United States EPA-905-R97-002g
Environmental Protection Agency May 1997
WASTE MANAGEMENT
Risk Assessment for the Waste Technologies Industries (WTI)
Hazardous Waste Incineration Facility (East Liverpool, Ohio)
VOLUME VII:
Accident Analysis: Selection and Assessment of
Potential Release Scenarios
U.S. Environmental Protection Agency - Region 5
Waste, Pesticides and Toxics Division
77 West Jackson Blvd.
Chicago, IL 60604
Prepared with the assistance of'
A.T Kearney, Inc. (Prime Contractor; Chicago, IL);
with Subcontract support from:
ENVIRON Corp. (Arlington, VA),
Midwest Research Institute (Kansas City, MO)
and EARTH TECH, Inc. (Concord, MA)
under EPA Contract No. 68-W4-0006
*>
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VOLUME VII
ACCIDENT ANALYSIS: SELECTION AND ASSESSMENT OF
POTENTIAL RELEASE SCENARIOS
CONTENTS
Page
I. INTRODUCTION 1-1
A. General Methodology I-1
B. U.S. EPA/FEMA/DOT Approach to Hazards Analysis 1-2
1. Hazards Identification 1-4
2. Vulnerability Analysis 1-6
3. Risk Analysis 1-7
C. Previous Accident Analyses for the WTI Facility I-11
D. History of Emergency Incidents Reported at Commercial
Incineration Facilities in the United States 1-12
II. IDENTIFICATION OF ACCIDENT SCENARIOS II-1
A. Methodology II-1
B. Initial Identification of Accident Scenarios II-1
C. Selection of Accident Scenarios for Quantitative
Consequence Evaluation II-6
1. On-Site Spill II-6
2. On-Site Fire 11-10
3. On-Site Mixing of Incompatible Wastes 11-12
4. Off-Site Tanker Truck Spill 11-14
5. Off-Site Tanker Truck Spill with Fire II-16
D. Summary of Results and Key Assumptions II-16
III. CHEMICALS OF POTENTIAL CONCERN III-1
A. Methodology III-1
B. Preliminary Identification of Chemicals o<~ Potential Concern III-1
C. Selection of Specific Chemicals for Each Accident Event III-4
1. On-Site Spill III-4
2. On-Site Fire III-7
3. On-Site Mixing of Incompatible Wastes III-8
4. Off-Site Tanker Truck Spill III-9
5. Off-Site Tanker Truck Spill with Fire HI-9
D. Selection and Acute Toxicity Criteria III-9
E. Summary of Results and Key Assumptions III-10
IV. CHARACTERIZATION OF ACCIDENTAL RELEASES IV-1
A. Methodology IV-1
B. Chemical-Specific Release Rate Calculations IV-2
1. On-Site Spill " IV-2
2. On-Site Fire IV-2
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CONTENTS
(continued)
3. On-Site Mixing of Incompatible Wastes IV-4
4. Off-Site Tanker Truck Spill IV-5
5. Off-Site Tanker Truck Spill with Fire IV-6
C. Summary of Results and Key Assumptions IV-6
V. ATMOSPHERIC DISPERSION MODELING V-l
A. Model Selection V- ]
B. Meteorological Conditions V-l
1. Typical Conditions V-2
2. Conservative Conditions V-2
3. Calm/Inversion Conditions V-3
C. Summary of Results and Key Assumptions V-4
VI. SEVERITY OF CONSEQUENCES AND PROBABILITY
OF OCCURRENCE VI-1
A. Severity of Consequences VI-3
1. On-Site Spill VI-4
2. On-Site Fire VI-5
3. On-Site Mixing of Incompatible Wastes VI-7
4. Off-Site Spill VI-8
5. Off-Site Fire VI-10
B. Probability of Occurrence VI-12
1. On-Site Events VI-12
2. Off-Site Events VI-18
C. Summary of Results and Key Assumptions VI-22
1. On-Site Events VI-22
2. Off-Site Events VI-24
3. Summary of Major Assumptions VI-25
D. Screening Level Evaluation at East Elementary School VI-25
1. Background and Objectives VI-25
2. Estimation of Chemical Concentrations VI-26
3. Comparison of Concentrations to Acute Toxicity Criteria VI-28
4. Probability of Occurrence VI-30
5. Results of Screening-Level Evaluation VI-32
6. Uncertainties VI-33
7. Discussion VI-36
VII. UNCERTAINTIES VII-1
A. Toxicity Evaluation VII-1
B. Exposure Assessment VII-1
1. Scenario Uncertainty ,- / VII-2
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VIII.
IX.
CONTENTS
(continued)
2. Parameter Uncertainty
3. Model Uncertainty
C. Sensitivity Analyses
1. Effect of Mitigation Measures
2. Effect of Averaging Time
3. Fire Scenarios Under Calm/Inversion Meteorological Conditions
SUMMARY AND CONCLUSIONS
REFERENCES
'age
VII-3
VII-4
VII-5
VII-6
VII-8
VII-10
VIII-1
IX-1
TABLES
Table I-1: Accident Scenarios Evaluated in the WTI Credible Event Analysis 1-14
Table 1-2: Results of the Report on Emergency Incidents at Hazardous Waste
Incinerators and Commercial Treatment, Storage, and Disposal
Facilities (TSDFs) 1-15
Table II-1: Partial List of Passive Mitigation Features at the WTI Facility 11-17
Table II-2: Preliminary 11-18
Table II-3: WTI Fire Protection Systems 11-22
Table II-4: Distribution of Cargo Losses from Full Size Tankers During Highway
Transit in the U.S. from 1971 to October 1986 11-23
Table II-5: Scenarios Selected for Quantitative Evaluation . 11-24
Table II-6: Key Assumptions Made in the Identification of Accident Scenarios 11-25
Table III-1: Summary of Chemicals of Potential Concern for
Short-Term Exposures III-11
Table III-2: Constituents Received in Largest Quantities in Pumpable Waste
at the WTI Facility III-18
Table III-3: Hydrogen Chloride and Phosgene Formation from Decomposition
of Chlorinated Hydrocarbons in Contact with Flame III-19
Table III-4: ERPG, LOG, and IDLH Values 111-20
Table III-5: Wastes and Chemicals Evaluated 111-21
Table III-6: Key Assumptions Made in Selecting Chemicals of Potential Concern 111-22
Table IV-1: Chemical-Specific Emission Rates IV-7
Table IV-2: Key Assumptions Made in Estimating Chemical Emission Rates IV-8
Table V-1: Stability Wind Speed Combinations Used to Determine
"Conservative" Meteorological Conditions V-5
Table V-2: Summary of Downwind Air Concentrations for the On-Site
Spill Scenario V-6
Table V-3: Summary of Downwind Air Concentrations for the On>Site
Mixing of Incompatible Wastes Scenario V-7
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CONTENTS
(continued)
Table V-4: Summary of Downwind Air Concentrations for the Off-Site
Spill Scenarios
Table V-5: Summary of Downwind Air Concentrations for the On-Site
Fire Scenario
Table V-6: Summary of Downwind Air Concentrations for the Off-Site
Fire Scenarios
Table V-7: Key Assumptions Made in Dispersion Modeling
Table VI-1: Criteria Used in Ranking the Severity of Consequence
Based on IDLH Valued
Table VI-2: Criteria Used in Ranking the Severity of Consequence
Based on LOG Values
Table VI-3: Criteria Used in Ranking Probability of Occurrence
Table VI-4: Severity of Consequence for On-Site Scenarios
Based on IDLH Values
Table VI-5: Severity of Consequence for On-Site Scenarios
Based on LOC Values
Table VI-6: Severity of Consequence for Off-Site Scenarios
Based on IDLH Values
Table VI-7: Severity of Consequence for Off-Site Scenarios
Based on LOC Values
Table VI-8: Summary of Downwind Distance to IDLH, On-Site Spill
Table VI-9: Summary of Downwind Distance to LOC, On-Site Spill
Table VI-10: Summary of Downwind Distance to IDLH, On-Site Fire
Table VI-11: Summary of Downwind Distance to LOC, On-Site Fire
Table VI-12: Summary of Downwind Distance to IDLH,
On-Site Mixing of Incompatible Wastes
Table VI-13: Summary of Downwind Distance to LOC, On-Site Mixing of
Incompatible Wastes
Table VI-14: Summary of Downwind Distance to IDLH, Off-Site Spill
Table VI-15: Summary of Downwind Distance to LOC, Off-Site Spill
Table VI-16: Summary of Downwind Distance to IDLH, Off-Site Fire
Table VI-17: Summary of Downwind Distance to LOC, Off-Site Fire
Table VI-18: Probability of Occurrence for On-Site Scenarios
Table VI-19: Probability of Occurrence for Off-Site Scenarios
Table VI-20: Severity of Consequence and Probability of Occurrence
Results for On-Site Scenarios
Table VI-21: Severity of Consequence and Probability of Occurrence
Results for Off-Site Scenarios
Table VI-22: Key Assumptions Made in Ranking of Accident Events
Table VI-23: Screening-Level Chemical Concentrations at the Distance
to the School
Page
V-8
V-9
V-10
V-ll
VI-38
VI-39
VI-40
VI-41
VI-42
VI-43
VI-44
VI-45
VI-46
VI-47
VI-48
VI-49
VI-50
VI-51
VI-52
VI-53
VI-54
VI-55
VI-56
VI-57
VI-58
VI-59
VI-60
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CONTENTS
(continued)
Table VI-24: Estimated RHR Values and Probabilities of Occurrence for
All Emission Scenarios
Table VII-1: Consequence Assessment, On-Site Spill with Mitigation
Table VII-2: Consequence Assessment, On-Site Fire with Mitigation
Table VII-3: Consequence Assessment, On-Site Mixing of Incompatible Wastes
with Mitigation
Table VII-4: Results of Averaging Time Sensitivity Analysis
Table VII-5: Summary of Maximum Concentration Factors Modeled by the
ISC-COMPDEP and CALPUFF Models for the Fire Scenarios
Table VII-6: Comparison of Downwind Distances to the IDLH and LOC Values
Modeled by the ISC-COMPDEP and CALPUFF Models
for the Fire Scenarios
Table VII-7: Severity of Consequence and Probability of Occurrence for the
Fire Scenarios Under Calm/Inversion Meteorological Conditions
Table VIII-1: Probability/Severity Matrix (Based on LOC Values)
Table VIII-2: Probability/Severity Combinations (Based on LOC Values)
Table VIII-3: Probability/Severity Matrix (Based on IDLH Values)
Table VIII-4: Probability/Severity Combinations (Based on IDLH Values)
VI-64
VII-13
VII-14
VII-15
VII-16
VII-17
VII-18
VII-19
VIII-3
VIII-4
VIII-5
VIII-6
FIGURES
Figure II-1: WTI Site Plan
Figure II-2: Local Access Route
Figure II-3: Location for the Off-Site Spill
Figure IV-1: Area of Off-Site Spill
Figure VIII-1: Illustrative Accident Frequency/Severity Screening Matrix
11-26
11-27
11-28
IV-9
VIII-7
Appendix VII-1:
Appendix VII-2:
Appendix VII-3:
Appendix VII-4:
Appendix VII-5:
APPENDICES
Incidents Reported at the WTI Facility and Comparable Facilities
Ranking of Chemicals of Potential Concern
Accidental Release Modeling
Atmospheric Dispersion Modeling
Off-Site Accident and Spill Frequency Analysis
Volume VII
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I. INTRODUCTION
A. General Methodology
The WTI Risk Assessment includes an analysis of potential human health effects caused
by accidents that may occur during operation of the WTI facility. The approach for
conducting this analysis has been developed based on guidance published by the United States
Environmental Protection-Agency (e.g., IJ.S. EPA 1987; 1995a) and other agencies, such as
the U.S. Federal Emergency Management Agency (FEMA 1993). The primary objective of
the Accident Analysis is to assess the potential for human health effects associated with general
types or classes of accidents that could occur at the WTI facility.
The WTI Accident Analysis also addresses comments from the independent peer review of
the WTI Phase II Project Plan (U.S. EPA 1993a). During the peer review, concerns were
raised regarding health impacts associated with chemical releases that could occur as a result
of on-site and off-site accidents, particularly given the proximity of the WTI facility to schools
and residences (U.S. EPA 1994a).
The data base for evaluating the human health risks posed by low frequency accidents at
hazardous waste management facilities is limited. Due to this limited data base, there is
significant uncertainty in conducting a quantitative analysis of risks posed by accidents at the
WTI facility. The Accident Analysis has, therefore, been developed based on scientific
judgment as well as available quantitative and qualitative information, an approach consistent
with the U.S. EPA's Accidental Release Prevention Requirements: Risk Management
Programs Under Clean Air Act Section ]]2(r)(7); Final Rule (U.S. EPA 1996a) and Technical
Guidance for Hazards Analysis: Emergency Planning for Extremely Hazardous Substances
(U.S. EPA 1987).
The Accident Analysis for the WTI facility evaluates the potential for acute health effects
that may result from short-term (i.e., less than 24 hour).exposures of individuals located
within the immediate vicinity of the WTI facility. Of primary interest in the Accident
Analysis are the potential health effects associated with events which could have significant
short-term off-site consequences; generally, these events do not have a*high probability of
occurring. In addition to these conservative scenarios, more typical events with a greater
likelihood of occurrence but a lower probability of causing adverse off-site health effects are
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also examined. For both conservative and typical accident scenarios, a range of
meteorological conditions (including atmospheric inversions) are evaluated, and the effect of
emergency response measures is assessed.
Consistent with the peer review comments, both on-site and off-site accidents are included
in the analysis. For the on-site accident scenarios, the off-site distance over which human
health effects might be anticipated is estimated. The distance over which health effects may
occur in the event of an off-site transportation accident along the local access roads to the
facility is also identified. In determining the distance over which effects may occur, inhalation
is expected to be the primary route of short-term exposure for the off-site community. While
direct dermal exposure may also be of concern, exposures through inhalation are predicted to
occur over a larger area, and be more likely to result in adverse health effects. Furthermore,
this analysis focuses on the short-term, direct exposure to accidental releases, rather than
longer-term, indirect exposures that might occur from contamination caused by an accident.
Given that the focus of this assessment is the adequacy of existing design and operation
features in protecting the off-site community, risks to on-site workers are not evaluated.
Furthermore, as discussed in U.S. EPA guidance (U.S. EPA 1992a), ecological assessments
typically focus on risks to ecological communities, rather than risks to individual receptors.
Most plausible accident scenarios would affect relatively small areas (i.e., within 5 miles of
the facility), and thus are unlikely to affect entire ecological communities. Thus, potential
ecological risks associated with facility accidents are not evaluated.
Many different types of events, or combination of events, could lead to the general classes
of accidents evaluated in this study. Thus, a rigorous evaluation of the causes of specific
accident scenarios, based on fault-tree analyses or other detailed techniques, has not been
performed. Instead, probabilities of occurrence of the various classes of accident events
considered are estimated using the semi-quantitative methods presented in technical guidance
for hazards analysis by U.S. EPA (1987) and FEMA (1993). This approach is consistent with
U.S. EPA's Final Rule for Accidental Release Prevention Requirements (U.S. EPA 1996a).
B. U.S. EPA/FEMA/DOT Approach to Hazards Analysis
The Emergency Planning and Community Right-to-Know Act (EPCRA) of 1986, also
known as Title HI of the Superfund Amendments and Reauthonzation Act (SARA), requires
local emergency planning committees (LEPCs) to develop emergency response plans for
facilities in the event of an emergency. Site-specific hazards analysis is one tool LEPCs can
use to better understand the potential risks posed by airborne releases &f extremely hazardous
substances (EHSs) from a facility. An EHS is defined by U.S. EPA as a chemical with high
acute lethality, having the potential for causing death in unprotected populations after
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relatively short exposure periods at low doses (U.S. EPA 1987). More than 360 chemicals
listed under Title III of SARA have been identified by U.S. EPA as EHSs. primarily on the
basis of acute toxicity (U.S. EPA 1987). This list of EHSs was considered in selecting
chemicals of potential concern in the WTI Accident Analysis. Additional chemicals of
potential concern in the WTI Accident Analysis were identified through a review of
information on wastes projected to be received during the first year of WTI operations.
To assist in the development of comprehensive emergency plans. I'.S EPA. FEMA and
the United States Department of Transportation (U.S. DOT) jointly issued the Technical
Guidance for Hazards Analysis (U.S. EPA 1987) outlining a three-step "hazards analysis"
process for identifying potential hazards facing a community with respect to accidental releases
of EHSs. This general approach was also adopted in the FEMA Handbook of Chemical
Hazard Analysis Procedures (FEMA 1993). The process described in U.S. EPA (1987)
consists of the following three components:
Hazards Identification, involving the collection and review of specific information on
situations that have the potential for causing injury to life or damage to property and
the environment due to a hazardous materials spill or release (e.g., chemical
identities; location of storage and use; quantities stored or used; nature of the hazard)
Vulnerability Analysis, involving the identification of areas in the community that ma\
be affected or exposed (vulnerable zones); individuals in the community who may be
subject to injury or death from certain specific hazardous materials (including
sensitive human subpopulations). and facilities, property or environment that may be
susceptible to damage should a hazardous materials release occur (critical facilities
and environment).
Risk Analysis, involving an assessment of the likelihood (probability) that an
accidental release of a hazardous matciial might occur, and the severity of
consequences that might result from the release. Combining the accident probability
analysis with measures of predicted consequences provides an estimation of the
overall risk, which can be used for priontization and planning purposes.
The intent of the Technical Guidance for Hazards Analysis (U.S. EPA 1987) is to assist with
the development of a community-scale emergency plan. Other guidance' has been used as
necessary to supplement the Technical Guidance for Hazards Analysis as described throughout
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this report. In developing a methodology for the Accident Analysis for the WTI facility, the
hazards analysis process has been adopted as a general framework, as described below.
1. Hazards Identification
Hazards identification, the first step in hazards analysis, is the process of collecting
and reviewing information on:
the types and quantities of hazardous materials at the facility;
the locations and conditions of specific.areas within the facility where hazardous
materials are handled, stored, used, treated or disposed; and
routes used for transporting hazardous materials to, from and within the facility.
From this information, it is possible to develop potential accident scenarios (both on-site
and off-site) that might result in spills or releases that could lead to off-site exposures in
the surrounding community. Examples of on-site accident scenarios that might be relevant
for a hazardous waste facility include storage tank ruptures, process line failures, fires in
storage tank areas, failures of transfer lines and hoses during off-loading of tanker trucks,
spills from off-loading tanker trucks, explosions during operation of a combustion system.
and failure of the air pollution control equipment Off-site accident scenarios that could
be considered include chemical releases caused by collisions involving tanker trucks or
railcars hauling hazardous materials
In the WTI Accident Analysis, the hazards identification process consists of the
following major elements:
Identification of conservative and typical accident scenarios, based on a general
review of the facility layout, a site visit and an evaluation of reports on accidents
that have occurred at WTI and at comparable U.S. facilities. The accident
scenarios identified for the WTI facility are representative of categories of
accidents listed in FEMA (1993), and which could occur during the types of
activities performed at the facility.
Review of chemicals of possible concern with regard to the identified accident
scenarios. Chemicals of possible concern are identified primarily through a
review of waste profiles received during WTI's first year of operation, acutely
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hazardous wastes ("P" wastes) as defined in 40 CFR §261.33(e), and hazardous
substances listed under Section 112(r) of the Clean Air Act and Section 302 of
EPCRA. Although "P" wastes are not currently received at the WTI facility.
these wastes are not prohibited by the permit.
Compilation of acute toxicity criteria and physical/chemical data for the
chemicals of possible concern. For this analysis, predicted off-site concentrations
associated with selected accident scenarios relevant to the WTI facility are
compared to acute toxicity criteria known as "Immediately Dangerous to Lite or
Health" (IDLH) values. IDLH values are developed by the National Institute tor
Occupational Safety and Health (NIOSH), and represent the maximum
concentration of a chemical in air from which an individual could escape within
30 minutes without experiencing any escape-impairing or irreversible health
effects (FEMA 1993). The IDLH values published by NIOSH were originally
developed to be protective for healthy adult male workers, and have not been
adjusted to account for the heterogeneous population (e.g., children, elderly) who
might be exposed to chemicals in an event with off-site consequences. In some
cases individuals in the general population might require a longer escape time
and/or be more sensitive to the chemical exposure compared to healthy adult male
workers (U.S. EPA 1987) Therefore, predicted off-site concentrations were also
compared to "Level of Concern" (LOC) values, which are generally more
conservative than the IDLH values. According to U.S. EPA (1996a), LOC
values "have been peer reviewed by EPA's Science Advisory Board, they are
intended to be protective of the general public for exposure periods of up to an
hour, they are widely used by the emergency response planning community, and.
for a majority of the listed toxic substances, there are no acceptable alternatives."
The LOC value for a given chemical is usually, but not always, equal to the
IDLH divided by a factor of ten
In addition to IDLH and LOC values, the American Industrial Hygiene
Association (AIHA) has developed Emergency Response Planning Guideline
(ERPG) values for examining the potential consequences of acute exposures.
According to AIHA, the ERPG values are intended to provide estimates of
concentration ranges above which one could reasonably anticipate observing
certain adverse effects. Three tiers of ERPG values are M'sted by AIHA, based
on the consequence of exposure to a specific substance (AIHA 1994).
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The ERPG-1 value is the maximum airborne concentration below which
it is believed nearly all individuals could be exposed for up to 1 hour
without experiencing other than mild transient adverse health effects or
perceiving a clearly defined objectionable odor.
The ERPG-2 value is the maximum airborne concentration below which
it is believed nearly all individuals could be exposed for up to 1 hour
without experiencing or developing irreversible or other serious health
effects or symptoms that could impair their abilities to take protective
action.
The ERPG-3 value is the maximum airborne concentration belou which
it is believed nearly all individuals could be exposed for up to 1 hour
without experiencing or developing life-threatening health effects.
The U.S. EPA has noted that for substances with both an ERPG-2 value and an
LOG value, the LOG value is similar to and in some cases identical to the
ERPG-2 value (U.S. EPA 1996a). A comparison of IDLH, LOG, and ERPG
values for the specific constituents evaluated in the Accident Analysis are
presented in Section D of Chapter III.
Each of the above steps is described in greater detail in subsequent chapters of this volume
of the WTI Risk Assessment.
2. Vulnerability Analysis
According to the Technical Guidance for Hazards Analysis document (U.S. EPA
1987), the vulnerability analysis involves the identification of areas of the community
surrounding a facility that may be affected in the event of a hazardous release, and the
identification of specific subpopulations within this area that may be of particular concern
The vulnerability analysis also includes an evaluation of the consequences of an accident.
In the WTI Accident Analysis, the methodology for the consequence analysis consists
of the following steps:
selecting, on the basis of comparison to published acute exposure levels, specific
waste materials and chemical constituents to characterize the potential
consequences of each accident scenario. Those substances with the greatest
hazard, based on acute toxicity, quantity, and release potential are selected for
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further evaluation, as these substances would generate the greatest impact if the\
were carried downwind in sufficient concentrations:
estimating the chemical constituent release rates for each accident scenario;
calculating the atmospheric dispersion of released materials or propagation of
energy release (e.g., heat effects) to receptors; and
comparing the resultant modeled exposure levels to published acute exposure
levels as a measure of the area over which adverse health effects might occur
Specific subpopulations within the community that may be at particular risk are
identified. A number of residences and an elementary school (East Elementary School)
are located approximately 1,000 feet north of the incinerator. This area is comprised of
single-family homes, the elementary school and a business college. The area due west of
the facility (approximately one-quarter mile) is also residential/commercial. Based on the
peer review Work Group comments (U.S. EPA 1994a), and observations made during a
site visit, subpopulations of special concern include children in the nearby school, as well
as residents living near the site or along the local access route.
3. Risk Analysis
Risk analysis, the final step in hazards analysis, provides an assessment of the
likelihood that an accidental release of a hazardous material will occur, a semi-quantitative
assessment of the associated consequences and the potential effect of emergency response
measures. Considered together, the outcomes of the accident probability analysis and the
consequence analysis can provide an overall measure of the risk. This overall measure of
risk can be expressed qualitatively, semiquantitatively or quantitatively, depending on the
objectives of the analysis and the nature of the available data.
As discussed previously, because of the limited availability of quantitative data, the
probability analysis consists primarily of a semi-quantitative evaluation of the likelihood
of an event occurring. The Technical Guidance for Hazards Analysis document (U.S.
EPA 1987) identifies the following guidelines as examples for evaluating accident
probability:
/.
Low Probability of occurrence considered unlikely during the expected
lifetime of the facility, assuming normal operation and maintenance.
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Medium Probability of occurrence considered possible during the expected
lifetime of the facility.
High Probability of occurrence considered sufficiently high to assume event
will occur at least once during the expected lifetime of the facility.
In addition to these qualitative guidelines, FEMA (1993) has also developed five
categories in cases where more quantitative information is available on accident
frequency:
Common Expected to occur one or more times each year on average.
Likely Expected to occur at least once every 10 years on average according to
available statistics.
Reasonably
Likely Predicted to occur between once every 10 years and once every 100
years on average
Unlikely Predicted to occur between once every 100 years and once every 1.000
years on average in a specific locale.
Very
Unlikely Predicted to occur less than once in 1,000 years.
Based on the guidelines presented in FEMA (1993), common and likely accidents
may be equated to "high"; reasonably likely and unlikely accidents to "medium"; and very
unlikely accidents to "low" probability categories, as defined by U.S. EPA (1987).
The following qualitative guidelines are provided by U.S. EPA (1987) as an example
to evaluate the severity of consequences:
Low Chemical is expected to move into the surrounding environment in
negligible concentrations Injuries expected only for exposure over
extended periods or when individual personal health conditions create
complications.
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Medium Chemical is expected to move into the surrounding environment in
concentrations sufficient to cause serious injuries and/or deaths unless
prompt and effective corrective action is taken. Death and/or injuries
expected only for exposure over extended periods or when individual
personal health conditions create complications.
High Chemical is expected to move into the surrounding environment in
concentrations sufficient to cause serious injuries and/or deaths upon
exposure. Large numbers of people expected to be affected.
FEMA (1993) presents a four tier system for classifying the consequences of accident
scenarios:
Minor
Low potential for serious human injuries; no potential for human
fatalities; and no need for a formal evacuation, although the public
may be cleared from the immediate area of the spill or discharge
Moderate
Major
Catastrophic
Up to 100 potential human injuries requiring medical treatment or
observation; up to 10 potential human fatalities; or evacuation of up
to 2.000 people.
Up to several hundred potential human injuries requiring medical
treatment or observation; up to 100 potential human fatalities; or
evacuation of up to 20.000 people.
More than 300 potential human injuries requiring formal medical
treatment; more than 100 potential human fatalities; or evacuation of
more than 20,000 people.
Although not explicitly indicated by FEMA (1993), it is reasonable to equate minor
accidents to "low"; moderate accidents to "medium"; and major and catastrophic accidents
to "high" severity of consequence categories, as defined by U.S. EPA (1987).
The definitions provided by FEMA (1993) for categorizing consequences are not
directly applicable to the WTI Accident Analysis. However, the general system described
in FEMA (1993) serves as the basis for the following severity of consequence categories
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developed specifically for the WTI Accident Analysis using LOG values as acute toxicitx
criteria:
Minor
No exceedance of an LOG value in inhabited off-site areas, and
negligible potential for off-site fatalities or serious injuries due to
heat effects from a fire.
Moderate
Major
Catastrophic
Exceedance of LOG values in inhabited off-site areas over distance*
of 200 meters or less; injuries due to heat effects limited to a
distance of 200 meters into inhabited areas.
.Exceedance of LOG values in inhabited off-site areas over distances
between 200 meters and 2.000 meters: injuries due to heat effects
limited to a distance of 2,000 meters into inhabited areas.
Exceedance of LOG values in inhabited off-site areas over distances
greater than 2,000 meters; injuries due to heat effects extend to
distances greater than 2,000 meters into inhabited areas.
A similar system based on IDLH values has also been developed:
Minor
No exceedance ot an IDLH value in inhabited off-site areas, and
negligible potential for off-site fatalities or serious injuries due to
heat effects from a fire
Moderate Exceedance of IDLH values in inhabited off-site areas over
distances of 100 meters or less; injuries due to heat effects limited to
a distance of 100 meters into inhabited areas.
Major
Catastrophic
Exceedance of IDLH values in inhabited off-site areas over
distances between 100 meters and 1,000 meters; injuries due to heat
effects limited to a distance of 1,000 meters into inhabited areas.
Exceedance of IDLH values in inhabited off-site areas over
distances greater than 1,000 meters; injuries due to heat effects
extend to distances greater than 1,000 meters into inhabited areas
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The severity of consequence categories used in this Accident Analysis are more
conservative than the rankings presented in FEMA (1993). For example, FEMA (1993)
assigns a moderate ranking to events which are predicted to result in "up to 100 potential
human injuries requiring medical treatment or observation; up to 10 potential human
fatalities; or evacuation of up to 2,000 people." In this Accident Analysis, a moderate
ranking is assigned to events which are estimated to have the potential to result in less
than 40 people on average exposed to concentrations exceeding the LOG, and 10 people
on average exposed to concentrations exceeding the IDLH. Similarly conservative criteria
are used in the Accident Analysis for ranking events as potentially major or catastrophic.
Thus, the severity of consequence rankings in this Accident Analysis cannot be directly
related to the criteria presented in FEMA (1993).
The accident scenarios identified for the WTI facility are evaluated to determine
whether any have likelihood-consequence rankings of high-high, high-medium, medium-
high, or medium-medium. Based on the Technical Guidance document (U.S. EPA 1987),
such events should be evaluated to determine whether additional mitigation or emergency
response measures are feasible. FEMA (1993) suggests that scenarios with likelihood-
consequence ranking of low-high and/or high-low also be included in evaluating
emergency planning.
C. Previous Accident Analyses for the WTI Facility
An analysis of the potential off-site consequences of accidents at the WTI facility was
previously performed by WTI to address the implications for immediate response actions. The
results of this analysis were summarized in a report entitled Waste Technologies Industries
Credible Event Analysis for Emergency Planning, prepared by SE Technologies, Inc. (1992).
The objectives stated in the report are to identify credible accident scenarios, assess their
impact in terms of release of hazardous agents into the environment, and identify a maximum
credible event that could be used as a reasonable basis for on-site and off-site emergency
planning. The WTI Credible Event Analysis does not include the preparation of a
comprehensive list of all potential accident scenarios, or the calculation of the relative
probabilities of various accidents occurring.
To finalize the WTI Credible Event Analysis, comments were solicited from the Ohio
State Emergency Management Agency, Ohio Department of Public Health, Ohio
Environmental Protection Agency, Columbiana County (Ohio) Local Emergency Planning
Committee, and the Emergency Management Agencies of Columbiana*County (Ohio),
Hancock County (West Virginia), and Beaver County (Pennsylvania). The scenarios used in
the final report were selected during a meeting held on January 17, 1992 in Columbus, Ohio
Volume VII Ml
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between WTI, SE Technologies, Inc., Ohio Environmental Protection Agency, Ohio
Department of Public Health, and Ohio Emergency Planning Agency.
The Credible Event Analysis evaluates eight accident scenarios. Of the eight scenarios,
one (a release of 20,000 Ib of ammonia) is no longer relevant to the WTI facility due to a
change in proposed facility design and operation. Of the seven remaining scenarios, five are
predicted to involve off-site hazards, as summarized in Table 1-1. The event determined by
WTI to have the greatest potential off-site consequences involves mixing of incompatible
wastes, which is predicted to result in possible exceedances of the LOG for chlorine up to
7,000 m downwind. Based on these results, the report concludes that it is prudent to plan for
public protection actions within approximately a 5-mile (8,000 m) radius of the WTI site.
While this is not the area over which worst-case accident scenarios would be confined, it is
identified as the area most likely to be affected in an extreme credible accident event (SE
Technologies 1992).
D. History of Emergency Incidents Reported at Commercial Incineration Facilities in the
United States
The U.S. EPA (1995b) has compiled a review of reported emergency incidents at
hazardous waste incinerators and commercial treatment, storage and disposal facilities
(TSDFs) regulated under the Resource Conservation and Recovery Act (RCRA). Descriptions
are provided for incidents reported to have occurred between 1977 and May 1995 at 11
commercial hazardous incinerators, 10 noncommercial incinerators and 23 other commercial
TSDFs in U.S. EPA (1995b), and summarized in Tables 1 and 2 of Appendix VII-1. The
information included in U.S. EPA (1995b) was compiled by contacting combustion experts
and permit writers in each of the 10 U.S. EPA Regional offices, as well as individuals within
state regulatory agencies. Since U.S. EPA does not maintain a central data base of
information on emergency incidents, some information is based on the recollections of U.S.
EPA and State staff. Additional limitations of the study include the lack of information on the
reporting period for the individual facilities, and that the information is received in response to
a voluntary survey.
In the U.S. EPA (1995b) report, an emergency incident is defined as "a hazardous waste
spill, unauthorized release, fire, or explosion." Not all incidents identified in the report
resulted in releases of hazardous waste to the environment. Furthermore, many of the
incidents reported in U.S. EPA (1995b) occurred before facilities received RCRA permits, and
full RCRA safeguards were, therefore, not necessarily in effect. The results of the U.S. EPA
(1995b) report are summarized on Table 1-2.
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A total of 50 emergency incidents, as defined by U.S. EPA. were reported at the
hazardous waste incinerators identified in the stud\. For commercial hazardous waste
incinerators only, 24 emergency incidents at 11 facilities were reported, with 10 of these
incidents involving a release of hazardous waste. It should be noted thai no emergency
incidents have been reported at 15 commercial incineration facilities (including WTI). so these
facilities were not discussed in U.S. EPA (1995b). The combustion facilities with no reported
emergency incidents are included in Table 1 in Appendix VII-1 to facilitate evaluation of
emergency incidents relative to the number of facilities operating in the United States.
The total operating time for the 26 commercial incinerators during the time period
considered by the study is approximately 250-300 years. This operating time total is likely to
be an underestimate, since no information is available for operations before 1981. and no
operating dates were available for two facilities. Based on 10 reported emergency incidents
involving hazardous waste over a total of 250-300 years of operation, approximately one
emergency incident involving a hazardous waste release has been reported for every 25-30
years of operation for the commercial incinerators. None of the 10 reported incidents
involving releases of hazardous waste resulted in a fatality or serious injury in off-site
communities, although on-site worker injuries and fatalities have occurred (U.S. EPA 1995b).
Based on the lack of fatalities or serious off-site injuries associated with reported accidents at
commercial hazardous waste combustion units, the probability of an event having moderate.
major or catastrophic consequences (i.e., a release of hazardous waste resulting in serious off-
site injuries or fatalities) would be classified as unlikely, or very unlikely over the facility
lifetime, using the definitions presented in FEMA (1993). The probability of occurrence of an
event having minor consequences (i.e., a release of hazardous waste resulting in minor or no
off-site effects) would be classified as reasonably likely over the facility lifetime, according to
FEMA (1993).
Volume VII 1-13
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TABLE 1-1
Accident Scenarios Evaluated in the WT1 Credible Event Analvsis1
Scenario
On-site spill of 55 gallons of liquid
waste containing 10% methyl aery late
(volatile release).
On-site spill of 50 gallons of liquid
waste containing 40% acrolein (volatile
release).
On-site spill of 5,000 gallons of liquid
waste containing 85% toluene (volatile
release).
On-site spill of 5,000 gallons of liquid
waste containing 85% toluene (fire).
On-site spill of 50 gallons of liquid
waste containing 20% acetone (volatile
release).
On-site mixing of incompatible waste,
resulting in 10,000 Ib release of
chlorine gas over 60 minutes.
On-site spill of 5,000 gallons of liquid
waste containing methyl ethyl ketone
(MEK) (volatile release).
On-site release of 20,000 Ib. of
ammonia over 60 minutes.2
Consequence
1. Exceedance of LOG up to 16 meters
(m) downwind; no off-site hazard
anticipated.
2. Exceedance of LOG up to 900 m
downwind.
3. Exceedance of LOG up to 70 m
downwind.
4. Damage from explosion of vapor cloud
could extend up to 375 m; detonation
of fireball could result in an injury zone
radius of 190 m and a fatality zone
radius of 90 m.
5. Exceedance of LOG up to 10m
downwind: no off-site hazard
anticipated.
6. Exceedance of LOG up to 7.000 m
downwind, under early morning
inversion conditions.
7. Exceedance of LOG up to 335 m
downwind.
8. Exceedance of LOG up to 6,300 m
downwind.
Notes:
1 Source: SE Technologies (1992).
2 This scenario is no longer relevant to the \VTI facility due to a change in facility design
and operation.
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TABLE 1-2
Results of the Report on Emergency Incidents at Hazardous Waste Incinerators
and Commercial Treatment, Storage, and Disposal Facilities (TSDFs)
Number of Facilities Reporting Incidents'
Total Number of Incidents Reported
Number ot Incidents Involving a Release ot
Hazardous Waste to the Environment1
Hazardous Waste
Combustion
Facilities
21
50
21
Commercial
Hazardous Waste
Combustion Facilities
11
24
10
Other
Commercial
TSDFs
T;
48
-"
Notes
Count adjusted from U.S. EPA (1995b) because (a) there was a typographical error under Region V, m which
there are 5 (not 6) combustion facilities and (b) classification of Rollins Environmental Services in Logan
Township, New Jersey, as an incinerator and not a TSDF, per Appendix 1 of U.S. EPA (1995b).
Counts in this row are derived from the summary table in U.S. EPA (1995b), which does not specify the
criteria used to classify "a release of hazardous waste to the environment." Based on information provided in
U.S. EPA (1995b) probable incidents at combustion facilities were identified; of these, 10 occurred ai
commercial facilities.
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II. IDENTIFICATION OF ACCIDENT SCENARIOS
A. Methodology
A first step in performing the Accident Analysis for the WTI facility is to identify accident
scenarios that may have the potential to cause adverse human health effects in the surrounding
community. Such scenarios are identified through a general review of the design and
operation of the WTI facility, and accident events that have occurred at WTI or comparable
U.S. facilities. Given the large number of hypothetical scenarios of potential concern, a subset
of accident events is selected for quantitative analysis. These events are chosen to represent
general types or classes of accidents that might occur, as identified in FEMA (1993). such as a
spill or fire.
This chapter provides an overview of the process used to identify possible accident
scenarios, and to select the specific scenarios to evaluate in the Accident Analysis.
B. Initial Identification of Accident Scenarios
The initial identification of accident scenarios involves the following steps:
A general background review of the tacihty design and layout, along with inlormation
on operating procedures and controls. Available accident data reported at WTI and at
facilities comparable to WTI are also reviewed.
Development of a preliminary list of accident events based on the background review.
A site visit to the WTI facility by the U.S. EPA Accident Analysis team to confirm
information gathered during the background review and observe actual facility
operations.
Analysis of information gathered by the U.S. EPA Accident Analysis work group
resulted in refinement of the preliminary list of accident scenarios and identification
of events of primary concern.
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The general background review of information relevant to accidents at the WTI facility focuses
on identifying areas where hazardous materials are transported, received, handled, stored or
treated. This involves a review of the permit and permit application for the WTI facility, as
well as a review of the facility plot plan. An overview of key accident prevention emergencx
response features of the design and operation of the WTI facility, as presented in WTI (1982 >
and WTI (1992), is provided below.
Fires and releases at the WTI facility are detected, monitored and controlled through a
computerized system that is run by the operator in the control room. Through a control panel.
the operator is able to monitor all process areas, thus assuring that they are functioning
normally. The operator is able to shut down facility processes and equipment, including the
electrical, heating, ventilation, air conditioning and exhaust systems, should a problem arise
The facility was designed, for orderly shutdown in the event of an equipment failure or power
outage. An emergency power generator is designed to provide electricity for electrical
motors, emergency lighting, pumps, instruments, and controls essential to safe plant operation.
According to WTI, the WTI facility was designed so that potential on-site spills would be
contained by a combination of sumps, drainage trenches, dikes, walls, curbs, speed bumps.
ramps, berms, and other contour features. Table II-l presents a partial list of passive
mitigation features in place at the WTI facility. In the event of a spill, inert or absorbent
materials will reportedly be placed in the path of the release to confine the release to as small
an area as possible. Materials and equipment that come in contact with waste have been
selected to withstand chemical and physical attack. Material thicknesses equal to or exceeding
the minimum required industry standards or codes have been specified to provide protection
against both corrosion and erosion. Concrete surfaces have been covered or treated, where
appropriate, to resist chemical attack. Incompatible wastes are segregated into separate
containment areas.
Where possible, piping is visible and easily accessible. Visual inspections are conducted
by WTI personnel at least once per day for the tanks and blending vessels, ventilation and
exhaust systems; instruments and controls, surfaces and sumps in the unloading, loading, and
sampling areas; processing and treatment areas; and paved and concrete surfaces. Inspections
of pumps and fans; electrical motors; and the emergency electric power generator are
conducted at least once per week. Additionally, more extensive inspection procedures are
conducted on a regular basis.
All buildings where hazardous waste is handled are protected by automatic fire
suppression systems designed to extinguish fires and keep fires from spreading. For certain
buildings or areas, this includes a foam system which is generally regarded as effective in
extinguishing and preventing the re-ignition of a wide variety of chemical fires. These
t
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systems are reportedly designed, constructed, equipped, and installed according to all
applicable codes and regulations, including those promulgated by the National Fire Protection
Association (NFPA), Factory Mutual, the Ohio Fire Code, and the Ohio Basic Building Code
In addition, fire suppression systems have been inspected and certified by the East Liverpool
Fire Department. Alarms on the fire monitor are triggered automatically whenever one of the
automatic sprinkler systems is activated or manually when one of the fire alarm boxes located
throughout the plant is activated.
Temperature, pressure, and fluid level data are available in the control room for each
enclosed tank, including the wastewater tanks and process water holding tanks. When pre-set
limits are reached, visual and audible alarms in the .control room will signal the operator that a
problem exists. In the case of a vessel or a tank being filled with a pump, the fluid level
control device will automatically deactivate the pump and close the intake valve whenever a
high level is indicated. Combustible gas detectors are present in sumps in the organic waste
tank farm to detect flammable vapors and thereby alen the operator to the potential for a fire.
In addition to an assessment of the facility design and operation, the background review
includes an evaluation of the following:
reported equipment and procedural failures at the WTI facility between June 1993 and
January 1997, as summarized in Table 3 of Appendix VII-1 (Victorine 1997)
scenarios described in two accident analyses previously performed for the WTI
facility Credible Event Analysis for Emergency Planning (SE Technologies 1992)
and WTI's Emergency Plan Exercise (Von Roll 1993).
reported incidents at hazardous waste incinerators and treatment, storage and disposal
facilities (TSDFs) in the United States, as compiled by U.S. EPA (1995b) These
incidents, which are summarized in Tables 1 and 2 of Appendix VII-1. tend to be
relatively high frequency, low consequence events primarily minor explosions in
incineration and air pollution control equipment. None of the incidents reported in
U.S. EPA (1995b) resulted in serious injuries or fatalities off-site, although serious
injuries and fatalities have occurred among on-site workers. The results of the U.S.
EPA (1995b) study were confirmed through a review of incidents reported at TSDFs
in the U.S. EPA Accident Release Inventory Program (ARIP) data base, which
summarizes information on releases which occurred from 19*7 to early 1993 (Chung
1995).
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Based on the background review, a preliminary list of conservative on-site and off-site
candidate events is developed for consideration in the WTI analysis (Table II-2). Many of the
events are very similar, differing only in the location of the accident and the quantities of the
chemicals involved. The potential accident scenarios for the WTI facility identified in Table
11-2 can be grouped into the following general categories:
Spill or leak of liquid waste, followed by:
evaporation and atmospheric dispersion of hazardous constituents: or
fire with entrainment and dispersion of hazardous constituents, generation and
dispersion of hazardous products of combustion or incomplete combustion, or
boiling, vaporization and dispersion of hazardous constituents in close proximit)
to the fire.
Mixing of incompatible wastes, followed by:
venting and dispersion of gaseous reaction products; or
bursting of tank or pipe and release of liquid waste.
Explosion of tank or pipe (hydraulic or thermal over-pressure) with release of liquid
wastes.
Failure of the air pollution control equipment.
Release and dispersion of hazardous substances from incinerator due to a leak,
explosion or component failure.
Transportation accidents, followed by a spill or leak.
Scenarios that involve fires or rapid gas generation may also involve explosions, depending on
the nature of the accident and waste.
Following the background review, these scenarios were further refined based on site
specific information resulting from a site visit by members of the U.S. EPA accident analysis
work group. Participating work group members included representatives of U.S. EPA Region
5, the Office of Solid Waste and Emergency Response (OSWER) and the Chemical Emergency
Preparedness and Prevention Office (CEPPO) The primary objective'of the site visit was to
examine potential accident scenarios in the context of the WTI facility location, layout and
operational practices.
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Based on existing guidance, the review of accidents reported at WTI and comparable
facilities, a review of the design and operation of the WTI facility, the site visit, and
subsequent discussions within the U.S. EPA Accident Analysis team, the following general
scenarios are considered to be of primary concern:
On-site spill
On-site fire
On-site mixing of incompatible wastes
Off-site tanker truck spill
Off-site tanker truck spill with fire
The criteria used hi selecting these general scenarios are: 1) potential for significant off-
site consequences, and 2) potential for occurring during the expected operating life of the
facility (30 years), based on available data. The on-site scenarios selected for the Accident
Analysis (spill, fire, and mixing of incompatible waste) are consistent with those evaluated in
the WTI Credible Event Analysis (SE Technologies 1992). However, an ammonia release
evaluated by SE Technologies (1992) is no longer relevant due to changes in the proposed
design and operation of the WTI facility. Furthermore, the Accident Analysis examined
several off-site scenarios not included in the Credible Event Analysis.
Possible off-site impacts due to upset conditions and accidents occurring inside the
incinerator are judged to be of lesser concern than other types of facility accidents, based on a
review of the consequences of accidents which have been reported at hazardous waste facilities
(U.S. EPA 1995b) and other industrial facilities. The consequences of these types of events
relative to accidents involving waste storage, handling or transport are typically lower,
primarily because the quantity of waste being processed by the incinerator at any one time is
much less than the quantities that are stored, handled or transported. As a result, accidents
involving the storage, handling and transport of wastes would be expected to have more severe
off-site consequences than accidents directly involving the incinerator.
In assessing off-site accidents, this analysis considers waste transport through the local
community. Although it is theoretically possible in the nature for wastes to be received by the
WTI facility via truck or rail, local waste transport currently occurs by truck. Transport via
barge does not occur within the vicinity of the facility, and there are no plans for barge
transport in the future. Rail transport represents a future option for the WTI facility, but plans
remain at the concept stage. Thus, the Accident Analysis evaluates the potential effects of
truck accidents only.
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Specific accident events from Table II-2 within each of the five general scenario categories
are evaluated. Because many of the events within each general scenario category are similar
in nature, a single conservative site-specific event within each category is selected for
quantitative evaluation. A more "typical" event, i.e., one with a higher likelihood of
occurrence than the conservative event, was also selected within each category The ti\ e
conservative events and five typical events selected for quantitative evaluation and the criteria
for their selection are discussed below.
C. Selection of Accident Scenarios for Quantitative Consequence Evaluation
1. On-Site Spill
Spills could be caused by numerous situations, including leaks from drums that are
not in good condition or are damaged; leaks from improperly packaged containers;
releases from tanks due to overfilling, faulty transfer lines or structural defects; releases
of the contents of tanker and trailer trucks from leaks or ruptures resulting from an on-site
accident; and releases caused by catastrophic events, such as a tornado. On-site spills
have been reported by U.S. EPA (1995b) at several commercial hazardous waste TSDFs.
Examples of some larger spills that have occurred include the following:
In 1982, at the Laidlaw incineration facility in Roebuck, South Carolina. 3.000-
gallons of solvent spilled from a corroded pipe. A 6,000-gallon spill of maleic
anhydride from a storage tank was reported to have occurred at the same facility
in 1988.
In 1985, at the CP Chemicals TSDF in Sumter. South Carolina, storage tank
valves reportedly were left open intentionally by two facility workers (both of
whom were later arrested), releasing 2,200 gallons of ammonia and 2,000 gallons
ofHCl.
In 1989, a transfer line failure resulted in a 9,600-gallon spill of wastewater with
solvents at the Oil and Solvent Process Company TSDF in Azusa, California. A
transfer line failure also reportedly resulted in a 30,000-gallon spill of wastewater
containing wood treating waste at the International Paper TSDF in Joplin.
Missouri in 1992. *'
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At the WTI facility, a total of five spills of waste, all less than 20 gallons have been
reported since operations began in June 1993 (see Table 3 of Appendix VII-1).
Spills that occur on-site may result in the formation of a liquid pool, the areal extent
and depth of which depends on the release rate and duration, as well as the presence of
any containment barriers (e.g., dikes, speed bumps, building walls, etc.) in the spill
vicinity. If no containment barriers are present to limit the areal extent of the pool, n can
be assumed that the spill will spread to an area with a thickness of approximate!) 1 cm
(U.S. EPA 1987; Moorhouse and Carpenter 1986). Following the release, evaporation of
the pool could result in off-site exposure to the spilled chemicals. The evaporation rate of
chemicals from a liquid pool is determined primarily by the rate of mass transfer as air
flows over the surface of the pool. The mass transfer rate is, in turn, determined largely
by the wind speed, the vapor pressure of the spilled material and the surface area of the
pool.
Spills could occur at the WTI facility during waste handling, transfer and storage
The WTI facility can store approximately 800.000 gallons of liquid waste in two main
permitted storage areas: 1) the Organic Waste Tank Farm, and 2) the Container
Processing Building (WTI 1992).
Consistent with the objective of this analysis to evaluate credible events that are
expected to result in the most potentially significant off-site consequences, three
conservative accident types are considered for quantitative analysis:
A major spill within the indoor drum storage area of the Container Processing
Building. The total capacity of the area is approximately 500,000 gallons of
liquid waste in drums. This corresponds to approximately 9,000 55-gallon
drums, which are stored in twelve separate rows and placed in racks with three
vertical levels. The Container Processing Building is divided into two sections.
each having a secondary containment capacity that exceeds 10%, i.e., one-tenth,
of the maximum volume of waste that can be accumulated in that area.
A major spill in the indoor Organic Waste Tank Farm storage area. There is a
total capacity of approximately 300,000 gallons of waste in the 16 large tanks in
this building, as well as a 20,000-gallon fuel tank. The Organic Waste Tank
Farm is divided into four sections, each having a secondary containment capacity
that exceeds the volume of the largest tank in that area. *
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A major spill outdoors due to an accident involving one full tanker truck, with a
capacity of 5,000 gallons of liquid waste. Locations where such an accident
could occur include the Truck Holding and Sampling Area, the Truck Unloading
Station, and the paved area between the Truck Unloading Station and the Truck
Holding and Sampling Area (see Figure II-l).
Of these three conservative events, the outdoor spill involving a tanker truck in the
Truck Unloading Station is selected for quantitative evaluation in the Accident Analysis
This event is selected for the following reasons:
All three events could involve a spill of large quantities of liquid waste. The
composition of the waste could also be the same in each event. While the two
indoor scenarios could conceivably result in larger volumes of spilled material,
the areas of the spills (and thus the hazardous waste constituent emission rates)
would be largely constrained by berms. For example, the Organic Waste Tank
Farm is divided into four containment areas of approximately 180 nr each. An
outdoor spill from a tanker truck potentially could spread and cover a maximum
area of approximately 418m2 due to the containment barriers. Thus, the area of
an outdoor spill, depending on its location, could be significantly larger than the
area of an indoor spill.
For indoor spills that do not exceed the secondary containment capacities,
atmospheric emissions will occur primarily via volatilization. Such volatilization
would be reduced relative to outdoor spills due to lower air flow rates over the
surface of the pool. Furthermore, a significant portion of the releases from an
indoor spill would be expected to be contained within the building. Because of
this, outdoor spills are expected to have a greater potential for substantial off-site
impacts.
A very large spill in the Container Processing Building or the Organic Waste
Tank Farm could possibly spill over the containment barriers, leading to a larger
pool area. However, it is unlikely that such pools would be larger than the pool
size (418 m2) estimated for the outdoor tanker truck spill. Although the
containment volume for each building is smaller than the maximum storage
capacity, the containment volumes should be sufficient for containing spills most
likely to occur.
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It should be emphasized that the event selected to evaluate the potential off-site
impacts of an on-site spill is judged to represent a "worst case" scenario. Thus, other on-
site spills, such as a leak from a transfer line, would be expected to ha\e lowr off-site
consequences. To evaluate the potential off-site health effects associated with a more
"typical" accident scenario, an on-site spill of 100 gallons of liquid waste is also
evaluated. The spill volume of 100 gallons is selected based on the review of reported
incidents at the WTI facility (the largest spill reported at WTI from June 1993 to Januarx
1997 was approximately 20 gallons), and data from the U.S. DOT (1995). According to
U.S. DOT (1995), the average spill of liquid hazardous materials accidentally released
during highway transponation was 120 gallons for the 10 year period ending in 1994. and
80 gallons for the 5 year period ending in 1994. indicating that 100 gallons is a reasonable
estimate of the size of a typical spill. For the purposes of this assessment, the typical 100-
gallon spill is also assumed to occur near the Truck Unloading Station.
In this Accident Analysis, both conservative and typical scenarios are evaluated
assuming no active mitigation. In finalizing its proposed rule regarding accidental release
prevention requirements (USEPA 1995a), U.S. EPA is considering incorporating effects
of passive mitigation systems, but not active mitigation systems, into the worst-case
release scenario, if such systems are capable of withstanding destructive events (e.g.,
fires, explosions, floods, hurricanes and earthquakes). Passive systems would include
dikes, catch basins, and drains for liquids, and enclosures for both liquids and gases.
Scenarios involving passive mitigation systems that have connections to the environment
(such as a rainwater drain valve) would have to assume failure of that connection. In the
WTI Accident Analysis, passive systems capable of withstanding destructive events are
included in evaluating the no active mitigation scenarios.
In Chapter VII (Uncertainties), a separate evaluation of the potential effect of active
mitigation is also assessed. Two mitigation scenarios are evaluated:
All releases are effectively mitigated within 10 minutes. This mitigation time is
conservative for smaller spills and in situations where automatic systems are in
place (e.g., foams for fire suppression). However, as discussed in Chapter VII,
mitigation of larger spills or accidents may require more than 10 minutes.
All releases are effectively mitigated in one hour. This mitigation time may be
appropriate for high volume spills and in situations where^automatic mitigation
systems are not in place. Based on a detailed review of emergency response
procedures, one hour was determined to be the approximate mitigation time for
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two major accident scenarios evaluated in WTI's Emergency- Exercise Plan (Von
Roll 1993).
Chapter VII also presents an assessment of the impact of a failure of passive
mitigation devices (e.g,. dikes and berms) in the case of a large on-site spill.
2. On-Site Fire
Several events, including an on-site spill, could cause a fire if an ignition source is
present. Such a fire could result in the increased volatilization of waste constituents, as
well as the formation of combustion products of concern, particularly when wastes
containing nitrogen, sulfur or halogens (e.g., chlorine or bromine) are burned. While
complete combustion typically results in the formation of relatively simple compounds
such as carbon dioxide (CO2), water (H:O), nitrogen oxides (NOX), sulfur dioxide (SO.)
and hydrogen chloride (HC1), other more complex substances may also be produced as a
result of incomplete combustion. The types of substances formed will depend on a
number of factors, including the chemical makeup of the waste, the combustion
temperature, and the extent of mixing with air. In addition to the release of these products
of combustion and incomplete combustion, heat effects from the fire could cause the
contents of nearby storage tanks to boil.
For a fire scenario, the most significant parameters for determining off-site
consequences are the types and quantities of the chemicals ignited, and the location of the
fire. Based on a review of U.S. EPA (1995b), most fires and explosions at hazardous
waste incineration facilities have been associated with operations of the combustion
system. The more frequently reported events include steam explosions resulting from
molten slag dropping into the ash quench, and fires and explosions in the air pollution
control equipment. These incidents have not been reported to have had off-site human
health effects (U.S. EPA 1995b). Additionally, the consequences of incidents of this type
are expected to be limited by the small amount of waste present at any one time in these
locations.
A fire with greater potential for causing adverse effects in the off-site community was
recently reported at the ThermalKem hazardous waste incinerator in South Carolina (U.S.
EPA 1995b). In January 1995, almost 1,900 30-gallon fiber drums possibly containing
hazardous and nonhazardous waste caught fire and burned, causing extensive damage and
one minor injury to an on-site employee. The fire started in two ffber drums containing
nonhazardous molybdenum wastes that had been rendered reactive due to mixing with
Volume VII 11-10
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wood flour during shredding. All fire-fighting water was contained, no explosions
occurred, and no off-site releases occurred above reportable quantities.
Significantly smaller fires have been reported at the WTI facility primarih in the bulk
solid waste pits (see Table 3 of Appendix VII-1). For example, according to facilin,
records, bulk solid waste in a clamshell used to feed bulk solids into the incinerator caught
fire in February 1995. The sprinkler system was activated, extinguishing the fire within
approximately one minute. Damage reportedly was limited to the crane bucket wires.
cables and insulation in the immediate area.
WTI reported a second, similar, waste-related fire on July 3, 1995. This time, the
fire occurred in one of the two bulk solid waste pits. The automatic water deluge system
extinguished this fire quickly, and only minor damage (mostly to the loading door for the
pit) was reported. Although the exact cause of this fire is unclear, it has been
hypothesized that a burning piece of waste escaped the double doors of the incinerator
feed chute and either floated through the air back to the waste pit or was carried back to
the waste pit via the clamshell bucket. WTI has made changes to operating procedures.
equipment, and control logic in response to this event (Victorine 1995c).
Automatic fire protection systems are in place at various locations across the WTI
facility, to allow quick response to fires such as those which occurred in February and
July of 1995. A summary of the WTI fire protection systems, as reported by Von Roll
(1994), is presented in Table II-3. Details regarding the fire protection systems are
provided in Von Roll (1994).
For the WTI Accident Analysis, the conservative on-site fire event selected for
quantitative evaluation involves a storage tank rupture in the Organic Waste Tank Farm
followed by ignition. It is assumed that a 20,000-gallon tank ruptures, emptying its
contents into the diked area, which has an area of approximately 180 nr. With the pool
size defined by this diked area, the pool depth is estimated to be 0.42 m, using the
methodology outlined in Appendix VII-3. It is assumed that the waste is ignited by an
undefined source, such as a spark, generating products of combustion. The primary .
reason for selecting this indoor fire scenario is the volume of the wastes involved. The
storage tanks in the Organic Waste Tank Farm have the largest on-site storage capacity for
a single container. The quantities involved in a spill from one of these tanks, followed by
ignition, would be expected to result in a more prolonged fire than a spill from any other
on-site containers.
In the "typical" on-site scenario, a fire involving 200 gallonrof waste is assumed to
ignite outdoors on a paved area near the center of the facility, generating products of
combustion. This is approximately the equivalent of four 55-gallon drums, and roughly
Volume VII 11-11
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twice the size of a typical transportation spill for the ten-year period ending in 1994.
according to U.S. DOT (1995).
As in the on-site spill scenario, the consequences of an on-site fire are evaluated
assuming no active mitigation to limit duration of emissions. An evaluation of the impact
of active mitigation measures on the consequences of the accident scenarios described is
presented in Chapter VII.
3. On-Site Mixing of Incompatible Wastes
Wastes containing certain chemicals may react when mixed, resulting in a vaneu of
adverse consequences, including the generation of flammable or toxic gases, fires or
explosions, or heat effects. Wastes which react to produce such adverse effects are
sometimes referred to as "incompatible" wastes. The specific outcome of mixing
incompatible wastes depends upon the concentrations and volumes of the reactants, the
rate of reaction, the type of vessel in which the reaction occurs, and the presence or
absence of mitigation devices. Among these possible consequences, the generation of a
gaseous toxic reaction product (e.g., HC1 or C12) can affect the largest off-site area
because the chemicals can be carried considerable distances downwind. For example, the
release and off-site migration of toxic and corrosive fumes such as HC1, phosgene and
other gaseous halogenated compounds can occur if halogenated hydrocarbons are mixed
with mineral acids (oxidizing or nonoxidizing), amines (aliphatic or aromatic), or strong
oxidizing agents (Sax and Lewis 1989; ASTM 1986; Bretherick 1985).
Under the Resource Conservation and Recovery Act (RCRA), incompatible wastes
must be segregated, reducing the potential for accidents (40 CFR 264.172). Despite such
precautions, a few incidents that may have been caused by mixing of incompatible wastes
at commercial hazardous waste treatment facilities have been reported (U.S EPA 1995b)
At the TWI hazardous waste incinerator in Sauget, Illinois, in 1990, mixing of
incompatible wastes is believed to have caused the contents of a blending tank to boil
over, releasing a plume of chlorinated gas. No off-site effects were reported in the TSDF
incident study (U.S. EPA 1995b). At the Washington Chemical Facility in the State of
Washington, mixing of incompatible wastes in a drum reportedly caused an explosion,
propelling the drum through the air and resulting in the release of waste material. Minor
property damage occurred but no on-site or off-site injuries were reported.
Mixing of incompatible wastes is a known hazard and, due to this concern,
procedures have been established at the WTI facility to reduce the potential for such an
event to occur. For example, incompatible wastes must be segregated as required under
RCRA (40 CFR 264.172). This Accident Analysis, however, assumes that an accident or
Volume VII 11-12
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unforeseen circumstance occurs, or there is a failure to follow the established accident
prevention procedures, and incompatible wastes are thus allowed to mix. Locations where
inadvertent mixing of incompatible wastes is most likely to occur at the WTI facility are
the Truck Unloading Stations, Organic Waste Tank Farm and Container Processing
Facility (extruder, pump-out tanks). Other possible scenarios include a release of vapors
during truck sampling (if a shipper mixed incompatible wastes, thereby generating vapors
within the truck during transport) and an on-site two truck accident involving the release
of incompatible materials from the two trucks and subsequent mixing of the materials
In storage areas where separate tanks of wastes are stored under a common root tie.
Organic Waste Tank Farm and Container Processing Facility), incompatible wastes are
stored in separate areas, and permanent containment barriers are in place to reduce the
potential for mixing.of incompatible wastes in the event of a spill. Situations where
mixing of incompatible materials might occur in these storage areas would thus likely
involve the misidentification or improper storage of incompatible wastes. For example, if
two tanks having a common containment barrier were to leak, mixing of incompatible
wastes could occur, but only if the operator failed to follow the standard practice of
storing incompatible wastes in separate areas. Similarly, a misidentified waste could be
accidentally pumped into a storage vessel already containing an incompatible material.
For the WTI analysis, two possibilities for on-site mixing of incompatible wastes are
considered for quantitative evaluation:
An on-site collision between two tanker trucks, each containing 5,000 gallons of
different wastes that are incompatible, resulting in toxic gases being released to
the atmosphere.
The inadvertent addition of 5,000 gallons of waste from a tanker into a 20,000
gallon Organic Waste Tank Farm storage tank containing 5,000 gallons of an
incompatible material, resulting in an incompatible mixture and the release of
toxic gases.
Between these two events, the scenario involving inadvertent mixing in the storage tank is
selected for quantitative evaluation because it is highly unlikely that complete mixing of
incompatible wastes from two tanker trucks would occur on-site due to the low volume of
on-site traffic and the low speed restriction at the facility. Pumpmg of a potentially
incompatible waste from a tanker truck to the wrong storage vessel is representative of
accidents which could occur because of sampling/analysis uncertainty or error, operator
Volume VII 11-13
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error, or other circumstances believed to have a higher probability of occurrence than the
collision of two tanker trucks.
In addition to the conservative scenario described above, a more "typical" scenario
involving the mixing of incompatible wastes is evaluated. In the typical scenario, a total
of 200 gallons of incompatible wastes are mixed together outdoors near the center of the
WTI facility, resulting in the generation of toxic gases. The 200-gallon volume
corresponds to the approximate volume of four 55-gallon drums.
In the Accident Analysis both conservative and typical scenarios are evaluated
assuming no active mitigation, although active mitigation measures are available at the
WTI facility. A separate evaluation of the potential effect of active mitigation is assessed
and presented in Chapter VII.
4. Off-Site Tanker Truck Spill
Off-site spill scenarios involve the release of the contents, or a portion of the
contents, of a tanker truck. Collisions, which could result in the release of a majority of
the contents of the tanker in a single location, would generally be expected to have the
greatest potential for adverse consequences in the community.
The U.S. DOT maintains a database entitled Hazardous Materials Information System
(HMIS) regarding accidents during the transport of both hazardous wastes and hazardous
materials (e.g., gasoline, process chemicals). A review of data between 1984 and 1993
indicates that during that 10-year period, there were 1,959 transportation incidents
involving hazardous waste on highways in the U.S., resulting in 143 reported injuries and
one reported fatality (U.S. DOT 1995). By comparison, during the same ten year period,
there were 63,577 highway transportation incidents involving hazardous materials,
resulting in 2,781 reported injuries and 115 reported fatalities (U.S. DOT 1995).
Hazardous materials include products (such as gasoline) and feedstocks (such as chlorine
gas) as well as hazardous waste.
In the WTI Accident Analysis, the subpopulation that is most likely to be adversely
affected by an off-site accident would be individuals who live or work along the local
access route. In the East Liverpool area, trucks transporting waste to the facility are
expected to travel along Pennsylvania Avenue (Route 39), a two-lane city street that
serves as the main thoroughfare for East Liverpool. Residences and commercial
establishments are located along this portion of the route, immediately adjacent to the
roadway. Approximately one-half mile from the facility, trucks tufh to the south along
Virginia Avenue, a two-lane residential street with houses located within 20 feet of the
street. A street light and gas station are located at the intersection of Virginia and
Volume VII 11-14
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Pennsylvania Avenues. Trucks travel approximately three blocks along Virginia Avenue.
cross a set of railroad tracks, and proceed to the facility gate. A map of the local access
route is shown on a topographic map in Figure II-2. This topographic map was rendered
prior to construction of the WTI facility.
For the purposes of the WTI Accident Analysis, a spill on a local access road near the
facility is assumed for the conservative off-site spill scenario. For this scenario categor\.
a 5.000-gallon tanker is assumed to rupture, releasing its entire contents. According to
U.S. DOT data covering the period from 1971 through 1986, as shown in Table II-4.
approximately 95% of all spills involving full-size tankers were less than 5.000 gallons
(U.S. DOT 1986). Furthermore, FEMA (1993) estimates that approximately 20% of all
spills would involve loss of the entire tanker contents. The pool is assumed to spread in
all directions at an equal rate, with liquids reaching the edge of the road running off onto
soil or into a ditch. Assuming the road on which the spill occurs is flat and has no curbs
capable of acting as a containment barrier, the liquid pool is assumed to reach a maximum
length and area defined by the width of the road and a 1 cm pool depth. In reality, the
road is likely to be sloped from the center line to the sides, reducing the spill area: thus
the assumption of a non-sloped road surface is believed to be conservative and tends to
overestimate potential off-site consequences. The location assumed for the spill is shown
in Figure II-3.
In addition to a spill onto the roadway, a spill into surface water is also theoretically
possible. For example, a collision on the Route 30 Bridge might possibly lead to a spill
into the Ohio River. In the event of a spill into surface water, chemicals in the waste may
either: 1) float; 2) sink; or 3) mix with the water. The greatest potential for acute human
exposures would involve inhalation of volatilizing chemicals that are floating on, or mixed
in, the water. Other potential pathways (such as fishing or drinking water ingestion)
might represent potential longer-term exposure routes, if remediation were not
undertaken, but would be less likely than inhalation to pose an acute risk. Short-term
exposures associated with a spill into surface water will not be quantified in the Accident
Analysis because the potential resulting acute impacts are judged to be less significant than
the impacts from a spill onto the road, for the following reasons:
A spill into surface water is less likely to occur than a spill onto the roadway.
Chemical mixing with the water, or sinking below the surface of the water,
would reduce emission rates relative to a spill onto the road.
Volume VII 11-15
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Potential human receptors are likely to be closer to a spill on the roadway than to
one into surface water, and thus receive higher levels of exposure as a result of a
roadway spill.
Potential adverse ecological effects associated with a spill into surface water are not
evaluated in this analysis. Although the ecological consequences of a spill into surface
water could possibly be significant, the probability of occurrence of such an event 1?
judged to be very low based on the accident frequency data from U.S. DOT (1995) and
the relatively short distance traveled over surface water.
In the "typical" off-site accident scenario, a spill of 100 gallons is assumed. As
previously discussed, a 100 gallon spill can be considered typical based on data reported
by U.S. DOT (1995). The location of the spill is assumed to be the same in the typical
scenario as in the conservative scenario.
5. Off-Site Tanker Truck Spill with Fire
If an ignition source is present at the time of the off-site tanker truck spill described
above, a fire could occur. U.S. DOT (1995) does not identify the number of hazardous
waste or hazardous material transportation incidents involving fire. Therefore, it is not
known what percentage of the 1.959 incidents between 1984 and 1993 involved fire
In the WTI Accident Analysis, 5.000 and 100-gallon spills are considered for the
conservative and typical off-site spill with fire scenarios, respectively. The rationale for
selecting these volumes is the same as the rationale for the volumes used in the off-site
spill scenarios. Emissions were assumed to consist of the same types of products of
combustion and incomplete combustion as those evaluated in the on-site fire scenario.
As in the off-site spill scenario, no mitigation or emergency response is assumed
which could limit emissions.
D. Summary of Results and Key Assumptions
As shown on Table II-5, the scenarios selected for quantitative evaluation in the Accident
Analysis are an on-site spill, an on-site fire, on-site mixing of incompatible wastes, an off-site
spill and an off-site fire.
Major assumptions made in the identification of accident scenarios are summarized in
Table II-6.
Volume VII II-16
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TABLE II-l
Partial List of Passive Mitigation Features at the WTI FacUity1
Source
Organic waste reception tanks
Organic waste holding tanks
Organic waste sludge tanks
Organic waste blending tanks
Tank truck unloading stations
Truck unloading docks - Drum Processing
Building.
Container holding rooms or areas
Container processing areas -
Drum Extruder Area
Drum pumpout tank
Drum staging area
Short-term containerized staging areas
Scrubber water holding tanks
Exterior truck wash
Storm water tanks
Caustic tank
Scrubber
Fuel oil tank
Diesel generator day-tank
Fire pump No. 1 day-tank
Fire pump No 2 day-tank
Type of Containment or
Diversionar\ Structures
Contoured surfaces and reinforced concrete dikes and sump^
Contoured surfaces and reinforced concrete dikes and .sumps
Contoured surfaces and reinforced concrete dikes and sumps
Contoured surfaces and reinforced concrete dikes and sumps
Contoured surfaces, speed humps, curbs, building ualK
reinforced concrete and sumps
Contoured surfaces, speed bumps, curbs, building walls and
reinforced concrete drainage trenches and sump
Contoured surfaces and reinforced concrete dikes and sumps
Contoured surfaces and reinforced concrete dikes and sumps
Contoured surfaces and reinforced concrete dikes and sumps
Reinforced concrete dikes and sumps
Contoured surfaces and reinforced concrete curbs and sumps
Contoured surfaces and reinforced concrete curbs and sump
Contoured surfaces and reinforced concrete dikes and sump
Contoured surfaces and reinforced concrete curbs and sump
Contoured surfaces and reinforced concrete dikes and sumps
Contoured surfaces and reinforced concrete dikes and sump
Contoured surfaces and reinforced concrete dikes and sump
Contoured surfaces and reinforced concrete dikes and sumps
Conioured surfaces and reinforced concrete sump
Reinforced concrete dike
Reinforced concrete dike
Note.
1 Source WTI 1992.
Volume VII
11-17
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TABLE II-2
Preliminary List of Potential Accident Events at WTI
Location
Accident Events
Assumptions/Considerations
Off-site Transportation
Tanker/Drum Truck
Spill onto roadway (evaporation)
Spill onto roadway (fire)
Spill into Ohio River
Transportation routes within a 5-mile radius of WTI
facility will he evaluated
River barge not considered as a transport option
Tank truck volume assumed to he 5,000 gallons
Trailer truck capacity assumed to he 80 55-gallon
drums
Transported wastes arc similar to WTI waste profile
for first year of operation
Truck Holding and Sampling Area
Tanker truck rupture (evaporation)
Tanker truck rupture (fire)
Incompatible wastes in tanker (vapor release upon
opening) .
60' X96' (60 ft hy 96 It) area
Tank truck volume assumed to he 5,000 gallons
6" (6 inch) curhs and speed humps (connected) and
paved surface sloped toward a reinforced concrete
sump. Containment capacity is 31,000 gallons.
Truck Unloading Stations (drum and hulk)
Drum Scenarios
Spill Irom pallet of drums during transfer
(evaporation)
'1 ruck ol drums catches fire
Spill of truck load of drums
Release Irom leaking drums within trailer
Bulk Pumpahle Scenarios
Spill from tanker truck (evaporation)
Spill from tanker truck (fire)
I;ailure ol transfer lines/hoses
Overflow due to improper unloading
Mixing ol incompatible wastes
Collision of trucks
Release ol combined contents of truck and
tank due to siphoning
Solids Scenarios
60' x75' area
A combination of 71/?" high speed humps, 8" high
curbs, and building walls surround each of three
unloading stations. Paved surface in each unloading
station sloped toward concrete sump. Containment
capacity in each unloading station is 10,000 gallons
Volume VII
11-18
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TABLE 11-2 (continued)
Preliminary List of Potential Accident Events at WTI
Location
Accident Events
Assumptions/Considerations
Organic Waste Tank Farm
Tank spill (multiple/single)
Fire (multiple/single)
Fire with boil-off
Ventilation fan failure
Mixing of incompatible wastes
52'x 162' area
Storage capacity is 300,000 gallons
Tank farm divided into two groups of tanks by a
reinforced concrete aisle, which acts as a common
containment curb. Entire combined containment area
surrounded by an exterior dike wall; surface in each
containment area sloped toward two concrete sumps.
Capacity of each containment area is 21,500 gallons.
Drum/Container Storage Area
(Container Processing Facility)
Multiple drum spill
I ire (maximum number of drums)
Ventilation fan failure
100'x210' area
Storage capacity ol entire Container Processing
Facility is 500,000 gallons
Storage area divided into two areas by a reinforced
concrete aisle, which acts as a common containment
curb. The entire combined containment area is
surrounded on three sides by an exterior wall and on
the fourth side by a curbed fire wall with three doors
having I'/i" high speed bumps The sutface in each
containment area is sloped toward a concrete sump.
Capacity of each containment area is 20,000 gallons.
Volume VII
11-19
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TABLE II-2 (continued)
Preliminary List of Potential Accident Events at WTI
Location
Drum Processing/Extruder
(Container Processing Facility)
Incinerator Feed Building
Incinerator. Train (e g , kiln, secondary
combustion chamber |SCC], air pollution
control equipment)
Accident Events
Drum Processing
Drum spill
Vapor release
Transfer line failure
Ventilation fan failure
Extruder
Drum spill
-- Mixing ol incompatible wastes
Explosion in hydropulper
Pump-Out Tanks
Mixing ot incompatible wastes
Fire in containerized waste area
Fire in feed chute
Explosion in kiln
Steam explosion in quench water
Release due to power failure
Failure of air pollution control equipment
Acid gas release
Non-combusted waste release
Particulates release
Boiler explosion
Failure of ID fan
Assumptions/Considerations
100' x237' area
Storage capacity of entire Container Processing
Facility is 500,000 gallons
Drum processing area surrounded by 6" high concrete
curb with I1/?" high speed bumps at the three interior
doors to the storage area and at the unloading
platform. All other exterior doors for the area have
either a 6" high concrete sill or speed bump The
floor is sloped towards three concrete sumps.
Containment capacity is 50,000 gallons
Drum extruder area surrounded by a 6" high concrete
curb. The floor is sloped toward a concrete sump.
Containment capacity is 9,000 gallons.
Outdoor tanks area contains three pump-out tanks and
one sludge reception tank. The capacity ol the
pumpout tanks is 2,500 gallons; the capacity of (he
sludge reception tank is 7, (XX) gallons. Area
surrounded by a 16" high concrete containment wall
Surface is sloped toward a concrete sump.
Containment capacity is 1 1,(XX) gallons.
Total containment capacity is 70,0(X) gallons.
61' x 55' area
Stores approximately 500 cubic yards of bulk solids
6" curb and/or speed humps run along (he outer edge
of the incinerator area that is not bordered by the Feed
Building, the Steam Plant Building, the Scrubber
Building, and the Caustic Tank Containment walls
Paved surfaces inside the curbs are sloped toward
cither the incinerator train storm wilier sump, the
spray dryer sump, or (he slag quench lank sump
Containment capacity is 176, (X)0 gallons
Volume VII
II-20
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TABLE H-2 (continued)
Preliminary List of Potential Accident Events at WTI
Location
Sieam Plant Building
Wastewater Treatment Building and
Collection Tank Area
Analytical Lab
Accident Events
Explosion
Release of wastewater
Vapor release
Fire
Release from lah (.ollcLtinii lank
Assumptions/Considerations
50' x 80' area
No hazardous materials released.
35' x48' building with 46.5' X202' collection tank
area (5 tanks)
Tanks are surrounded by a 6' 8" high concrete
cbntainment wall. An intermediate concrete wall 3"
lower than the surrounding walls separates the tanks
into two groups. Total containment capacity is
290,000 gallons.
Located within 100' X120' Administration Building
Volume VII
11-21
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TABLE II-3
WTI Fire Protection Systems
Facility Area
Administration
Laboratory
Maintenance Building
Steam Plant
Utility Bridge
Incinerator Feed Building
Container Holding Area
Truck Holding Area
Fire Water Pump House
Organic Waste Tank Farm
Foam Pump House
Truck Wash
Container Processing Building
Truck Unloading
Rack Storage Building
Fire Protection System
Wet System
Wet Svstem and Halon 1301 Svstem
Wet Svstem
Wet Svste-m
Water Deluge
Water Deluge
Dry System
Water Deluge
Wet Svstem
Foam Deluge
Foam Deluge
Dry Svstem
Foam Deluge
Foam Deluge
Foam Deluge
Source- Von Roll (1994)
Volume VII
11-22
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TABLE 11-4
Distribution of Cargo Losses from Full Size Tankers
During Highway Transit in the U.S. from 1971 to October 1986
Size of Spill
(gallons)
i
10
20
40
60
100
400
700
3,000
5,000
8,000
15,000
Number of Incidents Less Than
or Equal to Size of Spill
452
2,937
4.378
6.017
7.340
8,695
10,966
11,517
13,097
13.740
14.247
14.475
Cumulative Frequency of
Spill
00?
020
0 30
042
051
0.60
0.75
0.80
090
095
098
1 00
Source USDOT. 1986
Volume VII
11-23
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TABLE II-5
Scenarios Selected for Quantitative Evaluation
Scenario
On-Site Spill
On-Site Fire
On-Site Mixing of Incompatible Wastes
Off-Site Spill
Off-Site Fire
Description
Conservative (i.e., larger volume) Event
5,000 gallon spill due to a tanker truck accident, resulting
in volatile emissions
20,000 gallon spill in the Organic Waste Tank Farm
ignites, generating toxic products of combustion
Accidental pumping of 5,000 gallon of wastes from a
tanker truck to a storage vessel containing 5,000 gallons of
an incompatible waste, generating toxic gases
5,000 gallon spill along local access road, resulting in
volaiile emissions
5,000 gallon spill ignites, generating toxic products of
combustion-
Typical (i.e., smaller volume) Event
100 gallon spill due to tanker truck accident,
resulting in volatile emissions
200 gallon spill ignites, generating toxic products of
combustion
200 gallons of incompatible wastes are mixed,
generating toxic gases
100 gallon spill along local access road, resulting in
volatile emissions
100 gallon spill ignites, generating toxic products ol
combustion
Volume VII
11-24
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TABLE 11-6
Key Assumptions Made in the Identification of Accident Scenarios
Assumption
1 . Waste will continue to he received at the facility
by truck only.
2. For off-site spill and fire scenarios, assumed
conservative spill size of 5, (XX) gallon, typical
spill size of 100 gallon
3 For the mixing of incompatible waste scenarios,
assumed 10, (XX) gallon ol waste for the
conservative scenario, 2(X) gallon of waste for
the typical scenario
4 For on-site fire scenario, assumed 20, (XX) gallon
of waste for conservative scenario; 200 gallon
(>! waste of typical scenario
5. Typical spill sizes associated with on-site
accidents are comparable to the typical spill
sizes reported by U.S DOT for off-site
accidents.
6 Off-site spills into surface water not expected to
pose significant human health risks, and thus not
quantitatively evaluated.
Basis
There are currently no proposals to U.S. F,PA
to transport waste to WTI via rail or barge
Accidents that could be associated with rail or
large transport, if they were to occur in the
future, are not evaluated
Based on USDOT (1995) data, 95% of all
spills are less than 5,000 gallon, and 50% of
all spills are less than 100 gallon
Conservative scenario volumes based on tank
truck and storage vessel capacities. Typical
scenario based on assumed spill from multiple
drums (lour)
Conservative scenario based on storage vessel
capacities 1 ypical scenario based on
assumed spill from multiple drums (four)
Some failures which may lead to spills are
relevant to both on-site and off-site scenarios
Limited data from spills at WTI suggest that
the assumption made in the Accident Analysis
is conservative, however.
Off-site spills onto the roadway more likely to
occur, and more likely to affect the off-site
community, than spills into surface water.
Magnitude of Effect
i.OW
Medium
Medium
Medium
Medium
Low
Direction of Effect
Unknown
Conservative spill size likely
to overestimate, typical spill
size may over- or under-
estimate
Conservative scenario likely
to overestimate, typical
scenario may over- or under-
estimate
Conservative scenario likely
to overestimate, typical
scenario may over- or under-
estimate
Overestimate
Underestimate
Volume VII
11-25
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Volume VII
LOCAL ACCESS ROUTE FROM EAST
LIVERPOOL TO THE WTI FACILITY
11-27
FIGURE
11-2
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Volume VII
LOCATION FOR THE OFF-SITE SPILL
11-28
FIGURE
11-3
-------
III. CHEMICALS OF POTENTIAL CONCERN
A. Methodology
In addition to developing a list of candidate accident scenarios for consideration, the types
of waste that may be involved in each accident scenario and the specific chemicals released
into the environment must be identified. Specific chemicals to evaluate quantitatively in each
scenario in the WTI Accident Analysis are selected according to the following procedure:
Development of a preliminary list of acutely hazardous substances that may be
expected to be handled at the WTI facility.
Identification of chemicals of potential concern from the preliminary list of acutely
hazardous substances, including an initial screening of chemicals based on availability
of U.S. EPA or NIOSH acute toxicity criteria (FEMA 1993) and a subsequent
ranking of chemicals according to: 1) acute toxicity; 2) acute toxicity and volatility;
and 3) acute toxicity, volatility, and estimated maximum concentration in waste.
Acute toxicity criteria are used because they apply to the evaluation of short-term
(e.g., less than 1-day) exposures, which are the focus of hazards analysis (U.S. EPA
1987).
Selection of specific chemicals to be used in evaluating each accident event, based on
the type of scenario and the chemical ranking.
These steps are described below.
B. Preliminary Identification of Chemicals of Potential Concern
Several sources of information have been used to compile a preliminary list of wastes and
chemicals of potential concern:
,»"
Projected waste composition based on Waste Profiles from WTI.
Volume VII III-l
-------
Acutely hazardous wastes (i.e., "P" list hazardous wastes) as defined under Subpart D
of 40 CFR 260, Hazardous Waste Management System: General [40 CFR
§261.33(e)]; WTI has applied for acceptance of "P" wastes, but this request has not
yet been granted by U.S. EPA.
Chemicals regulated under Section 112(r) of the Clean Air Act (CAA) as toxic or
flammable substances that could be involved in an accidental release (59 FR 4 ?7S)
Chemicals listed as Extremely Hazardous Substances (EHSs) under Section 302 of
EPCRA.
The preliminary list of acutely hazardous substances consists of 309 chemicals. From this
list, a subset of 139 chemicals are identified which pose the greatest off-site risks in the event
of an accidental release. The chemicals selected for further analysis are presented in
Table III-l. Chemicals eliminated from further analysis are shown in Table 1 of
Appendix VII-2.
A key factor in evaluating the consequences of accidental releases is the acute toxicity
criterion. The acute toxicity criterion is used in determining the area potentially affected by a
vapor cloud resulting from an accidental release of hazardous material. The potentially
affected area is defined as the area over which the concentration of substance in the air exceeds
the selected acute toxicity criterion.
The acute toxicity criterion must be selected based on the objectives of the hazard or
consequence assessment. For example, if the objective of the hazard assessment is to
determine the area where fatalities are most likely to occur, then the acute criterion used in the
assessment should be based on the lethal concentrations. Conversely, if the purpose is to
assess irritation or odor detection, the criterion used must reflect a concentration where
irritation or odor detection is likely to occur.
The purpose of the WTI Accident Analysis is to determine the areas where, if an
accidental release were to occur, serious irreversible health effects are possible. This type of
evaluation is often conducted for emergency preparedness and planning activities, and is nearly
identical to the hazard assessment required for risk management programs under Clean Air Act
(CAA) Section 112(r). Note, however, that the results of this evaluation cannot be used to
confidently predict health effects during an actual accidental release because weather,
atmospheric dispersion and human exposure conditions may be much different than those
assumed in the Accident Analysis. The uncertainties associated with this Accident Analysis
are discussed in Chapter VII.
Volume VII III-2
-------
In the Accident Analysis, Immediately Dangerous to Life or Health (IDLH) values
established by the National Institute for Occupational Safety and Health (NIOSH) are used as
the acute toxicity criteria to develop an initial ranking of the chemicals in Table III-l. IDLH
values are defined by NIOSH as the maximum airborne contaminant concentrations from
which an individual could escape within 30 minutes without any escape-impairing symptoms or
any irreversible health effects (FEMA 1993). This definition is consistent with the purpose of
the Accident Analysis. Although the IDLH is primarily used for selection of occupational
respiratory protection levels, the IDLH values represent a consistent, relatively comprehensive
set of criteria that can be used to estimate the areas in an accidental release situation where
people may be potentially exposed to harmful concentrations of hazardous substances The
IDLH values used in the Accident Analysis can be found in U.S. EPA (1995c). For chemicals
without IDLH values, rankings in Table III-l are based on Level of Concern (LOO values
developed by U.S. EPA under the Emergency and Community Right to Know Act of 1986
(EPCRA).
To assist in selecting chemicals from Table III-l to evaluate quantitatively in each accident
event, chemicals are ranked according to the following criteria:
Acute toxicity. as represented by IDLH value:
t = IDLH
This ranking identifies chemicals of greatest concern with respect to toxicity
only. Chemicals with low IDLHs (and thus low values of R}) are the most highly
ranked. For chemicals without IDLH values, but for which U.S. EPA has
established an LOC, the LOC multiplied by a factor of 10 is used in ranking
according to acute toxicity.
Acute toxicitv and volatility. Chemicals are ranked as follows:
IDLH
VP
where VP represents the vapor pressure of the chemical. This ranking considers
both the acute toxicity and release potential (for example, in the event of an on-
Volume VII III-3
-------
site or off-site spill). Chemicals with a combination of a low IDLH value and
high volatility would have the lowest R2 values, and thus be the most highly
ranked.
Acute toxicitv. volatility and concentration. Chemicals are ranked as follows:
IDLH
where C represents the concentration reported in waste streams expected to be
received at the WTI facility. Specifically, the concentration is calculated for each
chemical where data are available as the average of the maximum concentrations
reported for individual waste streams containing that chemical. Chemicals with a
combination of a low IDLH value, high volatility, and high concentrations in
waste would have the lowest /?3 values, and thus be the most highly ranked.
Concentrations, expressed as a percent composition, are estimated from
information provided in waste profiles from WTI's first year of operation (see
Volume III, Appendix III-l). It should be noted that concentration data are
available for only a relatively limited number of possible chemicals of concern
The acute toxiciry values, vapor pressure data and concentration data used in ranking each
chemical are presented in Table III-l. The results of the rankings are presented in Table 2
of Appendix VII-2.
C. Selection of Specific Chemicals for Each Accident Event
1. On-Site Spill
Two chemicals, formaldehyde and acetone, are selected for evaluation in the on-site
spill scenario. Formaldehyde is selected as a "worst-case" chemical for evaluating spills
of a conservative waste; acetone is selected as a "typical" chemical for evaluating more
typical waste spills.
In the spill scenario, the combined ranking of acute toxicity, volatility and
concentration is most significant, because it considers both the toxicity of the chemical and
the potential magnitude of exposure. Of all chemicals of potential concern, formaldehyde
is the second most highly ranked chemical on the basis of acute toxicity, volatility and
Volume VII III-4
-------
concentration combined. The most highly ranked chemical was hydrogen chloride (HC1).
largely because of the extremely high vapor pressure of pure phase HC1 (31.000 mm Hg
at 20°C). However, HC1 would not be expected to be received in significant
concentrations, except in aqueous mixtures, where its vapor pressure is greatly reduced.
For example, according to Perry and Green (1984) the vapor pressure of HC1 in a 20£
aqueous solution is only 0.2 mm Hg at 20°C. (The concentration of HC1 used in the
ranking is 18%). While the vapor pressure of formaldehyde is also greatly reduced in an
aqueous solution (Gallant 1968), formaldehyde may also be present in an organic solution.
While formaldehyde ranks approximately 35th out of 133 chemicals of potential
concern based on acute toxicity alone, it ranks 7th out of 108 chemicals according to acute
toxicity and volatility combined. The 6 chemicals ranked more highly than formaldehyde
on the basis of toxicity and vapor pressure (i.e., arsine, diborane, nitrogen oxide.
hydrogen chloride, chlorine and hydrogen selenide) usually exist in gaseous form and are.
therefore, highly unlikely to be present at high concentrations in large quantities of liquid
waste. Thus, on the basis of toxicity and volatility alone, formaldehyde would also be
appropriate as a "worst-case" chemical for modeling in the spill scenario.
It should be recognized, however, that formaldehyde is a relatively minor constituent
in the overall waste feed at the WTI facility Based on waste profiles for the first year of
WTI operations, the ten constituents estimated as being received in the largest quantities in
pumpable waste at the WTI facility are listed in Table III-2. According to the waste
profile data for the first nine months of operation at the WTI facility, approximately
100,000 Ib/yr of formaldehyde were estimated to be received, constituting approximately
0.5% of the pumpable waste at the WTI facility. As shown in Table 2 of Appendix VII-2.
of the ten chemicals reported in the largest quantities in the liquid waste, acetone is ranked
highest on the basis of both: 1) acute toxicity and volatility; and 2) acute toxicity,
volatility and concentration. Overall, on the basis of acute toxicity, volatility and
concentration, acetone ranks 9th of the 47 chemicals of potential concern for which data
on acute toxicity, volatility, and concentration are available. Thus, acetone was selected
as a "typical" constituent for evaluating the spill scenarios.
A mixture containing 10% formaldehyde was selected as a reasonable "worst-case"
waste for spill scenarios. This is approximately equal to the combined average of the
maximum (i.e., highest) concentrations reported for individual waste streams containing
formaldehyde. For the purpose of modeling formaldehyde emissions, the remaining 90%
of the waste is assumed to be methanol. a chemical in which formaldehyde is soluble, and
which is projected to be received in high quantities at the WTI facility (see Table III-2).
Methanol is selected only to provide representative waste mixture properties for estimating
Volume VII III-5
-------
formaldehyde emissions: in reality, wastes are typically composed of many individual
chemicals. The selection of methanol is relatively conservative, i.e.. more likely to
overestimate than underestimate formaldehyde emissions. For example, the formaldehyde
emission rate from a 10% formaldehyde/90% toluene mixture would be lower than from a
10% formaldehyde/90% methanol mixture because the vapor pressure of the
formaldehyde/toluene mixture is lower than the formaldehyde/methanol mixture
Formaldehyde emissions from a more complex waste mixture with physical chemical
properties similar to methanol would be approximately the same as assuming a 10%
formaldehyde/90% methanol mixture.
A mixture containing 10% acetone was selected as a reasonable "typical" waste for
spill scenarios. A concentration of 10% is approximately equal to the combined average
of the mean concentrations of acetone reported for individual waste streams containing
acetone. The remainder of the waste stream was assumed to consist of toluene to estimate
waste mixture properties for the purposes of predicting acetone emission rates. Like
methanol, toluene has been reported to be received in high quantities in the pumpable
wastes (See Table III-2). The selection of other commonly received chemicals from Table
III-2 to determine waste mixture properties would not substantially affect acetone emission
rates.
In evaluating the on-site spill scenario, four cases are examined:
Conservative spill (5.000 gallons) of a worst-case waste (10% formaldehyde in
methanol).
Conservative spill (5.000 gallons) of a typical waste (10% acetone in toluene).
Typical spill (100 gallons) of a worst-case waste (10% formaldehyde in
methanol).
Typical spill (100 gallons) of a typical waste (10% acetone in toluene-like
chemicals).
These events were developed to bracket the types of credible on-site spills at the WTI
facility.
Volume VII III-6
-------
2. On-Site Fire
Typical combustion products generated by a waste fire include CO,. NOX. and SO,.
If chlorinated wastes are involved in the fire, combustion products may also include HC1
and phosgene. Due primarily to their acute toxicity, phosgene and HC1 were selected as
the chemicals to be modeled in the on-site fire scenario.
On the basis of acute toxicity alone, phosgene is one of the most highly ranked
chemicals listed in Table II1-1 (tied for 18th of 133 chemicals). The 17 chemicals ranked
more highly than phosgene are not expected to be significant combustion products
However, based on O'Mara et al. (1971) and Sjoberg (1952), phosgene emissions \\ould
be expected to be at least 20-fold lower than HC1 emissions when common chlorinated
compounds are burned. Based on Sjoberg (1952), higher emissions of phosgene relative
to HC1 are possible, but only at thermal decomposition temperatures well below those
expected in an open fire. Thus, HC1, which ranked 65th of 133 chemicals on the basis of
acute toxicity, is also assessed.
Phosgene and HC1 may be produced when various chlorinated wastes are burned
Sjoberg (1952) measured the amount of HC1 and phosgene formed when seven different
chlorinated substances were placed in contact with an open flame. Of the chemicals listed
on Table III-3, four (carbon tetrachloride, chloroform, tetrachloroethene and
trichloroethene) are among the 50 chemicals received in pumpable wastes in the highest
quantities, according to waste profile sheets from the first year of operation. Each of the
four are estimated to represent approximately 0.5% of the pumpable waste. Furthermore,
the concentrations of each of the four chemicals in individual waste streams are also
similar (see Table III-l). Since the quantities and concentrations of the four chemicals are
comparable, tetrachloroethene was selected to quantitatively evaluate the fire scenario
based on its relatively high formation rates for both phosgene and HC1.
According to the waste profiles estimated for the first year of operation, the average
of the maximum tetrachloroethene concentrations reported for individual waste streams
containing tetrachloroethene is approximately 15%. Thus, a waste consisting of 15%
tetrachloroethene was assumed for the fire scenarios. The remainder of the waste was
assumed to be toluene, a highly flammable chemical projected to be received in large
quantities in pumpable waste at the WTI facility.
in the Repon on the USEPA Technical Workshop on WTI Incinerator Risk Assessment
Issues (U.S. EPA 1996b), it was suggested that emissions of uncombusted residues from
waste constituents that are not completely destroyed in the fire may pose a greater risk
than chemicals that are created by the fire (such as HC1 and phosgene). Therefore, an
alternative approach is employed to examine emissions of waste constituents that are not
Volume VII III-7
-------
completely destroyed in the fire. A range of destruction efficiency (DE) values for open
burning of the waste are assumed to predict emission rates for residuals of uncombusted
organics in the waste. Emissions of "typical" and "worst case" waste constituents are
estimated assuming DE values of 90 % and 99 %, reflecting the extent of combustion that
might be expected in an open fire. "Typical" waste is defined to consist of the top five
specific compounds received in largest quantities in pumpable waste, according to the
WTI waste profile data for the first nine months of operation. "Worst case" waste is
defined to consist of the ten compounds ranked most highly based on both acute toxicity
and projected volume received at the WTI facility, in quantities proportional to the
reported quantities in the profile data. A detailed evaluation of the expanded waste fire
scenarios is presented in Volume VIII.
3. On-Site Mixing of Incompatible Wastes
ASTM (1986) has proposed guidelines for estimating the incompatibility of selected
hazardous wastes. The ASTM guidelines, which provide a systematic method for
determining the incompatibility of most binary combinations of hazardous wastes, were
consulted in selecting a mixing of incompatible wastes event involving chlorinated
hydrocarbons.
In the Accident Analysis, HC1 is selected to evaluate emissions generated by mixing
incompatible wastes. A review of various hazardous chemical handbooks (Bretherick
1985; Sax and Lewis 1989). indicates that HC1 is the chlorinated chemical most likely to
be generated by the mixing of incompatible wastes; furthermore. HC1 is more highly
ranked on the basis of toxicity and volatility than other gases that may be produced, such
as chlorine. According to ASTM (1986). HC1 formation can occur when chlorinated
hydrocarbons are mixed with mineral acids (oxidizing or nonoxidizing) or strong
oxidizing agents.
For this event, HC1 is assumed to be emitted when tetrachloroethene (a hydrocarbon
with high chlorine content that is reportedly received at the WTI facility) is mixed with a
70% nitric acid solution (an oxidizing mineral acid). The organic waste stream is
estimated to contain 15% tetrachloroethene, based on projected estimates from the first
year of operation at the WTI facility. The selection of tetrachloroethene is reasonably
conservative, i.e., is more likely to overestimate than underestimate HC1 emissions,
because of its high chlorine content relative to other common chlorinated hydrocarbons,
e.g., dichloroethene, trichloroethene and trichloroethane. In the 1993 Toxic Release
Inventory, nitric acid is listed among the top ten chemicals managed via off-site waste
treatment, including incineration (USEPA 1995d), and thus can reasonably be assumed to
Volume VII III-8
-------
be among the wastes to be received by WTI. Sulfuric acid, which is also listed among the
top ten chemicals in the 1993 Toxic Release Inventory, could be used in place of nitric
acid in evaluating this accident scenario. Using sulfuric acid would not affect the results
of the Accident Analysis, however, since the HC1 release is calculated based on the
amount of chlorine available in the tetrachloroethene solution.
4. Off-Site Tanker Truck Spill
As in the on-site spill scenario, mixtures of 10% formaldehyde/90% methanol and
10% acetone/90% toluene are both evaluated in the off-site spill scenario. The basis for
these selections is the same as for the on-site spill scenario, since the critical chemical-
specific factors affecting exposure and the potential for acute adverse health effects are
identical.
5. Off-Site Tanker Truck Spill with Fire
Phosgene and HC1 are selected for evaluation of the off-site tanker truck spill with
fire. The rationale for selection of phosgene and HC1 for the off-site fire scenario is the
same as for the on-site fire scenario. As in the on-site fire scenario, the type of waste
selected for evaluation is a mixture of 15% tetrachloroethene and 85% toluene.
At the suggestion of the Peer Review Panel (U.S. EPA 1996b), emissions of
uncombusted residues from waste constituents that are not completely destroyed in the off-
site fire are also evaluated in Volume VIII. Emissions of "typical" and "worst case"
waste constituents are estimated assuming DE values of 90% and 99%, reflecting the
extent of combustion that might be expected in a fire. The compounds defined for the
"worst case" and "typical" waste mixtures are the same as those used for the on-site fire
scenario, and are listed in Volume VIII.
D. Selection of Acute Toxicity Criteria
As previously discussed in this chapter. IDLH values were used in a ranking system to
identify chemicals of potential concern. Alternative criteria for evaluating acute exposures
include LOG and ERPG values. The types of health effects that could theoretically occur if
IDLH, LOG or ERPG values are exceeded are summarized below:
ERPG-1: possibility of mild, transient health effects or odors
LOG, ERPG-2: possibility of serious, irreversible health effects/-
IDLH, ERPG-3: possibility of life-threatening health effects
Volume VII III-9
-------
Consistent with U.S. EPA (1987) and FEMA (1993) guidance, the focus of the Accident
Analysis is on the potential for serious or life-threatening injuries in the off-site community
during operation of the WTI facility. Thus, ERPG-2. ERPG-3. LOG. and IDLH values were
considered for the consequence evaluation in the Accident Analysis.
Table III-4 presents available IDLH, LOG, ERPG-2 and ERPG-3 values for the chemicals
of potential concern selected for quantitative evaluation in the Accident Analysis. A direct
comparison of IDLH, LOG, and ERPG values is not possible, since the IDLH values are
based on 30-minute exposures, and ERPG and LOG values are based on 60-minute exposures
However, some general trends are apparent from Table III-4. and are supported by a broader
review of available IDLH, LOG, and ERPG values for chemicals projected to be received at
the WTI facility:
LOG values are generally lower (i.e., more stringent) than ERPG-2, ERPG-3. or
IDLH values.
ERPG-2 values are generally higher (i.e., less stringent) than the LOG values, but
lower (i.e., more stringent) than either the IDLH or ERPG-3 values.
Depending on the chemical, either the IDLH or ERPG-3 value is the highest (i.e..
least stringent) of the acute toxicity criteria.
In the Accident Analysis, LOG and IDLH values were selected to evaluate severity of
consequence. As indicated above, the LOG and IDLH values effectively bracket the
concentration ranges above which potentially serious or life-threatening health effects might be
expected to occur in some individuals within the general population. Furthermore. ERPG
values are not available for many substances projected to be received at the WTI facility.
As discussed in U.S. EPA (1987), LOG values are generally lower (more stringent) than
IDLH values because 1) the IDLH does not explicitly take into account the possible exposure
of more sensitive individuals in the general population, and 2) the IDLH is based upon a
maximum 30-minute exposure period, while the LOG takes into consideration that some .
exposures to accidental releases may persist for a longer period of time. Thus, severity of
consequence was evaluated separately using both IDLH and LOG values.
E. Summary of Results and Key Assumptions
The wastes and chemicals selected to be evaluated for the accident scenarios are
summarized in Table III-5.
Major assumptions made in selecting the chemicals to be quantitatively evaluated in the
Accident Analysis are summarized in Table III-6.
Volume VII III-10
-------
TABLE III-l
Summary of Chemicals of Potential Concern for Short-Term Exposures3
CAS
Number1
107-20-0
640-19-7
62-74-8
67-64-1
107-2-8
107 13 1
116-6-3
309-0-2
107 18-6
20859 73-8
2763 96-4
504 24-5
7664-41-7
62 53-3
50661-6
1327-53-3
1303 28-2
7784-34-1
7784-42-1
71-43-2
108 98-5
100-44-7
71 36-3
Substance
Acetaldehyde, chloro-
Acetamide, 2-fluoro-
Acetic acid, fluoro-, sodium sail
Acetone
Acrolein
Acrylonitrile
Aldicarh
Aldrin
Allyl alcohol
Aluminum phosphide
Aminomethyl-3-isoxazolol, 5-
Aminopyridine, 4-
Ammonia
Aniline
Argentate(l), bis(cyano-C)-, potassium
Arsenic oxide
Arsenic pentoxide
Arsenous trichloride
Arsine
Benzene
Benzenethiol
Benzyl chloride
Butanol
Basis2
B
B
B
A
B,C, D
A, C, D
B, D
B, D
B, C, D
B, D
B
B
C
A, D
B
B
B, D
C
C
A
B
B, D
A
IDLH3
(g/m3)
0.1442
0.058
0.0025
5.9
0.0046
0.1842
0.003
0.025
0.0474
0.2
0.17
0.2
0.2082
0.38
0.2
0.014
0.08
0.012
0.0095
1.59
0.014
0.005
4.234
Vapor Pressure4
(mm Hg @20°C)
100
NA
NA
180
220
83
00001 (25 °C)
0000075
17
NA
NA
000037 (25 °C)
6500
0.6
NA
NA
NA
10(23 5°C)
I1000(21°C)
75
2 (25"C)
1
6
Conservative
Percent
Composition5
NA
NA
NA
21
NA
3
NA
NA
NA
NA
NA
NA
NA
7
NA
NA
NA
NA
NA
7
NA
NA
19
Volume VII
III 1
-------
TABLE III-l (continued)
Summary of Chemicals of Potential Concern for Short-Term Exposures"
CAS
Number1
75-15-0
56-23-5
57-74-9
7782-50-5
10049-4-4
67-66-3
542-88-1
5344-82-1
542-76-7
8001-58-9
95-48-7
4170-30-3
98-82-8
506-77-4
1 10-82-7
108-94-1
19287-45-7
95-50-1
541-73-1
106-46-7
696-28-6
84-66-2
297-97-2
Substance
Carbon disulfide
Carbon tetrachloride
Chlordane
Chlorine
Chlorine dioxide
Chloroform
his-Chloroinethyl ether
1 -(o-ChUirophenyl)lhiourea
Chloropropionitrile, 3-
Creosoie (coal tar)
Cresol, 2-
Crotonaldehyde
Cumene
Cyanogen chloride
Cyclohexane
Cyclohexanone
Dihorane
Dichlorobenzene, 1,2-
Didilorobenzene, 1,3-
Didilorobenzene, 1 ,4-
Dichlorophenylarsine
Diethylphthalate
Diethyl O-pyrazinyl phosphorothioate, 0,O-
,_ Basis2
A, B, C, D
A
D
C
C
A, C, D
C
B
B
A
A, I)
A, C, D
A
B, C
A
A
C
A
A
A
13
A
B
IDLH3
(g/m3)
1.553
1.256
0.5,
0.0289
0.0138
2.437
0.0025
0.046
0.09
NA
1.104
0.143
4.416
3.6
4.468
2.806
0.017
1.2
NA
0.9
04
NA
0.035
Vapor Pressure4
Jmm Hg @20°C)
300
91
000001
5200
760
160
30 (22°C)
NA
5 (46°C)
NA
0 31 (25 °C)
19
8
1010
78
5
30000 (17°C)
1
2.3 (25°C)
1.3
0.087 (25 °C)
0.00165 (25 V)
0 003 (30"C)
Conservative
Percent
Composition'
19
17
3
NA
NA
8
NA
NA
NA
8
20
3
8
NA
13
19
NA
19
11
4
NA
3
NA
Volume VII
111-12
-------
TABLE III-l (continued)
Summary of Chemicals of Potential Concern for Short-Term Exposures"
CAS
Number1
55-91-4
60-51-5
540-73-8
77-78-1
534-52-1
88-85-7
123-91-1
152-16-9
107-49-3
298-4-4
541-53-7
1 15-29-7
72-20-8
106-89-8
16752-77-5
,64-17-5
1 10-80-5
140-88-5
100-41-4
151-56-4
82-41-4
640-19-7
50-0-0
Substance
Diisopropylfluorophosphate (DFP)
Dimeihoate
Dimethylhydrazine
Dimethyl sulfate
Dinitro-o-cresol, 4,6- & salts
Dinoseh
Dioxane, 1,4-
Diphosphoramide, octamethyl-
Diphosphoric acid, tetraethyl ester
Disultoton
Dithiohiuret
Endosulfan
Endrin, & meiabolites
Epichlorohydrin
Ethanimidothioic acid, N-[((methylamino)carhonyl)oxyl-,
methyl, ester (Metliomyl)
Ethanol
Ethoxyethanol, 2-
Ethyl acrylate
Ethylbenzene
Ethyleneimine
Fluorine
Fluoroacetamide
Formaldehyde
Basis2
B
B, D
A, C, D
A, D
B, D
B, D
A
B, D
B
B, D
B, D
B, D
B, D
A, C, D
B
A
A
A
A
B, C, D
B, C, D
B, D
A, C, D
IDLH3
(g/m3)
0.036
0.3
0.037
0.036
0.005
0.045
1.798
0.008
0.005
0.02
0.05
0.008
0.002
0.283
0.1
6.209
1.839
1.226
3.468
0.176
0.039
NA
0 0245
Vapor Pressure4
(mm Hg @20°C)
0.579
8.3E-06 (25°C)
68 (24.5°C)
0.5
0 00032
0.075
29
0.001 (25 T)
0 0002
0.00018
NA
IE-OS (25 V)
0.000003
13
5E-05 (25 °C)
44
4
29
7
160
76
NA
38X1 (2.TC)
Conservative
Percent
Composition5
NA
NA
3
4
NA
NA
12
NA
NA
NA
NA
NA
1
6
NA
24
24
3
20
NA
NA
NA
II
Volume VII
111-13
-------
TABLE III-l (continued)
Summary of Chemicals of Potential Concern for Short-Term Exposures8
CAS
Number1
142-82-5
302-1-2
79-19-6
74-90-8
7647-1-0
7664-39-3
7783-7-5
7783-6-4
13463-40-6
78-83-1
465-73-6
62-38-4
62-75-9
67-56-1
78-93-3
60-34-4
H38-10-1
624-83-9
75-86-5
298-0-0
91-20-3
86-88-4
13463-39-3
Substance
Heptane
Hydrazine
Hydrazinecarhothioamide
Hydrocyanic acid
Hydrogen chloride
Hydrogen fluoride
Hydrogen selenide
Hydrogen sullide
Iron, peniacarhonyl-
Isobutanol
Isodrin
Mercury, (acetato-O)phenyl-
Methanamine, N-methyl-N-nitroso-
Metlianol
Methyl ethyl ketone (2-Butanone)
Methyl hydrazine
Methyl isobutyl ketone (2-Methyl-4-pentanone)
Methyl isocyanate
Methylactronitrile, 2-
Methyl parathion
Naphthalene
Naphthylthiourea, alpha-
Nickel carbonyl
Basis2
A
A, C, D
B
B,C, D
C
C
C
C
C
A
B, D
B
B
A
A
B, C, D
A
B, C, D
B
B
A
B
B,C, D
IDLH3
(g/m3)
3.067
00655
0092,
00551
0.0745
00245
00033
0.139
0.008
4.839
0.07
0.22
0.19
7.861
8.829
0.0376
2.045
0.007
0 12
0.0034
1.308
0 1
0.0139
Vapor Pressure4
(mm Hg @20°C)
40 (22 °C)
10
NA
630
31000
783
7200 (2 1°C)
13000
40(31°C)
9
0.000006
0.00012 (25 °C)
3
96
77.5
38
16
348
0.8
0.00001
0.08
NA
315
Conservative
Percent
Composition5
17
3
NA
NA
18
3
NA
NA
NA
20
NA
NA
NA
20
34
NA
19
NA
NA
NA
9
NA
NA
Volume VII
111-14
-------
TABLE III-l (continued)
Summary of Chemicals of Potential Concern for Short-Term Exposures'
CAS
Number1
54-11-5
98-95-3
10102-44-0
10102-43-9
79-46-9
62-75-9
20816-12-0
56-38-2
108-95-2
62-38-4
103-85-5
298-2-2
75-44-5
7806-51-2
151-50-8
506-61-6
W7-12-0
75-55-8
110-86-1
26628-22-8
143-33-9
57-24-9
7783-60-0
Substance
Nicotine, & salts
Nitrobenzene
Nitrogen dioxide
Nitrogen oxide NO
Nitropropane, 2-
N-nitrosodimetliylainine
Osmium oxide Os()4
Parathion
Phenol
Phenylmercury acetate
Phenylthiourea
Phorate
Phosgene
Phosphine
Potassium cyanide
Potassium silver cyanide
Propanenitrile
Propylenimine, 1,2-
Pyridine
Sodium azide
Sodium cyanide
Strychnidin- 10-one, & salts
Sulfur tetrafluoride
Basis2
B, D
A, D
B, D
B, C, D
A
B, D
B
B, D
A, D
B, D
B, D
B, D
B, C, D
B, C, D
B, D
B, D
B, C
B, C, D
A
B, D
B, D
B, D
C
IDLH3
(g/m3)
0005
1 005
0.0376
0.1224
0 364
0 19
0001
001
096
022
0.03
0.001
0.0081
0.069
0.025
0.2
0.037
0.233
3 229
02
0.025
0003
0092
Vapor Pressure4
(mm Hg @20°C)
0.08
0.27
720
26000
13
2.7
7
0.00004
0.4
9E-06(35°C)
NA
0.0008
1215
NA
NA
NA
35
112
16
NA
NA
NA
8(KK) (2 IT)
Conservative
Percent
Composition*
NA
25
NA
NA
20
NA
NA
NA
10
NA
NA
NA
NA
NA
NA
NA
NA
NA
17
NA
NA
NA
NA
Volume VII
111-15
-------
TABLE III-l (continued)
Summary of Chemicals of Potential Concern for Short-Term Exposures'
CAS
Number1
7446-11-9
7446-18-6
95-94-3
127-18-4
3689-24-5
78-0-2
109-99-9
509-14-8
1314-32-5
39196-18-4
108-98-5
79-19-6
5344-82-1
7550-45-0
108-88-3
584-84-9
1 91-8-7
8001-35-2
71-55-6
79-1-6
1314-62-1
1330-20-7
Substance
Sulfur trioxide
Sulfuric acid, dithallium (1 +) salt
Tetrachlorobenzene (assumed 1,2,4,5-)
Tetrachloroethylene
Tetraethyldithiopyrophosphate
Tetraethyl lead
Tetrahydrofiiran
Tetranitromethane
Thallic oxide
Thiofanox
Thiophenol
Thiosemicarbazide
Thiourea, (2-chlorophenyl)-
Titanium tetrachloride
Toluene
Toluene-2,4-diisocyanate
Toluene-2,6-diisocyanate
Toxaphene
Trichloroelhane, 1,1,1-
Trichloroethylene
Vanadium oxide
Xylene
Basis2
c
B
A
A
B
B, D
A
B, C, D
B
B, D
B.D
B, D
B, D
C
A
A, C, D
A, C, D
B
A
A
B, D
A
IDLH3
(g/m3)
0.03
0.02
NA,
1.015
0.01
0.04
5.886
0.032
0.02
0.085
0.014
0.092
0.046
0.01
1.88
0.0178
0.009
0.2
3.811
5.363
0.035
NA
Vapor Pressure4
(mm Hg @20°C)
344 (25 °C, beta)
NA
40 (146°C)
14
0.00017
0.2
132
8
NA
0.00017 (25 °C)
2 (25 °C)
NA
NA
NA
21
0.01
0.02
0.4(25"C)
100
57.9
NA
8.763(25°C)
Conservative
Percent
Composition5
NA
NA
10
13
NA
NA
16
NA
NA .
NA
NA
NA
NA
NA
24
4
4
1
16
17
NA
22
Volume VII
111-16
-------
CAS
Number1
81-81-2
1314-84-7
Substance
Warfarin, & salts, when > 0.3%
Zinc phosphide, when > 10%
Basis2
B, D
B, D
IDLH3
(g/m3)
0.1
0.12
Vapor Pressure4
(mm Hg @20°C)
0.09
NA
Conservative
Percent
Composition5
NA
NA
TABLE III-l (continued)
Summary of Chemicals of Potential Concern for Short-Term Exposures8
Notes:
NA
139 chemicals were selected for further analysis.
CAS Number given for parent compound only.
A Wastes projected to be received by WTI during first year of operation
B Constituents listed as "P" wastes (acutely hazardous according to RCRA)
C Acutely toxic chemicals identified in CAA 112(r)
D Extremely hazardous substances from EPCRA
Immediately Dangerous to Life or Health (1DLH) value (U.S. EPA 1995c). For chemicals without an IDLH value, but for which a Level of Concern (LOG)
value has been established by U S. EPA, the LOC multiplied by a factor of 10 was used in place of the IDLH.
Vapor Pressure data compiled from the following sources:
Hazardous Substances Data Bank (HSDB). 1991. National Library of Medicine.
Howard, P. H. 1989. Handbook of environmental fate and transport data (Vol. I. Large production and priority pollutants). Chelsea, MI: Lewis
Publishers
Howard, P. H. 1990. Handbook of environmental fate and transport data (Vol. II. Solvents). Chelsea, MI: Lewis Publishers.
Montgomery, J.H., and L.M. Welkom. 1990. Groundwater chemicals desk reference. Chelsea, MI: Lewis Publishers.
Average of the maximum concentrations reported for all waste streams containing the compound, according to WTI waste profiles for first year of operations.
Not available.
Volume VII
111-17
-------
TABLE III-2
Constituents Received in Largest Quantities in Pumpable Waste at the WTI Facility
Constituent
1 . Hydrocarbon (unspecified)
2. Cresol
3 . Toluene
4. Methyl Ethyl Ketone
5. Methanol
6. Acetone
7. Cyclohexanone
8. Ethyl Aery late
9. Butanol
10. Xylene
Approximate Quantity in
Pumpable Waste (lb/yr)
3,200,000
1,000,000
770,000
680,000
590,000
560,000
480,000
470,000
460,000
450,000
Percent of Total
Pumpable Waste
16.8%
5.2%
4.0%
3.5%
3.1%
2.9%
2.5%
2.4%
2.4%
2.3%
Source: Appendix III-l, Volume III.
Volume VII
m-i8
-------
TABLE III-3
Hydrogen Chloride and Phosgene Formation from
Decomposition of Chlorinated Hydrocarbons in
Contact with Flame3
Substance
Carbon tetrachloride1
Chloroform2
Dichloroethane2
Pentachloroethane2
Tetrachloroethane2
Tetrachloroethene2
Trichloroethene2
HC1 Formed
(mg/g chemical combusted)
199
138
240
332
326
238
266
Phosgene Formed
(mg/g chemical combusted)
8
6
ND
2
3
7
1
Notes:
1 Average of three trials.
2 Average of two trials.
3 Source: Sjoberg (1952).
Volume VII
III-19
-------
TABLE III-4
ERPG, LOG, and IDLH Values
Chemical
Acetone
Formaldehyde
Hydrogen chloride (HC1)
Phosgene
ERPG-22
(ppm)
NA1
10
20
0.2
ERPG-3'
(ppm)
NA
25
100
1.0
LOG3
(ppm)
1960
9.6
9.9
0.2
IDLH3
(ppm)
2442
19.6
49.1
2.0
Notes:
1 NA = Not available
2 AIHA 1994.
3 USEPA 1995c.
Volume VII
ra-20
-------
TABLE III-5
Wastes and Chemicals Evaluated
Scenario
Waste/Chemical Evaluated
On-Site Spill
Waste consists of 90% methanol/10%
formaldehyde ("worst-case" waste) or 90%
toluene/10% acetone ("typical" waste).
Consequences of formaldehyde and acetcae
releases are assessed.
On-Site Fire
Waste consists of 15% tetrachloroethene/
85% toluene. Consequences of HC1 and
phosgene releases are assessed.
On-Site Mixing of Incompatible Wastes
Waste consisting of 15 %
tetrachloroethene/85 % methanol mixed with
waste consisting of 70% nitric acid.
Consequences of HC1 releases are assessed.
Off-Site Spill
Waste consists of 90% methanol/10%
formaldehyde ("worst-case waste") or 90%
toluene/10% acetone ("typical" waste).
Consequences of formaldehyde and acetone
releases are assessed.
Off-Site Fire
Waste consists of 85% toluene/15%
tetrachloroethene. Consequences of HC1 and
phosgene releases are assessed.
Volume VII
m-21
-------
TABLE III-6
Key Assumptions Made in Selecting Chemicals of Potential Concern
Assumption
1. Waste composition data from WTI waste profile
sheets for first year of operations adequately
characterizes future waste.
2. Chronic human impacts off-site could be avoided
through mitigation measures.
3. LOG and IDLH values can be used to evaluate
the potential for acute health effects.
4. Substances for which acute data are not available
are less toxic than those for which data are
available.
5. Use of vapor pressure to reflect release potential.
6. Selection of tetrachloroethene and toluene as the
chemicals of concern for fire scenarios.
7. Selection of HC1 as the chemical of concern for
mixing of incompatible wastes.
Basis
Site-specific waste profile information. The potential
x>r underestimating risk is reduced by making
conservative assumptions in calculating chemical
concentrations in waste from the information in the
Drofiles. For example, for a spill of "worst case"
waste, the formaldehyde concentration is assumed to be
10%, which is approximately equal to the combined
average of the highest concentrations reported for
individual waste streams containing formaldehyde.
Mitigation measures in effect at the WTI facility will
limit migration of spilled wastes and duration of fire
scenarios.
LOG and IDLH values represent a consistent, relatively
comprehensive set of criteria for assessing the acute
effects of short-term exposures.
Chemicals for which no acute toxicity data are available
are ranked below chemicals with acute toxicity data.
Represents a consistent basis for comparison.
Selection of toluene for examining heat effects is
believed to be appropriate, given its high flammability,
and high quantity in pumpable waste. Selection based
on review of WTI waste profile and evaluation of toxic
byproducts of combustion.
HC1 represents a high hazard chemical given its
relatively high acute toxicity.
Magnitude of Effect
vledium
Low
High
Low
Low
High
High
Direction of Effect
Jnknown
May underestimate
LOC values are generally
protective, i.e., are more likely
to overestimate than
underestimate the potential for
health effects. IDLH values may
overestimate or underestimate the
potential for health effects,
depending on the basis for, and
uncertainty associated with, the
IDLH for a specific chemical.
Unknown
Unknown
Probably overestimates risk,
given high HCI and phosgene
formation rates for
tetrachloroethene. Selection of
toluene for examining heat
effects is believed to be
appropriate, given its high
flammability, and high quantity
in pumpable waste.
Overestimates
Volume VII
111-22
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IV. CHARACTERIZATION OF ACCIDENTAL RELEASES
A. Methodology
Atmospheric release rates for the chemicals of primary concern are estimated for each
accident scenario selected for quantitative evaluation. Release rates and durations are
developed for specific constituents based on facility-specific parameters (e.g., tank volumes,
dike sizes), and short-term-modeling techniques. The models account for the physical/
chemical properties of the chemicals (e.g., volatility, density, liquid or gas phase), and the
presence of passive mitigation devices (e.g., concrete dikes and berms). As discussed in
Chapter II, two release scenarios are evaluated for each on-site accident event:
No active or automatic mitigation devices (e.g., nitrogen blankets or sprinkler
systems) assumed. Passive mitigation devices (e.g., dikes, berms) are assumed to be
effective.
Active or automatic mitigation devices are assumed to control emissions. The effect
of mitigation is evaluated through two separate cases, with assumed response times of
ten minutes and one hour, respectively (see Chapter VII).
For the off-site accident events, only scenarios without any active mitigation are
considered.
Wastes consisting of a mixture of chemicals are modeled for all of the events in this
Accident Analysis. Physical and chemical properties for these mixtures are estimated from the
properties of the pure chemicals, weighted by the mass fraction of each chemical constituent.
The procedures used to estimate chemical emission rates for each accident scenario are
summarized below. Details regarding the calculations are presented in Appendix VII-3.
Volume VII IV-1
-------
B. Chemical-Specific Release Rate Calculations
1. On-Site Spill
In modeling emission rates, the ambient temperature is assumed to be 68°F (or
20°C), which may underestimate emission rates somewhat on very hot days, and
overestimate emission rates somewhat on very cold days. The annual average temperature
in Pittsburgh is 50°F (or 10°C); the average of the daily maximum temperatures during
July, the hottest month of the year, is 83°F (or 28°C), according to the historical climatic
data (1961-1990) published by the U.S. Department of Commerce (U.S. DOC 1993).
While the temperature of 68°F (or 20°C) used in the emission modeling may not cover all
the possible high temperatures that could occur at the WTI site, the value is considered
adequate for characterizing the ambient temperature in the WTI vicinity.
The on-site spill scenario selected for quantitative evaluation results from a collision
involving one tanker truck hauling liquid waste. In general, if the boiling point of a waste
mixture is greater than normal ambient temperatures, the evaporation rate from the pool
determines the rate at which the chemical enters the atmosphere (U.S. EPA 1993b). In
this analysis, the boiling points of both the formaldehyde/methanol mixture, 97 °F (or
36°C) and the acetone/toluene mixture 201 °F (or 94°C), are well above ambient
temperatures. Thus, chemical emission rates can be estimated by multiplying the total
pool evaporation rate, E^,, by the mass fraction of the chemical in the vapor.
The size of the pool being formed depends on the release rate and duration, and the
presence of containment barriers (e.g., dikes, speed bumps, building walls, etc.) in the
spill vicinity. In the spill scenario, it is assumed that the full content of the tanker could
be released in 10 minutes, consistent with the Accidental Release Prevention
Requirements: Risk Management Programs under Clean Air Act, Section 112(r)(7);
Proposed Rule (40 CFR Pan 68) (U.S. EPA 1995a). For the conservative case, assuming
the 5,000 gallon spill (the assumed volume for one truck) is contained within the berms in
the truck unloading area, the area of the liquid pool would be approximately 418 m2. For
the typical case, assuming the 100 gallon spill spreads to a depth of 1 cm, the area of the
liquid pool would be approximately 38 m2. Calculations of spill areas and formaldehyde
and acetone release rates for the spill scenarios are described in Appendix VII-3.
2. On-Site Fire
The on-site fire scenario selected for quantitative evaluation is'a storage tank rupture
in the Organic Waste Tank Farm in the presence of an ignition source, resulting in a pool
fire. The contents of the storage tanks are a mixture of 15% tetrachloroethene and 85%
Volume VII IV-2
-------
toluene, as discussed in Chapter III. The total burning rate is estimated from two factors:
(1) the burning velocity; and (2) the size of the burning pool. The burning velocity for a
liquid with a boiling point above ambient temperature is given by FEMA (1993) and
Burgess et al. (1961). The pool size is defined by the size of the secondary containment
area in the building, or 180 m2 in this scenario.
Combustion products that may be emitted during a fire include NOX, SO2 and HC1.
Phosgene emissions are also possible as a product of incomplete combustion. O'Mara et
al. (1971) reported that the potential for phosgene formation during combustion of
chlorinated hydrocarbons could be evaluated based on the following parameter:
Number of Chlorine Atoms - Number of Hydrogen Atoms
a -
Number oi Carbon Atoms
Phosgene formation is likely when a^O.4. Thus, for example, phosgene could be formed
during the combustion of carbon tetrachloride (a=4), chloroform (a=2),
tetrachloroethene (a=2), and trichloroethene (a=l), but would not be expected during the
combustion of chlorobenzene (a = -0.7), dichlorobenzene (a=-0.3), or trichloroethane
(a=0). The formation of HC1 and phosgene from the combustion of several chlorinated
hydrocarbons was estimated by Sjoberg (1952), as discussed in Chapter III. According to
Sjoberg (1952), combustion of tetrachloroethene is estimated to form 238 mg/g of HC1,
and 7.0 mg/g of phosgene. These values were used for estimating HC1 and phosgene
releases. Details regarding the calculation of HC1 and phosgene release rates are
presented in Appendix VII-3.
In the WTI Accident Analysis, the Automated Resource for Chemical Hazard Incident
Evaluation (ARCHIE) model developed by FEMA (1993) is used to assess heat effects of
fires. For fires and explosions, ARCHIE can be used to estimate the size of a pool of
burning substances, the height of the expected resulting flame, the radius from the center
of the burning pool within which individuals could be potentially fatally burned, and the
radius from the center of the burning pool within which individuals could potentially
experience second degree burns or severe pain. ARCHIE modeling is performed to
examine the heat impacts resulting from a fire ignited both immediately after a spill, and
after a pool achieves its maximum size. The radius of the fire, the fatal zone radius, and
the injury zone radius are calculated.
The hazards associated with a possible fireball incident are also estimated using the
ARCHIE model. A fireball could be formed if a sealed or inadequately vented container
Volume VII IV-3
-------
of a flammable liquid or liquefied compressed gas is exposed to an external fire or other
source of heat sufficient to cause explosion or violent rupture of the container (FEMA
1993). If the container is fairly full and is fitted with a pressure relief device, it may vent
a considerable portion of its contents before the occurrence of a boiling liquid expanding
vapor explosion (BLEVE).
The fireball scenario can occur if: (1) the container releases only a portion of its
content (e.g. a hole one foot below the liquid level); (2) the liquid ignites immediately
after the spill; and (3) the container's ventilation system malfunctions. It is highly
unlikely that all three of these conditions would occur during an on-site or off-site
accident. Nazario (1988) indicates that the critical parameter for a BLEVE to occur is the
degree of vaporization of the chemical inside the container. If more than 10% of the
vessel contents will vaporize when depressurized (or pressure-relief-valve setpoint), the
vessel has the potential for a BLEVE (Nazario 1988). Based on the relatively low vapor
pressures of tetrachloroethene and toluene and the storage conditions for the chemicals, it
is unlikely that a BLEVE would occur during a fire incident involving only a contained
on-site storage tank or an off-site tanker truck. However, a fireball scenario may occur if
an on-site (or off-site) spill spreads, ignites, and the flames engulf another tank (or tanker
truck) with sufficient heat to cause an explosion.
In assessing fireballs, ARCHIE assumes that the fuel is similar in characteristics (both
physical and chemical) to liquefied compressed propane and treats the fuel as if it were
liquefied propane. Propane has a boiling point much lower than a tetrachloroethene/
toluene mixture and is normally stored under pressure. A tetrachloroethene/toluene spill,
where the liquid has a boiling point greater than the ambient temperature and is stored
under ambient temperature and pressure, is not expected to result in a fireball. A large
amount of heat would be required to raise the tetrachloroethene/toluene temperature to the
boiling point and to transfer the liquid-phase chemical to the gas-phase, so that vapors can
be formed rapidly. In addition, tetrachloroethene/toluene vapors will continue to escape
from the tank during the heating through the ventilation system, reducing the quantity of
chemical available for a possible fireball scenario if the tank temperature actually reached
the chemical boiling point.
Detailed information regarding the ARCHIE modeling and the heat impacts due to
fires is presented in Appendix VII-3.
3. On-Site Mixing of Incompatible Wastes
The on-site mixing of incompatible wastes scenario selected for quantitative
evaluation results from an accidental pumping of incompatible waste into an improper
Volume VII IV-4
-------
storage vessel. This assumes pumping of 5,000 gallons of a mixture of chlorinated
hydrocarbons (15% tetrachloroethene/85 % methanol mixture) into a storage vessel
containing 5,000 gallon of mineral acids (70% nitric acid solution). The mixing results in
the release of gaseous hydrogen chloride (ASTM 1986).
To model the release of HC1 resulting from the mixing of incompatible wastes, it is
assumed that as the two wastes mix inside the storage vessel, the reaction between the two
wastes to produce HC1 is instantaneous. The pumping rate of the contents of the tanker
truck into the storage vessel is estimated to be 250 gallon/min (Victorine 1995b). The
release of HC1 into the atmosphere is assumed to occur at ambient temperature and
pressure through the vapor recovery system and vent.
The total amount of HC1 released is calculated by assuming that all chlorine in the
waste reacts instantaneously to form HC1. Using this approach results in a potentially
significant overestimate of HC1 releases. Details regarding the calculation of HC1
emissions are presented in Appendix VII-3.
4. Off-Site Tanker Truck Spill
The size of the off-site spill depends on the release rate and duration, and the
presence of containment barriers (e.g., street curbs, speed bumps, building walls, etc.) in
the spill vicinity, if any. As in the case of the on-site spill, chemical emission rates would
be determined by the rate of evaporation from the liquid pool.
Assuming the road on which the spill occurs is flat and has no curbs that are capable
of acting as a containment barrier, the liquid pool resulting from the conservative
5,000-gallon spill is assumed to reach a maximum length of approximately 49 m,
assuming pool depth of 1 cm (see Appendix VII-3). This assumes the pool spreads in all
directions at an equal rate, with liquids reaching the edge of the road running off onto soil
or into a ditch. Assuming that the road is not sloped from the center line to the sides is
conservative; in reality, it is likely that liquid would run off from the center of the road to
the sides, reducing the size of the spill. The assumption of no roadway curbs appears to
be appropriate for the local access route based on observations made during a site visit.
Based on a road width of 15 m, the area of the pool is approximately 735 m2 (Figure
IV-1); in calculating the duration of emissions, it is conservatively assumed that the entire
5,000 gallons is emitted from this area (15 m by 49 m). In the typical 100-gallon spill
case, the pool size is approximately 38 m2 (assuming a pool depth of 1 cm), and would not
reach the edge of the road.
Details regarding emission calculations for the off-site soil scenario are provided in
Appendix VII-3.
Volume VII IV-5
-------
5. Off-Site Tanker Truck Spill with Fire
The off-site fire scenario is similar to. the off-site spill scenario, with the additional
presence of an ignition source. Chemical emission rates are calculated using the same
approach as for the on-site fire scenario. Details regarding emission calculations are
presented in Appendix VII-3; all waste spilled is assumed to be combusted.
The ARCHIE model is used to estimate the heat effect posed by the off-site fire
scenario. Detailed information regarding the ARCHIE modeling and the heat impacts is
presented in Appendix VII-3.
C. Summary of Results and Key Assumptions
The chemical-specific emission rates calculated for each accident scenario are summarized
in Table IV-1. The major .assumptions made in estimating chemical emission rates in the
Accident Analysis are summarized in Table IV-2.
Volume VII IV-6
-------
TABLE IV-1
Chemical-Specific Emission Rates
Scenario
On-Site Spill'
Formaldehyde/Methanol
Acetone/Toluene
On-Site Fire
HC1
Phosgene
On-Site Mixing of Incompatible Wastes
HC1
Off-Site Spill1
Formaldehyde/Methanol
Acetone/Toluene
Off-Site Fire
HC1
Phosgene
Conservative (i.e., larger
Event
Emission
Rate2
(g/s)
3.2 m/s
1,330
681
1 m/s
432
194
360
11
1,790
3.2 m/s
1,840
1,140
1 m/s
759
341
1,470
43
volume)
Emission
Duration
(s)
3.2 m/s
3,120
18,240
1 m/s
7,500
43,980
7,030
7,030
1,200
3.2 m/s
1,740
10,320
1 m/s
4,260
25,020
430
430
Typical (i.e., smaller
Event
Emission
Rate2
(g/s)
3.2 m/s 1 m/s
94 39
51 18
150
4.5
71
3.2 m/s 1 m/s
94 39
51 18
76
2.2
volume)
Emission
Duration
(s)
3.2 m/s
680
3.960
1 m/s
1.660
9,660
167
167
600
3.2 m/s
680
3,960
1 m/s
1,660
9,660
167
167
Notes:
1 For the spill scenarios, emission rates and emission durations are given for windspeeds of 3.2 m/s and 1 m/s.
2 Average emission rate over the duration of release, except for releases greater than 30 minutes. For emission durations over 30
minutes, the emission rate is averaged over the first 30 minutes, when releases would be greatest.
Volume VII
IV-7
-------
TABLE IV-2
Key Assumptions Made in Estimating Chemical Emission Rates
Assumption
Basis
Magnitude of Effect
Direction of Effect
All chlorine in the waste is converted to
HC1 in the mixing of incompatible waste
scenario.
Conservative assumption due to lack of data
regarding actual conversion rates. A fraction
of the chlorine would be expected to react to
form less hazardous compounds.
High
Overestimates
2. Ambient temperature assumed to be 68° F
(or 20"C).
Typical temperatures in the East Liverpool
area.
Low
Likely to overestimate
emissions expected on most
days, while underestimating
emissions on some days.
3. Roadway is assumed to be flat for the off-
site spill scenario.
Conservative assumption due to variability in
actual in actual road conditions.
Medium
Likely to overestimate
emissions in most cases. If
hilly, could overestimate if
near bottom of hill; or could
underestimate if near top of
hill. A peaked road would
likely reduce the size of the
pool.
4. The limited available data from Sjoberg
(1952) can be used to quantify emissions of
HC1 and phosgene in the event of a fire.
The Sjoberg (1952) is an older investigation,
but provides the most complete data for
quantifying emissions in the event of a fire
involving chlorinated waste.
Medium
Unknown
5. Spills will spread to a depth of 1 cm for the
off-site spills and the on-site typical volume
spills.
U.S. EPA (1987); Moorhouse and Carpenter
(1986)
Low
Expected to somewhat
overestimate emissions if
surface is not flat, or if berms
or drains are present.
6. Ambient wind speed assumed to be 3.2 m/s.
Average windspeed at the WTI facility based
on site-specific data.
Medium
Likely to overestimate
emissions under low wind
conditions, as defined in the
screening meteorological
conditions.
Volume VII
IV-8
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Area of off-site
spill « 735
Volume VII
Figure IV 1
WT1 ACaDENT ANALYSIS. OFF-SITE SPILL ANALYSIS
AREA OF OFF-SITE SPILL
-------
V. ATMOSPHERIC DISPERSION MODELING
A. Model Selection
In the Accident Analysis, atmospheric dispersion modeling of accidental releases was
performed using the SLAB and ISC-COMPDEP models. SLAB is selected for modeling
vapor releases from the spill and mixing of incompatible waste scenarios. It is a fully-
documented model released by Lawrence Livermore National Laboratory (Ermak 1990), and
listed by the U.S. EPA for use in modeling hazardous/toxic air pollutant releases (U.S. EPA
1993b). The model simulates both neutral and denser-than-air releases, and allows for
continuous, finite duration, and instantaneous releases as well as automatic transition of
continuous plume into transient plume with various time-averaged concentrations at the
receptor locations.
The ISC-COMPDEP model is selected for mooeling the on-site and off-site fire scenarios
for several site-specific reasons. ISC-COMPDEP is a steady-state Gaussian model that can be
used for both simple and complex terrain situations. Because of the high temperatures
associated with the fire scenarios, the ability to model plume rise is critical. In addition,
unlike SLAB, ISC-COMPDEP incorporates buoyant plume rise algorithms that allow the
gradual or transitional rise of plumes to be computed. A complete description of ISC-
COMPDEP is provided in Volume IV (Air Dispersion Analyses).
Details regarding the use of the SLAB and ISC-COMPDEP models in the Accident
Analysis are provided in Appendix VU-4.
B. Meteorological Conditions
For the accident events modeled using SLAB (on-site and off-site spills, and on-site
mixing of incompatible wastes), off-site chemical concentrations in air are evaluated for three
meteorological conditions: (1) "typical;" (2) "conservative;" and (3) "calm/inversion." For
each meteorological condition, 30-minute average concentrations were calculated using SLAB,
to allow for a direct comparison of IDLH values. For the on-site and off-site fire accident
events modeled using ISC-COMPDEP, typical and conservative mete6rological conditions are
evaluated. The one-hour average concentrations predicted by the ISC-COMPDEP model are
converted to 30-minute averages for comparison with the health-based reference
Volume VII V-l
-------
concentrations. The 30-minute average concentrations are obtained by multiplying the ISC-
COMPDEP results by a factor of 1.15 (U.S. EPA 1992b, Turner 1967). The ISC-COMPDEP
model is not appropri?te for use when calculating atmospheric dispersion under calm/
inversion conditions because the basic Gaussian steady-state assumption becomes invalid. An
evaluation of fire scenarios under calm/inversion conditions has thus been performed using the
CALPUFF model, and is discussed in Chapter VII (Uncertainties).
The three meteorological conditions evaluated in the Accident Analysis are described
below.
1. Typical Conditions
A hybrid surface meteorological data set was developed for use in the dispersion
modeling of the stack and fugitive emissions from the WTI facility (see Volume IV). This
database represents meteorological conditions from April 1992 through March 1993.
Based on these data, a typical meteorological condition was determined to be neutral
atmosphere (Pasquill-Gifford Stability Category D) with average wind speed (3.2 m/s).
Specifically, neutral atmospheric conditions (Stability Category D) are the most frequently
measured at the WTI facility, occurring approximately 57% of the time, and the average
windspeed during non-calm hours at the WTI facility is 3.2 m/s (see Volume IV). This
set of conditions was used to represent typical conditions using both the SLAB model (for
non-fire scenarios) and the ISC-COMPDEP model (for fire scenarios). As a sensitivity
analysis, ISC-COMPDEP is also used in conjunction with the one-year real-time
meteorological data to evaluate the off-site impacts of the fire scenarios during typical
meteorological conditions. The selection of the wind speed and atmospheric stability
characterizing the typical meteorological condition is discussed in Appendix VIM.
2. Conservative Conditions
For each accident scenario, 54 combinations of atmospheric stability and wind speed
are evaluated to determine which combination results in the maximum downwind ground
level concentrations off-site. These combinations correspond to non-calm meteorological
conditions at the WTI site, and are identified from the matrix of possible conditions
presented in U.S. EPA (1992b). The 54 combinations shown in Table V-l are evaluated
to determine the conservative meteorological conditions and resulting concentrations using
both the SLAB model (for non-fire scenarios) and the ISC-COMPDEP model (for fire
scenarios). ''
It is necessary to examine all 54 meteorological conditions to determine the maximum
ground-level concentrations at different downwind distances. For example, the maximum
Volume VII V-2
-------
ground-level concentration for a receptor far from a stack would occur during a stable
low-wind condition, while an unstable high-wind condition would result in the highest
ground-level concentration for a receptor immediately downwind of the same stack.
Thus, only by screening all 54 conditions can the worst-case meteorological condition and
maximum ground-level concentration be identified at each downwind distance. In general,
however, the conservative meteorological condition reflects a stable atmosphere with low
windspeed, e.g., a windspeed of 1.5 m/s and Stability Category F, as indicated in U.S.
EPA (1987).
As a sensitivity analysis, ISC-COMPDEP is also used in conjunction with the one-
year real-time meteorological data to further evaluate the off-site impacts of the fire
scenarios during conservative meteorological conditions. A more detailed discussion of
the SLAB and ISC-COMPDEP modeling of conservative meteorological conditions is
presented in Appendix VII-4.
3. Calm/Inversion Conditions
Calm/inversion meteorological conditions represent the most stable meteorological
condition that may occur at the WTI site, and thus results in the highest off-site
concentrations in air in the event of an accidental release. This hypothetical
meteorological condition assumes that emissions accumulate in the air immediately above
the source for one hour during calm conditions and stable atmosphere, and are then
transported downwind under low wind speeds. Additional emissions from the spill, if
there is sufficient quantity for further volatilization after the calm hour, would travel
downwind as a continuous plume.
The limited mixing in the surface layer imposed by the temperature inversion is
represented by a mixing height of 100 m in the SLAB model, and the worst-case
meteorological condition is represented by the combination of low wind speed (1 m/s) and
stable atmosphere (Monin-Obukov length of 8.3 m, approximately equivalent to Pasquill-
Gifford atmospheric stability of E or F based on the Liu-Durran regression equation, as
referenced by Randerson (1984). It is similar, in theory, to the calm meteorological
condition evaluated for the routine stack and fugitive emissions study for WTI, where
emissions during the calm hours are accumulated and released at the end of the calm
. period (see Volume IV).
As previously stated, the ISC-COMPDEP model is not appropriate for use when
evaluating atmospheric dispersion of accidental releases under calm wind conditions.
Potential releases associated with the on-site and off-site fire scenarios under calm/
inversion conditions have therefore not been evaluated using the ISC-COMPDEP model.
Volume VII V-3
-------
The impacts for the fire scenarios under this calm/inversion meteorological condition are
evaluated using the CALPUFF model, however, in Chapter VII (Uncertainties).
C. Summary of Results and Key Assumptions
Tables V-2 through V-4 summarize the downwind concentrations at four downwind
distances for the accident scenarios evaluated using the SLAB model (on-site spill, on-site
mixing of incompatible wastes, and off-site spill). Complete SLAB model outputs and
modeling parameters are presented in Appendix VII-4 and associated attachments.
The one-hour average concentrations predicted by the ISC-COMPDEP model for the
typical meteorological condition and each of the 54 screening meteorological conditions are
presented in Appendix VIM for both the on-site and off-site fire accident scenarios. Tables
V-5 and V-6 summarize the downwind concentrations at four downwind distances for the two
fire scenarios evaluated. In the Accident Analysis, concentrations resulting from the fire
scenarios associated with large quantity releases (on-site 20,000-gallon spill and off-site 5,000-
gallon spill) are modeled directly using ISC-COMPDEP. Fire scenarios associated with the
small quantity releases (on-site spill of 200 gallons, and off-site spill of 100 gallons) can not be
reliably modeled using ISC-COMPDEP because the releases associated with such small fires
are short-lived and should not be treated as continuous plumes. However, the off-site impacts
associated with the small quantity fire scenarios can be estimated from the ISC-COMPDEP
results for the large quantity fire scenarios. As discussed in Appendix VIM, the off-site
concentrations resulting from the large quantity fire scenarios, based on the considerations of
source size, emission rate, emission duration, and concentration averaging time, are predicted
to be at least 10-fold higher than concentrations resulting from small quantity fire scenarios.
Thus, in the Accident Analysis, air concentrations for the typical fire events are conservatively
estimated to be 10-fold lower than the concentrations modeled using ISC-COMPDEP for the
large fire scenarios.
The major assumptions made in order to perform the SLAB or ISC-COMPDEP dispersion
modeling are listed in Table V-7.
Volume VII V-4
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TABLE V-l
Stability Wind Speed Combinations Used
to Determine Conservative Meteorological Conditions
Atmospheric
Stability
Categories
A
B
C
D
E
F
Wind Speed (meters/s)
1
*
*
*
*
*
*
1.5
*
*
*
*
*
*
2
*
*
*
*
#
*
2.5
*
*
*
*
*
*
3
*
*
*
*
*
*
3.5
*
*
*
*
*
4
*
*
*
*
*
4.5
*
*
*
*
5
*.
*
*
*
8
*
*
10
*
*
15
*
20
-
Note:
Matrix of conditions taken from U.S. EPA 1992b. It is only necessary to consider the stability-wind speed conditions
relevant to the WTI site, which are marked with an asterisk (*).
Volume VII
V-5
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TABLE V-2
Summary of Downwind Air Concentrations for the On-Site Spill Scenarios
Chemical of
Concern
Formaldehyde
Acetone
Formaldehyde
Acetone
Spill Size
(pal>
5,000
5,000
100
100
Meteorological
Conditions
Typical
Conservative
Calm/Inversion
Typical
Conservative
Calm/Inversion
Typical
Conservative
Calm/Inversion
Typical
Conservative
Calm/Inversion
Downwind Concentrations (ppm)'
100m
310
3030
3740
57
330
430
9.7
120
160
3.8
41
44
500m
45
660
960
8.2
83
110
1.2
22
46
0.47
8.1
13
1000 m
16
250
450
2.8
34
53
0.40
8.1 '
20
0.15
3.0
6.1
2000m
5
89
180
0.9
12
23
0.12
2.6
6.5
0.05
1.0
2.4
Note:
1 Downwind distance from the property line to the east or west across the Ohio River to the south, or the existing railroad to the north, whichever is closer to
the location of the release. For the on-site spill, maximum downwind distance was calculated from the railroad to the north, approximately 75 m from the
edge of the spill.
Volume VII
V-6
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TABLE V-3
Summary of Downwind Air Concentrations for the On-Site Mixing of Incompatible Wastes Scenarios
Chemical of Concern
HCI
HC1
Waste Volume
(gal)
5,000
200
Meteorological
Conditions
Typical
Conservative
Calm/Inversion
Typical
Conservative
Calm/Inversion
Downwind Concentration (ppm)1
100m
375
4100
3700
11
120
170
500m
78
600
920
1.5
25
51
1000m
26
260
420
0.5
9.5
22
2000m
8.1
100.
170
0.15
3.0
7.5
Note:
1 Downwind distance from the property line to the east or west across the Ohio River to the south, or the existing railroad to the north, whichever is closer to
the location of the release. For the on-site mixing of incompatible waste, maximum downwind distance was calculated from the railroad to the north,
approximately 75 m from the release.
Volume VII
V-7
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TABLE V-4
Summary of Downwind Air Concentrations for the Off-Site Spill Scenarios
Chemical of
Concern
Formaldehyde
Acetone
Formaldehyde
Acetone
Spill Volume
(gal)
5,000
5,000
100
100
Meteorological
Conditions
Typical
Conservative
Calm/Inversion
Typical
Conservative
Calm/Inversion
Typical
Conservative
Calm/Inversion
Typical
Conservative
Calm/Inversion
Downwind Concentration (ppm)'
100m
660
6100
6810
170
940
1130
25
260
276
9.9
79
77
500m
61
830
1070
' 16
140
170
1.5
27
55
0.60
10
15.1
1000m
19
280
450
5.1
54
75
0.5
9.3
22
0.18
3.4
6.7
2000m
5.7
100
170
1.5
18
31
0.1
2.7
6.9
0.05
1.1
2.5
Note:
1 Downwind distance from edge of spill.
Volume VII
V-8
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TABLE V-5
Summary of Downwind Air Concentrations for the On-Site Fire Scenarios
Chemical of
Concern
Phosgene
HCI
Phosgene
HCI
Spill Size
(gal)
20,000
20,000
100
100
Meteorological
Conditions
Typical
Conservative
Calm/Inversion
Typical
Conservative
Calm/Inversion
Typical
Conservative
Calm/Inversion
Typical
Conservative
Calm/Inversion
Downwind Concentrations (ppm)2
100m
3
--
NE1
--
--
NE
--
-
NE
--
NE
500m
0.0080
NE
--
0.72
NE
--
0.0008
NE
--
0.07
NE
1000m
0.0046
0.14
NE
0.42
12.8
NE
0.0005
0.014
NE
0.04
1.3
NE
2000m
0.0043
0.053
NE
0.40
4.9
NE
0.0004
0.005
NE
0.04
0.5
NE
Notes:
1 NE: Not Evaluated as part of this analysis. A sensitivity analysis for this scenario is presented in Chapter VII.
2 Downwind distance from the property line to the east or west across the Ohio River to the south, or the existing railroad to the north, whichever is closer to
the location of the release. For the on-site fire, maximum downwind distance was calculated from the railroad to the north, approximately 75 m from the
edge of the fire.
3 --: Concentration less than 0.0001 ppm.
Volume VII
V-9
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TABLE V-6
Summary of Downwind Air Concentrations for the Off-Site Fire Scenarios
Chemical of
Concern
Phosgene
HCI
Phosgene
HCI
Spill Volume
(gal)
5,000
5,000
100
100
Meteorological
Conditions
Typical
Conservative
Calm/Inversion
Typical
Conservative
Calm/Inversion
Typical
Conservative
Calm/Inversion
Typical
Conservative
Calm/Inversion
Downwind Concentration (ppm)2
100m
0.011
2.6
NE1
1.0
243
NE
0.001
0.26
NE
0.10
24.3
NE
500m
0.0062
0.42
NE
' 0.57
39
NE
0.0006
0.042
NE
0.057
3.9
NE
1000m
0.0014
0.25
NE
0.13
23
NE
0.0001
0.025
NE
0.013
2.3
NE
2000m
0.00063
0.11
NE
0.058
10
NE
0.00006
0.011
NE
0.0058
1.0
NE
Notes:
1 NE: Not Evaluated as part of this analysis. A sensitivity analysis for this scenario is presented in Chapter VII.
2 Downwind distance from the edge of the fire.
Volume VII
V-10
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TABLE V-7
Key Assumptions Made in Dispersion Modeling
Assumption
Basis
Magnitude of Effect
Direction of Effect
SLAB Modeling
1. Source temperature assumed to be 20° C
2. Source height assumed to be 0.
3. Receptor elevation assumed to be 0.
4. Building wake effect not considered.
5. Typical meteorological conditions represented
by D-stability and 3.2 m/s winds.
6. Conservative meteorological conditions defined
by screening conditions.
7. Calm/Inversion meteorological conditions
assumed to be calm hours followed by stable
low wind condition.
Deflects typical temperatures in the East
Liverpool Area. The source temperature
variation is insignificant in the dispersion
analysis.
Simplifying assumption.
Simplifying assumption. May overestimate
downwind concentrations.
Simplifying assumption.
Site-specific data.
Approach outlined in U.S. EPA (1992b) allows
for selection of meteorological conditions which
result in maximum concentrations under different
accident scenarios
Simplifying assumption.
_ow
Low
Low
Medium
Low
Low
Low
Jnknown
Overestimates
Overestimates. The
overestimation is not
significant based on the
terrain elevations in the area
near the WTI facility.
May over or underestimate
downwind concentrations for
elevated stack release. May
overestimate downwind
concentrations for ground-
level spill.
Unknown. May over or
underestimate during any
given event.
Overestimates for almost all
meteorologic conditions
Significant overestimates for
almost all meteorologic
conditions
ISC-COMPDEP Modeling
1. Highest terrain elevation assumed for receptors
of the same downwind distance.
2. 30-minute average concentrations converted
from 60-minute averages calculated by ISC-
COMPDEP Model.
Simplifying assumption.
Allows for comparison to IDLH and LOG
values.
Low
Low
Likely overestimates
Likely overestimates
Volume VII
V-ll
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VI. SEVERITY OF CONSEQUENCES AND
PROBABILITY OF OCCURRENCE
The results of the Accident Analysis for the WTI facility are characterized in terms of
both severity of consequence and probability of occurrence. This approach is consistent with
the guidance established by U.S. EPA (1987) and FEMA (1993), as discussed in Chapter I.
Severity of consequence is ranked as minor, moderate, major, or catastrophic, based on
the distance over which predicted concentrations in potentially inhabited areas could
potentially exceed NIOSH Immediately Dangerous to Life or Health (IDLH) or U.S. EPA
Level of Concern (LOC) values. For on-site accident scenarios, the nearest inhabited areas
are conservatively assumed to be the property line to the east or west, across the Ohio River to
the south, or across the existing railroad tracks to the north. In each case, the nearest
inhabited area is at least 75 m from the location of the on-site accident. For off-site accident
scenarios, inhabited areas are assumed to be immediately adjacent to the location of release.
These assumed locations of inhabited areas are conservative because they represent the closest
possible resident; in most situations, the closest resident would be farther away from the
release.
In evaluating severity of consequence, the guidelines presented in FEMA (1993) have
been modified to correspond to distances over which IDLH or LOC values are predicted to be
exceeded. This involves a consideration of the population density within specific distances of
the site, and the width of a contaminant plume in air as it moves away from the source. Based
on 1990 census data, approximately 25 to 50 people live within approximately 175 m of the
facility, and approximately 1,000 to 1,500 people live within approximately 1,100 m of the
facility. Given the location of the WTI facility along the Ohio River, it can be assumed that
most people live within a rough semicircle (a 180° arc) to the north, with no inhabitants within
75 m of the location of an on-site accident. As a plume moves away from the source, its
width (described as concentrations within one standard deviation of the maximum, centerline
concentration) would cover an arc of approximately 5° to 10°.
Two separate severity of consequence ranking systems were developed for the Accident
Analysis, one based on IDLH values and the other based on LOC values. The ranking
systems based on IDLH and LOC values are shown in Tables VI-1 and VI-2, respectively. In
Volume VII VI-1
-------
the Accident Analysis, it was assumed that an exceedcnce of an IDLH value in inhabited areas
would have the potential to cause injuries. Assuming that a contaminant plume with
concentrations higher than IDLH values has a width of 10°, the average number of individuals
within 1,100 m who would be exposed to concentrations in excess of the IDLH would be
approximately 50 to 100. Within 175 m of the site, the average number of individuals
exposed to concentrations in excess of the IDLH would be less than 10. Thus, the
consequence of any event for which IDLH values are predicted to be exceeded up to a distance
of 100 m into inhabited areas (i.e., approximately 175 m from the source for on-site events, or
100 m from the source for off-site events) is ranked as moderate, corresponding to less than 10
people on average exposed to concentrations exceeding the IDLH. The consequence of any
event for which IDLH values are predicted to be exceeded up to a distance of 1,000 m into
inhabited areas is ranked as major, corresponding to up to 100 people on average exposed to
concentrations exceeding the IDLH. Events which do not result in exceedances of IDLH
values are ranked as minor, whereas events where IDLH values are exceeded over distances
greater than 1,000 m are ranked as catastrophic.
A key difference between LOG and IDLH values is that the LOG values are developed to
explicitly account for potentially sensitive individuals in the general population, whereas the
IDLH values are not. Below the LOG value, acute health effects would not be expected in any
individual in the general population. At concentrations between the LOG and IDLH, health
effects may occur in potentially sensitive individuals. Above the IDLH, acute health effects
may occur even in individuals who are not considered particularly sensitive.
Given that only a fraction of the general population might be considered to be potentially
sensitive in the event of an acute inhalation exposure, the severity of consequence ranking
system based on IDLH values has been adjusted to evaluate distances over which the LOG is
exceeded. In adjusting the ranking system, it is assumed up to 25% of the general population
might be considered potentially sensitive to acute exposures. This value is based on estimates
of the number of individuals in the U.S. who: (1) are considered asthmatics (approximately
5.9 percent of the total population, based on statistics provided by the Center for Disease
Control and Prevention); (2) over the age of 64 (approximately 12.6 percent of the total
population, based on 1990 U.S. Census Data); or (3) under the age of 5 (approximately 7.4
percent of the total population, based on 1990 U.S. Census Data). If it is conservatively
assumed that every individual in one of these three subpopulations is considered potentially
sensitive to inhalation exposures to the constituents of concern in the Accident Analysis, and
that there is negligible overlap between the groups, then the fraction of the population that
could be considered potentially sensitive is approximately 25 percent.
Volume VII Vl-2
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Accounting for the estimated 25 % of the general population who are considered
potentially sensitive, a severity of consequence ranking system based on LOG values has been
developed. Using this system, the consequence of an event for which LOG values are
predicted to be exceeded up to a distance of 200 m into inhabited areas is ranked as moderate.
and the consequence of any event for which LOG values are predicted to be exceeded up to a
distance of 2,000 m is ranked as major. Events which do not result in exceedances of LOG
values are ranked as minor, whereas events where LOG values are exceeded over distances
greater than 2,000 m are ranked as catastrophic.
The severity of consequence rankings in this Accident Analysis are more conservative
than the rankings presented in FEMA (1993). For example, FEMA (1993) assigns a moderate
ranking to events which are predicted to result in "up to 100 potential human injuries requiring
medical treatment or observation; up to 10 potential human fatalities; or evacuation of up to
2,000 people." In this Accident Analysis, a moderate ranking is assigned to events which are
estimated to have the potential to result in less than 10 people on average exposed to
concentrations exceeding the IDLH. Similarly conservative criteria are used in the Accident
Analysis for ranking events as potentially major or catastrophic. Thus, the severity of
consequence rankings in this Accident Analysis cannot be directly related to the criteria
presented in FEMA (1993).
Ranking by probability of occurrence is performed using the general criteria presented in
FEMA (1993) and is shown in Table VI-3. As indicated in Table VI-3, probability of
occurrence has been ranked as common, likely, reasonably likely, unlikely, or very unlikely.
based on the likelihood of the accident event, the composition of the waste, and the
meteorological conditions. FEMA (1993) presents the following guidelines for evaluating
accident probability: common, expected to occur one or more times each year on average;
likely, expected to occur at least once every 10 years on average; reasonably likely, predicted
to occur between once every 10 years and once every 100 years on average; unlikely.
predicted to occur between once every 100 years and once every 1,000 years on average; and
very unlikely, predicted to occur less than once in 1,000 years.
A. Severity of Consequences
The severity of consequence rankings developed for the various accident scenarios using
IDLH and LOG values are summarized in Tables VI-4 and VI-5, respectively, for on-site
events, and in Tables VI-6 and VI-7, respectively, for off-site events. The basis for these
rankings is discussed below. *'
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1. On-Site Spill
Four on-site spill events are evaluated:
Conservative spill (5,000 gallon) of formaldehyde-containing waste.
Conservative spill (5,000 gallon) of acetone-containing waste.
Typical spill (100 gallon) of formaldehyde-containing waste.
Typical spill (100 gallon) of acetone-containing waste.
The results of the.consequence analysis for these events are summarized in
Tables VI-8 and VI-9, and are discussed below.
a) Conservative (Large Volume) Spill of Formaldehyde-Containing Waste
In the event of a 5,000 gallon spill of liquid waste containing 10% formaldehyde,
assuming no active or automatic mitigation measures or emergency response, the
LOC is predicted to be exceeded up to approximately 1,360 meters (m) downwind in
potential receptor areas under typical meteorological conditions. The IDLH value is
predicted to be exceeded up to approximately 870 m downwind in potential receptor
areas under typical meteorological conditions. Under conservative meteorological
conditions, the LOC and IDLH values for formaldehyde are predicted to be exceeded
up to approximately 8,240 m and 4,870 m downwind, respectively. Under
calm/inversion conditions, the LOC and IDLH values for formaldehyde are predicted
to be exceeded up to approximately 14,100 m and 10,400 m downwind, respectively.
Given the large distances over which the IDLH and LOC values for
formaldehyde could potentially be exceeded, the severity of consequence for this
event is judged to be major to catastrophic, depending on the meteorological
conditions.
b) Conservative (Large Volume) Spill of Acetone-Containing Waste
For a 5,000 gallon spill of liquid waste containing 10% acetone, IDLH and LOC
values for acetone are not predicted to be exceeded in off-site inhabited locations
under any meteorological conditions. Thus, the severity of consequence for this event
is judged to be minor.
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c) Typical Spill of Formaldehyde-Containing Waste
For an on-site spill of 100 gallons of liquid waste containing 10% formaldehyde,
assuming no active mitigation or emergency response, LOG and IDLH values are
predicted to be exceeded up to approximately 100 m and 40 m downwind,
respectively, under typical meteorological conditions. Under conservative
meteorological conditions, LOG and IDLH values for formaldehyde are predicted to
be exceeded up to 910 m and 550 m downwind, respectively. Under calm/inversion
conditions, LOG and IDLH values for formaldehyde are predicted to be exceeded up
to 1,590 and 1,000 m downwind, respectively.
Given the areas over which IDLH and LOG values are predicted to be exceeded,
the severity of consequences for this event is judged to be moderate to major,
depending on the meteorological conditions at the time of the spill.
d) Typical Spill of Acetone-Containing Waste
IDLH or LOG values are not predicted to be exceeded in off-site inhabited
locations under any meteorological conditions. Thus, the severity of consequence is
judged to be minor.
2. On-Site Fire
Two on-site fire events are evaluated:
A fire involving a spill of 20,000 gallons of waste containing 15%
tetrachloroethene and 85% toluene.
A fire involving a spill of 200 gallons of waste containing 15% tetrachloroethene
and 85% toluene.
The results of the on-site fire scenarios are summarized in Tables VI-10 and VI-11, and
are discussed below. These scenarios have been evaluated using the ISC-COMPDEP
model under typical and conservative meteorological conditions. Fire scenarios under
calm/ inversion conditions are discussed in Section C of Chapter VII.
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a) Conservative (Large Volume) Fire Event
In the conservative fire event, LOG and IDLH values for phosgene and HC1 are
not expected to be exceeded off-site under typical meteorological conditions. Under
conservative meteorological conditions, the LOG for HC1 is predicted to be exceeded
at distances between 675 and 1,125 m downwind. The LOG value for phosgene, and
the IDLH values for HC1 and phosgene, are not expected to be exceeded off-site
under conservative meteorological conditions. Therefore, the severity of
consequences is predicted to be minor based on IDLH values and minor to moderate
based on LOG values.
According to the results of the ARCHIE model, an on-site fire involving the
20,000 gallon release assumed for this scenario could potentially result in a heat effect
fatality zone radius of 20 m, and an injury zone radius of 28 m. The fatality zone
radius is defined as the distance from the center of the pool within which individuals
may suffer from third-degree burns likely to be fatal. The injury zone radius is
defined as the distance from the center of the pool within which individuals may
suffer from second-degree burn injuries or severe pain on bare skin. Because
inhabited areas are more than 75 m from the fire location, neither fatalities nor
injuries would be expected off-site, although on-site impacts might occur.
The consequences of a fireball, which would be much less likely to occur than a
simple fire, could be more significant. According to the ARCHIE model, the fatality
zone radius would be 365 m, or possibly extending nearly 300 m into inhabited off-
site areas. The injury zone radius would be 695 m, or possibly extending to almost
625 m in inhabited off-site areas.
When heat effects are considered, the severity of consequence based on IDLH or
LOG values would remain unchanged. In the event of a fireball, the severity of
consequence would be classified as major; however, the potential for a fireball is very
low. The severity of consequence for this event does not change whether ignition
occurs during the release, or after the pool reaches its maximum size (see Appendix
VTi-3 for details).
b) Typical Fire Event
In the typical fire event, IDLH or LOG values for HC1 and phosgene are not
predicted to be exceeded off-site under either typical or conservative meteorological
conditions.
For the on-site fire involving a 200 gallon spill, the fatality zone radius for heat
effects from a pool fire is 13m, and the injury zone radius is 18m, assuming that the
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fire did not occur until the spill area reached its maximum size. If the waste were to
ignite upon discharge, both radii would be less. Thus, while on-site impacts might
occur, neither fatalities nor injuries are expected off-site.
For a fireball, the calculated fatality zone radius is approximately 30 m, and the
calculated injury zone radius is approximately 65 m. Given that the closest inhabited
areas are over 75 m from the on-site fire location, neither fatalities nor injuries would
be expected off-site. As discussed in Chapter IV of this report, the potential for a
fireball is very low, given the wastes expected to be received at the WTI facility.
Based on the results, the severity of consequence for the typical on-site fire is
judged to be minor.
3. On-Site Mixing of Incompatible Wastes
Two on-site events involving mixing of incompatible wastes are evaluated:
Mixing of a total of 10,000 gallons of incompatible wastes (by inadvertently
pumping 5,000 gallons of waste, at a rate of 250 gallons/min, into a tank which
contains 5,000 gallons of an incompatible waste), resulting in the generation of
HC1 emissions.
Mixing of a total of 200 gallons of incompatible wastes, resulting in the
generation of HC1 emissions.
The results of these events are summarized in Tables VI-12 and VI-13, and are
discussed below.
a) High Volume Mixing Event
In the Accident Analysis, HC1 emissions are calculated using a simple mass
balance and are likely to be significant overestimates, because it is assumed that 100%
of the chlorine in the waste reacts instantaneously to form HC1 and there is no active
mitigation or emergency response. Based on these assumptions, for the mixing event
involving 10,000 gallons of incompatible wastes, the LOG and IDLH values for HC1
are predicted to be exceeded up to approximately 1,780 m and 680 m downwind,
respectively, in potentially inhabited areas under typical meteorological conditions.
Under conservative meteorological conditions, the LOG and IDLH values are
predicted to be exceeded up to approximately 8,790 m and 3,190 m, respectively.
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Under calm/inversion conditions, LOG and IDLH values are predicted to be exceeded
up to approximately 12,200 m and 4,620 m, respectively.
Based on the assumptions of this analysis, the severity of consequence for this
event is judged to be major to catastrophic, depending on the meteorological
conditions.
b) Typical Volume Mixing Event
In the typical volume mixing event involving 200 gallons of waste, the LOG
value for HC1 is predicted to be exceeded up to a distance of approximately 130 m,
under typical meteorological conditions. The IDLH value for HC1 is not predicted to
be exceeded off-site under typical meteorological conditions. Under conservative
meteorological conditions, the LOG and IDLH values for HC1 are predicted to be
exceeded up to approximately 980 m and 270 m downwind, respectively. Under
calm/inversion conditions, the LOG and IDLH values are predicted to be exceeded up
to 1,700 m and 520 m downwind, respectively.
Based on the distances over which the IDLH and LOG are predicted to be
exceeded, the severity of consequence for this event is judged to be minor to major,
depending on the meteorological conditions at the time of the accident. As previously
noted with respect to the conservative mixing scenario, emissions of HC1 were
estimated using a mass balance approach, and are likely to be a significant
overestimate.
4. Off-Site Spill
Four off-site spill events are evaluated:
Conservative off-site spill of 5,000 gallons of liquid waste consisting of a 10%
formaldehyde/90% methanol mixture.
Conservative off-site spill of 5,000 gallons of liquid waste consisting of a 10%
acetone/90% toluene mixture.
Typical off-site spill of 100 gallons of liquid waste consisting of a 10%
formaldehyde/90% methanol mixture.
/
Typical off-site spill of 100 gallons of liquid waste consisting of a 10%
acetone/90% toluene mixture.
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The results of these events are summarized in Tables VI-14 and VI-15, and are discussed
below.
a) Conservative Spill of Formaldehyde-Containing Waste
Under typical meteorological conditions, LOG and IDLH values for
formaldehyde are predicted to be exceeded up to approximately 1,490 m and 980 m
downwind of the spill, respectively. Under conservative meteorological conditions,
LOG and IDLH values are predicted to be exceeded up to approximately 8,490 m and
5,120 m downwind, respectively. Under calm/inversion conditions, LOG and IDLH
values are predicted to be exceeded up to approximately 12,400 m and 9,050 m,
respectively.
Based on the .distances over which the IDLH and LOG values could potentially be
exceeded, the severity of consequence of this event is judged to be major to
catastrophic, depending on the meteorological conditions.
b) Conservative Spill of Acetone-Containing Waste
In the event of a large spill of acetone-containing waste, LOG and IDLH values
are predicted to be exceeded only immediately adjacent to the spill under typical
meteorological conditions. Under both conservative and calm/inversion
meteorological conditions, the LOG value for acetone is predicted to be exceeded up
to approximately 60 m downwind. The IDLH value for acetone is predicted to be
exceeded up to approximately 50 m downwind under both conservative and
calm/inversion meteorological conditions. On this basis, the severity of consequence
is judged to be minor to moderate depending on the meteorological conditions at the
time of the spill.
c) Typical Spill of Formaldehyde-Containing Waste
Under typical meteorological conditions, the LOG and IDLH values for
formaldehyde are predicted to be exceeded up to approximately 190 m and 130 m
from the spill, respectively. Under conservative meteorological conditions, the LOG
and IDLH values are predicted to be exceeded up to approximately 980 m and 630 m
downwind, respectively. Under calm/inversion conditions, the LOG and IDLH
values are predicted to be exceeded up to approximately 1,670 m and 1,080 m,
respectively. ''
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On the basis of the analysis described above, the severity of consequence for this
event is judged to be major to catastrophic (based on IDLH values) and moderate to
major (based on LOG values), depending on meteorological conditions.
d) Typical Spill of Acetone-Containing Waste
LOG and IDLH values for acetone are predicted to be exceeded only over a
relatively short distance (i.e., less than 10 m) under all meteorological conditions.
Thus, the severity of consequence for this event is judged to be minor.
5. Off-Site Fire
Two off-site fire events are evaluated:
A fire involving a spill of 5,000 gallons of waste containing 15%
tetrachloroethene and 85% toluene, resulting in HC1 and phosgene emissions.
A fire involving a spill of 100 gallons of waste containing 15% tetrachloroethene
and 85% toluene, resulting in HC1 and phosgene emissions.
The results of the off-site fire events are summarized in Tables VI-16 and VI-17, and are
discussed below. These events have been evaluated using the ISC-COMPDEP model
under typical and conservative meteorological conditions. Fire events under
calm/inversion conditions are discussed in Section C of Chapter VII.
a) Conservative Fire Scenario
In the off-site fire scenario, under typical meteorological conditions, LOC and
IDLH values for HC1 and phosgene are not predicted to be exceeded. Under
conservative meteorological conditions, LOC values are predicted to be exceeded up
to approximately 2,100 m (for HC1) an^ 1,100 m (for phosgene), while IDLH values
are predicted to be exceeded up to approximately 275 m (for HC1) and 125 m (for
phosgene). Any exceedances of IDLH or LOC values which occur would be in
"pockets", with the site and location of these pockets dependent upon terrain elevation
in the vicinity of the accident.
Based on the results of the ARCHIE model, the fatality zone radius for heat
effects would be 40 m, and the injury zone radius would be approximately 60 m,
assuming the fire did not occur until the spill area reached its maximum size. If the
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fire were to start at the time of the discharge, the fatality and injury zone radii would
be reduced to approximately 35 m and 50 m, respectively.
If a fireball were to form, the ARCHIE model predicts a fatality zone radius of
approximately 170 m, and an injury zone radius of approximately 340 m. As
discussed in Chapter IV of this report, it is highly unlikely that a fireball would form
given the types of wastes transported to the WTI facility.
On the basis of potential HC1 and phosgene emissions, the large off-site fire is
judged to have minor consequences under typical meteorological conditions. Under
conservative meteorological conditions, this event is predicted to have major
consequences (based on IDLH values) or catastrophic consequences (based on LOC
values).
Given the potential heat effects of the fire, the severity of consequence ranking
for a fire under "typical" meteorological conditions is increased to moderate. In the
event of a fireball, the severity of consequence would be classified as major;
however, the potential for a fireball is very low.
b) Typical Fire Scenario
In the typical off-site fire scenario, LOC and IDLH values for HC1 and phosgene
are not expected to be exceeded.
In the off-site fire scenario involving a 100 gallon spill, the fatality zone radius
for heat effects is 9 m, and the injury zone radius is 13m, assuming the fire does not
occur until the spill area reached its maximum size. If the fire is assumed to start
during the discharge, the fatality and injury zone radii decrease to 5 m and 7 m,
respectively.
If a fireball formation is assumed, the ARCHIE model predicts a fatality zone
radius of 20 m, and an injury zone radius of 45 m. However, a fireball is not likely
to form in a typical off-site fire scenario due to the small size of the spill leading to
the fire.
Although IDLH and LOC values are not expected to be exceeded, the typical off-
site fire event is categorized as moderate due to the potential for heat effects over
10 m from the spill location. In the event of a fireball, the severity of consequence
would be classified as moderate; however, the potential for a fireball is very low.
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B. Probability of Occurrence
1. On-Site Events
As discussed in Chapter I, the probability of occurrence in an Accident Analysis can
be assessed qualitatively, semiquantitatively or quantitatively. In this Accident Analysis.
the probability of occurrence has been assessed semiquantitatively, based on the data
available for the specific accident scenario. Furthermore, the probability rankings that are
assigned correspond to accident classes, rather than specific accident events. This
approach was adopted given the limited information available on the likelihood of specific
events, as discussed below.
As discussed in Chapter I, the U.S. EPA Report on Emergency Incidents at
Hazardous Waste Incinerators and Commercial Treatment, Storage, and Disposal
Facilities (TSDFs) (U.S. EPA 1995b) provides information regarding incidents reported at
hazardous waste facilities. A total of 50 emergency incidents, as defined by U.S. EPA,
were reported at the hazardous waste incinerators identified in the study. For commercial
hazardous waste incinerators only, 24 emergency incidents at 11 facilities were reported,
with 10 involving a release of hazardous waste. No emergency incidents have been
reported at 15 commercial incineration facilities, so these facilities were not discussed in
U.S. EPA (1995b). In all, 26 commercial hazardous waste incineration facilities were
identified to have operated in the U.S. sometime during the period from 1981 through
1994.
The total operating time for the 26 commercial incinerators during the time period
considered by the study is approximately 250-300 years. This operating time total is
conservative, since no information was available for operations before 1981, and no
operating dates were available for two facilities. Thus, approximately one emergency
incident involving a hazardous waste release has been reported for every 25 to 30 years of
operation for the commercial incinerators. None of the 10 incidents reported at
commercial combustion facilities involving releases of hazardous waste has resulted in a
fatality or serious injury in off-site communities, although on-site worker injuries and
fatalities have been reported (U.S. EPA 1995b).
According to the U.S. EPA Chemical Emergency Preparedness and Prevention Office
(CEPPO), the Emergency Response Notification System (ERNS) database includes first-
hand reports of incidents. Further detailed information on selected incidents from ERNS
is maintained in the Accidental Release Inventory Program (ARIP) database. However,
neither the ERNS nor ARIP databases provide comprehensive information on incidents at
specific incinerators or other TSDFs (Chung 1995). Finally, the RCRA Corrective Action
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database and the Bureau of Labor Statistics database do not provide relevant information
specific to incidents at hazardous waste TSDFs. In summary, a rigorous quantitative
analysis for hazardous waste-related accidents can not be performed based solely on data
from the operating history of commercial hazardous waste incinerators or TSDFs.
The probability of occurrence rankings for on-site events are presented in
Table VI-18. These rankings, which are based on the FEMA (1993) guidelines, do not
explicitly take into account WTI procedures and design features for preventing spills,
leaks, fires, and mixing of incompatible wastes, as discussed in Chapter II, and are thus
considered conservative. Furthermore, the probability of occurrence rankings correspond
to accident classes rather than specific accident events. For example, the probability
ranking presented hi Table VI-18 for a 100 gallon spill of acetone waste reflects the
overall probability of a "typical" sized spill of "typical" wastes received by the WTI
facility in relatively high volumes.
The bases for the probability of occurrence rankings for the various on-site accident
events are discussed separately below.
a) On-Site Spill
(5) Spill Size
The summary of incidents reported at the WTI facility (Table 3 of
Appendix VII-1) indicates that while there have been 5 spills of 20 gallons or less
in approximately 2 years of operation at the WTI facility, no spills greater than
20 gallons have been reported.
As documented in Table 1 of Appendix VII-1, several spills of 50 gallons or
more have been reported at commercial hazardous waste incineration facilities in
the U.S. since 1981. While data for quantifying the frequency of larger or more
spills at commercial hazardous waste incinerators are very limited, experience at
the WTI facility and the information summarized in Appendix VII-1 suggests that
spills of approximately 100 gallons would be expected to occur at a frequency of
less than once per year at the WTI facility. For example, according to the
information in Table 1 of Appendix VII-1, only three on-site spills involving
between 50 gallons and 500 gallons of waste have been reported in more than 250
total years of operation at commercial hazardous waste combustors in the U.S.
However, given limitations of the existing information, it'is conservatively
assumed in the Accident Analysis that spills of approximately 100 gallons could
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occur with a frequency between once per year and once per 10 years at the WTI
facility. .
Larger (e.g., 5,000 gallon) spills are generally expected to be less likely to
occur than small spills. For example, available data on the distribution of spill
sizes from full-size tankers during highway transit between 1971 and 1986
indicate that 70% of all spills were 20 gallons or more; 40% were 100 gallons or
more, but only 5% were 5,000 gallons or more (U.S. DOT 1986). Thus spills of
approximately 5,000 gallons are estimated to be approximately 10-fold less likely
to occur than spills of approximately 100 gallons. On this basis, a frequency of
occurrence of once in 10 years to once in 100 years was estimated for a large
(5,000 gallon) spill at the WTI facility. This is consistent with the information
provided in Table 1 of Appendix VII-1, which reports three spills with volumes
between 1,000 gallons and 10,000 gallons at hazardous waste incineration
facilities over 250 years of total operation (a frequency of one large spill for
every 50 to 100 years of operation).
(ii) Waste Composition
A range of waste types (from low hazard to high hazard) could be involved
in an on-site spill. Given information on waste composition from the first nine
months of operation at WTI, the likelihood of a "typical" waste spill is
considerably lower than the likelihood of a "worst-case" waste spill.
For example, acetone (selected as the chemical of concern in a "typical"
waste mixture) represents approximately 3 % of the total pumpable waste feeds
based on Waste profiles for the first nine months of operation, while
formaldehyde (selected as the chemical of concern in a "worst-case" waste
mixture) represents only approximately 0.5% of the total pumpable feeds.
While acetone itself represents only approximately 3 % of the total pumpable
waste feeds, it was selected in the Accident Analysis as the chemical of concern
for the entire class of wastes that represent the "typical" or "average" hazard.
Thus, the frequency for a spill of "typical" waste was conservatively set equal to
the overall frequency of a spill (i.e., between once in 1 year and once in 10 years
for a 100-gallon spill, and between once in 10 years and once in 100 years for a
5,000-gallonspill).
In the same way, formaldehyde was selected in the Afcident Analysis as the
chemical of concern for the entire class of wastes that represent a reasonable
"worst-case" hazard. Thus, while formaldehyde represents only approximately
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0.5% of the total pumpable waste streams, "worst-case" wastes are
conservatively assumed to represent 10% of the total pumpable wastes. Thus,
spills of "worst case" waste were assigned a frequency of occurrence 10-fold .
lower than the frequency for spills of "typical" wastes (i.e. between once in
10 years and once in 100 years for a 100 gallon spill, and between once in
100 years and once in 1,000 years for a 5,000-gallon spill).
(iii) Meteorological Conditions
It is less likely that spills will occur during conservative or calm/inversion
meteorological conditions than during typical meteorological conditions.
Conservative conditions, which reflect a stable atmosphere along with low wind
speeds (<2.0 m/s), would be expected to occur less than 10% of the hours in a
year, according to the meteorological data discussed in Chapter V. The calm/
inversion scenarios evaluated in this analysis (a calm period of at least one hour
followed immediately by a period of stable atmosphere with windspeed less than
2.0 m/s), would be expected to occur less than 5% of the hours in a year. For
example, based on the one-year hourly surface meteorological data (April 1992 -
March 1993) recorded at the WTI site, a stable atmosphere (F-stability) with low
wind speed (windspeeds between 1.0 and 1.5 m/s) would occur immediately after
a calm hour only approximately 1.7% of the time.
The "typical" meteorological condition is selected in the Accident Analysis
to represent average conditions near the WTI facility. Thus, the frequency of a
spill during "typical" meteorological conditions was conservatively set equal to
the frequency of a spill under any type of condition. Since "conservative"
meteorological conditions occur less than 10% of the year, a spill under such
conditions was estimated to be 10-fold less likely to occur than a spill under
"typical" meteorological conditions. Since "calm/inversion" meteorological
conditions occur less than 5 % of the year, a spill under such conditions was
estimated to be 20-fold less likely to occur than a spill under "typical"
conditions.
(iv) Summary, On-Site Spill
On the basis of the information provided above, the estimated frequencies of
occurrence for the on-site spill scenarios at the WTI facility are summarized
below.
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Qn-site Spill. "Typical" waste.
100 gallons
"typical" conditions
"conservative" conditions
"calm/inversion" conditions
On-site Spill. "Typical" waste.
5.000 gallons
"typical" conditions
"conservative" conditions
"calm/inversion" conditions
On-site Spill. "Worst-Case" waste.
100 gallons
"typical" conditions
"conservative" conditions
"calm/inversion" conditions
Estimated
Frequency of Occurrence
1 in 1 year - 1 in 10 years
1 in 10 years - 1 in 100 years
1 in 20 years - 1 in 200 years
1 in 10 years - 1 in 100 years
1 in 100 years - 1 in 1,000 years
1 in 200 years - 1 in 2,000 years
1 in 10 years - 1 in 100 years
1 in 100 years - 1 in 1,000 years
1 in 200 years - 1 in 2,000 years
On-site Spill. "Worst-Case" waste.
5.000 gallons
"typical" conditions
"conservative" conditions
"calm/inversion" conditions
1 in 100 years - 1 in 1,000 years
1 in 1,000 years - 1 in 10,000 years
1 in 2,000 years - 1 in 20,000 years
It should be emphasized that the frequencies of occurrence listed above are
order-of-magnitude estimates only and are based on limited data and information.
To offset uncertainties, conservative approaches have been taken in developing
these estimates.
b) On-Site Fire
Data on the frequency of fires at hazardous waste incineration facilities and other
TSDFs are very limited. Relatively few fires have been reported since 1981, when
reporting under RCRA began. Thus, there is considerable uncertainty in estimating
the frequency of occurrence for an on-site fire at the WTI facility.
The likelihood of ignition in the event of a spill depends on a number of factors,
including the flammability of the waste, the proximity of an ignition source, and
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atmospheric conditions. Based on data from oil refinery operations, Battelle (1987)
estimated an ignition frequency of one in every 25 spills at a proposed hazardous
waste facility. On this basis, it could be estimated that on-site fires are 25-fold less
likely to occur than on-site spills. However, given the limitations in available data.
and the possibility that events other than spills could lead to a fire involving
hazardous waste, the frequency of on-site fires is estimated to be approximately 10-
fold lower than the frequency of on-site spills. The resulting estimated frequencies of
occurrence for on-site fire scenarios are summarized below:
On-site fire. 200 gallons
"typical" conditions
"conservative" conditions
"calm/inversion" conditions
Estimated
Frequency of Occurrence
1 in 10 years - 1 in 100 years
1 in 100 years - 1 in 1,000 years
1 in 200 years - 1 in 2,000 years
On-site fire. 20.000 gallons
"typical" conditions
"conservative" conditions
"calm/inversion" conditions
1 in 100 years - 1 in 1,000 years
1 in 1,000 years - 1 in 10,000 years
1 in 2,000 years - 1 in 20,000 years
These frequencies do not take into account the reduced probability that chlorinated
wastes would be involved in the fire, and thus are expected to result in an
overestimate of the likelihood of adverse consequences. These frequencies are also
considered conservative because the fire events involve larger waste volumes than the
corresponding spill events (i.e., 5,000 gallons for the large on-site spill vs. 20,000
gallons for the large on-site fire, and 100 gallons for the typical on-site spill vs. 200
gallons for the typical on-site fire).
c) On-Site Mixing of Incompatible Wastes
Data on the frequency of incidents involving the mixing of incompatible wastes at
hazardous waste incineration facilities and other TSDFs are very limited. As shown
in Table 2 of Appendix VII-1, very few such incidents have been reported at other
TSDFs since 1981. However, based on U.S. EPA (1995b), if'does not appear that
incidents involving mixing of incompatible wastes are any more likely to occur than
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fires. Thus, the estimated frequencies of occurrence assumed for on-site fires are also
assigned for mixing of incompatible wastes, as shown below:
Estimated
Frequency of Occurrence
On-site mixing of incompatible wastes.
200 gallons
"typical" conditions 1 in 10 years - 1 in 100 years
"conservative" conditions 1 in 100 years - 1 in 1,000 years
"calm/inversion" conditions 1 in 200 years - 1 in 2,000 years
On-site mixing of incompatible wastes.
10.000 gallons -
"typical" conditions 1 in 100 years - 1 in 1,000 years
"conservative" conditions 1 in 1,000 years - 1 in 10,000 years
"calm/inversion" conditions 1 in 2,000 years - 1 in 20,000 years
Given the lack of frequency data for events involving mixing of incompatible wastes,
there is considerable uncertainty associated with these rankings.
2. Off-Site Events
The probability of occurrence rankings are assigned to the off-site spill events based
on the general guidance provided in U.S. EPA (1987) and FEMA (1993). These rankings
are presented in Table VI-19 and correspond to the likelihood of an event along the local
access route in East Liverpool. The basis for the probability rankings for the various off-
site accident events are discussed separately below.
a) Off-Site Spill
Site-specific calculations used to calculate the off-site accident and spill frequency
of trucks carrying waste to WTI are described in Appendix VII-5. Spills may occur
during waste transport as a result of both major accidents and minor valve and fitting
leaks. Based on an evaluation of site-specific traffic accident data, a collision-related
spill involving trucks bringing waste to the WTI facility is estimated to have
approximately a 1 in 60 chance of occurring each year on State Route 39 (SR 39) in
East Liverpool, Ohio. Non-collision related spills are estimated to have
approximately a 1 in 40 chance of occurring each year on the same route.
Considering both collision and non-collision related releases, and based on data
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regarding spill size, a spill of greater than 100 gallons is estimated to have a 1 in 60
chance of occurring each year. A spill of greater than 5,000 gallons is estimated to
have a 1 in 295 chance of occurring each year. On this basis, a frequency of
occurrence between once in 10 years and once in 100 years was estimated for a small
(100 gallon) spill, and a frequency of occurrence between once in 100 years and once
in 1,000 years was estimated for a large (5,000 gallon) spill.
The likelihood of a spill occurring during transport of waste to the WTI facility
can also be roughly approximated using national data for 1991, the most recent year
for which data on the total quantity of hazardous waste shipped in the U.S. are
available (U.S. EPA 1994b). Based on U.S. EPA (1994b), there were approximately
15 million tons of hazardous waste transported within the United States in 1991.
During that same .year, there were 175 highway-related incidents involving hazardous
waste, with an average spill size of 92 gallons (U.S. DOT 1995). Thus, there was
approximately one incident per every 75,000 tons of hazardous waste transported on
the highway. According to the RCRA permit for the WTI incinerator (U.S. EPA
1983), up to approximately 75,000 tons of waste is allowed to be incinerated at the
WTI facility each year. Thus, one transportation-related incident might be expected
during each year of operation at the WTI facility over the entire transportation
network for the facility. The number of incidents resulting in a spill along the local
access roads in East Liverpool only would be considerably lower.
Data are also available on the frequency of injuries during transport of hazardous
waste. In 1991, 25 injuries (and no fatalities) were reported to result from the 175
highway-related incidents reported by U.S. DOT (1995), or approximately one injury
for every 7 incidents. All injuries listed in U.S. DOT (1995) were the result of
chemical exposure (Duyzh 1995). On this oasis, it can be estimated that there is
approximately a 1 in 7 chance that an exposure-related injury might occur each year
over the entire generator-to-WTI transportation route, although the likelihood of an
injury along the local access route in East Liverpool only would be considerably
lower.
Estimating the frequency of fatalities due to chemical exposure during the
transport of hazardous waste requires that data collected over a larger time span be
reviewed. During the 10 years between 1984 and 1993, there were one fatality and
143 injuries reported involving highway transport of hazardous waste (U.S. DOT
1995). For highway transport of hazardous materials, there were 115 fatalities and
2,781 injuries. Thus, it can be estimated that there is between 1 fatality for every 25
injuries (using the hazardous materials data) and 1 fatality for every 140 injuries
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(using the hazardous waste data). Based on the 1 in 7 probability for an injury each
year along the overall WTI transportation route, there would be between 1 chance in
175 and 1 chance in 980 each year of an exposure-related fatality along the overall
generator to WTI transportation route. Again, the likelihood of a fatality along the
local access route in East Liverpool only would be lower.
Considering the U.S. DOT and U.S. EPA data summarized above, the estimated
frequencies of occurrence assigned for the off-site spill scenarios are shown below.
These frequencies reflect the analysis of the relative frequency of different spill sizes.
waste compositions, and meteorological conditions discussed in Section VI.B.I.
Off-site Spill. "Typical" waste.
100 gallons
"typical" conditions
"conservative" conditions
"calm/inversion" conditions
Off-site Spill. "Typical" waste.
5.000 gallons
"typical" conditions
"conservative" conditions
"calm/inversion" conditions
Off-site Spill. "Worst-Case" waste.
100 gallons
"typical" conditions
"conservative" conditions
"calm/inversion" conditions
Off-site Spill. "Worst-Case" waste.
5.000 gallons
"typical" conditions
"conservative" conditions
"calm/inversion" conditions
Estimated
Frequency of Occurrence
1 in 10 years - 1 in 100 years
1 in 100 years - 1 in 1,000 years
1 in 200 years - 1 in 2,000 years
1 in 100 years - 1 in 1,000 years
1 in 1,000 years - 1 in 10,000 years
1 in 2,000 years - 1 in 20,000 years
1 in 100 years - 1 in 1,000 years
1 in 1,000 years - 1 in 10,000 years
1 in 2,000 years - 1 in 20,000 years
1 in 1,000 years - 1 in 10,000 years
1 in 10,000 years - 1 in 100,000 years
1 in 20,000 yeaps - 1 in 200,000 years
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VI-20
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It should be emphasized that the frequencies of occurrence listed above are order-
of-magnitude estimates only and are based on limited data and information. To offset
uncertainties, conservative approaches have been taken in developing these estimates..
b) Off-Site Fire
As previously discussed, there is considerable uncertainty in estimating the
likelihood of a fire resulting from a spill. The likelihood of a fire depends on the
nature of the waste spilled, and the proximity of an ignition source, among other
factors. Based on data from oil refinery operations, Battelle (1987) estimated a fire
frequency of one in every 25 spills. According to data cited in FEMA (1993),
approximately 1 % of most types of truck accidents result in a fire; this corresponds to
a fire frequency of approximately one in every 20 to 50 spills. On this basis, the
frequency of off-site fires is estimated to be approximately 20-fold lower than the
frequency of off-site spills.
Considering the estimated likelihood of an off-site spill, and the reduced
likelihood of a spill leading to a fire, the estimated frequency of occurrence assumed
for the off-site fire events are shown below:
Off-site fire. 100 gallons
"typical "'conditions
"conservative" conditions
"calm/inversion" conditions
Off-site fire. 5.000 gallons
"typical" conditions
"conservative" conditions
"calm/inversion" conditions
Estimated
Frequency of Occurrence
1 in 200 years - 1 in 2,000 years
1 in 2,000 years - 1 in 20,000 years
1 in 4,000 years - 1 in 40,000 years
1 in 2,000 years - 1 in 20,000 years
1 in 20,000 years - 1 in 200,000 years
1 in 40,000 years - 1 in 400,000 years
These frequencies do not take into account the probability of chlorinated wastes being
involved in the fire, and thus may overestimate the likelihood of adverse
consequences.
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C. Summary of Results and Key Assumptions
1. On-Site Events
The severity of consequence and probability of occurrence results based on IDLH and
LOG values for on-site accident scenarios are summarized in Table VI-20. As shown in
Table VI-20, only on-site events with "minor" off-site consequences are judged "likely" to
occur at the WTI facility, and only on-site events with "minor" or potentially "moderate"
off-site consequences are judged to be "reasonably likely" to occur. All on-site accident
scenarios with potentially "major" off-site consequences are judged "unlikely" to occur.
All on-site accident scenarios with potentially "catastrophic" off-site consequences are
judged "very unlikely" to occur.
The results of the.Accident Analysis described in this report are consistent with the
results of the Credible Event Analysis performed by S.E. Technologies (1992) for WTI.
The results of the Credible Event Analysis (SE Technologies 1992) are not directly
comparable to the results of this Accident Analysis, because the Credible Event Analysis
compared downwind distances to U.S. EPA Level of Concern (LOG) values, rather than
IDLH values. However, the results of one type of accident, mixing of incompatible
wastes, can be compared. In both the Credible Event Analysis and the current Accident
Analysis, the mixing of incompatible waste scenario resulted in the potential for
significant off-site exposures. In the Credible Event Analysis, a "hazard distance" (i.e.,
distance over which an LOC would be exceeded) was calculated to be approximately
7,000 m for the mixing of incompatible waste scenario. As shown in Table VI-13, in this
Accident Analysis the downwind distance over which an LOC is predicted to be exceeded
for a comparable mixing of incompatible waste scenario ranges from 1,780 m to
12,200 m, depending on the meteorological conditions. Consistent with this Accident
Analysis, the Credible Event Analysis determined that the probability of occurrence for
this type of accident is low. The results of the Credible Event Analysis and this Accident
Analysis for the other types of on-site events (i.e., spills and fires) are also comparable,
with "hazard distances" potentially extending several hundred meters downwind due to
spills, and potential heat effects off-site due to major fires. However, this Accident
Analysis examined several scenarios involving large spills of very toxic, volatile waste not
- considered in the Credible Event Analysis, and thus has projected greater possible
consequences associated with spill events.
Given limitations in available data, it is difficult to compare the accidental risks
associated with operation of the WTI facility with similar risks posed by other types of
industrial facilities. USEPA maintains the Accidental Release Information Program
Volume VII VI-22
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(ARIP) to contain information from facilities that have reported accidental releases since
1986 that resulted in off-site consequences or environmental damage. According to the
ARIP, since 1986, there have been 169 incidents resulting in off-site consequences or
environmental damage at industrial facilities involved in the manufacture of chemicals and
allied products. Of the 169 reported incidents, four resulted in off-site injuries; these four
incidents resulted in 1,062 injuries, 107 hospitalizations, and no fatalities.
The potential for accidents at large industrial operations (such as those involved in the
manufacture of chemicals and allied products) was evaluated in the Quality Assurance
Review of the Kanawha Valley Hazard Assessments (JBF Associates 1994). This report
summarized the results of hazard assessments performed at ten facilities located in the
Kanawha Valley (located in the vicinity of Charleston, WV). A total of 72 chemical
release scenarios were.modeled; each assessment included "worst-case" and "more-
probable" release scenarios for the three most hazardous chemicals at the facility. Results
of the assessments included the following:
For "worst-case" release scenarios, hazard zones ranged up to approximately
60,000 meters. Approximately 50% of the "worst-case" hazard zones were
larger than approximately 9,500 meters. By comparison, the largest predicted
distance to an LOG value in the Accident Analysis is 14,100 m. The only three
individual emission scenarios evaluated in the Accident Analysis for which LOC
values are predicted to be exceeded over a distance of 9,500 m or more are: 1)
the on-site mixing of 10,000 gallons of incompatible wastes (12,200 m, under
calm/ inversion conditions); 2) the on-site spill of 5,000 gallons of "worst case"
waste (14,100 m, under calm/inversion conditions); and 3) the off-site spill of
5,000 gallons of "worst case" waste (12,400 m, under calm/ inversion
conditions).
For "more-probable" release scenarios, hazard zones ranged up to approximately
9,500 meters. Approximately 40% of the "more-probable" hazard zones were
greater than approximately 3,000 meters.
It is not possible to directly compare the results of the Kanawha Valley study to the results
of the Accident Analysis. For example:
>'
The Kanawha Valley study was based on ERPG-2 and ERPG-3 toxicity criteria,
while the WTI Accident Analysis uses IDLH and LOC values. For the chemicals
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evaluated in the Accident Analysis, LOG values are generally more stringent than
ERPG-2 values, but less stringent than the ERPG-3 values. IDLH values are
usually less stringent than ERPG-2 values, and may be more or less stringent
than ERPG-3 values.
Potential off-site receptor locations are not specified for the Kanawha Valley
study.
The Kanawha Valley Study did not attempt to quantify the probability of
occurrence for individual accident scenarios.
The results of the Kanawha Valley Study do suggest, however, that events with potentially
significant off-site consequences could theoretically occur at large industrial facilities,
although the likelihood of these events is low.
Many smaller, more common facilities (e.g., gasoline stations, dry cleaning
establishments, swimming pools) also receive relatively large quantities of materials which
could be hazardous in the event of a spill or fire. For example, in the ARIP data base, a
total of 11 incidents were reported for the services group. Of these 11 incidents, most
involved releases of chlorine or ammonia, and resulted in a total of 54 injuries,
12 hospitalizations, and no fatalities. These injuries were all caused by releases from
facilities in the amusement and recreational class of the services group. Furthermore, the
average gas station receives over 1,000,000 gallons of gasoline (which is highly
flammable and contains benzene) each year (U.S. DOE 1996; USDOC 1995).
2. Off-Site Events
The severity of consequence and probability of occurrence results for off-site accident
scenarios are summarized in Table VI-21. For the off-site accident scenarios, events with
minor consequences were determined to be at most, reasonably likely to occur. Off-site
accidents with potentially moderate or major consequences are judged to be unlikely or
very unlikely to occur. Events classified as having potentially catastrophic consequences
were determined to be very unlikely to occur.
The Credible Event Analysis performed by S.E. Technologies (1992) for WTI did not
assess off-site accidents. However, the results of the Accident Analysis can be considered
in the context of the general transportation of hazardous materials. 'Hazardous materials
include products (such as gasoline) and feedstocks (such as chlorine gas) as well as
hazardous waste. According to data from the U.S. Department of Transportation (DOT),
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approximately 1.5 billion tons of hazardous materials are transported annually in the U.S.
(Asp 1990). This includes approximately 10 million tons of hazardous waste,
representing less than one percent of the total hazardous materials. Over the ten years
from 1980 to 1989, there were over 3,200 injuries and over 130 fatalities associated with
releases during transportation of hazardous materials. Over the same ten-year period,
there were a total of 64 injuries and one fatality associated with releases during
transportation of hazardous waste in the U.S. Thus, hazardous waste accounted for less
than one percent of fatalities and two percent of injuries due to releases during transport of
hazardous materials (Asp 1990). On this basis, transportation of hazardous waste poses a
lower overall hazard than the transportation of hazardous materials, and the potential
health consequences associated with transportation accidents involving hazardous waste
are comparable to those associated with accidents involving hazardous materials.
3. Summary of Major Assumptions
Major assumptions made in ranking the accident events according to severity of
consequence and likelihood of occurrence are listed in Table VI-22.
D. Screening-Level Evaluation for East Elementary School
1. Background and Objectives
In the Report on the USEPA Technical Workshop on WTI Incinerator Risk Assessment
Issues (U.S. EPA 1996b), the Peer Review Panel recommended that an evaluation of
worst-case chemical concentrations at the East Elementary School be included in the
Accident Analysis. As shown in Figure II-3, the East Elementary School is located
approximately 1,000 feet to the north of the WTI incinerator. Due to the topography of
the area, which includes a steep river valley oriented in the east-northeast direction, the
East Elementary School is located on a terrace at a ground elevation approximately 15
meters higher than that of the WTI site.
Consistent with the Peer Review Panel comments, a screening-level evaluation has
been performed to compare hypothetical worst-case chemical concentrations with acute
toxicity criteria to identify the specific accident scenarios with the greatest potential to
cause adverse health consequences at the school. The hypothetical worst-case chemical
concentrations have been estimated using the emission and dispersion modeling results
described in Chapters IV and V. These concentrations are compared to U.S. EPA Level
of Concern (LOG) toxicity criteria. The likelihood (i.e., probability of occurrence) that
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accidents would result in chemical releases that could actually reach the school is also
evaluated.
Given the uncertainties of this analysis, and the highly protective approaches and
assumptions used to address those uncertainties, the results of the screening-level
evaluation should not be viewed as a realistic measure of the absolute level of exposure or
risk. Instead, this evaluation has been performed to provide a basis to better understand
and compare the relative hazard of the various accident scenarios, and to provide
additional information for the local emergency planning and preparedness process.
2. Estimation of Chemical Concentrations
In the Accident Analysis, "events" are defined by the type of release (i.e., spills,
mixing of incompatible wastes, or fire), the location of the accident (i.e., on-site or off-
site), the size of release (i.e., "typical" volume or "conservative" volume), and the
relative hazard of the chemicals involved (i.e., "typical" or "worst case"). Each event is
comprised of different "scenarios" specific to meteorological conditions (i.e., typical,
conservative or calm/inversion) and whether or not mitigation is assumed to occur (i.e.,
mitigation after 10 minutes, or no mitigation). A total of 18 events, comprising 84
scenarios, were identified for evaluation and are listed in Table VI-23.
For each of the 18 accident events identified for evaluation in the Accident Analysis,
one or more "surrogate" chemicals were identified to assist in evaluating the potential for
adverse health consequences. Each of these surrogate chemicals was selected to represent
an entire class of constituents that could potentially be released. For example, for the spill
scenarios, formaldehyde was selected as the surrogate "worst-case" chemical based on its
toxicity and volatility, while acetone was selected as the surrogate "typical" chemical.
Downwind concentrations calculated for the surrogate chemicals selected for each
accident event are summarized in Tables V-2 through V-6. In Tables V-2 through V-6,
concentrations are presented for typical, conservative, and calm/inversion meteorological
conditions at distances of 100 meters, 500 meters, 1,000 meters, and 2,000 meters
downwind from the location of the hypothetical release. For the on-site accident
scenarios, the downwind distance from the location of the release to the school would be
approximately 350 meters. For the off-site accident scenarios, which are assumed to
occur at the location shown in Figure II-3, the downwind distance to the school would be
approximately 790 meters. Based on the emission and dispersion modeling used to
estimate the downwind concentrations presented in Tables V-2 through V-6, the estimated
surrogate chemical concentrations at the distance to the school are presented in
Table VI-23 for each accident scenario. Concentrations are presented for each of the
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meteorological conditions evaluated; for on-site events, results with and without active
mitigation are shown, while no active mitigation is assumed for the off-site events.
For the accident scenarios involving mixing of incompatible wastes or volatile
releases from spills, the concentrations in Table VI-23 correspond to the approximate
distance to the school, but do not necessarily reflect the actual terrain elevation of the
school, which is approximately 15 meters higher than ground level at the hypothetical
location of the release. As discussed in Chapter V, downwind concentrations for the spill
and mixing of incompatible waste events are calculated using the SLAB dispersion model,
which assumes flat terrain. However, both the spill and mixing of incompatible waste
accident scenarios involve emissions of "worst-case" surrogate chemicals which are
denser than air, and would have limited dispersion to the height of the school. For
example, a ground level dense gas plume may not have sufficient energy to rise to the
level of the school and, as a result, may flow around the high elevation areas. Thus, the
surrogate chemical concentrations presented in Table VI-23 are generally higher than
would be estimated for dense gases at the height of the school for the spill and mixing of
incompatible waste scenarios.
SLAB and other EPA-reviewed dispersion models for evaluating dense gases do not
account for terrain effects and cannot be used to more accurately estimate concentrations
at the height of the school. To develop a better understanding of how terrain effects might
influence concentrations at the height of the school, a sensitivity analysis for the spill and
mixing of incompatible waste scenarios has been performed using the ISC1 dispersion
model. As discussed in Chapter V, the ISC-COMPDEP model has been used in the
Accident Analysis to estimate off-site surrogate chemical concentrations in the event of an
accidental fire. Unlike the SLAB model, ISC-COMPDEP can account for both terrain
effects (such as the elevation of the school relative to the accidental release elevation) and
building wake effects. It also allows for the modeling of a point source release, consistent
with the accident scenario involving the mixing of a large volume of incompatible wastes.
Because ISC-COMPDEP cannot model short-term, non-continuous, dense-gas releases, it
was assumed in the sensitivity analysis that the chemical emissions would have neutral
buoyancy. Although the effect of this assumption may vary depending on the type of
release, it would not be expected to underestimate concentrations for the scenarios
considered in the sensitivity analysis.
Based on dispersion modeling using the ISC model, estimated concentrations at the
height of the school may be up to 10-fold lower than those estimated using the SLAB
In this sensitivity analysis, ISCST3 (Version 96113) was used. ISCST3 is a recent update of the ISC-
COMPDEP model, and shares the same basic algorithms of ISC-COMPDEP.
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model, depending on the nature of the release and the atmospheric conditions. Although
more rigorous dispersion modeling would be necessary to better refine estimated surrogate
chemical concentrations at the school, the sensitivity analysis based on the ISC model
indicates that expected concentrations at the height of the school could be considerably
lower than those calculated using the SLAB model. For the purposes of this screening-
level evaluation, however, the results of the SLAB modeling only have been used to
estimate worst-case surrogate chemical concentrations at the distance to the school, and
are presented in Table VI-23.
3. Comparison of Concentrations to Acute Toxicity Criteria
As discussed in Chapter III, the acute toxicity criteria considered in the Accident
Analysis are the Immediately Dangerous to Life or Health (IDLH) values, the Emergency
Response Planning Guideline-Level 2 (ERPG-2) values, and the Level of Concern (LOG)
values. For the surrogate chemicals in this evaluation, the LOG values are generally
lower (i.e., more stringent) than either the IDLH or ERPG-2 values. Given the objectives
of this screening-level evaluation, LOG values are compared against the estimated worst-
case concentrations to identify those accident scenarios with the greatest potential to cause
adverse health consequences at the East Elementary School.
To evaluate the potential for adverse health consequences at the distance to the
school, a Relative Hazard Ratio (RHR) was calculated for each accident scenario:
RHR -
LOG
where:
RHR = Relative Hazard Ratio
Cs = "Worst-Case" surrogate chemical concentration (30-minute average)
at the distance to the school (ppm)
LOG = Level of Concern value for the surrogate chemical (ppm)
The calculated RHR values are presented in Table VI-24 for each accident scenario.
For RHR values less than 1, the estimated worst-case concentration at the school is lower
than the corresponding LOG value, indicating little, if any, potential for adverse health
consequences. However, RHR values greater than 1 do not necessarily mean that adverse
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effects would be expected, given the highly protective approaches and assumptions used in
this analysis.
Of the 84 individual emission scenarios evaluated, RHR values are below 1 for 44
scenarios, between 1 and 10 for sixteen scenarios, between 10 and 100 for seven
scenarios, and are equal to or greater than 100 for five scenarios. RHR values were not
estimated for 12 scenarios because the accidental fire events could not be modeled under
calm/inversion conditions using ISC-COMPDEP (see Chapter V, Section A). Fire events
modeled under calm/inversion conditions using an alternative model (CALPUFF) are
discussed in Chapter VIII.
Events for which RHR values at the distance to the school are less than 1 under all
meteorological conditions are:
on-site spill of a large volume of "typical" waste;
on-site spill of a typical volume of "typical" waste;
on-site fire involving a large volume of waste (surrogate chemicals: phosgene
and HC1);
on-site fire involving a typical volume of waste (surrogate chemicals: phosgene
and HC1);
off-site spill involving a large volume of "typical" waste;
off-site spill involving a typical volume of "typical" waste; and
off-site fire involving a typical volume of waste (surrogate chemical: phosgene).
Events for which the RHR values are greater than 1 but less than 10 under all
meteorological conditions evaluated are:
on-site spill of a typical volume of "worst-case" waste;
on-site mixing of a typical volume of incompatible wastes;
off-site spill of a typical volume of "worst-case" waste;
off-site fire involving a large volume of waste (surrogate chemicals: phosgene
and HC1); and
off-site fire involving a typical volume of waste (surrogate chemical: HC1).
Accident events identified as having the greatest potential for adverse health
consequences (i.e., RHR values greater than 10 under at least some meteorological
conditions and possibly over 100 under the most extreme meteorological conditions) are:
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On-site spill of a large volume of "worst-case" waste;
On-site mixing of a large volume of incompatible wastes; and
Off-site spill of a large volume of "worst-case" waste.
For those accident events with the greatest potential for adverse health consequences.
mitigation of the release within 10 minutes generally results in lower RHR values.
4. Probability of Occurrence
The overall probability of occurrence for each of the accident scenarios is discussed in
Section B of this chapter. In this screening-level evaluation, however, the probability of
occurrence values presented in Section B are adjusted to account for the likelihood that the
wind would be blowing toward the school at the time of the accident.
The frequency of wind direction can be estimated from on-site measurements taken at
the WTI facility. One year of hourly surface meteorological data collected from the WTI
site between January 1993 and December 1993 (a total of 8760 hours) has been used to
define the frequencies of wind direction under typical, conservative, and calm/inversion
meteorological conditions in the event of a hypothetical on-site or off-site accident
scenario. For both on-site and off-site accident scenarios, the school is considered to be
downwind of a release if the wind direction is within a 20 degree arc centered on a line
from the center of the release to the center of the school. Thus, if north is considered to
be located at 0 degrees, the school is considered downwind of a hypothetical on-site
accident if the wind vector falls between 340 and 360 degrees, and downwind of a
hypothetical off-site accident if the wind vector falls between 55 and 75 degrees. The
relevant wind direction data under specific meteorological conditions are summarized
below:
On-site Accident
For a total of 46 hours out of 8760 hours (i.e., 0.5% of the time), the wind
direction is from the hypothetical on-site accident location toward the school.
For a total of 5 hours out of the 46 hours during which the wind direction is from
the hypothetical on-site accident location toward the school (i.e., 0.06% of the
total 8760 hours), the wind speed is less than 2 m/s, and moderately stable
(Stability F) atmospheric conditions exist.
For only 1 hour out of the 46 hours during which the wind direction is from the
hypothetical on-site accident location toward the school (i.e., 0.01% of the total
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8760 hours), the wind speed is less than 2 m/s after a calm hour, and moderately
stable (Stability F) atmospheric conditions exist.
Off-site Accident
For a total of 1412 hours out of 8760 hours (i.e., 16% of the time), the wind
direction is from the hypothetical off-site accident location toward the school.
This is the predominant wind direction.
For a total of 76 hours out of the 1412 hours during which the wind direction is
from the hypothetical off-site accident location toward the school (i.e., 0.9% of
the total 8760 hours), the wind speed is less than 2 m/s, and moderately stable
(Stability F) atmospheric conditions exist .
For a total of.23 hours out of the 1412 hours during which the wind direction is
from the hypothetical off-site accident location toward the school (i.e., 0.3% of
the total 8760 hours), the wind speed is less than 2 m/s after a calm hour, and
moderately stable (Stability F) atmospheric conditions exist.
On this basis, the frequency of wind direction toward the school for on-site events is
assumed to be 0.5%, 0.06%, and 0.01% for typical, conservative, and calm/inversion
meteorological conditions, respectively. The frequency of wind direction toward the
school for off-site events is assumed to be 16%, 0.9%, and 0.3%.2 The probability of
occurrence values presented in Section B of this Chapter have been adjusted in the
screening-level evaluation to account for these estimated wind direction frequencies.
The location selected for the hypothetical off-site event is considered to represent a
reasonable worst-case assumption in terms of probability of occurrence, given that the
predominant wind direction is toward the school. If the accident were to occur at
locations other than that assumed in the Accident Analysis, there is a lower probability
that the wind would be blowing directly toward the school.
Table VI-24 presents the estimated probability of occurrence, adjusted for frequency
of wind direction, for each accident scenario. It should be emphasized that the probability
of occurrence values in Table VI-24 represent estimates for entire categories of events,
rather than for individual accidents. For example, the probability of occurrence value
listed for the on-site spill of 5,000 gallons of "worst-case" waste (surrogate chemical:
For the purposes of this analysis, the number of hours of "typical" meteorological conditions is conservatively
assumed to be equal to the total number of hours that tne wind blows toward the school (46 hours for on-site
events; 1412 hours for off-site events). In actuality only a portion of these total hours would correspond to
"typical" conditions.
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formaldehyde) represents the likelihood for the entire category of large on-site spills of
"worst-case" (i.e., high acute toxicity and volatility) waste. The likelihood of any one
accident with a specific chemical and volume of release would be much lower than
indicated for the corresponding general emission scenario in Table VI-24.
5. Results of Screening-Level Evaluation
As shown in Table VI-24, the two hypothetical accident events with the greatest
potential for adverse consequences are the on-site spill of a large volume of "worst-case"
waste, and the on-site mixing of a large volume of incompatible wastes. For both of these
events, the RHR values are greater than 100 under calm/inversion or conservative
meteorological conditions, if no active mitigation is taken to reduce emissions within 10
minutes. (If it is assumed that active mitigation reduces emissions within 10 minutes, the
RHR value for the on-site spill of a large volume of "worst-case" waste is less than 100.)
The likelihood that either one of these accident scenarios would occur at the WTI facility
is extremely small. Taking into account the fraction of the year that the wind blows
toward the school from the WTI facility, the frequency of occurrence for the on-site spill
for a large volume "worst-case" waste, or for the on-site mixing of a large volume of
incompatible wastes, is estimated to be between 1 in 170,000 years and 1 in 1,700,000
years under conservative meteorological conditions. The frequency of occurrence for
either one of these events under calm/inversion meteorological conditions is estimated to
be between 1 in 1,000,000 years and 1 in 10,000,000 years.
Under typical meteorological conditions, the RHR values for the on-site spill of a
large volume "worst-case" waste and the on-site mixing of a large volume of incompatible
wastes are greater than 10, but well below 100. The RHR value is also greater than 10,
but less than 100, for the off-site spill of a large volume "worst-case" waste under either
conservative or calm/inversion meteorological conditions. Again, the estimated frequency
of occurrence for these scenarios is relatively small. Under typical meteorological
conditions, the frequency of occurrence for an on-site spill of a large volume of "worst-
case" waste or for the on-site mixing of a large volume of incompatible wastes is
estimated to be between 1 in 20,000 years and 1 in 200,000 years. For an off-site spill of
a large volume of "worst-case" waste, the frequency of occurrence is estimated to be
between 1 in 110,000 years to 1 in 1,100,000 years under conservative meteorological
conditions and between 1 in 330,000 and 1 in 3,300,000 years under calm/inversion
meteorological conditions.
Five accident events resulted in RHR values greater than 1 but less than 10: (1) an
on-site spill of a typical volume of "worst-case" waste; (2) an on-site mixing of a typical
Volume VII VI-32
-------
volume of incompatible wastes; (3) an off-site spill of a typical volume of "worst-case"
waste; (4) an off-site fire involving a large volume of waste; and (5) an off-site fire
involving a typical volume of waste (surrogate chemical : HC1). These events are also
unlikely to occur over the expected life of the facility, with an estimated frequency of
occurrence ranging from 1 in 11,100 years to 1 in 2,200,000 years.
It is important to recognize that the results of this screening-level evaluation do not
provide a realistic measure of the absolute level of exposure or risk at East Elementary
School, given the limitations of the air modeling and the highly protective assumptions
and approaches used in developing both the worst-case concentrations and the estimated
frequencies of occurrence. However, the results provide a basis for evaluating the relative
significance of different types of accident scenarios to provide additional information for
the local emergency planning and preparedness process.
6. Uncertainties
There is considerable uncertainty in estimating worst-case chemical concentrations at
East Elementary School in the event of an accident during operation of the WTI facility,
and in estimating the likelihood of occurrence of these events. Given these uncertainties,
approaches and assumptions designed to be highly protective of human health have
generally been used in this screening-level evaluation. Critical assumptions and
approaches used in this evaluation include the following:
For the off-site spill and fire scenarios, spill sizes 5.000 gallons (for the large
volume spill), and 100 gallons (for the typical volume spill) have been assumed.
As discussed in Chapter II, according to U.S. Department of Transportation data
(U.S. DOT 1995), 95 percent of all spills are less than 5,000 gallons and
50 percent of all spills are less than 100 gallons. Thus, most off-site spills would
involve quantities that are much lower than that assumed in this screening-level
evaluation for the large volume spill. The release quantity assumed for the
typical volume spill is consistent with U.S. DOT data.
For on-site spill scenarios, spill sizes of 5.000 gallons (for the large volume
spiin. and 100 gallons (for the typical volume spiin have been assumed, based on
the U.S. DOT (1995) data. Data from the WTI facility (in operation for more
than three years), and other operating treatment and disposal facilities, indicate
that these spill sizes are overestimates. For example, all spills reported to date at
Volume VII VI-33
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the WTI facility have been less than 50 gallons; the largest reported liquid spill
between May 1993 and January 1997 at the WTI facility was 20 gallons.
For the on-site mixing of incompatible waste scenarios, releases from a total of
10.000 gallons of waste (for the large volume mixing of incompatible waste
scenario) and a total of 200 gallons of waste (for the typical volume mixing of
incompatible waste scenario^ have been assumed. The large volume scenario is
based on tank truck and storage vessel capacities at the WTI facility; the typical
volume scenario is based on an assumed spill involving four full drums of waste.
Given the experience at other treatment and disposal facilities, the large volume
scenario is likely to overestimate emissions. No mixing of incompatible waste
events involving a similarly large volume of waste have been reported by USEPA
(1995b) at hazardous waste treatment and disposal facilities. Furthermore, since
most spills at the WTI facility are expected to involve less than 100 gallons of
waste, the volume of waste for the typical mixing of incompatible waste scenario
is also conservative.
Waste composition data from WTI waste profile sheets for the first year of
operations were used to characterize the composition of future waste to be
received at the facility. Variability in the composition of the waste is expected
over time, and may lead to a more or less hazardous mixture in the future. The
potential for underestimating concentrations of hazardous chemicals in the overall
waste is reduced by making conservative assumptions in calculating chemical
concentrations in waste from the information provided in the site-specific waste
profiles. For example, for a spill of "worst-case" waste, the formaldehyde
concentration is assumed to be 10%, which is approximately equal to the
combined average of the highest concentrations reported for individual waste
streams containing formaldehyde.
Level of Concern (LOO values have been used in the screening level evaluation.
As previously discussed, the LOG values are the most stringent of the toxicity
criteria-based concentrations/values considered in the Accident Analysis.
Exposures to concentrations higher than the LOG would not necessarily result in
adverse human health effects. *'
Volume VII VI-34
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For the off-site and on-site spill scenarios, models and assumptions expected to
overestimate rather than underestimate chemical emission rates have been used.
As discussed in Chapter IV and Appendix VII-3, a number of conservative
assumptions have been made in calculating emission rates. For example, for the
on-site and off-site spill scenarios, it has been assumed that the roadways and
receiving areas are flat without drains, which is likely to overestimate emissions
in most cases. Thus, emission rates are expected to be lower than assumed in
this analysis, and corresponding concentrations at the distance to the school
would also be lower.
For the mixing of incompatible waste scenarios, it is assumed that all forms of
chlorine in the waste are instantaneously converted to hydrogen chloride (HC1).
This conservative assumption has been made due to a lack of data regarding the
actual rate and extent of conversion from different forms of chlorine to HC1. An
unknown fraction of the chlorine would either not react or be expected to react to
form compounds less hazardous than HC1, and the reaction rates may be
significantly slower than assumed.
Dispersion modeling may overestimate concentrations at the height of the school.
particularly for dense gas releases associated with a spill or mixing of
incompatible wastes. As previously discussed, EPA-reviewed models cannot
account for the terrain effects when evaluating emissions of the dense gases
considered in the spill and mixing of incompatible waste scenarios. Thus, the
worst-case concentrations estimated at the distance to the school assume flat
terrain and are likely to be overestimates.
For the off-site accident scenarios, the selected location of the release is in the
predominant upwind direction relative to the school. If the accident were to
occur at other locations equidistant from the school, there is a lower probability
that the release would create an adverse consequence at the school.
In estimating the probability of occurrence values for the screening level
evaluation, one year of on-site meteorological data was used. Some variation in
wind direction may be expected from year to year. However, one year of data is
considered adequate for the purposes of the screening level evaluation.
Volume VII VI-35
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The uncertainties associated with each step in the evaluation are presented in Chapters
I through VI of this volume, and are summarized in Chapter VII (Uncertainties).
7. Discussion
This screening-level evaluation suggests that several accident scenarios could
potentially result in worst-case concentrations that are higher than corresponding LOC
concentrations at the distance to the school. The on-site spill involving a large volume of
"worst-case" waste, and the on-site mixing of a large volume of incompatible waste, are
identified as the events with the most serious potential health consequences at the location
of the school. However, it is very unlikely that the events with the greatest potential
severity of consequences will occur during the expected lifetime of the facility.
The results of this .screening evaluation can be compared to previous accident analyses
for the WTI facility, as summarized in the Waste Technologies Industry Credible Event
Analysis for Emergency Planning (SE Technologies, Inc. 1992). As discussed in
Chapter I, the WTI Credible Event Analysis evaluates eight accident scenarios. Of the
eight scenarios, three indicate a potential exceedance of LOC values over a distance of at
least 350 meters, the approximate distance to the school. For these three events, the
probability of the release occurring was classified as "high" for one event (an on-site spill
of 50 gallons of liquid waste, resulting in volatile emissions); as "medium" for one
scenario (mixing of incompatible waste, resulting in a release of chlorine gas); and as
"low" for one scenario (an on-site release of ammonia3). The Credible Event Analysis did
not quantify the probability of occurrence for any scenario, or evaluate the relative
likelihood that a given scenario would impact the school. However, the overall results of
the screening-level evaluation are consistent with the results of the WTI Credible Event
Analysis, in that the scenarios with the greatest potential consequences are generally
considered to be unlikely to occur during the expected operating life of the facility.
The results of the screening-level evaluation are also consistent with U.S. EPA data
summarized in the report on the Emergency Incidents at Hazardous Waste Incinerators
and Commercial Treatment, Storage, and Disposal Facilities (TSDs) (USEPA 1995b). As
discussed in Section B of this chapter, a total of ten incidents involving the release of
hazardous waste have been reported at hazardous waste treatment and disposal facilities in
the U.S. since 1977. This corresponds to approximately one reported emergency incident
involving a hazardous waste release for every 25-30 years of operation for commercial
hazardous waste incineration facilities in the U.S. None of the tenlncidents reported at
3 This scenario is no longer relevant to the WTI facility due to a change in facility design and operation.
Volume VII VI-36
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the commercial combustion facilities involving releases of hazardous wastes resulted in a
serious injury or fatality in off-site communities (USEPA 19955); however, the distance
from the release to the nearest potential off-site receptor is not known.
Volume VII VI-37
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TABLE VI-1
Criteria Used in Ranking the Severity of Consequence Based on IDLH Values
Severity of
Consequence Ranking
Minor
Moderate
Major
Catastrophic
General Criteria
No exceedance of an IDLH value in inhabited off-site areas: and
negligible potential for off-site fatalities or serious injuries due to
heat effects from a fire.
Exceedance of IDLH values in inhabited off-site areas over
distances of 100 m or less; injuries due to heat effects limited to a
distance of 100 m into inhabited areas.
Exceedance of IDLH values in inhabited off-site areas over
distances between 100 m to 1000 m; injuries due to heat effects
limited to a distance of 1000 m into inhabited areas.
Exceedance of IDLH values in inhabited off-site areas over
distances greater than 1000 m; injuries due to heat effects extend to
distances greater than 1000 m into inhabited areas.
Volume VII
VI-38
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TABLE VI-2
Criteria Used in Ranking the Severity of Consequence Based on LOC Values
Severity of
Consequence Ranking
Minor
Moderate
Major
Catastrophic
General Criteria
No exceedance of an LOC value in inhabited off-site areas; and
negligible potential for off-site fatalities or serious injuries due to
heat effects from a fire.
Exceedance of LOC values in inhabited off-site areas over distances
of 200 m or less; injuries due to heat effects limited to a distance of
200 m into inhabited areas.
Exceedance of LOC values in inhabited off-site areas over distances
between 200 m to 2000 m; injuries due to heat effects limited to a
distance of 2000 m into inhabited areas.
Exceedance of LOC values in inhabited off-site areas over distances
greater than 2000 m; injuries due to heat effects extend to distances
greater than 2000 m into inhabited areas .
Volume VII
VI-39
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TABLE VI-3
Criteria Used in Ranking Probability of Occurrence
Probability of
Occurrence Ranking
Common
Likely
Reasonably Likely
Unlikely
Very Unlikely
General Criteria
Expected to occur one or more times each year on average.
Expected to occur at least once every 10 years on average
according to available statistics.
Predicted to occur between once every 10 years and once
every 100 years on average.
Predicted to occur between once every 100 years and once
every 1,000 years on average in a specific locale.
Predicted to occur less than once in 1,000 years.
Volume VII
VI-40
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TABLE VI-4
Severity of Consequence for On-Site Scenarios Based on IDLH Values
Meteorological Conditions
Typical
Conservative
Calm/Inversion
On-Site Spills
5, 000 gallon spill
Formaldehyde
Acetone
100 gallon spill
Formaldehyde
Acetone
Major
Minor
Moderate
Minor
Catastrophic
Minor
Major
Minor
Catastrophic
Minor
Major
Minor
On-Site Fires
20,000 gallons of waste
200 gallons of waste
Minor1
Minor2
Minor1
Minor2
NE3
NE3
Mixing of Incompatible Wastes
10,000 gallons of waste
200 gallons of waste
Major
Minor
Catastrophic
Major
Catastrophic
Major
Notes:
1 On the bases of potential HC1 and phosgene emissions and heat effects, the 20,000-
gallon fire is judged to have minor consequences. In the event of a fireball, the severity
of consequence would be classified as major; however, the potential for a fireball is very
low.
2 On the bases of potential HC1 and phosgene emissions, heat effects and assumed fireball
formation, the 200-gallon fire is judged to have minor consequences.
3 NE: Not Evaluated as part of this analysis. A sensitivity analysis for the calm/inversion
conditions for the fire scenarios was conducted and is presented in Chapter VII.
Volume VII
VI-41
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TABLE VI-5
Severity of Consequence for On-Site Scenarios Based on LOG Values
Meteorological Conditions
Typical
Conservative
Calm/Inversion
On-Site Spills
5,000 gallon spill
Formaldehyde
Acetone
100 gallon spill
Formaldehyde
Acetone
Major
Minor
Moderate
Minor
Catastrophic
Minor
Major
Minor
Catastrophic
Minor
Major
Minor
On-Site Fires
20,000 gallons of waste
200 gallons of waste
Minor1
Minor2
Moderate1
Minor2
NE3
NE3
Mixing of Incompatible Wastes
10,000 gallons of waste
200 gallons of waste
Major
Moderate
Catastrophic
Major
Catastrophic
Major
Notes:
1 In the event of a fireball, the severity of consequence would be classified as major;
however, the potential for a fireball is very low.
2 On the bases of potential HCI and phosgene emissions, heat effects and assumed fireball
formation, the 200-gallon fire is judged to have minor consequences.
3 NE: Not Evaluated as part of this analysis. A sensitivity analysis for the calm/inversion
conditions for the fire scenarios was conducted and is presented in Chapter VII.
Volume VII
VT-42
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TABLE VI-6
Severity of Consequence for Off-Site Scenarios Based on IDLH Values
Meteorological Conditions
Typical
Conservative
Calm/Inversion
Off-Site Spills
5,000 gallon spill
- Formaldehyde
- Acetone
100 gallon spill
- Formaldehyde
- Acetone
Major
Minor
Major
Minor
Catastrophic
Moderate
Major
Minor
Catastrophic
Moderate
Catastrophic
Minor
Off-Site Fires
5,000 gallons of waste -
100 gallons of waste
Moderate1
Moderate2
Major1
Moderate2
NE3
NE3
Notes:
1 On the basis of potential HCI and phosgene emissions, the 5,000-gallon fire is judged
to have minor consequences under typical meteorological conditions, and potentially
major consequences under conservative meteorological conditions. Given the potential
heat effects of the fire, the event would be judged to have moderate consequences. In
the event of a fireball, the severity of consequence would be classified as major;
however, the potential for a fireball is very low.
2 On the basis of potential HCI and phosgene emissions, the 100-gallon fire is judged to
have minor consequences. Given the potential heat effects of the fire, the event would
be judged to have moderate consequences. In the event of a fireball, the severity of
consequence would be classified as moderate; however, the potential for a fireball is
very low.
3 NE: Not Evaluated as part of this analysis. A sensitivity analysis for the calm/
inversion conditions for the fire scenarios was conducted and is presented in
Chapter VII.
Volume VII
VI-43
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TABLE VI-7
Severity of Consequence for Off-Site
Scenarios Based on LOC Values
Meteorological Conditions
Typical
Off-Site Spills
5,000 gallon spill
- Formaldehyde
- Acetone
100 gallon spill
.- Formaldehyde
- Acetone
Major
Minor
Moderate
Minor
Off-Site Fires
5,000 gallons of waste -
100 gallons of waste
Moderate1
Moderate2
Notes:
1 On the basis of potential HC1 emissions, the
Conservative
Catastrophic
Moderate
Major
Minor
Catastrophic1
Moderate2
Calm/Inversion
Catastrophic
Moderate
Major
Minor
NE3
NE3
5,000-gallon fire is judged to have minor
consequences under typical meteorological conditions, and potentially catastrophic
consequences under conservative meteorological conditions. Given the potential heat
effects of the fire, the event would be judged to have moderate consequences. In the
event of a fireball, the severity of consequence would be classified
the potential for a fireball is very low.
as major; however,
2 On the basis of potential HC1 and phosgene emissions, the 100-gallon fire is judged to
have minor consequences. Given the potential heat effects of the fire, the event would
be judged to have moderate consequences. In the event of a fireball, the severity of
consequence would be classified as moderate; however, the potential for a fireball is
very low.
3 NE: Not Evaluated as part of this analysis.
A sensitivity analysis for the
calm/ inversion conditions for the fire scenarios was conducted and
Chapter VE.
is presented in
Volume VII
VI-44
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TABLE VI-8
Summary of Downwind Distance to IDLH, On-Site Spill
Spill Size
(gallons)
5,000
5,000
5,000
5,000
5,000
5,000
100
100
100
100
100
100
Meteorological Conditions
Typical
Conservative
Calm/Inversion
Typical
Conservative
Calm/Inversion
Typical
Conservative
Calm/Inversion
Typical
Conservative
Calm/Inversion
Contaminant
Formaldehyde
Formaldehyde
Formaldehyde
Acetone
Acetone
Acetone
Formaldehyde
Formaldehyde
Formaldehyde
Acetone
Acetone
Acetone
Max. Downwind Dist. to IDLH,
no active mitigation1'2 (m)
870
4870
10400
--
40
550
1000
.
--
Notes:
1 Maximum downwind distance calculated from the property line to the east or west, or the existing railroad to the north, whichever is closer to the location of
the release. For the on-site spill, maximum downwind distance was calculated from the railroad line to the north, approximately 75 m from the edge of the
spill.
2 --: IDLH not exceeded in potential off-site receptor areas.
Volume VII
VI-45
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TABLE VI-9
Summary of Downwind Distance to LOC, On-Site Spill
Spill Size
(gallons)
5,000
5,000
5,000
5,000
5,000
5,000
100
100
100
100
100
100
Meteorological Conditions
Typical
Conservative
Calm/Inversion
Typical
Conservative
Calm/Inversion
Typical
Conservative
Calm/Inversion
Typical
Conservative
Calm/Inversion
Contaminant
Formaldehyde
Formaldehyde
Formaldehyde
Acetone
Acetone
Acetone
Formaldehyde
Formaldehyde
Formaldehyde
Acetone
Acetone
Acetone
Max. Downwind Dist. to LOC, no active
mitigation1'2 (in)
1360
8240
14100
--
100
910
1590
--
Notes:
1 Maximum downwind distance calculated from the property line to the east or west, or the existing railroad to the north, whichever is closer to the location of
the release. For the on-site spill, maximum downwind distance was calculated from the railroad line to the north, approximately 75 in from the edge of the
spill.
2 --: LOC not exceeded in potential off-site receptor areas.
Volume VII
VI-46
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TABLE VI-10
Summary of Downwind Distance to IDLH, On-Site Fire
Waste Volume
Ignited (gallons)
20,000
20,000
200
200
Meteorological
Conditions
Typical
Conservative
Typical
Conservative
Contaminant
HC1
Phosgene
HC1
Phosgene
HC1
Phosgene
HC1
Phosgene
Downwind Dist. to IDLH,
no active mitigation1 (m)
_ 2
__
_-
Max. Downwind
Dist. Affected by
Heat Effect (m)1
Fatality
--
--
--
--
Injury
--
--
--
--
Max. Downwind Dist. Affected
by Fireball(m)1
Fatality
300
300
--
--
Injury
625
625
-- .
--
Notes:
1 Maximum downwind distance measured from the property line to the east or west, or the existing railroad to the north, whichever is closer to the release.
1 : not exceeded in potential off-site receptor areas.
Volume VII
VI-47
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TABLE VI-11
Summary of Downwind Distance to LOG, On-Site Fire
Waste Volume
Ignited (gallons)
20,000
20,000
200
200
Meteorological
Conditions
Typical
Conservative
Typical
Conservative
Contaminant
HC1
Phosgene
HC1
Phosgene
HC1
Phosgene
HC1
Phoigene
Downwind Dist. to LOC,
no active mitigation1'2 (m)
675-1125
--
Max. Downwind
Dist. Affected by
Heat Effect (m)1
Fatality
-
-
--
Injury
-
-
--
--
Max. Downwind Dist. Affected
by Fireball(m)1
Fatality
300
300
--
--
Injury
625
625
--
--
Notes:
1 Maximum downwind distance measured from the property line to the east or west, or the existing railroad to the north, whichever is closer to the release.
1 --: not exceeded in potential off-site receptor areas.
Volume VII
VI-48
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TABLE VI-12
Summary of Downwind Distance to IDLH, On-Site Mixing of Incompatible Wastes
Waste Volume
(gallons)
Meteorological Conditions
Contaminant
Max. Downwind Dist. to IDLH,
no active mitigation" (m)
10,000
Typical
HCI
680
10,000
Conservative
HCI
3190
10,000
Calm/Inversion
HCI
4620
200
Typical
HCI
200
Conservative
HCI
270
200
Calm/Inversion
HCI
520
Notes:
Maximum Downwind Distance calculated from the property line to the east or west, or the existing railroad to the north, whichever is closer to the release.
For the on-site mixing of incompatible wastes, the maximum downwind distance was calculated from the railroad line to the north, or approximately 75 m
from the edge of the release.
--: IDLH not exceeded in potential off-site receptor areas.
Volume VII
VI-49
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TABLE VI-13
Summary of Downwind Distance to LOG, Qn-Site Mixing of Incompatible Wastes
Waste Volume
(gallons)
Meteorological Conditions
Contaminant
Max. Downwind Dist. to LOC, no active
mitigation1 (m)
10,000
Typical
HCI
1780
10,000
Conservative
HCI
8790
10,000
Calm/Inversion
HCI
12200
200
Typical
HCI
130
200
Conservative
HCI
980
200
Calm/Inversion
HCI
1700
Note:
Maximum downwind distance calculated from the property line to the east or west, or the existing railroad to the north, whichever is closer to the release.
For the on-site mixing of incompatible wastes, the maximum downwind distance was calculated from the railroad line to the north, or approximately 75 m
from the edge of the release.
Volume VII
Vl-50
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TABLE VI-14
Summary of Downwind Distance to IDLH, Off-Site Spill
Spill Size
(gallons)
5,000
5,000
5,000
5,000
5,000
5.000
100
100
100
100
100
100
Meteorological Conditions
Typical
Conservative
Calm/Inversion
Typical
Conservative
Calm/Inversion
Typical
Conservative
Calm/Inversion
Typical
Conservative
Calm/Inversion
Contaminant
Formaldehyde
Formaldehyde
Formaldehyde
Acetone
Acetone
Acetone
Formaldehyde
Formaldehyde
Formaldehyde
Acetone
Acetone
Acetone
Max. Downwind Dist. to IDLH,
no active mitigation1'1 (m)
980
5120
9050
< 10
50
50
130
630
1080
< 10
< 10
< 10
Notes:
1 Maxknum Downwind Distance calculated from edge of spill.
2 --: IDLH not exceeded in off-site potential receptor areas.
Volume VII
VI-51
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TABLE VMS
Summary of Downwind Distance to LOC, Off-Site Spill
Spill Size
(gallons)
5,000
5,000
5,000
5,000
5,000
5,000
100
100
100
100
100
100
Meteorological Conditions
Typical
Conservative
Calm/Inversion
Typical
Conservative
Calm/Inversion
Typical
Conservative
Calm/Inversion
Typical
Conservative
Calm/Inversion
Contaminant
Formaldehyde
Formaldehyde
Formaldehyde
Acetone
Acetone
Acetone
Formaldehyde
Formaldehyde
Formaldehyde
Acetone
Acetone
Acetone
Max. Down-wind Dist. to LOC, no active
mitigation1'2 (in)
1490
8490
12400
<10
60
60
190
980
1670
<10
<10
<10
Notes:
1 Maximum downwind distance calculated from edge of spill.
2 --: LOC not exceeded in off-site potential receptor areas.
Volume VII
VI-52
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TABLE VI-16
Summary of Downwind Distance to IDLH, Off-Site Fire
Waste Volume Ignited
(gallons)
5,000
5,000
100
100
Meteorological
Conditions
Typical
Conservative
Typical
Conservative
Contaminant
HC1
Phosgene
HC1
Phosgene
HCI
Phosgene
HCI
Phosgene
Downwind Dist. to IDLH1'2
no active mitigation
.-
275
125
Max. Downwind Dist.
Affected by Heat Effect
(m)
Fatality
'i
35-40
35-40
5-7
9-13
Injury
50-60
50-60
5-7
9-13
Max. Downwind Dist.
Affected by
Fireball(m)
Fatality
170
170
20
20
Injury
340
340
45
45
Notes:
1 For the off-site fire scenarios, IDLH values for HC1 and phosgene are predicted to occur in areas within approximately 275 m and 125 m, respectively,
downwind from the center of the fire under conservative meteorological conditions. The areas of exceedance within this zone are expected to he "pockets"
corresponding to locations of elevated terrain.
2 --: lt)LH not exceeded in potential receptors areas.
Volume VII
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TABLE VI-17
Summary of Downwind Distance to LOC, Off-Site Fire
Waste Volume
Ignited (gallons)
5,000
5,000
100
IvO
Meteorological
Conditions
Typical
Conservative
Typical
Conservative
Contaminant
HC1
Phosgene
HC1
Phosgene
HC1
Phosgene
HCI
Phosgene
Downwind Dist. to LOC,
no active mitigation1'1 (m)
2100'
1100'
..
Max. Downwind
Dist. Affected by
Heat Effect (m)
Fatality
35-40
35-40
5-7
9-13
Injury
50-60
50-60
5-7
9-13
Max. Downwind Dist. Affected
by Fireball(m)
Fatality
170
170
20
20
Injury
340
340
45
45
Notes:
1 Maximum downwind distance measured from the property line to the east or west, or the existing railroad to the north, whichever is closer to the release.
2 --: LOC not exceeded in potential off-site receptor areas.
Volume VII
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TABLE VI-18
Probability of Occurrence for On-Site Scenarios
Meteorological Conditions
Typical
Conservative
Calm/Inversion
On-Site Spills
5,000 gallon spill
Formaldehyde
Acetone
100 gallon spill
Formaldehyde
Acetone
Unlikely
Reasonably Likely
Reasonably Likely
Likely
Very Unlikely
Unlikely
Unlikely
Reasonably Likely
Very Unlikely
Unlikely
Unlikely
Reasonably Likely
On-Site Fires
20,000 gallons of waste
200 gallons of waste
Unlikely
Reasonably Likely
Very Unlikely
Unlikely
Very Unlikely
Unlikely
Mixing of Incompatible Wastes
10,000 gallons of waste
200 gallons of waste
Unlikely
Reasonably Likely
Very Unlikely
Unlikely
Very Unlikely
Unlikely
Volume VII
VI-55
-------
TABLE VI-19
Probability of Occurrence for Off-Site Scenarios
Meteorological Conditions
Typical
Conservative
Calm/Inversion
Off-Site Spills
5,000 gallon spill
Formaldehyde
Acetone
100 gallon spill
Formaldehyde
Acetone
Very Unlikely
Unlikely
Unlikely
Reasonably Likely
Very Unlikely
Very Unlikely
Very Unlikely
Unlikely
Very Unlikely
Very Unlikely
Very Unlikely
Unlikely
Off-Site Fires
5, 000 gallons of waste
100 gallons of waste
Very Unlikely
Unlikely
Very Unlikely
Very Unlikely
Very Unlikely
Very Unlikely
Volume VII
VI-56
-------
TABLE VI-20
Severity of Consequence and Probability of Occurrence Results for On-Site Scenarios4
Scenario
On-Site Spill
5,000 gallon spill
Formaldehyde Waste
Acetone Waste
100 gallon spill
Formaldehyde Waste
Acetone Waste
On-Site Fire
20,000 gallon
200 gallon
Mixing of Incompatible Wastes
10,000 gallon
200 gallon
Meteorological Conditions
Typical
Severity of
Consequence
Major
Minor
Moderate
Minor
Minor1
Minor2
Major
Moderate4
Probability of
Occurrence
Unlikely
Reasonably Likely
Reasonably Likely
Likely
Unlikely
Reasonably Likely
Unlikely
Reasonably Likely
Conservative
Severity of
Consequence
Catastrophic
Minor
Major
Minor
Moderate1-4
Minor2
Catastrophic
Major
Probability of
Occurrence
Very Unlikely
Unlikely
Unlikely
Reasonably Likely
Very Unlikely
Unlikely
Very Unlikely
Unlikely
Calm/Inversion
Severity of
Consequence
Catastrophic
Minor
Major
Minor
NE1
NE3
Catastrophic
Major
Probability of
Occurrence
Very Unlikely
Unlikely
Unlikely
Reasonably Likely
Very Unlikely
Unlikely
Very Unlikely
Unlikely
Notes:
1 On the bases of potential HO and phosgene emissions and heat effects, the 20,000 gallon fire is judged to have moderate consequences under conservative meteorological
conditions, and minor consequences under typical meteorological conditions. In the event of a fireball, the severity of consequence would be classified as major; however, the
potential for ajireball is very low.
2 On the bases of potential HCI and phosgene emissions, heat effects and assumed fireball formation, the 200 gallon fire is judged to have minor consequences.
3 NE: Not Evaluated as part of this analysis. A sensitivity analysis for this scenario is presented in Chapter VII.
4 Severity of Consequence rankings based on LOG values. Severity of consequence rankings based on IDLH values are the same, with the following exceptions: (1) on-site fire
involving 20,000 gallons of waste under conservative meteorological conditions, for which the severity of consequence ranking using IDLH values is minor: and (2) on-site
mixing of 200 gallons of incompatible wastes under typical meteorological conditions, for which the severity of consequence ranks using IDLH values is minor.
Volume VII
VI-57
-------
TABLE VI-21
Severity of Consequence and Probability of Occurrence Results for Off-Site Scenarios4
Scenario
Off-Site Spill
5, 000 gallon spill
Formaldehyde
Acetone
100 gallon spill
Formaldehyde
Acetone
Off-Site Fire
5,000 gallon
100 gallon
Meteorological Conditions
Typical
Severity of
Consequence
Major
Minor
Moderate4
Minor
Moderate1
Moderate2
Probability of
Occurrence
Very Unlikely
Unlikely
Unlikely
Reasonably Likely
Very Unlikely
Unlikely
Conservative
Severity of
Consequence
Catastrophic
Moderate
Major
Minor
Catastrophic1'4
Moderate2
Probability of
Occurrence
Very Unlikely
Very Unlikely
Very Unlikely
Unlikely
Very Unlikely
Very Unlikely
Calm/Inversion
Severity of
Consequence
Catastrophic
Moderate
Major4
Minor
NE'
NE5
Probability of
Occurrence
Very Unlikely
Very Unlikely
Very Unlikely
Unlikely
Very Unlikely
Very Unlikely
Notes:
1 On the basis of potential HCI and phosgene emissions, the 5,000 gallon fire is judged to have minor consequences under typical meteorological conditions and potentially
catastrophic consequences under conservative meteorological conditions. Given the potential heat effects of the fire, the event would be judged to have moderate consequences
under typical conditions. In the event of a fireball, the severity of consequence would be classified as major; however, the potential for a fireball is very low.
2 On the basis of potential HCI and phosgene emissions, the 100 gallon fire is judged to have minor consequences. Given the potential heat effects of the fire, the event would be
judged to have moderate consequences. In the event of a fireball, the severity of consequence would be classified as moderate; however, the potential for a fireball is very low.
5 NE: Not Evaluated as part of this analysis. A sensitivity analysis for this scenario is presented in Chapter VII.
4 Severity of Consequence rankings based on LOC values. Severity of Consequence rankings based on IDLH values are the same, with the following exceptions: (1) off-site spill
of 100 gallonsvof formaldehyde waste under typical meteorological conditions, for which the severity of consequence ranking is major: (2) off-site spill of 100 gallons of
formaldehyde waste under calm/inversion meteorological conditions, for which the severity of consequence ranking is catastrophic: and (3) off-site 5,000-gallon fire under
conservative meteorological conditions, for which the severity of consequence ranking is major.
Volume VII
VI-58
-------
TABLE VI-22
Key Assumptions Made in
Ranking of Accident Events
Assumption
I . Concentralions predicted by
modeling averaged over a 30-minute
duration for comparison to LOG and
IDLH values.
2. IDLH and LOG values can be used
as a benchmark to evaluate extent of
possible off-site health effects.
3. Wind is continuously blowing
toward the nearest off-site inhabited
area during the entire duration of
emissions.
4. A fireball forms in the event of a
fire.
5. Likelihood of occurrence can be
estimated based on historical data
from TSDFs, and from USDOT and
ODPS highway accident data.
6. The largest volume of a storage
tank/container is used in the fireball
scenario.
7. Population data from 1990 census
and estimated plume width used to
develop consequence criteria relating
LOG and IDLH values to potential
for injuries and fatalities.
Basis
IDLH based on a 30-minute
exposure; LOG based on exposures
up to 60 minutes.
IDLH and LOG values represent a
consistent, relatively comprehensive
set of acute toxicity criteria.
Simplifying assumption.
Simplifying assumption.
Historical data believed to be relevant
to the WTI facility.
Simplifying assumption.
Number of people potentially
impacted is based on population
density, size of plume, and chemical
concentration in plume relative to
lexicological criteria.
Magnitude of Effect | Direction of Effect
Medium
High
High
Medium
Low
Medium
Medium
May underestimate risk if individuals are
exposed to higher peak concentrations over
short periods of time. Use of 30-minute
average concentrations in comparing to LOG
values may overestimate risk, however, since
LOCs are protective for exposures up to 60
minutes.
Unknown. May over or underestimate size of
area over which effects may be observed,
depending on derivation of IDLH and LOG
values. LOG values, however, are believed to
be protective of the general populations, i.e.,
more likely to overestimate than underestimate
the potential for health effects.
Overestimates
Overestimates hazard; a fireball may form only
under specific circumstances.
Variable. May over or underestimate actual
accident frequencies, especially for low
probability events.
Overestimates the quantity available for
forming a fireball.
Approach used is likely to overestimate
severity of consequence, using FliMA (1993)
guidance.
Volume VII
VI-59
-------
TABLE VI-23
Screening-Level Chemical Concentrations at the Distance to the School
Run
No.
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
Accident Event
On-Site Spill
Large Volume
(5000 gallons)
of Worst-case Waste
(surrogate chemical: Formaldehyde)
On-Site Spill
Large Volume
(5000 gallons)
of "Typical" Waste
(surrogate chemical: Acetone)
On-Site Spill
Typical Volume
(100 gallons)
of "Worst-case" Waste
(surrogate chemical: Formaldehyde)
On-Site Spill
Typical Volume
(100 gallons)
of "Typical" Waste
(surrogate chemical: Acetone)
Meteorological
Conditions
Typical
Conservative
Calm/Inversion
Typical
Conservative
Calm/Inversion
Typical
Conservative
Calm/Inversion
Typical
Conservative
Calm/Inversion
Spill Duration1
Unmitigated
10 minutes
Unmitigated
10 minutes
Unmitigated
10 minutes
Unmitigated
10 minutes
Unmitigated
10 minutes
Unmitigated
10 minutes
Unmitigated
10 minutes
Unmitigated
10 minutes
Unmitigated
10 minutes
Unmitigated
10 minutes
Unmitigated
10 minutes
Unmitigated
jrf*
10 minutes
Upper Bound
Concentration
at Distance
to School
(ppm)23
110
83
1400
700
1790
700
20
8.8
150
55
200
55
3.1
3.2
48
47
83
75
1.2
0.76
19
7.1
23
7.6
Volume VII
VI-60
-------
TABLE VI-23 (continued)
Screening-Level Chemical Concentrations at the Distance to the School
Run
No.
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
Accident Event
On-Site Fire
(20,000 gallons)
(surrogate chemical: HC1)
On-Site Fire
Large Volume
(20,000 gallons)
(surrogate chemical: Phosgene)
On-Site Fire
Typical Volume
(200 gallons)
(surrogate chemical: HC1)
On-Site Fire
Typical Volume
(200 gallons)
(surrogate chemical: Phosgene)
Meteorological
Conditions
Typical
Conservative
Calm/Inversion
Typical
Conservative
Calm/Inversion
Typical
Conservative
Calm/Inversion
Typical
Conservative
Calm/Inversion
Spill Duration1
Unmitigated
10 minutes
Unmitigated
10 minutes
Unmitigated
10 minutes
Unmitigated
10 minutes
Unmitigated
10 minutes
Unmitigated
10 minutes
Unmitigated
10 minutes
Unmitigated
10 minutes
Unmitigated
10 minutes
Unmitigated
10 minutes
Unmitigated
10 minutes
Unmitigated
^*
10 minutes
Upper Bound
Concentration
at Distance
to School
(ppm)2-'
< 0.000001
< 0.000001
0.16
0.027
NE
NE
< 0.000001
< 0.000001
0.0017
0.00029
NE
NE
< 0.000001
< 0.000001
0.016
0.0027
NE
NE
< 0.000001
< 0.000001
0.00017
0.000029
NE
NE
Volume VII
-------
TABLE VI-23 (continued)
Screening-Level Chemical Concentrations at the Distance to the School
Run
No.
49
50
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
69
70
71
72
Accident Event
On-Site Mixing of
Incompatible Wastes
Large Volume
(10,000 gallons)
(surrogate chemical: HC1)
On-Site Mixing of
Incompatible Wastes
Typical Volume
(200 gallons)
(surrogate chemical: HC1)
Off-Site Spill; Large Volume (5000
gallons) of "Worst-case" Waste
(surrogate chemical: Formaldehyde)
Off-Site Spill; Large Volume
(5000 gallons) of "Typical" Waste
(surrogate chemical: Acetone)
Off-Site Spill; Typical Volume
(100 gallons) of "Worst-case" Waste
(surrogate chemical: Formaldehyde)
Off-Site Spill; Typical Volume
(100 gallons) of "Typical" Waste
(surrogate chemical: Acetone)
Meteorological
Conditions
Typical
Conservative
Calm/Inversion
Typical
Conservative
Calm/Inversion
Typical
Conservative
Calm/Inversion
Typical
Conservative
Calm/Inversion
Typical
Conservative
Calm/Inversion
Typical
Conservative
Calm/Inversion
Spill Duration1
Unmitigated
10 minutes
Unmitigated
10 minutes
Unmitigated
10 minutes
Unmitigated
10 minutes
Unmitigated
10 minutes
Unmitigated
10 minutes
Unmitigated
Unmitigated
Unmitigated
Unmitigated
Unmitigated
Unmitigated
Unmitigated
Unmitigated
Unmitigated
Unmitigated
Unmitigated ,
Unmitigated
Upper Bound
Concentration
at Distance
to School
(ppm)23
170
98
1400
710
1700
1000
3.8
3.8
49
49
90
90
28
400
610
7.6
76
100
0.71
14
31
0.27
5
9.0
Volume VII
VI-62
-------
TABLE VI-23 (continued)
Screening-Level Chemical Concentrations at the Distance to the School
Run
No.
73
74
75
76
77
78
79
80
81
82
83
84
Accident Event
Off-Site Fire
Large Volume (5000 gallons)
(surrogate chemical: HC1)
Off-Site Fire
Large Volume (5000 gallons)
(surrogate chemical: Phosgene)
Off-Site Fire
Typical Volume (100 gallons)
(surrogate chemical: HC1)
Off-Site Fire
Typical Volume (100 gallons)
(surrogate chemical: Phosgene)
Meteorological
Conditions
Typical
Conservative
Calm/Inversion
Typical
Conservative
Calm/Inversion
Typical
Conservative
Calm/Inversion
Typical
Conservative
Calm/Inversion
Spill Duration1
Unmitigated
Unmitigated
Unmitigated
Unmitigated
Unmitigated
Unmitigated
Unmitigated
Unmitigated
Unmitigated
Unmitigated
Unmitigated
Unmitigated
Upper Bound
Concentration
at Distance
to School
(ppm):-J
0.18
24
NE
0.0019
0.26
NE
0.018
2.4
NE
0.00019
0.026
NE
Notes:
1 For on-site accidents, both mitigated (10 minutes) and unmitigated scenarios were evaluated; for off-site
accidents, only unmitigated scenarios were evaluated.
2 Maximum 30 minute average concentration. Distance to school taken to be approximately 350 m
(approximately 270 m from the facility fenceline) for on-site events and approximately 790 m for off-site
events.
3 NE = Not evaluated.
Volume VII
VI-63
-------
TABLE VI-24
Estimated RHR Values and Probabilities of Occurrence for All Emission Scenarios
Run
No.
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
Accident Event
On-Site Spill Large Volume
(5000 gallons) of "Worst-case" Waste
(surrogate chemical: Formaldehyde)
On-Site Spill Large Volume
(5000 gallons) of "Typical" Waste
(surrogate chemical: Acetone)
, On-Site Spill Typical Volume
(100 gallons) of "Worst-case" Waste
(surrogate chemical: Formaldehyde)
Meteorological
Conditions
Typical
Conservative
Calm/Inversion
Typical
Conservative
Calm/Inversion
Typical
Conservative
Calm/Inversion
Spill Duration1
Unmitigated
10 minutes
Unmitigated
10 minutes
Unmitigated
10 minutes
Unmitigated
10 minutes
Unmitigated
10 minutes
Unmitigated
10 minutes
Unmitigated
10 minutes
Unmitigated
10 minutes
Unmitigated
10 minutes
Relative
Hazard
Ratio
(RHR)2
(unitless)M
11
8.6
150
73
190
73
0.01
0.0045
0.077
0.028
0.102
0.028
0.32
0.33
5
4.9
8.6
7.8
Probability of Occurrence5
events per year
5.0E-05 - 5.0E-06
5.0E-05 - 5.0E-06
5.9E-06 - 5.9E-07
5.9E-06 - 5.9E-07
l.OE-06- l.OE-07
l.OE-06- l.OE-07
5.0E-04 - 5.0E-05
5.0E-04 - 5.0E-05
5.9E-05 - 5.9E-06
5.9E-05 - 5.9E-06
l.OE-05- l.OE-06
l.OE-05- l.OE-06
5.0E-04 - 5.0E-05
5.0E-04-5.0E-05
5.9E-05 - 5.9E-06
5.9E-05 - 5.9E-06
l.OE-05- l.OE-06
1 .OE-05 - 1 .OE-06
frequency in years
1 in 20,000 - 1 in 200,000
1 in 20,000 - 1 in 200,000
1 in 170,000- 1 in 1,700,000
1 in 170,000- 1 in 1,700,000
1 in 1,000,000 - 1 in 10,000,000
1 in 1,000,000 - 1 in 10,000,000
1 in 2,000 - 1 in 20,000
1 in 2,000 - 1 in 70,000
1 in 17,000 - 1 in 170,000
1 in 17,000 - 1 in 170,000
1 in 100,000- 1 in 1,000,000
1 in 100,000- 1 in 1,000,000
1 in 2,000 - 1 in 20,000
1 in 2,000 - 1 in 20,000
1 in 17,000- 1 in 170,000
1 in 17,000 - 1 in 170,000
1 in 100,000- 1 in 1,000,000
1 in 100,000- 1 in 1,000,000
Volume VII
VI-64
-------
TABLE VI-24 (continued)
Estimated RHR Values and Probabilities of Occurrence for AH Emission Scenarios
Run
No.
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
Accident Event
On-Site Spill Typical Volume
(100 gallons) of "Typical" Waste
(surrogate chemical: Acetone)
On-Site Fire Large Volume
(20,000 gallons)
(surrogate chemical: HCI)
On-Site Fire Large Volume
(20,000 gallons)
(surrogate chemical: Phosgene)
Meteorological
Conditions
Typical
Conservative
Calm/Inversion
Typical
Conservative
Calm/Inversion
Typical
Conservative
Calm/Inversion
Spill Duration1
Unmitigated
10 minutes
Unmitigated
10 minutes
Unmitigated
10 minutes
Unmitigated
10 minutes
Unmitigated
10 minutes
Unmitigated
10 minutes
Unmitigated
10 minutes
Unmitigated
10 minutes
Unmitigated
10 minutes
Relative
Hazard
Ratio
(RHR)2
(unitless)34
0.00061
0.00039
0.0097
0.0036
0.012
0.0039
NC
NC
0.016
0.0027
NE
NE
NC
NC
0.0085
0.0015
NE
NE
Probability of Occurrence*
events per year
5.0E-03 - 5.0E-04
5.0E-03 - 5.0E-04
5.9E-04 - 5.9E-05
5.9E-04 - 5.9E-05
l.OE-04- l.OE-05
l.OE-04- l.OE-05
5.0E-05 - 5.0E-06
5.0E-05 - 5.0E-06
5.9E-06-5.9E-07
5.9E-06-5.9E-07
l.OE-06- l.OE-07
l.OE-06- l.OE-07
5.0E-05 - 5.0E-06
5.0E-05 - 5.0E-06
5.9E-06 - 5.9E-07
5.9E-06 - 5.9E-07
1 .OE-06 - 1 .OE-07
l.OE-06- l.OE-07
frequency in years
1 in 200 - 1 in 2,000
1 in 200 - 1 in 2,000
1 in 1,700- 1 in 17,000
1 in 1,700- 1 in 17,000
1 in 10,000 - 1 in 100,000
1 in 10,000 - 1 in 100,000
1 in 20,000 - 1 in 200,000
1 in 20,000 - 1 in 200,000
1 in 170,000- 1 in 1,700,000
1 in 170,000- 1 in 1,700,000
1 in 1,000,000 - 1 in 10,000,000
1 in 1,000,000 - 1 in 10,000,000
1 in 20,000 - 1 in 200,000
1 in 20,000 - 1 in 200,000
1 in 170,000- 1 in 1,700,000
1 in 170,000- 1 in 1,700,000
1 in 1,000,000 - 1 in 10,000,000
1 in 1,000,000 - 1 in 10,000,000
Volume VII
VI-65
-------
TABLE VI-24 (continued)
Estimated RHR Values and Probabilities of Occurrence for All Emission Scenarios
Run
No.
37
38
39
40
41
42
43
44
45
46
47
48
Accident Event
On-Site Fire Typical Volume
(200 gallons)
(surrogate chemical: HC1)
On-Site Fire Typical Volume
(200 gallons)
(surrogate chemical: Phosgene)
Meteorological
Conditions
Typical
Conservative
Calm/Inversion
Typical
Conservative
Calm/Inversion
Spill Duration1
Unmitigated
10 minutes
Unmitigated
10 minutes
Unmitigated
10 minutes
Unmitigated
10 minutes
Unmitigated
10 minutes
Unmitigated
10 minutes
Relative
Hazard
Ratio
(RHR)1
(unitless)'4
NC
NC
0.0016
0.00027
NE
NE
NC
NC
0.00085
0.00045
NE
NE
Probability of Occurrence*
events per year
5.0E-04 - 5.0E-05
5.0E-04 - 5.0E-05
5.9E-05 - 5.9E-06
5.9E-05 - 5.9E-06
l.OE-05- l.OE-06
l.OE-05- l.OE-06
5.0E-04 - 5.0E-05
5.0E-04 - 5.0E-05
5.9E-05 - 5.9E-06
5.9E-05 - 5.9E-06
l.OE-05- l.OE-06
l.OE-05- l.OE-06
frequency in years
1 in 2,000 - 1 in 20,000
1 in 2,000- 1 in 20,000
1 in 17,000 - 1 in 170,000
1 in 17,000 - 1 in 170,000
1 in 100,000- 1 in 1,000,000
1 in 100,000- 1 in 1,000,000
1 in 2,000 - 1 in 20,000
1 in 2,000 - 1 in 20,000
1 in 17,000 - 1 in 170,000
1 in 17,000 - 1 in 170,000
1 in 100,000- 1 in 1,000,000
1 in 100,000- 1 in 1,000,000
Volume VII
Vl-66
-------
TABLE VI-24 (continued)
Estimated RHR Values and Probabilities of Occurrence for All Emission Scenarios
Run
No.
49
50
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
Accident Event
On-Site Mixing of
Incompatible Wastes
Large Volume (10,000 gallons)
(surrogate chemical: HCI)
On-Site Mixing of
Incompatible Wastes
Typical Volume (200 gallons)
(surrogate chemical: HCI)
, Off-Site Spill; Large Volume
(5000 gals.) of "Worst-case" Waste
(surrogate chemical: Formaldehyde)
Off-Site Spill; Large Volume
(5000 gallons) of "Typical" Waste
(surrogate chemical: Acetone)
Meteorological
Conditions
Typical
Conservative
Calm/Inversion
Typical
Conservative
Calm/Inversion
Typical
Conservative
Calm/Inversion
Typical
Conservative
Calm/Inversion
Spill Duration1
Unmitigated
10 minutes
Unmitigated
10 minutes
Unmitigated
10 minutes
Unmitigated
10 minutes
Unmitigated
10 minutes
Unmitigated
10 minutes
Unmitigated
Unmitigated
Unmitigated
Unmitigated
Unmitigated
Unmitigated
Relative
Hazard
Ratio
(RHR)2
(unitless)3'4
17
9.9
140
72
170
100
0.38
0.38
4.9
4.9
9.1
9.1
2.9
42
64
0.0039
0.039
0.051
Probability of Occurrence5
events per year
5.0E-05 - 5.0E-06
5.0E-05 - 5.0E-06
5.9E-06 - 5.9E-07
5.9E-06-5.9E-07
l.OE-06- l.OE-07
l.OE-06- l.OE-07
5.0E-04 - 5.0E-05
5.0E-04 - 5.0E-05
5.9E-05 - 5.9E-06
5.9E-05 - 5.9E-06
l.OE-05- l.OE-06
l.OE-05- l.OE-06
1.6E-04- 1.6E-05
9.1E-06-9.1E-07
3.0E-06 - 3.0E-07
1 6E-03- 1.6E-04
9.1E-05-9.1E-06
3.0E-05 - 3.0E-06
frequency in years
1 in 20,000 - 1 in 200,000
1 in 20,000 - 1 in 200,000
1 in 170,000- 1 in 1,700,000
1 in 170,000- 1 in 1,700,000
1 in 1,000,000 - 1 in 10,000,000
1 in 1,000,000 - 1 in 10,000,000
1 in 2,000 - 1 in 20,000
1 in 2,000 - 1 in 10,000
1 in 17,000 - 1 in 170,000
1 in 17,000- 1 in 170,000
1 in 100,000- 1 in 1,000,000
1 in 100,000- 1 in 1,000,000
1 in 6,300- 1 in 63,000
1 in 110,000- ! in 1,100,000
1 in 330,000- 1 in 3,300,000
1 in 630 - 1 in 6,300
1 in 1 1 ,000 - 1 in 1 10,000
1 in 33, (XX)- 1 in 330,000
Volume VII
VI-67
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TABLE VI-24 (continued)
Estimated RHR Values and Probabilities of Occurrence for All Emission Scenarios
Run
No.
67
68
69
70
71
72
73
74
75
76
77
78
79
80
81
Accident Event
Off-Site Spill; Typical Volume
(100 gals.) of "Worst-case" Waste
(surrogate chemical: Formaldehyde)
Off-Site Spill; Typical Volume
(100 gallons) of "Typical" Waste
(surrogate chemical: Acetone)
Off-Site Fire Large Volume
(5000 gallons)
(surrogate chemical: HCI)
Off-Site Fire Large Volume
(5000 gallons)
(surrogate chemical: Phosgene)
Off-Site Fire
Typical Volume (100 gallons)
(surrogate chemical: HCI)
Meteorological
Conditions
Typical
Conservative
Calm/Inversion
Typical
Conservative
Calm/Inversion
Typical
Conservative
Calm/Inversion
Typical
Conservative
Calm/Inversion
Typical
Conservative
Calm/Inversion
Spill Duration1
Unmitigated
Unmitigated
Unmitigated
Unmitigated
Unmitigated
Unmitigated
Unmitigated
Unmitigated
Unmitigated
Unmitigated
Unmitigated
Unmitigated
Unmitigated
Unmitigated
Unmitigated
Relative
Hazard
Ratio
(RHR)1
(unitless)34
0.074
1.5
3.2
0.00014
0.0046
0.004
0.018
2.4
NE
0.0095
1.3
NE
0.0018
0.24
NE
Probability of Occurrence5
events per year
1.6E-03- 1.6E-04
9.1E-05-9.1E-06
3.0E-05 - 3.0E-06
1.6E-02- 1.6E-03
9.1E-04-9.1E-05
3.0E-04 - 3.0E-05
7.7E-05 - 7.7E-06
4.5E-06 - 4.5E-07
1.5E-06- 1.5E-07
7.7E-05 - 7.7E-06
4.5E-06 - 4.5E-07
1.5E-06- 1.5E-07
7.7E-04 - 7.7E-05
4.5E-05 - 4.5E-06
1.5E-05- 1.5E-06
frequency in years
1 in 630 - 1 in 6,300
1 in 11,000- 1 in 110,000
1 in 33,000 - 1 in 330,000
1 in 63 - 1 in 630
1 in 1 , 100 - 1 in 1 1 ,000
1 in 3,300 - 1 in 33,000
1 in 13,000- 1 in 130,000
1 in 220,000 - 1 in 2,200,000
1 in 670,000 - 1 in 6,700,000
1 in 13,000- 1 in 130,000
1 in 220,000 - 1 in 2,200,000
1 in 670,000 - 1 in 6,700,000
1 in 1,300- 1 in 13,000
1 in 22,000 - 1 in 220,000
1 in 67,000 - 1 in 670,000
Volume VII
VI-68
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TABLE VI-24 (continued)
Estimated RHR Values and Probabilities of Occurrence for All Emission Scenarios
Run
No.
82
83
84
Accident Event
Off-Site Fire Typical Volume
(100 gallons)
(surrogate chemical' Phosgene)
Meteorological
Conditions
Typical
Conservative
Calm/Inversion
Spill Duration'
Unmitigated
Unmitigated
Unmitigated
Relative
Hazard
Ratio
(RHR)2
(unitless)14
0.00095
0.13
NE
Probability of Occurrence'
events per year
7.7E-04 - 7.7E-05
4.5E-05 - 4.5E-06
1.5E-05- 1.5E-06
frequency in years
1 in 1,300- 1 in 13,000
1 in 22,000 - 1 in 220,000
1 in 67,000 - 1 in 670,000
Notes:
1 For on-site accidents, both mitigated (10 minute releases) and unmitigated scenarios were evaluated; for off-site accidents, only unmitigated scenarios were
evaluated.
2 Relative Hazard Ratio (RHR) = Worst-case concentration at the school divided by the LOG for the surrogate chemical.
3 NE = Not evaluated.
4 NC = Not calculated because upper bound concentration is negligible at the distance to the school (based on ISC-COMPDEP modeling results).
5 Probability per year of operation. For on-site events, accounts for wind blowing toward the school approximately 0.5%, 0.06% and 0.01% of the time for
typical, conservative, and calm/inversion meteorological conditions, respectively; for off-site events, accounts for wind blowing toward the school
approximately 16%, 0.9% and 0.3% of the time for typical, conservative, and calm/inversion meteorological conditions, respectively.
Volume VII
VI-69
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VII. UNCERTAINTIES
As emphasized in the U.S. EPA's exposure assessment guidelines (U.S. EPA 1992c),
identification and quantification of uncertainties is an important element of the risk assessment
process. The primary sources of uncertainty in a risk assessment are associated with both the
toxicity evaluation of chemicals of concern and the exposure assessment. These two sources
of uncertainty are discussed separately below.
A. Toxicity Evaluation
It is widely recognized that there is significant uncertainty associated with current
assessments of the toxicity of various chemicals. Sources of uncertainty in current toxicity
assessments for various chemicals may include inadequate toxicological data, extrapolation
from animals to humans, and a lack of knowledge regarding potential interactions among
various chemicals. The regulatory approach to dealing with these sources of uncertainty is to
use conservative techniques in deriving dose-response parameters. Because U.S. EPA relies
primarily upon the same data base (IRIS) for all its risk assessments, uncertainty in the dose-
response assessment is common to any risk assessment that uses toxicity data. More
sophisticated analyses of these uncertainties have not been included in the Accident Analysis
and the comparative rankings.
In the Accident Analysis, NIOSH IDLH and U.S. EPA LOG values are used to evaluate
the downwind distance over which adverse human health effects might be anticipated in the
event of an accident. IDLH values were originally developed by NIOSH to be protective of
healthy adult male workers, while LOG values account for potentially sensitive individuals in
the general population. Both IDLH and LOG values are believed to be protective, i.e., more
likely to overestimate than underestimate the potential for acute health effects.
B. Exposure Assessment
The sources and magnitude of the uncertainties associated with exposure assessment may
vary greatly from one risk assessment to another. These uncertainties are largely determined
by the media, chemicals, populations, pathways, data, and models involved in the assessment.
The U.S. EPA Exposure Assessment Guidelines (U.S. EPA 1992c) identify three types of
Volume VII VIM
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uncertainty typically associated with an exposure assessment: (1) scenario uncertainty,
(2) parameter uncertainty, and (3) model uncertainty. These types of uncertainty are discussed
in the context of the Accident Analysis in the following sections.
1. Scenario Uncertainty
Scenario uncertainty is the term used for uncertainty arising from the absence of
information needed to fully define the exposure and dose. Sources of scenario uncertainty
include errors in descriptive information; inaccurate professional judgment; and
incomplete analysis (e.g., failure to consider all exposed sub-groups and significant routes
of exposure).
Scenarios in the Accident Analysis are selected for quantitative evaluation to provide
a range of credible accident events. More extreme events, with potentially greater off-site
consequences, but significantly lower probabilities of occurrence, are also theoretically
possible. Such extreme events might include an on-site spill of 10,000 gallons of volatile
waste in an unbermed area, resulting from a collision of two full tankers, leading to high
volatile emissions. If these tank trucks in the scenario above carried incompatible wastes,
or the wastes were highly flammable, potential adverse consequences could be further
exacerbated. Under such scenarios, IDLH and LOG values could be exceeded over very
large off-site distances (e.g., > 10,000m). However, the likelihood of occurrence is
judged to be extremely small, given the very low probability of two trucks colliding on-
site, the low probability of the entire contents of both trucks being released, and the
presence of berms and drains in most paved areas where a large pool could otherwise
form.
Another major source of uncertainty is the incomplete information on waste
composition. Assumptions regarding the waste composition are critical in defining both
the nature and magnitude of accidental emissions. While the availability of data on waste
composition during the first year of operations at the WTI facility reduces this uncertainty,
some amount of scenario uncertainty is unavoidable because waste composition may
change over time.
A third major source of scenario uncertainty is the limited information available for
predicting emissions resulting from fires or the mixing of incompatible wastes. Under
these scenarios, substances are created as a result of chemical reactions involving
constituents in waste. The type and extent of these reactions is difficult to predict, and
there are also little relevant empirical data. For example, literally.'dozens of chemical
reactions could hypothetically occur during an open fire involving a complex waste
mixture, and data gaps exist regarding the initial composition of the waste mixture, the
Volume VII VII-2
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reactions which may occur between the constituents and the emission rates for toxic
substances which are produced by the combustion process. To offset such data gaps,
conservative assumptions are made regarding the composition of the wastes involved in
the accidents, and the rate of generation of toxic by-products. For example, a mass
balance approach is used to predict HC1 emissions due to mixing of incompatible wastes.
2. Parameter Uncertainty
The U.S. EPA Exposure Assessment Guidelines (U.S. EPA 1992c) indicate that
parameter uncertainty may arise from measurement errors, sampling errors, variability,
and the use of generic or surrogate data. Parameters that are subject to uncertainty
include those used to estimate emission rates (e.g., spill pool size and temperature) and
chemical concentrations in the media and locations of interest (e.g., wind speed and other
meteorological conditions).
Unlike uncertainty associated with scenario development, there are methods available
to quantify the magnitude and effect of uncertainty in a parameter value, such as spill size.
Sensitivity analysis is included in the Accident Analysis to examine the effects of certain
types of parameter uncertainty by developing both conservative and typical accident
scenarios, and evaluating the effect of a variety of meteorological conditions. For
example, in the on-site spill scenario, two different spill volumes are evaluated. For each
spill volume, two different chemicals (one higher hazard, one lower hazard), are assessed,
each under three different sets of meteorological conditions (typical, conservative and
calm/inversion). Finally, each combination of spill volume, chemical composition and
meteorological condition is evaluated with and without mitigation, resulting in a total of
24 conditions being quantitatively analyzed for the on-site spill scenario.
Meteorological uncertainty is partially offset by examining typical, conservative, and
calm/inversion weather conditions, and assuming that the wind is blowing continuously in
the direction of the nearest inhabited off-site area. The actual downwind distance
impacted by the potential release could be significantly less than that predicted for the
calm/inversion or conservative meteorological conditions, depending on the conditions at
the time of release. Other parameters such as humidity, height of the release, and ground
terrain features introduce additional uncertainty in the results.
Another potential source of parameter uncertainty is the need for physical/chemical
data for the substances of concern. Data on vapor pressure, molecular weight, boiling
point, density, and other properties are needed to model chemical emission rates. While
the uncertainty associated with some of these parameters is negligible (e.g., molecular
weight), it can be significant for other parameters (e.g., vapor pressure) for certain
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chemicals. Where such uncertainty is potentially significant, specific property values are
selected to overestimate, rather than underestimate, off-site chemical concentrations in air.
3. Model Uncertainty
Several models are used in the Accident Analysis to predict chemical releases and
subsequent atmospheric dispersion. Models required to predict release rates include the
following:
Approaches to predict the physical/chemical properties of a waste mixture based
on the properties of the pure components.
Models to predict chemical evaporation rates from spills.
Methods to predict the rate of generation of toxic gases as the result of mixing
two incompatible wastes.
Methods to predict the flame temperature and vapor cloud buoyancy in the event
of a waste fire.
Methods to predict the heat flux at various distances from a waste fire.
It is not feasible to quantify the extent of uncertainty inherent in each of these modeling
techniques. Thus, the modeling is generally implemented using assumptions expected to
result in an overestimate, rather than an underestimate, of chemical releases.
Many models have been developed to simulate the dispersion of short-term accidental
chemical releases. Each model has its own unique advantages and disadvantages. In the
Accident Analysis, two dispersion models (SLAB and ISC-COMPDEP) are used,
matching the appropriate model to the emission release condition. However, significant
uncertainties exist in the application of these models, particularly given the complex
topography in the immediate vicinity of the facility. Conservative assumptions are
generally made in applying these models to avoid underestimating potential off-site
consequences.
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C. Sensitivity Analyses
In order to evaluate the sensitivity of the results described in Chapter VI, a further
assessment is performed to examine the following specific issues:
The effect of active mitigation measures on severity of consequence. The effects of
terminating releases through active mitigation are assessed. Two active mitigation
time frames, 10 minutes and 60 minutes, are evaluated for the on-site accident
scenarios. In addition, the effect of an unconfmed (i.e., no berms) on-site spill is
evaluated to assess the highly unlikely failure of passive mitigation measures. Off-site
scenarios are not included in the sensitivity analysis because active mitigation would
likely take longer to occur. This sensitivity analysis is performed using IDLH values;
similar results are-expected using LOG values.
The effect of averaging time in comparing downwind concentrations to IDLH values.
In the Accident Analysis, downwind concentrations in air are averaged over a 30
minute period, and then compared to IDLH values developed by NIOSH based on a
30-minute exposure. For scenarios with maximum emission durations shorter than 30
minutes, the maximum exposure may be considerably higher than the 30-minute
average exposure. The effect of averaging downwind concentrations over a 30-
minute period is examined in the sensitivity analysis by comparing unaveraged
maximum exposure concentrations directly with the IDLH values.
Fire scenarios under calm/inversion meteorological conditions. As previously
discussed in Chapter V, the fire scenarios cannot be reliably evaluated using the ISC-
COMPDEP dispersion model for calm/inversion meteorological conditions. In this
sensitivity analysis, the results of dispersion modeling performed for calm/inversion
conditions using the CALPUFF model (Scire et al. 1995) are evaluated.
Each of these issues is addressed separately below.
Volume VII VH-5
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1. Effect of Mitigation Measures
In evaluating the effect of active mitigation, two time periods (10 minutes and
60 minutes) were assessed. Ten minutes is believed to be a conservative estimate of the
time it might take for automatic active mitigation procedures which are already in place to
halt emissions to air (e.g., foam or water deluge for fire suppression), or for a small spill
to be remediated. The time period for other active mitigation measures to be effective in
stopping emissions could be longer in the event of a conservative spill or fire situation, or
in the event that automatic active mitigation devices are not readily available or fail. In
these situations, sixty minutes or more may be required to effectively stop emissions.
In the WTI Emergency Plan Exercise (Von Roll 1993), a scenario was evaluated
involving two accidents which occur in sequence. The first accident is the shearing of the
cap and stem of a valve from the side of a tanker truck, resulting in a leak of hazardous
waste. In this exercise, it was estimated to take 10 minutes for the appropriate personnel
to reach the scene, and approximately an additional hour for the situation to be assessed,
the potential immediate off-site impact to be determined, the leak to be stopped and the
spill to be cleaned up.
The second accident involves a second truck colliding with the first truck, resulting in
the mixture of the (incompatible) contents of the two tankers. In this hypothetical
incident, two people have been injured. Therefore, the first twenty minutes are spent
removing the individuals from the accident area and assessing the situation. The leak of
materials is stopped after an additional 40 minutes.
In each of these accident scenarios, it appears that active mitigation measures and
emergency response can limit the release of chemicals to approximately one hour.
Because of the time required to notify the appropriate personnel and assess the situation
before proceeding, it is unlikely that a conservative release could be terminated within 10
minutes. In these two scenarios, 10 to 20 minutes have passed before any active response
designed to terminate emissions is initiated. Therefore, a mitigation time period of 60
minutes is also considered in this sensitivity analysis.
In the Accident Analysis, it was assumed that passive mitigation (e.g., berms, drains
and dikes) would be in place and effective for on-site scenarios. The likelihood of a
simultaneous accident and failure of the passive mitigation system is very small.
However, the impact of the failure of passive systems is illustrated through an evaluation
of the on-site spill in this sensitivity analysis.
Volume VII VII-6
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a) On-Site Spills
Active Mitigation
As shown in Table VI-8, assuming no active mitigation of a 5,000 gallon on-site
spill of "worst-case" waste, exceedances of the IDLH for formaldehyde extend to
approximately 8,250 m, 4,870 m and 870 m, under calm/inversion, conservative and
typical meteorological conditions, respectively. If it is assumed that mitigation and
emergency response limit emissions to a duration of 10 minutes, exceedances of the
IDLH for formaldehyde are reduced to 4,300 m, 3,900 m and 730 m, respectively
(Table VII-1). Therefore, the effect of mitigation, assuming the 10 minute response
time, reduces the predicted downwind distance to the IDLH by approximately 50% or
less, depending on the meteorological conditions. If active mitigation takes 60
minutes, the maximum downwind distance is the same as for no active mitigation.
Active mitigation has relatively little effect on the maximum distance downwind
to the IDLH value for the 100 gallon spill of formaldehyde waste. The effect of
mitigation, assuming the 10-minute response time, reduces the predicted downwind
distance to the IDLH by approximately 10% or less, depending on the meteorological
conditions. Additionally, as was discussed in Chapter VI, exceedances of the IDLH
value for acetone are not predicted to occur at any off-site inhabited locations, with or
without active mitigation.
Failure of Passive Mitigation
The size of the on-site spill scenario dictates the size of the off-site area that
could be impacted by the release. The larger the source area, the higher the
downwind concentration will be. To assess the increased spill size associated with a
failure of passive mitigation systems, the 5,000 gallon on-site spill of "worst-case"
waste was considered in the sensitivity analysis.
If a 5,000 gallon spill occurs on-site at a location without the berms or drains, the
source area would be approximately 4.5 tunes'greater than the area confined by the
berms, based on the assumption that the spill will form a liquid pool of 1 cm in depth.
A sensitivity analysis is performed to examine the distance to the IDLH concentration
for the on-site spill scenario.
For the 5,000 gallon spill of formaldehyde/methanol waste, the distance to the
IDLH concentration increases slightly for a release with no passive mitigation. Under
the typical meteorological condition, the distance to the IDLH concentration increases
by approximately 15%, from 870 m (for the confined release) to approximately
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980 m. Under the conservative meteorological condition, the distance to the IDLH
concentration increases from 4,870 m to approximately 5,000 m. A significant
increase in the maximum downwind distance would not be expected under
calm/inversion conditions. It should be emphasized that the passive mitigation
measures are already in place at the WTI facility, as shown in Table II-1.
b) On-Site Fires
As shown in Table VI-10 and discussed in Chapter VI, exceedances of the IDLH
values for HC1 and phosgene are not expected off-site with any combination of waste
volume ignited and meteorological conditions. Active mitigation procedures,
therefore, would not affect the results of these scenarios.
c.) On-Site Mixing of Incompatible Wastes
For the mixing of compatible waste scenario involving 10,000 gallons of waste,
the maximum downwind distance to reach exceedances of the IDLH value for HC1
without active mitigation are 4,630 m, 3,190 m and 680 m, for calm/inversion,
conservative and typical meteorological conditions, respectively (Table VI-12).
Mitigation within 10 minutes decreases the projected downwind distances under
calm/inversion and conservative conditions by approximately 30%, to 3,380 m and
2,170 m, respectively (Table VII-3). Mitigation within 10 minutes effectively
contains emissions to within the site boundaries under typical meteorological
conditions.
For the mixing of incompatible waste scenario involving 200 gallons of waste,
active mitigation within 10 minutes does not significantly reduce the maximum
downwind distance to the IDLH. Similarly, active mitigation requiring 60 minutes to
implement would not effect the results of the no-mitigation scenarios for either the
10,000 gallon or 200 gallon events.
2. Effect of Averaging Time
In order to make a direct comparison between the modeled off-site concentrations and
the IDLH value, which is based on a 30-minute exposure period, the modeled off-site
concentrations are also averaged over a 30-minute period. For events where exposures
are shorter than 30 minutes, this averaging serves to effectively decrease the modeled
concentration, therefore decreasing the downwind distance over which the IDLH is
exceeded.
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For a continuous plume, which applies to the on-site and off-site fire scenarios, the
concentrations downwind of a source generally decrease with increasing averaging time
due to the increased meandering of wind direction (Turner 1967):
Ct = C,_Ar (60/r/ (6)
where, Cs = Concentration averaged over tj, (ppm);
ts = the averaging time (minutes);
C,.hr = the 1-hr average concentration (ppm); and
p = 0.2 (U.S. EPA 1988).
The decrease in concentration follows a one-fifth power law with the averaging time for
averaging periods from approximately 3 to 30 minutes (Steward et al, as cited by Turner
1967). Studies also indicate the power law exponent could vary between 0.17 and 0.2 and
the power law relationship could be applied to averaging times up to 24 hours (Turner
1967). Based on the one-fifth power law relationship, a 15-minute average concentration
will be approximately 15% greater than a 30-minute average.
For a continuous finite duration release, which applies to the spill events and the
mixing of incompatible waste scenarios, the average concentration will be reduced from
the peak concentration if the averaging time is greater than the source release time,
because the release is relatively short and the receptor is exposed to the material for only a
fraction of the concentration averaging time. For receptors located within a short distance
downwind of the source (e.g. with 1 km downwind of the source), the exposure time is
approximately the same as the source release time. Therefore, a 10-minute average
concentration would be 3 times higher than a 30-minute average concentration if the
release duration is only 10 minutes. Accordingly, the distance to the IDLH concentration,
based on the 10-minute average concentration, will be greater than that defined based on
the 30-minute average concentration.
To quantitatively evaluate the effect of averaging time on the downwind distance
exceeding the IDLH, two events are examined in the sensitivity analysis:
On-site spill of 100 gallons of formaldehyde waste
On-site mixing of 10,000 gallons of incompatible wastes *
Volume VII VH-9
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The results of this analysis are shown in Table VII-4. For the on-site spill of
formaldehyde waste, the predicted emission duration is approximately 11 minutes. In the
Accident Analysis, the downwind concentrations from this 11 minute release are averaged
over 30 minutes and then compared to the IDLH. In this sensitivity analysis, the
downwind concentrations averaged over the 11-minute time span are compared directly to
the IDLH.
As shown in Table VIM, there is an increase in the maximum distance to the IDLH,
if the IDLH is compared directly to the downwind concentration averaged over the 11 -
minute time span. The greatest relative increase is under typical meteorological
conditions, where the downwind distance to the IDLH increases from 40 m to 140 m.
This would result in the event being reclassified as having major rather than moderate
consequences. The downwind distance increases from 550 m to 850 m under conservative
meteorological conditions, and from 1,000 m to 1,310 m under calm/inversion
meteorological conditions. Thus, the event would remain classified as having major
consequences under conservative meteorological conditions, but reclassified as having
catastrophic consequences under calm/inversion conditions. The probability of occurrence
ranking would not change for any meteorological condition.
The relative increases in maximum distance to IDLH are less significant for the on-
site mixing of incompatible waste scenario. The maximum distance to the IDLH increases
by approximately 30% for typical meteorological (680 m to 870 m), by approximately
10% for conservative meteorological conditions (3,190 m to 3,480 m), and by
approximately 5% for calm/inversion meteorological conditions (4,630 m to 4,800 m).
The severity of consequence classifications and the probability of occurrence ranking
would not change for any meteorological condition.
3. Fire Scenarios under Calm/Inversion Meteorological Conditions
As discussed in Chapter V, the ISC-COMPDEP model was used to evaluate off-site
concentrations resulting from accidental fires under both typical and conservative
meteorological conditions. However, ISC-COMPDEP is not appropriate for use when
evaluating atmospheric dispersion of releases from accidental fires under calm/inversion
conditions, because the basic Gaussian steady-state assumptions of the model become
invalid.
In order to evaluate the potential effect of emissions from the WTI fire scenarios
under calm/inversion meteorological conditions, as recommended in the Report on the
USEPA Technical Workshop on WTI Incinerator Risk Assessment Issues (U.S. EPA
1996b), a sensitivity analysis was performed using the CALPUFF model (Scire et al.
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1995). The CALPUFF model is capable of modeling buoyant releases under calm
meteorological conditions, as well as accounting for complex terrain, building wake
effects and time-varying emissions. A more detailed description of the CALPUFF model,
and its use in evaluating calm/inversion conditions for the fire scenarios, is presented in
Volume VIII. As discussed in Volume VIII, the following fire scenarios were modeled
using CALPUFF assuming calm/inversion meteorological conditions:
On-Site Fire, Unmitigated Conservative (Large Fire);
On-Site Fire, Mitigated Conservative (Large Fire);
On-Site Fire, Unmitigated Typical (Small Fire);
Off-Site Fire, Unmitigated Conservative (Large Fire); and
Off-Site Fire, Unmitigated Typical (Small Fire).
The calm/inversion meteorological conditions are represented by the CALPUFF
model as zero wind speed for the first hour followed by a screening meteorological
condition of 54 combinations of wind speed and stability for the remaining duration of the
fire. This representation of the calm/inversion meteorological conditions for the fire
scenarios is slightly different than for the spill and mixing of incompatible waste
scenarios, which involved vapor accumulation for one hour followed by a low wind speed
for the remaining duration of emissions. The screening meteorological conditions were
used for the fire scenarios due to the possibility that higher wind speeds may bring a
buoyant plume down to ground-level more quickly, and thus result in higher off-site
concentrations.
The maximum one-hour average concentration factors 0/g/m3 per g/s) for the
CALPUFF modeling under the calm/inversion conditions are compared to the results of
the ISC-COMPDEP modeling under conservative meteorological conditions in
Table VII-5. Concentration factors as a function of downwind distances is presented in
Volume Vin ("CALPUFF Modeling of Accidental Fires During Calm Wind Scenarios").
The concentration factors can be multiplied by the chemical-specific emission rate to
obtain the maximum one-hour average off-site air concentration. The one-hour average
concentrations are then multiplied by a factor of 1.15 (as discussed in Section E.6 (b) of
Appendix VII-4) to convert a one-hour average concentration to a 30-minutes average
concentration so that a direct comparison can be made to the IDLH and LOC values. The
resulting distances to the IDLH and LOC values for the ISC-COMPDEP (for
conservative meteorological conditions) and CALPUFF (for calm/inversion
meteorological conditions) modeling are summarized in Table VII-6.
Volume VII VII-11
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As shown in Table VII-6, for the typical (small) on-site and off-site fire scenarios and
for the mitigated conservative (large) on-site fire scenario, IDLH and LOG values are not
exceeded by concentrations modeled using either the ISC-COMPDEP (for conservative
meteorological conditions) or CALPUFF (for calm/inversion meteorological conditions).
Therefore, the severity of consequence ranking for these scenarios would be "minor"
under both the calm/ inversion and conservative meteorological conditions.
For the unmitigated conservative (large) on-site fire scenario, the IDLH value for
hydrogen chloride is predicted by the CALPUFF modeling to be exceeded for a small area
within a down-wind distance of approximately 120 meters of the fire. Since the distance
from the fire to the nearest residence is approximately 75 meters, the distance beyond the
fenceline for which the IDLH value for hydrogen chloride may be exceeded is 45 meters.
This event would then be classified as having "moderate" severity of consequence
ranking. The ISC-COMPDEP modeling of conservative meteorological conditions did not
result in concentrations exceeding IDLH values, corresponding to a "minor" severity of
consequence ranking. The probability of occurrence for both the conservative and the
calm/inversion meteorological conditions is "very unlikely," however, the frequency of
occurrence would be lower for calm/inversion conditions than for conservative
meteorological conditions. The area over which LOC values are predicted to be exceeded
is larger based on CALPUFF modeling than on ISC-COMPDEP modeling.
For the unmitigated conservative (large) off-site fire scenario, the CALPUFF
modeling under calm/inversion meteorological conditions results in off-site air
concentrations which do not exceed either the IDLH or the LOC values. By comparison,
the ISC-COMPDEP modeling of conservative meteorological conditions resulted in
concentrations exceeding both IDLH and LOC values. Thus, the severity of consequence
ranking for this scenario would change from "major", based on the ISC-COMPDEP
modeling, to "minor" based on the CALPUFF modeling.
Table VII-7 summarizes the severity of consequence ranking and the probability of
occurrence for the fire scenarios under calm/inversion meteorological conditions.
Volume VII VII-12
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TABLE VIM
Consequence Assessment, On-Site Spill with Mitigation1'2
Spill Size
(gallons)
5,000
5,000
5,000
5,000
5,000
5,000
100
100
100
100
100
100
Meteorological
Conditions
Typical
Conservative
Calm/Inversion
Typical
Conservative
Calm/Inversion
Typical
Conservative
Calm/Inversion
Typical
Conservative
Calm/Inversion
Contaminant
Formaldehyde5
Formaldehyde5
Formaldehyde5
Acetone
Acetone
Acetone
Formaldehyde6
Formaldehyde6
Formaldehyde6
Acetone
Acetone
Acetone
Max. Downwind Dist. to
IDLH, 60 min mitigation
time3 (m)
870
4870
8250
--
--
40
550
1000
--
--
Max. Downwind Dist. to
IDLH, 10 min mitigation
time4 (m)
730
3920
4270
--
--
--
40
550
900
-
--
--
Notes:
1 Maximum downwind distance from the property line to the east or west, or the existing railroad to the north, whichever is closer to the location of the
release. For the on-site spill, maximum downwind distance was calculated from the railroad line to the north, approximately 75 m from the edge of the spill.
2 --: IDLH not exceeded in potential off-site receptor areas.
3 Actjve mitigation assumed to stop emissions within 60 minutes.
4 Active or automatic mitigation assumed to stop emissions within 10 minutes.
5 Unmitigated emissions of formaldehyde for this scenario last approximately 50 minutes.
6 Unmitigated emissions of formaldehyde for this scenario last approximately 1 1 minutes.
Volume VII
VII-13
-------
TABLE VII-2
Consequence Assessment, On-Site Fire with Mitigation1
Waste Volume
Ignited (gallons)
20,000
20,000
200
200
Meteorological
Conditions
Typical
Conservative
Typical
Conservative
Contaminant
HC1
Phosgene
HC1
Phosgene
HCI
Phosgene
HCI
Phosgene
Downwind Dist. to IDLH, 60 min
mitigation time2 (m)
..
.-
-.
~
--
Downwind Dist. to
IDLH, 10 min mitigation time1 (m)
..
-.
__
Notes:
1 : IDLH not exceeded in potential off-site receptor areas.
2 Active mitigation assumed to stop emissions within 60 minutes. The maximum downwind distance to IDLH using a 60-minute mitigation time is the same as
the maximum distance to IDLH with no active mitigation.
3 Active or automatic mitigation assumed to stop emissions within 10 minutes.
Volume VII
VII-14
-------
TABLE VII-3
Consequence Assessment, On-Site Mixing of Incompatible Wastes with Mitigation1 2
Waste Volume
(gallons)
10,000
10,000
10,000
200
200
200
Meteorological
Conditions
Typical
Conservative
Calm/Inversion
Typical
Conservative
Calm/Inversion
Contaminant
HC1
HCI
HCI
HCI
HCI
HCI
Max. Downwind Dist. to IDLH, 60 min
mitigation time1 (m)
680
3190
4630
.-
270
520
Max. Downwind Dist. to
IDLH, 10 min mitigation
time4 (m)
__
2170
3380
270
520
Notes
1 Maximum downwind distance from the property line to the east or west, or the existing railroad to the north, whichever is closer to the release. Fur the on-
site mixing of incompatible wastes, the maximum downwind distance was calculated from the railroad line to the north, or approximately 75 m from the edge
of the release.
2 --: IDLH not exceeded in potential off-site receptor areas.
3 Active mitigation assumed to stop emissions within 60 minutes. The maximum downwind distance to IDLH using a 60-minute mitigation time is the same as
the maximum distance to IDLH with no active mitigation.
4 Active or automatic mitigation assumed to stop emission within 10 minutes.
Volume VII
VIMS
-------
" " TABLE VII-4
Results of Averaging Time Sensitivity Analysis
Scenario
On-site spill of 100 gallons
of formaldehyde waste
On-site mixing of 10,000
gallons of incompatible
wastes
Chemical of
Concern
Formaldehyde
HCI
Emission Scenario
Typical
Conservative
Meteorological
Conditions
Typical
Conservative
Inversion/Calm
Typical
Conservative
Inversion/Calm
Concentration
Averaging Time
(s)
680
1800
680
1800
310
1800
1200
1800
1200
1800
760
1800
IDLH
(ppm)
19.6
19.6
19.6
19.6
19.6
19.6
49.1
49.1
49.1
49.1
49.1
49.1
Max. Dist. to
IDLIl (m)1
140
40
850
550
1310
1000
870
680
3480
3190
4800
4630
Note
1 Maximum downwind distance calculated from the property line to the east or west, or the existing railroad to the north, whichever is closer to the location of
the release For the on-site spill, maximum downwind distance was calculated from the railroad line to the north, approximately 75 in from the edge of the
spill.
Volume VII
VII-16
-------
TABLE VII-5
Summary of Maximum Concentration Factors Modeled by the
ISC-COMPDEP and CALPUFF Models for the Fire Scenarios
Scenario
On-Site Fire, Unmitigated
Conservative (Large Fire)
On-Site Fire, Mitigated
Conservative (Large Fire)
On-Site Fire, Unmitigated Typical
(Small Fire)
Off-Site Fire, Unmitigated
Conservative (Large Fire)
Off-Site Fire, Unmitigated Typical
(Small Fire)
Spill Area (m2)
180
180
75.7
735
37.9
Duration(s)
7030
600
170
430
170
Maximum One-hour Average
Concentration Factor
(Mg/m3 per g/s)
ISC-COMPDEP,
Conservative
Meteorological
Conditions'
63.4
NC3
NC
218.1
NC
CALPUFF.
Calm/Inversion
Meteorological
Conditions2
201.6
0.60
0.23
0.15
1.22
Notes:
1 Tables 16 and 17 of Appendix VIM
2 CALPUFF Modeling of Accidental Fires During Calm Wind Scenarios, EARTH TECH (see Volume VIII).
3 NC = Not calculated
-------
TABLE VII-6
Comparison of Downwind Distances to the IDLH and LOG Values Modeled
by the ISC-COMPDEP and CALPUFF Models for the Fire Scenarios
On-Site Fire, Unmitigated
Conservative (Large Fire)J
On-Site Fire, Mitigated
Conservative (Large Fire)'
On-Site Fire, Unmitigated
Typical (Small Fire)
Of: Site Fire, Unmitigated
Conservative (Large Fire)
Off-Site Fire, Unmitigated
Typical (Small Fire)
Distance to IDLH (m)u
ISC-COMPDEP,
Conservative Meteorological
Conditions
j
...
125 (Phosgene)
275 (HCI)
...
CALPUFF,
Calm/Inversion
Meteorological Conditions
25 - 45 (HCI)
(IDLH not exceeded
for phosgene)
...
Distance to LOC (m)1 2
ISC-COMPDEP,
Conservative Meteorological
Conditions
675, 1,1 25 (HCI)
(LOC not exceeded
for phosgene)
1,100 (Phosgene)
2, 100 (HCI)
CALPUFF,
Calm/Inversion
Meteorological Conditions
25 - 1 ,465 (Phosgene)
25 -2,410 (HCI)
Notes:
1 Modeling was performed for distances beyond 100 meters from the source.
2 Distances from the on-site fires are measured from the property line, which is approximately 75 meters from the center of the source.
3 Did not exceed the criteria for either phosgene or HCI.
Volume VII
VII-18
-------
TABLE VII-7
Severity of Consequence and Probability of Occurrence for the Fire Scenarios
Under Calm/Inversion Meteorological Conditions
Scenario
Severity of
Consequence
Probability of
Occurrence
On-Site Fires
20,000 Gallons of Waste (Large Fire)
200 Gallons of Waste (Small Fire)
Moderate'
Minor
Very Unlikely
Unlikely
Off-Site Fires
5,000 Gallons of Waste (Large Fire)
100 Gallons of Waste (Small Fire)
Moderate3
Moderate4
Very Unlikely
Very Unlikely
Notes:
On the basis of potential HCI and phosgene emissions, the 20,000-gallon on-site fire under calm/inversion
meteorological conditions is judged to have moderate consequences. On the basis of potential heat effects, the
event would be judged to have minor consequences. In the event of a fireball, the severity of consequence
would be classified as major; however, the potential for a fireball is very low.
On the bases of potential HCI and phosgene emissions, heat effects and assumed fireball formation, the 200-
gallon on-site fire under calm/inversion meteorological conditions is judged to have minor consequences.
On the basis of potential HCI and phosgene emissions, the 5,000-gallon off-site fire under calm/inversion
meteorological conditions is judged to have minor consequences. On the basis of potential heat effects, the
event would be judged to have moderate consequences. In the event of a fireball, the seventy of consequence
would be classified as major; however, the potential for a fireball is very low.
On the basis of potential HCI and phosgene emissions, the 100-gallon off-site fire under calm/inversion
meteorological conditions is judged to have minor consequences. On the basis of potential heat effects of the
fire, the event would be judged to have moderate consequences. In the event of a fireball, the severity of
consequence would be classified as moderate; however, the potential for a fireball is very low.
-------
VIII. SUMMARY AND CONCLUSIONS
The overall results of the Accident Analysis based on LOG values are presented in Tables
VIII-1 and VIII-2. Table VIII-1 summarizes the severity of consequence and probability of
occurrence rankings for each of the accident scenarios. Table Vni-2 indicates the number of
scenarios which fall into each of the probability/severity combinations. As shown in the
summary tables, the probability of an accident with major or catastrophic consequences is
classified as unlikely or very unlikely. With two exceptions (on-site spill of 100-gallons of
formaldehyde waste and the on-site mixing of 200 gallons of incompatible wastes, both under
typical meteorological conditions) the probability of an accident with moderate consequences is
also classified as unlikely or very unlikely. The probability of occurrence for each of these
two events is classified as reasonably likelv. Only events with minor consequences are
classified as likely to occur; no accidents evaluated in this assessment are classified as
common. Results based on IDLH values, as summarized in Tables VTH-3 and VIII-4, are
similar to those based on LOG values.
There is no standard approach for interpreting the results of an Accident Analysis. As
stated in FEMA (1993), "Special circumstances may require special consideration on a case by
case basis. Specific guidelines should be worked out by each locale to represent the resources
and relationships between organizations applicable to that community" (p. 13-5). According to
U.S. EPA (1987) and FEMA (1993), however, an accident frequency/severity screening
matrix approach can be useful in considering the results of an Accident Analysis. An
illustrative matrix suggested by FEMA (1993) is presented in Figure VIII-1. In this matrix,
the need for comprehensive planning and preparedness is linked to the probability of
occurrence and severity of consequence of an event. Based on Figure VIII-1, and
Tables VIII-1 to VIII-4, the results of the WTI Accident Analysis can be presented as follows:
"Events for which comprehensive planning and preparedness are essentially mandatory at
the appropriate levels of government or industry" (FEMA 1993)
On-site spills of 100 gallons acetone waste
VTT
-------
"Events for which comprehensive planning is optional and does not necessarily warrant
any major efforts or costs" (FEMA 1993)
On-site spills of 100 gal'ons of formaldehyde waste
On-site spill of 5,000 gallons of formaldehyde waste
On-site mixing of 200 gallons of incompatible wastes
On-site mixing of 10,000 gallons of incompatible wastes
Off-site spill of 100 gallons of formaldehyde waste
Off-site spill of 5,000 gallons of formaldehyde waste
Off-site fire involving 100 gallons of chlorinated waste
Off-site fire involving 5,000 gallons of chlorinated waste
"Events for which comprehensive planing mav be unwarranted and unnecessary"
(FEMA 1993)
On-site spill of 5,000 gallons of acetone waste
On-site fire involving 200 gallons of chlorinated waste
On-site fire involving 20,000 gallons of chlorinated waste
Off-site spill of 100 gallons of acetone waste
Off-site spill of 5,000 gallons of acetone waste
In general, the consequence-probability rankings summarized in Tables VIII-1 to VIII-3
are consistent with the information presented in the Report on Emergency Incidents at
Hazardous Waste Incinerators and Commercial Treatment, Storage and Disposal Facilities
(TSDFs) (U.S. EPA 1995b). Using the data from U.S. EPA (1995b), and the rankings based
on FEMA (1993), the probability of an event having moderate, major, or catastrophic
consequences would be classified as unlikely or very unlikely over a facility lifetime. The
probability of an event having minor consequences would be classified as likely or reasonably
likely. This generally agrees with the consequence-probability rankings used in this Accident
Analysis.
In response to Peer Review Panel comments, a screening-level evaluation of hypothetical
concentrations at the East Elementary School, which lies approximately 1,000 feet north of the
WTI incinerator, has also been performed. The results of the screening-level evaluation
indicate that, for most accident event scenarios, worst-case concentrations at the distance to the
school are below LOG values. The accident scenarios for which LOG values might be
exceeded at the distance to the school are to be very unlikely to occur during the life of the
facility.
Volume VII VIII-2
-------
TABLE VIII-1
Probability/Severity Matrix (Based on LOG Values)
Probability of
Occurrence
Common
Likely
Reasonably Likely
Unlikely
Very Unlikely
Severity of Consequence
Minor
Scenario 1A1
Scenario 1A2-3
Scenario 1C'
Scenario 2A'
Scenario 4 A1
Scenario 1C2-3
Scenario 2A2-3
Scenario 2B'
Scenario 4A2-3
Scenario- 4C'
Scenario 4C2
Moderate
Scenario IB'
Scenario 3A'
Scenario 5A'
Scenario 4B'
Scenario 2B2 3
Scenario 4CJ
Scenario 5A2-3-3*
Scenario 5B1-3
Major
Scenario IB2-3
Scenario ID'
Scenario 3A2-3
Scenario 3B'
Scenario 2B'*-2+-3*
Scenario 4B2-3
Scenario 4D1
Scenario SB'*-2-'3*
Catastrophic ||
Scenario ID2'
Scenario 3B2 '
Scenario 4D2 3
Scenario 5B2
Notes.
Scenario 1A
Scenario IB
Scenario 1C
Scenario ID
Scenario 2A
Scenario 2B
Scenario 3A
Scenario 3B
Scenario 4A
Scenario 4B
Scenario 4C
Scenario 4D
Scenario 5A
Scenario 5B
On-site spill, 100 gallons, acetone waste 1
On-site spill, 100 gallons, formaldehyde waste 2
On-site spill, 5,000 gallons, acetone waste 3
On-site spill, 5,000 gallons, formaldehyde waste +
On-site fire, 200 gallons , chlorinated waste
On-site fire, 20,000 gallons, chlorinated waste
On-site mixing of incompatible wastes, 200 gallons
On-site mixing of incompatible wastes, 10,000 gallons
Off-site spill, 100 gallons, acetone waste
Off-site spill, 100 gallons, formaldehyde waste
Off-site spill, 5,000 gallons, acetone waste
Off-site spill, 5,000 gallons, formaldehyde waste
Off-site fire, 100 gallons, chlorinated waste
Off-site fire, 5,000 gallons, chlorinated waste
= Typical meteorological 1
conditions
= Conserv. meteorological
conditions
= Calm / Inversion
= Ignition of vapor cloud
Volume VII
vm-3
-------
TABLE VIII-2
Probability/Severity Combinations (Based on LOG Values)
Probability of
Occurrence
Severity of Consequence
Minor
Moderate
Major
Catastrophic
Common
Likely
Reasonably Likely
Unlikely
Very Unlikely
SEVERITY OF CONSEQUENCE:
Minor - No exceedance of LOC; negligible potential for off-site or injuries due to heat effects
Moderate - Exceedance of LOC or heat effect injuries over distances up to 200 m
Major - Exceed LOC or heat effect injuries between distances of 200 m - 2000 m
Catastrophic - Exceed LOC or heat effect injuries over distances greater than 2000 m
PROBABILITY OF OCCURRENCE:
,ommon
Likely
Reasonably Likely
Unlikely
Very Unlikely
1 or more times each year on average
Once in 10 years on average
Once in 10 years - Once in 100 years
Once in 100 years - Once in 1000 years
Less than once in 1000 years
Volume VII
vm-4
-------
TABLE VIII-3 I
Probability/Severity Matrix (Based on IDLH Values)
Probability of
Occurrence
Common
Likely
Reasonably Likely
Unlikely
Very Unlikely
Severity of Consequence
Minor
Scenario 1A'
Scenario 1A2-3
Scenario 1C'
Scenario 2A1
Scenario 3 A1
Scenario 4 A1
Scenario 1C--3
Scenario 2A2-3
Scenario 2B'
Scenario 4A2-3
Scenario 4C'
Scenario 2B2
Scenario 4C2
Moderate
'
Scenario IB'
Scenario 5A'
Scenario 2B3
Scenario 4C3
Scenario 5A2-3 3*
Scenario 5B'-3
Major
Scenario IB2-3
Scenario ID'
Scenario 3A2J
Scenario 3B'
Scenario 4B1
Scenario 2B'+-2+-J+
Scenario 4B:
Scenario 4D1
Scenario 5B'+-22+-3+
Catastrophic ||
Scenario 1D:1
Scenario 3B: 3
Scenario 4B1
Scenario 4D; 3
Notes:
Scenario 1A
Scenario IB
Scenario 1C
Scenario ID
Scenario 2A
Scenario 2B
Scenario 3A
Scenario 3B
Scenario 4A
Scenario 4B
Scenario 4C
Scenario 4D
Scenario 5 A
Scenario 5B
On-site spill, 100 gallons, acetone waste 1
On-siie spill, 100 gallons, formaldehyde waste 2
On-site spill, 5,000 gallons, acetone waste 3
On-site spill, 5,000 gallons, formaldehyde waste +
On-site fire, 200 gallons , chlorinated waste
On-site fire, 20,000 gallons, chlorinated waste
On-site mixing of incompatible wastes, 200 gallons
On-site mixing of incompatible wastes, 10,000 gallons
Off-site spill, 100 gallons, acetone waste
Off-site spill, 100 gallons, formaldehyde waste
Off-site spill. 5,000 gallons, acetone waste
Off-site spill, 5,000 gallons, formaldehyde waste
Off-site fire, 100 gallons, chlorinated waste
Off-site fire, 5,000 gallons, chlorinated waste
= Typical met. conditions
= Conservative met. conditions
= Calm / Inversion
= Ignition of vapor cloud
Volume VII
vm-5
-------
TABLE VIII-4
Probability/Severity Combinations (Based on IDLH Values)
Probability of
Occurrence
Common
Likely
Reasonably Likely
Unlikely
Very Unlikely
Severity of Consequence
Minor
1
6
8
2
Moderate
1
1
7
Major
7
9
Catastrophic
1
1
7
SEVERITY OF CONSEQUENCE: II
Minor - No exceedance of IDLH; negligible potential for off-site or injuries due to heat effects
Moderate - Exceedance of IDLH or heat effect injuries over distances up to 100 m
Major - Exceed IDLH or heat effect injuries between distances of 100 m - 1000 m
Catastrophic - Exceed IDLH or heat effect injuries over distances greater than 1000 m
PROBABILITY OF OCCURRENCE:
Common
Likely
Reasonably Likely
Unlikely
Very Unlikely
1 or more times each year on average
Once in 10 years on average
Once in 10 years - Once in 100 years
Once in 100 years - Once in 1000 years
Less than once in 1000 vears
Volume VII
vm-6
-------
SEVERITY OF CONSEQUENCE
REASONABLY
LIKELY'
COMPREHENSIVE PLANNING AND PREPAREDNESS ARE ESSENTIALLY
MANDATORY AT THE APPROPRIATE LEVELS Of GOVERNMENT OR INDUSTRY.
COMPREHENSIVE PLANNING IS OPTIONAL AND DOES NOT NECESSARILY
WARRANT ANY MAJOR EFFORTS OR COSTS. GIVE CONSIDERATION TO
SHARING ANY NECESSARY SPECIAL RESPONSE RESOURCES ON A
REGIONAL BASIS
COMPREHENSIVE PLANNING MAY BE UNWARRANTED AND UNNECESSARY.
TAKEN FROM FEMA (1993)
External Review Draft
Do Not Cite or Quote
DRAFTED
JT
DATt 8/28/95
Volume VTI
ILLUSTRATIVE ACCIDENT
FREQUENCY/SEVERITY
SCREENING MATRIX
Figure
VIII-1
\rn.-r
-------
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the WTI Accident Analysis. Memorandum from C. Bogard, Region 5 RCRA Permitting
Branch, to C. Matthiessen, CEPPO.
United States Environmental Protection Agency (U.S. EPA). 1995d. Toxic Release
Inventory, Public Data Release. Washington, D.C. EPA 745-R-95-010.
United States Environmental Protection Agency (U.S. EPA). 1996a. Accidental release
prevention requirements: Risk management programs under Clean Air Act Section
112(r)(7); Final rule. Federal Register 61:31667-31730. June 20.
/
United States Environmental Protection Agency (U.S. EPA). 1996b. Report on the USEPA
Technical Workshop on WTI Incinerator Risk Assessment Issues.
Volume VII IX-4
-------
Victorine, G. U.S. EPA Region 5. 1995a. Personal Communication. Febmary.
Victorine, G. U.S. EPA Region 5. 1995b. Personal Communication. May.
Victorine, G. U.S. EPA Region 5. 1995c. Personal Communication. September.
/Victorine, G. U.S. EPA Region 5. 1995d. Personal Communication. July.
Victorine, G. U.S. EPA Region 5. 1997. Personal Communication. January.
Von Roll Corporation (Von Roll). 1993. Waste Technologies Industries: Emergency plan
exercise. September 23.
Von Roll Corporation (Von Roll). 1994. Von Roll Fire Protection Systems.
Waste Technologies Industries (WTI). 1982. Application to the U.S. Environmental
Protection Agency. September 4, as revised November 11.
Waste Technologies Industries (WTI). 1992. Contingency plan and spill prevention, control
and countermeasures plan. April 24.
VTT
-------
APPENDIX VIM
Incidents Reported at the WTI Facility
and Comparable Facilities
-------
CONTENTS
Page
Table 1: Hazardous Waste Combustor Facilities 1 -1
Table 2: Summary of Incidents Reported at Treatment, Storage and
Disposal Facilities 1-13
Table 3: Reported Equipment/Procedural Failures at the WTI Facility
(Victorine 1997) 1-18
Volume VII
AnnpndlY VTT-I
-------
TABLE 1
Hazardous Waste Combustor Facilities'
Facility
5-M
Cottage Grove, MN
Allied Chemical
(aka "Allied Signal, IMC -
Environmental Systems and
Services" inHWC|1995|)
Birmingham, AL
Aptus
'offeyville, KS
Aptus v
Aragonite, UT
Commercial
Incinerator?/
Capacity (tpy)z
No
l£5
PAIC& RC(1) 2,2(X)
Yes
PAIC: 60,850
RC(1): 219,000
(Per Victorine 1995b,
facility says permit limit is
same as PAIC, not higher
RCRIS value.)
Yss
RC(3): 86,000
Years of
Operation1
15 + (since
at least early
80s, per
U S. EPA
I995a)
15 +
(pre 81)
10
(since 86)
4
(Since late
91)
Reported Incidents4
(1) incinerator
operations, explosion
(2) incinerator
operations; explosion
NR
incinerator operations;
explosion
NR
Incident Date and Description
(1) Date Early 1980s
Description: hot slag contacted low
temperature ash quench water, resulting in a
thermal explosion.
(2) Date: 9/18/92
Pes,criplipr|: molten metal in slag dropped into
ash quench, trapping some water and creating a
steam explosion.
Date Fall 1990
Description: was.e with high Bill levpl
introduced to incinerator; gas accumulated in
scrubber and was set off by spark, causing an
explosion in the scrubber.
Reported
Impact
[\) no injuries; no releases to
the environment
(2) no injuries; brief release
of smoke from burning fuel
oil; no other releases ol
hazardous waste
no injuries; no natural
resource damages; no
hazardous waste released,
possible exceedances ol
hydrochloric acid and
particulates in air emissions
olume VII
ppendix VI1-1
-------
Facility
Atochem
Carrollion, KY
TABLE 1 (continued)
Hazardous Waste Combustor Facilities'
Commercial
Incinerator?/
Capacity (tpy)2
==
Yes
RC(3): 11,000
Per Viciorine 1995h,
F.PA Region IV calls this
i "limned commercial
incinerator," allowed to
receive only 3,SIX) tpy oft
site haz waste, feed limits
total 13.7(X)lpy )
Years of
Operation'
^=
15 +
(pre-81)
Reported Incidents4
NR
Incident Date and Description
Bridgeport Rental and Oil
Services (BROS), NJ
No
I) incinerator
operations, explosi in
(2) incinerator
operations; release
(l)Date: 9/20/92
Description: explosion caused by rapid steam
generation that resulted when a slag ring that
formed in the kiln fell into the water in the ash
quench; fugitive emissions resulted. Total
hydrocarbon (I i!C) monitor readings unusual
prior to explosion.
(2) Date: 9/21/92
Description: release of large amount of ash;
paniculate matter released for 8 minutes.
(I) fugitive emissions, no
injuries or natural resource
damage reported
(2) paniculate matter
traveled oil-site; no impacts
reported
Chemical Waste Management
(CWM)
Chicago, 1L
Yes
10 +
(pre-81 to
2/91)
incinerator operations;
explosion
Date: 2/13/91
Description: drum with a packet containing
tetrazole fed into rotary kiln, causing an
explosion.
no injuries or releases to
environment
Volume VII
Appendix VII-1
1-2
-------
TABLE 1 (continued)
Hazardous Waste Combustor Facilities'
Facility
Chemical Waste Management
(CWM)
Port Arthur, TX
Cheinroii'
Palmer, AK
Diversified Scientific Services,
Inc. (DSSI)
Kingston, TN
Dow Chemical
Midland, MI
V
Commercial
Incinerator?/
Capacity (tpy)2
Yes
Yej;
RC(2) & RC(3) combined
13,000
No
No
Years of
Operation'
6
(since -90)
Reported Incidents4
(1) incinerator
equipment failure, fire
2) equipment failure,
spill
NR
operations; fire
(1) incinerator
operations; explosion
(2) incinerator
operations; explosion
Incident Date and Description
1) Date: 6/92
description, kiln fire that resulted from
werheating during normal operation
(2) Date: 12/24792
description; one gallon of air pollution control
rain waste leaked; workers assumed it
contained PCBs; immediate cleanup, including
removal of asphalt and soil, until no visible
waste (tests showed waste did not contain
PCBs)
Date: 7/31/92
Descrjptipn'- electrical outage allowpil sump
unburned propane to go through boiler;
charcoal filters in secondary air pollution
control (APC) system caught fire and burned
for 4 minutes.
(1) Date: 1/25/92
Description: feed line to incincrnmr Mnrlr,.,!
nozzle removed improperly and natural gas
leaked out, causing an explosion.
(2) Date: 2/4/93
Description, explosion in indneniior-
-------
TABLE 1 (continued)
Hazardous Waste Combustor Facilities1
==========
Facility
=^^!====
E I. DuPonl de Nemours7
Axis, AL
Eastman Kodak Company
Kodak Park, NY
ECOVA (formerly Waste-lech)
Kimball, NE
ENSCO
El Dorado, AK
V
General Electric
Pittsfield, MA
Commercial
Incinerator?/
Capacity (tpy)2
==============-
No
No
Yes
PAIC 45,000
Yes
Yes
=====
Years of
Operation1
New
15 +
(pre-81)
15 +
(pre-81)
^^
Reported Incidents4
1) equipment failure;
pill
2) operations;
explosion
numerator equipment
ailure
NR
(1) incinerator
equipment failure;
explosion
(2) operations; fire
NR
Incident Date and Description
1) Date- 6/9/94
Ascription: approx 3,800 gallons sulfuric
acid released from leaking transfer pipe; 2,500
;allons recovered.
2) Date: 6/10/94
description: One drum containing hydrogen
peroxide and ground corncobs burst.
Date 7/12/90
description: Recycle cooling water system
ruptured, spilling 75 gal water (2 gal onto
ground, 73 gal into industrial sewer). Loss of
iressure in system following rupture caused an
automatic shut-l.iwn of the facility; emergency
stack opened, resulting in a visible plume from
stack that lastei1 7 minutes (wastes in the kiln at
the time were 1 )-chloro-2,4-dinitrobenzene and
2-methylhydroquinone).
(1) Date: 4/20/89
Pescription(s): explosion in waste heat
recovery unit due to equipment failure; no
hazardous waste involved
(2) Date: 8/10/93
Description' spontaneous combustion due to
worker leaving cap olf container of bromine
and chlorine
Reported
Impact
1) 300 yd1 contaminated soil
emoved (apparently on-sile)
2) none reported U
visible soil contamination II
rom spill to ground (cleaned II
up immediately); visible II
plume; no other information II
available II
(1) no injuries or significant
releases
(2) no injuries, no
information on
environmental impacts
Volume VII
Appendix VII-1
1-4
-------
Facility
~
IC1 Environmental
Jophn, MO
Johnston Atoll Chemical Agents
Disposal System (JACADS),
Johnston Atoll
>;
n
========
Commercial
Incinerator?/
Capacity (tpy)1
=gg^=
IBS
No
1
Hazardou
Years of
Operation1
»Jew
5
;tnal hum
2/90, per
app to U S
1;,PA I995a)
fABLE 1 (continue(
s Waste Combustor
^-^
Reported Incidents4
NR
1) incinerator
equipment failure
(2) incinerator
equipment failure, Tire
(3) incinerator
equipment failure
(4) incinerator
equipment failure
(5) incinerator
equipment failure
(6) spill
1)
Facilities'
Incident Date and Description
(1) Date: 12/90
pescripl'ion: short-term leakage of nerve agent
From agent feed system after feed shut off;
emissions lasted for 45 minutes
(2) Date 3/11/91
Description' instrumentation malfunction
resulting in smoke release, no chemical agent
heing processed.
(3) Date: 5/2/91
Description' small hearing cooling oil lire,
caused hy an overheated bearing.
(4) Date 6/26/91
Description: pressure transient occurred
during start-up, resulting in deformation of
furnace chamber and building.
(5) Date: 1/21/92
Description: kiln stopped rotating, system shii
down.
(6) Date: 12/18/92
Description: spill onto coral of 50 gal xvlene,
1.6 gal hexane, 0.6 gal isopropanol, due to
wind storm; contingency plan implemented,
soil (coral) sampling performed
Reported
Impact
1) emissions below
>ermitted levels
2) no information provided
(3) no harmful .releases II
reported II
(4) no information provided [1
(5) no releases reported
(ft) no information provided
olume VII
ppendix VII-1
1-5
-------
TABLE 1 (continued)
Hazardous Waste Combustor Facilities'
Facility
=====
Johnston Atoll Chemical Agents
Disposal System (JACADS)
(continued)
Commercial
Incinerator?/
Capacity (tpy)2
Years of
Operation'
Reported Incidents4
7) operations'
8) leak'
9) operations', ("ire
(10) operations; release
(II) operations' spill
(12) incinerator
equipment malfunction;
fire
(13) incinerator
equipment malfunction,
etc ; release
Incident Date and Description
7) Date 12/27-28/92
description losses of ventilation due to power
oss in Munitions Demilitarization Building
MDB); contingency plan implemented
8) Date 12/28/92
Description small amount of leakage from
rocket.
9) Date 1/2/93
Description fire in Explosion Containment
Room.
(10) Date 5/31/93
Description' potential release of 0.012 mg/m1
mustard gas outside building (allowable stack
cone. = 0.03 nip/m1)
(11) Dais: 12/9/93
Description: spill of 500 Ihs of chemical agent
in MDB.
(12) Oaje.: 3/14/94
Description: small fire caused by hot gases in
feed chute, due to feed gates jamming
(13)0.3!?.: 3/24/94
Description: release of chemical agent above
allowable limit for 25 minutes, due to design
and procedural problems, equipment
malfunction, and operator error.
7) no chemical agent
nigration outside building
!8) oil-site, no hazards to
niman health or environment
(9) no information provided
(10) no information provided
(11) spill contained in
building
(12) no migration of
hazardous waste inside or
outside facility
(13) maximum ground level
concentrations below
General Population Limit
Volume VII
Appendix VII-1
1-6
-------
TABLE 1 (continued)
Hazardous Waste Combustor Facilities1
Facility
Laidlaw Environmental
Roebuck SC
Laidlaw Environmental Services
Clarence, NY
>
Lake City Army Ammunition
Plant
Independence, MO
Commercial
Incinerator?/
Capacity (tpy)2
l£S
PA1C& RC(1). 39,000
les
RC(1): 131
(Per Victorine 1995b,
NYDEC indicates this is a
non-RCRA incinerator
due to 1CR exemption)
No
Years of
Operation1
15 +
(pre-81)
15 +
(pre-81)
Reported Incidents4
(1) transfer line failure
(2) bulk liquid storage
(3) incinerator
equipment failure
(4) operations'
(5) operations5, fire
NR
incinerator operations
Incident Date and Description
(1) Date: 3/17/82
Description: 3.000-gal solvents spilled from
corroded pipe that connects the blend tanks to
the incinerator.
(2) Date. 2/9/88
Description: 6.000-gal maleic anhydride
spilled from storage tank.
(3) Date 3/22/91
Description: thermal relief vent from
incinerator vaporizer blown off the unit, fell
down to the direct burn containment pad
(4) Dale: 2/8/91
Description: vapor cloud emitted during
redrumming ol orthochlorophenol.
(5) Date: 9/19/94
Description: small fiberglass fire, mntninril
and extinguished in 3 minutes.
Dale: 3/29/91
Description During trial burn, live miimk pm
through incinerator, not completely treated, fell
oft of conveyor bell and set oil
Reported
Impact
J) on-site: soil
contamination (removed)
off-site: no impacts noted
(2) oii-sile- soil
contamination (removed)
off-site- no impacts noted
(3) no injuries or known
ha/ardous waste releases
(4) oil-site' vapor cloud
drilled off-site; one person
reported sinus problem
(5) none reported
no injuries; no significant
rclcdsi's
olume VII
ppendix VII-1
1-7
-------
TABLE 1 (continued)
Hazardous Waste Combustor Facilities'
Facility
LWD
Clay, KY
Monsanto Company
Muscatine, IA
Rhone-Poulenc Basic Chemical
Company-Hammond Plant6
Hammond, IN
Rhone-Poulenc Basic Chemicals
Company
Baton Rouge, LA
Rhone-Poulenc Basic Chemicals
Houston, TX *;
Rollins Environmental Services
Logan Township, NJ (aka
Bridgeport)
Commercial
Incinerator?/
Capacity (tpy)!
Xes
No
Yes
PAIC: 80,000
(converted from 20 mil
gpy assuming 8 Ih/gal)
RC(3): 84,000
Yes
Yes
Yes
RC(1): 81,796
Years of
Operation3
15 +
(pre-81)
15 +
(pre-81)
15 +
(pre-81)
25 (since 70
perLI.S
EPA 1995a,
App 1)
Reported Incidents4
transportation; Tire
incinerator equipment
failure; fire
NR
NR
NR
hulk liquid storage;
fire5
Incident Date and Description
Date: 2/2/82
Description: direct feed tank truck containing
acetone exploded and caught fire; three other
trucks also caught fire; no releases. Facility
now closed.
Date 7/92
Description: loss of quench water flow thai
caused temperature in scrubber to rise, causing
fire Incinerator only burning natural gas at
the time
Date: 12/8/77
Description: series of explosions and fires at a
tank farm.
Reported
Impact
on-site: operator had burns,
fractured leg; oil/acetone
mixture released, releases
contained 1.1 berm
off-site: lire -lighting water
reached drainage ditch, then
creek
no injuries, no release of
hazardous waste
on-site. 6 fatalities, 12
injuries, soil and giound
water contamination
oil site- no contamination
Volume VII
Appendix VII-1
1-8
-------
TABLE 1 (continued)
Hazardous Waste Combustor Facilities1
Facility
Rollins Environmental Services
Uaton Rouge, LA
Rollins Environmental Services
Deer l';irk, IX
Ross Incinei.iiion Services
(jrafton, OH
Commercial
Incinerator?/
Capacity (tpy)1
lei
RC(3) 59,000
or
RC(1) 289,605
(converted from 30 metric
tons/hr, assuming 1 metric
ton = 1 102 tons)
Yes
RCO) 122. (KM)
Yes
RC(1) 140.160
or
RC(2) 105,000
Years of
Operation1
15 +
(pre-81)
15 t
(pre-81)
15 +
(pre-81)
Reported Incidents4
NR
operations, fiie
( 1 ) incinerator
operations, fire
(2) incinerator
operations; explosion
Incident Date and Description
Date 11/91
Description fire in furnace duct.
(DDjtg 8/12 M
Description- drum ignited due to acid residue
improperly left on skid, cyclohexane, styrene,
and mineral spirits released to air.
(2) Dale: 5/1/95
Description: explosion in secondary
combustion chamber while feeding drummed
waste; chamber damaged; roof left open to
environment.
Reported
Impact
no information provided II
(1) one worker injured, no
inlormation on
environmental impacts
(2) no injuries; fugitive
emissions, no information on
environmental impacts
'olume VII
Appendix VII-1
1-9
-------
TABLE 1 (continued)
Hazardous Waste Combustor Facilities1
Facility
Commercial
Incinerator?/
Capacity (tpy)z
Years of
Operation*
Reported Incidents4
Incident Date and Description
Reported
Impact
HiermalKEM
Rock Hill, SC
Yes
'A1C: 25,000
15 +
(pre-81)
1) incinerator
iperations; explosion
(2) incinerator
operations, explosion
(3) incinerator
equipment failure;
explosion
(4) fire'
(5) mixing wastes'; fire
(l)Date 7/10/87
Description- three explosions resulted when
incorrectly identified nitroglycerine/
lactose material introduced into incinerator
(2) Date: 12/8/88
Description: drum caused strong reaction in
incinerator, which caused release of safety
pressure relief door and fuel line rupture,
caused by nitrocellulose incorrectly identified
as non-reactive.
(3) Date. 3/24/91
Description: low water pressure caused boiler
tube to fail, causing the package boiler to
explode. The incinerator was burning natural
gas at the time -f the explosion.
(4) Date: 4/25/93
Description: hydraulic hoses and oil, part of
drum repackaging system, caught fire.
(5) Date: 1/14/95
Description: fire in Drum Repackaging
(I) no environmental
releases or fires
(2) no information provided
Building, caused by improperly mixed wastes;
off site response agencies notified.
(3) no off-site impact,
diesel/waler spill was
contained
(4) no releases or iii|inics
(5) off-site' no releases
above reportable quantity
Volume VII
Appendix VII-1
1-10
-------
TABLE 1 (continued)
Hazardous Waste Combustor Facilities'
Facility
IWI
Sauget, IL
USDOE
Oak Ridge, TN
United States Pollution Control
Inc. (USPCI)
Clive, UT
Waste Reclamation and Research
Eau Claire, Wl v.
Commercial
Incinerator?/
Capacity (tpy)2
Y£S
RC(3): 50,000
No
Yes
RC(I): 359,160
Yes
PAIC: 2,500 (converted
from 624,000gpy to tpy
assuming 8 Ih/gal)
RC(2): 3,500
Years of
Operation'
15 +
(pre-81)
1
(Since 94)
15 +
(pre-81)
Reported Incidents4
(1) mixing of
incompatible wastes
(2) operations;
explosion
(3) incinerator
operations, explosion
incinerator equipment
failure
NR
NR
Incident Date and Description
(1) Date 1/16/90
Description' blending tank released plume of
196 Ibs of hydrochloric acid, due to improper
identification of corrosivity of waste being
added to tank.
(2) Date: 1/26/91
Description1 sodium azide incinerated- ash
placed in a dumpster; ash exploded a few hours
later.
(3) Date 2/5/91
Description molten slag partly blocked exit
from incinerator during operation; slag
dislodged and fell into standing water below,
causing a steam explosion
Date 6/15/89
Description: induced dratt fan for incinerator
failed; flying debris damaged stack.
Reported
Impact
(1) no information provided
;2) no ni]iiries or
environmental impacts
reported
(3) one wotker injury,
vaporized hazardous waste
released, no environmental
impacts
no injuiies; no detectable
off site releases of toxic
material
olume VII
Appendix VII-1
1-11
-------
TABLE 1 (continued)
Hazardous Waste Combustor Facilities'
Facility
Waste Technologies Industries
hast Liverpool, OH
Commercial
Incinerator?/
Capacity (tpy)1
Yes
PA1C& RC(3) 60,000
Years of
Operation5
2
(Since 93)
Reported Incidents4
NR, No major incidents
reported in I) S I- PA
(!995b)
Incident Date and Description
Reported
Impact
Notes:
Sources'
US FPA I995h Repon on Emergemy ln< iiienis (it Hazardous Waste Ini meralors and Commen tal Treatment, Storage, and Disposal Facilities fl'SDFs) Draft
May
Victorine, G US EPA Region 5 I995a Facsimile memo to Stall Members in OSW and FPA Regions, with List of Commercial Hazardous Waste Incinerators,
Providing Years of Operation under RCRA Regulations
Victorine, G US EPA Region 5 1995d Facsimile memo to M Mangmo Providing Capacity Information on Selected Commercial Incinerators July 27
Tfie Hazardous Wtnii' Consultant (HWC) 1995 Commercial Hazardous Waste Management Facilities: 1995 Survey of North America Vol 13, Issue 2,
March/April
"Yes" Dignities facility was identified as a commercial incinerator m Victorine (1995a)
Capacity Information (all capacities listed in tons per year |tpy|)
PAIC = permitted annual incineration capacity listed in IIWC (1995)
Capacities from RCR1S. retained from Victorine (1995b)
RC(1) = capacity per RCRIS in tpy, converted from tons/hr or Ih/hr
RC(2) = capacity per RCRIS in tpy, converted from gal/day or gal/hr assuming 1 gal ^8 Ihs (based on 128 ounces per gallon/16 ounces per pound)
RC(3) = capacity per RCRIS in tpy, converted from MMHTU/hour based on note in Viclorine (1995b) indicating that at one incinerator, 98 MMH'I U/hr is approximately
equal to 60,000 tpy
Values of RC(2) and RC(3), converted from liquid or thermal capacities, are rounded to two significant figures to reflect uncertainty in conversion factors
All calculations assume 24 hour/day operation
Years of operation are from Victorine (1995a) unless otherwise noted
NR = No incidents reported in U S. EPA (1995b).
Incident related to waste handling or storage, not incineration
Facility identified in HWC (1995), not listed in Victorine (1995a) Victorine (1995d) provides capacity information for rotary calciner and boiler
This facility is identified as a "permitted DuPont commercial combustion facility" in U.S. EPA (I995b), but not listed as such elsewhere. According to Chip Crockett of the
Alabama Environmental Management Agency (telephone call, 7/13/95), this facility burns only hazardous war,te generated on-site, and is not a commercial combustion lacilily
Volume VII
Appendix VII-1
1-12
-------
TABLE 2
Summary of Incidents Reported at Treatment, Storage and Disposal Facilities'
Facility
Reported Incidents
Incident Date and Description
Reported
Impact
\lhright and Wilson
Charleston, SC
I) explosion and fire
(2) equipment failure
1) Date 6/17/91
Jescription explosion and fire in Special Products Unit.
2) Date: 1/14/93
Description' rupture in steam jacket and piping released steam and by-
1) nine deaths (apparently on site),
ire figliling water flowed lo
onlaminenl pond
2) no information
products.
Mote- Neither incident involved hazardous waste.
Carolina So lite
Norwood, NC
(1) equipment failure.
spill
(2) equipment failure,
spill
(1) Date: 11/4/93
Description: waste blend tank hurst pipe, spilled 2,500 gal of waste; most
of spill contained; 50 to 100 gal escaped to soil; cleaned up.
(2) Date: 1/94
Description: similar to 11/93
(1) soil contamination (remediated), no
mman or environmental impacts
reported
(2)
Chemical Waste Management
Commercial TSD)
Imelle, AL
(1) mixing waste, fire
(2) operations
(3) mixing waste; fire
(4) "ball of fire"
(5) flash fire
(l)Date: 11/10/92
Description, while oil was being added to drum of epichlorohydrin,
mixture ignited.
(2) Date: 12/5/92
Description: 170,000 gal water pumped from fire water tank to crusher
dispersion unit, found to be contaminated with D039 waste; ditch through
which water flowed had contaminated soil.
(3) Date: 12/8/92
Description fire in vat of D004/D018 hazardous waste after addition of
Portland cement.
(4) Date- 1/9/93
Description: employee observed ball of fire rising above active trench,
followed by puff of smoke and another hall of fire.
(5) DM 2/26/93
Description' flash-ignition of reagent sulfur as it was mixed with waste;
lasted 1-2 seconds
(1) no injuries
(2) soil contamination (remediated)
(3) no injuries, no releases
(4) no information
(5) no visible releases ol li;i/ardous
substances
olume VII
ppendix VII-1
1-13
-------
TABLE 2 (continued)
Summary of Incidents Reported at Treatment, Storage and Disposal Facilities
- " ~- .. l'..=^J
Facility
M_ .-ii ' ' "" g^^SS' " "
"hemieal Waste Management
Arlington, OR
C'hemPro
1 aeoma, WA
('hem Tech Systems
I .os Angeles, CA
(T Chemicals
Suniter, SC
Delaware Container Company
Coatcsville, i'A
Fisher Industrial Services, Inc.
(Commercial TSD)
Glencoe, AL
Holnam/Safety-Kleen
Holly Hill, SC
V
International Paper
Joplin, MO
-
Reported Incidents
^=r^=^====^=:=:
"ire
operations, spill
hulk liquid handling
bulk liquid Murage
mixing ot incompatible
wastes
fire
(1) hulk liquid storage;
explosion
(2) transportation
transfer line failure
Incident Date and Description
3ate: 5/5/94
3escnp(ion ("ire in landfill, believed to be due to disposing wood debris
near stabilized, heat-generating waste streams.
Date - 87
Description 10.(XX)-gal spill of chromic acid through kxise valve
Pate: 8/29/94
Description release of nitrous oxide; acute emissions lasting 20 minutes to
1 hour, during transfer of water with chrome into tank with mixed acids
Date 11/29/85
Description spill of 2,200 gal ammonia and 2,(XX)-gal hydrochloric acid
from two storage tanks (lank valves left open by employees | intentionally))
Date 10/14/85
pe$crjp|ipn waste containing aluminum-based pain! (not on manifest)
released "some gas", residents delected odor, emergency personnel called
Dace: 8/13/93
pescriptjon. small Tire in roll off, including various D- and F- listed
wastes; fire restricted to container
(11 Date: 10/23/87
Description: 100,000-gal fuel tank exploded
(2) Date 8/13/92
Description. 638-eal spill during railcar transfer
Date- 10/1/92
Description: water contaminated with wood-treating wastes released during
transfer from one closed surface impoundment to another; 30,(XX) gal
released to the environment
Reported II
Impact II
jl
10 injuries; fire contained in landfill 11
soil contamination
two on-.sile employees complained of
di/.ziness and nausea, air emissions
dispersed by wind
no information provided
32 residents (or I(H), pet community) II
ireated for nose and Ihroat iinialions;
no hospitali/.ations or fatalities II
no information provided II
(1) no information provided (not a 1
regulated unit)
(2) site remediated
no information provided on waste
concentration in water or result of
release |
Volume VII
Appendix VIM
14
-------
TABLE 2 (continued)
Summary of Incidents Reported at Treatment, Storage and Disposal Facilities'
Facility
Reported Incidents
Incident Dale and Description
Reported
Impact
l.aidlaw Environmental Services
(GSX Laidlaw Landfill)
I'inewood, SC
Mill Service
Yukon, PA
I) operations; fire
(2) operations
(3) operations; fire
(4) fire
(5) waste mixing, lire
DDate: 1991
Jescription fire at drum shredder unit
(2) Date 2/92
Description' spill at waste solidification unit
(3) Date: 9/9/93
Description: fire at drum shredder unit, involving two drums of lithium
manganese batteries
(4) Date 4/12/94
Description fire involving alkaline batteries
(5) Date unknown
Description' smoke and small pockets ol llame from oil and grease
treatment tanks; later discovered load also contained caustic manure and
aluminum
(1) operations
(2) bulk liquid
unloading
(I) Date: 11/12/91
Description: partially treated waste sludges accidentally placed in a surface
impoundment.
(2) Date: six times in last 10 years, none since '92
Description: nitric acid puffs occur from waste pickle liquor. This occurs
when the dome of a tank truck that was not cleaned out properly is
removed.
1) no major release
2) soil contaminated (remediated)
3) no injuries reported
(4) no injuries reported
(5) no information provided
(1) no information provided
(2) no information provided
olume VII
Appendix VII-1
15
-------
TABLE 2 (continued)
Summary of Incidents Reported at Treatment, Storage and Disposal Facilities'
Facility
- -- - - "~^
Northwest Enviro Service
Seattle, WA
Oil and Solvent Process Company
Aziisa, CA
Phillips Environmental (formerly
ChemPro)
Pier 91
Port of Seattle, WA
Reported Incidents
r
1) operations; fire
2) operations
3) mixing waste
(4) spill
hulk liquid handling
operations
Incident Date and Description
1) Pate 1988
description welding sparks ignited fumes from below-grade pit, causing
ire
2) Date. 10/89
Jescriptimv during processing of oil wastes, workers from neighboring
>uilding hospitalized, complaining about fugitive emissions
3) Date. 3/28/92
Jescription. heal, flames and toxic fumes generated due to mixing
ncompatible wastes
(4) Date 2/14-15/94
Description spill into storm drain of 5,500 gal of hazardous waste and oil;
migrated to river and wetland (company claimed sabotage)
Date: 4/21/89
Description: 9,611-gal spill of wastewater containing 1 3% solvents
(mostly acetone) due to transfer line failure.
Date: 1990
Description' welders ignited fumes in an empty tank at tank farm/waste oil
facility
I) no injuries or natural resource
lamage
2) hospitah/ed oil site workers
3) no information
(4) contamination of site, wetlands,
and river
5 gallons released onto public road;
soil contamination cleaned up; no
threat to human health or environment
one worker killed; fugitive emissions
released
Rhone Poulenc Basic Chemical
Company
Martinez, CA
industrial operations;
fire; release
Date: 7/23/92
Description release of corrosive sulfonation acid sludge caused fire and
explosion; U S EPA criticized response actions and capabilities.
NOTE: This facility has never operated as a commercial TSDF under
RCRA. RCRA incinerator permit had been submitted at time of release,
but was withdrawn
one Pacific Gas & Electric worker
seriously injured (apparently on-siie)
due to contact with sludge; elevated air
concentrations of hydrogen sulfide and
sulfur dioxide in damaged area
Safety-Kleen Lexington Recycling
Center
Lexington, SC
bulk liquid handling
Dates: 4/8/92,6/19/92
Description two spills (300 gal and 40 gal) while filling tanks, substances
unknown
no information provided
Volume VII
Appendix VII-1
1-16
-------
TABLE 2 (continued)
Summary of Incidents Reported at Treatment, Storage and Disposal Facilities'
Facility
Sol- Pro
Tacoma, WA
Southeastern Chemicals
Sumter, SC
Statewide Environmental Services
I. os Angeles, CA
United States Pollution Control, Inc
(USPCI)
Grassy Mountain Landfill, looele
County, UT
Washington Chemical
Reported Incidents
(1) operations;
explosion
(2) operations
fires
operations
spill
mixing of incompatible
wastes; explosion
Incident Date and Description
(l)Date- -1991
Pescriptjon' welders working on a feed tank ignited fumes inside the tank,
resulting in explosion.
(2) Date: unknown
Description: fugitive emissions from solvent recyclers, evaporators, and
process vents containing acetone, toluene, and lacquer thinner, and from a
hopper for empty chemical drums, leaks from vats and containers.
Dales: 4/12/92, 4/14/92, 4/20/92, 6/6/92
Description' four fires in 1992
Date: 3/21/91
Description' solidified organic peroxides transferred into polyethylene
drum for incineration, resulting in unexpected reaction.
Date: 9/16/88
Description: 50 ga! of unknown liquid hazardous waste spilled onto prouml
Irom truck.
Date- 3/90 or 4/90
Description incompatible wastes mixed together and sealed in a SS-gal
drum, causing explosion. Drum propelled through air, spraying waste in al
directions.
Reported
Impact II
1) no injuries; small fugitive emission
releases
11
(2) hazardous emissions, releases to
surface water, no physical or healtli
problems
no major releases II
release of water vapor and carhon
dioxide; on-site workers visited
hospital, released same day
no damage to liners, no ground waler
contamination
no injuries; minor property damage
Notes:
1 Sources-
U.S liPA 1995b Report on Emergency Incidents at Hazardous Waste Incinerators and Commercial Treatment, Storage, and Disposal I auliiies (I Sl)l;s) Drali
May.
Victorine, G U.S FPA Region 5 I995a Facsimile memo to Staff Members in OSW and U.S EPA Regions, with List of Commercial lla/ardons Waste
Incinerators, Providing Years of Operation under RCRA Regulations
/olume VII
Vppendix VII-1
1-17
-------
TABLE 3
Reported Equipment/Procedural Failures at the WTI Facility (Victor ine 1997)
Date
05/27/93
09/1 5 '93
11/02 '93
12/10/93
12/14/93
12/15/93
12/15/93
12/16/93
12/22/93
12/23/93
12/27/93
12/28/93
12/29/93
01/09/94
01/10/94
01/11/94
Reported Equipment/Procedural Failures
Kiln is taken off-line due to brick failure Kiln is rebricked.
More brick failure occurs Back half of kiln is rebricked
10 gallons of high-BTU waste is spilled onto soil. All potentially contaminated MM! is
removed
Quench pump system failure results in ID fan trip while drums of waste were still in the
kiln; kiln reportedly released smoke for 3 minutes. (Apparently violation of RCRA
permit condition requiring negative pressure at all times.)
Ternary air fan bearing fails. Trial burn condition 2 rerun is delayed for repairs
Scrubber pump cavitation reportedly causes unacceptable flow variation: attributed to
check valve failure Trial burn is delayed while adjustments made.
Tank lining fails due to poor adhesion. Unacceptably high flow fluctuations in the orcanic
feed lance system result as the pieces c. i.ning flow through the pipes and out the lance.
Also, minor problems associated with spurious readings from a failed redundant
thermocouple (measuring kiln temperature) occur.
Ball of slagged clay falls out of kiln and ruptures pressure relief panels in slag quench
tank Trial burn is delayed for repairs. Failed tank linings which caused problem on
previous day are confirmed Trial bum is stopped due to delays.
Automatic Waste Feed Cutoff (AWFCO) results from low voltage in third field of the
Electrostatic Precipitator (ESP1) Problem is due to "ash bridge" in the hopper. In
cleaning out ash bridge. Permittee spills 10 Ibs of ash (HW) onto concrete containment
Ash is cleaned up
Malfunction of flyash handling system baghouse; 0.1 Ib of dust (HW) is released. II
Feed of drum into kiln with higher than expected BTU release rate causes process II
oscillation and AWFCO tor LOW TEMP Also results in process steam venting for
several minutes ||
Exceeds Ohio Environmental Protection Agency (EPA) temporary solids feed limit of
8000 Ib/hr for one hour by 98 Ibs (Permittee subsequently reported that drum weighing
sequence was changed to prevent this problem from occurring again.) II
Chain conveyor which drags quenched slag out of the slag quench tank breaks and falls II
into slag quench tank at 2.00 am Facility burns out waste for four hours, drains tank,
shuts down kiln and makes repairs ||
C-water tank W5 overflows into containment while transferring C-water from recycle tank II
W4 (which was temporarily being used for C-water) No wastewater is released from
containment 1
5 rings of bricks on the discharge end of kiln are replaced. |j
More C-water overflows tank W5 into containment, reportedly due to a valve being
partially snick open No wastewater is released from containment. ||
Volume VII
\nrvanrKv VTT-1
-------
TABLE 3 (continued)
Reported Equipment/Procedural Failures at the WTI Facility (Victorine 1997)
Date
01/14/94
01/14/94
01/17/94
01/17/94
01/18/94
01/19/94
01/22/94
01/24/94
01/28/94
01/31/94
2/14/94
02/15/94
Reported Equipment/Procedural Failures
1
AWFCO due to high flow after Hi-BTU lance pump fails: response measures (viz .
increasing feed through the organic liquids lance) evidently too aggressive Exceeded
65.000 standard cubic feet per minute (scfm) permit limit. Not burning any solids ai the
time |
One of three drums of the same waste opened for sampling begins smoking Vapor j
recover,' system captures fumes; fire extinguisher directed on drum; drum resealed No
significant releases. ||
Neutralization pump to spray dryer head tank leaks and spills spray dryer feed water onto
concrete containment. No releases to environment. jj
Steamjnot HW) is released due LO frozen pressure transmitters in steam loop ||
3-5 pounds of lime (not HW) onto concrete area is spilled after the lime screw unit which
feeds tank Nl is repaired and returned to service. Initial report is that a gasket was
evidently not correctly tightened after the lime screw unit was repaired. ||
Leak in condenser occurs due to cold weather; necessitates more than normal venting of
steam (not HW) |[
Damage from cold weather reportedly causes some of the steam coils in the flue gas
reheat system to rupture, resulting in high opacity readings. Facility brought off waste
and down onto natural gas (for 2 days) while repairs are made. Welding on heat
exchanger results in observations of smoke for several hours near the stack. ||
Failed check valve causes "C" water to backflow into a sump below the process water I
storage tanks Valve is isolated and replaced; no release to the environment. ||
3 second positive pressure excursion in secondary combustion chamber (SCO results in
AWFCO The pressure excursion is reportedly due to slag falling of the wall of the SCC
and into the slag quench tank, resulting in a large amount of steam generated and released
into the SCC. ||
Corrosion ot an "air bell" inside the ESP causes air bell to fall and short out the first field
of the ESP. This shuts down the first ESP field and triggers an AWFCO. Since fields 2
and 3 remained operative as the facility came off waste, it is believed that only a minor
increase in emissions would have been experienced for a very short time, with emissions
remaining within allowable limits. Quarterly ECIS performance test scheduled to start on
2/1 is postponed until 2/15
One atomizer in the spray dryer plugs up or malfunctions, so service water is fed to spray
dryer to maintain proper artemperation. However, since there is insufficient blowdown
from the scrubber (the scrubber is normally blown down to the spray dryer through the
atomizers, and blowdown evidently has to be reduced since the spray dryer cannot handle
a all), SO, removal in the scrubber evidently decreases and results in an S0: exceedance.
Between 2013 and 2119 hours, the facility emits up to 15.9 pounds per hour of SO2;
OEPA air permit limit is 1 1 3 pounds per hour jj
ID fan trips due to mistake made while electrical work is being done on control system
Sfo drums/bulk waste in the kiln ||
Volume VII
A 1:,. T/TT 1
1 10
-------
TABLE 3 (continued)
Reported Equipment/Procedural Failures at the WTI Facility (Victorine 1997)
Date
02/16/94
02/23/94
02/25/94
03/03/94
03/08/94
03/1 2 '94
03/26/94
04/06/94
04/16/94
04/26/94
05/10/94
05/14/94
06/08/94
06/15/94
Reported Equipment/Procedural Failures
AWFCO due to high carbon monoxide level resulting from plugging in the high-BTU
lance. Evidently, plugging causes "spurting" flow which leads to less complete
combustion than does smooth flow.
Same as 02/16, delays start of trial burn test. No drums or buik waste in the kiln
Attributed to soecific conditions of the trial burn.
Same as 02/16, trips incinerator 10 minutes before the 4-hour test run is complete per the
trial burn plan. No drums or bulk waste in the kiln. Attributed to specific conditions of
the trial burn.
5-8 gallons of acidic/solvent sludge is spilled when rupture disk blows in tank PT-3, due
to level alarm failure and related overfi'ling. Waste is contained in secondary
containment, but apparently gets pumped from sump into C-water system, contaminating
C-water
Power fluctuations cause problems for variable drives on spray dryer atomizers, atomizers
trip off, system has AWFCO at 6.00 am due to high temperature at the outlei of the spray
dryer System is checked out and returned to service, but has a similar AWFCO around
8-00 am due to failure of spray dryer atomizer vacuum pump which, under present logic,
automatically tips off the aio^'zer.
Kiln is rebncked
15-18 gallons of HW into is spilled secondary containment in the drum pumpout tank area,
due to apparent failure of maintenance personnel to reconnect a vent line on a sludge
pump after a service operation HW cleaned up and put in drums.
<5 gallons of waste is spilled into and just outside of secondary containment for the
pumpout tanks. Workers were disconnecting hoses used for temporary waste routing,
hoses were evidently under more pressure than anticipated. All spillage is onto pavement.
and is cleaned up
Problems occur with slag conveyor, plant is brought down for three days for repairs
While repackaging reactive wastes from drums into 5-gallon pails, three pails emu strong
tar-like odor Pails are immediately sent to the kiln and are destroyed, all within 20
minutes Waste was cumene hydroperoxide
Large piece of slag is rolled out of the kiln and into the slag quench tank, causing pressure
relief panels in the quench tank to release. Plant is brought down for repairs, plans are
made to modify the design of the slag quench tank and conveyor system
Slag conveyor is jammed, comes off track, and falls into the slag quench tank. Plant is
brought down for repairs Upon re-start on Sunday morning, ESP field #3 found to be
shorting out. Plant is brought back down so that ceramic insulators on ESP field #3 can
be changed Plan to be back on waste 5/17.
Problems occur with slag quench tank and conveyor.
Unit is shut down to inspect brickwork in kiln, need to replace several rows of bricks is
identified.
Volume VII
innonHiv V^TI-1
1-20
-------
TABLE 3 (continued)
Reported Equipment/Procedural Failures af the WTI Facility (Victorine 1997)
Date
07 ,'12 '94
07/28/94
08/19/94
08/25/94
09/01/94
09/29/94
10/23/94
10/31/94
11/04/94
12/08/94
12/29/94
01/04/95
01/08/95
02/14/95
02/15/95
Reported Equipment/Procedural Failures
Unit is down for repairs to slae conveyor
Unit is down tor rehncking of kiln and repairs to slag conveyor
Unit is down for repairs u> slag conveyor
Problem with large piece of slag falling into quench tank causes SCC overpressure and
visible puff for 3-5 seconds
During monitor recertification, CO monitors are found co be reading high and hence out of
certification. Even though this could be considered to be "overprotective," facility is
instructed not to burn waste until at least one monitor can be certified. WTI goes down
for about two weeks to install new slag quench tank, and also decides to lease a new CO
monitor, while also ordering two brand-new CO units. Temporary CO monitor LS
successfully certified, and facility operates on this monitor until new units arrive
Unit is down until 10/24/94 due to problems with spray dryer pump(s) and sensoris)
Unit is down (reason not recorded) until 10/25/94
Electrical technician causes fuse to blow while changing an indicator lamp for the water
level in the waste heat boiler The process computer interprets this as meaning that the
boiler has gone dry, and responds by tripping the plant off. Hot gases remaining in the
kiln evidently flow backward through the vapor recovery system piping and out the three
carbon absorber boxes associated with the vapor recovery system. Event lasts
approximately 10 minutes, with some visible emissions reportedly seen at ground level
Plant is down for minor brick repairs
Leaking piping is observed at scrubber water pump inside scrubber building
Rolled up cloth-like item in hulk waste teed is caught in hot-side doors of bulk teed chute,
and begins to smolder Technicians reportedly use a hose to extinguish the item and
knock it free
Steam is released due to frozen condensate line at heat exchanger. Corrective action
includes revision to control system to send information concerning temperature and valve
position up to the control room
Unit is down for partial rebncking
Small electrical fire occurs in a control cabinet within the spray dryer penthouse, and is
immediately extinguished by plant personnel with fire extinguisher. The spray drver is
controlled both electrically and hydraulically, and some of the hydraulic piping which runs
through the cabinet ruptures and spills into penthouse, onto floor grating, and through
grating onto insulation Oil is steam-cleaned off the following evening
When upper doors are opened to drop a load of bulk solids into the kiln, the bulk waste
which is in the clamshell catches fire Sprinkler system activates, extinguishing fire
reportedly within 1 minute This event is reportedly caused by a "flashback" of powdery
material falling out of clamshell bucket. Damage is reportedly limited to the crane bucket
wires, cables, and insulation in the immediate area.
Volume VII
-------
TABLE 3 (continued)
Reported Equipment/Procedural Failures at the WTI Facility (Victorine 1997)
Date
3/15/95
7/03/95
7/18/95
10/22/95
03/31/96
07/18/96
08/06/96
08/07/96
08/08/96
Reported Equipment/Procedural Failures
A release of a repulsive odor is reported, affecting much of East Liverpool, due to the
receipt and unloading of a tanker of waste which contained mercaptan thiopheno! No
exact release point is ever identified with certainty, but reportedly only a few drops, ot this
waste (which reportedly has an odor threshold of 0.3 ppb) could result in this kind of
problem. The possibility exists that this odor is, at least in part, due to releases from the
truck after it left the plant site. WTI stops receiving shipments of this waste until it
completes enclosure of the tanker truck unloading pad and venting of this enclosure to the
vapor recovery system.
The waste in one of the two enclosed bulk solid waste pits catches fire. The automatic
deluge system quickly extinguishes the fire. No injuries; minor damage to the door into
the pit Since this enclosure is vented to the vapor recovery system, no significant
releases are suspected, but some smoke i_ reported as leaking out from under and around
the door Ignition source is attributed to a burning piece of waste, either traveling through
the air from the incinerator feed chute doors to the pit, or being carried from the chute
doors to the pit via the clamshell bucket.
An incoming truck load of caustic waste is mistaken for an expected shipment of virgin
caustic from the same trucking company, and therefore the truck driver is mistakenly
directed by facility personnel to off-load the material into the caustic tank (this caustic
tank is used for neutralization of the scrubber liquor). The mistake is immediately caught,
and a!! the material (mixture of waste and virgin caustic) in the caustic tank is
subsequently treated as a hazardous waste. WTI cleans out the tank and institutes
additional verification procedures for bill-of-lading
Fire is observed in the clamshell bucket as it :s parked over the hopper doors (because of
AWFCO. load cannot be fed to incinerator) Bucket wash system is activated, which
suppresses, but does not extinguish, the fire. Bucket is moved to ground level, and more
water, plus chemical fire suppression, is used to extinguish the fire.
Fire is observed in one of the two solid waste pits, and is immediately extinguished with
chemical extinguisher.
At 6:00 pm. smoke or vapor is observed emanating from one of the pits. Area is sprayed
with purple K fire extinguisher At 8'15 pm, smoke is again observed, plus a small
flame Purple K and water are used to extinguish. Fire is blamed on a pocket of reactive
waste within the pit No known release to environment.
Cat-smell is reported in neighborhood. Although WTI is not at the time off-loading any
vehicles containing the paradichlorobenzene waste which has been associated with this
smell, a later report from OEPA indicates that WTI was transferring/burning such waste
that day.
Minor fire occurs in the bulk solid waste pits when a ball of waste, which had
accumulated on the lip of the feed hopper, ignites and rolls off the lip and down into the
pits Fire is extinguished locally with Purple K and water.
Unit is down for rebnckmg and back on waste 08/20.
Volume
VTT-1
1-22
-------
TABLE 3 (continued)
Reported Equipment/Procedural Failures at the WTI Facility (Victorine 1997)
Date
Reported Equipment/Procedural Failures
11/04/96
Minor fire occurs in Pu 2 Clamshell bucket is down in pit grabbing a load ot waste
operator notices small flame and immediately activates the water deluge system Thiv
immediately extinguishes fire, no call made to fire department Event thought to he
caused by a spark caused by bucket rubbing against wall, WTI to investigate feasibility ot
bucket bumpers made of brass or other non-sparking material
12/01/96
(Also observed 12/17, 12/19, 12/23. and 12/25). Iodine is driven out of the scrubber
water, resulting in pink or purple coloration of the normal steam plume from the plant
stack. These events are still under investigation as of this writing, but preliminarily
assessment blames effect on a sequence of events which include burning high-iodine
waste, followed by burning high-bromine waste. The bromine reportedly tends to convert
the iodine salts which exist in the scrubber water into insoluble diatomic iodine, which can
then be driven out of the scrubber watt., by the normal gas flow through the scrubber
Volume VII
Aooendix VIM
1-23
-------
APPENDIX VII-2
Ranking of Chemicals of
Potential Concern
-------
CONTENTS
Page
Table 1: Chemicals Eliminated from the Preliminary List 2-1
Table 2: Ranking of Chemicals of Potential Concern for Shon-Term Exposures 2-8
Volume VII
-------
TABLE 1
Chemicals Eliminated from the Preliminary List"
CAS Number
591-08-2
98-86-2
53-96-3
591-08-2
111-65-9
131-74-8
7803-55-6
7778-39-4
692-42-2
696-28-6
151-56-4
75-55-8
542-62-1
100-01-6
106-47-8
100-21-0
51-43-4
122-09-8
92-87-5
50-32-8
81-81-2
50-32-8
7440-41-7
598-31-2
357-57-3
39196-18-4
111-76-2
123-86-4
Substance
Acetamide, N-(aminothioxomethyl)-
Acetophenone
Acerylaminofluorene, 2-
1 -Acety l-2-thiourea
Aliphatic hydrocarbons (assumed octane)
Ammonium picrate
Ammonium vanadate
Arsenic acid H,AsO4
Arsine, diethyl-
Arsonous dichloride, phenyl-
Azindme
Azindme, 2-metnyl-
Banum cyanide
Benzenamme, 4-nicro-
Benzenamme, 4-chlor6-
Jenzenedicarboxylic acid. 1,2-
1 ,2-Benzenediol , 4-[ 1 -hydroxy-2-( methy lamino)ethy 1]-
knzeneethanamme, o.a-dimethyl-
knzidme
Jen/o(a)pyrene
2H-l-Benzopyran-2-one, 4-hydroxy-3-(3-oxo-l-phenylburyl)-. & salts, when present at concentrations greater
than 0.3%
Jenzoqumone, p-
Jeryllium
)romoacetone
Jmcine
-Butanone. 3,3-d]methyl-l-(methylthio)-.0-|methylaminocarbonyl) oxime
Butoxyethanol, 2- (Butyl cellosolve)
Bury) acetate
Volume VII
-------
CAS Number
592-01-8
75-44-5
107-20-0
106-47-8
108-90-7
218-01-9
544-92-3
106-44-5
108-39-4
57-12-5
460-19-5
-,i 131-89-5
53-70-3
106-93-4
1649-08-7
75-71-8
75-34-3
540-59-0
75-35-4
542-88-1
60-57-1
56-53-1
311-45-5
692-42-2
309-00-2
465-73-6
60-57- 1
TABLE 1 (continued)
Chemicals Eliminated from the Preliminary List2
Substance
Calcium cyanide
Carbonic dichlonde
Chloroacetaldehyde
p-Chloroaniline
Chlorobenzene
Chrysene
Copper cyanide
Cresol, 4-
Cresol, 3-
Cyanides (soluble cyanide salts), not otherwise specified
Cyanogen
2-Cyclohexyl-4, 6-dimtrophenol
Dibenz(a,h)anthracene
Dibromoethane
Dichlorodifluoroethane
Dichlorodifluoromethane
Dichloroethane, 1,1- (ethviidene dichlonde)
Zhchloroethene
Dichloroethene, 1,1-
Dichloromethyl
Dieldnn
Diethyl stilbestrol
Dieihyl-p-nitrophenyl phosphate
Diethylarsme
1,4,5.8-Dimethanonaphthalene, 1,2,3,4,10,10-hexa- chloro-l,4,4a,5,8,8a,-hexahydro-,
(la,4a.4ap.5a,8cr,8ap)-
1,4,5,8-Dimethanonaphthalene, 1.2.3.4.10,10-hexa- chloro-l,4.4a,5,8,8a,-hexahydro-,
(la.4a.4ap,5p,8p,8ap>- '' |
2.7 3.6-Dimethanonaphth f2.3-b]oxirene, 3,4,5.6.9,9-hexachloro-la,2.2a 3 6 6a 7 7a-octahydro-
(laa,2p.2aa.3p.6p. 6aa.7p 7aai- j|
Volume VII
Annendix VII-2
-------
CAS Number
72-20-8
124-40-3
119-93-7
105-67-9
131-11-3
122-09-8
51-28-5
121-14-2
606-20-2
145-73-3
51-43-4
460-19-5
107-12-0
141-78-6
51-79-6
105-39-5
52-85-7
206-44-0
62-74-8
64-18-6
28-86-4
98-01-1
76-44-8
110-43-0
57-58-4
110-54-3
142-92-7
60-34-4
TABLE 1 (continued)
Chemicals Eliminated from the Preliminary List"
Substance
? 7'3 6-Dimethajionaphth [2 3-b]oxirene 3456 9,9-hexachloro-la.2 2a,3 6.6a,7.7a-octahvdro-
(laa.2p,2ap.3cc,6a, 6ap,7p,7aa)-, & metabolites
Dimethylamme
Dimethylbenzidme, 3,3'-
Dimethylphenol (assumed 2.4-)
Dimethylphthalate
a , tt-Dimethyphenethy lamine
2,4-DinitrophenoL
Dmitrotoluene, 2,4-
Dinitrotoluene, 2,6-
Endothall
Epinephnne
Ethanedimtrile
Ethyl cyanide
Ethyl acetate
Ethyl carbamate
Ethylchloroacetate
Famphur
Fluoranthene
Fluoroacetic acid, sodium salt
Formic acid
Fulmimc acid, mercury (2 + ) salt
Furfural
rieptachlor j
rieptanone, 2-
rlexaethyl tetraphosphate
Hexane
4exyl acetate
rlydrazine, methyl-
Volume VII
-------
TABLE 1 (continued)
Chemicals Eliminated from the Preliminary List"
CAS Number
7803-51-2
193-39-5
78-59-1
67-63-0
108-21-4
120-58-1
2763-96-4
108-31-6
628-86-4
509-14-8
542-88-1
75-70-7
76-44-8
115-29-7
16752-77-5
80-62-6
504-60-9
36^9-5
75-09-2
1116-54-7
55-18-5
924-16-3
930-55-2
4549-40-0
134-32-7
91-59-8
-!; 557-19-7
100-01-6
Substance
Hydrogen phosphide
Indeno(1.2.3-cd)pyrene
Isophorone
Isopropanol
Isopropyl acetate
Isosafrole
3(2H)-lsoxazolone, 5-(aminomethyD-
Maleic anhydride
Mercury fulminate
Methane, tetramtro-
Methane. oxybis(chloro-
Methanethiol, trichloro-
4,7-Methano-lH-mdene, l,4.5.6.7.8,8-heptachloro-3a,4,7,7a-tetrahydro-
6,9-Methano-2.4,3-benzodioxathiepm. 6.7.8.9.iO,10-hexachloro-l,5,5a,6.9,9a-hexaliydro-, 3-oxide
Methomyl
Methyl methacrylate
Methylbutadiene, 1-
Methylcholanthrene, 3-
Methylene chloride
N -nitrosodiethanolamme
N-nitrosodiethylamme
N-nitrosodi-n-burylamine
N-mtrosopyrolidme
N-mtrosomethylvinylamine
Naphthylamine, 1-
Naphthylarnme, 2-
Nickel cyanide
p-Nitroanilme
Volume VII
-------
TABLE 1 (continued)
Chemicals Eliminated from the Preliminary List"
CAS Number
55-63-0
100-02-7
152-16-9
145-73-3
109-66-0
131-74-8
131-89-5
534-52-1
51-28-5
88-85-7
311-45-5
298-02-2
298-04-4
60-51-5
55-91-4
297-97-2
298-00-0
52-85-7
56-38-2
85-44-9
109-06-8
116-06-3
542-76-7
75-86-5
55-63-0
71-23-8
598-31-2
j 107-19-7
Substance
Nitroglycerine
Nitrophenol (para)
Octamethylpyrophosphoramide
7-Oxabicyclo[2.2.1]heptane-2.3-dicarboxylic acid
Pentane
Phenol, 2,4,6-trmitro-,
Phenol, 2-cyclohexyl-4,
ammonium salt
6-dirutro-
Phenol, 2-methyl-4,6-dimtro-, & salts
Phenol, 2,4-dmitro-
Pheno), 2-(l-methylpropyl)-4,6-dinitro-
Phosphonc acid, diethyl
Phosphorodithioic acid.
Phosphorodithioic acid,
Phosphorodithioic acid.
Phosphorofluoridic acid
4-nitrophenyl ester
0. O-diethyl S-|(ethylthio)methyl] ester
0. O-diethyi S-[2-(ethylthio)ethyl] esisr
0, O-dimethyl S-[2-(methylamino)-2-oxoethyl] ester
bis(l-methylethyl) ester
5hosphorothioic acid, O.O-diethyl O-pyrazmyl ester
-"hosphorothioic acid, O,O, -dimethyl O-(4-rutrophenyl) ester
'hosphorothioic acid. O-[4-[(dimethylammo)sulfonyl)phenyl] O,O-dimethyl ester
'hosphorothioic acid, O.O-diethvl O-(4-mtrophenvl) ester
'hthalic anhydride
3icoline, 2-
'ropanal, 2-methyl-2-(methylthio)-, O-[(methylamino)carbonyl]oxime
'ropanerutrile, 3-chloro-
'ropanemtrile, 2-hydroxy-2-methyl-
,,2.3-Propanetnol, tnnitrate
'ropanol, n-
2-Propanone, 1-bromoj-
Propargyl alcohol
Volume VII
i 1:_. tru >
-------
TABLE 1 (continued)
Chemicals Eliminated from the Preliminary Lisf
CAS Number
107-18-6
107-02-8
107-19-7
504-24-5
154-11-5
108-46-3
12039-52-0
630-10-4
506-64-9
357-57-3
630-20-6
:' 79-34-5
107-49-3
757-58-4
12039-52-0
7446-18-6
541-53-7
103-85-5
86-88-4
823-40-5
95-80-7
76-13-1
120-82-1
79-00-5
75-69-4
87-90-1
1 75-70-7
121-44-8
Substance
2-Propen-l-ol
2-Propenal
2-Propyn-l-ol
4-Pyndinamine
Pyridme, 3-(l-methyl-2-pyrrolidinyl)-, (S)-. & salts
Resorcmol
Selenious acid, dithalhumd + ) salt
Selenourea
Silver cyanide
Strychrudin- 10-one, 2,3-dimethoxy-
Tetrachloroethane, 1,1.1,2-
Tetrachloroethane, 1,1,2.2-
Tetraethy! pyrophosphaie
Tetraphosphonc acid, hexaeihyl tsier
Thallium(l) selenne
Thallium(l) sulfate
Thioimidodicarbonjc diamide [(H,N)C(S)]2NH
Thiourea, phenyl-
Thiourea, 1-naphihalenyl- 1
Toluenediamme, 2,6- 1
Toluenediamme, 2,4- 1
Tnchloro-l,2.2,-trifluoroethane, 1.1.2-
Tnchlorobenzene (assumed 1,2,4-) 1
Tnchloroethane, 1.1,2-
Trichlorofluoromethane
Tnchloroisocyanunc acid (Symclosene)
i*
Tr.chloromethanethioi
Tnethylamme 1
Volume VII
2-6
-------
TABLE 1 (continued)
Chemicals Eliminated from the Preliminary Lisf
CAS Number
Substance
7803-55-6
Vanadic acid, ammonium salt
4549-40-0
Vinvlamme. N-methvl-N-mtroso-
557-21-1 Zinc cyanide
Note.
170 chemicals were eliminated from the preliminary list of 309 chemicals.
Volume VII
-------
TABLE 2
Ranking of Chemicals of Potential Concern for Short-Term Exposures3
CAS
Number1
107-200
640-19 7
62-74-8
67-64 1
107-2-8
107-13-1
1166 3
309-0 2
107-18-6
20859-73-H
2763-964
504-24-5
7664-41-7
62-53-3
506-61-6
1327-53-3
1303-28-2
7784-34- 1
7784-42-1
71-43-2
108-98-5
100-44-7
71-36-3
Substance
Aceialdehyde, chloro-
Acetamide, 2-fluoro-
Acetic acid, fluoro-, sodium salt
Acetone
Acrolein
Acrylomlrile
Aldicarh
Aldrm
Allyl alcohol
Aluminum phosphide
Aminomethyl-3-isoxazolol, 5-
Aminopyridine, 4-
Atnmonia
Aniline
Argentate(l), bis(cyano-C)-, potassium
Arsenic oxide
Arsenic pentoxide
Arsenous trichloride
Arsine
Benzene
Benzenethiol
Benzyl chloride
Butanol
Basis2
B
B
B
A
B,C, D
A, C, D
B, D
B, D
B, C, D
B, D
B
B
C
A, D
B
B
B, U
C
C
A
B
B, D
A
R, Rank'
(1DLI1)
80
61
4
130
10
83
6
37
57
86
81
87
92
99
88
27
66
24
20
112
28
59
124
R2 Rank3
(II)LH,
VP)
29
NS
NS
47
13
31
93
97
32
NS
NS
100
15
77
NS
NS
NS
28
3
44
39
35
79
Rj Rank1
(IDLH,
LVP, 0
NS
NS
NS
9
NS
6
NS
NS
NS
NS
NS
NS j
NS
37
NS
NS
NS
NS
NS
15
NS
NS
34
Volume VII
Appendix VII-2
2-i
-------
TABLE 2 (continued)
Ranking of Chemicals of Potential Concern for
CAS
Number1
75-15-0
56-23-5
57-74-9
7782-50-5
10049-4-4
67-66-3
542-88-1
5344-82-1
542-76-7
8001-58-9
95-48-7
4170-30-3
98-82-8
506-77-4
1 10-82-7
108-94-1
19287-4,5-7
95-50-1
541-73-1
106-46-7
696-28-6
84 f\f\ 9
297-97-2
Substance
Carbon disulfide
Carbon tetrachlnnde
Chlordane
Chlorine
Chlorine dioxide
Chloroform
bis-Chloromeihyl eilier
l-(o-Chlorophenyl)thiourea
ChloropropionHnle, 3-
Creosote (coal lar)
Cresol, 2-
Crotonaldehyde
Cumene
Cyanogen chloride
Cyclohexane
Cyclohexanone
Diborane
Dichlorobenzene, 1,2-
Dichlorobenzene, 1,3-
" ~
Dichlorobenzene, 1,4-
Dichlorophenylarsine
Diethylphthalaie
Diethyl O-pyrazinyl phosphorothioate, O,O-
-
Short-Term I
Basis2
A, B, C, U
A
D
C
C
A, C, U
C
|
B
B
.M ... , ..,
A
A, D
A, C, D
A
B, C
'
A
A
C
A
A
A
1)
- -
A
B
'". "I ' -
Exposures3
-^-- ' -j-i-1 .
R, RamV
(IDLH)
...
ill
109
101
40
25
117
5
cc
68
- -
NS
106
79
125
122
^ _ _
126
118
30
107
NS
102
" " " i
100
- .
NS
4d
~ i
*'" .._i!L.'.""- i'-1
R2 Rank1
(IDLH,
VP)
.. -,_ I,, i .,.,111..,
36
41
108
6
II
42
18
NS
43
NS
85
40
74
33
51
75
2
81
NS
78
87
NS
" ' - ..,.-.
89
-
R3 Rank'
(IDLH,
VP, C)
,:
5
7
47
NS
NS
10
MC
NS
NS
NS
41
l£
KJC
20
11
K|C
->c
NS
40
NS
NS
NS
Volume VII
Appendix VII-2
2-9
-------
TABLE 2 (continued)
Ranking of Chemicals of Potential Concern for Short-Term Exposures"
CAS
Number1
55-91-4
60-51-5
540-73-8
77-78-1
534-52-1
88-85-7
123-91-1
152-16-9
107 49-3
298-4-4
541-53-7
115-29-7
72-20-8
106-89-8
16752-77-5
64-17-5
1 10-80-5
140-88-5
100-41-4
151-56-4
82-41-4
640-19-7
Substance
Diisopropylfluorophosphate (DF:P)
Dimelhoate
Dimethylhydrazine
Dimethyl sulfate
Dmilro-o-cresol, 4,6- & salts
Dinoseb
Dioxane, 1,4-
Diphosphoramide, ociamethyl
Diphosphoric acid, tetraeihyl ester
Disulfoton
Dithiohiuret
Endosulfan
Endrin, & metabolites
Epichlorohydrin
Ethanimidothioic acid, N-||(ine(hylamino)carhonyl]oxy]-, methyl ester
(Methomyl)
Eihanol
Ethoxyethanol, 2-
Ethyl acrylate
Ethylbenzene
Etliyleneinune
I:luorine
Fluoroacetamide
Basis2
B
B, D
A,C, D ,
A, D
B, D
B, D
A
B, D
B
B, D
B, D
B, D
B, D
A, C, D
B
A
A
A
A 1
B.C, D
B, C, D
B, D
R, RankJ
(IDLH)
46
97
48
47
11
54
113
15
12
32
58
16
3
96
72
131
114
108
121
82
52
NS
R2 Rank3
(IDLH,
VP)
53
107
24
57
90
76
52
88
92
95
NS
102
101
45
104
65
70
49
71
27
23
NS
R3 Rank'
(IDLH,
VP, C)
NS
NS
4
29
NS
NS
22
NS
NS
NS
NS
NS
46
17
NS
25
30
28
31
NS
NS
NS
Volume VII
Appendix VII-2
2-10
-------
CAS
Number'
50-0-0
142-82-5
302-1-2
79-19-6
74-90-8
7647-1-0
7664-39-3
7783-7-5
7783-6-4
13463-40-6
78-83-1
Af.< Tt f.
62-38-4
62-75-9
67-56-1
78-93-3
60-34-4
108-10-1
624-83-9
75-86-5
298-0-0
91-20-3
86-88-4
TABLE 2 (continued)
Ranking of Chemicals of Potential Concern for Short-Term Exposures3
Substance
Formaldehyde
Heptane
Hydr^zme
Hydrazmecarboiluoamide
Hydrocyanic acid
Hydrogen chloride
Hydrogen fluoride
Hydrogen selemde
Hydrogen sulfide
Iron, peniacarhonyl-
Isobutanol
Isodrin
Mercury, (acelato-O)phenyl-
Methanamine, N-methyl -N-nitroso-
Methanol
Methyl ethyl ketone (2-Butanone)
Methyl hydrazine
Methyl isobutyl ketone (2-Methyl-4-pentanone)
Methyl isocyanate
Methylactronitrile, 2-
Methyl parathion
Naphthalene
Naphthylthiourea, alpha-
Basis2
A, C, D
A
A, C, D
B
B,C, D
C
C
C
C
C
A
B, D
B
B
A
A
B,C, D
A
B, C, D
B
B
A
B
R, Rank3
(IDLH)
35
119
62
69
60
65
36
8
78
17
127
64
93
84
132
133
50
116
14
75
9
110
73
R2 Rank1
(IDLH,
VP)
7
59
37
NS
20
4
14
1
9
22
73
105
103
55
60
63
25
64
12
66
98
91
NS
R3 Rank3
(IDLH,
LVP, C)
2
21
11
NS
NS
1
3
NS
NS
NS
32
NS
NS
NS
19
16
NS
26
NS
NS
NS
45
NS
Volume VII
Appendix VII-2
2-11
-------
TABLE 2 (continued)
Ranking of Chemicals of Potential Concern for Short-Term Exposures"
CAS
Number1
13463-39-3
54-11-5
98-95-3
10102-44 0
110102-43-9
79-46-9
62-75-9
20816-12-0
56-38-2
108-95-2
62-38 4
103-85-5
298-2-2
75-44-5
7806-51-2
151-50-8
506-^1-6
107-12-0
75-55-8
110-86-1
26628-22-8
143-33-9
57-24-9
Substance
Nickel carbonyl
Nicotine, & salts
Nitrobenzene
Nitrogen dioxide
Nitrogen oxide NO
Nitropropane, 2-
N-mirosodimethylaniine
Osmium oxide OsO4, (T-4)-
Parathion
Phenol
PhenylmeiCury acetate
Phenylthiourea
Phorate
Phosgene
Phosphine
Potassium cyanide
Potassium silver cyanide
Propanenitrile
Propylenimine, 1,2-
Pyridine
Sodium azide
Sodium cyanide
Strychnidin- 10-one, & salts
Basis2
B,C, D
B, D
A, D
B, D
B, C, D
A
B, D
B
B, D
A, D
B,D
B, D
B, D
B, C, D
B,C, D
B, D
B, D
B,C
B,C, D
A
H, 13
B, D
B, D
R, Rank3
(LDLH)
26
13
104
51
77
98
85
1
21
103
94
41
2
18
63
38
89
49
95
120
90
39
7
R2 Rank3
(II)LH,
VP)
16
54
86
17
5
46
56
21
96
84
106
NS
82
8
NS
NS
NS
26
30
68
NS
NS
NS
R, Rank3
(IDLH,
VP, C) 1
NS
N" I
39
NS
NS
8
NS II
NS
NS I
42 I
NS ||
NS
NS
NS
NS
NS
NS
NS
NS
27
NS
NS
NS
Volume VII
Appendix VI1-2
2-12
-------
TABLE 2 (continued)
Ranking of Chemicals of Potential Concern for Short-Term Exposures"
CAS
Number1
7783-60-0
7446-11-9
7446-18-6
95-94-3
127-18-4
3689-24-5
78-0-2
109-99-9
509-14-8
1314-32-5
39196-18-4
108-98-5
79-19-6
5344-82-1
7550-45-0
108-88-3
584^84-9
91-8-7
8001-35-2
71-55-6
79-1-6
1314-62-1
1330-20-7
Substance
Sulfur tetrafluoride
Sulfur trioxide
Sulfuric acid, dithallium (!-(-) salt
Telrachlorobenzene (assumed 1,2,4,5-)
Tetrachloroeihylene
Tetraeihylditliiopyrophosphale
Tetraelhyl lead
Telrahydrofuran
Tetranuromethane
Thalhc oxide
Thiofanox
Thiophenol
Thiosemicarbazide
Thiourea, (2-chlorophenyl)-
Titanium tetrachloride
Toluene
Toluene-2,4-diisocyanate
Toluene-2,6-diisocyanate
Toxaphene
Trichloroethane, 1,1,1-
Trichloroeihylene
Vanadium oxide
Xylene
Basis2
c
c
B
A
A
B
B, D
A
B,C, D
B
B, D
B, D
B, D
B, D
C
A
A, C, D
A, C, D
B
A
A
B, D
A
R, Rank3
(IDLH)
70
42
33
NS
105
22
53
129
43
34
67
29
71
56
23
115
31
19
9)
123
128
45
NS
R2 Rank3
(IDLH,
VP)
10
19
NS
NS
58
94
67
50
34
NS
99
38
NS
NS
NS
61
83
69
72
48
62
NS
NS
Rj Rank3
(IDLH,
LVP, C)
NS
NS
NS
NS
24
NS
NS
14
NS
NS
NS
NS
NS
NS
NS
IK
43
38
44
12
23
NS
NS
Volume VII
Appendix VII-2
2-13
-------
TABLE 2 (continued)
Ranking of Chemicals of Potential Concern for Short-Term Exposures"
CAS
Number1
81-81-2
1314-84-7
Substance
Warfarin, & salts, when > 0 3%
Zinc phosphide, when > 10%
Basis2
B, U
B, D
R, Rank3
(IDLH)
74
76
R2 Rank'
(IDLH,
VP)
80
NS _,
R, Rank'
(IDLH,
VP, C)
NS
NS
Notes-
' 139 chemicals were selected for further analysis
1 CAS Number given for parent compound only
J A _ Wastes received by W 1 1 during first year of operation
B Constituents listed as "P" wastes (acutely hazardous according to RCRA)
C Acutely toxic chemicals identified in CAA 1 12(r)
I) E:.xtremely hazardous substances from HPCRA
' NS IDLH, vapor pressure, or Concentration data not available lor tins co npound Therefore, no score was calculated.
Volume VII
Appendix VII-2
2-14
-------
APPENDIX VII-3
Accidental Reiease Modeling
-------
CONTENTS
I. RELEASE CHARACTERIZATION
aiie
A. Methodology
B. Chemical-Specific Release Rate Calculations
1 . On-Site Spill
2. On-Site Fire
3. On-Site Mixing of Incompatible Wastes
4. Off-Site Tanker Truck Spill
5. Off-Site Tanker Truck Spill with Fire
C. Results of the Release Modeling
1 On-Site Spill
2 On-Site Fire
3 On-Site Mixing of Incompatible Wastes
4 Off-Site Tanker Truck Spill
5. Off-Site Tanker Truck Spill with Fire
II. REFERENCES
3-1
3-4
3-4
3-11
3-16
3-17
3-18
3-18
3-18
3-24
3-26
3-27
3-27
3-28
TABLES
Table 1: Accident Analysis Calculations - On-Site Spill (conservative).
Typical and Conservative Meteorological Condition 3-30
Table 2: Accident Analysis Calculations - On-Site Spill (typical),
Typical and Conservative Meteorological Condition 3-32
Table 3: Accident Analysis Calculations - On-Site Fire (conservative) 3-34
Table 4. Accident Analysis Calculations - On-Site Fire (typical) 3-35
Table 5: Accident Analysis Calculations - On-Site Mixing of Incompatible
Wastes (conservative) 3-36
Table 6. Accident Analysis Calculations - On-Site Mixing of Incompatible
Wastes (typical) 3-37
Table 7: Accident Analysis Calculations - Off-Site Spill (conservative).
Typical and Conservative Meteorological Condition 3-39
Table 8: Accident Analysis Calculations - Off-Site Spill (typical), Typical and
Conservative Meteorological Condition 3-41
Table 9: Accident Analysis Calculations - Off-Site Spill with Fire (conservative) 3-43
Table 10: Accident Analysis Calculations - Off-Site Spill with Fire (typical) 3-44
Table 11: Accident Analysis Calculations - On-Site Spill (conservative),
Calm/Inversion Meteorological Condition '" 3-45
Table 12: Accident Analysis Calculations - On-^'ie Spill (typical),
Calm/Inversion Meteorological Condition 3-47
Volume VII
A r\r%onr1i
-------
CONTENTS
(continued)
Table 13: Accident Analysis Calculations - Off-Site Spill (conservative).
Calm/Inversion Meteorological Condition
Table 14: Accident Analysis Calculations - Off-Site Spill (typical),
Calm/Inversion Meteorological Condition
Table 15: Summary of Average Total Emission Rates for All Events Evaluated
in the Accident Analvsis
Page
?-4Q
ATTACHMENT
Attachment 1: ARCHIE Output for On-Site and Off-Site Fire Events
Volume VII
Aooendix VII-3
-------
I. RELEASE CHARACTERIZATION
A. Methodology
Atmospheric release rates for the chemicals of primary concern are estimated for each
accident event selected for quantitative evaluation. The area and extent of on-site
spills/releases are based on facility-specific parameters (e.g.. tank volumes, dike sizes)
Emission rates and durations are developed for specific constituents in the emissions based
primarily on short-term modeling techniques. These models can take into account the
physical/chemical properties of the chemicals (e.g.. volatility, density, liquid or gas phase):
the presence of passive mitigation devices (e.g., concrete dikes and berms); and active and
redundant mitigation devices (e.g., nitrogen blankets and sprinkler systems).
Wastes consisting of a mixture of chemicals are modeled for all of the events in this
Accident Analysis. Physical and chemical properties for these mixtures are estimated from the
properties of the pure chemicals, weighted by the mass fraction of each chemical constituent.
For example, the molecular weight of a mixture. MWmt, containing jV components is.
i*
£
MW
(1)
where:
w, = mass fraction of the ah component.
A/Wj = molecular weight of the nh component.
The heat of vaporization of a mixture, ^.mu. is:
N
A. = Y w A. (2)
I IT Z. J II ' '
mu
(--]
where:
A,, = heat of vaporization of the /th component.
Volume VII
A nnpnHiv VTT-"} "5-1
-------
Except for vapor pressure and boiling point, all mixture parameters with units proportional to
the mass (e.g., density) are calculated in a manner similar to Equation (1), whereas parameters
with units proportional to the inverse mass (e.g.. heat capacity), are calculated in a manner
similar to Equation (2). The vapor pressure of a mixture is the sum of the vapor pressure^ (in
equilibrium with the liquid mixture) of the individual components. For a binan, mixture, the
liquid is assumed to act as an ideal solution Using Raoult's law. the vapor pressure of the
mixture is:
P. = x .p.., +x^p. (3)
where:
pi = vapor pressure of the mixture (Pa);
XA - liquid mole fraction of component A (unitless);
pvA' = vapor pressure of pure component A (Pa);
XB = liquid mole fraction of component B (unitless);
p^g = vapor pressure of pure component B (Pa).
The mass fraction, w,, and mole fraction. *,, are related by:
w (MW ) = x (MW)
(4)
and the vapor phase concentrations, v,. are related to the liquid phase concentrations. ,vr by
Raoult's law:
P,
(5)
where:
V, = vapor mole fraction of the rth component at equilibrium with liquid
(unitless);
pw" = vapor pressure of pure component i (Pa).
The vapor pressure of a pure component in a mixture depends on the boiling temperature
of the mixture which, in turn, is determined by the bubble point of the'mixture. The bubble
point is the temperature at which the first bubble of vapor forms when a liquid is heated at
Volume VII
Appendix VII-3
-------
constant pressure. The bubble point of a mixture is approximately its boiling point when the
pressure is equal to atmospheric pressure (i.e., 1 aim). For an ideal solution. Raoult's lau is
used to calculate the bubble point by solving equation (6) iteratively:
At the bubble point, and atmospheric pressure. Equation (3) becomes-
1 aim = xApv'A(Tb) - xBpv'B(Tb) (6)
where:
Tb = boiling point temperature of the mixture;
pvA'(Tb) = vapor pressure of pure component A at Tb (Pa):
= vapor pressure of pure component B at Tb (Pa).
Antoine's equation is used to determine the vapor pressure of the pure component as a
function of temperature:
(7)
where A. B and C are chemical-specific Antoine's constants. 7" is the boiling point in °C. and
the vapor pressure p\, is expressed in units of mm Hg The Antoine equation's constants are
obtained from a standard chemical engineering handbook (Dean 1973) If the constants are not
readily available, they are estimated from vapor pressure-temperature data (Perry and Green
1984).
The estimates of the chemical emission rates for the accident events discussed in this
report are based on the following assumptions:
Worst-case mixtures are represented as binary mixtures containing one chemical of
potential concern;
These binary mixtures behave as ideal solutions (i.e., Raoult's Law applies);
All liquids are stored at ambient temperature (20°C) and atmospheric pressure,
Worst-case releases are represented as the release of the largest stored quantity of a
chemical of potential concern over a 10-minute period, under worst case
Volume VII
Anoendix VII-3
-------
meteorological conditions (F stability and 1.0 m/s wind speed), considering passi\e
mitigation measures (U.S. EPA 1995);
For spills in areas where no containment barriers are present, the liquid pool u ill
reach its maximum size when the depth of the pool is 1 cm (U.S EPA 1992),
The temperature of the liquid after release is the same as the ambient temperature.
The procedures used to estimate chemical release rates for each accident event are described
below.
B. Chemical-Specific Release Rate Calculations
1. On-Site Spill
The spills of two types of mixtures, formaldel^de/methanol and acetone/toluene
mixtures, are examined in the Accident Analysis. The following parameters are used toi
the formaldehyde/methanol mixture:
Formaldehyde Methanoi Mixture
Mass Fraction 0.1 0.9 1.0
Molecular Weight 300 32.1 31.9
Boiling Point (K) 252 338 309
Density (kg/m3) 815 791 794
Vapor Pressure at 20°C (Pa) 441.000 12,900 58,400
The following parameters are used for the acetone/toluene mixture:
Acetone Toluene Mixture
Mass Fraction 0.1 0.9 1.0
Molecular Weight 581 92.1 870
Boiling Point (K) 329 384 367
Density (kg/m3) 790 870 861
Vapor Pressure at 20°C (Pa) 24,500 2,930 6.170
The conservative on-site spill event selected for quantitative evaluation results from a
spill of the contents of a 5,000-gallon tanker truck in the Organic Waste Tank Farm Truck
Unloading Station. The tanker is assumed to be a horizontal cylindrical tank, 9.5 m long
and 1.6 m in diameter. The typical on-site spill event selected results from the rupture of
two drums, resulting in a 100-gallon release The spilled drums are assumed to be
horizontal cylinders, 1 m long and 0.515 m in diameter.
Volume VII
Appendix VII-3 3-4
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To model the single-phase release of a liquid waste and the subsequent evaporation of
the resulting liquid pool, two emission rates must be determined and compared the
liquid release rate. £. and the rate of evaporation from a liquid pool. £,, Comparing
these two emission rates will determine the rate of release to the atmosphere
For low volatility liquids. £ will be greater than £ . and the pool's e\aporanon
determines the rate at which material enters the atmosphere The size ot the pool benit;
formed. A., depends on the release rate, duration, and the presence of containment
barriers (e.g.. dikes, speed bumps, building walls, etc.) in the spill vicinity. For the
conservative case, the size of the pool resulting from the 5.000 gallon spill is limited b\
the containment barriers of the Truck Unloading Station (i.e., approximately 418 m:
[75' x60']) . This corresponds to a pool depth of approximately 4.5 cm. For the typical
case, assuming the 100 gallon spill spreads to its maximum size and has a depth of 1 cm
(U.S. EPA 1992), the area of the liquid pool would be approximately 38 nr
In accordance with U.S. EPA guidelines (U.S. EPA 1995), a worst case release is
defined as the release over a 10-minute period of the largest quantity of a regulated
substance resulting from a vessel or process piping failure. Therefore, the liquid release
rate can be estimated by dividing the mass of the liquid in the tanker truck by ten minutes
E =
(10 mm) (60 sec/mm)
where:
£ = emission rate of liquid from hole (kg/s);
V!ank - volume of storage tank (m3);
ps = storage density (kg/m3).
The liquid release rate calculated by Equation (8) can be related to the dimensions of the
tanker and the hole in the tanker using the following (U.S. EPA 1993):
E = A C.
o d
2pt (ph ~ pa)
1 - (A I AY
(9)
Volume VII
Annendiv VIT-3
-------
where:
A0 = area of hole (m:):
Cd = discharge coefficient = 0.62 (unitless);
/Ij = cross-sectional area of liquid container (nr):
ph = pressure at the hole (Pa):
pa = ambient pressure (Pa);
The pressure at the hole (Pa) in Equation (9) is calculated as follows:
(10)
where:
g = acceleration due to gravity = 9.806 (m/s2);
//, = vertical distance between hole and the top of liquid level (m).
pvs = vapor pressure of the chemical at storage temperature, T3 (Pa)
Assuming the area of the hole is much smaller than the cross-sectional area of the liquid
container, Equation (9) reduces to:
(11)
This assumption will be verified when the hole area is calculated. Using the liquid release
rate defined in Equation (8). the area of the hole in the tanker (A() can be back calculated
from Equation (11).
The liquid release rate (E) is compared to the evaporation rate of a liquid pool
= 6.94X 10~7(1 +0.0043(Ara))£/,/l(MW) (12)
where:
Epooi ~ P°o1 emission rate (kg/s);
AT; = 0 if [Ta-273.15]^0
= [7;-273.15] if[70-273.15]>0;
Volume VII
Appendix VII-3 3-6
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Ur = ambient wind speed at 10 m alurude (mis):
Ap - pool size (m:):
p, = vapor pressure of the liquid at Tt, (Pa).
pvh = vapor pressure of hydrazine at 7",, (Pa).
The vapor pressure of hydrazine (Pvh) at T3 in Equation (12) is calculated as follows
exp
76.858 - 7'245'2 -8.221n(r )+0.0061557r
(13)
where:
Ta = ambient temperature (K).
For binary mixtures. Equation (3) can be used to calculate/?,.
Equation (12) is an empirical formula for estimating source emissions from spills of
toxic liquids (Clewell 1983). For the typical and conservative meteorological conditions
discussed in Appendix VII-4. a wind speed (Ur) of 3.2 m/s is used. For the
calm/inversion meteorological condition discussed in Appendix VII-4, a wind speed ot 1
m/s is used for , as discussed below.
Equation (12) will predict no emissions from a spill during calm hours (i.e.. zero
wind speed); therefore an ambient wind speed greater than zero must be used to calculate
emissions for the calm/inversion scenarios. However, using a default average wind speed
of 3.2 m7s in the equation is not realistic, and would overestimate emissions during calm
or extremely low wind speed conditions. To address this issue, the Peer Review Panel
(U.S. EPA 1996) suggested that alternative evaporation models specifically developed for
predicting emissions under extremely low wind conditions (e.g., calm/inversion) be
evaluated.
Two models recommended in the Peer Review Panel comments are evaluated and
discussed in Volume VIII (Response to Peer Review Workshop Comments). Based on the
evaluation, it is believed that chemical emission rates at calm or extremely low wind
conditions can be appropriately modeled by the EPA emission model discussed in this
section. The wind speed used is specified as 1.0 m/s, instead of 3.2 m/s. for the
following reasons:
Volume VII
Appendix VII-3 3-7
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According to U.S. EPA (1995), the calm condition corresponds to the ambient
wind speeds less than 1.0 m/s. A wind speed of 1.0 m/s is thus conservative for
predicting emissions under the calm/inversion condition.
An average wind speed of 3.2 m/s would overestimate emissions.
If the value of Epuih E and the discharge rate from the tanker determines
the atmospheric emission rate. As the chemical is released, a pool forms that is smaller
than Ap, with an evaporation rate from the formed pool equal to E. The smaller pool size
can be back calculated from Equation (12). setting Evoot equal to E.
To determine the evaporation rate of a chemical of concern, the total pool evaporation
rate, Epool, is multiplied by the chemical's mole fraction in the volatilizing mass Because
the vapor pressure of formaldehyde is much greater than that of methanol, formaldehyde
will volatilize from the liquid pool more rapidly than methanol. Since the two chemicals
are released into the atmosphere at different rates, the liquid pool composition will vary
with time. Using Equations (4) and (5) (Raoult's Law), the vapor mass fractions of
formaldehyde and methanol in equilibrium with a 10% formaldehyde, 90% methanol
solution are 0.47 and 0.12. respectively; the balance of the vapor mass is air. Therefore.
the volatilizing mass consists of 80% formaldehyde and 20% methanol.
Being much more volatile and initially present in a lower quantity, the liquid pool will
be depleted of formaldehyde before the entire pool evaporates. As the composition of the
pool changes, the vapor pressure, boiling point and equilibrium compositions will also
change. Therefore, assuming the system remains in pseudo-steady state, the properties of
the liquid pool and the emission rate are recalculated at discrete time intervals using
Equations (3) through (10) until the pool is depleted of formaldehyde.
For spills in which the chemical of concern is depleted in 30 minutes or less, the
calculated time required to deplete the pool of formaldehyde is used in the dispersion
modeling as the duration of release For spills which take longer than 30 minutes to
deplete the chemical of concern, a 30 minute duration is used in the dispersion modeling
since the emission rate and vapor fraction will be highest during this time. The average
emission rate for the mixture during the duration of release is calculated from the iterative
steps discussed above. The average mole fraction of formaldehydfe in vapor is calculated
by averaging the mole fraction computed in each time step. The average mole fraction is
Volume VII
4ooendix VII-3
-------
used in the dispersion analysis to convert the formaldehyde concentrations from the
mixture concentrations.
An algorithm is developed for estimating the average mole fraction of a chemical in
vapor during an accident release. It first estimates the quantity of chemicals emitted from
the liquid pool for a finite time increment. The vapor pressure and evaporation rate oi the
liquid pool are then recalculated for the next time increment using the remaining mass in
the liquid pool. By iterating the calculations, the duration and quantity of emissions and
the average mole fraction of the chemical of concern in the vapor phase can be estimated
The methodology is described as follows:
Step 1. Estimate the initial vapor emission rate
The initial emission rate for the mixture can be estimated using the steady-state
emission model described in Equation (12). The evaporation duration is defined for the
mixture (tmu) based on Equation (12) and the total amount of mixture available for
volatilization (U.S. EPA 1993, FEMA 1993V
r - M /F
Snu ^ 'mix' ^loiaf'
where Mmix is the total quantity of mixture available for evaporation.
It is assumed that the initial emission rate Eloial will remain constant during a release
duration of tmill (U.S. EPA 1993. FEMA 1993), which ignores the reduction in emissions
over time, and therefore overestimates the emission rates and durations for chemicals with
high volatility and underestimates emission rates for the chemicals with low volatility.
Step 2. Estimate the initial chemical-specific vapor emission rate
The initial chemical-specific vapor emission rate is estimated using the following
equation (U.S. EPA 1993):
Echem - (MWchcm/MWmix )(Pchcnl/Pmis)El(
.Dial
The product of MWchcm/MWmi;( and Pchcm/Pm,, represents the initial mass fraction of one
chemical in the vapor immediately after the volatilization
As previously mentioned, chemicals with higher evaporation potential will escape
from the pool faster than other chemicals, and therefore the mass fraction of a chemical
with higher volatility in the vapor phase will be greater than the chemical with low
Volume VII
Appendix VII-3 3-9
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volatility. For example, the initial emissions for a 10% formaldehyde and 90% methanol
mixture will consist of approximately 80% of formaldehyde in the vapor. As the time
elapses the percentage of formaldehyde in the vapor will decrease because of less
formaldehyde available for volatilization in the mixture.
Step 3. Estimate the amount of chemicals evaporated during the initial time step
The amount of chemical evaporated during the initial time step. dMchem, is calculate
by the following equation:
dMctiem = Echem x dt.
where dt is the time increment used in defining the time step. A time step of 60
seconds is used in the iterative calculations.
Step 4. Estimate the chemical properties of the liquid pool for the next time step
By calculating the mass volatilized from the mixture (Step 3) and subtracting it from
the total mass, the mass fractions for the next time step is known. With the new mass
fractions, the chemical properties of the residual liquid mixture can be determined.
Subsequently, the vapor pressure for the new mixture can be computed for estimating the
vapor emission rates for the next time step.
Step 5. Iterate the calculations in Steps 1 through 4 for the next time step
Steps 1 through 4 are repeated until the mass of the chemical of concern in the liquid
pool is completely depleted (i.e., mass fraction < 0.001).
Step 6. Compute the average chemical-specific emission rate, emission duration,
mass evaporated, and mole fraction in the vapor phase
The chemical-specific emission duration can be determined by identifying the time
required for a chemical to be completely depleted from the mixture. The average
chemical-specific emission rate can be calculated by summing the mass emitted for each
time step and dividing by the total time. The average mole fraction in the vapor phase is
calculated by the sum of the moles of the chemical of concern emitted divided by the total
moles emitted for the duration of the release. Emission rates are averaged over 10
minutes for the mitigated release, over one hour for accumulation during an inversion, and
over the time until the chemical of concern is depleted to a mass fraction of < 0.001 for
Volume VII
Appendix VII-3 3-10
-------
the unmitigated release. For an unmitigated release which lasts more than 30 minutes, the
emission rate and the mole fraction in the vapor phase are calculated over the first 30
minutes of the release. This coincides with the 30 minute averaging time used in the air
dispersion modeling and accounts for the fact that emissions of constituents of concern
will be highest during this time.
2. On-Site Fire
a) Emissions of Combustion Products
The on-site fire event selected for quantitative evaluation assumes that a storage
tank ruptures in the Organic Waste Tank Farm in the presence of an ignition source.
resulting in a pool.fire. The contents of the storage tanks are a mixture of 155J-
tetrachloroethene (PCE) and 85% toluene. The following parameters are used for the
tetrachloroethylene/toluene mixture
Mass Fraction
Molecular Weight
Boiling Point (K)
Density (kg/m3)
Vapor Pressure (Pa)
Tetrachloroethene
0.15
166
394
1.630
1.870
Toluene
0.85
92.1
384
870
2.930
Mixture
1.0
98.7
385
935
2.840
The storage tank is assumed to be a vertical cylinder, 6.1 m high and 4 m in
diameter.
The burning velocity for a liquid with a boiling point above ambient temperature
is given by (FEMA 1993; Burgess et al. 1961):
BV =
ID'
SpG
where-
BV
Tb
MW
SpG
burning velocity (m/s);
normal boiling point, (K).
molecular weight (kg/kgmol);
liquid specific gravity (unitless);
Volume VII
Annendix VII-3
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The rate of burning (mass burning rate per unit area) is defined as:
= (SV)Pj (15)
dt
where'
dm/dt = mass burning rate per unit area (kg/m:-s).
ps = liquid density or storage density (kg/m')
By substituting Equation (14) into (15), Equation (15) can be rewritten as.
18r»-4597) (16)
dt
The total burning rate is estimated from the product of Equation (16) and the size of
the burning pool. The pool size is defined by the size of the secondary containment
area in the building.
The height of the name is given by (FEMA 1993; World Bank 1988):
H = 42d
pool
(dm/dt)
0 61
(17)
where:
H = flame height (m);
dpooi ~ effective diameter of pool (m) (calculated from pool size) .
pfl = density of air (kg/m3):
g = acceleration due to gravity (m/s:).
As mentioned earlier, combustion products that may be emitted during a fire
include NO,, SO2, and HC1. Phosgene emissions are also possible as a product of
incomplete combustion. O'Mara et al. (1971) reported that the potential for phosgene
formation during combustion of chlorinated hydrocarbons could be evaluated based on
the following parameter:
Number of Chlorine Atoms - Number of Hydrogen Atoms
_ (18)
Number of Carbon Atoms
Volume VII
Appendix VII-3
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Phosgene formation is likely when a>Q 4. Thus, for example, phosgene could be
formed durin? the combustion of carbon tetrachloride (a = 4). chloroform
-------
Fa = 0.0089
D
(20)
The plume rise caused by a fire is analogous co that caused b\ heated gases released
from a stack. The buoyancy flux for a fire can thus be expressed using Equation
(20).
The heat emission rate can be obtained by multiplying the effective emission
power, Ep, by the area of a heat flux (FEMA 1993). The heat emission rate can thus
be expressed as:
QH - (-0.5634
(21)
where:
Tb = boiling temperature (K).
AH = area of heat emissions (m:);
The flame temperature is calculated based on the heat transfer by way of thermal
radiation. The Stefan-Boltzmann law states that the energy radiated by a hot bod\ is
proportional to the difference in the founh powers of the absolute temperatures of the
hot source and the more cool receiver of the radiation (Burgess 1978). By treating
the fire as a hot source, the flame temperature can be correlated to the heat flux of the
fire as:
QH = 5.67xKT"M,. T?-T4\eF_
(22)
where:
QH = heat emission rate (kW);
7} = flame temperature (K);
e = effective absorptivity on emission factor (£=1);
Fa = geometric configuration factor (Fa=\).
Volume VII
Appendix VII-3
3-14
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b) Emissions of Uncombusted Residues of Waste Constituents
The fire event described above was developed to evaluate emissions of products
of combustion that could possibly be formed during an accident waste fire. However.
emissions of uncombusted residues from waste constituents that are not complete!)
destroyed in the fire are not evaluated. As suggested in the Peer Review Panel
comments (U.S. EPA 1996). an alternative approach is employed to examine
emissions of waste constituents that are not completely destroyed in the fire. A ranee
of destruction efficiency (DE) values for open burning of the waste are assumed to
predict emission rates for residuals of uncombusted organic constituents in the v\ aste
Emissions of "typical" and "worst case" waste constituents are estimated assuming
DE values of 90% and 99%, reflecting the extent of combustion that might be
expected in an open fire. The "typical" and "worst case" waste constituents are
defined based on waste profile data for the first nine months of operation at the XVTI
facility. A detailed description of the expanded waste fire event is presented in
Volume VIII (Response to Peer Review Workshop Comments).
c) Heat Effects
Heat effects for the on-site fire event are calculated using the liquid pool fire
option of the FEMA hazard assessment and consequence analysis model ARCHIE
(FEMA 1993). ARCHIE calculates the radius of the circular zone around a liquid
pool fire in which unprotected and/or unsheltered people may experience lethal burns
due to thermal radiation exposures. The major assumptions of the pool fire model
include the following
The wind velocity in the burning pool area is insufficient to tilt the flame in
the direction of the wind to a significant degree;
Individuals in direct view of the flame and in the open have exposed skin
(i.e., their skin is not protected completely from the effects of thermal
radiation by any clothing being worn);
The base of the flame is fairly circular in shape;
Neither carbon dioxide nor water vapor .in the air absorbs any of the thermal
radiation impinging on exposed individuals;
The injury zone is defined by a radiation intensity of 5 kW/nr, which has
been reported to cause second degree burn injuries on'bare skin within 45
seconds (Mudan 1984);
Volume VII
Appendix VII-3 3-15
-------
The fatality zone is defined by a radiation intensity of 10 kW m:. which has
been reported to quickly cause third degree burns leading to potential
fatalities (Mudan 1984)
For the conservative on-site fire event evaluated here, the pool is assumed to igniit.-
immediately upon initiation of the liquid discharge. Thus, due to depletion of the
pool by combustion losses, the burning pool area may be smaller than the total spilled
pool area.
In addition to the heat effects from a pool fire, ARCHIE can calculate the size of
a fireball (diameter, height and duration) and associated thermal radiation zones
resulting from the rupture of a tank engulfed in fire and the subsequent ignition of us
contents. Thus, in the on-site fire event, the impact of an explosion of a tank adjacent
to the fire can be evaluated. The major assu.nptions of the fireball thermal radiation
model include the following:
No thermal radiation is absorbed by water vapor or carbon dioxide gas
present in the atmosphere;
All flammable materials of interest are similar in characteristics (both
physical and chemical properties) to liquefied compressed propane.
Both the container and exposed individuals are on or near the ground.
The burn seventy depends upon the amount of energy absorbed by the skin
after a surface temperature of 55 °C is achieved.
3. On-Site Mixing of Incompatible Wastes
According to ASTM (1986), the mixing of certain classes of incompatible wastes
could result in the generation of toxic gases such as hydrogen chloride, hydrogen cyanide
and hydrogen sulfide, all of which have similar Levels of Concern (LOCs). Because of
the relatively large amounts of chlorinated compounds expected to be processed at the
WTI facility, the generation and release of HC1 was selected for quantitative evaluation in
this event. One of the chemicals with the highest chlorine content that is likely to be
handled on-site is tetrachlorethene. A 15% tetrachlorethene/85 % methanol waste is
assumed to be accidentally added to a storage tank already containing mineral acids (70%
nitric acid solution). According to ASTM (1986), the mixture of strong mineral acids
with halogenated organic compounds may result in the generation of hydrogen halides
Volume VII
Appendix VII-3 3-16
-------
Therefore, the mixture of tetrachlorethene with nitric acid is likely to result in the
formation and release of gaseous hydrogen chloride.
The conservative on-site mixing of incompatible wastes event selected for quantitative
evaluation results from the accidental pumping of waste from a 5.000-gallon tanker into
the wrong vessel in the Organic Waste Tank Farm Assuming the waste from the tanker
is being pumped at its maximum rate of 250 gal/min. the tanker contents would be
transferred into the storage tank over a 20 minute period. The typical case involves a
situation similar to the typical case for the on-site spill event (i.e., the rupture of tour 55-
gallon drums). Two of the drums in the typical event contain a 15% tetrachlorethene 85 cr
methanol, and the other two drums contain a 70% nitric acid solution.
The following parameters are used for the tetrachlorethene/methanol mixture
Tetrachloro£...ene Methanol Mixture
Mass Fraction 0.15 0.85 1.0
Molecular Weight 166 32.1 36.5
Density (kg/m3) 1,630 791 857
To model the release of HC1 resulting from the mixing of incompatible wastes, it is
assumed that as the two wastes mix. the reaction between the two wastes to produce HC1
is instantaneous. For the conservative case, the duration of atmospheric release is
estimated to be the 20 minute period required to pump all of the contents of the tanker into
the storage tank For the typical case, the release duration is estimated to be the amount
of time required for the contents of the four drums to be spilled, forming a liquid pool
The total amount of HC1 emitted in both cases is calculated from a mass balance
4. Off-Site Tanker Truck Spill
The size of the off-site spill depends on the release rate, duration and the presence of
containment barriers (e.g., street curbs, speed bumps, building walls, etc ) in the spill
vicinity, if any. As is the case for the on-site spill, the evaporation of the off-site liquid
pool is dominated primarily by the rate of evaporation as air flows over the surface of the
pool. Equations (8) through (13) are used for estimating the emission rate for this event
Assuming the road on which the spill occurs has no curbs that are capable of acting as
a containment barrier, the liquid pool resulting from the conservative 5,000-gallon spill is
assumed to reach a maximum length of approximately 49 m, assuming pool depth of 1
cm. This assumes the pool spreads in all directions at an equal rate, with liquids reaching
the edge of the road running off onto soil or into a ditch. Assuming the width of the road
Volume VII
; _ ] 1
-------
limits the pool to 15 m wide, the area ot the poo! is 49 m x 15 m approximate!) ("35 nr i
In the typical 100-gallon spill case, the pool size is approximate!) 38 m:
5. Off-Site Tanker Truck Spill with Fire
The off-site fire event is similar to the off-site spill event, with the additional pre.serK
of an ignition source. To model emissions of products of combustion from the resulting
pool fire, Equations (14) through (22) are used. The pool is assumed to ignite
immediately upon initiation of the liquid discharge. Thus, the burning pool area ma\ be
smaller than the total spilled pool area. ARCHIE is used to calculate the heat effects
associated with the off-site fire (FEMA 1993).
Similar to the on-site fire event, emissions of uncombusted residues from waste
constiruents that are not completely destroyed in the off-site fire are evaluated in
Volume VIII. Emissions of "typical" and "wors. case" waste constiruents are estimated
assuming DE values of 90% and 99%, reflecting the extent of combustion that might be
expected in a fire. A detailed description of the expanded fire event is presented in
Volume VIII.
C. Results of the Release Modeling
Tables I through 14 show the input parameters used to derive average total emission rates
for each accident event under both conservative and typical emission conditions. Example
calculations and relevant input parameters for the initial time steps are presented below. The
average total emission rates are summarized in Table 15.
1. On-Site Spill
a) Physical and chemical properties of 10% Formaldehyde/90% Methanol
mixture
WF = 0.1
WM = 0.9
(1) Molecular weight
By Equation (1):
Volume VII
Annendix VII-3 3-18
-------
MW = = 31.9 g/mol
mu 0.1 0.9
30.0^/mo/ 32.\gimol
(2) Liquid mole fractions:
By Equation (4):
x = I \(ll.9g/mol) = 0.106
1 30.0^/mo/j
xu = 1 -0.106 - 0.894
M
(3) Boiling point:
Antoine's constants:
Formaldehyde A = 1.045; 5=929.5; C=243.1
Methanol A = 7.879; 5=1,473; C=230.0
Using these Antoine's constants. Equation (6) was solved iteratively for Th.
By Equation (7).
929 47
7 0.147
36: ' 2437/ =
pv (36.2°C) = 101 36 ' 43 = 5.300 mm Hg
787863
Pym (36.2°C) = 10 362 2300/ = 221 mmHg
where Tb = 36.2°C satisfies Equation (6) as follows:
(0.106)(5,300 mm Hg) + (0 894)(221 mm Hg) = 760 mm Hg
(4) Density
pF = 815 kg/m3 at 20°C
pM = 791 kg/m3 at 20°C
Volume VII
iv VTT-l
-------
According to Equation (1).
p = = 794 kg/m
0.1 0.9
815 kg/m* 19
(5) Vapor pressure
By Equation (7):
929
7 0447 - Hl_
Pvf (20CC) - 101 20 ' 2437/ = 3,310 mm Hg
1473
7 87863
/> (20°C) - 10l 20 ' 210° = 96.9
By Equation (3)
/7v(20°C) = (0.106)(3.310 mm Hg) +(0.894X96.9 mmHg)
= (438 mmHg)(133 Pa /mmHg)
- 5.84e-04Pa
(6) Vapor composition
By incorporating Equation (5):
(a) Initial vapor mole fractions
438
v (20X1^, = (0 B94X96.9 mmHg)
438 mmHg
Volume VII
Appendix VII-3 3-20
-------
(b) Initial vapor mass fraction per mole-
(0.80)(30.0g//no/)
(0.8Q)(30.0g/mol) -(0.20)(32.1 g/mol)
r = (0.80)(30.0g//no/) = Q ?92
V = (0.20)02.1 = 0.208
g/rro/) ~(0.20)(32.1g/mo/)
(7) Heat of vaporization
A.F = 8.25e+05J/kg
AM = 1.10e+06J/kg
By Equation (2):
Anu = (Q.lO)(8.25e+05J/kg)~(0.90)(lAOe+06J/kg)
(8) Heat capacity
(a) Equilibrium vapor at 20 °C. 1 atm
C^g = 789 J/kg K
CpMig = 1.370 J/kg K
In a similar fashion as Equation (2)
Cpmii = (0 792)(790///tg/O *(0.
= 910 JlkgK
(b) Liquid mixture, 25 °C
CpFl = 4.300 J/kg K (estimated by Kopp's rule)
CpM! = 2.540 J/kg K
In a similar fashion as (2).
^
mu, = (O.IO)(4,300//JkgAr)-*-(0.9K2.540//^AT) = 2,720J/kgK
Volume VII
-------
b) Other Parameters
(1) Volume of spill
V.....(m
S.OOQgfl/
264gal/m3
= 18.9m3
(2) Depth of pool
Containment area
= 418 nr = Ar
depth -
spill
18.9m 3
418m2
= 0.045m
(3) Effective diameter of pool
d ,(m) -- 2
pool
418 m*
\
= 23.1 m
(4) Cross sectional area of liquid container
//, = 1.6 m. vertical distance between hole and top of liquid level
5000 gal _
264 gal/m 3
71
.6 m
(1.6 m) = 15.1 m
Volume VII
Annendix VIT-3
1-22
-------
c) Calculations
(1) Pressure at the hole
By Equation (10)
p = max(1.01;tl05 Pa,
Pa) -(794kg/m 3)(9.81
I 14 x 10" PC
(2) Vapor pressure of hydrazine at Ta
By Equation (13):
76.858- 7'245"2 -8.221n(293 AT)+0.0061557 (293AT)
- 293 K
= 1,400 Pa
(3) Liquid release rate from tanker
By Equation (8).
5,000gal
(10mm)(60 sec/mm)
= 25 kg/sec
pool
(4) Total initial evaporation rate
By Equation (12).
= 6.94X 10~7(1 + 0.0043(20AT)(3.2
= 2.51 kg/s
°"(418,n>)(31.9,/,n0/)'5MOO/>a
1,400 Pa
(5) Initial evaporation rate of formaldehyde
E,otF -' Y '- (2.51**/5)(0.792) = 1.
Volume VII
Appendix VII-3
3-23
-------
(6) Evaporation time, average evaporation rate, or average mass
evaporation
Calculated iteratively as described in Steps 1 through 6 of Section B.I
(7) Area of hole
Using Equation (11):
- - = - g 5 -- 0 0091 m ~
- 1 .01 x
which confirms the assumption that A^A^.
2. On-Site Fire
The calculation of the mixture properties and storage tank parameters is the same as
demonstrated in the previous section. The values of these parameters are summarized in
Tabie 3
(a) Mass burning rate
By Equation (16):
= 1.54 x 10'3 (98.7 g/mol) e -° °043 0 8(384 45Ar> ~459 7>
dt
= '5.60E-02 kglm2-s
(b) Flame height
By Equation (17):
// = 42(15.1 m)
> \ 0 61
0.0560 kg/m2-s
v 1.2 Jk^/m v(15.1 m)(9.8
= 21.3 m
(c) HC1 emission rate
di \ kg PCE
Volume VII
Appendix VII-3 3-24
-------
m(HCl) = (0.15 kg PCE/kg) (0.0560 kg/m2-s) (180 m 2) 238 g
HCl
kg PCE
= 0.36 kg/s
1 k
;-., \
1000
(d) Phosgene emission rate
1 kg
m(phos) = (0.15 kg PCE/kg) (0.0560 kg/m2-s) (180 m :) 8 P
kg PCE
= 1.06E-02 kg/s
(e) Heat emission rate
By Equation (21):
QH
= -0.5634 (384 K) - 260.87 = 44.3 kWIm
1000 g
(f) Buoyancy flux
By Equation (20):
= 70.
(g) Average fire temperature
By Equation (22):
IH4
293*+ 1^_| = 942 AT
5.67E-11
(h) Heat effects
The input parameters used in ARCHIE to compute the liquid pool fire heat
effects and the fireball thermal radiation effects are summarized in Attachment 1
Volume VII
Annpnrliv VTT-1
-------
3. On-Site Mixing of Incompatible Wastes
Calculations not included follow those in Section I.C.I for the on-site spill event.
The values of these parameters are summarized in Tables 5 and 6.
(a) HCI release rate
The HCI release rate is based on a mass balance, assuming all Cl from the
tetrachloroethylene (PCE) reacts to form HCI. The number of moles of PCE
transferred from the tanker into the storage tank is:
0.15 **rt>c J'"uu*a< (857*g/m3)
I *?«««««^ 264ja//m3 j
Moles PCE transferred - '
166 "6'~"
1 kgmolPCE)
= 14.7 kgmolPCE
Four moles of HCI are produced for every mole of PCE:
Mass HCI produced = (14.1 kgmolPCE)] 4 kSmolHCl 36.5
( kgmolPCE)( kgmolHCl)
= 2,\50kgHCl
The release rate is calculated by averaging the amount of HCI produced over the
transfer time:
HCI release rate = 2,l50kgHCl = 1.19 kg/sec
(20mm)(60sec/min)
The exit velocity at which HCI is released from the vent (8 inch diameter) of the
Organic Waste Tank Farm is.
l.79kg/s (0.08206 ^ aim I kgmolK)(291, K)
, 36.5kg/kgmol 1 aim .. A .
HCI velocity = = 36.4m/sec
0.0324m:
Volume VII
4nnenriix VII-3 3-26
-------
4. Off-Site Tanker Truck Spill
The majority of the emissions calculations for the off-site spill event follow those ot
the on-site spill event described in Section II.C.I The major difference in the parameter-
used for the calculations is the size of the resulting pool. If the pool were allowed u>
reach its maximum diameter, at a depth of 1 cm, the resulting pool diameter would he
The length of the pool is assumed to reach this maximum diameter. Because of the
presence of ditches or soil along the side of the road, which restrict the flow of the pool in
the direction perpendicular to the road, the width of the pool is assumed to be the width of
the road (15 m). The spill is either collected by the ditches or adsorbed by the soil in the
direction perpendicular to the road. Therefore the pool size for the off-site spill event is:
A = (49m)(15/n) = 735m
P
The values of the parameters calculated for this off-site event are summarized in Tables 7
and 8.
5. Off-Site Tanker Truck Spill with Fire
The majority of the emissions calculations for the off-site spill with fire event follow
those of the off-site spill event described in the previous section, and the on-site fire event
described in Section I.C.2. The major differences in the parameters used for the
calculations is the volume of the spilled wastes that are ignited. The volume of spill
associated with the off-site fire is one quarter of the volume of spill associated with the
on-site fire. The values of the parameters calculated for this event are summarized in
Tables 9 and 10.
Volume VII
Aooendix VII-3 3-2'
-------
II. REFERENCES
American Society for Testing and Materials (ASTM). 1986. Proposed guide for estimating
the incompatibility of selected hazardous wastes based on binary chemical reactions
D-34 Proposal P 168. March.
Briggs, G.A. 1975. Plume rise predictions. In Lectures on air pollution and environmental
impact analyses. American Meteorological Society.
Burgess, D.S., A. Strasser, and J. Grumer. 1961. Diffusive burning of liquid fuel in open
trays. The Fire Research Abs. & Review 3.177.
Burgess, H.J. 1978. The thermal environment conditioning and control Harper & Row
Publisher, New York, N.Y.
Clewell, H.J. 1983. A simple formula for estimating source strengths for spills of toxic
liquids. U.S. Air Force Report ESL-TR-83-03.
Cooper, C.D. and F.C. Alley. 1990. Air pollution control: a design approach. Waveland
Press. Prospect Heights, IL
Dean, J.A. 1973. Lange's handbook of chemistry, eleventh edition. McGraw-Hill Book
Company, New York, N.Y.
Federal Emergency Management Agency (FEMA), United States Department of
Transportation (U.S. DOT), and United States Environmental Protection Agency (U.S.
EPA). 1993. Handbook of chemical hazard analysis procedure NTIS PB93-158756
Mudan, K.S. 1984. Thermal radiation hazards from hydrocarbon pool fires. Prog. Energy-
Comb. Sci. 10:59-80.
O'Mara, M.M., L.B. Crider, and R.L. Daniel. 1971. Combustion products from vinyl
chloride monomer. Amer. Industrial Hygiene Assoc. Journal 32:153-156.
Perry, R.H. and D.W. Green. 1984. Perry's chemical engineer's handbook. Sixth edition.
McGraw-Hill Book Company. New York, NY.
Volume VII
iv VTT-3 3-28
-------
Sjoberg. B 1952 Thermal decomposition of chlorinated hydrocarbons Svensk Kemisik
Tidsskrifi 64:63-79.
United States Environmental Protection Agency (U.S. EPA). 1992 Office of Air Qualu>
Planning and Standards. Workbook of screening techniques for assessing impact <
air pollutants (Revised). U.S. EPA-454/R-92-024. Research Triangle Park. NC Ma>
United States Environmental Protection Agency (U.S. EPA). 1993. Office of Air Qualitx
Planning and Standards. Guidance on the application of refined dispersion model* for
hazardous/toxic air releases. U.S. EPA-454/R-93-002. Research Triangle Park. NC
May.
United States Environmental Protection Agency (U.S. EPA). 1995. Office of Air Quality
Planning and Standards. User's guide for the Industrial Source Complex (ISC3)
dispersion models. Volumes I and II. U.S EPA-454/B-95-003a, -003b. Research
Triangle Park, NC. September.
United States Environmental Protection Agency (U.S. EPA). 1996. Post-workshop draft
comments from the Peer Review Workshop for the Draft Risk Assessment for WTI.
World Bank. 1988 Techniques for assessing industrial hazards. World Bank Technical
Paper Number 55. The World Bank Washington, D.C.
Volume VII
AnnpnHiv VTT-1 ~!-">Q
-------
TABLE 1
Accident Analysis Calculations
On-Site Spill (conservative). Typical and Conservative Meteorological Condition
(a) 5.000 gallon spill of 10% formaldehyde/90% methanol mixture
Chemical/Physical
Properties:
V.
X,
MWikg/kgmol)
Th(K)
p (kg/nV)
P. (Pa)
Y,
Xv,r (J/kg-K)
CP., U/kg-K)
C, , (J/kg-K)
Formaldehyde
1 OOe-01
1 06e-01
3 OOe + 01
2.52e-02
8.15e~02
441e^-05
7.92e-01
8 25e^05
7 89e-02
4.30e^03
Methanol
9 OOe-01
8 94e-01
3.21e-01
3.38e-02
7 91e-02
1.29e-r04
2.08e-01
!.10e + 06
I 3/e-03
2 54e-03
Mixture
1 OOe-00
1 OOe-00
3 19e~01
3 09e^02
7 94e->-02
5 84e-04
i OOe^OO
1 07e^06
9 10e-02
2 72e-03
Notes
hquia ma.^ traction
liquid mole traction
molecular weight
boiling temperature
liquid density at T
vapor pressure at T,
vapor mass traction at T
heat of vaporization at T
gas' heat capjui) ai 2^'C
liquid heat capacity at 25 CC
Truck parameters:
AO (nr)
A, (m:)
H, (m)
T,(K)
9.09e-03
l.Sle-t-01
1 60e + 00
2 93e + 02
area of hole
cross sectionai area of liquid container
venical distance between hole and top of liquid level
storage temperature
Other parameters:
T,(K)
P. (Pa)
V!P1|,
tspu< IS>
A,, ( m; )
e-02
4 I8e-02
2 31e~01
4 53e-02
3.20e^00
ambient teni^trature
ambient pressure
volume; ot spill (5 000 gal)
spill nme
pool area i75' x60'i
effective pool diameter
pool depth
wind speed ar 10 m height
Calculations:
pn (Pa)
P,h (Pa)
E (kg/s)
E^,, (kg/s)
Er,.,, isoo (kg/s)
E,,*! 6oo < kg/s >
W (s)
i
i 1800
.600
1 14e^05
1 40e*03
2.50e-01
1 04e^00
1 33e-00
1 99e*00
3 12e-r03
4 78e-01
6 Ole-01
7 42e-01
pressure at the hole
vapor pressure ot hydrazme at T,
liquid release rate trom the truck
average coul evaporation rate until lormaldehvde depleted
average total evaporation rate over the first 1800 s
average total evaporation rate over first 600 s
time to evaporate (formaldehyde)
average tormaldehvde vapor mole fraction until formaldehyde depleted
average formaldehyde vapor mole fraction over the first 1800 s
average formaldehyde vapor mole fraction over the first 600 s
Note
1 Depletion defined when the liquid mass fraction of tormaldehvde in the evaporatine pool reaches 0 001
Volume VII
\ TT-"
-------
TABLE 1 (continued)
i
Accident Analysis Calculations
On-Site Spill (conservative). Typical and Conservative Meteorological Condition
(a) 5,000 gallon spill of 10% formaldehyde/90% methanol mixture
Chemical/Physical
Properties:
w,
x,
MW (kg/kgmol)
Tb(K)
p (kg/m'i
p, (Pa)
Y,
A.,,, (J/kg-K)
Cp,£ (J/kg-K)
Cpl (J/kg-K)
Acetone
1 OOe-01
1 50e-01
5 816-01
3.29e-02
7 90e-02
2.45e + 04
5.96e-01
5.08e+05
1.29e + 03
2.23e+03
Toluene
9 OOe-01
8 50e-01
9 216-01
3 846-02
8 70e-02
2 93e-03
4.04e-01
3 60e-05
1 13e + 03
1 73e-03
Truck parameters:
AO (nr)
A, (nri
H, (m)
T,(K)
9 09e-0?
1 51e-01
1 60e-00
2.93e-02
Mixture
1 OOe-00
1 OOe-00
S 70e-01
3 67e-02
8 61e-02
6 17e+03
1 OOe+00
3 75e + 05
1 20e + 03
1.78e-03
Notes
liquid mass fraction
liquid mole traction
molecular ueiL'ln
boiling temperature
liquid densiu at T,
vapor pressure at T.
vapor mass fraction at T
heat of vaporization at T,
gas heat capacity at 25 °C
liquid heat capacity at 25 °C
area ot hole
cross sectional arc
d ot liquid container
vertical distance between hole and top ot liquid level
storage temperature
Other parameters:
Td(K>
pa (Pa)
V,P,n (mj)
t,n,H (S)
Ap (m:)
dp^tm)
depth (m)
U, (m/s)
2.93e+02
l.Ole + 05
1.89e-01
6.00e-02
4 18e+02
2.316-01
4 53e-02
3 20e - 00
ambient temperature
ambient pressure
total volume ot spill (5.000 gal)
spill time
pool area i75' x60'i
effective pool diameter
pool depth
wind speed at 10 m height
Calculations:
ph (Pa)
P«n (Pa)
E (kg/s)
Epo,,, (kg/s)
EP...I isoo (kg/s)
h- / L--fj / c )
"-pool 600 V^tf.'3/
W (s)
,
i 1800
i ISOO
1 15e-05
1 40e + 03
2 72e-01
4 65e-01
6.81e-01
7 12e-01
1 82e-04
2 73e-01
5.57e-0l
5 85e-0l
pressure at the hole
vapor pressure of hvdrazine at T,
liquid release rate
average total ev?"<
from the truck (assumed to be released in 10 minutes)
Cation rate until acetone depleted1
average total evaporation rate for the
average total evaporation rate for the
time to evaporate (acetone I
first 1800s
first 600 s
I
average acetone vapor mole traction until acetone depleied
average acetone vapor mole traction over the first 1800 s
average acetone vapor mole fraction over the first 600 s
Note
1 Depletion defined when the liquid mass traction of acetone in
the evaporating pool reaches 0 001
Volume VII
4noendi\ VTT-3
-------
TABLE 2
Accident Analysis Calculations
On-Site Spill (typical). Typical and Conservative Meteorological Condition
(a) 100 gallon spill of 10% formaldehyde/909c methanol mixture
Chemical/Physical
Properties:
w
X
MW (kg kgmoli
T.CK)
p (kg'm'i
p, (Pai
Y
A.vir (J/kg-Ki
Crs (J/kg-K)
Cr : (J/kg-K)
Formaldehyde
1 OOe-01
i 06e-01
3 OOe-01
2 52e-02
8 15e-02
4 41e-05
92e-01
8 25e-05
7 89e-02
4 30e-03
Methanol
9 OUe-OI
S 94e-01
3 21e-01
3 38e-02
" 91e-02
1 29e-()4
2 08e-01
1 10e-06
1 37e-03
2 54e-03
Mixture
1 OOe-00
! OOe-00
3 19e-01
3 09e-02
"? 94e-02
5 84e-04
! OUe-Ou
1 07e-06
9 10e-02
2 72e+03
Drum parameters:
AO (m;)
A, (m-)
H. (m)
T, (Ki
1 60e-04
2 06e-00
5 15e-01
2 93e-02
Notes
liquid mass traction
liquid mole fraction
molecular weight
boiling temperature
liquid densit) ai T
vapor pressure ai T
vapor mass traaion a; 1 j
heat of vaporization a; 1 j
gas heat capacity at 25 "C
liquid heat capacity at 25 °C
area of hole
cross sectional area of liquid container
vertical distance between hole and top of liquid level
storage temperature
Other parameters:
T,(K)
P. (Pa)
VW1. im1'
Isp,,, «>
A,, ( m~ )
d^( B)( ( m i
depth (m)
U, (m/s)
2 93e-02
1 Ole-05
3 79e-01
6 OOe-02
3 79e-01
6 94e-(K)
1 OOc-02
3 20e-(Xi
ambient temperature
ambient pressure
total volume of spill ( 100 gal)
spill time
pool area
etiecme pool diameter
pool depth
wind speed a: H) m height
Calculations:
ph (Pa)
P.h (Pa)
E (kg/s)
E^, (kg/s)
Ep^woOcg's)
W
-------
TABLE 2 (continued)
Accident Analysis Calculations
On-Site Spill (typical). Typical and Conservative Meteorological Condition
(a) 100 gallon spill of 10% formaldehyde/90^ methanol mixture
Chemical/Physical
Properties:
w,
X,
MW (kg/kgmol)
Th
H, (m)
T,(K)
1 6Ue-04
206e-00
5 15e-01
2 93e-02
area ot hole
cross sectional area of liquid container
vertical distance between hole and top of liquid level
storage temperature
Other parameters:
T,(K)
Pa (Pa)
vsmi: (m3)
l,p,i, (S)
Ar ( rrr i
d,,,,, (mi
depth (m)
U, (mis)
2 93e*02
1 Olc-05
3 79e-01
600e*02
3 79t-01
6 94e-00
1 OOe-02
3 20e^00
ambient temperature
ambient pressure
total volume of spill ( 100 gal)
spill time
pool area
effective pool diameter
pool depth
wind speed at 10 m height
Calculations:
P, (Pa)
Pvh (Pa)
E (kg/s)
EP...I (kg's)
EPO..I isoo ( kg' s)
Ep,K,]600(kg/s)
Uar (S)
'i
i 1800
..600
1 06e-r05
1 40e*03
2.72e-01
4 22e-02
? 05e-02
5 99e-02
3 96e-03
2 76e-01
4 20e-01
5 38e-01
pressure at the hole
vapor pressure of hvdraiine at T,
liquid release rate from each drum
average uual evaporation rate until acetone depleted
average total evaporation rale over the first 1800 s
average total evaporation rate tor the
first 600 s
time to evaporate (acetone)
average acetone vapor mole fraction until depleted'
average acetone vapor mole fraction over the first 1800 s
average acetone vapor mole fraction over the first 600 s
Note
Depletion defined when the liquid mass traction ot acetone in the evaporating pool reaches 0 001
Volume VII
Appendix VII-3
-------
TABLE 3
Accident Analysis Calculations
On-Site Fire (conservative)
PCE storage tank rupture in Organic Waste Tank Farm
Chemical/Physical
Properties:
u
\
MY\ ikg'kgmoli
Th(K>
p (kg m3>
p. (Pa)
A.v<(J/kg-Ki
PCE
! 5Ue-01
8 93e-02
1 bOe-02
3 94e-02
1 63e-03
1.87e^03
NU
Toluene
^ 5uc-0i
v : ic-ni
^ 2 1 r - 0 1
3 Me -02
8 70e-02
2.93e-03
NU
Mixture Notes
. OUe-OU iiquu mass ira^'.ioi
i UUe-lXi liquid mole tra^tio:
gS~e-0! molecular wemii i
3 85e-02 noiimg tempera. ure !
9.35e-02 liquid den.sin, a( Ta
2 84e-03 vapor pressure ai T
NU heat of vaporization at T,
Tank parameters:
AO (m2)
A, tm2)
H, (mi
dur, (mi
T%(Ki
1 86e-02
1 24e-01
6 10e-00
3 98e-00
2 93e-02
area of hole
cross sectional area of ' nuid container
height ot storage tank (20 ft)
tank diameter
storage temperature
Other parameters:
Tt(Ki
p, (Pa)
v,r,n tnr')
t,P,i: (SI
Ap (nri
^>,
depth (mi
HCI (g'kg)
PG(g/kg;
2 93e-02
1 Ole-05
1 57e-01
0 OOe-02
1 80e-02
1 5le-01
4 21e-01
2 38c-02
7 OOe*(X)
ambient temperature
ambient pressuie
total volume oi spill (20.000 gall
spill time
size ot containment area
ettectue pool uiameter
pool Jeptl!
HCI production in
m PCE
phosgene production trom PCE
Calculations:
dm/dt (kg/nv-si
H (m)
mHr, (kg/si
mpo (kg'si
QH (kW/m:i
F (m4
-------
TABLE 4
Accident Analysis Calculations
On-Site Fire (typical)
Four PCE drum rupture indoors
Chemical/Physical
Properties:
w,
X,
MW (kg/kgmol)
Th(K)
p (kg/m3)
p> (Pa)
A.var (J/kg-K)
PCE
1 50e-01
8.93e-02
1 66e~02
3 94e-02
1 63e^03
1 87e-03
NU1
Toluene
8 50e-01
9 lle-01
9.21e*01
3 84e~02
8 70e-02
2 93e~03
NU
Mixture Notes
1 OOe-t-00 liquid mass fraction
l.OOe-'-OO liquid mole traction
9 87e-^01 molecular weight
3 85e^02 boiling temperature
9 35e~02 liquid density at T
2 84e-t-03 vapor pressure at T,
NU heat of vaporization at T.
Drum parameters (modeled as a 220-gallon horizontal cylindrical container):
Afl(m2)
A, (m2)
H, (m)
TJK)
1 60e-04
2.06e-rOO
5.15e-01
2 93e~02
area of hole
cross sectional 'irea oi liquid container
vertical distance between hole and top of liquid level
storage temperature
Other parameters:
T, 00
pa (Pa)
Vv,,, (m3)
^ill (S)
Ap (m:)
dp.,,, (m)
depth (m)
HC1 (g/kgi
PG (g/kg)
293e~02
1 Ole-05
7.57e-01
600e^02
7.57e+01
9 82e + 00
1 OOe-02
2 38e+02
700e-00
ambient temperature
ambient pressure
total volume ol spill (200 gal)
spill time
size ot containment area
effective pool diameter
pool depth
HC1 production trom PCE
phosgene production from PCE
Calculations:
dm/dt (kg/m:-si
H(m)
mHCi (kg/s)
mrc (kg/s)
QH (kW/m-')
F (m4/s3)
T(K)
Ihun, (S)
5.60e-02
1 58e-OI
1.51e-01
4 45e-03
443e+01
298e+01
942e-»-02
1 67e+02
masv burning rate per unit area
flame height
emission rate ot HC1
emission rate ol phosgene
heat emission rate
buovanc\ flux
average fire temperature
time ot burn
Note
1 NU = Not used
Volume VII
Appendix VII-3
i- ;>
-------
TABLE 5
Accident Analysis Calculations
On-Site Mixing of Incompatible Wastes (conservative)
Pumping of tanker contents into wrong storage tank
Chemical Phv steal Properties
Truck:
v>
X
MW (kg/kgmol)
Th(K)
p (kg/m'i
p, (Pa)
Storage tank:
u
X
MW (kg/kgmol 1
Th(K)
p (kg/m-'i
p> (Pa)
PCE
1 50e-01
3 30e-02
1 66e-02
3 94e + 02
1 63e^03
1 87e + 03
Nitric acid
7 OOe-01
2 55e-01
6 30e^01
3 56e-02
1 506-03
6 40e-03
Methanol
8 50e-01
9 67e-01
3 2k-01
3 38e-02
7 9k-02
1 29e-04
V\ater
3 OOe-01
3 82e-01
1 80e-01
3 73e-02
1 OOe-03
2 34e-03
Mixture
1 OOe-00
1 OOe-00
3 65e-01
3 39e-02
8 57e-02
1 26-r04
Mixture
1 OOe-00
6 6e-01
2.29e+01
3 93e-02
1 lie -03
3 37e-03
Notts
liuuid mass traction
liquid mole traction
molecular weight
boiling temperature
liquid densirs
vapor pressure at T
liquid mass traction
liquid mole fraction
molecular weight
boiling temperature
liquid densin
vapor pressure at T4
Other parameters:
T,(K)
Pj (Pa)
V^,,, (ITM
r,,,- .Uiiragc tank (5 000 gjn
maximum pumping rate trom truck 250 gal mm)
wind speed ai 10 m height
area ot vent discharge (8 inch diameter)
height of vent discharge
Calculations:
MHC; (kg/si
U (s)
1 79e^00
1 20-03
relea.se rate of HC1
duration ot HC1 release
Note
Includes plume rise due to momentum
Volume VII
Appendix VII-3
-i -i /-
_>-_> 6
-------
TABLE 6
Accident Analysis Calculations
On-Site Mixing of Incompatible Wastes (typical)
Four drum rupture outdoors
Chemical/Physical Properties:
Drums A:
w,
X,
MW (kg/kgmol>
T,(K)
p (kg/m3)
P. (Pa)
Drums B:
w(
x,
MW (kg/kgmol)
Th(K)
p (kg/m3)
p, (Pa)
Drum parameters:
Ao(m2)
AO (nr)
A, (m2)
H, (m)
T,(K)
Other parameters:
T,(K)
P, (Pa)
Vspll, (m3)
\(m2)
dro-i (m)
depth (m)
Ur (m/s)
Calculations:
PM (Pa)
Ph: (Pa)
PVK (Pa)
E, (kg/s)
E, (kg/s)
PCE
I 50e-OI
3 30e-02
1 66e-02
3 94e~02
1.63e + 03
1.87e + 03
Nitric acid
7.00e:01
2.55e-01
6 3Ue + 01
3 56e~02
1 50e-^03
640e~03
Methanol
8 5Ue-ni
9 67e-01
3 21e-01
3 38e-02
791e-r02
1.29e-04
Water
3.00e-OI 1
3 82e-01
1 80e-01
? 73e-02
1 OOe-03
2.34c-03
Mixture
1 OOe-00
1 OOe-00
365e-01
3 39e+02
8.57e+02
1.26 -+-04
Mixture
l.OOe+OO
6 36e-01
229e + 01
3 93e+02
1 lle*03
3.37e + 03
Notes
liquid mass fraction
liquid mole traction
molecular weight
boiling temperature
liquid densm
vapor pressure at T
liquid mass fraction
liquid mole fraction
molecular weigh!
hoi 1 ing temperature
liquid densit)
vapor pressure at T.
1.60e-04
1 60e-04
206e+00
5 15e-0l
2 93e^02
area of hole for Drums A
area of hole tor Drums B
cross sectional area of liquid container
venical distance between hole and top of liquid level
storage temperature
2 93e-02
1 Ole-05
7 57e-01
7.57e + 01
9.82e-*-00
1 .OOe-02
3.20e+00
ambient temperature
ambient pressure
total volume of spill (200 gal)
pool area (low volatility)
effective pool diameter
pool depth ( 1 cmi
wind speed at 10 m height
1 06e-t-05
1 07e*05
1 40e^03
2 70e-01
3 51e-01
pressure at the hole in Drums A
pressure at the hole in Drums B
vapor pressure of hydrazine at T,
liquid release rate from Drums A
liquid release rate from Drums B
Volume VII
Annendix VII-3
-------
TABLE 6 (continued)
Accident Analysis Calculations
On-Site Mixing of Incompatible \Vastes (typical)
Four drum rupture outdoors
Calculations:
6 OOe-02
spill time rrom Drums A
6 OOe-02
spill time rrom Drums B
7 14e-02
release rate of HC1
L, IS I
600e-02
duration of HC1 release
Volume VII
Annendix VII-3
3-38
-------
TABLE 7
Accident Analysis Calculations
Off-Site Spill (conservative), Typical and Conservative Meteorological Condition
(a) One truck accident, containing 5.000 gallons of 10% formaldehyde/90 *7c methanol mixture
Chemical/Physical
[Properties:
1
r
MW (kg/kgmoU
rh(K)
p (kg/m-)
?> (Pa)
Y,
K^fJ/kg-K)
Cpe(J/kg-K)
Crl(J/kg-K)
Formaldehyde
1 OOe-01
1 06e-01
3 OOe-01
2 52e~02
8 15e^02
441e+-05
7.92e-01
8 25e+05
7 89e-02
4 30e-03
Methanol
9 Oue-01
8 94e-01
3 21e-01
3 38e*02
7 91e~02
1.29e-04
2 08e-01
1 10e-06
1 37e-03
2 54e-03
Mixture
1 OOe-00
1 OOe-00
3 19e-01
3 09e-02
7 94e-02
5 84e-04
1 OOe^OO
1 07e-06
9 10e-02
2 ^2c-0:-
Truck parameters:
AC (nv)
A, (nv)
H, (m)
T, (K)
9 09e-03
1 51e-01
1 60e + 00
293e-02
Notes
liquid rrus-. rrajnon
liquia mole traction
molecular weight
boiling temperature
liquid densirs at T.
vapor pressure at T
vapor mass fraction at T
leat ot vaporization at T
gas neat capaun at 25 "C
iquid heal capa>.it\ at 2^"C
area of hole
cross sectional area of liquid container
vertical distance between hole and top of liquid level
storage temperature
Other parameters:
MK>
p, (Pa)
vlnin (m')
t,n - (S>
Ar (rrr)
dp,,,,
depth (m)
L, (m/s)
2 93e*02
1 Ole-05
1 89e-01
600e-02
7 35e-02
3 06e^01
2.58e-02
3.20e-00
ambient temperature
ambient pressure
total volume ot spill (5.000 gal)
spill time;
pool area
effective pool diameter
pool depth
wind speed at 10 m
height
Calculations:
P, (Pa)
PVH (Pa)
E (kg/s)
EP,.,I (kg/s>
Uplsi
'.
1 14e*05
I 40e-0?
2 50c-01
1 84e-(X)
! 74c-03
4 84e-01
pressure at the hole
vapor pressure or hvdrdzme at Td
iquid rclea.se rate trom truck
average total evaporation rate until tormaldehvUe depleted
ime to evaporate (formaldehyde)
average formaldehyde vapor mole traction until depleted'
Mote.
Depletion defined when the liquid mass fraction of formaldehyde in the evaporatme pool reaches 0 001
Volume VII
-------
TABLE 7 (continued*
Accident Analysis Calculations
Off-Site Spill (conservative). Typical and Conservative Meteorological Condition
(a) One truck accident, containing 5.000 gallons of 10% formaldehyde '90^ methanol mixture
Chemical/Physical
Properties:
w.
\
MW (kg'kgmoh
Tn(K)
p (kg/m'i
p, (Pa)
V,
^ (J/kg-K)
Cpt (J/kg-K)
Cp, (J/kg-K)
Acetone
1 OOe-01
1 50e-01
5 81e-01
3 29e-02
7 90e-02
2 45e*04
5 96e-01
5 08e+05
1.29e + 03
2.23e-03
Toluene
9 OOe-Ul
b 5()t-OI
^ 21e-Ul
3 84^-02
S 70e*02
2 93e-03
4 04e-01
3 60e*05
1 13e + 03
1 73e-03
Mixture
! OOc-00
I OOc-OU
S 70e-0!
3 67e-02
8 61e-02
6 17e-t-03
1 OOe-00
3 75e + 05
1 20e + 03
: "8e~03
Notes
liquid mass rra^noi.
liquid mole rractioi,
molecular weigh:
boiling temperature
liquid densin at To
vapor pressure at T,
vapor mass traction at T,
heat of vaporization at T.
gas heat capacity at 25 °C
liquid heat capacir, at 25 "C
Truck parameters:
A,, im:)
A; im:)
-1, (m)
F,(K)
9 09e-0?
1 5ie-()l
1 60e-00
2 93e-02
area ol hole
LTOSV sectional area ol liquid container
vertical distance heiueen hole and top ot liquid level
storage temperarure
3ther parameters:
r« (K)
P, (Pa)
Vsp,,, (m')
IVM, (s)
A_ (trr)
iv.,, (m)
depth (m)
U, (m/s)
2 93e-02
1 Ole-05
1 89e-01
600e-0:
" 35e-02
? 06e-01
2 58e-02
3 20e-00
amhieni temperature
ambient pressure
total \olume ol spill (5.000 gall
spill time
pool area
ettecii\c pool diameter
pooi depth
umd speed at 10 m height
Calculations:
P, (Pa)
Pvh (Pa)
E (kg/s)
Ep..,, (kg/s)
EP..,, isoo (kg-M
W (S)
1800
1 15e-05
1 40et-03
2 72e^-01
8 18e-01
1 14e-01
1 03c-04
2 74e-01
5 27e-01
pressure at the hole
\apor pressure of hvdrazme at Td
liquid release rale trom truck
average total evaporation rate until acetone depleted'
average total evaporation rate over the first 1800 s
time to evaporate (acetone 1
average acetone vapor mole traction until depleted
average acetone vapor mole traction over the first 1800 s
Note
Depletion defined when the liquid mass traction ot" acetone in the evaporating pool reaches 0 001
Volume VII
Annendiv VII-3
-------
TABLE 8
Accident Analysis Calculations
Off-Site Spill (typical), Typical and Conservative Meteorological Condition
(a) One truck accident. 100 gallon spill of W9c formaldehyde/
90% methanol mixture
Chemical/Physical
Properties:
w
X
MW (kg<'kgmoli
Th(K)
p (kg/m1)
p, (Pa)
Y,
A.VJp(J/kg-K)
Cpt (J/kg-K)
Crl(J/kg-K)
Formaldehyde
1 OOe-01
I 06e-0i
3 OOe-01
2 52e^02
8 15e~02
4 41e-05
7 92e-01
8 25e-05
7 89e.-^02
4.30e-03
Methanol
9 OOe-01
8 94e-01
3 21c--01
3 38e-02
7 91e-02
! 29e-04
2 O&e-Ol
1 10e-06
1.37e-03
2 54e-03
Mixture
1 OOe-00
1 OOe-00
3 19e-01
3 09e-02
794e-02
5 84e-04
1 OOe-00
1 07e-^06
9 10e+02
2 -Je-t-03
Truck parameters:
A,, (rrr)
A, (rrr)
H, (mi
TJK)
1 82e-04
1 51e*01
1 60e-00
: 93tf-o:
Notes
liquid mass traction
liquid mass fraction
molecular weighi
boiling temperature
liquid densitx at T
\apor pressure ai T
\apor mass traction a! 1
heat ot vaporization at T
gas heat capacity at 25 DC
liquid heat capacity at 25 T
area of hole
cross sectional area of liquid container
vertical distance between hole and top of liquid level
storage temperature
Other parameters:
Td(K)
pd (Pa>
Vspl(1(m't
ISP,:
3 79e-01
6 OOe-02
3 79e-01
6 94e-0()
1 OOc-02
3 20e - 00
jmDient temperature
ambient pressure
lotal volume ot spill (100 gal)
spill time
pool area ilow volatility 1
etteaive pool diameter
pool depth
wind ^peed at 10 m heicht
Calculations:
ph (Pa)
P,h (Pa)
E (kg/s)
En..,! C^g/SI
W (S>
J'
1 Ht-O?
1 40e*0?
5 Ole-01
9 44e-02
6 80e-t-02
4 82e-01
pressure ai [lie ht>le
vapor pressure ot hvdrazine at T^
liquid release rate from the truck
average total evaporation rate until formaldehyde depleted
time to evaporate (formaldehyde)
average tormaldehyde vapor mole fraction until depleted
Depletion defined when the liquid mass traction ot formaldehyde in the evaporatine pool reaches 0 001
Volume VII
\noendix VII-3
-------
TABLE 8 (continued)
Accident Analysis Calculations
Off-Site Spill (typical). Typical and Conservathe Meteorological Condition
(a) One truck accident. 100 gallon spill of 10% formaldehyde
90% methanol mixture
Chemical/Physical
Properties:
V,
x,
M\V (kg/kgmol)
Th(K)
p (kg/mj)
p, (Pa)
Y
Xvar(J/kg-Ki
Crt(J/kg-K>
Cr,(J/kg-Ki
Acetone
l.OUe-01
1 50e-01
5.81e*01
3.29e*02
7.90e + 02
2 45e + 04
5.96e-01
5 08e*05
1 29c*03
2 23e+03
Toluene
9 OOe-01
8.50e-01
9.21e*01
3 84e + 02
8.70e+02
2 93e+03
4 04e-01
3. 60s -05
1 13e*03
1 73e+03
Mixture
1 OOe-00
1 OUe-00
8 70e + 0l
3 67e*02
8.61e+02
6.17et-03
1 OOe+00
3.75e+05
1 20e*03
. .86*03
Nolt^
liquid mass traction
liquid mass traction
molecular weight
boiling temperature
liquid density at T,
vapor pressure at T,
vapor mass fraction at T
heat of vaporization at T,
gas heat capacity at 25 °C
liquid heat capacin. at 25°C
Truck parameters:
A<, (nr)
A, (m:)
H, (m)
T,(K)
i 82e-04
1 51e + 01
1 60e-i-00
293e^02
area of hole
cross sectional area of liquid container
vertical distance between hole and top of liquid level
storage temperature
Other parameters:
T,(K)
p, (Pa)
V\P,II (m'l
t,P,ii (s)
A? (m-)
^ (m)
depth (m)
U, (m/s)
2 93e-02
1 Ole + 05
3 79e-0!
600e*02
3 79e^01
6.94e+00
1 OOe-02
3.20e-rOO
ambient temperature
ambient pressure
total volume or spill (100 gal)
spill time
pool area (low volatility)
effective pool diameter
pool depth
wind speed at 10 m height
Calculations:
ph (Pa)
pvh (Pa)
E(kg/si
Ep.,,, (kg/si
EP...I isoo (kg/M
W (S)
f,
f| 1800
1 156*05
1 40e-03
5 43e-01
4 22e-02
5 05e-02
3.96e+03
2.76e-01
4 20e-01
pressure at the hole
\apor pressure of hvdrazine at Td
liquid release rate
trom the truck
average total evaporation rate until acetone depleted
average total evaporation rate over the first 1800 s
time to evaporate (acetone)
average acetone vapor mole fraction until depleted1
average acetone vapor mole fraction over the first 1800 s
Note.
«
' Depletion defined when the liquid mass traction ot acetone in the evaporating pool reaches 0 001
Volume VII
\ T-»r\oor3tv \T
?-42
-------
TABLE 9
Accident Analysis Calculations
Off-Site Spill with Fire (conservative)
One truck accident, containing 5,000 gallons of 15% PCE/85% toluene mixture
Chemical/Physical
Properties:
w
X
MW (kg 'kernel)
Th(K)
p (kg/m3)
p, (Pa)
Avaf> (J/kg-Ki
PCE
1 50e-01
8 93e-02
1 66c-02
3 94c-02
1 63e-03
1.87e~03
NU1
Toluene
S 5ue-01
9 lle-01
V 21e-(>!
_^ j(4«r-o:
8 70c-02
293e-03
NU
Mixture Notes
1 Oue00 liquid mass traction
1 OUe-00 liquid mas^ tractioi,
9 8~e-01 molecular u,et>:ni
3 85e 02 huiiiiiLi temperaturt !
935e-02 liquid densin. ail j
2 84e-03 vapor pressure at T
NU heat of vaporization at 1
Tank parameters:
A<,(m2)
A, (m2)
H, (m)
TJK)
9 03e-03
1.51e*01
1 60e-00
2 93e-02
area of hole
cross sectional area of liquid container of the truck
vertical distance :
etween hole and top of liquid level
storage temperature
Other parameters:
T, (K)
Pl (Pa)
V!P,,, (m3)
W,, (s)
Ar (m:)
-------
TABLE 10
Accident Analysis Calculations
Off-Site Spill uith Fire (typical)
One truck accident. 100 gallon spill of 15Tr PCE 85^ toluene mixture
Chemical Phvsical
Properties:
V,
\
M\V (kg kgmol'
T. (Ki
p ikg/m3i
p, (Pa)
A,d- (J kg-K1
PCE
; 50e-01
8 93e-02
1 66e-02
3 94e-02
1 63e-03
1 S7e-03
NT
Toluene
8 5Ue-0!
9 iie-01
921e-01
3 84e-02
8 "Oe-02
2 93e-03
Nl
Mixture Notes
1 Due 00 liquid mass rracnor
1 0(je-00 liquid mass fraction
9 87eT01 molecular weignt
3 85e-02 boiling temperature
9 35e-02 liquid densm ai T.
2 84e-03 vapor pressure at T
NT heat ot vaporization a: T-
Tank parameters:
\ (m2i
A (m2i
H imi
T, (K)
1 S2e-04
1 51e-01
1 60e~00
2 93e-02
area ot hole
cross sectional area of liquid container
vertical distance betw-e. ,jole and top ot liquid level
storage temperature
Other parameters:
T, ('Ki
p, (Pai
V(n, im'i
i,. (si
A. (nr>
dp,., (mi
depth (mt
HCI (g.kgi
PG (g'kgi
2 93e-02
1 Ole-05
? "9e-01
6 OUe - 02
3 79e - 0 1
6 94e - (K)
1 (X)e-02
: 38e-02
7 OOe-00
amr>ient temperature
ambient pressure
total Noiume o! spill i IOC gab
spill time
size or ^oniainnieni area
ertecme pool diameter
pool deptn
HCI production rrom PCE
phosgene prouucuon irom PCE
Calculations:
dm.'dt (kg m~-s>
^ imi
mHr(kg.M
mpo (kg si
QH fkW'm-i
FtmV)
T(K)
t*u-r ( S 1
5 6()e-02
1 24e-0!
~ 5bc-02
2 22e-03
4 43e-(II
1 49e-01
9 42e-02
I 67e-02
mass burning rate per unu area
flame Meiniv
e mssi.'n rate i'1 HO
emission rale nt plu>si:enc
Meat emission r..:_
huoNaiK\ llu\
average fire temperature
time ot nurnmt1
Note
Not used
Volume VII
Appendix VII-3
-------
TABLE 11
Accident Analysis Calculations
On-Site Spill (conservative), Calm/Inversion Meteorological Condition
(a) 5.000 gallon spill of 10% formaldehyde/90% methanol mixture
Chemical/Physical
Properties:
u
X
MW (kg.kgmoii
Th(K)
p (kg/m'i
p, (Pa)
Y,
XV1P (J/kg-K)
Cp.8 (J/kg-K)
Cpl (J/kg-K)
Formaldehyde
1 OOe-01
1 06e-0i
3 OOe-01
2 52e-02
8 15e-02
4.41e*05
7 92e-01
8.25e + 05
7 89e + 02
4 30e + 03
Methanol
9 OOe-01
>< 94C-01
? 21e-01
3 3Sc-02
7 91c-02
1.29e-04
2.08e-01
1 10e^06
1 37e-03
2 54e-^03
Truck parameters:
AO (nr)
A, (m:)
H, (m)
T, (K)
9 09e-03
1 51e-01
1 60e^00
2.93e + 02
Mixture
1 OOe-00
1 OOe-00
3 19e-Ul
3 09e-02
^ 94e-02
5 84e-04
1 OOe + 00
1.07e-r06
9 10e^02
2 72e^03
Notes
liquid mass fraction
liquid mole tracnor
molecular ueis:lr. |
hoi ling temperature
liquid densir\ at T
vapor pressure at T,
vapor mass traction at T i
heat of vaporization at T
gas heat capacity ai 25 °C
liquid heat capacity at 25 °C
area of hole
cross sectional area ot liquid container
vertical distance between hole and top of liquid level
storage temperature
Other parameters:
TJK)
P, (Pa)
V,P,H (m3'
t,p,,, (S)
AP (nr)
depth irn)
Ur (m/si
2 93e~02
1 Ole*05
1 89e-01
600e-02
4 18e-02
2 3ie-0i
4 53e-02
1 OOe-00
ambient temperature
ambient pressure
volume ot spill (5.000 gal)
spill time
pool area (75 x 60' )
etteui\e pool diameter
pool depth
wind speed at 10 m height
Calculations:
P* (Pa)
Pv* (Pa)
E (kg/s)
E^,, (kg/s)
Qaoo (kg)
QJMO (kg)
E^,. 3600-end (kg/s)
W 1600-cnd
1 14e-05
pressure at the hole
1 40e-^03 vapor pressure of hydrazine at Td
2 50e-01
4 32e-01
5 71e*02
2 I7e + 03
2 74e-01
7 50e-03
7 78e-01
6.32e-01
1 52e-01
liquid release rate from the truck
average total evaporation rare until formaldehyde depleted1
total mass ot mixture evaporated over
total mass ot mixture evaporated over
the first 600 s
the first 3600 s
average total evaporation rate from 3600 s until formaldehyde depleted'
time to evaporate (formaldehyde)
average formaldehyde vapor mole fraction over the first 600 s
average formaldehyde vapor mole fraction over the first 3600 s
average formaldehyde vapor mole fraction from 3600 s until formaldehyde
depleted ^,
Note
1 Depletion defined when the liquid mass fraction of formaldehyde in the evaporatine pool reaches 0 001
Volume VII
-------
TABLE 11 (continued)
Accident Analysis Calculations
On-Site Spill (conservative), Calm/Inversion Meteorological Condition
(b) 5,000 gallon spill of 10% acetone/90% toluene mixture
Chemical/Physical
Properties:
w
X
MW(kg/kgmol)
Th(K>
p (kg/m')
p, (Pa)
Y,
A.v,p (J/kg-K)
CPE (J/kg-K)
Cp., (J/kg-K)
Acetone
1 OOe-01
1 50e-01
5 Sle^Ol
3.29e-02
-< 90e~02
2 45e-04
5 96e-01
5.08e*05
1.29ei-03
2.23e + 03
Toluene
9 OOe-01
8 50e-01
9 21e~01
? 84e-02
S 7Uc-02
2 93c-03
4 04e-0l
3 60e^05
1 13e-03
1 73e-03
Mixture
l.OOe-00
1 OOe-00
8 70e-01
3 67e-02
S61e-02
6,17e-r03
1 OOe-t-00
3 75e+05
1 20e-r03
1 78e+03
Truck parameters:
Ao600-entJ l^S'S)
UP IS)
:i 600
', 3600
'l 1600-cnd
1.15e-05
1 40e*03
2 72e*01
1.94e-01
l.SOe-i-02
1 03e+03
1.86e-01
4 39e-04
5 91e-01
5 62e-01
2.25e-01
pressure jt the hole
vapor pressure of hvdrazine at TH
liquid release rate trom the truck
average total evaporation rate until acetone depleted1
total mass of mixture evaporated over
total mass ot mixture evaporated over
the first 600 s
the first 3600 s
average total evaporation rate trom 3600 s until acetone depleted
time to evaporate (acetone!
average acetone vapor mole traction over the first 600 s
average acetone vapor mole traction over the first 3600 s
average acetone vapor mole fraction trom 3600 s until acetone depleted
Note
Depletion defined when the liquid mass traction ot acetone in
the evaporating pool reaches 0.001
Volume VII
-------
TABLE 12
Accident Analysis Calculations
On-Site Spill (typical). Calm/Inversion Meteorological Condition
(a) 100 gallon spill of lOTr formaldehyde/909r methanol mixture
Chemical/Physical
Properties:
w
X
MW (kg/kgmol)
Th(K)
p (kg/mj)
p, (Pa)
Y,
Xvdr (J/kg-fO
Crt(J/kg-K)
Cpl(J/kg-Ki
Formaldehyde
1 OOe-01
1 06e-01
3 OOe-0!
2 52e-02
8 15e-02
441e+05
7 92e-01
825e-05
7 89e-02
4 30e-03
Methanol
9 OOe-OI
S ^4e-01
3 21e-01
3 38e-02
7 91e-02
1.29e-04
2 08e-01
1 10e-06
1 37e-03
2 54e-03
Drum parameters:
AQ (nr)
A, (nr)
H, (m)
TJK)
1 60e-04
2 06e*00
5 15e-01
2 93e-02
Mixture
i OOe-00
1 OOe-00
3 19e-01
309e-02
7 94e-02
5 84e-04
1 OOe-rOO
1 07e-06
9 10e-02
2 72e-03
Notes
liquid mass traction
liquid mole traction
molecular ueight
boiling temperature-
liquid density at T
vapor pressure at T,
vapor mass traction at T
heat of vaporization at T
gas heat capacity at 25 °C
liquid heat capacity at 25 °C
area ot each hole
cross sectional area of liquid container
vertical distance between hole and top of liquid level
storage temperature
Other parameters:
T,(K)
p. (Pa)
V,P,,, (m-)
kn... (s)
A. (m;l
d,..,,
-------
TABLE 12 (continued)
Accident Analysis Calculations
Scenario 1: On-Site Spill (typical), Calm/Inversion Meteorological Condition
(b) 100 gallon spill of 10% acetone/90% toluene mixture
Chemical/Physical
Properties:
\v
X
MW (ke/kcmoli
T, (Ki
p (kg m''i
p, (Pa)
Y,
Avir (J/kg-K;
CPi: (J/kg-K)
Cr, (J/kg-K)
Acetone
1 OOe-01
1 50e-01
5 81c-01
3 29e~02
7 90e-02
2 45e~04
5 96e-01
5 08e + 05
1 29e + 03
2.23e^03
Toluene
9 OOe-01
8 50e-01
9 21e-01
3 84e-02
8 70e-02
2.93e-03
4 04e-01
3.60e-05
1 13e-03
1 73e-03
Mixture
1 OOe-00
1 OOe-00
S 70c-01
3 67e-02
8.61e^02
6 17e~03
l.OOe-i-00
3 75e-05
1 20e + 03
1 78e-03
Notes
liquid mass traction
liquid mole traction
molecular weight
boiling temperature
liquid density at T,
vapor pressure a! T,
vapor mass fraction at T
heat of vaporization ai T.
gas heat capacir\ at 25 "C
liquid heat capacit> ai 25 = C
Drum parameters:
An (m:)
A, (s)
Ar (m:)
dp,,,, (kg*
Q3600 (^)
EjMo-end (kg/s)
W (s)
'i 600
', 5600
'i 160»J
1 06e-i-05
1 40e*03
2 72e-01
1.80e-02
1 59e + 01
7 86e-^01
1 50e-02
966e-03
5 72e-01
4 45e-01
1 Ole-01
pressure at the hole
vapor pressure of hydrazine at T,
liquid release raie
trom each drum
average total evaporation rate until acetone depleted'
total mass of mixture evaporated over the first 600 s
total mass ot mixture evaporated over the first 3600 s
average total evaporation rate from 3600 s until acetone depleted
time to evaporate (acetone)
average acetone vapor mole traction over the first 600 s
average acetone vapor mole fraction
average acetone vapor mole fraction
Note.
Depletion defined when the liquid mass fraction of acetone in
over the first 3600 s
from 3600 s until acetone depleted1
*"
the evaporating pool reaches 0 001
Volume VII
« ,*;..- A'TT
-------
TABLE 13
Accident Analysis Calculations
Off-Site Spill (conservative). Calm/Inversion Meteorological Condition
(a) One truck accident, containing 5.000 gallons of 10% formaJdehvde/907r methanol mixture
Chemical/Physical
Properties:
w,
X,
MW (kg/kgmob
T,(K)
p -(kg/m-1)
p, (Pa)
Y,
A.VJr (J/kg-K)
Cp., (J/kg-K)
Cpl (J/kg-K)
Formaldehyde
l.OOe-01
1 06e-01
3 OOe + 01
2 52e-^02
8.15e-02
441e+05
7 92e-01
8.25e + 05
7.89e + 02
4.30e + 03
Methanol
9 OOe-01
8 94e-01
3.21e*01
3 38e-02
7 91e-02
1 29c-04
2 08e-01
1 10e*06
1 37e + 03
2.54e^03
Mixture
l.OOe-00
1 OOe-00
3 19e + 0!
3 09e^02
7 94e-r02
5 84e + 04
1 OOe-00
1.07e-t-06
9.lOe+02
2.72e+03
Truck parameters:
AO (m2)
A, (m2)
H, (m)
TS(K)
9.09e-03
l.Sle+01
1 60e + 00
2 93e-02
Notes
liquid mas-, traction
liquid mole traction
molecular weigh!
boiling temperature
liquid density at T
vapor pressure at T
vapor mass traction at T.
heat of vaporization at "L
gas heat capacity at 25 °C
liquid heat capacity at 25 °C
area of hole
cross sectional area of liquid container
vertical distance between hole and top of liquid level
storage temperature
Other parameters:
L(K)
Pa (Pa)
Vsr,,,, (m3)
V,, (s)
Ap (m:)
cU'
i 5600
i 5600-cikJ
1 14e-05
1 40e^03
2.50e-»-01
7.59e-01
2 95e+03
4.34e-01
4.26e + 03
5 17e-01
5 30e-02
pressure al the hole
vapor pressure of hydrazine at T,
liquid release rate from truck
average total evaporation rate until formaldehyde depleted1
total mass of mixture evaporated for first hour
average total evaporation rate from 3600 s until formaldehyde depleted
time to evaporate (formaldehyde)
average formaldehyde vapor mole fraction for first 3600 s
average formaldehyde vapor mole fraction until formaidehvde depleted
Note
' Depletion defined when the liquid mass traction of formaidehvde in the evaporating pool peaches 0 001
Volume VII
-------
TABLE 13 (continued)
Accident Analysis Calculations
Off-Site Spill (conservative), Calm/Inversion Meteorological Condition
(b) One truck accident, containing 5,000 gallons of 10% acetone/90kg-K)
Cr (J/kg-Ki
Acetone
1 OUe-01
1 5Ue-01
5 8ie~01
3 29e-02
7.90e~02
2 45e^04
5 96e-01
508e-r05
1 29e-rQ3
2 23c-03
Toluene
9 OUe-Ul
8 50e-01
9.21e-01
3 84e-02
8 70e-02
2.93e^03
4 04e-01
3 60e-05
1 13e-03
1 73c-03
Mixture
1 OOe-00
1 OOc-00
8 70e^-01
3.67e^02
8 61e-^02
6 17e-03
1 OOe-rOO
3 75e^05
1 20e~03
1 78e-03
Notes
liquid mass traction
liquid mole traction
molecular weight
boiling temperature
liquid density at Ta
vapor pressure at T.
vapor mass fraction at T
heat ot vaporization ai T
gas heat capacit\ ai 25 "C
liquid heal ^apa^nv at 25 C
Truck parameters:
AO (nr)
A, (m:)
H, (m)
T\fK)
9 09e-03
1 51e-01
1 60e+00
2 93e-02
area of hole
cross sectional area of liquid container
vertical distance between hole and top of liquid level
storage temperature
Other parameters:
T,(K)
p, (Pa)
V^.tnV)
t,p,l! (S)
A, (m:i
dp,.,, (mi
depth (mi
L', (m/s)
2 93e~02
1 Ole-05
1 89e-01
6 OOe - 02
1 35e-02
? 06e-01
2 58e-02
1 OOe-00
ambient temperature
ambient pressure
total volume ot spill (5.000 gal)
spill time
pool area
effective pool diameter
pool depth
wind speed at 10 m height
Calculations:
Ph (Pa)
p.* (Pa)
E (kg/si
E^fkg/si
Q56oo (kg)
Ep-xil JdO^enJ (kg/S)
W (s)
*i )«00
'i 3600-eivJ
! 15e-05
1 4Ue - 0?
2 ~2e~UI
3 41e-Ul
1 74e-03
3 17e-01
2 50e + 04
5 37e-01
1 93e-01
pressure at the hole
vapor pressure ot hvdrazine at Tj
liquid release rale trom truck
average total evaporation rate until acetone depleted
total mass ot mixture evaporated over first 3600 s
average total evaporation rate from 3600 s until acetone depleted
time to evaporate (acetone)
average acetone vapor mole fraction over first 3600 s
average acetone vapor mole fraction from 3600 s until acetone depleted'
N'ote
Depletion defined when the liquid mass traction of acetone in the evaporating pool reaches 0 001
Volume VII
-------
TABLE 14
Accident Analysis Calculations
Off-Site Spill (typical). Calm/Inversion Meteorological Condition
(a) One truck accident. 100 gallon spill of 109r formaldehyde
90% methanol mixture
Chemical/Physical
Properties:
w
X
MW (kg/kgmoli
Th(K)
p (kg/nTi
p. (Pa)
Y,
Avir (J/kg-K)
Cpt (J/kg-K)
Cpl (J/kg-K)
Formaldehyde
1 OOe-01
1 06e-01
3 OOe-01
2 52e-02
8 15e-02
441e + 05
7.92e-01
8.25e+05
7 89e + 02
4 30e + 03
Methanol
9 OOe-01
8 94e-01
? 21c-01
3 38e-02
7 91e*02
1.29C-T-G4
2.08e-OJ
1 10e+06
1 37e + 03
2 54e-03
Mixture
i Olle-OU
1 Oue-OU
3 19e-01
3 09e-02
794e~02
5 84e+04
l.OOe-t-00
1 07e + 06
9 10e^02
2 72e + 03
Truck parameters:
A, (m2)
A, (nr)
H, (mi
TJK)
1 82e-04
1 5ie-01
1 60e-00
2 93e-02
Notes
liquid mass rraaK-::
liquid mole traai.M'
molecular ucign:
boiling temperature
liquid densin. at T.
vapor pressure at T^
vapor mass fraction at Ta
heat of vaporization at T.
gas heat capacity at 25 °C
liquid heat capacity at 25 °C
area of hole
cross sectional area ol liquid container
vertical distance between hole and top of liquid level
storage temperature
Other parameters:
T,(K)
P, (Pa)
V,nil, (m3)
t,n,n (s)
Ar (m-)
dp,. (m>
depth (m;
U, (m/s)
2 93e~02
1 Ole-05
3 79e-01
600e-02
3 79e-01
6 94e-U)
1 OOe-02
1 (X)e-(X)
ambient temperature
ambient pressure
total volume of spill ( 100 gal)
spill time
pool area
ettecme pool diameier
pool depth
wind speed at 10 m height
Calculations:
P, (Pa)
Pvh (Pa)
E (kg/s)
£.,, (kg/si
Q(kg)
IT.* (S)
1 14e^05
1 40e-03
5 Ole-01
3 90e-02
648e-01
1 66e~03
4 77e-01
pressure at the hole
vapor pressure of hydrazine at Ta
liquid release rate from the truck
average total evaporation rate until formaldehyde depleted1
total mass ot mixture evaporated until
formaldehyde depleted
time u> evaporate itormaldehyde)
average formaldehyde vapor mole fraction until depleted
Note
Depletion defined when the liquid mass fraction of formaldehyde in the evaporating pool reaches 0 001
Volume VII
* i:_ i-T
-------
TABLE 14 (continued)
Accident Analysis Calculations
Off-Site Spill (typical), Calm/Inversion Meteorological Condition
(b) One truck accident, 100 gallon spill of
10% acetone/90% toluene mixture
Chemical/Physical
Properties:
V,,
X
MW (kg/kgmol)
Th(Ki
p (kg/m'i
P, (Pa)
Y,
XViir (J/kg-Ki
CPB(J/kg-K)
Cp , (J/kg-K)
Acetone
1 OOe-01
1 50e-01
5 8Ie-01
3.29e~02
7 90e-02
2 45e-04
5 96e-01
5 08e + 05
1.29e + 03
2.23e+03
Toluene
9 OOe-01
8 50e-01
921e-0!
3 84e-02
8 7Ue-02
2 93e-03
4 04e-01
3 60e~05
1 13e*03
1 73e-03
Mixture
1 OOe^OO
1 OOe-00
8 70e-01
3 67e-02
8 61e-02
6 17e-03
1 OOe-00
3 75e~05
i 20e-03
1 78e*03
Notes
liquid mass traction
liquid mole traction
molecular weight
boiling temperature
liquid densio. al T
vapor pressure Ji T
vapor mass traction a; 1
heat of vaporization at T
gas heat capacin. at 25 CC
liquid heat capacin at 25 °C
Truck parameters:
AO (m:)
A, (m2)
H, (m)
T, (K)
1.82e-04
1 51e-*-01
1 60e^00
2 93e-02
area of hole
cross sectional area of liquid container
vertical distance between hole and top of liquid level
storage temperature
Other parameters:
T. (K)
P, (Pa)
V,plll (m3)
1SP,P (S)
Ar (m:)
dp,,,, (m)
depth (m)
Ur (nv's)
2 93e-02
1 Ole-05
3 79e-01
600e-02
3 79e-01
6 94e-00
1 OOe-02
1 00e~00
ambient temperature
ambient pressure
total volume of spill (100 gal)
spill time
pool area
effective pool diameter
pool depth
wind speed at 10 m height
Calculations:
P, (Pa)
P,h (Pa)
E (kg/s)
E^ (kg/s)
Q3600 (kg)
EVOO, (kg/s)
««,» (s)
> '600
1600-cixl
1 15e~05
1 40e - 03
5 43e-01
1.80e-02
7.86e+01
1 50e-02
966e + 03
4 45e-01
1 Ole-01
pressure ai the hole
\apor pressure ot hvdrazme at T\
liquid release rate trom the truck
average total evaporation rate until acetone depleted1
total mass of mixture evaporated over
the first 3600 s
average total evaporation rate from 3600 s until acetone depleted'
time to evaporate (acetone)
average acetone vapor mole fraction over the first 3600 s
average acetone vapor mole fraction t'rom 3600 s until acetone depleted
Note
1 Depletion defined when the liquid mass traction ot acetone in the evaporating pool reaches,,0 001
Volume VII
A nnpnHiv VT
-------
TABLE 15 ]
Summary of Average Total Emission Rates for
All Events Evaluated in the Accident Analysis
Event
On-Site Spill1
3.2 m/s
Formaldehyde
Acetone
1.0 m/s
Formaldehyde
Acetone
On-Site Fire
HC1
Phosgene
On-Site Mixing of Incompatible Wastes
HC1
Off-Site Spill1
3.2 m/s
Formaldehyde
Acetone
1.0 m/s
Formaldehyde
Acetone
Off-Site Fire
HC1
Phosgene
Average Release Rate (kg's)
Conservative Emissions
1.33
0.681
0.432
0.194
0.36
0.011
1.79
1. 84
1.14
0.759
0.341
1.47
0.043
Typical Emissions
(J 044
0 051
0.039
>0018
0.15
0.0045
0.071
0094
0.051
0.039
0 018
0 076
0 0022
Note:
1 The spill events consider a typical wind speed of 3.2 m/s for the typical and conservative
meteorological conditions, and a calm wind speed of 1.0 m/s for the calm/inversion
meteorological condition. The emission rates for the non-spill events are not dependent on wind
speed.
Volume VII
-------
ATTACHMENT 1
ARCHIE Output for On-Site and Off-Site Fire Events
-------
1. Fire after the spill achieves maximum size
-------
HAZARDOUS MATERIAL = PCE/toluene
ADDRESS \ LOCATION * WTI, East Liverpool, OH
DATE OF ASSESSMENT = June 5, 1995
NAME OF DISK FILE = SC2CQN.ASF
*** SCENARIO DESCRIPTION
WTI Accident Analysis, Scenario 2 (conservative)
Storage tank rupture in organic waste tank farrr.
20,000 gallon spill and fire
******* DISCHARGE RATE/DURATION ESTIMATES
Liquid discharge from nonpressurized container
Average discharge rate * 15352 Ibs/mir.
Duration of discharge « 10.2 minutes
Amount discharged * 156095 Ibs
State of material = Liquid
******* LIQUID POOL SIZE ESTIMATES
Evaporating pool area » 1940 ft2
Burning pool area » 1940 ft2
Note: Pool is assumed to ignite after pool achieves max-
imum size.
******* pooL FIRE HAZARD ESTIMATION RESULTS
Burning pool radius » 24.9 feet
Flame height - 70 feet
Fatality zone radius « 65 feet
Injury zone radius » 93 feet
FIREBALL HAZARD RESULTS
Max fireball diameter - 859 feet
Maximum fireball height - 1411 feet
Fireball duration - 16.5 seconds
Fatality zone radius - 1199 feet
Injury zone radius * 2274 feet
-------
INPUT PARAMETER SUMMARY
233
98.68
.94
.409
21.13
PHYSIOCHEMICAL PROPERTIES OF MATER-
NORMAL BOILING POINT
MOLECULAR WEIGHT
LIQUID SPECIFIC GRAVITY
VAPOR PRES AT AMBIENT TEMP
CONTAINER CHARACTERISTICS
CONTAINER TYPE
TANK DIAMETER
TOTAL WEIGHT OF CONTENTS
LIQUID HEIGHT IN CONTAINER
DISCHARGE HOLE DIAMETER
DISCHARGE COEFFICIENT OF HOLE
TEMP OF CONTAINER CONTENTS
TANK CONTENTS DURING FIREBALL
ENVIRONMENTAL/LOCATION CHARACTERISTICS
AMBIENT TEMPERATURE - 68
WIND VELOCITY - 3.4
LIQUID CONFINEMENT AREA - NONE
aecrees
Vertical
13.046
156095
20
8.5
.62
66
156095
cylinder
feet
Ibs
fee-
inch ics)
decrees
Ibs
r
degrees F
nroh
KEY RESULTS PROVIDED BY USER INSTEAD OF BY EVALUATION METHODS
NONE OBSERVED
KEY RESULTS OVERRIDDEN BY USER AT SOME POINT AFTER COMPUTATION
NONE OBSERVED
-------
HAZARDOUS MATERIAL = PCS/toluene
ADDRESS \ LOCATION - WTI, East Liverpool, OH
DATE OF ASSESSMENT = June 5, 1995
NAME OF DISK FILE = SC2TYF.ASF
** SCENARIO DESCRIPTION
WTI Accident Analysis, Scenario 2 (typical)
Four drums rupture indoors
200 gallon spill and fire
******* DISCHARGE RATE/DURATION ESTIMATES
Liquid discharge from nonpressurized container
Average discharge rate « 156.5 Ibs/mir.
Duration of discharge - 9.99 minutes
Amount discharged « 1561 Ibs
State o_f material « Liquid
******* LIQUID POOL SIZE ESTIMATES
Evaporating pool area - 812 ft2
Burning pool area - 811.2 ft2
Note: Pool is assumed to ignite immediately upon initia-
tion of discharge.1
******* poOL FIRE HAZARD ESTIMATION RESULTS
Burning pool radius - 16.1 feet
Flame height - 52 feet
Fatality zone radius - 42 feet
Injury zone radius - 60 feet
FIREBALL HAZARD RESULTS
Max fireball diameter - 186 feet
Maximum fireball height » 305 feet
Fireball duration - 7.7 seconds
Fatality zone radius - 93 feet
Injury zone radius -208 feet
Note should read "Pool is assumed to ignite after pool
achieves maximum size." This is due to a scrambled flag in
the program's reportable module. This was^verifed by the
company which wrote the program, Hazmat America Inc.
-------
INPUT PARAMETER SUMMARY
PHYSIOCHEMICAL PROPERTIES OF MATERIAL
NORMAL BOILING POINT = 233 decrees -
MOLECULAR WEIGHT « 98.68
LIQUID SPECIFIC GRAVITY « .94
VAPOR PRES AT AMBIENT TEMP = .409 psia
* 21.13 mrr. Kg
CONTAINER CHARACTERISTICS
CONTAINER TYPE « Vertical cylinder
TANK DIAMETER > 3.53 feet
TOTAL WEIGHT OF CONTENTS - 1561 Ibs
LIQUID HEIGHT IN CONTAINER . » 2.8 feet
DISCHARGE HOLE DIAMETER . 1.42 inch(es)
DISCHARGE COEFFICIENT OF HOLE - .62
TEMP OF CONTAINER CONTENTS - 68 degrees F
TANK CONTENTS DURING FIREBALL - 1561 Ibs
ENVIRONMENTAL/LOCATION CHARACTERISTICS
AMBIENT TEMPERATURE « 68 degrees F
WIND VELOCITY - 3.4 mph
LIQUID CONFINEMENT AREA » NONE
KEY RESULTS PROVIDED BY USER INSTEAD OF BY EVALUATION METHODS
NONE OBSERVED
KEY RESULTS OVERRIDDEN BY USER AT SOME POINT AFTER COMPUTATION
NONE OBSERVED
-------
HAZARDOUS MATERIAL
ADDRESS \ LOCATION
DATE OF ASSESSMENT
NAME OF DISK FILE
« PCE/toluene
- WTI, East Liverpool, OH
= June 5, 1995
* SC5CON.ASF
SCENARIO DESCRIPTION
WTI Accident Analysis, Scenario #5 (conservative)
Off-site tanker truck accident
5,000 gallon spill and fire
DISCHARGE RATE/DURATION ESTIMATES
Liquid discharge from nonpressurized container
Average discharge rate = 3854.3
Duration of discharge » 10.2
Amount discharged * 39024
State of material « Liquid
LIQUID POOL SIZE ESTIMAi"ES
Evaporating pool area » 7907
Burning pool area * 7907
Ibs/min
minutes
Ibs
ft2
ft2
Note: Pool is assumed to ignite after pool achieves max-
imum size.
******
* POOL FIRE HAZARD ESTIMATION RESULTS
Burning pool radius - 50.2
Flame height « 114
Fatality zone radius » 131
Injury zone radius - 187
* FIREBALL HAZARD RESULTS
Max fireball diameter « 541
Maximum fireball height « 889
Fireball duration 13.1
Fatality zone radius - 552
Injury zone radius « 1106
feet
feet
feet
feet
feet
feet
seconds
feet
feet
-------
INPUT PARAMETER SUMMARY
PHYSIOCHEMICAL PROPERTIES OF MATERIAL
NORMAL BOILING POINT
MOLECULAR WEIGHT
LIQUID SPECIFIC GRAVITY
VAPOR PRES AT AMBIENT TEMP
CONTAINER CHARACTERISTICS
CONTAINER TYPE
TANK DIAMETER
TANK LENGTH
TOTAL WEIGHT OF CONTENTS
LIQUID HEIGHT IN CONTAINER
DISCHARGE HOLE DIAMETER
DISCHARGE COEFFICIENT OF HOLE
TEMP OF CONTAINER CONTENTS
TANK CONTENTS DURING FIREBALL
233
98 .68
.94
.409
21.13
aecrrees F
psia
mrr. He
Horizontal cylinder
4.2
48.3
39024
4.2
5.8
.62
66
39024
ENVIRONMENTAL/LOCATION CHARACTERISTICS
AMBIENT TEMPERATURE . 68
WIND VELOCITY » 3.4
LIQUID CONFINEMENT AREA . NONE
feec
feet
Ibs
feet
inch(es!
degrees F
Ibs
degrees F
tnph
KEY RESULTS PROVIDED BY USER INSTEAD OF BY EVALUATION METHODS
NONE OBSERVED
KEY RESULTS OVERRIDDEN BY USER AT SOME POINT AFTER COMPUTATION
NONE OBSERVED
-------
HAZARDOUS MATERIAL - PCE/tcluene
ATDRZSS \ LOCATION - WTI, East Liverpool, OK
DATE CF ASSESSMENT = June 5, 199b
NAME OF
* SCENARIO DESCRIPTION
WTI Accident Analysis, Scenario 5 (typical)
Off-site tanker truck accident
100 aallcn snill and fire
.*,,«. DISCHARGE RATE/DURATION ESTIMATES
Liquid discharge from ncnpressurized container
Average discharge rate « 78.4 Ibs/rr.in
Duration of discharge « 10 minutes
Amount discharged * 784 Ibs
State of material « Liquid
Note: Duration of discharge was intentionally shortened
by user to account for response to spill. Computed
duration was originally 498.1 minutes.
> LIQUID POOL SIZE ESTIMATES
Evaporating pool area « 408 ft2
Burning pool area - 407.4 ft2
Note: Pool is assumed to ignite immediately upon initia-
tion of discharge.^
POOL FIRE HAZARD ESTIMATION RESULTS
Burning pool radius « 11.4 feet
Flame height « 41 feet
Fatality zone radius « 30 feet
Injury zone radius 43 feet
FIREBALL HAZARD RESULTS
Max fireball diameter - 148 feet
Maximum fireball height '242 feet
Fireball duration - £.8 seconds
Fatality zone radius - 74 feet
Injury zone radius - 145 feet
1 Note should read "Pool is assumed to ignite after pool
achieves maximum size." This is due to a scrambled flag in
the program's reportable module. This vwys verifed by the
company which wrote the program, Hazmat America Inc.
-------
iNPir: PARAMETER SUMMARY
PHYSIOCHEMICAL PROPERTIES OF MATERIAL
NORMAL BOILING POINT
MOLECULAR WEIGHT
LIQUID SPECIFIC GRAVITY
VAPOR PRES AT AMBIENT TEMP
233
98.68
.94
.409
21.13
CONTAINER CHARACTERISTICS
CONTAINER TYPE
TANK DIAMETER
TANK LENGTH
TOTAL WEIGHT OF CONTENTS
LIQUID HEIGHT IN CONTAINER
DISCHARGE HOLE DIAMETER
DISCHARGE COEFFICIENT OF HOLE -
TEMP OF CONTAINER CONTENTS
TANK CONTENTS DURING FIREBALL
ENVIRONMENTAL/LOCATION CHARACTERISTICS
AMBIENT TEMPERATURE - 68
WIND VELOCITY - 3.4
LIQUID CONFINEMENT AREA - NONE
s
m
*
m
m
m
m
m
Horizontal
4.2
48.3
39024
4.2
.827
.62
68
784
degrees F
sia
cylinder
feet
feet
Ibs
feet
inch(es)
degrees F
Ibs
degrees F
mph
KEY RESULTS PROVIDED BY U£2R INSTEAD OF BY EVALUATION METHODS
NONE OBSERVED
KEY RESULTS OVERRIDDEN BY USER AT SOME POINT AFTER COMPUTATION
NONE OBSERVED
-------
2. Fire immediately upon the spill
-------
.HAZARDOUS MATERIAL * PCE/toluene
ADDRESS \ LOCATION = WTI, East Liverpool, OH
DATE OF ASSESSMENT = June 5, 1955
NAME OF DISK FILE = SC2CONP.ASF
SCENARIO DESCRIPTION
WTI Accident Analysis, Scenario 2 (conservative:
Storage tank rupture in organic waste tank farrr.
20,000 gallon spill and fire
.»*** DISCHARGE RATE/DURATION ESTIMATES
Liquid discharge from nonpressurized container
Average discharge rate - 15352 Ibs/mir.
Duration of discharge « 10.2 minutes
Amount discharged « 156095 Ibs
State of "material » Liquid
»**** LIQUID POOL SIZE ESTIMATES
Evaporating pool area - 1940 ft2
Burning pool area - 1940 ft2
Note: Pool is assumed to ignite after pool achieves max-
imum size. *
POOL FIRE HAZARD ESTIMATION RESULTS
Burning pool radius - 24.9 feet
Flame height - 70 feet
Fatality zone radius - 65 feet
Injury zone radius - 93 feet
FIREBALL HAZARD RESULTS
Max fireball diameter - 859 feet
Maximum fireball height - 1411 feet
Fireball duration - 16.5 seconds
Fatality zone radius - 1199 feet
Injury zone radius - 2274 feet
Note should read "Pool is assumed to ignite immediately
upon initiation of discharge." This is due to a scrambled
flag in the program's reportable module. This was verifed
by the company which wrote the program, Hazmat America Inc.
-------
INPUT PARAMETER SUMMARY
PHYSIOCHEMICAL PROPERTIES OF MATERIAL
NORMAL BOILING POINT
MOLECULAR WEIGHT
LIQUID SPECIFIC GRAVITY
VAPOR PRES AT CONTAINER TEMP
VAPOR PRES AT AMBIENT TEMP
» 233
* 98.68
= .94
= .406
= 21.1
= .408
= 21.1
decrees F
psia
mrr Kg
psia
mrr. He
CONTAINER CHARACTERISTICS
CONTAINER TYPE
TANK DIAMETER
TOTAL WEIGHT OF CONTENTS
LIQUID HEIGHT IN CONTAINER
DISCHARGE HOLE DIAMETER
DISCHARGE COEFFICIENT OF HOLE »
TEMP OF CONTAINER CONTENTS
TANK CONTENTS DURING FIREBALL «
Vertical cylinder
13.046
156095
20
8.5
.62
68
156095
ENVIRONMENTAL/LOCATION CHARACTERISTICS
AMBIENT TEMPERATURE - 68
WIND VELOCITY - 3.4
LIQUID CONFINEMENT AREA - NONE
feet
Ibs
feet
inch(es)
degrees F
Ibs
degrees F
tnph
KEY RESULTS PROVIDED BY USER INSTEAD OF BY EVALUATION METHODS
NONE OBSERVED
KEY RESULTS OVERRIDDEN BY USER AT SOME POINT AFTER COMPUTATION
NONE OBSERVED
-------
HAZARDOUS MATERIAL
ADDRESS \ LOCATION
DATE OF ASSESSMENT
NAME OF DISK FILE
- PCI/toluene
= W7I , Ease Liverpool, OK
= June 5. 1995
- SC2TYPP.ASF
SCENARIO DESCRIPTION
WTI Accident Analysis, Scenario 2 (typical}
Four drums rupture indoors
200 gallon spill and fire
*** DISCHARGE RATE/DURATION ESTIMATES
Liquid discharge from nonpressurized container
Average discharge rate « 156.5
Duration of discharge » 9.99
Amount discharged « 1561
State of material - Liquid
LIQUID POOL SIZE ESTIMATES
Evaporating pool area » 812
Burning pool area » 227.9
Ibs/min
minutes
Ibs
ft2
ft2
Note: Pool is assumed to ignite immediately upon initia-
tion of discharge.
POOL FIRE HAZARD ESTIMATION RESULTS
Burning pool radius » 8.6
Flame height » 34
Fatality zone radius - 23
Injury zone radius - 32
FIREBALL HAZARD RESULTS
Max fireball diameter 186
Maximum fireball height 305
Fireball duration 7.7
Fatality zone radius 53
-Injury zone radius 208
feet
feet
feet
feet
feet
feet
seconds
feet
feet
-------
INPUT PARAMETER SUMMARY
PHYSIOCHEMICAL PROPERTIES OF MATERIAL
NORMAL BOILING POINT - 233 decrees F
MOLECULAR WEIGHT =98.68
LIQUID SPECIFIC GRAVITY = .94
VAPOR PRES AT AMBIENT TEMP = .409 psia
* 21.13 mrr He
CONTAINER CHARACTERISTICS
CONTAINER TYPE - Vertical cylinder
TANK DIAMETER * 3.53 feet
TOTAL WEIGHT OF CONTENTS = 1561 Ibs
LIQUID HEIGHT IN CONTAINER - 2.8 feet
DISCHARGE HOLE DIAMETER - 1.42 inchies)
DISCHARGE COEFFICIENT OF HOLE « .62
TEMP OF CONTAINER CONTENTS - 68 degrees F
TANK CONTENTS DURING FIREBALL « 1561 Ibs
ENVIRONMENTAL/LOCATION CHARACTERISTICS
AMBIENT TEMPERATURE » 68 degrees F
WIND VELOCITY - 3.4 mph
LIQUID CONFINEMENT AREA - NONE
KEY RESULTS PROVIDED BY USER INSTEAD OF BY EVALUATION METHODS
NONE OBSERVED
KEY RESULTS OVERRIDDEN BY USER AT SOME POINT AFTER COMPUTATION
NONE OBSERVED
-------
HAZARDOUS MATERIAL = PCE/toluene
ADDRESS \ LOCATION = WTI, East Liverpool, OK
DATE OF ASSESSMENT = June 5, 1995
NAME OF DISK FILE = SC5CONP.ASF
SCENARIO DESCRIPTION
WTI Accident Analysis, Scenario #5 (conservative,
Off-site tanker truck accident
5,000 gallon spill and fire
****** DISCHARGE RATE/DURATION ESTIMATES
Liquid discharge from nonpressurized container
Average discharge rate. = 3854.3 Ibs/mir.
Duration of discharge * 10.2 minutes
Amount discharged « 39024 Ibs
State"of material « Liquid
****** LIQUID POOL SIZE ESTIMATES
Evaporating pool area - 7907 ft2
Burning pool area « 5611 ft2
Note: Pool is assumed to ignite immediately upon initia-
tion of discharge.
'***** POOL FIRE HAZARD ESTIMATION RESULTS
Burning pool radius « 42.3 feet
Flame height ~ 102 feet
Fatality zone radius * lie feet
Injury zone radius « 158 feet
***** FIREBALL HAZARD RESULTS
Max fireball diameter - 541 feet
Maximum fireball height - 889 feet
Fireball duration - 13.1 seconds
Fatality zone radius - 552 feet
Injury zone radius » 1106 feet
-------
INPUT PARAMETER SUMMARY
PHYSIOCHEMICAL PROPERTIES OF MATERIAL
NORMAL BOILING POINT
MOLECULAR WEIGHT
LIQUID SPECIFIC GRAVITY
VAPOR PRES AT AMBIENT TEMP
233
98.68
.94
.409
21.13
degrees F
psia
mrr. KG
CONTAINER CHARACTERISTICS
CONTAINER TYPE
TANK DIAMETER
TANK LENGTH
TOTAL WEIGHT OF CONTENTS
LIQUID HEIGHT IN CONTAINER
DISCHARGE HOLE DIAMETER
DISCHARGE COEFFICIENT OF HOLE
TEMP OF" CONTAINER CONTENTS
TANK CONTENTS DURING FIREBALL
Horizontal cylinder
feet
feet
Ibs
feet
inchfes!
4.2
48.3
39024
4.2
5.8
.62
68
39024
ENVIRONMENTAL/LOCATION CHARACTERISTICS
AMBIENT TEMPERATURE » 68
WIND VELOCITY - 3.4
LIQUID CONFINEMENT AREA - NONE
degrees F
Ibs
degrees F
mph
KEY RESULTS PROVIDED BY USER INSTEAD OF BY EVALUATION METHODS
NONE OBSERVED
KEY RESULTS OVERRIDDEN BY USER AT SOME POINT AFTER COMPUTATION
NONE OBSERVED
-------
HAZARDOUS MATERIAL PCE/toluene
ADDRESS \ LOCATION = WTI, East Liverpool, OH
DATE OF ASSESSMENT = June 5, 1955
NAME OF DISK FILE « SC5TYPP.ASF
SCENARIO DESCRIPTION
WTI Accident Analysis, Scenario 5 (typical)
Off-site tanker truck accident
100 gallon spill and fire
DISCHARGE RATE/DURATION ESTIMATES
Liquid discharge from nonpressurized container
Average discharge rate « 78.4 Ibs/min
Duration of discharge » 10 minutes
Amount discharged » 784 Ibs
State of material ' Liquid
Note: Duration of discharge was intentionally shortened
by user to account for response to spill. Computed
duration was originally 498.1 minutes.
****** LIQUID POOL SIZE ESTIMATES
Evaporating pool area - 408 ft2
Burning pool area - 114.2 ft2
Note: Pool is assumed to ignite immediately upon initia-
tion of discharge.
POOL FIRE HAZARD ESTIMATION RESULTS
Burning pool radius - 6.1 feet
Flame height - 27 feet
Fatality zone radius « 16 feet
Injury zone radius » 23 feet
FIREBALL HAZARD RESULTS
Max fireball diameter - 148 feet
Maximum fireball height - 242 feet
Fireball duration - 6.8 seconds
Fatality zone radius - 74 feet
Injury zone radius « 145 feet
-------
INPUT PARAMETER SUMMARY
PHYSIOCHEMICAL PROPERTIES OF MATERIAL
NORMAL BOILING POINT
MOLECULAR WEIGHT
LIQUID SPECIFIC GRAVITY
VAPOR PRES AT AMBIENT TEMP
CONTAINER CHARACTERISTICS
CONTAINER TYPE
TANK DIAMETER
TANK LENGTH
TOTAL WEIGHT OF CONTENTS
LIQUID HEIGHT IN CONTAINER
DISCHARGE HOLE DIAMETER
DISCHARGE COEFFICIENT OF HOLE »
TEMP OF CONTAINER CONTENTS
TANK CONTENTS DURING FIREBALL -
233
98.66
.94
.409
21.13
decrees F
psia
mrr. He
« Horizontal cylinder
4.2
48.3
39024
4.2
.827
.62
68
784
ENVIRONMENTAL/LOCATION CHARACTERISTICS
AMBIENT TEMPERATURE « 68
WIND VELOCITY - 3.4
LIQUID CONFINEMENT AREA « NONE
feet
feet
Ibs
feet
inch(es)
degrees F
Ibs
degrees F
tnph
KEY RESULTS PROVIDED BY USER INSTEAD OF BY EVALUATION METHODS
NONE OBSERVED
KEY RESULTS OVERRIDDEN BY USER AT SOME POINT AFTER COMPUTATION
NONE OBSERVED
-------
APPENDIX VII-4
Atmospheric Dispersion Modeling
-------
CONTENTS
Page
I. ATMOSPHERIC DISPERSION MODELING 4-!
A. Model Selection 4-1
1 SLAB Model 4-1
2. ISC-COMPDEP Model 4-1
B. Meteorological Data 4-2
1. Typical Condition 4-2
2. Conservative Condition 4-3
3. Calm/Inversion Condition 4-4
C. Dispersion Categories 4-5
D. Modeling Parameters 4-7
1. SLAB 4-7
2. ISC-COMPDEP 4-13
E Results and Discussions 4-15
1 Initial Concentration 4-15
2 Ambient Temperature 4-17
3 Relative Humidity 4-17
4 Modeling Emissions Under Calm/Inversion Conditions 4-18
5. Distances to LOC and IDLH Concentrations 4-21
6. Modeling Emissions from Large Fires Using ISC-COMPDEP 4-21
7. Interpreting ISC-COMPDEP Results for 10-min Release
Scenario 4-23
8. Modeling Emissions from Typical Fires Using the ISC-COMPDEP
Output for Large Fires 4-23
9 ISC-COMPDEP Modeling Results Using 1-yr Real-time
Meteorological Data 4-24
10 Modeling Emissions from Mixing of Incompatible Waste 4-25
11. Concentration Averaging Time at Receptors . 4-26
12. Unconfmed On-site Spill 4-27
II REFERENCES 4-29
TABLES
Table 1 Stability Wind Speed Combinations Used to Determine the
Conservative Meteorological Conditions 4-31
Table 2. Summary of Input Parameters for On-Site Spill Evenr0
(Conservative Emissions) 4-32
Volume VII
Aooendix VTI-4
-------
CONTENTS
(continued)
Page
Table 3: Summary of Input Parameters for On-Site Spill Event
(Typical Emissions) 4-33
Table 4 Summary of Input Parameters for On-Site the Mixing of
Incompatible Waste Event 4-34
Table 5 Summary of Input Parameters for Off-Site Spill Events
(Conservative Emissions) 4-35
Table 6. Summary of Input Parameters for Off-Site Typical Spill Events
(Typical Emissions) 4-3t>
Table 7: Definition of Input Variables for SLAB Modeling 4-37
Table 8: Summary of Air Dispersion Modeling Results
(On-site Spill Event) 4-38
Table 9- Summary of Air Dispersion Modeling Results
(On-site Fire Event) 4.39
Table 10 Summary of Air Dispersion Modeling Results
(On-site Mixing of Incompatible Wastes Event) 4-41
Table 11 Summary of Air Dispersion Modeling Results
(Off-site Spill Event) 4-42
Table 12: Summary of Air Dispersion Modeling Results
(Off-site Fire Event) 4-43
Table 13 Average Vapor Mole Fraction Used in SLAB Modeling for
Spill Events 4-44
Table 14 Summary of ISC-COMPDEP Screening Results for the
On-Site Fire Event 4.45
Table 15 Summary of ISC-COMPDEP Screening Results for the
Off-Site Fire Event 4-50
Table 16 Phosgene and HC1 Concentrations under Conservative and Typical
Meteorological Conditions for the Conservative Unmitigated On-Site
Fire Scenarios 4-55
Table 17: Phosgene and HC1 Concentrations under Conservative and Typical
Meteorological Conditions for the Conservative Off-Site Fire
Scenarios 4-56
Table 18: Phosgene and HC1 Concentrations under Conservative and Typical
Meteorological Conditions for the Conservative Mitigated On-Site
Fire Scenarios 4-57
Table 19 Average Emission Rates and Emission Durations for the
Release Events 4-58
Table 20 Air Dispersion Modeling Results Based on Various Concentration
Averaging Time 4-59
Volume VII
Aooendix VII-4
-------
CONTENTS
(continued)
Page
FIGURES
Figure 1 Source Area for On-Site Spill 4-60
Figure 2 Location for the Off-Site Spill 4-61
Fieure 3 Rate of Evaporation of 10% Formaldehyde/90% Methanol Liquid Pool
tor the On-Site Spill Event (Conservative Emissions) 4-62
Figure 4 Rate of Evaporation of 10% Acetone/90% Toluene Liquid Pool for the
On-Site Spill Event (Conservative Emissions) 4-63
ATTACHMENTS
Attachment 1 Program AIRCONC
Attachment 2 SLAB Output for the On-Site Spill Events
Attachment 3: Summary of Exposure Concentrations at Specific Receptor Locations
Attachment 4 ISC-COMPDEP Output Using Screening Meteorological Conditions
Attachment 5 ISC-COMPDEP Output Using Real-Time Meteorological Data
Volume VII
Appendix VII-4 -iii-
-------
I. ATMOSPHERIC DISPERSION MODELING
A. Model Selection
Atmospheric dispersion modeling of accidental releases is conducted using the following
approaches:
1. SLAB Model
SLAB is a computer model that simulates the atmospheric dispersion of denser-than-
air releases (Ermak 1990). and is one of the five models used in developing guidance on
the application of refined dispersion models to hazardous/toxic air pollutant releases (U.S
EPA 1993). SLAB is capable of modeling continuous, finite duration, and instantaneous
releases from four types of sources: 1) a ground level evaporating pool; 2) an elevated
horizontal jet; 3) a stack or elevated vertical jet; and 4) a ground-based instantaneous
release. SLAB is used to model the vapor releases in the WTI Accident Analysis for the
following reasons:
SLAB is a fully-documented model released by Lawrence Livermore National
Laboratory and listed by the U.S EPA for use when modeling hazardous'toxic
air pollutant releases;
SLAB simulates both neutral and denser-than-air releases; and
SLAB allows for continuous, finite duration, and instantaneous releases as well as
automatic transition of continuous plumes into transient plumes with various
time-averaged concentrations at the receptor locations
2. ISC-COMPDEP Model
The ISC-COMPDEP air dispersion model is used for modeling steady-state or quasi-
rf<
steady-state buoyant emissions resulting from accidents involving a fire. It was previously
modified to allow the use of wind and temperature data at multiple heights derived from
Volume VII
Appendix VII-4 4-1
-------
local meteorological observations at the WTI site (See Volume IV) ISC-COMPDEP IN
selected in the Accident Analysis for modeling the off-site air concentrations resulting
from emissions from fire events based on the following considerations
The model is used in the WTI risk assessment report for modeling stack and
fugitive emissions from the facility;
The model is capable of estimating off-site air concentrations in simple and
complex terrain: and
The emissions associated with fire events can be conservatively treated as
continuous buoyant plumes due to high temperature and strong mixing with
entrained air.
B. Meteorological Data
For each identified accident event, off-site chemical concentrations in air are evaluated for
three meteorological conditions: 1) typical. 2) conservative; and 3) calm/inversion The
modeling under each of these conditions is described below.
1. Typical Condition
Typical meteorological conditions may be best represented by the real-time
meteorological data observed at the site. A hybrid hourly surface meteorological data set,
DEPBIN.MET, was developed primarily from wind data observed at the on-site
meteorological towers and supplemented with ceiling height, cloud cover, and stability
data observed at other off-site meteorological towers (i.e., the Beaver Valley Power
Station meteorological tower and the National Weather Service Station at the Greater
Pittsburgh International Airport) The preprocessed data contains 8,760 hourly entries of
wind direction, wind speed, ambient temperature, atmospheric stability, and mixing height
recorded between April 1992 and March 1993. It is used in the air quality modeling of
stack and fugitive emissions from the WTI facility (See Volume IV).
The typical meteorological condition is defined based on the most frequent single type
of stability conditions at the facility to provide a simplified approach to estimate the
average zone of impact if an accidental release were to occur. The typical meteorological
condition is defined as neutral atmosphere (Pasquill-Gifford Stability Category D) with
average wind speed (3.2 m/s). Selection of this condition to represent the typical
Volume VII
Appendix VII-4 4-2
-------
meteorological conditions for the Accident Analysis is based on the hourly surface
meteorological data in DEPBIN.MET. which indicates the following-
The most common prevailing atmospheric stability at the WTI facility is st:ibilir\
category D, which occurs approximate!) 57£ of the time, the next moM
common stability category is F/G, which occurs approximately 21 7c of the time
The average wind speed for non-calm hours at the WTI facility is 3.2 m/s
The approach of using a typical condition is relatively simple because it assumes that
meteorological conditions are independent of wind direction and terrain elevation. While
the average zone of impact for a receptor could be direction-specific and terrain-specific.
it could alternatively be estimated using real-tirre meteorological conditions and site-
specific terrain elevations, averaging only the concentrations directly downwind of the
release. However, this would require advanced ISC-COMPDEP and SLAB air modeling
involving modification of the source codes. The advanced modeling is not warranted
given the range of meteorological conditions considered for each accident event.
It should be emphasized that the radius of the zone impacted by an accidental release
is usually developed primarily for emergency planning purposes During an accident, the
wind may suddenly change direction, thus affecting different off-site populations The use
of a typical meteorological condition reflecting a combination of average stability and
wind speed is considered adequate for a screening assessment to define an average zone ot
impact during an accident, independent of the wind direction. The average zone of impact
is presented in addition to the maximum zone of impact, determined from the worst-case
meteorological conditions, to assist the emergency planner in defining the radius of the
impacted zone under different meteorological conditions regardless of the wind direction.
This is consistent with the guidance for estimating vulnerable zones to actual releases
recommended by U.S. EPA (1987), where it is suggested that emergency planners use a
circle for fixed sites or a corridor for transportation routes when estimating vulnerable
zones, as both wind speed and direction may change during the course of the release.
2. Conservative Condition
The screening meteorological conditions used in the SCREEN2 air dispersion model
(U.S. EPA 1992) are used for identifying the conservative meteorofogical condition and
for determining the maximum vapor concentration at each receptor. The 54 combinations
Volume VII
Appendix VII-4 4-3
-------
of atmospheric stability and wind speed used in SCREEN2 for determining the
conservative off-site vapor concentrations are summarized in Table 1. The conservative
meteorological condition could be different for each downwind distance depending upon
other parameters that characterize the dispersion (e.g., plume rise, receptor downwind
distance, source elevation, terrain elevation and receptor height) . By examining all 54
combinations of wind speed and atmospheric stability, the maximum exposure
concentration for each downwind distance is determined. The 54 combinations ot
atmospheric conditions are considered to be more stringent than the conservative
meteorological conditions defined by various regulatory agencies in quantifying the
maximum exposure concentration for each downwind distance. For example, the
screening meteorological conditions covers the 1.5 m/s, F-stability meteorological
conditions suggested in U.S. EPA's technical guidance for hazards analysis (U.S. EPA
1987), and the 2 m/s, F-stability meteorological conditions for ground-level and elevated
releases affected by gravity or the 2 m/s. A-stability meteorological condition tor elevated.
hieh flowrate, buoyant releases used in the Toxic Catastrophe Prevention Act (TCPA)
program in New Jersey (NJDEP 1993). An average wind speed of 3.2 m/s is used to
estimate emission rates for spill scenarios under the conservative meteorological
conditions.
3. Calm/Inversion Condition
Ground-level vapor concentrations could be significantly increased during certain
meteorological conditions under which a plume is confined in the atmospheric boundary
layer. Limited mixing occurs when the vertical mixing of a plume with ambient air is
retarded by a stable layer aloft. The worst meteorological condition for off-site receptors
is a stagnation period (calm condition with no winds) associated with a strong temperature
inversion. During this period, air contaminants would accumulate over the source area
before being dispersed downwind by light winds. In this Accident Analysis, the
calm/inversion condition is defined as a stable atmosphere with little winds (Stability F
and wind speed of 1 m/s) immediately after a long period of calm conditions.
The calm/inversion meteorological condition represents one of the most stable
conditions that may occur at the WT1 sue. This hypothetical meteorological condition
assumes that a temperature inversion with conservative meteorological conditions would
occur after calm hours. The limited mixing in the surface layer imposed by the
temperature inversion is represented by a mixing height of 100 m in the SLAB model, and
the conservative meteorological condition is represented by the combination of low wind
Volume VII
Appendix VII-4 4-4
-------
speed (1 m/s) and stable atmospheric conditions (Monin-Obuko\ length of 8 3 m.
approximately equivalent to Pasquill-Gifford atmospheric stabiht\ of E or F based on the
Liu-Durran regression equation, as referenced by Randerson 1984) It is similar to the
calm meteorological condition previously evaluated in the routine stack and fugitne
emissions study (See Volume IV). where emissions during a calm period were
accumulated and released at the end of the calm period.
It is assumed that vapor emissions due to a spill would accumulate over the spill area
during a calm period and disperse slowly downwind in a confined stable atmospheric
boundary layer. The portion of emissions accumulated during the calm period would
transport downwind, as soon as winds resume, as a puff with the strength equal to the
total emissions accumulated during the calm period. A wind speed of 1.0 m/s is used to
estimate emission rates for spill scenarios under calm/inversion meteorological conditions
The continuous emissions, if there is a sufficient quantity of released constituents for
further volatilization after the calm hours, would travel downwind as a continuous plume.
Based on a screening analysis, it was determined that the worst off-site air impact would
occur due to short duration (up to 1 hour) of calm conditions. This screening analysis is
pro\ ided in Section E 4
Because ISC-COMPDEP does not simulate instantaneous or transient releases, the
calm/inversion meteorological condition is not modeled by ISC-COMPDEP However.
the exposure concentrations under the calm/inversion condition may be qualitatively
addressed using the results obtained under the conservative non-inversion condition. A
sensitivity analysis using the CALPUFF mode! for the scenarios modeled under the
calm/inversion meteorological condition is presented in Chapter VII.
C. Dispersion Categories
The release events identified for atmospheric dispersion modeling in the Accident Analysis
are described in Appendix VII-3 Two emission conditions, conservative and typical, are
identified for each release event. The five dispersion categories identified in the accident
analysis are:
Category 1: On Site Spill
(Conservative Emissions) - Spill of 5.000 gallons of liquid organic waste from one
tanker truck at the Organic Waste Tank Farm Truck Unloading Station area within the
WTI facility (Figure 1) The liquid organic waste is assumed t6 be stored under
Volume VII
Appendix VII-4 4-5
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ambient temperature and atmospheric pressure, and contains either formaldehyde or
acetone at 100,000 ppm (10% by weight).
(Typical Emissions) - Spill of 100 gallons of the same waste at the same area
Category 2: On-site Fire
(Conservative Emissions) - Storage tank rupture and release of 20.000 gallons of
liquid organic waste over a finite time period in the Organic Waste Tank Farm.
followed by ignition of the released waste. Phosgene and HC1 are assumed to be
released as combustion products of potential concern.
(Typical Emissions.) - Spill of 200 gallons of the same waste ignites at the same area
Category 3: On-site Mixing of Incompatible Wastes
(Conservative Emissions) - Release of HC1 from the storage vessel during an accident
involving mixing of 10,000 gallons of incompatible wastes (chlorinated hydrocarbons
and mineral acids) in the storage vessel. The potential accident is assumed to occur at
the storage tank area.
(Typical Emissions) - Release of HC1 resulting from mixing of 200 gallons of
incompatible wastes, as described in Appendix VII-3.
Category 4: Off-site Tanker Truck Spill
(Conservative Emissions) - Spill of 5,000 gallons of liquid organic waste over a finite
time period from an inbound tanker truck involved in an incident on the local access
route to the WTI facility (Figure 2) The liquid organic waste is assumed to be stored
under ambient temperature and atmospheric pressure and contains either
formaldehyde or acetone at 100.000 ppm (10% by weight).
(Typical Emissions) - The same accident event as the conservative emission condition
with a 100 gallon spill.
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Appendix VII-4 4-6
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Category 5: Off-site Tanker Truck Spill With Fire
(Conservative Emissions) - Spill and subsequent ignition of 5000 gallons of liquid
organic waste over a finite time period from an inbound tanker truck involved in an
incident on the local access route. Phosgene and HC1 are assumed to be released as
combustion products of potential concern.
(Typical Emissions) - Spill of 100 gallons of liquid waste and subsequent ignition of
same at the same area.
Because it is anticipated that the on-site emergency team would be able to respond and mitigate
a spill/fire accident on-site in 10 to 60 minutes, additional evaluation of all on-site accident
events is conducted assuming the fire/emission will be terminated in 10 or 60 minutes.
SLAB is used for modeling all release events exc ;pt the fire events where strong
buoyancy plumes may impinge on elevated terrains farther away from the source areas Fire
scenarios for typical and conservative meteorological conditions are modeled using the ISC-
COMPDEP model.
D. Modeling Parameters
1. SLAB
The SLAB modeling analyses are conducted assuming dispersion would occur in a
suburban environment (as defined by the surface roughness). Tables 2 through 6 show the
input parameters used in SLAB modeling The definition of each model parameter is
presented in Table 7. Detailed descriptions of these parameters can be found in the SLAB
user's manual (Ermak 1990) and in U.S. EPA guidance on the application of refined
models (U.S. EPA 1993). Specific modeling techniques requiring further discussion are
provided below.
Source Area
The source area for the conservative on-site spill event (Dispersion Category 1) is
calculated to be 418 nr for the conservative emission condition, based on an area
of 60 ft by 75 ft at the truck unloading station. A spill volume of 5,000 gallons
is determined to be the maximum release quantity. For the typical on-site spill
volume of 100 gallons, the area is calculated to be 38 nr. The source area is
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Annendix VII-4 4-7
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represented by a square and positioned at the center of the area to the north of the
Truck Unloading Station.
Phosgene and HC1 emissions would potentially result from the on-site fire
event (Dispersion Category 2). The area of emissions is assumed to be 180 m:
(1/4 of the Organic Waste Tank Farm area) for the conservative emission
condition. The source area is therefore represented by a square of 13.5 m h>
13.5 m, located at the Organic Waste Tank Farm area. For the typical on-Mte
spill of 200 gallons, the area is calculated to be 76 nr. assuming a spill depth of
1 cm.
HC1 emissions due to mixing of incompatible wastes (Dispersion Categorx 31
are expected to be instantaneous as the chemical reactions occur. HC1 emissions
resulting from.mixing of incompatibles wastes are expected to be vented through
the vapor recovery system of the sforag° vessel and the HC1 generation rate
depends on the waste pumping rate. The duration of release (20 minutes) is
determined by the amount of time required for emptying all of the contents of the
tanker truck (5.000 gallons). For a typical spill of 200 gallons of liquid waste.
the duration is assumed to be 10 minutes and the source area is calculated to be
76 nr.
The source area for the off-site spill (Dispersion Category 4) with
conservatively high emissions is calculated to be less than the area of an
unconfmed spill calculated using a spill depth of 1 cm (U.S. EPA 1992. U.S
EPA 1987) and a spill volume of 5.000 gallons (i.e., 1,900 nr). It is assumed
that the portion of the spill which flows toward the two sides of the road will be
either absorbed by soil or collected by the storm sewage system; therefore only
the spill along the road will not be confined The source is thus represented by a
rectangular road segment of 15 m by 49 m (approximately 735 nr for the
conservative event). The width of the road (15 m) is calculated based on a
typical two-lane highway with shoulder on each side. The width of each lane or
road shoulder is assumed to be 3.65 m (12 ft) based on the standard highway
construction (Durtenhoeffer et al. 1983). The length of the source area is
determined to be the same as the characteristic length of an unconfmed spill of
the same volume (i.e.. the diameter of an unconfmed spill). For the typical
release event, (i.e., 100 gallons) the area is calculated to be 38 m2.
Phosgene and HC1 would potentially be generated due'to a pool fire. The
source area for the off-site fire events (Dispersion Category 5) is assumed to be
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Annpndiv VTT-4 4-8
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the same as Dispersion Category 4. The source will be represented b\ a
rectangular road segment of 15 m by 49 m (approximate!) 735 m:) tor the
conservative release event and 38 m: for the typical release event
Source Temperature
For non-buoyant emissions (Dispersion Categories 1. 3. and 4). the source
temperatures are set equal to the ambient temperature. For emissions associated
with fire (or potential heat release) events (Dispersion Categories 2 and 5). the
event-specific source temperature is estimated, as described in Appendix VII-3
Source Height
The source hejght for mixing of incompatible wastes under the conservative
emissions event is assumed to be the he ght of the building vent plus an additional
height due to plume rise as a result of release gas momentum.
The effective stack height. hcff. is calculated using the Holland formula with
the release temperature equal to the ambient temperature:
h = h - A/I (\\
v d
Ah = (2)
where:
Ah = plume rise (m);
vs = stack gas exit velocity (m/s);
d = stack diameter (m);
u = ambient wind speed (m/s).
The stack gas exit velocity (37 m/s) is calculated as the volumetric flow rate
divided by the cross-sectional area of the stack. Therefore,
... (37 Bi/j)(0.20 m)
A/I = = 2.3 m
(3.2 mis)
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Appendix VII-4 4-9
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and the release height is:
heff = 6.1 m ' 2.3 m = 8.4 m (4)
Sources for all spill events are assumed to be at ground level
Source Elevation
For all events, it is assumed that there is no elevation difference between the
source and the receptors. For a ground-level release, the maximum exposure-
point concentration will occur at ground level and within a short distance from
the source. Treating elevated terrain as flat terrain would result in more
conservative (or higher) exposure concentrations at the off-site receptor locations.
Receptor Locations
The SLAB model automatically computes volume concentrations at 61 downwind
locations based on the maximum downwind distance specified by the user. It
does not calculate concentrations at used-specified downwind locations because.
in the model's transient puff dispersion mode, time is the independent variable
rather than the downwind distance A FORTRAN program. AIRCONC
(Attachment A), is thus developed to linearly interpolate concentrations at
specific receptor locations using the 61 values computed by SLAB For the
conservative release events where the impacts of the emissions are expected to
extend farther downwind, the maximum downwind distance used in the SLAB
model is assigned to 20.000 m such that concentrations at 24 hypothetical
receptor locations (x = 25. 50. 100. 200, 300, 400, 500, 600, 700. 800. 900.
1,000, 1,250, 1.500. 1.750. 2.000. 2.250, 2,500, 3,000, 4.000, 5,000. 10.000,
15,000, 20,000 m) can be interpolated. To increase the resolution of the model
predictions for the typical release events, the maximum downwind distance is
reduced to 5.000 m and the hypothetical receptor locations are reduced to 21.
thus excluding the receptors beyond 5.000 m.
Volume VII
Appendix VII-4 410
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Receptor Height
All receptors are assumed to be at ground level.
Receptor Elevation
All receptors are assumed to be at the same elevation as the source.
Surface Roughness Length
The surface roughness length is a measure of the roughness of a surface over
which air is flowing. For a homogenous surface, its value is sometimes
approximated as 1/10 of the average height of the surface irregularity. When the
landscape contains any obstructions (i.e., is nonhomogeneous), an effective
roughness length must be determined.
The overall effects of increasing surf-.ce roughness are to retard the
horizontal, buoyancy-induced spreading of the plume or cloud, and to enhance
the mixing between the plume and the environment as a result of ambient air and
plume turbulence Large surface roughness values could significantly decrease
modeled concentrations. For low or ground-level releases, increasing the surface
roughness value by a factor of 10 may reduce the modeled concentrations by a
factor of 2 (Britter and McQuaid 1988).
The surface roughness length (z0) are reported to be between 100 cm and 600
cm for urban areas and between 60 cm and 80 cm for suburban medium buildings
(U.S. EPA 1985). For suburban residential dwellings, z0 is found to be
approximately 5 cm (U.S. EPA 1985). In the vicinity of grassy areas or
agricultural crop field. ;,, varies from 4 cm to 20 cm (U.S. EPA 1985. 1993)
Based on the combined surface protrusions in the vicinity of WTI (suburban
medium building, suburban residential dwellings, grass and agricultural crops). ;,
is estimated to be between 10 cm and 50 cm. Therefore, a median site-specific
value of 30 cm, as used in the ISC-COMPDEP modeling for routine emissions
(See Volume IV), is selected for the atmospheric dispersion modeling.
Concentration Averaging Time
The concentration averaging time is set to be one-half hour, which is consistent
with the derivation of the Level of Concern (LOC) and Immediately Dangerous
to Life or Health (IDLH) acute toxicity criteria used in the accident analysis
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Appendix VIM 4-11
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For instantaneous puff releases or releases with a duration of 5 minutes or
less, the peak average concentrations over time periods of up to one hour depend
not only on the averaging time but also on the ambient wind speed and the
instantaneous horizontal puff dispersion coefficient (L'.S EPA 1988) For
continuous plume releases or releases with a duration of more than 5 mmute>. the
concentration estimate follows a power relationship with the averaging time
Using a power exponent of 0.2 suggested by U.S. EPA (1988). a 15-mmute
average would be approximately 1.15 times greater than the 30-minute average
Thus, an averaging time of 30 minutes represents an averaging duration that is
consistent with derivation of the health-based reference concentrations (IDLH or
LOG values) used in this assessment, and does not significantly underestimate the
concentrations when other short duration (i.e., less than 30 minutes) acute
toxicity criteria are applied.
Time-Varying Releases
Vapor emissions associated with unconfmed spills events are expected to be time-
varying and time-limited. The emission rates are expected to decrease from their
initial large emission rates due to chemical adsorption onto soils or surfaces for
unconfmed releases, and due to the decrease of chemical content in the spilled
solution for confined releases
For unconfmed spills, vapor emissions will be retarded because of the
reduction of released constituents available for volatilization and the increased
pathways for chemical vapors to travel into the soil medium after the spills.
Time-varying emission rates are governed by chemical-specific properties
and site-specific conditions that are too complex to be incorporated in the air
dispersion analysis. The steady-state emission model discussed in Appendix VII-
3 is likely to underestimate the emission duration and overestimate the emission
rates. A pseudo steady-state approach using the steady-state model for each time
increment is developed for use in the Accident Analysis. This approach is
discussed in detail in Appendix VII-3.
Time-varying emission rates are considered only for the spill events. The
fire and mixing of incompatible waste events are assumed to have constant
emission rates.
Volume VII
Appendix VII-4 4-12
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Building Wake Effect
The presence of buildings or structures increases the intensity of atmospheric
turbulence near an emission source. As a result, chemical vapors are rapidly
mixed with large volume of air at the source, and the plume travels downwind
with wider vertical and horizontal spread and lower concentration at the plume
centerline than that for the same release without nearby buildings For a release
that is confined within a building/warehouse. chemical vapors escaping from the;
building would be significantly less than the release. The current dispersion
modeling conservatively assumes that the release is in an open area without
considering the building wake effect (caused by the nearby structures) or build inn
confinement effect on the plume dispersion and. consequently, overestimates the
maximum downwind concentrations
Relative Humidity
The mean relative humidity at the WTI site is obtained from the historical
humidity data for Pittsburgh, Pennsylvania, complied by the U.S. Department of
Commerce (U.S. DOC 1993). An annual average relative humidity of 68 5r is
used in the SLAB modeling
2. ISC-COMPDEP
The ISC-COMPDEP modeling analyses are conducted for the conservative on-site
and off-site fire events. Typical fire events are addressed using the modeling results
developed for the conservative events, discussed in the following section. Common
modeling parameters, such as source size, fire temperature, and roughness length, are the
same as those used in SLAB modeling Specific modeling parameters requiring further
discussion are provided below
Source Elevation
The elevation for the source area is obtained from the USGS topographical maps
of the region.
Receptor Locations
A radial grid of receptors, the same grid used in the incinerator stack emission
modeling, is used in ISC-COMPDEP modeling. Receptors are placed in rings at
distances of 100, 200, 300, 400. 500, 600, 700, 800, 900, 1,000, 1,250. 1.500,
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Appendix VII-4 4-13
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1.750. 2.000. 2.250. 2.500. 3.000. 4.000. 5.000. 7.500. 10.000. 15.000.
20,000, 30,000. 40.000. and 50.000 m from the source Each receptor ring
consists of 36 receptors located at 10° intervals.
Receptor Elevation
The terrain elevation for each receptor is determined from the USGS
topographical maps as the maximum terrain height located with a sector defined
as ± 5° on either side of the receptor, including the area from the receptor ring
out to the next distant receptor ring. For the analyses involving the hypothetical
conservative and typical meteorological conditions, the highest elevation among
receptors of a fixed-distance ring is selected to represent the receptor elevation of
the receptor at.that downwind distance, since the most elevated receptor would
yield the maximum concentrations for a given ring. This application implies thai
the worst receptor elevation is used in addition to the conservative meteorological
conditions in the ISC-COMPDEP dispersion analysis.
Concentration Averaging Time
The minimum concentration averaging time employed by ISC-COMPDEP is one
hour because ISC-COMPDEP is a continuous plume model which does not allou
the use of various averaging times at receptors, and because the model specifies
the duration for each meteorological observation at one hour. However.
concentrations of shorter averaging time can be estimated from the 1-hour
average using the peak to mean concentrations observed for sampling periods
from 3 minutes to approximately one-half hour. The concentration of shorter
averaging time can be obtained by (Turner 1967. U.S. EPA 1988):
c -
(5)
where, Cs
C..H,
P
Concentration averaged over ts, (ppm);
the averaging time (minutes);
the 1-hr average concentration (ppm); and
0.2 (U.S. EPA 1988).
Volume VII
Appendix VII-4
4-14
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The above equation only accounts for plume movement due to wind direction and
may not be applicable for puff or transient plume releases.
Building Wake Effect
Building wake effect is considered for the on-site fire events due to the large
storage tanks located in the potential spill area. The building wake effect is
evaluated using the U.S. EPA Building Profile Input Program. Detailed building
information of the storage tanks is provided in Attachment 4. The building wake
analysis is discussed in Volume IV.
E. Results and Discussions
Attachment 2 presents .the SLAB model output for the conservative and typical on-sne
spill of formaldehyde and methanol. Complete SLA?, model outputs are available on two 3
1/2-inch floppy diskettes or can be reproduced using the input parameters listed in Tables 2
through 6 and the public-accessible SLAB model. Attachment 3 shows the computer outputs
from AIRCONC which display the 30-minute average exposure concentrations at specific
receptor locations. Tables 8 through 12 summarize the impact distances associated with each
chemical of concern and release event. Concentration estimates and associated modeling
techniques are discussed below.
1. Initial Concentration
All release events involving low volatility liquid spills are modeled as releases of the
mixtures (instead of individual constituents) using SLAB. The SLAB outputs are
summarized as volumetric concentrations of the initial mixtures. U.S EPA's guidance on
the application of refined dispersion models for hazardous/toxic air releases suggests that
the SLAB concentration results should be adjusted to account for the chemical-specific
portion of a release by multiplying the concentration results by the fraction of the
chemical in the initial vapor-phase concentration (U.S. EPA 1993) However, it should
be noted that the emission rate from a spill will not be constant in time. Effects such as
cooling of the spill as a result of evaporation will suppress the emission rate. Chemicals
with higher evaporation potential will escape from the spill mixture faster than other
chemicals in the mixture, and will slow down as their relative liquid concentration in the
spill mixture decreases. For volatile chemicals such as formaldehyde, the initial mole
fraction in the vapor phase is much greater than the mole fraction irfthe liquid. The mole
fraction of formaldehyde in vapor phase will decrease with time because the vapor
Volume VII
Appendix VII-4 4-15
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pressure of formaldehyde will decrease in the formaldehyde-depleted mixture as time
increases. Therefore, adjusting the concentration results by multiplying the results b\ the
mole fraction of chemical in the initial vapor-phase concentration would result in
sisnificant overestimation of the total mass available in the liquid for emissions The
algorithm developed in Appendix VII-3 is used to estimate the average mole fraction ot a
chemical in vapor during an accidental release. The methodology is developed from the
principle of mass conservation and takes into consideration the fact that chemicals with
higher volatility will evaporate from the spill pool faster than chemicals with lower
volatility.
Figure 3 shows the time-dependent mass evaporation rates of formaldehyde and
methanol for a conservative on-site spill event with a wind speed of 3.2 m/s. According
to the steady-state approach, the spilled liquid will emit the chemical mixture at a constant
rate of 2.5 kg/s for approximately 6.000 seconds (1 hour and 40 minutes) at the vapor
contains approximately 80% of formaldehyde and 20% of methanol throughout the
emissions. This would result in an overestimation of formaldehyde by approximate!} 8-
fold since formaldehyde initially constitutes only 10% of the liquid waste By using the
chemical-specific time-varying emissions, the principle of mass conservation is preserved.
as seen in Figure 3, where the area under the formaldehyde emission curve (representing
the total mass of formaldehyde emitted) is 10% of the total mass available in the spilled
mixture, and the emission duration is predicted to last for approximately 3.000 seconds
(50 minutes). As shown in Figure 3. formaldehyde leaves the liquid much faster than
methanol, and the time for methanol to evaporate is actually much longer than predicted
using the steady-state emission approach due to the low volatility of methanol. Similarly.
for spills involving an acetone/toluene mixture, acetone leaves the liquid faster than
toluene due to its higher volatility Figure 4 snows the time-dependent acetone and
toluene emission rates for a conservative on-site spill event with wind speed equal to 3.2
m/s.
The average mole fraction calculated over the time period of interest for each
chemical for each accident event is used to convert the SLAB output of mixture
concentrations to the desired chemical concentrations. Table 13 summarizes the average
mole fractions used for estimating the chemical air concentrations.
Volume VII
Appendix VII-4 4-16
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2. Ambient Temperature
The ambient temperature may have significant effect on hazardous releases and ma\
have a more significant effect on vapor emissions from these releases than air dispersion
If the ambient temperature is above the boiling point of the mixture, the liquid waste max
flash rather than evaporate. In addition, increased ambient temperatures would increase
the evaporation rate of the liquid waste. The boiling points for the liquid waste examined
in this assessment are well above the room temperature or the extreme high temperature
during summer months in the area of WTI. The maximum recorded temperature for the
Pittsburgh area is 103 °F (312 K) with a monthly normal maximum of 83 °F (307 K).
based on the historical climatic data published by the U.S. DOC (1993) Hence, flashing
which can significantly increase the emission rate and alter the air dispersion
characteristics, is not expected to occur during a spill accident. The monthly normal
maximum is only approximately 5% higher than the average ambient temperature used in
the analysis (307 K vs 293 K); therefore, the effect of temperature on vapor emission and
air dispersion is not considered significant.
3. Relative Humidity
The relative humidity can affect the dynamics of elevated jet releases and alter the
plume height above the ground (U.S EPA 1993). Higher humidity will increase the
water vapor content in the initial vapor concentration and slightly increase the buoyancy
effect of the plume However, the increase in plume buoyancy is not expected to be
significant because the mole fraction of water vapor in ambient air could not exceed 07%
based on the vapor pressure of H:O. Two SLAB modeling runs are performed to examine
the impact of relative humidity on plume dispersion using identical meteorological
conditions and modeling parameters It is found that the off-site concentrations predicted
by SLAB vary insignificantly (less than 1 %) as the relative humidity increases from 0 to
100%. Hence, the effect of relative humidity on vapor emission and plume dispersion LS
considered negligible, particularly in the greater Pittsburgh area where the seasonal
humidity average varies in a relatively narrow range of 56 to 77%, with an average of
68% (U.S. DOC 1993).
Volume VII
Appendix VII-4 4-17
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4. Modeling Emissions Under Calm/Inversion Conditions
As discussed in Section II.B.3. emissions during the calm/inversion conditions are
modeled by superimposing the exposure concentration resulting from a puff release to that
from a continuous or transient plume release. In the SLAB modeling, onh the puff model
is conducted for releases that last for less than an hour For releases lasting more than an
hour, it is assumed that the release would accumulate for a maximum duration of one hour
prior to the occurrence of conservative meteorological conditions (1 m/s wind in a stable
limited mixing layer). Emission rates are calculated using a wind speed of 1 m/s to be
consistent with the meteorological condition. The total mass for the puff is calculated
iteratively for the first hour, as discussed in Appendix VII-3. An average mass
evaporated is computed for the first hour and an average emission rate is calculated for the
remaining duration. Releases resulting from fire scenarios under the calm/inversion
conditions are evaluated separately using the CA'^PUFF model. The off-site impacts due
to fire emissions under calm/inversion meteorological conditions are discussed in Chapter
VII
The duration for vapors to accumulate during the calm hours is assumed to be the
actual emission time or a maximum of 1 hour. Although the calm meteorological
condition may occur at the WTI site for several consecutive hours, one hour is selected to
represent the duration that could possibly result in the worst impact to the off-site
community (with largest impact zone) based on the following considerations:
Although the mean motion of the atmospheric current ceases (or subsides to less
than 1 m/s) during the calm hours, both lateral and vertical velocity fluctuations
(atmospheric turbulence) will continue to disperse the vapor cloud accumulated
above the spill. The atmospheric turbulence will uniformly disperse the vapor
cloud in all directions during the calm hours. The average concentration within
this cloud is expected to be high, but not as high as the concentration at the
center of an instantaneously released puff.
The average concentration in the neutrally buoyant vapor cloud during a one
hour stagnation period can be estimated using the following assumptions.
a turbulent intensity of 3% for both lateral and vertical velocity
fluctuations;
a virtual wind speed of 1 m/s in a moderately stable atmosphere for
quantifying the atmospheric turbulence; and
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Appendix VII-4 4-18
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homogeneous mixing of neutrally buoyant eases in all directions
The value of 3 % for the atmospheric turbulent intensity has been referenced
as a typical value (1/30) in the literature (Tennekes and Lumley 1972) A wind
speed of 1 m/s is selected to represent the wind conditions belov, which \\ ind
measurements are generally considered "calm". The characteristic length scale
(L) developed by the cloud in one hour is calculated to be:
L,a,crai = 0.03 x 1 m/s x 3600 s
= 108 m;
Lvemcai = minimum(Llatcrai, Lmmng iaver)
= minimum (108 m. 100 m)
= 100m.
Using these characteristic length scales, the average concentration of a
stagnant vapor cloud for the acetone/toluene mixture for the conservative on-site
spill event can thus be estimated to be (acetone/toluene mixture is selected
because of the low volatility and potentially longer emission duration if not
mitigated):
C = 1674 kg/(108 m): (100 m)
= 1.44 x ID'3 kg/m3
= 594 ppm.
This value is approximately twice the concentration of 280 ppm a resident
residing approximately 100 meters directly downwind of the spill would be
exposed to in less than 2 minutes during the low wind stable condition. The size
of the vapor cloud will continue to grow as time increases, and the average
concentration within the cloud will continue to decrease since the increase in
volume outgrows the increase in emissions. Therefore, if the calm condition
persists for another hour, the average concentration within the 200 meter radius
area would be approximately 150 ppm. slightly more than the 120 ppm
concentration 200 meters downwind of the source during the stable low wind
condition.
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Appendix VII-4 4-19
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As indicated in Equation (12) of Appendix VII-3. emissions from j
liquid spill during the calm condition could be significant!)
overestimated because, without the atmospheric current, the \apors
accumulated above the liquid pool will significantly reduce the
evaporation potential of the liquid. Equation (12) of Appendix YII-3 is
not applicable to the calm condition since it predicts zero emissions from
the pool. Nevertheless. Equation (12) of Appendix VII-3 is used in
conjunction with an average wind speed at the WTI site to provide
conservative emission estimates for the calm condition defined in this
assessment. The emission rates.during calm hours are obvioush
overestimated by applying this emission model with an average wind
speed. The total emissions from the liquid pool during the calm
condition could be unrealisticaMy overestimated if the emissions are
allowed to continue for a long period of time. A reasonable cut-off time
is therefore assumed to be 1 hour.
Due to the size of the vapor cloud developed by the spill during the calm
hours (although much simplified without considering the density effect).
the emissions will be rapidly dispersed when the atmospheric current
resumes after a period of calm hours.
In addition, the initial dilution during the calm hour can not be simulated in
the SLAB model and. therefore, the accumulated vapor is released in the model
as a highly concentrated puff, which may result in unrealistic overestimation for
the off-site exposure concentration estimates, particularly when the conservative
meteorological condition is used to represent the resumed wind conditions A
long accumulation duration would result in misrepresentation of the source size in
the SLAB modeling.
While the conservative meteorological condition defines a very narrow area
(an elliptic-shape area) along the prevailing wind direction that may be impacted
by a release, the above calculation for calm conditions does not necessarily define
a smaller impact zone than the conservative meteorological condition. It simply
indicates that an area of approximately 100 m in radius will be impacted by an
average concentration of 594 ppm regardless of wind direction, which can
Volume VII
Appendix VII-4 4-20
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actually be larger than the elliptic-shape impact zone defined by the conservative
meteorological condition.
5. Distances to LOG and IDLH Concentrations
It is desirable to identify the region that could be exposed to concentrations greate:
than the LOG or IDLH values for the chemicals of concern This is handled b> Program
AIRCONC such that the maximum distance from the source area to the LOG or IDLH is
calculated. Tables 8 through 12 shew the maximum distances from the source area to the
LOG and IDLH for the release events.
6. Modeling Emissions from Conservative Fires Using ISC-COMPDEP
ISC-COMPDEP was used for modeling emissions from conservative fires based on
two assumptions
The denser-than-air toxic vapors would rapidly mix in a fire with entrained air
such that the density of the gas mixture is approximately the same as air; and
The plume would rise significantly and impact elevated receptors due to the
buoyancy flux generated by the fire.
Emissions from a fire are simulated as emissions from a stack. The flame height is
used to represent a virtual stack height of the emissions, and the area of the fire is used to
characterize the size of the virtual stack. An effective stack velocity is derived for the
emissions using the buoyancy flux calculated in Appendix VII-3 and Brigg's equation
(Briggs 1975). The modeling parameters are listed in Attachment 4. Complete ISC-
COMPDEP model outputs are available on a 3.5" floppy diskette.
a) ISC-COMPDEP Modeling Results for Conservative Meteorological Condition
The one-hour average concentrations predicted by the ISC-COMPDEP model for
each of the 54 screening meteorological conditions is presented in Table 14 for the
on-site accidental release event. The concentrations are based on a unit emission rate
(i.e., 1 g/s). The highest concentration factor of 63.4 /xg/m3 per g/s is predicted
under low wind speed stable conditions (1.0 m/s, F stability). Low wind speed
conditions result in lower plume dilution rates, and the stable atmospheric lapse rate
assumed during F stability conditions reduces the plume rise associated with the
Volume VII
Annendix VII-4 4-21
-------
buoyant source. The highest concentrations are predicted at a distance ot 800 meters
from the origin of the receptor grid, which is centered at the WTI incinerator stack
The second highest concentrations are predicted under moderate wind-speed neutral
conditions (5 m/s, D stability). In general, concentrations predicted during unstable
(daytime) conditions are much lower than the peak values predicted under stable and
neutral conditions.
Table 15 shows the predicted concentrations for the off-site accidental fire event
The highest predicted concentrations are predicted during E and F stabihn
conditions. The peak concentration factor of 218 /ig/m3 per g/s is predicted under 2.5
m/s winds with F stability. The concentrations under unstable conditions are typicalh
an order of magnitude lower than those predicted during conservative stable
conditions.
b) ISC-COMPDEP Modeling Results for Typical Meteorological Condition
The concentrations for the typical meteorological condition can be obtained b\
taking the average of the concentrations for the 3.0 m/s D-stability condition and the
3.5 m/s D-stability condition from Tables 14 and 15.
c) Off-Site Phosgene and HC1 Concentrations
The one-hour average concentrations predicted by the ISC-COMPDEP model
need to be convened to 30-mmutes averages for comparison with the health-related
reference concentrations. The 30-minute average concentration can be obtained by
multiplying the ISC-COMPDEP results by a factor of 1.15 using the equation
presented in Section D.2 of this appendix
(60/30)u: = 1.15
Tables 16 and 17 show the 30-minute average concentration under both
conservative and typical meteorological conditions for the on-site and off-site fire
events, respectively. The mass concentrations are converted to volumetric
concentrations and compared to the respective LOC and IDLH values. It is shown in
Table 9 that the off-site air concentrations would not exceed any LOC values with one
exception -- under the conservative meteorological condition, there will be areas
impacted by the emissions exceeding the LOC concentrations. 'Table 9 indicates areas
with concentrations potentially exceeding the LOC. Specifically, the off-site
Volume VII
Appendix VII-4 4-22
-------
concentrations at locations 675 to 1.125 m downwind of the WTI facility max exceed
the LOG concentrations during an on-site fire event. However, because the ISC-
COMPDEP model is used with the conservative receptor elevation (discussed in
Section D.2) in conjunction with the conservative meteorological conditions, a
receptor which is within 675 to 1.125 m downwind of the spill but is located on a
terrain with elevation less than the identified conservative terrain may not be impacted
by the LOG concentration or, if impacted, may have a very small impact radiu;.
For an off-site fire event, a few areas located up to 2100 m downwind of the fire
may be exposed to concentrations exceeding the LOG value under the conservative
meteorological condition As discussed above, these areas typically have high terrain
elevations and may have small impact zones.
7. Interpreting ISC-COMPDEP Results tor a 10-min Release Scenario
Under the mitigation scenario, emissions from an on-site fire are assumed to be
terminated/controlled 10 minutes after the occurrence by either the emergency response
team or any of the activated mitigation devices on-site. The 60-minute average
concentration resulting from a 10-mmute fire is estimated to be 1/6 of that resulting from
a 1-hour fire. Therefore, the 30-mmute average concentrations resulting from a 10-minute
on-site fire can be estimated from the ISC-COMPDEP results by multiplying the resuk.s
by a scaling factor of 1/6 to account for the shorter release time at the source, and by a
scaling factor of 1.15 to account for the shorter averaging time at the receptor Table 18
summarizes the estimated 30-mmute average off-site concentrations resulting from a 10-
minute on-site fire. Due to the unpredictability in the location, time, and accessibility of
an off-site fire accident, in the availability of a local emergency response team, and in the
effectiveness of the available mitigation reagents/devices, the off-site fire event is
considered to be uncontrollable for up to an hour.
Based on the 30-mmute average off-site concentrations estimated for the 10-mmute
on-site fire scenarios, no residents will be impacted with concentrations exceeding either
the LOG or IDLH values.
8. Modeling Emissions from Typical Fires Using the ISC-COMPDEP Output for
Large Fires
Because the ISC-COMPDEP results for the conservative fire events are derived based
on a unit emission rate and some physical characteristics of a large fire, the results can be
applied to the typical fire events to yield conservative concentration estimates.
Volume VII
Aooendix VII-4 4-23
-------
As indicated in Appendix VII-3. the parameters used in characterizing emissions from
a fire are the flame height, emission rate, buoyancy flux, flame temperature, and time of
burning. The exposure concentration can be easily adjusted based on the emission rate
since the exposure concentration is proportional to the emission rate The effective stack
exit velocity derived from the buoyancy flux, fire size, and Brigg's equation (Bnggs lQ"5i
for the typical fire is the same as for the large fire. The plume rise caused b\ the small
fire is somewhat less than the large fire due to lower buoyancy flux and flame height
However, the impact of this difference is not expected to be significant. The flame
temperature is the same for both large and small fires, while the time of burning (release-1
for a small fire is less than large fire.
The 30-mmute average emission rates of HC1 and phosgene for the typical fire events
are at least 20 times less than the 30-minute average emission rates for conservative fire
events, and the underestimation of using a <=ligbTlv larger plume rise for the typical fire
events is not expected to cause order-of-magnirude underestimation of the off-site
concentrations. Therefore, it is safe to say that the off-site impacts caused by typical fire
events are at least one order-of-magmtude (10 times) less than the off-site concentrations
caused by conservative fire events. It is thus concluded and shown in Tables 9 and 12.
based on the low off-site concentrations predicted for the conservative fire events and the
low emission rates calculated for the typical fire events, that the off-site impacts caused by
typical fire events will not exceed either the LOG or IDLH values for HC1 and phosgene
9. ISC-COMPDEP Modeling Results Using 1-yr Real-time Meteorological Data
The ISC-COMPDEP model is used in conjunction with one-year of site-specific
hourly surface meteorological data (DEPBIN.MET) to evaluate the results predicted by
the same model using the screening meteorological conditions. Both 1-hr and annual
average concentrations are calculated and summarized in Attachment 5.
For the on-site fire event, the grid receptors indicate that the maximum 1-hr average
concentration occurs at a distance approximately 300 m northeast of the incinerator with a
concentration coefficient of 100.3 jzg/m3 per g/s, compared to 64.4 ^g/m3 per g/s at a
distance 800 m downwind of the facility predicted with the conservative meteorological
condition. The difference is attributed to the receptor elevations used in the two analyses.
For a buoyant plume release with significant plume rise, the concentration at a receptor
close to the source is heavily affected by the terrain elevation. A polar grid system with
previously determined terrain elevations centered at the incinerator stack, available from
the routine and fugitive emission analysis (See Volume IV), is used in the ISC-COMPDEP
Volume VII
Aooendix VII-4 4-24
-------
modeling with real-time meteorological data. For the ISC-COMPDEP run with the
screening meteorological conditions, however, the grid system is relocated to the center ot
the spill and the ^ceptor elevations are redefined
Based on the use of real-time meteorological data. IDLH values are not predicted to
be exceeded for the on-site fire event. Only pocketed areas located within 1000 m
downwind of the facility are predicted by the ISC-COMPDEP run with real-time
meteorological data to exceed the LOC value for HC1. compared to an impact zone ot
approximately 1,100 m downwind of the facility predicted by the ISC-COMPDEP run
with the conservative meteorological condition. Off-site phosgene concentrations are
found to be less than the LOC value with one exception at an elevated individual receptor
where the concentration is approximately the same as the LOC value.
The annual average off-site air concentrations for the on-site fire event are also
presented in Attachment 5. These concentrations should not be compared to the off-site
concentrations predicted using the typical meteorological condition because the annual
average concentration at a specific receptor is obtained by averaging the hourly air
concentrations at the receptor regardless of the wind direction. Hence, the annual average
concentration at a receptor could be significantly less than the hourly concentration
obtained when the receptor is downwind of the source.
For the off-site fire event, the ISC-COMPDEP run with real-time meteorological daia
indicates that the maximum 1-hr average concentration occurs 1000 m west of the facilin
(or approximately 100 m west of the fire) with a concentration coefficient of 102.8 ^g/m'
per g/s. compared to 218 /ig/m3 per g/s at a distance 100 m off the fire predicted by the
ISC-COMPDEP run with the conservative meteorological conditions. The difference is
again attributed to the difference in terrain elevation used in the two analyses. The
impacted zone that may exceed the LOC value for HC1 extends from the fire to
approximately 3,000 m, east of the facility, consistent with that predicted by the
conservative meteorological conditions
10. Modeling Emissions from Mixing of Incompatible Waste
In the current SLAB modeling, HC1 releases from mixing of incompatible waste are
simulated as dense plume stack release which may have overestimated the initial slumping
of the release and resulted in higher exposure concentration estimates.
Volume VII
Appendix VII-4 4-25
-------
11. Concentration Averaging Time at Receptors
The concentration averaging time should be the appropriate averaging time for the
health and safety standard of interest For comparison with the IDLH values, the
averaging time is selected to be 30 minutes. However, it is desirable to evaluate the
averaging concentrations for periods less than 30 minutes.
For a continuous plume, the concentrations downwind of a source generall> decrease
with increasing averaging time due to the increased meandering of wind direction (Turner
1967). The decrease in concentration follows a one-fifth power law with the averaging
time for averaging periods from approximately 3 minutes to approximate!) 30 mmute.s
(Steward et al. as cited by Turner 1967). Studies also indicate the power lau exponent
could vary between 0.17 and 0.2 and the power law relationship could be applied to
averaging times up to 24 hours (Turner 1967). Based on the one-fifth power lau
relationship, a 15-minute average concentration vill be approximately 15% greater than a
30-minute average. This magnitude of concentration increase is considered relatively
insignificant and does not transfer into any meaningful increase in the development of the
zone/distance impacted by the release. Releases last for more than one hour are normally
treated as continuous plumes, and the concentration averaging time does not have any
significant impacts on the off-site air concentrations as well as the radius of impacted
zone. It is shown in Table 19 that the releases due to acetone/toluene spills can be treated
as continuous plumes based on the emission duration, and therefore the difference between
a 30-minute average and a 10-mmute average is not considered significant.
For a continuous finite-duration release, the average concentration will be reduced
from the peak concentration if the averaging time is greater than the source release time.
because the release is relatively shon and the receptor is exposed to the material for only a
fraction of the concentration averaging time For receptors located within a short distance
downwind of the source (e.g.. 1 kin downwind of the source), the exposure time is
approximately the same as the source release time. Therefore, a 10-minute average
concentration could be 3 times higher than a 30-minute average concentration if the
release duration is only 10 minutes and the receptor is located close to the release.
Accordingly, the distance, based on the 10-minute average concentration, to the IDLH
value will be greater than that defined by the 30-minute average concentration. Table 20
shows the distances to IDLH and LOG values for two emission scenarios. The averaging
time is set to be the same as the release duration. It is observed from Table 20 that the
maximum distance to the LOG value for formaldehyde increases by 2.5-fold (from 100 m
to 240 m downwind) when the averaging time decreases from 30 minutes (1800 seconds)
Volume VII
Appendix VII-4 4-26
-------
to approximately 11.5 minutes (680 seconds). However, the cloud duration increases as
the cloud moves farther away from the spill. Therefore a receptor located 1.000 m
downwind of a 10 minute release would be exposed to the cloud for approximate!) twice
the duration of the release (longer than the release time). The difference in concentration
caused by the averaging time for such a receptor becomes less significant than that for a
receptor located nearby the release Table 20 shows that the distance to either the LOC or
IDLH value increases by less than 50% for the receptors farther away from the spill
If the release is instantaneous or very short, it is difficult to estimate the cloud length
and cloud duration (Ermak 1990). A comparison of the concentration averaging time and
the cloud duration can only be made by additional dispersion modeling. It is found from
the SLAB modeling that the cloud duration for a puff release (under the calm/inversion
condition) is 306 seconds near the source. As the cloud moves farther downwind the
cloud duration is expected to increase. A receptor located at least 1.000 m downwind of
the release would be exposed to the elongated cloud for a period much greater than 306
seconds. Therefore, the maximum distance that already extends to 10 km from the release
is not expected to increase significantly if the concentration averaging time is decreased
from 30 minutes to 10 or less minutes.
12. Unconfined On-site Spill
The size of the on-site spill event dictates the zone that could be impacted by the
release. The larger the source area, the higher the downwind concentration will be This
could happen if a spill occurs at on-site areas outside the berms. The source area for such
an unconfined release would be approximately 4.5 times greater than the area confined by
the berms, based on the assumption that the spill will form a liquid pool of 1 cm in depth.
A sensitivity analysis is performed to examine the distance to the IDLH value for the on-
site spill event.
For the formaldehyde/methanol spill, the distance to the IDLH value increases
slightly for the unmitigated release Under the typical meteorological condition, the
distance to the LOC value increases from 1.360 m (for the confined release) to 1.500 m.
and from 870 m to 980 m for the IDLH value. Under the conservative meteorological
condition, the distance increases from 8,240 m to 8,400 m for LOC, and from 4.870 m to
5,000 m for IDLH. If the release were to be put out within 10 minutes after the spill
under the typical meteorological condition, the distance to the LOC value would be 1.500
m, or 980 m to the IDLH value. Under the conservative meteorological condition, the
Volume VII
Appendix VII-4 4-27
-------
distance to the LOG concentration would be 8400 m. or 5000 m to the IDLH
concentration. The slight increase is due to the following two facts:
The off-site concentration increases as the source area increases, and
For the same concentration averaging time at the receptor, the off-site
concentration decreases as the emission duration decreases
For the acetone/toluene spill, the distance to either the IDLH concentration or the
LOG concentration is less than 25 m, measured from the source area, for both typical and
conservative meteorological conditions.
Volume VII
Annpndix VII-4 4-28
-------
II. REFERENCES
Briggs, G.A. 1975. Plume rise predictions. In Lectures on air pollution and environmental
impact analyses. American Meteorological Society.
Britter. R.E., and J. McQuaid. 1988. Workbook on the dispersion of dense gases. HSE
Contract Research Report No 17/1988. Health and Safety Executive, Sheffield. England
Duttenhoeffer, R. et al. 1983. Highway Engineering, in Standard Handbook for Civil
Engineers, ed. by F.S. Merritt. McGraw-Hill Book Company, New York. NY.
Ermak, D.L. 1990. User's manual for the SLAB model, an atmospheric dispersion model for
denser-than-air releases, Lawrence Livermore National Laboratory UCRL-MA-105607.
New Jersey Department of Environmental Protection (NJDEP). 1993. Toxic catastrophe
prevention act program. N.J.A.C. 7:31-3.9
Randerson, D. 1984. Atmospheric boundary layer in Atmospheric science and power
production, ed. by D. Randerson, United Sates Department of Energy. DOE/TIC-27601.
Washington, D.C.
Turner, D.B. 1967. Workbook of Atmospheric Dispersion Estimates. U.S. Department of
Health, Education, and Welfare, Publication No. 999-A1-26. Cincinnati, Ohio.
Tennekes, H. and Lumley, J.L. 1972 A first course in Turbulence, MIT Press. Cambridge.
Mass.
United States Department of Commerce (U.S. DOC). 1993. Statistical Abstract of the United
States: 1993 (113th Ed.). U.S. Bureau of the Census. Washington, D.C.
United States Environmental Protection Agency (U.S. EPA). Office of Health and
Environmental Assessment. 1985. Rapid assessment of exposure to paniculate emissions
from surface contamination sites. Washington. D.C. U.S. EPA/600/8-85/002.
U.S. Environmental Protection Agency (U.S.EPA), Management Agency (FEMA), and
United States Department of Transportation (USDOT). 1987. Technical guidance for
hazards analysis: (NTIS PB93-206910). December.
Volume VII
Appendix VII-4
-------
United States Environmental Protection Agency (U.S. EPA). 1988. Office of Air Qualit}
Planning and Standards. A workbook of screening techniques of assessing impacts of toxic
air pollutants. U.S. EPA-450/4-88-009. Research Triangle Park, NC. September.
United States Environmental Protection Agency (U.S. EPA). 1992. Office of Air Quahn
Planning and Standards. Workbook of screening techniques for assessing impacts in toxu
air pollutants (Revised). U.S. EPA-454/R-92-024. Research Triangle Park. NC Ma>
United States Environmental Protection Agency (U.S. EPA). 1993. Office of Air Quahn
Planning and Standards. Guidance on the application of refined dispersion models for
hazardous/toxic air releases. U.S. EPA-454/R-93-002. Research Triangle Park. NC
May.
Volume VII
Appendix VII-4 4-30
-------
TABLE 1
Stability Wind Speed Combinations Used
to Determine the Conservative Meteorological Conditions
Atmospheric
Stability
Categories
A
B
C
D
E
F
Wind Speed (m/s)
1
*
*
*
*
*
*
1.5
*
*
*
*
*
*
2
*
*
*
*
*
*
2.5
*
*
*
*
*
3
*
*
*
*
*
*
3.5
*
*
*
*
*
4
*
*
*
*
*
4.5
*
*
*
*
5
*
*
*
*
8
*
#
10
*
*
15
*
20
-
Note:
* It is only necessary to consider the stability-wind speed conditions marked with an asterisk.
Volume VII
Appendix VII-4
4-31
-------
TABLE 2
Summary of Input Parameters for On-Site Spill Event (Conservative Emissions)
Run No.:
1
2
3
4
5a2
Sb1
6
7
8
9
10
llaj
lib3
12
lodeling Parameter*
IDSPL
NCALC
WMS
CPS
TBP
CMEDO
DHE
CPSL
RHOSL
SPB
SPC
TS
QS
AS
TSD
QTIS
HS
TAV
XFFM
Met.
Condition
1
1
0.03188
909.8
309.4
0
1070000
2716
793.7
-1
0
293
1.33
418
1800
0
0
1800
20000
Typical
1
1
0.03188
909.8
309.4
0
1070000
2716
793.7
-1
0
293
1 99
418
600
0
0
1800
20000
Typical
1
1
0.03188
909.8
309.4
0
1070000
2716
793.7
-1
0
293
1.33
418
1800
0
0
1800
20000
Conservative
1
1
0.03188
909.8
309.4
0
1070000
2716
793.7
-1
0
293
1.99
418
600
0
0
1800
20000
Conservative
4
1
0.03188
909.8
309.4
0
1070000
2716
793.7
-1
0
293
0
418
0
2167.7
0
1800
20000
1
1
0.03188
909.8
309.4
0
1070000
2716
793.7
-1
0
293
0.274
418
3900
0
0
1800
20000
Calm/Inversion
4
1
0.03188
909.8
309.4
0
1070000
2716
793.7
-1
0
293
0
418
0
570.6
0
1800
20000
Calm/
Inversion
1
1
0.08704
1204
367.5
0
375000
1781.5
861.3
-1
0
293
0681
418
1800
0
0
1800
20000
Typical
1
1
0.08704
1204
367.5
0
375000
1781.5
861.3
-1
0
293
0.712
418
600
0
0
1800
20000
Typical
1
1
0.08704
1204
367.5
0
375000
1781.5
861.3
-1
0
293
0.681
418
1800
0
0
1800
20000
Conservative
1
1
0.08704
1204
367.5
0
375000
1781.5
861.3
_1
0
293
0.712
418
600
0
0
1800
20000
Conservative
4
1
0.08704
1204
367.5
0
375000
1781.5
861.3
-1
0
293
0
418
0
1032.9
0
1800
20000
1
1
0.08704
1204
367.5
0
375000
1781 5
861 3
-1
0
293
0.186
418
40380
0
0
1800
2001X)
Calm/
Inversion
4
1
0.08704
1204
367.5
0
375000
1781.5
861.3
1
0
293
0
418
0
180.3
0
1800
20000
Calm/
Inversion
Jotes:
See TABLE 7 for definition
Run 5a is the puff release; Run 5h is the continuous release.
Run 1 la is the pulf release (as RUN 11.OUT in Attachment 2); Run 1 Ib is the continuous release (as RUNA1.OUT in Attachment 2).
olume VII
ppendix VII-4
4-32
-------
Modeling Para
IDSPL
NCALC
WMS
CPS
TBP
CMEDO
DHE
CPSL
RHOSL
SPB
SPC
TS
QS
AS
TSD
QTIS
HS
TAV
XFFM
Met.
Condition
meter1
1
1
0.03188
909.8
309.4
0
1070000
2716
793.7
-1
0
293
0.094
37.9
680
0
0
1800
5000
Typical
1
1
0.03188
909.8
309.4
0
1070000
2716
793.7
-1
0
293
0.10
37.9
600
0
0
1800
5000
Typical
TABLE 3
Summary of Input Parameters for On-Site Spill Event (Typical Emissions)
i
i
0.03188
909.8
309.4
0
1070000
2716
793.7
-1
0
293
0.094
37.9
680
0
0
1800
5000
Conservative
16
1
1
0.03188
909.8
309.4
0
1070000
2716
793.7
-1
0
293
0.10
37.9
600
0
0
1800
5000
Conservative
17
18
19
20
22
4
1
0.03188
909.8
309.4
0
1070000
2716
793.7
-1
0
293
0
37.9
0
64.8
0
1800
5000
Calm/
Inversion
4
1
0.03188
909.8
309.4
0
1070000
2716
793.7
-1
0
293
0
37.9
0
36.8
0
1800
5000
1
1
0.08704
1204
367.5
0
375000
1781.5
861.3
-1
0
293
0.051
37.9
1800
0
0
1800
5000
Calm/ 1
Inversion | Typical
1
1
0.08704
1204
367.5
0
375000
1781.5
861.3
i
0
293
0.06
37.9
600
0
0
1800
5000
=^=======
Typical
4otes:
See TABLE 7 for definition.
Run 23a is the puff release (as RUN23.OUT in Attachment 2); Run 23b is the continuous release (as RUNA3 OUT in
1
1
0.08704
1204
367.5
0
375000
1781.5
861.3
1
0
293
0.051
37 9
1800
0
0
1800
5000
=====
Conservative
1
1
0.08704
1204
367.5
0
375000
1781.5
861.3
-1
0
293
0.06
37.9
600
0
0
1800
5000
Conservative
Attachment 2).
4
1
0.08704
1204
367.5
0
375000
1781.5
861.3
-1
0
293
0
37.9
0
78.7
0
1800
1
1
0.08704
1204
367.5
0
375000
1781.5
861.3
-1
0
293
0015
37 9
6060
0
0
1800
5000 5000
1 "" "! '. ' .!" ^^^^
Calm/
Inversion
======2^=S==S=S==I
4
1
0.08704
1204
367.5
0
375000
1781.5
861.3
-1
0
293
0
37.9
0
15.9
0
1800
5000
_________
Calm/
Inversion
=====
olume VII
ppendix VII-4
4-33
-------
TABLE 4
Summary of Input Parameters for On-Site the Mixing of Incompatible Waste Event
Emissions | Conservative
Run No.:
49
50
51
52
53
54
Typical
55
56
57
58
59
60
Modeling Parameter1'2
IDSPL
NCALC
WMS
CPS
TBP
CMEDO
DUE
CPSL
RHOSL
SPB
SPC
TS
QS
AS
TSD
QTIS
HS
TAV
XFFM _j
Met.
Condition
3
1
0.03647
797.8
188.15
0
441500
1655.9
1187
-1
0
293
1.79
0.0324
1200
0
8.4
1800
20000
Typical
3
1
0.03647
797.8
188.15
0
441500
1655.9
1187
-1
0
293
1.79
0.0324
600
0
8.4
1800
20000
Typical
3
1
0.03647
797.8
188.15
0
441500
1655.9
1187
-1
0
293
1.79
0.0324
1200
0
8.4
1800
20000
Conservative
3
1
0.03647
797.8
188.15
0
441500
1655.9
1187
-1
0
293
1.79
0.0324
600
0
8.4
1800
20000
Conservative
4
1
0.03647
797.8
188.15
0
441500
1655.9
1187
-1
0
293
0
167.6
0
2148
8.4
1800
20000
Calm/
Inversion
4
1
0.03647
797.8
188.15
0
441500
1655.9
1187
-1
0
293
0
83.8
0
1074
8.4
1800
20000
Calm/
Inversion
1
1
0.03647
797.8
188.15
0
441500
1655.9
1187
-1
0
293
0.0714
75.7
600
0
0
1800
5000
Typical
1
1
0.03647
797.8
188.15
0
441500
1655.9
1187
-1
0
293
0.0714
75.7
600
0
0
1800
5000
Typical
1
1
0.03647
797.8
188.15
0
441500
1655.9
1187
-1
0
293
0.0714
75.7
600
0
0
1800
5000
Conservative
1
1
0.03647
797.8
188.15
0
441500
1655.9
1187
-1
0
293
0.0714
75.7
600
0
0
1800
5000
Conservative
4
1
0.03647
797.8
188.15
0
441500
1655.9
1187
-1
0
293
0
75.7
0
42.84
0
1800
5000
Inversion/
Calm
4
1
0.03647
797.8
188 15
0
441500
1655 9
1187
-1
0
293
0
757
0
42.84
0
1800
5000
Inversion/
Calm
Notes:
1 Properties of HCI.
2 See TABLE 7 for definition.
olume VII
ppendix VII-4
4-34
-------
TABLE 5
Summary of Input Parameters for Off-site Spill Events (Conservative Emissions)
Run No.:
61
62
63a2
63b2
64
Modeling Parameter1
IDSPL
NCALC
WMS
CPS
TBP
CMEDO
DHE
CPSL
RHOSL
SPB
SPC
TS
QS
AS
TSD
QTIS
HS
TAV
XFFM
Met.
Condition
1
1
0.03188
909.8
309.4
0
1070000
2716
793.7
-1
0
293
1.84
735.0
1740.0
0
0
1800
20000
Typical
1
1
0.03188
909.8
309.4
0
1070000
2716
793.7
-1
0
293
1.84
735.0
1740.0
0
0
1800
20000
Conservative
4
1
0.03188
909.8
309.4
0
1070000
2716
793.7
-1
0
293
0
735.0
0
2948.9
0
1800
20000
1
1
0.03188
909.8
309.4
0
1070000
2716
793.7
-1
0
293
0.434
735.0
660
0
0
1800
20000
Calm/Inversion
1
1
0.08704
1204
367.5
0
375000
1781.5
861.3
-1
0
293
1.14
735.0
1800
0
0
1800
20000
Typical
65
66a3
66b3
1
1
0.08704
1204
367.5
0
375000
1781.5
861.3
-1
0
293
1.14
735.0
1800
0
0
1800
20000
Conservative
4
1
0.08704
1204
367.5
0
375000
1781.5
861.3
-1
0
293
0
735.0
0.0
1743.9
0
1800
20000
1
1
0.08704
1204
367.5
0
375000
1781.5
861.3
-1
0
293
0.317
735.0
21420
0
0
1800
5000
Calm/Inversion
Notes:
1 See TABLE 7 for definition.
2 Run 63a is the puff release (as RUN63.OUT in Attachment 2); Run 63b is the continuous release (as RUNBS.Out in Attachment 2).
' Run 66a is the puff release (as RUN66.OUT in Attachment 2); Run 66b is the continuous release (as RUNA6.Out in Attachment 2).
Volume VII
Appendix VII-4
4-35
-------
TABLE 6
Summary of Input Parameters for Off-site Typical Spill Event (Typical Emissions)
Run No.:
67
68
69
70
71
72a2
72b2
Modeling Parameter1
IDSPL
NCALC
WMS
CPS
TBP
CMEDO
DHE
CPSL
RHOSL
SPB
SPC
TS
QS
AS
TSD
QTIS
HS
TAV
XFFM
1
1
0.03188
909.8
309.4
0
1070000
2716
793.7
-1
0
293
0.094
37.9
680
0
0
1800
5000
Met. Condition | Typical
1
1
0.03188
909.8
309.4
0
1070000
2716
793.7
-1
0
293
0.094
37.9
680
0
0
1800
5000
Conservative
4
1
0.03188
909.8
309.4
0
1070000
2716
793.7
-1
0
293
0
37.9
0
64.8
0
1800
5000
Calm/Inversion
1
1
0.08704
1204
367.5
0
375000
1781.5
861.3
-1
0
293
0.051
37.9
1800
0
0
1800
5000
Typical
1
1
0.08704
1204
367.5
0
375000
1781.5
861.3
-1
0
293
0.051
37.9
1800
0
0
1800
5000
Conservative
4
1
0.08704
1204
367.5
0
375000
1781.5
861.3
-1
0
293
0
37.9
0
78.6
0
1800
5000
1
1
0.8704
1204
367.5
0
375000
1781.5
861.3
-1
0
293
0.015
37.9
6060
0
0
1800
5000
Calm/Inversion
Notes:
1 See TABLE 7 for definition.
2 Run 72a is the puff release (as RUN72.OUT in Attachment 2); Run 72b is the continuous release (as RUNA7 Out in Attachment 2).
Volume VII
Apr ^dixVII-4
4-3*
-------
TABLE 7
Definition of Input Variables for SLAB Modeling
IDSPL
- NCALC
Source Properties
- WMS
- CPS
- TBP
- CMEDO
- DHE
- CPSL
- RHOSL
- SPB
- SPC
Spill Parameters
- TS
- QS
- AS
- TSD
- QTIS
- HS
Field Parameters
- TAV
- XFFM
- ZP(I)
Source Type and Numerical Substep Parameter
Spill source type
1 - evaporating pool release
2 - horizontal jet release
3 - vertical jet or stack release
4 - instantaneous or short duration evaporating pool release
Numerical substep parameter
Molecular weight of source material (kg)
Vapor heat capacity at constant pressure (J/kg-K)
Boiling point temperature (K)
Initial liquid mass fraction
Heat of vaporization (J/kg)
Liquid heat capacity (J/kg-K)
Liquid density of source material (kg/M3)
Saturation pressure constant (Default: SPB = -1.0)
Saturation pressure constant (Default: SPC = 0.0)
Temperature of source material (K)
Mass source rate (kg/S)
Source area (M2)
Continuous source duration (s)
Instantaneous source mass (kg)
Source height (M)
Concentration averaging time (s)
Maximum downwind distance (M)
Heights of concentration calculation (M); 1=1,4
Volume VII
Appendix VII-4
4-37
-------
TABLE 8
Summary of Air Dispersion Modeling Results (On-site Spill Event)
Run
No.
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
Chemical of
Concern
Formaldehyde
Acetone
Formaldehyde
Acetone
Emission
Scenario
Conservative
Conservative
Typical
Typical
Meteorological Condition
Typical
Conservative
Calm/Inversion
Typical
Conservative
Calm/Inversion
Typical
Conservative
Calm/Inversion
Typical
Conservative
Calm/Inversion
Spill Duration
Unmitigated
10 minutes
Unmitigated
10 minutes
Unmitigated
10 minutes
Unmitigated
10 minutes
Unmitigated
10 minutes
Unmitigated
10 minutes
Unmitigated
10 minutes
Unmitigated
10 minutes
Unmitigated
10 minutes
Unmitigated
10 minutes
Unmitigated
10 minutes
Unmitigated
10 minutes
LOC
(ppm)
9.6
9.6
96
9.6
9.6
9.6
1960
1960 ,
1960
1960
1960
1960
9.6
9.6
96
9.6
9.6
9.6
1960
1960
1960
1960
1960
1960
IDLH
(ppm)
19.6
19.6
19.6
19.6
19.6
19.6
2442
2442
2442
2442
2442
2442
19.6
19.6
19.6
19.6
19.6
19.6
2442
2442
2442
2442
2442
2442
Max. Dist. to
LOC (m)1
1360
1140
8240
6470
14100
7250
CIO1
<10'
< 101
< I01
< 10'
< 10'
100
I002
910
9102
1590
1430
<101
<101
<10'
<10'
<10'
< K)1
Max. Dist. to
IDLH (m)1
870
730
4870
3920
10400
4270
<10'
<10%
<101
<10%
<10'
<10'
40
40'
550
5502
1000
900
<10'
<10'
OO1
<10'
<10'
<10'
Notes:
1 All distances are measured from the property line to the east or west, across the Ohio river to the south, or from the existing railroad to the north, whichever is
closer to the spill.
: Mitigation does not decrease maximum distance.
' Distance from the edge of the source is expected to he less than 10 m.
Volume VII
Appendix VII-4
4-38
-------
TABLE 9
Summary of Air Dispersion Modeling Results (On-site Fire Event)
Run
No.
25
26
27
28
29
30
31
32
33
34
35
36
Chemical of
Concern
UC1
Phosgene
Emission Scenario
Conservative
Conservative-
Meteorological
Condition
Typical
Conservative
Calm/Inversion
Typical
Conservative
Calm/lmersion
Emission
Duration
Unmitigated
10 minutes
Unmitigated
10 minutes
Unmitigated
10 minutes
Unmitigated
10 minutes
Unmitigated
10 minutes
Unmitigated
10 minutes
LOC
(ppm)
9.9
9.9
9.9
9.9
9.9 '
9.9
0.2
0.2
0.2
0.2
0.2
0.2
IDLH
(ppm)
49 1
49.1
49.1
49 1
49 1
49.1
2
2
2
2
2
2
Max. Dist. to
LOC (m)1 2 '
NO
NO
675-1125
NO
NE
NE
NO
NO
NO
NO
NE
NE
Max. Dist. to
IDLH (m)' 2 '
NO
NO
NO
NO
NE
NE
NO
NO
NO
NO
NE
Nl.
Notes
1 Downwind distance from the property line to the east or west across the Ohio River to the south, or the existing railroad to the north, whichever is closer to the
location of the release. For the on-site fire, maximum downwind distance was calculated from the railroad to the north, approximately 75 m from the etlpe ol
the lire
2 NO - Do not occur.
3 NE = Not evaluated as a part of this analysis. A sensitivity analysis for this scenario was conducted and is presented in Chapter VII.
Volume VII
Appendix VII-4
4-.V)
-------
TABLE 9 (continued)
Summary of Air Dispersion Modeling Results (On-site Fire)
Run
No.
37
38
39
40
41
42
43
44
45
46
47
48
Chemical of
Concern
HCI
Phosgene
Emission Scenario
Typical
Typical
Meteorological
Condition
Typical
Conservative
Calm/Inversion
Typical
Conservative
Calm/Inversion
Emission
Duration
Unmitigated
10 minutes
Unmitigated
!0 minutes
Unmitigated
10 minutes
Unmitigated
10 minutes
Unmitigated
10 minutes
Unmitigated
10 minutes
LOC
(pprn)
9.9
99
99
9.9
99 ,
9.9
02
0 2
0 2
0.2
0.2
02
IDLII
(ppm)
49 1
49.1
49.1
49.1
49.1
49.1
2
2
2
2
2
2
Max. Dist. to
LOC (ni)1-2-'
NO
NO
NO
NO
NE
NE
NO
NO
NO
NO
NE
NE
Max. Dist. to
L IDLH (m)1-1-1
NO
NO
NO
NO
NE
NE
NO
NO
NO
NO
NE
NE
Note-,
' Downwind distance from the property line to the east or west across the Ohio River to the south, or the existing railroad to the north, whichever is closer to the
location of the release. For the on-site fire, maximum downwind distance was calculated from the railroad to the north, approximately 75 in from the edge of
the fire.
2 NO = Do not occur.
' NE = Not evaluated as a part of this analysis. A sensitivity analysis for this scenario was conducted and is presented in Chapter VII.
Volume VII
Appendix VII-4
4-40
-------
TABLE 10
Summary of Air Dispersion Modeling Results (On-site Mixing of Incompatible Wastes Event)
Run
No.
49
50
51
52
53
54
55
356
57
58
59
60
Chemical of
Concern
IICI
MCI
Emission Scenario
Conservative
Typical
Meteorological
Condition
Typical
Conservative
Calm/Inversion
1 ypical
Conservative
Calm/Inversion
Emission
Duration
Unmitigated2
10 minutes
Unmitigated
10 minutes
Unmitigated
10 minutes
Unmitigated
10 minutes
Unmitigated
10 minutes
Unmitigated
10 minutes
LOC
(ppm)
9.9
9.9
9.9
9.9
9.9'
99
99
9.9
9.9
9.9
99
9.9
IDLH
(ppm)
49.1
49.1
49.1
49.1
49.1
49.1
49.1
49.1
49.1
49.1
49.1
49.1
Max. Dist. to
LOC (m)1
1780
1260
8790
6250
12200
9190
130
130
980
980
1700
1700
Max. Dist. to
IDLH (m)
680
470
3190
2170
4620
3380
<10'
<10'
270
270
520
520
Notes:
' All distances are measured from the property line to the east or west, across the Ohio river to the south, or from the existing railroad to the north, whichever is
closer to the spill.
2 The unmitigated releases are assumed to last for 20 minutes.
' Distance from the edge of the source is expected to be less than 10 m.
Volume VII
Appendix VII-4
4-4:
-------
TABLE 11
Summary of Air Dispersion Modeling Results (Off-site Spill Event)
Run
No.
61
62
63
64
65
66
67
68
69
70
71
72
Chemical of
Concern
Formaldehyde
Acetone
Formaldehyde
Acetone
Emission Scenario
Conservative
Conservative
Typical
Typical
Meteorological
Condition
Typical
Conservative
Calm/Inversion
Typical
Conservative
Calm/Inversion
Typical
Conservative
Calm/Inversion
Typical
Conservative
Calm/Inversion
Emission
Duration
Unmitigated
Unmitigated
Unmitigated
Unmitigated
Unmitigated
Unmitigated
Unmitigated
Unmitigated
Unmitigated
Unmitigated
Unmitigated
Unmitigated
LOC
(ppm)
9.6
9.6
9.6
1960
1960 '
1960
9.6
9.6
9.6
1960
1960
1960
IDIJI
(ppm)
19.6
19.6
19.6
2442
2442
2442
19.6
196
19.6
2442
2442
2442
Max. Hist, to
LOC (m)1
1490
8490
12400
<252
58
59
190
980
1670
-------
TABLE 12
Summary of Air Dispersion Modeling Results (Off-site Fire Event)
Run
No.
73
74
75
76
77
78
79
80
81
82
83
«4
Cherr.ical of
Concern
HCI
Phosgene
HCI
Phosgene
Emission Scenario
Conservative
Conservative
Typical
1 ypical
Meteorological
Condition
Typical
Conservative
Calm/Inversion
Typical
Conservative
Calm/Inversion
Typical
Conservative
Calm/Inversion
Typical
Conservative
Calm/Inversion
Emission
Duration
Unmitigated
Unmitigated
Unmitigated
Unmitigated
Unmitigated
Unmitigated
Unmitigated
Unmitigated
Unmitigated
Unmitigated
Unmitigated
Unmitigated
LOC
(ppm)
99
9.9
99
0.2
0 2 '
02
99
99
99
02
0 2
0 2
ID1JI
(ppm)
49.1
49.1
49.1
2
2
2
49.1
49.1
49 1
2
2
2
Max. Dist. to
LOC (in)
NO1
2100
NE
NO
1100
NE
NO
NO
NE
NO
NO
NE
Max. Dist. to
IDLH (m)
NO1
275
NE
NO
125
NE
NO
NO
NE
NO
NO
NE
Notes:
' NO = Do not occur.
2 NE = Not evaluated as a part of this analysis. A sensitivity analysis for this scenario was conducted and is presented in Chapter VII.
Volume VII
Appendix VII-4
4-43
-------
TABLE 13
Average Vapor Mole Fraction Used in SLAB Modeling for Spills Events'
Event
Runs
Chemical
of Concern
Time Required
until Chemical of
Concern Depleted2
(s)
Total Evaporation
Time for the Spill
(s)
Average Vapor Mole Fraction
Until Depleted2
For 30 Minutes
(without mitigation)
For 10 Minutes
(with mitigation)
Typical and Conservative Meteorological Conditions (wind speed = 3.2 m/s)
Conservative On-Site Spill
Conservative On-site Spill
Typical On-Site Spill
Typical On-Site Spill
Conservative Off-Site Spill
Conservative Off-Site Spill
Typical Off-Site Spill
Typical Off-Site Spill
1-4
7-10
13-16
19-22
61-62
64-65
67-68
70-71
Formaldehyde
Acetone
Formaldehyde
Acetone
Formaldehyde
Acetone
Formaldehyde
Acetone
3120
18240
680
3960
1740
10320
680
3960
24170
39720
5340
8760
13800
22560
5340
8760
0.478
0.273
0.482
0.276 ,
0.484
0.274
0.482
0.276
0.601
0557
NC
0420
NC
0 527
NC
0 420
0.742
0.585
0.512
0538
NC
NC
NC
NC
Calm/Inversion Meteorological Conditions (wind speed = ni/s)
Conservative On-Site Spill
Conservative On-site Spill
T>pical On-Site Spill
Typical On-Site Spill
Conservative Off-Site Spill
Conservative Off-Site Spill
Typical Off-Site Spill
Typical Off-Site Spill
5-6
11-12
17-18
23-24
63
66
69
72
Formaldehyde
Acetone
Formaldehyde
Acetone
Formaldehyde
Acetone
Formaldehyde
Acetone
7560
43920
1660
9660
4260
25020
1660
9660
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
0.778
0.591
0.676
0572
NC
NC
NC
NC
Notes.
1 The mole fraction used for the mixing of incompatible wastes producing MCI was 1 0 for all runs.
= Depletion defined when the liquid mass fraction in the evaporating pool reaches 0.001.
NC = Not calculated.
Volume VII
Appendix VII-4
4-44
-------
11 TABLE 14
Summary of ISC-COMPDEP Screening Results for
the On-Site Fire Event
One-hour Average Concentrations (jtg/m3)
Emission Rate (1 g/s)
X
Downwind
Distance
(m)
Mixing
Height
100
200
300
400
500
600
700
800
900
1000
1250
1500
1750
2000
2250
2500
3000
4000
5000
7500
10000
15000
20000
30000
40000
50000
Stability Class A
Wind Speed (mis)
1.000
320
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1.500
480
0.000
0.000
0.000
0001
0.023
0.157
1.037
3.763
3.500
3.626
3.115
2.532
2.129
1.837
1.615
1 441
1.185
0.875
0.693
0.456
0.344
0.243
0.190
0.135
0.107
0.089
2.000
640
0.000
0.000
0.001
0.071
0.453
1.037
2.145
4.735
3.615
2.930
1.814
1.425
1.198
1.033
0.908
0.810
0.667
0.492
0.390
0.257
0.193
0.137
0.107
0.076
0.060
0.050
2.500
800
0.000
0.000
0.011
0495
1.535
2.186
2.693
4.938
3.502
2.631
1.336
0.920
0766
0.661
0.581
0.519
0.427
0.315
0.249
0 164
0 124
0.087
0.068
0.049
0.038
0.032
3.000
960
0.000
0.000
0.045
1.257
2.700
3.021
2.839
4.766
3.239
2.336
1.108
0.666
0533
0.459
0.404
0.360
0.296
0219
0.173
0.114
0.085
0056
0042
0028
0.021
0.017
Stability Class B
Wind Speed (m/s)
1.000
320
0.000
0.000
0000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0000
0000
0000
0000
0.000
0000
0.000
0.000
0.000
0.000
0000
0.000
0000
0000
0.000
0.000
1.500
480
0.000
0.000
0.000
0.000
0000
0.000
0.000
0.912
0.716
0.800
1.076
1.274
1 338
1.356
1.340
1.272
1.172
1.002
0.830
0.580
0451
0 316
0.247
0.174
0.137
0.113
2.000
640
0.000
0.000
0.000
0.000
0.002
0.009
0.023
1.951
1.518
1.637
1.886
1.879
1.693
1 496
1.308
1.115
0.852
0.594
0.470
0.326
0 254
0.178
0 139
0.098
0.077
0.064
2.500
800
0.000
0.000
0.000
0.005
0.057
0.155
0.246
3.285
2.512
2.544
2.486
2.172
1.789
1.478
1.230
1.014
0746
0.456
0.322
0.209
0.162
0.114
0.089
0063
0049
0.041
3.000
960
0.000
0.000
0.000
0.050
0.324
0.625
0.802
4.587
3.450
3.284
2.801
2.235
1.739
1.381
1.116
0.904
0.656
0.343
0.216
0.147
0.085
0.056
0.042
0028
0.021
0.017
3.500
1120
0.000
0.000
0.000
0 164
0834
1.330
1.516
5.620
4 170
3 767
2.902
2.177
1.634
1.265
1.004
0.809
0.548
0.296
0.184
0.088
0063
0041
0031
0.021
0.015
0.012
4.000
1280
0000
0.000
0000
0 324
1 436
2.048
2 175
6 306
4 634
4.019
2.872
2064
1 513
1 152
0.897
0716
0484
0.260
0 161
0072
0048
0.032
0.024
0016
0012
0.009
4.500
1440
0000
0 000
0 00 1
0 4S»ti
I ST4
2 635
2 674
6 2-3
4 875
4 098
2 743
1 904
1 381
1 039
0807
0643
0433
0.232
0 143
0061
0 039
0 025
0019
0012
)009
)007
5.000
1600
0 000
0 (XXI
0001
0 0?(i
2 ;y;
? 052
0 000
6 Odd
4 ?(W
3 914
2 55 1
1 752
1.262
0.946
0.733
0.582
0.391
0.209
0 129
0054
003'
0 020
0015
0 0 ! 0
0008
0 006
Volume VII
Appendix VII-4
4-45
-------
TABLE 14 (continued)
Summary of ISC-COMPDEP Screening Results for
the On-Site Fire Event
One-hour Average Concentrations Oig/m3)
Emission Rate (1 g/s)
X
Downwind
Distance
(m)
Mixing
Height
100
200
300
400
500
600
700
800
900
1000
1250
1500
1750
2000
2250
2500
3000
4000
5000
7500
10000
15000
20000
30000
40000
50000
Stability Class C
Wind Speed (m/s)
1.000
320
0.000
0.000
0.000
0000
0.000
0000
0000
0000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0000
0.000
0.000
1.500
480
0.000
0.000
0.000
0.000
0.000
0000
0.000
0498
0.355
0.355
0.414
0.488
0.538
0.610
0.694
0714
0.796
0.783
0.856
0.769
0.623
0.437
0.339
0.237
0.184
0.152
2.000
640
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1.035
0733
0750
0.891
1 019
1 061
1 113
1.162
1 109
1 062
0.994
0.831
0.514
0.366
0.246
0.190
0 133
0.104
0.085
2.500
800
0.000
0.000
0.000
0.000
0.001
0.003
0.005
1 902
1.341
1.364
1.543
1 631
1 567
1 517
1 466
1.329
1.286
1.026
0.786
0433
0.275
0 161
0 122
0085
0.066
0.055
3.000
960
0.000
0.000
0.000
0.000
0.014
0.039
0.060
3068
2.159
2.144
2230
2.159
1 930
1 750
1 595
1 538
1.351
0.685
0459
0.375
0 126
0061
0042
0027
0020
0.016
3.500
1120
0.000
0.000
0.000
0.001
0055
0.158
0.239
4.394
3.092
2.972
2.822
2.524
2 130
1.839
1 729
1 598
1.008
0606
0.402
0.187
0 108
0.051
0032
0020
0015
0.012
4.000
1280
0.000
0.000
0.000
0.003
0.123
0.362
0.543
5.697
4.015
3.730
3.253
2.726
2.204
1 808
1 497
1 255
0.914
0.542
0.357
0.165
0.095
0.044
0.026
0015
0.012
0.009
4.500
1440
0.000
0.000
0.000
0.004
0.200
0.604
0.906
5.824
4.735
4.290
3.358
2.635
2.093
1.690
1.387
1.155
0.833
0.489
0.320
0.147
0.085
0.039
0.023
0.012
0.009
0.007
5.000
1600
0.000
0.000
0.000
0.006
0.271
0.833
0.000
5.879
4.765
4.274
3.267
2.518
1.975
1.580
1 287
1 067
0764
0.445
0.291
0.133
0.076
0.035
0.020
0.010
0.007
0.006
S.OOO
256H
0 000
1)000
0000
0.009
0406
0.000
0000
5.515
4.389
3 750
2604
1.884
1 417
1 101
0 878
0 7P
0 503
0.287
0 185
0084
0.048
0.022
0.013
0006
0.003
0.002
10.000
?200
0 000
o ooo
0 000
0008
0000
0000
0000
5030
3969
3.325
2.232
1 58?
1 176
0 906
0 ""14
0 584
0 408
0231
0 149
0.067
0.038
0.018
0.010
0005
0003
0002
Volume VII
Appendix VII-4
4-46
-------
TABLE 14 (continued)
Summary of ISC-COMPDEP Screening Results for
the On-Site Fire Event
One-hour Average Concentrations (/*g/m3)
Emission Rate (1 g/s)
X
Downwind
Distance
(m)
Mixing
Height
100
200
300
400
500
600
700
800
900
1000
' 1250
1500
1750
2000
2250
2500
3000
4000
5000
7500
10000
15000
20000
30000
40000
50000
Stability Class D
Wind Speed (m/s)
1.000
320
0.000
0,000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0000
0.000
0.000
0.000
0000
0.000
0000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1.500
480
0000
0.000
0.000
0.000
0.000
0.000
0000
0.359
0.244
0.223
0.213
0.209
0.196
0.202
0.225
0.220
0.274
0.287
0262
0.229
0.227
0.250
0.272
0.255
0.224
0.197
2.000
640
0.000
0000
0.000
0.000
0.000
0.000
0.000
0.673
0445
0416
0421
0431
0.411
0.433
0.491
0479
0591
0.582
0.501
0.377
0.440
0.420
0.359
0.256
0.192
0.151
2.500
800
0000
0000
0.000
0.000
0.000
0.000
0.000
1 196
0.778
0736
0.767
0794
0.757
0791
0.882
0 846
0981
0 878
0707
0.660
0.627
0.485
0.374
0.242
0.174
0.133
3.000
960
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1.987
1.281
1.217
1.270
1.297
1.214
1.236
1.330
1.244
1.288
0987
0785
0493
0.342
0 198
0.132
0.073
0.048
0.035
3.500
1120
0000
0000
0.000
0.000
0.000
0.002
0.004
3.072
1 976
1 869
1 907
1.891
1 721
1 694
1.676
1.533
1 300
0 972
0758
0459
0 312
0.177
0 117
0064
0.042
0.030
4.000
1280
0.000
0.000
0.000
0.000
0.000
0.006
0.018
3998
2 851
2.668
2.619
2.361
2.099
1.883
1.701
1 544
1.291
0943
0 722
0426
0.286
0 160
0 105
0057
0.037
0027
4.500
1440
0000
0.000
0.000
0.000
0.001
0.015
0049
4.066
3.383
3.175
2.772
2.419
2.136
1.901
1.704
1.536
1.266
0.906
0685
0.396
0.262
0.145
0.094
0.051
0.033
0.024
5.000
1600
0000
0.000
0.000
0.000
0.001
0.027
0.000
4.141
3.456
3.252
2.834
2.457
2.152
1.901
1.691
1.513
1.232
0.867
0.647
0.368
0.241
0.133
0.086
0.046
0.030
0.022
8.000
2560
0.000
0000
0.000
0.000
0.002
0.000
0.000
4503
3.772
3.509
2.901
2.392
2.001
1.697
1.458
1.266
0.982
0.650
0467
0.252
0.161
0.086
0.055
0.030
0.019
0.014
10.000
3200
0.000
0000
0.000
0.000
0000
0.000
0.000
4 566
3.809
3 483
2.766
2.219
1.817
1.515
1.284
1.103
0.842
0546
0.388
0.206
0.131
0.070
0045
0.024
0.015
0.011
15.000
4800
0 000
0 1)00
0 000
0000
0 000
0000
0000
4 288
3 535
? 115
2.305
1.774
1 410
1.150
0.957
0.811
0607
0385
0270
0 141
0.089
0047
0030
0016
0.010
0007
20.000
6400
o ooti
li OOti
o Oou
0 000
0 OOO
0 000
0 000
? 815
3 1 Ifi
2 684
1.910
1.440
1.128
0.910
0.752
0.634
0.470
0 295
0 206
0 107
0 06^
0 036
0 023
0 012
0 008
0006
Volume VII
Appendix VII-4
4-47
-------
TABLE 14 (continued)
Summary of ISC-COMPDEP Screening Results for
the On-Site Fire Event
One-hour Average Concentrations (uglm3)
Emission Rate (1 g/s)
X
Downwind
Distance
(m)
Mixing
Height
100
200
300
400
500
600
700
800
900
1000
1250
1500
1750
2000
2250
2500
3000
4000
5000
7500
10000
15000
20000
30000
40000
50000
Stability Class E
Wind Speed (m/s)
1.000
10000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
62.572
53.023
45.741
33.155
25412
20.536
16.781
13.783
11.910
8.623
5.529
4.102
2.357
1 476
0.847
0.561
0.324
0.219
0.164
1.500
10000
0.000
0.000
0.000
0.000
0.000
o.ooo
0.000
44.669
37.699
32.392
23.132
17.593
14.127
11.472
9.364
8.059
5.779
3.663
2.702
1.540
0.957
0.546
0.361
0.208
0.140
0.105
2.000
10000
0.000
0.000
0.000
0.000
0.000
0.000
0.001
34.963
29.415
25.196
17.863
13.508
10.797
8.730
7.096
6.091
4.339
2.729
2.007
1.137
0704
0.401
0.264
0.152
0.102
0.077
2.500
10000
0.000
0.000
0.000
0.000
0.000
0.000
0.002
28.866
24.223
20.698
14.589
10984
8 749
7.051
5.713
4.894
3.469
2.170
1.592
0.899
0.554
0315
0.208
0.119
0.080
0060
3.000
10000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
24.654
20.644
17.603
12.348
9.264
7.358
5.914
4.780
4.088
2.888
1.799
1.317
0.742
0456
0.259
0.170
0.098
0.066
0.049
3.500
10000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
21.557
18.017
15.336
10.715
8014
6.351
5.094
4.109
3.510
2.471
1.535
1.122
0.631
0.387
0.220
0.144
0.083
0.056
0.042
4.000
10000
0.000
0,000
0.000
0.000
0.000
0.000
0.000
19.178
16.002
13.599
9469
7.064
5.587
4.473
3.602
3.074
2.159
1.337
0.976
0.548
0.336
0.190
0.125
0.072
0.048
0.036
4.5W)
10000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
17.288
14.405
12.225
8.486
6.317
4 988
3.987
3.206
2733
1.916
1.184
0.864
0.484
0.296
0.168
0.110
0.063
0.043
0.032
5.(MKI
10000
0 000
0000
0.000
0.000
0.000
0000
0000
15 749
13 105
11 109
7 690
5 714
4 505
3 596
2.888
2460
1 721
1.061
0.774
0.433
0.265
0 150
0.098
0.056
0.038
0028
Volume VII
Appendix VII-4
4-48
-------
TABLE 14 (continued)
Summary of ISC-COMPDEP Screening Results for
the On-Site Fire Event
One-hour Average Concentrations 0*g/m3)
Emission Rate (1 g/s)
X
Downwind
Distance
-------
TABLE 15
Summary of ISC-COMPDEP Screening Results for
the Off-Site Fire Event
One-hour Average Concentrations (/ig/m3)
Emission Rate (1 g/s)
X
Downwind
Distance
(m)
Mixing
Height
100
200
300
400
500
600
700
800
900
1000
1250
1500
1750
2000
2250
2500
3000
4000
5000
7500
10000
15000
20000
30000
40000
50000
Stability Class A
Wind Speed (m/s)
1.000
320
0.819
0000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1.500
480
1.092
0.625
0.591
0.615
0.750
0.000
0.000
0.000
0.000
0.000
0000
0.000
0.000
0.000
0.000
0.000
0000
0.000
0000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.000
640
1 552
1 087
1.176
1.298
1.469
1.628
1.630
1.603
1.620
1 647
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.500
800
2275
1.845
2.109
2.282
2.375
.2.299
2.024
1.716
1 411
1.196
0.923
0.773
0.663
0.580
0.515
0.464
0.387
0.290
0.232 "
0.155
0.117
0.083
0.066
0.047
0.037
0.031
3.000
960
3.343
2.953
3.355
3.406
3.201
2.749
2.205
1.743
1.357
1 070
0.669
0538
0460
0.403
0.358
0.322
0.268
0.201
0 161
0 107
0.082
0058
0046
0.032
0.026
0021
Stability Class B
Wind Speed (m/s)
1.000
320
0738
0.000
0.000
0.000
0.000
0.000
0.000
0000
0.000
0000
0000
0.000
0.000
0.000
0.000
0000
0.000
0000
0.000
0.000
0.000
0.000
0.000
0000
0000
0.000
1.500
480
0.882
0.421
0.332
0.264
0.213
0.000
0.000
0.000
0.000
0000
0.000
0.000
0.000
0.000
0.000
0.000
0000
0.000
0.000
0.000
0.000
0.000
0000
0.000
0.000
0.000
2.000
640
1.109
0.613
0.551
0.468
0.387
0.294
0.230
0.200
0.174
0.169
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0000 .
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.500
800
1.446
0.912
0.903
0.802
0.681
0.520
0.409
0.357
0.311
0.303
0.222
0.271
0.315
0.349
0.364
0.389
0.354
0.306
0.270
0.196
0.154
0.109
0.085
0.060
0.047
0.039
3.000
960
1.926
1.352
1.429
1.297
1.106
0.842
0.660
0.574
0497
0479
0.344
0.395
0.425
0.437
0.428
0.429
0.357
0.260
0.203
0.137
0.107
0.076
0.059
0.042
0.033
0.027
3.500
1120
2.584
1.965
2.149
1.954
1.653
1.246
0.967
0.832
0712
0.676
0475
0.507
0.510
0494
0.461
0441
0.348
0.241
0.174
0.103
0.079
0.056
0.043
0.031
0.024
0.020
4.000
1280
3 458
2 771
3.057
2 748
2.282
1 698
1.302
1 104
093?
0 871
0 598
0.596
0566
0 523
0471
0436
0.333
0.223
0.156
0.083
0.061
0.043
0.033
0.024
0018
0.015
4.500
1440
4 5"79
3 ~74
4.118
3 623
2.940
2 156
1 634
1 364
1 140
1 046
0 70?
0 661
0 599
0534
0467
0421
0.319
0.207
0 142
0.071
0.049
0.034
0026
0019
0.015
0012
5. OIK)
16
-------
H TABLE 15 (continued)
Summary of ISC-COMPDEP Screening Results for
the Off-Site Fire Event
One-hour Average Concentrations (^g/m3)
Emission Rate (1 g/s)
X
Downwind
Distance
(m)
Stability Class C
Wind Speed (m/s)
1.000
Mixing 320
Height J
100
200
300
400
500
600
700
800
900
1000
1250
1500
1750
2000
2250
2500
3000
4000
5000
7500
10000
15000
20000
30000
40000
50000
0.689
0.000
0000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1.500
480
0.762
0.349
0.267
0.205
0.153
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0000
0000
0.000
0.000
0.000
0.000
2.000
640
0.871
0.456
0.395
0.323
0.246
0.16.8
0.119
0.096
0.077
0.071
0.045
0.047
0.052
0.061
0.071
0.095
0.113
0.182
0.248
0.321
0.304
0.229
0.179
0.126
0.098
0.081
2.500
800
1.023
0.609
0588
0.507
0.394
0.268
0.188
0.152
0.122
0.115
0.070
0.076
0087
0 103
0 120
0.161
0.178
0.213
0.239
0.228
0 196
0 146
0 115
0.081
0.063
0.052
3.000
960
1.229
0.823
0.868
0779
0.614
0.416
0.291
0.236
0.190
0.181
0.110
0.122
0.140
0.165
0.187
0.243
0.253
0.283
0.285
0.225
0 167
0 106
0.080
0056
0.044
0036
3.500
1120
1.500
1.115
1.260
1.160
0.922
0.624
0.434
0.353
0.284
0.272
0.164
0.183
0.208
0.238
0.262
0.324
C316
0.335
0.311
0.219
0.153
0086
0061
0.041
0.032
0.026
4.000
1280
1.850
1.501
1 781
1.663
1.326
0.894
0.621
0.504
0.405
0.388
0.233
0.257
0.283
0.314
0.333
0.393
0.378
0.368
0.322
0.210
0.141
0075
0.049
0.032
0.025
0.020
4.500
1440
2.293
1.996
2 444
2.289
1.819
1 224
0.848
0.687
0.550
0.526
0.315
0.339
0.361
0386
0.398
0.447
0.429
0.386
0.322
0.198
0.130
0.068
0043
0.025
0.019
0.016
5.000
1600
2.843
2.612
3 245
3 024
2 388
1 602
1.109
0894
0.715
0.679
0.405
0.423
0,436
0.449
0466
0.485
0.466
0.394
0317
0 187
0.120
0062
0.038
0.021
0.016
0.013
8.000
2561)
208^
5 6b5
5 495
4 605
> t ~J ">
? 108
2.591
2.132
1.681
1.520
0.903
0.785
0 747
0 708
0657
0497
0 373
0 230
0 156
0 074
0 043
0020
0012
0005
0.003
0.002
10.000
3200
1 5^t>
^ ^L)-^
5 5S 5
4
-------
TABLE 15 (continued)
Summary of ISC-COMPDEP Screening Results for
the Off-Site Fire Event
One-hour Average Concentrations (^g/m3)
Emission Rate (1 g/s)
X
Downwind
Distance
(m)
Mixing
Height
100
200
300
400
500
600
700
800
900
1000
1250
1500
1750
2000
2250
2500
3000
4000
5000
7500
10000
15000
20000
30000
40000
50000
Stability Class D
Wind Speed (m/s)
1.000
320
0.659
0.000
0.000
0.000
0.000
0000
0000
0000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1.500
480
0.692
0.313
0.240
0.183
0 133
0.000
0000
0.000
0.000
0000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.000
640
0.738
0.377
0.329
0.265
0.196
0 128
0.086
0.067
0.052
0.047
0.026
0022
0.021
0.020
0.020
0.027
0.026
0.026
0.024
0.028
0.036
0.048
0.057
0.070
0072
0.072
2.500
800
0.799
0.460
0.451
0.384
0.288
0 184
0 121
0093
0072
0.067
0.035
0.031
0029
0030
0.031
0044
0042
0045
0.043
0.049
0061
0.073
0.078
0077
0.069
0.061
3.000
960
0.877
0.567
0.618
0.551
0419
0.263
0 169
0 131
0099
0.094
0.048
0043
0.041
0043
0.046
0069
0067
0074
0.070
0080
0094
0 104
0 104
0091
0076
0.064
3.500
1120
0.976
0.703
0.843
0.780
0.601
0371
0235
0 181
0.137
0.132
0065
0.059
0.058
0.062
0.067
0.103
0.102
0.112
0.104
0 116
0 130
0 132
0 122
0098
0078
0064
4.000
1280
1.097
0875
1.139
1.087
0.844
0516
0323
0.249
0.187
0.182
0.087
0.081
0.080
0.088
0.095
0 148
0.146
0.156
0.142
0 155
0.164
0 153
0.134
0 101
0078
0.062
4.500
1440
1.251
1.091
1.520
1.485
1.159
0703
0437
0.335
0.252
0.246
0.115
0.108
0.109
0.120
0.131
0.203
0.197
0.204
0.180
0 193
0.194
0.168
0.141
0.100
0.075
0.059
5.000
1600
1.533
1.357
1.999
1.985
1.553
0.938
0.579
0444
0.332
0.327
0.151
0.143
0.144
0.159
0.173
0.266
0.254
0.252
0.216
0.228
0.218
0.178
0 144
0.098
0.072
0.056
8.000
2560
0.271
1.718
2.283
2.220
2.010
1.782
1.574
1.393
1.150
1.109
0.524
0.480
0.462
0.478
0.485
0.546
0.472
0.362
0.286
0.178
0.122
0.070
0.047
0.026
0.017
0.012
10.000
3200
0.100
1.308
2.070
2.142
2.002
1.807
1 61?
1 438
1.284
1.152
0 852
0745
0.681
0.648
0.592
0.541
0.457
0.338
0.261
0.155
0.104
0.059
0.039
0021
0014
0.010
15.000
4800
0021
0 949
1 916
2 127
2 043
1 865
1 671
1 484
1 32T
1 186
0 897
0 783
0.688
0.607
0.539
0.481
0.389
0.272
0.202
0.114
0.075
0041
0.027
0.014
0009
0007
20. (KM)
MOO
0010
0 860
1 889
2 121
2 031
1 841
1 636
1 44~
1 281
1 137
0 856
0 725
0621
0.537
0468
0412
0 326
0.222
0.162
0.089
0058
0.031
0.020
0011
0007
0 005
Volume VII
Appendix VII-4
4-52
-------
II TABLE 15 (continued)
" Summary of ISC-COMPDEP Screening Results for
the Off-Site Fire Event
One-hour Average Concentrations Otg/m3)
Emission Rate (1 g/s)
X
Downwind
Distance
(m)
Mixing
Height
= - ""
100
200
300
400
500
600
700
800
900
1000
1250
1500
1750
2000
2250
2500
3000
4000
5000
7500
10000
15000
20000
30000
40000
50000
Stability Class E
Wind Speed (m/s)
1.000
10000
9 179
5.203
9.788
14.866
17.161
14.433
11.513
11.034
9.903
11 801
7.643
0.218
5.411
5.394
5.345
7.214
5.822
4.325
3 223
1.877
1.339
0.776
0.708
0.563
0.463
0.390
1.500
10000
26.374
5.639
11.202
16.901
18.945
15.837
12.654
11.945
10.644
12.066
7 978
6424
5.503
5.293
5.062
5.655
4.508
3.059
2 327
1.369
0.894
0.524
0.351
0.205
0.140
0.105
2.000
10000
62.234
11 462
12.354
18.189
19.650
16.330
13.092
12.163
10.766
11.603
7 860
6.282
5.313
4.953
4.598
4.360
3 459
2.300
1 742
1.029
0 660
0.384
0.257
0.150
0.102
0.077
2.500
10000
12040!
22 427
15.664
18.927
19.649
16.244
13.080
11.966
10.533
10 813
7.516
5.976
5.004
4.543
4.114
3.525
2 787
1 84!
1 390
0 817
0 521
0.302
0202
0 117
0.080
0.060
3.000
10000
191 379
38.042
25.634
19.254
19.191
15.794
12.785
11.527
10.098
9.825
7069
5.603
4.655
4 131
3 644
2 960
2 333
1.533
1 155
0675
0429
0.248
0.166
0.096
0.065
0.049
3.500
10000
207 639
56.090
35.425
23.486
18.443
15.122
12.312
10.952
9.558
8.722
6.584
5.210
4.303
3.719
3.199
2.552
2.006
1.313
0987
0.575
0.364
0.211
0.140
0.081
0.055
0.041
4.000
10000
189364
72.278
39.821
25.241
17.612
14.234
11.737
10.251
8.922
7.800
6.015
4.803
3.951
3.324
2.834
2.242
1.759
1.147
0 861
0.500
0.316
0.182
0.121
0.070
0.048
0.036
4.500
10000
16967>
70 t>6l
38229
24.092
16927
13 035
10.939
9.365
8.142
7.031
5471
4.360
3.581
2.998
2.533
2000
1 566
1 018
0 763
0442
0.279
0.161
0.107
0.062
0.042
0.031
5.00(>
10000
1 > 1 ~>->(\
df> °2:
3d ro
22 830
16.031
12 312
10.096
8.634
7498
6405
5 013
3996
3 277
2 714
2 290
1 805
1 411
0 915
0 684
0 39d
0 249
0 144
0095
0055
0.037
0.028
Volume VII
Appendix VII-4
4-53
-------
TABLE 15 (continued)
Summary of ISC-COMPDEP Screening Results for
the Off-Site Fire Event
One-hour Average Concentrations (/ig/m3)
Emission Rate (1 g/s)
X
Downwind
Distance
(m)
Mixing Height
100
200
300
400
500
600
700
800
900
1000
1250
1500
1750
2000
2250
2500
3000
4000
5000
7500
10000
15000
20000
30000
40000
50000
Stability Class F
Wind Speed (m/s)
1.000
10000
17.673
10.718
22.115
32.516
34.857
28975
23.247
21.615
19.160
20.693
14.095
11.294
9.602
9.110
8.585
7.888
6.390
4.437
3.457
2.156
1 445
0886
0.624
0.378
0.267
0.204
1.500
10000
57.570
12.139
25.155
34.118
33458
27.673
22.609
20.432
18.022
16.874
12.861
10.328
8.684
7.755
6.771
5487
4.422
3.042
2.357
1.454
0.965
0.586
0.411
0.248
0.174
0.133
2.000
10000
135.075
24.989
27.031
33.357
28 702
23 681
20.081
17.400
15.311
13.365
10.651
8.663
7 248
6.162
5.285
4.230
3.395
2.320
1.790
1.097
0 723
0437
0305
0 183
0 129
0.098
2.500
10000
218.080
47.283
31.287
30.851
24.205
19946
17.023
14.618
12.847
11.078
8.861
7.221
6.027
5.057
4.329
3.451
2.761
1.877
1 444
0.880
0.577
0347
0.242
0 145
0.102
0.077
3.000
10000
193 674
71.261
41.282
27.038
20.871
17.179
14.646
12.561
11.029
9.495
7.580
6.164
5.133
4.298
3.672
2.919
2.329
1.577
1.210
0.734
0.480
0.288
0.200
0.120
0.084
0.064
3.500
10000
167.072
72.022
39.381
24.942
18.405
15 133
12.890
11.044
9.687
8 329
6.638
5.387
4.479
3.743
3.193
2.531
2.016
1.360
1.041
0.629
0.410
0.245
0.171
0 102
0.071
0.054
4.000
10000
141 859
66 840
36 889
2? 471
16 553
1? 554
1 1 534
9 873
is 653
^ 431
5 913
4 791
3 976
3.318
2.827
2 236
1.777
1.195
0914
0551
0.358
0.214
0 148
0088
0062
0047
Volume VII
Appendix VII-4
4-54
-------
|| TABLE 16
Phosgene and HCI Concentrations under Conservative and Typical Meteorological Conditions for the
Conservative Unmitigated On-Site Fire Scenarios
Downwind
Distance4
(m)
100
200
300
400
500
600
700
800
900
1000
1250
1500
1750
2000
2250
2500
3000
4000
5000
7500
10000
15000
20000
30000
40000
50000
Notes:
Phosgene em
2 HCI emissioi
3 Concentratio
4 Downwind d
The concentratio
unmitigated on-s
Concentration Factors,
Gug/m3)/(g/s)
Meteorological Condition
Conservative
0
0
0045
1.257
2.7
3.052
2.839
63414
54.02
46.921
34.352
26.604
21.724
17.9
14.796
12.892
9.424
6.233
4.733
2.827
1 826
1.088
0.753
0448
0.313
0237
ission rate = 10.6
i rate = 360 g/s.
istance is measured
ns for typical volun
te fire scenarios, a
Typical
0
0
0
0
0
0.001
0.002
2.5295
1.6285
1.543
1.5885
1 594
1.4675
1 465
1.503
1.3885
1.294
0.9795
0.7715
0476
0.327
0 1875
0 1245
0.0685
0.045
0 0325
g/s.
concentration facu
from the center ot
le unmitigated on-s
5 discussed in Appe
Phosgene'J
Concentration, (ppm)
Meteorological Condition
Conservative
0.00
000
1 33e-04
3 72e-03
7 99e-03
9.03e-03
8.40e-03
1.88e-01
1 60e-01
1.39e-01
1.02e-01
7.87e-02
6.43e-02
5.30e-02
4.38e-02
3.82e-02
2 79e-02
1 84e-02
1 40e-02
8 37e-03
5 40e-0?
3 22e-03
2.23e-03
1.33e-03
9 26e-04
7 Ole-04
0.024
^r Y 1 1 C v
Typical
000
0.00
000
000
0.00
2.96e-06
5.92e-06
7.49e-03
4.82e-03
4.57e-03
4.70e-03
4.72e-03
4.34e-03
4.34e-03
4.45e-03
4.11e-03
3.83e-03
2.90e-03
2.28e-03
1 41e-03
9 68e-04
5.55e-04
3.68e-04
2.03e-04
1.33e-04
9.62e-05
HCI: '
Concentration, (ppm)
Meteorological Condition
Conservative
0.00
000
1 _23e-02
? 43e-01
7.24e-01
8 32e-OI
7.74e-01
1.73e + 01
1.47e + 01
1.28e-f01
9.37e+00
7.25e+00
5.92e+00
4.88e + 00
4.03e + 00
3.52e-t-00
2.57e+00
1 70e + 00
1.29e + 00
771e-01
4 98e-01
2 97e-0!
2 05e-01
1.22e-01
8.53e-02
6.46e-02
Typical
0 0(i
u ou
1 I 1 II 1
t> l)U
U t)U
2 73e-04
5 45e-04
690c-01
4.44c-01
4.21e-01
4.33e-01
4.35e-01
4 OOc-01
3.99e-01
4 10e-01
3 79e-01
3 53e-01
2 67e-01
2 10e-01
1 30e-01
8 92c-02
5 lie -02
3 39e-02
1.87e-02
1.23e-02
8.86e-03
MW
the source
ite fire scenarios are estimated to be 10-fold lower than for conservative volume
ndix VIM, Section I.E. 8.
Volume VII
Appendix VII-4
4-55
-------
TABLE 17
Phosgene and HC1 Concentrations under Conservative and Typical Meteorological Conditions tor the
Conservative Off-Site Fire Scenarios
Downwind
Distance4
(m)
100
200
300
400
500
600
700
800
900
1000
1250
1500
1750
2000
2250
2500
3000
4000
5000
7500
10000
15000
20000
30000
40000
50000
Notes:
1 Phosgene e
! HC1 emissk
7 Concentrati
4 Downwind
The concentrat
scenarios, as di
Concentration Factors.
(ug/m3)/(g/s)
Meteorological Condition
Conservative
218.080
72.278
41.282
34.118
34.857
28.975
23.247
21.615
19.160
20.693
14.095
11.294
9.602
9.110
8.585
7.888
6.390
4.437
3.457
2.156
1.445
0 886
0.708
0.563
0463
0.390
Tiission rate = 43.^
?n rate = 1470 g/s.
distance is measure
ons for typical voli
scussed in Appendi
Typical
0.927
0.635
0.731
0666
0.510
0 317
0.202
0.156
0.118
0.113
0.057
0.051
0.050
0.053
0.057
0.086
0.085
0093
0087
0098
0.112
0.118
0 113
0095
0077
0.064
- g/s.
x concentration fac
d from the center ot
ime off-site fire scei
x VI1-4, Section l.E
Phosgene1 '
Concentration, (ppm)
Meteorological Condition
Conservative
2.63e+00
8 71e-01
4.98e-01
4.11e-01
4.20e-01
3 49e-01
2.80e-01
2 61e-01
2.31e-01
2.49e-01
1.70e-01
1.36e-01
1.16e-01
1 10e-01
1.03e-01
9.51e-02
7 70e-02
5.35e-02
4 17e-02
2.60e-02
1.74e-02
1.07e-02
8 53e-03
6 79e-03
5 58e-03
4 70e-03
Typical
1.12e-02
7.65e-03
8.81e-03
8.02e-03
6.15e-03
3.82e-03
2 43e-03
1.88e-03
1 42e-03
1.36e-03
6.81e-04
6.15e-04
5.97e-04
6.33e-04
6.816-04
1.04e-03
1.02e-03
1.12e-03
1 .OSe-03
1.18e-03
1.35e-03
1 42e-03
1.36e-03
1.14e-03
9.28e-04
7.71e-04
0.024
HC1:
Concentration, (ppm)
Meteorological Condition
Conservative
2 436 + 02
8.046 + 01
4.59e + 01
3.80e + 01
3.886 + 01
3 22e-01
2.59e-01
2.40e-r01
2.13e-0l
2 30e-0l
1.57e-01
1.26e + 01
1 07e-0l
1.01e + 0l
9.55e + 00
8.78+00
7.11e+00
4.94e+00
3.85e + 00
2.40e+00
1.61e + 00
9 86e-01
7.88e-0l
6 26e-0l
5 15e-01
4 34e-01
Typical
1 03e-00
" Obe-01
S 13e-01
7 40e-01
> 67e-01
? 5.V01
2 25e-01
1 '46-01
1 316-01
1 26t-01
b 29e-02
5 67e-02
5 51 e-02
5 84e-02
6 29e-02
9.57e-02
9.40e-02
1.03e-01
9.68e-02
1 09e-01
1.25e-01
1.31e-01
1.26e-01
1 05e-01
8 57e-02
7 12e-02
MW
"the source.
lanos are estimated to be 10-fold lower than for conservative volume off-site fire
.8
Volume VII
Appendix VII-4
4-56
-------
|| TABLE 18
Phosgene and HCI Concentrations under Conservative and Typical Meteorological Conditions for the
Conservative Mitigated On-Site Fire Scenarios
Downwind
Distance4
(m)
100
200
300
400
500
600
700
800
900
1000
1250
1500
1750
2000
1 2250
2500
3000
4000
5000
7500
10000
15000
. 20000
30000
40000
50000
Notes:
Phosgene em
HCI emissior
1 Concentratioi
* Downwind di
The concentratio
mitigated on-site
Concentration Factors,
Concentration, (ppm)
Meteorological Condition
Conser\ati\f
0 00
000
2.04e-03
5.71e-02
1.23e-01
1.39e-01
1.29e-01
2.88e + 00
245e + 00
2.13e-rOO
1.56e+00
1.21e + 00
9.87e-01
8.13e-01
6.72e-01
5.86e-01
4 28e-01
2 83e-01
2 15e-01
1.28e-OI
8.30e-02
4.94e-02
3.42e-02
2.04e-02
1 .42e-02
1.08e-02
T\pical
ii (Hi
11 00
(I (Hi
0 (Hi
0 00
4 54c--05
9.09c-05
1.15e-01
7 40e-02
7 Ole-02
7.22e-02
7.24e-02
6 67e-02
6 66e-02
6 83e-02
6 31e-02
5.88e-02
4 45e-02
3 5U--02
2 lht-02
1 4<*.-02
8 52e-0?
5 66e-03
3 lle-03
2 04c-03
1.48e-03
A/W 60
lie source.
fire scenarios are estimated to be 10-fold lower than for conservative volume
xVII-4, Section I.E. 8
Volume VII
Appendix VII-4
4-57
-------
TABLE 19
Average Emission Rates and Emission Durations Events
Event
On-Site Spill1
Formaldehyde/Methanol
Acetone/Toluene
On-Site Fire
HC1
Phosgene
On-Site Mixing of Incompatible
Wastes
HC1
Off-Site Spill1
Formaldehyde/Methanol
Acetone/Toluene
Off-Site Fire
HC1
Phosgene
Conservative Emission
Emission
Rate
(kg/s)
3.2 m/s
1.33
0.681
1 m/s
0432
0.194
0.36
0.011
1.79
3.2 m/s
1.840
1.14
1 m/s
0.759
0.341
1.47
0.043
Emission
Duration
(s)
3.2 m/s
1.800
1.800
1 m/s
7,500
43.980
7,030
7.030
1,200
3.2 m/s
1.740
1.800
1 m/s
4,260
25.020
430
430
Typical Emission
Emission
Rate
(kg/s)
3.2 m/s
0.094
0.051
1 m/s
0.039
0.018
0.150
0.0045
0.071
3.2 m/s
0.094
0.051
1 m/s
0.039
0.018
0.076
0.0022
Emission
Duration
(s)
3.2 m s 1 m s
680 1.660
1.800 9.660
167
167
600
3 2 m/s 1 m s
680 1 .660
1.800 9.660
167
167
Volume VII
Appendix VII-4
4-58
-------
TABLE 20
Air Dispersion Modeling Results Based on Various Concentration Averaging Time
Chemical of
Concern
Formaldehyde
(on-site spill;
100 gallons of
waste)
MCI
(mixing of
incompatible
waste, 10,000
gallons of
waste)
Emission Scenario
Typical
Conservative
Meteorological
Condition
Typical
Conservative
Calm/Inversion
Typical
Conservative
Calm/Inversion
Release
Duration
|_ (S)
680
680
0
1200
1200
0
Concentration
Averaging
Time (s)
680
1800
680
1800
306
1800
1200
1800
1200
1800
759
1800
LOC
(ppm)
9.6
96
9.6
96
9.6
9.6
99
9.9
9.9
9.9
9.9
9.9
IDLH
(ppm)
196
196
19.6
19.6
19.6
19.6
49 1
49 1
49.1
49.1
49.1
49 1
Max. Dist. to
LOC (m)1
240
100
1270
910
1950
1600
2230
1780
9110
8790
12840
12200
Max. Dist.
to
1DLH (m)1
140
40
850
550
1310
1000
870
680
3480
3190
4800
4620
Note'
' All distances are measured from the property line to the east or west, across the Ohio river to the south, or from the existing railroad to the north, whichever
is closer to the spill.
Volume VII
Appendix VI1-4
4-59
-------
, rrarasco BUILDINGS
-, EnsriNC FACILITIES
CWCACTE PAVEMCNT
»«»EMtMT
_ igure 1: Source Area for On-Site Spill
-f
Volume VII
Appendix VI1-4
-------
LEGENCL
0 1000
Scale In Feet
ASSUMED LOCATION
OF OFF-SITE SPILL
SITE
NORMAL POOL Light
ELEVATION 665
Volume VII
Appendix VII-4
LOCATION FOR THE OFF-SITE SPILL
4-61
FIGURE
2
-------
O. n
ON
N>
Total
Formaldehyde
- - Methanol
Ste?dy-state
o
ill
in
3
UJ
Time, sec
f
HI
in
3
il
O)
(O
I
UJ
ro
o>
3
CO
rv
3
til
CM
Figure 3: Rate of Evaporation of the 10% Formaldehyde/ 90% Methanol Liquid Pool
for the On-Site Spill Scenario (Conservative Emissions)
-------
o o
l i
O. n>
*' <;
^^ ^*^
^-^ ^*^
HN
MH
^
08
07
06
05
I..
ui
0.3
0.2
0.1
Total
Acetone
- - Toluene
Steady-state
3
UJ
o
p
o
<*>
o
+
UJ
CO
o>
n
o
UJ
CM
O)
3
ID
0>
3
UJ
GO
in
3
UJ
00
O)
Time, sec
s
UJ
CO
s
UJ
o
UJ
UJ
to
in
S
UJ
Figure 4: Rate of Evaporation of 10% Acetone/ 90% Toluene Liquid Pool
for the On-Site Spill Scenario (Conservative Emissions)
-------
ATTACHMENT 1
Program AIRCONC
-------
program airconc
Integer indexl, indexh,npts,nmet,nblank,iloc
double precision mfrac,loc,idlh
character*80 filenm,fileout,chem
character*80 junk
character*7 seen, locat, drzrafc,meteo
double precision xp(54,61), zm(54,61), cvpm(54,61), timp(54,6l)
double precision maxconc(24),maxdist
double precision tcld(54,61),conc(54,24)
double precision x(24), rain, max, distl, dist2,xloc(13)
data X/25,50,100,200,300,400,500,600,700,800,900,1000,1250,1500,
1 1750,2000,2250,2500,3000,4000,5000,10000,15000,20000/
data xloc/0.0001,0.0005,0.001,0.005,0.01,0.05,0.1,0.5,1.0,5.0,
1 10.0,50.0,100.O/
open (unit=5,file«'ppm.dat',status«' old')
read(5,130) filenm
open(unit=3,file=filenm, status*'old')
flleout » 'ppm'// filenm(4:9)
open(unit=7,file*fileout, status*'new')
read(5,132) mfrac
read(5,132) loc
read(5,132) idlh
read(5,130) chem
read(5,131) seen
read(5,131) locat
read(5,131) meteo
read(5,131) durat
if(meteo.eq.'WORST ') then
nmet = 54
else
nmet « 1
endif
npts =24
write(7,133)'From Slab output file:',filenm
write(7,129)'Scenario:',seen
write(7,129)'Accident Location:', locat
write(7,129)'Duration:', durat
write(7,129)'Meteorology:', meteo
write(7,133)'Chemical:', chem
write(7,134)'Vapor phase mole fraction:',mfrac
write(7,134)'LOC:',loc
write(7,134)'IDLH:',idlh
if (nmet.eq.l) nblank = 323
if (nmet.eq.54) nblank «= 5
do 10 j -1, nmet
do 12 k = l, nblank
read(3,130) junk
12 continue
read (3,135) (xp(j,i),
1 cvpm(3,i), i - 1,61)
10 continue
find interpolation indeces
if(locat.eq.'ON-SITE') then
write(7,*)'*Output adjusted to be distance from fenceline.'
do 29 i-=l,61
do 28 j « l,nmet
xp(j,i) « xp(j,i) - (250./3.2808)
28 continue
29 continue
endif
do 30 j « l, nmet
do 35 k=l, npts
if(xp(j,6l).ge.x(k)) then
do 40 i = i, 61
if(xp(j,i).le.x(k)) then
-------
indexh « i+1
endif
40 continue
distl = xp(j,indexh) - xp(j,indexl)
dist2 * x(k) - xp(j,indexl)
max « cvpm(j~lhdexh)
rmin « cvpm(3,indexl)
cone(j,k) «mfrac*le+06* ((dist2* (rmax-rmin) /distl) +rmin)
else
npts - k-l
goto 30
endif
35 continue
30 continue
if (nmet.ne.l) then
write(7,145)'X,m',(i,i=l,27)
write(7,l40) (x(i),(conc(j,i), j-1,27), i-i,npts)
write(7,145) 'X^', (i,i«28,nmet)
write(7,140) (x(i),(conc(j,i), j-28,nmet), i«l,npts)
endif
do 45 k e 1, npts
maxconc(k) « O.'O
45 continue
write(7,147) 'X/n', 'Max concentration, ppa'
do 50 k=l,npts
do 60 j * 1, nmet
maxconc(k) = max(maxconc(k),cone(j,k))
60 continue
write(7,150) x(k), maxconc(k)
50 continue
; find distances to fractions of LOG
write(7,*)
write(7,*)
write(7,155)'Concentration (ppm)', 'Distance to (m)'
: do 80 iloc = 1,13
do 80 iloc =9,9
maxdist « 0.0
indexl=l
indexh-1
do 70 k*npts,l,-l
if(maxconc(k).le.(xloc(iloc)*loc)) then
indexl-k
indexh-k-1
endif
7 0 continue
if(maxconc(1).ge.(xloc(iloc)*loc).and.
1 maxconc(npts).le.(xloc(iloc)*loc)) then
distl * maxconc(indexh)-maxconc(indexl)
dist2 * maxconc(indexh)-(xloc(iloc)*loc)
rmax * x(indexh)
rain * x(indexl)
maxdist»rmax - (dist2*(rmax-rmin)/distl)
write(7,160) loc*xloc(iloc), maxdist
endif
if (maxconc(1).le.(loc*xloc(iloc))) then
write(7,l65) loc*xloc(iloc),' less than', x(l)
endif
if (maxconc(npts).ge.(loc*xloc(iloc))| then
write(7,165) loc*xloc(iloc),' greater than', x(npts)
endif
80 continue
c find distance to the IDLH
maxdist « 0.0
indexl«l
indexh=l
-------
95
if(maxconc(k).le.idlh) then
indexl«=k
indexh«k-l
endif
continue
if (maxconc.(1). ge. ocHh rand.
maxconc(npts).le.idlh} then
distl * maxconc(indexh)-maxconc(indexl)
dist2 * maxconc(indexh)-idlh
rmax - x(indexh)
rain - x(indexl)
maxdist=rmax - (dist2*(rmax-rmin)/distl)
write(7,161) idlh, maxdist
endif
if (maxconc(1).le.idlh) then
write(7,166) idlh,' less than', x(l)
endif
if (maxconc(npts).ge.idlh) then
write(7,i66) idlh,' greater than', x(npts)
endif
130 format (ABO)
131 format (A7)
132 format (f!2.3)
129 format (A26,T40,A7)
133 format (A26,T40,A80)
134 format (A26,T40,fl2.3)
135 format (e!2.2,42x,ell.2)
136 format (2el2.2)
40 format (28fl2.2)
^45 format (A12,27112)
147 format(/,A12,3x,A22 /, 40('-'))
150 format (F12'.2,3x,F12.2)
155 format (//,A19,8x,A15 /,40('-'))
156 format (2F12.2)
160 format ('LOG',5x,F12.4,8x,F12.2)
161 format ('IDLH',4X,F12.4,8x,F12.2)
165 format ('LOG',3x,F12.4,A15, F12.2)
166 format ('IDLH',2X,F12.4,A15, F12.2)
end
-------
RUN01.OUT
problem input
idspl =
ncalc =
wms
cps
tbp
cmedO =
dhe
cpsl =
rhosl =
spb
spc
ts
qs
as =
tsd
qtis =
hs
tav
xf fm =
zp(l) =
zp(2) =
zp(3) =
zp(4) =
zO
za =
ua
ta
rh
stab
1
1
.031880
909.80
309.35
.00
1070000.
2716.00
793.70
-1.00
.00
293.00
1.33
418.00
1800.
.00
.00
1800.00
20000.00
.00
.00
.00
.00
.300000
10.00
3.20
293.00
68.00
4.00
release gas properties
molecular weight of source gas (kg)
3.1880E-02
vapor heat capacity, const, p. (j/kg-k)
9.0980E+02
temperature of source gas (k)
3.0935E+02
density of source gas (kg/m3)
1.2559E+00
boiling point temperature
3.0935E+02
liquid mass fraction
O.OOOOE+00
liquid heat capacity (j/kg-k)
2.7160E+03
heat of vaporization (j/kg)
1.0700E+06
liquid source density (kg/m3)
7.9370E+02
saturation pressure constant
1.3263E+01
saturation pressure constant (k)
4.1028E+03
saturation pressure constant (k)
O.OOOOE+00
wms =
cps =
ts
rhos =
tbp =
cmedO=
cpsl =
dhe =
rhosl=
spa =
spb =
spc =
spill characteristics
spill type
- idspl=
-------
mass source rate (kg/s)
1.3300E+00
continuous source duration (s)
1.8000E+03
continuous source mass (kg)
2.3940E+03
instantaneous source mass (kg)
O.OOOOE+00
source area (m2)
4.1800E+02
vertical vapor velocity (m/s)
2.5335E-03
source half width (m)
1.0223E+01
source height (m)
O.OOOOE+00
horizontal vapor velocity (m/s)
O.OOOOE+00
- tsd
- qtcs
- qtis
- as
- ws
- bs
- hs
- us
field parameters
concentration averaging time (s)
1.8000E+03
mixing layer height (m)
1.0400E+03
maximum downwind distrace (m)
2.0000E-I-04
concentration measurement height (m)
O.OOOOE+00
O.OOOOE+00
O.OOOOE+00
O.OOOOE+00
- tav =
- hmx =
- xffm =
- zp(l) =
- zp(2)=
- zp(3)=
- zp(4)=
ambient meteorological properties
molecular weight of ambient air (kg) - wmae
2.8783E-02
heat capacity of ambient air at const p. (j/kg-k)- cpaa =
1.0144E+03
density of ambient air (kg/m3) - rhoa
1.1972E+00
ambient measurement height (m) - za
l.OOOOE+01
ambient atmospheric pressure (pa=n/m2=j/m3) - pa
1.0133E+05
ambient wind speed (m/s) - ua
3.2000E+00
ambient temperature (k) - ta
2.9300E+02
relative humidity (percent) - rh
6.8000E+01
ambient friction velocity (m/s) - uastr =
3.7515E-01
atmospheric stability class value - stab =
4.0000E+00
inverse monin-obukhov length (1/m) - ala =
O.OOOOE+00
surface roughness height (m) - zO =
3.0000E-01
-------
additional parameters
sub-step multiplier
1
number of calculational sub-steps
acceleration of gravity (m/s2)
9.8067E+00
gas constant (j/mol- k)
8.3143E+00
von karman constant
4.1000E-01
1
instantaneous spatially averaged cloud parameters
- ncalc =
- nssm =
- grav =
- rr =
- xk
x zc h
cv rho t
-1.02E+01 O.OOE+00 O.OOE+00
1.02E+01 O.OOE+00 1.20E+00 2
-8.18E+00 O.OOE+00 1.75E+00
1.13E+01 3.06E-03 1.20EfOO 2
-6.13E+00 O.OOE+00 2.37E+00
1.23E+01 3.58E-03 1.20E+00 2
-4.09E+00 O.OOE+00 2.86E+00
1.34E+01 3.90E-03 1.20E+00 2
-2.04E+00 O.OOE+00 3.29E+00
1.44E+01 4.12E-03 1.20E+00 2
-1.55E-06 O.OOE+00 3.67E+00
1.55E+01 4.29E-03 1.20E+00 2
2.04E+00 O.OOE+00 4.03E+00
1.65E+01 4.43E-03 1.20E+00 2
4.09E+00 O.OOE+00 4.36E+00
1.76E+01 4.53E-C3 1.20E+00 2
6.13E+00 O.OOE+00 4.67E+00
1.86E+01 4.62E-03 1.20E+00 2
8.18E+00 O.OOE+00 4.96E+00
1.97E+01 4.69E-03 1.20E+00 2
1.02E+01 O.OOE+00 5.25E+00
2.07E+01 4.75E-03 1.20E+00 2
1.04E+01 O.OOE+00 5.28E+00
2.09E+01 4.71E-03 1.20E+00 2
1.07E+01 O.OOE+00 5.32E+00
2.12E+01 4.65E-03 1.20E+00 2
1.10E+01 O.OOE+00 5.36E+00
2.16E+01 4.59E-03 1.20E+00 2
1.15E+01 O.OOE+00 5.41E+00
2.20E+01 4.51E-03 1.20E+00 2
1.19E+01 O.OOE+00 5.48E+00
2.25E+01 4.43E-03 1.20E+00 2
1.25E+01 O.OOE+00 5.55E+00
2.31E+01 4.32E-03 1.20E+00 2
1.33E+01 O.OOE+00 5.65E+00
2.39E+01 4.20E-03 1.20E+00 2
1.42E+01 O.OOE+00 5.76E+00
2.48E+01 4.06E-03 1.20E+00 2
1.53E+01 O.OOE+00 5.90E+00
2.59E+01 3.91E-03 1.20E+00 2
1.66E+01 O.OOE+00 6.06E+00
2.72E+01 3.73E-03 1.20E+00 2
1.82E+01 O.OOE+00 6.25E+00
2.89E+01 3.54E-03 1.20E+00 2
2.02E+01 O.OOE+00 6.48E+00
3.09E+01 3.32E-03 1.20E+00 2
2.25E+01 O.OOE+00 6.76E+00
3.34E+01 3.09E-03 1.20E+00 2
bb b
u ua
1.02E+01 9.20E+00
.93E+02 O.OOE+00 0
1.04E+01
.93E+02
1.05E+01
.93E+02 1
1.06E+01
.93E+02 1
1.07E+01
.93E+02 1
1.08E+01
.93E+02 1
1.09E+01
.93E+02 1
1.10E+01
.93E+02 1
1.12E+01
.93E+02 1
1.13E+01
.93E+02 1
1.14E+01
.93E+02 1
1.14E+01
.93E+02
1.14E+01
.93E+02 1
1.14E+01
.'93E+02 1
1.15E+01
. 93E+02 1
1.15E+01
.93E+02 1
1.1SE+01
.93E+02 1
1.16E+01
.93E+02 1
1.16E+01
.93E+02 1
1.17E+01
.93E+02 1
1.18E+01
.93E+02 1
1.19E+01
.93E+02 1
1.20E+01
93E+02 1
1.21E+01
9.20E+00
9.05E-01 9
9.20E+00
13E+00 1
9.20E+00
27E+00 1
9.20E+00
38E+00 1
9.21E+00
47E+00 1
9.21E+00
54E+00 1
9.21E+00
61E+00 1
9.22E+00
67E+00 1
9.22E+00
72E+00 1
9.22E+00
76E+00 1
9.23E+00
1.77E+00 1,
9.23E+00
77E+00 1.
9.23E+00
78E+00 1.
9.23E+00
79E+00 1.
9.23E+00
80E+00 1.
9.23E+00
81E+00 1.
9.23E+00
83E+00 1.
9.23E+00
84E+00 1.
9.24E+00
86E+00 1.
9.24E+00
89E+00 1.
9.25E+00
91E+00 1.
9.25E+0A
95E+00 1.
9.26E+00
93E+02 1.98E+00 1
bbx
1.02E+01
. OOE+00
1.13E+01
,08E-01
1.23E+01
13E+00
1.34E+01
28E+00
1.44E+01
39E+00
1.55E+01
48E+00
1.65E+01
55E+00
1.76E+01
62E+00
1.86E+01
67E+00
1.97E+01
73E+00
2.07E+01
77E+00
2.09E+01
78E+00
2.12E+01
78E+00
2.16E+01
79E+00
2.20E+01
80E+00
2.25E+01
81E+00
2.31E+01
82E+00
2.39E+01
83E+00
2.48E+01
85E+00
2.59E+01
87E+00
2.72E+01
89E+00
2.89E+01
92E+00
3.09E+01
95E+00
3.34E+01
99E+00
bx
-------
2.55E+01
3.64E+01 2
2.90E+01
4.OOE+01 2
3.33E+01
4.45E+01 2
3.86E+01
4.99E+01 2
4.50E+01
5.65E+01 1
5.29E+01
6.45E+01 1
6.24E+01
7.43E+01 1
7.40E+01
8.62E+01 1
8.82E+01
1.01E+02 9
1.05E+02
1.19E+02 8
1.27E+02
1.40E+02 6
1.52E+02
1.66E+02 5
1.83E+02
1.99E+02 4.
2.21E+02
2.38E+02 3.
2.68E+02
2.85E+02 2.
3.24E+02
3.43E+02 1.
3.93E+02
4.14E+02 1.
4.77E+02
5.OOE+02 1.
5.79E+02
6.05E+02 8.
7.04E+02
7.33E+02 6.
8.56E+02
8.89E+02 4.
1.04E+03
1.08E+03 3.
1.27E+03
1.31E+03 2.
1.54E+03
1.59E+03 1.
1.88E+03
1.94E+03 1.
2.28E+03
2.35E+03 9.
2.78E+03
2.86E+03 7.
3.39E+03
3.49E+03 5.
4.12E+03
4.24E+03 3.
5.04E+03
4.24E+03 2.
6.18E+03
4.24E+03 1.
7.61E+03
4.24E+03 1.
9.39E+03
4.24E+03 8.
1.16E+04
O.OOE+OO
.85E-03 1
O.OOE+00
.60E-03 1
O.OOE+00
-35E-03 1
O.OOE+00
.10E-03 1
O.OOE+00
.85E-03 1
O.OOE+00
.61E-03 1
O.OOE+00
.38E-03 1
O.OOE+00
.17E-03 1
O.OOE+00
-80E-04 1
O.OOE+00
.10E-04 1
O.OOE+00
.60E-04 1
O.OOE+00
.32E-04 1
O.OOE+00
.23E-04 1.
O.OOE+00
.32E-04 1.
O.OOE+00
.58E-04 1.
O.OOE+00
.98E-04 1.
O.OOE+00
.50E-04 1.
O.OOE+00
.13E-04 1.
O.OOE+00
.45E-05 1.
O.OOE+00
.27E-05 1.
O.OOE+00
62E-05 1.
O.OOE+00
39E-05 1.
O.OOE+00
48E-05 1.
O.OOE+00
81E-05 1.
O.OOE+00
32E-05 1.
O.OOE+00
61E-06 1.
O.OOE+00
01E-06 1.
O.OOE+00
11E-06 1.
O.OOE+00
74E-06 1.
O.OOE+00
63E-06 1.
O.OOE+00
84E-06 1.
O.OOE+00
29E-06 1.
O.OOE+00
95E-07 1.
O.OOE+00
7.08E+00
.20E+00 2
7.46E+00
.20E+00 2
7.91E+00
.20E+00 2
8.44E+00
.20E+00 2
9.05E+00
.20E+00 2
9.77E+00
.20E+00 2
1.06E+01
.20E+00 2
1.16E+01
.20E+00 2
1.27E+01
.20E+00 2
1.40E+01
.20E+00 2.
1.54E+01
.20E+00 2.
1.72E+01
.20E+00 2.
1.91E+01
.20E+00 2.
2.14E+01
.20E+00 2.
2.40E+01
.20E+00 2.
2.71E+01
.20E+00 2.
3.06E+01
.20E+00 2.
3.46E+01
.20E+00 2.
3.93E+01
.20E+00 2.
4.47E+01
.20E+00 2.
5.10E+01
20E+00 2.
5.82E+01
20E+00 2.
6.66E+01
20E+00 2.
7.63E+01
20E+00 2.
8.74E+01
20E+00 2.
l.OOE+02
20E+00 2.
1.15E+02
20E+00 2.
1.32E+02
20E+00 2.
1.52E+02
20E+00 2.
1.78E+02
20E+00 2.
2.09E+02
20E+00 2.
2.45E+02
20E+00 2.
2.86E+02
20E+00 2.
3.31E+02
1.23E+01
.93E+02 2
1.25E+01
.93E+02 2
1.27E+01
.93E+02 2
1.31E+01
.93E+02 2
1.34E+01
.93E+02 2
1.39E+01
.93E+02 2
1.44E+01
.93E+02 2
1.51E+01
.93E+02 2
1.60E+01
.93E+02 2
1.70E+01
.93E+02 2
1.82E+01
.93E+02 2
1.97E+01
.93E+02 2
2.14E+01
.93E+02 2.
2.36E+01
.93E+02 3.
2.61E+01
.93E+02 3.
2.92E+01
.93E+02 3.
3.29E+01
.93E+02 3.
3.74E+01
.93E+02 3.
4.27E+01
93E+02 3.
4.90E+01
93E+02 3.
5.65E+01
93E+02 3.
6.53E+01
93E+02 3.
7.58E+01
93E+02 4.
8.81E+01
93E+02 4.
1.02E+02
93E+02 4.
1.19E+02
93E+02 4.
1.39E+02
93E+02 4.
1.61E+02
93E+02 4.
1.87E+02
93E+02 4.
2.18E+02
93E+02 4.
2.53E+02
93E+02 4.
2.94E+02
93E+02 5.
3.41E+02
93E+02 5.
3.96E+02
9.27E+00
.02E+00 2
9.28E+00
.07E+00 2
9.29E+00
.12E+00 2
9.31E+00
.17E+00 2
9.33E+00
.23E+00 2
9.36E+00
.30E+00 2
9.39E+00
.37E-1-00 2
9.43E+00
.45E+00 2
9.47E+00
.53E+00 2
9.52E+00
. 62E+00 2
9.57E+00
.71E+00 2.
9.63E+00
. 80E+00 2.
9.70E+00
.90E+00 2.
9.76E+00
.OOE+00 3.
9.83E+00
.10E+00 3.
9.90E+00
.20E+00 3.
9.97E+00
.31E+00 3.
1.OOE+01
.42E+00 3.
Z.01E+01
.54E+00 3.
1.02E+01
65E+00 3.
1.02E+01
77E+00 3.
1.03E+01
88E+00 3.
1.03E+01
OOE+00 4.
1.03E+01
12E+00 4.
1.04E+01
24E+00 4.
1.04E+01
36E+00 4.
1.04E+01
48E+00 4.
1.04E+01
60E+00 4.
1.05E+01
71E+00 4.
1.05E+01
85E+00 4.
1.05E+01
98E+00 4.
1.05E+01
11E+00 5.
1.05E+01
24E+00 5.
1.05E+01
3.64E+01
.03E+00
4.OOE+01
.07E+00
4.45E+01
.12E+00
4.99E+01
.18E+00
5.65E+01
.24E+00
6.45E+01
.31E+00
7.43E+01
.38E+00
8.63E+01
.45E+00
1.01E+02
.53E+00
1.19E+02
.62E+00
1.40E+02
.71E+00
1.66E+02
. 80E+00
1.99E+02
.90E+00
2.38E+02
.OOE+00
2.85E+02
.10E+00
3.43E+02
.21E+00
4.14E+02
.31E+00
5.00E+02
.43E+00
6.05E+02
. 54E+00
7.33E+02
65E+00
8.89E+02
77E+00
1.08E+03
89E+00
1.31E+03
01E+00
1.59E+03
12E+00
1.94E+03
24E+00
2.35E+03
36E+00
2.86E+03
48E+00
3.49E+03
60E+00
4.24E+03
72E+00
4.42E+03
85E+00
4.62E+03
99E+00
4.87E+03
11E+00
5.18E+03
24E+00
5.54E+03
-------
4
4
4
4
1
.24E+03
1.44E+04
.24E+03
1.78E+04
.24E+03
2.21E+04
.24E+03
6.
4.
2.
2.
21E-07
O.OOE+00
31E-07
O.OOE+00
99E-07
O.OOE+00
07E-07
1
1
1
1
.20E+00
3.83E+02
.20E+00
4.40E+02
.20E+00
5.02E+02
. 20E+00
2.
2.
2.
2.
93E+02
4.58E+02
93E+02
5.28E+02
93E+02
6.08E+02
93E+02
5.
5.
5.
5.
35E+00
1.05E+01
46E+00
1.05E+01
56E+00
1.05E+01
66E+00
5.
5.
5.
5.
35E+00
5.98E+03
46E+00
6.50E+03
56E-t-00
7.13E+03
66E-t-00
x cm
vg ug
-1.02E+01 O.OOE+00
O.OOE+00 O.OOE+00 0
-6.18E+00 3.39E-03
O.OOE+00 2.35E-04 0
-6.13E+00 3.96E-03
O.OOE+00 6.03E-04 0
-4.09E+00 4.32E-03
O.OOE+00 1.04E-03 0
-2.04E+00 4.56E-03
O.OOE+00 1.54E-03 0
-1.55E-06 4.75E-03
O.OOE+00 2.08E-03 0
2.04E+00 4.90E-03
O.OOE+00 2.65E-03 0
4.09E+00 5.02E-03
O.OOE+00 3.25E-03 0
6.13E+00 5.12E-03
O.OOE+00 3.87E-03 0
8.18E+00 5.20E-03
O.OOE+00 4.52E-03 0
1.02E+01 5.26E-03
O.OOE+00 5.18E-03 0
1.04E+01 5.21E-03
O.OOE+00 5.25E-03 0
1.07E+01 5.15E-03
O.OOE+00 5.34E-03 0
1.10E+01 5.08E-03
O.OOE+00 5.44E-03 0
1.1SE+01 5.00E-03
O.OOE+00 5.57E-03 0
1.19E+01 4.90E-03
O.OOE+00 5.71E-03 0
1.25E+01 4.78E-03
O.OOE+00 5.89E-03 0
1.33E+01 4.65E-03
O.OOE+00 6.09E-03 0
1.42E+01 4.50E-03
O.OOE+00 6.33E-03 0
1.53E+01 4.32E-03
O.OOE+00 6.61E-03 0
1.66E+01 4.13E-03
O.OOE+00 6.93E-03 0
1.82E+01 3.91E-03
O.OOE+00 7.29E-03 0
2.02E+01 3.68E-03
O.OOE+00 7.69E-03 0
2.25E+01
3.43E-03
8.13E-03 0
3.16E-03
8.62E-03 0
2.88E-03
9.13E-03 0
2.60E-03
O.OOE+00
2.55E+01
O.OOE+00
2.90E+01
O.OOE+00
3.33E+01
O.OOE+00 9.67E-03 0
3.86E+01 2.32E-03
O.OOE+00 1.02E-02 0
cmv
w
O.OOE+00
.OOE+00 4
3.39E-03
.OOE+00 3
3.96E-03
.OOE+00 2
4.32E-03
.OOE+00 2
4.56E-03
.OOE+00 2
4.75E-03
.00&+00 2
4.90E-03
.OOE+00 2
5.02E-03
.OOE+00 2
5.12E-03
.OOE+00 2
5.20E-03
.OOE+00 2
5.26E-03
.OOE+00 2
5.21E-03
.OOE+00 2
5.15E-03
.OOE+00 2
5.08E-03
.OOE+00 2
5.00E-03
.OOE+00 2
4.90E-03
.OOE+00 2
4.78E-03
.OOE+00 2
4.65E-03
.OOE+00 1
4.50E-03
.OOE+00 1
4.32E-03
.OOE+00 1
4.13E-03
.OOE+00 1
3.91E-03
.OOE+00 1
3.68E-03
.OOE+00 1
3.43E-03
.OOE+00 1
3.16E-03
.OOE+00 1
2.88E-03
.OOE+00 1
2.60E-03
.OOE+00 1
2.32E-03
.OOE+00 1
cmda cmw
v vx
9.90E-01 1.01E-02
.12E-01 1.04E-01 0
9.87E-01 1.01E-02
.37E-01 2.85E-02 3
9.86E-01 1.01E-02
.86E-01 3.55E-02 3
9.86E-01
.62E-01
9.85E-01
1.01E-02
4.00E-02 4
1.01E-02
.46E-01 4.35E-02 4
9.85E-01 1.01E-02
.35E-01 4.62E-02 4
9.85E-01 1.01E-02
.26E-01 4.86E-02 4
9.85E-01 1.01E-02
.19E-01 5.06E-02 4
9.85E-01 1.01E-02
.14E-01 5.24E-02 4
9.85E-01 1.01E-02
.09E-01 5.40E-02 4
9.85E-01 1.01E-02
.04E-01 5.54E-02 4
9.85E-01 1.01L-02
.04E-01 5.55E-02 4
9.85E-01 1.01E-02
.03E-01 5.57E-02 4
9.85E-01 1.01E-02
.03E-01 5.59E-02 4
9.85E-01 1.01E-02
.02E-01 5.62E-02 4
9.85E-01 1.01E-02
.01E-01 5.65E-02 4
1.01E-02
69E-02 4
1.01E-02
9.85E-01
OOE-01 5
9.85E-01
99E-01 5.73E-02 4.
9.85E-01 1.01E-02
98E-01 5.78E-02 4.
9.86E-01 1.01E-02
96E-01 5.84E-02 4.
9.86E-01 1.01E-02
95E-01 5.91E-02 4.
9.86E-01 1.01E-02
93E-01 5.99E-02 4.
9.86E-01 1.01E-02
90E-01 6.09E-02 4.
9.86E-01 1.01E-02
88E-01 6.20E-02 4.
9.87E-01 1.01E-02
85E-01 6.32E-02 4.
9.87E-01 1.01E-02
82E-01 6.45E-02 4.
9.87E-01 1.01E-02
79E-01 6.61E-02 4.
9.88E-01 1.01E-02
76E-01 6.77E-02 4.
cmwv
1.01E-02
.OOE+00
1.01E-02
.45E-01
1.01E-02
.83E-01
1.01E-02
.05E-01
1.01E-02
.19E-01
1.01E-02
.30E-01
1.01E-02
-39E-01
1.01E-02
-46E-01
1.01E-02
.52E-01
1.01E-02
.57E-01
1.01E-02
.61E-01
1.01E-02
.62E-01
1.01E-02
.62E-01
1.01E-02
.63E-01
1.01E-02
.64E-01
1.01E-02
.64E-01
1.01E-02
.66E-01
1.01E-02
.67E-01
1.01E-02
,68E-01
1.01E-02
.70E-01
1.01E-02
,72E-01
1.01E-02
.74E-01
1.01E-02
.77E-01
1.01E-02
.79E-01
1.01E-02
.82E-01
1.01E-02
. 86E-01
1.01E-02
. 89E-01
1.01E-02
93E-01
-------
0
4 .50E+01
O.OOE+00 1
5.29E+01
O.OOE+00 1
6.24E+01
OOE+00 1
7.40E+01
O.OOE+00 1.
8.82E+01
O.OOE+00 1.
1.05E+02
O.OOE+00 1.
1.27E+02
O.OOE+00 1.
1.52E+02
O.OOE+00 1.
1.83E+02
O.OOE+00 1.
2.21E+02
O.OOE+00 1.
2.68E+02
O.OOE+00 1.
3.24E+02
2.04E-03 2.04E-03
08E-02 O.OOE+00 1
1.78E-03 1.78E-03
13E-02 O.OOE+00 1
1.53E-03 1.53E-03
18E-02 O.OOE+00 1
1.30E-0? 1.30E-03
22E-02 O.OOE+00 1
1.09E-03 1.09E-03
24E-02 O.OOE+00 1
8.97E-04 8.97E-04
9.88E-01 1.01E-02
72E-01 6.9SE-02 4
9.88E-01
68E-01 7
9.88E-01
64E-01 7
9.89E-01
60E-01 7
1.01E-02
97E-01
1.01E-02
01E-01
1.01E-02
04E-01
1.01E-02
9.89E-01
56E-01 7
9.89E-01
26E-02 0,
7.31E-04
26E-02 0.
5.89E-04
25E-02 0.
4.68E-04
OOE+00 1
7.31E-04
OOE+00 1
5.89E-04
OOE+00 1
4.68E-04
1.01E-02
15E-02 5
1.01E-02
35E-02 5
1.01E-02
57E-02 5.08E-01
1.01E-02 1.01E-02
12E-01
1.01E-02
16E-01
22E-02 O.OOE+00 1
3.68E-04 3.68E-04
17E-02 O.OOE+00 1
2.85E-04 2.85E-04
11E-02 O.OOE+00 1
2.19E-04 2.WE-04
O.OOE+00 1.04E-02 O.OOE+00 1
3.93E+02 1.66E-04 1.66E-04
62E-03 O.OOE+00 1
1.25E-04 1.25E-04
77E-03 0
9.36E-05
90E-03 0
6.95E-05
80E-02 5
1.01E-02
53E-01 8.04E-02 5
9.89E-01 1.01E-02 1.01E-02
49E-01 8.28E-02 5.20E-01
9.89E-01 1.01E-02 1.01E-02
45E-01 8.52E-02 5.23E-01
9.89E-01 1.01E-02 1.01E-02
41E-01 8.76E-02 5.26E-01
9.90E-01 1.01E-02 1.01E-02
OOE-02 5.30E-01
1.01E-02 1.01E-02
23E-02 5.32E-01
1.01E-02 1.01E-02
0
O.OOE+00 9
4.77E+02
O.OOE+00 8
5.79E+02
OOE+00 7
7.04E+02
O.OOE+00 7
8.56E+02
O.OOE+00 6
1.04E+03
O.OOE+00 5
1.27E+03
O.OOE+00 4
1.54E+03
O.OOE+00 4
1.88E+03
0,OOE+00 3,
2.28E+03
O.OOE+00 3.
2.78E+03
OOE+00 1
9.36E-05
OOE+00 1
6.95E-05
06E-03 O.OOE+00 1
5.12E-05 5.12E-05
23E-03 O.OOE+00 1
3.76E-05 3.76E-05 9.90E-01
47E-03 O.OOE+00 1.08E-01 1
2.75E-05 2.75E-05 9.90E-01
76E-03 O.OOE+00 1.04E-01 1
2.01E-05 2.01E-05 9.90E-01
09E-03 O.OOE+00 1.01E-01 1,
1.46E-05 1.46E-05 9.90E-01
51E-03 O.OOE+00 9.76E-02 1.
1.06E-05 1.06E-05 9.90E-01
03E-03 O.OOE+00 9
7.76E-06 7.76E-06
37E-01 9
9.90E-01
33E-01 9
9.90E-01
29E-01 9.45E-02 5
9.90E-01 1.01E-02
26E-01 9.65E-02
9.90E-01
22E-01 9
9.90E-01
18E-01 1
9.90E-01
15E-01 1
9.90E-01
11E-01 1
35E-01
1.01E-02
5.37E-01
1.01E-02
40E-01
1.01E-02
41E-01
1.01E-02
1.01E-02
84E-02 5
1.01E-02
OOE-01 5
1.01E-02
01E-01 5.43E-01
1.01E-02 1.01E-02
02E-01 5
1.01E-02
03E-01 5
1.01E-02
03E-01 5
1.01E-02
02E-01 5
1.01E-02
01E-01 5
1.01E-02
42E-02 9.97E-02 5
9.90E-01 1.01E-02
O.OOE+00 2.59E-03 O.OOE+00 9.08E-02 9.77E-02 5
3.39E+03 5.66E-06 5.66E-06 9.90E-01
O.OOE+00 2.24E-03 O.OOE+00 8.73E-02 9
4.12E+03 4.14E-06 4.14E-06 9.90E-01
O.OOE+00 1.93E-03 8.54E-05 8.37E-02 9
5.04E+03 2.91E-06 2.91E-06 9.90E-01
O.OOE+00 1.57E-03 6.99E-05 7.95E-02 8
6.18E+03 2.04E-06 2.04E-06 9.90E-01
8.80E-05 O.OOE+00 O.OOE+00 7.51E-02 8
7.61E+03 1.42E-06 1.42E-06 9.90E-01
O.OOE+00 2.19E-04 1.28E-05 7.05E-02 8
9.39E+03 9.91E-07 9.91E-07 9.90E-01
O.OOE+00 2.98E-04 1.82E-05 6.57E-02 7
1.16E+04 6.88E-07 6.88E-07 9.90E-01
O.OOE+00 4.19E-04 2
1.44E+04 4.77E-07
92E-05 6.08E-02 7
4.77E-07 9.90E-01
.80E-05 O.OOE+00 O.OOE+00 5.56E-02
1.78E+04 3.31E-07 3.31E-07 9.90E-01
1.01E-02
51E-02 5
1.01E-02
22E-02 5
1.01E-02
91E-02 5
1.01E-02
54E-02 5
1.01E-02
14E-02 5
1.01E-02
70E-02 5
1.01E-02
24E-02 4
1.01E-02
6.77E-02 4
1.01E-02
.44E-01
1.01E-02
.46E-01
1.01E-02
46E-01
1.01E-02
47E-01
1.01E-02
47E-01
1.01E-02
47E-01
1.01E-02
47E-01
1.01E-02
46E-01
1.01E-02
44E-01
1.01E-02
19E-01
1.01E-02
15E-01
1.01E-02
10E-01
1.01E-02
04E-01
1.01E-02
97E-01
1.01E-02
89E-01
1.01E-02
1.62E-04 O.OOE+00 O.OOE+00 5.01E-02 6.29E-C? 4.81E-01
2.21E+04 2.30E-07 2.30E-07 9.90E-01
.OOE+00 1.56E-04 1.32E-05 4.45E-02 5.
1.01E-02 1.01E-02
83E-02 4.72E-01
-------
time averaged (tav = 1800. s) volume concentration: concentration
contour parameters
c(x,y,z,t) = cc(x) * (erf(xa)-erf(xb)) * (erf(ya)-erf(yb)) *
(exp(-za*za)+exp(-zb*zb))
c(x,y,z,t) = concentration (volume fraction) at (x,y,z,t)
x = downwind distance (m)
y = crosswind horizontal distance (m)
z = height (m)
t = time (s)
erf = error
functon
xa = (x-xc+bx) / (sr2*
xb = (x-xc-bx) / (sr2*
ya = (y+b) /
yb = (y-b) /
betax)
betax)
' (sr2*betac)
' (sr2*betac)
exp = exponential function
za = (z-zc)
zb = (z+zc)
/ (sr2*sig)
/ (sr2*sig)
sr2 = sqrt(2.0)
t
4
x
xc
-1.02E+01
.08E+00
0
-8.18E+00
4
5
6
7
8
9
1
1
1
1
1
1
1
1
1
1
1
1
1
2
.82E+00
-6.13E+00
.57E+00
-4.09E+00
.41E+00
-2.04E+00
.25E+00
-1.55E-06
.19E+00
2.04E+00
.13E+00
4.09E+00
.02E+01
6.13E+00
. 12E+01
8.18E+00
.23E+01
1.02E+01
.34E+01
1.04E+01
. 37E+01
1.07E+01
. 40E+01
1.10E+01
.43E+01
1.15E+01
.48E+01
1.19E+01
.53E+01
1.25E+01
. 60E+01
1.33E+01
. 68E+01
1.42E+01
.78E+01
1.53E+01
. 90E+01
1.66E+01
.04E+01
1
2
3
4
5
6
7
8
9
1
1
1
1
1
1
1
1
1
1
1
cc(x)
b(x)
betac (x)
zc(x)
sig(x)
(t) bx(t) betax(t)
0. OOE+00
.OOE+00 1.
5.96E-04
.02E+00 1.
7.06E-04
.04E+00 1.
7.78E-04
.07E+00 1.
8.34E-04
.09E+00 1.
8.80E-04
.11E+00 1.
9.20E-04
.13E+00 1.
9.57E-04
.16E+00 1.
9.90E-04
.18E+00 1.
1.02E-03
.20E+00 1.
1.05E-03
.02E+01 2.
1.04E-03
.04E+01 2.
1.03E-03
. 07E+01 2.
1.02E-03
. 10E+01 2.
1.01E-03
. 15E+01 2.
9.91E-04
.19E+01 2.
9.72E-04
.25E+01 2.
9.50E-04
.33E+01 2.
9.25E-04
.42E+01 2.
8. 97E-04
.53E+01 2.
8.66E-04
. 66E+01 2.
9.20E+00
02E+01 8
9.20E+00
13E+01 9
9.20E+00
23E+01 1
9.20E+00
34E+01 1
9.20E+00
44E+01 1
9.21E+00
55E+01 1
9.21E+00
65E+01 1
9.21E+00
76E+01 1
9.22E+00
86E+01 1
9.22E+00
97E+01 1
9.22E+00
07E+01 1
9.23E+00
09E+01 1
9.23E+00
12E+01 1
9.23E+00
16E+01 1
9.23E+00
20E+01 1
9.23E+00
25E+01 1
9.23E+00
31E+01 1
9.23E+00
39E+01 1
9.23E+00
48E+01 2
9.24E+00
59E+01 2
9.24E+00
72E+01 2
.
.
.
.
.
.
.
.
.
.
2.57E+00
35E-02
2.76E+00
20E-02
2.92E+00
01E-01
3.07E+00
09E-01
3.23E+00
18E-01
3.40E+00
26E-01
3.56E+00
35E-01
3.73E+00
43E-01
3. 90E+00
52E-01
4 .07E+00
61E-01
4 .24E+00
69E-01
4 .26E+00
71E-01
4 .29E+00
73E-01
4.31E+00
76E-01
4.35E+00
80E-01
4.39E+00
84E-01
4.44E+00
89E-01
4.51E+00
95E-01
4.58E+00
02E-01
4.68E+00
11E-01
4 .79E+00
22E-01
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
OOE+00
OOE+00
OOE+00
OOE+00
OOE+00
OOE+00
OOE+00
OOE+00
OOE+00
OOE+00
OOE+00
OOE+00
OOE+00
OOE+00
OOE+00
OOE+00
OOE+00
OOE+00
OOE+00
OOE+00
OOE+00
0
1
1
1
1
2
2
2
2
2
3
3
3
3
3
3
3
3
3
3
3
.OOE+00
.01E+00
.37E+00
.65E+00
.90E+00
.12E+00
.32E+00
. 52E+00
.70E+00
. 87E+00
. 03E+00
.05E+00
.07E+00
. 09E+00
. 12E+00
. 16E+00
.21E+00
.26E+00
.33E+00
. 40E+00
.50E+00
-------
2
2
2
2
3
3
4
4
5
6
7
8
9.
1.
1.
1.
1.
2.
2.
2.
3.
3.
4 .
5.
6.
7.
8.
1.
1.
1.
1.
2.
1.
1.82E+01
.21E+01 1
2.02E+01
.41E+01 2
2.25E+01
. 65E+01 2
2.55E+01
. 94E+01 2
2.90E+01
.29E+01 2
3.33E+01
.71E+01 3
3.86E+01
.20E+01 3
4.50E+01
.78E+01 4
5.29E-I-01
.47E+01 5
6.24E+01
.29E+01 6
7.40E+01
.25E+01 7
8.82E+01
. 39E+01 8
1.05E+02
. 73E+01 1
1.27E+02
. 13E+02 1
1.52E+02
. 32E+02 1
1.83E+02
.54E+02 1,
2.21E+02
.80E+02 2,
2.68E+02
, 10E+02 2,
3.24E+02
46E+02 3,
3.93E+02
88E+02 3,
4.77E+02
38E+02 4.
5.79E+02
97E+02 5.
7.04E+02
66E+02 7.
8.56E+02
48E+02 8.
1.04E+03
44E+02 1.
1.27E+03
59E+02 1.
1.54E+03
94E+02 1.
1.88E+03
05E+03 1.
2.28E+03
24E+03 2.
2.78E+03
47E+03 2.
3.39E+03
73E+03 3.
4.12E+03
05E+03 4.
5.04E+03
99E+03 5.
6.18E+03
B.31E-04
.82E+01 2
7.94E-04
.02E+01 3
7.54E-04
.2SE+01 3
7.11E-04
. 55E+01 3
6.68E-04
. 90E+01 4
6.24E-04
.33E+01 4
5.80E-04
.86E+01 4
5.37E-04
.50E+01 5
4. 96E-04
.29E+01 6
4.57E-04
.24E+01 7
4 .20E-04
.40E+01 8
3.86E-04
. 82E+01 1
3.53E-04
. 05E+02 1
3.23E-04
.27E+02 1
2.94E-04
.52E+02 1.
2.67E-04
.83E+02 1,
2. 42E-04
.21E+02 2,
2.17E-04
.68E+02 2.
1.95E-04
.24E+02 3.
1.73E-04
, 93E+02 4.
1.53E-04
.77E+02 5.
1.35E-04
79E+02 6.
1. 18E-04
04E+02 7.
1.03E-04
56E+02 8.
8.98E-05
04E+03 1.
7.77E-05
27E+03 1.
6.71E-05
54E+03 1.
5.77E-05
88E+03 1.
4 . 96E-05
28E+03 2.
4.25E-05
78E+03 2.
3.64E-05
39E+03 3.
3.11E-05
12E+03 4.
2.67E-05
04E+03 4.
2.29E-05
9.25E+OC
.89E*01 2
9.25E+00
.09E+01 2
9.26E+00
.34E+01 2
9.27E+00
. 64E+01 2
9.28E+00
. OOE+-01 3
9.29E+00
.45E+01 3
9.31E+00
. 99E+01 4
9.33E+00
. 65E+01 4
9.36E+00
. 45E+01 5
9.39E+00
.43E+01 6
9.43E+00
. 62E-I-01 7
9.4--7E+00
. 01E+02 8
9.52E+00
. 19E+02 9
9.57E+00
. 40E+02 1.
9. 63E+00
. 66E+02 1.
9.70E+00
. 99E+02 1,
9.76E+00
. 38E+02 1,
9.83E+00
. 85E + 02 2.
9. 90E+00
.43E+02 2.
9.97E+00
.14E+02 3.
l.OOE-i-01
.OOE+02 4.
l.OlE-t-01
05E+02 4 .
-1.02E+01
33E+02 5.
1.02E+01
89E+02 7.
1.03E+01
08E+03 8.
1.03E+01
31E+03 1.
1.03E+01
59E+03 1.
1.04E+01
94E+03 1.
1.04E+01
35E+03 1.
1.04E+01
86E+03 2.
1.04E+01
49E+03 2.
1.05E+01
24E+03 3.
1.05E+01
24E+03 7.
1.05E+01
4. 93E+00
.36E-01
5.10E+00
.52E-01
5.31E+00
.72E-01
5.57E+00
.97E-01
5.38E+00
.27E-01
6.26E-t-00
. 63E-01
6.73E+00
.07E-01
7.31E+00
. 61E-01
8.01E+00
.27E-01
8.87E+00
. 07E-01
9. 91E+00
.04E-01
1.12E+01
.23E-01
1.27E+01
. 68E-01
1.46E+01
.14E+00
1.69E-I-01
. 36E+00
1. 97E+01
. 62E+00
2.31E+01
. 94E+00
2.71E+01
.33E+00
3.21E+01
. 80E+00
3.80E+01
.38E+00
4 .51E + 01
. 08E-I-00
5.36E+01
94E+00
6.38E+01
98E+00
7.60E+01
26E+00
9.04E+01
81E+00
1.08E+02
07E+01
I.28E+02
30E-KD1
1.51E+02
58E+01
1.79E+02
92E+01
2.11E+02
34E+01
2.48E+02
85E+01
2.91E+02
46E+01
3.41E+02
06E+02
3.99E+02
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0,
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
.OOE+00
.OOE+00
.OOE+00
. OOE+00
.OOE+00
.OOE+00
.OOE+00
.OOE+00
.OOE+00
.OOE+00
.OOE+00
.OOE+00
.OOE+00
.OOE+00
.OOE+00
.OOE+00
.OOE+00
.OOE+00
.OOE+00
.OOE+00
.OOE+00
.OOE+00
.OOE+00
OOE+00
OOE+00
OOE+00
OOE+00
OOE+00
OOE+00
OOE+00
OOE+00
OOE+00
OOE+00
OOE+00
3
3
3
4
4
4
4,
5.
5.
6.
6.
7.
8.
8.
9.
1.
1.
1.
1.
1.
2.
2.
2.
2.
3.
3.
4.
5.
5.
6.
7.
8.
1.
1.
. 61E+00
.74E+00
. 90E+00
. 09E+00
. 31E+00
. 57E+00
. 87E+00
.23E+00
. 64E+00
12E+00
68E+00
32E+00
06E+00
91E+00
90E+00
10E+01
24E+01
39E+01
56E+01
77E+01
OOE+01
27E+01
58E+01
94E+01
36E+01
85E+01
40E+01
05E+01
79E+01
65E+01
63E+01
76E+01
03E+02
21E+02
-------
2
2
2
3
3
4
5
1
.22E+03
7.61E+03
.51E+03
9.39E+03
.85E+03
1.16E+04
.27E+03
1.44E+04
.78E+03
1.78E+04
.41E+03
2.21E+04
. 17E+03
6.
18E+03
4
1.97E-05
7.
9.
1.
1.
1.
2.
61E+03
1.70E-05
39E+03
1.47E-05
16E+04
1.27E-05
44E+04
1.11E-05
78E+04
9.76E-06
21E+04
4
4
4
4
4
4
.24E+03
1.05E+01
.24E+03
1.05E+01
.24E+03
1.05E+01
.24E+03
1.05E+01
.24E+03
1.05E+01
.24E+03
1.05E+01
.24E+03
1
1
1
2
2
2
3
.06E+03
4.67E+02
.39E+03
5.45E+02
.71E+03
6.34E+02
.06E+03
7.37E+02
. 43E+03
8.52E+02
.85E+03
9.83E+02
.31E+03
0
0
0
0
0
0
.OOE+00
.OOE+00
.OOE+00
.OOE+00
. 00£+00
.OOE+00
1.
1.
1.
2.
2.
2.
41E+02
65E+02
91E+02
21E+02
54E+02
90E+02
time averaged (tav = 1800. s) volume concentration:
in the z = .00 plane.
concentration
downwind time of cloud effective
average concentration (volume fraction) at (x,y,z)
distance max cone duration half width
y/bbc= y/bbc= y/btec= y/bbc= y/bbc=
x (m) (s) (s) bbc (m)
0.5 1.0 1.5 2.0 2.5
-1.02E+01 9.02E+02 1.80E+03 1.02E+01
0. OOE+00 0. OOE+00 0. OOE+00 0. OOE+00 0. OOE+00
-8.18E+00 9.02E+02 1.80E+03 1.04E+01
4.42E-03 1.60E-03 5.12E-05 7.08E-08 0. OOE+00
-6.13E+00 9.01E+02 1.80E+03 1.05E+01
5.14E-03 1.85E-03 7.01E-05 1.49E-07 0. OOE+00
-4.09E+00 9.01E+02 1.80E+03 1.06E+01
5.56E-03 1.99E-03 8.75E-05 2.70E-07 0. OOE+00
-2.04E+00 9.00E+02 1.80E+03 1.08E+01
5.84E-03 2.08K-03 1.04E-04 4.47E-07 1.98E-10
-1.55E-06 9.00E+02 1.80E+03 1.09E+01
6.03E-03 2.14E-03 1.20E-04 6.88E-07 4.16E-10
2.04E+00 9.00E+02 1 . 80E+03 1.11E+01
6.16E-03 2.17E-03 1.35E-04 9.97E-07 6.49E-10
4.09E+00 9.01E+02 1 . 80E+03 1.13E+01
6.25E-03 2.20E-03 1 . 50E-04 1.38E-06 1.57E-09
6.13E+00 9.01E+02 1 . 80E+03 1.14E+01
6.31E-03 2.21E-03 1.63E-04 1.82E-06 2.77E-09
8.18E+00 9.02E+02 1.80E+03 1.16E+01
6.34E-03 2.21E-03 1.76E-04 2.33E-06 4.49E-09
1.02E+01 9.02E+02 1.80E+03 1.18E+01
6.36E-03 2.21E-03 1.87E-04 2.89E-06 7.26E-09
1.04E+01 9.02E+02 1.80E+03 1.18E+01
6.29E-03 2.19E-03 1.86E-04 2.92E-06 7.68E-09
1.07E+01 9.02E+02 1.80E+03 1.18E+01
6.21E-03 2.16E-03 1.85E-04 2.96E-06 7.84E-09
1.10E+01 9.02E+02 1.80E+03 1.19E+01
6.11E-03 2.12E-03 1.84E-04 3.01E-06 8.44E-09
1.15E+01 9.03E+02 1 . 80E+03 1.19E+01
6.00E-03 2.08E-03 1.82E-04 3.07E-06 9.01E-09
1.19E+01 9.03E+02 1.80E+03 1.20E+01
5.87E-03 2.03E-03 1.80E-04 3.13E-06 9.54E-09
1.25E+01 9.03E+02 1.80E+03 1.20E+01
5.71E-03 1.98E-03 1.78E-04 3.21E-06 1.05E-08.
1.33E+01 9.03E+02 1.80E+03 1.21E+01
5.53E-03 1.91E-03 1.75E-04 3.31E-06 1.15E-08
1.42E+01 9.03E+02 1.80E+03 1.22E+01
5.33E-03 1.84E-03 1.72E-04 3.42E-06 1.31E-08
1.53E+01 9.03E+02 1.80E+03 1.23E+01
5.09E-03 1.76E-03 1.69E-04 3.56E-06 1.49E-08
1.66E+01 9.04E+02 1 . 80E+03 1.24E+01
4.83E-03 1.66E-03 1.64E-04 3.71E-06 1.7-1E-08
y/bbc=
0.0
0. OOE+00
4.77E-03
5.63E-03
6.18E-03
6.60E-03
6.92E-03
7.19E-03
7.41E-03
7.60E-03
7.75E-03
7.88E-03
7.80E-03
7.72E-03
7.61E-03
7.49E-03
7.35E-03
7.18E-03
6.98E-03
6.76E-03
6.50E-03.
6.21E-03
-------
1.82E+01
4.54E-03 1
2.02E+01
4.23E-03 1
2.25E+01
3.89E-03 1
2.55E+01
3.54E-03 1
2.90E+01
3.17E-03 1
3.33E+01
2.80E-03 9
3.86E+01
2.44E-03 8
4.50E+01
2.09E-03 6
5.29E+01
1.77E-03 5
6.24E+01
1.46E-03 4
7.40E+01
1.19E-03 3
8.82E+01
9.54E-04 3
1.05E+02
7.51E-04 2
1.27E+02
5.82E-04 1.
1.S2E+02
4.45E-04 1.
1.83E+02
3.35E-04 1.
2.21E+02
2.50E-04 8.
2.68E+02
1.84E-04 5.
3.24E+02
1.35E-04 4.
3.93E+02
9.77E-05 3.
4.77E+02
7.05E-05 2.
5.79E+02
5.07E-05 1.
7.04E+02
3.63E-05 1.
8.56E+02
2.60E-05 8.
1.04E+03
1.85E-05 6.
1.27E+03
1.32E-05 4.
1.54E+03
9.46E-06 3.
1.88E+03
6.77E-06 2.
2.28E+03
4.85E-06 1.
2.78E+03
3.49E-06 1.
3.39E+03
2.52E-06 8.
4.12E+03
1.82E-06 5.
5.04E+03
1.22E-06 3.
6.18E+03
9.04E+02 1.80E+03 1.26E+01 5.89E-03
-56E-03 1.59E-04 3.87E-06 2.05E-08
9.04E+02 1.80E+03 1.28E+01 5.53E-03
-45E-03 I.53E-04 4.05E-06 2.48E-08
9.05E+02 1.80E+03 1.31E-KH 5.14E-03
-33E-03 1.46E-04 4.24E-06 3.02E-08
9.06E+02 1.80E+03 1.34E+01 4.72E-03
-20E-03 1.37E-04 4.41E-06 3.69E-08
9.06E+02 1.80E+03 1.38E+01 4.29E-03
.08E-03 1.28E-04 4.56E-06 4.52E-08
9.07E+02 1.80E-I-03 1.43E+01 3.84E-03
-47E-04 1.17E-04 4.64E-06 5.48E-08
9.08E+02 1.80E+03 1.49E+01 3.38E-03
.20E-04 1.06E-04 4.64E-06 6.51E-08
9.10E+02 1.80E+03 1.57E+01 2.93E-03
.99E-04 9.37E-05 4.53E-06 7.48E-08
9.12E + 02 l.SOE-t-03 1.67E-1-01 2.50E-03
.87E-04 8.13E-05 4.30E-06 8.26E-08
9.14E+02 1.80E+03 1.80E-t-01 2.09E-03
.84E-04 6.89E-05 3.94E-06 8.67E-08
9.16E+02 1.80E+03 1.96E+01 1.71E-03
.92E-04 5.72E-05 3.49E-06 8.62E-08
9.19E+02 - 1.80E+03 2.16E+01 1.38E-03
.13E-04 4.64E-05 2.99E-06 8.09E-08
9.23E+02 1.80E+03 2.40E+01 1.09E-03
.45E-04 3.69E-05 2.47E-06 7.20E-08
9.28E+02 1.80E+03 2.71E+01 8.44E-04
.90E-04 2.87E-05 1.98E-06 6.10E-08
9.33E+02 1.80E+03 3.09E+01 6.46E-04
.45E-04 2.20E-05 1.55E-06 4.95E-08
9.40E+02 1.80E+03 3.55E+01 4.87E-04
.09E-04 1.66E-05 1.18E-06 3.89E-08
9.48E+02 1.80E+03 4.11E-K01 3.63E-04
.11E-05 1.24E-05 8.90E-07 2.97E-08
9.58E+02 1.80E+03 4.80E+01 2.68E-04
.98E-05 9.16E-06 6.59E-07 2.23E-08
9.71E+02 1.80E+03 5.64E-t-01 1.96E-04
-37E-05 6.70E-06 4.84E-07 1.64E-08
9.86E+02 1.80E+03 6.65E+01 1.42E-04
17E-05 4.86E-06 3.52E-07 1.20E-08
l.OOE+03 1.80E+03 7.88E+01 1.03E-04
29E-05 3.51E-06 2.54E-07 8.68E-09
1.03E+03 1.80EH-03 9.34E+01 7.37E-05
65E-05 2.52E-06 1.83E-07 6.24E-09
1.05E+03 1.80E+03 1.11E+02 5.28E-05
18E-05 1.81E-06 1.31E-07 4.47E-09
1.09E+03 1.80E+03 1.32E+02 3.78E-05
43E-06 1.29E-06 9.36E-08 3.20E-09
1.13E+03 1.80E+03 1.57E+02 2.70E-05
02E-06 9.23E-07 6.68E-08 2.29E-09
1.18E+03 1.80E+03 1.87E+02 1.93E-05
30E-06 6.59E-07 4.77E-08 1.63E-09
1.24E+03 1.80E+03 2.21E+02 1.38E-05
07E-06 4.71E-07 3.41E-08 1.16E-09
1.31E+03 l.SOE-t-03 2. 62E+02 9.85E-06
20E-06 3.37E-07 2.44E-08 8.33E-10
1.40E+03 1.80E+03 3.10E+02 7.06E-06
58E-06 2.42E-07 1.75E-08 5.95E-10
1.51E+U3 l.SOE-t-03 3.66E+02 5.08E-06
13E-06 1.74E-07 1.26E-08 4.30E-10
1.64E+03 1.80E+03 4.30E+02 3.66E-06
17E-07 1.25E-07 9.08E-09 3.12E-10
1.80E+03 1.80E+03 5.04E+02 2.65E-06
90E-07 9.05E-08 6.56E-09 2.25E-10
1.99E+03 1.82E+03 5.90E+02 1.77E-06
96E-07 6.07E-08 4.40E-09 1.49E-10
2.22E+03 1.86E+03 6.91E+02 1.23E-06
-------
8.
5.
4.
2.
2.
1.
1.
1
46E-07 2.
7.61E+03
90E-07 1.
9.39E+03
14E-07 1.
1.16E+04
93E-07 9.
1.44E+04
08E-07 6.
1.78E+04
48E-07 4.
2.21E+04
06E-07 3.
time averaged
concentration
downwind
distance
x (m)
-1.02E+01
-8.18E+00
-6.13E+00
-4.09E+00
-2.04E+00
-1.55E-06
2.04E+00
4 .09E+00
6.13E+00
8.18E+00
1.02E+01
1.04E+01
1.07E+01
1. 10E+01
1.15E+01
1. 19E+01
1.25E+01
1.33E+01
1.42E+01
1.53E+01
1.66E+01
1.82E+01
2.02E+01
2.25E+01
2.55E+01
2.90E+01
3.33E+01
3.86E+01
4.50E+01
5.29E+01
6.24E+01
7.40E+01
8.82E+01
1.05E+02
1.27E+02
1.52E+02
1.83E+02
2.21E+02
2.68E+02
3.24E+02
3.93E+02
4 .77E+02
5.79E+02
7 .04E+02
8.56E+02
75E-07 4.
2.51E+03
92E-07 2.
2.85E+03
35E-07 2.
3.27E+03
50E-08 1.
3.78E+03
74E-08 1.
4.41E+03
81E-08 7.
5.17E+03
44E-08 5.
21E-08
1.
94E-08
1.
06E-08
2.
46E-08
2.
03E-08
2.
37E-09
2.
28E-09
(tav = 1800. s)
3.05E-09
91E+03
8
2.13E-09
98E+03
9
1.49E-09
07E+03
1
1.06E-09
19E+03
7.^9
34E+03
1
E-10
1
5.34E-10
52E+03
1
3.82E-10
volume
(volume fraction) along
maximum
height
z (m)
O.OOE+00
O.OOE+00
O.OOE+00
O.OOE+00
O.OOE+00
O.OOE+00
O.OOE+00
O.OOE+00
O.OOE+00
O.OOE+00
O.OOE+00
O.OOE+00
O.OOE+00
O.OOE+00
O.OOE+00
O.OOE+00
O.OOE+00
O.OOE+00
O.OOE+00
O.OOE+00
O.OOE+00
O.OOE+00
O.OOE+00
O.OOE+00
O.OOE+00
O.OOE+00
O.OOE+00
O.OOE+00
O.OOE+00
O.OOE+00
O.OOE+00
O.OOE+00
O.OOE+00
O.OOE+00
O.OOE+00
O.OOE+00
O.OOE+00
O.OOE+00
O.OOE+00
O.OQE+00
O.OOE+00
O.OOE+00
O.OOE+00
O.OOE+00
O.OOE+00
1.05E-10
.08E+02
7.28E-11
.44E+02
5.14E-11
.10E+03
3.56E-11
.28E+03
2.61E-11
. 48E+03
1.83E-11
. 70E+03
1.30E-11
concentration:
8.5'
6.0:
4.21
3.0;
2.1!
1.5'
maximum
centerline.
time of
concentration max cone
c(x,0, z)
- 0.
4.
5.
6.
6.
6.
7.
7.
7.
7.
7.
7.
7.
7.
7.
7.
7.
6.
6.
6.
6.
5.
5.
5.
4.
4.
3.
3.
2.
2.
2.
1.
1.
1.
8.
6.
4.
3.
2.
1.
1.
1.
7 .
5.
3.
OOE+00
77E-03
63E-03
18E-03
60E-03
92E-03
19E-03
41E-03
60E-03
75E-03
88E-03
80E-03
72E-03
61E-03
49E-03
35E-03
18E-03
98E-03
76E-03
50E-03
21E-03
89E-03
53E-03
14E-03
72E-03
29E-03
84E-03
38E-03
93E-03
50E-03
09E-03
71E-03
38E-03
09E-03
44E-04
46E-04
87E-04
63E-04
68E-04
96E-04
42E-04
03E-04
37E-05
28E-05
78E-05
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
1
1
1
1
(s)
. 02E+02
.02E+02
-01E+02
. 01E+02
.OOE+02
.OOE+02
.OOE+02
. 01E+02
. 01E+02
.02E+02
. 02E+02
. 02E+02
. 02E+02
. 02E+02
.03E+02
.03E+02
. 03E + 02
.03E+02
.03E+02
.03E+02
.04E+02
.04E+02
.04E+02
. 05E+02
.06E+02
.06E+02
.07E+02
.08E+02
. 10E+02
.12E+02
. 14E+02
.16E+02
.19E+02
.23E+02
.28E+02
.33E+02
.40E+02
.48E+02
.58E+02
.71E+02
.86E+02
.OOE+03
.03E+03
.05E+03
.09E+03
cloud
duration
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
I
I
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
(s)
-80E+03
.80E+03
.SOE-t-03
.80E+03
.80E+03
.80E+03
.80E+03
. 80E+03
.80E+03
.80E+03
.80E+03
.80E+03
.80E+03
.80E+03
.80E+03
.80E+03
.80E+03
.80E+03
.80E+03
.80E+03
.80E+03
.80E+03
.80E+03
.80E+03
.80E+03
.80E+03
.80E+03
.80E+03
.80E+03
.SOE-t-03
.80E+03
.80E+03
.80E+03
.80E+03
.80E+03
.80E+03
.80E+03
.80E+03
.80E+03
.80E+03
.80E+03
.80E+03
.80E+03
.80E+03
.80E+03
-------
1
1
1
1
2
2
3
4
5
6
7
9
1
1
1
2
.04E+03
.27E+03
.54E+03
.88E+03
.28E+03
.78E+03
.39E+03
.12E+03
.04E+03
.18E+03
.61E+03
. 39E+03
. 16E+04
.44E+04
.78E+04
.21E+04
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.OOE+00
.OOE+00
.OOE+00
.OOE+00
.OOE+00
.OOE+00
.OOE+00
.OOE+00
.OOE+00
.OOE+00
.OOE+00
.OOE+00
.OOE+00
.OOE+00
.OOE+00
.OOE+00
2
1
1
9
7
5
3
2
1
1
8
6
4
3
2
1
.70E-05
.93E-05
.38E-05
.85E-06
.06E-06
.08E-06
.66E-06
.65E-06
.77E-06
.23E-06
.59E-07
.03E-07
.26E-07
. 02E-07
. 15E-07
. 54E-07
1
1
1
1
1
1
1
1
1
2
2
2
3
3
4
5
.13E+03
.18E+03
.24E+03
.31E+03
.40E+03
-51E+03
.64E+03
. 80E+03
.99E+03
.22E+03
. 51E+03
. 85E+03
.27E+03
. 78E+03
. 41E+03
. 17E+03
1
1
1
1
1
1
1
1
1
1
1
1
2
2
2
2
.80E+03
.80E+03
.80E+03
.80E+03
.80E+03
.80E+03
.80E+03
.80E+03
.82E+03
.86E+03
. 91E+03
. 98E+03
.07E+03
.19E+03
.34E+03
.52E+03
-------
RUN13.OUT
problem input
idspl =
ncalc =
wms =
cps
tbp
cmedO =
dhe
cpsl =
rhosl =
spb
spc
ts
qs
as
tsd
qtis
hs
tav
xf fm =
zp(l) =
zp(2) =
zp(3) =
zp(4) =
zO
za
ua
ta
rh
stab =
1
1
.031880
909.80
309.35
.00
1070000.
2716.00
793.70
-1.00
.00
293.00
.09
37.85
680.
.00
.00
1800.00
5000.00
.00
.00
.00
.00
.300000
10.00
3.20
293.00
68.00
4.00
release gas properties
molecular weight of source gas (kg)
3.1880E-02
vapor heat capacity, const, p. (]/kg-k)
9.0980E+02
temperature of source gas (k)
3.0935E+02
density of source gas (kg/m3)
1.2559E+00
boiling point temperature
3.0935E+02
liquid mass fraction
O.OOOOE+00
liquid heat capacity (j/kg-k)
2.7160E+03
heat of vaporization (]/kg)
1.0700E+06
liquid source density (kg/m3)
7.9370E+02
saturation pressure constant
1.3263E+01
saturation pressure constant (k)
4.1028E+03
saturation pressure constant (k)
O.OOOOE+00
wms
cps
ts
rhos =
tbp =
cmedO=
cpsl =
dhe =
rhosl=
spa =
spb =
spc =
spill characteristics
spill type
- idspl=
-------
1
mass source rate (kg/s) ~
-------
additional parameters
sub-step multiplier - ncalc =
1
number of calculational sub-steps - nssm =
3
acceleration of gravity (m/s2) - grav
9.8067E+00
gas constant (j/mol- k) - rr
8.3143E+00
von karman constant - xk =
4.1000E-01
1
instantaneous spatially averaged cloud parameters
X ZC
cv rho
-3.08E+00 O.OOE+00
3.08E+00 O.OOE+00 1
-2.46E+00 O.OOE+00
3.40E+00 1.66E-03 1
-1.85E+00 O.OOE+00
3.73E+00 2.00E-03 1
-1.23E+00 O.OOE+00
4.05E+00 2.21E-03 1
-6.15E-01 O.OOE+00
4.38E+00 2.36E-03 1
3.87E-07 O.OOE+00
4.71E+00 2.47E-03 1
6.15E-01 O.OOE+00
5.03E+00 2.56E-03 1
1.23E+00 O.OOE+00
5.36E+00 2.64E-03 1
1.85E+00 O.OOE+00
5.68E+00 2.70E-03 1
2.46E+00 O.OOE+00
6.01E+00 2.75E-03 1
3.08E+00 O.OOE+00
6.34E+00 2.79E-03 1
3.14E+00 O.OOE+00
6.41E+00 2.77E-03 1
3.22E+00 O.OOE+00
6.49E+00 2.74E-03 1
3.32E+00 O.OOE+00
6.59E+00 2.70E-03 1
3.44E+00 O.OOE+00
6.72E+00 2.66E-03 1
3.58E+00 O.OOE+00
6.87E+00 2
3.75E+00
7.05E+00 2
3.96E+00
7.28E+00 2
4.22E+00
.61E-03 1
O.OOE+00
.55E-03 1
O.OOE+00
.49E-03 1
O.OOE+00
7.55E+00 2.41E-03 1
4.53E+00 O.OOE+00
7.88E+00 2.32E-03 1
4.91E+00 O.OOE+00
8.28E+00 2.22E-03 1
5.37E+00 O.OOE+00
8.76E+00 2.12E-03 1
5.92E+00 O.OOE+00
9.35E+00 2.00E-03 1
6.60E+00 O.OOE+00
1.01E+01 1.87E-03 1
O.OOE+00
.20E+00 2
1.11E+00
.20E*00 2
1.44E+00
.20E+00 2
1.70E+00
.20E+00 2
1.91E+00
.20E+00 2
2.10E+00
.20E+00 2
2.28E+00
.20E+00 2
2.44E+00
.20E+00 2
2.60E+00
.20E+00 2
2.74E+00
.20E+00 2
2.88E+00
.20E+00 2
2.90E+00
-20E+00 2
2.91E+00
.20E+00 2
2.93E+00
.20E+00 2
2.96E+00
.20E+00 2
2.99E+00
.20E+00 2
3.03E+00
.20E+00 2
3.07E+00
.20E+00 2
3.12E+00
.20E+00 2
3.18E+00
.20E+00 2
3.26E+00
.20E+00 2
3.35E+00
.20E+00 2
3.45E+00
.20E+00 2
3.58E+00
.20E+00 2
bb b
u ua
3.08E+00 2.77E+00
.93E+02 O.OOE+00 0
3.13E+00 2.77E+00
.93E+02 6.16E-01 6
3.16E+00 2.77E+00
.93E+02 7.78E-01 7
3.20E+00 2.77E+00
.93E+02 8.88E-01 8
3.23E+00 2.77E+00
.93E+02 9.72E-01 9
3.27E+00 2.77E+00
.93E+02 1.04E+00 1
3.30E+00 2.77E+00
.93E+02 1.10E+00 1,
3.34E+00 2.77E+00
.93E+02 1.15E+OC 1.
3.37E+00 2.77E+00
.93E+02 1.20E+00 1.
3.41E+00 2.77E+00
.93E+02 1.24E+00 1.
3.44E+00 2.77E+00
.93E+02 1.28E+00 1.
3.45E+00 2.77E+00
.93E+02 1.28E+00 1.
3.45E+00 2.77E+00
.93E+02 1.29E+00 1.
3.46E+00 2.77E+00
.93E+02 1.29E+00 1.
3.46E+00 2.77E+00
.93E+02 1.30E+00 1.
3.47E+00 2.77E+00
.93E+02 1.31E+00' 1.
3.48E+00 2.77E+00
.93E+02 1.32E+00 1.
3.49E+00 2.77E+00
.93E+02 1.33E+00 1.
3.51E+00 2.78E+00
.93E+02 1.34E+00 1.
3.53E+00 2.78E+00
. 93E+02 1.36E+00 1
3.55E+00 2.78E+00
.93E+02 1.38E+00 1
3.58E+00 2.78E+00
-93E+02 1.40E+00 1
3.61E+00 2.78E+00
.93E+02 1.42E+00 1
3.65E+00 2.78E+00
.93E+02 1.45E+00 1
bbx
3.08E+00
OOE+00
3.40E+00
18E-01
3.73E+00
80E-01
4.05E+00
90E-01 .
4.38E+00
74E-01
4.71E+00
04E+00
5.03E+00
10E+00
5.36E+00
16E+00
5.69E+00
20E+00
6.01E+00
24E+00
6.34E+00
28E+00
6.41E+00
29E+00
6.49E+00
29E+00
6.59E+00
30E+00
6.72E+00
30E+00
6.87E+00
31E+00
7.06E+00
32E+00
7.28E+00
33E+00
7.55E+00
35E+00
7.88E+00
36E+00
8.28E+00
38E+00
8.76E+00
40E+00
9.35E+00
43E+00
1.01E+01
46E+00
bx
-------
7.41E+00
1.09E+01 1
8.41E+00
1.20E+01 1
9.62E+00
1.33E+01 1
1.11E+01
1.48E+01 1
1.29E+01
1.67E+01 1
1.50E+01
1.90E+01 1
1.76E+01
2.18E+01 8
2.08E+01
2.51E+01 7
2.47E+01
2.92E+01 6
2.94E+01
3.42E+01 5
3.51E+01
4.02E+01 4
4.20E+01
4.76E+01 3
5.04E+01
5.65E+01 2
6.06E+01
6.73E+01 2
7.29E+01
8.04E+01 1
8.79E+01
9.63E+01 1.
1.06E+02
1.16E+02 1.
1.28E+02
1.39E+02 8.
1.55E+02
1.68E+02 6.
1.88E+02
2.02E+02 4.
2.27E+02
2.44E+02 3.
2.75E+02
2.95E+02 2.
3.34E+02
3.57E+02 1.
4.05E+02
4.32E+02 1.
4.90E+02
5.23E+02 9.
5.95E+02
6.34E+02 6.
7.22E+02
7.68E+02 5.
8.75E+02
9.31E+02 3.
1.06E+03
1.13E+03 2.
1.29E+03
1.37E+03 1.
1.57E+03
1.37E+03 1.
1.92E+03
1.37E+03 8.
2.36E+03
1.37E+03 5.
2.91E+03
O.OOE+00
.74E-03 1
O.OOE+00
.59E-03 1
O.OOE+00
.45E-03 1
O.OOE+00
.30E-03 1
O.OOE-f-00
.16E-03 1
O.OOE+00
.02E-03 1
O.OOE+00
.83E-04 1
O.OOE+00
.57E-04 1
O.OOE+00
.41E-04 1
O.OOE+00
.36E-04 1
O.OOE+00
.42E-04 1
O.OOE+00
.60E-04 1
O.OOE+00
.90E-04 1
O.OOE+00
.30E-04 1
0.OOE+00
.81E-04 1
O.OOE+00
.40E-04 1
O.OOE+00
.08E-04 1.
O.OOE+00
.19E-05 1.
O.OOE+00
.16E-05 1.
0.OOE+00
.60E-05 1.
O.OOE+00
.40E-OS 1.
O.OOE+00
50E-05 1.
O.OOE+00
83E-05 1.
O.OOE+00
33E-05 1.
O.OOE+00
66E-06 1.
O.OOE+00
98E-06 1.
O.OOE+00
04E-06 1.
O.OOE+00
63E-06 1.
O.OOE+00
61E-06 1.
O.OOE+00
88E-06 1.
O.OOE+00
29E-06 1.
O.OOE+00
81E-07 1.
O.OOE+00
95E-07 1.
O.OOE+00
3.72E+00
.20E+00 2
3.89E+00
.20E+00 2
4.09E+00
.20E+00 2
4.33E+00
.20E+00 2
4.60E+00
.20E+00 2
4.91E+00
.20E+00 2
5.27E+00
.20E+00 2
5.69E+00
.20E+00 2
6.16E+00
.20E+00 2
6.71E+00
.20E+00 2
7.34E+00
.20E+00 2
8.06E+00
-20E+00 2
8.89E+00
.20E+00 2
9.83E+00
.20E+00 2
1.09E+01
.20E+00 2
1.21E+01
.20E+00 2.
1.36E+01
.20E+00 2.
1.52E+01
.20E+00 2.
1.70E+01
.20E+00 2.
1.92E+01
.20E+00 2.
2.16E+01
.20E+00 2.
2.44E+01
20E+00 2.
2.77E+01
20E+00 2.
3.14E+01
20E+00 2.
3.56E+01
20E+00 2.
4.05E+01
20E+00 2.
4.61E+01
20E+00 2.
5.25E+01
20E+00 2.
6.00E+01
20E+00 2.
6.85E+01
20E+00 2.
8.05E+01
20E+00 2.
9.45E+01
20E+00 2.
1.11E+02
20E+00 2.
1.30E+02
3.70E+00
.93E+02 1
3.75E+00
.93E+02 1
3.82E+00
.93E+02 1
3.91E+00
.93E+02 1
4.01E+00
.93E+02 1
4.14E+00
.93E+02 1
4.29E+00
.93E+02 1
4.48E+00
.93E+02 1
4.70E+00
.93E+02 1
4.98E+00
.93E+02 1
5.31E+00
.93E+02 2
5.71E+00
.93E+02 2
6.19E+00
.93E+02 2
6.77E+00
.93E+02 2
7.48E+00
.93E+02 2
8.33E+00
.93E+02 2.
9.35E+00
.93E+02 2.
1.06E+01
.93E+02 2.
1.21E+01
.93E+02 2.
1.39E+01
93E+02 2.
1.60E+01
93E+02 3.
1.86E+01
93E+02 3.
2.17E+01
93E+02 3.
2.54E+01
93E+02 3.
2.99E+01
93E+02 3.
3.52E+01
93E+02 3.
4.15E+01
93E+02 3.
4.90E+01
93E+02 3.
5.79E+01
93E+02 3.
6.84E+01
93E+02 4.
8.09E+01
93E+02 4.
9.60E+01
93E+02 4.
1.14E+02
93E+02 4.
1.36E+02
2.78E+00
.49E+00 1
2.78E+00
.52E+00 1
2.79E+00
.56E+00 1
2.79E+CO
.61E+00 1
2.79E+00
.66E+00 1
2.80E+00
.71E+00 1
2.80E+00
.77E+00 1
2.81E+00
.84E+00 1
2.81E+00
.91E+00 1
2.82E+00
.98E+00 1
2.83E+CO
.06E+00 2
2.84E+00
.14E+00 2
2.85E+00
.22E+00 2
2.86E+00
.31E+00 2
2.87E+00
.40E+00 2
2.88E+00
.50E+00 2.
2.89E+00
.59E+00 2.
2.90E+00
.69E+00 2.
2.90E+00
.80E+00 2.
2.91E+00
90E+00 2.
2.92E+00
01E+00 3.
2.93E+00
11E+00 3.
2.93E+00
22E+00 3.
2.94E+00
34E+00 3.
2.94E+00
45E+00 3.
2.94E+00
56E+00 3.
2.95E+00
68E+00 3.
2.95E+00
79E+00 3.
2.95E+00
91E+00 3.
2.95E+00
03E+00 4.
2.95E+00
17E+00 4.
2.95E+00
31E+00 4.
2.95E+00
45E+00 4.
2.95E+00
1.09E+01
.49E+00
1.20E+01
.52E+00
1.33E+01
.57E+00
1.48E+01
.61E+00
1.67E+01
.66E+00
1.90E+01
.72E+00
2.18E+01
.78E+00
2.51E+01
.84E+00
2.92E+01
.91E+00
3.42E+01
.98E+00
4.02E+01
.06E+00
4.76E+01
.14E+00
5.65E+01
.22E+00
6.73E+01
.31E+00
8.04E+01
.40E+00
9.63E+01
.50E+00
1.16E+02
. 59E+00
1.39E+02
.69E+00
1.68E+02
.80E+00
2.02E+02
90E+00
2.44E+02
01E+00
2.95E+02
12E+00
3.57E+02
23E+00
4.32E+02
34E+00
5.23E+02
45E+00
6.34E+02
56E+00
7.68E+02
68E+00
9.31E+02
80E+00
1.13E+03
91E+00
1.37E+03
03E+00
1.43E+03
17E+00
1.51E+03
31E+00
1.60E+03
45E+00
1.71E+03
-------
1.37E+03 4.00E-07 1.20E+00 2.93E+02 4.58E+00 4.59E+00
3.61E+03 O.OOE+00 1.52E+02 1.61E+02 2.95E+00 1.85E+03
1.37E+03 2.67E-07 1.20E+00 2.93E+02 4.72E+00 4.72E+00
4.47E+03 O.OOE+00 1.77E+02 1.91E+02 2.95E+00 2.01E+03
1.37E+03 1.77E-07 1.20E+00 2.93E+02 4.85E+00 4.85E+00
5.54E+03 O.OOE+00 2.07E+02 2.26E+02 2.95E+00 2.21E+03
1.37E+03
1 .
1.17E-07 1.20E+00 2.93E+02 4. 98E-t-00 4.98E+00
x cm cmv
vg ug w
-3.08E+00 O.OOE+00
O.OOE+00 O.OOE+00 0
-2.46E+00 1.84E-03
O.OOE+00 1.21E-04 0
-1.85E+00 2.21E-03
O.OOE+00 3.07E-04 0
-1.23E+00 2.45E-03
O.OOE+00 5.23E-04 0
-6.15E-01 2.61E-03
O.OOE+00 7.59E-04 0
3.87E-07 2.74E-03
O.OOE+00 1.01E-03 0
6.15E-01 2.84E-03
O.OOE+00 1.27E-03 0
1.23E+00 2.92E-03
O.OOE+00 1.55E-03 0
1.85E+00 2.99E-03
O.OOE+00 1.83E-03 0
2.46E+00 3.04E-03
O.OOE+00 2
3.08E+00
cmda
cmw
.12E-03 0
3.09E-03
O.OOE+00 2.41E-03 0
3.14E+00 3.06E-03
O.OOE+00 2.44E-03 0
3.22E+00 3.03E-03
O.OOE+00 2.48E-03 0
3.32E+00 2.99E-03
O.OOE+00 2.52E-03 0.
3.44E+00 2.94E-03
O.OOE+00 2.57E-03 0.
3.58E+00 2.89E-03
O.OOE+00 2.64E-03 0.
3.75E+00 2.83E-03
O.OOE+00 2.71E-03 0.
3.96E+00 2.75E-03
O.OOE+00 2.80E-03 0.
4.22E+00 2.67E-03
O.OOE+00 2.90E-03 0.
4.53E+00 2.57E-03
O.OOE+00 3.01E-03 0.
4.91E+00 2.46E-03
O.OOE+00 3.14E-03 0.
5.37E+00 2.34E-03
O.OOE+00 3.29E-03 0.
5.92E+00 2.21E-03
O.OOE+00 3.45E-03 0.
6.60E+00 2.07E-03
O.OOE+00 3.63E-03 0.
7.41E+00 1.92E-03
O.OOE+00 3.83E-03 0.
8.41E+00 1.77E-03
O.OOE+00 4.03E-03 0.
9.62E+00 1.60E-03
O.OOE+00 4.25E-03 0.
1.11E+01 1.44E-03
O.OOE+00 4.46E-03 0.
O.OOE+00
.OOE+00 4
1.84E-03
.OOE+00 4
2.21E-03
.OOE+00 3
2.45E-03
.OOE+00 3
2.61E-03
.OOE+00 3
2.74E-03
. OOEx-00 3
2.84E-03
.OOE+00 2
2.92E-03
.OOE+00 2
2.99E-03
.OOE+00 2
3.04E-03
.OOE+00 2
3.09E-03
.OOE+00 2
3.06E-03
.OOE+00 2
3.03E-03
.OOE+00 2
2.99E-03
.OOE+00 2.
2.94E-03
.OOE+00 2.
2.89E-03
.OOE+00 2.
2.83E-03
.OOE+00 2.
2.75E-03
.OOE+00 2.
2.67E-03
.OOE+00 2.
2.57E-03
.OOE+00 2.
2.46E-03
.OOE+00 2.
2.34E-03
.OOE+00 2.
2.21E-03
OOE+00 2.
2.07E-03
OOE+00 2.
1.92E-03
OOE+00 2.
1.77E-03
OOE+00 2.
1.60E-03
OOE+00 2.
1.44E-03
OOE+00 2.
V VX
9.90E-01 1.01E-02
.80E-01 1.04E-01 0
9.88E-01
.55E-01 1
9.88E-01
.79E-01 2
9.87E-01
.43E-01
9.87E-01
.20E-01 3.13E-02 3
9.87E-01 1.01E-02
.05E-01 3.36E-02 3
9.87E-01 1.01E-02
1.01E-02
.99E-02 2
1.01E-02
.51E-02 3
1.01E-02
2.86E-02 3
1.01E-02
.92E-01 3.
9.87E-01
.83E-01 3.
9.87E-01
55E-02 3
1.01E-02
72E-02 3
1.01E-02
.75E-01 3.87E-02 3.
9.87E-01 1.01E-02
.68E-01 4.00E-02 4.
9.87E-01 1.01E-02
.62E-01 4.12E-02 4.
9.87E-01 1.01E-02
.61E-01 4.14E-02 4.
9.87E-01 1.01E-02
.60E-01 4.15E-02 4.
9.87E-01 1.01E-02
.60E-01 4.17E-02 4.
9.87E-01 1.01E-02
.59E-01 4.19E-02 4.
9.87E-01 1.01E-02
.57E-01 4.22t-02 4.
9.87E-01 1.01E-02
.56E-01 4.25E-02 4.
9.87E-01 1.01E-02
.55E-01 4.28E-02 4.
9.87E-01 1.01E-02
.53E-01 4.33E-02 4.
9.87E-01 1.01E-02
.51E-01 4.38E-02 4.
9.87E-01 1.01E-02
.48E-01 4.44E-02 4.
9.88E-01 1.01E-02
45E-01 4
9.88E-01
42E-01 4
9.88E-01
39E-01 4.67E-02 4.
9.88E-01 1.01E-02
35E-01 4.78E-02 4.
9.88E-01 1.01E-02
31E-01 4.89E-02 4.
9.88E-01 1.01E-02
27E-01 5.02E-02 4.
9.88E-01 1.01E-02
22E-01 5.17E-02 4.
.50E-02 4.
1.01E-02
.58E-02 4.
1.01E-02
cmwv
1.01E-02
.OOE+00
1.01E-02
.84E-01
1.01E-02
.20E-01
1.01E-02
.42E-01
1.01E-02
-57E-01
1.01E-02
.69E-01
1.01E-02
.79E-01
1.01E-02
.87E-01
1.01E-02
.94E-01
1.01E-02
.OOE-01
1.01E-02
.05E-01
1.01E-02
.06E-01
1.01E-02
.06E-01
1.01E-02
.07E-01
1.01E-02
.08E-01
1 .01E-02
09E-01
1.01E-02
11E-01
1.01E-02
12E-01
1.01E-02
14E-01
1.01E-02
16E-01
1.01E-02
18E-01
1.01E-02
21E-01
1.01E-02
24E-01
1.01E-02
28E-01
1.01E-02
31E-01
1.01E-02
36E-01
1.01E-02
40E-01
1.01E-02
45E-01
-------
9.78E-04
0.
0.
0.
0.
0.
0.
0.
0.
0.
27E-03 0
5.93E-04
32E-03 0
4.90E-04
30E-03 0
3.99E-04
22E-03 0
3.21E-04
07E-03 0
2.55E-04
1.29E+01
O.OOE+00 4
1.50E+01
O.OOE+00 4
1.76E+01
O.OOE+00 5
2.08E+01
O.OOE+00 5
2.47E+01
O.OOE+00 5
2.94E+01
.OOE+00 5
3.51E+01
OOE+00 5
4.20E+01
OOE+00 5
5.04E+01
OOE+00 5
6.06E+01
OOE+00 4
7.29E+01
OOE+00 4.
8.79E+01
OOE+00 4
1.06E+02
OOE+00 3.
1.28E+02
OOE+00 3.
1.55E+02
OOE+00 3.
1.88E+02
O.OOE+00 2.
2.27E+02
O.OOE+00 2.
2.75E+02
OOE+00 2.13E-03
3.34E+02 2.03E-05
OOE+00 1
4.05E+02
O.OOE+00 1
4.90E+02
OOE+00 1
5.95E+02
O.OOE+00 1
7.22E+02
O.OOE+00 9
8.75E+02
O.OOE+00 7
1.06E+03
O.OOE+00 6.63E-04
1.29E+03 2.08E-06
OOE+00 5
1.57E+03
O.OOE+00 4
1.92E+03
O.OOE+00 3
2.36E+03
2.69E-05 0
1.28E-03 1.28E-03
67E-03 O.OOE+00 2
1.13E-03
86E-03 0
1.13E-03
OOE+00 2
9.78E-04
04E-03 O.OOE+00 2
8.38E-04 8.38E-04
18E-03 O.OOE+00 2
7.10E-04 7.10E-04
OOE+00 1
5.93E-04
,OOE+00 1
4.90E-04
OOE+00 1
3.99E-04
OOE+00 1
3.21E-04
OOE+00 1
2.55E-04
86E-03 O.OOE+00 1
2.00E-04 2.00E-04
O.OOE+00 1
59E-03
1.56E-04
27E-03 0
1.19E-04
92E-03 0
9.07E-05
55E-03 0
6.82E-05
1.&6E-04
OOE+00 1
1.19E-04
OOE+00 1
9.07E-05
OOE+00 1
6.82E-05
0.
0.
0
18E-03 O.OOE+00 1
5.09E-05 5.09E-05
81E-03 O.OOE+00 1
3.77E-05 3.77E-05
45E-03 O.OOE+00 1
2.77E-05 2.77E-05
O.OOE+00 1,
9.89E-01
.17E-01 5
9.89E-01
.12E-01 5
9.89E-01
.07E-01 5
9.89E-01
.01E-01 5
9.89E-01
.96E-01 6
9.89E-01
. 91E-01 6
9.89E-01
.85E-01 6
9.89E-01
.80E-01 6
9.90E-01
.75E-01 7,
9.90E-01
69E-01 7.
9.90E-01
64E-01 7.
9.90E-01
60E-01 7.
9.90E-01
55E-01 8.
9.90E-01
50E-01 8.
9.90E-01
46E-01 8.
9.90E-01
41E-01 8.
9.90E-01
37E-01 9.
9.90E-01
33E-01 9.
9.90E-01
2.03E-05
84E-03 O.OOE+00 1.29E-01 9
1.48E-05 1.48E-05 9.90E-01
OOE+00 1
1.07E-05
OOE+00 1
7.73E-06
OOE+00 1
5.58E-06
OOE+00 1
4.02E-06
1.01E-02
.33E-02 4
1.01E-02
.50E-02 4
1.01E-02
.69E-02 4
1.01E-02
.89E-02 4
1.01E-02
.11E-02 4
1.01E-02
.33E-02 4
1.01E-02
.57E-02 4
1.01E-02
. 82E-02 4
1.01E-02
,08E-02 4
1.01E-02
34E-02 5,
1.01E-02
61E-02 5.
1.01E-02
89E-02 5.
1.01E-02
17E-02 5.
1.01E-02
44E-02 5.19E-01
1.01E-02 1.01E-02
72E-02 5.23E-01
1.01E-02 1.01E-02
99E-02 5.27E-01
1.01E-02 1.01E-02
25E-02 5
1.01E-02
51E-02 5
1.01E-02
1.01E-02
.50E-OI
1.01E-02
.56E-01
1.01E-02
. 62E-01
1.01E-02
. 67E-01
1.01E-02
.73E-01
1.01E-02
79E-01
1.01E-02
85E-01
1.01E-02
90E-01
1.01E-02
96E-01
1.01E-02
01E-01
1.01E-02
06E-01
1.01E-02
11E-01
1.01E-02
15E-01
1.01E-02
58E-03 0
1.07E-05
34E-03 0
7.73E-06
13E-03 0
5.58E-06
43E-04 0
4.02E-06
0
2.91E+03
92E-04 O.OOE+00 1
2.89E-06 2.89E-06
O.OOE+00 1.
2.08E-06
, 75E-05 1.
1.43E-06
. 16E-05 9.
9.75E-07
72E-05 9.
6.59E-07
OOE+00 9.
4.43E-07
.25E-01 9
9.90E-01
.21E-01 1
9.90E-01
. 18E-01 1
9.90E-01
.14E-01 1
9.90E-01
.11E-01 1
9.90E-01
.74E-02 5
1.01E-02
. 96E-02 5
1.01E-02
01E-01 5
1.01E-02
03E-01 5
1.01E-02
04E-01 5
1.01E-02
05E-01 5,
1.01E-02
50E-04 2
1.43E-06
30E-04 2
9.75E-07
34E-04 1
6.59E-07
OOE+00 0
4.43E-07
.81E-05 O.OOE+00 0
3.61E+03 2.95E-07
, OOE+00
07E-01 1.06E-01 5
9.90E-01 1.01E-02
04E-01 1.05E-01 5
9.90E-01 1.01E-02
98E-02 1.05E-01 5
9.90E-01 1.01E-02
58E-02 1.05E-01 5
9.90E-01 1.01E-02
18E-02 1.03E-01 5
9.90E-01
4.47E+03
.65E-05 7
1.96E-07
OOE+00 8.78E-02 1
2.95E-07 9.90E-01
8.38E-02
1.01E-02
01E-01 5
1.01E-02
.30E-01
1.01E-02
. 33E-01
1.01E-02
. 35E-01
1.01E-02
38E-01
1.01E-02
40E-01
1.01E-02
42E-01
1.01E-02
43E-01
1.01E-02
45E-01
1.01E-02
46E-01
1.01E-02
46E-01
1.01E-02
30E-01
1.01E-02
29E-01
1.01E-02
28E-01
1.01E-02
25E-01
1.01E-02
33E-06
1.96E-07
9.76E-02 5.23E-01
9.08E-06 O.OOE+00 O.OOE+00 7
5.54E+03 1.30E-07 1.30E-07
76E-05 O.OOE+00 O.OOE+00
9.90E-01
97E-02 9
9.90E-01
7.55E-02
1.01E-02
40E-02 5.
1.01E-02
1.01E-02
19E-01
1.01E-02
8.98E-02 5.15E-01
-------
time averaged (tav = 1800. s) volume concentration: concentration
contour parameters
c(x,y,z,t) = cc(x) * (erf(xa)-erf(xb)) * (erf(ya)-erf(yb)) *
(exp(-za*za)+exp(-zb*zb))
c(x,y,z,t) = concentration (volume fraction) at (x,y,z,t)
x = downwind distance (m)
y = crosswind horizontal distance (m)
z = height (m)
t = time (s)
erf = error
functon
xa = (x-xc+bx) / (sr2*betax)
xb = (x-xc-bx) / (sr2*betax)
ya = (y+b) / (sr2*betac)
yb = (y-b) / (sr2*betac)
exp = exponential function
za = (z-zc)
zb = (z+zc)
/ (sr2*sig)
/ (sr2*sig)
sr2 = sqrt(2.0)
t
X
xc
-3.08E+00
1
.76E+00
0
-2.46E+00
2
.08E+00
3
-1.85E+00
2
.39E+00
6
-1.23E+00
2
3
3
3
4
4
5
5
5
5
6
6
6
6
7
7
7
8
.75E+00
-6.15E-01
.10E+00
3.87E-07
.49E+00
6.15E-01
.88E+00
1.23E+00
.31E+00
1. 85E+00
.74E+00
2.46E+00
. 20E+00
3.08E+00
. 67E+00
3.14E+00
.77E+00
3.22E+00
.89E+00
3.32E+00
.05E+00
3.44E+00
.23E+00
3.58E+00
. 45E+00
3.75E+00
.71E+00
3.96E+00
.03E+00
4.22E+00
. 41E+00
4.53E+00
. 87E+00
4.91E+00
.42E+00
9
1
1
1
2
2
2
3
3
3
3
3
3
3
3
4
4
4
cc(x)
b(x)
betac (x)
zc(x)
sig(x)
(t) bx(t) betax(t)
O.OOE+00
.OOE+00 3.
3.24E-04
. 08E-01 3.
3. 95E-04
. 15E-01 3.
4.42E-04
.23E-01 4.
4.78E-04
.23E+00 4.
5.07E-04
.54E+00 4.
5.33E-04
.85E+00 5.
5.55E-04
.15E+00 5.
5.76E-04
.46E+00 5.
5.95E-04
.77E+00 6.
6.12E-04
.08E+00 6.
6.08E-04
.14E+00 6.
6.02E-04
.22E+00 6.
5.95E-04
.32E-HOO 6.
5.88E-04
.44E+00 6.
5.79E-04
.58E+00 6.
5.68E-04
.75E+00 7.
5.56E-04
.96E+00 7.
5.42E-04
.22E+00 7.
5.26E-04
. 53E+00 7.
5.08E-04
.91E+00 8.
2.77E+00
08E+00 2.
2.77E+00
40E+00 2.
2.77E+00
73E+00 3.
2.77E+00
05E+00 3.
2.77E+00
38E+00 3.
2.77E+00
71E+00 3.
2.77E+00
03E+00 4.
2.77E-t-00
36E+00 4.
2.77E+00
68E+00 4.
2.77E+00
01E+00 4.
2.77E+00
34E+00 5.
2.77E+00
41E+00 5.
2.77E+00
49E-I-00 5.
2.77E+00
59E+00 5.
2.77E-HOO
72E+00 5.
2.77E+00
87E+00 5.
2.77E+00
05E+00 5.
2.77E+00
28E+00 5.
2.78E+00
55E+00 6.
2.78E+00
88E+00 6.
2.78E+00
28E+00 6.
7.74E-01
51E-02
8.42E-01
78E-02
8.87E-01
04E-02
9.32E-01
31E-02
9.77E-01
58E-02
1.02E+00
84E-02
1.07E+00
11E-02
1.11E+00
38E-02
1 . 16E+00
64E-02
1.20E+00
91E-02
1.25E+00
17E-02
1.26E+00
23E-02
1.26E+00
30E-02
1.27E+00
38E-02
1.28E+00
49E-02
1.29E+00
61E-02
1.30E+00
76E-02
1.32E+00
94E-02
1.34E+00
17E-02
1.36E+00
43E-02
1.39E+00
76E-02
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
OOE+00
OOE+00
OOE+00
OOE+00
OOE+00
OOE+00
OOE+00
OOE+00
OOE+00
OOE+00
OOE+00
OOE+00
OOE+00
OOE+00
OOE+00
OOE+00
OOE+00
OOE+00
OOE+00
OOE+0^
OOE+00
0
6
8
9
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
.OOE+00
.40E-01
.33E-01
.80E-01
.10E+00
-22E+00
. 32E+00
.41E+00
. 50E+00
. 58E+00
. 66E+00
. 67E+00
. 68E+00
. 69E+00
.71E+00
.73E+00
. 75E+00
. 77E+00
. 80E+00
.84E+00
. 88E+00
-------
9
9
1
1
1
1
1
1
2
2
2
3
3
4,
4.
5,
6.
7 .
8.
1.
1.
1.
1.
1.
2.
2.
3.
3.
4.
4.
5.
6.
7.
5.37E+00
.08E+00 5
5.92E+00
.87E+00 5
6.60E+00
. 08E+01 6
7.41E+00
.19E+01 7
8.41E+00
. 32E+01 8
9.62E+00
.48E+01 9
1. 11E+01
. 67E+01 1
1.29E+01
.88E+01 1
1.50E+01
.14E+01 1
1.76E+01
.44E+01 1
2.08E+01
.79E+01 2
2.47E+01
.20E+01 2
2.94E+01
.69E+01 2
3.51E+01
.25E+01 3
4.20E+01
. 91E+01 4.
5.04E+01
4 .89E-04
.37E+00 8
4.67E-04
.92E+00 9
4 .44E-04
.60E+00 1
4 .20E-04
.41E+00 1
3. 95E-04
.41E+00 1
3.69E-04
-62E+00 1
3.43E-04
.11E+01 1
3. 18E-04
.29E+01 1
2. 93E-04
. 50E+01 1
2.69E-04
.76E+01 2
2.47E-04
. 08E+01 2
2.26E-04
.47E+01 2
2.06E-04
.94E+01 3
1.88E-04
.51E+01 4
1.71E-04
.20E+01 4
1.55E-04
.68E+01 5.04E+01 5
6.06E+01
.58E+01 6.
7.29E+01
.63E+01 7.
8.79E+01
85E+01 8.
1.06E+02
03E+02 1.
1.28E+02
20E+02 1.
1.55E+02
39E+02 1.
1.88E+02
62E+02 1.
2.27E+02
89E+02 2.
2.75E+02
20E+02 2.
3.34E+02
57E+02 3.
4.05E+02
OOE+02 4 .
4. 90E+02
51E+02 4.
5.95E+02
10E+02 5.
7.22E+02
80E+02 7.
8.75E+02
63E+02 8.
1.06E+03
60E+02 1.
1.29E+03
74E+02 1.
1.57E+03
1.41E-04
.06E+01 6,
1.27E-04
.29E+01 8.
1 . 14E-04
79E+01 9.
1.02E-04
06E+02 1.
9.10E-05
28E+02 1.
8.07E-05
55E+02 1.
7.13E-05
88E+02 2.
6.26E-05
27E+02 2.
5.48E-05
75E+02 2.
4 .78E-05
34E+02 3.
4.15E-05
05E+02 4.
3.59E-05
90E+02 5.
3.10E-05
95E+02 6.
2.67E-05
22E+02 7.
2.29E-05
75E+02 9.
1.97E-05
06E+03 1.
1.68E-05
29E+03 1.
1.45E-05
2.78E+00
.76E+00 7
2.78E+00
.35E+00 7
2.78E+00
.01E+01 8
2.78E+00
.09E-I-01 8
2.78E+00
.20E+01 9
2.79E+00
.33E+01 1
2.79E+00
.48E+01 1
2.79E+00
.67E+01 1
2.80E+00
. 90E+01 1
2.80E+00
. 18E+01 1
2.81E+00
. 51E+01 2
2.8-1E+00
. 92E+01 2
2.82E+00
.42E+01 2
2.83E+00
. 02E+01 3
2.84E+00
.76E+01 3
2.85E+00
. 65E+01 4
2.86E+00
.73E+01 5
2.87E+00
.04E+01 6.
2. 88E+00
,63E+01 7.
2.89E+00
16E+02 9.
2.90E+00
39E+02 1.
2.90E+00
68E+02 1.
2.91E+00
02E+02 1.
2.92E+00
44E+02 1.
2.93E+00
95E+02 2.
2.93E+00
57E+02 2.
2.94E+00
32E+02 3.
2.94E+00
23E+02 4.
2.94E+00
34E+02 5.
2.95E+00
68E+02 6.
2.95E+00
31E+02 7.
2.95E+00
13E+03 9.
2.95E+00
37E+03 1.
2. 95E+00
1.42E+00
.16E-02
1.46E+00
.64E-02
1.51E+00
.22E-02
1.58E+00
-93E-02
1.65E+00
.79E-02
1.74E+00
.08E-01
1.85E+00
.21E-01
1.99E+00
.36E-01
2.15E+00
.55E-01
2.35E+00
.78E-01
2.59E+00
.05E-01
2.88E+00
. 39E-01
3.24E+00
. 79E-01
3.67E+00
.29E-01
4.19E+00
.88E-01
4 .82E+00
.61E-01
S.59E+00
.49E-01
6.51E+00
. 56E-01
7.63E+00
.86E-01
8.99E+00
.44E-01
1.06E+01
14E+00
1.26E+01
37E+00
1.50E+01
65E+00
1.79E+01
99E+00
2.13E+01
41E+00
2.55E+01
91E+00
3.05E+01
53E+00
3.65E+01
27E+00
4.36E+01
17E+00
5.21E+01
27E+00
6.23E+01
60E+00
7.42E+01
22E+00
8.84E+01
12E+01
1.05E+02
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
3.
.OOE+00
.OOE+00
.OOE+00
.OOE+00
.OOE+00
.OOE+00
.OOE+00
.OOE+00
.OOE+00
.OOE+00
.OOE+00
.OOE+00
.OOE+00
.OOE+00
.OOE+00
.OOE+00
.OOE+00
.OOE+00
, OOE+00
OOE+00
OOE+00
OOE+00
OOE+00
OOE+00
OOE+00
OOE+00
OOE+00
OOE+00
OOE+00
OOE+00
OOE+00
OOE+00
OOE+00
OOE+00
1
1
J.
2
2
2
2
2
2
2
3
3
3
3
4
4
5
5
6
7,
7.
8.
9.
1.
1.
1.
1.
1.
2.
2.
2.
3.
3.
3.
4.
.93E+00
.99E+00
.06E+00
.15E+00
.25E+00
.36E+00
.50E+00
.65E+00
. 83E+00
. 04E+00
. 28E+00
. 56E+00
. 88E+00
.24E+00
. 66E+00
. 13E+00
. 68E+00
.30E+00
.01E+00
. 83E+00
77E+00
84E+00
11E+01
25E+01
41E+01
60E+01
81E+01
06E+01
34E+01
66E+01
03E+01
46E+01
95E+01
65E+01
-------
7.
8.
9.
1.
1.
1.
1.
.48E+02
1.92E+03
. 31E+02
2.36E+03
.32E+02
2.91E+03
.05E+03
3.61E+03
.20E+03
4 .47E+03
38E+03
5.54E+03
60E+03
1
1
2
2
3
4
5
.57E+03
1.24E-05
. 92E+03
1.07E-05
.36E+03
9.24E-06
.91E+03
8.00E-06
.61E+03
6.95E-06
. 47E+03
6.05E-06
.54E+03
1
1
1
1
1
1
1
.37E+03
2.95E+00
.37E+03
2.95E+00
.37E+03
2.95E+00
.37E+03
2.95E+00
.37E+03
2.95E+00
.37E+03
2.95E+00
. 37E+03
2
3
4
5
7
8
9
.43E+02
1.26E+02
.65E+02
1.52E+02
.79E+02
1.83E+02
.93E+02
2.20E+02
.15E-02
2.64E+02
.49E+02
3.17E+02
. 98E+02
0
0
0
0
0
0
.OOE+00
.OOE+00
.OOE+00
.OOE+00
. OOE+OO
.00c,+00
5
6
7
8
1
1
.46E+01
.40E+01
.50E-K01
. 77E+01
. 02E+02
. 19E+02
1
time averaged (tav = 1800. s) volume concentration: concentration
in the z = .00 plane.
downwind time of cloud effective
average concentration (volume fraction) at (x,y,z)
distance max cone duration
y/bbc= y/bbc= y/bbc= y/bbo
x (m) (s) (s)
0.5 1.0 1.5 2.0
-3.08E+00 3.41E+02 6.80E+02 3
0.OOE+00 0.OOE+00 0.OOE+00 0.OOE+00
-2.46E+00 3.41E+02 6.80E+02 3
9.03E-04 3.27E-04 1.09E-05 1.67E-08
-1.85E+00 3.40E+02 6.80E+02 3
1.08E-03 3.89E-04 1.52E-05 3.49E-08
-1.23E+00 3.40E+02 6.80E+02 3
1.19E-03 4.26E-04 1.91E-05 6.22E-08
-6.15E-01 3.40E+02 6.80E+02 3
1.26E-03 4.50E-04 2.28E-05 l.OOE-07
3.87E-07 3.40E+02 6.80E+02 3
1.32E-03 4.67E-04 2.63E-05 1.51E-07
6.15E-01 3.40E+02 6.80E+02 3
1.36E-03 4.78E-04 2.96E-05 2.14E-07
1.23E+00 3.40E+02 6.80E+02 3
1.38E-03 4.87E-04 3.27E-05 2.90E-07
1.85E+00 3.40E+02 6.80E+02 3
1.41E-03 4.93E-04 3.56E-05 3.78E-07
2.46E+00 3.41E+02 6.80E+02 3
1.42E-03 4.96E-04 3.84E-05 4.78E-07
3.08E+00 3.41E+02 6.80E+02 3
1.43E-03 4.99E-04 4.09E-05 5.88E-07
3.14E+00 3.41E+02 6.80E+02 3
1.42E-03 4.94E-04 4.07E-05 5.94E-07
3.22E+00 3.41E+02 6.80E+02 3
1.40E-03 4.87E-04 4.05E-05 6.01E-07
3.32E+00 3.41E+02 6.80E+02 3
1.38E-03 4.80E-04 4.02E-05 6.10E-07
3.44E+00 3.41E+02 6.80E+02 3
1.36E-03 4.72E-04 3.99E-05 6.20E-07
3.58E+00 3.41E+02 6.80E+02 3
1.33E-03 4.62E-04 3.96E-05 6.33E-07
3.75E+00 3.41E+02 6.80E+02 3
1.30E-03 4.50E-04 3.91E-05 6.48E-07
3.96E+00 3.41E+02 6.80E+02 3
1.26E-03 4.37E-04 3.86E-05 6.66E-07
4.22E+00 3.41E+02 6.80E+02 3
1.22E-03 4.22E-04 3.80E-05 6.86E-07
4.53E+00 3.41E+02 6.80E+02 3
1.17E-03 4.04E-04 3.72E-05 7.11E-07
4.91E+00 3.41E+02 6.80E+02 3
1.11E-03 3.85E-04
3.64E-05
7.39E-07
ilf width
y/bbc=
bbc (m)
2.5
1.08E+00
1 0. OOE+00
I.13E+00
1 0. OOE+00
I.17E+00
0. OOE+00
.21E+00
, 0. OOE+00
.25E+00
4.28E-11
.29E+00
9.08E-11
.33E+00
1.43E-10
.38E+00
2.97E-10
.42E+00
5.11E-10
.47E+00
8.41E-10
.52E+00
1.29E-09
.52E+00
1.39E-09
.53E+00
1.43E-09
.54E+00
1.47E-09
.55E+00
1.60E-09
.56E+00
1.68E-09
.57E+00
1.84E-09
.59E+00
2.00E-09
.61E+00
2.23E-09
.64E+00
2.53E-09
.67E+00
2.92E-09
y/bbc=
0.0
0. OOE+00
9.77E-04
1.19E-03
1.33E-03
1.43E-03
1.51E-03
1.58E-03
1.64E-03
1.69E-03
1.73E-03
1.76E-03
1.75E-03
1.73E-03
1.71E-03
1.68E-03
1.65E-03
1.62E-03
1.58E-03
1.53E-03
1.48E-03.
1.42E-03
-------
5.37E+00 3.41E*02 6.80E+02
1.05E-03 3.63E-04 3.54E-05 7.71E-07
5.92E+00 3.42E+02 6.80E+02 3
9.88E-04 3.40E-04 3.42E-05 8.07E-07
6.60E+00 3.42E+02 6.80E+02 3
9.17E-04 3.15E-04 3.28E-05 8.46E-07
7.41E+00 3.42FA02 6.80E+02 3
8.42E-04 2.88E-04 3.12E-05 8.85E-07
8.41E+00 3.42E+02 6.80E+02 3
7.65E-04 2.61E-04 2.94E-05 9.22E-07
9.62E+00 3.43E+02 6.80E+02 4
6.85E-04 2.33E-04 2.74E-05 9.54E-07
1.11E+01 3.43E+02 6.80E+02 4
6.06E-04 2.05E-04 2.52E-05 9.74E-07
1.29E+01 3.43E+02 6.80E+02 4
5.28E-04 1.78E-04 2.27E-05 9.76E-07
1.50E+01 3.44E+02 6.80E+02 4
4.54E-04 1.52E-04 2.02E-05 9.57E-07
1.76E+01 3.45E+02 6.80E+02 4
3.84E-04 1.28E-04 1.76E-05 9.13E-07
2.08E+01 3.45E+02 6.80E+02 5
3.20E-04 1.06E-04 1.50E-05 8.44E-07
2.47E+01 3.47E+02 -- 6.80E+02 5
2.62E-04 8.63E-05 1.25E-05 7.54E-07
2.94E+01 3.48E+02 6.80E+02 6
2.11E-04 6.93E-05 1.02E-05 6.52E-07
3.51E+01 3.49E+02 6.80E+02 6
1.68E-04 5.48E-05 8.21E-06 5.45E-07
4.20E+01 3.51E+02 6.80E+02 7
1.31E-04 4.27E-05 6.46E-06 4.42E-07
5.04E+01 3.53E+02 6.80E+02 8
1.01E-04 3.29E-05 4.99E-06 3.49E-07
6.06E+01 3.56E+02 6.80E+02 1
7.67E-05 2.50E-05 3.81E-06 2.70E-07
7.29E+01 3.59E+02 6.80E+02 1
5.76E-05 1.87E-05 2.86E-06 2.05E-07
8.79E+01 3.63E+02 6.80E+02 1
4.28E-05 1.39E-05 2.13E-06 1.53E-07
1.06E+02 3.68E-t-02 6.80E-H02 1.
3.16E-05 1.02E-05 1.57E-06 1.13E-07
1.28E+02 3.74E+02 6.80E+02 1.
2.31E-05 7.49E-06 1.15E-06 8.30E-08
1.55E+02 3.81E+02 6.80E+02 2.
1.67E-05 5.44E-06 8.34E-07 6.03E-08
1.88E+02 3.90E+02 6.80E+02 2.
1.21E-05 3.93E-06 6.02E-07 4.36E-08
2.27E+02 4.00E+02 6.80E+02 3.
8.70E-06 2.82E-06 4.33E-07 3.14E-08
2.75E+02 4.13E+02 6.80E+02 3.
6.23E-06 2.02E-06 3.10E-07 2.25E-08
3.34E+02 4.28E+02 6.80E+02 4.
4.45E-06 1.45E-06 2.22E-07 1.61E-08
4.05E+02 4.47E+02 6.80E+02 5.
3.18E-06 1.03E-06 1.58E-07 1.15E-08
4.90E+02 4.69E+02 6.80E+02 6.
2.26E-06 7.3SE-07 1.13E-07 8.16E-09
5.95E+02 4.97E+02 6.80E+02 7.
1.61E-06 5.23E-07 8.02E-08 5.81E-09
7.22E+02 5.30E+02 6.80E+02 9.
1.15E-06 3.72E-07 5.71E-08 4.14E-09
8.75E+02 5.71E+02 6.80E+02 1.
8.17E-07 2.65E-07 4.07E-08 2.95E-09
1.06E+03 6.20E+02 6.80E+02 1.
5.83E-07 1.89E-07 2.90E-08 2.10E-09
1.29E+03 6.80E+02 6.80E+02 1.
4.17E-07 1.35E-07 2.07E-08 1.50E-09
1.57E+03 7.48E+02 6.87E+02 1.
3.71E+00
7 3.43E-09
3.76E+00
7 4.08E-09
3.82E+00
7 4.93E-09
3.90E+00
7 6.03E-09
3.99E+00
7 7.42E-09
1.11E+00
7 9.10E-09
S.25E+00
1 1.11E-08
1.43E+00
' 1.32E-08
1.66E+00
' 1.53E-08
I.94E+00
1 1.70E-08
>.29E+00
1.80E-08
I.73E1-00
1.82E-08
1.28E-HOO
1.73E-08
i.95E-HOO
1.56E-08
.79E+00
1.34E-08
.82E+00
1.11E-08
.01E+01
8.83E-09
.16E+01
6.83E-09
.35E+01
5.17E-09
.58E+01
3.85E-09
.86E+01
2.83E-09
.20E+01
2.06E-09
. 61E+01
1.49E-09
. 11E+01
1.07E-09
.71E+01
7.68E-10
.43E+01
5.49E-10
.29E+01
3.92E-10
. 33E+01
2.80E-10
. S6E + 01
1.99E-10
.04E+01
1.41E-10
. 08E+02
l.OOE-10
.29E+02
7.18F-11
. 53E+02
5.15E-11
. 83E-I-02
1.35E-03
1.28E-03
1.20E-03
1.11E-03
1.02E-03
9.24E-04
8.27E-04
7.30E-04
6.34E-04
5.42E-04
4.55E-04
3.75E-04
3.04E-04
2.42E-04
1.90E-04
1.46E-04
1.11E-04
8.38E-05
6.23E-05
4.59E-05
3.36E-05
2.44E-05
1.76E-05
1.27E-05
9.07E-06
6.48E-06
4.62E-06
3.29E-06
2.34E-06
1.67E-06
1.19E-06
8.48E-07
6.06E-07
4.17E-07
-------
2.87E-07 9.31E-08 1.43E-
1.92E+03 8.31E+02
1.97E-07 6.40E-08 9.82E-
2.36E+03 9.32E-I-02
1.36E-07 4.40E-08 6.75E-
2.91E+03 1.05E+03
9.34E-08 3.03E-08 4 . 65E-
3.61E+03 1.20E+03
6.45E-08 2.09E-08 3.21E-
4.47E+03 1.38E+03
4.47E-08 1.45E-08 2 . 22E-
5.54E+03 1.60E+03
3.11E-08 1.01E-08 1.55E-
1
time averaged (tav = 1800. s) volume concentration: maximum
concentration (volume fraction) along centerline.
08 1.03E-09
7.00E+02 2.
09 7.11E-10
7.20E+02 2.
09 4.89E-10
7.47E+02 3.
09 3.37E-10
7.83E+02 3.
09 2.33E-10
8.29E+02 4.
09 1.61E-10
8.86E+02 5.
09 1.12E-10
3.51E-11
19E+02
2.43E-11
63E+02
1.67E-11
16E+02
1.16E-11
SOE-t-02
8.08E-12
57E+02
5.43E-12
49E+02
3.81E-12
2
1
1
9
6
4
.87E-07
.97E-07
-36E-07
.38E-08
. 50E-08
.53E-08
downwind
distance
-3
2
1
1
6
3
6
1
1
2
3
3
3
3
3
3
3
3
4
4
4
5
5
6
7
8
9
1
1
1
1
2
2
2
3
4
5
6
7
8
1
1
1
1
2
x (m)
.08E+00
.46E+00
.85E+00
.23E+00
.15E-01
.87E-07
.15E-01
.23E+00
.85E+00
.46E+00
.08E+00
. 14E+00
.22E+00
.32E+00
.44E+00
.58E+00
.75E+00
. 96E+00
.22E+00
.53E+00
. 91E+00
.37E+00
. 92E+00
. 60E+00
.41E+00
.41E+00
. 62E+00
.11E+01
.29E+01
. 50E+01
.76E+01
.08E+01
.47E+01
. 94E+01
.51E+01
.20E+01
.04E+01
.06E+01
.29E+01
.79E+01
. 06E+02
.28E+02
. 55E+02
.88E+02
.27E+02
maximum time of
height concentration max cone
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
z (m)
OOE+00 -
OOE+00
OOE+00
OOE+00
OOE+00
OOE+00
OOE+00
OOE+00
OOE+00
OOE+00
OOE+00
OOE+00
OOE+00
OOE+00
OOE+00
OOE+00
OOE+00
OOE+00
OOE+00
OOE+00
OOE+00
OOE+00
OOE+00
OOE+00
OOE+00
OOE+00
OOE+00
OOE+00
OOE+00
OOE+00
OOE+00
OOE+00
OOE+00
OOE+00
OOE+00
OOE+00
OOE+00
OOE+00
OOE+00
OOE+00
OOE+00
OOE+00
OOE+00
OOE+00
OOE+00
c
0
9
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
9
8
7
6
5
4
3
3
2
1
1
1
8
6
4
3
2
1
1
(x,0,z)
.OOE+00
.77E-04
.19E-03
.33E-03
.43E-03
.51E-03
.58E-03
.64E-03
.69E-03
.73E-03
.76E-03
.75E-03
.73E-03
.71E-03
. 68E-03
.65E-03
. 62E-03
.58E-03
.53E-03
.48E-03
.42E-03
.35E-03
.28E-03
.20E-03
.11E-03
.02E-03
.24E-04
.27E-04
.30E-04
.34E-04
.42E-04
.55E-04
.75E-04
.04E-04
.42E-04
. 90E-04
.46E-04
.11E-04
.38E-05
.23E-05
-59E-05
.36E-05
.44E-05
.76E-05
.27E-05
3.
3.
3.
3.
3.
3.
3.
3.
3.
3.
3.
3.
3.
3.
3.
3.
3.
3.
3.
3.
3.
3.
3.
3.
3.
3.
3.
3.
3.
3.
3.
3.
3.
3.
3.
3.
3.
3.
3.
3.
3.
3.
3.
3.
4 .
(s)
41E+02
41E+02
40E+02
40E+02
40E+02
40E+02
40E+02
40E+02
40E+02
41E+02
41E+02
41E+02
41E+02
41E+02
41E+02
41E+02
41E+02
41E+02
41E+02
41E+02
41E+02
41E+02
42E+02
42E+02
42E+02
42E+02
43E+02
43E+02
43E+02
44E+02
45E+02
45L+02
47E+02
48E+02
49E+02
51E+02
53E+02
56E+02
59E+02
63E+02
68E+02
74E+02
81E+02
90E+02
OOE+02
cloud
duration
6.
6.
6.
6.
6.
6.
6.
6.
6.
6.
6.
6.
6.
6.
6.
6.
6.
6.
6.
6.
6.
6.
6.
6.
6.
6.
6.
6.
6.
6.
6.
6.
6.
6.
6.
6.
6.
6.
6.
6.
6.
6.
6.
6.
6.
(s)
80E+02
80E+02
80E+02
80E+02
80E+02
80E+02
80E+02
80E+02
80E+02
80E+02
80E+02
80E+02
80E+02
80E+02
80E+02
80E+02
80E+02
80E+02
80E+02
80E+02
80E+02
80E+02
80E+02
80E+02
80E+02
80E+02
80E+02
80E+02
80E+02
80E+02
80E+02
80E+02
80E+02
80E+02
80E+02
80E+02
80E+02
80E+02
80E+02
80E+02
80E+02
80E+02
80E+02
80E+02
80E+02
-------
2
3
4
4
5
7
8
1
1
1
1
2
2
3
4
5
.75E+02
.34E+02
.05E+02
.90E+02
.95E+02
.22E+02
.75E+02
. 06E+03
.29E+03
. 57E+03
. 92E+03
.36E+03
. 91E+03
. 61E+03
.47E+03
.54E+03
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.OOE+00
.OOE+00
.OOE+00
.OOE+00
.OOE+00
.OOE+00
.OOE+00
.OOE+00
.OOE+00
.OOE+00
.OOE+00
.OOE+00
.OOE+00
.OOE+00
.OOE+00
.OOE+00
9.
6.
4 .
3.
2.
1.
1.
8.
6.
4 .
2.
1.
1.
9.
6.
4.
07E-06
48E-06
62E-06
29E-06
34E-06
67E-06
19E-06
48E-07
06E-07
17E-07
87E-07
97E-07
36E-07
38E-08
50E-08
53E-08
4
4
4
4
4
5
5
6
6
7
8
9
1
1
1
1
.13E+02
.28E+02
.47E+02
.69E+02
.97E+02
.30E+02
.71E+02
.20E+02
.80E+02
.48E+02
.31E+02
. 32E+02
. 05E+03
. 20E+03
. 38E+03
. 60E+03
6.
6.
6.
6.
6.
6.
6.
6.
6.
6.
7.
7.
7 .
7.
8.
8.
80E+02
80E+02
80E+02
80E+02
80E+02
80E+02
80E+02
80E+02
80E+02
87E+02
OOE+02
20E+02
47E+02
83E+02
29E+02
86E+02
-------
ATTACHMENT 3
Summary of Exposure Concentrations at
Specific Receptor Locations
-------
From Slab output file:
Scenario:
Accident Location:
Duration:
Meteorology:
Chemical:
Vapor phase mole fraction:
LOG:
IDLH:
RUN01.OUT
CONSERV
ON-SITE
UNMITIG
TYPICAL
FORMALDEHYDE
0.601
9.600
19.600
*0utput adjusted to be distance from fenceline.
X,m Max concentration, ppm
25.00
50.00
100.00
200.00
300.00
400.00
500.00
600.00
700.00
800.00
900.00
1000.00
1250.00
1500.00
1750.00
2000.00
2250.00
2500.00
3000.00
4000.00
5000.00
10000.00
15000.00
20000.00
694.50
512.61
313.65
154.73
93.24
62.13
44.78
.- 34.53
27.45
22.01
18.48
15.50
10.91
8.04
6.30
5.10
4.13
3.54
2.64
1.63
1.05
0.33
0.17
0.11
Concentration (ppm)
LOC
IDLH
9.6000
19.6000
Distance to (m)
1364.21
868.18
-------
From Slab output file: RUN02.0UT
Scenario: CONSERV
Accident Location: ON-SITE
Duration: MITIGAT
Meteorology: TYPICAL
Chemical: FORMALDEHYDE
Vapor phase mole fraction: 0.742
LOC: 9.600
IDLH: ' 19.600
*0utput adjusted to be distance from fenceline.
X,m Max concentration, ppm
25.00
50.00
100.00
200.00
300.00
400.00
500.00
600.00
700.00
800.00
900.00
1000.00
1250.00
1500.00
1750.00
2000.00
2250.00
2500.00
3000.00
4000.00
5000.00
10000.00
15000.00
20000.00
476.47
358.89
224.89
113.41
69.36
46.47
33.82
* 26.14
20.83
16.75
14.09
11.77
7.95
5.73
4.48
3.56
2.88
2.43
1.76
1.10
0.76
0.25
0.13
0.08
Concentration (ppm) Distance to (m)
LOC 9.6000 1141.92
IDLH 19.6000 730.21
-------
From Slab output file:
Scenario:
Accident Location:
Duration:
Meteorology:
Chemical:
Vapor phase mole fraction:
LOG:
IDLH:
RUN03.0UT
CONSERV
ON-SITE
UNMITIG
WORST
FORMALDEHYDE
0.601
9.600
19.600
*0utput adjusted to be distance from fenceline.
6
12
18
24
25
5846.80
5569.92
4879.85
4195.44
50
4493.36
4322.02
3841.34
3319.68
100
2990.21
2878.07
2578.46
2240.16
200
1717.50
1615.33
1440.31
1254.15
300
1162.43
1064.81
943.31
815.79
400
849.70
759.49
669.11
575.10
500
660.37
582.49
505.20
433.07
600
536.85
467.74
402.49
344.06
700
426.96
384.94
328.75
X,m 1
7
13
19
25
.00 111.39
83.37
66.66
55.63
112.92
.00 77-. 31
58.07
46.44
38.71
79.11
.00 43.77
32.83
26.31
21.89
45.45
.00 19.67
14.79
11.84
9.84
20.84
.00 11.27
8.48
6.76
5.64
12.10
.00 7.18
5.41
4.33
3.61
7.84
.00 5.08
3.81
3.05
2.54
5.56
.00 3.85
2.88
2.31
1.92
4.24
.00 3.01
2.26
1.80
1.50
2
8
14
20
26
268.23
199.16
158.58
131.71
311.11
189.20
139.95
111.36
92.49
225.48
108.54
80.59
63.92
53.10
133.90
50.04
36.90
29.31
24.36
63.99
29.08
21.42
17.04
14.15
37.86
18.76
13.88
10. 98
9.17
24.79
13.31
9.85
7.84
6.50
17.80
10.17
7.49
5.97
4.95
13.64
8.00
5.89
4.69
3.90
9
15
21
27
755.
553.63
438.59
363.66
630.79
551.
402.32
318.44
263.76
467.02
330.
240.44
189.41
157.12
285.36
159.
115.36
90.57
74.95
140.84
94.
68.50
53.83
44.43
84.70
62.
44 . 94
35.29
29.08
56.28
44.
32.27
25.34
20.90
40.70
34.
24.72
19.41
16.00
31.39
26.
19.55
15.33
12.64
3
10
16
22
39 1577.
1139.67
897.70
739.29
07 1177.
849.91
667.87
548.31
65 726.
522.49
408.19
335.53
19 361.
259.89
202.08
165.71
74 219.
157.41
122.03
99.84
14 145.
104.36
80.83
66.35
60 105.
75.92
58.67
47.99
16 81.
58.39
45.25
37.01
97 64.
46.33
35.97
29.42
4
ll"
17
23
46 3055
2310.53
1824.66
1507.85
73 2317
1759.27
1389.17
1146.59
58 1471
1124.99
883.42
723.95
53 764
584.48
458.21
374.24
02 477
363.58
284.57
231.79
37 325
246.66
192.39
156.80
09 239
180.93
141.45
114.76
07 187
140.78
110.12
89.29
39 150
112.69
88.15
71.52
5
.83
.65
.93
.19
.99
.64
.79
.39
.54
280.34
3.34
10.79
24.94
-------
800.00
329.50
319.04
270.41
229.93
900.00
279.80
273.97
231.54
195.96
1000.00
231.52
231.78
198.23
167.10
1250.00
164.18
150.50
144.15
121.48
1500.00
125.99
108.81
107.68
91.67
1750.00
98.47
86.35
79.35
73.11
2000.00
78.43
68.18
62.27
57.58
2250.00
65.51
56.36
49.05
43.70
2500.00
55.02
46.47
41.76
36.88
3000.00
40.74
33.99
29.99
26.43
4000.00
24.70
20.65
18.43
16.07
5000.00
16.58
13.99
12.46
10.94
1.78
1.42
1.19
2.65
1.48
1.18
0.99
2.21
1.23
0.98
0.82
1.84
0.85
0.68
0.56
1.28
0.61
0.49
0.41
0.93
0.47
0.38
0.32
0.73
0.38
0.30
0.25
0.59
0.31
0.24
0.20
0.47
0.26
0.21
0.17
0.40
0.19
0.15
0.13
0.30
0.11
0.09
0.08
0.18
0.07
0.06
0.05
0.13
2.37 6.34
4.68
3.72
3.09
8.61
1.97 5.28
3.90
3.10
2.58
7.21
1.63 4.39
3.25
2.58
2.15
6.02
1.12 3.05
2.26
1.79
1.50
4.21
6.81 2.22
1.65
1.31
1.09
3.09
0.63 1.72
1.28
1.02
0.85
2.42
0.51 1.35
1.03
0.82
0.69
1.95
0.40 1.05
0.83
0.66
0.55
1.58
0.34 0.88
0.71
0.56
0.47
1.35
0.24 0.63
0.51
0.42
0.35
1.00
0.14 0.38
0.29
0.24
0.21
0.62 °
0.09 0.25
0.20
0.16
0.14
0.43
15.59
12.22
10.07
19.97
13.04
10.23
8.43
16.77
10.89
8.55
7.06
14.06
7.57
5.98
4.94
9.89
5.56'
4.38
3.62
7.29
4.34
3.42
2.83
5.72
3.50
2.76
2.28
4.64
2.81
2.23
1.85
3.76
2.33
1.91
1.58
3.22
1.65
1.41
1.17
2.40
0.97
0.82
0.72
1.48
0.65
0.54
0.47
0.96
21.46
37.08
28.81
23.58
17.94
31.10
24.17
19.79
14.97
26.05
20.26
16.58
10.44
18.26
14.24
11.64
7.63
13.46
10.49
8.57
5.94
10.54
8.19
6.71
4.66
8.50
6.63
5.44
3.58
6.81
5.38
4.43
3.01
5.64
4.60
3.79
2.15
3.96
3.32
2.82
1.28
2.32
1.90
1.63
0.86
1.57
1.27
1.08
51.51
90.92
71.07
57.73
43.18
76.87
59.89
48.68
36.14
64.89
50.44
41.02
25.30
45.84
35.76
29.09
18.40
33.98
26.47
21.58
13.50
26.69
20.86
17.03
10.58
20.89
16.94
13.87
8.27
15.92
13.68
11.30
7.03
13.40
11.30
9.68
5.04
9.58
7.93
6.99
3.03
5.75
4.68
3.98
2.05
3.89
." 3.17
2.68
121.78
102.84
86.78
60.85
41.29
31.57
24.90
19.77
16.65
11.91
7.28
4.89
-------
10000
4.47
4.07
3.63
3.29
15000
1.97
1.89
1.72
1.57
33
39
45
51
25
1120.85
78.76
108.23
1195.90
50
849.48
55.43
78.40
869.03
100
535.92
31.74
46.55
521.46
200
274.14
14.56
22.20
250.87
300
169.27
8.45
13.12
149.30
400
114.58
5.47
8. 63
97.73
500
83.80
3.89
6.20
70.47
600
65.13
2.96
4.74
53.87
700
52.13
2.33
3.75
42.52
.00 0.
0.02
0.02
0.02
0.04
.00 0.
0.01
0.01
0.01
0.02
X,m
34
40
46
52
.00 1285.
3190.35
217.06
218.65
2399.74
.00 976.
2526.03
157.41
161.55
1761.67
.00 616.
1701.63
93.13
98.54
1076.17
.00 316.
946.18
44.45
48.31
534.96
.00 195.
614.39
26.34
29.08
325.62
.00 132.
430.46
17.25
19.30
217.74
.00 96.
323.32
12.40
13.97
158.51
.00 75.
255.84
9.50
10.79
122.75
.00 60.
207.99
7.52
8.57
97.57
03 0
0.06
0.05
0.04
0.13
01 0
0.03
0.03
0.02
0.07
28
35
41
47
53
27 3634
87.72
439.10
145.32
3817.44
78 2877
61.47
324.90
107.49
2847.07
12 1947
35.30
197.82
65.65
1804.23
34 1086
16.18
97.52
32.21
956.44
36 706
9.38
58.60
19.37
613.03
08 494
6.09
38.85
12.85
428.06
55 372
4.32
28.12
9.29
320.91
46 295
3.29
21.70
7.19
253.90
44 240
2.59
17.24
5.71
198.32
.08
0.20
0.17
0.15
0.30
.04
0.10
0.09
0.08
0.16
29
36
42
48
54
.72
241.39
893.62
109.02
5829.84
.45
175.03
673.66
80.76
4469.54
.89
104.01
425.09
49.11
3030.97
.02
49.47
217.35
24.13
1783.16
.30
29.31
133.89
14.51
1248.35
.96
19.18
90.
-------
800.00
42.07 170.41
1.85 5.99
2.98 6.87
33.85 77.46
900.00
35.50 145.26
1.54 5.02
2.50 5.76
28.26 62.24
1000.00
29.93 123.73
1.28 4.19
2.09 4.83
23.34 50.01
1250.00
21.24 89.10
0.89 2.93
1.46 3.40
15.02 33.75
1500.00
15.80 67.15
0.65 2.15
1.07 2.5i
10.60 24.04
1750.00
12.44 53.58
0.51 1.68
0.84 1.97
8.14 18.77
2000.00
10.13 44.00
0.41 1.36
0.68 1.60
6.40 14.64
2250.00
8.26 36.16
0.33 1.10
0.55 1.30
5.11 11.91
2500.00
7.09 31.17
0.28 0.94
0.47 1.11
4.28 9.80
3000.00
5.32 22.57
0.21 0.70
0.35 0.83
3.05 6.99
4000.00
3.31 12.79
0.13 0.43
0.21 0.51
1.85 4.25
5000.00
2.14 8.64
0.09 0.30
0.15 0.36
1.24 2.84
48.65
2.05
13.80
4.57
151.02
41.04
1.71
11.57
3.84
126.08
34.59
1.43
9.70
3.22
103.04
24.57
0.99
6.84
2.27
70.48
re. 25
0.72
5.05
1.67
53.00
14.36
0.56
3.96
1.32
41.16
11.69
0.46
3.21
1.07
31.79
9.55
0.37
2.61
0.87
26.78
8.19
0.31
2.23
0.74
21.77
6.14
0.23
1.67
0.55
16.11
3.55
0.14
1.03
0.34
9.48
2.35 '
0.10
0.72
0.24
6.34
196.66
6.69
33.21
3.42
342.88
167.59
5.59
28.01
2.88
286.48
142.80
4.66
23.62
2.42
253.17
103.25
3.26
16.81
1.70
184.08
77.67
2.39
12.48
1.25
138.19
62.07
1.87
9.83
0.98
112.24
50.94
1.51
8.02
0.80
89.39
41.51
1.22
6.56
0. 65
75.17
34.22
1.05
5.63
0.56
61.12
23.88
0.78
4.22
0.41
46.22
14.22
0.48
2.64
0.26
27.41
9.69
0.33
1.86
0.18
18.39
2.31
15.37
3.74
3.55
1.93
12.92
3.13
2.95
1.61
10.85
2.62
2.44
1.12
7.63
1.83
1.66
0.82
5.62
1.34
1.13
0.64
4.41
1.05
0.86
0.51
3.58
0.85
0.68
0.41
2.90
0.68
0.53
0.35
2.49
0.59
0.45
0.26
1.86
0.44
0.32
0.16
1.15
0.27
0.19
0.11
0.81
0.19
0.13
7.51
37.11
8.56
9.88
6.28
31.30
7.19
8.21
5.25
26.38
6.03
6.82
3.68
18.74
4.26
4.66
2.70
13.94
3.14
3.18
2.11
10.97
2.47
2.41
1.70
8.95
2.00
1.91
1.38
7.32
1.62
1.50
1.18
6.28
1.39
1.28
0.88
4.71
1.04
0.91
0.54
2.94
0.65
0.55
0.38
2.06
0.45
0.37
35
14.57
.22
8.60
6.35
4.98
4.04
3.28
2.81
2.10
1.30
0.90
-------
10000.00
0.67 2.
0.03 0.
0.05 0.
0.35 0.
15000.00
0.35 1.
0.02 0.
0.03 0.
0.17 0.
X,m
25.00
50.00
100.00
200.00
300.00
400.00
500.00
600.00
700.00
800.00
900.00
1000.00
1250.00
1500.00
1750.00
2000.00
2250.00
2500.00
3000.00
4000.00
5000.00
10000.00
15000.00
Concentration
LOG
IDLH 1
0.74 2.95
64 0.03 0.
10 0.23 0.
13 0.09 0.
79 1.71 4.
0.38 1.47
35 0.02 0.
05 0.12 0.
07 0.05 0.
36 0.79 2.
Max concentration, ppm
5846.80
4493.36
3030.97
1783.16
1248.35
862.07
660.37
-- 536.85
426.96
342.88
286.48
253.17
184.08
138.19
112.24
89.39
75.17
61.12
46.22
27.41
18.39
4.84
2.10
(ppm) Distance to
9.6000 8242.
9.6000 4865.
10
57
06
84
05
30
04
10
"
(m)
72
83
0.03
0.12
C.25
0.07
0.04
0.02
0.13
0.03
0.02
0.61
0.16
0.11
0.06
0.32
0.08
0.05
C.27
0.14
-------
From Slab output file:
Scenario:
Accident Location:
Duration:
Meteorology:
Chemical :
Vapor phase mole fraction:
LOG:
IDLH:
*0utput adjusted to be distance from
X,m 1 2
678
12 13 14
18 19 20
24 25 26
25.00 81.56 192.89
3112.56 61.16 142.96
3146.31 48.93 114.23
2944.74 40.78 94.67
2633.54 81.05 217.38
50.00 56.95 137.40
2402.57 42.82 102.10
2439.67 34.26 81.11
2311.65 28.55 67.49
2093.77 57.74 159.74
100.00 32.47 80.06
1549.78 24.41 59.36
1629.61 19.53 47.19
1559.58 16.30 39.24
1423.67 33.56 97.03
200.00 14.77 37.55
825.48 11.09 27.67
927.88 8.88 21.97
890.09 7.39 18.28
RUN04.OUT
CONSERV
ON-SITE
MITIGAT
WORST
FORMALDEHYDE
0.742
9.600
19.600
fenceline.
3
9 10
15 16
21 22
27
524.21 1058
386.47 783.37
306.26 617.25
254.26 510.06
434.80
387.63 794
284.95 591.10
225.71 465.28
186.75 383.65
327.43
236.90 499
174.05 371.43
136.90 292.19
113.75 240.12
204.46
116.91 254
85.49 189.13
67.11 148.36
55.42 121.99
4
11
17
23
.75 1894
1514.99
1223.67
1020.68
.34 1438
1167.76
943.27
786.11
.03 921
756.84
614.56
510.60
.05 486
402.64
326.82
271.00
5
.64
.12
.84
.75
811.51 15.58 47.24 103.46
300.00 8.49 21.99
556.15 6.38 16.21
578.29 5.10 12.86
568.43 4.25 10.68
540.49 9.12 28.32
400.00 5.44 14.30
412.97 4.08 10.50
407.86 3.26 8.34
386.74 2.72 6.92
386.23 5.92 18.69
500.00 3.84 10.21
323.93 2.88 7.49
310.63 2.30 5.94
290.27 1.92 4.94
278.16 4.22 13.43
600.00 2.86- 7.63
266.98 2.19 5.71
244.48 1.75 4.54
227.37 1.46 3.77
215.61 3.23 10.34
700.00 2.20 5.90
218.98 1.71 4.50
200.38 1.37 3.57
179.24 1.14 2.97
171.01 2.54 8.20
70.29 155
51.25 116.24
40.24 90.51
33.18 74.41
63.11
46.47 100
33.89 78.19
26.59 60.84
21.90 49.82
42.22
32.50 71
24.38 56.69
19.13 44.24
15.83 36.22
30.67
24.55 54
18.75 42.80
14.71 34.26
12.14 28.05
23.77
19.09 42
14.67 33.29
11.67 26.94
9.61 22.33
18.93
.85 290
254.54
205.85
170.49
.85 195
174.95
141.45
116.15
.89 144
123.90
104.18
86.16
.58 110
94.73
78.91
67.21
.37 85
74.17
,- 61.77
53.07
.03
.90
.13
.24
.97
-------
800.00
189.30
168.14
152.39
138.80
900.00
159.62
143.40
125.53
117.14
1000.00
142.68
122.70
110.13
99.53
1250.00
105.15
88.69
78.63
71.01
1500.00
81.08
69.43
58.91
53.26
1750.00
65.18
54.65
47.42
40.88
2000.00
52.08
44.78
37.34
33.77
2250.00
44.01
36.86
32.02
27.23
2500.00
37.00
31.59
26.70
23.44
3000.00
27.41
23.22
20.17
17.04
4000.00
16.72
14.30
12.44
10.75
5000.00
11.17
9.59 0
8.50 0
7.28 0
1.35
1.08
0.90
2.02
1.10
0.89
0.75
1.68
0.90
0.74
0.62
1.40
0.61
0.50
0.43
0.96
0.43
0.35
0.30
0.71
0.34
0.27
0.23
0.54
0.27
0.22
0.18
0.43
0.21
0.17
0.14
0.35
0.18
0.15
0.12
0.29
0.13
0.11
0.09
0.21
0.08
0.06
0.05
0.13
0.05
.04
.04
.09
1.70
3.57
2.84
2.36
6.55
1.41
2.93
2.37
1.97
5.48
1.15
2.41
1.97
1.64
4.59
0.78
1.64
1.33
1.14
3.20
U.56
1.17
0.95
0.81
2.28
0.44
0.92
0.74
0.62
1.75
0.34
0.73
0.59
0.50
1.40
0.28
0.58
0.47
0.39
1.12
0.23
0.49
0.40
0.34
0.96
0.16
0.36
0.29
0.25
0.70
0.10
0.22
0.18
0.15
0.43
0.07 -
0.15
0.12
0.10
0.30
4.59
11.44
9.31
7.69
15.17
3.82
9.47
7.66
6.44
12.75
3.11
7.75
6.29
5.37
10.70
2.12
5.32
4.29
3.64
7.51
1.55
3.90
3.10
2.62
5.40
1.21
3.02
2.42
2.04
4.16
0.94
2.36
1.91
1.62
3.31
0.78
1.94
1.56
1.30
2.63
0.64
1.60
1.30
1.10
2.25
0.46
1.16
0.94
0.80
1.64
0.28
0.72
0.59
0.50
1.02
0.19
0.50
0.40
0.34
0.70
14.88
25. 92
21.08
17.91
12.54
21.74
17.64
15.08
10.26
17.67
14.45
12.63
6.99
12.10
9.75
8.56
5.19
9.09
7.24
6.13
3.98
7.01
5.63
4.79
3.10
5.40
4.40
3.81
2.59
4.56
3.65
3.07
2.11
3.72
3.00
2.59
1.56
2.77
2.21
1.88
0.92
1.66
1.36
1.17
0.63
1.14
0.94
0.81
33.91
58.82
48.36
41.57
28.15
49.28
40.79
34.78
23.55.
40.84
33.23
28.48
16.35
28.64
23.13
19.42
12.04
21.31
17.30
14.53
9.03
16.19
13.32
11.29
7.31
13.15
10.54
8.76
5.90
10.66
8.79
7.40
5.00
9.06
7.31
6.03
3.65
6.63
5.43
4.53
2.22
4.09
3.32
2.75
1.51
2.80
2 . 30
1.91
.78
58.93
5C.73
35.31
26.04
20.77
16.26
13.74
11.22
8.42
5.06
3.43
-------
10000
2.89
2.64
2.48
2.22
15000
1.32
1.26
1.15
1.10
20000
0.73
0.71
0.67
0.65
.00 0
0.02
0.01
0.01.
0.03
.00 0
0.01
0.01
0.01
0.02
.00 0
0.01
0.00
0.00
0.01
X,m
33
39
45
51
25,
758.38
56.78
75.54
798.08
50.
585.39
40.33
55.57
584.24
100.
378.46
23.47
33.68
353.53
200.
199.41
10.89
16.38
172.65
300.
124.77
6.38
9.81
99.61
400.
85.61
4.13
6.46
64.70
500.
62.89
2.95
4.65
46.37
600.
49.10
2.25
3.58
34.98
34
40
46
52
.00 871.
2072.46
151.36
150.52
1467.37
,00 670.
1659.64
111.72
113.15
1079.80
00 435.
1140.28
67.51
70.54
665.01
00 230.
653.79
32.85
35.45
321.70
00 144.
431.97
19.65
21.60
194.14
00 98.
306.62
12.96
14.45
130.91
00 72.
232.82
9.37
10.50
95.52
00 56.
185.76
7.19
8.14
72.34
.02 0
0.05
0.04
0.03
0.10
.01 0
0.03
0.02
0.02
0.05
.01 0
0.02
0.01
0.01
0.03
28
35
41
47
53
,31 2329.
63.04
302.52
100.35
2098.59
87 1861.
44.83
227.06
74.95
1573.56
13 1280.
26.04
141.93
46.94
979.43
12 732.
12.09
71.34
23.60
491.31
02 484.
7.08
43.51
14.38
316.19
28 344.
4.60
29.12
9.61
224.55
61 262.
3.28
21.15
6.98
167.55
73 200.
2.50
16.37
5.40
134.74
.06
0.16
0.13
0.11
0.23
.03
0.08
0.07
0.06
0.12
.02
0.05
0.04
0.04
0.08
29
36
42
48
54
.06
168.52
604.99
75.09
3067.89
59
123.75
466.39
56.42
2255.16
35
75.13
301.18
35.19
1473.71
06
36.54
158.01
17.70
856.81
38
21.89
99.03
10.77
604.88
57
14.45
67.31
7.20
460.12
00
10.43
49.61
5.23
364.07
89
8.00
38.73
4.05
303.81
0.19
0.35
0.30
0.26
0.10
0.18
0.15
0.14
0.06
0.11
0.10
0.09
30
37
43
49
70.97
336.27
94.58
125.22
50.46
253.25
69.52
87.18
29.32
157.75
42.12
49.07
13.65
79.22
20.45
22.09
7.97
48.51
12.25
12.68
5.18
32.39
8.04
7.94
3.69
23.55
5.82
5.52
2.82
18.22
4.48
4.11
0.44
0.83
0.72
0.62
0.22
0.40
0.36
0.32
0.13
0.25
0.22
0.20
31
38
44
50
189.90
673.40
188.15
295.73
139.49
518.79
141.61
211.70
84.51
335.20
88.06
123.96
41.18
176.54
44 .37
58.26
24.67
110.33
27.02
33.56
16.24
75.20
18.02
21.18
11.70
55.46
13.12
14.95
9.04
43.31
>' 10.16
11.22
0.99
0.47
0.27
32
379.26
285.48
178.34
89.88
54.82
36.64
26.69
20.65
-------
700.00
39.41 148.32
1.77 5.69
2.84 6.48
26.78 56.96
800.00
31.88 116.71
1.41 4.55
2.26 5.19
21.99 46.65
900.00
26.96 98.60
1.17 3.81
1.90 4.36
17.83 38.29
1000.00
22.64 81.00
0.98 3.19
1.59 3.67
15.29 32.57
1250.00
15.36 55.81
0.68 2.23
1.12 2.59
10.44 22.59
1500.00
11.14 42.64
0.50 1.64
0.82 1.91
7.54 16.75
1750.00
8.74 33.22
0.39 1.29
0.64 1.51
5.73 13.17
2000.00
6.94 26.34
0.31 1.03
0.52 1.22
4.64 10.22
2250.00
5.65 22.05
0.25 0.82
0.42 0.99
3.66 8.58
2500.00
4.74 18.46
0.21 0.70
0.36 0.85
3.14 6.95
3000.00
3.43 13.79
0.16 0.51
0.27 0.63
2.26 5.17
4000.00
2.16 8.59
0.09 0.31
0.16 0.39
1.37 3.00
45.58
1.97
13.05
4.31
109.27
36.91
1.57
10.49
3.46
90.81
31.18
1.31
8.80
2.91
76.44
26.16
1.09
7.37
2.45
66.13
17.72
0.76
5.22
1.72
47.34
12.77
0.55
3.85
1.27
35.23
10.01
0.43
3.03
1.00
27.90
7.95
0.35
2.43
0.81
22.39
6.47
0.26
1.93
0.66
18.40
5.42
0.23
1.64
0.57
15.14
3.91
0.17
1.19
0.42
10.94
2.47
0.10
0.73
0.26
6.47
158.62
6.33
31.11
3.22
255.79
125.26
5.06
25.18
2.59
219.90
107.26
4.24
21.27
2.18
189.51
89.55
3.55
17.96
1.83
168.39
62.73
2.48
12.79
1.29
124.50
47.28
1.83
9.47
0.96
93.07
36.37
1.43
7.24
0.75
76.18
29.82
1.14
5.82
0.61
60. 68
24.33
0. 91
4 .63
0.50
51.38
20.86
0.77
3.96
0.42
42.07
15.35
0.56
2.89
0.32
31.53
9.62
0.34
1.7f
0.20
18.62
2.22
14.51
3.55
3.16
1.76
11.65
2.83
2.45
1.47
9.79
2.38
2.05
1.22
8.23
1.99
1.67
0.85
5.81
1.39
1.13
0.62
4.28
1.02
0.83
0.49
3.27
0.80
0.63
0.39
2.62
0.65
0.49
0.31
2.09
0.52
0.40
0.26
1.79
0.45
0.33
0.19
1.30
0.33
0.24
0.12
0.80
0.20
0.14
7.16
34.78
8.09
8.62
5.70
28.13
6.49
6.84
4.78
23.78
5.46
5.63
4.00
20.09
4.59
4.66
2.80
14.26
3.24
3.17
2.05
10.22
2.39
2.32
1.57
7.92
1.88
1.75
1.26
6.31
1.52
1.39
1.00
5.05
1.24
1.14
0.85
4.30
1.06
0.94
0.62
3.13
0.80
0.69
0.38
1.96
0.48
0.41
16.46
13.22
11.08
9.29
6.55
4.70
3.62
2.89
2.30
1.97
1.43
0.89
-------
5000.
1.50
0.06
0.11
0.92
10000.
0.49
0.02
0.04
0.26
15000.
0.26
0.01
0.02
0.12
20000.
0.16
0.01
0.01
0.07
00
5.98
0.21
0.27
2.01
00
1.88
0.07
0.09
0.56
00
0.91
0.04
0.05
0.26
00
0.57
0.02
0.03
0.14
1.70
0.07
0.50
0.18
4.32
0.55
0.02
0.16
0.06
1.16
0.28
0.01
0.09
0.03
0.52
0.18
0.01
0.06
0.02
0.29
6.63
0.23
1.24
'0.14
12.29
2.00
0.08
0.41
0.05
3.11
1.01
0.04
0.22
0.03
1.32
0.60
0.03
0.14
0.02
0.75
0.08
0.55
0.14
0.10
0.03
0.18
0.05
0.03
0.01
0.10
0.02
0.01
0.01
0.06
0.02
0.01
0.26
1.36
0.33
0.28
0.09
0.45
0.11
0.08
0.05
0.24
0.06
0.04
0.03
0.15
0.04
0.02
X,m Max concentration, ppm
25.00
50.00
100.00
200.00
300.00
400.00
500.00
600.00
700.00
800.00
900.00
1000.00
1250.00
1500.00
1750.00
2000.00
2250.00
2500.00
3000.00
4000.00
5000.00
10000.00
15000.00
20000.00
3146.31
2439.67
1629.61
927.88
604.88
460.12
364.07
303.81
255.79
219.90
189.51
168.39
124.50
93.07
76.18
60.68
51.38
42.07
31.53
18.62
12.29
3.11
1.32
0.75
C.62
0.20
0.07
Concentration (ppm)
LOG
IDLH
9.6000
19.6000
Distance to (m)
6464.52
3924.27
-------
From Slab output file:
Scenario:
Accident Location:
Duration:
Meteorology:
Chemical:
Vapor phase mole fraction:
LOG:
IDLH:
RUNSa.OUT
CONSERV
ON-SITE
UNMITIG
INVERSN
FORMALDEHYDE
0.632
9.600
19.600
"Output adjusted to be distance from fenceline.
X,m Max concentration, ppm
25.00
50.00
100.00
200.00
300.00
400.00
500.00
600.00
700.00
800.00
900.00
1000.00
1250.00
1500.00
1750.00
2000.00
2250.00
2500.00
3000.00
4000.00
5000.00
10000.00
15000.00
20000.00
6220.56
4825.41
3333.40
2004.76
1421.00
1082.45
851.73
-'713.36
599.12
519.32
447.39
400.10
300.80
231.73
191.95
155.80
133.62
111.45
85.93
53.30
36.63
10.44
4.88
2.81
Concentration (ppm)
LOC
IDLH
9.6000
19.6000
Distance to (m)
10756.67
8251.31
-------
From Slab output file: RUNSb.OUT
Scenario: CONSERV
Accident Location: ON-SITE
Duration: UNMITIG
Meteorology: INVERSN
Chemical: FORMALDEHYDE
Vapor phase mole fraction: 0.152
LOC: 9.600
IDLH: ' 19.600
*Output adjusted to be distance from fenceline.
X,m Max concentration, ppm
25.00
50.00
100.00
200.00
300.00
400.00
500.00
600.00
700.00
800.00
900.00
1000.00
1250.00
1500.00
1750.00
2000.00
2250.00
2500.00
3000.00
4000.00
5000.00
10000.00
15000.00
20000.00
776.73
598.04
404.90
243.68
172.26
131.93
106.80
- 90.02
77.69
67.39
59.76
52.29
39.94
31.79
25.57
21.05
17.59
15.02
11.19
6.94
4.67
1.24
0.60
0.34
Concentration (ppm) Distance to (m)
LOC 9.6000 3374.61
IDLH 19.6000 2105.09
-------
From Slab output file:
Scenario:
Accident Location:
Duration:
Meteorology:
Chemical:
Vapor phase mole fraction:
LOG:
IDLH:
RUN06.0UT
CONSERV
ON-SITE
MITIGAT
INVERSN
FORMALDEHYDE
0.778
9.600
19.600
"Output adjusted to be distance from fenceline.
X,m Max concentration, ppm
25.00
50.00
100.00
200.00
300.00
400.00
500.00
600.00
700.00
800.00
900.00
1000.00
1250.00
1500.00
1750.00
2000.00
2250.00
2500.00
3000.00
4000.00
5000.00
10000.00
15000.00
20000.00
2508.23
1959.11
1390.84
860.58
627.99
484.96
394.85
- 329.85
275.52
240.47
207 .28
182.91
135.45
106.54
85.21
68.42
57.56
48.33
35.83
21.56
14.35
3.79
1.67
0.95
Concentration (ppm)
Distance to (m)
LOG
IDLH
9.6000
19.6000
7248.29
4271.63
-------
From Slab output file: RUN07.0UT
Scenario: CONSERV
Accident Location: ON-SITE
Duration: UNMITIG
Meteorology: TYPICAL
Chemical: ACETONE
Vapor phase mole fraction: 0.557
LOC: 1960.000
IDLH: 2442.000
*0utput adjusted to be distance from fenceline.
X,m Max concentration, ppm
25.00
50.00
100.00
200.00
300.00
400.00
500.00
600.00
700.00
800.00
900.00
1000.00
1250.00
1500.00
1750.00
2000.00
2250.00
2500.00
3000.00
4000.00
5000.00
10000.00
15000.00
20000.00
123.90
91.74
56.54
28.10
17.02
11.29
8.16
6.30
5.01
4.01
3.36
2.82
1.97
1.45
1.14
0.92
0.74
0.64
0.47
0.29
0.19
0.06
0.03
0.02
Concentration (ppm) Distance to (m)
LOC 1960.0000 less than 25.00
IDLH 2442.0000 less than 25.00
-------
From Slab output file: RUN08.0UT
Scenario: CONSERV
Accident Location: ON-SITE
Duration: MITIGAT
Meteorology: TYPICAL
Chemical: ACETONE
Vapor phase mole fraction: 0.585
LOG: 1960.000
IDLH: 2442.000
*0utput adjusted to be distance from fenceline.
X,m Max concentration, ppm
25.00
50.00
100.00
200.00
300.00
400.00
500.00
600.00
700.00
800.00
900.00
1000.00
1250.00
1500.00
1750.00
2000.00
2250.00
2500.00
3000.00
4000.00
5000.00
10000.00
15000.00
20000.00
50.03
37.74
23.72
12.04
7.38
4.94
3.60
2.78
2.22
1.78
1.50
1.25
0.85
0.61
0.47
0.38
0.30
0.26
0.19
0.12
0.08
0.03
0.01
0.01
Concentration (ppm) Distance to (m)
LOG 1960.0000 less than 25.00
IDLH 2442.0000 less than 25.00
-------
From Slab output file:
Scenario:
Accident Location:
Duration:
Meteorology:
Chemical :
Vapor phase mole fraction:
LOG:
IDLH:
RUN 09. OUT
CONSERV
ON-SITE
UNMITIG
WORST
ACETONE
0.557
1960.000
2442.000
*0utput adjusted to be distance from fenceline.
6
12
18
24
25
498.03
638.62
645.45
626.22
50
405.22
492.26
498.37
485.95
100
290.78
331.69
331.86
323.70
200
184.52
193.93
189.86
182.07
300
133.17
133.46
128.03
120.65
400
102.80
98.84
93.27
86.58
500
82.89
78.00
71.89
66.29
600
68.62
64.00
58.48
53". 38
700
56.95
53.65
48.62
44.00
X,m
7
13
19
25
.00
14.55
11.59
9.66
19.72
.00
10.04
8.07
6.71
13.87
.00
5.69
4.57
3.80
7.95
.00
2.56
2.05
1.71
3.65
.00
1.47
1.18
0.98
2.12
.00
0.94
0.75
0.63
1.37
.00
0.66
0.53
0.44
0.97
.00
0.50
0.40
0.33
0.74
.00
0.39
0.31
0.26
0.58
1
8
14
20
26
19.77
35.35
27.90
23.07
54.73
13.60
24.98
19.68
16.24
39.71
7.62
14.39
11.31
9.33
23.66
3.40
6.62
5.19
4.28
11.34
1.95
3.85
3.02
2.49
6.72
1.25
2.48
1.95
1.61
4.41
0.88
1.76
1.39
1.14
3.17
0.67
1.34
1.05
0.87
2.43
0.52 -
1.06
0.83
0.69
1.92
2
9
15
21
27
48.52 139.
100.61
78.31
64.62
112.13
34.33 101.
73.22
56.88
46.81
83.29
19.80 60.
44.05
34.23
27.97
51.28
9.13 29.
21.22
16.46
13.42
25.37
5.31 17.
12.63
9.77
7.99
15.37
3.43 11.
8.27
6.43
5.23
10.18
2.43 8.
5.97
4.61
3.75
7.37
1.85 6.
4.56
3.53
2.87
5.69
1.45 4.
3.60
2.79
2.27
4.52
3
10
16
22
33 274
208.89
162.80
132.76
37 201
155.31
121.53
99.02
53 122
95.47
75.07
60.85
08 61
47.58
37.31
30.24
31 37
28.82
22.61
18.30
35 24
19.17
15.04
12.19
17 18
13.85
10.87
8.78
26 14
10.67
8.37
6.78
94 11
8.48
6.64
5.39
4
11
17
23
.70 426
381.59
319.94
267.47
.55 318
287.40
242.91
204.07
.93 202
182.12
154.78
130.36
.07 108
95.00
80.45
67.59
.33 69
59.75
50.21
42.15
.99 48
40.96
34.20
28.56
.23 36
30.37
25.15
20.99
.11 29
23.80
19.61
16.31
.26 23
19.17
15.75
13.05
5
.46
.42
.59
.04
.63
.72
.65
.08
.68
-------
46. 02
45.27
40.67
36.51
38 . 39
39.39
35.19
31.43
32 . 95
33. 81
30.47
27 . 06
23.83
22.62
22.65
19. 94
18.42
16.69
17.30
15.27
14.54
13.36
12.88
12.28
12.03
10.73
10.21
9.74
9.98
8.99
8.14
7.46
8.57
7.52
6.97
6.32
6.41
5.60
5.07
4.56
4.00
3.46
3.17
2.81
2.72
2.36
2.16
1.92
800. 00
0.31
0.25
0.21
0.46
900. 00
0.26
0.21
0.17
0.39
1000.00
0.21
0.17
0.14
0.32
1250.00
0.15
0.12
0.10
0.22
1500.00
0.11
' 0.09
0.07
0.16
1750.00
0.08
0.07
0.05
0.13
2000.00
0.07
0.05
0.04
0.10
2250.00
0.05
0.04
0.04
0.08
2500.00
0.05
0.04
0.03
0.07
3000.00
0.03
0.03
0.02
0.05
4000.00
0.02
0.02
0.01
0.03
5000.00
0.01
0.01
0.01
0.02
0.41
0.84
0.66
0.54
1.53
0.34
0.70
0.55
0.45
1.28
0.28
0.58
0.46
0.38
1.07
0.20
0.40
0.32
0.26
0.75
0.14
0.29
0.23
0.19
0.55
0.11
0.23
0.18
0.15
0.43
0.09
0.18
0.14
0.12
0.35
0.07
0.15
0.12
0.10
0.28
0.06
0.13
0.10
0.08
0.24
0.04
0.09
0.07
0.06
0.18
0.02
0.05
0.04
0.04
0.11
0.02
0.03
0.03
0.02
0.08
1.15
2.86
2.22
1.81
3.62
0.96
2.39
1.86
1.51
3.04
0.80
1.99
1.55
1.27
2.54
0.55
1.39
1.08
0.88
1.79
0.40
1.01
0.79
0.65
1.31
0.31
0.79
0.62
0.50
1.03
0.24
0.64
0.50
0.41
0.83
0.19
0.51
0.40
0.33
0.67
0.16
0.42
0.34
0.28
0.58
0.11
0.30
0.25
0.21
0.43
0.07
0.17
0.15
0.13
0.26
0.05
0.12
0.10
0.08
0.17
3.93
6.80
5.31
4.32
3.29
5.70
4.46
3.62
2.74
4.78
3.73
3.03
1.91
3.35
2.62
2.13
1.40
2.46
1.92
1.56
1.09
1.93
1.50
1.22
0.85
1.55
1.22
0.99
0.65
1.25
0.98
0.80
0.55
1.03
0.84
0.69
0.39
0.72
0.60
0.51
0.23
0.42
0.34
0.29
0.16
0.29
0.23
0.19
9.06
15.56
12.74
10.53
7.61
13.20
10.74
8.90
6.39
11.19
9.06
7.50
4.51
7.98
6.45
5.30
3.29
5.95
4.78
3.94
2.42
4.70
3.77
3.10
1.90
3.69
3.06
2.52
1.49
2.82
2.48
2.05
1.27
2.39
2.04
1.76
0.91
1.71
1.43
1.27
0.55
1.03
0.84
0.72
0.37
0.70
,- 0.57
0.48
19.42
16.54
13. 92
9.12
6.59
5.19
4.11
3.35
2.80
2.02
1.26
0.85
-------
10000
0.76
0.70
0.64
0.58
15000
0.34
0.33
0.30
0.28
33
39
45
51
25
197.79
13.74
18.82
205.97
50
150.67
9.64
13.63
144.37
100
95.54
5.53
8.09
84.65
200
49.54
2.54
3.86
40.65
300
30.74
1.48
2.29
24.45
400.
20.79
0.95
1.50
16.27
500.
15.25
0.68
1.08
11.82
600.
11.89
0.52
0.83
9.10
700.
9.52
0.41
0.65
.00
0.00
0.00
0.00
0.01
.00
0.00
0.00
0.00
0.00
X,m
34
40
46
52
.00
531.23
37.91
38.04
326.25
.00
418.86
27.43
28.14
239.25
.00
281.83
16.31
17.13
148.10
.00
157.74
7.80
8.40
76.80
.00
103.13
4.61
5.07
48.48
.00
72.63
3.02
3.36
33.31
,00
55.13
2.17
2.43
24.75
00
43.90
1.66
1.88
19.48
00
35.85
1.32
1.49
0.00
0.01
0.01
0.01
0.02
0.00
0.01
0.00
0.00
0.01
28
35
41
47
53
227.70
15.29
76.82
25.29
464.53
17-3.71
10.72
56.84
18.69
350.10
110.88
6.15
34.85
11.41
227.19
57.39
2.82
17.18
5.62
125.32
35.70
1.64
10.35
3.37
82.97
24.20
1.06
6.88
2.24
60.11
17.73
0.75
4.98
1.62
46.02
13.82
0.57
3.84
1.25
35.26
11.06
0.45
3.05
0.99
0.01
0.04
0.03
0.03
0.05
0.01
0.02
0.02
0.01 '
0.03
29
36
42
48
54
582.16
42.18
156.22
18.96
266.99
455.49
30.58
118.64
14.01
217.14
304.90
18.22
75.38
8.54
161.51
171.17
8.71
38.75
4 .19
109.38
112.45
5.16
23.97
2.53
84.03
79.89
3.38
16.21
1.68
61.02
60.69
2.43
11.87
1.21
48.45
48.50
1.86
9.24
0.93
40.27
39.75
1.47
7.41
0.74
0.05
0.09
0.07
0.06
0.02
0.04
0.04
0.03
30
37
43
49
17.21
85.68
23.56
31.09
12.12
63.59
17.07
21.45
6.93
38.96
10.13
11.98
3.18
19.21
4.83
5.33
1.85
11.62
2.86
3.04
1.20
7.71
1.87
1.94
0.85
5.58
1.35
1.36
0.65
4.30
1.03
1.03
0.51
3.42
0.82
0.80
0.11
0.21
0.18
0.15
0.05
0.10
0.09
0.08
31
38
44
50
47.59
174.50
47.63
75.22
34.53
132.69
35.23
53.33
20.56
84.22
21.49
30.80
9.83
43.48
10.54
14.24
5.83
26.94
6.38
8.27
3.82
18.22
4.22
5.35
2.74
13.34
3.05
3.80
2.10
10.39
2.35
2.89
1.66
8.31
' 1.87
2.27
0.25
0.12
32
97.32
72.04
44.21
21.88
13.20
8.78
6.36
4.90
3.89
7.24 15.72 26.92 34.82
-------
800.00
7.66 29.49
0.32 1.05
0.52 1.19
5.82 12.68
900.00
6.45 25.23
0.2"? 0.88
0.44 1.00
4.88 10.38
1000.00
5.43 21.57
0.22 0.73
0.36 0.84
4.05 8.39
1250.00
3.87 15.68
0.16 0.51
0.25 0.59
2.63 5.68
1500.00
2.86 11.85
0.11 0.38
0.19 0.44
1.87 4.10
1750.00
2.25 9.48
0.09 0.29
0.15 0.34
1.44 3.22
2000.00
1.83 7.82
0.07 0.24
0.12 0.28
1.14 2.54
2250.00
1.49 6.46
0.06 0.19
0.10 0.23
0.91 2.09
2500.00
1.28 5.57
0.05 0.16
0.08 0.19
0.77 1.72
3000.00
0.96 4.03
0.04 0.12
0.06 0.14
0.55 1.23
4000.00
0.59 2.29
0.02 0.08
0.04 0.09
0.33 0.76
5000.00
0.38 1.55
0.02 0.05
0.03 0.06
0.22 0.51
8.91
0.36
2.44
0.79
21.94
7.52
0.30
2.05
0.67
18.32
6.34
0.25
1.72
0.56
15.53
4.49
0.17
1.21
0.39
11.03
--3 . 32
0.13
0.89
0.29
8.33
2.62
0.10
0.70
0.23
6.42
2.13
0.08
0.57
0.19
5.26
1.73
0.06
0.46
0.15
4.30
1.48
0.05
0.39
0.13
3.66
1.11
0.04
0.29
0.10
2.68
0.64
0.02
0.18
0.06
1.64
0.42 -
0.02
0.13
0.04
1.10
32.81
1.17
5.99
0.59
30.24
28.11
0.98
5.04
0.50
26.84
24.10
0.82
4.24
0.42
23.87
17.65
0.57
3.01
0.30
18.59
13.43
0.42
2.23
0.22
15.02
10.77
0.33
1.76
0.17
12.57
8.85
0.27
1.43
0.14
10.48
7.23
0.21
1.17
0.11
9.03
5.99
0.18
1.00
0.10
7.69
4.20
0.14
0.75
0.07
5.95
2.51
0.08
0.47
0.04
3.77
1.72
0.06
0.33
0.03
2.59
0.40
2.74
0.65
0.63
0.34
2.30
0.55
0.52
0.28
1.93
0.46
0.43
0.20
1.36
0.32
0.29
0.14
1.00
0.23
0.20
0.11
0.78
0.18
0.15
0.09
0.63
0.15
0.12
0.07
0.51
0.12
0.09
0.06
0.44
0.10
0.08
0.05
0.33
0.08
0.06
0.03
0.20
0.05
0.03
0.02
0.14
0.03
0.02
1.33 3.11
6.70
1.50
1.79
1.11 ' 2.61
5.66
1.26
1.49
0.93 2.19
4.77
1.05
1.24
0.65 1.54
3.38
0.74
0.85
0.47 1.13
2.51
0.55
0.58
0.37 0.89
1.98
0.43
0.44
0.30 0.72
1.61
0.35
0.35
0.24 0.58
1.31
0.28
0.27
0.21 0.50
1.12
0.24
0.23
0.15 0.37
0.84
0.18
0.17
0.09 0.23
0.52
0.11
0.10
0.07 0.16
0.37
0.08
0.07
-------
10000.00
0.12 0.48
0.00 0.02
0.01 0.02
0.06 0.14
15000.00
0.06 0.24
0.00 0.01
0.01 0.01
0.03 0.06
X,m Max
25.00
50.00
100.00
200.00
300.00
400.00
500.00
600.00
700.00
800.00
900.00
1000.00
1250.00
1500.00
1750.00
2000.00
2250.00
2500.00
3000.00
4000.00
5000.00
10000.00
15000.00
Concentration (ppm)
LOG 1960.0000
IDLH 2442.0000
0.13 0.53
0.01 0.02
0.04 0.10
0.01 0.01
0.30 0.75
0.07 0.26 I
0.00 0.01
0.02 0.05
0.01 0.01
0.14 0.35
concentration, ppm
645.45
498.37
331.86
193.93
133.46
102.80
82.89
- 68 . 62
56.95
46.02
39.39
33.81
23.83
18.42
14.54
12.03
9.98
8.57
6.41
4.00
2.72
0.76
0.35
Distance to (m)
less than 25.00
less than 25.00
.01 0.02 C.05
0.04 0.11
0.01 0.03
0.01 0.02
.00 0.01 0.03
0.02 0.06
0.01 0.01
0.00 0.01
-------
From Slab output file:
Scenario:
Accident Location:
Duration:
Meteorology:
Chemical:
Vapor phase mole fraction:
LOG:
IDLH:
*0utput adjusted to be distance
RUN10.0UT
CONSERV
ON-SITE
MITIGAT
WORST
ACETONE
0.585
1960.000
2442.000
from fenceline.
6
12
18
24
25
234.74
230.43
235.70
230.94
50
182.75
178.20
182.34
179.93
100
115.60
120.69
122.25
120.95
200
64.10
66.17
70.85
69.11
300
44.42
43.87
46.26
46.54
400
33.63
32.26
32.22
33.79
500
26.77
25.18
24.63
24.75
600
21.79
20.09
19.63
19.39
700
18.79
17.15
15.77
15.56
X,m
7
13
19
25
.00
6.36
5.05
4.21
8.39
.00
4 .41
3.54
2.95
5.98
.00
2.51
2.02
1.68
3.48
.00
1.14
0.91
0.76
1.62
.00
0.66
0.53
0.44
0.95
.00
0.42
0.34
0.28
0.62
.00
0.30
0.24
0.20
0.44
.00
0.23
0.18
0.15
0.33
.00
0.18
0.14
0.12
0.26
1
8
14
20
26
8.56
15.01
11.88
9.83
22.60
-5.98
10.71
8.47
6.99
16.67
3.36
6.25
4.93
4.08
10.11
1.51
2.92
2.30
1.90
4.95
0.88
1.71
1.35
1.11
2.97
0.56
1.11
0.88
0.72
1.96
0.40
0.79
0.62
0.51
1.41
0.30
0.60
0.47
0.39
1.08
0.23
0.47
0.37
0.31
0.86
2
9
15
21
27
20.32
40.76
32.14
26.51
45.46
14.56
30.09
23.71
19.57
34.26
8.51
18.42
14.49
11.91
21.54
3.99
9.05
7.13
5.84
10.91
2.34
5.46
4.28
3.50
6.68
1.52
3.61
2.82
2.31
4.48
1.08
2.60
2.04
1.67
3.26
0.81
2.00
1.57
1.28
2.52
0.63
1.57
1.24
1.01
2.01
3
10
16
22
55.10
82.17
64.86
53.54
40.45
61.46
49.08
40.40
24.59
38.53
30.89
25.41
12.08
19.58
15.70
12.94
7.28
12.03
9.68
7.91
4.82
8.10
6.46
5.31
3.38
5.91
4.72
3.87
2.56
4.46
3.65
2.99
1.99
3.47
2.87
2.39
104
76
47
24
15
9
7
5
4
.
4 5
11
17
23
.37 156.74
143.85
123.22
104.61
.86 117.56
109.24
94.45
80.85
.63 75.28
69.75
61.15
52.49
.21 40.73
37.24
32.54
27.97
.00 24.82
23.81
20.62
17.67
.79 17.14
15.79
14.20
12.09
.02 12.86
11.48
10.57
8.98
.38 10.02
8.87
8.05
7.03
.21 7.98
6.98
6.31
5.55
-------
800.00
0.18
0.49
1.56
3.40
15.88
14.38
13.59
12.81
900
14.12
12.69
11.43
10.89
1000
12.35
10.99
10.07
9.31
1250
9.43
8.25
7.34
6.76
1500
7.44
6.47
5.66
5.16
1750
5.95
5.13
4.60
4.05
2000
5.00
4.33
3.66
3.37
2250
4.13
3.56
3.16
2.76
2500
3.54
3.08
2.66
2.37
3000
2.59
2.26
2.03
1.74
4000
1.62
1.41
1.27
1.11
5000
1.08
0.96
0.87
0.75
0.14
0.11
0.09
0.21
.00
0.11
0.09
0.08
0.17
.00
0.09
0.08
0.06
0.15
.00
0.06
0.05
0.04
0.10
.00
0.04
0.04
0.03
0.07
.00
0.03
0.03
0.02
0.06
.00
0.03
0.02
0.02
0.05
.00
0.02
0.02
0.01
0.04
.00
0.02
0.02
0.01
0.03
.00
0.01
0.01
0.01
0.02
.00
0.01
0.01
0.01
0.01
.00
0.01
0.00
0.00
0.01
0.38
0.30
0.25
0.69
0.15
0.31
0.25
0.20
0.57
0.12
0.25
0.21
0.17
0.48
0.08
0.17
0.14
0.12
0.34
6.06
0.12
0.10
0.08
0.24
0.05
0.10
0.08
0.06
0.19
0.04
0.08
0.06
0.05
0.15
0.03
0.06
0.05
0.04
0.12
0.02
0.05
0.04
0.04
0.10
0.02
0.04
0.03
0.03
0.07
0.01
0.02
0.02
0.02
0.05
0.01
0.02
0.01
0.01
0.03
1.22
0.99
'0.81
1.62
0.41
1.01
0.81
0.68
1.36
0.33
0.83
0.67
0.57
1.14
0.22
0.57
0.46
0.38
0.80
0.16
0.41
0.33
0.28
0.57
0.13
0.32
0.26
0.21
0.44
0.10
0.25
0.20
0.17
0.35
0.08
0.21
0.16
0.14
0.28
0.07
0.17
0.14
0.12
0.24
0.05
0.12
0.10
0.08
0.17
0.03
0.08
0.06
0.05
0.11
0.02
0.05
0.04
0.04
0.07
2.71
2.24
1.92
1.31
2.30
1.88
1.61
1.07
1.88
1.54
1.35
0.74
1.29
1.05
0.91
0.55
0.96
0.77
0.65
0.42
0.74
0.60
0.51
0.33
0.58
0.47
0.40
0.27
0.48
0.39
0.33
0.22
0.39
0.32
0.27
0.17
0.29
0.23
0.20
0.10
0.18
0.14
0.12
0.07
0.12
0.10
0.08
5.71
4.94
4.35
2.84
4.76
4.17
3.64
2.40
4.07
3.40
2.99
1.68
2.86
2.41
2.05
1.24
2.13
1.81
1.53
0.93
1.63
1.39
1.19
0.76
1.34
1.10
0.93
0.62
1.08
0.92
0.78
0.52
0.93
0.77
0.64
0.38
0.67
0.57
0.48
0.23
0.42
0.35
0.29
0.16
0.29
,< 0.24
0.20
5.57
4.83
3.44
2.60
2.08
1.63
1.39
1.14
0.87
0.53
0.36
-------
10000.
0. 30
0.29
0.26
0.23
15000.
0.14
0.13
0.12
0. 11
20000.
0.08
0. 07
0.07
0. 07
X
33
39
45
51
25.
78.72
5.87
7.82
77.25
50.
60.79
4.17
5.75
54.65
100.
39.52
2.42
3.48
32.37
200.
20.97
1.13
1.69
15.86
300.
13.19
0.66
1.01
9.26
400.
9.04
0.43
0.67
6.13
500.
6.68
0.31
0.48
4.44
600.
5.21
0.23
0.37
3.39
00
0.00
0.00
0.00
0.00
00
0.00
0.00
0.00
0.00
00
0.00
0.00
0.00
0.00
, m
34
40
46
52
00
200.48
15.71
15.56
119.46
00
159.18
11.53
11.70
88.08
00
108.61
7.03
7.31
55.08
00
62.23
3.41
3.67
26.48
00
41.27
2.05
2.23
16.70
00
29.51
1.35
1.49
11.62
00
22.54
0.97
1.09
8.62
00
18.12
0.75
0.84
6.61
0.00
0.01
0.00
0.00
0.01
0.00
0.00
0.00
0.00
0.01
0.00
0.00
0.00
0.00
0.00
28
35
41
47
53
90.23
6.52
31.38
10.33
169.69
69.65
4.64
23.63
7.80
128.01
45.28
2.70
14.76
4.85
77.24
24.07
1.26
7.43
2.44
40.78
15.19
0.73
4.55
1.49
26.67
10.39
0.48
3.05
0.99
19.35
7.68
0.34
2.22
0.72
14.99
6.01
0.26
1.71
0.56
11.90
0.01
0.02
0.01
0.01
0.02
0.00
0.01
0.01
0.01
0.01
0.00
0.01
0.00
0.00
0.01
29
36
42
48
54
217.33
17.46
62.71
7.74
282.55
171.03
12.89
48.39
5.83
205.93
116.01
7.79
31.38
3.64
130.71
66.22
3.80
16.57
1.83
73.27
44.12
2.28
10.41
1.11
49.88
31.74
1.50
7.10
0.75
37.77
24.42
1.08
5.23
0.54
30.36
18.84
0.83
4.09
0.42
25.32
0.02
0.04
0.03
0.03
0.01
0.02
0.02
0.01
0.01
0.01
0.01
0.01
30
37
43
49
7.33
34.98
9.75
13.27
5.23
26.35
7.21
9.24
3.04
16.50
4.36
5.22
1.41
8.32
2.12
2.35
0.83
5.09
1.27
1.35
0.54
3.41
0.83
0.84
0.38
2.48
0.60
0.59
0.29
1.92
0.46
0.44
0.05
0.09
0.08
0.06
0.02
0.04
0.04
0.03
0.01
0.03
0.02
0.02
31
38
44
50
19.70
70.00
19.47
30.47
14.49
53.89
14.65
21.78
8.79
34.99
9.13
12.74
4.30
18.54
4.60
6.00
2.58
11.66
2.80
3.47
1.70
7.92
1.87
2.21
1.22
5.87
1.36
1.56
0.94
4.59
1.05
1.17
0.10
0.05
0.03
32
39.53
29.77
18.67
9.45
5.78
3.87
2.81
2.18
-------
4.19
0.18
0.29
2.62
3.39
0.15
0.23
2.18
2.86
0.12
0.20
1.77
2.40
0.10
0.16
1.53
1.63
0.07
0.11
1.06
1.18
0.05
0.08
0.78
0.92
0.04
0.07
0.59
0.73
0.03
0.05
0.48
0.59
0.03
0.04
0.39
0.50
0.02
0.04
0.33
0.36
0.02
0.03
0.24
0.23
0.01
0.02
0.15
700.00
14.55
0.59
0.67
5.42
800.00
11.51
0.47
0.54
4.39
900.00
9.77
0.40
0.45
3.74
1000.00
8.07
0.33
0.38
3.10
1250.00
5.69
0.23
0.27
2.23
1500.00
4.35
0.17
0.20
1.70
1750.00
3.39
0.13
0.16
1.31
2000.00
2.71
0.11
0.13
1.06
2250.00
2.26
0.09
0.10
0.87
2500.00
1.90
0.07
0.09
0.73
3000.00
1.43
0.05
0.07
0.54
4000.00
0.90
0.03
0.04
0.32
4.83
0.20
1.36
0.44
9.81
3.90
0.16
1.09
0.36
8.25
3.25
0.14
0.92
0.30
7.10
2.67
0.11
0.77
0.25
6.08
"1.81
0.08
0.55
0.18
4.42
1.33
0.06
0.40
0.13
3.44
1.04
0.04
0.32
0.10
2.70
0.82
0.04
0.25
0.08
2.19
0.68
0.03
0.20
0.07
1.81
0.56
0.02
0.17
0.06
1.52
0.41
0.02
0.12
0.04
1.12
0.26
0.01
0.08
0.03
0.68
14.99
0.66
3.28
0.33
21.15
11.96
0.53
2.65
0.27 '
18.48
10.28
0.44
2.24
0.23
15.84
8.64
0.37
1.90
0.19
14.18
6.21
0.26
1.35
0.13
10.64
4.72
0.19
1.00
0.10
8.26
3.65
0.15
0.76
0.08
6.78
3.01
0.12
0.61
0.06
5.46
2.47
0.09
0.49
0.05
4.64
2.13
0.08
0.42
0.04
3.83
1.58
0.06
0.30
0.03
2.90
1.00
0.04
0.19
0.02
1.74
0.23
1.53
0.37
0.34
0.18
1.22
0.29
0.26
0.15
1.03
0.25
0.22
0.13
0.87
0.21
0.18
0.09
0.61
0.14
0.12
0.06
0.45
0.11
0.09
0.05
0.34
0.08
0.07
0.04
0.27
0.07
0.05
0.03
0.22
0.05
0.04
0.03
0.19
0.05
0.03
0.02
0.14
0.03
0.03
0.01
0.08
0.02
0.02
0.75
3.68
0.84
0.90
0.59
2.98
0.67
0.72
0.50
2.52
0.57
0.59
0.42
2.13
0.48
0.50
0.29
1.51
0.34
0.34
0.21
1.08
0.25
0.25
0.16
0.84
0.20
0.19
0.13
0.67
0.16
0.15
0.10
0.53
0.13
0.12
0.09
0.45
0.11
0.10
0.06
0.33
0.08
0.07
0.04
0.21
'- 0.05
0.04
1.74
1.39
1.17
0.98
0.69
0.49
0.38
0.30
0.24
0.21
0.15
0.09
-------
5000.00
0.18
0.69
0.01
0.03
0.16
0.01
0.01
0.10
10000
0.05
0.00
0.00
0.03
15000
0.03
0.00
0.00
0.01
20000
0.02
0.00
0.00
0.01
0.63
0.02
0.03
0.22
.00
0.20
0.01
0.01
0.06
.00
0.10
0.00
0.00
0.03
.00
0.06
0.00
0.00
0.02
0.01
0.05
0.02
0.45
0.06
0.00
0.02
0.01
0.12
0.03
0.00
0.01
0.00
0.05
0.02
0.00
0.01
0.00
0.03
0.02
0.13
0.01
1.17
0.21
0.01
0.04
0.01
0.31
0.11
0.00
0.02
0.00
0.14
0.06
0.00
0.01
0.00
0.08
0.06
0.01
0.01
0.00
0.02
0.00
0.00
0.00
0.01
0.00
0.00
0.00
0.01
0.00
0.00
0.14
0.03
0.03
0.01
0.05
0.01
0.01
0.00
0.02
0.01
0.00
0.00
0.02
0.00
0.00
X,m Max concentration, ppm
25.00
50.00
100.00
200.00
300.00
400.00
500.00
600.00
700.00
800.00
900.00
1000.00
1250.00
1500.00
1750.00
2000.00
2250.00
2500.00
3000.00
4000.00
5000.00
10000.00
15000.00
20000.00
282.55
205.93
130.71
73.27
49.88
37.77
30.36
25.32
21.15
18.48
15.84
14.18
10.64
8.26
6.78
5.46
4.64
3.83
2.90
1.74
1.17
0.31
0.14
0.08
C.06
0.01
c.o:
o.oi
Concentration (ppm)
Distance to (m)
LOG
IDLH
1960.0000
2442.0000
less than
less than
25.00
25.00
-------
From Slab output file: RUNlla.OUT
Scenario: CONSERV
Accident Location: ON-SITE
. Duration: UNMITIG
Meteorology: INVERSN
Chemical: ACETONE
Vapor phase mole fraction: 0.562
LOG: 1960.000
IDLH: 2442.000
*0utput adjusted to be distance from fenceline.
X,m Max concentration, ppm
25.00
50.00
100.00
200.00
300.00
400.00
500.00
600.00
700.00
800.00
900.00
1000.00
1250.00
1500.00
1750.00
2000.00
2250.00
2500.00
3000.00
4000.00
5000.00
10000.00
15000.00
20000.00
735.61
568.75
382.90
225.68
155.19
116.89
92.26
-- 74.58
63.70
53.73
47.47
41.92
31.77
24.83
20.39
17.02
14.42
12.31
9.42
6.02
4.27
1.35
0.66
0.39
Concentration (ppm) Distance to (m)
LOC 1960.0000 less than 25.00
IDLH 2442.0000 less than 25.00
-------
From Slab output file:
Scenario:
Accident Location:
Duration:
Meteorology:
Chemical:
Vapor phase mole fraction:
LOG:
IDLH:
RUNllb.OUT
CONSERV
ON-SITE
UNMITIG
INVERSN
ACETONE
0.225
1960.000
2442.000
*0utput adjusted to be distance from fenceline.
X,m Max concentration, ppm
25.00
50.00
100.00
200.00
300.00
400.00
500.00
600.00
700.00
800.00
900.00
1000.00
1250.00
1500.00
1750.00
2000.00
2250.00
2500.00
3000.00
4000.00
5000.00
10000.00
15000.00
20000.00
71.17
59.78
45.87
32.64
25.58
21.25
18.24
-- 15.95
14.17
12.85
11.67
10.73
8.89
7.57
6.58
5.78
5.16
4.65
3.85
2.84
2.22
1.00
0.62
0.44
Concentration (ppm)
LOC
IDLH
1960.0000
2442.0000
Distance to (m)
less than
less than
25.00
25.00
-------
From Slab output file: RUN12.0UT
Scenario: CONSERV
Accident Location: ON-SITE
Duration: MITIGAT
Meteorology: INVERSN
Chemical: ACETONE
Vapor phase mole fraction: 0.591
LOC: 1960.000
IDLH: 2442.000
*Output adjusted to be distance from fenceline.
X,m Max concentration, ppm
25.00
50.00
100.00
200.00
300.00
400.00
500.00
600.00
700.00
800.00
900.00
1000.00
1250.00
1500.00
1750.00
2000.00
2250.00
2500.00
3000.00
4000.00
5000.00
10000.00
15000.00
20000.00
169.90
135.09
93.44
58.74
41.97
32.55
26.61
- 22.14
18.66
16.22
14.06
12.41
9.34
7.50
6.08
4 .96
4.20
3.56
2.69
1.66
1.12
0.31
0. 14
0.08
Concentration (ppm) Distance to (m)
LOC 1960.0000 less than 25.00
IDLH 2442.0000 less than 25.00
-------
From Slab output file:
Scenario:
Accident Location:
Duration:
Meteorology:
Chemical:
Vapor phase mole fraction:
LOG:
IDLH:
RUN13.0UT
TYPICAL
ON-SITE
UNMITIG
TYPICAL
FORMALDEHYDE
0.482
9.600
19.600
*0utput adjusted to be distance from fenceline.
X,m Max concentration, ppm
25.00
50.00
100.00
200.00
300.00
400.00
500.00
600.00
700.00
800.00
900.00
1000.00
1250.00
1500.00
1750.00
2000.00
2250.00
2500.00
3000.00
4000.00
5000.00
24.22
16.68
9.66
4.35
2.59
1.69
1.21
- 0.92
0.72
0.57
0.48
0.40
0.28
0.20
0.16
0.12
0.10
0.08
0.06
0.04
0.03
Concentration (ppm)
LOG
IDLH
Distance to (m)
9.6000
19.6000
101.04
40.32
-------
From Slab output file: RUN14.0UT
Scenario: TYPICAL
Accident Location: ON-SITE
Duration: MITIG
Meteorology: TYPICAL
Chemical: FORMALDEHYDE
Vapor phase mole fraction: 0.512
LOC: 9.600
IDLH: 19.600
"Output adjusted to be distance from fenceline.
X,m Max concentration, ppm
25
50
100
200
300
400
500
600
700
800
900
1000
1250
1500
1750
2000
2250
2500
3000
4000
5000
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
24
16
9
4
2
1
1
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.65
.98
.84
.43
.65
.73
.24
.94
.74
.58
.49
.41
.28
.20
.16
.12
.10
.08
.06
.04
.03
Concentration (ppm) Distance to (m)
LOC 9.6000 104.49
IDLH 19.6000 41.46
-------
From Slab output file:
Scenario :
Accident Location:
. Duration:
Meteorology:
Chemical:
Vapor phase mole fraction:
LOG:
IDLH:
RUN15.0UT
TYPICAL
ON-SITE
UNMITIG
WORST
FORMALDEHYDE
0.482
9.600
19.600
*Output adjusted to be distance from fenceline.
6
12
18
24
25
245.18
223.21
194 .07
166.96
50
183.81
164.37
142.21
122.01
100
119.82
104.81
89.63
76.06
200
57.32
53.70
44 .83
37.73
300
35.12
32.95
28.27
23.67
400
24.01
21.29
18.40
16.08
500
17.36
15.24
12.96
11.82
600
13.62
11.43
9.71
8.88
700
10.82
8.82
7.40
6.80
X,m
7
13
19
25
.00
2.83
2.27
1.89
3.89
.00
1.85
1.48
1.23
2.59
.00
1.01
0.80
0.67
1.43
.00
0.42
0.33
0.28
0.61
.00
0.24
0.19
0.16
0.35
.00
0.15
0.12
0.10
0.22
.00
0.11
0.08
0.07
0.16
.00
0.08
0.06
0.05
0.12
.00
0.06
0.05
0.04
0.09
1
8
14
20
26
3.78
6.82
5.44
4.54
10.66
'2.47
4.53
3.62
3.02
7.21
1.34
2.51
2.00
1.67
4.09
0.56
1.06
0.85
0.71
1.80
0.32
0.61
0.49
0.41
1.06
0.20
0.39
0.31
0.26
0.68
0.14
0.27
0.22
0.18
0.49
0.10
0.20
0.16
0.14
0.37
0.08 -
0.16
0.13
0.11
0.29
2
9
15
21
27
9.11
18.81
14.93
12.45
22.11
6.03
12.73
10.10
8.41
15.19
3.34
7.23
5.74
4.77
8.78
1.41
3.18
2.53
2.10
3.96
0.82
1.87
1.49
1.23
2.36
0.52
1.21
0.96
0.80
1.54
0.36
0.86
0.68
0.57
1.11
0.27
0.65
0.52
0.43
0.84
0.20
0.50
0.40
0.34
0.66
3
10
16
22
25.48
39.64
31.28
25.90
17.25
27.30
21.55
17.82
9.82
15.84
12.49
10.30
4.31
7.14
5.61
4.64
2.53
4.24
3.35
2.77
1.64
2.76
2.18
1.81
1.16
1.98
1.56
1.29
0.86
1.50
1.19
0.98
0.66
1.17
0.93
0.77
4
11
17
23
53.76
83.41
66.10
54.60
37.21
58.93
46.44
38.27
21.64
35.06
27.63
22.72
9.73
16.34
12.84
10.54
5.79
9.88
7.80
6.40
3.77
6.55
5.13
4.24
2.62
4.57
3.72
3.06
1.94
3.39
2.85
2.35
1.48
2.59
2.22
1.85
5
109.91
77.76
46.56
21.90
13.00
8.22
5.77
4.28
3.23
-------
800.00
0.06
0.16
0.51
1.17
8.81
7.30
6.10
5.36
7.33
5.99
4.90
4.46
6.31
5.08
4.22
3.70
4.41
3.48
2.91
2.56
3.19
2.58
2.12
1.89
2.51
2.03
1.68
1.43
1.98
1.57
1.33
1.16
1.63
1.33
1.10
0. 94
1.31
1.10
0.90
0.81
0.96
0.81
0.67
0.59
0.56
0.49
0.40
0.37
33
39
45
51
0.05
0.04
0.03
0.07
900.00
0.04
0.03
0.03
0.06
1000.00
0.03
0.03
0.02
0.05
1250.00
0.02
0.02
0.01
0.03
1500.00
0.02
0.01
0.01
0.02
1750.00
0.01
0.01
0.01
0.02
2000.00
0.01
0.01
0.01
0.01
2250.00
0.01
0.01
0.01
0.01
2500.00
0.01
0.01
0.00
0.01
3000.00
0.00
0.00
0.00
0.01
4000.00
0.00
0.00
0.00
0.00
X,m
34
40
46
52
0.12
0.10
0.08
0.23
0.05
0.10
0.08
0.07
0.19
0.04
0.08
0.07
0.06
0.16
0.03
0.06
0.05
0.04
0.11
"0.02
0.04
0.03
0.03
0.08
0.02
0.03
0.03
0.02
0.06
0.01
0.02
0.02
0.02
0.05
0.01
0.02
0.02
0.01
0.04
0.01
0.02
0.01
0.01
0.03
0.01
0.01
0.01
0.01
0.02
0.00
0.01
0.01
0.01
0.01
28
35
41
47
53
0.39
0.32
0.26
0.52
0.13
0.32
0.27
0.22
0.44
0.11
0.26
0.22
0.18
0.37
0.07
0.18
0.15
0.13
0.26
0.05
0.13
0.11
0.09
0.18
0.04
0.10
0.08
0.07
0.14
0.03
0.08
0.07
0.06
0.11
0.03
0.07
0.05
' 0.04
0.09
0.02
0.05
0.04
0.04
0.08
0.02
0.04
0.03
0.03
0.06
0.01
0.02
0.02
0.02
0.03
29
36
42
48
54
0.90
0.74
0.61
0.43
0.75
0.62
0.52
0.35
0.61
0.50
0.43
0.23
0.41
0.34
0.29
0.17
0.30
0.25
0.21
0.13
0.23
0.19
0.16
0.10
0.18
0.15
0.13
0.09
0.15
0.12
0.10
0.07
0.12
0.10
0.09
0.05
0.09
0.07
0.06
0.03
0.06
0.05
0.04
30
37
43
49
2.06
1.71
1.48
0.96
1.69
1.43
1.23
0.80
1.41
1.16
1.00
0.54
0.97
0.80
0.67
0.40
0.72
0.59
0.50
0.30
0.54
0.45
0.39
0.24
0.44
0.3b
0.30
0.20
0.35
0.30
0.25
0.16
0.30
0.24
0.21
0.12
0.22
0.18
0.15
0.07
0.13
0.11
0.09
31
38
' 44
50
2.67
2.12
1.25
0.90
0.71
0.56
0.46
0.38
0.27
0.17
32
-------
40.47
2.73
3.75
39.32
28.35
1.81
2.54
26. 69
16.79
1 . 00
1.43
15.20
7.81
0. 42
0.63
6. 66
4 . 74
0 .24
0.37
3. 85
3. 14
0. 16
0.24
2.40
2.27
0.11
0.17
1 . 67
1 .74
0. 08
0.13
1.23
1.38
0. 06
0.10
0.93
1.10
0.05
0.08
0.75
0.93
0.04
0.07
0.61
0.77
0.03
0.06
0.51
25. 00
125.85
7.47
7.67
80.04
50.00
91.42
5.07
5.26
55.56
100.00
56.64
2.86
3.05
32.49
200.00
27.95
1.26
1.38
14.75
300.00
17.51
0.74
0.82
8.30
400.00
11.85
0.48
0.53
5.29
500.00
8.73
0.34
0.38
3.71
600.00
6.78
0.26
0.29
2.73
700.00
5.40
0.20
0.23
2.08
800.00
4.35
0.16
0.18
1.70
900.00
3.64
0.13
0.15
1.35
1000.00
2.94
0.11
0.13
1.16
46.43
3.03
15.40
5.12
142.45
32.57
2.01
10.58
3.52
102.38
19.30
1.11
6.14
2.03
62.81
8.96
0.47
2.76
0.92
28.18
5.44
0.27
1.65
0.55
16.50
3.60
0.17
1.07
0.36
10.95
2.61
0.12
0.77
0.26
7.75
2.00
0.09
0.59
0.20
5.81
1.58
0.07
0.46
0.15
4.63
1.26
0.05
0.36
0.12
3.62
1.07
0.05
0.31
0.10
3.08
0.89
0.04
0.26
0.09
2.57
143.87
8.31
32.23
3.84
252.35
104.75
5.62
22.56
2.64
182.53
65.22
3.18
13.36
1.53
115.80
32.22
1.39
6.23
0.69
62.96
20.17
0.82
3.77
0.41
41.16
13.68
0.53
2.50
0.27
29.51
10.07
0.38
1.81
0.19
22.23
7.81
0.29
1.39
0.15
16.96
6.14
0.22
1.10
0.11
14.09
4.74
0.18
0.88
0.09
11.29
3.97
0.15
0.74
0.08
9.71
3.24
0.12
0.62
0.06
8.12
3.41
17.11
4.66
5.67
2.26
11.77
3.15
3.70
1.25
6.80
1.79
2.01
0.53
3.07
0.79
0.83
0.31
1.83
0.46
0.48
0.19
1.20
0.30
0.29
0.14
0.86
0.21
0.20
0.10
0.65
0.16
0.15
0.08
0.51
0.13
0.11
0.06
0.41
0.10
0.09
0.05
0.34
0.08
0.07
0.04
0.28
0.07
0.06
9.33
35.86
9.60
13.63
6.31
25.13
6.60
9.06
3.58
14.88
3.82
5.00
1.57
6.90
1.72
2.12
0.92
4.19
1.03
1.22
0.60
2.78
0.67
0.76
0.43
2.01
0.48
0.52
0.32
1.54
0.37
0.39
0.25
1.22
0.29
0.29
0.20
0.97
0.23
0.23
0.17
0.82
0.19
0.19
0.14
0.69
.- 0.16
0.16
19.30
13.26
7.68
3.46
2.06
1.35
0.97
0.73
0.58
0.46
0.39
0.32
-------
0.55
0.02
0.04
0.35
0.39
0.02
0.03
0.25
0.30
0.01
0.02
0.19
0.24
0.01
0.02
0.15
0.19
0.01
0.01
0.12
0.16
0.01
0.01
0.10
0.12
0.01
0.01
0.07
0.07
0.00
0.01
0.04
1250.00
1.99
0.08
0.09
0.78
1500.00
1.48
0.06
0.07
0.56
1750.00
1.15
0.04
0.05
0.44
2000.00
0.89
0.04
0.04
0.34
2250.00
0.75
0.03
0.03
0.28
2500.00
0.61
0.02
0.03
0.23
3000.00
0.46
0.02
0.02
0.16
4000.00
0.28
0.01
0.01
0.10
0.60
0.03
0.18
0.06
1.76
0.43
0.02
0.13
0.04
1.29
0.34
0.01
0.10
0.03
0.97
0.27
0.01
0.08
0.03
0.79
6.22
0.01
0.07
0.02
0.62
0.18
0.01
0.06
0.02
0.53
0.13
0.01
0.04
0.01
0.38
0.08
0.00
0.02
0.01
0.22
2.20
0.09
0.44
0.04
5.74
1.65
0.06
0.32
0.03
4.21
1.27
0.05
0.26
0.03
3.17
1.00
0.04
0.21
0.02
2.56
0.83
0.03
0.16
0.02
2.04
0.70
0.03
0.14
0.01
1.69
0.52
0.02
0.10
0.01
1.17
0.32
0.01
0.06
0.01
0.68
0.03
0.20
0.05
0.04
0.02
0.15
0.04
0.03
0.02
0.12
0.03
0.02
0.01
0.09
0.02
0.02
0.01
0.07
0.02
0.01
0.01
0.06
0.02
0.01
0.01
0.05
0.01
0.01
0.00
0.03
0.01
0.00
0.10
0.49
0.11
0.11
0.07
0.36
0.08
0.08
0.06
0.28
0.06
0.06
0.04
0.22
0.05
0.05
0.03
0.18
0.04
0.04
0.03
0.15
0.04
0.03
0.02
0.11
0.03
0.02
0.01
0.07
0.02
0.01
0.22
0.16
0.13
0.10
0.08
0.07
0.05
0.03
X,m Max concentration, ppm
25.00
50.00
100.00
200.00
300.00
400.00
500.00
600.00
700.00
800.00
900.00
1000.00
1250.00
1500.00
1750.00
2000.00
2250.00
2500.00
252.35
183.81
119.82
62.96
41.16
29.51
22.23
16.96
14.09
11.29
9.71
8.12
5.74
4.21
3.17
2.56
2.04
1.69
-------
3000.00 1.17
4000.00 0.68
Concentration (ppm) Distance to (m)
LOG 9.6000 906.64
IDLH 19.6000 549.87
-------
From Slab output file:
Scenario :
Accident Location:
Duration:
Meteorology:
Chemical :
Vapor phase mole fraction:
LOG:
IDLH:
RUN16.0UT
TYPICAL
ON-SITE
MIT I GAT
WORST
FORMALDEHYDE
0.5.12
9.600
19.600
*0utput adjusted to be distance from fenceline.
6
12
18
24
25
241.68
221.68
194.45
167.97
50
181.60
164.02
142.66
123.25
100
114.17
104.64
90.05
77.17
200
55.57
53.44
45.28
38.30
300
33.92
31.41
27.66
24.08
400
23.32
20.78
17.81
16.37
500
17.32
14.92
12.68
11.49
600
13.54
11.10
9.47
8.57
700
10.51
8.89
7.31
6.55
X,m
7
13
19
25
.00
2.88
2.31
1.92
3.96
.00
1.89
1.51
1.26
2.63
.00
1.02
0.82
0.68
1.46
.00
0.43
0.34
0.28
0.62
.00
0.24
0.19
0.16
0.36
.00
0.15
0.12
0.10
0.23
.00
0.11
0.09
0.07
0.16
.00
0.08
0.06
0.05
0.12
.00
0.06
0.05
0.04
0.09
1
8
14
20
26
3.85
6.95
5.55
4.62
10.86
--2. 51
4.61
3.69
3.07
7.34
1.37
2.56
2.04
1.70
4.17
0.57
1.08
0.87
0.72
1.83
0.32
0.63
0.50
0.42
1.08
0.20
0.40
0.32
0.26
0.70
0.14
0.28
0.22
0.19
0.50
0.10
0.21
0.17
0.14
0.38
0.08
0.16
0.13
0.11
0.29
2
9
15
21
27
9.23
19.13
15.20
12.66
22.47
6.14
12.99
10.30
8.56
15.50
3.40
7.38
5.85
4.86
8.96
1.45
3.25
2.58
2.14
4.05
0.83
1. 91
1.52
1.26
2.41
0.53
1.24
0.98
0.81
1.58
0.37
0.88
0.70
0.58
1.13
0.27
0.67
0.53
0.44
0.86
0.21
0.51
0.41
0.34
0.67
3
10
16
22
25.94
40.31
31.82
26.33
17.59
27.79
21.94
18.14
10.02
16.14
12.73
10.53
4.40
7.28
5.75
4.74
2.59
4.33
3.42
2.83
1.67
2.83
2.23
1.84
1.16
2.02
1.60
1.32
0.86
1.50
1.21
1.01
0.65
1.15
0.94
0.79
4
11
17
23
54.75
84.61
67.25
55.49
37.85
59.49
47.24
38.96
22.01
35.62
28.12
23.15
9.93
16.65
13.08
10.79
5.91
10.07
7.94
6.53
3.74
6.69
5.25
4.32
2.59
4.66
3.80
3.13
1.92
3.45
2.84
2.40
1.46
2.63
- 2.17
1.87
5
110.58
78.38
47.19
22.18
12.61
8.10
5.72
4.22
3.27
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25.
41.13
2.77
3.82
39.86
50.
28.85
1.84
2.58
27.13
100.
17.13
1.02
1.46
15.49
200.
7.99
0.43
0.64
6.82
300.
4.84
0.25
0.38
3.80
400.
3.21
0.16
0.24
2.40
500.
2.32
0.11
0.17
1.68
600.
1.78
0.08
0.13
1.23
700.
1.41
0.06
0.10
0.92
800.
1.12
0.05
0.08
0.76
900.
0.95
0.04
0.07
0.60
1000.
0.79
0.03
0.06
0.52
00
127.50
7.60
7.80
80.52
00
92.88
5.14
5.38
55.86
00
57.75
2.92
3.11
32.81
00
28.47
1.28
1.40
14.39
00
17.83
0.75
0.84
8.19
00
12.09
0.49
0.55
5.27
00
8.90
0.35
0.39
3.69
00
6.91
0.26
0.30
2.70
00
5.43
0.21
0.23
2.11
00
4.20
0.16
0.19
1.69
00
3.53
0.14
0.16
1.38
00
2.88
0.11
0.13
1.15
47.21
3.08
15.64
5.20
141.28
33.12
2.05
10.76
3.58
101.88
19.68
1.14
6.23
2.07
60.70
9.16
0.48
2.81
0.94
27.53
5.56
0.28
1.68
0.56
16.10
3.68
0.18
1.10
0.36
10.73
2.67
0.12
0.79
0.26
7.57
2.04
0.09
0.60
0.20
5.88
1.61
0.07
0.47
0.16
4.57
1.28
0.06
0.37
0.12
3.70
1.08
0.05
0.31
0.10
3.04
0.87
0.04
0.26
0.09
2.59
145.62
8.44
32.73
3.90
236.20
106.02
5.71
22.96
2.68
171.82
66.35
3.24
13.61
1.56
110.32
32.80
1.43
6.36
0.70
60.81
20.54
0.84
3.85
0.42
40.61
13.93
0.54
2.55
0.27
29.13
10.26
0.39
1.85
0.20
21.75
7.69
0.29
1.42
' 0.15
17.33
5.88
0.23
1.12
0.12
13.96
4.65
0.18
0.89
0.09
11.52
3.87
0.15
0.76
0.08
9.56
3.22
0.13
0.63
0.07
8.22
3.47
17.43
4.75
5.75
2.30
11.97
3.21
3.77
1.28
6.93
1.82
2.05
0.54
3.13
0.80
0.85
0.31
1.87
0.47
0.49
0.20
1.22
0.30
0.30
0.14
0.87
0.22
0.20
0.10
0.67
0.16
0.15
0.08
0.52
0.13
0.11
0.06
0.41
0.10
0.09
0.05
0.35
0.09
0.07
0.04
0.29
0.07
0.06
9.51
36.46
9.75
13.86
6.44
25.59
6.70
9.21
3.65
15.17
3.89
5.10
1.60
7.08
1.76
2.16
0.94
4.28
1.05
1.23
0.61
2.84
0.69
0.76
0.43
2.06
0.49
0.53
0.33
1.58
0.37
0.39
0.26
1.24
0.29
0.29
0.20
0.99
0.23
0.24
0.17
0.84
0.20
0.19
0.14
0.70
, 0.16
0.16
19. 62
13.50
7.81
3.53
2.11
1.38
0.99
0.75
0.59
0.47
0.39
0.33
-------
1250.00
0.59
0.03
0.10
0
0
0
0
0
0
0
0
o
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.53
.02
.04
.35
.39
.02
.03
.25
.30
.01
.02
.19
.24
.01
.02
.15
.19
.01
.01
.12
.16
.01
.01
.10
.12
.01
.01
.07
.07
.00
.01
.05
1.
0.
0.
0.
1500.00
1.
0.
0.
0.
1750.00
1
0. .
0.
0.
0.
2000.00
0.
0.
0.
0.
2250.00
0.
0.
0.
0.
2500.00
0.
0.
0.
0.
3000.00
0.
0.
0.
0.
4000.00
0.
0.
0.
0.
96
08
09
78
47
06
07
57
13
05
05
44
90
04
04
34
74
03
03
28
62
02
03
23
46
02
02
17
29
01
01
10
c
0
0
1
0.43
0
0
0
1
0.34
0
0
0
0
0.26
0
0
0
0
O.22
0
0
0
0
0.18
0
0
0
0
0.13
0
0
0
0
0.08
0
0
0
0
.03
.18
.06
.78
.02
.13
.04
.29
.02
.11
.04
.99
.01
.09
.03
.79
.01
.07
.02
.64
.01
.06
.02
.53
.01
.04
.01
.37
.00
.03
.01
.22
0
0
b
5
1.64
0
0
0
4
1.24
0
0
0
3
1.01
0
0
0
2
0.82
0
0
0
2
0.70
0
0
0
1
0.52
0
0
0
1
0.32
0
0
0
0
.09
.45
.05
.69
.06
.33
.03
.07
.05
.26
.03
.24
.04
.20
.02
.51
.03
.16
.02
.08
.03
.14
.01
.66
.02
.10
.01
.22
.01
.06
.01
.69
0
0
0
0.02
0
0
0
0.02
0
0
0
0.01
0
0
0
0.01
0
0
0
0.01
0
0
0
0.01
0
0
0
0.00
0
0
0
.20
.05
.04
.15
.04
.03
.12
.03
.02
.09
.02
.02
.07
.02
.01
.06
.02
.01
.05
.01
.01
.03
.01
.00
0
0
0
0.07
0
0
0
0.06
0
0
0
0.04
0
0
0
0.04
0
0
0
0.03
0
0
0
0.02
0
0
0
0.01
0
0
0
.50
.11
.11
.35
.08
.08
.28
.07
.06
.22
.05
.05
.18
.04
.04
.15
.04
.03
.11
.03
.02
.07
.02
.01
0.23
0.16
0.13
0.10
0.08
0.07
0.05
0.03
X,m Max concentration, ppm
25.00
50.00
100.00
200.00
300.00
400.00
500.00
600.00
700.00
800.00
900.00
1000.00
1250.00
1500.00
1750.00
2000.00
2250.00
2500.00
241.68
181.60
114.17
60.81
40.61
29.13
21.75
17.33
13.96
11.52
9.56
8.22
5.69
4.07
3.24
2.51
2.08
1.66
-------
3000.00 1.22
4000.00 0.69
Concentration (ppm) Distance to (m)
LOG 9.6000 897.85
IDLH 19.6000 548.56
-------
From Slab output file:
Scenario:
Accident Location:
Duration:
Meteorology:
Chemical:
Vapor phase mole fraction:
LOG:
IDLH:
RUN17.0UT
TYPICAL
ON-SITE
UNMITIG
INVERSN
FORMALDEHYDE
0.477
9.600
19.600
"Output adjusted to be distance from fenceline.
X,m Max concentration, ppm
25.00
50.00
100.00
200.00
300.00
400.00
500.00
600.00
700.00
800.00
900.00
1000.00
1250.00
1500.00
1750.00
2000.00
2250.00
2500.00
3000.00
4000.00
5000.00
273
220
158
101
74
57
46
-- 37
31
26
22
19
14
10
8
6
5
4
3
1
1
.47
.48
.08
.63
.56
.80
.10
.41
.40
.42
.54
.49
.06
.39
.08
.46
.12
.32
.04
.72
.09
Concentration (ppm)
LOC
IDLH
9.6000
19.6000
Distance to (m)
1585.71
996.50
-------
From Slab output file:
Scenario:
Accident Location:
Duration:
Meteorology:
Chemical:
Vapor phase mole fraction:
LOG:
IDLH:
RUN18.OUT
TYPICAL
ON-SITE
MITIGAT
INVERSN
FORMALDEHYDE
0.676
9.600
19.600
*0utput adjusted to be distance from fenceline.
X,m Max concentration, ppm
25.00
50.00
100.00
200.00
300.00
400.00
500.00
600.00
700.00
800.00
900.00
1000.00
1250.00
1500.00
1750.00
2000.00
2250.00
2500.00
3000.00
4000.00
5000.00
247.95
200.50
145.35
93.12
67.52
51.94
41.08
33.12
27.62
22.96
19.63
16.75
11.90
8.67
6.81
5.37
4.25
3.55
2.49
1.41
0.89
Concentration (ppm)
Distance to (m)
LOC
IDLH
9.6000
19.6000
1428.31
901.11
-------
From Slab output file: RUN19.0UT
Scenario: TYPICAL
Accident Location: ON-SITE
Duration: UNMITIG
Meteorology: TYPICAL
Chemical: ACETONE
Vapor phase mole fraction: 0.420
LOC: 1960.000
IDLH: 2442.000
*Output adjusted to be distance from fenceline.
X,m Max concentration, ppm
25.00
50.00
100.00
200.00
300.00
400.00
500.00
600.00
700.00
800.00
900.00
1000.00
1250.00
1500.00
1750.00
2000.00
2250.00
2500.00
3000.00
4000.00
9
6
3
1
1
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.72
.66
.83
.71
.01
.66
.47
.36
.28
.22
.19
.15
.11
.08
.06
.05
.04
.03
.03
.02
Concentration (ppm) Distance to (m)
LOC 1960.0000 less than 25.00
IDLH 2442.0000 less than 25.00
-------
From Slab output file: RUN20.OUT
Scenario: TYPICAL
Accident Location: ON-SITE
Duration: MITIGAT
Meteorology: TYPICAL
Chemical: ACETONE
Vapor phase mole fraction: 0.538
LOC: 1960.000
IDLH: 2442.000
*Output adjusted to be distance from fenceline.
X,m Max concentration, ppm
25.00
50.00
100.00
200.00
300.00
400.00
500.00
600.00
700.00
800.00
900.00
1000.00
1250.00
1500.00
1750.00
2000.00
2250.00
2500.00
3000.00
4000.00
5000.00
5.
4.
2.
1.
0.
0.
0.
- o.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
82
02
33
05
63
41
29
22
17
14
12
10
06
05
04
03
02
02
01
01
01
Concentration (ppm) Distance to (m)
LOC 1960.0000 less than 25.00
IDLH 2442.0000 less than 25.00
-------
From Slab output file:
Scenario :
Accident Location:
Duration:
Meteorology:
Chemical :
Vapor phase mole fraction:
LOG:
IDLH:
*0utput adjusted to be distance
X,m 1
678
12 13 14
18 19 20
24 25 26
25.00 1.47
72.41 1.10 2.66
70.11 0.88 2.13
67.17 0.73 1.77
62.02 1.52 4.16
50.00 D.96
55.70 0.72 1.75
52.79 0.57 1.40
49.47 0.48 1.17
45.20 1.00 2.80
100.00 0.52
37.57 0.39 0.97
34.59 0.31 0.77
31.66 0.26 0.64
28.53 0.55 1.58
200.00 0.21
21.07 0.16 0.41
18.52 0.13 0.33
16.34 0.11 0.27
14.37 0.23 0.69
300.00 0.12
14.20 0.09 0.23
12.11 0.07 0.19
10.46 0.06 0.16
9.08 0.13 0.41
400.00 0.08
10.22 0.06 0.15
8.52 0.05 0.12
7.25 0.04 0.10
6.20 0.08 0.26
500.00 0.05
7.81 0.04 0.10
6.41 0.03 0.08
5.37 0.03 0.07
4.56 0.06 0.19
600.00 0.04
6.24 0.03 0.08
5.05 0.02 0.06
4.20 0.02 0.05
3.56 0.04 0.14
700.00 0.03
4.93 0.02 0.06
4.08 0.02 0.05
3.38 0.02 0.04
2.85 0.03 0.11
RUN21.0UT
TYPICAL
ON-SITE
UNMITIG
WORST
ACETONE
0.420
1960.000
2442.000
from fenceline.
2 3
9 10
15 16
21 22
27
3.54 10.50
7.64 16.39
5.97 12.81
4.90 10.45
8.85
2.34 7.07
5.12 11.21
4.01 8.75
3.30 7.14
6.02
1.29 3.99
2.90 6.47
2.27 5.03
1.86 4.10
3.47
0.54 1.73
1.26 2.87
0.99 2.24
0.81 1.83
1.55
0.31 1.01
0.74 1.70
0.58 1.33
0.48 1.09
0.92
0.20 0.65
0.48 1.11
0.37 0.86
0.31 0.71
0.60
0.14 0.46
0.34 0.79
0 26 0.61
0.22 0.51
0.43
0.10 0.35
0.25 0.59
0.20 0.47
0.16 0.38
0.32
0.08 0.27
0.20 0.46
0.16 0.36
0.13 0.30
0.25
4
11
17
23
21.72
32.96
27.05
22.40
14.93
23.15
18.92
15.64
8.65
13.80
11.18
9.23
3.88
6.43
5.18
4.26
2.30
3.90
3.12
2.56
1.50
2.59
2.06
1.69
1.07
1.86
1.48
1.22
0.81
1.42
1.13
0.93
0.63
1.12
0.89
0.73
5
39.38
28.07
17.08
8.23
5.07
3.39
2.46
1.89
1.49
-------
800.00
0.02
0.06
0.21
0.50
1.19
3.73
3.33
2.74
2.30
3.14
2.86
2.34
1.97
2.58
2.40
1.97
1.65
1.79
1.55
1.42
1.19
1.35
1.11
1.06
0.89
1.03
0.87
0.79
0.71
0.82
0.68
0.61
0.56
0.67
0.56
0.48
0.42
0.56
0.46
0.40
0.36
0.41
0.33
0.29
0.25
0.25
0.20
0.18
0.15
33
39
45
51
0.02
0.01
0.01
0.03
900.00
0.01
0.01
0.01
0.02
1000.00
0.01
0.01
0.01
0.02
1250.00
0.01
0.01
0.01
0.01
1500.00
0.01
0.00
0.00
0.01
1750.00
0.00
0.00
0.00
0.01
2000.00
0.00
0.00
0.00
0.01
2250.00
0.00
0.00
0.00
0.00
2500.00
0.00
0.00
0.00
0.00
3000.00
0.00
0.00
0.00
0.00
4000.00
0.00
0.00
0.00
0.00
X,m
34
40
46
52
0.05
0.04
0.03
0.09
0.02
0.04
0.03
0.03
0.07
0.02
0.03
0.03
0.02
0.06
0.01
0.02
0.02
0.01
0.04
O.01
0.02
0.01
0.01
0.03
0.01
0.01
0.01
0.01
0.02
0.01
0.01
0.01
0.01
0.02
0.00
0.01
0.01
0.01
0.02
0.00
0.01
0.01
0.00
0.01
0.00
0.01
0.00
0.00
0.01
0.00
0.00
0.00
0.00
0.01
28
35
41
47
53
0.15
0.12
0.10
0.20
0.05
0.13
0.10
0.09
0.17
0.04
0.11
0.08
0.07
0.14
0.03
0.07
0.06
0.05
0.10
0.02
0.05
0.04
0.04
0.07
0.02
0.04
0.03
0.03
0.06
0.01
0.03
0.03
0.02
0.05
0.01
0.03
0.02
0.02
0.04
0.01
0.02
0.02
0.02
0.03
0.01
0.02
0.01
0.01
0.02
0.00
0.01
0.01
0.01
0.01
29
36
42
48
54
0.37
0.29
0.24
0.18
0.31
0.24
0.20
0.15
0.25
0.20
0.17
0.10
0.18
0.14
0.12
0.07
0.13
0.10
0.08
0.06
0.10
0.08
0.07
0.05
0.08
0.07
0.05
0.03
0.07
0.05
0.04
0.03
0.05
0.05
0.04
0.02
0.04
0.03
0.03
0.01
0.02
0.02
0.02
30
37
43
49
0.89
0.70
0.58
0.42
0.75
0.60
0.49
0.35
0.63
0.49
0.41
0.24
0.44
0.35
0.29
0.18
0.33
0.26
0.21
0.13
0.26
0.20
0.17
0.10
0.20
0.16
0.14
0.08
0.15
0.13
0.11
0.07
0.13
0.11
0.09
0.05
0.09
0.08
0.07
0.03
0.06
0.05
0.04
31
38
44
50
0.84
0.59
0.40
0.31
0.24
0.19
0.16
0.11
0.07
32
-------
25.
16.37
1.06
1.46
15.36
50.
11.41
0.70
0.98
10.44
100.
6.72
0.39
0.55
5.94
200.
3.09
0.16
0.24
2.62
300.
1.86
0.09
0.14
1.54
400.
1.23
0.06
0.09
1.00
500.
0.89
0.04
0.06
0.71
600.
0.68
0.03
0.05
0.53
700.
0.53
0.02
0.04
0.41
800.
0.42
0.02
0.03
0.33
900.
0.36
0.02
0.03
0.27
1000.
0.30
0.01
0.02
0.22
,00
50.74
2.90
3.00
28.44
00
36.78
1.95
2.05
19.99
00
22.79
1.10
1.18
11.91
00
11.20
0.48
0.53
5.55
00
6.99
0.28
0.31
3.37
00
4.73
0.18
0.20
2.23
00
3.47
0.13
0.15
1.60
00
2.69
0.10
0.11
1.22
00
2.14
0.08
0.09
0.96
00
1.72
0.06
0.07
0.75
00
1.47
0.05
0.06
0.62
00
1.23
0.04
0.05
0.49
18. 97
1.18
6.08
2.00
44.98
13.22
0.78
4.14
1.36
33.15
7.79
0.43
2.38
0.78
21.13
3.58
0.18
1.06
0.35
10.82
2.16
0.10
0.63
0.21
6.88
1.43
0.07
0.41
0. 14
4.73
1.03
0.05
0.29
0. 10
3.49
0.78
0.03
0.22
0.07
2.71
0.62
0.03
0.18
0.06
2.11
0.49
0.02
0.14
0.05
1.58
0.42
0.02
0.12
0.04
1.32
0.34
0.01
0.10
0.03
1.06
56.22
3.22
12.89
1.50
78.06
40.93
2.17
8.95
1.02
60.91
25.52
1.22
5.28
0.59
41.41
12.66
0.53
2.43
0.26
24.25
7.94
0.31
1.47
0.16
16.73
5.40
0.20
0.97
0.10
10.97
3.96
0.14
0.70
0.07
8.06
3.08
0.11
0.53
0.06
6.31
2.45
0.08
0.42
0.04
5.09
1.97
0.07
0.34
0.03
4.16
1.68
0.06
0.28
0.03
3.57
1.41
0.05
0.24
0.02
3.0?
1.33
6.77
1.83
2.20
0.88
4.63
1.23
1.43
0.48
2.66
0.69
0.77
0.20
1.19
0.30
0.32
0.12
0.70
0.18
0.18
0.07
0.46
0.11
0.11
0.05
0.33
0.08
0.08
0.04
0.25
0.06
0.06
0.03
0.20
0.05
0.05
0.02
0.15
0.04
0.04
0.02
0.13
0.03
0.03
0.02
0.11
0.03
0.02
3.62
14.40
3.75
5.39
2.44
10.03
2.56
3.55
1.38
5.90
1.47
1.96
0.60
2.72
0.66
0.83
0.35
1.64
0.39
0.48
0.23
1.09
0.26
0.30
0.16
0.78
0.18
0.21
0.12
0.60
0.14
0.16
0.10
0.47
0.11
0.12
0.08
0.37
0.09
0.10
0.06
0.32
0.07
0.08
0.05
0.26
, 0.06
0.07
7.66
5.24
3.01
1.34
0.80
0.52
0.37
0.28
0.22
0.17
0.15
0.12
-------
1250.00
0.24
1.01
0.01
0.04
0.21
0.01
0.01
0.14
0.16
0.01
0.01
0.10
0.12
0.01
0.01
0.08
0.10
0.00
0.01
0.06
0.08
0.00
0.01
0.05
0.07
0.00
0.00
0.04
0.05
0.00
0.00
0.03
0.03
0.00
0.00
0.02
0.88
0.03
0.03
0.32
1500.00
0.66
0.02
0.02
0.23
1750.00
0.53
0.02
0.02
0.18
2000.00
0.43
0.01
0.02
0.14
2250.00
0.35
0.01
0.01
0.11
2500.00
0.30
0.01
0.01
0.09
3000.00
0.22
0.01
0.01
0.07
4000.00
0.12
0.00
0.01
0.04
0.01
0.07
0.02
0.72
0.18
0.01
0.05
0.02
0.54
0.14
0.01
0.04
0.01
0.41
0.12
0.00
0.03
0.01
0.32
- 0.09
0.00
0.03
0.01
0.26
0.08
0.00
0.02
0.01
0.21
0.06
0.00
0.02
0.01
0.16
0.03
0.00
0.01
0.00
0.09
0.03
0.17
0.02
2.15
0.76
0.02
0.12
0.01
1.62
0.60
0.02
0.10
0.01
1.25
0.49
0.01
0.08
0.01
1.01
0.40
0.01
0.06
0.01
0.82
0.33
0.01
0.06
0.01
0.68
0.23
0.01
0.04
0.00
0.49
0.14
0.00
0.03
0.00
0.29
0.08
0.02
0.02
0.01
0.06
0.01
0.01
0.01
0.04
0.01
0.01
0.01
0.04
0.01
0.01
0.00
0.03
0.01
0.01
0.00
0.02
0.01
0.00
0.00
0.02
0.00
0.00
0.00
0.01
O.OG
0.00
0.19
0.04
0.05
0.03
0.14
0.03
0.03
0.02
"0.11
0.02
0.02
0.02
0.09
0.02
0.02
0.01
0.07
0.02
0.01
0.01
0.06
0.01
0.01
0.01
0.05
0.01
0.01
0.01
0.03
0.01
0.01
0.0!
0.06
0.05
0.04
0.03
0.03
0.02
0.01
X,m Max concentration, ppm
25.
50.
100.
200.
300.
400.
500.
600.
700.
800.
900.
1000.
1250.
1500.
1750.
2000.
2250.
2500.
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
On
00
00
78
60
41
24
16
10
8
6
5
4
3
3
2
1
1
1
0
0
.06
.91
.41
.25
.73
.97
.06
.31
.09
.16
.57
.03
.15
.62
.25
.01
.82
.68
-------
3000.00 0.49
4000.00 0.29
Concentration (ppm) Distance to (m)
LOG 1960.0000 less than 25.00
IDLH 2442.0000 less than 25.00
-------
From Slab output file:
Scenario:
Accident Location:
Duration:
Meteorology:
Chemical :
Vapor phase mole fraction:
LOG:
IDLH:
*0utput adjusted to be distance
X,m 1
678
12 13 14
18 19 20
24 25 26
25.00 0.89
35.34 0.66 1.60
34.61 0.53 1.28
34.10 0.44 1.07
32.51 0.92 2.52
50.00 0.58
27.32 0.43 1.06
26.37 0.35 0.85
25.58 0.29 0.71
24.11 0.61 1.71
100.00 0.32
18.00 0.24 0.59
17.70 0.19 0.47
16.73 0.16 0.39
15.51 0.34 0.97
200.00 0.13
9.44 0.10 0.25
9.15 0.08 0.20
8.89 0.07 0.17
8.03 0.14 0.43
300.00 0.07
6.11 0.06 0.14
5.77 0.04 0.12
5.64 0.04 0.10
5.18 0.08 0.25
400.00 0.05
4.40 0.04 0.09
4.01 0 . 03 0. 07
3.72 0.02 0.06
3.43 0.05 0.16
500.00 0.03
3.38 0.02 0.06
2.96 0.02 0.05
2.71 0.02 0.04
2.44 0.04 0.12
600.00 0.02
2.71 0.02 0.05
2.28 0.01 0.04
2.06 0.01 0.03
1.85 0.03 0.09
700.00 0.02
2.16 0.01 0.04
1.87 0.01 0.03
1.61 0.01 0.02
1.42 0.02 0.07
RUN22.0UT
TYPICAL
ON-SITE
MITIGAT
WORST
ACETONE
0.538
1960.000
2442.000
from fenceline.
2 3
9 10
15 16
21 22
27
2.13 6.14
4.56 9.52
3.59 7.59
2.96 6.23
5.30
1.41 4.17
3.10 6.59
2.44 5.24
2.00 4.30
3.65
0.79 2.38
1.76 3.84
1.38 3.04
1.14 2.50
2.12
0.33 1.05
0.78 1.73
0.61 1.37
0.50 1.13
0.95
0.19 0.62
0.45 1.03
0.36 0.82
0.30 0.67
0.57
0.12 0.40
0.29 0.68
0.23 0.53
0.19 0.44
0.37
0.09 0.28
0.21 0.48
0.16 0.38
0.14 0.31
0.27
0.06 0.20
0.16 0.36
0.12 0.29
0.10 0.24
0.20
0.05 0.16
0.12 0.27
0.10 0.22
0.08 0.19
0.16
4
11
17
23
12.09
18.03
15.37
12.99
8.42
12.87
10.89
9.18
4.97
7.81
6.54
5.49
2.28
3.74
3.08
2.57
1.37
2.30
1.88
1.56
0.87
1.48
1.25
1.03
0.61
1.04
0.90
0.75
0.45
0.78
0.67
0.57
0.34
0.59
'0.51
0.45
5
20.51
14.84
9.25
4 .59
2.68
1.76
1.26
0.95
0.74
-------
800.00
0.01
0.04
0.12
0.28
1.84
1.50
1.34
1.18
1.52
1.30
1.11
0.95
1.34
1.10
0.95
0.83
0.95
0.79
0.66
0.58
0.72
0.59
0.49
0.42
0.57
0.45
0.39
0.33
0.44
0.37
0.30
0.26
0.37
0.30
0.26
0.22
0.31
0.26
0.21
0.18
0.23
0.18
0.16
0.14
0.14
0.11
0.10
0.08
33
39
45
51
0.01
0.01
0.01
0.02
900.00
0.01
0.01
0.01
0.01
1000.00
0.01
0.01
0.01
0.01
1250.00
0.00
0.00
0.00
0.01
1500.00
0.00
0.00
0.00
0.01
1750.00
0.00
0.00
0.00
0.00
2000.00
0.00
0.00
0.00
0.00
2250.00
0.00
0.00
0.00
0.00
2500.00
0.00
0.00
0.00
0.00
3000.00
0.00
0.00
0.00
0.00
4000.00
0.00
0.00
0.00
0.00
X,m
34
40
46
52
0.03
0.02
0.02
0.05
0.01
0.02
0.02
0.02
0.05
0.01
0.02
0.02
0.01
0.04
0.01
0.01
0.01
0.01
0.03
-o.oo
0.01
0.01
0.01
0.02
0.00
0.01
0.01
0.01
0.01
0.00
0.01
0.00
0.00
0.01
0.00
0.00
0.00
0.00
0.01
0.00
0.00
0.00
0.00
0.01
0.00
0.00
0.00
0.00
0.01
0.00
0.00
0.00
0.00
0.00
28
35
41
47
53
0.09
0.08
'0.06
0.13
0.03
0.08
0.06
0.05
0.11
0.03
0.06
0.05
0.04
0.09
0.02
0.04
0.03
0.03
0.06
0.01
0.03
0.03
0.02
0.04
0.01
0.02
0.02
0.02
0.03
0.01
0.02
0.02
0.01
0.03
0.01
0.02
0.01
0.01
0.02
0.01
0.01
0.01
0.01
0.02
0.00
0.01
0.01
0.01
0.01
0.00
0.01
0.00
0.00
0.01
29
36
42
48
54
0.21
0.17
0.15
0.10
0.18
0.14
0.12
0.08
0.15
0.12
0.10
0.06
0.10
0.08
0.07
0.04
0.07
0.06
0.05
0.03
0.06
0.05
0.04
0.02
0.04
0.04
0.03
0.02
0.04
0.03
0.02
0.02
0.03
0.02
0.02
0.01
0.02
0.02
0.01
0.01
0.01
0.01
0.01
30
37
43
49
0.48
0.40
0.34
0.23
0.39
0.33
0.29
0.19
0.33
0.27
0.23
0.13
0.23
0.19
0.16
0.09
0.17
0.14
0.12
0.07
0.13
0.11
0.09
0.06
0.10
0.08
0.07
0.05
0.08
0.07
0.06
0.04
0.07
0.06
0.05
0.03
0.05
0.04
0.04
0.02
0.03
0.03
0.02
31
38
44
50
0.60
0.49
0.42
0.29
0.21
0.17
0.13
0.11
0.09
0.07
0.04
32
-------
9.71
0.64
0.89
8.42
6.81
0.43
0.60
5.82
4.06
0.24
0.34
3.39
1.89
0.10
0.15
1.53
1.15
0.06
0.09
0.87
0.76
0.04
0.06
0.55
0.55
0.03
0.04
0.39
0.42
0.02
0.03
0.29
0.33
0.01
0.02
0.22
0.26
0.01
0.02
0.18
0.22
0.01
0.02
0.14
0.19
0.01
0.01
0.12
25.00
28.02
1.75
1.80
14.76
50.00
20.56
1.19
1.24
10.55
100.00
13.00
0.67
0.72
6.45
200.00
6.53
0.30
0.32
2.98
300.00
4.12
0.17
0.19
1.75
400.00
2.83
0.11
0.13
1.16
500.00
2.09
0.08
0.09
0.82
600.00
1.62
0.06
0.07
0.61
700.00
1.28
0.05
0.05
0.48
800.00
0.99
0.04
0.04
0.39
900.00
0.83
0.03
0.04
0.32
1000.00
0.68
0.03
0.03
0.27
11.13
0.71
3.65
1.20
22.67
7.85
0.47
2.51
0.83
16.90
4.68
0.26
1.46
0.48
10.69
2.18
0.11
0.66
0.22
5.18
F.32
0.06
0.39
0.13
3.16
0.88
0.04
0.26
0.08
2.19
0.63
0.03
0.18
0.06
1.60
0.48
0.02
0. 14
0.05
1.26
0.38
0.02
0.11
0.04
0.99
0.30
0.01
0.09
0.03
0.82
0.25
0.01
0.07
0.02
0.68
0.21
0.01
0.06
0.02
0.58
30.42
1.95
7.66
0.90
13.65
22.42
1.32
5.39
0.62
10.91
14.23
0.75
3.20
0.36
7.99
7.23
0.33
1.49
0.16
5.36
4.61
0.19
0.90
0.10
4.08
3.18
0.13
0.60
0.06
3.28
2.35
0.09
0.43
0.05
2.71
1.78
0.07
0.33
0.03
2.30
1.37
0.05
0.26
0.03
1.99
1.08
0.04
0.21
O.C2
1.71
0.90
0.04
0.18
0.02
1.52
0.75
0.03
0.15
0.02
1.33
0.80
4.07
1.10
1.33
0.53
2.80
0.74
0.87
0.29
1.62
0.42
0.47
0.13
0.73
0.19
0.20
0.07
0.44
0.11
0.11
0.05
0.29
0.07
0.07
0.03
0.20
0.05
0.05
0.02
0.16
0.04
0.03
0.02
0.12
0.03
0.03
0.01
0.10
0.02
0.02
0.01
0.08
0.02
0.02
0.01
0.07
0.02
0.01
2.20
8.56
1.26
3.20
1.49
6.03
1.55
2.13
0.85
3.58
0.90
1.18
0.37
1.67
0.41
0.50
0.22
1.01
0.24
0.29
0.14
0.67
0.16
0.18
0.10
0.48
0.11
0.12
0.08
0.37
0.09
0.09
0.06
0.29
0.07
0.07
0.05
0.23
0..05
0.06
0.04
0.20
0.05
0.04
0.03
0.16
*' 0.04
0.04
4.60
3.17
1.84
0.83
0.49
0.32
0.23
0.18
0.14
0.11
0.09
0.08
-------
1250.00
0.14
0.52
0.01
0.02
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
12
01
01
08
09
00
01
06
07
00
01
05
06
00
00
04
05
00
00
03
04
00
00
02
03
00
00
02
02
00
00
01
0.
0.
0.
0.
1500.00
0.
0.
0.
0.
1750.00
0.
0.
0.
0.
2000.00
0.
0.
0.
0.
2250.00
0.
0.
0.
0.
2500.00
0.
0.
0.
0.
3000.00
0.
0.
0.
0.
4000.00
0.
0.
0.
0.
47
02
02
18
35
01
02
13
27
01
01
10
21
01
01
08
17
01
01
07
15
01
01
05
11
00
01
04
07
00
00
02
0
0
0
0
0.10
0
0
0
0
0.08
0
0
0
0
0.06
0
0
0
0
'0.05
0
0
0
0
0.04
0
0
0
0
0.03
0
0
0
0
0.02
0
0
0
0
.01
.04
.01
.41
.00
.03
.01
.30
.00
.02
.01
.23
.00
.02
.01
.18
.00
.02
.01
.15
.00
.01
.00
.12
.00
.01
.00
.09
.00
.01
.00
.05
0
0
0
1
0.39
0
0
0
0
0.29
0
0
0
0
0.24
0
0
0
0
0.19
0
0
0
0
0.16
0
0
0
0
0.12
0
0
0
0
0.08
0
0
0
0
.02
.10
.01
.00
.01
.08
.01
.77
.01
.06
.01
.61
.01
.05
.00
.50
.01
.04
.00
.41
.01
.03
.00
.35
.00
.02
.00
.25
.00
.01
.00
.15
0.
0.
0.
0.01
0.
0.
0.
0.00
0.
0.
0.
0.00
0.
0.
0.
0.00
0.
0.
0.
0.00
0.
0.
0.
0.00
0.
0.
0.
0.00
0.
0.
0.
05
01
01
03
01
01
03
01
01
02
01
00
02
00
00
01
00
00
01
00
00
01
00
00
0.
0.
0.
0.02
0.
0.
0.
0.01
0.
0.
0.
0.01
0.
0.
0.
0.01
0.
0.
0.
0.01
0.
0.
0.
0.01
0.
0.
0.
0.00
0.
0.
0.
12
03
03
08
02
02
06
02
01
05
01
01
04
01
01
03
01
01
03
01
01
02
00
00
0.05
0.04
C.03
0.02
0.02
0.02
0.01
0.01
X,m Max concentration, ppm
25.00
50.00
100.00
200.00
300.00
400.00
500.00
600.00
700.00
800.00
900.00
1000.00
1250.00
1500.00
1750.00
2000.00
2250.00
2500.00
35.34
27.32
18.00
9.44
6.11
4 .40
3.38
2.71
2.16
1.84
1.52
1.34
1.00
0.77
0.61
0.50
0.41
0.35
-------
3000.00
4000.00
0.25
0.15
Concentration (ppm)
LOG
IDLH
1960.0000
2442.0000
Distance to (m)
less than
less than
25.00
25.00
-------
From Slab output file: RUN23a.OUT
Scenario: TYPICAL
Accident Location: ON-SITE
.Duration: UNMITIG
Meteorology: INVERSN
Chemical: ACETONE
Vapor phase mole fraction: 0.445
LOC: 1960.000
IDLH: 2442.000
*Output adjusted to be distance from fenceline.
X,m Max concentration, ppm
25.00
50.00
100.00
200.00
300.00
400.00
500.00
600.00
700.00
800.00
900.00
1000.00
1250.00
1500.00
1750.00
2000.00
2250.00
2500.00
3000.00
4000.00
5000.00
69.75
55.63
39.73
24.99
18.04
14.00
11.39
9.49
7.98
6.92
6.01
5.30
3.96
3.08
2.44
2.00
1.66
1.40
1.03
0.61
0.41
Concentration (ppm) Distance to (m)
LOC 1960.0000 less than 25.00
IDLH 2442.0000 less than 25.00
-------
From Slab output file:
Scenario:
Accident Location:
Duration:
Meteorology:
Chemical:
Vapor phase mole fraction:
LOC:
IDLH:
RUN23b.OUT
TYPICAL
ON-SITE
UNMITIG
INVERSN
ACETONE
0.101
1960.000
2442.000
*0utput adjusted to be distance from fenceline.
X,m Max concentration, ppm
25.00
50.00
100.00
200.00
300.00
400.00
500.00
600.00
700.00
800.00
900.00
1000.00
1250.00
1500.00
1750.00
2000.00
2250.00
2500.00
3000.00
4000.00
5000.00
6.44
5.46
4.28
3.02
2.32
1.90
1.59
1.35
1.16
1.03
0.92
0.82
0.64
0.53
0.44
0.38
0.32
0.28
0.21
0.13
0.09
Concentration (ppm)
LOC
IDLH
1960.0000
2442.0000
Distance to (m)
less than
less than
25.00
25.00
-------
From Slab output file: RUN24.0UT
Scenario: TYPICAL
Accident Location: ON-SITE
Duration: ' MITIGAT
Meteorology: INVERSN
Chemical: ACETONE
Vapor phase mole fraction: 0.572
LOG: 1960.000
IDLH: 2442.000
*0utput adjusted to be distance from fenceline.
X,m Max concentration, ppm
25.00
50.00
100.00
200.00
300.00
400.00
500.00
600.00
700.00
800.00
900.00
1000.00
1250.00
1500.00
1750.00
2000.00
2250.00
2500.00
3000.00
4000.00
5000.00
24 .55
19.78
14.36
9.28
6.87
5.37
4.33
- 3.55
3.00
2.55
2.20
1.91
1.39
1.04
0.82
0.66
0.52
0.44
0.32
0.18
0.12
Concentration (ppm) Distance to (m)
LOG 1960.0000 less than 25.00
IDLH 2442.0000 less than 25.00
-------
From Slab output file:
Scenario:
Accident Location:
Duration:
Meteorology:
Chemical:
Vapor phase mole fraction:
LOG:
IDLH:
RUN49.0UT
CONSERV
ON-SITE
UNMITIG
TYPICAL
HCL
1.000
9.900
49.100
*0utput adjusted to be distance from fenceline.
" X,m Max concentration, ppm"
25.00
50.00
100.00
200.00
300.00
400.00
500.00
600.00
700.00
800.00
900.00
1000.00
1250.00
1500.00
1750.00
2000.00
2250.00
2500.00
3000.00
4000.00
5000.00
10000.00
15000.00
20000.00
1010.97
655.38
375.56
222.62
153.10
106.62
77.62
-- 59.15
46.24
36.82
30.95
25.51
17.60
12.96
10.11
8.05
6.47
5.52
4.02
2.39
1.61
0.50
0.25
0.16
Concentration (ppm)
LOC
IDLH
9.9000
49.1000
Distance to (m)
1775.30
677.85
-------
From Slab output file: RUN50.OUT
Scenario: CONSERV
Accident Location: ON-SITE
Duration: MITIGAT
Meteorology: TYPICAL
Chemical: HCL
Vapor phase mole fraction: 1.000
LOC: 9.900
IDLH: 49.100
*0utput adjusted to be distance from fenceline.
" X,m Max concentration, ppm"
25.00
50.00
100.00
200.00
300.00
400.00
500.00
600.00
700.00
800.00
900.00
1000.00
1250.00
1500.00
1750.00
2000.00
2250.00
2500.00
3000.00
4000.00
5000.00
10000.00
15000.00
20000.00
569.66
371.51
212.82
125.60
86.42
60.21
43.98
' 33.52
26.20
20.87
17.57
14.52
10.01
7.12
5.47
4.29
3.45
2.89
2.07
1.27
0.87
0.27
0.14
0.09
Concentration (ppnj) Distance to (m)
LOC 9.9000 1259.72
IDLH 49.1000 less than 25.00
-------
From Slab output file: RUN51.0UT
Scenario: CONSERV
Accident Location: ON-SITE
Duration: UNMITIG
Meteorology: WORST
Chemical: HCL
Vapor phase mole fraction: 1.000
LOG: 9.900
IDLH: 49.100
*0utput adjusted to be distance from fenceline.
X,m 1 2
6789
12 13 14 15
18 19 20 21
24 25 26 27
25.00 211.86 424.
8087.54 160.13 275.56
6279.70 133.14 224.16
78.93 113.59 196.26
0.00 175.51 133.60
50.00 14-.49 351.
5029.25 112.70 235.56
6763.27 92.18 188.93
4889.99 77.77 159.57
77.85 139.67 179.50
213.
146.82
115.88
96.00
180.96
93.58
66. 10
51.86
43.53
106.12
52.32
37.41
29.11
23.84
64.20
32.61
23.44
18.37
15.33
100.00
2774.64
3306.22
4110.25
3564.67
200.00
1422.03
1487.99
1681.69
1889.01
300.00
950.41
946.98
990.89
1051.39
400.00
708.22
678.83
688.97
707.83
500.00
561.12
526.62
519.15
520.24
600.00
459.07
428.58
414.02
406.11
700.00
379.64
359.38
340.55
328.39
79.
60.75
48.59
41.23
84.30
33.
25.63
20.75
17.33
37.55
18.
13.88
10.96
9.29
20.53
11.
8.73
7.05
5.93
13.23
7.
6.02
4.85
4.08
9.19
5.
4.45
3.53
2.96
6.73
4.
3.46
2.77
2.30
5.25
62
78
35
54
96
90
59
3
10
16
22
27
91 2069.98 3969
487.33 1052.67
214.24 142.89
153.22 67.49
51.41
70 1499.70 2569
595.85 1406.00
304.18 391.73
219.72 197.00
133.36
55 767
479.75
293.89
217.66
217.24
296
233.80
165.02
127.82
188.45
166.02
132.85 294.82
98.65 230.16
77.68 170.33
132.40
105.06 203.
84.43 188.48
152.36
117.57
4 5
11
17
23
77 5654.50
2724.16
96.19
1.94
52 3413.61
3633.70
910.76
62.36
54
1146
531
310
31
529
370
252
1266.
.94
.14
.40
527.
.50
.75
.64
58
2145.
1515.
533.
85
895.
891.
583.
1728
70
31
42
809
39
63
34
.28
.76
42.22
16.40
12.83
10.64
29.92
12.31
9.58
7.83
22.52
9.54
7.47
6.17
17.72
63.97
50.49
93.00
306.72 496.06
504.97
505.59
406.39
43 350.67
341.83
332.65
283.54
22.67
16.99
13.15
58.67
45.13
35.84
68.30
43.51
33.74
27.07
52.49
33.36
26.02
21.07
41.35
73.32 146.
131.47
107.75
85.07
94 263.84
248.46
235.97
205.62
54.82
42.39
112.
97.69
80.23
64.47
87.
75.02
61.61 ,.
50.13
11 207
189.28
175.55
154.78
93 166
150.02
138.05
120.70
.52
.60
-------
800.00 3.61
320.12 2.72
303.33 2.19
283.95 1.83
270.46 4.20
900.00 2.97
271.24 2.21
256.51 1.78
246.74 1.46
233.30 3.38
1000.00 2.46
238.70 1.84
221.09 1.49
214.38 1.24
199.89 2.87
1250.00 1.66
176.96 1.26
162.21 1.01
159.23 0.84
147.58 1.95
1500.00 '1.20
137.03 0.91
123.43 0.73
119.04 0.61
113.91 1.42
1750.00 0.90
110.72 0.69
98.71 0.55
92.75 0.46
86.81 1.08
2000.00 0.72
92.00 0.55
81.63 0.44
76.26 0.37
70.81 0.87
2250.00 0.57
75.88 0.44
67.18 0.36
62.45 0.30
57.86 0.71
2500.00 0.48
65.70 0.37
58.12 0.30
53.44 0.25
48.81 0.59
3000.00 0.35
49.06 0.26
43.26 0.22
39.91 0.18
36.31 0.44
4000.00 0.20
31.16 0.16
27.42 0.13
24.65 0.11
21.98 0.26
5000.00 0.14
21.22 0.11
18.97 0.09
16.98 0.07
15.05 0.18
7.46
5.88
4.89
14.04
6.16
4.84
3.98
11.61
5.08
4.02
3.33
9.66
3.49
2.76
2.28
6.62
2.53
1.99
1.66
4.81
1.95
1.52
1.25
3.71
1.55
1.23
1.02
2.99
1.22
0.99
0.83
2.41
1.03
0.83
0.70
2.05
0.75
0.60
0.51
1.51
0.45
0.36
0.30
0.90
0.30
0.24
0.21
0.61
10.26
26.14
20.30
16.54
32.79
8.48
21.65
17.08
13.81
27.57
6.99
. 17.56
13.98
11.40
22.72
4.77
12.05
9.49
7.85
15.78
3.3"
8.74
6.88
5.67
11.54
2.56
6.75
5.38
4.40
9.08
2.03
5.29
4.29
3.54
7.28
1.60
4.20
3.43
2.84
5.84
1.35
3.53
2.90
2.42
5.00
0.97
2.53
2.08
1.76
3.65
0.59
1.53
1.24
1.04
2.17
0.40
1.03
0.84
0.70
1.47
33.17
60.21
49.34
40.00
28.01
49.71
40.83
33.27
23.00
41.22
33.86
27.23
15.34
27.89
22.86
18.78
10.94
20.91
16.81
13.78
8.46
16.05
13.10
10.83
6.65
12.45
10.33
8.62
5.37
9.98
8.26
6.94
4.48
8.31
6.91
5.85
3.20
5.96
4.95
4.19
1.95
3.62
2.98
2.52
1.32
2.44
2.01
1.70
71.07
124.26
112.63
98.65
59.99
102.70
91.65
80.33
50.24
88.49
78.56
68.29
33.58
61.51
54.58
46.99
24.83
44.85
40 54
34.80
19.18
34.21
31.11
26.95
14.98
26.71
23.96
21.28
12.32
22.35
19.80
17.38
10.21
18.16
16.18
14.31
7.30
13.54
11.52
10.27
4.49
8.17
7.13
6.25
3.02
5.54
4.83
4.23
140.51
118.39
IOC. 51
70.02
52.47
40.65
32.02
26.90
22.14
16.55
9.83
6.70
-------
10000
5.93
5.53
5.10
4.55
15000
2.65
2.56
2.44
2.24
33
39
45
51
25
0.06
137.71
92.23
1825.46
50
5.57
103.52
96.74
1153.39
100
87.02
60.24
73.24
608.51
200
208.35
25.98
37.52
287.20
300
193.31
14.68
22.14
172.10
400
157.53
9.24
14 .46
117.01
500
125.15
6.45
10.28
85.60
600
100.29
4.78
7.66
66.09
700
80.89
3.64
5.81
52.44
.00 0
0.03
. 0.03
0.02
0.06
.00 0
0.02
0.01
0.01
0.03
X,m
34
40
46
52
.00 0
0.00
112.50
36.88
2856.08
.00 -9
0.00
141.45
61.38
1826.44
.00 185
70.67
130.04
78.32
1051.41
.00 317
1419.08
72.78
59.89
519.04
.00 274
1063.05
43.91
41.13
326.88
.00 209
719.95
29.18
29.14
226.75
.00 160
516.66
20.71
21.57
169.92
.00 124
393.46
15.41
16.45
132.13
.00 98
310.84
11.84
13.10
105.63
.04 0.
0.09
0.08
0.07
0.19
.02 0.
0.05
0.04
0.03
0.10
28
35
41
47
53
.19 0.
146.70
37.08
34.01
3801.56
.45 0.
113.42
80.70
51.05
2573.77
.57 1393.
66.75
128.86
59.31
1547.47
.92 1893.
28.89
113.97
42.21
807.94
.10 1113.
16.24
81.29
28.23
539.34
.95 734.
10.33
58.88
19.77
390.98
.67 528.
7.21
43.80
14.41
293.63
.98 404.
5.30
33.43
11.00
232.27
.44 322.
4.00
26.90
8.86
188.04
12 0.
0.30
0.26
0.22
0.46
06 0.
0.16
0.13
0.11
0.23
29
36
42
48
54
00 159.
115.86
0.13
30.41
5314.38
03 125.
147.67
2.77
43.25
3891.35
75 74.
141.92
41.62
47.27
2532.95
05 32.
81.20
119.55
32.54
1477.99
48 18.
48.71
117.04
21.67
1034.23
35 11.
32.46
100.58
15.07
774.63
11 8.
22.99
83.57
11.01
604.16
80 5.
17.02
69.25
8.32
488.84
17 4.
13.30
57.61
6.61
401.77
.39
0.73
0.60
0.52
19
0.37
0.31
0.27
30
37
43
49
42
39.11
100.85
349.00
72
88.73
113.65
241.29
80
146.41
88.27
127.00
73
129.24
46.53
53.44
19
92.17
27.26
28.32
66
66.24
18.06
18.06
10
49.23
12.71
12.42
93
37.92
9.33
9.00
54
30.52
7.45
7.04
0.90
1.68
1.46
1.27
0.43
0.82
0.73
0.65
31
38
44
50
123.07
0.13
37.27
1105.73
158.30
3.76
66.35
694.13
158.58
55.20
89.20
339.34
92.18
150.74
72.80
139.34
54.76
145.75
50.29
74.70
36.63
123.45
35.92
48.21
25.96
101.02
26.41
33.56
19.19
82.46
20.58
24.55
15.27
67.67
16.45
19.37
1.97
0.94
32
43.50
104.96
169.22
151.26
108.22
76.83
56.85
44.09
35.11
-------
700.00
45.85 166.73
2.08 6.76
3.33 7.48
25.73 50.57
800.00
38.29 134.92
1.67 5.54
2.74 6.14
20.82 42.59
900.00
32.16 114.21
1.37 4.47
2.20 5.03
17.47 35.34
1000.00
27.39 96.20
1.15 3.81
1.89 4.31
14.76 30.81
1250.00
19.29 66.68
0.78 2.61
1.30 3.00
10.34 21.98
1500.00
14.44 48.86
0.57 1.91
0.95 2.20
7.72 16.37
175C.OO
11.14 37.83
0.44 1.46
0.72 1.71
5.90 12.84
2000.00
8.68 30.60
0.34 1.17
0.59 1.39
4.79 10.43
2250.00
7.07 24.59
0.29 0.96
0.47 1.12
3.89 8.49
2500.00
5.88 21.07
0.23 0.78
0.40 0.96
3.28 7.22
3000.00
4.24 15.58
0.17 0.57
0.30 0.71
2.41 5.23
4000.00
2.60 9.70
0.10 0.34
0.18 0.45
1.46 3.22
55.42
2.29
15.39
5.07
92.05
46.06
1.86
12.55
4.03
78.78
38.08
1.51
10.31
3.42
66.34
32.48
1.27
8.80
2.80
58.44
-22.62
0.86
6.13
1.97
42.80
16.54
0.63
4.54
1.48
32.45
12.55
0.48
3.47
1.15
26.44
9.69
0.38
2.82
0.91
21.33
8.01
0.32
2.30
0.76
17.93
6.58
0.26
1.92
0.63
14.86
4.71
0.19
1.39
0.48
10.98
2.92
0.11
0.82
0.29
6.60
170.98
7.61
32.82
3.79
212.16
139.25
6.17
27.44
3.08
180.98
117.75
4.97
23.68
2.51
158.55
97.71
4.26
20.13
2.15
138.35
68.00
2.92
14.47
1.50
103.53
50.13
2.14
10.99
1.10
83.24
39.86
1.62
8.74
0.86
67.18
32.37
1.29
7.01
0.69
55.06
26.55
1.04
5.60
0.56
46.35
22.68
0.86
4 .75
0.48
39.36
16.75
0.63
3.44
0.35
29.50
10.58
0.37
2.10
0.22
18.11
2.60
17.39
4.27
3.80
2.11
14.08
3.40
2.96
1.68
11.73
2.81
2.41
1.44
9.90
2.34
1.97
0.98
6.86
1.60
1.30
0.71
5.05
1.15
0.93
0.54
3.87
0.91
0.72
0.43
3.11
0.73
0.56
0.35
2.49
0.59
0.45
0.29
2.10
0.50
0.37
0.21
1.52
0.37
0.26
0.12
0.91
0.23 ,.
0.16
8.69
38.48
9.42
10.07
6.95
32.15
7.54
7.80
5.64
27.37
6.40
6.46
4.80
23.27
5.30
5.23
3.31
16.40
3.70
3.52
2.40
12.43
2.76
2.59
1.82
9.68
2.17
1.99
1.47
7.64
1.72
1.53
1.17
6.20
1.44
1.27
0.98
5.20
1.20
1.03
0.71
3.75
0.88
0.76
0.42
2.31
0.55
0.45
20. Cl
16.01
13.44
11.26
7.83
5.71
4.34
3.47
2.74
2.33
1.68
1.02
-------
10000
3.13
2.91
2.60
2.43
15000
1.39
1.34
1.25
1.16
20000
0.79
0.77
0.72
0.70
.00 0.
0.02
0.01
0.01
0.03
.00 0.
0.01
0.01
0.01
0.02
.00 0.
0.01
0.01
0.00
0.01
X,m
33
39
45
51
25.
0.03
76.64
51.53
922.02
50.
3.16
57.84
54.32
585.44
100.
49.50
33.95
41.42
310.32
200.
118.18
14.78
21.33
148.33
300.
109.65
8.33
12.58
87.31
400.
89.17
5.27
8.23
57.55
500.
71.02
3.68
5.86
41.88
600.
56.86
2.74
4.38
32.54
34
40
46
52
.00 -0.
0.00
62.90
20.92
1435.20
,00 5.
0.00
79.50
34.80
922.18
00 105.
40.05
73.20
44.54
531.67
00 178.
767.08
41.32
34.21
263.28
00 154.
565.99
24.98
23.53
158.96
00 117.
382.34
16.62
16.70
109.30
00 90.
274.82
11.83
12.36
81.59
00 70.
209.97
8.80
2.42
63.78
.02
0.05
0.04
0.04
0.10
01
0.03
0.02
0.02
0.06
01
0.02
0.01
0.01
0.04
28
35
41
47
53
11
81.90
21.01
19.27
1905.78
35
63.35
45.71
28.94
1295.98
22
37.63
73.22
33.73
780.35
75
16.37
64.81
24 .04
407.12
22
9.22
46.34
16.16
262.09
95
5.90
33.61
11.34
186.00
39
4.11
25.05
8.27
141.95
30
3.03
19.13
6.30
112.93
0.07
0.17
0.14
0.12
0.25
0.03
0.09
0.07
0.06
0.13
0.02
0.05
0.05
0.04
0.08
29
36
42
48
54
0.00
64.86
0.08
17.23
2662.19
0.01
82.84
1.57
24.58
1950.68
775.35
79.96
23.75
26.90
1266.48
992.64
46.06
68.43
18.55
757.34
582.63
27.6°
66.72
12.40
520.49
384.54
18.45
57.36
8.62
389.23
277.28
13.12
47.58
6.30
306.74
213.59
9.72
39.43
4.76
249.22
0.21
0.40
0.34
0.29
0.10
0.20
0.17
0.15
0.06
0.12
0.11
0.09
30
37
43
49
88.97
22.13
56.24
193.53
70.38
50.32
63.60
134.17
42.18
83.06
49.98
70.95
18.58
73.39
26.43
29.98
10.33
52.47
15.54
15.93
6.64
37.77
10.26
10.19
4.62
28.07
7.27
6.85
3.38
21.60
5.34
4.86
0.47
0.90
0.77
0.70
0.23
0.44
0.39
0.35
0.14
0.26
0.24
0.22
31
38
44
50
68.82
0.07
21.14
590.72
88.87
2.13
37.64
371.11
89.36
31.41
50.67
182.43
52.20
85.98
41.53
75.85
31.07
82.99
28.74
41.02
20.85
70.05
20.54
25.79
14.78
57.30
15.09
17.59
10.90
46.86
.- 11.76
12.93
0.49
0.29
32
24.68
59.25
96.26
86.13
61.55
43.70
32.33
25.13
-------
5000.00
1.99
7.31
0.08
0.29
1.78
0.07
0.13
0.98
10000.
0.56
0 .02
0.04
0.28
15000.
0.29
0 .01
0.02
0.13
20000.
0. 18
0.01
0.01
0.08
VJ W
6.69
0.23
0.31
2.14
00
2.08
0.08
0.10
0.60
00
1.03
0.04
0.05
0.27
00
0.63
0.03
0.03
0.16
0.08
. 0.56
0.21
4.44
0.62
0.03
0.18
0.07
1.21
0.32
0.01
0.10
0.04
0.55
0.20
0.01
0.06
0.02
0.30
0.25
1.44
0.16
12.14
2.25
0.08
0.46
0.05
3.21
1.11
0.04
0.24
0.03
1.38
0.67
0.03
0.15
0.02
0.79
0.62
0.16
0.11
0.03
0.20
0.05
0.03
0.01
0.11
0.03
0.02
0.01
0.07
0.02
0.01
1.58
0.38
0.30
0.09
0.51
0.12
0.09
0.05
0.26
0.06
0.04
0.03
0.16
0.04
0.03
X,m Max concentration, ppm
25.00
50.00
100.00
200.00
300.00
400.00
500.00
600.00
700.00
800.00
900.00
1000.00
1250.00
1500.00
1750.00
2000.00
2250.00
2500.00
3000.00
4000.00
5000.00
10000.00
15000.00
20000.00
4070
3429
2101
992
582
389
306
249
212
180
158
138
103
83
67
55
46
39
29
18
12
3
1
0
.16
.95
.31
.64
.63
.23
.74
.22
.16
.98
.55
.35
.53
.24
.18
.06
.35
.36
.50
.11
.14
.21
.39
.79
C.7C
0.22
0.07
Concentration (ppm)
LOG
IDLH
9.9000
49.1000
Distance to (m)
6254.60
2171.13
-------
From Slab output file:
Scenario:
Accident Location:
Duration:
Meteorology:
Chemical:
Vapor phase mole fraction:
LOC:
IDLH:
RUNS3.OUT
CCNSERV
ON-SITE
UNMITIG
INVERSN
HCL
1
9
000
900
49.100
^Output adjusted to be distance from fenceline.
X,m Max concentration, ppm
25.00
50.00
100.00
200.00
300.00
400.00
500.00
600.00
700.00
800.00
900.00
1000.00
1250.00
1500.00
1750.00
2000.00
2250.OC
2500.00
3000.00
4000.00
5000.00
10000.00
15000.00
20000.00
6922.40
5380.31
3699.98
2196.71
1539.06
1166.96
917.96
- 759.06
641.81
549.87
477.37
423.41
321.14
250.66
206.91
170.55
146.00
122.98
95.13
60.26
42.33
12.83
6.18
3.60
Concentration (ppm)
LOC
IDLH
9.9000
49.1000
Distance to (m)
12204.31
4622.65
-------
From Slab output file:
Scenario:
Accident Location:
Duration:
Meteorology:
Chemical:
Vapor phase mole fraction:
LOG:
IDLH:
RUNS4.OUT
CONSERV
ON-SITE
MITIGAT
INVERSN
hCL
1.000
9.900
49.100
*0utput adjusted to be distance from fenceline.
X,m Max concentration, ppm
25.00
50.00
100.00
200.00
300.00
400.00
500.00
600.00
700.00
800.00
900.00
1000.00
1250.00
1500.00
1750.00
2000.00
2250.00
2500.00
3000.00
4000.00
5000.00
10000.00
15000.00
20000.00
3914.84
3051.54
2133.12
1277.65
915.36
698.19
553.50
-- 465.95
389.78
339.32
290.62
261.54
197.50
153.22
126.38
102.52
88.40
74.27
57.16
35.67
24.63
7.06
3.31
1.91
Concentration (ppm)
Distance to
LOG
IDLH
9.9000
49.1000
9191.12
3375.25
-------
From Slab output file: RUN55.0UT
Scenario: TYPICAL
Accident Location: ON-SITE
Duration: UNMITIG
Meteorology: TYPICAL
Chemical: HCL
Vapor phase mole fraction: 1.000
LOG: 9.900
IDLH: 49.100
*0utput adjusted to be distance from fenceline.
X,m Max concentration, ppm
25.00
50.00
100.00
200.00
300.00
400.00
500.00
600.00
700.00
800.00
900.00
1000.00
1250.00
1500.00
1750.00
2000.00
2250.00
2500.00
3000.00
4000.00
5000.00
27.
19.
11.
5.
3.
2.
1.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
52
71
40
39
13
10
51
13
88
72
60
50
34
25
19
15
12
10
07
05
03
Concentration (ppm) Distance to (m)
LOC 9.9000 125.02
IDLH 49.1000 less than 25.00
-------
From Slab output file: RUN56.OUT
Scenario: TYPICAL
Accident Location: ON-SITE
Duration: MITIGAT
Meteorology: TYPICAL
Chemical: HCL
Vapor phase mole fraction: 1.000
LOC: 9.900
IDLH: 49.100
*0utput adjusted to be distance from fenceline.
X,m Max concentration, ppm
25.00
50.00
100.00
200.00
300.00
400.00
500.00
600.00
700.00
800.00
900.00
1000.00
1250.00
1500.00
1750.00
2000.00
2250.00
2500.00
3000.00
4000.00
5000.00
27.52
19.71
11.40
5.39
3.13
2.10
1.51
1.13
0.88
0.72
0.60
0.50
0.34
0.25
0.19
0.15
0.12
0.10
0.07
0.05
0.03
Concentration (ppm) Distance to (m)
LOC 9.9000 125.02
IDLH 49.1000 less than 25.00
-------
From Slab output file:
Scenario:
Accident Location:
Duration:
Meteorology:
Chemical :
Vapor phase mole fraction:
LOG:
IDLH:
RUN57.0UT
TYPICAL
ON- SITE
UNMITIG
WORST
HCL
1.000
9.900
49.100
*0utput adjusted to be distance from fenceline.
6
12
18
24
25
235.68
223.63
201.39
177.10
50
183.07
171.20
153.60
135.00
100
121.80
110.80
97.94
85.35
200
60.68
58.96
52.10
44 . 91
300
38.36
33.96
32.56
27.91
400
26.76
22.99
21.25
19.17
500
20.08
16.78
15.05
13.41
600
15.53
13.08
11.13
9.91
700
12.49
10.30
8.99
7.79
X,m
7
13
19
25
.00
3.27
2.62
2.18
4.45
.00
2.22
1.78
1.48
3.07
.00
1.19
0.95
0.79
1.69
.00
0.52
0.42
0.35
0.75
.00
0.29
0.23
0.19
0.42
.00
0.19
0.15
0.12
0.27
.00
0.13
0.10
0.09
0.19
.00
0.10
0.08
0.06
0.14
.00
0.07
0.06
0.05
0.11
1
8
14
20
26
4.36
7.77
6.22
5.18
12.19
'2.96
5.38
4.30
3.58
8.56
1.59
2.95
2.35
1.96
4.83
0.69
1.31
1.05
0.88
2.23
0.38
0.73
0.59
0.49
1.27
0.25
0.48
0.38
0.32
0.85
0.17
0.34
0.27
0.23
0.60
0.13
0.25
0.20
0.17
0.45
0.09
0.19
0.15
0.13
0.35
2
9
15
21
27
10.38
21.64
17.17
14.23
25.18
7.16
15.24
12.06
10.03
17.97
3.92
8.60
6.82
5.64
10.40
1.75
3.98
3.15
2.61
4.92
0.98
2.28
1.80
1.49
2.85
0.64
1.51
1.19
0.99
1.91
0.45
1.08
0.85
0.71
1.37
0.32
0.8C
0.64
0.53
1.03
0.24
0.60
0.49
0.41
0.80
3
10
16
22
29.27
45.07
35.64
29.44
20.65
32.37
25.51
21.07
11.71
18.77
14.74
12.21
5.41
8.88
6.99
5.77
3.09
5.16
4.06
3.35
2.03
3.45
2.71
2.24
1.40
2.45
1.95
1.61
1.02
1.79
1.47
1.21
0.78
1.36
1.14
0.94
4
11
17
23
60.80
92.36
73.93
61.26
43.78
67.87
54.20
44.81
25.43
40.65
32.28
26.63
12.07
20.05
15.85
13.08
7.01
11.89
9.42
7.75
4.48
7.98
6.39
5.26
3.11
5.54
4.64
3.81
2.27
4.05
3.49
2.90
1.78
3.14
,. 2.63
2.26
5
117.61
86.89
52.44
26.18
14 .84
9.72
6.81
5.07
4.03
-------
10.32
8.44
7.18
6.27
8.63
7.01
6.04
5.12
7.30
6.01
4.99
4.34
5.09
4 .24
3.43
3.01
3.88
3.13
2.64
2.22
3.02
2.42
2.04
1.76
2.37
1.96
1.61
1.38
1.97
1.59
1.34
1.16
1.63
1.34
1.12
0.95
1.19
0.96
0.84
0.71
0.71
0.59
0.51
0.43
33
39
45
51
800.00
0.06
0.05
0.04
0.09
900.00
0.05
0.04
0.03
0.07
1000.00
0.04
0.03
0.03
0.06
1250.00
0.03
0.02
0.02
0.04
1500.00
0.02
0.02
0.01
0.03
1750.00
0.01
0.01
0.01
0.02
2000.00
0.01
0.01
0.01
0.02
2250.00
0.01
0.01
0.01
0.02
2500.00
0.01
0.01
0.01
0.01
3000.00
0.01
0.00
0.00
0.01
4000.00
0.00
0.00
0.00
0.01
X,m
34
40
46
52
0.08
0.15
0.12
0.10
0.29
0.06
0.12
0.10
0.09
0.23
0.05
0.10
0.08
0.07
0.20
0.03
0.07
0.06
0.05
0.14
,0.02
0.05
0.04
0.04
0.10
0.02
0.04
0.03
0.03
0.08
0.01
0.03
0.02
0.02
0.06
0.01
0.02
0.02
0.02
0.05
0.01
0.02
0.02
0.01
0.04
0.01
0.01
0.01
0.01
0.03
0.00
0.01
0.01
0.01
0.02
28
35
41
47
53
0.20
0.49
0.40
0.33
0.66
0.16
0.39
0.33
0.27
0.54
0.13
0.33
0.28
0.23
0.46
0.09
0.22
0.18
0.16
0.31
0.07
0.16
0.13
0.11
0.23
0.05
0.12
0.10
0.09
0.17
0.04
0.10
0.08
0.07
0.14
0.03
0.08
n . 07
0.06
0.11
0.03
0.07
0.05
0.05
0.09
0.02
0.05
0.04
0.03
0.07
0.01
0.03
0.02
0.02
0.04
29
36
42
48
54
0.63
1.10
0.92
0.77
0.50
0.88
0.74
0.63
0.43
0.75
0.62
0.53
0.29
0.51
0.42
0.35
0.21
0.37
0.31
0.26
0.16
0.28
0.23
0.20
0.13
0.23
0.18
0.16
0.10
0.18
0.15
0.13
0.09
0.15
0.12
0.11
0.06
0.11
0.09
0.08
0.04
0.07
0.06
0.05
30
37
43
49
1.42
2.53
2.14
1.83
1.15
2.04
1.71
1.47
0.97
1.74
1.45
1.23
0.66
1.19
0.98
0.84
0.48
0.86
0.72
0.61
0.37
0.67
0.55
0.47
0.30
0.54
0.44
0.37
0.24
0.43
0.36
0.31
0.20
0.37
0.30
0.25
0.15
0.27
0.22
0.19
0.09
0.17
0.14
0.11
31
38
,- 44
50
2.68
2. 19
1.49
1.13
0.87
0.67
0.57
0.46
0.34
0.20
32
-------
45.54
3.11
4.26
44.40
33.28
2.15
2.99
31.47
19.77
1.18
1.69
17.87
9.63
0.53
0.78
8.30
5.72
0.29
0.44
4.56
3.89
0.19
0.30
2.93
2.82
0.13
0.21
2.04
2.14
0.10
0.16
1.48
1.67
0.08
0.12
1.17
1.38
0.06
0.10
0.93
1.14
0.05
0.08
0.76
25
50
100
200
300
400
500
600
700
f
800
900
1000
0.97
0.04
0.07
0.63
.00
136.66
8.47
8.77
86.17
.00
103.87
5.97
6.27
62.28
.00
65.20
3.36
3.60
36.62
.00
33.98
1.56
1.70
16.77
.00
20.97
0.89
0.99
9.38
.00
14.60
0.59
0.66
6.08
.00
10.80
0.42
0.48
4.30
.00
8.23
0.32
0.36
3.28
.00
6.21
0.24
0.28
2.54
.00
5.08
0.20
0.23
2.01
.00
4.09
0.16
0.19
1.68
.00
3.50
0.14
0.16
1.40
52.24
17
5
3.46
.47
.86
142.85
38.13
12
4
2.39
.55
.18
106.75
22.70
7
2
1.31
.22
.40
66.62
11.07
0
3
1
31
-6.58
0
1
0
18
4.46
0
1
0
12
3.24
0
0
0
9
2.46
0
0
0
6
1.92
.58
.42
.14
.20
.33
.99
.66
.64
.21
.33
.44
.50
.15
.96
.32
.12
.11
.72
.24
.94
0.08
0.56
0
.19
5.33
1.59
0.07
0.46
0.15
4
1.31
.45
0.06
0.38
0.13
3.57
1.09
0.05
0.32
0.11
154.85
36
4
9.43
.31
.39
3.89
19.49
5.32
6.54
10.58
21.93
40.37
10.
,97
15.47
206.49
117.55
26
3
6.64
.42
.13
2.69
13.91
3.
4.
73
45
7.48
15.74
29.43
7 .
10.
84
69
155.77
74.27
15
1
3.75
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1.47
E
2.
2.
1.03
10
39
4.21
9.05
17.45
4.
5.
51
87
107.65
38.84
1
7
0
63
24.00
0
4
0
42
16.72
0
3
0
31
12.20
0
2
0
24
8.92
0
1
.73
.66
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.55
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.55
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.58
.35
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0.18
0.66
3.
0.
1.
0.37
2.
0.
0.
0.24
1.
0.
0.
0.17
1.
0.
0.
0.13
0.
0.
0.
80
97
04
21
56
57
48
37
36
06
26
24
80
20
18
1.95
8.
2.
2.
1.12
5.
1.
1.
0.74
3.
0.
0.
0.53
2.
0.
0.
0.39
1.
0.
0.
54
13
63
06
24
47
44
83
93
50
60
64
90
45
47
4.29
2.49
1.66
1.20
0.90
19.60
6.86
0.27
1
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0.14
0.10
0.
0.
0.
62
15
13
0.30
1.
0.
0.
48
35
36
0.70
15.75
5.59
0.22
1
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0.11
0.08
0.
0.
0.
51
12
11
0.25
1.
0.
0.
22
29
29
0.58
13.30
4 .48
0
0
0
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3.87
0
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0.08
0.06
0.
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0.
0.05
0.
0.
0.
42
10
08
35
09
07
0.20
1.
0.
0.
0.17
0.
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0.
01
24
23
86
20
20
0.47
0.40
3.11 9.5<,
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1250.00
0.73
2.67
0.04
0.12
0.
0.
0.
0.
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0.
0.
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0.
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0.
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0.
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66
03
05
43
48
02
04
31
37
02
03
24
29
01
02
19
24
01
02
15
20
01
02
13
14
01
01
09
09
00
01
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0
0
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1500.00
1
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1
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0
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0
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0
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.05
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.04
.04
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.76
.03
.04
.29
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.02
.03
.21
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.01
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0
0
0
2
0.54
0
0
0
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0.41
0
0
0
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0.32
0
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0
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0
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0
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0
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0
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1.51
0
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0
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0.84
0
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0.61
0
0
0
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0.39
0
0
0
0
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.04
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.02
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.03
.16
.02
.02
.02
.12
.01
.47
.01
.07
.01
.84
0.
0.
0.
0.03
0.
0.
0.
0.02
0.
0.
0.
0.02
0.
0.
0.
0.01
0.
0.
0.
0.01
0.
0.
0.
0.01
0.
0.
0.
0.00
0.
0.
0.
25
06
05
18
04
03
14
03
03
11
03
02
09
02
02
08
02
01
06
01
01
03
01
01
0.
0.
0.
0.09
0.
0.
0.
0.07
0.
0.
0.
0.05
0.
0.
0.
0.04
0.
0.
0.
0.04
0.
0.
0.
0.03
0.
0.
0.
0.02
0.
0.
0.
60
14
13
44
10
10
34
08
07
26
06
06
22
05
05
18
05
04
13
03
03
08
02
02
:.20
o.i;
o.io
0.08
0.06
0.04
X,m
Max concentration, ppm
25.
50.
100.
200.
300.
400.
500.
600.
700.
800.
900.
1000.
1250.
1500.
1750.
2000.
225C .
2500.
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
235
183
121
63
42
31
24
19
15
13
11
9
6
4
3
2
2
2
.68
.07
.80
.55
.95
.57
.58
.60
.75
.30
.04
.54
.67
.93
.85
.96
.49
.02
-------
3000.00 1.47
4000.00 0.84
Concentration (ppm) Distance to (m)
LOG 9.9000 976.22
IDLH 49.1000 270.14
-------
From Slab output file:
Scenario:
Accident Location:
Duration:
Meteorology:
Chemical :
RUN58.0UT
TYPICAL
ON-SITE
MIT I GAT
WORST
HCL
Vapor phase mole fraction:
*0utput adjusted to
6
12
18
24
25
235.68
223.63
201.39
177.10
50
183.07
171.20
153.60
135.00
100
121.80
110.80
97.94
85.35
200
60.68
58.96
52.10
44 . 91
300
38.36
33. 96
32.56
27.91
400
26.76
22.99
21.25
19.17
500
20.08
16.78
15.05
13.41
600
15.53
13.08
11.13
9.91
700
12.49
10.30
8.99
7.79
X,m
7
13
19
25
.00
3.27
2.62
2.18
4 .45
.00
2.22
1.78
1.48
3.07
.00
1.19
0.95
0.79
1.69
.00
0.52
0.42
0.35
0.75
.00
0.29
0.23
0.19
0.42
.00
0.19
0.15
0.12
0.27
.00
0.13
0.10
0.09
0.19
.00
0.10
0.08
0.06
0.14
.00
0.07
0.06
0.05
0.11
LOG:
IDLH:
be distance
1
8
14
20
26
4.36
7.77
6.22
5.18
12.19
-2.96
5.38
4.30
3.58
8.56
1.59
2.95
2.35
1.96
4.83
0.69
1.31
1.05
0.88
2.23
0.38
0.73
0.59
0.49
1.27
0.25
0.48
0.38
0.32
0.85
0.17
0.34
0.27
0.23
0.60
0.13
0.25
0.20
0.17
0.45
0.09
0.19
0.15
0.13
0 35
1.000
9.900
49.100
from fenceline.
2
9
15
21
21
10.38
21.64
17.17
14.23
25.18
7.16
15.24
12.06
10.03
17.97
3.92
8.60
6.82
5.64
10. *0
1.75
3.98
3.15
2.61
4.92
0.98
2.28
1.80
1.49
2.85
0.64
1.51
1.19
0.99
1.91
0.45
1.08
0.85
0.71
1.37
0.32
0.80
0.64
0.53
1.03
0.24
0.60
0.49
0.41
O.£0
3
10
16
22
29.27
45.07
35.64
29.44
20.65
32.37
25.51
21.07
11.71
18.77
14.74
12.21
5.41
8.88
6.99
5.77
3.09
5.16
4.06
3.35
2.03
3.45
2.71
2.24
1.40
2.45
1.95
1.61
1.02
1.79
1.47
1.21
0.78
1.36
1. 14
0.94
4
T_T_
17
23
60.80
92.36
73.93
61.26
43.78
67.87
54.20
44.81
25.43
40.65
32.28
26.63
12.07
20.05
15.85
13.08
7.01
11.89
9.42
7.75
4.48
7.98
6.39
5.26
3.11
5.54
4 .64
3.81
2.27
4.05
3.49
2.90
1.78
3.14
2.63
2.26
5
117.61
86.89
52.44
26.18
14.84
9.72
6.81
5.07
4.03
-------
800.00
0.08
0.20
0.63
1.42
10.32
8 .44
7.18
6.27
900
8.63
7.01
6.04
5.12
1000
7.30
6.01
4 .99
4.34
1250.
5.09
4 .24
3.43
3.01
1500.
3.88
3.13
2.64
2.22
1750.
3.02
2.42
2.04
1.76
2000.
2.37
1.96
1. 61
1.38
2250.
1 . 97
1.59
1.34
1. 16
2500.
1.63
1.34
1.12
0.95
3000.
1.19
0.96
0.84
0.71
4000.
0.71
0.59
0.51
0.43
X
33
39
45
51
0.06
0.05
0.04
0.09
.00
0.05
0.04
0.03
0.07
.00
0.04
0.03
0.03
0.06
.00
0.03
0.02
0.02
0.04
00
0.02
0.02
0.01
0.03
00
0.01
0.01
0.01
0.02
00
0.01
0.01
0.01
0.02
00
0.01
0.01
0.01
0.02
00
0.01
0.01
0.01
0.01
00
0.01
0.00
0.00
0.01
00
0.00
0.00
0.00
0.01
,m
34
40
46
52
0.15
0.12
0.10
0.29
0.06
0.12
0.10
0.09
0.23
0.05
0.10
0.08
0.07
0.20
0.03
0.07
0.06
0.05
0.14
.-0.02
0.05
0.04
0.04
0.10
0.02
0.04
0.03
0.03
0.08
0.01
0.03
0.02
0.02
0.06
0.01
0.02
0.02
0.02
0.05
0.01
0.02
0.02
0.01
0.04
0.01
0.01
0.01
0.01
0.03
0.00
0.01
0.01
0.01
0.02
28 .
35
41
47
53
0.49
0.40
0.33
0.66
0.16
0.39
0.33
0.27
0.54
0.13
0.33
0.28
0.23
0.46
0.09
0.22
0.18
0.16
0.31
0.07
0.16
0.13
0.11
0.23
0.05
0.12
0.10
0.09
0.17
0.04
0.10
0.08
0.07
0.14
0.03
0.08
0.07
0.06
0.11
0.03
0.07
0.05
0.05
0.09
0.02
0.05
0.04
0.03
0.07
0.01
0.03
0.02
0.02
0.04
29
36
42
48
54
1.10
0.92
0.77
0.50
0.88
0.74
0.63
0.43
0.75
0.62
0.53
0.29
0.51
0.42
0.35
0.21
0.37
0.31
0.26
0.16
0.28
0.23
0.20
0.13
0.23
0.18
0.16
0.10
0.18
0.15
0.13
0.09
0.15
0.12
0.11
0.06
0.11
0.09
0.08
0.04
0.07
0.06
0.05
30
37
43
49
2.53
2.14
1.83
1.15
2.04
1.71
1.47
0.97
1.74
1.45
1.23
0.66
1.19
0.98
0.84
0.48
0.86
0.72
0.61
0.37
0.67
0.55
0.47
0.30
0.54
0.44
0.37
0.24
0.43
0.36
0.31
0.20
0.37
0.30
0.25
0.15
0.27
0.22
0.19
0.09
0.17
0.14
0.11
31
38
44
50
.68
1 9
1.49
1.13
0.87
0.67
0.57
0.46
0.34
0.20
32
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1250.00
0.73
0.04
0.12
0.66
0.03
0.05
0.43
0.48
0.02
0.04
0.31
0.37
0.02
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0.01
0.01
0.09
0.09
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0.01
0.06
2.40
0.09
0.11
0.96
1500.00
1.76
0.07
0.08
0.70
1750.00
1.34
0.06
0.06
0.53
2000.00
1.10
0.04
0.05
0.42
2250.00
0.88
0.04
0.04
0.34
2500.00
0.76
0.03
0.04
0.29
3000.00
0.56
0.02
0.03
0.21
4000. 00
0.35
0.01
0.02
0.12
0.03
0.22
0.07
2.14
0.54
0.02
0.17
0.06
1.54
0.41
0.02
0.13
0.04
1.20
0.32
0.01
0.10
0.03
0.95
.O.27
0.01
0.08
0.03
0.77
0.22
0.01
0.07
0.02
0.64
0.16
0.01
0.05
0.02
0.45
0.10
0.00
0.03
0.01
0.27
0.11
0.54
0.06
6.67
1.94
0.08
0.40
0.04
4.93
1.51
0.06
0.30
0.03
3.85
1.22
0.05
0.24 '
0.03
2.96
1.00
0.04
0.20
0.02
2.49
0.84
0.03
0.16
0.02
2.02
0.61
0.02
0.12
0.01
1.47
0.39
0.01
0.07
0.01
0.84
0.25
0.06
0.05
0.03
0.18
0.04
0.03
0.02
0.14
0.03
0.03
0.02
0.11
0.03
0.02
0.01
0.09
0.02
0.02
0.01
0.08
0.02
0.01
0.01
0.06
0.01
0.01
0.00
0.03
0.01
0.01
0.60
0.14
0.13
0.09
0.44
0.10
0.10
0.07
0.34
0.08
0.07
0.05
0.26
0.06
0.06
0.04
0.22
0.05
0.05
0.04
0.18
0.05
0.04
0.03
0.13
0.03
0.03
0.02
0.08
0.02
0.02
C.28
0.20
0.16
0.12
0.10
0.08
0.06
0.04
X,m Max concentration, ppm
25.
50.
100.
200.
300.
400.
500.
600.
700.
800.
900.
1000.
1250.
1500.
1750.
2000.
2250.
2500.
.00
00
.00
00
00
00
00
00
.00
00
00
00
00
,00
00
00
.00
.00
235
183
121
63
42
31
24
19
15
13
11
9
6
4
3
2
2
2
.68
.07
.80
.55
.95
.57
.58
.60
.75
.30
.04
.54
.67
.93
.85
.96
.49
.02
-------
3000.OC 1.47
4000.00 0.84
Concentration (ppm) Distance to (m)
LOG 9.9000 976.22
IDLH 49.1000 270.14
-------
From Slab output file: RUN59.0UT
Scenario: TYPICAL
Accident Location: ON-SITE
Duration: ' UNMITIG
Meteorology: INVERSN
Chemical: HCL
Vapor phase mole fraction: 1.000
LOC: 9.900
IDLH: 49.100
*0utput adjusted to be distance from fenceline.
X,m Max concentration, ppm
25
50
100
200
300
400
500
600
700
800
900
1000
1250
1500
1750
2000
2250
2500
3000
4000
5000
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
295
237
170
110
81
63
51
41
35
29
25
22
16
12
9
7
5
5
3
2
1
.17
.54
.19
.30
.48
.57
.14
.76
.16
.88
.56
.23
.08
.01
.36
.52
.97
.04
.60
.06
.30
Concentration (ppm) Distance to (m)
LOC 9.9000 1699.08
IDLH 49.1000 521."?
-------
From Slab output file: RUN60.0UT
Scenario: TYPICAL
Accident Location: ON-SITE
Duration: MITIGAT
Meteorology: INVERSN
Chemical: HCL
Vapor phase mole fraction: 1.000
LOG: 9-900
IDLH: 49.100
"Output adjusted to be distance from fenceline.
X,m Max concentration, ppm
25
50
100
200
300
400
500
600
700
800
900
1000
1250
1500
1750
2000
2250
2500
3000
4000
5000
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
295.
237.
170.
110.
81.
63.
51.
- 41.
35.
29.
25.
22.
16.
12.
9.
7 .
5.
5.
3.
2.
1 .
17
54
19
30
48
57
14
76
16
88
56
23
08
01
36
52
97
04
60
06
30
Concentration (ppm) Distance to (m)
LOC 9.9000 1699.08
IDLH 49.1000 521.79
-------
From Slab output file:
Scenario:
Accident Location:
Duration:
Meteorology:
Chemical:
Vapor phase mole fraction:
LOG:
IDLH:
RUN61.0UT
CONSERV
OFFSITE
UNMITIG
TYPICAL
FORMALDEHYDE
0.484
9.600
19.600
X,m Max concentration, ppm
25
50
100
200
300
400
500
600
700
800
900
1000
1250
1500
1750
2000
2250
2500
3000
4000
5000
10000
15000
20000
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
2252.
1352.
660.
259.
137.
87.
60.
44 .
-- 34.
27.
22.
18.
12.
9.
7.
5.
4 .
3.
2.
1.
1.
0.
0.
0.
21
68
84
13
95
72
74
88
65
39
55
84
90
50
28
73
78
97
92
80
18
36
19
12
Concentration (ppm)
LOC
IDLH
9.6000
19.6000
Distance to (m)
1492.39
979.60
-------
From Slab output file:
Scenario :
Accident Location:
Vapor phase
X,m
6
12
18
24
25.00
20795.87
14745.87
11535.33
9534.80
50.00
12574.32
9790.35
7850.48
6526.26
100.00
6080. 10
5362.37
4525.58
3824.54
200.00
2635.45
2475.31
2166.38
1855.93
300.00
1578.03
1474.97
1296.46
1117.00
400.00
1101.97
1016. 98
889.40
766.66
500.00
825.67
749.56
653.67
559.53
600.00
649.97
583.26
504.40
429.95
700.00
511.21
469.60
402.83
343.11
800.00
392.23
Duration :
Meteorology:
Chemical :
mole fraction:
LOG:
IDLH:
1
7 8
13 14
19 20
25 26
709.87 1337
530.79 1000.27
423.66 796.99
352.67 666.31
567.89 1182.57
313.46 666
234.53 496.55
187.46 397.62
155.93 331.00
283.45 665.96
113.17 267
84.67 198.93
67.71 158.56
56.17 131.81
112.91 301.53
35.62 90
26.73 66.67
21.39 53.11
17.82 44.21
37.83 110.82
17.42 44 ,
13.10 33.15
10.45 26.38
8.73 21.92
18.76 57.07
10.59 27.
7.92 20.35
6.34 16.16
5.29 13.45
11.50 35.82
7.06 18.
5.30 13.72
4.24 10.90
3.54 9.06
7.74 24 . 49
5.07 13.
3.82 9.94
3.05 7.88
2.54 6.55
5.63 17.91
3.84 10.
2.88 7.57
2.31 6.00
1.92 4.98
4.29 13.73
2.98 7.
2.24 5.90
RUN62.0UT
CONSERV
OFFSITE
UNMITIG
WORST
FORMALDEHYDE
0.
9.
19.
2 3
484
600
600
9 10
15
21
27
.45 2820.11
2087.65
1661.73
1381.01
2058.61
.18 1592.17
1176.70
935.86
777.50
1233.04
.16 726.30
535.41
423.57
352.50
599.81
.29 271.94
198.50
156.76
129.91
236.16
.91 141.62
103.07
81.07
67.09
125.47
56 89.23
64.57
5C 78
41.96
80.07
58 61.10
16
22
5082
3676.79
2904.00
2408.71
3046
2209.17
1743.76
1446.39
1491
1079.44
851.72
702.51
596
430.91
336.77
277.25
322
230.82
179.89
147.91
206
147.81
114.80
94 .13
143
44.28 102.44
34.77
28.70
55.38
46 44.73
32.37
25.43
20.99
40.84
24 34.33
24.83
19.50
16.09
31.51
99 26.96
19.52
79.48
65.14
105
75.77
58.68
48.10
81,
58.57
45.35
37.13 ,.
64.
46.23
4
11
17
23
.00 9002
6453.33
5082.00
4215.64
.30 5639
4099.29
3236.41
2675.75
.72 2907
2155.28
1702.79
1405.84
.84 1233
926.65
729.32
598.36
.19 692.
518.54
407.00
333.09
.18 453.
341.37
266.32
217.37
.00 321.
241.40
187.87
153.03
.69 241.
180.99
140.74
114.48
.74 189.
141.32
109.90
89.35
.60 151.
112.66
5
.40
.57
.66
. 92
.69
26
63
42
01
39
-------
384.31
328.36
279.19
900.00
326.09
325.45
276.68
234.68
1000.00
271.55
279.00
236.12
199.85
1250.00
190.21
192.23
168.43
141.81
1500.00
139.39
134.31
123.26
107.11
1750.00
111.47
100.05
89.31
84 .05
2000.00
89.02
79.98
68.93
67.46
2250.00
73.53
65.05
56.49
54.38
2500.00
61. 14
54.16
46.04
42.76
3000.00
44 .24
39.68
33.91
29.97
4000.00
26.93
23.76
19.94
18.22
5000.00
17.85
16.02
13.52
12.27
10000.00
4.77 0
4.51 0
1.79
1.49
3.34
1.82
1.46
1.21
2.73
1.50
1.20
1.00
2.26
1.00
0.80
0.67
1.52
0.73
0.58
0.48
1.11
0.55
0.44
0.37
0.84
0.43
0.34
0.29
0.66
0.35
0.28
0.24
0.55
0.29
0.23
0. 19
0.45
0.21
0.17
0.14
0.33
0.12
0.10
0.09
0.21
0.08
0.07
0.06
0.14
.02
.02
4.69
3.90
10.78
2.42
4.82
3.83
3.18
8.84
2.00
3.99
3.18
2.64
7.36
1.34
2.69
2.14
1.78
5.00
0.97
1.96
1.56
1.30
3.66
0.73
1.49
1.19
0.99
2.80
0.57
1.16
0.93
0.77
2.20
0.46
0.97
0.77
0.64
1.83
0.37
0.80
0.63
0.53
1.51
0.26
0.58
0.46
0.39
1.11
0.15
0.34
0.28
0.24
0.70
0.10
0.23
0.19
0.16
0.47
0.03
0.07
0.06
15.33
12.64
24.88
6.52
15.99
12.55
10.37
20.49
5.41
13.30
10.45
8.64
17.13
3.64
9.03
7.11
5.86
11.71
2.65
6.60
5.20
4.28
8.61
2.01
5.03
3.97
3.28
6.62
1.57
3.95
3.11
2.57
5.23
1.28
3.29
2.59
2.14
4.36
1.02
2.70
2.14
1.77
3.61
0.72
1.87
1.56
1.30
2.66
0.43
1.12
0.92
0.79
1.69
0.29
0.75
0.61
0.52
1.12
0.09
0.22
0.19
35.86
29.35
22.12
38.04
29.53
24.18
18.41
31.77
24.66
20.20
12.46
21.71
16.87
13.82
9.10
15.94
12.42
10.16
6.87
12.23
9.53
7.79
5.10
9.64
7.49
6.16
4.18
7.78
6.24
5. 14
3.36
6.17
5.17
4.25
2.36
4.34
3.79
3.13
1.44
2.63
2.20
1.92
0.97
1.77
1.47
1.26
0.29
0.53
0.44
87.56
71.23
52.94 125
93.24
72.62
58.99
44.16 105
78.40
61.07
49.57
30.25 70.
54.38
42.25
34.34
21.71 49.
40.26
31.30
25.48
15.74 36.
30.60
24.17
19.68
11.97 28.
22.84
19.13
15.60
9.77 22.
18.55
16.02
13.06
7.79 18.
14.80
13.22
10.87
5.63 13.
10.60
9.02
8.02
3.39 7.
6.38
5.37
4.64
2.28 5.
4.32
3.62
3.08
f"
0.68 1.
1.29
1.09
.70
. 7 8
.99
16
20
32
97
80
70
94
31
53
-------
3.95
3.63
15000
2.22
2.08
1.91
1.73
20000
1.25
1.19
1.09
1.04
33
39
45
51
25
3142.77
397.85
411.24
4517.33
50
1998.73
198.25
231.95
2545.84
100
1047.86
78.80
105.00
1154.16
200
443.14
26.44
36.60
432.25
300
244.90
13.10
19.88
225.15
400
159.27
8.04
12.45
141.73
500
112.17
5.43
8.49
96.94
600
83.78
3.92
6.22
71.03
700
65.33
2.99
0.02
0.04
.00 0
0.01
0.01
0.01
0.02
.00 0
0.01
0.01
0.01
0.01
X,m
34
40
46
52
.00 3600
7114.80
826.03
711.48--
8582.93
.00 2287
4889.56
467.00
428.26
5055.67
.00 1200
2884.88
210.48
208.33
2373.13
.00 509
1401.66
77.33
81.69
913.93
.00 281
839.31
39.87
43.31
488.19
.00 183
570.15
24.95
27.52
312.10
.00 129
416.04
17.06
19.02
217.07
.00 96
319.49
12.47
14.02
160.60
.00 75
254.26
9.57
0.05
0.14
.02 0.
0.04
0.03
0.03
0.07
.01 0.
0.02
0.02
0.02
0.05
28
35
41
47
53
.96 8147.
442.21
1432.64
474.32
15407.33
.96 5589.
220.39
859.78
284.59
8793.31
.44 3294.
87.76
418.60
138.90
3964.85
.44 1600.
29.39
164.02
54.51
1572.03
.81 958.
14.60
87.02
28.84
881.83
.88 658.
8.93
55.26
18.33
587.96
.28 480.
6.03
38.26
12.67
422.02
.43 368.
4.36
28.21
9.35
321.89
.23 293.
3.32
21.77
0.16
C.34
04 0.
0.11
0.10
0.08
0.17
03 0.
0.07
0.06
0.05
0.11
29
36
42
48
54
33 496.
919.60
2507.12
354.45
30604.93
23 247.
518.23
1593.13
213.00
13987.60
62 98.
234.03
836.14
103.92
5998.06
52 33.
86.07
352.41
40.76
2607.79
79 16.
44.37
194.07
21.64
1605. 17
43 10.
27.76
126.05
13.75
1107.62
52 6.
18.98
88.72
9.50
766.18
35 4.
13.87
66.22
6.99
585.28
49 3.
10.63
51.53
0.38
14 C
0.27
0.22
0.20
09 0
0.16
0.14
0.13
30
37
43
49
91 1034
1593.97
514.65
1066.41
89 583
956.77
290.30
474.55
81 263
465.45
131.45
172.39
11 96
182.62
48.31
54.25
41 49
96.98
24.88
26.17
07 31
61.60
15.56
15.82
80 21
42.60
10.62
10.55
92 15
31.43
7.78
7.60
74 -11
24.25
5.97
0.92
.33 0
0.63
0.55
0.48
.20 0
0.36
0.33
0.30
31
38
44
50
.15 1797
2787.84
893.^9
2024.73
.51 1077
1770.86
534 .92
1015.43
.54 526
929. 16
260.95
411.37
.74 205
392.51
102.07
140.61
.97 109
216.51
54.03
70.23
.26 69
140.81
34.45
43.28
.36 48
99.15
23.80
29.14
.62 35
73.94
17.56
21.11
.99 27
57.55
13.55
.73
.43
32
.25
.96
.14
.76
.46
.73
.15
.51
.42
-------
4.77
54.54
800.
52.13
2.33
3.74
42.75
900.
43.11
1.90
3.07
35.01
1000.
36.19
1.58
2.56
28.79
1250.
25.05
1.07
1.74
18.40
1500.
18.59
0.78
1.27
12.87
1750.
14.37
0.59
0.97
9.46
2000.
11.40
0.46
0.76
7.42
2250.
9.56
0.38
0.64
5.98
2500.
7.97
0.32
0.53
4.89
3000.
5.89
0.23
0.39
3.52
4000.
3.77
0.15
0.24
2.04
5000.
2.50
0.10
10.82
124.30
00
206.30
7.52
8.56
97.89
00
173.14
6.15
7.03
77.35
00
147.22
5.12
5.87
62.56
00
104.30
3.48
4.03
40.84
00
78.64
2.55
2.97
28.90
00
61.47
1.95
2.28
21.39
00
49.37
1.53
1.80
17.17
00
41.69
1.27
1.50
13.67
00
35.01
1.05
1.24
11.43
00
26.06
0.77
0.92
8.20
00
14.89
0.49
0.58
4.81
00
9.92
0.34
7.21
247.58
60.07
2.59
17.21
5.68
187.12
49.79
2.12
14.16
4.68
153.02
41.84
1.75
11.83
3.92
125.56
28.94
1.18
8.11
2.68
84.95
21.49
0.86
5.98
1.98
61.23
16.62
0. 66
4 .59
1.52
47.15
13.16
0.51
3.62
1.20
37.49
11.03
0.43
3.02
1.00
29.91
9.18
0.35
2*. 50
0.83
25.25
6.79
0.26
1.84
0.61
18.03
4.18
0.16
1.17
0.39
10.83
2.72
0.11
0.81
5.39
464.84
238.53
' 8.36
41.07
4.27
389.46
200.29
6.84
34.02
3.52
328.25
170.38
5.69
28.59
2.94
284.37
120.76
3.87
19.80
2.01
206.13
91.16
2.83
14. 6P
1.48
156.48
71.37
2.17
11.35
1.14
120.18
57.19
1.70
9.00
0.90
99.76
48.30
1.42
7.55
0.75
80.46
40.17
1.17
6.29
0.62
69.34
27.25
0.86
4.67
0.46
50.31
16.27
0.54
2.99
0.29
30.30
10.95
0.38
2.09
5.76
2.92
19.16
4.69
4.46
2.38
15.79
3.84
3.63
1.98
13.20
3.20
3.00
1.33
9.05
2.17
2.00
0.97
6.67
1.59
1.42
0.74
5.12
1.22
1.03
0.58
4.03
0.95
0.78
0.48
3.36
0.79
0.64
0.40
2.79
0.66
0.51
0.29
2.05
0.48
0.36
0.18
1.30
0.30
0.22
0.13
0.91
0.21
16.07
9.43
45.87
10.70
12.53
7.73
38.01
8.82
10.20
6.43
31.95
7.37
8.44
4.37
22.12
5.05
5.59
3.20
16.43
3.71
3.86
2.44
12.70
2.85
2.83
1.92
10.08
2.25
2.19
1.60
8.45
1.88
1.78
1.32
7.04
1.56
1.43
0.97
5.19
1.15
1.02
0.61
3.33
0.73
0.62
0':'42
2.33
0.51
21.67
17.85
14.91
10.19
7.50
5.76
4.54
3.79
3.15
2.32
1.47
1.02
-------
0
1
0
0
0
0
0
0
0
0
0
0
0
0
.17
.37
.74
.03
.06
.39
.38
.02
.03
.18
.25
.01
.02
.11
10000.
15000.
20000.
X
25.
50.
100.
200.
300.
400.
500.
600.
700.
800.
900.
1000.
1250.
1500.
1750.
2000.
2250.
2500.
3000.
4000.
5000.
10000.
15000.
20000.
,00
00
00
:,m
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
0.41
3.19
2.98
0.11
0.14
0.86
1.50
0.06
0.08
0.40
0.90
0.04
0.05
0.23
Max
0.82
0.42
0.27
0.27
7.16
0.03
0.25
0.09
1.91
0.02
0.13
0.05
0.85
0.01
0.08
0.03
0.48
concentration
30604
13987
6080
2635
1605
1107
825
649
511
392
328
284
206
156
120
99
80
69
50
30
19
5
2
1
Concentration (ppm)
LOC
IDLH
.93
.60
.10
.45
.17
.62
.67
.97
.21
.23
.25
.37
.13
.48
.18
.76
.46
.34
.31
.30
.95
.12
.32
.26
0
19
3.30
0
0
0
5
1.61
0
0
0
2
0.97
0
0
0
1
, ppm
.20
.95
.11
.62
.07
.12
.06
.32
.04
.32
.04
.21
.03
.26
Distance to (m)
9.6000
19.6000
8489.
5119.
,07
,39
0.15
C.41
0.04
0.27
0.07
0.04
0.02
0.14
0.04
0.02
0.01
0.09
0.02
0.01
0.13
0.68
0.17
0.12
0.07
0.35
0.09
0.06
0.04
0.23
0.06
0.03
C.3C
0.10
-------
From Slao output file:
Scenario:
Accident Location:
Duration:
Meteorology:
Chemical:
Vapor phase mole fraction:
LOG:
IDLH:
X,m Max concentration, ppm
RUN63a.OUT
CONSERV
OFFSITE
UNMITIG
INVERSN
FORMALDEHYDE
0.517
9.600
19.600
25
50
100
200
300
400
500
600
700
800
900
1000
1250
1500
1750
2000
2250
2500
3000
4000
5000
10000
15000
20000
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
29762
14467
6662
3001
1890
1349
1046
840
- 688
591
504
444
328
256
208
167
144
120
92
57
39
11
5
3
.75
.23
.73
.10
.15
.27
.28
.90
.30
.85
.54
.42
.81
.43
.59
.60
.06
.52
.22
.10
.38
.38
.33
.06
Concentration (ppm)
Distance to (m)
LOC
IDLH
9.6000
19.6000
11471.97
8532.36
-------
From Slab output file:
Scenario:
Accident Location:
Duration:
Meteorology:
Chemical:
Vapor phase mole fraction:
LOG:
IDLH:
RUN63b.OUT
CONSERV
OFFSITE
UNMITIG
INVERSN
FORMALDEHYDE
0.053
9.600
19.600
X,m Max concentration, ppm
25
50
100
200
300
400
500
600
700
800
900
1000
1250
1500
1750
2000
2250
2500
3000
4000
5000
10000
15000
20000
Concentra
LOG
IDLH
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
tion (ppm)
9.6000
19.6000
408
295
147
59
36
26
20
16
13
11
9
8
6
4
3
2
2
1
1
0
0
0
0
0
.63
.99
.29
.08
.31
.10
.24
.50
.57
.51
.79
.54
.19
.63
.68
.92
.42
.95
.43
.82
.54
.14
.06
.03
Distance to (m)
915.48
517.18
-------
From Slab output file: RUN64.0UT
Scenario: CONSERV
Accident Location: OFFSITE
Duration: UNMITIG
Meteorology: TYPICAL
Chemical: ACETONE
Vapor phase mole fraction: 0.527
LOG: 1960.000
X,m
25.00
50.00
100.00
200.00
300.00
400.00
500.00
600.00
700.00
800.00
900.00
1000.00
1250.00
1500.00
1750.00
2000.00
2250.00
2500.00
3000.00
4000.00
5000.00
10000.00
15000.00
20000.00
Concentration
LOC 1960.
IDLH 2442.
IDLH: 2442.000
Max concentration, ppm
592.00
354.40
173.24
69.04
36.99
23.66
16.40
12.12
- 9.36
7.39
6.09
5.09
3.47
2.55
1.95
1.54
1.28
1.06
0.78
0.47
0.31
0.09
0.05
0.03
(ppm) Distance to (m)
.0000 less tnan 25.00
.0000 less than 25.00
-------
From Slab output file:
Scenario :
Accident Location:
Duration:
Meteorology:
Chemical :
Vapor phase mole fraction:
LOG:
IDLH:
X,m
6
12
18
24
7
13
19
25
14
20
26
9
15
21
27
RUN65.OUT
CONSERV
OFFSITE
UNMITIG
WORST
ACETONE
0.527
1960.000
2442.000
3
10
16
22
25.00 182.52 348
4443.20 136.14 257.88
4147.49 108.39 205.18
90.29 170.57
145.80 305.13
81.37 174
60.14- 128.52
48.01 102.11
39.93 85.04
72.54 171.95
29.58 70
21.78 51.83
17.29 40.91
14.40 33.90
28.93 78.03
3265.64
2598.11
50.00
2157.95
2079.12
1914.70
1662.58
100.00
943.33
918.46
920.51
870.32
200.00 9.32
414.64 6.84
401.36 5.44
403.32 4.54
393.64 9.73
300.00 4.50
258.61 3.32
245.57 2.66
242.09 2.22
234.66 4.82
400.00 2.71
182.43 2.02
174.90 1.62
169.69 1.35
162.32 2.96
500.00 1.81
141.22 1.35
133.20 1.08
127.41 0.90
120.36 1.99
600.00 1.30
113.46 0.97
106.33 0.78
100.53 0.65
94.00 1.44
700.00 0.98
93.13 0.73
87.70 0.59
81.90 0.49
76.03 1.10
800.00 0.76
73.86 0.57
.35 813.34 1554
1031.16
779.96
634.16
555.11
434.42
358.18
537.19
.65 452.69 892
313.99 612.37
244.99 468.25
201.69 380.79
322.02
.81 201.75 401
143.13 296.53
228.79
186.17
111.37
91.64
156.99
24.26
74.34
152.
17.57
13.80
11.38
28.82
8.74
6.88
5.68
14.93
5.37
4.21
3.47
9.34
3.63
2.84
2.34
6.40
53.76 117.48
41.66 91.58
34.03 74.32
62.17
12.12 38.53
28.05 63.10
21.69 49.22
17.66 39.87
33.40
7.44 24.21
17.66 40.21
13.63 31.49
11.09
81
51.
5.02
3.64
.63
.06
.70
69
21.35
12.10
9.35
7.59
14.79
8.85
6.84
5.56
10.92
25.51
16.59 36.
27.89
21.86
17.70
12.13
26.
20.62
16.16
13.08
2.00
1.57
1.29
3.59
1.56
2.77
2.15
9.28
6.78
5.25
4.26
8. 44
5.31
15.92
12.46
10.09
7.29
20.
16.
12.56
4 5
11
17
23
.65 2772.02
1848.01
1389.52
1120.75
.32 1462.95
1113.87
867.44
707.23
.81 628.35
544.20
445.52
369.23
.00 247.58
222.94
189.12
158.48
05 139.89
124.30
105.81
88.96
87 93.97
81.96
69. 42
58.25
17 68.01
58.48
49.13
41.23
84 52.18
44.12
36.92
30.90
81 41.59
34.71
28.91
24.14
52 33.81
27.92
-------
73.57
67.85
62.64
900
60.61
63.48
58.09
53.18
1000
50.72
53.87
50.29
45.72
1250
36.63
36.05
36.86
33.12
1500
28.26
26.84
27.41
25.45
1750
22.60
20.61
20.13
20.22
2000
18.18
17.05
15.83
16.39
2250
15.49
13.94
13.13
13.24
2500
12.85
11.96
10.84
10.45
3000
9.81
8.92
8.12
7.44
4000
6.00
5.61
4.90
4.58
5000
4.11
3.86
3.38
3.12
10000
1.17
1.13
0.46
0.38
0.86
.00
0.46
0.37
0.31
0.70
.00
0.38
0.31
0.25
0.58
.00
0.26
0.20
0.17
0.39
.00
0.18
0.15
0.12
0.28
.00
0.14
0.11
0.09
0.22
.00
0.11
0.09
0.07
0.17
.00
0.09
0.07
0.06
0.14
.00
0.07
0.06
0.05
0.12
.00
0.05
0.04
0.04
0.08
.00
0.03
0.03
0.02
0.05
.00
0.02
0.02
0.01
0.04
.00
0.01
0.01
1.22
1.01
2.82
0.62
1.27
1.00
0.82
2.32
0.51
1.05
0.83
0.68
1.93
0.34
0.71
0.56
0.46
1.31
0.25
0.51
0.40
0.33
0.96
0.19
0.39
0.31
0.25
0.73
0.14
0.31
0.24
0.20
0.58
0.12
0.25
0.20
0.16
0.48
0.09
0.21
0.16
0.14
0.39
0.07
0.15
0.12
0.10
0.29
0.04
0.09
0.07
0.06
0.18
0.03
0.06
0.05
0.04
0.13
0.01
0.02
0.01
4.12
3.35
6.68
1.76
4.36
3.38
2.74
5.49
1.45
3.63
2.81
2.28
4.58
0.97
2.46
1.90
1.55
3.13
0.71
1.79
1.39
1.13
2.30
0.54
1.36
1.06
0.87
1.77
0.42
1.07
0.83
0.68
1.39
0.34
0.89
0.69
0.56
1.16
0.27
0.73
0.57
0.46
0.96
0.19
0.50
0.41
0.34
0.70
0.11
0.30
0.24
0.21
0.44
0.08
0.20
0.16
0.14
0.29
0.02
0.06
0.05
9.83
7.95
5.99
10.35
8.10
6.55
4.99
8.64
6.77
5.48
3.38
5.90
4.62
3.74
2.46
4.34
3.39
2.75
1.84
3.32
2.59
2.10
1.36
2.61
2.04
1.66
1.12
2.09
1.70
1.38
0.90
1.65
1.40
1.14
0.64
1.16
1.02
0.84
0.38
0.70
0.59
0.51
0.26
0.47
0.39
0.33
0.08
0.14
0.12
23.13
19.27
13.66
23.26
19.19
15.98
11.45
19.65
16.16
13.44
7.85
13.73
11.23
9.30
5.64
10.25
8.33
6.91
4.09
7.81
6.43
5.34
3.15
5.80
5.11
4.21
2.57
4.74
4.27
3.52
2.06
3.81
3.52
2.93
1.50
2.74
2.39
2.15
0.90
1.67
1.43
1.23
0.61
1.13
0.96
0.82
0.18
0.34
0.29
28.44
24.21
16.55
11.60
8.68
6.86
5.61
4.63
3.41
2.02
1.37
0.40
-------
1.01
0.94
0.56
0.52
0.49
0.45
15000.00
0.00
0.01
)
0.00
0.00
0.00
0.01
0.00
0.01
0.04
)
0.01
0.01
0.01
0.02
0.01
0.04
0.09
0.03
0.02
0.02
0.04
20000.00
0.00
0.01
0.32
0.31
0.29
0.27
33
39
45
51
25
820.36
101.89
105.22
1907.74
50
518.48
50.55
59.49
924.57
100
272.07
20.18
26.83
331.42
200
116.57
6.77
9.85
106.06
300
65.15
3.35
5.08
53. 98
400
42.59
2.05
3.17
34.00
500
30.04
1.38
2.17
23.46
600
22.48
1.00
1.59
17.31
700
17.54
0.76
0.00
0.00
0.00
0.00
X,m
34
40
46
52
.00 945
1877.88
212.21
182.87 -
2891.47
.00 599
1261.22
119.50
109.81
1273.23
.00 313
715.18
54 .03
53.37
491.64
.00 134
341.33
19.89
20.89
183.34
.00 75
204 .42
10.25
11.05
100.44
.00 49
140.46
6.41
7.03
66.19
.00 34
102.88
4.39
4.86
47.13
.00 26
79.59
3.21
3.58
35.71
.00 20
63.75
2.46
0.01
0.00
0.00
0.01
28
35
41
47
53
.09 2173
113.31
369.78
121.39
3599.41
.94 1437
56.45
221.72
72.85
1678.96
.48 795
22.43
107.93
35.45
685.04
.70 370
7.51
42.45
13.86
275.19
.42 221
3.73
22.58
7.35
161.41
.33 152
2.28
14.41
4.66
108.64
.90 112
1.54
9.97
3.23
81.15
.13 86
1.11
7.36
2.38
61.76
.40 69
0.85
5.68
0.02
0.02
0.01
0.03
29
36
42
48
54
.00 127
236.10
648.21
90.82
3315.72
.23 63
133.06
411.17
54.66
993.33
.38 25
60.04
215.63
26.56
437.36
.39 8
22.12
91.74
10.41
223.88
.17 4
11.44
50.89
5.50
155.63
.18 2
7.17
33.21
3.50
115.34
.08 1
4.90
23.42
2.42
84.57
.74 1
3.58
17.51
1.79
68.03
.62 0
2.74
13.66
0.04
0.04
0.03
30
37
43
49
.36 266.
412.29
131.93
280.36
.56 149.
247.06
74.10
125.91
.27 67.
120.33
33.58
46.43
.49 25.
47.41
12.35
14.71
.21 12.
25.30
6.37
7.11
.58 8.
16.12
3.97
4.28
.74 5.
11.15
2.71
2.85
.26 4.
8.25
1.99
2.04
. 96 3...
6.37
1.52
0.10 0.25
0.04 0.09 0.19
0.07 0.17
0.06 0.14
0.05 0.13 '
0.02 0.05 0.11
0.10
0.09
0.08
31
32
38
44
50
13 466.04
723.75
229.07
551.59
77 279.44
458.49
137.25
274.65
90 136.21
240.43
66.89
110.75
03 53.75
102.66
26.14
37.65
92 28.78
57.04
13.88
18.84
11 18.38
37.33
8.80
11.58
54 12.72
26.32
6.08
7.83
06 9.40
19.68
4.49
5.67
11 7.26
15.36
3.47
-------
1.22
13.38
14.00
0.60
0.96
10.59
11.62
0.49
0.78
8.73
9.77
0.40
0.65
7.19
6.75
0.27
0.44
4.59
5.00
0.20
0.32
3.26
3.86
0.15
0.25
2.42
3.06
0.12
0.19
1.91
2.56
0.10
0.16
1.55
2.13
0.08
0.13
1.27
1.57
0.06
0.10
0.92
1.00
0.04
0.06
0.54
0.66
0.03
800
900
1000
1250
1500
1750
2000
2250
2500
3000
4000
5000
o
£- .
28
.00
51
1.
2.
22
.00
43
1.
1.
17.
.00
37.
1.
1.
14 .
.00
26.
0.
1.
9.
.00
20.
0.
0.
7 .
.00
15.
0.
0.
5.
.00
12.
0.
0.
4 .
.00
10.
0.
0.
3.
.00
9.
0.
0.
2.
.00
6.
0.
0.
2.
.00
3.
0.
0.
1.
.00
2.
0.
76
.12
.89
93
18
.40
.79
59
80
83
40
32
50
53
69
90
03
75
27
65
76
02
96
50
58
24
88
39
46
26
89
33
38
42
15
27
32
88
83
20
23
09
88
12
15
25
60
09
1.
45
16.28
0
4.
1.
36
13.52
0
3.
1.
30.
11.36
0.
3.
1.
25.
7.85
0.
2.
0.
17.
5.83
0.
1.
0.
13.
4 .49
0.
1.
0.
10.
3.55
0.
0.
0.
8.
2.97
0.
0.
0.
6.
2.47
0.
0.
0.
5.
1.83
0.
0.
0.
4 .
1.11
0.
0.
0.
2.
0.72
0.
0.
84
.55
.66
48
45
.94
.54
69
20
43
45
09
00
39
30
11
69
80
22
55
50
53
17
19
39
56
13
94
31
27
11
78
25
98
09
65
21
72
07
48
16
26
04
30
10
56
03
21
1 .
56
57.02
2
10.
1.
48
48.30
1
9.
0.
42.
41.38
1.
7.
0.
37.
29.70
1.
5.
0.
29.
22.65
0.
3.
0.
23.
17.90
0.
3.
0.
19.
14.47
0.
2.
0.
16.
12.26
0.
1.
0.
13.
10.22
0.
1.
0.
11.
6.93
0.
1.
0.
9.
4.19
0.
0.
0.
5.
2.84
0.
0.
38
.93
.16
90
09
.55
.77
01
90
75
47
57
75
73
00
24
51
11
73
89
38
08
56
00
29
13
44
38
23
13
37
99
19
59
30
66
16
85
22
23
12
02
14
78
07
81
10
55
1
0.75
1
1
0.61
0
0
0.51
3
0
0
0.34
2
0
0
0.25
1
0
0
0.19
1
0
0
0.15
1
0
0
0.12
0
0
0
0.10
0
0
0
0.07
0
0
0
0.05
0
0
0
0.03
0
0
.54
5.03
.19
.19
4.14
.98
.97
.46
.82
.80
.37
.55
.53
.74
.41
.37
.34
.31
.27
.05
.24
.20
.88
.20
.17
.73
.17
.13
.53
.12
.09
2.44
2.01
1.67
1.13
0.83
0.63
0.50
0.41
0.34
0.25
4.31
12.27
2.74
3.36
10.15
2.26
2.74
8.52
1.89
2.27
5.89
1.29
1.49
4.38
0.95
1.03
3.38
0.73
0.76
2.68
0.58
0.58
2.24
0.48
0.47
1.86
0.40
0.38
1.38
0.29
0.27
0.16
.34
.08
.06
.24
.05
,..0.11
0.88
0.19
0.16
0.61
0.13
5.72
3. 94
2.70
1. 98
1.52
1.20
1.00
0.83
0.61
0.38
0.27
-------
0
o
o
0
0
o
o
0
0
o
0
o
0
0
.04
. 36
10000.
.19
.01
.01
. 10
15000,
. 10
. 00
.01
. 05
20000
.06
. 00
.00
.03
0.
0.
,00
0.
0.
0.
0.
.00
0.
0.
0.
0.
.00
0.
0.
0.
0.
10
84
79
03
04
23
39
01
02
11
24
01
01
06
0
1
0.21
0
0
0
0
0.11
0
0
0
c
0.07
0
0
0
0
.07
.71
.01
.06
.02
.47
.00
.03
.01
.21
.00
.02
.01
.12
0.
4 .
0.86
0.
0.
0.
1.
0.42
0.
0.
0.
0.
0.25
0.
0.
0.
0.
05
02
03
16
02
17
02
08
01
55
01
05
01
31
0.
0.01
0.
0.
0.
0.01
0.
0.
0.
0.00
0.
0.
0.
04
07
02
01
04
01
01
02
01
00
0
0.03
0
0
0
0.02
0
0
0
0.01
0
0
0
.11
.18
.04
.03
. 09
.02
.02
.06
.01
.01
X,m
Max concentration, ppm
25.
50.
100.
200.
300.
400.
500.
600.
700.
800.
900.
1000.
1250.
1500.
1750.
2000.
2250.
2500.
3000.
4000.
5000.
10000.
15000.
20000.
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
- 4443.
2157.
943.
414.
258.
182.
141.
113.
93.
73.
63.
53.
36.
28.
22.
18 .
15.
12.
9.
6.
4 .
1.
0.
0.
20
95
33
64
61
43
22
46
13
86
48
87
86
26
60
18
49
85
81
00
11
17
56
32
0.08
:.04
0.03
Concentration (ppm)
LOG
IDLH
1960.0000
2442.0000
Distance to (m)
58.15
46.89
-------
From Slab output file:
Scenario:
Accident Location:
Duration:
Meteorology:
Chemical:
Vapor phase mole fraction:
LOG:
IDLH:
X,m Max concentration, ppm
RUN66a.OUT
CONSERV
OFFSITE
UNMITIG
INVERSN
ACETONE
0.536
1960.000
2442.000
25.00
50.00
100.00
200.00
300.00
400.00
500.00
600.00
700.00
800.00
900.00
1000.00
1250.00
1500.00
1750.00
2000.00
2250.00
2500.00
3000.00
4000.00
5000.00
4118
2170
1039
458
282
196
148
119
- 98
82
71
61
45
35
29
24
20
17
13
8
6
.62
.68
.17
.90
.52
.35
.99
.68
.75
.04
.59
.73
.89
.88
.32
.17
.42
.57
.39
.79
.20
Concentration (ppm)
LOC
IDLH
1960.0000
2442.0000
Distance to (m)
59.31
46.52
-------
From Slab output file:
Scenario:
Accident Location:
Duration:
Meteorology:
Chemical:
Vapor phase mole fraction:
LOG:
IDLH:
RUN66b.OUT
CONSERV
OFFSITE
UNMITIG
INVERSN
ACETONE
0.193
1960.000
2442.000
X,m Max concentration, ppm
25.00
50.00
100.00
200.00
300.00
400.00
500.00
600.00
700.00
800.00
900.00
1000.00
1250.00
1500.00
1750.00
2000.00
2250.00
2500.00
3000.00
4000.00
5000.00
350.
156.
85.
49.
35.
28.
23.
20.
18.
16.
14.
13.
11.
9.
8.
7 .
6.
5.
4.
3.
2.
49
59
99
27
70
54
94
72
30
36
80
54
20
50
25
27
49
88
89
64
84
Concentration (ppm)
Distance to (m)
LOC
IDLH
1960.0000
2442.0000
less than
less than
25.00
25.00
-------
From Slab output file:
Scenario :
Accident Location:
Vapor phase
X,m
25.00
50.00
100.00
200.00
300.00
400.00
500.00
600.00
700.00
800.00
900.00
1000.00
1250.00
1500.00
1750.00
2000.00
2250.00
2500.00
3000.00
4000.00
5000.00
Duration:
Meteorology:
Chemical :
mole fraction:
LOG:
IDLH:
Max concentration, ppm
178.57
71.38
24.74
7.76
3.84
2.29
1.54
1.12
0.86
0.69
0.55
0.46
0.31
0.22
0.17
0.13
0.11
0.09
0.06
0.04
0.03
Concentration (ppm) Distance to
LOG
IDLH
9.6000 189.
19.6000 130.
RUN67.0UT
TYPICAL
OFFSITE
UNMITIG
TYPICAL
FORMALDEHYDE
0.482
9.600
19.600
(m)
15
28
-------
67.46
2.91
4.79
41.72
56.59
2.39
3.85
34.87
48.18
2.00
3.30
29.07
34.02
1.35
2.27
20.00
25.35
1.00
1.66
14 .60
19.84
0.76
1.25
11.46
15.86
0.59
1.02
9.03
13.12
0.50
0.82
7.39
11.10
0.41
0.70
6.13
8.16
0.30
0.52
4.39
4.92
0.19
0.32
2.69
3.32
0.13
0.22
1.80
800
900
1000
1250
1500
1750
2000
2250
2500
3000
4000
5000
.00
250
9.
10.
84
.00
211
7.
8.
72
.00
178
6.
7.
59
.00
128
4.
5.
42
.00
97
3.
3.
32
.00
76
2.
2.
25
.00
62
2.
2.
19.
.00
52
1.
1.
16.
.00
42
1.
1.
13.
.00
31.
1.
1.
9.
.00
18.
0.
0.
5.
.00
12.
0.
0.
3.
.00
69
76
.48
.54
81
78
.00
.73
66
52
.86
.45
56
22
.07
.26
34
83
.10
.15
55
99
.07
.97
04
43
52
.07
68
96
45
.80
39
68
37
16
04
24
96
87
64
78
88
89
44
54
97
81.72
3.26
21.95
7.03
155.67
67.50
2.63
18.04
5.96
133.46
57.55
2.22
15.37
4.89
114 . 95
40.03
1.51
10.68
3.43
83.42
29.58
1.11
7.92
2.58
63.77
22.99
0.84
6.05
2.01
49.56
18.28
0.67
4 . 94
1.59
40.51
15.20
0.55
4 .04
1.33
33.21
12.77
0.45
3.40
1.11
28.30
9.36
0.34
2.53
0.83
20.95
5.64
0.21
1.55
0.51
12.85
3.80
0.14
1.06
0.36
8.66
261.48
10
48.
5.
346
223.73
8
41.
4.
295
189.89
7
35.
3.
261
137.83
5
25.
2.
195
105.85
3
19.
1.
151
83.11
2
15.
1.
121
67.32
2
12.
1.
101.
54.83
1
10.
0.
84.
45.57
1
8.
0.
72.
33.57
1.
6.
0.
52.
20.13
0.
4 .
0.
33.
13.80
0.
2.
0.
22.
.77
12
38
.16
.69
53
39
.76
.46
34
75
.73
.10
40
61
.76
.73
24
92
.82
.83
29
50
.69
.29
36
21
26
.88
07
98
15
c f
65
84
16
16
44
62
93
71
04
39
10
48
73
27
17
3.68
24
5.
5.
2.94
20
4.
4.
2.51
17
4.
3.
1.71
11
2.
2.
1.25
8
2.
1.
0.95
6
1.
1.
0.76
5
1.
1.
0.62
4
1.
0.
0.51
3
0.
0.
0.38
2.
0.
0.
0.23
1.
0.
0.
0.16
1.
0.
0.
.67
93
56
.52
90
42
.29
08
69
.98
79
45
.83
02
74
.75
59
31
.53
27
05
.50
03
82
.80
87
69
82
64
50
72
40
29
17
28
20
12.19
56
13.
. 15.
9.88
48
11 .
12.
8.40
40
9.
10.
5.78
28
6.
6.
4.19
21
4.
4.
3.18
17
3.
3.
2.60
13
3.
2.
2.11
11
2.
2.
1.78
9
2.
1.
1.32
7.
1.
1.
0.80
4 .
0.
0.
0.54
2.
,. 0.
0.
.53
14
32
.12
16
32
.91
24
23
.87
46
85
.75
82
87
.28
79
71
.94
01
94
.44
50
31
.73
09
97
23
53
41
44
97
84
99
68
57
28.12
23.53
19.66
13.70
9.98
7.80
6.32
5.10
4.33
3.20
1.92
1.29
-------
1.01
0.04
0.07
0.52
0.51
0.02
0.04
0.24
Conc<
LOG
IDLH
10000
15000
25
50
100
200
300
400
500
600
700
800
900
1000
1250
1500
1750
2000
2250
2500
3000
4000
5000
10000
15000
entra'
.00
3
0
0
1
.00
1
0
0
0
X,m
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
..00
tion
t
1.13
.94
.14
.18
.12
0.58
.97
.07
.10
.53
Max conce
8087
6763
4110
1893
1113
774
604
- 488
401
346
295
261
195
151
121
101
84
72
52
33
22
6
2
(ppm)
9.9000
19.1000
4.25
0.05 0.
0.34 0.
0.12 0.
2.37 6.
2.08
0.02 0.
0.18 0.
0.07 0.
1.06 2.
ntration, ppm
.54
.27
.25
.05
.48
.63
.16
.84
.77
.16
.76
.73
.76
.82
.69
.26
.15
.16
.93
.10
.17
.00
.81
Distance to
8793.
3193.
16
86
09
00
08
44
05
81
(m)
28
13
0.05
0.17
0.37
0.09
0.06
0.03
0.20
0.05
0.03
0.93
0.22
0.16
0.09
0.48
0.12
0.08
0.21
-------
From Slab output file:
Scenario :
Accident Location:
Duration:
Meteorology:
Chemical :
Vapor phase mole fraction:
LOG:
IDLH:
RUN 5 2. OUT
CONSERV
ON-SITE
MIT I GAT
WORST
HCL
1.000
9.900
49.100
"Output adjusted to be distance from fenceline.
X,m 1
678
12 13 14
18 19 20
24 25 26
25.00 118.24 235
4070.16 89.59 154.00
3253.49 74.33 125.00
43.93 63.76 110.01
0.00 97.89 74.59
50.00 «2.50 195
2527.86 63.13 131.88
3429.95 51.77 105.86
2622.17 43.74 89.34
43.60 78.29 100.70
100.00 44.84 118
1397.32 34.26 82.54
1663.11 27.39 65.13
2101.31 23.25 54.10
1877.08 47.54 102.10
200.00 19.15 52
717.40 14.53 37.33
752.57 11.75 29.35
857.95 9.80 24.67
970.06 21.28 60.11
300.00 10.44 29
470.09 7.89 21.16
479.74 6.24 16.54
504.94 5.28 13.55 '
542.38 11.67 36.40
400.00 6.56 18
338.22 4.97 13.29
335.18 4.01 10.47
352.66 3.37 8.75
365.74 7.55 23.96
500.00 4.54 12
261.44 3.43 9.33
252.45 2.76 7.30
267.22 2.32 6.08
270.14 5.25 16.98
600.00 3.37 9
214.77 2.54 7.00
202.13 2.01 5.46
208.85 1.68 4.47
211.75 3.84 12.84
700.00 2.60 7
180.42 1.98 5.43
165.96 1.58 4.26
167.18 1.31 3.53
170.17 3.00 10.11
2 3
9 10
15 16
21 22
27
.73 1109.99 2052
273.09 586.08
120.21 80.78
85.73 38.12
29.08
.48 799.39 1324
332.75 768.00
170.30 221.13
123.56 111.76
75.55
.75 409.30 654
266.55 618.73
165.10 296.65
122.29 175.40
123.12
.40 159.22 274
129.90 286.01
92.74 206.21
71.94 142.22
106.27
.42 90.33 161
74.16 159.70
55.69 128.44
43.93 96.41
74.86
.38 57.33 107
47.19 102.93
36.09 84.83
28.68 66.29
52.73
.81 40.23 76
32.89 72.34
25.48 60.20
20.31 48.04
38.82
.44 29.74 57
24.42 53.93
19.07 44.99
15.40 36.44
29.88
.20 22.61 44
18.63 41.32
14.74 34.60 ,.
12.01 28.36
23.53
4
11
17
23
.56 2872
1470.49
54 .04
1.09
.15 1725
1910.00
507.66
35.20
.07 875
1111.16
821.77
300.31
.88 413
465.04
477.49
322.80
.19 254
264.91
271.98
225.10
.96 178
180.35
179.11
156.67
.75 130
130.77
127.86
113.86
.35 99
96.96
95.61
35.84
.14 79
75.92
75.32
67.18
5
.74
.89
.08
.12
.83
.53
.11
.78
.85
-------
800.00
152.35
139.34
137.05
136.61
900.00
134.48
121.29
118.02
116.31
1000.00
117.13
105.93
99.79
97.20
1250.00
89.81
79.27
72.90
69.72
1500.00
71.87
62.57
57.11
53.05
1750.00
58.13
50.34
45.98
42.49
2000.00
48.35
41.76
37.13
34.28
2250.00
40.73
35.28
31.74
28.71
2500.00
34. 91
30.28
26.50
24.18
3000.00
26.33
23.02
20.25
17.95
4000.00
16.49
14.43
12.67
11.50
5000.00
11.30
9.95 0
8.70 0
7.97 0
1.55
1.25
1.04
2 _ / n
1.26
1.01
0.84
1.93
1.03
0.85
0.71
1.65
0.68
0.57
0.48
1.12
0.48
0.40
0.35
0.81
0.37
0.30
0.25
0.60
0.29
0.24
0.20
0.48
0.23
0. 19
0.16
0.39
0.20
0.16
0.14
0.33
0.14
0.12
0.10
0.24
0.09
0.07
0.06
0.14
0.06
.05
.04
.10
2.00
4.24
3.35
2.80
8.01
1.62
3.50
2.77
2.28
6.64
1.32
2.84
2.29
1.91
5.53
0.89
1.89
1.53
1.30
3.78
-0.62
1.34
1.08
0.93
2.75
0.48
1.05
0.84
0.69
2.06
0.38
0.82
0.66
0.56
1.65
0.31
0.66
0.53
0.44
1.30
0.26
0.55
0.45
0.38
1.10
0.18
0.40
0.32
0.27
0.80
0.11
0.24
0.20
0.17
0.48
0.08
0.17
0.13
0.11
0.33
5.52
14.36
11.56
9.43
18.59
4.57
11.80
9.72
7.88
15.66
3.69
9.44
7.95
6.51
12.93
2.48
6.34
5.27'
4.47
8.99
1.81
4.65
3.76
3.16
6.38
1.39
3.55
2.90
2.43
4.97
1.07
2.73
2.27
1. 91
3.92
0.88
2.25
1. 82
1.50
3.13
0.72
1.84
1.52
1.28
2.63
0.51
1.32
1.09
0.92
1.90
0.32
0.81
0.67
0.56
1.16
0.22
0.55
0.46
0.38
0.79
17.55
32.63
27.77
22.66
14.58
26.49
22.81
18.85
11.87
21.71
18.60
15.43
8.05
14.69
12.23
10.43
5.92
10.68
8.90
7.51
4.52
8.12
6.81
5.79
3.47
6.26
5.27
4.51
2.90
5.24
4 .36
3.65
2.34
4.23
3.56
3.02
1.73
3.13
2.54
2.16
1.04
1.88
1.58
1.34
0.70
1.28
1.07
0.91
35.81
61.86
60.75
55.03
29.49
50.10
48.36
44.92
24.86
43.14
41.00
38.23
17.14
30.05
27.91
25.74
12.72
22.18
20.35
18.68
9.70
17.18
15.30
14.14
7.83
13.97
12.19
10.85
6.38
11.14
9. 95
9.03
5.35
9.61
8.33
7.32
3.93
7.05
6.12
5.37
2.38
4.39
3.70
3.27
1.62
3.01
- 2 . 52
2.23
66.73
55.20
48.05
34.36
25.83
20.57
16.71
13.69
11.65
8.55
5.35
3.62
-------
From Slab output file: RUN68.0UT
Scenario: TYPICAL
Accident Location: OFFSITE
Duration: UNMITIG
Meteorology: ' WORST
Chemical: FORMALDEHYDE
fraction: 0.482
LOC:
IDLH:
X,m 1
6 1 8
12 13 14
18 19 20
24
25
1277.30
1135.47
964 .41
825.86
50
580 . 01
536. 17
469.61
403. 50
100
249.24
227.08
197.52
169. 90
200
99. 28
87.35
74.27
62 .77
300
50.52
48.16
40.14
33.75
400
32.05
28.83
25.34
21 .20
500
22.35
19.12
16.54
14.79
600
16.47
14.09
11.84
10.95
700
12.73
10.81
9.13
8.23
800
10.34
25 26
.00 43.32
32.46
25.96
21.64
38.24
.00 13.49
10.11 --
8.10
6.72
13.03
.00 3.87
2.90
2.32
1.94
3.99
.00 1-05
0.79
0.63
0.52
1.13
.00 0.49
0.37
0.29
0.24
0.53
.00 0.28
0.21
0.17
0.14
0.31
.00 0.18
0.14
0.11
0.09
0.20
.00 0.13
0.10
0.08
0.06
0.14
.00 0.10
0.07
0.06
0.05
0.11
.00 0.08
0.06
66.98
53.68
44.61
89.42
22.83
18.27
15.24
33.23
6.98
5.57
4.65
10.90
1.98
1.58
1.32
3.26
0.93
0.74
0.62
1.58
0.54
0.43
0.36
0.93
0.35
0.28
0.23
0.62
0.25
0.20
0.17
0.45
0.. 19
0.15
0.13
0.34
0.15
9.600
19.600
2 3
9 10
15 16
21 22
27
89.32 210.
157.00
125.59
104.17
163.33
30.43 79.
58.71
46.69
38.81
65.48
9.33 26.
19.24
15.27
12.73
22.59
2.64 7.
5.76
4.57
3.81
7.04
1.24 3.
2.80
2.23
1.85
3.50
0.72 2.
1.65
1.31
1.09
2.09
0.47 1,
1.10
0.88
0.73
1.41
0.33 1
0.79
0.63
0.52
1.02
0.25 0
0.60
0.48
0.40
0.78
0.19 0
0.48
76 385.
287.62
229.52
190.94
25 156.
116.30
92.36
76.27
06 54.
40.50
31.95
26.46
82 17.
12.73
10.04
8.28
.80 8.
6.30
4.96
4.10
,23 5.
3.75
2.96
2.45
.49 3.
2.52
1.99
1.65
.07 2,
1.82
1.44
1.19
.80 1
1.40
1.11
0.92 ,.
.62 1
1.10
4
11
17
23
74 681.
519.57
415.69
346.54
86 296.
226.95
181.09
150.36
92 112.
85.11
67.44
55.72
39 37.
28.45
22.39
18.42
60 19.
14.50
11.41
9.36
11 11.
8.77
6.93
5.69
,43 7.
5.98
4.69
3.88
.38 5,
4.14
3.44
2.83
.80 4
3.15
2.67
2.20
.40 3
2.46
5
57
27
08
94
45
33
32
.29
.03
.09
-------
8.30
7.09
6.46
8.34
6.98
5.79
5.04
7.09
5.67
4 .74
4.28
4.83
3.85
3.17
2.86
3.45
2.85
2.32
2.05
2.72
2.16
1.81
1.53
2.09
1.71
1.40
1.24
1.74
1.40
1.17
0.98
1.38
1.17
0.94
0.85
1.02
0.85
0.71
0.61
0.59
0.50
0.42
0.38
0.39
0.34
0.29
0.26
33
39
0.05
0.04
0.09
900.00
0.05
0.04
0.03
0.07
1000.00
0.04
0.03
0.03
0.06
1250.00
0.02
0.02
0.02
0.04
1500.00
0.02
0.01
0.01
0.03
1750.00
0.01
0.01
0.01
0.02
2000.00
0.01
0.01
0.01
0.02
2250.00
0.01
0.01
0.01
0.01
2500.00
0.01
0.01
0.00
0.01
3000.00
0.00
0.00
0.00
0.01
4000.00
0.00
0.00
0.00
0.00
5000.00
0.00
0.00
0.00
0.00
X,m
34
40
0.12
0.10
0.27
0.06
0.12
0.10
o.oe
0.22
0.05
0.10
0.08
0.07
0.18
0.03
0.06
0.05
0.04
0.12
0.02
0.05
0.04
0.03
0.09
0.02
0.03
0.03
0.02
0.07
0.01
0.03
0.02
0.02
0.05
0.01
0.02
0.02
0.01
0.04
0.01
0.02
0.01
0.01
0.04
0.01
0.01
0.01
0.01
0.03
0.00
0.01
0.01
0.01
0.02
0.00
0.01
0.00
0.00
0.01
28
35
41
0.38
0.32
0.63
0.15'
0.37
0.31
0.25
0.50
0.13
0.31
0.26
0.21
0.42
0.08
0.20
0.17
0.14
0.29
0.06
0.15
0.12
0.10
0.20
0.04
0. 11
0.09
0.08
0.15
0.03
0.08
0.07
0.06
0.12
0.03
0.07
0.06
0.05
0. 10
0.02
0.06
0.05
0.04
0.08
0.02
0.04
0.03
0.03
0.06
0.01
0.03
0.02
0.02
0.04
0.01
0.02
0.01
0.01
0.02
29
36
42
0.88
0.73
0.49
0.86
0.71
0.59
0.41
0.72
0.59
0.49
0.27
0.47
0.38
0.32
0.19
0.34
0.28
0.23
0.14
0.25
0.21
0.18
0.11
0.19
0.16
0.14
0.09
0.16
0.13
0.11
0.07
0.13
0.11
0.09
0.05
0.10
0.08
0.07
0.03
0.06
0.05
0.04
0.02
0.04
0.03
0.03
30
37
43
2.10
1.76
1.09
1.93
1.64
1.42
0.93
1.62
1.37
1.18
0.61
1.08
0.90
0.77
0.43
0.78
0.65
0.55
0.32
0.58
0.48
0.42
0.26
0.47
0.38
0.32
0.21
0.37
0.31
0.27
0. 17
0.31
0.26
0.21
0.12
0.23
0.19
0.16
0.07
0.14
0.11
0.10
0.05
0.09
0.08
0.07
f '
31
38
44
2.54
2.06
1.37
0.99
0.77
0.59
0.49
0.40
0.29
0.17
0.11
32
-------
45
51
25.
259.32
26.75
31.58
319.24
50.
112.28
9.11
11.69
120.82
100.
41.30
2 . 79
3.84
40.21
200.
13.61
0.79
1.14
12.13
300.
6.94
0.37
0.55
5.87
400.
4 .21
0.21
0.33
3.34
500.
2.87
0. 14
0.22
2.14
600.
2.10
0.10
0.16
1.52
700.
1.63
0.08
0.12
1.15
800.
1.31
0.06
0.10
0.89
900.
1.06
0.05
0.08
0.71
1000
0.89
0.04
46
52
00 296.
625.57
62 31
56.67
571.39
00 128.
306.99
23.20
22.73
230.17
00 47.
128.15
7.64
7.84
81.73
00 15.
46.71
2.28
2.45
26.18
00 7.
25.00
1.11
1.22
12.86
00 4.
15.67
0.65
0.72
7.27
00 3.
10.90
0.44
0.49
4.74
00 2.
8.11
0.31
0.35
3.41
00 1.
6.36
0.24
0.27
2.57
00 1.
5.15
0.19
0.22
1.96
.00 1.
4.18
0.15
0.18
1.62
.00 1,
3.47
0.13
47
53
96 711.
29.74
114.26
37.85
895.39
40 349.
10.14
45.61
15.15
375.41
37 146.
3.10
15.74
5.23
145.17
64 53.
0.88
4.93
1.63
50.96
95 28.
0.41
2.44
0.81
24.58
84 18.
0.24
1.46
0.48
14.90
30 12.
0. 16
0.98
0.33
10.09
41 9.
0.11
0.71
0.24
7.29
87 7.
0.08
0.55
0. 18
5.40
50 5.
0.07
0.44
0.15
4.39
.21 4.
0.05
0.35
0.12
3.48
.02 3,
0.04
0.29
48
54
41
69.45
207.36
28.62
1233.92
84
25.79
89.35
11.39
560.27
46
8.49
32.89
3.93
256.16
81
2.53
10.83
1.23
95.44
82
1.23
5.53
0.61
56.14
04
0.72
3.35
0.36
37.29
59
0.48
2.28
0.24
27.29
35
0.35
1.67
0.18
20.97
34
0.27
1.30
0.14
16.28
80
0.21
1.04
0.11
13.41
.53
0.17
0.84
0.09
10.91
.80
0.14
0.71
49
33.45
126.67
39.00
64.99
11.42
50.84
14.49
20.21
3.49
17.49
4.77
5.81
0.99
5.46
1.42
1.58
0.47
2.71
0.69
0.73
0.27
1.62
0.41
0.42
0.18
1.09
0.27
0.26
0.12
0.79
0.20
0.18
0.10
0.61
0.15
0.14
0.08
0.49
0.12
0.10
0.06
0.39
0.10
0.08
0.05
0.33
0.08
50
78.03
230.70
70.96
133.02
29.07
99.59
28.45
45.47
9.54
36.60
9.81
13.95
2.85
12.06
3.07
3.95
1.38
6.12
1.52
1.86
0.81
3.73
0.91
1.07
0.54
2.55
0.61
0.69
0.39
1.86
0.44
0.47
0.30
1.45
0.34
0.36
0.24
1.16
0.27
0.28
0.19
0.94
0.22
0.22
,0.16
0.79
0.18
142.85
19.
6.17
3.06
1.82
1.23
0.89
0.69
0.55
0.44
0.37
-------
0.06
0.59
0.61
0.03
0.04
0.38
0.44
0.02
0.03
0.27
0.33
0.01
0.02
0.20
0.26
0.01
0.02
0.16
0.21
0.01
0.02
0.13
0.17
0.01
0.01
0.11
0.12
0.01
0.01
0.08
0.08
0.00
0.01
0.05
0.05
0.00
0.00
0.03
0.15
1.30
1250.00
2.27
0.09
0.10
0.85
1500.00
1.63
0.06
0.07
0.62
1750.00
1.23
0.05
0.06
0.47
2000.00
0.96
0.04
0.04
0.36
2250.00
0.80
0.03
0.04
0.30
2500.00
0.66
0.03
0.03
0.24
3000.00
0.49
0.02
0.02
0.17
4000. 00
0.30
0.01
0.01
0.10
5000.00
0.20
0.01
0.01
0.07
0.10
2.96
0.67
0.03
0.20
0.07
1.98
0.48
0.02
0.15
0.05
1.40
0.37
0.02
0.11
0.04
1.05
0.28
0.01
0.09
0.03
0.84
0.23
0.01
0.07
0.02
0.66
0.19
0.01
0.06
0.02
0.56
0.14
0.01
0.04
0.02
0.39
0.09
0.00
0.03
0.01
0.23
0.06
0.00
0.02
0.01
0.15
0.07
9.33
2.50
0.09
0.48
0.05
6.36
1.81
0.07
0.36
0.04
4.52
1.35
0.05
0.28
0.03
3.48
1.09
0.04
0.22
0.02
2.71
0.88
0.03
0.18
0.02
2.20
0.74
0.03
0.15
0.02
1.77
0.54
0.02
0.11
0.01
1.25
0.33
0.01
0.06
0.01
0.70
0.23
0.01
0.04
0.00
0.45
0.07
0.03
0.22
0.05
0.04
0.02
0.16
0.04
0.03
0.02
0.13
0.03
0.02
0.01
0.10
0.02
0.02
0.01
0.08
0.02
0.01
0.01
0.07
0.02
0.01
0.01
0.05
0.01
0.01
0.00
0.03
0.01
0.01
0.00
0.02
0.00
0.00
0.18
0.11
0.54
0.12
0.12
0.08
0.40
0.09
0.09
0.06
0.30
0.07
0.06
0.05
0.24
0.06
0.05
0.04
0.19
0.05
0.04
0.03
0.16
0.04
0.03
0.02
0.11
0.03
0.02
0.01
0.07
0.02
0.01
0.01
0.05
0.01
0.01
0.25
0.14
0.11
0.09
0.07
0.05
0. 03
0.02
X,m Max concentration, ppm
25.00
50.00
100.00
200.00
300.00
400.00
500.00
600.00
700.00
800.00
900.00
1277.30
580.01
256.16
99.28
56.14
37.29
27.29
20.97
16.28
13.41
10.91
-------
1000.00
1250.00
1500.00
1750.00
2000.00
2250.00
2500.00
3000.00
4000.00
5000.00
9.33
6.36
4.52
3.48
2.71
2.20
1.77
1.25
0.70
0.45
Concentration (ppm)
Distance to (m)
LOG
IDLH
9.6000
19.6000
982.84
629.22
-------
From Slab
output file:
Scenario :
Accident Location:
Duration :
Meteorology:
Chemical :
Vapor phase mole fraction:
X,m
25.00
50.00
100.00
200.00
300.00
400.00
500.00
600.00
700.00
800.00
900.00
1000.00
1250.00
1500.00
1750.00
2000.00
2250.00
2500.00
3000/00
4000.00
5000.00
Concentration
LOG
IDLH 1
LOC:
IDLH:
Max concentration, ppm
1132.95
551.02
276.38
140.33
93.92
70.02
54.66
43.99
35.98
29.97
25.50
21.62
15.31
11.40
8.78
6.86
5.53
4 .56
3.18
1 .80
1.13
(ppm) Distance to
9.6000 1672.
9.6000 1080.
RUN 6 9. OUT
TYPICAL
OFFSITE
UNMITIG
INVERSN
FORMALDEHYDE
0.477
9.600
19.600
(m)
05
08
-------
From Slab output file:
Scenario:
Accident Location:
Duration:
Meteorology:
Chemical:
Vapor phase mole fraction:
LOG:
IDLH:
RUN70.0UT
TYPICAL
OFFSITE
UNMITIG
TYPICAL
ACETONE
0.420
1960.000
2442.000
X,m Max concentration, ppm
25.00
50.00
100.00
200.00
300.00
400.00
500.00
600.00
700.00
800.00
900.00
1000.00
1250.00
1500.00
1750.00
' 2000.00
2250.00
2500.00
3000.00
4000.00
5000.00
75
29
9
3
1
0
0
0
- 0
0
0
0
0
0
0
0
0
0
0
0
0
.89
.40
.94
.07
.51
.89
.60
.43
.33
.26
.21
.18
.12
.09
.07
.05
.04
.04
.03
.02
.01
Concentration (ppm)
LOC
IDLH
1960.0000
2442.0000
Distance to (m)
less than
less than
25.00
25.00
-------
From Slab output file:
Scenario:
Accident Location:
Duration :
Meteorology:
Chemical :
Vapor phase mole fraction:
LOG:
IDLH:
X,m 1
678
12 13 14
18 19 20
24 25 26
25.00 17.28
349.62 12.94 27.11
365.76 10.38 21.73
357.63 8.64 18.09
330.39 15.52 37.28
50.00 5.30
160.48 3.97 , 9.05
163.54 3.18 7.22
161.86 2.65 6.02
152.52 5.17 13.35
100.00 1.50
73.50 1.13 2.72
71.26 0.90 2.18
68.32 0.75 1.82
63.14 1.55 4.25
200.00 0.40
32.15 0.30 0.76
29.18 0.24 0.61
26.42 0.20 0.51
23.67 0.43 1.26
300.00 0.19
19.16 0.14 0.36
16.72 0.11 0.29
14.68 0.09 0.24
12.88 0.20 0.61
400.00 0.11
12.95 0.08 0.20
10.95 0.06 0.16
9.42 0.05 0.14
8.14 0.12 0.36
500.00 0.07
9.50 0.05 0.13
7.89 0.04 0.11
6.69 0.03 0.09
5.70 0.08 0.24
600.00 0.05
7.32 0.04 0.10
5.99 ' 0.03 0.08
4.99 0.02 0.06
4.24 0.05 0.17
700.00 0.04
5.90 0.03 0.07
4.76 0.02 0.06
3.95 0.02 0.05
3.35 0.04 0.13
800.00 0.03
4.65 0.02 0.06
RUN 71. OUT
TYPICAL
OFFSITE
UNMITIG
WORST
ACETONE
0.420
1960.000
2442.000
2 3
9 10
15 16
21 22
27
36.12 90.35
66.71 124.42
52.62 98.31
43.50 81.27
69.26
12.00 33.14
24.23 48.98
19.02 38.38
15.66 31.53
26.72
3.63 10.74
7.81 16.74
6.10 13.09
5.01 10.68
9.04
1.01 3.17
2.30 5.17
1.80 4.03
1.48 3.29
2.78
0.48 1.52
1.11 2.54
0.87 1.98
0.71 1.62
1.37
0.27 0.89
0.65 1.50
0.51 1.17
0.42 0.96
0.81
0.18 0.59
0.43 1.01
0.34 0.79
0.28 0.65
0.54
0.13 0.42
0.31 0.72
0.24 0.56
0.20 0.46
0.39
0.10 0.32
0.24 0.55
0.19 0.43
0.15 0.36
0.30
0.08 0.26
0.19 0.44
4
11
17
23
165.04 257.
217.09
178.12
149.04
64.32 105.
91.06
75.32
62.56
22.19 40.
33.63
27.61
22.86
6.94 13.
11.20
9.04
7.46
3.43 7.
5.70
4.59
3.77
2.03 4.
3.46
2.76
2.27
1.37 3.
2.36
1.88
1.54
0.98 2.
1.72
1.36
1.12
0.76 1.
1.33
1.05
> 0.87
0.60 1.
1.07
^J
21
54
15
99
33
53
11
28
77
42
-------
3.91
3.22
2.72
3.56
3.22
2.64
2.22
3.00
2.75
2.25
1.89
2.02
1.78
1.57
1.31
1.47
1.25
1.17
0.97
1.10
0.94
0.87
0.76
0.88
0.71
0.65
0.60
0.71
0.59
0.52
0.46
0.59
0.47
0.42
0.38
0.43
0.35
0.30
0.27
0.25
0.21
0.18
0.16
0.17
0.14
0.12
0.11
33
39
0.
0.
0.
900.00
0.
0.
0.
0.
1000.00
0.
0.
0.
0.
1250.00
0.
0.
0.
0.
1500.00
0.
0.
0.
0.
1750.00
0.
0.
0.
0.
2000.00
0.
0.
0.
0.
2250.00
0.
0.
0.
0.
2500.00
0.
0.
0.
0.
3000.00
0.
0.
0.
0.
4000.00
0.
0.
0.
0.
5000.00
0.
0.
0.
0.
X,m
34
40
02
01
03
02
01
01
03
01
01
01
02
01
01
01
01
01
01
00
01
01
00
00
01
00
00
00
01
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
0.
0.
0.
0.02
0.
0.
0.
0.
0.02
0.
0.
0.
0.
0.01
0.
0.
0.
0.
0.01
0.
0.
0.
0.
0.01
0.
0.
0.
0.
0.01
0.
0.
0.
0.
0.00
0.
0.
0.
0.
0.00
0.
0.
0.
0.
0.00
0.
0.
0.
0.
0.00
0.
0.
0.
0.
0.00
0.
0.
0.
0.
28
35
41
05
04
10
05
04
03
08
04
03
03
07
03
02
02
05
02
01
01
03
01
01
01
03
01
01
01
02
01
01
01
02
01
01
00
01
01
00
00
01
00
00
00
01
00
00
00
00
0.
0.
0.
0.06
0.
0.
0.
0.
0.05
0.
0.
0.
0.
0.03
0.
0.
0.
0.
0.02
0.
0.
0.
0.
0.02
0.
0.
0.
0.
0.01
0.
0.
0.
0.
0.01
0.
0.
0.
0.
0.01
0.
0.
0 .
0.
0.01
0.
0.
0.
0.
0.00
0.
0.
0.
0.
0.00
0.
0.
0.
0.
29
36
42
15
12
24
0.
0.
35
28
0.20
15
12
10
19
12
10
08
16
08
07
05
11
06
05
04
08
05
04
03
06
04
03
02
05
03
02
02
04
02
02
02
03
02
01
01
02
01
01
01
02
01
01
00
01
0.17
0.11
0.08
0.06
0.05
0.04
0.03
0.02
0.01
0.01
30
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
37
43
35
28
23
29
23
19
20
16
13
14
11
09
11
09
07
09
07
06
07
06
05
06
05
04
04
03
03
02
02
02
02
01
01
0.
0.
0.48
0.
0.
0.
0.40
0.
0.
0.
0.27
0.
0.
0.
0.19
0.
0.
0.
0.14
0.
0.
0.
0.11
0.
0.
0.
0.09
0.
0.
0.
0.07
0.
0.
0.
0.05
0.
0.
0.
0.03
0.
0.
0.
0.02
0.
0.
0.
,
'' 31
38
44
84
69
86
68
56
72
57
47
49
39
32
36
28
23
28
22
18
22
17
14
17
14
12
14
12
10
10
08
07
06
05
04
04
03
03
1.15
0.97
0.66
0.45
0.33
0.25
0.21
0.17
0.12
0.07
0.05
32
-------
45
51
25
111.25
10.84
13.13
133.78
50
46.40
3.62
4.69
47.78
100
16.72
1.09
1.50
15.71
200
5.42
0.30
0.44
4 .75
300
2.74
0.14
0.21
2.31
400
1.65
0.08
0.12
1.36
500
1.13
0.05
0.08
0.91
600
0.82
0.04
0.06
0.65
700
0.63
0.03
0.05
0.50
800
0.51
0.02
0.04
0.39
900
0.41
0.02
0.03
0.31
1000
0.34
0.02
46
52
.00
266.93
25.97
23.93
209.29
.00
126.56
9.26
9.16
80.08
.00
51.66
2.97
3.06
29.02
.00
18.78
0.88
0.94
9.66
.00
10.01
0.42
0.46
4.93
.00
6.25
0.25
0.28
2.99
.00
4.35
0.17
0.19
2.04
.00
3.22
0.12
0.13
1.47
.00
2.52
0.09
0. 10
1.14
.00
2.04
0.07
0.08
0.91
.00
1.66
0.06
0.07
0.72
.00
1.41
0.05
47
53
127.44 297
12.05
48.10
16.09
260.94
53.22 139
4.02
18.45
6.14
110.52
19.36 57
1.21
6.22
2.05
45.78
6.31 21
0.34
1.91
0.63
17.60
3.18 11
0.16
0.94
0.31
9.70
1.92 7
0.09
0.56
0.18
6.19
1.30 4
0.06
0.38
0.12
4.35
0.95 3
0.04
0.27
0.09
3.25
0.73 2
0.03
0.21
0.07
2.55
0.59 2
0.03
0.17
0.06
1.98
0.47 1
0.02
0.13
0,04
1.51
0.40 1
0.02
0.11
48
54
.66
28.87
88.83
12.02
390.60
.76
10.32
36.74
4.60
172.79
.26
3.30
13.16
1.53
79.01
.08
0.97
4.27
0.47
35.65
.32
0.47
2.15
0.23
22.12
.10
0.28
1.30
0.14
15.31
.96
0.18
0.89
0.09
10.19
.68
0.13
0.64
0.07
7.57
.89
0.10
0.50
0.05
5.92
.34
0.08
0.40
0.04
4.87
.91
0.06
0.32
'0.03
3.98
.61
0.05
0.27
49
13.57
53.48
16.44
25.63
4.53
20.58
5.84
7.91
1.36
6.92
1.87
2.25
0.38
2.13
0.55
0.61
0.18
1.05
0.26
0.28
0.10
0.62
0.16
0.16
0.07
0.42
0.10
0.10
0.05
0.30
0.07
0.07
0.04
0.23
0.06
0.06
0.03
0.19
0.05
0.04
0.02
0.15
0.04
0.03
0.02
0.12
0.03
50
32.52
98.78
29.94
55.87
11.65
41.00
11.46
18.41
3.70
14.70
3.83
5.52
1.09
4.77
1.18
1.54
0.53
2.41
0.58
0.72
0.31
1.45
0.35
0.42
0.21
0.99
0.23
0.27
0.15
0.72
0.17
0.19
0.11
0.56
0.13
0.15
0.09
0.45
0.10
0.12
0.07
0.36
0.08
0.09
0,.-06
0.30
0.07
60.54
2.41
1.19
0.70
0.47
0.34
0.26
0.21
0.17
0.14
-------
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.02
.26
.23
.01
.02
.16
.17
.01
.01
.11
.13
.01
.01
.08
.11
.00
.01
.06
.09
.00
.01
.05
.07
.00
.00
.04
.05
.00
.00
.03
.03
.00
.00
.02
.02
.00
.00
.01
0
0
1250.00
0
0
0
0
1500.00
0
0
0
0
1750.00
0
0
0
0
2000.00
0
0
0
0
2250.00
0
0
0
0
2500.00
0
0
0
0
3000.00
0
0
0
0
4000.00
0
0
0
0
5000.00
0
0
0
0
.06
.59
.97
.03
.04
.37
.72
.02
.03
.26
.57
.02
.02
.19
.45
.01
.02
.15
.37
.01
.01
.12
.32
.01
.01
.10
.23
.01
.01
.07
.13
.00
.01
.04
.09
,00
.00
.03
0
J_
0.27
0
0
0
0
0.20
0
0
0
0
0.15
0
0
0
0
0.12
0
0
0
0
0.10
0
0
0
0
0.08
0
0
0
0
0.06
0
0
0
0
0.04
0
0
0
0
0.02
0
0
0
0
.04
.25
.01
.08
.03
.82
.01
.05
.02
.59
.01
.04
.01
.44
.00
.03
.01
.35
.00
.03
.01
.28
.00
.02
.01
.23
.00
.02
.01
.16
.00
.01
.00
.10
.00
.01
.00
.06
0
3
1.12
0
0
0
2
0.83
0
0
0
1
0.65
0
0
0
1
0.52
0
0
0
1
0.43
0
0
0
0
0.35
0
0
0
0
0.24
0
0
0
0
0.14
0
0
0
0
0.10
0
0
0
0
.03
.44
.04
.19
.02
.39
.03
.14
.01
.76
.02
.11
.01
.33
.02
.08
.01
.08
.01
.07
.01
.86
.01
.06
.01
.73
.01
.04
.00
.52
.00
.03
.00
.30
.00
.02
.00
.20
0.
0.01
0.
0.
0.
0.01
0.
0.
0.
0.01
0.
0.
0.
0.01
0.
0.
0.
0.00
0.
0.
0.
0.00
0.
0.
0.
0.00
0.
0.
0.
0.00
0.
0.
0.
0.00
0.
0.
0.
03
08
02
02
06
01
01
05
01
01
04
01
01
03
01
01
03
01
00
02
00
00
01
00
00
01
00
00
0
0.04
0
0
0
0.03
0
0
0
0.02
0
0
0
0.02
0
0
0
0.01
0
0
0
0.01
0
0
0
0.01
0
0
0
0.01
0
0
0
0.00
0
0
0
.08
.21
.05
.05
.15
.03
.04
.12
.03
.03
.09
.02
.02
.08
.02
.02
.07
.01
.01
.05
.01
.01
.03
.01
.01
.02
.00
.00
0.10
0.0"
0.05
0.04
0.03
0.03
0.02
0.01
0.01
X,m Max concentration, ppm
25.00
50.00
100.00
200.00
300.00
400.00
500.00
600.00
700.00
800.00
900.00
390.60
172.79
79.01
35.65
22.12
15.31
10.19
7.57
5.92
4.87
3.98
-------
1000.00 3.44
1250.00 2.39
1500.00 1.76
1750.00 1.33
2000.00 1.08
2250.00 0.86
2500.00 0.73
3000.00 0.52
4000.00 0.30
5000.00 0.20
Concentration (ppm) Distance to (m)
LOG 1960.0000 less than 25.00
IDLH 2442.0000 less than 25.00
-------
From Slab output file:
Scenario:
Accident Location:
Duration:
Meteorology:
Chemical:
Vapor phase mole fraction:
LOG:
IDLH:
RUN72a.OUT
TYPICAL
OFFSITE
UNMITIG
INVERSN
ACETONE
0.445
1960.000
2442.000
X,m Max concentration, ppm
25.00
50.00
100.00
200.00
300.00
400.00
500.00
600.00
700.00
800.00
900.00
1000.00
1250.00
1500.00
1750.00
2000.00
2250.00
2500.00
3000.00
4000.00
5000.00
332.68
153.15
70.83
34.35
22.87
16.84
13.26
10.81
9.10
7.73
6.67
5.84
4.31
3.29
2.59
2.13
1.75
1.48
1.08
0.63
0.41
Concentration (ppm)
Distance to (m)
LOG
IDLH
1960.0000
2442.0000
less than
less than
25.00
25.00
-------
From Slab output file:
Scenario:
Accident Location:
Duration:
Meteorology:
Chemical:
Vapor phase mole fraction:
LOG:
IDLH:
RUN72b.OUT
TYPICAL
OFFSITE
UNMITIG
INVERSN
ACETONE
0.101
1960.000
2442.000
X,m Max concentration, ppm
25.00
50.00
100.00
200.00
300.00
400.00
500.00
600.00
700.00
800.00
900.00
1000.00
1250.00
1500.00
1750.00
2000.00
2250.00
2500.00
3000.00
4000.00
5000.00
17.25
10.53
6.49
3.90
2.82
2.22
1.82
1.52
1.30
1.13
1.00
0.89
0.69
0.56
0.47
0.39
0.34
0.29
0.22
0.14
0.09
Concentration (ppm)
Distance to (m)
LOG
IDLH
1960.0000
2442.0000
less than
less than
25.00
25.00
-------
ATTACHMENT 4
ISC-COMPDEP Outputs Using Screening Meteorological Conditions
-------
A. On-Site Fire Scenario
-------
CO STARTING
TITLEONE
TITLETWO
MOOELOPT
AVERT I ME
POUUTID
TERRHGTS
ELEVUNIT
RUNORNOT
ERRORFIL
CO FINISHED
UTI Storage Tank Rupture, Screen Modeling ONSITE ORG. TANK
1 Point sourrc; 26 receptors up to 50KM away; Vapor.
NOSTO GRDRIS RURAL CONC
1
Fugitive
ELEV
METERS
RUN
ONSITE.ERR
SO STARTING
LOCATION ONSITE POINT
* Point Source OS
186.385 105.445 212.1
HS TS VS DS
SO SRCPARAM ONSITE 1.0 23.0 997. 0.225 15.14
** SO SRCPARAM ONSITE 1.0 23.0 997. 0.075 26
SO BUILDHGT ONSITE 17.37 17.37 17.37 17.37
SO BUILDHGT ONSITE 17.37 17.37 17.37 17.37
SO BUILDHGT
SO BUILDHGT
SO BUILDHGT
SO BUILDHGT
SO BUILDU1D
SO BUILDUID
SO BUILOUID
SO BUILDUID
SO BUILDUID
SO BUILDWID
SO SRCGROUP
SO FINISHED
RE STARTING
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
R£ DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
ONSITE 17.37
ONSITE 17.37
ONSITE 17.37
ONSITE 17.37
ONSITE 18.23
ONSITE 18.23
ONSITE 18.23
ONSITE 18.23
ONSITE 18.23
ONSITE 18.23
ALL
100.00000
200.00000
300.00000
400.00000
500.00000
600.00000
700.00000
800.00000
900.00000
1000.00000
1250.00000
1500.00000
1750.00000
2000.00000
2250.00000
2500.00000
3000.00000
4000.00000
5000.00000
7500.00000
10000.00000
15000.00000
20000.00000
30000.00000
40000.00000
50000.00000
17.37
17.37
17.37
17.37
18.23
18.23
18.23
16.23
18.23
18.23
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
o.ooocc
0.00000
17.37 17.37
17.37 17.37
17.37 17.37
17.37 17.37
18.23 18.23
18.23 18.23
18.23 18.23
18.23 18.23
18.23 18.23
18.23 18.23
213.4
225.6
231.6
231.6
268.2
304.8
323.1
353.
353.
353.
359.
365.
365.
371.9
384.0
384.0
408.4
420.6
415.4
408.4
426.7
420.0
420.0
420.0
420.0
420.0
.22
17.37 17.37
17.37 17.37
17.37 17.37
17.37 17.37
17.37 17.37
17.37 17.37
18.23 18.23
18.23 18.23
18.23 18.23
18.73 18.23
18.23 18.23
18.23 18.23
-------
RE FINISHED
ME STARTING
ME INPUTFIL SCREEN.NET
ME ANEMHGHT 10.0 METERS
ME SURFDATA 94823 1993
ME UAIRDATA 94823 1993
** ME PROFFILE TEMPS ISC_TEMP.STK
* ME PROF FILE VINOS ISC_WIND.STK
* DAYRANGE 1/3
ME FINISHED
TG STARTING
** INPUTFIL wti100k.out
LOCATION 538.4 4497.8 Ion
TG FINISHED
OU STARTING
RECTABLE ALLAVE FIRST-SECOND
DATTABLE ALLAVE
MAXTABLE ALLAVE 50
** MAXIFILE 3 ALL 30.0 NAXIALL.FIL 25
MAXIFILE 24 ALL 10.0 MAXIALL.FIL 25
» POSTFILE 1 ALL INDIV POST2C.BIN 20
* POSTFILE PERIOD ALL PLOT PSTANALL.FIL 21
*" Note that the following two input cards generate PLOTFILEs with the file
** unit dynamically allocated by the ISCST2 program. Uhen porting the model
** to another computer system, the user may need to specify the file units
* as is done on the previous four input cards.
* PLOTFILE 3 ALL 2ND PLT03ALL.FIL
* PLOTFILE 24 ALL 2ND PLT24ALL.FIL
OU PLOTFILE 1 ALL 1ST ONSITE.PL1
OU PLOTFILE 1 ALL 1ST ONSITE.PLT
OU FINISHED
SETUP Finishes Successfully
-------
* ISCOMDEP VERSION 94227 * WTI Storage Tank Rupture, Screen Modeling -- ONSITE ORC. TANK « 05
* 1 Point source; 26 receptors up to 50KM away; Vapor. »« 11
PA
*** MODELING OPTIONS USED: CONC RURAL ELEV GRDRIS NOSTD
* MODEL SETUP OPTIONS SUMMARY *
*Intermediate Terrain Processing is Selected
Model Is Setup For Calculation of Average Concentration Values.
-- SCAVENGING/DEPOSITION LOGIC --
Model Uses NO DRY DEPLETION. DDPLETE * F
Model Uses NO WET DEPLETION. WDPLETE * F
NO WET SCAVENGING Data Provided.
Model Does NOT Use GRIDDED TERRAIN Data for Depletion Calculations
Model Uses RURAL Dispersion. -
Model Uses User-Specified Options:
1. Gradual Plume Rise.
2. Not Use Stack-tip Downwash.
3. Buoyancy-induced Dispersion.
4. Calms Processing Routine.
5. Not Use Missing Data Processing Routine.
6. Default Wind Profile Exponents.
7. Default Vertical Potential TeMperature Gradients.
"Model Accepts Receptors on ELEV Terrain.
Model Assumes No FLAGPOLE Receptor Heights.
Model Calculates 1 Short Tem Average(s) of: 1-HR
This Run Includes: 1 Source(s); 1 Source Group(s); and 26 Receptor(s)
The Model Assumes A Pollutant Type of: FUGITIVE
Model Set To Continue RUNning After the Setup Testing.
Output Options Selected:
Model Outputs Tables of Highest Short Ten* Values by Receptor (RECTABLE Keyword)
Model Outputs Tables of Overall Maxinjn Short Term Values (MAXTABLE Keyword)
Model Outputs Tables of Concurrent Short Tern Values by Receptor for Each Day Processed (DAYTABLE Keyword)
Model Outputs External File(s) of High Values for Plotting (PLOTFILE Keyword)
NOTE: The Following Flags May Appear Following CONC Values: c for Calm Hours
for Missing Hours
b for loth Calm and Missing Hours
Misc. Inputs: Arum. Hgt. <) » 10.00 ; Decay Coef. - 0.0000 ; Rot. Angle * 0.0
Emission Units « GRAMS/SEC ; Emission Rate Unit Factor « 0.10000E+07
Output Units « NICXOGRAMS/M**3
Input Runstream File: ONSITE.INC ; Output Print File: ONSITE.OUT
Detailed Error/Message File: ONSITE.ERR
-------
*** ISCONDEP VERSION 94227 ** WTI Storage Tank Rupture, Screen Modeling -- OMSITE ORG. TANK * 05
* 1 Point source; 26 receptors up to 50KM away; Vapor. *** 11
PA
*** MODELING OPTIONS USED: CONC RURAL ELEV GRDRIS NOSTD
* POINT SOURCE DATA **
NUNBER EMISSION RATE BASE STACK STACK STACK STACK BUILDING EMISSION RATE
SOURCE PART. (GRAMS/SEC) X Y ELEV. HEIGHT TEMP. EXIT VEL. DIAMETER EXISTS SCALAR VARY
ID CATS. (METERS) (METERS) (METERS) (METERS) (DEG.K) (M/SEC) (METERS) BY
ONSITE 0 0.10000E+01 186.4 105.4 212.1 23.00 997.00 0.22 15.14 YES
-------
ISCONDEP VERSION 94227 * UTI Storage Tank Rupture, Screen Modeling -- ONSITE ORG. TANK * 05
** 1 Point source; 26 receptors up to 50KH auay; Vapor. *** 11
PA
MODELING OPTIONS USED: CONC RURAL ELEV GRORIS HOSTD
* SOURCE IDs DEFINING SOURCE GROUPS
GROUP ID SOURCE IDs
ALL ONSITE .
-------
1SCOMDEP VERSION 94227 ** " WTI Storage Tank Rupture, Screen Modeling -- ONSITE ORG. TANK * Ob
* 1 Point source; 26 receptors up to 50KM away; Vapor. ** 11
PA
MODELING OPTIONS USED: CONC RURAL ELEV GRDRIS HOSTD
* SOURCE PARTICULATE/GAS DATA "**
* SOURCE ID * ONSITE ; SOURCE TYPE = POINT ***
SCAV COEF [LIQ] 1/(S-MM/HR)=
O.OOE+00,
SCAV COEF tICE] 1/-
O.OOE+00.
-------
ISCOMDEP VERSION 94227
** UTl Storage Tank Ripture, Screen Modeling -- ONSITE ORG. TANK
*** 1 Point source; 26 receptors i*> to 50KM away; Vapor.
** MODELING OPTIONS USED: CONC RURAL ELEV
GRDRIS NOSTD
05
11
PA
DIRECTION SPECIFIC BUILDING DIMENSIONS
SOURCE ID: ONSITE
IFV BH
BW UAK IFV BH
BW UAK IFV BN
BW IMJC IFV BN
BW UAK IFV BH
BW UAK IFV BH
1 17.4.
7 17.4.
13 17.4,
19 17.4,
25 17.4,
31 17.4,
18.2, 0
18.2, 0
18.2, 0
18.2. 0
18.2, 0
18.2, 0
2 17.4,
8 17.4,
14 17.4,
20 17.4.
26 17.4,
32 17.4,
18.2, 0
18.2, 0
18.2, 0
18.2. 0
18.2, 0
18.2, 0
3 17.4,
9 17.4,
15 17.4,
21 17.4,
27 17.4,
33 17.4,
18.2, 0
18.2, 0
18.2, 0
18.2, 0
18.2, 0
18.2, 0
4
10
16
22
28
34
17.4,
17.4,
17.4,
17.4,
17.4,
17.4,
18.2, 0
18.2, 0
18.2, 0
18.2. 0
18.2. 0
18.2, 0
5 17.4,
11 17.4,
17 17.4,
23 17.4,
29 17.4,
35 17.4,
18.2, 0
18.2, 0
18.2, 0
18.2. 0
18.2, 0
18.2, 0
6 17.4.
12 17.4,
18 17.4.
24 17.4,
30 17.4,
36 17.4.
-------
ISCOMDEP VERSION 94227
UTI Storage Tank Rupture. Screen Modeling -- ONSITE ORG.
1 Point source; 26 receptor* up to 50KM away; Vapor.
MODEL!NG OPTIONS USED: CONC RURAL ELEV
GRDRIS NOSTD
TANK
t..
11
PA
* DISCRETE CARTESIAN RECEPTORS "
(X-COORD, Y-COORD, ZELEV, ZFLAG)
(METERS)
( 100.0,
( 300.0,
( 500.0,
( 700.0,
( 900.0,
( 1250.0,
( 1750.0,
( 2250.0,
( 3000.0,
( 5000.0,
( 10000.0,
( 20000.0,
( 40000.0.
0.0.
0.0,
0.0,
0.0.
0.0,
0.0.
0.0.
0.0.
0.0.
0.0,
0.0.
0.0.
o.o.
213.4,
231.6,
268.2,
323.1,
353.6,
359.7.
365.8,
384.0,
-408.4,
415.4,
426.7,
420.0,
420.0,
0.0);
0.0);
0.0);
0.0);
0.0);
0.0);
0.0);
0.0);
0.0);
0.0);
0.0);
0.0);
0.0);
( 200.0,
( 400.0,
( 600.0.
( 800.0,
( 1000.0,
( 1500.0,
( 2000.0,
( 2500.0,
( 4000.0,
( 7500.0,
( 15000.0.
( 30000.0,
( 50000.0,
o.o.
o.o.
o.o.
0.0,
o.o.
0.0,
0.0,
o.o,
o.o,
o.o,
o.o,
0.0.
o.o.
225.6,
231.6,
304.8,
353.6,
353.6,
365.8,
371.9,
384.0,
420.6,
408.4,
420.0,
420.0,
420.0,
0.0);
0.0);
0.0);
0.0);
0.0);
0.0);
0.0);
0.0);
0.0);
0.0);
0.0);
0.0);
0.0);
-------
ISCQMDEP VERSION 94227
VTI Storage Tank Ripture, Screen Modeling -- ONSITE ORG. TANK
1 Point source; 26 receptors up to SOOt away; Vapor.
MODELING OPTIONS USED: CONC RURAL ELEV
GRDRIS NOSTD
05
11
PA
METEOROLOGICAL DAYS SELECTED FOR PROCESSING
(1«YES; 0-NO)
1111111111 1111111111
1111111111 1111111111
1111111111 1111111111
1111111111 1111111111
1111111111 1111111111
1111111111 1111111111
1111111111 1111111111
1111111111 111111
1111
1111
1111
1111
1111
1111
1111
11111
11111
11111
11111
11111
11111
11111
1 1
1 1
1 1
1 1
1 1
1 1
1 1
1 1 1
1 1 1
1 1 1
1 1 1
1 1 1
1 1 1
1 1 1
1111
1111
1111
1111
1111
1111
1111
1
1
1
1
1
1
1
1111
1 ; 1 1
1111
1111
1111
1111
1111
1
1
1
1
1
1
1
1
1
1
1
1
1
1
i 1
1 1
1 1
1 1
i 1
1 i
1 1
1 1
1 ;
1 1
1 1
1 1
1 1
1 1
NOTE: METEOROLOGICAL DATA ACTUALLY PROCESSED HILL ALSO DEPEND ON WHAT IS INCLUDED IN THE DATA FILE.
UPPER BOUND OF FIRST THROUGH FIFTH WIND SPEED CATEGORIES
(METERS/SEC)
1.54. 3.09. 5.U, 8.23, 10.80.
WIND PROFILE EXPONENTS
STABILITY
CATEGORY
A
B
C
D
E
F
WIND SPEED CATEGORY
1
.70000E-01
.7DOOOE-01
.100006*00
.150006*00
.350006*00
.55000E+00
2
.70000E-01
.7DOOOE-01
.10000E+00
.150006*00
.350006*00
.550006*00
3
.7DOOOE-01
.700006-01
.100006*00
.150006+00
.350006*00
.550006*00
4
.70000E-01
.700006-01
.100006*00
.150006*00
.350006*00
.550006*00
5
.70000E-01
.70000E-01
.10000E+00
.150006*00
.350006*00
.550006*00
6
.70000E-01
.700006-01
.100006*00
. 15000E+00
.350006*00
.550006*00
VERTICAL POTENTIAL TEMPERATURE GRADIENTS
(DEGREES KELVIN PER METER)
STABILITY
CATEGORY
A
B
C
D
E
F
WIND SPEED CATEGORY
1
.000006*00
.000006*00
.000006*00
.000006*00
.200006-01
.350006-01
2
.000006*00
.000006*00
.000006*00
.000006*00
.200006-01
.350006-01
3
.000006*00
.000006*00
.000006*00
.000006*00
.200006-01
.350006-01
4
.000006*00
.000006*00
.000006*00
.000006*00
.200006-01
.350006-01
5
.000006*00
.000006*00
.000006*00
.000006*00
.200006-01
.350006-01
6
.000006*00
.000006*00
.000006*00
.000006*00
.200006-01
.350006-01
-------
ISCONDEP VERSION 94227
UTI Storage Tank Rupture, Screen Modeling -- ONSITE ORC.
1 Point source; 26 receptors up to 50KM away; Vapor.
TANK
MODELING OPTIONS USED: CONC RURAL ELEV
GRDRIS NOSTD
Oi
11
PA
THE FIRST 24 HOURS OF METEOROLOGICAL DATA
FILE: SCREEN.NET
SURFACE STATION NO.: 94823
YEAR: 1993
FORMAT: (4I2.2F9.4,F6.1.I2,2F7.1,f9.4,f10.1,f8.4,f5.1.»4.f7.2>
UPPER AIR STATION NO.: 94823
NAME: UNKNOWN
TEAR: 1993
TEAR MONTH
93 1
93 1
93 1
93 1
93 1
93 1
93 1
93 1
93 1
93 1
93 1
93 1
93 1
93 1
93 1
93 1
93 1
93 1
93 1
93 1
93 1
93 1
93 1
93 1
DAY HOUR
1 1
1 2 -
1 3
1 4
1 5
1 6
7
6
9
10
11
1 12
1 13
1 14
1 15
1 16
1 17
1 18
1 19
1 20
1 21
1 22
1 23
1 24
FLOW
VECTOR
90.0
90.0
90.0
90.0
90.0
90.0
90.0
90.0
90.0
90.0
90.0
90.0
90.0
90.0
90.0
90.0
90.0
90.0
90.0
90.0
90.0
90.0
90.0
90.0
SPEED
(M/S)
1.00
1.50
2.00
2.50
3.00
1.00
1.50
2.00
2.50
3.00
3.50
4.00
4.50
5.00
1.00
1.50
2.00
2.50
3.00
3.50
4.00
4.50
5.00
8.00
TEMP
293.1
293.1
293.1
293.1
293.1
293.1
293.1
293.1
293.1
293.1
293.1
293.1
293.1
293.1
293.1
293.1
293.1
293.
293.
293.
293.
293.
293.
293.
STAB
CLASS
1
1
1
1
1
2
2
2
2
2
2
2
2
2
3
3
3
3
3
3
3
3
3
3
NIXING HEIGHT (N)
RURAL URBAN
320.0
480.0
640.0
800.0
960.0
320.0
480.0
640.0
800.0
960.0
1120.0
1280.0
1440.0
1600.0
320.0
480.0
640.0
800.0
960.0
1120.0
1280.0
1440.0
1600.0
2560.0
320.0
480.0
640.0
800.0
960.0
320.0
480.0
640.0
800.0
960.0
1120.0
1280.0
1440.0
1600.0
320.0
480.0
640.0
800.0
960.0
1120.0
1280.0
1440.0
1600.0
2560.0
USTAR N-0 LENGTH
(N/S) (M)
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
2-0
(M)
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
2d I
(M)
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
o.c
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
NOTES: STABILITY CLASS 1«A, 2«B, 3«C, 4«0, 5-E AND 6-F.
FLOW VECTOR IS DIRECTION TOWARD WHICH WIND IS BLOWING.
-------
ISCOMDEP VERSION 94227
WTI Storage Tank Ripture, Screen Modeling -- ONSITE ORG.
1 Point source; 26 receptors ip to 50KM away; Vapor.
MODELING OPTIONS USED: CONC RURAL ELEV
GRORIS HOSTD
TANK
05
11
PA
CONCURRENT 1-HR AVERAGE CONCENTRATION
FOR SOURCE GROUP: ALL
INCLUDING SOURCE(S): ONSITE ,
VALUES ENDING WITH HOUR 1 FOR DAY 1
»* DISCRETE CARTESIAN RECEPTOR POINTS
* CONC OF FUGITIVE IN MICROGRAMS/M**3
X-COORD (M) Y-COORD (M)
CONC
X-COORD (N) Y-COORD (M)
CONC
100.00
300.00
500.00
700.00
900.00
1250.00
1750.00
2250.00
3000.00
5000.00
10000.00
20000.00
40000.00
0.00
0.00
0.00
o.oe
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
200.00
400.00
600.00
800.00
1000.00
1500.00
2000.00
2500.00
4000.00
7500.00
15000.00
30000.00
50000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
-------
ISCOMDEP VERSION 94227
UTI Storaae Tank Ri*>ture, Screen Modeling -- ONSITE ORC.
1 Point source; 26 receptors if> to 50KM away; Vapor.
** MODELING OPTIONS USED: CONC RURAL ELEV
GRDRIS NOSTD
TANK
11
PA
CONCURRENT 1-HR AVERAGE CONCENTRATION
FOR SOURCE GROUP: ALL
INCLUDING SOURCE(S): ONSITE ,
VALUES ENDING WITH HOUR Z FOR OAT 1
** DISCRETE CARTESIAN RECEPTOR POINTS
* CONC OF FUGITIVE IN NICROGRAMS/M**3
X-COORD (N) Y-COORD (M)
CONC
X-COORD (N) Y-COORD OO
CONC
100.00
300.00
500.00
700.00
900.00
1250.00
1750.00
2250.00
3000.00
5000.00
10000.00
20000.00
40000.00
0.00
0.00
0.00
o.oe
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00000
0.00000
0.02293
1.03664
3.49966
3.11532
2.12897
1 .61470
1.18499
0.69296
0.34380
0.19011
0.10656
200.00
400.00
600.00
800.00
1000.00
1500.00
2000.00
2500.00
4000.00
7500.00
15000.00
30000.00
50000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00000
0.00067
0.15725
3.76290
3.62576
2.53176
1.83657
1.44060
0.87455
0.45615
0.24271
0.13527
0.08872
-------
1SCONDEP VERSION 94227
VTI Storage Tank Rtpture, Screen Modeling -- ONSITE ORG. TANK
1 Point cource; 26 receptors up to 50Ot away; Vapor.
*** MODELING OPTIONS USED: CONC RURAL ELEV
GRDRIS NOSTD
05
11
PA
CONCURRENT 1-HR AVERAGE CONCENTRATION VALUES ENDING WITH HOUR 3 FOR DAT 1
FOR SOURCE GROUP: ALL
INCLUDING SOURCE(S): ONSITE ,
** DISCRETE CARTESIAN RECEPTOR POINTS **
* CONC OF FUGITIVE IN NICROGRAMS/M**3 **
X-COORO (M) Y-COORD (M)
CONC
X-COORD (M) Y-COORD (M)
CONC
100.00
300.00
500.00
700.00
900.00
1250.00
1750.00
2250.00
3000.00
5000.00
10000.00
20000.00
40000.00
0.00
0.00
0.00
0.00-
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00000
0.00055
0.45269
2.14537
3.61482
1.81360
1.19755
0.90827
0.66656
0.38979
0.19339
0.10694
0.05994
200.00
400.00
600.00
800.00
1000.00
1500.00
2000.00
2500.00
4000.00
7500.00
15000.00
30000.00
50000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00000
0.07051
1.03694
4.73459
2.93018
1 .42457
1.03307
0.81034
0.49193
0.25658
0.13653
0.07609
0.04990
-------
ISCOCEP VERSION 94227
VTI Storage Tank Ripture. Screen Modeling -- ONSITE ORG.
1 Point source; 26 receptors i*> to 50KM away; Vapor.
MODELING OPTIONS USED: CONC RURAL ELEV
GXDRIS NOSTD
TANK
(ft
11
PA
CONCURRENT 1-HR AVERAGE CONCENTRATION
FOR SOURCE GROUP: ALL
INCLUDING SOURCE(S): ONSITE ,
VALUES ENDING WITH HOUR 4 FOR DAT 1
DISCRETE CARTESIAN RECEPTOR POINTS
* CONC OF FUGITIVE IN NICROGRANS/M**3
X-COORD (N) Y-COORD (M)
CONC
X-COORD (M) Y-COORD (M)
CONC
100.00
300.00
500.00
700.00
900.00
1250.00
1750.00
2250.00
3000.00
5000.00
10000.00
20000.00
40000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00000
0.01101
1.53512
2.69253
3.50190
1.33560
0.76647
0.58129
0.42660
0.24947
0.12377
0.06844
0.03836
200.00
400.00
600.00
600.00
1000.00
1500.00
2000.00
2500.00
4000.00
7500.00
15000.00
30000.00
50000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00000
0.49471
2.18574
4.93815
2.63131
0.92004
0.66117
0.51862
0.31484
0.16421
0.08738
0.04870
0.03194
-------
ISCCNDEP VERSION 94227
VTI Storage Tank Rioture, Screen Modeling -- ONSITE ORG.
1 Point source; 26 receptors ip to 50KH away; Vapor.
** MODELING OPTIONS USED: CONC RURAL ELEV
GRDRIS NOSTD
TANK
05
11
PA
CONCURRENT 1-HR AVERAGE CONCENTRATION
FOR SOURCE GROUP: ALL
INCLUDING SOURCE(S): ONSITE ,
VALUES ENDING WITH HOUR 5 FOR DAY 1
DISCRETE CARTESIAN RECEPTOR POINTS
* CONC OF FUGITIVE IN NICROGRAMS/M**3
X-COORD (M) Y-COORD (M)
CONC
X-COORO (K) Y-COORD
-------
ISCOMOEP VERSION 94227
VTI Storage Tank Rupture, Screen Modeling ONSITE ORG.
1 Point source; 26 receptors up to 5001 away; Vapor.
MODELING OPTIONS USED: CONC RURAL ELEV
GRDR1S NOSTO
TANK
CONCURRENT 1-HR AVERAGE CONCENTRATION
FOR SOURCE GROUP: ALL
INCLUDING SOURCE(S): ONSITE ,
VALUES ENDING WITH HOUR 6 FOR DAY 1
DISCRETE CARTESIAN RECEPTOR POINTS
CONC OF FUGITIVE IN MICROGRAMS/M**3
X-COORD (M) Y-COORD (N)
CONC
X-COORD (N) Y-COORD (M)
CONC
100.00
300.00
500.00
700.00
900.00
1250.00
1750.00
2250.00
3000.00
5000.00
10000.00
20000.00
40000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
200.00
400.00
600.00
800.00
1000.00
1500.00
2000.00
2500.00
4000.00
7500.00
15000.00
30000.00
50000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
-------
1SCCNDEP VERSION 94227
WTI Storage Tank Rupture, Screen Modeling -- ONSITE ORG. TANK
1 Point source; 26 receptors up to 5001 away; Vapor.
MODELING OPTIONS USED: CONC RURAL ELEV
GRDR1S NOSTD
05
11
PA
CONCURRENT 1-HR AVERAGE CONCENTRATION VALUES ENDING WITH HOUR 7 FOR DAY 1
FOR SOURCE GROUP: ALL
INCLUDING SOURCE(S): ONSITE .
** DISCRETE CARTESIAN RECEPTOR POINTS *
* CONC OF FUGITIVE IN NICROGRAMS/M**3 **
X-COORD (M) Y-COORD (M)
CONC
X-CODRD (N) Y-COORD (M)
CONC
100.00
300.00
500.00
700.00
900.00
1250.00
1750.00
2250.00
3000.00
5000.00
10000.00
20000.00
40000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00000
0.00000
0.00000
0.00009
0.71572
1.07642
1.33757
1.33976
1.17236
0.83007
0.45067
0.24677
0.13666
200.00
400.00
600.00
800.00
1000.00
1500.00
2000.00
2500.00
4000.00
7500.00
15000.00
30000.00
50000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00000
0.00000
0.00001
0.91164
0.80047
1.27402
1.35620
1 .27164
1.00197
0.58033
0.31644
0.17439
0.11328
-------
ISCOMDEP VERSION 94227
UTI Storage Tank Kupture, Screen Modeling -- ONSITE OftG. TANK
1 Point source; 26 receptors up to 50KM way; Vapor.
MODELING OPTIONS USED: CONC RURAL ELEV
GRDRIS NOSTD
11
PA
CONCURRENT 1-HR AVERAGE CONCENTRATION
FOR SOURCE GROUP: ALL
INCLUDING SOURCE(S): ONSITE ,
VALUES ENDING WITH HOUR 6 FOR DAT 1
DISCRETE CARTESIAN RECEPTOR POINTS
** CONC OF FUGITIVE IN MICROGRAMS/M**3
X- COORD
Y- COORD (N)
CONC
X-COORD Y-COORD (M)
CONC
100.00
300.00
500.00
700.00
900.00
1250.00
1750.00
2250.00
3000.00
5000.00
10000.00
20000.00
40000.00
0.00
0.00
0.00
o.eo
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00000
0.00000
0.00173
0.02279
1.51803
1.88640
1.69324
1.30812
0.85239
0.47050
0.25350
0.13881
0.07687
200.00
400.00
600.00
800.00
1000.00
1500.00
2000.00
2500.00
4000.00
7500.00
15000.00
30000.00
50000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00000
0.00007
0.00922
1.95133
1.63705
1.87892
1.49577
1.11492
0.59448
0.32644
0.17800
0.09810
0.06372
-------
ISCOMDEP VERSION 94227
VTI Storage Tank Rupture, Screen Modeling -- ONSITE ORC. TANK
1 Point »ource; 26 receptor* up to SOW way; Vapor.
MODELING OPTIONS USED: CONC RURAL ELEV
GRORIS NOSTD
05
11
PA
CONCURRENT 1-HR AVERAGE CONCENTRATION VALUES ENDING WITH HOUR 9 FOR DAY 1
FOR SOURCE GROUP: ALL
INCLUDING SOURCE(S): ONSITE ,
* DISCRETE CARTESIAN RECEPTOR POINTS *
** CONC OF FUGITIVE IN MICROGRAKS/H"«3 *
X-COORD (K) Y-COORD (M)
CONC
X-COORD (N) Y-COORD (M)
CONC
100.00
300.00
500.00
TOO. 00
900.00
1250.00
1750.00
2250.00
3000.00
5000.00
10000.00
20000.00
40000.00
0.00
0.00
0.00
0.00 "
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00000
0.00001
0.05687
0.24646
2.51236
2.48588
1.78864
1.22950
0.74597
0.32248
0.16224
0.08884
0.04920
200.00
400.00
600.00
800.00
1000.00
1500.00
2000.00
2500.00
4000.00
7500.00
15000.00
30000.00
50000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00000
0.00548
0.15452
3.28459
2.54448
2.17235
1.47789
1.01387
0.45586
0.20913
0.11392
0.06278
0.04078
-------
ISCOMDEP VERSION 94227
UT1 Storage Tank Rt^ture, Screen Modeling -- ONSITE ORG. TANK
1 Point source; 26 receptors t*> to 50KM away; Vapor.
MODELING OPTIONS USED: CONC RURAL ELEV
GRDRIS NOSTD
05
11
PA
CONCURRENT 1-HR AVERAGE CONCENTRATION
FOR SOURCE GROUP: ALL
INCLUDING SOURCE(S): ONSITE ,
VALUES ENDING WITH HOUR 10 FOR DAY 1
*** DISCRETE CARTESIAN RECEPTOR POINTS
** CONC OF FUGITIVE IN NICROGRAMS/M**3
X-COORD (M) Y-COORD (N)
CONC
X-COORD (M) Y-COORD (M)
CONC
100.00
300.00
500.00
700.00
900.00
1250.00
1750.00
2250.00
3000.00
5000.00
10000.00
20000.00
40000.00
0.00
0.00
0.00
0.00-
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00000
0.00009
0.32378
0.80167
3.44999
2.80136
1.73919
1.11581
0.65630
0.21649
0.08500
0.04210
0.02095
200.00
400.00
600.00
800.00
1000.00
1500.00
2000.00
2500.00
4000.00
7500.00
15000.00
30000.00
50000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00000
0.04954
0.62452
4.58698
3.28362
2.23532
1.38067
0.90402
0.34305
0.14669
0.05631
0.02798
0.01674
-------
ISCOMDEP VERSION 94227
l/Tl Storage Tank kupture. Screen Model ins " ONSITE ORC.
1 Point source; 26 receptors if> to 50KM away; Vapor.
*** MGOELING OPTIONS USED: CONC RURAL ELEV
GRDRIS NOSTD
TANK
05
11
PA
CONCURRENT 1-HR AVERAGE CONCENTRATION VALUES ENDING WITH HOUR 11 FOR OAT 1
FOR SOURCE CROUP: ALL
INCLUDING SOURCE(S): ONSITE ,
* DISCRETE CARTESIAN RECEPTOR POINTS "**
** CONC OF FUGITIVE IN NICROGRAMS/M**3 **
X-COORD («) Y-COORD
CONC
X-COORD (N) Y-COORD (M)
CONC
100.00
300.00
500.00
700.00
900.00
1250.00
1750.00
2250.00
3000.00
5000.00
10000.00
20000.00
40000.00
0.00
0.00
0.00
0.80
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00000
0.00027
0.63423
1.51564
4.17008
2.90179
1.63359
1.00419
0.54820
0.18369
0.06255
0.03093
0.01539
200.00
400.00
600.00
800.00
1000.00
1500.00
2000.00
2500.00
4000.00
7500.00
15000.00
30000.00
50000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00000
0.16448
1.33047
5.61981
3.76749
2.17656
1.26494
0.80930
0.29583
0.08777
0.04137
0.02055
0.01230
-------
ISCOMDEP VERSION 94227
UTI Storage Tank Rusture, Screen Modeling -- ONSITE ORC.
1 Point source; 26 receptors tp to SOKM away; Vapor.
MODELING OPTIONS USED: CONC RURAL ELEV
GRDR1S HOSTD
TANK
05
11
PA
CONCURRENT 1-HR AVERAGE CONCENTRATION VALUES ENDING WITH HOUR 12 FOR DAY 1
FOR SOURCE GROUP: ALL
INCLUDING SOURCE(S): ONSITE ,
** DISCRETE CARTESIAN RECEPTOR POINTS **
CONC OF FUGITIVE IN MICROGRAMS/K**3 **
X-COORD (M) Y-COORD (N)
CONC
X-COORD (M) Y-COORD (M)
CONC
100.00
300.00
500.00
700.00
900.00
1250.00
1750.00
2250.00
3000.00
5000.00
10000.00
20000.00
40000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00000
0.00047
1 .43619
2.17457
4.63402
2.87154
1.51347
0.89720
0.48388
0.16075
0.04823
0.02366
0.01178
200.00
400.00
600.00
800.00
1000.00
1500.00
2000.00
2500.00
4000.00
7500.00
15000.00
30000.00
50000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00000
0.32855
2.04795
6.30585
4.01892
2.06444
1.15155
0.71627
0.26002
0.07152
0.03167
0.01574
0.00942
-------
ISCOMDEP VERSION 94227
WTI Storage Tank fixture. Screen Model ir« -- ONSITE ORG.
1 Point source; 26 receptors if to 50KM away; Vapor.
MODELING OPTIONS USED: CONC RURAL ELEV
CRDRIS NOSTD
TANK
05
11
PA
CONCURRENT 1-HR AVERAGE CONCENTRATION
FOR SOURCE GROUP: ALL
INCLUDING SOURCE(S): ONSITE ,
VALUES ENDING WITH HOUR 13 FOR DAY 1
** DISCRETE CARTESIAN RECEPTOR POINTS
* CONC OF FUGITIVE IN NrCROGRAMS/M**3
X-COORD Ol) Y-COORD (M)
CONC
X-COORD (N) Y-COORD (M)
CONC
100.00
300.00
500.00
700.00
900.00
1250.00
1750.00
2250.00
3000.00
5000.00
10000.00
20000.00
40000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00000
0.00064
1.97899
2.67886
4.87513
2.74288
1.38101
0.80696
0.43274
0.14312
0.03882
0.01871
0.00931
200.00
400.00
600.00
800.00
1000.00
1500.00
2000.00
2500.00
4000.00
7500.00
15000.00
30000.00
50000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00000
0.49603
2.634A4
6.27253
4.09815
1.90441
1.03949
0.64261
0.23186
0.06134
0.02503
0.01243
0.00744
-------
ISCOMDEP VERSION 94227 *
MODELING OPTIONS USED: CONC RURAL ELEV
** UTI Storage Tank Rupture, Screen Modeling -- ONSITE ORG. TANK
** 1 Point source; 26 receptors up to 50KM away; Vapor.
GRDRIS HOSTD
CONCURRENT 1-HR AVERAGE CONCENTRATION
FOR SOURCE GROUP: ALL
INCLUDING SOURCE(S): ONSITE ,
* DISCRETE CARTESIAN RECEPTOR POINTS
* CONC OF FUGITIVE IN HICROGRANS/M**3
X-COORD (M) Y-COORD (M>
CONC
X-COORD (M) Y-COORD (N)
CONC
11
PA
VALUES ENDING WITH HOUR U FOR DAY 1
100.00
300.00
500.00
700.00
900.00
1250.00
1750.00
2250.00
3000.00
5000.00
10000.00
20000.00
40000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00000
0.00075
2.39320
0.00000
4.70917
2.55091
1.26213
0.73255
0.39120
0.12898
0.03251
0.01516
0.00754
200.00
400.00
600.00
800.00
1000.00
1500.00
2000.00
2500.00
4000.00
7500.00
15000.00
30000.00
50000.00
0.00
0.00
0.00
Q.OO
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00000
0.63576
3.05156
6.05986
3.91382
1.75178
0.94617
0.58227
0.20915
0.05437
0.02028
0.01007
0.00603
-------
ISCOMDEP VERSION 94227
VTI Storage Tank Rupture, Screen Modeling -- ONSITE ORC.
1 Point source;. 26 receptors up to 50KH away; Vapor.
MODELING OPTIONS USED- CONC RURAL ELEV
GRDR1S NOSTD
TANK
05
11
PA
CONCURRENT 1-HR AVERAGE CONCENTRATION
FOR SOURCE GROUP: ALL
INCLUDING SOURCE(S): ONSITE ,
VALUES ENDING WITH HOUR IS FOR DAY 1
DISCRETE CARTESIAN RECEPTOR POINTS
CONC OF FUGITIVE IN MICROGRAMS/M**3
X-COORD (M) Y-COORD (M)
CONC
X-COORD (N) Y-COORD (M)
CONC
100.00
300.00
500.00
700.00
900.00
1250.00
1750.00
2250.00
3000.00
5000.00
10000.00
20000.00
40000.00
0.00
0.00
0.00
o.oo -
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
200.00
400.00
600.00
800.00
1000.00
1500.00
2000.00
2500.00
4000.00
7500.00
15000.00
30000.00
50000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
-------
ISCOMDEP VERSION 94227
VTI Storage Tank Rifrture, Screen Modeling -- ONSITE ORG. TANK
1 Point »ource; 26 receptors i*> to 50KM away; Vapor.
** MODELING OPTIONS USED: CONC RURAL ELEV
GRORIS NOSTD
05
11
PA
CONCURRENT 1-HR AVERAGE CONCENTRATION
FOR SOURCE GROUP: ALL
INCLUDING SOURCE(S): ONSITE ,
VALUES ENDING WITH HOUR 16 FOR DAY 1
* DISCRETE CARTESIAN RECEPTOR POINTS
M CONC OF FUGITIVE IN MICROGRANS/M**3
X-COORD (M) Y-COORD (M)
CONC
X-COORD (N) Y-COORD (M)
CONC
100.00
300.00
500.00
700.00
900.00
1250.00
1750.00
2250.00
3000.00
5000.00
10000.00
20000.00
40000.00
0.00
0.00
0.00
o.oo-
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00000
0.00000
0.00000
0.00000
0.35516
0.41352
0.53806
0.69374
0.79637
0.85563
0.62321
0.33855
0.18407
200.00
400.00
600.00
800.00
1000.00
1500.00
2000.00
2500.00
4000.00
7500.00
15000.00
30000.00
50000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00000
0.00000
0.00000
0.49781
0.35542
0.48755
0.60959
0.71369
0.78297
0.76923
0.43689
0.23681
0.15156
-------
* ISCONDEP VERSION 94227
UTI Storage Tank Rupture, Screen Modeling -- ONSITE ORC. TANK
1 Point source; 26 receptors up to SODt away; Vapor.
** MODELING OPTIONS USED: CONC RURAL ELEV
CRDRIS HOSTD
05
11
PA
CONCURRENT 1-HR AVERAGE CONCENTRATION
FOR SOURCE GROUP: ALL
INCLUDING SOURCE(S): ONSITE ,
VALUES ENDING WITH HOUR 17 FOR DAY 1 *
DISCRETE CARTESIAN RECEPTOR POINTS
CONC OF FUGITIVE IN NICROG*AMS/M**3
X-COORD (N) Y-COORD (M)
CONC
X-COORD (M) Y-COORD (M)
CONC
100.00
300.00
500.00
700.00
900.00
1250.00
1750.00
2250.00
3000.00
5000.00
10000.00
20000.00
40000.00
0.00
0.00
0.00
0,00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00000
0.00000
0.00001
0.00004
0.73275
0.89115
1.06070
1.16173
1.06167
0.83088
0.36598
0.19044
0.10354
200.00
400.00
600.00
800.00
1000.00
1500.00
2000.00
2500.00
4000.00
7500.00
15000.00
30000.00
50000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00000
0.00000
0.00002
1.03478
0.74956
1.01917
1.11316
1.10945
0.99398
0.51434
0.24610
0.13321
0.08525
-------
ISCOMDEP VERSION 94227
VTI Storage Tank Rijjture, Screen Koojeling -- ONSITE ORG. TANK
1 Point source; 26 receptors i*> to 50104 away; Vapor.
MODELING OPTIONS USED: CONC RURAL ELEV
GRDRIS NOSTD
05
11
PA
CONCURRENT 1-HR AVERAGE CONCENTRATION
FOR SOURCE GROUP: ALL
INCLUDING SOURCE(S): ONSITE ,
VALUES ENDING WITH HOUR 18 FOR DAY 1
DISCRETE CARTESIAN RECEPTOR POINTS
* CONC OF FUGITIVE IN NICROGRAMS/M**3
X-COORD (N) Y-COORD (M)
CONC
X-COORD (M) Y-COORD (N)
CONC
100.00
300.00
500.00
700.00
900.00
1250.00
1750.00
2250.00
3000.00
5000.00
10000.00
20000.00
40000.00
0.00
0.00
0.00
o.oo-
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00000
0.00000
0.00109
0.00519
1.34148
1.54328
1.56730
1.46576
1.28568
0.78552
0.27513
0.12207
0.06627
200.00
400.00
600.00
800.00
1000.00
1500.00
2000.00
2500.00
4000.00
7500.00
15000.00
30000.00
50000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00000
0.00003
0.00315
1.90220
1.36445
1.63103
1.51727
1.32860
1.02595
0.43262
0.16141
0.08525
0.05456
-------
ISCOMDEP VERSION 94227
WT1 Storage Tank Rupture, Screen Modeling -- ONSITE ORG.
1 Point cource; 26 receptors up to 50KM away; Vapor.
** MODELING OPTIONS USED: CONC RURAL ELEV
GRDRIS NOSTD
TANK
05
11
PA
CONCURRENT 1-HR AVERAGE CONCENTRATION
FOR SOURCE GROUP: ALL
INCLUDING SOURCE(S): ONSITE ,
VALUES ENDING WITH HOUR 19 FOR DAY 1
DISCRETE CARTESIAN RECEPTOR POINTS
CONC OF FUGITIVE IN NlCROGXAMS/ff**3
X-COORD («) Y-COORD (M)
COUC
X-COORO
-------
ISCONDEP VERSION 94227 *** "
4
MODELING OPTIONS USED: CONC RURAL ELEV
UTI Storage Tank nature, Screen Modeling -- ONSITE ORG. TANK
1 Point source; 26 receptors ip to 50KM away; Vapor.
GRDRIS NOSTD
CONCURRENT 1-HR AVERAGE CONCENTRATION
FOR SOURCE GROUP: ALL
INCLUDING SOURCE(S): ONSITE ,
* DISCRETE CARTESIAN RECEPTOR POINTS
M CONC OF FUGITIVE IN MICROGRAHS/K**3
X-COORD (N) Y-COORD (M)
CONC
X-COORD (M) Y-COORD (M)
CONC
0.
11
PA
VALUES ENDING WITH HOUR 20 FOR DAY 1
100.00
300.00
500.00
700.00
900.00
1250.00
1750.00
2250.00
3000.00
5000.00
10000.00
20000.00
40000.00
0.00
0.00
0.00
0.60
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00000
0.00000
0.05467
0.23896
3.09171
2.82183
2.13019
1.72940
1.00826
0.40216
0.10814
0.03198
0.01501
200.00
400.00
600.00
800.00
1000.00
1500.00
2000.00
2500.00
4000.00
7500.00
15000.00
30000.00
50000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00000
0.00127
0.15805
4.39351
2.97184
2.52382
1.83901
1.59844
0.60614
0.18731
0.05051
0.02007
0.01200
-------
ISCOMDEP VERSION 94227
VTI Storage Tank Rupture, Screen Modeling -- ONSITE ORG.
1 Point source; 26 receptors up to 50KM away; Vapor.
TANK
05
11
PA
MODEL!NG OPTIONS USED: COHC RURAL ELEV
GRDRIS MOSTD
COMCURRENT 1-HR AVERAGE CONCENTRATION
FOR SOURCE GROUP: ALL
INCLUDING SOURCE(S): ONSITE ,
VALUES ENDING WITH HOUR 21 FOR DAT 1
DISCRETE CARTESIAN RECEPTOR POINTS
CONC OF FUGITIVE IN NICROGRAMS/M**;
X-COORD (M) Y-COORD (M)
CONC
X-COORD (M) Y-COORD (N)
CONC
100.00
300.00
500.00
700.00
900.00
1250.00
1750.00
2250.00
3000.00
5000.00
10000.00
20000.00
40000.00
0.00
0.00
0.00
0.00 -
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00000
0.00000
0.12281
0.54328
4.01496
3.25340
2.20377
1.49681
0.91395
0.35694
0.09500
0.02627
0.01150
200.00
400.00
600.00
800.00
1000.00
1500.00
2000.00
2500.00
4000.00
7500.00
15000.00
30000.00
50000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00000
0.00281
0.36200
5.69707
3.73007
2.72637
1.80828
1.25509
0.54180
0.16501
0.04370
0.01546
0.00919
-------
ISCOMDEP VERSION 94227
l/TI Storage Tank Rupture, Screen Modeling -- ONSITE ORG. TANK
1 Point source; 26 receptors up to 50KM away; Vapor.
* MODELING OPTIONS USED: CONC RURAL ELEV
GRDRIS NOSTD
05
11
PA
CONCURRENT 1-HR AVERAGE CONCENTRATION VALUES ENDING WITH HOUR 22 FOR DAT 1
FOR SOURCE GROUP: ALL
INCLUDING SOURCE(S): tWSITE .
* DISCRETE CARTESIAN RECEPTOR POINTS *
* CONC OF FUGITIVE IN NICROGRANS/M**3 M
X-COORD (M) Y-COORD (M)
CONC
X-COORD (N) Y-COORD (M)
CONC
100.00
300.00
500.00
700.00
900.00
1250.00
1750.00
2250.00
3000.00
5000.00
10000.00
20000.00
40000.00
0.00
0.00
0.00
0.00-
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00000
0.00000
0.20044
0.90601
4.73503
3.35772
2.09344
1.38672
0.83313
0.32048
0.08468
0.02267
0.00909
200.00
400.00
600.00
800.00
1000.00
1500.00
2000.00
2500.00
4000.00
7500.00
15000.00
30000.00
50000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00000
0.00450
0.60350
5.82435
4.29039
2.63454
1.69019
1.15494
0.48890
0.14738
0.03877
0.01241
0.00726
-------
ISCOMDEP VERSION 94227
VTI Storage Tank Runure, ScrMn Modeling -- ONSITE ORC.
1 Point source; 26 receptors ip to 50KM away; Vapor.
MODELING OPTIONS USED: CONC RURAL ELEV
GRDRIS NOSTD
TANK
05
11
PA
CONCURRENT 1-HR AVERAGE CONCENTRATION
FOR SOURCE GROUP: ALL
INCLUDING SOURCE(S): ONSITE ,
VALUES ENDING WITH HOUR 23 FOR DAY 1
DISCRETE CARTESIAN RECEPTOR POINTS
* CONC OF FUGITIVE IN MICROGRAMS/tt**3
X-COORD (M) Y-COORD (M)
CONC
X-COORD
-------
ISCOMDEP VERSION 94227
WTI Storage Tank Rupture, Screen Modeling -- ONSITE ORG. TANK
1 Point source; 26 receptors up to 50KM away; Vapor.
MODELING OPTIONS USED: CONC RURAL ELEV
GRORIS NOSTD
(b
11
PA
CONCURRENT 1-HR AVERAGE CONCENTRATION
FOR SOURCE GROUP: ALL
INCLUDING SOURCE(S): ONSITE ,
VALUES ENDING WITH HOUR 24 FOR DAY 1
DISCRETE CARTESIAN RECEPTOR POINTS
* CONC OF FUGITIVE IN NICXOGRAMS/NM3
X-COORD (M) Y-COORD (M)
CONC
X-COORD (M) Y-COORD (M)
CONC
100.00
300.00
500.00
700.00
900.00
1250.00
1750.00
2250.00
3000.00
5000.00
10000.00
20000.00
40000.00
0.00
0.00
0.00
0.00>
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00000
0.00000
0.40590
0.00000
4.38890
2.60410
1.41706
0.87845
0.50281
0.18527
0.04799
0.01255
0.00341
200.00
400.00
600.00
800.00
1000.00
1500.00
2000.00
2500.00
4000.00
7500.00
15000.00
30000.00
50000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00000
0.00851
0.00000
5.51516
3.74987
1.88435
1.10085
0.71670
0.28662
0.08397
0.02187
0.00575
0.00242
-------
ISCOWEP VERSION 94227
WTI Storage Tank Rupture, Screen Modeling -- ONSITE ORG.
1 Point source; 26 receptors up to 50KM away; Vapor.
MODELING OPTIONS USED: CONC RURAL ELEV
GRORIS NOSTD
TANK
05
11
PA
CONCURRENT 1-HR AVERAGE CONCENTRATION
FOR SOURCE GROUP: ALL
INCLUDING SOURCE(S): ONSITE ,
VALUES ENDING WITH HOUR 1 FOR DAY
DISCRETE CARTESIAN RECEPTOR POINTS
* CONC OF FUGITIVE IN MICROGRAMS/M**3
X-CCORD (M) Y-COORD (M)
CONC
X-COORD (M) Y-COORD (N)
CONC
100.00
300.00
500.00
700.00
900.00
1250.00
1750.00
2250.00
3000.00
5000.00
10000.00
20000.00
40000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00000
0.00000
0.00000
0.00000
3.96872
2.23194
1.17603
0.71894
0.40758
0.14896
0.03845
0.01004
0.00265
200.00
400.00
600.00
800.00
1000.00
1500.00
2000.00
2500.00
4000.00
7500.00
15000.00
30000.00
50000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00000
0.00767
0.00000
5.02992
3.32493
1.58334
0.90612
0.58414
0.23105
0.06734
0.01751
0.00459
0.00177
-------
ISCOMDEP VERSION 94227
UTI Storage Tank Ri*)ture, Scrten Modeling -- ONSITE ORG.
1 Point source; 26 receptors up to 50Ot away; Vapor.
TANK
MODELING OPTIONS USED: CONC RURAL ELEV
GRDRIS NOSTD
05
11
PA
CONCURRENT 1-HR AVERAGE CONCENTRATION VALUES ENDING WITH HOUR 2 FOR DAT
FOR SOURCE GROUP: ALL
INCLUDING SOURCE(S>: ONSITE ,
* DISCRETE CARTESIAN RECEPTOR POINTS **
* CONC OF FUGITIVE IN MICROGRAMS/M**3
X-COORD (M) Y-COORD (M)
CONC
X-COORD (M) Y-COORD (M)
CONC
100.00
300.00
500.00
700.00
900.00
1250.00
1750.00
2250.00
3000.00
5000.00
10000.00
20000.00
40000.00
0.00
0.00
0.00
O.Ofr
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
200.00
400.00
600.00
800.00
1000.00
1500.00
2000.00
2500.00
4000.00
7500.00
15000.00
30000.00
50000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
-------
ISCOMDEP VERSION 94227
WTI Storage Tank Rupture. Screen Modeling -- ONSITE ORG. TANK
1 Point source; 26 receptors up to 50KM away; Vapor.
*** MODELING OPTIONS USED: CONC RURAL ELEV
GRDRIS NOSTD
05
11
PA
CONCURRENT 1-HR AVERAGE CONCENTRATION VALUES ENDING WITH HOUR 3 FOR DAY
FOR SOURCE GROUP: ALL
INCLUDING SOURCE(S): ONSITE ,
* DISCRETE CARTESIAN RECEPTOR POINTS **
* CONC OF FUGITIVE IN N1CROGRAMS/M**3 **
X-COORD (N) Y-COORD CM)
CONC
X-COORD (N) Y-COORD (M)
CONC
100.00
300.00
500.00
700.00
900.00
1250.00
1750.00
2250.00
3000.00
5000.00
10000.00
20000.00
400CO.OO
0.00
0.00
0.00
o.oo -
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00000
0.00000
0.00000
0.00000
0.24351
0. 21284
0.19563
0.22522
0.27371
0.26191
0.22724
0.27180
0.22390
200.00
400.00
600.00
800.00
1000.00
1500.00
2000.00
2500.00
4000.00
7500.00
15000.00
30000.00
50000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00000
0.00000
0.00000
0.35852
0.22329
0.20912
0.20175
0.21971
0.28663
0.22854
0.24962
0.25534
0.19725
-------
ISCOMDEP VERSION 94227
VTI Storage Tank Rupture. Screen Modeling -- ONSITE ORG.
1 Point source; 26 receptors up to 50KM away; Vapor.
** MODELING OPTIONS USED: CONC RURAL ELEV
GRORIS NOSTD
TANK
05
11
PA
CONCURRENT 1-HR AVERAGE CONCENTRATION
FOR SOURCE GROUP: ALL
INCLUDING SOURCE(S): ONSITE ,
VALUES ENDING WITH HOUR 4 FOR DAY
DISCRETE CARTESIAN RECEPTOR POINTS
** CONC OF FUGITIVE IN MICROGRAMS/M**3
X-COORD (M) Y-COORD (M)
CONC
X-COORD (N) Y-COORD (M)
CONC
100.00
300.00
500.00
700.00
900.00
1250.00
1750.00
2250.00
3000.00
5000.00
10000.00
20000.00
40000.00
0.00
0.00
0.00
0.00-
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00000
0.00000
0.00000
0.00000
0.44539
0.42104
0.41134
0.49127
0.59055
0.50098,
0.44014
0.35949
0.19203
200.00
400.00
600.00
800.00
1000.00
1500.00
2000.00
2500.00
4000.00
7500.00
15000.00
30000.00
50000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00000
0.00000
0.00000
0.67296
0.41629
0.43064
0.43323
0.47949
0.58230
0.37728
0.42043
0.25632
0.15120
-------
ISCOMDEP VERSION 94227 *
MODELIMG OPTIONS USED: CONC RURAL ELEV
** WTI Storage Tank Rupture, Screen Modeling -- ONSITE ORC. TANK
*« 1 Point source; 26 receptors up to 50KH auay; Vapor.
05
11
PA
GRORIS NOSTO
CONCURRENT 1-HR AVERAGE CONCENTRATION
FOR SOURCE GROUP: ALL
INCLUDING SOURCE(S): ONSITE .
VALUES ENDING WITH HOUR 5 FOR DAY
DISCRETE CARTESIAN RECEPTOR POINTS
* CONC OF FUGITIVE IN NICROGRAMS/K*«3
X-COORD
-------
ISCOMDEP VERSION 94227
WTI Storage Tank Rifrture, Screen Modeling - ONSITE ORG.
1 Point source; 26 receptors i*> to SOKM way; Vapor.
*** MODELING OPTIONS USED: CONC RURAL ELEV
GRORIS NOSTD
TANK
05
11
PA
CONCURRENT 1-HR AVERAGE CONCENTRATION
FOR SOURCE GROUP: ALL
INCLUDING SOURCE(S): ONSITE ,
VALUES ENDING WITH HOUR 6 FOR DAT 2 *
* DISCRETE CARTESIAN RECEPTOR POINTS
» CONC OF FUGITIVE IN MICROGRAMS/MM3
X-COORD
-------
ISCOMDEP VERSION 94227
VTI Storage Tank Ripture, Screen Modeling -- ONSITE ORG.
1 Point source; 26 receptors v*> to SOW away; Vapor.
*** MODELIMG OPTIONS USED: CONC RURAL ELEV
GRDRIS HOSTD
TANK
05
11
PA
CONCURRENT 1-HR AVERAGE CONCENTRATION
FOR SOURCE GROUP: ALL
INCLUDING SOURCE(S): ONSITE .
VALUES ENDING WITH HOUR 7 FOR DAT 2
DISCRETE CARTESIAN RECEPTOR POINTS
M CONC OF FUGITIVE IN MICROGRAMS/M**3
X-COORD (M) Y-COORD (M)
CONC
X-COORD (N) Y-COORD OO
CONC
100.00
300.00
500.00
700.00
900.00
1250.00
1750.00
2250.00
3000.00
5000.00
10000.00
20000.00
40000.00
0.00
0.00
0.00
0.06
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00000
0.00000
0.00013
0.00374
1 .97610
1.90724
1.72141
1.67589
1.30014
0.75753
0.31235
0.11705
0.04213
200.00
400.00
600.00
800.00
1000.00
1500.00
2000.00
2500.00
4000.00
7500.00
15000.00
30000.00
50000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00000
0.00000
0.00162
3.07187
1.86886
1.89053
1.69353
1.53326
0.97189
0.45942
0.17744
0.06415
0.03033
-------
ISCOMDEP VERSION 94227
WTI Storage Tank Rupture, Screen Modeling -- ONSITE ORG.
1 Point source; 26 receptors up to 50KM away; Vapor.
TANK
MODELING OPTIONS USED: CONC RURAL ELEV
GRDRIS NOSTD
05
11
PA
CONCURRENT 1-HR AVERAGE CONCENTRATION
FOR SOURCE GROUP: ALL
INCLUDING SOURCE(S): ONSITE ,
VALUES ENDING WITH HOUR 8 FOR DAY
DISCRETE CARTESIAN RECEPTOR POINTS
* CONC OF FUGITIVE IN MICROGRAMS/M**3
X-COORD (M> Y-COORD (M)
CONC
X-COORD (M) Y-COORD (M)
CONC
100.00
300.00
500.00
700.00
900.00
1250.00
1750.00
2250.00
3000.00
5000.00
10000.00
20000.00
40000.00
0.00
0.00
0.00
0.00-
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00000
0.00000
0.00040
0.01807
2.85100
2.61905
2.09678
1.70063
1.29080
0.72241
0.28562
0.10465
0.03725
200.00
400.00
600.00
800.00
1000.00
1500.00
2000.00
2500.00
4000.00
7500.00
15000.00
30000.00
50000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00000
0.00000
0.00646
3.99830
2.66761
2.36116
1.88289
1.54437
0.94286
0.42647
0.15986
0.05692
0.02677
-------
ISCOMDEP VERSION 94227
WTI Storage Tank Ri*>ture, Screen Modeline " ONSITE ORG.
1 Point source; 26 receptors up to 50KM away; Vapor.
MODELING OPTIONS USED: CONC RURAL ELEV
GRDRIS NOSTD
TANK
05
11
PA
CONCURRENT 1-HR AVERAGE CONCENTRATION
FOR SOURCE CROUP: ALL
INCLUDING SOURCE(S): ONSITE ,
VALUES ENDING WITH HOUR 9 FOR DAY
DISCRETE CARTESIAN RECEPTOR POINTS
CONC OF FUGITIVE IN MICROGRANS/M**3
X-COORD (M) Y-COORD (M)
CONC
X-COORD (M) Y-COORD (M)
CONC
100.00
300.00
500.00
700.00
900.00
1250.00
1750.00
2250.00
3000.00
5000.00
10000.00
20000.00
40000.00
0.00
0.00
0.00
0.00 -
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00000
0.00000
0.00079
0.04941
3.38335
2.77191
2.13556
1.70400
1.26625
0.68469
0.26206
0.09446
0.03336
200.00
400.00
600.00
800.00
1000.00
1500.00
2000.00
2500.00
4000.00
7500.00
15000.00
30000.00
50000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00000
0.00000
0.01543
4.06616
3.17512
2.41854
1 .90135
1 .53582
0.90637
0.39574
0.14508
0.05110
0.02393
-------
ISCOHDEP VERSION 94227
VTI Storage Tank Rupture, Screen Modeling -- ONSITE ORG.
1 Point source; 26 receptors up to SOKM away; Vapor.
*** MODELING OPTIONS USED: CONC RURAL ELEV
6RDRIS NOSTD
TANK
L
11
PA
CONCURRENT 1-HR AVERAGE CONCENTRATION
FOR SOURCE GROUP: ALL
INCLUDING SOURCE(S): ONSITE .
VALUES ENDING WITH HOUR 10 FOR DAY
DISCRETE CARTESIAN RECEPTOR POINTS
** CONC OF FUGITIVE IN MICROGRAMS/K**3
X-COORD (M) Y-COORD (M)
CONC
X-COORD (M) Y-COORD (M)
CONC
100.00
300.00
500.00
700.00
900.00
1250.00
1750.00
2250.00
3000.00
5000.00
10000.00
20000.00
40000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00000
0.00000
0.00121
0.00000
3.45579
2.83389
2.15250
1.69061
1.Z3202
0.64716
0.24147
0.08597
0.03019
200.00
400.00
600.00
800.00
1000.00
1500.00
2000.00
2500.00
4000.00
7500.00
15000.00
30000.00
50000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00000
0.00000
0.02717
4.14078
3.25192
2.45693
1.90102
1.51291
0.86669
0.36784
0.13259
0.04632
0.02163
-------
ISCONDEP VERSION 94227
UTI Storage Tank Rt*>ture, Screen Modeling -- ONSITE ORG.
1 Point source; 26 receptors up to 50KM away; Vapor.
TANK
*** MODELING OPTIONS USED: CONC RURAL ELEV
GRORIS NOSTO
05
11
PA
CONCURRENT 1-HR AVERAGE CONCENTRATION
FOR SOURCE GROUP: ALL
INCLUDING SCURCE(S): ONSITE ,
VALUES ENDING WITH HOUR 11 FOR OAT
** DISCRETE CARTESIAN RECEPTOR POINTS
** CONC OF FUGITIVE IN MICROGftANS/M**3
X-COORD (M) t-COORD (M)
CONC
X-COORD (M) Y-COORD (N)
CONC
100.00
300.00
500.00
700.00
900.00
1250.00
1750.00
2250.00
3000.00
5000.00
10000.00
20000.00
40000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00000
0.00000
0.00235
0.00000
3.77197
2.90088
2.00120
1.45757
0.96236
0.46698
0.16122
0.05541
0.01914
200.00
400.00
600.00
800.00
1000.00
1500.00
2000.00
2500.00
4000.00
7500.00
15000.00
30000.00
50000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00000
0.00000
0.00000
4.50307
3.50857
2.39218
1.69724
1.26581
0.64977
0.25199
0.08645
0.02952
0.01368
-------
ISCOMDEP VERSION 94227
VT1 Storage Tank (fixture. Screen Mode line " ONSITE ORG.
1 Point source; 26 receptors up to SOW away; Vapor.
MODELING OPTIONS USED: CONC RURAL ELEV
GRDRIS NOSTD
TANK
0.
11
PA
CONCURRENT 1-HR AVERAGE CONCENTRATION VALUES ENDING WITH HOUR 12 FOR DAY
FOR SOURCE GROUP: ALL
INCLUDING SOURCE(S): ONSITE ,
** DISCRETE CARTESIAN RECEPTOR POINTS **
* CONC OF FUGITIVE IN MICROGRAMS/tt**3 *
X-COORD (H) Y-COORD (M)
CONC
X-COORD (N) Y-COORD (N)
CONC
100.00
300.00
500.00
700.00
900.00
1250.00
1750.00
2250.00
3000.00
5000.00
10000.00
20000.00
40000.00
0.00
0.00
0.00
o.oe
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00000
0.00000
0.00000
0.00000
3.80947
2.76574
1.81722
1.28412
0.84217
0.38823
0.13118
0.04468
0.01537
200.00
400.00
600.00
800.00
1000.00
1500.00
2000.00
2500.00
4000.00
7500.00
15000.00
30000.00
50000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00000
0.00000
0.00000
4.56569
3.48282
2.21922
1.51549
1.10311
0.54633
0.20646
0.06991
0.02373
0.01098
-------
ISCOMDEP VERSION 94227
VTI Storage Tank Ri^jture, Screen Modeling -- ONSITE ORG. TANK
1 Point source; 26 receptors up to 50KM away; Vapor.
MODELING OPTIONS USED: CONC RURAL ELEV
GRDRIS NOSTD
05
11
PA
CONCURRENT 1-HR AVERAGE CONCENTRATION
FOR SOURCE GROUP: ALL
INCLUDING SOURCE(S): ONSITE ,
VALUES ENDING WITH HOUR 13 FOR DAY
*- DISCRETE CARTESIAN RECEPTOR POINTS
* CONC OF FUGITIVE IN NICROGRANS/M**3
X-COORD (M) Y-COORD (M)
CONC
X-COORD (M) Y-COORD (M)
CONC
100.00
300.00
500.00
700.00
900.00
1250.00
1750.00
2250.00
3000.00
5000.00
10000.00
20000.00
40000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00000
0.00000
0.00000
0.00000
3.53466
2.30460
1.40978
0.95736
0.60710
0.27001
0.08907
0.03003
0.01029
200.00
400.00
600.00
800.00
1000.00
1500.00
2000.00
2500.00
4000.00
7500.00
15000.00
30000.00
50000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00000
0.00000
0.00000
4.28782
3.11489
1.77414
1.14957
0.81127
0.38493
0.14126
0.04715
0.01591
0.00734
-------
ISCCMDEP VERSION 94227
WT1 Storage Tank Rn>ture, Screen Modeling -- ONSITE ORC. TANK
1 Point »ource; 26 receptor* up to 50KM away; Vapor.
* MODELING OPTIONS USED: CONC RURAL ELEV
GRDRIS NOSTD
05
11
PA
*** CONCURRENT 1-HR AVERAGE CONCENTRATION
FOR SOURCE GROUP: ALL
INCLUDING SOURCE(S): ONSITE ,
VALUES ENDING WITH HOUR U FOR DAY
* DISCRETE CARTESIAN RECEPTOR POINTS
* CONC OF FUGITIVE IN NICROGftANS/M*«3
X-COORD (M) Y-COORD (M)
CONC
X-COORD (M) Y-COORD (M)
CONC
100.00
300.00
500.00
700.00
900.00
1250.00
1750.00
2250.00
3000.00
5000.00
10000.00
20000.00
40000.00
0.00
0.00
0.00
o.oo-
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00000
0.00000
0.00000
0.00000
3.11636
1.90977
1.12801
0.75230
0.47013
0.20598
0.06729
0.02260
0.00773
200.00
400.00
600.00
800.00
1000.00
1500.00
2000.00
2500.00
4000.00
7500.00
15000.00
30000.00
50000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00000
0.00000
0.00000
3.81524
2.68416
1.43998
0.91036
0.63368
0.29522
0.10705
0.03552
0.01195
0.00551
-------
ISCOMDEP VERSION 94227
UT1 Storage Tank Ri*>ture, Screen Modeling -- ONSITE ORG. TANK
1 Point source; 26 receptors up to SOKM away; Vapor.
MODELING OPTIONS USED: CONC RURAL ELEV
CRDRIS NOSTD
05
11
PA
CONCURRENT 1-HR AVERAGE CONCENTRATION
FOR SOURCE GROUP: ALL
INCLUDING SOURCE(S): ONSITE ,
VALUES ENDING WITH HOUR 15 FOR DAY 2
DISCRETE CARTESIAN RECEPTOR POINTS
CONC OF FUGITIVE IN MICROGRAMS/N**3
X-COORD (M) Y-COORD (M)
CONC
X-COORD (N) Y-COORD (N)
CONC
100.00
300.00
500.00
700.00
900.00
1250.00
1750.00
2250.00
3000.00
5000.00
10000.00
20000.00
40000.00
0.00
0.00
0.00
o.oo-
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00000
0.00000
0.00000
0.00002
53.02272
33.15455
20.53589
13.78308
8.62315
4.10184
1.47648
0.56104
0.21901
200.00
400.00
600.00
800.00
1000.00
1500.00
2000.00
2500.00
4000.00
7500.00
15000.00
30000.00
50000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00000
0.00000
0.00000
62.57232
45.74073
25.41248
16.78118
11.90994
5.52872
2.35653
0.84673
0.32372
0.16437
-------
ISCOMDEP VERSION 94227
VTI Storage Tank Ripture, Screen Modeling -- ONSITE ORG.
1 Point source; 26 receptors up to 50KM away; Vapor.
MODELING OPTIONS USED: CONC RURAL ELEV
GRDRIS NOSTD
TANK
05
11
PA
CONCURRENT 1-HR AVERAGE CONCENTRATION
FOR SOURCE GROUP: ALL
INCLUDING SOURCE(S): ONSITE .
VALUES ENDING WITH HOUR 16 FOR DAT 2
DISCRETE CARTESIAN RECEPTOR POINTS
CONC OF FUGITIVE IN NICROGRAMS/NM3
X-COORD (M) Y-COORD (M)
CONC
X-COORD (N) Y-COORD (M)
CONC
100.00
300.00
500.00
700.00
900.00
1250.00
1750.00
2250.00
3000.00
5000.00
10000.00
20000.00
40000.00
0.00
0.00
0.00
o.oo
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00000
0.00000
0.00000
0.00024
37.69915
23.13220
14.12651
9.36406
5.77875
2.70237
0.95701
0.36093
0.14030
200.00
400.00
600.00
800.00
1000.00
1500.00
2000.00
2500.00
4000.00
7500.00
15000.00
30000.00
50000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00000
0.00000
0.00001
44.66874
32.39180
17.59253
11.47166
8.05933
3.66254
1.53952
0.54635
0.20770
0.10522
-------
ISCOMOEP VERSION 94227
UTI Storage Tank Rupture, Screen Modeling -- ONSITE ORG.
1 Point tource; 26 receptors 19 to 50Ot away; Vapor.
TANK
05
11
PA
MODELING OPTIONS USED: CONC RURAL ELEV
GRDRIS NOSTD
CONCURRENT 1-HR AVERAGE CONCENTRATION
FOR SOURCE GROUP: ALL
INCLUDING SOURCE(S): ONSITE ,
VALUES ENDING WITH HOUR 17 FOR DAT
DISCRETE CARTESIAN RECEPTOR POINTS
** CONC OF FUGITIVE IN NICROGRAMS/M**3
X-COORD (M) Y-COORD (M)
CONC
X-COORD (M) Y-COORD (N)
CONC
100.00
300.00
500.00
700.00
900.00
1250.00
1750.00
2250.00
3000.00
5000.00
10000.00
20000.00
40000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00000
0.00000
0.00000
0.00081
29.4U92
17.86273
10.79750
7.09592
4.33881
2.00681
0.70355
0.26419
0.10245
200.00
400.00
600.00
800.00
1000.00
1500.00
2000.00
2500.00
4000.00
7500.00
15000.00
30000.00
50000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00000
0.00000
0.00002
34.96266
25.19619
13.50803
£.73002
6.09073
2.72924
1.13742
0.40062
0.15179
0.07680
-------
1SCONDEP VERSION 94227
WTI Storage Tank Ripture, Screen Modeling -- ONSITE ORG. TANK
1 Point source; 26 receptors it? to SOKM away; Vapor.
* MODELING OPTIONS USED: CONC RURAL ELEV
GRDRIS NOSTD
05
11
PA
CONCURRENT 1-HR AVERAGE CONCENTRATION
FOR SOURCE CROUP: ALL
INCLUDING SOURCE(S): ONSITE ,
VALUES ENDING WITH HOUR 18 FOR DAY
** DISCRETE CARTESIAN RECEPTOR POINTS
* CONC OF FUGITIVE IN MICROGRANS/M**3
X-COORD (M) Y-COORD <*>
CONC
X-COORD (N) Y-COORO (N)
CONC
100.00
300.00
500.00
700.00
900.00
1250.00
1750.00
2250.00
3000.00
5000.00
10000.00
20000.00
40000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00000
0.00000
0.00000
0.00168
24.22348
14.58888
8.74911
5.71267
3.46935
1.59211
0.55426
0.20753
0.08035
200.00
400.00
600.00
800.00
1000.00
1500.00
2000.00
2500.00
4000.00
7500.00
15000.00
30000.00
50000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00000
0.00000
0.00004
26.66622
20.69772
10.98368
7.05054
4.89363
2.17046
0.89920
0.31507
0.11912
0.06021
-------
1SCONDEP VERSION 94227
WTI Storage Tank Bipture, Screen Modeling -- ONSITE ORG.
1 Point source; 26 receptors i*J to 50KM away; Vapor.
TANK
05
11
PA
MODELING OPTIONS USED: CONC RURAL ELEV
GRDRIS NOSTD
CONCURRENT 1-HR AVERAGE CONCENTRATION
FOR SOURCE GROUP: ALL
INCLUDING SOURCE(S): ONSITE ,
VALUES ENDING WITH HOUR 19 FOR DAY
DISCRETE CARTESIAN RECEPTOR POINTS
* CONC OF FUGITIVE IN KICROGRAMS/K**3
X-COORD (M) Y-COORD (M)
CONC
X-COORD (N) Y-COORD (M)
CONC
100.00
300.00
500.00
700.00
900.00
1250.00
1750.00
2250.00
3000.00
5000.00
10000.00
20000.00
40000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00000
0.00000
0.00000
0.00000
20.64429
12.34844
7.35844
4.78015
2.88771
1.31730
0.45619
0.17047
0.06592
200.00
400.00
600.00
800.00
1000.00
1500.00
2000.00
2500.00
4000.00
7500.00
15000.00
30000.00
50000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00000
0.00000
0.00008
24.65439
17.60280
9.26369
5.91436
4.08844
1.79905
0.74207
0.25902
0.09777
0.04939
-------
ISCOMDEP VERSION 94227
WTI Storage Tank Rupture. Scraen Modeling -- ONSITE ORG.
1 Point source; 26 receptors ip to 50Ot away; Vapor.
TANK
11
P*
MODELING OPTIONS USED: CONC RURAL ELEV
MORIS HOSTD
CONCURRENT 1-HR AVERAGE CONCENTRATION VALUES ENDING WITH HOUR 20 FOR DAY
FOR SOURCE GROUP: ALL
INCLUDING SOURCE(S): ONSITE ,
* DISCRETE CARTESIAN RECEPTOR POINTS ***
** CONC OF FUGITIVE IN MICROGRAKS/M"*3 **
X-COORD (M) Y-COORD (M)
CONC
X-COORD (M) Y-COORD (M)
CONC
100.00
300.00
500.00
700.00
900.00
1250.00
1750.00
2250.00
3000.00
5000.00
10000.00
20000.00
40000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00000
0.00000
0.00000
0.00000
18.01745
10.71450
6.35123
4.10867
2.47146
1.12210
0.38700
0.14439
0.05579
200.00
400.00
600.00
800.00
1000.00
1500.00
2000.00
2500.00
4000.00
7500.00
15000.00
30000.00
50000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00000
0.00000
0.00011
21.55747
15.33563
8.01418
5.09389
3.50971
1.53460
0.63085
0.21953
0.08276
0.04179
-------
ISCOMDEP VERSION 94227
UTI Storage Tank Rupture, Screen Modeling -- ONSITE ORG. TANK
1 Point source; 26 receptors up to 50KM away; Vapor.
05
11
PA
** MODELING OPTIONS USED: CONC RURAL ELEV
GRORIS NOSTC
CONCURRENT 1-HR AVERAGE CONCENTRATION
FOR SOURCE GROUP: ALL
INCLUDING SOURCE(S): ONSITE ,
VALUES ENDING WITH HOUR 21 FOR DAY
*** DISCRETE CARTESIAN RECEPTOR POINTS
* CONC OF FUGITIVE IN MICROGRAMS/M**3
X-COORD CM) Y-COORD (M)
CONC
X-COORD (M) Y-COORD (M)
CONC
100.00
300.00
500.00
700.00
900.00
1250.00
1750.00
2250.00
3000.00
5000.00
10000.00
20000.00
40000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00000
0.00000
0.00000
0.00000
16.00237
9.46883
5.58749
3.60198
2.15899
0.97645
0.33565
0.12508
0.04829
200.00
400.00
600.00
800.00
1000.00
1500.00
2000.00
2500.00
4000.00
7500.00
15000.00
30000.00
50000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00000
0.00000
0.00014
19.17776
13.59941
7.06426
4.47329
3.07368
1.33690
0.54809
0.19027
0.07166
0.03617
-------
*« ISCOMDEP VERSION 94227 *
VTI Storage Tank Ri*>ture, Screen Madeline " ONSITE ORC.
1 Point source; 26 receptor* ip to 50KN away; Vapor.
TANK
11
PA
MODELING OPTIONS USED: CONC RURAL ELEV
GRORIS NOSTD
CONCURRENT 1-HR AVERAGE CONCENTRATION VALUES ENDING WITH HOUR 22 FOR DAY
FOR SOURCE GROUP: ALL
INCLUDING SOURCE(S): ONSITE ,
** DISCRETE CARTESIAN RECEPTOR POINTS ***
CONC OF FUGITIVE IN NICROGRAMS/M**3 **
X-COORD (N) Y-COORD (N)
CONC
X-COORD (M) Y-COORD (M)
CONC
100.00
300.00
500.00
700.00
900.00
1250.00
1750.00
2250.00
3000.00
5000.00
10000.00
20000.00
40000.00
0.00
0.00
0.00
o.oe
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00000
0.00000
0.00000
0.00000
H. 404 75
8.48609
4.98817
3.20603
1.91587
0.86369
0.29608
0.11022
0.04253
200.00
400.00
600.00
800.00
1000.00
1500.00
2000.00
2500.00
4000.00
7500.00
15000.00
30000.00
50000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00000
0.00000
0.00000
17.28809
12.22498
6.31715
3.98734
2.73339
1.18362
0.48416
0.16774
0.06313
0.03185
-------
ISCOMDEP VERSION 94227
WTI Storage Tank Rtpture, Screen Modeling -- ONSITE ORG. TANK
1 Point cource; 26 receptor* if> to 50KM away; Vapor.
*** MODELING OPTIONS USED: CONC RURAL ELEV
GRDRIS NOSTD
05
11
PA
CONCURRENT 1-HR AVERAGE CONCENTRATION VALUES ENDING WITH HOUR 23 FOR DAT
FOR SOURCE GROUP: ALL
INCLUDING SOURCE(S): ONSITE ,
DISCRETE CARTESIAN RECEPTOR POINTS *»
** CONC OF FUGITIVE IN MICROG8AMS/M**3 **
X-COORO
Y-COORD
CONC
X-COORD (M) Y-COORD (M)
CONC
100.00
300.00
500.00
700.00
900.00
1250.00
1750.00
2250.00
3000.00
5000.00
10000.00
20000.00
40000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00000
0.00000
0.00000
0.00000
13.10529
7.69050
4.50517
2.88809
1.72138
0.77388
0.26467
0.09845
0.03797
200.00
400.00
600.00
800.00
1000.00
1500.00
2000.00
2500.00
4000.00
7500.00
15000.00
30000.00
50000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00000
0.00000
0.00000
15.74889
11.10862
5.71383
3.59643
2.46045
1.06137
0.43334
0.14988
0.05637
0.02844
-------
1SCOMDEP VERSION 94227
WTI Storage Tank Ripture, Screen Modeling -- ONSITE ORG.
1 Point source; 26 receptors up to SOKM away; Vapor.
MODELING OPTIONS USED: CONC RURAL ELEV
GRDRIS NOSTD
TANK
05
11
PA
CONCURRENT 1-HR AVERAGE CONCENTRATION
FOR SOURCE GROUP: ALL
INCLUDING SOURCE(S): ONSITE .
VALUES ENDING WITH HOUR 34 FOR DAT
DISCRETE CARTESIAN RECEPTOR POINTS
CONC OF FUGITIVE IN NICROGRAMS/M**3
X-COORD OO Y-COORD (M)
CONC
X-COORD (N) Y-COORD (M)
CONC
100.00
300.00
500.00
700.00
900.00
1250.00
1750.00
2250.00
3000.00
5000.00
10000.00
20000.00
40000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00000
0.00000
0.00000
0.00000
54.02040
34.35207
21.72369
14.79566
9.42373
4.73324
1.82605
0.75322
0.31324
200.00
400.00
600.00
800.00
1000.00
1500.00
2000.00
2500.00
4000.00
7500.00
15000.00
30000.00
50000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00000
0.00000
0.00000
63.41436
46.92068
26.60357
17.90035
12.89174
6.23338
2.82689
1.08768
0.44796
0.23723
-------
ISCONDEP VERSION 94227
UTl Storage Tank Ripture, Screen Modeling -- ONSITE ORG. TANK
1 Point source; 26 receptors i*> to 50KM away; Vapor.
MODELING OPTIONS USED: CONC RURAL ELEV
GRDRIS NOSTD
05
11
PA
CONCURRENT 1-HR AVERAGE CONCENTRATION
FOR SOURCE GROUP: ALL
INCLUDING SOURCE(S): ONSITE .
VALUES ENDING WITH HOUR 1 FOR DAT
DISCRETE CARTESIAN RECEPTOR POINTS
CONC OF FUGITIVE IN NICROGRAMS/K**3
X-COORD (M) Y-COORD (M)
CONC
X-COORO (N) Y-COORD (N)
CONC
100.00
300.00
500.00
700.00
900.00
1250.00
1750.00
2250.00
3000.00
5000.00
10000.00
20000.00
40000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00000
0.00000
0.00000
0.00000
38.46748
24.23649
15.15639
10.21285
6.42609
3.17854
1.20517
0.49244
0.20355
200.00
400.00
600.00
800.00
1000.00
1500.00
2000.00
2500.00
4000.00
7500.00
15000.00
30000.00
50000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00000
0.00000
0.00000
45.28408
33.32661
18.65625
12.42282
8.86820
4.20866
1.88087
0.71349
0.29169
0.15394
-------
ISCOMDEP VERSION 94227
VTI Storage Tank Rupture, Screen Modeling -- ONSITE ORG. TANK
1 Point source; 26 receptors up to 50O» away; Vapor.
MODELING OPTIONS USED: CONC RURAL ELEV
GRDRIS NOSTD
05
11
PA
CONCURRENT 1-HR AVERAGE CONCENTRATION VALUES ENDING UITH HOUR 2 FOR DAY 3
FOR SOURCE GROUP: ALL
INCLUDING SOURCE(S): ONSITE ,
** DISCRETE CARTESIAN RECEPTOR POINTS ***
** CONC OF FUGITIVE IN MICROGRAMS/K*«3 **
X-COORD (M) Y-COORD (M)
CONC
X-COORD (N) Y-COORD (M)
CONC
100.00
300.00
500.00
700.00
900.00
1250.00
1750.00
2250.00
3000.00
5000.00
10000.00
20000.00
40000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00000
0.00000
0.00000
0.00000
30.14240
18.86021
11.69847
7.82353
4.88164
2.39006
0.89624
0.36412
0.14997
200.00
400.00
600.00
800.00
1000.00
1500.00
2000.00
2500.00
4000.00
7500.00
15000.00
30000.00
50000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00000
0.00000
0.00000
35.56019
26.06351
14.45353
9.55245
6.77720
3.17590
1 .40597
0.52865
0.21517
0.11332
-------
ISCOMDEP VERSION 94227
WTI Storage Tank Rupture, Screen Modeling - ONSITE ORG.
1 Point source; 26 receptors up to SOW way; Vapor.
MODELING OPTIONS USED: CONC RURAL ELEV
GRORIS NOSTD
TANK
05
11
PA
CONCURRENT 1-HR AVERAGE CONCENTRATION
FOR SOURCE GROUP: ALL
INCLUDING SOURCE(S): ONSITE ,
VALUES ENDING WITH HOUR 3 FOR DAY 3
DISCRETE CARTESIAN RECEPTOR POINTS
** CONC OF FUGITIVE IN MICROGRAMS/M**3
X-COORD (M) Y-COORD (M)
CONC
X-COORD (N) Y-COORD (M)
CONC
100.00
300.00
500.00
700.00
900.00
1250.00
1750.00
2250.00
3000.00
5000.00
10000.00
20000.00
40000.00
0.00
0.00
0.00
o.oo-
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00000
0.00000
0.00000
0.00000
24.89685
15.49300
9.54912
6.34959
3.93725
1.91335
0.71187
0.28810
0.11837
200.00
400.00
600.00
800.00
1000.00
1500.00
2000.00
2500.00
4000.00
7500.00
15000.00
30000.00
50000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00000
0.00000
0.00000
29.42244
21.49452
11.83207
7.77493
5.49047
2.54896
1.12086
0.41885
0.16997
0.08939
-------
ISCQNDEP VERSION 94227
tfTI Storage Tank Ri*>ture, Screen Hodelinfl -- ONSITE ORC.
1 Point source; 26 receptors up to SOW away; Vapor.
MODELING OPTIONS USED: CONC RURAL ELEV
GRDRIS NOSTD
TANK
r
PA
CONCURRENT 1-HR AVERAGE CONCENTRATION
FOR SOURCE GROUP: ALL
INCLUDING SOURCE(S): ONSITE ,
VALUES ENDING WITH HOUR 4 FOR DAT
DISCRETE CARTESIAN RECEPTOR POINTS
CONC OF FUGITIVE IN NICROGRAMS/M**3
X-COORD (M) Y-COORD (N)
CONC
X-COORD (N) r-COORD (N)
CONC
100.00
300.00
500.00
700.00
900.00
1250.00
1750.00
2250.00
3000.00
5000.00
10000.00
20000.00
40000.00
0.00
0.00
0.00
o.oo
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00000
0.00000
0.00000
0.00000
21. 265 U
13.17389
8.07817
5.34702
3.29930
1.59413
0.58959
0.23793
0.09758
200.00
400.00
600.00
800.00
1000.00
1500.00
2000.00
2500.00
4000.00
7500.00
15000.00
30000.00
50000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00000
0.00000
0.00000
25.16628
18.33578
10.03277
6.56213
4.61697
2.12784
0.93093
0.34627
0.14021
0.07367
-------
** ISCOMDEP VERSION 94227
UT1 Storage Tank Rupture, Screen Modeling -- ONSITE ORC.
1 Point source; 26 receptors up to 50KK away; Vapor.
TANK
MODELING OPTIONS USED: CONC RURAL ELEV
GRORIS NOSTD
05
11
PA
CONCURRENT 1-HR AVERAGE CONCENTRATION VALUES ENDING WITH HOUR 5 FOR DAY 3
FOR SOURCE CROUP: ALL
INCLUDING SOURCECS): ONSITE ,
*** DISCRETE CARTESIAN RECEPTOR POINTS **
** CONC OF FUGITIVE IN NICROGRAMS/M**3 *
X-COORD (M) Y-COORD (M)
CONC
X-COORD (M) Y-COORD (M)
CONC
100.00
300.00
500.00
700.00
900.00
1250.00
1750.00
2250.00
3000.00
5000.00
10000.00
20000.00
40000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00000
0.00000
0.00000
0.00000
18.59078
11.47395
7.00580
4.61983
2.83919
1.36549
0.50267
0.20241
0.08290
200.00
400.00
600.00
800.00
1000.00
1500.00
2000.00
2500.00
4000.00
7500.00
15000.00
30000.00
50000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00000
0.00000
0.00000
22.02755
16.01270
8.71776
5.68021
3.98441
1.82547
0.79545
0.29480
0.11917
0.06256
-------
ISCCWEP VERSION 94227
l/TI Storage Tank Rusture, Screen Modeling -- ONSITE ORG.
1 Point source; 26 receptors up to SOKM away; Vapor.
*** MODELING OPTIONS USED: CONC RURAL ELEV
GRDRIS NOSTD
TANK
11
PA
CONCURRENT 1-HR AVERAGE CONCENTRATION
FOR SOURCE GROUP: ALL
INCLUDING SOURCE(S): ONSITE ,
VALUES ENDING WITH HOUR 6 FOR DAY
** DISCRETE CARTESIAN RECEPTOR POINTS
** CONC OF FUGITIVE IN MICROGRAMS/M**3
X-COORD
-------
ISCOMOEP VERSION 94227
VTI Storage Tank Ripture, Screen Modeling - ONSITE ORC.
1 Point source; 26 receptors up to 50KM away; Vapor.
TANK
05
11
PA
MODELING OPTIONS USED: CONC RURAL ELEV
GRDRIS NOSTD
THE 1ST HIGHEST 1-HR AVERAGE CONCENTRATION
INCLUDING SOJRCE(S): ONSITE ,
VALUES FOR SOURCE GROUP: ALL
DISCRETE CARTESIAN RECEPTOR POINTS
* CONC OF FUGITIVE IN MICR06RANS/M**3
X-COORD (M) Y-COORD (H>
CONC
(YTMMDDHH)
X-CCOW (M) Y-COORD (M)
CONC
(YYMMDOHH)
100.00
300.00
500.00
700.00
900.00
1250.00
1750.00
2250.00
3000.00
5000.00
10000.00
20000.00
40000.00
0.00
0.00
0.00
0.00
o.oo-
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00000
0.04468
2.70007
2.83874
54.02040
34.35207
21.72369
14.79566
9.42373
4.73324
1.82605
0.75322
0.31324
( 0)
(93010105)
(93010105)
(93010105)
(93010224)
(93010224)
(93010224)
(93010224)
(93010224)
(93010224)
(93010224)
(93010224)
(93010224)
200.00
400.00
600.00
800.00
1000.00
1500.00
2000.00
2500.00
4000.00
7500.00
15000.00
30000.00
50000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00000
1.25708
3.05156
63.41436
46.92068
26.60357
17.90035
12.89174
6.23338
2.82689
1.08768
0.44796
0.23723
( 0)
(93010105)
(93010114)
(93010224)
(93010224)
(93010224)
(93010224)
(93010224)
(93010224)
(93010224)
(93010224)
(93010224)
(93010224)
-------
1SCOM0EP VERSION 94227
VTI Storage Tank Rl-pture. Screen Modeling -- ONSITE ORG. TANK
1 Point source; 26 receptors 19 to 5004 may; Vapor.
MODELING OPTIONS USED: CONC RURAL ELEV
GRORIS NOSTD
0:
11
PA
THE 2ND HIGHEST 1-HR AVERAGE CONCENTRATION
INCLUDING SOURCE(S): ONSITE .
VALUES FOR SOURCE GROUP: ALL
DISCRETE CARTESIAN RECEPTOR POINTS
CONC OF FUGITIVE IN NICROGRAMS/M**3
X-COORD (M) Y-COORD (N)
CONC
(TYMMDDHH)
X-COORD (M) Y-COORD (H)
CONC
(YYMMDDHH)
100.00
300.00
500.00
700.00
900.00
1250.00
1750.00
2250.00
3000.00
5000.00
10000.00
20000.00
40000.00
0.00
0.00
0.00
0.00
o.oo -
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00000
0.01101
2.39320
2.69253
53.02272
33.15455
20.53589
13.78308
8.62315
4.10184
1.47648
0.56104
0.22390
( 0)
(93010104)
(93010114)
(93010104)
(93010215)
(93010215)
(93010215)
(93010215)
(93010215)
(93010215)
(93010215)
(93010215)
(93010203)
200.00
400.00
600.00
800.00
1000.00
1500.00
2000.00
2500.00
4000.00
7500.00
15000.00
30000.00
50000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00000
0.63576
3.02139
62.57232
45.74073
25.41248
16.78118
11.90994
5.52872
2.35653
0.84673
0.32372
0.19725
( 0)
(93010114)
(93010105)
(93010215)
(93010215)
(93010215)
(93010215)
(93010215)
(93010215)
(93010215)
(93010215)
(93010215)
(93010203)
-------
** ISCONDEP VERSION 94227
WTI Storage Tank Rupture, Screen Modeling -- ONSITE ORG. TANK
1 Point source; 26 receptors up to SOW away; Vapor.
05
11
PA
*** MODELING OPTIONS USED: CONC RURAL ELEV
GRDRIS NOSTD
RANK
THE MAXINUN 50 1-HR AVERAGE CONCENTRATION
INCLUDING SOURCE(S): ONSITE .
VALUES FOR SOURCE GROUP: ALL
CONC (YYMMDDHH) AT
** CONC OF FUGITIVE IN MICROGRAMS/NM3
RECEPTOR (XR,YR) OF TYPE RANK
CONC (YYNNPDHH) AT
RECEPTOR (XR.YR
1.
2.
3.
4.
5.
6.
7.
8.
9.
10.
11.
12.
13.
14.
15.
16.
17.
18.
19.
20.
21.
22.
23.
24.
25.
63.41436
62.57232
54.02040
53.02272
46.92068
45.74073
45.28408
44.66874
38.46748
37.69915
35.56019
34.96268
34.35207
33.32661
33.15455
32.39180
30.14240
29.42244
29.41492
28.86622
26.60357
26.06351
25.41248
25.19619
25.16628
(93010224) AT (
(93010215) AT (
(93010224) AT (
(93010215) AT (
(93010224) AT (
(93010215) AT (
(93010301) AT-(
(93010216) AT (
(93010301) AT (
(93010216) AT (
(93010302) AT (
(93010217) AT (
(93010224) AT (
(93010301) AT (
(93010215) AT (
(93010216) AT (
(93010302) AT (
(93010303) AT (
(93010217) AT (
(93010218) AT (
(93010224) AT (
(93010302) AT (
(93010215) AT (
(93010217) AT (
(93010304) AT (
800.00,
800.00,
900.00.
900.00,
1000.00,
1000.00,
800.00,
800.00,
900.00,
900.00,
800.00,
800.00,
1250.00,
1000.00,
1250.00,
1000.00,
900.00,
800.00.
900.00,
800.00,
1500.00,
1000.00,
1500.00.
1000.00,
800.00,
0.00)
0.00)
0.00)
0.00)
0.00)
0.00)
0.00)
0.00)
0.00)
0.00)
0.00)
0.00)
0.00)
0.00)
0.00)
0.00)
0.00)
0.00)
0.00)
0.00)
0.00)
0.00)
0.00)
0.00)
0.00)
DC
DC
DC
DC
nc
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
26.
27.
28.
29.
30.
31.
32.
33.
34.
35.
36.
37.
38.
39.
40.
41.
42.
43.
44.
45.
46.
47.
48.
49.
50.
24.89685
24.65439
24.23649
24.22348
23.13220
22.02755
21.72369
21.55747
21.49452
21 .26514
20.69772
20.64429
20.53589
19.60995
19.17776
18.86021
18.65625
18.59078
18.33578
18.01745
17.90035
17.86273
17.60280
17.59253
17.28809
(93010303)
(93010219)
(93010301)
(93010218)
(93010216)
(93010305)
(93010224)
(93010220)
(93010303)
(93010304)
(93010218)
(93010219)
(93010215)
(93010306)
(93010221 )
(93010302)
(93010301)
(93010305)
(93010304)
(93010220)
(93010224)
(93010217)
(93010219)
(93010216)
(93010222)
AT (
AT (
AT (
AT (
AT (
AT (
AT (
AT (
AT (
AT (
AT (
AT (
AT (
AT (
AT (
AT (
AT (
AT (
AT (
AT (
AT (
AT (
AT (
AT (
AT (
900.00,
800.00,
1250.00,
900.00,
1250.00,
800.00,
1750.00,
800.00,
1000.00,
900.00,
1000.00,
900.00,
1750.00,
800.00,
800.00,
1250.00,
1500.00,
900.00,
1000.00,
900.00,
2000.00,
1250.00,
1000.00,
1500.00,
800.00,
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
RECEPTOR TYPES: GC - GRIDCART
GP * GRIDPOLR
DC « DISCCART
DP « DISCPOLR
BO « BOUNDARY
-------
** 1SCONDEP VERSION 94227 *** *** WT1 Storage Tank RnKure. Screen Modeling - ONSITE C*G. TANK 05
*** 1 Point source; 26 receptors «*> to SOW away; Vapor. "* 11
PA
** MODELING OPTIONS USED: CONC RURAL ELEV GRDRIS NOSTD
** THE SUMKARY OF HIGHEST 1-HR RESULTS ***
* CONC OF FUGITIVE IN MICROGRAMS/M**3 *
DATE MET
GROUP ID AVERAGE CONC (YTNNDDHH) RECEPTOR (XR, YR, ZELEV. ZFLAG) OF TYPE GRI
ALL HIGH 1ST HIGH VALUE IS 63.4U36 ON 93010224: AT ( 800.00, 0.00, 353.60, 0.00) DC
HIGH 2ND HIGH VALUE IS 62.57232 ON 93010215: AT ( 800.00, 0.00, 353.60. 0.00) DC
** RECEPTOR TYPES: CC - GRIDCAKT
GP - GRIDPOLR
DC - OISCCART
DP - DI5CPOLR
BD BOUNDARY
-------
ISCOMDEP VERSION 94227 *** »* WTI Storage Tank Rupture, Screen Modeling -- ONSITE ORG. TANK *» 05
** 1 Point source; 26 receptors up to 50KM away; Vapor. ** n
PA
MODELING OPTIONS USED: CONC RURAL ELEV GRDRIS NOSTD
*** Message Summery : ISCOMDEP Model Execution **
Simnary of Total Messages
A Total of 0 Fatal Error Message(s)
A Total of 0 Warning Message(s)
A Total of 0 Informational Message(s)
FATAL ERROR MESSAGES
* NONE **
WARNING MESSAGES
*"* NONE *
ISCOMDEP Finishes Successfully
-------
B. Off-Site Fire Scenario
-------
CO STARTING
TITLEONE
TITLETWO
MOOELOPT
AVERTINE
POLLUTID
TERRHGTS
ELEVUNIT
RUNORNOT
ERRORFIL
CO FINISHED
UTI Truck Accident Off-Site, Screen Modeling -
1 Point source; 26 receptors up to 50 » a««y;
GRORIS NOSTD RURAL CJnC
1
Fugitive
ELEV
METERS
RUN
OFFSITE.ERR
- OFFSITE
Vapor.
SO STARTING
LOCATION OFFSITE POINT 0.0 0.0 216.4
"* Point Source 8S HS TS VS OS
** Parameters:
SOSRCPARAM OFFSITE 1.0 38.0 997. 0.225 30.59
* SO SRCPARAM OFFSITE 1.0 38.0 997. 0.075 52.98
SO SRCGROUP
SO FINISHED
RE STARTING
RE DISCCART
RE DISCCART
RE DISCCART
MSCCART
JISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE FINISHED
ME STARTING
ME INPUTFIL
ME ANEMHGHT
ME SURFDATA
- UAIRDATA
ALL
100.00000
200.00000
300.00000
400.00000
500.00000
600.00000
700.00000
800.00000
900.00000
1000.00000
1250.00000
1500.00000
1750.00000
2000.00000
2250.00000
2500.00000
3000.00000
4000.00000
5000.00000
7500.00000
10000.00000
15000.00000
20000.00000
30000.00000
40000.00000
50000.00000
. screen. wet
10.0 METERS
94823 1993
94823 1993
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
292.6
304.8
328.0
347.5
359.7
359.7
356.6
359.7
359.7
371.9
361.5
359.7
359.7
365.8
371.9
408.4
400.4
420.6
415.4
408.4
426.7
420.0
420.0
420.0
420.0
420.0
ME PROFFILE TEMPS ISC_TEMP.STK
- ME PROFFILE WINDS ISC_WIND.STK
** DAYRANGE 1/3
ME FINISHED
TG STARTING
-------
INPUTFIL MtnOOk.out
« LOCATION 538.4 4497.8 km
TG FINISHED
OU STARTING
RECTABLE ALLAVE FIRST
DAYTABLE ALLAVE
NAXTABLE ALLAVE 50
** NAXIFILE 3 ALL 30.0 MAXIALL.FIL 25
» NAXIFILE 24 ALL 10.0 NAXIALL.FIL 25
"* POSTFILE 1 ALL INOIV POST2C.BIN 20
* POSTFILE PERIOD ALL PLOT PSTANALL.FIL 21
** Note that the following two input cards generate PLOTFILEs with the file
* unit dynamically allocated by the ISCST2 program. When porting the Model
* to another computer system, the user My need to specify the file units
** as is done on the previous four input cards.
* PLOTFILE 3 ALL 2ND PLT03ALL.FIL
** PLOTFILE 24 ALL 2ND PLT24ALL.FIL
OU PLOTFILE 1 ALL FIRST OFFSITE.PLT
OU PLOTFILE 1 ALL FIRST OFFSITE.PLT *
OU FINISHED
** Message SuMsary For ISC2 Model Setup **
Summary of Total Messages
A Totsl of 0 Fatal Error Message(s)
A Total of 1 Warning Message(s)
A Total of 0 Informational Message(s)
FATAL ERROR MESSAGES
*** NONE ***
''m-a UARNING MESSAGES **-xi-L1*1
SO U320 17 PPARM : Source Parameter May Be Out-of-Range for Parameter OS
* SETUP Finishes Successfully **
-------
** ISCOMDEP VERSION 94227 ** * WTI Truck Accident Off-Site. Screen Modeling -- OFFSITE *« 09/14/95
* 1 Point source; 26 receptors up to SO KM away; Vapor. ** 12:59:48
PACE 1
* MODELING OPTIONS USED: CONC RURAL ELEV GRORIS NOSTD
** MODEL SETUP OPTIONS SUMMARY **
Intermediate Terrain Processing is Selected
Model Is Setup for Calculation of Average concentration Values.
-- SCAVENGING/DEPOSITION LOGIC --
"Model Uses NO DRY DEPLETION. DDPLETE * F
Model Uses NO WET DEPLETION. UDPLETE * F
**NO WET SCAVENGING Data Provided.
Model Does NOT Use GRIDDED TERRAIN Data for Depletion Calculations
Model Uses RURAL Dispersion.
Model Uses User-Specified Options:
1. Gradual Plume Rise.
2. Not Use Stack-tip Downwash.
3. Buoyancy-induced Dispersion.
4. Calms Processing Routine.
5. Not Use Missing Data Processing Routine.
6. Default Wind Profile Exponents.
7. Default Vertical Potential Temperature Gradients.
Model Accepts Receptors on ELEV Terrain.
Model Assumes No FLAGPOLE Receptor Heights.
Model Calculates 1 Short Tent Averag«(s) of: 1-HR
This Run Includes: 1 Source(s); 1 Source Group(s); and 26 Receptor(s)
The Model Assumes A Pollutant Type of: FUGITIVE
Model Set To Continue Running After the Setup Testing.
Output Options Selected:
Model Outputs Tables of Highest Short Term Values by Receptor (RECTABLE Keyword)
Model Outputs Tables of Overall Maximum Short Tern Values (NAXTABLE Keyword)
Model Outputs Tables of Concurrent Short Term Values by Receptor for Each Day Processed (DAYTABLE Keyword)
Model Outputs External File(s) of Nigh Values for Plotting (PLOTFILE Keyword)
NOTE: The Following Flags May Appear Following CONC Values: c for Calm Hours
m for Missing Hours
b for Both Cain and Missing Hours
Misc. Inputs: Anam. Hgt. <) 10.00 ; Decay Coef. * 0.0000 ; Rot. Angle * 0.0
E«*ssion units « GRAMS/SEC ; Emission Rate Unit Factor - 0.10000E+07
Output Units » NICROGRAMS/M**3
'Input Runstream File: offsite.inp ; Output Print File: offsite.lst
Detailed Error/Message File: OFFSITE.ERR
-------
tSCOHDEP VERSION 94227
l/TI Truck Accident Off-Site, Screen Modeling OFFSITE
1 Point source; 26 receptors up to 50 KM way; Vapor.
MODELING OPTIONS USED: CONC RURAL ELEV
GRORIS NOSTD
09/K/95
12:S9:48
PAGE 2
POINT SOURCE DATA
SOURCE
ID
NUMBER
PART.
CATS.
EMISSION RATE BASE STACK STACK STACK STACK
(GRAMS/SEC) X Y ELEV. HEIGHT TEMP. EXIT VEL. DIAMETER
(METERS) (METERS) (METERS) (METERS) (DEC.K) (M/SEC) (METERS)
BUILDING EMISSION RATE
EXISTS SCALAR VARY
BY
OFFSITE
0.10000E+01
0.0
0.0 216.4 38.00 997.00
0.22 30.59
NO
-------
1SCONDEP VERSION W227 "* " WTI Truck Accident Off-Site, Screen Modeling -- OFFSITE ** 09/U/95
** 1 Point source; 26 receptors up to 50 KM away; Vspor. 12:59:4fi
PAGE 3
MODELING OPTIONS USED: CONC RURAL ELEV CRDRIS NOSTD
* SOURCE IDs DEFINING SOURCE GROUPS
GROUP ID SOURCE IDs
ALL OFFSITE ,
-------
ISCOWEP VERSION 94227 WTI Truck Accident Off-Site, Screen Modeling -- OFFSITE » 09/U/95
** 1 Point source; 26 receptors up to 50 KM away; Vapor. * 12:59:48
PAGE 4
MODELING OPTIONS USED: CONC RURAL ELEV GRDRIS NOSTD
*** SOURCE PARTICULATE/GAS DATA ***
* SOURCE ID « OFFSITE ; SOURCE TYPE « POINT
SCAV COEF CLIQ] V(S-NM/HR)«
O.OOE+00,
SCAV COEF [ICE] 1/(S-MM/HR)=
O.OOE+00,
-------
ISCOCEP VERSION 94227
VTI Truck Accident Off-Site, Screen Modeling -- OFFSITE
1 Point source; 26 receptors up to 50 KM away; Vapor.
MODELING OPTIONS USED: CONC RURAL ELEV
CRDRIS NOSTD
09/U/95
12:59:48
PAGE 5
* DISCRETE CARTESIAN RECEPTORS «
(X-COORO, Y-COORD, ZELEV, ZFLAG)
(METERS)
(
(
(
(
t
c
(
(
(
(
(
(
(
100.0,
300.0,
500.0,
700.0,
900.0,
1250.0.
1750.0,
2250.0,
3000.0,
5000.0,
10000.0,
20000.0,
40000.0,
o.o.
o.o,
0.0,
o.o.
o.o,
0.0,
o.o,
0.0,
0.0,
0.0,
o.o,
o.o.
o.o,
292.6,
328.0,
359.7,
356.6,
359.7,
361.5,
359.7,
371.9,
408.4, '
415.4.
426.7,
420.0.
420.0,
0.0);
0.0);
0.0);
0.0);
0.0);
0.0);
0.0);
0.0);
0.0);
0.0);
0.0);
0.0);
0.0);
( 200.0,
( 400.0,
( 600.0,
( 800.0,
( 1000.0,
( 1500.0,
( 2000.0,
( 2500.0,
( 4000.0,
( 7500.0,
( 15000.0,
( 30000.0,
( 50000.0,
o.o.
o.o,
o.o,
0.0,
0.0,
o.o.
0.0,
0.0,
0.0,
0.0,
0.0,
0.0,
0.0,
304.8.
347.5,
359.7,
359.7.
371.9,
359.7.
365.8.
408.4,
420.6,
408.4,
420.0,
420.0,
420.0,
0.0);
0.0);
0.0);
0.0);
0.0);
0.0);
0.0);
0.0);
0.0);
0.0);
0.0);
0.0);
0.0);
-------
1SCOMDEP VERSION 94227
WTI Truck Accident Off-Site. Screen Modeling -- OFFSITE
1 Point source; 26 receptors up to 50 KM away; Vapor.
MODELING OPTIONS USED: CONC RURAL ELEV
GRDRIS NOSTD
09/U/95
12:59:46
PAGE 6
METEOROLOGICAL DAYS SELECTED FOR PROCESSING
(1-YES; 0-NO)
11111
11111
11111
11111
11111
11111
11111
11111
1 1
1
1
J
4
1
1
1 1
I 1 1
1 1 1
1 1
1 1
1 1
1 1
1 1
1111
1111
1111
1111
1111
1111
1111
1111
111111
111111
111111
11111
11111
11111
11111
1
11111
11111
11111
11111
11111
11111
11111'
1
1 1 1
1 1 1
1 1 1
1 1 1
1 1 1
1 1 1
1 1 1
1111111111 1111111111
1111111111 1111111111
1111111111 1111111111
1111111111 1111111111
1111111111 1111111111
1111111111 1111111111
1111111111 1111111111
NOTE: METEOROLOGICAL DATA ACTUALLY PROCESSED WILL ALSO DEPEND ON WHAT IS INCLUDED IN THE DATA FILE.
UPPER BOUND OF FIRST THROUGH FIFTH WIND SPEED CATEGORIES
(METERS/SEC)
1.54, 3.09, 5.14, 8.23, 10.80,
WIND PROFILE EXPONENTS
STABILITY
CATEGORY
A
B
C
D
E
F
WIND SPEED CATEGORY
1
.70000E-01
-70000E-01
.10000E+00
.150006+00
.350006+00
.55000E+00
2
.70000E-01
.70000E-01
.100006+00
.150006+00
.350006+00
.550006*00
3
.70000E-01
.700006-01
.100006 --00
.150006+00
.350006+00
.550006+00
4
.700006-01
.70000E-01
.100006+00
.150006+00
.350006+00
.550006+00
5
.70000E-01
.70000E-01
.10000E+00
.150006+00
.350006+00
.55000E+00
6
.70000E-01
.70000E-01
.100006+00
.15000E+00
.350006+00
.55000E+00
VERTICAL POTENTIAL TEMPERATURE GRADIENTS
(DEGREES KELVIN PER METER)
STABILITY
CATEGORY
A
B
C
D
E
F
WIND SPEED CATEGORY
1
.OOOOOE+00
.OOOOOE+00
.OOOOOE+00
.000006*00
.200006-01
.350006-01
2
.OOOOOE+00
.OOOOOE+00
.OOOOOE+00
.OOOOOE+00
.200006-01
.350006-01
3
.OOOOOE+00
.OOOOOE+00
.OOOOOE+00
.000006+00
.200006-01
.350006-01
4
.OOOOOE+00
.000006+00
.000006+00
.000006+00
.200006-01
.350006-01
5
.000006+00
.OOOOOE+00
.000006+00
.OOOOOE+00
.200006-01
.350006-01
6
.OOOOOE+00
.OOOOOE+00
.OOOOOE+00
.000006+00
.200006-01
.350006-01
-------
ISCOMDEP VERSION 94227
WTI True* Accident Off-Site. Screen Modeling OFFSITE
1 Point source; 26 receptors tp to 50 0* »«y; Vapor.
MODELING OPTIONS USED: CONC RURAL ELEV
GRDR1S NOSTO
09/U/95
12:59:48
PAGE 7
THE FIRST 24 HOURS OF METEOROLOGICAL DATA
FILE: screen.met
SURFACE STATION NO.: 94823
NAME: UNKNOWN
YEAR: 1993
FORMAT: <4I2,2F9.4,F6.1,l2,2F7.l,f9.4,f10.1.f8.4,f5.1, J4,f7.2)
UPPER AIR STATION NO.: 94823
NAME: UNKNOWN
YEAR: 1993
FLOW SPEED TEMP STAB MIXING HEIGHT (M) USTAR M-0 LENGTH Z-0 Zd IPCCOE PR
YEAR MONTH DAY HOUR VECTOR (M/S) (K) CLASS RURAL URBAN (n
93
93
93
93
93
93
93
93
93
93
93
93
93
93
93
93
93
93
93
93
93
93
93
93
1
1
1
)
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
I 1
I 2
1 3
1 4
1 5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
I 20
I 21
I 22
23
24
90.0
90.0
90.0
90.0
90.0
90.0
90.0
90.0
90.0
90.0
90.0
90.0
90.0
90.0
90.0
90.0
90.0
90.0
90.0
90.0
90.0
90.0
90.0
90.0
1.00
1.50
2.00
2.50
3.00
1.00
1.50
2.00
2.50
3.00
3.50
4.00
4.50
5.00
1.00
1.50
2.00
2.50
3.00
3.50
4.00
4.50
5.00
8.00
293.1
293.1
293.1
293.1
293.1
293.1
293.1
293.1
293.1
293.1
293.1
293.1
293.1
293.1
293.1
293.1
293.1
293.1
293.1
293.1
293.1
293.1
293.1
293.1
1
1
1
1
1
2
2
2
2
2
2
2
2
2
3
3
3
3
3
3
3
3
3
3
320.0
480.0
640.0
800.0
960.0
320.0
480.0
640.0
800.0
960.0
1120.0
1280.0
1440.0
1600.0
320.0
480.0
640.0
800.0
960.0
1120.0
1280.0
1440.0
1600.0
2560.0
320.0
480.0
640.0
800.0
960.0
320.0
480.0
640.0
800.0
960.0
1120.0
1280.0
1440.0
1600.0
320.0
480.0
640.0
800.0
960.0
1120.0
1280.0
1440.0
1600.0
2560.0
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0
O.X)
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
NOTES: STABILITY CLASS 1«A, 2»B, 3«C. 4«0. 5-E AND 6-F.
FLOW VECTOR IS DIRECTION TOWARD WHICH WIND IS BLOWING.
-------
ISCOHDEP VERSION 94227
WTI Truck Accident Off-Site, Screen Modeling -- OFFSITE
1 Point tource; 26 receptors up to 50 KM May; Vapor.
MODELING OPTIONS USED: CONC RURAL ELEV
GRDRIS NOSTD
09/H/9S
12:59:48
PACE 8
CONCURRENT 1-HR AVERAGE CONCENTRATION
FOR SOURCE GROUP: ALL
INCLUDING SOURCE(S): OFFSITE ,
VALUES ENDING WITH HOUR 1 FOR DAY 1
** DISCRETE CARTESIAN RECEPTOR POINTS
CONC OF FUGITIVE IN MICROGRAMS/M**3
X-COORD (M) Y-COORD (M)
CONC
X-COORD (M) Y-COORD (M)
CONC
100.00
300.00
500.00
700.00
900.00
1250.00
1750.00
2250.00
3000.00
5000.00
10000.00
20000.00
40000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.81890
0.00000
0.00000
er. ooooo
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
200.00
400.00
600.00
800.00
1000.00
1500.00
2000.00
2500.00
4000.00
7500.00
15000.00
30000.00
50000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
-------
tSCOMDEP VERSION 94227
WTI Truck Accident Off-Site, Screen Modeling -- OFFSITE
1 Point source; 26 receptors op to 50 KM way; Vapor.
MODELING OPTIONS USED: CONC RURAL ELEV
GRDRIS NOSTD
09/U/95
12:59:48
PAGE 9
CONCURRENT 1-HR AVERAGE CONCENTRATION
FOR SOURCE GROUP: ALL
INCLUDING SOURCE(S): OFFSITE ,
VALUES ENDING WITH HOUR 2 FOR DAY 1
DISCRETE CARTESIAN RECEPTOR POINTS
OWC OF FUGITIVE IN NICROGRAMS/M**3
X-COORD
CONC
100.00
300.00
500.00
700.00
900.00
1250.00
1750.00
2250.00
3000.00
5000.00
10000.00
20000.00
40000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
t. 09211
0.59055
0.75027
o.ooooo
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
200.00
400.00
600.00
800.00
1000.00
1500.00
2000.00
2500.00
4000.00
7500.00
15000.00
30000.00
50000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.62507
0.61457
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
-------
ISCOMDEP VERSION 94227
UTI Truck Accident Off-Site, Screen Modeling -- OFFSITE
1 Point »ouree; 26 receptors 143 to 50 KM «t*ay; Vapor.
** MODELING OPTIONS USED: CONC RURAL ELEV
GRORIS NOSTD
09/U/95
12:59:48
PAGE 10
CONCURRENT 1-HR AVERAGE CONCENTRATION VALUES ENDING WITH HOUR 3 FOR DAT 1
FOR SOURCE GROUP: ALL
INCLUDING SOURCE(S): OFFSITE ,
* DISCRETE CARTESIAN RECEPTOR POINTS *
CONC OF FUGITIVE IN MIC*OGRAMS/**«3 *
X-COORD (M) Y-COORD (M)
CONC
X-COORD (M) Y-COORD (M)
CONC
100.00
300.00
500.00
700.00
900.00
1250.00
1750.00
2250.00
3000.00
5000.00
10000.00
20000.00
40000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
1 .55244
1.17569
1.46886
-1.62981
1.62013
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
200.00
400.00
600.00
800.00
1000.00
1500.00
2000.00
2500.00
4000.00
7500.00
15000.00
30000.00
50000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
1.08747
1.29777
1.62803
1.60347
1.64727
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
-------
ISCOMDEP VERSION 94227
WTI Truck Accident Off-Site, Screen Modeling -- OFFSITE
1 Point source; 26 receptor* up to SO KM away; Vapor.
** MODELING OPTIONS USED: CONC RURAL ELEV
GRDRIS NOSTD
09/U/95
12:59:48
PACE 11
CONCURRENT 1-HR AVERAGE CONCENTRATION VALUES ENDING WITH HOUR 4 FOR DAT
FOR SOURCE GROUP: ALL
INCLUDING SOURCE(S): OFFSITE ,
*** DISCRETE CARTESIAN RECEPTOR POINTS "*
* CONC OF FUGITIVE IN NICROGRAMS/M**3 **
X-COORD <*) Y-COORO
CONC
X-COORD (M) Y-COORO CM)
CONC
100.00
300.00
500.00
700.00
900.00
1250.00
1750.00
2250.00
3000.00
5000.00
10000.00
20000.00
40000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
2.27503
2.10901
2.37484
2.02377
1.41099
0.92261
0.66265
0.51540
0.38655
0.23193
0.11740
0.065S2
0.03689
200.00
400.00
600.00
800.00
1000.00
1500.00
2000.00
2500.00
4000.00
7500.00
15000.00
30000.00
50000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
1.84501
2.28176
2.29886
1.71558
1.19607
0.77306
0.57982
0.46386
0.28991
0.15462
0.08340
0.04676
0.03074
-------
ISCONDEP VERSION 94227
UTI Truck Accident Off-Site, Screen Modeling -- OFFSITE
1 Point source; 26 receptors up to SO KM away; Vapor.
MODELING OPTIONS USED: CONC RURAL ELEV
GRORIS NOSTD
09/K/9S
12:59:48
PAGE 12
CONCURRENT 1-HR AVERAGE CONCENTRATION
FOR SOURCE CROUP: ALL
INCLUDING SOURCE(S): OFFSITE ,
VALUES ENDING WITH HOUR 5 FOR DAY 1
DISCRETE CARTESIAN RECEPTOR POINTS
* CONC OF FUGITIVE IN MIC*OGRAMS/M**3
X-COORD (M) Y-COORD (M)
CONC
X-COORD (M) Y-COORD (M>
CONC
100.00
300.00
500.00
700.00
900.00
1250.00
1750.00
2250.00
3000.00
5000.00
10000.00
20000.00
40000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
3.34302
3.35501
3.20150
2.20528
1.35652
0.66945
0.46018
0.35791
0.26844
0.16106
0.08163
0.04552
0.02562
200.00
400.00
600.00
800.00
1000.00
1500.00
2000.00
2500.00
4000.00
7500.00
15000.00
30000.00
50000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
2.95250
3.40608
2.74879
1.74341
1.07026
0.53763
0.40265
0.32212
0.20133
0.10737
0.05796
0.03248
0.02135
-------
1SCOMDEP VERSION 94227
UTI Truck Accident Off-Site, Screen Modeling -- OFFSITE
1 Point source; 26 receptors up to 50 KM away; Vapor.
MODELING OPTIONS USED: CONC RURAL ELEV
GRDRIS NOSTD
09/U/95
12:59:48
PAGE 13
CONCURRENT 1-HR AVERAGE CONCENTRATION
FOR SOURCE GROUP: ALL
INCLUDING SOURCE(S): OFFSITE ,
VALUES ENDING WITH HOUR 6 FOR DAY 1 ***
DISCRETE CARTESIAN RECEPTOR POINTS
CONC OF FUGITIVE IN MICROGRAMS/M**3
X-COORD (M) Y-COORD (M)
COHC
X-COORD (M) Y-COORD (N)
CONC
100.00
300.00
500.00
700.00
900.00
1250.00
1750.00
2250.00
3000.00
5000.00
10000.00
20000.00
40000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.73782
0.00000
0.00000
-o.ooooo
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
200.00
400.00
600.00
800.00
1000.00
1500.00
2000.00
2500.00
4000.00
7500.00
15000.00
30000.00
50000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00000
0.00000
0.00000
0.00000
0.00000
o.ooooo
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
-------
ISCOMDEP VERSION 94227
UTI Truck Accident Off-Site, Screen Modeling OFFSITE
1 Point source; 26 receptor* up to 50 KM away; Vapor.
MODELING OPTIONS USED: CONC RURAL ELEV
GRORIS NOSTD
09/U/95
12:59:48
PACE U
CONCURRENT 1-HR AVERAGE CONCENTRATION
FOR SOURCE CROUP: ALL
INCLUDING SOURCE(S): OFFSITE ,
VALUES ENDING WITH HOUR 7 FOR DAY 1 **
DISCRETE CARTESIAN RECEPTOR POINTS
* CONC OF FUGITIVE IN NICROGRAMS/H"«3
X-COORD (M) Y-COORD (M)
CONC
X-COORO (M) Y-COORD (M)
CONC
100.00
300.00
500.00
700.00
900.00
1250.00
1750.00
2250.00
3000.00
5000.00
10000.00
20000.00
40000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.88183
0.33234
0.21296
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
200.00
400.00
600.00
800.00
1000.00
1500.00
2000.00
2500.00
4000.00
7500.00
15000.00
30000.00
50000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.42052
0.26377
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
-------
1SCOM>EP VERSION 94227
tfTI Truck Accident Off-Site. Screen Modeling -- OFFSITE
1 Point source; 26 receptors tp to 50 KH *tMy; Vapor.
MODELING OPTIONS USED: CONC RURAL ELEV
GRORIS NOSTD
09/U/95
12:59:48
PAGE 15
CONCURRENT 1-HR AVERAGE CONCENTRATION
FOR SOURCE GROUP: ALL
INCLUDING SOURCECS): OFFSITE ,
VALUES ENDING WITH HOUR 8 FOR DAY 1 *"«
*** DISCRETE CARTESIAN RECEPTOR POINTS
* CONC OF FUGITIVE IN MICRCC»AMS/K**3
X-COORD (M) Y-COORD OO
CONC
X-COORD (N) Y-COORD (M)
CONC
100.00
300.00
500.00
700.00
900.00
1250.00
1750.00
2250.00
3000.00
5000.00
10000.00
20000.00
40000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
1.10912
0.55083
0.38747
0. 23023
0.17402
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
200.00
400.00
600.00
800.00
1000.00
1500.00
2000.00
2500.00
4000.00
7500.00
15000.00
30000.00
50000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.61332
0.46774
0.29377
0.20016
0.16905
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
-------
ISCOMDEP VERSION 94227
tfTI Truck Accident Off-Site, Screen Modeling -- OFFSITE
1 Point source; 26 receptors up to 50 KM away; Vapor.
MODELING OPTIONS USED: CONC RURAL ELEV
GXDRIS NOSTO
09/14/95
12:59:48
PAGE 16
CONCURRENT 1-HR AVERAGE CONCENTRATION VALUES ENDING WITH HOUR
FOR SOURCE GROUP: ALL
INCLUDING SOURCE(S): OFFSITE ,
*** DISCRETE CARTESIAN RECEPTOR POINTS **
CONC OF FUGITIVE IN MICROGRAMS/M**3
X-COORD (M) Y-COORD (M)
CONC
X-COORD (M) Y-COORD (M)
9 FOR DAY 1
CONC
100.00
300.00
500.00
700.00
900.00
1250.00
1750.00
2250.00
3000.00
5000.00
10000.00
20000.00
40000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
1.44608
0.90330
0.68065
-0.40882
0.31138
0.22177
0.31509
0.36427
0.35387
0.27006
0.15368
0.08501
0.04730
200.00
400.00
600.00
800.00
1000.00
1500.00
2000.00
2500.00
4000.00
7500.00
15000.00
30000.00
50000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.91202
0.80214
0.51961
0.35741
0.30266
0.27135
0.34855
0.38863
0.30555
0.19640
0.10865
0.06027
0.03924
-------
ISCOMDEP VERSION 94227
UTI Truck Accident Off-Site, Screen Modeling -- OFFSITE
1 Point source; 26 receptors up to SO KM away; Vapor.
MODELIMG OPTIONS USED: CONC RURAL ELEV
GRDRIS NOSTD
09/H/95
12:59:48
PAGE 17
CONCURRENT 1-HR AVERAGE CONCENTRATION VALUES ENDING WITH HOUR 10 FOR DAY 1
FOR SOURCE GROUP: ALL
INCLUDING SOURCE(S): OFFSITE ,
» DISCRETE CARTESIAN RECEPTOR POINTS **
* CONC OF FUGITIVE IN K1CROGRAMS/M*«3 *
X-COORD (M) Y-COORD (M)
CONC
X-COORD (M) Y-COORD (N)
CONC
100.00
300.00
500.00
700.00
900.00
1250.00
1750.00
2250.00
3000.00
5000.00
10000.00
20000.00
40000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
1.92557
1.42867
1.10621
0.65979
0.49681
0.34430
0.42503
0.42845
0.35660
0.20341
0.10695
0.05907
0.03285
200.00
400.00
600.00
800.00
1000.00
1500.00
2000.00
2500.00
4000.00
7500.00
15000.00
30000.00
50000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
1.35182
1.29651
0.84213
0.57385
0.47862
0.39451
0.43721
0.42889
0.26007
0.13720
0.07553
0.04187
0.02726
-------
ISCOMDEP VERSION 94227
VTI Truck Accident Off-Site, Screen Modeling -- OFFSITE
1 Point source; 26 receptors up to 50 KM May; Vapor.
MODELING OPTIONS USED: CONC RURAL ELEV
GRORIS NOSTD
09/U/95
12:59:4B
PAGE 18
CONCURRENT 1-HR AVERAGE CONCENTRATION
FOR SOURCE GROUP: ALL
INCLUDING SOURCE(S): OFFSITE ,
VALUES ENDING WITH HOUR 11 FOR DAT 1
« DISCRETE CARTESIAN RECEPTOR POINTS
** CONC OF FUGITIVE IN NICROGRAMS/M**3
X-COORD (M) Y-COORD (N)
CONC
X-COORD (N) Y-COORD (M)
CONC
100.00
300.00
500.00
700.00
900.00
1250.00
1750.00
2250.00
3000.00
5000.00
10000.00
20000.00
40000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
2.58426
2.14864
1.65292
0.96723
0.71214
0.47503
0.50958
0.46113
0.34819
0.17370
0.07873
0.04342
0.02414
200.00
400.00
600.00
800.00
1000.00
1500.00
2000.00
2500.00
4000.00
7500.00
15000.00
30000.00
50000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
1.96470
1.95U9
1.24624
0.83159
0.67593
0.50657
0.49384
0.44104
0.24054
0.10298
0.05553
0.03076
0.02003
-------
ISCQMDEP VERSION 94227
*** VTI Truck Accident Off-Site, Screen Modeling -- OFFSITE
"* 1 Point «ource; 26 receptors ip to 50 KM et«y; Vapor.
*** MODELING OPTIONS USED: CONC RURAL ELEV
CRDRIS NOSTD
09/U/95
12:59:48
PAGE 19
CONCURRENT 1-HR AVERAGE CONCENTRATION
FOR SOURCE GROUP: ALL
INCLUDING SOURCE(S): OFFSITE ,
VALUES ENDING WITH HOUR 12 FOR DAY
*** DISCRETE CARTESIAN RECEPTOR POINTS
* CONC OF FUGITIVE IN MICROGRANS/M**3
X-COORD (M) Y-COORD (M)
CONC
X-COORD (M) Y-COORD (M)
CONC
100.00
300.00
500.00
700.00
900.00
1250.00
1750.00
2250.00
3000.00
5000.00
10000.00
20000.00
40000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
3.45842
3.05698
2.28199
- 1.30217
0.93335
0.59801
0.56611
0.47128
0.33303
0.15583
0.06060
0.03325
0.01848
200.00
400.00
600.00
800.00
1000.00
1500.00
2000.00
2500.00
4000.00
7500.00
15000.00
30000.00
50000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
2.77124
2.74778
1.69778
1.10362
0.87100
0.59625
0.52340
0.43575
0.22346
0.08284
0.04253
0.02356
0.01533
-------
ISCOMDEP VERSION 94227
WTI Truck Accident Off-Site, Screen Modeling -- OFFSITE
1 Point source; 26 receptors up to 50 KM away; Vapor.
MODELING OPTIONS USED: CONC RURAL ELEV
CRDRIS HOSTD
09/14/95
12:59:45
PAGE 20
CONCURRENT 1-HR AVERAGE CONCENTRATION
FOR SOURCE GROUP: ALL
INCLUDING SOURCE(S): OFFSITE ,
VALUES ENDING WITH HOUR 13 FOR DAT 1
DISCRETE CARTESIAN RECEPTOR POINTS
CONC OF FUGITIVE IN KIC80GRA*S/ir*3
X-COORD (M) Y-COORD (M)
CONC
X-COORD (M) Y-COORD (N)
CONC
100.00
300.00
500.00
700.00
900.00
1250.00
1750.00
2250.00
3000.00
5000.00
10000.00
20000.00
40000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
4.57867
4.11814
2.94028
1. 63354
1.13951
0.70301
0.59867
0.46740
0.31939
0.14195
0.04858
0.02628
0.01461
200.00
400.00
600.00
800.00
1000.00
1500.00
2000.00
2500.00
4000.00
7500.00
15000.00
30000.00
50000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
3.77421
3.62343
2.15603
1.36412
1.04568
0.66094
0.53355
0.42131
0.20724
0.07053
0.03362
0.01861
0.01212
-------
1SCOMDEP VERSION 94227
WTI Truck Accident Off-Site, Screen Modeling - OFFSITE
1 Point source; 26 receptors ip to 50 KM away; Vapor.
MODELING OPTIONS USED: CONC RURAL ELEV
GRORIS NOSTD
09/14/95
12:59:48
PAGE 21
CONCURRENT 1-HR AVERAGE CONCENTRATION
FOR SOURCE GROUP: ALL
INCLUDING SOURCE(S): OFFSITE ,
VALUES ENDING WITH HOUR U FOR DAY 1
DISCRETE CARTESIAN RECEPTOR POINTS
X-COORD (N> Y-COORD (M)
CONC OF FUGITIVE IN MICROGRAMS/KM3
CONC
X-COORD (H) Y-COORD (N)
CONC
100.00
300.00
500.00
TOO. 00
900.00
1250.00
1750.00
2250.00
3000.00
5000.00
10000.00
20000.00
40000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
5.96480
5.27547
3.57619
1.93669
1.31723
0.78588
0.61309
0.45548
0.30380
0.13020
0.04047
0.02129
0.01183
200.00
400.00
600.00
800.00
1000.00
1500.00
2000.00
2500.00
4000.00
7500.00
15000.00
30000.00
50000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
4.95626
4.51893
2.58555
1.59475
1.19007
0.70301
0.53095
0.40264
0.19232
0.06240
0.02724
0.01508
0.00981
-------
ISCOMDEP VERSION 94227
VTI Truck Accident Off-Site, Screen Modeling -- OFFSITE
1 Point tource; 26 receptors up to 50 KM away; Vapor.
09/14/95
12:59:48
PAGE 22
** MODELING OPTIONS USED: CONC RURAL ELEV
GRDRIS HOSTD
CONCURRENT 1-HR AVERAGE CONCENTRATION VALUES ENDING WITH HOUR 15 FOR DAY 1
FOR SOURCE GROUP: ALL
INCLUDING SOURCE(S): OFFSITE ,
*** DISCRETE CARTESIAN RECEPTOR POINTS ***
** CONC OF FUGITIVE IN MIOtOGRAMS/M**3 *
X-COORD (M) Y-COORD (M)
CONC
X-COORD (N) Y-COORD (N)
CONC
100.00
300.00
500.00
700.00
900.00
1250.00
1750.00
2250.00
3000.00
5000.00
10000.00
20000.00
40000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.68894
0.00000
0.00000
D. 00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
200.00
400.00
600.00
800.00
1000.00
1500.00
2000.00
2500.00
4000.00
7500.00
15000.00
30000.00
50000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
-------
ISCOMDEP VERSION 94227
WTI Truck Accident Off-Site, Screen Modeling -- OFFSITE
1 Point source; 26 receptors up to 50 KM way; Vapor.
MODELING OPTIONS USED: CONC RURAL ELEV
GRDRIS NOSTD
09/U/95
12:59:48
PAGE 23
CONCURRENT 1-HR AVERAGE CONCENTRATION VALUES ENDING WITH HOUR 16 FOR DAT 1
FOR SOURCE GROUP: ALL
INCLUDING SOURCE(S): OFFSITE ,
* DISCRETE CARTESIAN RECEPTOR POINTS ""
" CONC OF FUGITIVE IN MCROGRAM$/K**3 "
X-COORD (M) Y-COORD (M)
CONC
X-COORD (M) Y-COORD (M)
CONC
100.00
300.00
500.00
700.00
900.00
1250.00
1750.00
2250.00
3000.00
5000.00
10000.00
20000.00
40000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.76179
0.26741
0.15277
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
200.00
400.00
600.00
800.00
1000.00
1500.00
2000.00
2500.00
4000.00
7500.00
15000.00
30000.00
50000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.34938
0.20527
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
-------
ISCOMDEP VERSION 94227
UTI Truck Accident Off-Site, Screen Modeling -- OFFSITE
1 Point source; 26 receptors up to 50 KM away; Vapor.
*** MODELING OPTIONS USED: CONC RURAL ELEV
GRDRIS NOSTD
09/U/95
12:59:48
PACE 24
CONCURRENT 1-HR AVERAGE CONCENTRATION
FOR SOURCE GROUP: ALL
INCLUDING SOURCE(S): OFFSITE ,
VALUES ENDING WITH HOUR 17 FOR DAY 1
** DISCRETE CARTESIAN RECEPTOR POINTS
** CONC OF FUGITIVE IN MICROGRAMS/N**3
X-COORD (M) Y-COORD (M)
CONC
X-COORD (M) Y-COORD (M)
CONC
100.00
300.00
500.00
700.00
900.00
1250.00
1750.00
2250.00
3000.00
5000.00
10000.00
20000.00
40000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.87063
0.39519
0.24606
0". 11893
0.07669
0.04468
0.05217
0.07082
0.11294
0.24819
0.30443
0.17898
0.09797
200.00
400.00
600.00
800.00
1000.00
1500.00
2000.00
2500.00
4000.00
7500.00
15000.00
30000.00
50000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.45629
0.32323
0.16816
0.09554
0.07120
0.04701
0.06386
0.09477
0.18240
0.32083
0.22927
0.12577
0.08075
-------
ISCOMDEP VERSION 94227
WTI Truck Accident Off-Site, Screen Modeling -- OFFSITE
1 Point source; 26 receptors up to 50 KM away; Vapor.
MODELING OPTIONS USED: CONC RURAL ELEV
GRORIS NOSTD
09/H/95
12:59:43
PAGE 25
CONCURRENT 1-hft AVERAGE CONCENTRATION VALUES ENDING WITH HOUR 18 FOR DAT
FOR SOURCE GROUP: ALL
INCLUDING SOURCE(S): OFFSITE ,
** DISCRETE CARTESIAN RECEPTOR POINTS ***
** CONC OF FUGITIVE IN MICROGRAMS/K*«3 *
X-COORD (M) Y-COORD (M)
CONC
X-COORD (N) Y-COORD (N)
CONC
100.00
300.00
500.00
700.00
900.00
1250.00
1750.00
2250.00
3000.00
5000.00
10000.00
20000.00
40000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
1.02308
0.58794
0.39393
- 0.18814
0.12210
0.07006
0.08705
0.11957
0.17840
0.23852
0.19646
0.11475
0.06274
200.00
400.00
600.00
800.00
1000.00
1500.00
2000.00
2500.00
4000.00
7500.00
15000.00
30000.00
50000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.60938
0.50678
0.26789
0.15194
0.11529
0.07642
0.10303
0.16053
0.21262
0.22802
0.14648
0.08058
0.05171
-------
ISCOMDEP VERSION 94227
VTI Truck Accident Off-Site, Screen Nodeling -- OFFSITE
1 Point source; 26 receptors up to 50 KM away; Vapor.
MODELING OPTIONS USED: CONC RURAL ELEV
GRDRIS NOSTD
09/U/95
12:59:43
PAGE 26
CONCURRENT 1-HR AVERAGE CONCENTRATION VALUES ENDING WITH HOUR 19 FOR DAY 1
FOR SOURCE GROUP: ALL
INCLUDING SOURCE(S): OFFSITE ,
DISCRETE CARTESIAN RECEPTOR POINTS *
* CONC OF FUGITIVE IN NICROGRAI«/II**3
X-COORD (M) Y-COORD (M)
CONC
X-COORD (M) Y-COORD (M)
CONC
100.00
300.00
500.00
700.00
900.00
1250.00
1750.00
2250.00
3000.00
5000.00
10000.00
20000.00
40000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
1.22892
0.86845
0.61432
- 0.29106
0.18973
0.10954
0.14038
0.18745
0.2S285
0.28522
0.16651
0.08018
0.04358
200.00
400.00
600.00
800.00
1000.00
1500.00
2000.00
2500.00
4000.00
7500.00
15000.00
30000.00
50000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.82335
0.77877
0.41638
0.23590
0.18104
0.12236
0.16482
0.24269
0.28284
0.22481
0.10601
0.05599
0.03592
-------
ISCOMDEP VERSION 94227
VTJ Truck Accident Off-Site, Screen Modeling -- OFFSITE
1 Point source; 26 receptors up to 50 KM away; Vapor.
MODELIMG OPTIONS USED: CONC RURAL ELEV
GRORIS NOSTD
09/U/95
12:59:48
PACE 27
CONCURRENT 1-HR AVERAGE CONCENTRATION VALUES ENDING WITH HOUR 20 FOR DAT 1
FOR SOURCE GROUP: ALL
INCLUDING SOURCE(S): OFFSITE ,
* DISCRETE CARTESIAN RECEPTOR POINTS **
* CONC OF FUGITIVE IN NICROGRANS/M**3 *
X-COORD (M) Y-COORD (N)
CONC
X-COORD (M) Y-COORD (M)
CONC
100.00
300.00
500.00
700.00
900.00
1250.00
1750.00
2250.00
3000.00
5000.00
10000.00
20000.00
40000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
1.49996
1.25983
0.92247
- 0.43443
0.28352
0.16389
0.20759
0.26172
0.31608
0.31119
0.15263
0.06066
0.03203
200.00
400.00
600.00
800.00
1000.00
1500.00
2000.00
2500.00
4000.00
7500.00
15000.00
30000.00
50000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
1.11479
1.15989
0.62356
0.35259
0.27185
0.18340
0.23761
0.32364
0.33463
0.21949
0.08631
0.04118
0.02639
-------
ISCOMDEP VERSION 94227
WTI Truck Accident Off-Site, Screen Modeling -- OFFSITE
1 Point source; 26 receptors up to 50 KM way; Vspor.
MODELING OPTIONS USED: CONC RURAL ELEV
GRDRIS NOSTD
09/U/95
12:59:48
PAGE 28
CONCURRENT 1-HR AVERAGE CONCENTRATION
FOR SOURCE GROUP: ALL
INCLUDING SOURCE(S): OFFSITE ,
VALUES ENDING WITH HOUR 21 FOR DAY 1
** DISCRETE CARTESIAN RECEPTOR POINTS
** CONC OF FUGITIVE IN MICROGRAMS/MM3
X-COORD (M) Y-COORD (M)
CONC
X-COORD (M) Y-COORD (M)
CONC
100.00
300.00
500.00
700.00
900.00
1250.00
1750.00
2250.00
3000.00
5000.00
10000.00
20000.00
40000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
1.84974
1.78126
1.32556
- 0.62105
0.40456
0.23305
0.28341
0.33334
0.37818
0.32169
0.14082
0.04941
0.02453
200.00
400.00
600.00
800.00
1000.00
1500.00
2000.00
2500.00
4000.00
7500.00
15000.00
30000.00
50000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
1 .50061
1.66318
0.89375
0.50371
0.38794
0.25704
0.31363
0.39338
0.36796
0.20971
0.07525
0.03167
0.02021
-------
ISCOMDEP VERSION 94227
UT1 Truck Accident Off-Site, Screen Modeling -- OFFSITE
1 Point source; 26 receptors up to 50 KM way; Vapor.
09/U/95
12:59:48
PAGE 29
MODELING OPTIONS USED: CONC RURAL ELEV
GRORIS NOSTD
CONCURRENT 1-HR AVERAGE CONCENTRATION
FOR SOURCE GROUP: ALL
INCLUDING SOURCE(S): OFFSITE ,
VALUES ENDING WITH HOUR 22 FOR DAY 1
DISCRETE CARTESIAN RECEPTOR POINTS
CONC OF FUGITIVE IN NICROGRAMS/N**3
X-COORD (M) Y-COORD (M)
CONC
X-COORD (M) Y-COORD (M)
CONC
100.00
300.00
500.00
700.00
900.00
1250.00
1750.00
2250.00
3000.00
5000.00
10000.00
20000.00
40000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
2.29270
2.44350
1 .81930
-0.84845
0.55031
0.31487
0.36142
0.39771
0.42908
0.32217
0.12995
0.04254
0.01940
200.00
400.00
600.00
800.00
1000.00
1500.00
2000.00
2500.00
4000.00
7500.00
15000.00
30000.00
50000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
1.99603
2.28925
1.22355
0.68656
0.52589
0.33865
0.38574
0.44738
0.38636
0.19825
0.06761
0.02537
0.01597
-------
ISCQMDEP VERSION 94227
tfTI Truck Accident Off-Site, Screen Modeling -- OFFSITE
1 Point source; 26 receptors up to 50 KM May; Vapor.
D9/U/95
12:59:48
PAGE 30
* MODELING OPTIONS USED: CONC RURAL ELEV
CRDRIS NOSTO
CONCURRENT 1-HR AVERAGE CONCENTRATION VALUES ENDING UITH HOUR 23 FOR DAY 1
FOR SOURCE GROUP: ALL
INCLUDING SOURCE(S): OFFSITE ,
*** DISCRETE CARTESIAN RECEPTOR POINTS **
** CONC OF FUGITIVE IN H1CK)GRA*S/K"*3
X-COORD (M) Y-COORD (M>
CONC
X-COORD (M) Y-COORD (M)
CONC
100.00
300.00
500.00
700.00
900.00
1250.00
1750.00
2250.00
3000.00
5000.00
10000.00
20000.00
40000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
2.84345
3.24546
2.38751
1.10895
0.71502
0.40548
0.43587
0.46577
0.46562
0.31662
0.12017
0.03791
0.01576
200.00
400.00
600.00
800.00
1000.00
1500.00
2000.00
2500.00
4000.00
7500.00
15000.00
30000.00
50000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
2.61234
3.02450
1.60183
0.89428
0.67926
0.42278
0.44908
0.48530
0.39383
0.18659
0.06156
0.02113
0.01294
-------
1SCOMDEP VERSION 94227
WTI Truck Accident Off-Site, Screen Modeling -- OFFSITE
1 Point source; 26 receptors 143 to SO KM away; Vapor.
09/U/95
12:59:48
PAGE 31
MODELING OPTIONS USED: CONC RURAL ELEV
GRDRIS NOSTD
CONCURRENT 1-HR AVERAGE CONCENTRATION VALUES ENDING WITH HOUR 24 FOR DAY 1
FOR SOURCE GROUP: ALL
INCLUDING SOURCE(S): OFFSITE ,
* DISCRETE CARTESIAN RECEPTOR POINTS "**
* CONC OF FUGITIVE IN MJCROGRAMS/M**3 **
X-COORD (N) Y-COORD «)
CONC
X-COORD (M) Y-COORD (N)
CONC
100.00
300.00
500.00
700.00
900.00
1250.00
1750.00
2250.00
3000.00
5000.00
10000.00
20000.00
40000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
2.08867
5.49504
3.77290
2.59060
1.68105
0.90328
0.74650
0.65674
0.37322
0.15551
0.04336
0.01167
0.00321
200.00
400.00
600.00
800.00
1000.00
1500.00
2000.00
2500.00
4000.00
7500.00
15000.00
30000.00
50000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
5.66463
4.60496
3.10751
2.13215
1.52042
0.78533
0.70761
0.49665
0.23038
0.07420
0.02016
0.00540
0.00229
-------
ISCOMDEP VERSION 94227
WTI Truck Accident Off-Site, Screen Modeling -- OFFSITE
1 Point source; 26 receptors up to SO KM away; Vapor.
MODELING OPTIONS USED: CONC RURAL ELEV
GRDRIS NOSTD
09/H/95
12:59:48
PACE 32
CONCURRENT 1-HR AVERAGE CONCENTRATION
FOR SOURCE GROUP: ALL
INCLUDING SOURCE(S): OFFSITE ,
VALUES ENDING WITH HOUR 1 FOR DAY
DISCRETE CARTESIAN RECEPTOR POINTS
** CONC OF FUGITIVE IN NICROGRAMS/M**}
X-COORD (M) Y-COORD (M)
CONC
X-COORD (N) Y-COORD (N)
CONC
100.00
300.00
500.00
700.00
900.00
1250.00
1750.00
2250.00
3000.00
5000.00
10000.00
20000.00
40000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
1.59015
5.58536
3.79475
2.55791
1.81858
1.05858
0.82346
0.50270
0.31392
0.12703
0.03490
0.00935
0.00250
200.00
400.00
600.00
800.00
1000.00
1500.00
2000.00
2500.00
4000.00
7500.00
15000.00
30000.00
50000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
5.59481
4.67075
3.09618
2.14266
1.56203
0.90184
0.73736
0.42498
0.19008
0.05996
0.01618
0.00431
0.00167
-------
1SCOMDEP VERSION 94227
WT1 Truck Accident Off-Site, Screen Modeling -- OFFSITE
1 Point source; 26 receptors ip to 50 KM away; Vapor.
** MODELIMG OPTIONS USED: CONC RURAL ELEV
GRDRIS NOSTD
09/U/95
12:59:48
PACE 33
CONCURRENT 1-HR AVERAGE CONCENTRATION VALUES ENDING WITH HOUR 2 FOR DAY
FOR SOURCE GROUP: ALL
INCLUDING SOURCE(S): OFFSITE ,
*" DISCRETE CARTESIAN RECEPTOR POINTS **
* CONC OF FUGITIVE IN K]CROGRAMS/K*«3 *»
X-COORD (M) Y-COORD (N)
CONC
X-COORD (N) Y-COORD (N)
CONC
100.00
300.00
500.00
700.00
900.00
1250.00
1750.00
2250.00
3000.00
5000.00
10000.00
20000.00
40000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.65923
0.00000
0.00000
t). 00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
200.00
400.00
600.00
800.00
1000.00
1500.00
2000.00
2500.00
4000.00
7500.00
15000.00
30000.00
50000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
-------
ISCOMDEP VERSION 94227
WTI Truck Accident Off-Site, Screen Modeling -- OFTSITE
1 Point source; 26 receptors up to SO KM away; Vapor.
MODELING OPTIONS USED: CONC RURAL ELEV
GRORIS NOSTD
09/U/95
12:59:48
PACE 34
CONCURRENT 1-HR AVERAGE CONCENTRATION
FOR SOURCE CROUP: ALL
INCLUDING SOURCE(S): OFFSITE ,
VALUES ENDING WITH HOUR 3 FOR DAY
DISCRETE CARTESIAN RECEPTOR POINTS
CONC OF FUGITIVE IN NICROGRAMS/M**3
X-COORD (M) Y-COORD (M)
CONC
X-COORD (M) Y-COORD (N)
CONC
100.00
300.00
500.00
700.00
900.00
1250.00
1750.00
2250.00
3000.00
5000.00
10000.00
20000.00
40000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.69152
0.24032
0.13296
e. ooooo
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
200.00
400.00
600.00
800.00
1000.00
1500.00
2000.00
2500.00
4000.00
7500.00
15000.00
30000.00
50000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.31257
0.18268
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
-------
ISCONDEP VERSION 94227
VTI Truck Accident Off-Site, Screen Modeling -- OFFSITE
1 Point source; 26 receptors up to SO KM away; Vapor.
MODELING OPTIONS USED: CONC RURAL ELEV
GRORIS NOSTD
09/U/95
12:59:46
PAGE 35
CONCURRENT 1-HR AVERAGE CONCENTRATION
FOR SOURCE GROUP: ALL
INCLUDING SOURCE(S): OFFSITE ,
VALUES ENDING WITH HOUR 4 FOR DAY
DISCRETE CARTESIAN RECEPTOR POINTS
CONC Of FUGITIVE IN NICROGRAMS/M**3
X-COORD (M) Y-COORD (M)
CONC
X-COORD (N) Y-COORD (N)
CONC
100.00
300.00
500.00
700.00
900.00
1250.00
1750.00
2250.00
3000.00
5000.00
10000.00
20000.00
40000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.73755
0.32853
0.19616
0.08585
0.05166
0.02599
0.02054
0.02044
0.02552
0.02434
0.03544
0.05732
0.07235
200.00
400.00
600.00
800.00
1000.00
1500.00
2000.00
2500.00
4000.00
7500.00
15000.00
30000.00
50000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.37658
0.26505
0.12761
0.06672
0.04744
0.02245
0.02035
0.02721
0.02610
0.02849
0.04756
0.06956
0.07179
-------
ISCOMDEP VERSION 94227
VTI Truck Accident Off-Site, Screen Modeling -- OFFSITE
1 Point source; 26 receptors up to 50 KM away; Vapor.
** MODELING OPTIONS USED: CONC RURAL ELEV
GRDRIS NOSTD
09/U/95
12:59:48
PAGE 36
CONCURRENT 1-HR AVERAGE CONCENTRATION
FOR SOURCE GROUP: ALL
INCLUDING SOURCE(S): OFFSITE .
VALUES ENDING UITH HOUR 5 FOR DAT 2
DISCRETE CARTESIAN RECEPTOR POINTS
** CONC OF FUGITIVE IN NICROGRAMS/M**3
X-COORD (M) Y-COORD (M)
CONC
X-COORD (N) Y-COORD (M)
CONC
100.00
300.00
500.00
700.00
900.00
1250.00
1750.00
2250.00
3000.00
5000.00
10000.00
20000.00
40000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.79885
0.45085
0.28827
0.12062
0.07162
0.03507
0.02900
0.03078
0.04230
0.04323
0.06051
0.07844
0.06906
200.00
400.00
600.00
800.00
1000.00
1500.00
2000.00
2500.00
4000.00
7500.00
15000.00
30000.00
50000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.45966
0.38360
0.18363
0.09339
0.06699
0.03091
0.02971
0.04382
0.04546
0.04929
0.07323
0.07692
0.06145
-------
ISCOMDEP VERSION 94227
UTI Truck Accident Off-Site, Screen Modeling -- OFFSITE
1 Point source; 26 receptors up to 50 KM away; Vapor.
MODELING OPTIONS USED: CONC RURAL ELEV
GRDRIS NOSTD
09/U/95
12:59:48
PAGE 37
CONCURRENT 1-HR AVERAGE CONCENTRATION
FOR SOURCE GROUP: ALL
INCLUDING SOURCE(S): OFFSITE ,
VALUES ENDING WITH HOUR 6 FOR DAY
** DISCRETE CARTESIAN RECEPTOR POINTS
* CONC OF FUGITIVE IN MICROGRAMS/M**3
X-COORD (M) Y-COORD (M)
CONC
X-COORD (M) Y-COORD (M)
CONC
100.00
300.00
500.00
700.00
900.00
1250.00
1750.00
2250.00
3000.00
5000.00
10000.00
20000.00
40000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.87742
0.61811
0.41929
0.16910
0.09937
0.04760
0.04111
0.04600
0.06743
0.07031
0.09418
0.10357
0.07610
200.00
400.00
600.00
800.00
1000.00
1500.00
2000.00
2500.00
4000.00
7500.00
15000.00
30000.00
50000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.56660
0.55069
0.26259
0.13057
0.09441
0.04282
0.04332
0.06864
0.07401
0.07954
0.10449
0.09075
0.06436
-------
ISCONDEP VERSION 94227
VTI Truck Accident Off-Site, Screen Modeling -- OFFSITE
1 Point source; 26 receptors up to SO KM May; Vapor.
MODELING OPTIONS USED: CONC RURAL ELEV
GROR1S NOSTD
09/14/95
12:59:43
PAGE 38
CONCURRENT 1-HR AVERAGE CONCENTRATION
FOR SOURCE GROUP: ALL
INCLUDING SOURCE(S): OFFSITE ,
VALUES ENDING WITH HOUR 7 FOR DAY
* DISCRETE CARTESIAN RECEPTOR POINTS
"* CONC OF FUGITIVE IN NICROGRAMS/M**3
X-COORD (M) Y-COORD (M).
CONC
X-COORD (M) Y-COORD (M)
CONC
100.00
300.00
500.00
700.00
900.00
1250.00
1750.00
2250.00
3000.00
5000.00
10000.00
20000.00
40000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.97568
0.84288
0.60055
"0.23522
0.13708
0.06452
0.05782
0.06726
0.10203
0.10425
0.13022
0.12217
0.07838
200.00
400.00
600.00
800.00
1000.00
1500.00
2000.00
2500.00
4000.00
7500.00
15000.00
30000.00
50000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.70307
0.78041
0.37108
0.18123
0.13194
0.05909
0.06227
0.10328
0.11155
0.11595
0.13193
0.09804
0.06421
-------
ISCOMDEP VERSION 94227
WT1 Truck Accident Off-Site, Screen Modeling -- OFFSITE
1 Point source; 26 receptors up to 50 CM M«y; Vapor.
MODELING OPTIONS USED: CONC RURAL ELEV
CRDRIS NOSTD
09/U/95
12:59:45
PAGE 39
CONCURRENT 1-HR AVERAGE CONCENTRATION
FOR SOURCE GROUP: ALL
INCLUDING SOURCE(S): OFFSITE .
VALUES ENDING WITH HOUR 8 FOR DAY
** DISCRETE CARTESIAN RECEPTOR POINTS
* CONC OF FUGITIVE IN NICROGRAMS/M**}
X-COORD (M) Y-COORD (M)
CONC
X-COORD (N) Y-COORD (M)
CONC
100.00
300.00
500.00
700.00
900.00
1250.00
1750.00
2250.00
3000.00
5000.00
10000.00
20000.00
40000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
1.09653
1.13892
O.S4357
'0.32307
0.18706
0.08681
0.08009
0.09544
0.14590
0.14210
0.16442
0.13420
0.07772
200.00
400.00
600.00
800.00
1000.00
1500.00
2000.00
2500.00
4000.00
7500.00
15000.00
30000.00
50000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.87549
1.08743
0.51595
0.24852
0.18188
0.08069
0.08751
0.14837
0.15600
0.15503
0.15328
0.10067
0.06226
-------
ISCOM>EP VERSION 94227
WTI Truck Accident Off-Site, Screen Modeling -- OFFSITE
1 Point source; 26 receptors up to SO KM away; Vapor.
MODELING OPTIONS USED: CONC RURAL ELEV
GRDRIS NOSTD
09/U/95
12:59:48
PAGE 40
CONCURRENT 1-HR AVERAGE CONCENTRATION
FOR SOURCE GROUP: ALL
INCLUDING SOURCE(S): OFFSITE ,
VALUES ENDING WITH HOUR 9 FOR DAT
** DISCRETE CARTESIAN RECEPTOR POINTS
** CONC OF FUGITIVE IN NICROGRAKS/M**3
X-COORD (M) Y-COORD (M)
CONC
X-COORD (M) Y-COORD (M)
CONC
100.00
300.00
500.00
700.00
900.00
1250.00
1750.00
2250.00
3000.00
5000.00
10000.00
20000.00
40000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
1.25098
1.52013
1.15857
^0.43650
0.25154
0.11549
0.10864
0.13086
0.19736
0.18034
0.19409
0.14088
0.07549
200.00
400.00
600.00
800.00
1000.00
1500.00
2000.00
2500.00
4000.00
7500.00
15000.00
30000.00
50000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
1.09092
1.48541
0.70343
0.33535
0.24636
0.10849
0.11962
0.20319
0.20398
0.19337
0.16836
0.10034
0.05948
-------
ISCOMDEP VERSION 94227
VJl Truck Accident Off-Site, Screen Nodeling -- OFFS1TE
1 Point source; 26 receptors i^ to 50 KM away; Vapor.
** MODELING OPTIONS USED: CONC RURAL ELEV
GRDRIS NOSTD
09/U/95
12:59:48
PACE 41
CONCURRENT 1-HR AVERAGE CONCENTRATION
FOR SOURCE GROUP: ALL
INCLUDING SOURCE(S): OFFSITE ,
VALUES ENDING WITH HOUR 10 FOR DAT
*** DISCRETE CARTESIAN RECEPTOR POINTS
** CONC OF FUGITIVE IN MICROGRAMS/N**3
X-COORD (M) Y-COORD (M)
CONC
X-COORD (M) Y-COORD (M)
CONC
100.00
300.00
500.00
700.00
900.00
1250.00
1750.00
2250.00
3000.00
5000.00
10000.00
20000.00
40000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
1.53251
1.99924
1.55276
' 0.57864
0.33223
0.15138
0.14388
0.17309
0.25361
0.21590
0.21807
0.14363
0.07250
200.00
400.00
600.00
800.00
1000.00
1500.00
2000.00
2500.00
4000.00
7500.00
15000.00
30000.00
50000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
1.35679
1.98495
0.93823
0.44408
0.32693
0.14310
0.15864
0.26570
0.25176
0.22843
0.17798
0.09826
0.05643
-------
1SCOHDEP VERSION 94227
tfTI Truck Accident Off-Site, Screen Modeling -- OFFSITE
1 Point source; 26 receptors up to 50 KM *way; Vapor.
MODELING OPTIONS USED: CONC RURAL ELEV
GRDRIS NOSTD
09/14/95
12:59:48
PAGE 42
CONCURRENT 1-HR AVERAGE CONCENTRATION
FOR SOURCE GROUP: ALL
INCLUDING SOURCE(S): OFFSITE ,
VALUES ENDING WITH HOUR 11 FOR DAY
** DISCRETE CARTESIAN RECEPTOR POINTS
** CONC OF FUGITIVE IN NICROGRAMS/M**:
X-COORD (M) Y-COORD (M)
CONC
X-COORD (M) Y-COORD (M)
CONC
100.00
300.00
500.00
700.00
900.00
1250.00
1750.00
2250.00
3000.00
5000.00
10000.00
20000.00
40000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.27107
2.28344
2.00967
'1.57371
1.14996
0.52386
0.46164
0.48491
0.47196
0.28626
0.12210
0.04661
0.01694
200.00
400.00
600.00
800.00
1000.00
1500.00
2000.00
2500.00
4000.00
7500.00
15000.00
30000.00
50000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
1.71777
2.21965
1.78189
1 .39321
1.10872
0.48024
0.47766
0.54602
0.36155
0.17751
0.07023
0.02571
0.01222
-------
ISCOMDEP VERSION 94227
UTI Truck Accident Off-Site, Screen Modeling -- OFFSITE
1 Point source; 26 receptors up to 50 » away; Vapor.
*** MODELING OPTIONS USED: CONC RURAL ELEV
GRDRIS NOSTD
09/U/95
12:59:48
PAGE 43
CONCURRENT 1-HR AVERAGE CONCENTRATION VALUES ENDING WITH HOUR 12 FOR DAY 2
FOR SOURCE GROUP: ALL
INCLUDING SOURCE(S): OFFSITE ,
» DISCRETE CARTESIAN RECEPTOR POINTS *
* CONC OF FUGITIVE IN NICROGRAKS/»r*3 **
X-COORD (M) Y-COORD (H)
CONC
X-COORD (N) Y-COORD (M)
CONC
100.00
300.00
500.00
700.00
900.00
1250.00
1750.00
2250.00
3000.00
5000.00
10000.00
20000.00
40000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.10018
2.06962
2.00171
'1.61295
1.28449
0.85233
0.68052
0.59155
0.45701
0.26054
0.10432
0.03851
0.01376
200.00
400.00
600.00
800.00
1000.00
1500.00
2000.00
2500.00
4000.00
7500.00
15000.00
30000.00
50000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
1.30773
2.14212
1.80676
1 .43766
1.15230
0.74482
0.64832
0.54123
0.33781
0.15511
0.05869
0.02100
0.00990
-------
ISCOMDEP VERSION 94227
WTI Truck Accident Off-Site. Screen Modeling -- OFFSITE
1 Point source; 26 receptors up to SO KM way; Vapor.
09/U/95
12:59:48
PAGE 44
MODELING OPTIONS USED: CONC RURAL ELEV
CRDRIS NOSTD
CONCURRENT 1-HR AVERAGE CONCENTRATION
FOR SOURCE CROUP: ALL
INCLUDING SOURCE(S): OFFSITE ,
VALUES ENDING WITH HOUR 13 FOR DAY
** DISCRETE CARTESIAN RECEPTOR POINTS
* CONC OF FUGITIVE IN MICROGRAMS/M**3
X-COORD (M) Y-COORD (N)
CONC
X-COORD (M) Y-COORD (M)
CONC
100.00
300.00
500.00
700.00
900.00
1250.00
1750.00
2250.00
3000.00
5000.00
10000.00
20000.00
40000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.02068
1.91570
2.04348
" 1.67058
1.32693
0.89734
0.68782
0.53873
0.38948
0.20237
0.07482
0.02658
0.00933
200.00
400.00
600.00
800.00
1000.00
1500.00
2000.00
2500.00
4000.00
7500.00
15000.00
30000.00
50000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.94900
2.12697
1.86491
1.48853
1.18646
0.78286
0.60707
0.48084
0.27228
0.11431
0.04103
0.01431
0.00669
-------
ISCOMDEP VERSION 94227
WTI Truck Accident Off-Site. Screen Modeling -- OFFSITE
1 Point source; 26 receptors ip to 50 KM way; Vapor.
09/14/95
12:59:48
PAGE 45
MODELING OPTIONS USED: CONC RURAL ELEV
CRDRIS NOSTD
CONCURRENT 1-HR AVERAGE CONCENTRATION
FOR SOURCE GROUP: ALL
INCLUDING SOURCE(S): OFFSITE .
VALUES ENDING WITH HOUR 14 FOR DAY
DISCRETE CARTESIAN RECEPTOR POINTS
* CONC OF FUGITIVE IN mCWGRAMS/H**3
X-COORD (M) Y-COORD (M)
CONC
X-COORD (M) Y-COORD (M)
CONC
100.00
300.00
500.00
700.00
900.00
1250.00
1750.00
2250.00
3000.00
5000.00
10000.00
20000.00
40000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00974
1.88919
2.03106
"1.63626
1.28060
0.85626
0.62138
0.46826
0.32603
0.16184
0.05779
0.02021
0.00704
200.00
400.00
600.00
800.00
1000.00
1500.00
2000.00
2500.00
4000.00
7500.00
15000.00
30000.00
50000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.86040
2.12054
1.84082
1.44688
1.13748
0.72546
0.53698
0.41185
0.22158
0.08930
0.03136
0.01083
0.00504
-------
ISCOMDEP VERSION 94227
WTI Truck Accident Off-Site, Screen Modeling -- OFFSITE
1 Point source; 26 receptors up to SO KM away; Vapor.
*** MODELING OPTIONS USED: CONC RURAL ELEV
GRORIS NOSTD
09/U/95
12:59:48
PAGE 46
CONCURRENT 1-HR AVERAGE CONCENTRATION
FOR SOURCE GROUP: ALL
INCLUDING SOURCE(S): OFFSITE ,
VALUES ENDING WITH HOUR 15 FOR DAY
DISCRETE CARTESIAN RECEPTOR POINTS
CONC OF FUGITIVE IN MIOKJGRAMS/M**3
X-COORD (M) Y-COORD (M)
CONC
X-COORD (M) Y-COORD (N)
CONC
100.00
300.00
500.00
700.00
900.00
1250.00
1750.00
2250.00
3000.00
5000.00
10000.00
20000.00
40000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
9.17914
9.7B82B
17.16070
11.51297
9.90330
7.64272
5.41060
5.34495
5.82222
3.22312
1.33870
0.70805
0.46332
200.00
400.00
600.00
800.00
1000.00
1500.00
2000.00
2500.00
4000.00
7500.00
15000.00
30000.00
50000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
5.20311
14.86587
14.43324
11.03429
11.80137
6.21791
5.39378
7.21376
4.32489
1.87735
0.77559
0.56321
0.38992
-------
ISCOMDEP VERSION 94227
WTI Truck Accident Off-Site, Screen Modeling -- OFFSITE
1 Point source; 26 receptors up to 50 KM May; Vapor.
09/H/95
12:59:48
PAGE 47
*** MODELING OPTIONS USED: CONC RURAL ELEV
GRDRIS NOSTD
CONCURRENT 1-HR AVERAGE CONCENTRATION VALUES ENDING WITH HOUR 16 FOR DAY
FOR SOURCE GROUP: ALL
INCLUDING SOURCE(S): OFFSITE ,
*** DISCRETE CARTESIAN RECEPTOR POINTS
* CONC OF FUGITIVE IN MICROGRAMS/M««3 **
X-COORD (M) Y-COORD (M)
CONC
X-COORD (M) Y-COORD (M)
CONC
100.00
300.00
500.00
700.00
900.00
1250.00
1750.00
2250.00
3000.00
5000.00
10000.00
20000.00
40000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
26.37437
11.20241
18.94490
12.65435
10.64366
7.97805
5.50312
5.06163
4.50767
2.32745
0.89431
0.35126
0.13974
200.00
400.00
600.00
800.00
1000.00
1500.00
2000.00
2500.00
4000.00
7500.00
15000.00
30000.00
50000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
5.63871
16.90074
15.83704
11.94546
12.06563
6.42436
5.29277
5.65509
3.05915
1.36933
0.52351
0.20522
0.10528
-------
ISCOHDEP VERSION 94227
WT1 Truck Accident Off-Site, Screen Modeling -- OFFSITE
1 Point source; 26 receptors up to 50 KM away; Vapor.
MODELING OPTIONS USED: CONC RURAL ELEV
GRDRIS NOSTD
09/14/95
12:59:46
PAGE 48
CONCURRENT 1-HR AVERAGE CONCENTRATION
FOR SOURCE GROUP: ALL
INCLUDING SOURCE(S): OFFSITE ,
VALUES ENDING WITH HOUR 17 FOR DAT
** DISCRETE CARTESIAN RECEPTOR POINTS
** CONC OF FUGITIVE IN MICROGRAMS/M**3
X-COORD (M) Y-COORD (M)
CONC
X-COORD (N) Y-COORD (N)
CONC
100.00
300.00
500.00
700.00
900.00
1250.00
1750.00
2250.00
3000.00
5000.00
10000.00
20000.00
40000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
62.23378
12.35422
19.64951
tS.09169
10.76628
7.85987
5.31279
4.59804
3.45930
1.74236
0.65978
0.25701
0.10176
200.00
400.00
600.00
800.00
1000.00
1500.00
2000.00
2500.00
4000.00
7500.00
15000.00
30000.00
50000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
11.46214
18.18891
16.33002
12.16302
11.60286
6.28158
4.95312
4.36019
2.30037
1.02928
0.38430
0.14970
0.07659
-------
ISCOHDEP VERSION 94227
UTI Truck Accident Off-Site, Screen Modeling -- OFFSITE
1 Point source; 26 receptors up to 50 KM *way; Vapor.
09/U/95
12:59:45
PAGE 49
MODELING OPTIONS USED: CONC RURAL ELEV
GRORIS NOSTD
CONCURRENT 1-HR AVERAGE CONCENTRATION
FOR SOURCE GROUP: ALL
INCLUDING SOURCE(S): OFFSITE ,
VALUES ENDING WITH HOUR 18 FOR DAY 2 ***
*** DISCRETE CARTESIAN RECEPTOR POINTS
** CONC OF FUGITIVE IN MICROGRAMS/M**3
X-COORD (M) Y-COORD (M)
CONC
X-COORD (M) r-COORD (N)
CONC
100.00
300.00
500.00
700.00
900.00
1250.00
1750.00
2250.00
3000.00
5000.00
10000.00
20000.00
40000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
120.40126
15.66378
19.64915
t3. 08050
10.53259
7.51630
5.00416
4.11389
2.78693
1 *30w6
0.52080
0.20173
0.07961
200.00
400.00
600.00
800.00
1000.00
1500.00
2000.00
2500.00
4000.00
7500.00
15000.00
30000.00
50000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
22.42717
18.92721
16.24436
11.96645
10.81345
5.97614
4.54292
3.52548
1.84120
0.81654
0.30231
0.11726
0.05989
-------
1SCOMDEP VERSION 94227
WT1 Truck Accident Off-Site, Screen Modeling -- OFFSITE
1 Point source; 26 receptors up to 50 KM away; Vapor.
MODELING OPTIONS USED: CONC RURAL ELEV
CRORIS NOSTD
09/U/95
12:59:48
PAGE 50
CONCURRENT 1-HR AVERAGE CONCENTRATION VALUES ENDING WITH HOUR 19 FOR DAY
FOR SOURCE GROUP: ALL
INCLUDING SOURCE(S): OFFSITE ,
** DISCRETE CARTESIAN RECEPTOR POINTS *
CONC OF FUGITIVE IN MICROGRAMS/IT"3 *
X-COORD (M) Y-COORD (M)
CONC
X-COORD (M) Y-COORD (M)
CONC
100.00
300.00
500.00
700.00
900.00
1250.00
1750.00
2250.00
3000.00
5000.00
10000.00
20000.00
40000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
191 .37901
25.63425
19.19101
- 12.78461
10.09808
7.06886
4.65516
3.64354
2.33326
1.15467
0.42914
0.16553
0.06517
200.00
400.00
600.00
800.00
1000.00
1500.00
2000.00
2500.00
4000.00
7500.00
15000.00
30000.00
50000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
38.04164
19.25438
15.79421
11.52680
9.82507
5.60258
4.13086
2.96026
1.53348
0.67544
0.24847
0.09607
0.04900
-------
ISCOMDEP VERSION 94227
WTI Truck Accident Off-Site, Screen Modeling -- OFFSITE
1 Point source; 26 receptors up to 50 KM away; Vapor.
09/U/95
12:59:46
PAGE 51
MODELING OPTIONS USED: CONC RURAL ELEV
GRDRIS NOSTD
CONCURRENT 1-HR AVERAGE CONCENTRATION
FOR SOURCE GROUP: ALL
INCLUDING SOURCE(S): OFFSITE ,
VALUES ENDING WITH HOUR 20 FOR DAY 2 *
DISCRETE CARTESIAN RECEPTOR POINTS
CONC OF FUGITIVE IN NICROGRAMS/M**3
X-COORD (M) Y-COORD (M)
CONC
X-COORD
-------
ISCOMDEP VERSION 94227
Wi: Truck Accident Off-Site, Screen Modeling -- OFFSITE
1 Point source; 26 receptors up to SO KM *way; Vapor.
MODELING OPTIONS USED: CONC RURAL ELEV
GRORIS MOSTD
09/U/95
12:59:48
PACE 52
CONCURRENT 1-HR AVERAGE CONCENTRATION
FOR SOURCE GROUP: ALL
INCLUDING SOURCE(S): OFFSITE ,
VALUES ENDING WITH HOUR 21 FOR DAY 2
DISCRETE CARTESIAN RECEPTOR POINTS
CONC OF FUGITIVE IN NICROGRAMS/M**3
X-COORD (N) Y-COORD (N)
CONC
X-COORD (M> Y-COORD
-------
ISCOMDEP VERSION 94227
UT1 Truck Accident Off-Site. Screen Modeling -- OFFSITE
1 Point source; 26 receptors ip to 50 KM away; Vapor.
MODELING OPTIONS USED: CONC RURAL ELEV
GftDRIS NOSTD
09/14/95
12:59:48
PACE 53
CONCURRENT 1-HR AVERAGE CONCENTRATION VALUES ENDING WITH HOUR 22 FOR DAY
FOR SOURCE GROUP: ALL
INCLUDING SOURCE(S): OFFSITE ,
** DISCRETE CARTESIAN RECEPTOR POINTS ***
** CONC OF FUGITIVE IN NICXOGRAMS/M**3 **
2
X-COORD (N) Y-COORD (M)
CONC
X-COORD (N) Y-COORD (M)
CONC
100.00
300.00
500.00
700.00
900.00
1250.00
1750.00
2250.00
3000.00
5000.00
10000.00
20000.00
40000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
169.67842
38.22655
16.92746
10.93935
8.14166
5.47144
3.58087
2.53310
1.56636
0.76265
0.278B6
0.10671
0.04183
200.00
400.00
600.00
800.00
1000.00
1500.00
2000.00
2500.00
4000.00
7500.00
15000.00
30000.00
50000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
70.66110
24.09174
13.03526
9.36549
7.03090
4.36030
2.99774
1.99987
1.01821
0.44233
0.16069
0.06176
0.03142
-------
ISCOMDEP VERSION 94227
UTI Truck Accident Off-Site, Screen Modeling -- OFFSITE
1 Point source; 26 receptors up to SO KM away; Vapor.
*** MODELING OPTIONS USED: CONC RURAL ELEV
GRDRIS NOSTD
09/U/95
12:59:45
PAGE 54
CONCURRENT 1-HR AVERAGE CONCENTRATION VALUES ENDING WITH HOUR 23 FOR DAT
FOR SOURCE GROUP: ALL
INCLUDING SOURCE(S): OFFSITE ,
* DISCRETE CARTESIAN RECEPTOR POINTS **
* CONC OF FUGITIVE IN MICR06RAMS/K^3 *
X-COORD (M) Y-COORD (M)
CONC
X-COORD (M) Y-COORD (M)
CONC
100.00
300.00
500.00
700.00
900.00
1250.00
1750.00
2250.00
3000.00
5000.00
10000.00
20000.00
40000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
151.22041
36.17004
16.03088
W.09557
7.49753
5.01292
3.27706
2.29028
1.41124
0.68441
0.24930
0.09523
0.03729
200.00
400.00
600.00
800.00
1000.00
1500.00
2000.00
2500.00
4000.00
7500.00
15000.00
30000.00
50000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
66.92157
22.82990
12.31160
8.63371
6.40542
3.99640
2.71366
1.80466
0.91491
0.39617
0.14350
0.05508
0.02801
-------
1SCONDEP VERSION 94227
UTI Truck Accident Off-Site, Screen Modeling -- OFFSITE
1 Point source; 26 receptors up to 50 KM away; Vapor.
09/U/95
12:59:48
PAGE 55
** MODELING OPTIONS USED: CONC RURAL ELEV
CRDRIS NOSTO
CONCURRENT 1-HR AVERAGE CONCENTRATION VALUES ENDING WITH HOUR 24 FOR DAY
FOR SOURCE GROUP: ALL
INCLUDING SOURCE(S): OFFSITE ,
*** DISCRETE CARTESIAN RECEPTOR POINTS **
* CONC OF FUGITIVE IN MICROGRAMS/M**3 **
2 *-
X-COORD (N) Y-COOTO (H)
CONC
X-COORD (M) Y-COORD (N)
CONC
100.00
300.00
500.00
700.00
900.00
1250.00
1750.00
2250.00
3000.00
5000.00
10000.00
20000.00
40000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
17.67307
22.11532
34.85668
23.24654
19.16001
14.09468
9.60246
8.58492
6.38994
3.45708
1.44461
0.62392
0.26734
200.00
400.00
600.00
800.00
1000.00
1500.00
2000.00
2500.00
4000.00
7500.00
15000.00
30000.00
50000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
10.71785
32.51575
28.97512
21.61471
20.69304
11.29400
9.10952
7.88782
4.43724
2.15608
0.88569
0.37837
0.20389
-------
ISCOHDEP VERSION 94227
WTI Truck Accident Off-Site, Screen Modeling -- OFFSITE
1 Point source; 26 receptors up to SO KM away; Vapor.
09/U/95
12:59:43
PAGE 56
*** MODELING OPTIONS USED: CONC RURAL ELEV
GRDRIS NOSTD
CONCURRENT 1-HR AVERAGE CONCENTRATION VALUES ENDING WITH HOUR 1 FOR DAY
FOR SOURCE GROUP: ALL
INCLUDING SOURCE(S): OFFSITE ,
** DISCRETE CARTESIAN RECEPTOR POINTS ***
CONC OF FUGITIVE IN MICROGRAMS/M*«3
X-COORD Y-COORD (M)
CONC
X-COORD (N) Y-COORD (M)
CONC
100.00
300.00
500.00
700.00
900.00
1250.00
1750.00
2250.00
3000.00
5000.00
10000.00
20000.00
40000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
57.56957
25.15523
33.45829
-22.60911
18.02194
12.86062
8.68409
6.77120
4.42163
2.35676
0.96494
0.41102
0.17439
200.00
400.00
600.00
800.00
1000.00
1500.00
2000.00
2500.00
4000.00
7500.00
15000.00
30000.00
50000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
12.13928
34.11783
27.67290
20.43232
16.87412
10.32840
7.75508
5.48719
3.04205
1.45425
0.58639
0.24767
0.13268
-------
ISCOMDEP VERSION 94227
WTI Truck Accident Off-Site, Screen Modeling -- OFFSITE
1 Point source; 26 receptors tp to 50 KM away; Vapor.
09/H/95
12:59:48
PAGE 57
MODELING OPTIONS USED: CONC RURAL ELEV
CRDRIS NOSTO
CONCURRENT 1-HR AVERAGE CONCENTRATION
FOR SOURCE GROUP: ALL
INCLUDING SOURCE(S): OFFSITE ,
VALUES ENDING WITH HOUR 2 FOR DAY 3
DISCRETE CARTESIAN RECEPTOR POINTS
CONC OF FUGITIVE IN KICROGRAMS/M**3
X-COORD (M) Y-COORD (M)
CONC
X-COORD (M) Y-COORD (M)
CONC
100.00
300.00
500.00
700.00
900.00
1250.00
1750.00
2250.00
3000.00
5000.00
10000.00
20000.00
40000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
135.07504
27.03052
28.70184
20.08150
15.31101
10.65054
7.24759
5.28539
3.39516
1.79032
0.72288
0.30517
0.12870
200.00
400.00
600.00
800.00
1000.00
1500.00
2000.00
2500.00
4000.00
7500.00
15000.00
30000.00
50000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
24.98931
33.35661
23.68114
17.39954
13.36535
8.66254
6.16188
4.23010
2.32025
1.09660
0.43677
0.18315
0.09777
-------
ISCOMDEP VERSION 94227
WTI Truck Accident Off-Site, Screen Modeling -- OFFSITE
1 Point source; 26 receptors up to 50 KM mwy; Vapor.
MODELING OPTIONS USED: CONC RURAL ELEV
GRDRIS NOSTD
09/U/95
12:59:48
PAGE 58
CONCURRENT 1-HR AVERAGE CONCENTRATION
FOR SOURCE GROUP: ALL
INCLUDING SOURCE(S): OFFSITE ,
VALUES ENDING WITH HOUR 3 FOR DAY
DISCRETE CARTESIAN RECEPTOR POINTS
CONC OF FUGITIVE IN MICROGRAMS/M**3
X-COORD (M) Y-COORD (M)
CONC
X-COORD (M) Y-COORD (M)
CONC
100.00
300.00
500.00
700.00
900.00
1250.00
1750.00
2250.00
3000.00
5000.00
10000.00
20000.00
40000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
218.07961
31.28687
24.20550
17.02319
12.84729
8.86100
6.02657
4.32855
2.76117
1.44400
0.57704
0.24206
0.10165
200.00
400.00
600.00
800.00
1000.00
1500.00
2000.00
2500.00
4000.00
7500.00
15000.00
30000.00
50000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
47.28311
30.85106
19.94574
14.61751
11.07833
7.22098
5.05741
3.45101
1.87722
0.87960
0.34723
0.14487
0.07714
-------
ISCOMDEP VERSION 94227
WTI Truck Accident Off-Site, Screen Modeling -- OFFSITE
1 Point source; 26 receptors up to 50 KM away; Vapor.
MODELING OPTIONS USED: CONC RURAL ELEV
GRDRIS HOSTD
09/14/95
12:59:48
PAGE 59
CONCURRENT 1-HR AVERAGE CONCENTRATION VALUES ENDING WITH HOUR 4 FOR DAT
FOR SOURCE GROUP: ALL
INCLUDING SOURCE(S): OFFSITE .
** DISCRETE CARTESIAN RECEPTOR POINTS »*
CONC OF FUGITIVE IN MICROGRAMS/K**3
X-COORD (M) Y-COORD (M)
CONC
X-COORD (M) Y-COORD (M)
CONC
100.00
300.00
500.00
700.00
900.00
1250.00
1750.00
2250.00
3000.00
5000.00
10000.00
20000.00
40000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
193.67424
41.28204
20.87127
'14.64603
11.02856
7.58009
5.13345
3.67234
2.32929
1.21004
0.47965
0.20024
0.08382
200.00
400.00
600.00
800.00
1000.00
1500.00
2000.00
2500.00
4000.00
7500.00
15000.00
30000.00
50000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
71.26071
27.03833
17.17882
12.56148
9.49537
6.16377
4.29847
2.91874
1 .57697
0.73389
0.28773
0.11959
0.06356
-------
1SCOHDEP VERSION 94227
WTI Truck Accident Off-Site, Screen Modeling -- OFFSITE
1 Point source; 26 receptors up to 50 KM May; Vapor.
09/U/95
12:59:43
PAGE 60
*** MODELING OPTIONS USED: CONC RURAL ELEV
GRDRIS NOSTO
CONCURRENT 1-HR AVERAGE CONCENTRATION
FOR SOURCE GROUP: ALL
INCLUDING SOURCE(S): OFFSITE ,
VALUES ENDING WITH HOUR 5 FOR OAT
* DISCRETE CARTESIAN RECEPTOR POINTS
* CONC OF FUGITIVE IN MICXOGRAMS/M**}
X-COORD (M) Y-COORD (M)
CONC
X-COORD (N) Y-COORD (M)
CONC
100.00
300.00
500.00
700.00
900.00
1250.00
1750.00
2250.00
3000.00
5000.00
10000.00
20000.00
40000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
167.07159
39.38115
18.40491
12.88981
9.68692
6.63757
4.47852
3.19289
2.01554
1.04128
0.41005
0.17054
0.07121
200.00
400.00
600.00
800.00
1000.00
1500.00
2000.00
2500.00
4000.00
7500.00
15000.00
30000.00
50000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
72.02185
24.94218
15.13344
11.04373
8.32914
5.38715
3.74304
2.53110
1.35980
0.62931
0.24537
0.10169
0.05397
-------
ISCOMDEP VERSION 94227
WTI Truck Accident Off-Site, Screen Modeling -- OFFSITE
1 Point source; 26 receptors up to 50 KM away; Vapor.
09/U/95
12:59:48
PACE 61
*** MODELING OPTIONS USED: CONC RURAL ELEV
GRDRIS NOSTD
CONCURRENT 1-HR AVERAGE CONCENTRATION VALUES ENDING WITH HOUR 6 FOR DAY 3
FOR SOURCE GROUP: ALL
INCLUDING SQURCE(S): OFFSITE .
*** DISCRETE CARTESIAN RECEPTOR POINTS ***
* CONC OF FUGITIVE IN MICROGRAMS/H"«3 **
X-COORD (M) Y-COORD (M)
CONC
X-COORD (N) Y-COORD
-------
ISCOMDEP VERSION 94227
VTI Truck Accident Off-Site, Screen Modeling -- OFFSITE
1 Point source; 26 receptors up to SO KM away; Vapor.
NQOELING OPTIONS USED: CONC RURAL ELEV
GRDRIS NOSTD
09/H/95
12:59:48
PAGE 62
THE 1ST HIGHEST 1-HR AVERAGE CONCENTRATION VALUES FOR SOURCE GROUP: ALL
INCLUDING SOURCE(S): OFFSITE ,
" DISCRETE CARTESIAN RECEPTOR POINTS *
CONC OF FUGITIVE IN NICROGRANS/M**3 **
X-COORD (M) Y-COORD (M)
CONC
(YYMMDDHH)
X-COQRD (H) Y-COORD (M)
CONC
(YYMMODHH)
100.00
300.00
500.00
700.00
900.00
1250.00
1750.00
2250.00
3000.00
5000.00
10000.00
20000.00
40000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
218.07961
41.28204
34.85668
23.24654
19-. 16001
14.09468
9.60246
8.58492
6.38994
3.45708
1.44461
0.70805
0.46332
(93010303)
(93010304)
(93010224)
(93010224)
(93010224)
(93010224)
(93010224)
(93010224)
(93010224)
(93010224)
(93010224)
(93010215)
(93010215)
200.00
400.00
600.00
800.00
1000.00
1500.00
2000.00
2500.00
4000.00
7500.00
15000.00
30000.00
50000.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
72.27760
34.11783
28.97512
21.61471
20.69304
11.29400
9.10952
7.88782
4.43724
2.15608
0.88569
0.56321
0.38992
(93010221)
(93010301)
(93010224)
(93010224)
(93010224)
(93010224)
(93010224)
(93010224)
(93010224)
(93010224)
(93010224)
(93010215)
(93010215)
-------
ISCQMDEP VERSION 9*227 *
WTI Truck Accident Off-Site, Screen Modeling -- OFFSITE
1 Point source; 26 receptors up to 50 KM «nay; Vapor.
MODELING OPTIONS USED: CONC RURAL ELEV
GRDR1S NOSTD
09/14/95
12:59:48
PAGE 63
RANK
THE MAXIMUM 50 1-HR AVERAGE CONCENTRATION
INCLUDING SOURCE(S): OFFSITE ,
VALUES FOR SOURCE GROUP: ALL
CONC (YYMMDDHH) AT
* CONC OF FUGITIVE IN MICROGRAMS/***3
RECEPTOR (XR.YR) OF TYPE RANK
CONC (YYMMDDHH) AT
RECEPTOR (XR.YR) OF TYP
1.
2.
3.
4.
5.
6.
7.
8.
9.
10.
11.
12.
13.
14.
15.
16.
17.
IS.
19.
20.
21.
22.
23.
24.
25.
***
218.07961 (93010303) AT (
207.63899 (93010220) AT (
193.67424 (93010304) AT (
191.37901 (93010219) AT (
189.36391 (93010221) AT (
169.67842 (93010222) AT (
167.07159 (93010305) AT (
151.22041 (93010223) AT (
141.85909 (93010306) AT (
135.07504 (93010302) AT (
120.40126 (93010218) AT (
72.27760 (93010221) AT (
72.02185 (93010305) AT (
71.26071 (93010304) AT (
70.66110 (93010222) AT (
66.92157 (93010223) AT (
66.84029 (93010306) AT (
62.23378 (93010217) AT (
57.56957 (93010301) AT (
56.09013 (93010220) AT (
47.28311 (93010303) AT (
41.28204 (93010304) AT (
39.82120 (93010221) AT (
39.38115 (93010305) AT (
38.22855 (93010222) AT (
RECEPTOR TYPES: GC * GRIDCART
GP « GRIDPOLR
DC « DISCCART
DP * DISCPOLR
BO * BOUNDARY
100.00,
100.00,
100.00,
100.00.
100.00,
100.00,
-100.00,
100.00,
100.00,
100.00,
100.00,
200.00,
200.00,
200.00,
200.00,
200.00,
200.00,
100.00,
100.00,
200.00,
200.00,
300.00,
300.00,
300.00,
300.00,
0.00)
0.00)
0.00)
0.00)
0.00)
0.00)
0.00)
0.00)
0.00)
0.00)
0.00)
0.00)
0.00)
0.00}
0.00)
0.00)
0.00)
0.00)
0.00)
0.00)
0.00)
0.00)
0.00)
0.00)
0.00)
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
26.
27.
28.
29.
30.
31.
32.
33.
34.
35.
36.
37.
38.
39.
40.
41.
42.
43.
44.
45.
46.
47.
48.
49.
50.
38.04164
36.88860
36.17004
35.42534
34.85668
34.11783
33.45829
33.35661
32.51575
31.28687
30.85106
28.97512
28.70184
27.67290
27.03833
27.03052
26.37437
25.63425
25.24093
25.15523
24.98931
24.94218
24.20550
24.09174
23.68114
(93010219)
(93010306)
(93010223)
(93010220)
(93010224)
(93010301)
(93010301)
(93010302)
(93010224)
(93010303)
(93010303)
(93010224)
(93010302)
(93010301)
(93010304)
(93010302)
(93010216)
(93010219)
(93010221)
(93010301)
(93010302)
(93010305)
(93010303)
(93010222)
(93010302)
AT (
AT (
AT (
AT (
AT (
AT (
AT (
AT (
AT (
AT (
AT (
AT (
AT (
AT (
AT (
AT (
AT (
AT (
AT (
AT (
AT (
AT (
AT (
AT (
AT (
200.00,
300.00,
300.00,
300.00,
500.00,
400.00,
500.00,
400.00,
400.00,
300.00,
400.00,
600.00,
500.00,
600.00,
400.00,
300.00,
100.00,
300.00,
400.00,
300.00,
200.00,
400.00,
500.00,
400.00,
600.00,
0.00)
0.00)
0.00)
0.00)
0.00)
0.00)
0.00)
0.00)
0.00)
0.00)
0.00)
0.00)
0.00)
0.00)
0.00)
0.00)
0.00)
0.00)
0.00}
0.00)
0.00)
0.00)
0.00)
0.00)
0.00)
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
-------
** ISCONDEP VERSION 94227 * ** WTI Truck Accident Off-Site, Screen Modeling -- OFFSITE " 09/U/95
*** 1 Point source; 26 receptors up to 50 KM way; Vapor. * 12:59:48
PAGE 64
** MODELING OPTIONS USED: CONC RURAL ELEV GRDRIS NOSTD
* THE SUMMARY OF HIGHEST 1-HR RESULTS ***
* CONC OF FUGITIVE IN MICROGRAMS/K««3
DATE NETWORK
GROUP ID AVERAGE CONC (YYNMDDHH) RECEPTOR (XR, YR, ZELEV, 2FLAG) OF TYPE GRID-ID
ALL HIGH 1ST HIGH VALUE IS 218.07961 ON 93010303: AT ( 100.00, 0.00, 292.60, 0.00) DC
*»* RECEPTOR TYPES: GC « GRIDCART
GP - GRIDPOLR
DC - DISCCART
DP DISCPOLR
BO - BOUNDARY
-------
ISCOMDEP VERSION 94227 *** "* WTI Truck Accident Off-Site, Screen Modeling -- OFFSITE 09/U/95
** 1 Point source; 26 receptors up to 50 KM away; Vapor. * 12:59:48
PAGE 65
MODELING OPTIONS USED: CONC RURAL ELEV CRORIS NOSTD
** Message Suireary : ISCOMDEP Model Execution "
Sumnary of Total Messages
A Total of 0 Fatal Error Message(s)
A Total of 1 Warning Message(s)
A Total of 0 Informational Message(s)
FATAL ERROR MESSAGES
** NONE *
*** WARNING MESSAGES «»«««»
SO U320 17 PPARM : Source Parameter May Be Out-of-Range for Parameter OS
ISCOMDEP Finishes Successfully
-------
ATTACHMENT 5
ISC-COMPDEP Outputs Using Real-Time Meteorological Data
-------
A. On-Site Fire Scenario
-------
CO STARTING
TITLEONE
TITLETWO
NGOELOPT
AVERTIME
POLLUTID
TERRNGTS
ELEVUNIT
RUNORNOT
ERRORFIL
CO FINISHED
WTI Storage Tank Rupture, ISCOMDEP -- ONSITE ORGANIC TANK
1 Point source; 936 receptor* up to 50KH away; Vapor.
NOSTD GRDR:S RURAL CONC
1 3 24 PERIOD
Chart cat
ELEV
METERS
RUN
ONSITE.ERR
FARM
SO STARTING
LOCATION ONSITE POINT 186.385 105.445 212.1
* Point Source OS HS TS VS OS
SO SRCPARAM ONSITE 1.0 23.0 997. 0.225 15.14
** SO SRCPARAM ONSITE 1.0 23.0 997. 0.075 26.22
SO BUILDHGT ONSITE 17.37 17.37 17.37 17.37 17.37
SO BUILDHGT ONSITE 17.37 17.37 17.37 17.37 17.37
SO BUILDHGT ONSITE 17.37 17.37 17.37 17.37 17.37
SO BUILDHGT ONSITE 17.37 17.37 17.37 17.37 17.37
SO BUILDHGT ONSITE 17.37 17.37 17.37 17.37 17.37
SO BUILDHGT ONSITE 17.37 17.37 17.37 17.37 17.37
SO BUILDUID ONSITE 50.09 47.00 42.49 36.68 29.75
SO BUILDUID ONSITE 18.23 26.39 33.74 40.06 45.17
SO BUILDUID ONSITE 51.16 51.86 50.98 50.09 51.66
SO BUILDWID ONSITE 50.09 47.00 42.49 36.66 29.75
SO BUILDUID ONSITE 18.23 26.39 33.74 40.06 45.17
SO BUILDUID ONSITE 51.16 51.86 50.98 50.09 51.66
SO SRCGROUP ALL
SO FINISHED
RE STARTING
RE DISCCART 17.36482 98.48077 213.4
RE DISCCART 34.72963 196.96155 225.6
RE DISCCART 52.09445 295.44232 225.6
RE DISCCART 69.45927 393.92310 225.6
RE DISCCART 86.82409 492.40387 225.6
RE DISCCART 104.18890 590.88464 225.6
RE DISCCART 121.55372 689.36542 243.8
RE DISCCART 138.91853 787.84619 256.0
RE DISCCART 156.28336 886.32697 280.4
RE DISCCART 173.64818 984.80774 286.5
RE DISCCART 217.06021 1231.00964 353.6
RE DISCCART 260.47226 1477.21167 353.6
RE DISCCART 303.88431 1723.41357 310.9
RE DISCCART 347.29636 1969.61548 347.5
RE DISCCART 390.70837 2215.81738 353.6
RE DISCCART 434.12042 2462.01929 359.7
RE OISCCART 520.94452 2954.42334 347.5
RE OISCCART 694.59271 3939.23096 341.4
RE DISCCART 868.24084 4924.03857 341.4
RE DISCCART 1302.36133 7386.05811 365.8
RE DISCCART 1736.48169 9848.07715 360.0
RE DISCCART 7604.72266 14772.11620 340.0
RE DISCCART 3472.96338 19696.15430 340.0
RE DISCCART 5209.44531 29544.23240 360.0
RE DISCCART 6945.92676 39392.3086C 350.0
17.37
17.37
17.37
17.37
17.37
17.37
21.92
48.91
51.66
21.92
48.91
51.66
-------
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
8682.40820
34.20201
68.40403
102.60604
136.80806
171.01007
205.21206
239.41409
273.61612
307.81812
342.02014
427.52518
513.03021
598.53522
684.04028
769.54529
855.05035
1026.06042
1368.08057
1710.10071
2565.15112
3420.20142
5130.30225
6840.40283
10260.60450
13680.80570
17101.00590
50.00000
100.00000
150.00000
200.00000
250.00000
300.00000
350.00000
400.00000
450.00000
500.00000
625.00000
750.00000
875.00000
1000.00000
1125.00000
1250.00000
1500.00000
2000.00000
2500.00000
3750.00000
5000.00000
7500.00000
10000.00000
15000.00000
20000.00000
25000.00000
64.27876
128.55753
192.83627
257.11505
321 .39380
385.67255
449.95132
514.23010
578.S08S5
642.78760
49240.38670
93.96926
187.93852
281.90778
375.87704
469.84631
563.81555
657.78485
751.75409
845.72339
939.69263
1174.61572
1409.53894
1644.46204
1879.38525
2114.30835
2349.23145
2819.07788
3758.77051
4698.46289
7047.69482
9396.92578
14095.38960
18793.85160
28190.77930
37587.70310
46964.63280
86.60254
173.20508
259.80762
346.41016
433.01270
519.61523
606.21777
692.82031
779.42285
866.02539
1082.53174
1299.03809
1515.54443
1732.05078
1948.55713
2165.06348
2598.07617
3464.10156
4330.12695
6495.19043
8660.25391
12990.38090
17320.50780
25960.76170
34641.01560
43301.26950
76.60445
153.20889
229.81334
306.41779
383.02222
459.62668
536.23114
612.83557
689.44000
766.04443
360.0
213.4
225.6
225.6
225.6
225.6
225.6
237.7
243.8
256.0
286.5
329.2
347.5
335.3
347.5
353.6
359.7
362.4
329.2
359.7
369.7
385.9
340.0
340.0
360.0
380.0
390.0
213.4
219.5
225.6
225.6
225.6
225.6
225.6
231.6
243.8
262.1
225.6
347.5
359.7
353.6
353.6
329.2
323.1
361.2
366.7
378.0
396.2
320.0
360.0
380.0
370.0
400.0
213.4
213.4
225.6
225.6
225.6
225.6
225.6
225.6
225.6
243.8
-------
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
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RE DISCCART
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RE DISCCART
RE DISCCART
RE DISCCART
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RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
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RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
803.48450
964.18140
1124.87830
1285.57520
1446.27209
1606.96899
1928.36279
2571.15039
3213.93799
4820.90674
6427.87598
9641.81348
12855.75200
19283.62700
25711.50390
32139.37890
76.60445
153.20889
229.81334
306.41779
383.02222
459.62668
536.23114
612.83557
689.44000
766.04443
957.55554
1149.06665
1340.57776
1532.08887
1723.59998
1915.11108
2298.13330
3064.17773
3830.22217
5745.33350
7660.44434
11490.66700
15320.88870
22981.33400
30641.77730
38302.22270
86.60254
173.20508
259.80762
346.41016
433.01270
519.61523
606.21777
692.82031
779.42285
866.02539
1082.53174
1299.03809
1515.54443
1732.05078
1948.55725
2165.06348
2598.07617
3464.10156
4330.12695
6495.19043
8660.25391
957.55554
1149.06665
1340.57776
1532.08887
1723.59998
1915.11108
2298.13330
3064.17773
3830.22217
5745.33350
7660.44434
11490.66700
15320.88870
22981.33400
30641.77730
38302.22270
64.27876
128.55753
192.83629
257.11505
321.39380
385.67258
449.95132
514.23010
578.50885
642.78760
803.48450
964.18140
1124.87830
1285.57520
1446.27209
1606.96899
1928.36279
2571.15039
3213.93799
4820.90723
6427.87598
9641.81445
12855.75200
19283.62890
25711.50390
32139.38090
50.00000
99.99999
150.00000
199.99998
249.99998
300.00000
349.99997
399.99997
449.99997
499.99997
624.99994
749.99994
874.99994
Wnt^*\/
Tl^rTWI
1125.00000
1249.99988
1499.99988
1999.99988
2*99.99976
3749.99976
4999.99951
280.4
353.6
361.5
353.6
353.6
353.6
335.3
353.9
353.0
378.0
398.4
376.0
380.0
360.0
420.0
420.0
213.4
207.3
213.4
219.5
219.5
219.5
219.5
219.5
225.6
219.5
219.5
323.1
353.6
353.6
335.3
347.5
347.5
341.4
335.3
373.1
396.2
360.0
380.0
380.0
420.0
420.0
213.4
207.3
207.3
201.2
207.3
213.4
213.4
213.4
213.4
219.5
225.6
219.5
243.8
292.6
310.9
323.1
317.0
323.1
359.7
378.9
408.7
-------
RE DISCCART
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RE DISCCART
RE DISCCART
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RE DISCCART
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RE .DISCCART
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RE DISCCART
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-------
RE DISCCART
RE OISCCART
RE OISCCART
RE DISCCART
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RE DISCCART
RE DISCCART
RE OISCCART
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K DISCCART
RE DISCCART
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RE OISCCART
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K DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE OISCCART
RE DISCCART
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22222222SSH2H222S22222220
I I I I I
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RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
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RE DISCCART
RE DISCCART
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RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE OISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
K DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
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RE DISCCART
RE DISCCART
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RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE OISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
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202.7
202.7
-------
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE OISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
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RE DISCCART
RE DISCCART
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RE OISCCART
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RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE OISCCART
RE OISCCART
RE OISCCART
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RE DISCCART
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213.4
213.4
256.0
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359.7
384.0
378.0
-------
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RE OISCCART
RE DISCCART
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213.4
213.4
213.4
-------
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
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RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
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RE DISCCART
RE DISCCART
RE DISCCART
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RE DISCCART
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RE DISCCART
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RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
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RE DISCCART
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RE DISCCART
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341.4
371.9
353.6
-------
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
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RE DISCCART
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RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
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RE DISCCART
RE DISCCART
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RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
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RE DISCCART
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RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
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RE DISCCART
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RE DISCCART
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RE DISCCART
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RE DISCCART
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RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
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RE OISCCART
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RE DISCCART
RE DISCCART
RE DISCCART
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RE DISCCART
RE DISCCART
RE DISCCART
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RE -DISCCART
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RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
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RE DISCCART
RE DISCCART
RE DISCCART
K DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
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2165.06323
2598.07593
3464.10132
4330.12646
6495.18994
8660.25293
12990.37990
17320.50590
25980.75980
34641.01170
43301.26560
93.96925
187.93851
281.90778
375.87701
469.84628
563.81555
657.78479
751.75403
845.72327
939.69257
1174.61572
1409.53882
1644.46191
1879.38513
2114.30811
2349.23145
2819.07764
3758.77026
4696.46289
7047.69385
9396.92578
14095.38770
18793.85160
28190.77540
37587.70310
46984.62890
98.48077
196.96155
295.44232
393.92310
492.40384
590.884M
689.36542
787.84619
886.32697
984.80768
1231.00964
1477.21155
1723.41345
1969.61536
2215.81738
2462.01929
2954.42310
3939.23071
4924.03857
7386.05762
9848.07715
14772.11520
19696.15430
347.5
353.6
353.6
384.0
384.0
384.0
378.0
365.8
371.9
360.0
360.0
340.0
380.0
350.0
213.4
225.6
225.6
225.6
225.6
243.8
262.1
286.5
280.4
292.6
323.1
353.6
359.7
359.7
329.2
347.5
378.0
385.0
371.9
329.2
349.0
360.0
360.0
340.0
370.0
350.0
213.4
225.6
225.6
225.6
22S.6
243.8
262.1
292.6
298.7
296.7
335.3
365.8
359.7
359.7
341.4
378.0
384.0
378.0
365.8
341.4
339.9
340.0
360.0
-------
RE D1SCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE FINISHED
ME STARTING
ME INPUTFIL
ME ANEMHGHT
ME SURFDATA
ME UAIRDATA
ME PROF FILE
ME PROF FILE
** DAYRANGE
ME FINISHED
-5209.45313
-6945.93750
-8682.42188
-0.00003
-0.00006
-0.00009
-0.00012
-0.00015
-0.00018
-0.00021
-0.00024
-0.00027
-0.00030
-0.00038
-0.00045
-0.00053
-0.00060
-0.00068
-0.00075
-0.00091
-0.00121
-0.00151
-0.00226
-0.00302
-0.00453
-0.00604
-0.00906
-0.01208
-0.01510
DEPBIN.MET
30.0 METERS
94823 1993
94823 1993
TEMPS ISC_TEMP
WINDS ISC WIND
1/3
29544.23050
39392.30860
49240. 38670
100.00000
200.00000
300.00000
400.00000
500.00000
600.00000
700.00000
800.00000
900.00000
1000.00000
1250.00000
1500.00000
1750.00000
2000.00000
2250.00000
2500.00000
3000.00000
4000.00000
5000.00000
7500.00000
10000.00000
15000.00000
20000.00000
30000.00000
40000.00000
50000.00000
.STK
.STK
340.0
330.0
320.0
213.4
225.6
225.6
225.6
225.6
237.7
256.0
280.4
298.7
292.6
353.6
323.1
341.4
317.0
359.7
359.7
378.0
383.4
359.7
371.9
380.1
360.0
340.0
380.0
350.0
350.0
TG STARTING
INPUTFIL wtilOOk.out
LOCATION 538.4 4497.8
TG FINISHED
OU STARTING
RECTABLE ALLAVE FIRST-SECOND
* DAYTABLE ALLAVE
MAXTABLE ALLAVE 50
* NAXIFILE 3 ALL 30.0 NAXIALL.FIL 25
* NAXIFILE 24 ALL 10.0 NAXIALL.FIL 25
* POSTFILE 1 ALL INDIV POST2C.BIN 20
* POSTFILE PERIOD ALL PLOT PSTANALL.FIL 21
* Note that the following two input cards generate PLOTFILEs with the file
** unit dynamically allocated by the ISCST2 program. When porting the Model
* to another computer system, the user Msy need to specify the file units
" as is done on the previous four input cards.
* PLOTFILE 3 ALL 2ND PLT03ALL.FIL
* PLOTFILE 24 ALL 2ND PLT24ALL.FIL
OU PLOTFILE 1 ALL 1ST ONSITE.1
OU PLOTFILE 3 ALL 1ST ONSITE.3
OU PLOTFILE 24 ALL 1ST ONSITE.24
-------
OU PLOTFILE PERIOD ALL OMSITE.ANN
* OU PLOTFILE 1 ALL 1ST OUSITE.PL2
OU FINISHED
SETUP Finishes Successfully
-------
* ISCST2 (94227): WTI Storafle Tank M>ture. ISCOMDEP - OMSITE ORGANIC TANK FARM
* MODELING OPTIONS USED:
* CONC RURAL ELEV GRDRIS NOSTD
PLOT FILE OF HIGH 1ST HIGH 1-HR VALUES FOR SOURCE GROUP: ALL
» FOR A TOTAL OF 936 RECEPTORS.
FORMAT: (3<1X,F13.5>.1X,F8.2,3X,A5,2X,A8,2X,A4)
, x Y CONC ZELEV AVE GRP HIVAL
17.36482
34.72963
52.09445
69.45927
86.82409
104.18890
121.55373
138.91852
156.28337
173.64818
217.06021
260.47229
303.88428
347.29639
390.70837
434.12042
520.94452
694.59271
868.24084
1302.36133
1736.48169
2604.72241
3472.96313
5209.44531
6945.92627
8682.40820
34.20201
68.40403
102.60603
136.80806
171.01007
205.21207
239.41408
273.61615
307.81812
342.02011
427.52518
513.03021
598.53522
684.04022
769.54523
855.05035
1026.06042
1368.08057
1710.10071
2565.15112
3420.20142
5130.30176
6840.40283
10260.60450
13680.80570
17101.00590
50.00000
100.00000
98.48077
196.96155
295.44235
393.92307
492.40384
590.88470
689.36542
787.84613
886.32697
984.80774
1231.00964
1477.21167
1723.41370
1969.61548
2215.81738
2462.01929
2954.42310
3939.23096
4924.03809
7386.05762
9848.07715
14772.11520
19696.15430
29544.23050
39392.30860
49240.38670
93.96926
187.93851
281.90778
375.87701
469.84631
563.81555
657.78491
751.75409
845.72339
939.69263
1174.61572
1409.53894
1644.46204
1879.38525
2114.30835
2349.23145
2819.07788
3758.77051
4696.46289
7047.69482
9396.92578
14095.38960
18793.85350
28190.77930
37587.70310
46984.63670
86.60254
173.20508
16.79521
16.61840
5.53868
5.30869
3.10193
3.69308
10.97034
13.74630
12.91760
16.09260
" 36.37793
29.38692
18.73467
19.57441
18.22014
16.84233
9.75648
6.88101
5.18808
3.01776
2.12708
1.25943
0.88135
0.57982
0.43556
0.34810
20.09486
62.92639
9.69793
9.42351
7.11029
5.43599
5.06535
4.94948
5.26656
15.08930
29.01570
23.78149
19.79313
16.52250
14.10990
12.23069
9.67375
6.04362
5.15676
3.00116
1.99441
1.73969
1.57623
0.73020
0.36371
0.26962
26.97623
59.04914
213.40
225.60
225.60
225.60
225.60
225.60
243.80
256.00
280.40
286.50
353.60
353.60
310.90
347.50
353.60
359.70
347.50
341.40
341.40
365.80
360.00
340.00
340.00
360.00
350.00
360.00
213.40
225.60
225.60
225.60
225.60
225.60
237.70
243.80
256.00
286.50
329.20
347.50
335.30
347.50
353.60
359.70
362.40
329.20
359.70
369.70
385.90
340.00
340.00
360.00
380.00
390.00
213.40
219.50
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1 MR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-Mt
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
-------
150.00000
200.00000
250.00000
300.00000
350.00000
400.00000
450.00000
500.00000
625.00000
750.00000
875.00000
1000.00000
1125.00000
1250.00000
1500.00000
2000.00000
2500.00000
3750.00000
5000.00000
7500.00000
10000.00000
15000.00000
20000.00000
25000.00000
64.27876
128.55754
192.83627
257.11508
321 .39377
385.67258
449.95132
514.23016
578.50885
642.78766
803.48456
964.18140
1124.87830
1285.57520
1446.27197
1606.96912
1928.36292
2571.15039
3213.93799
4820.90625
6427.87549
9641 .81250
12855.75200
19283.62700
25711.50390
32139.37890
76.60445
153.20888
229.81335
306.41779
383.02225
459.62671
536.23120
612.83557
689.44000
766.04443
957.55554
1149.06665
1340.57764
259.80762
346.41016
433.01273
519.61517
606.21777
692.82031
779.42291
866.02539
1082.53174
1299.03821
1515.54443
1732.05090
1948.55713
2165.06348
2598.07617
3464.10156
4330.12695
6495.19043
8660.25391
12990.38090
17320.50780
25980.76170
34641.01560
43301.26560
76.60445
153.20888
229.81335
306.41779
383.02225
459.62671
536.23120
612.83557
689.44000
766.04443
957.55554
1149.06665
1340.57764
1532.08899
1723.59998
1915.11108
2298.13330
3064.17798
3830.22192
5745.33301
7660.44434
11490.66600
15320.88870
22981.33400
30641.77730
38302.22270
64.27876
128.55754
192.83629
257.11508
321.39377
385.67261
449.95132
514.23016
578.50885
642.78766
803.48456
964.18140
1124.87830
27.20872
15.02902
14.53630
8.97993
6.45860
8.83360
14.90733
15.70679
7.27158
27.62148
21.64511
18.32998
15.58878
14.43524
11.43595
7.01111
5.10995
2.97486
1.97396
- 2.82748
0.96089
0.51697
0.37340
0.26257
33.78500
34.00709
100.29875
57.44691
33.55591
13.53698
7.75491
5.32684
5.06455
15.17323
22.78652
27.62006
21.84241
18.55730
15.75471
13.64595
11.16552
7.19737
5.33632
2.98305
1.96627
1.24070
0.86084
0.67867
0.32632
0.24829
20.86079
0.00000
55.07706
45.54440
21.33775
17.94308
13.29508
9.78028
9.54597
6.58953
4.85307
29.78035
22.22086
225.60
225.60
225.60
225.60
225.60
231.60
243.80
262.10
225.60
347.50
359.70
353.60
353.60
329.20
323.10
361.20
366.70
378.00
396.20
320.00
360.00
380.00
370.00
400.00
213.40
213.40
225.60
225.60
225.60
225.60
225.60
225.60
225.60
243.80
280.40
353.60
361.50
353.60
353.60
353.60
335.30
353.90
353.00
378.00
398.40
376.00
380.00
360.00
420.00
420.00
213.40
207.30
213.40
219.50
219.50
219.50
219.50
219.50
225.60
219.50
219.50
323.10
353.60
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-Hft ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-MJ ALL
1-HR ALL
1-HR ALL
1-HR ALL
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
-------
1532.08899
1723.59998
1915.11108
2298.13330
3064.17798
3830.22192
5745.33301
7660.44434
11490.66600
15320.88870
22981 .33400
30641.77730
38302.22270
86.60254
173.20508
259.80762
346.41016
433.01273
519.61517
606.21777
692.82031
779.42291
866.02539
1082.53174
1299.03821
1515.54443
1732.05090
1948.55725
2165.06348
2596.07617
3464.10156
4330.12695
6495.19043
8660.25391
12990.38090
17320.50780
25980.76170
34641.01560
43301.26560
93.96926
187.93851
281.90778
375.87701
469.84631
563.81555
657.78491
751.75409
845.72333
939.69263
1174.61572
1409.53894
1644.46204
1879.38525
2114.30835
2349.23145
2819.07788
3758.77051
4698.46289
7047.69482
9396.92578
14095.38960
18793.85350
28190.77930
1285.57520
1446.27197
1606.96912
1928.36292
2571.15039
3213.93799
4820.90674
6427.87549
9641.81348
12855.75200
19283.62700
25711.50390
32139.38090
50.00000
TT.yTTTT
150.00000
199.99997
249.99997
300.00000
349.99994
399.99994
449.99994
499.99994
625.00000
750.00000
875.00000
1000.00000
1125.00000
1250.00000
1500.00000
2000.00000
2499.99976
3749.99976
4999.99902
7499.99902
9999.99902
14999.99900
19999.99800
24999.99800
34.20201
68.40403
102.60603
136.80806
171.01007
205.21207
239.41411
273.61615
307.81815
342.02011
427.52518
513.03021
598.53528
684.04022
769.54535
855.05035
1026.06042
1368.08057
1710.10071
2565.15112
3420.20142
5130.30176
6840,40283
10260.60450
18.47447
16.48253
13.82754
10.77820
7.44035
5.59988
3.05963
1.99478
1.29926
0.86138
0.51739
0.32525
0.24724
27.17797
0.00000
18.20800
9.06094
16.68992
29.36513
* 25.16099
22.83578
20.88769
27.52405
28.21201
17.26831
25.65752
21.83312
21.23749
17.81623
14.05590
9.35248
6.25248
3.38971
2.09213
1.31895
1.12988
0.53638
0.37378
0.25133
12.33390
0.00000
7.39211
8.37012
10.97494
7.23640
4.84703
9.17665
9.66306
9.78090
9.29955
8.43639
7.42095
7.03921
6.56121
24.12316
20.86826
9.63144
5.81526
3.33586
2.35683
1.39824
0.90783
0.50488
353.60
335.30
347.50
347.50
341.40
335.30
373.10
396.20
360.00
380.00
380.00
420.00
420.00
213.40
207.30
207.30
201.20
207.30
213.40
213.40
213.40
213.40
219.50
225.60
219.50
243.80
292.60
310.90
323.10
317.00
323.10
359.70
378.90
406.70
380.00
360.00
380.00
380.00
420.00
207.30
201.20
202.70
202.70
207.30
207.30
207.30
213.40
213.40
213.40
213.40
213.40
213.40
213.40
213.40
231.60
231.60
310.90
384.00
384.00
370.30
360.00
380.00
400.00
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-Hvi ALL
1-H* ALL
1-HR ALL
1-HR ALL
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
-------
37587.70310
46984.63670
98.48077
196.96155
295.44235
393.92307
492.40384
590.88470
689.36542
787.84613
886.32697
984.80774
1231.00964
1477.21167
1723.41370
1969.61548
2215.81738
2462.01929
2954.42310
3939.23096
4924.03809
7386.05762
9848.07715
14772.11520
19696.15430
29544.23050
39392.30860
49240.38670
100.00000
200.00000
300.00000
400.00000
500.00000
600.00000
700.00000
800.00000
900.00000
1000.00000
1250.00000
1500.00000
1750.00000
2000.00000
2250.00000
2500.00000
3000.00000
4000.00000
5000.00000
7500.00000
10000.00000
15000.00000
20000.00000
30000.00000
40000.00000
50000.00000
98.48077
196.96155
295.44235
393.92307
492.40384
590.88470
689.36542
787.84613
886.32697
13680.80570
17101.00780
17.36482
34.72964
52.09447
69.45930
86.82410
104.18893
121 .55376
138.91856
156.28340
173.64821
217.06027
260.47235
303.88434
347.29648
390.70850
434.12051
520.94470
694.59296 -
868.24103
1302.36169
1736.48218
2604.72290
3472.96411
5209.44580
6945.92822
8682.41113
0.00001
0.00002
0.00002
0.00003
0.00004
0.00005
0.00005
0.00006
0.00007
0.00008
0.00009
0.00011
0.00013
0.00015
0.00017
0.00019
0.00023
0.00030
0.00038
0.00057
0.00075
0.00113
0.00151
0.00226
0.00302
0.00377
17.36482
-34.72964
-52.09446
-69.45927
-86.82410
-104.18891
-121.55373
-138.91853
-156.28339
0.62891
0.26623
2.59753
4.69783
8.48135
4.77423
5.68795
4.62604
3.23299
3.10778
2.97928
2.75755
2.63681
2.60276
3.90019
3.02954
3.33715
10.95022
17.00310
10.19148
7.07213
3.61724
2.53417
4.01392
1.03218
0.57193
0.39790
0.28149
1.92787
5.61738
5.52209
7.13858
4.49742
2.27909
1.83655
1.56700
1.53429
1.81226
15.36937
40.81028
34.50356
27.13080
25.28048
40.27191
16.60923
9.75752
6.26888
4.22683
2.58858
1.57603
1.20421
0.59988
0.39122
0.80650
5.56092
3.58844
1.14107
1.82645
3.62259
2.75895
2.71497
16.38509
29.87196
360.00
400.00
207.30
202.70
202.70
202.70
202.70
202.70
202.70
202.70
202.70
202.70
202.70
202.70
213.40
207.30
207.30
231.60
304.80
346.60
365.80
384.00
371.90
320.00
360.00
380.00
380.00
400.00
207.30
202.70
202.70
202.70
202.70
202.70
202.70
202.70
202.70
202.70
243.80
341.40
323.10
341.40
304.80
292.60
310.90
359.70
402.30
347.50
380.10
360.00
360.00
380.00
400.00
360.00
207.30
202.70
202.70
202.70
202.70
202.70
202.70
219.50
225.60
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
l-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
-------
984.80774
1231.00964
1477.21167
1723.41370
1969.61548
2215.81738
2462.01929
2954.42310
3939.23096
4924.03809
7386.05762
9848.07715
14772.11520
19696.15430
29544.23050
39392.30860
49240.38670
93.96926
187.93851
281 .90778
375.87701
469.84631
563.81555
657.78491
751.75409
845.72339
939.69263
1174.61584
1409.53894
1644.46216
1879.38525
2114.30835
2349.23145
2819.07788
3758.77051
4698.46338
7047.69482
9396.92676
14095.38960
18793.85550
28190.77930
37587.70700
46984.63670
86.60254
173.20508
259.80762
346.41016
433.01273
519.61517
606.21777
692.82031
779.42291
866.02539
1082.53174
1299.03821
1515.54443
1732.05090
1948.55713
2165.06348
2598.07617
3464.10156
4330.12695
6495.19043
-173.64819
-217.06023
-260.47232
-303.88431
-347.29642
-390.70840
-434.12045
-520.94458
-694.59277
-868.24091
-1302.36145
-1736.48181
-2604.72290
-3472.96338
-5209.44580
-6945.92676
-8682.40918
-34.20201
-68.40402
-102.60603
-136.80804
-171.01006
-205.21207
-239.41406
-273.61612
-307.81812
-342.02008
-427.52515
-513.03021
-598.53522
-684.04016
-769.54523
-855.05023
-1026.06030
-1368.08032
-1710.10059
-2565.15088
-3420.20093
-5130.30127
-6840.40234
-10260.60350
-13680.80470
-17101.00590
-50.00000
-100.00001
150.00002
-200.00002
-250.00003
-300.00003
-350.00003
-400.00003
-450.00003
-500.00006
-625.00006
-750.00006
-875.00006
-1000.00012
-1125.00012
-1250.00012
-1500.00012
-2000.00024
-2500.00024
-3750.00049
47.39488
35.12508
30.09088
23.13125
18.63275
16.09868
14.47428
14.88407
9.85795
6.85141
4.23198
3.01603
1.66579
1.22616
0.73998
0.52144
0.37662
7.23791
2.85747
2.54463
1.01166
1.63203
6.18410
60.31136
64.43974
56.14117
45.98010
34.14631
27.58699
21.40200
20.86284
17.59651
15.12554
12.18979
8.55346
. 7.06592
4.30253
2.70832
1.74549
1.73035
1.45142
1.19983
1.01686
7.53693
3.91989
1.94186
0.60907
1.40083
17.92687
68.57710
53.22472
45.19359
40.00871
33.03910
25.07100
19.61588
17.31517
17.01828
13.59570
11.98690
7.98354
6.89194
3.92211
329.20
347.50
353.60
323.10
341.40
341.40
323.10
347.50
353.60
386.50
353.60
360.00
340.00
380.00
380.00
380.00
400.00
207.30
202.70
202.70
202.70
202.70
213.40
256.00
298.70
286.50
323.10
347.50
347.50
310.90
353.60
350.20
347.50
347.50
345.90
371.90
365.80
408.40
380.00
360.00
360.00
360.00
360.00
207.30
202.70
202.70
202.70
213.40
268.20
317.00
347.50
353.60
347.50
310.90
359.70
335.30
359.70
359.70
347.50
365.80
359.70
353.60
402.30
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-H*
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
AU.
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
-------
8660.25391
12990.38090
17320.50780
25980.76170
34641.01560
43301.26560
76.60445
153.20888
229.81332
306.41779
383.02225
459.62668
536.23108
612.83557
689.44000
766.04443
957.55554
1149.06665
1340.57764
1532.08899
1723.59998
1915.11108
2298.13330
3064.17798
3830.22192
5745.33252
7660.44434
11490.66500
15320.88870
22981 .33200
30641.77730
38302.22270
64.27876
128.55754
192.83629
257.11508
321.39377
385.67261
449.95132
514.23016
578.50885
642.78766
803.48456
964.18146
1124.87830
1285.57520
1446.27197
1606.96912
1928.36292
2571.15039
3213.93799
4820.90674
6427.87549
. 9641.81348
12855.75200
19283.62700
25711.50390
32139.38090
50.00000
100.00001
150.00002
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-192.83629
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329
359
353
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408
420
371
392
390
340
380
400
400
380
207
202
202
213
268
.20 1-HR ALL
.00 .1-HR ALL
.00 1-HR ALL
.00 1-HR ALL
.00 1-HR ALL
.00
.30
1-HR ALL
1-HR ALL
.70 1-HR ALL
.70
1-HR ALL
.70 1-HR ALL
.80
.70
.10
.60
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
.60 1-HR ALL
.60
1-HR ALL
.60 1-HR ALL
.70 1-HR ALL
.40 1-HR ALL
.60 1-HR ALL
.60 1-HR ALL
.40 1-HR ALL
.70 1-HR ALL
.70 1-HR ALL
.70
.40
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1-HR ALL
1-HR ALL
1-HR ALL
.00 1-HR ALL
.00
1-HR ALL
.00 1-HR ALL
.00 1-HR ALL
.00 1-HR ALL
.30 1-HR ALL
.70 1-HR ALL
.70
1-HR ALL
.70 1-HR ALL
.20
.80
.90
.10
.20
.10
.50
.70
.20
.70
.60
.70
.40
.60
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-NR ALL
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.10 1-HR ALL
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.00 1-HR ALL
.00 1-HR ALL
.00 1-HR ALL
.30 1-HR ALL
.70 1-HR ALL
.70 1-HR ALL
.40 1-HR ALL
.20 1-HR ALL
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
-------
300.00003
350.00003
400.00003
450.00003
500.00003
625.00006
750.00006
875.00006
1000.00006
1125.00012
1250.00012
1500.00012
2000.00012
2500.00024
3750.00024
5000.00049
7500.00049
10000.00100
15000.00100
20000.00200
25000.00200
34.20202
68.40405
102.60606
136.80809
171.01012
205.21213
239.41414
273.61621
307.81821
342.02023
427.52527
513.03033
598.53546
684.04047
769.54547
855.05054
1026.06079
1368.08081
1710.10107
2565.15161
3420.20190
5130.30273
6840.40430
10260.60550
13680.80860
17101.01170
17.36483
34.72966
52.09449
69.45933
86.82413
104.18897
121.55380
138.91862
156.28346
173.64827
217.06036
260.47244
303.88449
347.29657
390.70868
434.12073
-519.61517
-606.21777
-692.82031
-779.42291
-866.02539
-1082.53174
-1299.03821
-1515.54443
-1732.05090
-1948.55713
-2165.06348
-2598.07617
-3464.10156
-4330.12695
-6495.19043
-8660.25391
-12990.38090
-17320.50780
-25980.76170
-34641.01560 ~
-43301.26560
-93.96926
-187.93851
-281.90778
-375.87701
-469.84631
-563.81555
-657.78479
-751.75409
-845.72333
-939.69257
-1174.61572
-1409.53894
-1644.46204
-1879.38513
-2114.30835
-2349.23145
-2819.07788
-3758.77026
-4698.46289
-7047.69434
-9396.92578
-14095.3887D
-18793.85350
-28190.77730
-37567.70310
-46984.62890
-96.48077
-196.96155
-295.44235
-393.92307
492.40384
-590.88470
-689.36542
-787.84613
-886.32697
-984.80774
-1231.00964
-1477.21143
-1723.41370
-1969.61548
-2215.81738
-2462.01929
66.08169
66.22234
56.64050
49.93258
43.79440
31.07504
26.65701
22.13122
17.84415
15.17900
13.08045
9.27843
6.20439
4.84817
2.84755
2.09474
1.65744
0.92703
0.50641
0.37813
0.28847
1 .37136
3.75761
1 .62716
2.51654
43.81467
45.06506
48.77239
42.64601
29.65354
26.27966
33.52996
27.65158
22.71933
18.64600
16.64400
14.82052
11.49531
8.14357
6.11550
3.85132
2.67066
1.75650
1.23901
0.66618
0.49753
0.35912
1.14018
1.51251
2.86994
1.32097
77.43610
53.58073
46.07051
34.40146
30.28798
26.93969
23.40391
20.81326
17.37552
13.80886
12.04333
14.79132
298.70
310.90
323.10
323.10
329.20
296.70
341.40
341.40
359.70
365.80
371.90
408.4C
420.60
408.40
408.40
396.20
340.00
360.00
420.00
400.00
400.00
207.30
202.70
202.70
207.30
268.20
292.60
304.80
304.80
286.50
286.50
304.80
310.90
304.80
335.30
359.70
378.00
396.20
402.30
411.50
402.30
408.10
360.00
360.00
420.00
400.00
420.00
207.30
202.70
202.70
202.70
249.90
286.50
280.40
274.30
286.50
286.50
296.70
304.80
304.80
296.70
298.70
365.80
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
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1-HR
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ALL
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-------
520.94489
694
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402.30 1-HR
390.10 1-HR
414
408
.50 1-HR
.40 1
-HR
398.10 1-H8
380
360
400
400
.00 1-HR
.00 1-HR
.00 1-HR
.00 1-HR
400.00 1-HR
207
202
202
202
219
274
280
274
243
298
304
304
304
292
298
365
406
402
396
390
396
380
360
380
380
400
207
202
202
202
202
225
274
274
237
292
304
286
.30 1-HR
.70 1-HR
.70 1-HR
.70 1-HR
.50 1-HR
.30
.40
.30
.80
.70
-HR
-HR
-HR
-HR
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.80 1-HR
.80 1-HR
.80 1-HR
.60 1
-HR
.70 1-HR
.80 1-HR
.30 1-HR
.30 1-HR
.20 1
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.10 1-HR
.20 1
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.00 1-HR
.00 1
.00
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292.60
280
304
353
384
396
415
390
392
360
340
340
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1-HR
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1-HR
360.00 1-HR
380.00 1-HR
213.40 1-HR
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
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ALL
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ALL
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ALL
ALL
ALL
ALL
ALL
ALL
ALL
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1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
-------
-68.40403
-102.60605
-136.80806
-171.01009
-205.21210
-239.41411
-273.61615
-307.81815
-342.02014
-427.52521
-513.03021
-598.53528
-684.04034
-769.54535
-855.05042
-1026.06042
-1368.08069
-1710.10083
-2565.15112
-3420.20142
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-64.27876
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-803.48456
-964.18134
-187.93851
-281.90778
-375.87701
-469.84631
-563.81555
-657.78491
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-845.72333
-939.69263
-1174.61572
-1409.53894
-1644.46204
-1879.38525
-2114.30835
-2349.23145
-2819.07788
-3758.77051
-4698.46289
-7047.69482
-9396.92578
-14095.38960
-18793.85350
-28190.77930
-37587.70310
-46984.62890
-86.60254
-173.20508
-259.80762
-346.41016
-433.01273
-519.61517
-606.21777
-692.82031
-779.42291
-866.02539
-1082.53174
-1299.03821
-1515.54443
-1732.05090
-1948.55713
-2165.06348
-2598.07617
-3464.10156
-4330.12695
-6495.19043
-8660.25391
-12990.38090
-17320.50780
-25980.76170
-34641.01560
-43301.26560
-76.60445
-153.20888
-229.81335
-306.41779
-383.02228
-459.62671
-536.23120
-612.83557
-689.44000
-766.04449
-957.55560
-1149.06689
0.86153
0.93634
1 »OooOV
2.05185
2.94671
18.42518
48.94185
8.92396
27.73095
22.20589
20.58523
23.44049
24.37258
24.78194
12.96266
12.41295
8.66000
6.82291
4.40018
- 3.12666
1.70519
1.51687
0.80036
0.58628
0.44819
5.39811
1.32882
1.44368
1.52961
2.20288
2.48093
2.45845
2.27271
2.44395
9.57495
11.06908
8.12199
8.05387
15.33556
13.64701
16.00921
11.35485
8.74818
6.48581
4.25152
3.05143
1.82504
1.35214
1.17298
0.99391
0.44796
5.64776
2.28080
2.93358
3.35882
2.75452
2.62344
2.44089
2.18523
1.91879
1.72417
2.03672
4.56743
202.70
202.70
202.70
202.70
202.70
219.50
249.90
219.50
280.40
280.40
280.40
280.40
262.10
296.70
353.60
371.90
402.30
397.20
384.00
384.00
340.00
340.00
360.00
380.00
380.00
213.40
202.70
202.70
202.70
202.70
202.70
202.70
202.70
202.70
219.50
219.50
213.40
213.40
231.60
231.60
292.60
359.70
396.20
414.50
396.20
392.60
360.00
380.00
360.00
360.00
380.00
213.40
202.70
202.70
202.70
202.70
202.70
202.70
202.70
202.70
202.70
202.70
213.40
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-KR
1-HR
1-HR
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
AIL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
-------
-1124.87830
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1948.55725
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12990.38180
17320.50980
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-964.18115
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-9641.81250
-12855.75000
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-25711.50000
-32139.37700
-49.99999
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-149.99997
-199.99994
-249.99994
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449.99988
-499.99988
624.99988
-749.99988
-874.99962
-999.99982
-1124.99976
-1249.99976
-1499.99976
-1999.99963
-2499.99951
-3749.99927
-4999.99854
-7499.99805
-9999.99805
4.31771
4.53335
4.62574
4.63243
10.26536
7.03551
5.04717
2.95479
2.09482
2.16312
1.62116
1.03687
0.35845
0.56918
18.36013
2.49516
3.85340
5.35805
4.28739
- 4.57951
4.56497
4.35188
4.20323
3.83155
2.98818
2.33672
1.85432
2.26492
2.44622
13.31734
12.64878
8.06207
5.66495
3.43284
2.42915
1.50944
1.03402
0.59627
0.42175
0.33931
10.86113
10.37302
10.07992
4.63257
9.71033
8.79602
8.68886
8.52437
8.36413
8.20592
19.95044
33.91507
24.77423
22.17144
26.00478
25.29171
23.81646
7.91192
5.86184
3.43095
2.27681
1.62650
1.03379
213.40
213.40
213.40
213.40
371.90
378.00
396.20
396.20
378.00
349.00
360.00
360.00
380.00
360.00
213.40
201.20
207.30
207.30
202.70
202.70
202.70
202.70
207.30
207.30
207.30
207.30
207.30
213.40
213.40
256.00
323.10
359.70
384.00
378.00
378.00
360.00
380.00
400.00
400.00
380.00
213.40
213.40
213.40
207.30
213.40
213.40
213.40
213.40
213.40
213.40
225.60
274.30
329.20
310.90
286.50
256.00
243.80
365.80
372.50
378.00
402.30
360.00
380.00
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HS ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
-HR ALL
-MR ALL
-HR ALL
-HR ALL
-HR ALL
-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
I-K; ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
-------
-25980.76370
-34641.01950
-43301 .27340
-93.96926
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-375.87701
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-845.72339
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0.00000
0.00000
0.00000
0.00000
0.00001
0.00001
0.00001
0.00001
0.62859
0.42170
0.96324
7.86850
18.80952
25.32590
27.80023
28.05257
27.25646
23.85008
41.54283
38.07674
19.90770
34.40738
27.84657
23.96006
20.74460
16.98963
17.09451
- 22.68429
12.31288
6.09084
3.54936
2.97932
1.91597
1.28700
0.82624
0.55549
0.45978
29.34946
10.83371
4.15836
6.76746
6.52867
7.37878
7.82478
8.32453
9.51651
50.06646
34.01350
27.77934
23.66722
20.31624
18.26186
16.04321
13.38622
9.71345
7.51949
4.36529
3.36789
2.61097
1.78871
0.74273
0.55564
0.42435
12.76491
3.06791
6.02702
9.60168
8.68618
9.13065
9.20840
8.77952
380.00
400.00
360.00
213.40
213.40
213.40
213.40
213.40
213.40
213.40
219.50
219.50
213.40
353.60
353.60
341.40
335.30
353.60
304.80
243.80
298.70
359.70
365.80
402.30
380.00
400.00
380.00
400.00
360.00
213.40
213.40
213.40
213.40
213.40
213.40
213.40
219.50
225.60
310.90
359.70
359.70
36S.80
371.90
353.60
371.90
353.60
365.80
365.80
390.10
339.90
360.00
380.00
420.00
400.00
400.00
213.40
213.40
213.40
213.40
213.40
213.40
213.40
213.40
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-NR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
-------
-900.00000
-1000.00000
-1250.00000
-1500.00000
-1750.00000
-2000.00000
-2250.00000
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14772.11520
19696.15430
29544.23050
39392.30860
49240.38670
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0.00001
0.00001
0.00001
0.00002
0.00002
0.00002
0.00003
0.00003
0.00004
0.00005
0.00006
0.00009
0.00012
0.00018
0.00024
0.00036
0.00048
0.00060
17.36481
34.72963
52.09445
69.45927
86.82407
104.18890
121.55371
138.91850
156.28336
173.64815
217.06020
260.47226
303.88428
347.29633
390.70834
434.12039
520.94452
694.59259
868.24072
1302.36133
1736.48157
2604.72241
3472.96289
5209.44482
6945.92578
8682.40820
34.20201
68.40401
102.60603
136.80803
171.01004
205.21204
239.41405
273.61609
307.81808
342.02008
427.52512
513.03021
598.53522
684.04016
769.54517
855.05017
1026.06030
1368.08020
1710.10034
9.68365
37.71264
26.04151
21.13331
19.57903
18.67771
18.07789
16.14324
13.22895
9.45539
7.43008
4.58871
3.30346
1.88862
1.40696
0.82705
0.58559
0.42451
4.10510
" 3.68074
5.41183
8.30245
6.39872
6.91676
5.92658
13.92644
15.20514
19.01018
27.81129
21.44968
16.65633
14.89861
13.11940
12.07690
9.71089
7.14024
5.25179
3.17776
2.20612
1.07114
0.70314
0.47572
0.33406
0.23940
6.75835
2.85728
3.10267
3.43951
3.34285
2.90392
4.51938
17.65741
25.69429
31.42371
28.42215
15.94647
12.67577
13.71146
11.06869
9.93518
8.04758
5.74839
4.39151
243.80
296.70
304.80
304.80
335.30
341.40
371.90
371.90
371.90
378.00
371.90
371.90
360.00
340.00
360.00
380.00
380.00
400.00
213.40
213.40
213.40
213.40
213.40
225.60
225.60
237.70
243.80
280.40
317.00
304.80
296.70
341.40
371.90
353.60
365.80
353.60
378.00
384.00
389.20
400.00
420.00
380.00
380.00
400.00
213.40
213.40
213.40
219.50
225.60
225.60
243.80
274.30
286.50
296.70
317.00
296.70
296.70
359.70
384.00
378.00
378.00
378.00
378.00
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
-HR
-HR
-HR
-HR
-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
-HR
-HR
-HR
-HR
-HR
-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
-HR
-HR
-HR
-HR
-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
-------
-7047.69482
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2565.15063
3420.20093
5130.30078
6840.40186
10260.60250
13680.80370
17101.00390
49.99999
99.99998
149.99997
199.99997
249.99994
299.99991
349.99991
399.99991
449.99991
499.99988
624.99988
749.99988
874.99988 "
999.99982
1125.00000
1249.99976
1499.99976
1999.99963
2499.99951
3749.99951
4999.99854
7499.99854
9999.99805
14999.99800
19999.99610
24999.99610
64.27876
128.55751
192.83626
257.11499
321.39374
385.67255
449.95126
514.22998
578.50873
642.78760
803.48444
964.18121
1124.87830
1285.57507
1446.27173
1606.96887
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2571.15015
3213.93750
4820.90576
6427.87451
9641.81250
12855.75000
19283.62500
25711.50000
32139.37700
76.60442
153.20885
229.81332
306.41772
2.87244
1.72744
1.04763
0.92909
0.46991
0.34988
0.25169
7.29729
2.66494
1.88088
3.08625
2.50315
3.92369
8.42885
31 .76547
32.02022
28.58289
19.71223
21.17135
16.48961
13.68632
12.01355
10.49539
8.51523
6.10111
4.59829
2.79373
1.72431
1.11421
0.78104
0.44347
0.33119
0.50245
6.74444
2.43339
3.34839
2.39780
2.01682
2.16860
14.90388
38.32604
36.18783
32.62605
22.65782
21.43189
17.14719
14.15745
12.20940
10.65245
8.48230
6.46535
4.63533
2.85532
1.98738
1.24561
0.78267
0.47113
0.33153
0.45354
8.48427
8.40527
4.^6649
2.18069
371 .90 1
424.90 1
420.00 1
360.00
400.00 1
380.00 '
400.00 1
213.40
213.40 1
219.50 1
231.60 '
225.60 1
231.60 1
268.20 1
304.80 '
310.90 1
304.80
292.60
323.10
359.70
371.90
371.90
378.00
378.00
378.00
384.00
384.00
426.70
400.00
400.00
420.00
400.00
350.00
213.40
213.40
225.60
231.60
225.60
23.1.60
268.20
304.80
316.40 '
317.00
304.80
341.40
353.60
365.80
371.90
378.00
384.00
359.70
384.00
378.00
379.20
360.00
400.00
400.00
400.00
370.00
213.40
225.60
231.60
231.60
-HR
-HR
I-HR
-HR
-HR
-HR
-HR
HR
HR
-HR
-HR
-HR
HR
-HR
-HR
-HR
-HR
-HR
-HR
-HR
-HR
-HR
HR
-HR
-HR
-HR
-HR
-HR
-HR
-MR
-HR
-HR
-HR
-HR
-HR
-HR
-HR
-HR
-HR
-HR
-HR
-HR
-HR
-HR
-HR
I-HR
I-HR
I-HR
I-HR
I-HR
I-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
-------
-321
-385
.39383
.67267
-449.95142
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-578
-642
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-964
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12855
19283
25711
.23022
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.48474
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.87854
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.27222
.96936
.36328
.15088
.93872
.90771
.87695
.81543
.75490
.63090
.50980
32139.38670
-50
-100
-150
-200
-250
-300
-350
-400
-450
-500
-625
-750
-875
.00002
.00003
.00005
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.00012
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.00024
.00024
.00031
-1000.00037
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-1250
-1500
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10000
15000
20000
25000
-34
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-769
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.20204
.40408
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.02036
.52545
.03052
.53571
.04065
.54584
383
459
536
612
689
766
957
1149
1340
1532
1723
1915
2298
3064
3830
5745
7660
11490
.02216
.62665
.23102
.83551
.43988
.04431
.55542
.06653
.57751
.08862
.59973
.11084
.13306
.17749
.22144
.33203
.44336
.66410
15320.88670
22981
30641
.33010 '
.77340
38302.21880
86
173
259
346
433
519
606
692
779
866
1082
1299
.60253
.20506
.80756
.41013
.01270
.61517
.21771
.82025
.42279
.02533
.53162
.03784
1515.54431
1732
1948
2165
2596
3464
4330
.05066
.55701
.06323
.07593
.10132
.12646
6495.18994
8660
12990
17320
25980
34641
43301
93
187
281
375
469
563
657
751
845
939
1174
1409
1644
1879
2114
.25293
.37990
.50590
.75960
.01170
.26170
.96925
.93851
.90778
.87696
.84631
.81555
.78479
.75403
.72327
.69257
.61572
.53894
.46191
.38513
.30811
4
12
20
40
34
30
24
23
20
17
14
12
9
6
5
2
1
1
.08251
.21246
.82514
.21757
.97815
.83339
.27721
.19573
.07016
.05709
.80667
.93382
.78141
.69608
.06957
.92663
.96190
.14278
0.76577
0
0
.46537
.59070
0.51383
8.62542
6
3
8
0
2
2
2
27
24
9
19
19
17
.76894
.82833
.45730
.82822
.55397
.81276
.89723
.36086
.50089
.91413
.44755
.85781
.44489
15.06950
12
9
6
.57573
.93906
.77750
5.11994
3
2
1
1
0
0
0
.03971
.00307
.32361
.05032
.72083
.33429
.43038
8.87911
10
.94706
3.05174
1
0
1
4
14
10
12
22
25
21
.86096
.58779
.20937
.06183
.22526
.02501
.97981
.93865
.57636
.21321
16.50457
12
.81844
225
231
274
304
310
310
317
347
353
353
359
365
384
384
378
378
378
380
400
400
360
360
.60 1-HR
.60 1-HR
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
30
80
90
90
00
50
60
60
70
80
00
00
00
00
00
00
00
-HR
-HR
-HR
-HR
-HR
-HR
-HR
-HR
-HR
-HR
-HR
HR
-HR
-HR
-HR
-HR
-HR
.00 1-HR
.00 1-HR
.00 1-HR
213.40
225
231
231
225
1-HR
.60 1-HR
.
,
.
60
60
60
243.80
249
243
304
304
286
329
347
353
353
384
384
384
.
90
1-HR
1-HR
1-HR
1-HR
1-HR
.80 1-HR
.
,
.
.
.
.
.
»
80
80
50
20
50
60
60
00
-HR
-HR
-HR
-HR
-HR
-HR
-HR
-HR
.00 1-HR
.00 1-HR
378.
365
371
360
00 1-HR
.80 1-HR
.
90
1-HR
.00 1-HR
360.00
340
380
350
213
225
225
225
225
243
262
286
280
292
323
353
1-HR
.00 1-HR
.00 1-HR
.
00
1-HR
.40 1-HR
.60 1-HR
.60 1-HR
r
60
1-HR
.60 1-HR
.
80
.10
.50
.40
.60
.10
.60
359.70
359
.70
329.20
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
-------
-855.05090
-1026.06104
-1368.08130
-1710.10181
-2565.15283
-3420.20337
-5130.30518
-6840.40674
-10260.61040
-13680.81450
-17101.01760
-17.36484
-34.72969
-52.09453
-69.45937
-86.82422
-104.18906
-121.55391
-138.91873
-156.28360
-173.64844
-217.06055
-260.47269
-303.88474
-347.29691
-390.70898
-434.12109
-520.94531
-694.59375
-868.24219
-1302.36353
-1736.48438
-2604.72656
-3472.96875
-5209.45264
-6945.93701
-8682.42188
-0.00003
-0.00006
-0.00009
-0.00012
-0.00015
-0.00018
-0.00021
-0.00024
-0.00027
-0.00030
-0.00038
-0.00045
-0.00053
-0.00060
-0.00068
-0.00075
-0.00091
-0.00121
-0.00151
-0.00226
-0.00302
-0.00453
-0.00604
-0.00906
-0.01208
-0.01510
2349.23145
2819.07764
3758.77026
4698.46289
7047.69385
9396.92578
14095.38770
18793.85350
28190.77540
37587.70310
46984.62890
98.48077
196.96155
295.44235
393.92307
492.40381
590.88470
689.36542
787.84613
886.32697
984.80768
1231.00964
1477.21143
1723.41345
1969.61523
2215.81738
2462.01929
2954.42285
3939.23071
4924.03809
7386.05713
9848.07715
14772.11430
19696.15430
29544.22850
39392.30860
49240.38670
100.00000
200.00000
300.00000
400.00000
500.00000
600.00000
700.00000
800.00000
900.00000
1000.00000
1250.00000
1500.00000
1750.00000
2000.00000
2250.00000
2500.00000
3000.00000
4000.00000
5000.00000
7500.00000
10000.00000
15000.00000
20000.00000
30000.00000
40000.00000
50000.00000
11.72927
10.96301
7.7Z337
6.04301
2.96586
2.36762
1.53541
1.08532
0.60606
0.47564
0.34774
12.20264
12.15792
7.01011
1.00551
2.05384
3.54073
4.76516
14.10182
" 16.50330
14.94542
27.44732
24.43270
19.61405
21.11319
15.18397
16.30547
12.95497
9.37742
7.28307
3.88370
2.73447
1.68321
1.30668
0.73742
0.57570
0.49303
15.70024
11.35771
2.70458
3.69062
4.05660
4.32104
3.79221
13.82174
28.61089
20.37133
35.25359
24.48816
20.46308
16.81103
18.77208
16.58580
13.33968
9.34522
7.26469
4.45992
3.06368
1.86240
1.36128
0.78080
0.63847
0.54603
347.50
378.00
385.00
371.90
329.20
349.00
360.00
360.00
340.00
370.00
350.00
213.40
225.60
225.60
225.60
225.60
243.80
262.10
292.60
298.70
298.70
335.30
365.80
359.70
359.70
341.40
378.00
384.00
378.00
365.80
341.40
339.90
340.00
360.00
340.00
330.00
320.00
213.40
225.60
225.60
225.60
225.60
237.70
256.00
280.40
298.70
292.60
353.60
323.10
341.40
317.00
359.70
359.70
378.00
383.40
359.70
371.90
380.10
360.00
340.00
380.00
350.00
350.00
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
-------
* ISCST2 (94227): UTI Storage Tank R^ture,
* MODELING OPTIONS USED:
CONC RURAL ELEV «»"is
* PLOT FILE OF PERIOD VALUES FOR SOURCE GROUP: ALL
FOR A TOTAL OF 936 RECEPTORS.
FORMAT: (3(1X.F13.5),1X,FS.2,2X,A6,2X.A8,2X,I8)
,x y CONC ZELEV AVE
ISCOCEP -- ONSITE ORGANIC TANK FARM
GRP
HUM HRS
17.36482
34.72963
52.09445
69.45927
86.82409
104.18890
121.55373
138.91852
156.28337
173.64818
217.06021
260.47229
303.88428
347.29639
390.70837
434.12042
520.94452
694.59271
868.24084
1302.36133
1736.48169
2604.72241
3472.96313
5209.44531
6945.92627
8682.40820
34.20201
68.40403
102.60603
136.80806
171.01007
205.21207
239.41408
273.61615
307.81812
342.02011
427.52518
513.03021
598.53522
684.04022
769.54523
855.05035
1026.06042
1368.08057
1710.10071
2565.15112
3420.20142
5130.30176
6840.40283
10260.60450
13680.80570
17101.00590
50.00000
100.00000
98.48077
196.96155
295.44235
393.92307
492.40384
590.88470
689.36542
787.84613
886.32697
984.80774
1231.00964 '
1477.21167
1723.41370
1969.61548
2215.81738
2462.01929
2954.42310
3939.23096
4924.03809
7386.05762
9648.07715
14772.11520
19696.15430
29544.23050
39392.30860
49240.38670
93.96926
187.93851
281.90778
375.87701
469.84631
563.81555
657.78491
751.75409
845.72339
939.69263
1174.61572
1409.53894
1644.46204
1879.38525
2114.30835
2349.23145
2819.07788
3758.77051
4698.46289
7047.69482
9396.92578
14095.38960
18793.85350
28190.77930
37587.70310
46964.63670
86.60254
173.20508
0.02545
0.01694
0.00306
0.00344
0.00391
0.00438
0.01219
0.01832
0.03929
0.04757
0.12532
0.10666
0.06029
0.07316
0.06579
0.05995
0.04539
0.03239
0.02653
0.01414
0.01078
0.00656
0.00456
0.00251
0.00186
0.00136
0.03513
0.03285
0.00772
0.01256
0.00896
0.00535
0.00951
0.01138
0.01675
0.04749
0.11497
0.10945
0.08917
0.07980
0.07215
0.06242
0.05135
0.03571
0.02814
0.01694
0.01174
0.00844
0.00600
0.00306
0.00204
0.00150
0,05057
0.02778
213.40
225.60
225.60
225.60
225.60
225.60
243.80
256.00
280.40
286.50
353.60
353.60
310.90
347.50
353.60
359.70
347.50
341.40
341.40
365.80
360.00
340.00
340.00
360.00
350.00
360.00
213.40
225.60
225.60
225.60
225.60
225.60
237.70
243.80
256.00
286.50
329.20
347.50
335.30
347.50
353.60
359.70
362.40
329.20
359.70
369.70
385.90
340.00
340.00
360.00
380.00
390.00
213.40
219.50
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PER 10)
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
AIL
ALL
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
-------
150.00000
200.00000
250. 00000
300.00000
350.00000
400.00000
450.00000
500.00000
625.00000
750.00000
875.00000
1000.00000
1125.00000
1250.00000
1500.00000
2000.00000
2500.00000
3750.00000
5000.00000
7500.00000
10000.00000
15000.00000
20000.00000
25000.00000
64.27876
128.55754
192.83627
257.11508
321 .39377
385.67258
449.95132
514.23016
578.50885
642.78766
803.48456
964.18140
1124.87830
1285.57520
1446.27197
1606.96912
1928.36292
2571.15039
3213.93799
4820.90625
6427.87549
9641.81250
12855.75200
19283.62700
25711.50390
32139.37890
76.60445
153.20888
229.81335
306.41779
383.02225
459.62671
536.23120
612.83557
689.44000
766.04443
957.55554
1149.06665
1340.57764
259.80762
346.41016
433.01273
519.61517
606.21777
692.82031
779.42291
866.02539
1082.53174
1299.03821
1515.54443
1732.05090
1948.55713
2165.06348
2598.07617
3464.10156
4330.12695
6495.19043
8660.25391
12990.38090 '
17320.50780
25980.76170
34641.01560
43301 .26560
76.60445
153.20888
229.81335
306.41779
383.02225
459.62671
536.23120
612.83557
689.44000
766.04443
957.55554
1149.06665
1340.57764
1532.08899
1723.59998
1915.11108
2298.13330
3064.17798
3830.22192
5745.33301
7660.44434
11490.66600
15320.88870
22981.33400
30641.77730
38302.22270
64.27876
128.55754
192.83629
257.11508
321.39377
385.67261
449.95132
514.23016
578.50885
642.78766
803.48456
964.18140
1124.87830
0.04241
0.02802
0.02022
0.01467
0.01002
0.01377
0.02142
0.03306
0.01570
0.13254
0.11912
0.09986
0.09015
0.07452
0.06321
0.04596
0.03511
0.02129
0.01400
0.01018
0.00598
0.00343
0.00241
0.00171
0.05370
0.01995
0.19797
0.17097
0.05783
0.03036
0.01963
0.01457
0.01843
0.03922
0.08612
0.17944
0.16109
0.13633
0.12412
0.10984
0.08659
0.06507
0.05013
0.02861
0.01879
0.01150
0.00831
0.00521
0.00310
0.00234
0.03277
0.00000
0.20144
0.22828
0.08641
0.04802
0.03157
0.02336
0.03823
0.02691
0.03639
0.32847
0.30432
225.60
225.60
225.60
225.60
225.60
231.60
243.80
262.10
225.60
347.50
359.70
353.60
353.60
329.20
323.10
361.20
366.70
378.00
396.20
320.00
360.00
380.00
370.00
400.00
213.40
213.40
225.60
225.60
225.60
225.60
225.60
225.60
225.60
243.80
280.40
353.60
361.50
353.60
353.60
353.60
335.30
353.90
353.00
378.00
398.40
376.00
380.00
360.00
420.00
420.00
213.40
207.30
213.40
219.50
219.50
219.50
219.50
219.50
225.60
219.50
219.50
323.10
353.60
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
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PERIOD
PERIOD
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PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL.
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
-------
1532.08899
1723.59998
1915.11108
2298.13330
3064.17798
3830.22192
5745.33301
7660.44434
11490.66600
15320.88870
22981.33400
30641.77730
38302.22270
86.60254
173.20508
259.80762
346.41016
433.01273
519.61517
606.21777
692.82031
779.42291
866.02539
1082.53174
1299.03821
1515.54443
1732.05090
1948.55725
2165.06348
2598.07617
3464.10156
4330.12695
6495.19043
8660.25391
12990.38090
17320.50780
25980.76170
34641.01560
43301.26560
93.96926
187.93851
281.90778
375.87701
469.84631
563.81555
657.78491
751.75409
845.72333
939.69263
1174.61572
1409.53894
1644.46204
1879.38525
2114.30835
2349.23145
2819.07788
3758.77051
4698.46289
7047.69482
9396.92578
14095.38960
18793.85350
28190.77930
1285.57520
1446.27197
1606.96912
1928.36292
2571.15039
3213.93799
4820.90674
6427.87549
9641.81348
12855.75200
19283.62700
25711.50390
32139.38090
50.00000
99.99999
150.00000
199.99997
249.99997
300.00000
349.99994 '
399.99994
449.99994
499.99994
625.00000
750.00000
875.00000
1000.00000
1125.00000
1250.00000
1500.00000
2000.00000
2499.99976
3749.99976
4999.99902
7499.99902
9999.99902
14999.99900
19999.99800
24999.99800
34.20201
68.40403
102.60603
136.80806
171.01007
205.21207
239.41411
273.61615
307.81815
342.02011
427.52518
513.03021
598.53528
684.04022
769.54535
855.05035
1026.06042
1368.08057
1710.10071
2565.15112
3420.20142
5130.30176
6840.40283
10260.60450
0.26639
0.22985
0.20481
0.16437
0.11599
0.08966
0.04832
0.03265
0.02060
0.01307
0.00770
0.00492
0.00370
0.02886
0.00000
0.40564
0.11439
0.11840
0.12144
0.07655
0.05486
0.05410
0.07719
0.11710
0.08957
0.19280
0.32995
0.33746
0.31120
0.24750
0.17578
0.12641
0.07047
0.04496
0.02709
0.01922
0.01059
0.00726
0.00499
0.00580
0.00000
0.03026
0.05300
0.0681B
0.05043
0.03915
0.05184
0.05533
0.05587
0.07287
0.08321
0.08773
0.08926
0.08794
0.14988
0.13186
0.18034
0.12153
0.07017
0.04957
0.02924
0.01897
0.01054
353.60
335.30
347.50
347.50
341.40
335.30
373.10
396.20
360.00
380.00
380.00
420.00
420.00
213.40
207.30
207.30
201.20
207.30
213.40
213.40
213.40
213.40
219.50
225.60
219.50
243.80
292.60
310.90
323.10
317.00
323.10
359.70
378.90
408.70
380.00
360.00
380.00
380.00
420.00
207.30
201.20
202.70
202.70
207.30
207.30
207.30
213.40
213.40
213.40
213.40
213.40
213.40
213.40
213.40
231.60
231.60
310.90
384.00
384.00
370.30
360.00
380.00
400.00
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
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PERIOD
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PER1OT
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PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL .
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL .
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760 '
8760
8760
8760
8760
8760
-------
37587.70310
46984.63670
98.48077
196.96155
295.44235
393.92307
492.40384
590.88470
689.36542
787.84613
886.32697
984.80774
1231.00964
1477.21167
1723.41370
1969.61548
2215.81738
2462.01929
2954.42310
3939.23096
4924.03809
7386.05762
9848.07715
14772.11520
19696.15430
29544.23050
39392.30860
49240.38670
100.00000
200.00000
300.00000
400.00000
500.00000
600.00000
700.00000
800.00000
900.00000
1000.00000
1250.00000
1500.00000
1750.00000
2000.00000
2250.00000
2500.00000
3000.00000
4000.00000
5000.00000
7500.00000
10000.00000
15000.00000
20000.00000
30000.00000
40000.00000
50000.00000
98.48077
196.96155
295.44235
393.92307
492.40384
590.88470
689.36542
787.84613
886.32697
13680.80570
17101.00780
17.36482
34.72964
52.09447
69.45930
86.82410
104.18893
121.55376
138.91856
156.28340
173.64821
217.06027
260.47235
303.88434
347.29648
390.70850
434.12051
520.94470
694.59296 '
868.24103
1302.36169
1736.48218
2604.72290
3472.96411
5209.44580
6945.92822
8682.41113
0.00001
0.00002
0.00002
0.00003
0.00004
0.00005
0.00005
0.00006
0.00007
0.00008
0.00009
0.00011
0.00013
0.00015
0.00017
0.00019
0.00023
0.00030
0.00038
0.00057
0.00075
0.00113
0.00151
0.00226
0.00302
0.00377
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0.00482
0.00449
0.00604
0.00687
0.01209
0.01715
0.03400
0.02922
0.03127
0.07780
0.20499
0.16610
0.12215
0.06699
0.04665
0.03223
0.01940
0.01084
0.00747
0.00536
0.00169
0.00582
0.00530
0.01446
0.00697
0.00373
0.00276
0.00284
0.00357
0.00524
0.07934
0.46378
0.36300
0.34013
0.23964
0.18899
0.19649
0.15428
0.10985
0.07560
0.04574
0.02821
0.01931
0.01072
0.00692
0.00603
0.00243
0.00382
0.00167
0.00373
0.00591
0.00500
0.00446
0.01769
0.02819
360.00
400.00
207.30
202.70
202.70
202.70
202.70
202.70
202.70
202.70
202.70
202.70
202.70
202.70
213.40
207.30
207.30
231.60
304.80
346.60
365.80
384.00
371.90
320.00
360.00
380.00
380.00
400.00
207.30
202.70
202.70
202.70
202.70
202.70
202.70
202.70
202.70
202;7D
243.80
341.40
323.10
341.40
304.80
292.60
310.90
359.70
402.30
347.50
380.10
360.00
360.00
380.00
400.00
360.00
207.30
202.70
202.70
202.70
202.70
202.70
202.70
219.50
225.60
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
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PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PEKIOD
PERIOD
PERIOD
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
-------
984.80774
1231.00964
1477.21167
1723.41370
1969.61548
2215.81738
2462.01929
2954.42310
3939.23096
4924.03809
7386.05762
9848.07715
14772.11520
19696.15430
29544.23050
39392.30860
49240.38670
93.96926
187.93851
281.90778
375.87701
469.84631
563.81555
657.78491
751.75409
845.72339
939.69263
1174.61584
1409.53894
1644.46216
1879.38525
2114.30835
2349.23145
2819.07788
3758.77051
4698.46338
7047.69482
9396.92676
14095.38960
18793.85550
28190.77930
37587.70700
46984.63670
86.60254
173.20508
259.80762
346.41016
433.01273
519.61517
606.21777
692.82031
779.42291
866.02539
. 1082.53174
1299.03821
1515.54443
1732.05090
1948.55713
2165.06348
2598.07617
3464.10156
4330.12695
6495.19043
-173.64819
-217.06023
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-347.29642
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-520.94458
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-868.24091
-1302.36145
-1736.48181
-2604.72290
-3472.96338
-5209.44580
-6945.92676
-8682.40918
-34.20201
-68.40402
-102.60603 "
-136.80804
-171.01006
-205.21207
-239.41406
-273.61612
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-513.03021
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0.50831
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0.27303
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0.15596
0.11311
0.07546
0.05095
0.03242
0.01888
0.01095
0.00776
0.00552
0.00314
0.00304
0.00199
0.00096
0.00161
0.00595
0.06812
0.22038
0.16963
0.34941
0.35778
0.31240
0.21257
0.25030
0.21184
0.19760
0.16270
0.12625
0.09872
0.05979
0.03998
0.02457
0.01808
0.01076
0.0077D
0.00579
0.00376
0.00257
0.00284
0.00067
0.00180
0.04448
0.25351
0.37065
0.34719
0.28853
0.16991
0.21772
0.17343
0.16451
0.15628
0.13258
0.11563
0.08652
0.07382
0.04321
329.20
347.50
353.60
323.10
341.40
341.40
323.10
347.50
353.60
386.50
353.60
360.00
340.00
380.00
380.00
380.00
400.00
207.30
202.70
202.70
202.70
202.70
213.40
256.00
296.70
286.50
323.10
347.50
347.50
310.90
353.60
350.20
347.50
347.50
345.90
371.90
365.80
408.40
380.00
360.00
360.00
360.00
360.00
207.30
202.70
202.70
202.70
213.40
268.20
317.00
347.50
353.60
347.50
310.90
359.70
335.30
359.70
359.70
347.50
365.80
359.70
353.60
402.30
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
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PERIOD
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PERIOD
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P^tlOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
-------
8660.25391
12990.38090
17320.50780
25980.76170
34641.01560
43301.26560
76.60445
153.20888
229.81332
306.41779
383.02225
459.62668
536.23108
612.83557
689.44000
766.04443
957.55554
1149.06665
1340.57764
1532.08899
1723.59998
1915.11108
2298.13330
3064.17798
3830.22192
5745.33252
7660.44434
11490.66500
15320.88870
22981 .33200
30641.77730
38302.22270
64.27876
128.55754
192.83629
257.11508
321 .39377
385.67261
449.95132
514.23016
578.50885
642.78766
803.48456
964.18146
1124.87830
1285.57520
1446.27197
1606.96912
1928.36292
2571.15039
3213.93799
4820.90674
6427.87549
9641.81348
12855.75200
19283.62700
25711.50390
32139.38090
50.00000
100.00001
150.00002
200.00002
250.00002
-5000.00049
-7500.00098
-10000.00100
-15000.00200
-20000.00200
-25000.00200
-64.27876
-128.55754
-192.83629
-257.11508
-321 .39377
-385.67261
-449.95132
-514.23016
-578.50885
-642.78766
-803.48462
-964.18146
-1124.87830
-1285.57520 '
-1446.27209
-1606.96924
-1928.36292
-2571.15039
-3213.93823
-4820.90674
-6427.87598
-9641.81348
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-19283.62700
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-383.02225
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0.01719
0.15052
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0.2S667
0.25865
0.24048
0.18747
0.17190
0.14936
0.14194
0.12229
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0.07056
0.05354
0.03138
0.02315
0.01464
0.01039
0.00621
0.00434
0.00338
0.00213
0.00317
0.00141
0.00202
0.05483
0.16639
0.16340
0.17782
0.18673
0.14656
0.17364
0.14824
0.10904
0.10885
0.09206
0.09084
0.07773
0.05626
0.04241
0.02668
0.01965
0.01385
0.00843
0.00466
0.00322
0.00273
0.00146
0.00415
0.00138
0.00336
0.06463
396.20
380.00
380.00
360.00
360.00
360.00
207.30
202.70
202.70
202.70
243.80
298.70
323.10
353.60
353.60
353.60
353.60
359.70
341.40
353.60
353.60
341.40
359.70
359.70
359.70
408.40
408.40
380.00
360.00
360.00
360.00
360.00
207.30
202.70
202.70
202.70
268.20
304.80
310.90
323.10
329.20
323.10
347.50
359.70
329.20
359.70
353.60
359.70
408.40
420.60
371.90
392.00
390.10
340.00
380.00
400.00
400.00
380.00
207.30
202.70
202.70
213.40
268.20
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
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PERIOD
PERIOD
PERIOD
PER tOD
PERIOD
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
AIL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
8760
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-------
300.00003 -519.61517
350.00003 -606.21777
400.00003 -692.82031
450.00003 -779.42291
500.00003 -866.02S39
625.00006 -1082.53174
750.00006 -1299.03821
875.00006 -1515.54443
1000.00006 -1732.05090
1125.00012 -1948.55713
1250.00012 -2165.06348
1500.00012 -2598.07617
2000.00012 -3464.10156
2500.00024 -4330.12695
3750.00024 -6495.19043
5000.00049 -8660.25391
7500.00049 -12990.38090
10000.00100 -17320.50780
15000.00100 -25980.76170
20000.00200 -34641.01560 '
25000.00200 -43301.26560
34.20202 -93.96926
68.40405 -187.93851
102.60606 -281.90778
136.80809 -375.87701
171.01012 -469.84631
205.21213 -563.81555
239.41414 -657.78479
273.61621 -751.75409
307.81821 -845.72333
342.02023 -939.69257
427.52527 -1174.61572
513.03033 -1409.53894
598.53546 -1644.46204
684.04047 -1879.38513
769.54547 -2114.30835
855.05054 -2349.23145
1026.06079 -2819.07788
1368.08081 -3758.77026
1710.10107 -4698.46289
2565.15161 -7047.69434
3420.20190 -9396.92578
5130.30273 -14095.38870
6840.40430 -18793.85350
10260.60550 -28190.77730
13680.80860 -37587.70310
17101.01170 -46984.62890
17.36483 -98.48077
34.72966 -196.96155
52.09449 -295.44235
69.45933 -393.92307
86.82413 -492.40384
104.18897 -590.88470
121.55380 -689.36542
138.91862 -787.84613
156.28346 -886.32697
173.64827 -984.80774
217.06036 -1231.00964
260.47244 -1477.21143
303.88449 -1723.41370
347.29657 -1969.61548
390.70868 -2215.81738
434.12073 -2462.01929
0.16885 298.70 PERIOD ALL
0.18694 310.90 PERIOD ALL
0.19630 323.10 PERIOD ALL
0.16994 323.10 PERIOD ALL
0.17670 329.20 PERIOD ALL
0.08516 298.70 PERIOD ALL
0.12500 341.40 PERIOD ALL
0.10542 341.40 PERIOD ALL
0.09865 359.70 PERIOD ALL
0.08375 365.80 PERIOD ALL
0.07867 371.90 PERIOD ALL
0.06686 408.40 PERIOD ALL
0.04844 420.60 PERIOD ALL
0.03532 408.40 PERIOD ALL
0.02278 408.40 PERIOD ALL
0.01717 396.20 PERIOD ALL
0.01213 340.00 PERIOD ALL
0.00807 360.00 PERIOD ALL
0.00401 420.00 PERIOD ALL
0.00295 400.00 PERIOD ALL
0.00232 400.00 PERIOD ALL
0.00103 207.30 PERIOD ALL
0.00361 202.70 PERIOD ALL
0.00197 202.70 PERIOD ALL
0.00218 207.30 PERIOD ALL
0.06860 268.20 PERIOD ALL
0.15540 292.60 PERIOD ALL
0.18843 304.80 PERIOD ALL
0.17923 304.80 PERIOD ALL
0.08465 286.50 PERIOD ALL
0.08048 286.50 PERIOD ALL
0.11051 304.80 PERIOD ALL
0.10331 310.90 PERIOD ALL
0.07953 304.80 PERIOD ALL
0.09491 335.30 PERIOD ALL
0.08882 359.70 PERIOD ALL
0.08416 378.00 PERIOD ALL
0.06637 396.20 PERIOD ALL
0.04711 402.30 PERIOD ALL
0.03580 411.50 PERIOD ALL
0.02268 402.30 PERIOD ALL
0.01634 408.10 PERIOD ALL
0.01084 360.00 PERIOD ALL
0.00729 360.00 PERIOD ALL
0.00368 420.00 PERIOD ALL
0.00270 400.00 PERIOD ALL
0.00200 420.00 PERIOD ALL
0.00083 207.30 PERIOD ALL
0.00177 202.70 PERIOD ALL
0.00313 202.70 PERIOD ALL
0.00203 202.70 PERIOD ALL
0.04530 249.90 PERIOD ALL
0.17778 286.50 PERIOD ALL
0.10333 280.40 PERIOD ALL
0.08049 274.30 PERIOD ALL
0.10732 286.50 PERIOD ALL
0.09488 286.50 PERIOD ALL
0.10856 298.70 PERIOD ALL
0.10526 304.80 PERIOD ALL
0.09116 304.80 PERIOD ALL
0.07445 298.70 PERIOD ALL
0.07088 298.70 PERIOD ALL
0.09381 365.80 PERIOD ALL
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
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8760
8760
8760
8760
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8760
8760
8760
8760
8760
8760
8760
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8760
8760
8760
8760
8760
8760
8760
8760
8760 *'
8760
8760
8760
8760
8760
-------
520.94489
694.59320
868.24146
1302.36230
1736.48279
2604.72412
3472.96558
5209.44824
6945.93115
8682.41504
0.00002
0.00003
0.00005
0.00006
0.00008
0.00009
0.00011
0.00012
0.00014
0.00015
0.00019
0.00023
0.00026
0.00030
0.00034
0.00038
0.00045
0.00060
0.00075
0.00113
0.00151
0.00226
0.00302
0.00453
0.00604
0.00755
-17.36482
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-86.82410
-104.18893
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-520.94470
-694.59296
-868.24115
1302.36182
1736.48218
2604.72314
3472.96436
5209.44629
6945.92871
8682.41113
-34.20201
-2954.42285
-3939.23096
-4924.03809
-7386.05762
-9848.07715
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-1000.00000 -
-1250.00000
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-2250.00000
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-984.80774
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-1969.61548
-2215.81738
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-2954.42310
-3939.23096
-4924.03809
-7386.05762
-9846.07715
-14772.11520
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-29544.23050
-39392.30860
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-93.96926
0.07467
0.05239
0.03825
0.02312
0.01769
0.01124
0.00804
0.00419
0.00297
0.00231
0.00087
0.00104
0.00198
0.00281
0.01558
0.17205
0.18625
0.11796
0.04582
0.18976
0.17140
0.13440
0.11465
0.07858
0.07567
0.09419
0.07330
0.05339
0.04182
0.02512
0.01794
0.01092
0.00809
0.00457
0.00320
0.00235
0.00118
0.00059
0.00114
0.00154
0.00246
0.02774
0.17269
0.15942
0.06227
0.19837
0.19489
0.13243
0.12700
0.09338
0.11507
0.11750
0.09531
0.06324
0.04728
0.02927
0.01987
0.01281
0.00967
0.00600
0.00382
0.00271
0.00405
402.30
390.10
414.50
408.40
398.10
380.00
360.00
400.00
400.00
400.00
207.30
202.70
202.70
202.70
219.50
274.30
280.40
274.30
243.80
298.70
304.80
304.80
304.80
292.60
298.70
365.80
406.30
402.30
396.20
390.10
396.20
380.00
360.00
380.00
380.00
400.00
207.30
202.70
202.70
202.70
202.70
225.60
274.30
274.30
237.70
292.60
304.80
286.50
292.60
280.40
304.80
353.60
384.00
396.20
415.40
390.10
392.00
360.00
340.00
340.00
360.00
380.00
213.40
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
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PERIOD
PERIOD
PERIOD
ALL
ALL
ALL
ALL
ALL
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ALL
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ALL
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ALL
ALL
ALL
ALL
8760
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8760
-------
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-102.60605
-136.80806
-171.01009
-205.21210
-239.41411
-273.61615
-307.81815
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-513.03021
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-769.54535
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-657.78491
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-845.72333
-939.69263
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-1644.46204
-1879.38525
-2114.30835
-2349.23145
-2819.07788
-3758.77051
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-7047.69482
-9396.92578 '
-14095.38960
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-46984.62890
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-173.20508
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-346.41016
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0.01412
0.15044
0.12900
0.11789
0.10788
0.06898
0.11563
0.12673
0.09653
0.06549
0.04989
0.03163
0.02203
0.01495
0.01061
0.00595
0.00402
0.00304
0.00332
0.00077
0.00075
0.00098
0.00137
0.00190
0.00250
0.00312
0.00371
0.01135
0.01294
0.01012
0.01064
0.02554
0.02533
0.08815
0.09415
0.05987
0.04525
0.02898
0.01972
0.01264
0.00840
0.00571
0.00408
0.00289
0.00360
0.00091
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0.00148
0.00166
0.00198
0.00246
0.00300
0.00355
0.00410
0.00533
0.01016
202.70
202.70
202.70
202.70
202.70
219.50
249.90
219.50
280.40
280.40
280.40
280.40
262.10
298.70
353.60
371.90
402.30
397.20
384.00
384.00
340.00
340.00
360.00
380.00
380.00
213.40
202.70
202.70
202.70
202.70
202.70
202.70
202.70
202.70
219.50
219.50
213.40
213.40
231.60
231.60
292.60
359.70
396.20
414.50
396.20
392.60
360.00
380.00
360.00
360.00
380.00
213.40
202.70
202.70
202.70
202.70
202.70
202.70
202.70
202.70
202.70
202.70
213.40
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
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ALL
ALL
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8760
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8760
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8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760 >'
8760
8760
8760
8760
8760
-------
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0.04369
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0.01982
0.01346
213.40
213.40
213.40
213.40
371.90
378.00
396.20
396.20
378.00
349.00
360.00
360.00
380.00
360.00
213.40
201.20
207.30
207.30
202.70
202.70
202.70
202.70
207.30
207.30
207.30
207.30
207.30
213.40
213.40
256.00
323.10
359.70
384.00
378.00
378.00
360.00
380.00
400.00
400,00
380.00
213.40
213.40
213.40
207.30
213.40
213.40
213.40
213.40
213.40
213.40
225.60
274.30
329.20
310.90
286.50
256.00
243.80
365.80
372.50
378.00
402.30
360.00
360.00
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
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8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
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6760
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8760
8760
8760
8760
8760
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8760
8760
-------
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0.00828
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0.01582
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0.00620
0.00725
380.00
400.00
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213.40
213.40
213.40
213.40
213.40
213.40
213.40
219.50
219.50
213.40
353.60
353.60
341.40
335.30
353.60
304.80
243.80
298.70
359.70
365.80
402.30
380.00
400.00
380.00
400.00
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213.40
213.40
213.40
213.40
213.40
213.40
213.40
219.50
225.60
310.90
359.70
359.70
365.80
371.90
353.60
371.90
353.60
365.80
365.80
390.10
339.90
360.00
380.00
420.00
400.00
400.00
213.40
213.40
213.40
213.40
213.40
213.40
213.40
213.40
PERIOD
.PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIX
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
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0.00001
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0.00002
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0.00004
0.00005
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0.00012
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0.00024
0.00036
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17.36481
34.72963 '
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0.00612
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0.05717
0.08890
0.08513
0.07500
0.06389
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243.80
298.70
304.80
304.80
335.30
341.40
371.90
371.90
371.90
378.00
371.90
371.90
360.00
340.00
360.00
380.00
380.00
400.00
213.40
213.40
213.40
213.40
213.40
225.60
225.60
237.70
243.80
280.40
317.00
304.80
298.70
341.40
371.90
353.60
365.80
353.60
378.00
384.00
389.20
400.00
420.00
380.00
380.00
400.00
213.40
213.40
213.40
219.50
225.60
225.60
243.80
274.30
286.50
298.70
317.00
298.70
298.70
359.70
384.00
378.00
378.00
378.00
378.00
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
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ALL
ALL
ALL
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8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
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8760
8760
8760
8760
8760
8760
8760
8760
8760
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8760
8760
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149.99997
199.99997
249.99994
299.99991
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399.99991
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624.99988
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874.99988 '
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0.06826
0.12045
0.12632
0.11477
0.09956
0.09223
0.07538
0.05595
0.04624
0.02873
0.01943
0.01221
0.00850
0.00485
0.00361
0.00355
0.01046
0.00248
0.00261
0.00281
0.00154
0.00297
0.03484
0.14881
0.17976
0.16868
0.10859
0.15540
0.14294
0.12338
0.11137
0.09725
0.07671
0.05916
0.04344
0.02626
0.01903
0.01217
0.00736
0.00443
0.00316
0.00271
0.01127
0.00804
0.00507
0.00172
371.90
424.90
420.00
360.00
400.00
380.00
400.00
213.40
213.40
219.50
231.60
225.60
231.60
268.20
304.80
310.90
304.80
292.60
323.10
359.70
371.90
371.90
378.00
378.00
378.00
384.00
384.00
426.70
400.00
400.00
420.00
400.00
350.00
213.40
213.40
225.60
231.60
225.60
231.60
268.20
304.80
316.40
317.00
304.80
341.40
353.60
365.80
371.90
378.00
384.00
359.70
384.00
378.00
379.20
360.00
400.00
400.00
400.00
370.00
213.40
225.60
231.60
231.60
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PER'OD
PERIOD
PERIOD
PERIOD
PERIOD
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
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8760
8760
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8760
8760
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8760
8760
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8760
8760
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8760
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8760
8760
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8760
8760'
8760
8760
8760
8760
8760
-------
-321.39383
-385.67267
-449.95142
-514.23022
-578.50897
-642.78772
-803.48474
-964.18152
-1124.87854
-1285.57532
-1446.27222
-1606.96936
-1928.36328
-2571.15088
-3213.93872
-4820.90771
-6427.87695
-9641.81543
12855.75490
19283.63090
25711.50980
32139.38670
-50.00002
-100.00003
-150.00005
-200.00006
-250.00009
-300.00009
-350.00012
-400.00012
-450.00015
-500.00018
-625.00024
-750.00024
-875.00031
-1000.00037
-1125.00037
-1250.00049
-1500.00049
-2000.00073
-2500.00098
-3750.00122
-5000.00195
-7500.00244
10000.00390
15000.00490
20000.00780
25000.00780
-34.20204
-68.40408
-102.60610
-136.80815
-171.01018
-205.21220
-239.41423
-273.61633
-307.81833
-342.02036
-427.52545
-513.03052
-598.53571
-684.04065
-769.54584
383.02216
459.62665
536.23102
612.83551
689.43988
766.04431
957.55542
1149.06653
1340.57751
1532.08862
1723.59973
1915.11084
2298.13306
3064.17749
3830.22144
5745.33203
7660.44336
11490.66410
15320.88670
22981 .33010 '
30641.77340
38302.21880
86.60253
173.20506
259.80756
346.41013
433.01270
519.61517
606.21771
692.82025
779.42279
866.02533
1082.53162
1299.03784
1515.54431
1732.05066
1948.55701
2165.06323
2598.07593
3464.10132
4330.12646
6495.18994
8660.25293
12990.37990
17320.50590
25980.75960
34641.01170
43301.26170
93.96925
187.93851
281.90778
375.87698
469.84631
563.81555
657.78479
751.75403
845.72327
939.69257
1174.61572
1409.53894
1644.46191
1879.38513
2114.30811
0.00120
0.00337
0.04874
0.14860
0.16194
0.14121
0.13229
0.14348
0.11287
0.10092
0.08770
0.07507
0.06108
0.04295
0.03208
0.01919
0.01385
0.00845
0.00540
0.00332
0.00273
0.00214
0.01205
0.00821
0.00338
0.00212
0.00064
0.00928
0.01154
0.00983
0.09395
0.08651
0.03698
0.08146
0.07954
0.06947
0.05363
0.04944
0.04007
0.02813
0.02042
0.01240
0.00900
0.00582
0.00388
0.00258
0.00160
0.00142
0.01349
0.01019
0.00144
0.00074
0.00054
0.00642
0.01477
0.03610
0.02741
0.03747
0.05964
0.07052
0.05843
0.04815
0.03696
225.60
231.60
274.30
304.80
310.90
310.90
317.00
347.50
353.60
353.60
359.70
365.80
384.00
384.00
378.00
378.00
378.00
380.00
400.00
400.00
360.00
360.00
213.40
225.60
231.60
231.60
225.60
243.80
249.90
243.80
304.80
304.80
286.50
329.20
347.50
353.60
353.60
384.00
384.00
384.00
378.00
365.80
371.90
360.00
360.00
340.00
380.00
350.00
213.40
225.60
225.60
225.60
225.60
243.80
262.10
286.50
280.40
292.60
323.10
353.60
359.70
359.70
329.20
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PER 'CD
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL .
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
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8760
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8760
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8760
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8760
8760
8760
8760
8760
8760 '
8760
8760
8760
8760
8760
-------
-855.05090 2349.Z3145
-1026.06104 2819.07764
-1368.08130 3758.77026
-1710.10181 4698.46289
-2565.15283 7047.69385
-3420.20337 9396.92578
-5130.30518 14095.38770
-6840.40674 18793.85350
-10260.61040 28190.77540
-13680.81450 37587.70310
-17101.01760 46984.62890
-17.36484 98.48077
-34.72969 196.96155
-52.09453 295.44235
-69.45937 393.92307
-86.82422 492.40381
-104.18906 590.88470
-121.55391 689.36542
-138.91873 787.84613
-156.28360 886.32697 -
-173.64844 984.80768
-217.06055 1231.00964
-260.47269 1477.21143
-303.88474 1723.41345
-347.29691 1969.61523
-390.70898 2215.81738
-434.12109 2462.01929
520.94531 2954.42285
694.59375 3939.23071
868.24219 4924.03809
-1302.36353 7386.05713
-1736.48438 9848.07715
-2604.72656 14772.11430
-3472.96875 19696.15430
-5209.45264 29544.22850
-6945.93701 39392.30860
-8682.42186 49240.38670
-0.00003 100.00000
-0.00006 200.00000
-0.00009 300.00000
-0.00012 400.00000
-0.00015 500.00000
-0.00018 600.00000
-0.00021 700.00000
-0.00024 800.00000
0.00027 900.00000
-0.00030 1000.00000
-0.00038 1250.00000
-0.00045 1500.00000
-0.00053 1750.00000
-0.00060 2000.00000
-0.00068 2250-OOOuO
-0.00075 2500.00000
-0.00091 3000.00000
-0.00121 4000.00000
-0.00151 5000.00000
-0.00226 7500.00000
-0.00302 10000.00000
-0.00453 15000.00000
-0.00604 20000.00000
-0.00906 30000.00000
0.01208 40000.00000
-0.01510 50000.00000
0.03845 347.50 PERIOD ALL
0.03339 378.00 PERIOD ALL
0.02373 385.00 PERIOD ALL
0.01773 371.90 PERIOD ALL
0.01035 329.20 PERIOD ALL
0.00815 349.00 PERIOD ALL
0.00503 360.00 PERIOD ALL
0.00356 360.00 PERIOD ALL
0.00230 340.00 PERIOD ALL
0.00154 370.00 PERIOD ALL
0.00129 350.00 PERIOD ALL
0.01627 213.40 PERIOD ALL
0.01058 225.60 PERIOD ALL
0.00207 225.60 PERIOD ALL
0.00071 225.60 PERIOD ALL
0.00094 225.60 PERIOD ALL
0.00594 243.80 PERIOD ALL
0.01178 262.10 PERIOD ALL
0.03511 292.60 PERIOD ALL
0.04108 298.70 PERIOD ALL
0.03979 296.70 PERIOD ALL
0.07424 335.30 PERIOD ALL
0.08236 365.80 PERIOD ALL
0.06907 359.70 PERIOD ALL
0.06204 359.70 PERIOD ALL
0.05155 341.40 PERIOD ALL
0.04931 378.00 PERIOD ALL
0.04094 384.00 PERIOD ALL
0.03026 378.00 PERIOD ALL
0.02326 365.80 PERIOD ALL
0.01429 341.40 PERIOD ALL
0.01032 339.90 PERIOD ALL
0.00644 340.00 PERIOD ALL
0.00421 360.00 PERIOD ALL
0.00284 340.00 PERIOD ALL
0.00202 330.00 PERIOD ALL
0.00162 320.00 PERIOD ALL
0.02140 213.40 PERIOD ALL
0.01037 225.60 PERIOD ALL
0.00185 225.60 PERIOD ALL
0.00148 225.60 PERIOD ALL
0.00194 225.60 PERIOD ALL
0.00569 237.70 PERIOD ALL
0.01115 256.00 PERIOD ALL
0.03124 280.40 PERIOD ALL
0.06229 298.70 PERIOD ALL
0.04796 292.60 PERIOD ALL
0.12129 353.60 PERIOD ALL
0.07946 323.10 PERIOD ALL
0.08049 341.40 PERIOD ALL
O.OS599 317.00 PERIOD ALL
0.06285 359.70 PERIOD ALL
0.05486 359.70 PERIOD ALL
0.04487 378.00 PERIOD ALL
0.03086 383.40 PERIOD ALL
0.02441 359.70 PERIOD ALL
0.01426 371.90 PERIOD ALL
0.00997 380.10 PERIOD ALL
0.00619 360.00 PERIOD ALL
0.00480 340.00 PERIOD ALL
0.00235 380.00 PERIOD ALL
0.00196 350.00 PERIOD ALL
0.00153 350.00 PERIOD ALL
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760 '
8760
8760
8760
8760
8760
-------
B. Off-Site Fire Scenario
-------
CO STARTING
TITLEONE
TITLETUO
MOOELOPT
AVERTIME
POLLUT1D
TERRHGTS
ELEVUNIT
RUHORNOT
ERRORFIL
CO FINISHED
UTI Truck Accident Off-Site, ISCCMDEP -- OFFSITE
1 Point «ource; 26 receptors up to 50K* auay; Vapor.
GRORIS MOSTD RURAL CONC
1 3 24 PERIOD
Chemical
ELEV
METERS
RUN
OFFSITE.ERR
SO STARTING
LOCATION OFFSITE POINT -908. 79. 212.1
* Point Source OS MS TS VS OS
* Parameters:
SO SRCPARAM OFFSITE 1.0 38.0 997. 0.225 30.59
**SO SRCPARAK OFFSITE 1.0 38.0 997. 0.075 52.98
SO SRCGROUP
SO FINISHED
RE STARTING
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
ALL
17.36482
34.72963
52.09445
69.45927
86.82409
104.18890
121.55372
138.91853
156.28336
173.64818
217.06021
260.47226
303.88431
347.29636
390.70837
434.12042
520.94452
694.59271
868.24084
1302.36133
1736.48169
2604.72266
3472.96338
5209.44531
6945.92676
8682.40820
34.20201
68.40403
102.60604
136.80806
171.01007
205.21208
239.41409
273.61612
307.81812
342.02014
427.52518
513.03021
598.53522
98.48077
196.96155
295.44232
393.92310
492.40387
590.88464
689.36542
787.84619
886.32697
984.80774
1231.00964
1477.21167
1723.41357
1969.61548
2215.81738
-2462.01929
2954.42334
3939.23096
4924.03857
7386.05811
9848.07715
14772.11620
19696.15430
29544.23240
39392.30860
49240.38670
93.96926
187.93852
281.90778
375.87704
469.84631
563.81555
657.78485
751.75409
845.72339
939.69263
1174.61572
1409.53894
1644.46204
213.4
225.6
225.6
225.6
225.6
225.6
243.8
256.0
280.4
286.5
353.6
353.6
310.9
347.5
353.6
359.7
347.5
341.4
341.4
365.8
360.0
340.0
340.0
360.0
350.0
360.0
213.4
225.6
225.6
225.6
225.6
225.6
237.7
243.8
256.0
286.5
329.2
347.5
335.3
-------
RE OISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
684.04028
769.54529
855.05035
1026.06042
1368.08057
1710.10071
2565.15112
3420.20142
5130.30225
6840.40283
10260.60450
13680.80570
17101.00590
50.00000
100.00000
150.00000
200.00000
250.00000
300.00000
350.00000
400.00000
450.00000
500.00000
625.00000
750.00000
875.00000
1000.00000
1125.00000
1250.00000
1500.00000
2000.00000
2500.00000
3750.00000
5000.00000
7500.00000
10000.00000
15000.00000
20000.00000
25000.00000
64.27876
128.55753
192.83627
257.11505
321.39380
385.67255
449.95132
514.23010
578.50885
642.78760
803.48450
964.18140
1124.87830
1285.57520
1446.27209
1606.96899
1928.36279
2571.15039
3213.91799
4820.90674
6427.87598
9641.81348
12855.75200
19283.62700
1879.38525
2114.30835
2349.23145
2819.07788
3758.77051
4696.46289
7047.69482
9396.92578
14095.38960
18793.85160
28190.77930
37587.70310
46984.63280
86.60254
173.20508
259.80762
346.41016
433.01270
519.61523
606-.21777
692.82031
779.42285
866.02539
1082.53174
1299.03809
1515.54443
1732.05078
1948.55713
2165.06348
2598.07617
3464.10156
4330.12695
6495.19043
8660.25391
12990.38090
17320.50780
25980.76170
34641.01560
43301.26950
76.60445
153.20889
229.81334
306.41779
383.02222
459.62668
536.23114
612.83557
689.44000
766.04443
957.55554
1149.06665
1340.57776
1532.08887
1723.59998
1915.11108
2296.13330
3064.17773
3830.22217
5745.33350
7660.44434
11490.66700
15320.88870
22981.33400
347.5
353.6
359.7
362.4
329.2
359.7
369.7
385.9
340.0
340.0
360.0
380.0
390.0
213.4
219.5
225.6
225.6
225.6
225.6
225.6
231.6
243.8
262.1
225.6
347.5
359.7
353.6
353.6
329.2
323.1
361.2
366.7
378.0
396.2
320.0
360.0
380.0
370.0
400.0
213.4
213.4
225.6
225.6
225.6
225.6
225.6
225.6
225.6
243.8
280.4
353.6
361.5
353.6
353.6
353.6
335.3
353.9
353.0
378.0
396.4
376.0
380.0
360.0
-------
RE DISCCART
RE DISCCART
RE OISCCART
RE OISCCART
RE OISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE OISCCART
RE OISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE OISCCART
RE OISCCART
RE OISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE OISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE OISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE OISCCART
RE OISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
25711.50390
32139.37890
76.60445
153.20889
229.81334
306.41779
383.02222
459.62668
536.23114
612.83557
689.44000
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7660.44434
11490.66700
15320.88870
22981.33400
30641.77730
38302.22270
86.60254
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433.01270
519.61523
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1732.05078
1948.55725
2165.06348
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4330.12695
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34641.01560
43301.26950
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187.93852
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563.81555
657.78485
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30641.77730
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f₯ ^rFFFf
150.00000
199.99998
249.99998
300.00000
349.99997
399.99997
449.99997
499.99997
624.99994
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219.5
219.5
219.5
219.5
219.5
22S.6
219.5
219.5
323.1
353.6
353.6
335.3
347.5
347.5
341.4
335.3
373.1
396.2
360.0
380.0
380.0
420.0
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213.4
207.3
207.3
201.2
207.3
213.4
213.4
213.4
213.4
219.5
225.6
219.5
243.8
292.6
310.9
323.1
317.0
323.1
359.7
378.9
408.7
380.0
360.0
380.0
380.0
420.0
207.3
201.2
202.7
202.7
207.3
207.3
207.3
213.4
213.4
-------
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
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RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
939.69263
1174.61572
1409.53894
1644.46204
1879.38525
2114.30835
2349.23145
2819.07788
3758.77051
4698.46289
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2215.81738 .
2462.01929
2954.42334
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213.4
213.4
213.4
213.4
213.4
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231.6
231.6
310.9
384.0
384.0
370.3
360.0
380.0
400.0
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207.3
202.7
202.7
202.7
202.7
202.7
202.7
202.7
202.7
202.7
202.7
202.7
213.4
207.3
207.3
231.6
304.8
346.6
365. 8
384.0
371.9
320.0
360.0
380.0
380.0
400.0
207.3
202.7
202.7
202.7
202.7
202.7
202.7
202.7
202.7
202.7
243.8
341.4
323.1
341.4
304.8
292.6
310.9
359.7
402.3
347.5
-------
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
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RE DISCCART
RE DISCCART
RE DISCCART
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RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE- DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
10000.00000
15000.00000
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40000.00000
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98.48077
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202.7
202.7
202.7
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202.7
202.7
219.5
225.6
329.2
347.5
353.6
323.1
341.4
341.4
323.1
347.5
353.6
386.5
353.6
360.0
340.0
380.0
380.0
380.0
400.0
207.3
202.7
202.7
202.7
202.7
213.4
256.0
298.7
286.5
323.1
347.5
347.5
310.9
353.6
350.2
347.5
347.5
345.9
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365.8
408.4
380.0
360.0
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360.0
360.0
207.3
202.7
202.7
202.7
213.4
-------
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
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RE DISCCART
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RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
519.61523
606.21777
692.82031
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866.02539
1082.53174
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268.2
317.0
347.5
353.6
347.5
310.9
359.7
335.3
359.7
359.7
347.5
365.8
359.7
353.6
402.3
396.2
380.0
380.0
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207.3
202.7
202.7
202.7
243.8
298.7
323.1
353.6
353.6
353.6
353.6
359.7
341.4
353.6
353.6
341.4
359.7
359.7
359.7
408.4
408.4
380.0
360.0
360.0
360.0
360.0
207.3
202.7
202.7
202.7
268.2
304.8
310.9
323.1
329.2
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347.5
359.7
329.2
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353.6
359.7
-------
RE
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RE 01SCCART
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RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
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335.3
341.4
371.9
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213.4
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225.6
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213.4
213.4
213.4
219.5
-------
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
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RE DISCCART
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RE. DISCCART
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RE OISCCART
RE DISCCART
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RE DISCCART
-469.84631
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13680.80370
17101 .00390
49.99999
99.99998
149.99997
199.99997
249.99995
fffw «^T^^T%
349.99994
TOO ******!
JTV »Tm^»
449.99994
499.99991
624.99988
749.99988
874.99988
999.99982
1124.99988
1249.99976
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1999.99963
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225.6
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274.3
286.5
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424.9
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380.0
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213.4
213.4
219.5
231.6
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231.6
268.2
304.8
310.9
304.8
292.6
323.1
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378.0
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400.0
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225.6
231.6
268.2
304.8
316.4
317.0
304.8
341.4
353.6
365.8
371.9
-------
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
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RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE OISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
-1915.11133
-2290.13354
-3064.17798
-3830.22266
-5745.33398
-7660. U531
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25711.50000
32139.37500
76.60443
153.20886
229.81331
306.41772
383.02216
459.62662
536.23102
612.83545
OoV»^i jiToO
766.04431
957.55542
1149.06653
1340.57764
1532.08862
1723.59973
1915.11084
2298.13306
3064.17725
3830.22168
5745.33252
7660.44336
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38302.21880
86.60253
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259.80759
346.41013
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606.21771
692.82025
779.42279
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1082.53162
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1948.55688
2165.06323
2598.07593
3464.10132
4330.12646
6495.18994
8660.25293
12990.37990
17320.50590
25980.75980
34641.01170
43301.26560
378.0
384.0
359.7
384.0
378.0
379.2
360.0
400.0
400.0
400.0
370.0
213.4
225.6
231.6
231.6
225.6
231.6
274.3
304.8
310.9
310.9
317.0
347.5
353.6
353.6
359.7
365.8
384.0
384.0
378.0
378.0
378.0
380.0
400.0
400.0
360.0
360.0
213.4
225.6
231.6
231.6
225.6
243.8
249.9
243.8
304.8
304.8
286.5
329.2
347.5
353.6
353.6
384.0
384.0
384.0
378.0
365.8
371.9
360.0
360.0
340.0
380.0
350.0
-------
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
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563.81555
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845.72327
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1409.53882
1644.46191
1879.38513
2114.30811
2349.23145
2819.07764
3758.77026
4698.46289
7047.69385
9396.92578
14095.38770
18793.85160
28190.77540
37587.70310
46984.62890
96.48077
196.96155
295.44232
393.92310
492.40384
590.88464
689.36542
787.84619
886.32697
984.80768
1231.00964
1477.21155
1723.41345
1969.61536
2215.81738
2462.01929
2954.42310
3939.23071
4924.03857
7386.05762
9848.07715
14772.11520
19696.15430
29544.23050
39392.30860
49240.38670
100.00000
200.00000
300.00000
400.00000
500.00000
600.00000
700.00000
800.00000
900.00000
1000.00000
1250.00000
213.4
225.6
225.6
225.6
225.6
243.8
262.1
286.5
280.4
292.6
323.1
353.6
359.7
359.7
329.2
347.5
378.0
385.0
371.9
329.2
349.0
360.0
360.0
340.0
370.0
350.0
213.4
225.6
225.6
225.6
225.6
243.8
262.1
292.6
298.7
298.7
335.3
365.8
359.7
359.7
341.4
378.0
384.0
378.0
365.8
341.4
339.9
340.0
360.0
340.0
330.0
320.0
213.4
225.6
225.6
225.6
225.6
237.7
256.0
280.4
298.7
292.6
353.6
-------
0.00045
0.00053
0.00060
0.00068
0.00075
0.00091
0.00121
0.00151
0.00226
0.00302
0.00453
0.00604
0.00906
0.01208
0.01510
1500
1750
2000
2250
2500
3000
4000
5000
7500
10000
15000
20000
30000
40000
50000
.00000
.00000
.00000
.00000
.00000
.00000
.00000
.00000
.00000
.00000
.00000
.00000
.00000
.00000
.00000
323.1
341.4
317.0
359.7
359.7
378.0
383.4
359.7
371.9
380,1
360.0
340.0
380.0
350.0
350.0
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE DISCCART
RE FINISHED
ME STARTING
ME INPUTFIL DEPBIN.aet
ME ANEMHGHT 30.0 METERS
ME SUtFDATA 94823 1993
ME UAIRDATA 94823 1993
ME PROFFILE TEMPS ISC_TEMP.STK
ME PROFFILE WINDS ISC_WINO.STK
* DAYRANGE 1/3
ME FINISHED
TG STARTING
INPUTFIL wtilOOk.out
LOCATION 538.4 4497.8 ton
TG FINISHED
OU STARTING
RECTABLE ALLAVE FIRST-SECOND
* DAYTABLE ALLAVE
MAXTABLE ALLAVE 50
** MAXIFILE 3 ALL 30.0 MAXIALL.FIL 25
** MAXIFILE 24 ALL 10.0 MAXIALL.FIL 25
* POSTFILE 1 ALL 1NDIV POST2C.BIN 20
* POSTFILE PERIOD ALL PLOT PSTANALL.FIL 21
Note that the following two Input card* generate PLOTFILEs Kith the file
* unit dynamically allocated by the 1SCST2 program. When porting the aodel
** to another computer systea, the user nay need to specify the file units
** a* is done on the previoua four input cards.
PLOTFILE 3 ALL 2ND PLT03ALL.FIL
PLOTFILE 24 ALL 2ND PLT24ALL.FU
OU PLOTFILE 1 ALL FIRST OFFSITE.PL1
OU PLOTFILE 1 ALL FIRST OFFSITE.1
OU PLOTFILE 3 ALL FIRST OFFSITE.3
OU PLOTFILE 24 ALL FIRST OFFSITE.24
OU PLOTFILE PERIOD ALL OFFSITE.ANN
OU FINISHED
** Message SuMMry For ISC2 Model
SuiMary of Total Message*
A Total of
A Total of
A Total of
0 Fatal Error Messaged)
1 Warning Messaged)
0 Informational Message(s)
-------
FATAL ERROR MESSAGES
** HOME *»*
« WARNING MESSAGES «««
SO W320 17 PPARM : Source Parmeter May Be Out-of-Range for Parameter DS
SETUP Finishes Successfully
-------
ISCST2 (94227): WTI Truck Accident Off-Site, ISCOHDEP -
MODELING OPTIONS USED:
CONC RURAL ELEV GRDRIS NOSTD
OFFSITE
PLOT FILE OF HIGH 1ST HIGH 1-HR VALUES FOR SOURCE CROUP: ALL
FOR A TOTAL OF 936 RECEPTORS.
FORKAT: (3(1X,F13.5),1X,F8.2,3X,A5,2X.A8,2X,A4)
x Y CONC ZELEV AVE GRP HIVAL
17.36482
34.72963
52.09445
69.45927
86.82409
104.18890
121.55373
136.91852
156.28337
173.64818
217.06021
260.4722V
303.88428
347.29639
390.70837
434.12042
520.94452
694.59271
868.24084
1302.36133
1736.48169
2604.72241
3472.96313
5209.44531
6945.92627
8682.40820
34.20201
68.40403
102.60603
136.80806
171.01007
205.21207
239.41408
273.61615
307.81812
342.02011
427.52518
513.03021
598.53522
684.04022
769.54523
855.05035
1026.06042
1368.08057
1710.10071
2565.15112
3420.20142
5130.30176
6840.40283
10260.60450
13680.80570
17101.00590
50.00000
100.00000
98.48077
196.96155
295.44235
393.92307
492.40384
590.88470
689.36542
787.84613
886.32697
984.80774
1231.00964
1477.21167
1723.41370
1969.61548
2215.81738
2462.01929
2954.42310
3939.23096
4924.03809
7386.05762
9648.07715
14772.11520
19696.15430
29544.23050
39392.30860
49240.38670
93.96926
187.93851
281.90778
375.87701
469.84631
563.81555
657.78491
751.75409
845.72339
939.69263
1174.61572
1409.53894
1644.46204
1879.38525
2114.30835
2349.23145
2819.07788
3758.77051
4698.46289
7047.69482
9396.92578
14095.38960
18793.85350
28190.77930
37587.70310
46984.63670
86.60254
173.20508
0.26880
0.33598
0.36408
0.33730
0.34637
0.34860
0.57377
0.74484
1.46575
2.05302
- 12.61975
10.95565
3.79691
8.00698
7.59468
4.95435
4.70006
3.21313
2.67063
2.82567
1.94967
0.98299
0.74547
0.60941
0.40966
0.34829
0.26873
0.33691
0.37006
0.28694
0.28421
0.36934
0.51489
0.57323
0.72210
1.96807
7.70763
9.52555
6.95155
7.50002
7.13345
6.57642
5.47722
2.96731
2.47798
2.91211
2.52572
0.97345
0.76762
0.60601
0.50508
0.40785
0.28014
0.28716
213.40
225.60
225.60
225.60
225.60
225.60
243.80
256.00
280.40
286.50
353.60
353.60
310.90
347.50
353.60
359.70
347.50
341.40
341.40
365.80
360.00
340.00
340.00
360.00
350.00
360.00
213.40
225.60
225.60
225.60
225.60
225.60
237.70
243.80
256.00
286.50
329.20
347.50
335.30
347.50
353.60
359.70
362.40
329.20
359.70
369.70
385.90
340.00
340.00
360.00
380.00
390.00
213.40
219.50
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HK
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
-------
150. 00000
200.00000
250.00000
300.00000
350.00000
400.00000
450.00000
500.00000
625.00000
750.00000
875.00000
1000.00000
1125.00000
1250.00000
1500.00000
2000.00000
2500.00000
3750.00000
5000.00000
7500.00000
10000.00000
15000.00000
20000.00000
25000.00000
64.27876
128.55754
192.83627
257.11508
321 .39377
385.67258
449.95132
514.23016
578.50885
642.78766
803.48456
964.18140
1124.87830
1285.57520
1446.27197
1606.96912
1928.36292
2571.15039
3213.93799
4820.90625
6427.87549
9641.81250
12855.75200
19283.62700
25711.50390
32139.37890
76.60445
153.20888
229.81335
306.41779
383.02225
459.62671
536.23120
612.83557
689.44000
766.04443
957.55554
1149.06665
1340.57764
259.80762
346.41016
433.01273
519.61517
606.21777
692.82031
779.42291
866.02539
1082.53174
1299.03821
1515.54443
1732.05090
1948.55713
2165.06348
2598.07617
3464.10156
4330.12695
6495.19043
8660.25391
12990.38090 '
17320.50780
25980.76170
34641.01560
43301 .26560
76.60445
153.20888
229.81335
306.41779
383.02225
459.62671
536.23120
612.83557
689.44000
766.04443
957.55554
1149.06665
1340.57764
1532.08899
1723.59998
1915.11108
2298.13330
3064.17798
3830.22192
5745.33301
7660.44434
11490.66600
15320.88870
22981.33400
30641.77730
38302.22270
64.27876
128.55754
192.83629
257.11508
321.39377
385.67261
449.95132
514.23016
578.50885
642.78766
803.48456
964.18140
1124.87830
0.35662
0.32557
0.29595
0.29250
0.40863
0.52095
0.61621
0.69656
0.52869
7.05143
8.60613
7.51029
6.75558
4.36960
3.28977
3.88733
3.04323
2.02383
1.50030
0.63818
0.57857
0.39186
0.26915
0.22724
0.29348
0.25689
0.31493
0.34678
0.31477
0.29315
0.34602
0.36397
0.45102
0.66126
1.25427
8.61035
8.66311
6.78554
6.10540
4.98055
4.01522
3.70575
2.90410
1.98154
1.47763
0.85381
0.62720
0.69921
0.32790
0.25307
0.30847
0.22848
0.24067
0.30236
0.34634
0.34414
0.32472
0.28523
0.43696
0.35947
0.39340
5.49557
7.44629
225.60
225.60
225.60
225.60
225.60
231.60
243.80
262.10
225.60
347.50
359.70
353.60
353.60
329.20
323.10
361.20
366.70
378.00
396.20
320.00
360.00
380.00
370.00
400.00
213.40
213.40
225.60
225.60
225.60
225.60
225.60
225.60
225.60
243.80
280.40
353.60
361.50
353.60
353.60
353.60
335.30
353.90
353.00
378.00
398.40
376.00
380.00
360.00
420.00
420.00
213.40
207.30
213.40
219.50
219.50
219.50
219.50
219.50
225.60
219.50
219.50
323.10
353.60
1-HR
. 1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HS
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
-------
1532.08899
1723.59998
1915.11108
2298.13330
3064.17798
3830.22192
5745.33301
7660.44434
11490.66600
15320.88870
22981 .33400
30641 .77730
38302.22270
86.60254
173.20508
259.80762
346.41016
433.01273
519.61517
606.21777
692.82031
779.42291
866.02539
1082.53174
1299.03821
1515.54443
1732.05090
1948.55725
2165.06348
2598.07617
3464.10156
4330.12695
6495.19043
8660.25391
12990.38090
17320.50780
25980.76170
34641.01560
43301.26560
93.96926
187.93851
281.90778
375.87701
469.84631
563.81555
657.78491
751.75409
845.72333
939.69263
1174.61572
1409.53894
1644.46204
1879.38525
2114.30835
2349.23145
2819.07788
3758.77051
4698.46289
7047.69482
9396.92578
14095.38960
18793.85350
28190.77930
1285.57520
1446.27197
1606.96912
1928.36292
2571.15039
3213.93799
4820.90674
6427.87549
9641.81348
12855.75200
19283.62700
25711.50390
32139.38090
50.00000
99.99999
150.00000
199.99997
249.99997
300.00000
349.99994
399.99994
449.99994
499.99994
625.00000
750.00000
875.00000
1000.00000
1125.00000
1250.00000
1500.00000
2000.00000
2499.99976
3749.99976
4999.99902
7499.99902
9999.99902
14999.99900
19999.99800
24999.99800
34.20201
68.40403
102.60603
136.80806
171.01007
205.21207
239.41411
273.61615
307.81815
342.02011
427.52518
513.03021
596.53528
684.04022
769.54535
855.05035
1026.06042
1368.08057
1710.10071
2565.15112
3420.20142
5130.30176
6840,40283
10260.60450
6.75017
5.10144
5.28185
4.46971
3.21061
2.39247
1.90956
1.52773
0.80456
0.64297
0.42405
0.39759
0.30839
0.32474
0.25609
0.24736
0.21004
0.24833
0.33927
- 0.37314
0.38559
0.38621
0.41852
0.45109
0.50349
1.20829
1.68499
2.95695
3.68385
2.79491
2.46894
3.16175
2.47585
1.82327
1.13814
0.73721
0.50751
0.40480
0.32852
0.33624
0.28222
0.22933
0.26756
0.32014
0.32257
0.32209
0.38282
0.39198
0.41010
0.44700
0.44691
0.43843
0.41389
0.40746
0.59610
0.53807
1.90567
3.83804
2.51031
1.70149
1.00714
0.81427
0.61590
353.60
335.30
347.50
347.50
341.40
335.30
373.10
396.20
360.00
380.00
380.00
420.00
420.00
213.40
207.30
207.30
201.20
207.30
213.40
213.40
213.40
213.40
219.50
225.60
219.50
243.80
292.60
310.90
323.10
317.00
323.10
359.70
378.90
408.70
380.00
360.00
380.00
380.00
420.00
207.30
201.20
202.70
202.70
207.30
207.30
207.30
213.40
213.40
213.40
213.40
213.40
213.40
213.40
213.40
231.60
231.60
310.90
384.00
384.00
370.30
360.00
380.00
400.00
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-KR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-KR
1-HR
1-HR
1-HR
1-HR
1-HR
1-KR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-MR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
-------
37587.70310
46984.63670
98.48077
196.96155
295.44235
393.92307
492.40384
590.88470
689.36542
787.84613
886.32697
984.80774
1231.00964
1477.21167
1723.41370
1969.61548
2215.81738
2462.01929
2954.42310
3939.23096
4924.03809
7386.05762
9848.07715
14772.11520
19696.15430
29544.23050
39392.30860
49240.38670
100.00000
200.00000
300.00000
400.00000
500.00000
600.00000
700.00000
800.00000
900.00000
1000.00000
1250.00000
1500.00000
1750.00000
2000.00000
2250.00000
2500.00000
3000.00000
4000.00000
5000.00000
7500.00000
10000.00000
15000.00000
20000.00000
30000.00000
40000.00000
50000.00000
98.48077
196.96155
295.44235
393.92307
492.40384
590.88470
689.36542
787.84613
886.32697
13680.80570
17101.00780
17.36482
34.72964
52.09447
69.45930
86.82410
104.18893
121.55376
138.91856
156.28340
173.64821
217.06027
260.47235
303.88434
347.29648
390.70850
434.12051
520.94470
694.59296 '
868.24103
1302.36169
1736.48218
2604.72290
3472.96411
5209.44580
6945.92822
8682.41113
0.00001
0.00002
0.00002
0.00003
0.00004
0.00005
0.00005
0.00006
0.00007
0.00008
0.00009
0.00011
0.00013
0.00015
0.00017
0.00019
0.00023
0.00030
0.00038
0.00057
0.00075
0.00113
0.00151
0.00226
0.00302
0.00377
17.36482
-34.72964
-52.09446
-69.45927
-86.82410
-104.18891
-121.55373
-138.91853
-156.28339
0.51459
0.43678
0.35359
0.31369
0.26612
0.25329
0.29654
0.33247
0.36039
0.38045
0.39332
0.39995
0.39583
0.38275
0.42299
0.39281
0.37818
0.67194
1.50775
3.14562
3.31588
2.59716
1.71830
0.62321
0.73195
0.50496
0.36129
0.29837
0.37070
0.34405
0.30541
0.26293
0.22294
0.23606
0.25777
0.27584
0.29033
0.30148
0.62002
4.91194
2.94301
4.05619
1.53264
0.95428
1.49695
3.21661
4.47226
1.55106
1.87059
1.00112
0.75303
0.58147
0.46521
0.28991
0.38699
0.37283
0.34232
0.30411
0.26565
0.23660
0.26201
0.37834
0.43138
360.00
400.00
207.30
202.70
202.70
202.70
202.70
202.70
202.70
202.70
202.70
202.70
202.70
202.70
213.40
207.30
207.30
231.60
304.80
346.60
365.80
384.00
371.90
320.00
360.00
380.00
380.00
400.00
207.30
202.70
202.70
202.70
202.70
202.70
202.70
202.70
202.70
202.70
243.80
341.40
523.10
341.40
304.80
292.60
310.90
359.70
402.30
347.50
380.10
360.00
360.00
380.00
400.00
360.00
207.30
202.70
202.70
202.70
202.70
202.70
202.70
219.50
225.60
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
-HR
-HR
-HR
-HR
-HR
-HR
-HR
-HR
-HR
-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
-------
984.80774
1231.00964
1477.21167
1723.41370
1969.61548
2215.81738
2462.01929
2954.42310
3939.23096
4924.03809
7386.05762
9848.07715
14772.11520
19696.15430
29544.23050
39392.30860
49240.38670
93.96926
187.93851
281.90778
375.87701
469.84631
563.81555
657.78491
751.75409
845.72339
939.69263
1174.61584
1409.53894
1644.46216
1879.38525
2114.30835
2349.23145
2819.07788
3758.77051
4698.46338
7047.69482
9396.92676
14095.38960
18793.85550
28190.77930
37587.70700
46984.63670
86.60254
173.20508
259.80762
346.41016
433.01273
519.61517
606.21777
692.82031
779.42291
866.02539
1082.53174
1299.03821
1515.54443
1732.05090
1948.55713
2165.06348
2598.07617
3464.10156
4330.12695
6495.19043
-173.64819
-217.06023
-260.47232
-303.88431
-347.29642
-390.70840
-434.12045
-520.94458
-694.59277
-868.24091
-1302.36145
-1736.48181
-2604.72290
-3472.96338
-5209.44580
-6945.92676
-8682.40918
-34.20201
-68.40402
-102.60603 '
-136.80804
-171.01006
-205.21207
-239.41406
-273.61612
-307.81812
-342.02008
-427.52515
-513.03021
-596.53522
-684.04016
-769.54523
-855.05023
-1026.06030
-1368.08032
-1710.10059 .
-2565.15088
-3420.20093
-5130.30127
-6840.40234
-10260.60350
-13680.80470
-17101.00590
-50.00000
-100.00001
-150.00002
-200.00002
-250.00003
-300.00003
-350.00003
-400.00003
-450.00003
-500.00006
-625.00006
-750.00006
-875.00006
-1000.00012
-1125.00012
-1250.00012
-1500.00012
-2000.00024
-2500.00024
-3750.00049
4.76881
6.27329
6.16611
2.94307
4.09769
3.76287
2.30627
3.32791
2.86217
3.90679
1.72526
1.47350
0.76150
0.90514
0.58147
0.42380
0.35992
0.40190
0.39868
0.37433
0.33824
0.29924
0.32718
0.56942
1.97247
1.05365
4.18020
6.32271
5.63219
2.16176
5.05036
4.39445
3.88288
3.34770
2.54836
2.59361
1.64010
1.56278
0.89712
0.60835
0.49872
0.41280
0.35222
0.41493
0.42042
0.39936
0.36209
0.34550
0.52975
3.67296
8.20457
8.61100
7.31127
2.32594
6.84067
4.02515
5.52586
5.03001
3.93320
4.15538
3.02563
2.29373
1.99081
329.20
347.50
353.60
323.10
341.40
341.40
323.10
347.50
353.60
386.50
353.60
360.00
340.00
380.00
380.00
380.00
400.00
207.30
202.70
202.70
202.70
202.70
213.40
256.00
298.70
286.50
323.10
347.50
347.50
310.90
353.60
350.20
347.50
347.50
345.90
371.90
365.80
408.40
380.00
360.00
360.00
360.00
360.00
207.30
202.70
202.70
202.70
213.40
268.20
317.00
347.50
353.60
347.50
310.90
359.70
335.30
359.70
359.70
347.50
365.80
359.70
353.60
402.30
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-NR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
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ALL
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ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
-------
8660.25391
12990.38090
17320.50780
25980.76170
34641.01560
43301.26560
76.60445
153.20888
229.81332
306.41779
383.02225
459.62668
536.23108
612.83557
689.44000
766.04443
957.55554
1149.06665
1340.57764
1532.08899
1723.59998
1915.11108
2298.13330
3064.17798
3830.22192
5745.33252
7660.44434
11490.66500
15320.88870
22981.33200
30641.77730
38302.22270
64.27876
128.55754
192.83629
257.11508
321.39377
385.67261
449.95132
514.23016
578.50885
642.78766
803.48456
964.18146
1124.87830
1285.57520
1446.27197
1606.96912
1928.36292
2571.15039
3213.93799
4820.90674
6427.87549
9641.81348
12855.75200
19283.62700
25711.50390
32139.38090
50.00000
100.00001
150.00002
200.00002
250.00002
-5000.00049
-7500.00098
-10000.00100
-15000.00200
-20000.00200
-25000.00200
-64.27876
-128.55754
-192.83629
-257.11508
-321 .39377
-385.67261
-449.95132
-514.23016
-578.50885
-642.78766
-803.48462
-964.18146
-1124.87830
-1285.57520 --
-1446.27209
-1606.96924
-1928.36292
-2571.15039
-3213.93823
-4820.90674
-6427.87598
-9641.81348
-12855.75290
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-32139.38090
-76.60445
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-3064.17798
-3830.22192
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-7660.44434
-11490.66600
-15320.88870
-22981.33400
-30641.77730
-38302.22270
-86.60254
-173.20508
-259.80762
-346.41016
-433.01273
1.42519
0.83092
0.60556
0.33625
0.24605
0.19235
0.42561
0.43716
0.41605
0.37383
0.49189
1.79875
4.64597
9.38023
8.82994
8.33411
7.29032
7.00924
4.69202
5.23867
4.77284
3.16810
3.33343
2.56669
2.06776
2.03090
1.48196
0.83548
0.52174
0.37065
0.30105
0.24722
0.43359
0.44835
0.42392
0.37336
0.57794
2.43991
3.02561
4.53357
5.22348
4.11713
6.00279
5.92884
2.83832
4.79220
3.50451
3.65866
5.16026
3.89373
2.27250
1.72043
1.24257
0.51671
0.53830
0.35506
0.25348
0.18634
0.43858
0.45374
0.42329
0.40890
0.84558
396.20
380.00
380.00
360.00
360.00
360.00
207.30
202.70
202.70
202.70
243.80
296.70
323.10
353.60
353.60
353.60
353.60
359.70
341.40
353.60
353.60
341.40
359.70
359.70
359.70
408.40
408.40
380.00
360.00
360.00
360.00
360.00
207.30
202.70
202.70
202.70
268.20
304.80
310.90
323.10
329.20
323.10
347.50
359.70
329.20
359.70
353.60
359.70
408.40
420.60
371.90
392.00
390.10
340.00
380.00
400.00
400.00
380.00
207.30
202.70
202.70
213.40
268.20
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
ALL
ALL
ALL
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1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
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1ST
1ST
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1ST
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1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
-------
300.00003
350.00003
400.00003
450.00003
500.00003
625.00006
750.00006
875.00006
1000.00006
1125.00012
1250.00012
1500.00012
2000.00012
2500.00024
3750.00024
5000.00049
7500.00049
10000.00100
15000.00100
20000.00200
25000.00200
34.20202
68.40405
102.60606
136.80809
171.01012
205.21213
239.41414
273.61621
307.81821
342.02023
427.52527
513.03033
598.53546
684.04047
769.54547
855. 05054
1026.06079
1368.08081
1710.10107
2565.15161
3420.20190
5130.30273
6840.40430
10260.60550
13680.80860
17101.01170
17.36483
34.72966
52.09449
69.45933
86.82413
104.18897
121.55380
138.91862
156.28346
173.64827
217.06036
260.47244
303.88449
347.29657
390.70868
434.12073
-519.61517
-606.21777
-692.82031
779.42^-,
-866.02539
-1082.53174
-1299.03821
-1515.54443
-1732.05090
-1948.55713
-2165.06348
-2598.07617
-3464.10156
-4330.12695
-6495.19043
-8660.25391
-12990.38090
-17320.50780
-25980.76170
-34641.01560 '
-43301 .26560
-93.96926
-187.93851
-281.90778
-375.87701
-469.84631
-563.81555
-657.78479
-751.75409
-845.72333
-939.69257
-1174.61572
-1409.53894
-1644.46204
-1879.38513
-2114.30835
-2349.23145
-2819.07788
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-393.92307
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-787.84613
-886.32697
-964.80774
-1231.00964
-1477.21143
-1723.41370
-1969.61548
-2215.81738
-2462.01929
1.88338
3.12102
4.47822
3.44037
3.99676
1.15026
3.60656
3.27483
4.40008
4.42819
4.40581
4.58552
3.37671
2.77139
1.79060
1.28702
0.51393
0.47360
0.43799
0.29078
0.24275
0.44039
0.45331
0.41498
0.42574
1.00140
1.42446
1.89658
1.81961
0.56008
0.54460
1.26652
1 .47459
1.08083
2.65939
4.18575
4.83353
4.71148
3.58915
3.00845
1.845U
1.42660
0.57411
0.42987
0.44024
0.29190
0.24473
0.43894
0.44718
0.41836
0.42576
0.95598
0.80975
0.59230
0.55650
0.60195
0.58568
1.00867
1.21439
1.12251
0.81909
0.7r251
4.30240
298.70
310.90
323.10
323.10
329.20
298.70
341.40
341.40
359.70
365.80
371.90
408.40
420.60
408.40
408.40
396.20
340.00
360.00
420.00
400.00
400.00
207.30
202.70
202.70
207.30
268.20
292.60
304.80
304.80
286.50
286.50
304.80
310.90
304.80
335.30
359.70
378.00
396.20
402.30
411.50
402.30
408.10
360.00
360.00
420.00
400.00
420.00
207.30
202.70
202.70
202.70
249.90
286.50
280.40
274.30
286.50
286.50
296.70
304.80
304.80
296.70
296.70
365.80
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
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1-HR
1-HR
1-KR
1-HR
1-HR
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1-HR
1-HR
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1-HR
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1-HR
1-HR
1-HR
1-HR
1-HR
1-H«
1-HR
1-HR
1-HR
1-HR
1-HR
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ALL
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ALL
ALL
ALL
ALL
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ALL
ALL
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1ST
1ST
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1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
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1ST
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1ST
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1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
-------
520.94489
694.59320
868.24146
1302.36230
1736.48279
2604.72412
3472.96558
5209.44824
6945.93115
8682.41504
0.00002
0.00003
0.00005
0.00006
0.00008
0.00009
0.00011
0.00012
0.00014
0.00015
0.00019
0.00023
0.00026
0.00030
0.00034
0.00038
0.00045
0.00060
0.00075
0.00113
0.00151
0.00226
0.00302
0.00453
0.00604
0.00755
-17.36482
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-390.70853
-434.12054
-520.94470
694.59296
-868.24115
-1302.36182
-1736.48218
-2604.72314
-3472.96436
-5209.44629
6945.92871
-8682.41113
-34.20201
-2954.42285
-3939.23096
-4924.03809
-7386.05762
-9848.07715
-14772.11520
-19696.15430
-29544.23050
-39392.30860
-49240.38670
-100.00000
-200.00000
-300.00000
-400.00000
-500.00000
-600.00000
-700.00000
-800.00000
-900.00000
-1000.00000 '
-1250.00000
-1500.00000
-1750.00000
-2000.00000
-2250.00000
2500.00000
-3000.00000
-4000.00000
-5000.00000
-7500.00000
-10000.00000
-15000.00000
-20000.00000
-30000.00000
-40000.00000
-50000.00000
-98.48077
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-9848.07715
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19696.15430
-29544.23050
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-49240.38670
-93.96926
4.96976
3.15816
3.16511
1.97938
1.33800
0.72961
0.64221
0.42567
0.30186
0.24893
0.43421
0.43548
0.41014
0.41080
0.39143
0.65616
0.59292
0.57072
0.44840
1.15070
1.38798
1 .27150
1.04510
0.56915
0.67898
3.83824
5.07416
4.70300
3.72727
2.34163
1.65182
1.00042
0.64804
0.56711
0.44071
0.33106
0.42628
0.41834
0.38521
0.37631
0.31955
0.37408
0.57250
0.51230
0.25795
0.89245
1 .47436
0.68115
0.63180
0.55796
1.62834
6.01295
6.88369
4.99100
5.23266
3.62055
2.56038
1 .33527
0.80047
0.51337
0.43789
0.41517
0.42530
402.30
390.10
414.50
408.40
398.10
380.00
360.00
400.00
400.00
400.00
207.30
202.70
202.70
202.70
219.50
274.30
280.40
274.30
243.80
298.70
304.80
304.80
304.80
292.60
298.70
365.80
406.30
402.30
396.20
390.10
396.20
380.00
360.00
380.00
380.00
400.00
207.30
202.70
202.70
202.70
202.70
225.60
274.30
274.30
237.70
292.60
304.80
286.50
292.60
280.40
304.80
353.60
384.00
396.20
415.40
390.10
392.00
360.00
340.00
340.00
360.00
380.00
213.40
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
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1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-KR
1-HR
1-HR
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
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ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
-------
68.40403
-102.60605
-136.80806
-171.01009
-205.21210
-239.41411
-273.61615
-307.81815
-342.02014
-427.52521
-513.03021
-598.53528
-684.04034
-769.54535
-855.05042
-1026.06042
-1368.08069
-1710.10083
-2565.15112
-3420.20142
-5130.30176
-6840.40332
10260.60450
13680.80660
17101.00780
-50.00000
-100.00000
-150.00000
-200.00000
-250.00000
-300.00000
-350.00000
-400.00000
-450.00000
-500.00000
-625.00000
-750.00000
-875.00000
-1000.00000
-1125.00000
-1250.00000
-1500.00000
-2000.00000
-2500.00000
-3750.00000
-5000.00000
-7500.00000
10000.00000
15000.00000
20000.00000
25000.00000
-64.27876
-128.55753
-192.83627
-257.11505
-321.39377
-385.67258
-449.95129
-514.23010
-578.50873
-642.78766
-803.48456
-964.18134
-187.93851
-281.90778
-375.87701
-469.84631
-563.81555
-657.78491
-751.75409
-845.72333
-939.69263
-1174.61572
-1409.53894
-1644.46204
-1879.38525
-2114.30835
-2349.23145
-2819.07788
-3758.77051
-4698.46289
-7047.69482
-9396.92578
-14095.38960
-18793.85350
-28190.77930
-37587.70310
-46984.62890
-86.60254
-173.20508
-259.80762
-346.41016
-433.01273
-519.61517
-606.21777
-692.82031
-779.42291
-866.02539
-1082.53174
-1299.03821
-1515.54443
-1732.05090
-1948.55713
-2165.06348
-2598.07617
-3464.10156
-4330.12695
-6495.19043
-8660.25391
-12990.38090
-17320.50780
-25980.76170
-34641.01560
-43301.26560
-76.60445
-153.20888
-229.81335
-306.41779
-383.02228
-459.62671
-536.23120
-612.83557
-689.44000
-766.04449
-957.55560
-1149.06689
0.39598
0.34401
0.32278
0.25914
0.21915
0.24554
0.33595
0.21976
0.61132
0.70153
0.71219
0.60392
0.39741
1.32031
6.41596
9.63020
7.83263
6.07217
3.64463
' 2.56743
1.10097
0.80734
0.60040
0.46494
0.35528
0.41205
0.36889
0.28972
0.25468
0.19106
0.20399
0.14085
0.14063
0.16760
0.19979
0.30762
0.25293
0.47151
0.68794
0.68386
1.31733
8.69092
8.28013
6.06948
2.34506
2*29909
1.08108
0.92917
0.50187
0.36425
0.31747
0.39648
0.33797
0.24396
0.19603
0.18121
0.18109
0.11973
0.10332
0.14028
0.20883
0.21102
0.37988
202.70
202.70
202.70
202.70
202.70
219.50
249.90
219.50
280.40
280.40
280.40
280.40
262.10
298.70
353.60
371.90
402.30
397.20
384.00
384.00
340.00
340.00
360.00
380.00
380.00
213.40
202.70
202.70
202.70
202.70
202.70
202.70
202.70
202.70
219.50
219.50
213.40
213.40
231.60
231.60
292.60
359.70
396.20
414.50
396.20
392.60
360.00
380.00
360.00
360.00
380.00
213.40
202.70
202.70
202.70
202.70
202.70
202.70
202.70
202.70
202.70
202.70
213.40
1-HR
1-HR
i-m
1-HR
1-HR
1-HR
1-HR
1-H»
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
-HR
-MR
-HR
-HR
-HR
1-HR
1-HR
1-Hf
1-HR
1-HR
1-HR
1-HR
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
-------
-1124.87830
-1285.57520
-106.27165
-1606.96912
-1928.36279
-2571.15039
-3213.93774
-4820.90625
-6427.87500
-9641.81250
-12855.75100
-19283.62700
-25711.50200
-32139.37890
-76.60445
-153.20891
-229.81339
-306.41782
-383.02231
-459.62674
-536.23120
-612.83563
-689.44006
-766.04456
-957.55566
-1149.06689
-1340.57800
-1532.08911
-1723.60022
-1915.11121
-2298.13354
-3064.17847
-3830.22241
-5745.33350
-7660.44531
-11490.66700
-15320.89060
-22981 .33590
-30641.78130
-38302.22660
-86.60255
-173.20509
-259.80765
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-519.61530
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-4330.12744
-6495.19092
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-1532.08899
-1723.60010
-1915.111*1
-2298.13354
-3064.17822
-3830.22241
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-11490.66600
-15320.88960
-22981.33400
-30641.77930
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-25711.50000
-32139.37700
-49.99999
9y »^9998
-149.99997
-199.99994
-249.99994
-299.99991
-349.99991
.tQO OOCMA
JTT 7 V^UU
-449.99988
-499.99988
-624.99988
-749.99988
-874.99982
-999.99982
-1124.99976
-1249.99976
-1499.99976
-1999.99963
-2499.99951
-3749.99927
-4999.99854
-7499.99805
"9999. 99805
0.42113
0.33151
0.21041
0.20507
10.92368
6.12952
5.59288
3.39607
2.09512
0.95523
0.79460
0.50451
0.41394
0.28435
0.37915
0.30194
0.24334
0.24787
0.15675
- 0.15750
0.09817
0.08347
0.19057
0.21027
0.33033
0.22863
0.08610
0.12589
0.16390
0.33260
2.51318
4.78648
5.21950
2.99722
2.12744
1.21761
1.04816
0.70586
0.49958
0.35612
0.3607?
0.30806
0.30228
0.23202
0.19677
0.20100
0.11360
0.12402
0.20287
0.23053
0.29869
0.68257
5.80748
2.85526
1.02760
0.47127
0.61170
6.05994
5.13877
3.36742
2.81302
1.22/40
1.05474
213.40
213.40
213.40
213.40
371.90
378.00
396.20
396.20
378.00
349.00
360.00
360.00
380.00
360.00
213.40
201.20
207.30
207.30
202.70
202.70
202.70
202.70
207.30
207.30
207.30
207.30
207.30
213.40
213.40
256.00
323.10
359.70
384.00
378.00
378.00
360.00
380.00
400.00
400.00
380.00
213.40
213.40
213.40
207.30
213.40
213.40
213.40
213.40
213.40
213.40
225.60
274.30
329.20
310.90
286.50
256.00
243.80
365.80
372.50
378.00
402.30
360.00
380.00
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HK ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-H« ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
-HR ALL
-HR ALL
-MR ALL
-HR ALL
m. ALL
-HR ALL
-HR ALL
-HR ALL
-HR ALL
-HR ALL
1-HR ALL
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
-------
-25980.76370
-34641.01950
-43301.27340
-93.96926
-187.93851
-281.90778
-375.87701
-469.84631
-563.81561
-657.78491
-751.75409
-845.72339
-939.69263
-1174.61584
-1409.53894
-1644.46216
-1879.38525
-2114.30835
-2349.23145
-2819.07788
-3758.77051
-4698.46338
-7047.69482
-9396.92676
-14095.38960
-18793.85550
-28190.77930
-37587.70700
-46984.63670
-98.48077
-196.96155
-295.44235
-393.92307
-492.40384
-590.88470
-689.36542
-787.84613
-886.32697
-984.80774
-1231.00964
-1477.21167
-1723.41370
-1969.61548
-2215.81738
-2462.01929
-2954.42310
-3939.23096
-4924.03809
-7386.05762
-9848.07715
-14772.11520
-19696.15430
-29544.23050
-39392.30860
49240.38670
-100.00000
-200.00000
-300.00000
-400.00000
-500.00000
-600.00000
-700.00000
-800.00000
-14999.99710
-19999.99610
-24999.99410
-34.20201
-68.40401
-102.60602
-136.80803
-171.01004
-205.21204
-239.41403
-273.61609
-307.81805
-342.02008
-427.52509
-513.03009
-598.53516
-684.04016
-769.54517
-855.05017
-1026.06030 "
-1368.08020
-1710.10022
-2565.15039
-3420.20044
-5130.30029
-6840.40137
-10260.60160
-13680.80270
-17101.00390
-17.36481
-34.72963
-52.09444
-69.45926
-86.82407
-104.18888
-121.55370 .
-138.91849
-156.28334
-173.64813
-217.06018
-260.47223
-303.88422
-347.29630
-390.70831
-434.12033
-520.94446
-694.59253
-868.24066
-1302.36096
-1736.48120
-2604.72192
-3472.96240
-5209.44385
-6945.92480
-8682.40625
0.00000
0.00000
0.00000
0.00000
0.00001
0.00001
0.00001
0.00001
0.65071
0.50114
0.38787
0.34193
0.27758
0.30064
0.24210
0.23461
0.15763
0.08975
0.12425
0.16871
0.20034
23.57302
17.52369
10.52689
7.80677
11.15181
2.12495
0.85507
1.22027
4.52741
2.97962
3.34343
1.78258
1.37034
0.76916
0.58259
0.37647
0.32349
0.23298
0.26115
0.25437
0.18446
0.11117
0.08299
0.05333
0.17726
30.73858
39.06137
29.75858
24.42535
24.63006
18.22574
21.34521
11.89429
9.83305
7.30066
5.14318
2.16896
1.73067
1.37949
0.82775
0.60091
0.47073
0.30609
0.19980
0.18474
0.17931
0.15481
0.11702
0.04870
0.02153
380.00
400.00
360.00
213.40
213.40
213.40
213.40
213.40
213.40
213.40
219.50
219.50
213.40
353.60
353.60
341.40
335.30
353.60
304.80
243.80
298,70
359.70
365.80
402.30
380.00
400.00
380.00
400.00
360.00
213.40
213.40
213.40
213.40
213.40
213.40
213.40
219.50
225.60
310.90
359.70
359.70
365.80
371.90
353.60
371.90
353.60
365.80
365.80
390.10
339.90
360.00
380.00
420.00
400.00
400.00
213.40
213.40
213.40
213.40
213.40
213.40
213.40
213.40
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-M
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1 SS
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
-------
-900.00000
-1000.00000
-1250.00000
-1500.00000
-1750.00000
-2000.00000
-2250.00000
-2500.00000
-3000.00000
-4000.00000
-5000.00000
-7500.00000
-10000.00000
-15000.00000
-20000.00000
-30000.00000
-40000.00000
-50000.00000
-98.48077
-196.96155
-295.44235
-393.92307
-492.40384
-590.88470
-689.36542
-787.84613
-886.32697
-984.80774
-1231.00964
-1477.21167
-1723.41370
-1969.61548
-2215.81738
-2462.01929
-2954.42310
-3939.23096
-4924.03809
-7386.05762
-9848.07715
-14772.11520
-19696.15430
-29544.23050
-39392.30860
-49240.38670
-93.96926
-187.93851
-281.90778
-375.87701
-469.84631
-563.81561
-657.78491
-751.75409
-845.72339
-939.69263
-1174.61584
-1409.53894
-1644.46216
-1879.38525
-2114.30835
-2349.23145
-2819.07788
-3758.77051
-4698.46338
0.00001
0.00001
0.00001
0.00002
0.00002
0.00002
0.00003
0.00003
0.00004
0.00005
0.00006
0.00009
0.00012
0.00018
0.00024
0.00036
0.00048
0.00060
17.36481
34.72963 '
52.09445
69.45927
86.82407
104.18890
121.55371
138.91850
156.28336
173.64815
217.06020
260.47226
303.88428
347.29633
390.70834
434.12039
520.94452
694.59259
868.24072
1302.36133
1736.48157
2604.72241
3472.96Z89
5209.44482
6945.92578
8682.40820
34.20201
68.40401
102.60603
136.80803
171.01004
205.21204
239.41405
273.61609
307.81808
342.02008
427.52512
513.03021
598.53522
684.04016
769.54517
855.05017
1026.06030
1368.08020
1710.10034
0.61109
102.67791
11.27636
7.64968
18.61171
16.82258
26.26138
21.94983
16.40848
11.44995
7.90828
4.61813
2.85313
1.39252
1.22709
0.83216
0.58564
0.45712
0.29029
0.17685
0.17193
0.15816
0.11901
0.24290
0.09810
0.39948
1.11855
58.00135
23.04494
5.07005
2.77523
11.35851
17.64771
10.66911
11.35334
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4.12978
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1.31141
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243.80
298.70
304.80
304.80
335.30
341.40
371.90
371.90
371.90
378.00
371 .90
371.90
360.00
340.00
360.00
380.00
380.00
400.00
213.40
213.40
213.40
213.40
213.40
225.60
225.60
237.70
243.80
280.40
317.00
304.80
298.70
341.40
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365.80
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378.00
384.00
389.20
400.00
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213.40
213.40
213.40
219.50
225.60
225.60
243.80
274.30
286.50
298.70
317.00
298.70
298.70
359.70
384.00
378.00
378.00
378.00
378.00
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-Hk ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1 HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
-------
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49.99999
<"M"t /"M-^Wt^
ww m TT TTU
149.99997
199.99997
249.99994
299.99991
349.99991
399.99991
449.99991
499.99988
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- 20.21211
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426.70
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268.20
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341.40
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384.00
378.00
379.20
360.00
400.00
400.00
400.00
370.00
213.40
225.60
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1-HR
1-HR
1-Hft
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1*HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
-------
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213.40
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365.80
371.90
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340.00
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213.40
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225.60
225.60
243.80
262.10
286.50
280.40
292.60
323.10
353.60
359.70
359.70
329.20
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-KR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
: MR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1-HR ALL
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
-------
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100.00000
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7500.00000
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15000.00000
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30000.00000
40000.00000
50000.00000
6.00507
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S. 26502
5.05579
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0.96014
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0.32325
0.26755
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3.52680
- 4.63940
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11.53791
14.17996
10.98341
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5.64667
11.07024
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6.14093
2.86053
1.43443
0.99675
0.71643
0.68092
0.39902
0.29454
0.22617
0.26872
0.33562
0.35192
0.32039
0.38591
0.54373
0.88000
1.56852
4. 25866
3.02284
13.86225
6.68S59
4.83731
2.67474
8.25474
7.53438
8.70597
6.97202
3.94968
3.12449
2.49004
1.14165
0.50949
0.54475
0.30209
0.27912
347.50
378.00
385.00
371.90
329.20
349.00
360.00
360.00
340.00
370.00
350.00
213.40
225.60
225.60
225.60
225.60
243.80
262.10
292.60
298.70
298.70
335.30
365.80
359.70
359.70
341.40
378.00
384.00
378.00
365.80
341.40
339.90
340.00
360.00
340.00
330.00
320.00
213.40
225.60
225.60
225.60
225.60
237.70
256.00
280.40
298.70
292.60
353.60
323.10
341.40
317.00
359.70
359.70
378.00
383.40
359.70
371.90
380.10
360.00
340.00
380.00
350.00
350.00
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-IM
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
1-HR
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
1ST
-------
ISCST2 (94227): l/TI Truck Accident Off-Site. ISCOMDEP -- OFFSITE
MODELING OPTIONS USED:
CONC RURAL ELEV GRDRIS NOSTD
PLOT FILE OF PERIOD VALUES FOR SOURCE GROUP: ALL
FOR A TOTAL OF 936 RECEPTORS.
* FORMAT: (3(1X,F13.5),1X,F8.2,2X>A6,2X,A8,2X,I8)
* X
*
17.36482
34.72963
52.09445
69.45927
86.82409
104.18890
121.55373
138.91852
156.28337
173.64818
217.06021
260.47229
303.88428
347.29639
390.70837
434.12042
520.94452
694.59271
868.24084
1302.36133
1736.48169
2604.72241
3472.96313
5209.44531
6945.92627
8682.40820
34.20201
68.40403
102.60603
136.80806
171.01007
205.21207
239.41408
273.61615
307.81812
342.02011
427.52518
513.03021
598.53522
684.04022
769.54523
855.05035
1026.06042
1368.08057
1710.10071
2565.15112
3420.20142
5130.30176
6840.40283
10260.60450
13680.80570
17101.00590
50.00000
100.00000
Y
98.48077
196.96155
295.44235
393.92307
492.40384
590.88470
689.36542
787.84613
886.32697
984.80774
1231.00964
1477.21167
1723.41370
1969.61548
2215.81738
2462.01929
2954.42310
3939.23096
4924.03809
7386.05762
9848.07715
14772.11520
19696.15430
29544.23050
39392.30860
49240.38670
93.96926
187.93851
281.90778
375.87701
469.84631
563.81555
657.78491
751.75409
845.72339
939.69263
1174.61572
1409.53894
1644.46204
1879.38525
2114.30835
2349.23145
2819.07788
3758.77051
4698.46289
7047.69482
9396.92578
14095.38960
18793.85350
28190.77930
37587.70310
46964.63670
86.60254
173.20508
CONC
0.00119
0.00207
0.00195
0.00187
0.00193
0.00210
0.00500
0.00827
0.01379
0.01560
" 0.06360
0.04269
0.01242
0.02092
0.02022
0.01824
0.01368
0.01053
0.00938
0.00856
0.00615
0.00361
0.00269
0.00187
0.00134
0.00109
0.00121
0.00210
0.00198
0.00187
0.00185
0.00197
0.00359
0.00514
0.00874
0.01711
0.04696
0.05825
0.03797
0.03427
0.02760
0.02720
0.02144
0.00999
0.01111
0.00855
0.00779
0.00419
0.00318
0.00231
0.00178
0.00144
0.00123
0.00160
ZELEV
213.40
225.60
225.60
225.60
225.60
225.60
243.80
256.00
280.40
286.50
353.60
353.60
310.90
347.50
353.60
359.70
347.50
341.40
341.40
365.80
360.00
340.00
340.00
360.00
350.00
360.00
213.40
225.60
225.60
225.60
225.60
225.60
237.70
243.80
256.00
286.50
329.20
347.50
335.30
347.50
353.60
359.70
362.40
329.20
359.70
369.70
385.90
340.00
340.00
360.00
380.00
390.00
213.40
219.50
AVE
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERICD
GRP
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
HUM HRS
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
-------
150.00000
200.00000
250.00000
300.00000
350.00000
400.00000
450.00000
500.00000
625.00000
750.00000
875.00000
1000.00000
1125.00000
1250.00000
1500.00000
2000.00000
2500.00000
3750.00000
5000.00000
7500.00000
10000.00000
15000.00000
20000.00000
25000.00000
64.27876
128.55754
192.83627
257.11508
321 .39377
385.67258
449.95132
514.23016
578.50885
642.78766
803.48456
964.18140
1124.87830
1285.57520
1446.27197
1606.96912
1928.36292
2571.15039
3213.93799
4820.90625
6427.87549
9641.81250
12855.75200
19283.62700
25711.50390
32139.37890
76.60445
153.20888
229.81335
306.41779
383.02225
459.62671
536.23120
612.83557
689.44000
766.04443
957.55554
1149.06665
1340.57764
259.80762
346.41016
433.01273
519.61517
606.21777
692.82031
779.42291
866.02539
1082.53174
1299.03821
1515.54443
1732.05090
1948.55713
2165.06348
2598.07617
3464.10156
4330.12695
6495.19043
8660.25391
12990.38090 -
17320.50780
25980.76170
34641.01560
43301.26560
76.60445
153.20888
229.81335
306.41779
383.02225
459.62671
536.23120
612.83557
689.44000
766.04443
957.55554
1149.06665 .
1340.57764
1532.08899
1723.59998
1915.11108
2298.13330
3064.17798
3830.22192
5745.33301
7660.44434
11490.66600
15320.88870
22981.33400
30641.77730
38302.22270
64.27876
128.55754
192.83629
257.11508
321.39377
385.67261
449.95132
514.23016
578.50885
642.78766
803.48456
964.18140
1124.87830
0.00201
0.00191
0.00187
0.00192
0.00214
0.00303
0.00530
0.00950
0.00374
0.06222
0.06612
0.05434
0.04729
0.03102
0.02198
0.02231
0.01692
0.01208
0.00847
0.00436
0.00361
0.00240
0.00181
0.00145
0.00125
0.00124
0.00207
0.00201
0.00198
0.00205
0.00218
0.00235
0.00257
0.00529
0.01397
0.06933
0.07158
0.05866
0.05599
0.05104
0.03614
0.03260
0.02655
0.01971
0.01550
0.00936
0.00650
0.00386
0.00278
0.00214
0.00127
0.00098
0.00127
0.00166
0.00170
0.00179
0.00190
0.00201
0.00263
0.00230
0.00271
0.03282
0.05449
225.60
225.60
225.60
225.60
225.60
231.60
243.80
262.10
225.60
347.50
359.70
353.60
353.60
329.20
323.10
361.20
366.70
378.00
396.20
320.00
360.00
380.00
370.00
400.00
213.40
213.40
225.60
225.60
225.60
225.60
225.60
225.60
225.60
243.80
280.40
353.60
361.50
353.60
353.60
353.60
335.30
353.90
353.00
378.00
398.40
376.00
380.00
360.00
420.00
420.00
213.40
207.30
213.40
219.50
219.50
219.50
219.50
219.50
225.60
219.50
219.50
323.10
353.60
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL .
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
-------
1532.08899
1723.59998
1915.11108
2298.13330
3064.17798
3830.22192
5745.33301
7660.44434
11490.66600
15320.88870
22981.33400
30641.77730
38302.22270
86.60254
173.20508
259.80762
346.41016
433.01273
519.61517
606.21777
692.82031
779.42291
866.02539
1082.53174
1299.03821
1515.54443
1732.05090
1948.55725
2165.06348
2598.07617
3464.10156
4330.12695
6495.19043
8660.25391
12990.38090
17320.50780
25980.76170
34641.01560
43301 .26560
93.96926
187.93851
281.90778
375.87701
469.84631
563.81555
657.78491
751.75409
845.72333
939.69263
1174.61572
1409.53894
1644.46204
1879.38525
2114.30835
2349.23145
2819.07788
3758.77051
4698.46289
7047.69482
9396.92578
14095.38960
18793.85350
28190.77730
1285.57520
1446.27197
1606.96912
1928.36292
2571.15039
3213.93799
4820.90674
6427.87549
9641.81348
12855.75200
19283.62700
25711.50390
32139.38090
50.00000
99.99999
150.00000
199.99997
249.99997
300.00000
349.99994 '
399.99994
449.99994
499.99994
625.00000
750.00000
875.00000
1000.00000
1125.00000
1250.00000
1500.00000
2000.00000
2499.99976
3749.99976
4999.99902
7499.99902
9999.99902
14999.99900
19999.99800
24999.99800
34.20201
68.40403
102.60603
136.80806
171.01007
205.21207
239.41411
273.61615
307.81815
342.02011
427.52518
513.03021
596.53528
684.04022
769.54535
855.05035
1026.06042
1368.08057
1710.10071
2565.15112
3420.20142
5130.30176
6840.40283
10260.60450
0.05026
0.03801
0.04494
0.04183
0.03345
0.02669
0.02484
0.01910
0.01182
0.00949
0.00593
0.00405
0.00297
0.00129
0.00102
0.00104
0.00087
0.00118
0.00158
0.00169
0.00181
0.00193
0.00249
0.00336
0.00315
0.00632
0.01629
0.02254
0.02680
0.02348
0.02227
0.02923
0.02324
0.01981
0.01295
0.00905
0.00619
0.00438
0.00329
0.00100
0.00082
0.00092
0.00100
0.00129
0.00140
0.00152
0.00200
0.00212
0.00225
0.00256
0.00285
0.00313
0.00338
0.00360
0.00557
0.00576
0.01818
0.03402
0.02356
0.01780
0.01099
0.00904
0.00575
353.60
335.30
347.50
347.50
341.40
335.30
373.10
396.20
360.00
380.00
380.00
420.00
420.00
213.40
207.30
207.30
201.20
207.30
213.40
213.40
213.40
213.40
219.50
225.60
219.50
243.80
292.60
310.90
323.10
317.00
323.10
359.70
378.90
408.70
380.00
360.00
380.00
380.00
420.00
207.30
201.20
202.70
202.70
207.30
207.30
207.30
213.40
213.40
213.40
213.40
213.40
213.40
213.40
213.40
231.60
231.60
310.90
384.00
384.00
370.30
360.00
380.00
400.00
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL .
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760*'
8760
8760
8760
8760
8760
-------
37587.70310
46984.63670
98.48077
196.96155
295.44235
393.92307
492.40384
590.88470
689.36542
787.84613
886.32697
984.80774
1231.00964
1477.21167
1723.41370
1969.61548
2215.81738
2462.01929
2954.42310
3939.23096
4924.03809
7386.05762
9848.07715
14772.11520
19696.15430
29544.23050
39392.30860
49240.38670
100.00000
200.00000
300.00000
400.00000
500.00000
600.00000
700.00000
800.00000
900.00000
1000.00000
1250.00000
1500.00000
1750.00000
2000.00000
2250.00000
2500.00000
3000.00000
4000.00000
5000.00000
7500.00000
10000.00000
15000.00000
20000.00000
30000.00000
40000.00000
50000.00000
98.48077
196.96155
295.44235
393.92307
492.40384
590.88470
689.36542
787.84613
886.32697
13680.80570
17101.00780
17.36482
34.72964
52.09447
69.45930
86.82410
104.18893
121.55376
138.91856
156.28340
173.64821
217.06027
260.47235
303.88434
347.29648
390.70850
434.12051
520.94470
694.59296 '
868.24103
1302.36169
1736.48218
2604.72290
3472.96411
5209.44580
6945.92822
8662.41113
0.00001
0.00002
0.00002
0.00003
0.00004
0.00005
0.00005
0.00006
0.00007
0.00008
0.00009
0.00011
0.00013
0.00015
0.00017
0.00019
0.00023
0.00030
0.00038
0.00057
0.00075
0.00113
0.00151
0.00226
0.00302
0.00377
-17.36482
-34.72964
-52.09446
-69.45927
-86.82410
-104.18891
-121.55373
-138.91853
-156.28339
0.00394
0.00324
0.00102
0.00090
0.00097
0.00106
0.00117
0.00129
0.00142
0.00155
0.00167
0.00180
0.00211
0.00239
0.00345
0.00320
0.00340
0.00609
0.02047
0.03276
0.03220
0.02586
0.01941
0.01019
0.00895
0.00615
0.00448
0.00350
0.00103
0.00092
0.00101
0.00111
0.00124
0.00137
0.00151
0.00165
0.00179
0.00194
0.00774
0.05510
0.03593
0.04748
0.02438
0.01977
0.02616
0.04243
0.04706
0.02397
0.02280
0.01462
0.01137
0.00786
0.00584
0.00437
0.00104
0.00094
0.00103
0.00115
0.00128
0.00142
0.00156
0.00292
0.00380
360.00
400.00
207.30
202.70
202.70
202.70
202.70
202.70
202.70
202.70
202.70
202.70
202.70
202.70
213.40
207.30
207.30
231.60
304.80
346.60
365.80
384.00
371.90
320.00
360.00
380.00
380.00
400.00
207.30
202.70
202.70
202.70
202.70
202.70
202.70
202.70
202.70
202.70
243.80
341.40
323.10
341.40
304.80
292.60
310.90
359.70
402.30
347.50
380.10
360.00
360.00
380.00
400.00
360.00
207.30
202.70
202.70
202.70
202.70
202.70
202.70
219.50
225.60
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
-------
984.80774
1231.00964
1477.21167
1723.41370
1969.61543
2215.81738
2462.01929
2954.42310
3939.23096
4924.03809
7386.05762
9848.07715
14772.11520
19696.15430
29544.23050
39392.30860
49240.38670
93.96926
187.93851
281 .90778
375.87701
469.84631
563.81555
657.78491
751.75409
845.72339
939.69263
1174.61584
1409.53894
1644.46216
1879.38525
2114.30835
2349.23145
2819.07788
3758.77051
4698.46338
7047.69482
9396.92676
14095.38960
18793.85550
28190.77930
37587.70700
46964.63670
86.60254
173.20508
259.80762
346.41016
433.01273
519.61517
606.21777
692.82031
779.42291
866.02539
1082.53174
1299.03821
1515.54443
1732.05090
1948.55713
2165.06348
2598.07617
3464.10156
4330.12695
6495.19043
-173.64819
-217.06023
-260.47232
-303.88431
-347.29642
-390.70840
-434.12045
-520.94458
-694.59277
-868.24091
-1302.36145
-1736.48181
-2604.72290
-3472.96338
-5209.44580
-6945.92676
-8682.40918
-34.20201
-68.40402
-102.60603 '
-136.80804
-171.01006
-205.21207
-239.41406
-273.61612
-307.81812
-342.02008
-427.52515
-513.03021
-598.53522
-684.04016
-769.54523
-855.05023
-1026.06030
-1368.08032
-1710.10059
-2565.15088
-3420.20093
-5130.30127
-6840.40234
-10260.60350
-13680.80470
-17101.00590
-50.00000
-100.00001
-150.00002
-200.00002
-250.00003
-300.00003
-350.00003
400.00003
-450.00003
-500.00006
-625.00006
-750.00006
-875.00006
-1000.00012
-1125.00012
-1250.00012
-1500.00012
-2000.00024
-2500.00024
-3750.00049
0.04641
0.06475
0.06638
0.03500
0.04653
0.04435
0.03190
0.04333
0.03981
0.04436
0.02554
0.02136
0.01372
0.01286
0.00842
0.00618
0.00492
0.00104
0.00095
0.00105
0.00115
0.00128
0.00200
0.00905
0.02126
0.01533
0.03866
0.05768
0.05280
0.02572
0.05061
0.04555
0.04289
0.03547
0.03100
0.03265
0.02283
0.02178
0.01389
0.00965
0.00653
0.00488
0.00387
0.00104
0.00095
0.00104
0.00113
0.00176
0,00964
0.03294
0.06026
0.06335
0.05492
0.02247
0.05446
0.03277
0.04736
0.04368
0.03224
0.03797
0.02757
0.02329
0.02125
329.20
347.50
353.60
323.10
341.40
341.40
323.10
347.50
353.60
386.50
353. iO
360.00
340.00
380.00
380.00
380.00
400.00
207.30
202.70
202.70
202.70
202.70
213.40
256.00
296.70
286.50
323.10
347.50
347.50
310.90
353.60
350.20
347.50
347.50
345.90
371.90
365.80
408.40
380.00
360.00
360.00
360.00
360.00
207.30
202.70
202.70
202.70
213.40
268.20
317.00
347.50
353.60
347.50
310.90
359.70
335.30
359.70
359.70
347.50
365.80
359.70
353.60
402.30
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
-------
8660.25391
12990.38090
17320.50780
25980.76170
34641.01560
43301.26560
76.60U5
153.20888
229.81332
306.41779
383.02225
459.62668
536.23108
612.83557
689.44000
766.04443
957.55554
1149.06665
1340.57764
1532.08899
1723.59998
1915.11108
2298.13330
3064.17798
3830.22192
5745.33252
7660.44434
11490.66500
15320.88870
22981.33200
30641.77730
38302.22270
64.27876
128.55754
192.83629
257.11508
321.39377
385.67261
449.95132
514.23016
578.50885
642.78766
803.48456
964.18146
1124.87830
1285.57520
1446.27197
1606.96912
1928.36292
2571.15039
3213.93799
4820.90674
6427.87549
9641.81348
12855.75200
19283.62700
25711.50390
32139.38090
50.00000
100.00001
150.00002
200.00002
250.00002
-5000.00049
-7500.00096
-10000.00100
-15000.00200
-20000.00200
-25000.00200
-64.27876
-128.55754
-192.83629
-257.11508
-321.39377
-385.67261
-449.95132
-514.23016
-578.50885
-642.78766
-803.48462
-964.18146
-1124.87830
-1285.57520
-1446.27209
-1606.96924
-1928.36292
-2571.15039
-3213.93823
-4820.90674
-6427.87598
-9641.81348
-12855.75290
-19283.62700
-25711.50590
-32139.38090
-76.60445
-153.20888
-229.81332
-306.41779
-383.02225
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-536.23108
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-766.04443
-957.55554
-1149.06665
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-1532.08899
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-3064.17798
-3830.22192
-5745.33301
-7660.44434
-11490.66600
-15320.88870
-22961.33400
-30641.77730
-38302.22270
-86.60254
-173.20508
-259.80762
-346.41016
-433.01273
0.01653
0.01040
0.00813
0.00492
0.00368
0.00292
0.00104
0.00095
0.00102
0.00110
0.00496
0.01780
0.03371
0.06255
0.05933
0.05308
0.04604
0.04724
0.03173
- 0.03579
0.03246
0.02528
0.02883
0.02149
0.01828
0.01620
0.01258
0.00768
0.00517
0.00367
0.00262
0.00209
0.00103
0.00093
0.00099
0.00106
0.00792
0.01921
0.02076
0.02798
0.03000
0.02427
0.03828
0.03784
0.01963
0.03018
0.02462
0.02448
0.03379
0.02699
0.01680
0.01339
0.01004
0.00526
0.00505
0.00343
0.00254
0.00187
0.00102
0.00091
0.00097
0.00145
0.00742
396.20
380.00
380.00
360.00
360.00
360.00
207.30
202.70
202.70
202.70
243.80
298.70
323.10
353.60
353.60
353.60
353.60
359.70
341.40
353.60
353.60
341.40
359.70
359.70
359.70
408.40
408.40
380.00
360.00
360.00
360.00
360.00
207.30
202.70
202.70
202.70
268.20
304.80
310.90
323.10
329.20
323.10
347.50
359.70
329.20
359.70
353.60
359.70
408.40
420.60
371.90
392.00
390.10
340.00
380.00
400.00
400.00
380.00
207.30
202.70
202.70
213.40
268.20
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
876Q
8760
8760
8760
8760
-------
300
350
400
450
500
625
750
875
1000
1125
1250
1500
2000
2500
3750
5000
7500
10000
15000
20000
25000
34
68
102
136
171
205
239
273
307
.00003
.00003
.00003
.00003
.00003
.00006
.00006
.00006
.00006
.00012
.00012
.00012
.00012
.00024
.00024
.00049
.00049
.00100
.00100
.00200
.00200
.20202
.40405
.60606
.80809
.01012
.21213
.4U14
.61621
.81821
342.02023
427
513
598
684
769
855
1026
1368
1710
2565
3420
5130
6840
10260
13680
17101
17
34
52
69
86
104
121
138
156
173
217
260
303
347
390
434
.52527
.03033
.53546
.04047
.54547
.05054
.06079
.08081
.10107
.15161
.20190
.30273
.40430
.60550
.80860
.01170
.36483
.72966
.09449
.45933
.82413
.18897
.55380
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.28346
.64827
.06036
.47244
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.29657
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.01560 -
.26560
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298
310
323
323
329
298
341
341
.70
.90
.10
.10
.20
.70
.40
.40
359.70
365
371
408
420
408
408
396
340
360
420
400
400
207
202
202
207
268
292
304
304
286
286
304
310
304
335
359
378
396
402
411
402
408
360
360
420
400
420
207
202
202
202
249
286
280
274
286
286
298
.80
.90
.40
.60
.40
.40
.20
.00
.00
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.00
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.30
.70
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.30
.20
.60
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.50
.50
.80
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.80
.30
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.00
.20
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.50
.30
.10
.00
.00
.00
.00
.00
.30
.70
.70
.70
.90
.50
.40
.30
.50
.50
.70
304.80
304
298
296
365
.80
.70
.70
.80
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PER I a
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760^
8760
8760
8760
8760
8760
-------
520.94489
694.59320
868.24146
1302.36230
1736.48279
2604.72412
3472.96558
5209.44824
6945.93115
8682.41504
0.00002
0.00003
0.00005
0.00006
0.00008
0.00009
0.00011
0.00012
0.00014
0.00015
0.00019
0.00023
0.00026
0.00030
0.00034
0.00038
0.00045
0.00060
0.00075
0.00113
0.00151
0.00226
0.00302
0.00453
0.00604
0.00755
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0.02731
0.01930
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0.01294
0.00970
0.00592
0.00431
0.00331
0.00248
0.00209
0.00097
0.00083
0.00085
0.00082
0.00123
0.00511
0.00528
0.00444
0.00201
0.00789
0.00820
0.00809
0.00760
0.00543
0.00623
0.02398
0.03236
0.02645
0.02152
0.01482
0.01208
0.00701
0.00480
0.00347
0.00259
0.00217
0.00095
0.00080
0.00080
0.00074
0.00063
0.00113
0.00425
0.00389
0.00145
0.00586
0.00807
0.00453
0.00599
0.00449
0.00851
0.02468
0.03526
0.03135
0.02653
0.01653
0.01200
0.00632
0.00407
0.00282
0.00230
0.00199
0.00122
402.30
390.10
414.50
408.40
396.10
380.00
360.00
400.00
400.00
400.00
207.30
202.70
202.70
202.70
219.50
274.30
280.40
274.30
243.80
298.70
304.80
304.80
304.80
292.60
298.70
365.80
406.30
402.30
396.20
390.10
396.20
380.00
360.00
380.00
380.00
400.00
207.30
202.70
202.70
202.70
202.70
225.60
274.30
274.30
237.70
292.60
304.60
286.50
292.60
280.40
304.80
353.60
384.00
396.20
415.40
390.10
392.00
360.00
340.00
340.90
360.00
380.00
213.40
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
-------
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10260.60450
13680.80660
17101.00780
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-14095.38960
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306.41779
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0.00077
0.00075
0.00067
0.00055
0.00048
0.00076
0.00216
0.00069
0.00404
0.00400
0.00441
0.00486
0.00377
0.00901
0.03169
0.03623
0.03386
0.02467
0.01501
0.01020
0.00451
0.00327
0.00250
0.00200
0.00165
0.00120
0.00074
0.00071
0.00061
0.00049
0.00043
0.00039
0.00036
0.00036
0.00062
0.00074
0.00082
0.00106
0.00186
0.00196
0.00749
0.02988
0.03053
0.02433
0.01181
0.00864
0.00425
0.00350
0.00197
0.00153
0.00131
0.00119
0.00072
0.00068
0.00058
0.00046
0.00039
0.00035
0.00033
0.00033
0.00037
0.00048
0.00075
202.70
202.70
202.70
202.70
202.70
219.50
249.90
219.50
280.40
280.40
280.40
280.40
262.10
298.70
353.60
371.90
402.30
397.20
, 384.00
384.00
340.00
340.00
360.00
380.00
380.00
213.40
202.70
202.70
202.70
202.70
202.70
202.70
202.70
202.70
219.50
219.50
213.40
213.40
231.60
231.60
292.60
359.70
396.20
414.50
396.20
392.60
360.00
380.00
360.00
360.00
380.00
213.40
202.70
202.70
202.70
202.70
202.70
202.70
202.70
202.70
202.70
202.70
213.40
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PCS I CO
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
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ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALI
ALL
ALL
ALL
ALL
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
-------
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^^r B^^^n^D
-149.99997
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-249.99994
-299.99991
-349.99991
-399.99988
-449.99988
-499.99988
624.99988
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-1999.99963
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-3749.99927
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-7499.99805
-9999.99805
0.00081
0.00076
0.00068
0.00064
0.03071
0.02088
0.01728
0.01068
0.00654
0.00353
0.00305
0.00193
0.00165
0.00118
0.00118
0.00065
0.00078
0.00068
0.00044
0.00037
0.00032
0.00030
0.00039
0.00045
0.00051
0.00039
0.00028
0.00033
0.00037
0.00156
0.00789
0.01669
0.01971
0.01305
0.01018
0.00561
0.00490
0.00320
0.00244
0.00186
0.00117
0.00108
0.00101
0.00068
0.00073
0.00059
0.00051
0.00047
0.00053
0.00059
0.00068
0.00280
0.01623
0.00812
0.00400
0.00178
0.00155
0.03177
0.02766
0.02001
0.01754
0.00870
0.00688
213.40
213.40
213.40
213.40
371.90
378.00
396.20
396.20
378.00
349.00
360.00
360.00
380.00
360.00
213.40
201.20
207.30
207.30
202.70
202.70
202.70
202.70
207.30
207.30
207.30
207.30
207.30
213.40
213.40
256.00
323.10
359.70
384.00
378.00
378.00
360.00
380.00
400.00
400.00
380.00
213.40
213.40
213.40
207.30
213.40
213.40
213.40
213.40
213.40
213.40
225.60
274.30
329.20
310.90
286.50
256.00
243.80
365.80
372.50
378.00
402.30
360.00
380.00
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PER ID
PERIOD
PERIOD
PERIOD
PERIOD
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
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ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
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ALL
ALL
ALL
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ALL
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ALL
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ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
8760
8760
8760
8760
8760
8760
8760
8760
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8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
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8760
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8760
8760
8760
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8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
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8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760 *'
8760
8760
8760
8760
8760
-------
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0.00000
0.00000
0.00000
0.00000
0.00001
0.00001
0.00001
0.00001
0.00450
0.00340
0.00240
0.00116
0.00108
0.00100
0.00093
0.00081
0.00063
0.00053
0.00068
0.00077
0.00053
0.07633
0.05945
0.04463
0.03991
0.06316
0.01553
0.00269
0.01064
0.02829
0.01835
0.01661
0.00960
0.00748
0.00456
0.00326
0.00240
0.00116
0.00108
0.00100
0.00095
0.00089
0.00075
0.00058
0.00072
0.00124
0.06814
0.16513
0.1746^
0.14016
0.12010
0.10686
0.12781
0.07013
0.06004
0.04532
0.03536
0.01428
0.01262
0.01046
0.00747
0.00533
0.00420
0.00115
0.00107
0.00101
0.00095
0.00090
0.00082
O.OOU68
0.00044
380.00
400.00
360.00
213.40
213.40
213.40
213.40
213.40
213.40
213.40
219.50
219.50
213.40
353.60
353.60
341.40
335.30
353.60
304.80
243.80
298.70
359.70
365.80
402.30
380.00
400.00
380.00
400.00
360.00
213.40
213.40
213.40
213.40
213.40
213.40
213.40
219.50
225.60
310.90
359.70
359.70
365.80
371.90
353.60
371.90
353.60
365.80
365.80
390.10
339.90
360.00
380.00
420.00
400.00
400.00
213.40
213.40
213.40
213.40
213.40
213.40
213.40
213.40
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
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PERIOD
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PERIOD
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PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PER I0t)
PERIOD
PERIOD
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
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0.00941
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0.00100
0.00093
0.00084
0.00204
0.00170
0.00729
0.01254
0.04935
0.05729
0.01524
0.00860
0.03665
0.05462
0.03651
0.04048
0.02321
0.02681
0.01621
0.01202
0.00787
0.00589
0.00363
0.00267
0.00215
0.00115
0.00106
0.00098
0.00134
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0.00184
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0.02947
0.02077
0.03183
0.04720
0.01909
0.01417
0.07458
0.08170
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0.04173
0.02828
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243.80
298.70
304.80
304.80
335.30
341.40
371.90
371.90
371.90
378.00
371.90
371.90
360.00
340.00
360.00
380.00
380.00
400.00
213.40
213.40
213.40
213.40
213.40
225.60
225.60
237.70
243.80
280.40
317.00
304.80
298.70
341.40
371.90
353.60
365.80
353.60
378.00
384.00
389.20
400.00
420.00
380.00
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400.00
213.40
213.40
213.40
219.50
225.60
225.60
243.80
274.30
286.50
298.70
317.00
298.70
298.70
359.70
384.00
378.00
378.00
378.00
378.00
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
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PEftlOD
PERIOD
PERIOD
PERIOD
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PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
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8760
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8760
8760
8760
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8760
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8760
8760
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360.00
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213.40
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219.50
231.60
225.60
231.60
268.20
304.80
310.90
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323.10
359.70
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384.00
384.00
426.70
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400.00
420.00
400.00
350.00
213.40
213.40
225.60
231.60
225.60
231.60
268.20
304.80
316.40
317.00
304.80
341.40
353.60
365.80
371.90
378.00
384.00
359.70
384.00
378.00
379.20
360.00
400.00
400.00
400.00
370.00
213.40
225.60
231.60
231.60
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
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PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PER -00
PERIOD
PERIOD
PERIOD
PERIOD
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760*'
8760
8760
8760
8760
8760
-------
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- 0.00283
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400.00
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360.00
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213.40
225.60
231.60
231.60
225.60
243.80
249.90
243.80
304.80
304.80
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329.20
347.50
353.60
353.60
384.00
384.00
384.00
378.00
365.80
371.90
360.00
360.00
340.00
380.00
350.00
213.40
225.60
225.60
225.60
225.60
243.80
262.10
286.50
280.40
292.60
323.10
353.60
359.70
359.70
329.20
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
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PERIOD
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PER ICO
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ALL
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ALL .
ALL
ALL
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ALL
ALL
ALL
ALL
ALL
ALL
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
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8760
8760
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8760
8760
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8760
8760
8760
8760
8760
8760
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8760
8760
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8760
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8760
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8760
8760
8760
8760
8760
8760
8760
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-855
-1026
-1368
-1710
-2565
-3420
-5130
-6840
10260
13680
17101
-17
-34
-52
-69
-86
-104
.05090
.06104
.08130
.10181
.15283
.20337
.30518
.40674
.61040
.81450
.01760
.36484
.72969
.09453
.45937
.82422
.18906
-121.55391
-138
-156
-173
-217
-260
-303
-347
-390
-434
-520
-694
-868
-1302
-1736
-2604
-3472
-5209
-6945
-8682
-0
-0
-0
-0
-0
-0
-0
-0
-0
-0
-0
-0
-0
-0
-0
0
-0
0
-0
-0
0
-0
-0
-0
-0
-0
.91873
.28360
.64844
.06055
.47269
.88474
.29691
.70898
.12109
.94531
.59375
.24219
.36353
.48438
.72656
.96875
.45264
.93701
.42188
.00003
.00006
.00009
.00012
.00015
.00018
.00021
.00024
.00027
.00030
.00038
.00045
.00053
.00060
.00068
.00075
.00091
.00121
.00151
.00226
.00302
.00453
.00604
.00906
.01208
.01510
2349
2819
3758
4698
7047
9396
14095
18793
28190
37587
46984
98
196
295
393
492
590
689
787
886
984
1231
1477
1723
1969
2215
2462
2954
3939
4924
7386
9848
14772
19696
29544
.23145
.07764
.77026
.46289
.69385
.92578
.38770
.85350
.77540
.70310
.62890
.48077
.96155
.44235
.92307
.40381
.88470
.36542
.84613
.32697 -
.80768
.00964
.21143
.41345
.61523
.81738
.01929
.42285
.23071
.03809
.05713
.07715
.11430
.15430
.22850
39392.30860
49240
100
200
300
400
500
600
700
800
900
1000
1250
1500
1750
2000
2250
2500
3000
4000
5000
7500
10000
15000
20000
30000
40000
50000
.38670
.00000
.00000
.00000
.00000
.00000
.00000
.00000
.00000
.00000
.00000
.00000
.00000
00000
.00000
.00000
.00000
.00000
.00000
.00000
.00000
.00000
.00000
.00000
.00000
.00000
.00000
0.01592
0.02119
0.01957
0.01509
0.00596
0.00551
0.00387
0.00283
0.00174
0.00152
0.00116
0.00117
0.00204
0.00193
0.00193
0.00214
0.00563
0.00902
0.01994
0.01919
0.01263
0.02377
0.03509
0.02532
0.02231
0.01469
0.02307
0.02015
0.01530
0.01077
0.00640
0.00497
0.00343
0.00302
0.00183
0.00133
0.00106
0.00118
0.00205
0.00193
0.00190
0.00206
0.00392
0.00820
0.01354
0.02341
0.01513
0.04249
0.01430
0.01720
0.01011
0.02035
0.01846
0.02003
0.01555
0.00990
0.00784
0.00627
0.00337
0.00239
0.00179
0.00125
0.00101
347.50
378.00
385.00
371.90
329.20
349.00
360.00
360.00
340.00
370.00
350.00
213.40
225.60
225.60
225.60
225.60
243.80
262.10
292.60
298.70
298.70
335.30
365.80
359.70
359.70
341.40
378.00
384.00
378.00
365.80
341.40
339.90
340.00
360.00
340.00
330.00
320.00
213.40
225.60
225.60
225.60
225.60
237.70
256.00
280.40
298.70
292.60
353.60
323.10
341.40
317.00
359.70
359.70
378.00
383.40
359.70
371.90
380.10
360.00
340.00
380.00
350.00
350.00
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
PERIOD
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
ALL
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
8760
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8760
8760
8760
8760
8760
8760
8760
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8760
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APPENDIX VII-5
Off-Site Accident and Spill Frequency Analysis
-------
CONTENTS
Summary
I. Collision-Related Spill Frequency
II. Non Collision-Related Spill Frequency
III. Frequency of a Specific Size Spill
IV. REFERENCES
Page
5-1
5-1
5-4
5-4
5-6
Table 1:
Table 2.
TableS:
Table 4:
Table 5-
TABLES
Number of Spills from WTI Truck Accidents
Number of Spills from WTI Truck Accidents
Overall Truck AVMT
Distribution of Cargo Losses from Full Size Tankers
During Highway Transit in the U.S. from 1971 to October 1986
Frequency of Specific Size Spill Occurring on SR 39
5-7
5-8
5-9
5-10
5-11
Attachment 1:
Attachment 2:
ATTACHMENTS
Ohio Department of Public Safety Data
Ohio Department of Transportation Data
Volume VII
Appendix VII-5
-i-
-------
OFF-SITE ACCIDENT AND SPILL FREQUENCY ANALYSIS
FOR THE WTI FACILITY
Summary
Spills may occur during waste transport as a result of both major accidents and minor
valve and fitting leaks. Based on an evaluation of site-specific traffic accident data, a
collision-related spill involving trucks bringing waste to the WTI facility is estimated to have
approximately a 1 in 60 chance of occurring each year on State Route 39 (SR 39) in East
Liverpool, Ohio. Non-collision related spills are estimated to have approximately a 1 in 40
chance of occurring each year over the same route. Considering both collision and non-
collision releases, a spill of greater than 100 gallons is estimated to have a 1 in 60 chance of
occurring each year along SR39 in East Liverpool. A spill of greater than 5,000 gallons is
estimated to have a 1 in 295 chance of occurring each year.
I. Collision-related Spill Frequency
The collision-related spill frequency for WTI trucks was derived using the equation shown
in Table 1 and described below.
The potential number of spills each year on SR 39 involving trucks carrying waste to WTI
is estimated by multiplying the number of accidents each year involving trucks carrying waste
to WTI by the probability of a spill occurring during a truck accident:
xrs
Volume VII
Appendix VII-5 5-1
-------
where:
SWTI = Number of spills involving trucks carrying waste to WTI (spills/year);
AWTI = Number of accidents involving trucks carrying waste to WTI
(accidents/year);
Ps = Probability of a spill resulting from a collision (unitless).
According to FEMA (1993) the number of spills per truck accident (Ps) is approximately 0.2,
or approximately 1 spill for every five collisions. The potential number of collisions each year
on SR 39 involving trucks carrying waste to WTI (Awl-i) is calculated by multiplying the
overall truck accident frequency on SR 39 by the annual vehicle miles traveled (AVMTWT1) on
SR 39 by trucks carrying waste to WTI:
Total
where:
AFToial = Overall truck accident frequency on SR 39 (accidents/vehicle-miles): and
AVMTw-r, = Annual vehicle miles traveled on SR 39 by trucks carrying waste to WTI
(vehicle-miles/year).
The overall truck accident frequency on SR 39 (AF,) is equal to the total number of truck
accidents on SR 39 (A,) each year divided by the AVMT on SR 39 by all trucks (AVMT,):
AFTotal= AToul -i- AVMTToUl
where:
ATOUJ = Number of overall truck accidents on SR 39 (accidents/year); and
AVMTTola, = Overall truck AVMT (vehicle-miles/year).
Volume VII
Appendix VII-5 5-2
-------
The AVMT^ is equal to the number of trucks carrying waste to WTI on SR 39 annual!}
(NWTI) multiplied by the length of SR 39 in East Liverpool (D):
AVMT, = NWTI x D
where:
NWT1 = Number of trucks carrying waste to WTI on SR 39 (trucks/year): and
D = Length of SR 39 in East Liverpool (miles/truck).
The Traffic Crash Records Division of the Ohio Department of Public Safety (ODPS) provided
the number of truck accidents on SR 39 (At) in East Liverpool between 1990 and 1995 (see
Attachment 1). These figures include pickup trucks and vans as well as tractor trailer trucks.
The number of trucks carrying waste to WTI on SR 39 (N^,) was estimated to be 3,850,
based on the tons of waste shipped to WTI annually (77,000 tons/year) and the assumption that
each truck transports 20 tons at a time (77.000 tons/year + 20 tons/truck = 3,850
trucks/year). According to ODPS. the length of SR 39 in East Liverpool (D) is 339 miles.
The calculation of Awn is summarized in Table 2.
The AVMT on SR 39 by all trucks (AVMTTmal) was calculated using the equation shown
in Table 3. AVMTToul is equal to the product of the general vehicle daily miles traveled
(DVMTGV), the ratio of truck DVMT to general vehicle DVMT in Ohio State (F), and a
conversion factor of 365 days/year:
AVMTToul = DVMTGV x RT/G, x 365 days/year
where:
DVMTGV = General vehicle DVMT (vehicle-miles); and
RT/GV = Ratio oftruck DVMT to general vehicle DVMT (unitless).
f
The Ohio Department of Transportation (ODOT) provided general vehicle DVMT for SR 39
in East Liverpool (see Attachment 2), but was unable to provide similar data for trucks on this
Volume VII
Appendix VII-5 5-3
-------
route. However, such data are available for other portions of SR 39. Between 1990 and
1994, the ratio of truck DVMT to general vehicle DVMT on SR 39 (RT/GV) was approximately
0.06 in Columbiana County, and 0.08 in the State. Although the traffic in Columbiana County
is likely to be more representative of traffic in East Liverpool, the fraction of truck DVMT to
general vehicle DVMT for the State of Ohio was used as a conservative measure. The truck
DVMT was converted to truck AVMT by multiplying by 365 days/year.
On the basis of the foregoing assessment, it is estimated that the frequency of collision-
related spills on the local access route is 0.017 per year, or approximately once in 60 years.
II. Non Collision-Related Spill Frequency
According to FEMA (1993), the likelihood of a transportation spill resulting from all
causes, including minor valve and fitting leaks as well as collisions, is approximately 2 1/2-
fold higher than the likelihood of a collision-related spill. Thus, the combined collision and
non-collision related spill frequency is approximately 0.043 per year (once in approximately
25 years), and the non-collision related spill is apprDximately 0.026 per year (once in 40
years).
HI. Frequency of a Specific Size Spill
Two different spill sizes were chosen for evaluation in the Accident Analysis: 100 gallons
and 5,000 gallons.
According to FEMA (1993), based on available information on spill sizes, and
considering the likely causes of accidents, it is assumed that 20% of collision-related spills will
result in the loss of the entire tanker contents. In the Accident Analysis, the off-site
conservative volume spill scenario is assumed to involve a 5,000 gallon tanker. On this basis,
it has been assumed that 20% of all collision-related spills would result in a release of 5,000
gallons. The frequency of a 5,000 gallon spill on the local access routes is thus 0.0034 per
year, or approximately once in 295 years.
The distribution of liquid releases from full size tankers (minimum 4,000 gallon capacity)
«
during highway transit between 1971 and 1986 is presented in Table 4. As shown in Table 4,
when all spills are considered, approximately 40% are 100 gallons or larger. On this basis, it
Volume VII
Appendix VII-5 5-4
-------
has been assumed that 40% of all spills (including both collision and non-collision related
spills) would be 100 gallons or larger. The frequency of a 100 gallon spill on the local access
route is thus 0.017 per year, or approximately once in 60 years.
The calculation of frequency for 5000 gallon and 100 gallon spills is summarized in
Table 5.
Volume VII
Appendix VII-5 5-5
-------
IV. REFERENCES
ENVIRON Corporation, Inc. (ENVIRON). 1988. Site assessment phase 4B: Risk
assessment, Volume 2, Appendices A through D. January. Page C-136.
Federal Emergency Management Agency (FEMA). 1993. Handbook of chemical hazard
analysis procedures. NTIS PB93-158756.
Ohio Department of Public Safety (ODPS). 1995. Traffic Crash Records Section. Facsimile
on totals of crashes occurring on SR 39 by years. August 24.
Ohio Department of Transportation (ODOT). 1995. Office of Technical Services. Letter on
Travel Data for SR 39 in East Liverpool, Columbiana County. August 31.
United States Department of Transportation (USDOT). 1986. Hazardous Materials
Information System.
Volume VII
Appendix VII-5 5-6
-------
TABLE 1
Number of Spills from WTI Truck Accidents
SWTI = AWTI x s
Parameter
Su = Number of spills involving trucks carrying waste to WTI
(spills/year)
1990
1991
1992
1993
1994
Average 1990-1994
A,, = Number of accidents involving trucks carrying waste to
WTI (accidents/year)
1990
1991
1992
1993
1994
Average 1990-1994
Ps = Probabilirv of a spill resulting from a collision (unitless)
Value
0.012
0.014
0.022
0.008
0.026
0.017
0.06
0.07
0.11
0.04
0.13
0.08
0.2
Reference
Calculated
Calculated -
See Table 2
FEMA 1993
Volume VII
Appendix VII-5
5-7
-------
TABLE 2
Number of Spills from WTI Truck Accidents
AWT-, = AFToU, x AVMTWT1
where
AFTotal = ATOU1 + AVMTToul
and
AVMTWTI = NIVn x D
Parameter
AWT, = Number of Accidents Involving Trucks Carrying Waste to
WTI (accidents/year)
1990
1991
1992
1993
1994
Average 1990-1994
ATnui = Number of Overall Truck Accidents (accidents/year)
1990
1991
1992
1993
1994
Average 1990-1994
AVMTToul = Overall Truck AVMT in East Liverpool
(vehicle-miles per year)
1990
1991
1992
1993
1994
Average 1990-1994
NWT, = Number of Trucks Carrying Waste to WTI on SR 39
(trucks/year)
D = Length of SR 39 in Fast Liverpool (miles)
Value
0.06
0.07
0.11
0.04
0.13
0.08
5
6
8
3
10
6
1,55,597
1,163,448
929,436
948,883
989,208
985,780
3,850
3.39
Reference
Calculated
ODPS 1995
Calculated -
See Table 3
Calculated -
See Text
ODOT 1995
Volume VII
Appendix VII-5
5-8
-------
TABLE 3
Overall Truck AVMT
AVMTTotal = DVMTGV x RT/GV x 365 days/year
Parameter
AVMTT,,U = Overall Truck AVMT in East Liverpool
(vehicle-miles per year)
1990
1991
1992
1993
1994
Average 1990-1994
DVMTC% = Genera! Vehicle DVMT in East Liverpool
(vehicle-miles per day)
1990
1991
1992
1993
1994
Average 1990-1994
RT/GX = Ratio of Truck DVMT to General Vehicle DVMT in
Ohio State (unitless)
1990
1991
1992
1993
1994
Average 1990-1994
365 (days/year)
Value
1,155,596
1,163,448
929,436
948,883
989,208
985,780
35,178
35,417
31,830
32,496
33,877
33,760
0.09
0.09
0.08
0.08
0,08
0.08
Reference
Calculated
ODOT 1995
Calculated from
ODOT 1995
Conversion Factor
Volume VII
Appendix VII-5
5-9
-------
TABLE 4
Distribution of Cargo Losses from Full Size Tankers
During Highway Transit in the U.S. from 1971 to October 1986
Size of Spill
(gallons)
1
10
20
40
60
100
400
700
3000
5000
8000
15000
Number of Incidents Less Than
or Equal to Size of Spill
452
2937
4378
6017
7340
8695
10866
11517
13097
13740
14247
14475
Cumulative
Frequency of Spill
0.03
0.2
0.3
0.42
0.51
0.6
0.75
0.8
0.9
0.95
0.98
1
Source: USDOT. 1986.
Volume VII
Appendix VII-5
5-10
-------
TABLE 5
Frequency of Specific Size Spill Occurring on SR 39
Size of Spill
(gallons)
100
5,000
Number of Spills Each
Year Involving Trucks
Carrying Waste to
WTI (Sw) (spills/year)
0.043
0.017
Frequency of
Specific Size
Spill Occurring
0.40
0.20
Frequency of Size
Spill Occurring on
SR 39 (per year)
0.017
0.0034
Recurrence Interval
(Years) of Specific
Size Spill Occurring
on SR 39
60
295
Volume VII
Appendix VII-5
5-11
-------
ATTACHMENT 1
Ohio Department of Public Safety Data
-------
FACSIMILE MESSAGE
A*******************************************************
OHIO DEPARTMENT OF PUBLIC SAFETY
TRAFFIC CRASH RECORDS SECTION
1952 VEST BROAD STREET
COLUMBUS, OHIO 43223
PHONE: 614/752-1575
FAX: 614/752-1363
*******************************************************
DATE:
***NOTICE***
THE INFORMATION CONTAINED IN TBIS FACSIMILE MESSAGE IS CONFIDENTIAL BELONGING TO
THE SENDER. THE INFORMATION IS INTENDED ONLY FOR USE OF THE INDIVIDUAL OR ENTITY.
NAMED ABOVE. IF ANY PAGES ARE UNCLEAR OR THERE IS ANY PROBLEM WITH THIS
TRANSMISSION, PLEASE CALL IMMEDIATELY.
-------
Ohio D*p«rtB»nt of Blfhmy Safety - Traffic Craah lUoocda faction
Typaa of Mot ox Vahiclaa Involved in Ohio AccLdaota (mcll)
Craahaa FZOM January, 1 19*0 Thru Dacmbar, 31 1»»0 Data of Rant OI/23/»5 14t2»
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Ohio D*parta»nt of Bigfiver fafety - Traffic Creeti Record* faction
Sypea of Motor Vehicle* Involved la Ohio Aooidente (WC11)
Craahea rxon January. 1 1995 Ttura D«oenfc*r, 31 1995 Data of Bun: 01/23/95 Hi35
Vehicle* la
In-jury
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COMPACT
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fox Dat«a Bp*olfl«d
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OHIO DnimnosT or BICBIOT unry - ranawiFD TRMTIC RICORDI SXSTZM
CJtOOl - Motor Vehicle Traffic Cxaabei In Ohio (Cn) Oat* of Kuni OI/23/95 14:44
Statewide) Craabea Wicm January, 1 1(90 Thru Dao«ab«c. 31 1990
Cr»*b Severity Total Iota!
J*iri«dictlon Xr Total fatal Injury Proprtj Daatha Padaat Injury
anA. County
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Muai Stxa«t
M
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Ccrunty Sub -Total* 3,275 17 1,079 2,179 li 0 1,719 M
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OHIO DBPJUUMDK Or HICINAY KaVKTT - nKRCUXID tRXITIC RBOCKD8 «!
CXOOI - Motor Vahicl* Traffic Craabaa In Ohio (Cum) Data of Raai 09/23/95 14:49
fttatavlda CzaBbas Frco January, 1 1991 Thru D*canb*x, 31 1991
CEMb Satailty Total, Total
Juzledictlon Tr Total ratal Injury Proprty Daatha Padast Injury Padaat
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Unkaom 91 J 0010000
1,227 3 399 *2S 4 1 CM 23
c«un«l Tot*.la J,I7« T5 1,045 2,099 14 2 1.734 32
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ATTACHMENT 2
Ohio Department of Transportation Data
-------
George V. Voinovich
Governor
25 South Front Street
P.O. Box 899
Columbus, Ohio 43216-0899
Au2ust3l. 1995
Ms. Daune Arnsow
ENVIRON
214 Carnegie Center
Princeton, New Jersey 08540-6284
Re: Travel Data for SR 39 in East Liverpool, Columbiana County
Dear Ms. Amsow:
We have prepared the attached data sheet in response to the subject request. The information was
extracted from our historic Highway Performance Monitoring System databases.
The traffic data was available for each section of SR 39 at the state, county and incorporated level. The
HPMS truck information, however, was not available on a sufficient number of sections to be
particularly meaningful except, possibly, at the State level. Furthermore, the HPMS sections with the
additional truck data are selected for statistical adequacy upon a basis that is not necessarily sufficient
for projecting a single route, even at the State-wide level.
The SR 39 data is only for those sections of SR 39 that are primary routes. In other words, those
sections of SR 39 "overlapping" with other route(s) with a higher functional class, a higher jurisdictional
level (interstate or US route), or a lower route number at the same jurisdictional level, are not included in
this data. In Columbiana County, such sections would be where SR 39 follows SR 7 and US 30.
Some additional truck data was available in the current State "traffic book" database. The truck data
from that file represents East Liverpool and Columbiana County for approximately 1992-94, and the
State for about 1990-1994. The values computed from the traffic book's data are as follows:
East Liverpool
Columbiana County
State of Ohio
SR 39 traffic is 11.20% trucks
SR 39 traffic is 7.00% trucks
SR 39 traffic is 6.70% trucks
-------
August 31, 1995
ENVIRON - page 2
Please note that the HPMS truck data indicates that the proportions of SR 39 truck travel in Columbiana
County range from 8% (1990-91) to 5% (1992-94) of the total vehicle travel, and at the State wide level.
about 8%.
Please do not hesitate to call Ms. Andrea Goldberg of my staff (614)466-2697 if you have any questions
or require additional information.
Respectfully,
James E. McQuirt, P.E.
Administrator
Office of Technical Services
JEM:db
Attachment
-------
ATTACHMENT
1) Estimated Daily Vehicle Miles Traveled (DVMT) for Columbiana County
DVMT
2)
1990
1991
1992
1993
1994
SR 39 State-Wide Data
2,480,770
2,550,010
2,695,350
2,671,490
2,724,910
1990
1991
1992
1993
1994
All
DVMT
613,901
624,036
640,018
694,641
705,359
3) SR 39 Columbiana County Data
1990
1991
1992
1993
1994
4) SR 39 East Liverpool Urban Area Data
All
DVMT
1990
1991
1992
1993
1994
35,178
35,417
31,830
32,496
33,877
(projected from 1993)
Truck
DVMT
53,924
56,251
48,588
56,085
56,950
All
DVMT
81,093
82,074
82,168
84,292
86,180
Truck
DVMT
6,487
5,566
4,108
4,215
4,309
Truck
DVMT
Miles
140.90
140.90
140.74
140.74
140.74
Miles
17.11
17.11
17.11
17.08
17.08
Miles
3.39
3.39
3.39
3.36
3.36
a)
b)
New traffic counts taken for Columbiana County in 1992. 1990 and 1991 counts are projections of the
previous (circa 1988) counts; 1993 and 1994 are projections cf the 1992 counts.
Truck information is based upon a sample of approximately 11.5% of the statewide mileage and
approximately 2% of the Columbiana County mileage. No truck breakdowns were available within East
Liverpool.
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