United States
Environmental Protection
Agency
Office of Research
and Development
Washington DC 20460
EPA-600 '8-80-046
September 1 980
Research and Development
An  Introduction
to the Treatability
Manual for
Industrial Wastewater
Videotape Series
Workbook

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                                        EPA-600/8-80-046
                                        September  1980
       AN INTRODUCTION TO THE
         TREATABILITY MANUAL
      FOR INDUSTRIAL ¥ASTEWATER
      VIDEOTAPE SERIES WORKBOOK
 Office of Research and Development
U.S. Environmental Protection Agency
       Washington, D.C.  20Jf60

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                            ACKNOWLEDGEMENTS

     The Wastewater Treatability Coordination Committee developed
this videotape series entitled "An Introduction to the Treatability
Manual for Industrial ¥astewater."  The series was coproduced by
EPA's television unit in Cincinnati, Ohio, and EPA's closed circuit
television studio in Washington, D.C.

     Assistance in the videotape production and workbook preparation
was provided by individuals from EPA's Center for Environmental
Research Information (CERl), Industrial Environmental Research
Laboratory-Cincinnati (lERL-Ci), Office of Water Enforcement (OWE),
and Office of Water and Waste Management (OWWM), and from Monsanto
Research Corporation and MATHTECH, Inc.

     The Wastewater Treatability Coordination Committee particularly
thanks the following individuals for their participation in the
videotape production:
     Sarah Compton- Deputy Asst. Administrator  OWE
     William Cawley
     Bill Chang
     Paul Fahrenthold
     Gail Goldberg
     Thomas Hughes
     William Jordan
     Gregory Kew
     Susan Korper
     Jack Newman
     Terry Oda
     Harry Thron
lERL-Ci
OWE-Permits
OWWM-Effluent Guidelines
OWE-Permits
Monsanto Research
OWE-Permits
OWWM-MDSD
MATHTECH
Region V
Region III
OWE-Permits
                        U,S. Environmental Protection Agency

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                                 PREFACE

     The videotape series you are about to see was prepared to introduce
the Treatability Manual to State and EPA regional offices.  The purpose
of the videotape and workbook is to brief potential users of the Manual
about its content and uses during the next round of NPDES permits.  The
format of the videotape series is:

Tape 1                              Introductory Remarks
Tape 2                              Description of Contents
Tape 3                              Permit Exercise - Gum and Wood Chemicals
Tape U                              Permit Exercise - Textile Mills
Tape 5                              Panel Discussion

     This workbook is designed for use in conjunction with the videotape.
A summary of each tape is included in this workbook along with an
identification of the participants and any illustrations used or pages
cited in the videotape.  Also included is a copy of the Federal Register
notice of the availability of the Manual.  The notice summarizes the
genesis, content, and potential utility of the Manual.

     NPDES Permit Applications #1 and #2 for the Gum and Wood Chemicals
Exercise and the Textile Mills Exercise should be reviewed prior to
viewing Tapes 3 and k.  Additionally, it will clarify the presentations
if you read the tape summary before viewing each tape.
                                   iii

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                            TABLE  OF CONTENTS



Tape 1 - Overview of the Treatability Manual	1

Tape 2 - Description of Contents	2

     Volume 1	3
     Volume II	13
     Volume III	28
     Volume IV	37
     Volume V	V/

Tape 3 - Gum and ¥ood Chemicals Permitting Problem	57

     NPDES Permit Application #1	58
     Method Used for Solution 1	73
     Solution 1	77
     Solution 2	88

Tape k - Textile Mills Permitting Problem	101

     NPDES Permit Application #2	102
     Solution 1	117
     Solution 2	126

Tape 5 - Panel Discussion	139

Appendix A - Members of the ¥astewater Treatability Coordination
Committee

Appendix B - Federal Register Notice of the Availability of the
Treatability Manual

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                                TAPE  1

     This portion of the Treatability Manual orientation, Videotape 1,
consists of introductory remarks by R. Sarah Compton, Deputy Assistant
Administrator for Water Enforcement and J. William Jordan, Chief,
Industrial Permits Branch.  Sarah Compton discusses the Manual and its
role in the next phase of NPDES permits to control toxic pollutants.
She provides background information on the formation of the Wastewater
Treatability Coordination Committee which guided the development of
the document.  Members of the Committee included representatives of
the Office of Research and Development, the Office of Water Enforcement's
Industrial Permits Branch, the National Enforcement Investigations Center,
the Office of Water and Waste Management's Effluent Guidelines Division,
and contractor support from Monsanto Research Corporation, Aerospace
Corporation, and MATHTECH, Inc.  (Appendix A of this workbook provides
a complete list of Committee members.)

     Sarah Compton also describes, in general terms, the contents of
the Treatability Manual's five volumes and what data sources were
utilized.  In addition, Ms. Compton discusses the Federal Register
notice of the availability of the Manual and request for comments.
(This notice is included in Appendix B of your workbook.)

     Bill Jordan's remarks focus on the strategy for the next round of
NPDES permitting.  He points out that in the past, most permits focused
on the control of traditional pollutants.  However, the next round will
be more complex since the new consolidated permit application form and
regulations are intended to control toxic pollutants as well.  Mr. Jordan
discusses a two-pronged approach to assist permit writers during the
implementation phase.  The first part of the approach is to develop
industry teams of experts on several priority industrial categories in
order to provide assistance to other permit writers and develop model
permits on specific industries.  The second part is the development
and distribution of guidance documents.  The Treatability Manual
constitutes one such guidance document.

     Sarah Compton then introduces Gregory Kew (formerly the Industrial
Permits Branch's project manager during development of the Manual and
currently with the Office of Water and Waste Management) who will briefly
describe the format of this videotape series in the introduction to Tape
2.

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                      TAPE 2  DESCRIPTION OF CONTENTS


     A detailed description of the contents of each volume in the
Treatability Manual is given by Gail S. Goldberg and Bill Chang from
the Permits Division in EPA, headquarters.

Volume I                            Treatability Data
Volume II                           Industrial Descriptions
Volume III                          Treatment Technologies
Volume IV                           Cost Estimating
Volume V                            Executive Summary

     The following pages include both the illustrations used in this
tape and the original pages from the Manual used to generate the
illustrations.

     You may notice that in some cases, data cited in the videotape
are different from those found in the September, 1980, edition of the
Treatability Manual.  These discrepancies resulted from the fact that
the videotape series was prepared prior to the final draft (6/23/80)
of the Manual.  Where possible, the final text pages with corrected
data and revised formating have been included in-the workbook.  In
some cases, where the clarity of the presentation would be diminished
by using final pages, text pages are included from previous drafts.
In one instance,  Volume II, Table 6-63, the data were revised
subsequent to the preparation of the final draft.

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         VOLUME I - TREATABILITY DATA






Physical, chemical, and biological properties



Carbon adsorption data (organics)



Precipitation and coagulation properties (metals)



Industrial occurrence



Probable fate



Pollutant treatability

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            Formula:  [O
Compound:  Benzene
Alternate Names:
            Benzol,
            Cyclohexatriene
CAS #:  71-43-2

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Physical, Chemical, and Biological Properties [1-3]

mol. wt.:  78.12    m.p., °C:  5.5             b.p.  (760 torr), °C:  80.1
vapor pressure (25°C),  torr:  95.2
solubility in water  (25°C), mg/L:  1,780-1,800
log octanol/water partition coefficient:  Conflicting data reported
Henry's law constant:  5.55 x 10~3 atmos. m3 mole"1
biodegradability:  33% theoretical oxidation of 500 ppm benzene by
                   phenol-acclimated sludge after 12 hr aeration

Probable Fate  [1]

photolysis:  Photooxidation of volatilized benzene is the only form of
             photolysis which occurs
oxidation:  No aqueous oxidation occurs, but volatilized benzene is
            photooxidized at a rapid rate
hydrolysis:  Not important
volatilization:  Rapid volatilization  (half-life =4.81 hr) is the primary
                 transport process for benzene
sorption:  Benzene should be adsorbed by organic material
biological processes:  Low potential for bioaccumulation; metabolized to
                       catechols by many organisms;  biodegraded at a slow rate
other reactions/interactions:  Not important

Carbon Adsorption Data  [43]
pH:  5.3
type of carbon:
adsorbability:
                                               1.000
 Filtrasorb-300             g
9,000 mg/L; carbon dose re- |
quired to reduce pollutant  ^
concentration from 10 mg/L  |
to 1 mg/L at a pH of 5.3    S
                            S
                            r
                            1
                                                        LO       U      MO

                                                         RESIDUALCONC. (Cf>. mg/L
                                                                              ion
 Date:   6/23/80
                    1.9.1-1

                       5

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      Probable Fate
        Photolysis
        Oxidation
        Hydrolysis
Carbon Adsorption Data
           pH
      Type of Carbon
       Adsorbability

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Compound:   Benzene                        Formula:

Alternate Names:  Benzol, Cyclohexatriene

CAS #;  71-43-2

Physical,  Chemical, and Biological Properties [1-3]

mol. wt.:   78.12    m.p., °C:  5.5             b.p. (760 torr), °C:  80.1
vapor pressure  (25°C),  torr:  95.2
solubility in water  (25°C), mg/L:  1,780-1,800
log octanol/water partition coefficient:  Conflicting data reported
Henry's law constant:  5.55 x 10~3 atmos. m3 mole"1
biodegradability:  33% theoretical oxidation of 500 ppm benzene by
                   phenol-acclimated sludge after 12 hr aeration
             Photooxidation of volatilized benzene is the only form of
             photolysis which occurs
            No aqueous oxidation occurs, but volatilized benzene is
            photooxidized at a rapid rate
             Not important
volatilization:  Rapid volatilization  (half-life = 4.81 hr) is the primary
                 transport process for benzene
sorption:  Benzene should be adsorbed by organic material
biological processes:  Low potential for bioaccumulation; metabolized to
                       catechols by many organisms; biodegraded at a slow rate
other reactions/interactions:  Not important


                 Filtrasorb-300
                9,000 mg/L; carbon dose re-
                quired to reduce pollutant
                concentration from 10 mg/L
                to 1 mg/L at a pH of 5.3
                                            S
                                            r
                                            1

no
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f


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vi









100 1.01
                                                         RE5IDUALCONC. 
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                 Industrial Occurrence of Benzene
                              Raw Wastewater
                   Concentration jjg/l       Loading, kg/d
°°        Industry   Min   Max   Mean   Min    Max   Mean
         Coal     ND     15    2.6    0    0.069 0.0098
         Mining

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o
0)
ft
to
00
o
INDUSTRIAL OCCURRENCE OF BENZENE
                                a,b
H
 I
ro

Raw wastewater
Concentration, yg/L
Industry
- -. '••' . ".* <&
Textile mills
Timber products processing
Petroleum refining
Paint and ink formulation
Gum and wood chemicals
Rubber processing
Pulp, paper and paperboard mills
Auto and other laundries
Pharmaceutical manufacturing
Ore mining and dressing
Steam electric power generating
(condenser cooling system)
Steam electric power generating
(water treatment)
Inorganic chemicals manufacturing
Coil coating
Foundries
Leather tanning and finishing
Nonferrous metals manufacturing
Iron and steel manufacturing
Minimum
».-&'-
NA
BDL
NA
ND
BDL
NA
<1
ND
ND
ND

NA

NA
NA
<10
ND
ND
ND
NA
Maximum
y. v^..
200 *
2,800
NA
9,900
710
3,400
3
23,000
2,100
4.2

NA

NA
156
<10
NA
150
160
43,000
Mean
. NfcA.
<5
350e
>100
1,200
180
610
<2
840
220
2.1

45

2
NA
<10
200
19
11
2,000
Loading, kg/d
Minimum
..^'-"^V-*
2~\ x lO1^
0
0
0
0.0016
0.00012
0
0.00076
0
0

0.0024

1.2 x 10~8
0
<0.0005
0
0
0
0
Maximum

0.14
16
9.3
0.055
1.3
0.52
NA
1.2
0.18
NA

0.050

0.12
0.94
<0.018
1.3
NA
NA
NA
Mean
v%£«jiJ^F
'o.°o69*o~
0.030
0.58
0.0019
2.7
0.020
0.060
0.18
0.20
0.078

0.011

0.0003
0.19
<0.0048
0.54
0.029
0.58
360

      Information contained in this table was obtained from Volume II of the Treatability Manual.
      NA - not available; ND - not detected; BDL - below detection limit.
     "Pollutant loadings determined by multiplying mean pollutant concentration by industry wastewater
      discharges as reporteed in Section 1.3, where mean is not available, one-half the reported
      maximum was utilized.
      Median, not average.
     £*
      Average of maximums reported for various industry segments.

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              Pollutant
      Removability/Treatability
             for Benzene

                    Actual Wastewater
                   Removal    Average
                   range, %   achievable
Treatment Process              cone., ug/l

Sedimentation     23->63     85

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               POLLUTANT REMOVABILITY/TREATABILITY WASTEWATER TREATMENT ALTERNATIVE FOR BENZENE3
0>
ft
(D
tsi
CO
Treatment process
Gravity oil separation
Gas flotation with chemical addition (calcium
chloride, polymer)
Gas flotation with chemical addition (polymer)
Filtration
Sedimentation
Sedimentation with chemical addition (alum, lime)
Sedimentation with chemical addition (lime, polymer)
Sedimentation with chemical addition (polymer)
Sedimentation with chemical addition (alum, polymer)
Anaerobic lagoons
Aerated lagoons
Solvent extraction
Activated sludge
Powdered activated carbon adsorption
Granular activated carbon adsorption
Reverse osmosis
Synthetic wastewater Actual
Removal Average Removal
range, C achievable range,
% cone . , pg/L %
NA
d
od
33C
28->99
23->63
50C
od'e
od'e
49->97
50*
56->95
90-97
•v-100 <50 49->99
80 4,000 95d
48->80
43-80
wastewater
Average
achievable
cone . , 'jjg/L
>75
,3

12C
45
85
46C
_d
_d
160
5,000*
<16
11,000
4,100
20,000d
73
1.5
Volume III
references.
Section numbers
III. 4.1

III. 4. 5
III. 4. 5
III. 4. 6
III. 4. 2
III. 4. 3
III. 4. 3
III. 4. 3
III. 4. 3
III. 5. 3
III. 5. 3
III. 5. 6
III. 5.1
III. 6. 2
III. 6.1
III. 6. 9
       aSee Volume  III for detailed information.

       bNA - Not available, ND - not detected,  BDL - below detection limit.


       CAverage and maximum removals reported.


        Actual data indicate negative removal.

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       VOLUME II - INDUSTRIAL DESCRIPTIONS






Industry summary tables



Descriptions of industrial categories and subcategories



Effluent data and information on wastewater treatment



Plant-specific data



Summary tables on EPA standards and guidelines
                     13

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        Industry Summary
Industry:  Petroleum Refining
Total BAT Subcategories:  1 (5 BPT)
BAT Subcategories Studied:   1 (5 BPT)
Number of Dischargers in Industry
        1973 [2]  1976 [3]  1 976 [4]
Direct:     -        230      182
Indirect:    -         26        48
Zero:       -          -         55
Total:    247      256      285

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             TABLE 14-1.  INDUSTRY SUMMARY  [1-4]
    Industry:  Petroleum Refining
    Total Number of Subcategories:  1  (5 for BPT)
    Number  of  Subcategories Studied:   1  (5 for BPT)

    Number  of  Dischargers  in  Industry:

                          1973  [2]     1976  [3]     1976  [4]

       • Direct:                         230          182
       • Indirect:                       26           48b
       • Zero:                                        55
       • Total:               247         256          285

    Pollutants and Toxics  Found in  Significant Quantities:

       • For direct discharge:     • For  indirect discharge:

        BOD5      Cyanide         Ammonia
        COD       Pyrenes         Sulfides
        TOC       Phthalate        Oil  and grease
        TSS          esters         Phenols
        Oil and                    Chromium
           grease                   Zinc
        Ammonia nitrogen           Cyanide
        Phenolic  compounds         Pyrenes
        Sulfides                   Phthalate  esters
        Chromium
        Zinc

    Number  of  Toxic Pollutants  Found  in:

       • Raw wastewater:   40
       • Treated effluent:  32

    Candidate  Treatment and  Control Technologies:

       • Recycle/reuse
       • Powdered  activated  carbon
       • Metals  removal (precipitation)


    Note:   Blanks  indicate data not available.

    aSix of these  refineries  indicate intent  to  connect to
     POTW  in  the near future.  Some of these  refineries dis-
     charge only a portion of their wastewater to the POTW.

     Six of these  refineries  reported no wastewater
     generation.
Date:  6/23/80              II.14-2

                              15

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 Direct
BOD5
COD
TOC
TSS
Cyanide
Pyrenes
Phthalate
  esters
Oil and grease
Ammonia
  nitrogen
Phenolic compounds
Sulfides
Chromium
Zinc
 Indirect
Ammonia
Sulfides
Oil and grease
Phenols
Chromium
Zinc
Cyanide
Pyrenes
Phthalate esters
                   16

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               TABLE 14-1.  INDUSTRY SUMMARY  [1-4]
     Industry:  Petroleum Refining
     Total Number of Subcategories:  1  (5 for BPT)
     Number of Subcategories Studied:   1  (5 for BPT)

     Number of Dischargers  in  Industry:

                            1973  [2]     1976  [3]     1976  [4]

         • Direct:                         230          182a
         • Indirect:                       26           48^
         • Zero:                                        55
         • Total:               247         256          285

     Pollutants and Toxics  Found  in  Significant Quantities:

         • For direct discharge:    • For  indirect discharge:

          BOD5      Cyanide         Ammonia
          COD       Pyrenes         Sulfides
          TOC       Phthalate        Oil  and grease
          TSS          esters         Phenols
          Oil and                    Chromium
            grease                   Zinc
          Ammonia nitrogen           Cyanide
          "Phenolic  compounds         Pyrenes
          Sulfides                   Phthalate esters
          Chromium
          Zinc

     Number of Toxic Pollutants  Found  in:

         • Raw wastewater:   40
         • Treated effluent:  32

     Candidate Treatment and  Control Technologies:

         • Recycle/reuse
         • Powdered  activated  carbon
         • Metals  removal (precipitation)


     Note:  Blanks  indicate data not available.

       Six of  these  refineries  indicate intent  to  connect to
       POTW  in  the near future.  Some of these  refineries dis-
       charge only a portion of their wastewater  to the POTW.

       Six of  these  refineries  reported no wastewater
       generation.
Date:  6/23/80               II.14-2

                               17

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Raw Wastewater:  40
Treated Effluent:  32
Recycle/reuse
Powdered Activated Carbon
Metals  Removal
(precipitation)
        18

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               TABLE 14-1.  INDUSTRY SUMMARY [1-4]
     Industry:  Petroleum Refining
     Total Number of Subcategories:   1 (5 for BPT)
     Number of Subcategories Studied:  1 (5 for BPT)

     Number of Dischargers in Industry:

                           1973 [2]     1976 [3]    1976 [4]

        • Direct:                        230         182a
        • Indirect:                       26          48,
        • Zero:                                       55
        • Total:              247        256         285

     Pollutants and Toxics Found in Significant Quantities:

        • For direct discharge:    • For indirect discharge:

          BOD5      Cyanide          Ammonia
          COD       Pyrenes          Sulfides
          TOC       Phthalate        Oil and grease
          TSS         esters         Phenols
          Oil and                    Chromium
            grease                   Zinc
          Ammonia nitrogen           Cyanide
          Phenolic compounds         Pyrenes
          Sulfides                   Phthalate esters
          Chromium
          Zinc

     Number of Toxic Pollutants Found in:

        • Raw wastewater:  40
        • Treated effluent:  32

     Candidate Treatment and Control Technologies:

        • Recycle/reuse
        • Powdered activated carbon
        • Metals removal  (precipitation)
     Note:  Blanks indicate data not available.
      Six of these refineries indicate intent to connect to
      POTW in the near future.  Some of these refineries dis-
      charge only a portion of their wastewater to the POTW.
      Six of these refineries reported no wastewater
      generation.
Date:  6/23/80              II.14-2


                               19

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           Number      Concentration, mg/l
Parameter detected   Med.      Max.      Avg.
Ammonia      8      2,400    8,300     3,500
Phenol        7       630    1,700       740
                      20

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 from  air pollution emission scrubbers.   Some additional waste-
 water may  result  from coke wharf drainage,  quench pump overflows,
 and coal pile  runoff.   Table 6-4 shows  the ranges of volumes for
 these sources.
         TABLE  6-4.
  WASTEWATER FLOWS FROM SOURCES IN THE
  BYPRODUCT COKEMAKING SUBCATEGORY [2]
                   Wastewater stream
                            Average,
                             m3/Mg
            Excess ammonia liquor               0.17
            Final cooler wastewater             0.14
            Benzol plant wastes                 0.25
            Barometric condenser                0.16
            Desulfurizer                        0.081
            Air pollution emission scrubbers    1.7
            Steam condensates                   0.040
            Miscellaneous wastes                0.15
 Conventional pollutants often found in the raw wastewater include
 significant concentrations of total suspended solids, ammonia,
 sulfide,  and oil and grease.  Subcategory data are presented in
 Table 6-5.   Toxic pollutants found in the wastewater generally
 consist of metals,  phenols, and aromatics.  Table 6-6 lists
 information on these pollutants.
       TABLE 6-5.
WASTEWATER CHARACTERIZATION OF CONVENTIONAL
POLLUTANT FOR THE BYPRODUCT RECOVERY
COKEMAKING SUBCATEGORY  [2]
Raw wastewater
Parameter
Ammonia
Thiocyanate
Oil and grease
Phenol
Sulfide
TSS
PH
Number
detected
7
7
7
7
7
7
7
Concentration ,
Median
2,400
593
63
630
440
59
6.6
Maximum
8,300
1,250
180
1,700
1,800
97
9.7
mg/La
Average
2,900
530
140
740
630
67
8.3
Number
detected
9
9
8
7
8
8
9
Treated effluent
Concentration ,
Median
220
29
11
5.1
91
41
8.5
Maximum
4,900
1,050
40
220
1,800
540
11.8

mg/La percent
Average removal
900 69
29 95
16 90
26 96
320 49
120 -b
8.9
 'Except pB values, given in pH units.
  Negative removal.
Date:  6/23/80
          II.6.1-19


             21

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                                Treated effluent
            Toxic    Number Concentration, mg/l     %


          pollutant  detected Med.  Max.  Avg.   removal


         Cyanide       5    2.5     22    6.9      87
ro
ro

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     ft
     to
     a\
     to
     u>
     00

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ro
OJ
CTi
     I

     to

     O
                  TABLE  6-6.   WASTEWATER CHARACTERIZATION OF TOXIC  POLLUTANTS

                                 FOR THE  BYPRODUCT RECOVERY COKEMAKING SUBCATEGORY  [2]
Toxic pollutant
Metals and inorganics
Antimony
Arsenic
Cyanide
Selenium
Silver
Zinc
Nitrogen compounds
Acrylonitrile
Phenols
2 , 4-Dimethylphenol
2-Nitrophenol
Pentachlorophenol
Phenol
2,4, 6-Trichlorophenol
p-Chloro-m-cresol
4, 6-Dinitro-o-cresol
Aromatics
Benzene
2 , 4-Dinitrotoluene
2 , 6-Dinitrotoluene
Ethylbenzene
Toluene
Polycyclic aromatics
Acenaphthylene
Benzo ( a ) anthracene
Benzo(a)pyrene
Chrysene
Fluoranthene
Fluorene
Naphthalene
Pyrene
Halogenated aliphatics
Chloroform
1 , 1-Dichloroethylene
Pesticides and metabolites
Isophorone

Number
detected

3
3
7
4
6
5

5

3
2
1
7
1
2
2

7
1
1
5
5

7
3
4
5
7
7
7
6

5
2

2
Raw
wastewater
Treated effluent
Concentration, p
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     Plant Specific Data (Plant 009)

          Concentration, mg/l
 Toxic      Raw     Treated   Percent
pollutant wastewater  effluent   removal

Benzene     43       0.010     99

Toluene      11.5     0.008     99

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               TABLE 6-63.
PLANT SPECIFIC TOXIC POLLUTANT DATA
FOR THE BYPRODUCT COKE SUBCATEGORY
(PLANT 009) [1]
        Toxic pollutant
                                         Concentration, mg/L
       Raw wastewater   Treated effluent
               Percent
               removal
Metals and Inorganics
  Cyanide

Nitrogen compounds
  Acrylonitrile
           31
            1.45
22
 0.180
32
94
Phenols
2 ,4-Dimethylphenol
2-Nitrophenol
Pentachlorophenol
Phenol
p_-Chloro-m-cresol
2,4,6-Trichlorophenol
4 , 6-Dinitro-o-cresol
Aromatics
Benzene
Ethylbenzene
Toluene
2 ,4-Dinitrotoluene
2 , 6-Dinitrotoluene
Polycyclic aromatic hydrocarbons
Acenaphthylene
Benz ( a ) anthracene
Benzo(a)pyrene
Chrysene
Fluoranthene
Fluorene
Naphthalene
Phenanthrene
Pyrene
Halogenated aliphatics
Chloroform

ND
ND

40
ND
ND
ND

85.5
0.005
11.5
ND
ND

1.20
1.20
ND
1.50
0.950
0.175
27.5

1.05

ND

ND
<0.005
0.049
0.048
0.002
ND
<0.005

0.010
0.008
0.008
ND
ND

0.005
0.005
0.003
0.01
0.009
0.005
0.005
0.005
0.008

0.046




99


a

99
-a
99
-
-

93
93
-a
99
89
97
>99
a
99

_a

Note:  Blanks indicate data not available.
       Dashes indicate negligible removal.

 Treated effluent concentration exceeds raw wastewater concentration.
 Asbestos sampled but not analyzed.

-------
               Treatment      Subcategory number
               technology    1	17-1 9	24


               Gas floatation x         x  x

               Activated     x
                 sludge
IV)
ON

-------
o TABLE 6-120.
ti-
ro
TREATMENT TECHNOLOGIES CURRENTLY IN
IRON AND STEEL INDUSTRY [1-9]
USE IN THE
Subcategory number
a\ Treatment technology
r"? Settling, scale pit, or lagoon
\ Clarifier
oo Thickener
0 Centrifuge
Settling cone
Chemical addition - lime
- polymer
- ferric sulfate
- alum
- sulfur dioxide
- chromium reduction
-alkaline chlorination
pH adjustment
H Filtration
• Filtration - pressure
„„ ** - sand
ro • , ..
-j j_i - mixed media
1 - flat bed
^ - deep bed
^ - carbon3
- vacuum
Ultrafiltration
Activated carbon column
Oil skimming
API separators
Lamella separator
Aeration
sludge
Biological oxidation
Free still
Fixed still
Deep well injection
Cooling tower
Partial recycle
Complete recycle
Contractor hauled
123456789 10
XXX X
X XX X X X X
XXXXXXXXX


XXX X
X X X X X X




X XX
X ^ _ X _ 	 	

X X

X

X
X X
XX XX

X
X

X
X
x
X
X
X
X
X
X X XXX X
XX X XX

11 12
X X
X X
X X


X X
X X
X




13
X
X
X

X
X
X
X
X



14
X
X
X

X
X
X
X
X



15 16
X X
X X
X X


X X
X
X X
X



17
X
X
X


X
X

X



18 19 20 21 22
X X X X X
X
X
X
X
X X X X X
X X X X X

X

X X

X X X X X X
-.->,;. ;».-y-'?'-"V:.-.'"' i^V^V^V/A-^'^^H'^'^.^-'O*'-'-^
:?*'5>'i"^v^fcv--'HQ>Pfc'^^
'X
X
X X

X
X




X

X

', " °t i




X
X X
X
X
X
X



X

X


X

X

*• • ,,_




X
X
X
X
X
X
X




X


X








X
X
X
X
X X
X X
X
X



X X


X X
X


-




X X
X X
X
X
X






X


X


X
'*> ,




X
X

X
X


X



X XXX
X
X
X X X X


X X X X X
-, ,<. >,''>,•>•>,>•* ^ *•:•*'«



X
X X X X X

XX X
23 24
X
X
X
X
X
X
X X


X
X
X
X X

X
X
X



X X
X
X
X X








X


In development stage.

-------
                VOLUME III - TREATMENT TECHNOLOGIES
Format
     Sec. 3  Wastewater conditioning (Preliminary treatment)




     Sec. k  Primary treatment




     Sec. 5  Secondary treatment




     Sec. 6  Tertiary treatment




     Sec. 7  Sludge treatment




     Sec. 8  Disposal










Content




     Design criteria




     Typical performance




     Applications and limitations




     Reliability




     Chemical requirements



     Environmental impacts
                                    28

-------
    I NEUTRALIZATION I
                           pAVITY OIL SEPARATION!
                               [SEDIMENTATION!
                     I ACTIVATED SLUDGE I

                     I TRICKLING FILTER I

                        I LAGOONS I

AERATED
LAGOONS




AEROBIC
LAGOONS






ROTATING BIOLOGICAL
CONTACTORS

FACULTATIVE
LAGOONS



ANAEROBIC
LAGOONS




EFFLUENT POLISHING
LAGOONS

                              lULTRAFILTRATlONl
                                                                    ISTEAM STRIPPING!

                                                                   [SOLVENT EXTRACTIONI
                           IA1R STRIPPING!

                           NITRIFICATION)

                           iDENlTRlFlCATiONl
                            I10N EXCHANGE!
                        1POLYMERIC ADSORPTIONl

                           [REVERSE OSMOSISI

                           IELECTROD1ALYS1SI

IDISTIL

IDISINF

IDECHLOR

ATIONI

CTIONI

NATION!
                                                 [GRAVITY THICKENING!
                                                IFLOTATION THICKENING!
I CENTRIFUGAL THICKENING

  I AEROBIC DlCESTiON"!

  lANEROBIC PlCCSTlONl

I CHEMICAL CONDITIONING"
 THERMAL CONDITIONING
    (H£AT TREATMENT)
                                                        REATI
                                                 IDlSINFECnON IHEATII
  [VACUUM FILTRATION!
           DEWATERINC I
                                                BEIT FILTER OCWATtRINCI

                                               (CtNTRIFUCAI. DEWATERINC I
                            I DEEP WELL INJECTION 1
                                                [BY-PRODUCT RECOVERY  |
     SUBCLASSIFICATIONS FOR PERFORMANCE DATA SUMMARY PURPOSES
     ARE BASED ON THE TYPES OF COAGULANTS OR SETTLING AIDS USED.
                        Figure  1.     Treatment  technology  overview.
Date:    12/10/79
      III.2-4

            29

-------
Treatment Technology:
  Activated Sludge

Data Source:
  Effluent Guidelines

Category:
  Textile Mills

Data Source Status:
  Full Scale
         30

-------

point s't
Subcategory:  Stock and yarn finishing
Plant:
References:  A6,  p. VII-61
Use in system:  Secondary
Pretreatment of influent:  Screening, neutralization

DESIGN OR OPERATING PARAMETERS

Process modification:  One 19,900 m3  (5.25 Mgal)  basin, surface aeration
                        (8 aerators)
Wastewater  flow:  3,500 m3/d  (925,000 gpd)
Hydraulic aeration detention time:  120 hr
Volumetric loading:
MLSS:
Volatile fraction of MLSS:
F/M:
Mean  cell residence time:
 Sludge  recycle ratio:
 Mixed liquor dissolved oxygen:
 Oxygen  consumption:
 Aerator power requirement:  22.5 W/m3
                             (114 hp/Mgal) Percent solids in sludge:
Secondary clarifier
  configuration:
Depth:
Hydraulic loading
  (overflow rate):
Solids loading:
Weir loading:
Sludge underflow:
                                 REMOVAL DATA
Sampling period: 72-hr
composite

Concentration, yg/L
Pollutant/parameter
Toxic pollutants:
Arsenic
Influent

19
Bis(chloromethyl) ether 59
Di-n-butyl phthalate
Dimethyl phthalate
2 , 4-Dichlorophenol
2 , 4-Dimethylphenol
2,4, 6-Tr ichlorophenol
p-Chloro-m-cresol
1 , 2-Dichlorobenzene
1, 2-Dichloropropane
Tetrachloroethylene
Trichloroethylene
25
18
20
190
16
29
56
56
310
10
Effluent

<10
a
ND
ND
ND
ND
ND
<10
ND
ND
ND
<10
ND

Percent
removal

>47
MOO
VLOO
-v.100
VLOO
'vlOO
>37
VLOO
M.OO
VLOO
>96
MOO
             Not detected.
 Note:  Blanks indicate that information was not specified.
 Date:   8/13/79                  III.5.1-49
                                       31

-------
                     Concentration, ug/l   Percent
Pollutant/parameter    Influent   Effluent   removal
2,4-Dichlorophenol       20        ND
                         32

-------
 TREATMENT  TECHNOLOGY:  Activated Sludge

 Data  source:  Effluent Guidelines
 Point source  category:  Textile mills
 Subcategory:  Stock and yarn finishing
 Plant:
 References:   A6, p. VII-61
                       Data source status:
                         Engineering estimate
                         Bench scale
                         Pilot scale
                         Full scale
 Use  in  system:  Secondary
 Pretreatment of influent:
Screening, neutralization
 DESIGN OR OPERATING PARAMETERS

 Process modification:  One 19,900 m3  (5.25 Mgal) basin, surface aeration
                       (8 aerators)
 Wastewater flow:  3,500 m3/d  (925,000 gpd)
 Hydraulic aeration detention  time:  120 hr
Volumetric loading:
MLSS:
Volatile fraction of MLSS:
F/M:
Mean cell residence time:
Sludge recycle ratio:
Mixed liquor dissolved oxygen:
               Secondary clarifier
                 configuration:
               Depth:
               Hydraulic loading
                 (overflow rate):
               Solids  loading:
               Weir loading:
               Sludge  underflow:
Oxygen consumption:
Aerator power requirement:  22.5 W/m3
                            (114 hp/Mgal) Percent solids in sludge:
REMOVAL DATA
Sampling period: 72-hr
composite



Concentration, ug/L
Pollutant/parameter
Toxic pollutants:
Arsenic
Influent

19
Bis(chloromethyl) ether 59
Di-n-butyl phthalate
Dimethyl phthalate
2, 4-Dimethylphenol
2,4, 6-Tr ichlorophenol
p-Chloro-m-cresol
1 , 2-Dichlorobenzene
1, 2-Dichloropropane
Tetrachloroethylene
Trichloroethylene
25
18
190
16
29
56
56
310
10
Effluent

<10
ND3
ND
ND
ND
<10
ND
ND
ND
<10
ND
Percent
removal

>47
MOO
VLOO
MOO
^100
>37
VLOO
^100
^100
>96
MOO

            Not detected.
Date:   8/13/79
       III.5.1-49

         33

-------
Control Technology Summary for Activated Sludge
                   Data        Effluent cone.
     Pollutant      points   Min.  Max.  Mean
2,4-Dichlorophenol    2     <4    <10.    <7
                                Removal eff., %
                           Min.  Max.   Mean
                           >0    >50   >25

-------
       o
       01
       rt
       (D
       to
       OJ
       00
       o
CONTROL TECHNOLOGY SUMMARY  FOR ACTIVATED SLUDGE
UJ


Pollutant
Conventional pollutants, mg/L:
BOD5
COD
TOC
TSS
Oil and grease
Total phenol
TKN
Total phosphorus
Toxic pollutants, pg/L:
Antimony
Arsenic
Cadmium
Chromium
Copper
Cyanide
Lead
Mercury
Nickel
Selenium
Silver
Thallium
Zinc
Bis(chloromethyl) ether
Bis(2-chloroethyl) ether
4-Bromophenyl phenyl ether
Bis(2-ethylhexyl) phthalate
Butyl benzyl phthalate
Di-n-butyl phthalate
Diethyl phthalate
Dimethyl phthalate
Di-n-octyl phthalate
Benzidine
1 , 2-Diphenylhydrazine
N-nitrosodiphenylamine
N-nitroso-di-n-propylamine
2-Chlorophenol
2;4:''Bi':," ,<-lK',r-'
Q --•7
Qa


Oa
Maximum

>99
96
95
96
>98
>99
63
97

90
96
>99
99
>99
>90
99
>97
92

>96

92





>99
>99
>99



>99

92
•' '"""^SO-'I c'~:
>95


>99
Median

91
67
69
25
92
64
44
27

15
39
0
48
56
oa
50
>29
7

20

27





>84
>99
>99







"rVoa':"


>98
Mean

86
63
63
34
74
60
43
32

30
>43

45
52
>18
>49

>29
oa
31
38
35
>83
>47
95

0
>60
>56
>60
0
0
oa
>84
oa
46
"•- -~>3&:-
>32
>99
>99
>70
                                                                                      (continued)

-------
           VOLUME IV - COST ESTIMATING




 Total capital investment




 Annual operating cost




 General overview




       Engineering and design criteria




       Common modifications




       Typical equipment




       Process flow diagram




       Assumptions










CLASSIFICATION OF POLLUTION CONTROL TECHNOLOGIES




                 IN VOLUME IV




 ¥astewater conditioning




 Primary treatment




 Secondary treatment




 Tertiary treatment




 Sludge treatment




 Sludge disposal
                      37

-------
     TOTAL CAPITAL INVESTMENT






Fixed capital investment




      Direct cost components




      Indirect cost components




Working capital
    TOTAL ANNUAL OPERATING COST






Total direct operating cost




Total indirect operating cost
                 39

-------
    Design criterion     Value
    Detention time      3-1 Od
    Depth              6-20 ft
    pH                 6.5-8.0
Operating/wastewater
    characteristic	Assumed value
Service life            30 yr
Detention time        7d(15-ft
                       water depth)
                 ifO

-------
When high-intensity  aeration produces completely mixed  (all
aerobic) conditions,  a  final settling tank is required.  Solids
are recycled to maintain  about 800 mg/L MLVSS in this mode.

Equipment normally associated with aerated lagoons includes
lining systems, aerators,  and hydraulic controls.  A flow
diagram for aerated  lagooning is shown below.
             INFLUENT
                        AERATED
                       LAGOON(S)
              TO POLISHING POND
     Typical design  criteria.   Typical design criteria  for  aer-
ated lagoons consist of  operation and energy requirements.   The
operation requires one or more aerated cells, followed  by a set-
tling  (unaerated) cell.   Additional operational criteria are
provided below.
    Water temperature range
    Optimum water temperature
    Oxygen requirement
    Organic loading
    Operation
  0-40°C
  20°C
  0.7-1.4 times the amount of BODs removed
  10-300 Ib BODs/acre/d
  One or more cells
     Costs.  Purchased equipment and installation cost  for  esti-
mation of the  total  capital investment includes excavation,  em-
bankment, seeding  of lagoons/slopes (three cells), service  road,
fencing rirap  embankment protection, hydraulic control  works,
aeration equipment,  and electrical equipment.  The following
operating and  wastewater characteristics were assumed for cost
estimation:
^^ts&^a§i^
 Horsepower required
 BOD5
 COD
 TSS
 Total-P
 NH3-N
36 hp/Mgal capacity
210 mg/L influent; 25
400 mg/L influent; 50
230 mg/L influent; 40
 11 mg/L influent;   8
 20 mg/L influent; 18
                                                 mg/L effluent
                                                 mg/L effluent
                                                 mg/L effluent
                                                 mg/L effluent
                                                 mg/L effluent

-------
      100
    (0
    ^
    CO
    =5  1°
    Q
    = 1.0
       0.1
          0.1
                        Total Capital
                        Investment
                                    Xrurchased
                                        and  Installed
                                        Equipment
 1.0         10
Capacity, Mgal
100
NOTE:  The format of this graph has been revised in the final draft
of the Manual.  Specifically,  you will notice the horizontal axis
now reflects loading in pounds per day of BOD^ instead of capacity
in millions of gallons.

-------
                    TOTAL CAPITAL INVESTMENT
         100 F
  CO
  on
  o
  o
  u_
  o
  00
        0.01  =
                      LOADING, IWdayBOD,
Date:  6/23/80
IV.4.3-3

-------
-p-
O P  O !2!
p M  H> O
V P-   1-3
fD tB  ct- M
O    ty ••
H- cs  CD

42

H- 4
ti CD
  Hj
e P
H- CD
M O
H d-
H- TO  CO c+
O    W
0 Hj (D O
03 H O H,
  O  H-
O Sj  Hj c*-
Ht,   H- tT
  H- O H-
TO t!  P ID
fB    (_i
H S  MTO
H H-Vl i-j
O I-"-  P
P H_ . •£.
           P-
             CD
           to O
           H)
                                         o
                                         o
Millions of Dollars/Year
       o
       b              9

-------
                 ANNUAL OPERATING COST
         100 F
                                                 0.001
        0.001
                        0.0001
Date:  6/23/80
FLOW, Mgal/d
 IV.4.3-4

-------
        VOLUME V - EXECUTIVE SUMMARY






Guidance for use



Indicators



References



Median observed effluent concentrations



Median removal efficiencies



Pollutant treatability index

-------
                               Number of data sets
                                With both influent
                                 and effluent data	
                             Full      Pilot     Bench
Industry/control technology  scale     scale      scale

Auto and Other Laundries

  Granular Activated           1          2
    Carbon Adsorption

Coal Mining

  Sedimentation               3

-------
   TABLE A-l.  NUMBER OF SOURCE/TREATMENT TECHNOLOGY DATA SETS
                                      Number of data sets
                                 Data sets with
                                both influent and
                                  effluent data
Industry/control technology
                               Full
                               scale
Pilot
scale
Bench
scale
 Effluent
   data
(any scale)
Adhesives and Sealants
  Ozonation
  Reverse osmosis
  Sedimentation                  1
  Ultrafiltration

Auto and Other Laundries

  Filtration                     3
  Gas flotation with
    chemical addition           10
  Granular activated
    carbon adsorption            1
  Sedimentation with
    chemical addition            1
  Ultrafiltration

Coal Gas Washing Process

  Activated sludge

Coal Mining

  Rotating biological
    contactors
  Sedimentation                  7

Coal Tar Distillation Plant

  Activated sludge

Coke Gasification Plant
  Activated sludge
Combined Waste - Petrochemical
  and Paper Mills
  Activated sludge               1

Electroplating

  Filtration                     2
  Ion exchange                   2
  Ozonation                      1
  Reverse osmosis
  Sedimentation                  1
                                        1

                                        6
                                       "2


                                        8
Date:  6/23/80
                               V.A-2

-------
                   Appendix B

                    Treatment technique
          Activated        Lagoons        Solvent
Pollutant    sludge    Aerated  Anaerobic  extraction

Benzene     <0.02     <7.5     5,000    8,100

-------
o
fu
rt
(D
                  TABLE  B-3.    MEDIAN  OBSERVED  EFFLUENT  CONCENTRATIONS
a\
OJ
CO
o
                     Pollutant*
 Acti-               . 	
vated   Trickling
sludge    filters    Aerated
                                                                                 Treatment technique
                                                                    Lagoons istabilization PondsJ^
                                                                        Anaerobic
                                                                         Facul-
                                                                         tative
                   Tertiary
                   polishing
 Rotating
biological
contactors
                                 Steam
                                stripping
 Solvent
extraction
Conventional pollutants, mg/L:
  BOD5                               49       27         90
  COD                              425      623         591
  TSS                               92       45         155
  TKN                              174                  64
  TOC                              280                  126

Toxic pollutants,  mg/L:
  Cyanide, total                     26       16         101
  Phenols, total                  0.028     <1.0      C.0105
  488
2,300
  152
1,410
   76
   68
                                                                                               202
                                                                                                25
                                                                                              Q.04
                                                                18
                                                               750
                                                                62
                                                                15
                                                                                                                        173
                                                                                                                        110
                                                                                                                                 1,140
                                                                                                                                  43.5
          Toxic pollutants, ug/L:
            Scenaphthene                     <1.02                    t
            Acroleic
            Acrylonitrile

            Benzene                         «0.82                  7.5    5,000                                                  8.100
            Benzidins                           4                  7.0
            Carbon tetrachloride              <5.05

            Chlorobenzene                    <0.02
            1,2,4-Trichlorobenzene             6.3
            Hexachlorobenzene                0.2S                  <10C

            1,2-Dichloroethane                                                                                        9,OOC      31,500
            1,1,1-Trichloroethan*             <2.C                   22                                               42,000
            Hexachloroethane

            1,1-Dichloroethane               '6.5                                                                          .
            1,1,2-Trichloroethane              <10                                                                        10      16,000
            1,1,2,2-Tetrachloroethane          <10                                                                    33,000       2,000

            Chloroethane
            Bis(chloromethyl) ether            <10
            Bi*(2-chloroethyl) ether           <10

            2-Chloroethyl vinyl ether
            2-Chloronaphthalene               1.0                 
-------
                     Appendix C (Percent)


                          Treatment technique

                    •  ^ _•      Lagoons          ^ ,
                 Activated 	I	   Solvent

      Pollutant    sludge   Aerated   Anaerobic   extraction


      Benzene     >81       >65        50         96
ro

-------
     o
     0)
     ft
     NJ
     00
     o
                             TABLE C-3.
MEDIAN REMOVAL EFFICIENCIES

    (Percent)
(JO
      I
     **
     o


Pollutant"
Conventional pollutants :
BOD5
COD
TSS
TKN
TOC
Toxic pollutants:
Cyanide, total
Phenols, total
Acenaphthene
Acrolein
Acrylonitrile
Sitwzene --':;>.•,'" .'• .•,,'. . . "•-•'-,
Benzidine
Carbon tetrachloride
Chlorobenz'ne
1,2, 4-Trichlorobenzene
Hexachlorobenzene
1 , 2-Dichloroe thane
1,1, 1-Trichloroe thane
Hexachloroe thane
1,1-Dichloroe thane
1,1, 2-Trichloroe thane
1,1,2, 2-Tetrachloroe thane
Chloroe thane
Bis(chloromethyl) ether
Bis(2-chloroethyl) ether
2-Chloroethyl vinyl ether
2-Chloronaphthalene
2 , 4 , 6-Trichlorophenol
g-Chloro-m-cresol
Chloroform
2-Chlorophenol
1 , 2-Dichlorobenzene
1 , 3-Dichlorobenzene
1 ,4-Dichlorobenzene
3,3' -Dichlorobenzidine

Acti-
vated
sludge
91
67
25
44
69
ob
64
>99

. -**VY
0

>99
49
49
>85

>9
Ob

>83
>47
50
0
>2
46
>96

95

Treatment technique
Lagoons (Stabilization Ponds) Rotating
Trickling Facul- Tertiary biological
filters Aerated Anaerobic tative polishing contactors
92 78 65 87 72
23 63 35 62 26 41.
59 24 80 50 0
77 50 33
46
78 46 >72
>97 >65 23
0

..v Y,,- ,••.;-:-•* .-. •' w-.--^:--^:,:-&FJ:.:^,. :'/-.;.
41


>0
>0
96




0
>0
h >47
Ob >99
Ob >36
>96

>81



Steam Solvent
stripping extraction
67 50
72
35
69


..-. ..--.•',-:-,•»




>99 89
9


>99. 92
Ob 98



>99




                                                                           (continued)

-------
                    Appendix D
                       Phenol
                               Lowest      Highest
                               effluent      removal
Pollution treatment    Data   concentration  efficiency
    technology      points     ug/l

 Activated sludge      30       <0.07        >99

-------
TABLE D-l  (continued)
D 	 	
rt
fO Number
" of data
Pollutant Pollution treatment technology points
CTi


"\ Phenol (continued) Gas Flotation (Dissolved Air
to
to
00
0




<
L,
I
oo
Ul












Flotation)

Gas Flotation with Chemical Addition
(Alum, Polymer)
Gas Flotation with Chemical Addition
(Calcium chloride, Polymer)
Gas Flotation with Chemical Addition
(Polymer)

Gas Flotation with Chemical Addition
(Ferrous sulfate. Lime, Polymer)

Granular Media Filtration
Activated Sludge







Trickling Filters
Lagoon (Aerated)
Solvent Extraction
Granular Activated Carbon Adsorption
2


1

3

2


1

10
30







1
3
15
5
Lowest
observed
effluent
concentration,
pg/L

L.
5b


28b

42

9a,b
26

190b

<0.07
<0.07







37
93
>99







oc
>99
>99
>96
Volume III
pacje(s)


4.4-6


4.5-5

4.5-7

4.5-15


4.5-12

4.6-10
5.1-24, 5.1-47,
5.1-48, 5.1-50,
5.1-52, 5.1-56,
5.1-57, 5.1-58,
5.1-59, 5.1-61,
5.1-66, 5.1-69,
5.1-70, 5.1-74

5.2-13
5.3-12
5.6-19
6.1-39
                                         (continued)

-------
                                 TAPE 3

     This tape contains the first of two sample permitting problems
designed to familiarize videotape viewers with the content and the
use of the Treatability Manual.  Dr. Gregory Kew of the U.S. EPA
and Mr. Thomas Hughes of the Monsanto Research Corporation will be
presenting both exercises.  The permitting exercise presented in
this tape has been taken from the gum and wood chemicals industry.

     Mr. Hughes will first give you a quick overview of a hypothetical
NPDES permit application.  This will be followed by Dr. Kew's descrip-
tion of one method by which permit writers may use the Treatability
Manual to arrive at best engineering judgment (BEJ) permit limits.
A list of steps used in Dr. Kew's method is given in Section V. 3-2
of the Manual.  Mr. Hughes will then present an alternative solution
to the problem and show a different approach for using the Manual
to help determine appropriate permit limits.

     It is suggested that videotape viewers examine "KFDES Permit
Application #1". included in this workbook package, before viewing
this tape.  You may also wish to scan Dr. Kew's approach which is
included immediately following the permit application.

     Illustrations used in the presentations and/or more detailed
information extracted from Trea'taMlJ-'by' Manual data follow the outline
of Dr. Kew's approach.  As mentioned in the Tape 2 summary, in a few
instances these data may not represent those found in the published
version of the Manual but are presented solely to demonstrate alternative
ways in which the Manual might be used towards drafting BAT permit
limits.
                                    57

-------
                                       EPA I D ti\jw&Kn(copy /
Please print or type tn the unshaded areas only
  FORM

  2C
  WOES
                                                                                   Form Apprond OMB Ha. 158-R0173
vvEPA
                                           U.S. KHVmON.gffNTAU PROTECTION AGCNCV
                                      A«*UCATiGN FOR P$«&
-------
PLANT WATER FLOW AND THE EXISTING TREATMENT  SYSTEM
     Distillation
     and Receiving
       0.026
Batch Extraction
  & Separation
      0.080
                   0.106
                             RAW WASTEWATER
                  EQUALIZATION BASIN
                   0.106
                  ASH SETTLING BASIN
                   0.106
                 AERATED LAGOON WITH
                    SETTLING BASIN
                   0.106  1>  TREATED  EFFLUENT
             PLANT MEETING BPT  REGULATIONS


  * All units in millions of  gallons  per  day  (MGD)
                         59

-------
CONTINUED FROM THE FRONT
 C. Except for storm runoff, leaks, or splllt, are any of th« ditthargtc described in I tarn* II-A or B intermittent or Mason*.?
          £] YCS (complete tht following table}                                       9£NO (go to Section III)
I. OUTFALL
 NUMBER
   (tut)
                          2. OPERATION/!,'
                       CONTRIBUTING FLOW
                                                            >. FREQUENCY
                                                                     fa. MONTH*:
                                                           (specify
                                                                                (specify with unit*)
                                                                                                      c DUR-
                                                                                                      ATION
                                                                                                      fin dayt)
 III. MAXIMUM PRODUCTION^
  A. Does an effluent guideline limitation promulgated by EPA under Section 304 of the Dean Water Act apply to your facility?
          jj£ YES (complete Item III-B)                                               DHO (to to Section I
  B. Are th* limitations m the applicable effluent guideline expressed in terms of production (or ottw mmturv of apentionn
          53 YK (complete Item IIl-C)                                              QHO (go to Section /V)
  C. If you answered "Yes" to Item IH-B, list the quantity which represents an actual measurement of your maximum level of production, expressed in the terms
     and units used m the applicable effluent guideline, and indicate the affected outfalls.
   •  «u ANTI-TV fm.it c
                                                               C. OPERATION, PKoeUCT, MATKMIAL. I
                                                                            f«pee.fy>
                                                                                             ft AFFECTED
                                                                                              OUTFAL.I-S
                                                                                          (lift outfall numbers)
   125,000
Lbs/day
                                               Wood  rosin,

                                               Pine  oil,   and

                                               turpentine  via  solvent  extraction
001

002
 A. Are you now required by any Federal, State or local authority to meet any implementation schedule for the construction, upgrading or operation of waste-
    water treatment equipment or practices or any other environmental programs which may effect the discharges described in this application' This includes,
    but is not limited to, permit conditions, administrative or enforcement orders, enforcement compliance schedule letters, stipulations, coviit orders, and grant
    or loan conditions                    Ov« (complete the toUowint table)            ^noltotaltemlVB)
        AGREEMENT. CTC.
                                         b. BOVIICK or OMCMA
                                                                           >. BRIEF DESCRIPTION OF PROJECT
                                                                                                                         Fl-iANCE
                                                                                                                                   >TE
 B. OPTIONAL Vou may attach additional sheets describing, any additional water pollution control programs (or otner environment*/ pro/acts wnicn mty affect
    your discharges! you now have underway or which you  plan. Indicate whether each program is now underway or planned, and indicate your actual or
    planned schedules for construction.   QMAMK -x- IF DESCRIPTION OF ADDITIONAL CONTROL. PROCRAMS is ATTACHED               	
EPA Form 3510-2C (6-90)
                                                              PACE 2 OF 4
                                                                                                                    CONTINUE ON PAGE 3
                                                                   60

-------
CONTINUED FROM PAGE 2
 V. INTAKE AND EFFLUENT CHARACTERISTICS
                                                                                                      Form Approved OMB No 1S8- RO173
 A, B, & C:
See instructions before proceeding - Complete one set of tables for each outfall — Annotate the outfall number in the space provided.
NOTE  Tebles V-A. V-B, and V-C are included on separate sheets numbered V-1 through V-8.
   D  Use the spece below to list any of the pollutants listed in Table 2c-3 of the instructions, which you know or have reason to believe » discharged or may be
    '  discharged from any outfall. For every pollutant you list, briefly describe the reasons you believe it to be present and report any analytical data in your
      possession.
        I. POU1.UTANT
                                               t. SOURCE
                                                                                 t. POLLUTANT
                                                                                                                       Z. SOURCE
           NA
                                                NA
                                                                                      NA
                                                                                                                         NA
 VI. POTENTIAL DISCHARGES NOT COVERED BY ANALYSIS
   A  Is any pollutant listed in Item V-C a substance or a component of a substance which you do or expect that you will over the next 5 years use or manufacture
      as an intermediate or final product or byproduct?
                                        t °" *uch Pollutants below.)
                                                                                              55"° («o to Item VI-B)
   t. Are your operations such that your raw materials, processes, or products can reasonably be expected to vary so that your discharges of pollutant) may during
      the next 6 yeers exceed two times the maximum values reported in Item V?
                              Q YES Icomplftt Item Vl-C b flow I
                                                                                                ] "O do to Section VII)
   C. If you answered "Yes" to Item VI-B, explain below end describe in detail the sources and expected levels of such pollutants which you anticipate will be
      discharged from each outfall over the next 5 years, to the best of your ability at this time  Continue on additional sheets if you need more space
 EPA Form 3510-2C .6-80,  ^  =  ^ avai]able
                                                                   PAGE 3 OF 4
                                                                                                                          CONTINUE ON REVERSE

-------
CONTINUED FROM THE FRONT
VII.  BIOLOGICAL TOXICITY TESTING DATA"
   Do you have any knowledge or reason to believe that any biological tett for acute or chronic toxicity has been made on any of your discharges or on a
   receiving water in relation to your discharge within the last 3 yeen?
                             (identify the tett(s) and detcribe th«tr purpo
                                                                                                    NO (go to Section VIZI)
 ^|(| CONTRACT ANALYSIS INFORMATION]
   Were any of the analyses reported in Item V performed by a contract laboratory or consulting firm?


                      Q YES (list the name, address, and telephone number of, and pollutant*
                              analyzed by, each such laboratory or firm below)
                                    |X] NO (go to Section IX)
                                                                                                                   D. PoLLUtANTi ANALYZED
                                                                                                                      	(U»t)	
». ADDRESS
                                                                                               (area code A no.)
/ certify under penalty of law that 1 have personally examined and am familiar with the information submitted in this application and all
attachments and thatf based on my inquiry of those individuals immediately responsible for obtaining the information, 1 believe that the in-
formation is true, accurate and complete. 1 am aware that there are significant penalties for submitting false information, including the
possibility of fine and imprisonment.

C SIGNATURE
B. PHONE NO (area code & no )
D DATE SIGNED
  EPA Form 3510-20(6-80)
                                                                  PAGE 4 OF 4
                                                                       62

-------
PLEASE PRINT OR TYPE IN THE UNSHADED AREAS ONLY. You may report some or all of
this information on separata sheets lute thosame format) instead of completing these pages.
SEE INSTRUCTIONS
  V. INTAKE AND EFFLUENT CHARACTERISTICS (continued from page 3 of Form 2-CI
                                                                                                                                    Form Approved OMB No. 1S6-ft0173
  PART A • You must provide the results of at least one analysis for every pollutant m this table. Complete one table for each outfall  See instructions for additional details.
 1. POLLUTANT
 •. Biochemical
 Oxvoen Demand
 (BOD)
                                                      Z EFFLUENT
                    NA
                                              NA
                                                                                                                3. UNITS
                                                                                                              tipeclfy it Hank)
                                                                                                                                        4. INTAKE (optional)
 b. Chemical
 Oxygen Demand
 (COD)
                  340
                                              NA
                                                                      227
                                                                                                         rag/1
11
                                                                                                                                                             NA
 c. Total Organic
 Carbon (TOCI
                    NA
                                               NA
                                                                         NA
                                                                                                 NA
                                                                                                          NA
                                                                                                                                      NA
                                                                                                                                                            _NA.
 d. Total Suspended
 Solids (TSS)
                    70
                                               NA
                                                                         55
                                                                                                          mg/1
                                                                                                                                    NA
                                                                                                                                                            NA
 e. Ammonia (at N)
                    NA
                                               NA
                                                                         NA
                                                                                                 NA
                                                                                                          NA
                                                                                                                                     NA
                                                                                                                                                             NA
                         .125
                                                    NA
                                                                              .106
                                                                                                NA
                                                                                                                        mgd
                                                                                                                                        .106
                                                                                                                                                            NA
 0. Temperature
 (winter)
                            NA
                                                    NA
                                                                                NA
                                                                                                NA
                                                                                                                                            NA
                                                                                                                                                             NA
 b. Temperature
 (fummtr)
                            NA
                                                                                                                  °c
                                                                                                           STANDARP UNITS
 PART B • Mark "X" in column 2-a for each pollutant you know or have reason to believe is present. Mark "X" in column 2-bfor each pollutant you believe to be absent. If you mark *
          column 2-a for any pollutant, you must provide the results of at least one analysis for that pollutant. Complete one table for each outfall. See the instructions for additional
          details and requirements.
I. POLLUT-
ANT AND
 CAS NO.
(If available}
             2. MARK 'X'
                                                            3. EFFLUENT
                                                                                                                                           !. INTAKE (optional)
                         a. MAXIMUM DAILY VALUC
                                                      !&
                                                  """"""•"ION
                                                                  1.1 >.»>.
                                                                            C.LONO
                                                                                              .VALUE
                                                                                &

                                                                                                      4NO OF
                                                                                                       KNAL-
                                                                                                       Y«E0
                                                                                                                                       	•. LQN&TERM
                                                                                                                                        AVEttACE VALUE

                        .NO. OP
                        ANAL'
                         Y«E1
 a  Bromide
 (24859-87-81
  . Chlorine.
 Total Residual
 d. Fecal
 Conform
a. Fluoride
(16884-48-8)
f. Nitrate-
Nitrite (at N)
EPA Form 3610-2C (6-80)
                          NA  = not available
                                                                                                                                              CONTINUE ON REVERSE

-------
CT\

1. POLLUT-
ANT AND
g Nltrogan,
Total Organic
la* N)
h OH and
Graaw
1 Phoaphorul
(at Ft, Total
(7723 140)
j. Radioactivity
(1) Alpha,
Total
(2) Bata,
Total
(3) Radium,
Total
(4) Radium
226, Total
k Sulfatt
(01 SO 4)
(148 OB 79-8)
1. Sulflda
«uSI
m Surfrta
fa. S03>
(14266 46 3)
n. Surfactants
o. Aluminum,
Total
(742990-6)
p. Barium, 	
Total
q. Boron,
Total
(7440-42-8)
r. Cobalt,
Total
(7440-48-4)
t. Iron, Total
(7439-89-6)
t. Magnaalum,
Total
(7439 95 4)
u. Molybdanum,
Total
(7439 98 7)
v. Manoanaw,
Total
(7439 96-6)
w Tin, Total
17440-31-B)
x. Titanium,
Total
(744O-J2-6)
2 MA
NA
X




















UK X'
b ut-
NA

X

X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X

NA
12




















(.1 -...





















3 EFFLUENT
NA
NA










































prrB-^M-
NA
12




















A^p. VALUE!
(,!-...






















YSES
NA
3





















4 U
NA
mg/1




















NITS























5 INTAKE (uplttmal)
NA
10










































b NO or
ANAL-
NA
NA




















                     EPA Form 3610-2C (6-8O)
                                                                                                                                                CONTINUE ON PAGE V - 3
                                             NA =  not available

-------
EPA 1 D NUMBER (copy from IUm 1 of Form 1) OUTFALL NUMBER
NA 001
Form Approved OMB No 158-RO173
PART C - If you are a primary industry and this outfall contains process wastewater, refer to Table 2c-2 in the instructions to determine which of the GC/MS fractions you must test
for Mark "X" in column 2-a for all such GC/MS fractions that apply to your industry and for ALL toxic metals, cyanides, and total phenols. If you are not required to mark
column 2-a (secondary industries, non-process wastewater outfalls, and non— required GC/MS fractions), mark "X" in column 2-b for each pollutant you know or have reason
to believe is present. Mark "X" in column 2-c for each pollutant you believe to be absent. If you mark either columns 2-a or 2-b for any pollutant, you must provide the re-
sults of at least one analysis for that pollutant. Note that there are seven pages to this part; please review each carefully. Complete one table (all seven pages) for each outfall.
See instructions for additional details and requirements.
1. POLLUTANT
AND CAS
NUMBER
fit available)
2 M ARK 'X'
areBT
He-
METALS CYANIDE. ANC
IM. Antimony,
Total (7440-36 0)
2M. Arsenic. Total
(744038-2)
3M Beryllium,
Total, 7440 41 7)
4M. Cadmium,
Total (7440-439)
6M Chromium,
Total (7440-47-3)
CM Coppar, Total
(7550-60-8)
7M. Lead, Total
(7438-97-6)
8M. Mercury, Total
(7439-97-6)
9M. Nickel. Total
(7440-02-0)
1OM. Selenium,
Total (7782-49-2)
11M Silver, Total
(7440-22-4)
12M Thallium,
Total (7440-28-0)
13M Zinc, Total
(7440-66-6)
14M Cyanide,
Total (57-12-5)
15M Phanoli,
Total
DIOXIN
2,3,7,8 Tetra-
chlorodibenzo P
Dioxin (1764 01 6)
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X


EPA Form 3610-2C (6-80
b. »c-
Ifc tfEU
• •NT
c ae-
AB-
»KNT
3. EFFLUENT
a. MAXIMUM DAILY VALUE
10
TOTAL PHENOLS




































NA
0.022
NA
NA
0.130
0.016
<0.010
NA
NA
NA
NA
NA
0.049
NA
140

|l) MA..

















b. MAX.M.U.M J^DAY VALUE
III

NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
i
-------
             CONTINUED FROM THE FRONT
ON
ON
1 POLLUTANT
AND CAS
NUMBER
flfainalabhl
2 MARK X'
Qum
• «NT

*•-
• •NT
3 EFFLUENT

III
GC/MS FRACTION - VOLATILE COMPOUNDS
IV. Acrol«ln
(107-02-8)
2V. Acrylonltrll*
(107-13.11
3V. Banzvn*
(71-43-2)
4V. Bit (Chloro
methyl) Eth«r
(64288 1 1
&V. Bromoform
(76-25-2)
6V. C.rbon
T*tr>chlorl NO OP
ANAL-
V*K

NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
CONTINUE ON PAGE V-6
                              NA= Not Available    ND= Not Detected

-------
a\
CONTINUED FROM PAGE V-4
AND CAS
NUMBER
lit available)
OC/MS FRACTIOf
22V. M«thyl«n.
Chloride (76-09-2)
23V. 1.1.2,2 Tro«-
chloixMthsn*
(79-34-6)
24V. Tnrachloro-
Mhyun* (127-18-4
2SV. Toluww
(108-88-3)
2«V. 1,2-Tram-
DIchloroKhyMn*
(1EO-6O-S)
27V. 1.1.1-Trt-
ohloro«th«n«
(71-66-61
chlonxnhm
(79-00-B)
29V. Trtehloro-
•tfiytan* (79-O1-0)
fluoranwUuM
(76-69-4)
31V. Vinyl
ChlorKta (76-O1-4)

IHf,
UK-
aunt-
i — VC
X
X
X
X
X
X
X
X
X
X
tx.<-
UJTK"
IATH










c •.-
;t*vg
AV











a. MAXIMUM DAILY
I'l
•POUNDS fcontt
430
NA
NA
<10
NA
NA
NA
NA
NA
NA
OCM FRACTION -ACtapOMPQUMCW
1A. 2-ClUoroplMmo
(9S.-67-6I
2A. 2,4-Dtehloro-
plMnol (120-83-2)
3A. 2,4-Dlm«hy|.
ph«ioM 10667-9)
4A 4,6-Dlnrtro-O-
Cmol (634-62-11
6A. 2.4-Olnitro-
ptanol (51-28-S)
6A. 2 -Nltroph.no!
(88-76-6)
7 A. 4-Nluophmol
(100-O27)
8A. P-Chloro-M
C'MOl I69-SO-7)
9A. Pvnuchloro-
ptwnol (87-86-8)
10A. Phwiol
(108-962)
88-O8-2)
X
X
X
X
x
X
X
X
X
X
X






















NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
1.1

EPA I.O. NUMBER (copy from Item 1 of Form It OUTFALL NUMBER
Form Approved OMB Nc 15S-RO173
3. EFFLUENT
VALUE
»**••






















H-Ata.a.io.ac.Mo) NA = Nofc ayail
b. MAXIM.J^^JYVATSJT
III
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA

NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
i.i....






















C.LONG Tjf/tM&Yf*?- VALUE
I'l
CQ»C«I.T««T.O«
343
NA
NA

-------
               CONTINUED FROM THE FRONT
ON
CO
1 POLLUTANT
AND CAS
NUMBER
ill available )
2 MARK 'X'
a.'«^r
1 It UCL
• BNT
C. Bfc-

3 EFFLUENT
a. MAXIMUM OAIL.Y VALUE
[•]
|.|M...
GC/MS FRACTION - BASE/NEUTRAL COMPOUNDS
IB Acenaphthene
(83-32-9)
2B Acenaphtylen*
(206-96-8)
3B Anthracene
(120-12-7)
46 Benzldine
(92-87-6)
58 B«mo la)
Anthracene
(E6-5S-3)
68. Benio M
Pyrene (BO-32-C)
78- 3,4-Benzo-
fluoranthene
(206-892)
BB. Benzo (IM)
Perylena
(191-24-2)
98. Benzo (*)
Ftuor enthene
(207-08-9)
108. Bto (1-CMon-
tttioty) Methene
(111-91-1)
118. Blifl-CMoro-
•rnyij Ether
(111-44-4)
12B. Bit r2-Ckloro>
Uopropyl) Ether
(39638-329)
138. Bit (i-Stliyl-
hexyO Phthalata
(117-81-7)
phenyl Phenyl
Eth« (101-66-3)
16B. Butyl Benzyl
Phth>l»u (86 <8-7
188. 2-Chloro-
naphthat*n«
(91-S8-7)
178. 4-Chloro-
ph«nyl Ph«nyl
Ethw (7OOS-72-3)
18B. Chryww
(218-01-9)
198 Dlbenzo fa.h>
Anthracene
(S3 70-3)
208. 1.2 Dichloro-
boni.n. (95-50-1)
2 IB. 1.3-Olchlora-
bwiune (641-73-1
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X










































NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA





















b MAXIMUM 3O DAY VALUE
(if available)
lil

NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
iii --..






















C LONG TERM AVRG. VALUE
(if available)
dl

NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
1,1 M...






















a NO OF
VSE5

NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
4 UNITS
• CONCEN
TRATION

NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
b MAftS






















5 INTAKE I optional)
8 L.ONO TERM
(O cone.*

NA
NA
NA
Hfl
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
(t) MA»»






















b NO OF
YSES

NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
                                                                                                                            CONTINUE ON PAOE V-7
                                  NA= Not availabe

-------

1. POLLUTANT
AND CAS
NUMBER
(i/ otxulabJ.*)
2
VI ARK
b 1.1
;:;*
X'
cut
urn
NA 001
a MAXIMUM DAILY VALUE
I'l
<>i «...
GC/MS FRACTION BASE/NEUTRAL COMPOUNDS (continued)
22B 1,4-Dichloro-
banzana (106-467
23B 3,3'-Dfchloro-
banzidlne
(91-94-1)
24B. Diethyl
Phthalate
(84-66-2)
25B Dimethyl
Phthalata
(131-11-3)
26B DiN-Butyl
Phthslat«
(84-74-2)
27B 2,4-Oinitro-
toluane (121-14-2)
28B. 2,6-Dmitro-
toluana (6O6-20-2)
298 Di-N-Octvl
Phthalate
(117-84-0)
3OB. 1,2-Dlph«nyl>
hydrazlna (as Azo-
benzene) (122-66-7;
31B Fluoranth«na
(20fr44-0)
32 B Fluorena
(86737)
33B Haxa-
chlorobanzena
(118-71 1)
34B Haxa-
chlorobutadiana
(87-68-3)
36B Haxachloro-
cyclopantadiana
(77 47-4)
36B Haxachloro-
athana (67-72-1)
37 B Indeno
(1,2.3-cd) Pyrana
(19339 5)
38 B l»ophoron«
(78-59-1)
398 Naphthatane
(91-20-3)
40B Nhrobanzena
(98-95-3)
41 B N Nitro-
sodimethy lamina
(62 75 9)
42B N Nitrosodi-
N Propylamma
X
X
X
X
X"
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X










































NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA





















b-MAX'M,!«,8&YVA1-UE
LI

NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
U) M*».






















C.L.ONG T^J^gf VALUE
LI

NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
M M*».
























-------

I. POLLUTANT
A N 15 CAS
NUMBt-R
(it available!
GC/MS FRACTION
43B N Nitro
•odiphany lamina
(86-30-6)
448. Phananthrana
(8B-01-8)
458. Pyrana
(129 OO-OI
468. 1,2,4-Tri-
chlorobanzjana
{120 82-1)
OC/MS FRACTION
1P, Aldrln
(309-O02)
2P, a BHC
(319-84-6)
3P li-BHC
131985 71
4P T BHC
(58-83-9)
BP 6-BHC
(316-86-8)
6P Chlordane
(57-74-8)
7P. 4,4'-ODT
(60-293)
•P 4,4' DDE
(72-669)
»P 4,4'-DDO
(72-54-8)
10P. Oialdrln
(60-57-1)
11? 
-------

1. POLLUTANT
AND CAS
NUMBER
ft/ ai'ultubli-)
','„',."
L) •!_
• •»T
C »fc-
A»-
EPA I.O. NUMBER (copy from Item 1 of Form 1) OUTFALL NUMBER
NA 001

i'l
GC/MS FRACTION - PESTICIDES /continued}
17P Heptachlor
E pox Ids
(1024-57-3)
18P PCB-1242
(63469-21-9)
19P. PCB-12S4
(1109769 1 1
20P PCB-1221
111104-38-2)
21P. PCB-1232
(11141-18-6)
22P PCS 1248
112672-29-8)
23P. PCB-1260
411098-82-5)
24f . PCB-1018
(12874-11-2)
26P. Toniphww
(8001-36-2)
X
X
X
X
X
x
x
x
X


















NA
NA
NA
NA
NA
NA
NA
NA
NA
!,] M...










b MAXIMUM 30 OAY VALUE
ti)

NA
NA
NA
NA
NA
NA
NA
NA
NA
(ji ««•>










c LONG TE^A^fJf. VALUE
{•I

NA
NA
NA
NA
NA
NA
NA
NA
NA
1,1 "...











li NO OF
ANAL
vsts

NA
NA
NA
NA
NA
NA
NA
NA
NA
Forr



NA
NA
NA
NA
NA
NA
NA
NA
NA












n Approved OMB No. 1S8-R0173
a LONC. TE RM
l'l.C^V",o»'"

NA
NA
NA
NA
NA
NA
NA
NA
NA
i,i .».•










b NO OF
ANAL
vses

NA
NA
NA
NA
NA
NA
NA
NA
NA
EPA Focm 3610-2C (6-80)
                   NA=  Not  available

-------
V.3.2  STEPWISE APPROACH FOR USING THIS MANUAL

The steps listed below may be followed in using the Manual and the
information in revised permit applications to write Section ^02(a) (l)
second-round permits.  This sequence is intended only as an example
because many circumstances may arise during the preparation of a given
permit which justify the deletion of certain steps or the addition of
others.

Step 1.  Complete preapplication communications or hold conferences with
         permittee.

Step 2.  Review first-round permit to determine the parameters limited
         and BPT levels.

Step 3-  Review the permittee's compliance with first-round permit to
         detect obvious deficiencies.

Step h.  Conduct a preliminary review of the application for completeness
         and obvious inconsistencies.  Notify the prospective permittee
         immediately if further information or clarification is needed.

Step 5-  Consult Volume II of this Manual and the applicable Development
         Document for a description of the industry, its wastes, and
         treatment technology.

Step 6.  Identify any applicable promulgated effluent guidelines,
         pretreatment standards, or water quality standards as of the
         current date.

Step 7-  Review wastewater pollutants reported in the application to
         determine:

         a.  which toxic pollutants are present and whether there
             are groups of toxic pollutants (chemical classes or
             treatability classes); and

         b.  traditional parameters present.

Step 8.  Consider BMP approaches to toxic pollutant reduction on
         particular processes, if appropriate.

Step 9-  Consider requests for exclusion of specific hazardous
         substances from Section 311 coverage and review Volumes I
         and III for applicable treatment.
                                    73

-------
Step 10.  Refer to this volume (Section V.^ and Appendix E) to determine
          the potential "indicator" pollutant parameters for the toxic
          pollutants found, and the approximate correlation with concen-
          trations.  Where possible, determine the optimum overlap in
          coverage of a number of toxic pollutants by as few indicators
          as possible.

Step 11.  Refer to Volume III to determine the treatment technology
          options capable of reducing indicator parameters to levels
          that reasonably assure adequate toxic pollutant reduction.
          Review of Volume II should provide indications of "significant"
          parameters from the Effluent Guidelines Division (EGD)
          perspective in planning BAT.  If resource or time constraints
          require a choice among controlled parameters, the permit
          writer may choose to focus on coverage of those.

Step 12.  If the production volume has changed or the facility been
          modified, recalculate BPT (including BCT, Water Quality
          Standards (¥QS), and if02(a)(l) considerations).

Step 13-  Summarizing, choose the most suitable treatment processes,
          taking into consideration:

          a.  Attainment of desired toxic pollutant level;
          b.  Ability to monitor the operation of the system using
              indicator substances or other operating parameters;
          c.  Process reliability and operator skill requirements;
          d.  Recovery of products;
          e.  Reuse and recycling of water;
          f.  Overall process simplicity;
          g.  Process options consistent with or in addition to
              those already in place;
          h.  Prospect of meeting future limits based on BAT
              guidelines;
          i.  Cost (in a general way) including:

              (l) a comparison of processes capable of achieving
                  acceptable controls; and
              (2) cost/benefit on levels of reduction below
                  minimum acceptable reduction.

Step 1U.  Refer to Volume III and this volume for levels of "indicator"
          parameters that are attainable by the installation of the
          specific combination of treatment processes chosen, if they
          are properly designed, sized, operated, and maintained.

-------
Step 15-  Calculate the interim and final permit limits.

Step 16.  Determine any special requirements, e.g., pilot-plant
          treatability studies or additional monitoring.

Step 17-  Determine a compliance schedule leading to BAT by 7/1/84,
          where appropriate.

Step 18.  Complete a "fact sheet" summarizing the onsiderations that
          served as a basis for writing the permit, including a
          listing of "indicator" pollutants limited and toxic
          pollutants "covered" by each (as noted in column 3,
          p. 34398 of 44 Federal Register. June 14, 1979) (2).

Step 19-  Complete the draft permit and issue a public notice.
                                    75

-------
                        GUM AND WOOD CHEMICALS

                       GUIDELINES FOR WOOD BASIN,
                  TURPENTINE,  AND PINE OIL SUBCATEGORY
                     PROPOSED  11/29/79 (Mf FR 68710)
                                  BPT

Parameter                 Maximum (kg/kkg)               Average  (kg/kkg)

   BOD5                         2.08                         1.10

   TSS                          1.38                         O.V75

   pH                                          6-9


                                 BCT = BPT  = NSPS
                                  77

-------
                       TENTATIVE BCT LIMITATIONS
Parameter               Maximum (kg/day)               Average (kg/day)

  BOD5                       118*                             63

  TSS                         78                              28

  pH                                        6-9
   The following sample calculation illustrates the method for
   arriving at the BCT limit - in this case, using the proposed
   daily maximum waste load allocation of 2.08 kg/kkg of production
   for
   Daily maximum = (2.08 kg/kkg) (56.8 kkg/day) = 118 kg/day
                                   78

-------
                   ACTUAL LEVELS REPORTED IN APPLICATION
Parameter               Maximum (kg/day)               Average (kg/day)




  BOD5                        —                             10




  TSS                         29                             23




  pH                                         6-9
                                   79

-------
   "HIGH INTEREST" POLLUTANTS

           TREATED    AVERAGE    MAXIMUM
 PARAMETER  INFLUENT    EFFLUENT    EFFLUENT
COD (mg/l)    11        227       340

methylene
chloride
  (pg/l)       910       343       430

Cr(pg/l)      <10       111       130

Zn (pg/l)      <10       37       49
                   80

-------
                            POLLUTANTS REPORTED
Parameter

Flow  (Mgd)
BOD (mg/1)
OttD Cag/l)
TSS (mg/1)
Total phenols
Treated
Influent*
0.106
-
n
-
120
Average
Effluent*
0.106
22
227' "' •' •'•'
55
85
Maximum
Effluent*
0.125
_

-------
        CONFIRMATION OF
'COMMON TREATMENT" HYPOTHESIS
   •  Volume I tables
   •  Volume III tables
   •  Volume V, Appendices B and C
                 82

-------
                                       •• f ISWMEBJf »  HYPOTHESIS
Confirmation may be sought in;
                     |t listing the treatment  alternatives  for
       specific poutants;
      y^^jjiM^. listing the pollutants  removed by a
       specific treatment process; or in
               ?a;-^p^^^f:.'^6Jf;.j(5y which  list median observed
       effluent concentrations and percent  removals,  listed by
       specific pollutant and treatment process.
                                   83

-------
                     -' fHQM •
Candidate technologies for attaining BAT are :
    (oil/water separation, equalization, air floatation,
biological treatment) plus:
       -.Hfttals precipi1»tion,by -

-------
                        EXAMPLES OF           'GqS|SxfCJI| ••.••":
                                            *1
Assumptions:

      o   permit writer decides additional treatment is needed


      o   design flow =0.2 Mgd

                                                itttial'.-.'Cfoeff-ftMag •   Ref.  p.


                                                                    IV.  3-3-10
                              ?70ydcfe::'•,.•••.;;•"•>-"•:.. $l6Q:,000;>!',.>';•'

-------
  DRAFT PERMIT LIMITS





PARAMETER    MAX. (kg)   AVG. (kg)



BODs        118       63



TSS           78       28



Cr           0.13       —



pH                6-9
            86

-------
                        DRAFT PERMIT LIMITS
                                                    Average (k^/day)

                                                           63

                                                           28
                                           6-9
The following calculation illustrates how to arrive at the draft
permit limit for total chromium assuming (l) the maximum effluent
flow for the plant is 125,000 gal./day (or approximately if72,000 I/day)
and (2) the daily maximum for chromium is to be 260 ug/1:
(260 x 10-6 g/1)
                      x  105  I/day)  =   1227 *  10-1  g/day
                                    -          0.13  kg/day
                                87

-------
POLLUTANT      AVG.. mg/l



BOD              22



COD             227



TSS               55



PHENOLS       0.085
          88

-------
                         GUM AND WOOD CHEMICALS
            Pollutant	      Average a       Maximum
Conventional Pollutants
                                                          3^0 mg/1
                                                           70 mg/1
          |Siil|i|f^^


Toxic Pollutants, ug/1
            Chloroform                      17             20
            Ethylbenzene                  <10           < 10
            Methylene Chloride b           3^3            ^30
            Toluene                       <10           <10
            Arsenic                         17             22
            Chromium                       111          0.130
            Copper                          16             16
            Lead                          < 10           < 10
            Zinc                            37             37
a.  ug/1 except as noted.
b.  Suspect methylene chloride is an artifact.
                                   89

-------
 POLLUTANT         AVG., (jg/l
Chloroform           17

Ethylbenzene        <10

Methylene           343
Chloride*

Toluene             <10

^Artifact
             90

-------
            Pollutant
Conventional Pollutants



            BOD



            COD



            TSS



            Phenols,  Total






Toxic Pollutants, ug/1


            MI i  "^fei*>"*r%'« ***-
                          >*. •*:
            Arsenic



            Chromium



            Copper



            Lead.



            Zinc
Average a







  22 mg/1



 22? mg/1



  55 mg/1



  85 ug/1
Maximum a
  3^0 mg/1



   70 mg/1



  1*10 ug/1
                    20
                                                            430
17
111
16
22
0.130
16
  37
   37
a.  ug/1 except  as  noted.



b.-'
                                    91

-------
POLLUTANT        AVG., fig/I




Arsenic            17




Chromium         111




Copper            16




Lead              <10




Zinc               37

-------
          Pollutant
Conventional Pollutants




          BOD




          COD




          TSS




          Phenols, Total





Toxic Pollutants, ug/1




          Chloroform




          Ethylbenzene




          Methylene Chloride




          Toluene
Average








   22 mg/1



  22? mg/1



   55 mg/1



   85 ug/1









   17
Maximum
                                                                a
a.  ug/1 except as noted.



b.  Suspect methylene chloride is an artifact.
  3^0 mg/1



   70 mg/1



      ug/1
   20
                   ^30
                                   93

-------
AERATED LAGOON
EXISTING SYSTEM IS
BETTER THAN MOST

-------
Volume
Pollutant
BOD, mg/1
COD, mg/1
TSS, mg/1
Phenols, Total mg/1
Chloroform, ug/1
Ethylbenzene, ug/1
Methylene Chloride,
ug/1
Toluene, ug/1
Arsenic, ug/1
Chromium, ug/1
Copper, ug/1
Lead, ug/1
Zinc, ug/1
Cone.
at
Plant
22
227
55
0.085
17
<10
343
<10
17
111
16
<10
37

Min.
6
92
3
0.003
10
<10
32
<10
—
9
5
<20
to
General
Max.
869
1,610
1,790
0.018
1,000
<10
1,000
30
—
1,000
110
80
510
Systems
Median
78
600
80
0.0105
10
<10
130
<10
—
16
26
50
80

Mean
128
311
0.0105
340
<10
390
14
—
380
40
50
180
a.  Note units  change on toxic metals.




b.  See pages III. 5.3 - 8.2 and III. 5.3 - 8.3.




c.  Blanks indicate no data.
                                   95

-------
D  AERATED LAGOONS



D  GAS FLOTATION



D  GAS FLOTATION/CHEMICAL ADDITION



D  REVERSE OSMOSIS



D  OZONATION



n  SEDIMENTATION/CHEMICAL ADDITION
                 96

-------
Volume V
Technology

Total Capital
Inve s tment. j&

    Ob

  400,000

  500,000

2,000,000



  300,000
   Total Annual
Operating Cost ($/Yr.)

         Oc

    50,000

   100,000

    60,000



    50,000
a.  0.106 MGD

b.  Plant has aerated lagoon, no new capital required.

c.  Plant has aerated lagoon, no increase in cost.

d.  Chemical = ferric chloride
                                   97

-------
           CONCLUSIONS




Vol. 3  	^ Existing System is Good



Vol. 1  	»- Other Systems Slightly Better



Vol. 4  	^ Incremental Costs High



Overall	+~ Issue Permit
                  98

-------
                              CONCLUSIONS
VOLUME 3



VOLUME 1




VOLUME 4




OVERALL
operated in country (except chromium)
                            ire -lower
                         but not sub-
stantially lower (except chromium)
        ^-^      _
($1.60 to $3.00 per 1,000 gallons of

treated effluent)
                          technology
                   HH with existing
                                   99

-------
                                 TAPE
     Tape h contains the second sample permitting problem which has
been taken from the textile mills industry.  The same format of
presentation used in Tape 3 is used in this tape - a review of the
permit application and presentation of two solution alternatives
for the problem.

     Please review NPDES Permit Application #2.  before viewing this
tape.
                                   101

-------
Please print or type in the unshaded areas only
FORM
NPDES
oEPA
1. OUTFALL LOCATION ^
g| EPA I D. NUM»EH 1. ••«.
001 NA
002 NA




X. MtM. 1. »
NA N
NA N




C LONGITUDE
EC. 1. 0*0. I. MIM. 1, SVC.
i
A NA NA NA NA
A NA NA NA NA





II. FLOWS, SOURCES OF POLLUTION. AND TREATMENT TECHNOLOGIES^ ••^L^HK9^^LaaMaaHaa^n^mBVH»iVmHRN
A. Attach a line drawing showing the water flow through the facility. Indicate sources of intake water, operations contributing wastewater to the effluent,
and treatment units labeled to correspond to the more detailed descriptions in Item B. Construct a water balance on the line drawing by showing average
flows between intake*, operations, treatment units, and outfalls. If a weter balance cannot be determined fag., for certain mining activities), provide a
pictorial description of the nature and amount of any sources of water and any collection or treatment measure*.
B. For each outfall, provide a description of (1) Alt operations contributing wastewater to the effluent, including process wastewater, sanitary wastewater,
cooling water, and storm watar runoff; {2} The average flow contributed by each operation; end (3) The treatment received by the wastewater. Continue
on additional sheets if necessary.
1. OUT-


001


002
t. 0


a. OPERATION fttor>








Scoured wool (15%)
Dyed wool
(15%)
Woven fabric 10
0%)
Knit fabric (100%)
Stock & yarn dyeing (15%)
Felt Dyeing (15%)

TOTAL





NA




(include unit*)








.021 mgd
.021 mgd
. 300 mgd
.300 mgd
.02.1 mgd
.021 mgd

.384 mgd





NA


1. TREATMENT
a. DESCRIPTION








Activated carbon to remove
oil, grease, & color (flow=
.600 mgd) Half of treated
wastewater (.300 mgd)
is recycled back to the
influent. The other half
(also .300 mgd) is combined
with water from occasional
processes (.084 mgd) and
sent to activated sludge.
Clarifier overflow is dis-
charged to river.

NA


b LIST CODES FROM
TABLE 2C-1








2



4




3














A



C




A






OFFICIAL USE ONLY (effluent tuldelmet nib-enttfonet)
EPA Form 3B1O-2C 1640)
                                                     F 1 OF 4
                                                                                            CONTINUE ON I
                                                   102

-------
                  PLANT WATER  FLOW AND THE EXISTING TREATMENT  SYSTEM
INFLUEWT
                WOVEN
               FABRIC
                KNIT
               FABRIC
               SCOURED
                WOOL
DYED
WOOL
                              0. 3
                              0. 3
                                    ACTIVATED
                                     CARBON
                STOCK
                 AND
             YARN DYEING
                FELT
               DYEING
                              0. 021
                              0.021
             0.021
                              0.021
                                                       0. 3
                                                       0. 3
                                                               ACTIVATED
                                                                  SLUDGE.
                                                       0. 084
                                                                              0. 384
TREATED
 EFFLUENT
      *  All  units In millions  of gallons per  day (MGD)
                                          103

-------
 CONTINUED FROM THE FRONT
 C. Except fornorm runoff. leeks, or spill., en any of the dajctwrgM dsacrtbad In lams Iw or B intermment or eworal?
           [3v«* (complete «.« /WtouMrw teM»;                                         QMO fro (o gecnon ra;
 I. OUTFALL
   NUMBER
   t. OPERATION^,;
CONTRIBUTING FLOW
                                                              I. FREQUENCY
 a. DAYS
PER WEEK
                                                             avenge*;
b. MONTHS
PER YEAR
  (tpeeity
a. FLOW RATE
   (in mid)
D. TOTAL VOLUME
 (tpectfy with unlit)
                                                                                                                                   C DUR-
                                                                                                                                   ATION
                                                                                                                                  (in day,)
     001
                 Scoured wool

                 Dyed  wool

                 Stock  & yarn  dyeing

                 Felt  dyeing
                                                  1.8

                                                  1.8

                                                  1.8

                                                  1.8
                        .021

                        .021

                        .021

                        .021
 in. MAXIMUM PRODUCTION":
  A. Does an effluent guideline limitation promulgated by EPA under Section 304 of the Clean Water Act apply to your facility?
 	EH*" (complete Item Ol-BI                                                DUO (to to Section IV>
  B. Are the limitations in the applicable effluent guideline
          §T) VE» (complete Item in-C)
                                      taom of production lor othtr measure of opentionn
                                                            QNO (go to Section IV)
  C. If you answered "Ye§" to Item III*, lift the quantity which represents an actual measurement of your meximum level of production, expressed in the terms
     and units uead in the applicable effluent guideline, and indicate th« affected outfalls.


«. •UAMTITV •>«» DAY
15,000
13,000
220,000
229,000
30,000
30,000


b. UNIT* «H> MBA*U*B
Kg/day
Kg/day
Kg/day
Kg/day
Kg/day
Kg /day
1. MAXIMUM QUANTITY

C. OPBHATfON, PHODUCT, MA
IWtetft)
Scoured wool
Dyed wool
Woven fabric continuous,
Knit fabric continuous,
Stock & yarn dyeing
Felt dyeing


rSHfJU.. KTC.
occasional
occasional
complex finishing
complex finishing
occasional
occasional


flut out fait number*)
001
001
001
001
001
001
 iv. IMPROVEMENTS:
 A. Are you now required by any Federal, State or local authority to meet any implementation schedule for the construction, upgrading or operation of waste-
    water treatment equipment or practices or any other environmental programs which may affect the discharges described in this application' This includes,
    but is not limited to, permit conditions, administrative or enforcement orders, enforcement compliance schedule letters, stipulations, court orders, and grant
                                       DYES (complete the foUowtni tablet           5fino (to  to Item IV-BI
  IDENTIFICATION OF CONDITION.
        AORHMEHT, ETC.
                                     «. AFFECTED OUTFALLS
                                                                             B. KRIEF DCSCRIFTION OF PROJECT
 B. OPTIONAL- You may attach additional sheets describing any additional water pollution control programs lor other environmental pro/nets which may affect
    your discharges! you now have underway or which you  plan. Indicate whether each program is now underway  or planned and indicate your actual or
    planned schedules for construction.
                                              «K.. „ OEKmrriOH OF
EPA Form 3510-2C (6-80)
                                                               PAGE Z OF 4
                                                                                                                      CONTINUE ON PAGE 3

-------
                                ••PA 1.0. NUMacFtreopy from Item 1 of Form 11 I
XtNTINUED FROM PAGE 2 1
V. INTAKE AND EFFLUENT CHARACTERISTICS^^^^^^^^^^^I
A, B, ft C: See instructions be1
NOTE: Tables V-A
Pore proceeding — Complete one set of tables fo

ftfftfftftffffffftftOSi^M
•ach outfall — Annotate the outfall number in the space provided.
•umbered V-1 through V-8.
D. Use the space below to list any of the pollutants listed in Table 2c-3 of the instructions, which you know or have reason to believe is discharged or may be
discharged from any outfall. For every pollutant you list, briefly describe the reasons you believe it to be present and report any analytical date in your
possession.
4. POU.UTAMT

a. »ouitcc

1. POLLUTANT

2. SOURCE

  A  Is any pollutant listed in Item V-C e substance or a component of e substance which you do or expect thet you will over the next 5 years use or manufacture
     as an intermediate or final product or byproduct?
Q Y«a Hi" a" mek foOutcnti below)
                                                                              3 no (to to item VI-B;
  B. Are your operations such that your raw materials, processes, or products can reasonably be expected to very so that your discharges of pollutants may during
    the next 6 yeers exceed two times the maximum values reported in Item V?
                           ] Yea tcomplett Item V/-C below}
                                                                                    (go to Section VII)
  C.  If you answered "Yes" to Item VI-B. explein below and describe in detail the sources and expected levels of such pollutants which you anticipate will be
     discharged from eech outfall over the next E yeers, to the best of your ability at this time. Continue on additional sheets if you need more space
    Concentrations in outfall  001  are  expected  to  vary by as much  as  a factor  of  20 d^ei to
 batch production  method  for wool  scouring,  wool dyeing  and  felt dyeing.

    1,2,A Trichlorobenzene  - up to 10,000 ug/1
    Ethylbenzene - up to  1,500 ug/1
    Toluene - up to  1,400 ug/1
    Benzene  - up to 200 ug/1
EPA Form 3S10-2C (640)
                                                       PAGE 1 OF 4
                                                                                                     CONTINUE ON REVERSE
                                                         105

-------
CONTINUED FROM THE FRONT

VII.  BIOLOGICAL TOXICITY TESTING DATA]
  Do you have any knowledge or reason to believe that any biological test for acute or chronic toxicity has been made on any of your discharges or on a
  receiving water in relation to your discharge within the last 3 yaan?
                           (identify thr teitftt and detcrlbe their purpora below I
                                                                                         DUO (to to Section Vint
    Litton tested  for  Ames  Mutagenicity,  Fathead  Minnow,  and  Daphnia  and found  no  response

    for  all.
VIII CONTRACT ANALYSIS INFORMATION""
  Were any of the analyses reported in Item V performed by a contract laboratory or consulting firm?

                    £3 YES flut the name, addrets, and telephone number of. and pollutant!
                           analyzed by. each such laboratory or firm below)
ff '" S«crion IX)
                                                        •. ADDRESS
 / certify under penalty of law that I have personally examined and am familiar with the information submitted in this application and all
 attachments and that, based on my inquiry of those individuals immediately responsible for obtaining the information, I believe that the in-
 formation is true, accurate and complete. I am aware that there are significant penalties for submitting false information, including the
 possibility of fine and imprisonment.
   A NAME a. OFFICIAL TITLE Hype or print)
                                                                                            B. PHONE NO. (area code & no )
   C SIGNATURE
                                                                                            D. DATE SIGNED
 EPA Form 3610-2C (6-80)
                                                            PAGE 4 OF 4
                                                               106

-------
EPA I.D
PLEASE PRINT OR TYPE IN THE UNSHADED AREAS ONLY. You mav report some or all of
this information on separate sheets fuse the same format) instead of completing these pages
SEE INSTRUCTIONS
O
-0
V. INTAKE AND EFFLUENT CHARACTERISTICS /continued from page 3 of Form 2-CI ^^^^^M^^^^^^M
PART A - You must provide the results of at least one analysis for every poll
1. POLLUTANT
a Biochemical
Oxygen Demand
(BOD)
b Chemical
Oxygen Demand
(COD)
c. Total Organic
Carbon (TOO)
d. Total Suspended
sondi (Tssi
e. Ammonia {of N)
f. Flow
g. Temperature
(winter)
h Temparatura
(tummer)
\. pH

I'l I,!-...
2270
6875
1125
510
NA
VALUE
NA 	
VALUE
MA 	
VALUE
NA

2 EFFLUENT
b MAXl»JtfM ^g^V VALUE
COMC.W.AII.. ''> """•
NA
NA
NA
NA
NA
VALUE
2.52
VALUE
18
VALUE
41

jtdiH in this table Complete
c LONG TJ^M^jJf VALUE
275
/
750
250
76
NA
VALUE
0.384
VALUE
14
VALUE
•^

NUMBER (copy from Item 1 of Form 1)
jne table for each outfall See tnstructi

36
Ifi
36
36
NA
NA
>inn
>1"0

3. UNITS
f«p«ci/j if blank)
mg/1
mg/1
mg/1
mg/1
NA
*>IE(d
°C
°C
STANDARD UNITS
Form Approved OMB No 158-R0173
°UTFALL N°
MB^ — •-• ' '
ons for additiona details.
4 INTAKE (optional
a LONG TERM
C..C.W..™. W— •
NA
NA
NA
NA
NA
VALUE
NA
VALUE
TM/l
VALUE '
a^_J4A 	 	
;
tx NO. OF
NA
NA
NA
NA
NA,
NA,
NA
HA ^—

PART B - Mark "X" in column 2-a for each pollutant you know or have reason to believe is present. Mark "X" in column 2-b for each pollutant you believe to be absent. If you mark
column 2-a for any pollutant, you must provide the results of at least one analysis for that pollutant. Complete one table for each outfall. See the irwtructioiw for additional
details and requirements.
1. POLLUT-
ANT AND
CAS NO.
0" ~.J!«. <•» — ... .«!*.

X 2,0 ^ 1-2 NA mg/1 NA .MA...
X
X
X

6PA Form 3B10-2C <6-«>l PAGE V-l CONTINUE ON REVERSE
NA = not available
                           ND = not detected

-------
o
oo
ITEM V B CONTINUED FROM FRONT
1. POLLUT-
ANT AND
CAS NO.
lit available 1
g. Nltrogan,
Total Organic
tat Nl
h. oil and
Graa-a
1. Phoaphorua
(at P), Total
(7723-14-0)
i MA
a ut-
Llftvea
• KMT
NA


HK X
b r,K.
I~IK V HD
AB-
• «MT
NA
X
X
J. Radioactivity
(1) Alpha,
Total
B) en,.
Total
(3) Radium.
Tout
(4) Radium
228. Total
k. Surfata
(aiSOtl
(14BO8 79-8)
1. Suit KM
f««>
m. Sutflt*
lot S03I
(1426846-3)
n. Surfactant!
«. Aluminum,
Total
(742B-BO-C)
p. Barium,
Total
(7440-38-3)
q. Boron,
Total
(7440-42-8)
r. Cobalt,
Total
(7440-48-41
ft. Ifon, Tout
(7439-80-B)
t. Magnaalum,
Total
(7439 99 4)
u. Molvbdanum,
Total
(7439 US 71
v. Manganaaa,
Total
( 7430-96 6 1
w. Tin, Total
(7440-31 5)
x. Titanium,
Total
(7440-32-6)





x

x
x



X
x




X
X
X
X
X

x


X
x
X


x
x
x
V
3 EFFLUENT
a MAXIMUM DAILY VALUE
M
NA








35

in
25



30
isn




I.I M*..






















b MAXIMUM 30 PjAY VALUE
|,| ''-1-
c o*t« PNTH ATW N
NA








NA

NA
NA



NA
NA




la) •!*••






















C.LONC T^JMJ^y VALUE
(,|
co-<..«T.»-r,o«
NA








5

5
15



25
so




(«) MA»B






















d NO of
ANAL-
YSES
NA








NA

NA
NA



NA
NA





t UNITS
a CONCEN-
TRATION
NA








mg/1

mg/1
mg/1



mE/1
mg/1




b. MASS























5 INTAKt lofinunull
AV-EHPAtWAVur
COMOKMTMATION
NA


,, -_. 	





NA

NA
NA



NA
NA




(*| MAS*



... /—i-^Iii-j —


















J NO OP
ANAL-
YSES
NA








NA

NA
NA



NA
NA




           EPA Form 3610-2C (6-80)
                                                                                                                                CONTINUE ON PAGE V • 3
                              NA=not available
ND=not   detected

-------

EPA l.D. NUMBER (copy from /(cm 1 of Form 1)
NA
OUTFALL. NUMBER
001
Form Approved OMB No. 15B-RO173
PART C - If you are a pr.mary industry and this outfall contains process wastewater, refer to Tdbk 2c-2 in the instructions to determine which of the GC/MS fractions you must test
for Mark "X" in column 2-a for all such GC/MS fractions that apply to your industry and for ALL toxic metals, cyanides, and total phenols. If you are not required to mark
column 2-a (secondary industries, non-process wastewater outfalls, and non-required GC/MS fractions), mark "X" in column 2-b for each pollutant you know or have reason
to believe is present. Mark "X" in column 2 c for each pollutant you believe to be absent. If you mark either columns 2-a or 2-b for any pollutant, you must provide the re-
sults of at least one analysis for that pollutant. Note that there are seven pages to this part, please review each carefully. Complete one table tail seven pages) for each outfall.
See instructions for additional details and requirements.
(.POLLUTANT
AND CAS
NUMBER
ftf avatlablet
2 MARK 'X'
He-
QUIK-
b. • •-
LltVBO
METALS, CYANIDE. AND TOT/
tM. Antimony,
Total 1 7440-36-0)
2M. Arfamc, Total
(7440-38-2)
3M Barylllum,
Total, 7440-41-7)
4M. Cadmium,
Total (7440-43-9)
8M Chromium,
Total (7440-47-3)
8M. Coppar. Total
(766O-50-8)
JM. Laad, Total
(7438-97-6)
»M Marcury, Total
J7438-87-e>
JIM. Nlckal, Total
(7440-O2-0)
10M Salanlum,
Total (7782-49-2)
IIM.Silvac, Total
<7440-22-4)
f — 	 • 	 •
:12M. Thallium,
Total (7 440-28-0)
13M. Zinc, Total
•(7440-66-8)
i)4M. Cyanida,
Total (67-1241)
IBM. Phanoll.
Total
X
X
X
X
X
X
X
X
X
X
X
X
X
Y
X















& •*-
AB-
• KNT
3. EFFLUENT
a MAXIMUM DAILY VALUE
10
U, PHENOL*















0.017
0.150
0.025
0.013
0.750
0.300
0.120
0.0007
0.025
0.065
0.025
0.018
1 .800
22
1800
|l) MAM
















D1OXIN
2,3,7,8-Tatra-
cnlorodloanzo-P-
plo.ln (1764-01 8)

IPA Form 3610-2C (6-80


b. MAXUJU.M^gAjY VALUE
I.I

NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
<,)—••
















C.LONO Tfy«JMJkv,|*f • VALUE
COF4CI

0
0
0
0
n
n
0
(NTMATION

007
039
025
006
020
025
045
0.0004
0
0
0
0
0
012
047
015
003
200
n
115

{.) M...
















d. NO. or
ANAL-
YSES

12
12
12
12
12
1?
12
12
12
12
12
12
12
12
36
4. UNITS
a. CONCEN-
TRATION
•^•ja.
mg/1
mg/1
mg/1
mg/1
mq/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mq/1
mq/1
uq/1
ug/1


j-,ji -















B. INTAKE [optional)
AVERAG
(»' CONCKM-
.NATION
.!_ U — ^u.
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
E VAL.UE
(t) MAM
















tx NO. OP
ANAL-
YSES

NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA

DCICRIIE RESULT!

NA • not available
                             ND - not detected

-------
CONTINUED FROM THE FRONT
AND C Ab
NUMULH

11 I'M '
f;:V,T.y£
3 EFFLULNT
a MAXIMUM DAILY VALUE
M
GC/MS FRACTION - VOLATILE COMPOUNDS
IV Aorolem
(107 028)
2V Acrytonitrile
(107-13-1)
3V Benzene
(71-43-2)
4V ali (Chloro-
mcttiyl) Eth«r
(64288 1)
5V Bromoform
{75-25 2)
6V Carbon
Tatrachloride
(56-23 6)
7V Chlorob«nz«n«
(10890 7)
8V Chlorodt-
iromomathana
(12448 1)
9V Chloroethana
(75-00-3)
10V 2-Chtoro-
•thylvmyl Ethar
(110-75-8)
11V Chloroform
(67-66-3)
12V Olchloro-
iromomethana
(75 27 4)
13V Dichloro-
difluoromathana
(75-71 8)
14V 1,1-Dlchloro-
ethana (76-34 3)
1&V 1,2 Dichloro-
«hana (107-06-2)
16V 1,1 Dichloro-
athylane (75-35 4)
17V 1,2 Dichioro-
profane J73-S7 5)
oropylene
(642 75 6)
19V Ethylbonjerwi
J100-41 4)
20V Methyl
BramidB (74-839)
21V Methyl
Chiorlda (74-87 3)
X
X
X
X
X
X
X
X
x
x
V
X
X
Y
Y 1
V
i
-X— I














	
	 1
x i
X
X
Y

I

















(




NA
,,nlm9»n
25
NA
NA
NA
4.1
NA
NA
NA
22
NA
NA 	
NA
NP
... NA
NA
. NA,
	 125 	
NA
NA
111 «A»,






















b MAXIMUM -10 DAY VALUE
(If auallubl?)
Ill

NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA

NA
NA,
NA
NA
NA
NA
NA
I.|M...






















c LONG TEHM AVRG. VALUE
(If available)
^o«c.i','..,,o

ND
400
9
ND
Nn
ND
3.5
ND
ND
Nn
g
ND
NA
Nn

ND
ND
NA
63
ND
ND

!,!-.».























ti NO 01-
VSES

3
1
3


NA
3
3


3
3
NA


3
3
NA
i
3
3

4 UNITS
A CONCEN
TRATION

Ug/1
Ug/1
ue/1
"E/1


"g/1 —
ug/1
UB/1
ug/1
110 /T
/ 1
ug/1
UB/1
"g/"'
1.0 /I
.,/> /I
Ug/,.
Ilff/1

us'1
ug/1


b. MASS






















5 INI AK t ,l,i_,i,i,,,^lj
d LON
SI cone.*

NA
NA
NA


NA
NA
NA
NA
NA

NA
NA
NA '
NA

NA


NA
NA
, TEHM
111 MA**






















b NO OF
ANAL-
YSES

NA
NA
NA
KA

NA
NA
NA
NA
NA
MA
NA
NA
NA


	 WA—
NA
NA

MA
NA
CONTINUE ON PAGE V-6
                  NA = not available
                                              ND = not detected

-------
CONTINUED FROM PAGE V-4
AND CAS
NUMBER
til available!

JjUL-
A::;
••"••
LIB VKC
• •NT
EPA I.o. NLIMBCI? (copy from Item J of Form It OUTFALL NUMBER
Form Approved OMB No 158 HOI 73
3 EFFLUENT
a. MAXIMUM OABLV
CO^C.L','.,,,,,-
VALUE
iti»»
GC/MS FRACTION - VOLATILE COMPOUNDS fcantfriiwj;
22V. Molhylon«
Chloric). (75-09-2)
chloro«than«
(78-34-BI
24V. Tvtrachloro-
•thytant (127-18-4
25V Toluanc
(10B-88-3)
28V. 1,2-Tran».
Dichloroathylanfl
(186-60-5)
27V. 1,1,1-Trl-
chloroathan*
(71-66-6)
28V. 1,1,2-Trl-
chlorovthan*
(78-OO-S)
29V. Trlchloro
•thytofM <78-OI-«)
3OV. Trlchloro
'luoromathaM
(78-89-4)
31V Vinyl
Chlorlo, (75-01-4)
X
X
X
X
X
X
X
X
—X
— X-
I



















NA
NA
- 5
32
. NA
17
. NA
7 S
NA

OC/M8 FRACTION - ACID COMrOMNO
1A. 2-Chlorophwui
(95-67-8)
2A. 2.4-DlchlOro-
pMnal 112043-2)
3A. 2.4-Dlm*thyl-
phwtol( 106-67-9)
4A. 4.6-Dlnitro-O-
Crnal (634-62-1)
5A 2.4-Dinitro-
phmol (61-28-S)
8A. 2-Nltroph*npl
M-76-6)
7A 4-Nltroph«m>l
(10O-O2-7)
8A. P-Cftloro-M-
CrMOl (69-60-7)
9A. P*nt«chloro-
10A. Ph«nol
(108-96-2)
11 A. 2.4.6-Trl-
chlorophwtol
(88-06-2)
X
X
X
X
X
X
X
X

X























11
9
NA
NA
NA
NA
NA
NA
15
71
10


D MAXIM.U.MJJkgA^Y VALUE
COr,c«~T»«TION

	 NA
	 NA.




















NA
NA
NA
NA
NA
NA
NA
NA

NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
d) •**•»























C.LONC Tf^jf^^- VALUE
10

NT)
- NT!
Q
.. 14
ND
11
MD
4.9
ND
Kin

6
6
ND
ND
ND
ND
ND
ND
12
19

i,i....























d. NO OF
YSES








3
3


3
3
3
3
3
3
3
3
3
3
3
4 UNITS
a CONCEN-
TRATION

HE/I


— ug/1
IIC-/1
,10,/T
Ug/1
UO/1
Ug/1
"£/]

ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ue/1
ug/1
ug/1
b. MASS























5 INTAKE luitliurialj
a LONG TERM


NA
NA
1.1 -...



i


NA
NA
WA
NA
NA.

NA
NA
NA
NA
NA
NA
NA
NA
NA
JPA
NA



















b NO Of
ANAL
V»«»

NA
NA
HA
]^A
MA
NA
NA
MA
NA
NA

NA
NA
NA
NA
NA
NA
NA
NA
NA

NA
6"~-*"«c'-«' NA = not availble ND = not detect6 ** CONTWOE ON BiVfMi

-------
CONTINUED FROM THE FRONT
1 POLLUTANT
AND CAS
NUMBER
i


' iK'TAtV'

di
1,1-...
aC/MS FRACTION - BASE/NEUTRAL COMPOUNDS

(83-32-9)
2B Acenaphtvlans
(208-96-8)
38 Anthracsn*
(120-12-7)
48 Banzidina
(92-B7-5)
6B. Benzo (a)
Anthracanw
156553)
68. Bonzo (a)
Pyrana (50-32-8)
78. 3,4-Barup-
fluoranth«n«
(206 99-2)
8B. B«nzo (ghi)
Pvrylan*
(191-24-2)
98 B.nzo (k>
f luoranthan*
(207-08-9)
1OB. BH (2-Chloro-
ethoxy) Mtthan*
(111-91-1)
118. 8i< (1-Chloro-
tthyl) Ethar
(111-44-4)
12B. Bit f3-C*loro.
bopropylt Eth*r
(38638-329)
138. Bto t2-Etllyl-
h«yl) PhthaUt*
(117-S1-7)
148 4-Bromo-
phanyl Ph*nyl
Ethw (1O1-B5 3)
1KB. Butyl Banxyl
Phth.lata (86-68-7
188 2-Chloro-
(91-68-7)
178 1-Chtoro-
phvnyl Phanyl
Ethar (7OO6-72-3)
IBB. ChryMru
(218-01-9)
198. Dlbanzo 
Anthrac«n«
(S3-7O-3)
208. 1,2-Dichloro-
banzana (95-50 1 1
21B. 1.3 Dlchloro-
banzana (641 73-1
X

X
x
x

x
x
x
x
x
x


y
X


x
x
Y










































unknown
NA
6.5
NA
NA
NA

NA
NA
NA
NA
NA
23
NA
NA
NA
NA
NA
NA
7
NA





















3 EFFLUENT
III

NA
NA
NA
NA
NA
NA
NA

NA

NA
NA
NA
NA
NA
NA

NA
NA
NA
NA


























.5
ND
4.1
ND
ND
ND
NA
ND
ND
wp
ND
ND
18
ND
ND
ND
up
ND
NT)

ND
(?) <*«••























YSES

1
3
3
3
3
3
NA

3-

q
3
3
I
3

^
^
^
3


4 Uf


ug/1
ug/1
-"8/1-
ug'l

Ug/1
Ug/1-

ug/1

-a/1
UK/1
Ug/1
ug/1
Ug/1
Ug/1
"E/1
'ifi/1
"E/1
ne/1

>IITS
























S INTAKE l»pnt>
(l) COMCKH-

NA
NA
NA


NA -
....NA -
NA
NA
NA

NA
NA

NA
NA
NA
NA.
NA
NA
NA























•""> , ...
ANAL-
YSES

NA
NA
NA
NA

NA,
NA
NA
NA
NA
NA
NA
NA

NA
NA
NA
NA
NA

NA
EPA Fom 3610-2C (640)
                        NA
                             not  available
                                                  ND
                                                                  PAGE V-«
                                                       not detected
                                                                                                                        CONTINUE ON PAGE V-7

-------

1 POLLUTANT
AND CAS
NUMBER
(l/ anuifaMi'J
2 MAHK X
*£,"
^



a MAXIMUM OAILY
co«.W..,.u.
NA
3 EFFLUfc-NT
VALUE
10 «.»
GC/MS FRACTION - BASE/NEUTRAL COMPOUNDS Icontlnuedl
228 1,4-Dlchloro-
banzana (10646 7
23B 3,3'-Dlchloro
banzidlna
(91-94-1)
24B Dlathyl
Phthalate
(84-662)
25B Dimethyl
Phthaiata
(131-11 3)
26B. DIN Butyl
Phthaiata
(8474-2)
27B 2,4 Dlnltro-
toluana U21 14-2)
28B. 2,6-Dmltro-
toluana (606-20-2)
29B. Di-N Octyl
Phthaiata
(117-84-0)
30B. 1 ,2-Dlphanyl-
hydrazlna ftu Axo-
twiu«neH122-6S-7
31 B Fluorantharw
(206-44-0)
32 B. Fluorana
(86-73-7)
33B Haxa
chlorobanzan*
(118-71 1)
34B. Hexa-
chlorobutadiarw
(87 68-3)
368 Hexachloro-
cyclopantadlana
(7747-4)
36B. Hexachloro-
athana (67-72-1)
37B. Indano
(1.2.3-cd) Pyrana
(193-39-6)
38B laophorona
(7869 1)
39B Naphthalana
(91 203)
408 Nitrobenzena
(98 96-3)
41B N-N.tro-
•odimethy lamina
(62 75-9)
42B N-Nltrotodi-
N Propylamlne
x
x



x
X
Y
V
x
x
x
x
x

x

X













































20
NA
20
9.0
unknown
NA
NA

NA
NA
NA
NA
NA
NA
MA
NA
NA
Q 3
NA
NA






















b MAXIMUM 30 DAY VALUE
iff available)
hi

NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
Ul M~t>






















001
Form Approved OMB No tS8-ROI73

C.LONG TERM ftVRC VALUE
(if available)
I OHO
di

10
ND
1
1
3
5
0
ft
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Q
2
ND
ND
ND
EPAFom,3610-2C «MX» m . ^ avallable PAGE V
i
-------
CONTINUED FROM THE FRONT
AN [) CAS
NUM BE R
til auailaM* )

h,r'
"^o"
| b «t I c »k
kv.'f'::"
........
3 EF FLUE: NT
a. MAXIMUM DAII-V VALUE
^o.^!.'.'...^.! l'l"«"
GC/MS FRACTION - BASE/NEUTRAL CCNMPOUNOS leonttaufitl
43B N-Nitro
•oil iphany lamina
(86 30-6)
44B Phananthrana
186-01-B)
468. Pyrana
(1290O01
46B. 1,2,4- TrP-
chlorobenzana
(120-82- 11
X
IT
X
X








NA
NA
n,i
1400
OC/MS FRACTION - PESTICIDES
IP Aldnn
(3O9 002)
2P a BHC
(3 IS 84-6)
SP /3 BHC
(319-86 7)
4P 7 BHC
(68-899)
•P.6-BHC
(319-868)
9P Chlordana
)

NA
NA
NA
NA

NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
ill -...






















c LOr,G T^M mf VALUE
111

ND
ND
0.2
200

ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NH
OT1
NT)
ND
ND
ND
|,l M...






















a NO of
ANAL
YSES

3
3
3
6

3
3
3
3
3
3
3
3
3
3
3
3
1
3
3
3
4 UNITS
A CONCEt*
TRATION

ug/1
us/i
ug/1
ug/1

UR/1
UR/1
ug/1
UB/1
ug/1
Ug/1
Ug/1
"E/1
ug/1
ug/1
"E/1
"e/1
i.g/7
UB/1
.,~/l
ug/1
U MASS






















5 INTAKL j,:llll,,tljl/
a L ON
	 A_V.SJiAit
|l| !„«...

NA
NA
NA
NA

NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
MA
NA
j 1 fc HM
L VALUE
<>) M«..






















b NO OF
ANAL
VSES

NA
NA
NA
NA

NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA

NA
EPA Form 3S10-2C (6-80)
                           NA = not available
         PAGE V-8




ND =  not detected
                                                                                                                            CONTINUE ON PAGE V-B

-------
CONTINUEO FROM PAGE V 8
1. POLLUTANT
AND CAS
NUMBER
lit available!
6C/MS FRACTION
17P. H«pt»chlor
Epoxkto
(1024-67-3)
18P. PCB 1242
(634*8-21-8)
IBP. PCB 1 254
(11007-8H-1)
20P. PCB-1221
(11104-28-21
21P. PCB-1232
(11141-16-6)
22P. PCB-124B
<1267228-a)
23P. PCB-128O
(110M-82-6)
24P. PCB 101*
(12874-11-21
26P. ToxapteM
2 MARK 'X1
QUM*
-PE1
X
X
X
X
X
X
X
X
X
tx •«-
TIC40









C Bfc-
AT."»
Effff*










NA
3 EFFLUENT
B. MAXIMUM DAILY VALUE


NA
NA
NA
NA
NA
NA
NA
NA
NA
1,1 -...










b-MAx"ws,2&,a»/v*LuE
iii

NA
NA
NA
NA
NA
NA
NA
NA
NA
|,l M...










001
Form Approved OMB No 159- ft 01 73

C.LONG TJf7""AXPP' VALUE
COttCIMTMAIIOM

ND
ND
ND
ND
ND
ND
ND
ND
ND
MM...










d. HO OF
ANAL
vses

3
3
3
3
3
3
3
3
3
4 UNITS
• CONCEN-
TRATION
^ ^
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
UQ/1
b. MASS










5. INTAKE {optional)
• LONG TERM
AVERAGE VALUE
|l| CONCBM-
TMATION

NA
NA
NA
NA
NA
NA
NA
NA
NA
111 MAM










t> NO or
ANAL
V*E(

NA
NA
NA
NA
NA
NA
NA
NA
NA
EPA Foan 3610-2CIIMO)
                                                        PAGE V-»
                                                   NA  = not  available
                                                   ND  = not  detected

-------
                                TEXTILES

                        "HIGH INTEREST"  POLLUTANTS
                        (selected from 50 reported)
       BOD (mg/1)
       COD (mg/1)
       TOG (mg/1)
     Total phenols
     Acrylonitrile
1,2, if- Trichlorobenzene
          As
          Be
          Cr
          Pb
          Zn
Residual Chlorine (mg/l)
     Sulfide (mg/1)
Average (ug/l)

     275
     750
     250
     115
     200
      39
      25
      20
      ^5
     200
     1.2
     5.0
Maximum (ug/l)

  2,270
  6,875
  1,125
  1,800

  l,toO
    150
    25
    750
    120
    600
    2.0
   35.0
                                    117

-------
                        POTENTIAL "INDICATORS"
                     Indicator             Other Toxics Covered

                         Zn                 Cr(IIl), Pb, Be, As?

                     Total phenols        Phenol, 2-Chlorophenol,
                                          Pentachlorophenol, 2,^,6-
                                          Tri chlorophenol

1,2,^-Trichlorobenzene                    6 other chlorobenzenes
                                   118

-------

Checking removal data summaries for potential processes where we
presently have data;
                              pp. III.4.6-7 through .4.6-8

     o  Sedimentation with chemical addition pp. 111.4.3-13 through
        .4.3-20

                         pp. III.5.1-16 through .5.1-17

                pp. 111.5-3-9 through .5.3-11

                               fta pp.III.6.1-5
                                 119

-------
     FABRIC
  Woven (complex
  finishing)

  Knit (complex
  finishing)
      MAXIMUM
       (kg/day)


       220,000


       229,000
     DRAFT LIMITS — BCT
     BOD
     TSS
     PH
     MAXIMUM
      (kg/day)

       2000
       2200
6-9
     DRAFT LIMITS — BAT
                  MAXIMUM (kg/day)
COD
Total phenol
Total Cr
Total Cu
Total Zn
Color (ADMI units)
1,2,4-trichlorobenzene
     23,200
          7.0
         46
         46
         91
         340
           0.29
               120

-------
                       DRAFT PERMIT LIMITS FOR
                 PROCESSES OPERATED 100$ OF THE  TIME
        Considering only the continuous processes

        jjiiijjjr^J^^
                             -            :•
                                     1100 + 893 -L.
                                     1034 + 1145 m
                                            55.0
                                               •
 'The following calculations illustrate  how to determine BCT Limits
 for BOD^:

     o  Woven fabric - complex finishing (12,200 kkg/yr or greater)
        for BODjj, daily maximum waste load allocation = 5.0 kg/kkg
        of production
        (5-0 kg/kkg) (220 kkg) = 1100 kg 6005 = daily maximum allowed
        from woven fabric process

     o  Knit fabric - complex processing (11,700 kkg/yr or greater)
        for BODc;, daily maximum waste load allocation =3.9 kg/kkg
        of production          ^
        (3-9 kg/kkg) (229 kkg) '= 893 kg BOD5 = daily maximum allowed
        from knit fabric process

     o  Considering only the continuous processes operated 100$ of
        the time at this mill, then BOD5 daily maximum = 1'!00 kg +
        893 kg = 1993 kg * 2000 kg.

2The following calculation illustrates how to determine BAT Limits
 for 1,2,4 - Trichlorobenzene:
     Total effluent flow = 0.384 Mgd = 1,454,000 liters/day

     ,2,4 - Trichlorobenzene is present at 200 ug/1.
     (200 x 10-6 g/D (-1.378 x 106 /day) = 291 g/d = 0.29 kg/day
                                  121

-------
  DRAFT LIMITS — BCT
          MAXIMUM (kg/day)
BOD          1350
TSS          3330
pH     6-9
  DRAFT LIMITS — BAT

                MAXIMUM
                  (kg/day)
COD             6650
Total phenol           2.4
Total Cr             1 2
Total Cu             12
Total Zn             24
Color (ADMI units)   830
           122

-------
     STEPWISE CALCULATION OF DRAFT PERMIT LIMITS FOR
          k PROCESSES OPERATED 15$ OF THE TIME
Next considering the other four processes:
.v":
tr
C^ci^.V^JJi^ '. - '•• : :•
^f- •' 159
;:,-.; ^83
ff; 0
>&. 0
-.->• 0
+
+
292
1+58
+
+
522
1+5 + 1072 + 7^1
.03 + 0.1+2 + 0.
.15 + 3.38 + 2.
.13 + 3.38 + 2.
.30 + 6.76 + 5.
+ 693 =i§o':;::''
+ i860 -<:3330-
+ 1+290 = 6650
39 + l.5j=*2A
7 + 5-7 =:12'":::
7+5-7=12:-
1+ + 11.1+ = 2k
                            (0.25)X(2J|00+190+3^0+38o) ^830*
   Further assuming "Color (ADMI units)" can be adjusted for the
   contribution of various processes in proportion to the fraction
   of total wastwater flow which results from that particular
   process (e.g. "wool scouring," etc.).
                                    123

-------
     DRAFT LIMITS — BCT
              MAXIMUM (kg/day)
   BOD             3400
   TSS             5600
   pH       6-9
    DRAFT LIMITS — BAT
                MAXIMUM (kg/day)
COD               29,900
Total phenol             9.4
Total Cr                58
Total Cu                58
Total Zn               115
Color (ADMI units)      450
1,2,4-trichlorobenzene    0.29

-------
         OVERALL DRAFT PERMIT LIMITS FOR THE  15$  OF TIME
WHEN ALL 6 PROCESSES ARE OPERATED SIMULTANEOUSLY  PLUS OVERALL
              HOLDING TIME OF TREATMENT SYSTEM
    ; IGf ;•: ;,. '-;•-''       •    -      Dally Maadym

     •: BOB •••:    ,                  2000 +  1350 '=
                                   2200 +  3330 = 5600
                                23,200 +  6650 =». 2$,
                                    7-0 +  2. if- =  9.W
                                     46 +  12  = 0
                                     46 +  12  = 58  :
                                     91 +  24  ^ 115
             •wilts }  (0.781 x 34o)+(o.2i9 x  830) -s
                                             0,29
                                  125

-------
Pollutant     Avg., mg/l
  BOD       275



  COD       750



  TSS        76



  TOC       250
        126

-------
                                TEXTILES
Pollutant
Conventional or
  Traditional Pollutants

        BOB
        COD
        fSS
        TOG
Cyanide
Phenols
Chlorine
Sulfide
Oil and Grease
Average (mg/l)
                                                      Maximum (mg/l)
      0.011
      0.115
      1.2
      5.0
2,270
6,875
  510
1,125
    0,022
    1.8
    2.0
   35.0
                                   127

-------
Pollutant       Avg., mg/l
Cyanide       0.011
Phenols       0.115
Chlorine       1.2
Sulfide        5
          128

-------
Pollutant
Average (mg/l)
Maximum (mg/l)
Conventional or
   Traditional Pollutants
        BOD
        COD
        TSS
        TOG
Cyanide
Phenols
Chlorine
Sulfide
Oil and Grease
      275
      750
       76
      250
        0,011
        0.115
        1.2
        5-0
   2,270
   6,875
     510
   1,125
       0.022
       1.8
       2.0
      35-0
                                   129

-------
       Pollutant          Avg., ug/l
       Benzene               9
1,2,4-Trichlorobenzene      200
     Ethylbenzene            63
       Toluene              14
                  130

-------
Pollutant                          Average  (ug/l)      Maximum (ug/l)
Toxic Organic Pollutants

Acenaphthene                             0.5                 ?
Acrylonitrile                          400                   ?
                                V .,, <"^r&4..•            25
Chlorobenz ene                            3«5                 4.1

1,1,1-Trichloroethane                   11                 17
2,4,6-Trichlorophenol                   14                 19
Chloroform                               9                 22
2-Chlorophenol                           6                 11
1,2-Dichlorobenzene                      3-5                 7
1,4-Dichlorobenzene                     10                 20
2,4-Dichlorophenol                       6                   9
lfthylb
-------
      Pollutant            Cone., ug/l
       Benzene                0.2
1,2,4-Trichlorobenzene         0.09
     Ethylbenzene             0.2
       Toluene                0.1
                   132

-------
             VOLUME 5

    Pollutant Treatability Index
                    Lowest Observed
Technology          Concentration (u.g/1)       Page

Activated Sludge         <0.2            III.  5.1-59
                                          III.  5.1-106


Activated Sludge         <0.09           III.  5.1-46
                                          III.  5 • 1-57
                                          III.  5-1-60


Activated Sludge         <0.2            III.  5.1-^5
                                          III.  5.1.46
                                          III.  5.1-56
                                          HI.  5.1-58
                                       ,   III.  5-1-59
                                          III.  5.1-60
                                          III.  5-1-62
                                          III.  5.1-67
                                          III.  5-1-99
                                          in.  5.1-101


Activated Sludge         <0.1            III.  5.1-^0
                                          III.  5.1-^5
                                          III.  5.1-67
                                          III.  5.1-100
                133

-------
PAGE             INDUSTRY
  .5.1-45        Textiles



  .5.1-46        Textiles



  .5.1-59        Textiles



III.5.1-67        Textiles

-------
                        VOLUME 3
      Page   .    -  .                  Industry
III, g,l - %5                        Textiles
III, 5-1- ^                        Textiles
HI. 5.1-59                        Textiles
III. 5-1 - 6?                        Textiles
                        VOLUME 2a
     	Effluent Concentrations (u.g/1)	
      Benzene     1.2, k-Trichlorobenzene  Ethyl Benzene
                             40             <0.3
                            <2             <0.3
                            <2             <0.3
                            <2             <0.3
                             17               0.3
                           135

-------
Batch Operations
Oxygen Stress
Variability
Basins
      136

-------
                        VOLUME 2 (ALTERNATE USE)





                           Page II. 20 - 17







                  which also cause variability (per application) also




discharge high levels of sulfide.






Sulfide may be causing an               in an already overloaded




activated sludge unit.





             H2S + 202 -^H^O^





 35 ppm S~  Requires 70 ppm 02






&&'•*njt&/i$£$$fy may also be shocking activated sludge.






Plants 400, 500 and 700 in volume II, pages II. 20 - 22 to 11.20 - 27




(textiles) utilize hotitt|;'fcftgilg for flow equalization.
                                   137

-------
                                 TAPE 5
                           TREATABILITY MANUAL
                            PANEL DISCUSSION
MODERATOR
RESPONDENTS
PANEL MEMBERS
William Cawley
Gregory Kew
Thomas Hughes
Paul Fahrenthold
Terry Oda
Jack Newman
Harry Thron
Deputy Director
lERL-Cincinnati

OWE-Permits
Monsanto Research
Corporation

OWWM-Effluent Guidelines
Region III
Region V
OWE-Permits
     The Treatability Manual Panel Discussion presents issues related
to the development and use of the Manual in a question and answer
format.  Mr. Cawley, Chairman of the Wastewater Treatability Manual
Coordination Committee, moderates a discussion among the technical
directors of the Treatability Manual project, Mr.  Huges and Dr.  Kew,
and panel members knowledgeable about effluent guidelines development
and the NPDES permit program.
                                 139

-------
                               APPENDIX A
        MEMBERS OF WASTEWATER TREATABILITY COORDINATION COMMITTEE

     It would be impossible to adequately describe the contributions of
committee members and all other individuals who have provided so much
thoughtful assistance during the development of the Treatability Manual,
the videotape series, and the workbook.  The following list serves
merely to identify active membership in the committee during the final
stages of preparation for the first edition of the Treatability Manual;


                    William A. Cawley (Chairman), lERL-Ci
                    Harry E. Bostian, lERL-Ci
                    Bill Chang, OWE-Permits
                    Jesse M. Cohen, MERL-Ci
                    A. B. Craig, IERL-RTP
                    Kenneth A. Dostal, lERL-Ci
                    Paul Fahrenthold, OWWM-Effluent Guidelines
                    Gail S. Goldberg, OWE-Permits
                    Thomas W. Hughes, Monsanto
                    R. Dean Jarman, CERI-Ci
                    I. Atly Jefcoat, lERL-Ci
                    Gary L. Johnson, IERL-RTP
                    William J. Jordan, OWE-Permits
                    Gregory Kew, OWWM-MDSD
                    Susan H. Korper, MATHTECH
                    Art Masse, NEIC
                    Leon Myers, lERL-Ada
                    Murray A. Strier, OWWM-Effluent Guidelines
                    Harry M. Thron, OWE-Permits
                    Marvin Wood, lERL-Ada

-------
             APPENDIX B
       Federal Register Notice
          Vol. ^5, No. 159
           August 1lf, 1980
    National Pollution Discharge
     Elimination System (NPDES);
Availability of Wastewater Treatment
    Manual (Treatability Manual)
                 143

-------
AGENCY:  Environmental Protection Agency





ACTION:  Notice of Availability of Technical Information and



Request for Comments





SUMMARY:  This notice announces the availability of the



Treatability Manual.  The Treatability Manual is a compilation of



available information including:  1) physical, chemical, biological



and treatability data on the toxic or "priority" pollutants; 2)



descriptive information on numerous industrial categories; 3)



summaries of performance data on existing pollutant treatment



technologies; 4) capital, operating and maintenance cost estimates



for these treatment technologies; and 5) an executive summary to



assist users.  To enhance the quality of information in future



supplements or revisions to the Treatability Manual, EPA also is



providing a review and comment period.





DATES:  Comments may be submitted at any time.  However, to be



considered for inclusion in the Manual's first scheduled annual



supplement or revision, comments must be received on or before



April  1, 1981.





ADDRESSES:  Interested persons may obtain a copy of the Treat-



ability Manual after September 15, 1980 by requesting publication



stock  number 055-000-00190-1 from the Superintendent of Documents,

-------
U.S. Government Printing Office, Department 50, Washington, D.C.

20402.  The price of the Manual is $47.00.  The Treatability

Manual is available for examination at the following EPA Regional

Offices, Laboratories and State Offices after September 1, 1980:
EPA Regions

Region I
Region II
Region III
Region IV
(Connecticut, Maine, Massachusetts, New Hampshire,
 Rhode Island, Vermont)

Library
EPA Region I
Twenty-first Floor
JFK Building
Boston, Massachusetts  02203
(617) 223-5791

Librarian
Environmental Research Laboratory
U.S. EPA
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(401) 789-1071

(New Jersey, New York, Puerto Rico, Virgin Islands)

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EPA Region II
Room 845
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New York, New York  10278
(212) 264-9895

(Delaware, Maryland, Pennsylvania, Virginia,
 West Virginia, District of Columbia)

Library
EPA Region III
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(215) 597-0580

(Alabama, Georgia, Florida, Mississippi,
 North Carolina, South Carolina, Tennessee,
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Library
EPA Region IV
345 Courtland Street, N.E.
Atlanta, Georgia  30365
(404) 881-4216

-------
Region V
Region VI
Chris L. West
Office of Public Awareness
Environmental Research Center
Room M-306
U.S EPA
Research Triangle Park, North Carolina  27711
(919) 541-4577

Robert C. Ryans
Environmental Research Laboratory
U.S. EPA
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Athens, Georgia  30613
(404) 546-3306

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Environmental Research Laboratory
U.S. EPA
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Gulf Breeze, Florida  32561
(904) 932-5311  Ext. 218

(Illinois, Indiana, Ohio, Michigan, Wisconsin,
 Minnesota)

Ms. Lou W. Tilley, Librarian
Library
EPA Region V
230 S. Dearborn Street
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(312) 353-2022

Library
Environmental Research Laboratory
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(Arkansas, Louisiana, Oklahoma, Texas, New Mexico)

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EPA Region VI
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1201 Elm Street
Dallas, Texas  75270
(214) 767-4375

-------
Region VII
Region VIII
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Region X
Marvin L. Wood
Robert S. Kerr Environmental Research Laboratory
U.S. EPA
Ada, Oklahoma  74820
(405) 332-8800

(Iowa, Kansas, Missouri, Nebraska)
                    Library
                    EPA Region VII
                    324 E. 11th Street
                    Kansas City, Missouri
                    (816) 374-3497
                       64106
(Colorado, Utah, Wyoming, Montana, North Dakota,
South Dakota)

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Librarian
EPA Region VIII
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(303) 837-2560

(Arizona, California, Nevada, Hawaii)

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EPA Region IX
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Office of Environmental Quality
City Hall
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Las Vegas, Nevada  89101
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(Alaska, Idaho, Oregon, Washington)

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EPA Region X
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Public Information Office
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200 SW 35th Street
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-------
States and Territories
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Alabama Water Improvement Commission
Perry Hill Office Park
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Montgomery, Alabama  36109
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Alaska Operation Office
EPA
Room E-535
Federal Building
701 C Street
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Pati Faiai, Executive Secretary
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Will Gilbert
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John Ward
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 Control and Ecology
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Edward C. Anton
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 Control Board
1416 9th Street, Room 631
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Mr. Arden Wallum
Colorado Department of Health
Water Quality Control Division
4210 East  11th Avenue
Denver, Colorado  80220
(303) 320-8333 Ext. 3361

Connecticut Department
 of Environmental Protection
Water Compliance Unit
122 Washington Street
Hartford,  Connecticut  06115
(203) 566-7167

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Delaware
District of Columbia
Florida
Georgia
Guam
Hawaii
Idaho
Illinois
Mr. Robert Zimmerman
Department of Environmental Control
Water Pollution Control Branch
Edward Tatnall Building
Legislative Avenue and William Penn Street
Dover, Delaware  19901
(302) 736-4761
District of Columbia Department
 of Environmental Services
Room 309
415 12th Street, N.W.
Washington, D.C. 20004
(202) 727-5748

Library
Room 423
Florida Department of Environmental Regulation
Twin Tower Office Building
2600 Blair Stone Road
Tallahassee, Florida  32301
(904) 487-1620

Water Protection Branch
Georgia Environmental Protection Division
270 Washington Street, S.W.
Atlanta, Georgia  30334
(404) 656-4887

O.V. Natarajan, Administrator
Guam Environmental Protection Agency
Agana, Guam  96910

Hawaii State Department of Health
Pollution Technical Review Branch
645 Halekauwila Street
Honolulu, Hawaii  96813
(808) 548-6410

Idaho Operation Office
EPA
422 W. Washington Street
Boise, Idaho  83702
(208) 384-1450

Permits Section
Illinois Environmental
 Protection Agency
2200 Churchill Road
Springfield, Illinois  62706
(217) 782-0610

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Indiana
Iowa
Kansas
Kentucky
Louisiana
Maine
Maryland
Massachusetts
Indiana State Board of Health
Division of Water Pollution Control
Room A-320
1330 West Michigan Street
Indianapolis, Indiana  46206
(317) 633-0795

Department of Environmental
 Quality
Henry A. Wallace Building
900 E. Grand
Des Moines, Iowa  50313
(515) 281-8863

Donald R. Carlson
Kansas Department of Health and Environment
Building 740 - Forbes Field
Topeka, Kansas  66620
(913) 862-9360

Library Conference Room
Division of Water Quality
Kentucky Department for Natural Resources
 and Environmental Protection
Century Plaza #B
1065 U.S. 127 Bypass South
Frankfort, Kentucky  40601
(502) 564-2126

Louisiana Department of Natural Resources
Water Pollution Control Division
625 North 4th Street
Baton Rouge, Louisiana  70804
(504) 342-6363

Steve Groves
Maine Department of Environmental Protection
Hospital Road
Augusta, Maine 04333
(207) 289-2591

William E. Chicca
Office of Environmental Programs
Tawes State Office Building
Annapolis, Maryland  21401
(301) 269-3821

Massachusetts Division of Water
 Pollution Control
110 Tremont Street
Boston, Massachusetts  02108
(617)  727-3855
                                 150

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Michigan
Minnesota
Mississippi
Missouri
Montana
Nebraska
Nevada
New Hampshire
New Jersey
Water Quality Division
Michigan Department of Natural Resources
Stevens T. Mason Building
Lansing, Michigan  48909
(517) 373-8088

Randy D. Burnyeat
Minnesota Pollution Control Agency
Water Quality Division
Permits Section
1935 West County Road B-2
Roseville, Minnesota  55113
(612) 296-7228

Mississippi Department of Natural Resources
Bureau of Pollution Control
2380 Highway 80 West at Southport Mall
Jackson, Mississippi  39209
(601) 961-5171

Missouri Department of Natural Resources
Division of Environmental Quality
Water Pollution Control Program
2010 Missouri Boulevard
Jefferson City, Missouri  65101
(314) 751-3241

Montana Department of Health
 and Environmental Sciences
Water Quality Bureau
Cogswell Building
Helena, Montana  59601
(406) 449-2406

Nebraska Department of Environmental Control
301 Centennial Mall South
Lincoln, Nebraska  68509
(402) 471-2186

Nevada Division of Environmental
 Protection
201 South Fall Street
Room 221
Carson City, Nevada  89710
(702) 885-4670

New Hampshire Water Supply and Pollution
 Control Commission
Hazen Drive
Concord, New Hampshire  03301
(603) 271-3503

New Jersey State Library
185 West State Street
Trenton, New Jersey  08625
(609) 292-6220
                                151

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New Mexico
New York
North Carolina
North Dakota
Ohio
Oklahoma
Oregon
New Mexico Environmental Improvement
 Division
Water Pollution Control Bureau
725 St. Michaels
Santa Fe, New Mexico  87503
(505) 827-5271

New York Department of Environmental
 Conservation
Division of Water
Room 306
50 Wolf Road
Albany, New York  12233
(518) 457-1067

Permits and Engineering Branch
North Carolina Division of Environmental
 Management
Room 912, Archdale Building
512 North Salisbury Street
Raleigh, North Carolina  27611
(919) 733-7120

Division of Water Supply and Pollution
 Control
North Dakota State Department
 of Health
1200 Missouri Avenue
Bismarck, North Dakota  58505
(701) 224-2354

Ann Galli, Librarian
Environmental Technical Information Center
Ohio EPA
361 E. Broad Street
Columbus, Ohio  43216
(614) 466-6058

Office of Water Resources Board
Water Quality Division
1000 N.E. 10th Street
Oklahoma City, Oklahoma  73105
(405) 271-2555

Oregon Department of Environmental Quality
Second Floor
522 South West 5th Avenue
Portland, Oregon  97204
(503) 229-5325
                                 152

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Pennsylvania
Puerto Rico
Rhode Island
South Carolina
South Dakota
Tennessee
Texas
Ernest Giovannitti
Division of Nonpoint and Industrial Sources
Bureau of Water Quality Management
Pennsylvania Department of Environmental Resources
12th Floor, Foulton Bank Building
Third and Locust Streets
Harrisburg, Pennsylvania  21720
(717) 787-8184

Mr. Weems Clevenger
EPA Carribean Field Office
Stop 8 1/2
Avenue Fernandez Juncos
San Juan, Puerto Rico  00902
(809) 725-7825

James Fester
Division of Water Resources
Rhode Island Department of Environmental Management
Room 209
75 Davis Street
Providence, Rhode Island  72908
(401) 227-2234

Charles R. Jeter, Chief
Bureau of Wastewater & Stream Quality Control
South Carolina Department of
 Health and Environmental Control
2600 Bull Street
Columbia, South Carolina  29201
(803) 758-3877

Steve Pirner
Office of Water Quality
South Dakota Department of Water and
 Natural Resources
Room 413, Joe Foss Building
Pierre, South Dakota   57501
(605) 773-4523

Paul E. Davis, Manager
Permits Section
Tennessee Department of Public Health
Division of Water Quality Control
Room 490, Capitol Hill Building
Nashville, Tennessee   37219
(615) 741-7883

Texas Department of Water Resources
Library, Room 511
Stephen F. Austin Building
1700 North Congress
Austin, Texas
(512) 475-7896
                                 153

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Trust Territories
Utah
Vermont
Virgin Islands
Virginia
Washington
West Virginia
Wisconsin
Wyoming
Nachsa Siren, Executive Director
Environmental Protection Board
Trust Territory of the Pacific Islands
Saipan, Mariana Islands  96950

Steve McNeil
State of Utah
Bureau of Water Pollution Control
Room 410
150 W. North Temple
Salt Lake City, Utah  84110
(801) 533-6146

Vermont Agency of Environmental Conservation
81 River Street
Montpelier, Vermont  05602
(802) 828-3345

Division of Natural Resources Management
Building 129
Sub Base
St. Thomas, Virgin Islands  00801
(809) 774-6420

Larry G. Lawson
Virginia State Water Control Board
211 N. Hamilton Street
Richmond, Virginia  23230
(804) 257-6361

State of Washington Department of
 Ecology
St. Martins College Campus
Olympia, Washington  98504
(206) 753-3864

Water Resources Division
West Virginia Department of Natural Resources
1201 Greenbrier Street
Charleston, West Virginia  25305
(304) 348-2107

Paul Didier
Wisconsin Department of Natural Resources
101 S. Webster Street
Madison, Wisconsin  53707
(608) 266-0289

John F. Wagner
Wyoming Department of Environmental Quality
Water Quality Division
401 West 19th Street
Cheyenne, Wyoming  82002
(307) 777-7781

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Comments on the Treatability Manual should be submitted to:

              William A. Cawley
              Industrial Environmental Research Laboratory
              U.S. Environmental Protection Agency
              26 West St. Clair
              Cincinnati, Ohio  45268
              (513) 684-4310
FOR FURTHER INFORMATION CONTACT:

              William A. Cawley
              Industrial Environmental Research Laboratory
              U.S. Environmental Protection Agency
              26 West St. Clair
              Cincinnati, Ohio  45268
              (513) 684-4310
SUPPLEMENTARY INFORMATION:


     The Clean Water Act of 1977 (the Act) places an increased

emphasis on the control of discharges of toxic pollutants from

industrial sources by requiring the achievement of effluent

limitations based on the application of the best available

technology economically achievable (BAT) by July 1, 1984.  The

BAT effluent limitations guidelines are currently under develop-

ment by EPA's Effluent Guidelines Division for numerous industries

which discharge toxic (priority) pollutants.  Although BAT

guidelines have been proposed for several industrial categories,

some BAT guidelines will not be available in the immediate

future.  Also, even where guidelines are available, certain

waste streams may not be covered by the guidelines.  Therefore,

in those cases where no national guidelines exist or where

guidelines are not applicable, NPDES permitting authorities,

either the EPA Regional Office or NPDES State, will be required

to exercise "best engineering judgement" in order to establish

BAT effluent limitations in new or renewed permits.
                                155

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     The Treatability Manual (The Manual) was developed by



EPA's Office of Research and Development (ORD) with assistance



from the Office of Water and Waste Management (OWWM) and the



Office of Water Enforcement (OWE).  The Manual is, primarily, a



compilation of currently available data on the effectiveness of



water pollution control technologies for removal of toxic



pollutants from industrial waste streams.  A variety of data



sources were used to develop the Manual, including:  EPA's



Effluent Guidelines Division's technical files; EPA Regional



and State files; government publications; ORD treatability



studies; equipment vendors' information; and open literature.



     The Manual is expected to be of general interest to industry,



academia, and public interest groups.  NPDES permitting authorities



should find the Manual useful to develop case-by-case effluent



limitations for toxic pollutants in permits in the absence of



national effluent limitations guidelines.  In addition, the



Manual may be used to develop limitations for conventional



and nonconventional pollutants as well as other pollutants not



specifically addressed by national guidelines.  In summary, the



Manual is expected to be useful for:





     o  Evaluating the potential effectiveness and approximate



        costs of proposed effluent treatment systems;



     o  Determining the potential cost and feasibility of compliance



        with discharge limitations under consideration; and



     o  Developing wastewater pollution control strategies.






     While the Manual has been developed to be a  comprehensive



information resource, it is not intended to be a  substitute for



effluent limitations guidelines.
                                 156

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     The Manual consists of five volumes:





          Volume I - Treatability Data



          Volume II - Industrial Descriptions



          Volume III - Technologies



          Volume IV - Cost Estimating



          Volume V - Summary






     Volume I is a compendium of treatability data for specific



pollutants.  Information is provided on the 129 priority pollutants



developed by EPA from the list of 65 chemicals and classes of



chemicals originally contained in a Consent Agreement between EPA



and the Natural Resources Defense Council, 8 ERC 2120 (D.D.C.



1976).  Also included is information on a number of compounds



found among the 299 chemicals (now 297 with the deletion of



calcium oxide and calcium hydroxide from the list) designated



by EPA as hazardous substances under the authority of Section 311



of the Act.  The pollutants contained in the volume are organized



into the following chemical categories:





         o Metals and inorganics



         o Ethers



         o Phthalates



         o Nitrogen compounds



         o Phenols



         o Aromatics



         o Polynuclear aromatic hydrocarbons



         o PCB's and related compounds



         o Halogenated hydrocarbons
                                157

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         o Pesticides



         o Oxygenated compounds



         o Miscellaneous





     For each of the pollutants,  the followinq information is



     provided when available:





     o Alternate names of the  chemical;



     o Chemical Abstracts Number;



     o Physical, chemical, and biological properties,  including



       molecular weight, melting  point,  boiling point, vapor



       pressure, solubility in water at  20° C, log octanol/water



       partition coefficient,  Henry's Law constant, and biodegrad-



       ability data;



     o Probable fate of the compound in  the aqueous environment.



       Removal processes considered include photolysis, oxidation,



       hydrolysis, volatilization, sorption and biological



       processes;



     o Isotherm data on the effectiveness of activated carbon to



       remove organics;



     o Industrial occurrence of the material.  Minimum, maximum,



       and mean concentrations are reported for both untreated and



       treated wastewater for each industry in which the substance



       has been detected; and



     o Average and maximum removal efficiencies and average



       effluent concentrations for specific control technologies.





     Volume II contains a general description of most of the



primary industries  [and their major subcategories] cited in the



1976 NRDC Consent Agreement.  Also included are:
                                158

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         o Subcategory-wide or industry-wide tables covering,



             - the number of dischargers,



             - the types of pollution control systems in use,



             - the range of effluent flow rates and pollutant



                 concentrations in controlled and uncontrolled waste



                 streams, and



             - the efficiency of treatment systems, when available;



         o Summary tables, when available, on BPT effluent



           guidelines and the status of BAT guidelines, New



           Source Performance Standards, and Pretreatment Standards;



           and



         o Tabulated information on individual plants specifying



           industrial subcategory, treatment systems (including



           operating characteristics, when available), effluent



           pollutant concentrations, and influent pollutant



           concentrations, when available.






     Volume III summarizes information on the nature and



effectiveness of various pollution treatment technologies.  It



describes the nature of the generic type of control equipment,



the major variations of design, and the following information on



each of the technologies:





     o Design criteria



     o Typical performance



     o Applications and limitations



     o Reliability information



     o Chemical requirements



     o Environmental impacts
                                 159

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A summary table for each technology is also provided showing the



concentrations of various pollutants in the effluents; the



minimum, maximum, median, and mean removal efficiencies for these



pollutants; and the number of data points used to generate this



information.  Data sheets summarizing the sampling results at



specific installations also are included.






     Volume IV provides typical costs of treatment unit operations,



The following information is provided for each unit operation:






     o Equipment purchase and installation costs;



     o Total capital cost;



     o Total direct operating cost, including materials,



       chemicals, power, fuel and labor; and



     o Total annual operating cost, including total direct



       operating cost and total indirect operating cost



        (plant overhead, taxes, insurance, administrative



       expenses, depreciation, and interest on working capital).






     Volume V is a summary designed to facilitate the use of the



first four volumes by including a user's guide and several



summary tables in the appendices.  Volume V also contains an



executive summary of Volumes I through IV, and a bibliography



listing all references examined and/or used in developing the



Manual.



     Although the Manual contains a considerable amount of data,



it is not intended to be the sole source of information for



permit writers in establishing case-by-case effluent limitations.
                                 160

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Permit writers can be expected to use other available information



including but not limited to:  historical information on the



individual facility; personal knowledge of the particular facility



and similar facilities; applications for permit(s) previously



submitted; applicable Effluent Guidelines' Development Documents;



the initial permit for the discharger (if any) and associated



files; consultation with technical experts both within and



outside EPA; relevant technical reports such as those published



by EPA's Office of Research and Development; attainable effluent



limitations for similar facilities; EPA guidance for best practi-



cable, best available and best conventional technologies as well



as best management practices; trip reports on site visits;



results of ambient and effluent water monitoring; compliance



monitoring reports; and permit writers' engineering judgement.



     The Manual, in the present form, is  intended to be neither



a definitive document on treatment systems performance, nor an



effluent limitations guideline.  The document is a compilation of



existing data as of early 1980 on the performance of various



water pollution control technologies and  systems.



     The Agency expects to update the Manual annually as additional



data become available and believes that the Manual can be improved



and important issues resolved by soliciting public comments on



its content and format.  Therefore, the Agency welcomes any data



or comments of a technical nature that might improve the quality



of the Manual.
                                161

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     At the present time, EPA plans to  revise  the  Manual  by

publishing annually either a supplement or  a revised  manual.   The

supplement or revision will consist of  changes resulting  from

public comments and newly acquired data.  The  Agency  will accept

written comments on the Manual at any time  after the  date of  this

notice.  However, in order for comments to  be  considered  for

inclusion in the first supplement or revision,  comments must  be

received no later than April 1,  1981, 90 days  before  the  expected

publication date of the first annual supplement or revised

manual.  Comments received after this date  will be reviewed and

considered for the next supplement or revision. The  same time-

table is expected to be maintained for  subsequent  supplements or

revisions, as necessary.


     Each year, the Agency will  review  all  comments received

during the preceeding 12-month period and respond  to  significant

comments as appropriate.  The response  may  take the form  of the

publication of a summary of significant comments and  responses in

the Federal Register and/or incorporation of suggestions  into the

annual supplement or revision.

DATED:
     Jeffrey G. Miller                       Stephen J.  Gage
Acting Assistant Administrator          Assistant  Administrator
      for Enforcement                 for  Research  and Development
                                 162
                                   •fr U.S. GOVERNMENT PRINTING OFFICE:  1980--657-165/0152

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