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1 1 1
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CifiS
/ v>4
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OTAL SAMPLES TAKCN
AYS EXCEEDING MAXIMUM
G MAX. VIOL
i_ i j
'til
1 1^-
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OUP PUNCH l» •»! '
River 'Available Cap'
kn/day
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HIGH
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\
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1 1 1 1 1 1
1 1 1 1 1
UMKB DAYS HEPODTINO
OTAI SAMPLES TAKEN
AYS (XCECOING MAXIMUM
.p 1
1
1
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DUP PUNCH ll> "1
Phosphorus - Total
mo/1
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C.. '3
VE RAGC
AXIMUM
HIGH
y
1 1 1
1 1 1 1
lilt
I 1 1 1
LOW
.5 )
(3,. ,3
1
L. . .1 -
UMIEK DAYS MPOHTINC
OTAL SAMPLES TAKEN
AYS EXCEEDING MAXIMUM
,C MA. V«X | , ,
1
, 1
DUP PUNCH III 114
s
10
IS
20
5
0
P£fiSONAUY EXAMINED AND AM FAMILIAR WITH THf INfOHMATlON SUBMITTED IN THIS DOCUMENT AND All ATTACHMENTS AND
e
t
-------
DOW CHEMICAL USA
MICHIGAN DIVISION — MIDLAND PLANT
NON-CONVENTIOMAL/TOXIC POLLUTANTS — OUTFALL 031
PERMIT 0MI 0000868
TABLE 2
Monitoring Results - September, 1985
Phenol
2,4-Dichloropheno xy-
acetic acid
Bis(2-chloroethyl)ether
Chloroform
2,3,7,8-Tetrachloro-
dibenzo-p-dioxin
1,1,2,2-Tetrachloroethane
Tetrachloroethylene
1,1,2-Trichloroethane
Pentachlorophenol
1,3-Dichlorobenzene
1,4-Dichorobenzene
1,2,4-Trichlorobenzene
Methylene Chloride
2-Chlorophenol
2,4-Dichlorophenol
Naphthalene
1,1,1-Trichloroethane
. Bromoform
Chlorobenzene
Carbon Tetrachloride
2,4,6-Trichlorophenol
1,2-Dichlorobenzene
Acrylonitrile
Concentration
A g/liter
1
ND(1)
ND(1)
7
5 ppq*
4
5
ND(3)
- ND(2)
.08
0.9
3
16
NDC0.8)
2
-0.4 -
6
ND(4)
ND(2)
ND(3)
3
0.9
ND(1)
Sample Concentration Sample
Date ^g/liter Date
9/03/85
9/03/85
9/03/85
9/03/85
8/21/85
9/03/85
9/03/85
9/03/85
9/03/85
9/03/84
9/03/85
9/03/85
9/03/85
9/03/85
9/03/85
9/03/85
9/03/85
9/03/85
9/03/85
9/03/85
9/03/85
9/03/85
9/03/85
2
ND(1)
1
4
4 ppq*
6
7
ND(2)
ND(2)
2
1
5
30
ND(0.8)
ND(1)
0.6
5
9
ND(1)
ND(1)
ND(2)
ND(.7)
ND(3)
9/16/85
9/16/85
9/16/85
9/16/85
9/04/35
9/16/85
9/16/85
9/16/85
9/16/85
9/16/85
9/16/85
9/16/85
9/16/85
9/16/85
9/16/85
9/16/85
9/16/85
9/16/85
9/16/85
9/16/85
9/16/85
9/16/85
9/16/85
ND = Not Detected
() = Lowest Detection Limit
»
= Concentration Reported as Part Per Quadrillion
-------
c
/:
DOW CHEMICAL USA
MICHIGAN DIVISION — MIDLAND PLANT
NON-CONVENTIONAL/TOXIC POLLUTANTS — OUTFALL 031
PERMIT *MI 0000868
TABLE 1
Monitoring Results - September, 1985
Phenol
2,4-Dlchlorophenoxyacetic
acid
Bis(2-chloroethyl) ether
Chloroform
2,3,7,8-Tetrachloro-
dibenzo-p-dioxin
1 ,1 ,2,2-Tstrachloroethane
Tetrachloroethylene
1 ,1 ,2-Trichloroethane
Pentachlorophenol
1 ,3-Dichlorobenzene
1 ,4-Dichorobenzene
1 ,2,4-Trichlorobenzene
Methylene Chloride
2-Chloro phenol
2 , 4-Di chloropheno 1
Naphthalene
1,1, 1-Trichloroethane
Bromoform
Chlorobenzene
Carbon Tetrachloride
2,4 ,6-Trichlorophenol
1 ,2-Dichlorobenzene
Acrylonitrile
Monthly
Average
(Ibs/day)
.3
.030*
—
1.3
0.6x10
1.1
1.4
—
—
.3
.2
.9
5.2
—
—
.1
1.3
—
—
—
—
Daily
Max imum
(Ibs/day)
.4
.052*
.2
1.8
1.1x10~6
1.3
1.5
—
—
.4
.2
1.1
6.4
—
.3
.1
1.5
1.9
—
—
.8
.2
Monthly Daily
Average Maximum
Jfrg/l) >g/l)
2
ND(1)
ND(1)
6
5 ppq
5
6
ND(2)
ND(2)
V.4
1
4
23
NDC0.8)
ND(1)
0.5
6
ND(4)
ND(1)
ND(1)
ND(2)
ND(.7>
ND(1)
2
ND(1)
1
7
5 ppq
6
7
ND(3)
ND(2)
2
1
5
30
ND(.8)
2
0.6
6
9
ND(2)
ND(3)
6
0.9
ND(3)
Mass discharge measured at 031 a
-------
*«DOH CHEMICAL COMPANY
MIDLAND DIV
MIDLAND
~"j ll
J L
569C • —
DOW CHEMICAL COMPANY
OUTFALL : 031
PROC.WASTES TO TITTABAHASSEE*R. 031
PERMIT EXPIRATIONJ 10/79
Dale form was
punted
IAM|
ME
ITS
i
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I
4
5
5
7
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NUMBER DAYS REPORTING
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1
PUP PUNCH I'i »tl
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DUP PUNCH IIS Ml
1 CftHfV IJNDEfi PfNALTV OF (.AW THAT
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INDIVIDUALS IMfV
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UMBER DAYS REPORTING
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UMBER DAYS REPORTING
OTAL SAMPLES TAKEN
C MAX VIOL
i
l
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OUP PUNCH IIS •«!
Consumers Power ,
Intake cfs
. - -
1
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c
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1
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1
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UMBER DAYS REPORTING
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OTAL. SAMPLES TAKEN \^ t\
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f 1 1 L 1
OUP PUNCH US Ml
Consumers Power
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i
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C
t
f
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AXIMUM ,
1
1
1
1
1
1
1 i ^
1 1 -~
1
L, 1 J
UMiCR OATS REPORTING | 3 1 L
OTAL SAMPLES TAKEN
C MAX VKX
.,
1 1
_li^
1 i
OUP PUNCH in »ii
S
10
5
0
5
0
UY EXAMINED AND AM FAMILIAR WITH THE INFORMATION SUBMITTED IN THIS DOCUMENT AND ALl ATTACHMENTS ANO
EDIATELY HESPONSIUlE FOR (3l)!AININCj THE INFOHMAMON. BELIEVE THAT THE INFORMATION IS THUC. ACCURATE. AND
irjn iiDiNG IDE POSSIblLiry Of FINE ANO IMPfll^ONMbNT
lr -
o
-------
DOW CHEMICAL USA
MICHIGAN DIVISION — MIDLAND PLANT
NON-CONVENTIONAL/TOXIC POLLUTANTS — OUTFALL 031
PERMIT 0MI 0000868
. TABLE 1
Monitoring Results - April, 1985
Phenol
2,4-Dichlorophenoxyacetic
acid
Bis(2-chloroethyl)ether
Chloroform
2,3,7,8-Tetrachloro-
dibenzo-p-dioxin
1,1,2,2-Tetrachloroethane
Tetrachloroethylene
1,1,2-Trichloroethane
Pentachlorophenol
1,3-Dichlorobenzene
1,4-Dichorobenzene
1,2,4-Trichlorobenzene
Methylene Chloride
2-Chlorophenol
2,4-Dichlorophenol
Naphthalene
1,1,1-Trichloroethane
Bromoform
Chlorobenzene
Carbon Tetrachloride
2,4,6-Trichlorophenol
1,2-Dichlorobenzene
Acrylonitrile
Monthly
Average
(Ibs/day)
—
.001*
—
3.6
4.0x10~6
—
—
—
3.4
—
—
—
—
—
_
—
4.2
—
—
3.4
—
—
—
Daily
Maximum
(Ibs/day)
.2
.001»
.6
3.7
4.8x10~6
1.6
2.2
—
5.2
.4
.4
.8
2.0
—
.4
—
4.7
5.4
—
5.2
1.0
.4
.5
Monthly -
Average
(ug/1)
ND(0.6)
ND(2)
ND(0.5)
16
19PPQ
ND(7)
ND(8)
ND(7)
15
NDC0.6)
ND(0.6)
ND(0.8)
ND(2)
ND(0.7)
ND(1)
ND(0.2)
19
ND(6)
ND(5)
15
ND(2)
ND(0.6)
ND(2)
Daily
Maximum
(ug/1)
1
24
3
17
24ppq
8
11
ND(7)
21
2
.2
4
8
ND(.7)
2
ND(.2)
19
22
MD(5)
21
5
2
2
Mass discharge measured at 031a
-------
DOW CHEMICAL USA
MICHIGAN DIVISION — MIDLAND PLANT
NON-CONVENTIONAL/TOXIC POLLUTANTS — OUTFALL 031
PERMIT 0MI 0000868
. TABLE 2
Monitoring Results - April, 1985
Phenol
2,4-Dichlorophenoxy-
acetic acid
Bis(2-chloroethyl)ether
Chloroform
2,3,7,8-Tetrachloro-
dibenzo-p-dioxin
1,1,2,2-Tetrachloroethane
Tetrachloroethylene
1,1,2-Trichloroethane
Pentachlorophenol
1,3-Dichlorobenzene
1,4-Dichorobenzene
1,2,4-Trichlorobenzene
Methylene Chloride
2-Chlorophenol
2,4-Dichlorophenol
Naphthalene
1,1,1-Trichloroethane
Bromoform
Chlorobenzene
Carbon Tetrachloride
2,4,6-Trichlorophenol
1,2-Dichlorobenzene
Acrylonitrile
Concentration Sample Concentration
ug/liter Date ug/liter
ND(0.6)
ND(2)
MD(0.5)
15
24 ppq*
ND(7)
ND(8)
ND(7)
- 21
ND(0.6)
ND(0.6)
ND(O.S)
8
ND(0.6)
ND(1)
ND(0.2)-
19
22
ND(4)
21
ND(2)
NDC0.6)
2
4/1/85
4/1/85
1/1/85
4/1/85
3/25/85
4/01/85
V01/85
4/01/85
4/01/85
4/01/85
4/01/85
4/01/85
4/01/85
4/01/85
4/01/85
4/01/85
4/01/85
4/01/85
4/01/85
4/01/85
4/01/85
4/01/85
4/01/85
1
24'
3
17
13 ppq*
8
11
MD(7)
8
2
2
4
ND(2)
ND(0.7)
2
ND(0.2)
18
ND(6)
ND(5)
8
5
2
ND(2)
Sample
Date
4/15/85
4/15/85
4/15/85
4/15/85
4/02/85
4/15/85
4/15/85
4/15/85
4/15/85
4/15/85
4/15/85
4/15/85
4/15/85
4/15/85
4/15/85
4/15/85
4/15/85
4/15/85
4/15/85
4/15/85
4/15/85
4/15/85
4/15/85
ND = Not Detected
() = Lowest Detection Limit
= Concentration Reported as Part Per Quadrillion
-------
OW CMEMCAL COMPANY
1DLAND DIV
C'tIM NUWHl^~l rrihu.l NUMMIA j ft>.1lAU WUMbtiT
;6Q009 J LllIC>O.QQ8.6.flJ 156013.8
MONTHLY OPERATING REPORT FOR
mis is YOUII MONTHLY mroni roni.t f on
SEE MCVEIISE SIDE FOR RETURN MAIL
Pkjic cumplcic jort luUnil I wo copiei ol Urn luim
»i Hit end ol i-ach monih. Thil ICJKJII mull icjch oui
L«miny office by ihc lOihol the month.
PART 1 - RETURN TO DEtT OF NATURAL RESOURCES
* «4>O «.. ( tl
411) HVO
DOH CHEMICAL COMPANY
OUTFALL' I 031
PROC.HASTES'TO TITTABAHASSEE. R. 031
PERH1T
10/79
Dale loim w»»
CM.
>.1./1.Q/_25
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AXIMUM
HIGH
LOW
1
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_i_i£j!£jl
i i i i j
i i i i_i
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a
£
L
it-fl
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OTAL SAMPLES TAKEN
ATS EXCEEDING MAXIMUM
VC MAX. VIOL 111
River Flow
cfs
i.'
, '
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v
f
c
,
(
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V
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l
DAILY AVG
7^.0
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IUMU(R DATS Bti'OH
HIGH
LOW
1
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ING
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r^
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,
-------
1,
COHPAUY
KJDLAfiD DIV
r.t 140640
MONTHLY OPERATING REPORT FOR
1HIS li YOUII MUU1IHV III I'OIII f OH'-' I OH
SEE MEVCIISC SIOC fOfl nCTUMU MAIL
Plt-jic c«ini|ilci« jnd luluinl Iwo cuf'd ol llin luim
.1 ila tod (.1 c^ch monlh. Tim u|>oil mull u-ch out
/Jt>,,l IV-
02
OOW CHEMICAL COMPANY
OUTFALL I 031
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H CHEMICAL COMPANY
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PART 1 - RETURN 70 DEPT OF NATURAL RESOURCES
Apr, I
1985T
n 4470
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OUTFALL I 031
PROC.HASTES TO TITTABAMASSEE'R. 031
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DOW CHEMICAL USA
MICHIGAN DIVISION — MIDLAND PLANT
o
NON-CONVENTIONAL/TOXIC POLLUTANTS — OUTFALL 031
PERMIT tfMI 0000868
TABLE 1
Monitoring Results - March, 1985
Phenol
2,4-Dichlorophenoxyacetic
acid
Bis(2-chloroethyl)ether
Chloroform
2,3,7,8-Tetrachloro-
dibenzo-p-dioxin
1,1,2,2-Tetrachloroethane
Tetrachloroethylene
1,1,2-Trichloroethane
Pentachlorophenol
1,3-Dichlorobenzene
1,4-Dichorobenzene
1,2,4-Trichlorobenzene
Methylene Chloride
2-Chlorophenol
2,4-Dichlorophenol
Naphthalene
1,1,1-Trichloroethane
Bromoform
Chlorobenzene
Carbon Tetrachloride
2,4,6-Trichlorophenol
1,2-Dichlorobenzene
Acrylonitrile
Monthly
Average
(Ibs/day)
—
»,020
.3
2.4
6.1x10~6
—
—
—
^3.2
.2
.5
.3
—
—
—
—
3.3
2.9
— •
5.8
.5
.6
_«
Daily
Maximum
(Ibs/day)
—
».020
.5
4.8
10.2x10~6
1.4
1.6
.2
3.6
.3
.7
.6
.2
—
.6
—
4.3
4.2
.2
6.6
.8
.7
__
Monthly Daily
Average Maximum
(ug/D (ug/1)
ND(0.8)
35
3
21
28ppq
ND(7)
ND(7)
ND(7)
23
2
4
4
ND(8)
ND(0.7)
ND(1)
ND(0.3)
19
14
ND(6)
32
6
3
ND(2)
—
40
3
28
44ppq
6
7
1
25
2
6
4
.8
—
4
—
27
18
1
42
6
3
__
Mass discharge measured at 031a
-------
DOW CHEMICAL USA
MICHIGAN DIVISION — MIDLAND PLANT
NON-CONVENTIONAL/TOXIC POLLUTANTS — OUTFALL 031
PERMIT ffMI 0000868
TABLE 2
Monitoring Results March, 1985
Phenol
2,4-Dichlorophenoxy
acetic acid
Bis(2-chloroethyl)ether
Chloroform
2,3i7,8-Tetrachloro-
dibenzo-p-dioxin
1,1,2,2-Tetrachloroethane
Tetrachloroethylene
1,1,2-Trichloroethane
Pentachlorophenol
1,3-Dichlorobenzene
1,4-dichorobenzene
1,2,4-Trichlorobenzene
Methylene Chloride
2-Chlorophenol
2,4-Dichlorophenol
Napthalene
1,1,1-Trichloroethane
Bromoform
Chlorobenzene
Carbon Tetrachloride
2,4,6-Trichlorophenol
1,2-Dichlorobenzene
Acrylonitrile
Concentration
Pg/liter
ND(0.7)
no
3
28
12ppq*
ND(7)
ND(10)
ND(7)
22
2
6
3
ND(8)
ND(0.7)
ND(1.2)
ND(0.3)
27
10
ND(6)
42
6
ND(0.6)
ND(2)
Sample Concentration
Date Ug/iiter
2/27/85
2/27/85
2/27/85
3/4/85
2/21/85
3/4/85
3/4/85
3/4/85
2/27/85
2/27/85
2/27/85
2/27/85
3/4/85
2/27/85
2/27/85
2/27/85
3/4/85
3/4/85
3/4/85
3/4/85
2/27/85
2/27/85
3/4/85
NDC0.8)
36
3
13
44ppq»
6
7
1
23
2
4
4
0.8
ND(0.7)
14
ND(0.3)
10
18
1
22
5
3
NDC.7)
Sample
Date
3/4/85
3/4/85
3/4/85
3/18/85
3/5/85
3/18/85
3/18/85
3/18/85
3/4/85
3/4/85
3/4/85
3/4/85
3/8/85
3/4/85
3/4/85
3/4/85
3/18/85
3/18/85
3/18/85
3/18/85
3/4/85
3/4/85
3/18/85
ND = Not Detected
() = Lowest Detection Limit
-------
Capillary Column GC/HRMS Operating Parameters
Section C: Methods Section
GC Parameters:
22 m glass capillary column (WCOT) coated with SE-30.
Injection port temperature 260°C.
Column temperature 80°C.
The column temperature was manually programmed (34°C/min) to
270°C exactly six minutes after injection of sample. J
GC transfer line into MS ion source was maintained at 255°C.
The GC/MS retention time of 2,3,7,8-TCDD was 14 min, 30 sec, ±
15 sec. The retention time was stable and reproducible during
daily operation but did change over a period of days.
MS Parameters:
Ion source temperature 240°C.
Variable acceleration voltage.
Electron energy 70 ev.
2 Ma filament emission.
Mass resoltuion 7,000-9,000.
Multiplier gain greater than 10 .
Multi-ion selection (MIS) technique, electric peak jumping mode.
Cl-TCDD integration rate 100 milliseconds.
Cl-TCDD integration rate 30 milliseconds.
Details of these analyses were as described in a report to you dated
20 December 1978 on this subject.
-------
Section C. Methods Section
Analysis of Environmental Samples for 2,3,7,8-TCDD
using High Resolution Capillary Column
Gas Chromatography Interfaced with
High Resolution Mass Spectrometry
-------
26) Using a slow stream of dry nitrogen, carefully concentrate
the benzene solution at room temperature tb a volume of 60 jui.
27) Using a 100 jul syringe, place the extract into a 3 mm id x 10 cm
glass tube that has been pre-sealed at the bottom.
23) Seal the open end of the glass tube with a torch.
29) Extract Is stored in freezer ur.ril it can'be analyzed by mass
spectrometry.
-------
26) Using a slow stream of dry nitrogen, carefully concentrate
the benzene solution at room temperature tb a volume of 60>ul.
27) Using a 100 jil syringe, place the extract into a 3 mm id x 10 cm
glass tube that has been pre-sealed at the bottom.
28) Seal the open end of the. glass tube with a torch.
29) Extract is stored in freezer ur.ril it can'-be analyzed by mass
spectrometry.
-------
until the aqueous layer is neutralized Cfizzing ceases).
Discard aqueous layer.
13) Prewash the drying column containing 10 cm anhydrous
with 25 jnl hexane. Discard washings. Place a Kuderna-Danish
apparatus C250 ml flask equipped with a 10 ml concentrator
tube) beneath the column as a receiver. Drain the hexane
layer from the separatory funnel into the column containing
the Na^CO-j. Rinse the separatory funnel with several ml hexane,
Allow ringings to drain into column. After the hexane fil-
ters through the Na^CO^ into the Kuderna-Danish concentrator,
vash. the column with 25 ml hexane. Collect washings in K-D.
14) Place a carborundun boiling chip into the K-D concentrator
and attach a 3"ball Snyder column. Using a .steam bath, con-
. centrate the hexane extract . to a volume of 3-4 ml.
15) Place a waste container beneath a column of activated alumina.
Pre-wet the column with, 1 ml hexane. By means -of a 9 inch
disposable Pasteur pipet, transfer the hexane extract from the
concentrator tube onto the alumina column.
16) After the last portion of hexane is removed from the tube and
placed on the column, .pour 3 ml CC1/ onto the concentrator tube.
17) Vnen the hexane drains into the NaSO^, pipet the CCl^ onto the
column.
18) Using the same technique, continue eluting the column with an
additional 3 ml CCl^ followed by A ml CH C12. Collect the
eluant into a 12 ml distillation receiver.
19) Place a carborundum boiling chip into the receiver, add a micro
Snyder column and concentrate the Cl^C^ eluant to a volume of
approx. 100 fi~L by boiling gently on a hot water bath.
20) Add 2 ml hexane through the Snyder column and again concentrate
to approx. 100
21") Repeat step 20.
22) Pour 3 ml hexane into the receiver tube and repeat steps 15 — 19
23) Pour 2 ml benzene through the Snyder column. Using a boiling
vater bath, concentrate the benzene to a volume of 100 - 200 /il.
24) Repeat step 23.
25) Using a 100 >ul syringe, transfer the benzene solution into a •
2 ml chromaflex sample tube. Rinse the receiver tube with two
separate 200 jul portions of benzene. Boil the benzene each
time to rinse down the sides of the receiver tube. Transfer
the rinses to the sample tube.
-------
Extraction and Cleanup
1) Accurately wfcigh 10 g of tissue into a 100 ml round bottom
flask.
2) Add 20 ml ethanol to the flask. Using a 100>ul syringe,.
fortify the sample with AO ;ul of the working TCDD standard
(40/il - 20 ng - 2ppb). Add AO ml A5Z aqueous KOH and
place a 1 inch teflon coated stir bar into the flask.
(Note - For adipose samples only, add 15 ml distilled water
to the flask.)
3) Place a teflon sleeve on the ground glass joint of a water-
cooled Liebig condenser.. Attach the flask to the condenser.
Using a .heatingjmantle,'.heat* the. solution under gentle re-
flux with magnetic^ stir-ring lfor''2*5 hours.-
4) Allow the solution to cool and pour 25 ml of hexane through
the condenser into the flask.
5) Detach the flask from the condenser and pour the mixture into
a 250 ml separatory funnel. Rinse the flask with 10 ml ethanol
followed by 20 ml hexane.
6) Shake the separatory funnel vigorously for one minute, allow
the phases ~to separate, and drain the aqueous layer (bottom)
into a second 250 ml separatory funnel. Drain the hexane
layer into the original 100 ml flask.
7) Reextract the aqueous layer with three separate 25 ml portions
h/ixane. Combine all but the last hexane extract into the flask.
Allow the.last hexane extract to remain in the separatory funnel.
8) Pour the combined hexane extracts from the flask into the separa-
tory funnel containing the fourth extract. Rinse the flask with
two separate 5 ml portions ethanol followed by two separate 5 ml
portions hexane.
9) Add 25 ml IN KOH to the separatpry funnel, ana< shake vigorously
for one minute. Allow the phases to separate and discard the
basic wash..
10) Add 50 ml concentrated sulfuric acid to the separatory funnel,
shake with frequent venting of pressure for one minute. Allow
phases to separate fully and discard the sulfuric acid.
11. Wash hexane layer with three additional 50 ml portions of con-
centrated sulfuric acid. Discard the acid each time.
12. Pour 25 ml distilled water into the separatory funnel and
vash hexane with frequent venting of pressure. Allow layers
to separate and add'powdered NaoCO^ portion-wise with a spatula
-------
Apparatus
1) Chromatographic columns (alumina) - disposable Pasteur Pipet,
5 3/4 inches long (Scientific Products). Prepare column as
follows: Gently tamp a plug of glass vool into the bottom of
a 5 3/4 inch disposable Pasteur pipet. Pour Woelm neutral
alumina into the pipet while tapping the column with a pencil
until a height of.4.5 cm of alumina is packed into the column.
Top the alumina with 0.5 cm of anhydrous granular Na2S04. Pre-
wash. tKe column with 3 ml CH2C12. Allow the CH^C^ to drain
from tne column, then force the remaining CH2C12 from the
column,with, a stream of dry nitrogen. Place prepared columns
"in an oven set at 225°C. Store columns in the oven until
ready for use, .at least overnight. Remove only the columns
needed and place them in a dessicator over Drierite until they
have equilibrated to room temperature. . Use immediately.
2) Drying column - 11 mm id x 39 cm glass column equipped with
a 125 ml reservoir and teflon stopcock ^nd removable drip tip.
Prepare column as follows: Tamp a plug of glass wool into
the bottom of the column just above the stopcock. Pour anhy-
drous powdered sodium carbonate into the column with gentle
tapping until a height of 10 cm is obtained.
-------
Glassware
Separatory funnels (ground glass stopper and teflon stopcock) -
250 ml.
Pipers (Pasteur) disposable - Scientific Products,5' 3/4 inches
9 inches
Ctnndard wall pyrex glass tubing — O.D. 3mm
Colurm - 11 mm i.d. x 39 cm, equipped with teflon stopcock and
125 ml reservoir.
Crystallizing dish (used for hot water bath) - Scientific Products,
diaaeter 150 mm
height 75 mm
The following obtained from Kontes Glass Co.; Vineland, New Jersey:
Flasks,' round bottom (§" 14/20) - 100 ml
Condensers, Llebig (£ 14/20)
Tojdcrna ^ Danish, concentrator - 3 ball Snyder column, 250 ml
reservoir, 10 ml concentrator tube.
Micro Snyder column C$ 14/20)
Distillation receiver, graduated ($ 14/20) -= Capacity 12 ml.
Chronaflex Cample tube C^10/18) - Capacity 2 ml.
Funnels, powder (Jl4/20).
Stoppers ($ 14/20 and ~£ 10/18),
-------
Reagents
1) Sodium carbonate (anhydrous powder) - Mallinckrodt, AR
grade. Soxhlet extracted with methylene chloride for
2 hr. and dried at 200°C.
» t
2) Sodium sulfate - Mallinckrodt,.AR grade.. Soxhlet extracted
with methylene chloride for 2 hr. and dried at 200 °C.
3) Potassium hydroxide (pellets) - Mallinekrodt, AR grade.
A) Sulfuric acid - Mallinckrodt, AR grade.
5) Benzene, dichloromethane, hexane, ethyl alcohol - Mallinckrodt,
nanograde.
6) Carbon tetrachloride - Fisher, ACS grade (water .01% max.)
7) Distilled water - Free of organic impurities.
8) Alumina - Woelm neutral,.activity grade I (ICN Pharmacenticals,
26201 Miles Ave., Cleveland, OHIO 44128).
9) Drierite (anhydrous calcium sulfate) - Scientific Products.
-------
Standard
37
1) Internal Standard Solution - 2,3,7,8-ClJ -tetrachlorodibenzo-
p-dioxin (XCDD) (Eco-Control, Inc.; 71 Rogers Street; Cambridge,
Mass. 02U2)
Make all dilutions with nanograde benzene. Store all solutions
in freezer.
a) Stock-Solution - 1.5 jug/ml. Dissolve 200 ing of Cl37 -
chlorinated dioxin mixture containing exactly 0.150 mg
of 2.3,7,8-Cl37-TCDD (isotopic purity 982 Cl37) in 75
ml of boiling benzene in a 100 ml volumetric flask. Di-
lute the solution to volume with hot benzene and allow
the flask to equilibrate to room temperature. Dilute
to volume with, benzene, and mix.
5) • •WoTklfflg "Solution - 0.5 /ig/ml. Pipet 30 ml stock solution
into a 100 ml volumetric flask* Pipet 60 ml benzene into
'flask and mix. Mark volume.
-------
PROCEDURE FOR THE EXTRACTION AND CLEANUP
OF TISSUE SAMPLES FOR 2,3,7,8 - TETRACHLORODIBENZO-P-DIOXIN (TCDD)
EPA- Pesticides Monitoring
Bay St. Louis, Mississippi
-------
8. Add 100 ml of CH-C1. to the separatory funnel and repeat the
extraction. Again drain the CH Clj through a funnel containing
Na SO into the same A liter flask.
2 4
9. Repeat step 8.
10. Add 2 liters of pesticide quality CH-C^ to the same flask and
attach it to the soxhlet apparatus.
11. Heat the CH Cl- under reflux into the carbon for 16 hours.
22
12. Remove the round bottom flask from the soxhlet apparatus, add
a Snyder column and evaporate all of the CE^CIj from the flask.
13. Transfer the residue by rinsing with CH Cl_ into a 50 ml graduate
cylinder equipped with a ground glass stopper.
14. Build the volume to 50 ml with C^Cl-, place a glass stopper in
the cylinder and shake to ensure complete mixing.
15. Place 10 ml of this extract into a 100 ml round bottom flask.
Evaporate the CH Cl^ completely off by means of a steam bath-.
16. Proceed with steps 2 through 25 as described in the tissue
procedure.
-------
Procedure Used for the Extraction and Cleanup
Of Carbon Filtered Water Samples for TCDD
Note: To our knowledge, there are no existing extraction procedures
for removing 2,3,7,8-TCDD from carbon materials. No carbon
filters were received at our laboratory through which water
containing a known quantity of 2,3,7,8-TCDD was passed. There-
fore, neither the trapping efficiency on carbon nor the ex-
traction efficiency from carbon for TCDD are known nor could
they be ascertained by us due to the lack of proper controls.
The procedure used by us is one which generally extracts a
wide variety of organic compounds; however, there is no
guarantee that TCDD is extracted.
If TCDD is identified in the extract, we cannot verify that
it was quantitatively extracted. If TCDD does not appear in
the extract, it is possible that the TCDD is trapped on the
carbon and not efficiently extracted by this procedure.
1. Transfer the wet carbon filter material to the extractor tank of
a large scale soxhlet extractor.
2. Pour three liters of pesticide quality acetone into a A liter
round bottom flask and attach the flask to the soxhlet apparatus.
3. Heat the acetone under reflux into the carbon for 16 hours.
A. Remove the round bottom flask from the soxhlet apparatus. Add a
Snyder column and evaporate the acetone completely by means of
a steam both.
5. Transfer the remaining aqueous solution to a 1,000 ml separatory
funnel. Rinse the round bottom flask with two-100 ml portions
of CH Cl and transfer the rinsings to the separatory funnel.
6. Stopper the separatory funnel and shake vigorously for 1 minute.
7. Allow the layers to separate and drain the lower (CH^C^) layer
through a funnel containing Na-SO, into a A liter round bottom
flask.
-------
Procedure for the Extraction and Cleanup of Sludge Samples for TCDD
1. Weigh 10 g of sludge into a 100 ml round bottom flask.
2. Proceed with steps 2 through A in the tissue procedure.
3. Detach the flask from the condenser and decant the mixture
through a filter containing glass wool into a 250 ml separatory
funnel. Rinse the flask with 10 ml of ethanol followed by 20 ml
hexane and decant rinsings through the funnel into a 250 ml
separatory funnel.
A. Shake the separatory funnel vigorously for one minute, allow
the phases to separate, and drain the aqueous layer into a second
250 ml separatory funnel. Drain the hexane layer into a 250 ml
Erlenmeyer flask.
5. Proceed with steps 7 through 25 in the tissue procedure.
-------
Procedure for the Extraction and Cleanup of Water Samples for TCDD
1. Place 500 g of water in a 1,000 ml separator/ funnel. Fortify with
37C1-TCDD.
2. Add 100 ml of methylene chloride to the separatory funnel and shake
vigorously for about 1 minute.
3. Allow the layers to separate and drain lower layer (CH C12) into a
500 ml Erlenmeyer flask.
4. Repeat steps 2 and 3 twice more.
5. Place a Snyder column onto the 500 ml Erlenmeyer flask, add boiling
beads and concentrate the CH C10 to near dryness on a steam bath.
22
6. Add 100 ml of hexane through the Snyder column into the 500 ml Erlen-
meyer flask and concentrate this to near dryness.
7. Allow the flask to cool, add 30 ml of hexane through the column.
8. Remove the Snyder column and transfer the hexane into a 250 ml separa-
tory funnel. Rinse the flask with two separate 10 ml portions of hexane
and add these to the separatory funnel.
9. Wash the hexane with 50 ml of 1 N KOH.
10. Proceed with steps 10 through 29 as described in the Tissue Procedure.
-------
Attachment B. Methods Section
Sample Preparation
-------
Decoding of Samples Shipped to EPA-RTP on 2/7/79
Sample
Shipment Sample Sample
Number '."umber Type
DW-1 EA05S28
DW-2 Q.C. 1
Sample
Description
Sample
Wt. (g)
--Fortification Level
ng Cl-TCDD ppt native I
water Dow Chetn. In- 500
Plant (2,4-D
process to deep
well
water distilled water 500
0.2
DS-1 EA05S18A
sludge
DCW-1 EA05S10
DCW-2 EA05S03
DO?-3 EA05S04
blank
carbon
carbon
filtered
water
carbon
filtered
water
Dow Chem. In-
Plant (phenol
treatment sys-
tem waste)
dry carbon
powder in fil-
ter
Dow Chem.
effluent
10
920,000
Tittabawasee 1,150,000
River upstream
at Dow Bridge
-------
Attachment A. Methods Section
Sample Identification Codes
-------
Table 1.
CRITERIA USED FOR CONFIRMATION OF 2,3,7,8-TCDD RESIDUES IN HUMAN
AND ENVIRONMENTAL SAMPLES
1. Capillary Column GC/MS retention time of 2,3,7,8-TCDD.
2. Co-injection of sample plus 35 Cl-2,3,7,8-TCDD standard.
3. Molecular ion Cl isotope ratio (M/E 320 and M/E 322),
A. Capillary column GC/HRMS multiple ion monitoring response-
(Simultaneous response for elemental composition of M/E 320,
M/E 322, and M/E 328).
5. Response of M/E 320 and M/E 322 greater than 2.5 times the noise
level.
-------
Results for Analyses of Environmental Samples
from Michigan - (EPA Region V)
for 2,3,7,8-Tetrachlorodibenzo-p-dioxin (TCDD)
Analyses by The Analytical Chemistry Branch
Members of: Environmental Toxicology Division
Health Effects Research Laboratory
U. S. Environmental Protection Agency
Research Triangle Park, NC 27711 (MD-69)
Samples Prepared The EPA Pesticides Monitoring Lab
by Members of: Office of Toxic Substances
U. S. Environmental Protection Agency
Bay St. Louis, Mississippi 39529
Date: 9 April 1979
-------
APPENDIX B-5
PCDDs and PCDFs
1981 USEPA Study
-------
arger: Dow Chemical Co. Midland, MI
a Date: September 3-10, TJB1
U.S. ENVIRONMENTAL PROTECTION AGENCY
REGION V
Eastern District Oi'flce
Large Volume Water Samples
'LE TYPE
J MGD '
'ERATURE 'C
(S.U.)
DUCTIVITY vmho/cm
AMETER
2.3.7.8 TCOD
Ortnrhlnrn <«nnif»r<
Pnlyrhlnrinatpd fHhf>n?of
2 3.7.8 TCDF
T*»t rurhlnrn <«ftm*r<
H»v«rh1nrft 1«nmpr<
Mpptarhlnrn <
1.63 •
3.8V
.—
Outfall 005
24 EVC
0755-0450
3.5
17.5-21.5
7.2-7.5
570-770
(1 Isomers)
< 120*
2700/K1
< ?Q
< tin
< 00
< 100
1700
42007
56007
507
< 80
< 100
ttl
4)
1)
Gross
ID'5
Ibs/da
..
K 71
•t •
4.96'.'
12.26
16.35
O.H
OUtfall 031
24 EVC
0900-0630
34.6
18-20
6.7-7 0
4000-5500
PPq/
(1 isomers)
50
RO/^2)
< 20
V 40
< 80
<100
790
9000/M
190/(6
< 40
< 80
< |UU
1
Gross
10'5
Ibs/da
1.44 "
9.n
••
--
«
22.80
250. 7l
b.48
—
Outfall 031
Plume Mixing Zone
24 EVC
0935-0645
' 18-20
7.1-7.5
2200-4500
ppq/ ,
(f Isomers)
45
50/M)
< 40-
< 1
-------
I. niOKIN METHODOLOGY - WATE.1
The objective of this study was to analyze selected polychlorinated
dibenzofurans (PCDF) and polychlorinated dibenzo-p-dioxins (PCDD) in
water. The detection limits specified for these compounds were parts-
p»r-quaurillion (1 part in 1015 or ppq). Specific compounds vihich
were selected for identification included: 2,3,7,8-tetrachlorodibenzofuran
(2,3,7,S-TCDF), 2,3,7,8-tetrachlorodibenzo-p-dioxin (2,3,7,8-TCDD), and
all zzz-s. through octa chloro furan and dioxin isoners. High resolution
gas chromatography/high resolution nass spectrometry (HRGC/HRMS) was used
to identify ar.d quantify these naterials at the indicated trace level.
The exact masses used for each isomer class and the expected isotope
ratio u3=sd in part for identifying individual compounds, as veil as
limits of detection for the water are presented in Table 1. 2,3,7,8-
tetrachlorodibenzo-p-dioxin-13c^2 was used as an internal standard for
quantification and recovery determinations. These recovery determinations
are found in Table 2 and were used to estimate the influence of the
matrices on the analytical ceasurenents.
Preparation of Water Samples
The water samples were extracted and cleaned-up using the following
procedure. A ten liter aliquot of water was transferred from the
original sample bottle to a 19 liter glass bottle, and spiked with
2 ng of 2,3,7,8-tetrachlorodibenzo-p-dioxin-C12 (2,3,7,8-TCDD-13C12).
The water aliquot and internal standard were mixed for 30 minutes
using a magnetic stirring bar. After the initial mixing, the stirring
was discontinued and one liter of hexane was added to the aliquot for
extraction of organics. The stirring was resumed and the aliquot
extracted for 16 hours. After the extraction process, the aliquot
and hexane were allowed to equilibrate for two hours. The hexane was
transferred to a 1000 nl Kuderna-Danish (K-D) flask using a 100 ml-
volumetric pipet. Distilled water was added to the bottle to force
the last 100 ml or less of hexane into the neck of the bottle which
facilitated its transfer. The K-D flasks were placed in a hot water
bath and the extracts were concentrated to a volume of 20 ml. The •
extracts were transferred to 250 ml separatory funnels, using three
5 ml hexane rinses of the K-D flask.' The hexane extracts were washed ."
three .tines each in the .following sequence: 50 ml of 1M NaOH, 50 ml
of distilled water, 50 ml of concentrated H2S04, and finally 50 ml
of distilled water. All base, acid and water washes were collected,
neutralized and discarded. The hexane extracts were transferred to
125 nl K-D flasks, using three 5 ml hexane rinses of 250 separatory
funnels, and concentrated to a volume of 5 ml. The extracts were
introduced onto alumina columns to isolate the furan and dioxin
compound classes. The columns were eluted sequentially with 25 ml
of hercane, 25 nl of 1:1 (V:Y) hexane:carbon tetrachloride, and 20 ml
of 1:1 (V:V) hexane:methylene chloride. Decane (20 ul) was added to
the hexane:methylene chloride fraction containing the furans and
dioxins, and the fraction concentrated to 20 ul prior to analyses.
-------
The extracts were analyzed by high resolution gas chro.-natography/
hish resolution mass spectroaetry (HRGC/HRMS) at a mass resolution
of 8000-12000 (H&H, 10 percent valley). A VG Model 7070H mass
spactroneter interfaced to a Carlo Erba Model 4160 gas chromatograph
v;as used. The chromatogrnphic column was a 30M D3-5 fused silica
column with heliuta carrier gas. All HRGC/HRMS data were acquired
in the -ultiple ion detection mode using a VG Model 2035 Data System
and -ill ba archived on magnetic tape for a period of five years.
II. QUALITY COTTTROI,
A. Internal Audits
The following quality assurance procedures V7ere eraployed.
Perfluorokerosene was introduced through a heated inlet for tuning,
mass calibration and establishing mass resolution. A 2 ul injection
of a test mixture containing 20 pg/ul of 2,3,7,8-TCDD and 95 pg/ul of
2,3,7,8-TCDD-3"5Cj_2 was analyzed. The analysis of this test mixture
provided the following information:
formation concerning sensitivity (absolute response
2,3,7,8-TCDD-13C12) .
r* ._ • f^ . • s . •
0 Information
of 2, . ,
* Accuracy of quantification (native response as compared
to that of its C—13 analogue)
* Elution within a specific retention time window
*• * Chronatographic peak shape symmetry.
Decane was analyzed to check for dioxin carry "over. This
information is used to access performance of the instrument before
the measurement of PCDF and PCDD at trace levels is conducted in
actual samples. . - '
The actual sample analyses were by the following procedure:
four to six samples, a duplicate or spike, an extraction blank, a •
test mixture, a decane blank, then the cycle was repeated.
B. External Audits ' ........ ""- -".." ; V . '.•
* * s *•_ •"•*
1. On-site Visit " -
Curing Septeaber 20-21, 1982, Marcia A. Kuehl> QC Coordinator
for the Central Regional Laboratory, toured the Battelle Columbus dioxin
facilities and audited the chain-of-custody documentation. She spent
a large portion of the time observing the acquisition and reduction of
the dixoin/furan data by HRGC/HRMS.
-------
The objective of this audit t:as Co inspect whether the
analysis of Dow Study samples was conducted according to Contract £68-01-6421,
(Amendment to Work Assignment Specifications 2003) and to present and resolve
any anonalous results reported by Battelle for the blind QC samples that
CPxt. submitted along with the actual samples.
Document Control Study
When the Dow samples arrived at Battelle,-the secured shipping
and receiving area contacted the team responsible for the project. An
authorized person signed for the samples and transported them to the
Dio:dLa Extraction Laboratory. There the samples were unpacked and checked
against the packing list. They were then recorded in the GCA Project File
logbook along with a Battelle number. All logbook entries were of the
forra XXYYZZ where XX indicates the logbook number, YY the page of entry
and ZZ the line number of the page.
Only three people had keys to the Dioxin Extraction Laboratory
and sample storage area. As the extraction of the samples proceeded; all
extraction notes were entered in the GCA Project File logbook according
to the format above. When the extracts were ready for HRGC/HRMS, they.
were picked up by Dan Aichele, and all HRGC/HRMS work pertaining to the
samples was entered in the HRGC/HRMS logbook, with cross-references
to the extract numbers obtained froa the GCA Project File logbook kept
in the locked Dioxin Extraction Laboratory. All computer outputs and
raw HRGC/HRMS data was filed by CRL sample number designation in a
file box kept in the HRGC/HRMS laboratory^ The discs containing Dow.
sample KRGC/HRMS data were also stored there.
The entire Battelle facility is a security area. In order
for visitors to gain entry, they must fill out a visitors card indicating
their affiliation and Battelle employee to be contacted. A visitor's
badge is typed which indicates that a Battelle escort is required at
all°tiiaes. Bnployees wear identification badges and can only gain"
entry by a coded keycard or by showing their ID card to a receptionist*.
Battelle personnel were careful to not divulge the exact nature of . .
the analytical .work being done on other projects, nor to name any.
other clients. . '• . • . ' : - - .- .
All of the GCA Project File logbook information, relating
HRGC/KRMS logbook Information, and raw computer printouts was photocopied
and submitted with the final draft of the report on 12/30/82. The final
report was peer reviewed at Battelle and was sent to GCA (prime Contractor)
as required by the contract. The photocopied logbook and raw data was
sent directly to the CRL on 12/30/82 along with a copy of the final report.
-------
Battclle QA/QC Protocols
A decane solvent blank and 2>3,7>8-TCDD-13Cl2 standard was run at
least once a day. The area response of the 2,3,7 ,8-TCDD-*3Cl2 standard
must ba approximately 4000 and no less than 2000. The ion peak ratio
at n/z of 320 to 322 and 332 to 334 nust be 0.77 ± 10X. This ion peak
ratio for the native 2,3,7,8-TCDD to 2,3,7,8-TCDD-13Cl2 must be within
10% cf tha expected ratio for the analysis to be acceptable.
A seven-point calibration curve of 2,3,7,8-TCDD is run every 6 nonths.
Each day, the saaples are injected to insure that they are within the
linear raage before actual data reduction/quantitation is done. Two
injections of each extract were made to monitor precision of the
2,3,7,8-TCDD-C13 recovery. For all of the Dow Samples, 2,3,7,8-TCDD-C13
was used as the internal standard. No historically based control limits
for 2,3,7,8-TCDD-J"3C12 recovery from water and fish have been set by
Battelle. Recovery information is found in Table 2.
No splitting of Dow Samples into lab-prepared duplicates was done.
No lab spiking of actual Dow Samples to serve as a natrix spike was
done either. The blind QC samples submitted by CRL served in these
functions. ' • •
Quantification Procedure
Before any samples, standards or blanks are injected into the
Carlo Erba HRGC and VG 7070H HRMS system, the instrument is tuned by
the perfluorokerosene lock mass of 319. The response of the MS to this
corapound must neet the mass criteria specified before samples are injected. *
The VG 7070H electronics were modified by Battelle personnel to allow
more rapid scans over the acquisition tine, and thus give greater resolution
and lower detection levels.
All quantitation is done on the basis of a one-point calibration
standard of 2,3,7,8-TCDDrC13. Qualitative identification .is done on
the "basis of retention time. The correct raa'ss ratio Qh 10%) of the ; • .
isomsr^s .two largest peaks is also used-for verification of .identity. "* •
The siaplified formulas used are given below:
COSC pg/g = 2000 pg 2,3,7,8-TCDD-C13 x area of analyte in sample
area of 2,3,7,8-TCDD-ci3 in sample
weight of sample (g)
detection limit » 2.5 x area of analyte in sample x 2000 pg •
area of 2,3,7,8-TCDD-C1-1 in sample . .
sample weight
-------
2. Blind QC Water Sample Results
QC samples were prepared and originally analyzed by
Dr. Robert llarless, EPA-RTP. They were sent to Curtis Ross, Director CRL,
EPA Region V to use as part of the Quality Assurance program audit of
Battelle Columbus Laboratories for this study. The water QC samples
were received, in sealed ampules with benzene as the solvent. These
ampules vere opened by CRL personnel at Argonne National Laboratory and
nixed with approximately 25 liters of organic free v/ater to form the blind
QC saaples. CRL saaple numbers were assigned to the blind QC samples to
further aid in disguising them.
Before any analytical data was generated, a comparison of
EPA 2,3,7,8-TCDD standard (82LS10R05) was made with the Battelle prepared
quantitation standard. The EPA standard was previously round robin-tested
and found to contain 10 pg/ul (600 pg in the 60 ul ampule). .A variation
of only •*• 10% was allowed between Battelle and this EPA standard. Four
additional standards in benzene were then analyzed for 2,3^7, 8-TCDD;
1,3,6,8-TCDD; 1,3,7,9-TCDD; 2,3,7,8-TCDF; OCDD and OCDF.
After these standards were judged acceptable by Dr. Harless,
a blind QC spike (81EH07S09) was analyzed and reported next. After
acceptance of this data, actual sample and other blind analysis began.
Results of all blind standards and samples are given in Table 3.
Recovery Comments • .
1) 81EH07S23(Spike QC) - OCDF was reported at a much higher level
than the spiked ""Tn'e"dia't:a was re-reduced and the result of 230 ppt was
verified. The problems in OCDD and OCDF recoveries appear to stem from
the lack of a OCDD-C13 standard to check the actual response against
the internal standard. • - .
2) 81EH07S24 (Blank QC) - OCDF at a level of 180 ppq was reported.
No OCDF x,*as~present"in"the"ljC"ampule used to mix this sample. The data
was recalled from .disc and the result reverified at 230 ppq. If this
.QC sample was mixed after the 81EH07S23 and/or 81EH07S25 QC Samples, .
carryover .isay have occurred .to account for- this value i. .• -. • "
3) 81ZH07S25( Spike QC) - Recovery of OCDF was high' (750 ppq recovered
vs 160 ppq s?Iite3}"~Due to~EKe lack of a Cl3 labelled OCDD standard to
judge the relative response against 2,3,7,8-TCDD-C^, quantitation was,
at best, an estimate. The data was recalled from disc and reverified
at A30 ppq using peak height rather than area.
CONCLUSION:
Due to the imprecise and inaccurate OCDF results discovered by the
three blind audits, any positive OCDF data for water sanples should not
be considered usable. All other dioxin/furan sample data should be
considered of an acceptable level of quality.
-------
TABLE 1. " SELECTED DATA FOR THE POLYCHLORINATED DIBENZOFURAHS AHU
POLYCHLORINATED DIBENZO-P-DIOXINS OF INTEREST
Limit of
• '• • Accurate mass ' Theoretical Isotope Detection
Compounds
Te tr achlorod ib cnzo f uran
Tetrachlorodibenzo-p-dioxin
Pcntachlorodibcnzofuran •
Pentachlorodibenzo-p-dioxin
Hexachlorodibenzofuran _' •
Hexachlorodibenzo-p-dioxin
i
Hep tachlorodibcnzof uran
Heptachlorodibenzo-p-dioxin
Octachlorodibenzofuran
Octachlorodibenzo-p-dioxin-
Low Mass
. 303.9016
319.8965
339,8597*
355,8546
' 373,8207*
389.8156
• 407.7817*
• 423.7766*
441.7428
• 457.7377
High Mass
305,8987*
321,8936 .
34118567 '
357.8517
375.8178
391.8127
409.7788
425.7737
443.7398*
459.7347*
Ratio
.77
.77
1.54
1.54
1.23
1.23
1.03
. 1.03
0.88.
0.88
Vfatcr
10 ppq
10 ppq
20 ppq
20 ppq
40 ppq
40 ppq
80 ppq
80 ppq
•100 ppq
100 ppq
Fish
5 ppt
5 ppt
20 ppt
20 ppt
40 ppt
40 ppt
80 ppt
80 ppt
100 ppt
100 ppt
Quantitation Mass
.1.
-------
TABLE 2. IWTERNAL STANDARD RECOVERIES 0?
2>3>7,8-TETPuXatLORODI.BE:s7.0-P-DIOXlN-l3C12 IN WATER
Water Recoveries
Internal Standard
Sample Name Recovery (%)
81EH07S10
81EU07S12
81EH07S22
81EH07S23
81EH07S23
81EH07S24 - .
81EH07S13
81EH07S26
81EH07S39
81EH07S53
81EH07S66
81EH07S38
90
71
81
89
87
94
71
91
83
85
84
83
-------
TABLE 3. BLIND WATER SAMPLE KESULTS
UNITS - ps/1
, t
I 2,3,7,8-TCDO
0
190
4.a-Tcoy
IloporCcdlTruelt Recovery
0
0
0
0
' 25
<3
<3
<5
01 -
X>l -
01 -
01 -
74"
0
0
104
1
.
ol -
i7", ' lil Hi
i
41
01 -
4B
1 65
1" l.i.'i.i-TCUD1
1,5,7,9-TCDD
Reported (True 1 Z Recovery 1 Kepor ccd 1 True
1 0
"'116 '
70
63
5
<3
05
<3
or - i o
260| SB 1 44
100
100
111
0
0
0
g**f *g
"' *<1
6
27**l 32
70
; 63
31
-
-
-
100
-
30
22
2
400
180 1 Ot
60 7SO | 1GO[>4CQ
* - below contract required detection Halt , • .•
»* - reported «< tot*l of 2 isaner»
A - 54-77 P8/1 pentaehlorinAted dtbenzofuraiu «l«o reported
S - 11 pg/1 pentachlorlnated dlbencofurau «lio reported
-------
DOW CHEMICAL USA
MICHIGAN DIVISION — MIDLAND PLANT
NON-CONVENTIONAL/TOXIC POLLUTANTS ~ OUTFALL 031
PERMIT Ml #0000868
TABLE 1
Mon itor ing ResuIts — September, 1984
Phenol
2,4-DIchlorophenoxyacetlc
ac id
Bi s(2-chloroethyI)ether
Chloroform
2,3,7,8-TetrachIoro-
d ibenzo-p-d ioxi n
1 ,1,2,2-Tetrachloroethane
TetrachIoroethyIene
1,1,2-TrichIoroethane
Pentachlorophenol
1,3-Dichlorobenzene
1,4-Dichorobenzene
1,2,4-Tr ichlorobenzene
Methylene Chloride
2-Chlorophenol
2,4-D ichlorophenol
Naphtha Iene
1,1,1-Tr ichIoroethane
Bromoform
Chlorobenzene
Carbon Tetrachloride
2,4,6-Tr ichlorophenol
1,2-Dichlorobenzene
Aery Ion itr iIe
Month 1 y
Average
(Ibs/day)
0.2
.0135*
0.3
4.9
5.6x10~7
0.2
0.1
0.4
8.8 _
0.9
4.1
0.2
Da i ly Month ly
Maximum Average
(Ibs/day) (pg/ liter)
0.2 1
.0165* NDU.6)
0.4 1
5.3 22
6.5x10 3.4 ppq
ND(7.0)
ND(7.0>
ND(11 )
ND(5)
0.2 0.9
0.2 1
0.5 2
11.8 40
NDC0.7)
ND ( 1 )
ND(.3)
ND(6.8)
1.8 ND(7.6)
NDC5.8)
4.2 18
ND(2)
0.2 1
ND(4.2)
Dai ly
Max imum
(ua/l iter)
r
—
2
24
3.7 ppa
—
—
—
—
1
1
2
54
—
—
—
—
—
—
18
—
,1
__
-------
DOW CHEMICAL USA
MICHIGAN DIVISION — MIDLAND
NON-CONVENTIONAL/TOXIC POLLUTANTS -
PERMIT Ml #0000868
TABLE 2
PLANT
- OUTFALL 031
MOP itor ing ResuIts — September, 1984
Concentration
ya/l iter
Phenol ND(1)
2,4-Dich lorophenoxy
acetic acid ND(1 .6)
Bis(2-chloroethyl )ether 2
Chloroform 24
2,3,7,8-Tetrach loro-
d ibenzo-p-d iox in 3.7
1 ,1 ,2,2-Tetrachloroethane 7.0
Tetrachloroethy 1 ene 7.0
1 , 1 ,2-Tr ichloroethane 11
Pentachiorophenol ND(3)
1 ,3-Dichlorobenzene 1
1 ,4-Dichorobenzene 1
1 ,2,4-Tr ichlorobenzene 2
Methyl ene Chloride 54
2-Chlorophenol ND(0.8)
2,4-Dichlorophenol ND(1)
Naphthalene ND(.3)
1,1,1-Tr ichloroethane NDC6.8)
Bromoform ND(7.5)
Chlorobenzene NO (5. 8)
Carbon Tetrach lor ide 18
2,4,6-Trichlorophenol ND(2)
1 ,2-D ! ch I orobenzene 1
Aery Ion i tri le ND(4.1)
Sample Concentration
Date uci/l iter
9/04/84
9/04/84
9/04/84
9/04/84
8/21/84
9/04/84
9/04/84
9/04/84
9/04/84
9/04/84
9/04/84
9/04/84
9/04/84
9/04/84
9/04/84
9/04/84
9/04/84
9/04/P4
9/04/84
9/04/84
9/04/84
9/04/84
9/04/84
1
ND ( 1 . 7 )
1
19
3.0
7.0
ND(7.0)
12
ND(6)
0.7
NDC0.5)
2
25
ND(0.6)
ND(1 )
0.4
ND(6.8)
ND(7.7)
NDC5.9)
18
ND(2)
1
4.4
Samp 1 P
Date
9/17/84
" 9/17/84
9/17/84
9/17/84
9/03/84
9/17/84
9/17/84
9/17/84
9/17/84
9/17/84
9/17/84
9/17/84
9/17/84
9/17/84
9/17/84
9/17/84
9/17/84
9/17/84
9/17/84
9/17/84
9/17/84
9/17/84
9/17/84
ND = Not Detected
() = Lowest Detection Lfmit
-------
•*DOH CHEMICAL COMPANY
MIDLAND DIV
MlOLAND
.illL-.J^lu'sMM 11;., 12^jj|IWJ8MQ(BMii9fiWi!ili!iJ''~ iMHiuM.ij^uw>rUi^uu-uJUJvaeuuiiw^aiiuuwu .- . ><-.
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(AtHIH NUMlliT~j I FlHMll NUMUlftI ft'.TIAU NUMUt H I
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MONTHLY OPERATING REPORT FOR
1ms is Ytmn MONTHLY lUroiu f OI\IA ion
SEE ncvtnsE SIDE FOR RETURN MAIL
Picnic cumplcu* anci lulmul ivvo copies ol this foim
* I iliv end ol tad) monih This ICIKHI inusl iLich our
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PAHT 1 - nETURN TO DEPT OF NATURAL RESOURCES
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.OUTFALL' I 031
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-------
<
'OH CHEMICAL COMPANY
UDUUD DIV
IDLAND
OOB6Bj IJ.6013B
MONTHLY OPERATING REPORT FOR
THIS IS YOUII MONTHLY REPOnT fOIIM fOfl
SEE REVERSE SIDE FOR RETURN MAIL
Please comjilcie and julwnii two copies ol ihn lorm
dl ihu1 end ol cdctk month Ttm report muil rudch our
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-------
DOW CHEMICAL USA
MICHIGAN DIVISION -- MIDLAND PLANT
NON-CONVENTIONAL/TOXIC POLLUTANTS - OUTFALL 031
PERMIT #MI 0000868
TABLE 1
Monitoring Results -- August, 1984
Phenol
2,4-Dichl orophenoxyacetic
acid
Bis(2-chloroethyl )ether
Chi oroform
2,3,7,8-Tetrachloro-
dibenzo-p-dioxin
1,1,2,2-Tetrachl oroethane
Tetrachloroethyl ene
1,1,2-Trichl oroethane
Pentachlorophenol
1,3-Dichlorobenzene
1,4-Dichorobenzene
1,2,4-Tn'chlorobenzene
Methyl ene Chloride
2-Chlorophenol
2,4-Dichl orophenol
Naphthalene
1,1,1-Trichloroethane
Bromoform
Chiorobenzene
Carbon Tetrachloride
2,4,6-Trichl orophenol
1,2-Dichlorobenzene
Acryl onitnl e
Monthly Daily
Average Maximum
Obs/day) (Ibs/day)
0.2 0.4
.0018* .0029*
0.2 0.4
3.0 3.6
1.9xlO"7 3.8xlO'7
.05 .1
.1 .3
-2 .4
2.6 3.6
1.8 3.6
2.1 2.7
0.1 0.3
Month! y
Average
(ug/i)
2
3
3
32
4.5 ppq
ND(6.8)
N0(6.8)
ND(8.7)
ND(7)
1
2
3
25
ND(0.5)
ND(1)
ND(.2)
ND(6.9)
14
ND(5.7)
9
ND(2)
2
ND(4.2)
Daily
Maximum
(ug/i)
3
3
3
44
5.9 ppq
—
--
—
--
1
2
3
30
—
--
--
--
20
--
15
--
2
_ _
-------
DOW CHEMICAL USA
MICHIGAN DIVISION -- MIDLAND PLANT
NON-CONVENTIONAL/TOXIC POLLUTANTS -- OUTFALL 031
PERMIT #MI 0000868
TABLE 2
Phenol
2,4-Dichlorophenoxy
acetic acid
Bis(2-chloroethyl )ether
Chloroform
2,3,7,8-Tetrachloro-
dibenzo-p-dioxin
Moni
Concentration
ug/1 iter
1
3
2
20
5.9 ppq
1,1,2,2-Tetrachl oroethane ND(6.5)
Tetrachl oroethyl ene
1,1,2-Tric hi oroethane
Pentachlorophenol
1 ,3-Dichl orobenzene
1 ,4-Dichorobenzene
1 ,2,4-Trichl orobenzene
Methyl ene Chi oride
2-Chl orophenol
2,4-Dichlorophenol
Naphthal ene
1 ,1,1 -Trie hi oroethane
Bromoform
Chi orobenzene
Carbon Tetrachl oride
2,4,6-Tric hi orophenol
1 ,2 -Die hi orobenzene
Acryl oni tn'l e
ND(6.6)
N0(9.3)
ND(7)
1
1
3
20
'ND(O.S)
ND(1)
ND(0.2)
ND(7)
20
ND(5.8)
ND(7.1)
ND(2)
1
ND(3.9)
toring Resul
Sampl e
Date
7/23/84
7/23/84
7/23/84
7/25/84
7/23/84
7/25/84
7/25/84
7/25/84
7/23/84
7/23/84
7/23/84
7/23/84
7/25/84
7/23/84
7/23/84
7/23/84
7/25/84
7/25/84
7/25/84
7/25/84
7/23/84
7/23/84
7/25/34
ts -- August,
Concentration
yg/l iter
3
2
3
44
3.1 ppq
ND(7.1)
ND(7.0)
ND(8.1)
N0(6)
1
2
3
30
ND(0.6)
ND(1)
ND(0.2)
ND(6.7)
ND(9.1)
ND(5.6)
15
ND(1)
2
NO (4. 5)
1984
Sampl e
Date
8/06/34
8/06/84
8/06/84
8/13/84
8/06/84
8/13/84
8/13/84
8/13/84
8/06/84
8/06/84
8/06/84
8/06/84
8/13/84
8/06/84
8/06/84
8/06/84
8/13/84
8/13/84
8/13/84
8/13/84
8/06/84
8/06/84
8/12/34
ND = Not Detected
-------
jiif
i iii
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• •DOH CHEMICAL COHPAHY
MIDLAND OIV
HI ['LAND
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MONTHLY OPERATING REPORT FOR
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•DON CHEMICAL COMPANY
MIDLAND DIV
MIDLAND :'I 486<|0
IACKITY NUMIfA
[560004 ._
|P(KMiT NUM8EH I j'J.*»*U NuMBta
I (110000868 J LS60136
MONTHLY OPERATING REPORT FOR
THIS IS YOUR MONTHLY RtfonT FORM FOR
SEE REVERSE SIDE FOR RETURN MAIL
Please complete and iulimit two copits ol this loim
al (he end ol each month. Tim report must reach our
Lansing office by the lOlh of the month.
PART 1 - RETURN TO DEFT OF NATURAL RESOURCES
02
* 4470 "'• • » ""•
4113 ••10
DOW CHEMICAL COMPANY
OUTFALL I 031
PROC.HASTES TO TITTABAHASSEE' R. 031
PERMIT EXPIRATION} JO/79
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1 HAVE PERSONALLY EXAMINED AND AM FAMILIAR WITH THE INFORMATION SUBMITTED IN THIS DOCUMENT AND ALL ATTACHMENTS AND
INDIVIDUALS IMMEDIATELY RESPONSIBLE FOR OBTAINING THE INFORMATION. 1 BELIEVE THAT THE INFORMATION IS TRUE. ACCURATE. ANO
SIGNIFICANT PENALTIES FOR SUBMITNNG FALSS-, INFORMATION. INCLUDING THE POSSIBILITY OF FINE AND IMPRISONMENT.
-,f., vnnuir c- A"" T/Ste* CERTIFICATION NUMBER WflOlPfli
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-------
DOW CHEMICAL USA
MICHIGAN DIVISION — MIDLAND PLANT
NON-CONVENTIONAL/TOXIC POLLUTANTS — OUTFALL 031
PERMIT #MI 0000868
TABLE 2
Monitoring Results - July, 1985
Phenol
2,4-Dichlorophenoxy-
acetic acid
Bis(2-chloroethyl)ether
Chloroform
2,3,7,8-Tetrachloro-
dibenzo-p-dioxin
1,1,2,2-Tetrachloroethane
Tetrachloroethylene
1,1,2-Trichloroethane
Pentachlorophenol
1,3-Dichlorobenzene
1,4-Dichorobenzene
1,2,4-Trichlorobenzene
Methylene Chloride
2-Chlorophenol
2,4-Dichlorophenol
Naphthalene
1,1,1-Trichloroethane
Bromoform
Chlorobenzene
Carbon Tetrachloride
2,4,6-Trichlorophenol
1,2-Dichlorobenzene
Acrylonitrile
Concentration
ug/liter
2
5
2
8
33 ppq*
3
4
NDC0.8)
ND(2)
1
2
3
ND(6)
ND(0.6)
2
-0.3
5
1
2
1
ND(2)
3
ND(1)
Sample Concentration Sample
Date Mg/liter Date
6/24/85
6/24/85
6/24/85
6/24/85
6/24/85
6/24/85
6/24/85
6/24/85
6/24/85
6/24/85
6/24/85
6/24/85
6/24/85
6/24/85
6/24/85
6/24/85
6/24/85
6/24/85
6/24/85
6/24/85
6/24/85
6/24/85
6/24/85
4
18
2
10
31 ppq*
ND(6)
6
ND(5)
ND(2)
0.9
2
2
7
ND(0.7)
4
0.3
ND(7)
ND(6)
ND(3)
ND(5)
ND(2)
4
3
7/08/85
7/08/85
7/08/85
7/08/85
7/10/85
7/08/85
7/08/85
7/08/85.
7/08/85
7/08/85
7/08/85
7/08/85
7/08/85
7/08/85
7/08/85
7/08/85
7/08/85
7/08/85
7/08/85
7/08/85
7/08/85
7/08/85
7/08/85
ND = Not Detected
() = Lowest Detection Limit
»
= Concentration Reported as Part Per Quadrillion
-------
DOW CHEMICAL USA
MICHIGAN DIVISION — MIDLAND PLANT
NON-CONVENTIONAL/TOXIC POLLUTANTS — OUTFALL 031
PERMIT #MI 0000868
TABLE 1
Monitoring Results - July, 1985
Phenol
2, 1-Dichlorophenoxyacetic
acid
Bis(2-chloroethyl)ether
Chloroform
2,3,7,8-Tetrachloro-
dibenzo-p-dioxin
1,1,2,2-Tetrachloroethane
Tetrachloroethylene
1,1,2-Trichloroethane
Pentachlorophenol
1,3-Dichlorobenzene
1,1-Dichorobenzene
1,2,4-Trichlorobenzene
Methylene Chloride
2-Chlorophenol
2,U-Dichlorophenol
Naphthalene
1,1,1-Trichloroethane
Bromoform
Chlorobenzene
Carbon Tetrachloride
2,4,6-Trichlorophenol
1,2-Dichlorobenzene
Acrylonitrile
Monthly Daily
Average Maximum
(Ibs/day) (Ibs/day)
.5 .7
.016* .027*
.3 .3
1.5 1.7
2.7x10~6 5.3x10~6
.8 1.0
.8 1.0
—
— —
.2 .2
.3 .3
.1 .5
1.2
—
.5 .7
.05 .05
.8
.2
.3
.2
—
.6 .7
.5
Monthly Daily
Average Maximum
(ug/D (ug/D
3
12
2
9
32 ppq
5
5
MD(3)
ND(2)
1
2
3
ND(6)
ND(0.6)
3
0.3
ND(7)
ND(6)
ND(3)
ND(5)
ND(2)
4
ND(1)
U
18
2
10
33 ppq
6
6
ND(5)
ND(2)
1
2
3
7
ND(.7)
H
0.3
5
1
2
1
ND(2)
4
3
Mass discharge measured at 031a
-------
•00* CHEMICAL COIiPAKT
KJDLAND OIV
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MONTHLY OPERATING REPORT FOR
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SEE /irvtMSI SIDE f OH ntlOHW MAIL
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PART 1 - RETURN TO DEFT OF NATURAL RESOURCES
Jv.l-1
111 •;
02
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OOH CHEMICAL
OUTFALL I 031
PROC.KASTES'TO TIITAOAHASSEE-R. Oil
PERMIT EXPIRATION!
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OH CHEr.ICAl COMPm
IDlAND OIV
ll'LA'ID
MONTHLY OPERATING REPORT FOR
1MISISVOUKMONIMLV lllrOAI (OMMIOH
S££ AVERSE SIDE.? on nuuriN MAIL
PICJIC compltu 'T9 pr-
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DATS (KCUOING MAMIMU*^ ^ ^
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1 IQIALSAMKtS AM« 1^ L
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MAI ON I HI I «VI IHAI II* INIOI.MAHON Ii IMUt. Al.CimAIC. AMD
JIMC, llli I'0'..MUILIIV Ul IINC AND IMI'IIIIONMINI
-------
JOrt CHEMICAL COMPANY
1IOLAUO OIV
iJOlAfVD
18640
565004,U5lop.B6
MONTHLY OPERATING REPORT FOR
THIS 15 rOUK MUNfMLV HLvanT t OHM tun
SEE REVERSE SIDE FOR RETURN MAIL
Pkjve complete and lubmd two cop*i ol inn toim
ai Ihi- end ol i-acli month Tim (cporl mull (each out
taming oFlicu by Ihr lOlh ol the month
PARf 1 - RETURN 70 DEPT OF NATURAL RESOURCES
DOw CHEMICAL COMPANY
OUTFALL t Oil
PROC. HASTES TO
PERMIT EXPIRATION! JO/79
* ' ."
Date form w*
p»u««
R. 031
JI616
COL
IFORM-FEC*
JMAXI
lloAILY AVG
| 1
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1 cr.l'lr < '.Ur< niiAiIV OF LAW 1MAI 1 |IAVE PERSONALLY EXAMINED AND AM FAMILIAR WITH THE INFOIIMATION SuOMIHCD IN THIS DOCUMENT AND ALL ATTACHMENTS AND
THAI IIA'.ld UN Mr M,Jl|IY UF IMOLi l/ii, V (,UAI S IMMEDIATELY HECI'ON'JIUIE (OR OBTAINING THE INFOIIMATlON 1 IIEIILVE IHAI TML IMIOKMAIION IS THUS. ACCURATE. AND
COMI.lIt 1 AM AV/AIIE cflAF IIILIIl ANV/SlCNlFICANf POlAlTlES (Oft SUDMIFIING f ALSC^INrOFllJlAIION. INCLUFJINC TML I'OE'jIOILIlY OF 1 INC ANO IMI'llliiONMlN I
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-------
DOW CHEMICAL USA
MICHIGAN DIVISION ~ MIDLAND PLANT
NON-CONVENTIONAL/TOXIC POLLUTANTS — OUTFALL 031
PERMIT SMI 0000868
TABLE 2
Monitoring Results - June, 1985
Phenol
2, U-Dichlorophenoxy-
acetic acid
Bis(2-chloroethyl)ether
Chloroform
2,3,7,S-Tetrachloro-
dibenzo-p-dioxin
1,1,2 ,2-Tetrachloroethane
Tetrachloroethylene
1,1,2-Trichloroethane
Pentachlorophenol
1,3-Dichlorobenzene
1,U-Dichorobenzene
1,2,1-Trichlorobenzene
Methylene Chloride
2-Chlorophenol
2,M-Dichlorophenol
Naphthalene
1,1,1-Trichloroethane
Bromoform
Chlorobenzene
Carbon Tetrachloride
2,4,6-Trichlorophenol
1,2-Dichlorobenzene
Acrylonitrile
Concentration
ug/liter
3
HD(2)
ND(O.M
6
17 ppq*
ND(1)
ND(5)
ND(6)
~ ND(3)
2
1
6
ND(16)
NDCQ.5)
ND(1)
1 "
5
ND(5)
NDCO
MDC5)
MD(2)
2
MD(2)
Sample Concentration Sample
Date u g/liter Date
5/28/85
5/28/85
5/28/85
5/28/85
5/21/85 •
5/28/85
5/28/85
5/28/85
5/28/85
5/28/85
5/28/85
5/28/85
5/28/85
5/28/85
5/28/85
5/28/85
5/28/85
5/28/35
5/28/85
5/23/85
5/28/35
5/28/85
5/28/35
2
ND(2)
2
NDC14)
16 ppq*
HDC7)
ND(8)
ND(6)
NDC2)
1
1
4
11
ND<0.4)
NDC0.9)
NDC0.2)
ND(10)
MD(6)
NDC7)
MDC5)
HD(2)
2
MDC3)
6/10/85
6/10/35
6/10/85
6/10/35
6/03/85
6/10/85
6/10/85
6/10/85
6/10/85
6/10/85
6/10/85
6/10/85
6/10/85
6/10/85
6/10/85
6/10/85
6/10/85
6/10/85
6/10/85
6/10/85
6/10/85
6/10/85
6/10/85
ND = Not Detected
() = Lowest Detection Limit
= Concentration Reported as Part Per Quadrillion
-------
DOW CHEMICAL USA
MICHIGAN DIVISION — MIDLAND PLANT
NON-CONVENTIONAL/TOXIC POLLUTANTS — OUTFALL 031
PERMIT 0MI 0000868
TABLE 1
Monitoring Results - June, 1985
Phenol
2,4-Dichlorophenoxyacetic
acid
Bis(2-chloroethyl)ether
Chloroform
2,3,7,8-Tetrachloro-
dibenzo-p-dioxin
1,1,2,2-Tetrachloroethane
Tetrachloroethylene
1,1,2-Trichloroethane
Pentachlorophenol
1,3-Dichlorobenzene
1 ,M-Dichorobenzene
1,2,U-Trichlorobenzene
Methylene Chloride
2-Chlorophenol
2,4-Dichlorophenol
Naphthalene
1,1,1-Trichloroethane
Bromoform
Chlorobenzene
Carbon Tetrachloride
2 ,U ,6-Trichlorophenol
1,2-Dichlorobenzene
Acrylonitrile
Mass discnarge measured at 031a
Monthly
Average
(Ibs/day)
.6
.017*
~
2.1
2.8x10~6
—
—
—
—
.3
.2
1.1
—
—
I -
—
—
—
—
—
.4
—
t 031a
Daily Monthly
Maximum Average
(Ibs/day) (ug/1)
.8 3
.027* ND(2)
.4 ND(0.4)
2.7 10
3.2x10~6 17 ppq
ND(6)
ND(7)
ND(6)
ND(3)
.5 1.5
.3 1
1.5 5
2.1 ND(16)
— NDC0.5)
— ND(1)
.3 ND(0.2)
1.3 ND(10)
ND(6)
ND(U)
ND(5)
ND(2)
.5 2
ND(2)
Daily
Maximum
(Wg/1)
3
ND(2)
2
14
17 ppq
ND(7)
ND(8)
ND(6)
ND(3)
2
1 . :"{.
6 -\ " -"•
11 1 £
ND(.5)j 2§
HDC1) Jf
1
5
ND(6)
ND(7)
ND(5)
ND(2)
2
ND(3) =
iff =
i*l §0
««l tu
-------
Li
r \
• »DOH CHEMCAL COMPAMr
MIDLAND DIV
MIDLAND VI «86<|0
j ffACitll* huVfcilT'l IflHM.I NOMBtH j rti.l*AYl~ NUMttl
'J 1363001 I UlCLOQOfi&sJ 156015.8
MONTHLY OPERATING REPORT FOR JUr>« . i'^
02
* 4»0 •-• I II
4«J3 • <•/!>
THIS IS VOUR MONTHLY HEI'OHT f OHM FOB
SEE REVERSE SIDE FOR RETURN WAIL
PICJIC complete ind tulunit I wo copies of thu lorm
bl Ihc «nd ol t«ch monlh. Thu rcpon mull itach oui
Ummg ollicc by Ihc lOlh ol llic monlh.
PART 1 - RETURN TO DEPT OF NATURAL RESOURCES
•OOH CHEMICAL COMPANY
OUTFALL I 03J
PROC. HASTES' TO T ITTABAHASSEEi R. 031
PERMIT EXPIRATIOH! 10/79
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TOTAL SAMPLES TAKEN
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m i
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1
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AVERAGE , | , , ,(T ,. |'i
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1 1 1 _L_1_.
DuP PUNCH in Ml
5
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20
25
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PART 1 - RETURN TO DEPT OF NATURAL RESOURCES
* 44>0 »•• ( «
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MIDLAND
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MONTHLY OPERATING REPORT FOR
THIS IS YOUR MONTHLY RtPORT f OHM fOR
SEE REVERSE SIDE FOR RETURN MAIL
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19/f
4<;o >••• in
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OUTFALL I 031
PROC,HASTES TO TITTABAWASSEE:H. 031
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-DOW CHEMCAL COMPAWT
MIDLAND DIV
MIPLAND ! : Ofl6<|0
MONTHLY OPERATING REPORT FOR
THIS IS YOUH MONTHLY RCrOUT IOIIM fOH
SEE REVERSE SIDE FOR RETURN MAIL
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c
DOW CHEMICAL USA
MICHIGAN DIVISION — MIDLAND PLANT
NON-CONVENTIONAL/TOXIC POLLUTANTS — OUTFALL 031
PERMIT *MI 0000868
TABLE 2
Monitoring Results - May. 1985
Phenol
2,4-Di chloropheno xy-
acetic acid
Bi s(2-chloroethyl)ether
Chloroform
2,3,7,8-Tetrachloro-
dibenzo-p-dioxin
1,1,2,2-Tetrachloroethane
Tetrachloroethylene
1,1,2-Trichloroethane
Pentachlorophenol
1,3-Dichlorobenzene
1,4-Dichorobenzene
1,2,4-Trichlorobenzene
Methylene Chloride
2-Chlorophenol
2,4-Dichlorophenol
Naphthalene
1,1,1 -Trichloroethane
Bro 010 form
Chlorobenzene
Carbon Tetrachloride
2,4,6-Trichlorophenol
1,2-Dichlorobenzene
Acrylonitrile
Concentration
y g/liter
5
33
2
12
3 PPQ*
ND(7)
ND(9)
ND(7)
ND(5)
2
1
4
ND(6)
ND(0.6)
ND(1)
ND(0.2)
10"
14
ND(4)
ND(5)
ND(3)
1
ND(2)
Sample Concentration Sample
Date u g/liter Date
4/30/85
4/30/85
4/30/85
4/30/85
4/21/85
4/30/85
4/21/85
4/30/85
4/30/85
4/30/85
4/30/85
4/30/85
4/30/85
4/30/85
4/30/85
4/30/85
4/30/85
4/30/85
4/30/85
4/30/85
4/30/85
4/30/85
4/30/85
3
5
2
NDC12)
3 ppq*
ND(6)
ND(9)
5
10
0.8
0.6
2
5
ND(0.5)
ND(1)
0.2
ND(9)
ND(6)
ND(4)
ND(5)
ND(2)
0.7
2
5/13/85
5/13/85
5/13/85
5/13/85
5/08/85
5/13/85
5/13/85
5/13/85
5/13/85
5/13/85
5/13/85
5/13/85
5/13/85
5/13/85
5/13/85
5/13/85
5/13/85
5/13/85
5/13/85
5/13/85
5/13/85
5/13/85
5/13/85
ND = Not Detected
() = Lowest Detection Limit
= Concentration Reported as Part Per Quadrillion
-------
DOW CHEMICAL USA
MICHIGAN DIVISION ~ MIDLAND PLANT
c.
f~i*
NON-CONVENTIONAL/TOXIC POLLUTANTS — OUTFALL 031
PERMIT 0MI 0000868
TABLE 1
Monitoring Results - May, 1985
Phenol
2,4-Dichlorophenoxyacetic
acid
Bis(2-chloroethyl)ether
Chloroform
2,3,7,8-Tetrachloro-
dibenzo-p-dioxi n
1,1,2,2-Tetrachloroethane
Tetrachloroethylene
1,1,2-Trichloroethane
Pentachlorophenol
1,3-Dichlorobenzene
1,4-Dichorobenzene
1,2,M-Trichlorobenzene
Methylene Chloride
2-Chlorophenol
2,4-Dichlorophenol
Naphthalene
1,1,1-Trichloroethane
Bromoform
Chlorobenzene
Carbon Tetrachloride
2,4,6-Trichlorophenol
1,2-Dichlorobenzene
Acrylonitrile
Monthly Daily Monthly Daily
Average Maximum Average Maximum
(Ibs/day) (Ibs/day) (ug/l> (ug/D
.7 .84
.058* .116* 19
.3 .4 2
— 2.1 ND(12)
6.3x10"7 7.4x10~7 3 PPQ
ND(7)
ND(9)
ND(7)
1.8 ND(5)
.2 .3 1.U
.1 .2 0.8
.5 .7 3
.9 ND(6)
ND(0.6)
ND(1)
- — NDC0.2)
1.8 ND(9)
2.5 ND(6)
ND(4)
— . ND(5)
ND(3)
.1 .2 0.7
.4 ND(2)
5
33
2
12
3 ppq
ND(7)
ND(9)
ND(7)
10
2
1
4
5
ND(.6)
ND(1)
0.2
10
14
ND(4)
ND(5)
ND(3)
1
2
Mass discharge measured at 031 a
-------
>OH CHEMICAL COMPANY
UOlAUO DIV
iIDLAND
563flOM6(fl I jlTn U L NUM8C (Hi
illPJ!8.0868_j L?6$I3 i_)
MONTHLY OPERATING REPORT FOR
THIS IS YOUH MONTHLY REPORT FOflM fOH
SEE REVERSE SIDE FOR RETURN MAIL
Pic tic complete and submit iwo copitl ol lint loim
at the end ol each month Thil report mull reach our
Laming oflicc by the 10th o( the month.
PART 1 - RETURN 70 DEPT OF NATURAL RESOURCES
02
• 4470 »'• • •<
4(1) t«»0
OOH CHEMICAL COMPANY
OUTFALL « 031
PROC,HASTES TO TITTABAHASSEE* R. 031
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JO/79
Date lorm v»«
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t HAVE PERSONALLY EXAMINED AND AM FAMILIAR W»TH THE INfOHMAllON SUBMITTED IN THIS DOCUMENT AND ALL ATTACHMENTS AND
INUIVIDUAIS IMMLUtATCtY HbU'ONMOit FOH OHfAINING 1H( INf (JMMAfiON, 1 BClltVf THAT THE (NfOftMATION IS TRUE, ACCtmAH. AND
SlGfJlFlC/sNf I'ENALllLS fOH SUOMITIING ^^^ INlOtiMAllON. llJCl UUiNU ll'lL C(JL"T*lUtLl IV Of I^NC AND IMMtlMJNMLNf
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-------
Summary of Results
(1) 2,3,7,8-TCDD was not detected in any of these Michigan sample
extracts. ACB-75 (received 02/08/79). Other tetrachlorodibenzo-
p-paradioxin (TCDD) isomers were detected.
(2) TCDD isomers were detected in DS-1 and DCW-2 based upon (a) capillary
column GC/HRMS multiple ion monitoring analyses - m/e 320, 322 and
chlorine isotope ratio; (b) capillary column GC/HRMS peak matching
analyses of m/e 320 at 8500 mass resolution in real time; and (c)
one of these TCDD isomers had the same exact mass and same GC
retention characteristics as a 1,3,6,8-TCDD standard (DS-1).
(3) The collection efficiency of the carbon filters for 2,3,7,8-TCDD is
unknown. Furthermore, the analytical extraction efficiency for
2,3,7,8-TCDD from carbon is not known. The limit of detection
for 2,3,7,8-TCDD was based on a. theoretical 100% collection and
extraction efficiency. The actual efficiency is not known.
(4) The carbon collection and analytical extraction efficiency must be
determined before such data could be fully utilized.
-------
»\
• r
I
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
ENVIRONMENTAL TOXICOLOGY DIVISION
HEALTH EFFECTS RESEARCH LABORATORY
DATE:
April 9, 1979
Results for Analyses of Environmental Samples from Michigan - Region V -
for 2,3,7,8 Tetrachlorodibenzo-p-dioxin (TCDD)
FROM: Edward 0. Oswald, Ph.D., Chief ^^LM^-^S- V>-
Analytical Chemistry Branch, ETD, HERL (MD-69)
T0: Mr. Karl E. Bremer, Toxic Substances Coordinator
U. S. EPA, Region V, 230 Dearborn St.
Chicago, Illinois 60604
THRU: F. Gordon Hueter, Ph.D., Director
Health Effects Research Laboratory (MD-51)
and
William F. Durham, Ph.D., Director
Environmental Toxicology Division (MD-66)
Attached you will find the results of analyses for samples of
water, sediment and carbon filters from Michigan - Region V - for
2,3,7,8-TCDD. These environmental samples were shipped from Michigan
to the EPA Pesticide Monitoring Laboratory (PML) at Bay St. Louis,
Miss, where these samples were extracted and prepared for GC/MS analysis.
The final purified extracts and appropriate controls then were
shipped to the Analytical Chemistry Branch in Research Triangle Park, NQ.
Upon receipt of the sample extracts, these analyses were carried out by
members, of the Analytical Chemistry Branch, ETD, HERL using high
resolution capillary column gas chroraatography interfaced with high
resolution mass spectrometry in the electron impact multiple ion moni-
toring mode.
In order to confirm the presence of 2,3,7,8-TCDD in these samples,
the analytical data must meet the criteria as outlined in the attached
Table 1. Attached you will find a summary of results for these
analyses and information on the general extraction and cleanup procedures
and the overall mass spectrometric techniques utilized for analysis of
2,3,7,8-TCDD
The results of these analyses were conveyed to you by phone on
5 March 1979.
This report completes the analyses for 2,3,7,8-TCDD on all environ-
mental samples received from EPA Region V by the Analytical Chemistry Bra
ETD, HERL.
Attachments
-------
APPENDIX B-4
PCOOs and PCDFs
1978 USEPA Study
-------
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-------
DOW CHEMICAL USA
MICHIGAN DIVISION -- MIDLAND PLANT
NON-CONVENTIONAL/TOXIC POLLUTANTS — OUTFALL 031
TABLE 2
Monitoring Resul ts — July, 1984
Concentration
pg/1 Her
Phenol
2,4-Dichl orophenoxy
acetic acid
Bis(2-chloroethyl )ether
Chloroform
2,3,7,8-Tetrachloro-
dibenzo-p-dioxin
1,1,2,2-Tetrachl oroethane
Tetrachl oroethyl ene
1,1,2-Trichl oroethane
Pentachlorophenol
1,3-Dichl orobenzene
1 ,4-Dichorobenzene
1 ,2,4-Trichl orobenzene
Methyl ene Chi oride
2-Chl orophenol
2,4-Dichl oro phenol
Naphthal ene
1 ,1 ,1 -Trie hi oroethane
Bromoform
Chi orobenzene
Carbon Tetrachl oride
2, 4, 6-Tric hi orophenol
1 ,2-Dichl orobenzene
Acryl onitril e
2
ND(2)
2
30
11 ppq
ND(6.4)
ND(6.4)
ND(9.1)
ND(6)
1
2
2
60
ND(0.5) '
ND(1)
0.3
ND(6.8)
ND(7.0)
ND(5.8)
15
ND(2)
2
ND(4.5)
Sampl e
Date
6/26/84
6/26/84
6/26/84
7/16/84
6/21/84
7/16/84
7/16/84
7/16/84
6/26/84
6/26/84
6/26/84
6/26/84
7/16/84
6/26/84
6/26/84
6/26/84
7/16/84
7/16/84
7/16/84
7/16/84
6/26/84
6/26/84
7/16/84
Concentration
ug/1 iter
2
6
2
30
10 ppq
ND(6.4)
ND(6.5)
ND(9.1)
ND(5)
2
1
2
30
ND(0.4)
1
ND(0.2)
ND(6.8)
ND(7.3)
ND(5.7)
9
ND(2)
1
ND(3.8)
Sampl e
Date
7/09/84
7/09/84
7/09/84
7/20/84
7/01/84
7/20/84
7/20/84
7/20/84
7/09/84
7/09/84
7/09/84
7/09/84
7/20/84
7/09/84
7/09/84
7/09/84
7/20/84
7/20/84
7/20/84
7/20/R4
7/09/84
7/09/34
7/20/84
-------
DOW CHEMICAL USA
MICHIGAN DIVISION -- MIDLAND PLANT
NON-CONVENTIONAL/TOXIC POLLUTANTS — OUTFALL 031
TABLE 1
Monitoring Resul ts — July, 1984
Phenol
2,4-Dichlorophenoxyacetic
acid
Bis(2-chloroethyl)ether
Chioroform
2,3,7,8-Tetrachloro-
dibenzo-p-dioxin
1,1,2,2-Tetrachl oroethane
Tetrachloroethyl ene
1,1,2-Trichl oroethane
Pentachl orophenol
1,3-Dichlorobenzene
1,4-Dichorobenzene
1,2,4-Trichlorobenzene
Methyl ene Chloride
2-Chlorophenol
2,4-Dichl orophenol
Naphthalene
1,1,1-Triehi oroethane
Bromoform
Chi orobenzene
Carbon Tetrachloride
2,4,6-Trichl orophenol
1,2-Die hiorobenzene
Acryl onitril e
Monthly
Average
(Ibs/day)
0.3
0.002*
0.3
4.9
2.2xlO"6
0.2
0.3
0.4
7.4
0.1
2.0
0.3
Daily Monthly
Maximum Average
(Ibs/day) fug/day)
0.4 1.5
0.005* 3.5
0.4 2
5.9 30
2.5xlO~6 10.5 ppq
ND(6.4)
ND(6.5)
ND(9.1)
ND(6)
0.4 1.5
0.4 1.5
0.4 2
10.2 45
ND(0.5)
1
0.1 0.3
ND(6.8)
ND(7.3)
ND(5.8)
2.5 12
ND(2)
0.4 1.5
ND(4.5)
Daily
Maximum
(yg/day)
2
6
2
30
11 ppq
—
--
—
--
2
2
2
60
—
1
0.3
--
._
--
15
2
—
-------
i.i".
»,'
i
»«OOH CHEMICAL COHPANr
MIDLAi/D D1V
MIDLAND
48610
AOim NUM«I«~J in**! »UWM»-1 ju -MU „„„„,
s 63009 I L{U£Lyo0668J L56.0JL3B_
MONTHLY OPERATING REPORT FOR
llllS IS VUUH MUNI ML V IUI-UII1 f OHM * Oil
SLC IICVLnSL ilUE TOR (ICTUnw MAI I.
Pkjic couiiilou- dim iulimil two coi*iti el itui loim
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PAHT i - RETURN TO DEPT OF NATURAL RESOURCES
DOH CMEMICAL COMPANY
OUTFALL J Oil
PROC.HASTES TO T 1 TTABAHASSEE' R. 031
PERMIT EXPIRATION} 10/79
Dale form wat
pitnted
p K KT-1
L_61_/10/29_J
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-------
DOW CHEMICAL USA
MICHIGAN DIVISION — MIDLAND PLANT
C
NON-CONVENTIONAL/TOXIC POLLUTANTS — OUTFALL 031
PERMIT 0MI 0000868
TABLE 2 - Page Two
Monitoring Results March, 1985
Concentration Sample
u g/liter Date
Phenol
2,U-Dichlorophenoxy
acetic acid
Bi s(2-chloroethyl)ether
Pentachlorophenol
1,3-Dichlorobenzene
1,U-dichorobenzene
1,2,4-Trichlorobenzene
2-Chlorophenol
2,4-Dichlorophenol
Napthalene
2,4,6-Tr ichlorophenol
ND(0.8)
3/18/85
29
2
25
ND(0.7)
3
ND(0.8)
ND(0.7)
ND(1)
ND(0.3)
ND(1)
3/18/85
3/18/85
3/18/85
3/18/85
3/18/85
3/18/85
3/18/85
3/18/85
3/18/85
3/18/85
1,2-Dichlorobenzene
3/18/85
ND = Not Detected
() = Lowest Detection Limit
* = Concentration Reported as Part Per Quadrillion
-------
•*l/-r< CHEMICAL COHPAHT
MIDLAND DIV
MIDLAND
MONTHLY OPERATING REPORT FOR MtxrcU 1985T
02
I Hfi&<<0
THIS is YOUR MONTHLY furom foni.i ton
SEE REVERSE SIDE FOR RETURN MAIL
DOH CHEMICAL COMPANY
OUTFALL « 031
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-------
»«OOK .EPICAL COHPAKY
DIV
r.I
sj [$60138 I
MONTHLY OPE^TING REPORT FOR
THIS li YOUII MONIIUY miOIll ( OMI.I I OR
SEE nCVEIISE SIDE COFl nETUIUJ MAIL
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DDH CHEMICAL
OUTFALL I 031
PROC.UASTEB'TO TUTABAHAS3EE R. Oil
PERMIT EXPIRATION: 10/79
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pnnitd
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DATE
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lU.°IUL 1 AM AWARF THAT THUd .(fa ilGNIF K,iNT PENALTIES (OR SUBMlPirjC, (AlSE- INFORMATION. INCLUDING THE POSSIBILITY OF FINE AND IMPRISONMENT
-------
,. CHEMICAL COMPANY
M1DLAUD DIV
MIDLAND '-'I 16610
IIAOIIIV riuuiiK I [rtiiMii NuwilRI j»->»u NUMII«~|
l_56.40..Q4 I LK IMP. 086 B J [j60.1 3_B._|
MONTHLY OPLv'UTING REPORT FOR VAo-rcW
THIS IS YOUR MONTHLY RCPORT FOIIM FOR
SEE REVERSE SIDE FOR RETURN MAIL
Pk'iitc complete and iulimil two copies ot llm loim
dl the end ol each month This report rnuil rL'jch our
Ljnung ollicc by the 10th ol the munih
PART 1 - RETURN TO DEPT OF NATURAL RESOURCES
DOW CHEMICAL COMPANY
OUTFALL I 031
PROC.HASTES TO TITTABAHASSEE' R. 031
PERMIT EXPIRATlONj
10/79
Dole fo L L
' L 1 1
1 1
L..I 1. J .1 1
U*'B£R r-YS HEIOIUiNG
DIAL S-MPlES TAKEN |
AYSEx,i0,-,rp
fVCI-./NCH
1 1
J 1
-
1
—
DAILY AVG
HIGH
LOW
t
I
VtflAGE
AXiMUM
Ui.'flER D
OTAL SAK
i I i l
i 1 l
i 1 i
1
tYS REPORTING
PLES TAKEN
AYS EXCEECJINC MAXIMUM
1 1
ut'"
1
DUP PUNCH i's «i
OISEF
MAXI
0 '
i
i VAT 1 01^
0 TO'
MUMT
DAILY AVG.
o
a
t
i
0
0
o
0
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0 1
6
O
O
o
o
<
«
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LOW
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0
o
0
0
0
n
AVERAGE
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UMDER D
AYS EXCE
VC MAK V
01
1
i i ii
10
• i i i .1 t. iP
hYS REPORTING
1~1~
EDING MAXIMUM . .K
r PUNCH I" »il
1
—
(
DAILY AVG
1
J
AVE
tAGE
MAXIMUM
UM6ER O
OTAL SAh
HIGH
LOW
_L L J 1
' 1
i i l l 1 i
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kYS REPORTING
PLES TAKEN
AYS EXCCEOING MAXIMUM
*c M" vioc _L_i a.
1 L_J_
l__j_i_
i l
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Consumers Power
Intake cfs
• • r
DAILY AVG
o
o
Ck
0
0
o
o
o
0
0
0
o
0
o
p
0
0
o
p
o
rt
a
0
a
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,
LOW
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1 1 1
1
NUMBER DAYS REPORTING
OTAL SAMPLES TAKEN
AYS EXCEEDING MAXIMUM
~ — "*" VlOt _i 1. ^J
DUP PUNCH JJ» 1
_
L_
L_
i_JO_
1 1
1 1 1
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i
-
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c
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0 .
0
o
—
_&
0
-fl- -
a
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0
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----
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>
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o
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o
o
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MAXIMUM
UMBER D
--
—
.
..:
i j i
L. J .
A .1
1 1-
AYS HE lOMMNG
-------
DOW CHEMICAL USA
MICHIGAN DIVISION -- MIDLAND PLANT
NON-CONVENTIONAL/TOXIC POLLUTANTS -- OUTFALL 031
PERMIT *MI 0000868
TABLE 1
MonUonng ResuHs - £ebruary^_1985
Phenol
2,4-Dichlorophenoxyacetic
acid
Bis(2-chloroethyl)ether
Chloroform
2,3,7,8-Tetrachloro-
dibenzo-p-dioxin
1,1,2,2-Tetrachloroethane
Tetrachloroethylene
1,1,2-Trichloroethane
Pentachlorophenol
1,3-Dichlorobenzene
1,4-Dichorobenzene
1,2,4-Trichlorobenzene
Methylene Chloride
2-Chlorophenol
2,4-Dichlorophenol
Naphthalene
1,1,1-Trichloroethane
Bromoform
Chlorobenzene
Carbon Tetrachlonde
2,4,6-Trichlorophenol
1,2-Dichlorobenzene
Acrylonitrile
Monthly
Average
iibs/dayj^
.3
.035*
.7
5.5
1.7xlO"6
2.0
2.9
--
4.6
.6
1.2
1.2
5.4
.2
.7 ~~
.08
5.2
13.5
.6
14.4
1.0
2.2
.5
DaTTy
Maximum
(Ibs/dayJ
.4
.070*
.8
6.6
2.3xlO"6
2.7
4.0
—
7.3
.8
1.3
1.5
7.2
.3
1.0
.08
7.5
31.7
1.0
21.6
1.8
2.8
.6
Monthly
Average
. I 3/l]__
2
50
5
38
13ppq
14
20
ND(8)
32
4
8
9
37
1.1
5
.5
36
94
5
100
7
15
4
DaTly
Maximum
— i-9/il
3
88
6
47
17ppq
19
28
--
50
6
9
11
50
2
7
.6
52
220
7
150
13
20
4
Mass discharge measured at 031a
-------
DOW CHEMICAL USA
MICHIGAN DIVISION -- MIDLAND PLANT
NON-CONVENTIONAL/TOXIC POLLUTANTS -- OUTFALL 031
PERMIT tfMI 0000868
TABLE 2
Concentration
u q/1 iter
1
22
3
23
17ppq*
ne 19-
28
ND(8)
16
4
9
9
50
ND(0.7)
1
0.5
23
220
7
150
2
17
4
Sample
Date
1/21/85
1/21/85
1/21/85
1/21/85
1/23/85
1/21/85
1/21/85
1/21/85
1/21/85
1/21/85
1/21/85
1/21/85
- 1/21/85
1/21/85
1/21/85
1/21/85
1/21/85
1/21/85
1/21/85
1/21/85
1/21/85
1/21/85
1/21/85
Concentration
u g/1 iter
3
88
6
47
8ppq*
15
21
ND(7)
29
6
9
11
22
2
7
0.6
52
50
5
57
13
20
4
Sample
Date
2/4/85
2/4/85
2/4/85
2/4/85
2/4/85
2/4/85
2/4/85
2/4/85
2/4/85
2/4/85
2/4/85
2/4/85
2/4/85
2/4/85
2/4/85
2/4/85
2/4/85
2/4/85
2/4/85
2/4/85
2/4/85
2/4/85
2/4/85
Phenol
2,4-Dichlorophenoxy
acetic acid
Bis(2-chloroethyl)ether
Chloroform
2,3,7,8-Tetrachloro-
dibenzo-p-dioxin
1,1,2,2-Tetrachloroethane
Tetrachloroethylene
1,1,2-Trichloroethane
Pentachlorophenol
1,3-Dichlorobenzene
1,4-Dichorobenzene
1,2,4-Trichlorobenzene
Methylene Chloride
2-Chlorophenol
2,4-Dichlorophenol
Naphthalene
1,1,1-Trichloroethane
Bromoform
Chlorobenzene
Carbon Tetrachloride
2,4,6-Trichlorophenol
1,2-Dichlorobenzene
Acrylonitrile
NO = Not Detected
( ) = Lowest Detection Limit
* = Concentration Reported as Part Per Quadrillion
-------
DOW CHEMICAL USA
MICHIGAN DIVISION -- MIDLAND PLANT
NON-CONVENTIONAL/TOXIC POLLUTANTS -- OUTFALL 031
PERMIT #MI 0000868
TABLE 2 - page two
Phenol
t!2Dli2![lD2 B£su1ts February, 1985
Concentration SaiiipTe"
2/18/85
2,4-Dichlorophenoxy
acetic acid
Bis(2-ch1oroethyl)ether
Chloroform
40
5
44
2/18/85
2/18/85
2/18/85
2,3,7,8-Tetrachloro-
dibenzo-p-dioxin
1,1,2,2-Tetrachloroethane
Tetrachl oroethylene
1,1,2-Trichloroethane
Pentachlorophenol
1,3-Dichlorobenzene
1,4-Dichorobenzene
1,2,4-Trichlorobenzene
Methylene Chloride
2-Chlorophenol
2,4-Dichlorophenol
Naphthalene
1,1,1-Trichloroethane
Bromoform
Chlorobenzene
Carbon Tetrachloride
2,4,6-Trichlorophenol
1,2-Dichlorobenzene
-Acrylonitrile
2/18/85
11
ND(8)
50
2
6
6
39
0.9
6
0.5
33
12
ND(5)
92
5
9
3
2/18/85
2/18/85
2/18/85
2/18/85
2/18/85
2/18/85
2/18/85
2/18/85
2/18/85
2/18/85
2/18/85
2/18/85
2/18/85
2/18/85
2/18/85
2/18/85
2/18/85
NO = Not Detected
M = lowpst OptPFtion limit
-------
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618
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ILY AVG
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70
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(j 9
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70
70
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7.0
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7.0
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70
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7.J.
7 /
7 '
1,' .
71
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7.0
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f * '
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I
1 CISTirY UNDER PENALTY OF LAW THAT 1 HAVE PERSONALLY EXAMINED AND AM FAUfllAR WITH THE INFORMATION SUBMITTED IN THIS DOCUMENT AND ALL ATTACHMINTS A
THA", BASED ON MY INQUIRY OF THOSE INDIVIDUALS IMMED)*TEtV''ptSF10"SIBlE IOf( OBTAINING THE INFORMATION. 1 BEUEVE THAT THE INFORMATION IS TRUE. ACCURATE. A'
COk'IHE 1 AM AWARE THAT THERE ARE SIGNlWBANT PENAl^lUr F/MSUfMirtjNa.rAttE (INFORMATION. INCLUDING THE POSSIBllITT OF FINE AND IMPRISONMENT
-------
1 >
t,
MIDLAND OIV
Ml PL ANO
'I »06<|0
THIS is voun MONT MI vntiniirmnMion
SFE EltVEFlSE SIOE FOP FIETUFIN MAIL
DOH CMFHIC»L
OUTFALL I 031
PROC. HASTES TO TITUBAHASSEE' R. OJ1
PERMIT EXPIRATIOHj 10/79
«.
i'Hic'f,
'tl^
-------
•j
\.
•UUH lnc.rilt.nL
HIDUUD ftiv
MIDLAND
.•'I /I0610
LjU
fAC'l'r* HUM*CI» 1 iPIMM.t NUMfIN ~1 ! •' 1MI Nu'-»ll(0
569.0.0<1 I Lbinj»MB6_8J |JAQ138_
THIS IS VOl/fl MONIHtV ftf I'ttni I OHM f O't
SEE REVERSE SIDE FOR RETURN MAIL
Pk-iiie comiilclc and iuliT>H two copitl of Ihn loim
•t the end ol «*cli monlh Tim frpofl muu teach ou'
Lanung office by Ihs tOih of the month
PART 1 - RETURN TO DEFT OF NATURAL RESOURCES
DOW CI'fMICAL COMPANY
OUTFiU I Oil
PRDC.WASTES TO TITTAn*HASSEE ' R. 03]
PERHlT EXPlRATIONi
10/7?
D.ilt Ir-m
pr.nl.t)
ei/io/a?
PARAM
NAME
UNITS
LIMIT
DATE
2
3
i
5
6
7
e
9
0
1
2
3
4
5
6
7
s
9
20
-21
21
23
2<
25
31616>
COlIFORH-FECAl'
" ' HF/l&OHL'
i
t
L
DAILY AVG
t
1
1
I
0
MAXIMUM
100
HIGH
J3r«k
1
1
. 1
3 1
1
1
26
27 1
28 1
29 j j 0
30
31
MONTHly
SUMMARY
AVEHAGC
VAX'MUM
,.„_„„
MC.INIIIWG DATE
HIDING OATI
_J !_
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1 J_
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L_J|
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101 1 I 1 I 1
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1
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0
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6
0
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0
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0
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c
o
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1 CEKIIFY UNHEO PIMALTY OF LAW THAT 1 HAVE I'EHSONAyLLY EXAMIIJED .ANL1 AM FA'.vyf/q WITH THE INIO"MA1ION S 'H\MTTEO IN TH S DOCUMINT ANt) ALL ATTACHMINIS
THAT. OASEO ON MY INQUIRY OF THOSE INDIVIDUALS IWinEDIATELY, llTsrpN'^'Ptr TO'/JIWIAIMING THE INFORM*' ON 1 BtllfVE THAT THE INIOK'/ATION IS IPL'F ACCUH01F.
COMriETE 1 AM AWAHE THAT THERE ABE SIGNIFICANT /JtBAlTIES 'tlt/^n!>yyj'''9J^ifl INFOnMATION. INCLUDING THE rOSS'BllirY OF FIUE AND IWrniSOMMFNT
-------
y y.
a. p^_
DOW CHEMICAL USA
MICHIGAN DIVISION — MIDLAND PLANT
NON-CONVENTIONAL/TOXIC POLLUTANTS — OUTFALL 031
PERMIT #MI 0000868
TABLE 1
Monitoring Results --January, 1985
Phenol
2 ,4-Di chl orophenoxyaceti c
acid
Bis(2-chloroethyl )ether
Chloroform
2,3,7,8-Tetrachloro-
dibenzo-p-dioxin
1,1,2 , 2-Tetrachl oroe thane
Tetrachl oroethyl ene
1 , 1 ,2-Trichl oroethane
Pentachl orophenol
1 ,3-Oi chl orobenzene
1 ,4-Di chorobenzene
1 ,2 ,4-Trichl orobenzene
Methyl ene Chloride
2-Chl orophenol
2, 4-Di chl orophenol
Naphthalene
1,1,1-Tri chl oroe thane
Bromoform
Chl orobenzene
Carbon Tetrachl oride
2, 4, 6 -Tri chl orophenol
1,2-Di chl orobenzene
Acryloni tri 1 e
Monthly
Average
(Ibs/day)
.4
.0004*
.6
2.3
4.8xlO"6
3.5
5.1
-__
4.6
.9
1.8
1.9
--
--
.3
.1
2.7
31.4
--
11.9
--
3.7
2.4
Daily
Maximum
(Ibs/day)
.4
.0004*
.7
3.3
e.ixio"6
5.0
7.7
--
5.8
1.5
2.9
3.5
12.1
--
.4
.2
3.3
54.0
2.2
18.6
.9
6.8
3.9
Monthly
Average
(ug/1)
2
25
3
12
19ppq
18
25
ND(8)
25
4
9
9
ND(6)
ND(0.6)
2
.5
14
149
ND(13)
58
ND(1)
18
14
Daily
Maximum
(u g/1 )
2
48
3
15
24ppq
23
35
--
34
7
13
16
55
--
2
.8
15
246
10
85
5
31
23
Mass discharge measured at 031a
-------
DOW CHEMICAL USA
MICHIGAN DIVISION — MIDLAND PLANT
NON-CONVENTIONAL/TOXIC POLLUTANTS — OUTFALL 031
PERMIT jfMI 0000868
TABLE 2
Monitoring Results --January, 1985
Concentration
u g/1 i ter
Phenol
2,4-Dichlorophenoxy
acetic acid
Bis(2-chloroethy1 )ether
Chloroform
2,3,7,8-Tetrachloro-
dibenzo-p-dioxin
1,1, 2 ,2-Tetrachl oroe thane
Tetrachl oroethyl ene
1 ,1 ,2-Trichl oroethane
Pentachlorophenol
1 ,3-Di chl orobenzene
1 ,4-Dichorobenzene
1, 2, 4-Tri chl orobenzene
Methylene Chloride
2-Chlorophenol
2,4-Dichlorophenol
Naphthalene
1,1,1-Tri chl oroe thane
Bromoform
Chl orobenzene
Carbon Tetrachl oride
2 ,4 ,6-Tri chl orophenol
1, 2 -Di chl orobenzene
Acrylonitrile
2
2
3
8
24ppq*
12
15
ND(9)
34
1
4
2
ND(6)
ND(0.6)
1
0.2
12
52
MD(13)
30
5
4
23
Sampl e
Date
12/24/84
12/24/84
12/24/84
12/24/84
12/21/84
12/24/84
12/24/84
12/24/84
12/24/84
12/24/84
12/24/84
12/24/84
12/24/84
12/24/84
12/24/84
12/24/84
12/24/84
12/24/84
12/24/84
12/24/84
12/24/84
12/24/84
12/24/84
Concentration Sample
u g /liter Date
2
48
3
15
14ppq*
23
35
ND(8)
16
7
13
16
55
MD(0.9)
2
0.8
15
246
10
85
ND(l)
31
4
1/7/85
1/7/85
1/7/85
1/7/85
1/2/85
1/7/85
1/7/85
1/7/85
1/7/85
1/7/85
1/7/85
1/7/85
1/7/85
1/7/85
1/7/85
1/7/85
1/7/85
1/7/85
1/7/85
1/7/85
1/7/85
1/7/85
1/7/85
NO = Not Detected
( ) = Lowest Detection Limit
* = Concentration Reported as Part Per Quadrillion
-------
\ I
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PART i - nrrunw TO Drrr OF NATUHAI nrsouncis
DOW CHFMICAL COMPANY •
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1 CER1IFY UNDER PENALTY OF LAW THAT 1 HAVE PEnSI/NALLY EXAMINED AND AM FAMILIAR WI1H 1HE INIOn^AllON
THAT BASED ON MY INQUIRY OF THOSE INWyllDIIALS /MMEDIATELY/IESPONSmiE (OH OBTAINING THE INFORMATION.
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\. i r...
DOW CHEMICAL USA
MICHIGAN DIVISION — MIDLAND PLANT
NON-CONVENTIONAL/TOXIC POLLUTANTS ~ OUTFALL 031
PERMIT #MI 0000868
TABLE 1
Mon i tor i no Results —December, 1984
Phenol
2,4-D ich lorophenoxyacetic
acid
B i s ( 2-ch 1 oroethy 1 ) ether
Ch loroform
2,3,7, 8-Tetrach 1 oro-
dibenzo-p-dioxi n
1,1,2, 2-Tet r ach 1 oroethane
Tetrachl oroethy iene
1,1, 2-Tr i ch 1 oroethane
Pentach 1 oropheno 1
1 ,3-D i ch lorobenzene
1 ,4-Dichorobenzene
1 ,2,4-Tr ich lorobenzene
Methylene Chloride
2-Ch 1 oropheno 1
2,4-0 ich 1 crop hen 1
Naphthalene
1 » 1 , 1 -Tr i ch 1 oroethanp
Brcmoform
Ch lorobenzene
Carbon Tetrach lor i de
2,4,6-Tr ich lorophenol
1 ,2-D i ch lorobenzpne
Acrylonitri I 9
Monthly
Average
(Ibs/dey)
.3
.001*
.6
—
2.9x10~6
1 .4
2.0
—
3.6
.2
—
.5
6.2
—
—
—
2.0
—
—
13.5
.6
—
.4
Dai ly
Maximum
(Ibs/day)
.4
.001*
.6
2.5
4.1x10"6
1 .6
2.1
—
3.8
.2
.2
.6
7.4
—
—
—
2.1
—
—
22.1
.8
—
.4
Monthly Dai ly
Averaoe Maximum
u( a/1) u( g/I)
2 2
ND(1.4)
3 3
ND(7) 13
12.5 ppa 16 ppa
8 8
11 11
ND(8)
19 20
1 1
ND(0.5) 1
2 3
33 38
ND(0.6)
ND(1)
ND(0.2)
10 11
ND(6)
ND(10)
71 116
3 4
ND(0.6)
2 2
w
Mess discharge measured at 03la
-------
C
DOW CHEMICAL USA
MICHIGAN DIVISION — MIDLAND PLANT
NON-CONVENTIONAL/TOXIC POLLUTANTS — OUTFALL 031
PERMIT 0MI 0000868
TABLE 2
Mon
Concentration
uQ/l l+er
1
ND(1 .6)
3
13
9 ppo*
10 ppq*
ne 7
10
NTH8)
20
1
1
2
27
NDC0.6)
ND(1)
ND(0.2)
10
MD(6)
ND(10)
116
2
ND(0.6)
2
itorina Results — December,
Sample Concentration
Date up/I i ter
11/26/84 2
11/26/84 NDC1.3)
11/26/84 3
11/26/84 ND(7)
12/08/84 16 ppa*
11/20/84
11/26/84 8
11/26/84 11
11/26/84 ND(8)
11/26/84 18
11/26/84 1
11/26/84 ND(0.5)
11/26/8^ 3
11/26/84 38
11/26/84 ND(0.7)
11/26/84 ND(1)
11/26/84 NDC0.2)
11/26/84 11
11/26/84 NDC6)
11/26/84 NDC11)
11/26/84 26
11/26/84 4
11/26/84 ND(0.6)
11/26/84 2
1984
Semp le
Date
17/10/84
12/10/84
12/10/84
12/10/84
12/20/84
12/10/84
12/10/84
12/10/84
12/10/84
12/10/84
12/10/84
12/10/84
12/10/84
12/10/84
12/10/84
12/10/84
12/10/P4
12/10/84
12/10/84
12/10/84
12/10/84
12/10/84
12/10/84
Phenol
2,4-Dichlorophenoxy
acetic acid
B i s(2-chIoroethyI)ether
Chloroform
2,3,7,8-TetrachIoro-
d ibenzo-p-dioxi n
1,1,2,2-TetrachIoroethane
Tetrachloroethy!ene
1,1,2-Tr i chIoroethane
PentachIorophenoI
1 ,3-Dichlorobenzene
1,4-Dichorobenzene
1,2,4-Tr ichlorobenzene
Methylene Chloride
2-ChIoropheno1
2,4-DichIorophenoI
Naphtha Iene
1,1,1-Tri chIoroethane
Bromoform
Chlorobenzene
Carbon Tetrpchloride
2,4 ,6-Tr ichIoropheno i
1 ,2-D i chlorobenzene
Aery Ion i tr i le
ND = Not Detected
( ) = Lowest Detection Limit-
* = Concentration Reportpd as Part Per Quadrillion
-------
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(AULY msi><*SiuiE mu OBTAINING THE iNfORMATion. BEUEVE THAT THE iNfORMAiioN is i«ut. ACCUHAIE AND
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-------
• «DOH CHEMCAL COHPAIir
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111 »«r
A1ION SUBMITTED IN THIS OOCUMENI AND AIL ATTAtHMlHii ' '"
MION. 1 BELIEVE MAT THE INIORMATION IS IRUE ACCUIlAli A JO
G THE POSSIBILITY OF IINE AND IMPRISONMENT.
-------
(
v. i
•
if-
-•DOH CHEMICAL COMPANY
MIDLAND DIV
MIDLAND '•'' «66«0
,„-„„-»,-,.,. I (.,«. *«.. —I !-.--.«, «»«.-j
56(001 J ( r-HOVOOB&S J I 5601 Jp I
;HLY OPERATING RLPORT FOR
>ltS IS VOUH MUNIHLY HCrOlU * OHM I Ofl
SEE I1EVCIISC SIDE fOII flETUMN MAIL
Pkju- loiitpltie ••'"' «if»nm uvo toinii ol ihii loim
jl ihc end ol cjcli iniiiilh Th.i upon nmil n jch out
l.intiliijulliiFliy ll"1 lOlhol U» lliiinlli
PART 1 - IILIUflN 10 Did Ol NAIUUAL HtSOUIICCS
DOW CHEMICAL COMPANY
OUTFALL I OJ!
PROC.HASTES TO T I T T Afi A WASSEE R . OJ1
PERMIT EXPIRAT10NI 10/79
. . ... J
I'AMAM
NAME
UNITS
LIMIT
OATt
. 1
2
3
4
5
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B
9
10
II
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13
14
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19
20
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24
25
26 J
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30
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1 | DAILY AVG
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NUMBER UAfS RtKJRIiNG [ f{
TOTAL, SAMMIES TAKEN [ ( ^
DATS txcUDiNC rtxir-'unf j j6
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THAT BASED ON MY INOU
COMflETE 1 AM AWAHE TH
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1 1
1 1
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TOTAL SAMPLES TAKEN j ( |
DAYS [XCEEOING MAXIMUk^ | |
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OF LAW THAT 1 HAVE PERSON
BY OF THOSE J'llJIVIOUALi IJ/
AT THERE Anf(^BNIFICAl«r Ut,
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MA
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TOTAL SAMPLES TAMN j , ,
DAYS f KCEtUING MAXtMU^ , |
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LIAR WITH THE INFORMATION
OBTAINING THE INFORMATION
/^FORMATION, INCLUDING THE
'
Consumers Power
Intake
1
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r,
r
/
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DATS {XCUDlNG MAXIMUI^
cfs_
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1_ 1C
.1 J
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Our PUNCH i'* MI
SUBMIlltD IN THIS OOCUMEN
BELIEVE THAT THE INFOHMA
possioiLirv Of FINE AND IMP
(
l
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81m
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^
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fs
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1
fe:
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1 . i
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AND ALL AHACHMI MS AHO
TlON IS TRUE ACLUKME A'(O
Hr ON WENT
'5 |
mm
r" ; i ;. J i ',
wm
ci«iuiuii
-------
DOW CHEMICAL USA
MICHIGAN DIVISION -- MIDLAND PLANT
NON-CONVENTIONAL/TOXIC POLLUTANTS — OUTFALL 031
PERMIT #MI 0000868
TABLE 1
Monitorina Results —November,
Phenol
2,4-Dichlorophenoxyacetic
ac i d
B i s(2-ch1oroethy I )ether
Chloroform
2,3,7,3-TetrachIoro-
dibenzo-p-dioxi n
1,1 ,2,2-Tetrachloroethane
TetrachIoroethyIene
1 ,1 ,2--Trich loroethane
PentachlorophenoI
1,3-Dichlorobenzene
1 ,4-Dichorobenzene
1,2,4-Trichlorobenzene
Methylene Chloride
2-Chlorophenol
2,4-Di chI orophen I
Naphthalene
1 ,1 ,1-Tr ichloroethane
Brcrroform
Chlorobenzene
Carbon Tetrachloride
2,4 ,6-Tr ichlorophenol
1 ,2-D i chlorofapnzene
Aery Ion itr iIe
Month ly
Averaae
(Ibs/day)
.2
.028*
.4
1 .2
1 .Ox10~6
—
1 .0
—
3.1
.1
—
.3
5.5
—
—
—
—
~~
10.9
—
—
Dai ly
Maximum
(Ibs/day)
.3
.054*
.5
1 .5
2.0x10~6
.5
1 .3
—
4.7
.1
.2
.3
7.0
—
—
—
1 .3
_ —
15.4
.5
.1
__
Mon+h I y
Averaae
W'l )
2
ND(1 .8)
3
9
12.5 ppa
ND(7)
7
ND(8)
22
1
NDC0.5)
2
45
ND ( 0 . 6 )
ND(1 )
ND ( 0 . 2 )
ND(7)
NDU)
77
ND(2)
NO ( 0 . 7 )
ND(2)
Dai ly
Max imum
(uc/n
2
—
3
q
1 6 ppa
5
8
—
29
1
1
2
64
—
—
—
12
—
95
3
7
—
Mass discharge measurpd at 031a
-------
DOW CHEMICAL USA
MICHIGAN DIVISION ~ MIDLAND PLANT
NON-CONVENTIONAL/TOXIC POLLUTANTS -- OUTFALL 031
PERMIT AMI 0000868
TABLE 2
MonitprIng Results — November, 1984
Phenol
2,4-D i chIorophenoxy
acetic acid
Bis(2-chloroethyl)ether
Chloroform
2,3,7,8-TetrachIoro-
d i benzo-p-d i ox i n
TetrachIoroethyIene
1,1,2-Trichloroethane
Pentach1orophenoI
1,3-Dichlorobenzene
1,4-Dichorobenzene
1,2,4-Trichlorobenzene
Methylene Chloride
2-Chlorophenol
2,4-Dichlorophenol
Naphtha Iene
1 ,1 ,1-Trichloroethane
Bromoform
Chlorobenzenp
Carbon Tetrachloride
2,4 ,6-Tr ichlorophenoI
1,2-Di chlorobenzene
Aery ion i tr iIe
Concentration
ug/l iter
2
ND(1 .9)
3
Q
8.9 ppa*
ne ND(7)
8
NJpm
29
1
1
2
25
ND(0.7)
ND(1)
ND(0.2)
ND(7)
ND(8)
ND(3)
95
3
ND(0.7)
ND(2)
Samp 1 e
Date
10/29/84
10/29/84
10/29/84
10/29/84
10/22/84
10/29/84
10/29/84
10/29/84
10/29/84
10/29/84
10/29/84
10/29/84
10/29/84
10/29/84
10/29/84
10/29/84
10/29/84
10/29/84
10/29/84
10/29/84
10/29/84
10/29/84
10/29/84
Concentration
u g/t iter
1
NDU .6)
2
8
16 ppa*
5
6
ND(8)
14
1
NDC0.5)
2
64
ND(0.6)
NDC1)
ND(0.2)
12
ND(6)
NDU)
59
ND(2)
1
ND(2)
Samp 1 e
Date
11/12/84
11/12/84
11/12/84
11/12/84
11/05/84
11/12/84
11/12/84
11/12/84
11/12/84
11/12/84
11/12/84
11/12/84
. 11/12/84
11/12/84
11/12/84
11/12/84
11/12/84
U/12/84
1 1/12/84
11/12/84
11/12/84
11/12/84
11/12/84
ND = Not Detected
( ) = Lowest Detection Limit
* = Concentration Reported as Part Per Quadrillion
-------
lMi^iili^ ; ., • -
'vs.:-
C»ICt;ICAL CUI'.PAHY
K.JDLAtiD DIV
r.l 40640
HI 00 0.0.8<>R
j I:*, it AII wuvtiinn
MONTHLY OPERATING REPORT FOR
mis is VOUM uoiviitiY ruiom runu ron
SEE IIEVEIISE SIDt FOH HCTUIIN MAIL
Pkjic ci»ii|ik'li: jnrt tulMiin iwu cu|i.i-i uf ilut luifn
«l (lit end (>l L.*ch month. Tint it|tuf t niuti u-«ch oui
(-..1111,9 oilILC by ihc lOih ul ilic- month.
PART 1 - RETURN TO DEPT OF NATURAL RESOURCES
V. [
• f
DOW CHEMICAL
OUTFALL I fi3l
PROC,WASTES'TO TITTAGAHASSEE: R. 031
PERMIT EXPIRATION! 10/79
DJIC loirn wjj
pnnlcd
I Tl M. !>.,
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MIN , i j
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-------
*OOH CHEMCAL COMPANY
MIDLAND OIV
MJl'LAfJD -I flfl&ifO
1 TfACtklTr MUMbt* j 1>1MM>1 NUMbfJII JO.TIAU NUMBIA
J[5&000«..J LlIfi.QflQ86lJ '.5601 ?8^_
f ,1
*J« - •
MONTHLY OPERATING REPORT FOR
IHIS IS VOUH MONTHLY RtronT f OHM I UK
SEE REVERSE SIDE FOR RETURN MAIL
Plcaic complete und submit two copies ol this loim
bi the end ol t*ch month This rL'iuirl must nach our
Laming ollice by the lOthol the month.
PART 1 - RETURN TO DEPT OF NATURAL RESOURCES
l98-<
1
02
• 4<70 ••• I II
*D)too
DOH CHEMICAL COMPANY
OUTfALL J 051
PROC.HASTES'TO T ITTABAHASSEEi R. Oil
PERMIT EXPIRATION! 10/79
Dale loim w«
printed
p.£to oTT
LJ.1,£10Z2*
z
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TE
-
. OO.C11 | 00095
TEMP-HATER
f:
1
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OUTFALL' I 031
PROC.HASTES TO TITTABAHASSEE' R. 031
PERMIT EXPIRATIONI 10/79
Dale loim was
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,r
DOW CHEMICAL USA
MICHIGAN DIVISION — MIDLAND PLANT
NON-CONVENTIONAL/TOXIC POLLUTANTS — OUTFALL 031
PERMIT #MI 0000868
TABLE 1
Monitor!no Results — October, 1984
Phenol
2,4-D i chIorophenoxyacetIc
acid
B i s(2-chIoroethy1)ether
Chloroform
2,3,7,8-Tetrachloro-
dibenzo-p-d ioxi n
1,1,2,2-Tetrachloroethane
TetrachIoroethyIene
1,1,2-Tr ichloroethane
Pentachlorophenol
1,3-Dichlorobenzene
1,4-Dichorobenzene
1,2,4-Trichlorobenzene
Methylene Chloride
2-Chlorophenol
2,4-Dichlorophenol
Naphthalene
1,1,1-Trichloroethane
Bromoform
Chlorobenzene
Carbon Tetrachloride
2,4,6-Tr ichlorophenol
1,2-D i chIorobenzene
Aery Ion itr ile
Month ly
Average
(!bs/day)
0.3
.0005*
0.5
2.2
1.1x10~6
0.2
0.4
" —
.04
4.9
Dai ly Month 1 y
Maximum Averaae
(Ibs/day) (ua/h
0.4 2
.0005* NDC1.5)
0.6 3
2.5 11
1 .6x10" 6.2 ppa
ND ( 5 . 0 )
NDC6.0)
ND ( 1 1 )
ND(4)
0.2 0.5
NDC0.6)
0.4 2
ND(9)
ND(0.6)
ND(1 )
.04 .2
ND(7)
ND(6)
ND(5)
6.4 24
ND(2)
ND(0.6)
ND(2)
Dai ly
Maximum
(pa/I)
2
4
3
12
8.8 ppa
5
—
—
18
1
1
2
30
—
—
0.2
—
2
—
30
—
1
13
Mass discharqe measured at 031 a
-------
DOW CHEMICAL USA
MICHIGAN DIVISION ~ MIDLAND PLANT
NON-CONVENTIONAL/TOXIC POLLUTANTS — OUTFALL 031
PERMIT #MI 0000868
TABLE 2
Phenol
2,4-Dichlorophenoxy
acetic acid
B'\s( 2-ch I oroethy I) ether
Chloroform
2,3,7,8-Tetrachloro-
d ibenzo-p-diox i n
1,1,2,2-Tetrach ioroethane
TetrachIoroethyIene
1,1,2-Tr ichIoroethane
Pentachloropheno!
1,3-Dichlorobenzene
1,4-Dichorobenzene
1,2,4-Tr ichlorobenzene
Methylene Chloride
2-Chlorophenol
2,4-Dichlorophenol
Naphtha!ene
1,1,1-Tr ichIoroethane
Bromoform
Chlorobenzene
Carbon Tetrachloride
2,4,6-Tr ichlorophenol
1,2-D ichlorobenzene
Aery Ion itr iIe
Mon
Concentrat ion
ug/l iter
2
4
2
12
3.5 ppa
ie ND(5)
ND(5)
ND ( 11 )
~ND(4)
1
ND(0.6)
2
30
ND(0.6)
NDU )
0.2
ND(7)
2
ND(5)
17
ND(2)
ND(0.6)
ND(2)
itorina Resu!
Samp 1 e
Date
10/1/84
10/1/84
10/1/84
10/1/84
9/24/84
10/1/84
10/1/84
10/1/84
10/1/84
10/1/84
10/1/84
10/1/84
10/1/84
10/1/84
10/1/84
10/1/84
10/1/84
10/1/84
10/1/84
10/1/84
10/1/84
10/1/84
10/1/84
Its — October,
Concentrat ion
yg/ I iter
1
ND(1 .5)
3
9
8.8 ppci*
5
ND(6)
ND ( 1 0 )
18
0.5
1
2
ND(9)
ND(0.5)
ND(1 )
0.2
ND(7)
ND(6)
ND(2)
30
ND(2)
1
13
1984
Samp 1 e
Date
10/15/84
10/15/84
10/15/84
10/15/84
10/06/P4
10/15/84
10/15/84
10/15/84
10/15/84
10/15/84
10/15/84
10/15/84
10/15/84
10/15/84
10/15/84
10/15/84
10/15/84
10/15/84
10/15/84
10/15/84
10/15/84
10/15/84
10/15/84
ND = Not Detected
( ) = Lowest Detection Limit
* = Concentration Reported as Part Per Quadrillion
-------
HIt>LA"0 DIV
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Ple.isc complete and sulimil Iwo copies ol Ihis loim
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PART 1 - RETURN TO DEFT OF NATURAL RESOURCES
c>nH ciinur. AL
.OUTFALL I 031
PROC.HASTES TO T ITTABAHASSEEi R, 031
PERMIT EXPIRATION!
10/79
Date fo'm was
pf.ntcd
81^.1 0/29
PAR AM
NAME
UNITS
LIMIT
DATE
10-1
2
3
4
S
6
7
8
9
10
11
12
13
14
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16
(7
18
19
20
1.21
22
23
24
25
26
27
28
29
30
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-------
MlOLAUD
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Ldomig olliu1 |jy ihc lOih ol ll* month.
PART 1 - RETURN TO DEFT OF NATURAL RESOURCES
OUTfALL f fiJl
PROC,WASTES TO T I TTABAHASSEE'R. 031
PERMIT EXPIRATION! 10/79
Dote fo'
printed
.•8I/10/2SLJ
PARAM
NAME
UNITS
LIMIT
DATE
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3
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5
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9
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,, | V S,! |t
till1* 8,6, *(
1 1 1 1 1
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U'-^RFR DAYS REPORTING
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AYS EXCEEDING MAXIMUM
VC MAX V
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Ht Ihc end ol each monlh This rcpoM muit reach our
L anvnq office by Ihe 10lh of Ihc monlh
PART 1 - RETURN TO DEFT OF NATURAL KESOUnCES
OHW CHFIIIfAL COMPANY
OUTFALL I 031
PROC. HASTES TO T I TTADAWASSEE' R. 031
PERMIT EXPIRATION! in/79
Dale form wai
printed
Bl/10/29
PAH AM
NAME
UMTS
"LIMIT
DATE"
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TOTAL SAMPLES TAKEN | ( ,
DAYS EXCEEDING MAXiMUKlJ
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NUMBER DAYS RE POST ING 1^1C
OTAL SAMcil S TAKEN ]
JAYS E XCC ED'NG '.'A XIMIJ« i i
VG M,, V,OL 1 | | , | ,
DUP PUNCH l»l *«t
1 CEFOIFY UNDER PENALTY OF LAW THAT 1 IAVE PERSONALLY EXAMINED AND AM FAMILIAR WITH THE INFORMATION SUBMI1TED IN THIS DOCUMENT AND ALL ATTACHMENTS AN
THAT DASEO ON MY INQUIRY OF THOSE INDIVIDUALS IMMEDIATELY RESPONSIBLE TOR, OBTAINING THE INFORMATION. 1 RELIEVE THAT THE INFORMATION IS TRUE ACCURATE. AN!
COMPLETE 1 AM AWARE THAT THERE ARE SIGNIFICANT PENALTIES FOR SUnMITTING FA/gE INFORMATION. INCLUDING THE POSSIBILITY OF FINE AND IMPRISONMENT
Z_. /~)ll f'j /
*/ rCJr •'"< ntt* 1 /' f/S/ft^'le
SIGNATURE O» CERTlflED OPERATOR_ R YDEN- T H 0 M A S--E^tft! '•'
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ONNUMSER_WOOI287 -
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'I-1/' * L ... , 'i
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TrT
' 4*
-------
APPENDIX C-2
1981 USEPA Sediment Survey
-------
MIDLAND
CONTINUOUS
MO»TITOf»l»» STA:
LE9END
SEOIMEMT SAMPLIM* STATIOH3
SAM^LINO SrATIONS
-------
TABLE 1
SEDIMENT SAMPLING LOCATIONS •
TITTABAWASSEE AND CHIPPEWA RlVERSt M-20 to Smith's Crossing
MARCH 18-19, 1981
Station
Number
1*
2»
3
-------
scturgcr: Tittabowassco Illvcr
•ople Date: March 18-19, 1981
U.S. ENVIRONMENTAL PROTECTION AGENCY
REGION V
Eastern District Office
Sediment Results
Sample Type: 0 C-8 dour (low proi>ortloned composite
2'iC-Z'i ttour flow proportioned composite
EVC-Equal Volume Composite
G-Gr«b
VtflE TYPE
HE
JE
!PTH FEET -(water)
&AMETEH
ORGAN I CS
A. Bas
1,3
e/Neutral & Acid Comppum
-diehlorobonzene
1 ,4-dichlorobenzcne
hcxachloruL'thane
bis
n-n
^-chlorocthyl ) ether
itrosoduiroovldiiiine
nitrobenzene
iso
' bis
1.2
j2
phorone
2-chl oroethoxy )methane
-dichlorobenzene
,4-trichl orobenzene
naphthalene
hexachl orobu tad i ene
2-chloronaphthalene
ace
dim
naphthylene
et lylpnthalate
2,6-dinitrotoluene
acenaphthene
2.4-dinitro toluene
f jj
d e
1.5
Osfl
orene
thylphthalate
-dlphenyl hydrazine
itmodinhpnvlamine
mg/kg
e
•
Gross
l/Oay
Titt. River
Above Dow Dan
EH03S02
G
1505
3/18/81
3.0
mg/kg
<0.1
-------
iscfurger: THtabowassee River
Date: March 10-19, 1'JUl
U.S. ENVIRONMENTAL PROTECTION AGENCY
REGION V
Eastern District Office
Sediment Results
Sample Type: 8 C-0 l>our (low proportioned composite
Z'iC-l'i liour MUM proportioned composite
EVC-tqu«l Vulunie Composite
G-Grab \
-AMPLE TYPE
;IME
DATE
OEPTH FEET • (Water)
3ARA«ETER
A. Base/Neutral & Acid Compounds
4-bromophenvlphenvl ether
hexachlorobenzene
1-chloronaph thai one
phenanthrene/anthracene
fluorantherie
pyrene
di-n-butylphthalate
butvlbenzvlDhthalate
chrysene
benzo(A)anthracene
b1s(2-ethylhexvl)phthalate
a i-n-c
benro
benzot
Indeno
benzo(
dlbrom
2-nitr
2-chlc
phenol
?'4-dj
2.4-dl
P^bu
L iy i pin.no i<
Blfluorantf
A) pyrene
1.2.3-C.O"]
»,H,I)pery
obfphenyl(
oghenol
rophenol
methyl phenc
chloropfenc
ty\ phenol
ie
iene
pyrene
ene
STD)
»1
>1
•
mg/kg
Cross
I/Day
TUt. River
Above Dow Oar
FH03502
6
1505
3/18/81
3.0
rag/ kg
<0.2
<0.0
<0.0
-------
.charger: THtabawasscc River
t>U Dale: March 18-19, 1981
U.S. EHYIRONMEM1AL PROTECTION AGENCY
REGION V
Eastern District Office
Sediment Results
Sample Type: 8 C-fl hour
2'tC-J'i duur
Mow proportioned composite
DIM proportioned composite
EVC-Cqu«l Volume Composite
C-Grab
HPLE TYPE
Hi
TE
PT'H FEET (Water)
(URETER
BaseVNeiLiral & Acid Compounds
p-chl oro-m-cresol
2,4 ,6-trichlorophcnol
pentachlorouhenol
4-pi trc
jDhenol
PCB's i PBB's
PCB 1242
PCB 1248
PCB 1254
PtB 1260
hexabrbnio-biphenyl _
dib_romo-biohenvl
Puroeablps*
cjjlgfgbenzene
Other Comoounds
hydrocarbons (9)
sulfur
1.7r7-
he
Tsa^
trimethvl -bicyclo [2.2.1
•
mg/kg
Gross
//Day
TiU. River
Above Dow Dan
EH03S02
G
1505
3/18/81
3.0
mg/kg
"0.4
<0.5
<0 1
< 13
_< 1_
"fr~7~
<0:Q5
1.0
Gross
//Day
..
. ^
— m
Titt. River
Below H Flume
EH03S03
G
0935
3/19/81
2.0
mg/kg
<5.2
<0.5
< 6
<0.6 '
-------
Dlscrvaroer: Tittabjwassec River
Sample Date: March 18-19, 1981
u.s. ENVIRONMENTAL PROTECTION AGENCY
REGION v
Eastern District Office
Sample Type: 8 C-8 l.our Mow proportioned compos Ice
24C-A Ituur Mow proportioned composite
EVC-Equal Volume Composite
C-Grab
SAMPLE TYPE
TIME
DATE
DEPTH FEET • (Uater)
PARAMETER
D. Other Compounds
octanpic acid
bota-gurjunene
alpha-fornesene
1 -methoxy-4- ( phenyl ethyi
unidentified compounds
unidentified compounds
unidentified compounds
unidentified compounds
unidentified compounds
unidentified compounds
unidentified compounds
unidentified com
hydrocarbons (2)
sec-butvlcthvlbe
3,5-dimethyl-2-c
).3.5-tris(1-met
1 ,1 'oxybisbenzen
2-phenoxv-l ,1 'bi
terpheny'l
l.r :3',l-terphe
hydrocarbons (11
sulfur molecule
iy~1)benz{
Spectrui
Spectrui
Spectrur
i Spectrur
'Specirur
Spectrur
Spectrur
aounas Spectrur
yclohexen-1-one
hvlethvllbenzeni
e
phenyl
nyl
S8)
•
mg/kg
ne
395<
si;
Gross
//Day
T1U. River
Above Dow Dar
EH03S02
G
1505
3/18/81
3.0
mg/kg
n
--
Gross
I/Day
^ «•
Titt. River
Below H Flume
EH03S03
G
0935
3/19/81
2.0
mg/kg
—
--
Gross
//Day
-
T1tt. River
Near J6.Br1ne
Pond
EH03S04
G
0945
3/19/81
2.0
mg/kg
—OTB"
-T7T
— DTT
I.I
0.2
0.4
0.9
1.. G
Q.9
Q. 5
Gross
I/Day
--
--
THt. River
Below Bullock
Creep.
EH03S05
G
1005
3/19/81
1.5
mg/kg
--
0.3
Q.I
0.1
o.i
0.8
0.1
2 2
4..Q
Gross
//Day
--
__J1^-
Titt. River
Below L ingle
EH03S06
G
1025
3/19/81
1.0
mg/kg
--
Q.5
0.8
Gross
//Day
--
--
T1tt. River
Above Smith1!
Crossing
EHU3S07
G
•1045
3/19/01
2.5
mg/kg
3.0
5.3
7.7
Gross
jf/Oay
--
--
mg/kg
Gross
I/Day
mg/kg
Gr.
-------
Discharger: T1 ttabawassce lilver
Sample Date: March 10-19, 1901
U.S. CHVIROHMCHTAL PROTECTIOK AGENCf
REGION V
Eastern District Office
Sediment Results
Sample Type: 8 C-8 hour fluw proportioned compojlte
Z'iC-J'i hour HtM proport looed composite
EVC-Cqual Volume Composite
C-Crab
SAMPLE TYPE
TIME
DATE
DEPTH FEET -(Water)
PARAMETER
). Other Compounds
unidentified silicon compounds
hexactlwl benzene
4-phenoxy-l ,1 '-biphenyl
tetrapthvl benzene (1 isdmpr )
1 ,2,4,b-tetrakis (' -methyl ethyl
benzene
unidentified silicon compounds
hydrocarbons (1 )
unidentified compounds Spectri
unidentified compounds Spectri.
mg/kg
[10j
\ w
[4)
"
n 448'
m 973
Cross
I/Day
Titt. River
Above Dow Dai
EH03S02
G
1505
3/18/81
3.0
mg/kg
..
»
v
__
Cross
I/Day
*.
- .•
• •
• .
-»
Titt. River
iBelow H Flume
EH03S03
G
0935
3/19/81
2.0
mg/kg
.-
._
__
^ f.
„
Cross
I/Day
—
..
..
. .
_.
_—
Titt. River
Near #6 Brine
Pond
EH03S04
G
0945
3/19/01
2.0
mg/kg
—
--
..
..
..
__
Cross
»/Oay
—
--
.-
..
--
„_
— w
Titt. RiveT
Below Bullock
Creek
EH03S05
G
1005
3/19/81
1.5
mg/kg
•-
—
--
-.
—
_.
— m
Cross
X/Oay
--
—
--
--
--
.-
__
Titt. River
Below Lingle
Drain
EH03S06
G
1025
3/19/81
1.0
mg/kg
3.3
--
--
..
—
—
..
__
Gross
f/Day
--
--
—
.-
—
—
--
..
Titt. River
Above Smith's
Crossing
EH03S07
G
1045
3/19/01
2.5
mg/kg
--
1 O~~
2.3
1.4
0.9
4.4
4:0
? 1
Gross
//Ojy
--
--
--
--
--
--
..
--
..
mg/kg
I/Day
mg/kg
Groi t
//Dir
-------
APPENDIX C-3
1984 USEPA Sediment Survey
-------
Table 1
Sediment Sampling Locations
Tittabawassee River
July 25-27, 1984
Station
Number
TR-1
TR-2
TR-3
TR-4
TR-5
TR-6
TR-7
Sample
Number
84ER04S01
84ER04S02
84ER04S03
84ER04S05
84ER04S07
84ER04S08
84ER04S09
TR-8 84ER04S12
TR-9 84ER04S13
Location and Site Specific Collection Method
The site is located above the ash pond, below the confluence of the Chippewa
River, at the abandoned Benson Street bridge abutments. The sample was taken by
Ekman dredge in 10 feet of water.
The site is located below the ash pond discharge and above the Dow Chemical
Tittabawassee River water intake.
The site is located above Lingle Drain about 750 feet above the railroad bridge.
Samples were collected with a Peterson dredge in 3 inches of water.
The site is located 12 yards downstream of the Smith's Crossing bridge. The
samples were taken with a Peterson dredge.
This site is located 1200 feet downstream of Sarle Drain and upstream of Brown
Mills Run. Samples were obtained from a water depth of 6 inches using a stainless
steel spoon.
Samples were collected from about the midpoint of the Freeland Road bridge using
an Ekman dredge to a water depth of 4 feet.
Samples were collected from the Tittabawassee Road bridge using an Ekman dredge
to a depth of about 3 feet.
Samples were collected from the Gratiot Road bridge using an Ekman dredge.
Samples were collected from the Center Road bridge using an Ekman dredge.
-------
Table 2
Flood Plain Sampling Locations
Tittabawassee River
July 25-27, 1984
Station Sample
Number Number Location and Site Specific Collection Method
FP-1 84ER04S04
This soil sample was taken in the Tittabawassee River Flood Plain adjacent to
the Dow Chemical tertiary pond, about 200 feet from the river. The soil was
removed to a depth of 1 inch using a shovel and large spoon.
FP-2 84ER04S06 This soil sample was taken in the Tittabawassee River Flood Plain about 1200
feet upstream of Gordonville Road and below Waite and Debolt drain. The samples
were taken by stainless steel spoon to a depth of 1 inch.
FP-3 84ER04S10 This soil sample was obtained in the Tittabawassee River Flood Plain under the
Tittabawasse bridge about 10 feet from shore.
-------
charger:
;p1e Date:
Tittabawassee River
U.S. ENVIRONMENTAL PROTECTION AGENCY
REGION Y
EASTERN DISTRICT OFFICE
Sediment Analyses
Sample Type;
8 C-8 hour flow proportioned composite
24C-24 hour flow proportioned composite
EVC-Equal volume composite
7/27/84 TR-5 G-Grab
.Station #: TR-1 TR-2 TR-3 TR-4 Uostream TR-6 TR-7 TR-8 TR-9
Sample Type
Time
Sample Number 84ER04
Date
Parameter
I. VOLATILES
Acrolein
Acrylonitrile
Benzene
Carbon tetrachloride
Chlorobenzene
1,2-dichloroethane
1,1,1-trichloroethane
1,1-dichloroethane
1,1,2-trichloroethane
1 ,1 ,2 ,2-tetrachl oroethane
Chloroethane
Bi s( chl oromethyl ) ether
Z-chloroethyl vinyl ether
Chloroform
1,1-dichloroethene
Trans-l,2-dichloroethene
1 ,2-dichloropropane
Trans-1 ,3-dichloropropene
Cis-l,3-dichloropropene
Ethyl benzene
Methyl ene chloride
Chloromethane
Above
Ash
Pond
G
1610
SOI
7/25/84
ug/kg
(ppb)
NO/50
ND/50
ND/2.5
ND/2.b
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/5
ND/2.5
2400*
ND/2.5
Below
Ash
Pond
G
1700
S02
7/25/84
ug/kg
(ppb)
ND/50
ND/50
ND/2.B
ND/2.b
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/5
ND/2.5
32*
ND/2.5
Above
Lingle
Drain
G
1900
S03
7/25/84
ug/kg
(ppb)
ND/50
ND/50
ND/2.b
NU/2.b
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/5
ND/2.5
29*
ND/2.5
At
Smith's
Crossing
G
2010
SOS
7/25/84
ug/kg
(ppb)
ND/b'O
ND/b'O
ND/2.b
m/'l.b
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/5
ND/2.5
17*
ND/2.5
of Brown
Mill's
Run
G
2050
S07
7/25/84
ug/kg
(ppb)
ND/bU
ND/50
NU/5».b
NU/^.b
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/5
ND/2.5
46*
ND/2.5
At
Freeland
Road
G
0840
SOS
7/27/84
ug/kg
(ppb)
NU/bU
ND/bO
ND/^.b
NU/^.b
wn/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/5
ND/2.5
16*
ND/2.5
At
Titta.
Road
G
0920
S09
7/27/84
ug/kg
(ppb)
ND/bU
ND/bU
ND/i!.b
NU/'^.b
Nn/?.s
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/5
ND/2.5
57*
ND/2.5
At
Gratiot
Road
G
0945
S12
7/27/84
ug/kg
(ppb)
NU/bU
NU/bU
"NU/^.b
NU/z.b
Nn/?.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/5
ND/2.5
40*
ND/2.5
I At
Center
Road
G
0850
S13
7/27/84
ug/kg
(ppb)
NU/bU
NU/bU
NU/Z.b
NU/Z.b
wn/?.s
ND/2,5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
Kin/?. 5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
NO/?. 5
ND/ 5
ND/2.5
99*
ND/2.5
-------
^charger:
Tittabawassee River
U.S. ENVIRONMENTAL PROTECTION AGENCY
REGION V
EASTERN DISTRICT OFFICE
Sample Type: 8 C-8 hour flow proportioned compos1t<
24C-24 hour flow proportioned composit*
Die Date:
^ . , tVU-cquat vu unic luuiuus i ic
7/25/84 Sediment Analyses JR_5 G-Grab
7/27/84 Station #• ™_i TB.2 TR-3 TR-4 ,ne^M« TR-6 TR-7 TR-8 TR-9
Sample Type
Time
Sample Number a/ironA
Date
Parameter
1. VOLATILE* (continued)
Bromomethane
Bromoform
Bromodichl oromethane
THcl
il orof 1 uoromethane
Dlchl orodl f 1 uoromethane
Chlorodlbromomethane
Tetrachl oroethene
Toluene
Trichloroethene
Vinyl chloride
Acetone
2-butanone
Carbon dlsulfide
2-hexanone
4-methyl -2-pentanone
Styrene
Viny'
Total
acetate
xylenes
Above
Ash
Pond
G
1610
SD1
7/25/84
ug/kg
(ppb)
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2t5
ND/2.5
5 2
ND/2.5
ND/2.5
ND/50
ND/100
ND/5
ND/50
ND/50
ND/2.5
ND/5
ND/2.5 |
Below
Ash
Pnnd
G
1700
SQ2
7/25/84
ug/kg
( ppb)
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
, ND/2.5
ND/2.5
ND/2.5
ND/100
ND/5
ND/50
ND/50
ND/2.5
ND/5
ND/2.5
Above
L ingle
Drain
G
1900
S03
7/25/84
ug/kg
(DDb)
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2-5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/50
ND/100
ND/5
ND/50
ND/50
ND/2.5
ND/5
ND/2.5
At
Smith's
fj-pssing
G
2010
S05
7/25/84
ug/kg
(ppb)
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2, 5
ND/2.5
ND/2.5
ND/50
ND/100
ND/5
ND/50
ND/50
ND/2.5
ND/5
ND/2.5
of Brown
Mill's
Run
G
2050
S07
7/25/84
ug/kg
(ppb)
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/50
NU/IUU
ND/5
[ ND/50 I
ND/50
ND/2.5
ND/5
1 ND/2.5
At
rreeland
Road
G
0840
SOS
7/27/84
ug/kg
(ppb)
Hft/2.5
ND/2.5
ND/2.5
ND/2.5
Nn/2.5
ND/2.5
ND/2.5
ND/2.5
[ ND/2.5 ]
t ND/2.5 1
ND/50
NU/ 1UU
ND/5
1 ND/50 1
ND/50
ND/2.5
ND/5
1 ND/2.5
At
Titta.
Road
G
0920
S09
7/27/84
ug/kg
(ppb)
ND/2.IT
ND/2.5
ND/2.5
ND/2.5
ND/2.5,
ND/2.5
ND/2.5
[ ND/2.5 1
[ ND/2.5 I
[ ND/2.5 1
ND/50
MD/I nn
ND/5
1 ND/50 1
1 ND/50
ND/2.5
ND/5
1 ND/2.5
At
Gratiot
Road
G
0945
S12
7/27/84
ug/kg
(ppb)
ND/2.5
ND/2.5
ND/2 . 5
ND/2.5
ND/2.5
ND/2.5
(NH/2.5 1
[ND/2.5 1
| ND/2. 5 1
[ND/2.5 1
ND/50
ND/1 00
ND/5
ND/50
ND/50
ND/2.5
[ND/5
ND/2.5
At
Center
Road
G
0850
S13
7/27/84
ug/kg
(ppb)
ND/Z.b
ND/2.5
ND/2.5
ND/2.5
ND/2 5
ND/2 5
ND/2.5 I
ND/2.5 I
I ND/2, 5 I
t ND/2. 5 I
ND/50
ND/100
ND/ 5
ND/50
ND/50
ND/2.5
1 ND/ 5 ,
I ND/2. 5
-------
scharger:
Tittabawassee River
U.S. ENVIRONMENTAL PROTECTION AGENCY
REGION V
EASTERN DISTRICT OFFICE
Sample Type: 8 C-8 hour flow proportioned composite
24C-24 hour flow proportioned composite
pie Date: 7/25/84 Sediment Analyses Tn c Evu-tquai volume composite
7/?7/ft4 TR~5 G-Grab
' ' Station #: TR-1 TR-2 TR-3 TR-4 un^r^m TR-6 TR-7 TR-8 TR-9
Sample Type
Time
Samole Number 84ER04
Date
Parameter
Above
Ash
Pond
G
1610
SOI
7/25/84
ug/kg
(ppb)
II. ACID AND BASE NEUTRAL POLLUTANTS
2 ,4 ,6-trichlorophenol
4-chl oro-3-methyl phenol
2-chlorophenol
2,4-d1chlorophenol
2, 4-dimethyl phenol
2-nitrophenol
4-nitrophenol
2,4-dinitrophenol
4 ,6-di ni tro-2-methyl phenol
Pentachlorophenol
Phenol
Benzoic acid
2-methyl phenol
4-methyl phenol
2 ,4 ,5-trichl orophenol
Acenaphthene
Benzidine
1,2,4-trlchlorobenzene
Rexachl orobenzene
Hexachloroethane
Bis(2-chloroethyl) ether
ND/10
ND/20
ND/10
ND/10
ND/10
ND/20
ND/100
ND/50
ND/20
ND/20
ND/10
ND/100
ND/10
ND/10
ND/100
ND/10
ND/40
ND/10
ND/10"
ND/10
ND/10
Below
Ash
Pond
G
1700
S02
7/25/84
ug/kg
(ppb)
ND/10
ND/20
ND/10
ND/10
ND/10
ND/20
ND/100
ND/50
ND/20
ND/20
ND/10
ND/100
ND/10
ND/10
ND/100
ND/10
ND/40
ND/10
N0710
ND/10
ND/10
Above
Llngle
Drain
G
1900
SOS
7/25/84
ug/kg
(ppb)
ND/10
ND/20
ND/10"
ND/10
ND/10
ND/20
ND/100
ND/50
ND/20
ND/20
ND/10
ND/100
ND/10
ND/10
ND/100
ND/10
ND/40
ND/10
ND/10
ND/10
ND/10
At
Smith's
Crossing
G
2010
S05
7/25/84
ug/kg
(ppb)
ND/10
ND/20
ND/10
ND/10
ND/10
ND/20
ND/100
ND/50
ND/20
ND/20
ND/10
ND/100
ND/10
ND/10
ND/100
ND/10
ND/40
ND/10
ND/10
ND/10
ND/10
of Brown
Mill's
Run
G
2050
S07
7/25/84
ug/kg
(ppb)
ND/10
ND/20 .
ND/10
ND/10
ND/10
ND/20
ND/100
ND/50
ND/20
ND/20
ND/10
ND/100
ND/10
ND/10
ND/100
ND/10
ND/40
ND/10
ND/10
ND/10
ND/10
At
Free! and
Road
G
0840
SOS
7/27/84
ug/kg
(ppb)
ND/10
ND/20
ND/10
ND/10
ND/10
ND/20
ND/100
ND/50
ND/20
ND/20
ND/10
ND/100
ND/10
ND/10
ND/100
ND/10
ND/40
ND/10
ND/10
ND/10
ND/10
At
Titta.
Road
G
0920
S09
7/27/84
ug/kg
(ppb)
ND/10
ND/20
ND/10
ND/10
ND/10
ND/20
ND/100
ND/50
ND/20
ND/20
ND/10
ND/100
ND/10
ND/:O
NO/: oo
ND/10
ND/40
ND/10
ND/10
ND/10
ND/10
At
Gratiot
Road
G
0945
S12
7/27/84
ug/kg
(ppb)
ND/10
ND/20
ND/10
ND/10
ND/10
ND/20
ND/100
ND/50
ND/20
ND/20
ND/10
ND/100
ND/10
ND/10
ND/100
ND/10
ND/40
ND/10
ND/10
ND/10
ND/10
At
Center
Road
G
0850
S13
7/27/84
ug/kg
(ppb)
ND/10
ND/20
NO/10
ND/10
ND/10
ND/20
ND/100
ND/50
ND/2Q
ND/20
ND/10
ND/100
ND/10
ND/10
ND/100
ND/10
ND/40
ND/10
ND/10
ND/10
ND/10
-------
icharger:
Tittabawassee River
nple Date: 7/25/84
U.S. ENVIRONMENTAL PROTECTION AGENCY
REGION V
EASTERN DISTRICT OFFICE
Sediment Analyses
Sample Type;
TR-5
8 C-8 hour flow proportioned composite
24C-24 hour flow proportioned composite
EYC-Equal volume composite
G-Grab
""'** ,tat,nn #. TP.l TR-? TR-3 TR-4 ,^^MM TR-6 TR-7 TR-8 TR-9
Sample Type
Time
Sample Number QAFDHA
Date
Parameter
II. ACID AND BASE NEUTRAL POL
2-chloronaphtha ene i
1 ,2-d1chlorobenzene
1 ,3-dichlorobenzene
1 ,4-dichlorobenzene
3,3*-dichlorobenzidine
2, 4-dinitro toluene
2, 6-d1n1tro toluene
1 ,2-dlphenyl hydrazlne
Fluoranthene
4-chloro
4-bromo
Bis(2-c
p
l
phenyl phenyl ether
lenyl p lenyl ether
lorolsopropyl Jether
Bl sl 2-chl oroethoxy )me thane
Hexachl orobutadf ene
Hexachlorocyclopentadiene
Isophorone
Napithalene
Nitrobenzene
N-nltrosodlmethylamlne
N-nitrosodl phenyl ami ne
N-nitrosodlprop yamine
Bis 2-ethyl lexyl Jphthalate
Above
Ash
Pond
G
1610
sni
7/25/84
ug/kg
(nob) l ... .
Below
Ash
Pond
G
1700
SO?
7/25/84
ug/kg
(DDb)
mm (
-------
.charger:
Tittabawassee River
U.S. ENVIRONMENTAL PROTECTION AGENCY
REGION Y
EASTERN DISTRICT OFFICE
Sample Type;
iple Date: 7/25/84
7/27/84
Station #
Sediment Analyses
TR-1 TR-2 TR-3
TR-5
TR-4
TR-6
8 C-8 hour flow proportioned composite
24C-24 hour flow proportioned composite
EYC-Equal volume composite
G-Grab
TR-7 TR-8 TR-9
Sample Type
Time
Sample Number 84FR04
Date
Parameter
Above
Ash
i Pnnd
G
1610
5501
7/25/84
ug/kg
(DDb)
Below
Ash
Pond
G
1700
SO?
7/25/84
ug/kg
(DDb)
II. ACID AND BASE NEUTRAL POLLUTANT^ (continued
Butyl benzyl phthalate
Di-n-butyl phthalate
Di-n-octyl phthalate
Di ethyl phtialate
Dimethyl phthalate
Benzo(a)anthracene
Benzol a )pyrene
Benzol b & k)fluoranthene
Benzo( k ) f 1 uoranthene
Chrysene
Acenapnthylene
Anthracene
Benzo(ghi)perylene
Fluorene
Phenanthrene
Dibenzo( a, h) anthracene
Indeno(l,2,3-cd)pyrene
Pyrene
'Aniline
Benzyl alcohol
4-chloroani ine
Dibenzofuran
ND/10
10J*
ND/10
ND/10
ND/10
ND/10
ND/20
ND/20
ND/20
ND/10
ND/10
ND/10
ND/20
ND/10
ND/10
ND/20
ND/20
ND/10
ND/10"
MO/20
ND/50
ND/10
ND/10
wn/io
ND/10
ND/10
ND/10
ND/10
ND/20
ND/20
ND/20
ND/10
ND/10
ND/10
ND/20
ND/10
ND/10
ND/20
ND/20
ND/10
Mb/10
NO/20
ND/50
ND/10
Above
L ingle
Drain
G
1900
S03
7/25/84
ug/kg
(DDb)
ND/10
840
ND/10
ND/10
ND/10
ND/10
ND/20
ND/20
ND/20
ND/10
ND/10
ND/10
ND/20
ND/10
ND/10
ND/20
ND/20
ND/10
MD/10
MO/20
ND/50
ND/10
At
Smith's
r^-nQcing
G
2010
SOS
7/25/84
ug/kg
(DDb)
ND/10
ND/10
ND/10
ND/10
ND/10
ND/10
ND/20
ND/20
ND/20
ND/10
ND/10
ND/10
ND/20
ND/10
ND/10
ND/20
ND/20
ND/10
ND/lO
MD/20
ND/50
ND/10
of Brown
Mill's
Run
G
2050
S07
7/25/84
ug/kg
(DDb)
ND/10
wn/io
ND/10
ND/10
ND/10
ND/10
ND/20
ND/20
ND/20
ND/10
ND/10
ND/10
ND/20
ND/10
ND/10
ND/20
ND/20
ND/10
ND/10
ND/20
ND/50
ND/10
At
Freel and
Road
G
0840
508
7/27/84
ug/kg
(DDb)
ND/10
Kin/io
ND/10
ND/10
ND/10
ND/10
ND/20
ND/20
ND/20
ND/10
ND/10
ND/10
ND/20
ND/10
ND/10
ND/20
ND/20
ND/10
ND/10
ND/20
ND/50
ND/10
At
Titta.
Road
G
0920
S09
7/27/84
ug/kg
(DDb)
ND/10
Nn/io
ND/10
ND/10
ND/10
ND/10
ND/20
ND/20
ND/20
ND/10
ND/10
ND/10
ND/20
ND/10
ND/10
ND/20
ND/20
ND/10
ND/10
ND/20
ND/50
ND/10
At
Gratiot
Road
G
0945
S12
7/27/84
ug/kg
(DDb)
ND/10
Nn/io
NP/IQ
ND/10
ND/10
ND/10
ND/20
ND/20
ND/20
ND/10
ND/10
ND/10
ND/20
ND/10
ND/10
ND/20
ND/20
ND/10
ND/10
ND/20
ND/50
NP/IQ
At
Center
Road
G
0850
S13
7/27/84
ug/kg
(DDb)
ND/10
Nn/in
Kin/io
10.1*
Kin/10
ND/10
ND/20
ND/20
ND/20
ND/10
ND/10
ND/10
ND/20
ND/10
ND/10
ND/20
ND/20
ND/10
ND/10
ND/20
ND/50
NO/10
-------
scharger:
mple Date:
Tittabawassee River
U.S. ENVIRONMENTAL PROTECTION AGENCY
REGION Y
EASTERN DISTRICT OFFICE
7/25/84
7/27/84
Station #: TR-1
Sediment Analyses
TR-2 TR-3 TR-4
Sample Type: 8 C-8 hour flow proportioned composit
24C-24 hour flow proportioned composit
EVC-Equal volume composite
TR-5 G-Grab
Uostream TR-6 TR-7 TR-8 TR-9
Sample Type
Time
Samole Number 84ER04
Date
Parameter
Above
Ash
Pond
G
1610
SOI
7/25/84
ug/kg
(ppb)
Below
Ash
Pond
G
1700
S02
7/25/84
ug/kg
(ppb)
II. ACID AND BASE NEUTRAL POLLUTANTS {continued
2-methyl naphtha"! ene
-mtroaniiine
3-nitroaniline
4-nitroanlline
ND/20
NO/100
ND/100
ND/100
ND/20
ND/100
ND/100
NO/100
Above
Lingle
Drain
G
1900
SOS
7/25/84
ug/kg
(ppb)
ND/*0
ND/100
ND/100
ND/100
At
Smith's
Crossina
G
2010
S05
7/25/84
ug/kg
(ppb)
ND/20
ND/100
ND/100
ND/100
)f Brown
Mill's
Run
G
2050
S07
7/25/84
ug/kg
(ppb)
ND/20
ND/100
ND'/lOO
ND/100
At
:reel and
Road
G
0840
SOS
7/27/84
ug/kg
(ppb)
HD/20
ND/100
ND/100
ND/100
At
Titta.
Road
G
0920
S09
7/27/84
ug/kg
(ppb)
ND/20
ND/100
ND/100
ND/100
At
Gratiot
Road
G
0945
S12
7/27/84
ug/kg
(ppb)
ND/20
ND/100
ND/100
ND/100
At
Center
Road
G
0850
S13
7/27/84
ug/kg
(ppb)
ND/20
ND/100
ND/1UU
ND/100
-------
scharger:
mple Date:
Tittabawassee River
U.S. ENVIRONMENTAL PROTECTION AGENCY
REGION V
EASTERN DISTRICT OFFICE
Sample Type;
7/25/84
7/27/84
Sediment Analyses
Station #: TR-1
TR-2
TR-3
TR-4
TR-5
Upstream
TR-6
8 C-8 hour flow proportioned composite
24C-24 hour flow proportioned composite
EVC-Equal volume composite
G-Grab
TR-7 TR-8 TR-9
Sample Type
Time
Sample Number 84ER04
Date
Parameter
III. PCB/PESTICIDE POLLUTANTS
Aldrin
Dieldrin
Chlordane
4, 4 l -DDT
4, 4 '-DDE
4, 4' -ODD
Alpha-endosulfan
Beta-endosulfan
Endosulfan sulfate
Endrin
Endrln aldehyde
Heptachlor
Heptachlor epoxide
Alpha-BHC
Beta-BHC
Gamma-BHC
Delta-BHC
PCB-1242
PCB-1254
PCB-1221
PCB-1232
PCB-1248
PCB-1260
PCB-1016
Toxaphene
Above
Ash
Pond
G
1610
SOI
7/25/84
ug/kg
(ppb)
ND/4.0
ND/4.0
ND/4.0
14
20
15
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
Below
Ash
Pond
G
1700
S02
7/25/84
ug/kg
(ppb)
ND/4.0
ND/4.0
ND/4.0
17
19
14
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.6
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
Above
Llngle
Drain
G
1900
SOS
7/25/84
ug/kg
(DDb)
ND/4.0
ND/4.0
ND/4.0
R.3
19
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
At
Smith's
Crosslna
G
2010
SOB
7/25/84
ug/kg
(ppb)
ND/4.0
ND/4.0
ND/4.0
wn/4.n
l?
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
MD/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
of Brown
Mill's
Run
G
2050
S07
7/25/84
ug/kg
(ppb)
ND/4.0
ND/4.0
ND/4.0
wn/d.n
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
wn/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
At
Freeland
Road
G
0840
SOS
7/27/84
ug/kg
(ppb)
ND/4.0
ND/4.0
ND/4.0
Mn/4_n
wn/d.n
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
Nn/4.n
ND/4.0
ND/4.0
ND/4.0
ND/4.0
Np/4,0
At
Titta.
Road
G
0920
S09
7/27/84
ug/kg
(ppb)
ND/4.0
ND/4.0
ND/4.0
Mn/4.n
Mn/4.n
Kin/4.0
wn/4.n
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
Nn/4.0
ND/4.0
ND/4.0
ND/4.0
wn/4.n
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
At
Gratlot
Road
G
0945
S12
7/27/84
ug/kg
(ppb)
ND/4.0
ND/4.0
ND/4.0
Mn/4 . n
wn/4.n
NH/4.0
wn/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
un/4.n
ND/4.0
ND/4.0
ND/4.0
wn/4 n
Nn/4.n
ND/4.0
ND/4.0
ND/4.0
NO/4.0
At
Center
Road
G
0850
S13
7/27/84
ug/kg
(ppb)
NO/4.0
ND/4.0
ND/4.0
Mn/4 n
wn/4.n
Kin/4.0
wn/4.n
ND/4.0
ND/4.0
NH/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
Mn/4 n
Mn/4.n
ND/4.0
ND/4.0
Kin//i n
wn/4.n
wn/4.0
MD/4.0
ND/4.0
Nn/4.o
-------
ischarger:
ample Date:
Tittabawassee River
7/25/84
U.S. ENVIRONMENTAL PROTECTION AGENCY
REGION V
EASTERN DISTRICT OFFICE
Sediment Analyses
Sample Type:
TR-5
8 C-8 hour flow proportioned composit
24C-24 hour flow proportioned composit
EVC-Equal volume composite
G-Grab
/ C-l /Ot _ .
Station i
Sample Type
Time
Samole Number 84ER04
Date
Parameter
IV. METALS**
Aluminum
Antimony
Arsenic
Barium
Beryllium
Cadmium
Chromium
Cobalt
Copper
Iron
Manganese
Nickel
Selenium
Silver
Thallium
Vanadium
Zinc
?: TR-1 TR-2 TR-3 TR-4 ,,nqtr.Min TR-6 TR-7 TR-8 TR-9
Above
Ash
Pond
G
1610
SOI
7/25/84
mg/kg
(ppm)
1460C
ND/0.3
1.5
20. 2C
ND/.05
0.08
5.40
1.70
7.68C
3490C
228
3.05
0.13
ND/.15
ND/0.1
3.50
17.6C
Below
Ash
Pond
G
1700
S02
7/25/84
mg/kg
(ppm)
1810C
ND/0.3
1.6
22. 5C
ND/.05
0.20
6.5
1.95
9.98C
4100C
195
3.55
0.10
ND/.15
ND/0.1
4.55
26. <5C
Above
L ingle
Drain
G
1900
S03
7/25/84
mg/kg
(ppm)
1450C
ND/0.3
1.5
15. 1C
ND/.05
0.08
5.80
1.80
6.78C
3450C
147
3.15
ND/0.1
ND/.15
ND/0.1
3.85
22. 6C
At
Smith's
Crossing
G
2010
SOS
7/25/84
mg/kg
(ppm)
2180C
ND/0.3
1.8
23. OC
0.08
0.11
6.05
2.20
9.08C
4710C
137
4.75
0.11
ND/.15
ND/0.1
5.76
22. 3C
of Brown
Mill's
Run
G
2050
S07
7/25/84
mg/kg
(ppm)
496C
ND/0.3
0.86
4.83C
ND/.05
ND/.02
2.65
0.80
1.13C
1820C
96.5
1.20
ND/0.1
MD/.15
ND/0.1
1.75
10. OC
At
Freeland
Road
G
0840
S08
7/27/84
mg/kg
(ppm)
596C
ND/0.3
1.1
5.03C
ND/.05
MD/..02
4.20
1.00
1.93C
1900C
75.5
1.60
ND/0.1
ND/.15
ND/0.1
2.25
13. 5C
At
Titta.
Road
G
0920
S09
7/27/84
mg/kg
(ppm)
373C
wn/0.3
0.68
4. sac
ND/.05
0.08
2.65
0.75
2.28C
1150C
45.3
ND/.75
ND/0.1
ND/.15
ND/0.1
1.10
29. 9C
At
Gratiot
Road
G
0945
S12
7/27/84
mg/kg
(ppm)
40or
wn/o.3
0.70
4. oar.
ND/.05
ND/.025.
2.75
0.75
3.38C
1130C
39.9
1.20
ND/0.1
ND/.15
ND/0.1
1.15
9.54C
At
Center
Road
G
0850
S13
7/27/84
mg/kg
(ppm)
.rw.
wn/o.3
?.?ar
MH/.05
ND/.025
3.05
MD/0.5
2.33C
993C
35.5
0.80
ND/0.1
ND/.15
ND/0.1
0.80
8.99C
-------
scharger:
mple Date:
Tittabawassee River
U.S. ENVIRONMENTAL PROTECTION AGENCY
REGION V
EASTERN DISTRICT OFFICE
Sample Type:
7/25/84
7/27/84
Sediment Analyses
Station #: TR-1
TR-2
TR-3
TR-4
TR-5
Upstream
TR-6
8 C-8 hour flow proportioned composite
24C-24 hour flow proportioned composite
EVC-Equal volume composite
G-Grab
TR-7 TR-8 TR-9
Sample Type
Time
Sample Number 84ER04
Date
Parameter
V. DIOXINS AND FURANS
2378-TCDD
Total Tetra CDDs
Total Penta CDDs
Total Hexa CDDs
Total Hepta CDDs
OCDD
23/8-TCDF
Total Tetra CDFs
Total Penta CDFs
Total Hexa CDFs
Total Hepta CDFs
OCDF
Above
Ash
Pond
G
1610
SOI
7/25/84
ng/g
(ODD)
ND/0.03
ND/0.01
ND/0.03
ND/0.03
0.11
0.47
ND/0.03
ND/0.03
ND/0.03
ND/0.03
0.06
0.17
Below
Ash
Pond
G
1700
S02
7/25/84
ng/g
(DDb)
ND/0.01
ND/0.01
ND/0.01
ND/0.01
0.02
0.08
ND/0.01
ND/0.01
ND/0.01
ND/0.01
0.01
0.02
Above
Lingle
Drain
G
1900
S03
7/25/84
ng/g
(DDb)
ND/0.01
0.15
ND/0.01
0.02
0.29
1.6
0.01
2.7
0.02
0.03
0.16
0.30
At
Smith's
Crossina
G
2010
S05**
7/25/84
ng/g
(DDb)
ND/0.01
0.08
0.03
0.11
1.1
6.8
0.10
0.43
0.20
0.37
1.3
3.0
of Brown
Mill's
Run
G
2050
S07**
7/25/84
ng/g
(DDb)
ND/0.01
0.01
ND/0.01
ND/0.01
0.03
0.26
0.02
0.19
ND/0.01
ND/0.01
0.04
0.10
At
Free! and
Road
G
0840
SOS
7/27/84
ng/g
(DDb)
ND/0.01
0.02
ND/0.01
0.01
0.05
0.25
0.03
0.20
0.02
0.05
0.07
0.07
At
Ti tta .
Road
G
0920
S09**
7/27/84
ng/g
(DDb)
ND/0.01
0.01
ND/0.01
ND/0.01
0.05
0.46
0.02
0.13
ND/0.01
0.02
0.05
0.12
At
Gratiot
Road
G
0945
S12
7/27/84
ng/g
(DDb)
ND/0.02
ND/0.02
NP/0.05
ND/0.07
ND/0.04
0.33
0.03
1.4
ND/0.03
ND/0.03
ND/0.04
0.08
At
Center
Road
G
0850
S13
7/27/84
ng/g
(DDb)
ND/0.01
ND/0.01
ND/0.03
ND/0.03
ND/0.04
0.30
ND/0.02
0.09
ND/0.03
ND/0.03
0.03
0.10
-------
NOTES:
1. ND = Compound was analyzed for but not detected. Value reported is the detection limit.
2. * = Presence of compound may be due to sample bottle preparation, field and/or labora-
tory contamination. Methylene chloride is used as a cleaning agent for sample
bottles. Phthalate compounds are components of certain plastics and are widespread
in the environment at low levels.
3. ** = Data reported on wet weight basis.
4. J = Estimated value, detected below minimum specified contract detection limit but
greater than zero.
5. C = Blank corrected.
6. ug/kg = microgram per kilogram.
7. mg/kg = milligram per kilogram.
8. ppb = parts per billion.
9. ppm = parts per million.
10. ng/g = nanogram per gram.
-------
Ischarger:
ample Date:
7/25-27/84
U.S. ENVIRONMENTAL PROTECTION AGENCY
REGION V
EASTERN DISTRICT OFFICE
THtabawassee River Flood Plain Analyses
Sample Type: 8 C-8 hour flow proportioned composite
24C-24 hour flow proportioned composite
EYC-Equal volume composite
G-Grab
Cation #: FP-1 FP-2 FP-3
Sample Type
Time
Sample Number 84ER04
Date
Parameter
I. VOLATILES
Acrolefn
Acrylonltrlle
Benzene
;arbon tetrachioride
Chlorobenzene
,Z-dlchloroetnane
,1 ,1-trlchloroethane
,1-dichl oroethane
,1 ,2-trlchl oroethane
.,1,2 ,2-tetracni oroetnane
Chi oroethane
Bl s( chl oromethyl ) ether
2-chloroethyl vinyl ether
Chloroform
,.1-dlchloroethene
Trans-1 .Z-dlchloroethene
L,2-dlchloropropane
Trans-1 ,3-dlchloropropene
:is-l,3-dlchloropropene
Ethyl benzene
Methyl ene chloride
Chl orome thane
At Dow
Tertiary
Pond
G
1550
S04
7/26/84
ug/kg
(ppb)
KID/50
ND/50
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5j
ND/2.5
ND/2.5
ND/ 5
ND/2.5
85*
_JjD/2_.5_
At Waite
& Debolt
Drain
G
1940
S06
7/25/84
ug/kg
(ppb)
ND/5Q
ND/50
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
Nb/2.5
ND/2.5
MD/2.b
ND/2.5
ND/2.5
ND/2.5
MD/i.S
ND/2.5
ND/2.5
ND/ 5 i
ND/2.5
ND/2.5
ND/2.5
At
Titta.
Road
G
0915
S10
7/27/84
ug/kg
(ppb)
_NQ/100
ND/100
5J
ND/ 5
ND/ 5
ND/ 5
NO/ 5
ND/ 5
Mb/ 5
HD7 5
ND/ 5
ND/ b
ND/ 5
ND/ 5
1 ND/ 5 1
ND/ 5
ND/ 5
ND/ 5
ND/10
ND/ 5
9500*
ND/ 5
[Refer to notes page for explanation of data qualifiers and acronyms.]
-------
ischarger:
ample Date:
7/25-27/84
U.S. ENVIRONMENTAL PROTECTION AGENCY
REGION V
EASTERN DISTRICT OFFICE
Tittabawassee River Flood Plain Analyses
Sample Type: 8 C-8 hour flow proportioned composit
24C-24 hour flow proportioned composit
EVC-Equal volume composite
G-Grab
Station #• f^-1 FP-? Fp-3
Sample Type
Time
Sample Number 84ER04
Date
Parameter
I. YOLATILES (continued)
Bromome thane
Bromoform
Bromodichloromethane
Trichl orofluoromethane
Dlchlorodlfluoromethane
Chi orodi bromomethane
Tetrachloroethene
Toluene
Trichl oroethene
Vinyl chloride
Acetone
2-butanone
Carbon disultide
2-hexanone
4-methyl -2-pentanone
Styrene
Vinyl acetate
Total xylenes
At Dow
Tertiary
Pond
G
1550
S04
7/26/84
ug/kg
(ppb)
ND/Z.b
ND/Z . b
ND/Z.b
ND/2.b
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/50
ND/100
ND/ 5
ND/50
ND/50
ND/2.5
NO/ 5
ND/2.5
At Waite
& Debolt
Drain
G
1940
S06
7/25/84
ug/kg
(ppb)
ND/Z.b
ND/Z.b
ND/Z.b
ND/Z.b
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/50
ND/100
ND/ 5
ND/50
ND/50
ND/2.5
ND/ 5
ND/Z.b
At
Titta.
Road
G
0915
S10
7/27/84
ug/kg
(ppb)
ND/ b
ND/ b
ND/ b
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/lOiL
ND/200
ND/10
ND/100
ND/100
ND/ 5
ND/10
5J
-~~
•
• --
••^•— -
• • mi i • 1 1 —
-• •• ' "*
-------
scharger:
mple Date:
7/25-27/84
U.S. ENVIRONMENTAL PROTECTION AGENCY
REGION V
EASTERN DISTRICT OFFICE
Tittabawassee River Flood Plain Analyses
Sample Type: 8 C-8 hour flow proportioned composite
24C-24 hour flow proportioned composite
EVC-Equal volume composite
G-Grab
Station #
FP-1
FP-2
FP-3
Sample Type
Time
Samole Number 84ER04
Date
Parameter
At Dow
Tertiary
Pnnrl
G
1550
SQ4
7/26/84
ug/kg
(nob)
II. ACID AND BASE NEUTRAL POLLUTANTS
2 ,4 ,6-trichl orophenol
4-chl oro-3-methyl phenol
2-chl orophenol
2, 4-dichl orophenol
2, 4-dimethyl phenol
2-nitrophenol
4-nitrophenol
2,4-dlnltrophenol
4, 6-dlnltro-2-methyl phenol
Pentachl orophenol
Phenol
Benzole acid
2-methyl phenol
4-methyl phenol
2 ,4 ,5-trlchl orophenol
Acenaphthene
Benzldlne
1 ,2,4-trlchlorobenzene
Hexachlorobenzene
Hexachloroethane
Bis(2-ch1oroethy1)ether
Kin/in
ND/20
ND/10
ND/10
ND/10
ND/20
ND/100
ND/50
ND/20
ND/20
ND/10
ND/100
ND/10
ND/10
ND/100
ND/10
ND/40
ND/10
ND/10
ND/10
ND/10
At Walte
& Debolt
Drain
G
1940
S06
7/25/84
ug/kg
(ppbl
ND/10
ND/20
ND/10
ND/10
ND/10
ND/20
ND/100
ND/50
ND/20
ND/20
ND/10
ND/100
ND/10
ND/10
ND/100
ND/10
ND/40
ND/10
ND/10
ND/10
ND/10
At
Tltta.
Rnarl
G
0915
S10
7/27/84
ug/kg
(ppbi
ND/10
ND/20
ND/10
ND/10
ND/10
ND/20
ND/100
ND/50
ND/20
ND/20
ND/10
ND/100
ND/10
ND/10
ND/100
ND/10
ND/40
ND/10
ND/10
ND/10
ND/10
-------
ischarger:
ample Date:
7/25-27/84
U.S. ENVIRONMENTAL PROTECTION AGENCY
REGION Y
EASTERN DISTRICT OFFICE
Tittabawassee River Flood Plain Analyses
Sample Type
8 C-8 hour flow proportioned composU
24C-24 hour flow proportioned composlt
EVC-Equal volume composite
G-Grab
Station if- CD-1 Fp-9 FP-?
Sample Type
Time
Sample Number 84ER04
Date
Parameter
II. ACID AND BASE NEUTRAL POLL
2-chl oronaphthalene
1,2-dichlorobenzene
1 ,3-dichlorobenzene
1 ,4-dichlorobenzene
3,3*-dichlorobenzidine
2,4-dinitrotoluene
2, 6-dlnitro toluene
1,2-di phenyl hydrazine
Fluoranthene
4-chlorophenyl phenyl ether
4-bromophenyl pnenyl ether
Bi s( 2-chl oroi sopropyl ) ether
Bi s( 2-chl oroethoxy )me thane
Hexachl orobutadiene
Hexachlorocyclopentadiene
Isophorone
Naphthalene
Nitrobenzene
N-nitrosodimethylamine
N-ni trosodi phenyl ami ne
N-nitrosodi )roplyamine
Bis(2-ethyl iexy' Jphthalate
At Dow
Tertiary
Pnnrt
G
1550
end
7/26/84
ug/kg
(ppb)
.UTANTS Tc
ND/10
ND/10
ND/10
ND/10
ND/20
ND/20
ND/20
ND/20
ND/10
ND/10
ND/10
ND/20
ND/20
ND/10
ND/10
ND/10
ND/10
ND/10
ND/10
ND/10
NU/iU
ND/10
At Waite
& Debolt
Drain
G
1940
SQfi
7/25/84
ug/kg
(ppt^
Continued
ND/10
ND/10
ND/10
ND/10
ND/20
ND/20
ND/20
ND/20
ND/10
ND/10
ND/10
ND/20
ND/20
ND/10
ND/10
ND/10
ND/10
ND/10
ND/10
ND/10
nu/cV
•ND/10
At
Titta.
Road
G
0915
S1Q
7/27/84
ug/kg
(pob)
ND/10
ND/10
ND/10
ND/10
ND/20
ND/20
ND/20
ND/20
ND/10
ND/10
ND/10
ND/20 |
ND/20
ND/10
ND/10
ND/10
ND/10
ND/10
ND/10
ND/10
kin /9n
NU/^U
10J
__. ._._-- —
-------
ischarger:
ample Date: 7/25-27/84
U.S. ENVIRONMENTAL PROTECTION AGENCY
REGION Y
EASTERN DISTRICT OFFICE
Sample Type:
Tittabawassee River Flood Plain Analyses
8 C-8 hour flow proportioned composite
24C-24 hour flow proportioned composite
EYC-Equal volume composite
G-Grab
Station #
FP-1
FP-2
FP-3
Sample Type
Time
Sample Number 84ER04
Date
Parameter
At Dow
Tertiary
Pond
G
1550
S04
7/26/84
ug/kg
(ppb)
At Waite
& Debolt
Drain
G
1940
S06
7/25/84
ug/kg
(ppb)
11. ACID AND 6AS£ NEUTRAL POLLUTANTS (continued
Butyl benzyl phthalate
Dl-n-butyl phthalate
01-n-octyl phthalate
Diethyl phthalate
Dimethyl phthalate
Benzol a) anthracene
Benzol a)pyrene
Benzol b 1 k)fluoranthene
Benzol Ic ) f 1 uoranthene
Chrysene
Acenaphthylene
Anthracene
Benzo( ghl ) peryl ene
Fluorene
Phenanthrene
Dlbenzo(a,h)anthracene
lndeno(l,2,3-cd)pyrene
Pyrene
Aniline
Benzyl alcohol
4-chloroanlHne
Dlbenzofuran
ND/10
ND/10
450
ND/10
ND/10
ND/10
ND/20
ND/20
ND/20
ND/10
ND/10
ND/10
ND/20
ND/10
ND/10
ND/20
MD/20
ND/10
ND/10
ND/20
ND/50
ND/10
ND/10
ND/10
3100
ND/10
ND/10
ND/10
ND/20
ND/20
ND/20
ND/10
ND/10
ND/10
ND/20
ND/10
ND/10
ND/20
ND/20
ND/10
ND/10
ND/20
ND/50
ND/10
At
Titta.
Road
G
0915
S10
7/27/84
ug/kg
(ppb)
ND/10
ND/10
ND/10
ND/10
ND/10
ND/10
ND/20
ND/20
ND/20
ND/10
ND/10
ND/10
ND/20
ND/10
ND/10
ND/20
ND/20
ND/10
ND/10
ND/20
ND/50
ND/10
-------
scharger:
imple Date:
7/25-27/84
U.S. ENVIRONMENTAL PROTECTION AGENCY
REGION V
EASTERN DISTRICT OFFICE
Tittabawassee River Flood Plain Analyses
Sample Type;
8 C-8 hour flow proportioned compositi
24C-24 hour flow proportioned composit
EYC-Equal volume composite
G-Grab
Station #: FP-1 FP-2 FP-3
Sample Type
Time
Sample Number 84ER04
Date
Parameter
!I. ACID AND BASE NEUTRAL POL
2-methyl naphtha! ene
2-nitroaniline
3-nitroaniline
4-nitroaniline
At Dow
Tertiary
Pond
G
1550
S04
7/26/84
ug/kg
(ppb)
At Waite
& Debolt
Drain
G
1940
S06
7/25/84
ug/kg
(ppb)
UTANTS (continued
ND/20
ND/100
NO/100
ND/100
ND/20
NO/100
ND/100
ND/100
At
Titta.
Road
G
0915
S10
7/27/84
ug/kg
(ppb)
ND/20
ND/100
ito/100
ND/100
-------
scharger:
smple Date:
7/25-27/84
U.S. ENVIRONMENTAL PROTECTION AGENCY
REGION V
EASTERN DISTRICT OFFICE
Tlttabawassee River Flood Plain Analyses
Sample Type: 8 C-8 hour flow proportioned composite
24C-24 hour flow proportioned composite
EVC-Equal volume composite
G-Grab
Station #: FP-1 FP-2 FP-3
Sample Type
Time
Sample Number 84ER04
Date
Parameter
III. PCB/PESTICIDE POLLUTANTS
AldHn
DieldHn
Chlordane
4, 4 '-DDT
4,4'-DDE
4, 4 '-ODD
Alplia-endosulfan
Beta-endosulfan
Endosulfan sulfate
Endrin
Endrin aldehyde
Heptachlor
Heptachlor epoxide
Alpha-BHC
Beta-BHC
Gamma-BHC
Dena-BHC
PCB-1242
PCB-I254
PCB-1221
PCB-1232
PCB-1248
PCB-1260
PCB-1016
Toxaphene
At Dow
Tertiary
Pnnrt
G
1550
S04
7/26/84
ug/kg
(ppb)
ND/4.0
ND/4.0
ND/4.0
6.6
ND/4.0
7.3
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
At Waite
& Debolt
Drain
G
1940
S06
7/25/84
ug/kg
(ppb)
ND/4.0
ND/4.0
ND/4.0
ND/4.0
88
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
At
Titta.
Rnflrt
G
0915
S10
7/27/84
ug/kg
(ppb)
Nb/4.0
ND/4.0
ND/4.0
31
43
13
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
Nb>4.6
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4,0,,.
-------
scharger:
;mple Date:
7/25-27/84
U.S. ENVIRONMENTAL PROTECTION AGENCY
REGION V
EASTERN DISTRICT OFFICE
Tittabawassee River Flood Plain Analyses
Sample Type:
8 C-8 hour flow proportioned composit
24C-24 hour flow proportioned composit
EVC-Equal volume composite
G-Grab
Station #: FP-1
FP-2
FP-3
Sample Type
Time
Sample Number 84ER04
Date
Parameter
IV. METALS**
Aluminum
Antimony
Arsenic
Barium
Beryllium
Cadmium
Chromium
Cobalt
Copper
Iron
Manqanese
Nickel
Selenium
Silver
Thallium
Vanadium
Zinc
At Dow
Tertiary
Pond
G
1550
S04
7/26/84
mg/kg
(ppm)
4300C
ND/.3
3.9
53. 4C
0.21
0.25
11.7
3.35
20. OC
16700C
381
7.80
0.18
ND/.15
ND/.l
9.70
48. 4C
At Waite
& Debolt
Drain
G
1940
S06
7/25/84
mg/kg
(ppm)
4300C
ND/.3
4.7
54. OC
0.25
0.25
12.5
3.8
17. 1C
9516C
579
8.50
0.16
ND/.3
ND/.l
10.6
51. 5C
At
Titta.
Road
6
0915
S10
7/27/84
mg/kg
(ppm)
4030C
ND/.3
4.0
47. 6C
0.17
0.24
11.5
3.40
18. OC
8&20C
423
7.70
0.18
0.31
ND/.l
9.70
53. 2C
-------
APPENDIX B-6
PCDDs and PCDFs
1984 USEPA Study
-------
Data Report X
Table V: Second Stage Analysis of Sediment and Sludge for TCOD
by the Absolute Intensity Method
by GLC/HRMS
ID# Nature of Sample Sample Wt. Conc(ppt)1 Cone, at2 dl 1 320/3
100% rec 1 322
•
UN 160 Sediment
UN 161
UN 162
UN 163
UN 164
UN 165
UN 166 Sludge
UN 167
UN 168
UN 169
UN 170
UN 171
UN 172 Water
UN 173
9.13
9.46
9.75
9.02
9.36 ;
10,15
9.27
10.23
4.85
7.23
9.50
4.08
199.
181
ndH
nd
nd
nd
nd
nd
nd
nd
97
3500
280
170 *
nd
.23 .
8
41
12
680
48
10
8
8
T60 12
5800 56
470 10
283 48
.25
.38 .2
-
.215
1.635
2.005
1.965
-
.966
.SO6
.78
.78
.80
.79
2.165
.84
1. ppt = parts per trillion
2. Corrected by assuming a recovery of 60% based on results of blanks run with
these samples.
3. Theoretical value: 0.771 .10
4. Peak observed at m/z 322 only
5. Peak observed at m/z 320 and 322 but isotope ratio incorrect
6. Small signals were detected at approximately 8 ppt which may indicate a
positive. Validation of samples at this level is sometimes difficult.
-------
Mr. Michael Dellarco
Page 3
August 5, 1980
The results of attempts to validate the positive samples found in Tables
I through III are reported in Table VI. Of the four samples that we recorded
as positive in the first three tables, none could be confirmed using the
m/z 320: m/z 322 isotope ratio. We feel that there may be positives among
this set of samples; however, the positives are below the recorded detection
limits.
The first results of the monkey tissue analyses are contained in Table VII.
These samples were extracted by Pat O'Keefe at the New York State Department
of Health. As you can see, a significant fraction of the samples contain
readily measured concentrations of TCDO. We have asked Pat O'Keefe to send
to us an extraction procedure, and when we receive it, I will forward a copy
to you to be appended to this report. You asked about concentration of
PCB's in these samples. The remainder of the samples show no evidence for
this contaminant. We can conclude that the level of PCB must be considerably
less than 1000 times the reported TCDD concentration. That means that if
the TCDD concentration is 100 parts per trillion or the detection limit 1s
100 parts per trillion, the maximum amount of PCB in the sample would be
100 parts per billion. Of course, this does not mean that no PCB's were
in the original sample. Recall that the clean-up procedure 1s designed to
minimize PCB contamination.
We have arranged our priorities for extraction in the near future and have
begun with the extraction of the four fish samples submitted to us from
Hemlock, Michigan.
If you have questions on any of these analyses, please give me a call.
Sincerely yours,
Michael L. Gross
Professor
MLGcep
-------
Department of Chemistry
Lincoln. NE 68588
The University of Nebraska-Lincoln 402-472-3501
August 5, 1980
Mr. Michael Dellarco
Special Pesticides Review
CM-2, Room 711K
TS 791
401 M Street, SW
Washington, DC 20460
Dear Mike:
This letter constitutes the cover for Data Report X. The report consists of
Table I for UN Series Samples 191 to 204, Table II for UN Series Samples 185
to 188A, Table III for UN Series Samples 118 and 127, Tables IV and V for
UN Series Samples 159 to 173.
•
The first analyses of the biological samples contained in Table I showed that
all samples clearly contained no detectable levels of TCDD except for Sample
UN-204. However, the attempt to validate UN-204 by measuring the isotope
ratio of m/z 320 and m/z 322 was not successful, and therefore the sample must
be considered to contain a not detectable amount of TCDD. However, it is
possible that there is a very low level concentration of TCDD in this sample.
It may be worth further investigation. The detection limits for these
samples ranged from two to eight parts per trillion except for UN-193 which
gave a detection limit of 18 parts per trillion. This detection limit is
high because of the poor recovery for the sample. As I mentioned in my last
letter, we are reextracting samples UN-193, 197, 202. 203, and 204.
Among the samples reported in Table 2, one was found to contain TCDD on the
first stage of analysis. This sample, UN-188A, cannot be validated according
to the isotopic ratio measurements (see Table 6). You will note that some
of the samples in this table gave rather high detection limits. This is
because of the small samples sizes, less than one gram. Also included among
these samples is a Water Pick Cartridge which we purchased at a local
distributor and which we used as a validation sample to check for recovery
and for background level. The recovery for this analysis was 2Q% with a
detection limit of 12 parts per trillion. This result should be compared with
Sample UN-185 for which a recovery of 50% was obtained. We feel that the
low recovery for the new Water Pick Cartridge may be largely due to some
chromatography problems which we have recently solved, rather than a matrix
problem. Therefore, we feel we are in a position to analyze the remainder of
these filters if you wish. Please advise!
In this data report, we present results on a set of sludge and sediment samples
(Table IV and V). These samples were analyzed in two stages. The first stage
employed the conventional method wherein we monitor m/z 322 and m/z 334 (the
C-13 internal standard). The results of the first stage of analysis of these
samples (Table IV) showed these matrices were extremely difficult to handle.
T>>n i inivor^itv of Nebraska Medical Cer
-------
Samples Obtained by USEPA Region V
October 1978
T1ttabawassee/Sag1naw Rivers; Dow Chemical - Midland Plant
USEPA-Reglon V UML
Sample Number Number Sample Site
Tittabawassee River/Saglnaw River Sediments
EA06S12 UN159 Tittabawassee River - Dow Chemical Bridge Upstream
of Dow Dam
EA06S13A UN160 Tittabawassee River - near Smith's Crossing Road
EA06S13B UN161 Tittabawassee River - near Smith«s Crossing Road
EA06S14 UN162 Tittabawassee River - at Free!and Road
EA06S15 UN163 Tittabawassee River - at Center Road Upstream from
Saginaw
EA06S16 UN164 Saginaw River - 1-75 at ZHwaukee
EA06S17 UN165 Saginaw River - Salzburg Road at Bay City
Dow Chemical Sludges/Wastewaters
EA06S18A UN166 Phenol Treatment System - Waste Primary Sludge
EA06S18B UN167 Phenol Treatment System - Waste Primary Sludge
EA06S19 UN168 Phenol Treatment System - Waste Activated Sludge
EA06S24 UN169 General Treatment System - Waste Primary Sludge
EA06S2S UN170 General Treatment System - Primary Skimmings
EA06S26 UN171 General Treatment System - Waste Activated Sludge
EA06S28 UN172 2,4-D Process Waste to Deep Well
EA06S29 UN173 Raw Phenol Wastewaters after Equalization
-------
APPENDIX C-l
1978 USEPA Sediment Survey
-------
APPENDIX C
Tittabawassee River Sediments
-------
ACCESS NO: 158-1
11
XCWP T-PUND POST-SAND FILTER 3/19-23 COMPOS PART. (REF 3
PCST-SANO: 03198*
3 333333X3233X3333333
SPECIES MONITORED
S 3333=33333=3.3333X23
1*69. TCCO
1269. TCCC
1267. TCOC
1289. TCDC
1269. TCDO
1 2*7+12*8. TCOO
1278. TCDO
1268. TCDC
1237+1238. TCOD
1279. TCDC
12*6. TCOO
1*73. TCCC
1236. TCOD
1239. TCDD
12*9. TCCC
1263. TCOC
1379. TCCD
1276. TCOC
123*. TCDO
TCTAL ISC-TCDOS
2378. TCDD
12C. 2378. TCOO RECCVE
0.0193G (FROM TSS)
£333333 = 33 333333 33333
CONCENTR
PPB ( LCD )
S3 2 = 33333333333333333
N 0.*)
N 0.*)
N 0.*)
N 0.*)
N 0.3)
2.1 0.3)
N 0.3)
0.3 ( C.3)
36. C ( _ )
N ( 0.5)
N ( 0.3)
_ )
N 0.3)
N 0.3)
N 0.2)
6*.C _ )
39. C _ )
2.9 C.3)
N 0.3)
1 * * . 3
0.* ( 0.3)
RY 82X
2*07-107-3
3333333333333X33
A T I 0 N
RELATIVE (X)
33333333 33333333
N
N
N
N
N
1.5
N
0.2
2*. 9
N
N
^
N
N
N
**.2
27.0
2.0
N
99.7
0.3
2373.TCDF
13C.2378.TCDF RECOVERY
0.7 ( 0.7)
86X
1
1
1
1
1
1
1
2*679 +
23*68.
23679 +
23*69.
23*78.
23678.
23*67+
12*689
HCOO
123639
HCDD
HCDD
HCOO
123789
.HCDO
S
.HCDOS
.hCDO
S
2
1
5
•
•
•
N
^^
N
6
C
C
(
(
(
(
(
(
(
1.0)
1.0)
1.0)
)
iTo)
_ )
1.0)
30
11
58
.2
.6
.1
N
^^
N
TCTAL HCDDS
12C.123*78.HCDO RECOVERY
8.6
100.0
8 OX
1 23*679. HC70D
123*678. HC700
17. C (
15.0 {
_ ) 53.1
_ ) *6.9
32. C
100.0
89X
TCTAL H7CDDS
H7CCD CORRECTION FACTOR
OCDQ
12C.CCDO RECOVERY
3 ===== = === = = = = ========= =
N*NQT DETECTED AT LOO I.E. 2.5X PEAK TO VALLEY NOISE
( ) SIGNIFIES RESPONSE >= 25X PEAK TC VALLEY NOISE
120.0 ( _ )
96*
-------
ACCESS NO: 157-III
T-PONO POST-SAND FILTER 3/19-22 COHPOS (REF 5158)
3450.6G TCTAL WATER 2407-107-3
XCW
SPECIES MONITORED
CONCENTRATION
PPQ
( LCD ) RELATIVE (X)
1469. TCCD
1269. TCDO
1267. TCDC
1289. TCCO
1369.TCDU
1247+1248. TCDD
1278. TCCD
1268. TCDO
1237+1233. TCOO
1279. TCDO
1246. TCCD
1478. TCCD
1236. TCDO
1239. TCDD
1249. TCCD
1368. TCDC
1379. TCCC
1378. TCDD
1234. TCCO
TCTAL 1SC-TCDDS
2378. TCCD
13C. 2378. TCDO RECOVERY
2378. TCOF
13C.2378.TCDF RECOVERY
124679+124689. HCOOS
1 23468. HCOO
123679+123689. VCDDS
1 23469. HCDD
1 234 78. HCDD
123676. HCOD
123467+123789. HCDOS
TCTAL HCDOS
12C. 123478. HCDD RECOVERY
1 234679. HC7DD
1 234678. HC7DO
TCTAL H7CDDS
H7CCD CORRECTION FACTOR
OCDC
N ( 2.0)
N ( 2.0)
N ( 2.0)
N < 2.0)
N ( 2.0)
12.0 ( 2.0)
N ( 2.0)
2.C ( 2.0)
200. C ( _ )
N ( 3.0)
N ( 1.0)
( )
N < 2.0)
N ( 1.0)
N ( 1.0)
360.0 ( _ )
220.0 ( _ )
16.0 ( 2.0)
N ( 1.0)
810.0
2.0 ( 1.4)
32%
4.0 ( 4.0)
86%
15.0 7.0)
8.0 7.0)
28.0 7.0)
_ )
N 7.0)
_ )
N 7.0)
51.0
80%
96.0 ( . )
83.0 ( _ )
179. C
89%
690. C ( _ )
N
N
N
N
N
1.5
N
0.2
24.6
N
N
T
N
N
N
44.3
27.1
2.0
N
99.8
0.2
29.4
15.7
54.9
^
N
^^
N
100.0
53.6
46.4
100.0
12C.CCOO RECOVERY
N=NOT DETECTED AT LDD I.E. 2.5X PEAK TO VALLEY NOISE
nrcnr-*icc V— "> K Y
TT V«I(PY NHTSF
-------
ECWP T-PCNO OUTLET
T-DISCHARGE: 031984
x ss«rz3sssss»sas*=*
SPECIES MONITORED
ACCESS NC: 156-111
3/19-23 CQMPCS PART. (REF 5155)
0.0373G (FROh TSS) 2*07-107-2
: r s s s x x :
CONCENTRATION
PPB
( LCD ) RELATIVE (X)
= 3 = = s = ss
1 469. TCCO
1 269.TCDC
1267. TCDD
1289. TCCD
1369. TCCD
1247+1243. TCOO
1 278. TCCC
1268. TCCD
1237+1238. TCDO
1279.TCCL
1246. TCDD
1 473. TCCC
1236. TCDO
1239. TCCD
1249. TCCD
1368. TCDO
1379. TCCC
1378. TCDD
1234. TCOD
TCTAL 1SC-TCODS
2378. TCCC
N
N
N
N
0.6
5.7
0.5
0.6
110.0
N
0.2
N
N
0.3
190.0
110. C
7.2
0.2
425.3
1.2
0.2)
0.2)
0.2)
0.2)
C.4)
. )
0.4)
C.4)
_ )
0.8)
0.1)
_ )
0.6)
0.1
C.I
= 25X PEAK TC VALLEY NCISE
-------
ECW T-POND OUTLET
T-OI5CHARGE: 03198*
ACCESS NC: 155-111
3/19-23 COMPCS (REF 5156)
3457.9G TOTAL WATER 2407-107-2
SPECIES MONITORED
- szszsz ssrzajsazsrsaz ss as
1*69. TCCC
1269. TCDC
1267. TCCO
1289. TCOO
1269. TCOC
12*7+1248. TCDO
1278. TCCC
1268. TCCO
1237+1238. TCOD
1279. TCDO
12*6. TCCO
1*78. TCCO
1236. TCOC
1239. TCCD
12*9. TCCO
1 363. TCCO
1379. TCCD
1378. TCCD
123*. TCDO
TCTAL ISC-TCDDS
2378. TCOO
13C. 2378. TCOO RECOVERY
C 0 N C £
PPQ 1
3SSSZ2 2553
N
N
N
N
6.C
62.0
5 .0
6 .0
1200.0
N
2.0
N
N
3.0
2COO.C
1200.C
78 .0
2.C
4564. C
13.0
1
: N T R
LCD )
: s s, ss x *
2.0)
2.0)
2.0)
2.0)
4.0)
_ )
4.0)
4.0)
_ )
9.0)
1.0)
_ )
[ 7.0)
[ 1.0)
I 1.0)
t - )
[ _ )
[ _ )
( 1.0)
( _ )
55%
A T I 0 N
RELATIVE (X)
XSX333X3X3232S 3 3 S
N
N
N
N
0.1
1.4
0.1
0.1
26.2
N
0.0
N
N
0.1
43.7
26.2
1.7
0.0
99.7
0.3
2378.TCOF
13C.2378.TCOF RECCVERY
16.C ( 5.0)
72*
1
1
1
1
1
1
1
2*679 +
23468.
23679 +
23*69.
23478.
23678.
23467+
124689
HCOD
123689
HCOO
HCOO
HCOO
123789
.HCOOS
.HCCC
s
.HCDOS
87
52
150
35
19
.C (
.0 (
.C (
_ (
7o (
<
7o (
77
_
77
_
77
0
0
25
15
43
10
)
0) 5
•
•
•
_
•
•
4
2
7
2
5
TCTAL HCDDS
13C. 123473. HCDO RECOVERY
343.0
100.0
9CX
123*679. HC7DD
1 23*673. HC7DD
770.C (
690.0 (
_ ) 52.7
_ ) 47.3
TCT4L H7CODS
H7CCO CC*RECTICN FACTOR
1460. C 100.0
ABSOLUTE
OCDO
13C.OCOO RECOVERY
N=NQT DETECTED AT LOO I.E
t_) SIGMFIES RESPONSE > =
7800. C ( _ )
ABSOLUTE
, 2.5X PEAK TD VALLEY NOISE
25X PEAK TC VALLEY NCISE
-------
ACCESS NO: 150-111
XCWP T-PONO PCST-SANO FILTER 3/12-16 CQPPCS PART. (REF
POST-SAND: 031284 0.01790 (FROM TSS) 2407-91-3
S232Z23S3232»Z3ZZ333:ZZSS.333=Z3ZZ32Z3zazSZ383233ZS;z:ZZZZ3
SPECIES MONITORED CONCENTRAT ION
PPB ( LCD ) RELATIVE (X)
23333322323S222222S2222233333335S2232223
1 *69. TCCD
1269. TCOD
1267. TCCD
1289. TCDO
1369. TCOO
1247+1248. TCDD
1278. TCDO
1269. TCOD
1237+1238. TCOO
1279. TCDO
1246. TCOO
1478. TCCC
1236. TCOD
1239. TCOO
1249. TCDC
1368. TCDO
1379. TCOD
1378. TCDD
1234. TCDO
TCTAL ISC-TCDDS
2375. TCCD
13C.237S.TCDO RECOVERY
2373. TCDF
12C.2378.TCDF RECOVERY
124679+124689. HCDOS
123468. HCOO
1 23679+123689. HCCDS
123469. HCOD
123478. HCOD
1 23679. HCDD
123467+123739. HCCDS
TCTAL HCDDS
13C. 123478. HCDC RECOVERY
1234679. HC700
1 23467S.HC70D
TCTAL H7CDOS
H7CCD CORRECTION FACTOR
N
N
N
N
N
5.6
0.6
1.0
110.0
N
0.2
N
N
N
210. C
140.0
7.7
N
475.1
0.7
1.2
5.0
4.C
3.0
273
27o
21.3
23.0
21. C
44. C
( 0.3)
( 0.3)
( 0.3)
( 0.3)
( 0.4)
( _ )
( 0.4)
( 0.4)
{ _ )
( C.4)
( C.2)
( __ )
( C?7)
( 0.2)
( 0.2)
( _ )
( _ )
( _ )
( 074)
( 0.2)
77%
( C.7)
73^
2.0)
2.0)
2.0)
)
27o)
_ )
27o)
85X
( _ )
( _ )
9CX
N
N
N
N
N
1.2
0.1
0.2
23.1
N
0.0
N
N
N
44.1
29.4
1.6
N
99.9
0.1
23.5
18.8
37.6
io7a
974
100.0
52.3
47.7
100.0
OCDD 150.0 ( _ )
1 3C.DCDO RECOVERY 96%
N=NOT DETECTED AT LOD I.E. 2.5X PEAK TO VALLEY NOISE
(_) SIGNIFIES RESPCNSE >* 25X PEAK TC VALLEY NCISE
-------
ACCESS NO: 149-111
XCW T-PONO POST-SAND FILTER 3/12-16 COPOS (REF 5150)
PCST-SAKO: 031284 3433.2G TCTAL WATER 2407-91-3
= ======. = ==X=== = ===X= ===== = = = = = = = ====X=X3S=XS=3=ZX = = = = = =
SPECIES MONITORED CONCENTRATION
PPQ ( LCD ) RELATIVE U)
1469.TCCC N ( 2.0) N
1269.TCDO N ( 2.0) N
1267.TCCD N ( 2.0) N
1289.TCCC N ( 2.0) N
1369.TCDO N < 2.0) N
1247+1248.TCOD 29.0 < . ) 1.2
1273.TCDO 3.C ( 2.0) 0.1
1268.TCCC 5.C ( 2.0) 0.2
1237 + 1236.TCOO 550.0 ( _ ) 22.4
1279.TCOD N ( 2.0) N
1246.TCCC 1.0 ( 1.0) 0.0
1478.TCCC . ( > )
1236.TCOC N ( 4.0) N
1239.TCCC N ( 1.0) N
1249.TCCC N ( 1.0) N
1368.TCDO 1100.C ( _ ) 44.9
1379.TCCC 720.C ( . ) 29.4
1373.TCCC 40.C ( . ) 1.6
1234.TCOC N ( 2.0) N
TCTAL ISC-TCODS 2443.C 99.9
237C.TCDO 3.4 ( 1.0) 0.1
13C.2378.TCOD RECOVERY 77*
2378.TCCF 6.C ( 4.0)
13C.2378.FCOF RECOVERY 73%
124679+124689.HCODS 26.C ( 9.0) 23.6
123468.HCOO 21.C ( 9.0) 19.1
123679+123689.HCODS 42.C ( 9.0) 38.2
1 23469. HCOO _ ( _ )
123478.HCDO 12.0 ( 8.0) 10.9
123678.HCOD _ ( _ )
123467+123739.HCOOS 9.C ( 8.0) 8.2
TCTAL HCDOS 110.0 100.0
13C.123473.HCDC RECOVERY 85%
1234679.HC700 120.0 ( _ ) 52.2
1234678.HC700 110.C ( _ ) 47.8
TCTAL H7CDOS 230.0 100.0
H7COD CORRECTICN FACTOR 90%
OCDO 800.C ( _ )
13C.OCOO RECOVERY 96%
N=NCT DETECTED AT LOO I.E. 2.5X PEAK TO VALLEY NOISE
i > CT/-MTCTCC pcsppNSF >= ?5X PFAK TC VALLEY NOISE
-------
ECWP T-PQND OUTLET
T-DISCHARGE: 03128*
s====s===r==s===zr=
SPECIES MONITORED
ACCESS NO: 1*8-111
3/12-16 COMPCS PART. {REF 51*7)
0.1026G (FROf TSS) 2*07-91-2
: s 2 s 3 = =:
CONCENTRATION
PPB ( LCD ) RELATIVE (X)
1*69. TCCO
1269. TCCC
1267. TCCO
1289. TCOD
1369. TCDO
12*7+12*8. TCDO
1278. TCCD
1 268. TCDO
1237+1238. TCDD
1279. TCCC
12*6. TCDD
1*78. TCCO
1236. TCDC
1239. TCOO
1 2*9. TCDD
1368. TCDD
1379 .TCDC
1378. TCCD
123* .TCCC
TCTAL ISC-TCDDS
2378. TCDD
N
O.E
N
N
0.9
19. C
1 .C
2.0
370.0
N
0.2
N
0.5
0.3
780. C
*70.0
26. C
0.2
1670.9
2.0
0.5)
0.5)
0.5)
0.5)
0.3)
_ )
C.5)
C.5)
_ )
C.8)
0.0)
_ )
1.9)
_ )
C.O)
_ )
_ )
_ )
0.0)
( - )
N
0.0
N
N
0.1
1.1
0.1
0.1
22.1
N
0.0
•—
N
0.0
0.0
*6.6
28.1
1.6
0.0
99.9
0.1
13C.2378.rCOD RECOVERY
8C*
2378.TCDF
13C.2378.TCOF RECOVERY
3.1 ( _ )
76X
12*679+12*689. HCDDS
123*68. HCDO
1 23679+123689 .HCDDS
1 23*69. HCDO
1 23* 78. HCDO
123678. HCOO
123*67+123789. HCDCS
15. C
18.0
3*.C
_
loTo
_
3?9
_ 1
_
—
^^
0.5
18.5
22.2
*2.0
—
12.*
^
*.8
TCT4L HCCOS
13C.123*78.HCDO RECOVERY
80.9
100.0
95%
1 23*679. HC70D
1 23*678. HC700
110.0 (
120.0 {
_ ) *7.8
_ ) 52.2
TCTAL H7COOS
H7CDD CORRECT ICN FACTOR
230.0 100.0
AESCLUTE
OCDO
13C.CCDC RECOVERY
1600.0 ( _ )
ABSOLUTE
N=NCT DETECTED AT LOD I.E. 2.5X PEAK TO VALLEY NOISE
( ) DIGNIFIES RESPONSE >= 25X PEAK TC VALLEY NOISE
-------
ECW T-PCNO
T-OISCHARGE:
CUTLET
031284
ACCESS NO: 147-III
3/12-16 C3MPCS (REF 3148)
2663.7G TCTAL WATER 2407-91-2
SPECIES MONITORED
3 ==3333==33SS3SSS = =33=S =
1169. TCCC
1269. TCDO
1267. TCOO
1 289. TCCC
1 369.TCCO
1247 + 1248. TCDO
1278. TCCD
126«J. TCCC
1237 + 1238. TCDO
1279. TCDC
1246. TCDC
1 47?. TCCD
1236. TCCD
1239. TCCD
1249. TCCC
1 368. TCCC
1379. TCCO
1378. TCDD
1 234. TCCC
TCTAL ISC-TCDDS
2378. TCDO
13C.2378.TCOD RECOVERY
C C N C E
PPQ <
= = S = SS 3 = 33
N <
3.0 (
N <
N
35.0
750.0
40. C
80.0
14000. C
N
8.C
N
21 .0
12.0
30000. C
18000. C
1000.C
9.C
63958. C
76. C
f
N T R
LCD )
I 33 33 S3
2.0)
2.0)
2.0)
2.0)
10.0)
_ )
20?0)
20.0)
_ )
3o7o)
2.0)
)
75?0)
_ )
27o
_ )
)
_ )
27o
t _ )
>0%
A T I 0 N
RELATIVE (5,')
33S3333XSS33XS3S3
N
0.0
N
N
0.1
1.2
0.1
0.1
21.9
N
0.0
_
N
0.0
0.0
46.9
28.1
1.6
0.0
99.9
0.1
2378.TCOF
13C.2378.TCOF RECOVERY
120.0 (
1
1
1
1
1
1
1
24679 +
23468.
23679 +
23469.
23473.
23678.
23467+
124689
HCDD
123689
HCDD
HCDD
HCOD
123789
.HCDOS
.HCCCS
.HCODS
580
700
1300
390
150
• C (
.0 (
.0 (
( _
• C (
*
To ( 2c7o
18
22
41
12
4
.6
.4
.7
_
.5
^
.8
TCTiL HCCOS 3120.C
13C.123473.HCOD RECOVERY 95X
100.0
1234679.HC700
1 234678.HC700
4100.0
4800.C
46.1
53.9
TCTAL H7C9DS
H7CCC CORRECTION FACTOR
8900.C 100.0
ABSOLUTE
OCDO
13C.CCOC RECOVERY
60000.C ( _ )
ABSOLUTE
N=NCT DETECTED AT LOO I.E. 2.5X PEAK TO VALLEY NOISE
(.) SIGNIFIES RESPONSE >= 25X PEAK TC VALLEY NOISE
-------
ACCESS NC:
XCWP T-PONO POST-SAND FILTER 3/5-9
PCST-SANC: 03058* 0.031CG (FROM
1*2-111
COMPCS
TSS)
PART. (REF
2*07-76-3
1*1)
SPECIES MONITORED
CO
PPB
N C
N T
LOO
T I 0 N
RELATIVE
(X)
sazrs - ---:
1*69. TCCC
1269. TCOO
1267. TCOC
1289.TCDC
1369. TCCC
12*7 + 12*8. TCDO
1273. TCCC
1268. TCCO
1 237 + 1238. TCDO
1279. TCCC
1 2*6. TCCO
1*73. TCOO
1236. TCCD
1239. TCCO
12*9. TCCO
1368. TCOC
1379. TCCO
1378. TCCD
123*. TCCD
TCTAL ISO-TCOOS
2373. TCDO
N
N
N
N
N
*.9
0.*
0.*
69.0
N
N
_
N
N
N
120. C
86. C
5.C
N
285.7
0.6
0.3)
0.3)
C.3)
0.3)
C.3)
_ )
0.3)
0.3)
_ )
0.3)
0.3)
. )
0.5)
0.3)
0.3)
_ )
_ )
_ )
0.3)
( C.2)
N
N
N
N
N
1.7
0.1
0.1
2*.l
N
N
N
N
N
*1.9
30.0
1.7
N
99.8
0.2
13C.2378.TCOO RECOVERY
79%
2373. TCDF
13C.2376.TCDF RECOVERY
12*679+12*689. HCODS
1 23*68. HCDO
123679+123689. HCDDS
123*69. HCOD
1 23*78. HCDO
123678. HCOO
123*67+123789. HCDOS
TCTAL HCDOS
13C. 123*78. HCOD RECOVERY
123*679. HC 700
1 23*678. HC70D
TLTAL H7CODS
H7C3D CORRECTION FACTOR
0.9
*.C
*.C
8.2
2.0
1.0
19.2
17. C
17.0
3*.0
( 0.7)
86X
( 1.0)
( 1.0)
( 1.0)
( _ )
( 1.0)
( _ )
( 1.0)
81X
( _ )
( _ )
82%
20.8
20.8
*2.7
10.*
5.2
100.0
50.0
50.0
100.0
OCDO
13C .OCDD RECOVERY
1*0.0 ( _ )
83%
N=NC7 DETECTED AT LOO I.E. 2.5X PEAK TO VALLEY NOISE
{_) SIGNIFIES RESPONSE >= 25X PEAK TC VALLEY NOISE
-------
ACCESS NC: 1*1-111
XCW T-PUND PCST-SANO FILTER 3/5-S CQMPCS (REF 51*2)
PLST-SANC: 03058* 3373.3G TCTAL WATER 2*07-76-3
ssxsr s;
SPECIES MONITORED
1*69. TCCO
1269. TCOC
1267. TCCO
1289. TCCC
1269. TCCO
1 2*7 + 12*8. TCDD
1278. TCOC
1268. TCDD
1237+1238. TCDO
1279. TCDD
12*6. TCOC
1*78. TCCC
1236. TCOO
1239. TCDD
12*9. TCCD
1368. TCCC
1379. TCDC
1378. TCDC
123*. TCDO
TCTAL ISC-TCOOS
237S.TCDC
13C. 2378. TCDO RECOVERY
2278. TCDF
13C.2378.TCOF RECOVERY
12*679+12*689. HCDCS
123*68. HCOO
123679+123639. HCDDS
123*69. HCDD
123* 78. HCOO
1 23673.HCOD
123*67+123789. HCDDS
TLTAL HCCOS
13C .123*78. HCDO RECOVERY
123*679. HC700
1 23*678. HC700
TCT4L H7CDOS
H7CCD CORRECTION FACTOR
C G N C
PPQ
N
N
N
N
N
*5.C
* .0
*.o
630.0
N
N
N
N
N
1100. C
790. C
*6.C
N
2619. C
5.C
a.o
*o.o
*o.c
75.0
is7c
_
10. C
180. C
160. C
160.0
320.0
E N T R
( LCD )
( 3.C)
( 3.0)
( 3.0)
( 3.0)
( 3.0)
( )
( 3.0)
( 3.0)
( _ )
( 270)
( 3.0)
( )
( s7o)
( 3.0)
( 3.0)
( _ )
( __ )
( _ )
( 370)
( 2.0)
79X
( 6.0)
86%
( 10.0)
( 10.0)
( 10.0)
( _ )
( ic7o)
( _ )
( 10.0)
six
( _ )
( _ )
82*
4 T I 0 N
RELATIVE (X)
tsxxsss^sssxsssss s s
N
N
N
N
N
1.7
0.2
0.2
2*.0
N
N
N
N
N
41.9
30.1
1.8
N
99.8
0.2
22.2
22.2
*1.7
873
576
100.0
50.0
50.0
100.0
IKDO
13C.DCOC RECOVERY
1300.C ( _ )
82*
N=N2T DETECTED AT LOO I.E. 2.5X PEAK TO VALLEY NOISE
i \ CTKNTFTFS RFSPHNSE >= 25X PEAK TC VALLEY NCISE
-------
ECWP T-PONO
T-OISCHARGE:
OUTLET
03058*
ACCESS NC: 1*0-111
3/5-9 COMPCS PARTICIPATES
0.0641G (FROP TSS) 2*07-76-2
(REF S
13S)
SPECIES MONITORED
CGNCtNTRAT ION
PP8 ( LCD ) RELATIVE (X)
:=2===s=a=r===rs==2==23222==a==
1 *69.TCCC
1269. TCCC
1267. TCCD
1289. TCCD
1 369. TCDC
1 2*7+12*8. TCOD
1273. TCCC
1268. TCOO
1 237 + 1238. TCOD
1279. TCDD
12*6. TCDD
1*73. TCCC
1236. TCCC
1239. TCDC
1 2*9. TCDC
1368. TCDO
1 379.TCUC
1373. TCCC
123*. TCDC
TCTAL ISO-TCDDS
2378. TCCC
13C. 2378. TCOD RECOVERY
237S.TCDF
1 2C.2378.TCDF RECOVERY
12*679+12*639. HCCOS
123*69. HCDD
123679+123639. HCCDS
1 23*69. HCDD
123*78. HCOD
123673. HCDD
123*67+123739. HCCDS
TCTAL HCDOS
13C. 123*78. HCDC RECOVERY
123*679. HC70D
123*678. HC700
TLT1L H7CDOS
H7COC CIKRECTICN FACTOR
OCDC
13C.CCDD RECOVERY
N
N
N
N
0.*
11 .C
1.2
1.3
170.0
N
N
N
0.2
0.2
220. C
1*0. C
9.*
0.1
553.8
0.9
1 .5
8.3
9.*
16. C
57o
27c
*0.7
53.0
53. C
106.0
510. C
0.2)
0.2)
0.2)
0.2)
0.*)
o7*)
C.*)
o7*)
0.2)
i7o)
0.2)
( 0.2)
< _ )
( _ )
( i7o)
( 0.1)
( 0.1)
7CX
{ C.3)
72*
( 1.0)
( 1.0)
( _ )
( _ )
( i7o)
( _ )
( i7o)
82*
( _ )
( _ )
9CX
( _ ,
99^5
N
N
N
N
0.1
2.0
0.2
0.2
30.6
N
N
N
0.0
0.0
39.7
25.2
1.7
0.0
99.8
0.2
20.*
23.1
39.3
1273
A 79
100.0
50.0
50.0
100.0
N=NCT DETECTED AT LCD I.E. 2.5X PEAK TO VALLEY NOISE
( ) SIGNIFIES RESPONSE >= 25X PEAK TC VALLEY NCISE
-------
ECU T-PONO
T-OISCHARGE:
ACCESS NC: 139-111
OUTLET 3/5-9 COMPCS (REF 5140)
030584 3409.7G TOTAL WATER 2407-76-2
SPECIES KCNI fORED
3
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
T
2
1
2
1
1
1
1
1
1
1
1
T
1
1
469.TCCC
269. TCOO
267. TCDO
289. TCCO
369.TCCD
247+1243. TCOO
273. TCOO
268. TCCO
237 + 1238. TCOO
279.TCDD
246.TCCC
478.TCDD
236. TCDO
239. TCDO
249.TCOC
368. TCDO
379.TCDD
375.TCDQ
234.TCDD
CTAL 1SO-TCOOS
378.TCCD
3C. 2378. TCOD RECCVERY
378.TCOF
3C.2376.TCOF RECOVERY
24679+124689. HCCOS
23468. HCOO
23679+123639. ^CODS
23469. HCOD
23478. HCOD
23678. HCOD
23467+123789. HCODS
CTAL HCCOS
3C. 123478. HCDO RECOVERY
234679. HC700
1234678. HC700
TCTAL H7CDDS
S 3 = 3 3
CON
PRO
3 S 3 3 S
9
200
22
23
3100
4
4
4 COO
2600
170
3
1013*
17
27
s
s
N
N
N
N
•
•
«
•
•
N
N
N
•
•
*
•
•
•
•
•
*
C
S =
0
C
0
C
C
C
C
C
C
C
C
C
C
0
E
(
S 3
(
(
(
(
(
(
(
(
(
(
(
(
(
(
7C
{
= =3,
N T
LOO
3 SS
3.
3.
3.
3.
7.
77
7.
77
3.
207
3.
3.
_
2c7
2.
2.
*
5.
333
R
9
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
)
s s
)
)
)
)
)
)
)
)
)
)
)
)
)
)
)
)
)
)
)
)
)
A T
=
3S:r==:SSSS*SS
I 0 N
RELATIVE (X)
3 S 3
s
S33SS3S3S3S3
N
N
N
N
0
2
C
0
30
•
*
•
•
•
1
0
2
2
5
N
N
N
0
0
39
25
1
0
99
0
•
•
•
•
•
•
•
•
0
0
4
6
7
0
8
2
72*
150
170
230
90
40
730
•
*
•
•
•
•
C
0
0
C
0
C
(
(
(
(
(
(
(
2C.
2C.
2C7
••
2C.
0)
0
0
0
)
)
)
)
)
)
20
23
38
12
5
100
•
•
•
.
•
•
5
3
4
3
5
0
82X
960
960
1920
•
•
•
C
0
C
H7C3D CORRECTION FACTOR
(
<
)
>
50
50
100
•
•
•
0
0
0
9C2
ocoo
13C.CJCUD RECOVERY
9100.C (
995:
N=NCT DETECTED AT LOO I.E. 2.5X PEAK TO VALLEY NOISE
< > DIGNIFIES RESPCNSE >= 25X PEAK TC VALLEY NOISE
-------
EEW T-POND OUTLET
WATER:051383-5
SPECIES MONITORED
ACCESS MC: 81-111
UNSETTLED HATER (REF 582)
1919.3G 2060-59-1
==========
rsxsxszcsssxsx
CCNCENTRAT10N
PPQ
( LCD ) RELATIVE (X)
: = 2 = = = s :
1469.TCOC
1269. TCOO
1267. TCCO
1289. TCDO
1369. TCDD
1247 + 124d.TCOO
1278. TCCO
1268. TCCC
1237+1238. TCDD
1279. TCCO
1246. TCDC
1 473. TCDO
1236. TCCO
1239. TCDO
1249. TCCC
1368. TCOD
1379. TCQC
1378. TfCD
1234. TCOO
TCTAL ISC-TCDDS
2378. TCCD
13C. 2378. TCDD RECOVERY
2373. TCOF
13C.2378.TCDF RECOVERY
1 24679+124689. HCDOS
123468. HCOO
123679+123689. HCCDS
123469. HCOO
123478. HCDO
1236 78. HCDO
123467+123789. HCDDS
N
N
N
N
4.C
22. C
N
3.C
94.0
N
3.C
N
N
N
2.C
345. C
97.0
11.0
N
581 .C
11 .C
_
^^
_
_mi
_
-
3.0)
3.0)
3.0)
3.0)
2.0)
)
?7o)
2.0)
( _ )
( 270)
( 2.0)
2.0)
2.0)
2.0)
2.0)
_ )
_ )
370)
3.0)
( 2.0)
87%
( _ )
-
( _ )
( _ )
_ )
)
_ )
_ )
- }
N
N
N
N
0.7
3.7
N
0.5
15.9
N
0.5
N
N
N
0.3
58.3
16.4
1.9
N
98.1
1.9
— ^
_
^^
_
TCTAL HCCOS
13C.123479.HCDO
RECOVERY
1234679.HC700
1234678.HC7DD
TCTAL H7CDDS
H7CDO CCSRECTICN FACTOR
OCDD
13C.GCOO
RECOVERY
==================== ======================S3I===XZ=z:
N=NCT DETECTED AT LOO I.E. 2.5X PEAK TC VALLEY NOISE
(_) SIGNIFIES RESPONSE >= 25X PEAK TC VALLEY NOISE
-------
ECU
ACCESS NO: 104-111
T-PQNO OUTLET UNFILTER5D KATER
WATER: C4C433-2W
975G
2C74-65-2H
zssssrssa
C3ZSSX.SSSS3S
i s s a s x
SPECIES MONITORED
CONCENTRATION
PPQ < LCD ) RELATIVE U)
1 469. TCOO
1269. TCOC
1267. TCOO
1289. TCDD
1 369. TCDO
1247+1248. TCOO
1278. TCDO
1263. TCOO
1 237+1238. TCOO
1279. TCDD
1246. TCDO
1478. TCDD
1236. TCOO
1239. TCDO
1249. TCDD
1 368. TCOO
1379. TCOO
1373. TCOO
1234. TCDO
TCTAL ISC-TCOOS
2378. TCDO
13C.2378.TCOD RECOVERY
2378. TCCF
13C.2378.TCDF RECOVERY
124679 + 124689. HCDOS
123468. HCOO
123679+123689. KOOS
1 23469. HCDD
123 4 73. HCOO
1236 78. HCOO
123467+123739. HCDDS
N
N
N
N
11.0
67.0
12. C
11 .0
360.0
9.0
N
7.0
7.C
N
8.C
750. C
270. C
34. C
5.0
1551 .0
40.0
(
-
6.0)
6.0)
6.0)
6.0)
6.0)
)
6?0)
6.0)
_ )
67o)
5.0)
5.0)
5.0)
5.0)
5.0)
_ )
)
570)
5.0)
f - )
J5*
( _ )
( _ )
_ )
)
)
_ )
_ )
- }
N
N
N
N
0.7
4.2
0.8
0.7
22.6
0.6
N
0.4
0.4
N
0.5
47.1
17.0
2.1
0.3
97.5
2.5
-
TCTAL HCDOS
13C. 123478.HCDD RECOVERY
1234679.HC700
1 234678.HC7DO
TCTAL H7CODS
H7CCD CCRRECTICN FACTOR
OCDD
13C.CCOD RECOVERY
N=NCT DETECTED AT LCD I.E. 2.5X PEAK TC VALLEY NOISE
( ) SIGNIFIES RESPCNSE >= 25X PEAK TC V4LLEY NCISE
-------
DOW CHEMICAL
2,3,7,8,TETRACHLORODIBENZO-P-DIOXIN
MOR SUBMITTALS TO MDNR
MONTH
JULY 1984
AUGUST
SEPTEMBER
OCTOBER
NOVEMBER
DECEMBER
JANUARY 1985
FEBRUARY
MARCH
APRIL
MAY
JUNE
JULY
AUGUST
SEPTEMBER
OCTOBER
NOVEMBER
DECEMBER
JANUARY 1986
February
March
MONTHLY AVE
PPQ
10.5
4.5
3.4
6.2
12.5
12.5
19
13
28
19
3
17
32
17
5
9
2
4
to
11(6/21),
5.9(7/23)
3.7(8/21)
3.5(9/24)
8.9(10/22
9(12/8),
24(12/21)
17(1/23),
12(2/21)
24(3/25),
3(4/21) 3
17(5/21),
33(6/24),
12(7/23),
5(8/21),
9(9/23),
2(10/21),
2(11/21),
5(ifc/*&)
8(1/21)
4(2/23)
10(7/1)
, 3.1(8/6)
, 3.0(9/3)
, 8.8(10/6)
), 16(11/5)
16(12/20)
, 14(1/2)
8(2/4)
44(3/5)
13(4/2)
(5/8)
16(6/3)
31(7/10)
22(8/5)
4(9/4)
8(10/3)
2(11/6)
5(12/4)
8(2/3)
3(3/3)
-------
APPENDIX B-7
PCDDs and PCDFs
Dow Chemical Data
-------
Mscharger:
Sample Date;
U.S. ENVIRONMENTAL PROTECTION AGENCY
REGION Y
EASTERN DISTRICT OFFICE
Dow Chemical Intakes/Outfall 031/Pilot Plant
Sample Type: 8 C-8 hour flow proportioned composite
24C-24 hour flow proportioned composite
EYC-Equal volume composite
G-Grab
Sample Type
Time
Sample Number 84ER06
Date
Parameter
DIOXINS AND FURANS
2378-TCbD
Total Tetra CODS
TbTal Penta CDDS
Total Hexa CDDS
Tolai Hepta CUDS
OCDD
2378-TCDF
Total Tetra CDFs
Total Penta CDFs
Total Hexa CDFS
Total Hepta CDFs
OCDF
Ti tta .
River
Intake
Com p.
1214-
0940
505
8/28-
29/84
P9/9
(ppt)
ND/.022
ND/.012
ND/.120
ND/.046
ND/.087
0.188
ND/.022
0.043
ND/.051
ND/.036
ND/.054
ND/.175
Lake
Huron
Intake
Comp.
1220-
0905
S10
8/28-
29/84
pg/g
(ppt)
ND/.045
ND/.015
ND/.150
ND/.057
ND/458
0.305
ND/.OZ9
ND/.013
ND/.057
ND/.043
ND/.104
ND/.126j
Outfal 1
031
Comp.
1206-
0853
S15
8/28-
29/84
pg/g
(ppt)
NO/. 050
ND/.035
ND/.126
ND/.082
NO/. 191
ND/.333
nn / nc£
ML)/ .USD
3.94
ND/.046
ND/.079
ND/.084
ND/.209
85ER03
Pilot
Plant
Influent
G
0825
S24
12/4/84
P9/1
(ppq)
NO/ 9d
2000
350
180
1400
5400
wn/ QU
12000
1700
1500
7400
6600
Pilot
Plant
Effluent
G
0857
S25
12/4/84
P9/1
(ppq)
NQ/ 8d
69
NO/17
180b
280&
790&
wn/ 7
1500
ND/33
NO/ 15
86
440°
b = Possible carryover from previous injection of standard.
d = Data for 2378-TCDD and 2378-TCDF was generated 3/1/85 using an Gometer SP 2330 column.
-------
scharger:
nple Date: 7/25-27/84
U.S. ENVIRONMENTAL PROTECTION AGENCY
REGION Y
EASTERN DISTRICT OFFICE
Tittabawassee River Flood Plain Analyses
Sample Type:
8 C-8 hour flow proportioned composite
24C-24 hour flow proportioned composite
EVC-Equal volume composite
G-Grab
Station #
FP-1
FP-2
FP-3
Sample Type
Time
Sample Number 84ER04
Date
Parameter
V. DIOXINS AND FURANS
2378-TCDD
Total Tetra CDDs
Total Penta CDDs
Total Hexa CDDs
Total Hej)ta CDDs
OCDD
Z378-TCDF
Total Tetra CDFs
Total Penta CDFs
Total Hexa CDFs
total Hepta COFs
OCDF '
At Dow
Tertiary
Pond
G
1550
S04
7/26/84
ng/g
(ppb)
ND/.01
0.11
0.09
0.14
2.1
16
0.02
1.0
0.10
0.15
0.65
1.3
At Waite
& Debolt
Drain
G
1940
S06
7/25/84
ng/g
(ppb)
ND/.01
0.13
ND/.01
ND/.01
0.53
3.9
0.11
1.5
0.09
0.04
0.65
1.5
At
Ti tta .
Road
G
0915
510
7/27/84
ng/g
(ppb)
ND/.03
0.36
0.12
0.20
1.3
7.8
2.18
7.6
4.1
1.7
1.9
2.3
-------
NOTES:
1. ND = Compound was analyzed for but not detected. Value reported is the detection limit.
2. * = Presence of compound may be due to sample bottle preparation, field and/or labora-
tory contamination. Methylene chloride is used as a cleaning agent for sample
bottles. Phthalate compounds are components of certain plastics and are widespread
in the environment at low levels.
3. ** = Data reported on wet weight basis.
4. J = Estimated value, detected below minimum specified contract detection limit but
greater than zero.
5. C = Blank corrected.
6. ug/kg = microgram per kilogram.
7. mg/kg = milligram per kilogram.
8. ppb = parts per billion.
9. ppm = parts per million.
10. ng/g = nanogram per gram.
-------
Tittabawassee River Sediment Analyses
Tentatively Identified Compounds
Station Number:
Sample Type:
Time:
Sample Number: 84ER04
Date:
CAS
Number Parameter
1604-34-8 2-undecanone, 6,10-dimethyl
638-66-4 Octadecanal
1120-25-8 9-hexadecenoic acid, methylester, (z)-
5129-60-2 Pentadecanoic acid, 4-methyl-,
methylester-
2091-29-4 9-hexadecenoic acid
57-10-3 Hexadecanoic acid
5353-25-3 Etnanol, 2-(9-octadecenyloxy)-, (z)-
26489-01-0 6-octen-l-ol, 3,7-dimethyl-, ( )-
1454-85-9 1-heptadecanol
630-06-8 Hexatriacontane
TK-1
Above
Ash
Pond
G
1610
SOI
7/25/84
ug/g
(PP"0
0.78 UK
0.91 01
1.5 UK
0.92 01
1.1 01
6.2 01
0.77 UK
1.0 UK
4.5 01
6.5 UK
1.1 UK
11.0 UK
2.7 01
2.0 Uk
2.3 UK
12.0 01
4.6 Ot
TR-2
Below
Ash
Pond
6
1700
S02
7/25/84
ug/g
(ppm)
1.6 UK
TR-3
Above
Lingle
Drain
G
1900
S03
7/25/84
ug/g
(Ppm)
1.2 UK
1.2 UK
1.7 UK
TR-4
Smith's
Crossing
G
2010
S05
7/25/84
ug/g
(ppm)
0.54 UK
TR-5
Upstream
of Brown
Mills
G
2050
S07
7/25/84
ug/g
(ppmj
TR-6
At
Freeland
Road
G
0840
S08
7/27/84
ug/g
(PP"0
TR-7
At
Titta.
Road
G
0920
S09
7/27/84
ug/g
(PPi")
1.2 RS
1. 1 UK
TR-8
At
Gratiot
Road
G
0945
S12
7/27/84
ug/g
(ppm)
TR-9
At
Center
Road
G
0850
S13
7/27/84
ug/g
(ppm)
3 .0 UK
0.73 01
6.0 01
1.7 UK
NOTES: 01 - Isomer or similar compound.
UK - Unknown, not in N8S library.
RS - Reasonable detection, retention time compatibility.
-------
CAS
Number
Station Number:
Sample Number:
Parameter
84ER04
3790-71-4 2,6,l()-dO(lecrttrten-l-ol,
3,7,11-trimethyl-, (Z,E)-
629-73-2 1-hexadecene
54833-48-6 Heptadecane, 2.6.10.15-tetramethyl-
56554-96-2 2-octadecenal
55320-02-0 9,12,15-octaiiecatrlenoic acid,
2,3-bis(acetyloxy) propyl
56599-50-9 2H-pyran, 2-(7-heptadecynyloxy)
tetrahydro-
1002-84-Z Pentadecanolc acid
131-18-0 1,2-benzene dicarboxylic acid,
dlpentylester
55162-61-3 Tetracontane. 3,5,24-trimethyl-
56771-77-8 4-hexanoic acid, 3-methyl-2.6-d1oxo-
56554-88-2 5-octadecenal
14676-29-0 Heptane, 3-ethyl-2-methyl-
629-99-2 Pentacosane
629-74-3 1-hexadecyne
10544-50-0 Sulfur. Mol (58)
544-63-8 Tetradecanotc acid
29812-79-1 Hydroxylamine, o-decyl
Tittabawassee River Sediment Analyses
Tentatively Identified Compounds
(continued)
TK-1
Above
Ash
Pond
SOI
ug/g
(PP"i)
4.0 UK
1.0 UK
1.8 UK
3.4 UK
1.7 UK
5.6 UK
4.0 UK
1.2 UK
6.7? UK
2.0 uk
0.9 Uk
0.76 UK
1.7 UK
3.9 UK
2.7 UK
1.7 01
1.8 UK
0.62 UK
1.5 UK
TR-2
Below
Ash
Pond
so 2
ug/g
(PP"0
1.5 UK
TR-3
Above
Llngle
Drain
S03
ug/g
(ppm)
1.2 UK
0.85 RS
0.65 UK
1.0 UK
TR-4
Smith's
Crossing
SOS
ug/g
(Pfm)
0.54 UK
TK-5
Upstream
of Brown
Mills
SO 7
ug/g
(ppm)
TR-6
At
Freeland
Road
SOS
ug/g
(PP"i)
TR-7
At
Tltta.
Road
S09
ug/g
(PP"i)
0.66 UK
0.92 Uk
TR-8
At
lira t lot
Road
S12
ug/g
(ppm)
0.33 UK
TR-9
At
Center
Road
S13
ug/y
(ppm)
1.6 UK
1.3 01
2.0 RS
0.76 UK
0.66 UK
NOTES: 1)1 - Isomer or similar compound.
UK - Unknown, not in NBS library.
RS - Reasonable detection, retention time compatibility.
-------
Tittabawassee River Sediment Analyses
Tentatively Identified Compounds
(continued)
CAS
Number
Station Number:
Sample Number:
Parameter
84ER04
3913-02-8 1-octanol , 2-butyl
1002-69-3 Decane, 1-chloro-
629-97-0 Docosane
7098-22-8 Tetratetracontane
27554-26-3 1,2-benzenedicarboxylic acid,
di tsooctylester
55334-42-4 Dodecane, 1,2-dibromo-
131-16-8 l,2-benzenedicarboxyl1c acid,
di propylester
1560-92-5 Hexadecane, 2-methyl-
3508-00-7 Heptadecane, 1-bromo-
22599-96-8 Cholestan-3-ol, 2-methylene-,
(3.beta., 5.alpha.)-
1745-81-9 Phenol, 2-(2-propenyl)
2380-18-9 Octadecanoic add, 2-oxo-, methylester_
32391-46-1 2H-2,4A-ethanonaphthalen-
8(5H)-one, l,3,4,6,8A-hexa
6269-92-7 Octane, 1,2-dibromo-
18344-37-1 Heptadecane. 2,6,10,14-tetramethyl-
28080-85-5 10-undecenoic acid, octylester-
593-45-3 Octadecane
TR-1
Above
Ash
Pond
SOI
ug/g
(PP"0
0.69 UK
0.96 UK
TR-2
Below
Ash
Pond
S02
ug/g
(PP"i)
1.1 UK
1.0 UK
2.5 UK
2.1 UK
1.1 01
0.46 UK
1.1 01
1.9 UK
1.1 UK
0'.54 UK
0.65 UK
0.95 UK
0.58 UK
TR-3
Above
Llngle
Drain
S03
ug/g
(ppm)
0.65 UK
0.62 UK
2.2 UK
0.79 UK
2.7 RS
TR-4
Smith's
Crossing
SOS
ug/g
(ppm)
2.1 UK
TR-5
Upstream
of Brown
Mills
S07
ug/g
(ppm)
TR-6
At
Freeland
Road
S08
ug/g
(ppm)
TR-7
At
Titta.
Road
S09
ug/g
(ppm)
TR-8
At
Gratlot
Road
S12
ug/g
(PPm)
TR-9
At
Center
Road
S13
ug/g
(ppm)
1.8 UK
NOTES: 01 - Isomer or similar compound.
UK - Unknown, not in NBS library.
RS - Reasonable detection, retention time compatibility.
-------
Tlttabawassee River Sediment Analyses
Tentatively Identified Compounds
(continued)
CAS
Number
112-44-7
107-51-7
4443-60-1
55401-55-3
3731-38-2
1560-84-5
17364-34-0
629-05-0
79-34-5
4562-27-0
54889-97-3
49607-51-4
112-80-1
56554-99-5
52783-43-4
38653-28-0
56554-64-4
56781-85-2
Station Number:
Sample Number: 84ER04
Parameter
Undecanal
Trislloxane, octamethyl-
Cyclohexane, (1-hexyltetradecyl)-
Oocosane, 11-decyl-
l-azab1cyclo[2.2.2]octan-3-one
Elcosane, 2-methyl-
6,9,12,15-docosatetraenolc acid,
methylester
1-octyne
Ethane. 1,1,2,2-tetrachloro-
4(lH)-pyr1mfd1none
Benzene, 1-(1,1-dlmethylethyl)
-4-(2-ethoxyethoxy)-
lH-l,2,4-tr1azol-3-amtne. 1-methyl-
9-octadecenolc add (z)-
3-octadecenal
Nonadecano)
Cyclopentanol, 2-(2-propynyloxy), trans-
Hexadecane, l.l-bis(dodecyloxy)-
Tricyclo[3.3.1.13,7]decan-2-one,
4-1odo-, 1.alpha.,3.
TR-1
Above
Ash
Pond
SOI
ug/g
(pp)
s-
TR-2
Below
Ash
Pond
S02
ug/g
(ppm)
TH-3
Above
tingle
Drain
S03
ug/g
(PP"0
TR-4
Smith's
Crossing
S05
ug/g
(pprc)
1.1 UK
0.58 UK
0.66 UK
0.88 Uk
1.2 UK
.2 UK
1.1 UK
..5 UK
0.45 UK
TR-5
Upstream
of Brown
Mills
S07
ug/g
(ppm)
TR-6
At
Freeland
Road
S08
ug/g
(ppnt)
TR-7
At
Tltta.
Road
S09
ug/g
(ppm)
0.46 UK
1.2 UK
03 w~
TR-8
At
Gratlot
Road
S12
ug/g
(ppf)
TR-9
At
Center
Road
SU
ug/g
(ppfli)
2.3 UK
0.58 01
0.67 UK
0.75 UK
T73 DT"
\8 UK
.2 UK
77 UK
J.5 UK
UK
NOTES: 01 - Isomer or similar compound.
UK - Unknown, not In NBS library.
RS - Reasonable detection, retention time compatibility.
-------
Tittabawassee River Flood Plain Analyses
Tentatively Identified Compounds
Station Number:
Sample Type:
Time:
Sample Number: 84ER04
Date:
CAS
Number Parameter
26489-01-0 6-octen-l-ol, 3,7-dimethyl-, ( )-
79-34-5 Ethane, 1,1,2,2-tetrachloro-
57-10-3 Hexadecanoic acid
52783-43-4 Nonadecanol
3913-02-8 1-octanol, 2-butyl-
17851-53-5 1,2-benzenedicarboxylic acid,
butyl-2-methylpropylester
10042-59-8 1-heptanol, 2-propyl-
7146-60-3 Octane, 2,3-dimethyl
1001-89-4 Heptane, 2-chloro-
630-06-8 Hexatriacontane
131-18-0 1,2-benzenedicarboxylic acid,
dipentylester
56259-10-0 Akuammilan-17-ol, 10-methoxy-
502-69-2 2-pentadecanone, 6,10,14-trimethyl
18344-37-1 Heptadecane, 2,6,10,14-tetramethyl
FP-1
Flood Plain
Tertiary
Pond
G
1550
S04
7/26/84
ug/g
(ppm)
0.53 UK
FP-2
Flood Plain
at White &
Debolt Drain
G
1940
S06
7/25/84
ug/g
(ppm)
1.1 RS
0.94 UK
0.69 UK
2.0 UK
2.6 UK
1.9 UK, 2.8 UK
2.4 UK
1.1 UK
1.1 RS
7.3 UK
3.0 UK
FP-3
Flood Plain
at
Tittabawassee Rd.
G
0915
S10
7/27/84
ug/g
(ppm)
3.8 UK
0.51 UK
0.99 UK
NOTES: 01 - Isomer or similar compound.
UK - Unknown, not in NBS library.
RS - Reasonable detection, retention time compatibility.
-------
Tittabawassee River Flood Plain Analyses
Tentatively Identified Compounds
(continued)
Station Number:
Sample Number: 84ER04
CAS
Number Parameter
1454-85-9 1-heptadecanol
55401-55-3 Docosane, 11-decyl-
3790-71-4 2,6,10-dodecatrien-l-ol,
3,7,11-trimethyl-, (Z,E)-
593-45-3 Octadecane
29354-98-1 Hexadecanol
7098-22-8 Tetratetracontane
143-28-2 9-octadecen-l-ol, (Z)-
10314-91-7 16,17-seco-24-nor-5.alpha.,
13.alpha., 14.beta., 17.alpha.-
1249-75-8 Cholan-24-oic acid, 3-hydroxy-,
methylester, (3.alpha., 5)
56847-03-1 6,9-octadecadiynoic acid, methylester
FP-1
Flood Plain
Tertiary
Pond
S04
ug/g
(ppm)
FP-2
Flood Plain
at White &
Debolt Drain
S06
ug/g
(ppm)
FP-3
Flood Plain
at
Tittabawassee Rd.
S10
ug/g
(ppm)
1.8 UK
2.7 UK
0.86 UK
3.0 01
3.2 UK
1.5 UK
0.96 UK
2.4 UK
0.55 UK
2.9 UK
NOTES: 01 - Isomer or similar compound.
UK - Unknown, not in NBS library.
RS - Reasonable detection, retention time compatibility.
-------
APPENDIX D
Bioaccumulation Studies
-------
APPENDIX D-l
PCDDs and PCDFs
1981 USEPA-MDNR Study
-------
MIDLAND
,?i~t ftivtr Copflutnct
2.3 Milts Upttreom
• i
•'"": DOW-'
CHEMICAL
. -STATION :A
^i R'ver
V . . ' SANF.C
STATION .B
-------
charger: Dow Chemical Co. Midland, Ml
pie Date: September 1-30, 1981
U.S. ENVIRONMENTAL PROTECTION AGENCY
REGION V
Eastern District Office
SAMPLE TYPE
PARAMETER
7.V7.8 TCDO 3
Hcotncl
Octachl
F. Polvch
2.3.7
Hexach
iloro mon^rs
loro laoiMri
lorinated Dlbenzo
7 TCDF
iloro Uomc- 1
>loro Itomers
Flfh Food
Fish Food
pg/g/
Jljsomers)
•P-oinxIn*
< 6
< 10
< *o
< go
20
70/f4)
< 10
< 20
< 40
< 90
Control
Caged Fish
Day
0
pg/g/
(1 Isomers)
7
7
< 10
< ?o
< 00
< go
10
60/<1)
< 10
< 20
. < 40
5 90
IA
Son ford Dom
Caged Fish
Day'
28
P9/9/
(1 Isoincrt)
< q
< IQ
< 90
< AQ •
< "Q
8
8/m
< 10
< 20
< 40
< 90
1}
Tlttabawassee RIvtr
Near Poseyvllle Road
Caged Fish
Day
28
P9/V
I Isotners]
8
8
<'Q
<'Q
<o
< ?o
< *o
< ^o
no
«;floo/(7)
S90/(6^
< 20
< J.O
< 90
Day
. 28
Dup
P9/9/
(1 Isomers
80 |
1 770/rO |
s'Q'^)
< ?Q
< 40
1 * % 1
5!
85007 U
8700/f61
< 20
< 40
< 90
IB
Grand River
9
Jones Road
Caged Fish
Day
28
pg/g/
(1 Isomers)
< 5
< '
-------
APPENDIX D-2
Other Organic Pollutants
1981 USEPA-MDNR Study
-------
?ir* Rivtr Cocflutnct
2.3 Milts Upjfreom
MIDLAND
• t
:.'•: DOW-
CHEMI.CAL
•STATION :"A
Sonford
Lake
TiUabawossee
^yi R»ver
V . SANF.
STATION .B
Jones
- Rood
6 miles to
-------
larger: Dow Chemical, Midland, Ml
D1o Study
ie Date: September 1-30, 1901
U.S. ENVIRONMENTAL PROTECTION AGENCY
RFG10N V
Eastern District Office
TYPE
TER
GANICS
Qase/Neutral
Phenanthrene
Naphthalene
Bis[2-ethvlhexyl) .
Dhthalate
Di-n-Butv) phthalate
1 .2-01chlorobenzone
1.3-Dic.hlorobt>n7ene
1 ,4-Dichlorobenzene .
1 .2.4-Trichlorohenzene
HcAflchlorobejizene
•
Acid Extractabl«
2.4.G-Tricfi1orf)ptlf*nOl
Pentachloroohenol
Phonnl
I
1
Control •
Fish
°8/
pS/kg
60
84
2700
..
_.
._
_.
..
-.
..
--
Day
Du°p
p9/kg
_.
62
.
_
mm
mm
m-
' Sanford Dam
Caged Fish
°K
pg/kg
._
..
..
_.
__
..
._
..
..
..
-,
140»
•
*
rf/k,
._
..
95
mm .
mm
mm
mm
mm
,.
mm
mm
mm.
Day
28
Dup.
*m.
mm
mm
260
150
..
..
..
..
..
..
-,
THtabawassee River
Near Poseyvllle Roac
Caged Fish
Day
14.
pg/kg
.-
..
.
.
,
.
.
..
..
..
__
100a
Day
28
V9A9
72
..
1200
•
..
..
mm
no
160
630
mm
Day
28
Dup.
V9A9
..
22
..
_.
_.
..
..
--
..
.
,.
..
--
12
TUtabawassee River
Upstream of
fiutfaii rm
Caged Fish
Day
14
V9A9
—
-.
..
• ..
_.
. .
..
..
..
..
.-
--
Day
28
U9A9
--
.-
21
_.
•_.
..
..
..
--
mm
mm
mm
Dup.
V9A9
..
• ^
360
78
...
..
..
• ..
..
mm
mm
mm
13
Tittabawassee River
Outfall 031 Mixing Zone
Caged Fish
Day
2
*/*
34
60
--
70
^60
17Q
160
160Q
w-
870
Day
4
*n*
—
28
..
84
140
220
260
2400
46
»*
1300
Day
8
,9/K9
--
..
-.
._
26
120
1
JLI
20
'00
..
,
^^
900
Day
14
,9/4
"
-.
..
...
48
150
160
T20~5
..
_ —
— ^
Day
14
Dup.
pg/kg
—
—
.-
..
62
130
-m-
.-
— .
— ^
Day
21
pg/kg
--
--
390
..
250
280
T800
84
. _
500
Day
28
.g/X
•-
--
..
..
..
90
110
1900
120
140
1000
>,OJ 1-i, 1
•) r»3 I
0 0
•-g A
--
r --
--
--
..
12L
14C
I90C
HC
_»
900
- • Less than detection ' a
Sample matrix caused reduced resolution between native phenol and the ds phenol surrogate spike.
As a result, the presence of phenol Is not confirmed In this sample.
-------
charger: Oow Chemical, Midland, Ml
Oio StuJy
pic Date:
September 1-30, 1981
U.S. ENVIRONMENTAL PROTECTION AGENCY
REGION V
Eastern District Office
iPLE TYPE
5AMETER
RGAN1CS
Base/Neutnil
1,3-Dfch1ornhpn»p_n,p
• 1 . 4-D1 ch 1 proben ?pne
JL2.4-THrhlnrnhpn7Pni»
01-n-Butvl nhtha^tfi
BISfZ-rthvJhMvMphMiiilat*
Naphthalene
Phenanjhrene
l,2-Dichloroben2pnP
Olethvl ohth^late
. Add Extractables
14
Tittabawassee River
D/S of Outfall 031
Caged Fish
Day
14
wg/kg
E6
no...
fi«iO
150
—
34
Nene
Day
20
wg/kg
7?
70
7
• •.
• — -
w»
_-
-.
MM
Day
28
wg/kg
*«•
*•
•••
V •»
62
3000
24
__
„„
Day
28
Dyp
wg/kg
^ —
<•••
^^
120
— —
*•
'W
Grand Ulvor at Jones Road
Native Fish
/
82LS07
SOI
wg/kg
-
^m
m ~
* —
_.
^^
— —
02LS07
S02
wg/kg
.
— ml
ft *
• *
•»•
— ^
82LS07
S03
wg/kg
— B
52
320
22
02LS07
SOI
wg/kg
— ^
100
1700
82LS07
SOS
wg/kg
— ^
78
660
Grand
River
Native
Fish
82LS07
SOS
vg/^g
— —
<• •
„ _
- • Less than detection
-------
arger: Dow Chemical Co., Midland, MI Bio Sludy
e Date: September 1-30, 1901
U.S. ENVIRONMENTAL PROTECTION AGENCY
IUIGION V
Eastern District Office
v>
E TYPE
•flctsblei Qualitative
nioxolanp-4-Mpthnnol
2.2-d1methv1
iildehvdf?
n. 2-oentvl
f pn-?-Onp
Heptad1en-?-One.6-
,npn-?-Onp
hlorobenzene i sowers
tpnal^^-butvl
ene areMr .iHrf, alpf
methoxv psfprs of
/trhlf)ro bpn.'pnp
£np acetic acid
nten-2-One.5 ohenvl
Bi nhenvl. 2-phenox\
ycjohexen-1-ono.
3,5-dimethyl
-Nonadl ena 1
lohexanone
jten-2-Une,4-PhenyT
rohexanol
Control
Caged Fish
Day
0
pg/kg
340Q
fl
-------
Discharger: 2ow chemical Co., Midland, Ml B1o Study''
Sample Date: September 1-30, 1981
U. S. ENVIRONMENTAL PROTECTION AGCNCY
REGION V
Eastern District Office
SAMPLE TYPE
4METERS
Fxtractah]*? Qualitative Analy
1 *^»ni njcf»1 An/>-4»M/»thiinnl
? 9-Hnfy1
VOrtpn-P-Onf1
1,^-llppl.iH1f»n.7-nno.fi.
mothyl
l-Nnnpn-7-flnp
Trirhlnrnhpn^pnp iPnp
Rpn?»np. »th^nvl
Nltrnjis aHH.^-yelnKpyyl *gAg
nnn
?floo
4QOO
13000
• '
82LS07
S03
vg/kg
^no
3200
82LS07
S04
pg/kg
.
82LS07
SOS
wgAg
MOO
..
5100
..
--
..
..
w .
m m
,.
7200
17000
7000
Grand
River
Natlvt
F1sh
82LS07
S06
pg/kg
..
..
__
__
..
• -
..
..
.•
.»
» ,
„.
,»
.»
(1) Concentration based on a comparison of the total 1on area of the compound with that of the internal standard.
« • Less than detection .
-------
"
X/l.
90S
ZOS120
aMlCN
£3
--
--
—
-•
--
--
.-
651/6"
SOS
--
• -
--
--
--
--
--
M/M
»os
£05128
(JVS
02^
--
--
--
'OOU
--
6^/61
EOS
iOSliO
MIJ<
--
0091
--
—
--
6,/6«
20S
>A|1«?N
•-
—
--
002Z
uuut
OOH
—
--
•vw
IOS
^OS128
peon sauop IP JOAHJ pueag
(If
—
—
—
—
~
—
Ki
*"••
•dnQ
82
--
--
--
--
*™
~
~
6))/6rt
XBQ
•
--
—
--
-•
~
Old
— -
6>|/6rt
A"OQ
qsij paSeo
peoa sauof
)« U3A^ pUBJg
fll
•-
--
--
--
-- •
"•
avx
•dna
82
XOQ
••
•-
-™
• •
--
0016'
""
4/M
82
--
--
-•
•••
•—
6>t/6rt
A"CQ
«.U P-O
U)B3JaSU«OQ ^H 59 '2
J3A^ oasscMpqs;^n
SI
••
••
~*
••
••
00 It
65)/5rt
•dna
82
™"
•"
•*
~™
••"•
6)|/6rt
82
..
*"
™ ™"
'
•••
°3 U )
6)|/6t
H
OU P'6.0
OU02 tiu^xjH
ICO Iteiino jo s/0
[ vi
^rtudi^d y duu ^ ud^iiy (,
maui^Q-§ £ -dito-l-U3xoyo[3X3-2
PL3W 3L^d3\/ OUO^UOQ
ISAIVNV 3Aiivinvno sjiavuvui
S«313HV>iV
3dAl 31JWVS
•
A NOKXTH
JOK3DV NOIIOSIOUd TVOK'BU«IIAK3 'S'Cl
TflCt 'OC-1 .'i
IW 'P"VIL>|W "CO trow up '«a :aoaix?vpsTa
-------
narger: Dow Chemical Co, Midland, MI, Bio Study
le Date: September 1-30, 1981
U.S. ENVIRONMENTAL PROTECTION AGENCY
REGION V
Eastern District Office
IE TYPE
\METER
!CS
B/Pesticide
drln
BHC
BHC
BHC
4-DDE
4 -DDT
eldrln
drln Aldehyde
jjtachlor pnoxld*
dosulfan^ sulfatt
otachlor
dHn
dosulfan II
B-1248
II -
1
Control •*.
Caged
F1sh
Day
0
vg/kg
8.70
— —
•* •
?ia
26°
w v
1?a
15*
m ^
mm
34b
..
.,
..
..
Day
0
Dup.
vg/kg
5 jb
m —
-w
7.8°
17b
_„
130
loD
— —
„_
._
r 1 Q
._
-.
..
) IA
Sonford Dam
Caged
Fish
Day .
14
pg/kg
"7 Ob"
• •»
mm
'™b
— »
17«>
13b
._
— —
_»
..
..
..
--
Day
28
vq/kq
-.
»*
ww
• ••
11°
.„
9-?°
H Sb
_
„
w
.
.
.
.-
Day
28
Dup.
vg/kg
5 9s
— —
. ..
P Qa
103
_»
5.1'
5,Zg
_
M
Tittabawassee River
Near Poseyvllle Road
Caged
Fish
Da/
14
vg/kg
• ••
5 4^
— m
w.
21*
17b
Mw
15*
15b
•
b
Day
28
vg/kg
I f !
is6'
MW
».
ww
__
_.
..
fl.44
_„
_„
._
..
..
_.
--
Day
28
Dup.
vg/kg
• v
9 la
5.3C
44"
323
..
39°
ISC
„.
mm
69
..
._
21D
46b
12
Tittabawassee River
Upstream of
Caged
Fish
Day
14
vg/kg
• .- •
10a
_,
__
mm
9 lb
17b
..
?3°
17a
9.51)
2"5r
..
.,
..
..
Day
28
vg/kg
5 9b
..
„•
_.
._
37*
20a
..
..
iaa
vw
_.
..
21b
..
.-
Day
28
Dup.
vg/kg
._
5.4"
ww
•m
..
42a
lea
..
33U
He
„_
..
..
18
._
-.
13
Tittabawassee River
Outfall 031 Mixing Zone
Catjcd
Fish
Day
2
vg/kg
70b
47°
fi lb
..
..
12a
26b
..
12a
700
7.4b
Day
4
vg/kg
„
57D
8 1°
._
..
12D
15b
..
14*
P.
Day
8
vg/kg
f,r
31U
6 2°
._
._
9.9b
.-
..
7.5»
121>
..
100
Z30T"
..
—
—
Day
14
vg/kg
100b
20D
5.5b
42J
40b
--
7. 1*
46*
..
46*>
23°
llb
--
—
--
Day
14
Dup.
vg/kg
121
99b
--
.-
..
26C
65a
.-
-|4*~
126
{6°
..
7.40
•-
—
—
Day
21
ug/kg
260»
TelF"
--
..
--
6.5b
TfOb
2?*
I?,1!
il°
26*
-.
-.
14°
63b
—
—
Day
28
«,«
250C
220b
24t-
--
16-
75b
S2b
^>7«i
7.8*
^liO- •
•-
65°
22i>
220
—
—
--
Day
28
Dup.
vg/k
ZfiOj.,..
no"
nD
. .
..
37J
.-
?T^
^5B—
T^U
17 1>
• •
10°
?*>c
--
.-
• Conflnncd on second column 8C/ECD
• Not confirmed on Second column GC/ECD
• Not confinned on second column due to interference
Less than detection
-------
Discharger: cow aitiiUc.il, Midland, MI Dio Study
Sample Date: septodxir 1-30, 1901
U.S. ENVIRONMENTAL PROTECTION AGENCY
REGION V
Eastern District Office
SAMPLE TYPE
PARAMETER
ORGAN (CS
0. PCB/Pesticide
Aldrin
. o-BHC
B-BHC
6-BHC
Y-BHC
4-4'-D)D
4,4'-DD£
4.4'-Dl
OieTdr
11
n
Endosu fan I
EndHn aldehyde -
Heotachlor eooxide
Endosulfan sulfate
Heptachlor
Endosulfan II
PCB-1260 ~
Tittabawassce River
D/S of Outfall 031
Mlvlrm 7nrt rt
Caged
Fish
Day
14
MA.
34a
43°
..
..
--
28a
IP
—
118
33°
Day
28
pg/kg
67"
58°
-.
--
-.
360
—
5.78
40D
9. Ob
37°
Day
28
Dup.
pg/kg
88C
570
..
..
7.60
363
16C
..
3D
20"
15
Tittabawassee River
2.C5 M1 Downstream
of Dew Da~i
Caged
Fish
Day
14
pg/kg
530
540
6. 60
-.
340
-21°
.-
13a
,7-7b..,
208
5.68
Day
28
pg/kg
..
5.68
..
._
.-
..
lia
--
..
—
Day
28
Dup.
pg/kg
56C
__
._
5.3°
36a
..
-.
158 .
27C
IflC
--
IB
Grand River
Jones Road
Caged
Fish
Day
14
pg/kg
..
9.7&
.•
„ »
6 1*
iga
__
23"
9. Ob
.-•
Day
28
pg/kg
».
5.2
m —
.—
16a
340.
—
Day
28
Dup.
vg/kg
• *
«••*
»*•
*•.
.* '
16a
140
*•»
aJ
—
IU
Grand River at Jones Road
Native Fish
8?LS07
SOI
pg/kg
— —
13 b
— —
7.5C
1308
1408
noc
-flf-
1 M.C
OOQ
-JBQ"
5109..
82LS07
S02
pg/kg
— w
— —
9.0C
18b
1903
150C
8.9b
94b
27C
lab
i*
5503
101Qa. .
82LS07
S03
vg/kg
-p *
— —
428
37a
48C
23a
16oa
82LS07
S04
v9/kg
•
_.
13b
IK
2408
240a
IftOc
llOb
24b
PIC
6403
82LS07
SOS
pg/kg
12b
7 6b
6 lb
300^
230C
173
150b
10208
136Q8
Grand
River
Native
Fish
82LS07
S06
pg/kg
_ ^
71b
1603
79c
7 2f
62c
14
_««_
b » Not confirmed on second column GC/ECD
c • Not confirmed on second column GC/ECD due to Interference
Less than detection
-------
III. DIOXIN METHODOLOGY AND QUALITY CONTROL
A. Method for Fish Analyses
3arcelle Columbus Laboratories, under subcontract 1-453-003-222-01
to CCAj performed the dioxin analyses. The objective of this study was to
anal^cj selected polychlorinated dibenzofurans (PCDF) and polychlorinated
dibenzo-p-dioxins (PCDD) in fish. The detection limits specified for
these compounds were parts-per-trillion (1 part in 1012, or ppt) in fish.
Specific coapounds which were selected for identification included: -
2,3,7,8-tetrachlorodibenzofuran (2,3,7,8-TCDF); -2,3,7,8-tetrachlorodibenzo-
p-dioxia (2,3,7,8-TCDD), and all tetra through octa chloro furan and dioxin
isomer classes. High resolution gas chromatography/high resolution mass
spectronetry (HRGC/HRMS) was used to Identify and quantify these materials
at the indicated trace level. The exact masses used for each Isomer class
and the expected isotope ratio used in part for Identifying individual
compounds, as well as limits of detection for the fish are presented
in Table 1. 2,3,7,8-tetrachlorodibenzo-p-dioxin- C12 was used as an
internal standard for quantification and recovery determinations.
These recovery determinations are found in Table 2 and were used to
estimate the influence of the matrices on the analytical measurements.
Preparation of Fish Samples
The fish samples were extracted and cleaned up using the
following procedure. Approxinately 5 g portions of fish were placed
in 125 ml round bottom flasks. The fish samples were spiked with 2 ng
of 2,3,7,8-TCDD-*3C,2 internal standard followed by the addition of
20 ml of ethanol and 20 ml of 40 percent KOH. The samples were digested
for one hour at 80*C. After cooling, they were extracted three times
each with 10 ml volumes of hexane. The combined hexane extracts weree
transferred to 125 ml separatory funnels and washed three times each
with 10 ml of distilled water. The hexane extracts were concentrated
to 5 ml using K-D apparatus. Each concentrate was transferred to a
multilayered silica column containing the following materials oriented
top to bottom:
Activated silica
Silica containing 44 percent concentrated sulfuric acid
Activated silica
Silica containing 33 percent 1M sodium hydroxide
Activated silica
These columns were eluted with 30 ml of 1:1 (V:V) benzenerhexane.
The benzene:hexane fraction was exchanged into 5 ml of hexane and transferred
to alunina columns. The alumina column was eluted sequentially with 25 ml
of hexane, 25 nl of 1:1 (V:V) hexane:carbon tetrachloride, and 20 ml of
1:1 (V:V) hexane:raethylene chloride. Decane (20 ul) was added to the
hexaneriaethylene chloride fraction, and these mixtures were concentrated
to 20 ul prior to their analyses.
-------
The extracts were analyzed by high resolution gas chroma tography/
high resolution mass spectrometry (HRGC/HRMS) at a mass resolution of
8000-12000
-------
Blanks
Along with the actual fish samples two grinding blanks and two
dioxir.-"ree fish filet samples were analyzed. Battelle also extracted .and
anal /.-.m a solvent blank. The only reported levels of furans in any blank
were i« ?g in the grinding blank (dry ice) prepared before fish sample
grinding and 95 ppt in the blank perch filet EPA-V-17. The source of
the 10 pg tecrachlorinated dibenzofuran in the grinding blank is not known.
The concentration of 10 pg per saaple jar rinse .cannot be converted to
ppt, so data is uncorrected.
1) 82LS10R02
Originally, only five grams of the filet was taken for analysis.
95 ppt 2,3,7,8-TCDF was reported for this first run. A suppression at the
prefluorokerosene lock mass appeared, creating an artifically low
2,3,7,8~TCDD-C*3 signal. This suppression caused all quantitation to be
biased high. The remaining 5 grams of filet were extracted and put through
an additional florisil clean-up and the suppression disappeared.
No 2,3,7,8-TCDF was reported for this aliquot.
Spikes
Four spiked fish filets were obtained from Dr. Harless at RTF
and sent as "blinds" to Battelle for analysis. However, since the appearance
of the samples EPA-V-21-2, EPA-V-20, EPA-V-21, and EPA-V-22 differed from
the actual sample catfish pastes, they were not actually "blinds".
Battelle, however, did not know which filets, if any, were blanks and
they did not know the isomers or levels used in spiking.
A nearly consistent lack of recovery of OCDF and OCDD at
levels of 100-200 ppt occurred. This nay be due to the fact that the
spike levels used were near or at the detection limit. In conversations
with Battelle, it was discovered that OCDD and OCDF have varying response
factors relative to C^-TCDD. These results are therefore estimated
against 2,3,7,8-TCDD-C13 as no pure certified OCDD and OCDF standards
were available. Such quantitation may be biased low for the sample
results. No OCDD or OCDF was reported above the contract detection
limit of 90 ppt in any of the samples.
820IS22 (EPA-V-22)
This spiked filet QC sample yielded high (277Z) recovery of
2,3,7,8-TCDF and low 2,3,7,8-TCDD recovery (54%). The spectral data
was recalled off of the disc and the results recalculated. A suppression
of the 2,3,7,8-Cl3 signal occurred. The usual Battelle procedure is
to go back and rerun the extract through an additional florisil column.
This was done and the unsuppressed signals yielded 168Z recovery for
2,3,7,8-TCDF and 922 recovery 2,3,7,8-TCDD. The recovery for
2,3,7,8-TCDF was still high due to reappearing mass interference at
mass 304 of TCDF.
-------
CONCLUSION
Due to the imprecise and low biased OCDD and OCDF recovery discovered in
blind spike audits, any positive OCDD and OCDF data for fish samples should
not be considered valid. All other dioxin/furan sample data should be
r-sd of an acceptable level of quality.
-------
TABLE 1. SELECTED DATA FOR THE POLYCHLORINATED DIBEN7.0FURANS AND
POLYCHLORINATE1) DIDENZO-P-DIOXINS OF INTEREST
Limit of
Accurate mass Theoretical Isotope Detection
Compounds
Te trachlorod ib enzo fur an
Te tr achlo rod ib enzo-p-d ioxin
Pcntachlorod ibenzofuran
Pentachlorodibcnzo-p-dioxln
Hexachlorodibenzofuran
Hexachlorod ib enzo-p-d ioxin
Hep tachlorod ibenzofuran
Hep tachlorodibenzo-p-d ioxin
Octachlorodibenzofuran
Oc tachlorodibenzo-p-d ioxin
Low Mass
303.9016
319.8965
339.8597*
355.8546*
373.8207*
389.8156*
407.7817*
423.7766*
441.7428
457.7377
High Mass
305.8987*
321.8936
341.8567
357.8517
375.8178
391.8127
409.7788
425.7737
443.7398*
459.7347
Ratio
.77
.77
1.54
1.54
1.23
1.23
1.03
1.03
0.88
0.88
Water
10 ppq
10 ppq
20 ppq
20 ppq
40 ppq
40 ppq
80 ppq
80 ppq
•100 ppq
100 ppq
Fish
.5 ppt
5 ppt
20 ppt
20 ppt
40 ppt
40 ppt
80 ppt
80 ppt
100 ppt
100 ppt
* Quantitation Mass
-------
TABLE 2. INTERNAL STANDARD RECOVERIES OF
2,3,7,8-TETRACHLORODIBENZO-P-DIOXIN-l3C12
IN FISH
Fish Recoveries
Sample Naae Internal Standard
Recovery (X)
82LS10R04 52
82LS10R02 50
82LS10R01 56
82LS05S01 93
82LS05S02 89
81LS15S08 56
81LS11S01 59
81LS17S01 86
81LS17S03 57
81LS17S06 72
81LS17S07 47
82LS07S05 49
82LS07506 . 51
-------
TABLE 3. DOW FISH BLANK RESULTS
UNITS: ppt
1 IBattellelDry Ice**I Dry Ice**| 82L510R02 I820I07R15
1Solvent iBefore (After | EPA-V-17
I SOV.E?. I3lank 18 2L205S02182L505S02|Run 1 |Run~2T
2,3,7,8-TCD?
2,3,7,8-TCDD
Tetra CD?
Tetra CDD
Penta CD?
Penta CDD
Hexa CDF
Hexa CDD
Hepta CDF
Hepta CDD
Octa CDF
Octa CDD
<(7)
<(4)
<(4)
<(4)
<(D
<(1)
<(2)
<(5)
<(D
<(2)
<(4)
<(3)
< 5
< 5
10
< (2)
<(20)
< (7)
<(12)
<(17)
< (6)
<(25)
<(11)
< 5
< 5
< (4)
< (2)
<(19)
<(37)
<(19)
< (9)
<(12)
< (4)
-------
TABLE 4. DOW FISH SPIKE RESULTS
UNITS: Z recovery
JE?A-V-21-2|EPA-V-20 IEPA-V-21 IEPA-V-22 |Spike (ppt)
{82LS10R04 j82LS10R0111820I07S20\820I07S22JLevels
ISCMZR
2,3,7,8-TCDDi
2,3,7,3-TCDFl
1,3,6,8-TCDDJ
1,3,7,9-TCDDJ
OCDO I
OCDF 1
173
70
105* -
105*
0
0
80
125
92*
92*
75
64
103
154
60
115
0
0
54
-277
88
130
0
0
10- 30
20- 40
10- 33
•3- 10
100-200
100-200
*Isomers not quantified spearately.
-------
APPENDIX D-3
Dow Chemical Biouptake Study
October, 1985
-------
STATE OF MICHIGAN
NATURAL RESOURCES COMMISSION
THOMAS j ANDERSON JAMES J. BUVNCHARD. Governor
E R CAROLLO
ST^NJ! %££? DEPARTMENT OF NATURAL RESOURCES
O STEWART MYERS STEVENS T MASON BUILDING
RAYMOND PCXJPORE BOX 30028
HARRY H WHITELEY LANSING. Ml 48909
RONALD O SKOOG. Oreclor
March 21, 1986
Mr. Gary Amendela
U.S. EPA - Region V
Eastern District Office
25089 Center Ridge Road
Westlake, Ohio 44145
Dear Gary,
Please find enclosed, copies of the Dow Chemical Company October, 1985
Fish Biouptake Study and the Michigan Department of Public Health "Back-
ground Document Concerning 1986 Fish Consumption Advisory for Dioxin
Contaminated Fish."
If you have any questions, please contact me.
Sincerely,
£6~-
Linn Duling
Aquatic Biologist
Toxic Chemical Evaluation Section
Surface Water Quality Division
517-373-2190
Enclosure
-------
.0°
DOW CHEMICAL U.S.A.
December 31, 1985 M1CMIGAN OIVISION
MIOCANO. MICHIGAN 486*0
Mr. Paul Zugger, Chief
Surface Water Quality Division
MI Dept. of Natural Resources
P.O. Box 30028
Lansing, MI 48909
Dear Mr. Zugger:
SUBJECT: FISH BIO-UPTAKE STUDY, SPECIAL CONDITION 9, NPOES PERMIT
10000868
In accordance with Special Condition 9 of the NPOES permit issued to
Dow Chemical's Midland location on May 17, 1984, a fish bio-uptake
study has been performed following the study conditions described in:
Dow Chemical letter to MDNR, December 18, 1984
MDNR letter to Dow Chemical, April 15, 1985
Dow Chemical letter to MDNRTJune 26, 1985
MDNR letter to Dow Chemical, August 20, 1985
A laboratory study only was performed.
Water chemistry measurements taken in the exposure chambers during the
course of the study are shown in Table 1. The results of the analyses
of whole and gutted fish samples are shown in Tables 2 to 4. Table 2
contains the results for the fish at the beginning of the study.
Table 3 shows the results for fish exposed for 28 days to 100%
Tittabawassee River water. The results for fish exposed to 15%
effluent and 85% Tittabawassee River water for 28 days are shown in
Table 4. If there are any questions or concerns regarding this study,
please don't hesitate to telephone.
Sincerely,
W. I. Delaney #
Technical Manager
Environmental Services
628 Building
(517)636-3595
clr
Attachments
-------
TABLE 1
FISH BIO-UPTAKE STUDY
WATER CHEMISTRY MEASUREMENTS
100% River Water
15% Effluent/85% River Water
10/2/85
10/4/85
10/7/85
10/9/85
10/11/85
10/14/85
10/16/85
10/18/85
10/21/85
10/23/85
10/25/85
10/28/85
Temp.
•c
15.0
17.0
17.5
16.5
16.7
16.5
15.0
15.5
17.0
17.5
17.0
14.0
D.O.
mg/l
9.4
8.0
8.3
8.4
8.6
8.4
9.0
8.9
7.8
8.1
7.8
9.4
•
PH
7.1
7.7
8.1
8.2
8.0
8.2
7.9
8.0
8.1
7.9
8.1
8.1
Conductivity
^mhos/cm
598
500
591
581
548
441
497
497
510
526
570
606
Temp.
•c
18.5
20.5
21.0
20.0
17.8
19.0
17.5
18.0
19.0
19.5
20.0
16.0
0.0.
mg/L
9.4
8.2
9.2
8.4
8.9
8.6
9.1
8.9
8.5
8.2
8.5
9.4
pH
7.1
7.8
8.1
8.1
8.0
8.1
7.9
8.1
8.0
7.9
8.2
8.1
Conductivity
^mhos/cm
1.534
1,420
1,293
1,563
1,482
1,278
1,301
1,084
907
1,134
1,152
1,149
-------
TABLE 2
FISH BIO-UPTAKE STUDY
DAY ZERO FISH
(All results in ppm unless otherwise specified)
Whole Fish Gutted Fish
Acrylonitrlle NQ(0.004) NQ(0.004)
Aldrin NQ(1.8) NQ(1.8)
alpha-BHC NQ(3.6) NQ(3.6)
Aniline NQ(2.6) NQ(2.6)
1,2-01 chlorobenzene NQ(0.004) NQ(0.004)
i,3-D1chlorobenzene NQ(0.004) NQ(0.004)
1.4-01chlorobenzene NQ(0.004) NQ(0.004)
2,4-01chlorophenol NQ(0.8) NQ(0.8)
Heptachlor Epoxlde NQ(0.6) NQ(0.6)
Hexachlorobenzene NQ(0.04) NQ(0.04)
PCB Isomers
Oichloro- NQ(2.3) NQ(2.3)
Trlchloro- NQ(2.3) NQ(2.3)
Tetrachloro- NQ(2.3) NQ(2.3)
Pentachloro- NQ(2.3) NQ(2.3)
Hexachloro- ~ NQ(2.3) NQ(2.3)
Pentachlorobenzene NQ(O.Oll) NQ(O.Oll)
Pentachlorophenol NQ(1.9) NQ(1.9)
1,2,3,4-Tetrachlorobenzene NQ(0.007) NQ(0.007)
1,2,4,5-Tetrachlorobenzene NQ(0.006) NQ(0.006)
2,3,7,8-TCOO 0.7 ppt 0.7 ppt
2,3,7,8-TCDF* 2.4 ppt 2.1 ppt
1,2,3-Trlchlorobenzene NQ(2.1) NQ(2.1)
1.2,4-Trlchlorobenzene NQ(O.OOOl) NQ(O.OOOl)
2,4,5-Trlchlorophenol NQ(O.Oll) NQ(O.Oll)
2,4,6-Trichlorophenol NQ(O.Oll) NQ(O.Oll)
*Qual1fied: Isomer specificity cannot be proven.
-------
TABLE 3
FISH BIO-UPTAKE STUDY
DAY 28 FISH
EXPOSED TO 1001 RIVER WATER
(All results 1n ppm unless otherwise specified)
Whole Fish Gutted Fish
Acrylonitrile NQ(0.004) NQ(0.004)
AldMn NQ(1.8) NQ(1.8)
alpha-BHC NQ(3.6) NQ(3.6)
Aniline NQ(2.6) NQ(2.6)
1,2-01chlorobenzene NQ(0.004) NQ(0,004)
1,3-DIchlorobenzene NQ(0.004) NQ(0.004)
1,4-01chlorobenzene NQ(0.004) NQ(0.004)
2,4-Oichlorophenol NQ(0.8) NQ(0.8)
Heptachlor Epoxlde NQ(0.6) NQ(0.6)
Hexachlorobenzene 0.022 0.017
PCS Isomers
Dlchloro- NQ(2.3) HQ(2,3)
Trlchloro- NQ(2.3) NQ(2.3)
Tetrachloro- ~ NQ(2.3) NQ(2.3)
Pentachloro- NQ(2.3) NQ(2.3)
Hexachloro- NQ(2.3) NQ(2.3)
Pentachlorobenzene NQ(O.Oll) 0.2
Pentachlorophenol NQ(1.9) NQ(1.9)
1,2,3,4-Tetrachlorobenzene 1.1 2.3
1,2,4,5-Tetrachlorobenzene 1.5 0.5
2,3,7,8-TCDO 0.9 ppt 0.9 ppt
2,3,7,8-TCDF* 2.4 ppt 2.4 ppt
1,2,3-Trichlorobenzene NQ(2.1) NQ(2.1)
1,2,4-Trlchlorobenzene NQ(O.OOOl) NQ(O.OOOl)
2,4,5-Trlchlorophenol NQ(O.Oll) NQ(O.Oll)
2,4,6-Trichlorophenol NQ(O.Oll) NQ(O.Oll)
*Qualified: Isomer specificity cannot be proven.
-------
TABLE 4
FISH BIO-UPTAKE STUDY
DAY 28 FISH
EXPOSED TO 15% EFFLUENT/85% RIVER WATER
(All results In ppm unless otherwise specified)
Whole F1sh , Gutted F1sh
Acrylonltrlle NQ{0.004) NQ(0.004)
Aldrin NQ(1.8) NQ(1.8)
alpha-BHC NQ(3.6) NQ(3.6)
Aniline NQ(2.6) NQ(2.6)
1,2-Dichlorobenzene NQ(0.004) NQ(0.004)
1,3-Dichlorobenzene NQ(0.004) NQ(0.004)
1,4-Dichlorobenzene NQ(0.004) NQ(0.004)
2,4-D1chlorophenol NQ(0.8) NQ(0.8)
Heptachlor Epoxlde NQ(0.6) NQ(0.6)
Hexachlorobenzene 3.7 0.2
PCB Isomers
Dichloro- NQ(2.3) NQ(2.3)
Trichloro- NQ(2.3) NQ(2.3)
Tetrachloro- - NQ(2.3) NQ(2.3)
Pentachloro- NQ(2.3) NQ(2.3)
Hexachloro- NQ(2.3) NQ(2.3)
Pentachlorobenzene 0.5 f NQ(O.Oll)
Pentachlorophenol NQ(1.9) NQ(1.9)
1,2,3,4-Tetrachlorobenzene - . • 1.0 NQ(0.007)
1,2,4,5-Tetrachlorobenzene 4.9 NQ(0.006)
2,3,7,8-TCOO 1.2 ppt 1.2 ppt
2,3,7,8-TCOF* . 2.5 ppt . 2.3 ppt
1,2,3-Trichlorobenzene NQ(2.1) NQ(2.1)
1,2,4-Trichlorobenzene 0.29 0.5
2,4,5-Trichlorophenol NQ(O.Oll) NQ(O.Oll)
2,4,6-Trichlorophenol NQ(O.Oll) NQ(O.Oll)
*Qualified: Isomer specificity cannot be proven.
-------
APPENDIX E
Supplemental Environmental Studies
-------
APPENDIX E
SUPPLEMENTAL ENVIRONMENTAL STUDIES
In addition to the environmental studies presented in this report, several
other related studies of the Tittabawassee River, Saginaw River and Saginaw Bay
have been conducted by or for USEPA Region V, USEPA's Great Lakes National
Program Office (GLNPO), the U.S. Food and Drug Administration (USFDA), the U.S.
Fish and Wildlife Service (USFWS), the U.S. Army Corps of Engineers (USACOE) and
the New York Departments of Health (NYDH) and Environmental Conservation.
Those supplemental environmental studies are briefly summarized below. This is
not an exhaustive review of the available literature, however. Details of
study design, sample preparation and analytical methods, concentrations detected
at other sites in control fish, and the results for all species sampled have
been omitted for the sake of brevity.
A. Contaminants in Fish and Birds
1. PCDDs and PCDFs
Concentrations of 2378-TCDD in skinless filets of Tittabawassee River fish
collected below Dow Dam in July 1978 under the direction of USEPA and analyzed
by Harless and co-workers at USEPA's Health Effects Research Laboratory in
Research Triangle Park, North Carolina, ranged from 10 ppt in a yellow perch to
695 ppt in a channel catfish. The contamination was found to extend to the
mouth of the Saginaw River, with levels in the range 30 to 105 ppt in channel
catfish. A Saginaw Bay sucker was found to contain 4 ppt. Other PCDDs
tentatively identified in Tittabawassee River fish were trichlorodibenzo-p-
dioxins and pentachlorodibenzo-p-dioxins.l
Carp, channel catfish, sucker and yellow perch collected in 1979 from Saginaw
Bay were analyzed by O'Keefe and co-workers at NYDH and showed levels of
2378-TCDD of 26, 20, 2.5 and nondetectable (NO), respectively.2
The USFDA also reported finding TCDDs in fish from Saginaw Bay.3 Analyses
performed by USFDA on edible filets of 27 fish collected from Saginaw Bay in
1979 gave four positive results for TCDDs (21 to 45 ppt). Subsequent analyses
by USFDA of a Saqinaw Bay filet composite of carp collected in 1981 showed
68 ppt 2378-TCDD.J
In 1980 Hallett and Norstrum of the Canadian Wildlife Service reported
2378-TCDD in herring gull eggs collected in 1980 at 12 different locations in
tne Great Lakes.4 The highest levels of 2378-TCDO were found in Saginaw
Bay eggs (43-86 ppt). Background levels appeared to be in the range 2-3 ppt.
Greater than 90% of all the PCDDs detected in all the eggs analyzed was
2378-TCDD.
-------
- 2 -
Analyses of single composites of whole carp from the Tittabawassee River and
Saginaw Bay (collected in 1978) and individual herring gull eggs (collected in
1980) for PCDOs and PCDFs were conducted by Stalling and co-workers at the
National Fisheries Research laboratory of the USFWS in Columbia, Missouri.5
TCODs and TCDFs, respectively, in Tittabawassee River and Saginaw Bay carp,
respectively, were 81 and 37, and 94 and 27 ppt. Tetra- through octa- CDFs and
tetra-, hexa- and octa-CODs were detected in Saginaw Bay herring gull eggs
supplied to Or. Stalling by Or. Hallett, confirming the latter's -earlier
findings. The highest concentrations of 2378-TCDD and 2378-TCOF in Saginaw Bay
herring gull eggs were 165 and 4 ppt, respectively. Greater than 90% of the
dioxins and furans detected were substituted in the 2378-positions.
The results of most of the above studies, and related Dow Chemical studies,
are summarized in the USEPA staff document entitled, "A Report On Polychlon'nated
Dibenzo-p-Dioxins (PCDDs) and Polychlon'nated Dibenzofurans (PCDFs): A Summary
of Studies Conducted in the Great Lakes Area (July 1981)".
In 1982 Rohrer published the results of analyses performed by Harless and
co-workers at RTP on samples of carp collected in the area in 1980.6 Concen-
trations of 2378-TCDD in carp from the Tittabawassee River, Saginaw River and
Saginaw Bay ranged up to 142 ppt, 63 ppt and 61 ppt, respectively.
In 1983, USFDA collected fish from fifteen Michigan rivers and inland lakes
and analyzed composite edible portions of carp for 2378-TCDD at a working limit
of detection of 10 ppt. Only two of the sites showed detectable 2378-TCDD:
Muskegon Lake and the Tittabawassee River downstream of Dow Dam. The former
carp composite was measured at 11 ppt, while the latter was at 65 ppt.3 A 1983
report by a Michigan State University graduate student indicated widespread
contamination of rivers throughout Michigan with 2378-TCDD.7 The above study
found substantially lower levels in many of the streams.
In 1985 Stalling et al.8 reported that 2378-TCDD in herring gull egg
composites from a Saginaw Bay colony contained 141 ppt 2378-TCDD. In addition
samples of tern chicks and eggs collected from Saginaw Bay colonies contained
2378-TCDD in the range 21-35 ppt and 40-63 ppt, respectively.9
2. Other Contaminants
In 1976 Kuehl and co-workers at USEPA1s ERL-Duluth reported detection of
hexa-, hepta- and octachlorostyrene(s) in a composite of fish collected in
1974 from Saginaw Bay.10 Subsequently, in 1981, Kuehl and co-workers analyzed
Saginaw Bay whole fish composites of catfish and carp collected in 1980 and
quantified hexachlorobenzene at 5.0 ppb and octachlorostyrene at 110.7 ppb.11
Other chloroaromatic substances tentatively identified by Harless et al.l
in Tittabawassee River fish collected in 1978 included tetra-, penta- and
hexachlorinated diphenyl ethers, a trichlorobenzylphenyl ether, tetrachlorodi-
benzofurans, trichloroterphenyl and PCBs.
-------
- 3 -
Results of analyses of carp collected in 1983 from the Tittabawassee River,
Saginaw River and Saginaw Bay, as well as other sites in the Upper Great Lakes,
were published by Jaffe et al. in 1985.12 in addition to the banned pesticides
and PCBs, the authors found polychlorinated benzenes, tetra- and pentachloro-
anisole (PCA), octachlorostyrene (OCS) and polychlorinated diphenyl ethers
(PCDEs). OCS and PCA were highest from the Tittabawassee River Station #1 at
177 ppb and 4 ppb, respectively, while PCDEs were highest in the Saginaw River
and Bay at 38 and 18.6 ppb, respectively. The 1,2,4,5-tetra-, penta- and
hexachlorobenzene(s) were highest at the Tittabawassee River Station #1, at
236, 30.7 and 66 ppb, respectively. The 1,2,4,5-tetrachlorobenzene is the
immediate precursor of 2,4,5-TCP, from which 2,4,5-T is manufactured.
B. Contaminants in Sediments
1. PCDDs and PCDFs
Dow Chemical failed to detect TCDDs in its 1978 studies of Tittabawassee
River sediments. Accumulations of chlorophenols were noted, however.13
In 1984, Czuczwa and Hites published results of PCDD and PCDF analyses of
core samples of Saginaw River, Saginaw Bay and Lake Huron sediments. The
Saginaw River sediment samples were obtained from depositional zones outside of
the navigation channel. PCDDs and PCDFs were detected in all cores down to a
depth equivalent to a time period corresponding to about 1940.i4 Although
individual isomers were not quantified, totals for tetra- through octa-
homologues were reported. Results for the Saginaw River for TCDOs and TCDFs were
3200 ppt and 710 ppt, respectively. Corresponding concentrations in Lake Huron
were 78 ppt and ND, respectively.15
Gross et al. performed PCDO and PCDF analyses on Saginaw River and Bay
sediments in the Saginaw River navigation channel for the USACOE Detroit District
Office.16 Concentrations of TCDFs and TCDDs at a site near Gull Island at the
mouth of the Saginaw River were approximately 3000 and 1000 ppt, respectively.
Concentrations in the navigation channel taken just downstream of Essexville
(ERG-SR33), for example, were reported as 290 and 30 ppt, respectively. (Results
reported on a wet weight basis.) Follow-up studies by Gross et al. quantified
2378-TCDD in one sample of sediment collected from a sediment depositional zone
in the vicinity of Crow Island at 60 ppt.I7 An analysis of a split sample of the
same sediment by Smith and co-workers at the USFWS laboratory in Columbia,
Missouri, found 15 parts per trillion.1?
2. Other Substances
In a 1974 report by Sylvester, Tittabawassee River sediments contained
detectable levels of ODD and elevated levels of arsenic, copper, total chromium,
zinc, nickel and lead.l8 The Tittabawassee River sediments would have been
classified as heavily polluted with lead and zinc and moderately polluted with
nickel and arsenic based on USEPA guidelines for the classification of dredged
material published in 1977i9 and the data reported.
-------
- 4 -
Data reported by Rossmann et al. to GLNPO in 1982 indicate that some layers
of sediment collected via core sampling in 1981 just below Freeland Road and
the Tittabawassee Township POTW are heavily polluted with arsenic, barium,
chromium and total phosphorus; and arsenic, barium, chromium, manganese and
total phosphorus, respectively, based on 1977 EPA pollution classification
guidelines for Great Lakes sediments. In addition, the authors reported the
detection of di-, tri-, tetra- and pentachlorophenol(s); di-, tri-, tetra-,
penta- and hexachlorobenzene(s); PCBs; and 2,4,5-T and Silvex in higher
concentrations downstream than upstream of Dow Dam. Of the surface cores
collected (5-10 cm depth), the highest concentrations of 2,4,5-T and Silvex
were found in sediments just below Dow Chemical's Lingle Drain at 83.7 and 28.9
ug/kg, respectively.20
Analyses of Saginaw River and Saginaw Bay sediments were conducted for the
USACOE Detroit District Office to support the development of an Environmental
Impact Statement for planned dredging and disposal of portions of the Saginaw
River navigation channel.21 Bottom sediments of the Saginaw River were tested
during 1978, 1980 and 1983 for various contaminants at a number of sites in the
project area. Sediment samples varied in PCB concentrations from NO up to
27 ppm. Based on the 1977 EPA pollutional guidelines, of the 28 Saginaw River
and 11 Saginaw Bay sites sampled, all would be moderately polluted, while 12
and 3 sites, respectively, would be heavily polluted for one or more of the
inorganic parameters considered. Two Saginaw River sites would be heavily
polluted for PCBs.
-------
- 5 -
REFERENCES
1. Harless, R. et al., "Determination of 2378-Tetrachlorodibenzo-P-Dioxin in
Fresh Water Fish", Chemosphere, 11 (2): 193-198, 1982.
2. O'Keefe, P. et al., "Analysis of 2378-Tetrachlorodibenzo-P-Dioxin in Great
Lakes Fish", Chemosphere, 12 (3): 325-332, 1982.
3. DeVault, 0., Polychlorinated Dioxins and Polychlorinated Furans in Fish
from the Great Lakes and Midwest, GreatLakes NationalProgramOffice,
USEPA, Chicago, Illinois, October 1984.
4. Hallett, D. and Norstrom, R., 2,3,7,8-TCDD in Great Lakes Herring Gulls.
Canadian Fish and Wildlife Service,Reportto theInternationalJoint
Commission, December 1980.
5. Stalling, D. et al., "Residues of Polychlorinated Dibenzo-P-Dioxins and
Dibenzofurans in Laurentian Great Lakes Fish," in Human and Environmental
Risks of Chlorinated Dioxins and Related Compounds, R^Tucker arid"
A. Young, Plenum, New York: 221-240, 1983.
6. Rohrer, T., 2,3,7,8-Tetrachlorodibenzo-p-dioxin Residues i"Fish from the
Tittabawassee and Saginaw Rivers and Saginaw Bay - 1980,StaffReport,
Office of Toxic Materials Control, Michigan Dept.ofNatural Resources,
Lansing, Michigan, September 1982
7. Kaczmar, S., Ph.D. Thesis, Michigan State University, 1983.
8. Stalling, D. et al., "Patterns of PCDD, PCDF, and PCB Contamination in
Great Lakes Fish and Birds and their Characterization By Principal
Components Analysis", Chemosphere, 14 (6/7): 627-643, 1985
9. Personal Communication with Howard Zar, Water Division, USEPA Region V,
Chicago, Illinois, May 1986.
10. Kuehl, D. et al., "Isolation and Identification of Polychlorinated Styrenes
in Great Lakes Fish", Bulletin of Environmental Contamination and
Toxicology. 16 (2): 127-132, 1976.
11. Kuehl, D., et al., "Quantification of Octachlorostyrene and Related
Compounds in Great Lakes Fish by Gas Chromatography—Mass Spectrometry",
J. Great Lakes Res.. 7 (3): 330-335, 1981.
12. Jaffe, R., et al., "Anthropogenic, Polyhalogenated, Organic Compounds
in Sedentary Fish from Lake Huron and Lake Superior Tributaries and
Embankments", J. Great Lakes Res., 11 (2): 256-162, 1985.
-------
- 6 -
13. Gledhill, T., General Manager, Michigan Division, Dow Chemical Company,
letter to John Hesse, Chief, Office of Toxic Materials Control, Michigan
Department of Natural Resources, June 1978.
14. Czuczwa, J. and Hites, R., "Environmental Fate of Combustion-Generated
Polychlon'nated Dioxins and Furans", Environmental Science Tech., 18(6):
444-450, 1984.
15. Czuczwa, J. and Hites, R., "Comments on Analysis of Polychlorodibenzo-P-
Dioxin (PCDD) and Polychlorodibenzofuran (PCDF) in Sediment Samples by
Michael L. Gross", in letter to Frank Snitz, USACOE, Detroit District
Office, March 1984.
16. Gross, M., Analysis of Polychlodibenzo-P-Dioxin (PCDD) and Polychlorodi-
benzofaran (PCDF) in Sediment Samples. Report to U.S.ArmyColdRegions
Research and Engineering Laboratory, TCDERGMI04, November 1984.
17. Personal Communication Between Larry Smith, Columbia National Fisheries
Research Laboratory, USFWS, Columbia, Missouri, and Larry Fink, Great
Lakes National Program Office, USEPA, Chicago, Illinois, December 1984.
18. Sylvester, S., "A Biological Survey on the Tittabawassee River, Staff
Report, Michigan Department of Natural Resources, Water Quality Division,
Biology Section, 1974.
19. USEPA Region V, USEPA Region V Guidelines for the Pollutional Classifica-
tion of Great Lakes Harbor Sediments, Chicago, Illinois, April, 1977.
20. Rossmann, R., et al., "The Impact of Pollutants on the Tittabawassee River,
Report to Great Lakes National Program Office, USEPA, Chicago, Illinois,
Grant Nos. R005691 and R005691-02, October 1982.
21. U.S. Army Corps of Engineers, Detroit District, Draft Environmental Impact
Statement: Upper Saginaw River Diked Disposal Facility of Crow Island
State Game Area Saginaw and Bay Counties, Michigan, November 1984.
U.S. Environmental Protection Agency
Region 5, Library (PL-12J)
77 West Jackson Boulevard, 12th Roar
Chicago. IL 60604-3590
-------
905488003A
APPENDIX A
Dow Chemical Untreated Wastewaters and
In-Plant Sludges
U.S. Environmental Protection Agency
Region 5, Library (PI-12J)
77 West Jackson Boulevard, 12th Floor
Chicago. II 60604-3590
-------
APPENDIX A-l
Major Process Sewers
-------
ischarger:
imple Date;
U.S. ENVIRONMENTAL PROTECTION AGENCY
REGION V
EASTERN DISTRICT OFFICE
Dow Chemical Process Sewers
Sample Type: 8 C-8 hour flow proportioned composite
24C-24 hour flow proportioned composite
EVC-Equal volume composite
G-Grab
Sample Type
Time
Sample Number 84ER07
Date
Parameter
I. VOLATILES
Acroleln
Acrylonltrile
Benzene
Carbon tetrachlorlde
Chlorobenzene
1,2-dichloroethane
1,1,1-tnchloroethane
1,1-dichloroethane
1 ,1 ,2-trlchloroethane
1,1,2 ,2-tetrachl oroethane
Chloroethane
B1 s( chl oromethyl J ether
2-chloroethyl vinyl ether
Chloroform
1,1-dichloroethene
Trans-1 ,2-dichloroethene
1 ,2-dlchloropropane
Trans-l ,3-d1chl oropropene
Cls-1 ,3-dlchl oropropene
Ethyl benzene
Methyl ene chloride
Chl orome thane
100
Sewer
G
0003
S02
8/29/84
ug/1
(ppb)
ND/100
ND/100
ND/ 5
ND/ 5
240
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ R
ND/ 5
ND/ 5
ND/ 5
ND/10
ND/ 5
8100*
ND/ 5
100
Sewer
G
1025
S03
8/29/84
ug/1
(ppb)
ND/100
ND/100
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
Np/ 5
NH/ $
wn/ 5
ND/ 5
ND/ 5
ND/ 5
ND/10
ND/ 5
19000*
ND/ 5
200
Sewer
G
0043
S07
8/29/84
ug/1
(ppb)
ND/100
ND/100
ND/ 5
ND/ 5
1200
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/10
ND/ 5
40000*
ND/ 5
200
Sewer
G
1040
SOS
8/29/84
ug/1
(ppb)
ND/100
3200
5J
ND/ 5
1900
ND/ 5
ND/ 5
ND/ 5
NO/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
MD/ 5
wn/ «>
ND/ 5
54
ND/ 5
ND/10
ND/ 5
2900*
ND/ 5
300
Sewer
G
0058
S17
8/29/84
ug/1
(ppb)
ND/1000
ND/1000
120A
ND/100
580A
ND/100
ND/100
ND/100
ND/100
ND/100
ND/100
ND/100
ND/1000
?80A
Nn/inn
170A
ND/100
ND/100
ND/100
ND/100
11000*
ND/100
300
Sewer
G
1105
S18
8/29/84
ug/1
(ppb)
ND/500
ND/500
140A
ND/50
650
ND/50
ND/50
ND/50
ND/50
ND/50
ND/50
ND/50
ND/500
470 A
ND/50
170A
ND/50
ND/50
ND/50
ND/50
8500*
ND/50
400
Sewer
G/1021
85ER01
S20
10/23/84
ug/1
(ppb)
NA
NA
18000
ND/ 5
6900
8.5
12
5J
ND/ 5
ND/ 5
ND/10
NA
ND/10
5 ft
NR/ «;
NH/ 5
3?
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/10
500
Sewer
G
0200
S32
8/29/84
ug/1
(ppb)
ND/100
ND/100
1300
81
120
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
«vl
Nn/ *\
ND/ 5
ND/ 5
MD/ 5
ND/10
450
140*
8000
500
Sewer
G
1150
S33
8/29/84
ug/1
(ppb)
ND/100
ND/100
1000
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
Nn/ 5
NR/ *5
un/ 5
Nn/ 5
Nn/ 5
Nn/io
540
1100*
2700
601
Sewer
G
0050
S53
8/29/84
ug/1
(ppb)
ND/5000
ND/5000
590A
21000
ND/500
ND/500
ND/500
ND/500
ND/500
ND/500
ND/500
NO/500
Nn/Rooo
Nn/^nn
wn/^nn
Nn/^no
Nn/snn
ND/500
ND/500
3000A
890 A*
6600
-------
scharger:
.mple Date:
U.S. ENVIRONMENTAL PROTECTION AGENCY
REGION V
EASTERN DISTRICT OFFICE
Dow Chemical Process Sewers
Sample Type: 8 C-8 hour flow proportioned composit
24C-24 hour flow proportioned composit
EYC-Equal volume composite
G-Grab
Sample Type
Time
Samole Number 84ER07
Date
Parameter
I. VOLATILE"*
Ac role In
Acrylonltrlle
Benzene
Carbon tetrachloride
Chlorobenzene
1,2-dichloroethane
1 ,1 ,1-trlchloroethane
1,1-dichloroethane
1,1,2-trlchloroethane
1 ,1 ,2 ,2-tetrachloroethane
Chloroethane
B1 s( chl oromethyl ) ether
2-chloroethyl vinyl ether
Chloroform
1,1-dlchloroethene
Trans-l ,2-dfchloroethene
1 ,2-dlchloropropane
Trans-l ,3-dlchloropropene
Cls-1 ,3-dlchloropropene
Ethyl benzene
Methyl ene chloride
Chloromethane
601
Sew^r
G
0945
S54
8/29/84
ug/1
(ppb)
ND/2000
ND/2000
920A
36000
ND/200
ND/200
3600
ND/200
ND/200
ND/200
ND/200
ND/200
ND/2000
ND/200
ND/200
ND/200
ND/200
ND/200
ND/200
3900
1700A
10000
610
Sewer
G
0107
S58
8/29/84
ug/l
(ppb)
ND/10
ND/10
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/10
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
4A*
2A
610
Sewer
G
1000
S59
8/29/84
ug/1
(ppb)
ND/200
ND/200
ND/20
540
ND/20
110A
ND/20
ND/20
ND/20
ND/20
ND/20
ND/20
ND/200
29A
ND/20
ND/20
ND/20
ND/20
ND/20
100A
850*
2400
50
Sewer
G
0245
S48
8/29/84
ug/1
(ppb)
ND/100
ND/100
20000
ND/ 5
4400
ND/ 5
ND/ 5
ND/ 5
ND/ 5
NO/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
5J
ND/ 5
ND/ 5
ND/ 5
ND/10
ND/ 5
670*
ND/ 5
50
Sewer
G
1225
S49
8/29/84
ug/1
(ppb)
ND/100
ND/100
29000
ND/ 5
5500
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/10
ND/ 5
ND/ 5
ND/ 5
76
Sewer
G
0220
S22
8/29/84
ug/1
(ppb)
ND/100
ND/100
26000
ND/ 5
2000
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/10
ND/ 5
690*
ND/ 5
76
Sewer
G
1205
S23
8/29/84
ug/1
(ppb)
ND/100
ND/100
7000
ND/ 5
820
ND/ 5
ND/ 5
ND/ 5
ND/ 5
NO/ 5
NO/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/10
ND/ 5
5J*
ND/ 5
Dow
Corning
G
0330
S42
8/29/84
ug/1
(ppb)
ND/100
ND/100
5J
ND/ 5
ND/ 5
ND/ 5
22000
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/10
ND/ 5
5J*
19000
Dow
Corning
G
0905
S43
8/29/84
ug/1
(ppb)
ND/100
ND/100
ND/ 5
ND/ 5
ND/ 5
ND/ 5
19000
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/1Q
ND/ 5
5J*
18000
-------
scharger:
mple Date:
U.S. ENVIRONMENTAL PROTECTION AGENCY
REGION Y
EASTERN DISTRICT OFFICE
Dow Chemical Process Sewers
Sample Type: 8 C-8 hour flow proportioned composite
24C-24 hour flow proportioned composite
EVC-Equal volume composite
G-Grab
Sample Type
Time
Samole Number 84ER07
Date
Parameter
I. VOLATILE^ (continued)
Bromomethane
Bromoform
Bromodlchl oromethane
Trlchlorofluoromethane
Dlchl orodl f 1 uoromethane
Chi orodi bromomethane
Tetrachloroethene
oluene
richioroethene
Vinyl chloride
Acetone
-butanone
Carbon dlsulfide
-hexanone
4-methyl -Z-pentanone
Styrene
Vinyl acetate
Total xylenes
100
Sewer
G
0003
S02
8/29/84
ug/1
(DDb)
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ b
260
ND/ 5
ND/ 5
ND/ 5
ND/100
ND/200
ND/10
ND/100
ND/100
ND/ 5
ND/10
ND/ 5
100
Sewer
G
1025
SOS
8/29/84
ug/1
(ppb)
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/100
ND/200
ND/10
ND/100
ND/100
ND/ 5
ND/10
ND/ 5
200
Sewer
G
0043
S07
8/29/84
ug/1
(ppb)
ND/ 5
ND/ 5
ND/ 5
ND/ 5
Nb/ 5
ND/ 5
1300
ND/ 5
ND/ 5
ND/ 5
ND/100
ND/200
ND/10
ND/100
ND/100
ND/ 5
ND/10
ND/ 5
200
Sewer
G
1040
SOS
8/29/84
ug/1
(ppb)
ND/ 5
ND/ 5
ND/ 5
ND/ 5
my 5
ND/ 5
440
5J
ND/ 5
ND/ 5
ND/100
ND/200
ND/10
ND/100
ND/100
ND/ 5
ND/10
ND/ 5
300
Sewer
G
0058
S17
8/29/84
ug/1
(ppb)
ND/100
ND/100
ND/100
ND/100
ND/100
ND/100
250A
ND/100
270A
ND/100
300
Sewer
G
1105
S18
8/29/84
ug/1
(ppb)
ND/50
ND/50
ND/50
ND/50
ND/50
ND/50
290A
ND/50
310A
ND/50
1500A* 1600*
ND/1000
ND/100
ND/100
ND/100
ND/100
ND/100
ND/100
690
ND/50
ND/50
ND/50
ND/50
ND/50
ND/50
400
Sewer
G/1021
85ER01
S20
10/23/84
ug/1
(ppb)
ND/10
ND/ 5
ND/ 5
NA
NA
ND/ 5
5.1
8.4
ND/ 5
ND/10
ND/10
ND/10
ND/ 5
ND/10
ND/10
ND/ 5
ND/10
ND/ 5
500
Sewer
G
0200
S32
8/29/84
ug/1
(ppb)
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
So
1100
ND/ 5
ND/ 5
ND/100
ND/200
ND/10
ND/100
ND/100
ND/ 5
ND/10
5J
500
Sewer
G
1150
S33
8/29/84
ug/i
(ppb)
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 6
1500
ND/ 5
ND/ 5
ND/100
ND/200
ND/10
ND/100
ND/100
820
ND/10
NO/ 5
601
Sewer
G
0050
S53
8/29/84
ug/1
(ppb)
ND/500
ND/500
ND/500
ND/500
ND/500
ND/500
ND/500
4900A
ND/500
ND/500
ND/5000*
ND/5000
ND/500
ND/500
ND/500
29000
ND/500
ND/500
-------
scharger:
ample Date:
U.S. ENVIRONMENTAL PROTECTION AGENCY
REGION V
EASTERN DISTRICT OFFICE
Dow Chemical Process Sewers
Sample Type: 8 C-8 hour flow proportioned composit
24C-24 hour flow proportioned composit
Eye-Equal volume composite
G-Grab
Sample Type
Time
Sample Number 84ER07
Date
Parameter
I. VOLATILES (continued)
Bromomelhane
Bromoform
Bromodi chl oromethane
Trichl orof 1 uoromethane
Dichlorodi f 1 uoromethane
Chlorodibromomethane
Tetrachloroethene
Toluene
Trichl oroethene
Vinyl chloride
Acetone
2-butanone
Carbon disulfide
2-hexanone
4-methyl -2-pentanone
Styrene
Vinyl acetate
Total xylenes
601
Sewer
G
0945
S54
8/29/84
ug/1
(ppb)
ND/200
ND/200
ND/200
ND/200
ND/200
ND/200
ND/200
14000
ND/200
ND/200
ND/2000
NO/2000
ND/200
ND/200
ND/200
44000
ND/200
3200
610
$ewer
G
0107
S58
8/29/84
ug/1
(ppb)
2A
25
ND/ 1
ND/ 1
ND/ 1
NO/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
21A*
ND/10
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
610
Sewer
G
1000
S59
8/29/84
ug/1
(ppb)
ND/20
ND/20
ND/20
ND/20
ND/20
ND/20
34A
710
ND/20
ND/20
340A*
MD/200
ND/20
ND/20
ND/20
840
ND/20
110A
50
Sewer
G
0245
S48
8/29/84
ug/1
(ppb)
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
NO? 5
ND/ 5
ND/ 5
• wm
rtD/200
ND/10
ND/100
ND/100
ND/ 5
ND/10
ND/ 5
50
Sewer
G
1225
S49
8/29/84
ug/1
(ppb)
ND/ 5
NO/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
5J
ND/ 5
ND/ 5
ND/100
NV200
ND/10
ND/100
ND/100
ND/ 5
ND/10
ND/ 5
76
Sewer
G
0220
S22
8/29/84
ug/1
(ppb)
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/100
ND/200
ND/10
ND/100
ND/100
ND/ 5
ND/10
ND/ 5
76
Sewer
G
1205
S23
8/29/84
ug/1
(ppb)
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/100
ND/200
ND/:.O
NDAOO
ND/100
ND/ 5
ND/10
ND/ 5
Dow
Corning
G
0330
S42
8/29/84
ug/1
(ppb)
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
77000
ND/ 5
ND/ 5
ND/100
ND/200
ND/10
ND/100
ND/100
ND/ 5
ND/10
5J
Dow
Corning
G
0905
S43
8/29/84
ug/1
(ppb)
ND/ 5
NO/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
31000
ND/ 5
ND/ 5
ND/100
ND/200
ND/10
ND/100
ND/100
ND/ 5
ND/10
5J
-------
ischarger:
jmple Date:
U.S. ENVIRONMENTAL PROTECTION AGENCY
REGION Y
EASTERN DISTRICT OFFICE
Dow Chemical Process Sewers
Sample Type: 8 C-8 hour flow proportioned composite
24C-24 hour flow proportioned composite
EVC-Equal volume composite
G-Grab
Sample Type
Time
Sample Number 84ER07
Date
Parameter
100
Sewer
Comp.
1300-
1025
SOB
8/28-
29/84
ug/1
(ppb)
11. ACID AND BASOEUTRAL POLLUTANTS
z ,4 ,b-trichlorophenol
4-ch l oro-3-methyl phenol
2-chlorophenol
'd. ,4-dlchlorophenol
2, 4-dimethyl phenol
2-nitrophenol
4-mtrophenol
2,4-dinitrophenol
4 ,6-d1 ni tro-2-methy 1 phenol
Pentachlorophenol
Phenol
Benzole acid
2-methyl phenol
4-methyl phenol
i ,4 ,5-tnchl orophenol
Acenaphthene
Benzidine
,2,4-trichlorobenzene
Hexachlorobenzene
nexachioroethane
Bis(2-chloroethyi jether
ND/10
ND/20
ND/10
ND/10
ND/10
ND/20
ND/:,OO
ND/50
ND/20
ND/20
ND/10
ND/100
ND/:.O
ND/:.O
ND/100
ND/10
ND/40
ND/10
ND/10
ND/10
ND/10
200
Sewer
Comp.
1315-
1040
S10
8/28-
29/84
ug/1
(ppb)
ND/10
ND/20
ND/10
ND/10
ND/10
ND/20
ND/100
ND/50
ND/20
ND/20
550
ND/100
ND/10
490
ND/100
ND/10
ND/40
ND/10
ND/10
ND/10
ND/10
300
Sewer
Comp.
1405-
1105
S20
8/28-
29/84
ug/1
(ppb)
1800
ND/40
1400
9100
ND/40
ND/40
ND/40
ND/40
ND/40
4900
3100
ND/40
ND/40
ND/40
1100
ND/40
ND/40
ND/40
ND/40
ND/40
ND/40
400
Sewer
G
1021
85ER01
S20
10/23/84
ug/1
(ppb)
120
ND/10
110
260
ND/10
ND/10
ND/50
ND/50
ND/50
960
200
ND/50
ND/10
ND/10
100
ND/10
ND/100
200
10J
ND/10
ND/10
500
Sewer
Comp.
1440-
1150
S35
8/28-
29/84
ug/1
(ppb)
270
ND/20
ND/10
570
ND/10
ND/20
ND/100
ND/50
ND/?0
ND/20
44
ND/100
ND/10
ND/10
ND/100
ND/10
ND/40
ND/10
ND/10
ND/10
ND/10
601
Sewer
Comp.
1236-
0945
S5<5
8/28-
29/84
ug/1
(ppb)
ND/ ?
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ ?
ND/ 2
120
130
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
610
Sewer
Comp.
1241-
1000
§61
8/28-
29/84
ug/1
(ppb)
7A
ND/ 2
ND/ 2
240
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ ?
ND/ 2
4A
NO/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
NO/ 2
ND/ 2
ND/ 2
ND/ 2
50
Sewer
Comp.
1500-
1225
551
8/28-
29/84
ug/1
(ppb)
1500
ND/2Q
670
3800
ND/10
ND/20
ND/100
ND/50
hin/?o
3300
6500 0
ND/100
ND/10
ND/10
100J
ND/1Q
ND/40
500
ND/10
ND/10
ND/10
76
Sewer
Comp.
1405-
1205
S2b
8/28-
29/84
ug/1
(ppb)
MD/1Q
HP/20
ND/10
ND/10
ND/10
ND/20
ND/100
ND/50
MD/?Q
ND/20
19QQQQ 0
ND/100
ND/10
ND/10
ND/100
ND/1Q
ND/40
10J
ND/10
ND/10
ND/10
Dow
Corning
Comp.
1220-
0905
S4b
8/28-
29/84
ug/1
(ppb)
NJ/1Q
ND/2Q
m/10
ND/10
ND/10
ND/20
ND/100
ND/50
MD/?O
ND/2Q
ND/1Q
23
ND/10
ND/10
ND/100
ND/1Q
ND/4Q
ND/10
ND/10
ND/10
ND/10
-------
ischarger:
ample Date:
U.S. ENVIRONMENTAL PROTECTION AGENCY
REGION Y
EASTERN DISTRICT OFFICE
Dow Chemical Process Sewers
Sample Type: 8 C-8 hour flow proportioned composU
24C-24 hour flow proportioned composit
EVC-Equal volume composite
G-Grab
Sample Type
Time
Sample Number 84ER07
Date
Parameter
TTTACID AND BASE NEU1KAL POLL
Z-chloronaphthalene
T7?-dichl orobenzene
1,3-dlchlorobenzene
1 ,4-dichlorobenzene
3,3J-dichlorobenz1dine
2, 4-d1n1tro toluene
2~76-di n i troto I uene
172-dl phenyl hydrazine
FTuoranthene
4-chlorophenyl phenyl etner
•-Droinopncnjr i pncnjr i ~ mcr
Bls(2-chioroisopropyi jetner
B1 s( Z-chl oroethoxy )me thane
Hexachl orobutadi ene
Hexachl orocyc l opentadl ene
Isophorone
Naphthalene
Nitrobenzene
N-ni trosodimetnyl ami ne
N-ni trosodi phenyl ami ne
N-nitrosodlproplyamine
Bts(2-ethylhexyi )phthalate
100
Sewer
Comp.
1300-
1025
S05
8/28-
29/84
ug/1
[ (ppb)
.UTANTS ((
ND/10
ND/10
ND/10
ND/10
ND/20
ND/20
ND/10
ND/20
ND/10
ND/10
kin /i n
nuf L\J
ND/10
ND/20
ND/10
ND/10
ND/10_j
ND/10
ND/10
ND/10
ND/10
ND/20
ND/10
200
Sewer
Comp.
1315-
1040
S10
8/28-
29/84
ug/1
(ppb)
:ontlnued
ND/10
360
ND/10
ND/10
ND/20
ND/20
ND/10
ND/20
ND/10
ND/10
un/1 n
ND/10
ND/20
ND/10
ND/10
ND/10
330
ND/10
ND/10
ND/10
ND/20
ND/10
300
Sewer
Comp.
1405-
1105
S2U
8/28-
29/84
ug/1
(ppb)
ND/40
77A
ND/40
130A
ND/40
ND/40
ND/40
ND/40
ND/40
ND/40
ND/40
ND/40
ND/40
ND/40
ND/40
ND/40
ND/40
ND/40
ND/40
ND/40
ND/40
ND/40
400
Sewer
G
1021
bbEKUl
S20
10/23/84
ug/1
(ppb)
ND/10
280
17
220
ND/20
ND/10
ND/10
NA
ND/10
ND/10
ND/10
56
ND/10
ND/10
ND/10
ND/10
10J
ND/10
ND/10
ND/10
ND/10
10JB
500
Sewer
Comp.
1440-
1150
S3b
8/28-
29/84
ug/1
(ppb)
ND/10
30
ND/10
10J
ND/20
ND/20
ND/10
ND/20
ND/10
ND/10
ND/10
ND/10
ND/20
ND/10
ND/10
ND/10
30
ND/10
ND/10
ND/10
ND/20
ND/10
601
Sewer
Comp.
1236-
0945
Sbb
8/28-
29/84
ug/1
(ppb)
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
NO/ 2
ND/ 2
ND/ 2
NO/ 2
ND/ 2
ND/ 2
67
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
610
Sewer
Comp.
1241-
1000
bbl
8/28-
29/84
ug/1
(ppb)
ND/ 2
34
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
4A
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
29
ND/ 2
ND/ 2
ND/ 2
ND/ 2
8A
50
Sewer
com p.
1500-
1225
bbi
8/28-
29/84
ug/1
(ppb)
ND/10
620 0
77
540 0
ND/20
ND/20
ND/10
ND/20
Nn/10
ND/10
ND/10
10J
ND/20
ND/10
ND/10
ND/10
260 0
ND/10
ND/10
10J
ND/20
ND/10
76
Sewer
comp .
1405-
1205
b£5
8/28-
29/84
ug/1
(ppb)
ND/10
110
ND/10
88
ND/20
ND/20
ND/10
ND/20
wn/in
ND/1Q
ND/10
22
ND/20
ND/10
ND/10
ND/10
ND/10
ND/10
ND/10
ND/10
ND/20
ND/10
Dow
Corning
1220-
0905
8/28-
29/84
ug/1
(ppb)
ND/10
ND/10
ND/10
ND/10
ND/20
ND/20
ND/10
NU/20
wn/io
Nn/io
ND/10
ND/10
ND/2Q
ND/10
ND/10
ND/10
N.n/10
un/io
un/io
ND/10
ND/20
ND/10
-------
ischarger:
imple Date:
U.S. ENVIRONMENTAL PROTECTION AGENCY
REGION V
EASTERN DISTRICT OFFICE
Dow Chemical Process Sewers
Sample Type: 8 C-8 hour flow proportioned composite
24C-24 hour flow proportioned composite
EYC-Equal volume composite
G-Grab
. e Type
Time
Sample Number 84ER07
Parameter
100
^wp>r
Comp.
1300-
in?5
SOS
8/28-
?Q/ft4
ug/1
(nob)
200
-------
ischarger:
imple Date:
U.S. ENVIRONMENTAL PROTECTION AGENCY
REGION V
EASTERN DISTRICT OFFICE
Dow Chemical Process Sewers
Sample Type: 8 C-8 hour flow proportioned composit
24C-24 hour flow proportioned composit
EYC-Equal volume composite
G-Grab
e Type
Time
Sample Number 84ER07
Date
Parameter
II. ACID AND BASE NEUTRAL POL
Z-methyl naphthalene
2-mtroanillne
3-mtroanllTne
4-nltroan1line
100
Sewer
Comp.
1300-
1025
S05
8/28-
29/84
ug/1
(ppb)
200
Sewer
Comp.
1315-
1040
§10
8/28-
29/84
ug/1
(ppb)
UTANTS (continued
ND/20
ND/100
ND/100
ND/100
ND/20
ND/100
ND/100
ND/100
300
Sewer
Comp .
1405-
1105
S20
8/28-
29/84
ug/1
(ppb)
ND/40
ND/40
ND/40
ND/40
400
Sewer
G
1021
85ER01
S20
10/23/84
ug/1
(ppb)
ND/10
ND/50
ND/50
ND/50
500
Sewer
Comp.
1440-
1150
535
8/28-
29/84
ug/1
(ppb)
ND/20
ND/100
ND/100
ND/100
601
Sewer
Comp.
1236-
0945
556
8/28-
29/84
ug/1
(ppb)
ND/ 2
ND/ 2
ND/ 2
ND/ 2
610
Sewer
Comp.
1241-
1000
561
8/28-
29/84
ug/1
(ppb)
ND/ 2
ND/ 2
ND/ 2
ND/ 2
50
Sewer
Comp.
1500-
1225
Sbl
8/28-
29/84
ug/1
(ppb)
ND/20
ND/100
ND/100
ND/100
76
Sewer
Comp.
1405-
1205
SJ?b
8/28-
29/84
ug/1
(ppb)
ND/20
ND/100
ND/100
ND/100
Dow
Corning
Comp.
1220-
0905
S4b
8/28-
29/84
ug/1
(ppb)
ND/20
ND/100
ND/100
ND/100
-------
scharger:
imple Date:
U.S. ENVIRONMENTAL PROTECTION AGENCY
REGION V
EASTERN DISTRICT OFFICE
Dow Chemical Process Sewers
Sample Type: 8 C-8 hour flow proportioned composite
24C-24 hour flow proportioned composite
EYC-Equal volume composite
G-Grab
sample Type
Time
Sample Number H4ER07
Date
Parameter
III. PCB/PESTICIDE POLLUTANTS
Aldrin
Dieldrfn
Chlordane
4, 4 '-DDT
4,4'-DDE
4, 4 '-ODD
Alpha-endosulfan
Beta-endosuifan
Endosulfan sulfate
Endrln
Endrln aldehyde
Heptachlor
Heptacmor epoxide
Alpha-BHC
Beta-BHC
Gamma-BHC
Delta-BHC
PCB-1242
PCB-1Z54
PCB-1221
PCB-1232
PCB-124U
PCB-1260
PCB-1016"
Toxaphene
100
Sewer
Com p.
1300-
1025
SUb
8/28-
29/84
ug/1
(ppb)
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
200
Sewer
Comp.
1315-
1040
SiU
8/28-
29/84
ug/1
(ppb)
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/O.i
ND/6.1
ND/0.1
300
Sewer
Comp.
1405-
1105
S2U
8/28-
29/84
ug/1
(ppb)
ND/50
ND/50
ND/500
ND/50
ND/50
ND/50
ND/50
ND/50
ND/50
ND/50
ND/50
ND/50
ND/50
ND/50
ND/50
ND/50
ND/50
ND/500
ND/500
ND/500
ND/500
ND/500
ND/500
ND/500
ND/500
400
Sewer
ti
1021
BbLKUl
S20
10/23/84
ug/1
(ppb)
ND/0.5
ND/ 1
ND/ 5
ND/ 1
ND/ 1
ND/ 1
ND/0.5
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/0.5
ND/0.5
ND/0.5
ND/0.5
ND/0.5
ND/0.5
ND/ 5
ND/10
ND/ 5
ND/ 5
ND/ 5
NO/10
ND/ 5
ND/10
500
Sewer
uomp.
1440-
1150
bJb
8/28-
29/84
ug/1
(ppb)
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/Qrl
601
Sewer
Comp.
1236-
0945
bbb
8/28-
29/84
ug/1
(ppb)
ND/0.1
ND/O.I
ND/ 1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.5
ND/0.1
ND/0.5
ND/0.1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
NP/ I
610
Sewer
Comp.
1241-
1000
bSi1 '
8/28-
29/84
ug/1
(ppb)
ND/ 9
ND/ ?
ND/?0
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ml 2
ND/ 7
ND/ 2
ND/ 2
ND/ 2
ND/20
ND/20
ND/20
ND/20
ND/20
ND/20
ND/20
ND/20
50
Sewer
C6rtlp.
1500-
1225
-"SSI"-
8/28-
29/84
ug/1
(ppb)
ND/0.1
ND/D.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.
ND/0.
ND/0.1
ND/0.
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
76
Sewer
Comp.
1405-
1205
— "S2S
8/28-
29/84
ug/1
(ppb)
ND/n.i
hin/n.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.
ND/0.
ND/0.
ND/0.
ND/0.
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
Dow
Corning
•tomp':1 •
1220-
0905
— s«—
8/28-
29/84
ug/1
(ppb)
ND/n.1
wn/n . i
wn/n.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
wn/n.i
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0 . 1
-------
scharger:
mple Date:
U.S. ENVIRONMENTAL PROTECTION AGENCY
REGION Y
EASTERN DISTRICT OFFICE
Dow Chemical Process Sewers
Sample Type: 8 C-8 hour flow proportioned composit
24C-24 hour flow proportioned composit
EVC-Equal volume composite
G-Grab
Sample Type
Time
Sample Number 84ER07
Date
Parameter
IV. METALS
Aluminum
Antimony
Arsenic
Barium
Beryl 1 1 urn
Cadmium
Chromium
Cobal t
Copper
Iron
Lead
Manganese
Mercury
Nickel
Selenium
Silver
Thallium
Tin
Vanadium
Zinc
100
Sewer
Comp.
1300-
1025
505
8/28- '
29/84
ug/1
(ppb)
62 5C
ND/ 6
ND/ 8
109
ND/ 1
ND/0.5
25
ND/10
14
2270C
ND/ 2
205
ND/0.2
ND/15
ND/ 2
ND/ 3
ND/ 2
ND/ B
17
96C
200
Sewer
Comp.
1315-
1040
S1U
8/28-
29/84
ug/1
(ppb)
1850C
ND/ 6
38
65
ND/ 1
1.2
1490
ND/10
219
11000C
37
504
0.27
428
ND/ 2
ND/ 3
ND/ 2
ND/ B
6
929C
300
Sewer
Comp.
1405-
1105
S2U
8/28-
29/84
ug/1
(ppb)
86C
ND/ 6
94
35
ND/ 1
ND/0.5
9
ND/10
7
824C
6.2
71
ND/0.2
ND/15
ND/ 2
ND/ 3
ND/ 2
ND/ B
ND/ 4
131C
400
Sewer
G
1021
85ERU1
S20
10/23/84
ug/1
(ppb)
731
74
ND/ 9
97
ND/1.3
ND/2.3
34
ND/4.7
25
8670
ND/4.5
140
1.5
28
ND/ 2
9.1
ND/ 5
ND/14
9.2
205
500
Sewer
Comp.
1440-
1150
S3b
8/28-
29/84
ug/1
(ppb)
\?RC.
ND/ 6
ND/ 8
35
ND/ 1
0.77
205
ND/10
30
36300C
ND/ 2
97
0.75
ND/15
ND/ 2
ND/ 3
ND/ 2
ND/ B
5
84C
601
Sewer
Comp.
1236-
0945
Sbb
8/28-
29/84
ug/1
(ppb)
664C
ND/ 6
ND/ 8
45
ND/ 1
2.4
320
ND/10
1010
2090C
ND/ 2
166
0.57
ND/15
ND/ 2
4
ND/ 2
ND/ B
5
143C
610
Sewer
Comp.
1241-
1000
Sbl
8/28-
29/84
ug/1
(ppb)
4Q30C
27
13
70
ND/ 1
0.89
103
ND/10
22
1370C
5.0
69
ND/0.2
16
2.8
ND/ 3
ND/ 2
ND/ B
6
234C
50
Sewer
Comp.
1500-
1225
5bl
8/28-
29/84
ug/1
(ppb)
370C
17
ND/ 8
46
ND/10
ND/0.5
48
ND/100
76
10800C
9.9
200 _j
0.33
ND/150
15
ND/30
ND/ 2
ND/200
ND/40
126C
76
Sewer
Comp.
1405-
1205
bZb
8/28-
29/84
ug/1
(ppb)
M on
49
79
230
ND/10
5.2
600
300
1940
649000C
125
5540
0.93
1570
ND/30
ND/ 2
ND/200
99
586C
Dow
Corning
Comp .
1220-
0905
8/28-
29/84
ug/1
(ppb)
5.3?r.
NP7 6
ND/ 8
51
ND/ 1
6.5
350
ND/10
2910
3980C
6.8
288
1.3
N.p/15
ND/ 2
ND/ 3
ND/ 2
ND/ B
7
195C
-------
scharger:
mple Date;
U.S. ENVIRONMENTAL PROTECTION AGENCY
REGION V
EASTERN DISTRICT OFFICE
Dow Chemical Process Sewers
Sample Type: 8 C-8 hour flow proportioned composite
24C-24 hour flow proportioned composite
EYC-Equal volume composite
G-Grab
Sample Type
Time
Sample Number 84tRU/
Date
Parameter
v. DIOXINS AND FURANS
2378-TCDD
Total Tetra, CDDs
Total Penta CDDs
Total Hexa CDDs
Total Hepta CDDs
OCDD
2378-TCDF
Total Tetra CDFs
Total Penta CDFs
Total Hexa CDFs
Total Hepta CDFs
OCDF
100
Sewer
Comp.
1300-
1025
SUb
8/28-
29/84
ppt
ND/.046
ND/.019
ND/.080
ND7.049
ND/.058
1.43
ND/.050
0.098
ND/.066
ND/.056
ND/.055
NO/. 377
200
Sewer
Comp.
1315-
1040
blU
8/28-
29/84
PPt
300
Sewer
Comp.
1405-
1105
bzu
8/28-
29/84
ppt
ND/.177
0.355
ND/.433
ND/.623
3.41
28.2
0.685
5.50
5.91
KID 7.493
1.06
2.45
400
Sewer
G
1021
tJbtKUl
S20
.0/23/84
ppt
ND
ND/.02
ND/.015
0.25
0.45
3.67
0.25
0.97
1.16
Np/.Ol
8.4
22.2
500
Sewer
Comp.
1440-
1150
bJb
8/28-
29/84
ppt
NO/. 645
28.9
ND/.310
ND/.235
8.24
62.7
0.557
566
4.32
4.67
15.5
19.3
601
Sewer
Comp.
1236-
0945
Sbb
8/28-
29/84
ppt
ND/.036
ND/.033
ND/.201
ND/.055
0.124
1.06
ND/.099
0.439
ND/.044
ND/.093
0.183
0.466
610
Sewer
Comp.
1241-
1000
M>1
8/28-
29/84
ppt
ND/.057
ND/.051
ND/.271
ND/.144
ND/.38
3.93
ND/.054
ND/.066
ND/.123
ND/.258
8.03
208
50
Sewer
Comp.
1500-
1225
bbl
8/28-
29/84
ppt
76
Sewer
Comp.
1405-
1205
bZb
8/28-
29/84
ppt
ND/.132
ND/.117
ND/.39E
ND/.167
2.69
16.6
ND/.230
NO/. 071
ND/.070
ND/.125
ND/.222
1.43
Dow
Corning
Comp.
1220-
0905
blb
8/28-
29/84
ppt
ND/.016
ND/.011
ND/.522
ND/.116
ND/.172
0.305
ND/.057
ND/.061
ND/.069
ND/.128
ND/.291
ND/.128
-------
scharger:
imple Date:
U.S. ENVIRONMENTAL PROTECTION AGENCY
REGION V
EASTERN DISTRICT OFFICE
Dow Chemical Process Sewers
Sample Type: 8 C-8 hour flow proportioned composlt
24C-24 hour flow proportioned composlt
EYC-Equal volume composite
G-Grab
Sample Type
Time
Sample Number 84ER07
Date
Parameter
VI. OTHFR PARAMFTERS
Total Dissolved Solids
Total Susoended Solids
BODc
KIHo
TP
TKN
Total Phpnolics
100
Sewer
Comp.
1300-
1025
SOS '
8/28-
29/84
mg/1
3726
413
5.52
1.?ft
0.202
1.67
0.15
200
Sewer
(lomp.
1315-
1040
510'
8/28-
29/84
mg/1
4068
40
264
10.6
42.0
21.9
1.00
300
Sewer
Comp.
1405-
1105
S20
8/28-
29/84
mg/1
472
42
55
1.68
n.604
2.82
20.0
400
Sewer
G
1021
85ERU1 '
S20
10/23/84
mg/1
NA
NA
NA
NA
NA
NA
NA
500
Sewer
Comp.
1440-
1150
b3b
8/28-
29/84
mg/1
1422
586
118
0.891
0.151
2.12
1.60
601
Sewer
Comp.
1236-
0945
Sbb
8/28-
29/84
mg/1
2940
1096
67.8
4.28
0.277
4.78
5.00
610
Sewer
Comp.
1241-
1000
J>bi
8/28-
29/84
mg/1
1846
88
123
0.653
0.244
2.98
0.50
50
Sewer
Comp.
1500-
1225
Sbl
8/28-
29/84
mg/1
26170
66
5.76
1.12
ND/.l
1.39
240
76
Sewer
comp.
1405-
1205
bZb
8/28-
29/84
mg/1
17700
116
NO/ 6
0.558
ND/.l
0.46
600
Dow
Corning
comp.
1220-
0905
575
8/28-
29/84
mg/1
4324
60
18.0
8.7
0.468
6.74
0.50
-------
Dow Chemical Process Sewers
NOTES:
1. * = Compound was present in blank sample. Methylene chloride is used as a cleaning
agent for sample bottles. Phthalate compounds are components of certain plastics
and are widespread in the environment at low levels.
2. A = Detected below quantisation limit (quantisation limit is 10 x detection limit).
3. C = Blank corrected.
4. J = Estimated value, detected below minimum specified contract detection limit but
greater than zero.
5. NA = Not analyzed.
6. ND = Compound was analyzed for but not detected. Value reported is the detection limit.
7. ND/ B = Not detected due to blank.
8. Q = Quantltated from secondary ion.
9. ug/1 = micrograms per liter.
10. mg/1 = milligrams per liter.
11. ppb = parts per billion.
12. ppm = parts per million.
13. ppt = parts per trillion.
14. — = Data unusable.
-------
Tentatively Identified Compounds
-------
KO t
ut>
QC ICKRT MD:
(00
IKKTlfltO
1
; I
.
5
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ft
7
t
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10
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12
13
14
IS
16
17
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20
21
22
23
24
25
2ft
J7
21
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30
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,
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mcriONJMASS mrcMiNG wxniics
i$KCirt)
• • ;
1
i »
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FlLiiNnriE:
NUliBEl-1
COtll::ULlJlIU_CJkUhltllLii_ijUtiLi:Sli .OdIu_SBELI
Ut>'nKY -.•.EHH-I H I^E^ULTS OK El'.TF'HNI OUS PEAK'7, i,
E;,|[HHrEfi COMCEHTRHTIGH OF TEHTHTIMELY IDENTIFIED COMPOUNDS
FRhCTIOH: FSCC7
AMPLE #
CA
K'35
20324-32-7
7
8
20324-32
20324-33
HHf-IE
2-PROPHWOL . l-(2-HETHOXY-l -METHYLETHOXY J >-
2-PROPAMOL . l-(2-f€THOXY-l-METHYLETHOXY>-
2-PfrOPAHOL 1 -x2-< 2-HETHOXY- 1 -f'lETHYLETHOXY) -1 -METhYLE
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PURITY
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RS 01 UK
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Q
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ITY
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kCP 4/SAS * 3069 LABORATORY IT/WCTS SAMPLE * E0475
DATE REC'D: 08/31/84 CONTRACT *: 6582 X MOISTURE: NA
DATA RELEASE AUTHORIZED BY:
'ANAtTYS
ORGAN1CS ^NAtTYSIS DATA SHEET
VOLATILE COMPOUNDS
SURROGATE SPIKE RECOVERIES
UNITS: UG/L
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LAB ID COMPOUND SAMPLE SPIKED 7. RECOVERY
1.2-DICHLOROETHANE-D4 5000. SOOG. IOO
30624N9 TOLUENE-D8 5060. SOOO loi
4-BROMOFLUOROBENZENE 5010. "5OOO. IOO
# - ASTERISKED VALUES ARE OUTSIDE QC LIMITS NS - NOT SPIKED
tt - RECOVERIES DUE TO DILUTION
* - RECOVERIES DUE TO MATRIX EFFECTS
TENTATIVELY IDENTIFIED COMPOUNDS
CONC(J) CAS # COMPOUND NAME SCAN # FIT
4 / / / /_
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7 / / / /_
8 / / / /_
9 / / / /
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18 / / / /_
19 / /__ / /_
20 / /____ / /_
21 / / / /_
22 / /_ / /_
23 / /_____ / /
24 / /___ / /~
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DATA RELEASE AUTHORIZED BY:
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LAB ID COMPOUND SAMPLE SPIKED % RECOVERY
1.2-DICHLOROETHANE-D4 2500. 2SCO IOO ^
30614N29 TOLUENE-D8 2910. 2SOO. I Up
4-BROMOFLUOROBENZENE 270O. 25OO )Cfc>
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CONC(J) CAS # COMPOUND NAME SCAN # FIT
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CASE */SAS *: 3069 LABORATORY. IT/WCTS
DATE REC'D: 08/31/84 CONTRACT * 6582
DATA RELEASE AUTHORIZED BY:
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ORGANIC
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-------
LAB NAME CAL CASE NO. 3383 SAMPLE NO ES498
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//
//
PROBABILITY THAT IDENTIFICATION 16 CORRECT:
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CAS* COMPOUND NAME FRACTION NUMBER PURITY J V
1. 54833-78-2 ACETAMIDE, N-\2-<1, 2-DIHYDRO-l- VOA 42 392 12
2. 616-21-7 BUTANE, 1,2-DICHLORO- VOA 299 82O 25
3. 106-46-7 BENZENE. 1.4-DICHLORO- VOA 362 892 86
4. 95-50-1 BENZENE, 1,2-DICHLORO- VOA 564 9O9 65
5. 95-50-1 BENZENE,1.2-DICMLORO- VOA 373 817 12
COMPOUND NAME PROBABILITY COMMENTS
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514
605
650
721
729
773
739
8!3
932
lOib
10-*3
1037
1232
1323
O. £
1408
2.000
;. - REnJ.O
ChS tt
5*4-25-2
1U0-41-4
100-41-4
629-20-9
5131-66-8
611-14-3
873-49-4
105-05-5
105-05-5
3454-97-7
103-57-6
108-57-6
55956-25-7
69-72-7
52783-43-4
29812-79-1
774-40-3
55956-41-7
2700 OC G —
50649-03-1
57-10-3/
COMPOUND NriME
1 , 3, 5-CYCLOHEPTATRIL-NE \^^~
fcENZENt, ETHYL —7
BENZENE, ETHYL- ^
1,3,5, 7-CYCLGOCTATE TRAENE
>PRGPhMOU 1-BUTQXY-
BENZENE, l-ETh'iL-2-METHYL-
BENZENE,CYCLOPROPYL-
BENZENE > 1 , 4-D I ETHYL 1
BENZENE, 1 . 4-D i ETHYL— "*
BENZENE , l-ETHEHYL-4-ETHYL-
BENZENE , 1 , 3-D i ETHENYL- 1
BENZENE , L 3-D 1 ETHENYLs J
2-PROPAf-WL • 1- l-METHYL-2-<2-PROPENYLOXY>ETHuXYv-
BENZuitHCiD,: HYDRO: :Y-
HONADELMNOL
HYDROXMAMIHE . 0-DEC YL-
BEN2ENEACETICHCIO/ .nLPHn. -HYDROXY-.ETHMESTER
PURITY
95.8
92.9
93.1
95.6
81.4
89.2
83.9
88.0
88.9
86.5
89.3
87.5
43.7
81.2
59.7
66.8
67.3
BICYCLO\3.2.1 OCT-2-ENE»3-BROMO-4-METHYL-,E:CO- 34.4
— 5 1 HLrl th . n tiJKUS i MM- 1 5-ur I/ T tu x IE i HT LcricMtRl'nF'TULL 9/1.4
L-HISTIDINE,h--x(2>4-OICHLOROPHENOXT)ACETYL>-.- 47.0
HEXADECANOICACID
40.00 5
UrtBLE IDENTIFICATION RETENTION TIME COMPATIBILITY
68.4
FECTROSCOPIST
DATE
ESTIMATED CONC.
ASSESSMENT* JH UG PER
RS 01 UK £K D D D
L KG ML G
D (3 D 370.
D El D 510.
nan
n S n
a a a
nan
n ca n
n a n
nan
nan
nan
n S n
n n 0
n o a
n n L?
n n H
n 0 n
n n 0
Bn n
LJ LIT
n n 0
n n n
n n E
~"&*
99.
340.
150.
150.
520.
240.
59.
47.
180.
80.
110.
82.
89.
91.
440.
56.
67.
£B.
61.
01 - ISOMES OR SIMILAR COMPOUND
Uc, - UNKNOWN, NOT IN NBS LIBRnPr
-------
CASE *. SAS * 3C69 LABORATORY IT/WCFS SAMI'LE I*
DATE REC'D OS/31/H'l CONTRACT * 65U2 /: NOlSTURE. NA
DATA RELEASE AUTHORIZE.!) BY
ORGAN ICS ANALYSIS DATA SHFFTl
VOLATILE COMPOUNDS
SURROGATE SPIKE RECOVER IflS
UNITS: UG/L
CDMC CONC
LAB ID COMPOUND SAMPLE Sf'JKED 7. RECOVERY
1,2-DICHLCROETHANE-04 2310O. 25000. 92
30624N17 TOLUENE-OS 24300. 25000. 97
4-BROMOFLUORQBENZENE 25100. 25000. 100
* - ASTERISKED VALUES ARE OUTSIDE QC LIMITS NS - NOT SPIKED
# - RECOVERIES DUE TO DILUTION
% - RECOVERIES DUE TO MATRIX EFFECTS
TL-MTATIVELY IDENTIFIED COMPOUNDS
CONC(J) CAS tt COMPOUND NAME SCAN # FIT
1 / / NONE FOUIO / /
3
4
5
6
7
8
9
1O
11
13
11
IS
16
17
IB
Vi
20
21
23
24
J - CONC. QUANTITATED USING PEAK HEIGHT, ASSUMING A RESPONSE FACTOR OF 1
-------
CASE-t/SAS tt 3069 LA30RATORY. IT/WCTS
DATE REC'D' 08/31/34 CONTRACT W. 65:32
D-ATA RELEASE AUTHORIZED QY:
SAMPLE *: E9030
7. (MOISTURE. NA
ORGAN ICS ANALYSIS DATA SHtlET
VOLATILE COiMPOUNDS
SURROGATE SPIKE RECOVER I US
UNITS: UG/L
LAD ID COMPOUND
1.2-DICHLOROETHANE-D4
30614N37 TCLUENE-D3
4-BROMOFLU030BENZENE
* - ASTERISKED VALUES ARE OUTSIDE QC LIMITS
# - RECOVERIES DUE TO DILUTION
* - RECOVERIES DUE TO MATRIX EFFECTS
CONC
SAMPLE
9790.
10200.
10200.
CONC
SP I KED
1OOOO.
10000.
10000.
7. RECOVERY
98
102
1O3
NS - MOT SPIKED
TFfNTATIVELY IDENTIFIED COMPOUNDS
CONC'.J) CAS U COMPOUND NAME
——••*-— — — • — — -—/•**•* -• • -" •" *—....--.-.....- . V- — -—_^- -..-Ij.W
SCAN *
FIT
3
5
6
7
8
9
10
11
13
16
17
IE*
19
cO
J - CONG. QUANTITATED USING PEAK HEIGHT, ASSUMING A RESPONSE FACTOR OF l.
-------
CASE »/SAS *: 3069 LABORATORY. IT/WCTS
DATE REC'D. 08/31/34 CONTRACT » o382
DATA RELEASE AUTHORIZED BY:
SAMPLE * E9080
V. MOISTURE NA
^^^
CRGANICS ANALYSIS DATA SHEET
EASE/NEUTRAL AND ACID COMPOUNDS
SURROGATE SPIKE RECOVERIES
UNITS: UG/L
LAB ID
30614F23
COMPOUND
2. -
NITROEENZENE-D5
2-FLUJPC3 IPHENYL
2. 4, &-TRI2P.GMOPHENOL
P-TERPHENYL-D1 4
CONC
SAMPLE
46.
66.
101.
86.
85.
55.
CONC
SPIKED
105.
110.
106.
104.
103.
50.
'/. RECOVERY
44
60
95
S3
83
110
* - ASTERISKED VALUES ARE OUTSIDE QC LIMITS
tt - RECOVERIES DUE TO DILUTION
* - RECOVERIES DUE TO MATRIX EFFECTS
NS - NOT SPIKED
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
?5
CONCCJ)
Voc
Zoo
•toe
7. PC-i?
O
Zoo
lo a
IP
/CO
_2AZ.
too
100
foo
1*3
CAS ft
TENTATIVELY IDENTIFIED COMPOUNDS
COMPOUND NAME
n-)
lal-LS-l
. t
SCAN ft FIT
T/7
-5V/
rn
173
4ijc
-------
C<* t_ » _>M.J f .jw^J I - •- -
DATE REC'D 08/31/9^ CONTRACT * 6582 '/. MOISTURE. NA
DATA RELEASE AUTHORIZED BY
ORGANTCS AjXTVSIS DATA SHEE'I
VOLATILE COMPOUNDS
SURROGATE SPIKE RECOVERIES
UNITS. UC/L
CQNC CDNC
LAB ID COMPOUND SAMPLE SPIKED '/. RECOVERY
1. 2-DICHLOROETHANE-D4 52. 5O. 1<)4
30624 N3 TOLUENE--D8 50 50. 100
4-BRONOFLUOROOENZENE 50 50. 100
* - ASTERISKED VALUES ARE OUTSIDE QC LIMITS '.MS - NOT SPIKED
* - RECOVERIES DUE TO DILUTION
* - RECOVERIES DUE TO MATRIX EFFECTS
TENTATIVELY IDENTIFIED COMPOUNDS
CONC(J) CAS # COMPOUND NAME SCAN 4* FIT
3 / /_i
4 / / ' \YVAlC
3
9
10
11
13
14
16
17
18
19
20
21
22
25 / / / /_
J - CONC. QUANTITATED USING PEAK HEIGHT, ASSUMING A RESPONSE FACTOR OF l
-------
CASE tV/SAS » 3069 LABORATORY IT/UiCTS
DATE REC'D. 08/31/94 CONTRACT * 6332
DATA RELEASE AUTHORIZED BY h
SAMPLE »: E908Q
7. MOISTURE: NA
ORGAN ICS ^rwtCVSIS DATA SHEET
VOLATILE COMPOUNDS
SURROGATE SPIKE RECOVERIES
UNITS: UG/L
LAB ID COMPOUND
1,2-DICHLOROETHANE-D4
30614N34 TOLUENE-D8
4-BROMOFLUOROBENZENE
* - ASTERISKED VALUES ARE OUTSIDE QC LIMITS
* - RECOVERIES DUE TO DILUTION
% - RECOVERIES DUE TO MATRIX EFFECTS
CONC
SAMPLE
988.
1060.
1210.
CONC
SPIKED
1000.
1000.
1000.
'/. RECOVERY
99
106
121
IMS - NOT SPIKED
1
^
c:
3
4
5
6
7
8
9
1O
11
12
13
15
16
17
18
19
20
21
TENTATIVELY IDENTIFIED COMPOUNDS
CONC(J) CAS # COMPOUND NAME
SCAN 1* FIT
23 / / / /
24 / / / /
25 / / / /
J - CONC. QUANTITATED USING PEAK HEIGHT, ASSUMING A RESPONSE FACTOR OF 1.
-------
CASE »/SAS tt: 3069 LABORATORY
DATE REC'D: 08/31/84 CONTRACT tt
DATA RELEASE AUTHORIZED BY:
IT/WCTS
6532
SAMPLE «: E9088
V. MOISTURE: NA
DATA SHEET
BASE/NEUTRAL AND ACID COMPOUNDS
SURROGATE SPIKE RECOVERIES
UNITS: UG/L
LAB ID
3O614F17
COMPOUND
NITROBENZENE-DS
2-FLUOROBIPHENYL
2, 4, 6-TRI3ROMOPHENOL
P-TERPHENYL-D14
CGNC
SAMPLE
v7? A
11
85.
82.
69.
CCNC
SPIKED
105.
110.
106.
104.
103.
50.
7. RECOVERY
fo *
109
82
30
138 *
* - ASTERISKED VALUES ARE OUTSIDE QC LIMITS
tt - RECOVERIES DUE TO DILUTION
* - RECOVERIES DUE TO MATRIX EFFECTS
NS - NOT SPIKED
CONC(J)
TENTATIVELY IDENTIFIED COMPOUNDS
CAS tt COMPOUND NAME
SCAN
FIT
-
7-*
/ fog -(/-;
v fc
/ /*/-/.?-.?
L7- 7/ -
' -*-»'«•'
i/ n/ <^ •« j .
tJ/Jr -J 6
3? <;
&OO
617
rot.
/**'
TtZ.
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
17
18
19
20
21
22
23 .
24 / / / /
25 / / / /
J - CCNC. GUANTITATED USING PEAK HEIGHT, ASSUMING A RESPONSE FACTOR OF 1.
77
-------
CKCA.NICS
DATA S*CET .
ut
QC «K*T NO:
•.
*****
SH6-SO
1
2
5
4
f
*
7
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10
11
12
19
14
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16
17
11
tt
20
21
22
»
24
25
M
27
n
29
JO
CAS t
-
OOKPOIM3 WMC
Vl/flfl T^TX/ldJC
O^
'
%
FRACTION
f MAXIN^* SCOWL ATTAINED
MASS MATCHING ROUT INC J
f SPECIFY)
* ' .
'
1
-------
JATA FILENAMEi GJ834717C84
ITEM
1 437
* -714
363
3+ 372
CAS t
188-98-7
—188^5-2
188-43-8
54446-78-5
1878
1861
£ 8 1834
7 9 1122
£tf 1163
? if 1183
/o *t 1248
u \X 1238
1343
1468
1467
1481
1576
1676
1816
1841
1831
63-72-7
13165-71-4
28324-33-8
32-52-4
181-64-8
14XZ2-6
38-43-7
28324-33-8
32-63-3
54852-74-3
143-22-6
55373-93-8
6738-*4-l
3333-94-6
2432-11-3
6833-63-4
COMPOUND NArtE
I
COMPOUNDS
Pl&TY
SMfflE t
BENZENE/ CHLORO-
86.4
PHENOL,3-CHLORO-
.l-a-aJTOXYETHOXY)-
D E D
D D D
D CO D
DDE
6ENZOICACIO/ 2-HYDROXY-
NAPHTHILENE, 2HCTHYL-
2-PROPflNOL, l-N2-<2-METHJXY-l-ieTHYIiTHOXY>-l-METlM*-T
l/r-«lPHENYL
:,l,r-OKYBIS-
2-PROPANOL, l-v2-<2-METHQXY-l-METHYl£THOXty-
M,r-8IPHENYL\-4-OL
BENZENE. ETHYLPHENQXY-
ETHANOL, 2-N2-<2-BUTOXYETOOXY>ETHOXY\- 1
BENZENE/ L1', 1' '-\l-(BROMOMETHYL)-2-METHOXY-l-METHYL
1,1' -BIPHENYL/2-PHENOXY-
1.1'-6IPHENYL/4-PHENOXY-
M /1' i3M "-TERPHENYLN-2'-OL
M,ri3M' '-TERPHENYL\-4'-OL
RETENTION TIHE COMPATIBILITY
-------
-
«
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it
91
-------
DATA FILENAMEi CH034724B15
ITEM
tfOW
CAS t
COMPOUND NAME
k
COMPOUNDS
PURITY
1
2
3
4
3
6
7
8
9
10
11
12
13
jH*5~
&
i£*r
i-
2-PROPANOL, l-\2-<2-METHOXY-l-METHYLETHOXY)-l-METI
BEN20ICACIO, 2-HYDRQXY-
Ll'-BIPHENYL
HEXANE,3,3-DIMETHYL-
BEHZENE,l,r-OXYBIS-
ETHANOL,2-\2-«
!-8UTOXYETHOXY)ETHOXYS"
M/r-BIPHENYLv-2-OL
2-PROPANOL, l-s2-<2-METHOXY-l-METHYLETHOXY)-|l-METI
PROPM40ICIC1D/2
HftDROXY-2-*ETHYL-,ETHVlJESTf R
ETHANE, 1 , 1' -OXYBIS\2-ETHOKY-
rL-Tonr
iftHUUUtlHnfc
ETHANOL, 2-\2-<2-BUTOXYETHOXY)ETHOXY\ -.
ETHENE, <2-ETHOXY-HCTHOXYETHOXY>-
BENZENAMINE, 4-METHYL-2, 6-OINITRO-
BEN2DC/L1M1
1 -\l-(BROMOMETHYL)-2-tl£THOXY-l-ME
96.2
87.7
74.3
HYLE-^, 84.6
86.7
90.8
82.8
88.4
77.4
80.5
4VLB-* 84.3
66.4
75.0
-86re
72.7
tvm ft
iir.o
73.2
45.6
FHYL 61.0
l-PROPA»«.,3,3t-Nl,3-PROPANEDIYLBIS
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-------
APPENDIX A-2
Nonprocess Wastewater Sources
-------
CA ^ «*/5AS 4*.
DA"E SEC 'D:
DA i'A
7-O6S
LABORATORY: IT/UCT5
CONTRACT **: 6532
SAMPLE *: E8A52
7. MOISTURE: NA
AUTHORIZED 2Y:
V >X-~
CHGANICS ANALYSIS DATA SHEET
VOLATILE COMPOUNDS
SURROGATE SPIKE RECOVERIES
UNITS: UG/L
LAB ID
30482N2
COMPOUND
1,2-DICHLGROETHANE-D4
TOLUENE-D3
4-3ROMOFLUOR02ENZENE
CONC
SAMPLE
4930.
4410.
4730.
CONC
SPIKED
5000.
50OO.
50OO.
7. RECOVERY
99
88
95
* - ASTERISKED VALUES AHE OUTSIDE QC LIMITS
# - RECOVERIES DUE TO DILUTION
RECOVERIES DUE TO MATRIX EFFECTS
NS - NOT SPIKED
$ -
CC,\'C< J>
1
2
3
4
5
h
7
3
9
10
11
13
13
16
17
10
19
20
21
r>r>
25
TENTATIVELY IDENTIFIED COMPOUNDS
CAS * CGnPOUND NAME
NONE FOUND
SCAN 1* FIT
J - CLir 1C. QUANTITATED USING PEAK HEIGHT, ASSUMING A RESPOIMSE FACTOR OF 1.
-------
scharger:
iiple Date:
U.S. ENVIRONMENTAL PROTECTION AGENCY
REGION V
EASTERN DISTRICT OFFICE
Dow Chemical Incinerator Wastewater Streams
Sample Type:
8 C-8 hour flow proportioned composite
24C-24 hour flow proportioned composite
EYC-Equal volume composite
G-Grab
Sample Type
Time
Sample Mnmhor 84ER06
Date
Parameter
I. VOLATILES
Acrolein
Acrylonitrile
Benzene
Carbon tetrachloride
Chlorobenzene
1,2-dlchloroethane
1,1,1-trichloroethane
1,1-dlchloroethane
1 ,1 ,2-trichloroethane
1 ,1 ,2 ,2-tetrachl oroethane
Chloroethane
81 s( chl oromethyl ) ether
2-chloroethyl vinyl ether
Chloroform
1,1-dlchloroethene
Trans-l ,2-dichloroethene
1,2-dlchloropropane
Trans-l ,3-dlchloropropene
C1s-l,3-dichloropropene
Ethyl benzene
Methyl ene chloride
Chloromethane
Service
Water
G
1755
SPO
8/29/84
ug/1
{ppb}
ND/10
ND/10
ND/ 1
13
1A
5A
8A
ND/ 1
NO/ 1
ND/ 1
ND/ 1
ND/ 1
ND/10
9A
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
120*
ND/ 1
Ash
Pit
G
0211
84FRQ8
S12
8/29/84
ug/1
(ppb}
ND/10
ND/10
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
NO/ 1
ND/ 1
ND/10
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
5A*
ND/ 1
Ash
Pit
G
1235
S13
8/29/84
ug/1
(opb)
ND/10
ND/10
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
NO/ 1
ND/ 1
ND/10
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
12*
ND/ 1
Quench
G
0143
S17
8/29/84
ug/1
(DDb)
ND/10
ND/10
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/10
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
3A*
ND/ 1
Quench
G
1136
S18
8/29/84
ug/1
(DDb)
ND/10
ND/10
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/10
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
11*
ND/ 1
ESP
G
0150
S27
8/29/84
ug/1
(DDb)
Kin/200
ND/200
ND/20
ND/20
ND/20
70A
ND/20
ND/20
ND/20
ND/20
ND/20
ND/20
ND/200
ND/20
ND/20
ND/20
ND/20
ND/20
ND/20
ND/20
2300*
67A
ESP
G
1136
S28
8/29/84
ug/1
(DDb)
ND/10
ND/10
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/10
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
9A*
3A
pemister
Venturi
G
0123
S32
8/29/84
ug/1
(pDb)
ND/10
ND/10
ND/ 1
ND/ 1
ND/ 1
ND/ 1
9A
ND/ 1
ND/ 1
NO/ 1
ND/ 1
ND/ 1
ND/10
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
12*
ND/ 1
)emister
Yenturi
G
1016
S33
8/29/84
ug/1
(ppb)
ND/10
ND/10
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/10
ND/ 1
ND/ 1
ND/ 1
ND/ 1
Nin/ 1
ND/ 1
ND/ 1
3A*
ND/ 1
-------
scharger:
nple Date;
U.S. ENVIRONMENTAL PROTECTION AGENCY
REGION V
EASTERN DISTRICT OFFICE
Dow Chemical Incinerator Wastewater Streams
Sample Type:
8 C-8 hour flow proportioned composite
24C-24 hour flow proportioned composite
EVC-Equal volume composite
G-Grab
Sample Type
Time
Sample Number 84ER08
Date
Parameter
II. ACID AND BASE NEUTRAL P'OLI
2 ,4 ,6-trichlorophenol
4-chl oro-3-methyl phenol
2-chlorophenol
2,4-dichlorophenol
2 ,4-dimethyl phenol
2-nitrophenol
4-nitrophenol
2 ,4-dinitrophenol
4 ,6-df ni tro-2-methyl phenol
Pentachlorophenol
Phenol
Benzole add
2-methyl phenol
4-methyl phenol
2 ,4 .5- trichl orophenol
Acenaphthene
Benzldlne
1,2,4-trlchlorobenzene
Hexachlorobenzene
Hexachloroethane
Bis(2-chloroethyl)ether
Service
Water
G
1755
84ER06
S20
8/29/84
ug/1
(ppb)
UTANTS
ND/ 2
ND/ 2
ND/ 2
4A
ND/ 2
NO/ 2
ND/ 2
ND/ 2
ND/ 2_
180
4A
7A
ND/ 2
ND/ 2
13A
ND/ 2
ND/ 2
8A
ND/ 2
ND/ 2
ND/ 2 I
Ash
Pit
Comp.
1356-
1235
S15
8/28-
29/84
ug/1
(ppb)
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
NO/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
2A
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
NDZ 2
ND/ 2
ND/ 2 |
ND/ 2
Quench
Comp.
1319-
1136
S20
8/28-
29/84
ug/1
(ppb)
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
62
21
12A
ND/ 2
ND/ 2
5A
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2 j
ND/ 2
ESP
Comp.
1330-
1136
S30
8/28-
29/84
ug/1
(ppb)
ND/ 2
ND/ 2
ND/ 2
7A
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
28
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
Demister
Venturi
Comp.
1300-
1016
S35
8/28-
29/84
ug/1
(ppb)
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
150
20
10A
ND/ 2
ND/ 2
8A
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
-------
charger:
iple Date:
U.S. ENVIRONMENTAL PROTECTION AGENCY
REGION V
EASTERN DISTRICT OFFICE
Dow Chemical Incinerator Wastewater Streams
Sample Type: 8 C-8 hour flow proportioned composite
24C-24 hour flow proportioned composite
EVC-Equal volume composite
G-Grab
Sample Type
Time
Sample Number 84ER06
Date
Parameter
1. VOUTILES (continued)
Bromomethane
Bromoform
Bromodi chl oromethane
Trichlorofluoromethane i
Dichlorodifluoromethane
Chlorodibromomethane
Tetrachloroethene
Toluene
Trichloroethene
Vinyl chloride
Acetone
2-butanone
Carbon disulfide
2-hexanone
4-methyl -2-pentanone
Styrene
Vinyl acetate
Total xylenes
Service
Water
G
1755
S20
8/29/84
ug/1
(ppb)
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
2A
ND/ :.
ND/ :. ™
ND/ 1
ND/:.O
ND/10
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
Ash
Pit
G
0211
84ER08
5>12
8/29/84
ug/1
(ppb)
ND/ 1
ND/ 1
ND/ .
ND/ .
ND/ ,
ND/ :.
ND/
ND/
ND/
ND/ :
:.7A*
ND/10
ND/ I
, ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ .
Ash
Pit
G
1235
S13
8/29/84
ug/1
(ppb)
ND/ 1
iND/ .
ND/ .
ND/ .
ND/ ,
ND/ .
ND/
ND/
ND/
ND/
ND/10
' "WI 0
ND/ 1
N£/ \
ND/ 1
ND/ :.
ND/ 1
ND/ 1
Quench
... G
0143
S17
8/29/84
ug/1
(ppb)
3A
ND/ 1
ND/ .
ND/ .
ND/ .
ND/ .
ND/
ND/
ND/
ND/ :
12 A*
ND/10
ND/ 1
ND/ :.
ND/ .
ND/ :.
ND/ :.
ND/ :.
Quench
G
1136
S18
8/29/84
ug/1
(ppb)
ND/ .
ND/ 1
ND/ 1
ND/ 1
ND/ :.
ND/ :.
ND/ :.
ND/ :.
ND/ 1
ND/ 1
ND/10
hlb/io
ND/ 1
ND/ 1
ND/ 1
ND/ :.
ND/ :.
ND/ 1
ESP
G
0150
S27
8/29/84
ug/1
(ppb)
Kin/?n
ND/20
ND/20
ND/20
ND/20
ND/20
54A
2800
ND/20
ND/20
640A*
ND/200
NJ)/2Q__
ND/20
ND/20
300
ND/20
ND/20
ESP
(i
1136
S28
8/29/84
ug/1
(ppb)
7A
ND/ ,
NO/ ,
ND/ .
ND/ ,,
ND/ ,
ND/ .
ND/ :.
ND/ :.
ND/
1 A*
ND/10
NO/
ND/ :.
ND/ :.
NP/ ;
ND/ :
ND/
uemister
Venturi
G
0123
S32
8/29/84
ug/1
(ppb)
ND/
NO/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ :.
ND/ :.
ND/ .
39A*
ND/10
2A
1 ND/ 1 i
1 ND/ 1 1
ND/ , .
ND/ :.
ND/ :.
uemister
Venturi
1016
S33
8/29/84
ug/1
(ppb)
NP7
NPY .
ND/ ,, .
ND/
ND/ ,
ND/
ND/ , ..
ND/ ;
ND/ 1
ND/ 1
ND/10
ND/10
NPY 1
ND/ 1
I ND/ 1 1
. ND/ 1
ND/ 1
I ND/ 1
-------
scharger:
tuple Date:
U.S. ENVIRONMENTAL PROTECTION AGENCY
REGION V
EASTERN DISTRICT OFFICE
Sample Type;
Dow Chemical Incinerator Wastewater Streams
8 C-8 hour flow proportioned composite
24C-24 hour flow proportioned composite
EVC-Equal volume composite
G-Grab
Sample Type
Time
Sample Number 84ER08
Date
Parameter
Service
Water
G
1755
84ER06
S20
8/29/84
ug/1
(ppb)
Ash
Pit
Comp.
1356-
1235
SIS
8/28-
29/84
ug/1
(ppb)
II. ACID AND BASE NEUTRAL POL.UTANTS (continued
Butyl benzyl phthalate
DT-n-butyl phthalate
Di-n-octyl phthalate
Di ethyl phtialate
Dimethyl phthalate
Benzol a}anthracene
Benzo(a)pyrene
Benzo(b & kjfluoranthene
Benzol k ) f 1 uoranthene
Chrysene
Acenaphthylene
Anthracene
Benzol ghi)perylene
Fluorene
Phenanthrene
Dibenzo( a ,h) anthracene
Indeno( 1 ,2 ,3-cd)pyrene
Pyrene
Aniline
Benzyl alcohol
4-chloroaniline
Dibenzofuran
ND/ 2
2A
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
NO/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ *
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
Mb/ 2
ND/ 2
ND/ 2
ND/ 2
Quench
Comp.
1319-
1136
S26
8/28-
29/84
ug/1
(ppb)
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ESP
Comp.
1330-
1136
S30
8/28-
29/84
ug/1
(ppb)
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
Demister
Venturi
Comp.
1300-
1016
S35
8/28-
29/84
ug/1
(ppb)
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
NO/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
-------
scharger:
mple Date;
U.S. ENVIRONMENTAL PROTECTION AGENCY
REGION V
EASTERN DISTRICT OFFICE
Dow Chemical Incinerator Wastewater Streams
Sample Type:
8 C-8 hour flow proportioned composite
24C-24 hour flow proportioned composite
EVC-Equal volume composite
G-Grab
Sample Type
Time
Sample Number 84ER08'"
Date
Parameter
11. ACID AND BASE NEUTRAL POL"
2-ch1oronaphthalene
1 ,2-dlchlorobenzene
1 ,3-dlchlorobenzene
1 ,4-dlchlorobenzene
3,3*-d1chlorobenz1d1ne
2,4-dlnltrotoluene
2,6-dlnitrotoluene
1 ,2-dlphenylhydrazlne
Fluoranthene
4-chlorophenyl phenyl ether
4-bromo
B1s(2-c
p icnyl p lenyl ether
ilorolsopropyl ) ether
Bl s( 2-chloroethbxy )me thane
Hexachlorobutadlene
Hexachl orocycl opentadlene
Isophorone
Napithalene
Nitrobenzene
N-nltrosodlmethylamlne
N-nltrosodlphenylamlne
N-nltrosodl
Bis 2-ethyl
prop yamine
lexy Jphthalate
Service
Water
'G
1755
84ER06
520 '
8/29/84
ug/1
(ppb)
Ash
Pit
Comp .
1356-
1235
$15
8/28-
29/84
ug/1
(ppb)
UTANTS continued
ND/ 2
11A
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
i KID/ 2
MD/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
NO/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
Quench
Comp.
1319-
1136
520
8/28-
29/84
ug/1
(ppb)
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
Nb/ 2
ND/ 2
ND/ 2
ND/ 2
, ND/ 2
i ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ESP
Comp.
1330-
1136
1 $30
8/28-
29/84
ug/1
(ppb)
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
Demister
Venturi
Comp.
1300-
1016
S3b
8/28-
29/84
ug/1
(ppb)
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
Kin/ ?
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
-------
scharger:
mple Date;
U.S. ENVIRONMENTAL PROTECTION AGENCY
REGION V
EASTERN DISTRICT OFFICE
Dow Chemical Incinerator Wastewater Streams
Sample Type;
8 C-8 hour flow proportioned composite
24C-24 hour flow proportioned composite
EYC-Equal volume composite
G-Grab
Sample Type
Time
Sample Number 84ER08
Date
Parameter
III. PCB/PESTICIDE POLLUTANTS
Aldrin
Dieldrln
Chlordane
4, 4 '-DDT
4, 4 '-DDE
4, 4 '-ODD
Alpha-endosulfan
Beta-endosulfan
Endosulfan sulfate
Endrin
Endrin aldehyde
Heptachlor
Heptachlor epoxlde
Alpha-BHC
Beta-BHC
Gamma-BHC
Delta-BHC
PCB-1242
PCB-1254
PCB-1221
PCB-1232
PCB-1248
PCB-1H60
PCB-1016
Toxaphene
Service
Water
G
1755
84ER06
S20
8/29/84
ug/1
(ppb)
ND/0.1
ND/0.1
ND/1.0
NO/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.5
ND/0.5
ND/0.5
ND/0.5
ND/1.0
ND/1.0
ND/1.0
ND/1.0
ND/1.0
ND/1.0
ND/1.0
ND/1.0
Ash
Pit
Comp.
1356-
1235
S15
8/28-
29/84
ug/1
(ppb)
ND/0.1
ND/0.1
ND/1.0
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/1.0
ND/1.0
ND/1.0
ND/1.0
ND/1.0
ND/1.0
ND/1.0
ND/1.0
Quench
Comp.
1319-
1136
S20
8/28-
29/84
ug/1
(ppb)
ND/0.1
ND/0.1
ND/1.0
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/1.0
ND/1.0
ND/1.0
ND/1.0
ND/1.0
ND/1.0
ND/1.0
ND/1.0
ESP
Comp.
1330-
1136
S30
8/28-
29/84
ug/1
(ppb)
ND/0.1
ND/0.1
ND/1.0
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/1.0
ND/1.0
ND/1.0
ND/1.0
ND/1.0
ND/1.0
ND/1.0
ND/1.0
Demister
Venturi
Comp.
1300-
1016
S35
8/28-
29/84
ug/1
(ppb)
ND/0.1
ND/0.1
ND/1.0
ND/0 . 1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.5
ND/0.1
ND/0.5
ND/0.5
ND/0.5
ND/0.5
ND/1.0
ND/1.0
ND/1.0
ND/1.0
ND/1.0
ND/1.0
ND/1.0
ND/1.0
-------
scharger:
nple Date:
U.S. ENVIRONMENTAL PROTECTION AGENCY
REGION V
EASTERN DISTRICT OFFICE
Dow Chemical Incinerator Wastewater Streams
Sample Type: 8 C-8 hour flow proportioned composite
24C-24 hour flow proportioned composite
EVC-Equal volume composite
G-Grab
Sample Type
Time
Sample Number 84LKU8
Date
Parameter
II. ACID AND BASE NEUTRAL POL
2 -methyl naphtha! ene
2-nitroani line
3-nltroaniline
4-nitroanlline
Service
Water
G
1755
84ER06
b^U '
8/29/84
ug/1
(ppb)
Ash
Pit
Comp .
1356-
1235
bib
8/28-
29/84
ug/1
(ppb)
UTANTS (continued
NIP/ 2
ND/ 2
NIP/ 2
ND/ 2
ND/ 2
, ND/ 2
, ND/ 2
ND/ 2
Quench
Comp.
1319-
1136
— "-SJttJ
8/28-
29/84
ug/1
(ppb)
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ESP
Comp.
1330-
1136
bJU
8/28-
29/84
ug/1
(ppb)
ND/ 2
ND/ 2
ND/ 2
ND/ 2
Demister
Venturi
Comp.
1300-
1016
bJ5
8/28-
29/84
ug/1
(ppb)
ND/ 2
ND/ 2
NO/ 2
ND/ 2
-------
scharger:
,mple Date:
U.S. ENVIRONMENTAL PROTECTION AGENCY
REGION Y
EASTERN DISTRICT OFFICE
Dow Chemical Incinerator Wastewater Streams
Sample Type:
8 C-8 hour flow proportioned composite
24C-24 hour flow proportioned composite
EYC-Equal volume composite
G-Grab
Sample Type
Time
Sample Number 84ER08
Date
Parameter
V. DIOXINS AND FURANS
2378-TCDD
Total Tetra CDDs
Total Penta CDDs
Total Hexa CDDs
Total Hepta CDDs
OCDD
Z378-TCDF
Total Tetra CDFs
Total Penta CDFs
Total Hexa CDFs
Total Hepta CDFs
OCDF
Service
Water
G
1755
84ER06
S20
8/29/84
ppt
ND/1.053
64.2
8.05
2.24
13.9
97.5
1.03
1143
11.8
9.69
25.9
34.2
Ash
Pit
Comp.
1356-
1235
S15
8/28-
29/84
ppt
ND/.031
0.642
ND/.028
ND/.034
ND/.514
6.02
ND/.021
14.5
ND/.040
ND/.033
ND/.250
1.97
Quench
Comp.
1319-
1136
S20
8/28-
29/84
PPt
ND/.561
27.2
ND/.382
ND/.308
6.72
41.7
0.419
536
3.09
5.17
12.9
14.9
ESP
Comp.
1330-
1136
S30
8/28-
29/84
PPt
ND/.396
15.0
1.33
ND/.094
0.719
3.65
ND/.183
230
1.34
0.224
1.19
1.31
Demister
Venturi
Comp.
1300-
1016
S35
8/28-
29/84
ppt
ND/.073
ND/.050
ND/.221
ND/.072
0.389
1.87
ND/.217
KID/. 148-
ND/.201
1.09
0.776
2.98
-------
scharger:
mple Date:
U.S. EMVIRONMENTAL PROTECTION AGENCY
REGION V
EASTERN DISTRICT OFFICE
Dow Chemical Incinerator Wastewater Streams
Sample Type: 8 C-8 hour flow proportioned composite
24C-24 hour flow proportioned composite
EVC-Equal volume composite
G-Grab
Sample Type
Time
Sample Number 84ER08
Date
Parameter
IV. METALS
Aluminum
Antimony
Arsenic
Barium
Beryllium
Cadmium
Chromium
Cobalt
Copper
Iron
Lead
Manganese
Mercury
Nickel
Selenium
Silver
Thallium
Tin
Vanadium
Zinc
Service
Water
G
1755
84ER06
$20
8/29/84
ug/1
(ppb)
149C
42
NO/ 8
83
ND/ 1
8.3
25
MD/10
275
3480C
16
903
0.39
116
ND/ 2
ND/ 3
ND/ 2
ND/ B
ND/ 4
764C
Ash
Pit
Comp.
1356-
1235
S15
8/28-
29/84
ug/1
(ppb)
1700C
34
12
114
ND/ 1
3.3
20
ND/10
522
3970C
125
199
0.63
16
ND/ 2
3
ND/ 2
ND/ B
7
895C
Quench
Comp.
1319-
1136
520
8/28-
29/84
ug/1
(ppb)
4370C
125
23
190
ND/ 5
25
55
ND/50
1740
4010C
1060
1040
3.5
140
ND/ 2
ND/15
ND/ 2
ND/100
ND/20
7050C
ESP
Comp.
1330-
1136
530
8/28-
29/84
ug/1
(ppb)
87C
34
9.9
43
ND/ 1
9.8
9
Nb/:.0
963
683C
618
66
2.7
ND/15
ND/ 2
3
ND/ 2
ND/ B
ND/ 4
3200C
Demister
Venturi
Comp.
1300-
1016
S3b
8/28-
29/84
ug/1
(ppb)
215C
124
16
90
ND/ 5
16
44
ND/50
1900
1420C
935
835
0.93
110
ND/ 2
ND/15
ND/ 2
ND/100
ND/20
4890C
-------
Dow Chemical Incinerator Wastewater Streams
NOTES:
1. * = Presence of compound may be due to sample bottle preparation and/or laboratory
contamination. Compound was present in blank sample. Methylene chloride is used as
a cleaning agent for sample bottles. Phthalate compounds are components of certain
plastics and are widespread in the environment at low levels.
2. A Detected below quantitation limit (quantisation limit is 10 x detection limit).
3. C = Blank corrected.
4. NA = Not analyzed.
5. ND = Compound was analyzed for but not detected. Value reported is the detection limit.
6. ND/ B = Not detected due to blank.
7. ug/1 = micrograrns per liter.
8. mg/1 = milligrams per liter.
9. ppb = parts per billion.
10. ppm = parts per million.
11. ppt = parts per trillion.
-------
;charger:
iple Date:
U.S. ENVIRONMENTAL PROTECTION AGENCY
REGION V
EASTERN DISTRICT OFFICE
Sample Type;
Dow Chemical Incinerator Wastewater Streams
8 C-8 hour flow proportioned composite
24C-24 hour flow proportioned composite
EYC-Equal volume composite
G-Grab
Sample Type
Time
Sample Number
Date
84ER08
Parameter
VI. OTHER PARAMETERS
Total Dissolved
To±al SiisoendeC
Rf)Dc
MH?
Solids
i Solids
TKN
To_tal P heno 1 i C5
Service
Water
G
1755
84ER06
S20
8/29/84
mg/1
6994
52
6.99
1.87
0.370
2.80
0.14
Ash
Pit
Comp.
1356-
1235
SIS
8/28-
29/84
mg/1
1740
82
ND/ 6
0.282
0.260
0.55
0.30
Quench
Comp.
1319-
1136
S20
8/28-
29/84
mg/1
8226
840
ND/ 6
0.764
1.10
1.63
0.40
ESP
Comp.
1330-
1136
§30
8/28-
29/84
mg/1
880
34
ND/ 6
0.200
ND/0.1
0.54
0.40
Demister
Venturi
Comp.
1300-
1016
§35
8/28-
29/84
mg/1
7196
276
ND/ 6
0.518
0.397
1.64
0.30
-------
scharger:
nple Date:
U.S. ENVIRONMENTAL PROTECTION AGENCY
REGION V
EASTERN DISTRICT OFFICE
Dow Chemical
Riverbank Revetment System Analyses
Sample Type: 8 C-8 hour flow proportioned composite
24C-24 hour flow proportioned composite
EVC-Equal volume composite
G-Grab
Sample Type
Time
Date
Sample Number
Parameter
I. VOLATILES (continued)
Bromomethane
Bromoform
Bromodichloromethane
Trichlorofluoromethane
Di chl orodi f 1 uoromethane
Chlorodibromomethane
Tetrachloroethene
oluene
Trichloroethene
Vinyl chloride
Acetone
2-butanone
Carbon disulfide
2-hexanone
4-methyl-2-pentanone
Styrene
Vinyl acetate
Total xylenes
Section
#1
G
0130
8/29/84
84ER07
S12
ug/1
(ppb)
ND/300
ND/300
ND/300
ND/300
ND/300
ND/300
520A
ND/300
ND/300
ND/300
Nb/3000
2500A
ND/300
ND/300
ND/300
ND/300
ND/300
ND/300
Section
#1
G
1125
8/29/84
84ER07
S13
ug/1
(ppb)
ND/100
ND/100
ND/100
ND/100
ND/100
ND/100
2300
220A
790A
590A
ND/1000
ND/1000
320A
ND/100
ND/100
ND/100
ND/100
ND/100
Section
#2
G
1600
8/29/84
84ER08
505
ug/1
(ppb)
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
2A
5A
24
19*
NO/10
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
Section
#3
G
1700
8/29/84
84ER08
S10
ug/1
(ppb)
ND/30
ND/30
ND/30
ND/30
ND/30
ND/30
220A
39A
37A
ND/30
ND/300
NO/300
ND/30
ND/30
ND/30
ND/30
ND/30
ND/30
Section
#4
G
1845
8/29/84
84ER07
S46
ug/1
(ppb)
ND/ 5
NO/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
22A
ND/ 5
ND/ 5
260A*
66A
NO/ 5
ND/ 5
35A
ND/ 5
ND/ 5
ND/ 5
Section
#1
Sediment
G
0955
10/23/84
85ER01
S07
mg/kg
(ppm)
ND/20
ND/10
ND/10
NA
NA
ND/10
6300
ND/10
38
ND/20
ND/20
ND/20
NDAO
ND/20
ND/20
ND/10
ND/20
ND/10
-------
scharger:
nple Date:
U.S. ENVIRONMENTAL PROTECTION AGENCY
REGION V
EASTERN DISTRICT OFFICE
Dow Chemical
Riverbank Revetment System Analyses
Sample Type: 8 C-8 hour flow proportioned composite
24C-24 hour flow proportioned composite
EVC-Equal volume composite
G-Grab
Sample Type
Time
Date
Sample Number
Parameter
I. VOLATlLES
Acrolein
Acrylonitrile
Benzene
Carbon tetrachloride
Chlorobenzene
1,2-dichloroethane
,1 ,1-trichloroethane
1 ,1-dichloroethane
1 ,1 ,2-trichloroethane
1 ,1 ,2 ,2-tetrachl oroethane
Chloroethane
Bis(chloromethyl ) ether
2-chloroethylvinyl ether
Chloroform
1,1-dichloroethene
Trans-1 ,2-dichloroethene
1 ,2-dichloropropane
Trans-1 ,3-dichloropropene
Cis-1 ,3-dichloropropene
Ethyl benzene
Methylene chloride
/* 1. 1 ~—,..., -.i-u~,...
Chloromethane
Section
#1
G
0130
8/29/84
84ER07
S12
ug/1
(ppb)
ND/3000
1 ND/3000
29QQA
ND/300
2800A
ND/300
ND/3QQ
ND/300
ND/30Q
ND/300
ND/300
ND/300
ND/300Q
1300A
ND/30Q
ND/300
ND/300
ND/300
ND'/300
ND/300
42000*
ND/300
Section
#1
— ~G •"
1125
8/29/84
84ER07
S13
ug/1
(ppb)
ND/100Q
ND/1QOO
2200
ND/100
3200
520A
ND/1QQ
ND/100
ND/1QO
ND/100
ND/100
ND/100
ND/10QO
3600
830A
540A
ND/IUU
ND/100
ND/100
ND/100
26000*
ND/IUU
Section
#2
G
1600
8/29/84
84ER08
505
ug/1
(ppb)
JO/JO
ND/10
6A
ND/ ..
NO/ •
ND/ 1
ND/ 1
[ ND/ .
ND/ .
, ND/ :.
ND/ :.
ND/ :.
ND/10
ND/ 1
ND/ 1
43
NU/ 1
ND/ :.
ND/ .
ND/ 1
13*
iirS / 1
NU/ 1
Section
#3
b
1700
8/29/84
84ER08
S10
ug/1
(ppb)
ND/300
ND/300
290
ND/30
2400
ND/30
ND/30
ND/30
ND/30
ND/30
ND/30
ND/30
N.D/300
ND/30
ND/30
110A
ii n yin
NU/oU
ND/30
ND/30
67A
230A*
kin /^n
NU/ oU
Section
#4
(3
1845
8/29/84
84ER07
S46
ug/1
(ppb)
ND/50
ND/50
60
NU/ b
270_
ND/ 5
ND/ 5
NO/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/50
12A
ND/ 5
7A
kin/ 5
NU/ 0
ND/ 5
ND/ 5
37A
32A*
wn / 5
nu/ o i
section
#1
Sediment
0955
10/23/84
85ER01
S07
mg/kg
(ppm)
NA
I NA 1
23.7
wn /1 n
NU/J-U
184
I ND/10 1
wn /in
NU/iU
ND/10
ND/10
ND/10
ND/20
NA
Nn/20
22
I ND/10 1
ND/10
wn/m
ND/10 ,
ND/10
ND/10
95*
Mn/2Q
,
-------
scharger:
nple Date:
U.S. ENVIRONMENTAL PROTECTION AGENCY
REGION V
EASTERN DISTRICT OFFICE
Dow Chemical
Riverbank Revetment System Analyses
Sample Type: 8 C-8 hour flow proportioned composite
24C-24 hour flow proportioned composite
EVC-Equal volume composite
G-Grab
, e Type
Time
Date
Sample
Number
Parameter
II. ACID
AND BASE NEUT
Section
#1
EVC
1420/112
5/28-29/8
84ER07
S15
ug/1
(ppb)
Section
#2
G
1600
8/29/84
84ER08
SOB
ug/1
(ppb)
RAL POLLUTANTS (continued
2-chloronaphthalene
1 ,2-dichlorobenzene
1 ,3-dichlorobenzene
1 ,4-dichlorobenzene
3,3'.-dichlorobenzidi
2,4-di
2,6-di
nitrotoluene
ni tro toluene
ne
1,2-diphenylhydrazine
luoranthcne
4-chloropheny] phenyl other
4-bromophenyl phenyl
isiZ-ch orolsopropy
ether
) ether
i s( 2-chl oroethoxy Jmethane
Hexachl
Hexachl
orobutadiene
rorocycl open tad iene
Isopnorone
Napnth£
""TniroKe
R— — — 9 1
Icne
nzene
-mtrosodimethylamine
- ni tro sod 1 phenyl ami ne
N-nitrosodi prop! y ami ne
Bisiz-etny hexyl Jphthalate
ND/40
810
ND/40
ND/40
ND/40
ND/40
ND/40
ND/40
ND/40
ND/40
ND/40
ND/40
ND/40
ND/40
ND/40
ND/40
ND/40
ND/40
ND/40
ND/40
ND/40
ND/40
ND/ 4
250
ND/ 4
600
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
21A
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
Section
#3
G
1700
8/29/84
84ER08
S10
ug/1
(ppb)
ND/20
2500
140A
3100
ND/20
ND/20
ND/20
ND/20
ND/20
ND/20
ND/20
ND/20
ND/20
ND/20
ND/20
ND/20
49A
ND/20
ND/20
ND/20
ND/20
ND/20
Section
#4
G
1845
8/29/84
84ER07
S46
ug/1
(ppb)
ND/ 2
54
14A
130
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
Sectior
#1
Sediment
G
0955
10/23/84
85ER01
S07
mg/kg
(ppm)
ND/20
1180
250
960
ND/40
ND/20
ND/20
NA
20J
ND/20
ND/20
ND/20
ND/20
5300
5300
ND/20
20J
ND/20
ND/20
ND/20
ND/20
ND/20
-------
.charger:
iple Date:
U.S. ENVIRONMENTAL PROTECTION AGENCY
REGION V
EASTERN DISTRICT OFFICE
Dow Chemical
Riverbank Revetment System Analyses
Sample Type: 8 C-8 hour flow proportioned composite
24C-24 hour flow proportioned composite
EVC-Equal volume composite
G-Grab
Sample Type
Time
Date £
Sample Number
Parameter
11. ACID AND BASE NEUTRAL POL
2 ,4 ,6-trichl orophenol
4-chl oro-3-methyl phenol
2-chl orophenol
2 ,4-dichlorophenol
2, 4-dimethyl phenol
2-nitrophenol
4-nitrophenol
2,4-dinitropheno
4 ,6-dinitro-2-methyl phenol
Pentachl orophenol
Phenol
Benzoic acid
2-methyl phenol
4-methyl phenol
2 ,4 ,5- trichl orophenol
Acenaphthene
Benzidine
1 ,2 ,4-trichl orobenzene
Hexachlorobenzene
Hexachloroethane
Bis( 2-chloroethyl ) ether
Section
#1
EVC
1420/1125
728-29/84
84ER07
S15
ug/1
(ppb)
UTAHTS
800
ND/40
1500
3500
ND/40
ND/40
ND/40
ND/40
ND/40
920
2700
ND/40
ND/40
230A
270A
NO/40
ND/40
67A
ND/40
ND/40
260A
Section
#2
G
1600
8/29/84
84ER08
SOS
ug/1
(ppb)
ND/ 4
ND/ 4
10A
16A
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
19A
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
Section
#3
G
1700
8/29/84
84ER08
S10
ug/1
(ppb)
ND/20
ND/20
ND/20
ND/20
ND/20
ND/20
ND/20
ND/20
ND/20
ND/20
ND/20
ND/20
ND/20
ND/20
ND/20
ND/20
ND/20
130A
ND/20
ND/20
ND/20
Section
#4
G
1845
8/29/84
84ER07
S46
ug/1
(ppb)
ND/ 2
ND/ 2
8A
55
ND/ 2
ND/ 2
ND/ 2
ND/ 2
NO/ 2
510
220
110
NO/ 2
11A
12A
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ ?
Section
#1
Sediment
G
0955
10/23/84
85ER01
S07
mg/kg
(ppm)
ND/20
ND/20
ND/20
42
ND/20
ND/20
ND/96
ND/96
ND/96
ND/96
25
ND/96
ND/20
ND/20
ND/96
ND/20
1 ND/96
940
1730
150
ND/20
-------
CASE i/'SAS 3: 3O63 LADORATORY: IT/WCTS SAMPLE #: E3451
CATE *£C'D: 08/16/84 CONTRACT #: 6582 V. MOISTURE: NA
CATA «eL£A£E AUTHORIZED BY:
ORGANICS ANALYSIS DATA SHEET
VOLATILE COMPOUNDS
SURROGATE SPIKE RECOVERIES
UNITS: UG/L
CCNC CONC
LAD ID COMPOUND SAMPLE SPIKED 7. RECOVERY
1,2-DICHLOROETHANE-D4 409. 50O. 82
30482N6 TOLUENE-DS 465. 50O. 93
4-BRDMOFLUOROBENZENE 481. 500. 96
# - ASTERISKED VALUES ARE OUTSIDE QC LIMITS NS - NOT SPIKED
* - RECOVERIES DUE TO DILUTIOM
* - RECOVERIES DUE TO MATRIX EFFECTS
TENTATIVELY IDENTIFIED COMPOUNDS
(J) CAS * COMPOUND MAMS SCAN fc FIT
}coo_ / io66-te-6' -r£)in&&iM£/4~A-i\}oL * / f8r- /
3&O
5 / /
7 / /
8 / /
9 / / / /
10 / / / /
11 / / / /
12 / / / /
13 / / : / /
14 / / / /
15 / / / /
16 / / / /
17 / / / /
10 / / / /
19 / / / /
20 / / / /
21 / / / /
22 / / / /
22 / / / /
24 / / / /
25 / / ; / /
J - CONC. QUANTITATED USING PEAK HEIGHT, ASSUMING A RESPONSE FACTOR OF 1.
-------
CASE */SAS *: 3068 LABORATORY: IT/WCTS
DATE REC'D: 08/16/84 CONTRACT #: 6582
DATA RELEASE AUTHORIZED BY:
SAMPLE f»: E8430
X MOISTURE: NA
ORGANICS^ANALVSIS DATA SHEET
BASE/NEUTRAL AND ACID COMPOUNDS
SURROGATE SPIKE RECOVERIES
UNITS: UG/L
LAB ID COMPOUND
PHENOL-D5
2-FLUOROPHENOL
30482F13 NITROBENZENE-OS
2-FLUOROBIPHENYL
2,4,6-TRIBROMOPHENOL
P-TERPHENYL-D14
CONC
SAMPLE
59.
56.
64.
83.
58.
25.
CONC
SPIKED
7. RECOVERY
* - ASTERISKED VALUES ARE OUTSIDE QC LIMITS
# - RECOVERIES DUE TO DILUTION
9 - RECOVERIES DUE TO MATRIX EFFECTS
104. 57
110. 51
105. 61
103. 81
102. 57
49. 51
NS - NOT SPIKED
2
3
4
5
6
7
8
9
10
11
12
13 !
14
15
16
17
18
19
20
21 !
22
23
24
25
J -
TENTATIVELY IDENTIFIED COMPOUNDS
CONC(J) CAS <* COMPOUND NAME
M.n
SCAN * FIT
/
50
_,_ t
/'
U A? o /tAt
^70
CONC. QUANTITATED USING PEAK HEIGHT, ASSUMING A RESPONSE FACTOR OF 1.
-------
CASE 3/3A<£: #: 3Oo8 LABORATORY: IT/WCTS
DATE RtIC'0 03/16/84 CONTRACT tf: 6582
D*TA RELEASE AU-.HORIZED 3Y:
SAMPLE *. E8430
~ MOISTURE: NA
DATA SHEET
VOLATILE COMPOUNDS
SURROGATE SPIKE RECOVERIES
UNITS: UG/L
LAB ID
S0492NS
COMPOUND
1,2-DICHLORGETHANE-D4
TOLUEMS-D8
4-uROMOFLUQRQBENZENE
CONC
SAMPLE
55.
46.
44.
CONC
SPIKED
50.
50.
50.
V. RECOVERY
110
92
S3
* - ASTERISKED VALUES Ar.E OUTSIDE QC LIMITS
# - RECOVERIES DUE TO DILUTION
RECOVERIES DUE TO MATRIX EFFECTS
NS - NOT SPIKED
* -
3
4
5
6
7
p
9
10
11
12
13
14
15
17
13
19
20
21
22
23
24
25
CGNC
-------
CASE tt/SAS #: 3O68 LABORATORY: IT/WCTS
DATE REC'D: O8/16/84 CONTRACT t»: 6582
DATA RELEASE AUTHORIZED BY:
SAMPLE #: E8449
V. MOISTURE: NA
&HER.05 SI
ORGANICS^ANALYSIS DATA SHEET
BASE/NEUTRAL AND ACID COMPOUNDS
SURROGATE SPIKE RECOVERIES
UNITS: UG/L
LAB ID COMPOUND
PHENOL-D5
2-FLUOROPHENOL
30482F21 NITROBENZENE-DS
2-FLUOROBIPHENYL
2,4,6-TRIBROMOPHENOL
P-TERPHENYL-D14
1
2
3
4
5
CONC
SAMPLE
56.
51.
90.
83.
60.
CONC
SPIKED
X RECOVERY
* - ASTERISKED VALUES ARE OUTSIDE QC LIMITS
# - RECOVERIES DUE TO DILUTION
* - RECOVERIES DUE TO MATRIX EFFECTS
104. 54
HO. 46
105. 86
103. 81
1O2. 59
49. 63
NS - NOT SPIKED
CONC(J)
if r-
TENTATIVELY IDENTIFIED COMPOUNDS
CAS # COMPOUND NAME
SCAN # FIT
o
"'fee
T fi.
.•52.Cs
_/
"/"
QUANTITATED USING PEAK HEIGHT, ASSUMING A RESPONSE FACTOR OF 1
-------
rA3£ «/5AS * 3C63 LABORATORY' IT/WCTS SAMPLE t»: EG4A9
PATE REC'D 03/16/34 CONTRACT it: i>532 'I. MOISTURE: r'A
DATA RELEASE AUTHORIZED DY: / * ^ &HERO5 S35
toC.fcuJEl.i-
CRGANICS ANALYSIS DATA SHEET
VOLATILE COMPOUNDS
SURROGATE SPIKE RECOVERIES
UNITS: UG/L
LAD ID
30482N9
COMPOUND
1,2-DICHLQROETHANE-D4
TOLUENE-D8
4-BROMOFLUORQ13ENZENE
CONC
SAMPLE
5190.
4990.
4640.
CGMC
SPIKED
5000.
5000.
5000.
'/I RECOVERY
104
100
93
•» - ASTERISKED VALUES ARE OUTSIDE QC LIMITS
# - RECOVERIES DUE TO DILUTION
* - _ RECOVERIES DUE TO MATRIX EFFECTS
NS - NOT SPIKED
CCNC(J)
CA
TENTATIVELY IDENTIFIED COMPOUNDS
COMPOUND NAME
SCAN
FIT
1
2
3
4
5
6
7
e
9
10
13
14
15
16
17
IB
1^
20
23
24
J - CCNC. QUANTITAFED USING PEAK HEIGHT, ASSUMING A RESPONSE FACTOR OF 1.
-------
LA2 HKME: CAL
QC REPORT NO.
ft- HIGH
HNHLYblb UHIH ahctI
CASE NO. 3385 SAMPLE NO. E84Q6,
LAB SAMPLE NO. L24881AB
THAT IDENTIFICATION IS CORRECT:
8- nODERdTE C- LOU D- SOLVENT irFURITY. SEE VOft
CflS*
COrPOUND NAME
I.
2.
3.
4.
5.
a.
?.
3.
183-98-7 BENZENE.CHLORO-
67-72-1 ETHANE.HEXACHLORO-
634-98-2 BENZENE.1.2.3.5-TETRACHLORO-
634-90-2 BENZENE.1.2.3,5-TETRACHLORO-
68d-93-5 BENZENE.PENTACHLQRO-
93-S6-3 BENZENE.1.l'-(OXVDIETHYLIDENE)
2142-25-2 BENZENE.1.4-DlChLORQ-2.5-8IS(T
10544-58-8 SULFUS.MOL.(S8)
SCAN
FRACTION NUMBER PURITY
A'BN 258 93?
ft/BN 568 952
A/8N 312 384
A/BN 855 863
AxBN 967 825
I) AXBN 1819 708
T flxBN 1728 ZC6
AxBN 1338 834
ESTIMATED
CONC.
J vqLL'E
^£. 1 UGxU
53.9 UG^G
116.6 UG/G
2E5.1 L'G/G
Qt.l UG/G
43.5 UG-'i:
£-.4 UG^'G
245 . 1 UG^G
COMPOUND
1. BENZENE.CHLORO-
2. ETHANE.HEXflCHLORO-
3. BENZENE. 1.2.3.5-TETRflCHLORO-
4. BENZENE.1.2,3.5-TETRflCHLORO-
J. BENZENE.PENTPCHLORO-
6. BENZENE.1.l'-(OXYDIETHYLIDENE)
7. BENZENE.1.4-DICHLORO-2.5-BIS(T
9. SLuFUR.MOL.(SB)
y
PROB^aiLITY
i. O i.
2.
CC 7SNTS
2. A
3. A
4. /V
5. A
6. ^
7. ft
8. A
4.'
5.
6.
7.
8.
-------
ORCANICS ANALYSIS DATA SHEET 8 5 E to \ SO7
i NAME" CAL CASE NO. 3385 SAMPLE NO. E8486
REPORT NO. /9 LAB SAMPLE NO. L24802VA
=
-------
CASE &/S.V3 <*: 3O69 LABORATORY IT/WCTS
DATE REC'D: O3/31/84 CONTRACT tt: 6582
DATA RELEASE AUTHORIZED EY:
SAMPLE #: E9458
7. MOISTURE: NA
ORGANICS
EASE/NEUT
ilS DATA SHEET
"AND ACID COMPOUNDS
SURROGATE SPIKE RECOVERIES
UNITS: UG/L
LAB ID
30614F6
COMPOUND
ro p r_
- y-5*
NITROEENZENE-D5
2-FLUORQB IPHENYL
2, 4, 6-TRIBROMOPHENOL
P-TERPHENYL-D14
- ASTERISKED VALUES ARE OUTSIDE QC LIMITS
CONC
SAMPLE
63.
68.
85.
74.
64.
39.
CONC
SPIKED
105.
11O.
106.
104.
103.
50.
RECOVERY
60
62
80
71
62
78
NS - NOT SPIKED
ft -
1
2
3
4
5
6
7
6
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
to
10
50
7c
Jt
70
RECOVERIES DUE TO DILUTION
RECOVERIES DUE TO MATRIX EFFECTS
TENTATIVELY IDENTIFIED COMPOUNDS
CONC(J) CAS # COMPOUND NAME
SCAN # FIT
3*76- / °lf?
foo-r-v /
S//
6/4 ^
Cf«=j
C f
• .? -e-f
'/50
-5/0 -5 1-
i i • - h
• f> ,\t /i.
- CONC. QUANTITATED USING PEAK HEIGHT, ASSUMING A RESPONSE FACTOR OF 1.
-------
CASE 4t/£A5 «: 3069 LABORATORY: IT/WCTS
DATE REC'D: 08/31/34 CONTRACT #: 6582
DATA RELEASE AUTHORIZED BY:
SAMPLE #: E3/J50
7. MOISTURE: NA
ORGANICS ANALYSIS DATA SHEET
VOLATILE COMPOUNDS
SURROGATE SPIKE RECOVERIES
UNITS: UG/L
LAB ID COMPOUND
1.2-DICHLOROETHANE-D4
3O614N21 TOLUENE-D8
4-BROMOFLUORQBENZENE
CONC
SAMPLE
237.
252.
241.
CONC
SPIKED
250.
250.
250.
7. RECOVERY
95
101
96
* - ASTERISKED VALUES ARE OUTSIDE QC LIMITS
ft - RECOVERIES DUE TO DILUTION
* - RECOVERIES DUE TO MATRIX EFFECTS
NS - NOT SPIKED
1
2
3
4
5
6
7
8
9
1O
11
12
13
16
17
18
19
20
21
22
23
24
TENTATIVELY IDENTIFIED COMPOUNDS
CONC(J) CAS # COMPOUND NAME SCAN # FIT
/ / NO>IE FOUND / /
J - CONC. QUANTITATED USING PEAK HEIGHT, ASSUMING A RESPONSE FACTOR OF 1.
-------
»CASE */SAS #: 2O69 LABORATORY: IT/WCTS
DATE REC'D: 03/31/84 CONTRACT *: 6582
DATA RELEASE AUTHORIZED BY:
*** "1.
SAMPLE #: E8455
7. MOISTURE: NA
SIS DATA SHEET
AND ACID COMPOUNDS
ORGAN res
BASE/NEU
i
SURROGATE SPIKE RECOVERIES
UNITS: UG/L
LAB ID
COMPOUND
CONC
SAMPLE
3\
H
^
SO
NITROBENZENE-OS
2-FLUQROB IPHENYL
2, 4, 6-TR I BROMOPHENOL
P-TERPHENYL-D 1 4
* - ASTERISKED VALUES ARE OUTSIDE QC LIMITS
* - RECOVERIES DUE TO DILUTION
* - RECOVERIES DUE TO MATRIX EFFECTS
CONC
SPIKED
104.
110.
105.
104.
102.
50.
NS - NOT SPIKED
'/. RECOVERY
2
3
4
5
6
7
8
9
10
11
12
13
14
15
17
18
IS?
20
21
24
25
CONC(J)
CAS ft
TENTATIVELY IDENTIFIED COMPOUNDS
COMPOUND NAME
SCAN
FIT
/ /oy-^-7
J -~CONC. QUANTITATED USING PEAK HEIGHT, ASSUMING A RESPONSE FACTOR OF 1
-------
OA^E */SAS #: 3069 LABORATORY: IT/WCTS SAMPLE #: E8455
DATE REC'D. 08/31/34 CONTRACT *: 6532 7. MOISTURE: NA
DATA RELEASE AUTHORIZED BY:
ORGANICS ANALYSIS DATA SHEET
VOLATILE COMPOUNDS
SURROGATE SPIKE RECOVERIES
UNITS: UG/L
CONC CONC
LAB ID COMPOUND SAMPLE SPIKED 7. RECOVERY
1,2-DICHLOROETHANE-D4 1230. 1250. 98
30614N32 TOLUENE-D9 1330. 1250. 106
4-BROMOFLUCROBENZENE 1460. 1250. 117
* - ASTERISKED VALUES ARE OUTSIDE QC LIMITS NS - NOT SPIKED
ft - RECOVERIES DUE TO DILUTION
•» - RECOVERIES DUE TO MATRIX EFFECTS
TENTATIVELY IDENTIFIED COMPOUNDS
CONC(J) CAS # COMPOUND NAME SCAN tt FIT
j f j NONE FOUND / /
3 / / / /
4 / / / /
5 / / / /
6 / / / /
7 / / _/ /
8 / / / /
9 / / / /
10 / / / /
11 / / __/ /
12 / / __/ /
13 / / / /
14 / / / /
15 / / __/ /
16 / / / /
17 / / / /
IB / / / /
19 / / / /
20 / / __/ /
21 / / __/ /
22 / / / /
23 / / / /
24 / / / /
2f> / / / /
J - CONC. QUANTITATED USING PEAK HEIGHT, ASSUMING A RESPONSE FACTOR OF 1.
-------
CASE <*/SAS *: 3069 LABORATORY: IT/WCTS
DATE REC'D: 08/31/34 CONTRACT tt: 65B2
DATA RELEASE AUTHORIZED BY:
SAMPLE «*: E9100
7. MOISTURE: NA
CRGANICB-A*NALYSIS DATA SHEET
EASE/NEUTRAL AND ACID COMPOUNDS
SURROGATE SPIKE RECOVERIES
UNITS: UG/L
LAB ID
30614F24
COMPOUND
* -
NITROSENZENE-D5
2-FLUORQBIPHENYL
2, 4, 6-TRIEROMOPHENOL
P-TERPHENYL-D14
CONC
SAMPLE
66.
74.
88.
77.
77.
CONC
SPIKED
104.
110.
1O5.
103.
1O2.
49.
7. RECOVERY
63
67
84
75
75
65
* - ASTERISKED VALUES ARE OUTSIDE QC LIMITS
$ - RECOVERIES DUE TO DILUTION
RECOVERIES DUE TO MATRIX EFFECTS
NS - NOT SPIKED
CONC(J)
TENTATIVELY IDENTIFIED COMPOUNDS
CAS # COMPOUND NAME
SCAN # FIT
1
2
3
4
5
6
7
8 / / / /
9 / / / /
10 / / / /
11 / / /_____/
12. / / / /
13 / / . / /
14 / / / /
15 . / / / /
16 / / / /
17 / / ___/ /
18 / / / /
19 / / / /
20 / /_ / ./
21 /___ / / /
22 / / / /
22 / / /_ /
24 / / /. /
25 / / i / /
J - CONC. QUANTITATED USING PEAK HEIGHT, ASSUMING A RESPONSE FACTOR OF 1.
/CD
507
300
/ —
/ /OI-S1-8
30
//Si"
-------
CASE #/SAS #: 3069 LABORATORY:
DATE REC'D: 03/31/84 CONTRACT #:
DATA RELEASE AUTHORIZED BY:
IT/WCTS
6582
SAMPLE *»: E9092
7. MOISTURE: NA
ORGAN PCS rtNACYSIS DATA SHEET
VOLATILE COMPOUNDS
SURROGATE SPIKE RECOVERIES
UNITS: UG/L
LAB ID COMPOUND
1,2-DICHLOROETHANE-D4
30614N23 TOLUENE-D9
4-BROMOFLUOROBENZENE
CONC
SAMPLE
50OO.
4710.
4890.
CONC
SPIKED
300O.
30OO.
•/. RECOVERY J
*C
100
* - ASTERISKED VALUES ARE OUTSIDE QC LIMITS
# - RECOVERIES DUE TO DILUTION
* - RECOVERIES DUE TO MATRIX EFFECTS
NS - NOT SPIKED
TENTATIVELY IDENTIFIED COMPOUNDS
CONC(J) CAS tt COMPOUND NAME SCAN # FIT
--2 -
7 CCO /
3 /
27
3
4 / / " / /
5 / / / /
6 / / / /
7 / / ~/ /
8 / / / /
9 / / / /
10 / / ~/ /
11 / / """/ /
12 / / / /
13 / / / '/
14 / / / /
15 / / / /
16 / / / ~j
17 / / ""••/ /
18 / / / /
19 / / / /
20 / / ""/' /
21 / / __ / /
22 / / / /
23 / / / /
24 / / / /
25 / / / ~~/
J - CONC. QUANTITATED USING PEAK HEIGHT, ASSUMING A RESPONSE FACTOR OF 1
-------
CASE */SAS #: 3069 LABORATORY: IT/WCTS
DATE REC'D: 08/31/34 CONTRACT #: 6532
DATA RELEASE AUTHORIZED BY:
SAMPLE #: E9100
7. MOISTURE: NA
ORGANICS ANJ^^S^T-TJATA SHEET
VOLATILE COMPOUNDS
SURROGATE SPIKE RECOVERIES
UNITS: UG/L
SECTION
LAB ID COMPOUND
1,2-DICHLCHOETHANE-D4
3O614N31 TCHJENE-D3
4-BROMOFL.UOROBENZENE
* - ASTERISKED VALUES ARE OUTSIDE QC LIMITS
# - RECOVERIES DUE TO DILUTION
$ - RECOVERIES DUE TO MATRIX EFFECTS
CONC
SAMPLE
47.
55.
DS.
CONC
SP 1 KED
50.
50.
50.
7. RECOVERY
94
110
116
NS - MOT SPIKED
CONC(J)
TENTATIVELY IDENTIFIED COMPOUNDS
CAS # COMPOUND NAME
SCAN 3 FIT
3
4
5
6
7
8
9
10
11
12
13
16
17
18
19
20
21
22
23
24
25
6-0
\CT>
J - CONC. QUANTITATED USING PEAK HEIGHT, ASSUMING A RESPONSE FACTOR OF 1.
-------
CASE */SAS K: 3O69 LABORATORY. IT/WCTS
DATE REC'D: O8/3J/S4 CONTRACT *: 6582
DATA RELEASE AUTHORIZED BY:
• v . — — ,.
SAMPLE »: E9O92
% MOISTURE: NA
QRGANICS ANALYSIS DATA SHEET
BASE/NEUTRAL AND ACID COMPOUNDS
SURROGATE SPIKE RECOVERIES
UNITS: UG/L
sE
-------
Tentatively Identified Compounds
-------
charger:
pie Date:
U.S. ENVIRONMENTAL PROTECTION AGENCY
REGION V
EASTERN DISTRICT OFFICE
Dow Chemical Landfill Analyses
Sample Type: 8 C-8 hour flow proportioned composite
24C-24 hour flow proportioned composite
EVC-Equal volume composite
G-Grab
Salzbura Salzbura Posyvle.
Sample Type
Time
Sample Number
Date
Parameter
VI. INORGANICS
Chloride
Sul fate
Fl uoride
Bromide
Iodide
Rockwell
De-
waterinc
G
0830
S35
8/14/84
mg/1
2880
69
0.21
ND/ 2
2.3
Landfill
Cells
9-10
G
1205
S36
8/14/84
mg/1
720
184
0.32
6.8
19.8
Landfill
Cells
3-5
G
1330
S37
8/14/84
mg/1
3460
209
0.35
ND/ 2
2.4
Posyvle.
Landfill
NE Sump
G
1520
S38
8/14/84
mg/1
7500
1.7
0.17
ND/ 2
5.2
Landfill
Purge
Well 28
G
1615,
S39
8/14/84
mg/1
1260
47
0.125
ND/ 2
2.8
-------
Dow Chemical Landfill Analyses
NOTES:
1. ND = Compound was analyzed for but not detected. Value reported is the detection limit.
2. NA = Not analyzed.
3. * Presence of compound may be due to sample bottle preparation, field and/or labora-
tory contamination. Methylene chloride is used as a cleaning agent for sample
bottles. Phthalate compounds are components of certain plastics and are widespread
in the environment at low levels.
4. A Detected below quantisation limit (quantisation limit is 10 x dectection limit).
5. mg/1 = milligram per liter.
6. ug/1 = microgram per liter.
7. ug/kg = micrograrn per kilogram.
8. mg/kg = milligram per kilogram.
9. ppb = parts per billion.
10. ppm = parts per million.
11. ng/g = nanogram per gram.
12. pg/1 = picogram per liter.
13. ppq = parts per quadrillion.
-------
scharger:
nple Date:
U.S. ENVIRONMENTAL PROTECTION AGENCY
REGION V
EASTERN DISTRICT OFFICE
Dow Chemical Landfill Analyses
Salzburg Salzburg
Sample Type;
Posyvle.
8 C-8 hour flow proportloneu composite
24C-24 hour flow proportioned composite
EVC-Equal volume composite
G-Grab
Sample Type
Time
Sample Number 84ER05
Date
Parameter
IV. METALS
Aluminum
Antimony
Arsenic
Barium
Beryl 1 1 urn
Cadmium
Chromium
Cobalt
Copper
Iron
Lead
Manganese
Mercury
Nickel
Selenium
Silver
Thallium
Tin
Vanadium
Zinc
Rockwel 1
De-
watering
G
0830
S35
8/14/84'
ug/1
(ppb)
ND/100
23
ND/10
450
6
ND/ 1
ND/10
ND/50
ND/50
58900
18
2550
ND/.2
ND/40
ND/ 2
ND/10
ND/10
ND/20
ND/200
3550
Landfill
Cells
9-10
G
1205
S36
8/14/84
ug/1
(ppb)
270
31
ND/10
270
7
ND/ 1
ND/10
ND/50
ND/50
4760
9.0
903
ND/.2
53
ND/ 2
ND/10
ND/10
ND/20
ND/200
890
Landtl 1 1
Cells
3-5
G
1330
S37
8/14/84
ug/1
(ppb)
590
ND/20
ND/10
450
ND/ 5
1.6
40
ND/50
31?0
180
33
ND/10
ND/.2
380
ND/ 2
ND/10
ND/10
25
ND/200
86
posyvie.
Landfill
NE Sump
G
1520
S38
8/14/84
ug/1
(ppb)
ND/100
ND/20
11
2160
8
ND/ 1
10
ND/50
73
26930
89
141Q
ND/.2
ND/40
ND/ 2
ND/10
ND/10
ND/20
ND/200
48
Landfill
Purge
Well 28
G
1615
S39
8/14/84
ug/1
(ppb)
ND/100
ND/20
ND/10
970
10
ND/ 1
ND/10
ND/50
Kin /so
9110
39
375
ND/.2
ND/40
ND/ 2
ND/10
ND/10
ND/20
ND/200
22
-------
scharger:
mple Date:
U.S. ENVIRONMENTAL PROTECTION AGENCY
REGION V
EASTERN DISTRICT OFFICE
Dow Chemical Landfill Analyses
Sample Type: 8 C-8 hour flow proportioned composite
24C-24 hour flow proportioned composite
EVC-Equal volume composite
G-Grab
Sample Type
Time
Sample Number 85ER03
Sample Date
Parameter
V. DIOXINS AND FURANS
2378-TCDD
Total Tetra CDDs
Total Penta CDDs
Total Hexa CDDs
Total Hepta CDDs
OCDD
2378-TCDF
Total Tetra CDFs
Total Penta CDFs
Total Hexa CDFs
Total Hepta CDFs
OCDF
Rockwell
De-
wateri ng
G
S08d
12/4/84
pg/i
(ppq)
NCb
Rockwell
De-
waterinq
G
SOS
12/4/84
[rerun)
pg/i
(ppq)
270<- '
.-jqi 4"m y.
Landfill
Cells
9-10
G
S09
12/4/84
pg/i
(ppq)
ND/82d
jg i .t-uui vj
Landfill
Cells
9-10
G
S09
12/4/84
(rerun)
pg/i
(ppq)
ND/10
~?" I y-um y
Landfill
Cells
3-5
G
S10
12/4/84
pg/i
(DPQ)
ND/52a
-'" ' t-uiii y
Landfill
Cells
3-5
G
S10
12/4/84
(rerun)
pg/i
(ppq )
llc
Posyvle.
Landfill
NF Sump
G
. Sll
12/4/84
pg/i
ND/17a
Posyvle.
Landfill
NF. Sump
G
Sll
12/4/84
(rerun)
pg/i
(ppq.) —
ND/ 6C
Landfill
Purge
Well ?R
G
12/4/84
pg/i
(ppq) .. -
ND/12
a = High background sample will be reanalyzed following cleanup on Carbopak C/Celite.
b = Determination for 2378-isorner will require analysis on a 60 m SP-2330 column.
c = Data for 2378-TCDD and 2378-TCDF was generated 3/1/85 using an Gometer SP-2330 column.
d = Original sample extract could not be concentrated further than 5 mL. Required
additional cleanup using a Carbopack C/Celite column.
Other PCDD/PCDF considered not valid due to laboratory contamination in contract lab
(Midwest Research Institute).
-------
scharger:
nple Date:
U.S. ENVIRONMENTAL PROTECTION AGENCY
REGION V
EASTERN DISTRICT OFFICE
Dow Chemical Landfill Analyses
Sample Type;
8 C-8 hour flow proportioned composite
24C-24 hour flow proportioned composite
EVC-Equal volume composite
G-Grab
Salzburq
Sample Type
Time
Sample Number 84ER05
Date
Parameter
II. ACID AND BASE NEUTRAL POL
2-methyl naphthal ene
2-nitroaniline
3-nitroaniline
4-nitroaniline
Rockwell
De-
waterinc
G
0830
S35
8/14/84
ug/1
(ppb)
Landfill
Cells
9-10
G
1205
S36
8/14/84
ug/1
(ppb)
.UTANTS (continued
460
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
Salzburq Posyvle.
Landfill
Cells
3-5
G
1330
S37
8/14/84
ug/1
(ppb)
ND/400
ND/400
ND/400
ND/400
Posyvle.
Landfill
NE Sump
G
1520
S38
8/14/84
ug/1
(ppb)
ND/80
ND/80
ND/80
ND/80
Landfill
Purge
Well 28
G
1615
S39
8/14/84
ug/1
(ppb)
ND/ 4
ND/ 4
ND/ 4
ND/ 4
-------
•scharger:
imple Date:
U.S. ENVIRONMENTAL PROTECTION AGENCY
REGION V
EASTERN DISTRICT OFFICE
Dow Chemical Landfill Analyses
Sample Type: 8 C-8 hour flow proportioned composite
24C-24 hour flow proportioned composite
EVC-Equal volume composite
G-Grab
<;al7hura Sal7hurci Poswle. _ - .._ _
Sample Type
Time
Sample Number • 84ER05
Date
Parameter
III. PCB/PESTICIDE POLLUTANTS
Aldrin
Dieldrin
Chlordane ,
4, 4 '-DDT
4, 4 '-DDE
4, 4 '-ODD
Alpha-endosulfan
Beta-endosulfan
Endosulfan sulfate
Endrin
Endrin aldehyde
Heptachlor
Heptachlor epoxide
Alpha-BHC
Beta-BHC
Gamma-BHC
Delta-BHC
PCB-1242
PCB-1254
PCB-1221 |
PCB-1232
PCB-1248 _J
PCB-1260
PCB-1016
Toxaphene
Rockwell
De-
watering
G
0830
S35
8/14/84
ug/1
(ppb)
MD/l.Q
NQ/l.Q
ND/1Q
ND/Q.l
NID/l.Q
ND/0.1
ND/1.0
ND/0.1
ND/Q.l
ND/Q.l
ND/0.1
ND/1.0
ND/1.0
ND/1.0
ND/1.0
ND/l.Q
ND/1.0
ND/10
ND/1.0
ND/10
ND/1Q
ND/10
ND/1.0
ND/10
ND/1.0 1
.andfill
Cells
9-10
G
1205
S36
8/14/84
ug/1
(ppb)
ND/Q.l
ND/Q.l
HP7UO
, ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/1.0
ND/1.0
ND/1.0
ND/0.1
ND/10
ND/1.0
ND/:.O
ND/10
ND/10
ND/1.0
ND/10
ND/1.0 J
.andfill
Cells
3-5
G
1330
S37
8/14/84
ug/1
(ppb)
NJ>/;LOO
HP/100
ND/1000
ND/100
ND/1QO
ND/100
ND/100
ND/100
ND/100
ND/100
ND/100
ND/1000
ND/10Q
ND/1000
ND/1000
ND/1000
ND/100
ND/1000C
ND/1000
ND/.OOOC
ND/1000C
ND/.OOOC
ND/1000
ND/10000
ND/1000
'osyvle.
.andfill
NE Sumo
G
1520
S38
8/14/84
ug/1
(ppb)
MD/ 2
ND/ 2
ND/20
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
NP/ 2
NO/ 2
ND/ 2
ND/ 2
ND/ 2
ND/20
ND/20
ND/20
ND/20
ND/20
ND/20
ND/20
ND/20 1
.andfill
Purge
Well 28
G
1615
S39
8/14/84
ug/1
(ppb)
ND/1.0
ND/0.1
ND/10
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/1.0
ND/0.1
ND/1.0
ND/1.0
ND/1.0
ND/1.0
ND/10
ND/:..O
ND/10
ND/10
ND/10
ND/1.0
ND/10
ND/1.0 1
-------
charger:
iple Date:
U.S. ENVIRONMENTAL PROTECTION AGENCY
REGION V
EASTERN DISTRICT OFFICE
Dow Chemical Landfill Analyses
Sample Type: 8 C-8 hour flow proportioned composite
24C-24 hour flow proportioned composite
EVC-Equal volume composite
G-Grab
Salzbura Salzbura
Sample Type
Time
Sample Number 84ER05
Date
Parameter
11. ACID AMD BASE NEUTRAL POL
2-chloronaphtha ene
1 ,2-dichl orobenzene
1 ,3-dichlorobenzene
1 ,4-dichlorobenzene
3,34-dkhlorobenzldine
2,4-dinitrotoluene
2 ,6-dlnitrotol uene
1 ,2-dlphenyl hydrazine
Fluoranthene
4-chloro
4-bromo
Bis(2-c.
p
phenyl phenyl ether
lenyl p lenyl ether
ilorolsopropyl Jether
B1 s( 2-chl oroethoxy )me thane
Hexachlorobutadlene
Hexachlorocyclopentadiene
Isophorone
Napithalene
Nitrobenzene
N-nltrosodimethylamlne
N-nl trosodl phenyl ami ne
N-nitrosodiproplyamine
Bis(2-ethyliexy' Jphthalate
Rockwell
De-
waterinc
G
0830
S35
8/14/84
ug/1
(ppb)
Landfill
Cells
9-10
G
1205
S36
8/14/84
ug/1
(oob)
.UTANTS (conUfnued
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
21A
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
1200
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
23A
NO/ 4
ISA
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
Landfill
Cells
3-5
G
1330
S37
8/14/84
ug/1
(ppb)
ND/400
ND/400
ND/400
ND/400
ND/400
ND/400
ND/400
ND/400
ND/400
ND/400
ND/400
ND/400
ND/400
ND/400
ND/400
ND/400
ND/400
ND/400
ND/400
ND/400
ND/400
ND/400
Posvvle.
Posyvle.
Landfill
NE Sump
G
1520
S38
8/14/84
ug/1
(oob)
ND/80
230A
ND/80
ND/80
ND/80
ND/80
ND/80
ND/80
ND/80
ND/80
ND/80
ND/80
ND/80
ND/80
ND/80
ND/80
ND/80
ND/80
ND/80
ND/80
ND/80
ND/80
Landfill
Purge
Well 28
G
1615
S39
8/14/84
ug/1
(DDb)
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
35A
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
NP/ 4
-------
ischarger:
ample Date:
U.S. ENVIRONMENTAL PROTECTION AGENCY
REGION Y
EASTERN DISTRICT OFFICE
Dow Chemical Landfill Analyses
Sample Type: 8 C-8 hour flow proportioned composite
24C-24 hour flow proportioned composite
EYC-Equal volume composite
G-Grab
Sample Type
Time
Sample Number 84ER05
Date
Parameter
II. ACID AND BASE NEUTRAL POL
Butyl benzyl pntnalate
D1-n-butyl phthaiate
D1-n-octyl phthaiate
Diethyl phthaiate
D~i methyl phthaiate
Benzo(a)anthracene
Benzol a)pyrene
Benzolb & kjtiuoranthene
Benzol kjfluoranthene
Chrysene
Acenaphthylene
Anthracene
Benzol ghDperyiene
Fluorene
Phenanthrene
Di benzol a ,h ) anthracene
Indeno(l,2,3-cd)pyrene
Pyrene
Aniline
Benzyl alcohol
4-chloroan1line
Dlbenzofuran
Rockwell
De-
u//%"fp f\ no
G
0830
S35
8/14/84
ug/1
.UTANTS U
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
10A
200
28A
ND/ 4
140
170
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
Landfill
Cells
q-10
G
1205
S36
8/14/84
ug/1
(ppb)
:ontinued
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
sai7mirg
Landfill
Cells
3-5
G
1330
S37
8/14/84
ug/1
(ppb)
ND/400
ND/400
ND/400
ND/400
ND/400
ND/400
ND/400
ND/400
ND/400
ND/400
vin /A r\r\
NIJ/H-UU
ND/400
ND/400
ND/400
ND/400
ND/400
ND/400
ND/400
ND/400
ND/400
ND/400
ND/400
Posyvle.
Landfill
ME Sumo
G
1520
S38
8/14/84
ug/1
(DDb)
ND/80
ND/80
ND/80
ND/80
ND/80
ND/80
~ND/80
ND/80
ND/80
ND/80
NU/OU
ND/80
ND/80
ND/80
ND/80
ND/80 _j
ND/80
ND/80
ND/80
ND/80
ND/80
ND/80
ro^yvie.
Landfill
Purge
Well 28
G
1615
S39
8/14/84
ug/1
(pob)
ND/ 4
7A*
ND/ 4
ISA
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
Ml")/ A
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
•••— • —
•^^MBMIMM"1^^^
• • 1 •
• I • 1 • ••
• ••^•-» "'
-------
:harger:
U.S. ENVIRONMENTAL PROTECTION AGENCY
REGION V
EASTERN DISTRICT OFFICE
Sample Type:
8 C-8 hour flow proportioned composite
24C-24 hour flow proportioned composite
)le Date: Dow Chemical Landfill Analyses EYC-Equal volume composite
G-Grab
Salzburq Salzburq Posyvle.
Sample Type
! Time
! Sample Number 84ER05
; Date
Parameter
I. VOLATILES (continued)
Bromome thane
Bromoform
Bromodlchloromethane
Trl chl orof 1 uoromethane
Dlchlorodlfluoromethane
Chl orodlbromomethane
Tetrachloroethene
Toluene
Trlchlorpethene i
Vinyl chloride
Acetone
2-butanone
Carbon dlsulflde
2-hexanone
4-methyl-2-pentanone
Styrene
Vinyl acetate
Total xylenes
Rockwell
De-
watering
G
0830
S35
8/14/84
ug/1
(ppb)
NO/100
ND/100
ND/100
ND/100
ND/100
ND/100
ND/100
2500
MD/1QQ
ND/10Q_
1700A
ND/1000
ND/100
ND/100
ND/100
880A
ND/100
1000
Landfill
Cells
9-10
G '
1205
S36
8/14/84
ug/1
(ppb)
ND/ 1
NO/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
2A
3A
ND/ 1
3A
81A
64A*
ND/ 1
ND/ 1
7A
ND/ 1
ND/ 1
ND/ 1
Landfill
Cells
3-5
G
1330
S37
8/14/84
ug/1
(ppb)
ND/10
230
ND/10
ND/10
ND/10
ND/10
12A
100
ND/1Q
ND/1Q
860A
ND/1QO
ND/10
ND/10
110
88A
ND/10
3?A
Posyvle.
Landfill
NE Sump
G
1520
S38
8/14/84
ug/1
(ppb)
ND/50
ND/50
ND/50
ND/50
ND/50
ND/50
ND/50
660
NO/50
ND/50
3100A
1600A*
ND/50
ND/50
530
ND/50
ND/50
ND/50
Landfill
Purge
Well 28
G
1615
S39
8/14/84
ug/1
(ppb)
ND/100
ND/100
ND/100
NO/:. oo
NO/:. oo
ND/:.OO
ND/:,OO
250A
wn/100
ND/100
1900A
ND/1000
ND/:.OO
ND/. 00
NDA.OO
NDA.OO
ND/:.OO
ND/100
-------
scharger:
nple Date:
U.S. ENVIRONMENTAL PROTECTION AGENCY
REGION V
EASTERN DISTRICT OFFICE
Dow Chemical Landfill Analyses
.Salzburg Salzburg
Sample Type: 8 C-8 hour flow proportioned composite
24C-24 hour flow proportioned composite
EVC-Equal volume composite
G-Grab
PosvvTe.
Sample Type
Time
Sample Number 84ER05
Date
Parameter
Rockwel
De-
water in
G
0830
S35
8/14/84
ug/1
(ppb)
II. ACID AND BASE NEUTRAL POLLUTANTS
2 ,4 ,6- trichl orophenol
4-chl oro-3-methy 1 phenol
2-chl orophenol
2, 4-dichl orophenol
2, 4-dimethyl phenol
2-n1trophenol
4-m"trophenol
2,4-dim'trophenol
4 ,6-dtnl tro-2-methyl phenol
Pentachl orophenol
Phenol
Benzole actd
2-methyl phenol
4-methyl phenol
2,4,5-trichlorophenol
Acenaphthene
Benzidine
1 ,2 ,4-trlchlorobenzene
Hexachlorobenzene
Hexachloroethane
Bis{ 2-chl oroethyl) ether
ND/ 4
ND/ 4
ND/ 4
12A
120
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
290
ND/ 4
ND/ 4
71
ND/ 4
28A
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
Landfil
Cells
9-10
G
1205
S36
8/14/84
ug/1
(DDb)
6fi
NO/ 4
8A
340
NO/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
60
300
130
ND/ 4
20A
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
Landfill
Cells
3-5
G
1330
S37
8/14/84
ug/1
(ppb)
45000
ND/400
5500
70000
ND/400
ND/400
ND/400
ND/400
ND/400
9100
12000
ND/400
ND/400
ND/400
11000
ND/400
ND/400
ND/400
ND/400
ND/400
ND/400
Posyvle.
Landfill
NE Sump
G
1520
S38
8/14/84
ug/1
(ppb)
ND/BO
ND/80
ND/80
ND/80
ND/80
ND/80
ND/80
ND/80
ND/80
120A
1600
3600
ND/80
280A
ND/80
ND/80
ND/80
ND/80
ND/80
ND/80
ND/80
Landfill
Purge
Well 28
G
1615
S39
8/14/84
ug/1
(ppb)
ISA
ND/ 4
34A
130
6A
ND/ 4
ND/ 4
ND/ 4
ND/ 4
840
72
ND/ 4
12A
60
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
25A
-------
NOTES:
1. ND = Compound was analyzed for but not detected. Value reported is the detection limit.
2. NA = Not analyzed.
3. NR = Not reported.
4. A = Detected below quantitation limit (quantitation limit is 10 x dectection limit).
5. C = Blank corrected.
6. J = Estimated value, detected below minimum specified contract detection limit but
greater than zero.
7. * = Presence of compound may be due to sample bottle preparation, field and/or labora-
tory contamination. Methylene chloride is used as a cleaning agent for sample
bottles. Phthalate compounds are components of certain plastics and are widespread
in the environment at low levels.
8. mg/1 = milligram per liter.
9. ug/1 = microgram per liter.
10. mg/kg = milligram per kilogram.
11. ppb = parts per billion.
12. ppm = parts per million.
13. ng/g = nanogram per gram.
14. pg/g = picogram per gram.
15. ppt = parts per trillion.
-------
scharger:
mple Date:
U.S. ENVIRONMENTAL PROTECTION AGENCY
REGION V
EASTERN DISTRICT OFFICE
Dow Chemical Landfill Analyses
Salzburg Salzburg
Sample Type;
8 C-8 hour flow proportioned composite
24C-24 hour flow proportioned composite
EVC-Equal volume composite
G-Grab
Posyvie.
Sample Type
Time
Sample Number 84ER05
Date
Parameter
I. YOLATILES
AcroTein
Acrylonitrile
Benzene
Carbon tetrachloride
Chlorobenzene
1 ,2-dichloroethane
1 ,1,1-trichloroethane
1,1-dichloroethane
1,1,2-trichloroethane
1 ,1,2,2-tetrachloroethane
Chloroethane
Bi s( chl oromethyl ) ether
2-chloroethyl vinyl ether
Chloroform
1,1-dichloroethene
Trans-l ,2-dichloroethene
1 ,2-dichloropropane
Trans-l ,3-dlchloropropene
Cls-l,3-dichloropropene
Ethyl benzene
Methyl ene chloride
Chloromethane
Rockwell
De-
watering
G
0830
S35
8/14/84
ug/1
(ppb)
ND/1000
ND/1000
8900
ND/100
ND/100
ND/100
ND/100
ND/100
ND/100
ND/100
1300
ND/100
ND/1000
170A
ND/100
ND/100
ND/100
ND/100
ND7100
760A
1800*
ND/100
Landfill
Cells
9-10
G
1205
S36
8/14/84
ug/1
(ppb)
ND/10
ND/10
49
ND/ 1
49
ND/ 1
ND/ 1
NO/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/10
2A
1A
ND/ 1
ND/ 1
ND/ 1
ND/ 1
3A
60*
ND/ 1
Landfill
Cells
3-5
G
1330
S37
8/14/84
ug/1
(ppb)
ND/100
ND/100
69A
25A
170
32A
17A
ND/10
ND/10
ND/10
ND/10
ND/10
ND/100
150
21A
ND/10
ND/10
ND/10
ND/10
50A
410*
20A
Posy vie.
Landfill
NE Sump
G
1520
S38
8/14/84
ug/1
(ppb)
ND/500
ND/500
1700
ND/50
460A
ND/50
ND/50
ND/50
ND/50
ND/50
180A
ND/50
ND/500
95A
ND/50
ND/50
ND/50
ND/50
W/50
320A
1100*
ND/50
Landfill
Purge
Well 28
G
1615
S39
8/14/84
ug/1
(ppb)
ND/1000
ND/1000
3100
ND/100
ND/100
ND/100
ND/100
ND/100
ND/100
ND/100
780A
ND/100
ND/lOOn
180A
ND/100
ND/100
ND/100
ND/100
ND/100
ND/100
2200*
ND/100
[Refer to notes page for explanation of data qualifiers and acronyms.]
-------
charger:
pie Date;
U.S. ENVIRONMENTAL PROTECTION AGENCY
REGION Y
EASTERN DISTRICT OFFICE
Dow Chemical
Riverbank Revetment System Analyses
Sample Type: 8 C-8 hour flow proportioned composite
24C-24 hour flow proportioned composite
EYC-Equal volume composite
G-Grab
. e Type
Time
Date 8
Sample Number
Parameter
V. DIOXIMS AND FURANS
2378-TCDD
Total Tetra CDDs
Total Penta CDDs
Total Hexa CDDs
Total Hepta CDDs
OCDD
Z378-TCDF
Total Tetra CDFs
Total Penta CDFs
Total Hexa CDFs
Total Hepta CDFs
OCDF
Section
#1
EVC
.420/1125
'28-29/84
84ER07
S15
pg/g
(ppt)
ND/.083
0.412
ND/.198
ND/.131
ND/.317
ND/.875
ND/.104
0.090
ND/.119
ND/.225
ND/.152
ND/.661
Section
#2
G
1600
8/29/84
84ER08
SOS
pg/g
(ppt)
ND/.029
ND/.015
ND/.074
ND/.098
0.351
1.76
ND/.030
ND/.014
ND/.061
ND/.069
ND/.134
ND/.392
Section
#3
G
1700
8/29/84
84ER08
S10
pg/g
(ppt)
NO/. 021
ND/.012
ND/.036
NO/. 046
ND/.052
ND/.096
0.028
0.048
ND/.030
ND/.032
ND/.045
ND/.102
Section
#4
G
1845
8/29/84
84ER07
S46
pg/g
(ppt)
ND/.022
ND/.013
ND/.057
ND/.081
ND/.106
ND/.123
ND/.020
ND/.015
ND/.023
ND/.053
ND/.070
ND/.096
Section
#1
Sediment
G
0955
10/23/84
85ER01
S07
ng/g
(ppb)
3.7
145.8
111.5
179.9
364.9
916.2
63.97
248.5
127.4
108.9
853.3
2739
-------
scharger:
nple Date:
U.S. ENVIRONMENTAL PROTECTION AGENCY
REGION V
EASTERN DISTRICT OFFICE
Dow Chemical Landfill Analyses
Sample Type: 8 C-8 hour flow proportioned composite
24C-24 hour flow proportioned composite
EVC-Equal volume composite
G-Grab
Sample Type
Time
Date
Sample Number
Parameter
VI. OTHER PARAMETERS
TDS
TSS
BOD5
NH3
TP
TKN
Total Phenol ics
Section
#1
Comp.
1420/1125
8/28-
29/84
84ER07
S15
mg/1
(ppm)
5954
52
203
5.59
0.184
2.44
20.0
Section
#2
G
1600
8/28-
29/84
84ER08
S05
mg/1
(ppm)
2728
24
6.51
14.0
0.522
7.28
0.50
Section
#3
G
1700
8/28-
29/84
84ER08
S10
mg/1
(ppm)
3482
52
5.94
19.5
0.413
19.5
0.40
Section
#4
G
1845
8/28-
29/84
84ER07
S46
mg/1
(ppm)
2392
36
18.8
7.11
0.479
2.17
0.80
-------
scharger:
mple Date:
U.S. ENVIRONMENTAL PROTECTION AGENCY
REGION Y
EASTERN DISTRICT OFFICE
Dow Chemical
Riverbank Revetment System Analyses
Sample Type: 8 C-8 hour flow proportions Composite
24C-24 hour flow proportioned composite
EVC-Equal volume composite
G-Grab
Sample Type
Time
Date {
Sample Number
Parameter
III. PCB/PESTICIDE POLLUTANTS
Aldrin
Dieldrin
Chlordane
4, 4 '-DDT
4,4'-DDE
4, 4 '-ODD
Alpha-endosulfan
Beta-endosulfan
Endosulfan sulfate
Endrin
Endrin aldehyde
Heptachlor
Heptachlor epoxide
Alpha-BHC
Beta-BHC
Gamma-BHC
Delta-BHC
PCB-1242
PCB-1254
PCB-1221
PCB-1232
PCB-1248
PCB-1260
PCB-1016
Toxaphene
Methoxychlor
r^j-,-^ L~*.. — •
Section
#1 1
EVC
1420/112!
728-29/8^
84ER07
S15
ug/1
(ppb)
ND/10
ND/10
ND/100
ND/10
ND/10
ND/10
ND/10
ND/10
ND/10
ND/10
ND/10
ND/10
ND/10
ND/10
ND/10
ND/10
ND/10
ND/100
ND/100
ND/100
ND/100
ND/100
ND/100
ND/100
ND/100
NA
u i1
Section
#2
G
1600
8/29/84
84ER08
SOS
ug/1
(ppb)
ND/0.2
ND/0.2
ND/2.0
ND/0.2
ND/0.2
ND/0.2
ND/0.2
ND/0.2
ND/0.2
ND/0.2
ND/0.2
ND/0.2
ND/0.2
ND/0.2
ND/0.2
ND/0.2
ND/0.2
ND/2.0
ND/2.0
ND/2.0
ND/2.0
ND/2.0
MD/2.0
ND/2.0
ND/2.0
NA
LI 1
Section
#3
G
1700
8/29/84
84ER08
S10
ug/1
(ppb)
ND/0.1
ND/0.1
ND/1.0
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/1.0
ND/0.1
ND/1.0
ND/1.0
ND/1.0
ND/1.0
ND/1.0
ND/1.0
ND/1.0
ND/1.0
ND/1.0
ND/1.0
ND/1.0
ND/1.0
NA
....... |( M i .1
Section
#4
G
1845
8/29/84
84ER07
S46
ug/1
(ppb)
ND/0.1
ND/0.1
ND/1.0
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.5
ND/0.1
ND/0.5
ND/0.5
ND/0.5
ND/0.1
ND/1.0
ND/1.0
ND/1.0
ND/1.0
ND/1.0
Nb/i.O
ND/1.0
ND/1.0
NA
. . • •, • Ti-a- •
Section
#1
Sediment
G
0955
10/23/84
85ER01
S07
mg/kg
(ppm)
ND/1.2
ND/2.4
ND/1.2
ND/2.4
ND/2.4
ND/2.4
ND/1.2
ND/2.4
ND/2.4
ND/2.4
ND/2.4
ND/1.2
ND/1.2
ND/1.2
ND/1.2
ND/1.2
ND/1.2
ND/12
ND/24
ND/12
ND/12
ND/12
ND/24
ND/12
ND/24
ND/12
-------
scharger:
iinple Date:
U.S. ENVIRONMENTAL PROTECTION AGENCY
REGION V
EASTERN DISTRICT OFFICE
Dow Chemical
Riverbank Revetment System Analyses
Sample Type: 8 C-8 hour flow proportioned composite
24C-24 hour flow proportioned composite
EVC-Equal volume composite
G-Grab
Sample Type
Time
Date _$
Sample Number
Parameter
IV. METALS
Aluminum
Antimony
Arsenic
Barium
Beryllium
Cadmium
Chromium
Cobalt
Copper
Iron
Lead
Manganese
Mercury
Nickel
Selenium
Silver
Thallium
Tin
Vanadium
Zinc
Section
#1
EVC
L420/1125
/28-29/S4
84ER07
S15
ug/1
(ppb)
MR
ND/ 6
240
221
NO/ 1
ND/0.5
NO/ 4
ND/10
3
5480C
ND/ 2
1220
0.21
ND/15
NO/ 2
NO/ 3
2.1
MR
6
5C
Section
n
G
1600
8/29/84
84ER08
SOS
ug/1
(ppb)
NR
ND/ 6
75
339
ND/ 1
ND/0.5
5
ND/10
2
6800C
ND/ 2
1260
0.33
ND/15
ND/ 2
ND/ 3
2.1
NR
5
NR
Section
#3
G
1700
8/29/84
84ER08
S10
ug/1
(ppb)
105C
ND/ 6
84
590
ND/ 1
ND/0.5
ND/ 4
ND/10
5
13100C
ND/ 2
2110
NO/0.2
ND/15
ND/ 2
ND/ 3
ND/ 2
NR
ND/ 4
14C
Section
#4
G
1845
8/29/84
84ER07
S46
ug/1
(ppb)
NR
ND/ 6
11
335
ND/ 1
ND/0.5
ND/ 4
ND/10
ND/ 2
11500C
ND/ 2
1150
ND/0.2
ND/15
ND/ 2
ND/ 3
ND/ 2
NR
NO/ 4
NR
Section
#1
Sediment
G
0955
10/23/84
85ER01
S07
mg/kg
(ppm)
4570.
50
, 113
125
ND/3.5
ND/6.2
15
ND/13
114
120000
ND/12
253
52
ND/5.4
?0
ND/13
ND/38
48
178
•••• —
i. •'-
-------
charger:
pie Date;
U.S. ENVIRONMENTAL PROTECTION AGENCY
REGION Y
EASTERN DISTRICT OFFICE
Dow Chemical
Riverbank Revetment System Analyses
Sample Type: 8 C-8 hour flow proportioned composite
24C-24 hour flow proportioned composite
EYC-Equal volume composite
G-Grab
Sample Type
Time
Date £
Sample Number
Parameter
Section
#1
EVC
1420/1125
728-29/84
84ER07
S15
ug/1
(ppb)
Section
#2
6
1600
8/29/84
84ER08
S05
ug/1
(ppb)
II. ACID AND BASE NEUTRAL POL .UTANTS (continued
Butyl benzyl phthalate
Di-n-butyl phthalate
Di-n-octyl phthalate
Diethyl phtialate
Dimethyl phthalate
Benzo( a) anthracene
Benzo(a pyrene
Benzo(b & k)fluoranthene
Benzo( k ) f 1 uoranthene
Chrysene
Acenaphthylene
Anthracene
Benzolghi)perylene
Fluorene
Phenanthrene
Di benzol a, h) anthracene
Indeno(l,2,3-cd)pyrene
Pyrene
Aniline
Benzyl alcohol
4-chloroani ine
Dibenzofuran
ND/40
ND/40
ND/40
ND/40
ND/40
ND/40
ND/40
ND/40
ND/40
ND/40
ND/40
ND/40
ND/40
ND/40
ND/40
ND/40
ND/40
ND/40
ND^40
ND/40
ND/40
ND/40
ND/ 4
ND/ 4
NO/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
NO/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
NO/ 4
ND/ 4
Section
#3
6
1700
8/29/84
84ER08
S10
ug/1
(ppb)
ND/20
ND/20
ND/20
ND/20
ND/20
ND/20
ND/20
ND/20
ND/20
ND/20
ND/20
ND/20
ND/20
ND/20
ND/20
ND/20
ND/20
ND/20
ND/20
ND/20
ND/20
ND/20
Section
#4
G
1845
8/29/84
84ER07
S46
ug/1
(ppb)
ND/ 2
ND/ 2
NO/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
NO/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
ND/ 2
Section
#1
Sediment
G
0955
10/23/84
85ER01
S07
mg/kg
( ppm)
ND/20
ND/20
ND/20
ND/20
ND/20
ND/20
ND/20
ND/20
ND/20
ND/20
ND/20
ND/20
ND/20
ND/20
20J
ND/20
ND/20
20J
ND/20
ND/20
ND/20
ND/20
-------
: (larger :
3le Date:
U.S. ENVIRONMENTAL PROTECTION AGENCY
REGION V
EASTERN DISTRICT OFFICE
Dow Chemical
Riverbank Revetment System Analyses
Sample Type: 8 C-8 hour flow proportioned composite
24C-24 hour flow proportioned composite
EVC-Equal volume composite
G-Grab
Sample Type
Time
Date
a
Sample Number
Parameter
II. ACID AND BASE
2-methyl naphtha!
Z-nitroaniline
3-nitroanil ine
4-nitroanil ine
Section
#1
EVC
1420/1125
728-29/84
84ER07
S15
ug/1
(ppb)
Section
#2
6
1600
8/29/84
84 EROS
SOS
ug/1
(ppb)
NEUTRAL POLLUTANTS (continued
ene
ND/40
ND/40
ND/40
ND/40
ND/ 4
ND/ 4
ND/ 4
ND/ 4
Section
#3
G
1700
8/29/84
84 EROS
S10
ug/1
(ppb)
ND/20
ND/20
ND/20
ND/20
Section
#4
G
1845
8/29/84
84ER07
S46
ug/1
(ppb)
ND/ 2
ND/ 2
ND/ 2
ND/ 2
Section
#1
Sediment
G
0955
10/23/84
85ER01
S07
mg/kg
(ppm)
ND/20
ND/96
ND/96
ND/96
-------
;charger:
iple Date:
U.S. ENVIRONMENTAL PROTECTION AGENCY
REGION V
EASTERN DISTRICT OFFICE
Dow Chemical Treatment Pond Analyses
Sample Type: 8 C-8 hour flow proportioned compos1t<
24C-24 hour flow proportioned compos1t>
EYC-Equal volume composite
G-Grab
sample Type
Time
Sample Number 84ER04
Date
Parameter
Pond
Surface
Sediment
G
1910
S26
7/26/84
ug/kg
(ppb)
Pond
Bottom
Sediment
G
1915
S27
7/26/84
ug/kg
(ppb)
II. ACID AND BASE NEUTRAL POLLUTANTS (continued
Z-methyl naphthal ene
2-nltroani line
-nitroanlline
4-nitroan1line
ND/20
ND/100
ND/100
ND/100
ND/20
ND/100
ND/100
ND/100
Pond
Surface
Sediment
G
1800
S24
7/26/84
ug/kg
(ppb)
ND/20
ND/100
ND/100
ND/100
Pond
Bottom
Sediment
G
1810
S25
7/26/84
ug/kg
(ppb)
ND/20
ND/100
ND/100
ND/100
Pond Up
Surface
Sediment
G
1635
S19
7/26/84
ug/kg
(ppb)
Pond Up
Bottom
Sediment
G
1645
S23
7/26/84
ug/kg
(ppb)
ND/20
ND/100
ND/100
ND/100
Pond M1d
Surface
Sediment
1140
S17
7/26/84
ug/kg
(ppb)
ND/20
ND/100
ND/100
ND/100
Pond Mid
Bottom
Sediment
G
1220
S21
7/26/84
ug/kg
(ppb)
ND/?0
ND/100
ND/100
ND/100
Pond Low
Surface
Sediment
G
1007
S16
7/26/84
ug/kg
(ppb)
ND/?0
ND/100
ND/lOO
ND/100
Pond Low
Bottom
Sediment
G
1045
S20
7/26/84
ug/kg
(ppb)
MD/?0
NO/100
ND/100
-------
:harger: U.S. ENVIRONMENTAL PROTECTION AGENCY
REGION V J A ..
• EASTERN DISTRICT OFFICE Sample Type: 8 C-8 hour flow proportioned composite
:-' 24C-24 hour flow proportioned composite
3le Date: Dow Chemical Treatment Pond Analyses EVC-Equal volume composite
G-Grab
Primarv Primary Scndarv. Scndary. Tertiary Tertiary Tertiary Teritary Tertiary Tertiary
Sample Type
Time
Sample Number 84ER04
Date
Parameter
Pond
Surface
, Sediment
G
1910
S26
7/26/84
ug/kg
(ppb)
II. ACID AND BASE NEUTRAL POLLUTANTS
Butyl benzyl phthalate
Di-n-butyl pfithalate
Di-n-octyl phthalate
D1 ethyl phtnalate
Dimethyl phthalate
Benzo(a)anthracene
Benzol ajpyrene
Benzol b & Kjtiuoranthene
Benzol k)fluoranthene
Chrysene
Acenaphthylene
ATthracene
Benzol ghDperylene
Fl uorene
Phenanthrene
01 benzo( a, h) anthracene
lndenoll,2,3-cd)pyrene
Pyrene
Aniline
Benzyl alconoi
4-chloroaniline
Dlbenzofuran
ND/10
10J
ND/10
ND/10
ND/10
ND/10
ND/20
ND/20
ND/20
10J
ND/10
ND/10
ND/20
ND/10
ND/10
ND/20
ND/20
wn/io
ND/10
NO/20
ND/50
ND/10
Pond
Bottom
Sediment
G
1915
S27
7/26/84
ug/kg
(ppb)
.continued
ND/10
ND/10
ND/10
ND/1Q
ND/10
ND/10
ND/20
ND/20
ND/20
ND/10
ND/10
ND/10
ND/20
ND/10
ND/10
ND/20
ND/20
ND/10
ND/1Q
ND/20
ND/50
ND/10
Pond
Surface
Sediment
G
1800
S24
7/26/84
ug/kg
(ppb)
ND/10
iUJ
ND/10
NU/iU
ND/10
ND/10
ND/20
ND/20
ND/20
kin /i A
NU/IU
ND/10
ND/10
ND/20
ND/10
ND/10
ND/ZO
ND/20
ND/10
ND/10
ND/20
ND/50
ND/10
Pond
Bottom
Sediment
G
1810
S25
7/26/84
ug/kg
(ppb)
ND/10
1 7nn
I/UU
ND/10
ND/10
ND/10
ND/20
ND/20
ND/20
im /i n
NU/iU
ND/10
ND/10
ND/20
ND/10
ND/10
ND/20
ND/20
ND/10
ND/10
ND/20
ND/50
ND/10
Pond Up
Surface
Sediment
G
1635
S19
7/26/84
ug/kg
(ppb)
Pond Up
Bottom
Sediment
6
1645
S23
7/26/84
ug/kg
(ppb)
ND/10
wn/1 n
nu/ iu
ND/10
wn/1 n
ND/10
ND/10
ND/20
ND/20
ND/20
Mn/1 n
ND/10
ND/10
ND/20
ND/10
ND/10
ND/20
ND/20
ND/10
Kin /i n
ND/20
ND/50
ND/10
Fond Mid
Surface
Sediment
CT
1140
S17
7/26/84
ug/kg
(ppb)
ND/10
1QJ
ND/10
ND/10
ND/10
ND/10
ND/20
ND/20
ND/20
ND/10
ND/10
ND/10
ND/20
ND/10
ND/10
ND/20
ND/20
4600
Mn/i n
ND/20
ND/50
ND/10
Pond Mid
Bottom
Sediment
1220
S21
7/26/84
ug/kg
(ppb)
ND/10
ND/10
ND/10
ND/10
ND/10
ND/10
ND/20
ND/20
ND/20
ND/10
ND/10
ND/10
ND/20
ND/10
ND/10
ND/20
ND/20
ND/10
wn/i n
ND/20
ND/50
ND/10
HO no LOW
Surface
Sediment
n
1007
S16
7/26/84
ug/kg
(ppb)
ND/10
ND/10
ND/10
ND/10
ND/10
ND/10
ND/20
ND/20
ND/20
ND/10
ND/10
ND/10
ND/20
ND/10
ND/10
ND/20
ND/20
ND/10
MQ/10
ND/20
ND/50
ND/10
pona La*
Bottom
Sediment
1045
S20
7/26/84
ug/kg
(ppb)
ND/10
ND/10
10J
ND/10
ND/10 |
ND/10
ND/2Q
NO/20
ND/20
ND/10
ND/10
ND/10
NU/<:U
ND/10
NU/IU
N072lT~
ND/20
ND/10
ND/10
ND/20
ND/50
r NO/IP i
-------
ischarger:
ample Date:
U.S. ENVIRONMENTAL PROTECTION AGENCY
REGION V
EASTERN DISTRICT OFFICE
Sample Type: 8 C-8 hour flow proportioned composH
24C-24 hour flow proportioned composlt
EVC-Equal volume composite
G-Grab
Primary Primary Scndarv. Scndary. Tertiary Tertiary Tertiary Terltary Tertiary Tertiary
Dow Chemical Treatment Pond Analyses
Sample Type
Time
Sample Number 84ER04
Date
Parameter
Pond
Surface
Sediment
G
1910
S26
7/26/84
ug/kg
(ppb)
Pond
Bottom
Sediment
G
1915
S27
7/26/84
ug/kg
(ppb)
u. ACID AND BASE NEUTRAL POLLUTANTS (continued
2-chl oronaphthal ene
1 ,2-dlchl orobenzene
1 ,3-dichl orobenzene
1 ,4-dichl orobenzene
3,34-dichlorobenzidine
2 ,4-di ni trotol uene
2, 6-dinitro toluene
1,2-diphenylhydrazine
Fluoranthene
4-chlorophenyl phenyl ether
4-bromophenyl phenyl ether
Bl s( 2-cm orol sopropyl )ether
Bl s( 2-cn i oroethoxy jmethane
Hexachlorobutadlene
Hexach I orocycl opentadiene
Isophorone
Naphthalene
Nitrobenzene
N-nitrosodlmethylamlne
N-n1 trosodl phenyl ami ne
N-nitrosodiproplyamine
Bis(2-ethylhexyl)phthalate
ND/10
ND/10
13000
67000
ND/20
ND/20
ND/20
ND/20
ND/10
ND/10
ND/10
ND/20
ND/20
ND/10
ND/10
ND/10
10J
ND/10
ND/10
ND/10
ND/20
9500
ND/10
10/10
2000
10000
ND/20
ND/20
ND/20
ND/20
ND/10
ND/10
ND/10
ND/20
ND/20
ND/10
ND/10
ND/10
ND/10
ND/10
ND/10
ND/10
ND/20
ND/20
Pond
Surface
Sediment
1800
S24
7/26/84
ug/kg
(ppb)
ND/10
2700
100
8500
ND/20
ND/20
ND/20
ND/20
ND/10
ND/10
ND/10
ND/20
ND/20
ND/10
ND/10
ND/10
ND/10
ND/10
ND/10
ND/10
ND/20
2300
Pond
Bottom
Sediment
G
1810
S25
7/26/84
ug/kg
(ppb)
ND/10
ND/10
ND/10
ND/10
ND/20
ND/20
ND/20
ND/20
ND/10
ND/10
ND/10
ND/20
ND/20
ND/10
ND/10
ND/10
ND/10
ND/10
ND/10
ND/10
ND/20
ND/20
Pond Up
Surface
Sediment
G
1635
S19
7/26/84
ug/kg
(ppb)
Pond Up
Bottom
Sediment
G
1645
S23
7/26/84
ug/kg
(ppb)
ND/10
ND/10
ND/10
ND/10
ND/20
ND/20
ND/20
ND/20
ND/10
ND/10
ND/10
ND/20
ND/20
ND/10
ND/10
ND/10
ND/10
ND/10
Np/10
ND/10
ND/20
ND/20
Pond Mid
Surface
Sediment
G"
1140
S17
7/26/84
ug/kg
(ppb)
ND/10
ND/10
ND/10
3600
ND/20
ND/20
ND/20
ND/20
ND/10
ND/10
ND/10
ND/20
ND/20
ND/10
ND/10
ND/10
ND/10
ND/10
NO/10
ND/10
ND/20
3200
>ond Mid
Bottom
Sediment
G
1220
S21
7/26/84
ug/kg
(ppb)
ND/10
ND/10
ND/10
ND/10
ND/20
ND/20
ND/20
ND/20
ND/10
ND/10
ND/10
ND/20
ND/20
ND/10
ND/10
ND/10
ND/10
ND/10
ND/10
ND/10
ND/20
ND/20
>ond Low
Surface
Sediment
G
1007
S16
7/26/84
ug/kg
(ppb)
ND/10
ND/10
ND/10
10J
ND/20
ND/20
ND/20
ND/20
Kin/10
ND/10
ND/10
ND/20
ND/20
ND/10
ND/10
ND/10
ND/10
ND/10
ND/10
ND/10
ND/20
ND/20
>ond Low
Bottom
Sediment
fi
1045
S20
7/26/84
ug/kg
(ppb)
ND/10
ND/10
ND/10
ND/10
ND/20
ND/20
ND/20
ND/20
Nin/10
ND/10
ND/10
ND/20
ND/20
ND/10
ND/10
ND/10
ND/10
ND/10
NO/10
ND/10
ND/20
ND/20
-------
ischarger:
jmple Date:
U.S. ENVIRONMENTAL PROTECTION AGENCY
REGION V
EASTERN DISTRICT OFFICE
Dow Chemical Treatment Pond Analyses
Sample Type: 8 C-8 hour flow proportioned composite
24C-24 hour flow proportioned composite
EVC-Equal volume composite
G-Grab
Primary Primary Scndarv. Scndarv. Tertiary Tertiary Tertiary Teritary Tertiary Tertiary
Sample Type
Time
Samole Number 84ER04
Date
Parameter
II. ACID AND BASE NEUTRAL POL
2 ,4 ,6-tri chl orophenol
4-chl oro-3-methyl phenol
2-chl orophenol
2, 4-dichl orophenol
2 ,4-dlmethyl phenol
z-nitrophenol
4-nltrophenol
2,4-dinitrophenol
4 ,6-dlni tro-2-methyl phenol
Pentachl orophenol
Phenol
Benzole acid
2-methyl phenol
4-methyl phenol
2 ,4 ,5-trichl orophenol
Acenaphthene
Benzidine
1,2,4-trichlorobenzene
Hexachlorobenzene
Hexachloroethane
Blsl 2-chl oroethyl) ether
Pond
Surface
Sedinent
G
1910
S26
7/26/84
ug/kg
(ppb)
.UTAHTS
ND/10
ND/20
ND/10
ND/10
ND/10
ND/20
ND/100
ND/50
ND/20
ND/20
ND/10
ND/100
ND/10
ND/10
ND/100
ND/10
ND/40
ND/10
ND/10
ND/10
ND/10
Pond
Bottom
Sediment
G
1915
S27
7/26/84
ug/kg
(ppb)
ND/10
ND/20
ND/10
ND/10
ND/10
ND/20
ND/100
ND/50
ND/20
ND/20
ND/10
ND/100
ND/10
ND/10
ND/100
ND/10
ND/40
ND/10
ND/10
ND/10
ND/10
Pond
Surface
Sediment
G
1800
S24
7/26/84
ug/kg
(ppb)
ND/10
ND/20
ND/10
ND/10
ND/10
ND/20
ND/100
ND/50
ND/20
ND/20
ND/10
ND/100
ND/10
17000
ND/100
ND/10
ND/40
35000
10J
ND/10
ND/10
Pond
Bottom
Sediment
G
1810
S25
7/26/84
ug/kg
(ppb)
ND/10
ND/20
ND/10
ND/10
ND/10
MD/20
ND/100
ND/50
ND/20
ND/20
ND/10
ND/100
ND/10
ND/10
ND/100
ND/10
ND/40
10J
ND/10
ND/10
ND/10
Pond Up
Surface
Sediment
G
1635
S19
7/26/84
ug/kg
(ppb)
Pond Up
Bottom
Sediment
G
1645
S23
7/26/84
ug/kg
(ppb)
ND/10
ND/20
ND/10
ND/10
ND/10
ND/20
ND/100
ND/50
ND/20
ND/20
ND/10
ND/100
ND/10
ND/10
ND/100
ND/10
ND/40
ND/10
ND/10
ND/10
ND/10
Pond Mid
Surface
Sediment
G
1140
S17
7/26/84
ug/kg
(ppb)
ND/10
NO/20
ND/10
ND/10
ND/10
wn/?o
100J
ND/50
ND/20
7900
10J
ND/100
ND/10
ND/10
ND/100
ND/10
ND/40
2800
ND/10
ND/10
ND/10
Pond Mid
Bottom
Sediment
G
1220
S21
7/26/84
ug/kg
(ppb)
ND/10
ND/20
ND/10
ND/10
ND/10
wn/?o
ND/100
ND/50
ND/20
ND/20
ND/10
ND/100
ND/10
ND/10
ND/100
ND/10
ND/40
ND/10
ND/10
ND/10
ND/10
Jond Low
Surface
Sediment
G
1007
S16
7/26/84
ug/kg
(ppb)
ND/10
ND/20
ND/10
NDAQ
Nn/10
NH/PQ
ND/100
ND/50
ND/20
ND/20
ND/10
ND/100
, ND/10
ND/10
ND/100
ND/10
ND/40
NP/10
ND/10
NDAO
ND/10
Jond Low
Bottom
Sediment
G
1045
S20
7/26/84
ug/kg
(ppb)
ND/10
ND/20
ND/10
ND/IO
Nn/io
Nn/?a
MD/lOO
ND/50
ND/2Q
ND/20.
ND/10
ND/100
NO/10
ND/10
wrwino
ND/10
ND/40
NO/10
ND/10
ND/IO
ND/10
-------
scharger:
nple Date:
U.S. ENVIRONMENTAL PROTECTION AGENCY
REGION V
EASTERN DISTRICT OFFICE
Sample Type: 8 C-8 hour flow proportioned composltt
24C-24 hour flow proportioned composH.
EVC-Equal volume composite
G-Grab
Primary Primary Scndary. Scndary. Tertiary Tertiary Tertiary Teritary Tertiary Tertiary
Dow Chemical Treatment Pond Analyses
Sample Type
Time
Sample Number 84ER04
Date
Parameter
!. VOLATILES (continued)
Bromomethane
Bromoform
Bromodichloromethane
Trichl orof 1 uoromethane
Dichl orodl f 1 uoromethane
Chlorodibromomethane
Tetrachloroethene
Toluene
Trichloroethene
Vinyl chloride
Acetone
2-butanone
Carbon disulfide
2-hexanone
4-methyl -2-pentanone
Styrene
Vinyl acetate
Total xylenes
Pond
Surface
Sediment
G
1910
S26
7/26/84
ug/kg
(ppb)
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2 . 5
ND/2.5
340
ND/2.5
ND/2.5
1300
ND/100
ND/ 5
ND/50
ND/50
ND/2.5
ND/ 5
310
Pond
Bottom
Sediment
G
1915
S27
7/26/84
ug/kg
(ppb)
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
9.4
ND/2.5
ND/2.5
50 c
ND/100
ND/ 5
ND/50
ND/50
ND/2.5
ND/ 5
9.7
Pond
Surface
Sediment
G
1800
S24
7/26/84
ug/kg
(ppb)
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
16
110
2.5J
ND/2.5
50 J
ND/100
Pond
Bottom
Sediment
G
1810
S25
7/26/84
ug/kg
(ppb)
ND/2.5
9.8
ND/2.5
ND/2.5
ND/2.5
ND/2.5
12
26
2.5J
ND/2.5
ND/50
ND/100
ND/ 5 NO/ 5
ND/50 ND/50
ND/50 | ND/50
2.5J ND/2.5
ND/ 5
39
ND/ 5
15
Pond Up
Surface
Sediment
G
1635
S19
7/26/84
ug/kg
(ppb)
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/50
ND/100
ND/ 5
ND/50
ND/50
ND/2.5
NO/ 5
ND/2.5
Pond Up
Bottom
Sediment
G
1645
S23
7/26/84
ug/kg
(ppb)
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/50
ND/100
ND/ 5
ND/50
ND/50
ND/2.5
ND/ 5
ND/2.5
Pond Mid
Surface
Sediment
G
1140
S17
7/26/84
ug/kg
(ppb)
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
2.5J
ND/2.5
ND/2 . 5
50 J
ND/100
ND/ 5
ND/50
ND/50
ND/2.5
ND/ 5
ND/2.5
Pond Mid
Bottom
Sediment
G
1220
S21
7/26/84
ug/kg
(ppb)
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
fJD/2.5
ND/2.5
ND/2.5
ND/50
ND/100
ND/ 5
ND/50
ND/50
M/2.5
NO/ 5
ND/2.5
Pond LOW
Surface
Sediment
G
1007
S16
7/26/84
ug/kg
(ppb)
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
2.5J
ND/2.5
ND/2.5
ND/50
ND/100
ND/ 5
ND/50
ND/50
ND/2.5
NO/ 5
ND/2.5
Pond LOW
Bottom
Sediment
1045
S20
7/26/84
ug/kg
(ppb)
ND/2 . 5
ND/2.5
ND/2.5
ND/2.5
ND/2 . 5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/50
NO/100
ND/ 5
ND/50
NO/50
NO/2.5
NO/ 5
ND/2.5
-------
scharger:
tmple Date:
U.S. ENVIRONMENTAL PROTECTION AGENCY
REGION V
EASTERN DISTRICT OFFICE
Dow Chemical Treatment Pond Analyses
Sample Type: 8 C-8 hour flow proportioned composite
24C-24 hour flow proportioned composite
EYC-Equal volume composite
G-Grab
n^,- 0^^™=,^,, c™Ha».w onHar-v/. Tertiary Tertiary TertlaCY_
Sample Type
Time
^amnlp Wumhpr 84ER04
Date
Parameter
I. YOLATILES
Acrolein
Acrylonltrlle
Benzene
Carbon tetrachlorfde
Chlorobenzene
1,2-dlchloroethane
1,1,1-tnchioroethane
1,1-dlchloroethane
1,1,2-trlchloroethane
1,1,2 ,2-tetracnl oroetnane
Chloroethane
B1 s( chl oromethyl ) ether
2-chloroethyl vinyl ether
Chloroform
1,1-dichioroethene
Trans-1 ,2-dtchloroethene
1,2-dlchloropropane
Trans-i ,o-oicn i oropropene
C1 s-l ,3-dich I oropropene
Ethyl benzene
Methyl ene chloride
Chloromethane
Pond
Surface
Sediment
G
1910
S26
7/26/84
ug/kg
(DDb)
ND/50
ND/50
500
ND/Z.b
4000
ND/2 . 5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/£. b
NO/ 5
2800
1900
ND/2.5
Pond
Bottom
Sediment
G
1915
S27
7/26/84
ug/kg
(DDb)
ND/50
ND/50
20
ND/2.b
78
ND/2 . 5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
kin /o c
NU/£ . 3
ND/ 5
190
1100
ND/2.5
Pond
Surface
Sediment
G
1800
S24
7/26/84
ug/kg
(DDb)
ND/50
ND/50
30
ND/2.5
160
NU/d. b
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
un/9 5
NU/C . 0
ND/ 5
230
98
ND/2.5
r Pond
Bottom
Sediment
G
1810
S25
7/26/84
ug/kg
(DDb)
ND/50
ND/50
2.5J
ND/2.5
23
2C 1
. Do
ND/2.5
ND/2 . 5
ND/2.5
ND/2.5
ND/2 . 5
ND/2.5
MD/2.5
2.5J
ND/2.5
ND/2.5
ND/2.5
MD/? 5
ND/ 5
25
50
ND/2.5
Pond Up
Surface
Sediment
G
1635
S19
7/26/84
ug/kg
(ppb)
ND/50
ND/50
ND/2.5
ND/2.5
6.0
wn/9 R
NU/& . 0
ND/2.5
ND/2 . 5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2 5
ND/ 5
ND/2.5
ND/2.5
Pond Up
Bottom
Sediment
G
1645
S23
7/26/84
ug/kg
(DDb)
ND/50
ND/50
ND/2.5
ND/2.5
ND/2.5
un/o c
nU/ £. . 3
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/ 5
ND/2.5
ND/2.5
ND/2.5
Pond Mid
Surface
Sediment
G
1140
S17
7/26/84
ug/kg
(ppb)
ND/50
ND/50
ND/2.5
ND/2.5
22
kin/? c
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/ 5
16
350
ND/2.5
Teritary Tertiary Tertiary
Jond Mid
Bottom
Sediment
G
1220
S21
7/26/84
ug/kg
(ppb)
ND/50
ND/50
ND/2.5
ND/2.5
ND/2.5
ND/2 5
ND/2.5
ND/2 . 5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2 . 5
NO/ 5
ND/2.5
1100BG
ND/2.5
Pond Low
Surface
Sediment
G
1007
S16
7/26/84
ug/kg
(ppb)
ND/50
ND/50
ND/2.5
ND/2.5
2.5J
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
nl U / £ 9 >j
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/ 5
2. 50
110
ND/2.5
»ond LOW
Bottom
Sediment
G
1045
S20
7/26/84
ug/kg
,(ppb)
ND/50
ND/50
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
ND/2.5
NO/ 5
ND/2.5
NO/2.5
NO/2.5
-------
APPENDIX A-4
Tertiary Pond Sediments
-------
NOTES;
1. NA = Not analyzed.
2. ND = Not detected (detection HmH).
3. B = The analyte 1s found 1n the blank as well as the sample. This Indicates possible/
probable blank contamination.
4. J = Estimated value, detected below minimum specified contract detection limit but
greater than zero.
5. ug/g * mlcrograms per gram.
6. mg/kg - milligrams per kilogram.
7. ppb = parts per billion.
8. ppm = parts per million.
-------
Discharger:
Sample Date:
U.S. ENVIRONMENTAL PROTECTION AGENCY
REGION V
EASTERN DISTRICT OFFICE
Dow Chemical Process Sewer Sediments/Residue
Sample Type: 8 C-8 hour flow proportioned composi
24C-24 hour flow proportioned composi
EYC-Equal volume composite
G-Grab
Sample Type
Time
Sample Number
Date
General General
85ER01
Parameter
V. DtOXlNS AND FURANS
1 2378-TCDD
Total Tetra
Total Penta
Total Hexa ,
Total Hepta
QCDD
:DDS
:DDS
bDs
CDDs
1 ' 2378-TCDF 1
| Total Tetra
Total Penta
Total Hexa \
Total Hepta
OCDF
CDFs I
CDFs ]
DFs ]
CDFs
50
Sewer
G
1258
S05*
100/200
Sewer
G
0909
S06
10/23/84 10/23/84
ppb
10.994
20.980
10.836
24.414
13.9916
ID7S3T.91
"8.838
11,113
i:..769
6.201
37.892
101.810
ppb
ID
JD/0.032
0.186
:.3.090
33.539
71.810
4.621
$.768
8.785
JD/.0819
24.458
:. .605
300
Sewer
G
0933
508
.0/23/84
PPb
0.469
2.610
6.950
42.628
39000
ND/3000
1.164
3.905
13.777
40.199
29000
1700
500
Sewer
G
1343a
S10a
10/23/84
PPb
0.390
0.390
ND/0.547
3.33
85.469
134.176
6.833
0.833
IND/0.153I
| 0.2111
68.311
376.541
Sewer
Incin.
Area #1
G
1437
S12
10/23/84
PPb
9.174
138.755
189.483
869.902
30000
ND/23000
14.326
303.584
I 292.7521
1 988.0421
4300
35000
Sewer
Incin.
Area #2
G
1500
S13
10/23/84
ppb
ND
0.0339
0.0681
r 0.375
r 1.289
0.723
NO
:.0516
1 0.01731
0.100
1 4.047
5.754
i
a - Tetra-CDD data from CP Sil-88.
-------
scnarger:
Sample Date:
U.O. tNViKUNMtNIAL KKUFEUION AGENCY
REGION V
EASTERN DISTRICT OFFICE
Dow Chemical Process Sewer Sediments/Residue
Sample Type:
General General
8 C-8 hour flow proportioned composi
24C-24 hour flow proportioned composi
EVC-Equal volume composite
G-Grab
Sample Type
Time
Sample Number 85ER01
Date
Parameter
IV. METALS
Aluminum
Antimony
Arsenic
Barium
Beryl 1 1 urn
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Mercury
Nickel
Potassium
Selenium
Silver
Sodium
Thallium
Tin
Vanadium
50
Sewer
G
1258
S05
10/23/84
mg/kg
(own)
988
12
ND/5.5
57
ND/0.8
ND/1.4
ND/ 20
43
ND/2.9
61
15600
4.1
494
91
1.8
37
1280
2.0
3.2
1860
ND/3.1
ND/8.6
6.4
100/200
Sewer
G
0909
S06
10/23/84
mg/kg
(oom)
2430
ND/ 15
ND/5.9
22
ND/0.8
ND/1.5
28700
67
ND/3.1
32
20100
4.6
6930
157
0.15
16
2610
ND/1.3
ND/3.4
461
ND/3.3
ND/9.1
11
300
Sewer
G
0933
SOS
10/23/84
mg/kg
(oom)
1570
ND/ 14
18
13
ND/0.8
2.6
6550
256
ND/2.9
21
4160
ND/2.7
851
33
ND/.16
24
1770
ND/1.2
4.9
249
ND/3.0
9.7
8.8
500
Sewer
G
1343
S10
10/23/84
mg/kg
(com)
771
464
ND/ 10
30
4.6
4.0
18500
86
ND/5.3
22
19800
7.5
2780
66
0.66
13
1350
ND/2.3
6.4
1370
ND/5.6
ND/ 16
7.6
Sewer
Incin.
Area #1
G
1437
S12
10/23/84
mg/kg
(oom)
7220
151
65
125
9.8
ND/4.8
180000
667
ND/9.8
168
27200
ND/9.4
87100
561
0.14
96
14600
ND/4.2
11
11400
ND/ 10
ND/ 29
59
Sewer
Incin.
Area #2
G
1500
S13
10/23/84
mg/kg
(oom)
3230
151
16
111
8.1
ND/4.2
29300
195
ND/8.6
238
12800
13
16700
136
0.16
69
5130
7.5
17
?970
ND/9.2
44
29
Zinc
31
195
381
187
556
274
-------
Dlscnarger:
Sample Date:
REGION V
EASTERN DISTRICT OFFICE
Dow Chemical Process Sewer Sediments/Residue
Sample Type: 8 C-8 hour flow proportioned composl
24C-24 hour flow proportioned composi
EYC-Equal volume composite
G-Grab
General General
Sample Type
Time
Sample Number 85ER01
Date
Parameter
III. PCB/PESTICIDE POLLUTANTS
Aldrin
Dieidrm
Chlordane
A, 4 '-DDT
4, 4 '-DDE
4, 4 '-ODD
Alpha-endosulfan
Beta-endosulfan
Endosulfan sulfate
Endrln
Endrln aldehyde
Heptachlor
Heptachlor epoxlde
Alpha-Bhc
Beta-BHt
Gamma-BHC
Delta-BHC
PCB-1242
PCB-1254
PCB-1221
PCB-1232
PCB-1248
PCB-1260
PCB-1016
Toxaphene
Endrin ketone
Methoxychlor
50
Sewer
G
1258
SOS
10/23/84
ug/g
(ppm)
ND/1.2
ND/2.4
ND/12
ND/2.4
ND/2.4
ND/2.4
ND/1.2
ND/2.4
ND/2.4
ND/2.4
ND/2.4
ND/12
ND/1.2
ND/12
ND/12
ND/12
ND/12
ND/12
ND/24
ND/12
ND/12
ND/12
ND/24
ND/12
JJP7£4
ND/2.4
hlO/12
100/200
Sewer
G
0909
SOS
10/23/84
ug/g
(ppm)
ND/12
ND/24
ND/24
ND/24
ND/24
ND/24
ND/12
ND/24
ND/24
ND/24
ND/24
ND/12
ND/12
ND/12
ND/12
ND/12
ND/12
ND/120
ND/240
ND/120
ND/120
ND/120
ND/240
ND/120
ND/240
ND/24
ND/120
300
Sewer
G
0933
SOS
10/23/84
ug/g
(ppm)
ND/.2
ND/.4
ND/.4
ND/.4
ND/.4
ND/.4
ND/.2
ND/.4
ND/.4
ND/.4
ND/.4
ND/.2
NO/. 2
ND/.2
ND/.2
ND/.2
ND/.2
ND/2
ND/4
ND/2
ND/2
ND/2
ND/4
ND/2
ND/4
ND/.4
ND/2
500
Sewer
G
1343
S10
10/23/84
ug/g
(ppm)
wn/1?
ND/24
ND/24
ND/24
ND/24-
ND/24
ND/12
ND/24
ND/24
ND/24
ND/24
ND/12
ND/12
ND/12
ND/12
ND/12
ND/12
ND/120
ND/240
ND/120
ND/120
ND/120
ND/240
ND/120
ND/240
ND/24
ND/120
Sewer
Incin.
Area #1
G
1437
S12
10/23/84
ug/g
(£pm)
NR/1.2
wn/2. 4
ND/2.4
ND/2.4
ND/2.4
ND/2.4
ND/1.2
ND/2.4
ND/2.4
ND/2.4
ND/2.4
ND/1.2
ND/1.2
ND/1.2
ND/1.2
ND/1.2
ND/1.2
ND/12
ND/24
ND/12
ND/12
ND/12
ND/24
ND/12
ND/24
ND/2.4
ND/12
Sewer
Incin.
Area #2
G
1500
S13
10/23/84
ug/g
(pprn)
wn/i?n
Kin/240
ND/240
ND/240
ND/240
ND/240
ND/12Q
ND/240
ND/240
ND/240
ND/240
ND/120
ND/120
ND/120
ND/120
ND/120
ND/120
ND/1200
ND/2400
ND/1200
ND/1200
ND/1200
ND/2400
ND/1200
ND/2400
ND/240
ND/1200
-------
ischargcr: Dow Chemical Co. Midland Plant
anple Date: septaii-cr 1-30, 19U1
U.S. ENVIRONMENTAL PROTECTION AGENCY
REGION V
Eastern District Office
Conventional Water Sairples
S**pl« Typ*: 0 C-B dour flow proportioned co»poi!t
Z^C-i1* Imui flow proportioned ccxnpoiit-
EVC-lqual Volume Composite
*• •.
C-Cr«b
MPLE TYPE
ME
OW. MQD '
nPCRATURE C
(S.U.)
INDUCT IVITY /rt»/Cm
\RAHETER
ORGANICS (Continued)
E. Other Extractables U) (Cent!
Pcntanone,hvdroxv methyl
Ben7.nldehvde
1,1'Biphenyl ,z-pneno*y
1,1'Bionenyl ,4-phenoxy
1,1 Biphenyl
Alkyl benzene, CB HIA
AUcvl benzene,
C« H, ;
2-Cyclohexen-l-Ol (BJJ
2-Cvclohexen-l- one
1 , 2-Cyclohexandiol
Cyclohexone
2-Propanol,l-
l-Propanol,2-
2-methoxy , prop
2-hydroxy»prop:
Benzamide , N-butyl
Qxybis propanoi
\\
SURVEY *1 1}
i.H.
Intake
4 EVC
0808-
no^i
12.4*
19-21
7.7-6.0
210-
230
Gross
*/Oay
wed)
—
—
—
—
—
—
—
~
—
xy
*X
—
—
TU.R.
Intake
24 EVC
073&-
OfilO
65,0*
22-24
7.9-83
330-
MO
Grots
//Day
—
_
—
—
— .
—
~
--
—
—
—
•—
-
002
24 EVC
0844-
0906
5.5*
32-34
G.0-7.4
>OSS
*/Day
~
—
—
—
~
~
—
—
—
—
—
—
•••»
005
24 EVC
0737-
0650
5.2*
22-27
7.7-8.3
700-
900
Cross
I/Day
—
—
—
~
~
— •
—
—
— '
—
—
—
012
24 EVC
0955-
0840
34.6*
25-27
8.1-8.2
Gross
*/Day
—
—
—
.__
—
~
—
—
—
— —
—
—
031
24 EVC
0950-
0730
34.8*
21-26
0 7-7.2
3700-
3800
Cross
//Day
—
—
—
--
—
—
—
—
— -
' —
Vow •
Corn.
24 EVC
0925-
0920
1.87*
25-30
Gross
*/Day
—
—
~
-—
—
—
—
~
~
—
SURVEY #2
L.'H.
Intake
24 EVC
1108-
0550
12.4*
18-20
7.I-7.C
220-
240
Cross
*/Day
— —
—
—
—
—
—
—
--
TU.R.
Intake
24 EVC
0720-
0435
65.2*
18-20
7.1-8.2
500-
650
Gross
I/Day
—
— —
~
—
—
—
—
—
031
24 EVC
0900-
0635
34. G*
10-20
C.7 - 7.0
4000-
5000
Cross
//Day
—
—
—
—
—
—
SURVEY 13
..H.
Intake
34 EVC
.002-
Q521
12.4*
14-16
7.1-7.5
230-
260
Gross
I/Day
1.30
0.16
—
~
—
Tit.R.
Intake
«
0450
55.0*
16-18
C.9-8.3
500-
680
Cross
//Day
—
—
—
—
031
24 EVC
0900-
OS42
27.3*
17-20
6.0 -7.4
4800-
5400
Gross
I/Day
1.30
—
—
—
—
—
— —
Dow
Corn.
24 rue
1020-
OC-10
1.87*
20-23
Gross
//Day
0.15
0.04
2.20
3.00
--
—
—
—
~
SURVEY t4
L.H.
Intak
24 EVC
0917-
0518
12.4*
12-16
7.0-7.3
210-
280
Gross
'/Day
—
—
—
—
—
1.45
0.33
—
Tit.R
Intak
24 EVC
0800-
0504
65.7*
10-15
70-80
450-
700
Cross
'/Day
6.S6
—
—
—
2.00
1.59
—
031
24 EVC
0948-
055$
45.0*
11-17
C !• - 7.4
2400-
4000
Gross
*/Oay
—
--
— .
—
—
—
101.35
60.05
277(3
33.03
C
/
—
*Dow Est. B4 - Blank oontamination Survey 14
— • Less than detection '
(1) « Cone, based on a comparison of the total ion area of the oorpound
with that of an internal std.
-------
Discharger: Dew aionicnl Co. Midland Plant
Simple Date: September 1-30, 1981
U.S. EHVIRONMENTAl PROTECTION AGlNCY
REGION V
Eastern District Office
Conventional Water Sarrples
Sample Typ*: 8 t-0 hour Mow proportioned
J|'"hnnf»
Mr»t-hylerx? chloride ffi!34^
TTJ chiorof luorcrosthf*^
*/~UiivnJv>rpsHiy-iens . _
t , l-Dichloroethane
Chloroform (°134)
T~ '
1,2-Dichlorootnano (»134)
1,1, 1-TricMoroothano
tcorijon TotrAchloricie
Brorodichloranethanc (°4)
1 r 2"*Dicliloropropano
Trichloroethyleno
Dibrcmochloranethane
1,1,2, 2-Tetracnloroethane
Toluene
Chlorobsnzene
Chloroetnane
Trans-1 ^-DichloroethylenS1 '
Bronoioon
SURVEY 1)
L.H.
Intake
G
2238
12.4*
20.0
7.8
220
Gross
I/Day
—
__
_-
_
3.6
—
"*~
0.78
~- ' '
0.9^
—
N
TH.R.
Intake
G
2130
65.0*
24.0
8.2
380
Grots
*/D»y
_
_
—
..
— .
—
—
—
_
•"•
•=
F=l
002
G
23SS
5.5*
33.0
7.4
iross
l/Diy
.
— .
1.6
2*6
.9
P,*o
4, 50
0.20
«»*•
0.10
i 10
o.u
~1.30
•nu~
M
005
G
1751
5.2*
27.0
8.1
850
Grot*
I/Day
__
0.2
—
—
—
—
—
_«
—
••«•
012
G
0043
34.6*
27.0
8.15
Gross
I/Day
__
__
---,--•
—
—
—
— -
—
.„.
"*-
^>aw
—
031
#
34.8*
5.8/6.J
3800/
J / V/V
Cro$*
I/Day
—
^tf*?
*zZ~tf£*
^--fTTsi
iLJ«rr.4
^P-— 'tTJi
°^
-------
APPENDIX B-2
Conventional, Nonconventional, and Toxic Pollutants
1984 USEPA Study
-------
APPENDIX B-l
Conventional, Nonconventional, and Toxic Pollutants
1981 USEPA Study
-------
Discharger: Dow Chemical Co. Midland Plant
Sample Date: Septcnbcr 1-30, 1901
U.S. ENVIRONMENTAL PROTECTION AGENCY
REGION V
Eastern District Office
Conventional Water Sanples
Sample Tyfx: 8 C-8 hour flow proportioned
Jlit-J^ hour flow proportioned
iVl-tqual Volume Composite
C-Cr*b
SAMPLE TYPE
TIKE
FLOW* MOO
TEMPERATURE *C
PH (S.U.)
CONDUCTIVITY unho/cm
PARAMETER
I. ORGAN'ICS (Continued)
B. Pesticides/PCBs
Aldrin (la)
o-BHC (lc)
4.4--DDD Ha)
4 , A ' -nw 1 1 £•)
d,4'-mrr f2a)
nir.lrlrin n&\
rrv-Vyailffln T
HoplvirtOnr
PTR-1242
._ PCB-1254
R-RMT
Endrin
PCB-1260
v-BHC
•
a » Confirmed on second colur
b • Not confirmed on second <
c • Mot confirmed on second <
— - Less than detection
SURVEY 11
L.H.
Intake
24 EVC
0808-
1923
12.4*
19-21 -
7.7-8.0
210-
7V>
Gross
*/Oay
—
—
__
— —
^ _.
__
—
<••••
nn GC/B
x>l\mn
»lumn
TU.R.
Intake
24 LVC
0735-
65.0*
22-24
r.9-8.3
300-
•n n
Cross
'/Day
—
—
__
__
_
m •
•«
002
24 EVC
0844-
090^
5.5*
32-34
6.0-7.4
>ross
_ .
o.or-'
__
0 Mc
__
__
—
MM
CO
3C/ECD
OG/ECD due tD
005
24 EVC
0737-
06^0
5.2*
22-27
7.7-0.3
700-
Cross
. //Day
—
—
__
n pic
——
„
^.v*
—
interfe
012
24 EVC
0955-
OB40
34.6*
25-27
8. i - 0.2
Gross
*/Day
0.010
0.01°
O.Ola
o ma
WM
• i^
—
rence
031
24 EVC
0950-
Q7?0
34.8*
21-26
C.7-7.2
3700-
3800
Cross
'/Day
0.06a
—
o mb
VM
o'o^b
o.ni°
0 01
.
Dow
Corn.
24 EVC
0925-
0920
1.87*
25-30
Gross
I/Day
— .
— „
— ^_
J?.Q7,
0,01
* Do
(1) Bl
(2) Bl
SURVEY 12
L.H.
Intake
24 EVC
1108-
0550
12.4*
18-20
7.1-7.6
220-
?40
Cross
'/Day
—
_ —
^^
__
w Est.
ank con
ank con
TU.R.
Intake
24 EVC
0720-
0435
65.2*
18-20
7.1 - 87
500-
C50
Gross
l/Oay
0.02D
—
-^^ _
—
tandnat
tondnat
031
24 EVC
0900-
Q634
34.6*
18-20
0.7 -7.0
4000-
5000
Cross
'/Day
0.06a
o.o?b
n.ni"
Q,.QIa
ion dur
Jon dux
SURV Y 13
L.H.
Intake
24 EVC
1002-
0521
12.4*
14-16
7.1 - 7. 5
230-
Gross
I/Day
o.ooib
6.6610
0 002a
0.004b
H
0.001a
ing fix
ing thi
TU.R.
Intake
24 EVC
0735-
55.0*
16-18
6.9-83
500-
GDO
Cross
//Day
6.01L
_
—
•st sun
jcA sun
031
24 £VC
0900-
0542
27.3*
17-20
C.8-7.4
4800-
5400
Gross
*7Day
JULO
0.09
0.2
«y
«y
Dow
Corn.
24 J.VC
1020-
0040
1.87*
20-23
Cross
//Day
0.004
DJQQ3
**»
SURVEY 14
L.H.
Intat
24 LVC
0917-
0518
12.4*
12-10
7.0-7.3
210-
280
Gross
'/Day
•••>
- __
> «
w
•»
1
TU.R
Intak
24 L"VO
0800-
0504
65.7*
10-15
7.0 -8.0
450-
700
Cross
r/Day
—
0 Olc
0 02b
0 02b
0.02b
— _
_M
—
031
24 CVC
0940-
0555
45.0*
11-17
C5-7.4
2400-
4000
Gross
I/Day
0.21J
—
0.01L
__
0, 0217
0.01b
-------
scharger: Dew Chanicftl Oo. Midland Plant
auo: SepUjiJjcr 1-30, 1901
U.S. ENVIRONMENTAL PROTECTION ACEHCt
RICIOK V
Eastern District Office
Conventional Water Sanplcs
Sample TyjH.: 8 C-8 hour flow proportioned
J^C-?V hour flow proportioned co»>poili«
lVC-tqu»l Volume Composite
C-Cr«b
it rm
, M3D
ERATURE "C
/0»y
—
—
_j w
mf^
7ft
031
24 EVC
0900-
ftr,0
27.3*
17-20
6.8-7.4
4800-
^/Iftfi
Gross
//Day
— •
—
—
Tr.-w-o
0.13
fl-Vq
0.^2
7.1
n ^t
•Qrace
Dow
Corn.
24 ivq
1020-
nr,40
1.87*
20-23
Cross
//Day
—
0.61
—
0.1J
—
•»•
rT^
0.02
SURVEY «<
L.H.
Intak
24 IM.
0917-
DS1B
12.4*
12-16
7.0-7.3
210-
?sn
Gross
'/Day
—
—
—
—
—
_
K39
ft ?1
T ^?
_.i..2a
n 17
Croii
//D*r
*Dcw Est. . **Blan)t ContnminatJgon Survey II ( f4
— Less than detection
***Blanlc Contionination Survey 12 t 3 ****Blank Contaninaticn Survey 14
-------
ischarger: Do1 C!«iu.cal Co. Midland Plant
anple Date; September 1-30, 1901
U.S. ENVIRONMENTAL PROTECTION AGENCY
REGION V
Eastern District Office
Conventional Water Sanples
Sample Type: 0 C-D lx>ur flow proportioned cowpotlte
?liC-7H lii.u/ flov proportioned composite
CVt-(.|u»l Vi>lutJ>w«
Elhylhrjnzpne
Xylono
Kthvl methv benzene
Dichjoroothvl benzene
TVstradecnnoic acid
— Hewsdicanoic acid
— Ttoni*M]rtide.N-N-dijiii*thy;i
Al>vl benzene C,^ H,Q
Biohenvl *"
Benzene, 1 , 1-oxvbis
BiDhenvl.ethvl
Benzoitacid
Dimethyl Dhenol,isomsr of
Diostvl adipate (833)
M>thane,sulfonvl bis
Ethane, l.l'0xybis(2-msthoxy)
T^trachloro benzene
*Dow Est. &23 • BlanX cc
— • Less than detection
SURVEY 11
L.H.
Intake
24 EVC
0808-
0923
12.4*
19-21
7.7-0. 0
210-
230
Gross
#/Day
—
__
__
....
_
__
_-
—
_
—
—
--
— •
--
Mitominj
Tlt.R.
Intake
24 EVC
0735-
0030
65'.0*
22-24
7.9-8.3
380-
510
Gross
~
__
__
__
__
__
—
—
—
—
—
—
—
—
—
—
ktion Si
002
24 EVC
0844-
0906
5.5*
32-34
6.0-7.4
iross
#/Oay
— —
__
__
4.10
0.70
0.90
6.90
0.50
—
—
—
—
—
~
—
"
arvey 1
005
24 EVC
0737-
OG50
5.2*
22-27
7.7-8.8
700-
900
Cross
I/Day
—
__
__
__
__
__
—
0.30
0.30
—
— .
—
—
—
—
2(3
012
24 EVC
0955-
OfMO
34. C*
25-27
8. 1 - 8.2
Gross
I/Day
—
__
—
„
__
—
—
—
2.60
—
—
—
—
— .—
• (1]
031
24 EVC
0950-
0730
34.8*
21-26
6.7-7.2
3700-
' 3800
Gross
//Day
11.90.
0.80
1.20
—
—
—
—
—
—
—
—
—
—
» Corx
an .
Oow •
Corn.
24 LVC
0925-
1.87*
25-30
Gross
I/Day
~
—
—
—
—
—
—
—
—
—
—
1.30
12.50
10.90
1.60l
3.90
6.90
:. basa
Internal
SURVEY 12
L.H.
Intake
24 EVC
L108-
12.4*
18-20
7.1-7.6
220-
240
Gross
*/Day
-
~
—
—
—
—
~
—
--
—
—
—
— .
—
—
0.88
1 on a <
L std.
TH.R.
Intake
24 EVC
0720-
65.2*
18-20
7.1-8.2
500-
650
Gross
*/Oay
~
—
—
—
—
—
—
~
—
—
—
—
—
xmpari
031
24 EVC
0900-
34.6*
18-20
6.7-7.0
4000-
5000
Gross
X/Day
6.30
—
—
—
—
—
0.09
—
—
—
17.0
0~9T"
^0.38
' 6.18
son of
SURVfY J3
..H.
Intake
24 EVC
1002-
12.4*
14-16
7.1-7.9
230-
260
Gross
I/Day
—
—
—
—
—
•—
—
—
—
—
—
—
3.10
the tot
Tlt.R.
Intake
24 EVC
0735-
55.0*
16-10
M)0-
C80
Cross
//Day
—
—
--
—
—
—
--
—
—
—
—
—
__
1.00
al ion
031
24 KVC
0900-
27.3*
17-20
C 6- 7.4
4800-
5100
Gross
*/Day
*
9.80
—
—
—
—
—
—
—
—
—
—
—
0.59
0.43
area ol
Dow
Corn.
24 LVC
1020-
1.07*
20-23
Gross
'/Day
—
—
—
—
—
—
—
—
—
' the cc
SURVEY »<
L.H.
Intaki
24 LVC
0917-
12.4*
12-16
7.0-7.3
210-
?80
Gross
#/Day
*
—
—
—
—
—
— •
—
.—
—
"186
XTpound
Tlt.R
Intake
24 EVC
0000-
0504
65.7*
10-15
7.0-8.0
450-
700
Cross
f/Oay
—
—
--
—
—
—
—
—
—
—
—
41
with U
031
24 EVC
0948-
0555
45.0*
11-17
6.5-74
2400-
4000
Gross
•'/Day
45.04
—
—
—
—
— —
— —
—
—
—
—
—
30
TT3T-
ut of
f;
-------
Discharger: Dow ClKmlcal Co. Midlord Plant
Sanple Date: September 3-30, 1901
U.S. ENVIROUrtENTAl PROTECT I OK AGENCY
RECIOK V
C*sterr> CM strict Office
Conventional Hater Samples
S*mplc Type: 8 C-8 hour flow proportioned co*votltr
2VC-7V hour flow proportioned coxipos i (•
[VC-|<|ii*l
C-Ur»b
4-
V^LG TYPE
IKE
-ov , MOD '
WERATURE »C
H (S.U.)
ONOUCTiVITY unto/on
ARAMETEK
. ORGANICS ftontinncdl
C. Herbicides
Dichloroprop
2.4-D
2.4,5-T
D. Acid Extractafoles
•Pfvsnol
CvclohoxaneT rHchlorO fiBi)
2-ProrviiTTl , 1 f 7-methoxv-l
nr'tihylffthmrv^ oc isor«»r^
?i*> rvr1ohexadienp-j,4^jyr
* W?ir9
SURVEY 11
L.H.
Intake
53 oS^*
L2.4*
L9-21
7.7-8.0
" 230
Gross
#/Day
—
Trace
2.50
ra
7U.R
Intake
U EVC
)735-
i5.0*
12-24
7.9-0.3
380-
510
Cross
_ajS.
0.02
12.50
002
24 EVC
0844-
5.5*
32-34
6.0-7.4
iross
—
0.07
a. 02 _
n.n?
•«•
005
24 EVC
3737-
5.2*
22-27
7.7- 83
700-
900
Cross
'/Day
0.001
Trace
—
1.10
•••»
012
24 EVC
0955-
34.6*
25-27
8,1-8.2
Gross
*/Day
0.32
0.03
0.0?
Trace
—
031
24 EVC
09DO-
:mo
34.8*
21-26
6.7-7.8
3700-
3800
Cross
//D*y
T5-1
SL3SL-
0.28
n.Vi .
I.?1!,,
—
A.Vt
3.90
Dow •
Corn.
24 EVC
0925-
0020
1.87*
25-30
Gross
«/Day
0.001
O.OQ1.
Trace
-an, i. ..
SURVEY 12
L.'H.
Intak
24 EVC
11 OS-
OS r>0
12.4*
18-20
7.1-7.0
220-
240
Cross
'/D«y
—
—
~
Ttt.R
Intak
24 EVC
0720-
65.2*
18-20
7.1-8.2
500-
650
Gross
I/Day
fLr*
— .
—
031
24 EVC
0900-
34.6*
18-20
6.7- 7.0
4000-
5000
Gross
//Day
Tjcacs
JJ.JML.
SURVLY 13
1..H.
Intake
24 EVC
1002-
0521
12.4*
14-16
7.1-73
230-
260
Gross
*/Day
0.01
0.07
Tit.R.
Intake
24 nvc
0730-
55.0*
16-18
6.9-6.3
500-
680
Gross
//Day
—
—
031
24 I.VC
0900-
27.3*
17-20
0.8-74
4800-
5400
Gross
I/Day
0.30H
0.40
Trace
3,40_
Dow
Corn.
24 KVC
1020-
oc.-io
1.87*
20-23
Cross
0.002
JD..Q0/L
Trace
0.2
^
SURVEY *4
L.H.
Intak
24 EVC
0917-
0518
12.4*
12-16
7.0-7.3
210-
280
Gross
0.01
—
~
Tit.R
InUk
24 I.VC
0800-
OS04
65.7*
10-15
7.0 -e.o
450-
700
//Djy
0.0>,
0.08
—
031
24 LV^
09-18-
OD55
45. 04
11-17
6.5-7.4
2400-
4000
Gross
r/Diy
0.22
2.14
0.18
Trace
Trace
0.26
^
Crc
//O
*Cow Est. ' i^ - Blank contamination Survey II
— " Less than detection
(1) - Cone, based on a comparison of the total ion area of the oenpound with that of
an internal std.
-------
narger: Dew Comical C\>. Midland Plant
;le Date: Septtufccr 1-30, 1901
U.S. ENVIRONMENTAL PROUCTIOH ACtNCY
REC.ION V
Cistern District Office
Oonventlonal Water Sanples
Typ«: 6 f 8 Ixiur
(VC~l<|u*l
C-Cr«t>
flow proportioned
flow proportioned compos I tt
Co«vovlt«
IE TYPE
', M3D
ERATURE *C
(S.U.)
ACTIVITY virho/cm
XMETCR
. METAUS
Arsenic
r/irjm< tin
fhrrrMin
fVipprur
T/vid
J.inc
T. fYY\A/F.yri[p[>y\i,
TDS
TSS
BOD-5
ran
•nrr
NH3-*1
TKN
NO, + MT1
ItaEa 1 Phrtvnhrtn ia
Chloride
— Fluoride
Sulfat^
Phenol (AAAP)
cvanid*
SURVEY
L.H.
Intake
24 EVC
0008-
Anoo
12.4*
19-21
7.7- 80
210-
Gross
I/Day
—
vw
_
^ £.7Q
5.0
14170
520
620
. tt.9_
JJ.3-
34.1
930
1760
_=_
TH.R.
Intake
24 EVi
0735-
nnin
65.0*
22-24
7.9-0.3
380-
Cross
//0»y
__
w.
.s.
J.BO
_„
4.9
178890
4880
" ioeo"
_Ui3fi.
3 60
330
27
>1'690
2253d '
002
24 EVC
0844-
5.5*
32-34
6.0-7.4
Jross
*/Oay
_.
•M.
2LJDL
0-30
_
JL1CL.
14910
J^60
206Q
460
30
39
2890
1610 '
11 .
005
24EVC
0737-
5.2*
22-27
7.7-8.3
700-
onn
Cross
f/Day
-
0.
2(
__
Q.43
0.35
„».
0.4.F
L.
2082i
»
130
1520
J9Q
—
30
10
»
6030
S
w
012
2412VC
34.6*
25-27
0.1-0.2
Gross
I/Day
—
__
P. 58
••—
2.90
86289
7790
_
5190
200
180
11540
57
11250
031
24EVC
0950-
0?30
34.8*
21-26
6.7-7.2
3700-
Cross
f/Doy
—
__
2,30
0.58
_
18^0
810000
1450
—
34540
1640
1860
115
1 irt
J.JU
340000
i AiW
" 8
Dow '
Corn.
24IVC
1.87*
25-30
Gross
I/Day
_
__
J.2.5Q
-JL2JL
1.70
74720
1840
2680
J9J58J?
^150
t 835
880
16
42116
— 12..
SURVEY *2
L.H.
Intake
24EVC
12.4*
10-20
7.1- 7.C
220-
Cross
'/Day
—
_.
__
_iJ31
2.69
14170
620
105
—
— JJL
34
830
10
1655
_UL_
Tit.R.
Intake
24 EVC
65.2*
18-20
7. i - 8.2
500-
Gross
~
_
1.10
4. cm
174000
14140
1090
-1700.
4350
_.
375
375
' 97
ft
1.9030
lop
22840
-JiL
031
24 EVC
34.6*
18-20
6.7-7.0
4000-
Cross
X/Ojy
6.87
—
3.60
1.40
—
26.8
789500
2600^
1445
29150
6060
1750
2070
104
B7ftfK
6,1
J1L_
SURVEY IJ
..H.
Intake
24 EVC
12.4*
14-1G
7.1- T.8
230-
Gross
I/Day
—
— .
—
5.10
0.50
1.20
11790
206
413
6.2
19.6
827
ii&
J1L-.
TU.R.
Intake
24 EVC
55.0*
16-10
0.9-8.3
500-
Cross
//D«y
—
—
0.90
1.00
1.4C
135320
6880
1380
9630
3670
270
73.3
•mir
igfef
-1L-
031
24 KVC
0000-
OS4?
27.3*
17-20
fc 0 - 7.4
4000-
Gross
e/Oay
—
—
3.20
23.2
676440
3640
'"1370
^8480
5460
1310
1700
U.4
30282C
_J60
63750
2.5
JiLJ
Dow
Corn.
24 I^VC
1.87*
20-23
Cross
—
—
—
—
—
^554TJ
9^80
lllfi
T70
740
2.8
— 2TT
s. /
^37430
.4
"CD"
' SURVEY »4
L.H.
InUki
2J?1
12.4*
12-16
70-7.3
210-
Gross
*/Oay
— ~*
—
"•"
-2.-30-
1241Dj
1^50
~
11.4
17.6
930
IbbO
(1)
Tit.R
Intake
W
65.7*
10-15
70- 0.0
450-
700
Cross
'/Day
~
—
1.64
2.1s
•T.-38-
^06030
1^603
—
8V?C
5480
43C
143C
• ' yj t
ft,i
54. £
yj
031
24 EVC
0948- •
0555
45.0*
11-17
05-74
2400-
4000
Gross
#/Ojy
~
—
3.75
1.13
39. K
961520
71 30
15do
_4J?83
7680
1180
1630
413
1 4o
4Z704U
751
'T'U
Cros
. (1).Not analyzed
•— « Less than detection
-------
Discharger: r^ Oicmical Oo. Midland Plant
Sanplc Date: 5V-ptaiiIxir 1-30, 1981
U.S. ENVIROUMCHTAl PROTECTION AGENCY
REGION V
Eastern District Office
Conventional Water Sanples
Sample Type: 0 C-8 lour
Jl«f.-7^ hour
lVl-Ii|u»t
C-trab
flow proportioned
flow proportioned
* Composite
WM»Lt TYPE
IMt
LOU, M3D
CMPERATURE »c
« (S.U.)
ONOUCTIVITY yhtO/OT
ARAMETER
. OK-A^JC? (Contiwpd*
G. Other VolotUe9UJ
/•^U){\rM> , (IJTWj^Jioxv
Eth.inc. 1.1'Qxvbis
Ethane.. J , 1 . 1 .. 2-iTPl.rnnhlnrr1
Dtaizcnc^ othenyl
Itoicaittx-dincUiyJbisaicrs^j
Ik'Jiycvx.'. oDtvL-iftQncrs ~
lp 11 V
—y Ii
V^ppprvuvw*
i ^V*^^"l^V>v'"*rv* "f^^hMl
fctithanftt__l-j-iinr.t-tx«y.., . „
7«<~hTnmpr<^paiv» .
Br/ynnn| ?r?'-Ovyh<«
Brnpi^nni, 1 , 1 f 1 -Tri rfil nm ^^
2=Rll«-J>tv^1 _, 5-Vlftt-hyl
».^h>vyb
SURVEY 11
L.H.
Intake
G
2238
12.4*
20.0
7.0
220
Gross
*/Day
—
—
.-si.—
^w
rr-_,.
•*••
TU.R.
Intake
G
2130
65.0*
24.0
8.2
300
Cross
f/Day
—
-!•
• !
^^
I~T
-ai*
.FT., —
002
G
MM
5.5*
33.0
7.4
iross
I/Day
— •
—
in.r.o
.24*40.
_JUO.
AA nn
"•-T— 1
__
js:
005
G
17-51
5.2*
27.0
U.I
850
Cross
//Day
—
— •
-!•" -
012
G
0043
34.6*
27.0
8.15
Gross
i/Oay
—
—
--- ..
«••
.-* _
— —
031
a*
34.8*
C.8/6.-
3800/
, T70O
Cross
I/Oay
^i!?^
;^->?vr
—
p r
-
;&*"-
mrmf
—
Dow •
Corn.
G
2310
1.87*
27.5
Gross
*/Day
—
.608
— .
jua_
1-7. ?n
— •
T\ Q
— —
—
SURVEY 12
L.fc.
Intake
G
?225
12.4*
19.5
7.4
220
Cross
'/Day
~
—
«••
— ,
—«•
—
Tit.R
Intake
G
2020
65.2*
20.0
7.1
510
Gross
I/Day
—
—
.— —
— -
-^
^^
(1)
031
Cross
//Day
i
\ 1
47"
_i-Z_
~~y"
I
y\
i\
i \
i \
i-^
SURV
L.H.
Intake
G
2340
12.4*
16.0
7.4
260
Gross
f/0a>
—
—
—
ir~TV
•— ^
TH.R.
Intake
G
2000
55.0*
1C.O
0.0
500
Cross
>/0»y
—
—
—
^•^
__
~
Y 13
03)
G
.204 5._
27.3*
19.0
7.2
4900
Gross
'/Day
21. W
~O6'
—
^mm
--
Dow
Corn.
G
?205
1.87*
23.0
Cross
//Day
—
~1S3
—
Ji?- .
L U)3
-S3
in
0 97
0.47
_0,28
SURVEY *4
L.H.
Intak
f!
1735
12.4*
12.0
7.0
210
Gross
'/Day
—
—
—
"*m-
—
Tit.R
Intak
G
1710
65.7*
10.0
8.0
520
Cross
//D*y
—
—
—
C-
__, m
--
—
031
G
1820
•:>.o«
12.0
7.3
4000
Gross
f/Day
45TD7
T.T HIT
-ZZ
|1M|J_
^•^
•
H.13
Crc
//t
Est. (1) MO volatile samples
Less than detection
(2) Cone, based on a ccnpariscn of the total ion area of the ocnpound with that
of an internal, std.
-------
CASE */SAS «: 3068 LABORATORY: IT/WCTS
DATE REC'D: 08/16/84 CONTRACT *: 6582
DATA RELEASE AUTHORIZED BY:
SAMPLE *: E8432
% MOISTURE: NA
ORGANICS ANALYSIS DATA SHEET
BASE/NEUTRAL AND ACID COMPOUNDS
SURROGATE SPIKE RECOVERIES
UNITS: UG/L
LAB ID COMPOUND
PHENOL-D5
2-FLUOROPHENOL
30482F11 NITROBENZENE-OS
2-FLUOROBIPHENYL
2, 4, 6-TRIBROMQPHENOL
P-TERPHENYL-D14
CONC
SAMPLE
93.
96.
96.
93.
95.
29.
CONC
SPIKED
104.
11O.
105.
103.
1O2.
49.
RECOVERY
89
87
91
90
93
59
» -
tt -
ASTERISKED VALUES ARE OUTSIDE QC LIMITS
RECOVERIES DUE TO DILUTION
RECOVERIES DUE TO MATRIX EFFECTS
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
NS - NOT SPIKED
TENTATIVELY IDENTIFIED COMPOUNDS
CONC(J) CAS tt COMPOUND NAME SCAN # FIT
/ 37? /
3*12.
/ /0
-------
CA .-Z «*/5AS ft: "3368
DATE REC'D: 03/16/34
DAi" A RELEASE AUTHORIZE
LAUORATQRY: IT/UCTS
CONTRACT ft. 6532
SAMPLE ft:
7. MOISTURE: NA
IZED 2Y: I n
_^M
(/ -X
CHGANICS ANALYSIS DATA SHEET
VOLATILE COMPOUNDS
SURROGATE SPIKE RECOVERIES
UNITS: UG/L
M. 26
LAB ID
304S2IVi2
COMPOUND
1,2-DICHLCRQETHANE-D4
TOLUENE-D8
4-3ROMOFLUOR02ENZENE
CONC
SAMPLE
4930.
4410.
4730.
CONC
SPIKED
5000.
50OO.
5000.
7. RECOVERY
99
88
95
* - ASTERISKED VALUES ARE OUTSIDE QC LIMITS
ft - RECOVERIES DUE TO DILUTION
$ - RECOVERIES DUE TO MATRIX EFFECTS
NS ..- NOT SPIKED
1
2
"}
^J
4
5
6
7
a
9
10
11
12
13
14.
13
16
17
13
25
TENTATIVELY IDENTIFIED COMPOUNDS
CAS ft CCMPOUNO NAME
MONE FOliJiD
SCAN ft
FIT
______ _
J - CCMC. GUANTITATED USING PEAK HEIGHT, ASSUMING A RESPONSE FACTOR OF 1.
-------
CASE */SAS #: 3068 LABORATORY: IT/WCTS
DATE REC'D: 08/16/84 CONTRACT *: 6582
DATA RELEASE AUTHORIZED BY:
SAMPLE #: E8453
X MOISTURE: NA
ORGANrcS-A'NALYSIS DATA SHEET
BASE/NEUTRAL AND ACID COMPOUNDS
SURROGATE SPIKE RECOVERIES
UNITS: UG/L
LAB ID COMPOUND
PHENOL-D5
2-FLUOROPHENOL
30482F25 NITROBENZENE-DS
2-FLUOROBIPHENYL
2,4,6-TRIBROMOPHENOL
P-TERPHENYL-D14
* - ASTERISKED VALUES ARE OUTSIDE QC LIMITS
# - LCu:' RECOVERIES DUE TO DILUTION
$ - RECOVERIES DUE TO MATRIX EFFECTS
CONC
SAMPLE
SC7.lt
fo.u.
f0.U~
fO.u-
fO.u
yo.u
CONC
SPIKED
1O4.
110.
1O5.
1O4.
1O2.
50.
y. RECOVERY
^ K dt
-©- 4 f-
*• r »
NS - NOT SPIKED
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
CONC(J)
TENTATIVELY IDENTIFIED COMPOUNDS
CAS # COMPOUND NAME
SCAN tt
/ Stt t
FIT
"ScoC-
loco
<=? ,
-------
CAbt. #/3AS *»• 3068 LABORATORY: IT/WCTG SAMPLE 4»- E8433
DATE REC'D: 02/16/84 CONTRACT t»: 6582 ','. MOISTURE' NA
RtLEASE AUTHORIZED BY:
ORGANICS A-ftALYSIS DATA SHEET
VOLATILE COMPOUNDS
SURROGATE SPIKE RECOVERIES
UNITS: UG/L
CCNC CONC
LAD ID COMPOUND SAMPLE SPIKED 7. RECOVERY
1,£-DICHLDROETHANE-D4 2200. 2500 88
30482N7 TOLUENE-D8 214O. 2500 86
4-BROMOFLUOROBENZENE 218O. 2500. 87
* - ASTERISKED VALUES ARE OUTSIDE QC LIMITS NS - NOT SPIKED
* - RECOVERIES DUE TO DILUTION
S - RECOVERIES DUE TO MATRIX EFFECTS
TENTATIVELY IDENTIFIED COMPOUNDS
CCNC(J) CAS 4* COMPOUND NAME SCAN * FIT
^ -fo
5
6
7
e
9
iO
11
13
14
15
16
17
IB
19
20
21
25
J -
GUANHTATED USING PEAK HEIGHT, ASSUMING A RESPONSE FACTOR OF l.
-------
CASE'*/SA5 fc. 3068 LABORATORY: IT/WCTS
DATE REC'D. 03/16/84- CONTRACT tt: 6582
DATA RELEASE AUTHORIZED BY:
SAMPLE *: EB451
'/. MOISTURE: NA
ORGAN I CS ANALYSIS DATA SHEET
BASE/NEUTRAL AND ACID COMPOUNDS
SURROGATE SPIKE RECOVERIES
UNITS: UG/L
CEu.i
LAB ID
30482F24
CONG
SAMPLE
«tOi?'J
$ -
COMPOUND
PHENOL-D5
2-FLUOROPHENOL
NITROBENZENE-D5
2-FLUOROE IPHENYL
2, 4, 6-TRIBROMOPHENOL
P-TERPHENYL-D14
ASTERISKED VALUES ARE OUTSIDE QC LIMITS
RECOVERIES DUE TO DILUTION
RECOVERIES DUE TO MATRIX EFFECTS
CONC
SPIKED
'/. RECOVERY
104. O *
110. 0 <
105. 0 *
1O4. O *
102. 0 *
50. O */
NS - NOT SPIKED
CGNC(J)
\0,oc3
L.CGO
TENTATIVELY IDENTIFIED COMPOUNDS
CAS S COMPOUND NAME
, r .
:0-*/3 ' / L', ' * &''
SCAN tt FIT
ilb'f
2
3 / / / /
4 / / / /
5 / / / /
6 / / / /_
7 / / / /
8 / / _____/ /
9 / / / /
1O / / ; / /
11 / / / /
12 / / / /
13 / / / /
14 / / __/ /
15 / / __/ /
16 / / / /
17 / / / /
18 / / / /
19 / / / /
20 / / / /
21 / / . / /
22 / / / /
23 / / / /
24 / / / /
25 / / / /
J - CCNC. QUANTITATtD USING PEAK HEIGHT, ASSUMING A RESPONSE FACTOR OF 1.
-------
Mil
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SEE HEVEMSE SIOC rOfl nCTUIUJ MAIL
Pkjic ci'Tiiili'li' jnrt iulimii two cupicj ol ilm loim
dl Ilii/ Hid I.I I'jch month Tim rcpuM niull reach ou'
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DOW CHEMICAL COMPANY
OUTFALL t 031
PROC.WASTES TO TI TTABAKASSEE R. Oil
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LIMIT
DATE
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4
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11
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COMPANY
' I 18640
MONTHLY GREETING REPORT FOR
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j jufin-nf two copies ol fhn fo'm
at ihc end ot each month This report muji reach our
Lanitnrj office t)y tlir 10th of the month
PART i - RETURN TO DEFT OF NATURAL RESOURCES
DOW CHEMICAL COMPANY
OUTFALL I Oil
PROC. HASTES TO TI TTAfi A WASSEE R, 031
PERMIT EXPIRATION:
D.llc lorm •
81/10/29
PAftAMll
NAME
UNITS
Jlbl6
COlIFORH-FECAl
HF/100HL'
LIMIT 1
DATE
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2
3
4
5
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100
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THAT 1 HAVE PtnSONALlY EXAMINED AND AM FAMILIAR WITH THE INFOnr.'AT ION SUPMIMEtl IN THIS POCUMtNI AND ALL AT1ACHMINIE A'
ODE INDIVIDUALS IMMEDIATELY RESPONSIBLE «}<\ OBTAINING THE INFORM.MION. 1 BELIEVE THAT 1HC INFORMATION IS TFUJt ATCUFIA1E A'
AF1F SIGNIIICANT PENALTIES FOR SUBMITTING F/1LSE INFORMATION INCLUDING THE POSSIOILITY OF FINE AND IVrmsoNMENT
'tT»V
-------
APPENDIX B-3
Conventional, Nonconventional, and Toxic Pollutants
Dow Chemical Data
-------
DOW CHEMICAL
OUTFALL 031/DOW CHEMICAL INTAKES/PILOT PLANT
TENTATIVELY IDENTIFIED COMPOUNDS
Sample Type:
Sample Time:
Sample Number: 84Eft06
Sampling Date:
Methane, dlmethoxy
Hexadecanolc acid
9-Octadecenanlde, (z)-
2,6,10-Dodecatrlen-l-ol. 3.7.11-
trlmethyl-, (t,e)-
Decane, 1-chloro-
Stlane, (11-chloro-undecyl)oxy
trlmethyl
Cyclohexene
1-Propanol, 2-methoxy
Methane, dfmetnoxy
1-Propene, 3-chloro
Ethanol , 2-phenoxy
[l.r-blphenyU-3-ol _
Benzeneacetlc add, alpha hydroxy__
Unknown hydrocarbons
Benzene, 1,2,3,5-tetrachloro-
Unknown
Hexane, 3,3-dlmethyc-
Outfall 031
6
0200
S12
8/29/84
ug/1
(PPb)
150 01
y
G
0853
S13
8/29/84
ug/1
(ppb)
110 01
Comp.
1206-
0853
S15
8/28-
29/84
ug/1
(ppb)
110 01
45 UK
19 UK
310 UK
' 28 UK"
32 UK
Lake Huron Intake
G
0400
SO 7
8/29/84
uy/1
(PPb)
G
0955
SOB
8/29/84
(PPb)
25 01
Comp.
1220-
0905
SIO
8/28-
29/84
ug/i
(ppb)
TUtabawassee River Intake
G
0033
S02
8/29/84
ug/1
(PPb)
G
0904
S03
8/29/84
ug/1
(PPb)
Comp.
1214-
0904
S05
8/28-
29/84
ug/1
(PPb)
•
9 J
Pilot Plant
Influent
G
0825
86ER03
S24
12/4/84
ug/1
(PPb)
210 J
15 J
11 J
21 J
14 J
69 J
17 J
55 J
20 J
21 J
21 J
33 J
13 J
55 J
13 J
14 J
Effluent
G
0857
85ER03
S25
12/4/84
ug/1
(PPb)
3cT3
10 J
23 J*
94 J
58 J*~
18 J
18 J
11 J
26 J
46 J
15 J
11 J
11 J
11 J
NOTES: J
RS
01
UK
*
Estimated concentration.
Reasonable IdenttfIcatton. retentlonal time cowpdttbility.
Isomer or similar compound.
Unknown, not In N8S library.
Coelutlng peak.
-------
ischarger:
ample Date:
U.S. ENVIRONMENTAL PROTECTION AGENCY
REGION V
EASTERN DISTRICT OFFICE
Dow Chemical Intakes/Outfall 031/Pilot Plant
Sample Type: 8 C-8 hour flow proportioned composite
24C-24 hour flow proportioned composite
EVC-Equal volume composite
G-Grab
Sample Type
Time
Sample Number 84ER06
Date
Parameter
Titta.
River
Intake
Comp.
1214-
0940
505
8/28-
29/84
ug/1
(ppb)
Lake
Huron
Intake
Comp.
1220-
0905
S10
8/28-
29/84
ug/1
(ppb)
II. ACID AND BASE NEUTRAL POLLUTANTS (continued
2-chloronaphthalene
1 ,2-dichlorobenzene
1 ,3-dichlorobenzene
1 ,4-dichlorobenzene
3,3J-dichlorobenz1dine
2,4-dinitrotoluene
2,6-dinitrotoluene
1 ,2-diphenylhydrazine
Fluoranthene
4-chTorophenyl phonyl ether
4-bromophenyl phenyl ether
Bis(2-chloroisopropyl )ether
Bi s( 2-chl oroethoxy Jmethane
Hexachlorobutadiene
Hexachlorocyclopentadiene
Isophorone
Naphthalene
Nitrobenzene
N-nitrosodimethylamine
N-ni trosodiphenyl ami ne
N-nitrosodiproplyamine
I3is(2-ethylhexyl Jphthalate
ND/ 4
NO/ 4
ND/ 4.
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/10
ND/10
ND/10
ND/10
ND/20
ND/20
ND/10
ND/20
ND/10
ND/10
ND/10
ND/10
ND/20
ND/10
ND/10
ND/10
ND/10
ND/10
ND/10
ND/10
ND/20
ND/10
Outfall
031
Comp.
1206-
0853
S15
8/28-
29/84
ug/1
(ppb)
ND/10
ND/10
ND/10
ND/10
ND/20
ND/20
ND/10
ND/20
ND/10
ND/10
ND/10
ND/10
ND/20
ND/10
ND/10
ND/10
ND/10
ND/10
ND/10
ND/10
ND/20
ND/10
85ER03
Pilot
Plant
Influent
G
0825
S24
12/4/84
ug/1
(ppb)
ND/10
ND/10
ND/10
ND/10
ND/20
ND/10
ND/10
NA
ND/10
ND/10
ND/10
3J
ND/10
ND/10
ND/10
ND/10
ND/10
ND/10
ND/10
ND/10
ND/10
ND/10
Pilot
Plant
Effluent
G
0857
S25
12/4/84
ug/1
(ppb)
ND/10
ND/10
ND/10
ND/10
ND/20
ND/10
ND/10
NA
ND/10
ND/10
ND/10
2J
ND/10
ND/10
ND/10
ND/10
ND/10
ND/10
ND/10
ND/10
ND/10
ND/10
-------
harger:
le Date:
U.S. ENVIRONMENTAL PROTECTION AGENCY
REGION V
EASTERN DISTRICT OFFICE
Dow Chemical Intakes/Outfall 031/Pilot Plant
Sample Type: 8 C-8 hour flow proportioned composite
24C-24 hour flow proportioned composite
EYC-Equal volume composite
G-Grab
Sample Type
Time
Sample Number 84EROb
Date
Parameter
TT7~ATID AND BASE HEUIUAL POLL
2,4,6-trichlorophenol
4-chl oro-3-methyl phenol
2-chlorophenoi
2,4-dlchlorophenol
2, 4-dimethyl phenol
2-nitrophenol
4-nitrophenol
2,4-dinitrophenol
4 ,6-dlnf tro-2-methyl phenol
Pentachlorophenol
Phenol
Benzole add
2-methyl phenol
4-methyl phenol
2~7$~,5-trichlorophenol
Acenaphthene
Benzidine
1 ,2,4-trichlorobenzene
Hexachlorobenzene
Hexachl oroethane
Bis(2-chloroethyl )ether
Titta.
River
Intake
Comp.
1214-
0940
SUb
8/28-
29/84
ug/1
(ppb)
.UTANTS
Np/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
iin / A
NU/ 4
ND/ 4 j
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
Lake
Huron
Intake
Comp.
1220-
0905
S1U
8/28-
29/84
ug/1
(ppb)
ND/10
ND/20
ND/10
ND/10
ND/10
ND/20
ND/100
ND/50
ND/20
ND/20
kin i\ r\
NU/1U
ND/100
ND/10
ND/10
ND/100
ND/10
ND/40
ND/10
ND/1U
ND/10
ND/10
Outfall
031
Comp.
1206-
0853
Sib
8/28-
29/84
ug/1
(ppb)
ND/10
ND/20
ND/10
ND/10
ND/10
ND/20
ND/100
ND/50
ND/20
ND/20
un/i n
ND/100^
ND/10
ND/10
ND/100
ND/10
ND/40
ND/10
ND/1U
ND/10
ND/10
SbtKU^
Pilot
Plant
Influent
ti
0825
S24
12/4/84
ug/1
(ppb)
ND/10
ND/10
ND/1U
ND/1U
ND/10
ND/10
ND/50
ND/50
ND/*n
Nn/^n
wn /in
ND/5Q
ND/10
ND/10
ND/50
ND/10
ND/100
ND/10
ND/10
ND/10
3J
Pilot —
Plant
Effluent
U
0857
SZb
12/4/84
ug/1
(ppb)
ZJ
ND/10
NU/iU
HO/10
ND/10
ND/10
ND/50
ND/50
NO 750
?J
Nn/i o
ND/50
ND/10
ND/10
ND/50
ND/10
ND/100
2J
ND/10
ND/10
3J
•••—
, i .1 i
i
J__
-------
ischarger:
ample Date:
U.S. ENVIRONMENTAL PROTECTION AGENCY
REGION Y
EASTERN DISTRICT OFFICE
Dow Chemical Intakes/Outfall 031/Pilot
Sample Type: 8 C-8 hour flow proportioned composite
24C-24 hour flow proportioned composite
Plant EYC-Equal volume composite
G-Grab
Sample Type
Time
Sample Number 84ER06
Date
Parameter
I. VOLATILES (continued)
Bromome thane
Bromoform
Bromodichloromethane
Trlchlorofluoromethane
Dlchl orodl f l uoromethane
Chi orodlbromomethane
Tetrachloroethene
Toluene
Trlchloroethene
Vinyl chloride
Acetone
2-butanone
Carbon dlsulflde
Z-hexanone
4-methyl -Z-pentanone
Styrene
vinyl acetate
Total xylenes
Tlttabawassee
River
Intake
G
0033
SOZ
8/29/84
ug/1
(ppb)
ND/ 1
ND/ 1
NO/ 1
ND/ 1
NO/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
NO/ 1
ND/10
ND/10
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
G
0904
S03
8/29/84
ug/1
(ppb)
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/10
ND/10
ND/ 1
ND/ 1
ND/ 1
NO/ 1
ND/ 1
ND/ 1
Lake Huron
Intake
G
0400
S07
8/29/84
ug/1
(ppb)
ND/ 5
ND/ 5
11
ND/ 5
NA
5J
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/100
ND/200
ND/10
ND/100
ND/100
ND/ 5
ND/10
ND/ 5
G
0955
SOS
8/Z9/84
ug/1
(ppb)
ND/ 5
ND/ 5
11
ND/ 5
NA
5J
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/100
ND/200
ND/10
ND/100
ND/100
ND/ 5
ND/10
ND/ 5
Outfall 031
G
0020
S12 j
8/29/84
ug/1
(ppb)
ND/ 5
ND/ 5
ND/ 5
ND/ 5
NA
ND/ 5
5J
ND/ 5
ND/ 5
ND/ 5
ND/100
ND/200
ND/10
ND/100
ND/100
ND/ 5
ND/10
ND/ 5
G
0853
S13
8/29/84
ug/1
(ppb)
ND/ 5
ND/ 5
ND/ 5
ND/ 5
NA
ND/ 5
5J
ND/ 5
ND/ 5
ND/ 5
ND/100
ND/200
ND/10
ND/100
ND/100
ND/ 5
ND/10
ND/ 5
85ER03
Kl lOt
Plant
Influent
u
0825
S24
12/4/84
ug/1
(ppb)
ND/10
ND/ 5
ND/ b
NA
NA
ND/ 5
5
NO/ 5
ND/ 5
ND/10
ND/10
ND/10
ND/ 5
ND/10
ND/10
ND/ 5
ND/10
ND/ 5
Hi lot
Plant
Effluent
b
0857
S25
12/4/84
ug/1
(ppb)
NO/10
ND/ 5
ND/ 5
NA
NA
NO/ 5
5
ND/ 5
ND/ 5
ND/10
ND/10
ND/10
ND/ 5
ND/10
ND/10
ND/ 5
ND/10
NO/ 5
-------
charger:
pie Date:
U.S. ENVIRONMENTAL PROTECTION AGENCY
REGION V
EASTERN DISTRICT OFFICE
Dow Chemical Intakes/Outfall 031/Pilot Plant
Sample Type: 8 C-8 hour flow proportioned composite
24C-24 hour flow proportioned composite
EVC-Equal volume composite
G-Grab
Sample Type
Time
Sample Number 84ER06
Date
Parameter
I. YOLATILES
Acrolein
Acrylonltrile
Benzene
Carbon tetrachloride
Chlorobenzene
1,2-dichloroethane
1,1,1-trichloroethane
1,1-dichloroethane
1,1,2-trlchloroethane
1,1,2,2-tetrachloroethane
Chloroethane
Bi s( chl oromethyl ) ether
2-chloroethyl vinyl ether
Chloroform
1,1-dichloroethene
Trans-l ,2-dichloroethene
1 ,2-dichloropropane
Trans-1 ,3-dichloropropene
Cis-1 ,3-dichloropropene
Ethyl benzene
Methyl ene chloride
Chloromethane
Tittabawassee
River
Intake
G
0033
S02
8/29/84
ug/1
(ppb)
ND/10
ND/10
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/10
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
5A*
ND/ 1
G
0904
S03
8/29/84
ug/1
(ppb)
ND/10
ND/10
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/10
KID/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
ND/ 1
21*
NO/ 1
Lake Huron
Intake
G
0400
S07
8/29/84
ug/1
(ppb)
ND/100
ND/100
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
60
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/10
ND/ 5
ND/ 5
ND/ 5
G
0955
SOS
8/29/84
ug/1
(ppb)
ND/100
ND/100
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
NU/ 0
ND/ 5
wn/ 5
50
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/10
ND/ 5
ND/ 5
ND/ 5
Outfall 031
G
0020
S12
8/29/84
ug/1
(ppb)
ND/100
ND/100
ND/ 5
17
ND/ 5
5.8
ND/ 5
ND/ 5
ND/ 5
ND/ 5
NU/ 0
ND/ 5
ND/ 5
?0
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/10
ND/ 5
11*
ND/ 5
G
0853
S13
8/29/84
ug/l
(ppb)
ND/100
ND/100
ND/ 5
17
ND/ 5
6.2
5J
ND/ 5
ND/ 5
NO/ 5
ND/ 5
wn/ 5
?0
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/10
ND/ 5
10*
ND/ 5
85ER03
•
TTToT —
Plant
Influent
0825
S24
12/4/84
ug/1
(ppb)
NA
NA
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ S
N&/16
NA
ND/10
NO/ 5
ND/ 5
NO/ 5
ND/ 5
ND/ 5
ND/ 5
NO/ 5
18*
ND/1fl
TTToI —
Plant
Effluent
G
0857
S25
12/4/84
ug/1
(ppb)
NA
NA
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/10
NA
ND/10
11
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
ND/ 5
?1*
Np/in
.1 • • •
-------
.ii
OW CHEMICAL
IDLAND OIV
UPLAND
ACUtIV NUMBIII I
364004 1
COMPANY
••:
08640
PIW.I NUMMH jtl.TIAU NUMBIR
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TEMP-WATER
i
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UP PUNCH
IFY UNC
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i
MONTHLY OPERATING REPORT FOR
JMIS IS YOUR MONTHLY FUI-OHT FonM FOR
SEE REVERSE SIDE FOR RETURN MAIL
Plujc complete -nd jubmn two cop't» o( thu loim
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AVERAGE ,
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NUMBER DAYS RCPO
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OOH CHEMICAL COMPANY
OUTFALL 1 031
PROC. WASTES TO TITTABAHASSE
PERMIT EXPIRATIOHI 10/79
Dale loim w
printed
Flow
DAILY AVG
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ATION
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DAILY AVG.
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-------
J._
• OOv, CHEr.lCAL COl'.PAUY
MDLAfiD 01 V
.1
MONTHLY OPERATING REPORT FOR On:
**?0 •"• t tl
r.I 40640
i L56DOD
1
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OTAI SAMPIIS TAKEN , ,('
v<. »AA ,,
-------
icharger:
iple Date:
U.S. ENVIRONMENTAL PROTECTION AGENCY
REGION V
EASTERN DISTRICT OFFICE
Dow Chemical Intakes/Outfall 031/Pilot
Sample Type: 8 C-8 hour flow proportioned composite
24C-24 hour flow proportioned composite
Plant EYC-Equal volume composite
G-Grab
Sample Type
Time
Sample Number 84ER06
Date
Parameter
Titta.
River
Intake
Comp.
1214-
0940^
SOS
8/28-
29/84
ug/1
(ppb)
Lake
Huron
Intake
Comp.
1220-
0905
S10
8/28-
29/84
ug/1
(ppb)
II. ACID AND BASE NEUTRAL POLLUTANTS (continued
2 -methyl naphthal ene
2-nltroaniline
3-nltroanlline
4-nitroaniline
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/20
ND/100
ND/100
ND/100
Outfall
031
Comp.
1206-
0853
S15
8/28-
29/84
ug/1
(ppb)
ND/20
ND/100
ND/100
ND/100
85ER03
Pilot
Plant
Influent
G
0825
S24
12/4/84
ug/1
(ppb)
ND/10
NP/5,0
ND/50
ND/50
Pi 1 ot
Plant
Effluent
G
0857
S25
12/4/84
ug/1
(ppb)
ND/10
ND/50
ND/50
ND/50
-------
ischarger:
ample Date:
U.S. ENVIRONMENTAL PROTECTION AGENCY
REGION Y
EASTERN DISTRICT OFFICE
Dow Chemical Intakes/Outfall 031/Pilot Plant
Sample Type: 8 C-8 hour flow proportioned composite
24C-24 hour flow proportioned composite
EVC-Equal volume composite
G-Grab
Sample Type
Time
Sample Number 84ER06
Date
Parameter
11. AC ID AND BASE NEUTRAL POLl
Butyl benzyl phthalate
Dl-n-butyl pnthalate
Dt-n-octyl phthalate
Diethyl phthalate
Dlmetiyl phthalate
Benzo{a)anthracene
Benzo( a) pyrene
Benzo(b 4 kjfluoranthene
Benzol k ) f 1 uoranthene
Chrysene
Acenaphthylene
Anthracene
Benzol ghpperylene
Fluorene
Phenanthrene
01 benzol a, h) anthracene
Indenot 1 ,2 ,3-cd) pyrene
Pyrene
Aniline
Benzyl alcohol
4-chloroanlline
Dlbenzofuran
Titta.
River
Intake
Comp.
1214-
Q94Q
SOS
8/28-
29/84
ug/1
(ppb)
Lake
Huron
Intake
Comp.
1220-
Q9Q5
S10
8/28-
29/84
ug/1
(nob)
UTANTS continued
ND/ 4
ND/ 4
i ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
ND/ 4
KID/10
ND/10
ND/10
ND/10
ND/10
ND/10
ND/20
ND/20
ND/2Q
ND/10
ND/10
ND/10
ND/20
ND/10
ND/10
NMO
ND/20
ND/10
ND/10
ND/2Q
ND/50
1 ND/10 |
Outfall
031
Comp.
1206-
0853
S15
8/28-
29/84
ug/1
(ppb)
ND/1Q
ND/10
ND/10
ND/10
ND/10
ND/10
ND/20
ND/20
ND/20
ND/10
ND/10
ND/10
ND/20
ND/10
ND/10
M/20
ND/20
ND/10
ND/10
ND/20
ND/50
1 ND/10 |
85ER03
Pilot
Plant
Influent
G
0825
S24
12/4/84
ug/1
(DDb)
ND/10
U*
NO/10
ND/10
ND/10
ND/10
ND/10
ND/10
ND/10
ND/10
ND/10
NO/10
ND/10
ND/10
ND/10
ND/10
ND/10 N
ND/10
ND/10
ND/10
ND/AO
1 ND/10 1
Pilot
Plant
Effluent
G
0857
S25
12/4/84
ug/1
(DDb)
ND/10
ND/10
ND/10
ND/10
ND/10
ND/10
ND/10
ND/10
ND/10
ND/10
ND/10
ND/10
ND/10
ND/10
ND/10
ND/10
ND/10
ND/10
ND/10
ND/10
ND/10
ND/10
-
-------
scharger:
imple Date:
U.S. ENVIRONMENTAL PROTECTION AGENCY
REGION V
EASTERN DISTRICT OFFICE
Sample Type:
Dow Chemical Intakes/Outfall 031/Pilot Plant
8 C-8 hour flow proportioned composite
24C-24 hour flow proportioned composite
EVC-Equal volume composite
G-Grab
Sample Type
Time
Sample Number 84ER06
Date
Parameter
IV. METALS
Aluminum
Antimony
Arsenic
Barium
Beryl 1 1 urn
Cadmium
Chromi urn
Cobalt
Copper
Iron
Lead
Manganese
Mercury
Mkkel
Selenium
Silver
Thallium
Tin
Vanadium
Zinc
Maonesi urn ( ma/1 }
Sodium (ma/1)
Titta.
River
I ntaj
-------
scharger:
nple Date:
U.S. ENVIRONMENTAL PROTECTION AGENCY
REGION V
EASTERN DISTRICT OFFICE
Dow Chemical Intakes/Outfall 031/Pilot Plant
Sample Type: 8 C-8 hour flow proportioned composite
24C-24 hour flow proportioned composite
EYC-Equal volume composite
G-Grab
Sample Type
Time
Sample Number 84LRU6
Date
Parameter
III. PCB/PESTICIDE POLLUTANTS
Aldrin
Dieldrln
Chlordane
1 4 ,4 '-DDT ]
1 4,4'-DDE 1
4, 4 '-ODD
Alpha-endosulfan
Beta-endosulfan
Endosulfan sulfate
Endrin
Endrln aldehyde
Heptachlor
Heptachlor epoxide
Alpha-BHC
Beta-BHC
1 Gamma-BHC I
1 Delta-BHC I
PCB-1242
PCB-1254
PCB-1221
PCB-1232
PCB-1248
PCB-1260
PCB-1016
Toxaphene
Titta.
River
Intake
Comp.
1214-
0940
SUb
8/28-
29/84
ug/1
(ppb)
ND/0.2
ND/Q. 2
ND/2.Q
ND/0.2
ND/0.2
ND/0.2
ND/0.2
ND/0.2
ND/0.2
| ND/0.2 1
1 ND/0.2 ]
ND/0.2
ND/0.2
I ND/0.2 |
ND/0.2
ND/0.2
ND/Q. 2
ND/2.0
ND/2.0
ND/2.0
ND/2.0
1 ND/2.0 1
ND/2.0
ND/2.0
L ND/jMjJ
Lake
Huron
Intake
Comp.
1220-
0905
S1(J
8/28-
29/84
ug/1
(ppb)
ND/Q.l
ND/Q.l
ND/0.1
ND/0.1
ND/0.1
ND/0.1
, ND/0.1
ND/Q.l
ND/O.:.
ND/O.:.
1 ND/0.1 1
ND/0.1
ND/0.1
1 ND/0.1 ]
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
ND/0.1
1 ND/0.1 |
ti* m -i
ND/U. 1
ND/0.1
1 ND/0.1 ]
Outfall
031
Comp.
1206-
0853
Sib
8/28-
29/84
ug/1
(ppb)
ND/Q.l
ND/Q. .
ND/Q.:.
ND/O. .
ND/O. .
ND/O. .
ND/O. .
ND/O. .
ND/O. .
ND/O.
i ND/0.1
ND/O. .
ND/Q.:
ND/O.
ND/O. .
ND/O.
ND/Q.l
ND/0.1
ND/O. .
ND/O.:.
ND/0.1
1 ND/0.1 |
— iJft lf\ 1 —
NU/U.l
ND/O.:
L ND/O.iJ
PI I6t —
Plant
Influent
0825
12/4/84
ug/1
(ppb)
ND/O. 5
ND/ :,
ND/ 5
ND/ :.
ND/ 1
ND/ :.
ND/O. 5
ND/ 1
NO/ :.
1 ND/ 1 j
ND/ 1
ND/O. 5
ND/O. 5
ND/O. 5
ND/O. 5
ND/O. 5
ND/O. 5
ND/ 5
ND/10
ND/ 5
ND/ 5
ND/ 5
1 ND/ 5 j
"W10
mot —
Plant
Effluent
G
0857
12/4/84
ug/1
(ppb)
ND/O. 5
ND/ 1 1
ND/ 5
ND/ .
i ND/ 1 1
ND/ 1
ND/O. 5
ND/ 1
ND/ 1
| ND/ 1 1
| NO/ 1 1
ND/O. 5
ND/0.5
ND/O. 5
ND/O. 5
ND/O. 5
ND/O. 5
ND/ 5
NO/10
NO/ 5 i
ND/ 5
1 ND/ 5
1 ND/ 5
ND/10
-------
Dow Chemical Intakes/Outfall 031/Pilot Plant
NOTES:
1. ND/ B = Not detected due to blank.
2. ND = Compound was analyzed for but not detected. Value reported is the detection limit.
3. NA = Not analyzed.
4. NR = Not reported.
5. A = Detected below quantitation limit (quantitation limit is 10 x dectection limit).
6. C = Blank corrected.
7. J = Estimated value, detected below minimum specified contract detection limit but
greater than zero.
8. * = Presence of compound may be due to sample bottle preparation, field and/or labora-
tory contamination. Methylene chloride is used as a cleaning agent for sample
bottles. Phthalate compounds are components of certain plastics and are widespread
in the environment at low levels.
9. mg/1 = milligram per liter.
10. ug/1 = microgram per liter.
11. mg/kg = milligram per kilogram.
12. ng/g = nanogram per gram.
13. pg/g = picogram per gram.
14. ppb = parts per billion.
15. ppm = parts per million.
16. ppt = parts per trillion.
-------
scharger:
.mple Date:
U.S. ENVIRONMENTAL PROTECTION AGENCY
REGION Y
EASTERN DISTRICT OFFICE
Dow Chemical Intakes/Outfall 031/Pilot Plant
Sample Type: 8 C-8 hour flow proportioned composite
24C-24 hour flow proportioned composite
EVC-Equal volume composite
G-Grab
Sample Type
Time
Sample Number 84ER06
Date
Parameter
V. OTHER PARAMETERS
TDS (mq/1 )
TSS (mg/1 )
BOOR (mq/1)
NH3 (mq/1)
TP (mq/1)
TKN (mq/1)
Total Phenol ic s (mq/1)
Titta.
River
Intake
Comp.
1214-
0940
S65
8/28-
29/84
112
22
ND/2.0
0.098
ND/0.1
0.53
0.03
Lake
Huron
Intake
Comp.
1220-
0905
sio
8/28-
29/84
92
7
ND/2.0
0.064
ND/0.1
0.16
ND/.02
Outfal 1
031
Comp.
1206-
0853
si 5
8/28-
29/84
5008
46
8.22
0.822
0.555
2.18
0.20
85ER03
Pilot
Plant
Infl uent
G
0825
S24
12/4/84
510Q
24 j
NA
1.0
0.42
3.7
0.014
Pilot
Plant
Effluent
G
0857
S25
12/4/84
5090
£ J
NA
0.99
0.18
2.4
0.014
-------
DOW CHEMICAL USA
MICHICAH DIVISION — MIDLAND PLANT
MCN-CONVEMTICNAL/TOXIC POLLUTANTS — OUTFALL 031
PERMIT //MI 0000868
TABLE 1
Monitoring Results -
Phenol
2,4-Dichlorophenoxyacetic
acid
Bis(2-chloroethyl)ether
Chloroform
2,3t 7,8-Tetrachloro-
dibenzo-p-dioxin
1,1,2,2-Tetrachloroethane
Tetrachloroethylene
1,1,2-Trichloroethane
Pentachlorophenol
1,3-Dichlorobenzene
1,1-Dichlorobenzene
1 ^.iJ-Trichlorobenzene
Methylene Chloride
2-Chlorcphenol
2,1-Dichlorophenol
Naphtha]ene
1,1,1-Trichloroethane
Erorr.oforn
Chlorobonzeno
Carbon Tetrachloride
2,4,6-TrichJorophcnol
1,2-Dichlorobcnzcno
AcryJonitriJo
Monthly
Average
(Ibs/day)
—
.016*
.3
.6
0.3X10~6
__
0.7
—
0.9
•""•
— •-
0.1
— —
— —
0.2
— _
O.fi
—
0.3
—
-—
Daily
Maximum
. Obs/day)
—
.031*
.3
0.7
0.3X10~6
—
1.4
0.3
1.0
—
—
0.2
0,9
—
0.3
—
1.6
0.6
—
0.3
0.5
C.1
—
Monthly
Average
(ug/1)
NB(.6)
•3
2
5
2 ppq
MD(1)
5
MD(1)
7
ND(.?>
ND(.7)
1
ND(17)
ND(0.7)
2
HD(.3)
5
ND(2)
MD(1)
ND(1)
2
MD(.7)
HD(2)
F ' , >~ ^
Daily
Maximum
(u g/1)
MD(.6)
3
2
6
2 ppq
ND(9)
7
2
9
ND(.7)
ND(.7)
1
5
HD(.7)
2
HD(.3)
5
n
ND(1)
2
3
1
N'D(3)
Mass discharre reasurcd at. fPla
ppq = part- per quadrillion
-------
c
DOW CHEMICAL USA
MICHIGAN DIVISION — MIDLAND PLANT
NON-CCNVENTIGNAL/TOXIC POLLUTANTS — OUTFALL 031
PERMIT //MI 0000868
TABLE 2
Monitoring Results - November, 1985
Phenol
2,4-Dichlorophenoxy-
acetic acid
Bis(2-chloroethyl)ether
Chloroform
2,3,7,3-Tetrachloro-
dibenzo-p-dioxin
1,1,2,2-Tetrachloroethane
Tetrachloroethylene
1,1,2-Trichloroethane
Pentachlorophenol
1,3-Dichlorobenzene
1,H-Dichorobenzene
1,2,4-Trichlorobenzene
Methylene Chloride
2-Chlorophenol
2,U-Dichlorophenol
Naphthalene
1,1,1-Trichloroethone
Bromoforn
Chlorobenzcne
Carbon Tetrnchloride
2,4 ,6-Trichlorophenol
1,2-Dichlorob«nzene
Acrylonitrilc
Concentration
u g/liter
NDC.6)
3
2
3
2 ppq*
ND(9)
2
2
5
NDC.7)
ND(.7)
1
5
ND(0.7)
2
NDC.3)
5
ND(2)
MD(1)
2
-5
tlD( .7)
t:o(3)
Sample Concentration
Date u g/liter
11/11/85
11/11/85
11/11/85
10/28/85
10/21/85
10/28/85
10/28/85
10/28/85
11/11/85
11/11/85
11/11/85
11/11/85
10/28/85
11/11/85
11/1 1/85
11/11/85
10/28/85
10/28/85
10/28/85
10/28/85
11/11/85
11/11/85
10/28/85
ND(.6)
2
2
6
2 ppq*
ND(1)
7
ND(1)
9
ND(.6)
ND(.6)
1
ND(17)
ND(0.6)
1
NDC.2)
5
4
ND(1)
MD(1)
1
1
ND(2)
Sample
Date
11/18/85
11/18/85
11/18/85
11/11/85
11/06/85
11/11/85
11/11/85
11/11/85
11/18/85
11/18/85
11/18/85
11/18/85
11/11/85
11/18/85
11/18/85
11/18/85
11/11/85
11/1 1/85
11/11/85
11/11/85
11/18/C5
1 1/18/85
11/11/85
ND - riot Detected
() = Lowest Detection Lirut
= Concentration Reported .is Part Per Quadrillion
-------
DOW CHEMICAL USA
MICHIGAN DIVISION -- MIDLAND PLANT
NON-CONVENTIONAL/TOXIC POLLUTANTS — OUTFALL 031
PERMIT //MI 0000868
TABLE 1
Monitoring Results - October, 1985
Phenol
2,U-Dichlorophenoxyacetic
acid
Bis(2-chloroethyl)ether
Chloroform
2,3,7,8-Tetrachloro-
dibenzo-p-dioxin
1,1,2,2-Tetrachloroethane
Tetrachloroethylene
1,1,2-Trichloroethane
Pentachlorophenol
1,3-Dichlorobenzene
1,U-Dichorobenzene
1,2,4-Trichlorobenzene
Methylene Chloride
2-Chlorophenol
2,U-Dichlorophenol
Naphthalene
1,1,1-Trichloroethane
Bromoform
Chlorobenzene
Carbon Tetrachloride
2 ,4 ,6-Trichlorophenol
1,2-Dichlorobenzene
Acrylonitrile
Monthly
Average
(Ibs/day)
.6
.005*
.1
0.8
1.5x10~6
0.1
0.3
3.3
0.8
Daily
Maximum
. (Ibs/day)
.8
.008*
.2
1.1
1.5x10~6
0.7
0.7
0.5
0.2
o.u
5.7
.1
1.1
0.1
0.9
Monthly Daily
Average Maximum
tyg/1) tyg/1)
U
2
1
5
9 ppq
NDCO
ND(6)
NDCO
2
NDC.7)
NDC.7)
2
18
ND(0.8)
ND(1)
NDC.3)
5
ND(1)
ND(1)
ND(1)
ND(1)
NDC.7)
ND(1)
5
3
1
6
9 ppq
4
4
NDCO
3
1
ND(.7)
2
31
ND(.8)
ND(1)
0.3
6
NDCO
ND(2)
ND(3)
ND(2)
0.7
5
Mass discharge measured at 031 a
-------
DCW CHEMICAL USA
MICHIGAN DIVISION — MIDLAND PLANT
HON-CONVENTIONAL/TOXIC POLLUTANTS — OUTFALL 031
PERMIT //MI 0000868
TABLE 2
Monitoring Results - October, 1985
Phenol
2,4-Dichlorophenoxy-
acetic acid
Bis(2-chloroethyl)ether
Chloroform
2,3,7,8-Tetrachloro-
dibenzo-p-dioxin
1,1,2,2-Tetrachloroethane
Tetrachloroethylene
1,1,2-Trichloroethane
Pentachlorophenol
1,3-Dichlorobenzene
1,4-Dichorobenzene
1,2,4-Trichlorobenzene
Methylene Chloride
2-Chlorophenol
2,4-Dichlorophenol
Naphthalene
1,1,1-Trichloroethane
Bromoform
Chlorobenzene
Carbon Tetrachloride
2,4 ,6-Trichlorophenol
1,2-Dichlorobenzene
Acrylonitrile
Concentration
•Vg/liter
2
ND(1)
1
3
9 ppq*
4
4
ND(1)
ND(2)
NDC.7)
ND(.6)
2
5
MD(0.7)
ND(1)
0.3
3
ND(1)
ND(1)
MD(1)
ND(2)
NDC.7)
ND(1)
Sample Concentration
Date 4/g/\iter
9/30/85
9/30/85
9/30/85
9/30/85
9/23/85
9/30/85
9/30/85
9/30/85
9/30/85
9/30/85
9/30/85
9/30/85
9/30/85
9/30/85
9/30/85
9/30/85
9/30/85
9/30/85
9/30/85
9/30/85
9/30/85
9/30/85
9/30/85
4
2
1
6
8 ppq*
ND(4)
ND(6)
ND(4)
2
1
ND(.7)
2
31
HD(O.S)
ND(1)
NDC.3)
6
ND(4)
ND(2)
ND(3)
ND(1)
0.7
5
Sample
Date
10/14/85
10/14/85
10/14/85
10/W85
10/03/85
10/11/85
10/14/85
10/14/85
10/14/85
10/14/85
10/14/85
10/14/85
10/14/85
10/14/85
10/14/85
10/14/85
10/14/85
10/14/85
10/14/85
10/14/35
10/14/35
10/14/85
10/14/85
ND = Not Detected
() = Lowest Detection Limit
= Concentration Reported as Part Per Quadrillion
-------
DOW CHEMICAL USA
MICHIGAN DIVISION — MIDLAND PLANT
c
NON-CONVENTIONAL/TOXIC POLLUTANTS — OUTFALL 031
PERMIT ffMI 0000868
TABLE 2
Monitoring Results
October, 1985
Phenol
2,U-Dichlorophenoxy-
acetic acid
Bis(2-chloroethyl)ether
1,1,2,2-Tetrachloroethane
Pentachlorophenol
1,3-Dichlorobenzene
1,4-Dichorobenzene
1,2,4-Trichlorobenzene
2-Chlorophenol
2,4-Dichlorophenol
Naphthalene
2,4 ,6-Trichlorophenol
1,2-Dichlorobenzene
Concentration
it g/liter
5
3
1
U
3
ND(.7)
NDC.7)
2
NDC0.8)
ND(1)
ND(.3)
ND( 1 )
ND(.7)
Sample
Date
10/20/85
10/20/85
10/20/85
10/20/85
10/20/85
10/20/85
10/20/85
10/20/85
10/20/85
10/20/85
10/20/85
10/20/85
10/20/85
MD = Not Detected
() = Lowest Detection Limit
-------
TREATMENT PONO SEDIMENT ANALYSE!)
TENTATIVELY IDENTIFIED COMPOUNDS
(continued)
CAS
Number
Simple Type:
Tune:
Sd'iiple Number:
Oare:
Parameter
84EK04
630-06-8 Hex.itriacontanp
6912-07-8 Hex.nlecane, "i-butyl
1560-84-5 E'rosane, ?-methyl -
103-82-2 Bcn/piie acetic acid
638-67-5 Tricosane
629-62-9 Pentadecane
629-94-7 Hen.'icosane
53044-27-2 At.'tic acid, [bis[( trtmethyl si lyl)
oxy] phoshinyl]-tr)
ert iary
ond Low
Surface
edintent
G
ino/
Slfi
7/2R/84
ii-i/q
(ppl'l)
Tertiary
Pond Low
Bottom
Sediment
G
1045
S20
7/26/84
"9/9
( ppm)
Tertiary
Pond Mid
Surface
Sediment
G
1140
S17
7/26/84
"9/9
(PP"0
Teritary
Pond Mid
Bottom
Sediment
G
1220
S21
7/26/84
uy/y
(PP"i)
Tertiary
Pond Up
Surface
Sediment
G
1635
S19
7/26/84
ug/g
(ppni)
Tertiary
Pond Up
Bottom
Sediment
G
1645
S23
7/26/84
ug/9
(ppm)
Primary
Pond
Surface
Sediment
G
1910
S26
7/26/84
ug/y
(ppm)
Primary
Pond
Bottom
Sediment
G
1915
S27
7/26/84
ucj/9
(ppm)
Scndary.
Pond
Surface
Sediment
G
1800
S24
7/26/84
"9/9
(ppm)
Scndary.
Pond
Bottom
Sediment
G
1810
S25
7/26/84
U9/9
(ppm)
2.6 01
2fi Uk
11.0 01
4 ftS
11 RS
4.6 RS
7.S R5
7.5 UK
NOTES: A -- High probability that identification is correct.
8 = Moderate prolMhfllty that Identification (s correct.
C = Low probability that Identification is correct.
0 = Solvent Impurity.
01 = Isomer or similar compound.
UK = Unknown, not in NBS library.
RS = Reasonable identification, retention tune capatlbillty.
ug/l = iiilcrograms per liter.
ppb - parts per billion.
* ; May be due Io column bleeding.
-------
TREATMENT POND SEDIMENT ANALYSIS
TENTATIVELY IDENTIFIED COMPOUNDS
(continued)
CAS
Number
Sample Type:
Time:
Sample Number: 84EK04
Date:
Parameter
35882-88-3 26.27-Oinorergosta-5.22-dien-3-ol ,
(3.beta.)-
60-29-7 Ethane, l,l'-oxybis
149-73-b Methane, trlmethoxy-
565-59-3 Pentane, 2.3-d1methyl-
106-96-7 1-Propyne, 3-bromo-
592-13-2 Hexane. 2,5-d1methyl-
98-82-8 Benzene (1-methylethyl)-
108-38-3 Benzene. 1,3-dimethyl- _
56666-78-5 Tricyclo [4.2.0.02,4] oct-7-en-5-one_
556-67-2 Cyclotetraslloxane, octamethyl-
28654-79-7 Benzene, sec-butyl ethyl
1120-21-4 Undecane
544-76-3 Hexadecarie
25649-70-1 4H-l,2-diazepine, 3,5,7-trlphenyl-
7683-64-9 2,6,10,14,18,22-tetracos-
ahexaene, 2,6.10,15.19,2J-Hex
278b4-41-7 Irider.ane. 2-methyl-2-phenyl-
19HS-5/-b Henzpne (1,1-diinethylbutyl )-
160-02-5 lJxacyclohexailecdn-2-one
717-74-8 Benzene. 1,3.5-tris(l-methylethyl)-~
600-36-2 3-Pentomol , 2,4-dnnethyl-
108-86-1 Benzene, bromo-
2177-67-5 Hutanolc aclil. 2-methylene-,
methyl ester
112-95-8 Eicosane
26356-11-6 Benzene (1,1,2-trlmethylpropyl)-
18060-77-0 2-8utenolc arid, l-methylethylester_
75-25-2 Methane, trlbromo-
629-99-2 Pentacosane
Tertiary
Pond Low
Surface
Sediment
G
1007
S16
7/26/84
ug/g
(PP"i)
e
Tertiary
Pond Low
Bottom
Sediment
G
1045
S20
7/26/84
ug/g
(ppm)
Tertiary
Pond Mid
Surface
Sediment
G
1140
S17
7/26/84
ug/y
(PP"i)
Terltary
Pond Mid
Bottom
Sediment
G
1220
S21
7/26/84
ug/g
(pom)
Tertiary
Pond Up
Surface
Sediment
G
1635
S19
7/26/84
ug/u
(PP"l)
11.0 UK
Tertiary
Pond Up
Bottom
Sediment
G
1645,
S23
7/26/84
ug/g
(PP"|)
Primary
Pond
Surface
Sediment
G
14H)
S26
7/26/84
ug/g
(PP"i)
0.17 01
0.23 01
0.20 01
0.25 UK
0.0« 01
0.55 0!
0.12 01
0.38 UK
93 01
140 01
68 UK
92 01
47 UK
Primary
Pond
Bottom
Sediment
G
1915
S27
7/26/84
ug/g
(PP"i)
0.008 01
0.057 01
0.018 UK
0.094 01
5.6 01
13 UK
11 01
11 01
41.0 UK
7.0 01
14.0 UK
Scndary.
Pond
Surface
Sediment
G
1800
S24
7/26/84
ug/g
(PP*)
0.016 RS
0.042 RS
0.080 RS
0.16 01
0.043 01
44 0!
37.0 UK
22.0 01
0.064 RS
0.032 UK
68 UK
25 Ot
55.0 UK
0.015 01
Scndary.
Pond
Bottom
Sediment
G
1810
S25
7/26/84
"9/9
(PP")
8.9 RS
4.3 01
2.3 UV
7.7 01
6.8 RS
0.026 01
8.1 01
7.U 01
6.2 RS
7.5 01
7.9 01
6.8 01
5.8 01
3.4 01
5.5 RS
10 01
9.7 01
-------
TREATMENT PONO SEDIMENT ANALYSES
TENTATIVELY IDENTIFIED COMPOUNDS
(continued)
CAS
Number
Sample Type:
Time:
Sample Number: 84ER04
Date:
Parameter
56554-87-1 16-octadecenal
2091-29-4 9-hexadecenoic acid
143-07-7 Dodecanolc add
10544-50-0 Sulfur, Mol(58)-
5393-81-7 Oecanolc acid, 2-hydroxy-
57-11-4 Octadecanotc add
143-28-2 9-octadecen-l-ol, (/_)-
26489-01-0 6-octen-l-ol, 3,7-d1methyl-. ( )-
3789-85-3 Benzole acid, 2-[(tr1methylstlyl)
oxy]-, trlmethylsllyl
3618-20-0 Benzole add, 2,5-b1s(tr1methyl-
stloxy)-, trlmethylsilyl
629-78-7 Heptadecane
6006-01-5 3.7,H-trfdecatrfenenttr11e,
4,8,12-trlmethyl-
54284-45-6 9,1^-octadecadlenulc add, (Z,Z)-
?,1-b1s[tr1inethylsll-
540-84-1 Pentane, 2,2,4-trtmethyl-
79-34-5 Ethane, 1,1,2,2-tetrachloro-
593-68-0 Phosphlne, ethyl-
3910-35-8 IH-Indene, 2,3-dthydro-1,
l,3-trlmethyl-3-phenyl
107-51-7 Trlslloxane, octamethyl-
541-05-9 Cyclotrlstloxane, hexamethyl-
29812-79-1 Hydroxylamlne, 0-decyl-
55125-22-9 Hexanedtolc add, bis (1.3-
dfmethylbutyl) ester
56701-02-1 Isoxazoltdlne, 5-ethyl-2,4-
dimethyl-ds-
5353-25-3 Ethanol, 2-(9-octadecenyloxy)-,
56554-97-3 6-Octadecenal
56554-88-2 5-Octadecenal
54594-42-2 2(lH)-Naphthalenone, octahydro-4A-
methyl-7-(l-methy1e)
Tertiary
Pond Low
Surface
Sediment
6
1007
S16
7/26/84
ug/9
(PP"0
)
-
(z)-
A-
Tertlary
Pond Low
Bottom
Sediment
G
1045
S20
7/26/84
ug/9
(PPi»)
Tertiary
Pond M1d
Surface
Sediment
G
1140
S17
7/26/84
ug/g
(ppm)
30.0 UK
130 UK
...... -.— • *. «•»••••-
•12.0 UK
"lOo UK
760 UK
—55 • ' UK 1
4.9 UK
Terltary
Pond Mid
Bottom
Sediment
G
1220
S21
7/26/84
ug/g
(ppm)
••'1.3 UK
"1.9 01"
— ^0.519 UK
Tertiary
Pond Up
Surface
Sediment
G
1635
S19
7/26/84
ug/g
(ppm)
' — 5.4 " UK
— 0.93 UK
"'"D.flS 01
— 1.6 Uk"
1.4 UK
8.7 UK
1.0 UK
— y~i — m —
— 1.5 01
' 5.0 UK"
l.fi Uk
4.5 Uk' '
1.5 Ulf '
— im — nj —
10.0 uk
Tertiary
Pond Up
Bottom
Sediment
G
1645
S23
7/26/84
ug/g
(PI*)
Primary
Pond
Surface
Sediment
G
1910
S26
7/26/84
ug/g
(ppm)
270 Uk
400 UK
1000 UK
— 230 Uk
— a uk
1000 01
— 82 — OR —
100 UK
82.0 01
1.501
Primary
Pond
Bottom
Sediment
G
1915
S27
7/26/84
ug/g
(ppm)
17.0 UK
1 17.fl Uk
"IB OT~
10 UK
110 01
— 4~.2 • Uk
7.9 01
— 6.4' 01 —
0.060 01
— 4.3 Uk '
10.0 01
7.7 UK
Scndary.
Pond
Surface
Sediment
G
1800
S24
7/26/84
ug/g
(ppm)
210 Uk
38.0 Uk'
280 01
54 UK '
TT in
25 UK
0.34 01
26 UK
35 UK
Scndary .
Pond
Bottom
Sediment
G
1810
S25
7/26/84
ug/g
(PP»)
1 37.0 01
190 01
3.0 UK
3.1 01
B.I 0$
.034 01
r — 3 — RS~
-------
Treatment Pond Sediment Analyses
Tentatively Identified Compounds
CAS
Number
Sample Type:
Time:
Sample Number:
Date:
Parameter
84ER04
109-87-5 Methane, dlmethoxy
S93-4S-3 Octadecane
629-73-2 1-hexadecane
29833-69-0 1-pentadecene, 2-methyl
57-10-3 HexadecanoU acid
2078-22-0 1,2-benzene dlcarboxyllc add,
b(s(tr1methyl silyljester
32064-79-2 6-decen-5-one
17104-67-5 2-naphthanltrlle, 5,6,7.8-
tetrahydro-
629-96-9 1-eicosanol
1454-85-9 1-heptadecanol
638-66-4 Octadecanal
2490-48-4 1-henadecanol, 2-methyl-
3790-71-4 2,6,10-dodecatrlen-l-ol,
3,Ml-tr1«ethyl-, (Z.E)-
29354-98-1 Hex.i.fecanol
59-02-9 2H-l-Benzopyran-6-ol, 3.4-dlhydro-
2,5,7,8-tetramethyl
2400-03-5 Benzene, (1-propylheptadecyl)-
1898-13-1 1,3,6,10-Cyclotetra decatetraene
3,;.ll-tr1methyl-14-
26047-31-4 Ergost-7-en-ol, (3.beta.)-
17608-76-3 Ervjosta-7,22-die»-3-ol,
(J.beta. 22E)-
112-53-8 1-Dodecanol
1002-69-3 Decane, 1-chloro-
26248-42-0 Tridecanol
544-63-8 Tetradecanolc add
17233-71-5 Hexathlepane
1002-84-2 Pentadecanotc acid
Tertiary
Pond Low
Surface
Sediment
G
1007
516
7/26/84
ug/y
(PP">)
0.13 01
6.5 01
5.7 01
3.2 UK
' 6.4 01 '
14.0 UK
30.0 'UK"
TO" OK '-
29.0 UK
16.0 UK
3.7 01
8.2 01
7.3 UK
14.0 UK
24.0 UK
lfi.0 UK
9.8 UK '
27.0 UK
Tertiary
Pond Low
Bottom
Sediment
G
1045
S20
7/26/84
ug/g
(ppm)
0.53 UK
1.3 UK
0.52 UK
Tertiary
Pond M1d
Surface
Sediment
G
1140
S17
, 7/26/84
ug/g
(ppm)
0.18 01
6i .0 or
150 UK
31 UK
53 UK" '
280 UK
78.0 UK
26.0 UK
33.0 UK
58.0 01
14.0 UK
Terltary
Pond Mid
Bottom
Sediment
G
1220
S21
7/26/84
ug/g
(pprc)
0.019 01
Tertiary
Pond Up
Surface
Sediment
G
1635
S19
7/26/84
ug/g
(ppm)
0.0086 01
1.4 UK
1.5 UK
2.$ UK
3.3 UK
Tertiary
Pond Up
Bottom
Sediment
G
1645
S23
7/26/84
ug/g
(Ppml
0.740 0!
Primary
Pond
Surface
Sediment
G
1910
S26
7/26/84
(Sa
1.7 01
5BO UK
' 290 UK
84 UK
170 01
82 UK
Primary
Pond
Bottom
Sediment
G
1915
S27
7/26/84
ug/g
(fPi")
0.19 01
24 UK
8.6 UK
Scndary.
Pond
Surface
Sediment
G
1800
S24
7/26/84
ug/g
(ppm)
0.25 RS
310 UK
30 UK
32 UK
74 UK
30 01
27 UK
Scndary.
Pond
Bottom
Sediment
G
1810
S2S
7/26/84
ug/g
(Ppm)
0.078 01
7.5 0[
6.2 01
6.7 01
5.6 RS
5.1 RS
27 01
11.0 UK
3.3 RS
2.8 01
-------
Dow Chemical Treatment Pond Analyses
NOTES:
1. BG = The concentration in the blank is greater than 1/2 of the method detection limit
and is less than or equal to 1/2 the concentration detected in a sample. The
concentration in the blank is subtracted from the sample.
2. C = Blank corrected.
3. J = Estimated value, detected below minimum specified contract detection limit but
greater than zero.
4. NA = Not analyzed.
5. NO = Compound was analyzed for but not detected. Value reported is the detection limit.
6. ND/ B = Not detected due to blank.
7. ug/kg = micrograms per kilogram.
8. mg/kg = milligrams per kilogram.
9. ng/g = nanograms per gram.
10. ppb = parts per billion.
11. ppm = parts per million.
12. ** = Data reported on wet weight basis.
-------
scharger:
nple Date:
U.S. ENVIRONMENTAL PROTECTION AGENCY
REGION Y
EASTERN DISTRICT OFFICE
Dow Chemical Treatment Pond Analyses
Sample Type: 8 C-8 hour flow proportioned composite
24C-24 hour flow proportioned composite
EYC-Equal volume composite
G-Grab
Primary Primary Scndary. Scndary. Tertiary Tertiary Tertiary Teritary Tertiary Tertiary
Sample Type
Time
Sample Number 84ER04
Date
Parameter
VI. TETRACHLORODIBENZO-P-DIO)
ISOMERS OTHER THAN 2378-1
1368
1379
1369
1247. 1248, 1378, 1469
1246
1278Q (1268)
1478
1268° (1279)
1234, 1236, 1269
1237, 1238
1239
1279d (1278)
1267
1289
Pond
Surface
Sediment
G
1910
S26
7/26/84
ng/g
(ppb)
INS
CDD*
9.30
4.00
ND/.300
1.30
ND/.300
ND/.300
ND/.300
ND/.300
ND/.300
1.80
ND/.400
ND/.400
ND/.400
NO/. 400
Pond
Bottom
Sediment
G
1915
S27
7/26/84
ng/g
(ppb)
5.15
2.30
ND/.200
1.10
ND/.200
ND/.200
ND/.200
ND/.250
ND/.200
0.500
ND/.150
0.200
ND/.150
ND/.250
Pond
Surface
Sediment
G
1800
S24
7/26/84
ng/g
(ppb)
11.8
5.60
0.200
1.76
NO/. 200
ND/.250
ND/.250
ND/.250
ND/.300
2.80
ND/.300
0.700
ND/.150
ND/.150
Pond
Bottom
>ediment
G
1810
S25
7/26/84
ng/g
(ppb)
0.250
ND/.150
ND/.050
ND/.050
ND/.050
ND/.050
ND/.050
ND/.050
ND/.050
ND/.090
ND/.050
ND/.050
ND/.050
NO/. 050
>ond Up
Surface
>ediment
G
1635
S19
7/26/84
ng/g
(ppb)
0.760
0.380
ND/.030
0.090
ND/.030
ND/.030
ND/.030
ND/.030
ND/.030
0.100
ND/.030
ND/.030
ND/.030
ND/.030
Pond Up
Bottom
Sediment
G
1645
S23
7/26/84
ng/g
(ppb)
0.200
0.070
ND/.010
0.024
ND/.008
ND/.008
ND/.008
ND/.008
ND/.008
0.050
ND/.OOfi
0.010
ND7.010
0.010
Pond Mid
Surface
Sediment
G
1140
S17
7/26/84
ng/g
(ppb)
4.78
1.65
ND/.140
0.750
ND/.150
ND/.150
ND/.150
ND/.150
ND/.150
0.950
ND/.150
0.200
ND/.150
ND/.200
Pond Mid
Bottom
Sediment
G
1220
S21
7/26/84
ng/g
(ppb)
0.130
0.040
ND/.020
0.020
ND/.010
ND/.010
ND/.010
ND/.010
ND/.010
0.020
ND/.010
ND/.010
ND/.010
ND/.010
Pond Low
Surface
Sediment
G
1007
S16
7/26/84
ng/g
(ppb)
1.28
0.380
ND/.030
0.100
ND/.030
ND/.030
ND/.030
ND/.030
NO/. 030
0.180
ND/.030
ND/.030
ND/.030
ND/.030
Pond Low
Bottom
Sediment
G
1045
S20
7/26/84
ng/g
(ppb)
0.057
0.017
ND/.010
0.012
ND/.010
ND/.010
ND/.010
NO/. 010
0.013
0.027
Nin/.oio
NO/. 010
ND/.010
ND/.020
^Analyses performed on Brehm Laboratory GC-MS System B.
dldentity of these isomers is unclear published retention data; therefore,
the oossible alternate identities for these isomers are listed in paranthesls.
-------
charger:
iple Date:
U.S. ENVIRONMENTAL PROTECTION AGENCY
REGION V
EASTERN DISTRICT OFFICE
Dow Chemical Treatment Pond Analyses
Sample Type: 8 C-8 hour flow proportioned composite
24C-24 hour flow proportioned composite
EVC-Equal volume composite
G-Grab
Primary Primary Scndary. Scndary. Tertiary Tertiary Tertiary Teritary Tertiarv Tertiary
Sample Type
Time
Sample Number 84ER04
Date
Parameter
V. DIOXINS AND FURANS
2378-TCDD
Total Tetra CDDs
Total Penta CDDs
Total Hexa CDDs
Total Hepta CDDs
OCDD
2378-TCbP
Total Tetra CDFs
Total Penta CDFs
Total Hexa CDFs
Total Hepta CDFs
OCDF
Pond
Surface
Sediment
G
1910
S26
7/26/84
ng/g
(PPb)
1.7
18
10
14
125
482
ND/.50
95
26
20
84
117
Pond
Bottom
Sediment
G
1915
S27
7/26/84
ng/g
(ppb)
0.87
10
5.9
17
64
168
0.25
19
6.5
7.0
18
22
Pond
Surface
Sediment
G
1800
S24
7/26/84
ng/g
(ppb)
3.8
26
23
38
840
920
1.8
93
14
16
320
256
Pond
Bottom
Sediment
G
1810
S25
7/26/84
ng/g
(Ppb)
NO/. 08
0.25
ND/2.0
ND/.35
6~.0
16
0.10
1.5
ND/.20
ND/.30
1.3
2.8
Pond Up
Surface
Sediment
G
1635
S19
7/26/84
ng/g
(ppb)
0.14
1.5
0.81
2.6
17
72
0.09
15
2.5
1.8
4.5
7.3
Pond Up
Bottom
Sediment
G
1645
S23
7/26/84
ng/g
(PPb)
0.05
0.41
0.26
0.49
2.0
12
0.04
3.6
0.43
0.29
0.50
0.94
Pond Mid
Surface
Sediment
G
1140
S17
7/26/84
ng/g
(ppb)
0.93
9.2
6.3
26
201
324
0.90
44
3.4
8.0
31
33
Pond Mid
Bottom
Sediment
G
1220
S21
7/26/84
ng/g
(PPb) .
0.02
0.23
0.08
0.75
6.4
23
0.06
1.5
0.26
0.20
0.80
1.7
Pond Low
Surface
Sediment
G
1007
S16
7/26/84
ng/g
(PPb)
0.10
2.0
0.67
1.7
11
44
0.153
223
P..Q
1.4
5.1
5.6
Pond Low
Bottom
Sediment
G
1045
S20b
7/26/84
ng/g
(PPb)
0.03
0.11
NO/. 03
ND/.15
1.0
4.4
n.n?
n.4Q
0.09
n.nfi
n.?o
0.35
Notes: aDi0xin data reported on wet weight basis, with the exception of sample 84ER04S20.
bTCDF data listed was calculated based upon results obtained during reanalysis
of sample extract on Brehm Laboratory GC-MS System A.
-------
•charger:
iple Date:
U.S. ENVIRONMENTAL PROTECTl'ON AGENCY
REGION V
EASTERN DISTRICT OFFICE
Sample Type: 8 C-8 hour flow proportioned composite
24C-24 hour flow proportioned composite
EVC-Equal volume composite
G-Grab
Primary Primary Scndary. Scndary. Tertiary Tertiary Tertiary Teritary Tertiary Tertiary
Dow Chemical Treatment Pond Analyses
Sample Type
Time
Sample Number 84ER04
Date
Parameter
IV. METALS**
Aluminum
Antimony
Arsenic
Barium
Beryl 1 i urn
Cadmium
Chromium
Cobalt
Copper
Iron
Lead
Manganese
Mercury
Nickel
Selenium
Silver
Thallium
Tin
Vanadium
Zinc
Pond
Surface
Sediment
G
1910
S26
7/26/84
mg/kg
(ppm)
1250C
0.6
5.8
15.8
MD/.05
1 .3
33?
0.80
115C
1700C
25C
?.3.7
NO/ B
6.75
0.22
0.46
0.13
ND/ B
1.40
595C
Pond
Bottom
Sediment
G
1915
S27
7/26/84
mg/kg
(ppm)
2700C
NO/. 3
7.60
15. 6C
0.13
0.3?
8?
1.95
37. OC
10900C
NO/ B
4!51
ND/ B
7.15
0.18
ND/.15
ND/.l
ND/ B
7.75
295C
Pond
Surface
Sediment
G
1800
S24
7/26/84
mg/kg
(ppm)
1580C
ND/.3
5.0
5.38C
ND/.Q5
0.48
135
0.60
45. 4C
4960C
NO/ B
134
0.16C
9.15
0.12
0.15
ND/.l
ND/ B
3.10
455C
Pond
Bottom
Sediment
G
1810
S25
7/26/84
mg/kg
(ppm)
701C
ND/T3
4.4
6.73C
0.07
NH/.025
5.10
ND/.5
17. 9C
14700C
ND/ B
910
0.16C
8.10
ND/0.1
ND/1.5
ND/0.1
ND/ B
3.50
39. 6C
Pond Up
Surface
Sediment
G
1635
S19
7/26/84
mg/kg
(ppm)
2?30C
ND/.3
4.7
15. 5C
0.05
0.70
50
2.90
22. 7C
6100C
ND/ B
102
ND/ B
12.5
0.14
NO/. 15
ND/.l
ND/ B
7.35
444C
Pond Up
Bottom
Sediment
G
1645
S23
7/26/84
rng/kg
(ppm)
3300C
NO/. 3
3.9
14. 7C
0.11
0.13
9.45
3.95
10. 3C
8300C
ND/ B
197
ND/ B
10.7
ND/.l
NO/. 15
ND/.l
ND/ B
10.0
46. 6C
Pond Mid
Surface
Sediment
G
1140
S17
7/26/84
mg/kg
(ppm)
1200C
ND/.3
4.6
7.88C
ND/.05
0.4ft
55
1.65
21. 4C
3040C
NJLLB
44
NO/ B
10.7
0.22
NO/. 15
ND/.l
ND/ B
3.65
690C
Pond Mid
Bottom
Sediment
G
1220
S21
7/26/84
mg/kg
(ppm)
511C
ND/.3
1.1
5.33C
ND/.05
0.04
2.35
ND/.5
3.13C
833C
ND/ B
131
ND/ B
2.25
ND/.l
ND/.15
ND/.l
ND/ B
1.25
37. 3C
Pond Low
Surface
Sediment
G
1007
S16
7/26/84
mg/kg
(ppm)
561C
0.3
4.2
7.83
NO/. 05
0.35
34.5
1.7
13. 6C
1990C
ND7 B
61.0
ND/ B
10.0
0.15
ND/.15
ND/.l
ND/ B
2.80
421C
Pond Low
Bottom
Sediment
G
1045
S20
7/26/84
mg/kg
(ppm)
4890C
NO/. 3
3.7
11.6C
0.1 fi
n.03
9.75
4.45
10. OC
11300C
ND/ B
192
ND/ B
12.7
NO/.l
ND/.15
ND/.l
ND/ B
11.7
32. 7C
-------
;charger:
iple Date:
U.S. ENVIRONMENTAL PROTECTION AGENCY
REGION Y
EASTERN DISTRICT OFFICE
Dow Chemical Treatment Pond Analyses
Sample Type: 8 C-8 hour flow proportioned composite
24C-24 hour flow proportioned composite
EYC-Equal volume composite
G-Grab
Prihi*™ Primarv .Srndarv. Scndarv. Tertiary Tertiary Tertiary Teritary Tertiary Tertiary
Sample Type
Time
Sample Number 84ER04
Date
Parameter
III. PCB/PESTICIDE POLLUTANTS
Aldrin
Dieldnn
Chlordane
4, 4 '-DDT
4, 4 '-DDE
4, 4 '-ODD
Alpha-endosulfan
Beta-endosulfan
Endosulfan sulfate
Endrin
Endrin aldehyde
Heptachl or
Heptachlor epoxfde
Alpha-BHC
Beta-BHC
Gamma-BHC
Delta-BHC
PCB-1242
PCB-1254
PCB-122I
PCB-1232
PCB-1248
PCB-1260
PCB-1016
Toxaphene
Pond
Surface
Sediment
G
1910
S26
7/26/84
ug/kg
(ppb)
wn/4.0
Nin/d.n
ND/4.Q
ND/4.0
ND/4.Q
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.Q
ND/4.0
ND/4.0
ND/4.0
ND/4 . 0
ND/4.0
ND/4.0
ND/4.Q
ND/4.Q
ND/4.Q
ND/4.Q
ND/4.Q
Pond
Bottom
Sediment
G
1915
S27
7/26/84
ug/kg
(ppb)
Nn/4.0
Nn/4.0
N.n/4.0
Nn/4.o
Nn/4,Q
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4^Q
ND/4.Q
ND/4.Q
ND/4.0
ND/4.Q 1
Pond
Surface
Sediment
G
1800
S24
7/26/84
ug/kg
(ppb)
ND/4.0
wn/4.n
sin/4.n
480
_ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
330
ND/4.0
12000
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.Q
ND/4.0
ND/4.Q
ND/4.Q
NP/4.Q 1
Pond
Bottom
Sediment
G
1810
S25
7/26/84
ug/kg
(ppb)
Nn/4.o
wn/4 . n
wn/4.n
Nn/4.0
Nn/4.n
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.Q
ND/4.0
_RB/4L0
ND/4.0
ND/4.0 1
Pond Up
Surface
Sediment
G
1635
S19
7/26/84
ug/kg
(ppb)
Nn/4.0
Mn/4 n
wn/4.n
NH/4.0
NH/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
NIP/4.0
ND/4.0
ND/4.0
ND/4.0
1 ND/4.Q 1
Pond Up
Bottom
Sediment
G
1645
S23
7/26/84
ug/kg
(ppb)
Nn/4.o
wn/4 n
wn/4.n
Nn/4.0
wn/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
Nn/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
Mn/4.0
ND/4.0
ND/4.0
ND/4.0
1 ND/4.Q I
Pond Mid
Surface
Sediment
G
1140
S17
7/26/84
ug/kg
(ppb)
wn/4.0
Mn/4.n
wn/4.n
117
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
99
120
80
ND/4.0
Nn/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
Nn/4.0
ND/4.0
ND/4.0
ND/4.0
NP/4.Q 1
Pond Mid
Bottom
Sediment
G
1220
S21
7/26/84
ug/kg
(ppb)
Nn/4.Q
wn/4.n
wn/4.n
Nn/4.0
Nn/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
wn/4.n
.ND/4,0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
Nn/4.0
>ID/4.0
NQ/4.Q
ND/4.0
.ND/4,0
Pond Low
Surface
Sediment
G
1007
S16
7/26/84
ug/kg
(ppb)
wn/4.n
wn/4.n
wn/4.n
Nn/4.n
NJV4.n
Nn/4.0
ND/4.0
ND/4.0
. NO/4,0
83
ND/4,0
ND/4.0
ND/4.0
N.D./4.Q
_, ND/4.0.
_ ND/4,0
ND/4.0
.,NP/4,0
ND/4.0
ND/4.0
Nn/4.0
. ND/4.Q
ND/4.0
ND/4.0
ND/4.0
Pond Low
Bottom
Sediment
G
1045
S20
7/26/84
ug/kg
(ppb)
, N.D./4.Q,
Nn/4,n
wn/4.n
Nn/4.Q
^wn/4.0
ND/4.Q
ND/4,0
ND/4.0
ND/4.0
ND/4.0
_ ND/4,0
ND/4.0
ND/4.Q
Nn/4.0
ND/4.0
ND/4.0
ND/4.0
ND/4.0
NO/4.0
ND/4.0
NH/4,0
Nn/4.0
WH/4.Q
un/4.o
wn/4.o
-------
'•DOH CHEMCAL
MI I'LA NO 01 V
MlOLA'JO
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MONTHLY OPERATING REPORT FOR
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PART 1 - RETURN TO DbPT OP NATURAL RESOURCES
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-------
KJPI iuo 01 v
Mini AMD
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, , Tiu" BASED ON Mr MQUIHY of THOSE INDIVIDUALS IMMIOIAHLY iiiGPONT.miE roft)OBiAiNiNG IHE INIOHMAHOM. BELIEVE IHAI THE H.-IOKMAIION is THLit. ACCiinAtf
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-------
DOW CHEMICAL USA
MICHIGAN DIVISION -- MIDLAND PLANT
MOM-CONVENTIONAL/TOXIC POLLUTANTS — OUTFALL 031
PERMIT #MI 0000868
TABLE 1
Monitoring Results - December, 1985
e
Phenol
2,4-Dichlorophenoxyacetic
acid
Bis(2-chloroethyl)ether
Chloroform
2,3,7,8-Tetrachloro-
dibenzo-p-dioxin
1,1,2,2-Tetrachloroethane
Tetrachloroethylene
1,1,2-Trichloroethane
Pentachlorophenol
1,3-Dichlorobenzene
1,4-Dichlorobenzene
1 ,2 ,4-Trichlorobenzer.e
Methylene Chloride
2-Chlorophenol
2,4-Dichlorophenol
Naphthalene
1,1,1-Trichloroethane
BromoforT.
Chlorobenzene
Carbon Tctrachloride
2 ,'t ,6-Trichlorophenol
1 ,2-Cichiorobenzene
Acrylonitrilo
Monthly Daily Monthly Daily
Average Maximum Average Maximum
(Ibs/day) (Ibs/day) (ug/1) (ug/1)
0.5 0.5 i
.009* .011*
0.5 0.5
1.5 2.0
0.9X10~6 1.1X10~6
0.8
~ 1.9 2.3
0.3
3.7 3.8
0.3
0.3
0.14 0.5
0.5
—
0.3 0.3
0.2 0.3
1.8 2.0
1.3 1.5
0.5
0.8
—
0.5
— — — _
2
ND(2)
2
6
4 ppq
ND(2)
8
ND(1)
14
ND(.7)
ND(.6)
2
ND(13)
ND(0.7)
1
0.8
8
6
MD(1)
ND(1)
ND(1.5)
ND(.7)
ND(2)
2
2
2
8
5 ppq
3
9
1
1t
1
1
2
2
NDC.7)
1
1
8
6
2
3
NDC1.5)
2
MD(3)
"ass CiGchar^e
~t 031s
-------
DOW CHEMICAL USA
MICHIGAN DIVISION — MIDLAND PLANT
NON-CONVENTIONAL/TOXIC POLLUTANTS — OUTFALL 031
PERMIT ffMI 0000868
TABLE 2
Monitoring Results - December, 1985
c
Phenol
2,4-Dichlorophenoxy-
acetic acid
Bis(2-chloroethyl)ether
Chloroform
2,3,7,8-Tetrachloro-
dibenzo-p-dioxin
1,1 ,2,2-Tetrachloroethane
Tetrachloroethylene
1 ,1,2-Trichloroethane
Pentachlorophenol
1,3-Dichlorobenzene
1,4-Dichorobenzene
1,2,4-Trichlorobenzene
Methylene Chloride
2-Chlorophenol
2,4-Dichlorophenol
Naphthalene
1,1,1-Trichloroethane
Bromoform
Chlorobenzene
Carbon Tetrachloride
2,4,6-Trichlorophenol
1,2-Dichlorobenzene
Acrylonitrile
Concentration
ug/liter
2
ND(2)
2
4
2 ppq*
MD(2)
7
ND(1)
m
ND(.7)
NDC.6)
1
ND(13)
ND(0.7)
1
0.5
7
5
ND(1)
ND(1)
MD(1.5)
MD(.7)
HD(2)
Sample Concentration
Date ug/liter
12/13/85
12/13/85
12/13/85
12/5/85
11/21/85
12/5/85
12/5/85
12/5/85
12/13/85
12/13/85
12/13/85
12/13/85
12/5/85
12/13/85
12/13/85
12/13/85
12/5/85
12/5/85
12/5/85
12/5/85
12/13/85
12/13/85
12/5/85
2
2
2
8
5 ppq*
3
9
1
14
1
1
2
2
NDC0.7)
1
1
8
6
2
3
NDC1 .5)
2
ND(8)
Sample
Date
12/17/85
12/17/85
12/17/85
12/17/85
12/04/85
12/17/85
12/17/85
12/17/85
12/17/85
12/17/85
12/17/85
12/17/85
12/17/85
12/17/85
12/17/85
12/17/85
12/17/85
12/17/35
12/17/85
12/17/85
12/17/85
12/17/85
12/17/85
C
ND = tlot Detected
() - Lowest Detection Limit
= Concentration Henorte'J 35 Part Per Quadrillion
-------
OOW CHEMICAL USA
MIDLAND LOCATION
OUTFALL 031
Total Phosphorus (as P)
mgm/L
July, 1984 0 5
August, 1984 Q 4
September, 1984 0.7
October, 1984 Q 4
November, 1984 n ?
u • c.
December, 1984 0>15
January, 1985 0.4
February, 1985 0 4
March, 1985 Q>3
April, 1985 Q 2
May, 1985 n -,
U • O
June, 1985 n «
\j • O
July, 1985 Q>2
August, 1985 0.3
September, 1985 Q>3
October, 1985 Q 5
November, 1985 0.3
December, 1985 0.2
-------
DOW CHEMICAL U.S.A.
MICHIGAN DIVISION
November 27, 1985 M(OLANa MICH1GAN 48640
Mr. Paul Zugger, Chief
Surface Water Quality Division
MI Dept. of Natural Resources
P.O. Box 30023
Lansing, MI 43909
Dear Mr. Zugger:
SUBJECT: PHOSPHORUS MINIMIZATION STUDY, NPDES PERMIT 0000868
The NPDES permit issued to Dow Chemical's Midland location on May 17,
1984 included a monthly monitoring requirement for total phosphorus.
The monitoring data gathered to date are included in the attached
table for your reference.
The wastewater treatment system at this facility is not designed
specifically for phosphorus removal. Some removal does occur as
phosphorus is utilized by the wastewater treatment system bio-mass.
Therefore, the appropriate control procedures for phosphorus are
controls at individual sources. The present mix of products produced
at this location does not involve a significant amount of phosphorus
chemistry. This is clearly illustrated in the attached data. We
conclude that 1.0 mg/L as a 30-day average is presently attainable and
attainment could be maintained in the future through source control.
If you have any questions regarding this conclusion, please contact
me.
Sincerely,
7,/^
'
Technical Manager
Environmental Services
628 BuiIdinq
(517)636-3595
clr
Attachment
-------
DOW CHEMICAL USA
MIDLAND LOCATION
031 Outfall
Sample date 7/24-25/84
(Ail Pecj|-t-3 ;„ ppb)
Acrylonitri|e N0 (3.0)
Benzene N0 (1\2)
Carbon Tetrachloride (gp (7.1)
Chlorobenzene N0 (5'mS}
1,2,4-trichlorobenzene 3.5
HexacMorobenzene NO (0.3)
1,2-dichloroethane NQ (j^)
1,1,1-trichtoroethane NQ (7.0)
Hexachloroethane NO (0^2)
1,1, 2-trichloropthane NQ (0.3)
1,1,2,2- tetrachloroethane fjQ (6.5)
Bis (2-chloroethyl) ethpr p',8
2,4,6- trichlorophenol NQ (1.5)
P-chloro-m-cresol NQ (olq)
Chloroform 20
2-chlorophenol ^D (0.5)
1,2-dichlorobenzene 1 3
1,3-dichlorobenzene g j
1,4-d i chIorobenzene ] m0
2,4-dichlorophenol ^Q (|.Q)
Bis (2-chloroisopropyl) ether NQ (4.2)
Bis (2-ch loroethoxy) methane (gp (04)
Methylene Chloride 20
Bromoform 2Q
Hexachlorobutediene ^Q (0 gj
Naphthalene ND (o;2)
2,4- dinitrophenol (^Q (2.5)
Pentachlorophenol wn I-*.'Q\
r»i_ i ^ * - • • '
Phenol 0
Tetrachloroethylene NQ (6*.6)
TrichJoroethy lene jgp (7*2)
Heptachlor epoxide N0 (Q]P)
ND (0"5)
»^-r
»2,3,7,8-TCDO Result In Parts Per OvJ?dri||ion.
2,3,7,8-TCDD Sample date 7/1/84
-------
DOW CHEMICAL
December 31, 1Q84 VIOUANO. MICHIGAN 13540
Mr. Paul Zjocer, Chief
Sjrf?ce Water Quality Division
Ml Qeoartment of Natural Resources
P.O. Box 3002S
Lansing, Ml 48909
Dear Mr. Zugger:
SUBJECT: SPECIAL CONDITION 12 OF NPDES PERMIT #OOOQP6P
The attached data table shows results obtained from a semolina of
outfall 031, the tertiary pond discharge, from Dow Chemical
Company's Midland location. The sampling was done in accordance
with Special Condition 12 of Permit #0000868. Samples were
analyzed by gas chromatography-mass spectrometry (GC-MS) by two
fundamental procedures. The first procedure tests for those
compounds that are purged from the water sample. The total ion
current chromatccram showed no additional non-priority pollutant
peal's that exceed a 50:1 signal-to-noise ratio and meet the
criteria of Special Condition 12.
The second procedure tests for those compounds that are extracted
from water. Total ion current chromatoorams here showed only one
peak that exceeded 50:1 signal-to-noise, and met the criteria of
Special Condition 12. That peak was tentatively identified as
2-nitro-I-butanol by computerized mass spectra library search. A
check of GC retention time with that compound has not yet been
done.
Additional work pursuant to ("he reau irements of Special Condition
12 is in progress. If you have any questions regarding this
submittal, please telephone me.
Si ncer»ly,
Gary
Envi r6**m*>n fa I Service?
628 Bui I ding
(517)636-26-^
cp
-------
TABLE 2, CONTINUED
Dibutyl phthalate
di-n-Octyl phthalate
Diethyl phthalate
3enzo(a)anthracene
Benzo(a)pyrene
3,^-Benzo fluroanthene
Chrysene
Acenaphthylene
Anthracene
3enzo(g,h,i) perylene
Fluorene
Phenanthrene
Indeno(1,2,3-c,
NQ(1)
NQ(1)
NQ(1)
NQ(1)
NQ(1)
50
ND(1)
ND(50)
ND(50)
ND(100)
200
ND(100)
ND(2)
ND(100)
ND(1)
ND(200)
300
-------
TABLE 2
DOW CHEMICAL U.S.A.
MIDLAND LOCATION
031 OUTFALL
(All results in ppb)
Sample Date
Acenaphthene
Acrolein
1,1-Dichloroethane
Chloroethane
2-Chloroethyl vinyl ether
2-Chloronaphthalene
1,1-Dichloroethene
1,2-t-Dichloroethene
1,2-Dichloropropane
1,3-t-Dichloropropene
1,3-c-Dichloropropene
2,4-Dimethylphenol
2,1-Dinitrotoluene
2,6-Dinitrotoluene
Fluoranthene
4-Chlorophenyl phenyl ether
U-Bromophenyl phenyl ether
Vinyl chloride
Aldrin
Dieldrin
Chlordane
U.U'-DDT
U.U'-DDE
U.U'-DDD
Endosulfan sulfate
Endrin
Endrin aldehyde
Methyl chloride
Methyl bromide
Dichlorobromomethane
Chlorodibromomethane
Hexachlorocyclopentadiene
Isophorone
Nitrobenzene
2-Hitrophenol
^-Nitrophenol
4,6-Dinitro-o-cresol
N-nitrosodiphenyl amine
N-nitroso-n-propyl amine
bis(2-Ethyl hexyl)phthalatc
Butyl benzyl phthalate
NQ(2)
ND(20)
ND(2)
ND(13)
ND(70)
NQ(2)
ND(U)
ND(3)
ND(3)
ND(5)
NQ(1)
MQ(3)
NQ(6)
NQ(2)
NQ(1)
NQ(1)
ND(6)
NQ(5)
NQ(6)
NQ(21)
NQ(3)
NQ(3)
NQ(3)
NQ(9)
NQ(6)
NQ(9)
ND(5)
ND(8)
ND(2)
ND(3)
NQ(1)
NQ(2)
NQ(2)
NQ(3)
NQ(7)
NQ(3)
NQ(3)
-------
TABLE V
DOW CHEMICAL U.S.A.
MIDLAND LOCATION
031 OUTFALL
(All results in ppb)
Aniline
Benzene
bis Chlorobutyl ether
bis(2-Chloroethoxy)methane
bis(2-Chloroisopropyl)ether
beta-3HC
Chlorpyrifos
Cresol
2,4-D esters
2,6-D
1,2-Dichloroethane
2,2-Dichloroproprionic acid
2,4-Dinitrophenol
Dinoseb
Ethylene dibromide
Heptachlor epoxide
Hexachlorobenzene
Hexachlorobutadiene
Hexachlorocyclohexane
Hexachloroethane
Hydroquinone
1-Methyl naphthalene
p-Chloro-m-cresol
Pentachlorobenzene
Silvex
Silvex esters
Styrene
1 ,2,3,4-Tetrachlorobenzene
1,2,4,5-Tetrachlorobenzene
2,4,6-Tribromophenol
1,2,3-Trlchlorobenzene
Trichloroethylene
2,4,5-Trichlorophenol
2.4,5-T
2,1,5-T esters
Sample Date
7/24/34
0.2
ND(7)
95.3
ND(.4)
ND(4.2)
MD(0.5)
ND(7.5)
ND(0.5)
ND(2)
3.9
NDd4)
NDC1.8)
ND(2.5)
ND(1.8)
8.7
NDC0.8)
MD(0.3)
ND(0.6)
ND(0.5)
ND(0.2)
MDC1.2)
ND(0.8)
ND(0.9)
ND(2)
4.0
ND(tt)
ND(5.3)
ND( 1.1)
4.7
NDd.3)
ND(0.8)
ND(7.2)
ND(1.2)
ND(2.9)
ND<
-------
Mr. Paul Zugger
June 26, 1^85
Page Two (2)
d. EPA method 656 was specified for 1-chloro-2, 3-epoxypropane analy-
sis and method 653 was specified for ethylene oxide analysis.
Both of these methods require the use of a heated purge system in
the purge-trap technique. Work with the heating purge system in
our laboratory has not yet proved successful. This work is still
in progress.
Part B of Special Condition 12 requires an annual priority pollutant
scan. The attached Table 2 of this letter along with the results
submitted to the MDNR in a letter dated 12/31/31 complete this first
annual requirement.
If there are any questions regarding these data, please don't hesitate
to call.
Sincerely,
iry RyVeurink, Manager
Environmental Service
628 Building
(517)636-2646
scr
Attachments
-------
DOW CHEMICAL U.S./
June 26, 1985 MICH1GAN OW1S'ON
MIDLAND. MICHIGAN 486-10
Mr. Paul lugger, Chief
Surface Water Quality Division
MI Dept. of natural Resources
P.O. Box 30023
Lansing, MI 18909
Dear Mr. Zugger:
SUBJECT: SPECIAL CONDITION 12 OF NPDES PERMIT #0000868
Monitoring data for Outfall 031 obtained in accordance with Part A of
Special Condition 12 of Permit J0000868 are shown in the attached
Table 1. As specified in the special condition, the following
compounds will now be monitored annually for the life of the permit:
Aniline
bis-Chlorobutyl ether
2,6-Dichlorophenoxy acetic acid
Dinoseb
Ethylene dibromicJe
Silvex
1,2,1,5-Tetrachlorobenzene
1,2,3-Trichlorobenzene
Eighteen of the 53 compounds specified for analysis in Special Condi-
tion 12 were outside the scope of the EPA priority pollutant methods.
The MDHR has provided methods for 5 of these compounds. Work with
these methods has yielded the following results to date.
a. EPA method 666 was specified for the analysis of acrylic acid.
Blank water showed a low level interference when taken through the
procedure. The procedure was modified to incorporate the use of a
capillary GC column. With this method modification, acrylic acid
was shown to be not detected in Outfall 031 discharge water with a
detection limit of 3 ppb.
b. EPA method 615 was specified for the analysis of dichlorprop.
Performing method 615 as written resulted in many low level
interferences at the low ppb lovel. The method was modified to
Incorporate the GC/MS technique for final quantification and
dichlorprop was shown to be not detected In Outfall 031 discharge
water with a detection limit of 5 ppb.
c. EPA method 669 was specified for the analysis of dimethylamlne.
This r.etnod has produced 3<:v»r=»L low-level interferences whun
analysis at the low ppb level r.as been attempted. No r.ethod
r^odi flcaticns to date have pr-v/«»d successful.
-------
DOW CHEMICAL USA
MICHIGAN DIVISION — MIDLAND PLANT
NON-CONVENTIONAL/TOXIC POLLUTANTS — OUTFALL 031
PERMIT *MI 0000868
TABLE 2
Monitoring Results - August, 1985
Phenol
2, JJ-Dichlorophenoxy-
acetic acid
Bis(2-chloroethyl)ether
Chloroform
2,3,7,8-Tetrachloro-
dibenzo-p-dioxin
1,1,2,2-Tetrachloroethane
Tetrachloroethylene
1,1,2-Trichloroethane
Pentachlorophenol
1,3-Dichlorobenzene
1,H-Dichorobenzene
1,2,4-Trichlorobenzene
Methylene Chloride
2-Chlorophenol
2,1-Dichlorophenol
Naphthalene
1,1,1-Trichloroethane
Brocnoform
Chlorobenzene
Carbon Tetrachloride
2,U,6-Trichlorophenol
1,2-Dichlorobenzene
Acrylonitrile
Concentration
ug/liter
2
8
1
7
12 ppq*
ND(7)
ND(7)
ND(9)
ND(2)
ND(.7)
2
2
ND(6)
ND(0.7)
2
0,3
ND(7)
ND(7)
ND(6)
ND(5)
ND(2)
2
ND(4)
Sample Concentration Sample
Date ug/liter Date
7/23/85
7/23/85
7/23/85
7/23/85
7/23/85
7/23/85
7/23/85
7/23/85
7/23/85
7/23/84
7/23/85
7/23/85
7/23/85
7/23/85
7/23/85
7/23/85
7/23/85
7/23/85
7/23/85
7/23/85
7/23/85
7/23/85
7/23/85
3
15
2
17
22 ppq*
ND(7)
ND(9)
ND(3)
2
1
6
3
ND(6)
ND(0.7)
U
0.7
6
NDC4)
2
4
ND(2)
6
ND(1)
s .8/05/85
8/05/85
8/05/85
8/05/85 .
8/05/85
8/05/85
8/05/85
8/05/85
8/05/85
8/05/85
8/05/85
8/05/85
8/05/85
8/05/85
8/05/85
8/05/85
8/05/85
8/05/85
8/05/35
8/05/85
8/05/85
8/05/85
8/05/35
ND = Not Detected
() = Lowest Detection Limit
•
= Concentration Reported as Part Per Quadrillion
-------
0
DOW CHEMICAL USA
MICHIGAN DIVISION — MIDLAND PLANT
HON-CONVENTIONAL/TOXIC POLLUTANTS — OUTFALL 031
PERMIT ffMI 0000868
TABLE 1
Monitoring Results - August, 1985
Phenol
2,1-Dichlorophenoxyacetic
acid
Bis(2-chloroethyl)ether
Chloroform
2,3,7,8-Tetrachloro-
dibenzo-p-dioxin
1,1,2,2-Tetrachloroethane
Tetrachloroethylene
1,1,2-Trichloroethane
Pentachlorophenol
1,3-Dichlorobenzene
1,4-Dichorobenzene
1,2,1-Trichlorobenzene
Methylene Chloride
2-Chlorophenol
2,1-Dichlorophenol
Naphthalene
1,1,1-Trichloroethane
Bromoform
Chlorobenzene
Carbon Tetrachloride
2,4 ,6-Trichlorophenol
1,2-Dichlorobenzene
Acrylonitrile
Monthly Daily
Average Maximum
(Ibs/day) "(Ibs/day)
.3 .5
.020* .052»
.2 .3
1.« 2.7
3.2x10~6 3.5x10~6
.3
^ n
— *" • j
^2
.4 1.0
.4 .5
.7
—
.- .5 - .6
.08 .16
— 1.0
—
.3 .3
.6
—
.*» 1.0
_ _ __
Monthly Daily
Average Maximum
(ug/D (ug/1)
2
12
2
12
17 ppq
ND(7)
ND(8)
ND(6)
ND(2)
ND(.5)
3
2
ND(6)
ND(0.7)
3
0.5
ND(7)
ND(6)
U
ND(5)
ND(2)
3
ND(3)
3
15
2
17
22 ppq
9
10
ND(9)
2
1
6
3
20
NDC.8)
H
0.7
6
ND(7)
5
U
ND(2)
6
NDC4)
Mass discharge measured at 031 a
-------
.1
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OH CHEKICAL CUr.PAUY
JDLAUD DIV
ACUITY l
Mi* I In m* i NUMUI*. I ji.'iAii HUMII« I
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MONTHLY OPERATING REPORT FOR
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PART 1 - RETURN TO DEPT OF NATURAL RESOURCES
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DOW CHEMICAL .COMPANY
OUTFALL I 031
PROC.UASIEB'TO TITTABAHAS3EE: R. 031
PERMIT EXPIRATION! 10/79
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