600D80022
Tuesday
December 18, 1979
Part IV
Environmental
Protection Agency
Guidelines Establishing Test Procedures
for the Analysis of Pollutants; Proposed
Regulations; Correction
EPA-600/D-80-022
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75028 Federal Register / Vol. 44. No. 244 / Tuesday. December 18. 1979 / Proposed Rules
ENVIRONMENTAL PROTECTION
AGENCY
40 CFR Part 136
[FRL 1323-D]
Guidelines Establishing Test
Procedures for the Analysis of
Pollutants
Correction
In FR Doc. 79-36871, appearing at
page 69464 in the issue for Monday,
December 3,1979, Table I—List of
Approved Test Procedures (pages
69568—69573) and Table II--Containers,
Preservation, and Holding Times (pages
69574—69575), contained numerous
printing errors. Tables I and II should
have read as set forth below:
BILLINO CODE 1S05-01-M
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Federal Register / Vol. 44, No. 244 / Tuesday, December 18, 1979 / Proposed Rules
75029
1MUB I. LIST OF AttWWED TC9T
mxjaiuws
Reference (Page Hoe.)
1.
2.
3.
Parameter and units
Acidity, as CaOOj,
milligrams par liter
Alkanl'jilty, as CaCOj
milligrams per liter
ftmonla (as H) ,
milligrams per liter
1974
H*
Method Methods
Electrometric end point (pH of 8.2) 1
or phenolphthalein end point
Electrometric titration (only to 3
pH 4.5) manual or automated, or 5
equivalent aubomated methods
Manual distillation3 (at pH 9.5)
followd by nesslerlzaticn, titration, 159
electrode, 165
automated phenolate 168
14th Ed. Part 31
Standard 1975
Methods ASM
273 (4d) 116
278 111
-
410
412 237
-
61S
Other
U9G3 , Approved
Methods Methods
40 (607) 2
41 (607) 2
-
-
116 (614) 2
-
"
Bacteria
4.
5.
6.
7.
8.
Ooliform (fecal)4
number per 100 ml
Coliform (fecal)4 in
presence of chlorine.
number per 100 ml
Coliform (total)4,
number per 100 ml
Ooliform (total)4 in
presence of chlorine,
number per 100 ml
Fecal streptococci4.
number per 100 ml
MWi5
membrane filter
MTO;5
membrane filter 5«7
MPt»,5
membrane filter
MPHi5
membrane filter Kith enrlchnant
MPNt5
membrane f liter I
plate count
922
937
922
928,937
916
928
916
933
943
944
947
<130«
(45»*
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75030
Federal Register / Vol. 44, No. 244 / Tuesday, December 18, 1979 / Proposed Rules
TNSUS I. LIST OT MVMWEU TEST MtXUXWS (Conl.)
Parameter and cnits
Method
1974
cm
Methods
Reference (Page Nog.)
14th M. Part 3l
Standard 197S U9GS
ASM
Methods
Other
Approved
Methods
13. Chloride, milligram
par liter
14. Chlorinated organic
compounds (exoept
pesticides), milligram
per liter
15. Chlorine—total
residual, milligram
per liter
16. color, platlnn cobalt
uilta or dominant «ava
length, hue, lualnanos,
purity
Silver nitratet
mercuric nitrate) or
automated coloria»tric-ferricyanide
GM chromabography U
29
31
lodonetxlc titratlen, amperometrlc or
•tarch-iodlne end-point) 35
at) coloriaetrie or
Tltrimetrlc •athodi Rtaae last two
are Interim matted* pending labora-
tory testing.)
ODlortaetrlci 36
•pectrophotcnetrlci or 39
AM procedure U
303
304
613
267
265
(46) W
1615)'
318
322
332
329
64
66
278
82
17. Cyanide, total u,
•llllgram per liter
IB. Cyanide amenable to
chlorinatitn, mllil-
grana per liter
19. Uaaolved oxygen,
milligram per liter
20, Fluoride, milligram
per liter
21. Hardness—total, aa
CaCo.,, milligram
par liter
Distillation followed by silver nitrate 40
titratlen or pyridine pyrazolone (or
barbituric acid) colorlmetric
361
85 (22)'
Distillation followed by silver nitrate 49 376
titratlen or pyridine pyrazolone (or
barbituric acid) colorinetrlc
MnUer (Aside modification) or 51 443
electrode method 56 450
Distillation3 followed by - 389
ion electrode) 65 391
SPAtNEi or 59 393
autonated ooifileonne 61 614
EDZA titratlen) 68 202
autcnated ooloriimstrlc) or 70 -
atomic absorption (BUB of Ca and Hj -
aa their reapective carbonates)
503
503
368 126 (609)'
307 93
305
161
94 (617)2
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Federal Register / Vol. 44, No. 244. / Tuesday, December 18, 1979 / Proposed Rules
75031
•ML* I. UST OF APPROVED TOST PROCEDURES (Cant.)
Parameter and mite
Method
Reference (Page NOB.)
1974 14th ftl. Part 31
EPA Standard 1975 U9GS .
Methods Method! ASM Methods
Other
Approved
Methods
22. Hydrogen Icn (pH),
pH unita
23. Kjeldahl nitrogen (as-
N), milligram par
liter
Electrcmetrlc measurement 239
Digestion and distillation followed 175
by nesslerlzaticn, tltraticn, or
electrode) 165
automated dlgeatlon autanted phenolata 182
460
437
178
129
122
(606)'
(612)'
Metal*
24. Alunintn—total,
•llllgnn par liter
25. AlvminuB—dissolved,
mllligrtms per liber
Digestion14 followed by
atcnic absorption15 or by
oolorinetrlc (Eriochrome Cyanide R)
or by I0>27
0.45 micron filtration16 followed Jy
referenced nthads for total aliadnui
92
152
171
(19)
10
26. Antimony—total,
milligram per liter
Digestion14 followed by
atsnic absorption U
27. Antinny—disaolvwS,
•ilUgnwper liter
28. Arsenic—total,
Milligram per liter
29. Arsenic—dlMolved,
•illignoa per liter
30. Baria—total,
•dlUgrao* par liter
31. B«rii»—dissolved.
•UliqraM per liter
32. Barylllvw—total,
ndlligran per liter
0.45 micron filtration u followed by
referenced method for total antimony
Digestion followed by
silver diethyldithiocarbaBBtei or
atomic absorption 1S< a
or by 1O> n
0.45 micron filtration M followed by
araenio
referenced method for
Digestion ** followed fay atomic
absorption15 or by KP27
0.45 micron filtration" followed by
referenced method for total Darin
Digestion M followed by atomic
absorption** or by oolarimetria
(Alimdnon) or fay TCP27
9
95
97
285
283
159
152
.152
177
(31)
(37)
10
10
52
S3
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75032
Federal Register / Vol. 44, No. 244 / Tuesday, December 18, 1979 / Proposed Rules
•WBIB1, UST OP ATPncMEO TEST PHXEDWES (Cont.l
33.
34.
35.
36.
37,
38.
39.
40.
41.
42.
43.
44.
Parameter and units
BeryUium— dissolved.
milligram per liter
Boron— total. Milli-
grams per liter
Boron — dissolved,
Milligram per liter
Cadmium— total
milligram per liter
Cadmium— dlsaolwd.
milligram per liter
Calcium— total.
milligram per liter
Calcium— dissolved,
Milligram per liter
Chromium VI, milli-
gram per liter
Chromium VI— dissolved.
milligram per liter
Chromium— total,
mllllaram per liter
Milligram per liter
Cobalt— total.
Milligram per liter
deference (Page NOB.)
1974 14th Bd. Part 31 Other
EPA Standard 1975 U9GS , Approved
Method Methods Methods ASM Methods Methods
0.45 micron filtration1* followed by -
referenced Method tor total beryllium
Colorimetrie (Curcumln), 13 287 - -
or by ICP27 ... -
0.45 micron filtration1* followed by -
referenced method for total boron
Digestion14 followed by 101 148 345 62 (619) 2 (37)'
atomic absorption or by
oolorimetric (Dithiscne) 182
or by ICP27 - -
0.45 micron filtration 1S followed by -
referenced method tor total cedmlu*
Digestion14 followed by 103 148 345 6«
atomic absorptlont or
BDT* titration - 189 - -
or by TCP "
0.45 micron filtration16 followed -
by referenced method for total calcium
Extraction and atomic absorption) 89, 105 76
colorlmetrlc (Dlphanylcarbazide) 192 75
0.45 micron filtration16 followed by -
referenced Method for chromium VI
Digestion" followed by 105 148 345 78 (619) 2
atomic absorption or by
oolorimetric (Diphenyloarbazide) - 192 286 77
or by KP27 ...
0.45 Micron filtration16 followed by
referenced method fair total otumium
Digestion 1* followed by 107 148 345 80 (37)
or by KP27 ... -
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Federal Register / Vol. 44. No. 244 / Tuesday, December 18, 1979 / Proposed Rules
75033
TTIBLB I. UST or AITIOVED TEST PWXHWBE8 (cont.)
45.
46.
Psrareter and wiita
Cobalt — dissolved,
milligram per liter
Copper — total,
milligram per liter
1974
EPA
Method Methods
0.45 micron filtration16 followed by
referenced method for total cobalt
Digestion 14 followed by 108
atonic absorption or by
colorimetric (Neocuproine) »
14th td.
HeShrds
148
196
Rpferenre \fz 27
16
0.45 micron filtration followed by
referenced method for total copper
Digestion 14 followed by
atonic absorption 18
49. Iridium—total, milli-
grams per liter
Digestion
14
followed by
atonic absorption 19
50. Iron—total, milli-
grams per liter
Digestion U followed by
atonic absorption or by
colorimetric (Phsnanthrollne)
or by ICP 27
110
148
206
345
326
102 (619)"
51. Iron—dissolved,
milligram per liter
52. lead—total, milli-
grams per liter
53. Lead—dissolved,
milligram per liter
54. Magnesia*—total,
milligram per liter
55. Itegnesiin-dlsaolved,
milligram per liter
56. Manganese total,
milligram par liter
0.45 micron filtration16 followed by
referenced method for total iron
Digestion 14 followed by
atonic absorption or by
colorinetric (Dithizcne)
or by ICP27
0.45 micron filtration16 followed by
referenced method for total lead
Digestion14 followed by
atonic absorption) or
9raviinetrlc
or by ICP27
0.45 micron filtration 1S followed by
referenced method for total mognesiun
Digestion followed by
atonic absorption or by
colorimetrlo (Feraulfate or perlodate)
or by Id 2*
112
114
116
148
215
148
221
148
225, 227
345
105
(619)'
345
109
(619)'
345
111
(619)'
-------
75034
Federal Register / Vol. 44, No. 244 / Tuesday, December 18, 1979 / Proposed Rules
TOBLE I. LIST or WT1WEO TEST PKXETWraS (Cont.)
57 .
58.
59.
60.
SI.
62.
61.
64.
Parameter and units
}tai JIJ^M nj-jc dissolved .
milligram per liter
ttercury— total.
milligram per liter
Mercury — dissolved,
milligrams per liter
jfclybJenu*— total,
milligrams per liter
MDlytdenim— dissolved.
milligram per liter
Nickel—total,
milligrams par liter
Nickel— dissolved,
milligram per liter
CWniun— total,
milligram per liter
Reference (Page Mne.)
1974 14th Ed. Part 31 Other
B* Standard 1975 UBG8 . Approved
Method Methods Methods ASTM MeUwds Methods
0.45 micron filtration followed by -
referaiced method for total aainjarieua
Flawless atrmio absorptim 118 156 338 (51) 10
0. 45 micron filtration16 followed by -
referenced method for total mercury
Digestion M followed by 139 - 350 - -
atomic absorption 15
or by 10>27 -
0.45 micron filtration16 followed by - -
referenced method for total molybdenui
Digestion M followsd by 141 148 345 115
atomic absorption or by
colorlmetrlc (Heptadire) _ 232 ...
orbylCP27
0.45 micrcn filtration16 followed by -
referenced method for total nickel
Digestion U followed by -
atomic absorption
65. Palladitm—total,
milligram per liter
Digestion14 followed by
atomic absorption U
66. Platintn—total,
milligram per liter
Digestion
14
followed by
atomic absorption 18
67. Potassium—total,
^ milligrams per liter
Digestion U follownd by
atomic absorption,
coloriaetric (Oobaltinitrite), or by
flame photometric
or by ICP 2'
143
134
(620)'
235
234
403
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Federal Register / Vol. 44, No. 244 / Tuesday, December 18, 1979 / Proposed Rules
75035
ireus i. LIST or MHWED it&r faoaauaa (ooot.)
68.
69.
70.
71.
72.
73.
74.
75.
76.
77.
78.
Parameter and imits
Potaaaiun— dissolved,
milligrams per liter
Rndlm— total,
milligrams per liter
Ititheniun— total,
milligrams per liter
Seleniu*— total,
milligrams per liter
Selenlin— dissolved.
milligrams per liter
Silica— dissolved.
miligram per liter
Silver-total M
ftfiijji ffff per liter
Silver-dissolved ls.
milligrams per liter
Sodlm— total,
milligrams per liter
Sodivin— -dissolved.
milligram!! per liter
Tnslliun— total,
milligram per liter
Reference (Page (fee.)
1974 14th Bd. Part 31 Other
B* Standard 1975 USGS . Approved
Method Methods Methods ASTM Methods Methods
0.45 micron filtration 16 followed by -
ref erenoed method for total potoasiun
Digestion M followed by -
atonic absorption lg
Digestion M followed by -
atonic absorption
Digeatlon M followed by 145 159 -
atcmic absorption "• 1B
orbyld>27
0.45 micron filtration 1S followed by -
reference method for total seleniun
0.45 micron filtration l6 followed by 274 <• 398 139
colorinetrlc Qtolybdoeilicate) 497
or by 1CP27 .....
Digestion M followed by 146 148 - 142 (619) 2 (37)9
atomic absorption or by
colorjnetric (Dithixone) 243 - -
orbyHT27
0.45 micron filtration 1S followed by -
ref erenoed method for total silver
Digestion M followed by 147 143 (621) 2
atonic absorption or by
flans photometric * 250 403
orbyltT27
0.45 micron filtration 1S followed by -
referenced nothod fot tPtJil sodltn
Digestion 14 followed by 149
atonic absorption 15
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75036
Federal Register / Vol. 44, No. 244 / Tuesday, December 18, 1979 / Proposed Rules
TflBUB I. LIST 07 APPRWED TEST PROCEDURES (Cont.)
Parameter and units
Method
Beference (Page NOB.)
1974 14th W. tart 31 Other
em Standard 197S U9GS . Approved
Methods Methods WSTM Methods1 Methods
79. Thallim-dissolved,
milligram per liter
60. Tin—total, milli-
grams per liter
0.45 micron filtration16 followed by
referenoed method for total thallium
Digestion 14 followed by
atonic absorption
15
150
(65)
10
01. Tin—dissolved, milli-
gram per liter
82. Titenlin—total,
milligrams per liter
0.45 micron filtration U followed by
referenced method for total tin
Digestion M followed by
atomic absorption
151
83. Titanius-dissolved,
milligrams per liter
84. Vanadium—total,
milligram per liber
0.45 micron filtration 1S followed by
referenced method for total titanium
Digestion M followed by
atonic absorption or by
oolceimetric (Gallic add)
or by KT n
153
152
260
Ml
W?)
10
85. Vanadiun—dissolved
milligram per liter
86. Zinc—total, milli-
grams per liter
87. tine—dissolved,
milligram par liber
0.45 micron filtration16 followed by
referenoed method for total vanadltm
Digestion14 followed by
atomic absorption or by
colorimetric (Dithlione)
or by OT27
0.45 micron filtration16 followed by
mefchod Cor totflJL sine
155
148
345
159
(619)2(J7)9
88. Nitrate (as Nt, milli-
grams per liter
89. Nitrite (as N), milli-
grams per liter
90. CHI and grease, milli-
gram per liter
Cadmiu* reduction 201
brucine sulfatel 197
automated cadMin or hydrazine reduc- 207
tien20
Manual or autcmted colcriTOtric 215
(Dlaxotizatlon)
Liquid-liquid extraction with tri- 229
chlorotrmuoroethane-gravinetric
423
427
620
434
SIS
358
119
121
(614)2 (28)'
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Federal Register / Vol. 44, No. 244 / Tuesday, December 18, 1979 / Proposed Rules
75037
TtBLE 1. UST OP ATPflWED 1BOT PROCEDURES (Cont.)
Parameter and units
Method
Reference (Page Nos.)
1974 14th W. Part 31 Other
Hf» Standard 1975 UBGS . Approved
Methods Methods ASM Methods Methods
91. Organic carbon) total
(TOC), milligram per
liter
92. Organic nitrogen
(as N), mllligrms
per liter
Confcustlon— Infrared netted2 236 532
KJeldahl nitrogen ndnm amonia 175,159 43V
nitrogen
467
( 4)
122
22
(612,614)'
Qrauiic
93. Acenaphthene,
microgra™ per liber
94. Acenaphthylane,
nicrogranv per liter
95. Acroleln,
mlcrogrwiB par liter
96. ftcrylonitrile,
•dcxogranB par liter
OC or HPIC method (610)
OVM3 i»sthod(625) 26
GC or HPI£ method (610)38
GO/MS mettod(625) M
OC method (603)31
BBthDd(524) M
31
OC method (603)
method (624)
K
97. Aldrln,
nicrogramg per liter
98. Anthracene,
nicrograma par liter
99. Benzene,
micrognro par liter
100. Benzldlnei
mllllgron per liter
nicrograna par liter
101. Benzo(a)anthracenB,
nicrograno per liter
102. Benzo(a)pyrena,
mictograms per liter
103. Benzo(b)fluoranthena
Bd.crujj.MTiB per liter
104. Benxo(g,h,l)peryl0na,
microgranv per liter
GC method (608)
GC/MS, method
36
26
,26
OC or VPIC method (610)
OC/IB method (62S)26
OC method (602)
GC/MS method (62'4)'
HPIC method (60S)33
Oxldatlon-oolormetrlc*
GC/MS method(625) 26
OC or HPIC method (610)
GC/MS, method (625)26
OC or HPIC method (610)
ethod
38
38
38-
OC or W1C method (610)
OC/HB method ( 625 )26
OC or HPIC method (610)
method (625) 26
38
38
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75038
Federal Register / Vol. 44, No. 244 / Tuesday, December 18, 1979 / Proposed Rules
17IBt£ I. LIST OF APPRWED TEST PHUCHJUHtS (Cent.)
105.
106.
107.
108.
109,
110.
111.
112.
113.
114.
115.
116.
117.
118.
119.
120.
Parameter and units
DenzoOc) CluoranthenBf
RilcLuyiauB per liter
B-BHC,
ntlczogran per liter
b-BHC,
mlcrograme per liter
d-BHC,
nicrognn per liter
g-BIC
microgranB per liter
Bis(2-chloroethyl) ether
•ticxocfraRB per liter
Bis(2-chloroethoKy) methane
raicrogra™ par liter
Bl»(2-chlorolaopropyl) ether
microgranB per liter
BU(2-ethylhexyl) phthalate,
micrograms per liter
Brarodichloromethane,
microgranB per liter
micrograms per liter
BromofflethanB,
mlcrograma per liter
4-Bronophenylphenyl ether,
nicrograRB per liter
Butyltenzyl phthalate,
micrograne per liter
Carbon te trichloride,
micrograme per liter
Chlordane,
micrograRis per liter
Reference (Page Nos.)
1974 14th M. Part 31
EPA Standard 1975 USGS ,
Method Methods Methods ASW Methods
OC or HPIC method (610)38 ....
OC/MS method, U25)2* .
OC method (60S)36 -
OC/MS method (62S)26 -
OC method (60S)36 -
OC/MS method (6J5)26 ....
OC method (60S)36 -
GC/MS method (625) X -
OC method (60S)36 -
OC/MB method (625) M ....
GC method (611)39 ....
OC/MS method (625) M -
GC method (611)39 ....
OC/MS method (625) 26 -
OC method I611)39 -
OC/MS method (625) x -
OC method (606)34 -
OC/MS method (62B)26 -
OC method (601)29 -
OC/MS method (SZ^)2* -
GC method (601) W ....
GC/MS method (624)* -
OC method (601)29 ....
GC/MS method (6Z4)26 -
GC method (fill)39 -
OC/MS method (82S)26 ....
GC method (606)34 -
OC/MS method (62S)26 -
OC method (601)29 ....
OC/MS method (624)26 -
OC method (60S)36 ....
GC/MS method (6i5) -
Other
Methods
_
.
-
-
-
;
-
:
:
-
.
-
-
-
-
:
-
.
-
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Federal Reeister / Vol. 44, No. 244 / Tuesday, December 18, 1979 / Proposed Rules
75039
TOW* 1. LIST OF APPBCWED TEST PWXECU3S (Oont.)
121.
122.
123.
124.
125.
126.
127.
128.
129.
130.
131.
132.
133.
134.
135.
136.
Parameter and wits
4-Chloro-3-methylphenol
nlcrocfFBnB per liter
OilorobenxenB/
ntcrognro per liter
Odoroe thane,
mlcrogrwna per liter
2-Chloroettrylviiyl fetter
nicroijiflns per liter
ChlorofoOT,
inicxuyiflsTB per liter
ChloconethBnBf
•dciugiaia per liter
2LC method (610)38 -
OC/MS method (eWfl26 -
OC method (608)3* -
OC/MS method (625) X -
OC mettnd (60S)36 -
OC/MS method (625) 2S -
OC method (60S)36 -
OC/MS method (625) * -
OC or BPLC method (610)38 -
OC/MS method(625) 26 _ - - -
OC method (601)29 -
OC/MS method (624J26 -
OC methods (601)M (602) 30 (612) 40 -
OC/MS method (62J)26 _ - - -
Other
flpprowed
Methods
-
•
-
-
-
-
-
-
-
-
-
-
-
-
-
-
—
-
™
-
-
-
-
-
-
-
-
-
-
-
-
-------
75040
Federal Register / Vol. 44, No. 244 / Tuesday, December 18, 1979 / Proposed Rules
TRBUS I. UST OF AOTWED TEST PI»?EDUHES (Cont.)
Parameter and units
137.
138.
139.
140.
141.
142.
143.
144.
145.
146.
147.
148.
149.
150.
151.
152.
1 , 3-Oichlorobenzene
micrograms per liter
1, 4-Oichlorobenzene,
micrograms per liter
3 , 3 ' -Dichlorcfcenzidine ,
micrograms per liter
Dichlorodifluorone thane
micrograms per liter
1,1- Dichloroethana
ntLcrogrsms per liber
1, 2-Dichloroethana,
raicrogra™ per liter
1,1-Oichloroethane
micrograms per liter
trano-l, 2-OidiloeDeth»nB,
miciuyiswB per liter
2, 4-Oichlorophenol,
microgranB per liter
fnl 'ii un JMIM r^r 1 4 titr
ci8-l,3-Dichlaropropene
microgramB per liter
trans-1, 3-Dichloropropaie
mjuimjt MM per ULber
Dieldrin,
micrograms per liter
Diethyl phthalabs,
microgrjro pel liter
2, 4-DtnethylphenDl,
nicrograms per liter
Dimethyl phthalabs.
microgramB per liter
Reference (Page Nos.)
1974 14th Ed. Part Jl
EEft Standard 1975 U9GS ,
Method (tethods Methods ASTM Methods
GC methods (601) M (602) X (612) 40 -
GC/ttS method (62S)26 -
OC methods (601) 29 (602) M (612) 40 -
QC/HS method (S25)26 ....
One method (60S)33 -
OC/MS method (6ZS}26 -
OC method (601)29 - -
OC method (601) ** -
OC/»B method (624) K -
OC method (601)29 -
OC/HS method (624) 2* - _ _ -
OC method (601)29 -
OC/MS method (624) 2S -
OC method (601)29 -
OC/M5 method (624) * -
OC method (604)32 -
OC/MS method (625)26 -
OC method (601)29 -
OC/MS method (624)26 -
OC method (601)29 -
OC/«S BBthod(624)26 -
OC method (601)29 -
GC/VB netted (62O26 -
OC method (60S)36 -
OC/MS method (625) * -
OC method (606)34 ....
OC/MB method (62Sf 28 -
OC method (604)32 -
OC/MB method (625) M -
OC method (606)34 -
OC/MS method (625) 26 -
Other
Approved
Methods
-
-
-
-
-
-
-
-
-
.
-
-
-
-
-
-
-
-
-
-
-
-
-
-
*
-
*
-
-
'-
"
-------
Federal Register / Vol. 44, No. 244 / Tuesday, December 18, 1979 / Proposed Rules
75041
tfBlX I. LIST OP APVRM9J TE3T PRXEDWES (Cont.)
153.
154.
155.
156.
157.
158.
159.
160.
161.
162.
163.
164.
165.
166.
167.
168.
Parameter and units
Di-n-butyl phthalat*,
micrograms per liter
Di-n-octyl phthalabe,
itdcrograms per liter
4 , 6-Dini tro- 2-methylph»-
nol, micrograms per liter
2,4-Dinitrophenol,
micrograms per liter
2,4-Dlnitrotoluane,
micrograms per liter
2, 6-Dini trotoluene,
micrograms per liter
1,2-Dlfhenylhydraslne,
nd-crograBiB por liter
Endoeulfan I,
ndcrograrae per liter
Enfeeulfen II,
miuiuyrsMi per liter
Endoeulfen eullafae,
micrograws per liter
Endrin,
BdcrograM per liter
Endrin aldehyde,
•dcrograMs per liter
Bthylbamene,
nicrograms per liter
Fluoranthene,
micrograns per liter
Pluorene,
mtciMiii.au) per liter
fteptechlor.
Reference (Page NOB.)
1974 14th Bd. Part 31
EPA Standard 1975 USGS .
Method Methods Methods WIM Methods
OC method <606) 34 -
OC/MS method (625)26 -
OC method (606)3* -
GC/MS method (625) 26 -
OC method (604)32 -
GC/MS method (625) 26 -
OC method (604)32 -
OC/MS method (6Z5)26 -
OCiBBtnod (609)37 -
OC/MB method (625)2S -
OC method (609)37 ....
OC/HS method (62S)26 -
OC/HB method (6Z5)26 -
OCBsthod (608)36 -
OC/MS method (62S)26 ....
OC method (608)36 - ...
OC/HS method (625) M -
OC method itm}36 .
DC/to method (625) * - ...
OC method (60S)36 - ...
OC/MS method (625) W - ...
OC method (608)36 -
OC/HB method (625) K -
OC method (602)30 - ...
OCAB method (624) ^ - ...
OCor me method (610) M -
OVHB method (62S) * -
OC or HPIC method (610)38 - . .
OCVHB method (62S>26 - ...
OC method (6O8)36 -
Other
Approved
Methods
-
-
-
-
-
:
_
_
-
-
-
-
-
mlcrogrtpB per liter
OC/HB method (625)
**
-------
75042
Federal Register / Vol. 44, No. 244 / Tuesday, December 18,1979 / Proposed Rules
TffUE 1. LIST OF KfPKNED TEST MUEUUWS (Cnnt.)
Parameter and unlta
169.
170.
171.
172.
173.
174.
175.
176.
177.
178.
179.
180.
181.
182.
Heptachlor epoxide,
ralcrrxfranw per liter
Itexachlorcfoenssens,
mlcrogrwiB per liter
tfexachlorobutadlwe,
ndcrogra™ per litar
itexachlarocjclopentacUsne,
mtcrogrsw par liter
ttexadhloroethane.
micrograna per liber
micrograms per liter
Isophorone,
microgrsiB per liter
Methylene chloride,
micrograne per liter
Nitrobenzene,
micrograniB per liter
2-Hitrophenol,
4-Hitrophenol,
micro^nvrB per liter
^^^^l^ t^ » >E'«HI"»I ^ylf11^ y^i
H^troBodipropylaidnB,
Befermra (Page »«.)
1974 l4th «. ParFTT
K>thod Methods Methods ASflH Methods
OC method (60S)3* -
OV^E method (625)26 - -
GC method (612) 40 -
OC/MS method (625)2S -
OC meOcd <6ia)40 -
OC/MS method (625J26 -
OC emthod (612)40 -
OC/»« method (625) 2fr -
QC nethod (612) 40 -
OC/MS method (625) 26 -
OC or OPIC method (610)38 -
OC/MS method (625) ^ -
OC method (609)37 -
OCAB method (62S)26 -
QC method (601)29 -
OCABmBewd (624)26
OC or HPUC method (610)38 -
OCAB mthod (625)26 -
OC nethod (609)37 -
OCAB method (625)26 -
0= method (604)32 -
OCAB method (625)2S - - - -
OC nethod (604)32 -
OCAB method (625)26 -
OC method (607)35 -
OCAB method (625) * -
OC netted (607)35 -
OtSier
Mettxris
-
-
-
-
-
„
-
:
-
-
-
_
_
_
.
-
26
183. H-NitrooodiphenylaBdne,
nticxo^rafflB per liter
184. PCB-1016,
per liter
OC/MS method (625)
OC method (607) 35
OCAS method (625)
OC method (60S)
OC/HB method (625)26
26
-------
Federal Register / Vol. 44, No. 244 / Tuesday, December 18, 1979 / Proposed Rules
75043
- —
185.
186.
187.
188.
189.
190.
191.
192.
Parameter en) unlU
POB-1221,
microgr&Kj P&f liter
PCB-12J2,
ndcrograms per liter
PCB-1242,
*B| r^W^ur >U.-1 f»f 1 ^ ^"OT
PCB-1248,
mlcro^frafno per Xlber
PCB-1254,
• n •!!• r*»T 1 1 t^V
PCB-1260,
PentacMorophenol,
mlcrogrow per liter
Phenanthrene,
T«BU! I. UST OF APPKNED TEST PWXEDOiaS (Cont.)
Reference (Page_NoB . )
1974 14th ta. Pwt "11
EPA Standard 1975 USGS j
Methtid Methods Methods ."OTM Mctficds
OC method (60S)36 -
OVMS method ($2S) 26 -
a.' metiiod (60S)36 -
GC/MS method (626) 2* -
GC method (60S)3* -
OVMS methtxl(625)M -
OC mathod (60S)36 -
OC/>6 method (S?5)2S - - - -
OC method (608) X -
OCAB method (6Z5) 26 -
OC m-ttiod (60S)36 -
OC/tE method (625) 26 -
GC netiiod (60S) - -
GC/MS matiod (625) 26 _ - - -
GC or MPIC method (610) M -
Otlier
Approved
Methods
-
~
-
-
-
-
-
-
-
-
193. Pherol,
ndcxogram per liter
194. Pyrene,
ndcrogrnB per liter
195. 2,3,7,9-ttetrarfdoto-
dlbenzo-p-dioBtln
mlcrogmiB per liter
196. 1,1,2,2-TetrachlDeoB-
thnno,
per liter
197. Tetrachlaroethene,
sr liter
198. Tbluene,
micro9mno per liter
199. Ttaxaphene,
OC/MS mettod (625) 26
GC netted (604)
32
26
OC/MS method (6?S)
GC or HPIC method (610)
GC/MS metiwd (623\26
38
irethods (613)41 (6S5)2'
OC method (601)
29
26
26
psr liter
GC/»B method (62«)
OC method (601)29
OC/W method (624)
OC method (602)M
DC/MS method (624).26
OC method (609)36
GC/MS method (GZ5)26
-------
75044
Federal Register / Vcl. 44, i\'o. 244 / Tuesday, December 18, 1979 / Proposed Rules
TBBIE I. UST Of APFRWED TEST PHOCEDUPES (Goflt.)
Parameter and initn
200. l,2,4-Trlc^oroben»es*,
inicmyi <_HKI pc_r li^jsr
201. 1,1,1-Triohloroethai*,
wiu JL uy i w w per ii bsx"
202. 1,1,2-Trichloroethane,
mictogiavM per liter
203. TrichlDroethene,
ndcrogme per liter
204. TriehlegoflueaoneUianB,
mlcrogramB per liter
205. 2,4,6-TricMQrophe«>l,
niicrograms per liter
206. Vinyl Chloride,
micrograms per liter
207. Qrthophosphate (as P),
milligrams per liber
208. •Pesticides, milligram
per liter
209. Phenols, milligram
per liter
210. Phosphorus (elemental),
milligrams per liter
211. Phosphorus) total (as
P), milligrams per
*°
QC nethod (612)
OC/MS i~rthod(625)
OC msthod (601)29
QC/fB i
26
QC method (601)
OC/MS nethod(624)
OC method (601)W
OC/MS method(62«)
OC method (601)W
OC/MS method (624)
OC method (604)32
29
OC meUwd (601)
TOthod(624)
26
14th BH.
"tar OF
1975
OtJ>er
Manual car 249
automated ascorbic acid reduction 256
.10
Gaa chxtmtography'
Oolorlimtrlc, (4AAP)
22
241
481
624
555
582
384
529
545
131 (621)"
(24)U
Gas chrcnatography'
Persulfate digestion followed by manual 249
or autonted ascotblc acid reduction 256
476,481
624 384
133
(621)''
-------
Federal Register / Vol. 44, No. 244 / Tuesday, December 18, 1979 / Proposed Rules
75045
I. LIST OF APPROVED TEST PROCEDURES (Cont.)
Parameter aid units
Method
1974
EPA
Methods
Reference (Page NOB.)
14th W. Part 31
Standard 1975 U9GS
Otter
Methods
Methods Methods
Radiological
212. Alpha—total, pCi per
liter
213. Alpha—countin} error,
pCi per liter
214. Beta—total, pCi par
liter
215, Beta—oounting error,
pCi per liter
216. a) tediim—total, pd
per liter
b) 22«n», pCi per
liter
Residue
217. Total, milligrams per
liter
218. Total dissolved (fil-
terable) , milligram
per liter
219. Total suspended (non-
filterable), milli-
gram per liter
220. Settleable, mllU-
llters per liter or
milligram per liter
221. Total volatile, •dill-'
grans per liter
Proportional or scintillation
Proportional or scintillation
counter
Proportional counter
Proportional counter
Proportional counter
Scintillation counter
Gravimetric, 103 to 105"C
270
Glass fiber filtration, 180*C 266
Glass fiber filtration, 103 to 105*0 268
Vblunetric or gravimetric
Gravimetric, 550*C
272
648
648
648
648
661
667
91
92
94
95
95
591 (75)10 (78)2*
594
606
661
(79)
10
601 {75)10 (78)2t
(79)
10
(81)
10
(537)
26
-------
75046
Federal Register / Vol. 44, No. 244 / Tuesday, December 18, 1979 / Proposed Rules
TABLE I. UCT CT MTBCNED TEST PH3OMJWS (Cont.)
Parameter and units
222.
223.
224.
225.
226.
227.
228.
Specific conductance,
mlciuiif m6 per centi~ '
meter at 25*C
Sulfate (as SOj)
milligram per liter
Sulflde (as S), Milli-
grams per liter
Sulfite (as S03),
milligrams per liter
Surfactants, milli-
grams per liter
Tenperature, degrees C
Turbidity, NIU
1974
EPA
Method Methods
ftieatstone bridge conaucUnetry 275
Gravimetric;
turbidinetrici or 277
automted colocimetric (barton 279
chloranilata)
tttrlmetric— iodine for levels greater 284
than 1 mg per liter)
Methylene blue photometric
TltrlnBtric, lodlne-iodate 285
ODlorinetric (Methylene blue) 157
Calibrated glass or electromatric 286
thsuiuiieter
Hephelcnetrlc 295
Reference (Page Noe.)
14th Hi. Part 31 Other
Standard 1975 USGS . approved
Methods ASW Methods Methods
71 120 148 (606)2
493 424 - (624 ?
496 425 - (623) 2
- - - -
505 - 154
503
508 435
600 494 (ID22
125 - (3D25
132 223 156
-------
Federal Register / Vol. 44. No. 244 / Tuesday, December 18. 1979 / Proposed Rules 75047
Footnotes:
1. All page references for USGS methods unless otherwise noted are to Brown, E., Skougstad, N.W.,
and Fishman, M.J., "Methods for Collection and Analysis of Water Sanples for Dissolved Minerals
and Gases, "U.S. Geological Survey Techniques of Water-Resources Inv., book 5 ch. Al, (1970)."
2. EPA comparable method may be found on indicated page of "Official Methods of Analysis of the
Association of Official Analytical Chemists" methods manual, 12th ed. (1975).
3. Manual distillation is not required if comparability data on representative effluent samples
are on coipany file to show that this preliminary distillation step is not necessary; however,
manual distillation will be required to resolve any controversies.
4. The method used must be specified.
5. The 5 tube MPN is used.
6. Slack, K.V. and others, "Methods for Collection and Analysis of Aquatic Biological and Micro-
biological Samples "U.S. Geological Survey Techniques of Water-Resource Inv., book 5, ch A4 (1973)."
7. Since the membrane filter technique usually yields low and variable recovery from chlorinated
wastewaters, the MPN method will be required to resolve any controversies.
8. The_chloromine-T oxidation-colorraetric procedure for benzidine is available from the Environmental
Monitoring and Support Laboratory, U.S. Environmental Protection Agency, Cincinnati.Ohio 45268
9. American National Standard on Photographic Processing Effluents, Apr. 2, 1975. Available
from ANSI, 1430 Broadway, New York, N.Y. 10018.
10. Fishman, M.J. and Brown, Eugene, "Selected Methods of the U.S. Geological Survey for Analysis
of Wastewaters," (1976) open-file report 76-177.
11. Procedures for pentachlorophenol, chlorinated organic compounds, and pesticides can be obtained
from the Environmental Monitoring and Support Laboratory, U.S. Environmental Protection Agency,
Cincinnati, Ohio 45268.
12. Color method (ADMI procedure) available fron Environmental Monitoring and Support Laboratory, U.S.
Environmental Protection Agency, Cincinnati, Ohio 45268.
13. For samples suspected of having thiocyanate interference, magnesium chloride is used as the
digestion catalyst. In the approved test procedure for cyanides, the recommended catalysts are
replaced with 20 ml of a solution of 510 g/1 magnesium chloride (MgCl_•6H 0). This substitution
will eliminate thiocyanate interference for both total cyanide and cyanide amenable to chlori-
nation measurements.
14. For the determination of total metals the sample is not filtered before processinq. Because
vigorous digestion procedures may result in a loss of certain metals through precipation, a
less vigorous treatment is recommended as given on p. 83 (4.1.4) of "Methods for Chemical
Analysis of Water and Wastes" (1974). In those instances where a more vigorous digestion
is desired the procedure on p. 82 (4.1.3) should be followed. For the measurement of the
noble metal series (gold, iridium, osmium, palladium, platinum, rhodium and ruthenium), an
aqua regia digestion is to be substituted as follows: Transfer a representative aliquot
of the well-mixed sample to a Griffin beaker and add 3 ml of concentrated redistilled HNO .
Place the beaker on a steam bath and evaporate to dryness. Cool the beaker and cautiously
add a 5 ml portion of aqua regia. (Aqua regia is prepared immediately before use by carefully
adding 3 volumes of concentrated HC1 to one volume of concentrated HNO,.) Cover the beaker
with a watch glass and return to the steam bath. Continue heating the covered beaker for
50 rain. Remove cover and evaporate to dryness. Cool and take up the residue in a small
quantity of 1:1 HC1. Wash down the beaker walls and watch glass with distilled water and
filter the sample to remove silicates and other insoluble material that could clog the
atomizer. Adjust the volume to some predetermined value based on the expected metal
concentration. The sample is now ready for analysis.
-------
75048 Federal Register / Vol. 44. No. 244 / Tuesday, December 18. 1979 / Proposed Rules
15. As the various furnace devices (flameless AA) are essentially atonic absorption techniques,
they are considered to be approved test methods. Methods of standard addition are to be
followed as noted in p. 78 of "Methods for Chemical Analysis of Water and Wastes." 1974
16. Dissolved metals are defined as those constLtutuents which will pass through a 0.45 jsn
membrane filter. A prefiltration is permissible bo free the sample from larger suspended
solids. Filter the sample as scon as practical after collection using the first 50 to 100 ml
to rinse the filter flask. (Glass or plastic filtering apparatus are reccrnnended to avoid
possible contamination.) Discard the portion used to rinse the flask and collect the required
volume of filtrate. Acidify the filtrate with 1:1 redistilled UNO, to a pH or 2. Normally,
3 ml of (1:1) acid per liter should be sufficient to preserve the samples.
17. See "Atonic Absorption Newsletter," vol. 13, 75 (1974). Available from Perkin-Elmer Corp.,
MainAve., Norwalk, Conn. 06852
18. Method available from Environmental Monitoring and Support laboratory, U.S. Environmental
Protection Agency, Cincinnati, Ohio 45263
19. Recfrntvended methods for the analysis of silver in industrial wastewaters at concentrations
of 1 mg/1 and above are inadequate where silver exists as an inorganic halide. Silver halides
such as the brotd.de and chloride are relatively insoluble in reagents such as nitric acid
but are readily soluble in an aqueous buffer of sodium thiosulfate and sodium hydroxide to a
pH of 12. Therefore, for levels of silver above 1 mg/1 20 ml of sample should be diluted
to 100 ml by adding 40 ml each of 2M Na 5,0., and 2M NaOH. Standards should be prepared in the
same manner. For levels of silver below I ffig/1 the recomended method is satisfactory.
20. An automated hydrazine reduction method is available fron the Environmental Monitoring and
Support Laboratory, U.S. Environmental Protection Agency, Cincinnati, Ohio 45268.
21. A number of such systems manufactured by various cotpanies are considered to be comparable
in their performance. In addition, another technique, based on conbustion-methane detection
is also acceptable.
22. Goerlitz, D., Brown, E., "Methods for Analysis of Organic Substances in Water"! U.S.
Geological Survey Techniques of Water-Resources Inb., book 5, ch. A3 (1972)
23, R.F, Addison and E.G. Ackman, "Direct Determination of Elemental Phosphorus by Gas-Liquid
Chranatography," "Journal of Chromatography," vol. 47, No. 3, pp. 421-426, 1970.
24. The method found on p. 75 measures only the dissolved portion while the method on p. 78
measures only suspended. Therefore, the 2 results must be added together to obtain "total".
25. Stevens, H.H., Fick, J.F., and Snoot, G.F., "Water Temperature - Influential Factors, Field
Measurement and Data Presentation; U.S. Geological Survey Techniques of Water Resources
Inv., book 1 (1975)."
26. EPA interim methods for analysis of organics in municipal and industrial wastewater by GC/MS
purge and trap (Method 624 and methylene chloride extraction (Method 625) procedures are
available from the Enyironnental Monitoring and Support Laboratory, O.S.E.P.A., Cincinnati,
Ohio, 45268. Direct Aqueous injection is to be used in these GC/MS procedures for all compounds
that exceed 1000 micrograms per liter. Dichlorodifluoronethane should be analyzed by the
interim gas chranatographic method 601. For differentiation between iscmeric pairs anthracene
and phenanthrene, chrysena and benzo(a)anthracene, and benzo (b) fluoranthene and benzo
(k) fluoranthene use method 610 of polynuclear aromatic hydrocarbons. "Interim Method for
Benzidine and its Salts in Wastewater" is available frou the Environmental Monitoring and
Support Laboratory, U.S.E.P.A., Cincinnati, Ohio, 45268 (EMSL-CI).
27. The Inductively Coupled plasma Optical Emission Spectronetric Method (ICP) is available from
the Environmental Monitoring and Support Laboratory, IJ.S-E.P.A. Cincinnati, Ohio 45268
(EMSL-CI),
28. Method 507 for Carbonaceous Biochemical Oxygen Demand (BOD carbonaceous) is available fron
the Environmental Monitoring and Support Laboratory, U.S.E.P.A. Cincinnati, Ohio 45268
(EM3L-CI),
-------
Federal Register / Vol. 44, No. 244 / Tuesday. December 18. 1979 / Proposed Rules 75049
29. Inert gas purge, followed by gas chromatography with halide specific detection
(interim method 601), available from EMSL-CI.
30. Inert gas purge followed by gas chronatography and photoionization detection
(interim method 602), available from EMSL-CI.
31. Inert gas purge followed by gas chrctnatographic separation and detection with flame
ionization detector (interim method 603), available from EMSL-CI.
32. Methylene chloride extraction, followed by gas chromatography with flame ionization or
electron capture detection (interim method 604), available from EMSL-CI.
33. Chloroform extraction followed by concentration and high performance liquid chromatography
(HPLC) with electrochemical detection (interim method 605), available from EMSL-CI.
34. Methylene chloride extraction followed by gas chronatography with flame ionization or
electron capture detection (interim method 606), available from EMSL-CI.
35. Methylene chloride extraction followed by gas chronatography with nitrogen-phosphorous or
reductive Hall detectors (interim method 607), available from EMSL-CI.
36. Methylene chloride extraction followed by gas chronatography with electron capture or
halogen specific detection (interim method 608), available fron EMSL-CI.
37. Methylene chloride extraction followed by exchange to toluene, gas chromatography with
flame ionization detection (interim method 609), available fron EMSL-CI.
38. Methylene chloride extraction followed by HPIC with fluoresence or UV detection; or gas
chronatography (interim method 610), available from EMSL-CI.
39. Methylene chloride extraction followed by gas chromatography with halogen-specific
detector (interim method 611), available froti EMSL-CI.
40. Methylene chloride extraction followed by concentration, gas chromatography with electron
capture detection (interim method 612), available from EMSL-CI.
41. Methylene chloride extraction followed by transfer to hexane and capillary column gas
chromatography/faass spectonetry with electron impact ionization (interim method 613),
available from EMSL-CI.
42. Microbiological Methods for Monitoring the Environment (December 1978) available for the
Environmental Monitoring and Support Laboratory U.S. E.P.A. Cincinnati, Ohio 45268.
-------
75050
Federal Register / Vol. 44,'No. 244 / Tuesday, December 18, 1979 / Proposed Rules
TABLE
Measurement
1
2
3
4-7
8
9
10
11
12
13
14
15
16
17-18
19
20
21
22
23&92
40-41
Acidity
Alkalinity
Armenia
BACTERIA
Coliform, fecal
and total
Fecal streptococci
Biochemical oxygen demand
Biochemical oxygen
demand Carbonaceous
Bromide
Chemical oxygen
demand
Chloride
Chlorinated organic
compounds
Chlorine, total
residual
Color
Cyanide, total and
amenable to chlorination
Dissolved oxygen
Probe
Winkler
Fluoride
Hardness
Hydrogen ion (pH)
Kjeldahl and organic nitrogen
hETAIS6
Chromium VI
II. CCNBUNEPS, PRESETOATICN,
Container
P.G
P.G
P.G
P,G
P.G
P,G
R,G
P.G
P.G
P,G
G, teflon-lined
cap
P.G
P.G
P.G
P.G
G bottle I top
G bottle & top
P
P.G
P.G
P.G
P.G
Atd HOUMJG TIMES
Preservative
Cool, 4"C
Cool, 4°C
Cool, 4°C
H-9O. to pH<2
Cool, 4'C h
0.008% Ha^SjO,
Cool, 4°C .
0.008% MajSjOj
Cool, 4'C
Cool, 4°C
None required
Cool, 4*C
HjSO^ to pH<2
None Required
Cool, 4°C h
0.008% NajSjO,
Determined on-site
Cool, 4°C
Cool, 4°C
NaOH to PIM2,,
0.008% Na2S20^
Determine on site
Fix on site
None Required
HN03 to pH<2
Determine on site
Cool, 4°C
H-SO. to pH<2
Cool, 4°C
Maximum ,
Holding Time
14 days
14 days
28 days
6 hours
6 hours
48 hours
48 hours
28 days
28 days
28 days
7 days (until extraction)
30 days (after extraction)
2 hours
48 hours
14 days
1 hour
8 hours
28 days
6 months
2 hours
28 days
48 hours
-------
Federal Register / Vol. 44, No. 244 / Tuesday, December 18, 1979 / Proposed Rules
75051
TABLE II. COtnWNERS, PRESERVATION, AMD BODING TIMES (cont.)
Measurement3 Container
58-59
24-87
88
88 (a)1
89
90
91
93-206
Mercury
Mstals
except above
Nitrate
Nitrate-nitrite
Nitrite
Oil and Grease
Organic Carbon
ORWNIC COMPOUNDSf
P,G
P,G
P,C
P,G
P.G
G
P.G
Extractables (including G, teflon-lined
phtha2at.es, nitrosamines cap
organochlorine pesticides,
PCB's, nitroaromatics,
isophorone, polynuclear aromatic
hydrocarbons, haloethers,
chlorijiated hydrocarbons and TCDD)
207
208
209
210
211
Extractables (phenols)
Purgeables (Halocarbons and
Aroma tics)
Purgeables (Acrolein and
Acrylonitrite)
Orthqphosphate
Pesticides
Phenols
Phosphorus (elemental)
Phos^.iorus, total
G, teflon-lined
cap
G, teflon-lined
septum
G, teflon-lined
septum
P,G
G, teflon-lined
cap
P,G
G
P,G
Preservative
HNOjto pH<2
0.05% K2Cr207
HNOj to pH-'2
Cool, 4°c
Cool, 4°C
Cool, 4°C
Cool, 4°C
H.SO. to pH'2
Cool, 4°C
H SO to pfl<-2
Cool, 4°C h
0.008% Na-^Oj
Cool, 4°C
HjSO .to pH<2
0.008% Na2S2Oj
Cool, 4°C .
0.008% NajS-jOj
Cool, 4°C .
0.008% Na2S20;J
Filter on site
Cool, 4»C
Cool, 4°C .
0.008% Na2S2Oj
Cool, 4°C
H S<^ to pli<2
Cool, 4"C
Cool, 4«C
Maximvn .
Holding Time
28 days
6 months
48 hours
28 dayg
48 hours
28 days
28 days
7 days (until
30 days (after
7 days (until
JO days (after
14 days
3 days
48 hours
7 days (until
30 days (after
28 days
48 hours
28 days
extraction)
extr-.i--j.on)
extraction)
extrai-t-ion)
extraction)
extraction)
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75052
Federal Register / Vol. 44, No. 244 / Tuesday, December 18, 1979 / Proposed Rules
TABLE
Measttreinent
212-216
217
218
219
220
221
73
222
223
224
225
226
227
228
RADIOUOGICAL
Alpha, Beta and radiiin
Residue, total
Residue, Filterable
Residue, nonfilterable
Residue, settleable
Residue, volatile
Silica
Specific conductance
Sulfate
Sulfide
Sulfibe
Surfactants
Temperature
Turbidity
11. CONTAINERS,
Container
P,G
P,G
P,G
P,G
P,G
P,G
P
P,G
P,G
P,G
P,G
P,G
P,G
P,G
PRESERVATION, AND HOU)IH3 TIMES (oont.)
Preservative
HNO3 to pH<2
Cool, 4°C
Cool, 4°C
Cool, 4°C
Cool, 4°C
Cool, 4°C
Cool, 4°C
Cool, 4°C
Cool, 4°C
Cool, 4°C
Zinc flcetate
Cool, 4°C
Cool, 4°c
Determine on site
Cool, 4°C
Maximum -,
Holding Time
6 months
14 days
14 days
7 days
7 days
7 days
28 days
28 days
28 days
28 days
48 hours
48 hours
imnediately
48 hours
a Parameter numbers refer to Table I.
b Polyethylene (P) or Glaes (G).
c Sample preservation should be performed immediately upon sample
collection. For composite samples each aliquot should be preserved
at the time of collection. When use of an automatic sampler makes
impossible to preserve each aliquot, then samples may be
preserved by maintaining at 4°C until compositing and
sample splitting is completed.
d Samples should be analyzed as soon as possible after collection.
•n» times listed are the maximum tines that samples may be held
before analysis and still considered valid. Samples may be held
for longer periods only if the permittee, or monitoring laboratory,
has data on file to show that the specific types of samples under
study are stable for the longer time.
Some samples may not be stable for the maximum time period given in
the table. A permittee, or monitoring laboratory, is obligated to
hold the sample for a shorter time if knowledge exists to show this
is necessary to maintain sample stability.
e Samples should be filtered immediately en-site before adding preser-
vative for dissolved metals.
f Guidance applies to samples to be analyzed by GC, 1C, or GC/MS for
specific organic compounds.
g This parameter not listed in Table I.
h Should only be uaed In the presence of residual chlorine,
i Not available in Table I.
BILLING CODE 15O5-01-C
i US GOVERNMENT PRINTING OFFICE 1981 -757-064/0214
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