapolate knowledge to higher
      ambient C0_ environment

    Global atmospheric carbon dioxide (CCO concentration has been gradually
increasing over the centuries.  Measurements of CO. concentration in ice cores
from Greenland and Antarctica indicate an ambient CO, concentration of about
205 ppm some 20,000 years ago and approximately 280 ppm during the past 10,000
years (Neftel et al. 1982); values from 1905 indicate an early industrial level
of about 290 ppm (Reelings 1978).  Since 1957, both at Mauna Loa, Hawaii, and in
Antarctica, atmospheric C0» concentration has been continuously monitored.  The

-------
                                       25
records at Mauna Loa indicate that in 1968 the atmospheric CO- concentration was
317 ppm; today it is 340 ppm.  In the decade between 1958 and 1969, the ambient
CO- concentration increased by 0.7 ppm per year, while from 1970 to 1982 it
increased by 1.3 ppm per year.  It is anticipated that sometime between 2075 and
2100, the atmospheric CO  concentration will reach 600 ppm (Gates 1983).  The
major source contributing to the increase in CO^ concentration has been the
burning of fossil fuels.  It is estimated that the world's remaining recoverable
resources of oil, gas, and coal contain some 4.13 x 1012 metric tons of carbon.
If this amount is burned and half remains airborne, the atmospheric CO-
concentration would increase by a factor of four (Gates 1983).

    At present we have no experimental evidence on the effects of enhanced
levels of UV-B radiation under increased levels of atmospheric CO,-.  However, on
the basis of other plant responses reported in the literature,  some speculations
could be made.  It should be emphasized that these represent only potential, and
not actual, circumstances.  The individual effects of enhanced levels of UV-B
radiation and increased atmospheric CO- concentration on various plant
parameters are summarized in Table 9.  In general, UV-B radiation has
deleterious effects, while increased CO  has potentially beneficial effects on
plant growth and development.

    Photosynthesis is ordinarily inhibited by UV-B radiation but is increased by
higher levels of CO- concentration, especially in C- plants.   This results in a
reduction of plant productivity by UV-B radiation and an increase in
productivity by increased CO- concentration.  Since CO^ increases plant growth
to a greater extent, the net effect of an interaction Between UV-B radiation and
increased levels of CO- may be a general compensation of the deleterious effects
of UV-B radiation on plant productivity.

    Water-use efficiency increases with an increase in CO  concentration due to
decreased stomatal conductance and increased photosynthesis.   On the other hand,
in UV-B irradiated plants, water-use efficiency decreases due to the inhibition
of photosynthesis.  This results in increased drought tolerance with elevated
ambient CO- concentration, and a decrease in tolerance with enhanced UV-B
radiation.   The net effect resulting between these two environmental changes
would be a compensation of the increased drought tolerance by UV-B radiation.

    Increased atmospheric CO- concentration has been shown to result in early
flowering and accelerated maturity without a concomitant reduction in
plant productivity.   UV-.B radiation inhibits flowering in some  plants but
stimulates flowering in others,  with no apparent effect on maturity.  The net
anticipated effect of a combination of increasing levels of UV-B radiation and
CO- concentration would be an increase in plant flowering and maturity which
could then lead to longer-term changes in the pattern of community succession.

    Responses to both increased levels of UV-B radiation and CO  concentration
produce inter- and intraspecific variations,  which could result in changes in
the competitive balance among various plant associations (Gold and Caldwell
1983;  Strain and Bazzaz 1983).   The product of these two environmental changes
could lead to an eventual alteration in plant composition and community
structure.   Changes  in competitive balance could especially have adverse effects
in agricultural systems if weeds increase their competitive advantage over crop
plants.   Since an increased need for weed control requires more tillage and/or

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                                       26
             Table 9.  Summary of UV-B and CO  Effects on Plants
                       (Lemon 1983; Teramura 1983).
Plant Characteristic
     Enhanced UV-B
    Doubling of CO,
Photosynthesis
Leaf conductance
Water use efficiency
Dry matter produc-
tion and yield
Leaf area


Specific leaf weight

Crop maturity

Flowering
Interspecific
differences

Intraspecific
differences

Drought stress
Decreases in many C_
and C,  plants
No effect in many plants
Decreases in most plants
Decreases in many plants
Decreases in many plants


Increases in many plants

No effect

May inhibit or stimulate
flowering in some plants

Species may vary in
degree of response

Response varies among
cultivars

Plants become less sen-
sitive to UV-B but not
tolerant to drought
In C  plants, increases
up to 100% but in C
plants only a small
increase
Decreases both in C_ and C,
plants
Increases in both C_ and C,
plants
In C_ plants, almost
doubles but in C, plants,
only a small increase

Increases more in C_ than in
C, plants

Increases

Accelerated

Flowers produced earlier


Major differences occur
between C- and C. plants
         3      4

Response may vary among
cultivars

Plants become more
drought tolerant

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                                       27
herbicide application, the increase in production cost could render somet crops
uneconomical to produce,  and thus potentially alter the economic importance of
some plants.

    It is predicted that an increase in CCL concentration would result in major
climatic changes.  Some regions of the world, including large portions of the
central U.S.  and much of eastern Europe and USSR, would experience serious
decreases in precipitation, while the climates of Canada, Alaska, Western
Europe, North and East Africa, and others may become wetter.  Therefore, the
great grain belts are predicted to become much drier (Gates 1983) and probably
less productive.  It has been shown that water stress increases plant tolerance
to UV-B radiation (Teramura et al.  1984, Murali and Teramura 1986c).   Thus, in
these drier regions, UV-B radiation may not be as effective in reducing plant
growth.  Moreover, in the wetter regions, UV-B radiation may also not
appreciably affect growth since increased levels of C0~ would have the
predominate effect.

    The long-term effects of increased levels of atmospheric CO. are not fully
known.  However, it is projected that plant carbon:nitrogen (C/N) ratios would
increase, and that the increase in the rate of plant succession would produce
more organic matter available for decomposition.  With high C/N ratios, the rate
of mineralization would decrease due to limitations in the rate of
decomposition, and thus the availability of nitrogen, phosphorus, and other
nutrients might ultimately limit growth.  Under mineral deficiency, plants have
been demonstrated to be more tolerant to UV-B radiation (Murali and Teramura
1984a, 1984b).  Although the relative impact of UV-B may be somewhat lessened by
mineral deficiency,  plant productivity and yield would nonetheless be
deleteriously affected.

    There is a very high degree of uncertainty in the assessment of these
combined scenarios because of the lack of actual experimental data on the
complex interactions between increased C0_ concentration and UV-B radiation.  In
general, it appears that direct, negative effects of UV-B radiation on plant
growth and development may be somewhat compensated by increased atmospheric CO.
levels.  However, the complex indirect effects resulting from changes in the
competitive balance among species and changes in the quality and quantity of
energy inputs into various ecosystem trophic levels cannot be assessed at this
time.  In light of the extreme importance of these interactions, the potential
risks warrant great concern.

2.H.  Uncertainties in the ability to extrapolate knowledge to include other
      atmospheric pollutants

    One of the growing environmental problems that has been of great concern to
many industrialized countries is the increasing extent and occurrence of lower
atmospheric air pollution.  Primarily anthropogenic in origin,  the major
pollutants include ozone, sulfur oxides (SOx),  and nitrogen oxides (NOx).   All
three major pollutants are deleterious to plant growth and development.
According to the National Crop Loss Assessment Network, farm crop losses in the
United States in 1981 due to air pollution amounted to between $1 billion and $2
billion.  Ozone alone, or in combination with SOx and NOx, is responsible for up
to 90% of the crop losses in the U.S.  caused by gaseous air pollutants (Heck et
al.  1982).   The major sources of air pollutants are transportation vehicles,

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                                       28
industrial production facilities, and electrical power generation, each
accounting for 60%, 16%, and 14% of the total, respectively (Mudd and Kozlowski
1975) .   The mechanism of ozone damage is through the destruction of the
structural integrity of membranes,  which impairs both membrane transport and ion
uptake (Heath 1975).  Sulfur dioxide affects photosynthesis through the lowering
of pH,  which results in chlorophyll destruction by loss of magnesium ions (Mudd
1975).   The mode or target of injury of nitrogen dioxide (NO.,  has not been
fully examined.  Some studies report that it may arise due to enzyme
inactivation through acidification of the cell milieu (Tylor et al.  1975).  Many
investigators have studied plant responses to combinations of 0,, SO., and NO .
In most plants, the deleterious effects were additive and, in a few cases,   X
multiplicative (Reinert et al. 1975).

    UV-B radiation has been shown to inhibit photosynthesis through the
inactivation of the reaction centers of PS II (Iwanzik and Tevini 1982, Tevini
and Iwanzik 1983,  Iwanzik et al. 1983), consequently reducing plant
growth (Teramura 1983).  At present, no data are available on the interaction
between UV-B radiation and various  air pollutants.   However, since both UV-B
radiation and various air pollutants independently have deleterious effects,
their net interactions are anticipated to be additive or multiplicative.
Because of the complete absence of experimental data, there is a high degree of
uncertainty in this projection. •

3.  RISKS TO CROP YIELD RESULTING FROM AN INCREASE IN SOLAR
    UV-B RADIATION

3.A.  Direct effects on total yield

    During the past 10 years, there have been nine field studies examining the
effects of UV-B radiation on crop yield.  Three other field studies have been
reported (Caldwell et al. 1975, Caldwell 1983, Dumpert 1983);  however,
harvestable yield was not the focus of these studies.  Combined, these nine
studies included 22 crop species.  The most widely examined species was corn
(Zea mays), which was included in six of the nine studies, soybean (Glycine max
found in four, and tomato (Lycopersicon esculentum),  bean (Phaseolus vulgaris),
and potato (Solanum tuberosum) each found in three studies.  The relevant
details of each study are listed in Table 10 and a brief summary follows below.
A more comprehensive review of crop responses to UV-B radiation can be found in
Appendix C (Effects of UV-B Radiation on the Growth and Yield of Crop Plants).

    Ambler et al.  (1978) grew eight species of crops (Table 11) in a field at
Beltsville, Maryland (39°N).   Species were paired and grown in six plots with a
lamp irradiation system maintained 1.6m above the plants.  The irradiation
system consisted of a linear arrangement of unfiltered Westinghouse BZS-CLG and
FS-40 sunlamps.  A two-dimensional  gradient was established:  one parallel to
the lamps and another at right angles.  Of the eight species examined, only one,
broccoli, showed a significant UV effect (Table 10) although the authors
suggested that sorghum and corn also were affected.  There are two major areas
of concern with the study.  First,  since unfiltered lamps emit both UV-B and
UV-C radiation, both quantitative and qualitative effects must be reviewed with
utmost caution (Nachtwey 1975).  Second, where effects were reported,
only significant differences were found for plants directly beneath the lamps,
and not at a location farther away from lamps with the same (or higher) UV dose.

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                                    Table 10.  Summary of Field Studies Examining the Effects of UV-B Radiation on Crop Yields.
                                                          Values  represent percent changes  from controls
Ambler
et al.
(1978)
(1)
Bartholic
et al.
(1975)
(2)
Becwar
et al.
(1982)
C3)
Cucurbita maxima              0
Cucurbita pepo
Phaseolus vulgaris            0       +12 to +15
Triticum aestivum
Zea mays                      0       +29 to +39
Spinacia oleracea
Sorghum bicolor               0
Capsicum annum
Glycine max                   0
Cynodon dactylon
Beta vulgaris                 0
Brassica oleracea var.
  capitata
Brassica oleracea var.   -24 to -45%
  botrytis
Lycopersicon esculentum               -5 to -26
Nicotiana tobaccum
Raphanus sativus
Pennisetum glaucum
Solanum tuberosum
Brassica juncea
Vigna unguiculata
Oryza sativa
Arachis hypogaea
 Biggs and   Biggs   Eisenstark
and Kossuth  et al.    et al.
   (1978)    (1984)    (1984)
    (4)       (4)       (4)
-14 to -90
-11 to -39
 -9 to -43
-18 to -38
              -5
               0
                                  Esser
                                  (1980)
                                   (5)
                                +53 to -75
                                                                                                        Hart
                                                                                                       et al.
                                                                                                       (1975)
                                                                                                        (1)
                     -79 to -87               0
                                +11 to -56
                                +19 to -49
                                 -2 to -41
     Teramura
(1981)(1982)(1983)
       (4)
                                                     -8
(1) Unfiltered Westinghouse BZS-CLG and FS-40  sunlamps
(2) Ambient UV filtered with Mylar Tape S  or polyethylene
(3) Ambient UV filtered with cellulose acetate,  Aclar,  or Mylar
(4) Westinghouse FS-40 sunlamps filtered with  cellulose acetate  or Mylar
(5) Unfiltered Philips TL 40/12 sunlamps and lamps  filtered with Schott WG 305  (2  and  3 mm)  filters

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                                       30
                Table 11.  Details of Field Study by Ambler et al.  (1978) a/
     Crop
  Yield
Character b/
  Percent
  Change
Significance c/
Cucurbita
maxima
(squash)
  fruit f.w.
 -23 to -26
                                      ns
Phaseolus
vulgaris
(bean)

Glycine max
(soybean)

Beta vulgaris
(sugar beet)

Sorghum
bicolor
(sorghum)

Zea mays
(corn)

Brassica
oleracea
var.
botrytis
(broccoli)
  fruit f.w.
  seed d.w.
  root f.w.
  shoot f.w.
  ear f.w.
  fruit f.w.
  +2 to -12
+0.3 to   3
 -34 to -46
 -14 to -15
 -24 to -44
 -24 to -45
                                      ns
                                      ns
                                      ns
  ns (P=0.3)



  ns (P=0.2)


  (P=0.01)
a/  Irradiation system used was unfiltered Westinghouse BZS-CLG and FS-40
    sunlamps; the percent ozone change cannot be calculated due to the inclusion
    of UV-C radiation.
b/  f.w. = fresh weight, d.w. = dry weight
c/  ns = not significant

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                                      31
Therefore, shading may be a complicating factor in this study,  although this
possibility was not discussed.

    Bartholic et al. (1975) conducted field exclusion studies in Gainesville,
Florida (29° 36'N) where ambient levels of UV-B were filtered through plastic
films of Mylar Type S or polyethylene (Table 12).   Since plants were grown under
panels covered with these films, only the direct beam component of ambient UV
was removed (which represents approximately one-half the total ambient UV
present).  Three crop species were tested (beans,  corn, and tomato), and each
treatment was replicated five times in three KT plots.   Compared with uncovered
plots, total bean yields under Mylar decreased 15% and under polyethylene by
11%.  In corn, Mylar reduced yield by 28% and polyethylene by 23% compared with
uncovered plots, resulting in a 30-40% increase in ear fresh weight in plants
growing under ambient levels of UV-B.  Tomato matured significantly earlier
under Mylar, resulting in an apparent decrease in fruit weight in plants growing
in uncovered plots.  Although no data were given,  these authors did mention the
possibility of confounding spidermite damage in the corn study.  Apparently,
there was a significant effect of growing plants under the plastic panels
compared with uncovered plants.  Despite both materials being reported as
reducing PAR (photosynthetically active radiation) by only 7% each, there may
have been a shading problem associated with the panel framework.  Alternatively,
a difference may have been maintained in leaf temperatures or soil moisture as a
direct result of the exclosures themselves.

    The study by Becwar et al.  (1982) was also an exclusion study (Table 13)
located at 3000 m in the Colorado Rocky Mountains (39° ll'N).  Three types of
filters were used:  Mylar, Aclar, and cellulose acetate.  Four crop species were
examined including Alaska pea  (Pisum sativus), potato, radish  (Raphanus
sativus), and wheat (Triticum aestivum).  Plants were grown in pots with peat,
vermiculite and sand.  The only UV effect reported was a decrease in wheat
height (between 8% and 19%, depending upon plant age), with no corresponding
change in total plant dry weight.  A second study was also conducted at the high
elevation field site using filtered FS-40 sunlamps, which supplemented ambient
levels of solar UV-B.  Lamps were held in standard two-lamp fluorescent fixtures
and filtered with cellulose acetate and Mylar.  These were suspended l.lm above
the plants and produced no significant effect on crop yield despite a calculated
52% UV enhancement  (based on the generalized plant action spectrum by Caldwell,
1971) compared with sea level  irradiances at the same latitude.  Unfortunately,
there were no plants grown under a UV irradiance that simulated the dose plants
received at sea level as control to make actual comparisons.

    Biggs and Kossuth (1978) grew nine crops (Table 14) in raised beds filled
with a synthetic soil mix in Gainesville, Florida (29° 36').  Yield data were
reported for seven of the nine  crops.  UV-B radiation was supplemented in the
field with a linear arrangement of six FS-40 sunlamps mounted end-to-end and
kept at a 12% angle relative to the soil surface.  This produced a  "gradient" in
UV-B irradiances.  Control plants were those growing without lamps above them
adjacent to those receiving the highest UV dose.  Although "significant" UV
effects were reported in half  the plants, no indication of the statistical tests
used were found in the report,  nor were other descriptive statistics given
(such as S.D. or S.E.).  One area of concern was the lack of consistency of
effects  in this study.  For instance, the greatest reductions  in yield were

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                                       32
               Table 12.  Details of Field Study Excluding Ambient Solar UV
                          by Bartholic et al.  (1975) a/
                          Yield               Percent
    Crop                Character b/          Change          Significance
Zea mays                ear f.w.(?)            +29 to +39        P=0.05
(corn)
Lycopersicon            fruit f.w.(?)           -5 to -26        (?)
esculentum
(tomato)

Phaseolus               fruit f.w.(?)          +12 to +15        P=0.05
vulgaris
(bean)
a/  Irradiation system used was Mylar and polyethylene exclusion panels of
    ambient UV; ozone was simulated to increase

b/  f.w. = fresh weight

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                                       33
           Table 13.  Details of Field Study Excluding Ambient Solar UV
                          by Becwar et al.  (1982) a/
   Crop
   Yield
Character b/
Percent
Change
Significance c/
Raphanus
sativus
(radish)

Solanum
tuberosum
(potato)
root d.w.
tuber d.w.
+11 to +20
 -1 to -17%
                                         ns
                                         ns
a/  Irradiation system used was Mylar, Aclar, and cellulose acetate exclusion
    panels for ambient UV and filtered FS-40 sunlamps; ozone was simulated to
    increase

b/  d.w. = dry weight

c/  ns = not significant

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                                       34
         Table 14.  Details of Field Study by Biggs and Kossuth  (1978) a/
   Crop
  Yield
Character b/
 Percent
 Change
Significance c/
Solanum
tuberosum c/
(potato)

Lycopersicon
esculentum
(tomato)

Zea mays
(corn)

Vigna
unguiculata
(blackeye
pea)

Arachis
hypogaea
(peanut)

Cucurbita
pepo
(squash)

Brassica
juncea
(mustard)
tuber f.w.(?)      +2 to -21
fruit f .w. (?)     -11 to -39
ear dia.
fruit d.w.(?)
leaf f.w.
-3 to  +1
fruit f.w.(?)     -18 to -38
 0 to -24%
fruit f.w.(?)     -14 to -90
-9 to -43
                  ns
                   P=0.05(?)
                                     ns
                  P=0.05(?)
                  ns
                   P=0.05(?)
  P=0.05(?)
a/  A gradient of UV-B irradiances was produced by using a  linear
    arrangement of sunlamps (cellulose acetate filtered FS-40).  Plants
    without lamps above them were controls receiving no supplement UV-B
    irradition.

b/  f.w. = fresh weight

c/  ns = not significant

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                                       35
often found in plants growing in the lowest UV irradiance, or the largest UV
effects were found in plants growing adjacent to ones showing little or no
effect.  By using a gradient, essentially each plant received a uniquely
different UV dose, therefore plants and treatments must, by necessity,  be pooled
for statistical analysis.   Such data manipulation would almost certainly add a
great deal of experimental variability and lead to further difficulty in
interpretation.

    In another field experiment, Biggs et al. (1984) studied the effects of UV
radiation on crop yield over the course of several growing seasons in four
field- grown species including rice (Orzya sativa),  wheat, corn, and soybean
(Table 15).   Again, plants were grown in raised beds filled with synthetic
soils, but in this instance UV irradiation was not supplied as a gradient.
Instead, each system contained six FS-40 sunlamps (three rows of two linearly
arranged lamps) filtered with 3-, 5-,  or 10-ml cellulose acetate providing 32%,
23%, or 16% UV enhancements (based on the generalized plant action spectrum)
above ambient.  Control plants were grown under Mylar-filtered lamps.  Despite
relatively large reductions in rice yield (up to 50%),  these were not found to
be statistically significant.  The only significant yield reduction reported was
for wheat (5% reduction) and only for one of the two experimental years.  The
data for rice, corn, and soybean were highly variable and therefore only very
substantial changes could be statistically detected.  The underlying reasons for
this high degree of variability are presently unknown.

    Eisenstark et al. (1984) grew corn (Table 16) for three growing seasons in
Columbia, Missouri (38° 57'N).  Plants were grown in large pots and irrigated
during the study.  Two levels of UV radiation were supplied by cellulose-
acetate-filtered FS-40 sunlamps simulating a 7% and 21% ozone depletion (based
upon the generalized plant action spectrum).  There were two types of controls:
in one, plants were grown under lamps filtered with Mylar, and in the second,
plants were grown without overhead lamps.  In the most recent field study, half
the plants were irradiated 4 weeks after germination (vegetative) and the other
half, at tassel formation (reproductive).  Plants were found to be particularly
susceptible to UV-induced effects during tassel development (Eisenstark and
Perrot 1985).  In plants irradiated as seedlings, 7% and 21% ozone reductions
produced total grain yield reductions of 23% and 32%, respectively, when
compared with Mylar control plants.

    However, even larger differences were found when plants grown under either
Mylar or cellulose-acetate-filtered lamps were compared with those grown without
overhead lamps.  In this case, yield was reduced by 80% in plants filtered by
Mylar and 87% in those grown under cellulose acetate.  Even more dramatic was
the differential ear maturation:  59% matured when grown in sunlight without
overhead lamps, none matured under cellulose-acetate-filtered lamps and only 18%
matured under Mylar-filtered lamps.  Although the authors suggest that this
large lamp effect is perhaps due to the additional UV-A emitted from the
sunlamps, this UV-A supplement is very small (only several percent) relative to
that UV-A present in midday solar radiation  (see Caldwell et al. 1984).  At
present, these responses are not well understood and certainly need to be
clarified.

    Esser (1980) conducted field studies in Frankfurt,  Federal Republic of
Germany (50° N), on six crop species,  but yield was only reported in four:

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                                       36
   Table 15.  Details of Field Study by Biggs et al.  (1984) and Biggs  (1985) a/
  Crop
  Yield
Character b/
Percent
Change
Significance c_/
Dry z a
sativa
(rice)
seed d.w.
no. seed heads
-26 to -47
-18 to -50
   ns
   ns
Triticum
aestivum
(wheat)

Zea mays
(corn)

Glycine
max
(soybean)
seed d.w. (1982)      -5
seed d.w. (1984)       0
ear f.w.              (?)
pod d.w.              (?)
                   P=0.05(?)
                   ns
                   ns
                   ns
a/  Irradiation system used was cellulose acetate and Mylar-filtered FS-40 sunlamps;
    ozone was simulated to decrease by 16%, 23%, and 32%.

b/  d.w. = dry weight; f.w. = fresh weight

c/  ns = not significant

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                                       37
              Table 16.  Details of Field Study by Eisenstark et al.  (1985)
                                                    Simulated
                                                      Ozone
             Yield        Percent                    Change          Irradiation
  Crop     Character      Change     Significance      (%)             System
Zea mays   grain dry       -87         P=0.05        -7,-21     Cellulose acetate-
(corn)     weight                                               and Mylar-filtered
                                                                FS-40 sunlamps

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                                       38
bean, cabbage (Brassica oleraceae var.  capitata),  spinach (Spinacia oleracea)
and potato (Table 17).   He used linearly arranged Philips TL 40/12 sunlamps
suspended 3 m above the plants and produced four UV enhancements using a
combination of reflectors and Schott WG305 filters.  His two highest UV doses,
simulating 40% and 15%  ozone reductions (based on the generalized plant action
spectrum) were produced by using unfiltered lamps.   Although significant yield
reductions were found in the four crops tested,  these were only found under
unfiltered lamps.  In fact,  yields for spinach,  cabbage, and bean appeared to
increase under filtered lamps.

    Hart et al.  (1975)  grew plants (Table 18) under unfiltered FS-40 sunlamps at
Beltsville, Maryland (39° N).   Lamps were linearly arranged and suspended 3.7 m
above the ground.  Almost no other details of the experiment were given and no
actual yield data are presented.  Only a short descriptive summary of the
results are reported in a table.  Because of the complete absence of data, this
study may only be useful in a very qualitative way.  Even in this light, one
must be careful with any interpretations drawn from this study due to the
presence of UV-C radiation from these unfiltered lamps.

    Teramura has grown soybeans for five seasons (Table 19) at a farm owned and
operated by U.S.D.A. in Beltsville, Maryland (39° N).  During the first two
years, six different soybean cultivars were grown under filtered FS-40 sunlamps
oriented perpendicular to the soybean rows (rows oriented in an east-west
direction).  This arrangement avoids the large variation in UV irradiance along
the length of the bulb, which is a major problem with linearly arranged
(end-to-end) lamps.  (See Section 5, Recommendations.)  Control plants were
grown under Mylar-filtered lamps.  In the last three years, only two cultivars
were grown to increase the sample size to at least 200 plants per cultivar per
treatment.  Field experiments simulated 0, 5%, and 16% ozone depletions (based
on the generalized plant action spectrum) during the first year and 0, 16%, and
25%
ozone depletions thereafter.  Significant reductions in crop yield were found
only in 1981 for cultivars Essex and James.  Interestingly, total seed
yield/plant was significantly increased in cultivar Williams during this same
year.  Although similar general trends were found in 1982, there were no
significant differences associated with increasing UV-B radiation.  Yield was
decreased  in cultivar Essex and increased in cultivar Williams, in 1984, 1985.
and 1986, by supplemental UV-B.  In 1983, a substantially higher yield per plant
(on a relative basis) was found in cultivar Essex,  which was opposite to that
observed in the previous 2 years.  One critical caveat that must be included
with this  observation is that 1983 was an extremely dry-year.  Actual seed
weights of control plants during 1983 were only 20-30% of those harvested  in
1981 and 1982.  Therefore, it is rather tentative whether these 1983 data  are
representative of true (normal) field trends.  This graphically illustrates the
importance of multiyear studies to obtain a more representative description of
the potential impacts of an increase in solar UV radiation reaching the surface
of the earth.  It also emphasizes the need to monitor other environmental
variables  in addition to UV radiation.

    Soybean yield is Influenced by microclimatic factors as well as total  UV-B
dose.  Yield appears to be strongly Influenced bv  the number of days of
precipitation, the number of  days when maximum temperature exceeds 35°C, and  the
number of  days where total irradiance is  low  (i.e. , cloudy days).

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                                       39
               Table 17.  Details of Field Study by Esser (1980) a/
  Crop
  Yield
Character b/
Percent
Change
Significance
Solanum
tuberosum
(potato)

Spinacia
oleracea
(spinach)

Brassica
oleracea
var.
capitata
(cabbage)

Phaseolus
vulgaris
(bean)
 tuber f.w.
 leaf f.w.(?)
 leaf f.w.
 fruit f.w.(?)
 -2 to -41
+11 to -56
+19 to -49
+53 to -75
  P=0.05(?)
   P=0.05(?)
  P=0.05(?)
   P=0.05(?)
a/  Irradiation system used consisted of unfiltered Philips TL 40/12 and
    Schott  WG305 filtered TL 40/12 sunlamps; ozone was simulated to
    decrease by 3%, 8%, 15%, and 40%.

b/  f.w. = fresh weight

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                                       40
             Table 18.  Details of Field Study by Hart et al.  (1975) a/
   Crop
  Yield
Character b/
Percent
Change
Significance c/
Lycopersicon
esculentum
(tomato)

Capsicum
annum
(bell pepper)

Zea mays
(corn)

Glycine max
(soybean)

Arachis
hypogaea
(peanut)

Pennisetum
glaucum
(pearl
millet)

Cynodon
dactylon
(Bermuda
grass)
 fruit no.
 fruit size
 fruit size
 fruit no.
 grain wt.
 bean wt.
 nut wt.
 shoot d.w.(?)
 shoot d.w.(?)
no data given
no data given
no data given
no data given
no data given
no data given
no data given
no data given
    ns
    ns
    ns
    P=0.05(?)
    ns
                                          ns
                                          ns
    ns
    ns
a/  Irradiation system used consisted of unfiltered FS-40 sunlamps; ozone
    change cannot be calculated due to the inclusion of UV-C radiation.

b/  d.w. = dry weight

c/  ns = not significant

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                                                            41
                         Table 19.  Details of Field Study by Teramura (1981-1985) that Measured
                            Percent Change in Seed Dry Weight of Soybean (Glycine max) from a
                                              Simulated Decrease in Ozone3
Cultivar
                                                    Simulated Ozone Change (X)
1981
-16
1982
-16 -25
1983
-16 -25
1984
-16 -25
1985
-16 -25
1986
-16 -25
Bay              -10      +6       -8

Essex            -25b     -12     -23       +39b    +6         +14b     -7         +6    -20b        -5     -19b

James            -14b     -22     -25

Williams         +22b     +9      +14

York

Forrest          --       -14     +27
a Irradiance was provided by Mylar (control)  and cellulose acetate  (UV-B  supplement)  filtered FS-40  sunlamps.

  Significantly different from controls at P<0.05 level.

After initially screening 23 cultivars in the greenhouse,  6 were  chosen for  field  experimentation.   These  six were picked
because they represented the range of UV sensitivity found in  the greenhouse,  including very  sensitive  as  well  as very
tolerant cultivars.   Beginning in 1983,  only  Essex,  a very sensitive,  and Williams,  a very  tolerant  cultivar were planted
in the field to increase experimental sample  sizes  to 200  plants  per treatment.  As  the table above  shows, yields for
Essex were generally reduced by the higher UV supplementation  (25%  ozone  depletion)  while the lower  supplementation  showed
variable results.   In the UV-tolerant cultivar Williams, a 16% ozone depletion generally increased yield,  with  much  more
variable results found at the higher ozone depletion.   One important point to  be made is that the sensitive cultivar Essex
is currently replacing other older cultivars,  including Williams, and  is  becoming  one of the  most widely planted soybeans
in the U.S.   This  is because Essex has other  features that crop breeders  find  superior to Williams.  In a  UV-enriched
environment,  however,  Essex will be deleteriously affected.  Therefore, superior cultivars  that  crop breeders are
developing today may not be suitable for the  future  should the environment change.

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                                       42
Interestingly, the total amount of precipitation received is not nearly as
important as is its distribution over the growing season.  In general, yield
decreases as the number of hot days increases,  and increases as the number of
days with precipitation approaches 25 in the growing season.  Further increases
in the number of days with precipitation decrease yield.  Overall, those
microclimatic factors that induce plant water stress (i.e.,  sunny, hot days with
widely dispersed precipitation) reduce yield, while conditions of reduced water
stress (i.e., cloudy, cooler days with frequent precipitation) enhance yield up
to a threshhold point when yield is again reduced.  By contrast, the effects of
UV-B appear to be more pronounced in years when microclimatic factors favor high
yield.  The effects of UV-B have been shown to be masked under conditions of
plant water stress (Murali and Teramura 1986c).   The relative importance of UV-B
is a function of the cultivar and other prevailing microclimatic factors.  For
example,  in Essex, total seed yield can be predicted within 95% confidence
intervals with a regression model which includes total UV-B dose, number of
precipitation events, and the number of days where air temperature exceeds 35°C
as predictor variables.

    Despite the broad range of experimental protocols and dosimetry used by
various investigators, it appears that increases in solar UV radiation
penetrating to the earth's surface could potentially have a deleterious impact
upon global crop yields.   Even discounting the data from the three unfiltered
lamp studies (Ambler et al.  1978, Esser 1980, Hart et al. 1975), there are still
more instances of significant reductions in yield than reports of no effect at
all.  The uncertainty associated with this conclusion is moderate to large,
since all these studies were imperfect validations, suffering from one problem
or another in experimental design or dosimetry.   Furthermore, only three studies
(Biggs et al. 1984, Eisenstark et al.  1984, and Teramura 1981-1984) include
multiyear observations where longer-scale environmental variability has been
taken into consideration.  Even small reductions in yield can have enormous
consequences when considering the fine balance of the economics of modern
agriculture.  Therefore the data concerning the effects of increasing UV
radiation to global agricultural productivity imply large risks and warrant
great concern.

3.B.  Risks to yield due to a decrease in quality

    The quality of crop yield has only been quantitatively examined in a few
limited studies.  Biggs and Kossuth (1978) reported differences in the quality
of tomato and potato yields from field trials conducted in Gainesville, Florida
(see previous section on crop yield).   In that study, they reported that the
number of abnormally shaped tomato fruit (called defective in the study)
decreased under enhanced levels of UV-B radiation supplied from filtered FS-40
sunlamps.   The range of this reduction in defective fruit was from 11% to 41%
compared with ambient grown controls;  however,  there was no clear relationship
between the magnitude of this reduction and UV-B dose.  They also reported a 6%
to 23% reduction in the number of culls (rots,  cracks, sunscald, etc.) in plants
receiving moderate UV-B enhancements,  while those receiving low enhancements of
UV-B radiation produced a 10-34% increase in culls.  Again,  there was not a
simple, linear relationship between UV dose and the number of culls produced.

    Biggs and Kossuth (1978) also report a 3-13% increase in the mean potato
weight of grade A large potatoes under enhanced levels of UV-B radiation, but

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                                       43
not in any other grade categories.  Again, there did not appear to be a specific
UV-B dose-response relationship for this observation.  In both tomato and
potato, no data were included to  indicate whether these differences were
significant, and if so, the specific statistical tests used to determine this.

    In a field study conducted in Beltsville, Maryland, Ambler et al. (1978)
examined the effects of UV radiation supplied from unfiltered sunlamps.   They
reported that the sugar content in sugar beet significantly increased between
17% and 21% with increasing UV-B  irradiance.  However, they only observed these
significant increases in plants directly beneath the lamp irradiation system and
not in plants receiving an identical UV-B dose at some distance away.  This
suggests that some other uncontrolled factor (shading?) was inadvertently
introduced into the experiment.   Additional experiments are needed to clarify
this point.

    A study conducted by Teramura (1982-1985) examined the effects of UV-B
radiation on seed protein and lipid concentrations of soybean plants grown in
the field at Beltsville, Maryland.  A summary of those data are presented in
Table 20 for the six cultivars tested in 1982 and the two cultivars tested in
1983 and 1984.  Overall, the effects of UV radiation were relatively small.  For
example, seed protein concentrations did not change by more than 5%, and lipids
not more than 13%, over all cultivars and treatments for both years.
Nonetheless, significant UV effects were detected.  Seed protein concentrations
declined by as much as 5% during  both the 1981 and 1982 growing seasons in
cultivar Essex.  Seed lipid concentrations were reduced by 3-5% in cultivar
Forrest in 1982, the only year in which this character was measured in Forrest.
Interestingly, lipid concentrations increased during both years in cultivar
Williams, although this increase  was only significant for the 1982 harvest.
Williams is a cultivar whose seed quality and total seed yield (see Table 20)
were positively affected by UV-B  enhancements,  while Essex is generally
deleteriously affected.

    In addition to direct losses  in yield (reductions in quantity),  increasing
levels of UV-B radiation also may affect yield quality as shown above by several
investigators.  The extent of UV-mediated alterations in global yield quality
cannot presently be estimated with any degree of confidence,  due simply to the
lack of experimental data for different species.   Furthermore,  conclusions drawn
from a single growing season may be unreliable due to the interactions
apparently involved between UV-B  radiation and other commonly experienced plant
stresses (see Section 2.C,  Issues Associated with the Extrapolation of Data from
Controlled Environments into the  Field).  Nonetheless, evidence collected over
several years show consistent reductions in yield quality in soybean,
suggesting that the risk to yield may be quite high in other crops as well.

3.C.  Risks to yield due to possible Increases in disease or pest attack

    Six studies that examined the effects of UV-B radiation on the severity of
pests and diseases are summarized in Table 21.   Esser (1980)  reported that the
number of aphids per bean plant was significantly decreased by UV-B radiation 11
days after their introduction,  but there was no significant difference in the
spidermite population 7 days after their application.   Although the results
suggest that UV-B radiation can have potentially beneficial effects on pest
control,  these conclusions  must be judged with caution since the observation
period was less than 2 weeks long.  Whether there would be any longer-term

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                                                             44
             Table 20.   Sunmary  of Changes  in Yield Quality in Soybean Between the 1982 and 1985 Growing Seasons
                                                    (Teramura 1982-1985)
Crop
Glycine max
cv Bay

Essex

James

Williams

Forrest

York

Yield
Character

% protein
% lipid
% protein
% lipid
% protein
% lipid
% protein
% lipid
% protein
% lipid
% protein
% lipid
1982
% Change

0 to -5
-1.4 to +3
-3 to -5
-2 to +.5
+.2 to +3
-1 to -2
0 to -.2
+5 to +8
+.5 to +2
-3 to -5
-2 to -3
0 to +3
Signi-
ficance

ns*
ns
P=0.05
ns
ns
ns
ns
P=0.05
ns
P=0.05
ns
ns
1983 Signi- 1984 Signi- 1985 Signi- 1986 Signi-
% Change ficance % Change ficance % Change ficance % Change ficance



+1 to -5 P=0.05 +1 to 0 ns -0.7 to 0 ns 0 to -1 ns
+2 to -2 ns -2 to 0 ns 0 ns 0 to -2 P=0 . 05


+.4 to -.2 ns +3 to +5 P=0.05 -0.5 to -1 P=0.05 -1 to -3 P=0.05
-1 to +6 ns -5 to -10 P=0.05 0 ns 0 to +1 P=0.05




* ns = not significant

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                                                             45
                                     Table 21.  Summary of UV-B Effects on Plant Pests and Diseases
         Pest or Disease
                                         Host Plant
                                                              UV-B
                                                            Irradiance a/
                                                                                 Conclusion b/
                                                                                                         Reference
Aphids (Aphis fabae)                 bean

Spidermite (Tetranychus uticae)      bean

Rust (Uromyces striatus)             alfalfa


Scab (Cladosporium cucumerinum)      cucumber
Early blight (Alternaria solani)      tomato
Leaf spot (Stemphyilium botryosum)    alfalfa
Anthracnose (Colletotrichum
  lagenarium)
                                     cucumber
Black rot (Mycosphrella melonis)      cucumber
Scab (Cladosporium cucumerinum)       cucumber
6-25% 0  depl.
       3
6-25% 0  depl.
       3
55-93 mWm
         -2
55-93 mWm
         -2
                                                          8-112 mWm
                                                                   -2
                                                          55-93  mWm
                                                                   -2
                                                          8-112 mWm
                                                                   -2
                                                          55-93 mWm
                                                                   -2
                                                          8-112 mWm
                                                                   -2
                                                                   -2
                                                          55-93 mWm
                                                          8-112  in Wm
                                                          55-93 mWm
                                                                   -2
                                                                  -2
8-112 mWm

80-800 Wra
(unweighted)
                                                                                                         Esser  1980
                                               Cams et al. 1978
decreased no. by 79-81%

-15 to +3% change  (n.s.)

-1 to -2% change in spore
germination  (n.s.)

-4 to -11% change  in spore
germination  (n.s.)

disease severity unaffected

-1 to 2% change in spore
germination  (n.s.)

disease severity unaffected

-2 to 2% change in spore
germination  (n.s.)

disease severity unaffected

spore germination decreased
33 to 89%

disease severity decreased
with UV-B by 33-66%

spore germination decreased
10-60%

disease severity decreased
spore germination decreased   Owens and Krizek 1980
by 10-40%

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                                                                   46
                               Table 21.   Summary  of UV-B Effects  on  Plant Pests and Diseases  (continued)
         Pest or Disease
                                         Host Plant
                         UV-B

                       Irradiance a/
                                                                                   Conclusion b/
                                                                                                           Reference
Rust  (Uromyces phaseoli)
Rust (Puccinia coronata)
                                     bean
                                     oats
                                                          A.8-20 mHm
                                                                    -2
                                                          4.8-20 mWm
                                                                    -2
                                      infected leaves decreased

                                      by 61%



                                      infected leaves decreased

                                      by 30-44%
                                                                                                         Esser 1980
Powdery mildew (Erysiphe graminis)   wheat
                               -2
                     4.8-20 mWm       infected leaves decreased

                                      by 90-100%


                              -2
                     10-20 mWm        99% reduction in conidia      Esser (1979)
Leaf rust (Puccinia recondita)       wheat
                                                          8-16% 0  depl.    infection decreased  14-67%     Biggs  et  al.  1984

                                                                           (n.s.)
Glume blotch (Septoria nodorum)      wheat
                                                          8-16%  0  depl.    infection  decreased  12-14%

                                                                           (n.s.)
Leaf spot (Helminthosporium

  sativum)
                                     wheat
                     8-16% 0  depl.    infection decreased 4-6%

                                      (n.s.)
Frog eye spot (Cercospora sp)        soybean
                     8-16% 0  depl.    0-10% change in seed
                            3
                                      infection (n.s.)
Seed blight (Phomopsis sp)
soybean
8-16% 0  depl.    0-6% change in seed
       3
                 infection
                                                                    -2
Leaf virus (Potato virus S)          Chenopodium quinoa   25-110  mWm       44% decrease  in  lesion no.    Semeniuk  and Goth  1980
a/
   Weighted with generalized plant action spectrum.



b/ n.s. = not significant

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                                      47
differences in pest attack is yet unknown.  Field studies (Esser 1980)
detailing crop growth under enhanced UV-B radiation do not report any
difference in natural pest attack among UV-B treatments.

    The severity of some crop diseases has also been studied under laboratory,
greenhouse, and field conditions (Table 21).  Studies by Cams et al. (1978)
on in-vitro spore germination of six fungal pathogens showed that hyaline
spores are more sensitive to UV-B radiation than are pigmented spores.  Their
tests conducted on plants grown in growth chambers also showed a similar
relationship.  Owens and Krizek (1980), however, found that in a pigmented
spore (dados porium cucumerinum),  survival was decreased with UV-B radiation.
This was due more to a delay in germ tube emergence than complete inhibition
of growth.  Other studies (Esser 1980, Biggs et al.  1984) also indicate that
there is not any clear relationship between spore coloration and UV-B
radiation effectiveness.

    Short-term growth chamber studies by Esser (1980) on three leaf fungal
pathogens showed a significant decrease in disease severity with UV-B
radiation (Table 21).  In contrast, a field study by Biggs et al.  (1984)
showed no significant difference in disease severity on leaves or seeds under
increased UV-B radiation.  However, when leaf rust-resistant and rust-
sensitive cultivars of wheat were tested, Biggs et al.  (1984) and Biggs (1985)
found that in the sensitive cultivar there were no differences up to 60 days
after planting, while 119 days after planting, disease severity increased with
UV-B radiation.  In the resistant cultivar, there were no differences in
disease severity.  These results suggest that the effects of UV-B radiation on
plant diseases can vary with pathogen, plant species, and cultivar.

    Semeniuk and Goth (1980) found significant UV-B-mediated reductions in
potato virus infection on Chenopodium quinoa.   At irradiances over 86 mW m
UV-B   (weighted with generalized plant action spectrum), no infection
occurred.  In this study, virus extract was exposed to UV-B radiation
immediately upon its application over the leaf surface.  Intuitively, viruses
should be highly susceptible to UV-B radiation since they only contain nucleic
acids covered with proteins, both of which have high UV absorption properties.
Furthermore, viroids, which are devoid of a protein coat, may be more
susceptible despite their small size.  These effects would probably be
greatest when the virus or viroids are directly exposed to UV-B radiation as
may happen during mechanical transmission.  Virus or viroids transmitted
through seed, pollen, insects, mites, nematodes, and fungi may not be as
susceptible to UV-B radiation, due to the additional cellular screening
offered by the host tissues.

    One of the plant defense mechanisms that inhibits fungal development is
the production of a class of chemicals known as phytoalexins (Bell 1981).
Uehara (1958) first demonstrated the existence of phytoalexins in soybeans,
and later Klarman and Gerdemann (1963) demonstrated their importance in
disease resistance.   Phytoalexin production in plants can be induced
artificially through mechanical injury, high temperature, the application of
fungicides and antibiotics,  and by UV-C radiation (Bridge and Klarman 1973,
Reilly 1975).  It is suggested that thymine dimers produced after UV-C
absorption by DNA are involved in the synthesis of phytoalexins (Reilly 1975).
UV-B radiation also induces isoflavonoid phytoalexin synthesis (Bakker et al.
1983),  thereby possibly having an antifungal affect  on plants;  however,  excess
production can be toxic due to free radical formation (Beggs et al. 1984).

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                                     48
    At present it is difficult to forecast the consequences of enhanced UV-B
radiation in terms of pest and disease damage.  From the limited information
available, it appears that in some cases UV-B radiation might decrease disease
severity, while in others it might aggravate it.   Coupled with reduced vigor
in plants sensitive to UV-B radiation, an increase in disease severity could
pose a considerable risk, resulting in substantial losses in crop yield.
Further studies are obviously needed to develop a better understanding of the
consequences of increased levels of UV-B radiation on pests and plant
diseases.

3.D.  Risks to yield due to competition with other plants

    The following is a summary of the potential impacts of the interactions
between UV-B radiation and plant competition.  A more comprehensive review can
be found in Gold and Caldwell (1983).  Plant resistance to a change in an
environmental stress is, in part, a genotypically controlled, species-specific
characteristic (Levitt 1980).   An alteration of an environmental stress could
thus lead to a change in the competitive balance of the plant community due to
inherent differences in plant resistance.  Many plants have been shown to
exhibit a wide range of sensitivity to enhanced UV-B radiation (for review see
Teramura 1983).  Since UV-B radiation can be considered as an environmental
stress, any increase in UV irradiance could, in turn, lead to changes in
competitive ability within plant communities through differential UV-B
resistance of the competing species (Caldwell 1977) .  Competition could occur
within the same species  (intraspecific) or between different species
(interspecific).   Intraspecific competition becomes increasingly important in
monospecific communities such as agricultural systems.  On the other hand, in
natural ecosystems with high species diversity, interspecific competition
predominates.  In agricultural systems interspecific competition could also be
important between crops and weed species.

    Gold and Caldwell (1983) studied intraspecific competition in wheat
(Triticum aestivum L.), wild oats (Avena fatua L.), and goat grass (Aegilops
cylindrica Host) at various planting densities.  The study was
conducted in the field at ambient levels of UV-B and those simulating a 16%
ozone reduction (at Logan, Utah, 40° N, based on the generalized plant action
spectrum).  There were no significant differences in shoot biomass production
at the various planting  densities with enhanced UV-B radiation for all  three
species.  This indicates that in these species, enhanced levels of UV-B
radiation may be of little consequence in terms of intraspecific plant
competition.  Preliminary results (M. M. Caldwell, unpublished data, 1985)
however,  indicate that  interspecific competition may be affected by enhanced
levels of UV radiation.  Enhanced levels of UV-B appeared  to alter growth
allocation patterns by  inhibition of internode elongation  in wild oat but not
in wheat.  This was reported to favor wheat  in competition for available
light.   Whether similar  responses occur  among other agricultural crops  is yet
to be determined.

    Solar UV exclusion  studies  in West Germany by Bruzek  (cited in Gold and
Caldwell 1983) with two  pairs of naturally  competing species show large
differences  in response  to present  levels of ambient solar UV radiation.  In a
Fraxinus excelsior/Carpinus betulus  species  pairing, reduction in shoot
biomass  with solar UV radiation was  42-14%,  respectively,  while in Rumex
obtusifolius/R. alpinus,  it was  10%  and  24%,  respectively.   This suggests that

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                                     49


current levels of UV radiation are partly responsible for interspecific
competition among various native plant species.

    Very few studies have addressed interspecific competition under enhanced
UV-B radiation.  Fox and Caldwell (1978)  and Gold and Caldwell (1983)  examined
the effects of enhanced UV-B radiation on the competitive interaction of nine
groups of field grown competing pairs from three plant associations:
agricultural crops and associated weeds,  montane forage crops, and disturbed
weedy associates.  The results are summarized in Table 22.

    To measure the competitive ability of one species when grown in mixture
with a second species, relative crowding coefficients (RCC) were used.  An RCC
of 1.0 indicates that both species have a similar competitive ability.
Species 1 has a competitive advantage when the RCC is greater than 1.0;
species 2 has the advantage when the RCC is less than 1.0.   As shown in Table
22, the RCCs based upon total above ground biomass indicate that there was a
significant shift in the competitive balance in four of the species pairs:
Medicago sativa/Amaranthus retroflexus; Triticum aestivum/Avena fatua;
Triticum aestivum/Aegilops cylindrica; Geum macrophyllum/Poa pratensis.
Amaranthus was more competitive under ambient UV conditions,  while Medicago
exhibited the competitive advantage under enhanced UV-B radiation.  In
Triticum grown under a simulated 16% ozone reduction, there was no significant
difference in competitive ability with Avena but under a 40% ozone reduction,
Triticum had a competitive advantage over Avena.  However,  in the previous
year the competitive balance was found to be just the opposite, in favor of
Avena.  It was suggested that this difference was due to a late planting,
which resulted in great water and temperature stresses during seedling
development (Gold and Caldwell 1983).  Between Triticum and Aegilops the
competitive balance was shifted in favor of Triticum under enhanced UV-B
radiation.  Similarly, Geum had the competitive advantage over Poa under
ambient conditions, but under enhanced UV-B radiation, the balance was shifted
in the opposite direction.

    Results also show that the extent of dominance can vary with UV-B
irradiance.  In the Setaria glauca/Trifolium pratense pairing, Setaria was
dominant both under ambient and enhanced UV-B levels, but under enhanced
levels the degree of dominance was expanded to a much greater extent.   On the
other hand, in the Bromus tectorum/Alyssum alyssoides pairing, although Bromus
was dominant under both ambient and enhanced UV-B levels, this dominance was
greatly reduced with enhanced UV-B radiation.  These conclusions were all
based on vegetative biomass since results on reproductive biomass, have not
yet been made available.  However, Gold and Caldwell (1983) report from
preliminary field data that the competitive ability of wheat, based on seed
biomass, increased relative to wild oats under enhanced UV-B radiation.

    Combined, these results clearly demonstrate that enhanced levels of UV-B
radiation can alter the competitive interactions of some species pairs.  The
competitive advantage of one species over the other depends upon the species
pairing and the level of UV-B irradiation.  Among the agricultural crops
studied, Medicago sativa was more affected while Triticum aestivum was less
affected by weed competition under enhanced UV-B radiation.  Since there are a
large number of weeds typically associated with various crop plants, the

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                                                             50
                             Table 22.  Relative Crowding Coefficients Based Upon Shoot Biomass
                      Under Ambient and Enhanced Levels of UV-B Radiation.  Enhanced UV-B Was Supplied
                      Via Filtered (Kodacel TA 401)  FS-40  Sunlamps.   Data  from  Gold  and Caldwell  (1983)
                                                and Fox and Caldwell (1978).
Competing Species Pair
Relative Crowding a/
Coefficient
Simulated Ozone
Plant Association
Agricultural crops
and associated
weed species




Montane forage
species
Disturbed area
weedy associates
Species 1
Alyssum alyssoides
Amaranthus retroflexus
Amaranthus retroflexus
Setaria glauca
Triticum aestivum
Triticum aestiuum
Triticum aestivum
Poa pratensis

Bromus tectorum
Plantago patagonica
Species 2 Depletion (%) b/ Ambient UV
Pisum sativum
Medicago sativa
Allium cepa
Trifolium pratense
Avena fatua
Avena fatua
Aegilops cylindrica
Geum macrophyllum

Alyssum alyssoides
Lepidium perfoliatum
40
40
40
40
16
40
16
40

40
40
0.34
3.56
1.89
2.06
1.08
1.08
0.48
0.85

6.35
0.75
Enhanced UV c/
0.25
0.73*
2.01
18.74
1.28
1.69"
1.57*
2.28*

1.63
0.68
a/ Relative crowding coefficient of 0 means  neither species  has  competitive  advantage, more  than  1 means  species  1
   has competitive advantage,  less  than 1 means  species  2  has  advantage.

b/ Simulated ozone depletion based  upon generalized plant  action spectrum (Caldwell 1971), calculated at
   Logan, UT (40°N).
c_/ Asterisk denotes a significant difference (P less  than 0.05)  between control and enhanced  UV treatment.

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                                     51
impact of enhanced levels of UV-B radiation upon agricultural systems is quite
complex, but could potentially have serious consequences if weeds have a
competitive advantage over crop plants.   Total harvestable yield, as well as
its quality, can be altered by the presence of weeds (Bell and Nalewaja 1968,
McWhorter and Patterson 1980),  even in the absence of UV.

    Interspecific competition in natural plant communities even under current
ambient UV-B radiation levels has rarely been documented through
experimentation.  Results of Caldwell and co-workers indicate that
interspecific competition can be affected by enhanced levels of UV-B
radiation.  Thus the relative species composition of many natural plant
communities could possibly change as a consequence of increased levels of UV-B
radiation.

    Caldwell (1977) suggested that because of the subtle nature of UV-B
radiation stress, an enhancement of solar UV-B radiation may more likely alter
the competitive balance of plants rather than directly affect ecosystem
primary productivity.  The results of Gold and Caldwell (1983) and Fox and
Caldwell (1978) support this hypothesis.  Except for the Pisum sativum/
Alyssum alyssoides species pair, total productivity of each species pair was
never significantly affected under enhanced UV-B radiation compared with
ambient-grown controls.  In contrast, the results of several field studies
have demonstrated that total harvestable yield may be directly affected by
UV-B radiation in agricultural systems (see Section 3.A, Direct Effects on
Total Yield).

    Because of the shifts in competitive balance reported here, increasing
solar UV-B radiation could pose a considerable risk both to agricultural, as
well as to natural, ecosystems.  In agricultural systems,  any shift toward
increasing weed competitiveness would inevitably be detrimental in an economic
sense, resulting in the need to increase tilling and/or herbicide application.
Without such measures, an increase in weed occurrence may result in reductions
in actual harvestable crop yields, a lowering in crop quality, or an
alteration in disease or pest sensitivity.  The apparent interactions of
competitive balance with other commonly experienced environmental stresses,
such as water and temperature stress, make it difficult to ascertain even the
magnitude of the risk.  Clearly, more experimental data is needed in this
area.

    Changes in the competitive balance of native species could also have
profound effects on the structure and function of natural ecosystems.
Presumably, the more UV-B-tolerant species would proliferate at the expense of
the sensitive ones.  Even very subtle differences in sensitivity could result
in large changes in species composition over time and possibly affect
ecosystem function.  Again, because of the total lack of experimental
evidence, the uncertainty is high; however, in light of the importance of this
question, the risks are considerable.

3.E.  Risks to yield due to changes in pollination and flowering

    It would seem that the reproductive tissues of plants whose pollination
and subsequent fertilization take place during the day with flowers fully open
would receive an appreciable UV-B dose.  However, ovules enclosed in the ovary
are well protected against UV-B radiation, and, therefore, female reproductive
structures would not likely be affected.  Flint and Caldwell (1983) have shown

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                                     52
in six plant species that the anther wall filters out over 98% of the incident
UV-B radiation.  Therefore,  before anther dehiscence,  pollen is also well
protected.  In-vitro experiments with pollen from numerous species demonstrate
that UV-B radiation can inhibit pollen germination (Table 23).   Sensitivity
varies among species but even relatively low levels of UV-B radiation can
inhibit germination in-vitro.  Supported by other published results, Flint and
Caldwell (1984) speculate that pollen shed in the binucleate condition would
be more susceptible to UV-B radiation damage than pollen shed in the
trinucleate condition.  This speculation is based on the knowledge that the
time course of germination and penetration of the stigma is more rapid in
trinucleate species, and, thus, these would be less exposed to a UV-B
radiation environment.  Whether inhibition of pollen germination does occur
under in-vivo conditions is yet to be determined.

    In nine plant species, Southworth (1969) found UV-absorbing compounds in
the wall of pollen, with a maximum absorbance in the UV-B range.  The proposed
role of pollen pigments also includes screening from UV radiation (Stanley and
Linskens 1974).  Furthermore, studies on the UV absorption profiles of
stigmatic surfaces and exudates of many species show one or more peaks in the
UV-B region (Martin 1970, Martin and Brewbaker 1971).   Therefore, under
natural conditions, the effectiveness of UV-B may be minimal because of
UV-absorbing pigments in the anther and pollen walls.   Upon deposition over
the stigmatic surface, pollen would further be protected from UV-B radiation
if the surface has exudates, since these often contain UV-absorbing compounds.
On dry stigmatic surfaces, UV-B radiation may still have only minor effects,
especially in trinucleate pollen because of the short time between germination
and penetration.  Furthermore, pollen absorption by the stigmatic surface also
reduces its exposure.  Although no direct experimental evidence is available
to support or refute the hypothesis proposed by Flint and Caldwell  (1984),
results from various field experiments do not substantiate a meaningful change
in grain yield or seed set under enhanced UV-B radiation.

    Flint and Caldwell (1984) reported that maximum levels of solar UV-B
radiation found in temperate latitudes were insufficient to inhibit pollen
germination in-vitro, but that the two- to three-fold greater UV-B  irradiance
incident at high elevation, low latitude environments is effective  in
partially inhibiting germination in three of the four species they examined.
This raises the question, then, whether pollen from tropical or subtropical
species respond similarly or whether it is inherently more resistant to the
greater, naturally occurring levels of UV-B radiation.  Currently, no
experimental evidence exists to help resolve this question.  Overall, it
appears that pollination at temperate latitudes may be little affected by the
present projections for increases in solar UV radiation.  However,  there  is
considerable uncertainty with regard to risks to yield due to UV-mediated
changes in pollination in tropical highlands.  Intuitively, one might
anticipate evolutionary adaptations which would protect the pollen  of tropical
species from the proportionally greater UV doses received in such
environments.  Despite its potential importance, however, the void  of
information available makes it impossible to assess this question fully at  the
present.

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                                                     53
                            Table  23.   Summary of UV-B Effect on In-Vitro Pollen Germination
Species
Petunia hybrida
Vicia villosa
Tradenscantia Clone 4430
Tradenscantia Clone 4430
Clone 02
Brassica oleracea
Cleome lutea
Papaver sp
Papaver rhoeas




Cleome lutea

Geramium viscosissiura
Scrophularia peregrina
Irradiance*
mWta UV-B
BE
67
67
67
67
67
54
56
56
35
60
68
137
170
40
60
73
73
Duration
(hours)
1.0
1.0
1.0
1.5
1.5
2.5
3.5
3.5
3.0
3.0
2.0
3.0
3.0
3.0
3.3
3.0
3.0
Germination
Inhibition
(X)
65
65
23
44
12
28
28
41
3
35
26
52
52
2
33
20
53
Reference

Campbell et al. (1975)


Chang and Campbell (1976)

Caldwell et al. (1979)




Flint and Caldwell (1984)





* Biologically effective UV-B weighted according  to the  plant  effective  action  spectrum  (Caldwell et al., 1979)

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                                     54
    During the early part of this century numerous studies on the effects of
solar UV radiation were conducted using window glass to filter out UV
radiation (see reviews by Popp and Brown 1936; Caldwell 1971).  The results
from these studies indicated an inhibition of flowering by solar ultraviolet
radiation.  However, these experiments were generally executed with
insufficient sample sizes and failed to isolate ultraviolet irradiation as the
single contributing factor causing the difference in flowering.   For instance,
Caldwell (1968) has shown that leaf temperatures under window glass are
markedly higher than under screen filters.   Such changes in temperature alone
are generally sufficient to alter the induction of flowering (Zeevaart 1976) .

    A summary of results from recent experiments under similar microclimatic
conditions is presented in Table 24.  Results of Kasperbauer and Loomis (1965)
studying Melilotus and Caldwell (1968) with Trifolium dasyphyllum show an
increase in flowering with the exclusion of solar ultraviolet radiation using
greenhouse glass or Mylar filters.  A growth chamber study by Klein et al.
(1965) incorporating primarily UV-A radiation also shows an increase in the
number of flowers produced in marigold by the exclusion of ultraviolet
radiation.  Similarly, greenhouse trials on beans and peas also show an
inhibition of flowering and decrease in flower number due to UV-B radiation
(Biggs and Basiouny 1975).

    However, field studies providing enhanced levels of ultraviolet radiation
using unfiltered sunlamps (which emit both UV-B and UV-C), produce no
significant effects on flower number or date of flowering in marigold and
tomatoes, tasseling in maize, or heading in sorghum (Hart et al. 1975).  Biggs
and Kossuth (1978), on the other hand, found an increase in flower number in
potatoes at peak flowering in UV-B irradiated plants.  However,  the duration
of flowering was longer under ambient levels of UV-B irradiance.  In contrast,
the number of flowers was significantly reduced in tomatoes after UV-B
irradiation.  Although these various observations apparently suggest changes
in flowering which correlate with ultraviolet radiation, whether this would
lead to an appreciable affect in harvestable yield has not been fully
investigated.  Biggs and Kossuth  (1978) found a stimulation of flowering and
an increase in tuber weight (grade A large) in potatoes with UV-B radiation,
while UV-B induced inhibition of flowering in tomatoes resulted in reductions
in fruit weight of 11 different maturity classes.

    These results demonstrate that UV-B radiation can have both inhibitory and
stimulatory effects on flowering, depending on the plant species, growth
conditions and other factors.  Whether UV-B radiation directly influences
flowering events or plays an indirect role through changes in photosynthate
reserves is not yet known.  Presently, no clear trends emerge on the effects
of UV-B radiation on flowering.  Therefore, there is a high degree of
uncertainty concerning the risk to yield due  to a change in the timing of
flowering.  This uncertainty is primarily due to the paucity  of experimental
evidence available at this time.  Whether alterations in flowering will  lead
to changes in harvestable yield still awaits  further experimentation.

3.F  Risks to yield due to structural plant changes affecting harvestability

    At present, no experimental study has directly addressed  the question
whether enhanced levels of UV-B radiation will alter the harvestability  of

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                                                          55
                                      Table 24.  Summary of UV Effects on Flowering
Growth Irradiation
Plant Species Condition a/ System
Melilotus G.H. unfiltered G.E.
sunlamp and glass
filtered
G.H.&F none in G.H.
ambient in F

inf lo . no
Conclusions
. declined under
unfiltered, but increased under
glass
flowered
decreased

all season in G.H. ,
with season in field
Reference
Kasperbauer and
Loomis (1965)

Kasperbauer and
Loomis (1965)
Tnfolium dasyphyllum      F
Kobresia myosuriodes
Petunia

Zea mays

Sorghum bicolor
ambient filtered
with Mylar or
Polyvinyl fluoride
Carex rupestris
Geum rossii
Oreoxis alpina
Tagetes

F
F
F
G.C.

same
same
same
unfiltered black
light b/
                                         unfiltered FS-40
increased flowering under Mylar    Caldwell (1968)
                                                               no sign, diff, but a trend of
                                                               increased flowering under Mylar

                                                               flowering under Mylar
                      exclusion of UV increased no.
                      flower buds by 80X addition of
                      UV increased no.  flowers by 12X

                      no sign,  effect

                      no sign,  effect

                      no effect on tasseling

                      no effect on heading
                                                                                                  Klein et al.  (1965)
                                                                                                  Hart et al.  (1975)

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                                                          56
                              Table 24.   Summary of UV Effects on Flowering (continued)
    Plant Species
                           Growth
                         Condition a/
   Irradiation
     System
                                                                         Conclusions
                                                                                                      Reference
Fhaseolus vulgaris         G.C.
Pisum sativus
Solanum tuberosum
                           G.C.
                                         Mylar and CA
                                         filtered FS-40
                      UV delayed flowering,  no. and
                      size of flowers
Biggs and Basiouny
(1975)
                                                               UV decreased flowering duration    Biggs and Kossuth
                                                               increased no.  open flowers at      (1978)
                                                               peak flowering
Lycopersicon esculentum    F
Glycine max
                           G.H.
Mylar and CA
filtered FS-40
                      UV decreased no. flowers on a
                      single sample date

                      no difference
Murali and
Teramura
(unpublished)
&/ GH = greenhouse, GC = growth chamber,  F = field.

b/ 70X of radiation was between 355-380 nm (UV-A).

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                                      57
field crops.  However, from morphometric changes reported in the literature,
some speculations could be made.  These speculations warrant caution because
they represent only potential and not actual circumstances.

    Crop harvestability is dependent upon crop architecture, time,  and mode of
harvesting.  Crop architecture can be broadly grouped into 1) row type (e.g.,
cereals), 2) bushy (e.g., beans and tomatoes), and 3) trees.  Crops are
harvested either during final maturity as in cereals and legumes or at regular
intervals as in alfalfa or other forage crops or fruits.  Harvesting can be
performed either manually or mechanically,  or both.  Changes in the
harvestability of five crops are reported here as representative of potential
scenarios.

    Case 1. cereals (row crop).  Harvestability of cereal crops, either
mechanically or manually, depends upon the occurrence and extent of lodging.
Losses would be heavy if there is a high degree of lodging,  especially when
harvested mechanically since no efficient mechanism for lifting plants without
shattering grains has been developed.  Most modern cultivars are highly
resistant to lodging because of short and sturdy culms.  However, under high
sowing densities or excessive nitrogen supply, coupled with ample soil
moisture, these cultivars tend to grow taller and occasionally lodge severely
during storms.   Furthermore, culms can break in strong winds resulting in
goosenecking of panicles.  Enhanced levels of UV-B radiation generally reduces
plant height in cereals (Table 25).  Such an effect would have a positive
effect on the harvestability of cereals by decreasing their susceptibility to
lodging.

    Case 2. tomatoes (bushy crop).  Tomatoes are grown either for fresh market
or processing.   The former is mainly of indeterminate and the latter of
determinate type.  In indeterminate tomatoes, plants are pruned to remove the
lateral buds/branches and staked because of their viney nature.  These are
highly labor-intensive operations.  Hart et al. (1975) reported an inhibition
of branching with no reduction in fruit number or size due to enhanced UV-B
irradiance in field-grown tomatoes (cultivar Fire ball).  This suggests that
increasing UV-B levels could potentially have a favorable effect on tomato
culture by minimizing the labor requirement for pruning.  Presently, it is not
known whether pruning or UV-induced inhibition of lateral branching will
result in greater yields due to reallocation of resources to the main stem.
Larger fruits may possibly be produced by the removal of lateral branches due
to the diversion of photosynthate.  Another advantage of UV-induced inhibition
of lateral branching concerns the earliness of ripening.  For instance, it is
known that with fewer branches, ripening occurs earlier in indeterminate
types.   Thus, early-season market requirements can be met by the reduction of
branching.   An increase in UV-B radiation could also favor a longer period of
staggered production due to early ripening and thus an improved distribution
of fruit for harvesting.  At higher latitudes, where the growing season is
shorter, earliness in ripening can be an advantage to a grower.

    Tomatoes grown for processing are primarily of the determinate type.
Because of their uniform ripening they can be mechanically harvested.  In
mechanical harvesting, one of the prerequisite characteristics is the ease of
separation of fruits from stems and leaves.  Fruits can be generally separated
more easily when there are fewer branches,  ceteris paribus.   Thus,  UV-mediated
inhibition of branching could also increase mechanical harvestability of
tomatoes.

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                                58
Table 25.   Summary  of UV-B Effects on Plant Height of Cereals
Crop Growth Condition
Sweet corn (Zea mays) Field




Sorghum (Sorghum vulgare)
Sweet corn (Zea mays) Greenhouse

Wheat (Triticum aestivum) Growth Chamber

Barley (Hordeum vulgare) Growth Chamber

Com (Zea mays) Growth Chamber

Millet (Pennisetum glaucum) Growth Chamber

Oats (Avena sativa) Growth Chamber

Rice (Oryza sativa) Growth Chamber

Rye (Secale cereale) Growth Chamber

Corn (Zea mays) Field
Barley (Hordeum vulgare) Growth Chamber

Wheat (Triticum aestivum) Growth Chamber

UV-B Irradiance
1.0-1.7 UV-B
Beltsville Sun
Equivalents
Unfiltered FS-40
Sunlamps

-2
131-225 mWm
UV-B (plant)
BE
0.5 to 2.0 UV-B
Sun Equivalents
0.5 to 2.0 UV-B
Sun Equivalents
0.5 to 2.0 UV-B
Sun Equivalents
0.5 to 2.0 UV-B
Sun Equivalents
0.5 to 2.0 UV-B
Sun Equivalents
0.5 to 2.0 UV-B
Sun Equivalents
0.5 to 2.0 UV-B
Sun Equivalents
8-16% 0 red.
1060-1760
-2 -1
Jm -day
UVB (Plant)
BE
1060-1760
-2 -1
Jm -day
UVB (Plant)
BE
% Relative Change
in Plant Height References
+14 to -3 Ambler et al. (1978)




- 1 to +3 Ambler et al. (1978)
-15 to -22 Allen et al. (1977)

-5 to -22 Biggs and Kossuth (1978)

-14 to -22 Biggs and Kossuth (1978)

-14 to -28 Biggs and Kossuth (1978)

-13 to -20 Biggs and Kossuth (1978)

-9 Biggs and Kossuth (1978)

-4 to -13 Biggs and Kossuth (1978)

-21 Biggs and Kossuth (1978)

+1 to +5 Biggs et al. (1984)
-1 to -12 Dumpert (1983)

-1 to -2 Dumpert (1983)


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                                      59
    Case 3. cotton (bushy crop).  Grading the quality of cotton harvested
mechanically or manually depends on the degree of contamination, especially
from dried leaves.  Although defoliants are used before mechanical picking,
the extent of leafiness still can have a direct bearing upon harvestability.
Intuitively, the more leafy the crop, the greater the probability of
contamination.  Biggs and Kossuth (1978) found a significant increase  (9 to
16%) in leaf area produced under enhanced levels of UV-B radiation in  cotton
(Gossipium hirsutum).   Unfortunately, they did not evaluate cotton yield or
quality to determine whether the increase in leafiness had any deleterious
effects.

    Case 4. tobacco (bushy crop).  The mechanical harvesters presently
designed and used for tobacco are more effective in cultivars with leaves
oriented in an upright fashion.  Since larger leaves tend to droop, cultivars
with smaller leaves are better suited for mechanical harvesting.  To date,
there are no experimental data on morphological changes arising from enhanced
levels of UV-B radiation in tobacco.  However, studies conducted with  numerous
crop plants show a general reduction in leaf area (Teramura 1983).  On the
other hand, an increase in leaf area as found in cotton (Biggs and Kossuth
1978), could pose some difficulty for mechanical harvesting.

    Case 5. fruits (tree crop).  Phytohormones such as ABA and ethylene
regulate fruit abscission.  Biggs and Kossuth (1978) reported an increase in
both ABA and ethylene with enhanced levels of UV-B radiation in bean plants.
Currently, it is not known whether such a response is general in nature and
elicited in tree fruits.  If so, there is the possibility that fruit may be
abscissed prior to reaching maturity, resulting in considerable economic
losses.

4.  SUMMARY AND CONCLUSIONS

    Global UV-B radiation varies diurnally and seasonally because of changes
in solar angle,  stratospheric ozone concentration,  degree of cloud cover, etc.
Presently, most investigators evaluate the effects of UV-B radiation using a
constant UV-B supplied via simple lamp systems without considering these
temporal changes in UV-B irradiation.  This results in an oversupplementation
of UV during periods of low solar angle (morning and afternoons) and during
overcast skies.

    The effects of UV-B radiation in producing a plant response is highly
wavelength dependent.   In evaluating the effectiveness of UV-B'radiation, more
than 10 action spectra have been developed and used by various investigators.
Since these action spectra vary tremendously many of the experimental  data
from various UV-B studies are not directly comparable.   Thus,  a realistic
action spectrum developed under more natural conditions must be developed and
used in all future experiments.

    There are 10 major terrestrial plant ecosystems in the world and these
include  314 plant families.   The effects of enhanced levels of UV-B have been
studied in only four of these ecosystems and in only 6% of the plant families.
UV effects have  been examined in only about a third of the plant growth forms
and in many,  such as vines,  epiphytes,  small woody shrubs,  etc.,  virtually no
data exists.   Most of  our knowledge of UV effects is derived from studies
focused upon agricultural crops,  yet crop yield has been evaluated in only 22
species  from 7 plant families.   Overall,  very little information is available

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                                      60
on the effectiveness of UV-B radiation on other economically important plants
such as trees and forage grasslands and especially on native plant species.
To adequately address the question of what potential impacts enhanced levels
of UV-B radiation will have on global terrestrial plant communities and
ecosystems, many unrealitic assumptions must be made.  For example, to assess
the potential impacts on forest communities, we must assume that perennial
woody trees and shrubs respond similarly to annual agricultural crops.
Clearly more data would be needed before any attempt for realistic projections
on a global scale could be made.

    Plant responses to increased levels of UV-B radiation vary markedly both
among (interspecific) and within (intraspecific) plant species.  At present,
the bases for these inherent differences have not yet been well documented.
There are three general categories cf UV-protective mechanisms which may be
involved in producing this variation in responses.  The first includes repair
mechanisms, such as photoreactivation, which is an enzyme mediated,
light-activated process.  Although not specifically demonstrated in plant
tissues, various experimental results suggests it is a widespread phenomenon.
Excision repair is the process whereby potentially deleterious photoproducts
of UV absorption are removed and replaced by new, correct DNA sequences.  This
is clearly demonstrated and is a widespread phenomenon in plants.
Postreplication repair involves the replication and combination of intact DNA
strands over damaged ones, but is yet unknown in plant tissues.

    The second category of protective mechanisms are those that tend to
minimize the damaging effects of UV-B radiation.  Probably the most important
of these is growth delay, which allows time for other repair mechanisms to
correct the damage.  The last category involves those which effectively reduce
the amount of UV-B radiation reaching sensitive targets.  The most widespread
mechanism in plants is probably the selective absorption by UV-absorbing
pigments such as flavonoids in outer tissue layers.  Some studies show that
despite a large increase in flavonoids, the photosynthetic machinery is still
adversely affected by UV-B radiation.  Therefore the inherent inter- and
intraspecific differences in UV-B sensitivity are probably the product of a
number of natural UV protective mechanisms acting in concert within the plant.
More information is critical to refine our understanding of natural plant
protective mechanisms which may potentially help compensate damage arising due
to the anticipated increase in solar UV-B radiation.

    Large  intraspecific differences in UV-B sensitivity have been reported,
which are not merely the result of gross morphological or physiological
differences, as might commonly occur interspecifically.  Crop breeding could
be used as a tool to minimize the deleterious effects of UV-B radiation if a
thorough understanding of the genetic bases for these differences were
understood.  Despite the evidence of UV-tolerant cultivars supporting the
notion that crop breeding may limit the deleterious  impacts of enhanced solar
UV-B radiation, a large degree of uncertainty still  remains in the absence of
any information on the genetic bases for these  differences.

    Much of our understanding of the effects of UV-B radiation on plants  is
derived from studies conducted under artificial growth conditions  (growth
chamber or greenhouse) which neither quantitatively  nor qualitatively resemble
field conditions.  Of utmost concern  is that plants  are apparently more
sensitive  to a given UV-B dose in artificial growth  conditions compared with
field conditions.  The  theoretical basis for increased susceptibility is  that

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                                      61
 under  artificial  conditions  only  a  single  factor  is  generally manipulated,
 while  all  other factors  are  kept  constant  or  optimized  for  growth.  Under
 field  conditions, however, plants typically experience  multiple  stresses
 (water, nutrients, etc.)  simultaneously.   Few studies have  examined the
 interaction between other commonly  experienced stresses and UV-B radiation.
 Both water and nutrient  stresses  apparently increase plant  tolerance  to UV-B
 radiation  by  stimulating the production of UV screening chemicals.  Artificial
 growth environments can  provide valuable information on the interaction
 between UV-B  radiation and other  environmental factors;  however,  they cannot
 be used in place  of actual field validation studies  where a host of complex
 natural interactions occur.  It is  concluded  that when  extrapolations from
 controlled environments  are  made  into  the  field,  they must  be done so with
 extreme caution.  At best, general  trends  may be  implied, but specific or
 quantitative  extrapolations  do not  yet seem plausible.

    Atmospheric CO- concentration has been steadily  increasing over the
 centuries, but at an alarmingly faster rate during the  past two  decades.  To
 date,  no information is  available on the effects of  UV-B radiation under
 increased  atmospheric CO  concentrations;  however, some speculations  could be
 made.  In  general, enhanced  levels  of UV-B radiation has a  negative effect,
 while  CO-  has a positive  effect, on the growth and development of plants.
 Since  the  positive effects of CO- are generally greater than the negative
 effects produced by UV-B  irradiation, the  combination of these two
 environmental changes might  lead to a compensation of some  of the deleterious,
 direct effects of UV-B radiation.   Therefore,  more subtle,  indirect effects
 may be those most critically affected.  Both  UV-B and CO- have been shown to
 alter  the  competitive balance among various plant associations.  Changes in
 competitive balance, especially in  agricultural systems  between  crops and
 weeds  could produce subtle,  yet economically  catastrophic changes.  Shifts in
 competitive ability among native species could lead  to  changes in community
 composition and structure, with ultimate large-scale ecosystem modifications.
 Considering the lack of any  experimental data on the actual interaction
 between UV-B and CO   there  is a high degree  of uncertainty in the assessment
 of the possible global effects of enhanced levels of UV-B radiation in an
 elevated CO- atmosphere.

    In all of the industrialized countries in the world, ground-level air
 pollution  (oxides of nitrogen,  sulphur dioxide, fluoride, and ozone)  is
 rapidly increasing.   In many cases these pollutants have already had
 detrimental effects on plant productivity.   At present,  no  experimental data
 are available on the interactions between UV-B radiation and these various
 other air pollutants.   However,  since most air pollutants have deleterious
 effects on plants, it is  anticipated that  the  effects of UV-B would be
 additive.

    Only a handful of field studies have examined the effects of UV-B
 radiation on crop yield.   Despite a broad range of experimental protocols and
 dosimetry,  in nearly half of the plant species examined, UV-B radiation
 produced a deleterious effect on yield.  Although reductions in yield were
 reported for some crops,  this result should be evaluated with caution since
most studies lasted for only a single growing season.  Field studies conducted
 over several years show large annual variation in response.   Only two studies
have evaluated the effects of UV-B radiation on the quality of crop yield,  and
both reported reductions.  Overall,  UV-B radiation deleteriously affects both
 the quantity and quality  of crop yield, but the magnitude of the effect is

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                                     62
highly variable from one year to another.   Longer-term field studies are
essential for realistic assessments of the impact of increased levels of solar
UV-B radiation on the quantity and quality of global crop productivity.

    Crop yield is also affected by factors such as the occurrence of pests and
diseases, weeds,  problems associated with pollination, etc.   Several studies
have specifically examined the effects of UV-B radiation on the severity of
pest and disease incidence.   Although some of these results suggest that UV-B
can have potentially beneficial effects on pest control, these must be
interpreted cautiously since the observation period was very short.  The
effects of UV-B radiation on plant diseases was equivocal, varying with
pathogen, plant species, and cultivar.  One study reported that UV-B radiation
significantly reduced virus  infection transmitted mechanically.  However,
virus or viroids transmitted through seeds, pollen, insects, or nematodes may
not be as susceptible to UV-B radiation due to the additional cellular
screening offered by the host tissue.  UV-B radiation may further reduce yield
by increasing the incidence  of pests and diseases, or in other instances
potentially have beneficial  effects on pest and disease control.  Lack of
sufficient information leads to a high degree of uncertainty in the projection
of the impact of enhanced solar UV-B radiation on pest and diseases.

    Numerous agricultural and native plant species are differentially affected
by UV-B radiation, which could ultimately lead to changes in the competitive
balance within plant communities.  In agricultural situations, there may be a
shift in the competitive ability of weeds, resulting in the need for increased
production costs (tillage, herbicides, etc.).  Without such measures, an
increase in weed competition would reduce the quantity and quality of yield.
Once more, the lack of experimental evidence precludes more detailed
assessment.

    In-vitro experiments with pollen from numerous species show that even
relatively low levels of UV-B radiation can inhibit pollen germination.
However, whether a similar response occurs in-vivo has yet to be determined.
Both the pollen wall and stigmatic surfaces have UV-absorbing pigments,  thus
under natural conditions the effectiveness of UV-B may be minimized.
Observations from various field experiments do not indicate any substantial
change in the seed set which would support this notion.  Therefore,  it appears
that the projected increase in UV-B radiation may not affect pollination.

     Only two field studies have investigated the effects of UV-B  radiation on
flowering.  Based upon this limited information, UV-B may affect flowering in
some plants, but possibly without any affect on yield.  However, the absence
of conclusive information makes it impossible to further assess the  impact of
UV-B radiation on pollination and flowering.

    No experimental information is available on UV-induced  structural changes
which might affect the harvestability of  field crops.  However, on the basis
of reported morphometric changes, some speculations were made  on five crops.
UV-B radiation may potentially have a beneficial effect by  reducing  the  labor
cost for pruning in some crops and stimulate ripening for early season market.
UV-B radiation has been  shown to increase  leaf area in  cotton, which may
reduce cotton quality because of higher levels of contamination from dry
leaves.  In cereals, UV-B reduces internode length and  thus the height of  the
plant.   This may have a  positive effect on the harvestability  of cereals by
decreasing their susceptibility to lodging.  UV-B may also  increase  mechanical

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                                      63
harvesting efficiency in some crops by decreasing leaf area.  It is reported
that UV-B radiation increases both ABA and ethylene production in some plants.
Since phytohormones regulate fruit abscission, UV-B radiation may result in
considerable economic losses by abscissing fruit prior to maturity.  Overall,
it appears that increased levels of UV-B may be beneficial to the
harvestability of some crops, while others might be negatively affected.

5.  RECOMMENDATIONS

    A plethora of experimental approaches, equipment and dosimetry have been
utilized in the numerous studies presented in various earlier sections.  One
major consequence of such experimental diversity is the difficulty in
interpreting data for comparative purposes.  In a worst-case example, consider
the field studies conducted with unfiltered fluorescent sunlamps that emit
short wavelength UV-C radiation.  Caldwell (1977) calculated that even in the
unlikely event of a catastrophic 907, stratospheric ozone depletion, almost no
energy would be emitted at wavelengths shorter than 280 nm (in the UV-C
waveband).  Furthermore, evidence suggests that the effects of the UV-C
waveband may differ both quantitatively and qualitatively from effects of UV-B
radiation (Nachtwey 1975).   Since unfiltered lamps emit energy both in UV-C
and UV-B wavelengths, such studies have virtually no utility in estimating the
potential impacts of increasing solar UV-B radiation reaching the earth's
surface.  To have any ecological relevance, UV lamps must be filtered to
remove the UV-C component.

    The most common UV sources used for plant effects research are the Philips
TL 40/12 fluorescent sunlamps filtered with Schott cut-off absorption filters
(WG series), used primarily by European investigators, and the Westinghouse
FS-40 fluorescent sunlamp filtered with cellulose acetate plastic films used
exclusively by U.S. investigators.  The Philips lamps have a considerably
greater UV emittance than the Westinghouse ones, and the two filtered lamp
systems differ in spectral energy distribution (Caldwell et al.  1984).
Therefore, it is crucial that the same weighting functions be used when
comparing experiments using different UV irradiation systems.  As the
difference between spectral distributions increases (for example when
comparing high- and low-pressure mercury vapor lamps) the choice of the action
spectrum becomes more critical (see Appendix A, Action Spectra and their Key
Role in Assessing Biological Consequences of Solar UV-B Radiation Change).
Since FS-40 lamp output decreases rapidly (20%) during the first 100 hours of
use, it is recommended that lamps be pre-aged prior to use (Teramura et al.
1980).

    The UV-B irradiation emitted along the length of a fluorescent tube varies
greatly.  Maximum emittance occurs in the middle third of the lamp and this
diminishes rapidly near the ends, where emittance may be only 50% of maximum.
This can be graphically seen in Figure 4 showing the normalized irradiance
0.5 m beneath a Westinghouse FS-40 lamp array.  The array consisted of six
parallel lamps (shown by arrows), and measurements were made each 10 cm in a
2.3 square meter area directly beneath the lamps.  Plants grown in the middle
0.6 m^ of such an array receive a relatively uniform irradiance which varies
by less than 10%.  Therefore, it is recommended that lamps be oriented
perpendicular to experimental plant rows, rather than in an end-to-end
fashion.  Although an end-to-end orientation is much more economical, plants
beneath such an irradiation system would receive a highly variable UV dose,
ultimately producing an appreciable degree of experimental error (in a

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                                       64
25  30  34  39  41  45  45  45  48   45   45   45   45  43  41   39  36  32  23
30  36  43  52  55  59  61  59  64   64   61   59   59  57  55   50  48  41  34
36  48  55  61  68  61  73  68  77   77   75   61   73  57  66   64  57  48  41
43  52  61  70  77  80  84  84  86   86   86   84   82  80  75   70  64  57  45
45  59  68  77  84  89  91  93  93   93   91   91   91   39  82   77  68  59  48
48  59  70  80  89  91  95  98  100  98   98   95   93  89  86   77  73  61  50
52  59  70  80  89  93  95  98  100 100  98   98   93  93  86   80  73  61  50
48  59  68  75  86  91  93  95  98   95   95   93   91   89  82   80  68  59  50
43  55  64  70  80  84  89  91  91   89   89   89   89  82  77   73  64  57  45
36  48  57  61  68  73  30  82  80   77   55   77   77  73  68   64  57  50  41
27  39  45  50  57  61  61  64  66   66   64   64   61   57  55   52  45  41  32
18  27  34  36  41  45  48  48  50   48   48   45   45  45  41   39  32  30  23
   Fig. 4   Normalized irradiance 0.50m beneath a single UV-B lamp array.
            Measurements were made each 100  cm2 with lamps positioned at 0.30m
            centers (actual lamp position indicated by arrows).

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                                      65
statistical sense).   It is likely that the larger error associated with such a
variable dose could mask some of the subtle UV-B radiation effects, and
therefore not be a reliable test.

    The level of visible radiation supplied during growth has profound effects
on plant sensitivity to UV-B radiation (see Section 2.C, Issues Associated
with the Extrapolation of Data from Controlled Environments into the Field).
Therefore, caution must be exercised in controlled environment studies to
maintain an adequate level of visible radiation.  Since leaf anatomy and
photosynthetic characteristics have been shown to be related to the daily
integrated levels of visible radiation (Chabot et al. 1979, Nobel and Hartsock
1981),  it is recommended that the daily dose of visible radiation be in an
ecologically realistic range wherever possible.

    In nearly all field experiments, supplemental UV-B radiation is provided
as a squarewave, simply by turning lamps on or off with the use of timers.
Natural solar UV irradiance,  in contrast, gradually increases on a daily basis
with a peak at solar noon that coincides with peak visible irradiances.
Therefore under artificial lamps producing a squarewave function,
proportionately more UV is provided during the periods of low solar altitudes
(mornings and late afternoons) compared with natural solar UV.  This results
in a greater simulated ozone reduction during these periods.  Of even greater
concern, however, is that such a squarewave is generally supplied during
cloudy and overcast skies, when the levels of ambient UV may be less than 50%
of clear sky irradiances due to the absence of the direct beam component.
During these periods, the lamps would supply a UV dose equivalent to a much
greater ozone depletion than originally intended when the lamps were
calibrated for clear sky conditions.  More realistic field validations of
anticipated ozone depletion may be made using a modulated lamp system as
described by Caldwell et al.  (1983b).   Such a system would reduce the errors
cited above by providing UV as a sinewave during clear sky conditions and
modulate lamp output during cloudy or overcast skies.  A further advantage in
a modulated system would be a reduction in the frequency of filter changes
necessary (currently once every 4-7 days for most investigators) since the
system would correct for filter solarization.   The disadvantage with such a
system is the additional project cost.   Estimates for building a modulated
system range between $1,000 to $1,500 per unit (Caldwell personal
communication),  and one unit would be necessary to control an array of six
lamps.   In the field study conducted by Teramura (1981), 60 such modulated
systems would be necessary.  Despite the additional expense, such a refinement
could greatly improve the field simulation and sensitivity of ongoing and
future field validation studies.   In light of the great risks posed to global
crop yield and quality loss resulting from a projected increase in UV-B
radiation reaching the earth's surface, such an investment seems well
warranted and therefore highly recommended.

    Instrumentation to measure UV-B radiation has essentially evolved along
with project needs during the past decade.  The current spectroradiometer used
by U.S. scientists involved in plant effects research is the Optronics
(Orlando, Florida) Model 742,  with a double monochrometer and dual halographic
grating specifically designed to measure the UV spectral irradiance of
sunlight.  Although this instrument is  excellent in laboratory situations, it
is not ideally suited for field measurement.   Several investigators have made
some extensive modifications  which have greatly improved its ability to
function in the field.   For instance,  Caldwell (personal communication) has

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                                      66


installed a Peltier cooling device to keep the photomultiplier tube at a
uniform temperature, enabling the spectroradiometer to operate in a
temperature range typically found in the field (30-40°C) .   It is recommended
that this equipment modification as well as others be made (perhaps in
conjunction with Optronics) to improve the reliability of our field
measurements.

    The recommendations made above are suggestions which will help improve
field experimental design and measurement and help limit extraneous variations
which may mask any true UV-induced biological effects.  More importantly,
however, an adoption of standardized protocols and dosimetry will greatly aid
in the interpretation and intercomparison of field collected data and provide
a reliable basis from which to assess the potential impacts of stratospheric
ozone depletion.

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                                      67
6.  LITERATURE CITED

Allen, L.H. Jr.,  C.V.  Vu,  R.H.  Berg III and L.A.  Garrard, 1977.  Impact of
    solar UV-B radiation on crops and crop canopies.   Final Report, UV-B
    Biological and Climatic Effects Research (BACER),  EPA, Washington, B.C.

Ambler, J.E., R.A. Rowland and N.K. Maher,  1978.   Response of selected
    vegetable and agronomic crops to increased UV-B irradiation under field
    conditions.  UV-B Biological and Climatic Effects  Research (BACER), Final
    Report EPA-IAG-D6-0168, EPA, Washington, D.C.

Antonovics, J., 1975.   Predicting evolutionary response of natural populations
    to increased UV radiation.   In Climatic Impact Assessment Program (CIAP),
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    8-7 - 8-27.  U.S.  Dept. Transport,  Report No.  DOT-TST-75-55,  National
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Bakker, J., F.J.  Grommers, L.  Smits,  A. Fuchs and F.W. de Vries,  1983.
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Bartholic, J.F.,  Halsey,  L.H.  and L.A.  Garrard, 1975.   Field trials with
    filters to test for effects of UV radiation on agricultural productivity.
    In Climatic Impact Assessment Program (CIAP),  Monograph 5 (Nachtwey, D.S.,
    Caldwell, M.M. and Biggs,  R.H., eds.),  pp.  61-71.   U.S. Department of
    Transportation, Report No.  DOT-TST-75-55, National Techn. Infor. Serv.,
    Springfield,  Virginia.

Becwar, M.R., F.D. Moore III and M.J. Burke, 1982.  Effects of deletion and
    enhancement of ultraviolet-B (280-315 nm) radiation on plants grown at
    3000 m elevation.   J.  Amer. Soc.  Hort.  Sci. 107:771-779.

Beggs, C.J.,  U. Schneider-Ziebert and E.  Wellmann, 1986.   UV-B radiation and
    adaptive mechanisms in plants.  In Stratospheric  Ozone Reduction,  Solar
    Ultraviolet Radiation and Plant Life  (R.C.  Worrest, ed.) Springer-Verlag.
    ISBN 13875-7.

Bell, A.A., 1981.   Biochemical mechanisms of disease  resistance.   Ann. Rev.
    Plant Physiol. 32:21-81.

Bell, A.R. and J.D. Nalewaja,  1968.  Competition  of wild oats in wheat and
    barley.  Weed Sci. 16:505-508.

Bennett, J.H., 1981.  Photosynthesis and  gas diffusion in leaves of selected
    crop plants exposed to ultraviolet-B  radiation.  J. Environ.  Qual.
    10:271-275.

Biggs, R.H.,  1985.  Effects of enhanced ultraviolet-B  radiation (280-320 nm)
    on soybean, wheat, corn, rice, citrus,  and duckweed.   EPA Progress Report
    CR-811216.  Washington, D.C.

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                                     68
Biggs, R.H.  and F.M.  Basiouny,  1975.   Plant growth respones to elevated UV-B
    irradiation under growth chamber,  greenhouse,  and solarium conditions.   In
    Impacts  of Climatic Change  on the  Biosphere CIAP Monograph 5 (Nachtway,
    D.S., Caldwell,  M.M.  and Biggs,  R.H.,  eds.) pp.  4-197-4-248.  U.S.
    Department of Transportation, Report No.  DOT-TST-75-55, National Techn.
    Info. Serv. Springfield, Virginia.

Biggs, R.H.  and S.V.  Kossuth, 1978.   Effects of ultraviolet-B radiation
    enhancement under field conditions on potatoes,  tomatoes, corn,  rice,
    southern peas, peanuts, squash,  mustard and radish.   UV-B Biological and
    Climatic Effects Research (EAGER),  Final Report, EPA, Washington, D.C..

Biggs, R.H., S.V. Kossuth and A.H. Teramura,  1981.  Response of 19 cultivars
    of soybeans to ultraviolet-B irradiance.   Physiol.  Plant.  53:19-26.

Biggs, R.H., P.G. Webb, L.A. Garrard,  T.R. Sinclair, and S.H. West,  1984.   The
    effects  of enhanced ultraviolet-B radiation on rice, wheat, corn, soybean,
    citrus,  and duckweed.  Year 3 Interim Report.   Environmental Protection
    Agency Report 808075-03, EPA, Washington, D.C.

Bogenrieder, A. and Y. Doute, 1982.   The effects of UV on photosynthesis and
    growth in dependence of mineral nutrition (Lactuca sativa L. and Rumex
    alpinus  L.).  In Biological Effects of UV-B Radiation  (H. Bauer, M.M.
    Caldwell, M. Tevini and R.C. Worrest,  eds.), Gesellschaft fur Strahlen-und
    Umweltforschung mbH Munchen, pp.  164-169.

Bogenrieder, A. and R. Klein, 1978.   Die abhangigkeit der UV-empfindlichkeit
    von der lichtqualitat bel der aufzucht (Lactuca sativa L.).  Angew.
    Botanik 52:283-293.

Brasseurl, G. and A. de Rudder, 1984.   Agent and effects of ozone trends in
    the  atmosphere.  In Stratospheric Ozone Reduction,  Solar Ultraviolet
    Radiation and Plant Life (R.C. Worrest, ed).  Springer-Verlag.  ISBN
    13875-7.

Bridge, M.A. and W.L. Klarman,  1973.   Soybean phytoalexin hydroxyphaseollin,
    induced by ultraviolet  irradiation.  Phytopathol. 63:606-608.

Caldwell, M.M., 1968.  Solar ultraviolet radiation as an ecological factor for
    alpine plants.  Ecolo. Monogr. 38:243-268.

Caldwell, M.M., 1971.  Solar UV irradiation and the growth and development of
    higher plants.  Photophysiol. VI (Giese, A.C., ed.), pp. 131-177.
    Academic Press, New York.

Caldwell, M.M., 1977.  The  effects of solar UV-B  (280-315  run) on higher
    plants:   Implications  of stratospheric ozone reduction.  In Research in
    Photobiology  (A. Castellani,  ed.), pp. 597-607.  Plenum Publ. Corp., New
    York.

Caldwell, M.M., 1981.  Plant response to solar ultraviolet radiation.  In
    Encyclopedia  of Plant  Physiology New Series, Volume  12A.  Physiological
    Plant Ecology I  (Lange, O.L., Nobel, P.S., Osmond, C.B., and Ziegler, H.,
    eds.).  Springer-Verlag, Berlin, Germany, pp. 169-197.

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                                     69
Caldwell,  M.M.,  1982.   Geometric considerations:   A brief synopsis.   In
    Biological  Effects of UV-B Radiation (H.  Bauer, M.M.  Caldwell, M.  Tevini
    and R.C.  Worrest),  pp. 142-144 Gesellschaft fur Strahlen-und
    Umweltforschung mbH Munchen.

Caldwell,  M.M.,  1983.   Solar UV-B radiation and higher plants:   Photosynthetic
    inhibition  and acclimation.   Annual Report for EPA.  EPA,  Washington,  D.C.

Caldwell,  M.M.,  R. Robberecht, S. Holman,  R.  Nowak, L.B.  Camp,  S. Flint,
    G.  Harris,  and A.M. Teramura, 1979.  Higher plant responses to elevated
    ultraviolet irradiance.   Annual Report 1978 NAS-9-14871, NASA, Dept.  Range
    Sci.  & Ecology Center, Utah State Univ.,  Utah.

Caldwell M.M.,  R.  Robberecht and W.D. Billings, 1980.  A steep latitudinal
    gradient of solar ultraviolet-B radiation in the artic-alpine life zone.
    Ecology 61:600-611.

Caldwell,  M.M.,  R. Robberecht, and S.D. Flint, 1983a.  Internal filters:
    Prospects for UV-allimation in higher plants.   Physiol.  Plant.
    58:445-450.

Caldwell,  M.M.,  W.G. Gold, G. Harris and C.W. Ashurst, 1983b.   A modulated
    lamp system for solar UV-B (280-320 nm).   Supplementation studies in the
    field.  Photochem.  Photobiol. 37:479-485.

Caldwell,  M.M.,  W.B. Sisson, F.M. Fox and J.R. Brandle, 1975.   Plant growth
    response to elevated UV irradiation under field and greenhouse conditions.
    In Climatic Impacts Assessment Program (CIAP), Monograph 5 (Nachtwey,
    D.S.,  Caldwell, M.M. and Biggs,  R.H.,  eds.),  pp. 4-243 to 4-249.  U.S.
    Department  of Transportation, Report No.  DOT-TST-75-55,  National Techn.
    Info.  Serv.,  Sprinfield, Virginia.

Caldwell,  M.M.,  L.B. Camp, C.W.  Warner and S.D. Flint, 1986.  Action spectra
    and their key role in assessing biological consequences  of solar UV-B
    radiation change.   In Stratospheric Ozone Reduction,  Solar Ultraviolet
    Radiation and Plant Life, (R.C.  Worrest,  ed.), Springer-Verlag.   ISBN
    13875-7.

Campbell,  W.F.,  M.M. Caldwell, and W.B. Sisson, 1975.  Effect of UV-B
    tadiation on pollen germination.  In Impacts of Climatic Change on the
    Biosphere,  CIAP Monog. 5., Department of Transportation, Washington,  D.C.,
    pp. 4-227 to 4-276.

Cams,  H.R.,  J.H.  Grahm, and S.J. Ravitz,  1978.  Effects of  UV-B radiation on
    selected leaf pathogenic fungi and on disease severity.   EPA-IAG-D6-0168.
    EAGER Program, EPA, Washington,  D.C.

Chabot, B.F., T.W. Jurik and J.F. Chabot,  1979.  Influence of instantaneous
    and integrated light-flux density on leaf anatomy and photosynthesis.   Am.
    J.  Bot. 66:940-945.

Chang,  D.C.N. and W.F.  Campbell, 1976.  Responses of tradescantia stamen
    hairs and pollen to UV-B irradiation.   Envi.  Exp. Bot. 16:195-199.

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                                     70
Cronquist,  A.,  1981.   An integrated system of classification of flowering
    plants.  Columbia University Press,  New York,  p.  1262.

Dickson,  J.G.  and M.M.  Caldwell, 1978.   Leaf development of Rumex patLentLa
    L.  (polygonaceae) exposed to UV irradiation (280-320 run).   Amer.  J.  Bot.
    65:857-863.

Dumpert,  K.,  1983.   Einfluss erner nach schadstoffimmission vermehrten UV-B
    strahlung auf kulturpflanzen.   Bericht fur Gesellschaft fur Strahlen-und
    Umweltforschung mbH Bereich Projekttragerschaften Munchen.

Dumpert,  K. and J.  Boscher,  1982.   Response of different crop and vegetable
    cultivars to UV-B irradiance:   Preliminary results.   In Biological Effects
    of UV-B Radiation (H.  Bauer, M.M.  Caldwell, M. Tevini and R.C. Worrest,
    eds.),  pp.  102-107.   Gesellschaft  fur Strahlen-und Umweltforschung mbH,
    Muchen.  ISBN 0721-1694.

Eisenstark, A.  and G. Perrot, 1985.  Enhanced UV-B irradiation (290-320 nm) of
    corn (Zea mays L.).   II. Effects of various stages of tassel formation
    (greenhouse-plants).  Submitted to J. Agronomy.

Eisenstark, A.,  G.H.  Perrot, G. Ulmer,  and C.D. Miles, 1985.  Enhanced UV-B
    irradiation (290-320 nm) of corn (Zea mays L.) I. Effects on growth and
    yield.   Manuscript submitted to J.  Agronomy.

Esser,  G.,  1979.  Einfluss einer nach  schadstoffimmission vermehrten
    einstrahlung von UV-B-licht auf den ertrag von kulturpflanzen (FKW 22), 1.
    Versuchsjahr.   Battelle-Institut E.V. Frankfurt.

Esser,  G.,  1980.  Einfluss einer nach  schadstoffimission vermehrten
    einstrahlung von UV-B-licht auf kulturpflanzen,  2. Versuchsjahr.   Bericht
    Battelle Institut E.V. Frankfurt,  BF-R-63, 984-1.

Flint,  S.D. and M.M.  Caldwell, 1983.  Influence of floral optical properties
    on the ultraviolet radiation environment of pollen.   Amer.  J. Bot.
70:1416-1419.

Flint,  S.D. and M.M.  Caldwell, 1984.  Partial inhibition of in vitro pollen
    germination by simulated solar ultraviolet-B radiation.  Ecol. 65:792-795.

Flint,  S.D. and M.M.  Caldwell, 1984.  Comparative sensitivity of binucleate
    and trinucleate pollen to ultraviolet radiation:   A theoretical
    perspective.  In Stratospheric Ozone Reduction,  Solar Ultraviolet
    Radiation and Plant Life,  (R.C. Worrest, ed.).  Springer-Verlag.   ISBN
    13875-7.

Flint,  S.D., P.W. Jordan, and M.M. Caldwell, 1985.  Plant protective response
    to enhanced UV-B radiation under field conditions:  Leaf optical
    properties and photosynthesis.  Photochem. Photobiol. 41(1):95-99.

Fox, P.M.  and M.M. Caldwell, 1978.  Competitive interaction in plant
    populations exposed to  supplementary ultraviolet-B radiation.  Oecologia
    36:173-190.

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                                      71
Garrard,  L.A.,  T.K.  Van and S.H. West, 1976.   Plant response to middle
    ultraviolet (UV-B) radiation:  Carbohydrate levels and chloroplast
    reactions.   Soil and Crop Sci. Soc. Florida Proc.  36:184-188.

Gates, D.M., 1983.   An overview.  In CO  and Plants (Lemon,  E.R. ed.),
    pp. 7-20.  Westview Press Inc., Boulder,  Colorado  80301.

Gold,  W.G. and M.M.  Caldwell, 1983.  The effects of ultraviolet-B radiation on
    plant competition in terrestrial ecosystems.  Physiol. Plant 58:435-444.

Green, A.E.S.,  K.R.  Cross and L.A. Smith, 1980.  Improved analytical charac-
    terization of ultraviolet skylight.  Photochem. Photobiol.  31:59-65.

Hart,  R.H., G.E. Carlson, H.H. Klueter and H.R. Carns, 1975.  Response of
    economically valuable species to ultraviolet radiation.   In Climatic
    Impacts Assessment Program (CIAP), Monograph 5 (Nachtway, D.S., Caldwell,
    M.M.  and Biggs,  R.H., eds.), pp. 263-275.  U.S. Department of
    Transportation,  Report No. DOT-TST-75-55, National Tech. Info.  Serv.,
    Springfield, Virginia.

Hashimoto, T. and M. Tajima, 1980.  Effects of ultraviolet irradiation on
    growth and pigmentation in seedlings.  Plant Cell Physiol.  21:1559-1571.

Howland,  G.P.,  R.W.  Hart and M.L. Yette, 1975.  Repair of DNA strand breaks
    after gamma-irradiation of protoplasts isolated from cultured wild carrot
    cells.  Mutat.  Res. 27:81-87.

Heath, R.L., 1975.   Ozone.  In Response of Plants to Air Pollution (Mudd,
    J.B., and Kozlowski, T.T., eds.), pp. 23-56.  Academic Press,  New York.
    ISBN 0-12-509450-7.

Heck,  W.W., W.W. Cure, D.S. Shriner, R.J. Olson and A.S. Heagle, 1982.  Ozone
    impacts on the productivity of selected crops.  In Effects of Air
    Pollution on Farm Commodities  (Jacobson,  J.S. and Millen, A.A., eds.).
    Izaak Walton League of Am., Arlington, Virginia  22209.

Iwanzik,  W. and M.  Tevini, 1982.  Effects of enhanced UV-B radiation on
    photosynthetic activity of barley seedlings and chloroplasts.   In
    Biological Effects of UV-B Radiation.  Proc. workshop, Munich.   May 25-27,
    1982.  BPT-Bericht, pp. 121-131.

Iwanzik,  W., M. Tevini, G. Dohnt, M. Voss, W. Weiss, P. Graber and G. Renger,
    1983.  Action of UV-B radiation on photosynthetic primary reactions in
    spinach chloroplast.  Physiol. Plant.  58:401-407.

Johnston, H.S.  1971.  Reduction of stratospheric ozone by nitrogen oxide
    catalysts from supersonic transport exhaust.  Science 173:517-522.

Jones, L.W. and B.  Kok, 1966.  Photoinhibition of chloroplast reactions.   I.
    Kinetics and action spectra.  Plant Physiol. 41:1037-1043.

Kasperbauer, M.J. and W.E. Loomis, 1965.  Inhibition of flowering by natural
    daylight on an inbred strain of melilotus.  Crop Sci. 5:193-194.

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                                     72
Keeling,  C.D.,  1978.   Atmospheric carbon dioxide in the 19th century.   Sci.
    202:1109.

Klarman,  W.L. and J.W. Gerdemann, 1963.   Resistance of soybean to three
    phytophthora species due to the production of a phytoalexin.   Phytopathol.
    53:1317-1320.

Klein, R.M.,  P.C. Edsall and A.C. Gentile,  1965.  Effects of near
    ultraviolet and green radiations on plant growth.  Plant Physiol.
    40:903-906.

Krizek, D.T., 1978.  Differential sensitivity of two cultivars of cucumber
    (Cucumis sativus L.) to increased UV-B irradiance:  I. Dose-response
    studies.   Final Report EPA-IAG-D6-0168,  USDA/EPA EAGER Prog., EPA,
    Washington, D.C.

Lemon, E.R.,  1983.   CO- and Plants.  The Response of Plants to Raising
    Levels of Atmospheric Carbon Dioxide.  Westview Press Inc., Boulder,
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Levitt, J.,  1980.  Responses of plants to environmental stresses.  Vol. 1
    Academic Press, New York, pp. 10-18.  ISBN 0-12-445501-8.

Lydon, J., A.H. Teramura and E.G. Summers,  1986.  Effects of ultraviolet-B
    radiation on the growth and productivity of field grown soybeans.   In
    Stratospheric Ozone Reduction, Solar Ultraviolet Radiation and Plant Life,
    (R.C. Worrest,  ed.), Springer-Verlag.  ISBN 13875-7.

Martin, F.W., 1970.  The ultraviolet absorption profile of stigmatic
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Martin, F.W. and J.L. Brewbaker, 1971.  The nature of the stigmatic exudate
    and its  role in pollen germination.  In Pollen:  Development and
    Physiology (Heslop-Harrison, ed.), Appleton-Century-Crofts, New York, pp.
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McWhorter, C.G. and D.T. Patterson, 1980.  Ecological factors affecting weed
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Mirecki, R.M.  and A.H. Teramura, 1984.  Effects of ultraviolet-B irradiance on
    soybean  V. The dependence of plant sensitivity on the photosynthetic
    photon flux density during and after leaf expansion.  Plant  Physiol.
    74:475-480.

Mudd,  J.B.,  1975.  Sulfur dioxide.  In Response of Plants to Air Pollution
    (Mudd, J.B.  and Kozlowski, T.T., eds.), pp. 9-22.  Academic  Press, New
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Mudd,  J.B.,  and  T.T.  Kozlowski,  1975.  Response of Plants to Air Pollution,
    Academic Press, New York.  ISBN 0-12-509450-7.

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                                      73
Murali, N.S. and A.H. Teramura, 1985a.  Effects of UV-B irradlance on soybean.
    VI.  Influence of phosphorus nutrition on growth and flavonoid content.
    Physiol. Plant.  63:413-416.

Murali, N.S. and A.H. Teramura, 1985b.  Effects of ultraviolet-B irradiance on
    soybean.  VII.  Biomass and concentration and uptake of nutrients at
    varying P supply.  J. Plant Nutrition.  8(2):177-192.

Murali, N.S. and A.H. Teramura, 1986a.  Intraspecific differences in Cucumis
    sativa L. sensitivity to ultraviolet-B radiation.  Physiol Plant in press.

Murali, N.S. and A.H. Teramura, 1986b.  Effects of supplemental ultraviolet-B
    radiation on the growth and physiology of field-grown soybean.  Env. Exp.
    Bot. 26:233-242.

Murali, N.S. and A.H. Teramura, 1986c.  Effectiveness of UV-B radiation on the
    growth and physiology of field-grown soybean modified by water stress.
    Photochem. Photobiol. 44:215-220.

Murali, N.S., A.H. Teramura, and S.K. Randall, 1986d.  A comparative study of
    ultraviolet-B sensitivity between two soybean cultivars.  Env. Exp.  Bot.
    in review.

Nachtwey, D.S., 1975.  Linking photobiological studies at 254 nm with UV-B.
    In Climatic Impact Assessment Program (CIAP),  Monograph 5 (Nachtwey, D.S.,
    Caldwell, M.M. and Biggs,  R.H.,  eds.), pp. 3-50 to 3-84.  U.S. Department
    of Transportation,  Report No.  DOT-TST-75-55, National Techn.  Info.  Serv.,
    Springfield, Virginia.

NAS.  National Academy of Sciences, 1979.   Stratospheric ozone depletion by
    halocarbons:  Chemistry and transport.  National Academy Press,
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NAS.  National Academy of Sciences, 1984.   Causes and effects of changes  in
    stratospheric ozone:   Update 1983.  National Academy Press,  Washington,
    D.C.

NRC.  National Research Council, 1982.  Causes and effects  of stratospheric
    ozone reduction:  An update.   National Academy Press,  Washington,  D.C.
    ISBN 0-309-03248-2.

Nobel,  P.S.  and T.L. Hartsock,  1981.   Development  of leaf thickness  for
    Plectranthus parviflorus -  influence  of photosynthetically active
    radiation.   Physiol.  Plant. 51:163-166.

Owens,  O.V.H.  and D.T.  Krizek,  1980.   Multiple effects of  UV radiation
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                                      74
Reilly, J.J.,  1975.   The role of thymine dimers in the induction of
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Strain, B.R., and F.A. Bazzaz,  1983.  Terrestrial plant communities.  In CO
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                                      76
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                                      77
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    78
APPENDICES

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                          79
                      APPENDIX A
    ACTION SPECTRA AND THEIR KEY ROLE IN ASSESSING
BIOLOGICAL CONSEQUENCES OF SOLAR UV-B RADIATION CHANGE
                          By




                    M.  M.  Caldwell

                      L.  B.  Camp

                     C.  W.  Warner

                     S. D. Flint

                Utah State University
                     Logan, Utah

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                                  80
Action  Spectra and Their Key Role  in Assessing Biological
Consequences of Solar UV-B Radiation Change

M.M. Caldwell, L.B.  Camp, C.W. Warner, and S.D. Flint
Utah State University,  Logan, Utah,  USA
  ABSTRACT


  Action spectra of UV damage to plants must be used  as weighting functions
  to  (1)  evaluate the  relative  increase of  solar UV radiation that would
  result from a decreased  atmospheric  ozone layer,  the  radiation amplifica-
  tion  factor—RAF,  (2) evaluate  the existing natural  gradients  of solar UV
  irradiance on the earth,  and (3) compare  UV radiation from lamp systems in
  experiments  with  solar  UV  radiation in  nature.   Only  if  the  relevant
  biological action spectra have  certain characteristics  is there a potential
  biological problem  that  would result from  ozone  reduction.   Similarly the
  existence of a natural latitudinal solar UV gradient  is dependent on action
  spectrum characteristics.

  Several  UV action  spectra associated with different basic modes of damage
  to  plant tissues all  have  the common characteristic of decreasing effect
  with increasing wavelength; however,  the rate of decline varies consider-
  ably.   Extrapolation from  action  spectra  that have  been measured on
  isolated  organelles and  microorganisms using monochromatic radiation to
  effects  of  polychromatic radiation  on intact higher plants  is precarious.
  Development  of action  spectra using  polychromatic radiation  and intact
  higher plant organs can yield spectra that are of more  ecological relevance
  for weighting  factors  in  assessment of the ozone reduction problem.   An
  example of an action spectrum  for  photosynthetic inhibition developed with
  polychromatic  radiation is provided in  this chapter.   This  action spectrum
  has different characteristics,  and results  in  a greater RAF than do action
  spectra  for inhibition  of a  partial photosynthetic reaction,  the  Hill
  reaction, developed  with isolated chloroplasts and photosynthetic bacteria.
  Circumstantial  evidence from experiments  with plants originating  from
  different latitudes  also supports the  notion  that  action spectra  with
  characteristics  similar to that of the  provisional  spectrum,  developed  with
  polychromatic  radiation,  are appropriate.   Further work with polychromatic
  radiation is  encouraged.

  There are two basic types of error  that  are  associated  with the use of
  action  spectra  in  biological  assessments  of  the  ozone reduction problem,
  the RAF errors and the enhancement errors.  The former are those associated
  with calculation of the RAF,  and the latter are those derived from calcula-
  tion of the UV radiation  enhancement used in experiments with lamp systems.
  While the RAF errors are recognized, the enhancement  errors have not  been
  generally appreciated.   An error  analysis is presented showing  that the

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                                   81

 enhancement  errors will typically be  larger and  in  the opposite direction
 than  the RAF errors.   The enhancement  error should be considerably less in
 field  UV supplementation experiments than in most  laboratory experiments
 which employ fluorescent lamps as the primary UV-B radiation source.


 INTRODUCTION

 Traditionally,  biological action spectra have  been  employed to  elucidate
 photobiological  mechanisms, and specifically to identify potential  chromo-
 phores.   Action spectra  are usually  assessed  by evaluating biological
 responsiveness  to  monochromatic  irradiation.    In  order  to identify
 potential chromophores, there has been an emphasis on the fine structure of
 action spectra and little attention has been directed to the tails  of these
 spectra.

 In assessment of the consequences of  solar UV-B radiation changes, action
 spectra serve a very different role.   Weighting functions are derived from
 action spectra to assess the relative  biological effectiveness of polychro-
 matic  irradiance.   Spectral  irradiance is weighted  and then integrated over
 a waveband of interest, thus:
          effective  irradiance ^I^E^d ^                               (1)


where I^is  the  spectral irradiance,  and E^is the relative  effectiveness of
irradiance  at  wavelength    to elicit a  particular biological response.   The
limits of the  integration are prescribed by the wavelengths where either  I«
or Fj^approach zero.

Spectral irradiance  and the  action  spectra  can  be  expressed on either a
photon  or  an energy basis.   As units  of effective irradiance it is  most
useful to speak  of  "weighted"  or  "effective"  energy flux or photon  flux
density (e.g.,  effective  W m~2 Or effective moles photons m~2 s'1) and, of
course, to  specify the action spectrum used as a weighting function and the
wavelength  to which the spectrum is normalized.   Special units analogous to
units of illumination (e.g.,   lux) have been previously devised for effec-
tive  UV radiation  (such  as sunburn  units,  E-viton  and the Finsen for
erythemally effective radiation (Robertson  1975;  Luckiesh  and  Holladay
1933)  and  the G-viton for germicidal  UV radiation (Luckiesh and Holladay
1933).  However, unlike illumination where  a  standard spectral  luminosity
function has been well accepted, UV  action spectra for various biological
phenomena  are continually being  refined or abandoned in favor of new action
spectra and,  thus,  either the  units  need to be redefined  or  new  units
described.   Therefore,  use  of effective energy or  photon  flux with  a
specified  action spectrum is quite preferable  to the definition of  new
units.

The  utility  of weighting the UV irradiance  and,  thus, expressing biolog-
ically  effective  irradiance for  the  ozone reduction problem  derives  from
the  highly  wavelength-specific  absorption characteristics of atmospheric
ozone  and  the wavelength specificity  of  biological  action spectra in the
UV-R waveband (National Academy of Sciences 1979; Nachtwey and Rundel  1982;
Caldwell 1981).   The  expression of  weighted  effective irradiance is useful
in addressing  three  basic  issues:

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(1)  The degree  to  which  biologically damaging  solar  UV  irradiation is
increased when atmospheric ozone decreases is very dependent on the action
spectrum  characteristics.   The increment  of  biologically damaging solar
^irradiation resulting  from  a given level of ozone  reduction for a specific
set  of  conditions,  is known as  the  radiation  amplification factor,  RAF
(National Academy  of Sciences 1979).   Without calculation of an RAF, which
takes the  biological  effectiveness  of each wavelength into account,  the
increment  of total solar   UV-B  flux  resulting  from  ozone  reduction is
trivial,  e.g.,  1% increase   of UV-B radiation for 16%  ozone reduction for
midday  irradiance  in the summer  at  temperate  latitudes (Caldwell  1981).
The  increase  of  solar UV-B  irradiation as a function of ozone  reduction
only becomes significant when the biological effectiveness of this  radia-
tion is  calculated and the  action spectrum  for this calculation has certain
characteristics.   By the same  token,  if the action  spectrum  of  a particular
biological phenomenon does not exhibit  the  appropriate characteristics,  the
RAF will be very small and  this phenomenon can be eliminated from concern
with respect to  the consequences of ozone  reduction without the necessity
of dose-response studies.

(2)  The steepness of the natural latitudinal gradient of solar  UV-B
irradiance  that  currently  exists  on  the  Earth's  surface should also  be
evaluated  in terms  of potential biological  effectiveness.   The natural
gradient of UV-B radiation  serves  as  a basis for  study of organism response
to solar UV-B radiation  and can provide insight  into potential consequences
of ozone  reduction.   This  gradient has been used  most frequently  in  the
analysis of human skin cancer incidence; however, study of plant adaptation
to  UV-B  radiation  at  different  latitudes  can  also  be instructive  (e.g.,
Caldwell et al. 1982;  Robberecht et al. 1980).   As is  the case with ozone
reduction,  without taking  biological  effectiveness of solar UV-B irradia-
tion into account,  the natural latitudinal gradient  of  solar UV-B radiation
is virtually nonexistent  (Caldwell  1981).

(3) Since spectral  irradiance received from  commonly-used lamp systems for
UV-B studies does not match that of solar irradiance, it is only possible
to draw comparisons  by  calculating "biologically effective"  radiation using
action spectra as  weighting  functions.  Characteristics of action spectra
will  thus  dictate the amount of radiant flux delivered by lamp systems in
experiments designed  to  evaluate potential  consequences of ozone reduction
under different  conditions.

This chapter  will  (1) review a few  action spectra  illustrating different
fundamental mechanisms  of  UV-B damage in plant cells, (2)  discuss the use
of  polychromatic  radiation in determining action spectra and  illustrate
this  with a new  action spectrum for photosynthetic inhibition,  (3) show the
nature  of  radiation amplification  factors  that  result  from action spectra
of different  characteristics,  (4)  briefly discuss  the implications of
action  spectra for the natural latitudinal  gradient of solar UV-B radia-
tion, and  (5) develop an  error  analysis  of  the  types  and magnitude of
errors that might  be encountered  in biological assessments by  assuming an
improper action spectrum.

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ANALYSIS

Modes of Damage  and Their Spectra

Ultraviolet  radiation  can damage  plant  cells by several basic mechanisms
and  these pathways of damage  likely involve several different chromophores.
To illustrate  the diversity of  damage pathways, several action spectra are
depicted in Fig.  1.   In each case  the reaction is identified  with damage to
a  specific  entity or process in the cell.   However, this does not mean that
the  entity damaged  is necessarily  the primary chromophore  (Peak and  Peak
1983).   All  spectra are  normalized  to  300 nm.    Though  these  spectra
   10
   10'
V
   ,o-
1'°'
o-
o>
CT
  10'
    ,-5
JHill reaction
                                ATPase
  ^-single  strand
            breaks'
       280  300  320  340  360  380  400

                Wavelength    (nm)
Fig. 1.  Ultraviolet action spectra representing basic modes  of damage to
plant tissues.   The spectra were all developed with monochromatic radiation
and are plotted on  a quantum effectiveness basis relative to 300 nm.   These
include  inhibition of Hill  reaction activity in isolated chloroplasts of
spinach  (Jones and  Kok 1966),  inhibition of  adenosine triphosphatase
(ATPase)  from  plasma membranes of  Rosa damascene  (Imbrie and Murphy  1982),
induction of single strand breaks  of  Bacillus subtilis DNA (Peak and  Peak
1982), lethality of stationary phase  cells of £._  coli associated with  cell
membrane damage  (Kelland  et al.  1983),  inhibition of alanine uptake in £._
coli linked  to inactivation  of  carrier proteins  (Sharma  and  Jagger 1981),
and inactivation  of stationary phase cells in  F^  coli associated  with
nucleic  acid damage (Webb 1977).

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                                  84

represent different basic pathways of damage,  and  in many cases presumably
very different  chromophores, all  have the common property  of decreasing
effect as wavelength increases.  These spectra have  been developed in the
normal manner using monochromatic radiation and in several cases have been
pursued through several orders  of magnitude.   If  these were  to be plotted
with a linear ordinate,  the differences in these spectra would be much less
apparent.  Nevertheless,  as  will be discussed subsequently,  if these
spectra are to  be used as weighting factors  for solar UV radiation, which
increases by  orders  of  magnitude with increasing wavelength,  the
differences in slopes  of these action  spectra'are of key importance.  These
spectra have been determined with isolated organelles, membranes, or micro-
organisms, but  none involved intact higher plants.

Complications:  Intact Higher Plants and Polychromatic Radiation

Since  the spectra illustrated  in  Fig. 1 differ  greatly in  their  decline
with increasing  wavelength,  it is important to know which of  these  primary
damage mechanisms are the most important for intact higher plants  exposed
to solar radiation.  This is not an easily answered  question.  One would
need  to know   (1) the basic sensitivity of  the  respective  targets (e.g.,
DNA,  membranes,  Photosystem  II  of photosynthesis,  etc.) for the higher
plant species in question, (2) how  well  shielded  these  targets are within
the plant organ (i.e.,  the effective  spectral fluence  reaching the  target),
(3)  to  what extent reciprocity  would apply,  and (4)  if  radiation at
different  wavelengths  when  applied  simultaneously  and in  proportion to
their occurrence  in sunlight  would have strictly  additive effects, as
predicted by  the action spectrum, or  whether these effects would  be posi-
tively or negatively synergistic.   Addressing  these several  issues  is
hardly a  trivial undertaking and satisfactory  answers are  not likely to be
quickly  forthcoming.   For example,   as to the question of synergistic
effects  of radiation  at  different  wavelengths, much is  known about
mechanisms of   UV radiation effects on nucleic  acids  and  yet  it is  still
difficult  to  quantitatively  predict  synergistic  effects in  higher plants.
From jn_ vitro studies and  from  ^n_ vivo experiments with microorganisms,  it
is clear that  there are qualitative  differences between UV-B  and UV-A
damaging  photoreactions  (Peak  and Peak 1983):  UV-A radiation  can drive
photorepair of UV-B-induced damage (Jagger 1981),  UV-B radiation can induce
other repair systems which  can  repair at  least a fraction of the UV damage
(Menezes  and  Tyrrell  1982),  UV-A radiation can cause  growth  delay  in
bacteria which   allows more time for  dark repair systems to  operate (Jagger
1981),  and,  finally,  UV radiation  at high fluence rates  can damage  UV
repair systems  (Webb 1977).  The net effect  of these phenomena and their
applicability  to higher plant nucleic  acid  damage is not easily envisaged.

The  primary site of UV damage to photosynthesis  is in the  reaction center
of Photosystem  II  (Penger et al. this volume; Noorudeen and Kulandaivelu
1982)  and most  likely  does not involve  nucleic  acids.  For intact higher
plants, interactions between  UV-B and longer wavelength radiation have been
frequently reported though the mechanisms are not understood. Plant leaves
which have developed under low visible  radiation conditions  are  consider-
ably  more sensitive  to  UV-B  inhibition  of  photosynthesis  (Teramura  et
al.  1980; Sisson and  Caldwell 1976; Warner and Caldwell 1983).   Yet, there
is also some evidence  that  higher visible irradiance during UV-B  irradia-
tion  increases  the inhibition  of  photosynthesis  even  though  the  visible
irradiation by   itself  is  not sufficient  to inhibit photosynthesis  (Warner
and  Caldwell 1983).  At present, one can  only speculate about the mecha-

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nisms involved in  these  interactions.

A Photosynthetic Inhibition Spectrum

Predicting  the net effect of  interactions between radiation  of different
wavelengths  for phenomena  such  as  nucleic  acid damage or  inhibition of
photosynthesis is  not  possible at present  even though the  action spectra
for some repair processes such as photoreactivation are  known.  Thus, in
order to  account  for  the  synergistic  effects of  radiation  at  different
wavelengths  when  "damage"  action  spectra  are to be  used as  weighting
functions  for polychromatic radiation,  one is forced to take a  more
empirical approach.  This can be done by employing polychromatic radiation
in the development  of action spectra and using intact  plant organs.  In
this  process  the biological  responses  to  different  combinations of  poly-
chromatic  irradiation  are determined  and these responses  and  associated
spectral  irradiance data  can be deconvoluted  to yield an action spectrum
(Rundel  1983).   With respect  to  the  ozone  reduction problem,  the most
logical combinations of polychromatic irradiation involve a  constant back-
ground of longwave UV-A and visible  irradiance with increments of radiation
at shorter  wavelength intervals.   This process can sacrifice  some of the
fine  structure  of  an  action  spectrum,  but this is  of  less concern for the
purpose of  weighting  functions.

This  series of polychromatic irradiation distributions should be planned to
account  for  the  tail  of  the  action  spectrum  into  the  UV-A  or visible
waveband,  as the case may be.  Characteristics of the action  spectrum below
280 nm are of no concern with respect to solar UV radiation changes because
of the effectiveness of atmospheric ozone absorption, even in the case of  a
severely  depleted  ozone  layer (Caldwell  1979).   Yet,  if  a particular lamp
system emits  shorter  wavelengths,  the weighting  function  should  include
these as well.

To illustrate this  polychromatic approach to action spectrum  development,
reduction of photosynthesis  of an intact  leaf of Rumex patientia  will be
depicted.   Photosynthetic inhibition of higher plants by UV  radiation is of
potential concern  with respect to ozone reduction.   For some species  under
certain  experimental  conditions,   solar  UV   radiation at  flux  rates now
received at temperate  latitudes has been shown to reduce photosynthesis
(Bogenrieder  and Klein  1977; Sisson and  Caldwell  1977).   Yet to be
resolved, however, is  the extent to which  plants experience photosynthetic
inhibition under field  conditions, or how much they might  be inhibited  in
the  event  of  ozone  layer  reduction.   Nevertheless,  there  is  sufficient
impetus to select  net photosynthesis for  action  spectrum analysis because
of its potential  susceptibility  to  solar UV radiation and its obvious
importance for plant  biology.   Furthermore,  net photosynthesis is an inte-
grated  physiological process which requires the integrity  of  membrane
systems  and  the  coordinated action  of photochemical and  enzymatic
processes.   Thus,  it  also serves as a useful  indicator of plant response  to
stress.

Methods:   Assessment  of  photosynthetic  depression resulting from  UV
irradiation involved the  determination of net CO2  uptake by  plant leaves,
exposure of  the leaves  to a particular polychromatic irradiation distribu-
tion,  and then subsequent determination of CO2 uptake capacity under iden-
tical  conditions.   Ideally, the leaves would be exposed to the inactivating
UV irradiation over a period of several days  or weeks  as  would occur under

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                                   86

field conditions.   Unfortunately, this involves  unreasonable biological and
experimental  complications.   Leaf  photosynthetic characteristics  change
appreciably with leaf age (e.g.,   Sestak 1977; Sisson and  Caldwell  1977).
These  changes combined  with the time  and  logistic requirements for such
experiments render  this approach infeasible.  Thus, the  irradiation  periods
ranged from  one to 16 hours.  Seven polychromatic radiation  distributions
were employed.  For each, a  dose-response  relationship was developed.  Even
with these irradiation periods, such experiments are very time consuming.

The  spectral  irradiance  for  the  seven polychromatic  irradiation distribu-
tions are  shown in  Fig.  2.  These were developed  by  using  a 2.5-kW xenon
high pressure lamp and a combination of dichroic  and sharp cutoff  filters.
Much  of  the  visible and  infrared radiation was  removed  by  the dichroic
filter arrangement  in  order  to prevent excessive  leaf temperatures.  Yet,
there was sufficient visible  flux (400^pioles m~2  s~l  between  400 and 700
nm)  to drive photosynthesis of  the plants during  the UV  irradiation.
Leaves still intact  with the remainder of the plant were  placed on a slowly
revolving  stage in  this  radiation field  to insure even  irradiation  of the
leaves.
 c
    1000
 O)
 u
 c
 O
 •6
 o
 OJ
 0.
 CO
     100
10
      O.I
          280
         260  280  300  320   WO   360   380   40O

                    Wavelength  (nm)
Fig. 2. Spectral  irradiance  for  seven polychromatic  irradiation distribu-
tions used  in  the development  of an  action  spectrum  for inhibition  of
photosynthesis.   Radiation is supplied by a  2.5-kW xenon high pressure lamp
and  filtered with  a  combination of  dichroic and absorption filters.  The
sharp  cutoff  filters  used  for  each  distribution  are from  the  Schott  WG
series.
Net photosynthetic rates of intact leaves were  assessed by measurements of
net  CC>2 uptake  under specific environmental  conditions in a gas exchange
cuvette.   By measurement  of simultaneous C02 and water vapor  flux of the
foliage as  well as other parameters including leaf temperature, CC>2 concen-
tration in  the cuvette air, and water vapor concentration in the cuvette,
it  is  possible to  calculate intercellular  CO2 concentrations  within  the
leaf (e.g.,  Caldwell et  al.  1977).   Intercellular  CC>2  is influenced

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primarily by photosynthetic  rates,  CO2  in  the  cuvette  airstream,  and
diffusion resistance provided by stomata.   Since  photosynthesis  is normally
substrate limited,  it  is  important to  manage  the  cuvette  conditions to
maintain  a  constant intercellular C02 concentration in the leaf before and
after  irradiation  so that  metabolic  photosynthetic  capacity  of a  leaf is
assessed without the complication of  changes in diffusion  resistances
between the leaf  intercellular CC>2 and the air.   Direct coupling of the gas
exchange system  with a  computer allows immediate assessment  of these
parameters  so that adjustments in cuvette  conditions can be made during the
course of these measurements.

Results and discussion:  The dose-response relationships  for net photosyn-
thetic inhibition  of  Rumex patientia leaves are  shown  in Fig.  3  for the
different spectral irradiance  distributions.   Each  data point  represents a
different  leaf measured on  a  different  date since each  determination
required a day to complete.  Nevertheless, these dose-response data reveal
linear relationships.  The coefficients of determination,  R2, range between
0.63 and 0.98 with an average of 0.87.   The spectral irradiance combination
which included  the least  short wavelength radiation (WG 360,  Fig. 2) did
not  result  in inhibition  of photosynthesis under  these  conditions  even
after 16 hours of exposure.
   50
   40J-
   30-
I
"^
"i 20
   10
 c
 >»
 1/1
 o
          I WG 280
               WG 295
                    WG 305
                             WG320
                                        WG 335
                                            WG 345
                                            WG360
                  6    6    10   i2    14

                  Irradiation  period (hrs)
Fig. 3.  Relative inhibition of net photosynthesis  of intact Rumex patientia
leaves exposed  to  the polychromatic irradiation  combinations  shown in
Fig. 2.
These  photosynthetic  inhibition data indicate that when there  was sensi-
tivity  to a  particular  irradiation distribution,  we  were  dealing with  a
linear  portion of  the dose-response  relationship.   This is important  in
developing action  spectra.   If a  particular dose-response  relationship
exhibits diminished slope as  with  saturation, these data cannot be compared
with a dose-response  relationship which is in  the  initial,  linear phase.
The dose-response  relationships presented here indicate that it is  suitable
to utilize  the slope  of these linear regression  relationships  for biolog-

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ical response in  developing  these  action spectra.

When  these  slopes are  taken  as the relative effect  for  each  spectral
irradiance combination, an  action  spectrum can be  deconvoluted from the
slopes and  respective  spectral  irradiance data  (Rundel  1983).    Several
possible  spectra  can result depending on the exact procedure followed.  The
spectrum shown  in Fig. 4  is  the monotonic function  that provided  the best
fit to the data (Rundel 1983).
 O)
 c
 51 10
Ol

"5   0
   10

3
"E
O

§  I0''h
 OJ
 cr
                         Anocystis
                    reaction^-—.;
                      chioroplasts
       280  300  320  340   360   380

                 Wavelengih    (nm)
Fig. 4.  Action spectrum for inhibition of photosynthesis for an intact  leaf
of Rumex patientia deconvoluted  from the data of Figs.  2  and 3 by Rundel
(1983) for his monotonic function that provided the best fit.   Spectra for
inhibition of  Hill  reaction  in isolated spinach chioroplasts  (Jones and  Kok
1966) and of the Cyanobacterium,  Anacytis, (Hirosawa and Miyachi 1983) are
also shown.   The  two Hill  reaction spectra were developed  with monochro-
matic radiation.
The  action  spectrum deconvoluted  from the polychromatic  radiation study
with intact  leaves  is considerably steeper than the spectrum for inhibition
of a  partial  photosynthetic reaction, the  Hill  reaction, conducted by
treating  isolated spinach chloroplasts  with  monochromatic  radiation (Jones
and Kok  1966).   The spectrum for inhibition of fluorescence rise time from
spinach thylakoid suspensions (Bjorn et al. this volume) and a spectrum  for
Hill  reaction inhibition of  the  Cyanobacterium,  Anacystis nidulans,
(Hirosawa and Miyachi  1983), also developed with monochromatic radiation,
correspond  closely  with  the spectrum  of Jones  and  Kok.   The  two  Hill
reaction  inhibition  spectra  are  also shown in Fig. 4.

Preliminary  results  of more recent action spectrum studies  for  Rumex
patientia  and  other species  suggest that the action  spectrum  may  exhibit
steeper declines  with increasing  wavelength than  the spectrum for Rumex
shown  in  Fig. 4.   This new  work involves simultaneous UV irradiation and
leaf  gas exchange measurements.  With a split-beam arrangement, the leaf is
also  simultaneously  receiving high  visible irradiation  (800  to  1200  i^

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                                   89

 m-2 s'1, depending on the species being investigated).   Though the visible
 flux  employed is still  only 40  to  60 percent  of that in midday solar
 radiation,  photosynthesis is light saturated.   Since subsequent action
 spectra conducted  with higher  visible  irradiance may reveal  steeper
 declines with  increasing wavelength,  the  action  spectrum shown in Fig. 4
 for Rum ex should be considered as only provisional.  The importance of the
 rate of  decline with increasing wavelength  when action  spectra are used as
 weighting  functions is  discussed in a subsequent  section.

 Although  practical limitations  do  not permit these  experiments  to be
 performed  with  spectral  irradiance  that  exactly  matches  that  of solar
 radiation,  this approach with polychromatic  radiation  and intact leaves
 should  provide a  much  more realistic  approximation of the  ecologically
 relevant action  spectra  for  photosynthetic inhibition.    It  also indicates
 that extrapolation from damage spectra  of  specific  physiological  reactions,
 as shown in  Fig. 1,  to intact  organisms may  not provide reliable  results.
 As  will be discussed  in a  subsequent  section, there is  also  indirect
 evidence that  the action spectrum developed  for inhibition of  photosyn-
 thesis  by  this polychromatic  approach  may be appropriate for plants in
 nature.


 Action Spectra and Radiation  Amplification Factors

 One  of the functions of action spectra in assessment of the ozone reduction
 problem  is  their  use  in evaluating radiation  amplification factors,  RAF,
 i.e.,    the  relative  increase  in  biologically effective UV radiation  for  a
 given  level of ozone  reduction.   As noted in  a  previous section,  all  UV
 damage spectra exhibit a general decrease  in effectiveness with increasing
 wavelength, though the rates of decline vary  considerably (e.g.,   Fig. 1).
 Since  solar  spectral  irradiance  increases by  orders of magnitude  with
 increasing  wavelength,  the rate  of decline  of  action  spectra has  a
 pronounced  effect on the resulting RAF when these spectra  are  used as
 weighting functions.  Furthermore, even though ozone reduction would only
 result  in increases  of  solar  spectral  irradiance  in  the  UV-B  part  of  the
 spectrum (Caldwell  1981), the weighting function should include  all wave-
 lengths of the  solar spectrum where  the weighted spectral irradiance adds
 appreciably to the  integral  of  Eq. (1).   Although  many UV-B  biological
 damage spectra include the UV-A  region,  few extend far into the  visible
 spectrum.  This is not  of great consequence if  the effectiveness is already
 so low by 400 nm that  the  weighted  visible flux would  not contribute
 significantly  to the total biologically effective flux  (such  as  is the case
 for DNA damage), or if the action spectrum is already  sufficiently flat so
 as to  result in  a negligible   RAF (as is  the case  for  the Hill  reaction
 spectrum).

 To illustrate  the behavior of the RAF  calculated  with different  action
 spectra,  a variety of spectra currently in  use, as  well  as the provisional
 photosynthetic  inhibition  action  spectrum  for Rumex,  are portrayed  in
 Fig.  5   and  the respective RAF values  for different  total  ozone  column
 thickness relative to 0.32 cm  in Fig.  6.  The model of Green et al.  (1980)
 was  used to  calculate  the spectral irradiance.   The action spectra have
been chosen because they illustrate the  RAF values for spectra with  a broad
range  of slopes.

The  DNA damage spectrum is a generalized spectrum compiled by Setlow
(1974).  The  generalized plant  damage spectrum is  also the  result of  a

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                                   90

compilation of  several plant'damage spectra that exhibit similar character-
istics (Caldwell 1971).   The generalized plant damage spectrum terminates
at 313.3 nm simply  because  that  was the longest wavelength  (an  emission
line from mercury vapor UV lamps) where information was available for these
spectra at  the  time  they were compiled.  (If these spectra decline steeply
beyond 313  nm as the DNA-damage  spectrum does,  the contribution of  weighted
spectral irradiance  at wavelengths greater than  313 nm would be negligible
for the  total  integrated  biologically effective  flux.) The Robertson-
Berger, R-B,  meter is  a widely  used integrating dosimeter  for solar UV
monitoring  (Perger  et al. 1975).  The spectral response of this meter was
originally designed to approximate that of human  skin erythema.  The provi-
sional  spectrum for  photosynthetic  inhibition  of Rumex  (Fig. 4)  is  also
included;   although  preliminary data  (cited  previously) indicate that a
steeper spectrum may be more appropriate and  that  this would  result in
greater RAF values.
    280  290  300  3iO   320  330  340
              Wavelength  (nm)

Fig. 5.   Action  spectra  exhibiting  different  rates of  decline  with
increasing  wavelength.  These include  the  spectrum for Hill  reaction
inhibition of spinach chloroplasts  (Jones  and Kok 1966),  the  Rumex  leaf
photosynthesis  inhibition spectrum (Fig. 4),  a spectrum for the Robertson-
Berger  meter (Robertson 1975),  a  generalized plant damage spectrum
(Caldwell 1971) and  a generalized  DNA  damage spectrum  (Setlow  1974).
The RAF values in Fig. 6 are calculated over the waveband 290-380 nm.  For
the DNA and generalized plant damage spectra there would be no significant
effect if  the integral  included  longer wavelengths.   For the Hill  reaction
and R-B meter spectra,  the  RAF values would be  even smaller if  longer wave-
lengths were included in the integration.  The deconvoluted Rumex spectrum

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                                   91
is unreliable  at  longer wavelengths.   As noted  in  the previous section,
polychromatic irradiation  which did not include wavelengths  shorter  than
330 nm had  no  effect on photosynthesis (Figs. 2  and 3).   Also shown in
Fig. 6 is  a slope  indicating a 2%  increase of biologically damaging radia
tion for each 1% decrease of ozone column thickness which has commonly  been
used as a  guideline for the RAF (National Academy of  Sciences 1979).

Radiation  amplification factors  are  dependent  on  the degree  of ozone
reduction  and this dependency is more pronounced for  steeper action spectra
(Fig.  6).   The RAF is also quite dependent on solar angle and, thus,  RAF
values appropriate for total daily effective  radiation  would  be an inte-
grated  function  for  different  times of day.   The  daily RAF  would be
dependent on latitude and time of year (National Academy of Sciences 1979).
The RAF  values in Fig. 6 are plotted for a solar angle from the zenith of
33.6*  (air mass of 1.2)..  For  the  summer solstice at 40* latitude, these
RAF values would also be approximately the same as total integrated daily
dose RAF  values.
  3.0
              ,DNA  domoge
  2.0
<
er
   i.O
       ~Ol92	O224   0.256   0.288   0.320
                   Ozone Column  (cm)

Fig. 6. Radiation amplification factors  calculated for different ozone
column  thickness,  relative to 0.32 cm,  and a solar angle from the zenith of
33.6* calculated according  to  the action spectra shown in Fig. 5.   The
dashed  line  represents  a case  of 2% increase in  biologically effective
radiation for a 1%  decrease of ozone.   The model of Green et al. (1980) was
used  to calculate  the solar spectral  irradiance (direct  beam + diffuse)
used for those RAF values.
The  Natural  Latitudinal  Gradient of Solar UV-B Radiation

Natural latitudinal gradients of solar UV-P radiation exist  on the earth.
This is primarily  the  result  of  differences in prevailing solar angles  and
total ozone column thickness  at different latitudes  (Caldwell  1981).
Correlations between the  latitudinal  UV-B gradient and skin cancer
incidence of selected human populations have been used as a tool to predict
increases  of skin  cancer as a function of ozone  reduction  (e.g..  National
Academy of Sciences 1979).   An  analogous correlation between  latitude  and
changes  in  crop  yield or  other nonhuman biological phenomena are  too
confounded  with other environmental variables such as soils,  temperature
and  moisture to be of use  in predicting  the consequences  of ozone  reduc-
tion.  Nevertheless,  controlled  study of plant response  to,  and tolerance

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                                    92

of, UV-B  irradiation by species  from different latitudes can provide some
useful insight as to how plants cope  with different levels of UV-B irradia-
tion.   However, just as  the magnitude of solar UV-B increase resulting from
ozone reduction is dependent on the action spectrum used, the steepness of
the present  latitudinal  gradient  of  solar  UV-B  irradiance  is  also quite
dependent  on the action spectrum used for evaluation.

The  effective UV-B radiation for the  season of  year of maximum solar
radiation at  different   latitudes  is shown  in Fig. 7.    These are  plotted
relative  to  the radiation at  40* latitude.   (The  date of maximum solar
radiation at  each  latitude corresponds to the time when solar zenith angles
are minimal. Above 23° latitude this  occurs at the  summer solstice, but at
latitudes  less  than 23*.  this time  is  progressively  closer  to  the equi-
noxes, about March 21  and September 23,  which are the dates of maximum
solar  radiation at  the equator.)  Three  different action spectra  have been
used  as  weighting  functions to illustrate  the dependence  of this  gradient
on action spectrum characteristics.  Just as the RAF is greater for steeper
action spectra  (Fig. 6),  steeper  action  spectra  also result  in   a  more
pronounced latitudinal gradient of solar  UV-B irradiance.
   1.8

   1.6

   1.4
o
1   '-2


^ 0.6
o
Q
   0.4
   0.2
          —— DNA damage
          	Generalized plant damage
          	 Hill  reaction
       0
10   20
30    40
Latitude
50    60    70
Fig. 7. Daily effective  UV-B radiation for the season of year of maximum
solar radiation at  different  latitudes relative  to that  at  40*  latitude
calculated according to the generalized DNA damage action spectrum (Setlow
1974), the generalized plant damage action spectrum (Caldwell 1971) and the
Hill reaction inhibition spectrum  (Jones and  Kok, 1966).
If a spectrum has a rather slow rate of decline with increasing wavelength.

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                                  93
such  as the  Hill reaction spectrum,  there is no  latitudinal solar UV-B
gradient.   Thus,  study of characteristics of plants that have  originated
from  different latitudes can provide some indirect evidence of the  type of
UV damage  action  spectrum  that  is  indeed  appropriate for plants.   For
example, if  a spectrum such  as the Hill reaction is indeed  representative
of the spectrum  for UV damage to plants, one might expect  little correla-
tion between the  latitude of  origin of plants  and their sensitivity to UV-B
radiation when this radiation is presented at sufficient flux densities to
result in damage.

There are  several lines of evidence that suggest that a sufficiently steep
action spectrum  for plant damage exists  so that  an  appreciable latitudinal
gradient of  solar UV-B  radiation  has been  extant.   The  first   line of
evidence is  a correlation between the latitude  of  origin of crop  species
and their sensitivity to UV-B  radiation as measured by a reduction of plant
biomass  in experiments with UV-B radiation lamps.  Over 50% of the crop
species  which have  originated from temperate  latitudes were sensitive to
UV-B radiation in these tests,  whereas  for crop species  that have origi-
nated at low latitudes, only 20% were  classified as sensitive  (Teramura and
Caldwell unpublished).

The second two lines of evidence are derived from a latitudinal gradient in
the arctic-alpine  life zone ranging from sea level locations  in the Arctic
to alpine  elevations (3000-4000  m) at  mid to low latitudes.   In  this
situation an even steeper  gradient  should be expected  because elevation
above sea  level  is  superimposed on the  latitudinal  gradient (Caldwell et
al. 1980).    A survey  of UV  optical properties of leaves from nonagricul-
tural,  as  well as  agricultural,  plant  species has been  conducted by
sampling plants in the field   at various  locations along  this gradient  and
determining the UV epidermal  transmittance of the leaves.  Plants occurring
in areas of high  solar UV-B radiation, at low latitudes and high altitudes,
exhibited a  greater capacity  to selectively absorb  UV-B radiation in the
upper tissue layers of the  leaves  (Robberecht et al. 1980).   If the selec-
tive  pressure  for UV  absorption in  the  epidermis  of plant  leaves  were
approximately  the same  at  all locations along  this gradient,  such as would
be the  case  if an action spectrum  like that of the Hill reaction inhibition
were  appropriate  for  UV-B damage,  one would  not expect  a  correlation
between latitude  and UV-B filtration capacity  of  the leaf epidermis.

A  third  line  of  evidence involves the inherent  differences  in sensitivity
of the photosynthetic system to UV-B radiation damage that have been demon-
strated for species  of  the  same  genus or even races  of the same  species
which occur in  different locations on the latitudinal gradient of the
arctic-alpine life  zone  (Caldwell et al.  1982).   In these experiments,
plants were  cultured  under identical  conditions  in environmental  growth
chambers before the sensitivity of  their photosynthetic systems to the UV-B
radiation was assessed.   Arctic  races  or species  consistently showed much
greater  sensitivity to UV-B  radiation and this could not be solely attri-
buted to differences in the optical properties of  the leaf epidermis.  Such
evidence certainly supports the notion that  a steeper action spectrum for
photosynthetic damage by UV radiation such as that developed using poly-
chromatic  radiation  (Fig. 4)  would be  more  appropriate than  an action
spectrum such as  that  for  the Hill  reaction.   Although all  three  lines of
evidence are circumstantial,   they  support the  notion that an appreciable
RAF exists for higher plants.

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                                    94

 Biological Assessments and Errors Deriving from Action Spectra

 Before  radiation amplification factors can be used in assessment of biolog-
 ical and  ecological  consequences of  ozone reduction,  it is  necessary to
 demonstrate biological  effects  of  UV-B  radiation.   Ideally,  one  should
 establish  a dose-response  relationship.   In  any case,  it  is at  least
 necessary  to show a meaningful response at UV-B flux densities exceeding
 those currently in sunlight.   (Investigations involving the removal of  UV-B
 from  solar  radiation, such  as with filters, have  generally not  resulted in
 significant  plant  responses  (Caldwell  1968; Becwar et al.  1982; Caldwell
 1981),  although  there  are  some notable exceptions (e.g., Bogenreider and
 Klein 1977).)

 Experiments with lamps;  One  cannot  easily  simulate  the  solar spectral
 irradiance either with  or-without reduced ozone using  UV lamps.   Thus,
 weighted UV irradiance  from  the  lamp system is compared with weighted solar
 UV irradiance  as would occur with  a particular solar angle, ozone concen-
 tration, etc.  The most common lamps used are  fluorescent lamps which emit
 principally  in  the UV-B region.  The spectral irradiance  from  the  most
 frequently used bulbs is shown  in Fig. 8.  As  with all fluorescent  lamps,
 these are basically low  pressure mercury vapor lamps with a phosphor that
 fluoresces in  a continuous  spectrum  —  in  this case, mainly  in the  UV-B
 region,  but some UV-C and  UV-A radiation is included.   Though  most of the
 radiant  emission  from the bulbs comes from the  fluorescing phosphor, the
 emission  from  the mercury vapor  is also present and this  appears as
distinct lines  in  the spectrum.   The fluorescent lamp  manufactured  by
Philips Co.  emits substantially more  than the bulb of Westinghouse.

Filters are  commonly employed to absorb the  UV-C  and short-wavelength UV-B
radiation  emitted by these  bulbs.   Investigators  in Europe  have commonly
used  the  Philips  bulbs with glass  cutoff  absorption  filters (Schott  WG
series)  for  this purpose, while  in North America,  cellulose  acetate plastic
film has been used with the  bulbs manufactured  by Westinghouse (Caldwell et
al. 1983).  The  glass absorption filters have the  advantage  of being stable
in  their  transmittance,  while  the plastic film filters are considerably
less expensive  but exhibit decreased  transmittance as  they  are  exposed to
UV radiation (Caldwell et al. 1983).   The spectral irradiance  from filtered
and unfiltered  lamps shown  in Fig.  8 is provided as a  comparison of these
lamp  and   filter  combinations.    Naturally,  individual lamps  will vary in
 their  emission and,  as  with all fluorescent   lamps,  their emission  will
decrease with  age,  especially during the first  100 hours  of use,  and with
temperatures that are too warm  or too cold for optimal operation  (Bickford
and Dunn  1972).

 If filtered fluorescent lamps are the  only source  of UV radiation for plant
experiments, the discrepancy between spectral  irradiance received from the
sun and that received  from the lamps is  considerable  (Fig. 9a).   When
compared  with  the midday  solar irradiance in  the summer at  temperate
latitudes,   a bank of filtered Westinghouse  fluorescent lamps provide  more
shortwave UV-B radiation and more than an order of magnitude less longwave
 UV-B and  UV-A radiation.   Thus, the action  spectrum used to  weight the
spectral irradiance for  comparison of the lamp systems with solar radiation
is particularly critical  as will  be demonstrated subsequently.

 When  such lamp systems are used to supplement  the normal solar radiation,
i.e.,  when plants are  exposed  both  to  the solar radiation as well  as a

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                                   95
     120
     100
 'E
  c
'E

*
1  80
    60
  a.
 to
    40
    20
                    •Phillips
                      Westmghouse
Phillips  with
  WG 305 SchotT
 Westmghouse  with
  cellulose  ocetote
  film
       250 275  300 325 350  375 400
                                     250 275  300 325 350 375 4QO
                          Wavelength  (nm)
Fig. 8. The  spectral irradiance at 30 cm from comm.on fluorescent UV-B  lamps
with and  without filters.  The lamps and  filters were new and  the  spectral
irradiance was measured  with a  double  monochromator  spectroradiometer
(Optronic Laboratories).   The Philips TL 40W/12 and the Westinghouse FS40
lamps  without filters are  shown on the left and  with filters on  the right.
Schott W3 305  sharp cutoff  absorption  filters  (2  mm thickness)  were used
with  the  Philips  lamp  and cellulose  acetate plastic  film  (0.13 mm
thickness) with the Westinghouse lamp.   These lamp/filter combinations have
commonly been used in studies in Europe and North America, respectively.

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                                  96
 1000
 600
100
60


20

 10
 6
       G local-
              CA-Mtered
               lamps
                                            /: ^Myiof-filtered lamps
                                               € gioDoi
     300   12Z
               340   360 300  320
                               340  360 300  320   340   360
                               (nm)
Fig. 9.  Global  (direct  beam  + diffuse)  UV spectral irradiance and  the
spectral irradiance from filtered lamp systems used in experiments.  In the
left  panel,  a,  global  spectral  irradiance  as  measured  at  solar noon  on
August 20  at  41* 45'  N latitude  and 1460  m elevation and  the spectral
irradiance  from  Westinghouse FS 40 lamps with cellulose  acetate film
filters (without background global radiation) are shown.   The lamp  system
is adjusted to provide a UV-B  supplement  equivalent to a 16% ozone  reduc-
tion under these conditions  calculated according  to  the generalized plant
damage action spectrum.  In the middle panel, b, the theoretical  global UV
spectral  irradiance  for these  conditions,  as calculated by  the  model  of
Green  et  al.  (1980),  is shown for current  ozone conditions as well  as
conditions  with a 16%  reduction of the  atmospheric ozone  layer.   In the
right panel, c,  the UV spectral irradiance  measured under lamp systems with
cellulose acetate and Mylar  film filters with the  background global  radia-
tion is shown.   The  Mylar-filtered lamp system provides a control with the
same UV-A irradiance and obstruction of global radiation as the CA-filtered
lamps which constitute the enhancement treatment.  The UV-A irradiance in
both treatment  and  control  is less  than  the ambient global shown  in the
left  panel  because  of  the  obstruction created  by the  lamps.   The  UV-B
supplement in the right panel represents the  same  effective UV-B radiation
as that predicted with the Green ej  al.  (1980) model when calculated using
the generalized plant damage  action spectrum.   Adapted from  Caldwell et
al. (1983).
supplement from  the filtered  lamp bank, the discrepancy in spectral distri-
bution is much less.   Ideally,  the supplemented UV  spectral irradiance
would only  be that  shown  as  the  difference  between solar  spectral
irradiance  under  normal conditions and  with ozone reduction (Fig. 9b).
Since the filtered fluorescent lamps emit longer wavelength radiation than
is desired  for  the supplement,  it is necessary to use control lamps  which
are  identical except  that  they are filtered so as  to  exclude the  UV-B
radiation.   Thus, the  amount of  UV-A radiation provided by the control
lamps would  be the same as that  coming from the treatment lamps, and the
other microenvironmental influences such as shading by the lamps would also

-------
                                  97

be the same.  In Fig.  9c  the resulting spectral irradiance under lamp banks
with  two different  plastic  film  filters,  corresponding to  treatment and
control,  is  shown  with the solar radiation background.   The  difference
between  these is still  not a perfect simulation of what  would be calculated
as the difference between solar spectral irradiance with and without ozone
reduction; however, the correspondence is considerably better than when the
lamps are used  by  themselves  such as would  be the case in a glasshouse,
growth chamber or laboratory situation.

Error analysis;  There  are then two basic types of error that  are  involved
in use of action spectra as weighting  functions in biological  assessments
of ozone reduction,  namely RAF errors  and  enhancement errors.  The  RAF
errors are those resulting from an overestimation or underestimation of the
radiation amplification fac'tors by assuming an  incorrect action spectrum.
The  RAF errors would be  associated  with  application  of dose-response
relationships to the solar UV-B irradiance  that  would result  from various
scenarios of ozone reduction.   For  example,  if a given amount of UV-B
irradiation  corresponding  to 10%  ozone  reduction resulted in 5% reduction
of photosynthesis, one would employ the  RAF  to extrapolate  to  other ozone
reduction levels for a given latitude and season  of year.

The  enhancement  error is  that  associated with relating UV-B radiation
supplied by  lamp systems  in an experiment  with solar UV-B  radiation  for a
particular ozone level.   For  example,  if  one desires  to provide  a UV-B
radiation supplement  under field  conditions corresponding to  a 15% ozone
reduction, and an incorrect action spectrum is  used  as a  weighting factor
for comparing UV irradiance  from the lamps  and the  sun,  an error in the
desired  enhancement  will  result.   The  enhancement error necessarily
includes an  RAF error  —  namely that associated with calculating the effec-
tive UV irradiance corresponding to the 15%  ozone reduction.

These two types of error are shown in Fig. 10 for  a scenario  in which the
generalized  plant damage  action spectrum (Fig. 5) is employed  for calculat-
ing the RAF and the  effective UV radiation enhancement  when the  DNA-damage
spectrum (Fig. 5) is indeed  the  most appropriate for plant damage.  (This
is,  of course,  hypothetical as  the  most  appropriate  action  spectrum  to
represent higher plant  damage is not known.)   The discrepancy between RAF
values calculated by  the generalized plant damage  and DNA damage spectra  is
illustrated in  the upper portion of Fig.  10.   With greater ozone reduction,
which requires larger RAF values,  the divergence from the diagonal 1:1 line
increases, i.e.,   the difference  between the  RAF  values calculated  using
the  two action spectra increases.   This is directly from information
presented in  Fig. 6.    The  differences  in  UV radiation enhancement  in a
field  experiment that  would result from  use of the  two action spectra are
shown in  the  lower half of Fig. 10.   In field experiments the lamps are
used to supplement the solar radiation, and a  certain amount of obstruction
of  the  solar  global (direct beam +  diffuse) radiation inevitably results.
The  exact spectral distribution of the radiation  reaching the plants in the
enhancement experiments then depends  on the mixture of global and  lamp
radiation.   The  relationship in  Fig. 10 was determined  from actual measure-
ments of spectral  irradiance  under lamp  systems in  a  field  experiment.
Each  point represents  a combination of the UV radiation from the lamps and
the background  global radiation  convoluted using the  two action spectra.
Relative enhancement  is the ratio of the  UV-B radiation from the lamps plus
the background  global radiation to the ambient global radiation without the
lamp  systems  for particular  conditions.   The  range  of  values shown  in

-------
                                   98

Fig. 10 results  from different  experiments in which enhancements corre-
sponding  with  different  levels of  ozone  reduction  and different  solar
angles were  used.   The lamp  system is  specially modulated  so that the
amount of UV supplement is adjusted for particular solar conditions such as
solar  angle,  atmospheric turbidity,  current ozone  concentrations,  etc.
(Caldwell  et al. 1983).   A linear regression  fits these points adequately
(r2 = 0.96).  The discrepancy between relative enhancements calculated by
the two action  spectra  is greater than the discrepancy between the  RAF
values calculated with the two spectra.

For the action  spectra represented in this paper (Figs.  1, 4 and 5) and the
filtered UV .fluorescent lamps  commonly used,  (Fig. 8), the RAF and enhance-
ment  errors  are in  opposite  directions  as  depicted  in Fig. 11.   These
relative  errors  are  shown  as a function of ozone reduction for  field
enhancement  experiments under temperate-latitude conditions in the summer
as portrayed in Fig.  10.   The scenario  is  the  same,  namely,  that the
generalized plant damage action spectrum  was assumed while  the DNA-damage
spectrum is  correct.  Although  the relative RAF errors  are small for situa-
tions  where  the ozone  reduction  is  small,  this  is not the  case for the
enhancement  errors (Fig. 11).

If a different scenario is pursued such that  the generalized  plant damage
spectrum is  assumed,  but a spectrum with a slower rate of decline  with
increasing wavelength, such  as  the R-B spectrum (Fig.  5), is  correct,  then
the RAF and  enhancement  errors would be reversed —  an overestimation of
the RAF and  underestimation of the enhancement.

As shown in Fig.  9, field UV enhancement  experiments provide a much closer
simulation  of the spectral irradiance resulting  from  ozone reduction  than
do experiments in glasshouses or growth chambers in which UV radiation is
provided  only by filtered fluorescent lamps, since there is no  solar UV
background.   The  enhancement  errors  that  might result  from  use  of an
incorrect action spectrum  for calculating  the enhancement are considerably
greater than  for field  experiments,  as shown  in Fig. 12.   The  spectral
irradiance  from  filtered  Philips  and Westinghouse UV fluorescent  tubes
following  aging  of  the lamps and  filters  for  about 100 hours was used to
calculate  the errors  shown in  Fig. 12.   The  same spectral distribution  is
assumed for  all  enhancement  levels in such experiments,  which is normally
the situation,  as doses are  typically adjusted  by varying the  number of
lamps, distance  between the lamps and  the experimental objects,  or  use of
neutral  density  filters.    The  errors   portrayed  here  are  striking,
especially  when  one  considers  that  the two  action spectra  used for this
scenario  are  not so very dissimilar (Fig.  5).  Other scenarios could easily
lead to larger  overestimation  or underestimation  errors for the  calculated
enhancement.  Also,  for the  errors depicted in Fig.  12 the relative  over-
estimation  errors are  greater at  UV  levels corresponding  to  smaller  ozone
reductions.

If a source of background  UV radiation  were present, such as from a  xenon
arc lamp, these  errors could be substantially  reduced.   However, this  would
depend on the  flux density and  spectral distribution  received  from  the
background  source.   An  empirical  analysis  of  the  errors  for particular
situations would need  to be conducted.  However, without knowledge of the
most appropriate  action  spectra  for plant damage, the error analysis
remains as  a heuristic  exercise  quite  dependent  on  the action spectrum
scenarios assumed.

-------
                                 99
     10
1.5       2.0
  RAF GEN. PLANT
     1.0       2.0        3.0        4.0
            Relative enhancement  (GEN. PLANT)
Fig. 10.   The  relationship  between  radiation  amplification  factors
calculated  with  the generalized  plant  damage action  spectrum  and  the
generalized DNA damage action spectrum for different  conditions and levels
of ozone reduction (upper).  The relative enhanced UV-B radiation in field
experiments calculated  according to the  generalized plant damage spectrum
and the generalized  DNA damage spectrum for different conditions and levels
of ozone reduction based on field spectral  irradiance measurements (lower).
The  solid  diagonal  lines in both  graphs  represent a  situation of equiva-
lence  for  the  RAF  and relative enhancements  calculated  from  the two
spectra.

-------
                                  100
     40
   o
   o 30

 J*°

 S°.o
     I0h
   -S20
               Enhancement  error
               Ozone reduction (%)
               RAF error
Fig.  11.  Relative RAF and enhancement errors as a function of ozone reduc-
tion  for field  UV supplementation  experiments under  temperate-latitude
conditions in the summer as portrayed in Fig. 10.   The scenario for  these
errors is that  the  RAF  values  and the  enhancements  were calculated
following the generalized  plant  action  spectrum  when  the DNA  damage
spectrum was indeed correct.
CONCLUDING REMARKS
The  potential errors  resulting from assuming  an incorrect action spectrum
are  compelling  reasons  for  further  action  spectrum  development.   This
should indeed be pursued.   Yet, one should not expect  that a single defini-
tive  action spectrum  for  higher  plant damage will  necessarily be forth-
coming.  It is unlikely when one considers the many basic modes of damage
to plant tissues  that  UV  radiation can  effect (Fig. 1),  the  physiological
and  morphological  diversity  of plant species,  and  the interactions  with
other environmental factors,  such  as  visible light, that can ensue.

Extrapolation from  spectra  of component reactions of isolated  organelles to
spectra of higher plant  response  in nature is precarious as shown for the
case of photosynthetic damage  (Fig.  4).  Thus,  use  of intact plant organs
and polychromatic radiation should  be  emphasized in further action spectrum
development  where  these spectra bear on the ozone reduction problem.   For
damage to higher  plant  photosynthesis,  the  provisional action spectrum
developed for Rumex patientia  (Fig.  4) as well  as circumstantial  evidence
from  the natural latitudinal  gradient indicate that the appropriate action
spectrum is  much steeper  than the  spectra  for the Hill reaction.   Thus,
contrary to what one  might conclude  from component photosynthetic  reac-
tions,  an appreciable RAF  exists for damage to higher plant  photosynthesis.
More recent preliminary work with  polychromatic radiation suggests that the
spectrum may yet be even steeper and, therefore, one should view the Rumex
spectrum presented here as only provisional.

-------
                                 101
   200
 5 150
 g
 "5
 I 100
 0)

 O
    50
                    Laboratory -
                      Phillips *  Schott 305
   Laboratory ~
       FS-40 + CA film
Reid- FS-40*CA film
              10       20      30
                 Ozone  reduction (%}
                          40
Fig. 12.  Enhancement errors calculated  according to the same scenario as
for Fig. 11, but with enhancement experiments using different lamp systems.
In the field supplementation experiment  using Westinghouse  FS40 lamps and
cellulose acetate  film,  the errors  are  the  same as portrayed  in  Fig. 11.
Under laboratory conditions (which would correspond to glasshouse or growth
chamber conditions with no background UV radiation) the Philips lamps with
Schott WG  305  filters  and  the Westinghouse  FS40  lamps with  cellulose
acetate film render the errors depicted.  The lamps and filters were aged
for about 100 hours for these measurements.
In our present state of ignorance  concerning the most  appropriate  action
spectra for higher plant damage,  we  feel it is  reasonable to continue to
use an action spectrum with an intermediate  rate  of decline with increasing
wavelength, such  as the generalized plant damage spectrum.  An intermediate
spectrum  will, of course,  yield  intermediate  RAF and enhancement values.
If the appropriate spectra  are later  found to be  either  steeper or flatter,
correction from an intermediate  spectrum will be  easier to  conduct.

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                                  1 02


ACKNOWLEDGMENTS


This work has been supported by the U.S.  Environmental Protection Agency.
Although the research described in this chapter  has been funded primarily
by the U.S. Environmental Protectio*\Agency through Cooperative Agreement
CR808670  to  Utah  State University,  it  has  not been  subjected  to  the
Agency's required peer and policy review and therefore does not necessarily
reflect  the views  of the Agency and  no official endorsement should be
inferred.


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                                     105


                                  APPENDIX B

                 STRATOSPHERIC CHEHISTRY AND NATURE OF OZONE
    Stratospheric ozone is the primary attenuator of extraterrestrial solar
ultraviolet radiation and therefore determines the quality and quantity
ultimately reaching the earth's surface.  Approximately 95% of the total
atmospheric ozone is found in the stratosphere, a region of the atmosphere
about 16 to 50 km above the earth's surface at low latitudes and about 8 to 50
km at high latitudes.   Global stratospheric ozone concentration is maintained
by a balance of various processes that generate and remove it (Figure B-l).
Ozone is formed by a reaction between atomic oxygen (0) with diatomic
molecular oxygen (0.)  and the process is initiated by the photolysis of
diatomic oxygen:

         0  + hv       P 0 + 0                   (1)
         0 + 02        P 03 (ozone).             (2)

The energy required for photolysis is 5.41 ev and is provided by solar
radiation of wavelengths below 242 run.  According to figures published by the
National Reseach Council (1982) ,  photolysis provides a global source of ozone
amounting to 50 billion metric tons per year, with more than 90% of this
formed above 25 km.   Approximately 1% of the ozone created in the stratosphere
is removed by transport to the troposphere.  The remainder is destroyed by
chemical reactions involving oxygen (0), hydrogen (H),  chlorine (Cl),  and
nitrogen (N) compounds, with the last three acting as catalysts in very low
concentrations.  The net effect of these various reactions is either the
association of ozone with atomic oxygen to form 0_,  or the association of two
ozone molecules:

       Process I    0+0     P 20               (3)

       Process II   0+0     P 30           ,   (4)

The various reactions  in process I are:

       Cl + 03    P CIO + 0                      (5)

       CIO +0    P Cl + 0                       (6)

       NO + 03    P N02 + 02                     (7)

       N02 + 0    P NO + 0                       (8)

       OH + 03    P H02 + 02                     (9)

       0 + H0     P OH + 0                      (10)

-------
                                    106
Fig. B-l.  Representation of the processes that determine the concentration of
           ozone in the stratosphere (NRG 1982)

-------
                                     107
These reactions are limited by the availability of oxygen atoms, therefore
effectively restricting them to altitudes above 25 km.  The regeneration of
oxygen occurs through photolysis of ozone:

       03 + hv    P 02 + 0.                     (11)

The reaction schemes in process II where atomic oxygen is not limiting,  are:

       OH + 03    P H02 + 02                    (12)

       H02 + 03    P OH + 202                   (13)

   At altitudes between 25 and 45 km, reaction 7 accounts for approximately
45% of total ozone removal, while reactions 3 and 5 each account for about
20%, and reaction 9 for 10%.  Below 25 km, reactions 12 and 13 account only
for 1% (NRC 1982).

   In reactions 5 and 7, Cl and NO are not consumed during ozone destruction
because they are regenerated in reactions 6 and 8.  A single chlorine atom can
affect the recombination of 10^ to 10  ozone molecules during its mean
residence time in the stratosphere (about 2 years) before returning to the
troposphere mainly as hydrochloric acid (HC1).   The average NO  molecule is
equally effective during its 2 years of residence in the stratosphere.  Thus,
the addition of these substances into the stratosphere profoundly affects the
balance between production and removal process by which the total abundance of
ozone is governed.

   To date, approximately three parts per billion (ppb) of the lower
stratosphere consists of Cl bound in organic molecules such as methyl chloride
(CHC1), carbon tetrachloride (CC1 ), and chlorofluorocarbons (CFG).  Table
B-l lists the abundance of several prevalent species and their rate of
release.  Among these, methyl chloride is known to have substantial natural
origins, while most others are anthropogenic.  The global release of CFG-11
and CFG-12 from 1952 to 1980 is shown in Figure B-2.  Although the release
rate has decreased by about 20% from the peak rate of 1974, approximately 90%
of all CFC-11 produced has been already released into the atmosphere and about
90% of this amount still remains in the atmosphere today (NAS 1984).  The
largest sources of CFCs are the industrial countries of the northern
mid-latitudes, and the greatest concentrations are found over Europe and the
eastern portions of the North America.  The Atmospheric Lifetime Experiments
(ALE) stations have been monitoring the concentration of CFC-11, CFC-12, CC1
CH CGI  and NO  in Ireland, Oregon (USA), Barbados, Samoa and Tasmania.
Overall, there has been a steady increase in the concentrations of CFCs over
the past decade.  At altitudes above 20 km, halocarbons decompose in sunlight
to release free chlorine.  This free chlorine is converted to inorganic
species including HC1, chlorine nitrate (C1NO ) and CIO.  HC1 is the major
reservoir for chlorine at altitudes above 25 km.

    The estimated ozone reduction due to changes in the rate of release of
various chemicals is summarized in Table B-2.  According to current
theoretical estimates, continuing production of CFCs at rates of 3.1 million
metric tons of CFC-11 and 4.3 million metric tons of CFC-12 annually
(approximately the 1980 production rate) would lead to a steady-state

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                                        108
Table B-l.  Concentration in the Lower Stratosphere and Release Rates of Major
            Sources of Chlorine in the Stratosphere (NRC 1982)
         Compound
Concentration (ppb)
Molecular   Chlorine
  Rate of Release
  (million metric
tons of Cl per year)
Methyl
chloride
(CH
F-12 (CF0Cln)

F-ll ((
Carbon
Methyl
/ /



0
J


tetrachloride
chloroform (C
Cl)




-------
                                      109
             400
             200
           S 200
           3
           Z
           z
             100
                          1960
1970
                                                      1930
                                YEAR
Fig. B-2.  Estimated annual worldwide releases of CFC-11 and CFC-12, 1952-1980

           NAS  (1984).

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                                        110
Table B-2.   Sensitivity of Total Column Ozone to Perturbing Influences
            (NAS 1984)
Trace Gas and Magnitude of

       Perturbation
Typical
Estimate
of Ozone
 Column
 Change
Atmospheric
 Lifetime
 (years)
                            Principal Mode of
                            Pollutant Removal
CFG-11 and -12
(1980 release rates)

Other halocarbons
(2 ppbv Cl increase)
Subsonic aircraft
(2 x 10  kg
N02/yr @ 12 km)

N20 (20% increase by 2050)


CH  (doubling)
CO  (doubling)
-2 to -4
-1
+1
-4
+3
+3 to +6
  50-150
   1-15
     100
     10
Photolysis of CFCs
in middle stratosphere

Decomposition of
tropospheric chloro-
carbon reservoir by
reaction with OH

Conversion to nitric
acid and removal to
surface

Photolysis in
stratosphere

Reaction with
tropospheric OH

Uptake by oceans,
sediment, and biosphere
*  Ozone column change (steady-state) was estimated using 1-D photochemical
models.

-------
                                      Ill
 reduction in  the  total  column  of ozone of  2-4%  (NAS  1984) .  These
 calculations, however,  were performed with a highly  restrictive  set  of
 physical  and  chemical parameters and did not include temperature feedback.   In
 the  stratosphere,  temperature  increases with altitude due  to  the ozone
 absorbance of UV  radiation.  When temperature was  included in the
 calculations, the reduction in the ozone column was  computed  to  be 3-5%.

   There  have been many attempts over the  past decade to estimate the
 magnitude of  ozone change due  to continuous CFG release.   As  seen in Figure
 B-3,  there have been wide variations in the estimate of the magnitude of  ozone
 reduction.  Recently, there has been a trend toward  lower  calculated changes.
 In many ozone pertubation estimates, the release of  CFCs is assumed  to remain
 constant  for  100  to 200 years, producing an eventual steady-state condition.
 However,  this may not be true  of future, long-term trends  (as  shown  in Figure
 B-2)  of worldwide release of CFCs.  Wuebbles (NAS  1984) calculated a
 time -dependent ozone depletion for 18 halocarbon release scenarios (Figure
 B-4) .  In the scenarios projecting variations in CFG release  rates by as  much
 as 3% per year, the non steady- state total ozone reductions by the year 2030
 ranged from 3% to 9%.   With a  3% increase  in CFG releases, however,  the total
 ozone change  falls precipitously beyond this date.   These  calculations
 demonstrate that  the growth and decay of halocarbons occur over  long time
 scales and that ozone depletion is very sensitive  to growth in the rate of
 chlorine  emissions.

   A decade ago projections of large fleets of supersonic  aircraft (SSTs)
 flying at altitudes of  20 km raised the concern over large-scale stratospheric
 ozone depletion due to  the injection of nitrogen oxides (Johnston 1971).
 However,  an economical  SST system has not materialized and apparently will not
 be developed  during this century.  Nitrogen oxides are currently emitted  into
 the lower stratosphere  and upper troposphere (below  13 km) by  subsonic
 commercial  aircraft.  At relatively low altitudes, photochemical reactions of
 NO  in the  presence of  hydrocarbons generate small amounts of  ozone  (by an
 estimated 1%).  However, large injections of NO  at  altitudes  above  17 km
 could result  in large reductions in stratospheric  ozone.  Global nitrous  oxide
 concentrations appear to have  increased by 2.7% over the past  16 years (from
 292 ppb in  1964 to 300  ppb in  1980) .   It is likely to further  increase with
 increases  in  emissions  associated with agricultural  activities, disposal  of
 human and animal wastes, and possibly combustion (NAS 1984).   The
 stratospheric decomposition of NO into NO  occurs mainly in the middle
 stratosphere  (between 20 and 40 km).   In tSis region, catalytic ozone
 destruction by NO is extremely efficient and therefore increases in  N 0 will
 result in decreases in  stratosphere ozone.   A 20%  increase of  N 0 by the  year
 2050 could  decrease ozone concentrations by 4%.   This could be expected if the
 currently observed rate of increase of NO concentrations were to continue
 over the next 100 years.  However,  it has been suggested that  such reductions
may be masked to some extent by increases in tropospheric ozone attributed to
 subsonic jets and urban smog (NAS 1984).
   Methane (CH^) concentrations in the atmosphere are currently estimated to
be increasing at a rate of 2% per year.  Methane converts ozone -reactive
chlorine atoms into HC1,  which does not affect 0  directly.  Hence, an
increase in CH^ leads to a decrease in free chlorine, with a resultant
reduction in ozone catalysis.  Photodecomposed products of CH  also interact

-------
                                     112
          20
          10
      z
      5

I
1974



1975
i
f
IMPROVED Cl
i
1
1976 1977 1978
1
H
CHEMISTRY

MOLINA »
ROWLAND

SLOW

NO » HO2.
DIURNAL
Avg'g
1979
t
1
1930 1981
i
t
TEMPERATURE
FEEDBACK

OH * HO_. HO. * 0
j j


CION02 ' HQc,

t
OH » HN03


FAST HOj.
1 1
1982






NO
OH * H°2 Rev.s.d HO
1983
FAST
CIO » NO2
SLOW
CIO ' 0
REDUCED
Fig. B-3. Estimates of steady-state reductions in total column ozone for
          continuous releases of CFCs at approximately 1975 rates as
          calculated from different chemical models.  Changes in the models
          and simulation techniques are indicated in chronological order
          (adapted by NAS (1984) from Turco 1984).

-------
                                      113
          V
          o
          o
          c
          i,
          m
          0
  8
  6
  4
  2
  0
 -2
 -4
 -6
 -8
-10
-12
             -14
             -16
                              CLC growth raw
                      Scenario    1980-2000     2000-
                        IV       +3%/year     +3%/year
                        V
                        VI
 0%/year
- 3%/year
               1980  2000   2020  2040   2060   2080   2100
                                  Year
Fig. B-4. Time dependence of  total  column ozone calculated for several
          scenarios of CFG releases using 1982 chemistry.  Calculations using
          more recent chemical models would yield smaller reductions in total
          ozone.  (NAS, 1984)

-------
                                     114
with NO  to produce ozone.   If CH,  concentrations were to double those of
current values,  the total ozone column could be increased by approximately 3%
(NAS 1984).

   Carbon dioxide (CO-) provides the dominant heat sink for the middle
atmosphere through the emission of infrared radiation into space.   Changes in
CO. concentration can alter the heat balance and temperature of the
stratosphere and thereby the rates of basic chemical reactions.  An increase
in CO, concentration lowers stratospheric temperatures and leads to increases
in ozone concentrations.  Current estimates of the net perturbations of
stratospheric ozone resulting from a doubling of atmospheric CO- are between
3% and 6% (NAS 1984).

   It is evident from the above discussion that the effects of individual
gases differ, some causing reductions in the total ozone column (CFCs,
stratospheric NO ,  CH,, N~0) and others leading to net increases (tropospheric
NO , CH,,  CO-).   when the concentrations of these gases change simultaneously,
the net effect on 0- may be quite complex.  Few recent models have reported
effects of the combined releases of several compounds on the stratospheric
ozone concentration.  Wuebbles (NAS 1984) estimated the time-course change in
ozone corresponding to a combination of emissions.  This scenario assumes that
1) release of CFCs, CH CC1   and CC1  (designated CLC) is constant at 1980
levels; 2) N_0 increases at 0.2% per year; 3) CO- increases at 0.6% per year;
4) aircraft emissions of NO  below 13 km increase by a factor between 5 and 6
from 1975 to 1990 and remain constant thereafter; and 5) there is a constant
flux of CH  at the earth's surface.  According to this scenario, there will be
a fraction of a percent increase in the total column ozone by the year 2050.
Atmospheric and Environmental Research (AER) and Du Pont (NAS 1984) have also
calculated ozone depletion using scenarios for CLC, CO   N-0 and NO  similar
to those used by Wuebbles,  but with more recent chemistry and variable fluxes
of CH4  (AER 1.2; Du Pont 1.5%).  If CFC releases are doubled by 1980, and CH4
release is constant, there would be 2% decrease in ozone concentration by the
year 2050; if CH, release increases, ozone concentration would increase by 4%.

   Brasseurl and Rudder (1984) have recently studied the sensitivity of the
ozone layer to several chemical agents, individually and in coupled scenarios.
The results are presented in Table B-3.  The CFC perturbation  (P) corresponds
to a constant emission of CFC1  (3.4 x 105 T/year), CF Cl  (4.1 x 105 T/year),
CC14 (1.0 x 105 T/year), and C^CCl  (3.6 x 105 T/yearJ.  For other species
(C0_, N_0 and CH,), current concentrations were doubled.  They also considered
temperature feedback in the model, and the simulations were made with
presently adopted chemistry.  The results show that the ozone depletion due to
CFCs lies between 3% and 3.5%, whereas for NO it lies between 7.8% and 8.9%.
A combination of different sources results in an ozone reduction of 1.3% to
6.8%.  Compared to reports by NAS  (1984), the computations made by Brasseurl
and Rudder (1984) indicate a larger influence of nitrogen-containing compounds
and a smaller influence of CFCs.  They attribute this difference to a smaller
calculated value in OH radicals as a result of revisions in the reaction rates
involved in the odd hydrogen destruction.  This exemplifies the sensitivity of
simulation models to revisions in reaction rates.  These computations show
that future ozone changes associated with CFCs may be drastically altered when
other perturbing effects are included, and that the net ozone change may be
extremely difficult to detect, since counteracting effects tend to reduce the
perturbation signal in total ozone.

-------
                                    115
Table B-3.  Perturbation of the Ozone Column (Brasseurl and Rudder,  1984)

Case
A
A'
B
C
C'
D
D'
E
F
F'
G

CO NO CH CFCs
P*
P
x 2
x 2
x 2
x 2
x 2
x 2 P
x 2 x 2 P
x 2 x 2 P
x 2 x 2 x 2 P
Temperature
Feedback
Yes
No
Yes
Yes
No
Yes
No
Yes
Yes
No
Yes
% Change
in
Ozone
-3
-3
+3
-7
-8
+0
+0
-1
-5
-6
-3
.50
.37
.14
.79
.92
.97
.87
.30
.56
.84
.06
   *
     Emission of CFCs.

-------
                                     116
   These models are severely limited because of the uncertain reliability of
assumptions about release rates over many decades, photochemical processes and
rate coefficients, and radiative-dynamical effects and interactions (NAS
1984).  Schmailzl and Crutzen (1984) modelled the distribution of various
ozone-destroying catalysts and the resulting ozone loss as a function of
altitude, latitude, and season using recent photochemistry.  They found a
large imbalance in the ozone budget, with additional ozone destruction above
29 km and additional production below 29 km.  They suggest this to be due to
errors in reaction rate coefficients, in the source gas distribution, in the
solar fluxes, and in other deficiencies in understanding stratospheric
photochemistry.  Until such inconsistencies are resolved, there will continue
to be a high degree of uncertainty associated with our predictions of future
changes in stratospheric ozone concentration.

-------
                      117
                   APPENDIX C

     EFFECTS OF ULTRAVIOLET-B RADIATION ON
      THE GROWTH AND YIELD OF CROP PLANTS
                       By
                Alan H.  Teramura
(from Physiol Plant 58:415-427,  Copenhagen 1983)

-------
 PHYSIOL. PLANT. 58: -415-427. Copenhagen 19H3
 Effects  of  ultravioIet-B radiation on  the  growth  and yield of
 crop  plants
Alan H. Teramura
.»'/
                                       I erunuira. A. II  19X3  Hllects of ultraviolet-B radiation on the growth and yield of
                                       crop plants. - Physiol. Plant. 58' 415-127

                                       I Ins paper roicws growth chamber, greenhouse, .mil lii.li) studies on ilie elkils ol
                                       ullraviolet-B (UV-B. between 2X0 and 320 inn) radiation on agricultural crop plains
                                       Our understanding of the physiological effects of UV-B  radiation comes primarily
                                       from growth chamber studies, where UV-B is artificially supplied Ma liltered lamps
                                       Both photosystems I and II. as well as carboxvlaung cn/ymes. are sensitive to UV-B
                                       radiation. Ullraviolcl-B radiation also aftects stomaial resistance, chlorophyll  con-
                                       centration, soluble leaf proteins, lipids. and carbohydrate pools  In general, ihe ef-
                                       tects of UV-B radiation are accentuated by the low levels ol visible radiation  typically
                                       found  inside growth chambers.
                                       Ultravtolet-B radiation has also been shown to alfect ,in;itomical and morphological
                                       plant  characteristics.  Commonly  observed UV-B induced  changes include plant
                                       stunting, reductions in leaf area and total biomass, and alterations in the pattern ol
                                       biomass partitioning into various plant  organs. In sensitive plants, evidence of cell
                                       and (issue damage often appears on  the upper leaf epidermis as bron/mg.  gla/ing.
                                       and chlorosis.  Epidermal transmission  in the UV region  decreases in irradiated
                                       leaves. This decrease  is primarily associated with a stimulation in llavnnoiit biosyn-
                                       thesis and is thought to bo a protective, screening response to the deleterious elletis
                                       of UV-B. A considerable degree of variability exists in sensitivity to UV-B radiation
                                       between different species. Approximately 30% ot the species tested  were resist.mt,
                                       another 20'!'o were extremely sensitive, and  the  remainder were of intermediate
                                       sensitivity,  in terms of reductions  in total  dry  weight In addition  to this >,i7.ibie
                                       interspecific variability, there appears to be a similarly wide intraspecilic variability in
                                       UV-B  response.
                                       The effects of UV-B  radiation on crop yield have only been examined in a limited
                                       number of field studies, with ambient levels of UV-B radiation being supplemented
                                       with fluorescent sun lamps. Due to various deficiencies, all these field experiments to
                                       date have only  limited utility for assessing the potential impact of enhanced levels of
                                       UV-B  on crop productivity.

                                      A. H.  Teramura,  De-pi of lloiiinv,  Univ  of \tar\ltiiul. College Park. Ml) 2U742,
                                       U.S.A.

                                      This paper is part of the contribution to tbe Intern.ilional Workshop on the Ellccts of
                                       Ultraviolet  Radiation on Plants, held in Delhi. India. 1-5 November. 19X2.
Table of contents

Abstract	  415
Introduction	  416
Physiological and biochemical effects	  416
  Photosynthetic processes	  416
  Dark respiration	  418
                                                        Stomata 	4|X
                                                        Photosynthetic pigments	  4IK
                                                        Lipids  and carbohydrates	419
                                                        Non-photosyntheltc pigments	419
                                                        Ion transport	  420
                                                     Morphological and anatomical  effects	  42<>
                                                        Leaf area and specific leaf weight	  420
Received 16 December. 1982; revised  15 March, 1983
27 Phvjiol Plan! 
-------
  Bronzing, glazing and chlorosis  	   421
  Plant stunting       	421
  Dry matter production and allocation   	  421
  Crop yield	      	4?3
Response differences to UV-B radiation	  424
  Interspecific dillerences	425
  Intraspecilic dillerences	425
References
I .ill  I  Major world liKid crops and  production  (loud and
Agriculture Organization
Crop
Introduction
During  the past decade,  there has been considerable
concern over  reductions  in  stratospheric o/one con-
centration resulting from man's activities. Since stratos-
pheric ozone  is the  primary attenuator of solar  ul-
traviolet radiation, such a reduction would result m an
increase m ultraviolet  radiation  reaching the earth's
surface. Cunent estimates of ozone  depletion during
the next century range between  5 and  Wo  (National
Academy  of Sciences 1982). Atmospheric attenuation
of solar radiation  is wavelength  dependent, therefore
the anticipated spectral irradiation changes would occur
within a relatively narrow waveband in the ultraviolet-13
(UV-B) region (between 28U-320 nm). Even under an
unlikely 4U"/o global ozone reduction  (Green  et al.
1974, 1980)  radiation of shorter wavelengths  (UV-C,
20(1-280 nm) would  not  penetrate the earth's atmos-
phere. Furthermore, since the ozone absorption coeffi-
cient is  very low at longer wavelengths, UV-A radiation
(320—100 nm) is also virtually unaffected by changes in
stratospheric ozone concentration (Caldwell 1981). The
intent of this article is specifically to review the effects
of enhanced UV-B radiation on agricultural crops, as a
result of ozone depletion.
   For the purposes of this review, the term "crop" re-
fers to  an agricultural plant species that is either culti-
vated or  domesticated tor harvest.  Putting  this into
perspective, there  are over 350 000 species of plants in
the  world  and  over  80 000  ot these are edible.
Nevertheless,  only about 3 000 are harvested by man
and used for food (Miller 1982).  Currently, only about
80 plants species have been domesticated (Ehrlich et al.
 1977),  and ot these only 15 spectes supply nearly  all the
food  calories  and three-fourths  of the  protein to the
world (Tab.  I). Three members of the Poaceae, rice,
wheat and corn  supply  two-thirds of these calories and
one-half of the protein.
   A summary of the effects of UV-B radiation on the
physiology and growth of crops is presented in Tab. 2. A
brief description of these effects and generalities  drawn
from specific studies follows below.
 Abbreviations - UV-A. ultraviolet radiation between 32(1 and
 400 nm; UV-U. ultraviolet radiation between 280 and 320 nm:
 UV-C. ultraviolet radiation between 200 and 280 nm; PAK.
 photosynthetically active radiation between 400 and 700 nm;
Production   Crop
(It)6 metric
   tons)
                                          Production
C f reals
rice
wheat
corn
sorghum
barley
Legume* l/>u/*e*l
sovbean
peanut
bean

4|1
45X
451
72
I5K
KK
IV
42
Smw <.rtii>*
sugar c.inc
sug.ir heel
Root < r(i[>\
sweet potato
cassava
1 rev ( rti/x,
coconut
banana
nuts

775
2SI

I4(S
127
17
4
 PS  1. photosystem 1; PS II. photosystem  II;  d, plants with
 ribulose-bisphosphate earboxylase-oxygcnase  as primary car-
 boxyladng enzyme; Cj. plants with phosphoenol-p>ru\ate car-
 boxylase   as  primary  carhoxylating  en/yme:   KuUPcase,
 ribulose-l.S-bisphosphate  carboxvlabe-oxvgenase.  R.  red
 radiation,  FR. tar-red radiation. SLW, specihc leaf weight
 Physiological and biochemical effects of UV-B
 radiation
 Ultraviolet radiation can affect  the carbon balance of
 crops  in at least 4 different ways by allccting:  I) the
 primary photochemical events and electron transport
 reactions,  2)  the dark  reactions fixing carbon into re-
 duced compounds, 3) dark respiration, and 4) stomatal
 resistance.
 Pholosynthetic processes
 Although  there  are large  species  differences in sen-
 sitivity, UV-B radiation generally results in reductions
 in net photosynthesis. These reductions are  paralleled
 by decreases in Hill activity in crops such as pea (PiMini
 \aiivum  L; Brandle et al.  1977, Gurrard et  al.  1976,
 Van et  al. 1977),  collard (BrtiMica oleraceae  L. cv.
 acephala;  Van et al.  1977, Basiouny et al. 1978), and
 soybean (Glycine max (L.) Merr; Basiouny et al. 1978,
 Vu  et al.  1981), indicating the sensitivity of photosys-
 tem II (PS II) to UV-B radiation.  Both Brandle et ai.
 (1977) and Van et  al. (1977) concluded that although
 cyclic photophosphorylation  (PS  1) was also somewhat
 sensitive to UV-B radiation, the primary effect involved
 PS  II. In  a study of the etlects of UV-B  radiation on
 several C., and C4 crops. Basiouny et al. (1978) found
 that C, species were generally more sensitive than those
 with the  C4  photosynthetic  pathway.  This  sensitivity
 among other  factors,  was associated with significant re-
 ductions in Hill  activity. However, in peanut (Arm/us
 tiypogaea  L.), a "resistant" C,  species.  Hill activity was
 416
                                                                                             I'hyuul I'Unt 5H. IVKJ

-------
 T.ih 2  A summ.irv of the eltects ot UV'-B radiation on crop growth.
 A
                           elfects
     I  I'lioiiisynthcMs
       Hill reaction
       f-.lcctnin transport
       KuUI' carhoxyl.ise
       I'EI' caihoxylase
       Dark respiration
       Slomuta
       Pholosynthctic pigments

    2  Soluble proteins

    1  Lipids
    4  Carbohydrates
    5. Noii-pliolosynthetic pigments

    6  Plant hormones
    7  Ion transport

II  Morphological/anatomical effects

    I  Leat area

    2. Specific leaf weight
    i  Epidermal transmission
    4  Uron/mg gla/mg/chlorosis

    5  Seedling growth/stunting

    6  Dry mutter production/allocation

    7  Yield

C  Response differences

    I. Interspecific (species differences)
    2  Intruspecific (culuvar differences) ~

t)   Environmental interactions
    1  Visible radiation (pholoprotection)
    2.  Water stress
                     References*
                 I, 4. 5, 1. Id, 11,  12, 18, 32, 37, .18,
                 40. 41, 43, 44, 45, 47, 4H. 49, 55
                 I. 5, 12,  20. 38. 41,  44, 49
                 12, 44
                 I. 20, 38, 44, 46, 47, 48
                 47
                 12. 18, 37, 40
                 7, 12. 37, 39. 40
                 I, 5, 16.  18, 20, 38,  40, 41, 42, 46,
                 48, 49, 55. 56. 57
                 1,5. 16.  18. 20. 38,  40, 41, 42, 46,
                 47, 48. 49, 57, 58
                 IK, 41, 42. 57
                 2. 18. 20
                 3, 7, 15,  16, 30, 31.  32, 38, 41, 42
                 51. 52, 53, 54, 55. 56. 57. 5H
                 15, 51, 52, 53
                 3,6


                 3, 5. 8. 9, 16. 32,  36. 37, 38, 39,
                 41, 42, 48, 50, 57, 58
                 H, 9, 37,  48
                6. 19. 30, 31, 55
                 1, 3, 6, 7, 8. 9, 21, 30, 39, 40, 41
                 42. 46, 47, 48. 49, 50, 56
                 3, 5, 8. 9, 21, 32,  36, 37, 38, 39,
                 41, 42,46,49, 50. 51, 54, 56, 57
                 5,6.8,9, 14, 16,  18, 21, 22
                 36, 37, 41, 42, 43, 45, 49, 50, 56, 57
                 2, 4, 8, 18. 22


                 I. 2,4, 5, 6, 7, 8,  10, 14, 16,
                 IK, 2d, 21, 22, 30. 36, 39, 41,
                 42, 43, 44,45, 46,47, 50, 51.
                 54, 55, 56, 57, 58
                 3, 7, 8, 9, 16. 50
                7, 35. 36. 40, 45
                37, 39, 58
   I. Allen etal. 1978; 2. Ambler et al. 1978; 3. Ambler etal. 1975; 4. Bartholic et al.  1975; 5. Basiouny et al. 1978; 6, Benedict
   1934; 7 Bennett 19X1; X  Biggs and Kossuth  1978; 9. Biggs et al. 1981; 10. Bogenneder 1982; if Bogenneder and Klein
   1978; 12 llrjiullc el al. 1977; |4  Caklwell et al. 1975; 15. Orumm-Hcrrel and Mohr 1981; 16  Dumper! and Boscher 1982:
   18  Esser I9MO;  19  Oausman el al. 1975; 20. Garrard el al. 1976; 21  Kri/ek 1975; 22 Hart etal  1975.3(1  Robberccln jnd
  Cdklwell 1978; 31 Robberecht et al. 1980; 32. Sisson 1981; 35. Teramura 1982; 36 Teramura I9NO-.37 Teramura and Perry
   1982; 38. Teramura and Caldwell 1981; 39. Teramura et al. 1983; 40. Teramura et al. 1980. 41 Tevmi and Iwanzik 1982, 42.
  levimetal. 1981,43. Van et al. 1975; 44. Van et al. 1977; 45. Van et al. 1976;  46. Vu et al. 1983; 47 Vu et al. 1982a; 48. Vu
  et al.  !982b; 49. Vu et al. 1981; 50. Vu et al. 1978; 51. Wellmann 1982; 52. Wellmann 1975;  53. Wellmann 1971; 54
  Chassagne et al.  I981a, 55. Chassagne et  al. 1981b; 56. Hashimoto and Tajima 1980; 57. Tevim et  al. 1982; 58. Tevim et al.
   1983.

unaffected by UV-B radiation. Similarly, Hill  activity    1977, Sisson and Caldwell 1976, Teramura et al. 1980,
was unaffected in all the resistant C4 species.
  Reductions in  net photosynthesis were also coinci-
dent with ultrastructural damage to chloroplasts in pea
(Brandle et al. 1977) and soybean (Allen et al. 1978).
Disruption of the  membrane structural integrity par-
tially damages components necessary for both light and
dark reactions of photosynthesis. High UV-B irradiance
also significantly increases mesophyll  (residual) resis-
tance  to carbon dioxide and  thereby limits net photo-
synthesis in a number of plant species (Nrandle et al.
Teramura and  Perry 1982). This resistance term in-
cludes resistance associated with both electron transport
and  carboxylation reactions in photosynthesis (Jarvis
1971,  Nobel 1974).
  Tevini et al. (1981) reported large increases in sol-
uble leaf proteins in barley (Hordeum vulgare L.), corn
(Zea mays L.), bean  (Phaseolus vulgaris L.) and radish
(Raphanus sativus L.) grown  and exposed to a high
UV-B radiation dose. The authors indicated this might
be a reflection of increased synthesis of aromatic amino
   I'hynol HUnl. 5H. IVKJ
                                                  417

-------
acids, the precursors for flavonoid biosynthesis. In an
outdoor field experiment, Esser (1980) also lound thai
soluble leaf proteins in potato (Solatium tuberowm L.),
radish, bean,  and spinach  (Spinacia oleraceu  L.)  in-
creased with increasing UV-B irradiance. However, for
plants grown  under low  levels of visible  radiation,
UV-B radiation has also been shown to be effective in
decreasing total soluble  leaf proteins m sensitive crops
(Basiouny et  al. 1978. Vu et al. I982a, b). Due to  the
disparate  nature  of these  studies, these contrasting
findings may be the result of differences in experimental
conditions, the UV-B irradiance employed, or the  re-
flection of species response  differences to UV-B radia-
tion. Vu  et  al. (I982a) found  that total soluble leaf
proteins on a tresh weight basis increased after UV-U
irradiation in tomato (Lvcopersicon esculemum Mill.)
and corn, but  was reduced  in soybean and pea. Addi-
tionally there is evidence that UV-B radiation increases
soluble leaf proteins only during early leaf development
in soybean, and decreases thereafter (Vu et al. 1982b).
  Since as much as 50% of the total soluble leaf pro-
teins may be in the form of the major Cj carboxylating
enzyme,  RuBPcase (Stemback  1981), a reduction in
leaf protein  may  be a reflection of a  decrease in car-
boxylating  enzyme concentration.  Increasing  UV-B
radiation produced reductions in RuBPcase activity in
4-week-old soybean and pea, and in 8-week-old tomato
in shaded (0.22-0.25 mmol m"2 s~' photosynthetically
active radiation, PAR) greenhouse experiments (Vu et
al. I982a, h).  Although  net photosynthesis in pea and
cabbage  (Hrai\ica olcniceae L.  cv. capitata)  had been
shown to be  sensitive to UV-B radiation (Van et al.
1976), Garrard et al. (1976) found no significant differ-
ences m  RuBPcase activity  in these same crops. This
apparent discrepancy may be the result of differences m
UV-B irradiance or due to different growth conditions.
It is now  well documented for a number of plant species
that  net  photosynthesis is  more  sensitive  to  UV-B
radiation when plants are  grown under low levels of
visible radiation (Sisson  and Caldwell  1976,  Teramura
et al. 1980, Teramura 1982). Recently Vu et  al. (1983)
examined the  ctfocts ot  UV-B radiation on RuBPcase
concentration and activity in greenhouse-grown pea  and
soybean. They lound that high UV-B  irradiance, cor-
responding to a 36% decrease in  stratospheric ozone
concentration, reduced RuBPcase activity by as much as
40-60%  of Mylar control levels, and that this reduction
was due  to a decrease in the amount  of carboxylating
enzyme present, and not due to enzyme inactivation.


Dark respiration

The  carbon  balance of  crops can  also be affected by
changes  in dark respiration. After only 5 h of UV-B
irradiation, dark respiration was significantly greater in
pea exposed to a  moderate UV-B irradiance (Brandle
et al. 1977). Sisson and Caldwell (1976) found that dark
respiration was increased after only 2 days of moderate
UV-B  radiation in  Rnniex />atienria  L., a very UV-B
sensitive  herbaceous  plant.  In   soybean,  however,
Teramura et al. (1980) found that dark respiration was
unaffected by  low UV-B  irradiance  under a range of
different PAR growth conditions.  With the  paucity of
information available, it cannot be  concluded that dark
respiration in sensitive species is generally affected  by
UV-B  radiation. Furthermore, no conclusive data exist
on the  effects of UV-B radiation on photorespiration in
crop plants, other  than some preliminary studies  by
Esser (1980).

Stomala
Net photosynthesis  can also be limited  by the diffusion
of carbon dioxide entering the leaf through the stomata.
Although net photosynthesis was significantly  reduced
after 4  h of UV-B irradiation in pea, stomatal resistance
was unaffected (Brandle et al. 1977).  Stomatal resis-
tance,  accounting for 10-20%  of  the  total  leaf resis-
tance to carbon dioxide in soybean, was increased after
a 2-week exposure  to relatively low UV-B  irradiance
(Teramura et  al. 1980).  Bennett  (1981), using high
UV-B  irradiance in  greenhouses and  growth  chambers,
found  small increases in stomatal  resistance for bean,
soybean,  and  cucumber (Cttcumis sativus L.),  which
coincided with  significant reductions in net  photosyn-
thesis.  He also found that adaxial stomatal resistance in
one  bean  cultivar  was somewhat more  sensitive  to
UV-B   radiation  than  abaxial  stomata.  In  a  growth
chamber study on cucumber and radish, Teramura et al.
(1983) found thut moderate levels of UV-B radiation
produced only small increases in stomatal  resistance m
radish  after 12 days exposure, but  had  dramatic effects
on cucumber.  After only  1  day of irradiation, adaxial
stomatal resistance in cucumber increased by  3-fold and
remained high  for 8 or 9 days, and  then  dramatically
decreased. By this time, cucumber had apparently  lost
stomatal function as evidenced from  diurnal  studies on
stomatal response to water stress.

Photosynlhetic pigments
The  photostability  of  chlorophylls has also  received
considerable  attention.  Basiouny et  al. (1978)  found
that  reductions in total dry weight and net  photosyn-
thesis were paralleled by reductions in total chlorophyll
concentration  m  collard,  oats (Avena  saliva L.), and
soybean (C3  species sensitive  to UV-B radiation).
Meanwhile, chlorophyll concentration  m  resistant  C3
and C4 species was unaffected. They found no selective
differences in  the chlorophyll a OT b concentration of
sensitive plants. High UV-B irradiance in combination
with low  PAR growth levels produced significant  re-
ductions in chlorophyll concentration m bean and cab-
bage (Garrard et  al. 1976), pea (Vu et al. 1983). soy-
bean (Vu et al. 1983,  1982, 1981),  bean, barley, and
corn (Tevini et al. 1981). In general,  these studies indi-
cated that the degree of chlorophyll  destruction was a
418
                                                                                         Physiol Plant 58. 1983

-------
function of UV-B irradumcc, and that although less af-
lected, c.imlenotds responded similarly. The effects of
UV-U  radiation  on chlorophyll  a/h  ratios differed
somewhat between studies and  therefore could reflect
species  differences.  Vu  el al.  (I9HI)  reported  that
chlorophyll alh ratios decreased with increasing UV-B
irradiance m soybean, but increased in pea at high UV
irradiance (Vu  et al. I9K3). Tevini et al. (1981) con-
cluded that high UV-B irradiance inhibited the biosyn-
thesis of chlorophyll b  more than a, since alb ratios
increased in bean, barley, radish, and corn. In contrast,
when soybean was grown under a range of PAR growth
regimes in combination  with low and moderate UV-B
irradiance,  there appeared to  be  no  effect on total
chlorophyll concentration, despite  large effects on  net
photosynthesis  (Teramura et  al. 1980). In  fact, when
soybean leaves were expanded under 0.75 mmol m~2 s~'
PAR and moderate UV-B irradiance, there was an  ap-
parent stimulation in chlorophyll  biosynthesis  (Tera-
mura and Caldwell 1981). In  a field experiment, Esser
(1980) found that chlorophyll concentration decreased
in bean and increased in spinach under high UV-B ir-
radiance while  potato,  barley and radish were unaf-
fected. The reason for a reduction in chlorophyll and
carotenoid concentrations after UV-B irradiation is still
unclear.  It could  be the result  of an inhibition  of
chlorophyll biosynthesis, or due to the degradation of
these pigments or their  precursors.  Due to the large
differences both in growth and treatment  conditions,
more studies are necessary to determine whether these
differential responses are species specific or artifacts of
the experiments themselves.


I.ipids and carbohydrates

A combination of low PAR and high, continuous UV-B
irradiance produced  large reductions in the total lipid
content of corn  and  bean seedlings after only 5 to 10
days. Higher irradiance also  reduced lipid concentra-
tions in barley (Tevini et al. 1981). It appears from  this
study that UV-B radiation  has  a differential effect on
various membrane systems. The galactolipids, which are
principally found in chloroplasts, were  greatly reduced
in barley, corn, bean, and radish seedlings. This was also
paralleled by large decreases in  chlorophyll concentra-
tion in these crops. Shifts in specific galactolipid con-
centration were noted to be similar to the pattern found
during tissue senescence. Changes in the phospholipids,
which occur in generally all membranes, were seen in
bean and corn, but not in barley or radish. Under field
conditions, Esser  (1980) found  that  total lipids  in-
creased in bean and cabbage, decreased in spinach,  and
were unaffected in potato grown under unfiltered  UV
lamps. Due to the unnatural conditions under which the
plants  were grown and irradiated,  however, further in-
terpretation of these two studies  must be made  with
caution. Further work is needed to  substantiate these
observations.
  In growth  chamber  studies,  Garrard et al.  (1976)
found that  high UV-B  irradiance produced substantial
reductions  in the major carbohydrate components of
tomato, cabbage, and collard while it had little effect on
peanut  and corn.  UV-U radiation quantitatively af-
fected reducing sugars, sucrose, starch, and non-struc-
tural carbohydrates.  Of the five  crops tested,  tomato
was the most adversely affected in each case.  In a field
study using  unfiltered  lamps.  Ambler et al.  (1978)
found  that massive  UV enhancements resulted in  a
17-20% increase in  sugar beet (Beta  vulgaris L.) root
sucrose, despite reductions in shoot dry weight and root
fresh weight. In  another field experiment, low  supple-
mental  UV-B irradiance was supplied by sunlamps fil-
tered with  Schott WG 305 cut-off filters, and high ir-
radiance (UV-B and UV-C) was supplied by unfiltered
lamps (Esser 1980). Under these conditions, reducing
sugars and starch were only reduced under the unfil-
tered lamps in spinach and radish, while bean  showed
slight increases in these carbohydrate pools. Once more,
these studies indicate that UV-B radiation is most ef-
fective when PAR is low during growth.

Non-photosynthetic pigments
The attenuation of UV-B radiation by outer leaf tissue
layers is one means of reducing the UV-B flux received
at potentially sensitive sites. This  may  represent  an
adaptive response  to UV-B radiation. In a survey of
epidermal  transmission  of nearly 70 native  plants
(Gausman  et al.  1975,  Robberecht and Caldwell 1978,
Robberecht et al.  1980), it was found that  epidermal
transmission  in the UV-B waveband was generally be-
low  10%.  Furthermore, epidermal  transmission  was
lowest for  plants growing in regions of high, naturally
occurring UV-B flux, and increased as UV-B radiation
diminished along a latitudinal gradient.  Much of this
UV-B  attenuation was  removed  upon methanolic ex-
traction of  the epidermis, suggesting that phenolic com-
pounds such as  flavonoids  were  important in  the ab-
sorption of UV-B radiation. Such compounds produce
ideal UV screens since they are  nearly transparent in
the  visible region,  while possessing  high absorption
coefficients in the UV  region.  In greenhouse  experi-
ments, epidermal transmission was significantly reduced
by UV-B radiation  in corn (Robberecht and Caldwell
1978) and  pea (Robberecht et al. 1980).
  Under low PAR growth regimes and high  UV-B ir-
radiance, Tevini et  al. (1981) found  that a high con-
centration  of flavonoids (water  extractable)  was pro-
duced by seedlings which appeared to be relatively re-
sistant to UV-B  radiation (barley and radish).  In con-
trast, very  little flavonoid production was  found in the
sensitive species, corn and bean.  Flavonoid content in
barley leaves rose in direct response to increasing UV-B
irradiance,  suggesting that  this might be  a  protective
response.  Nevertheless,  moderate  UV-B  irradiance
produced significant reductions  in net photosynthesis
I'tuii..! Plant  5H. IVKJ
                                                                                                     419

-------
despite   an  increase   in   flavonoid   concentration
(mcthanolic extractable)  throughout  leaf ontogeny in
soybean  (Teramura  and  Caldwell   1981). Similarly,
Sisson {19H1) found that leaf expansion and net photo-
synthesis in squash (Cticurhita pepo L.) were repressed
hy moderate UV-B irradiance, although flavonoid ab-
sorbance  (methanolic  extractable)  substantially  in-
creased. Flavonoid concentration (acetone extractable)
also greatly increased m pea (Vu et ul.  1983) and soy-
bean (Vu et ul. 1981) leaves grown under high  UV-B
irradiance. UV-B  radiation has also been shown to
stimulate  flavonoid   biosynth&sis   in   parsley   (Pet-
rnwlinum Itormme Hoffm.) cell  suspension  cultures
(Wcllmann 11J7I, 1975),  and this induction apparently
involves  the phytochrome  system. Flavone glucoside
synthesis was stimulated  by a 1 h pre-irradiation with
UV-B  and this was further enhanced by a subsequent
15 h FR  irradiation. This FR effect was reversed by R
irradiation; however, neither R nor FR had any  effect
without pre-irradiation with UV-B. Wellmann (1982)
has also  recently  reported  that  flavonoid formation is
stimulated by  UV-B irradiation  in parsley  and  dill
(Anethum graveolens  L.) hypocotyl and roots, and of
wheat  (Tritiatm ucitmim L.) and rye coleoptiles. Due
to its  rapid and dose dependent response, its  high
quantum  effectiveness near 290  nm,  and the  strong
UV-B  absorption it appears that flavonoid biosynthesis
in these systems is a protective reaction against UV-B
radiation.
  High UV-B  irradiance  has been reported to increase
anthocyanm production in several crop species. Ambler
et ul. (1975) and Bennett (1981) have reported  the
formation of a  red pigment, presumably anthocyanins,
in cotton  (do\\ypnim hirsiitnrn L.) petioles. Recently,
Drumm-Herrel and  Mohr (1981) demonstrated that
anthocyanin synthesis  m  sorghum  (Sorghum  vulgare
Pers.) mesocotyls involved interactions between UV-A,
UV-B,  and phytochrome  photoreceptors. UV-B in-
duced anthocyanin production has also been reported in
mustard  hypocotyls,  and corn, wheat,  and  rye (Secule
cerate  L.) coleoptiles (Wellmann 1982). Although  this
pigment  production represents a specific UV-B effect,
anthocyanin biosynthesis may not be  particularly adap-
tive since it has little absorption in the UV-B waveband.


Ion transport

Very little work has been done on the effects of UV-B
radiation on ion transport. In an early study, Benedict
(1934) concluded that  UV-B radiation between  290
and  310 nm stimulated growth and  increased  calcium
content in tomato, soybean, and cucumber. Radiation
below  265 nm was inhibitory. However, these data must
be viewed with caution due to the extremely low visible
light growth conditions (approximately 0.04 mmol m"2
s~' PAR) used in this study. More recently, Ambler et
al. (1975) examined the influence of UV-B radiation on
"Zn translocation in seedlings of two  cotton cultivars.
In general,  "Zn translocation from  cotyledons  into
shoots was proportionately reduced as UV'-li irradiance
increased.
Morphological and anlomical effects of UV-B
radiation
l.eiif area and specific leaf weight
Among the most sensitive plant organs to environmen-
tal stress are plant leaves. Leaf area is generally reduced
by temperature, water, mineral, or salt stresses. There-
tore, it is not surprising that leaf area is also reduced by
UV-B radiation. In an extensive growth chamber study
screening over 70 unrelated crop species and cultivars.
Biggs and Kossuth (1978) found that leaf area was sig-
nificantly reduced  m over 60% of the cases. The most
sensitive crops included soybean, bean,  pea,  cowpea
[Vigna unguiculata (L.)  Walp.j, cucumber, watermelon
(Citrullus  vulgaris  L.)  rhubarb (Rheum  rhaponncum
L.), rutabaga [Brassica napobrassica (L.) Mill), kohlrabi
(Brassica  oleracea  L.  cv.   gongylodes),  and  brussel
sprouts (B. oleracea L. cv. gemmifera),.while little effect
was noted in rice (Oryza saliva L.), wheat, barley, millet
(I'ennisetum glaucum L.),   oats,  peanut,  cotton, and
sunflower (Heliantlius annuus L.). In  the most sensitive
plants, leaf expansion was reduced by 60-70% (Tevmi
et al. 1981, Biggs et al.  1981). It  must be noted, how-
ever, that such large area reductions are only found in
studies utilizing very low PAR. Teramura (1980) found
that UV-U radiation was more efficient at reducing leaf
expansion in soybean under decreasing PAR. Growth in
moderate UV-B irradiance  and high PAR had no sig-
nificant effect on soybean leaf area, and in fact,  ambient
UV-B irradiance  may  even stimulate leaf  expansion
(Teramura and Caldwell 1981). In field grown  crops,
leaf expansion was substantially increased by moderate
UV-B  radiation  enhancements  m  potato  (70% in-
crease) and mustard (30%  increase), while leaf expan-
sion was unaffected in corn, cowpea, peanut, rice, and
radish (Biggs and  Kossuth  1978).  It is noteworthy that
cowpea and mustard were among the most  sensitive
crops in terms of leaf area  reduction based on growth
chamber data, while field  experiments indicated they
were among those  most resistant. This suggests that
qualitative as well  as quantitative differences exist be-
tween  plants grown in growth  chambers  and those
grown in the field. Nevertheless, a  few  very  sensitive
species such as squash (Cucurbita pepo L.; Sisson 1981)
and cucumber (Teramura et al. 1983) do show signific-
ant leaf area reductions  even when irradiated with mod-
erate levels of UV-B and  high PAR, indicating their
potential sensitivity under  natural conditions.
   Plants may also adapt to a UV-B  radiation  environ-
 ment by increasing their specific leaf weight (SLW), the
 ratio of leaf mass  to area.  In  this manner, upper leaf
 tissue layers might act as anatomical screens or filters to
decrease  UV-B transmission into sensitive  underlying
 420
                                     Phynol Plinl 58, 1981

-------
  areas. Specific leaf weight was fount! to increase in a
  number ol soybean cullivars exposed to UV-Il radiation
  (Biggs et al.  1981,  Vu  et al.  1982). However,  in  a
  screening experiment of X2 different crop and other
  economically  important  species conducted in growth
  chambers (IJiugs and Kossuth 1978), SLW changes did
  not always correspond with UV-B radiation resistance,
  as was anticipated.  In fact, SLW was  unaffected by
  UV-B radiation m many plants and decreased in re-
  sponse to UV-B radiation in some species. Therefore,
  this  anatomical  manifestation  alone is  insufficient  to
  protect crops from UV-H radiation and cannot be used
  as an indicator characteristic of UV-B radiation stress
  per se.


  Rron/ing, glazing and chlorosis

  UV-B radiation  also  produces bronzing, scorching,
 glazing or chlorosis in leaves of susceptible plants such
 as soybean (Vu et al. 1983, Biggs et al. 1981), pea (Vu
 et al.  1978) and cucumber (Teramura et al. 1983). Un-
 der high  UV-B irradiancc, even  relatively  resistant
 crops such as  barley (Tevmi et al.  1981) and  cotton
 (Ambler et al. 1975, Krizek 1975) show these effects.
 However, these symptoms are nearly always associated
 with plants grown under either high UV-B irradiance or
 with moderate UV-B irradiation but low PAR. In field
 studies with high UV irradiance supplied by unfiltered
 lamps, these  symptoms  have  not   been  reported.
 Nevertheless, a few crops such as cucumber and at least
 one cultivar  of soybean (cv. Hardee)  do seem to de-
 velop  some of  these manifestations when grown  under
 moderate UV-B irradiance and high PAR (Teramura et
 al. 1980, Teramura et al. 1983),  indicating that they
 may  occur  m  natural conditions.  Robberecht  and
 Caldwell  (1978) reported that leaf bron/ing  was not
 apparent  in corn, but did develop in tomato exposed to
 UV-B radiation in a greenhouse. The authors suggested
 that this might  be partially due  to differences in UV-B
 epidermal transmittance, since a significant increase in
 tlavonoid biosynthesis was found  in corn, but not in
 tomato. The presence and effectiveness of UV-B ab-
 sorbing pigments in the leaf epidermis may be  impli-
 cated in explaining some of the differences in observed
 leaf symptoms  discussed above.

 Plant stunting

 One of the most common observations on seedling
 growth after UV-B irradiation is stunting or dwarfing,
 primarily resulting from a decrease in internode length.
 Similar to  bronzing and chlorosis, stunting is  exacer-
 bated by  high  UV-B  irradiation and  low PAR. In a
 greenhouse study, Teramura (1980) found that after 6
 or 7 weeks exposure to a range  of moderate UV-B ir-
 radiance,  stunting in wheat and  soybean  was  only
 observed in plants grown under shaded conditions. In
 tact, under unshaded conditions  more  closely ap-
 proximating those of the field (average mid-day PAR =
 1.6 mmol m~- s"1),  soybean which did not receive any
 UV-B radiation were shorter than those grown under
 low and moderate levels ot UV-B. Stunting in soybean
 was primarily due to shorter internodes and not a re-
 duction m  node number. This suggested that  UV-B
 radiation did not simply delay the rate of plant de-
 velopment, but rather  involved some intrinsic growth
 characteristics. In a field experiment. Biggs and Kossuth
 (1978) reported that the height of the mam stalk in corn
 was reduced by UV-B radiation, although their data
 indicate that the greatest  reduction occurred under the
 lowest UV-B  radiation  enhancement.  In the same
 study,  rice height   was unaffected and  squash  even
 showed a slight stimulation of growth. In another field
 experiment, Ambler et al. (1978) found that high UV
 (UV-B and  UV-C) irradiance  from untiltered  lamps
 had no effect on height in soybean, sorghum, or corn.


 Dry matter production and allocation

 Total  plant biomass accumulation (dry weight) is a good
 indicator of  UV-B  radiation effects on  growth. Total
 biomass represents a long-term integration of all bio-
 chemical,  physiological,  and   growth   parameters.
 Therefore, even  subtle UV-B induced effects on phy-
 siological processes could accumulate and result  in sig-
 nificant effects on biomass. Since plant biomass data are
 easily  obtainable, it  is not surprising that a number of
 studies (Tab. 3) have  included the effects of  UV-B
 radiation on dry matter production and  its allocation
 into component plant organs. These studies show that
 total plant dry weight is often substantially reduced by
 UV-B. Brandle et al. (1977) found that dry weight in
 pea was significantly reduced after only 9 days of  UV-B
 irradiation.  Although  large species differences  exist
 (Tab.  3), reductions in  total biomass are often accom-
 panied by substantial modifications m  the partitioning
 of biomass into component plant organs. In dicotyle-
 dons, a greater proportion of biomass is  allocated into
 leaves (despite an absolute reduction in leaf area) and
 less into stems and roots. In species such as so>bean,
 bean, pea, and cucumber, the increase in the proportion
 of dry  weight found in leaves is the result  of an increase
 in SLW. This trend is not nearly as clear m monocotyle-
 dons, where a multitude of species specific responses
 are found. As with the other morphological and ana-
 tomical  characteristics   previously  examined,   the
 greatest effects on total dry weight accumulation and
 biomass realiocation  were reported in growth chamber
 (Biggs and Kossuth 1978)  or shaded greenhouse (Vu et
 al.  1978, Van et al.  1976) studies. Teramura (1980),
 using  various combinations of UV-B and PAR  levels
 found  that soybean dry  weight and the allocation into
various organs  were increasingly  affected as growth
PAR levels decreased.  This indicated  that  UV-B in-
duced reductions in total biomass were magnified under
low PAR regimes.
Phmol Pljni 5H. IVKJ
                                                                                                    421

-------
T.ih  1  Elfccts of ullravuilel-U radiation on greenhouse and growth chamber grown plants. *, refers to citations in Tab 2.

                                                    UV effects on total plant dry weight
C'rop
Wheat
Rice
Corn
Darky
Oats
Sorghum
So\bean
Collon
Beans
Peas
Rye
Tomato
Millet
Peanut
Radish
Cucumber
Squash
C.ibh;ige
Collards
Onion
Lettuce
Celery
Carrots
Parsnip
Eggplant
Hell pepper
Chard
Okra
Asparagus
Artichoke
Sunflower
Itroccoli
Hrusscl sprouts
Cauliflower
Kale
Kohlrabi
Mustard
Rutabaga
Pumpkin
Watermelon
Cantaloupe
Oiufa
Rhubarb
Increase
8*



X




8

6

8
8
6





8
8

8




8
8










8

Decrease
8, 36
8
8, 50
8, 57
5, 43, 45
8, 45
5, 8. 9, 21, 36, 37,43,45, 49, 50

8,42
8, 12, 43, 45, 50
8, 45
8,45
8

57, 58
8
8
8,45
5, 8, 45

8





8
8



8
8
8
8
8
8
8
8
8
8

8
No change
8, 21
8, 45
5, 42, 43, 45. 57
42

5

2, 8. 21
21, 57


21
21, 43, 45
5, 43. 45
21,42
21



8
21


8

8


8








-





  In a field study with unfiltered lamps. Ambler et al.
(1978) found that massive UV doses simulating up to an
8-fold increase  in  ambient  levels, had  no effect  on
abovcground dry weight production in squash (Cucur-
bita  maxima L.), bean, or corn; however,  reductions
were noted for broccoli (B. oleracea L. cv. botrytis) and
sugar beet (Tab. 4). Also using unfiltered lamps. Hart et
al. (1975) found no effect on corn, sorghum, soybean or
peanut. Biggs and Kossuth (1978) on  the other hand,
reported total dry weight reductions in field grown corn,
pea, tomato and mustard (Brassica juncea cv. cripifolia)
irradiated with filtered  lamps.  Interestingly,  plant dry
weight was somewhat stimulated by the highest UV-B
irradiance in potato although this  stimulation cannot
presently be explained. In sensitive  crops, leaf biomass
proportionately increased,  while stem and sometimes
root biomass decreased. The  trends  observed in  this
field study were remarkably similar to those found in
growth chambers. In another field experiment, Caldwell
et al. (1975) found that aboveground dry weight  was
reduced in barley and pepper (Capsicum annum  L.),
while belowground reductions were observed  in soy-
bean, pepper and  corn. Alfalfa (Medicago sativa L.) and
tomato  were apparently unaffected by  the  relatively
large UV-B irradiance (simulating  5U% ozone deple-
tions) used in that study.
 422
                                     Phynol Plant 58. 198}

-------
 I ab 4  Effects of UV supplementation on field grown crops. I), unaffected, •*-, stimulated and -, decreased relative to controls. 1,
 unliliered 13ZS-CLG and HS-40 bunlamps, 2. FS-40 sunlamps filtered with (I 13 mm cellulose atetate, 3. F-S-4IJ sunlamps tillered
 with (i 13 mm  Kodacel IA4DI, 4. untiltercd r-S-40 sunlamps.
Crop
Rice
Corn
Potato
Sorghum
Sovbe.m
Sugar beet
Ue.ms
Cowpea
fomulo
Pcamil
Pepper
li.irley
loh.iccn
Millet
Calibiige
Squash
Hroccoh
Must.ird
UV effect on total dry weight
Ambler et1 Biggs and' C.ildwell et->
al. (I97H) Kossuth (I97H) al. (1975)
0
0 - -t-
+
0
0
"
0
0
0
0
-
—



0 0
—
—

Hart et al.4
(1975)

0

0
0




0


1)
0
0



Crop yield

Nearly all of our information on the effects of UV-B
radiation on crops comes from either growth chamber
or greenhouse studies. Owing to space limitations, it is
impractical to grow plants to reproductive maturity in
such facilities. Of all the components of dry matter pro-
duction,  allocation  into reproductive  organs or crop
yield is of major interest in crop species. It  is the key
factor  in our assessment of the impacts of a  partial
stratospheric ozone depletion.  Yet surprisingly, only a
handful of studies exist where plants were grown to a
stage with harvestable fruit (Tab. 5), and none of these
arc readily available to the scientific community. With
the exception ul leafy  vegetables, whose  yield  may
perhaps be assessed in the confinement of controlled
environments, our  understanding  of UV-B  radiation
effects on crop yield is based on only a few field trials
and on a  limited number of crops. Hart et al.  (1975)
grew 10 crop species [tomato, sweet pepper, corn, sor-
ghum,  soybean, peanut, cotton,  tobacco  (Nicotiana
tdbacnm  L), millet and  cabbage]  under  unfiltered
(FS-40) sunlamps, providing a very large UV radiation
(UV-B and  UV-Q supplement. Despite this massive
UV dose, they only found a significant reduction in fruit
number in pepper, and only  for one of the two experi-
mental growing seasons. Yield was unaffected in the 9
other crops.  In a similar field experiment. Ambler et al.
(1978) used unfiltered (BZS-CLG and FS-40)  sun-
lamps to test 8 crops (squash, bean, corn, sorghum, soy-
bean, sugar  beet, broccoli and cowpea). Based upon
their biological effectiveness  (A£9 weighting function).
these lamps produced UV enhancements up to 8-fold
greater than normally incident in the field. Again, de-
spite the high UV irradiance, yield was significantly re-
duced  only in broccoli. Esser (1980) conducted a field
experiment in the Federal  Republic of Germany using
filtered (Schott \VG 305, 2 and 3 mm) and unfiltered
(Philips  TL 40/12) sunlamps over 6  crops  (potato,
spinach, bean, radish, barley, and cabbage). The radia-
tion from filtered lamps simulated UV-B enhancements
resulting from less than 10% ozone depletions and had
no significant effect on yield in any of the crops tested.
In fact, yield was slightly stimulated in  most crops re-
ceiving the additional UV-B radiation. Unfiltered lamps
which produced irradiances simulating up to 40% ozone
reduction, reduced yields in potato (lubers) by as much
as 41%, spinach (leaves) by 66%, cabbage (leaves) by
49%, and bean (pods) by  as much as 75%. However,
the emission from these unfiltered lamps also included
UV-C radiation. Because of the strong wavelength  spe-
cificity of biological  responses, the large effects resulting
from unfiltered lamps are most likely grossly  exagger-
ated and therefore,  interpretations from studies using
unfiltered lamps should only be made with utmost cau-
tion.
  An interesting field study was conducted by Bartholic
et al. (1975)  in Florida.  Three crops (corn, bean,  and
tomato)  were grown under panels covered with either
UV-B   absorbing  (Mylar)  or  UV-B  transmitting
(polyethylene) films. Plants grown  under the Mylar
panels  had the direct beam component of the naturally
occurring UV-B  irradiance filtered  out,  but  still re-
ceived  the diffuse component. This diffuse component
Ptmiol. Plant. 58. IVHJ
                                                                                                     423

-------
I .ill S  A summary »l licld studies on the ellccu of supplemental UV radiation on crop yield. Values represent the percentage
Ji.inge  Iron) comrolb  I, unhltcrcd sunlamps, 2, ambient UV-L) irradiuncc; .1. cellulose acetate tillered sunlamps. 4, \alues nul
given
( rop
Rice
C'om
Potato
Sorghum
So\hean
Sugar heel
Deans
C'owpea
Tomato
Peanut
Pepper
C'otlon
"fohacco
Millet
Cahhuue
Squash
liroeeoli
Radish
Mustard
Sptnaeh
Hart el1
al. (1975)

0

1)
(1



I)
II
()/-•'«
(1
II
I)
1)




ll.irtliolic' Amhleret'
et al (1975) al. (1978)

+ 8% 0

1)
I)
0
0 II
I)
0






0
-45%



fiieus' and Esser1
Kos.siith (1978) ( I9SII)
0
0 1
II — K)%



-75'".,
-26%

(1




-49%
-69%
n
-19%
-66%
contains nearly 50% of the total incoming UV-B radia-
tion. They found no yield differences in bean or tomato,
Init yield  in corn  was significantly greater under the
polyethylene panels (Tab. 5). This apparent stimulation
in yield was al least partially the result of greater insect
infestation under the Mylar panels.
   Biggs and Kossuth (1978) used filtered (0.13  mm
cellulose  acetate)   sunlamps  (FS-40) to  supplement
natural UV-B radiation in the field. Unlike the previ-
ously  described studies,  they used  an  artificial  soil
medium in raised  beds  and grew 9 crops (potato, to-
mato,  corn, pea,  peanut,  squash,  rice,  mustard,  and
radish) under a gradient of increasing UV-B radiation.
Total yield in corn, rice, radish, peanut, and potato was
uii.illcftcd by enhanced levels of UV-U, although there
was some evidence ot qualitative changes in tuber and
fruit sizes in potato and peanut, respectively. In mus-
tard, the only leaty crop investigated, enhanced UV-B
resulted in significant reductions in  leaf dry weight and
therefore  yield. In  squash, total fruit weight decreased,
while both total fruit weight and number diminished  in
pea. UV-U irradiation also resulted in reductions in to-
tal fruit production and average fruit weight in tomato.
Although  the results from  this study suggested  that
UV-B radiation from filtered lamps was  apparently ef-
fective in reducing yield in  4 out of 9 crops, the mag-
nitude of yield reduction was not generally related  to
UV-B dose. In 2 of the 3 crops showing fruit yield re-
ductions,  the highest UV-B irradiance had only a small
effect, while a much lower one produced substantial
effects. As was the case in the study by Bartholic et  al.
(1975), some of these inconsistencies were produced  by
insect infestation (R.  H. Biggs personal communica-
tion).
  Until  the discrepancies can be resolved, all the field
experiments to date have only limited use. As can be
gathered from these disparate studies, much more in-
formation is needed before a reliable assessment can be
made on  the effects  of  a  partial  ozone  depletion on
global crop productivity.
Response differences to UV-B radiation
Prior to  the organization of the Climatic Impact As-
sessment Program (CIAP) by the U.S. Department of
Transportation (Nachtwey et al.  1975), very little was
known about the effects of UV-B radiation on plants. In
fact, nearly all the  studies available  up  to that time
utilized broadband UV-C radiation or monochromatic
UV-C radiation, principally 254 nm. Unfortunately,
known photobiological responses to 254 nm can only be
used for comparative purposes and  not for extrapola-
tion or quantitative assessments of UV-B  radiation  en-
hancements arising  from projected  ozone  reductions.
Not only do quantitative differences in response occur
between the two wavebands, but there has been some
suggestion that  qualitative  differences might  also  be
present (Nachtwey  1975). Therefore, one  of  the pri-
mary objectives of CIAP was to empirically determine
UV-B sensitivities in a range of different plant and crop
species. As a result of this and other continuing efforts,
over 45 different crop species have been screened under
a diverse range of environmental conditions in growth
424
                                                                                           Phyjiol. Plinl 58. 1981

-------
  chambers and greenhouses (Tab. 3), and in a limited
  number of ticld  experiments (Tab. 4). This numher
  would approximately double if crop cultivars and other
  economically important plant species are also consid-
  ered.

  Interspecific differences
  There are large interspecific response  differences to
  UV-B radiation  in terms of total biomass production
  (Tabs  3  and 4). Some species are  resistant to  UV-B
  radiation, most are sensitive to a degree, while growth
  in others  is apparently  stimulated. In  an extensive
  screening experiment conducted in growth chambers in-
  cluding over 40 crop species and 30 cultivars (Biggs and
  Kossuth  1978), about 30% of the  crops tested were
  cither  unaffected or stimulated  by  UV-B  radiation,
  another 20% were extremely sensitive, and the remain-
  der were  intermediate in sensitivity, based upon total
  dry  matter production.  Considering all  other plant
  characteristics which were influenced by UV-B  radia-
  tion, such as leat area, height,  biomass partitioning pat-
  tern, etc, there apparently is an enormous array of
  UV-B  responses expressed by different crop  species.
 Obviously, a multitude of morphological, anatomical
 and physiological processes all act in  concert to provide
 different  species  sensitivities,  including  differences in
 cuticle  thickness, the presence of UV  absorbing pig-
 ments, changes in SLW, leaf  reflectivity, crop or leaf
 canopy development, etc.
   Regardless of these species specific response differ-
 ences,  however, a  few  broad generalizations can be
 made,   given   the  same   treatment   conditions.
 Monocotyledons as a whole, seem to  be less affected by
 UV-B  radiation than dicotyledons (Van and Garrard
  1975, Teramura 1980, Tevini  et al. 1981). It has been
 suggested  that this difference might be partially due to
 the vertical leaf orientation, protective basal sheath, and
 the protected menstematic region in monocotyledons
 (Van and Garrard  1975). At least one study (Basiouny
 et al.  1978) concluded that crops with  the C, photo-
 synthetic  pathway were more affected than those with
 the C4 pathway.  In  terms of plant  height  and total
 biomass accumulation, those  researchers  found that
 neither of the C4 crops investigated (sorghum and corn)
 was affected by UV-B irradiation, while all the Cj crops
 (collard, oats, peanut, and soybean) had at least one of
 these  characteristics  affected. Finally,  some  plant
 families show relatively uniform responses. For exam-
 ple, 8 of  10 crops belonging  to the  Cruciferae  were
 extremely  sensitive  to   UV-B  radiation  while  the
 Poaceae was  relatively resistant (Uiggs  and Kossuth
 1978).


Inlraspecific differences

In addition to  the sizable interspecific  differences in
UV-B radiation response, there is an appreciable in-
 traspecific response difference (Tab.  3). Many of the
 crops listed showed a variable response to UV-B radia-
 tion in terms of dry matter production. Although some
 of this  represents differences  in  UV-B irradiance or
 treatment conditions between individual studies, it also
 reflects  cultivar  response  differences. Large  cultivar
 differences in UV-B  response have  been reported in
 soybean  (Biggs et  al. 1981, Vu  et al. 1978), cotton
 (Ambler et al. 1975), bean  (Bennett  1981, Dumpert
 and  Boscher 1982), collard  and  cabbage  (Van et al.
 1976, Garrard et  al. 1976), wheat, barley, corn  and rice
 (Biggs and Kossuth 1978), and spinach (Dumpert and
 Boscher  1982). In a growth chamber study of 19 soy-
 bean cultivars. Biggs et al. (1981) concluded that 20%
 were extremely sensitive  to UV-B radiation, 20% were
 relatively  resistant,  and  the remainder were inter-
 mediate in sensitivity. Surprisingly, these proportions of
 sensitive and resistant cultivars are very similar  to those
 found between species,  indicating that a tremendous
 range of intraspecitic variability to UV-B  radiation is
 present  in the  soybean  germplasm.  Currently,  the
 reasons  for the cultivar variability are  not completely
 understood, nevertheless it does suggest that there is a
 potential for  genetically  modifying future cultivars to
 minimize the  deleterious effects of a global ozone de-
 pletion.
Acknowledgements - The author would like to thank Irv For-
seth, Roman Mirccki and John Lydon for their comments on
.in earlier version ol lliib manuscript. Also many thanks ui Inez
Miller tor her careful typing. This work was supported by the
United Slates Environmental  Research Laboratory in Corval-
lis, Oregon (CR 808-035-020), and grunts from the Graduate
School  and  Provost to the  author.  Scientific Article  No.
A-3368, Contribution No. 6440 of the Maryland Agricultural
Experiment Station, Department of Botany.  Although  the
work described in this article has been funded in part by the
United  States Environmental  Protection Agency, it has  not
been subjected to the Agency's required peer and policy re-
view and therefore does not necessarily reflect the view of the
Agency and no official endorsement should be interred
  Travel to the international  workshop held in Delhi, India.
was supported by N. S F
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Edited by L. O.  Bjorn and J. F. Bornman


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