United States
Environmental Protection
Agency
Office of Air Quality
Planning and Standards
Research Triangle Park, NC 27711
EPA-454/R-00-036b
July 2000
AIR
&EPA
Final Report
Testing of a 2-Stroke Lean Burn
Gas-Fired Reciprocating Internal
Combustion Engine to Determine
the Effectiveness of an Oxidation
Catalyst System for Reduction of
Hazardous Air Pollutants
Volume 2 of 2
">t i^S*»
-------
FINAL REPORT
TESTING OF A 2-STROKE LEAN BURN GAS-FIRED
RECIPROCATING INTERNAL COMBUSTION ENGINE TO DETERMINE THE
EFFECTIVENESS OF AN OXIDATION CATALYST SYSTEM FOR
REDUCTION OF HAZARDOUS AIR POLLUTANT EMISSIONS
VOLUME 2 OF 2
Prepared for:
Terry Harrison (MD-19)
Work Assignment Manager
SMTG, EMC, EMAD, OAQPS
U.S. Environmental Protection Agency
Research Triangle Park, NC 27711
July 2000
Submitted by:
PACIFIC ENVIRONMENTAL SERVICES, INC.
5001 S. Miami Blvd., Suite 300
Research Triangle Park, NC 27709-2077
(919)941-0333 FAX (919) 941-0234
U.S. Environmental Protection Agency
Region 5, Library (PL-12J)
77 West Jackson Bpu/evard, 12th Floor
Chicago, il 60604-3590
-------
DISCLAIMER
Pacific Environmental Services, Inc. (PES) prepared this document under EPA
Contract No. 68D98004, Work Assignment No. 3-01. PES reviewed this document in
accordance with its internal quality assurance procedures and approved it for distribution.
The contents of this document do not necessarily reflect the views and policies of the U.S.
EPA. Mention of trade names does not constitute endorsement by the EPA or PES.
-------
DISTRIBUTION LIST
U.S. ENVIRONMENTAL PROTECTION AGENCY
Terry Harrison, Work Assignment Manager, OAQPS, EMC, SCGA
Laura P. Autry, Quality Assurance Manager, OAQPS, EMC
Kathy Weant, Contracting Officer, OAQPS, EMAD
Sims Roy, Lead Engineer, OAQPS, ESD, CG
ENGINES AND ENERGY CONVERSION LABORATORY
COLORADO STATE UNIVERSITY
Dr. Bryan D. Wilson, Director, EECL
PACIFIC ENVIRONMENTAL SERVICES, INC.
John T. Chehaske, Program Manager, Research Triangle Park, NC
Dennis A. Falgout, Project Manager, Herndon, VA
PIPELINE RESEARCH COMMITTEE INTERNATIONAL
Sam L. Clowney, Chairman, Compressor Research Supervisory Committee
GAS RESEARCH INSTITUTE
James M. McCarthy, Program Team Leader, Air Quality
11
-------
TABLE OF CONTENTS
VOLUME 1 Page
1.0 INTRODUCTION 1-1
2.0 SUMMARY OF RESULTS 2-1
2.1 EMISSIONS TEST LOG 2-1
2.2 ENGINE PARAMETERS AND EXHAUST FLOW RATES 2-6
2.3 FTIRS AND CEM MEASUREMENTS 2-6
2.4 GCMS MEASUREMENTS 2-7
2.5 POLYNUCLEAR AROMATIC HYDROCARBON (PAH)
MEASUREMENTS 2-12
2.6 DESTRUCTION OF ORGANIC COMPOUNDS BY THE CATALYST 2-17
3.0 SOURCE DESCRIPTION AND OPERATION 3-1
3.1 ENGINE DESCRIPTION 3-1
3.2 ENGINE OPERATION DURING TESTING 3-4
4.0 SAMPLING LOCATIONS 4-1
5.0 SAMPLING AND ANALYSIS METHODS 5-1
5.1 LOCATION OF MEASUREMENT SITES AND SAMPLE/VELOCITY
TRAVERSE POINTS 5-1
5.2 DETERMINATION OF STACK GAS VOLUMETRIC FLOW RATE... 5-3
5.3 DETERMINATION OF STACK GAS DRY OXYGEN AND CARBON
DIOXIDE CONTENT 5-4
5.4 DETERMINATION OF STACK GAS MOISTURE CONTENT 5-4
5.5 DETERMINATION OFNITROGEN OXIDES 5-5
5.6 DETERMINATION OF CARBON MONOXIDE 5-5
5.7 DETERMINATION OF METHANE AND NON-METHANE
HYDROCARBONS 5-7
5.8 DETERMINATION OF GASEOUS ORGANIC HAPS
USING FTIRS 5-7
5.9 DETERMINATION OF ORGANIC HAPS BY DIRECT
INTERFACE GCMS 5-8
111
-------
TABLE OF CONTENTS (Concluded)
5.10 DETERMINATION OF POLYCYCLIC AROMATIC HYDROCARBONS
BY CARB 429 5-11
6.0 QUALITY ASSURANCE/QUALITY CONTROL PROCEDURES
AND RESULTS
6-1
6.1
6.2
6.3
6.4
6.5
6.6
FTIRS QA/QC PROCEDURES 6-1
CEMS QA/QC PROCEDURES 6-5
GCMS QA/QC PROCEDURES 6-14
CARB 429 QA/QC CHECKS 6-19
CORRECTIVE ACTIONS 6-26
DATA QUALITY ASSESSMENT 6-30
APPENDIX A
APPENDIX B
SUBCONTRACTOR TEST REPORT - COLORADO STATE
UNIVERSITY ENGINES AND ENERGY CONVERSION
LABORATORY, "EMISSIONS TESTING OF CONTROL DEVICES
FOR RECIPROCATING INTERNAL COMBUSTION ENGINES IN
SUPPORT OF REGULATORY DEVELOPMENT BY THE U.S.
ENVIRONMENTAL PROTECTION AGENCY (EPA) PHASE 1:
TWO-STROKE, LEAN BURN, NATURAL GAS FIRED INTERNAL
COMBUSTION ENGINES"
SUBCONTRACTOR TEST REPORT - EMISSION MONITORING,
INC. "RESULTS OF DIRECT INTERFACE GCMS TESTING
CONDUCTED ON A 2-STROKE LEAD BURN ENGINE"
VOLUME 2
APPENDDC C SUBCONTRACTOR TEST REPORT - EASTERN RESEARCH
GROUP, INC. "CARB METHOD 429: SAMPLE ANALYSIS"
APPENDIX D CARB METHOD 429 FIELD DATA
IV
-------
LIST OF TABLES
VOLUME 1
Table 2.1 Emissions Test Log 2-2
Table 2.2 Summary of Exhaust Gas Flow Rates 2-4
Table 2.3 Emission Rates of Detected FTIRS and CEM Compounds 2-8
Table 2.4 Emission Rates of Detected GCMS Compounds 2-10
Table 2.5 Summary of Stack Gas and Sampling Parameters GARB 429
Catalyst Inlet and Outlet 2-14
Table 2.6 Emission Rates of Detected PAHS at Catalyst Inlet 2-15
Table 2.7 Emission Rates of Detected PAHS at Catalyst Outlet 2-16
Table 2.8 Removal Efficiencies of Detected Organic Compounds 2-18
Table 3.1 Engine and Catalyst Specifications 3-2
Table 3.2 Summary of Nominal Engine Parameters 3-3
Table 3.3 Target Engine Operating Conditions During Testing 3-5
Table 3.4 Summary of Engine Parameters - Cooper Bessemer GMV-4-TF 3-7
Table 3.5 Summary of Engine Parameters During Baseline Runs 3-9
Table 5.1 Summary of Sampling and Analysis Methods 5-2
Table 6.1 Detection Limits of FTIRS and CEMS Compounds 6-7
Table 6.2 Types and Frequencies of CEMS Analyzer Calibrations 6-10
Table 6.3 Summary of Fuel Factor Values 6-13
Table 6.4 Summary of CEMS Analytical Detection Limits 6-14
Table 6.5 Summary of GCMS Continuing Calibrations and Audit Results 6-16
Table 6.6 Detection Limits of GCMS Compounds at Catalyst Inlet 6-17
Table 6.7 Detection Limits of GCMS Compounds at Catalyst Outlet 6-18
Table 6.8 CARB 429 Sample Train - Summary of Temperature Sensor
Calibration Data 6-20
Table 6.9 CARB 429 Sample Train - Summary of Dry Gas Meter and Orifice
Calibration Data 6-21
Table 6.10 Summary of CARB 429 Blank Results 6-24
Table 6.11 Summary of CARB 429 Surrogate Recoveries 6-25
Table 6.12 Detection Limits of PAH Compounds at Catalyst Inlet 6-27
Table 6.13 Detection Limits of PAH Compounds at Catalyst Outlet 6-28
Table 6.14 Summary of Corrective Actions 6-29
Table 6.15 Summary of Engine and Method Performance 6-32
-------
LIST OF FIGURES
VOLUME 1 Page
Figure 1.1 Test Program Organization and Major Lines of Communication 1-3
Figure 4.1 Sample Port Locations for Velocity, CARB 429, FTIRS, CEMS,
and GCMS Sampling 4-3
Figure 4.2 Sample Point Locations for Velocity and CARB 429 Sampling 4-4
Figure 5.1 Schematic Diagram of EECL CEMS/FTIRS Sampling and
Analysis System 5-5
Figure 5.2 Schematic of GCMS Sampling and Analysis System 5-10
Figure 5.3 Schematic Diagram of CARB 429 PAH Sampling Train 5-12
VI
-------
APPENDIX C
SUBCONTRACTOR TEST REPORT
EASTERN RESEARCH GROUP, INC.
"CARB METHOD 429: SAMPLE ANALYSIS"
-------
CARB Method 429: Sample Analysis
Contract #68-D7-0069-WA213-ERG
Prepared for:
Dennis Falgout
Pacific Environmental Services, Inc.
560 Herndon Parkway, Suite 200
Herndon. VA 22070
Prepared by:
Joan Bursey
Eastern Research Group, Inc.
P. O. Box 2010
Mordsville, NC 27560
December 1999
EASTERN RESEARCH GROUP, INC
-------
CARB Method 429: Sample Analysis
Contract #68-D7-0069-WA213-ERG
Prepared for:
Dennis Falgout
Pacific Environmental Services, Inc.
560 Herndon Parkway. Suite 200
Herndon, VA 22070
Prepared by:
Joan Bursey
Eastern Research Group. Inc.
P. O. Box 2010
Morrisville. NC 27560
December 1999
-------
FASTFRN RFS^ARCH GROUP INC
ATTACHMENT 1
P.O. Box 2010
Morrisville, NC27560
Ph.(919)468-7800
NARRATIVE
Site: Cooper-liessemer GMB-4VTF
Ft. Collins, CO
Prepared for: Pacific Environmental Services
Description of Procedures for Modified Method CARB 429 and Observations
Sample Collection Dates: April 2,1999
Sample Preparation
Filters/XAD
Procedure—The filters and XAD were placed into soxhiets and extracted for approximately
18 hours with methylene chloride. Surrogates were added to the soxhiets to assure that the
method produced acceptable recoveries.
Observations—The filters were fairly clean and free of particulates: the XAD had some
discoloration. Some of the XAD was slightly yellow in color. After pouring methylene chloride
through the XAD, some of the color came off, but even after 18 hours of extractions, some of the
XAD retained the yellow color and was eventually discarded.
Front Half, Back Half, and Inipinger Rinses
Procedure—All three rinses were combined, then poured through a bed of sodium s LI I fate to
remove any water that might have been present. This fraction was eventually combined with the
rest of the other fractions for concentration.
Observations—No observations out of the ordinary were noted.
CahAK \0122\WA2-1\NARRATIV WPD
notify
Ux>\> J c><
-------
Impinger Rinses
Procedure—The impinger rinses were poured into individual separatory funnels for extraction.
Into each separatory funnel approximately 200 mL of HPLC grade methylene chloride was
added. The samples were shaker, for approximately 3 minutes and then allowed to separate.
After separation, the bottom methylene chloride layer was drained into a clean, pre-rinsed beaker.
This procedure was then repeated two more times. The final extract was then set aside to be later
combined with the other fractions.
Observations—No obser\ ations out of the ordinary were noted.
Reagent Blanks
Procedure—The volumes for the acetone, hexane and methylene chloride reagent blanks were
noted and these samples were (hen concentrated to 1 mL. The water reagent blank was extracted
using separatory funnel extraction with methylene chloride as the solvent. This extract was then
concentrated to I mL.
Observations—No observations out of the ordinary were noted.
All Samples
Procedure—After all components of the sample had been extracted, they were all combined into
a 1000 mL Kuderna-Danish flask. The samples were concentrated until approximately 10-15 mL
of solvent remained. The last 10-15 mL of solvent was evaporated using a nitrogen blowdown
apparatus. The samples were adjusted to a final volume of I mL with hexane. The final sohent
for the samples is hexane.
Sample Analysis Using Gas Chromatosraphy/Mass Spectrometr\
Combined Sample Extract Analvsis b\ CC/MS
Procedure—All the sample extracts were analyzed by the California Air Resources Board
Method 429 (Determination of Polycyclic Aromatic Hydrocarbon (PAH) Emissions from
Stationary Sources) using a Hewlett Packard 5989B Mass Spectrometer operating in the selected
ion mode (SIM).
Observations—No problems were encountered with the analysis of the sample extracts, although
there were problems with surrogate recoveries from the laboratory XAD-2® blank . Several PNA
compounds such as dl(l-anthracene. dr-benzo(a)pyrene. di:-benzo(a)anthracene. and
d|2-benzo(g.h.i.)perylene demonstrated low recoveries due to the compounds' lack of solubility
in hexane. Oxidation by the source effluent may also contribute to the low recoveries of the
surrogates in the field samples. Clean-up procedures to remove the hydrocarbons present in the
Cah \K\0122WA2-1\NARRATIVWPD 2
-------
sample extracts and the removal of hexane as a probe rinse could enhance the method's ability to
recover specific PNAs. One solution would be to substitute toluene as a rinse or analyze the
probe rinse separately.
Compound concentrations were corrected for surrogate recoveries when surrogate recoveries
were below 100 percent. Target compounds were also flagged if they were detected below the
practical quantitation limit (PQL) with a "U". The PQL is as follows:
Compound Total ng
Naphthalene 500
Acenaphthylene 500
Acenaphthene 500
Fluorene 500
Phenanthrene 500
Anthracene 500
Fluoranthene 500
Pyrene 500
Benzo(a)anthracene 500
Chry.sene 500
Benzo(b)fluoranthene 500
Benzo(k)fluoranthene 500
Benzol a)pyrene 500
lndeno( 1.2,3-cd)pyrene 1.000
Dibenz(a.h)anthracene 1.000
Benzo(g.h.i)perylene 1,000
The sample results are presented in Table 1.
Cah \K ,0122VWA2-1 \NARRATIV WPD
-------
PES • CARB Method 429
Table 1.
Field ID
Sample ID
Data File
Date Sampled
Date Analyzed
Units:
Naphthalene
Acenaphthylene
Acenaphthene
:luorene
Phenanthrene
Anthracene
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
3enzo(b)fluoranthene
Benzo(k)fluoranthene
Benzo(a)pyrene
lndeno(1 ,2,3-cd)pyrene
Dibenz(a,h)anthracene
Benzo(g,h,i)perylene
Surrogate Recoveries
Units:
Naphthalene-dS
Acenaphthylene-d8
Acenaphthene-d1 0
Fluorene-d10
Phenanthrene-d10
Anthracene-d10
Fluoranthene-d10
Pyrene-d10
Benzo(a)anthracene-d12
Chrysene-d12
Benzo(b)f Iuoranthene-d1 2
Benzo(k)fluoranthene-d1 2
Benzo(a)pyrene-d12
lndeno(1 ,2,3-cd)pyrene-d1 2
Dibenz(a,h)anthracene-d14
Benzo(g,h,i)perylene-d12
Recovery Standard
Units:
2-Methlynaphthalene-d10
p-Terphenyl-d14
...
Laboratory
Blank
ENG1316.D
—
05/18/99
Total ng
3,780
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
%
86
45
64
80
73
1
73
39
10
68
74
73
ND
32
34
ND
%
NS
NS
CB-429-B-Hex
Hexane
Blank
ENG1317.D
—
05/18/99
Total ng
6 U
ND
ND
ND
35 U
8 U
6 U
ND
ND
ND
ND
ND
ND
ND
ND
ND
%
NS
NS
NS
NS
NS
NS
NS
NS
NS
NS
NS
NS
NS
NS
NS
NS
%
NS
NS
CB-429-B-Ace
Acetone
Blank
ENG1318.D
...
05/18/99
Total ng
ND
ND
ND
ND
10
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
%
NS
NS
NS
NS
NS
NS
NS
NS
NS
NS
NS
NS
NS
NS
NS
NS
%
NS
NS
CB-429-B-MeCI
Methylene Chloride
Blank
ENG1319.D
—
05/18/99
Total ng
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
%
NS
NS
NS
NS
NS
NS
NS
NS
NS
NS
NS
NS
NS
NS
NS
NS
%
NS
NS
U = Detected below the PQL
ND = Not detected
NS = Not spiked
pes_pna.xls
-------
PES • CARB Method 429
Table 1.
Sample ID
Data File
Date Sampled
Date Analyzed
Units:
Naphthalene
Acenaphthylene
Acenaphthene
Fluorene
Phenanthrene
Anthracene
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Benzo(a)pyrene
lndeno(1 ,2,3-cd)pyrene
Dibenz(a,h)anthracene
Benzo(g,h,i)perylene
Surrogate Recoveries
Units:
Naphthalene-d8
Acenaphthylene-d8
Acenaphthene-d1 0
Fluorene-d10
Phenanthrene-d10
Anthracene-d10
Fluoranthene-d10
Pyrene-d10
Benzo(a)anthracene-d1 2
Chrysene-d12
Benzo(b)fluoranthene-d12
Benzo(k)f!uoranthene-d1 2
Benzo(a)pyrene-d12
Indeno(1,2,3-cd)pyrene-d12
Dibenz(a,h)anthracene-d14
Benzo(g,h,i)perylene-d1 2
Recovery Standard
Units:
2-Methlynaphthalene-d10
p-Terphenyl-d14
Dl Water
Blank
ENG1320.D
—
05/18/99
Total ng
12 U
ND
ND
ND
4 U
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
%
NS
NS
NS
NS
NS
NS
NS
NS
NS
NS
NS
NS
NS
NS
NS
NS
%
NS
NS
CB-429-B
Dl Water
Blank
ENG1320.D
—
05/18/99
Total ng
12 U
ND
ND
ND
4 U
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
%
NS
NS
NS
NS
NS
NS
NS
NS
NS
NS
NS
NS
NS
NS
NS
NS
%
NS
NS
CB-429-I-FB
Inlet XAD
Blank
ENG1324.D
4/2/99
05/19/99
Total ng
3,352
ND
ND
ND
54 U
ND
ND
29 U
0
46 U
ND
ND
ND
ND
ND
ND
%
74
48
70
74
70
10
76
71
68
85
109
82
ND
77
82
53
%
60
44
CB-429-O-FB
Outlet XAD
Blank
ENG1325.D
4/2/99
05/19/99
Total ng
3,425
ND
ND
ND
43 U
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
%
81
24
74
76
71
11
73
61
46
76
87
76
ND
48
57
7
%
64
42
U = Detected below the PQL
ND = Not detected
NS = Not spiked
Afv^'•V'V.'} I
Utt;^-:jl
pes_pna.xls
-------
PES - CARB Method 429
Table 1.
Field ID
Sample ID
Data File
Date Sampled
Date Analyzed
Units:
Maphthalene
Acenaphthyfene
Acenaphthene
Fluorene
Phenanthrene
Anthracene
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
Benzo(b}fluoranthene
Benzo(k)fluoranthene
Benzo(a)pyrene
lndeno(1 ,2,3-cd)pyrene
Dibenz(a,h)anthracene
Benzo(g,h,i)perylene
Surrogate Recoveries
Units:
Naphthalene-d8
Acenaphthylene-d8
Acenaphthene-d10
Fluorene-d10
Phenanthrene-d10
Anthracene-d10
Fluoranthene-d10
Pyrene-d10
Benzo(a)anthracene-d12
Chrysene-d12
Benzo(b)fluoranthene-d1 2
Benzo(k)fluoranthene-d1 2
Benzo(a)pyrene-d1 2
lndeno(1 ,2,3-cd)pyrene-d1 2
Dibenz(a,h)anthracene-d14
Benzo(g,h,i)perylene-d1 2
Recovery Standard
Units:
2-Methlynaphthalene-d10
p-Terphenyl-d14
CB-429-M
Inlet 1
ENG1350.D
4/2/99
05/25/99
Total ng
17,155
ND
759
1,261
1,592
ND
ND
239 U
82 U
212 U
ND
ND
ND
ND
ND
ND
%
83
51
70
85
80
29
94
91
107
144
98
86
9
58
63
47
%
68
91
CB-429-I-2
Inlet 2
ENG1330.D
4/2/99
05/19/99
Total ng
10,934
531
180 U
ND
1,323
ND
266 U
316 U
ND
ND
ND
ND
ND
ND
ND
ND
%
96
58
83
97
116
30
137
133
111
125
143
127
13
70
80
57
%
78
116
CB-429-I-3
Inlet 3
ENG1349.D
4/2/99
05/25/99
Total ng
11,233
ND
ND
318 U
870
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
%
89
58
72
91
88
34
101
100
110
113
113
108
19
61
70
54
%
71
81
U = Detected below the PQL
ND = Not detected
NS = Not spiked
;*"*. ,
pes_pna.xls
-------
PES - CARB Method 429
Table 1.
U = Detected below the PQL
ND = Not detected
NS = Not spiked
Field ID
Sample ID
Data File
)ate Sampled
Date Analyzed
Units:
Naphthalene
Acenaphthylene
Acenaphthene
:luorene
'henanthrene
Anthracene
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
Benzo(b)f1uoranthene
5enzo(k)fluoranthene
Benzo(a)pyrene
lndeno(1 ,2,3-cd)pyrene
Dibenz(a,h)anthracene
Benzo(g,h,i)perylene
Surrogate Recoveries
Units:
Naphthalene-d8
Acenaphthylene-d8
Acenaphthene-d1 0
:luorene-d10
Phenanthrene-d1 0
Anthracene-d10
rluoranthene-d10
Pyrene-d10
3enzo(a)anthracene-d12
Chrysene-d12
Benzo(b)fluoranthene-d1 2
Benzo(k)fluoranthene-d1 2
3enzo(a)pyrene-d1 2
lndeno(1 ,2,3-cd)pyrene-d1 2
Dibenz(a,h)anthracene-d14
Benzo(g,h,i)perylene-d12
Recovery Standard
Units:
2-Methlynaphthalene-d10
p-Terphenyl-d14
CB-429-O-1
Outlet 1
ENG1326.D
4/2/99
05/19/99
Total ng
8,802
614
ND
ND
792
ND
116 U
ND
ND
ND
ND
ND
ND
ND
ND
ND
%
106
69
97
92
73
30
63
60
73
63
96
80
29
97
107
98
%
80
50
CB-429-O-2
Outlet 2
ENG1327.D
4/2/99
05/19/99
Total ng
8,056
500
ND
ND
547
110 U
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
%
111
69
93
99
69
34
67
65
61
71
0
0
32
49
54
46
%
83
60
CB-429-O-3
Outlet 3
ENG1328.D
4/2/99
05/19/99
Total ng
8,069
512
ND
ND
570
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
%
117
63
86
100
88
50
109
107
113
115
125
107
47
71
81
70
%
95
107
oc>
pes_pna.xls
-------
ERG PPK Sample Prep Traveler
Project Name:
Analysis Type:
Analyst:
Date released:
PES
MS
Amy Frame ^^/^2—f
-------
O PACIFIC ENVIRONMENTAL SERVICES. INC.
Central Park West
5001 South Miami Boulevard. P.O. Box 12077
Research Triangle Park, North Carolina 27709-2077
(919) 941-0333 FAX: (919) 941-0234
Chain of Custody Record
Project Num
S513000
Project Name
RICE
Samplers:
Maret, Mike
Date
fwMb/Ai
red by: (Signaiurk) / / ' /
Received for lab by (Signature)
Analysis Requested
Relinquished by. (Signature)
'w
Relinquished by: (Signature)
Date/Time
Date/Time
REMARKS
Remarks
<^M^7 ^f.\f 1 ^
4la*M
\
Received by (Signature)
Received by. (Signature)
(Page. of
CJ
c
-------
O PACIFIC ENVIRONMENTAL SERVICES. INC.
Central Park West
5001 South Miami Boulevard, P.O. Box 12077
Research Triangle Park, North Carolina 27709-2077
(919)941-0333 FAX: (919) 941-0234
Chain of Custody Record
Project Num
S51 3.000
Project Name
RICE
Samplers:
Maret, Mike
Date
V'3-i*!
V
f
Time
0*l<,
V
Field Sample ID
CB-429-O-1-BH
CB-429-0-1-F
CB-429-O-1-FH
CB-429-O-1-IC
CB-429-O-1-IR
CB-429-O-2-BH
CB-429-O-2-F
CB-429-O-2-FH
CB-429-O-2-IC
CB-429-O-2-IR
CB-429-O-3-BH
CB-429-O-3-F
CB-429-O-3-FH
CB-429-O-3-IC
CB-429-O-3-IR
Relinquished by (Signature)
' JjymJ-l' \P"YUA»^VJ*'X
Relinquished by. (Signature)
Relinquished by. (S gnature)
Date/Time/
Date/Time
Date/Time
Sample Description
Back Half Ace/Hexane/MeCI rince
Filter, dry
Front Half Ace/Hexane/MeCI rince
Impinger Contents
Impinger Ace/Hexane/MeCI rince
Back Half Ace/Hexane/MeCI rince
Filter, dry
Front Half Ace/Hexane/MeCI rince .
Impinger Contents
Impinger Ace/Hexane/MeCI rince
Back Half Ace/Hexane/MeCI rince
Filter, dry
Front Half Ace/Hexane/MeCI rince
Impinger Contents
Impinger Ace/Hexane/MeCI rince
^-^
Reo
Analysis Requested
ived by: (Signature) / i Relinquished by: (Signature)
Received by: (SigiiatuVe) / / J 1 J Relinquished by (Signature)
J \J '
Date/Time
Date/Time
Received for lab by (Signature) REMARKS
Remarks
Received by: (Signature)
Received by: (Signature)
'""""I ; "' 4 •
-------
/ZZ7/ /( /
Q PACIFIC ENVIRONMENTAL SERVICES. INC.
Central Park West
5001 South Miami Boulevard, P.O. Box 12077
Research Triangle Park, North Carolina 27709-2077
(919) 941-0333 FAX: (919) 941-0234
Chain of Custody Record
Project Num
S51 3.000
Samplers.
Maret. Mike
Date
Time
0«lS
v.
J
Project Name
RICE
Field Sample ID
CB-429-I-1-BH
CB-429-I-1-F
CB-429-I-1-FH
CB-429-I-1-IC
CB-429-I-1-IR
CB-429-I-2-BH
CB^29-l-2-F
CB-429-I-2-FH
CB-429-I-2-IC
CB-429-I-2-IR
CB-429-I-3-BH
CB-429-I-3-F
CB-429-I-3-FH
CB-429-I-3-IC
CB-429-I-3-IR
Relinquished by (Signature)
CU~ fc. V^JUU
Relinquished by: (Signature)"
Relinquished by: (Signature)
Date/Time
V'/S-^r?
Date/Time
Date/Time
Sample Description
Back Half Ace/Hexane/MeCI rince
Filter, dry
Front Half Ace/Hexane/MeCI rince
Impinger Contents
Impinger Ace/Hexane/MeCI rince
Back Half Ace/Hexane/MeCI rince
Filter, dry
Front Half Ace/Hexane/MeCI rince
Impinger Contents
Impinger Ace/Hexane/MeCI rince
Back Half Ace/Hexane/MeCI rince
Filter, dry
Front Half Ace/Hexane/MeCI rince
Impinger Contents
Impinger Ace/Hexane/MeCI rince
Analysis Requested
P
K
rV
Received by (Signature) / Relinquished by. (Signature)
V/fr'^w llvfa
Received by: (Signature) ' 1 f j Relinquished by (Signature)
Date/Time
Date/Time
Received (or lab by. (Signature) REMARKS
Remarks
Received by. (Signature)
Received by: (Signature)
|Page of
v _-
f
-------
O PACIFIC ENVIRONMENTAL SERVICES. INC.
Central Park West
5001 South Miami Boulevard, P.O. Box 12077
Research Triangle Park, North Carolina 27709-2077
(919) 941-0333 FAX: (919) 941-0234
Chain of Custody Record
Project Num
S51 3.000
Samplers:
Maret, Mike
Date
V-/3^
'
^
Time
a,*.^
s
'
Project Name
RICE
Field Sample ID
CB-429-B-Ace
CB-429-B-DI
CB-429-B-F
CB-429-B-Hex
CB-429-B-MeCI
CB-429-B-XAD
CB-429-I-FB-BH
CB-429-I-FB-F
CB-429-I-FB-FH
CB-429-I-FB-IC
CB-429-I-FB-XAD
CB-429-O-FB-BH
CB-429-O-FB-F
CB-429-O-FB-IC
CB-429-O-FB-XAD
Relinquished by: (Signature)
^J/£*«*V VvSAujfct**-^
Relinquished by (Signature)
Relinquished by (S gnature)
Date/Time
Date/Time
Date/Time
Sample Description
Acetone
Dl Water
Filter, dry
Hexane
Methylene Chloride
XAD Sorbent Module
Back Half Ace/Hexane/MeCI rince
Filter, dry
Front Half Ace/Hexane/MeCI rince
Impinger Contents
XAD Sorbent Module
Back Half Ace/Hexane/MeCI rince
Filter, dry
Impinger Contents
XAD Sorbent Module
/
Analysis Requested
/Keceived by (Signatufe// . > Relinquished by: (Signature)
Received by (Signaiurfe) / / / Relinquished by: (Signature)
\J
Daten"ime
Date/Time
Received for lab by (Signature) REMARKS
Remarks
Received by (Signature)
Received by (Signature)
i , 'lage-j «of » .
*__^_* "^^ -• m • •
-------
( /
O PACIFIC ENVIRONMENTAL SERVICES. INC.
Central Park West
5001 South Miami Boulevard, P.O. Box 12077
Research Triangle Park, North Carolina 27709-2077
(919) 941-0333 FAX: (919) 941-0234
Chain of Custody Record
Project Num
S51 3.000
Project Name
RICE
Samplers:
Maret, Mike
Date
«HS-n
V
f
Time
OSK>
V
Field Sample ID
CB-429-I-1-XAD
CB-429-I-2-XAD
CB-429-I-3-XAD
CB-429-O-1-XAD
CB-429-O-2-XAD
CB^429-O-3-XAD
Relinquished by: (Signature)
0*** M!{{/(^
Relinquished by (Signature)
Relinquished by: (Signature)
Date/Time
DateHlme
Date/Time
Sample Description
XAD Sorbent Module
XAD Sorbent Module
XAD Sorbent Module
XAD Sorbent Module
XAD Sorbent Module
XAD Sorbent Module
Re'ceWed by: (Sig0fftu/e) / )
Received by (S/gJatuJe) Ij 'l
Received for lab by: (Signature)
Analysis Requested
Relinquished by: (Signature)
Relinquished by: (Signature)
Date/Time
Date/Time
REMARKS
Remarks
Received by: (Signature)
Received by: (Signature)
|Page: of
-------
'PACIFIC ENVIRONMENTAL SERVICES. INC.
Central Park West
5001 South Miami Boulevard, P.O. Box 12077
Research Triangle Park, North Carolina 27709-2077
(919)941-0333 FAX: (919) 941-0234
Chain of Custody Record
Project Num
S513 000
Project Name
RICE
Samplers:
Maret, Mike
Date
J3 ^
\
,}
Time
-
v/
Field Sample ID
CB-429-O-1-BH
CB-429-O-1-F
CB-429-O-1-FH
CB-429-O-1-IC
CB-429-O-1-IR
CB-429-O-2-BH
CB-429-O-2-F
CB-429-O-2-FH
CB-429-O-2-IC
CB-429-O-2-IR
CB-429-O-3-BH
CB-429-O-3-F
CB-429-O-3-FH
CB-429-O-3-IC
CB-429-O-3-IR
Relinquished by. (Signature)
Relinquished by: (Signature)
Relinquished by (S gnature)
Date/Time/
Date/Time
Date/Time
Sample Description
Back Half Ace/Hexane/MeCI rince
Filter, dry
Front Half Ace/Hexane/MeCI rince
Impinger Contents
Impinger Ace/Hexane/MeCI rince
Back Half Ace/Hexane/MeCI rince
Filter, dry
Front Half Ace/Hexane/MeCI rince .
Impinger Contents
Impinger Ace/Hexane/MeCI rince
Back Half Ace/Hexane/MeCI rince
Filter, dry
Front Half Ace/Hexane/MeCI rince
Impinger Contents
Impinger Ace/Hexane/MeCI rince
^^^
Red
Analysis Requested
ived by (Sigrratu/e) / i Relinquished by: (Signature)
Received by: (SigJiatu/e) // 7/ / Relinquished by. (Signature)
(/ '
Date/Time
Date/Time
Received for lab by: (Signature) REMARKS
Remarks
Received by: (Signature)
Received by. (Signature)
_- : ;'P1£=! nk=| J
-------
O PACIFIC ENVIRONMENTAL SERVICES. INC.
Central Park West
5001 South Miami Boulevard, P.O. Box 12077
Research Triangle Park, North Carolina 27709-2077
(919) 941-0333 FAX: (919) 941-0234
Chain of Custody Record
Project Num
S51 3.000
Project Name
RICE
Samplers:
Maret, Mike
Date
J
Time
O^?' ^>
•v,
J
Field Sample ID
CB-429--1-BH
CB-429--1-F
CB-429--1-FH
CB-429--1-IC
CB-429--1-IR
CB-429- -2-BH
CB-429- -2-F
CB-429- -2-FH
CB-429- -2-IC
CB-429- -2-IR
CB-429- -3-BH
CB-429- -3-F
CB-429- -3-FH
CB-429- -3-IC
CB-429- -3-IR
Relinquished by: (Signature)
0«^ &. VVW^
Relinquished by: (Signature)
Relinquished by: (Signature)
Date/Time
H-rt-tfi
Date/Time
Date/Time
Sample Description
Back Half Ace/Hexane/MeCI rince
Filter, dry
Front Half Ace/Hexane/MeCI rince
Impinger Contents
Impinger Ace/Hexane/MeCI rince
Back Half Ace/Hexane/MeCI rince
Filter, dry
Front Half Ace/Hexane/MeCI rince
Impinger Contents
Impinger Ace/Hexane/MeCI rince
Back Half Ace/Hexane/MeCI rince
Filter, dry
Front Half Ace/Hexane/MeCI rince
Impinger Contents
Impinger Ace/Hexane/MeCI rince
Received by: (Signatufe) ^
Q fl'J»M 7/9 4*
Received by: (Signature) J /
Received for lab by: (Signature)
Analysis Requested
P
P\
*
Relinquished by. (Signature
Relinquished by: (Signature)
Dateffime
Dateffime
REMARKS
Remarks
Received by: (Signature)
Received by: (Signature)
|Page: of
c
-------
Q PACIFIC ENVIRONMENTAL SERVICES, INC.
Central Park West
5001 South Miami Boulevard, P.O. Box 12077
Research Triangle Park, North Carolina 27709-2077
(919)941-0333 FAX: (919) 941-0234
Chain of Custody Record
Project Mum
S513.000
Samplers:
Maret
Date
^-/5-1-H
\>
f
Project Name
RICE
Mike
Time
oa» Gd2,M
Relinquished by: (Signature)
Relinquished by: (Signature)
Date/Time
V-/3*fi
Dateffime
Date/Time
Sample Description
XAD Sorbent Module
XAD Sorbent Module
XAD Sorbent Module
XAO Sorbent Module
XAD Sorbent Module
XAD Sorbent Module
Rrfcdived by: (Siguffiu/e) / )
U/IWV w?f
Received by: (SigJatufe) IJ 'I I
deceived for lab by: (Signature)
Analysis Requested
Relinquished by: (Signature)
Relinquished by: (Signature)
Date/Time
Date/Time
REMARKS
Remarks
Received by: (Signature)
Received by: (Signature)
_<— JEas j^f i_
-------
PES Stocks
Pre-spike solution:
PES-JEM-032299-01
p-Terphenyl-d14
2-Methylnaphthalene-d10
Pre-spike solution:
PES-JEM-032299-02 *
p-Terphenyl-d14
2-Methylnaphthalene-d10
Manufacturer
Chem Service
Aldrich
Lot*
214-144A
0241 5BQ
Initial
Cone
(ug/mL)
2000
Initial
Cone
(ug/mL)
2000
2026
Raw
Amount
(g)
0.01013
Initial
Volume
(mL)
1
1
Solution
Volume
(mL)
5
5
Final
Volume
(mL)
50
50
Final
Cone
(ug/mL)
2000
2026
Final
Cone
(ug/mL)
40.0
40.5
* Dilution made from PES-JEM-032299-02
D-labelled
PES-JEM-041 499-01
Acenaphthalene-d10
Acenaphthylene-d8
Anthracene-d10
Benz[a]anthracene-d12
Benzo[b]fluoranthene-d12
Benzo[k]fluoranthene-d12
BenzO[ghi]perylene-d12
Benzo[a]pyrene-d12
Chrysene-d12
Dibenz[ah]anthracene-d14
Fluoranthene-d10
Fluorene-d10
lndeno[1 23-cd]pryene-d1 2
Naphthalene-d8
Phenanthrene-d10
Pyrene-d10
Manufacturer
CIL
CIL
CIL
CIL
CIL
CIL
CIL
CIL
CIL
CIL
CIL
CIL
CIL
CIL
CIL
CIL
Manufacturer
Lot*
IG-248
IG-248
IG-248
IG-248
IG-248
IG-248
IG-248
IG-248
IG-248
IG-248
IG-248
IG-248
IG-248
IG-248
IG-248
IG-248
Lot*
Initial
Cone
(ug/mL)
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
Initial
Cone
(ug/mL)
Initial
Volume
(mL)
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
Initial
Volume
(mL)
Final
Volume
(mL)
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
Raw
Amount
(g)
Final
Cone
(pg/mL)
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
Solution
Volume
(mL)
•
Final
Cone
(ug/mL)
Internal Standard
PES-JEM-051199-01
2,2-Difluorobiphenyl AccuStandard
Methylene Chloride Lot # - B & J BS575
A7120073
2,002
0.25
500.6
Page!
OC03933
-------
PES Stocks (2)
Manufacturer
Lot*
Initial
Cone
(ug/mL)
Chem Service
Aldrich
Pre-spike solution:
PES-JEM-032299-01
p-Terphenyl-d14
2-Methylnaphthalene-d10
Pre-spike solution:
PES-JEM-082399-01 *
p-Terphenyl-d14
2-Methylnaphthalene-d10
• Dilution made from PES-JEM-032299-01
214-144A
02415BQ
2000
Initial
Cone
(ug/mL)
2000
2026
Raw Solution Final
Amount Volume Cone
(g) (mL) (ug/mL)
0.01013
5
5
Initial Final
Volume Volume
(ml) (mL)
2000
2026
Final
Cone
0.1
0.1
50
50
4.0
4.1
Pagel
OCC3034
-------
PES: STANDARDS PREPARATION
ChmJcalNm*
Ifephthilene
i-MelhymphUulaw-dlO
Acenaphthew-dlO
Pluonne-dlO
Fluonne
Phenanthraw-dlO
Phenanthnne
Anthracene-dIO
Anthracene
Pluoranthene-dlO
Fluoranlhene
Pvrene-dlO
p-Tefphenyl-dl4
Benzo(a)anthncene-dl 2
Benzo(a)anthncene
0-222^
Stock COM.
0.10 1.0 1.0
0.10 1.0 1.0
0.10 1.0 1.0
0.10 1.0 1.0
0.10 1.0 1.0
0.10 1.0 1.0
PESMAJMSUM-04
A»M.t nwl SMCMc.
Spik*4<«L) VdnM(«L) (M/»tL)
025 1.0 2.5
0.25 1-0 2.5
0.25 1.0 2.5
0.25 1.0 2.5
0.25 1.0 2.5
0.25 1.0 2.5
0.25 1.0 2-5
0.25 1-0 2.5
0.25 1.0 2.5
0.25 1.0 2.5
0.25 1.0 2.5
0.25 1.0 2.5
0.25 1.0 2.5
0.25 1-0 2.5
0.25 1.0 2.5
0.25 1.0 2.5
0.25 1.0 2.5
0.25 1.0 2.5
0.25 1.0 2.5
0.25 1.0 2.5
0.25 1.0 2.5
0.25 1.0 2.5
0.25 1.0 2.5
0.25 1.0 2.5
0.25 1.0 2.5
0.25 1.0 2.5
0.25 1.0 2.5
0.25 1.0 2.5
0.25 1.0 2.5
0.25 1.0 2.5
FES-HAH-MU»»-<»
AiMUt PbMl SMCMC.
SplkW(«L) V.IMM (•>!,) (M/taL)
0.50 1 00 5.0
0.50 1.00 5.0
030 1.00 5.1
0.50 1.00 5.0
0.50 1.00 5.0
0.50 1.00 5.0
0 50 1 00 5.0
0.50 1.00 5.0
0.50 1.00 5.0
0.50 1.00 5.0
0.50 1.00 5.0
0.50 1.00 5.0
0.50 1.00 5.0
0.50 1.00 5.0
050 1 00 50
0.50 1.00 5.0
0.50 1.00 5.0
0.50 1.00 5.0
050 1.00 5.0
0.50 1.00 5.0
030 1 00 5.0
0.50 1.00 5.0
0.50 1.00 5.0
030 1.00 5.0
030 1.00 5.0
0.50 1.00 5.0
030 1.00 5.0
030 1.00 5.0
030 1.00 5.0
0.50 1.00 5.0
0.50 1.00 5.0
0.50 1.00 5.0
0.50 1. 00 5.0
o
-------
PES: STANDARDS PREPARATION
Chwlnl Nun
2-Methynaphtlulone-dlO
(\cenaphthylene-d8
Aceiuphlhylene
taenaphthene-dl 0
Fluorenc-dIO
Fluocene
Phenanthrane-dlO
tathncene-dl 0
Anthracene
Fluonuithene
Pyrene-dlO
Slock CMC.
7.0
0.70 1.0 7.0
0.70 1-0 7.0
0.70 U> 7.0
0.70 1-0 7.0
070 1.0 7.0
070 1.0 7.0
0.70 1.0 7.0
0.70 1.0 7.0
0.70 1.0 7.0
070 1.0 7.0
070 1.0 7.0
0.70 1.0 7.0
070 1.0 7.0
070 1.0 7.0
070 1.0 7.0
0.70 1.0 7.0
0.70 1.0 7.0
0.70 1 .0 7.0
0.70 1 .0 7.0
PES-MAH451Z99-01
A»o»l Flul Sid Co.c.
Spiked («L) V«|MM <«L) (ft/mL)
0.50 5.0 10.0
0.025 5.0 10.0
0.025 5.0 10.1
0.50 5.0 10.0
0.025 5.0 10.0
0.50 5.0 10.0
0.025 5.0 10.0
0.50 5.0 10.0
0.025 5.0 10.0
0.50 5.0 10.0
0.025 5.0 10.1
0.50 5.0 10.0
0.025 5.0 10.1
0.50 5.0 10.0
0.025 5.0 10.0
0.50 5.0 10.0
0.025 5.0 10.0
0.025 5.0 10.0
0.50 5.0 10.0
0.50 5.0 10.0
0.025 5.0 10.0
0.50 5.0 10.0
0.025 5.0 10.0
0.50 5.0 10.0
0.025 5.0 10.0
0.50 5.0 10.0
0.025 5.0 10.1
0.50 5.0 10.0
0.025 5.0 10.0
0.50 5.0 10.0
0.025 5.0 10.0
0.50 5.0 10.0
PES-MAH-051899-ai
Anroml FUi.l Sid CMC.
Spiked (ML) Vol«M(»L) («/«L)
0.15 1.0 15-0
0.0075 1.0 15.0
0.0075 1.0 15-2
0.15 1-0 15.0
0.0075 1.0 15-1
0.15 . 1.0 15.0
0.0075 1.0 15-1
0.15 1-0 15.0
0.0075 1-0 15-1
0.15 1-0 15.0
0.0075 1-0 15.1
0.15 1.0 15.0
0.0075 1-0 15.1
0.15 1.0 15.0
0.0075 1-0 15.1
0.15 1.0 15.0
0.0075 1.0 15.0
0.0075 1.0 15.0
0.15 1.0 15.0
0.0075 1.0 15.1
0.0075 1.0 15.1
0.15 1.0 15.0
0.0075 1-0 15.1
0.15 1.0 15.0
0.0075 1.0 15.0
0.15 1.0 15.0
0.0075 1.0 15.1
0.15 1-0 15.0
0.0075 1.0 15.0
0.15 1.0 15.0
0.0075 1.0 15.0
0.15 1.0 15-0
0.0075 1-0 15.1
tp
o
o
-------
1
I
OCC3037
-------
Sheetl
compound
Naphthalene
Acenaphthytene
Acenaphlhene
Fluorene
'henanthrene
Anthracene
Fluoranthene
Pyrene
Benzo(a)anlhracene
Chrysene
Benzo(b)fluoranthene
Benzo(k)Huoranthene
Benzo(a)pyrene
lndeno(1 ,2,3-cd)pyrene
Dibenz(a,h)an(hracene
Benzo(g,h,i)perylene
Naphlhalene-d8
Acenaphthytene-d8
Acenaphlhene-d 1 0
Fluorene-d10
Phenanlhrene-dIO
Anlhracene-dlO
:luoranthene-d10
Pyrene-d10
Benzo(a)anthracene-d12
Chrysene-d12
Benzo(b)fluoranthene-d12
Benzo(k)fluoranlhene-d12
Benzo(a)pyrene-d12
ndenod .2 ,3-cd)pyrene-d 1 2
Dibenz(a,h)anthracene-d14
3enzo(g,h,0perytene-d12
Stock pg/mL
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
r 100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
Ar
nount spilt
ML
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0 "
19-01 |
ed F
InalVoluir
ML
1000
1000
1000
1000
1000
1000
1000
1000
looo
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
e
Std. Cone
pg/mL
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.10
0.10
pes-
Ar
mah-1013!
nount splk
ML
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.6
9-03
ed F
I I
Inal Volum
ML
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000 1
1000
1000
1000
1000 |
1000
1000
1000
1000
1000
1000
1000
1000 "I
1000
1000
1000
1000
1000
1000 '
1000 _,
1000
e
pg/mL
0.25
0.25
0.25
0.25
0.25
0.25
0.25
0.25
0.25
0.25
0.25
0.25
0.25
0.25
025
0.25
0.25
0.25
0.25
0.25
0.25
0.25
0.25
0.25
0.25
0.25
0.25
0.25
0.25
0.25
0.25
0.25
pts-i
mah-1013]
ML
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
9-02
pL
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
pg/hllS
0.50,
0.50^
0.5Q"
0.50*.
0.50.T
0.50*3
0.50C
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
0.50
Pagel
-------
Shaetl
ML
10.0
10.0
10.0
10.0
10.0
10.0
10.0
Too
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
ed F
1 1
ML
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
'000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
Std. Cone
pg/mL
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
.00
.00
.00
.00
!6o
!6o
56
.00
!6o
.00
loo
xio
.00
paSH
Ai
m«h-10149
Mjunt splk
1 *• 1
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
2OO
20.0
205
2OO
2OO
9-03
«r — f
lulVotum
nan
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1
a
Std. Cone
W/mL
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2.00
2M
2.00
2tiO
2.00
2.00
pas-
nah-1014!
ML
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
9-01
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00
3.00
CO
O
Page 2
-------
Cambridge Isotope Laboratories, Inc.
50 Frontage Road, Andover, MA 01810-5413 USA
PH: 800.311.1174 (USA) PH: 978.749.8000
FAX: 978.749.2768 URL: http://www.isotope.com
Technical Data Sheet
Compound:
Acenaphthene(Dio, 98%)
Acenaphthylene (09,98%)
Anthracene (Di rj,98%)
Benz[a]anthracene (D-|2.98%)
Benzo[blfluoranthene (D-|2- 98%)
Benzo[k]fluoranthene (Di2,98%)
Benzo[ghi]perylene (D^, 98%)
Benzojajpyrene (D-|2,98%)
Chrysene(D-|2,98%)
Dibenz[ah]anthracene (D-|4,97%)
Fluoranthene (D<|Q, 98%)
Fluorene(Dio,98%)
lndeno[123-cd]pyrene (D-J2,98%)
Naphthalene (Ds, 98%)
Phenanthrene (DIQ, 98%)
Pyrene (D-jQ, 98%)
Catalog Number:
PAH Cocktail for GARB Method 429
containing approximately 100 ±
of each of the following:
C12D10
C12D8
C14D10
C18D12
C22&12
C2QD12
C18D12
C16D10
C13D10
C22D12
C14D10
ES-2528
Lot Number:
IG-248
Chemical Purity:
98%+
Amount:
1 milliliter
Solvent:
Benzene (Dfi, 99.6%)
Date Prepared:
3/98
OCGOO'10
-------
ABSOLUTE STANDARDS, INC • 44 Rossotto Drive • Hamden, CT • 06514 • (800)-368-1131
CERTIFIED WEIGHT REPORT: Uncertainty < +,-0.5% Stated Values.
ISO 9001 Quality System Registered.
DLS ANSI-RAB Accredited.
1.
2.
3.
4.
5.
6.
7.
8.
9.
10.
11.
12.
13.
14.
15.
16.
17.
18.
19.
20.
Part Number:
Lot Number
Description:
Expiration Date:
Nominal Concentration (ug/mL):
Weight(s) shown below were combined and
Compound RM#
Acenaphthene 1
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Benzo(g,h,i)perylene
Chrysene
Dibenzo(a,h)anthracene
Fluoranthene
Fluorene
lndeno(1 ,2,3-cd)pyrene
Naphthalene
Phenanthrene
Pyrene
3
13
28
30
31
33
32
91
112
183
184
202
222
248
259
10017
Q22228
CLP Semi-Volatiles - PAH Mix
16 Components
092403 Solvent(s):
Methylene Chloride
2000 Benzene
diluted to : 500 mL.
Nominal Purity
Lot Number Cone (ug/mL) (%)
01619AX
HKY-27456-24
04806HX
31331-13
060691
CAP-27981-50
30893-34
31331-40
RAC-29697-23
29494-83
AJO-22599-72
ECH-29240-49
29494-93
0481 3DW
0341 OPV
123196
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
99
99
99
99
98
99
99
99
99
99
99
99
99
99
98
99
Lot *
M03A01
G06634
Max. Target
Weight(g)
1.01010
1.01010
1.01010
1.01010
1.02041
1.01010
1.01010
1.01010
1.01010
1.01010
1.01010
1.01010
1.01010
1.01010
1.02041
1.01010
(50%)
(50%)
Actual
Weight(g)
1.00403
1.00421
1.00527
1.00531
1.00632
1.00372
1.00253
1.00367
1.00458
1.00255
1.00419
1.00471
1.00328
1.00202
1.00703
1.00292
Formulated By:
// / x £ •
Vincent K.
Reviewed
>^
Criscio, Jr.
By:
"" ^^""
Pedro L. Rentas
•Actual (Solvent
Cone (ug/mL) CAS*
2008.1
2008.4
2010.5
2010.6
2012.6
2007.4
2005.1
2007.3
2009.2
2005.1
2008.4
2009.4
2006.6
2004.0
2014.1
2005.8
00083-32-9
00208-96-8
00120-12-7
00056-55-3
00050-32-8
00205-99-2
00207-08-9
00191-24-2
00218-01-9
00053-70-3
00206-44-0
00086-73-7
00193-39-5
00081-20-3
00085-01-8
00129-00-0
— r ' 092398
DATE
-7
"*-*••"• 092398
DATE
USDS Information
Safety Info. On Attached pg.)
OSHA PEL (TWA) LD50
N/A
N/A
0.2mg/m3 <8H)
N/A
0.2mg/m3 (8H)
N/A
N/A
N/A
0.2mg/m3
0.2mg/m3
N/A
N/A
N/A
10 ppm
-------
ABSOLUTE STANDARDSJnc. • 44 Rossotto Drive • Hamden, CT • 06514 • (800)-368-1131
ISO 9001 Quality System Registered
DLS ANSI-RAB Accredited
LO
co
CO
Tf
in
CNJ
Date: Thu, Oct 1, 1998 6:57 AM
Data: P10017 L092398-024
Sample: Absolute Standards, Inc. QA/QC Analysis by FID
P10017 L092398
[2000ng/mL in Methylene chloride/Benzene]
0.1 nL Standard injection, Range = 3
CLP Semi-Volatiles - PAH Mix
16 Components
Method: GC4 M2
Sampling Int: 0.1 Seconds
Data:
2
Method GC4-M2:Column SPB-5:(30m X 0.53mm ID X 1.5 urn film
thickness). Flow rates: Total flow = 260mL/min, Helium (carrier) = 5 mL/min.,
Helium (make-up) = 15 mL/min., Hydrogen (make-up) = 40 mL/min., air (make
up) = 200 mL/min.. Temp. 1 = 50°C (1 min.), Temp. 2 = 300°C (14 min.), Rate
= 10°C/min., Injector Temp. = 250°C, FID Temp. = 300°C. Analysis performed
by Lance R. Boynton. *
co
CO
10
1 1
12
13
1
0.0
Retention Time (min.)
Naphthalene
Acenaphthylene
Acenaphthene
Fluorene
Phenanthrene
Anthracene
Fluoranthene
Benzo(a)anthracene
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Benzo(a)pyrene
ndeno( 1,2,3-cd)pyrene
)ibenzo(a,h)anthracene
tenzo(g,h,i)perylcne
9.89
13.52
13.96
15.13
17.36
17.47
20.17
20.68
23.54
23.64
26.01
26.01
26.64
29.75
29.75
30.55
40.0
o
Page 2
-------
AccuStandard Inc.
125 Market Street
n,CT06513
OF ANALYSIS
Ph: 203-786-5290
Fax: 203-786-5287
E-mail: usadaccustandard.com
CATALOG NO. M-625-07-10X
DESCRIPTION: Calibration Standard
LOT: ' A7120073
SOLVENT: CH2CI2
EXPIRATION: On-going Stability
Program
,i _ 4
II Component
Jf2,2'-Difluorobiphenyl
-__ „ _ .. „
CAS # Punty %
(GC/MS)
388-82-9 100
Gravimetric
Concentration'
(ngrtnL)
2002
Analyte
Concentration8
(ug/mL)
2002
1. Al weights are trassabte through Nafional InsJUute of
Standards & Technotofly, Test No. 822/254480
2. Analyte Coneentratton = Purity x Gravtmetrte Concentrafcn
000394;
C««Mbr
±£
This product was manufactured to meet the quality system requirements of ISO 9001
-------
HP 5989 High Mass Autotune
Instrument: HP 5989B
Mon May 17 15:05:46 1999
C:\HPCHEM\1\5989\ATUNE.U
Mass 68.90
Ab 251872
Pw50 0.55
1
|
,
J
1
Mass 218.90
% 21.22
Pw50 0.52
J
I
Mass
%
Pw50
1
i i i ' i ' i ' ' ' i ' ' i '
66 71 216 221 500
502.00
1.10
0.53
1
k
Mode: El Inlet: GC
Repeller 7.00 EMVolts 1606
lonFGain 0 AtnuGain 122
lonFocus 55 AmuOffs 128
EntLens 100 MassGain 27
Xray 5 MassOffs 9
Emission 300 Integr 50
EleEnergy 70 Samples 16
Polarity POS Averages 1
StepSize 0.13
Temperatures :
MS Source 260
MS Quad 102
i i i |
505
Scan: 50.00 - 650.00 Samples: 16 Thresh: 20 Step: 0.13
122 peaks Base: 68.90 Abundance: 181376
100 .,
80 .
60 .
40 -
20 -
100
Mass
68.90
219.00
502.00
200
300
400
500
600
Abund Rel Abund Iso Mass Iso Abund Iso Ratio
181376 100.00 69.95 2359 1.30
47168 26.01 220.00 2207 4.68
2421 1.33 503.00 242 10.00
OCOD944
-------
Instrument: HP 5989B
Tue May 18 08:34:57 1999
HP 5989 High Mass Autotune
C:\HPCHEM\1\5989\ATUNE.U
Mass 68.80
Ab 207617
Pw50
J
0.58
Mass 218.90
% 29.87
Pw50 0.50
1
J
L
Mass 502.05
% 1.91
Pw50 0.45
1
L
Mode: El Inlet: GC
Repeller 7.00 EMVolts 1677
lonFGain 0 AmuGain 123
lonFocus 60 AmuOffs 129
EntLens 105 MassGain 28
Xray 0 MassOffs 9
Emission 300 Integr 50
EleEnergy 70 Samples 16
Polarity POS Averages 1
StepSize 0.13
Temperatures :
MS Source 200
MS Quad 100
66 71 216 221 500 505
Scan: 50.00 - 650.00 Samples: 16 Thresh: 20 Step: 0.13
138 peaks Base: 68.95 Abundance: 148096
100,
80 .
.
60 .
40 .
20 -
0
/^J '/><
' / ^
[ • • f -....p.—.,^..— .-J-.—.y. . . f - | , , 1 1 , ! 1 1 1 , , 1 I j I I 1 1 11
100 200 300 400 500 600
Mass Abund Rel Abund Iso Mass Iso Abund Iso Ratio
68.95 148096 100.00 69.95 1888 1.27
219.00 53752 36.30 220.00 2507 4.66
502.00 3057 2.06 503.00 313 10.24
-------
HP 5989 High Mass Autotune
Instrument: HP 5989B
Wed May 19 10:42:54 1999
C:\HPCHEM\1\5989\ATUNE.U
Mass 68.95
Ab 221150
Pw50
J
0.49
Mass 219.00
% 24.88
Pw50
0.52
U
Mass 502.00
% 1.18
Pw50 0.55
j
I
v — ^ __
Mode: El Inlet: GC
Repeller 7.00 EMVolts 1701
lonFGain 0 AmuGain 119
lonFocus 50 AmuOffs 130
EntLens 105 MassGain 33
Xray 10 MassOffs 8
Emission 300 Integr 50
EleEnergy 70 Samples 16
Polarity POS Averages 1
StepSize 0.13
Temperatures :
MS Source 216
MS Quad 100
1 ! \ 1 1 j""' T [ I T ' I ' ' ' ' ' 1
66 71 216 221 500 505
Scan: 50.00 - 650.00 Samples: 16 Thresh: 20 Step: 0.13
119 peaks Base: 68.85 Abundance: 149824
100 „
80 -
60 .
40 -
20-
-i 1 1 r
100
200
300
400
I1 '
500
600
Mass Abund Rel Abund Iso Mass Iso Abund Iso Ratio
68.85 149824 100.00 69.85 1978 1.32
218.95 50120 33.45 219.95 2317 4.62
501.95 2509 1.67 502.95 260 10.36
OCC39I5
-------
Instrument: HP 5989B
Thu May 20 08:23:58 1999
HP 5989 High Mass Autotune
C:\HPCHEM\1\5989\ATUNE.U
Mass 68.90
Ab 223393
Pw50
J
0.59
— ~v
Mass 218.95
% 27.65
Pw50
J
0.54
n
Mass 501.95
% 2.06
Pw50 0.54
1
I
k
Mode: El Inlet: GC
Repeller 7.00 EMVolts 1654
lonFGain 0 AmuGain 121
lonFocus 55 AmuOffs 128
EntLens 110 MassGain 29
Xray 5 MassOffs 9
Emission 300 Integr 50
EleEnergy 70 Samples 16
Polarity POS Averages 1
StepSize 0.13
Temperatures :
MS Source 200
MS Quad 98
66 71 216 221 500 505
Scan: 50.00 - 650.00 Samples: 16 Thresh: 20 Step: 0.13
127 peaks Base: 69.00 Abundance: 172160
100 .,
80 .
60 .
40 .
20 .
100
Mass
69.00
218.95
501.95
200
Abund
172160
55936
4058
300
Rel Abund
100.00
32.49
2.36
400
Iso Mass
70.00
219.95
502.95
500
600
Iso Abund Iso Ratio
2109 1.23
2631 4.70
420 10.35
OGC30I6
-------
Instrument: HP 5989B
Thu May 20 14:51:20 1999
HP 5989 High Mass Autotune
C:\HPCHEM\1\5989\ATUNE.U
Mass 68.80
Ab 219353
Pw50
1
0.52
Mass 218.90
% 26.02
Pw50 0.53
1
1
Mass 502.00
% 1.22
Pw50
I
66 71 216 221 500
0.51
L
505
Mode: El Inlet: GC
Repeller 7.00 EMVolts 1677
lonFGain 0 AmuGain 126
lonFocus 55 AmuOffs 128
EntLens 105 MassGain 25
Xray 5 MassOffs 9
Emission 300 Integr 50
EleEnergy 70 Samples 16
Polarity POS Averages 1
StepSize 0.13
Temperatures :
MS Source 260
MS Quad 102
Scan: 50.00 - 650.00 Samples: 16 Thresh: 20 Step: 0.13
126 peaks Base-. 68.90 Abundance: 157760
100 _,
80 -
60 .
40 -
20 -
0
i r—r
100
200
300
400
500
~"—I—r
600
Mass Abund Rel Abund Iso Mass Iso Abund Iso Ratio
68.90 157760 100.00 69.90 2064 1.31
219.00 51192 32.45 220.00 2324 4.54
501.95 2236 1.42 502.95 227 10.15
OCC3047
-------
HP 5989 High Mass Autotune
Instrument: HP 5989B
Fri May 21 10:43:03 1999
C:\HPCHEM\1\5989\ATUNE.U
Mass 68.90
Ab 228158
Pw50 0.50
1
J
j
L
Mass 218.95
% 25.72
Pw50
i
J
0.53
IA
Mass 501.95
% 1.89
Pw50 0.45
1
1
i
\
66 71 216 221 500 505
Mode: El Inlet: GC
Repeller 7.00 EMVolts 1630
lonFGain 0 AmuGain 125
lonFocus 60 AmuOffs 129
EntLens 105 MassGain 29
Xray 5 MassOffs 9
Emission 300 Integr 50
EleEnergy 70 Samples 16
Polarity POS Averages 1
StepSize 0.13
Temperatures :
MS Source 200
MS Quad 100
Scan: 50.00 - 650.00 Samples: 16 Thresh: 20 Step: 0.13
145 peaks Base: 69.00 Abundance: 153152
100 .,
80 .
60 -
40 -
20 -
100
200
300
400
500
600
Mass Abund Rel Abund Iso Mass Iso Abund Iso Ratio
69.00 153152 100.00 70.00 1859 1.21
218.95 51000 33.30 219.95 2460 4.82
501.95 3809 2.49 502.95 383 10.06
-------
Instrument: HP 5989B
Tue May 25 10:00:28 1999
HP 5989 High Mass Autotune
C:\HPCHEM\1\5989\ATUNE.U
Mass 68.85
Ab 232091
Pw50
J
0.52
Mass 219.00
% 26.19
Pw50 0.50
|
,
Mass 502.00
% 1.32
Pw50 0.42
1
k.
Mode: El Inlet: GC
Repeller 7.00 EMVolts 1748
lonFGain 0 AmuGain 121
lonFocus 45 AmuOffs 130
EntLens 95 MassGain 35
Xray 20 MassOffs 8
Emission 300 Integr 50
EleEnergy 70 Samples 16
Polarity POS Averages 1
StepSize 0.13
Temperatures :
MS Source 260
MS Quad 100
i ' ' ' • i ' i ' ' ' ' i ' ' i ' ' • ' i
66 71 216 221 500 505
Scan
148 ]
100 _
80 .
60.
40.
20
0
i
?e<
50.00 - 650.00 Samples: 16 Thresh: 20 Step: 0.13
aks Base: 68.95 Abundance: 158272
5 '
l.i 1 i
, i i , i | i i i | i i i i | i i i i | i • i i | i i
100 200 300 400 500 600
Mass Abund Rel Abund Iso Mass Iso Abund Iso Ratio
68.95 158272 100.00 69.95 1951 1.23
219.00 56400 35.63 219.90 2545 4.51
502.05 2502 1.58 502.90 256 10.23
OCCDQ49
-------
Method
Title
Last Update
Response via
Response Factor Report HP 5989B
C:\HPCHEM\1\METHODS\PES.M
Wed May 19 09:55:02 1999
Initial Calibration
Calibration Files
0,5 =ENG1308.D 2.5
7 =ENG1311.D 10
Compound
1)
2)
3)
4)
5)
6)
7)
8)
9)
10)
11)
12)
13)
14)
15)
16)
17)
18)
19)
20)
21)
22)
23)
24)
25)
26)
27)
28)
29)
30)
31)
32)
33)
34)
35)
S
s
s
s
s
s
s
s
s
s
s
s
s
s
s
s
s
s
2 , 2 -Dif luorobipheny]
Naphthalene -d8
Naphthalene(CCC)
2 -Methlynaphthalene
Acenaphthylene-d8
Acenaphthylene
Acenaphthene-dlO
Acenaphthene (CCC)
Fluorene-dlO
Fluorene
Phenant hrene - dl 0
Phenanthrene
Anthracene-dlO
Anthracene
Fluoranthene-dlO
Fluoranthene (CCC)
Pyrene-dlO
Pyrene
p-Terphenyl-d!4
Benzo (a) anthracene-
Benzo (a) anthracene
Chrysene-dl2
Chrysene(CCC)
Benzo (b) fluoranthen
Benzo (b) fluoranthen
Benzo (k) fluoranthen
Benzo (k) fluoranthen
Benzo (a) pyrene-d!2
Benzo (a) pyrene (CCC)
Indeno ( 1 , 2 , 3 - cd) pyr
Indeno ( 1 , 2 , 3 - cd) pyr
Dibenz (a, h) anthrace
Dibenz (a, h) anthrace
Benzo (g, h, i) perylen
Benzo (g,h, i) perylen
=ENG1309
=ENG1313
0.5 2.5
1.552
1.811
0.770
1.472
1.666
1.029
1.163
1.150
1.344
1.941
2.369
1.617
2.222
2.167
2.814
2.391
3.022
1.739
1.009
1.684
1.563
2.167
0.871
1.342
1.210
1.422
0.554
0.879
1.548
1.757
0.814
1.660
1.860
1.170
1.256
1.223
1.467
2.062
2.486
1.783
2.415
2.134
2.825
2.389
3.094
1.771
1.389
2.210
1.880
2.584
1.190
1.838
1.711
1.986
0.974
1.525
1.050
1.324
0.607
1.038
0.755
1.119
.D 5
.D 15
5 7
1.604
1.826
0.859
1.768
1.917
1.140
1.303
1.267
1.519
1.981
2.369
1.699
2.270
1.934
2.580
2.130
2.809
1.602
1.485
2.204
1.778
2.501
1.290
1.898
1.776
2.076
1.194
1.880
1.473
1.806
0.846
1.482
1.200
1.554
- TQTn
1.620
1.858
0.876
1.825
2.019
1.169
1.275
1.287
1.544
1.945
2.337
1.642
2.215
1.767
2.355
1.943
2.550
1.479
1.404
1.977
1.583
2.248
1.258
1.782
1.619
1.905
1.172
1.834
1.569
1.860
0.888
1.503
1.230
1.585
=ENG1310.D
=ENG1314.D
10 15
1.466
1.724
0.791
1.543
1.732
0.995
1.148
1.073
1.324
1.510
1.853
1.356
1.782
1.401
1.868
1.516
1.994
1.180
1.152
1.504
1.214
1.656
1.085
1.445
1.482
1.729
1.106
1.537
1.370
1.562
0.836
1.278
1.094
1.409
1.356
1.661
0.739
1.374
1.556
0.890
1.030
0.937
1.167
1.311
1.621
1.245
1.664
1.241
1.632
1.317
1.752
1.068
1.058
1.358
1.066
1.454
0.994
1.283
1.309
1.485
1.056
1.362
1.303
1.440
0.795
1.193
1.079
1.301
1
1
0
1
1
1
1
1
1
1
2
1
2
1
2
1
2
1
1
1
1
2
1
1
1
1
1
1
1
1
0
1
1
1
Avg
.524
.773
.808
.607
.792
.066
.196
.156
.394
.792
.173
.557
.095
.774
.345
.948
.537
.473
.250
.823
.514
.102
.115
.598
.518
.767
.009
.503
.353
.598
.795
.299
.072
.394
%RSD
6.47
4.11
6.49
10.88
9.56
10.64
8.53
11.52
10.28
17.01
16.06
13.46
14.29
21.58
21.25
23.06
21.81
19.83
16.14
19.87
20.92
21.66
14.56
17.00
14.85
15.24
23.49
24.21
14.57
14.45
13 .81
15.14
17.60
13.74
(#) = Out of Range
PES.M
Wed May 19 10:09:12 1999
OC03207
HP 5989B
Page 1
-------
Quantitation Report
Data File : C:\HPCHEM\1\DATA\9919\ENG1308.D
Acq On : 17 May 99 9:32 pm
Sample : PES-MAH-051299-02 0.5 ng//iL
Misc :
Quant Time: May 19 9:11 1999
Method : C:\HPCHEM\1\METHODS\PES.M
Title :
Last Update : Wed May 19 09:55:02 1999
Response via : Multiple Level Calibration
Vial: 2
Operator: JEMcCartney
Inst : HP 5989B
Multiplr: 1.00
Internal Standards
R.T. Qlon Response Cone Units Dev(Min)
1)
2 , 2 -Dif luorobiphenyl
24
.59
190
1379349
5
.00
System Monitoring Compounds
2)
4)
5)
7)
9)
11)
13)
15)
17)
19)
20)
22)
24)
26)
28)
30)
32)
34)
Naph t hal ene - d8
2-Methlynaphthalene-dlO
Acenaphthylene-d8
Acenaphthene-dlO
Fluorene-dlO
Phenanthrene - dl 0
Anthracene -dlO
Fluoranthene-dlO
Pyrene -dlO
p-Terphenyl-d!4
Benzo (a) anthracene -d!2
Chrysene-dl2
Benzo (b) f Iuoranthene-dl2
Benzo (k) f luoranthene -d!2
Benzo (a) pyrene-d!2
Indenod, 2, 3-cd)pyrene-dl2
Dibenz (a,h) anthracene-d!4
Benzo (g, h, i)perylene-d!2
22
23
26
26
28
30
30
33
34
34
38
39
45
46
48
0
0
0
.23
.96
.29
.71
.00
.43
.57
.57
.25
.57
.87
.03
.85
.06
.52
.00
.00
.00
136
152
160
164
176
188
188
212
212
244
240
240
264
264
264
288
292
288
214094
106255
203002
141993
158613
267782
222977
298937
329801
239823
139163
215551
120183
166918
76396
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.51
.48
.46
.47
.50
.54
.52
.61
.61
.59
.40
.51
.35
.43
.28
.00
.00
.00
Target Compounds
3)
6)
8)
10)
12)
14)
16)
18)
21)
23)
25)
27)
29)
31)
33)
35)
Naphthalene (CCC)
Acenaphthylene
Acenaphthene (CCC)
Fluorene
Phenanthrene
Anthracene
Fluoranthene (CCC)
Pyrene
Benzo (a) anthracene
Chrysene(CCC)
Benzo (b) f luoranthene
Benzo (k) f luoranthene
Benzo (a) pyrene (CCC)
Indenod, 2, 3- cd) pyrene
Dibenz (a, h) anthracene
Benzo (g,h, i)perylene
22
26
26
28
30
30
33
34
38
39
46
46
48
0
0
0
.28
.32
.79
.08
.49
.62
.62
.31
.98
.16
.05
.22
.74
.00
.00
.00
128
152
154
166
178
178
202
202
228
228
252
252
252
276
278
276
249739
229839
160460
185411
326793
306550
388098
416816
232296
298879
185170
196143
121311
0
0
0
0
0
0
0
0
0
0
0
0
0
.51
.47
.49
.48
.55
.53
.60
.60
.46
.51
.42
.41
.29
ng/uL -0
.03
%Recovery
ng/uL
ng/uL
ng/uL
ng/uL m
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL m
ng/uL m
ng/uL m
Qvalue
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
93
96
83
85
100
99
99
100
99
97
95
94
95
Not Detected
Not Detected
Not Detected
0000203
(#) = qualifier out of range (m) = manual integration
ENG1308.D PES.M Wed May 19 10:10:54 1999 HP 5989B
Page 1
-------
Quantitation Report
C:\HPCHEM\1\DATA\9919\ENG1308.D
17 May 99 9:32 pm
PES-MAH-051299-02 0.5
Data File
Acq On
Sample
Misc :
Quant Time: May 19 9:11 1999
Method
Title
Last Update
Response via
C:\HPCHEM\1\METHODS\PES.M
Wed May 19 09:55:02 1999
Multiple Level Calibration
Vial: 2
Operator: JEMcCartney
Inst : HP 5989B
Multiplr: 1.00
Abundance
1100000 J
1000000 :
900000 :
:
sooooo:
700000 -
600000 J
500000 :
400000 -
300000 -
200000 -
100000-
n
U -
TIC: ENG1308.D
1
A
4S
1 1 i 1 i *T
M
6s 13s
5s
7^s
it8
IJS
*"as 7X&R
\ 2°S 2^S 2,4
J A A
— i — i — i — i — i — i — i — i — i — i — i — i — i — i — i — i — i — i — i — i — i —
Time--> 20:00 30:00 40:00 50.00 60.00
OC05S03
ENG1308.D PES.M
Wed May 19 10:11:03 1999
HP 5989B
Page 2
-------
(Abundance
100000 -
50000-
TIC: ENG1308.D
Time-->
0
22.10
22.20
22.30
lAbundancelon 136.00
Ion 68.00
100000J
50000 .
0 .
(135.70 to 136.70): ENG
(67.70 to 68.70): ENG13
22.23
Time-->
22.10
22 .20
22.30
Abundance
100000 .
50000 .
Time--> 22 .00
TIC: ENG1308.D
0
22.20
22 .40
Abundancelon 128.00 (127.70 to 128.70)
Ion 127.00 (126.70 to 127.70)
22.28
100000 .
50000 -
0 .
ENG
ENG
#2
Naphthalene-d8
Concen: 0.51 ng/uL
RT: 22.23 min Scan# 1566
Delta R.T. -0.05 min
Lab File: ENG1308.D
Acq: 17 May 99 9:32 pm
Tgt Ion:136 Resp:
Ion Ratio Lower
100
136
68
0
0
17.9
0.0
0.0
16.1
0.0
0.0
214094
Upper
24.1
0.0
0.0
Time--> 22.00
22:20
22.40
ENG1308.D—PES.M
Wed May 19 10:11:07 1999
#3
Naphthalene(CCC)
Concen: 0.51 ng/uL
RT: 22.28 min Scan# 1574
Delta R.T. -0.05 min
Lab File: ENG1308.D
Acq: 17 May 99 9:32 pm
Tgt Ion:128 Resp: 249739
Ion Ratio Lower Upper
128 100
127 12.7 0.0 30.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0003210
HP 5989B
Page 3
-------
jABundance
40000 -
20000 -
TIC: ENG1308.D
T I 1 1 1— 1 1 1 1 1 r
Time--> 23.90 24.00
0
Abundancelon 152.00 (151.70 to 152.70)
23.96
40000 -
20000 '.
"ENG~
0 .
Time-->
-i 1 I r
23.90
24.00
Abundance
100000 -
50000 .
Time--> 26 .10
TIC: ENG1308.D
26120
26.30
26.40
2-Methlynaphthalene-dlO
Concen: 0.48 ng/uL
RT: 23.96 min Scan# 1928
Delta R.T. -0.04 min
Lab File: ENG1308.D
Acq: 17 May 99 9:32 pm
Tgt Ion:152 Resp: 106255
Ion Ratio Lower Upper
152 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
(AbundanceIon 160.00 (159.70 to 160.70): ENG
100000 .
50000 -
0 .
26.29
rime--> 26 .10
26.20
26.30
26.40
-.-. ENG1308.DPES.M
#5
Acenaphthy1ene-d8
Concen: 0.46 ng/uL
RT: 26.29 min Scan# 2450
Delta R.T. -0.01 min
Lab File: ENG1308.D
Acq: 17 May 99 9:32 pm
Tgt Ion:160 Resp: 203002
Ion
160
0
0
0
Ratio
100
0.0
0.0
0.0
Lower Upper
0.0
0.0
0.0
0.0
0.0
0.0
OC0321
Wed May 19 10:11:10
HP 5989B
iJ.
Page 4
-------
Abundance
100000 .
50000 .
Time-->
TIC: ENG1308.D
26.20
26.30
26.40
Abundance Ion 152.00 (151.70 to 152.70)
Ion 153.00 (152.70 to 153.70)
26.32
100000-
50000-
0 -
ENG
ENG
Time-->
26.20
26.30
26.40
Abundance
150000j
100000 -
50000 .
Time--> 26.60 26.65 26.70 26.75 26.80
TIC: ENG1308.D
0
Acenaphthylene
Concen: 0.47 ng/uL
RT: 26.32 min Scan# 2455
Delta R.T. -0.02 min
Lab File: ENG1308.D
Acq: 17 May 99 9:32 pm
Tgt Ion:152 Resp: 229839
Ion Ratio Lower Upper
152 100
153 13.3 12.1 18.1
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundancelon 164.00 (163.70 to 164.70): ENG
60000 J
40000:
20000:
26.71
Time--> 26160 26.65 26.70 26175 26.80
ENGX3TT8TD PES.M
#7
Acenaphthene-dl0
Concen: 0.47 ng/uL m
RT: 26.71 min Scan# 2513
Delta R.T. -0.04 min
Lab File: ENG1308.D
Acq: 17 May 99 9:32 pm
Tgt Ion:164 Resp: 141993
Ion
164
0
0
0
Ratio
100
0.0
0.0
0.0
Lower Upper
0.0
0.0
0.0
0.0
0.0
0.0
OCi
Wed May 19 10:11:14 1999
HP 5989B
Page 5
-------
Time-->
fundance
150000 ..
100000 -
50000 -
TIC: ENG1308.D
26.70
26.80
26.90
Abundancelon 154.00 (153.70 to 154.70): ENG
Ion 153.00 (152.70 to 153.70): ENG
80000 :
60000 :
40000:
20000:
o:
26.79
Time-->
26.70
26.80
26.90
Abundance
150000 J
100000 '-
50000 .
Time-->
TIC: ENG1308.D
0
2790
28 o
28 i
Acenaphthene(CCC)
Concen: 0.49 ng/uL
RT: 26.79 tnin Scantt 2525
Delta R.T. -0.04 min
Lab File: ENG1308.D
Acq: 17 May 99 9:32 pm
Tgt Ion:154 Resp: 160460
Ion Ratio Lower Upper
154 100
153 102.3 69.5 104.2
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundancelon 176.00 (175.70 to 176.70;
ENG
80000 :
60000 -
40000 -
20000 .
0 .
28.00
Time-->
2790
28 o
28 i
ENG1308.DPES.M
Wed May 19 10:11:17 1999
#9
Fluorene-dlO
Concen: 0.50 ng/uL
RT: 28.00 min Scantf 2709
Delta R.T. 0.00 min
Lab File: ENG1308.D
Acq: 17 May 99 9:32 pm
Tgt Ion:176 Resp: 158613
Ion
176
0
0
0
Ratio
100
0.0
0.0
0.0
Lower Upper
0.0
0.0
0.0
0.0
0.0
0.0
HP 5989B
Page 6
-------
SBundance
150000J
100000 '.
50000.
Time-->
TIC: ENG1308.D
27.90 28.00 28.10 28.20
Abundance Ion 166.00 (165.70 to 166.70)
100000-
50000 .
Ion 165.00 (164.70 to 165.70): ENG
28.08
Time-->
T 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 T
27.90 28.00 28.10 28.20
#10
Pluorene
Concen: 0.48 ng/uL
RT: 28.08 min Scan# 2720
Delta R.T. -0.05 min
Lab File: ENG1308.D
Acq: 17 May 99 9:32 pm
Tgt Ion:166 Resp: 185411
Ion Ratio
166 100
165 88.8
0 0.0
0 0.0
Lower Upper
61.0 91.5
0.0 0.0
0.0 0.0
Abundance
150000 .
100000:
50000 .
0
Time--> 30130
TIC: EWG1308.D
30.40
30.50
lAbundance I on 188.00
150(
100000.
50000 .
Ion
(187.70tO 188.70): ENG
94.00 (93.70 to 94.70): ENG13
30.43
Time--> 30.30
30.40
30.50
ENG1J08.D—PES.M
Wed May 19 10:11:20 1999
#11
Phenanthrene-dl0
Concen: 0.54 ng/uL
RT: 30.43 min Scan# 3078
Delta R.T. -0.04 min
Lab File: ENG1308.D
Acq: 17 May 99 9:32 pm
Tgt Ion:188 Resp: 267782
Ion Ratio
188 100
94 24.8
0 0.0
0 0.0
Lower Upper
24.1
0.0
0.0
36.1
0.0
0.0
Of
l/V
HP 5989B
Page 7
-------
Abundance
150000J
100000:
50000 '-
Time-->
TIC: ENG1308.D
30.40
30.50
30.60
Abundance Ion 178.00 (177.70 to 178.70): ENG
Ion 176.00 (175.70 to 176.70): ENG
30.49
150000J
100000:
50000:
o:
lime- ->
30.40
30.50
30.60
#12
Phenanthrene
Concen: 0.55 ng/uL
RT: 30.49 min Scantf 3087
Delta R.T. -0.06 min
Lab File: ENG1308.D
Acq: 17 May 99 9:32 pm
Tgt Ion:178 Resp: 326793
Ion Ratio Lower Upper
178 100
176 20.0 16.1 24.1
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance
150000 .
100000 J
50000 -
rime-->
TIC: ENG1308.D
30.40 30.50 30.60 30.70
lAbundancelon 188.00 (187.70 to 188.70):
150000HIon 94>00 (93.70 to 94.70): ENG13
100000 .
50000 .
30.57
Time--> 30.40 30.50 30.60 30.70
ENGTJUF7D PES.M
Wed May 19 10:11:24
#13
Anthracene-dlO
Concen: 0.52 ng/uL
RT: 30.57 min Scan# 3099
Delta R.T. -0.06 min
Lab File: ENG1308.D
Acq: 17 May 99 9:32 pm
Tgt Ion:188 Resp:
Ion Ratio Lower
188 100
94 28.8 24.1
0 0.0 0.0
0 0.0 0.0
222977
Upper
36.1
0.0
0.0
HP 5989B
Page 8
-------
Abundance
150000:
100000:
50000 J
Time-->
TIC: ENG1308.D
30.50
30.60 30.70
T
lAbundance Ion 178.00 (177.70 to 178.70)
Ion 176.00 (175.70 to 176.70)
150000 '-
100000:
50000 -
ENG
ENG
30.62
Time--> '30150 ' '30!60 ' '30170
Anthracene
Concen: 0.53 ng/uL
RT: 30.62 min Scan# 3106
Delta R.T. -0.07 min
Lab File: ENG1308.D
Acq: 17 May 99 9:32 pm
Tgt Ion:178 Resp: 306550
Ion Ratio Lower Upper
178 100
176 19.6 16.1 24.1
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance
150000 :
100000:
soooo:
ritne-->
TIC: ENG1308.D
33.40 33.50 33.60 33.70
Abundancelon 212.00 (211.70 to 212.70)
Ion 106.00 (105.70 to 106.70)
33.57
100000 .
50000 .
0 .
ENG
ENG
Time-->
33.40 33.50 33.60 33.70
ENG1308.DPES. M
#15
Fluoranthene-dlO
Concen: 0.61 ng/uL
RT: 33.57 min Scan# 3625
Delta R.T. -0.04 min
Lab File: ENG1308.D
Acq: 17 May 99 9:32 pm
Tgt Ion:212 Resp: 298937
Ion Ratio
212 100
106 30.4
0 0.0
0 0.0
Lower Upper
24.1
0.0
0.0
36.1
0.0
0.0
OCC 321S
Wea May 19 10:11:27 1999
HP 5989B
Page 9
-------
l&tiundance
150000 :
100000:
50000:
TIC: ENG1308.D
Time--> 33.40
0
33.60
33.80
Abundancelon 202.00 (201.70 to 202.70): ENG
Ion 101.00 (100.70 to 101.70): ENG
150000 .
100000 '.
50000 .
o:
33.62
rime--> 33.40
33:60
33.80
Fluoranthene(CCC)
Concen: 0.60 ng/uL
RT: 33.62 min Scantf 3633
Delta R.T. -0.01 min
Lab File: ENG1308.D
Acq: 17 May 99 9:32 pm
Tgt Ion:202 Resp: 388098
Ion Ratio Lower Upper
202 100
101 27.7 21.7 32.5
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance
200000:
150000:
100000 -
50000:
Time-->
TIC: ENG1308.D
0
34:00
34:20
34.40
Abundancelon 212.00 (211.70 to 212.70)
Ion 106.00 (105.70 to 106.70)
34.25
100000 .
50000.
0 -
ENG
rime-->
34.00
34.20
34.40
ENG1308.DPES.M
#17
Pyrene-dlO
Concen: 0.61 ng/uL
RT: 34.25 min Scan# 3727
Delta R.T. -0.08 min
Lab File: ENG1308.D
Acq: 17 May 99 9:32 pm
Tgt Ion:212 Resp: 329801
Ion
212
106
0
0
Ratio
100
34.2
0.0
0.0
Lower Upper
27.3
0.0
0.0
40.9
0.0
0.0
OCO )217
Wed May 19 10:11:30 1999
HP 5989B
Page 10
-------
IT
H686S dH
O'O O'O
O'O O'O
S'2C L'lZ
O'O
O'O
S'LZ
001
66
N
UTUI 90'0- 'i'H
HOS UTUI AS'
in/5u 6S'0 ^
O'O
O'O
S'8£
jaddn
91891^
UTUI
O'O
O'O
L'SZ
O'O
O'O
I'2£
001
0
0
uoj
6T#
fififil
fit
P3M
• .0
oooos
SN3 MOZ/22I 03 OA'121) 00'22I
DN3
00009
00008
0
0
101
202
uoi
202 =
66
z.0'0- 'i'H
UTUI ic'frE :iH
qn/Su 09 '0 :ueouo3
0
oooos
: oooooi
- oooosi
000002
sougpunqy
8T#
. ofr'fre 02'frE oo;
j—i—i—i—i—i—i—i—i—i i i i i i i
DN3 :(OZ.'IOI 03 OZ/OOI) OO'IOI uoi
ON3 '-(OL'ZOZ 03 OZ/I02) 00'202
OOOOS
OOOOOI
OOOOSI
r o
oooos
OOOOOI
OOOOSI
000002
aouepungg
-------
Abundance
80000:
60000 :
40000:
20000:
Time--> 38.70
TIC: ENG1308.D
0
38.80
38.90
39.00
Abundance Ion 240.00 (239.70 to 240.70): ENG
Ion 120.00 (119.70 to 120.70): ENG
40000 -
20000.
Time--> 38.70
38180
38190
39100
#20
Benzo(a)anthracene-d!2
Concen-. 0.40 ng/uL
RT: 38.87 min Scan# 4422
Delta R.T. -0.11 min
Lab File: ENG1308.D
Acq: 17 May 99 9:32 pm
Tgt Ion:240 Resp: 139163
Ion Ratio
240 100
120 30.0
0 0.0
0 0.0
Lower Upper
24.1 36.1
0.0 0.0
0.0 0.0
Abundance
80000 :
60000:
40000:
20000:
0
Time-->
TIC: ENG1308.D
38180
39100
39120
Abundance Ion 228.00 (227.70 to 228.70): ENG
Ion 114.00 (113.70 to 114.70): ENG
60000 J
40000 J
20000 .
0 .
Time-->
38180
39100
39120
ENG1308.D—PES.M
Wed May iy 10:11:37 1999
#21
Benzo' (a) anthracene
Concen: 0.46 ng/uL
RT: 38.98 min Scan# 4439
Delta R.T. -0.07 min
Lab File: ENG1308.D
Acq: 17 May 99 9:32 pm
Tgt Ion:228 Resp: 232296
Ion Ratio
228 100
114 25.7
0 0.0
0 0.0
Lower Upper
20.1 30.1
0.0 0.0
0.0 0.0
OCC5213
HP 5989B
Page 12
-------
Abundance
80000 :
Time-->
TIC: ENG1308.D
38.80
39.00
39.20
Abundance Ion 240.00 (239.70to 240.70)
Ion 120.00 (119.70 to 120.70)
39.03
40000 J
20000 .
ENG
ENG
0 .
Time-->
38.80
39.00
39120
Abundance
80000 :
60000:
40000:
20000:
Time-->38.80
TIC: ENG1308.D
39.00
39:20
39.40
Abundance Ion 228.00 (227.70 to 228.70):
Ion 114.00 (113.70 to 114.70):
sooooJ 39'1S
40000 -
20000 .
0 .
Time-->38.80 39.00 39.20 39.40
ENGT3UBTDPES . M~~~~~~
#22
Chrysene-d!2
Concen: 0.51 ng/uL
RT: 39.03 min Scan# 4447
Delta R.T. -0.06 min
Lab File: ENG1308.D
Acq: 17 May 99 9:32 pm
Tgt Ion:240 Resp: 215551
Ion Ratio Lower Upper
240 100
120 26.4 24.1 36.1
0 0.0 0.0 0.0
0 0.0 0.0 0.0
ENG
#23
Chrysene(CCC)
Concen: 0.51 ng/uL
RT: 39.16 min Scan# 4467
Delta R.T. -0.06 min
Lab File: ENG1308.D
Acq: 17 May 99 9:32 pm
Tgt Ion:228 Resp: 298879
Ion
228
114
0
0
Ratio
100
23.4
0.0
0.0
Lower Upper
20.1
0.0
0.0
30.1
0.0
0.0
OCO 3220
Wed May 19 10:11:41 1999
HP 5989B
Page 13
-------
Abundance
60000 -
40000:
20000 -
^—
Time--> 45.60
TIC: ENG1308.D
45.80
-i 1 1 r
46.00
#24
Benzo(b)fIuoranthene-dl2
Concen: 0.35 ng/uL
RT: 45.85 min Scantf 5496
Delta R.T. -0.12 min
Lab File: ENG1308.D
Acq: 17 May 99 9:3 2 pm
Tgt Ion:264 Resp: 120183
Ion Ratio Lower Upper
264 100
132 30.2 24.1 36.1
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundanceton 264.00 (263.70 to 264.vu;
•lion 132.00 (131.70 to 132.70)
20000 -
10000 J
ENG
Time--> 45 .60
45180
46100
Abundance
60000 :
40000 .
20000:
Time-->
TIC: BNG1308.D
0
45.90 46.00 46.10 46.20
AbundanceXon 252.00 (251.70 to 252.70): fiNG
Ion 126.00 (125.70 to 126.70): ENG
30000 -
20000 J
10000 -
Time-->
46.05
45190 46100 46.10 46.20
ENG1308.DPES.M
#25
Benzo(b)fluoranthene
Concen: 0.42 ng/uL
RT: 46.05 min Scantf 5526
Delta R.T. -0.12 min
Lab File: ENG1308.D
Acq: 17 May 99 9:32 pm
Tgt Ion:252 Resp: 185170
Ion
252
126
0
0
Ratio
100
27.7
0.0
0.0
Lower Upper
20.1
0.0
0.0
30.1
0.0
0.0
Wed May 19 10:11:44 1999
HP 5989B
Page 14
-------
Abundance
60000.
40000 -
20000 -
Time-->
TIC: ENG1308.D
0
~\ 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 r
45.80 46.00 46.20
lAbundancelon 264.00 (263.70 to 264.70): ENG
Ion 132.00 (131.70 to 132.70): ENG
46.06
20000 -
10000 .
0 .
Time-->
45i80
46.00
46.20
Benzo(k)fIuoranthene-dl2
Concen: 0.43 ng/uL
RT: 46.06 min Scan# 5527
Delta R.T. -0.11 min
Lab File: ENG1308.D
Acq: 17 May 99 9:32 pm
Tgt Ion:264 Resp:
Ion Ratio Lower
264 100
132 32.0 24.1
0 0.0 0.0
0 0.0 0.0
166918
Upper
36.1
0.0
0.0
Abundance
60000 J
40000:
20000:
Time-->
TIC: ENG1308.D
46.00
46^20
46.40
Abundance Ion 252.00 (251.70 to 252.70)
Ion 126.00 (125.70 to 126.70)
ENG
ENG
30000.
20000-
10000 -
46.22
Time-->
46100
46.20 46.40
ENG1308.D PES.M
Wed May 19 10:11:48 1999
#27
Benzo(k)fluoranthene
Concen: 0.41 ng/uL
RT: 46.22 min Scan# 5552
Delta R.T. -0.11 min
Lab File: ENG1308.D
Acq: 17 May 99 9:32 pm
Tgt Ion:252 Resp: 196143
Ion
252
126
0
0
Ratio
100
27.9
0.0
0.0
Lower Upper
20.1
0.0
0.0
30.1
0.0
0.0
OCG 33-22
HP 5989B
Page 15
-------
Abundance
30000 -
20000 -
rime-->
'TIC: ENG1308.D
10000 -
0
T 1 1 1 1
48.20
48.40
i — i — I — i — i — i — i — I — i —
48.60 48.80
Abundancelon 264.00 (263.70 to 264.70): ENG
Ion 132.00 (131.70 to 132.70): ENG
48.52
10000 -
5000 .
Time-->
48.20 48.40 48.60 48.80
#28
Benzo(a)pyrene-d!2
Concen: 0.28 ng/uL
RT: 48.52 min Scant* 5905
Delta R.T. -0.14 min
Lab File: ENG1308.D
Acg: 17 May 99 9:32 pm
Tgt Ion:264 Resp: 76396
Ion Ratio Lower Upper
264 100
132 30.4 24.1 36.1
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance
30000J
20000 -
10000 -
0
Time-->
TIC: ENG1308.D
48.40 48.60 48.80 49.00
(Abundance I on 252TOO (251.70 to 252.70): ENG
Ion 126.00 (125.70 to 126.70): ENG
48.74
15000.
10000.
5000 -
0'.
Time-->
48.40 48.60 48.80 49.00
ENG1308.D—PES.M
Wed May 19 10:ll:bl
#29
Benzo(a)pyrene(CCC)
Concen: 0.29 ng/uL
RT: 48.74 min Scan# 5938
Delta R.T. -0.13 min
Lab File: ENG1308.D
Acq: 17 May 99 9:32 pm
Tgt Ion:252 Resp: 121311
Ion
252
126
0
0
Ratio
100
27.6
0.0
0.0
Lower Upper
20.1
0.0
0.0
30.1
0.0
0.0
HP 5989B
Page 16
-------
Abundance
20000-
Time--> 60.50 61.00 61.50 62.00 62.50
TIC: ENG1308.D
10000-
0
Abundancelon 288.00 (287.70 to 288.70): ERG
6000 .
4000:
2000:
o:
Time--> eols'o' 'eilo'o' 'e'lls'o' '62 loo' '62150
#30
Indeno(1,2,3-cd)pyrene-d!2
Concen: 0.00 ng/uL
Expected RT: 61.66 min
Lab File: ENG1308.D
Acq: 17 May 99 9:32 pm
Tgt Ion: 288
Ion Exp Ratio
288 100
0 0.0
0 0.0
0 0.0
ENG
Abundance
20000 .
10000 .
0 -
TIC: ENG1308.D
Time--> ' 6l!o6 ' ' 62lo6 ' ' 63loO
Abundance
8000 .
6000 :
4000 :
2000 .
o :
rime - - >
Ion 276.05 (275.75 to 276.75): ENG
Ion 138.00 (137.70 to 138.70): ENG
i-M**.*,.^,***,**,-, _«r -*/ ^*t*£*ZZ2?M~^' r-^-TOY^rr^rw*,
eiloo ' ' 62!oo ' ' esloo
1308. D PES.M Wed May 19 10:11:55 1999
#31
Ind
Con
Exp
Lab
Acq
Tgt
Ion
276
138
0
0
Indeno(1,2,3 -cd)pyrene
Concen: 0.00 ng/uL
Expected RT: 62.00 min
.le: ENG1308.D
Acq: 17 May 99 9:32 pm
n: 276.05
Exp Ratio
100
64.0
0.0
0.0
OC032
HP 5989B
Page 17
-------
Abundance
20000 -
10000-
o
TIC: ENG1308.D
^_f I .hi I***., f* t
u • r -T- ni i i i i i i ' ' |
Time--> 61 00 62.00
Abundance
4000 -
2000 -
0-
Time-->
Ion 292.00 (291.70 to 292. 70): ENG
61 00 62.00
#32
Dibenz (a
Concen :
Expected
Lab File
Acq: 17
Tgt Ion:
Ion
292
0
0
0
, h) anthracene-d!4
0.00 ng/uL
RT: 61.60 min
: ENG1308.D
May 99 9:32 pm
292
Exp Ratio
100
0.0
0.0
0 .0
ENG
Abundance
20000 -
10000-
0 -
TIC: ENG1308.D
Time--> ' 6l!od ' ' 62loO ' 63loO
Abundance
8000 -
6000 :
4000 -
2000 .
0 .
Time-->
Ion 278.00 (277.70 to 278.70): ENG
Ion 139.00 (138.70 to 139.70): ENG
6l!o6 ' 62ioO ' ' 63lod
1308. D PEb.M Wed May 19 10:11:59 1999
#33
Dibenz(a,h)anthracene
Concen: 0.00 ng/uL
Expected RT: 62.03 min
Lab File: ENG1308.D
Acq: 17 May 99 9:32 pm
Tgt Ion: 278
Ion Exp Ratio
278 100
139 60.0
0 0.0
0 0.0
oec
HP 5989B
Page 18
-------
Abundance
15000 -
10000-
5000-
Time--> 64.00
TIC: ENG1308.D
65.00
66.00
Abundance Ion 288700 (287.70 to 288.70) : ENG
6000 J
4000 .
2000-
o:
Time--> 64.00
65.00
66.00
#34
Benzo(g,h,i)perylene-d!2
Concen: 0.00 ng/uL
Expected RT: 65.27 min
Lab File: ENG1308.D
Acq: 17 May 99 9:32 pm
Tgt Ion: 288
Ion Exp Ratio
288 100
0 0.0
0 0.0
0 0.0
ENG
Abundance
15000 -i
10000 .
5000.
0
Time-->
TIC: ENG1308.D
/v v___
esloo ' ' eelob '
Abundancelon 276.00 (275.70 to 276.70): ENG
.
8000 :
eooo:
4000 .
2000.
0-
Pime - - >
Ion 138.00 (137.70 to 138.70): ENG
/\
A
__Jv__
esloo ' ' eeiod '
1308. D PES.M wea May 19 10:12:04 iyyy
#35
Benzo(g,h,i)perylene
Concen: 0.00 ng/uL
Expected RT: 65.64 min
Lab File: ENG1308.D
Acq: 17 May 99 9:32 pm
Tgt Ion: 276
Ion Exp Ratio
276 100
138 60.0
0 0.0
0 0.0
000)225
HP 5989B
Page 19
-------
Quantitation Report
Data File
Acq On
Sample
Misc
Quant Time: May 19
C:\HPCHEM\1\DATA\9919\ENG1309.D
17 May 99 10:48 pm
PES-MAH-051299-04 2.5 ng//iL
9:29 1999
Vial: 3
Operator: JEMcCartney
Inst : HP 5989B
Multiplr: l.OO
Method
Title
Last Update
Response via
C:\HPCHEM\1\METHODS\PES.M
Wed May 19 09:55:02 1999
Multiple Level Calibration
Internal Standards
1)
2 , 2 -Dif luorobiphenyl
R
24
.T.
.59
Qlon
190
Response
1184369
Cone Units Dev(Min)
5
.00
System Monitoring Compounds
2)
4)
5)
7)
9)
11)
13)
15)
17)
19)
20)
22)
24)
26)
28)
30)
32)
34)
Naphthalene -d8
2-Methlynaphthalene-dlO
Acenaphthylene-d8
Acenaphthene-dlO
Fluorene-dlO
Phenant hrene - dl 0
Anthracene -dlO
Fluoranthene-dlO
Pyrene-dlO
p-Terphenyl-d!4
Benzo (a) anthracene-d!2
Chrysene-dl2
Benzo (b) f Iuoranthene-dl2
Benzo (k.) f Iuoranthene-dl2
Benzo (a) pyrene-d!2
Indeno(l,2, 3-cd)pyrene-dl2
Dibenz (a,h) anthracene-d!4
Benzo (g, h, i) perylene-d!2
22
23
26
26
28
30
30
33
34
34
38
39
45
46
48
61
61
65
.23
.96
.29
.71
.00
.43
.57
.57
.25
.57
.87
.03
.87
.06
.53
.47
.40
.03
136
152
160
164
176
188
188
212
212
244
240
240
264
264
264
288
292
288
916794
482332
983139
693103
724332
1220981
1056015
1263845
1414655
1048780
822781
1113145
704982
1013323
576625
622065
359691
447124
2
2
2
2
2
2
2
3
3
3
2
3
2
3
2
1
1
1
.54
.52
.58
.75
.64
.88
.86
.01
.07
.00
.76
.09
.41
.07
.47
.99
.93
.73
Target Compounds
3)
6)
8)
10)
12)
14)
16)
18)
21)
23)
25)
27)
29)
31)
33)
35)
Naphthalene(CCC)
Acenaphthylene
Acenaphthene (CCC)
Fluorene
Phenanthrene
Anthracene
Fluoranthene (CCC)
Pyrene
Benzo (a) anthracene
Chrysene(CCC)
Benzo (b) f luoranthene
Benzo (k) f luoranthene
Benzo (a) pyrene (CCC)
Indeno (1,2,3- cd) pyrene
Dibenz (a, h) anthracene
Benzo (g, h, i) perylene
22
26
26
28
30
30
33
34
38
39
46
46
48
61
61
€5
.28
.32
.79
.07
.49
.62
.62
.30
.98
.16
.06
.23
.75
.79
.82
.41
128
152
154
166
178
178
202
202
228
228
252
252
252
27€
278
276
1040208
1101521
743658
868765
1472070
1430308
1673083
1832217
1308489
1529953
1088213
1176178
902924
783891
614691
6€2556
2
2
2
2
2
2
3
3
3
3
2
2
2
2
1
2
.48
.60
.63
.63
.86
.88
.01
.05
.03
.07
.88
.86
.53
.07
.99
.01
ng/uL -0.
03
% Re co very
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL m
ng/uL m
ng/uL
Qvalue
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uLm
ng/uL#
ng/uL#
92
98
90
87
99
99
92
93
95
98
91
86
92
39
35
41
OC03227
(#) = qualifier out of range (m) = manual integration
ENG1309.D PES.M Wed May 19 10:12:42 1999 HP 5989B
Page 1
-------
Quantitation Report
Data File : C:\HPCHEM\1\DATA\9919\ENG1309.D
Acq On : 17 May 99 10:48 pm
Sample : PES-MAH-051299-04 2.5
Misc :
Quant Time: May 19 9:29 1999
Method
Title
Last Update
Response via
C:\HPCHEM\1\METHODS\PES.M
Wed May 19 09:55:02 1999
Multiple Level Calibration
Vial: 3
Operator: JEMcCartney
Inst : HP 5989B
Multiplr: 1.00
Abundance
1000000 J
900000.
sooooo:
•
700000^
600000 :
500000 J
400000 I
300000^
200000-
100000
0
Time-->
TIC: ENG1309.D
16
12
10 14
1 8
6
3
2s
4s
1 — i
1 1 1 1 1 T
20.00
5£
9
3
i:
i
3
S -j
U_i
:
X
S
)S
21
2*?
1 233B3
2( S 2?
2^s29 31
28S
§§(§ 35
i 1 34s
LLU LL
1 1 1 i 1 1 1 I i 1 1 1 1 1 i 1 i 1 1 1 ;
30 00 40.00 50.00 60.00
ENG1309.D PES.M
Wed May 19 10:12:54 1999
HP 5989B
Page 2
-------
ENG
Abundance
400000 -
200000 -
0
Time-->
Abundance
400000 :
300000 :
200000 :
100000 :
o :
Time - - >
TIC: ENG1309.D
l\
— 1 1 1 1 1 1 1 1 1 r~ — i 1 1 1 r I i |
22.00 22.20 22.40
Ion 136.00 (135.70 to 136.70): ENG
Ion 68.00 (67.70 to 68.70): ENG13
22.23
(1
1
l/\
22100 ' 22 20 ' 22140 '
Abundance
400000-
200000 -
0
Time--> I
Abundance
400000-
200000 .
0
Time--> <
TIC: ENG1309.D
/ \_
>2lo6 ' ' 22120 ' ' 22140 '
Ion 128.00 (127.70 to 128.70): ENG
Ion 127.00 (126.70 to 127.70): ENG
22.28
A
it
22100 ' 22120 ' ' 22U6 '
1309. D PES.M wea May 19 10:12:59 1999
#2
Naphthalene-d8
Concen: 2.54 ng/uL
RT: 22.23 min Scantt 1566
Delta R.T. -0.05 min
Lab File: ENG1309.D
Acq: 17 May 99 10:48 pm
Tgt Ion: 136 Resp-. 916794
Ion
136
68
0
0
Ratio
100
16.9
0.0
0.0
Lower Upper
10.1
0.0
0.0
30.1
0.0
0.0
Naphthalene(CCC)
Concen: 2.48 ng/uL
RT: 22.28 min Scantf 1574
Delta R.T. -0.05 min
Lab File: ENG1309.D
Acq: 17 May 99 10:48 pm
Tgt Ion:128 Resp: 1040208
Ion
128
127
0
0
Ratio
100
13.1
0.0
0.0
Lower Upper
0.0
0.0
0.0
60.0
0.0
0.0
OCC3223
HP 5989B
Page 3
-------
Abundance
200000:
isoooo:
100000:
soooo:
TIC: ENG1309.D
Time-->
Abundance ion 152.00 (151.70 to 152.70): ENG
23.90
24.00
200000 .
100000.
0-
23.96
23.90
24.00
2-Methlynaphthalene-dlO
Concen: 2.52 ng/uL
RT: 23.96 min Scant 1927
Delta R.T. -0.04 min
Lab File: ENG1309.D
Acq: 17 May 99 10:48 pm
Tgt Ion:152 Resp: 482332
Ion Ratio Lower Upper
152 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
^MBBS6
400000 .
200000.
0
Time-->
Abundance
400000-
200000.
0
Time-->
TIC: ENG1309.D
J {
'26!io' 26! 20' 26130' 26l4o' '26!5o'
ion 160.00 (159.70 to 160.70): ENG
26.29
A
J\_
26lio' 26! 20 26130 26140' 26l50'
ENG1309.D—PES.M
Wed May 19 10:13:02
#5
Ac enaphthylene-d8
Concen: 2.58 ng/uL
RT: 26.29 min Scan# 2449
Delta R.T. -0.01 min
Lab File: ENG1309.D
Acq: 17 May 99 10:48 pm
Tgt Ion:160 Resp: 983139
Ion
160
0
0
0
Ratio
100
0.0
0.0
0.0
Lower Upper
0.0
0.0
0.0
0.0
0.0
0.0
HP 5989B
Page 4
-------
^B89B5e
400000 .
200000 -
0 -
rime - - >
Abundance
400000-
200000 -
0-
Time-->
— — Tnrr~ENG1309.D
\
26.20 26.40
Ion 152.00 (lSl.70 to 152.70): ENG
Ion 153.00 (152.70 to 153.70): ENG
26.32
fl
JA.
26120 ' ' 26140 '
Abundance
600000 .I
400000 .
200000.
rime--> 26.50 26.60 26.70 26.80 26.90
TIC: ENG1309.D
#6
Acenaphthylene
Concen: 2.60 ng/uL
RT: 26.32 min Scan# 2454
Delta R.T. -0.02 min
Lab File: ENG1309.D
Acq: 17 May 99 10:48 pm
Tgt Ion-.152 Resp: 1101521
Ion Ratio
152 100
153 14.2
0 0.0
0 0.0
Lower Upper
7.6
0.0
0.0
22.6
0.0
0.0
Abundance Ion 164.0(3 (163.70 to 164.70); ENG
300000 -
200000 .
100000 '.
26.71
Time-->
26.50
26.60 26.70 26:80 26.90
^, ENG1309 .D PES.M
#7
Acenaphthene-dl0
Concen: 2.75 ng/uL
RT: 26.71 min Scantf 2511
Delta R.T. -0.04 min
Lab File: ENG1309.D
Acq: 17 May 99 10:48 pm
Tgt Ion:164 Resp: 693103
Ion
164
0
0
0
Ratio
100
0.0
0.0
0.0
Lower Upper
0.0
0.0
0.0
0.0
0.0
0.0
oc
Wed May 19 10:13:Ob
HP 5989B
C3221
Page 5
-------
riC: ENG1309.D
Time-->
0
30.40
30.50
30.60
Abundance Ion
Ion
600000 J
400000:
200000:
0
178.00
176.00
(177.70 to 178.70): EtfG
(175.70 to 176.70): ENG
30.49
Time-->
30.40
30!50
30.60
#12
Phenanthrene
Concen-. 2.86 ng/uL
RT: 30.49 min Scantf 3085
Delta R.T. -0.06 min
Lab File: ENG1309.D
Acq: 17 May 99 10:48 pm
Tgt Ion:178 Resp: 1472070
Ion Ratio
178 100
176 20.5
0 0.0
0 0.0
Lower Upper
10.1
0.0
0.0
30.1
0.0
0.0
rime- ->
TIC: ENG1309.D
30.40
30.60
30.80
Abundancelon 188.00 (187.70 to 188.70): ENG
600000JIon 94-00 (93.70 to 94.70): ENG13
400000 .
200000 -
0
30.57
Time-->
30.40
30.60
30.80
ENG1309.DPES.M
Wed May 19 10:13:17 1993
#13
Anthracene-dlO
Concen: 2.86 ng/uL
RT: 30.57 min Scantf 3098
Delta R.T. -0.06 min
Lab File: ENG1309.D
Acq: 17 May 99 10:48 pm
Tgt Ion:188 Resp: 1056015
Ion
188
94
0
0
Ratio
100
31.8
0.0
0.0
Lower Upper
15.1
0.0
0.0
45.1
0.0
0.0
000224
HP 5989B
Page 8
-------
TIC: ENG1309.D
Time--:30 40 30.50 30.60 30.70
600000 J
400000 -
200000 .
0
30.80
Abundance Ion 178.00 (177.70 to 178.70):
Ion 176.00 (175.70 to 176.70):
30.62
600000 J
400000 J
200000:
ENG
ENG
0
Time--^0 40 30150 30!60 30170 30^80
#14
Anthracene
Concen: 2.88 ng/uL
RT: 30.62 min Scant 3105
Delta R.T. -0.07 min
Lab File: ENG1309.D
Acq: 17 May 99 10:48 pm
Tgt Ion:178 Resp: 1430308
Ion Ratio Lower Upper
100
10.1
178
176
0
0
19.7
0.0
0.0
0.0
0.0
30.1
0.0
0.0
Abundance
800000 :
600000 :
400000 :
200000 :
o :
Time-->
Abundance
400000 -
200000 -
0 .
Time-->
TIC: ENG1309.D
A/1
I j
/ v
33U6 ' ' 33160 ' ' 33180
Ion 212.00 (211.70 to 212.70): ENG
Ion 106.00 (105.70 to 106.70): ENG
33.57
A
Jr\_
33140 ' ' 33160 ' ' 33180
ENG1309.DPES.M
#15
Fluoranthene-dlO
Concen: 3.01 ng/uL
RT: 33.57 min Scan# 3624
Delta R.T. -0.04 min
Lab File: ENG1309.D
Acq: 17 May 99 10:48 pm
Tgt Ion:212 Resp: 1263845
Ion
212
106
0
0
Ratio
100
33.5
0.0
0.0
Lower Upper
15.1
0.0
0.0
45.1
0.0
0.0
wea May 19 10:13:21 1999
HP 5989B
Page 9
-------
ENG
Sundance
800000 J
600000 :
400000 :
200000 :
0 J
Time - - >
Abundance
600000 -
400000 :
200000 :
0 -
Time - - >
TIC: ENG1309.D
A/1
I \
^x ^^~
33.40 33 60 33.80
Ion 202.00 (201.70 to 202.70): ENG
Ion 101.00 (100.70 to 101.70): ENG
33.62
j
II
33140 33 60 33!s6
Abundance
800000 -
600000 :
400000 _
200000 :
0
rime-->
Abundance
400000 .
200000 .
0 .
rime-->
TIC: ENG1J09.D
r
A
J { /I
1 ! ! , , , , . r.... 1 I 1 1 1 1 1—
34 00 34.20 34.40
Ion 212.00 (211.70 to 212.70): ENG
Ion 106.00 (105.70 to 106.70): ENG
34.25
A
A
H .
34lo6 34120 34140 '
1309. D PES.M Wed May 19 10:13:2b lyyy
#16
Fluoranthene(CCC)
Concen: 3.01 rig/uL
RT: 33.62 min Scan# 3632
Delta R.T. -0.01 min
Lab File: ENG1309.D
Acq: 17 May 99 10:48 pm
Tgt Ion:202 Resp: 1673083
Ion Ratio
202 100
101 31.2
0 0.0
0 0.0
Lower Upper
13.6 40.6
0.0 0.0
0.0 0.0
#17
Pyrene-dlO
Concen: 3.07 ng/uL
RT: 34.25 min Scan# 3725
Delta R.T. -0.08 min
Lab File: ENG1309.D
Acq: 17 May 99 10:48 pm
Tgt Ion:212 Resp: 1414655
Ion
212
106
0
0
Ratio
100
37.5
0.0
0.0
Lower Upper
17.1
0.0
0.0
51.1
0.0
0.0
OCC3235
HP 5989B
Page 10
-------
lAbundance
800000 :
600000:
400000:
200000:
TIC: ENG1309.D
Time--> 34.00
0
34.20
34.40
Abundancelon 202.00 (201.70 to 202.70)
Ion 101.00 (100.70 to 101.70)
34.30
600000 J
400000:
200000:
o:
ENG
ENG
Time--> 34.00
34.20
34.40
Pyrene
Concen: 3.05 ng/uL
RT: 34.30 min Scan# 3733
Delta R.T. -0.08 min
Lab File: ENG1309.D
Acq: 17 May 99 10:48 pm
Tgt Ion:202 Resp: 1832217
Ion Ratio
202 100
101 35.8
0 0.0
0 0.0
Lower Upper
16.1
0.0
0.0
48.1
0.0
0.0
Abundance
800000:
Time-->
TIC-. ENG1309.D
34.40
34.60
34.80
Abundance Ion 244.00 (243.70 to 244.70): ENG
400000:
Ion 122.00 (121.70 to 122.70): ENG
34.57
300000:
200000:
100000:
Time-->
34.40
34:50
34!80
ENG1J09.D—PES.M
Wed May iy 10:13:28
#19
p-Terphenyl-d!4
Concen: 3.00 ng/uL
RT: 34.57 min Scan# 3773
Delta R.T. -0.06 min
Lab File: ENG1309.D
Acq: 17 May 99 10:48 pm
Tgt Ion:244 Resp: 1048780
Ion
244
122
0
0
Ratio
100
28.8
0.0
0.0
Lower Upper
13 .6
0.0
0.0
40.6
0.0
0.0
OCC3237
HP 5989B
Page 11
-------
Time--> 38.70 38.80 38.90 39.00
undance
400000 .
300000 .
200000 .
100000 -
0
TIC: ENG1309.D
Abundancelon 240.00 (239.70 to 240.70): ENG
Ion 120.00 (119.70 to 120.70): ENG
200000 -
100000 .
Time--> 38.70 38.80 38.90
39:00
#20
Benzo(a)anthracene-d!2
Concen: 2.76 ng/uL
RT: 38.87 min Scan# 4420
Delta R.T. -0.11 min
Lab File: ENG1309.D
Acq: 17 May 99 10:48 pm
Tgt Ion:240 Resp: 822781
Ion Ratio
240 100
120 32.0
0 0.0
0 0.0
Lower Upper
15.1
0.0
0.0
45.1
0.0
0.0
Abundance
Time-->
TIC: ENG1309.D
38.80
39.00
39.20
Abundancelon 228.00 (227.70 to 228.70): ENG
Ion 114.00 (113.70 to 114.70): ENG
300000:
200000 J
100000:
o:
38.98
rime-->
39:00
39.20
ENG1309.D—PES.M
Wed May iy 10:13:32 1999
Benzo(a)anthracene
Concen: 3.03 ng/uL
RT: 38.98 min Scant 4437
Delta R.T. -0.07 min
Lab File: ENG1309.D
Acq: 17 May 99 10:48 pm
Tgt Ion:228 Resp: 1308489
Ion
228
114
0
0
Ratio
100
27.7
0.0
0.0
Lower Upper
12.6
0.0
0.0
37.6
0.0
0.0
OCO 32.23
HP 5989B
Page 12
-------
Abundance
400000 :
300000 :
200000:
100000:
Time-->
TIC: ENG1309.D
0
38.80
-i 1 1 r
39.00
Abundance Ion 240.00 (239.70 to 240.70): ENG
Ion 120.00 (119.70 to 120.70): ENG
39.03
200000-
100000 .
Time-->
38.80
39.00
39.20
#22
Chrysene-dl2
Concen: 3.09 ng/uL
RT: 39.03 min Scan# 4445
Delta R.T. -0.06 min
Lab File: ENG1309.D
Acq: 17 May 99 10:48 pm
Tgt Ion:240 Resp: 1113145
Ion Ratio
240 100
120 29.6
0 0.0
0 0.0
Lower Upper
15.1
0.0
0.0
45.1
0.0
0.0
Abundance
400000 .
300000 .
200000 .
100000 -
Time-->38 .80
TIC: ENG1309.D
39.00
39.20
39.40
(AbundanceIon 228.00 (227.70 to 228.70) :
Ion 114.00 (113.70 to 114.70):
39.16
300000 J
200000 -
100000 J
0 .
Time-->38!80 39100 39120 39140
ENG
ENG
ENG1309.D—PEST]
Wed May 19 10:13:36 1999
#23
Chrysene(CCC)
Concen: 3.07 ng/uL
RT: 39.16 min Scan# 4465
Delta R.T. -0.06 min
Lab File: ENG1309.D
Acq: 17 May 99 10:48 pm
Tgt Ion:228 Resp: 1529953
Ion
228
114
0
0
Ratio
100
26.0
0.0
0.0
Lower Upper
12.6
0.0
0.0
37.6
0.0
0.0
HP 5989B
Page 13
-------
PIC: ENG1309.D
Time-->
i—i—i—r—i—i—i—i—I—i—r
45.70 45.80
T ! 1 I 1 1 1 1
45!90 46lOO
Abundanceton 264.00 (263.70 to 264.70): ENG
150000JIOn 132'00 (131-70 to 132.70): ENG
100000 J
50000 -
Time-->
45.70 45.80 45.90 46.00
#24
Benzo(b)fluoranthene-d!2
Concen: 2.41 ng/uL
RT: 45.87 min Scan# 5496
Delta R.T. -0.10 min
Lab File: ENG1309.D
Acq: 17 May 99 10:48 pm
Tgt Ion:264 Resp: 704982
Ion Ratio Lower Upper
264 100
132 31.5 15.1 45.1
0 0.0 0.0 0.0
0 0.0 0.0 0.0
[Abundance
TIC: ENG1309.D
Time--> 45.80
46.00
46.20
Abundancelon 252.00 (251.70 to 252.70): ENG
Ion 126.00 (125.70 to 126.70): ENG
46.06
150000J
100000 .
50000-
0 .
Time--> 45180 46lOO 4€l20
ENG1309.DPBS.M
#25
Benzo(b)fluoranthene
Concen: 2.88 ng/uL
RT: 46.06 min Scan# 5525
Delta R.T. -0.11 min
Lab File: ENG1309.D
Acq: 17 May 99 10:48 pm
Tgt Ion:252 Resp: 1088213
Ion
252
126
0
0
Ratio
100
29.3
0.0
0.0
Lower Upper
12.6
0.0
0.0
37.6
0.0
0.0
OCC3210
Wed May 19 10:13:4O 1999
HP 5989B
Page 14
-------
Abundance
300000 :
200000:
100000:
Time-->
TIC: ENG1309.D
Abundancelon 264.00 (263.70 to 264.70)
150000 -
100000 .
50000 -
0 .
Ion 132.00 (131.70 to 132.70): ENG
46.06
Time-->
45.80
46.00 46.20
#26
Benzo(k)fIuoranthene-dl2
Concen-. 3.07 ng/uL
RT: 46.06 min Scan# 5526
Delta R.T. -0.11 min
Lab File: ENG1309.D
Acq: 17 May 99 10:48 pm
Tgt Ion:264 Resp: 1013323
Ion Ratio
264 100
132 32.6
0 0.0
0 0.0
Lower Upper
15.1
0.0
0.0
45.1
0.0
0.0
Abundance
300000 -
200000:
100000:
Time-->
TIC: ENG1309.D
46100
45:20
46.40
Abundance Ion 252.00 (251.70 to 252.70)
Ion 126.00 (125.70 to 126.70)
46.23
150000J
100000-
50000.
ENG
ENG
0.
Time-->
46.00
46.20
46.40
ENGUOy.D PES.M
Wed May 19 10:1J:43
#27
Benzo(k)fluoranthene
Concen: 2.86 ng/uL
RT: 46.23 min Scan# 5551
Delta R.T. -0.10 min
Lab File: ENG1309.D
Acq: 17 May 99 10:48 pm
Tgt Ion:252 Resp: 1176178
Ion
252
126
0
0
Ratio
100
32.2
0.0
0.0
Lower Upper
12.6
0.0
0.0
37.6
0.0
0.0
0(20321
-t
HP 5989B
Page 15
-------
Abundance
150000-
100000 -
50000 .
Time-->
TIC: ENG1309.D
0
T 1 1 1 1 1 1 1 1 1 1 1 1 1 I 1 1 I 1 1
48!20 48.40 48.60 48.80
Abundance Ion 264.00 (263.70 to 264.70): ENG
80000 -ilon 132.00 (131.70 to 132.70): ENG
48.53
60000 :
40000 :
20000:
Time-->
48.20
I—i—i—i—i
48.40 48.60
48.80
#28
Benzo(a)pyrene-d!2
Concen: 2.47 ng/uL
RT: 48.53 min Scantf 5904
Delta R.T. -0.13 min
Lab File: ENG1309.D
Acq: 17 May 99 10:48 pm
Tgt Ion:264 Resp: 576625
Ion Ratio
264 100
132 32.5
0 0.0
0 0.0
Lower Upper
15.1
0.0
0.0
45.1
0.0
0.0
Abundance
150000 -
100000 .
50000 .
Time-->
TIC: ENG1309.D
48.50
49.00
Abundancelon 252.00 (251.70 to 252.70)
Ion 126.00 (125.70 to 126.70)
48.75
100000 J
50000 .
0 .
ENG
Time-->
48.50
49100
#29
Benzo(a)pyrene(CCC)
Concen: 2.53 ng/uL
RT: 48.75 min Scantf 5938
Delta R.T. -0.12 min
Lab File: ENG1309.D
Acq: 17 May 99 10:48 pm
Tgt Ion:252 Resp: 902924
Lower Upper
Ion
252
126
0
0
Ratio
100
28.9
0.0
0.0
12.6
0.0
0.0
37.6
0.0
0.0
ENG1309.DPES.M
Wed May 19 10:13:47 1999
HP 5989B
Page
-------
Abundance
150000 -I
100000 .
50000H
Time-->
TIC: ENG1309.D
61.00
61.50
62:00
Abundance Ion 288.00 (287.70 to 288.70): ENG
40000 :
30000 .
20000:
10000 -
o:
61.47
Time-->
61.00
61.50
62.00
Abundance
150000 -I
100000 -
50000 .
Time--> 61.00
TIC: ENG1309.D
61.50
62.00
62.50
#30
Indeno(1,2,3-cd)pyrene-d!2
Concen: 1.99 ng/uL m
RT: 61.47 min Scantf 8104
Delta R.T. -0.19 min
Lab File: ENG1309.D
Acq: 17 May 99 10:48 pm
Tgt Ion:288 Resp: 622065
Ion Ratio
288 100
0 0.0
0 0.0
0 0.0
Lower Upper
0.0
0.0
0.0
0.0
0.0
0.0
Abundance Ion 276.05 (275.75 to 276.75) : ENG
Ion 138.00 (137.70 to 138.70): ENG
60000 .
40000 .
20000 J
0 .
61.79
rime--> 61.00
61.50
62100
62!50
ENG1309.DPES. M
#31
Indeno(1,2,3 -cd)pyrene
Concen: 2.07 ng/uL m
RT: 61.79 min Scan# 8165
Delta R.T. -0.21 min
Lab File: ENG1309.D
Acq: 17 May 99 10:48 pm
Tgt Ion:276.05 Resp: 783891
Ion
276
138
0
0
Ratio
100
42.8
0.0
0.0
Lower Upper
32.1
0.0
0.0
96.1
0.0
0.0
Wed May 19 10:13:51 1999
HP 5989B
Page 17
-------
Abundance
150000 -I
100000 -
50000-
rime-->60:50 61.00
TIC: ENG1309.D
61.50
Abundancelon 292.00 U91.70 to 292.70)
61.40
20000.
10000 .
0 -
rime-->60.50
61.00
61.50
62.00
Abundance
150000 J
100000 .
50000 -
Time-->
TIC: ENG1309.D
0
#32
Dibenz(a,h)anthracene-d!4
Concen: 1.93 ng/uL m
RT: 61.40 min Scantf 8091
Delta R.T. -0.20 min
Lab File: ENG1309.D
Acq: 17 May 99 10:48 pm
Tgt Ion:292 Resp: 359691
Ion Ratio Lower Upper
292 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
62.00
62.50
Abundancelon 278.00 (277.70 to 278.70): ENG
Ion 139.00 (138.70 to 139.70): ENG
61.82
40000-
20000-
rime-->
61.50
62.00
62.50
PES.M
Wed May 19 10:13:55
#33
Dibenz(a,h)anthracene
Concen: 1.99 ng/uL
RT: 61.82 min Scant 8170
Delta R.T. -0.21 min
Lab File: ENG1309.D
Acq: 17 May 99 10:48 pm
Tgt Ion:278 Resp: 614691
Ion
278
139
0
0
Ratio
100
10.8
0.0
0.0
Lower Upper
30.1
0.0
0.0
90.1#
0.0
0.0
OCC3213
HP 5989B
Page 18
-------
Abundance
60000 :
40000 -
20000:
Time--> 64.50
TIC: ENG1309.D
65.00
65150
Sundance Ion 288.00 (287.70 to 288.70): ENG
65.03
30000 :
20000:
10000:
Time--> 64.50
65.00
65.50
20000 .
0
Time-->
TIC: ENG1309.D
65.00
65.50
66.00
Abundancelon 276.00 (275.70 to 276.70): ENG
Ion 138.00 (137.70 to 138.70): ENG
65.41
40000.
20000 .
#34
Benzo(g,h,i)perylene-d!2
Concen: 1.73 ng/uL
RT: 65.03 min Scan# 8828
Delta R.T. -0.24 min
Lab File: ENG1309.D
Acq: 17 May 99 10:48 pm
Tgt Ion:288 Resp: 447124
Ion Ratio Lower Upper
288 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 .
rime-->
65.00
65!50
66.00
ENG1309.DPES.M
#35
Benzo(g,h,i)perylene
Concen: 2.01 ng/uL
RT: 65.41 min Scan# 8921
Delta R.T. -0.23 min
Lab File: ENG1309.D
Acq: 17 May 99 10:48 pm
Tgt Ion:276 Resp: 662556
Ion
276
138
0
0
Ratio
100
15.2
0.0
0.0
Lower Upper
30.1
0.0
0.0
90.1#
0.0
0.0
Wed. May 19 10:13:59 1999
HP 5989B
Page 19
-------
Quantitation Report
Data File :
Acq On :
Sample :
Misc ;
Quant Time:
Method
Title
Last Update
Response via
C:\HPCHEM\1\DATA\9919\ENG1310.D
18 May 99 12:04 am
PES-MAH-051299-05 5 ng//iL
May 19 9:37 1999
: C:\HPCHEM\1\METHODS\PES.M
: Wed May 19 09:55:02 1999
Multiple Level Calibration
Vial: 4
Operator: JEMcCartney
Inst : HP 5989B
Multiplr: 1.00
Internal Standards
R.T. Qlon Response Cone Units Dev(Min)
1)
2 , 2 -Dif luorobiphenyl
24
.58
190
1169914
5
.00
System Monitoring Compounds
2)
4)
5)
7)
9)
11)
13)
15)
17)
19)
20)
22)
24)
26)
28)
30)
32)
34)
Naphthalene -d8
2-Methlynaphthalene-dlO
Acenaphthylene-d8
Acenaphthene-dlO
Fluorene-dlO
Phenan t hr ene - dl 0
Anthracene -dlO
Fluoranthene-dlO
Pyrene -dlO
p-Terphenyl-d!4
Benzo (a) anthracene -d!2
Chrysene-dl2
Benzo (b) f luoranthene -d!2
Benzo (k) f Iuoranthene-dl2
Benzo (a) pyrene-d!2
Indenod, 2, 3-cd)pyrene-dl2
Dibenz (a, h) anthracene -d!4
Benzo (g, h, i) perylene-d!2
22
23
26
26
28
30
30
33
34
34
38
39
45
46
48
61
61
65
.23
.96
.29
.71
.00
.43
.57
.57
.25
.57
.87
.03
.87
.07
.54
.48
.44
.06
136
152
160
164
176
188
188
212
212
244
240
240
264
264
264
288
292
288
1876458
1025447
2068133
1333374
1481983
2317755
1987643
2262279
2491344
1873909
1737418
2079850
1509750
2078310
1397377
1723736
989890
1403802
5
5
5
5
5
5
5
5
5
5
5
5
5
6
5
5
5
5
.26
.42
.50
.35
.48
.53
.45
.45
.47
.44
.94
.87
.79
.01
.99
.50
.35
.59
ng/uL
-0.04
% Recovery
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
Target Compounds
3)
6)
8)
10)
12)
14)
16)
18)
21)
23)
25)
27)
29)
31)
33)
35)
Naphthalene (CCC)
Acenapht hy 1 ene
Acenaphthene (CCC)
Fluorene
Phenanthrene
Anthracene
Fluoranthene (CCC)
Pyrene
Benzo (a) anthracene
Chrysene(CCC)
Benzo (b) f luoranthene
Benzo (k) f luoranthene
Benzo (a) pyrene (CCC)
Indenod, 2, 3 -cd) pyrene
Dibenz (a, h) anthracene
Benzo (g,h, i)perylene
22
26
26
28
30
30
33
34
38
39
46
46
48
61
61
65
.28
.32
.79
.08
.49
.62
.62
.30
.98
.16
.07
.23
.74
.83
.85
.44
128
152
154
166
178
178
202
202
228
228
252
252
252
276
278
276
2135850
2242559
1523875
1777441
2771683
2655715
3018048
3286165
2578744
2926481
2220049
2429284
2199024
2112387
1733759
1817794
5
5
5
5
5
5
5
5
6
5
5
6
6
5
5
5
.15
.35
.45
.45
.45
.41
.50
.54
.04
.95
.94
.04
.25
.64
.67
.55
C
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
m
m
Qvalue
90
99
94
87
98
100
87
88
93
95
93
82
90
67
100
92
(#) = qualifier out of range (m) = manual integration
ENG1310.D PES.M Wed May 19 10:15:57 1999 HP 5989B
Page 1
-------
Quantitation Report
Data File : C:\HPCHEM\1\DATA\9919\ENG1310.D
Acq On : 18 May 99 12:04 am
Sample : PES-MAH-051299-05 5 ng//iL
Misc :
Quant Time: May 19 9:37 1999
Method
Title
Last Update
Response via
C:\HPCHEM\1\METHODS\PES.M
Wed May 19 09:55:02 1999
Multiple Level Calibration
Vial: 4
Operator: JEMcCartney
Inst : HP 5989B
Multiplr: 1.00
Abundance
1800000 _
1600000-
-
1400000 .
.
1200000.
•
1000000-
800000 -
•
600000-
:
400000 -
200000 .
0
Time - - >
10 12
8
6
5S
3
2
S
1
r
4£
9
5
14
i:
i
3
.S
S
2olod 3olod
TIC: ENG1310.D ~
1
i
lc
JL
^—
8
S
21
223s
2(
JJHf
S 2
24
7
29 32
S
34s
li h
40.00 50 00 60.00
OCC321S
ENG1310.D PES.M Wed May 19 10:16:09 1999 HP 5989B
Page 2
-------
Abundance
1000000 -
500000 .
0 -
Time-->
Abundance
800000 :
600000 :
400000 :
200000 :
0 '
Time-->
TIC: KNG1310.D
A
22!00 ' ' 22120 ' ' 22140
Ion 136.00 (135.70 to 136.70): ENG
Ion 68.00 (67.70 to 68.70): ENG13
22.23
ft
1
l\
22!o6 22120 22U6
#2
Naphthalene-d8
Concen: 5.26 ng/uL
RT: 22.23 min Scantf 1566
Delta R.T. -0.05 min
Lab File: ENG1310.D
Acq: 18 May 99 12:04 am
Tgt Ion:136 Resp: 1876458
Ion Ratio
136 100
68 17.7
0 0.0
0 0.0
Lower Upper
10.1 30.1
0.0 0.0
0.0 0.0
Abundance
1000000j
Time--> 22.00
TIC: ENG1310.D
500000-
0
22.20
22.40
Abundancelon 128.00 (127.70 to 128.70): ENG
1000000 .
500000.
0
Ion 127.00 (126.70 to 127.70): ENG
22.28
rime--> 22.00
22.20
22.40
ENG1310.DPES.M
#3
Naphthalene(CCC)
Concen: 5.15 ng/uL
RT: 22.28 min Scantf 1574
Delta R.T. -0.05 min
Lab File: ENG1310.D
Acq: 18 May 99 12:04 am
Tgt Ion:128 Resp: 2135850
Ion
128
127
0
0
Ratio
100
13.7
0.0
0.0
Lower Upper
0.0
0.0
0.0
60.0
0.0
0.0
OCO')2-I7
Wed May 19 10:16:14 1999
HP 5989B
Page 3
-------
Abundance
400000 :
300000 :
200000 :
100000 :
o •
rime-->
Abundance
400000 .
200000 -
0 -
Time-->
TIC: ENG1310.D
' 231 80 ' ' 23.90 ' ' 24 lob ' ' 24 i 10 '
Ion 152.00 (151.70 to 152.70): ENG
23.96
A
J{
-\ — i — i — i — i — i — i — i — i — i — i — i — i — i — i — i — i — i — i — i —
23.80 23 90 24!oO 24 1 10
#4
2-M
Con
RT:
Del
Lab
Acq
Tgt
Ion
152
0
0
0
2-Methlynaphthalene-dlO
:en: 5.42 ng/uL
23.96 min Scantf 1927
.a R.T. -0.04 min
File: ENG1310.D
Acq: 18 May 99 12:04 am
Tgt Ion:152 Resp: 1025447
Ratio Lower Upper
100
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
Abundance
1000000 .
500000 .
0
Time-->26
Abundance
1000000 _
500000 -
0
Time-->26
TIC: ENG1310.D
j\
00 ' ' 26! 20 ' ' 26 Ud
Ion ISO. 00 (159.70 to 160.70): ENG
26.29
j[
1 1 1 1 1 1 1 1 1 1 1 1 1 r—
.00 26.20 26!40
#5
Acenaphthylene-d8
Concen: 5.50 ng/uL
RT: 26.29 min Scan# 2450
Delta R.T. -0.01 min
Lab File: ENG1310.D
Acq: 18 May 99 12:04 am
Tgt Ion:160 Resp: 2068133
Ion
160
0
0
0
Ratio
100
0.0
0.0
0.0
Lower Upper
0.0
0.0
0.0
0.0
0.0
0.0
OC03&23
HP 5989B
Page 4
-------
Abundance
1000000 .
500000 _
0 -
Time-->
Abundance
1000000-
500000 -
0
Time-->
TIC: ENG1310.D
l\
26\2Q 26140
Ion 152.00 (151.70 to 152.70): ENG
Ion 153.00 (152.70 to 153.70): ENG
26.32
J/\
26120 ' ' 26 Uo' ' ' ' '
Abundance
1000000 .
500000 .
Time--> 26.50 26.60 26.70 26.80 26.90
TIC: ENG1310.D
0
#6
Acenaphthylene
Concen: 5.35 ng/uL
RT: 26.32 min Scan# 2455
Delta R.T. -0.02 min
Lab File: ENG1310.D
Acq: 18 May 99 12:04 am
Tgt Ion:152 Regp: 2242559
Ion Ratio Lower Upper
100
7.6
152
153
0
0
14.7
0.0
0.0
0.0
0.0
22.6
0.0
0.0
Abundancelon 164.00 (163.70 to 164.TO) : ENG
600000J
400000 '.
200000:
26.71
rime--> 26.50 26.60 26.70 26.80 26.90
ENG1310.DPES.M
#7
Acenaphthene-dl0
Concen: 5.35 ng/uL
RT: 26.71 min Scant 2513
Delta R.T. -0.04 min
Lab File: ENG1310.D
Acq: 18 May 99 12:04 am
Tgt Ion:164 Resp: 1333374
Ion
164
0
0
0
Ratio
100
0.0
0.0
0.0
Lower Upper
0.0
0.0
0.0
0.0
0.0
0.0
Wed May 19 10:16:20 1999
HP 5989B
Page 5
-------
Abundance
1000000 .
500000.
rime-->
TIC: ENG1310.D
2680
2vo
iAbundancelon 154.00 (153.70 to 154.70):
Ion 153.00 (152.70 to 153.70):
26.79
600000 .
400000.
200000-
ENG
ENG
Time-->
2680
27o
Acenaphthene(CCC)
Concen: 5.45 ng/uL
RT: 26.79 min Scantf 2525
Delta R.T. -0.04 min
Lab File: ENG1310.D
Acq: 18 May 99 12:04 am
Tgt Ion:154 Resp: 1523875
Ion Ratio Lower Upper
154 100
153 92.7 43.5 130.3
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance
1500000j
1000000.
500000 .
rime-->
TIC: ENG1310.D
27!80
28.00
28.20
Abundanceion 176.00 (175.70 to 176.70): ENG
800000.4
600000.
400000 .
200000J
28.00
rime-->
27!80
28.00
28.20
ENG1310.DPES.M
#9
Fluorene-dIO
Concen: 5.48 ng/uL
RT: 28.00 min Scan# 2709
Delta R.T. 0.00 min
Lab File: ENG1310.D
Acq: 18 May 99 12:04 am
Tgt Ion:176 Resp: 1481983
Ion
176
0
0
0
Ratio
100
0.0
0.0
0.0
Lower Upper
0.0
0.0
0.0
0.0
0.0
0.0
000)250
Wed May IS 10:16:24 1999
HP 5989B
Page 6
-------
Abundance TIC: h^G1310.D
1500000 H
1000000 .
500000 -
0 -
ft
A 1
J \
Time--> 27180 28!00 28:20
Abundanceton 166.00 {165.70 to 166.70): ENG
-
500000 -
0 .
Time-->
Ion 165.00 (164.70 to 165.70): ENG
28.08
1
J \_
"— I 1 1 1 1 1 1 1 1 1 1 1 1 1 1 I" '
27 80 28.00 28.20
#10
Fluorene
Concen: 5.45 ng/uL
RT: 28.08 min Scan# 2720
Delta R.T. -0.05 min
Lab File: ENG1310.D
Acq: 18 May 99 12:04 am
Tgt Ion:166 Resp: 1777441
Ion Ratio Lower Upper
166 100
165 87.7 38.2 114.4
0 0.0 0.0 0.0
0 0.0 0.0 0.0
TIC: ENG1310.D
Time-->
! I i i ,
30.30
30.40
30.50
Abundanceton 188.00 (187.70 to 188.70): EMG
Ion 94.00 (93.70 to 94.70): ENG13
1000000-1 30.43
500000-
lime - - >
30.30
30.40
30)50
#11
Phenanthrene-dl0
Concen: 5.53 ng/uL
RT: 30.43 min Scan# 3078
Delta R.T. -0.04 min
Lab File: ENG1310.D
Acq: 18 May 99 12:04 am
Tgt Ion:188 Resp: 2317755
Ion
188
94
0
0
Ratio
100
28.6
0.0
0.0
Lower Upper
15.1
0.0
0.0
45.1
0.0
0.0
ENG1310.DPES.M
wed May 19
HP 5989B
Page 7
-------
TIC: ENG1310.D
Abundance Ion 1TSTOO (17T.70 to 178.70): ENG
Ion 176.00 (175.70 to 176.70): ENG
30.49
1000000 -
500000 .
Time-->
30.40
30.50
30.60
#12
Phenanthrene
Concen: 5.45 ng/uL
RT: 30.49 min Scan# 3087
Delta R.T. -0.06 min
Lab File: ENG1310.D
Acq: 18 May 99 12:04 am
Tgt Ion:178 Resp: 2771683
Ion Ratio Lower Upper
178 100
176 20.9 10.1 30.1
0 0.0 0.0 0.0
0 0.0 0.0 0.0
lime - - >
TIC: ENG1310.D
1000000 -
500000 .
30.40
30.60
30.80
Abundancelon 188.00 (187.70 to 188.70): ENG
Ion 94.00 (93.70 to 94.70): ENG13
1000000 -
500000 .
30.57
Time-->
30.40
30.60
30;80
ENG1310.DPES. M
#13
Anthracene-dlO
Concen: 5.45 ng/uL
RT: 30.57 min Scan# 3099
Delta R.T. -0.06 min
Lab File: ENG1310.D
Acq: 18 May 99 12:04 am
Tgt Ion:188 Resp: 1987643
Ion Ratio
188 100
94 34.2
0 0.0
0 0.0
Lower Upper
15.1
0.0
0.0
45.1
0.0
0.0
OCO252
Wed May 19 10:16:30
HP 5989B
Page 8
-------
Time-->
TIC: ENG1310.D
1000000 -
500000 .
-I 1 1 I 1 1 1 1 1 1 1 1 I 1 1 1 1 1~
30.50 30.60 30.70 30.80
Abundanceton 178.00 (177.70 to 178.70): ENG
Ion 17€.00 (175.70 to 176.70): ENG
1000000 -
500000 .
30.62
rime-->
30.50 30.60 30.70 30.80
Anthracene
Concen: 5.41 ng/uL
RT: 30.62 min Scan# 3107
Delta R.T. -0.07 min
Lab File: ENG1310.D
Acq: 18 May 99 12:04 am
Tgt Ion:178 Resp: 2655715
Ion Ratio
178 100
176 20.2
0 0.0
0 0.0
Lower Upper
10.1 30.1
0.0 0.0
0.0 0.0
1
ENG
Abundance
1500000 -
1000000.
500000 .
0 .
Time - - >
Abundance
800000:
600000-
400000 .
200000-
0
Time-->
TIC: ENG1310.D
ft/1
/ V
33U6 ' ' 33160 ' ' 33isO
Ion 212.00 (211.70 to 212.70): ENG
Ion 106.00 (105.70 to 106.70): ENG
33.57
A
K
33140 33160 33180
1310. D PES.M Wed May 19 10:16:34 1999
#15
Fluoranthene-dlO
Concen: 5.45 ng/uL
RT: 33.57 min Scan# 3625
Delta R.T. -0.04 min
Lab File: ENG1310.D
Acq: 18 May 99 12:04 am
Tgt Ion:212 Resp: 2262279
Ion Ratio
212 100
106 35.5
0 0.0
0 0.0
Lower Upper
15.1
0.0
0.0
45.1
0.0
0.0
HP 5989B
Page 9
-------
Abundance TIC: ENG1310.D
1500000 -
1000000 -
500000 -
0
Time--> ' 33140 ' ' 33.60 ' ' 33180
Abundancelon 202.00 (201.70 to 202.70): ENG
1000000 .
500000 .
0 .
Ion 101.00 (100.70 to 101.70): ENG
33.62
A
A '
i\
Time--> 33.40 33.60 33.80
Abundance TIC: ENG1310.D
1500000-
-
1000000 J
500000 .
n
A
1
/ \
/ \
j V.
Time--> 34!o6 34!20 34!40
Abundancelon 212.00 (211.70 to 212.70): ENG
500000 .
0 .
Ion 106.00 (105.70 to 106.70): ENG
34.25
A
i
n „
Time--> 34!oO 34!20 ' 34!40
#16
Flue
Lone
RT:
Delt
Lab
Acq
Tgt
Ion
202
101
n
0
#17
Pyr
Con
RT:
TiciT
LJG±
Lab
Acq
Tgt
Ion
212
106
o
0
Fluoranthene(CCC)
Concen: 5.50 ng/uL
RT: 33.62 min Scantf 3633
-0.01 min
ENG1310.D
Acq: 18 May 99 12:04 am
Tgt Ion:202 Resp: 3018048
Ratio Lower Upper
100
13.6
0.0
0.0
33 .8
0.0
0.0
40.6
0.0
0.0
Concen: 5.47 ng/uL
RT: 34.25 min Scan# 3726
R.T. -0.08 min
Lie: ENG1310.D
Acq: 18 May 99 12:04 am
Tgt Ion:212 Resp: 2491344
Ratio
100
39.9
0.0
0.0
Lower Upper
17.1
0.0
0.0
51.1
0.0
0.0
OCC 3254
ENG1310.DPES.M
Wea May
10:16:37 1999
HP 5989B
Page 10
-------
Abundance
1500000 -
1000000 '.
500000 '.
rime--> 34.00
TIC: ENG1310.D
34.20
34.40
Abundanceton 202.00 (201.70 to 202.70): ENG
1000000 .
500000 .
Ion 101.00 (100.70 to 101.70): ENG
34.30
Time--> 34.00
34.20
34.40
#18
Pyrene
Concen: 5.54 ng/uL
RT: 34.30 min Scan# 3734
Delta R.T. -0.08 min
Lab File: ENG1310.D
Acq: 18 May 99 12:04 am
Tgt lon:202 Resp: 3286165
Ion Ratio Lower Upper
202 100
101 38.8 16.1 48.1
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance
1500000 '.
1000000 .
500000 .
Time-->
TIC: ENG1310.D
34.40
34i60
34.80
Abundance!on 244.00 (243.70 to 244.70): ENG
Ion 122.00 (121.70 to 122.70): ENG
34.57
600000J
400000J
200000:
lime-->
34140
34.60
34.80
ENG1310.DPES. M
#19
p-Terphenyl-d!4
Concen: 5.44 ng/uL
RT: 34.57 min Scan# 3774
Delta R.T. -0.06 min
Lab File: ENG1310.D
Acq: 18 May 99 12:04 am
Tgt Ion:244 Resp: 1873909
Ion
244
122
0
0
Ratio
100
28.8
0.0
0.0
Lower Upper
13.6
0.0
0.0
40.€
0.0
0.0
OCC3255
Wed May 19 10:16:40 1999
HP 5989B
Page 11
-------
Abundance
800000 :
600000:
400000:
200000:
Time--> 38.70 38.80 38.90 39.00
TIC: ENG1310.D
0
Abundance Ion 240.00 (239770 to 240.70) : ENG
lion 120.00 (119.70 to 120.70): ENG
400000 .
200000 -
Time--> 38.70 38.80 38.90
39.00
Abundance
800000:
600000:
400000:
200000:
Time-->
TIC: ENG1310.D
~l 1 1 r-
38.80
39.00
39.20
#20
Benzo(a)anthracene-d!2
Concen: 5.94 ng/uL
RT: 38.87 min Scan# 4422
Delta R.T. -o.11 min
Lab File: ENG1310.D
Acq: 18 May 99 12:04 am
Tgt Ion:240 Resp: 1737418
Ion Ratio Lower Upper
240 100
120 32.7 15.1 45.1
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundancelon 228.00 (2Z7.70to 2213770}: ENG
•Ion 114.00 (113.70 to 114.70): ENG
600000J
400000:
200000:
rime-->
38:80
39:00
39:20
ENG1310.DPES. M
#21
Benzo(a)anthracene
Concen: 6.04 ng/uL
RT: 38.98 min Scan# 4438
Delta R.T. -0.07 min
Lab File: ENG1310.D
Acq: 18 May 99 12:04 am
Tgt Ion:228 Resp: 2578744
Ion
228
114
0
0
Ratio
100
28.6
0.0
0.0
Lower Upper
12.6
0.0
0.0
37.6
0.0
0.0
Wed May 19 10:16:44
HP 5989B
Page 12
-------
Abundance
600000 _
400000 -
i
200000 .
0 -
Time-->
Abundance
300000 J
200000 :
100000 :
0 -
Time-->
TIC: ENG1309.D
A
A 1
J \j \
26.60 26.70 26.80 26.90 27.00
Ion 154.00 (153.70 to 154.70): ENG
Ion 153.00 (152.70 to 153.70): ENG
26.79
-i — i — i — i — i — i — i — i — i — i — i — i — i — i — i — i — i — i — i — i — i — i — i — i i i
26 60 26 70 26180 26.90 27.00
Abundance
600000 :
400000 -
200000 -
0 .
Time-->
Abundance
300000 .
200000 .
100000 .
0
Time-->
TIC: ENG1309.D
1
f\J \
27 1 80 ' ' 27 ! 90 ' ' 28 1 00 ' ' 28 1 10 ' '
Ion 176.00 (175.70 to 176.70)-. ENG
28.00
27 1 80 ' ' 27 ! 90 ' ' 28 1 00 ' ' 28 1 10 ' ' '
#8
Acenaphthene(CCC)
Concen: 2.63 ng/uL
RT: 26.79 min Scan# 2523
Delta R.T. -0.04 min
Lab File: ENG1309.D
Acq: 17 May 99 10:48 pm
Tgt Ion:154 Resp: 743658
Ion Ratio Lower Upper
154 100
153 96.3 43.5 130.3
0 0.0 0.0 0.0
0 0.0 0.0 0.0
#9
Fluorene-dlO
Concen: 2.64 ng/uL
RT: 28.00 min Scan# 2707
Delta R.T. 0.00 min
Lab File: ENG1309.D
Acq: 17 May 99 10:48 pm
Tgt Ion:176 Resp: 724332
Ion
176
0
0
0
Ratio
100
0.0
0.0
0.0
Lower Upper
0.0
0.0
0.0
0.0
0.0
0.0
OCC3232
ENG1309.DPEb.M
wea May 19 iu:i3:io iyyy
HP 5989B
Page 6
-------
Abundance
eooooo:
400000:
200000:
Time-->
TIC: ENG1309.D
27.80
28.00
28.20
T
Abundancelon 166.00 (165.70 to 166.70)
Ion 165.00 (164.70 to 165.70)
28.07
400000J
300000:
200000 :
100000 :
o:
ENG
ENG
Time-->
27.80
1 1 1 r
28.00
1 1 1
28l20
SB"
rime-->
TIC: ENG1309.D
600000 :
400000:
200000:
30.30
30^40
30.50
#10
Fluorene
Concen: 2.63 ng/uL
RT: 28.07 min Scan# 2718
Delta R.T. -0.06 min
Lab File: ENG1309.D
Acq: 17 May 99 10:48 pm
Tgt Ion:166 Resp: 868765
Ion Ratio
166 100
165 87.2
0 0.0
0 0.0
Lower Upper
38.2
0.0
0.0
114.4
0.0
0.0
Abundancelon 188.00 (187.70 to 188.70): ENG
600000 J
400000 .
200000 .
Ion
94.00 (93.70 to 94.70)
30.43
ENG13
rime-->
30.30
30.40
30.50
ENG1309.D—PES.M
Wed May 19 10:13:13 1999
#11
Phenanthrene-dl0
Concen: 2.88 ng/uL
RT: 30.43 min Scan# 3076
Delta R.T. -0.04 min
Lab File: ENG1309.D
Acq: 17 May 99 10:48 pm
Tgt Ion:188 Resp: 1220981
Ion Ratio
188 100
94 27.3
0 0.0
0 0.0
Lower Upper
15.1
0.0
0.0
45 .1
0.0
0.0
OCC3233
HP 5989B
Page 7
-------
Abundance
800000 :
600000 :
TIC: ENG1310.D
39.00
39.20
Abundancelon 240.00 (239.70 to 240.70): ENG
Ion 120.00 (119.70 to 120.70): ENG
39.03
400000 .
200000.
rime-->
38.80
39.00
39120
#22
Chrysene-dl2
Concen: 5.87 ng/uL
RT: 39.03 min Scan# 4446
Delta R.T. -0.06 min
Lab File: ENG1310.D
Acq: 18 May 99 12:04 am
Tgt Ion:240 Resp: 2079850
Ion Ratio Lower Upper
240 100
120 29.9 15.1 45.1
0 0.0 0.0 0.0
0 0.0 0.0 0.0
[Abundance
800000J
eooooo:
400000:
200000:
Time-->
TIC: ENG1310.D
39.00
39.20
39.40
[Abundancelon 228.00 (227.70 to 228.70):
Ion 114.00 (113.70 to 114.70):
39.16
600000 J
400000 '.
200000 -
Time--> 39.00 39.20 39.40
ENGTJTDTD PES . M
ENG
ENG
Wed May 19 10:lt»:47 1999
#23
Chrysene(CCC)
Concen: 5.95 ng/uL
RT: 39.16 min Scant 4466
Delta R.T. -0.06 min
Lab File: ENG1310.D
Acq: 18 May 99 12:04 am
Tgt Ion:228 Resp: 2926481
Ion Ratio
228 100
114 27.3
0 0.0
0 0.0
Lower Upper
12.6 37.6
0.0 0.0
0.0 0.0
OCCKc'
7
HP 5989B
Page 13
-------
Abundance
600000 J
400000:
200000 -i
Time-->
TIC: ENG1310.D
45. 70 458o
46 00
AbundanceIon 264.00 (263.70 to 264.70)
Ion 132.00 (131.70 to 132.70)
300000 J
200000 J
100000 .
ENG
ENG
0 -
Time-->
45. 70' 45! 80 45190' 46 1 00
#24
Benzo(b)fIuoranthene-dl2
Concen: 5.79 ng/uL
RT: 45.87 min Scan# 5496
Delta R.T. -0.10 min
Lab File: ENG1310.D
Acq: 18 May 99 12:04 am
Tgt Ion:264 Resp: 1509750
Lower Upper
Ion
264
132
0
0
Ratio
100
31.6
0.0
0.0
15.1
0.0
0.0
45.1
0.0
0.0
Abundance
Time--> 45.80
TIC: ENG1310.D
46.00
46.20
Abundance Ion 252.00 (251.70 to 252 .70)
400000Jlon 126.00 (125.70 to 126.70)
ENG
ENG
46.07
300000J
200000 J
100000:
Time--> 45.80
46.00
46.20
ENG1310.DPES. M
#25
Benzo(b)fluoranthene
Concen: 5.94 ng/uL
RT: 46.07 min Scan# 5527
Delta R.T. -0.10 min
Lab File: ENG1310.D
Acq: 18 May 99 12:04 am
Tgt Ion:252 Resp: 2220049
Ion Ratio
252 100
126 28.4
0 0.0
0 0.0
Lower Upper
12.6 37.6
0.0 0.0
0.0 0.0
OCCJ253
Wed May
10:16:bU 1999
HP 5989B
Page 14
-------
(Abundance
600000:
400000:
200000:
TIC: ENG1310.D
Time-->
45:80
-1—I—I—I—
46.00
46.20
Abundanceton 264.00 (263.70 to 264.70): ENG
Ion 132.00 (131.70 to 132.70): ENG
300000 .
200000 .
100000 -
Time-->
46.07
45.80
46.00
46.20
#26
Benzo(k)fIuoranthene-dl2
Concen: 6.01 ng/uL
RT: 46.07 min Scan# 5528
Delta R.T. -0.10 min
Lab File: ENG1310.D
Acq: 18 May 99 12:04 am
Tgt Ion:264 Resp: 2078310
Ion Ratio Lower Upper
264 100
132 32.2 15.1 45.1
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance
600000 J
400000:
200000:
Time - - >
TIC: ENG1310.D
0
46.00
46.20
46.40
Abundance Ion 252.00 (251.70 to 252.70)
ENG
400000Jlon 126.00 (125.70 to 126.70): ENG
46.23
300000 J
200000:
looooo:
Time-->
46.00
46.20
46.40
ENGT3TOTD PES.M
#27
Benzo(k)fluoranthene
Concen: 6.04 ng/uL
RT: 46.23 min Scan# 5552
Delta R.T. -0.10 min
Lab File: ENG1310.D
Acq: 18 May 99 12:04 am
Tgt Ion:252 Resp: 2429284
Ion
252
126
0
0
Ratio
100
34.1
0.0
0.0
Lower Upper
12.6
0.0
0.0
37.6
0.0
0.0
npni«-».T/Q
Ul/io- J,-*-^jJ
wea May 19 I0:it:54
HP 5989B
Page 15
-------
Abundance
300000 :
200000.
100000:
Time-->
TIC: ENG1310.D
48.20 48'.40 48.60 48.80
1
Abundance Ion 264.00
200000H
150000.
100000.
50000.
(263.70 to 264.70)
Ion 132.00 (131.70 to 132.70)
48.54
ENCT
ENG
0.
Time-->
48.20 48.40 48.60 48.80
#28
Benzo(a)pyrene-d!2
Concen: 5.99 ng/uL
RT: 48.54 min Scan# 5906
Delta R.T. -0.12 min
Lab File: ENG1310.D
Acq: 18 May 99 12:04 am
Tgt Ion:264 Resp: 1397377
Ion Ratio
264 100
132 33.0
0 0.0
0 0.0
Lower Upper
15.1
0.0
0.0
45.1
0.0
0.0
Abundance
300000 .
200000:
100000:
rime--> 48.00
TIC: ENG1310TD
48.50
49.00
I
Abundance Ion 252.00 (251.70 to 252.70)
300000.
200000.
100000.
0.
lon 126.00 (125.70 to 126.70)
48.74
ENG
ENG
Time--> 48.00
48.50
49.00
ENG1J10.D PES.M
Wed May 19 10:16:58
#29
Benzo(a)pyrene(CCC)
Concen: 6.25 ng/uL
RT: 48.74 min Scantf 5937
Delta R.T. -0.13 min
Lab File: ENG1310.D
Acq: 18 May 99 12:04 am
Tgt Ion:252 Resp: 2199024
Ion
252
126
0
0
Ratio
100
30.0
0.0
0.0
Lower Upper
12.6
0.0
0.0
37.6
0.0
0.0
HP 5989B
Page 16
-------
lAbundance
400000 j
300000 .
200000:
100000:
TIC: ENG1310.D
Titne-->
Abundancelon 288.00 (287.70 to 288.70): ENG
0
61.00
61.50
62!00
100000 -
50000
0 .
61.48
Time-->
61.00
61.50
62.00
#30
Indenod, 2, 3-cd)pyrene-dl2
Concen: 5.50 ng/uL m
RT: 61.48 min Scan# 8107
Delta R.T. -0.18 min
Lab File: ENG1310.D
Acq: 18 May 99 12:04 am
Tgt Ion:288 Resp: 1723736
Ion Ratio Lower Upper
288 100
0
0
0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
Abundance
400000 j
Time--> 61.00
TIC: ENG1310.D
6l!50
62 00
62.50
Abundance Ion 276.05
Ion 138.00
150000 '.
100000 '.
50000J
Time--> 61.00 61.50
(275.75 to
(137.70 to
61.83
276.75)
138.70)
1NQ-
ENG
62.00
62.50
#31
Indeno(1,2,3 -cd)pyrene
Concen: 5.64 ng/uL
RT: 61.83 min Scantf 8172
Delta R.T. -0.17 min
Lab File: ENG1310.D
Acq: 18 May 99 12:04 am
Tgt Ion:276.05 Resp: 2112387
Ion
276
138
0
0
Ratio
100
38.3
0.0
0.0
Lower Upper
32 .1
0.0
0.0
96.1
0.0
0.0
00032-5:
ENG1310.DPES.M
wea May 19
HP 5989B
Page 17
-------
Abundance
400000 -i
300000 J
200000:
100000:
Time-->
TIC: ENG1310.D
61.00
61.50
62.00
Abundancelon 292.00 (291.70 to 252.70): ENG
60000 J
40000:
20000:
o:
61.44
rime-->
61.00
61.50
62.00
#32
Dibenz(a,h)anthracene-d!4
Concen: 5.35 ng/uL in
RT: 61.44 min Scan# 8099
Delta R.T. -0.16 min
Lab File: ENG1310.D
Acq: 18 May 99 12:04 am
Tgt Ion:292 Resp: 989890
Ion Ratio Lower Upper
292 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance
400000 j
300000:
200000:
100000:
Time-->61.00
TIC: ENG1310.D
61.50
62.00
62.50
Abundancelon 278.00 (277.70 to 278.70): EtfG
150000-
100000-
50000.
0 .
Ion 139.00 (138.70 to 139.70): ENG
61.85
rime-->61.00
61.50
62.00
62:50
ENG1310.DPES. M
#33
Dibenz(a,h)anthracene
Concen: 5.67 ng/uL
RT: 61.85 min Scan# 8176
Delta R.T. -0.18 min
Lab File: ENG1310.D
Acq: 18 May 99 12:04 am
Tgt Ion:278 Resp: 1733759
Ion
278
139
0
0
Ratio
100
24.9
0.0
0.0
Lower Upper
12.6
0.0
0.0
37.6
0.0
0.0
OCCJ262
Wed May 19 10:17:0b 1999
HP 5989B
Page 18
-------
Abundance
150000 .
100000 J
50000:
rime-->
TIC: ENG1310.D
-i 1 1 1 1 i 1 1 1 1 1 1 1 1 1—
64.50 65.00 65.50
Abundancelon 288.00 (287.70 to 288.70)
100000 .
50000 -
0 .
Time - - >
i—i—i
64.50
esoo
n 1 1 1 1 r
65.50
#34
Benzo(g,h,i)perylene-d!2
Concen: 5.59 ng/uL
RT: 65.06 min Scan# 8836
Delta R.T. -0.21 min
Lab File: ENG1310.D
Acq: 18 May 99 12:04 am
Tgt Ion:288 Resp: 1403802
Ion Ratio
288 100
0 0.0
0 0.0
0 0.0
Lower Upper
0.0
0.0
0.0
0.0
0.0
0.0
TIC: ENG1310.D
rime-->
65.00
65.50
66.00
Abundancelon 276.00 (275.70 to 276.70)
ENG
150000 -I
100000 .
50000 -
0 .
Ion 138.00 (137.70 to 138.70): ENG
65.44
[Time-->
ENG1310.DPES. M
65.00
65.50
66.00
#35
Benzo(g,h,i)perylene
Concen: 5.55 ng/uL
RT: 65.44 min Scan# 8928
Delta R.T. -0.20 min
Lab File: ENG1310.D
Acq: 18 May 99 12:04 am
Tgt Ion:276 Resp: 1817794
Ion
276
138
0
0
Ratio
100
16.2
0.0
0.0
Lower Upper
10.1
0.0
0.0
30.1
0.0
0.0
OCC-3263
Weo. May 19 10:17:09 1999
HP 5989B
Page 19
-------
Quantitation Report
Data File
Acg On
Sample
Misc
C:\HPCHEM\1\DATA\9919\ENG1311.D
18 May 99 1:19 am
PES-MAH-051299-06 7 ng/piL
Quant Time: May 19 9:42 1999
Vial: 5
Operator: JEMcCartney
Inst -. HP 5989B
Multiplr: 1.00
Method
Title
Last Update
Response via
C:\HPCHEM\1\METHODS\PES.M
Wed May 19 09:55:02 1999
Multiple Level Calibration
Internal Standards
1)
2 , 2 -Dif luorobiphenyl
R
24
.T.
.58
Qlon
190
Response
1252038
Cone Units Dev(Min)
5
.00
System Monitoring Compounds
2)
4)
5)
7)
9)
11)
13)
15)
17)
19)
20)
22)
24)
26)
28)
30)
32)
34)
Naphthalene-d8
2 -Methlynaphthalene-dlO
Acenaphthylene-d8
Acenaphthene-dlO
Fluorene-dlO
Phenant hr ene - dl 0
Anthracene -dlO
Fluoranthene-dlO
Pyrene -dlO
p-Terphenyl-d!4
Benzo (a) anthracene-d!2
Chrysene-dl2
Benzo (b) fluoranthene-d!2
Benzo (k) fluoranthene-dl2
Benzo (a) pyrene-d!2
Indenod, 2, 3-cd)pyrene-dl2
Dibenz (a,h) anthracene-d!4
Benzo (g,h, i)perylene-d!2
22
23
26
26
28
30
30
33
34
34
38
39
45
46
48
61
61
65
.23
.96
.29
.71
.00
.43
.57
.57
.25
.57
.87
.04
.87
.08
.54
.51
.46
.07
136
152
160
164
176
188
188
212
212
244
240
240
264
264
264
288
292
288
2838973
1558122
3199203
2048684
2255875
3408533
2878606
3096975
3406045
2593178
2461735
2775565
2205243
2838622
2054355
2750331
1556733
2156111
7
7
7
7
7
7
7
6
6
7
7
7
7
7
8
8
7
8
.43
.70
.95
.68
.79
.60
.38
.97
.98
.03
.87
.32
.90
.67
.22
.10
.81
.02
ng/uL
0.00
%Recovery
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
Target Compounds
3)
6)
8)
10)
12)
14)
16)
18)
21)
23)
25)
27)
29)
31)
33)
35)
Naphthalene (CCC)
Acenaphthylene
Acenaphthene (CCC)
Fluorene
Phenanthrene
Anthracene
Fluoranthene (CCC)
Pyrene
Benzo (a) anthracene
Chrysene(CCC)
Benzo (b) f luoranthene
Benzo (k) f luoranthene
Benzo (a) pyrene (CCC)
Indeno ( 1 , 2 , 3 - cd) pyrene
Dibenz (a, h) anthracene
Benzo (g,h, i)perylene
22
26
26
28
30
30
33
34
38
39
46
46
48
61
61
65
.28
.32
.79
.08
.49
.62
.62
.30
.98
.16
.07
.24
.75
.86
.87
.47
128
152
154
166
178
178
202
202
228
228
252
252
252
276
278
276
3256746
3539103
2234218
2706051
4095917
3882147
4127259
4469319
3464591
3940503
3123629
3339029
3214938
3261076
2634146
2778637
7
7
7
7
7
7
7
7
7
7
7
7
8
8
8
7
.34
.89
.46
.75
.53
.39
.03
.04
.58
.48
.81
.76
.53
.14
.04
.93
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
m
Qvalue
89
100
87
86
97
99
84
86
92
95
93
82
89
67
100
83
OCC326*
(#) = qualifier out of range (m) = manual integration
ENG1311.D PES.M Wed May 19 10:17:50 1999 HP 5989B
Page l
-------
Quantitation Report
C:\HPCHEM\1\DATA\9919\ENG1311.D
18 May 99 1:19 am
PES-MAH-051299-06 7 ng//zL
Data File
Acq On
Sample
Misc
Quant Time: May 19 9:42 1999
Method
Title
Last Update
Response via
C:\HPCHEM\1\METHODS\PES.M
Wed May 19 09:55:02 1999
Multiple Level Calibration
Vial: 5
Operator: JEMcCartney
Inst : HP 5989B
Multiplr: 1.00
Abundance
2600000:
2400000.
•
2200000-
•
2000000 :
•
isooooo :
.
isooooo:
1400000 :
1200000 -
1000000 -
800000 -
600000 -
400000 -
200000 -
3
2S
4
Time--> 20.00
q
*
14
631
5
•
9
3
°11
i:
5
S
S
TIC: ENG1311.D
16,
IE
3o!od
:
s
>s
21
2,3 2ffis
2^
2C
S -3
£
2'
7
31
29
s 1
3ag 35
11 IT
4o!oo ' ' soloo ' ' eolod
ENG1311.D PES.M
Wed May 19 10:18:01 1999
HP 5989B
Page 2
-------
Abundance
1500000 -
1000000 -
500000 -
0 "
Time-->
Abundance
1000000 -
500000 -
0 '
rime-->
TIC: ENG1311.D
y
/ \
22!o6 ' ' 22120 ' ' 22140
ion 136.00 (135.70 to 136.70): ENG
Ion 68.00 (67.70 to 68.70): ENG13
22.23
ft
1
1 "T- 1 1 1 1 1 1 1 1 1 1 1 | 1 1
22.00 22 20 22:40
#2
Naphthalene-d8
Concen: 7.43 ng/uL
RT: 22.23 min Scantf 1566
Delta R.T. -0.00 min
Lab File: ENG1311.D
Acq: 18 May 99 1:19 am
Tgt Ion:136 Resp: 2838973
Ion Ratio
136 100
68 19.0
0 0.0
0 0.0
Lower Upper
10.1 30.1
0.0 0.0
0.0 0.0
ENG
Abundance
1500000-
1000000-
500000-
0
Time--> 2
Abundance
1500000.
1000000.
500000.
0
Time - - > 2
TIC: ENG1311.D " -
jy
/ \
2.00 22.20 22.40
ion 128.00 (127.70 to 128.70): ENG
Ion 127.00 (126.70 to 127.70): ENG
22.28
A
j
11
2lo6 22 20 22140
Ull.D PES.M Wed May 19 10:18:06 199"9"
#3
Naphthalene(CCC)
Concen: 7.34 ng/uL
RT: 22.28 min Scant 1574
Delta R.T. -0.00 min
Lab File: ENG1311.D
Acq: 18 May 99 1:19 am
Tgt Ion:128 Resp: 3256746
Ion Ratio Lower Upper
128 100
127 14.1 0.0 60.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
HP 5989B
Page 3
-------
Abundance
600000 '.
400000 -
200000 -
0.
Time-->
Abundance
800000.
600000-
400000-
200000 -
0
rime-->
TIC: ENG1311.D
A
1 1
' / \
1 \
J V
23.80 23 90 24.00 24.10
Ion 152.00 (lSl.70 to 152.70): ENG
23.96
A
/ \
J ^
' — i 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 r
23.80 23.90 24.00 24.10
#4
2-M<
Con<
RT:
T"\^T
JJS1
Lab
Acq
Tgt
Ion
152
0
0
0
2-Methlynaphthalene-dl0
Concen: 7.70 ng/uL
23.96 min Scan# 1927
.a R.T. -0.00 min
File: ENG1311.D
Acq: 18 May 99 1:19 am
Tgt Ion:152 Resp: 1558122
Ratio Lower Upper
100
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
Abundance
1500000 :
1000000 :
sooooo :
0
Time-->
Abundance
1500000 .
1000000-
500000-
0
Time - - >
TIC: ENG1311.D
j \
26loO ' ' 26l20 ' ' 26140 '
Ion 160.00 (159.70 to 160.70) : ENG
26.29
rt
j^
26lo6 ' ' 26120 ' ' 26140 '
Acenaphthylene-d8
Concen: 7.95 ng/uL
RT: 26.29 min Scan# 2450
Delta R.T. 0.00 min
Lab File: ENG1311.D
Acq: 18 May 99 1:19 am
Tgt Ion:160 Resp: 3199203
Ion
160
0
0
0
Ratio
100
0.0
0.0
0.0
Lower Upper
0.0
0.0
0.0
0.0
0.0
0.0
OCO267
ENG1311.DPES.M
wea way 19 I0:io:io 1999
HP 5989B
Page 4
-------
Abundance
1500000 J
•
1000000 :
sooooo :
o
TIC: ENG1311.D
A
\
\
J
ritne-->26.00 26.20
\
V
26140 ' ' ' ' '
Abundance ton 152.00 (151.70 to lb2.YU): ENG
.
-
1500000 :
1000000 :
sooooo :
0 .
Ion 153.00 (152.70 to 153.70): ENG
26.32
A
J/^
"i — i — i — i — i — i — i — i — 1~
Time-->26.00 26.20
i
— i 1 1 1 1 i 1 r
26 40
#6
Acei
Cone
RT:
Dell
^XG -t
Lab
Acq
Tgt
Ion
152
153
0
0
Acenaphthylene
Concen: 7.89 ng/uL
26.32 min Scan# 2455
a R.T. 0.00 min
File: ENG1311.D
Acq: 18 May 99 1:19 am
Tgt Ion:152 Resp: 3539103
Ratio Lower Upper
100
7.6
0.0
0.0
14.9
0.0
0.0
22.6
0.0
0.0
Abundance
1500000.
1000000 :
sooooo:
0
rime-->
Abundance
1000000.
500000 .
0
Time - - >
TIC: BNG1311.D
yv\
'26160 ' ' 26 ISO
Ion 164.00 (163.70 to 164.70): ENG
26.71
j\
26 !60 ' ' 26180
ENG1311.DPES.M
#7
Acenaphthene-dl0
Concen: 7.68 ng/uL
RT: 26.71 min Scan# 2513
Delta R.T. -0.00 min
Lab File: ENG1311.D
Acq: 18 May 99 1:19 am
Tgt Ion:164 Resp: 2048684
Ion
164
0
0
0
Ratio
100
0.0
0.0
0.0
Lower Upper
0.0
0.0
0.0
0.0
0.0
0.0
OCC)2i3
Wed May 19 10:18:13 1999
HP 5989B
Page 5
-------
(Abundance
1500000:
1000000:
500000 -
TIC: ENG1311.D
26.60
26.80
27!00
Abundance I on 154.00 (153.70 to 154.70): ENG
Ion 153.00 (152.70 to 153.70): ENG
1000000J 26.79
500000 -
Time-->
26.60
26.80
27.00
#8
Acenaphthene(CCC)
Concen: 7.46 ng/uL
RT: 26.79 min Scan# 2525
Delta R.T. -0.00 min
Lab File: ENG1311.D
Acq: 18 May 99 1:19 am
Tgt Ion:154 Resp: 2234218
Ion Ratio Lower Upper
154 100
153 98.8 43.5 130.3
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance
2000000 :
1500000 :
1000000 :
sooooo :
o
Time- ->
TIC: ENG1311.D
A
/ 1
i
A I 1
A /
/ \ \
/ \
_J V
'27180' '21\9Q 28160' 28lio' '2B\20
Abundancelon 176.00 (175.70 to 176.70): ENG
1000000 .
500000 .
0
Time-->
28.00
A
1
J v_
27180' 27190' 28loo' ^islio' '28120'
#9
Flu
C U. LA.
Con
RT:
Del
Lab
Acq
Tgt
Ion
176
0
0
0
ENGl.ill.D PEb.M Wed May 19 10: IB: 17 1999
Concen: 7.79 ng/uL
28.00 min Scantf 2709
a R.T. -0.00 min
File: ENG1311.D
Acq: 18 May 99 1:19 am
Tgt Ion:176 Resp: 2255875
Ratio
100
0.0
0.0
0.0
Lower Upper
0.0
0.0
0.0
0.0
0.0
0.0
OCC32-C9
HP 5989B
Page 6
-------
Abundance
2000000 :
isooooo:
1000000 :
500000 :
0
rime-->
Abundance
1000000 -
500000.
0 ."
Time - - >
TIC: ENG1311.D
A
/M
27!80 ' ' 28100 ' ' 28120 '
Ion 166.00 (165.70 to 166.70): ENG
Ion 165.00 (164.70 to 165.70): ENG
28.08
|
]{
27\3Q ' 28lob '28120' ' ' '
#10
Fluorene
Concen: 7.75 ng/uL
RT: 28.08 min Scan# 2720
Delta R.T. 0.00 min
Lab File: ENG1311.D
Acq: 18 May 99 1:19 am
Tgt Ion:166 Resp: 2706051
Ion Ratio Lower Upper
166 100
165 88.0 38.2 114.4
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance
2000000 :
1500000:
1000000 .
500000:
Time-->
TIC: ENG1311.D
30.30
30.40
30.50
Abundance Ion 188.00 (187.70 to 188.70): ENG
Ion 94.00 (93.70 to 94.70): ENG13
1500000 -
1000000 J
500000-
0
30.43
Time-->
30.30
30:40
30:50
ENG1311.DPBS.M
#11
Phenanthrene-dl0
Concen: 7.60 ng/uL
RT: 30.43 min Scan# 3078
Delta R.T. -0.00 min
Lab File: ENG1311.D
Acq: 18 May 99 1:19 am
Tgt Ion:188 Resp: 3408533
Ion
188
94
0
0
Ratio
100
29.7
0.0
0.0
Lower Upper
15.1
0.0
0.0
45.1
0.0
0.0
OCOSI-O
Wed May 19 10:18:21 1999
HP 5989B
Page 7
-------
i&buridance
2000000 -
1500000:
1000000-
500000:
TIC: ENG1311.D
0
rime-->
30.40
30.50
30.60
Abundance I on 178.00 (177.70 to 178.70): ENG
2000000:
1500000 -
1000000 -
500000-
lon 176.00 (175.70 to 176.70): ENG
30.49
prime - - >
30.40
30.50
30.60
#12
Phenanthrene
Concen: 7.53 ng/uL
RT: 30.49 min Scan# 3087
Delta R.T. -0.00 min
Lab File: ENG1311.D
Acq: 18 May 99 1:19 am
Tgt Ion:178 Resp: 4095917
Ion Ratio Lower Upper
178 100
176 21.3 10.1 30.1
0 0.0 0.0 0.0
0 0.0 0.0 0.0
pUDunaance
2000000 .
1500000 J
1000000-
500000 -
TIC: ENG1311.D
Time-->
30.40
30.60
30.80
Abundancelon 188.00 (187.70 to 188.70): ENG
Ion 94.00 (93.70 to 94.70): ENG13
1500000J
30.57
1000000J
500000.
Time-->
ENG1311.D—PES.M
Wed May 19 10:18:24
#13
Anthracene-dlO
Concen: 7.38 ng/uL
RT: 30.57 min Scan# 3100
Delta R.T. 0.00 min
Lab File: ENG1311.D
Acq: 18 May 99 1:19 am
Tgt Ion:188 Resp: 2878606
Ion
188
94
0
0
Ratio
100
36.2
0.0
0.0
Lower Upper
15.1
0.0
0.0
45.1
0.0
0.0
OCC32'?i
HP 5989B
Page 8
-------
Abundance
2000000 :
1500000:
1000000:
500000:
Time-->
TIC: ENG1311.D
0
30.50
30.60
30.70
Abundance I on 178TOO (177.70 to 178.70)
Ion 176.00 (175.70 to 176.70)
30.62
2000000 :
1500000:
1000000:
500000:
ENG
ENG
Time-->
30.50
30.60
30.70
Anthracene
Concen: 7.39 ng/uL
RT: 30.62 min Scan# 3107
Delta R.T. -0.00 min
Lab File: ENG1311.D
Acq: 18 May 99 1:19 am
Tgt Ion:178 Resp: 3882147
Ion Ratio Lower Upper
178 100
176 20.6 10.1 30.1
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance TIC: ENG1311.D
2000000 :
1500000 :
1000000 :
500000 :
0 "
Time--> ' ' 33U6 ' ' 33!e6 ' ' 33!sO
Abundancelon 212.00 (211.70 to 212.70): ENG
1000000 -
500000 .
0.
Ion 106.00 (105.70 to 106.70): ENG
33.57
1
Time--> ' ' 33140 ' ' 33160 ' ' 33ls6
ENGuii.D PES.M wed May iy 10:18:28 iyyy
#15
Fluoranthene-dl0
Concen: 6.97 ng/uL
RT: 33.57 min Scan# 3625
Delta R.T. 0.00 min
Lab File: ENG1311.D
Acq: 18 May 99 1:19 am
Tgt Ion:212 Resp: 3096975
Ion Ratio
212 100
106 37.0
0 0.0
0 0.0
Lower Upper
15.1
0.0
0.0
45.1
0.0
0.0
HP 5989B
Page 9
-------
Abundance
2000000 :
1500000-
1000000 :
500000-
0 .
rime-->
Abundance
1500000 :
1000000 -
500000-
0
Titne-->
TIC: ENG1311.D
l
/ {
' 33140 ' is! 60 ' 33! 80 ' ' '
Ion 202.00 (201.70 to 202.70): ENG
Ion 101.00 (100.70 to 101.70): ENG
33.62
A
f.
Ji
33140 33160 33!80 '
#lb
Flu(
Con<
RT:
Del
Lab
Acq
Tgt
Ion
202
101
0
0
Fluoranthene(CCC)
Concen: 7.03 ng/uL
33.62 min Scan# 3633
.a R.T. 0.00 min
File: ENG1311.D
Acq: 18 May 99 1:19 am
Tgt Ion:202 Resp: 4127259
Ratio
100
35.1
0.0
0.0
Lower Upper
13.6 40.6
0.0 0.0
0.0 0.0
Abundance
2000000 :
.
1500000 :
•
1000000 :
.
sooooo :
-
o
TIC: ENG1311.D
A
/ \
/ \
/ V
J v
rime--> 34! 00 34120 34140
Abundancelon 212.00 (211.70 to 212.70): ENG
1000000 -
500000 .
0 "
Time-->
Ion 106.00 (105.70 to 106.70): ENG
34.25
A
A
11
34! 00 34120 ' ' 34140 '
#17
Pvr
ey i
Con
RT:
Del
Lab
Acq
Tgt
Ion
212
106
o
0
ENGlJil.D PES.M Wed May 19 10:1S:32 1999
Concen: 6.98 ng/uL
34.25 min Scan# 3726
,a R.T. 0 .00 min
File: ENG1311.D
Acq: 18 May 99 1:19 am
Tgt Ion:212 Resp: 3406045
Ratio
100
41.6
0.0
0.0
Lower Upper
17.1
0.0
0.0
51.1
0.0
0.0
OCO273
HP 5989B
Page 10
-------
Abundance
2000000 :
1500000:
1000000.
500000:
Time--> 34.00
TIC: ENG1311.D
34:20
34.40
Abundance Ion 202.00 (201.70 to 202.70): ENG
Ion 101.00 (100.70 to 101.70): ENG
34.30
1500000J
1000000 J
500000:
rime--> 34.00
34.20
34.40
#18
Pyrene
Concen: 7.04 ng/uL
RT: 34.30 min Scan# 3734
Delta R.T. 0.00 min
Lab File: ENG1311.D
Acq: 18 May 99 1:19 am
Tgt Ion:202 Resp: 4469319
Ion Ratio Lower Upper
202 100
101 40.1 16.1 48.1
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance
2000000 :
1500000 :
1000000 :
500000 :
o :
rime-->
Abundance
1000000 .
500000 .
0
Time-->
TIC: ENG1311.D
\j \
\ A
v i V
34i40 ' ' 34!60 ' ' 34180
Ion 244.00 (243.70 to 244.70): ENG
Ion 122.00 (121.70 to 122.70): ENG
34.57
fl
34140 34!e6 34180
ENG1311.DPES.M
#19
p-Terphenyl-d!4
Concen: 7.03 ng/uL
RT: 34.57 min Scan# 3774
Delta R.T. 0.00 min
Lab File: ENG1311.D
Acq: 18 May 99 1:19 am
Tgt Ion:244 Resp: 2593178
Ion
244
122
0
0
Ratio
100
29.2
0.0
0.0
Lower Upper
13.6
0.0
0.0
40.6
0.0
0.0
OCC3
Wed May 19 10:18:36 1999
HP 5989B
Page 11
-------
AEundance
1000000 .
Time--> 38.70 38.80 38.90 39.00
TIC: ENG1311.D
500000 -
Abundancelon 240.00 (239.70 to 240.70): ENG
Ion 120.00 (119.70 to 120.70): ENG
6000004
400000 .
200000 -
Time-->
#20
Benzo(a)anthracene-d!2
Concen: 7.87 ng/uL
RT: 38.87 min Scan# 4422
Delta R.T. -0.00 min
Lab File: ENG1311.D
Acq: 18 May 99 1:19 am
Tgt Ion:240 Resp: 2461735
Ion Ratio Lower Upper
240 100
120 32.5 15.1 45.1
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance
1000000.
Time-->
TIC: ENG1311.D
500000 -
38.80
39.00
39.20
Abundancelon 228.00 (227.70 to 228.70): ENG
"Ion 114.00 (113.70 to 114.70): ENG
500000.
Time-->
38.80
39100
39.20
ENG1311.DPES.M
Wed May 19 10:18:39 1999
#21
Benzo(a)anthracene
Concen: 7.58 ng/uL
RT: 38.98 min Scan# 4439
Delta R.T. 0.01 min
Lab File: ENG1311.D
Acq: 18 May 99 1:19 am
Tgt Ion:228 Resp: 3464591
Ion
228
114
0
0
Ratio
100
29.1
0.0
0.0
Lower Upper
12.6
0.0
0.0
37.6
0.0
0.0
OCO275
HP 5989B
Page 12
-------
Abundance
1000000 .
rime--> 38.80
TIC: ENG1311.D
50000.0 -
39.00
39.20
Abundance Ion 240.00 (239.70 to 240.70)
Ion 120.00 (119.70 to 120.70)
EW
ENG
600000 J
400000 J
200000 .
Time-->
39.04
38.80
39.00
39.20
#22
Chrysene-dl2
Concen: 7.32 ng/uL
RT: 39.04 min Scan# 4447
Delta R.T. 0.01 min
Lab File: ENG1311.D
Acq: 18 May 99 1:19 am
Tgt Ion:240 Resp: 2775565
Ion Ratio Lower Upper
240 100
120 30.0 15.1 45.1
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance
1000000 .
Time-->
TIC: EHG1311.D
500000 .
39.00
39.20
39.40
Abundance Ion 228.00 (227.70 to 228.70): ENG
•LOUaiJUO "Ion 114.00 (113.70 to 114.70): ENG
39.16
500000 -
39:00
39:20
39!40
ENG1311.DPES.M
#23
Chrysene(CCC)
Concen: 7.48 ng/uL
RT: 39.16 min Scan# 4466
Delta R.T. 0.00 min
Lab File: ENG1311.D
Acq: 18 May 99 1:19 am
Tgt Ion:228 Resp: 3940503
Ion Ratio Lower Upper
228 100
114 27.7 12.6 37.6
0 0.0 0.0 0.0
0 0.0 0.0 0.0
OC03S75
Wed May 19 10:18:43 1999
HP 5989B
Page 13
-------
^Abundance
1000000 -
Time-->
TIC: ENG1311.D
500000.
45.80
46.00
Abundance Ion 264.00 (263.70 to264.70): ENG
jlon 132.00 (131.70 to 132.70): ENG
400000-
200000 .
Time-->
45.80
46.00
#24
Benzo(b)fluoranthene-d!2
Concen: 7.90 ng/uL
RT: 45.87 tnin Scan# 5497
Delta R.T. 0.01 min
Lab File: ENG1311.D
Acq: 18 May 99 1:19 am
Tgt Ion:264 Resp: 2205243
Ion Ratio Lower Upper
264 100
132 31.5 15.1 45.1
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance
1000000 .
Time-->
TIC: ENG1311.D
500000 .
0
45.80
46.00
46.20
Abundance Ion 252.00 (251.70 toZ52.70) :
126.00 (125.70 to 126.70): ENG
46.07
400000 .
200000 .
lime-->
45.80
46.00
46.20
ENGl311.DPES.M
wed. May iy 10:18:47 1999
#25
Benzo(b)fluoranthene
Concen: 7.81 ng/uL
RT: 46.07 min Scan# 5528
Delta R.T. 0.01 min
Lab File: ENG1311.D
Acq: 18 May 99 1:19 am
Tgt Ion:252 Resp: 3123629
Ion Ratio
252 100
126 28.7
0 0.0
0 0.0
Lower Upper
12.6 37.6
0.0 0.0
0.0 0.0
Y"?'
-j.'« i
HP 5989B
Page 14
-------
Abundance
1000000 -
Time--> 45.80
TIC: ENG1311.D
500000 .
46.00
46.20
Abundance Ion 264.00 (263.70 to 264.70): ENG
Ion 132.00 (131.70 to 132.70): ENG
46.08
400000 J
200000 .
rime--> 45.80
46.00
46.20
#26
Benzo(k)fIuoranthene-dl2
Concen: 7.67 ng/uL
RT: 46.08 min Scan# 5529
Delta R.T. 0.01 min
Lab File: ENG1311.D
Acq: 18 May 99 1:19 am
Tgt Ion:264 Resp: 2838622
Ion Ratio Lower Upper
264 100
132 32.2 15.1 45.1
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance
1000000 -
Time-->
TIC: ENG1311.D
500000 -
46!00
46120
46.40
Abundancelon 252.00 (251.70 to 252770)
Ion 126.00 (125.70 to 126.70)
46.24
400000 J ^
200000 .
ENG
ENG
Time-->
46.00
46120
46.40
ENG1311.DPES.M
#27
Benzo(k)fluoranthene
Concen: 7.76 ng/uL
RT: 46.24 min Scan# 5554
Delta R.T. 0.01 min
Lab File: ENG1311.D
Acq: 18 May 99 1:19 am
Tgt Ion:252 Resp: 3339029
Ion
252
126
0
0
Ratio
100
33.9
0.0
0.0
Lower Upper
12.6
0.0
0.0
37.6
0.0
0.0
OCC5273
Wed May 19 10:18:50 1999
HP 5989B
Page 15
-------
(Abundance
400000 -
200000 -
TIC: ENG1311.D
ritne-->
48.20 48.40 48.60 48.80
Abundance Ion 264.00 (263.70 to 264.70): ENG
Ion 132.00 (131.70 to 132.70): ENG
48.54
200000 -
rime--> 48.20 48.40 48.60 48.80
#28
Benzo(a)pyrene-dl2
Concen: 8.22 ng/uL
RT: 48.54 min Scan# 5906
Delta R.T. 0.00 min
Lab File: ENG1311.D
Acq: 18 May 99 1:19 am
Tgt Ion:264 Resp: 2054355
Ion Ratio
264 100
132 33.3
0 0.0
0 0.0
Lower Upper
15.1
0.0
0.0
45.1
0.0
0.0
Abundance
400000 -
200000 -
rime--> 48.00
TIC: ENG1311.D
48.50
49.00
(Abundance I on 252.00 (251.70 to 252 .70)
Ion 126.00 (125.70 to 126.70)
400000 :
300000:
200000:
100000:
o:
ENG
ENG
48.75
Time--> 48.00
48.50
49.00
ENG1311.DPES. M
Wed May 19 10:18:54 1999
#29
Benzo(a)pyrene(CCC)
Concen: 8.53 ng/uL
RT: 48.75 min Scan# 5938
Delta R.T. 0.01 min
Lab File: ENG1311.D
Acq: 18 May 99 1:19 am
Tgt Ion:252 Resp: 3214938
Ion
252
126
0
0
Ratio
100
30.6
0.0
0.0
Lower Upper
12.6
0.0
0.0
37.6
0.0
0.0
OCCJ279
HP S989B
Page 1€
-------
Abundance
600000 J
400000.
200000 -
Time-->
TIC: ENG1311.D
61.00
61.50
62100
Abundancelon 288.00 (287.70 to 288.70): ENG
200000J
150000 :
100000:
50000:
o:
61.51
Time-->
61.00
61.50
62100
Abundance
600000 J
400000 .
200000 .
Time-->
TIC: ENG1311.D
6l!00 61.50 62:00 62.50
Abundancelon 276.05 (27S.75 to 276.7$)
Ion 138.00 (137.70 to 138.70)
61.86
200000 .
100000 -
#30
Indeno(1,2,3-cd)pyrene-d!2
Concen: 8.10 ng/uL m
RT: 61.51 min Scan# 8113
Delta R.T. 0.03 min
Lab File: ENG1311.D
Acq: 18 May 99 1:19 am
Tgt Ion:288 Resp: 2750331
Ion Ratio
288 100
0 0.0
0 0.0
0 0.0
Lower Upper
0.0
0.0
0.0
0.0
0.0
0.0
ENG
Time-->
61.00 61.50 62.00 62.50
ENG1311.DPES .M
#31
Indeno(1,2,3-cd)pyrene
Concen: 8.14 ng/uL
RT: 61.86 min Scan# 8177
Delta R.T. 0.03 min
Lab File: ENG1311.D
Acq: 18 May 99 1:19 am
Tgt Ion:276.05 Resp: 3261076
Ion
276
138
0
0
Ratio
100
37.9
0.0
0.0
Lower Upper
32.1
0.0
0.0
96.1
0.0
0.0
ocosao
wed May is 10:18:58 iyyy
HP 5989B
Page 17
-------
Abundance
600000 J
400000.
200000-
Time-->
TIC: ENG1311.D
61.00
61.50
62.00
Abundancelon 292.00 (291.70 to 292.70): ENG
100000
50000.
0 -
61.46
rime- ->
61.00
61.50
62.00
Abundance
600000 J
400000 .
200000 -
Time-->
TIC: ENG1311.D
0
61150
62.00
62150
#32
Dibenz(a,h)anthracene-d!4
Concen: 7.81 ng/uL
RT: 61.46 min Scantf 8103
Delta R.T. 0.02 min
Lab File: ENG1311.D
Acq: 18 May 99 1:19 am
Tgt Ion:292 Resp: 1556733
Ion Ratio
292 100
0 0.0
0 0.0
0 0.0
Lower Upper
0.0
0.0
0.0
0.0
0.0
0.0
Abundance Ion
Ion
200000 -
100000-
0 .
278.00
139.00
(277.70 to 278.70) : ENG
(138.70 to 139.70): ENG
61.87
Time - - >
~~i I - > i - 1 - 1 - 1 - 1
61.50 62.00
1 - 1 - 1 - r-
62.50
ENG1311.D—PES.M
Wed May 19 10:19:02 1999
#33
Dibenz(a,h)anthracene
Concen: 8.04 ng/uL
RT: 61.87 min Scan# 8180
Delta R.T. 0.02 min
Lab File: ENG1311.D
Acq: 18 May 99 1:19 am
Tgt Ion:278 Resp: 2634146
Ion
278
139
0
0
Ratio
100
24.9
0.0
0.0
Lower Upper
12.6
0.0
0.0
37.6
0.0
0.0
OCC32,
HP S989B
Page 18
-------
Abundance
200000 .
100000 .
Time-->
TIC: ENG1311.D
64.50
esloo
65.50
Abundancelon 288.00 (287.70 to 288.70): ENG
150000.
100000 .
50000 -
Time-->
65.07
64:50
65.00
65.50
#34
Benzo(g,h,i)perylene-d!2
Concen: 8.02 ng/uL
RT: 65.07 min Scan# 8838
Delta R.T. 0.01 min
Lab File: ENG1311.D
Acq: 18 May 99 1:19 am
Tgt Ion:288 Resp: 2156111
Ion Ratio Lower Upper
288 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance
200000 .
100000 .
Time-->
TIC: ENG1311.D
65.00
eslso
66.00
Abundancelon 276.00 (275.70 to 276.70):
Ion 138.00 (137.70 to 138.70):
65.47
200000 -
100000 .
ENG
ENG
rime-->
65.00
65.50
66.00
ENG1311.DPES.M
#35
Benzo(g,h,i)perylene
Concen: 7.93 ng/uL
RT: 65.47 min Scan# 8934
Delta R.T. 0.03 min
Lab File: ENG1311.D
Acq: 18 May 99 1:19 am
Tgt Ion:276 Resp: 2778637
Ion
276
138
0
0
Ratio
100
33.4
0.0
0.0
Lower Upper
10.1
0.0
0.0
40.1
0.0
0 .0
Wed May 19 10:19:Ub 1999
HP 5989B
Page 19
-------
Quantitation Report
Data File :
Acg On :
Sample :
Misc :
Quant Time:
Method
Title
Last Update
Response via
C:\HPCHEM\1\DATA\9919\ENG1313.D
18 May 99 10:26 am
PES-MAH-051299-01 10 ng//iL
May 19 9:46 1999
: C:\HPCHEM\1\METHODS\PES.M
: Wed May 19 09:55:02 1999
Multiple Level Calibration
Vial: 2
Operator: JEMcCartney
Inst : HP 5989B
Multiplr: 1.00
Internal Standards
R.T. Qlon Response Cone Units Dev(Min)
1)
2 , 2 -Dif luorobiphenyl
24
.58
190
1628638
5
.00
System Monitoring Compounds
2)
4)
5)
7)
9)
11)
13)
15)
17)
19)
20)
22)
24)
26)
28)
30)
32)
34)
Napht hal ene - d8
2-Methlynaphthalene-dlO
Acenaphthylene-d8
Acenapht hene - dl 0
Fluorene-dlO
Phenant hrene - dl 0
Anthracene - dl 0
Fluoranthene-dlO
Pyrene-dlO
p-Terphenyl-d!4
Benzo (a) anthracene -d!2
Chrysene-dl2
Benzo (b) f Iuoranthene-dl2
Benzo (k) f Iuoranthene-dl2
Benzo (a) pyrene-d!2
Indenod, 2, 3-cd)pyrene-dl2
Dibenz (a, h) anthracene -d!4
Benzo (g, h, i) perylene-d!2
22
23
26
26
28
30
30
33
34
34
38
39
45
46
48
61
61
65
.23
.96
.28
.71
.00
.44
.58
.58
.26
.57
.88
.04
.89
.10
.57
.55
.49
.10
136
152
160
164
176
188
188
212
212
244
240
240
264
264
264
288
292
288
4774440
2601351
5025155
3240225
3495368
4919507
4418139
4562687
4936885
3841959
3752189
3952888
3532842
4826771
3601708
4463931
2722761
3562016
9
9
9
9
9
8
8
7
7
8
9
8
9
10
11
10
10
10
.61
.88
.60
.34
.28
.43
.71
.90
.78
.01
.22
.02
.73
.10
.13
.11
.55
.22
Target Compounds
3)
6)
8)
10)
12)
14)
16)
18)
21)
23)
25)
27)
29)
31)
33)
35)
Naphthalene (CCC)
Acenaphthylene
Acenapht hene (CCC)
Fluorene
Phenanthrene
Anthracene
Fluoranthene (CCC)
Pyrene
Benzo (a) anthracene
Chrysene(CCC)
Benzo (b) f luoranthene
Benzo (k) f luoranthene
Benzo (a) pyrene (CCC)
Indeno (1,2, 3 -cd) pyrene
Dibenz (a, h) anthracene
Benzo (g,h, i)perylene
22
26
26
28
30
30
33
34
38
39
46
46
48
61
61
65
.28
.32
.79
.07
.50
.62
.63
.31
.99
.17
.08
.26
.77
.90
.92
.51
128
152
154
166
178
178
202
202
228
228
252
252
252
276
278
276
5614786
5641885
3738345
4312160
6096084
5861339
6082971
6494037
4948487
5394006
4708001
5630794
5006612
5086367
4162365
4590769
9
9
9
9
8
8
7
7
8
7
9
10
10
9
9
10
.72
.67
.60
.50
.61
.59
.97
.86
.33
.88
.05
.08
.22
.76
.79
.08
ng/uL 0
.00
%Recovery
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL m
ng/uL m
ng/uL m
ng/uL m
ng/uL
Qvalue
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uLm
ng/uL
ng/uL
ng/uL
ng/uL
88
100
89
85
97
98
90
91
92
95
92
82
89
72
97
77
OCC3263
(#) = qualifier out of range (m)
ENG1313.D PES.M Wed May 19
= manual integration
10:29:21 1999 HP
5989B
Page 1
-------
Quantitation Report
C:\HPCHEM\1\DATA\9919\ENG1313.D
18 May 99 10:26 am
PES-MAH-051299-01 10 ng/jiL
Data File
Acq On
Sample
Misc :
Quant Time: May 19 9:46 1999
Method
Title
Last Update
Response via
C:\HPCHEM\1\METHODS\PES.M
Wed May 19 09:55:02 1999
Multiple Level Calibration
Vial: 2
Operator: JEMcCartney
Inst -. HP 5989B
Multiplr: 1.00
Abundance
3500000 -
•
3000000 .
2500000-
•
2000000 .
1500000 .
1000000.
500000-
0
Time-->
Q
^1
5
3
2s
4s
1
9
5
12
0 1
ii
3
4
TIC: ENG1313.D
16
3
1!
2o!oo ' ' ijoloo
•
5
)S
21
TJSP
72P&.
2(
S 2
2<
7
31
29
28S
ids 35
IT
U
v v_ / \^_ j \
4o!od ' ' 5oloo ' ' eoloo
OCC-Kci
ENG1313.D PES.M
Wed May 19 10:29:33 1999
HP 5989B
Page 2
-------
Abundance
2000000:
1500000:
1000000 :
500000-
0-
Iime-->
Abundance
2000000 :
1500000.
1000000 -
500000 .
0 .
Time - - >
TIC: EM51313.D
22.00 22 20 22 40
Ion 136.00 (135.70 to 136.70): ENG
Ion 68.00 (67.70 to 68.70): ENG13
22.23
A
A
A
H 1 1 1 1 1 1 1 1 1 1 1 r — i 1 i
22 00 22 20 22.40
#2
Naphthalene-d8
Concen: 9.61 ng/uL
RT: 22.23 min Scan# 1566
Delta R.T. 0.00 min
Lab File: ENG1313.D
Acq: 18 May 99 10:26 am
Tgt Ion:136 Resp: 4774440
Ion Ratio Lower Upper
136
68
0
0
100
22.8
0.0
0.0
10.1
0.0
0.0
30.1
0.0
0.0
ENG
Abundance
2000000:
1500000.
1000000 :
500000:
o:
Time-->
Abundance
2000000.
1000000-
0
Time-->
TIC: ENG1313.D
22lo6 ' ' 22120 ' ' 22140
Ion 128.00 (127.70 to 128.70): ENG
Ion 127.00 (126.70 to 127.70): ENG
22.28
/A!
22lo6 ' ' 22120 22U6
1313. D PES.M wea May 19 io:^y:Jb lyyy
#3
Naphthalene(CCC)
Concen: 9.72 ng/uL
RT: 22.28 min Scan# 1573
Delta R.T. -0.01 min
Lab File: ENG1313.D
Acq: 18 May 99 10:26 am
Tgt Ion:128 Resp: 5614786
Ion Ratio Lower Upper
128 100
127 14.5 0.0 60.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
OCC3255
HP 5989B
Page 3
-------
'Abundance
1000000 .(
TIC: ENG1313.D
Time--> 23.80
500000 .
23.90
24.00
24.10
Abundance Ion 152.00 (151.70 to 152.70): Eire
1000000 .
500000 .
23.96
Time--> 23.80
23190
24.00
24.10
#4
2-Methlynaphthalene-dlO
Concen: 9.88 ng/uL
RT: 23.96 min Scan# 1928
Delta R.T. 0.00 min
Lab File: ENG1313.D
Acq: 18 May 99 10:26 am
Tgt Ion:152 Resp: 2601351
Ion Ratio Lower Upper
100
152
0
0
0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
ENG
Abundance
2000000.
1000000-
0
rime-->
TIC: ENG1313.D
j\
2elo6 ' ' 2el2o ' ' 26U6 '
Abundancelon 160.00 (159.70 to 160.70): ENG
2000000.
1500000-
1000000 .
500000-
0
Time-->
26.28
A
J ^
261-00 ' 26120 ' ' 26140 '
1-J1J.D PES.M Wed May iy 10:29:38 1999
#5
Acenaphthylene-d8
Concen: 9.60 ng/uL
RT: 26.28 min Scan# 2450
Delta R.T. -0.00 min
Lab File: ENG1313.D
Acq: 18 May 99 10:26 am
Tgt Ion:160 Resp: 5025155
Ion Ratio Lower Upper
160 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
OC03285
HP 5989B
Page 4
-------
Abundance TIC: ENG1313.D
•
2000000 .
1000000 -
o
1
/
J
Time--> 26120
\
V
26140 ' ' ' '
Abundancelon 152.00 (151.70 to 152.70): ENG
•
i
2000000 _
1000000 -
0 -
Ion 153.00 (152.70 to 153.70): ENG
26.32
A
JS
rime--> 26.20
1
4
26140 '
#6
Acei
Con<
RT:
Del
Lab
Acq
Tgt
Ion
152
153
0
0
Acenaphthylene
Concen: 9.67 ng/uL
26.32 min Scantt 2455
a R.T. -0.00 min
File: ENG1313.D
Acq: 18 May 99 10:26 am
Tgt Ion:152 Resp: 5641885
Ratio Lower Upper
100
7.-6
0.0
0.0
15.1
0.0
0.0
22.6
0.0
0.0
Abundance
2000000 .
1000000 .
rime-->26.50 26.60 26.70
TIC: ENG1313.D
26.80
Abundancelon 164.00 (163.70 to 164.70]
ENG
1000000 -
500000 .
26.71
rime-->26.50 26.60 26.70 26:80
ENGT3TJ7D PES . M
#7
Acenaphthene-dl0
Concen: 9.34 ng/uL
RT: 26.71 min Scan# 2513
Delta R.T. -0.00 min
Lab File: ENG1313.D
Acq: 18 May 99 10:26 am
Tgt Ion:164 Resp: 3240225
Ion
164
0
0
0
Ratio
100
0.0
0.0
0.0
Lower Upper
0.0
0.0
0.0
0.0
0.0
0.0
Wed May 19 10:29:41 1999
HP 5989B
Page 5
-------
Abundance
:
2000000 .
.
•
1000000 -
o
TIC: ENG1313.D
A
Ml 1
/ \/ 1
/ \
_J \
Time--> 26140 26160 ' '26!so' '2?loO
Abundance ton 154.00 (153.70 to 154.70): ENG
•j
1500000 .
1000000 -
500000 -
0 .
Ion 153.00 (152.70 to 153.70): ENG
26.79
A
|
y I
Time--> 26140 ' ' 26160 ' ' 26180 ' ^'vlob'
#8
Acei
Con<
RT:
Del
Lab
Acq
Tgt
Ion
154
153
0
0
Abundance
3000000J
2000000 .
1000000 .
Time-->
TIC: ENG1313.D
28o
2820
Acenaphthene(CCC)
Concen: 9.60 ng/uL
26.79 min Scantf 2525
a R.T. -0.00 min
File: ENG1313.D
Acq: 18 May 99 10:26 am
Tgt Ion:154 Resp: 3738345
Ratio Lower Upper
100
43.5
0.0
0.0
96.6
0.0
0.0
130.3
0.0
0.0
Abundancelon 176.00 (175.70 to 176.70) : ENG
1500000.
1000000-
500000 -
0
28.00
Time-->
2780
28o
2820
ENG1313.DPES.M
Wed May 19 10:29:44 1999
#9
Fluorene-dlO
Concen: 9.28 ng/uL
RT: 28.00 min Scan# 2709
Delta R.T. -0.00 min
Lab File: ENG1313.D
Acq: 18 May 99 10:26 am
Tgt Ion:176 Resp: 3495368
Ion
176
0
0
0
Ratio
100
0.0
0.0
0.0
Lower Upper
0.0
0.0
0.0
0.0
0.0
0 .0
OCC3233
HP 5989B
Page 6
-------
Abundance TIC: ENG1313.D
3000000 -
2000000 .
1000000-
0 '
Time - - >
Abundance
2000000 .
1500000 :
1000000-
500000 1
0 "
ritne-->
A
A
/ v
J \
21\BO 28!ob 28120 '
Ion 166.00 (165.70 to 166.70): ENG
Ion 165.00 (164.70 to 165.70): ENG
28.07
27180 ' ' 28lo6 ' 28120 '
#10
r J-Ui
Con
RT:
T""\^l
U61
Lab
Acq
Tgt
Ion
166
165
0
0
Concen: 9.50 ng/uL
RT: 28.07 tnin Scant 2720
-0.00 min
ENG1313.D
Acq: 18 May 99 10:26 am
Tgt Ion:166 Resp: 4312160
Ratio Lower Upper
100
38.2
0.0
0.0
89.1
0.0
0.0
114.4
0.0
0.0
Abundance
3000000 _i
2000000 .
1000000 .
Time--> 30.30
TIC: ENG1313.D
30.40
30:50
\
Abundance Ion 188.00 (187.70 to 188.70): ENG
.Ion 94.00 (93.70 to 94.70): ENG13
2000000 4 30.44
1500000 :
1000000 .
500000.
Time--> 30.30
30140
30.50
ENG1313.D—PES.M
Wed May 19 10:29:46 1999
#11
Phenanthrene-dl0
Concen: 8.43 ng/uL
RT: 30.44 min Scan# 3079
Delta R.T. 0.01 min
Lab File: ENG1313.D
Acq: 18 May 99 10:26 am
Tgt Ion:188 Resp: 4919507
Ion Ratio
188 100
94 30.2
0 0.0
0 0.0
Lower Upper
15.1
0.0
0.0
45.1
0.0
0.0
OCO269
HP 5989B
Page 7
-------
Abundance
3000000 J
2000000 -
1000000 .
Time-->
TIC: ENG1313.D
30.40
30.50
30.60
Abundance Ion 178.00 (177.70 to 178.70): ENG
3000000Hjon 176.00 (175.70 to 176.70): ENG
30.50
2000000 -
1000000 .
0
Time-->
30.40
30150
3o:eo
#12
Phenanthrene
Concen: 8.61 ng/uL
RT: 30.50 min Scantf 3088
Delta R.T. 0.01 min
Lab File: ENG1313.D
Acq: 18 May 99 10:26 am
Tgt Ion:178 Resp: 6096084
Ion Ratio Lower Upper
178 100
176 21.6 10.1 30.1
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance
3000000J
2000000.
1000000 .
Time-->
TIC: ENG1313.D
30.40
30.60
30.80
Abundance Ion 188.00 (187.70 to 188.70): ENG
Ion 94.00 (93.70 to 94.70): ENG13
30.58
2000000:
isooooo:
1000000:
500000:
rime-->
30.40
30.80
ENG1313.DPES.M
#13
Anthracene-dlO
Concen: 8.71 ng/uL
RT: 30.58 min Scan# 3100
Delta R.T. 0.01 min
Lab File: ENG1313.D
Acq: 18 May 99 10:26 am
Tgt Ion:188 Resp: 4418139
Ion
188
94
0
0
Ratio
100
34.9
0.0
0.0
Lower Upper
15.1
0.0
0.0
45.1
0.0
0.0
OCCX&d
Wed May 19 10:29:50 1999
HP 5989B
Page 8
-------
Abundance
3000000 J
2000000 -
1000000 .
rime-->
TIC: ENG1313.D
T 1 1 1 1 1 1 1 1 1 !~
30.50 30.60
30.70
Abundancelon 178.00 (177.70 to 178.70): ENG
3000000 HIon 3.76.00 (175.70 to 176.70): ENG
30.62
2000000 -
1000000 -
rime-->
-i 1 r
30:50
—I 1 1 1 1 i 1 1—
30.60 30170
#14
Anthracene
Concen: 8.59 ng/uL
RT: 30.62 min Scantf 3107
Delta R.T. -0.00 min
Lab File: ENG1313.D
Acg: 18 May 99 10:26 am
Tgt Ion:178 Resp: 5861339
Ion Ratio
178 100
176 20.9
0 0.0
0 0.0
Lower Upper
10.1 30.1
0.0 0.0
0.0 0.0
Abundance
2000000-
1000000 .
Time-->
TIC: ENG1313.D
-1 1 1 1 r-
33.40
-i ] 1 r
33.60
^—I—"~
33.80
Abundance Ion 212.00 (211.70 to 212.70): ENG
Ion 106.00 (105.70 to 106.70): ENG
33.58
1500000.
1000000 -
500000-
rime-->
33.40
33.60
33.80
ENGT3T3TD PEb .M
#15
Fluoranthene-dlO
Concen: 7.90 ng/uL
RT: 33.58 min Scan# 3626
Delta R.T. 0.00 min
Lab File: ENG1313.D
Acq: 18 May 99 10:26 am
Tgt Ion:212 Resp: 4562687
Ion Ratio Lower Upper
212 100
106 35.0 15.1 45.1
0 0.0 0.0 0.0
0 0.0 0.0 0.0
OCC13:
wea May is 10:29:54
HP S989B
Page 9
-------
Abundance
2000000 .
1000000.
0 _
rime - - >
Abundance
2000000 '.
1000000 -
0
Time - - >
TIC: ENG1313.D
| \
33:40 33160 33.80
Ion 202.00 (201.70 to 202.70): ENG
Ion 101.00 (100.70 to 101.70): ENG
33.63
ft
1
33140 33160 Sslsb '
#16
Fluoranthene(CCC)
Concen: 7.97 ng/uL
RT: 33.63 min Scan# 3634
Delta R.T. 0.00 min
Lab File: ENG1313.D
Acq: 18 May 99 10:26 am
Tgt Ion:202 Resp: 6082971
Ion Ratio
202 100
101 32.1
0 0.0
0 0.0
Lower Upper
13.6 40.6
0.0 0.0
0.0 0.0
ENG
Sundance
3000000-
2000000.
1000000.
0-
Time-->
Abundance
1500000 :
1000000.
500000.
0
Time - - >
TIC: ENG1313.D
A/I ,
1 1 A
34100 ' ' 34!20 ' ' 34U6 '
Ion 212.00 (211.70 to 212.70): ENG
Ion 106.00 (105.70 to 106.70): ENG
34.26
A
Ji ^
34lo6 ' ' 34J26 ' ' 34140 '
1313. D PES.M wed May is 10:29:5Y iyyy
#17
Pyrene-dlO
Concen: 7.78 ng/uL
RT: 34.26 min Scan# 3728
Delta R.T. 0.01 min
Lab File: ENG1313.D
Acq: 18 May 99 10:26 am
Tgt Ion:212 Resp: 4936885
Ion
212
106
0
0
Ratio
100
39.5
0.0
0.0
Lower Upper
17.1
0.0
0.0
51.1
0.0
0.0
occ
'"'
HP 5989B
Page 10
-------
Abundance
3000000 J
2000000 .
1000000 -
Time-->34.00
TIC: ENG1313.D
34.20
34.40
AbundanceXon 202.00 (201.70 to 202.70): ENG
Ion 101.00 (100.70 to 101.70): ENG
34.31
2000000 .
1000000 .
Time-->34. 00
34.20
34.40
#18
Pyrene
Concen: 7.86 ng/uL
RT: 34.31 min Scan# 3736
Delta R.T. 0.01 min
Lab File: ENG1313.D
Acq: 18 May 99 10:26 am
Tgt Ion:202 Resp: 6494037
Ion
202
101
0
0
Ratio
100
36.9
0.0
0.0
Lower Upper
16.1
0.0
0.0
48.1
0.0
0.0
Abundance
3000000J
2000000 .
1000000-
rime-->
TIC: ENG1313.D
34.40
34.60
34.80
Abundance Ion 244.00 (243.70 to 244.70): ENG
1500000J
1000000.
500000J
0
Ion 122.00 (121.70 to 122.70): ENG
34.57
lime-->
34.40
34!60
34.80
ENG1313.DPES. M
#19
p-Terphenyl-d!4
Concen: 8.01 ng/uL
RT: 34.57 min Scan# 3775
Delta R.T. 0.00 min
Lab File: ENG1313.D
Acq: 18 May 99 10:26 am
Tgt Ion:244 Resp: 3841959
Ion
244
122
0
0
Ratio
100
29.6
0.0
0.0
Lower Upper
13.6
0.0
0.0
40.6
0.0
0.0
OCCK
»• -u \j
Wed May 19 10:30:00 1999
HP 5989B
Page 11
-------
Abundance
1500000 -
1000000-
500000-
Time-->
TIC: ENG131J.D
i i i i i
38.70
38.80 38.90 39.00
Abundancelon 240.00 (239.70 to 240.70): ENG
1000000HIon 120.00 (119.70 to 120.70): ENG
38.88
500000-
Time - - >
H—i—i—i—i—i—i—i—i—i—i—i—r
38.70 38.80 38.90 39!00
#20
Benzo(a)anthracene-d!2
Concen: 9.22 ng/uL
RT: 38.88 min Scan# 4424
Delta R.T. 0.01 min
Lab File: ENG1313.D
Acq: 18 May 99 10:26 am
Tgt Ion:240 Resp: 3752189
Ion Ratio
240 100
120 32.4
0 0.0
0 0.0
Lower Upper
15.1
0.0
0.0
45.1
0.0
0.0
Time-->
Uoundance
1500000 -
1000000 -
500000 -
TIC: ENG1313.D
0
38.80
39.00
39.20
Abundancelon 228.00 (227.70 to 228.70): ENG
Ion 114.00 (113.70 to 114.70): ENG
1000000 .
500000 -
Time-->
ssTso
-i 1 1 1 1 r
39.00 39:20
ENG1313.D—PES.M
Wed May 19 10:30:03
#21
Benzo(a)anthracene
Concen: 8.33 ng/uL
RT: 38.99 min Scan# 4441
Delta R.T. 0.01 min
Lab File: ENG1313.D
Acq: 18 May 99 10:26 am
Tgt Ion:228 Resp: 4948487
Ion
228
114
0
0
Ratio
100
29.2
0.0
0.0
Lower Upper
12.6
0.0
0.0
37.6
0.0
0.0
OC!
HP 5989B
Page 12
-------
[Abundance
1500000 -
1000000 -
500000:
TIC: ENG1313.D
Time--> 38.80
39.00
39.20
Abundance Ion 240.ou
10000001Ion 120.00
(239.70 to 240.70): ENG
(119.70 to 120.70): ENG
39.04
500000 -
rime-->
39.00
39.20
#22
Chrysene-dl2
Concen: 8.02 ng/uL
RT: 39.04 min Scantf 4449
Delta R.T. 0.01 min
Lab File: ENG1313.D
Acq: 18 May 99 10:26 am
Tgt Ion:240 Resp: 3952888
Ion Ratio Lower Upper
240 100
120 29.6 15.1 45.1
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance
1500000-
1000000 J
500000 .
Time-->
TIC-. ENG1313.D
0
-i ] 1 r
39.00
39.20
39.40
Abundance Ion 228.00 {227.70 to 228.70): ENG
Ion 114.00 (113.70 to 114.70): ENG
39.17
1000000.
500000-
Time-->
39.00
39.20
39.40
~ ENG131J.D—PES.M
Wed May 19 ! 1999
#23
Chrysene(CCC)
Concen: 7.88 ng/uL
RT: 39.17 min Scan# 4468
Delta R.T. 0.01 min
Lab File: ENG1313.D
Acq: 18 May 99 10:26 am
Tgt Ion:228 Resp: 5394006
Ion Ratio Lower Upper
228 100
114 27.4 12.6 37.6
0 0.0 0.0 0.0
0 0.0 0.0 0.0
OCC)2;J5
HP 5989B
Page 13
-------
Abundance
1500000 -
1000000 .
500000 -
Time--:45. 60
TIC: ENG1313.D
i i
45.80
46.00
Abundance Ion 264.00 (263.70 to 264.70): ENG
;ion 132.00 (131.70 to 132.70): ENG
600000:
400000:
200000 .
rime---AS .60
45.80
46.00
Abundance
1500000-
1000000.
500000 -
Time-->
TIC: ENG1313.D
45180
46.00
46.20
46140
Abundance Ion 252.00 (251770 to 252.70) : ENG
Ion 126.00 (125.70 to 126.70): ENG
800000 J
eooooo:
400000:
200000:
rime-->
#24
Benzo(b)fluoranthene-dl2
Concen: 9.73 ng/uL
RT: 45.89 min Scan# 5500
Delta R.T. 0.02 min
Lab File: ENG1313.D
Acq: 18 May 99 10:26 am
Tgt Ion:264 Resp: 3532842
Ion Ratio Lower Upper
264 100
132 33.7 15.1 45.1
0 0.0 0.0 0.0
0 0.0 0.0 0.0
45.80
46.00
46120
46.40
ENGT3T3TB PES .M
#25
Benzo(b)fluoranthene
Concen: 9.05 ng/uL
RT: 46.08 min Scan# 5530
Delta R.T. 0.01 min
Lab File: ENG1313.D
Acq: 18 May 99 10:26 am
Tgt Ion:252 Resp: 4708001
Ion
252
126
0
0
Ratio
100
29.1
0.0
0.0
Lower Upper
12.6
0.0
0.0
37.6
0.0
0.0
OCC.J&35
Wed May 13 10:30:Uy 1999
HP 5989B
Page 14
-------
Abundance
1500000 -
1000000-
TIC: ENG1313.D
46.40
Abundance Ion 264.00 (263.70 to 264.70)
Ion 132.00 (131.70 to 132.70)
600000J 46.10
400000 J
200000 -
Time-->
TiEFG"
ENG
-i — i — I — i — i
45.80
46.00
46.20
46.40
Abundance
1500000 -
1000000 .
500000 -
Time-->
TIC: ENG1313.D
46.00 46.20
-i 1 1 1 r-
46.40
—i—i—i—r
46.60
#26
Benzo(k)fluoranthene-d!2
Concen: 10.10 ng/uL m
RT: 46.10 min Scan# 5533
Delta R.T. 0.03 min
Lab File: ENG1313.D
Acq: 18 May 99 10:2€ am
Tgt Ion:264 Resp: 4826771
Ion Ratio Lower Upper
264 100
132 35.4 15.1 45.1
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance Ion 252.00 (251.70 to 252.70): ENG
Ion 126.00 (125.70 to 126.70): ENG
800000 :
600000 .
400000 .
200000-
Time-->
46.26
"1—'—'
46.00
-i—i—i—i—i—i—i—r—i—i—i—i—r
46.20 46.40 46.60
ENG13T3TD"PES.M
#27
Benzo(k)fluoranthene
Concen: 10.08 ng/uL m
RT: 46.26 min Scan# 5557
Delta R.T. 0.03 min
Lab File: ENG1313.D
Acq: 18 May 99 10:26 am
Tgt Ion:252 Resp: 5630794
Ion
252
126
0
0
Ratio
100
34.4
0.0
0.0
Lower Upper
12.6
0.0
0.0
37.6
0.0
0.0
wed May 19
HP 5989B
Page 15
-------
Abundance
800000 J
600000 :
400000:
200000:
TIC: ENG1313.D
48.20 48.40
48.60 48.80
49.00
Abundance Ion 264.00 (263.70 to 264.70): ENG
Ion 132.00 (131.70 to 132.70): ENG
48.57
400000 J
200000 -
0 .
rime-->
48! 20 48.40 48.60'
#28
Benzo(a)pyrene-d!2
Concen: 11.13 ng/uL m
RT: 48.57 min Scan# 5911
Delta R.T. 0.03 min
Lab File: ENG1313.D
Acq: 18 May 99 10:26 am
Tgt Ion:264 Resp: 3601708
Ion Ratio Lower Upper
264 100
132 36.2 15.1 45.1
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance
800000 j
Time-->48 .00
TIC: ENG1313.D
48.50
49.00
Abundancelon 252.00 (251.70 to 252.70): ENG
Ion 126.00 (125.70 to 126.70): ENG
600000 J
400000:
200000 .
0 .
48.77
rime-->48.00
48.50
49.00
ENGI3T3TBPES.M
#29
Benzo(a)pyrene(CCC)
Concen: 10.22 ng/uL
RT: 48.77 min Scan# 5943
Delta R.T. 0.03 min
Lab File: ENG1313.D
Acq: 18 May 99 10:26 am
Tgt Ion:252 Resp: 5006612
Ion
252
126
0
0
Ratio
100
30.7
0.0
0.0
Lower Upper
12.6
0.0
0.0
37.6
0.0
0.0
OCC 32C3
Wed May IS 10:30:lb 1999
HP 5989B
Page 16
-------
jAb~undance
800000:
600000:
400000:
200000:
TIC: ENG1313.D
rime-->
0
61.00
61.50
62.00
Abundance Ion 288TOO (287.70 to 288.70)
ENG
300000-
200000J
100000 -
0 J
61.55
Time-->
61.00
61.50
62.00
Abundance
800000-
600000.
400000 -
200000 :
Time--> 61.00
TIC: ENG1313.D
61.50
62.00
62.50
Abundancelon 276.05 (275.75 to 276.75): ENG
400000JIon 138.00 (137.70 to 138.70): ENG
#30
Indeno(1,2,3-cd)pyrene-d!2
Concen: 10.11 ng/uL m
RT: 61.55 min Scan# 8121
Delta R.T. 0.07 min
Lab File: ENG1313.D
Acq: 18 May 99 10:26 am
Tgt Ion:288 Resp: 4463931
Ion Ratio Lower Upper
288 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
61.90
300000.
200000:
100000:
rime--> 61.00
61.50
62.00
62.50
ENG1313.DPES.M
Wed May 19 10:30:19 1999
#31
Indeno(1,2,3 -cd)pyrene
Concen: 9.76 ng/uL
RT: 61.90 min Scan# 8187
Delta R.T. 0.07 min
Lab File: ENG1313.D
Acq: 18 May 99 10:26 am
Tgt Ion:276.05 Resp: 5086367
Ion Ratio
276 100
138 42.3
0 0.0
0 0.0
Lower Upper
32.1 96.1
0.0 0.0
0.0 0.0
OCCJ2C9
HP 5989B
Page 17
-------
lAbundance
800000 .
600000 .
400000 .
200000 .
TIC: ENG1313.D
rime-->
0
61.00
61.50
62.00
Abundance Ion 292.00 (291.70 to 292.70)
200000j
61.49
150000.
100000 .
50000.
ENG
0.
lime-->
61.00
61.50
62.00
#32
Dibenz(a,h)anthracene-d!4
Concen: 10.55 ng/uL m
RT: 61.49 min Scantf 8110
Delta R.T. 0.05 min
Lab File: ENG1313.D
Acq: 18 May 99 10:26 am
Tgt Ion:292 Resp: 2722761
Ion Ratio Lower Upper
292 100
0
0
0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
Abundance
800000:
600000 :
400000 .
200000 .
o:
Time-->
TIC: ENG1313.D
61.50
62!00
62.50
Abundance Ion 278.00 (277.70 to 278.70): ENG
Ion 139.00 (138.70 to 139.70): ENG
61.92
300000:
200000:
100000 :
Time-->
61.50
62.00
62!50
ENGTTT3TD PES .M
wed May 19 10:30:22 1999
#33
Dibenz(a,h)anthracene
Concen: 9.79 ng/uL
RT: 61.92 min Scan# 8190
Delta R.T. 0.07 min
Lab File: ENG1313.D
Acq: 18 May 99 10:26 am
Tgt Ion:278 Resp: 4162365
Ion
278
139
0
0
Ratio
100
26.6
0.0
0.0
Lower Upper
12.6
0.0
0.0
37.6
0.0
0.0
OCO2C3
HP 5989B
Page 18
-------
Sundance
400000 -
300000-
200000 :
100000:
TIC: ENG1313.D
rime-->
Abundancelon 288.00 (287.70 to 288.70): ENG
0
-i 1 1 1 1 1 1 1 r—
64.50 65.00
eslso
65.10
200000-
100000 -
Time-->
64.50
65.00
65.50
#34
Benzo(g,h,i)perylene-d!2
Concen: 10.22 ng/uL
RT: 65.10 min Scant 8847
Delta R.T. 0.04 min
Lab File: ENG1313.D
Acq: 18 May 99 10:26 am
Tgt Ion:288 Resp: 3562016
Ion Ratio Lower Upper
288 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
PIC: EUG1313.D
100000 :
Time-->
65.00
65.50
eeloo
Abundancelon 27S.OO (275.70 to 276.70): ENG
400000 -IT™-! i-a a nn Mi7 7n t-n i7fl 7m • PINO
ion 138.00 (137.70 to 138.70): ENG
65.51
300000:
200000J
100000 :
o:
Time-->
65.00
65.50
66.00
ENG1313.DPES.M
#35
Benzo(g,h,i)perylene
Concen: 10.08 ng/uL
RT: 65.51 min Scan# 8946
Delta R.T. 0.07 min
Lab File: ENG1313.D
Acq: 18 May 99 10:26 am
Tgt Ion:276 Resp: 4590769
Ion Ratio Lower Upper
276 100
138 36.4 10.1 40.1
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0003301
wea May is
HP 5989B
Page 19
-------
Quantitation Report
Data File
Acq On
Sample
Misc
C:\HPCHEM\1\DATA\9919\ENG1314.D
18 May 99 11:47 am
PES-MAH-051899-01 15 ng/^L
Quant Time: May 19 9:50 1999
Vial: 3
Operator: JEMcCartney
Inst : HP 5989B
Multiplr: 1.00
Method
Title
Last Update
Response via
C:\HPCHEM\1\METHODS\PES.M
Wed May 19 09:55:02 1999
Multiple Level Calibration
Internal Standards
1)
2 , 2 -Dif luorobiphenyl
R
24
.T.
.59
Qlon
190
Response
1695013
Cone Units Dev(Min)
5
.00
System Monitoring Compounds
2)
4)
5)
7)
9)
11)
13)
15)
17)
19)
20)
22)
24)
26)
28)
30)
32)
34)
Naphthalene-dS
2 - Me t hlynapht hal ene - dl 0
Acenaph thyl ene - d8
Acenaphthene - dl 0
Fluorene-dlO
Phenant hr ene - dl 0
Anthracene - dl 0
Fluoranthene-dlO
Pyrene-dlO
p-Terphenyl-d!4
Benzo (a) anthracene-d!2
Chrysene-dl2
Benzo (b) f Iuoranthene-dl2
Benzo (k) f Iuoranthene-dl2
Benzo (a) pyrene-d!2
Indenod, 2, 3-cd)pyrene-dl2
Dibenz (a,h) anthracene-d!4
Benzo (g, h, i) perylene-dl2
22
23
26
26
28
30
30
33
34
34
38
39
45
46
48
61
61
65
.23
.96
.29
.71
.01
.44
.58
.58
.26
.58
.88
.06
.90
.13
.58
.58
.55
.14
136
152
160
164
176
188
188
212
212
244
240
240
264
264
264
288
292
288
6894641
3810059
6988904
4526627
4765306
6668207
6332823
6312241
6697071
5428448
5378552
5421865
5056548
6656221
5371120
6626228
4043442
5487442
13
13
12
12
12
10
12
10
10
10
12
10
13
13
15
14
14
15
.34
.90
.83
.53
.16
.98
.00
.50
.14
.87
.70
.56
.38
.14
.81
.43
.99
.18
Target Compounds
3)
6)
8)
10)
12)
14)
16)
18)
21)
23)
25)
27)
29)
31)
33)
35)
Naphthalene(CCC)
Acenaphthylene
Acenaphthene (CCC)
Fluorene
Phenanthrene
Anthracene
Fluoranthene (CCC)
Pyrene
Benzo (a) anthracene
Chrysene (CCC)
Benzo (b) f luoranthene
Benzo (k) f luoranthene
Benzo (a) pyrene (CCC)
Indeno ( 1 , 2 , 3 - cd) pyrene
Dibenz (a, h) anthracene
Benzo (g, h, i)perylene -
22
26
26
28
30
30
33
34
39
39
46
46
48
61
61
65
.28
.33
.79
.08
.50
.63
.63
.32
.00
.18
.11
.28
.79
.96
.99
.57
128
152
154
166
178
178
202
202
228
228
252
252
252
276
278
276
8448218
7966152
5272463
5971314
8298929
8518188
8352204
8909693
6949192
7442076
6567796
7551799
6970082
7323596
6068973
6658795
14
13
13
12
11
11
10
10
11
10
12
12
13
13
13
14
.06
.12
.01
.63
.27
.99
.51
.36
.24
.45
.13
.76
.68
.50
.75
.07
ng/uL 0
.00
%Recovery
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL m
ng/uL m
ng/uL m
ng/uL m
ng/uL m
Qvalue
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uLm
ng/uL
ng/uL
ng/uL
ng/uL
87
100
88
85
96
98
88
90
89
92
89
79
84
74
95
80
OCCJ2C2
(#) = qualifier out of range (m) = manual integration
ENG1314.D PES.M Wed May 19 10:33:05 1999 HP 5989B
Page l
-------
Quantitation Report
Data File : C:\HPCHEM\1\DATA\9919\ENG1314.D
Acq On : 18 May 99 11:47 am
Sample : PES-MAH-051899-01 15 ng//iL
MlSC :
Quant Time: May 19 9:50 1999
Method
Title
Last Update
Response via
C:\HPCHEM\1\METHODS\PES.M
Wed May 19 09:55:02 1999
Multiple Level Calibration
Vial: 3
Operator: JEMcCartney
Inst : HP 5989B
Multiplr: 1.00
„
Abundance
5000000.
4500000 -
4000000 -
3500000 .
3000000 -
2500000.
2000000 -
1500000-
1000000 -
500000 J
0 '
Time-->
%
3 5
2
S
4S
1
1
9
3
12
0 ]
i:
3
1
s
s
2o!od ' ' 3o!oo
TIC: ENG1314.D
16
1
I/!;
•
8
,s
3S
21 ^
53 7X¥&
2C
S
^
2*
3!
29
23s
1 IT
4olo6 ' ' 5o!oo ' ' eolod
„ ENG1314.D PES.M
Wed May 19 10:33:15 1999
HP 5989B
OCG ices
Page 2
-------
Abundance
3000000 '.
2000000 :
1000000 :
0
lime - - >
Abundance
2000000 -
1000000 1
0 "
Time-->
TIC: ENG1314.D
1
/ \
22100 ' 22120 ' ' 22U6
Ion 136.00 (135.70 to 136.70): ENG
Ion 68.00 (67.70 to 68.70): ENG13
22.23
[\
A
11
22lo6 22.20 22U6
#2
Naphthalene-d8
Concen: 13.34 ng/uL
RT: 22.23 min Scan# 1566
Delta R.T. 0.00 min
Lab File: ENG1314.D
Acq: 18 May 99 11:47 am
Tgt Ion:136 Resp: 6894641
Ion Ratio Lower Upper
136 100
68 21.7 10.1 30.1
0 0.0 0.0 0.0
0 0.0 0.0 0.0
ENG
Abundance
3000000 :
2000000 :
1000000 :
0 "
rime--> :
Abundance
3000000 :
2000000 .
1000000 .
0
Time-->
TIC: ENG1314.D
1
/ \
22100 ' ' 22120 ' ' 22U6 '
Ion 128.00 (127.70 to 128.70): ENG
Ion 127.00 (126.70 to 127.70): ENG
22.28
A
11
22!o6 22120 22140 '
U14.D PES.M wea May 19 10:33:18 iyyy
#3
Nap]
Con
RT:
noi
JJex
Lab
Acq
Tgt
Ion
128
127
0
0
Naphthalene(CCC)
Concen-. 14.06 ng/uL
22.28 min Scan# 1574
a R.T. 0.00 min
File: ENG1314.D
Acq: 18 May 99 11:47 am
Tgt Ion:128 Resp: 8448218
Ratio
100
14.8
0.0
0.0
Lower Upper
0.0
0.0
0.0
60.0
0.0
0.0
HP 5989B
Page 3
-------
Abundance
1000000 -
500000 -
rime-->
TIC: ENG1J14.D
23.80 23.90
—I [~T—
24.00
24 110
Abundancelon 152.00 (151.70 to 152.70): ENG
1500000 :
1000000 J
500000:
0
23.96
rime-->
-i 1—i—i i—i—i 1 1—r
23.80 23.90
24.00 24.10
#4
2-Methlynaphthalene-dlO
Concen: 13.90 ng/uL
RT: 23.96 min Scan# 1928
Delta R.T. 0.00 min
Lab File: ENG1314.D
Acq: 18 May 99 11:47 am
Tgt Ion:152 Resp: 3810059
Ion Ratio Lower Upper
152 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
ENG
Abundance
4000000^
3000000:
.
2000000 :
•
1000000 :
0
rime--> 2
TIC: ENG1314.D
l\
1
1 \
I \
J v
elo6 ' ' 26120 ' ' 26140 '
Abundancelon 160.00 (159.70 to 160.70): ENG
3000000 _
2000000.
1000000 .
0
Time--> 2
26.29
A
J{
>6!00 ' ' 26120 ' ' 26140 '
1314. D PES.M Wea May 19 10:33:22 1999
#b
Ace:
con1
RT:
Del
Lab
Acq
Tgt
Ion
160
0
0
0
Acenaphthylene-d8
Concen: 12.83 ng/uL
RT: 26.29 min Scan# 2451
R.T. 0.01 min
.16: ENG1314.D
Acq: 18 May 99 11:47 am
Tgt Ion:160 Resp: 6988904
Ratio Lower Upper
100
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
HP 5989B
Page 4
-------
ENG
Abundance
4000000 .
3000000 :
2000000 :
1000000 :
0 '
Time- -> 26
TIC: ENG1314.D
\
1
} \
.06 ' 2el2o ' ' 26U6 ' ' ieleo
Abundancelon 152.00 (151.70 to 152.70): ENG
3000000 .
2000000 .
1000000.
0
Time- -> 26
Ion 153.00 (152.70 to 153.70): ENG
26.33
A
il
!oo 26120 ieUo ieleo
^888888"
3000000.
2000000 .
1000000 :
0
Time-->
^mm
1500000 .
1000000 -
500000.
0
rime-->
TIC: ENG1314.D
l\
I \
J\J \
' 26 1 60 ' ' 26 1 70 ' ' 26 1 80 ' ' ' '
Ion 164.00 (163.70 to 164.70): ENG
26.71
' 26160 ' ' 26170 ' ' 26 1 80 ' ' ' '
rli!4.D PES.M Wea May 19 10: 33:25 1999
#6
Acenaphthylene
Concen: 13.12 ng/uL
RT: 26.33 min Scantf 2456
Delta R.T. 0.01 min
Lab File: ENG1314.D
Acq: 18 May 99 11:47 am
Tgt Ion:152 Resp: 7966152
Ion Ratio Lower Upper
152 100
153 15.1 7.6 22.6
0 0.0 0.0 0.0
0 0.0 0.0 0.0
#7
Acenaphthene-dlO
Concen: 12.53 ng/uL
RT: 26.71 min Scan# 2514
Delta R.T. 0.01 min
Lab File: ENG1314.D
Acq: 18 May 99 11:47 am
Tgt Ion:164 Resp: 4526627
Ion
164
0
0
0
Ratio
100
0.0
0.0
0.0
Lower Upper
0.0
0.0
0.0
0.0
0.0
0.0
OCC73C5
HP 5989B
Page 5
-------
Abundance
4000000 -,
3000000:
2000000:
1000000 :
0
Iime--> 2(
Abundance
2000000.
1000000 .
0
Time--> 2(
TIC: ENG1314.D
'
r\
aUb ' ' 26160 ' ' 26! 80 ' ' 27100 ' ' ' '
Ion 154.00 (153.70 to 154.70): ENG
Ion 153.00 (152.70 to 153.70): ENG
26.79
n
i
5l40 26160 26180 27lob '
#8
Acenaphthene(CCC)
Concen: 13.01 ng/uL
RT: 26.79 min Scan# 2526
Delta R.T. 0.01 min
Lab File: ENG1314.D
Acq: 18 May 99 11:47 am
Tgt Ion:154 Resp: 5272463
Lower Upper
Ion
154
153
0
0
Ratio
100
97.4
0.0
0.0
43.5
0.0
0.0
130.3
0.0
0.0
ENG
Abundance
4000000 :
3000000 :
2000000 .
1000000 -
0
Pime-->
TIC: ENG1314.D
1
1
r\
27\80 ' ' 28lo6 ' ' 28120
Abundance Ion 176.00 (175.70 to 176.70): ENG
2000000 .
1500000.
1000000 :
500000.
0
Time-->
28.01
A
I
1 \
27180 ' ' 28lo6 ' ' 28120
1314. D PES.M Wea May 19 10:33:28 1999
#9
Fluorene-dlO
Concen: 12.16 ng/uL
RT: 28.01 min Scantf 2710
Delta R.T. 0.01 min
Lab File: ENG1314.D
Acq: 18 May 99 11:47 am
Tgt Ion:176 Resp: 4765306
Ion Ratio Lower Upper
176 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
OCC52C7
HP 5989B
Page €
-------
Abundance
4000000:
3000000:
2000000:
1000000 -
Time-->
TIC: ENG1314.D
27.80
28.00
28.20
—I 1—I r
28.40
Abundancelon 166.00 (165.70 to 166.70): ENG
Ion 165.00 (164.70 to 165.70): ENG
28.08
2000000 .
1000000 -
rime-->
27.80
28.00
28.20
28.40
Fluorene
Concen: 12.63 ng/uL
RT: 28.08 min Scan# 2721
Delta R.T. 0.01 min
Lab File: ENG1314.D
Acq: 18 May 99 11:47 am
Tgt Ion:166 Resp: 5971314
Ion Ratio Lower Upper
166 100
165 89.3 38.2 114.4
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Time--> 30.30
TIC: ENG1314.D
3000000:
2000000:
1000000:
30140
30.50
Abundance Ion 188.00 (187.70 to 188.70): ENG
Ion 94.00 (93.70 to 94.70): ENG13
30.44
3000000J
2000000-
1000000J
—I 1 1 1 1 1 1 1 1 1 1 1 r—T r
fTime--> 30.30 . 30.40 30.50
ENGT3T3TDPES.M
Wed May 19 10:33:31
#11
Phenanthrene-dlO
Concen: 10.98 ng/uL
RT: 30.44 min Scan# 3080
Delta R.T. 0.01 min
Lab File: ENG1314.D
Acq: 18 May 99 11:47 am
Tgt Ion:188 Resp: 6668207
Ion
188
94
0
0
Ratio
100
30.0
0.0
0.0
Lower Upper
15.1
0.0
0.0
45.1
0.0
0.0
occ )
HP 5989B
Page 7
-------
Abundance
4000000:
3000000:
2000000:
1000000 -
Time-->
TIC: EMG1314.D
-f=—I—r-
30.40
iolso
ioleo
Abundance ion 17S.OO (177.70 to 178.70): ENG
4000000Jlon 176.00 (175.70 to 176.70): ENG
3000000:
2000000:
1000000:
Time-->
#12
Phenanthrene
Concen: 11.27 ng/uL
RT: 30.50 min Scan# 3088
Delta R.T. 0.00 min
Lab File: ENG1314.D
Acq: 18 May 99 11:47 am
Tgt Ion:178 Resp: 8298929
Ion Ratio Lower Upper
178 100
176 21.8 10.1 30.1
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance
4000000:
3000000 .
2000000:
1000000:
rime-->
TIC: ENG1314.D
30.40
30.60
i i i I r
3o:so
Abundance Ion 188.00
3000000 -•
2000000 -
1000000.
94.00
(187.70 to 188.70): ENG
(93.70 to 94.70): ENG13
30.58
rime-->
30.40
30.60
30.80
#13
Anthracene-dl0
Concen: 12.00 ng/uL
RT: 30.58 min Scan# 3101
Delta R.T. 0.01 min
Lab File: ENG1314.D
Acq: 18 May 99 11:47 am
Tgt Ion:188 Resp: 6332823
Ion
188
94
0
0
Ratio
100
35.6
0.0
0.0
Lower Upper
15.1
0.0
0.0
45.1
0.0
0.0
ENG1314.DPES.M
Wed May 19 10:33:34 1999
HP 59S9B
Page 8
-------
Abundance
4000000 :
3000000 .
2000000.
1000000.
Time - - >
TIC: ENG1314.D
30.50
30.60
30.70
T
Abundancelon 178.00 (177.70 to 178.70)
4000000^lon 176.00 (175.70 to 176.70)
30.63
3000000:
2000000 J
1000000 .
Time-->
ENG
ENG
30.50
30.60
30.70
#14
Anthracene
Concen: 11.99 ng/uL
RT: 30.63 min Scan# 3108
Delta R.T. 0.00 min
Lab File: ENG1314.D
Acq: 18 May 99 11:47 am
Tgt Ion:178 Resp: 8518188
Lower Upper
10.1 30.1
0.0 0.0
0.0 0.0
Ion Ratio
178 100
176 21.0
0 0.0
0 0.0
ENG
^mm
3000000 .
2000000 -
1000000 -
0
Time - - >
Abundance
2000000-
1000000 .
0 "
Time-->
TIC: ENG1314.D
1
/ V
isUo ' ' isieo ' ' 33!so
ion 212.00 (211.70 to 212.70): ENG
Ion 106.00 (105.70 to 106.70): ENG
33.58
A
A
33l40 33l60 33180
iJii.D PES.M wed May 19 10:33:38 1999
#15
Fluoranthene-dlO
Concen: 10.50 ng/uL
RT: 33.58 min Scan# 3627
Delta R.T. 0.01 min
Lab File: ENG1314.D
Acq: 18 May 99 11:47 am
Tgt Ion:212 Resp: 6312241
Ion
212
106
0
0
Ratio
100
36.6
0.0
0.0
Lower Upper
15.1
0.0
0.0
45.1
0.0
0.0
0003310
HP 5989B
Page 9
-------
^W0SB8e
3000000 .
2000000 .
1000000 -
o
Time-->
Abundance
3000000 -
2000000 J
1000000 :
0 '.
lime - - >
TIC: ENG1314.D
/ {
' 33140 ' ' 33160 ' 33l80 ' ' '
Ion 202.00 (201.70 to 202.70): ENG
Ion 101.00 (100.70 to 101.70): ENG
33.63
A
A
33l4o 33!eb s'slsb '
#16
Fluoranthene(CCC)
Concen: 10.51 ng/uL
RT: 33.63 min Scan# 3635
Delta R.T. 0.01 min
Lab File: ENG1314.D
Acq: 18 May 99 11:47 am
Tgt Ion:202 Resp: 8352204
Ion Ratio
202 100
101 33.1
0 0.0
0 0.0
Lower Upper
13.6 40.6
0.0 0.0
0.0 0.0
ENG
Abundance
4000000:
3000000 .
2000000 .
1000000 :
0
rime-->
Abundance
2000000 '.
1000000 -
0
Time-->
TIC: ENG1314.D
A/
i .A
1 \
/ I \
34 00 34.20 34.40
Ion 212.00 (211.70 to 212.70): ENG
Ion 106.00 (105.70 to 106.70): ENG
34.26
A
i ,
'—i — i — | — i — i — i — i — | — i — i — i — i — i — i — i — i — i — i-
34.00 34.20 34.40
1.314. D PES.M Wed May 19 10:33:41 1999
#17
Pyrene-dlO
Concen: 10.14 ng/uL
RT: 34.26 min Scan# 3728
Delta R.T. 0.01 min
Lab File: ENG1314.D
Acq: 18 May 99 11:47 am
Tgt Ion:212 Resp: 6697071
Ion
212
106
0
0
Ratio
100
41.6
0.0
0.0
Lower Upper
17.1
0.0
0.0
51.1
0.0
0.0
OCO3U
HP 5989B
Page 10
-------
Abundance
4000000
3000000:
2000000:
1000000 :
Time-->
TIC: ENG1314.D
00
3420
34
34e
lAbundanceTon 202.00 (201.70 to 202770):
Ion 101.00 (100.70 to 101.70):
3000000J 34.32
2000000:
1000000 -
ENG
ENG
Time-->
00
3420
34
3460
#18
Pyrene
Concen: 10.36 ng/uL
RT: 34.32 min Scan# 3737
Delta R.T. o.Ol min
Lab File: ENG1314.D
Acq: 18 May 99 11:47 am
Tgt Ion:202 Resp: 8909693
Ion Ratio Lower Upper
202 100
101 37.8 16.1 48.1
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance
4000000:
3000000:
2000000 .
1000000 .
Time-->
TIC: ENG1314.D
34
34.60
34l80
Abundancelon 244.00 (243.70 to 244.70): ENG
Ion 122.00 (121.70 to 122.70): ENG
34.58
2000000:
1500000 .
1000000 -
500000-
rime-->
3440
3460
3480
PES.M
Wed May iy 10:33:44 lyyy
#19
p-Terphenyl-d!4
Concen: 10.87 ng/uL
RT: 34.58 min Scan# 3776
Delta R.T. 0.01 min
Lab File: ENG1314.D
Acq: 18 May 99 11:47 am
Tgt Ion:244 Resp: 5428448
Ion
244
122
0
0
Ratio
100
29.5
0.0
0.0
Lower Upper
13.6
0.0
0.0
40.6
0.0
0.0
0007312
HP 5989B
Page 11
-------
Abundance
2000000 :
1500000:
1000000:
sooooo:
Time-->
TIC: ENG1314.D
38.70 38.80 38.90 39.00
Abundance Ion
Ion
1000000 .
500000-
240.00
120.00
(239.70 to
(119.70 to
38.88
240.70): ENG
120.70): ENG
rime-->
38.70 38.80 38.90 39.00
Abundance
2000000:
1500000 :
1000000:
500000:
Time-->
TIC: ENG1314.D
38.80
39.00
39.20
#20
Benzo(a)anthracene-d!2
Concen: 12.70 ng/uL
RT: 38.88 min Scan# 4424
Delta R.T. 0.01 min
Lab File: ENG1314.D
Acq: 18 May 99 11:47 am
Tgt Ion:240 Resp: 5378552
Ion Ratio Lower Upper
240 100
120 32.1 15.1 45.1
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance Ion 228.00 (227.70 to 228.70): ENG
Jlon 114.00 (113.70 to 114.70): ENG
1500000.
1000000 :
sooooo:
rime-->
38.80
39.00
39.20
ENG1314.DPES.M
#21
Benzo(a)anthracene
Concen: 11.24 ng/uL
RT: 39.00 min Scan# 4442
Delta R.T. 0.02 min
Lab File: ENG1314.D
Acq: 18 May 99 11:47 am
Tgt Ion:228 Resp: 6949192
Ion
228
114
0
0
Ratio
100
30.7
0.0
0.0
Lower Upper
12.6
0.0
0.0
37.6
0.0
0.0
OCC3313
Wed May 19 10:33:48 1999
HP 5989B
Page 12
-------
Abundance
2000000 :
1500000 -
1000000 -
500000 -
1 1 1 1 1 r
Time--> 38.80 39.00
TIC: ENG1314.D
0
-i i 1 1 1 r
39.20
Abundancelon240.00 (239.70 to 240.70): ENG
Ion 120.00 (119.70 to 120.70): ENG
39.06
1000000 -
500000 -
Time--> 38.80
39.00
39.20
#22
Chrysene-dl2
Concen: 10.56 ng/uL
RT: 39.06 min Scan# 4451
Delta R.T. 0.03 min
Lab File: ENG1314.D
Acq: 18 May 99 11:47 am
Tgt Ion:240 Resp: 5421865
Ion Ratio Lower Upper
240 100
120 31.0 15.1 45.1
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance
2000000 .
1500000 .
1000000 .
500000:
(
Time-->
TIC: ENG1314.D
39.00
39.20
39:40
Abundance Ion 228.00 (22TT70 to 228.713): ENG
Ion 114.00 (113.70 to 114.70): ENG
39.18
1500000.
1000000 J
500000:
rime-->
39:00
39:20
39:40
ENG1J14.DPES.M
#23
Chrysene(CCC)
Concen: 10.45 ng/uL
RT: 39.18 min Scan# 4470
Delta R.T. 0.02 min
Lab File: ENG1314.D
Acq: 18 May 99 11:47 am
Tgt Ion:228 Resp: 7442076
Ion
228
114
0
0
Ratio
100
29.1
0.0
0.0
Lower Upper
12.6
0.0
0.0
37.6
0.0
0.0
oee)
Wed May iy 10:33:51 1999
HP 5989B
Page 13
-------
Abundance
2000000-
1500000 .
1000000.
500000.
Time-->
TIC: ENG1314.D
45.80
46.00
Abundance Ion 264.00 (263.70 to 264.70)
Ion 132.00 (131.70 to 132.70)
ENG
ENG
500000 .
Time-->
45!80
46.00
#24
Benzo(b)fluoranthene-d!2
Concen: 13.38 ng/uL
RT: 45.90 min Scan# 5502
Delta R.T. 0.03 min
Lab File: ENG1314.D
Acq: 18 May 99 11:47 am
Tgt Ion:264 Resp: 5056548
Ion
264
132
0
0
Ratio
100
33.5
0.0
0.0
Lower Upper
15.1
0.0
0.0
45.1
0.0
0.0
Abundance
2000000 :
isooooo:
1000000:
500000:
rime-->
TIC: ENGI314.D
45.80
46.00
46.20
46.40
Abundance Ion 252.00 (251.70 to 252.70) : ENG
jlon 126.00 (125.70 to 126.70): ENG
1000000 .
500000 .
Time - - >
45.80
] 1 1 1 1—I 1 1 1 1 1 1—r
46.00 46.20 46.40
ENG1314.D—PES.M
Wed May 19 10:33:S4 1999
#25
Benzo(b)fluoranthene
Concen: 12.13 ng/uL
RT: 46.11 min Scan# 5534
Delta R.T. 0.04 min
Lab File: ENG1314.D
Acq: 18 May 99 11:47 am
Tgt Ion:252 Resp: 6567796
Ion Ratio Lower Upper
252 100
126 30.6
0 0.0
0 0.0
12.6
0.0
0.0
37.6
0.0
0.0
OCO)3i3
HP 5989B
Page 14
-------
Abundance
2000000 -
1500000J
1000000:
500000 -
Time--> 45.80
TIC: ENG1314.D
46.00
46.20
46.40
Abundance Ion 264.00 (263.70 to 264.70): ENG
Ion 132.00 (131.70 to 132.70): ENG
46.13
500000 -
rime--> 45.80
46.00
46.20
46.40
#26
Benzo(k)fluoranthene-d!2
Concen: 13.14 ng/uL m
RT: 46.13 min Scan# 5537
Delta R.T. 0.05 min
Lab File: ENG1314.D
Acq: 18 May 99 11:47 am
Tgt Ion:264 Resp: 6656221
Ion Ratio Lower Upper
264 100
132 36.1 15.1 45.1
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance
2000000 :
1500000:
1000000:
sooooo:
rime-->
TIC: ENG1314.D
0
46.00
46.20
46.40
46.60
Abundancelon 252.00 (251.70 to 252.70): ENG
Ion 126.00 (125.70 to 126.70): ENG
46.28
1000000 J
500000 -
Time-->
46.00 46.20 46.40 46.60
ENG1314.DPES.M
#27
Benzo(k)fluoranthene
Concen: 12.76 ng/uL m
RT: 46.28 min Scan# 5560
Delta R.T. 0.05 min
Lab File: ENG1314.D
Acq: 18 May 99 11:47 am
Tgt Ion:252 Resp: 7551799
Ion Ratio
252 100
126 35.3
0 0.0
0 0.0
Lower Upper
12.6
0.0
0.0
37.6
0.0
0.0
wed May 19 10:33:57
HP 5989B
Page 15
-------
Sundance
1000000 -
rime-->48.00
TIC: ENG1314.D
500000 -
48.50
49.00
Abundancelon 264.00 (263.70 to 264.70): ENG
Ion 132.00 (131.70 to 132.70): ENG
48.58
600000 J
400000 J
200000:
o:
Time-->48 .00
48.50
49.00
#28
Benzo(a)pyrene-d!2
Concen-. 15.81 ng/uL m
RT: 48.58 min Scan# 5913
Delta R.T. 0.04 min
Lab File: ENG1314.D
Acq: 18 May 99 11:47 am
Tgt Ion:264 Resp: 5371120
Ion Ratio
264 100
132 37.0
0 0.0
0 0.0
Lower Upper
15.1
0.0
0.0
45.1
0.0
0.0
Abundance
1000000 -
rime-->
TIC: ENG1314.D
500000 .
0
48.50
49:00
ancelon 252.00 (251.70 to 252.70)
000^ 126.00 (125.70 to 126.70)
48.79
500000 -
ENG
Time-->
48.50
49.00
ENG1J14.D—FEST71
Wed May 19 10:34:01 1999
#29
Benzo(a)pyrene(CCC)
Concen: 13.68 ng/uL
RT: 48.79 min Scan# 5946
Delta R.T. 0.05 min
Lab File: ENG1314.D
Acq: 18 May 99 11:47 am
Tgt Ion:252 Resp: 6970082
Ion Ratio Lower Upper
252 100
126 32.9 12.6 37.6
0 0.0 0.0 0.0
0 0.0 0.0 0.0
OCi
HP 5989B
Page 16
-------
Abundance
1000000 .
500000.
Time-->
TIC: ENG1314.D
61.00
61.50
62100
Abundance I on 288.Ou (287.70^ to 288.70): ENG
400000 -
300000 .
200000 .
100000 .
61.58
Time-->
61.00
61.50
62.00
Abundance
1000000 .
500000 .
Time-->
TIC: ENG1314.D
6ll50
62100
62.50
Abundancelon 276.05 (275.75 to 276.75): ENG
Ion 138.00 (137.70 to 138.70): ENG
61.96
400000 .
200000-
#30
Indenod, 2, 3-cd) pyrene-d!2
Concen: 14.43 ng/uL m
RT: 61.58 min Scan# 8127
Delta R.T. 0.10 min
Lab File: ENG1314.D
Acq: 18 May 99 11:47 am
Tgt Ion:288 Resp: 6626228
Ion Ratio
288 100
0 0.0
0 0.0
0 0.0
Lower Upper
0.0
0.0
0.0
0.0
0.0
0.0
Time - - >
6l!50
62100
62.50
ENG1314.DPES.M
#31
Indeno(1,2,3-cd)pyrene
Concen: 13.50 ng/uL
RT: 61.96 min Scan# 8197
Delta R.T. 0.13 min
Lab File: ENG1314.D
Acq: 18 May 99 11:47 am
Tgt Ion:276.05 Resp: 7323596
Ion
276
138
0
0
Ratio
100
43.5
0.0
0.0
Lower Upper
32.1
0.0
0.0
96.1
0.0
0.0
OCOJ313
wea May 19 10:34:05 1999
HP 5989B
Page 17
-------
Abundance
1000000 -
500000 -
TIC: EMG1314.D
rime-->
Abun
61.00 61.50 62.00
:lon 292.00 (291.70 to 292.70)
61.55
200000.
100000 -
rime-->
61.50
62.00
Abundance
1000000 -
500000 .
Time-->
TIC: ENG1314.D
61.50
62100
€2.50
#32
Dibenz(a,h)anthracene-d!4
Concen: 14.99 ng/uL m
RT: 61.55 min Scan# 8120
Delta R.T. 0.11 min
Lab File: ENG1314.D
Acq: 18 May 99 11:47 am
Tgt Ion: 292 Resp-. 4043442
Ion Ratio Lower Upper
292 100
0
0
0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
Abundancelon 278.00 (277.70 to 278.70):
Ion 139.00 (138.70 to 139.70): ENG
€1.99
400000-
200000.
Time-->
i I 1 1 1 1 1 1 1 1 i 1 r-
61.50 62100 €2l50
ENG1314.DPES.M
Wed May 19 10:J4:U8
#33
Dibenz(a,h)anthracene
Concen: 13.75 ng/uL
RT: 61.99 min Scan# 8202
Delta R.T. 0.13 min
Lab File: ENG1314.D
Acq: 18 May 99 11:47 am
Tgt Ion:278 Resp: 6068973
Ion
278
139
0
0
Ratio
100
27.8
0.0
0.0
Lower Upper
12.6
0.0
0.0
37.6
0.0
0.0
OCCKI3
HP 5989B
Page 18
-------
Abundance
600000 -
400000 -
200000 .
Time-->
TIC: ENG1314.D
—i 1 1 \ 1 1 ] 1 1 1 1 1 1 1 r
64.50 65100 65.50
Abundance I on 288.00 (287T70 to 288.70)
65.14
300000-
200000 J
100000:
ENG
o:
Time - - >
64.50
65.00
65.50
Abundance
600000 -
400000-
200000 -
rime-->
TIC: ENG1314.D
65.00
65.50
66.00
Abundancelon 276^00 (275.70 to 276.10}: ENG
Ion 138.00 (137.70 to 138.70): ENG
65.57
400000.
200000 .
#34
Benzo(g,h,i)perylene-d!2
Concen: 15.18 ng/uL m
RT: 65.14 min Scan# 8856
Delta R.T. 0.08 min
Lab File: ENG1314.D
Acq: 18 May 99 11:47 am
Tgt Ion:288 Resp: 5487442
Ion Ratio Lower Upper
288 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Time-->
65.00
65150
66;00
ENG1314.DPES.M
#35
Benzo(g,h,i)perylene
Concen: 14.07 ng/uL
RT: 65.57 min Scan# 8960
Delta R.T. 0.13 min
Lab File: ENG1314.D
Acq: 18 May 99 11:47 am
Tgt Ion:276 Resp: 6658795
Ion
276
138
0
0
Ratio
100
35.0
0.0
0.0
Lower Upper
10.1
0.0
0.0
40.1
0.0
0.0
OCO320
wea May 19 10:34:12 iyyy
HP 5989B
Page 19
-------
Response Factor Report HP 5989B
Method : C:\HPCHEM\1\METHODS\PES1.M ^4' )/~
Title : /*" ^ cc
Last Update : Won May 24 08:02:51 1999 '"- £ .S '>]
Response via : Initial Calibration -*
Calibration Files
0.5 =ENG1334.D 2.5
7 =ENG1332.D 10
Compound
1)
2)
3)
4)
5)
6)
7)
8)
9)
10)
11)
12)
13)
14)
15)
16)
17)
18)
19)
20)
21)
22)
23)
24)
25)
26)
27)
28)
29)
30)
31)
32)
33)
34)
35)
s
s
s
s
s
s
s
s
s
s
s
s
s
s
s
s
s
s
2, 2-Difluorobipheny3
Naphthalene -d8
Naphthalene(CCC)
2 -Methlynaphthalene
Acenaphthylene-d8
Acenaphthylene
Acenaphthene - dl 0
Acenaphthene (CCC)
Fluorene-dlO
Fluorene
Phenant hrene - dl 0
Phenanthrene
Anthracene -dlO
Anthracene
Fluoranthene - dl 0
Fluoranthene (CCC)
Pyrene-dlO
Pyrene
p-Terphenyl-dl4
Benzo (a) anthracene-
Benzo (a) anthracene
Chrysene-dl2
Chrysene (CCC)
Benzo (b) f luoranthen
Benzo (b) f luoranthen
Benzo (k) f luoranthen
Benzo (k) f luoranthen
Benzo (a) pyrene-d!2
Benzo (a) pyrene (CCC)
Indeno ( 1 , 2 , 3 - cd) pyr
Indeno ( 1 , 2 , 3 - cd) pyr
Dibenz (a, h) anthrace
Dibenz (a,h) anthrace
Benzo (g,h, i)perylen
Benzo (g, h, i) perylen
=ENG1336.
=ENG1338.
0.5 2.5
2.069
2.239
1.036
1.611
1.617
1.158
1.265
1.126
1.206
1.375
1.515
1.096
1.331
1.214
1.475
1.354
1.563
1.131
0.875
1.039
0.848
0.988
0.801
0.911
0.873
0.942
0.732
0.924
1.880
1.971
0.969
1.507
1.541
1.148
1.032
0.999
1.071
1.226
1.350
1.011
1.212
1.088
1.310
1.210
1.380
0.969
0.804
0.925
0.815
0.982
0.746
0.842
0.849
0.928
0.698
0.847
0.779
0.942
0.525
0.841
0.733
0.868
.D 5
,D 15
5 7
1.785
1.879
0.936
1.535
1.552
1.052
1.007
0.997
1.081
1.241
1.368
1.013
1.217
1.105
1.315
1.217
1.390
0.978
0.840
0.978
0.855
1.039
0.819
0.944
0.938
0.997
0.793
0.952
0.982
1.091
0.605
0.938
0.844
0.968
- TQTTi- -
1.808
1.830
0.922
1.458
1.381
0.940
0.885
0.942
0.971
1.127
1.282
1.046
1.231
0.931
1.076
0.994
1.129
0.798
0.744
0.871
0.722
0.899
0.734
0.893
0.857
0.957
0.726
0.944
0.976
1.089
0.612
1.004
0.785
1.030
=ENG1337.D
=ENG1339.D
10 15
1.704
1.757
0.916
1.466
1.486
0.955
0.994
0.939
1.008
1.169
1.281
0.963
1.135
1.078
1.263
1.165
1.339
0,934
0.850
0.968
0.839
1.020
0.813
0.940
0.947
1.002
0.823
0.973
1.050
1.108
0.658
0.979
0.874
0.992
1.561
1.633
0.843
1.371
1.381
0.866
0.915
0.876
0.946
1.085
1.203
0.930
1.115
0.999
1.174
1.069
1.243
0.867
0.817
0.946
0.785
0.969
0.778
0.905
0.891
0.952
0.787
0.945
1.000
1.038
0.659
0.945
0.820
0.944
1
1
0
1
1
1
1
0
1
1
1
1
1
1
1
1
1
0
0
0
0
0
0
0
0
0
0
0
0
1
0
0
0
0
Avg
.838
.931
.953
.510
.516
.060
.035
.994
.063
.222
.351
.020
.221
.081
.285
.183
.363
.964
.823
.955
.809
.980
.783
.899
.886
.958
.751
.922
.931
.018
.595
.905
.787
.938
%RSD
9.97
11.67
7.60
5.94
7.02
14.30
12.78
8.70
9.04
8.58
8.01
5.96
6.50
8.70
10.20
10.22
10.71
11.81
5.06
5.39
5.70
4.58
4.14
4.20
4.79
3.16
6.57
5.07
12.21
10.55
10.73
11.52
9.81
8.28
OG03321
(#) = Out of Range ### Number of calibration levels exceeded format ###
PESl.M Mon May 24 08:03:28 1999 HP 5989B Page
-------
Quantitation Report
Data File
Acq On
Sample
Misc :
Quant Time: May 24
C:\HPCHEM\1\DATA\9919\ENG1334.D
20 May 99 5:28 pm
PES-MAH-051299-02 0.5ng/uL
8:02 1999
Vial: 3
Operator: JEMcCartney
Inst : HP 5989B
Multiplr: 1.00
Method
Title
Last Update
Response via
C:\HPCHEM\1\METHODS\PES1.M
Mon May 24 08:02:51 1999
Multiple Level Calibration
Internal Standards
R.T. Qlon Response Cone Units Dev(Min)
1)
2 , 2 -Dif luorobiphenyl
24
.54
190
601068
5.
00
System Monitoring Compounds
2)
4)
5)
7)
9)
11)
13)
15)
17)
19)
20)
22)
24)
26)
28)
30)
32)
34)
Naphthalene-d8
2-Methlynaphthalene-dlO
Acenapht hy 1 ene - d8
Acenaphthene-dlO
Fluorene-dlO
Phenanthrene - dl 0
Anthracene-dlO
Fluoranthene-dlO
Pyrene-dlO
p-Terphenyl-d!4
Benzo (a) anthracene -d!2
Chrysene-dl2
Benzo (b) f Iuoranthene-dl2
Benzo (k) f Iuoranthene-dl2
Benzo (a) pyrene-d!2
Indenod, 2, 3-cd)pyrene-dl2
Dibenz (a, h) anthracene-d!4
Benzo (g,h, i)perylene-d!2
22
23
26
26
27
30
30
33
34
34
38
38
45
45
48
61
61
64
.18
.91
.24
.66
.96
.38
.52
.51
.19
.50
.78
.94
.72
.92
.38
.22
.15
.73
136
152
160
164
176
188
188
212
212
244
240
240
264
264
264
288
292
288
124348
62257
96810
69579
67682
82633
65883
72963
81376
67986
52588
50970
48145
52488
44009
46308
26049
40624
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
56
54
53
55
57
56
54
56
57
59
53
52
51
50
49
41
35
43
Target Compounds
3)
6)
8)
10)
12)
14)
16)
18)
21)
23)
25)
27)
29)
31)
33)
35)
Naphthalene(CCC)
Acenaphthylene
Acenapht hene (CCC)
Fluorene
Phenanthrene
Anthracene
Fluoranthene (CCC)
Pyrene
Benzo (a) anthracene
Chrysene(CCC)
Benzo (b) f luoranthene
Benzo (k) f luoranthene
Benzo (a) pyrene (CCC)
Indeno ( 1 , 2 , 3 - cd) pyrene
Dibenz ( a , h) anthracene
Benzo (g, h, i) perylene
22
26
26
28
30
30
33
34
38
39
45
46
48
61
61
65
.24
.27
.74
.03
.44
.57
.56
.24
.89
.07
.91
.08
.58
.53
.56
.15
128
152
154
166
178
178
202
202
228
228
252
252
252
276
278
276
134577
97218
76026
72475
91078
79977
88632
93928
62461
59358
54755
56618
55559
52949
47218
54180
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
58
53
63
57
56
55
57
57
54
50
51
50
50
43
43
47
ng/uL
0.00
%Recovery
ng/uL #
ng/uL
ng/uL
ng/uL m
ng/uL
ng/uL #
ng/uL #
ng/uL
ng/uL
ng/uL #
ng/uL #
ng/uL #
ng/uL
ng/uL #
ng/uL #
ng/uL m
ng/uL m
ng/uL m
Qvalue
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL#
ng/uL#
ng/uL
ng/uL#
ng/uL
ng/uL#
ng/uL#
ng/uLm
ng/uLm
ng/uLm
95
94
92
96
93
92
73
70
76
70
76
50
50
18
50
0
0000325
(#) = qualifier out of range (m) = manual integration
ENG1334.D PES1.M Mon May 24 08:03:43 1999 HP 5989B
Page 1
-------
Quantitation Report
Data File : C:\HPCHEM\1\DATA\9919\ENG1334.D
Acq On : 20 May 99 5:28 pm
Sample : PES-MAH-051299-02 0.5ng/uL
Misc :
Quant Time: May 24 8:02 1999
Method
Title
Last Update
Response via
C:\HPCHEM\1\METHODS\PES1.M
Mon May 24 08:02:51 1999
Multiple Level Calibration
Vial: 3
Operator: JEMcCartney
Inst : HP 5989B
Multiplr: 1.00
Abundance
350000.
TIC: EUG1334.D
300000-
250000 -
200000,
150000-
100000 .
50000 -
Time-->
3
2s
1J
13s
23S3
J_
34§
20.00 3oiod''4o!od''5o!oo''eoToo'r
0003323
ENG1334.D PES1.M
Mon May 24 08:03:52 1999
HP 5989B
Page 2
-------
Time-->
TIC: ENG1334.D
60000 :
40000:
20000:
22:10
22.20
22:30
Abundance Ion 136.00 (135.70 to 136.70): ENG
Ion 68.00 (67.70 to 68.70): ENG13
22.18
60000-
40000J
20000 .
0 .
lime-->
22:20
22:30
Naphthalene-d8
Concen: 0.56 ng/uL
RT: 22.18 min Scan# 1559
Delta R.T. 0.01 min
Lab File: ENG1334.D
Acq: 20 May 99 5:28 pm
Tgt Ion:136 Resp:
Ion Ratio Lower
100
136
68
0
0
7.9
0.0
0.0
10.1
0.0
0.0
124348
Upper
30.1#
0.0
0.0
ENG
60000 J
•
40000 :
20000 :
0
Time-->
Abundance
60000.
40000 .
20000:
0 _
rime-->
TIC: ENG1334.D
' 22 ! 10 ' ' 22 ! 20 ' ' 22 1 30 ' ' 22 1 40 '
Ion 128.00 (127.70 to 128.70): ENG
Ion 127.00 (126.70 to 127.70): ENG
22.24
A
IxV
' 22 ! 10 ' ' 22 ! 20 ' ' 22 1 30 ' ' 22 \ 40 '
1JJ4.D PESI.M won way 24 08:03:bb iyyy
#3
Nap]
Con
RT:
Del
Lab
Acq
Tgt
Ion
128
127
0
0
Naphthalene(CCC)
Concen: 0.58 ng/uL
22.24 min Scan# 1567
;a R.T. 0 .01 min
File: ENG1334.D
Acq: 20 May 99 5:28 pm
Tgt Ion:128 Resp: 134577
Ratio Lower Upper
100
11.7 0.0 60.0
0.0 0.0 0.0
0.0 0.0 0.0
000332-1
HP 5989B
Page 3
-------
Abundance
30000 H
20000 .
10000.
Time--> 23.80 23.85
TIC: ENG1334.D
i—i—I—i—r
23.90
23.95 24.00
Abundancelon 152.00 (lSl.70 to 152.70): ENG
30000 J
20000:
10000:
o:
23.91
T 1 1 1 1 1 1 1 1 1 ! 1 1 1 1 1 1 1 1 1 1 1
Time--> 23:80 23.85 23.90 23.95 24.00
Abundance
60000 .
40000-
20000 -
Time--> 26.10 26.20 26.30
TIC: ENG1334.D
0
Abundancelon 160.00 (159.70 to 160.70): ENG
26.24
40000 -
20000 .
0.
Time--> 26!lO 26!20 26130
2-Methlynaphthalene-dlO
Concen: 0.54 ng/uL
RT: 23.91 min Scan# 1911
Delta R.T. 0.01 min
Lab File: ENG1334.D
Acq.- 20 May 99 5:28 pm
Tgt Ion:152 Resp: 62257
Ion Ratio Lower Upper
152 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
ENG1334.DPES1.M
#5
Acenaphthylene-d8
Concen: 0.53 ng/uL
RT: 26.24 min Scan# 2442
Delta R.T. 0.01 min
Lab File: ENG1334.D
Acq: 2 0 May 99 5:2 8 pm
Tgt Ion:160 Resp: 96810
Ion Ratio Lower Upper
160 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Ati'tJ
won May 24tJ8 : 03 :
i9yy
HP 5989B
Page 4
-------
Abundance
60000 -
40000 -
20000.
Time-->
TIC: ENG1334.D
26.20
26.30
26.40
lAbundancelon 152.00 (151.70 to 152.70): ENG
Ion 153.00 (152.70 to 153.70): ENG
26.27
40000 .
20000-
0.
Time-->
26.20
1 | 1 1 1 1 1 r—
26.30 26.40
Abundance
60000 .
40000 .
20000 .
Time-->
TIC: ENG1334.D
26.60
26.70
#6
Acenaphthylene
Concen: 0.53 ng/uL
RT: 26.27 min Scan# 2447
Delta R.T. 0.01 min
Lab File: ENG1334.D
Acq: 20 May 99 5:28 pm
Tgt Ion:152 Resp:
Ion Ratio Lower
152 100
153 12.4 7.6
0 0.0 0.0
0 0.0 0.0
97218
Upper
22.6
0.0
0.0
(Abundanceion 164.00 (163.70 to 164.70)
ENG
26.66
30000 J
20000 -
10000 -
lime-->
26.60
26.70
ENG13J4.D—PES1.M
#7
Acenaphthene - dl 0
Concen: 0.55 ng/uL m
RT: 26.66 min Scantf 2505
Delta R.T. 0.01 min
Lab File: ENG1334.D
Acq: 20 May 99 5:28 pm
Tgt Ion: 164 Resp:
Ion Ratio Lower
164 100
0 0.0 0.0
0 0.0 0.0
0 0.0 0.0
69579
Upper
0.0
0.0
0.0
Mon May 24 08:04:03 1999
HP 5989B
Page 5
-------
Abundance
60000-
40000 -
20000-
TIC: ENG1334.U
Time-->26.60
-i 1 r
26.70
i 1 i 1 1 r
26.80
Abundanceton 154.00 (153.70 to 154.70):
Ion 153.00 (152.70 to 153.70):
26.74
30000J
20000 J
10000:
ENG
Time-->26.60
26.70
26180
Abundance
60000 -
40000 -
20000 -
rime--=27 .80
TIC: ENG1334.D
0
27.90
28.00
#8
Acenaphthene(CCC)
Concen: 0.63 ng/uL
RT: 26.74 min Scan# 2517
Delta R.T. 0.01 min
Lab File: ENG1334.D
Acq: 2 0 May 99 5:2 8 pm
Tgt Ion:154 Resp: 76026
Ion Ratio
154 100
153 79.2
0 0.0
0 0.0
Lower Upper
43.5
0.0
0.0
130.3
0.0
0.0
Abundancelon 176.00 1175770 to 176 .70) : ENG
30000-
20000 .
10000 .
0 -
27.96
Time- -;27. 80
27.90
1 1 1 1 1 r
28.00
ENG1334.D—PES1.M
#9
Fluorene-dlO
Concen: 0.57 ng/uL
RT: 27.96 min Scan# 2701
Delta R.T. 0.01 min
Lab File: ENG1334.D
Acq: 20 May 99 5:28 pm
Tgt Ion:176 Resp: 67682
Ion Ratio Lower Upper
176 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
OCC3327
Mon May 24 08:04:06 1999
HP 5989B
Page 6
-------
[Abundance
i ,
60000 -
40000 -
20000 .
Time-->
TIC: ENG1334.D
27.90
28.00
28.10
lAbundanceion 166.00 (165.70 to 166.70)
40000n 165-00 (164.70 to 165.70)
28.03
30000 .
20000 .
10000 .
0 .
ENG
ENG
Time-->
T 1 1 1 1
27.90
1 1 1 1 1 1 1 1 1 1 1 1 r
28100 28.10
Abundance
40000 .
20000.
Time-->
TIC: ENG1334.D
0
30.30
30.40
30.50
Fluorene
Concen: 0.57 ng/uL
RT: 28.03 min Scantf 2712
Delta R.T. 0.01 min
Lab File: ENG1334.D
Acq: 20 May 99 5:28 pm
Tgt Ion:166 Resp: 72475
Ion Ratio
166 100
165 79.3
0 0.0
0 0.0
Lower Upper
38.2 114.4
0.0 0.0
0.0 0.0
Abundance Ion 188.00 (187.70 to 188.70) : ENG
Ion 94.00 (93.70 to 94.70): ENG13
40000 J
30000:
20000:
10000:
0.
30.38
Time-->
30.30
~l 1 1 1 1 1 1 1—
30.40 30.50
ENG1JJ4.D—PES1.M
Mon May 24 08:04:09
#11
Phenanthrene-dl0
Concen: 0.56 ng/uL
RT: 30.38 min Scant 3069
Delta R.T. -0.00 min
Lab File: ENG1334.D
Acq: 20 May 99 5:28 pm
Tgt Ion:188 Resp: 82633
Ion
188
94
0
0
Ratio
100
13.0
0.0
0.0
Lower Upper
15.1
0.0
0.0
45.1
0.0
0.0
1O!
HP 5989B
Page 7
-------
Abundance
40000 .
20000-
Time-->
TIC: ENG1JJ4.D
30.40
30.50
Abundance Ion 178.00
Ion 176.00
40000 -
20000 .
(177.70 to 178.70)
(175.70 to 176.70)
30.44
ENG"
ENG
rime-->
3040
30.50
#12
Phenanthrene
Concen: 0.56 ng/uL
RT: 30.44 min Scantf 3078
Delta R.T. -0.00 min
Lab File: ENG1334.D
Acq: 20 May 99 5:28 pm
Tgt Ion:178 Resp: 91078
Ion Ratio Lower Upper
178 100
176 17.0 10.1 30.1
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance
40000 .
20000 -
T 1 1 1 1 1 1 1 1 1 1 1 1 1 1"
fTime--> 30.40 30.50 30.60
TIC: ENG1334.D
Abundance Ion 188.00 (187.70 to 188.70): ENG
Ion 94.00 (93.70 to 94.70): ENG13
40000 J
30000 :
20000:
10000:
30.52
Time-->
30.40
30.50
30.60
ENG1334.DPES1.M
#13
Anthracene-dl0
Concen: 0.54 ng/uL
RT: 30.52 min Scan# 3091
Delta R.T. 0.01 min
Lab File: ENG1334.D
Acq: 20 May 99 5:28 pm
Tgt Ion:188 Resp: 65883
Ion Ratio
188 100
94 14.1
0 0.0
0 0.0
Lower Upper
15.1
0.0
0.0
45.1
0.0
0.0
OC0J329
Mon May 24 08:04:12 1999
HP 5989B
Page 8
-------
Abundance
40000 .
20000
i — i
rime--> 30.40
TIC: ENG13J4.U
30.50
30.60
s'olvo
Abundancelon 178.00 (177.70 to 178.70):
Jlon 176.00 (175.70 to 176.70): ENG
40000 -
20000 -
30.57
Time--> 30.40
30.50
30.60
30.70
#14
Anthracene
Concen: 0.55 ng/uL
RT: 30.57 min Scan# 3098
Delta R.T. -0.00 min
Lab File: ENG1334.D
Acq: 20 May 99 5:28 pm
Tgt Ion:178 Resp: 79977
Ion Ratio Lower Upper
178 100
176 16.2 10.1 30.1
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance
40000 -
20000 .
rime-->
TIC: ENG1334.D
33.40
33.50
33.60
Abundancelon 212.00 (211.70 to 212.70)
30000:
20000 J
10000:
Ion 106.00 (105.70 to 106.70)
33.51
o:
ENG
lime - - >
33.40
33!50
33.60
#15
Fluoranthene-dl0
Concen: 0.56 ng/uL
RT: 33.51 min Scan# 3609
Delta R.T. 0.00 min
Lab File: ENG1334.D
Acq: 20 May 99 5:28 pm
Tgt Ion:212 Resp: 72963
Ion
212
106
0
0
Ratio
100
15.4
0.0
0.0
Lower Upper
15.1
0.0
0.0
45.1
0.0
0.0
OG03330
ENG1334.DPES1.M
won May 24 08:04:15 iyyy
HP 5989B
Page 9
-------
Abundance
40000 -
20000 -
Time-->
TIC: ENG1334.D
33.70
Abundancelon 202.00 (201.70 to 202.70): ENG
40000-lion 101.00 (100.70 to 101.70): ENG
33.56
30000:
20000J
10000:
o:
Time-->
33.40 33.50 33.60 33.70
#16
Fluoranthene(CCC)
Concen: 0.57 ng/uL
RT: 33.56 min Scan# 3617
Delta R.T. 0.00 tnin
Lab File: ENG1334.D
Acq: 20 May 99 5:28 pm
Tgt Ion:202 Resp: 88632
Ion
202
101
0
0
Ratio
100
13.1
0.0
0.0
Lower Upper
13.6
0.0
0.0
40. 6#
0.0
0.0
Abundance
40000 .
rime-->
TIC: ENG13347D
20000-
34.10
34120
34:30
Abundancelon 212.00 (211.70 to 212.70):
Ion 106.00 (105.70 to 106.70):
34.19
30000:
20000:
10000:
o:
ENG
Time-->
i I i i 1 1 1 1 1 1 1 1 1 1 r
34.10 34.20 34.30
ENGT3T5TBPES1 .M
Mon May 24 08:04:18 1999
#17
Pyrene-dlO
Concen: 0.57 ng/uL
RT: 34.19 min Scan# 3711
Delta R.T. 0.01 min
Lab File: ENG1334.D
Acq: 20 May 99 5:28 pm
Tgt Ion:212 Resp: 81376
Ion
212
106
0
0
Ratio
100
17 .5
0.0
0.0
Lower Upper
17.1
0.0
0.0
51.1
0.0
0.0
OC03331
HP 5989B
Page 10
-------
Abundance
40000 .
20000 -
Time - - >
TIC: ENG1334.D
34.10 34.20 34.30 34.40
Abundance Ion 202.00 (201.70 to 202.70): ENG
40000 J
30000 -
20000 .
10000 -
o:
Ion 101.00 (100.70 to 101.70): ENG
34.24
Time - - >
34.10 34.20 34.30 34140
#18
Pyrene
Concen: 0.57 ng/uL
RT: 34.24 min Scantf 3719
Delta R.T. 0.01 min
Lab File: ENG1334.D
Acq: 20 May 99 5:28 pm
Tgt Ion:202 Resp: 93928
Ion Ratio Lower Upper
202 100
101 15.1 16.1 48.1#
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance
40000 :
30000 :
20000 .
10000 .
0 -
TIC: ENG1334.D
Time--> 34140 ' ' 34is6 ' ' 34!e6
Abundance
30000 1
20000 -
10000 .
0 .
lime - - >
ion 244.00 (243.70 to 244.70): ENG
Ion 122.00 (121.70 to 122.70): ENG
34.50
34140 ' ' 34!s6 ' ' 34160
#19
p-Terphenyl -d!4
Concen: 0.59 ng/uL
RT: 34.50 min Scan# 3758
Delta R.T. 0.01 min
Lab File: ENG1334.D
Acq : 2 0 May 99 5 : 2 8 pm
Tgt Ion: 244 Resp: 67986
Ion Ratio Lower Upper
244 100
122 12.4 13.6 40. 6#
0 0.0 0.0 0.0
0 0.0 0.0 0.0
OCO332
ENG1334.DPES1.M
Mon May 24 08:04:21 1999
HP 5989B
Page 11
-------
Abundance
30000J
20000 -
10000 -
Time - - >
TIC: ENG1JJ4.D
-i—i—I—i—i—i—i—I—i—i—r
38.60 38.70 38.80 38.90
Abundance Ion 240.00
Ion 120.00
15000 J
10000:
5000.
Time-->
(239.70 to
(119.70 to
38.78
240.70)
120.70)
~ENG~
ENG
38190
#20
Benzo(a)anthracene-d!2
Concen: 0.53 ng/uL
RT: 38.78 min Scan# 4401
Delta R.T. 0.01 min
Lab File: ENG1334.D
Acq: 20 May 99 5:28 pm
Tgt Ion:240 Resp: 52588
Ion Ratio
240 100
120 13.8
0 0.0
0 0.0
Lower Upper
15.1
0.0
0.0
45.1#
0.0
0.0
Abundance
30000 J
20000 .
10000 .
Time--> 38.70
TIC: ENG1334.D
Abundancelon 228.00 (227.70 to 228.70): ENG
Ion 114.00 (113.70 to 114.70): ENG
38.89
15000 J
10000:
5000:
o:
Time--> 38!70 38.80 38.90
39.00
ENG1334.DPES1.M
Mon May
#21
Benzo(a)anthracene
Concen: 0.54 ng/uL
RT: 38.89 min Scan# 4418
Delta R.T. -0.00 min
Lab File: ENG1334.D
Acq: 20 May 99 5:28 pm
Tgt Ion:228 Resp: 62461
Ion
228
114
0
0
Ratio
100
13.1
0.0
0.0
Lower Upper
12.6
0.0
0.0
37.6
0.0
0.0
"333
08 :04 :24 1999
HP 5989B
Page 12
-------
Abundance
30000 J
20000 .
10000-
Time--^38.70 38.80 38.90 39.00 39.10
TIC: ENG1334.D
Abundance Ion 240.00 (239.70 to 240.70)
Ion 120.00 (119.70 to 120.70)
15000J
10000:
5000
o:
"EFTS"
ENG
38.94
Time--^38.70 38.80 38.90 39.00 39.10
Abundance
30000 J
20000.
10000 .
Time-->
TIC: ENG1334.D
0
38.90 39.00 39.10 39120
Abundancelon 228.00 (227.70 to 228.70):
Ion 114.00 (113.70 to 114.70):
39.07
15000 .
10000 .
5000 J
Time-->
#22
Chrysene-dl2
Concen: 0.52 ng/uL
RT: 38.94 min Scan# 4426
Delta R.T. -0.00 min
Lab File: ENG1334.D
Acq: 20 May 99 5:28 pm
Tgt Ion:240 Resp: 50970
Ion Ratio
240 100
120 12.3
0 0.0
0 0.0
Lower Upper
15.1
0.0
0.0
45. 1#
0.0
0.0
ENG
38:90 39100
i—|—i—i—i—i—i—;—i—r
39.10 39.20
ENG1JJ4.D PES1.M
Mon May 24 08:04:27
#23
Chrysene(CCC)
Concen: 0.50 ng/uL
RT: 39.07 min Scan# 4446
Delta R.T. 0.01 min
Lab File: ENG1334.D
Acq: 20 May 99 5:28 pm
Tgt Ion:228 Resp: 59358
Ion
228
114
0
0
Ratio
100
9.9
0.0
0.0
Lower Upper
12.6
0.0
0.0
37.6#
0.0
0.0
OCC3334
HP 5989B
Page 13
-------
rime--> 45.50 45.60 45.70 45.80 45.90
TIC: ENG1334.D
20000-
10000 .
Abundance Ion 264 .00 (263 . 7D to 264.70):
Ion 132.00 (131.70 to 132.70):
10000J 45.72
5000-
0-
Time--> 45^50 45^60 45i70 45^80
ENG
#24
Benzo(b)fluoranthene-d!2
Concen: 0.51 ng/uL
RT: 45.72 min Scan* 5468
Delta R.T. 0.01 min
Lab File: ENG1334.D
Acq: 20 May 99 5:28 pm
Tgt Ion:264 Resp: 48145
Ion Ratio
264 100
132 15.9
0 0.0
0 0.0
Lower Upper
15.1
0.0
0.0
45.1
0.0
0.0
rime-->45.70 45.80 45.90
TIC: ENG1334.D
20000 -
10000 .
46.00
Ion 126.00
Abundancelon 252.00 (251.70 to 252.70): ENG
(125.70 to 126.70): ENG
45.91
10000 -
5000 -
0-
rime--> 45.70
— i — r~i — i
45.80
i — i — i — i — i — i — i — I — i — i — r
45l90 46.00
•. ENG1334.D—PES1.M
#25
Benzo(b)fluoranthene
Concen: 0.51 ng/uL
RT: 45.91 min Scan# 5497
Delta R.T. -0.01 min
Lab File: ENG1334.D
Acq: 20 May 99 5:28 pm
Tgt Ion:252 Resp: 54755
Ion
252
126
0
0
Ratio
100
13.0
0.0
0.0
Lower Upper
12.6
0.0
0.0
37.6
0.0
0.0
Mon May "24 U«:04:3U 1999
HP 5989B
Page 14
-------
Time-->
TIC: ENG1334.D
20000 -
10000 -
0
-i 1 r
45.80
T 1 1 r
46.00
T
Abundance Ion 264.00 (263.70 to 264.70)
Ion 132.00 (131.70 to 132.70)
45.92
10000 J
5000 .
ENG
ENG
Time - - >
45.80
46.00
#26
Benzo(k)fIuoranthene-dl2
Concen: 0.50 ng/uL
RT: 45.92 min Scan# 5499
Delta R.T. -0.01 min
Lab File: ENG1334.D
Acq: 20 May 99 5:28 pm
Tgt Ion:264 Resp: 52488
Ion Ratio Lower Upper
264 100
132 0.0 15.1 45.1#
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abu
Time--> 45 .80
TIC: ENG1334.D
10000 .
46.00
46.20
Abundance Ion 252.00 (251.70 to 252.70)
Ion 126.00 (125.70 to 126.70)
46.08
10000- ^
5000 -
ENG
ENG
Time--> 45 .80
46!00
46120
ENG1334.DPES1.M
#27
Benzo(k)fluoranthene
Concen: 0.50 ng/uL
RT: 46.08 min Scan# 5523
Delta R.T. -0.01 min
Lab File: ENG1334.D
Acq: 20 May 99 5:28 pm
Tgt Ion:252 Resp: 56618
Ion
252
126
0
0
Ratio
100
0.0
0.0
0.0
Lower Upper
12.6
0.0
0.0
37.6#
0.0
0.0
Mon May 24 08:04:33
HP 5989B
Page 15
-------
Abundance
15000:
10000:
sooo:
ritne-->
TIC: ENG1334.D
-I 1 1 1 1 1 1 1 1 r-
48.20 48.40
48.60
Abundanceton 264.00 (263.70 to ^64.70): ENG
Ion 132.00 (131.70 to 132.70): ENG
8000:
48.38
rime-->
0 :
48.20
48.40
48.60
#28
Benzo(a)pyrene-d!2
Concen: 0.49 ng/uL
RT: 48.38 min Scan# 5876
Delta R.T. 0.01 min
Lab File: ENG1334.D
Acq: 20 May 99 5:28 pm
Tgt Ion:264 Resp: 44009
Ion Ratio Lower Upper
264 100
132 0.0 15.1 45.1#
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance
15000 :
10000:
5000:
1—I—I—I—I—I—I—I—I—I—I—I—I—I—I—I—I—
Time-->48.20 48.40 48.60 48.80
TIC: ENG1334.D
Abundancelon 252.00 (251.70 to 252.70)
10000 .
Ion 126.00 (125.70 to 126.70): ENG
48.58
5000.
Time-->48.20
48.40
48.60
48.80
ENGT3T3TIS—PES1.M
Mon May 24 OH:U4:Jb
#29
Benzo(a)pyrene(CCC)
Concen: 0.50 ng/uL
RT: 48.58 min Scan# 5907
Delta R.T. -0.01 min
Lab File: ENG1334.D
Acq: 20 May 99 5:28 pm
Tgt Ion:252 Resp: 55559
Ion
252
126
0
0
Ratio
100
0.0
0.0
0.0
Lower Upper
12.6
0.0
0.0
37.6#
0.0
0.0
OCG3337
HP 5989B
Page 16
-------
Abundance
20000 J
10000 .
Time--> 60.80 61.00 61.20 61.40 61.60
TIC: ENG1334.D
Abundancelon 288.00 (287.70 to 288.70): ENG
6000 J
4000:
2000:
o:
61.22
rime--> 60.80 61.00 61.20 6ll40 61.60
#30
Indeno(1,2,3-cd)pyrene-d!2
Concen: 0.41 ng/uL m
RT: 61.22 min Scan# 8053
Delta R.T. -0.05 min
Lab File: ENG1334.D
Acq: 20 May 99 5:28 pm
Tgt Ion:288 Resp: 46308
Ion Ratio Lower Upper
288 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance
20000 -
10000 -
Time-->
TIC: ENG1334.D
61.20 61.40 61.60 61.80
Abundancelon 276.05 (275.75 to 276.75)
Ion 138.00 (137.70 to 138.70)
61.53
6000 J
4000 :
2000:
ENG
ENG
Time-->
61.20 61.40 61.60 61.80
ENG1334.DPES1.M
#31
Indeno(1,2,3 -cd)pyrene
Concen: 0.43 ng/uL m
RT: 61.53 min Scan# 8111
Delta R.T. -0.09 min
Lab File: ENG1334.D
Acq: 2 0 May 99 5:2 8 pm
Tgt Ion:276.05 Resp: 52949
Ion
276
138
0
0
Ratio
100
63.0
0.0
0.0
Lower Upper
32.1
0.0
0.0
96.1
0.0
0.0
Mon May 24 08:04:39 1999
HP 5989B
Page 17
-------
Abundance
20000 -
10000 -
o
TIC: ENG1334.D
J^
w^^^v, J^
.X ^-w-^X^
^r^
-v -~f~ •J*V^^~^
rime--> 60 80 ' ' 6llob ' 6ll20 6l!40
Abundance
6000 -
4000 .
2000 .
0 .
Time--> <
Ion 292.00 (291.70 to 2V2./U): ENU
61.15
50.80 61.00 61.20 61.40
Abundance
20000.
10000.
n
TIC: ENG1334.D
rime--> ' Viiio' ViU'o' 'eileo' 'eils'o' '
Abundance
6000 .
4000.
2000.
0.
Time-->
Ion 278.00 (277,70 to 278.70): ENG
Ion 139.00 (138.70 to 139.70): ENG
61.56
'eil^o' 'eiU'o' 'eile'o' 'eils'o' '
#32
Dibenz (a,h) anthracene -d!4
Concen: 0.35 ng/uL m
RT: 61.15 min Scan# 8039
Delta R.T. -0.06 min
Lab File: ENG1334.D
Acq: 20 May 99 5:28 pm
Tgt Ion: 292 Resp: 26049
Ion Ratio Lower Upper
292 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
#33
Dibenz (a, h) anthracene
Concen: 0.43 ng/uL m
RT: 61.56 min Scan# 8116
Delta R.T. -0.07 min
Lab File: ENG1334.D
Acq: 20 May 99 5:28 pm
Tgt Ion: 278 Resp: 47218
Ion Ratio Lower Upper
278 100
139 57.6 12.6 37. 6#
0 0.0 0.0 0.0
0 0.0 0.0 0.0
nf>AYl>a
VrVrv •J^*u\/
ENG1334.DPES1.M
MOn May 24 08:04:44 1999
HP 5989B
Page 18
-------
Abundance
10000 -
5000 .
rime-->
TIC: ENG1334.D
0
64.40 64.60 64.80 65.00
Sundance Ion 288.00 (287.70 to 288.70): ENG
6000 .
4000.
2000.
64.73
Time-->
64:40 64.60 64.80 65.00
Abundance
10000 .
5000 .
TIC: ENG1334.D
Time-->
65.00
65.50
#34
Benzo(g,h,i)perylene-d!2
Concen: 0.43 ng/uL m
RT: 64.73 min Scan# 8747
Delta R.T. -0.05 min
Lab File: ENG1334.D
Acq: 20 May 99 5:28 pm
Tgt Ion:288 Resp: 40624
Ion Ratio
288 100
0 0.0
0 0.0
0 0.0
Lower Upper
0.0
0.0
0.0
0.0
0.0
0.0
Abundancelon 276.00 (275.70 to 276.70):
Ion 138.00 (137.70 to 138.70):
65.15
6000 J
ENG
ENG
0 .
Time-->
ENG1334.DPES1.M
65.00
65!50
#35
Benzo(g,h,i)perylene
Concen: 0.47 ng/uL m
RT: 65.15 min Scan# 8851
Delta R.T. -0.04 min
Lab File: ENG1334.D
Acq: 2 0 May 99 5:2 8 pm
Tgt Ion:276 Resp: 54180
Ion Ratio
276 100
138 59.0
0 0.0
0 0.0
Lower Upper
10.1
0.0
0.0
40.1#
0.0
0.0
oeosio
May 24^ 08 :04 :48
HP 5989B
Page 19
-------
Quantitation Report
Data File
Acq On
Sample
Misc :
Quant Time: May 24
C:\HPCHEM\1\DATA\9919\ENG1335.D
20 May 99 6:43 pm
PES-MAH-051299-03 1.0 ng/uL
Vial: 4
Operator: JEMcCartney
Inst : HP 5989B
Multiplr: 1.00
7:08 1999
Method
Title
Last Update
Response via
C:\HPCHEM\1\METHODS\PES1.M
Fri May 21 10:22:25 1999
Multiple Level Calibration
Internal Standards
1)
2 , 2 -Dif luorobiphenyl
R
24
. T. Qlon Response
.54
190
635444
Cone Units Dev(Min)
5
.00
System Monitoring Compounds
2)
4)
5)
7)
9)
11)
13)
15)
17)
19)
20)
22)
24)
26)
28)
30)
32)
34)
Naphthalene-d8
2-Methlynaphthalene-dlO
Acenaphthylene-d8
Acenaphthene-dlO
Fluorene-dlO
Phenanthrene-dlO
Anthracene-dlO
Fluoranthene-dlO
Pyrene-dlO
p-Terphenyl-d!4
Benzo (a) anthracene-d!2
Chrysene-dl2
Benzo (b) fluoranthene -d!2
Benzo (k) fluoranthene -d!2
Benzo (a) pyrene-dl2
Indenod, 2, 3-cd)pyrene-dl2
Dibenz (a,h) anthracene-d!4
Benzo (g,h, i)perylene-d!2
22
23
26
26
27
30
30
33
34
34
38
38
45
45
48
61
61
64
.18
.91
.24
.66
.95
.38
.52
.51
.18
.50
.78
.93
.72
.91
.37
.19
.16
.75
136
152
160
164
176
188
188
212
212
244
240
240
264 •
264
264
288
292
288
261450
133553
206624
165150
137505
169047
137822
146705
161395
136350
105864
101684
100680
107135
88899
101333
64990
84466
1
1
1
1
1
1
1
1
1
1
1
0
1
0
0
0
0
0
.12
.10
.08
.23
.09
.09
.06
.07
.07
.11
.01
.99
.01
.96
.94
.86
.84
.84
Target Compounds
3)
6)
8)
10)
12)
14)
16)
18)
21)
23)
25)
27)
29)
31)
33)
35)
Naphthalene (CCC)
Acenaphthylene
Acenaphthene (CCC)
Fluorene
Phenanthrene
Anthracene
Fluoranthene (CCC)
Pyrene
Benzo (a) anthracene
Chrysene (CCC)
Benzo (b) fluoranthene
Benzo (k) fluoranthene
Benzo (a) pyrene (CCC)
Indeno (1 , 2 , 3 - cd) pyrene
Dibenz ( a , h) anthracene
Benzo (g,h, i)perylene
22
26
26
28
30
30
33
34
38
39
45
46
48
61
61
65
.24
.27
.73
.02
.44
.57
.56
.24
.88
.06
.90
.07
.57
.54
.55
.13
128
152
154
166
178
178
202
202
228
228
252
252
252
276
278
276
280533
209804
145904
147425
185367
165881
175543
189968
121781
122562
109561
117948
110322
106294
92113
104760
1
1
1
1
1
1
1
1
1
0
0
0
0
0
0
0
.14
.09
.14
.09
.08
.08
.08
.10
.00
.98
.96
.99
.94
.82
.79
.86
ng/uL
0.00
%Recovery
ng/uL #
ng/uL
ng/uL
ng/uL m
ng/uL
ng/uL #
ng/uL #
ng/uL
ng/uL
ng/uL #
ng/uL #
ng/uL #
ng/uL #
ng/uL #
ng/uL
ng/uL m
ng/uL m
ng/uL m
Q value
ng/uL
ng/uL
ng/uLm
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL#
ng/uL#
ng/uL#
ng/uL
ng/uL
ng/uL#
ng/uLm
ng/uLm
ng/uLm
96
94
95
97
93
90
74
71
75
69
79
81
64
18
50
50
(#) = qualifier out of range (m) = manual integration
ENG1335.D PES1.M Mon May 24 07:10:23 1999 HP 5989B
Page 1
-------
Quantisation Report
Data File : C:\HPCHEM\1\DATA\9919\ENG1335.D
Acq On : 20 May 99 6:43 pm
Sample : PES-MAH-051299-03 1.0 ng/uL
Misc :
Quant Time: May 24 7:08 1999
Method
Title
Last Update
Response via
C:\HPCHEM\1\METHODS\PES1.M
Fri May 21 10:22:25 1999
Multiple Level Calibration
Vial: 4
Operator: JEMcCartney
Inst : HP 5989B
Multiplr: 1.00
Abundance
350000 -
300000-
250000 .
200000-
150000 -
100000 .
50000-
0
3
2s
4S
4
#10
5s
TIC: ENG1335.D
12
—r
f\
y
A
i:
s
rime--> 20^00 30i
4
s
s
iVs
LI S
72SB
O T J i
I 21^2%% 3Qs
— ,1 L * , — A-u
yu u i 1 <> — i v 1 LA___
00 40.00 ' 50.00 60.00
OCM342
ENG1335.D PES1.M
Mon May 24 07:10:31 1999
HP 5989B
Page 2
-------
Abundance
100000 .
50000.
i — i
[Time-->22:oo
TIC: ENG1335.D
22.10
i — I — i — i
22.20
i — I — i
22.30
Abundancelon 136.00 (135.70 to 136.70):
100000-
50000 .
0 .
Ion 68.00
(67.70 to 68.70)
22.18
ENG13
Time-->22.00
22.10
22.20
22!30
Abundance
100000 .
50000 -
Time--> 22.00
TIC: ENG1335TD
22.20
22140
#2
Naphthalene-d8
Concen: 1.12 ng/uL
RT: 22.18 min Scan# 1559
Delta R.T. 0.01 min
Lab File: ENG1335.D
Acq: 20 May 99 6:43 pm
Tgt Ion:136 Resp: 2€1450
Ion Ratio
136 100
68 7.6
0 0.0
0 0.0
Lower tipper
10.1
0.0
0.0
30.1#
0.0
0.0
Abundance ion 128.00 {127.70 to 128.70) : ENG
Ion 127.00 (126.70 to 127.70): ENG
22.24
100000-
50000 .
0.
Time--> 22!00 22120 22l40
ENGT335TDPES1.M
#3
Naphthalene(CCC)
Concen: 1.14 ng/uL
RT: 22.24 min Scan# 1567
Delta R.T. 0.01 min
Lab File: ENG1335.D
Acq: 20 May 99 6:43 pm
Tgt Ion:128 Resp: 280533
Ion
128
127
0
0
Ratio
100
11.5
0.0
0.0
Lower Upper
0.0
0.0
0.0
60.0
0.0
0.0
Won May 24 07:10:35 1999
HP 5989B
Page 3
-------
Abundance
40000.
20000.
lime-->
TIC: ENG133S.D
23.80
23.90
24.00
Abundance Ion 152.00 (151.70 to 152.70): ENG
eoooo:
40000-
20000J
0-
23.91
rime- - >
23.80
23.90
24lo6
Abundance
100000.
50000 -
Time-->
TIC: ENG1335.D
0
26.10 26.20 26.30 26.40
#4
2-Methlynaphthalene-dlO
Concen: 1.10 ng/uL
RT: 23.91 min Scan# 1911
Delta R.T. 0.01 min
Lab File: ENG1335.D
Acq: 20 May 99 6:43 pm
Tgt Ion:152 Resp: 133553
Ion Ratio Lower Upper
152 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance Ion 160700 (159.70 to 160.70): ENG
100000 .
50000 -
0 .
26.24
Time-->
26!lO 26.20 26130 26.40
ENGT3T5TBPES1.M
#5
Acenaphthylene-d8
Concen: 1.08 ng/uL
RT: 26.24 min Scan# 2443
Delta R.T. 0.01 min
Lab File: ENG1335.D
Acq: 20 May 99 6:43 pm
Tgt Ion:160 Resp: 206624
Ion
160
0
0
0
Ratio
100
0.0
0.0
0.0
Lower Upper
0.0
0.0
0.0
0.0
0.0
0.0
OC!
Won May 24 07:1U:38 1999
HP 5989B
Page 4
-------
26.40
Abundancelon 152.00 (151.70 to 152.70):
100000 .
50000 -
0 .
Ion 153.00 (152.70 to 153.70): ENG
26.27
rime--> 26.10
26.20
26.30
26.40
Abundance
100000.
50000 .
Time-->
TIC: ENG1335.D
0
26.60
26.70
#6
Acenaphthylene
Concen: 1.09 ng/uL
RT: 26.27 min Scan# 2448
Delta R.T. 0.01 min
Lab File: ENG1335.D
Acq: 20 May 99 6:43 pm
Tgt Ion: 152 Resp: 209804
Ion Ratio
152 100
153 12.4
0 0.0
0 0.0
Lower Upper
7.6 22.6
0.0 0.0
0.0 0.0
Abundance Ion 164.00 (163.70 to 164.70): ENG
60000 :
40000 .
20000:
26.66
Time-->
26.60
26.70
ENG1335.DPES1.M
#7
Acenaphthene-dlO
Concen: 1.23 ng/uL m
RT: 26.66 min Scan# 2506
Delta R.T. 0.01 min
Lab File: ENG1335.D
Acq: 20 May 99 6:43 pm
Tgt Ion:164 Resp: 165150
Ion
164
0
0
0
Ratio
100
0.0
0.0
0.0
Lower Upper
0.0
0.0
0.0
0.0
0.0
0.0
OCO343
Mon KayZf 07:10:41 1999
HP 5989B
Page 5
-------
Abundance
100000.
50000 .
Time-->
TIC: ENG1335.D
0
Sundance ion 154.00 (153.70 to 154.70)
Ion 153.00 (152.70 to 153.70)
26.73
60000J
40000:
20000:
ENG
ENG
Time-->
26.65 26.70 26.75 26.80
#8
Acenaphthene(CCC)
Concen: 1.14 ng/uL m
RT: 26.73 min Scantf 2517
Delta R.T. -0.00 min
Lab File: ENG1335.D
Acq: 20 May 99 6:43 pm
Tgt Ion:154 Resp: 145904
Ion Ratio
154 100
153 91.1
0 0.0
0 0.0
Lower Upper
43.5
0.0
0.0
130.3
0.0
0.0
ENG
Abundance
100000-
50000-
0
Titne-->
TIC: ENG1335.D
A
/ \
/ \
A / \
J\J \^
27l80 ' ' 27190 ' ' 28lob ' ' 28ilb
Abundancelon 176.00 (175.70 to 176.70): ENG
60000.
40000-
20000 :
o:
rime-->
27.95
A~
27180 ' ' 27190 ' ' 28lob ' ' 28!lO
1335. D PESI.M won way ^4 07:iU:44 iyyy
#9
Fluorene-dlO
Concen: 1.09 ng/uL
RT: 27.95 min Scan# 2701
Delta R.T. -0.00 min
Lab File: ENG1335.D
Acq: 20 May 99 6:43 pm
Tgt Ion: 176 Resp: 137505
Ion Ratio Lower Upper
176 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
OCC334S
HP 5989B Page
-------
Abundance
100000
T—i—i—i—i—i—i—i—i—i—i—i—|—i—i—i—i—I—i—i—r
Time--> 27180 27190 28.00 28.10 28.20
TIC: ENG1335.D
50000 -
Abundancelon 166.00 (165.70 to 166.70): ENG
Ion 165.00 (164.70 to 165.70): ENG
28.02
60000 :
40000 J
20000:
o :-
Time--> 27.80 27.90 28.00 28.10 28.20
Abundance
100000 .
rime-->
TIC: ENG13J5.D
50000 -
0
30130
30.40
30.50
#10
Fluorene
Concen: 1.09 ng/uL
RT: 28.02 min Scan# 2712
Delta R.T. -0.00 min
Lab File: ENG1335.D
Acq: 20 May 99 6:43 pm
Tgt Ion:166 Resp: 147425
Ion Ratio
166 100
165 79.1
0 0.0
0 0.0
Lower Upper
38.2
0.0
0.0
114.4
0.0
0.0
Abundancelon 188.00 (187.70 to 188.70): ENG
Ion 94.00 (93.70 to 94.70): ENG13
30.38
80000 :
60000 :
40000:
20000:
o:
rime-->
30.30
30:40
30.50
ENGT3T5TD PES1 .M
#11
Phenanthrene-dl0
Concen: 1.09 ng/uL
RT: 30.38 min Scan# 3070
Delta R.T. 0.00 min
Lab File: ENG1335.D
Acq: 20 May 99 6:43 pm
Tgt Ion:188 Resp: 169047
Ion Ratio
188 100
94 11.4
0 0.0
0 0.0
Lower Upper
15.1
0.0
0.0
45.1#
0.0
0.0
OG03327
Mon May 24 07:1U:47 1999
HP 5989B
Page 7
-------
Abundance
100000 -
Time-->30.30
TIC: ENG1335.D
50000 -
0
30.40
30150
lAbundancelon 178.00 (177.70 to 178.70)
100000^ 17g_00 dvs.vo to 176.70)
30.44
50000 .
ENG
ENG
Time-->30.30
30.40
-i 1 1 r
30150
#12
Phenanthrene
Concen: 1.08 ng/uL
RT: 30.44 min Scan# 3079
Delta R.T. 0.00 min
Lab File: ENG1335.D
Acq: 20 May 99 6:43 pm
Tgt Ion:178 Resp: 185367
Ion Ratio
178 100
176 16.7
0 0.0
0 0.0
Lower Upper
10.1 30.1
0.0 0.0
0.0 0.0
Abundance
100000 .
Time-->
TIC: ENG1335.D
50000 -
30.40
30150
30.60
30i70
Abundance ion 188.00 (187.70 to 188.70) :
Ion 94.00 (93.70 to 94.70): ENG13
80000 :
60000 .
40000 .
20000.
rime - - >
30.52
~\ 1 1 1 r
30.40
i—i—i—i—i—i—i—i—r
30150 30.60 30.70
ENG1JJS.D—PE5T71
#13
Anthracene-dlO
Concen: 1.06 ng/uL
RT: 30.52 min Scan# 3092
Delta R.T. 0.01 min
Lab File: ENG1335.D
Acq: 20 May 99 6:43 pm
Tgt Ion:188 Resp: 137822
Ion
188
94
0
0
Ratio
100
12.5
0.0
0.0
Lower Upper
15.1
0.0
0.0
45.1#
0.0
0.0
OCO)3-:3
Mon May 24 07:10:51 1999
HP 5989B
Page 8
-------
[Abundance
100000 .
TIC: ENG133S.D
Time-->30.40
50000 -
30.50
30.60
30.70
Ab
ENG
:ancelon 178.00 (177.70 to 178.VO)
000-,T~, 176.00 (175.70 to 176.70): ENG
30.57
50000 -
Time-->30.40
30:50
#14
Anthracene
Concen: 1.08 ng/uL
RT: 30.57 min Scan# 3099
Delta R.T. o.OO min
Lab File: ENG1335.D
Acq: 20 May 99 6:43 pm
Tgt Ion:178 Resp: 165881
Ion Ratio
178 100
176 15.6
0 0.0
0 0.0
Lower Upper
10.1 30.1
0.0 0.0
0.0 0.0
Abundance
80000
60000 :
40000:
20000:
rime-->
TIC: ENG1335.D
0
33.40
33.60
Abundancelon 212.00 (211.70 to 212.70)
Ion 106.00 (105.70 to 106.70)
33.51
60000 .
40000
20000 -
0 J
ENG
Time-->
33.40
33.60
ENG1335.DPES1.M
#15
Fluoranthene-dlO
Concen: 1.07 ng/uL
RT: 33.51 min Scan# 3610
Delta R.T. 0.00 min
Lab File: ENG1335.D
Acq: 20 May 99 6:43 pm
Tgt Ion:212 Resp: 146705
Ion
212
106
0
0
Ratio
100
15.1
0.0
0.0
Lower Upper
15.1
0.0
0.0
45.1
0.0
0.0
OCC3329
Won May 24 07:1U:54^ 1999
HP 5989B
Page 9
-------
Time-->
Sundance
80000 :
TIC: ENG1335.D
T 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1-
33.40 33.50 33.60 33.70
Abundancelon 202.00 (201.70 to 202 .70) : ENG
80000-'Ion 101.00 (100.70 to 101.70): ENG
33.56
60000 :
40000:
20000:
o:
rime-->
33.40 33.50 33.60 33.70
#16
Fluoranthene(CCC)
Concen: 1.08 ng/uL
RT: 33.56 min Scan# 3618
Delta R.T. 0.00 min
Lab File: ENG1335.D
Acq: 20 May 99 6:43 pm
Tgt Ion:202 Resp: 175543
Ion Ratio Lower Upper
202 100
101 13.6 13.6 40.6
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance
80000 :
60000:
40000:
20000:
Time--> 34.00 34.10 34.20 34.30
TIC: ENG133S.D
0
Sundance Ion 212.00 (211.70 to 212.70)
Ion 106.00 (105.70 to 106.70)
60000J 34.18
40000 .
20000 .
o:
ENG
ENG
Time--> 34.00 34.10 34.20 34.30
ENG1335.D PES1.M
Mon May 24 07:10:5V
#17
Pyrene-dlO
Concen: 1.07 ng/uL
RT: 34.18 min Scan# 3711
Delta R.T. -0.00 min
Lab File: ENG1335.D
Acq: 20 May 99 6:43 pm
Tgt Ion:212 Resp: 161395
Ion Ratio
212 100
106 17.7
0 0.0
0 0.0
Lower Upper
17.1
0.0
0.0
51.1
0.0
0.0
HP 5989B
Page 10
-------
Abundance
80000J
60000:
40000 -
20000:
TIC: ENG1335.D
Time--> 34.00
34.20
34.40
Abundance Ion 202.00 (201.70 to 202.70): ENG
Ion 101.00 (100.70 to 101.70): ENG
34.24
60000 :
40000:
20000 .
o:
Time--> 34.00
34.20
34.40
#18
Pyrene
Concen: 1.10 ng/uL
RT: 34.24 min Scan# 3719
Delta R.T. o.OO min
Lab File: ENG1335.D
Acq: 20 May 99 €:43 pm
Tgt Ion:202 Resp: 189968
Ion Ratio
202 100
101 15.6
0 0.0
0 0.0
Lower Upper
16.1
0.0
0.0
48.1#
0.0
0.0
Abundance
80000 :
60000 :
40000 -
20000 :
0
Time- ->
Abundance
40000 -
20000 .
0 .
Time-->
TIC: ENG1335.D
\ A
v_ / v
34130' 34140' ^Is'o' S^le'o' 34!7o'
Ion 244.00 (243.70 to 244.70): ENG
Ion 122.00 (121.70 to 122.70): ENG
34.50
A
11
34.30 34.40 34.50 34.60 34 70
#19
p-Terphenyl-d!4
Concen: 1.11 ng/uL
RT: 34.50 min Scantf 3759
Delta R.T. 0.01 min
Lab File.- ENG1335.D
Acq: 20 May 99 6:43 pm
Tgt Ion:244 Resp: 136350
Ion
244
122
0
0
Ratio
100
12.4
0.0
0.0
Lower Upper
13.6
0.0
0.0
40.6#
0.0
0.0
OCO )3ui
Mon May 24 07:11:00 1999
HP 5989B
Page 11
-------
Abundance
40000
30000 -
20000 :
Time--> 38.60 38.70 38.80 38.90
TIC: ENGl33b.D
10000 :
0
AbundanceIon 240.00 (239.70 to 240.70)
ENG
30000 .jlon 120.00 (119.70 to 120.70): ENG
38.78
20000 .
10000 -
Time--> 38.60 38170 38180 38190
#20
Benzo(a)anthracene-d!2
Concen: 1.01 ng/uL
RT: 38.78 min Scan# 4402
Delta R.T. 0.01 min
Lab File: ENG1335.D
Acq: 20 May 99 6:43 pm
Tgt Ion:240 Resp: 105864
Ion Ratio
240 100
120 13.1
0 0.0
0 0.0
Lower Upper
15.1
0.0
0.0
45.1#
0.0
0.0
TIC: ENG1335.D
Abundance
40000 :
30000 :
20000 :
10000 :
T—i—i—i—I—i—I—I—i—I—I—r
Time--> 38170 38.80. 38.90
Abundance I on 228.00 (227.70 to 228.70): ENG
Ion 114.00 (113.70 to 114.70): ENG
30000J 38.88
20000 J
10000 .
Time--> 38.70 38.80 38190 39.00
ENG1335.DPES1.M
#21
Benzo(a)anthracene
Concen: 1.00 ng/uL
RT: 38.88 min Scan# 4418
Delta R.T. -0.01 min
Lab File: ENG1335.D
Acq: 20 May 99 6:43 pm
Tgt Ion:228 Resp: 121781
Ion
228
114
0
0
Ratio
100
12.5
0.0
0.0
Lower Upper
12.6
0.0
0.0
37.6#
0.0
0.0
OC03362
Mon May 24 07:11:U3 1999
HP 5989B
Page 12
-------
Abundance
40000 :
30000:
20000 :
10000:
TIC: ENG1335.D
—i—i—i—i—|—i—i—i—i—I—i—i—i—i—I—i—i—i—i—|—i—i—r
Time-->38:?0 38.80 38.90 39.00 39.10
Abundance I on 240/00 (239.70 to 240.70): ENG
30000Jlon 120.00 (119.70 to 120.70): ENG
38.93
20000 -
10000 -
Time-->38.70 38.80 38.90 39.00 39.10
#22
Chrysene-dl2
Concen: 0.99 ng/uL
RT: 38.93 min Scan# 4426
Delta R.T. -0.01 min
Lab File: ENG1335.D
Acq: 20 May 99 6:43 pm
Tgt Ion:240 Resp: 101684
Ion Ratio
240 100
120 12.9
0 0.0
0 0.0
Lower Upper
15.1
0.0
0.0
45.1#
0.0
0.0
Abundance
40000 .
30000 .
20000 .
10000 -
Time-->
TIC: ENG1335.D
0
39.00
39.20
AbundanceIon 228.00 (227.70 to 228.70)
Ion 114.00 (113.70 to 114.70)
30000.
20000 .
10000.
o 4
Time--> 38.80
ENG1335.D—PES1.M
ENG
ENG
39.06
39100
39.20
#23
Chrysene(CCC)
Concen: 0.98 ng/uL
RT: 39.06 min Scan# 4445
Delta R.T. -0.01 min
Lab File: ENG1335.D
Acq: 20 May 99 6:43 pm
Tgt Ion:228 Resp: 122562
Ion
228
114
0
0
Ratio
100
9.2
0.0
0.0
Lower Upper
12.6
0.0
0.0
37.6#
0.0
0.0
Mon May 24 07:11:06 1999
HP 5989B
Page 13
-------
Abundance
40000 .
30000:
20000:
Time-->
TIC: ENG1335.D
10000:
45.60
45.80
Abundance Ion 264.00 (263.70 to 264.70)
20000JIon 132.00 (131.70 to 132.70)
ENG
ENG
15000 :
10000:
5000:
Time-->
45.60
45.80
#24
Benzo(b)fIuoranthene-dl2
Concen: 1.01 ng/uL
RT: 45.72 min Scan# 5468
Delta R.T. 0.01 min
Lab File: ENG1335.D
Acq: 20 May 99 6:43 pm
Tgt Ion:264 Resp: 100680
Ion Ratio Lower Upper
264 100
132 13.9 15.1 45.1#
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance
40000 :
30000 :
20000:
10000:
rime-->
TIC: ENG1335.D
45.70 45.80 45.90 46.00 46.10
Abundance Ion 252.00
Ion 126.00
20000 J
15000 :
10000:
5000:
o:
(251.70 to 252.70): ENG
(125.70 to 126.70): ENG
45.90
rime-->
4590 46o 46io
ENG1335.DPES1.M
#25
Benzo(b)fluoranthene
Concen: 0.96 ng/uL
RT: 45.90 min Scantf 5496
Delta R.T. -0.02 min
Lab File: ENG1335.D
Acq: 20 May 99 6:43 pm
Tgt Ion:252 Resp: 109561
Ion
252
126
0
0
Ratio
100
14.2
0.0
0.0
Lower Upper
12.6
0.0
0.0
37.6
0 .0
0 .0
OCC3354
Mon May 24 07:11:09
HP 5989B
Page 14
-------
TIC: ENGl33b.D
Time--> 45.60
45.80
46.00
46.20
Abundance ion 264.u6
20000JIon 132.00
(263.70 to 264.70): ENG
(131.70 to 132.70): ENG
45.91
15000 J
10000:
5000
Time--> 45.60
45.80
46.00
46.20
#26
Benzo(k)fIuoranthene-dl2
Concen: 0.96 ng/uL
RT: 45.91 min Scan# 5498
Delta R.T. -0.02 min
Lab File: ENG1335.D
Acq: 20 May 99 6:43 pm
Tgt Ion:264 Resp: 107135
Ion Ratio Lower Upper
264 100
132 14.0 15.1 45.1#
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance
40000 :
30000:
20000:
10000:
TIC: ENG1335.D
i—I—i—i—i—i—I—i—i—i—i—I—i—i—i—i I i~
Time--> 45.80 46.00 46.20 46.40
Abundancelon 252.00 (251.70 to 252.70): ENG
lion 126.00 (125.70 to 126.70): ENG
0
20000:
15000:
10000:
5000:
rime--> 45.80
ENGT3T5TDPES1.M
46.07
46.00 46.20 46.40
Mon May 24 07:11:12
#27
Benzo(k)fluoranthene
Concen: 0.99 ng/uL
RT: 46.07 min Scan# 5523
Delta R.T. -0.01 min
Lab File: ENG1335.D
Acq: 20 May 99 6:43 pm
Tgt Ion:252 Resp: 117948
Ion Ratio Lower Upper
252 100
126 15.7 12.6 37.6
0 0.0 0.0 0.0
0 0.0 0.0 0.0
OCi
HP 5989B
Page 15
-------
Abundance
20000 .
10000 -
Time--> 48.00
TIC: ENG1335.D
48.20
48.40
48.60
Abundance Ion 264.00 (263.70 to 264.70)
ENG
15000-lion 132.00 (131.70 to 132.70): ENG
48.37
10000 -
5000 _
Time--> 48.00
48.20
48.40
48.60
#28
Benzo(a)pyrene-d!2
Concen: 0.94 ng/uL
RT: 48.37 min Scan# 5874
Delta R.T. -0.01 min
Lab File: ENG1335.D
Acq: 20 May 99 6:43 pm
Tgt Ion:264 Resp: 88899
Ion Ratio
264 100
132 16.5
0 0.0
0 0.0
Lower Upper
15.1
0.0
0.0
45.1
0.0
0.0
Abundance
20000 -
10000 -
Time--> 48.20 48.40 48.60 48.80
TIC: ENG1335.D
Abundancelon 252.00 (251.70 to 252.70)
Ion 126.00 (125.70 to 126.70)
15000 J
10000 -
5000:
o:
ENG
ENG
rime--> 48.20 48.40 48.60 48.80
ENGTT3T7D PES1.M
#29
Benzo(a)pyrene(CCC)
Concen: 0.94 ng/uL
RT: 48.57 min Scantt 5906
Delta R.T. -0.01 min
Lab File: ENG1335.D
Acq: 20 May 99 6:43 pm
Tgt Ion:252 Resp: 110322
Ion Ratio
252 100
126 7.2
0 0.0
0 0.0
Lower Upper
12.6
0.0
0.0
37.6#
0.0
0.0
OCO 33-56
Mon May 24 07:ll:lb 1999
HP 5989B
Page 16
-------
(Abundance
30000 -
20000:
10000 -
Time- ->
TIC: ENG1335.D
61.00
61.50
Abundancelon 288.00 (287.70 to 288.70): 2NG
10000 -
61.19
5000 -
Time- ->
61.00
61150
#30
Indenod, 2, 3-cd)pyrene-dl2
Concen: 0.86 ng/uL m
RT: 61.19 min Scan# 8047
Delta R.T. -0.08 min
Lab File: ENG1335.D
Acq: 20 May 99 6:43 pm
Tgt Ion:288 Resp: 101333
Ion Ratio Lower Upper
288 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
ENG
Abundance
30000 -
20000 .
10000 -
0 '.
TIC: ENG1335.D
A
/^J V_
X ^^-v^-^^
Time--> 6lloo' ' ' '6l!so' ' ' 62loo'
Abundance
10000 .
5000 .
0 -
Time--> 6:
Ion 276.05 (275.75 to 276.75): ENG
Ion 138.00 (137.70 to 138.70): ENG
61.54
. -_ - ^.^^^ ^^^^^^-^'^-J^^n^AVWMv,
iloo' ' ' 'eilso' ' ' '62loo'
1335. D PES1.M Mon May 24 07:11:19 1999
#31
Indeno ( 1 , 2 , 3 - cd) pyrene
Concen: 0.82 ng/uL m
RT: 61.54 min Scan# 8113
Delta R.T. -0.08 min
Lab File: ENG1335.D
Acq: 20 May 99 6:43 pm
Tgt Ion: 276. 05 Resp: 106294
Ion Ratio Lower Upper
276 100
138 45.2 32.1 96.1
0 0.0 0.0 0.0
0 0.0 0.0 0.0
OCC 3357
HP 5989B Page 17
-------
Time-->
Abundancelon 292.00 (291.70 to 292.70): ENG
8000 :
6000 J
4000:
2000:
61.16
Time-->
61.00
61.50
Abundance
30000 :
20000:
10000 -
Time-->
TIC: ENG1335.D
0
T—i—i—i—I—I—r
61.20
r • i—i—i—r
61.40
~1 1 1 1" 1
61.60
T—\—I—i—I—i—I—I—i—r
61.80 62.00
Abundancelon 278.00 (277.70 to 278.70): ENG
Ion 139.00 (138.70 to 139.70): ENG
#32
Dibenz(a,h)anthracene-d!4
Concen: 0.84 ng/uL m
RT: 61.16 min Scan# 8042
Delta R.T. -0.04 min
Lab File: ENG1335.D
Acq: 20 May 99 6:43 pm
Tgt Ion:292 Resp: 64990
Ion Ratio Lower Upper
292 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
10000-
61.55
5000 .
Time-->
H—i—i—|—i—i—i—i—I—i—i—i—i—|—I—I—i—i—I—|—i—I—i
61.20 61.40 61.60 61.80 62.00
ENG1335.DPES1.M
Mon May 24 07:11:22
#33
Dibenz(a,h)anthracene
Concen: 0.79 ng/uL m
RT: 61.55 min Scantf 8115
Delta R.T. -0.08 min
Lab File: ENG1335.D
Acq: 20 May 99 6:43 pm
Tgt Ion:278 Resp: 92113
Ion
278
139
0
0
Ratio
100
41.6
0.0
0.0
Lower Upper
12.6
0.0
0.0
37.6#
0.0
0 .0
OC032::3
HP 5989B
Page 18
-------
Abundance
15000 J
10000 .
5000 -
Time-->
TIC: ENG1335.D
1 1 r
65.00
(Abundance I on 288.00 {287.70 to 288.70): ENG
10000J
64.75
5000 .
0 .
Time-->
64.50
65.00
#34
Benzo(g,h,i)perylene-d!2
Concen.- 0.84 ng/uL m
RT: 64.75 min Scan# 8752
Delta R.T. -0.03 min
Lab File: ENG1335.D
Acq: 20 May 99 6:43 pm
Tgt Ion:288 Resp: 84466
Ion Ratio
288 100
0 0.0
0 0.0
0 0.0
Lower Upper
0.0
0.0
0.0
0.0
0.0
0.0
Abundance
15000 -
10000 J
5000 -
0
Time-->64 !
TIC: ENG1335.D
65.00
65.50
Abundance Ion 276.00 (275.70 to 276.70): ENG
Ion 138.00 (137.70 to 138.70): ENG
10000 .
5000.
0 .
65.13
Time-->64.50
65100
65.50
ENG1335.DPES1.M
#35
Benzo(g,h,i)perylene
Concen: 0.86 ng/uL m
RT: 65.13 min Scan# 8847
Delta R.T. -0.06 min
Lab File: ENG1335.D
Acq: 20 May 99 6:43 pm
Tgt Ion:276 Resp: 104760
Ion Ratio
276 100
138 43.3
0 0.0
0 0.0
Lower Upper
10.1
0.0
0.0
40.1
0.0
0.0
0003359
Mon May 24 07:ll:2t> 1999
HP 5989B
Page 19
-------
Quantisation Report
Data File
Acq On
Sample
Misc
C:\HPCHEM\1\DATA\9919\ENG1336.D
2 0 May 99 7:5 9 pm
PES-MAH-051299-04 2.5ng/uL
Quant Time: May 24 7:17 1999
Vial: 5
Operator: JEMcCartney
Inst : HP 5989B
Multiplr: 1.00
Method
Title
Last Update
Response via
C:\HPCHEM\1\METHODS\PES1.M
Mon May 24 07:17:45 1999
Multiple Level Calibration
Internal Standards
R.T. Qlon Response Cone Units Dev(Min)
1)
2 , 2 -Dif luorobiphenyl
24
.54
190
593687
5
.00
System Monitoring Compounds
2)
4)
5)
7)
9)
11)
13)
15)
17)
19)
20)
22)
24)
26)
28)
30)
32)
34)
Naphthalene -d8
2 -Methlynaphthalene-dlO
Acenaphthylene-d8
Acenaphthene - dl 0
Fluorene-dlO
Phenanthr ene - dl 0
Anthracene -dlO
Fluoranthene -dlO
Pyrene-dlO
p-Terphenyl-d!4
Benzo (a) anthracene-d!2
Chrysene-dl2
Benzo (b) f Iuoranthene-dl2
Benzo (k) fluoranthene-d!2
Benzo (a) pyrene-d!2
Indenod, 2, 3-cd)pyrene-dl2
Dibenz (a, h) anthracene-d!4
Benzo (g, h, i)perylene-d!2
22
23
26
26
27
30
30
33
34
34
38
38
45
45
48
61
61
64
.19
.91
.23
.66
.95
.38
.52
.51
.18
.50
.77
.93
.71
.91
.36
.20
.13
.73
136
152
160
164
176
188
188
212
212
244
240
240
264
264
264
288
292
288
558154
287534
447460
340843
296495
363899
300004
322824
359268
287517
238586
241808
221541
251910
207321
231272
155856
217573
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
.56
.54
.50
.52
.51
.51
.48
.52
.56
.51
.44
.51
.38
.40
.34
.08
.15
.34
Target Compounds
3)
6)
8)
10)
12)
14)
16)
18)
21)
23)
25)
27)
29)
31)
33)
35)
Naphthalene (CCC)
Acenaphthylene
Acenaphthene (CCC)
Fluorene
Phenanthrene
Anthracene
Fluoranthene (CCC)
Pyrene
Benzo (a) anthracene
Chrysene(CCC)
Benzo (b) fluoranthene
Benzo (k) fluoranthene
Benzo (a) pyrene (CCC)
Indenod, 2, 3 -cd) pyrene
Dibenz (a, h) anthracene
Benzo (g,h, i)perylene
22
26
26
28
30
30
33
34
38
39
45
46
48
61
61
65
.24
.27
.74
.02
.44
.57
.56
.24
.88
.06
.91
.07
.57
.53
.56
.13
128
152
154
166
178
178
202
202
228
228
252
252
252
276
278
276
584957
457422
306461
318009
400876
359734
388839
409533
274468
291572
249877
275578
251341
279754
249720
257684
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
.55
.54
.49
.52
.50
.49
.55
.53
.42
.50
.34
.45
.30
.33
.33
.28
Oi
ng/uL 0 ,
.00
% Re co very
ng/uL #
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL #
ng/uL #
ng/uL
ng/uL
ng/uL #
ng/uL #
ng/uL #
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL m
ng/uL m
Qvalue
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL#
ng/uL#
ng/uL#
ng/uL#
ng/uL
ng/uL
ng/uL
ng/uLm
ng/uLm
ng/uLm
u>U -fvlr'C t>
96
96
98
96
93
91
73
70
75
72
79
78
80
18
50
50
(#) = qualifier out of range (m) = manual integration
ENG1336.D PES1.M Mon May 24 07:22:04 1999 HP 5989B
Page 1
-------
Quantitation Report
t File : C:\HPCHEM\1\DATA\9919\ENG1336.D
:c On : 20 May 99 7:59 pm
imple : PES-MAH-051299-04 2.5ng/uL
a .it Time: May 24 7:17 1999
et-.hod : C:\HPCHEM\1\METHODS\PES1.M
M le :
,&ot Update : Mon May 24 07:17:45 1999
Response via : Multiple Level Calibration
Vial: 5
Operator: JEMcCartney
Inst : HP 5989B
Multiplr: l.OO
u dance
300000 _
'50000 .
200000 _
150000-
100000 -
50000 -
0
Time-->
TIC: ENG1336.D
2
5
4f
4
6 10
•
5
•
^— J
3
5
9
3
12
14
i:
i:
5
e. IB
s 16
1
s
If
• •
s
/
s
Is
21 2^
22s
23
20s
:? 31
2^ s 29
28s ifi-i
I 35
L7
1 — i . , l[-^i
U\ I^-J^ 1 \]\
1 ' " ~~1 i [ r ( i ] - r I 7 T — ! ! ! 1 ] 1 [ 1 1 1 T 7 1
20 00 30 00 40.00 50.00 60.00
ENG1336.D PES1.M
Mon May 24 07:22:13 1999
HP 5989B
Page 2
-------
Abundance
200000 .
100000 .
Time-->
TIC: ENG1336.D
22.00
22.20
22.40
Abundancelon 136.00 (135.70 to 136.70): ENG
Ion 68.00 (67.70 to 68.70): ENG13
200000 .
100000 .
0 -
22.19
Time-->
"^—I—r
22loO
-i 1 r
22.20
22.40
Abundance
200000 .
100000 -
rime-->
TIC: ENG133S.D
0
22.00
22! 26
~i 1 1 1 r-
22.40
#2
Naphthalene-d8
Concen: 2.56 ng/uL
RT: 22.19 min Scan# 1559
Delta R.T. 0.01 min
Lab File: ENG1336.D
Acq: 20 May 99 7:59 pm
Tgt Ion:136 Resp:
Ion Ratio Lower
100
136
68
0
0
7.3
0.0
0.0
10.1
0.0
0.0
558154
Upper
30. l#
0.0
0.0
Abundancelon 128.00 (127.70 to 128.70): ENG
Ion 127.00 (126.70 to 127.70): ENG
200000 .
100000 .
0-
22.24
rime-->
"•—i—'
22.00
~i I 1 1 1 1 1 1 1 r
22.20 22!40
ENG1336.D PES1.M
#3
Naphthalene(CCC)
Concen: 2.55 ng/uL
RT: 22.24 min Scan# 1567
Delta R.T. 0.01 min
Lab File: ENG1336.D
Acq: 2 0 May 99 7:59 pm
Tgt Ion:128 Resp: 584957
Ion
128
127
0
0
Ratio
100
11.5
0.0
0.0
Lower Upper
0.0
0.0
0.0
60.0
0.0
0.0
Mon May 24 07:22:16 1999
HP 5989B
Page 3
-------
Abundance
100000 .
50000 -
0
Time-->
TIC: ENG1336.D
-i 1 1 1 1 i 1 1 1 1 1 1 1 1 1 1 1 —
23 80 23.90 24.00
Abundancelon 152.00 (151.70 to 152.70): ENG
•
100000 -
50000 -
0 .
Time- ->
23.91
A
_J \
23 80 ' 23190 ' ' 24lo6
Abundance
200000 .
•
100000 .
0 .
Time-->
Abundance
200000 .
150000 .
100000 -
50000 .
0 .
rime-->
TIC: ENG1336.D
l\
I
1
/ \
J \_
26.00 ' ' 26120 ' ' 26140
Ion 160.00 (159.70 to 160.70): ENG
26.23
A
j \
26 00 26.20 26.40
#4
2-M(
Con<
RT:
T"\£O 4
Del i
Lab
Acq
Tgt
Ion
152
0
0
0
#5
Ace
Con
RT:
Del
LJtZJ-
Lab
Acq
Tgt
Ion
160
0
0
0
2-Methlynaphthalene-dlO
Concen: 2.54 ng/uL
.91 min Scan# 1910
R.T. 0.01 min
le: ENG1336.D
Acq: 20 May 99 7:59 pm
Tgt Ion:152 Resp:
Ratio Lower
100
0.0
0.0
0.0
0.0
0.0
0.0
287534
Upper
0.0
0.0
0.0
Acenaphthylene-d8
Concen: 2.50 ng/uL
26.23 min Scan# 2441
a R.T. 0 . 00 min
File: ENG1336.D
Acq: 20 May 99 7:59 pm
Tgt Ion: 160 Resp:
Ratio Lower
100
0.0 0.0
0.0 0.0
0.0 0.0
447460
Upper
0.0
0.0
0.0
ENG1336.D PES1.M
Mon May 24 07:22:19 1999
HP S989B
Page 4
-------
Abundance
200000 -
100000 .
TIC: ENG1336.D
Titne-->
0
26.10 26.20 26.30 26.40
Abundance Ion 152.00 (151.70 to 152.70):
Ion 153.00 (152.70 to 153.70):
200000J 26'27
150000 .
100000:
50000 -
0 -
ENG
ENG
rime-->
26.10 26.20 26.30
26.40
Abundance
200000 :
150000 J
100000:
50000:
Time-->26 .50
TIC: ENG1336.D
0
26.60
26.70
26180
#6
Ac enapht hy1 ene
Concen: 2.54 ng/uL
RT: 26.27 min Scantf 2446
Delta R.T. 0.00 min
Lab File: ENG1336.D
Acq: 20 May 99 7:59 pm
Tgt Ion:152 Resp: 457422
Ion Ratio Lower Upper
152 100
153 13.3 7.6 22.6
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance Ion 164.00 (163.70 to 164.70): ENG
100000-
50000 -
26.66
Time-->26.50
26.60
26.80
ENGT3T6TD PES1 .M
#7
Acenaphthene-dlO
Concen: 2.52 ng/uL
RT: 26.66 min Scan# 2504
Delta R.T. 0.01 min
Lab File: ENG1336.D
Acq: 2 0 May 99 7:5 9 pm
Tgt Ion:164 Resp:
Ion Ratio Lower
100
164
0
0
0
0.0
0.0
0.0
0.0
0.0
0.0
340843
Upper
0.0
0 .0
0.0
OCC3364
Mon May 24 07:22:22 1999
HP 5989B
Page 5
-------
[Abundance
TIC: ENG1336.D
Time-->
26.60
26.70
26.80
26190
Abundance I on 154.00 (153.70 to 154.70): ENG
150000HIon 153.00 (152.70 to 153.70): ENG
100000 .
50000 .
0 .=
26.74
Time-->
26.60
26.70
26.80
26.90
Abundance
200000 -
100000 -
Time-->
TIC: ENG13367D
i—i—I—i—i—i—i—I—i—i—i—i—I—i—i—i—i—|—i—i—r
27.80 27.90 28.00 28.10
#8
Acenaphthene(CCC)
Concen-. 2.49 ng/uL
RT: 26.74 min Scantt 2516
Delta R.T. o.Ol min
Lab File: ENG1336.D
Acq: 20 May 99 7:59 pm
Tgt Ion:154 Resp: 306461
Ion Ratio
154 .100
153 84.9
0 0.0
0 0.0
Lower Upper
43.5
0.0
0.0
130.3
0.0
0.0
Abundancelon 176.00 (175.70 to 176.70): ENG
150000 J
100000J
50000 .
0.
27.95
Time-->
I I | I I I I | 1 1 l~—I 1 1 1 1 I I 1 1 1 T
27.80 27.90 28.00 28.10
ENG1JJ6.D PES1.M
Mon May 24 07:22:2b
#9
Fluorene-dlO
Concen: 2.51 ng/uL
RT: 27.95 min Scan# 2699
Delta R.T. -0.00 min
Lab File: ENG1336.D
Acq: 20 May 99 7:59 pm
Tgt Ion: 176 Resp: 296495
Ion Ratio Lower Upper
100
0.0 0.0
0.0 0.0
0.0 0.0
176
0
0
0
0.0
0.0
0.0
HP 5989B
Page 6
-------
Abundance
200000 .
100000 -
Time--> 27.80 27.90 28.00 28.10 28.20
TIC: ENG1336.D
Abundance Ion 166.00 (165.70 to 166.70) : ENG
Ion 165.00 (164.70 to 165.70): ENG
150000 -
100000 .
50000 .
o:
28.02
Time--> 27.80 27.90 28.00 28.10 28.20
#10
Fluorene
Concen: 2.52 ng/uL
RT: 28.02 min Scan# 2710
Delta R.T. -0.00 min
Lab File: ENG1336.D
Acq: 20 May 99 7:59 pm
Tgt Ion:166 Resp: 318009
Ion Ratio Lower Upper
166 100
165 79.6 38.2 114.4
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance
200000 J
150000:
100000:
50000:
Time-->
TIC: ENG1336.D
iolso
30.40
30.50
[Abundancelon 188.00 (187.70 to 188.70): ENG
Ion 94.00 (93.70 to 94.70): ENG13
30.38
150000 J
100000 :
50000:
o:
Time-->
30.30
30.40
30.50
ENGTTJ5TD PES1.M
#11
Phenanthrene-dlO
Concen: 2.51 ng/uL
RT: 30.38 min Scan# 3068
Delta R.T. 0.00 min
Lab File: ENG1336.D
Acq: 20 May 99 7:59 pm
Tgt Ion:188 Resp: 363899
Ion
188
94
0
0
Ratio
100
11.1
0.0
0.0
Lower Upper
15.1
0.0
0.0
45.1#
0.0
0.0
OCC336Q
Mon May 24 Q7:22:2V 1999
HP 5989B
Page 7
-------
[Abundance
200000H
TIC: ENG1336.D
Time--> 30.30
-i 1 r
30.40
Abundance Ion 178.00 (177.70 to 178.70): ENG
200000-,Ion 176.00 (175.70 to 176.70): ENG
30.44
150000 J
100000:
50000:
Time--> 30.30
30:40
30.50
#12
Phenanthrene
Concen: 2.50 ng/uL
RT: 30.44 min Scan# 3077
Delta R.T. 0.00 min
Lab File: ENG1336.D
Acq: 20 May 99 7:59 pm
Tgt Ion:178 Resp: 400876
Ion Ratio
178 100
176 16.6
0 0.0
0 0.0
Lower Upper
10.1
0.0
0.0
30.1
0.0
0.0
Acundance
200000J
Time-->
TIC: ENG1336.D
30.40
30.60
Abundance Ion 188.00 (187.70 to 188.70) : ENG
Ion 94.00 (93.70 to 94.70): ENG13
150000 .
100000 -
50000.
30.52
-> 30.40 30160
ENG1336.D PES1.M Mon May 24 07:22:30 1999'
#13
Anthracene-dlO
Concen: 2.48 ng/uL
RT: 30.52 min Scan# 3089
Delta R.T. 0.00 min
Lab File: ENG1336.D
Acq: 20 May 99 7:59 pm
Tgt Ion:188 Resp: 300004
Ion Ratio
188 100
94 12.5
0 0.0
0 0.0
Lower Upper
15.1
0.0
0.0
45.1#
0.0
0.0
HP 5989B
OCO'Kv
Page 8
-------
(Abundance
i 200000J
150000:
100000:
50000:
TIC: ENG13Jb.D
Time--> 30.40
30.50
30.60
iolvo
Abundancelon 178.00 (177.70 to 178.70): ENG
2000001Ion 176.00 (175.70 to 176.70): ENG
30.57
isoooo:
100000:
50000:
Time--> 30.40
Anthracene
Concen: 2.49 ng/uL
RT: 30.57 min Scantf 3097
Delta R.T. 0.00 min
Lab File: ENG1336.D
Acq: 20 May 99 7:59 pm
Tgt lon:178 Resp: 359734
Ion Ratio Lower Upper
178 100
176 16.0 10.1 30.1
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance
150000 '.
100000 -
50000:
Time--> 33.30 33!40 33.50 33.60 33.70
TIC: ENG1336.D
0
Abundancelon 212.00 (211.70 to 212.70):
Ion 106.00 (105.70 to 106.70): ENG
33.51
100000 -
50000
0 .
-i—i—i—i—i—i—r—i—i—i—i—i—i—i—i—i—i—i—i—|—i i
Time--> 33i30 33.40 33.50 33.60 33.70
ENG1336.DPES1.M
Mon May 24 07:22:33
#15
Fluoranthene-dl0
Concen: 2.52 ng/uL
RT: 33.51 min Scan# 3608
Delta R.T. 0.00 min
Lab File: ENG1336.D
Acq: 20 May 99 7:59 pm
Tgt Ion:212 Resp: 322824
Ion
212
106
0
0
Ratio
100
15.4
0.0
0.0
Lower Upper
15.1
0.0
0.0
45 .1
0.0
0.0
OCC33c3
HP 5989B
Page 9
-------
(Abundance
150000 J
100000:
50000:
TIC: ENG1336.D
Time-->
33.40
33.60
33!80
Abundance Ion 202.00 (201.70 to 202.70): ENG
Ion 101.00 (100.70 to 101.70): ENG
150000 .
100000 J
50000 J
o:
33.56
Time-->
33.40
33.60
33.80
Abundance
150000 .
100000:
50000:
TIC: ENG1336TD
0
Time-->
34.00
34.20
34.40
#16
Fluoranthene(CCC)
Concen: 2.55 ng/uL
RT: 33.56 min Scant 3616
Delta R.T. 0.00 min
Lab File: ENG1336.D
Acq: 20 May 99 7:59 pm
Tgt Ion:202 Resp: 388839
Ion Ratio
202 100
101 13.0
0 0.0
0 0.0
Lower Upper
13.6
0.0
0.0
40. 6#
0.0
0.0
Abundancelon 212.00 (211.70 to 212.70): ENG
Ion 106.00 (105.70 to 106.70): ENG
100000-
50000-
0 .
34.18
Time-->
34.00
34120
-i 1 1 r
34.40
ENG1336.D—PES1.M
Mon May 24 07:22:36 1999
#17
Pyrene-dlO
Concen: 2.56 ng/uL
RT: 34.18 min Scan# 3709
Delta R.T. 0.00 min
Lab File: ENG1336.D
Acq: 20 May 99 7:59 pm
Tgt Ion:212 Resp: 359268
Ion
212
106
0
0
Ratio
100
17.1
0.0
0.0
Lower Upper
17.1
0.0
0.0
51.1
0.0
0.0
OCC3369
HP 5989B
Page 10
-------
Abundance
150000 :
100000 J
50000:
Titne--> 34.00 34.10 34.20 34.30 34.40
TIC: ENGlJJb.D
Abundance Ion 202.00 (201.70 to 202.70): ENG
Ion 101.00 (100.70 to 101.70): ENG
150000 .
100000 -
50000 J
0 -
34.24
Time-->34.00 34.10 34.20 34.30 34.40
#18
Pyrene
Concen: 2.53 ng/uL
RT: 34.24 min Scan# 3717
Delta R.T. 0.00 min
Lab File: ENG1336.D
Acq: 20 May 99 7:59 pm
Tgt Ion:202 Resp: 409533
Ion Ratio Lower Upper
202 100
101 15.1 16.1 48.'1#
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance
150000 -
100000:
50000:
Time- ->
TIC: ENG1336.D
0
34.40
34.60
Abundancelon 244.00 (243.70 to 244.70)
Ion 122.00 (121.70 to 122.70)
100000J 34.50
50000 .
0 .
ENG
ENG
Time-->
34.40
341 60
ENG1336.DPES1.M
#19
p-Terphenyl-d!4
Concen: 2.51 ng/uL
RT: 34.50 min Scan# 3757
Delta R.T. 0.01 min
Lab File: ENG1336.D
Acq: 20 May 99 7:59 pm
Tgt Ion:244 Resp: 287517
Ion Ratio
244 100
122 13.1
0 0.0
0 0.0
Lower Upper
13.6
0.0
0.0
40. 6
0.0
0.0
Mon May 24 07:22:39 1999
OCO370
HP 5989B Page 11
-------
[Abundance
80000 :
60000 :
40000 :
20000:
TIC: ENG1336.D
0
Time--> 38.60
38.70
38.80
38.90
^bundancelon 240.00 (235.70 to 240.70): ENG
Ion 120.00 (119.70 to 120.70): ENG
60000 -
40000 J
20000 -
Time--> 38.60
38.77
38.70
38.80
38.90
Time-->
oandance
80000
TIC: ENG1336.D
38.70 38.80 38.90 39100
Abundancelon 228.00 (227.70 to 228.70)
Ion 114.00 (113.70 to 114.70)
38.88
60000 J
40000 J
20000:
o:
ENG
ENG
#20
Benzo(a)anthracene-d!2
Concen: 2.44 ng/uL
RT: 38.77 min Scan# 4399
Delta R.T. 0.00 min
Lab File: ENG1336.D
Acq: 20 May 99 7:59 pm
Tgt Ion: 240 Resp-. 238586
Ion Ratio Lower Upper
240 100
120 13.4 15.1 45.1#
0 0.0 0.0 0.0
0 0.0 0.0 0.0
fTime--> 38.70 38.80 38.90 39.00
ENG1336.DPES1.M
#21
Benzo(a)anthracene
Concen: 2.42 ng/uL
RT: 38.88 min Scan# 4416
Delta R.T. -0.01 min
Lab File: ENG1336.D
Acq: 20 May 99 7:59 pm
Tgt Ion:228 Resp: 274468
Ion Ratio
228 100
114 12.6
0 0.0
0 0.0
Lower Upper
12 .6
0.0
0.0
37.6#
0.0
0.0
OCO)3vi
Mon May 241)7:22:42 1999
HP 5989B
Page 12
-------
Abundance
rime-->
TIC: ENG1336.D
40000:
20000:
o
38.80
39.00
Abundance Ion 240.00 (239.70 to 240.70)
Ion 120.00 (119.70 to 120.70)
60000 .
40000 .
20000 .
0 '.
ENG
ENG
38.93
Time-->
38.80
39:00
#22
Chrysene-dl2
Concen-. 2.51 ng/uL
RT: 38.93 min Scantf 4424
Delta R.T. -0.01 min
Lab File: ENG1336.D
Acq: 20 May 99 7:59 pm
Tgt Ion:240 Resp: 241808
Ion
240
120
0
0
Ratio
100
12.0
0.0
0.0
Lower Upper
15.1
0.0
0.0
45.1#
0.0
0.0
Abundance
80000 :
60000 :
40000 :
20000:
rime-->
TIC: ENG1336.D
0
s'slsb
39.00
39.20
Abundancelon 228.00 (227.70 to 228.70)
Ion 114.00 (113.70 to 114.70)
39.06
60000J
40000:
20000:
Time-->
ENG
ENG
38.80
39.00
39.20
ENGTJJ6TD PES1.M
#23
Chrysene(CCC)
Concen: 2.50 ng/uL
RT: 39.06 min Scan# 4444
Delta R.T. 0.00 min
Lab File: ENG1336.D
Acq: 20 May 99 7:59 pm
Tgt Ion:228 Resp: 291572
Ion
228
114
0
0
Ratio
100
10.9
0.0
0.0
Lower Upper
12.6
0.0
0.0
37. 6
0.0
0.0
OCC3372
Mon May 24 07:22:45 1999
HP 5989B
Page 13
-------
[Abundance
80000 :
TIC: ENG1336.D
Time-->
45.60
45.80
Abundancelon 264.00 (263.70 to 264.vu;
Ion 132.00 (131.70 to 132.70)
40000:
45.71
30000 J
20000 :
10000
o:
"ERG1
ENG
Time- ->
45.60
45.80
#24
Benzo(b)fIuoranthene-dl2
Concen: 2.38 ng/uL
RT: 45.71 min Scantf 5465
Delta R.T. -0.00 min
Lab File: ENG1336.D
Acq: 20 May 99 7:59 pm
Tgt Ion:264 Resp: 221541
Ion Ratio Lower Upper
264 100
132 15.2 15.1 45.1
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance
80000:
60000
40000 :
20000
Time-->
TIC: ENG1336.D
45.80
46.00
[AbundanceIon 252.00 (251.70 to 252.707
Ion 126.00 (125.70 to 126.70)
400004 45'91
30000:
20000:
10000:
o:
ENG
ENG
Time-->
45.80
46.00
ENG1336.DPES1. M
#25
Benzo(b)fluoranthene
Concen: 2.34 ng/uL
RT: 45.91 min Scan# 5495
Delta R.T. -0.01 min
Lab File: ENG1336.D
Acq: 20 May 99 7:59 pm
Tgt Ion:252 Resp: 249877
Ion Ratio
252 100
126 14.6
0 0.0
0 0.0
Lower Upper
12.6
0.0
0.0
37.6
0.0
0.0
occ
> 6
Mon May 24 07:22:48 1999
HP 5989B
Page 14
-------
Abundance
80000 .
60000 :
40000 :
20000:
—] 1 1 1 1 1 1 1 1" • 'i [ 1 1 1 ! 1 r~
Time--> 45.60 45.80 46.00 46.20
TIC: ENG1336.D
Abundancelon 264.00 (263.70 to 264.70): ENG
Ion 132.00 (131.70 to 132.70): ENG
40000 .
30000 :
20000:
10000:
0 j
Time--> 45.60
45.91
45.80
46.00
46.20
#26
Benzo(k)fIuoranthene-dl2
Concen: 2.40 ng/uL
RT: 45.91 min Scan# 5495
Delta R.T. -0.03 min
Lab File: ENG1336.D
Acq: 20 May 99 7:59 pm
Tgt Ion:264 Resp: 251910
Ion Ratio Lower Upper
264 100
132 18.2 15.1 45.1
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance
80000.
60000 .
40000.
20000-
Time - - >
TIC: ENG13357D
0
45.80
46.00
46.20
46.40
Abundance!on 252.00 (251.70 to 252.70)
Ion 126.00 (125.70 to 126.70)
400004 46'07
ENG
46.00
46:20
46.40
ENGTJJ5TD PES1 .M
Mon May 24 07:22:52
#27
Benzo(k)fluoranthene
Concen: 2.45 ng/uL
RT: 46.07 min Scan# 5520
Delta R.T. -0.02 min
Lab File: ENG1336.D
Acq: 2 0 May 99 7:59 pm
Tgt Ion:252 Resp: 275578
Ion
252
126
0
0
Ratio
100
13.7
0.0
0.0
Lower Upper
12.6
0.0
0.0
37.6
0.0
0.0
0003374
HP 5989B
Page 15
-------
(Abundance
1
40000 :
30000:
20000:
10000:
TIC: ENG1336.D
Time--> 48.00
Abundance Ion 264.00 (263.70 to 264.70)
48.20
48.40
48.60
ENG
30000 .
20000.
10000 -
0 -
Ion 132.00 (131.70 to 132.70): ENG
48.36
|Time--> 48.00 48.20 48.40 48.60
TIC: ENG1336.D
Abundance
40000J
30000:
20000 :
10000 -
Time--> 48.20 48.40 48.60 48.80
#28
Benzo(a)pyrene-d!2
Concen: 2.34 ng/uL
RT: 48.36 min Scan# 5871
Delta R.T. -0.01 min
Lab File: ENG1336.D
Acq: 2 0 May 99 7:59 pm
Tgt Ion:264 Resp: 207321
Ion Ratio
264 100
132 15.9
0 0.0
0 0.0
Lower Upper
15.1
0.0
0.0
45.1
0.0
0.0
[Abundanceion 252.00 (251.70 to 252.70)
Ion 126.00 (125.70 to 126.70)
48.57
30000
20000J
10000 .
0 .
ENG
ENG
Time--> 48.20 48.40 48.60 48.80
ENG1336.DPES1.M
#29
Benzo(a)pyrene(CCC)
Concen: 2.30 ng/uL
RT: 48.57 min Scan# 5904
Delta R.T. -0.01 min
Lab File: ENG1336.D
Acq: 20 May 99 7:59 pm
Tgt Ion:252 Resp: 251341
Ion Ratio
252 100
126 14.8
0 0.0
0 0.0
Lower Upper
12.6
0.0
0.0
37.6
0.0
0.0
Mon May 24 07:22:55 1999
HP 5989B
Page 16
-------
rime-->
TIC: ENG1336.D
40000-
20000.
'sbia'o' 'si!bo 61.20 si.40 si.so
Abundance Ion 288.00 (287.70 to 288.70): ENG
20000.
61.20
Time-->
60.80 61.00 61.20 61.40 61.60
#30
Indeno(1,2,3-cd)pyrene-d!2
Concen: 2.08 ng/uL
RT: 61.20 min Scan# 8047
Delta R.T. -0.07 min
Lab File: ENG1336.D
Acq: 20 May 99 7:59 pm
Tgt Ion:288 Resp: 231272
Ion Ratio Lower Upper
288 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Time--> 61.00
TIC: ENG1335.D
61150
62.00
^bundancelon 276.05 (275.75 to 276.75):
Ion 138.00 (137.70 to 138.70):
61.53
20000 .
10000 -
ENG
Time--> 61.00
61.50
62.00
ENG1336-DPES1.M
#31
Indeno(1,2,3 -cd)pyrene
Concen: 2.33 ng/uL m
RT: 61.53 min Scan# 8109
Delta R.T. -0.09 min
Lab File: ENG1336.D
Acq: 2 0 May 99 7:5 9 pm
Tgt Ion:276.05 Resp: 27975.
Ion
276
138
0
0
Ratio
100
34.8
0.0
0.0
Lower Upper
32 .1
0.0
0.0
96.1
0.0
0.0
OCO
Mon May 24 07:22:58 1999
HP 5989B
Page 17
-------
TIC: ENG1336.D
Time-->
Abundancelon 292.00 (291.70 to 292.70): ENG
40000 -
20000
-1 1 :
61.00
61.50
15000 -
10000 -
5000 -
Time-->
61.13
61.00
61.50
'#32
Dibenz(a,h)anthracene-d!4
Concen: 2.15 ng/uL m
RT: 61.13 min Scant 8035
Delta R.T. -0.07 min
Lab File: ENG1336.D
Acq: 20 May 99 7:59 pm
Tgt Ion:292 Resp: 155856
Ion Ratio Lower Upper
292 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
TIC: ENG1336.D
Time-->
61.00
61.50
62.00
Abundancelon 278.00 (277.70 to 278.70): ENG
Ion 139.00 (138.70 to 139.70): ENG
20000 :
15000:
10000:
sooo:
Time-->
61.56
61.00
61.50
62.00
ENG1336.DPES1.M
Mon May 24 1)7:^:02
#33
Dibenz(a,h)anthracene
Concen: 2.33 ng/uL m
RT: 61.56 min Scan# 8115
Delta R.T. -0.06 min
Lab File: ENG1336.D
Acq: 20 May 99 7:59 pm
Tgt Ion:278 Resp: 249720
Lower Upper
Ion
278
139
0
0
Ratio
100
28.1
0.0
0.0
12.6
0.0
0.0
37.6
0.0
0.0
t t
HP 5989B
Page 18
-------
Abundance
20000 .
10000-
rime-->64.00
TIC: ENG1336.D
64.50
65.00
Abundancelon 288.00 (287.70 to 288.70): ENG
15000 :
10000:
5000:
o:
64.73
Time-->64.00
64.50
65.00
#34
Benzo(g,h,i)perylene-d!2
Concen: 2.34 ng/uL m
RT: 64.73 min Scan# 8747
Delta R.T. -0 .05 min
Lab File: ENG1336.D
Acq: 20 May 99 7:59 pm
Tgt Ion:288 Resp: 217573
Ion Ratio Lower Upper
288 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance
20000-
10000 -
TIC: ENG1336.D
Time--> 64.50
Abundance Ion 276.00 (275.70 to 276.70): ENG
Ion 138.00 (137.70 to 138.70): ENG
65.00
65.50
20000J
15000-
10000 J
5000:
o:
65.13
rime--> 64.50
65.00
65.50
ENGTJT5TDPES1.M
Mon May 24 07 : 2.4 : Ob
#35
Benzo(g,h,i)perylene
Concen: 2.28 ng/uL m
RT: 65.13 min Scan# 8845
Delta R.T. -0.06 min
Lab File: ENG1336.D
Acq: 20 May 99 7:59 pm
Tgt Ion:276 Resp: 257684
Ion
276
138
0
0
Ratio
100
33.7
0.0
0.0
Lower Upper
10.1
0.0
0.0
40 .1
0.0
0.0
0003373
HP 5989B
Page 19
-------
Quantitation Report
Data File :
Acq On :
Sample :
Misc :
Quant Time:
Method
Title
Last Update
Response via
C:\HPCHEM\1\DATA\9919\ENG1337.D
20 May 99 9:14 pm
PES-MAH-051299-05 5.0 ng/uL
May 24 7:27 1999
: C:\HPCHEM\1\METHODS\PES1.M
•
Mon May 24 07:28:17 1999
Multiple Level Calibration
Vial: 6
Operator: JEMcCartney
Inst : HP 5989B
Multiplr: 1.00
Internal Standards
R.T. Qlon Response Cone Units Dev(Min)
1)
2 , 2-Dif luorobiphenyl
24.
54
190
562738
5
.00
System Monitoring Compounds
2)
4)
5)
7)
9)
11)
13)
15)
17)
19)
20)
22)
24)
26)
28)
30)
32)
34)
Naph t hal ene - d8
2-Methlynaphthalene-dlO
Acenaphthylene-d8
Acenaphthene -dl 0
Fluorene-dlO
Phenant hrene - dl 0
Anthracene -dlO
Fluoranthene-dlO
Pyrene-dlO
p-Terphenyl-d!4
Benzo (a) anthracene -dl 2
Chrysene-dl2
Benzo (b) f Iuoranthene-dl2
Benzo (k) f Iuoranthene-dl2
Benzo (a) pyrene-d!2
Indeno (1,2, 3 -cd) pyrene-d!2
Dibenz (a, h) anthracene-d!4
Benzo (g, h, i) perylene-d!2
22.
23.
26.
26.
27.
30.
30.
33.
34.
34.
38.
38.
45.
45.
48.
61.
61.
64.
19
91
23
65
95
38
52
51
18
50
77
93
72
92
36
21
15
73
136
152
160
164
176
188
188
212
212
244
240
240
264
264
264
288
292
288
1004306
537461
863713
592234
561198
698634
569832
621851
684592
550420
472667
481336
460720
528021
446189
552543
340231
475044
4
5
5
4
5
5
4
5
5
5
5
5
5
5
5
5
5
5
.85
.01
.08
.63
.02
.08
.96
.11
.15
.07
.10
.27
.23
.29
.31
.28
.01
.41
Target Compounds
3)
6)
8)
10)
12)
14)
16)
18)
21)
23)
25)
27)
29)
31)
33)
35)
Naph thai ene (CCC)
Acenaphthylene
Acenaphthene (CCC)
Fluorene
Phenanthrene
Anthracene
Fluor ant hene (CCC)
Pyrene
Benzo (a) anthracene
Chrysene(CCC)
Benzo (b) f luoranthene
Benzo (k) f luoranthene
Benzo (a) pyrene (CCC)
Indeno ( 1 , 2 , 3 - cd ) pyrene
Dibenz (a, h) anthracene
Benzo (g, h, i) perylene
22.
26.
26.
28.
30.
30.
33.
34.
38.
39.
45.
46.
48.
61.
61.
65.
23
27
73
02
44
57
56
24
88
06
91
07
57
53
57
14
128
152
154
166
178
178
202
202
228
228
252
252
252
276
278
276
1057590
873546
566552
608590
769658
685071
740096
782317
550266
584637
531449
560960
535570
614107
527791
544616
4
5
4
5
5
5
5
5
5
5
5
5
5
5
5
5
.86
.12
.86
.09
.06
.01
.12
.10
.12
.29
.25
.21
.16
.38
.16
.11
ng/uL
0.00
%Recovery
ng/uL #
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL #
ng/uL #
ng/uL
ng/uL #
ng/uL #
ng/uL #
ng/uL #
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL m
Qvalue
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL#
ng/uL#
ng/uL#
ng/uL
ng/uL
ng/uL
ng/uLm
ng/uLm
ng/uLm
95
98
100
96
93
92
74
70
75
72
79
81
80
18
77
50
OCC3379
(#) = qualifier out of range (m) = manual integration
ENG1337.D PESl.M Mon May 24 07:28:49 1999 HP 5989B
Page 1
-------
Quantitation Report
C:\HPCHEM\1\DATA\9919\ENG1337.D
20 May 99 9:14 pm
PES-MAH-051299-05 5.0 ng/uL
Data File
Acq On
Sample
Misc :
Quant Time: May 24 7:27 1999
Method
Title
Last Update
Response via
C:\HPCHEM\1\METHODS\PES1.M
Mon May 24 07:28:17 1999
Multiple Level Calibration
Vial: 6
Operator: JEMcCartney
Inst : HP 5989B
Multiplr: 1.00
Abundance
550000 :
500000 :
•
450000 :
•
400000 -
350000:
300000 .
250000:
200000 .
150000 -
100000 .
50000 -
0
rime-->
2
,
s 5
<
45
4
1
r
i
1
9
5
0
12
14
i:
i:
,,_J
s
s '•
^— \
2o!od ' ' 3o!od
TIC: ENG1337.D
1*8
-f
s
23S
2( S
27 32
2' s 29
28s 38|s
1 i 34S
nj \ —
4o!od ' ' solod ' ' eolod
ENG1337.D PES1.M
Mon May 24 07:28:58 1999
HP 5989B
Page 2
-------
Abundance
400000 :
300000
200000 :
100000:
Time-->
TIC: ENG1337.D
22.00
22.20
22140
Abundancelon 136.00 (135.70 to 136.70): ENG
Ion 68.00 (67.70 to 68.70): ENG13
400000 .
300000 :
200000 :
100000 -
o:
22.19
rime-->
22100
22.20
22.40
Abundance
400000 :
300000:
200000 :
100000 :
rime-->
TIC: ENG1337.D
22.00
22.20
22.40
#2
Naphthalene-d8
Concen: 4.85 ng/uL
RT: 22.19 min Scan# 1559
Delta R.T. 0.01 min
Lab File: ENG1337.D
Acq: 20 May 99 9:14 pm
Tgt Ion:136 Resp: 1004306
Ion Ratio Lower Upper
136 100
68 7.6 10.1 30.1#
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance Ion 128700(127.70 to 128.70): ENG
Ion 127.00 (126.70 to 127.70): ENG
22.23
400000 -I
200000 .
0 .
Time-->
22.00
22:20
22140
ENG1337.DPES1.M
#3
Naphthalene(CCC)
Concen: 4.86 ng/uL
RT: 22.23 min Scantf 1566
Delta R.T. 0.00 min
Lab File: ENG1337.D
Acq: 20 May 99 9:14 pm
Tgt Ion:128 Resp: 1057590
Ion
128
127
0
0
Ratio
100
12.0
0.0
0.0
Lower Upper
0.0
0.0
0.0
60.0
0.0
0.0
oeo:«3i
MOn May 24 07:29:01 1999
HP S989B
Page 3
-------
[Abundance
200000 :
150000.
100000:
soooo:
TIC: ENGlJJV.lJ
rime-->
23.80
23:90
24100
Abundance Ion 132^00 (151.70 to 152.70)
23.91
200000 -
100000-
ENG
0-
Time-->
23:80
23:90
24:00
#4
2-Methlynaphthalene-dlO
Concen: 5.01 ng/uL
RT: 23.91 min Scan# 1909
Delta R.T. 0.00 min
Lab File: ENG1337.D
Acq: 20 May 99 9:14 pm
Tgt Ion:152 Resp: 537461
Ion Ratio Lower Upper
152 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance
400000 :
•
300000 :
•
200000 :
100000 :
0
Time - - >
Abundance
400000.
300000J
200000 -
100000-
0 .
Time - - >
TIC: ENG1337.D
26llO 26120 26130 26140
Ion 160.00 (159.70 to 160.70): ENG
26.23
A
/ \
I \
_J V
' 26 ! 10 26 1 20 ' ' 26 1 30 26 1 40
#5
Acenaphthylene-d8
Concen: 5.08 ng/uL
RT: 26.23 min Scan# 2442
Delta R.T. 0.00 min
Lab File: ENG1337.D
Acq: 20 May 99 9:14 pm
Tgt Ion: 160 Resp: 863713
Ion Ratio Lower Upper
160 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
OCC33&2
ENGTJJ7TD PES1.M
MOn May 24 07:29:04 1999
Page 4
-------
Abundance
400000 .
300000 :
200000 .
100000 :
n
TIC: ENG1337.D
f\
1 \
1
I \
I \
1 \
I \
/ V
^x ^-.
rime--> '26lio' '26 l2'o' 26 Is'o' '26! 40'
Abundancelon 152.00 (151.70 to 152.70): ENG
400000 .
300000 :
200000 -
100000 .
0 .
Ion 153.00 (152.70 to 153.70): ENG
26.27
A
/ 1
/ \
J/\^
Time--> ' ' 26 1 10 ' ' 26 ! 20 ' ' 26 1 30 ' ' 26\4Q'
tffo
Acei
Con
RT:
r\— .1
JJS-L
Lab
Acq
Tgt
Ion
152
153
n
0
Acenaphthylene
Concen: 5.12 ng/uL
26.27 min Scan# 2447
a R.T. 0.00 min
File: ENG1337.D
Acq: 20 May 99 9:14 pm
Tgt Ion:152 Resp: 873546
Ratio Lower Upper
100
14.0 7.6 22.6
0.0 0.0 0.0
0.0 0.0 0.0
Abundance
400000 .
300000 .
200000 -
100000
Time--> 26.50
TIC: ENG1337.D
—I 1 1 1 1 1 1 1 1 1 1 1 1—
26.60 26.70 26.80
Abundancelon 164.00 (163.70 to 164.70): EtfG
200000 .
100000 .
26.65
— I — i
Time--> 26.50
26.60
i — i — | — i
26.70
26.80
ENG1337.D—PES1.I
Mon May 24 07:29:07 1999
#7
Acenaphthene-dlO
Concen: 4.63 ng/uL
RT: 26.65 min Scan# 2505
Delta R.T. -0.00 min
Lab File: ENG1337.D
Acq: 20 May 99 9:14 pm
Tgt Ion:164 Resp: 592234
Ion
164
0
0
0
Ratio
100
0.0
0.0
0.0
Lower Upper
0.0
0.0
0.0
0.0
0.0
0.0
OCOJ383
HP 5989B
Page 5
-------
Abundance
400000 :
Time--> 26.50
TIC: ENG1337.D
eo 26 so 215 90
Abundance Ion 154.00 (153.70 to 154.70): ENG
Ion 153.00 (152.70 to 153.70): ENG
26.73
200000 .
100000 .
Time--> 26.50
lsvo
25 90
Abundance
400000 -
300000 :
200000 -
100000 .
Time-->
TIC: ENG1337.D
2780
28o
2820
#8
Acenaphthene(CCC)
Concen: 4.86 ng/uL
RT: 26.73 min Scan# 2517
Delta R.T. -0.00 min
Lab File: ENG1337.D
Acq: 20 May 99 9:14 pm
Tgt Ion:154 Resp: 566552
Ion
154
153
0
0
Ratio
100
86.4
0.0
0.0
Lower Upper
43.5
0.0
0.0
130.3
0.0
0.0
Abundancelon 176.00 (175.70 to 176.70): ENG
200000 -
100000 .
0 .
27.95
Time-->
27 e
28 o
2820
ENGTJJ7TD PES1 .M
#9
Fluorene-dlO
Concen: 5.02 ng/uL
RT: 27.95 min Scan# 2701
Delta R.T. -0.00 min
Lab File: ENG1337.D
Acq: 20 May 99 9:14 pm
Tgt Ion:176 Resp: 561198
Ion
176
0
0
0
Ratio
100
0.0
0.0
0.0
Lower Upper
0.0
0.0
0.0
0.0
0.0
0.0
OCC3384
Won May 24 07:29:09
HP 5989B
Page 6
-------
Abundance
400000 .
300000 .
200000 .
100000 .
ritne-->
TIC: ENG1337.D
27.80
28.00
28.20
Abundanceion 166.00 (165.70 to 166.70): ENG
300000J
200000 -
100000 .
0
Ion 165.00 (164.70 to 165.70): ENG
28.02
Time-->
27!80
2s:oo
28.20
#10
Fluorene
Concen: 5.09 ng/uL
RT: 28.02 min Scan# 2712
Delta R.T. -0.00 min
Lab File: ENG1337.D
Acq: 20 May 99 9:14 pm
Tgt Ion:166 Resp: 608590
Ion Ratio Lower Upper
166 100
165 79.9 38.2 114.4
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Sundance
300000:
200000:
100000:
TIC: ENG1337.D
rime-->
—i 1 1 r
30.30
30.40
i — i — i — i —
30.50
Abundancelon 188.00 (187.70 to 188.70): ENG
Ion 94.00 (93.70 to 94.70): ENG13
300000:
200000.
100000:
o:
30.38
Time-->
30130
30!40
—i i 1 r
30l50
ENG1337.D—PES1.M
#11
Phenanthrene-dl0
Concen: 5.08 ng/uL
RT: 30.38 min Scan# 3070
Delta R.T. 0.00 min
Lab File: ENG1337.D
Acq: 20 May 99 9:14 pm
Tgt Ion:188 Resp: 698634
Ion
188
94
0
0
Ratio
100
11.4
0.0
0.0
Lower Upper
15.1
0.0
0.0
45.1#
0.0
0.0
0003365
Mon May 24 07:29:12 1999
HP 5989B
Page 7
-------
Abundance
300000 .
200000 .
100000 .
Time-->30.30
TIC: ENG1337.D
30.40
30.50
Abundance Ion 178.00 (177.70 to 178.70)
Ion 176.00 (175.70 to 176.70)
30.44
300000 .
200000 J
100000:
Time-->30.30
ENG
ENG
30.40
30.50
#12
Phenanthrene
Concen: 5.06 ng/uL
RT: 30.44 min Scan# 3079
Delta R.T. 0.00 min
Lab File: ENG1337.D
Acq: 20 May 99 9:14 pm
Tgt Ion:178 Resp: 769658
Ion Ratio
178 100
176 16.9
0 0.0
0 0.0
Lower Upper
10.1
0.0
0.0
30.1
0.0
0.0
Abundance
Time--> 30.30 30.40 30.50 30.60 30.70
TIC: ENG1337.D
Abundance Ion 188.00 (187.70 to 188.70): ENG
Ion 94.00 (93.70 to 94.70): ENG13
300000 .
200000 .
100000 .
30.52
0 .
rime-->
30.30 30.40 30.50
30.70
ENGI3T7TDPES1.M
#13
Anthracene-dlO
Concen: 4.96 ng/uL
RT: 30.52 min Scan# 3091
Delta R.T. 0.00 min
Lab File: ENG1337.D
Acq: 20 May 99 9:14 pm
Tgt Ion:188 Resp: 569832
Ion
188
94
0
0
Ratio
100
13.0
0.0
0.0
Lower Upper
15.1
0.0
0.0
45.1#
0.0
0 .0
OCC33BS
Won May 24 07:29:15 1999
HP 5989B
Page 8
-------
Abundance
300000 :
200000:
100000:
Time--> 30.40
TIC: ENG1337.D
30:50
30.60
30.70
Abundance Ion 178.00 (177.70 to 178.70): ENG
Ion 176.00 (175.70 to 176.70): ENG
300000 J
200000:
100000:
o:
30.57
Time--> 30.40
30.50
30.60
30.70
#14
Anthracene
Concen: 5.01 ng/uL
RT: 30.57 min Scan# 3099
Delta R.T. 0.00 min
Lab File: ENG1337.D
Acq: 20 May 99 9.-14 pm
Tgt Ion:178 Resp: 685071
Ion Ratio Lower Upper
178 100
176 16.2 10.1 30.1
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance
300000 '.
200000 '.
100000 '.
Time--> 33.20
TIC: ENG1337.D
33:40
33.60
Abundance Ion 212.00 (211.70 to 212.70): ENG
Ion 106.00 (105.70 to 106.70): ENG
33.51
200000 .
100000.
0 .
Time--> 33.20
33140
33160
ENGlJJTTD PES1 .M
MOn May 24 07:29:18
#15
Fluoranthene-dlO
Concen: 5.11 ng/uL
RT: 33.51 min Scan# 3609
Delta R.T. -0.00 min
Lab File: ENG1337.D
Acq: 20 May 99 9:14 pm
Tgt Ion:212 Resp: 621851
Ion
212
106
0
0
Ratio
100
15.8
0.0
0.0
Lower Upper
15.1
0.0
0.0
45.1
0.0
0.0
OCC3367
HP 5989B
Page 9
-------
Abundance
300000 J
200000 .
100000 -
Time-->
TIC: ENG1337.D
33.40
33.60
Abundance Ion 202.00 (201.70 to 202.70)
300000 -
200000.
100000.
0 '.
Ion 101.00 (100.70 to 101.70)
33.56
ENG
ENG
Time-->
33140
33.60
Abundance
300000 '.
200000 -
100000.
Time-->
TIC: ENG1337TD
34.00
34.20
34U6
#16
Fluoranthene(CCC)
Concen: 5.12 ng/uL
RT: 33.56 min Scan# 3617
Delta R.T. -0.00 min
Lab File: ENG1337.D
Acq: 20 May 99 9:14 pm
Tgt Ion:202 Resp: 740096
Lower Upper
13.6 40.6
0.0 0.0
0.0 0.0
Ion Ratio
202 100
101 13.7
0 0.0
0 0.0
Abundance Ion 212.00 (211.70 to 212.70) :
Ion 106.00 (105.70 to 106.70):
34.18
200000.
100000.
0.
ENG
ENG
-i 1 1 1 1 r
34.00
—i 1 1 1 1 1 1 1 1 r
34.20 34.40
ENGTJJ7TBPES1.M
#17
Pyrene-dlO
Concen: 5.15 ng/uL
RT: 34.18 min Scan# 3710
Delta R.T. 0.00 min
Lab File: ENG1337.D
Acq: 20 May 99 9:14 pm
Tgt Ion:212 Resp: 684592
Ion
212
106
0
0
Ratio
100
17.0
0.0
0.0
Lower Upper
17.1
0.0
0.0
51.1#
0.0
0.0
000)363
MOn May 24 07:29:21 1999
HP 5989B
Page 10
-------
Abundance
300000 J
200000 '.
100000.
Time-->
TIC: ENG1337.D
34:00
34120
34:40
Abundance Ion 202.00 (201.70 to 202.70): ENG
300000 '.
200000.
100000 .
0.
Ion 101.00 (100.70 to 101.70): ENG
34.24
rime-->
34:00
34:20
34:40
#18
Pyrene
Concen: 5.10 ng/uL
RT: 34.24 min Scan# 3718
Delta R.T. 0.00 min
Lab File: ENG1337.D
Acq: 20 May 99 9:14 pm
Tgt Ion:202 Resp: 782317
Ion
202
101
0
0
Ratio
100
15.5
0.0
0.0
Lower Upper
16.1
0.0
0.0
48. l#
0.0
0.0
Abundance
300000 '.
200000
100000 J
Time--> 34.20
TIC: ENG1337.D
34:40
34:60
Abundance Ion 244.00 (243.70 to 244.70): ENG
Ion 122.00 (121.70 to 122.70): ENG
200000 .
150000.
100000.
50000 .
0 .
34.50
rime--> 34.20
—i 1 1 1 1 1 1 1 1 1 r
34.40 34.60
ENG1337.DPES1.M
#19
p-Terphenyl-d!4
Concen: 5.07 ng/uL
RT: 34.50 min Scan# 3757
Delta R.T. 0.00 min
Lab File: ENG1337.D
Acq: 20 May 99 9:14 pm
Tgt Ion:244 Resp: 550420
Ion
244
122
0
0
Ratio
100
13.2
0.0
0.0
Lower Upper
13.6
0.0
0.0
40. 6#
0.0
0.0
MOn May 24 07:29:24 1999
HP 5989B
Page 11
-------
Abundance
150000 .
100000 .
BOOOO:
rime--> 38.60 38.70 38.80 38.90
TIC: ENG1337.D
Abundance Ion 240.00 (239.70 to 240.70) :
Ion 120.00 (119.70 to 120.70):
38.77
100000-
ENG
ENG
38.80 38.90
#20
Benzo(a)anthracene-d!2
Concen: 5.10 ng/uL
RT: 38.77 rain Scantf 4400
Delta R.T. -0.00 min
Lab File: ENG1337.D
Acq: 20 May 99 9:14 pm
Tgt Ion:240 Resp: 472667
Ion
240
120
0
0
Ratio
100
14.5
0.0
0.0
Lower Upper
15.1
0.0
0.0
45. l#
0.0
0.0
Abundance
150000 J
100000:
50000 .
Time--> 38170 38.80 38.90
TIC: ENG1337.D
0
39.00
Abundance Ion 228.00 (227.70 to 228.70)
ENG
150000Jlon 114.00 (113.70 to 114.70): ENG
100000 .
50000 -
rime--> 38.70 38.80 38190 39.00
ENG1337.D—PES1.M
Mon May 24 07:29:2V
#21
Benzo(a)anthracene
Concen: 5.12 ng/uL
RT: 38.88 min Scan# 4417
Delta R.T. -0.01 min
Lab File: ENG1337.D
Acq: 20 May 99 9:14 pm
Tgt Ion:228 Resp: 550266
Ion
228
114
0
0
Ratio
100
12.3
0.0
0.0
Lower Upper
12.6
0.0
0.0
37. 6#
0.0
0.0
HP 5989B
Page 12
-------
Abundance
150000 .
100000J
50000:
(
Time-->
TIC: ENG1337.D
38.80
39.00
39120
Abundance Ion 240.00 (239.70 to 240.70): ENG
Ion 120.00 (119.70 to 120.70): ENG
38.93
1000004
50000 -
0 .
Time-->
38.80
39:00
39.20
#22
Chrysene-d!2
Concen: 5.27 ng/uL
RT: 38.93 min Scan# 4425
Delta R.T. -0.01 min
Lab File: ENG1337.D
Acq: 20 May 99 9:14 pm
Tgt Ion:240 Resp: 481336
Ion
240
120
0
0
Ratio
100
12.6
0.0
0.0
Lower Upper
15.1
0.0
0.0
45.1#
0.0
0.0
Abundance
150000.
100000 J
50000 .
rime-->
TIC: ENG1337.D
38.80
39.20
Abundance Ion 228.00 (227.70 to 228.70): ENG
150000Jlon 114.00 (113.70 to 114.70): ENG
39.06
100000.
50000 -
Time-->
38:80
39:00
39:20
ENG1337.DPBS1. M
#23
Chrysene(CCC)
Concen: 5.29 ng/uL
RT: 39.06 min Scan# 4444
Delta R.T. -0.01 min
Lab File: ENG1337.D
Acq: 20 May 99 9:14 pm
Tgt Ion:228 Resp: 584637
Ion Ratio Lower Upper
228 100
114 10.8 12.6 37.6#
0 0.0 0.0 0.0
0 0.0 0.0 0.0
OCC33S1
Mon May 24 07:29:30 1999
HP 5989B
Page 13
-------
Abundance
150000 J
100000 -
50000 .
TIC: ENG133V.D
45.60
45.80
Sundance Ion 264.00 (263.70 to 264.70)
Ion 132.00 (131.70 to 132.70)
800004
45.72
eoooo:
ENG
ENG
Titne-->
45.60
45.80
#24
Benzo(b)fluoranthene-d!2
Concen: 5.23 ng/uL
RT: 45.72 min Scantf 5467
Delta R.T. 0.01 min
Lab File: ENG1337.D
Acq: 20 May 99 9:14 pm
Tgt Ion:264 Resp: 460720
Ion Ratio Lower Upper
264 100
132 15.9 15.1 45.1
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance
150000 J
100000:
50000 .
(
rime-->
TIC: ENG1337.D
45.80
46100
Ab
elon 252.00 (251.70 to 252.70)
Ion 126.00 (125.70 to 126.70)
ENG
ENG
50000 .
lime - - >
45.80
46.00
ENG1337.DPES1.M
#25
Benzo(b)fluoranthene
Concen: 5.25 ng/uL
RT: 45.91 min Scan# 5496
Delta R.T. -0.01 min
Lab File: ENG1337.D
Acq: 20 May 99 9:14 pm
Tgt Ion:252 Resp: 531449
Ion Ratio
252 100
126 14.5
0 0.0
0 0.0
Lower Upper
12.6
0.0
0.0
37.6
0.0
0.0
OCC03C2
Won May 24 07:29 :32
HP 5989B
Page 14
-------
Abundance
150000:
100000:
soooo:
rime--> 45.60
TIC: ENG1337.D
45.80
46.00
46.20
Abundance Ion 264.00 (263.70 to 264.70): ENG
Ion 132.00 (131.70 to 132.70): ENG
80000 .
60000 .
40000 -
20000 -
0 .
45.92
Time--> 45.60
45.80
46.00
46.20
#26
Benzo(k)fluoranthene-d!2
Concen: 5.29 ng/uL
RT: 45.92 min Scan# 5498
Delta R.T. -0.01 min
Lab File: ENG1337.D
Acq: 20 May 99 9:14 pm
Tgt Ion:264 Resp: 528021
Ion Ratio Lower Upper
264 100
132 16.8 15.1 45.1
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance
150000J
100000 -
soooo:
TIC: ENG1337.D
45.80
46.00
46.20
lAbundance Ion 252.00 (251.70 to 252.70)
lUUUUUH 126.00 (125.70 to 126.70)
46.07
50000 .
ENG
Time-->
45.80
46:00
46120
ENG1337.D—PES1.M
#27
Benzo(k)fluoranthene
Concen: 5.21 ng/uL
RT: 46.07 min Scan# 5522
Delta R.T. -0.01 min
Lab File: ENG1337.D
Acq: 20 May 99 9:14 pm
Tgt Ion:252 Resp: 560960
Ion
252
126
0
0
Ratio
100
15.4
0.0
0.0
Lower Upper
12.6
0.0
0.0
37.6
0.0
0.0
Mon May 24 07:29:35 1999
HP S989B
OCO393
Page 15
-------
kbundance
80000:
60000:
40000:
20000:
T 1 1 1 1 1 1 1 ! 1 1 1 1 1 1 1 1 1 1
rime--> 48.00 48.20 48.40 48.60
TIC: ENG1337.D
Abundance ion 264TOO (263.70 to 264.70)
60000 J
40000 -
20000 .
0 .
Ion 132.00 (131.70 to 132.70)
48.36
ENG
ENG
Time--> 48.00 48.20 48.40 48.60
#28
Benzo(a)pyrene-d!2
Concen: 5.31 ng/uL
RT: 48.36 min Scan# 5872
Delta R.T. -0.01 min
Lab File: ENG1337.D
Acq: 20 May 99 9:14 pm
Tgt Ion:264 Resp: 446189
Ion Ratio
264 100
132 17.2
0 0.0
0 0.0
Lower Upper
15.1
0.0
0.0
45.1
0.0
0.0
Abundance
80000 :
Time-->48.00
TIC: ENG1337.D
48.50
49.00
Abundance Ion 252.00 (251.70 to 252.70):
Ion 126.00 (125.70 to 126.70):
48.57
60000 :
40000:
20000.
Time-->48.00
ENG
ENG
48.50
49.00
ENGT3T7TD PES1 .M
#29
Benzo(a)pyrene(CCC)
Concen: 5.16 ng/uL
RT: 48.57 min Scan# 5905
Delta R.T. -0.01 min
Lab File: ENG1337.D
Acq: 20 May 99 9:14 pm
Tgt Ion:252 Resp: 535570
Ion
252
126
0
0
Ratio
100
15.0
0.0
0.0
Lower Upper
12.6
0.0
0.0
37.6
0.0
0.0
OCC03S4
MOn May 24 07:29:38
HP 5989B
Page 16
-------
Abundance
100000 -
—i 1 ; 1 -i 1 1 i 1 1 1 1 i r
Time-->60:50 61.00 61.50
TIC: ENG1337.D
50000 .
Abundance Ion 288.00 (287.70 to 288.70): ENG
40000:
30000 :
20000:
10000:
o:
61.21
Time-->60.50
61.00
61.50
Abundance
100000 -
Time-->
TIC: ENG1337.D
50000 .
61.00
61.50
62.00
#30
Indeno(1,2,3-cd)pyrene-d!2
Concen: 5.28 ng/uL
RT: 61.21 min Scan# 8050
Delta R.T. -0.06 min
Lab File: ENG1337.D
Acq: 20 May 99 9:14 pm
Tgt Ion:288 Resp: 552543
Ion
288
0
0
0
Ratio
100
0.0
0.0
0.0
Lower Upper
0.0
0.0
0.0
0.0
0.0
0.0
Abundancelon 276.05 (275.75 to 276.75): ENG
Ion 138.00 (137.70 to 138.70): ENG
61.53
40000 -I
20000 .
0 .
Time-->
61.00
61.50
62.00
ENG1337.DPES1.M
#31
Indeno(1,2,3-cd)pyrene
Concen: 5.38 ng/uL m
RT: 61.53 min Scan# 8110
Delta R.T. -0.09 min
Lab File: ENG1337.D
Acq: 20 May 99 9:14 pm
Tgt Ion:276.05 Resp: 614107
Ion
276
138
0
0
Ratio
100
30.0
0.0
0.0
Lower Upper
32.1
0.0
0.0
96.1#
0.0
0.0
Mon May 24 07:29:41 1999
HP 5989B
Page 17
-------
Abundance
100000 -
T—i—i—i—I—i—I—i—i—|—i—i—i—r
Time--> 60.80 61.00 6ll20 61140
TIC
50000 .
Abundancelon 292.00 (291.70 to 292.70): ENG
30000 .
20000 .
10000.
61.15
Titne-->
60.80 61.00 61.20 61.40
#32
Dibenz(a,h)anthracene-d!4
Concen: 5.01 ng/uL
RT: 61.15 min Scan# 8039
Delta R.T. -0.05 min
Lab File: ENG1337.D
Acq: 20 May 99 9:14 pm
Tgt Ion:292 Resp:
Ion Ratio Lower
100
292
0
0
0
0.0
0.0
0.0
0.0
0.0
0.0
340231
Upper
0.0
0.0
0.0
Abundance
100000 .
Time--> 61.00
TIC: ENG1337.D
50000 .
61.50
62100
Abundance Ion
Ion
40000 -
20000-
0.
278.00
139.00
(277.70 to 278.70)
(138.70 to 139.70)
61.57
ENG
ENG
Time--> 61.00
61.50
62100
ENG1337.DPES1.M
#33
Dibenz(a,h)anthracene
Concen: 5.16 ng/uL ra
RT: 61.57 min Scan# 8118
Delta R.T. -0.05 min
Lab File: ENG1337.D
Acq: 20 May 99 9:14 pm
Tgt Ion:278 Resp: 527791
Ion
278
139
0
0
Ratio
100
21.0
0.0
0.0
Lower Upper
12.6
0.0
0.0
37.6
0.0
0.0
OCCT3CS
Mon May 24 07:29:45
HP 5989B
Page 18
-------
Abundance
40000 .
20000 .
rime--> 64 .00
TIC: ENG1337.D
64.50
65.00
Abundancelon 288.00 (287.70 to 288.70): ENG
30000.
20000J
10000.
0.
64.73
Time--> 64.00
64!50
65.00
Abundance
40000 .
20000 .
rime--> 64.50
TIC: ENG1337.D
65.00
65150
Abundancelon 276.00 (275.70 to 276.70)
Ion 138.00 (137.70 to 138.70)
#34
Benzo(g,h,i)perylene-d!2
Concen: 5.41 ng/uL m
RT: 64.73 min Scan# 8748
Delta R.T. -0.04 min
Lab File: ENG1337.D
Acq: 20 May 99 9:14 pm
Tgt Ion:288 Resp: 475044
Ion
288
0
0
0
Ratio
100
0.0
0.0
0.0
Lower Upper
0.0
0.0
0.0
0.0
0.0
0.0
40000 .
30000 .
20000.
10000.
0 .
ENG
65.14
, i
rime--> 64.50
"i - 1 - i
65.00
1 - 1 - 1 - 1 - r
65.50
ENG1J37.D—PES1.M
Mon May 24 07:29:48 1999
#35
Benzo(g,h,i)perylene
Concen: 5.11 ng/uL m
RT: 65.14 min Scan# 8850
Delta R.T. -0.04 min
Lab File: ENG1337.D
Acq: 20 May 99 9:14 pm
Tgt Ion:276 Resp: 544616
Ion
276
138
0
0
Ratio
100
26.6
0.0
0.0
Lower Upper
10.1
0.0
0.0
40.1
0.0
0.0
HP 5989B
Page 19
-------
Quantitation Report
C:\HPCHEM\1\DATA\9919\ENG1332.D
20 May 99 2:57 pm
PES-MAH-051299-06 7ng/^L
Data File
Acq On
Sample
Misc
Quant Time: May 24 7:45 1999
Method
Title
Last Update
Response via
C:\HPCHEM\1\METHODS\PES1.M
Mon May 24 07:45:49 1999
Multiple Level Calibration
Vial: 2
Operator: JEMcCartney
Inst : HP 5989B
Multiplr: 1.00
Inte
1)
rnal Standards
2 , 2 -Dif luorobiphenyl
System Monitoring Compounds
2) Naphthalene-dS
4)
5)
7)
9)
11)
13)
15)
17)
19)
20)
22)
24)
26)
28)
30)
32)
34)
2 -Methlynaphthalene-dlO
Acenaphthylene-d8
Acenapht hene - dl 0
Fluorene-dlO
Phenanthrene-dlO
Anthracene -dlO
Fluoranthene-dlO
Pyrene -dlO
p-Terphenyl-d!4
Benzo (a) anthracene-d!2
Chrysene-dl2
Benzo (b) fluoranthene-d!2
Benzo (k) fluoranthene-d!2
Benzo (a) pyrene -d!2
Indeno ( 1 , 2 , 3 -cd) pyrene-d!2
Dibenz (a,h) anthracene-d!4
Benzo (g, h, i) perylene-d!2
R
24
22
23
26
26
27
30
30
33
34
34
38
38
45
45
48
61
61
64
.T.
.54
.18
.91
.23
.66
.95
.38
.52
.51
.19
.50
.78
.94
.72
.94
.38
.26
.20
.80
Qlon
190
136
152
160
164
176
188
188
212
212
244
240
240
264
264
264
288
292
288
Response
637618
1614374
834960
1301127
838783
840688
1005618
933489
830669
887662
712325
664400
644797
655453
764909
647763
871638
546650
700805
Cone Units Dev(Min)
5
6
6
6
5
6
6
7
6
5
5
6
6
6
6
6
7
7
7
.00
.88
.87
.76
.78
.63
.45
.18
.03
.89
.79
.33
.24
.56
.74
.77
.35
.16
.02
Target Compounds
3)
6)
8)
10)
12)
14)
16)
18)
21)
23)
25)
27)
29)
31)
33)
35)
Naphthalene (CCC)
Acenaphthylene
Acenapht hene (CCC)
Fluorene
Phenanthrene
Anthracene
Fluoranthene (CCC)
Pyrene
Benzo (a) anthracene
Chrysene(CCC)
Benzo (b) f luoranthene
Benzo (k) f luoranthene
Benzo (a) pyrene (CCC)
Indeno ( l , 2 , 3 - cd) pyrene
Dibenz (a, h) anthracene
Benzo (g, h, i) perylene
22
26
26
28
30
30
33
34
38
39
45
46
48
61
61
65
.23
.27
.73
.02
.44
.57
.56
.25
.89
.07
.93
.09
.59
.60
.63
.16
128
152
154
166
178
•178
202
202
228
228
252
252
252
276
278
276
1633637
1232880
790167
866958
1144383
1098427
960627
1008074
777269
802685
796987
854257
842847
972424
896096
919290
6
6
5
6
6
7
5
5
6
6
6
6
7
7
7
7
.63
.38
.99
.39
.64
.08
.86
.80
.38
.41
.95
.96
.17
.49
.76
.67
0
ng/uL
0.00
%Recovery
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
^j i — ^—
ng/uL
ng/uL
ng/uL
mj * ^^^
ng/uL
ng/uL
ng/uL m
ng/uL m
ng/uL m
Qvalue
ng/uL
ng/uL
w *
ng/uL
ng/uL
ng/uL
.j * ™~~ ^™
ng/uL
•j *
ng/uL
ng/uL
ng/uL
w * -— —
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL#
ng/uLm
99
99
98
99
99
99
96
96
97
97
97
94
98
91
72
62
}
(#) = qualifier out of range (m) = manual integration
ENG1332.D PES1.M Mon May 24 07:46:17 1999 HP 5989B
Page 1
-------
Quantitation Report
Data File : C:\HPCHEM\1\DATA\9919\ENG1332.D
Acq On : 20 May 99 2:57 pm
Sample : PES-MAH-051299-06 7ng/piL
Misc :
Quant Time: May 24 7:45 1999
Method
Title
Last Update
Response via
C:\HPCHEM\1\METHODS\PES1.M
Mon May 24 07:45:49 1999
Multiple Level Calibration
Vial: 2
Operator: JEMcCartney
Inst : HP 5989B
Multiplr: 1.00
Abundance
900000 .
800000 .
700000.
600000.
500000.
400000 1
300000 1
.
200000 1
.
100000 J
0
Time-->
TIC: ENG1332.D
2s
-
10
5i
4S
1
s
9
9
3
1
*
5
%
*!&
13 i
— i
S
O T ^^*^S
^ x
22s
23
2C8 :? 3i
28s 3 38
1 35
1 34s
1 U V
' ' 1 1 ' i i ' [ 1 I -l -I T 1 1 1 1 1 1 1 1 1 1 1 1
20.00 30.00 40!00 50.00 60.00
OCG9393
ENG1332.D PBSl.M
Mon May 24 07:46:27 1999
HP 5989B
Page 2
-------
Abundance
600000 :
400000:
200000 :
0
rime-->
Abundance
600000 .
400000-
200000 .
0 .
Iime-->
TIC: ENG1332.D
J v
1 1 1 1 1 1 1 1 1 r 1 1 1
22.00 22.20 22.40
Ion 136.00 (135.70 to 136.70): ENG
Ion 68.00 (67.70 to 68.70): ENG13
22.18
A
|\
22lo6 22 20 22140
Abundance
600000 .
400000 .
200000 :
0
rime-->
Abundance
600000 .
400000 .
200000.
0 .
Time-->
TIC: ENG1332.D
/ {
22100 ' ' 22.20 ' ' 22U6
Ion 128.00 (127.70 to 128.70): ENG
Ion 127.00 (126.70 to 127.70): ENG
22.23
A
IsL^
22lo6 22 20 22140
#2
Naphthalene-d8
Concen: 6.88 ng/uL
RT: 22.18 min Scan# 1558
Delta R.T. 0.00 min
Lab File: ENG1332.D
Acq: 20 May 99 2:57 pm
Tgt Ion:136 Resp: 1614374
Ion Ratio Lower Upper
100
136
68
0
0
7.8
0.0
0.0
3.9
0.0
0.0
11.5
0.0
0.0
#3
Naphthalene(CCC)
Concen: 6.63 ng/uL
RT: 22.23 min Scan# 1566
Delta R.T. 0.00 min
Lab File: ENG1332.D
Acq: 20 May 99 2:57 pm
Tgt Ion:128 Resp: 1633637
Ion Ratio Lower Upper
128 100
127 12.3 0.0 62.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
OCC34CO
ENGTJJ2TD PES1.M
MOn May 24 07:46:31
HP 5989B
Page 3
-------
Abundance
300000 J
200000 -
100000 J
TIC: ENC1332.D
I i i i i i i . I—i—I—i—
Time--> 23.70 23.80 23.90
24:00 24110
Abundancelon 152.00 (151.70 to 152.70): J<i
400000 :
300000:
200000 :
100000:
o:
23.91
1—I—I—1—I—I—I—I—I—I—I—I—I—I—I—I—I—I—I—I—I—I I
h?ime--> 23!70 23:80 23.90 24.00 24.10
Abundance
600000 -
400000 '.
200000 '.
Time--> 26.00
TIC: EtfGl332.D
26.20
26.40
Abundance Ion 160.00 (159.70 to 160.70): ENG
600000J
400000 -
200000 J
o:
26.23
Time--> 26.00
26.20
26.40
#4
2-Methlynaphthalene-dlO
Concen: 6.87 ng/uL
RT: 23.91 min Scantt 1909
Delta R.T. 0.00 min
Lab File: ENG1332.D
Acq: 20 May 99 2:57 pm
Tgt Ion:152 Resp: 834960
Ion
152
0
0
0
Ratio
100
0.0
0.0
0.0
Lower Upper
0.0
0.0
0.0
0.0
0.0
0.0
ENG1332.D—PES1.M
Mon May 24 UV:46:34
#5
Acenaphthylene-d8
Concen: 6.76 ng/uL
RT: 26.23 min Scan# 2441
Delta R.T. 0.00 min
Lab File: ENG1332.D
Acq: 20 May 99 2:57 pm
Tgt Ion:160 Resp: 1301127
Ion
160
0
0
0
Ratio
100
0.0
0.0
0.0
Lower Upper
0.0
0.0
0.0
0.0
0.0
0.0
OCC'JiC
HP 5989B
Page 4
-------
Abundance
600000 .
400000.
200000.
Time-->
TIC: ENG1332.D
26.10 26.20 26.30 26.40
Abundance Ion 152.00 (151.70 to 152.70): ENG
600000J
400000 .
200000.
0-
lon 153.00 (152.70 to 153.70): ENG
26.27
Time-->
26.10 26.20 26.30 26.40
Abundance
600000 -
400000 .
200000 .
Time--> 26.50
TIC: ENG1332.D
26.60
26.70
26.80
#6
Acenaphthy1ene
Concen: 6.38 ng/uL
RT: 26.27 min Scan# 2446
Delta R.T. 0.00 min
Lab File: ENG1332.D
Acq: 20 May 99 2:57 pm
Tgt Ion:152 Resp: 1232880
Ion Ratio
152 100
153 14.2
0 0.0
0 0.0
Lower Upper
7.1
0.0
0.0
21.1
0.0
0.0
Kb'
eTon 16^4.00 (163.70 to 164.70): ENG
300000J
200000 J
100000:
26.66
rime--> 26.50
26.60
26170
26.80
ENGTJJ2TDPES1.M
#7
Acenaphthene-dlO
Concen: 5.78 ng/uL
RT: 26.66 min Scan# 2504
Delta R.T. 0.00 min
Lab File: ENG1332.D
Acq: 20 May 99 2:57 pm
Tgt Ion:164 Resp: 838783
Ion
164
0
0
0
Ratio
100
0.0
0.0
0.0
Lower Upper
0.0
0.0
0.0
0.0
0.0
0.0
Mon May 24 07 :46:37 1999
HP 5989B
Page 5
-------
Abundance TIC: ENG1332.D
600000 .
•
400000 .
200000 -
L °
Time-->
^88888*
300000 :
200000 .
1
100000 .
o :
fTime - - >
A
A
,/V 1
1 1 1 i 1 r~ — ~i 1 i i i i
26.60 26 80
Ion 154.00 (153.70 to 154.70): ENG
Ion 153.00 (152.70 to 153.70): ENG
26.73
A
A
26! 60 26! 80 '
Abundance
600000 J
400000:
200000 -
0
Time- ->
TIC: ENG1332.D
1
J\l\
27l80 ' ' 28!00 ' ' 28!20
Abundancelon 176.00 (175.70 to 176.70): ENG
400000 -
300000.
200000.
100000-
0.
Time-->
27.95
A
J\^
27!s6 28!od ' 28!20
#8
Acenaphthene(CCC)
Concen: 5.99 ng/uL
RT: 26.73 min Scan# 2516
Delta R.T. -0.00 min
Lab File: ENG1332.D
Acq: 20 May 99 2:57 pm
Tgt Ion:154 Resp: 790167
Ion Ratio Lower Upper
154 100
153 87.9 43.3 129.7
0 0.0 0.0 0.0
0 0.0 0.0 0.0
#9
Fluorene-dlO
Concen: 6.63 ng/uL
RT: 27.95 min Scantf 2700
Delta R.T. -0.00 min
Lab File: ENG1332.D
Acq: 20 May 99 2:57 pm
Tgt Ion:176 Resp: 840688
Ion Ratio
176 100
0 0.0
0 0.0
0 0.0
Lower Upper
0.0
0.0
0.0
0.0
0.0
0.0
OCOMC3
MOn May 24 07:4t>:JS 1999
HP 5989B
Page €
-------
Abundance
600000 -
400000.
200000 .
Time-->
TIC: ENG1332.D
27.80
28.00
28.20
Abundance Ion 166.00 (165.70 to 166.70) : ENG7
Ion 165.00 (164.70 to 165.70): ENG
400000 .
300000 .
200000 .
100000 .
0 .
28.02
Time-->
27.80
28.00
28.20
#10
Fluorene
Concen: 6.39 ng/uL
RT: 28.02 min Scantt 2711
Delta R.T. -0.00 min
Lab File: ENG1332.D
Acq: 20 May 99 2:57 pro
Tgt Ion:166 Resp: 866958
Ion
166
165
0
0
Ratio
100
80.9
0.0
0.0
Lower Upper
40.0
0.0
0.0
119.9
0.0
0.0
Abundance
400000 .
200000 .
Time-->
TIC: ENG1332.D
30.30
30.40
30.50
Abundance ion 188.00 (187.70 to 188.70): ENG
Ion 94.00 (93.70 to 94.70): ENG13
30.38
400000J
200000.
rime-->
30.30
30.40
30.50
ENGT3T2TD PES1 . M
#11
Phenanthrene-dl0
Concen: 6.45 ng/uL
RT: 30.38 min Scan# 3069
Delta R.T. -0.00 min
Lab File: ENG1332.D
Acq: 2 0 May 99 2:57 pm
Tgt Ion:188 Resp: 1005618
Ion Ratio Lower Upper
188 100
94 12.7 5.8 17.2
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Mon May 24 07:46:42 1999
HP 5989B
Page 7
-------
'Abundance
400000 -
200000 -
TIC: ENG1332.D
Time--> 30.30
0
30.40
-i 1 1 r
30.50
Abundance Ion 178.00
Ion 176.00
400000 -
(177.70 to 178.70): ENG
(175.70 to 176.70): ENG
30.44
200000 J
[Time--> 30.30
30.40
30.50
#12
Phenanthrene
Concen: 6.64 ng/uL
RT: 30.44 min Scan# 3078
Delta R.T. -0.00 min
Lab File: ENG1332.D
Acq: 20 May 99 2:57 pm
Tgt Ion:178 Resp: 1144383
Ion Ratio Lower Upper
178 100
176 17.5 8.5 25.4
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance
400000 -
200000 -
TIC: ENG1332.D
Time-->
0
30.40
30.60
Abundance Ion 188.00 (187.70 to 188.70): ENG
Ion 94.00 (93.70 to 94.70): ENG13
400000 J A 30.52
200000-
Time-->
30.40
30.60
ENGTJJ2TD PES1.M
#13
Anthracene-dl0
Concen: 7.18 ng/uL
RT: 30.52 min Scan# 3091
Delta R.T. 0.01 min
Lab File: ENG1332.D
Acq: 20 May 99 2:57 pm
Tgt Ion:188 Resp: 933489
Lower Upper
Ion
188
94
0
0
Ratio
100
14.9
0.0
0.0
6.6
0.0
0.0
19.6
0.0
0.0
OCCJ403
Mon May 24 0/:4b:47 1999
HP 5989B
Page 8
-------
sundance
400000 .
200000.
TIC: ENG1332.D
Time--> 30.40
30.50
30.60
30.70
Abundance Ion 178.00
Ion 176.00
400000 J
200000 J
il77.70 to 178.70): ENG
[175.70 to 176.70): ENG
30.57
Time--> 30.40
30.50
30.60
30.70
#14
Anthracene
Concen: 7.08 ng/uL
RT: 30.57 min Scantt 3098
Delta R.T. -0.00 min
Lab File: ENG1332.D
Acq: 20 May 99 2:57 pm
Tgt Ion:178 Resp: 1098427
Ion Ratio Lower Upper
178 100
176 16.8 8.2 24.4
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance
400000 :
300000:
20-Qooo:
100000:
Time-->
TIC: ENG1332.D
33.40
33.60
Abundance Ion 212.00
Ion 106.00
300000 J
200000:
100000:
o:
(211.70 to 212.70)
(105.70 to 106.70)
33.51
ENG
Time-->
33.40
33:60
ENGT3T2TD PES1 .M
#15
Fluoranthene-dl0
Concen: 6.03 ng/uL
RT: 33.51 min Scantf 3609
Delta R.T. 0.00 min
Lab File: ENG1332.D
Acq: 20 May 99 2:57 pm
Tgt Ion:212 Resp: 830669
Ion
212
106
0
0
Ratio
100
16.8
0.0
0.0
Lower Upper
8.0
0.0
0.0
23 .8
0.0
0.0
OCOJiCS
MOn May 24 07:4b:5U 1999
HP 5989B
Page 9
-------
Abundance
400000 :
300000 :
200000 :
100000 :
0
Time-->
Abundance
400000J
300000 :
;
200000 :
100000 :
o:
Time- ->
TIC: BNG1332.D
A
AJ \
I \
/ v_
— i — i i — i — i — i — i — i — i — i — i — i — i — i i —
33.40 33.60 33 80
Ion 202.00 (201.70 to 202.70): ENG
Ion 101.00 (100.70 to 101.70): ENG
33.56
A
\
yv^
33140 ' ' 33l60 ' ' 33ls6
Abundance
400000 :
300000:
200000 :
100000 :
0
Time-->
Abundance
300000:
200000.
100000 '-
0 .'
Time-->
S T"1 M T\ T^
TIC: ENG1332.D
/^ A
I
! 1
11 /
, J • ,_. ,/
34.00 34.20 34 40
Ion 212.00 (211.70 to 212.70): ENG
Ion 106.00 (105.70 to 106.70): ENG
34.19
A
/A
34.00 34.20 34.40
#16
Fluoranthene(CCC)
Concen-. 5.86 ng/uL
RT: 33.56 min Scan# 3617
Delta R.T. 0.00 min
Lab File: ENG1332.D
Acq: 20 May 99 2:57 pm
Tgt Ion:202 Resp: 960627
Ion
202
101
0
0
Ratio
100
15.2
0.0
0.0
Lower Upper
6.9
0.0
0.0
20.6
0.0
0.0
#17
Pyrene-dlO
Concen: 5.89 ng/uL
RT: 34.19 min Scan# 3710
Delta R.T. 0.00 min
Lab File: ENG1332.D
Acq: 20 May 99 2:57 pm
Tgt Ion:212 Resp: 887662
Ion
212
106
0
0
Ratio
100
18.2
0.0
0.0
Lower Upper
8.6
0.0
0.0
25.6
0.0
0.0
OCC31C7
HP 5989B
Page 10
-------
Abundance
I 400000J
300000 .
200000 .
100000.
TIC: ENG1332.D
Time--> 34.00
34.20
34.40
Abundance Ion 202.00 (201.70 to 202.70)
400000HIon loi.OO (100.70 to 101.70)
34.25
300000:
200000:
100000:
o:
ENG
ENG
Time--> 34.00
34.20
34140
#18
Pyrene
Concen: 5.80 ng/uL
RT-. 34.25 min Scantf 3719
Delta R.T. 0.01 min
Lab File: ENG1332.D
Acq: 20 May 99 2:57 pm
Tgt Ion: 202 Resp: 1008074
Ion Ratio Lower Upper
202 100
7.8
0.0
0.0
101
0
0
17.3
0.0
0.0
23.3
0.0
0.0
Abundance
400000 :
300000 .
200000 -
100000 .
Time-->
TIC: ENG1332.D
34.40
34.60
Abundance Ion 244.00 (243.70 to 244.70)
Ion 122.00 (121.70 to 122.70)
34.50
200000 .
100000 .
0 .
ENG
ENG
rime-->
34.40
34.60
ENG1332.D PES1.M
Mon May 24 U7:4fe:bb
p-Terphenyl-dl4
Concen: 5.79 ng/uL
RT: 34.50 min Scan# 3758
Delta R.T. 0.01 min
Lab File: ENG1332.D
Acq: 20 May 99 2:57 pm
Tgt Ion:244 Resp: 712325
Ion
244
122
0
0
Ratio
100
15.4
0.0
0.0
Lower Upper
6.7
0.0
0.0
19 .9
0 .0
0.0
OC034C3
HP 5989B
Page 11
-------
'Abundance
200000-
100000.
TIC: ENG1332.D
, ~\—f~
Time--> 38.60
—i 1 1 r
38.70
—i [ 1 r
38.80
38.90
Abundance Ion 240.00 (239.70 to 240.voj : ENG
Ion 120.00 (119.70 to 120.70): ENG
150000J 38.78
100000 J
50000 -
IT
ime--> 38.60
38.70
38180
38.90
#20
Benzo(a)anthracene-d!2
Concen: 6.33 ng/uL
RT: 38.78 min Scantf 4401
Delta R.T. 0.01 min
Lab File: ENG1332.D
Acq: 20 May 99 2:57 pm
Tgt Ion:240 Resp: 664400
Ion
240
120
0
0
Ratio
100
15.6
0.0
0.0
Lower Upper
7.3
0.0
0.0
21.8
0.0
0.0
Abundance
200000 .
100000 .
Time--> 38.70 38.80 38.90 39.00
TIC: ENG1332.D
Abundancelon 228.00 (227.70 to 228.70): ENG
200000Jlon 114.00 (113.70 to 114.70): ENG
38.89
150000:
100000:
soooo:
Time-->
ENG13T2TD~
38.70 38.80 38.90 39.00
PEbl.M
Mon May 24 07:4b:59
#21
Benzo(a)anthracene
Concen: 6.38 ng/uL
RT: 38.89 min Scantf 4419
Delta R.T. 0.01 min
Lab File: ENG1332.D
Acq: 20 May 99 2:57 pm
Tgt Ion:228 Resp: 777269
Ion
228
114
0
0
Ratio
100
13.5
0.0
0.0
Lower Upper
6.2
0.0
0.0
18.5
0.0
0.0
OCC02C9
HP S989B
Page 12
-------
Abundance
200000 .
100000 .
TIC: ENG1332.D
Time-->
38.80
39.00
Abundancelon 240.00 (239.70 to 240.70)
Ion 120.00 (119.70 to 120.70)
150000J 38.94
100000:
50000 .
Time-->
ENG
ENG
38.80
39.00
#22
Chrysene-dl2
Concen: 6.24 ng/uL
RT: 38.94 min Scan# 4426
Delta R.T. 0.00 min
Lab File: ENG1332.D
Acq: 20 May 99 2:57 pm
Tgt Ion:240 Resp: 644797
Ion Ratio
240 100
120 14.1
0 0.0
0 0.0
Lower Upper
6.4 19.0
0.0 0.0
0.0 0.0
Abundance
200000 .
100000 j
TIC: ENG1332.D
Time - - >
38.80
39.00
39.20
Abundance Ion 228.00 (227.70 to 228.70)
2000004Ion 114.00 (113.70 to 114.70)
39.07
A
isoooo:
100000:
soooo:
ENG
Time-->
ENG1JJ2.D
38.80
PES1.M—
39.00
39.20
#23
Chrysene(CCC)
Concen: 6.41 ng/uL
RT: 39.07 min Scan# 4446
Delta R.T. 0.01 min
Lab File: ENG1332.D
Acq: 20 May 99 2:57 pm
Tgt Ion:228 Resp: 802685
Ion
228
114
0
0
Ratio
100
12 .0
0.0
0.0
Lower Upper
5.5
0.0
0.0
16.3
0.0
0.0
OCCM10
Mon May 24 U7:47:U2 1999
HP 5989B
Page 13
-------
[Abundance
200000.
100000 .
TIC: ENG1332.D
Time--> 45;50 45! 60 45:70 45! 80 45 .'90
Abundancelon 264.00 (263.70 to 264.70): ENG
Ion 132.00 (131.70 to 132.70): ENG
100000 .
50000 -
fTime--> 45.50 45.60 45.70 45.80 45.90
#24
Benzo(b)fIuoranthene-dl2
Concen: 6.56 ng/uL
RT: 45.72 min Scantf 5468
Delta R.T. 0.01 min
Lab File: ENG1332.D
Acq: 20 May 99 2:57 pm
Tgt Ion:264 Resp: 655453
Ion Ratio Lower Upper
264 100
132 17.9 8.0 23.9
0 0.0 0.0 0.0
0 0.0 0.0 0.0
[Abundance
200000 .
100000 -
TIC: ENG1332.D
ime-->
45.80
46.00
Abundance ion 252.Ou (251.70 to 252.70): ENG
150000Hlon 126.00 (125.70 to 126.70): ENG
100000 .
50000 -
Time-->
45:80
46.00
PES1.M
#25
Benzo(b)fluoranthene
Concen: 6.95 ng/uL
RT: 45.93 min Scan# 5500
Delta R.T. 0.01 min
Lab File: ENG1332.D
Acq: 2 0 May 99 2:5 7 pm
Tgt Ion:252 Resp:
Ion Ratio Lower
252 100
126 15.9 7.3
0 0.0 0.0
0 0.0 0.0
796987
Upper
21.8
0.0
0.0
Mon May 24 07:47:06 1999
HP 5989B
Page 14
-------
Abundance
200000.
100000 .
TIC: ENG1332.D
Time- ->
Abundance Ion 264.00 (263.70 to 264.70):
lion 132.00 (131.70 to 132.70):
45.94
ENS'
ENG
100000 _
50000 -
Time-->
45.80
46.00
46.20
#26
Benzo(k)fluoranthene-d!2
Concen: 6.74 ng/uL
RT: 45.94 min Scan# 5501
Delta R.T. 0.01 min
Lab File: ENG1332.D
Acq: 20 May 99 2:57 pm
Tgt Ion:264 Resp: 764909
Ion
264
132
0
0
Ratio
100
19.4
0.0
0.0
Lower Upper
8.5
0.0
0.0
25.3
0.0
0.0
Abundance
200000 -
100000 _
Time--> 45.80
TIC: ENG1332.D
46.00
46.20
Abundance Ion 252.00 (251.70 to 252.70)
150000HIon 126.00 (125.70 to 126.70)
46.09
100000-
50000-
0-
ENG
ENG
rime--> 45.80
46.00
45:20
ENG1J32.D—PES1.M
Mon May 24 U7;4V;U9
#27
Benzo(k)fluoranthene
Concen: 6.96 ng/uL
RT: 46.09 min Scantf 5525
Delta R.T. 0.01 min
Lab File: ENG1332.D
Acq: 20 May 99 2:57 pm
Tgt Ion:252 Resp: 854257
Ion
252
126
0
0
Ratio
100
17.9
0.0
0.0
Lower Upper
7.8
0.0
0.0
23 .2
0.0
0 .0
OCC3411
HP 5989B
Page 15
-------
Abundance
100000 -
50000-
TIC: ENG1332.D
ime--> 48.00
48.20
48 I 40 ' ' 48!60
Abundanceton 264.00 (263.70 to 264.70): ENG
Ion 132.00 (131.70 to 132.70): ENG
80000 :
60000J
40000:
20000 J
48.38
o:
Time--> 48.00
48.20
48.40
48.60
#28
Benzo(a)pyrene-d!2
Concen: 6.77 ng/uL
RT: 48.38 min Scan# 5875
Delta R.T. 0.01 min
Lab File: ENG1332.D
Acq: 20 May 99 2:57 pm
Tgt Ion:264 Resp: 647763
Ion Ratio Lower Upper
264 100
132 19.3 8.7 25.9
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance
100000 -
50000 -
Time--> 48.00
TIC: ENG1332.D
48.50
49.00
Abundancelon 252.00 (251.70 to 252.70): ENG
Ion 126.00 (125.70 to 126.70): ENG
100000 -
50000 .
0 .
48.59
Time--> 48 .00
48.50
49.00
ENG1332.DPES1.M
#29
Benzo(a)pyrene(CCC)
Concen: 7.17 ng/uL
RT: 48.59 min Scant 5908
Delta R.T. 0.01 min
Lab File: ENG1332.D
Acq: 20 May 99 2:57 pm
Tgt Ion:252 Resp: 842847
Ion Ratio Lower Upper
252 100
126 15.8 7.6 22.6
0 0.0 0.0 0.0
0 0.0 0.0 0.0
OCC3412
Mon May 24 07:47:12 1999
HP 5989B
Page 16
-------
Abundance
150000:
100000:
50000:
TIC: ENG1332.D
0
Time--> 60 .50
61.00
61.50
Abundancelon 288.00 (287.70 to 288.70): ENG
60000 J
40000 -
20000:
0 -
61.26
Time--> 60 .50
61.00
61150
#30
Indeno(1,2,3-cd)pyrene-d!2
Concen: 7.35 ng/uL m
RT: 61.26 min Scan# 8059
Delta R.T. -0.01 min
Lab File: ENG1332.D
Acq: 20 May 99 2:57 pm
Tgt Ion:288 Resp:
Ion Ratio Lower
288 100
0 0.0 0.0
0 0.0 0.0
0 0.0 0.0
871638
Upper
0.0
0.0
0.0
TIC: ENG1332.D
Time-->61.00
61.50
62.00
Abundance Ion 276.05 (275.75 to 276 .75) : ENG
80000 J
60000 .
40000 .
20000 .
rime-->61.00
Ion 138.00 (137.70 to 138.70): ENG
61.60
i 1 1 r
62.00
ENG1JJ2.D—PES1.M
#31
Indeno(1,2,3 -cd)pyrene
Concen: 7.49 ng/uL
RT: 61.60 min Scan# 8124
Delta R.T. -0.02 min
Lab File: ENG1332.D
Acq: 20 May 99 2:57 pm
Tgt Ion:276.05 Resp: 972424
Ion
276
138
0
0
Ratio
100
25.4
0.0
0.0
Lower Upper
15.1
0.0
0.0
45.1
0.0
0.0
OCCOiiS
Mon May 24 07:47:15 1999
HP 5989B
Page 17
-------
Abundance
150000:
100000:
50000:
Time-->
TIC: ENG1332.D
61.00
61.50
Abundancelon 292.00 (291.70 to 252.70): EMG
40000.
20000
61.20
Time-->
61.00
61.50
#32
Dibenz(a,h)anthracene-d!4
Concen: 7.16 ng/uL m
RT: 61.20 min Scan# 8048
Delta R.T. -0.01 min
Lab File: ENG1332.D
Acq: 20 May 99 2:57 pm
Tgt Ion:292 Resp: 546650
Ion Ratio Lower Upper
292 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
TIC: ENG1332.D
Time--> 61.00
Abundanceion 278.00 (277.70 to 278.70): ENG
Ion 139.00 (138.70 to 139.70): ENG
6i:so
80000:
60000:
40000:
20000:
o:
61.63
Time--> 61.00
61.50
ENG13T77D—PES1.M
62.00
Mon May 24 07:47:19 1999
#33
Dibenz(a,h)anthracene
Concen: 7.76 ng/uL
RT: 61.63 min Scan# 8128
Delta R.T. -0.00 min
Lab File: ENG1332.D
Acq: 20 May 99 2:57 pm
Tgt Ion:278 Resp: 896096
Ion
278
139
0
0
Ratio
100
8.0
0.0
0.0
Lower Upper
10.6
0.0
0.0
31.€#
0.0
0.0
OC03414
HP 5989B
Page 18
-------
Abundance
80000 -i
60000 :
40000 .
20000 -
rime-->
TIC: ENG1332.D
64.50
65.00
Abundancelon 288.00 (287.70 to 288.70}
64.80
40000 .
20000 -
ENG
0 .
Time-->
64.50
65.00
#34
Benzo(g,h,i)perylene-d!2
Concen: 7.02 ng/uL m
RT: 64.80 min Scantf 8765
Delta R.T. 0.02 min
Lab File: ENG1332.D
Acq: 20 May 99 2:57 pm
Tgt Ion:288 Resp: 700805
Ion Ratio Lower Upper
288 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance
80000 -i
Time--> 64.50
TIC: ENG1332.D
65.00
65150
Abundancelon 276.00 (275.70 to 276.70)
Ion 138.00 (137.70 to 138.70)
60000J 65'16
40000.
20000:
o:
ENG
ENG
rime--> 64.50
eslod
i i i
65.50
ENG1JJ2.D PES1.M
Mon May 24 07:47:22
#35
Benzo(g,h,i)perylene
Concen: 7.67 ng/uL m
RT: 65.16 min Scantf 8855
Delta R.T. -0.03 min
Lab File: ENG1332.D
Acq: 2 0 May 99 2:5 7 pm
Tgt Ion:276 Resp: 919290
Ion
276
138
0
0
Ratio
100
26.6
0.0
0.0
Lower Upper
10.7
0.0
0.0
42.6
0.0
0.0
OCCMI3
HP 5989B
Page 19
-------
Quantitation Report
Data File
Acq On
Sample
Misc
Quant Time
Method
Title
Last Update
Response via
C:\HPCHEM\1\DATA\9919\ENG1338.D
20 May 99 10:29 pm
PES-MAH-051299-01 10 ng/uL
May 24 7:48 1999
: C:\HPCHEM\1\METHODS\PES1.M
Vial: 7
Operator: JEMcCartney
Inst : HP 5989B
Multiplr: 1.00
Won May 24 07:50:43 1999
Multiple Level Calibration
Internal Standards
R.T. Qlon Response Cone Units Dev(Min)
1)
2 , 2 -Dif luorobiphenyl
24
.54
190
556202
5
.00
System Monitoring Compounds
2)
4)
5)
7)
9)
11)
13)
15)
17)
19)
20)
22)
24)
26)
28)
30)
32)
34)
Naphthalene-d8
2 -Methlynaphthalene-dlO
Acenaphthylene-d8
Acenaphthene-dlO
Fluorene-dlO
Phenanthrene-dlO
Anthracene-dlO
Fluoranthene-dlO
Pyrene-dlO
p-Terphenyl-d!4
Benzo (a) anthracene-d!2
Chrysene-dl2
Benzo (b) f Iuoranthene-dl2
Benzo (k) f Iuoranthene-dl2
Benzo(a)pyrene-dl2
Indenod, 2, 3-cd)pyrene-dl2
Dibenz (a, h) anthracene-d!4
Benzo (g, h, i)perylene-d!2
22
23
26
26
27
30
30
33
34
34
38
38
45
45
48
61
61
64
.18
.91
.23
.65
.95
.38
.52
.50
.18
.50
.77
.93
.71
.93
.36
.24
.17
.75
136
152
160
164
176
188
188
212
212
244
240
240
264
264
264
288
292
288
1895935
1029029
1630454
1062442
1044974
1300849
1070774
1199569
1295418
1038448
945495
933226
904310
1053936
915312
1168056
732036
972191
9
9
9
8
9
9
9
9
9
9
10
10
10
10
10
11
10
11
.27
.71
.71
.39
.45
.57
.44
.98
.85
.68
.33
.36
.38
.67
.97
.28
.99
.16
Target Compounds
3)
6)
8)
10)
12)
14)
16)
18)
21)
23)
25)
27)
29)
31)
33)
35)
Naphthalene (CCC)
Acenaphthylene
Acenaphthene (CCC)
Fluorene
Phenanthrene
Anthracene
Fluoranthene (CCC)
Pyrene
Benzo (a) anthracene
Chrysene (CCC)
Benzo (b) f luoranthene
Benzo (k) f luoranthene
Benzo (a) pyrene (CCC)
Indeno ( 1 , 2 , 3 - cd) pyrene
Dibenz ( a, h) anthracene
Benzo (g, h, i) perylene
22
26
26
28
30
30
33
34
38
39
45
46
48
61
61
65
.23
.27
.73
.02
.44
.57
.56
.24
.88
.06
.92
.09
.58
.60
.61
.16
128
152
154
166
178
178
202
202
228
228
252
252
252
276
278
276
1954848
1652978
1106204
1121429
1439029
1275291
1405320
1489117
1087163
1135169
1045384
1114383
1082839
1232471
1088800
1103824
9
9
9
9
9
9
9
9
10
10
10
10
10
10
10
10
.10
.81
.61
.48
.58
.41
.83
.83
.24
.40
.46
.44
.56
.89
.81
.58
ng/uL 0
.00
%Recovery
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
Qvalue
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL#
ng/uL
ng/uL#
OCCCi
99
99
96
99
99
99
99
99
99
100
99
99
100
67
85
48
'?••••
*Ju
„, <#) = qualifier out of range (m) = manual integration
ENG1338.D PES1.M Mon May 24 07:50:59 1999 HP S989B
Page 1
-------
Quantitation Report
Data File : C:\HPCHEM\1\DATA\9919\ENG1338.D
Acq On : 20 May 99 10:29 pm
Sample : PES-MAH-051299-01 10 ng/uL
Misc :
Quant Time: May 24 7:48 1999
Method
Title
Last Update
Response via
C:\HPCHEM\1\METHODS\PES1.M
Mon May 24 07:50:43 1999
Multiple Level Calibration
Vial: 7
Operator: JEMcCartney
Inst : HP 5989B
Multiplr: 1.00
Abundance
1000000 :
900000 :
sooooo:
700000 '.
600000 '.
500000 :
400000:
300000 .
200000-
100000.
0
TIC: ENG1338.D
2
5£
P <
4s
S
20lOD
1
3
3
1
9
3
0 12
1
i:
i:
5
4
sil
:
,s
?S
2% 2^
23
2( s
31
27
29
28s ia§
T 35
i i 34s
soloo ' ' 4oloo soloo ' ' eolod
ENG1338.D PES1.M
Mon May 24 07:51:09 1999
HP 5989B
Page 2
-------
Abundance
800000:
600000:
400000:
200000:
Time-->
TIC: ENG1338.D
0
—i 1 r
22.00
22120
22140
elon 136.00 (135.70 to 136.70): ENG
68.00 (67.70 to 68.70): ENG13
22.18
600000 J
400000 J
200000 J
Time-->
22.00
22 .20
22.40
Abundance
800000 :
600000 :
400000:
200000:
Time-->
TIC: ENG1338.D
22.00
22.20
22.40
#2
Naphtha!ene-d8
Concen: 9.27 ng/uL
RT: 22.18 min Scantf 1558
Delta R.T. 0.00 min
Lab File: ENG1338.D
Acq: 20 May 99 10:29 pm
Tgt Ion:136 Resp: 1895935
Ion Ratio Lower Upper
100
136
68
0
0
7.9
0.0
0.0
3.9
0.0
0.0
11.5
0.0
0.0
[AbundanceIon 128.00 (127.70 to 128.70): ENG
nn n~ -|°n 127.00 (126.70 to 127.70): ENG
800000j 22.23
600000 :
400000:
200000:
0 J
Time - - >
22.00
22.20
22.40
ENG1338.DPES1.M
#3
Naphthalene(CCC)
Concen: 9.10 ng/uL
RT: 22.23 min Scan# 1566
Delta R.T. 0.00 min
Lab File: ENG1338.D
Acq: 20 May 99 10:29 pm
Tgt Ion:128 Resp: 1954848
Ion Ratio Lower Upper
128 100
127 12.5 0.0 62.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Mon May ^4 U7:bl:12 1999
HP 5989B
Page 3
-------
TIC: ENG1338.D
300000 J
200000:
100000:
23180
24.00
Abundance Ion 152.00 (151.70 to 152.70)
400000J 23.91
300000 .
200000 -
100000:
ENG
0 .
Time-->
23180
24.00
#4
2-Methlynaphthalene-dlO
Concen: 9.71 ng/uL
RT: 23.91 min Scan# 1909
Delta R.T. 0.00 min
Lab File: ENG1338.D
Acq: 20 May 99 10:29 pm
Tgt Ion:152 Resp: 1029029
Ion Ratio
152 100
0 0.0
0 0.0
0 0.0
Lower Upper
0.0
0.0
0.0
0.0
0.0
0.0
Abundance
800000 :
600000 :
400000 :
200000 :
o .
rime-->
Abundance
600000.
400000.
200000 .
0
Time - - >
TIC: ENG1338.D
f\
J
L
26 100 ' ' 26! 20' ' ' 26140
Ion 160.00 (159.70 to 160.70): ENG
26.23
I
/
1
A
V
26100 26120 26140
#5
Acenaphthylene-d8
Concen: 9.71 ng/uL
RT: 26.23 min Scan# 2442
Delta R.T.
Lab File:
Acq: 20 May
Tgt Ion: 160
Ion Ratio
160 100
0 0.0
0 0.0
0 0.0
0.00 min
ENG1338.D
99 10:29 pm
Resp: 1630454
Lower Upper
0.0 0.0
0.0 0.0
0.0 0.0
OGC3113
ENGT3T8TD PES1 .
MOn May 24 07:51:lb 1999
Page 4
-------
Abundance
800000 .
600000 .
400000 .
200000 .
Time--> 26.00
TIC: ENG1338.D
0
26.20
26.40
lAbundancelon 152.00 (151.70 to 152.70)
800000 -ilon 153.QO (152.70 to 153.70)
2€.27
600000 J
400000:
200000
ENG
ENG
04:
Time--> 26 .00
26.20
26 .40
Abundance
800000 -j
600000 .
400000 .
200000 -
Titne-->
TIC; ENG1338.D
0
26.50 26.60
-1—I—I—I—r
26170
i—i—I—i—i—r
26.80
#6
Acenaphthylene
Concen-. 9.81 ng/uL
RT: 26.27 min Scan# 2447
Delta R.T. 0.00 min
Lab File: ENG1338.D
Acq: 20 May 99 10:29 pm
Tgt Ion:152 Resp: 1652978
Ion Ratio Lower Upper
152 100
153 14.5 7.1 21.1
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundancelon 164.00 (163.70 to 164.70): ENG
400000:
300000 :
200000:
100000.
26.65
Time-->
26150' 26 I 60
i—i—|—i—i—i—r—i—i—i—i—r
26.70 26.80
ENGT3T5TD PES1.]
Mon May 24 07:51:19 1999
#7
Acenaphthene-dlO
Concen: 8.39 ng/uL
RT: 26.65 min Scantf 2505
Delta R.T. -0.00 min
Lab File: ENG1338.D
Acq: 20 May 99 10:29 pm
Tgt Ion:164 Resp: 1062442
Ion
164
0
0
0
Ratio
100
0.0
0.0
0.0
Lower Upper
0.0
0.0
0.0
0.0
0.0
0.0
OCCjIiO
HP 5989B
Page 5
-------
Abundance
800000 .,
600000 .
400000 .
200000 .
n
Time-->
Abundance
400000 .
200000 .
0 .
Time-->
TIC: ENG1338.D
A
/ \ II
/ \ / 1
/ \ / \
J V_
26160 ' ' 26180 ' ' 27100
Ion 154.00 (153.70 to 154.70): ENG
Ion 153.00 (152.70 to 153.70): ENG
26.73
/)
A
26leo 2e!so 27loo
#8
Ace
Con
RT:
Del
Lab
Acq
Tgt
Ion
154
153
0
Abundance
800000 :
600000:
400000:
200000:
Time-->
TIC: ENG1338.D
2780
28o
2820
Acenaphthene(CCC)
Concen: 9.61 ng/uL
26.73 min Scantf 2517
.a R.T. -0.00 min
File: ENG1338.D
Acq: 20 May 99 10:29 pm
Tgt Ion:154 Resp: 1106204
Ratio Lower Upper
100
43.3
0.0
0.0
82.5
0.0
0.0
129.7
0.0
0.0
Abundance Ion 176.00 (175.70 to 176.70) : ENG
400000.
200000 .
0.
27.95
Time - - >
2780
28o
2820
ENG1J38.D—PKS1.M
#9
Fluorene-dlO
Concen: 9.45 ng/uL
RT: 27.95 min Scan# 2701
Delta R.T. -0.00 min
Lab File: ENG1338.D
Acq: 20 May 99 10:29 pm
Tgt Ion:176 Resp: 1044974
Ion
176
0
0
0
Ratio
100
0.0
0.0
0.0
Lower Upper
0.0
0.0
0.0
0.0
0.0
0.0
OCCJK:.
Mon May 24 UV:bl:22 lyyy
HP 5989B
Page 6
-------
(Abundance
800000:
600000 .
400000 .
200000 .
TIC: ENG1338.D
Time- ->
27.80
28.00
28.20
Abundancelon 155.00 (165.70 to 166.70): ENu
Ion 165.00 (164.70 to 165.70): ENG
28.02
400000 .
•
200000 J
0 -
Time-->
27:80
-i 1 1 1 r
28.00
—i 1 1 1 r-
28.20
#10
Fluorene
Concen: 9.48 ng/uL
RT: 28.02 min Scan# 2712
Delta R.T. -0.00 min
Lab File: ENG1338.D
Acq: 20 May 99 10:29 pm
Tgt Ion:166 Resp: 1121429
Ion
166
165
0
0
Ratio
100
80.6
0.0
0.0
Lower Upper
40.0
0.0
0.0
119.9
0.0
0.0
lAbundance
600000 .
400000 .
200000 .
Time-->
TIC: ENG1338.D
30.30
30!40
30!50
Abundancelon 188.00 (187.70 to 188.70): ENG
600000 .
400000 '.
200000 J
Ion 94.00
(93.70 to 94.70): ENG13
30.38
Time-->
30.30
~i - 1 - 1
30.40
1 - 1 - 1 - r
30.50
ENG1J38.D—PBS1.M
Mon May 24 07:51:2b 1999
#11
Phenanthrene-dl0
Concen: 9.57 ng/uL
RT: 30.38 min Scan# 3070
Delta R.T. -0.00 min
Lab File: ENG1338.D
Acq: 20 May 99 10:29 pm
Tgt Ion:188 Resp: 1300849
Ion Ratio Lower Upper
188 100
94 11.9 5.8 17.2
0 0.0 0.0 0.0
0 0.0 0.0 0.0
HP 5989B
Page 7
-------
Abundance
600000 .
400000 .
200000 .
Time--> 30.30
TIC: EJJG1338.D
0
30.40
30.50
Abundanceion 178.00 (177.70 to 178.70)
ilon 176.00 (175.70 to 176.70)
30.44
600000 J
400000J
200000:
o:
ENG
Time--> 30.30
30.40
30!50
#12
Phenanthrene
Concen: 9.58 ng/uL
RT: 30.44 min Scan# 3079
Delta R.T. -0.00 min
Lab File: ENG1338.D
Acq: 20 May 99 10:29 pm
Tgt Ion:178 Resp: 1439029
Ion Ratio Lower Upper
178 100
176 17.3 8.5 25.4
0 0.0 0.0 0.0
0 0.0 0.0 0.0
TIC: ENG1338.D
200000 .
rime-->
30.40
30.60
Abundancelon 188.00 (187.70 to 188.70) : ENG
600000JIon 94.00 (93.70 to 94.70): ENG13
400000 .
200000 .
0-
30.52
Time - - >
30.40
30.60
ENG1338.D—PES1.M
Mon May 24 07:51:28
#13
Anthracene-dlO
Concen: 9.44 ng/uL
RT: 30.52 min Scan# 3091
Delta R.T. -0.00 min
Lab File: ENG1338.D
Acq: 20 May 99 10:29 pm
Tgt Ion:188 Resp: 1070774
Ion
188
94
0
0
Ratio
100
13.6
0.0
0.0
Lower Upper
6.6
0.0
0.0
19.6
0.0
0.0
OCC3423
HP 5989B
Page 8
-------
Time--> 30.40
Abundance I on 178.00 (177.70 to 178.70) : ENG
Ion 176.00 (175.70 to 176.70): ENG
30.50
30.60
30.70
600000:
400000:
200000
fTime--> 30.40
30.57
30.50
3o:eo
30.70
#14
Anthracene
Concen: 9.41 ng/uL
RT: 30.57 min Scan# 3099
Delta R.T. -0.00 min
Lab File: ENG1338.D
Acq: 20 May 99 10:29 pm
Tgt Ion:178 Resp: 1275291
Ion Ratio Lower Upper
178 100
176 16.7 8.2 24.4
0 0.0 0.0 0.0
0 0.0 0.0 0.0
abundance
600000-1
400000 .
200000 .
TIC: ENG1338.D
Time--> 33.20
—i 1 1 r
33140
33 .60
T
Abundancelon 212.00 (211.70 to 212.70): ENG
Ion 106.00 (105.70 to 106.70): ENG
33.50
400000 J
200000 .
0 .
Time--> 33.20
"^—I—•"
33140
-i 1 1 r
33.60
T
ENG1JJ8.D—FE5T7]
#15
Fluoranthene-dlO
Concen: 9.98 ng/uL
RT: 33.50 min Scan# 3609
Delta R.T. -0.00 min
Lab File: ENG1338.D
Acq: 20 May 99 10:29 pm
Tgt Ion:212 Resp: 1199569
Ion Ratio Lower Upper
100
212
106
0
0
16.0
0.0
0.0
8.0
0.0
0.0
23.8
0.0
0.0
Won May 24 U7:51:J1 1999
HP 5989B
Page 9
-------
Abundance
600000 j
400000 -
200000 .
Time-->
TIC: ENG1338.D
-i 1 r
33!40
-i—i—|—i-
33.60
sslsd
Abundancelon 202.00 (201.70 to 202.70): ENG
Ion 101.00 (100.70 to 101.70): ENG
600000 H
400000 .
200000 -
33.56
Time-->
33.40
33.60
33.80
#16
Fluoranthene(CCC)
Concen: 9.83 ng/uL
RT: 33.56 min Scan# 3617
Delta R.T. -0.00 min
Lab File: ENG1338.D
Acq: 20 May 99 10:29 pm
Tgt Ion:202 Resp: 1405320
Ion Ratio Lower Upper
202 100
101 14.2 6.9 20.6
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance
600000 .
•
400000 .
200000 -
0
Time-->
Abundance
400000 .
200000 .
0 .
ritne-->
TIC: ENG1338.D
All
I ft
J LJl
34100 ' ' 34120 ' ' 34140
Ion 212.00 (211.70 to 212.70): ENG
Ion 106.00 (105.70 to 106.70): ENG
34.18
JL_
34lo6 ' ' 34120 ' ' 34140
#17
Pyr
L,OH
RT:
Del
Lab
Acq
Tgt
Ion
212
106
0
0
Concen: 9.85 ng/uL
34.18 min Scan# 3711
a R.T. 0.00 min
File: ENG1338.D
Acq: 20 May 99 10:29 pm
Tgt Ion:212 Resp: 1295418
Ratio Lower Upper
100
17.5
0.0
0.0
8.6
0.0
0.0
25.6
0.0
0.0
ENGlJJB.DPES1.M
Mon May 24 07:51:34
HP 5989B
Page 1C
-------
'Abundance
600000 J
400000 j
200000 .
TIC: ENG1-1J8.D
Time-->
34.00
34.20
34140
elon 202.00 (201.70 to 202.70): ENG
Ion 101.00 (100.70 to 101.70): ENG
34.24
400000
200000 -
0-L.
[Time--> 34.00
-i 1 1 r
34:20
34.40
#18
Pyrene
Concen: 9.83 ng/uL
RT: 34.24 min Scan# 3719
Delta R.T. 0.00 min
Lab File: ENG1338.D
Acq: 20 May 99 10:29 pm
Tgt Ion:202 Resp: 1489117
Ion Ratio Lower Upper
202 100
101 16.1 7.8 23.3
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance
600000 J
400000 -
200000 .
Iime--> 34.20
TIC: ENG1338.D
34.40
34.60
Abundancelon 244.00 (243.70 to 244.70)
ENG
400000 J
300000 .
200000:
100000 -
o:
Ion 122.00 (121.70 to 122.70): ENG
34.50
rime--> 34.20
34.40
34.60
ENG1338.DPEbl. M
#19
p-Terphenyl-d!4
Concen: 9.68 ng/uL
RT: 34.50 min Scan# 3758
Delta R.T. 0.00 min
Lab File: ENG1338.D
Acq: 20 May 99 10:29 pm
Tgt Ion:244 Resp: 1038448
Ion
244
122
0
0
Ratio
100
13.5
0.0
0.0
Lower Upper
6.7
0.0
0.0
19.9
0.0
0.0
OC03425
MOn May 24 U7:51:J7 1999
HP S989B
Page 11
-------
Abundance
300000 -
200000 J
100000 -
TIC: ENG1338.D
Time-->
T—i—|—i—r
38.60
33:70
38 1 80
38 ! 90
Abundancelon 240.00 (239.70 to 240.70): ENG
Ion 120.00 (119.70 to 120.70): ENG
38.77
200000 .
100000 .
Time-->
38.60 38.70 38.80 38.90
#20
Benzo(a)anthracene-dl2
Concen: 10.33 ng/uL
RT: 38.77 min Scantf 4401
Delta R.T. -0.00 min
Lab File: ENG1338.D
Acq: 20 May 99 10:29 pm
Tgt Ion:240 Resp: 945495
Ion Ratio Lower Upper
240 100
120 15.0 7.3 21.8
0 0.0 , 0.0 0.0
0 0.0 0.0 0.0
Abundance
300000 1
200000 '.
100000:
c
Titne-->
TIC: ENG1338.D
38.70 38.80 38.90 39.00
.ancelon 228.00 (227.70 to 228.70)
000 ^ 114.00 (113.70 to 114.70)
38.88
200000
100000 .
ENG
Time-->
38.70 38.80 38.90 39.00
ENG1338.DPBS1.M
#21
Benzo(a)anthracene
Concen: 10.24 ng/uL
RT: 38.88 min Scan# 4418
Delta R.T. -0.01 min
Lab File: ENG1338.D
Acq: 20 May 99 10:29 pm
Tgt Ion:228 Resp: 1087163
Ion Ratio Lower Upper
228 100
114 12.7 6.2 18.5
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Mon May 24 07:5i:4U iyyy
HP 5989B
0003*27
Page 12
-------
[Abundance
1
300000 -
200000 .
100000 .
(
Time-->
TIC: EMG1338.D
38.80
39.00
Abundancelon 240.00 {239.70 to 240.70):
Ion 120.00 (119.70 to 120.70): ENG
38.93
200000.
100000 .
38.80
39.00
#22
Chrysene-dl2
Concen: 10.36 ng/uL
RT: 38.93 min Scantf 4426
Delta R.T. -0.01 min
Lab File: ENG1338.D
Acq: 20 May 99 10:29 pm
Tgt Ion:240 Resp: 933226
Ion Ratio Lower Upper
240 100
120 12.9 6.4 19.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
(Abundance
300000 J
200000 .
100000:
(
Time-->
TIC: ENG1338.D
elon 228.00 (227.70 to 228.70): ENG
Ion 114.00 (113.70 to 114.70): ENG
39.06
200000.
100000-
Time-->
38.80
39!00
39.20
ENGT3TBTDPES1.M
#23
Chrysene(CCC)
Concen: 10.40 ng/uL
RT: 39.06 min Scan# 4446
Delta R.T. -0.00 min
Lab File: ENG1338.D
Acq: 20 May 99 10:29 pm
Tgt Ion:228 Resp: 1135169
Ion
228
114
0
0
Ratio
100
10.9
0.0
0.0
Lower Upper
5.5
0.0
0.0
16.3
0.0
0.0
OCG3428
MOn May 24 07:51:44
HP S989B
Page 13
-------
Abundance
300000 1
200000 J
100000:
(
Time - - >
TIC: ENG1338.D
45.60
45.80
Abundancelon 264.00 (263.70 to 264.70)
]Ion 132.00 (131.70 to 132.70)
150000 J
100000:
50000.
Time-->
ENG"
ENG
45.60
45.80
#24
Benzo(b)fluoranthene-d!2
Concen: 10.38 ng/uL
RT: 45.71 min Scantf 5468
Delta R.T. -0.00 min
Lab File: ENG1338.D
Acq: 20 May 99 10:29 pm
Tgt Ion:264 Resp: 904310
Ion Ratio Lower Upper
264 100
132 16.9 8.0 23.9
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance
300000 '-
200000 '.
100000:
Time--> 45.60
TIC: ENG1338.D
45.80
46.00
46.20
Abundancelon 252.00 (251.70 to 252.70):
jlon 126.00 (125.70 to 126.70): ENG
150000.
100000 :
50000:
Time--> 45.60
45.80
46.00
46.20
ENG1338.D—PES1.M
Mon May 24 07:bl:47
#25
Benzo(b)fluoranthene
Concen: 10.46 ng/uL
RT: 45.92 min Scantf 5500
Delta R.T. -0.00 min
Lab File: ENG1338.D
Acq: 20 May 99 10:29 pm
Tgt Ion:252 Resp: 1045384
Ion
252
126
0
0
Ratio
100
14.9
0.0
0.0
Lower Upper
7.3
0.0
0.0
21.8
0 .0
0 .0
0000153
HP 5989B
Page 14
-------
I-IC: ENG1338.D
Time--> 45.60
45.80
46.00
46.20
Abundancelon 264.00 (263.Vo to 264.vu; :
Ion 132.00 (131.70 to 132.70):
45.93
150000 J
100000 -
50000
ime- -> 45.60
"ESS
ENG
45.80
46.00
46.20
#26
Benzo(k)fluoranthene-dl2
Concen: 10.67 ng/uL
RT: 45.93 min Scan# 5501
Delta R.T. -0.01 min
Lab File: ENG1338.D
Acq: 20 May 99 10:29 pm
Tgt Ion:264 Resp: 1053936
Ion Ratio Lower Upper
264 100
132 17.8 8.5 25.3
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance
300000 J
200000 1
100000-
Time-->
TIC: ENG1338.D
45.80
46.00
46.20
46.40
Abundance 1onz 5 2 70 0 (251.70 to 252.70): ENG
Ion 126.00 (125.70 to 126.70): ENG
46.09
150000 J
100000:
50000:
Time--> 45.80 46.00 46.20 46.40
ENG1JJET7D PES1 .M
#27
Benzo(k)fluoranthene
Concen: 10.44 ng/uL
RT: 46.09 min Scan# 5526
Delta R.T. -0.00 min
Lab Pile-. ENG1338.D
Acq: 20 May 99 10:29 pm
Tgt Ion:252 Resp: 1114383
Ion
252
126
0
0
Ratio
100
15.7
0.0
0.0
Lower Upper
7.8
0.0
0.0
23.2
0.0
0.0
0003430
Mon May 24 07:51:5U 1999
HP 5989B
Page 15
-------
Abundance
150000J
100000 .
50000 J
TIC: EUG1338.D
L_
Time--> 48.00
—i—I—i
48.20
48.40 48.60
Abundancelon 264.00 (263.70 to 264.vuj
Ion 132.00 (131.70 to 132.70)
48.36
100000 .
50000 .
0 -,
ENG
Time--> 48.00 48.20 48.40 48.60
#28
Benzo(a)pyrene-d!2
Concen: 10.97 ng/uL
RT: 48.36 tnin Scan# 5875
Delta R.T. -0.01 min
Lab File: ENG1338.D
Acq: 20 May 99 10:29 pm
Tgt Ion:264 Resp: 915312
Ion Ratio Lower Upper
264 100
132 18.1 8.7 25.9
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance
150000 .
100000 J
50000 .
(
ritne-->
TIC: ENG1338.D
Abundance ion 252.00 (251.70 to 252.70) : ENG
Ion 126.00 (125.70 to 126.70): ENG
48.58
48.50
49.00
150000 .
100000 .
50000 .
0.
Time-->
ENG1338.D PES1.I
- 1 — ~"
48.50
49.00
Mon May 24 07:51:!
#29
Benzo(a)pyrene(CCC)
Concen: 10.56 ng/uL
RT: 48.58 min Scan# 5908
Delta R.T. -0.01 min
Lab File: ENG1338 .D
Acq: 20 May 99 10:29 pm
Tgt Ion:252 Resp: 1082839
Ion Ratio
252 100
126 14.9
0 0.0
0 0.0
Lower Upper
7.6 22.6
0.0 0.0
0.0 0.0
0003431
HP 5989B
Page 16
-------
Abundance
200000:
150000 .
100000:
50000 .
Time--> 60.50
TIC: ENG1338.D
61.00
61.50
Abundance Ion 288.00 (287.70 to 288.70)
ENG
80000 J
60000:
40000:
20000:
o:
61.24
Time--> 60.50
61.00
6ll50
Abundance
200000:
150000 :
100000:
soooo:
(
Time-->
TIC: ENG1338.D
Abundance Ion 276.05 (275.75 to 276.75)
61.00
61.50
62.00
#30
Indeno(1,2,3 -cd)pyrene-d!2
Concen: 11.28 ng/uL
RT: 61.24 min Scan# 8058
Delta R.T. -0.03 min
Lab File: ENG1338.D
Acq: 20 May 99 10:29 pm
Tgt Ion:288 Resp: 1168056
Ion Ratio
288 100
0 0.0
0 0.0
0 0.0
Lower Upper
0.0
0.0
0.0
0.0
0.0
0.0
100000 .
50000 .
0.
Ion 138.00 (137.70 to 138.70)
61.60
ENG
ENG
rime-->
61.00
61.50
€2.00
ENG1JJ8.D—PES1.M
Won May 24 07:51:b7
#31
Indeno(1,2,3-cd)pyrene
Concen: 10.89 ng/uL
RT: 61.60 min Scan# 8124
Delta R.T. -0.03 min
Lab File: ENG1338.D
Acq: 20 May 99 10:29 pm
Tgt Ion:276.05 Resp: 1232471
Ion
276
138
0
0
Ratio
100
12.3
0.0
0.0
Lower Upper
15.1
0.0
0.0
45.1#
0.0
0.0
ocoiia?.
HP 5989B
Page 17
-------
'[Abundance
200000:
150000:
100000:
50000:
TIC: ENG1338.D
Time-->
-i 1 1 r
61.00
'eilso
Abundancelon 292.00 (291.70 to 292.vu;
60000 .
40000 -
20000 -
"ENS'
Time-->
61.00
#32
Dibenz(a,h)anthracene-d!4
Concen: 10.99 ng/uL
RT: 61.17 min Scantt 8045
Delta R.T. -0.03 min
Lab File: ENG1338.D
Acq: 20 May 99 10:29 pm
Tgt Ion:292 Resp:
Ion Ratio Lower
100
292
0
0
0
0.0
0.0
0.0
0.0
0.0
0.0
732036
Upper
0.0
0.0
0.0
Abundance
200000:
TIC: ENG1338.D
Time--> 61.00
62.00
Abundance Ion 27B.OO
100000 .
Ion 139.00
50000.
0.
(277.70 to 278.70): ENG
(138.70 to 139.70): ENG
61.61
Time--> 61.00
61.50
62 loo'
ENG1338.D—PES1.M
Mon May 24 07:52:01
#33
Dibenz(a,h)anthracene
Concen: 10.81 ng/uL
RT: 61.61 min Scantf 8126
Delta R.T. -0.02 min
Lab File: ENG1338.D
Acq: 20 May 99 10:29 pm
Tgt Ion:278 Resp: 1088800
Ion
278
139
0
0
Ratio
100
14.2
0.0
0.0
Lower Upper
10.6
0.0
0.0
31.6
0.0
0.0
OOCM23
HP 5989B
Page 18
-------
Abundance
100000 -l
TIC
50000 -
^ J 1 1 1 1 1 1 r-
Time--> 64.00 64.50
Abundancelon 288.00 (287.Vo to 288.70): ENG
esloo
60000:
40000:
20000:
o .-
64.75
1—i-
?ime--> 64.00
64.50
65.00
Abundance
100000 j
Time-->64.50
TIC: ENG1338.D
50000 -
65.00
65.50
#34
Benzo(g,h,i)perylene-d!2
Concen: 11.16 ng/uL
RT: 64.75 min Scantt 8754
Delta R.T. -0.03 tnin
Lab File: ENG1338.D
Acq: 20 May 99 10:29 pm
Tgt Ion:288 Resp: 972191
Ion Ratio Lower Upper
288 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance ion 276.00
;Ion 138.00
80000 :
60000:
40000:
20000:
o :-
(275.70 to 276.70): ENG
(137.70 to 138.70): ENG
65.16
Time-->64.50
65.00
65.50
"ENG1338 .D PES1.M
MOn May 24 07:52:Ub
#35
Benzo(g,h,i)perylene
Concen: 10.58 ng/uL
RT: 65.16 min Scantt 8855
Delta R.T. -0.03 min
Lab File: ENG1338.D
Acq: 20 May 99 10:29 pm
Tgt Ion:276 Resp: 1103824
Ion
276
138
0
0
Ratio
100
0.0
0.0
0.0
Lower Upper
10.7
0.0
0.0
42.6#
0.0
0.0
HP 5989B
Page 19
-------
Data File
Acq On
Sample
Misc
Quantitation Report
C:\HPCHEM\1\DATA\9919\ENG1339.D
20 May 99 11:45 pm
PES-MAH-051899-01 15 ng/uL
Quant Time: May 24 7:55 1999
Vial: 8
Operator: JEMcCartney
Inst : HP 5989B
Multiplr: 1.00
Method
Title
Last Update
Response via
C:\HPCHEM\1\METHODS\PES1.M
Mon May 24 07:56:15 1999
Multiple Level Calibration
Internal Standards
l)
2, 2-Difluorobiphenyl
R
24
.T.
.53
Qlon
190
Response
515589
Cone Units Dev(Min)
5
.00
System Monitoring Compounds
2)
4)
5)
7)
9)
11)
13)
15)
17)
19)
20)
22)
24)
26)
28)
30)
32)
34)
Naphthalene -d8
2-Methlynaphthalene-dlO
Acenaph thyl ene - d8
Acenaphthene - dl 0
Fluorene-dlO
Phenanthrene - dl 0
Anthracene -dlO
Fluoranthene-dlO
Pyrene-dlO
p-Terphenyl-d!4
Benzo (a) anthracene-d!2
Chrysene-dl2
Benzo (b) f Iuoranthene-dl2
Benzo (k) f Iuoranthene-dl2
Benzo (a) pyrene-d!2
Indeno (1, 2 , 3-cd)pyrene-dl2
Dibenz (a, h) anthracene-d!4
Benzo (g,h, i)perylene-d!2
22
23
26
26
27
30
30
33
34
34
38
38
45
45
48
61
61
64
.18
.91
.23
.66
.95
.38
.52
.51
.18
.50
.77
.94
.71
.93
.37
.27
.20
.77
136
152
160
164
176
188
188
212
212
244
240
240
264
264
264
288
292
288
2413931
1320737
2119929
1339510
1354549
1678739
1438313
1544629
1652988
1341674
1263156
1214223
1203297
1378887
1217609
1547005
1019842
1267730
12
13
13
11
13
13
13
13
13
13
14
14
14
15
15
16
16
15
.74
.44
.61
.42
.21
.32
.67
.86
.55
.49
.88
.54
.90
.05
.71
.12
.62
.64
ng/uL
0.00
%Recovery
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
W '
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
^ i "~™ ™~
ng/uL
ng/uL
Target Compounds
3)
6)
8)
10)
12)
14)
16)
18)
21)
23)
25)
27)
29)
31)
33)
35)
Naphthalene (CCC)
Acenaphthylene
Acenaphthene { CCC)
Fluorene
Phenanthrene
Anthracene
Fluoranthene (CCC)
Pyrene
Benzo (a) anthracene
Chrysene(CCC)
Benzo (b) f luoranthene
Benzo (k) f luoranthene
Benzo (a) pyrene (CCC)
Indeno ( 1 , 2 , 3 - cd) pyrene
Dibenz ( a ; h) anthracene
Benzo (g, h; i) perylene
22
26
26
28
30
30
33
34
38
39
45
46
48
61
61
65
.23
.27
.73
.02
.44
.57
.56
.24
.89
.06
.92
.09
.59
.62
.63
.19
128
152
154
166
178
178
202
202
228
228
252
252
252
276
278
276
2525735
2149569
1423999
1472641
1873765
1736842
1828079
1922904
1473146
1508140
1408550
1473217
1471012
1605448
1461059
1469893
12
13
13
13
13
13
13
13
14
14
15
14
15
15
15
15
.68
.75
.34
.43
.45
.82
.80
.69
.96
.91
.20
.87
.47
.30
.65
.20
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
^j i •— ^—
ng/uL
m
Qvalue
98
99
96
99
99
98
98
98
99
99
99
98
99
88
86
ng/uL# 68
oec
J433
(#) = qualifier out of range (m) * manual integration
ENG1339.D PES1.M Mon May 24 07:57:21 1999 HP 5989B
Page 1
-------
Quantitation Report
Data File : C:\HPCHEM\1\DATA\9919\ENG1339.D
Acq On : 20 May 99 11:45 pm
Sample : PES-MAH-051899-01 15 ng/uL
Misc :
Quant Time: May 24 7:55 1999
Method
Title
Last Update
Response via
C:\HPCHEM\1\METHODS\PES1.M
Mon May 24 07:56:15 1999
Multiple Level Calibration
Vial: 8
Operator: JEMcCartney
Inst : HP 5989B
Multiplr: 1.00
Abundance
1300000 .
.
1200000 .
1100000 :
1000000 -i
.
800000 .
700000.
600000.
500000 .
400000 -
300000.
200000 -
100000.
o
Time - - >
2
20 00
5
4
5!
*
S
1
3l
B
9
5
0
1
1
i:
i:
3
30!
2
4
S
S
* — i
00
1*
I?
• •
_J^
PIC: ENG1339.D
58
,s
)S
21 2^
2Cs
27
2-s29
3S. 35
1 -i 34S
1
LLu u
4o!od soloo €olod
ENG1339.D PESl.M
Mon May 24 07:57:30 1999
HP S989B
Page 2
-------
Abundance
1000000 .
TIC: ENG1339.D
500000 -
Time-->
22.00
22.20
22.40
Abundancelon 136.00 (135.70 to 136.70): ENG
68.00 (67.70 to 68.70): ENG13
22.18
500000 .
Time - - >
22.00
22.20
22.40
Abundance
1000000 -
TIC: ENG1339.D
Time-->
500000 -
22;00
22.20
22.40
#2
Naphthalene-d8
Concen: 12.74 ng/uL
RT: 22.18 rain Scan# 1558
Delta R.T. -0.00 min
Lab File: ENG1339.D
Acq: 20 May 99 11:45 pm
Tgt Ion:136 Resp: 2413931
Ion Ratio Lower Upper
100
136
68
0
0
8.0
0.0
0.0
3.9
0.0
0.0
11.5
0.0
0.0
[Abundance I on 128.00 (127.70 to 128.70): ENG
Ion 127.00 (126.70 to 127.70): ENG
1000000 .
500000.
22.23
Time-->
22.00
22.20
22.40
ENGTJJ9TD PES1 .M
Naphthalene(CCC)
Concen: 12.68 ng/uL
RT: 22.23 min Scan# 1566
Delta R.T. -0.00 min
Lab File: ENG1339.D
Acq: 20 May 99 11:45 pm
Tgt Ion:128 Resp: 2525735
Ion
128
127
0
0
Ratio
100
12.9
0.0
0.0
Lower Upper
0.0
0.0
0.0
62 .0
0 .0
0.0
OCOM.2-
MOn May iJ4 07 : 57 : 33
HP 5989B
Page 3
-------
Abundance
400000 .
200000 .
0 .
Time--> 2
Abundance
600000 .
400000 -
200000 .
!
0 J
Time--> 2
TIC: ENG1339 .D
/ \
j\^
3.70 23 80 23.90 24.00 24.10
Ion 152.00 (151.70 to 152.70): ENG
23.91
A
J{_
'slVo' '23! BO' '23 90 ' '24 lob' '24! 10
lAbundance
1000000 -
500000 .
0 .
Time-->
^w$me
500000
0
Time - - >
TIC: ENG1339.D
j\
26ioO ' 26 20 ' 26140
Ion 160.00 (159.70 to 160.70): ENG
26.23
: j^
26loO ' ' 26120 ' ' 26U6
#4
2-Methlynaphthalene-dlO
Concen: 13.44 ng/uL
RT: 23.91 min Scantf 1908
Delta R.T. -0.00 min
Lab File: ENG1339.D
Acq: 20 May 99 11:45 pm
Tgt Ion:152 Resp: 1320737
Ion Ratio
152 100
0 0.0
0 0.0
0 0.0
Lower Upper
0.0
0.0
0.0
0.0
0.0
0.0
Acenaphthylene-d8
Concen: 13.61 ng/uL
RT: 26.23 min Scantf 2442
Delta R.T. -0.00 min
Lab File: ENG1339.D
Acq: 20 May 99 11:45 pm
Tgt Ion:160 Resp: 2119929
Ion Ratio Lower Upper
160 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
OCC3423
ENG1339.DPES1.M
May 24
-------
Abundance
1000000 .
•
500000 .
0 .
Time-->
TIC: ENG1339.D
f\
I
26lo6 26l20
I
26l40
Abundancelon 152.00 (151.70 to 152.70): ENG
1000000 Jlon 153.00 (152.70 to 153.70): ENG
1 26.27
-I
_
500000.
0
Time-->
A
J/^
26100 ' ' 26l20
I
26U6
#6
Acei
Con
RT:
T^«T
jjex
Lab
Acg
Tgt
Ion
152
153
0
0
Abundance
1000000 J
Time--> 26 .40
TIC: ENG1339TD
500000 -
26.60
26.80
Acenaphthylene
Concen: 13.75 ng/uL
26.27 min Scantf 2447
:a R.T. -0.00 min
File: ENG1339.D
Acg: 20 May 99 11:45 pm
Tgt Ion: 152 Resp.- 2149569
Ratio Lower Upper
100
7.1
0.0
0.0
14.5
0.0
0.0
21.1
0.0
0.0
Abundance Ion 164.00 (163.70 to 164.70)
600000 .
26.66
400000 .
200000 .
ENG
Time--> 26.40
26.60
26.80
ENGT33F7D—PES1.M
Mon May 24 U7;57;4U
#7
Acenaphthene-dlO
Concen: 11.42 ng/uL
RT: 26.66 min Scan# 2505
Delta R.T. -0.00 min
Lab File: ENG1339.D
Acq: 20 May 99 11:45 pm
Tgt Ion:164 Resp: 1339510
Ion
164
0
0
0
Ratio
100
0.0
0.0
0.0
Lower Upper
0.0
0.0
0.0
0.0
0.0
0.0
HP 5989B
Page 5
-------
Abundance
1000000 -
500000-
0 _
Titne--> 2
Abundance
600000 '.
400000 -
200000 .
0 .
Time--> 2
TIC: fcJNGl339.D
M
6.40 26.60 26.80 27.00
Ion 154.00 (153. VO to 154.70): ENG
Ion 153.00 (152.70 to 153.70): ENG
26.73
ft
_J\^
' — i 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 r-
6.40 26 60 26.80 27.00
Abundance
1000000 J
Titne-->
TIC: ENG1339.D
500000-
27.80
^ 1 n
28.00
28.20
#8
Acenaphthene(CCC)
Concen: 13.34 ng/uL
RT: 26.73 min Scan# 2517
Delta R.T. -0.00 min
Lab File: ENG1339.D
Acq: 20 May 99 11:45 pm
Tgt Ion:154 Resp: 1423999
Ion
154
153
0
0
Ratio
100
82.8
0.0
0.0
Lower Upper
43.3
0.0
0.0
129.7
0.0
0.0
Abundance Ion 176700 (175.70 to 176.70): ENG
600000 .
400000 .
200000.
27.95
Time-->
27180
28.00
28.20
ENG1339.DPES1.M
#9
Fluorene-dlO
Concen: 13.21 ng/uL
RT: 27.95 min Scan# 2701
Delta R.T. -0.00 min
Lab File: ENG1339.D
Acq: 2 0 May 99 11:45 pm
Tgt Ion:176 Resp: 1354549
Ion Ratio Lower Upper
176 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Mon May 24 07:57:43 1999
HP 5989B
Page 6
-------
Abundance
1000000 -
500000 -
0 _
Time -->
Abundance
600000 .
400000 .
200000 .
0 '.
Time- ->
TIC: ENG1339.D
A
27180 ' 28lo6 ' ' 28.20
Ion 166.00 (165.70 to 166.70): ENG
Ion 165.00 (164.70 to 165.70): ENG
28.02
A
|
!\
— i — i — i — i — i — i — i — i — i — i — i — i — i — i — i — i —
27.80 28.00 28.20
#10
Fluorene
Concen: 13.43 ng/uL
RT: 28.02 min Scan# 2712
Delta R.T. -0.00 min
Lab File: ENG1339.D
Acq: 20 May 99 11:45 pm
Tgt Ion:166 Resp: 1472641
Ion
166
165
0
0
Ratio
100
80.4
0.0
0.0
Lower Upper
40.0
0.0
0.0
119.9
0.0
0.0
[Abundance
800000:
TIC: ENG1339.D
Time--> 30.20
Abundance ion 188.00 (187.7CT to 188.70): ENG
30.40
30.50
800000-
600000-
400000 .
200000 .
Ion
94.00 (93.70 to 94.70): ENG13
30.38
Time--> 30.20
i >' '—i—r—i—i—i—i—i—i—i—r
30.30 30:40 30.50
ENG1J39.D—PES1.M
Mon May 24 07:57:46
#11
Phenanthrene-dl0
Concen: 13.32 ng/uL
RT: 30.38 min Scan# 3070
Delta R.T. -0.00 min
Lab File: ENG1339.D
Acq: 20 May 99 11:45 pm
Tgt Ion:188 Resp: 1678739
Ion
188
94
0
0
Ratio
100
12.2
0.0
0.0
Lower Upper
5.8
0.0
0.0
17.2
0.0
0.0
HP 5989B
Page 7
-------
TIC: ENG1339.D
0
Time--> 30^30
30.40
30.50
Sundance Ion 178.00 (177.70 to 178.70): ENG
Ion 176.00 (175.70 to 176.70): ENG
800000 -
600000:
400000:
200000:
30.44
Time--> 30.30
-i 1 1 r-
30.40
30!50
#12
Phenanthrene
Concen: 13.45 ng/uL
RT: 30.44 min Scan# 3079
Delta R.T. -0.00 min
Lab File: ENG1339.D
Acq: 20 May 99 11:45 pm
Tgt Ion:178 Resp: 1873765
Ion Ratio Lower Upper
178 100
176 17.5 8.5 25.4
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance
800000.
600000 .
400000:
200000 -
Time-->
TIC: ENG1339.D
0
30.40
"• 1 r
30.60
~\ 1 r
Abundancelon 188.00 (187.70 torTSB.70): ENG
SOOOOOJIon 94.00 (93.70 to 94.70): ENG13
600000.
400000.
200000.
30.52
Time - - >
30.40
30.60
ENGT3T9TD
#13
Anthracene-dlO
Concen: 13.67 ng/uL
RT: 30.52 min Scant 3091
Delta R.T. -0.00 min
Lab File: ENG1339.D
Acq: 20 May 99 11:45 pm
Tgt Ion:188 Resp: 1438313
Ion
188
94
0
0
Ratio
100
13.9
0.0
0.0
Lower Upper
6.6
0.0
0.0
19.6
0.0
0.0
OCOMii
.M
MOn May 24 07:57:49 1999
HP 5989B
Page 8
-------
Abundance
800000 :
600000 .
400000:
200000:
Time--> 30.40
TIC: ENG1339.D
30.50
30.60
30.70
Abundance Ion 178.00 (177.70 to 178.70): ENG
Ion 176.00 (175.70 to 176.70): ENG
800000 J
600000 .
400000 -
200000 .
30.57
Time--> 30.40
30.50
30.60
30.70
#14
Anthracene
Concen: 13.82 ng/uL
RT: 30.57 min Scan# 3099
Delta R.T. -0.00 min
Lab File: ENG1339.D
Acq: 20 May 99 11:45 pm
Tgt Ion:178 Resp: 1736842
Ion Ratio Lower Upper
178 100
176 17.0 8.2 24.4
0 0.0 0.0 0.0
0 0.0 0.0 0.0
ENG
Sundance
800000 -
600000 :
400000 :
200000 :
0 "
Time- -> 33
TIC: ENG1339.D
A/1
I
/ ^
120 ' 33140 ' ' 33!60 '
Abundancelon 212.00 (211.70 to 212.70): ENG
600000 1
400000.
200000-
0
Time - - > 3 2
Ion 106.00 (105.70 to 106.70): ENG
33.51
A
y\V
il20 ' ' 33140 ' ' 33!e6 '
r!3^y.D PESl.M raon raay 24 07:57:t>2 iyyy
#15
Fluoranthene-dl0
Concen: 13.86 ng/uL
RT: 33.51 min Scan# 3609
Delta R.T. -0.00 min
Lab File: ENG1339.D
Acq: 20 May 99 11:45 pm
Tgt Ion:212 Resp: 1544629
Ion
212
106
0
0
Ratio
100
16.3
0.0
0.0
Lower Upper
8.0
0.0
0.0
23 .8
0.0
0.0
OCCOM3
HP 5989B
Page 9
-------
Abundance
800000 H
600000 .
400000 :
200000:
TIC: ENG1339.D
Time-->
33140
33160
33.80
Abundance Ion 202.00 (201.70 to 202.70)
ENG
800000 J
600000
Ion 101.00 (100.70 to 101.70): ENG
33.56
400000 J
200000
0 J
Time-->
33.40
33.60
33.80
#16
Fluoranthene(CCC)
Concen: 13.80 ng/uL
RT: 33.56 min Scan# 3617
Delta R.T. -0.00 min
Lab File: ENG1339.D
Acg: 20 May 99 11:45 pm
Tgt Ion:202 Resp: 1828079
Ion Ratio Lower Upper
202 100
101 14.4 6.9 20.6
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance
800000 ..
600000 :
400000:
200000:
Time-->
TIC: ENG1339.D
34.00
34.20
34.40
Abundance Ion 212.00 (211.70 to 212.70): ENG
600000 -
400000 J
200000 -
Ion 106.00 (105.70 to 106.70): ENG
34.18
Time--
— i - 1 - r— i - 1 - 1 - r— — i
34.00 34.20
\ - 1 - 1 - 1 - 1 - 1 - r
34.40
ENGT3T9TD PES1 .M
#17
Pyrene-dlO
Concen: 13.55 ng/uL
RT: 34.18 min Scantf 3710
Delta R.T. -0.00 min
Lab File: ENG1339.D
Acq: 20 May 99 11:45 pm
Tgt Ion:212 Resp: 1652988
Ion
212
106
0
0
Ratio
100
17.8
0.0
0.0
Lower Upper
8.6
0.0
0.0
25.6
0.0
0.0
OCO 31-lG
Mon May 24 07:57:56 1999
HP 5989B
Page 10
-------
KB"
Time-->
TIC: ENG1339.D
600000 -
400000 .
200000 .
34.00
34.20
34.40
Abundancelon 202.00 (201.70 to 202.70)
Ion 101.00 (100.70 to 101.70)
34.24
600000 J
400000:
200000:
0 1
ENG
ENG
Time-->
34.00
34:20
i—I—i
34.40
#18
Pyrene
Concen: 13.69 ng/uL
RT: 34.24 min Scan# 3718
Delta R.T. -0.00 min
Lab File: ENG1339.D
Acq: 20 May 99 11:45 pm
Tgt Ion:202 Resp: 1922904
Ion Ratio
202 100
101 16.5
0 0.0
0 0.0
Lower Upper
7.8
0.0
0.0
23.3
0.0
0.0
Time--> 34.20
TIC: ENG1339.D
eooooo:
400000 .
200000:
34.40
-i 1 1 r
34.60
Abundancelon 244.00 (243.70 to 244.70)
Ion 122.00 (121.70 to 122.70)
34.50
400000.
200000 .
ENG
Time--> 34.20
34:40
1 1 1 1 1 r
34.60
ENGlJjy.D—PES1.M
Mon May 24 U'7:b7:59
#19
p-Terphenyl-d!4
Concen: 13.49 ng/uL
RT: 34.50 min Scan# 3757
Delta R.T. -0.00 min
Lab File: ENG1339.D
Acq: 20 May 99 11:45 pm
Tgt Ion:244 Resp: 1341674
Ion
244
122
0
0
Ratio
100
14.0
0.0
0.0
Lower Upper
6.7
0.0
0.0
19.9
0.0
0.0
OCC344"
HP 5989B
Page 11
-------
Abundance
400000:
300000 -
200000 -
100000 .
TIC: ENG1339.D
Time--> 38.60 38.70 38.80 38.90
Abundance Ion 240.00 (239.70 to 240.70): ENG
Jlon 120.00 (119.70 to 120.70): ENG
300000J 38.77
200000 J
100000 H
Time-->
38.60 38!70 38.80 38.90
#20
Benzo(a)anthracene-dl2
Concen: 14.88 ng/uL
RT: 38.77 min Scan# 4400
Delta R.T. -0.00 min
Lab File: ENG1339.D
Acq: 20 May 99 11:45 pm
Tgt Ion:240 Resp: 1263156
Ion Ratio Lower Upper
240 100
120 15.2 7.3 21.8
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance
j
400000:
300000:
200000:
100000:
Time-->
TIC: ENG1339.D
38.70 38.80 38.90 39.00
Abynaanqelon 228.00 (227.70 to 228.70)
Ion 114.00 (113.70 to 114.70)
38.89
300000-
200000.
100000.
ENG
ENG
Time-->
38.70 38.80 38190 39.00
ENG1339. DPES1.M
#21
Benzo(a)anthracene
Concen: 14.96 ng/uL
RT: 38.89 min Scan# 4418
Delta R.T. -0.00 min
Lab File: ENG1339.D
Acq: 20 May 99 11:45 pm
Tgt Ion:228 Resp: 1473146
Ion Ratio Lower Upper
228 100
114 12.9 6.2 18.5
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Mon May 24 07:58:03 1999
HP 5989B
Page 12
-------
Abundance
TIC: ENG13J9.D
Time-->
38.80
39.00
Sundance I on 240.00 (239.70 to 240.70}
Ion 120.00 (119.70 to 120.70)
300000J
200000 -
100000 -
ENG
ENG
ime-->
38.80
#22
Chrysene-dl2
Concen: 14.54 ng/uL
RT: 38.94 min Scantt 4426
Delta R.T. -0.00 min
Lab File: ENG1339.D
Acq: 20 May 99 11:45 pm
Tgt Ion:240 Resp: 1214223
Ion Ratio Lower Upper
240 100
120 13.0 6.4 19.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance
400000 .
300000 .
200000 .
100000 .
Time-->
TIC: ENG1339.D
0
38.80
-i ' 1 r-
39.00
~i 1 1 1 r
39.20
elon 228.00 (227.70 to 228.70): ENG
Ion 114.00 (113.70 to 114.70): ENG
39.06
300000 .
Time-->
38.80
ENG1JJ9.D—PKS1.M
Mon May 24 07:58:Ufa
#23
Chrysene(CCC)
Concen: 14.91 ng/uL
RT: 39.06 min Scan# 4445
Delta R.T. -0.00 min
Lab File: ENG1339.D
Acq: 20 May 99 11:45 pm
Tgt Ion:228 Resp: 1508140
Ion Ratio Lower Upper
228 100
114 11.3 5.5 16.3
0 0.0 0.0 0.0
0 0.0 0.0 0.0
OCCjilo
HP 5989B Page 13
-------
Abundance
400000:
TIC: ENC1339.D
Time-->
45160
45.80
Abundancelon 264.00 (263.70 to 264.70)
Ion 132.00 (131.70 to 132.70)
200000 .
"ETJG~
ENG
45.71
150000 J
100000:
50000:
rritne-->
45.60
45.80
#24
Benzo(b)fluoranthene-dl2
Concen: 14.90 ng/uL
RT: 45.71 min Scan# 5467
Delta R.T. -0.00 min
Lab File: ENG1339.D
Acq: 20 May 99 11:45 pm
Tgt Ion:264 Resp: 1203297
Ion Ratio Lower Upper
264 100
132 17.0 8.0 23.9
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance
400000 :
300000:
200000:
100000:
Time--> 45 .60
TIC: ENG1339.D
0
45.80
46.00
46120
Abundancelon 252.00 (251.70 to 252.70): ENG
Ion 126.00 (125.70 to 126.70): ENG
200000-
100000.
Time--> 45 .60
45.80
46.00
46.20
ENG1339.D—PES1.M
Mon May 24 07:b8:U9
#25
Benzo (b) f luoranthene
Concen: 15.20 ng/uL
RT: 45.92 min Scan# 5499
Delta R.T. -0.00 min
Lab File: ENG1339.D
Acq: 20 May 99 11:45 pm
Tgt Ion: 252 Resp: 1408550
Ion Ratio Lower Upper
100
7.3 21.8
0.0 0.0
0.0 0.0
252
126
0
0
14.9
0.0
0.0
OCC34*1;
HP 5989B Page 14
-------
Abundance
400000.
TIC: ENG1339.D
Time-->45.60
45.80
46.00
46.20
Abundance I on 264.00 (263.70 to 264.70): ENG
Ion 132.00 (131.70 to 132.70): ENG
200000.
45.93
Time-->45.60
45.80
46.00
46.20
#26
Benzo(k)fIuoranthene-dl2
Concen: 15.05 ng/uL
RT: 45.93 min Scan# 5501
Delta R.T. -0.00 min
Lab File: ENG1339.D
Acq: 20 May 99 11:45 pm
Tgt Ion:264 Resp: 1378887
Lower Upper
Ion
264
132
0
0
Ratio
100
17.9
0.0
0.0
8.5
0.0
0.0
25.3
0.0
0.0
[Abundance
400000 4
300000J
200000:
100000:
TIC: ENG1339.D
Time--> 45.80
0
46.00
46.20
Sundance Ion 252.00 (251.70 to 252.70)
Ion 126.00 (125.70 to 126.70)
46.09
200000.
100000 .
ENG
ENG
rime--> 45.80
46100
46.20
ENG1339.DPES1.M
#27
Benzo(k)fluoranthene
Concen: 14.87 ng/uL
RT: 46.09 min Scan# 5525
Delta R.T. -0.00 min
Lab File: ENG1339.D
Acq: 20 May 99 11:45 pm
Tgt Ion:252 Resp: 1473217
Ion
252
126
0
0
Ratio
100
16.3
0.0
0.0
Lower Upper
7.8
0.0
0.0
23.2
0.0
0.0
MOn May 24 07:58:1-2 1999
HP 5989B
OC0044S
Page 15
-------
[Ab-
undance
200000 :
150000:
100000:
50000:
TIC: ENG1339.D
Time--> 48.00 48.20 48.40 48.60
Abundancelon 264.00 (263.70 to 264.7U)
Ion 132.00 (131.70 to 132.70)
150000-
100000 .
50000 i
"ENS'
ENG
48.37
Time--> 48.00 48.20 48.40 48.60
#28
Benzo(a)pyrene-d!2
Concen-. 15.71 ng/uL
RT: 48.37 min Scantt 5875
Delta R.T. -0.00 min
Lab File: ENG1339.D
Acq: 20 May 99 11:45 pm
Tgt Ion:264 Resp: 1217609
Ion Ratio Lower Upper
264 100
132 18.5 8.7 25.9
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance
200000:
Time--> 48.00
TIC: ENG1339.D
48.50
49.00
Abundancelon 252TOO (251.70 to2527TO): ENG
200000 J
150000:
100000:
50000:
o:
Ion 126.00 (125.70 to 126.70): ENG
48.59
Time--> 48.00
48.50
49.00
ENG1339.DPES1.M
#29
Benzo(a)pyrene(CCC)
Concen: 15.47 ng/uL
RT: 48.59 min Scantf 5908
Delta R.T. -0.00 min
Lab File: ENG1339.D
Acq: 20 May 99 11:45 pm
Tgt Ion:252 Resp: 1471012
Ion Ratio Lower Upper
252 100
126 14.4 7.6 22.6
0 0.0 0.0 0.0
0 0.0 0.0 0.0
OCC-'l-K'Q
Mon May 24 07:bB:lb 1999
HP 5989B
Page
-------
Abundance
300000 j
200000.
100000 .
TIC: ENG1339.D
Time--> 60.50
Abundance Ion 288.00 (287.70 to 288.70)
61.00
61.50
62.00
ENG
100000 .
50000 .
0-
61.27
Time--> 60.50
61.00
61.50
62:00
#30
Indenod, 2, 3-cd) pyrene-d!2
Concen: 16.12 ng/uL
RT: 61.27 min Scantt 8062
Delta R.T. -0.00 min
Lab File: ENG1339.D
Acq: 20 May 99 11:45 pm
Tgt Ion:288 Resp: 1547005
Ion Ratio Lower Upper
288 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance
300000 -i
200000 .
100000 .
Time--> 61.00
TIC: ENG1339.D
61150
62.00
Abundance ion 276.05 (275.75 to 276.75): ENG
Ion 138.00 (137.70 to 138.70): ENG
61.62
100000 -
50000 .
0 .
Iime--> 61.00
61.50
62.00
ENGlJjy.D—PES1.M
Mon May 24 U7:b8;^U
#31
Indenod, 2, 3-cd)pyrene
Concen: 15.30 ng/uL
RT: 61.62 min Scan# 8128
Delta R.T. -0.00 min
Lab File: ENG1339.D
Acq: 20 May 99 11:45 pm
Tgt Ion:276.05 Resp: 160544J
Ion Ratio
276 100
138 23.5
0 0.0
0 0.0
Lower Upper
15.1
0.0
0.0
45 .1
0 .0
0 .0
OC03
HP 5989B
Page 17
-------
Abundance
300000
200000 .
100000 -
TIC
j 1 1 1 1 1 1 1 1 1 1 r-
Time--> 60.50 61.00 61.50
;elon 292.00 (291.70 to 292.70)
61.20
60000 :
40000:
20000:
o:
Time--> 60.50
61.00
61.50
Abundance
300000 j
200000 .
100000 -
TIC: ENG1339.D
rime--> 61.00
6l!50
62.00
#32
Dibenz(a,h)anthracene-d!4
Concen: 16.62 ng/uL m
RT:' 61.20 min Scan# 8050
Delta R.T. -0.00 min
Lab File: ENG1339.D
Acq: 20 May 99 11:45 pm
Tgt Ion:292 Resp: 1019842
Ion Ratio Lower Upper
100
292
0
0
0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
Abundance Ion 278.00 (277.70 to 278.70)
Ion 139.00 (138.70 to 139.70)
61.63
100000 .
50000 .
0 .
ENG
ENG
[Time--> 61.00
61.50
62!00
ENG133y.D
#33
Dibenz(a,h)anthracene
Concen: 15.65 ng/uL
RT: 61.63 min Scan# 8129
Delta R.T. -0.00 min
Lab File: ENG1339.D
Acq: 20 May 99 11:45 pm
Tgt Ion:278 Resp: 1461059
Ion Ratio
278 100
139 14.6
0 0.0
0 0.0
Lower Upper
10.6 31.6
0.0 0.0
0.0 0.0
Mon May 24 07:58:23 1999
HP 5989B
Page 18
-------
Abundance
100000 -
50000 J
TIC: ENG1339.D
0
rime--> 64.00
64:50
65.00
Abundancelon 288.00 (287.70 to 288.70)
80000: 64.77
60000 J
40000 :
20000:
ENG
0 J
Time--> 64.00
64.50
65.00
#34
Benzo(g,h,i)perylene-d!2
Concen: 15.64 ng/uL
RT: 64.77 min Scan# 8760
Delta R.T. -.0.00 min
Lab File: ENG1339.D
Acq: 20 May 99 11:45 pm
Tgt Ion:288 Resp: 1267730
Ion Ratio Lower Upper
288 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance
100000 .
50000 .
Titne--> 64.50
TIC: ENG1339.D
65.00
65150
Abundance Ion 276.00 (275.70 to 276.70)
Ion 138.00 (137.70 to 138.70)
65.19
100000 J
50000 .
ENG
ENG
rime--> 64.50
65. 00
65150
ENG1J39.D—PfiSl.M
#35
Benzo(g,h,i)perylene
Concen: 15.20 ng/uL
RT: 65.19 min Scan# 8862
Delta R.T. -0.00 min
Lab File: ENG1339.D
Acq: 20 May 99 11:45 pm
Tgt Ion:276 Resp: 1469893
Ion
276
138
0
0
Ratio
100
10.0
0.0
0.0
Lower Upper
10.7
0.0
0.0
42. 6#
0.0
0.0
OCC
Mon May '24 07:58:27 1999
HP 5989B
Page 19
-------
Evaluate Continuing Calibration Report
Data File
Acq On
Sample
Misc :
Method
Title
Last Update
Response via
Min. RRF
Max. RRF Dev
C:\HPCHEM\1\DATA\9919\ENG1321.D
19 May 99 10:51 am
PES-MAH-051299-06 7ng//zL
C:\HPCHEM\1\METHODS\PES.M
Wed May 19 12:02:47 1999
Multiple Level Calibration
Vial: l
Operator: JEMcCartney
Inst : HP 5989B
Multiplr: 1.00
0.000 Min. Rel. Area
30% Max. Rel. Area
1% Max. R.T. Dev O.SOmin
500%
Compound
AvgRF CCRF
%Dev Area% Dev(min)
1
2
3
4
5
6
7
8
9
1 0
1
j.2
13
4
_5
16
7
3
19
"0
L
22
73
1
t.5
26
1
_ 3
29
' D
L
32
°3
. I
35
S
s
s
s
s
s
s
s
s
s
s
s
s
s
s
s
s
s
2 , 2 -Dif luorobiphenyl
Naphthalene-d8
Naphthalene (CCC)
2-Methlynaphthalene-dlO
Acenaphthylene-d8
Acenaphthylene
Acenaphthene - dl 0
Acenaphthene (CCC)
Fluorene-dlO
Fluorene
Phenanthrene-dlO
Phenanthrene
Anthracene -dlO
Anthracene
Fluoranthene-dlO
Fluoranthene (CCC)
Pyrene-dlO
Pyrene
p-Terphenyl-d!4
Benzo (a) anthracene-d!2
Benzo (a) anthracene
Chrysene-dl2
Chrysene(CCC)
Benzo (b) fluoranthene-d!2
Benzo (b) f luoranthene
Benzo (k) f Iuoranthene-dl2
Benzo (k) f luoranthene
Benzo (a) pyrene-d!2
Benzo (a) pyrene {CCC)
Indenod, 2, 3-cd)pyrene-dl2
Indeno(l,2, 3 -cd) pyrene
Dibenz (a, h) anthracene-d!4
Dibenz (a, h) anthracene
Benzo (g, h, i) perylene-d!2
Benzo (g,h, i)perylene
1
1
l
0
1
1
1
1
1
1
1
2
1
2
1
2
1
2
1
1
1
1
2
1
1
1
1
1
1
1
1
0
1
1
1
.000
.524
.773
.808
.607
.792
.066
.196
.156
.394
.792
.173
.557
.095
.774
.345
.948
.537
.473
.250
.823
.514
.102
.115
.598
.518
.767
.009
.503
.353
.598
.795
.299
.072
.394
1
1
1
0
1
1
1
1
1
1
1
2
1
2
1
2
1
2
1
1
1
1
1
1
1
1
1
1
1
1
1
0
1
1
1
.000
.214
.634
.757
.689
.947
.151
.383
.194
.535
.617
.138
.564
.080
.576
.041
.667
.158
.383
.307
.783
.493
.894
.247
.685
.732
.904
.195
.614
.446
.650
.840
.312
.162
.417
0
20
7
6
-5
-8
-8
-15
-3
-10
9
1
-0
0
11
13
14
14
6
-4
2
1
9
-11
-5
-14
-7
-18
-7
-6
-3
-5
-1
-8
-1
.0
.3 •
.8
.4
.1
.7
.0
.7
.2
.1
.7
.6
.4
.7
.2
.0
.4
.9
.1
.6
.2
.4
.9
.9
.5
.1
.7
.4
.4
.9
.2
.7
.0
.4
.7
C
191
- 143
168
165
177
185
188
208
178
190
159
175
182
180
171
166
164
162
179
178
173
180
161
190
181
205
191
195
168
176
170
181
167
181
171
ip.o ~o
Jtv, Jo'
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
p'
.01
.00
.00
.01
.00
.00
.01
.00
.01
.01
.01
.01
.01
.01
.01
.01
.02
.02
.00
.02
.02
.03
.02
.03
.03
.04
.04
.04
.05
.07
.08
.07
.08
.07
.07
o
A*
•*#) = Out of Range
ENG1321.D PES.M
SPCC's out = 0 CCC's out = 0
Wed May 19 12:08:37 1999 HP 5989B
Page 1
-------
Quantitation Report
C:\HPCHEM\1\DATA\9919\ENG1321.D
19 May 99 10:51 am
PES-MAH-051299-06
Data File
Acq On
Sample
Misc :
Quant Time: May 19 12:00 1999
Vial: l
Operator: JEMcCartney
Inst : HP 5989B
Multiplr: 1.00
Method
Title
Last Update
Response via
C:\HPCHEM\1\METHODS\PES.M
Wed May 19 12:02:47 1999
Multiple Level Calibration
Internal Standards
R.T. Qlon Response Cone Units Dev(Min)
1)
2 , 2 -Dif luorobiphenyl
24
.60
190
2396016
5
.00
System Monitoring Compounds
2)
4)
5)
7)
9)
11)
13)
15)
17)
19)
20)
22)
24)
26)
28)
30)
32)
34)
Naphthalene-d8
2-Methlynaphthalene-dlO
Acenaphthylene-d8
Acenaphthene - dl 0
Fluorene-dlO
Phenanthrene-dlO
Anthracene-dlO
Fluor ant hene-dlO
Pyrene-dlO
p-Terphenyl -d!4
Benzo (a) anthracene-d!2
Chrysene-dl2
Benzo (b) f Iuoranthene-dl2
Benzo (k) f Iuoranthene-dl2
Benzo (a) pyrene-d!2
Indeno (1,2, 3-cd) pyrene-d!2
Dibenz (a, h) anthracene-d!4
Benzo (g, h, i) perylene-dl2
22
23
26
26
28
30
30
33
34
34
38
39
45
46
48
61
61
65
.24
.97
.29
.72
.02
.45
.58
.58
.27
.58
.89
.06
.90
.11
.58
.55
.51
.13
136
152
160
164
176
188
188
212
212
244
240
240
264
264
264
288
292
288
4072870
2574514
5665181
3860599
4004263
5424358
5246534
5285196
5592668
4639055
4383671
5007776
4183489
5810884
4009804
4850965
2816046
3897180
5
6
7
7
7
6
7
6
5
6
7
6
7
7
8
7
7
7
.58
.65
.36
.56
.23
.32
.03
.22
.99
.57
.32
.90
.83
.99
.29
.48
.40
.59
Target Compounds
3)
6)
8)
10)
12)
14)
16)
18)
21)
23)
25)
27)
29)
31)
33)
35)
Naphthalene (CCC)
Acenaphthylene
Acenaphthene (CCC)
Fluorene
Phenanthrene
Anthracene
Fluoranthene (CCC)
Pyrene
Benzo (a) anthracene
Chrysene(CCC)
Benzo (b) f luoranthene
Benzo (k) f luoranthene
Benzo (a)pyrene (CCC)
Indeno (1,2, 3-cd)pyrene
Dibenz (a, h) anthracene
Benzo (g, h, i) perylene
22
26
26
28
30
30
33
34
39
39
46
46
48
61
61
65
.29
.33
.79
.09
.50
.63
.63
.32
.00
.18
.09
.27
.79
.91
.93
.51
128
152
154
166
178
178
202
202
228
228
252
252
252
276
278
276
5479606
6530965
4640437
5148520
7171437
6977737
6845280
7238162
5982002
6352600
5653298
6386677
5412393
5534551
4402408
4752539
6
7
8
7
6
6
6
5
6
6
7
7
7
7
7
7
.45
.61
.10
.71
.89
.95
.09
.95
.85
.31
.38
.54
.52
.23
.07
.12
ng/uL 0
.01
%Recovery
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL m
ng/uL m
ng/uL m
ng/uL m
ng/uL m
Qvalue
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uLm
ng/uL
ng/uL#
ng/uL
ng/uL
OCC'}S.i
88
100
88
83
96
98
98
100
99
96
97
86
85
18
95
72
"• (^
- -i
(#) = qualifier out of range (m) = manual integration
ENG1321.D PES.M Wed May 19 12:08:57 1999 HP 5989B
Page 1
-------
Quantitation Report
Data File : C:\HPCHEM\1\DATA\9919\ENG1321.D
Acq On : 19 May 99 10:51 am
Sample : PES-MAH-051299-06 7ng/>L
Misc :
Quant Time: May 19 12:00 1999
Method
Title
Last Update
Response via
C:\HPCHEM\1\METHODS\PES.M
Wed May 19 12:02:47 1999
Multiple Level Calibration
Vial: 1
Operator: JEMcCartney
Inst : HP 5989B
Multiplr: 1.00
Abundance
4500000 j
TIC: ENG1321.D
4000000 „
3500000 _;
3000000 .
2500000 1 :
j
2000000 1
1500000 _"
1000000 _
500000 .
n
Time--> 20.00
J
3
4s
6
5
1
1
;
9
3
0
i:
3
30.
S
s
00
1
1*
1
6
'
'
L
8
,s
9S
2
23
2C
4C
1 -~
4^£
^
s
2-!
J
).00
.
&
i-CD
7
29 3J
S
28s
3Q6 35
1 1 3¥
ill
I
^ ^ • V_ j I
soloo eoloo
ENG1321.D PES.M
Wed May 19 12:09:07 1999
HP 5989B
Page 2
-------
Abundance
i 2000000 J
TIC: ENG1321.D
1500000 _
1000000 2
500000
(r
#2
Naphthalene-d8
Concen: 5.58 ng/uL
RT: 22.24 min Scantf 1567
Delta R.T. 0.01 min
Lab File: ENG1321.D
Acq: 19 May 99 10:51 am
i Tgt Ion:136 Resp: 4072870
Ion Ratio Lower Upper
136 100
68
ime-->
22.10
22.20
22.30
Abundance I on 136.00
j ]Ion 68.00
1 "!
' 1500000J
1000000
500000 J
(135.70 to 136.70): ENG
(67.70 to 68.70): ENG13
0
0
16.7
0.0
0.0
10.1
0.0
0.0
30.1
0 .0
0.0
Time-->
22 .10
22.20
22 .30
'Abundance
I 2000000 J
! 1500000 J
1000000
500000:
TIC: ENG1321.D
0 I.
I #3
Naphthalene(CCC)
Concen: 6.45 ng/uL
RT: 22.29 min Scan# 1575
Delta R.T. 0.01 min
Lab File: ENG1321.D
Acq: 19 May 99 10:51 am
Tgt Ion:128 Resp: 5479606
Ion Ratio Lower Upper
128 100
127
0
22 iOO
22.20
22.40
14 .3
0.0
0.0
0.0
0.0
0.0
60 .0
0.0
0.0
'Abundancelon 128.00 (127.70 to 128.70): ENG
1 I
i
2000000 :
i :
i 1500000 -
1
: 1000000 J
1
1
1
| 500000 :
i o :
Time--> 2
Ion 127.00 (126.70 to 127.70): ENG
22 .29
A
/ i
; ,
,' i
, i
/ \
^/\v
2100 22120 22140 '
ENG1321.D PES.M Wed May 19 12:09:10 lyyy
OCC'jSc,
HP 5989B
Page 3
-------
Abundance
800000 :
600000
400000 :
TIC: ENG1321.D
200000 _
n -
Time--> 23:80
Abundance Ion 152.00
1000000 1
I \
I \
J V_
24:00 24:20
(151.70 to 152.70) : EttG
23.97
A
152
0
0
0
500000 .
#4
2-Methlynaphthalene-dl0
Concen: 6.65 ng/uL
RT: 23.97 min Scan# 1931
Delta R.T. 0.01 min
Lab File: ENG1321.D
Acq: 19 May 99 10:51 am
Tgt Ion:152 Resp: 2574514
Ion Ratio Lower Upper
100
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0
Time-->
Abundance
3000000 1
! 2000000 J
. 1000000:
n
23 80
24 00
24 20
TIC: ENG1321.D
V
Time--> 26.00
2620
26:40
\
2000000 J
26.29
#5
Acenaphthylene-d8
Concen: 7.36 ng/uL
RT: 26.29 min Scan# 2451
Delta R.T. 0.01 min
Lab File: ENG1321.D
Acq: 19 May 99 10:51 am
Tgt Ion:160 Resp: 5665181
Ion Ratio Lower Upper
160 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance Ion 160.00 (159.70 to 160.70) : ENG
1000000 _
0 '
Time--> 26.00
26:20
26:40
ENG1J21.D PESTFT
Wed May 19 12:09:13 1999
oe<
HP 5989B
Page 4
-------
Abundance
; 3000000 ^
H
! j
2000000 -,
1000000
0
Time-->
TIC: ENG1321.D
/\
#6
Acenaphthylene
Concen: 7.61 ng/uL
RT: 26.33 min Scantt 2456
Delta R.T. 0.01 min
Lab File: ENG1321.D
Acq: 19 May 99 10:51 am
Tgt Ion:152 Resp: 6530965
Ion Ratio Lower Upper
100
15.2
0.0
26.20
26.40
26.60
Abundance Ion 152.00' (151.70 to 152.70): ENG
3000000Jlon 153.00 (152.70 to 153.70): ENG
\ 26.33
2000000 J
1000000 ^
152
153
0
0
0.0
7.6
0.0
0.0
22 .6
0.0
0.0
0
Time-->
Abundance
3000000
2000000
26.20
26.40
26.60
TIC: ENG1321.D
#7
Acenaphthene-dlO
Concen: 7.56 ng/uL
| RT: 26.72 min Scan# 2514
Delta R.T. 0.01 min
Lab File: ENG1321.D
Acq: 19 May 99 10:51 am
A
1000000 J / \ ' ^
^ 1 \l \
i / V \
n 1 J ^
Tgt Ion: 164
Ion Ratio
164
0
n
Time--> ' 26160' '26 170' '26180 ! j 0
100
0
0
0
.0
.0
.0
Resp: 3860599
Lower Upper
0
0
0
.0
. 0
.0
0
0
0
.0
. 0
.0
Abundancelon 164.00 (163.70 to 164.70)
ENG
i 1500000 '
1000000
500000 J
26.72
[Time--> 26.60 26.70 26:80
ENG1321.DPES.M
Or,
wea May 19 12 : 09 :16 iyyy
HP 5989B
Page 5
-------
Abundance
i
1 3000000 _
| J
2000000 J
, 1
1 1000000 J
TIC: ENG1321.D
0
fTime--> 26!40 26.60 26^80 27.00
pvbundancelon 154.00 (153.70 to 154.70): ENG
; 2000000Jlon 153.00 (152.70 to 153.70): ENG
! ' 26.79
1500000 1
! 1000000 :
i .
. sooooo;
0
Time--> 26^40 26160 26180 27100
Abundance
TIC: ENG1321.D
3000000
J
•i
2000000 _
H
1000000 _
0
'Time - - > 27 . 80 2 8 ! 0 0 28^20
(Abundance ion 176.00 (175.70 to 176.70): ENG
1500000
1
28 .02
A
/ \
i \
1000000
500000 J
#8
Acenaphthene(CCC)
Concen: 8.10 ng/uL
RT: 26.79 min Scantf 2525
Delta R.T. 0.01 min
Lab File: ENG1321.D
Acq: 19 May 99 10:51 am
Tgt Ion:154 Resp: 4640437
Ion Ratio
154 100
153 97.6
0 0.0
0 0.0
Lower Upper
43.5
0.0
0.0
130.3
0.0
0.0
Fluorene-dlO
Concen: 7.23 ng/uL
RT: 28.02 min Scan# 2710
Delta R.T. 0.01 min
Lab File: ENG1321.D
Acq: 19 May 99 10:51 am
Tgt Ion:176 Resp: 4004263
Ion Ratio Lower Upper
176 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
J
i
[Time-
ENG132T7
->
rr~
PES
27
.M
:so
wed
—i 1 1 r
2s:oo
May 19
1
12
28
:09
20
T20
1999
HP 5989B
page 6
-------
Abundance TIC: E]
i 1
! 3000000 .j
1
j
| •
2000000 J
NC.
A
51321. D
!
#10
Fluorene
Concen: 7.71 ng/uL
RT: 28.09 min Scantt 2721
Delta R.T. 0.01 min
Lab File: ENG1321.D
Acq: 19 May 99 10:51 am
1000000
o
Time-->
Abundance
2000000 _
1500000 -
1000000 -
500000 .
0
\/
/ "
J
27.80 28.00
Ion 166.00 (165.
Ion 165.00 (164.
2i
\ I
3 /
\ J
i
\
28
70 to
70 to
3 .09
K
\\
\
\
i
\
\
V
20 28140
166.70) : ENG
165.70) : ENG
166 100
165 90.4
0 0.0
0 0.0
Tgt Ion:166 Resp: 5148520
Ion Ratio Lower Upper
38.2
0.0
0.0
114 .4
0.0
0.0
Time-->
27!80
28 !00
28^20
28.40
Abundance
3000000
2000000 ]
j
1000000 _
TIC: ENG1321.D
A
V
Time--> 30.30
30.40
30150
Abundance Ion 188.00 (187.70 to 188.70) : ENG
: lion 94.00 (93.70 to 94.70): ENG13
30.45
2000000 -
1000000
0
1
#11
Phenanthrene-dl0
Concen: 6.32 ng/uL
RT: 30.45 min Scan# 3079
Delta R.T. 0.01 min
Lab File: ENG1321.D
Acq: 19 May 99 10:51 am
Tgt Ion:188 Resp: 5424358
Ion Ratio Lower Upper
188 100
94 26.3 15.1 45.1
0 0.0 0.0 0.0
0 0.0 0.0 0.0
iTime--> 30.30
-i—i—i—i—•—
30:40
1 1 1 r
30!50
ENGTJ2T7D PES.M
Wed May 19 12:09:2J
firr -10
"
-------
Abundance
3000000 ^
TIC: ENG1321.D
1
2000000
1000000 J
.> /
n * ^
Time--> 30^40
Abundance I on 178.00
ilon 176 .00
3000000 J
i
V
176 21.6
n n n
30150 30^60 0 0.0
(177 .70
(175.70
to 178
to 176
.70) : ENG
.70) : ENG
30.50
A! V
/ \ i
#12
Phenanthrene
Concen: 6.89 ng/uL
RT: 30.50 min Scantf 3088
Delta R.T. 0.01 min
Lab File: ENG1321.D
Acq: 19 May 99 10:51 am
Tgt Ion:178 Resp: 7171437
Ion Ratio Lower Upper
178 100
10.1 30.1
0.0 0.0
0.0 0.0
2000000
1000000
0
fTime-->
• ^// Vs_ _^S \
30!40 30.'50 ' ' 30.60
Abundanc
3000000
2000000
1000000
0
Time-->
8 TIC: ENG1321.D
j- A A
i A M A ; i
; AM /v1
- ' 1 1 !
1 ' W i ; 1
i i v 1 ' !
1 / 1;' 1
i ; V \v
30!40 30:60 30i80
Abundancelon 188.00 (187.70 to 186.70): ENG
lion 94.00 (93.70 to 94.70): ENG13
! o n c o
#13
Anthracene-dlO
Concen: 7.03 ng/uL
RT: 30.58 min Scan# 3100
Delta R.T. 0.01 min
Lab File: ENG1321.D
Acq: 19 May 99 10:51 am
Tgt Ion:188 Resp: 5246534
Ion Ratio Lower Upper
188 100
94 30.0 15.1 45.1
0 0.0 0.0 0.0
0 0.0 0.0 0.0
I 2000000 4 A A
i 1000000 J
'A '
T
|Time--> 30.40 30160 30180
ENGlTZTTD PKi>.M Wed May 19
HP 5989B
Page 8
-------
ENGT
Abundance TIC: ENG1321.D
A n
I \ / \
3000000 j ' \ / \
h / i A/ 1
2000000 j \ / j ,' W i,
' \ 1 •' i
i V i
1000000 J /
1 \ /
n] ^ V
p?ime- -> 30.50 3ol60 3o!70 ' 30 80
Abundancelon 178.00 (177.70 to 178.70): ENG
lion 176.00 (175.70 to 176.70): ENG
! 3000000 ^ 30.63
" A A
: / \
| 2000000 _| 1 \ I
1 ! \ M
. 1000000 . / \ / \
] 1 '
•yM ''/y\
1 o^y w yy Vv
Time--> 30!50 30^60 3o!70 30 80
'Abundance TIC: ENG1321.D
i 3000000 J A
i \
\ } \
: ^ A /
; 2000000 1 i \j \
~ I \
^ ' 1
1000000 H I I
' i !
' : i \
! n : 7 V_
[Time--> 33140 33 60 33i80
Abundancelon 212.00 (211. '70 to 212.70): ENG
Uon 106.00 (105.70 to 106.70): ENG
2000000 J 33.58
: ! A
f i
1500000 j / 1
-i ' \
! ^ 1 1
! 1000000 ^ ' i
• ; i 1;
500000 ^ !/\ '
Time--> 33.40 33.60 33180
#14
Anthracene
Concen: 6.95 ng/uL
RT: 30.63 min Scan# 3108
Delta R.T. 0.01 min
Lab File: ENG1321.D
Acq: 19 May 99 10:51 am
Tgt Ion:178 Resp: 6977737
Ion Ratio Lower Upper
178 100
176 20.9 10.1 30.1
On n n A on
-------
Abundance
3000000 I,
2000000 -
j
1000000 J
TTU7
0
ENG1321.D
A
Time-->
33.40
33160
33.80
#16
Fluoranthene(CCC)
Concen: 6.09 ng/uL
RT: 33.63 min Scan# 3628
Delta R.T. 0.01 min
Lab File: ENG1321.D
Acq: 19 May 99 10:51 am/
Tgt Ion:202 Resp: 6845280
Ion Ratio Lower Upper
202 100
28.0
0.0
101
0
0
0.0
13.6
0.0
0.0
Abundance Ion 202.00
I lion. 101.00
2000000 _
(201.70 to 202.70): ENG
(100.70 to 101.70): ENG
33.63
40.6
0.0
0.0
1000000 .i
Time-->
Abundance
3000000 J
-t
i
j
2000000 1
1000000 J
JL
33 .40
33 .60
33 I
TIC: ENG1321.D
J
Time-->
34.00
34.20
34.40
#17
Pyrene-dlO
Concen: 5.99 ng/uL
RT: 34.27 min Scantf 3722
Delta R.T. 0.02 min
Lab File: ENG1321.D
Acq: 19 May 99 10:51 am
Tgt Ion:212 Resp: 5592668
Ion Ratio Lower Upper
100
35.6
0.0
212
106
0
0
lAbundance Ion 212.00
}Ion 106.00
2000000
1
(211.70 to 212 .70) : ENG
(105.70 to 106.70): ENG
34.27
1500000 4
0.0
17.1
0.0
0.0
51.1
0.0
0.0
1000000 J
1
I
500000 J
^
n ]
Time--> 34.00
' i
A ••
J \ ^
34.20 34140
Wed May 19 12:09:32 1999
HP 5989B
OCC3S/3
Page 10
-------
Abundance
i 3000000 J
i J
2000000
TIC: ENG1321.D
A
1000000 J
i #18
I Pyrene
j Concen: 5.95 ng/uL
j RT: 34.32 min Scan# 3730
| Delta R.T. 0.02 min
Lab File: ENG1321.D
Acq: 19 May 99 10:51 am
Tgt Ion:202 Resp: 7238162
Ion Ratio Lower Upper
202 100
101
0
Time-->34.00
34.20
34.40
jAbundancelon 202.00 (201.70 to 202.70) : ENG
Jlon 101.00 (100.70 to 101.70): ENG
\ 34.32
2000000 j
0
31.9
0.0
0.0
16.1
0.0
0.0
48 .1
0 .0
0.0
1000000 4
Time-
->34
i — ' — ' —
.00
34
i' ! '
.20
— i — i —
34
~] 1 1 1 —
.40
' '
Abundance
3000000 _|
A
TIC: ENG1321.D
2000000
1000000 J
rv
#19
p-Terphenyl-d!4
Concen: 6.57 ng/uL
RT: 34.58 min Scan# 3769
Delta R.T. 0.01 min
Lab File: ENG1321.D
Acq: 19 May 99 10:51 am
Tgt Ion:244 Resp: 4639055
Ion Ratio Lower Upper
244 100
4
1
0
Time-->
Abundance
i
i j
\
\ 1500000 :
i
i
i
i
i 1000000 :
i
i
i
. sooooo :
j
0
Time-->
V^ J
34^40 34
Ion 244.00 (243.70
Ion 122.00 (121.70
34.5
A
\
1
i
A
A
//
/
34140 34
\
60 34 80
to 244.70) : ENG
to 122.70) : ENG
8
t
1
\
\
\
\
\\
\^~
— ; — i — i — i — i — i — i —
60 34.80
122 26.5 13.6 40.6
n on on n n
w \J * \J \J f \J U.U
0 0.0 0.0 0.0
ENGT3-2T
HP 5989B
Page 11
-------
Abundance
i 2000000 -
. 1500000 :j
! 1000000 j
TIC: ENG1321.D
#20
Benzo(a)anthracene-d!2
Concen: 7.32 ng/uL
RT: 38.89 min Scan# 4419
Delta R.T. 0.02 min
Lab File: ENG1321.D
Acq: 19 May 99 10:51 am
Tgt Ion:240 Resp: 4383671
500000
0
Time- ->
-: / v v,
i j
\ _x
38170 38i80 '38i90 391 00 ' :
Abundancelon 240.00 (239.70 to 240.70): ENG
1000000
lion 120.00 (119.70 to 120.70): ENG
1 38.89
Ion Ratio Lower Upper
240 100
120 31.4 15.1 45.1
0 0.0 0.0 0.0
0 0.0 0.0 0.0
500000 -,
Time--> 38.70 38.80 38.90 39:00
Abundance
2000000 -
i
i
1 1500000 .
i 1000000 -
! 500000-
i
TIC: ENG1321.D
A
; \
i \ /
A \ / -
/ \ / \ \
/ \ \ 1 \
/ w \ / \
/ ^ \J \
j ^
brime--> 38i80 39:00 39^20
Abundancelon 228.00 (227.70 to 228.70): ENG
! lion 114.00 (113.70 to 114.70): ENG
! 1500000 j
i 1000000
500000
fTime-->
38l80
39IOO
#21
Benzo(a)anthracene
Concen: 6.85 ng/uL
RT: 39.00 min Scan# 4435
Delta R.T. 0.02 min
Lab File: ENG1321.D
Acq: 19 May 99 10:51 am
Tgt Ion:228 Resp: 5982002
Ion Ratio Lower Upper
228 100
114 24.6 12.6 37.6
0 0.0 0.0 0.0
0 0.0 0.0 0.0
ENGT3^
PES.M
Wed May 19 12:09:38 1999
HP 5989B
12
-------
Abundance
2000000 -;
i
: j
| 1500000 J
TIC: ENG1321.D
1 1000000 J
500000
#22
Chrysene-dl2
Concen: 6.90 ng/uL
RT: 39.06 min Scan# 4444
Delta R.T. 0.03 min
Lab File: ENG1321.D
Acg: 19 May 99 10:51 am
Tgt Ion:240 Resp: 5007776
fTime--> 38^80 ' ' 39^00 ' 39
JAbundancelon 240.00 (239.70 to 240
! lion 120.00 (119.70 to 120
1 39.06
1 1000000 J « A
; l \ \
: 1 1
20
.•70) -. ENG
.70) : ENG
500000
Ion Ratio
240 100
120 26.2
0 0.0
0 0.0
Lower Upper
15.1
0.0
0.0
45 .1
0.0
0.0
Time--> 38.80
39.00
39.20
'Abundance
i 2000000 -i
1500000:
1000000
500000 J
TIC: EUG1321.D
jTime--> 39:oo 39;20 39:40
lAbundancelon 228.00 (227.70 to 228.70): ENG
lion 114.00 (113.70 to 114.70): ENG
#23
Chrysene(CCC)
Concen: 6.31 ng/uL
RT: 39.18 min Scan# 4463
Delta R.T. 0.02 min
Lab File: ENG1321.D
Acq: 19 May 99 10:51 am
Tgt Ion:228 Resp: 6352600
Ion Ratio Lower Upper
228 100
114
0
0
23.2
0.0
0.0
12 .6
0.0
0.0
37.6
0.0
0.0
1500000
1000000 J,
500000 .
Time-->
39.18
39.00
ENG1J21.DPES.M
Wed May iy 12:09:41 1999
HP 5989B
Page 13
-------
Abundance
i
1500000 J
1
1000000 j
J
1
500000 J
TIC: ENG1321.D
fTime-->
45:80
46.00
Abundance I on 264.00 TZfoJTvOto 264.7^)
i 800000Jlon 132.00 (131.70 to 132.70)
600000 j
ENG
ENG
o:
fTime- - >
45.80
46.00
Abundance
1500000 J
1000000
500000
TIC: ENG1321.D
0
Time--> 45.80 46JOO 46120 46.40
Abundancelon 252.00 (251.70 to 252.70): ENG
1000000 .(ion 126.00 (125.70 to 126.70): ENG
500000
|Time-->
45.80
46.00
46.20
46.40
ENG1J21.D
. M
Wed May 19 12:09":4b
#24
Benzo(b)fIuoranthene-dl2
Concen: 7.83 ng/uL
RT: 45.90 min ScanH 5495
Delta R.T. 0.03 min
Lab File: ENG1321.D
Acq: 19 May 99 10:51 am
Tgt Ion=264 Resp: 4183489
Ion Ratio Lower Upper
264 100
132
0
34.3
0.0
0.0
15.1
0.0
0.0
45.1
0.0
0.0
#25
Benzo(b)fluoranthene
Concen: 7.38 ng/uL
RT: 46.09 min Scan# 5525
Delta R.T. 0.03 min
Lab File: ENG1321.D
Acq: 19 May 99 10:51 am
Tgt Ion:252 Resp: 5653298
Ion Ratio Lower Upper
252
126
0
0
100
26.7
0.0
0.0
12.6
0.0
0.0
37.6
0.0
0.0
HP 5989B
Page 14
-------
Abundance
j
1 1500000 J
I 1000000
500000 -j
TIC: ENG1321.D
01
rrime--> 45.80 46.00 46.20 46^40
[AbundanceIon 264.00 (263.70 to 264.70): ENG i
#26
Benzo(k)fIuoranthene-dl2
Concen: 7.99 ng/uL m
RT: 46.11 min Scantf 5528
Delta R.T. 0.04 min
Lab File: ENG1321.D
Acq: 19 May 99 10:51 am
Tgt Ion: 264 Resp.- 5810884
Ion Ratio Lower Upper
264 100
35.3
0.0
132
1 0
0
0.0
15 .1
0.0
0.0
45 .1
0.0
0.0
800000,Ion 132.00 (131.70 to 132.70):
46.11
600000
400000 J
200000 _
ENG
45.80 46.00 46.20 46.40
'Abundance
]
•j
TIC: ENG1321.D
A
#27
Benzo{k)fluoranthene
Concen: 7.54 ng/uL m
RT: 46.27 min Scan# 5552
Delta R.T. 0.04 min
Lab File: ENG1321.D
Acq: 19 May 99 10:51 am
Tgt Ion:252 Resp: 6386677
Time-->
46.00
4620
46
'Abundance I on 252.00 (251.70 to 252.70)
1000000^lon 126.00 (125.70 to 126 70)
. J 46.27
500000
Ion
252
126
0
0
Ratio
100
29 .7
0.0
0.0
Lower Upper
12.6
0.0
0.0
37.6
0.0
0.0
TMT|
ENG :
Time-->
46.00
46.20
ENGTT2T7D—PES .M
46.40
Wed May iy 12:09:48 1999
HP 5989B
Page 15
-------
Abundance
800000 j
600000
400000 ;
200000 1
TIC: ENG1321.D
0
-i—i ' r
Time--> 48.20 48.40 48.60 48.80
Abundance Ion 264.00 (263.70 to 264.70)
1Ion 132.00 (131.70 to 132.70)
1 48.58
400000 J
200000 -i
ENG
ENG
0 j-
rrime--> 48.20 48.40 48.60 48.80
Abundance
800000
600000 J
400000 :
TIC: ENG1321.D
#28
Benzo(a)pyrene-d!2
Concen: 8.29 ng/uL m
RT: 48.58 min Scantf 5906
Delta R.T. 0.04 min
Lab File: ENG1321.D
Acq: 19 May 99 10:51 am
Tgt Ion: 264 Resp: 4009804
Ion Ratio
264 100
132 38.1
0 0.0
0 0.0
Lower Upper
15.1
0.0
0.0
45.1
0.0
0.0
^uuuuu _
1 ]
: n i
Time- - >
Abundance Ion
; 800000 ^ion
; -\
1 J
48150
252.00 (
126.00 (
V
49
_
00
251.70 to 252
125.70 to 126
48.79
252
126
• n
— i 1 r- u
! o
.70) : ENG i
.70) : ENG J
100
32 .4
0.0
0.0
#29
Benzo(a)pyrene(CCC)
Concen: 7.52 ng/uL
RT: 48.79 min Scantf 5938
Delta R.T. 0.05 min
Lab File: ENG1321.D
Acq: 19 May 99 10:51 am
Tgt Ion:252 Resp: 5412393
i Ion Ratio Lower Upper
12.6 37.6
0.0 0.0
0.0 0.0
600000 J
400000 :
1
i
1
200000 J
0 i
fTime-->
48:50
49.00
ENG1J21.D PES.M
Wed May 19 12:09:bl 1999
OCC3S;-3
HP 5989B
Page 16
-------
Abundance
: 1000000 .
TIC: EKG1321.D
500000
-1
I
0 J=
Time-->
61.00
61.50
62
•Abundance I on 288.00 (287.70 to 288
1 j
| 300000 j
200000 j
-]
J
100000J
00
TUT
500000 _
0
Time--> 61.00 61.50 62.00 62^50
JAbundancelon 276.05 (275.75 to 276.75)
i lion 138.00 (137.70 to 138.70)
i 400000 61.91
Time--> 61
Abundance
i 1000000 J
~i — i — ' — i — i — i — i — i — ' — i — i — i — i — i —
.00 61.50 62.00
TIC: ENG1321.D
A
ENG
300000 J
200000 .j
1
100000 4
1
1
-)
04-
iTime--> 61.00 6l!50 62.00 621,
ENGTT2TTD PES . M
Wed May 19 12:09:55 1999
#30
Indenod, 2, 3-cd)pyrene-dl2
Concen: 7.48 ng/uL m
RT: 61.55 min Scan# 8114
Delta R.T. 0.07 min
Lab File: ENG1321.D
Acq: 19 May 99 10:51 am
Tgt Ion:288 Resp: 4850965
Ion Ratio Lower Upper
288 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
#31
Indeno(1,2,3 -cd)pyrene
Concen: 7.23 ng/uL
RT: 61.91 min Scan# 8180
Delta R.T. 0.08 min
Lab File: ENG1321.D
Acq: 19 May 99 10:51 am
Tgt Ion:276.05 Resp: 5534551
Ion Ratio
276 100
138 0.0
0 0.0
0 0.0
Lower Upper
32.1
0.0
0.0
96. 1#
0.0
0.0
OCO2.3
HP 5989B
Page 17
-------
Abundance
1000000 _
TIC: ENG1321.D
500000 -
#32
Dibenz(a,h)anthracene-d!4
Concen: 7.40 ng/uL m
RT: 61.51 min Scantf 8106
Delta R.T. 0.07 min
Lab File: ENG1321.D
Acq: 19 May 99 10:51 am
Tgt Ion:292 Resp: 2816046
Ion Ratio Lower Upper
292 100
Time-- >
61.00
61.50
62 .00
Sundance Ion 292.00 (291.70 to 292.70)
200000 J
ENG
61.51
150000 J
4
100000 J
J
H
50000 J
Abundance
1000000
TIC: ENG1321.D
500000 J
Time-->
61.50
62.00
62.50
0
0
0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
n • X ^-r—
1 1
Time-->
i
61
loo
61
150
62
:oo
#33
Dibenz(a,h)anthracene
Concen: 7.07 ng/uL
RT: 61.93 min Scantf 8185
Delta R.T. 0.08 min
Lab File: ENG1321.D
Acq: 19 May 99 10:51 am
Tgt Ion:278 Resp: 4402408
Abundance I on 278.00
I 400000ion 139.00
300000 -
200000 J
100000
(277.70 to 278.70): ENG
(138.70 to 139.70): ENG
61.93
Ion Ratio
278 100
139 27.5
0 0.0
0 0.0
Lower Upper
12 .6
0.0
0.0
37.6
0.0
0.0
Time--> 61.50 62.00
TDPES.MWed May 19 12
62.50
1999
OCC-JSir
HP 5989B
Page 18
-------
Abundance
400000
: 200000^
TIC: ENG1321.D
Time-->
64.50
65.00
65.50
Abundancelon 288.00 (287.70 to 288.70): ENG
j
200000 _
100000 .
65.13
A
#34
Benzo(g,h,i)perylene-d!2
Concen: 7.59 ng/uL m
RT: 65.13 min Scan# 8847
Delta R.T. 0.07 min
Lab File: ENG1321.D
Acg: 19 May 99 10:51 am
Tgt Ion:288 Resp: 3897180
Ion Ratio Lower Upper
288 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Time--> 64!50 65:00 65.50
Abundance
400000 J
200000 ,
TIC: ENG1321.D
|Time--> 65.00 65.50 66.00
Abundancelon 276.00 (275.70 to 276.70): ENG
400000HIon 138.00 (137.70 to 138.70): ENG
65.51
#35
Benzo(g,h,i)perylene
Concen: 7.12 ng/uL
RT: 65.51 min Scan# 8939
i Delta R.T. 0.07 min
j Lab File: ENG1321.D
i Acq: 19 May 99 10:51 am
i
Tgt Ion:276 Resp: 4752539
Ion Ratio Lower Upper
276 100
138 38.9 10.1 40.1
0 0.0 0.0 0.0
0 0.0 0.0 0.0
300000
200000
i
100000 ^
0 J-
Time--> 65^00 65.50 66.00
Wed May iy 12:10:02 1999
ENG1J21.D—PEST
HP 5989B
Page 19
-------
Evaluate Continuing Calibration Report
Data File
Acq On
Sample
Misc
C:\HPCHEM\1\DATA\9919\ENG1342.D
21 May 99 12:06 pm
PES-MAH-051299-06 7ng//iL
Method
Title
Last Update
Response via
Min. RRF
Max. RRF Dev
C:\HPCHEM\1\METHODS\PES1.M
Tue May 25 10:32:38 1999
Multiple Level Calibration
Vial: 2
Operator: JEMcCartney
Inst : HP 5989B
Multiplr: 1.00
^ >' )-}
t^ i
0.000 Min. Rel. Area
30% Max. Rel. Area
1% Max. R.T. Dev O.BOmin
500%
Compound
AvgRF
CCRF
%Dev Area% Dev(min)
1
2 S
3
"4 S
5 S
6
7 s
8
9 s
10
1 s
_2
13 s
4
5 E
16
•"7 s
8
±9 S
20 s
1
2 S
23
"4 s
5
26 s
77
8 s
_9
30 s
,1
.2 s
33
34 s
,5
2 , 2 -Dif luorobiphenyl
Naphthalene-d8
Naphthalene (CCC)
2-Methlynaphthalene-dlO
Acenaphthylene-d8
Acenaphthylene
Acenapht hene - dl 0
Acenaphthene (CCC)
Fluorene-dlO
Fluorene
Phenant hrene - dl 0
Phenanthrene
Anthracene-dlO
Anthracene
Fluor an thene-dlO
Fluoranthene (CCC)
Pyrene-dlO
Pyrene
p-Terphenyl-d!4
Benzo (a) anthracene-d!2
Benzo (a) anthracene
Chrysene-dl2
Chrysene (CCC)
Benzo (b) f Iuoranthene-dl2
Benzo (b) f luoranthene
Benzo (k) f Iuoranthene-dl2
Benzo (k) f luoranthene
Benzo (a) pyrene-d!2
Benzo (a) pyrene (CCC)
Indeno (1,2, 3-cd) pyrene-d!2
Indeno (1,2, 3-cd) pyrene
Dibenz (a, h) anthracene-d!4
Dibenz (a, h) anthracene
Benzo (g, h, i) perylene-d!2
Benzo (g, h, i) perylene
1.000
1.838
1.931
0.953
1.510
1.516
1.060
1.035
0.994
1.063
1.222
1.351
1.020
1.221
1.081
1.285
1.183
1.363
0.964
0.823
0.955
0.809
0.980
0.783
0.899
0.886
0.958
0.751
0.922
0.931
1.018
0.595
0.905
0.787
0.938
1.000
1.815
1.883
0.941
1.419
1.311
0.892
0.838
0.817
0.870
1.012
1.163
0.938
1.109
0.803
0.966
0.877
1.041
0.732
0.771
0.913
0.734
0.942
0.791
0.889
0.901
0.972
0.794
0.968
1.061
1.070
0.688
0.954
0.831
1.009
0.0
1.2
2 .5
1.3
6.1
13.5
15.9
19.0
17 .8
18.2
17.2
14.0
8.1
9.2
25.7
24.8
25.8
23.6
24.1
6.3
4.4
9.2
3 .9
-1.0
1.1
-1.8
-1.5
-5.7
-5.0
-14.0
-5.1
-15.6
-5.4
-5.6
-7.6
77
77
79
78
74
73
73
72
66
69
69
69
69
69
66
69
68
71
70
79
80
78
80
82
76
81
78
84
78
83
75
86
73
81
75
0.00
0.00
0 .00
0.00
0.00
0.00
0.00
0.00
0 .00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0 .00
0.00
0.00
0.00
0.00
0.00
0.00
(#) = Out of Range
ENG1342.D PES1.M
SPCC's out = 0 CCC's out = 0
Tue May 25 10:33:27 1999 HP 5989B
OC
-------
Quantitation Report Summary
Data File
Date Analyzed:
Sample ID
Method ID
Operator
Instrument
Compounds
Naphthalene(CCC)
Acenaphthylene
Acenaphthene(CCC)
Fluorene
Phenanthrene
Anthracene
Fluoranthene(CCC)
Pyrene
Benzo(a)anthracene
Chrysene(CCC)
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Benzo(a)pyrene(CCC)
lndeno(1 ,2,3-cd)pyrene
Dibenz(a,h)anthracene
Benzo(g,h,i)perylene
Surrogate Recoveries
Compound
Naphthalene-d8
Acenaphthylene-d8
Acenaphthene-d10
Fluorene-d10
Phenanthrene-d10
Anthracene-d10
Fluoranthene-d10
Pyrene-d10
Benzo(a)anthracene-d1 2
Chrysene-d12
Benzo(b)fluoranthene-d12
Benzo(k)fluoranthene-d1 2
Benzo(a)pyrene-d12
lndeno(1 ,2,3-cd)pyrene-d1 2
Dibenz(a,h)anthracene-d14
Benzo(g,h,i)perylene-d1 2
Recovery Standard
Compound
2-Methlynaphthalene-d1 0
p-Terphenyl-d14
Compiled by:
Reviewed by:
Reviewed by:
PES.XLS
ENG1342.D
05/21/99
PES-MAH-051 299-06 7ng/pL
PES
JEMcCartney
HP 5989B
Area
1286440
895498
572811
594671
794381
757586
659951
711232
624010
228
607672
664441
661119
730912
651712
689653
Concentration (ng/uL)
Concentration (ng/uL)
6.91
6.58
5.90
5.76
5.80
6.43
5.20
5.19
6.56
6.34
7.07
7.18
7.44
7.98
7.87
7.35
Concentration (ng/uL)
7.01
5.31
/
^'/ ( x^2 ^"
_
-7 _
' ^/X->/7fy
6.823
6.054
5.830
5.731
6.024
6.409
5.263
5.349
6.696
6.714
6.928
7.253
7.347
7.345
7.316
7.373
% Recovery
98.71
93.94
84.24
82.22
82.80
91.91
74.34
74.20
93.69
90.52
100.99
102.54
106.25
113.97
112.48
104.95
% Recovery
,\.
/'•''Itti A
/••'vruis-3*-*' -^
'
OCv, j
ls
^7
-------
Quantitation Report
C:\HPCHEM\1\DATA\9919\ENG1342.D
21 May 99 12:06 pm
PES-MAH-051299-06 7ng/^L
Data File
Acq On
Sample
Misc
Quant Time: May 25 10:28 1999
Vial: 2
Operator: JEMcCartney
Inst : HP 5989B
Multiplr: 1.00
Method
Title
Last Update
Response via
C:\HPCHEM\1\METHODS\PES1.M
Tue May 25 10:29:00 1999
Multiple Level Calibration
Internal Standards
R.T. Qlon Response Cone Units Dev(Min)
1)
2 , 2 -Dif luorobiphenyl
24
.53
190
488038
5
.00
System Monitoring Compounds
2)
4)
5)
7)
9)
11)
13)
15)
17)
19)
20)
22)
24)
26)
28)
30)
32)
34)
Naphthalene-d8
2-Methlynaphthalene-dlO
Acenaphthylene-d8
Acenaphthene-dlO
Fluorene-dlO
Phenanthrene-dlO
Anthracene -dlO
Fluoranthene-dlO
Pyrene-dlO
p-Terphenyl-d!4
Benzo (a) anthracene-d!2
Chrysene-dl2
Benzo (b) f Iuoranthene-dl2
Benzo (k) fluoranthene-d!2
Benzo (a) pyrene-d!2
Indeno (1,2, 3-cd) pyrene-d!2
Dibenz (a, h) anthracene -d!4
Benzo (g, h, i) perylene-d!2
22
23
26
26
27
30
30
33
34
34
38
38
45
45
48
61
61
64
.18
.91
.23
.65
.95
.38
.52
.50
.18
.50
.77
.93
.71
.92
.36
.23
.15
.75
136
152
160
164
176
188
188
212
212
244
240
240
264
264
264
288
292
288
1240415
651799
969327
609263
558501
691174
640654
548861
599271
499938
526893
501831
540424
615911
542347
725263
469999
567537
6
7
6
5
5
5
6
5
5
5
6
6
7
7
7
7
7
7
.91
.01
.58
.90
.76
.80
.43
.20
.19
.31
.56
.34
.07
.18
.44
.98
.87
.35
Target Compounds
3)
6)
8)
10)
12)
14)
16)
18)
21)
23)
25)
27)
29)
31)
33)
35)
Naphthalene (CCC)
Acenaphthylene
Acenaphthene (CCC)
Fluorene
Phenanthrene
Anthracene
Fluoranthene (CCC)
Pyrene
Benzo (a) anthracene
Chrysene(CCC)
Benzo (b) f luoranthene
Benzo (k) f luoranthene
Benzo (a) pyrene (CCC)
Indeno (1, 2, 3-cd) pyrene
Dibenz (a, h) anthracene
Benzo (g, h, i) perylene
22
26
26
28
30
30
33
34
38
39
45
46
48
61
61
65
.23
.27
.73
.02
.44
.56
.56
.24
.88
.06
.91
.08
.57
.56
.59
.15
128
152
154
166
178
178
202
202
228
228
252
252
252
276
278
276
1286440
895498
572811
594671
794381
757586
659951
711232
624010
643552
607672
664441
661119
730912
651712
689653
6
6
5
5
6
6
5
5
6
6
6
7
7
7
7
7
.82
.05
.83
.73
.02
.41
.26
.35
.70
.71
.93
.25
.35
.35
.32
.37
ng/uL
0.00
%Recovery
ng/uL #
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL #
ng/uL #
ng/uL #
ng/uL #
ng/uL #
ng/uL #
ng/uL #
ng/uL
ng/uL
ng/uL
ng/uL m
ng/uL m
ng/uL m
Qvalue
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL#
ng/uL#
ng/uL#
ng/uL#
ng/uL
ng/uL
ng/uL
ng/uLm
ng/uLm
ng/uLm
OCC 3*
96
97
100
94
94
92
74
70
74
71
79
80
78
0
0
0
*" *< ' .1
(#) = qualifier out of range (m) = manual integration
ENG1342.D PES1.M Tue May 25 10:31:05 1999 HP 5989B
Page 1
-------
Quantitation Report
Data File : C:\HPCHEM\1\DATA\9919\ENG1342.D
Acq On : 21 May 99 12:06 pm
Sample : PES-MAH-051299-06 7ng/^tL
Misc :
Quant Time: May 25 10:28 1999
Method
Title
Last Update
Response via
C:\HPCHEM\1\METHODS\PES1.M
Tue May 25 10:29:00 1999
Multiple Level Calibration
Vial: 2
Operator -. JEMcCartney
Inst : HP 5989B
Multiplr: 1.00
Abundance
700000 J
650000 :
'.
• 600000.
i
.
550000:
sooooo:
.
•
i 450000:
.
1 400000:
:
'
1
; 350000-
:
1 300000-
250000 :
200000 :
150000:
• 100000.
50000 -
0
Time-->
2
•
— ,
20:00
s
1
4s
L
lA
6
5:
1
1 '
5
gl
5
^
0
i
i:
i:
3
^ — f
30.
I
s
s
'•
00
1
i "V
li
1
Lf
^
PIC: ENG1342.D
i
i
i
>8 j
i
i
s '
JS .
21 2353
i 22s .
23 !
2C s 31
2^ s 29
28s 32§
i 35
1 34s
I I
)
j j fj j1^ |
J V
i I — i " r 1 1 1 ' '"i i 1 r1 i T "T ""T~ ^
40.00 50:00 eo:oo
ENG1342.D PES1.M
Tue May 25 10:31:15 1999
HP 5989B
Page 2
-------
Abundance
I 600000 .,
400000
200000 ,
TIC: ENG1342.D
0
,Time-->
22.00
22.20
22i40
Abundance Ion 116.00
i Ion 68.00
400000
200000 J
[135.70 to 136.70): ENG
[67.70 to 68.70): ENG13
22.18
||' •'-!
Time--> 22
Abundance
600000 .,
'ill " i -r — r 1 1 1 r
00 22 20 22.40
TIC: ENG1342.D
A
#2
Naphthalene-d8
Concen: 6.91 ng/uL
RT: 22.18 min Scantf 1558
Delta R.T. 0.00 min
Lab File: ENG1342.D
Acq: 21 May 99 12:06 pm
Tgt Ion:136 Resp: 1240415
Ion Ratio
136 100
68 6.8
0 0.0
0 0.0
Lower Upper
10.1
0.0
0.0
30.1#
0.0
0.0
400000
200000
Naphthalene(CCC)
Concen: 6.82 ng/uL
RT: 22.23 min Scan# 1566
Delta R.T. 0.00 min
Lab File: ENG1342.D
Acq: 21 May 99 12:06 pm
Tgt Ion:128 Resp: 1286440
Ion Ratio Lower Upper
128 100
60 .0
0.0
Time--> 22.00
Abundance Ion 128.00
600000
22.20 22.40
(127.70 to 128.70) : ENG
127
0
0
11.6
0.0
0.0
0.0
0.0
0 .0
0 .0
-| I on 127.00
(126.70 to 127.70)
22.23
ENG
A
400000 J
200000
n , Jy x ^ —
Time--> 22 :00
ENG1342 . D~ PES1.M
1 r- 1 1 1
22^0
Tue way 25
-i — i — i — i — i —
22:40
10:31:18 IS
>99
HP 5989B
Page 3
-------
Abundance"
200000
j
100000 J
TIC: ENG1342.D
A
\
\
0
Time--^3.70 23:80
23.9o
24 00
, #4
| 2-Methlynaphthalene-dlO
Concen: 7.01 ng/uL
RT: 23.91 min Scan# 1908
Delta R.T. 0.00 min
Lab File: ENG1342.D
Acq: 21 May 99 12:06 pm
Tgt Ion:152 Resp: 651799
Ion Ratio Lower Upper
152 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundancelon 152.00 (151.70 to 152.70): ENG
300000
200000
23.91
A
100000
hrime--:23 .70 23.80 23:90 24100
Abundance
400000-
TIC: ENG1342.D
200000 -j
0 _=
J
-'
Tlme-->
26:00
26:20
26.40
#5
Acenaphthylene-d8
Concen: 6.58 ng/uL
RT: 26.23 min Scan# 2441
Delta R.T. 0.00 min
Lab File: ENG1342.D
Acq: 21 May 99 12:06 pm
.
400000 j
200000
26.23
0 ^
Time- -> 2 6 :0
ENG1342.D PES1.M
26.20 26.40
Tue May 2b 10:31:21
Tgt Ion: 160 Resp:
Ion Ratio Lower
160 100
0 0.0 0.0
0 0.0 0.0
0 0.0 0.0
969327
Upper
0 .0
0 .0
0.0
Abundancelon 160.00 (159.70 to 160.70): ENG'
HP 5989B
Page 4
-------
Abundance"
400000 „
! j
I 200000 '
TIC: ENG1342.D
0 ±
Time--> 26.00
26.20
26l40
Abundance Ion 152.00
]Ion 153.00
400000 J
300000 J
j
200000:
100000:
[151.70 to 152.70): ENG
1152.70 to 153.70): ENG
26.27
Acenaphthylene
Concen: 6.05 ng/uL
RT: 26.27 min Scan# 2446
Delta R.T. 0.00 min
Lab File: ENG1342.D
Acq: 21 May 99 12:06 pm
Tgt Ion:152 Resp: 895498
Ion Ratio
152 100
153 13.7
0 0.0
0 0.0
Lower Upper
7.6
0.0
0.0
22.6
0.0
0.0
0
Time- - >
26100 26 20
v_
— : 1 1 1 1 1 r
26 40
iAbundance
i 400000J
300000
200000 J
100000 .1
rrime-->26 i 50
TIC: ENG1342.D
26.60
26:70
Abundance Ion 164.150 (163.70 to 164.70): ENG
26.65
#7
Acenaphthene-dl0
Concen: 5.90 ng/uL
RT: 26.65 min Scan# 2504
Delta R.T. -0.00 min
Lab File: ENG1342.D
Acq: 21 May 99 12:06 pm
Tgt Ion:164 Resp: 609263
Ion Ratio Lower Upper
164 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
1
200000 Jj
H
1
100000 \
i
1
•i
n i
Time-->26!50
1342. D PEbl.M
/ \
/ \
2€;60 ' 26170 '
Tue May 2b 10:31:24 1999
OC
HP 5989B
Page 5
-------
Abundance
: 400000 :
300000:
200000:
100000 J
TIC: ENG1342.D
A
0 i
Time-->26.50 26!60 26.70 26.80 26:90
Abundancelon 154.00(153.70 to 154.70): ENG
lion 153.00
200000
100000
;i52.70 to 153.70): ENG
26.73
A
#8
Acenaphthene(CCC)
Concen: 5.83 ng/uL
RT: 26.73 min Scan# 2516
Delta R.T. -0 .00 min
Lab File: ENG1342.D
Acq: 21 May 99 12:06 pm
Tgt Ion:154 Resp: 572811
Ion Ratio Lower Upper
154
153
0
0
100
86.8
0 .0
0.0
43.5
0.0
0.0
130 .3
0.0
0 .0
Time-->26.50 26^60 26.70 26^80 26190
Abundance
400000 -
300000 -
200000 .
100000 _
i
o J
TIC: ENG1342.D
'
Time--> 27 :80 27.90 28lOO 28.10
Abundancelon 176.00(175.70 to 175.70): ENG
#9
Fluorene-dlO
Concen: 5.76 ng/uL
RT: 27.95 min Scan# 2700
Delta R.T. -0.00 min
| Lab File: ENG1342.D
i Acq: 21 May 99 12:06 pm
Tgt Ion:176 Resp: 558501
Ion Ratio Lower Upper
176 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
200000 J
27.95
A
i \
< \
100000 _
Time-->
27!80 27:90 28:00
ENG1J42 . D PESl.M Tue"
~May-
25
10
28
:J1:
10
27 1999
HP 5989B
Page 6
-------
Abundance
400000 -j
300000
200000:
100000 J
TIC: ENG1342.D
[Time--> 27.80 28100 28 .20
(Abundancelon 166.00 (165.70 to 166.70): ENG
jlon 165.00 (164.70 to 165.70):
28.02
ENG
200000 J
100000
0 -j
Time--> 27.80
#10
Fluorene
Concen: 5.73 ng/uL
RT: 28.02 min Scan# 2711
Delta R.T. 0.00 min
Lab File: ENG1342.D
Acq: 21 May 99 12:06 pm
Tgt Ion:166 Resp: 594671
Ion Ratio Lower Upper
166 100
165 80.9 38.2 114.4
0 0.0 0.0 0.0
0 0.0 0.0 0.0
28iOO
28120
Abundance
I 400000.
300000 J
TIC: ENG1342.D
200000 .
100000 _
0
#11
Phenanthrene-dIO
Concen: 5.80 ng/uL
RT: 30.38 min Scan# 3069
Delta R.T. -0.00 min
Lab File: ENG1342 .D
Acq: 21 May 99 12:06 pm
iTime-->
30.30
30.40
30.50
Abundancelon 188.00
' Jlon 94.00
' 300000
200000 J
100000 -•
(187.70 to 188.70): ENG
(93.70 to 94.70): ENG13
30.38
fTime-->
Tgt Ion:188 Resp:
Ion Ratio Lower
188 100
94 13.6 15.1
0 0.0 0.0
0 0.0 0.0
691174
Upper
45.18
0.0
0.0
ENG1342.DPES1.M
Tue May 25 10:31:30 1999
HP 5989B
Page 7
-------
Abundance
400000 -
-I
300000 J
200000 :
100000:
TIC: ENG1342.D
I—i
/\
Time-->3
'f^mm
0
e
i
130
Ion
Ion
178
176
I
00
00
30
40
(177
(175
1 i 1 1 ! 1 T 1
30150
.70
.70
to
to
178
176
.70) :
.70) :
ENG
ENG
#12
Phenanthrene
Concen: 6.02 ng/uL
RT: 30.44 min Scantf 3078
Delta R.T. -0.00 min
Lab File: ENG1342.D
Acq.- 21 May 99 12:06 pm
Tgt Ion:178 Resp: 794381
Ion Ratio Lower Upper
178 100
176 17.1 10.1 30.1
0 0.0 0.0 0.0
0 0.0 0.0 0.0
300000 J
200000 :
100000:
Time-->30.30
30.40
Abundance
1 400000 -
300000 J
200000 :
100000:
Time-->
TIC: ENG1342.D
#13
Anthracene -dlO
Concen: 6.43 ng/uL
RT: 30.52 min Scantf 3090
Delta R.T. -0.00 min
Lab File: ENG1342 .D
Acq: 21 May 99 12:06 pm
30.40
Tgt Ion:188 Resp:
Ion Ratio Lower
188 100
94 14.6 15.1
0 0.0 0.0
0 0.0 0.0
640654
Upper
45. lit
0.0
0.0
Abundance Ion 188.00
Jlon 94.00
300000J
200000 _
100000 _
(187.70 to 188770): ENG
(93 .70 to 94.70) : ENG13
30.52
A
-1
: j
0 "i
|Time-->
_>/XV_,/xV_
3ol40 soleo
Tue May 25 10:31:JJ
HP 5989B
Page 8
-------
Abundance
400000 H
TIC: ENG1342.D
300000:
200000:
100000:
0
Time--> 30.40
30.50
30.60
3o!vo
elon 176.00 (177.70 to 17S.70): ENG
Ion 176.00 (175.70 to 176.70): ENG
30.56
300000J
200000 J
100000:
o:
iTime--> 30.40
30.50
30160
30170
Anthracene
Concen: 6.41 ng/uL
RT: 30.56 min Scantf 3097
Delta R.T. -0.01 min
Lab File: ENG1342.D
Acq: 21 May 99 12:06 pttl
Tgt Ion:178 Resp: 757586
Ion Ratio Lower Upper
178 100
176 16.2 10.1 30.1
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance
200000
100000 .
Time--> 33.20
TIC: ENG1342.D
0
33.40
33.60
Abundance Ion 212.00 (211.70 to 212.70): ENG
Ion 106.00 (105.70 to 106.70): ENG
200000:
150000 .
100000 .
50000 .
0 .
33.50
Time--> 33.20
33.40
33.60
ENG1342.D—PES1.M
#15
Fluoranthene-dl0
Concen: 5.20 ng/uL
RT: 33.50 min Scantf 3608
Delta R.T. -0.01 min
Lab File: ENG1342.D
Acq: 21 May 99 12:06 pm
Tgt Ion:212 Resp: 548861
Ion
212
106
0
0
Ratio
100
14.7
0.0
0.0
Lower Upper
15.1
0.0
0.0
45.1#
0.0
0.0
'Tiie May 25 10:31:J6 1999
HP 5989B
Page 9
-------
Abundance
200000 -
100000 -
0
Time-->
Abundance
200000 .
100000 -
0 .
Time-->
TIC: ENG1342.D
A/1
1 V
33! 40 ' ' 33! eo ' ' 33 led
Ion 202.00 (201.70 to 202.70): ENG
Ion 101.00 (100.70 to 101.70): ENG
33.56
u.
33140 33!60 33 ISO
Abundance
200000 1
100000 -
0 "
Time-->
Abundance
200000 .
150000 .
100000 .
50000 .
0 .
lime - - >
•I I A "1 T^ T1
TIC: ENG1342.D
J ^- /
"
34 loo' ' ' 34.20' ' ' 341 40
Ion 212.00 (211.70 to 212.70): ENG
Ion 106.00 (105.70 to 106.70): ENG
34.18
A
/ \
}A^
34.00 34.20 34.40
#16
Fluoranthene(CCC)
Concen: 5.26 ng/uL
RT: 33.56 min Scanfc 3616
Delta R.T. -0.00 min
Lab File: ENG1342.D
Acg: 21 May 99 12:06 pm
Tgt Ion:202 Resp: 659951
Ion Ratio
202 100
101 13.6
0 0.0
0 0.0
Lower Upper
13.6
0.0
0.0
40.6
0.0
0.0
#17
Pyrene-dlO
Concen: 5.19 ng/uL
RT: 34.18 min Scan# 3709
Delta R.T. -0.01 min
Lab File: ENG1342.D
Acq: 21 May 99 12:06 pm
Tgt Ion:212 Resp: 599271
Ion
212
106
0
0
Ratio
100
16.5
0.0
0.0
Lower Upper
17.1
0.0
0.0
0.0
0.0
OCC3S£'3
HP 5989B
Page 10
-------
Abundance
200000 -
100000 -
Time-->
TIC: ENG1342.D
"^—I—r
34.00
34.20
34U6
Abundancelon 202.00 (201.70 to ^02.70): ENG
Ion 101.00 (100.70 to 101.70): ENG
34.24
200000 .
100000 -
0 -
Time-->
34.00
34.20
34.40
#18
Pyrene
Concen: 5.35 ng/uL
RT: 34.24 min Scant 3718
Delta R.T. 0.00 min
Lab File: ENG1342.D
Acq: 21 May 99 12:06 pm
Tgt Ion:202 Resp.- 711232
Ion Ratio Lower Upper
202 100
101 15.5 16.1 48.1#
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance
200000 .
100000 -
TIC: ENG1342.D
Time-->34.20
#19
p-Terphenyl-d!4
Concen: 5.31 ng/uL
RT: 34.50 min Scanfl 3757
Delta R.T. 0.00 min
Lab File: ENG1342.D
Acq: 21 May 99 12:06 pm
34.40
34.60
Sbundancelon 244.00 (243.70 to 244.70):
200000-ilon 122.00 (121.70 to 122.70):
34.50
150000 J
100000:
50000:
o:
ENG
ENG
Time-->34.20
34.40
34.60
ENG1342 .D PES1.M
Tgt Ion:244 Resp:
Ion Ratio Lower
100
13.6
0.0
244
122
0
0
0.0
13.6
0.0
0.0
499938
Upper
40.6#
0.0
0.0
TUB May 25 10:31:42 1999
HP 5989B
OCC33&
Page 11
-------
Abundance
150000 :
100000 -
50000:
TIC: ENG1342.D
Time-->
T 1 1 1 r
38.60
—i 1 1—i 1—I 1—r—i—i 1 1—I—
38.70 38.80 38.90
Abundancelon 240.00 (239.70 to 240.70): EMG
Ion 120.00 (119.70 to 120.70): ENG
38.77
100000.
50000 .
Time--> 38.60 38.70 38.80 38.90
#20
Benzo(a)anthracene-d!2
Concen: 6.56 ng/uL
RT: 38.77 min Scan# 4400
Delta R.T. -0.00 min
Lab File: ENG1342.D
Acq: 21 May 99 12:06 pm
Tgt Ion:240 Resp: 526893
Ion
240
120
0
0
Ratio
100
14.3
0.0
0.0
Lower Upper
15.1
0.0
0.0
45.1#
0.0
0.0
Abundance
150000 :
100000:
50000:
rime-->
TIC: ENG1342.D
38.70 38.80 38.90 39.00
Abundancelon 228.00 (227.70 to 228.70): ENG
,Ion 114.00 (113.70 to 114.70): ENG
150000 J
100000.
50000 .
Time-->
38.70 38.80 38.90 39.00
ENGTJ52TD PES1 .M
#21
Benzo(a)anthracene
Concen: 6.70 ng/uL
RT: 38.88 min Scantf 4417
Delta R.T. -0.01 min
Lab File: ENG1342.D
Acq: 21 May 99 12:06 pm
Tgt Ion:228 Resp: 624010
Ion
228
114
0
0
Ratio
100
12.1
0.0
0.0
Lower Upper
12.6
0.0
0.0
37.6#
0.0
0.0
Tue May 2,5
HP 5989B
Page 12
-------
Abundance
TIC: ENG1342.D
Time-->
1 — i — i
38.80
39.00
"ENS'
Abundancelon 240.00 (239.70 to 240.70):
Ion 120.00 (119.70 to 120.70): ENG
38.93
100000-
50000.
0 .
Time-->
38.80
39.00
#22
Chrysene-dl2
Concen: 6.34 ng/uL
RT: 38.93 min Scan# 4425
Delta R.T. -0.01 min
Lab File: ENG1342.D
Acq: 21 May 99 12:06 pm
Tgt Ion:240 Resp: 501831
Ion
240
120
0
0
Ratio
100
12.5
0.0
0.0
Lower Upper
15.1
0.0
0.0
45.1#
0.0
0.0
Abundance
150000J
100000 .
50000:
Time-->
TIC: ENG1342.D
sslso
39.00
39.20
lAbundancelon 228.00 (227.70 to 228.70): ENG
Ion 114.00 (113.70 to 114.70): ENG
39.06
150000 -
100000.
50000.
rime-->
38.80
39:00
39.20
ENG1342.DPES1.M
#23
Chrysene(CCC)
Concen: 6.71 ng/uL
RT: 39.06 min Scan# 4444
Delta R.T. -0.01 min
Lab File: ENG1342.D
Acq: 21 May 99 12:06 pm
Tgt Ion:228 Resp: 643552
Ion
228
114
0
0
Ratio
100
10.3
0.0
0.0
Lower Upper
12.6
0.0
0.0
37.6#
0.0
0.0
OCC3SC*6
Tue May 25 10:31:48 1999
HP 5989B
Page 13
-------
Abundance
200000 H
Titne-->
TIC: ENG1342.D
45.60
45:80
Abundancelon 264.00 (263.70 to 264.70)
100000Jlon 132.00 (131.70 to 132.70)
ENG
ENG
50000
Time-->
45.60
45.80
Abundance
200000 H
Time-->45.60
TIC: ENG13^2TD
45180
46.00
#24
Benzo(b)fIuoranthene-dl2
Concen: 7.07 ng/uL
RT: 45.71 min Scan# 5467
Delta R.T. 0.00 min
Lab File: ENG1342.D
Acq: 21 May 99 12:06 pm
Tgt Ion:264 Resp: 540424
Ion Ratio
264 100
132 15.7
0 0.0
0 0.0
Lower Upper
15.1
0.0
0.0
45.1
0.0
0.0
[AbundanceIon 252.00 (251.70 to 252T70): ENG
Ion 126.00 (125.70 to 126.70): ENG
100000 J
45.91
50000 .
Time--> 45 .60
45.80
46.00
ENG1J42.D—PES1.M
Tue May 2b 10:31:51
#25
Benzo(b)fluoranthene
Concen: 6.93 ng/uL
RT: 45.91 min Scan# 5497
Delta R.T. -0.01 min
Lab File: ENG1342.D
Acq: 21 May 99 12:06 pm
Tgt Ion:252 Resp: 607672
Ion
252
126
0
0
Ratio
100
14.3
0.0
0.0
Lower Upper
12.6
0.0
0.0
37.6
0.0
0.0
OCC'jSi?
HP 5989B
Page 14
-------
Abundance
I 200000^
TIC: ENG1342.D
0
Time--> 45160
45.80
46:00
46.20
Abundancelon 264.00 (263.70 to 264.70): ENG
100000Jlon 132.00 (131.70 to 132.70): ENG
45.92
50000 -
Time--> 45.60
45.80
46.00
46.20
#26
Benzo(k)fIuoranthene-dl2
Concen: 7.18 ng/uL
RT: 45.92 min Scan# 5498
Delta R.T. -0.02 min
Lab File: ENG1342.D
Acq: 21 May 99 12:06 pm
Tgt Ion:264 Resp: 615911
Ion
264
132
0
0
Ratio
100
17.3
0.0
0.0
Lower Upper
15.1
0.0
0.0
45.1
0.0
0.0
Abundance
200000H
150000 J
100000:
50000:
TIC: ENG1342.D
Time-->
Abundancelon 252.00 (251.70 to 252.70): ENG
Ion 126.00 (125.70 to 126.70): ENG
46.20
100000 .
46.08
50000 -
Time-->
45.80
46.00
46.20
ENG1342.DPES1.M
#27
Benzo(k)fluoranthene
Concen: 7.25 ng/uL
RT: 46.08 min Scantf 5523
Delta R.T. -0.01 min
Lab File: ENG1342.D
Acq: 21 May 99 12:06 pm
Tgt Ion:252 Resp: 664441
Lower Upper
Ion
252
126
0
0
Ratio
100
15.0
0.0
0.0
12.6
0.0
0.0
37.6
0.0
0.0
Tue May 25 10:31:54 iyyy
HP 5989B
OCC.3S23
Page 15
-------
TIC: ENG1342.D
50000 -
?ime--> 48.00 48.20 48.40 48.60
jundancelon 264.00 (263.70 to 264.70)
\Ion 132.00 (131.70 to 132.70)
48.36
60000 J
40000:
ENG
ENG
20000 .j
0 4
[Time--> 48.00
48.20 48.40 48.60
1*28
Benzo(a)pyrene-d!2
Concen: 7.44 ng/uL
RT: 48.36 min Scantf 5873
Delta R.T. -0.01 min
Lab File: ENG1342.D
Acq: 21 May 99 12:06 pm
Tgt Ion:264 Resp: 542347
Ion Ratio Lower Upper
264 100
132 16.9 15.1 45.1
0 0.0 0.0 0.0
0 0.0 0.0 0.0
>mm*
TIC: ENG1342.D
50000 -
Time-->
lAbundancelon 252.00 (251.70 to 252770): ENG
Ion 126.00 (125.70 to 126.70): ENG
48.50
49.00
80000 J
60000 .
40000 .
20000 .
o:
48.57
lime - - >
48.50
49.00
ENG1J42.D PES1.M
#29
Benzo(a)pyrene(CCC)
Concen.- 7.35 ng/uL
RT: 48.57 min Scan# 5906
Delta R.T. -0.01 min
Lab File: ENG1342.D
Acq: 21 May 99 12:06 pm
Tgt Ion:252 Resp: 661119
Ion Ratio
252 100
126 14.2
0 0.0
0 0.0
Lower Upper
12.6
0.0
0.0
37 .6
0 .0
0 .0
0€CjS£'3
TUB May '2b 10:31:57 1999
HP 5989B
Page 16
-------
Abundance"
100000 -
500CO -
TIC: ENG1342.D
p • i • i i r™ | '" i" — i r i 1 ~" '
Time--> 60.50 61.00 61.50
Abundancelon 288.00 (287.70 to 288.70): ENG
40000 .
20000 -
61.23
ime--> 60.50
61.00
61.50
#30
Indeno(l,2,3-cd)pyrene-dl2
Concen: 7.98 ng/uL m
RT: 61.23 min Scant 8054
Delta R.T. -0.04 min
Lab File: ENG1342.D
Acq: 21 May 99 12:06 pm
Tgt Ion:288 Resp: 725263
Ion Ratio Lower Upper
288 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance
100000 -
50000 H
rime--> 61.00
TIC: ENG1342.D
61.50
62:00
Abundancelon 276.05 (275.75 to 276.75): ENG
60000 .
40000 .
20000 J
0 .
Ion 138.00 (137.70 to 138.70): ENG
61.56
Time--> 61.00
ENG1342.D—PES1.M
61.50
62 loo
#31
Indeno(1,2,3-cd)pyrene
Concen: 7.35 ng/uL m
RT-. 61.56 min Scant 8116
Delta R.T. -0.06 min
Lab File: ENG1342.D
Acq: 21 May 99 12:06 pm
Tgt Ion:276.05 Resp: 730912
Ion Ratio
276 100
138 28.8
0 0.0
0 0.0
Lower Upper
32.1
0.0
0.0
96.1#
0.0
0.0
occ.jvea
Tue May 25 10:32:01 1999
HP 5989B
Page 17
-------
Abundance
100000 -
TIC: ENG1342.D
50000 .
Time-->60.50
T 1 I 1 1 1 1 r
61.00 61.50
Abundancelon 292.00 (291.70 to 292.vb)
40000 j
61.15
30000 j
20000 1
10000:
o:
fTime-->60.50
61.00
61.50
Time--> 6i:OQ 6l!50 62.00
Abundancelon 278.00 (277.70 to 278.70):
#32
Dibenz(a,h)anthracene-d!4
Concen: 7.87 ng/uL m
RT: 61.15 min Scantf 8039
Delta R.T. -0.05 min
Lab File: ENG1342.D
Acq: 21 May 99 12:06 pm
Tgt Ion:292 Resp: 469999
Ion Ratio Lower Upper
292 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
TIC: ENG1342.D
60000 -i
40000 .
20000-
0.
Ion 139.00 (138.70 to 139.70):
61.59
~ETJG~
ENG
Time--> 61.00
eilso
62.00
ENG1J42.D PES1.M
Tue May 25 10:J2:U4
#33
Dibenz(a,h)anthracene
Concen: 7.32 ng/uL m
RT: 61.59 min Scan# 8121
Delta R.T. -0.04 min
Lab File: ENG1342.D
Acq: 21 May 99 12:06 pm
Tgt Ion:278 Resp: 651712
Ion Ratio Lower Upper
278 100
139 21.3 12.6 37.6
0 0.0 0.0 0.0
0 0.0 0.0 0.0
OCC )?C'i
HP 5989B
Page 18
-------
Abundance
60000 .,
40000 -
20000 _,
Time--> 64 .00
TIC: ENG1342.D
64.50
Abundance Ion 288.00 (287.70 to 288.70)
ENG
40000 J
30000:
20000:
10000:
64.75
Time--> 64 .00
64.50
65.00
Abundance
60000 J
40000 -
20000 .
0
fTime--> 64^50
TIC: ENG1342.D
65.00
65.50
Abundance Ion 276.00 (275.70 to 276.70)
Ion 138.00 (137.70 to 138.70)
65.15
40000 .
20000 ^
0 .
ENG
ENG
#34
Benzo(g,h,i)perylene-dl2
Concen: 7.35 ng/uL m
RT: 64.75 min Scantf 8753
Delta R.T. -0.03 min
Lab File: ENG1342.D
Acq: 21 May 99 12:06 pm
Tgt Ion:288 Resp: 567537
Ion Ratio Lower Upper
288 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Time--> 64.50
65.00
•T 1 1 1 1 r
65.50
ENG1J42.D PES1.M
#35
Benzo(g,h,i)perylene
Concen: 7.37 ng/uL m
RT: 65.15 min Scantf 8852
Delta R.T. -0.04 min
Lab File: ENG1342.D
Acq: 21 May 99 12:06 pm
Tgt Ion:276 Resp: 689653
Ion Ratio Lower Upper
276 100
138 25.3 10.1 40.1
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Tue May 25 10:32:07 1999
HP 5989B
OCC 37C2
Page 19
-------
Evaluate Continuing Calibration Report
Data File
Acq On
Sample
Misc
C:\HPCHEM\1\DATA\9919\ENG1346.D
25 May 99 12:05 pm
PES-MAH-051299-06 Vng/jzL
Vial: 2
Operator: JEMcCartney
Inst : HP 5989B
Multiplr: 1.00
Method
Title
Last Update
Response via
Min. RRF
Max. RRF Dev
Compound
C:\HPCHEM\1\METHODS\PES1.M
Mon May 24 15:51:53 1999
Multiple Level Calibration
0.000 Min. Rel. Area
30% Max. Rel. Area
1% Max. R.T. Dev O.SOmin
500%
AvgRF CCRF
%Dev Area% Dev(min)
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
12
23
24
'.5
16
17
!8
!9
.0
1
2
3
4
5
(#
EN
s
s
s
s
s
s
s
s
s
s
s
s
s
s
s
s
s
s
)
G]
2 , 2 -Dif luorobiphenyl
Naphthalene -d8
Naphthalene (CCC)
2 -Methlynaphthalene-dlO
Acenapht hylene - d8
Acenaphthylene
Acenapht hene - dl 0
Acenaphthene (CCC)
Fluorene-dlO
Fluorene
Phenanthrene-dlO
Phenanthrene
Anthracene-dlO
Anthracene
Fluoranthene-dlO
Fluoranthene (CCC)
Pyrene -dlO
Pyrene
p-Terphenyl-d!4
Benzo (a) anthracene-d!2
Benzo (a) anthracene
Chrysene-dl2
Chrysene (CCC)
Benzo (b) f Iuoranthene-dl2
Benzo (b) f luoranthene
Benzo (k) f Iuoranthene-dl2
Benzo (k) f luoranthene
Benzo (a) pyrene-d!2
Benzo (a) pyrene (CCC)
Indeno ( 1 , 2 , 3 -cd) pyrene-d!2
Indeno (1,2,3- cd) pyrene
Dibenz (a, h) anthracene-d!4
Dibenz ( a, h) anthracene
Benzo (g,h, i)perylene-d!2
Benzo (g, h, i) perylene
= Out of Range SPCC1
L346.D PES1.M Tue May 25 13
1.
1.
1.
0.
1.
1.
1.
1.
0.
1.
1.
1.
1.
1.
1.
1.
1.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
0.
0.
0.
0.
s o
:51
000
838
931
953
510
516
060
035
994
063
222
351
020
221
081
285
183
363
964
823
955
809
980
783
899
886
958
751
922
931
018
595
905
787
938
ut
:32
1.
1.
1.
0.
1.
1.
0.
0.
0.
0.
1.
1.
0.
1.
0.
1.
1.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
= 0
1999
000
748
828
899
412
370
941
860
846
934
029
172
962
119
924
083
007
130
809
803
875
720
901
773
803
844
915
775
929
896
933
585
845
749
867
CCC's
0
4
5
5
6
9
11
16
14
12
15
13
5
8
14
15
14
17
16
2
8
11
8
1
10
4
4
-3
-0
3
8
1
6
4
7
out =
HP 59
.0
.9
.3
.7
.5
.6
.2
.9
.9
.2
.8
.3
.7
.3
.6
.7
.8
.1
.1
.5
.4
.1
.1
.3
.8
.7
.4
.1
.8
.8
.3
.8
.7
.8
.5
0
89B
92
89
92
90
89
91
92
90
83
89
84
84
85
84
92
93
93
92
93
99
93
92
92
97
83
91
88
98
91
85
79
88
78
88
78
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
ni
-w
.02
.03
.02
.02
.02
.02
.02
.02
.02
.02
.02
.02
.02
. 02
.02
.02
.03
.03
.03
.04
. 03
. 03
.03
.06
.04
.05
.04
.06
.06
. 06
.05
.05
.08
.12
.08
^ ^^ **'/**?*•»
*k-J i"C
Page 1
-------
Quantitation Report Summary
[Data File
Date Analyzed:
Sample ID
Method ID
Operator
Instrument
Compounds
Naphthalene(CCC)
Acenaphthylene
Acenaphthene(CCC)
Fluorene
Phenanthrene
Anthracene
Fluoranthene(CCC)
Pyrene
Benzo(a)anthracene
Chrysene(CCC)
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Benzo(a)pyrene(CCC)
lndeno(1 ,2,3-cd)pyrene
Dibenz(a,h)anthracene
Benzo(g,h,i)perylene
Surrogate Recoveries
Compound
Naphthalene-d8
Acenaphthylene-d8
Acenaphthene-d10
Fluorene-d10
Phenanthrene-d10
Anthracene-d10
Fluoranthene-d10
Pyrene-d10
Benzo(a)anthracene-d12
Chrysene-d12
Benzo(b)fluoranthene-d12
Benzo(k)fluoranthene-d12
Benzo(a)pyrene-d1 2
lndeno(1 ,2,3-cd)pyrene-d12
Dibenz(a,h)anthracene-d14
Benzo(g,h,i)perylene-d12
Recovery Standard
Compound
2-Methlynaphthalene-d1 0
p-Terphenyl-d14
Compiled by:
Reviewed by:
Reviewed by:
PES.XLS
ENG1346.D
05/25/99
PES-MAH-051 299-06 7ng/uL
PES
JEMcCartney
HP 5989B
Area
1504713
1127759
708015
768474
964512
921311
891383
929760
720061
228
660549
753499
764978
767623
695268
713745
Concentration (ng/uL)
.
Concentration (ng/uL)
6.66
6.54
6.21
5.95
5.90
6.60
5.98
5.96
6.82
6.22
6.91
6.67
7.22
6.73
6.88
6.67
Concentration (ng/uL)
^
6.70
5.87
/
_
^^7 j^^s^e^f ^> /^-> /J *7
6.627
6.328
5.817
6.146
6.071
6.418
5.900
5.803
6.413
6.435
6.245
6.689
7.057
6.416
6.532
6.473
% Recovery
95.10
93.47
88.77
85.07
84.24
94.28
85.42
85.18
97.49
88.92
98.73
95.34
103.13
96.21
98.22
95.23
% Recovery
95.70
83.89
(T- JY
-------
Quantitation Report
Data File : C:\HPCHEM\1\DATA\9919\ENG1346.D
Acq On : 25 May 99 12:05 pra
Sample : PES-MAH-051299-06 7ng//iL
Misc :
Quant Time: May 25 13:50 1999
Method : C:\HPCHEM\1\METHODS\PES1.M
Title :
Last Update : Tue May 25 13:51:07 1999
Response via : Multiple Level Calibration
Vial: 2
Operator: JEMcCartney
Inst : HP 5989B
Multiplr: l.OO
Internal Standards
R.T. Qlon Response Cone Units Dev(Min)
1)
2 , 2-Dif luorobiphenyl
24
.56
190
587932
5
.00
System Monitoring Compounds
2)
4)
5)
7)
9)
11)
13)
15)
17)
19)
20)
22)
24)
26)
28)
30)
32)
34)
Naphthalene -d8
2-Methlynaphthalene-dlO
Acenaphthylene-d8
Acenaphthene - dl 0
Fluorene-dlO
Phenanthrene-dlO
Anthracene -dlO
Fluor ant hene - dl 0
Pyrene -dlO
p-Terphenyl-d!4
Benzo (a) anthracene-dl2
Chrysene-dl2
Benzo (b) f Iuoranthene-dl2
Benzo (k) f Iuoranthene-dl2
Benzo(a)pyrene-dl2
Indenod, 2, 3-cd)pyrene-dl2
Dibenz (a,h) anthracene-d!4
Benzo (g, h, i) perylene-d!2
22
23
26
26
27
30
30
33
34
34
38
38
45
45
48
61
61
64
.20
.93
.25
.67
.97
.40
.54
.53
.21
.52
.81
.97
.77
.98
.43
.33
.25
.90
136
152
160
164
176
188
188
212
212
244
240
240
264
264
264
288
292
288
1438622
750816
1162048
774344
696305
847286
791797
760165
829122
665759
660588
592238
636607
694962
637720
737161
481132
616683
6
6
6
6
5
5
6
5
5
5
6
6
6
6
7
6
6
6
.66
.70
.54
.21
.95
.90
.60
.98
.96
.87
.82
.22
.91
.67
.22
.73
.88
.67
ng/uL
0
.02
%Recovery
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
Target Compounds
3)
6)
8)
10)
12)
14)
16)
18)
21)
23)
25)
27)
29)
31)
33)
35)
Naphthalene (CCC)
Acenaphthylene
Acenaphthene (CCC)
Fluorene
Phenanthrene
Anthracene
Fluoranthene (CCC)
Pyrene
Benzo (a) anthracene
Chrysene(CCC)
Benzo (b) f luoranthene
Benzo (k) f luoranthene
Benzo (a) pyrene (CCC)
Indeno ( 1 , 2 , 3 - cd ) pyrene
Dibenz (a, h) anthracene
Benzo (g,h, i)perylene
22
26
26
28
30
30
33
34
38
39
45
46
48
61
61
65
.25
.29
.75
.04
.46
.59
.58
.26
.92
.10
.96
.13
.64
.68
.70
.27
128
152
154
166
178
178
202
202
228
228
252
252
252
276
278
276
1504713
1127759
708015
768474
964512
921311
891383
929760
720061
741637
660549
753499
764978
767623
695268
713745
6
6
5
6
6
6
5
5
6
6
6
6
7
6
6
6
.63
.33
.82
.15
.07
.42
.90
.80
.41
.43
.25
.69
.06
.42
.53
.47
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
166
16
163
155
148
147
165
149
149
14
170
155
172
166
180
168
171
166
.43%
.75%
.58%
.35%
.87%
.42%
.00%
.48%
.06%
.68%
.61%
.61%
.78%
.85%
.48%
.37%
.88%
.66%
Qvalue
ng/uL#
ng/uLm
ng/uL#
OCC
}?!
100
100
97
100
100
100
98
99
100
99
99
98
97
68
84
64
£5.
(#) = qualifier out of range (m) = manual integration
ENG1346.D PES1.M Tue May 25 13:52:37 1999 HP 5989B
Page 1
-------
Quantitation Report
C:\HPCHEM\1\DATA\9919\ENG1346.D
25 May 99 12:05 pm
PES-MAH-051299-06 7ng//xL
Data File
Acq On
Sample
Misc :
Quant Time: May 25 13:50 1999
Method
Title
Last Update
Response via
C:\HPCHEM\1\METHODS\PES1.M
Tue May 25 13:51:07 1999
Multiple Level Calibration
Vial: 2
Operator: JEMcCartney
Inst : HP 5989B
Multiplr: l.OO
Abundance
800000.
750000-
700000-
650000 _
600000 -
550000 .
500000 .
450000 .
400000.
350000:
300000 :
250000 :
200000 .
150000.
100000 .
50000 .
0 '
Time - - >
2
—
20.00
s
4
L
6
5
3 *
1
/•*-— ^
sl
8
*
^
0
1
i:
i:
5
_
30!
\
s
s
^-1
00
13
A
JV
FIC: ENG1346.D
58
JS
O T "Ttli?
£i J» ^fjja
22s
'f8 2J7
2' S22g9s
1 J 34S
I 1
, I 11 'I Jl
4o!o6 ' 5o!o6 ' ' 60.00
OCC37C5
ENG1346.D PES1.M
Tue May 25 13:52:47 1999
HP 5989B
Page 2
-------
Abundance
i
600000 J
400000 .
200000 .
TIC: EtfGl346.D
Time-->
Sundance Ion 136.00 (I35.70to 136.70): ENG
22.00
22.20
22.40
600000 .
400000.
200000 .
Ion
68.00 (67.70 to 68.70): ENG13
22.20
[Time - - >
22.00
22:20
22.40
Abundance
600000 J
400000 J
200000:
Time--> 22.00
TIC: ENG1346.D
22.20
22.40
Abundance Ion 128.00 (127.70 to 128.70): EMG
Ion 127.00 (126.70 to 127.70): ENG
600000J 22.25
400000 J
200000:
#2
Naphthalene-d8
Concen: 6.66 ng/uL
RT: 22.20 min Scan# 1562
Delta R.T. 0.03 min
Lab File: ENG1346.D
Acq: 25 May 99 12:05 pm
Tgt Ion:136 Resp: 1438622
Ion Ratio Lower Upper
100
136
68
0
0
6.4
0.0
0.0
3.9
0.0
0.0
11.5
0.0
0.0
o:
Time--> 22.00
22.20
22140
ENG1J46.D—PKS1.M
#3
Naphthalene(CCC)
Concen: 6.63 ng/uL
RT: 22.25 min Scantf 1569
Delta R.T. 0.02 min
Lab File: ENG1346.D
Acq: 25 May 99 12:05 pm
Tgt Ion:128 Resp: 1504713
Ion
128
127
0
0
Ratio
100
12.0
0.0
0.0
Lower Upper
0.0
0.0
0.0
62 .0
0. 0
0.0
Tue May 25 13:52:51 1999
HP 5989B
Page 3
-------
ENG
Abundance
200000 '.
100000 -
0 .
Time - - >
Abundance
300000 -
200000 :
100000 :
o :
Time-->
TIC: ENG1346TD" "
J\
23.70 23 80 23 90 24 00 24 1 10
Ion 152.00 (151.70 to 152.70): ENG
23.93
11
jv
— i — | — i — i — i — i — I — i — I — i — i — ] — r— i — i — i — i — i — i — : — i — | — i — i — i — i —
23 70 23 80 23.90 24 00 24 10
Abundance
600000 .,
400000 .
200000 .
0
Time-->
Abundance
400000.
200000 .
0.
Time-->
TIC: ENG1346.D
n
J \
26lo6 ' ' 26120 ' 26U6
Ion 160.00 (159.70 to 160.70): ENG
26.25
A
J\
26100 ' ' 26120 ' ' 26140
1.J46. D PESl.M TU6 May 25 13:b2:5b 1999
#4
2-Methlynaphthalene-dlO
Concen: 6.70 ng/uL
RT: 23.93 min Scant 1916
Delta R.T. 0.02 min
Lab File: ENG1346.D
Acq: 25 May 99 12:05 pm
Tgt Ion:152 Resp:
Ion Ratio Lower
100
152
0
0
0
0.0
0.0
0.0
0.0
0.0
0.0
750816
Upper
0.0
0.0
0.0
#5
Acenaphthylene-d8
Concen: 6.54 ng/uL
RT: 26.25 min Scantf 2444
Delta R.T. 0.02 min
Lab File: ENG1346.D
Acq: 25 May 99 12:05 pm
Tgt Ion:160 Resp: 1162048
Ion Ratio Lower Upper
160 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
OOC37es
HP 5989B
Page 4
-------
TIC: ENG1346.D
Time--> 26.00
Abundance Ion 152.00 (151.70 to 152.70)
400000 -
200000^
T 1 1 1 r
26.20
-i 1 1 r
26.40
400000 .
200000 -
Ion 153.00 (152.70 to 153.70)
26.29
ENG
[Time--> 26.00
26.20
26.40
Abundance
400000 -
200000 -
TIC: ENG13467D
Time--> 26.50 26.60 26.70
Abundancelon 164.00 (163.70 to 164.70): ENG
26.80
Acenaphthylene
Concen: 6.33 ng/uL
RT: 26.29 min Scan# 2449
Delta R.T. 0.02 min
Lab File: ENG1346.D
Acq: 25 May 99 12:05 pm
Tgt Ion:152 Resp: 1127759
Ion Ratio Lower Upper
152 100
153 14.0 7.1 21.1
0 0.0 0.0 0.0
0 0.0 0.0 0.0
300000 J
200000:
100000 J
26.67
Time--> 26.50
26.60
26.70
26.80
ENG1346.DPES1. M
#7
Acenaphthene-dlO
Concen: 6.21 ng/uL
RT: 26.67 min Scan# 2506
Delta R.T. 0.02 min
Lab File: ENG1346.D
Acq: 25 May 99 12:05 pm
Tgt Ion:164 Resp: 774344
Ion Ratio
164 100
0 0.0
0 0.0
0 0.0
Lower Upper
0.0
0.0
0.0
0.0
0.0
0.0
Tue May 25 13:52:58
HP 5989B
Page 5
-------
Abundance
400000 -
200000 -
TIC: ENG1346.D
Time-->
26160
26.80
27100
Abundance Ion 154.00 (153.'Jo to 154.70)
Ion 153.00 (152.70 to 153.70): ENG
300000J 26'75
200000:
100000 J
(Ti
ime- ->
26.60
26.80
27100
#8
Acenaphthene(CCC)
Concen: 5.82 ng/uL
RT: 26.75 min Scan# 2518
Delta R.T. 0.02 min
Lab File: ENG1346.D
Acq: 25 May 99 12:05 pm
Tgt Ion:154 Resp: 708015
Ion Ratio Lower Upper
154 100
153 89.0 43.3 129.7
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance
400000 .
200000 -
TIC: ENG1346.D
Time-->
Abundancelon 176.00 (175.70 to 176.70): ENG
27.80
28.00
28.20
300000 '.
200000-
100000:
o:
27.97
27.80
28.00
28.20
#9
Fluorene-dlO
Concen: 5.95 ng/uL
RT: 27.97 min Scan# 2702
Delta R.T. 0.02 min
Lab File: ENG1346.D
Acq: 25 May 99 12:05 pm
Tgt Ion:176 Resp: 696305
Ion
176
0
0
0
Ratio
100
0.0
0.0
0.0
Lower Upper
0.0
0.0
0.0
0.0
0.0
0.0
ENG1346.DPES1.M
Tue May 25 13:53:01 1999
HP 5989B
OCOJ710
Page €
-------
Abundance
400000 .
200000 -
TIC: ENG134&.D
Time-->
27.80
2s!oo
Abundancelon 166.00 (165.70 to 166.70): ENG
Ion 165.00 (164.70 to 165.70): ENG
28.04
300000 J
J
200000:
100000:
o 4
Time-->
27.80
28.00
28.20
#10
Fluorene
Concen: 6.15 ng/uL
RT: 28.04 min Scan# 2713
Delta R.T. 0.02 min
Lab File: ENG1346.D
Acq: 25 May 99 12:05 pm
Tgt Ion: 166 Resp: 768474
Ion Ratio Lower Upper
166 100
165 79.7
0 0.0
0 0.0
40.0
0.0
0.0
119.9
0.0
0.0
Abundance
400000 :
300000:
200000:
100000:
TIC: ENG1346.D
Time-->
Abundancelon 188.00 (187.70 to 188.70):
30.30
30.40
30.50
400000 J
300000 :
200000:
100000:
o:
Ion
94.00 (93.70 to 94.70): ENG13
30.40
Titne-->
30:30
30.40
30.50
ENG1346.D PES1.M
Tue May 25 13:bJ:04
Phenanthrene-dlO
Concen: 5.90 ng/uL
RT: 30.40 min Scant 3071
Delta R.T. 0.02 min
Lab File: ENG1346.D
Acq: 25 May 99 12:05 pm
Tgt Ion:188 Resp: 847286
Ion Ratio Lower Upper
188 100
94 11.3 5.8 17.2
0 0.0 0.0 0.0
0 0.0 0.0 0.0
OCC 3711
HP 5989B
Page 7
-------
Abundance
I :
400000:
"TIC: ENG1346.D
Time-->
0
30.40
30.50
Abundancelon 178.00 (177.70 to 178.70)
Ion 176.00 (175.70 to 176.70)
ENG
400000:
300000:
200000 J
100000 .
[Time-->
30.46
30.40
30.50
#12
Phenanthrene
Concen: 6.07 ng/uL
RT: 30.46 min Scantf 3080
Delta R.T. 0.02 min
Lab File: ENG1346.D
Acq: 25 May 99 12:05 pm
Tgt Ion:178 Resp: 964512
Ion Ratio Lower Upper
178 100
176 16.9 8.5 25.4
0 0.0 0.0 0.0
0 0.0 0.0 0.0
TIC: ENG1346.D
frime-->
30.40
30.60
Abundancelon 188.uo (187.70 to 188.7U): ENG
J 400000-|ion 94.00 (93.70 to 94.70): ENG13
300000 J
200000:
100000:
rime-->
30.54
30.40
30.60
ENG1346.DPES1.M
#13
Anthracene-dl0
Concen: 6.60 ng/uL
RT: 30.54 min Scantf 3092
Delta R.T. 0.02 min
Lab File: ENG1346.D
Acq: 25 May 99 12:05 pm
Tgt Ion:188 Resp: 791797
Ion
188
94
0
0
Ratio
100
12.8
0.0
0.0
Lower Upper
6.6
0.0
0.0
19.6
0.0
0.0
TU6TMay 2513 : 53: 08 1999
HP 5989B
Page 8
-------
Abundance
400000 :
300000:
200000:
100000:
TIC: ENG1346.D
Time--;30.40
30.50
30.60
30.70
Abundancelon 178.00 (177.70 to 178.70): ENG
lion 176.00 (175.70 to 176.70): ENG
400000 :
300000:
200000 J
100000 4
Time- -£0.40
30.59
30.50
30.60
30.70
#14
Anthracene
Concen: 6.42 ng/uL
RT: 30.59 min Scan# 3100
Delta R.T. 0.02 min
Lab File: ENG1346.D
Acq: 25 May 99 12:05 pm
Tgt Ion:178 Resp: 921311
Ion Ratio
178 100
176 16.2
0 0.0
0 0.0
Lower Upper
8.2 24.4
0.0 0.0
0.0 0.0
Abundance
i
300000:
200000 '.
100000:
TIC: ENG1346.D
Time-->33.20
Abundance Ion 212.00 (211.70 to 212.70)
33.40
33.60
33.80
ENG
300000 J
200000 .
100000 .
0 .
Ion 106.00 (105.70 to 106.70): ENG
33.53
Time-->33.20
33.40
33.60
i—i—r
33180
ENG1346.D PES1.M
Tue May 25 13:53:11
#15
Fluoranthene-dlO
Concen: 5.98 ng/uL
RT: 33.53 min Scantf 3610
Delta R.T. 0.02 min
Lab File: ENG1346.D
Acq: 25 May 99 12:05 pm
Tgt Ion:212 Resp:
Ion Ratio Lower
100
212
106
0
0
14.3
0.0
0.0
8.0
0.0
0.0
760165
Upper
23 .8
0 .0
0.0
OCC 371;
HP 5989B
Page 9
-------
•undance
300000:
200000:
100000:
TIC: ENG1346.D
Time--> 33 .40
Abundance Ion 202.00
•Ion 101.00
300000 J
200000 .
100000J
33.60
[201.70
T
to
33.80
202.70) : ENG
(100.70 to 101.70): ENG
33 .58
Time-->
33 .40
33.60
33 .80
Abundance
300000:
200000:
^
100000
Time-->
TIC: ENG 13 4 6JD
0
34100
34.20
34.40
Abundance Ion 212.00 (211.70 to 212.70)
#16
Fluoranthene(CCC)
Concen: 5.90 ng/uL
RT: 33.58 min Scan# 3618
Delta R.T. 0.02 min
Lab File: ENG1346.D
Acq: 25 May 99 12:05 pm
Tgt Ion:202 Resp: 891383
Ion Ratio Lower Upper
202 100
101 12.9 6.9 20.6
0 0.0 0.0 0.0
0 0.0 0.0 0.0
300000 J
200000 -
100000 -
0 .
Ion 106.00 (105,70 to 106.70): ENG
34.21
Time-->
34.00
34.20
34.40
ENG1346.D—FEST7I
Pyrene-dlO
Concen: 5.96 ng/uL
RT: 34.21 min Scan# 3712
Delta R.T. 0.03 min
Lab File: ENG1346.D
Acq: 25 May 99 12:05 pm
Tgt Ion:212 Resp: 829122
Lower Upper
Ion
212
106
0
0
Ratio
100
15.8
0.0
0.0
8.€
0.0
0.0
25.6
0.0
0.0
OCC 3714
Tue May 25 13:53:14 1999
HP 5989B
Page 10
-------
Abundance
300000:
TIC: ENG1346.D
I
200000:
100000:
Time--> 34.00
34.20
-i 1 1 r
34!40
Abundance Ion 202.00 (201.70 to 202.70): ENG
Ion 101.00 (100.70 to 101.70): ENG
300000J 34'26
200000 J
100000 J
Time--> 34.00
34.20
34.40
#18
Pyrene
Concen: 5.80 ng/uL
RT: 34.26 min Scantf 3720
Delta R.T. 0.03 min
Lab File: ENG1346.D
Acq: 25 May 99 12:05 pm
Tgt Ion:202 Resp:
Ion Ratio Lower
202 100
101 15.1 7.8
0 0.0 0.0
0 0.0 0.0
929760
Upper
23.3
0.0
0.0
Abundance
300000 J
200000:
100000:
TIC: ENG1346.D
Time-->
34.40
34.60
Abundance Ion 2^T. 00 1243.70 to 244.70)
Ion 122.00 (121.70 to 122.70)
34.52
200000 .
100000 -
0 .
ENG
ENG
T 1 1 1 1 1 1 1 1 1 1 1 1 1 T
Time--> 34.40 34i60
ENG13 4 6.D PES1.M
p-Terphenyl-d!4
Concen: 5.87 ng/uL
RT: 34.52 min Scant 3759
Delta R.T. 0.03 min
Lab File: ENG1346.D
Acq: 25 May 99 12:05 pm
Tgt Ion:244 Resp: 665759
Ion Ratio
244 100
122 12.4
0 0.0
0 0.0
Lower Upper
6.7
0.0
0.0
19 .9
0 .0
0 .0
rue way 25 13:53:18
HP 5989B
OCC 3715
Page 11
-------
(Abundance
200000:
IBOOOO :
100000 J
soooo:
TIC: ENG1346.D
0
Time--> 38.60 38.70 38.80 38.90 39.00
Abundance Ion 240.00 (239.70 to 240.70): ENG
lion 120.00 (119.70 to 120.70): ENG
150000J 38.81
100000
50000 J
Time--> 38.60 38:70 38180 38.90 39.00
#20
Benzo(a)anthracene-d!2
Concen: 6.82 ng/uL
RT: 38.81 min Scantf 4404
Delta R.T. 0.04 min
Lab File: ENG1346.D
Acq: 25 May 99 12:05 ptn
Tgt Ion:240 Resp: 660588
Ion Ratio Lower Upper
240 100
120 13.9 7.3 21.8
0 0.0 0.0 0.0
0 0.0 0.0 0.0
(Abundance
TIC: ENG1346.D
Time--> 38.70 38.80 38.90 39.00 39.10
[Abundance Ion 228.00 (227 .70 to 228.70):
Ion 114.00 (113.70 to 114.70):
38.92
150000 4
100000-
50000 .
[rime--> 38.70 38.80 38.90 39.00 39.10
ENG
ENG
ENG1J46.D—PHSJ1.M
Tue May 2b
#21
Benzo(a)anthracene
Concen: 6.41 ng/uL
RT: 38.92 min Scan# 4421
Delta R.T. 0.03 min
Lab File: ENG1346.D
Acq: 25 May 99 12:05 pm
Tgt Ion:228 Resp: 720061
Ion Ratio
228 100
114 12.2
0 0.0
0 0.0
Lower Upper
6.2 18.5
0.0 0.0
0.0 0.0
1999
OCO7I5
HP 5989B Page 12
-------
'Abundance
200000:
150000 -
100000:
soooo:
(
Time-->
TIC: ENG1346.D
38.80
39.00
39!20
Abundance Ion 240.00
Ion 120.00
150000 J
100000 -
50000 -
Time-->
(239.70 to 240.70)
(119.70 to 120.70)
38.97
ENG
ENG
38.80
39.00
39:20
#22
Chrysene-dl2
Concen: 6.22 ng/uL
RT: 38.97 min Scan# 4429
Delta R.T. 0.03 min
Lab File: ENG1346.D
Acq: 25 May 99 12:05 pm
Tgt lon:240 Resp: 592238
Ion Ratio
240 100
120 12.3
0 0.0
0 0.0
Lower Upper
6.4 19.0
0.0 0.0
0.0 0.0
lAbundance
•i
200000 :
isoooo:
100000:
50000:
TIC: ENG1346.D
Time--> 38.80
0
39:00
39:20
Abundancelon 228.00 {227.70 to 228.70): ENG
lion 114.00 (113.70 to 114.70): ENG
150000:
100000:
soooo:
Time-->
ENGU4b.D
38.80
PKS1.M
39.00 39:20
Tue May 25 13:
#23
Chrysene(CCC)
Concen: 6.43 ng/uL
RT: 39.10 min Scan# 4448
Delta R.T. 0.03 min
Lab File: ENG1346.D
Acq: 25 May 99 12:05 pm
Tgt Ion:228 Resp: 741637
Ion Ratio
228 100
114 10.3
0 0.0
0 0.0
Lower Upper
5.5
0.0
0.0
16.3
0 .0
0 .0
OCC37I7
HP 5989B
Page 13
-------
Abundance
! 200000:
150000:
100000:
soooo:
(
Time- ->
TIC: EMG1346.D
45.60 45.70 45.80 45.90
Abundance Ion 264.00 (263.VO to 264.70)
Ion 132.00 (131.70 to 132.70)
100000 .I
ERG"
ENG
50000
IT
rrime-->
45.60
-i—i—I—i—i—i—i—r
45.70 45.80
45.90
#24
Benzo(b)fluoranthene-d!2
Concen: 6.91 ng/uL
RT: 45.77 min Scan# 5473
Delta R.T. 0.0€ min
Lab File: ENG1346.D
Acq: 25 May 99 12:05 pm
Tgt Ion:264 Resp: 636607
Ion Ratio Lower Upper
264 100
132 15.4 8.0 23.9
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Dundance
200000 :
150000 :
100000:
50000
TIC: ENG1346.D
Time-->45l70 45.80 45.90 46.00 46.10
o 4
Abundance Ion 252.00 (251.70 to 252.70)
Ion 126.00 (125.70 to 126.70)
100000 .
50000 .
ENG
ENG
Time-->45.70 45.80 45.90 46.00 46.10
ENG1346.DPES1.M
#25
Benzo(b)fluoranthene
Concen: 6.25 ng/uL
RT: 45.96 min Scan# 5503
Delta R.T. 0.04 min
Lab File: ENG1346.D
Acq: 25 May 99 12:05 pm
Tgt Ion:252 Resp: 660549
Ion
252
126
0
0
Ratio
100
15.0
0.0
0.0
Lower Upper
7.3
0.0
0.0
21.8
0.0
0.0
000)713
Tue
13:53:28 1999
HP S989B
Page 14
-------
Abundance
200000 :
150000:
100000:
50000:
c
Time-->
TIC: ENG1346.D
45.80
46.00
46.20
Abundancelon 254.00 (263.70 to 264.70): ENG
Ion 132.00 (131.70 to 132.70): ENG
100000 .
45.98
50000 -
IT
ime-->
45.80
46.00
46.20
Benzo(k)fIuoranthene-dl2
Concen: 6.67 ng/uL
RT: 45.98 min Scan# 5506
Delta R.T. 0.05 min
Lab File: ENG1346.D
Acq: 25 May 99 12:05 pm
Tgt Ion:264 Resp: 694962
Ion Ratio Lower Upper
264 100
132 17.3 8.5 25.3
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance
200000 :
150000:
100000:
soooo:
Time--> 45 .80
TIC: ENG1346.D
46.00
46.20
46.40
Abundancelon 252.00 (251.70 to 252.70):
Ion 126.00 (125.70 to 126.70):
46.13
100000 J
50000.
ENG
ENG
Time--> 45.80
~i 1 1 1 r
46.00
i 1 1 1 1 r
46!20 46.40
ENG1346 .D PES1 .M
#27
Benzo(k)fluoranthene
Concen: 6.69 ng/uL
RT: 46.13 min Scan# 5529
Delta R.T. 0.04 min
Lab File: ENG1346.D
Acq: 25 May 99 12:05 pm
Tgt Ion:252 Resp: 753499
Ion Ratio Lower Upper
252 100
126 14.6 7.8 23.2
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Tue May 25 13:53:31
HP 5989B
OCCJ7I9
Page 15
-------
[Abundance
100000 _
TIC: ENG1346.D
50000 .
Time-->
48.20
48.40
-i 1 1 r—
48.60
Abundancelon 264.00 (263.70 to 264. 7U)
80000 JIon iSS.OO (131.70 to 132.70)
ENG
48.43
60000 4
40000 J
i
20000 -j
-i
1
Q J , ,
Time-->
48
!20 '
48
140
48
!eo
i i i i
[Abundance
100000 .
TIC: ENG1346.D
50000 J
Time-->48.00
48 .50
49.00
#28
Benzo(a)pyrene-d!2
Concen: 7.22 ng/uL
RT: 48.43 min Scan# 5881
Delta R.T. 0.06 min
Lab File: ENG1346.D
Acq: 25 May 99 12:05 pm
Tgt Ion:264 Resp: 637720
Ion Ratio Lower Upper
264 100
132 16.5 8.7 25.9
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance Ion 252.00 (251.70 to 252.70)
Ion 126.00 (125.70 to 126.70)
48.64
50000 -
0 -
ENG
ENG
Time-->4 8.0 0
48.50
49.00
ENG1J46.D—PES1.M
TUB May 25 13:53:3S 1999
#29
Benzo(a)pyrene(CCC)
Concen: 7.06 ng/uL
RT: 48.64 min Scan# 5914
Delta R.T. 0.06 min
Lab File: ENG1346.D
Acq: 25 May 99 12:05 pm
Tgt Ion:252 Resp: 764978
Ion Ratio Lower Upper
252 100
126 13.8 7.6 22.6
0 0.0 0.0 0.0
0 0.0 0.0 0.0
HP 5989B
Page 1€
-------
[Abundance
100000 .
50000 .
TIC: ENG1346.D
Time - - >
61.00
61.50
Abundance Ion 288 . 00 (287 .70 to 288.70): ENG
40000 .
20000 .
61.33
fTime-->
eilooeilsd
#30
Indenod, 2, 3-cd) pyrene-d!2
Concen: 6.73 ng/uL
RT: 61.33 min Scan# 8071
Delta R.T. 0.06 min
Lab File: ENG1346.D
Acq: 25 May 99 12:05 pm
Tgt Ion:288 Resp: 737161
Ion Ratio
288 100
0 0.0
0 0.0
0 0.0
Lower Upper
0.0
0.0
0.0
0.0
0.0
0.0
(Abundance
100000 -
50000 J
TIC: ENG1346JD
Time-->61.00
61.50
62.00
AbundanceTon 276 .05 (275 .75 to 276.75)
60000-jlon 138.00 (137.70 to 138.70)
ENG
ENG
61.68
40000 .
20000 .
lime-->61.00
61.50
62.00
ENG1J46.D—PES1.M
Tue May '2b 13:53:39
#31
Indeno(1,2,3 -cd)pyrene
Concen: 6.42 ng/uL
RT: 61.68 min Scan# 8135
Delta R.T. 0.05 min
Lab File: ENG1346.D
Acq: 25 May 99 12:05 pm
Tgt Ion:276.05 Resp: 767623
Ion Ratio Lower Upper
276 100
138 12.8 15.1 45.1#
0 0.0 0.0 0.0
0 0.0 0.0 0.0
OCC37;ii
HP 5989B Page 17
-------
Time-->
61.00
61.50
Abundance ion 292.00 (291.70 to 292770) : ENG
40000 -i
61.25
30000 4
20000
10000 .,
iTime--> 61.00 61.50
#32
Dibenz(a,h)anthracene-d!4
Concen: 6.-88 ng/uL
RT: 61.25 min Scantf 8056
Delta R.T. 0.05 min
Lab File: ENG1346.D
Acq: 25 May 99 12:05 pm
Tgt Ion:292 Resp: 481132
Ion Ratio Lower Upper
292 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
lAbundance
100000 -
50000 -
TIC: ENG1346.D
Time-->
6l!50
62.00
ACundanceion 278.00 (277.70 to 278.70): ENG
Ion 139.00 (138.70 to 139.70): ENG
61.70
40000 .
20000-
Time - - >
eilso"
T 1 1 r
62lOO
ENGU46.D—PES1.M
Tue May 2b 1J:53:42 1999
#33
Dibenz(a,h)anthracene
Concen: 6.53 ng/uL m
RT: 61.70 min Scan# 8140
Delta R.T. 0.08 min
Lab File: ENG1346.D
Acq: 25 May 99 12:05 pm
Tgt Ion:278 Resp: 695268
Ion
278
139
0
0
Ratio
100
20.7
0.0
0.0
Lower Upper
10.6
0.0
0.0
31.6
0.0
0.0
-"
HP 5989B
Page 18
-------
Abundance
60000 -l
40000 .
20000 -I
TIC: ENG1346.D
Time-->
-i 1 1 r
64.50
65.00
65.50
Abundancelon 288.00 (287.70 to 288.70): ENG
40000 :
30000 .
20000
64.90
-I
10000
o:
Time-->
64.50
65.00
65.50
(Abundance
60000 J
40000 -
20000 -
Time-->
TIC : ENG134 6 . D
65.00
65.50
#34
Benzo(g,h,i)perylene-d!2
Concen: 6.67 ng/uL
RT: 64.90 min Scan# 8786
Delta R.T. 0.12 min
Lab File: ENG1346.D
Acq: 25 May 99 12:05 pm
Tgt Ion:288 Resp: 616683
Ion Ratio Lower Upper
288 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundancelon 276.00 (275.70 to 276.70)
Ion 138.00 (137.70 to 138.70)
65.27
40000 .
20000 .
ENG
ENG
Time-->
65.00
65.50
ENG1J46.D—PES1.M
Tue May 2b 13:b3:4fe
#35
Benzo(g,h,i)perylene
Concen: 6.47 ng/uL
RT: 65.27 min Scantt 8879
Delta R.T. 0.08 min
Lab File: ENG1346.D
Acq: 25 May 99 12:05 pm
Tgt Ion:276 Resp: 713745
Ion
276
138
0
0
Ratio
100
8.2
0.0
0.0
Lower Upper
10.7
0.0
0.0
42. 6
0.0
0.0
OOC37£3
HP 5989B
Page 19
-------
SUMMARY"! XLS
Quantitation Report Summary
Data File
Dale Analyzed:
Sample ID
Method ID
Operator
Instrument
Compounds
Naphthalene(CCC)
Acenaphthylene
Acenaphthene(CCC)
Fluorene
Phenanthrene
Anthracene
Fluoranthene(CCC)
Pyrene
Benzo(a)anthracene
Chrysene(CCC)
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Benzo(a)pyrene(CCC)
lndeno(1,2,3-cd)pyrene
Dibenz(a,h)anthracene
Benzo(g,h,i)perylene
ENG1316D
05/18/99
PES XAD/FILTER LAB BLANK
PES
JEMcCartney
HP 5989B
Area
2136822
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
* PQL - practical quantrtation limit
Surrogate Recoveries
Compound
Naphthalene-dS
Acenaphthylene-d8
Acenaphthene-d10
Fluorene-d10
Phenanthrene-d10
Anthracene-d10
Fluoranthene-d10
Pyrene-d10
Benzo(a)anthracene-d12
Chrysene-d12
Benzo(b)fluoranthene-d12
Benzo(k)fluoranthene-d12
Benzo(a)pyrene-d12
Indeno(1,2,3-cd)pyrene-d12
Dibenz(a,h)anthracene-d14
Benzo(g,h,i)peryiene-d12
Recovery Standard
Compound
2-Methiynaphthalene-d10
p-Terphenyl-d14
Compiled by
Reviewed by
Reviewed by.
Cone.
(ng/pL)
3.241
0.000
0.000
0.000
0.000
0.000
0000
0000
0.000
0.000
0.000
0.000
0000
0000
0000
0000
Cone. (ng/uL)
3.43
1 79
2.55
3.21
2.91
0.04
2.92
1.56
0.41
271
2.94
2 92
0.00
1.28
1 34
0.00
Concentration (ng/uL)
,..,, ~~~-^'~
0.00
0.00
,/
^^ .
PQL*
(ng/pL)
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
S"f Jfrttst/i _s / / // 77
«- ^i£V>-x<
-------
Quantitation Report
C:\HPCHEM\1\DATA\9919\ENG1316.D
18 May 99 2:35 pm
PES XAD/FILTER LAB BLANK
Data File
Acq On
Sample
Misc :
Quant Time: May 26 13:04 1999
Vial: 4
Operator: JEMcCartney
Inst : HP 5989B
Multiplr: 1.00
Method
Title
Last Update
Response via
C:\HPCHEM\1\METHODS\PES.M
Mon May 24 16:23:27 1999
Multiple Level Calibration
Internal Standards
R.T. Qlon Response Cone Units Dev(Min)
1
)
2 , 2-Dif luorobiphenyl
24
.60
190
1859797
System Monitoring Compounds
2
4
5
7
9
11
13
15
17
19
20
22
24
26
28
30
32
34
)
)
)
)
)
)
)
)
)
)
)
)
)
)
)
)
)
)
Naphthalene-d8
2-Methlynaphthalene-dlQ
Acenaphthylene-d8
Acenaphthene-dlO
Fluorene-dlO
Phenanthrene-dlO
Anthracene-dlO
Fluoranthene-dlO
Pyrene-dlO
p-Terphenyl-d!4
Benzo (a) anthracene-d!2
Chrysene-dl2
Benzo (b) f Iuoranthene-dl2
Benzo (k) f Iuoranthene-dl2
Benzo (a) pyrene-d!2
Indeno (1,2, 3-cd)pyrene-dl2
Dibenz (a, h) anthracene-d!4
Benzo (g, h, i) perylene-d!2
22
0
26
26
28
30
30
33
34
0
38
39
45
46
0
61
61
0
.24
.00
.29
.72
.01
.44
.58
.58
.26
.00
.88
.04
.89
.09
.00
.50
.46
.00
136
152
160
164
176
188
188
212
212
244
240
240
264
264
264
288
292
288
1944122
0
1068558
1010097
1378849
1942626
25378
1924080
1131404
0
188418
1528155
1219679
1650721
0
644776
396076
0
Target Compounds
3
6
8
10
12
14
16
18
21
23
25
27
29
31
33
35
)
)
)
)
)
)
)
)
)
)
)
)
)
)
)
)
Naphthalene (CCC)
Acenaphthylene
Acenaphthene (CCC)
Fluorene
Phenanthrene
Anthracene
Fluoranthene (CCC)
Pyrene
Benzo (a) anthracene
Chrysene (CCC)
Benzo (b) f luoranthene
Benzo (k) f luoranthene
Benzo (a) pyrene (CCC)
Indeno ( 1 , 2 , 3 - cd ) pyrene
Dibenz (a , h) anthracene
Benzo (g,h, i)perylene
22
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.30
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
128
152
154
166
178
178
202
202
228
228
252
252
252
276
278
276
2136822
5.00 ng/uL
0
.01
% Re co very
3.43 ng/uL
0.00 ng/uL
1.79 ng/uL
2.55 ng/uL
3 .21 ng/uL
2 .91 ng/uL
0.04 ng /;:"_.
2.92 ng/uL
1.56 ng/uL
0 .00 ng/uL
0.41 ng/uL
2 .71 ng/uL
2.94 ng/uL
2 .92 ng/uL
0.00 ng/uL
1.28 ng/uL
1.34 ng/uL
0.00 ng/uL
85
0
44
63
80
72
1
72
39
0
10
67
73
73
0
32
33
0
.73%
.00%
.69%
.71%
.16%
.87%
.10%
.90%
.05%
.00%
.13%
. 84%
.53%
.09%
.00%
.02%
.50%
.00%
Qvalue
3 .24 ng/uL
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
90
(#) = qualifier out of range (m) = manual integration
ENG1316.D PES.M Wed May 26 13:10:49 1999 HP 5989B
Page l
-------
Quantitation Report
Data File : C:\HPCHEM\1\DATA\9919\ENG1316.D
Acq On : 18 May 99 2:35 pm
Sample : PES XAD/FILTER LAB BLANK
Misc :
Quant Time: May 26 13:04 1999
Method
Title
Last Update
Response via
C:\HPCHEM\1\METHODS\PES.M
Mon May 24 16:23:27 1999
Multiple Level Calibration
Vial: 4
Operator: JEMcCartney
Inst : HP 5989B
Multiplr: 1.00
Abundance
le + 07 ^
9000000 -
8000000
7000000 -
6000000 _
5000000 -|
4000000 -
3000000 _
2000000 -
1000000 _
"Time-->
TIC: ENG1316.D
3
2s
lls
15s
1
; ,j
1
LJLiin
L
3*PS
,11
i:
173 22S
*Tt£i^i
5s
20s 32s
. 1 R
20.00
30:00
40:00
50.00
60.00
OCi
- <•
.ENG1316.D PES.M
Wed May 26 13:10:55 1999
HP 5989B
Page 2
-------
Abundance TIC: ENG1316.D
,\
/ i
/ \
: 1000000 . Ay
/ 1
' '
500000- / \
' / \
Time
n '
--> 22!lO ' 22:20 22:30
Abundancelon 136.00 (135. vu to ub.vuj: awu
i nnnnnn ;ion 68.00 (67.70 to 68.70): ENG13
, 800000 J 22 .24
600000 : , '.
400 ooo: : '{
' 200000 _ / / \ \
n J ^~~~ -=^ x _ V: - — — •
Time
--> 22 :iO 22 :20 22:30
Abundance TIC: ENG1316.D
#2
Napht hal ene - d8
Concen: 3.43 ng/uL
RT: 22.24 min Scan# 1568
Delta R.T. 0 . 01 min
Lab File: ENG1316.D
Acq: 18 May 99 2 :35 pm
Tgt Ion: 136 Resp: 1944122
Ion Ratio Lower Upper
136 100
68 0.0 10.1 30. 1#
0 0.0 0.0 0.0
0 0.0 0.0 0.0
#3
1000000
500000 -
Naphthalene(CCC)
Concen: 3.24 ng/uL
RT: 22.30 min Scan# 1577
Delta R.T. 0.02 min
Lab File: ENG1316.D
Acq: 18 May 99 2:35 pm
Tgt Ion:128 Resp: 2136822
Ion Ratio Lower Upper
128 100
0.0
0 . 0
Time-->
22:20
22:30
22.40
127
0
0
13 .9
0 .0
0.0
0.0
60.0
0.0
0 .0
Abundancelon 128.00 (127.70 to 128.70): ENG
'. 1000000 Jlon 127.00 (126.70 to 127.70): ENG
22.30
1
500000 .,
0
Time--> 22 .20
ENGT3T6TD PES .M
22:30
22:40
Wed May 2613:10:by 1999
HP 5989B
Page 3
-------
Abundance TIC: ENG1316.D
: !
sooooo ;
600000 J
1
400000 -J
200000 :
1 1 '\
Time--> '23 loo' '23!so' 24 I 00 24 I 5
0 25 loo'
#4
2-Methlynaphthalene-dlO
Concen: 0.00 ng/uL
Expected RT: 23.96 min
Lab File: ENG1316.D
Acq-. 18 May 99 2:35 pm
Tgt Ion: 152
Ion Exp Ratio
152 100
0 0.0
0 0.0
0 0.0
4000
3000
2000 J
1000 :
Time--> 23loO '23150 24 1
Abundance
400000 -
300000 _
1 200000-
100000 .
0
Time- - >
00 24:50' 25.'00'
TIC: ENG1316.D
p
I I
1 1
i -
j
1
1
AJ
26.20
#5
Acenaphthylene-d8
Concen: 1.79 ng/uL
RT: 26.29 min Scan# 2450
Delta R.T. 0.01 min
Lab File: ENG1316.D
Acg: 18 May 99 2:35 pm
1
j
1
V
26140
Tgt Ion:160 Resp: 1068558
Ion Ratio Lower Upper
160 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundancelon 160.00 (159.70 to 160.70
26.29
: 400000 j A
; ! M
200000 J ;
ENG i
n
«* Time-->
PES.M
26:20 26140
Wed May 26 13:11:01 1999
ore }•;
HP 5989B
Page 4
-------
Abundance
400000:
300000:
i
200000:
100000 J
J
0 i
TIC: ENG1316.D
": #6
: Acenaphthylene
i Concen: 0.00 ng/uL
! Expected RT: 26.32 min
Lab File:
ENG1316.D
Acq: 18 May 99 2:35 pm
Tgt Ion: 152
Time-->
25.50 26:00 26.50 27.00
Abundance Ion 152.00 (151. 70 to 152 . 70)
2000004Ion 153.00 (152.70 to 153.70)
150000 _
100000 :
50000:
Ion
152
i 153
i 0
0
~ENG~
ENG
Exp Ratio
100
15.0
0.0
0.0
n j
Time-->
Abundance
i
I 400000 J
300000:
I 200000:
1 100000:
25.50 26.00 26.50 27.00
TIC: ENG1316.D
\
Time--> 26.60 26170 26^80
Abundance Ion 164.00 (163.70 to 164 . 70
26.72
400000 j
200000 _
n
Time-->
ENG'Ulb.D
26i60
#7
Acenaphthene-dlO
Concen: 2.55 ng/uL
RT: 26.72 min Scan# 2514
Delta R.T. 0.01 min
Lab File: ENG1316.D
Acq: 18 May 99 2:35 pm
Tgt Ion:164 Resp: 1010097
j Ion Ratio Lower Upper
164 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
ENG
PES.M
26:70 26:80
wea way 2b 13:11:04 1999
oc
^.;
HP 5989B
Page 5
-------
Abundance
600000 -
400000 J
TIC: ENG1316.D
200000
0 ^=
Time-->
ATjuncTance
600000 ,
400000 -
200000
TIC: ENG131S.D
V
Time--> 26.00 26.50 27.00 27.50
Abundance Ion 154.00 (153.70 to 154.70): ENG
: 200000 Ion 153.'. (152.70 to 153.70): ENG
150000
100000
50000 :
0 1
— #8
I i Acenaphthene(CCC)
:': i Concen: 0.00 ng/uL
i! i Expected RT: 26.79 min
ii;
II I Lab File: ENG1316.D
Acq: 18 May 99 2:35 pm
Tgt Ion: 154
Ion Exp Ratio
154 100
153 86.8
0 0.0
0 0.0
26:00 26.50 27.00 27.50
; o i . , -/
Time--> 27180 28^00 28^20
Abundancelon 176.00 (175.70 to 176.70): ENG
#9
Fluorene-dlO
Concen: 3.21 ng/uL
RT: 28.01 min Scan# 2709
Delta R.T. 0.01 min
| Lab File: ENG1316.D
| Acq: 18 May 99 2:35 pm
i
i
I Tgt Ion:176 Resp: 1378849
Ion Ratio Lower Upper
176 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
600000 J
400000 J
28.01
200000 _
Time
ENG1316
-->
.L)
27
PES.M
80'
wea
28.00
May 26
1 , —
13:1
28
1 : 0
. 20
6 1999
OCC)7:0
HP 5989B Page 6
-------
Abundance
; 600000.
400000
200000 _
TIC: ENG1316.D
0
j L
Time--> 27:00 27.50 28.00 28.50 29.00
~. #10
i Fluorene
| Concen: 0.00 ng/uL
i Expected RT: 28.08 min
i
. Lab File: ENG1316.D
! Acq: 18 May 99 2:35 pm
Tgt Ion: 166
Ion Exp Ratio
166 100
165 76.2
0 0.0
0 0.0
Abundancelon 166.00 (165.70 to 166.70): ENG
lion 165.00 (164.70 to 165.70): ENG
4000 -
2000 -
Time--> 27.00 27.50 28.00 28.50 29.00
Abundance
1000000 -
TIC: ENG1316.D
A
500000 _
0
Time--> 30i30 30:40 30.50 30^60
Abundancelon 188.00 (187.70 to 188.70): ENG
Jon 94.00 (93.70 to 94.70): ENG13
30.44
#11
Phenanthrene-dlO
Concen: 2.91 ng/uL
RT: 30.44 min Scan# 3078
Delta R.T. 0.01 min
Lab File: ENG1316.D
Acq: 18 May 99 2:35 pm
Tgt Ion:188 Resp: 1942626
Ion Ratio Lower Upper
188 100
94 30.1 15 .1 45.1
0 0.0 0.0 0.0
0 0.0 0.0 0.0
500000 _•
Time--> 30^30
ENG1J16.D PES.M
30.4030:50 30:60
Wed May 2fe 13:11:UH
w .•%•; ;
HP 5989B Page 7
-------
Abundance TIC: EN<
1000000 _
; 1
\ I
500000 -
t
1 n ] . _ _ J
fTime--> 29! 50 30 100 3C
31316. D
i
!
i
1-
1.50 31.00
Abundancelon 178.00 (177.70 to 178.70): ENG
'! lion 176.00 (175.70 to 176.70): ENG
#12
Phenanthrene
Concen: 0.00 ng/uL
Expected RT: 30.49 min
Lab File: ENG1316.D
Acq: 18 May 99 2 :35 pm
Tgt Ion: 178
Ion Exp Ratio
178 100
176 20.0
0 0.0
0 0.0
10000 -!
5000 _!
Time-->
29.50 30.00 30.50
Abundance
1000000 _
"TIC: ENO1316.D
500000 _
0
Time--> 30.40 30^50 30.60 30.70
Abundancelon 188.00 (187.70 to 188.70): fiNG
#13
Anthracene-dlO
Concen.- 0.04 ng/uL
RT: 30.58 min Scan# 3099
Delta R.T. 0.01 min
| Lab File: ENG1316.D
Acq: 18 May 99 2:35 pm
Tgt Ion:188 Resp: 25378
Ion Ratio Lower Upper
188 100
94 36.9 15.1 45.1
0 0.0 0.0 0.0
0 0.0 0.0 0.0
;lon 94.00 (93.70 to 94.70;
ENG 13
500000
30.58
Time--> 30i40 30.50 30^60 30.70
Wed May
1999
OCi
HP 5989B
Page 8
-------
Abundance
1000000 _
TIC: ENG1316.D
500000
#14
Anthracene
Concen: 0.00 ng/uL
Expected RT: 30.62 min
Lab File: ENG1316.D
! Acq: 18 May 99 2:35 pm
i Tgt Ion: 178
n "
*Time-->29
Abundance
:so
Ion
Ion
30
178
176
.00
uu
00
; i
_j <
30.
(177
(175
^/^^
50
.70
.70
31
to
to
.00
178
176
.70) :
.70) :
ENG
ENG
Ion Exp Ratio
178 100
176 20.0
0 0.0
0 0.0
10000
5000_
Time-->29.50 30.00 30!5o' ' 31 1 00 ' ' 31 1 50 '
Abundance
800000 J
T
600000 1
I
1
, 400000J
1 200000 :
TIC: ENG1316.D
#15
Fluoranthene-dlO
Concen: 2.92 ng/uL
RT: 33.58 min Scan# 3619
Delta R.T. 0.01 min
Lab File: ENG1316.D
Acq: 18 May 99 2:35 pm
Tgt Ion:212 Resp: 1924080
Ion Ratio Lower Upper
212 100
. ; J V_
Time--> 33.40 33.60 ' 33i80
ADunaancelon 212.00 (211.70 to 212.70): fiNG
800000 Jlon 106.00 (105.70 to 106.70)- ENG
\ 33.58
1 600000.
i
400000 .
200000 .
0 .
f\
1 \
1 \
I \
i
: A '
106 35 .0 15 . 1 45 .1
0 0.0 0.0 0.0
0 0.0 0.0 00
' ' \ '
'J \'\
/ ^
OCC }/••;;
Time--> 33140 33.60 33.80
HP 5989B
Page 9
-------
ABunoTance TIC: ENG1316.D #16
800000 : ( j
: 600000 J i'.
i *;
400000 ji''
1i|
\ ' • \
; 200000jh
Fluoranthene
j Concen: 0 .00
i Expected RT:
i
\
Lab File:
Acq: 18 May
i
Tgt Ion: 202
\
i-1' K K
0 v ^- — 1 v ' ^
Time--> 32.50 33lOo' 'sSiSO '34100 34lsO
Abundancelon 202.00 (201.70 to 202.70): ENG
jlon 101.00 (100.70 to 101.70): ENG
i 6000 1 ]\
j
/
\
r
l\
Ion Exp
202 100
101 27
0 0
w v/
0 0
/r -v-J V ^yvAfN'^^^^f^--^
2000. i
i
n '
Time--> 32!50 33. Oo' 'ssls'o 34. DO' 34.50
(CCC)
ng/uL
33 .62 min
ENG1316.D
99 2 :35 pm
Ratio
.0
o
• W
.0
Abundance
400000 _
200000 J
TIC: ENG1316.D
A
#17
Pyrene-dlO
! Concen-. 1.56 ng/uL
| RT: 34.26 min Scan# 3721
! Delta R.T. 0.01 min
Lab File: ENG1316.D
| Acq: 18 May 99 2:35 pm
I
Tgt Ion:212 Resp: 1131404
Ion Ratio Lower Upper
0 r
Time-->
Abundance
( ~*
i 400000 :
^
34
Ion
Ion
:oo
212 . 00
106.00
i
J
34.20
(211.
(105.
34
1
v..
212
106
n
| i | . ; i -r --[ j
34140
70 to
70 to
.26
P
212 .70) : ENG
106.70) : ENG
0
100
36
0
0
.9
. 0
.0
17
o
0
.1
. 0
.0
51.1
0 . 0
0.0
300000 j
200000:
100000:
vs
Time-->
34
00
34
i — i — i—
.20
— i 1 1 r
34UO
1 1 r™ -T
Wed May
1999
OCC/.V-'j:
— -!*
HP 5989B Page 10
-------
Abundance
800000 :
600000;
J
400000^
1
T
; 200000 .j
TIC: ENG1316.D
Time-->
33:50 34:00 34.50 35:00
Abundancelon 202.00 (201.70 to 202.70)
'Ion 101.00 (100.70 to 101.70)
6000 j
4000:
2000
ENG
ENG
#18
Pyrene
Concen: 0.00 ng/uL
Expected RT: 34.30 min
Lab File: ENG1316.D
Acq: 18 May 99 2:35 pm
Tgt Ion: 202
Ion Exp Ratio
202 100
101 32.0
0 0.0
0 0.0
Time-->
33.50 34.00 34.50 35lOO
Abundance
i j
! sooooo:
600000 _
400000 .
! 200000
TIC: ENG1316.D
0
Time--> 33:50 34:00 34:50 35:00 35:50 |
Abundancelon 244.00 (243.70 to 244.70): ENG I
Jlon 122.00 (121.70 to 122.70): ENG |
! 4000n
2000 H
#19
p-Terphenyl-d!4
Concen: 0.00 ng/uL
Expected RT: 34.57 min
I Lab File: ENG1316.D
i Acq: 18 May 99 2:3 5 pm
Tgt Ion: 244
Ion Exp Ratio
244 100
122 27.0
0 0.0
0 0.0
Time--> 33:50 34.00 34.50 35:00 35.50
ENG'Ulfe.D PES.M
Wed May 26 13:11:21 1999
HP 5989B
Page 11
-------
Abundance
! 400000 J
; 300000:
-i
200000 J
l
1 1
looooo:
TIC: ENG1316.D
0
Time--> 38^70 38.80 38.90 39-°°
Ion 240.00 (239.70 to 240.70): ENG
120.00 (119.70 to 120.70): ENG
300000 J
200000 j
100000:
38.88
0 ;-
,Time--> 38.70
38^80
38.90
39:00
Abundance
400000-
\
300000-
1 i
200000 :
100000 :
TIC: ENG1316.D
0
,Time-->
3s:oo seiso 39.00
Time-->
38.00 38.50 39.00 39.50
ENG1316.DPES.M
Wed May 26 13:11:23 1999
#20
Benzo(a)anthracene-d!2
Concen: 0.41 ng/uL
RT: 38.88 min Scan# 4416
Delta R.T. 0.01 min
Lab File: ENG1316.D
Acq: 18 May 99 2:35 pm
Tgt lon:240 Resp: 188418
Ion Ratio Lower Upper
240 100
120 30.5 15.1 45.1
0 0.0 0.0 0.0
0 0.0 0.0 0.0
#21
Benzo(a)anthracene
Concen: 0.00 ng/uL
Expected RT: 38.98 min
Lab File: ENG1316.D
Acq: 18 May 99 2 : 3 5 puv
Tgt Ion: 228
Ion Exp Ratio
228 100
114 25.0
0 0.0
0 0.0
AbundanceTon 22BTOO(227.70 to 228.70): ENG
; jlon 114.00 (113.70 to 114.70): ENG
8000:
6000 j
oe
c/y.,.,3
HP 5989B
Page 12
-------
Abundance TIC: ENG1316.D
1
'• A
400000 Jj / \
1 ' \
300000- : \
-
200000 :
i
H / \
100000 : / \
n 1 " •
w -! 1 1 1 1 i 1 ] ' 1 1 ' 1 : i r-
Time--> 38.80 39.00 39.20
Ab
Ti
undancelon 240.00 (239.70 to ^4U.7U): E
400000 -ion 120.00 (119.70 to 120.70): E
\ 39.04
r
300000 : / \
200000 J
\
' \
4 ' \
100000 _; . \
1 / \. \
/ / x v
n ^ ^^^>--^// ^-^±r— -— _
me--> 38.80 39.00 39i20
Abundance TIC: ENG1316.D
Ti
400000 J 1
^ i
300000 J
1 1
j I
200000 _ i
'_ i
100000 : ;
•* i i
A ' *
n 1
me--> 38.50 '39 00 39^50' VoiOO
: #22
Chrysene-dl2
Concen: 2.71 ng/uL
i RT: 39.04 min Scan# 4441
Delta R.T. 0.01 min
Lab File: ENG1316.D
! Acq: 18 May 99 2:35 pm
Tgt Ion:240 Resp : 1528155
Ion Ratio Lower Upper
240 100
120 28.8 15.1 45.1
— n n n n n n n
p W \J . \J \J , \J W.W
0 0.0 0.0 0.0
NG
NG
I
1
#23
Chrysene (CCC)
Concen: 0.00 ng/uL
Expected RT: 39.16 min
Lab File: ENG1316 .D
Acq: 18 May 99 2:35 pm
Tgt Ion: 228
'• Ion Exp Ratio
228 100
: 114 25.0
0 0.0
0 0.0
Abundancelon 228.00 (227.70 to 228.70): ENG;
}Ion 114.00 (113.70 to 114.70): ENG:
8000 J
' i
6000 J
J : !
4000 :
1 A ' r- ' A
'• 1 \ ! r\ . /A
2000 J" ' " ""
0 _
Time--> 38^50 39.00 39^50 40iOO
i
V^
fir~
wC-;V,:7
ENG'1316 .D PES .M
wea May 26 l3TTi:26
HP 5989B
Page 13
-------
Abundance^
200000 4
100000
TIC: ENG1316.D
0
#24
Benzo(b)fluoranthene-d!2
Concen: 2.94 ng/uL
RT: 45.89 min Scantt 5492
Delta R.T. 0.02 min
Lab File: ENG1316.D
Acq: 18 May 99 2:35 pm
j Tgt Ion:264 Resp: 1219679
! Ion Ratio Lower Upper
j 264 100
132
0
Time--> 45.80 46^00
Abundancelon 264.00 (263.70 to 264.70): ENG
^lon 132.00 (131.70 to 132.70): ENG
200000 H 45 .89
150000
100000
50000 ;
Time-->
45.80
46.00
Abundance
200000 .
100000
TIC: ENG1316.D
0
Time--> 45.00 45.50 46.00 46^50 47.00
Abundancelon 252.00 (251.70 to 252.70): ENG
Ion 126.00 (125.70 to 126.70): ENG
6000
4000 „
2000 „
0
Time--> 45^00 45.50 46.00 46.50 47^00
0
33.6
0.0
0.0
15.1
0.0
0.0
45.1
0.0
0.0
#25
Benzo(b)fluoranthene
Concen: 0.00 ng/uL
Expected RT: 46.07 min
Lab File: ENG1316.D
Acq: 18 May 99 2:35 pm
Tgt Ion: 252
Ion Exp Ratio
252 100
126 25.0
0 0.0
0 0.0
PES.M
Wed May 26 13:11:29 1999
HP 5989B
Page 14
-------
Abundance
200000 „•
100000 .:
TIC: ENG1316.D
/ \
\
Time - - >
Abundance
200000 -]
150000 ;
100000 :
50000 -
0 -i
Time-->
Abundance
45180 46 '.00 46120 46140
Ion 264.00 (263.70 to 264.70): ENG
Ion 132.00 (131.70 to 132.70): ENG
46.09
^ A
A !\
' \ ! \
\
: ,r\ '^ /V\
•"^ i " •
45 .80 46 100 46i 20 46 40 '
TIC: ENG1316.D
] #26
: Benzo(k)fluoranthene-dl2
: Concen: 2.92 ng/uL tn
! RT: 46.09 min Scan# 5523
Delta R.T. 0.01 min
Lab File: ENG1316.D
j Acq: 18 May 99 2:35 pm
Tgt Ion:264 Resp: 1650721
i Ion Ratio Lower Upper
! 264 100
I 132
0
37.3
0.0
0.0
15 .1
0.0
0.0
45.1
0.0
0.0
200000 _
100000 _•
1 #27
Benzo(k)fluoranthene
Concen: 0.00 ng/uL
Expected RT: 46.23 min
Lab File: ENG1316.D
Acq: 18 May 99 2:35 pm
Tgt Ion: 252
Ion Exp Ratio
i \
; / \.
n
Time--> 45.50 46100 46150 47.00
252 100
j 126 25 . 0
- : 0 0.0
i o o.o
Abundancelon 252.00 (251.70 to 252.70): ENGi
126.00 (125.70 to 126.70): ENG
6000:
4000 J
2000:
0 _
Time-->
ENGUlfe.D
T
45.50 46.00 46150 47100
PES.MWed May 2fe 13:11:J2
oc
.» i' i- >-/
HP 5989B
Page 15
-------
Abundance
15000 -
! 10000 -
! 5000 -
TIC: ENG1316.D
0
Time--> 47150 48:00 48!50 49.00 49.50
'Abundancelon 264.00 (263.70 to 264.70): ENG
i ]Ion 132.00 (131.70 to 132.70): ENG
; 6000
4000^
Benzo(a)pyrene-d!2
Concen: 0.00 ng/uL
Expected RT: 48.54 min
Lab File: ENG1316.D
Acq: 18 May 99 2:35 pm
Tgt Ion: 264
Ion Exp Ratio
264 100
132 30.0
0 0.0
0 0.0
2000 :
47.50 48.00 48.50 49.00 49^50
Abundance
15000 J
10000-
5000J
0
TIC: ENG1316.D
A
Time--> 48.00 49.00 50.00
Abundancelon 252.00 (251.70 to 252.70): ENG '.
6000jlon 126.00 (125.70 to 126.70): ENG,
4000 J
Benzo (a) pyrene (CCC)
Concen: 0.00 ng/uL
Expected RT. 48.74
Lab File: ENG1316.D
: Acq: 18 May 99 2:35 pm
i
Tgt Ion: 252
: Ion Exp Ratio
252 100
i 126 25.0
0 0.0
0 0.0
2000^
0 _
Time-->
"*™ENG1316 .D PES .M
48.00
49.00
sooo
Wea May 26 13:11:35 1999
Of
HP 5989B
Page 16
-------
Abundance
• 80000 :
60000-
40000-
20000 j
TIC: ENG1316.D
#30
Indeno(1,2,3-cd)pyrene-d!2
Concen: 1.28 ng/uL
RT: 61.50 min Scan# 8103
Delta R.T. 0.02 min
; Lab File: ENG1316.D
. Acq: 18 May 99 2:35 pm
Tgt Ion:288 Resp: 644776
Ion Ratio Lower Upper
n ;
Time--> 61.00 ' 6ll50 62loO
Abundancelon 288.00 (287.70 to 288.70): ENG
i 61.50
; A
40000 _• / \
/ \
20000 J / \
- • \
u
Time--> 6llOD 61.50 62100
Abundance TIC: ENG1316.D
1 80000 : A
M
' 60000 _ I i
i 1
i ' i
; \
40000 _ ;' \
\
20000: j V^_
n i
Time--> 6lloO ' 62ioO ' 63.00
Abundancelon 276.05 (275.75 to 276.75): ENG
^lon 138.00 (137.70 to 138.70): ENG
4000 J
3 A
< y v
2000 :
1000 J
o :
Time--> 61.00 62100 63 00
0 0.0 0.0 0
0 00 00 0
0 0.0 0.0 0
#31
Indeno (1,2, 3-cd) pyrene
Concen: 0.00 ng/uL
Expected RT: 61.83 min
Lab File: ENG1316.D
Acq: 18 May 99 2 :35
Tgt Ion: 276.05
Ion Exp Ratio
o 7£ inn
138 64.0
0 00
0 0.0
I
i
OCC 57 v [
.0
n
.0
pm
Wed May 2k 13:11:38
HP 5989B
Page 17
-------
Abundance
80000 :
60000 ;
40000 :
20000 ^
1
Time-->
Abundancelon
30000 -
20000 _
10000 .
0 .
Time-->
Abundance
80000 _;
60000 J
40000 :
20000 _
n -
Time-->
Abundance Ion
•ilon
4000 :
3000 -^w*v/s
2000 .
1000 .
0 _
*Time-->
T T 1 c — rs nrr" — r
TIC: ENG1316.D . #32
A Dibenz (a, h) anthracene -d!4
/ \ Concen: 1.34 ng/uL
' - RT: 61.46 min Scan# 8095
; \ < Delta R.T. 0 .02 min
\ 1 Lab File: ENG1316.D
/ \ ' Acq: 18 May 99 2:35 pm
/' \ ! Tgt Ion: 292 Resp: 396076
J ^-*~^___^ Ion Ratio Lower Upper
. / " — 292 100
| 0 0
i n n
61 '. 00 61.50 62 i 00 j 0 0
292.00 (291.70 to 292.70): ENG!
61.46 ;
/ \
. \
/ * '
1
' l i
\
i
61.00 61.50 62.00
TIC: ENG1316.D j #33
A Dibenz (a
/ \ Concen:
/ 1 ; Expected
/ 1
\ ! Lab File
! \ ! Acq: 18
\ Tgt Ion:
/ "v^ Ion
-S — • — 7 "7 P
139
0
61.00 62.00 63.00 0
278.00 (277.70 to 278.70): ENG
139.00 (138.70 to 139.70): ENG
/N
^WVvi-/vSW**'' '^"^^^'^i^MM^ArS^nkAwgi^^
^***\
**rV***~~'V-*tT**n~' ^~J^-*f-J^-^^^^~f^^-r~~^^tr^r^rJ^^^f^,
61.00 62.00 €3100 j
.0 0.0 0.0
.0 0.0 0.0
.0 0.0 0.0
, h) anthracene
0.00 ng/uL
RT: 61.85 min
: ENG1316.D
May 99 2 : 3 5 pm
278
Exp Ratio
100
25 .0
0.0
0.0
HP 5989B
Page 18
-------
Abundance
15000 _v-
TIC: ENG1316.D
J
10000 _
5000 -•
0
Time--> 64J 00 65:pQ 66.00
Abundance Ion 288.00 (287.70 to 288.70): ENG
3000 -,'
~t\
2000 1
•I
1000 j
j
0 _
Benzo(g,h,i)perylene-d!2
Concen: 0.00 ng/uL
Expected RT: 65.06 min
Lab File: ENG1316.D
Acq: 18 May 99 2:35 pm
Tgt Ion: 288
Ion Exp Ratio
288 100
0 0.0
0 0.0
0 0.0
Time- - >
Abundance
: 15000 J*
! -\
j
! 10000 J
1
5000 -
0 "
Time- -> 64
64 .00 65 . 00 6c . 00
TIC: ENG1316.D
oo 6s:oo 66:00
#35
Benzo(g,h, i)perylene
Concen: 0.00 ng/uL
Expected RT: 65.44 min
Lab File: ENG1316.D
Acq: 18 May 99 2 :35 pm
Tgt Ion.- 276
Ion Exp Ratio
276 100
138 25.0
o n o
0 o.O
jlon 138.00 (137.70 to 138.70]
ENG
3000 J
2000 J
r^^
1000 _
0
Time-->64.00
ENG1J16 .D
65:00 66.00
Wed May 26 1J:11:4S
0,
HP 5989B
Page 19
-------
ENG1317.XLS
Quantitation Report Summary
Data File
Date Analyzed:
Sample ID
Method ID
Operator
Instrument
Compounds
Naphthalene(CCC)
Acenaphthylene
Acenaphthene(CCC)
Fluorene
Phenanthrene
Anthracene
F)uoranthene(CCC)
Pyrene
Benzo( a )anthracene
Chrysene(CCC)
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Benzo(a)pyrene(CCC)
lndeno(1,2,3-cd)pyrene
Dibenz(a,h)anthracene
Benzo(g,h,i)perylene
ENG1317.D
05/18/99)
PES HEXANE BLANK
PES
JEMcCartney
HP 5989B
Area
3138
0
0
0
21849
5063
4046
0
0
0
0
0
0
0
0
0
* PQL - practical quantitation limit
Surrogate Recoveries
Compound
Naphthalene-d8
Acenaphthylene-d8
Acenaphthene-d10
Fluorene-d10
Phenanthrene-d10
Anthracene-d10
Fluoranthene-d10
Pyrene-d10
Benzo(a)anthracene-d12
Chrysene-d12
Benzo(b)fluoranthene-d12
Benzo(k)fluoranthene-d12
Benzo(a)pyrene-d12
Indeno(1,2,3-cd)pyrene-d12
bibenz(a,h)anthracene-d14
Benzo(g,h,i)perylene-d12
Recovery Standard
Compound
2-Methlynaphthalene-d10
3-Terphenyl-d14
Compiled by:
Reviewed by:
Cone.
(ng/uL)
0.006
0.000
0.000
0.000
0.035
0.008
0.006
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Cortc. (ng/uL)
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
Concentration (ng/pL)
0.00
0.00
s'
^^
PQL*
(ng/uL)
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
y^f^fe^***" ,>//7/7y
dfeWnOCTja^Oxv^^ ^O.vy?
\J
Cone.
(ng/sample)
6.2
0.0
0.0
0.0
35.0
8.4
6.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
% Recovery
0.00
0.00
0.00
0,00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
% Recovery
0.00
0.00
A
Cone, (ng/sample)
wl Surr. correction
6.2
0.0
0.0
0.0
35.0
8.4
6.0
0.0
0.0
0.0
0.0
0.0
0.0
L 0.0
0.0
0.0
-------
Quantitation Report
C:\HPCHEM\1\DATA\9919\ENG1317.D
18 May 99 3:50 pm
PES HEXANE BLANK
Data File
Acq On
Sample
Misc :
Quant Time: May 26 13:34 1999
Vial: 5
Operator: JEMcCartney
Inst : HP 5989B
Multiplr: 1.00
Method
Title
Last Update
Response via
C:\HPCHEM\1\METHODS\PES.M
Mon May 24 16:23:27 1999
Multiple Level Calibration
Internal Standards
R.T. Qlon Response Cone Units Dev(Min)
1)
2 , 2-Dif luorobiphenyl
24
.59
190
1438550
5.
System Monitoring Compounds
2)
4)
5)
7)
9)
11)
13)
15)
17)
19)
20)
22)
24)
26)
28)
30)
32)
34)
Naphthalene -d8
2-Methlynaphthalene-dlO
Acenaphthylene-d8
Acenaphthene-dlO
Fluorene-dlO
Phenant hrene - dl 0
Anthracene - dl 0
Fluoranthene-dlO
Pyrene-dlO
p-Terphenyl-dl4
Benzo (a) anthracene-d!2
Chrysene-dl2
Benzo (b) f Iuoranthene-dl2
Benzo (k) f Iuoranthene-dl2
Benzo (a) pyrene-d!2
Indeno ( 1 , 2 , 3 - cd) pyrene-d!2
Dibenz (a, h) anthracene -d!4
Benzo (g, h, i) perylene-d!2
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
136
152
160
164
176
188
188
212
212
244
240
240
264
264
264
288
292
288
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
Target Compounds
3)
6)
8)
10)
12)
14)
16)
18)
21)
23)
25)
27)
29)
31)
33)
35)
Naphthalene (CCC)
Acenapht hyl ene
Acenaphthene (CCC)
Fluorene
Phenanthrene
Anthracene
Fluoranthene (CCC)
Pyrene
Benzo (a) anthracene
Chrysene(CCC)
Benzo (b) f luoranthene
Benzo (k) f luoranthene
Benzo (a) pyrene (CCC)
Indeno ( 1 , 2 , 3 - cd) pyrene
Dibenz (a, h) anthracene
Benzo (g, h, i) perylene
22
0
0
0
30
30
33
0
0
0
0
0
0
0
0
0
.28
.00
.00
.00
.50
.63
.63
.00
.00
.00
.00
.00
.00
.00
.00
.00
128
152
154
166
178
178
202
202
228
228
252
252
252
276
278
276
3138
21849
5063
4046
0.
Not
Not
Not
0.
0.
0.
Not
Not
Not
Not
Not
Not
Not
Not
Not
00 ng/uL
0
.00
%Recoverv
00 ng/uL
00 ng/uL
00 ng/uL
00 ng/uL
00 ng/uL
00 ng/uL
00 ng/uL
00 ng/uL
00 ng/uL
00 ng/uL
00 ng/uL
^ •
00 ng/uL
00 ng/uL
00 ng/uL
00 ng/uL
00 ng/uL
00 ng/uL
00 ng/uL
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.00%
.00%
.00%
.00%
.00%
.00%
.00%
.00%
.00%
.00%
.00%
.00%
.00%
.00%
. 00%
.00%
.00%
.00%
Qvalue
01 ng/uLm
Detected
Detected
Detected
03 ng/uL#
01 ng/uL#
01 ng/uLm
Detected
Detected
Detected
Detected
Detected
Detected
Detected
Detected
Detected
0
56
56
48
OC03765
(#) = qualifier out of range (m) = manual integration
ENG1317.D PES.M Wed May 26 13:37:27 1999 HP 5989B
Page 1
-------
Quantitation Report
Data File : C:\HPCHEM\1\DATA\9919\ENG1317.D
Acq On : 18 May 99 3:50 pm
Sample : PES HEXANE BLANK
Misc :
Quant Time: May 26 13:34 1999
Method
Title
Last Update
Response via
C:\HPCHEM\1\METHODS\PES.M
Mon May 24 16:23:27 199?
Multiple Level Calibration
Vial: 5
Operator: JEMcCartney
Inst : HP 5989B
Multiplr: 1.00
Abundance
1100000 J
1000000 :
900000 .
800000.
700000^
600000 :
500000 :
400000 :
300000 1
200000 _
100000.
n
rime-->
3
1 . . . 1.
' 1 1 1 1 1 — Lrd
20.00
u
Lu— .
1 1 1 r
soloo
TIC: ENG1317.D
j
!
16
-J-r— — X. __ ,
1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1
40.00 50.00 60.00
OOC3765
ENG1317.D PES.M Wed May 26 13:37:32 1999 HP 5989B Page 2
-------
Sundance
10000.
5000.
0
Time-->21
Abundance
4000.
2000 .
i
0 .
Time-->21
TIC: ENG1317.D
loo' '2ll5o' 22loo' 22150 23loO
Ion 136.00 (135.70 to 136.70): ENG
Ion 68.00 (67.70 to 68.70): ENG13
rA^v-vAA^v^^^^^V-w^"*^ VAkvw*t^^rNA^V*-^-v*V«^A^
" - 0^^-^-—-^*^-™—-
OO' '2li5o' '22! bo' '22!50' '2:3 loo'
#2
Naphthalene-d8
Concen: 0.00 ng/uL
Expected RT: 22.23 min
Lab File: ENG1317.D
Acq: 18 May 99 3:50 pm
Tgt Ion: 136
Ion Exp Ratio
136 100
68 20.0
0 0.0
0 0.0
Sundance
•
10000 .
•
5000 .
'
0 .
TIC: ENG1317.D
• — — ^ _ .
Time--> '22120' '22125' '22130 ' ' 22\35 '
Abundancelon 128.00 (127.70 to 128.70): ENG
-
4000 -
3000 .
2000-
1000-
0.
Ion 127.00 (126.70 to 127.70): ENG
22.28
//~""-\
^/___^
Time--> '22120' '22125' '22 lab' ' 22135'
#3
Nap!
Con<
RT:
r)e»T H
J^*C^
Lab
Acq
Tgt
Ion
128
127
0
0
ENG1317.D PES.M wed May 26 13:37:35 iyyy
Naphthalene(CCC)
Concen: 0.01 ng/uL m
22.28 min Scan# 1573
a R.T. -0.01 min
File: ENG1317.D
Acq: 18 May 99 3:50 pm
Tgt Ion:128 Resp: 3138
Ratio Lower Upper
100
73.1 0.0 60.0#
0.0 0.0 0.0
0.0 0.0 0.0
KM -M
'•<- S
HP 5989B
Page 3
-------
Abundance
600000 J
400000 .
200000 1
0 '
Time-->
TIC: ENG1317.D
'2:3 loo' '23l50' '24 loo' '24l50' Vslo'o'
Abundancelon 152.00 (151.70 to 152.70): ENG
3000 J
1
j
2000 J
.
1000 J
0 '
Time-->
23 loo' '23.501 '24l do' '24l5o' Vslo'o'
#4
2-Methlynaphthalene-dlO
Concen: 0.00 ng/uL
Expected RT: 23.96 min
Lab File: ENG1317.D
Acq: 18 May 99 3:50 ptn
Tgt Ion: 152
Ion Exp Ratio
152 100
0 0.0
0 0.0
0 0.0
Abundance
8000_
6000 :
4000 :
2000 .
0
Time-->
Abundance
3000 .
2000^
1000.
0 '
rime-->
TIC: ENG1317.D
25.50 26.00 26.50 27.00
Ion 160.00 (159.70 to 160.70): EtfG
>— *_Cw^V~Vv' "VX-ww-Jyi
1 i ' i • iii -i — 1 — i — i — i — i — 1 — \ — i — i — i — | — i — i — i — i — j-
25 50 26100 26150 27loO
ENGIJJ./.D jjfcb.ivi wed May 26 13:37:38 1999
#5
Acenaphthylene-d8
Concen: 0.00 ng/uL
Expected RT: 26.29 min
Lab File: ENG1317.D
Acq: 18 May 99 3:50 pm
Tgt Ion: 160
Ion Exp Ratio
160 100
0 0.0
0 0.0
0 0.0
HP 5989B
Page 4
-------
Abundance
sooo:
eooo:
4000 :
2000 :
0
rime-->
Abundance
3000-
2000 .
1000 .
0
Time - - >
TIC: ENG1317.D
K. - . .25
Abundance
3000.
2000J
1000-
0
rime-->25
TIC: ENG1317.D
^-WL-~-— -A-^A
Is'o' Velo'o' '26 Is'o' '27!o'o' '2i\5o'
Ion 164.00 (163.70 to 164.70): ENG
^A__,
Is'o' Veldo' 26 Is'o' '2?! do' '271501
1317. D PES.M Wed May 2b 13:37:41 1999
#7
Acenaphthene-dl0
Concen: 0.00 ng/uL
Expected RT: 26.71 min
Lab File: ENG1317.D
Acq: 18 May 99 3:50 pm
Tgt Ion: 164
Ion Exp Ratio
164 100
0 0.0
0 0.0
0 0.0
00!
HP 5989B
Page 5
-------
Abundance
8000 :
eooo:
4000 :
2000 .
0 "
Time-->
Abundance
3000 :
1
2000 :
1000 -
0
Time-->
TIC: ENG1317.D
26.00 26.50 27.00 27.50
Ion 154.00 (153.70 to 154.70): ENG
Ion 153.00 (152.70 to 153.70): ENG
^^>v__^|vU^^
Velo'o' Vels'o' '2?! do' '27150' ' ' '
[Abundance
10000 -
TIC: ENG1317.D
fTime--> 27.00 27.50 28100 28.50 29.00
5000-
Abundancelon 176.00 (175.7Uto 176T70): ENG
3000 .
2000 .
1000 :
Time--> 27.00 27.50 28!00 28.50 29.00
#8
Acenaphthene(CCC)
Concen: 0.00 ng/uL
Expected RT: 26.79 min
Lab File: ENG1317.D
Acq: 18 May 99 3:50 pm
Tgt Ion: 154
Ion Exp Ratio
154 100
153 86.8
0 0.0
0 0.0
ENG1317.D
wea way
#9
Fluorene-dlO
Concen: 0.00 ng/uL
Expected RT: 28.00 min
Lab File: ENG1317.D
Acq: 18 May 99 3:50 pm
Tgt Ion: 176
Ion Exp Ratio
176 100
0 0.0
0 0.0
0 0.0
HP 5989B
Page 6
-------
Abundance
10000.
rime--> 27.00 27.50 28.00 28.50 29.00
TIC: ENG1317.D
5000.
Abundancelon 166.00 (165.70 to 166.70): ENG
Ion 165.00 (164.70 to 165.70): ENG
4000.
2000 .
0
Time--> 27100 27150 28!00 28150 29100
Abundance
30000 '.
TIC: ENG1317.D
rime--> 29.50 30.00 30.50 31.00
#10
Fluorene
Concen: 0.00 ng/uL
Expected RT: 28.08 min
Lab File: ENG1317.D
Acq: 18 May 99 3:50 pm
Tgt Ion: 166
Ion Exp Ratio
166 100
165 76.2
0 0.0
0 0.0
Abundance Ion 188.00 (187.70 to 188.70): ENG
Ion 94.00 (93.70 to 94.70): ENG13
6000 J
4000:
2000 '.
.A—
rime-->
29.50 30.00 30.50 31.00
ENGT3TT7DPBS .M
#11
Phenanthrene-dl0
Concen: 0.00 ng/uL
Expected RT: 30.43 min
Lab File: ENG1317.D
Acq: 18 May 99 3:50 pm
Tgt Ion: 188
Ion Exp Ratio
188 100
94 30.0
0 0.0
0 0.0
"771
Wed May 26 13:;37:48 1999
HP 5989B
Page 7
-------
Sundance
20000 .
10000.
T1C:
0
Time-->
30.40
3ol50
30.60
Abundancelon 178.00 (177.70 to 178.70): ENG
f T5DUO-1Ion 176.00 (175.70 to 176.70): ENG
30.50
10000-
5000 „
rime-->
30.40
3050
30.60
#12
Phenanthrene
Concen: 0.03 ng/uL
RT: 30.50 min Scan# 3088
Delta R.T. 0.01 min
Lab File: ENG1317.D
Acq: 18 May 99 3:50 pm
Tgt Ion:178 Resp: 21849
Lower Upper
Ion
178
176
0
0
Ratio
100
0.0
0.0
0.0
10.1
0.0
0.0
30.1#
0.0
0.0
Abundance
30000J
20000 -
10000 .
Time--> 29.50 30.00 30.50 31.00 31.50
TIC: ENG1317.D
0
Abundancelon 188.00 (187.70 to 188.70): ENG
Ion 94.00 (93.70 to 94.70): ENG13
6000 J
4000 J
2000J
Time--> 29l5o' 's'o
ENG1317.DPES.M
#13
Anthracene-dlO
Concen: 0.00 ng/uL
Expected RT: 30.57 min
Lab File: ENG1317.D
Acq: 18 May 99 3:50 pm
Tgt Ion: 188
Ion Exp Ratio
188 100
94 30.0
0 0.0
0 0.0
Wed May 26 13:37:bl
HP 5989B
r- -v
, O
Page 8
-------
Abundance
15000 J
10000J
sooo:
TIC: ENG1317.D
0
Time-->
30.55 30.60 30.65 30.70
lAbundancelon 178.00
10000Jion 176.00
(177.70 to 178.70): ENG
(175.70 to 176.70): ENG
5000 .
Time-->
30.55
30.60 30.65
30.70
#14
Anthracene
Concen: 0.01 ng/uL
RT: 30.63 min Scan# 3107
Delta R.T. 0.01 min
Lab File: ENG1317.D
Acq: 18 May 99 3:50 pm
Tgt Ion:178 Resp: 5063
Ion Ratio Lower Upper
178 100
176 0.0 10.1 30.1#
0 0.0 0.0 0.0
0 0.0 0.0 0.0
ENG
Abundance
800000:
600000:
400000 :
200000:
0 '
Time-->
Abundance
20000.
10000 .
0
rime-->
_J
TIC: ENG1317.D
3:2! so' 'aslo'o' ssls'o' '34 loo' '34! so'
Ion 212.00 (211.70 to 212.70): ENG
Ion 106.00 (105.70 to 106.70): ENG
1
.
i — ' " -j"— — — . — -
[•---- - - -
3i2l 50 ' '33lo'o' 33l SO' '34! OO' '34150'
rl317.D PES.M Wed. May 26 13:37:54 ISSS
#15
Fluoranthene-dl0
Concen: 0.00 ng/uL
Expected RT: 33.57 min
Lab File-. ENG1317.D
Acq: 18 May 99 3:50 pm
Tgt Ion: 212
Ion Exp Ratio
212 100
106 30.0
0 0.0
0 0.0
HP 5989B
GGC3773
Page 9
-------
Abundance
10000 '.
5000 .
0 .
Iime-->
Abundance
4000 .
2000 .
0 .
Time-->
TIC: ENG1317.D
331 55 ' ' 33i 60 ' ' 33! 65 ' ' 33! 70 '
Ion 202.00 (201.70 to 202.70): ENG
Ion 101.00 (100.70 to 101.70): ENG
33.63
^X V^
33! 55 ' ' 33! 60 ' ' 33l 65 ' ' 33i 70 '
#16
Fluoranthene(CCC)
Concen: 0.01 ng/uL m
RT: 33.63 min Scan# 3628
Delta R.T. 0.01 min
Lab File: ENG1317.D
Acq: 18 May 99 3:50 pm
Tgt Ion:202 Resp:
4046
Ion Ratio
202 100
101 83.8
0 0.0
0 0.0
Lower Upper
13.6
0.0
0.0
40.6#
0.0
0.0
ENG
Abundance
30000J
20000J
10000 J
01
TIC: ENG1317.D
1 J UA^-J
rime--> 33.50 34.00 34.50 35.00
Abundance
20000 .
10000^
0 '.
Time-->
Ion 212.00 (211.70 to 212.70): ENG
Ion 106.00 (105.70 to 106.70): ENG
1 -~-L-_-_
T TII III 1 1 1 1 I '"'I ' |— T'l 1 1 I 1 | |
33.50 34.00 34i50 35ioO
1.317. D PES.M Wed May 2fe 13:37:57 1999
#17
Pyrene-dlO
Concen: 0.00 ng/uL
Expected RT: 34.25 min
Lab File: ENG1317.D
Acq: 18 May 99 3:50 pm
Tgt Ion: 212
Ion Exp Ratio
212 100
106 34.0
0 0.0
0 0.0
HP 5989B
Page 10
-------
Abundance
30000J
20000:
10000 .
lime - - >
TIC: ENG1317.D
33.50 34.00 34.50 35.00
Abundance Ion 202.00 (201.70 to 202770) : ENG
Ion 101.00 (100.70 to 101.70): ENG
8000 j
6000 :
4000:
2000:
o :J
rime-->
1—i—I—i—i—i—i—I—i—i—i—i—|—i—i—i—i—1—i—i—i—r
33.50 34.00 34.50 35.00
#18
Pyrene
Concen: 0.00 ng/uL
Expected RT: 34.30 min
Lab File: ENG1317.D
Acg: 18 May 99 3:50 pm
Tgt Ion: 202
Ion Exp Ratio
202 100
101 32.0
0 0.0
0 0.0
Abundance
30000 :
20000 :
10000 :
0.
JLj
TIC: ENG1317.E)
Time--> 33.50 34 00 34.50 35.00 35.50
Abundance
4000.
2000.
0-
ion 244.
Ion 122.
00 (243.70 to 244.70) : ENG
00 (121.70 to 122.70): ENG
Iime--> 33. 50 ' '34! do' 's^is'o' 'ssio'o' 'ssis'o'
ENGl.il /.u PKb.M Wed May 26 13:38:00 1999
#19
p-Terphenyl-
Concen: 0.00
Expected RT:
Lab File:
Acq: 18 May
Tgt Ion: 244
Ion Exp
244 100
122 27
0 0
0 0
d!4
ng/uL
34.57 min
ENG1317.D
99 3:50 pm
Ratio
.0
.0
.0
00037.-5
HP 598 9B Page
-------
Abundance
15000 J
10000 :
5000 J
0
Time - - >
Abundance
4000 _
i
2000 .
0
[Time-->
.'W^'*'^*^^™*'
TIC: ENG1317.D
38.
00 38.50 39 00 39.50
Ion 240.00 (239.70 to 240.70): ENG
Ion 120.00 (119.70 to 120.70): ENG
^*_^^^v>>^•*^r*^M^p^^
'ss.oo' Vs.s'o' '39 oo ' '39! so'
#20
Benzo(a)anthracene-d!2
Concen: 0.00 ng/uL
Expected RT: 38.87 min
Lab File: ENG1317.D
Acq: 18 May 99 3:50 pm
Tgt Ion: 240
Ion Exp Ratio
240 100
120 30.0
0 0.0
0 0.0
Abundance TIC: ENG1317.D
15000 :
10000 :
5000 :
o •
Time - - >
Abundance
4000 :
3000 :
2000 :
1000 :
o -
Time - - >
/\ . ^ /^X - /~^V
L^v^ •>— __ TXW^- • ~/~Vv- ^, .. -N^-J^
'ss.oo' 's'sls'o' 's'gio'o' 's'glso' '
Ion 228.00 (227 .70 to 228.70): ENG
Ion 114.00 (113.70 to 114.70): ENG
A r^
0^yv\AA^J V_^yx^
111" i i i i i i i i i -1" i — i — i— r ~r ' i — r i — i T — i
38.00 38i50 39100 39150
ENGlJ±/.JJ F£b.M wea May 2b 13: 38: 04 1999
#21
Benzo(a)anthracene
Concen: 0.00 ng/uL
Expected RT: 38.98 min
Lab File: ENG1317.D
Acq: 18 May 99 3:50 pm
Tgt Ion: 228
Ion Exp Ratio
228 100
114 25.0
0 0.0
0 0.0
HP 5989B
Page 12
-------
Abundance
15000.
10000 J
5000.
0 "
1*1 ri
TIC: ENG1317.D
rime--> 38.oo' Ysls'o' Ysio'o' Ysls'o' Voio'o'
Abundance
4000 -
2000 .
0.
Time--> 3
Ic
Ic
>n 240.00 (239.70 to 240.70): ENG
>n 120.00 (119.70 to 120.70): ENG
v^V'*~*'v'v-'^*vM-'''""'*V'>*^
s.o'o' Ysls'o' '39 loo' 's'gls'o' '40 loo'
1 #22
Chrysene-dl2
Concen: 0.00 ng/uL
Expected RT: 39.03 min
Lab File: ENG1317.D
Acg: 18 May 99 3:50 pm
Tgt Ion: 240
Ion Exp Ratio
240 100
120 30.0
0 0.0
0 0.0
ENG
Abundance
10000 .
5000 .
0
Time-->
Abundance
4000 :
3000.
2000.
1000.
0-
rime - - >
TIC: ENG1317.D
Yslso' 39 loo' '39! BO' '40 loo'
Ion 228.00 (227.70 to 228.70): ENG
Ion 114.00 (113.70 to 114.'70): ENG
^J ^-vyVvAy^\VfcAJ V^^^yNv-sr^^/s^
, . A-/V_
'sal so' '39 loo' 'sgls'o' '40 loo"
1J17.D PES.M Wea May 26 1J:38:OV 1999
#23
Chrysene(CCC)
Concen: 0.00 ng/uL
Expected RT: 39.16 min
Lab File: ENG1317.D
Acq: 18 May 99 3:50 pm
Tgt Ion: 228
Ion Exp Ratio
228 100
114 25.0
0 0.0
0 0.0
HP 5989B
Page 13
-------
Abundance
15000 J
10000 J
5000 J
0-
Iime-->
Abundance
4000-
2000-
0
Time-->
TIC: ENG131V.D
rv^vMW—xl*"-'**^'— ^ ^""^""-v— -\-f-vV* •'•• >••»'-
ii ••..'v-v .. -1
1 1 1
45
r~ i i i i i i i i i i i i i ' '
00 45.50 46.00 46.50
Ion 264.00 (263.70 to 264. VO): 1SNU
Ion 132.00 (131.70 to 132.70): ENG
•^A/t*_ri~^t~>f^l*/v^^
1 — i — i — i 1 — i — i — i — 1 — i — i — i — i — " • i i i i | i i i i
45.00 45.50 46 00 46.50
#24
Benzo(b)fluoranthene-dl2
Concen: 0.00 ng/uL
Expected RT: 45.87 min
Lab File: ENG1317.D
Acq: 18 May 99 3:50 pm
Tgt Ion: 264
Ion Exp Ratio
264 100
132 30.0
0 0.0
0 0.0
ENG
Abundance
15000 J
10000 J
5000 J
n
TIC: ENG1317.D
*~*~^~~J
Time--> 45.00 45 50 46 00 46.50 47.00
Abundance
8000 :
6000 :
4000 -
2000 .
0.
Ion 252.00 (251.70 to 252.70): UIMU
Ion 126.00 (125.70 to 126.70): ENG
(rime--> '45 oV Vsls'o' Ye 1 00^4 el so ' YvloY
1317. D PES.M wea way 26 i3:^«:io iyyy
#25
Benzo(b)fluoranthene
Concen: 0.00 ng/uL
Expected RT: 46.07 min
Lab File: ENG1317.D
Acq: 18 May 99 3:50 pm
Tgt Ion: 252
Ion Exp Ratio
252 100
126 25.0
0 0.0
0 0.0
HP 5989B
Page 14
-------
Abundance
15000 J
10000 J
5000.
0 "
rime--> 4
Abundance
4000.
2000 .
0 J
Time--> 4
TIC: ENG1317.D
]
Slo'o' Vsls'o' '46lo'o' '46! SO' '47io'o'
Ion 264.00 (263.70 to 264.70): ENG
Ion 132.00 (131.70 to 132.70): ENG
p"nta^^J">~V^^^^*^'•vVv~~H"v^
s.o'o' '45! so' Vsido' Veis'o' ^'vio'o'
#26
Benzo(k)fluoranthene-dl2
Concen: 0.00 ng/uL
Expected RT: 46.07 min
Lab File: ENG1317.D
Acq: 18 May 99 3:50 pm
Tgt Ion: 264
Ion Exp Ratio
264 100
132 30.0
0 0.0
0 0.0
ENG
Abundance
15000 :
10000 J
5000 J
0 '
Time-->
Abundance
8000 :
6000.
4000 .
2000 .
0.
rime-->
TIC: ENG1317.D
^sls'o' '46lo'o' ^'eis'o' '47! do' ' ' '
Ion 252.00 (251.70 to 252.70): ENG
Ion 126.00 (125.70 to 126.70): ENG
Vsls'o' '46 loo Veis'o' '47 loo' ' ' '
1317. D PES.M Wed May 2b 13:38:13 1999
#27
Benzo(k)fluoranthene
Concen: 0.00 ng/uL
Expected RT: 46.23 min
Lab File: ENG1317.D
Acq: 18 May 99 3:50 pm
Tgt Ion: 252
Ion Exp Ratio
252 100
126 25.0
0 0.0
0 0.0
HP 5989B
Page 15
-------
Abundance
15000.
10000.
5000.
0
• TIC: ENG1317.D
Time--> 471 SO' Vsldo' Vsis'o' Vgldo' Vsls'o'
Abundance
4000.
2000.
.;
Time - - >
Ion 264.00 (263.70 to 264.70): ENG
Ion 132.00 (131.70 to 132.70): ENG
^^M^ji^JV^I^^^^^^t^^^
47ls'o' Veldo' 481 SO' 49loo' 49l5o'
#28
Ben-
Com
Exp<
Lab
Acq
Tgt
Ion
264
132
0
0
Benzo(a)pyrene-d!2
Concen: 0.00 ng/uL
Expected RT: 48.54 min
-le: ENG1317.D
Acq: 18 May 99 3:50 pm
>n: 264
Exp Ratio
100
30.0
0.0
0.0
ENG
Abundance
15000.
10000.
5000^
0.
TIC: ENG1317.D
Time--> 48.00 49.00 50.00
Abundance
6000 .
4000.
2000 .
0-
Time-->
Ion 252.00 (251.70 to 252.70): ENG
Ion 126.00 (125.70 to 126.70): ENG
'V^«^V»~^>»VV^^^A J % , * \J
Page 16
-------
Abundance
15000-
10000.
5000 .
0 '
rime-->60
Abundance
2000 _
1000 .
^0 .
ime - - >6 0
TIC: ENG1317.D
06 ' ' eiloo ' ' 62loo ' ' esloo
Ion 288.00 (287.70 to 288.70): ENG
^-^TMVwwjM^^^Mpv^''^^
.00 ' ' eiloo ' ' 62loo ' ' esloo
#30
Indeno(l,2,3-cd)pyrene-dl2
Concen: 0.00 ng/uL
Expected RT: 61.48 min
Lab File: ENG1317.D
Acq: 18 May 99 3:50 pm
Tgt Ion: 288
Ion Exp Ratio
288 100
0 0.0
0 0.0
0 0.0
ENG
Abundance
15000 .
10000 .
.
5000 J
0 '
Time - - >
Abundance
3000 I
2000 :
1000 -
0.
Time-->
TIC: ENG1317.D
eiloo ' ' 62lo6 ' ' esloo
ion 276.05 (275.75 to 276.75): ENG
Ion 138.00 (137.70 to 138.70): ENG
WM<^Vw^»^VV'Vv^AA^^
eiloo ' 62loo ' ' esloo
1J1V.D PES.M Wed May 2b 13:38:20 1999
#31
Indeno (1,2,3
Concen: 0.00
Expected RT:
Lab File:
Acq: 18 May
Tgt Ion: 276
Ion Exp
276 100
138 64
0 0
0 0
-cd)pyrene
ng/uL
61.83 min
ENG1317 .D
99 3:50 pm
.05
Ratio
.0
.0
.0
OCC3
vs
S
a -
HP 5989B Page
-------
Abundance
15000.
10000.
5000.
0
Time- -> 60
Abundance
2000.
1000 -
0-
rime-->6C
' " TIC: ENG1317.D
100 61.00 62.00
Ion 292.00 (291.70 to 292.70): ENG
fU/^J^t^tf^^f^^^
.00 61.00 62.00
#32
Dibenz(a,h)anthracene-d!4
Concen: 0.00 ng/uL
Expected RT: 61.44 min
Lab File: ENG1317.D
Acq: 18 May 99 3:50 pm
Tgt Ion: 292
Ion Exp Ratio
292 • 100
0 0.0
0 0.0
0 0.0
ENG
Abundance
15000.
10000-
5000 J
0 '
rime-->
Abundance
4000 :
3000:
2000-
1000-
0.
Time - - >
TIC: ENG1317.D
eilod ' ' 62lod ' ' eslod
Ion 278.00 (277.70 to 278.70): ENG
Ion 139.00 (138.70 to 139.70): ENG
vJw*U*tW 1^:38:24 1999
#33
Dibenz(a,h)anthracene
Concen: 0.00 ng/uL
Expected RT: 61.85 min
Lab File: ENG1317.D
Acq: 18 May 99 3:50 pm
Tgt Ion: 278
Ion Exp Ratio
278 100
139 25.0
0 0.0
0 0.0
HP 5989B
Page 18
-------
Abundance
15000.
10000 .
5000.
o
Time - - >
Ai5unfa68en
2000-
1000 J
0 .
Time-->
TIC: ENG1317.D
64 od ' ' 6s!od ' ' eelod
Ion 288.00 (287.70 to 288.70): ENG
64.od ' ' eslod ' eelod
#34
Benzo(g,h,i)perylene-d!2
Concen: 0.00 ng/uL
Expected RT: 65.06 min
Lab File: ENG1317.D
Acq: 18 May 99 3:50 ptn
Tgt Ion: 288
Ion Exp Ratio
288 100
0 . 0.0
0 0.0
0 0.0
Abundance
15000 J
10000 -
5000-
0 J
TIC: ENG1317.D
>i
Time- -> 64. 00 ' ' 65!od ' ' SeloO
Abundance
3000:
2000J
1000:
o:
Time- -> 64
Ion 276.00 (275.70 to 276.70): ENG
Ion 138.00 (137.70 to 138.70): ENG
iod ' ' 6s!od ' ' 6e!od
ENGlJl/.D .Ptib.M Wea May 26 13:38:27 1939
#35
Benzo(g,h,i)perylene
Concen: 0.00 ng/uL
Expected RT: 65.44 min
Lab File: ENG1317.D
Acq: 18 May 99 3:50 pm
Tgt Ion: 276
Ion Exp Ratio
276 100
138 25.0
0 0.0
0 0.0
OOC3783
HP 5989B
Page 19
-------
ENG1318.XLS
Quantitation Report Summary
Data File
Date Analyzed:
Sample ID
Method ID
Operator
Instrument
Compounds
Naphthalene(CCC)
Acenaphthylene
Acenaphthene(CCC)
Fluorene
Phenanthrene
Anthracene
Fluoranthene(CCC)
Pyrene
Benzo(a)anthracene
Chrysene(CCC)
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Benzo(a)pyrene(CCC)
lndeno(1,2,3-cd)pyrene
Dibenz(a,h)anthracene
Benzo(g,h,i)perylene
ENG1318.D
05/18/99)
ACETONE BLANK
PES
JEMcCartney
HP 5989B
Area
0
0
0
0
5339
0
0
0
0
0
0
0
0
0
0
0
* PQL - practical quantitation limit •
Surrogate Recoveries
Compound
Naphthalene-d8
Acenaphthylene-d8
Acenaphthene-d10
Fluorene-d10
Phenanthrene-d10
Anthracene-d10
Fluoranthene-d10
Pyrene-d10
Benzo(a)anthracene-d12
Chrysene-d12
Benzo(b)fluoranthene-d12
Benzo(k)fluoranthene-d12
Benzo(a)pyrene-d12
Indeno(1,2,3-cd)pyrene-d12
Dibenz(a, h)anthracene-d1 4
Benzo(g, h, i)perylene-d1 2
Recovery Standard
Compound
2-Methlynaphthalene-d1 0
p-Terphenyl-d14
Compiled by:
Reviewed by:
Cone.
(ng/uL)
0.000
0.000
0.000
0.000 _,
0.010
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Cone. (ng/uL)
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
Concentration (ng/uL)
0.00
0.00
S
*•
PQL*
(ng/uL)
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
, s
/rl f&PZ&t^l *>/ I 7 fy^
^^y-i~£-Ggue&~rojij <=^\ mo |q
Cone.
(ng/sample)
0.0
0.0
0.0
0.0
9.7
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
% Recovery
0.00
0.00
L_ 0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
% Recovery
0.00
0.00
Cone, (ng/sample)
w/ Surr. correction
0.0
0.0
0.0
0.0
9.7
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
A/^fyy- •
-------
Quantitation Report
Data File :
Acq On :
Sample :
Misc :
Quant Time:
Method
Title
Last Update
Response via
C:\HPCHEM\1\DATA\9919\ENG1318.D
18 May 99 5:06 pm
ACETONE BLANK
May 26 13:42 1999
: C:\HPCHEM\1\METHODS\PES.M
Vial: 6
Operator: JEMcCartney
Inst : HP 5989B
Multiplr: 1.00
Mon May 24 16:23:27 1999
Multiple Level Calibration
Internal Standards
R.T. Qlon Response Cone Units Dev(Min)
1)
2 , 2-Dif luorobiphenyl
24
.60
190
1267594
System Monitoring Compounds
2)
4)
5)
7)
9)
11)
13)
15)
17)
19)
20)
22)
24)
26)
28)
30)
32)
34)
Naphthalene-d8
2-Methlynaphthalene-dlO
Acenaphthylene-d8
Acenaphthene-dlO
Fluorene-dlO
Phenant hr ene - dl 0
Ant hr acene - dl 0
Fluoranthene-dlO
Pyrene-dlO
p-Terphenyl-dl4
Benzo (a) anthracene-d!2
Chrysene-dl2
Benzo (b) f Iuoranthene-dl2
Benzo (k) f luoranthene -d!2
Benzo (a) pyrene-d!2
Indenod, 2, 3 -cd) pyrene -d!2
Dibenz (a,h) anthracene -d!4
Benzo (g, h, i) perylene-d!2
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
136
152
160
164
176
188
188
212
212
244
240
240
264
264
264
288
292
288
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Target Compounds
3)
6)
8)
10)
12)
14)
16)
18)
21)
23)
25)
27)
29)
31)
33)
35)
Naphthalene (CCC)
Acenaphthylene
Acenaphthene (CCC)
Fluorene
Phenanthrene
Anthracene
Fluoranthene (CCC)
Pyrene
Benzo (a) anthracene
Chrysene(CCC)
Benzo (b) f luoranthene
Benzo (k) f luoranthene
Benzo (a) pyrene (CCC)
Indeno ( 1 , 2 , 3 - cd) pyrene
Dibenz (a, h) anthracene
Benzo (g, h, i)perylene
0
0
0
0
30
0
0
0
0
0
0
0
0
0
0
0
.00
.00
.00
.00
.50
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
128
152
154
166
178
178
202
202
228
228
252
252
252
276
278
276
5339
5.00 ng/uL
0
.02
%Recovery
0.00 ng/uL
0.00 ng/uL
0.00 ng/uL
0.00 ng/uL
0.00 ng/uL
0.00 ng/uL
0.00 ng/uL
0.00 ng/uL
0.00 ng/uL
0.00 ng/uL
0.00 ng/uL
0.00 ng/uL
0.00 ng/uL
0.00 ng/uL
0.00 ng/uL
0.00 ng/uL
0.00 ng/uL
0.00 ng/uL
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.00%
.00%
.00%
.00%
.00%
.00%
.00%
.00%
.00%
.00%
.00%
.00%
.00%
.00%
.00%
.00%
.00%
.00%
Qvalue
Not Detected
Not Detected
Not Detected
Not Detected
0.01 ng/uL#
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
56
(#) = qualifier out of range (m) = manual integration
ENG1318.D PES.M Wed May 26 13:43:24 1999 HP 5989B
Page 1
-------
Quantitation Report
Data File : C:\HPCHEM\1\DATA\9919\ENG1318.D
Acq On : 18 May 99 5:06 pm
Sample : ACETONE BLANK
Misc :
Quant Time: May 26 13:42 1999
Method
Title
Last Update
Response via
C:\HPCHEM\1\METHODS\PES.M
Mon May 24 16:23:27 1999
Multiple Level Calibration
Vial: 6
Operator: JEMcCartney
Inst : HP 5989B
Multiplr: 1.00
Abundance
1000000 J
900000 .
800000.
700000 J
600000 .
500000 J
400000 J
300000 .
200000 '.
100000 '.
Time-->
TIC: ENG1318.D
12
20.00 30.00 40.00 50.00 60.00
OOC37SS
ENG1318.D PES.M
Wed May 26 13:43:29 1999
HP 5989B
Page 2
-------
Abundance
10000.
5000.
0 '
Time-->21
Abundance
4000 .
2000 '.
0 -
Time-->21
TIC: ENG1318.D
^^-^^^^^^^^v^j/\^^-^^^^
lo'o' '21! SO' ^izlo'o' '22l5o' '2:3 loo'
Ion 136.00 (135.70 to 136.70): ENG
Ion 68.00 (67.70 to 68.70): ENG13
A A
t^j~fW*^j(J^uS«*d Vv/^v/ vAj^^^A^uvAv^^r^^^,,^
.00' ^ils'o' '22! do' '22150' '23 loo'
#2
Naphthalene-d8
Concen: 0.00 ng/uL
Expected RT: 22.23 min
Lab File: ENG1318.D
Acq: 18 May 99 5:06 pm
Tgt Ion: 136
Ion Exp Ratio
136 100
68 20.0
0 0.0
0 0.0
ENC,
Abundance
10000 .
5000.
0
Time-->
Abundance
3000.
2000.
1000 .
0.
Time-->
TIC: ENG1318.D
.^v~'N*V«--s^_^~w^^/Avu---%~XVv>^^
^ils'o' '22 lo'o' '22! so' '23 lo'o'
Ion 128.00 (127.70 to 128.70): ENG
Ion 127.00 (126.70 to 127.70): ENG
2l! 50 22 Ido 22! 50 23 lo'o '
1318. D PEb.M wea May 25 13:43:33 1999
#3
Naphthalene(CCC)
Concen: 0.00 ng/uL
Expected RT: 22.28 min
Lab File: ENG1318.D
Acq: 18 May 99 5:06 pm
Tgt Ion: 128
Ion Exp Ratio
128 100
127 10.0
0 0.0
0 0.0
HP 5989B
Page 3
-------
Abundance
400000 :
300000:
200000 :
100000 :
o :
Time-->
Abundance
3000.
2000-
1000 .
0
Time-->
TIC: ENG1318.D
)
23100 23.
Ion 152.00
1 1 1 1 1 1 1 1 '
23.00 23
SO' '24 100 24l 50 25l6o
(151.70 to
— i — i — i — i — i — i — i — i
50 24100
152.70) : ENG
24l50' '251 00
#4
2-Methlynaphthalene-dlO
Concen: 0.00 ng/uL
Expected RT: 23.96 min
Lab File: ENG1318.D
Acq: 18 May 99 5:06 pm
Tgt Ion: 152
Ion Exp Ratio
152 100
0 0.0
0 0.0
0 0.0
ENG
^unm^e
eooo:
4000 :
2000 :
0
rime-->
Abundance
3000.
2000.
1000.
0
Time - - >
1
'1C: EUG1318.D
'25150' '26 1 do' Vels'o' 27 1 do' ' ' '
Ion 160.00 (159.70 to 160.70): ENG
'25150' Veldo' '26! so' '2'?! do' ' ' '
131B.D PES.M Wed May ~2b 13:43 :3b 1999
#5
Acenaphthy1ene-d8
Concen: 0.00 ng/uL
Expected RT: 26.29 rain
Lab File: ENG1318.D
Acq: 18 May 99 5:06 pm
Tgt Ion: 160
Ion Exp Ratio
160 100
0 0.0
0 0.0
0 0.0
OOG37cS
HP 5989B
Page 4
-------
^^iBftS6
6000 :
4000 :
2000 :
0 '
rime-->
Abundance
3000.
2000J
1000.
0
Time-->
FIG: ENG1318.D
t
'25150 2 IS ioO 26150 27ldo '
Ion 152 .00
Ion 153.00
(151.70 to 152.70): ENG
(152.70 to 153.70) : ENG
'25150' Velo'o' Ve! so' '27lo'o' ' ' '
#6
Acenaphthy1ene
Concen: 0.00 ng/uL
Expected RT: 26.32 min
Lab File: ENG1318.D
Acq: 18 May 99 5:0 6 pm
Tgt Ion: 152
Ion Exp Ratio
152 100
153 15.0
0 0.0
0 0.0
ENG
Sundance
8000-
6000 :
4000 :
2000 :
0 "
Time-->25
TIC: ENG1318.D
ISO' '26 loo' '26! SO' '27lo'o' ^vls'o'
Abundancelon 164.00 (163.70 to 164.70): ENG
3000 J
2000:
1000.
0
rime-->25
150' '26ldo' ^els'o' '2?! DO' '27l50'
ri.ii8.D PES.M wea May zb i^:4^:^y iyyy
#7
Acenaphthene-dl0
Concen: 0.00 ng/uL
Expected RT: 26.71 min
Lab File: ENG1318.D
Acq: 18 May 99 5:06 pm
Tgt Ion: 164
Ion Exp Ratio
164 100
0 0.0
0 0.0
0 0.0
HP 5989B
Page 5
-------
Abundance TIC: ENG1318.D
8000 j
6000 :
4000 :
2000 .
0 _
— rw J«— ^~ — r~~~*~~r~~*r'
Time--> 26iOO 26.50 27:00 27150
Abundancelon 154.00 (153.70 to 154.70): ENG
3000.
2000 '.
\
1000 .
0 .
rime-->
Ion
153.00 (152.70 to 153.70): ENG
Veldo VelsV '27! do' '27150' ' ' '
#8
Acenaphthene(CCC)
Concen: 0.00 ng/uL
Expected RT: 26.79 min
Lab File: ENG1318.D
Acq: 18 May 99 5:06 pm
Tgt Ion: 154
Ion Fxp Ratio
154 100
153 86.8
0 0.0
0 0.0
ENG
Abundance
8000-
6000 J
4000 :
2000.
0 .
TIC: ENG1318.D
Time--> 271 do' '27 [50' '28 Ido' Vsis'o' Vgldo'
Abundance
3000 1
2000:
1000 J
0.
Ion 176.00 (175.70 to 176.70): ENG
Time--> 27! 00 27l50 28100 2 IB i 50 29ido
1318. D PES.M Wed May 26 13:43:43 1999
#9
Fluorene-dlO
Concen: 0.00 ng/uL
Expected RT: 28.00 min
Lab File: ENG1318.D
Acq: 18 May 99 5:06 pm
Tgt Ion: 176
Ion Exp Ratio
176 100
0 0.0
0 0.0
0 0.0
HP 5989B
Page 6
-------
Abundance
8000.
6000.
4000 :
2000:
0 '
rime-->
Abundance
4000 .
3000.
2000.
1000 .
0
Time-->
TIC: ENG1318.D
27 loo' '27l 50 VsloV 28!s'o' Vgioo'
Ion 166.00 (165.70 to 166.70): ENG
Ion 165.00 (164.70 to 165.70): ENG
crr^rri^iil
27 loo' '271501 '28 loo' ^sisV VgloV
#10
Fluorene
Concen: 0.00 ng/uL
Expected RT: 28.08 min
Lab File: ENG1318.D
Acg: 18 May 99 5:06 pm
Tgt Ion: 166
Ion Exp Ratio
166 100
165 76.2
0 0.0
0 0.0
ENG
Abundance
10000 .
•
5000 .
0 J
TIC: ENGl3l8.t>
rime--> ' '29 1 so' Vo.o'o' Vols'o' Yilo'o' '
Abundance
4000 .
3000 .
2000.
1000.
o:
Ion 188.00 (187.70 to 188.70): ENG
Ion 94.00 (93.70 to 94.70): ENG13
Iime--> ' '29! SO' 30.o'o' Yols'o' 'silo'o' ' ' '
1J18.D PKS.M Wed May 2fe 1J:43:46 1999
#11
Phenanthrene-dl0
Concen: 0.00 ng/uL
Expected RT: 30.43 min
Lab File: ENG1318.D
Acq: 18 May 99 5:06 pm
Tgt Ion: 188
Ion Exp Ratio
188 100
94 30.0
0 0.0
0 0.0
OeC37£l
HP 5989B
Page 7
-------
^^ess6
10000 .
5000 .
0
Time--> 3C
Abundance
6000 J
4000:
•
2000 '.
0 .
Time--> 3C
TIC: ENG1318.D
) ! 40 ' ' 30 1 45 ' ' 30 ! 5 0 ' ' 3 0 ! 55 ' ' ' '
Ion 178.00 (177.70 to 178.70): ENG
Ion 176.00 (175.70 to 176.70): ENG
30.50
/ \
_^-//- — \^v_ ^__/
)!40 ' 'sb! 45 ' 'sol 50 ' '30 IBS ' ' ' '
#12
Phenanthrene
Concen: 0.01 ng/uL
RT: 30.50 min Scan# 3088
Delta R.T. 0.01 min
Lab File: ENG1318.D
Acq: 18 May 99 5:06 pm
Tgt Ion:178 Resp:
5339
Ion Ratio
178 100
176 0.0
0 0.0
0 0.0
Lower Upper
10.1
0.0
0.0
30.1#
0.0
0.0
TIC: ENG1318.D
10000.
5000 .
I 0
Time-->
29.50 30.00 30.50
31.00
(187.TO to li
31.50
Abundance Ion 188.00
Ion 94.00 (93.70 to 94.70): ENG13
4000.
2000.
rime--> 29.50 30.00 30.50 31.00 31.50
ENG1318.D—PES.M
Wed May ^fe 13:43:49 1999
#13
Anthracene-dl0
Concen: 0.00 ng/uL
Expected RT: 30.57 min
Lab File: ENG1318.D
Acq: 18 May 99 5:06 pm
Tgt Ion: 188
Ion Exp Ratio
188 100
94 30.0
0 0.0
0 0.0
occ
HP 5989B
Page 8
-------
Abu:
Time-->29.50 SOiOO 30.50 31.00 31.50
TIC: ENG1318.D
10000 .
5000.
Abundance Ion 178.00 (177.70 to 178.70): ENG
60001Ion 176.00 (175.70 to 176.70): ENG
4000 .
2000 .
Time-->29.50 30.00 30l50 31.00 31.50
#14
Anthracene
Concen: 0.00 ng/uL
Expected RT: 30.62 min
Lab File: ENG1318.D
Acq: 18 May 99 5:06 pm
Tgt Ion: 178
Ion Exp Ratio
178 100
176 20.0
0 0.0
0 0.0
ENG
Sundance TIC: ENG1318.D
800000 :
600000 J
400000 :
200000:
0 '
Time-->
Abundance
4000 :
3000 .
2000.
1000-
0
Time-->
1
32 so' 'aiaio'o' 'ssls'o' 34!o'o' 's^ls'o'
ion 212.00 (211.70 to 212.70): ENG
Ion 106.00 (105.70 to 106.70): ENG
^v/A>v-wwv\r-' X^^^V^^AK^VVrSM/W
32150 33!00 33150 34!6o 34150
ri3i8.D PES.M wea May 26 13:43:52 iyyy
#15
Fluoranthene-dlO
Concen: 0.00 ng/uL
Expected RT: 33.57 min
Lab File: ENG1318.D
Acq: 18 May 99 5:06 pm
Tgt Ion: 212
Ion Exp Ratio
212 100
106 30.0
0 0.0
0 0.0
OCC37S3
HP 5989B Page 9
-------
Abundance
800000 :
600000 :
400000 .
200000 .
o:
Time--> 3
Abundance
4000.
3000 :
2000 :
1000 :
0 '
rime--> 3
TIC: ENG1318.D
2.50' '33 loo' '33l5o' 's^io'o' 's^ls'o'
Ion 202.00 (201.70 to 202.70): ENG
Ion 101.00 (100.70 to 101.70): ENG
fc^fc^ZK^
2.501 'sslo'o' '33! 50 '34lo'o' 34] 50*
#16
Fluoranthene(CCC)
Concen-. 0.00 ng/uL
Expected RT: 33.62 min
Lab File: ENG1318.D
Acq: 18 May 99 5:06 pm
Tgt Ion: 202
Ion Exp Ratio
202 100
101 27.0
0 0.0
0 0.0
Abundance
15000 :
10000 :
5000 J
0
Time -->
Abundance
4000 ;
3000 :
2000 ;
1000 .
0 .
Time-->
TIC: ENG1318.D
'33! so' '34 loo' 'aiiso' '35 loo' ' ' '
Ion 212.00 (211.70 to 212.70): ENG
Ion 106.00 (105.70 to 106.70): ENG
^^v\**j^rS^swT~Tl^^
1 > i i 1 i i i i l i i i i i i p1 1 i-"i —i— i — i — i — i
33150 34100 .34150 3sloO
ENG-UJ.8.1J Wib.M Wed May 26 U:43:bfc 1999
#17
Pyrene-dlO
Concen.- 0.00 ng/uL
Expected RT: 34.25 min
Lab File: ENG1318.D
Acq: 18 May 99 5:06 pm
Tgt Ion: 212
Ion Exp Ratio
212 100
106 34.0
0 0.0
0 0.0
OCC3794
HP 5989B
Page 10
-------
Abundance
15000 :
10000 J
5000 :
0
Time - - >
Abundance
4000 .
3000 .
2000 .
1000.
0 .
Time-->
TIC: ENG1318.D
33.50 34.00 34.50 35 00
Ion 202.00 (201.70 to 202.70): ENG
Ion 101.00 (100.70 to 101.70): ENG
/Wv^yvftvs^^W^
'33! so' '34 loo' '34! so' '35! do' ' ' '
#18
Pyrene
Concen: 0.00 ng/uL
Expected RT: 34.30 min
Lab File: ENG1318.D
Acq: 18 May 99 5:06 pm
Tgt Ion: 202
Ion Exp Ratio
202 100
101 32.0
0 0.0
0 0.0
ENG
Abundance
15000 :
10000 :
sooo :
0 '
Time-->
Abundance
4000 .,
3000 :
2000.
1000-
0
Time-->
~i**~-*-~+J V— «-^-
TIC: ENG1318.D
^^r^+S^mfr ^^V\J* N^l^^V/^^.^«*^N^V»^^a^|^VF^*^^J**^^*N*^^*/
33! so' '34! do' '34! so' 'sslo'o' 's's! so'
Ion 244.00 (243.70 to 244.70): ENG
Ion 122.00 (121.70 to 122.70): ENG
«^+*^
33! so' '34! do' '34! so' 'ssio'o' 'ssl so'
1318. D PES.M Wea May 26 13:43:by 1999
p-Terphenyl-d!4
Concen: 0.00 ng/uL
Expected RT: 34.57 min
Lab File: ENG1318.D
Acq: 18 May 99 5:06 pm
Tgt Ion: 244
Ion Exp Ratio
244 100
122 27.0
0 0.0
0 0.0
OCC5755
HP 5989B Page 11
-------
Abundance
15000 J
10000 J
5000 :
n
•/v^-/~~^X^
u - — i — i — i —
Time--> 38
Abundance
4000 .
2000 .
0 .
Ion 2
Ion 1
' 1 1 T
Time--> 38
TIC: BNG1318.D
— P i i * i i i i i i * § i i i i i i i i
00 38.50 39.00 39.50
40.00 (239.70 to 240.70): ENG
20.00 (119.70 to 120.70): ENG
1 1 1 1 -rill i i i i i i i i i I
00 38.50 39.00 39.50
#20
Benzo(a)anthracene-d!2
Concen: 0.00 ng/uL
Expected RT: 38.87 tnin
Lab File: ENG1318.D
Acq: 18 May 99 5:06 pra
Tgt Ion: 240
Ion Exp Ratio
240 100
120 30.0
0 0.0
0 0.0
ENG
Abundance
15000 :
10000 :
5000 J
o
s^~^w.
TIC: ENGl3l8.:D
rime--> 38 loo 3s!50 s'gloo 39! so
Abundance
3000 :
2000:
1000 :
o:
Ion \
Ion :
228.00 (227.70 to 228.70): ENG
L14.00 (113.70 to 114.70): ENG
^-^^w-^-^ jL-^-^^vyV^^^.^^. ,,_,_
rime--> ' 'SB. o'o ' Ysis'o' Ygido' 'sgis'o' '
1318. D PES.M Wea May 26 13:44:U2 1999
#21
Benzo(a)anthracene
Concen: 0.00 ng/uL
Expected RT: 38.98 min
Lab File: ENG1318.D
Acq: 18 May 99 5:06 pm
Tgt Ion: 228
Ion Exp Ratio
228 100
114 25.0
0 0.0
0 0.0
HP 5989B
Page 12
-------
Abundance
15000 J
10000 :
5000.
0
Iime--> 3
Abundance
4000 .
2000.
0 .
Time--> 3
TIC: ENG1318.D
Kvw
8.00 38!50 39loO 39!sO 4oloO
Ion 240.00 (239.70 to 240.70): ENG
Ion 120.00 (119.70 to 120.70): ENG
^^^^^^^"^^^
8.00' Ysls'o' '39! do' Ygis'o' '40 loo'
#22
Chrysene-dl2
Concen: 0.00 ng/uL
Expected RT: 39.03 min
Lab File: ENG1318.D
Acq: 18 May 99 5:06 pm
Tgt Ion: 240
Ion Exp Ratio
240 100
120 30.0
0 0.0
0 0.0
ENG
Abundance
10000 .
5000 '.
0 .
TIC: ENG1318.D
.*•»• .'- W^^V^X ^Vvv^^^^^"^ ^^^^~^*********>**vilf*ltf^^*s*^^
Time--> ' ' Vsiso' 'sblo'o' Ygiso' Volo'o'
Abundance
3000 :
2000 -
1000 :
o :
rime-->
Ion 228.00 (227.70 to 228.70): ENG
Ion 114.00 (113.70 to 114.70): ENG
^ f ._ ^f^/^^^^^^^^ '*''*'
Ysls'o' '39 Ido' '391501 '4'oio'o'
1318. D PES.M Wed May 26 13:44:05 1999
#23
Chrysene(CCC)
Concen: 0.00 ng/uL
Expected RT: 39.16 min
Lab File: ENG1318.D
Acq: 18 May 99 5:06 pm
Tgt Ion: 228
Ion Exp Ratio
228 100
114 25.0
0 0.0
0 0.0
HP 5989B
Page 13
-------
Abundance
10000.
5000 _
0 '
Pime-->
Abundance
4000-
2000 .
0
Time - - >
TIC: ENG1318.D
45.00 45.50 46.00 46.50
Ion 264.00 (263.70 to 264.70): ENG
Ion 132.00 (131.70 to 132.70): ENG
pt>yAlJV<'''v~1"V'*w-Ax-«-^^
45.00 45.50 46.00 46.50
#24
Benzo(b)fIuoranthene-dl2
Concen: 0.00 ng/uL
Expected RT: 45.87 min
Lab File: ENG1318.D
Acq: 18 May 99 5:06 pm
Tgt Ion.- 264
Ion Exp Ratio
264 100
132 30.0
0 0.0
0 0.0
Abundance
10000 .
5000 '.
0 .
TIC: ENG1318.D
Iime--> 45 00 45150 '46loO ^elso' V? ! 00
Abundance
4000.
2000.
'
0 .
Time - - >
Ion
Ion
'
252.00 (251.70 to 252.70): ENG
126.00 (125.70 to 126.70): ENG
1— A^u .moAr-^JOv VW*"--V'U>-1-"* v^^r..TJV^WWJ>--|^VJVuVAt-^W_vvJr
45.00 4Sl 50 46 !00 46lso' '47lo'o'
ENGlJia.U PKS.M Wed May 2<> 13:44:09 1999
#25
Benzo(b)fluoranthene
Concen: 0.00 ng/uL
Expected RT: 46.07 min
Lab File: ENG1318.D
Acq: 18 May 99 5:06 pm
Tgt Ion: 252
Ion Exp Ratio
252 100
126 25.0
0 0.0
0 0.0
HP 5989B
Page 14
-------
Abundance
10000.
5000 .
n
J
Time--> 45 .
Abundance
4000 .
2000 .
0 .
[ritne--> 4
Ic
Ic
TIC: ENG1318.D
"~»-wYV'v-^^J«^^^vJ^--^^Jlluw^J«^JW-|^~*••.»..^'.0^^.-1 .TJ-^U^^^U^V .„-. ... .,_ ,_
00 45.50 46 00 46.50 47.00
on 264.00 (263.70 to 264.70): ENG
Dn 132.00 (131.70 to 132.70): ENG
s.o'o' Vsis'o' Velo'o' '46! so' '47 loo'
#26
Benzo(k)fluoranthene-d!2
Concen: 0.00 ng/uL
Expected RT: 46.07 min
Lab File: ENG1318.D
Acq: 18 May 99 5:06 pm
Tgt Ion: 264
Ion Exp Ratio
264 100
132 30.0
0 0.0
0 0.0
ENG
Abundance
10000 .
5000 '.
0 '
rime-->
Abundance
4000 .
2000.
0.
rime-->
TIC: ENG1318.D
Vslso' Velo'o' Vels'o' ^vlo'o' ' ' '
Ion 252.00 (251.70 to 252.70): ENG
Ion 126.00 (125.70 to 126.70): ENG
^^^^^^^^^_^
'45!5o' Velo'o' Vels'o' ^Vio'o' ' ' '
:1318.D PES.M Wed May 26 13:44:12 1999
#27
Benzo(k)fluoranthene
Concen: 0.00 ng/uL
Expected RT: 46.23 min
Lab File: ENG1318.D
Acq: 18 May 99 5:06 pm
Tgt Ion: 252
Ion Exp Ratio
252 100
126 25.0
0 0.0
0 0.0
HP 5989B
Page 15
-------
Abundance
10000.
5000-
o
TIC: KNGJ1318.D
w -i — i — i — i — r1 i — r | i i i i i i i i | i i i i
Time--> 47:50 48.00 48 50 49.00 49
Abundance
4000.
3000.
2000J
1000 :
o :
Time -->
50 '
Ion 264.00 (263.70 to 264.70): KNG
Ion 132.00 (131.70 to 132.70): ENG
->YAAu-AA*< 48 lod ' ' 49loO ' ' 5olo6
Abundance
4000^
2000.
0-
rime-->
Ion 252.00 (251.70 to 252.70): ENG
Ion 126.00 (125.70 to 126.70): ENG
.A^^rt^v^wJ^Jvrtws•?<''>*^^^yl^~-^
48 iod ' ' 49 Io6 ' ' 50 100
ENGl^lB.D FEb.M Wed May 2fc 13:44:15 1999
#29
Benz o ( a ) py rene ( CCC )
Concen: 0.00 ng/uL
Expected RT: 48.74 min
Lab File: ENG1318.D
Acg: 18 May 99 5:06 pm
Tgt Ion: 252
Ion Exp Ratio
252 100
126 25.0
0 0.0
0 0.0
OPf-i$r^
\!*~ \* JO'^'t
HP 5989B Page
-------
Abundance
15000 .
10000 .
5000 .
0 '
Time-->60
Abundance
2000 -
1000 .
0 '.
Time-->60
TIC: ENG1318.D
if uA|V'f*"**-V>nfTV*l-V.'irv T-ifc-i If-nv 1 — 1-f-«i-'-t-riu-lrir— nJ.a'JUtl'-T-;-T-j-j , -|(LK»i.»r M_J
.00 ' ' eiloo ' ' 62loo ' ' esloo
Ion 288.00 (287.70 to 288.70): ENG
.00 ' 6llo6 ' ' 62lo6 ' ' 63lo6
#30
Indenod, 2, 3-cd)pyrene-dl2
Concen: 0.00 ng/uL
Expected RT: 61.48 tnin
Lab File: ENG1318.D
Acq: 18 May 99 5:06 pm
Tgt Ion: 288
Ion Exp Ratio
288 100
0 0.0
0 0.0
0 0.0
ENG
Abundance
15000 .
10000 .
5000.
0 -
TIC: ENG1318.D
Time--> 61 loo ' 62! 00 ' 63lo6
Abundance
3000 :
2000 J
1000 :
0 -
rime-->
ion 276.05 (275.75 to 276.75): ENG
Ion 138.00 (137.70 to 138.70): ENG
lfa»*W4Jt<>>t"^^
eiloo ' ' 62lo6 ' esloo
1318. U PES.M Wed May 2b lJ:44:iy lyyy
#31
Indeno(1,2,3-cd)pyrene
Concen-. 0.00 ng/uL
Expected RT: 61.83 min
Lab File: ENG1318.D
Acq: 18 May 99 5:06 pm
Tgt Ion: 276.05
Ion Exp Ratio
276 100
138 64.0
0 0.0
0 0.0
OCC3SO
HP 5989B
Page 17
-------
Abundance
15000 .
10000.
5000.
0 '
rime- -> 60
Abundance
2000 .
1000 1
i
0.
Time- -> 60
TIC: ENG1318.D
1 T T P - i i i i i l i i i i
.00 61.00 62 00
Ion 292.00 (291.70 to 292.70): ENG
.00 61.00 62.00
#32
Dibenz(a,h)anthracene-d!4
Concen: 0.00 ng/uL
Expected RT: 61.44 min
Lab File: ENG1318.D
Acq: 18 May 99 5:06 pm
Tgt Ion: 292
Ion Sxp Ratio
292 100
0 0.0
0 0.0
0 0.0
ENG
Abundance
15000.
10000 '.
5000.
0 .
TIC: ENG1318.D
rime--> ' 6l!o6 ' ' 62l 00 ' 63lo6
Abundance
!
3000 :
2000:
1000 :
0.
Time-->
Ion 278.00 (277.70 to 278.70): ENG
Ion 139.00 (138.70 to 139.70): ENG
*vi^*'l«TW%»^^
61 iod ' ' 62lo6 ' ' €3 iod
1318. D J?ES.M Wed May 2b 13:44:22 1399
#33
Dibenz(a,h)anthracene
Concen: 0.00 ng/uL
Expected RT: 61.85 min
Lab File: ENG1318.D
Acq: 18 May 99 5:06 pm
Tgt Ion: 278
Ion Exp Ratio
278 100
139 25.0
0 0.0
0 0.0
HP 5989B
Page 18
-------
Abundance
i ^nnn
10000 J
5000 .
0 .
Time - - >
Abundance
2000.
1000 i
0-
Time-->
TIC: ENG1318.D
64 od ' ' eslod ' ' eelod
Ion 288.00 (287.70 to 288.70): ENG
64 od ' eslod ' ' eelod
#34
Benzo(g,h,i)perylene-d!2
Concen: 0.00 ng/uL
Expected RT: 65.06 min
Lab File: ENG1318.D
Acq: 18 May 99 5:06 pm
Tgt Ion: 288
Ion Exp Ratio
288 100
0 0.0
0 0.0
0 0.0
ENG
Abundance
15000.
10000 1
5000.
0 '
rime- -> 64
Abundance
3000.
2000:
1000 J
o:
Time- -> 64
TIC: ENG1318.D
-W
!od ' ' eslod ' ' eelod
Ion 276.00 (275.70 to 276.70): ENG
Ion 138.00 (137.70 to 138.70): ENG
.00 es.oo eeloo
1J1B.D PKS.M Wed May 2b 13:44:26 1999
#35
Benzo(g,h,i)perylene
Concen: 0.00 ng/uL
Expected RT: 65.44 min
Lab File: ENG1318.D
Acq: 18 May 99 5:06 pm
Tgt Ion: 276
Ion Exp Ratio
276 100
138 25.0
0 0.0
0 0.0
HP 5989B
Page 19
-------
ENG1319.XLS
Quantitation Report Summary
Data File
Date Analyzed:
Sample ID
Method ID
Operator
Instrument
Compounds
Naphthalene(CCC)
Acenaphthylene
Acenaphthene(CCC)
Fluorene
Phenanthrene
Anthracene
Fluoranthene(CCC)
Pyrene
Benzo(a)anthracene
Chrysene(CCC)
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Benzo(a)pyrene(CCC)
lndeno(1 ,2,3-cd)pyrene
Dibenz(a,h)anthracene
Benzo(g,h,i)perylene
ENG1319.D
05/18/99)
MECL2 BLANK
PES
JEMcCartney
HP 5989B
Area
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
* PQL - practical quantitation limit
Surrogate Recoveries
Compound
Naphthalene-d8
Acenaphthylene-d8
Acenaphthene-d10
Fluorene-d10
Phenanthrene-d10
Anthracene-d10
Fluoranthene-dlO
Pyrene-d10
Benzo(a)anthracene-d12
Chrysene-d12
Benzo(b)fluoranthene-d12
Benzo(k)fluoranthene-d12
Benzo(a)pyrene-d12
lndeno(1 ,2,3-cd)pyrene-d12
Dibenz(a,h)anthracene-d14
Benzo(g,h,i)perylene-d12
Recovery Standard
Compound
2-Methlynaphthalene-d10
p-Terphenyl-d14
Compiled by: /^>
Reviewed by:
Reviewed by:
Cone.
(ng/uL)
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Cone. (ng/uL)
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
Concentration (ng/uL)
,/ ./*
0.00
0.03
PQL*
(ng/uL)
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
'0iv{ / /*? / <7'7
r^\itv>.4-^udcw>u., ^la^i°i
vj
I
Cone.
(ng/sample)
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
% Recovery
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
% Recovery
0.00
0.07
=V
Cone, (ng/sample)
w/ Surr. correction
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
-------
Quantitation Report
Data Pile :
Acq On :
Sample :
Misc :
Quant Time:
Method
Title
Last Update
Response via
C:\HPCHEM\1\DATA\9919\ENG1319.D
18 May 99 6:21 pm
MECL2 BLANK
May 24 16:55 1999
: C:\HPCHEM\1\METHODS\PES.M
Vial: 7
Operator: JEMcCartney
Inst : HP 5989B
Multiplr: 1.00
Mon May 24 16:23:27 1999
Multiple Level Calibration
Internal Standards
R.T. Qlon Response Cone Units Dev(Min)
1)
2, 2-Difluorobiphenyl
24
.60
190
1403347
System Monitoring Compounds
2)
4)
5)
7)
9)
11)
13)
15)
17)
19)
20)
22)
24)
26)
28)
30)
32)
34)
Naphthal ene - d8
2-Methlynaphthalene-dlO
Acenaphthylene-d8
Acenapht hene - dl 0
Fluorene-dlO
Phenanthrene - dl 0
Anthracene - dl 0
Fluoranthene - dl 0
Pyrene-dlO
p-Terphenyl-d!4
Benzo (a) anthracene-d!2
Chrysene-dl2
Benzo (b) f Iuoranthene-dl2
Benzo (k) f luoranthene -d!2
Benzo (a) pyrene-d!2
Indeno(l,2, 3-cd)pyrene-dl2
Dibenz (a,h) anthracene -d!4
Benzo (g, h, i) perylene-d!2
0
0
0
0
0
0
0
0
0
34
0
0
0
0
0
0
0
0
.00
.00
.00
.00
.00
.00
.00
.00
.00
.58
.00
.00
.00
.00
.00
.00
.00
.00
136
152
160
164
176
188
188
212
212
244
240
240
264
264
264
288
292
288
0
0
0
0
0
0
0
0
0
11911
0
0
0
0
0
0
0
0
Target Compounds
3)
6)
8)
10)
12)
14)
16)
18)
21)
23)
25)
27)
29)
31)
33)
35)
Naphthal ene (CCC)
Acenaphthylene
Acenaphthene (CCC)
Fluorene
Phenanthrene
Anthracene
Fluoranthene (CCC)
Pyrene
Benzo (a) anthracene
Chrysene(CCC)
Benzo (b) f luoranthene
Benzo (k) f luoranthene
Benzo (a) pyrene (CCC)
Indeno ( 1 , 2 , 3 - cd) pyrene
Dibenz (a, h) anthracene
Benzo (g, h, i) perylene
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
128
152
154
166
178
178
202
202
228
228
252
252
252
276
278
276
5.00 ng/uL
0.
02
%Recovery
0.00 ng/uL
0.00 ng/uL
0.00 ng/uL
0.00 ng/uL
0.00 ng/uL
0.00 ng/uL
0.00 ng/uL
0.00 ng/uL
0.00 ng/uL
0.03 ng/uL
0.00 ng/uL
0.00 ng/uL
0.00 ng/uL
0.00 ng/uL
0.00 ng/uL
0.00 ng/uL
0.00 ng/uL
0.00 ng/uL
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
00%
00%
00%
00%
00%
00%
00%
00%
00%
07%
00%
00%
00%
00%
00%
00%
00%
00%
Qvalue
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
000385
;r~
(#) = qualifier out of range (m) = manual integration
ENG1319.D PES.M Wed May 26 13:47:38 1999 HP 5989B
Page 1
-------
Quantitation Report
Data File : C:\HPCHEM\1\DATA\9919\ENG1319.D
Acg On : 18 May 99 6:21 pm
Sample : MECL2 BLANK
Misc :
Quant Time: May 24 16:55 1999
Method
Title
Last Update
Response via
C:\HPCHEM\1\METHODS\PES.M
Mon May 24 16:23:27 1999
Multiple Level Calibration
Vial: 7
Operator: JEMcCartney
Inst : HP 5989B
Multiplr: 1.00
Abundance
1000000.
1
900000 .
800000.
7*00000 J
600000 J
500000 1
400000 J
•
300000 J
200000 J
100000 '.
0 '
Time - - >
TIC: ENG1319.D
1
19S
' ' ' | ' " ' 1 I ' 1 1 1 1 1 1 1 1 I 1 1 1 1 1 1 1 1 | —
20.00 30.00 40.00 50.00 60.00
OCG33C-5
ENG1319.D PES.M Wed May 26 13:47:43 1999 HP 5989B Page 2
-------
Abundance
10000.
5000^
0 "
rime-->21
Abundance
4000 .
2000 '.
0 _
Time-->21
TIC: ENG1319.D
A
lo'o' '21150' '2:2! 00 ' '22l5o' '23ldo'
Ion 136.00 (135.70 to 136.70): ENG
Ion 68.00 (67.70 to 68.70): ENG13
^^J^v%AV^-w^ W^
,A rtr*"v» J* f*n / \
.00 2l!50 22100 22!so' ^slo'o'
#2
Naphthalene-d8
Concen: 0.00 ng/uL
Expected RT: 22.23 min
Lab File: ENG1319.D
Acq: 18 May 99 6:21 pm
Tgt Ion: 136
Ion Exp Ratio
136 100
68 20.0
0 0.0
0 0.0
ENG
Abundance
10000.
5000.
0 -
TIC: ENG1319.D
Time--> ^lls'o' '22lo'o' '22J501 '23lo'o'
Abundance
3000 J
2000:
1000 J
o:
Time - - >
Ion 128.00 (127.70 to 128.70): ENG
Ion 127.00 (126.70 to 127.70): ENG
r*li-iJur^\jKiiT3iT*^-iyti>1v»Titfit.--ATjl(^'\-lr,t"t)iiioU^»"l« flt^'^f^fn'ilM'Kvt
2ll50 22100 22l50' 23ldo' ' ' '
1J19.D PES.M Wed May 2b 13:47:47 1999
#3
Naphthalene(CCC)
Concen: 0.00 ng/uL
Expected RT: 22.28 min
Lab File: ENG1319.D
Acq: 18 May 99 6:21 pm
Tgt Ion: 128
Ion Exp Ratio
128 100
127 10.0
0 0.0
0 0.0
0003857
HP 5989B
Page 3
-------
Abundance
600000 J
400000 :
200000 1
o :
Time - - >
Abundance
3000 '.
2000 '.
1000 .
0 "
Time-->
TIC: UWGJ1319.D
/
'23 loo' '2:3! so' 24! do' '24! so' '25! do'
Ion 152 .00
(151.70 to
152 .70) : ENG
23!00 23150 24100 24150 25ldo
#4
2-Methlynaphthalene-dlO
Concen: 0.00 ng/uL
Expected RT: 23.96 min
Lab File: ENG1319.D
Acq: 18 May 99 6:21 pm
Tgt Ion: 152
Ion Exp Ratio
152 100
0 0.0
0 0.0
0 0.0
ENG
Abundance
6000 J
4000 J
2000 :
0 '
Time-->
Abundance
2000.
1000 J
0 "
Time-->
1
~~*~~~^ — i^-r ._..„.
"1C: ENG1319.D
'25! so' '26 loo' '26! so' '27! do' ' ' '
Ion 160.00 (159.70 to 160.70): ENG
^sls'o' 26 ! do' '215 i so' ^Vlo'o' ' ' '
i^iy.D PES.M wed May 26 i3:47:t>u iyyy
#5
Acenaphthy1ene-d8
Concen: 0.00 ng/uL
Expected RT: 26.29 min
Lab File: ENG1319.D
Acq: 18 May 99 6:21 pm
Tgt Ion: 160
Ion Exp Ratio
160 100
0 0.0
0 0.0
0 0.0
OC03803
HP 5989B
Page 4
-------
Abundance
6000 :
4000:
2000:
0 '
Time-->
Abundance
3000 J
2000 -
1000 J
0 '
Time-->
*••• i i^j^jv^-,^ .
TIC: ENG1319.D
^sis'o' '26! do' Vels'o' '2? loo' ' ' '
Ion 152.00
Ion 153.00
(151.70 to 152.70): ENG
(152.70 to 153.70) : ENG
A
'251 SO' '26 loo' VelsV '2?1 do' ' ' '
#6
Acenaphthylene
Concen: 0.00 ng/uL
Expected RT: 26.32 min
Lab File: ENG1319.D
Acq: 18 May 99 6:21 pm
Tgt Ion: 152
Ion Exp Ratio
152 100
153 15.0
0 0.0
0 0.0
Abundance
6000 .
4000 :
2000 .
0 .
TIC: ENG1319.D
Time-->25l50 2(6 1 00 26150 2?! 00 27150'
Abundance
3000 -
2000 :
1000 1
0 J
Ion 164.00 (163.70 to 164.70): ENG
Time-->25i50 26ldo 26l50 27! 00 27150
r-LJiy.D PES.M Wed May 2b 1J:47:S3 1999
#7
Acenaphthene-dlO
Concen: 0.00 ng/uL
Expected RT-. 26.71 min
Lab File: ENG1319.D
Acq: 18 May 99 6:21 pm
Tgt Ion.- 164
Ion Exp Ratio
164 100
0 0.0
0 0.0
0 0.0
OCC38S3
HP 5989B
Page 5
-------
Abundance
6000 :
4000 :
2000 :
0 1
Time - - >
Abundance
3000 1
2000 J
1000 .
0
Time-->
TIC: ENG1319.D
—I 1 1 1 p [III] ill i i i i 1 i i "1 i |
26.00 26.50 27 00 27.50
Ion 154.00 (153.70 to 154.70): ENG
Ion 153.00 (152.70 to 153.70): ENG
H — i —
i — i — i — i — i — i — : — ] — i — i — i — i 1 — i — r t i i i |
26 00 26.50 27.00 27.50
#8
Acenaphthene(CCC)
Concen: 0.00 ng/uL
Expected RT: 26.79 min
Lab File: ENG1319.D
Acq: 18 May 99 6:21 pm
Tgt Ion: 154
Ion Exp Ratio
154 100
153 86.8
0 0.0
0 0.0
ENG
Abundance
8000.
6000 J
4000:
2000:
0 '
rime-->
Abundance
3000 ^
2000.
1000.
0
Time-->
TIC: ENG1319.D
^ —
v_^_^^w — —
27.00 27.50 28.00 28.50 29.00
Ion 176.00 (175.70 to 176.70): ENG
h — i 1 — i — i — i — i — i — i — i — i — | — i — i — i — i — 1 — i — i — r T-I ' i "i
27.00 27.50 28.00 28.50 29.00
1319.D PES.M wed way 2b U:4V:bb iyyy
#9
Fluorene-dIO
Concen: 0.00 ng/uL
Expected RT: 28.00 min
Lab File: ENG1319.D
Acq: 18 May 99 6:21 pm
Tgt Ion: 176
Ion Exp Ratio
176 100
0 0.0
0 0.0
0 0.0
HP 5989B
0003310
Page 6
-------
Abundance
8000 J
6000.
4000.
2000-
0-
Time-->
Abundance
3000:
2000 :
1000 :
0 .
Time-->
TIC: EMG1319.D
27io'o' '271.50 '28 Ido' Vsis'o' Vglo'o'
Ion 166.00 (165.70 to 166.70): ENG
Ion 165.00 (164.70 to 165.70): ENG
c^rrrrirl^lll
27 loo' '27!50' VsloV Vslso' Vgldo'
#10
Fluorene
Concen: 0.00 ng/uL
Expected RT: 28.08 min
Lab File: ENG1319.D
Acq: 18 May 99 6:21 pm
Tgt Ion: 166
Ion Exp Ratio
166 100
165 76.2
0 0.0
0 0.0
ENG
Abundance
10000 .
5000 '.
0 .
TIC: ENG1319.D
Time--> 291 50 30 00 's'ois'o' 3lloO '
Abundance
4000 .
3000 J
2000.
1000.
0 .
Ion 188.00 (187.70 to 188.70): ENG
Ion 94.00 (93.70 to 94.70): ENG13
Time--> '29! SO* Yo.ob' 'sbls'o' Vllo'o' ' ' '
1319 .D PEy.M Wed May 2b 13:48:OU 1999
#11
Phenanthrene-dl0
Concen: 0.00 ng/uL
Expected RT: 30.43 min
Lab File: ENG1319.D
Acq: 18 May 99 6:21 pm
Tgt Ion: 188
Ion Exp Ratio
188 100
94 30.0
0 0.0
0 0.0
OC03SI1
HP 5989B
Page 7
-------
Abundance
10000 .
5000 .
Time - - >
TIC: ENG1319.D
29150
-i—i—|—i—i
30.00
30.50 31.00
T
Abundancelon 178.00 (177.70 to 178.70): ENG
lion 176.00 (175.70 to 176.70): ENG
4000 :
3000 :
2000:
1000:
Time-->
-i—i—i—i—i
29.50
i—i—i—i—i
30.00
30.50 31.00
#12
Phenanthrene
Concen: 0.00 ng/uL
Expected RT: 30.49 min
Lab File: ENG1319.D
Acq: 18 May 99 6:21 pm
Tgt Ion: 178
Ion Exp Ratio
178 100
176 20.0
0 0.0
0 0.0
Abundance
_
10000 '.
5000 .
0
TIC: ENG1319.D
J\ S^
rime--> 291501 30.00 'sblso' 'silo'o' 'silso'
Abundance
4000 -
2000 .
0 .
Ion 188.00 (187.70 to 188.70): ENG
Ion 94.00 (93.70 to 94.70): ENG13
-^ - - - 'V-A,!- - - ,--„„-
rime--> 29!5o' '30.00' 'sbls'o' '31 loo' '31! so'
ENGl.iiy.D PES.M Wed May 2b 13:48:0.3 1999
#13
Anthracene-dlO
Concen: 0.00 ng/uL
Expected RT: 30.57 min
Lab File: ENG1319.D
Acq: 18 May 99 6:21 pm
Tgt Ion: 188
Ion Exp Ratio
188 100
94 30.0
0 0.0
0 0.0
HP 5989B
OCC3S12
Page 8
-------
Abundance
10000 .
5000 .
Time-->29.50 30:00 30.50 3l!00 3l!50
TIC: ENG1319.D
0
Abundancelon 178.00 (177.70 to 178.70): ENG
4000JOn 176-°° (175.70 to 176.70): ENG
3000 J
2000:
1000:
Time-->29.50 30.00 30.50 31.00 31.50
#14
Anthracene
Concen: 0.00 ng/uL
Expected RT: 30.62 min
Lab File: ENG1319.D
Acq: 18 May 99 6:21 ptn
Tgt Ion: 178
Ion Exp Ratio
178 100
176 20.0
0 0.0
0 0.0
Abundance
800000 :
600000 :
:
400000 :
200000 :
o :
Time-->
Abundance
4000 :
3000 _
2000 .
1000 :
o •
Time-->
_j
TIC: ENG1319.D
^
32.50 33.00 33.50 34.00 34.50
Ion 212.00 (211.70 to 212.70): ENG
Ion 106.00 (105.70 to 106.70): ENG
_^_^..1VT^.u^r-^Vr«J^LL^r^MVW^^_J-.*y^^ ^Vv-V-' V^A/v^
32. SO' 33] DO' '33! SO' 34! do' '34l50'
rlJiy.D PES.M Wed May 2fe 13:48:07 1999
#15
Fluoranthene-dl0
Concen: 0.00 ng/uL
Expected RT: 33.57 min
Lab File: ENG1319.D
Acq: 18 May 99 6:21 pm
Tgt Ion: 212
Ion Exp Ratio
212 100
106 30.0
0 0.0
0 0.0
OCG38I2
HP 5989B
Page 9
-------
Abundance
sooooo:
eooooo:
400000:
200000:
oi
Time - - > 3
Abundance
3000:
2000:
1000 :
1
1
0 "
Time - - > 3
"TIC: ENG1319.D
2.50 33.00 33.50 34.00 34.50
Ion 202.00 (201.70 to 202.70): ENG
Ion 101.00 (100.70 to 101.70): ENG
r^T^^
i 1 — i — i — i — i — i — i — r- i i i i I I i i i i 1 i : i
2 50 33.00 33.50 34.00 34.50
#16
Fluoranthene(CCC)
Concen: 0.00 ng/uL
Expected RT: 33.62 min
Lab File: ENG1319.D
Acq: 18 May 99 6:21 pm
Tgt Ion-. 202
Ion Exp Ratio
202 100
101 27.0
0 0.0
0 0.0
ENG
Abundance
20000:
15000 :
10000 :
5000 :
o •
TIC: ENG1319.D
"~\
i - •"
Time--> ' ' 's'sls'o' '34loV '34! 50' 'ssloo'
Abundance
4000 :
3000 .
2000 .
1000.
0.
Time-->
Ion 212.00 (211.70 to 212.70): ENG
Ion 106.00 (105.70 to 106.70): ENG
1^ A. A
'33! so' '34 loo' '34! so' '35! do' ' ' '
ri3iy.D PES.M wed way 2& i3:48:iu iyyy
#17
Pyrene-dlO
Concen: 0.00 ng/uL
Expected RT: 34.25 min
Lab File: ENG1319.D
Acq: 18 May 99 6:21 pm
Tgt Ion: 212
Ion Exp Ratio
212 100
106 34.0
0 0.0
0 0.0
HP 5989B
Page 10
-------
Abundance
20000 :
IBOOO:
10000 .
5000 :
o :
lime - - >
Abundance
3000 :
2000 :
1000 :
0 .
rime-->
TIC: ENG1319.D
1
3:3! 50 ' 34! do' '341501 35l DO' ' ' '
Ion 202.00 (201.70 to 202.70): ENG
Ion 101.00 (100.70 to 101.70): ENG
_^^A^-^^
'ssis'o' '34 loo' '34! so' '35! do' ' ' '
#18
Pyrene
Concen: 0.00 ng/uL
Expected RT: 34.30 min
Lab File: ENG1319.D
Acg: 18 May 99 6:21 pm
Tgt Ion: 202
Ion Exp Ratio
202 100
101 32.0
0 0.0
0 0.0
Abundance TIC: ENG1319.D
•
20000 :
•
isooo :
•
*
10000 :
.
5000 :
:
o :
s^~\
/ \
^/ \__ _
Time--> ' ' ' 34150 ' ' 34led ' ' 34170
Abundancelon 244.00 (243.70 to 244.70): ENG
'
-
6000 :
4000 .
2000 .
0 .
Ion 122.00 (121.70 to 122.70): ENG
34.58
A
/A____
/ NS-^
rime--> ' ' ' 34150 ' ' 34led ' ' 34170
#19
p-T(
Con<
RT:
Dell
Lab
Acg
Tgt
Ion
244
122
0
0
ENGx^iy.jj PES.M wea way 26 13:48:1.3 lyyy
p-Terphenyl-d!4
Concen: 0.03 ng/uL
RT: 34.58 min Scan# 3769
R.T. 0.02 min
.le: ENG1319.D
Acg: 18 May 99 6:21 pm
Tgt Ion:244 Resp: 11911
Ratio Lower Upper
100
0.0 13.6 40.6#
0.0 0.0 0.0
0.0 0.0 0.0
000-3815
HP 5989B
Page 11
-------
Abundance
15000 :
10000 1
5000 J
0
*~~-~^V~~
TIC: ENG1319.D
Time--> ' Y'slo'o' Ysiso' '39lo'o' '39!s'o' ' ' '
Abundance
4000 .
2000.
0 .
Ion 2
Ion 1
40.00 (239.70 to 240.70): ENG
20.00 (119.70 to 120.70): ENG
Time--> ' '38 0 0 ' Ys 1 50 ' '39 1 00 ' Y^is'o' ' ' '
#20
Benzo(a)anthracene-d!2
Concen: 0.00 ng/uL
Expected RT: 38.87 min
Lab File: ENG1319.D
Acq: 18 May 99 6:21 pm
Tgt Ion: 240
Ion Exp Ratio
240 100
120 30.0
0 0.0
0 0.0
ENG
Abundance
15000 .
10000 '.
5000 J
o :
~^~^Vv^
TIC: ENG1319.D
Time--> 38.00 38.50 39.00 39.50
Abundance
3000 J
"
2000 :
1000 :
o:
Ion :
Ion :
228.00 (227.70 to 228.70): ENG
L14.00 (113.70 to 114.70): ENG
-^ Jrr^ ^ ^ _/^Vl__/-vi. ~^*~*
Iime--> ' Yslo'o' YslsV Yglo'o' 'ssls'o' '
1319. D PES.M Wed May 2b 13:4B:16 1999
#21
Benzo(a)anthracene
Concen: 0.00 ng/uL
Expected RT: 38.98 min
Lab File: ENG1319.D
Acq: 18 May 99 6:21 pm
Tgt Ion: 228
Ion Exp Ratio
228 100
114 25.0
0 0.0
0 0.0
HP 5989B
Page 12
-------
Abundance
15000 J
10000 J
5000 J
0
rime--> 3
Abundance
4000 .
2000 .
i
0 -
Time--> 3
w_^
TIC: ENG1319.D
8 o'o Ysls'o' '39 loo' 's'gls'o' Volo'o'
Ion 240.00 (239.70 to 240.70): ENG
Ion 120.00 (119.70 to 120.70): ENG
_^___
8. o'o' Ysls'o' '39! o'o' 's'gls'o' '40! o'o'
#22
Chrysene-dl2
Concen: 0.00 ng/uL
Expected RT: 39.03 min
Lab File: ENG1319.D
Acq: 18 May 99 6:21 pm
Tgt Ion: 240
Ion Exp Ratio
240 100
120 30.0
0 0.0
0 0.0
Abundance
10000 .
5000 .
0
Time-->
Abundance
3000 :
2000 :
1000 :
o:
rime-->
TIC: ENG1319.D
38.50 39.00 39.50 40.00
ion 228.00 (227.70 to 228.70): ENG
Ion 114.00 (113.70 to 114.70): ENG
A A
"-"-^rwvwV ^-'H-Nn-iX _fr^^r^j_ '* -^JMJ^-' "J
Ysls'o' '39! o'o' Ygls'o' Volo'o'
Wed May 26 13:48:20 1999
#23
Chrysene(CCC)
Concen: 0.00 ng/uL
Expected RT: 39.16 min
Lab File: ENG1319.D
Acq: 18 May 99 6:21 pm
Tgt Ion: 228
Ion Exp Ratio
228 100
114 25.0
0 0.0
0 0.0
HP 5989B
OC0.331?
Page 13
-------
Abundance
10000.
5000 .
I
n
1
u -1 — 1 — 1 — 1 —
Time--> 45.
Abundance
4000:
3000.
2000 .
1000 -
0.
Ion 2<
Ion I!
TIC: ENG1319.D
— i — i — i i | i i i i | > i i i iii i f
00 45.50 46.00 46.50
54.00 (263.70 to 264.70): ENG
32.00 (131.70 to 132.70): ENG
Time--> Vs.o'o' Vslso' '46! 00 46150
#24
Benzo(b)fluoranthene-dl2
Concen: 0.00 ng/uL
Expected RT: 45.87 min
Lab File: ENG1319.D
Acq: 18 May 99 6:21 pm
Tgt Ion: 264
Ion Exp Ratio
264 100
132 30.0
0 0.0
0 0.0
ENG
Abundance
10000 .
5000 .
0
TIC: ENG1319.D
Time--> 45.00 VslsO 46 OO' '46.50 '47!00
Abundance
4000 .
2000 .
0.
Ion
Ion
252.00 (251.70 to 252.70): ENG
126.00 (125.70 to 126.70): ENG
Time--> 45! 00 45!50 46100 46 1 50 4?! 00
1319. D PES.M Wea May 26 13:48:23 1999
#25
Benzo(b)fluoranthene
Concen: 0.00 ng/uL
Expected RT: 46.07 min
Lab File: ENG1319.D
Acq: 18 May 99 6:21 pm
Tgt Ion: 252
Ion Exp Ratio
252 100
126 25.0
0 0.0
0 0.0
HP 5989B
Page 14
-------
Abundance
10000.
5000 _
0 J
Time--> 4
Abundance
4000 .
3000 .
2000.
1000:
0.
rime--> 4
TIC: ENG1319.D
p , — - '- -- i-nr ^ - - rr
J
5 o'o' '45150' '46! do' Vels'o' '47! do'
Ion 264.00 (263.70 to 264.70): ENG
Ion 132.00 (131.70 to 132.70): ENG
5 oo '45! BO Ye 1 o'o' Yels'o' '47! o'o'
#26
Benzo(k)fluoranthene-d!2
Concen: 0.00 ng/uL
Expected RT: 46.07 min
Lab File: ENG1319.D
Acq: 18 May 99 6:21 pm
Tgt Ion: 264
Ion Exp Ratio
264 100
132 30.0
0 0.0
0 0.0
ENG
Abundance
10000 .
5000.
0 .
TIC: ENG1319.D
Time--> 45.50 46 00 46.50 47 00
Abundance
4000.
2000.
0-
rime-->
Ion 252.00 (251.70 to 252.70): ENG
Ion 126.00 (125.70 to 126.70): ENG
•*"*^/Wv~JV~^^^w-<^^M(^^^'V*^>>>— »N\ ^v«v-~vfvvvv»v^~w-1»rt^~<^^-.
'45150' '46 1 o'o' Vels'o' '47! o'o' ' ' '
uiy.u PES.M wed May 26 13:48:26 1999
#27
Benzo(k)fluoranthene
Concen: 0.00 ng/uL
Expected RT: 46.23 min
Lab File: ENG1319.D
Acq: 18 May 99 6:21 pm
Tgt Ion: 252
Ion Exp Ratio
252 100
126 25.0
0 0.0
0 0.0
000-39:19
HP 5989B
Page 15
-------
Abundance
10000.
5000.
n
•' ' TIC: ENG1319.D
Time--> 47.50 48.00 48.50 49.00 49.50
Abundance
4000:
3000;
2000:
1000-
0.
Time-->
Ion 264.00 (263.70 to 264.70): KNG
Ion 132.00 (131.70 to 132.70): ENG
1 >»v'^M^'*'^>VjW-v*^fv*Kl'^ 48loci ' ' 49lo6 ' ' 5olo6
Abundance
4000 .
2000_
0.
Time -->
ion 252.00 (251.70 to 252.70): ENG
Ion 126.00 (125.70 to 126.70): ENG
r**+**J^Tlffi"*?*^l*^'***^n*J#»^^^
48lod ' ' 49lod ' ' solod
1319. D PES.M Wea May 26 13:48:30 1999
#29
Benzo(a)pyrene(CCC)
Concen: 0.00 ng/uL
Expected RT: 48.74 min
Lab File: ENG1319.D
Acq: 18 May 99 6:21 pm
Tgt Ion: 252
Ion Exp Ratio
252 100
126 25.0
0 0.0
0 0.0
HP 5989B
Page 16
-------
Abundance
15000 .
10000 L
5000 i
0 "
lime - - >6 0
Abundance
2000 .
1000 .
0 '.
Time-->60
TIC: ENG1319.D
L ._ . .......fln.-i . mi i I.MI J i nlrt ii -f \Jtt- -fr-*' »t •" f^Vm -i >V "jnjv-i^uif<.
!00 ' ' 6l!o6 ' ' 62io6 ' ' 63loO
Ion 288.00 (287.70 to 288.70): ENG
.00 ' ' eiloo ' ' 62lo6 ' ' esioo
#30
Indenod, 2, 3-cd) pyrene-d!2
Concen-. 0.00 ng/uL
Expected RT: 61.48 min
Lab File: ENG1319.D
Acg: 18 May 99 6:21 pm
Tgt Ion: 288
Ion Exp Ratio
288 100
0 0.0
0 0.0
0 0.0
Abundance
15000-
10000 J
5000 -
0 '
Time-->
TIC: ENG1319.D
krr^j_J^ M -^^..-i mj)j(|Tr n nnU'*i->»-MiJ--'jVJWri<|rV r i "fr "/^ VH'"1* T*lJ "J^JMiji*^
6llo6 ' ' 62lo6 ' ' 63lo6
Abundancelon 276.05 (275.75 to 276.75): ENG
3000 J
2000J
1000 J
0 J
Time - - >
Ion 138.00 (137.70 to 138.70): ENG
AjjL|..-jj-J1,,,,,1fc.-Ju^MLU^^ W^rf.fY^kn*****/
eiloo ' ' 62!oo ' ' 63!oo
ENGlJiy.D PES.M Wed May 2k 13:48:33 1999
#31
Indeno(1,2,3 -cd)pyrene
Concen: 0.00 ng/uL
Expected RT: 61.83 min
Lab File: ENG1319.D
Acq: 18 May 99 6:21 pm
Tgt Ion: 276.05
Ion Exp Ratio
276 100
138 64.0
0 0.0
0 0.0
HP 5989B
Page 17
-------
Abundance
15000-
10000-
5000-
0 J
Time- -> 60
Abundance
2000 .
1000 J
oj
Time- -> 60
TIC: ENG1319.D
LuWj. wJJrt,,, <*. *^#v^^**t*4r*'*-~ton^f&*~*ar~*^^'~'fM+**~~fTt' >V| *'tft > ^fV^ "
loo ' ' eiloo ' ' 62lod
Ion 292.00 (291.70 to 292.70): ENG
.00 ' ' 61 io6 ' ' 62! 00
#32
Dibenz(a,h)anthracene-dl4
Concen: 0.00 ng/uL
Expected RT: 61.44 tnin
Lab File: ENG1319.D
Acg: 18 May 99 6:21 pm
Tgt Ion: 292
Ion Exp Ratio
292 100
0 0.0
0 0.0
0 0.0
lAbundance
15000.
10000.
5000 1
0
Time -->
Abundance
3000J
2000:
1000.;
oj
Time - - >
TIC: ENG1319.D
61.00 62.00 63.00
Ion 278.00 (277.70 to 278.70): ENG
Ion 139.00 (138.70 to 139.70): ENG
61.00 62.00 63.00
1999
#33
Dibenz(a,h)anthracene
Concen: 0.00 ng/uL
Expected RT: 61.85 min
Lab File: ENG1319.D
Acq: 18 May 99 6:21 pm
Tgt Ion: 278
Ion Exp Ratio
278 100
139 25.0
0 0.0
0 0.0
HP 5989B
>is-x>
~ •^'V.x*
Page 18
-------
Abund^n^e TIC: ENG1319.D
10000.
5000 -
n
rime--> 64lod ' ' eslod ' ' eelod
Abundance
2000 '.
1000 .
0-
Time-->
Ion 288.00 (287.70 to 288.70): ENG
54! od ' ' 65 loo ' ' eelod
#34
Benzo(g,h,i)perylene-d!2
Concen: 0.00 ng/uL
Expected RT: 65.06 min
Lab File: ENG1319.D
Acq: 18 May 99 6:21 pm
Tgt Ion: 288
Ion Exp Ratio
288 100
0 0.0
0 0.0
0 0.0
ENC
^siuW
10000.
5000 .
0 J
TIC: ENG1319.D
Time-->64lod ' ' eslod ' ' eelod
Abundance
3000 J
2000J
1000.
0 .
rime--> 64
Ion 276.00 (275.70 to 276.70): ENG
Ion 138.00 (137.70 to 138.70): ENG
loo ' ' eslod ' ' eelod
rlJiy.D PES.M Wed May 26 13:48:39 1999
#35
Benzo(g,h,i)perylene
Concen: 0.00 ng/uL
Expected RT: 65.44 min
Lab File: ENG1319.D
Acq: 18 May 99 6:21 pm
Tgt Ion: 276
Ion Exp Ratio
276 100
138 25.0
0 0.0
0 0.0
OCC3
HP 5989B
Page 19
-------
ENG1320.XLS
Quantitation Report Summary
Data File
Date Analyzed:
Sample ID
Method ID
Operator
Instrument
Compounds
Naphthalene(CCC)
Acenaphthylene
Acenaphthene(CCC)
Fluorene
Phenanthrene
Anthracene
Fluoranthene(CCC)
Pyrene
Benzo(a)anthracene
Chrysene(CCC)
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Benzo(a)pyrene(CCC)
lndeno(1,2,3-cd)pyrene
Dibenz(a,h)anthracene
Benzo(g,h,i)perylene
ENG1320.D
05/18/99
Dl BLANK
PES
JEMcCartney
HP 5989B
Area
6957
0
0
0
2744
0
0
0
0
0
0
0
0
0
0
0
* PQL - practical quantitation limit
Surrogate Recoveries
Compound
Naphthalene-d8
Acenaphthylene-d8
Acenaphthene-d10
Fluorene-d10
Phenanthrene-d10
Anthracene-d10
Fluoranthene-d10
Pyrene-d10
Benzo(a)anthracene-d12
Chrysene-d12
Benzo(b)fluoranthene-d12
Benzo(k)fluoranthene-d12
Benzo(a)pyrene-d12
Indeno(1,2,3-cd)pyrene-d12
Dibenz(a,h)anthracene-d14
Benzo(g, h, i)perylene-d 1 2
Recovery Standard
Compound
2-M ethlynaphthalene-d 1 0
p-Terphenyl-d14
Compiled by:
Reviewed by:
Reviewed by:
Cone.
(ng/pL)
0.012
0.000
0.000
0.000
0.004
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Cone. (ng/uL)
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
O.OOj
0.00
0.00
0.00
Concentration (ng/uL)
0.00
0.00
/
•^
PQL*
(ng/ML)
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1 ** Jrc
./rr 4^^ $ //?//,
JI5t*Y\
-------
Quantitation Report
Data File :
Acq On :
Sample :
Misc ;
Quant Time:
C:\HPCHEM\1\DATA\9919\ENG1320.D
18 May 99 7:37 pm
DI BLANK
May 26 13:51 1999
Vial: 8
Operator: JEMcCartney
Inst : HP 5989B
Multiplr: 1.00
Method
Title
Last Update
Response via
C:\HPCHEM\1\METHODS\PES.M
Mon May 24 16:23:27 1999
Multiple Level Calibration
Internal Standards
1)
2 , 2-Dif luorobiphenyl
R.
24.
T. Qlon
60
190
Response
1649095
System Monitoring Compounds
2)
4)
5)
7)
9)
11)
13)
15)
17)
19)
20)
22)
24)
26)
28)
30)
32)
34)
Naphthalene-d8
2 -Me thlynapht hal ene - dl 0
Acenapht hy 1 ene - d8
Acenaphthene - dl 0
Fluor ene -dlO
Phenanthrene-dlO
Anthracene -dlO
Fluor ant hene - dl 0
Pyrene-dlO
p-Terphenyl-d!4
Benzo (a) anthracene-d!2
Chrysene-dl2
Benzo (b) f luoranthene -d!2
Benzo (k) f Iuoranthene-dl2
Benzo (a) pyrene-d!2
Indenod, 2, 3-cd)pyrene-dl2
Dibenz (a, h) anthracene -d!4
Benzo (g, h, i) perylene-d!2
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
136
152
160
164
176
188
188
212
212
244
240
240
264
264
264
288
292
288
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Target Compounds
3)
6)
8)
10)
12)
14)
16)
18)
21)
23)
25)
27)
29)
31)
33)
35)
Naphthalene(CCC)
Acenapht hyl ene
Acenaphthene (CCC)
Fluorene
Phenanthrene
Anthracene
Fluoranthene (CCC)
Pyrene
Benzo (a) anthracene
Chrysene (CCC)
Benzo (b) f luoranthene
Benzo (k) f luoranthene
Benzo (a) pyrene (CCC)
Indeno (1,2,3- cd) pyrene
Dibenz (a, h) anthracene
Benzo (g, h, i) perylene
22.
0.
0.
0.
30,
0,
.30
.00
.00
.00
.50
.00
0.00
0
0
0
0
0
0
0
0
0
.00
.00
.00
.00
.00
.00
.00
.00
.00
128
152
154
166
178
178
202
202
228
228
252
252
252
276
278
276
6957
2744
Cone Units Dev(Min)
5.00 ng/uL
0.
02
%Recovery
0.00 ng/uL
0.00 ng/uL
0.00 ng/uL
0.00 ng/uL
0.00 ng/uL
0.00 ng/uL
0.00 ng/uL
0.00 ng/uL
0.00 ng/uL
0.00 ng/uL
0.00 ng/uL
0.00 ng/uL
0.00 ng/uL
0.00 ng/uL
0.00 ng/uL
0.00 ng/uL
0.00 ng/uL
0.00 ng/uL
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
00%
00%
00%
00%
00%
00%
00%
00%
00%
00%
00%
00%
00%
00%
00%
00%
00%
00%
Qvalue
0.01 ng/uL#
Not Detected
Not Detected
Not Detected
0.00 ng/uLm
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
3-S
73
0
~
(#) = qualifier out of range (m) = manual integration
ENG1320.D PES.M Wed May 26 13:51:43 1999 HP 5989B
Page 1
-------
Quantitation Report
Data File : C:\HPCHEM\1\DATA\9919\ENG1320.D
Acg On : 18 May 99 7:37 pm
Sample : DI BLANK
Misc :
Quant Time: May 26 13:51 1999
Method
Title
Last Update
Response via
C:\HPCHEM\1\METHODS\PES .M
Mon May 24 16:23:27 1999
Multiple Level Calibration
Vial: 8
Operator: JEMcCartney
Inst : HP 5989B
Multiplr: 1.00
TIC: ENG13207D
1100000:
1000000 J
900000:
sooooo:
700000:
eooooo:
sooooo:
400000:
300000:
200000:
100000:
Time-->
12
20.00
3oiod
4olod
50.00
~i 1 1 1 r
60.00
ENG1320.D PES.M
Wed May 26 13:51:48 1999
OC03S26
HP 5989B Page 2
-------
Abundance
15000 -I
10000 .
5000.
rime-->2i:00 2l!50 22100 22.50 23.00
TIC: ENG1320.D
0
Abundancelon 136.00 (135.70 to 136.70): ENG
onAn lion 68.00 (67.70 to 68.70): ENG13
8000 -
6000:
4000:
2000:
o:
rime-->2llOO 2i:50
22.50 23.00
#2
Naphthalene-d8
Concen: 0.00 ng/uL
Expected RT: 22.23 min
Lab File: ENG1320.D
Acq: 18 May 99 7:37 pm
Tgt Ion: 136
Ion Exp Ratio
136 100
68 20.0
0 0.0
0 0.0
ENCj
Sundance
10000.
•
5000 1
0 '
Time - - >
Abundance
6000 J
4000 J
2000.
0.
rime-->
TIC: ENG1320.D
22120 ' ' 22130 ' ' 22U6
Ion 128.00 (127.70 to 128.70): ENG
Ion 127.00 (126.70 to 127.70): ENG
22.30
^Av
22i20 ' ' 22!30 ' ' 22U6
ri320.D PES.M wea way 26 13:51:51 iyyy
#3
Nap]
Con<
RT:
Del
Lab
Acq
Tgt
Ion
128
127
0
0
Naphthalene(CCC)
Concen: 0.01 ng/uL
22.30 min Scan# 1576
a R.T. 0.01 min
File: ENG1320.D
18 May 99 • 7:37 pm
Tgt Ion:128 Resp: 6957
Ratio Lower Upper
100
0.0 0.0 60.0
0.0 0.0 0.0
0.0 0.0 0.0
HP 5989B
Page 3
-------
Abundance
800000 :
600000 :
400000:
200000 :
0-
rime - - >
Abundance
3000.
2000 .
1000 -
0
Time - - >
TIC: UNG1320.D
j
'23lo'o' '23150' '24! do' '24! 50 25!00
Ion 152.00
(151.70 to
152.70) : ENG
1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 r- -ill ii
23.00 23.50 24 00 24.50 25 00
#4
2-Methlynaphthalene-dlO
Concen: 0.00 ng/uL
Expected RT: 23.96 min
Lab File: ENG1320.D
Acq: 18 May 99 7:37 pm
Tgt Ion: 152
Ion Exp Ratio
152 100
0 0.0
0 0.0
0 0.0
ENG
Abundance
6000 J
4000 :
2000:
;
0<
Time - - >
Abundance
2000 J
1000.
0
rime-->
1
"~~ ~~~-r~_^_
1C: ENG1320.D
25l50' '26 100 26150 2?loO '
Ion 160.00
(159.70 to 160.70): ENG
25.50 26.00 26.50 27.00
1320. D PES.M wea May 26 13:51:54 iyyy
#5
Acenaphthylene-d8
Concen: 0.00 ng/uL
Expected RT: 26.29 min
Lab File: ENG1320.D
Acq: 18 May 99 7:37 pm
Tgt Ion: 160
Ion Exp Ratio
160 100
0 0.0
0 0.0
0 0.0
HP 5989B
Page 4
-------
Abundance
6000 J
4000 :
2000 :
0
Time-->
Abundance
3000 .
2000 .
1000 .
0
rime-->
1
KG: ENG1320.D
'25150' '26 loo' 26lso 27 loo '
Ion 152.00
Ion 153.00
(151.70 to 152. 70): ENG
(152.70 to 153.70) : ENG
'25l50' VeloV '2(5 1 SO' ^vio'o' ' ' '
#6
Acenaphthylene
Concen: 0.00 ng/uL
Expected RT: 26.32 min
Lab File: ENG1320.D
Acq: 18 May 99 7:37 pm
Tgt Ion: 152
Ion Exp Ratio
152 100
153 15.0
0 0.0
0 0.0
ENG
Sundance
6000 J
4000 J
2000 :
o '
Time-->25
Abundance
3000 _
2000.
1000 .
0
Time-->25
TIC: ENG1320.D
— ~-~J
l50' '26lo'o' '26150' '27l6o' '27\50'
Ion 164.00 (163.70 to 164.70): BUG
Is'o' '26ldo' Velso' '27 loo' '2?! so'
1320. D PEb.M Wea IViay 26 13:51:58 1999
#7
Acenaphthene-dl0
Concen: 0.00 ng/uL
Expected RT: 26.71 min
Lab File: ENG1320.D
Acq: 18 May 99 7:37 pm
Tgt Ion: 164
Ion Exp Ratio
164 100
0 0.0
0 0.0
0 0.0
HP 5989B
Page 5
-------
Abundance
6000 J
4000-
2000.
0 "
Time-->
Abundance
3000 J
2000.
1000 J
0 '
Time - - >
TIC: ENG1320.D
r*1-^ _A ^ f^^+i+ts^r-twA
'26 loo' '26! so' '2? loo' ^vls'o' ' ' '
Ion
Ion
154.00 (153.70 to 154.70): ENG
153.00 (152.70 to 153.70): ENG
'26 loo' Velso' '27lo'o' Vvls'o' ' ' '
#8
Acenaphthene(CCC)
Concen: 0.00 ng/uL
Expected RT: 26.79 min
Lab File: ENG1320.D
Acq: 18 May 99 7:37 pm
Tgt Ion: 154
Ion Exp Ratio
154 100
153 86.8
0 0.0
0 0.0
ENG
eooo:
4000;
2000.
0
Time-->
Abundance
3000-
2000.
1000.
0 '
rime-->
TIC: ENG1320.D
27 loo 27.50 28l6o VslsO '29 6o'
Ion 176.00 (175.70 to 176.70): ENG
ii i i i i i i i i i •] •'-[ — i — i — i — i — i — i — i — i — | — i — r
27.00 27.50 28100 28150 29 00
IJ^JU.D PKS.M wed May 26 13 :52 :01 "199^"
#9
Fluorene-dlO
Concen: 0.00 ng/uL
Expected RT: 28.00 min
Lab File: ENG1320.D
Acq: 18 May 99 7:37 pm
Tgt Ion: 176
Ion Exp Ratio
176 100
0 0.0
0 0.0
0 0.0
HP 5989B
OCC3S30
Page 6
-------
Abundance
6000 :
•
4000 :
2000 :
0
lime - - >
Abundance
3000 J
2000:
1000 :
0 '
fTime-->
TIC: ENG132U.D
27loo' '211.50 Vsloo' ^slsV '29loo'
Ion 166.00 (165.70 to 166.70): ENG
Ion 165.00 (164.70 to 165.70): ENG
c^r^rr^rrZII
27!oV ^VlsV '28 loo' Vsls'o' '29! do'
Abundance
10000 -
5000 _
Time-->
TIC: ENG1320.D
2S50
loo
ilon 188.00 (187.70 to 188.70): ENG
lion 94.00 (93.70 to 94.70): ENG13
3000 J
2000 J
1000:
rime-->
soo soso soo
#10
Fluorene
Concen: 0.00 ng/uL
Expected RT: 28.08 min
Lab File: ENG1320.D
Acq: 18 May 99 7:37 pra
Tgt Ion: 166
Ion Exp Ratio
166 100
165 76.2
0 0.0
0 0.0
ENG1320.D—PES.M
Wed May 2t 13:b2:U4 1999
Phenanthrene-dl0
Concen: 0.00 ng/uL
Expected RT: 30.43 min
Lab File: ENG1320.D
Acq: 18 May 99 7:37 pm
Tgt Ion: 188
Ion Exp Ratio
188 100
94 30.0
0 0.0
0 0.0
fkf*.
-------
Abundance
10000 .
5000 .
n
TIC: ENG1320.D
" -J 1 1 — r— 'i — i i i i | i i i i i i i i ] i
Time-->30.40 30.45 30.50 30.55
Abundance
4000 :
3000 :
2000 :
1000 :
o :
Time--> 3C
Ion 178.00 (177.70 to 178.70): ENG
Ion 176.00 (175.70 to 176.70): ENG
30.50
) 1 40 ' ' 30 1 45 ' ' 30 ! 50 ' ' 30 1 55 ' ' ' '
#12
Phenanthrene
Concen: 0.00 ng/uL m
RT: 30.50 min Scan# 3089
Delta R.T. 0.01 min
Lab File: ENG1320.D
Acq: 18 May 99 7:37 pm
Tgt Ion:178 Resp:
Ion Ratio
178 100
176 76.8
0 0.0
0 0.0
2744
Lower Upper
10.1
0.0
0.0
30.1#
0.0
0.0
ENG
Abundance
10000 .
5000 .
0 -
TIC: ENG1320.D
Time--> 29150 30.00 30.50 31; 00 31.50
Abundance
4000 J
3000 :
2000.
1000.
0.
Ion 188.00 (187.70 to 188.70): ENG
Ion 94.00 (93.70 to 94.70): ENG13
Time--> 29150' Voloo' 'sblsV 'silo'o' 'silsV
1J20.D PEb.M Wea May 2t> 13:5^:07 1999
#13
Anthracene-dl0
Concen: 0.00 ng/uL
Expected RT: 30.57 min
Lab File: ENG1320.D
Acq: 18 May 99 7:37 pm
Tgt Ion: 188
Ion Exp Ratio
188 100
94 30.0
0 0.0
0 0.0
HP 5989B
Page 8
-------
Abundance
10000 .
5000 .
TIC: ENG1320.D
Time-->29.50 30.00 30.50 31.00 31.50
Abundancelon 178.00 (17T770 to 178.70): ENG
Ion 176.00 (175.70 to 176.70): ENG
4000 J
3000 J
2000:
1000 :
Time-->29.50 30.00 30.50 31.00 31.50
#14
Anthracene
Concen: 0.00 ng/uL
Expected RT: 30.62 min
Lab File: ENG1320.D
Acg: 18 May 99 7:37 pm
Tgt Ion: 178
Ion Exp Ratio
178 100
176 20.0
0 0.0
0 0.0
ENG
500000 .
0-
Time-->
Abundance
3000 :
2000.
1000 .
0
rime-->
j
TIC: ENG1320.D
L
3:2.50' 33 Ido 331 50 '34 Ido 34l 50
Ion 212.00 (211.70 to 212.70): ENG
Ion 106.00 (105.70 to 106.70): ENG
r— ^^^3^
32 50' '33 loo' Ysls'o' '34 Ido' '34! 50 '
r!320.D PEb.M Wea May 2b 13:52 :1U 1999
#15
Fluoranthene-dl0
Concen: 0.00 ng/uL
Expected RT: 33.57 min
Lab File: ENG1320.D
Acq: 18 May 99 7:37 pm
Tgt Ion: 212
Ion Exp Ratio
212 100
106 30.0
0 0.0
0 0.0
OCC1S23
HP 5989B
Page 9
-------
^Mees6
500000 .
0-
Time--> 3
Abundance
3000 :
2000.
1000 .
0
Time--> 3
TIC: ENG1320.D
2l SO' 33!o'o' '33l50' 's^io'o' '34! SO*
Ion 202.00 (201.70 to 202.70): ENG
Ion 101.00 (100.70 to 101.70): ENG
^^^^^^^^v^^^^
2.50' '33! do' '33! so' '34! do' '34! so'
#16
Fluoranthene(CCC)
Concen: 0.00 ng/uL
Expected RT: 33.62 tnin
Lab File: ENG1320.D
Acg: 18 May 99 7:37 pm
Tgt Ion: 202
Ion Exp Ratio
202 100
101 27.0
0 0.0
0 0.0
ENG
Abundance
15000 .
10000.
5000 .
0 J
rime- -=33
™un%me.
3000 :
2000:
1000 :
o ^
Time- -^3
TIC: ENG1320.D
1___J
do' '33! so' '34 loo' 's^is'o' '35 loo'
Ion 212.00 (211.70 to 212.70): ENG
Ion 106.00 (105.70 to 106.70): ENG
^w^-^^->^VYA*^*'^JL''V"vV*'tfV^^
00 33! 50 34 Ido 34150' 'ssldo'
1J2U.D PEb.M Wed May ^b 1^:5^:14 1999
#17
Pyrene-dlO
Concen: 0.00 ng/uL
Expected RT: 34.25 min
Lab File: ENG1320.D
Acg: 18 May 99 7:37 pm
Tgt Ion: 212
Ion Exp Ratio
212 100
106 34.0
0 0.0
0 0.0
HP 5989B
Page 10
-------
Abundance
15000 J
10000 1
5000.
0 '
Time-->
Abundance
3000.
2000J
1000.
0 .
Time-->
TIC: ENG1320.D
Vsis'o' '34! do' 34l5o' '35 lob' ' ' '
ion 202.00 (201.70 to 202.70): ENG
Ion 101.00 (100.70 to 101.70): ENG
cri^czii^iiir^
'33! so' '34! do' '34! so' '35! do' ' ' '
#18
Pyrene
Concen: 0.00 ng/uL
Expected RT: 34.30 min
Lab File: ENG1320.D
Acq: 18 May 99 7:37 pm
Tgt Ion: 202
Ion Exp Ratio
202 100
101 32.0
0 0.0
0 0.0
ENG
Abundance
15000 J
10000 J
5000 J
0 '
Time-->
Abundance
3000.
2000:
1000 :
0 '
Time-->
* 1
TIC: ENG1320.D
33150' '34 Ido' 'sils'o' 'sslo'o' 'ssisV
ion 244.00 (243.70 to 244.70): ENG
Ion 122.00 (121.70 to 122.70): ENG
rv^-vyu>rf-v-A~^^^^/Sgv>VVv««*A^^^
sisls'o' '34! do' '34l5'o' '35 loo' 'ssls'o'
132U.D PES.M Wed May 2b 13:52:17 1993
#19
p-Terpheny1-dl4
Concen: 0.00 ng/uL
Expected RT: 34.57 min
Lab File: ENG1320.D
Acq: 18 May 99 7:37 pm
Tgt Ion: 244
Ion Exp Ratio
244 100
122 27.0
0 0.0
0 0.0
.~O ••;--
HP 5989B
Page 11
-------
Abundance
80000:
60000 :
40000 :
20000 :
n
TIC: laJGl.
\ 7
J215TD
1
u -j — | — | — | 1 — | — r i I i i i i I i i i i i ... |
rime--> 38 00 38l50 39.00 39.50
Abundance
10000 _
5000 .
0 -
Ion 240.00 (233. VU
Ion 120.00 (119.70
^ _J
to 240.70) : ENG
to 120.70) : ENG
A
V,
r_^ -^_~
' — i — i — i 1 — i — i — r-r i i i i i i i i . i i i i
Time--> 38 00 38.50 39.00 39.50
#20
Benzo(a)anthracene-d!2
Concen: 0.00 ng/uL
Expected RT: 38.87 min
Lab File: ENG1320.D
Acq: 18 May 99 7:37 pm
Tgt Ion: 240
Ion Exp Ratio
240 100
120 30.0
0 0.0
0 0.0
ENG
Abundance
80000 :
60000 :
40000 :
20000 :
o :
rime-->
Abundance
50000 .
0
Time-->
TIC: ENG:
\ 1
L320.D
'SB loo' 'SB! so' '39.00' '39! so' '
Ion 228.00 (227.70
Ion 114.00 (113.70
;
to 228 . 70) : ENG
to 114.70) : ENG
A
1
r
Vsio'o' 'SB! so' 'ag.oo1 's'siso' '
1320. D PES.M wea way 26 13:52:20 iyyy
#21
Benzo(a)anthracene
Concen: 0.00 ng/uL
Expected RT: 38.98 min
Lab File: ENG1320.D
Acq: 18 May 99 7:37 pm
Tgt Ion: 228
Ion Exp Ratio
228 100
114 25.0
0 0.0
0 0.0
HP 5989B
OCC385G
Page 12
-------
Abundance
80000 :
eoooo:
40000 :
20000-
0
rime - - > 3
TIC: ENG1320.D
II
H
s.oo' 's'sls'o' '39 loo' 'sgiso' '40 lob'
Abundancelon 240.00 (239.70 to 240.70): ENG
10000-
5000 .
i
i
0 -
Time--> 3
Ion 120.00 (119.70 to 120.70): ENG
A
JL____.
s. bo' Yslso' '39 lob' 's'gls'o' '40 lob'
#22
Chrysene-dl2
Concen: 0.00 ng/uL
Expected RT: 39.03 min
Lab File: ENG1320.D
Acq: 18 May 99 7:37 pm
Tgt Ion: 240
Ion Exp Ratio
240 100
120 30.0
0 0.0
0 0.0
ENG
Abundance
80000 :
60000 :
40000 :
20000 :
0 '
Time-->
Abundance
50000 .
0 .
Time - - >
TIC: ENG1320.D
j [
Ysisb' '39 bo' Ygis'o' '40 lob'
Ion 228.00 (227.70 to 228.70): ENG
Ion 114.00 (113.70 to 114.70): ENG
A
1
SsisO 39100 39150 40ioO
1320. D PES.M wed May 26 13:52:23 iyyy
#23
Chrysene(CCC)
Concen: 0.00 ng/uL
Expected RT: 39.16 min
Lab File: ENG1320.D
Acq: 18 May 99 7:37 pm
Tgt Ion: 228
Ion Exp Ratio
228 100
114 25.0
0 0.0
0 0.0
HP 5989B
OCC38-37
Page 13
-------
Abundance
10000.
5000.
n
i
u •J — i — i — i —
Time--> 45.
Abundance
4000:
3000-
2000.
1000 .
0.
Ion 2<
Ion i:
TIC: ENG1320.D
*-\*
1™" I 1 1 1 i i < i | i ' i ' iii ~l
00 45.50 46.00 46.50
54.00 (263.70 to 264.70): ENG
32.00 (131.70 to 132.70): ENG
1 1 1 1 1 1 1 1 1 1 T '"III 1 ! 1 1 1 1 1 1
Time--> 45:00 45.50 46 00 46.50
#24
Benzo (b) f luoranthene-dl 2
Concen: 0.00 ng/uL
Expected RT: 45.87 min
Lab File: ENG1320.D
Acq: 18 May 99 7:37 pm
Tgt Ion: 264
Ion Exp Ratio
264 100
132 30.0
0 0.0
0 0.0
Abundance
10000 .
5000 -
0 '.
TIC: ENG1320.D
r~**~ff-^
J ' ~~
rime--> '45.00' '45ls'o' Veio'o' Vels'o' '47lo'o'
Abundance
4000 .
2000 _
0 .
Ion 252.00 (251.70 to 252.70): ENG
Ion 126.00 (125.70 to 126.70): ENG
Time--> '45.001 Vsls'o' Veio'o' Vels'o' V7lo'o'
ENGlTZDTD PES.M
Wea May 26 13:52:26 1999
#25
Benzo(b)fluoranthene
Concen: 0.00 ng/uL
Expected RT: 46.07 min
Lab File: ENG1320.D
Acq: 18 May 99 7:37 pm
Tgt Ion: 252
Ion Exp Ratio
252 100
126 25.0
0 0.0
0 0.0
OCC3558
HP 5989B
Page 14
-------
Abundance
10000.
5000-
0
rime--> 4
Abundance
4000 .
3000.
2000.
1000 .
0 .
Time--> 4
TIC: ENC1320.D
P»^VS/U_VV^^_V__-V-I^ 45.50 46.00 46.50 47.00
Abundance
4000 -
2000 .
0.
rime-->
Ion 252.00 (251.70 to 252.70): ENG
Ion 126.00 (125.70 to 126.70): ENG
'45150' Velo'o' Veis'o' '47 loo ' ' '
#27
Benzo(k)fluoranthene
Concen: 0.00 ng/uL
Expected RT: 46.23 min
Lab File: ENG1320.D
Acq: 18 May 99 7:37 pm
Tgt Ion: 252
Ion Exp Ratio
252 100
126 25.0
0 0.0
0 0.0
PEb.M
W6CL
HP 5989B
Page 15
-------
Abundance
10000 .
5000.
0
rime-->
Abundance
4000J
3000:
2000 :
1000 :
o:
rime - - >
TIC: ENG1320.D
47! 50 48 loV 48l5o' ^loV Vglso'
Ion 264.00 (263.70 to 264.70): ENG
Ion 132.00 (131.70 to 132.70): ENG
47l SO' '48!oo' VslsV 49ldo' Vslso'
#28
Benz o(a)pyrene-dl2
Concen: 0.00 ng/uL
Expected RT: 48.54 min
Lab File: ENG1320.D
Acq: 18 May 99 7:37 pm
Tgt Ion: 264
Ion Exp Ratio
264 100
132 30.0
0 0.0
0 0.0
Abundance
10000 '.
5000 i.
0 J
TIC: ENG1320.D
Time--> 48.00 49.00 50.00
Abundance
4000 :
3000.
2000 .
1000 :
o:
Time-->
ion 252.00 (251.70 to 252.70): ENG
Ion 126.00 (125.70 to 126.70): ENG
4^
-------
Abundance
10000 .
5000 i
n
TIC: ENG1320.D
Time-->60.o6 ' 6lio6 ' ' 62!o6 63100
Abundance
2000 .
1000 .
0 -
Time - - >6 0
Ion 288.00 (287.70 to 288.70): ENG
.00 ' ' 6lio6 ' ' 62!o6 ' ' 63io6
#30
Indeno(1, 2,3 -cd)pyrene-d!2
Concen: 0.00 ng/uL
Expected RT: 61.48 min
Lab File: ENG1320.D
Acq: 18 May 99 7:37 pm
Tgt Ion: 288
Ion Exp Ratio
288 100
0 0.0
0 0.0
0 0.0
Abundance
10000 .
5000 .
0
TIC: ENG1320.D
rime--> ' 6llo6 ' ' 62lo6 ' ' 63lo6
Abundance
3000 1
2000 .
1000 .
0 .
rime-->
Ion 276.05 (275.75 to 276.75): ENG
Ion 138.00 (137.70 to 138.70): ENG
6llo6 ' ' 62io6 ' ' 63io6
ENG13~2U7B
#31
Indeno(1,2,3 -cd)pyrene
Concen: 0.00 ng/uL
Expected RT: 61.83 min
Lab File: ENG1320.D
Acq: 18 May 99 7:37 pm
Tgt Ion: 276.05
Ion Exp Ratio
276 100
138 64.0
0 0.0
0 0.0
Wea May 2b 13:52:35
HP 5989B
Page 17
-------
Abundance
10000 '.
5000 '.
0 j
TIC: ENG1320.D
Time-->6o!o6 ' ' 61 lod ' ' 62! 00
Abundance
2000 '.
1000 J
0.
rime-->60
Ion 292.00 (291.70 to 292.70): ENG
lod eilod ' ' 62lod
#32
Dibenz(a,h)anthracene-dl4
Concen: 0.00 ng/uL
Expected RT: 61.44 min
Lab File: ENG1320.D
Acq: 18 May 99 7:37 pm
Tgt Ion: 292
Ion Exp Ratio
292 100
0 0.0
0 0.0
0 0.0
ENG
Abundance
10000 _
5000 J
0.
TIC: ENG1320.D
rime--> 61 lod 62! 00 ' 63loO
Abundance
3000.
2000:
1000.
0 J
Time - - >
Ion 278.00 (277.70 to 278.70): ENG
Ion 139.00 (138.70 to 139.70): ENG
M"^rt^•>^*H^^W4vM''^^
1 ' ' t ' ' ' • I 1 T 'I 1^ 'I 1
61.00 62.00 63lOO
J..i^U.JJ PES.M Wed May 26 U:b2:jy 1999
#33
Dibenz(a,h)anthracene
Concen: 0.00 ng/uL
Expected RT: 61.85 min
Lab File: ENG1320.D
Acq: 18 May 99 7:37 pm
Tgt Ion: 278
Ion Exp Ratio
278 100
139 25.0
0 0.0
0 0.0
HP 5989B
Page 18
-------
Abundance
10000.
5000.
0
TIC: ENG1320.D
Time--> ' 64 00 ' ' eslod ' ' 66! 00
Abundance
2000.
1000.
0 I
Time-->
Ion 288.00 (287.70 to 288.70) : ENG
64!od ' ' eslod ' ' eelob
#34
Benzo(g,h,i)perylene-d!2
Concen: 0.00 ng/uL
Expected RT: 65.06 min
Lab File: ENG1320.D
Acq: 18 May 99 7:37 pm
Tgt Ion: 288
Ion Exp Ratio
288 100
0 0.0
0 0.0
0 0.0
ENG
Abundance
10000 J
5000 J
0 J
TIC: ENG1320.D
A
Time- -> 64. 00 ' ' 6s!oo' ' ' 66! 00
Abundance
3000 .
2000-
1000.
0 '.
rime- -> 64
Ion 276.00 (275.70 to 276.70): ENG
Ion 138.00 (137.70 to 138.70): ENG
iod ' ' eslod ' ' 6e!od
U2U.D PES.M Wed May 2fo 13:52:42 1999
#35
Benzo(g,h,i)perylene
Concen: 0.00 ng/uL
Expected RT: 65.44 min
Lab File: ENG1320.D
Acq: 18 May 99 7:37 pm
Tgt Ion: 276
Ion Exp Ratio
276 100
138 25.0
0 0.0
0 0.0
HP 5989B
Page 19
-------
ENG1323.XLS
Quantitation Report Summary
Data File
Date Analyzed:
Sample ID
Method ID
Operator
Instrument
Compounds
Naphthalene(CCC)
Acenaphthylene
Acenaphthene(CCC)
Fluorene
Phenanthrene
Anthracene
Fluoranthene(CCC)
Pyrene
Benzo(a)anthracene
Chrysene(CCC)
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Benzo(a)pyrene(CCC)
lndeno(1,2,3-cd)pyrene
Dibenz(a,h)anthracene
Benzo(g,h,i)perylene
ENG1323.D
05/1 9/99 j
XAD/FILTER RUN BLANK 4/2/99
PES
JEMcCartney
HP 5989B
Area
3200394
0
0
0
6104
0
0
0
0
0
0
0
0
0
0
0
* PQL - practical quantitation limit
Surrogate Recoveries
Compound
Naphthalene-dS
Acenaphthylene-d8
Acenaphthene-d10
Fluorene-d10
Phenanthrene-d10
Anthracene-d10
Fluoranthene-d10
Pyrene-d10
Benzo(a)anthracene-d12
Chrysene-d12
Benzo(b)fluoranthene-d12
Benzo(k)fluoranthene-d 1 2
Benzo(a)pyrene-d12
Indeno(1,2,3-cd)pyrene-d12
Dibenz(a,h)anthracene-d14
Benzo(g,h,i)perylene-d12
Recovery Standard
Compound
2-Methlynaphthalene-d10
p-Terphenyl-d14
Compiled by:
Reviewed by:
Reviewed by:
Cone.
(ng/pL)
2.585
0.000
0.000
0.000
0.004
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Cone. (ng/uL)
3.20
2.79
2.97
3.18
2.73
0.34
2.90
2.73
2.59
3.17
3.44
2.85
0.00
2.54
2.38
1.52
Concentration (ng/pL)
22.98
16.75
y
PQL*
(ng/pL)
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
/s~-
srl tfMs^*' < // //
^te^Vy-^^Cj-T^vV^^jia.
-------
Quantitation Report
C:\HPCHEM\1\DATA\9919\ENG1323.D
19 May 99 1:22 pro
XAD/FILTER RUN BLANK 4/2/99
Data File
Acq On
Sample
Misc :
Quant Time: May 26 14:05 1999
Vial: 3
Operator: JEMcCartney
Inst : HP 5989B
Multiplr: 1.00
Method
Title
Last Update
Response via
C:\HPCHEM\1\METHODS\PES.M
Mon May 24 16:23:27 1999
Multiple Level Calibration
Internal Standards
R.T. Qlon Response Cone Units Dev(Min)
1)
2 , 2 -Dif luorobiphenyl
24
.60
190
3491908
System Monitoring Compounds
2)
4)
5)
7)
9)
11)
13)
15)
17)
19)
20)
22)
24)
26)
28)
30)
32)
34)
Naphthalene -d8
2 -Methlynaphthalene-dlO
Acenaphthylene-d8
Acenaphthene-dlO
Fluorene-dlO
Phenanthrene - dl 0
Anthracene -dlO
Fluorant hene - dl 0
Pyrene-dlO
p-Terphenyl-d!4
Benzo (a) anthracene -d!2
Chrysene-dl2
Benzo (b) f Iuoranthene-dl2
Benzo (k) f luoranthene -d!2
Benzo (a) pyrene -d!2
Indeno (1,2, 3-cd)pyrene-dl2
Dibenz (a, h) anthracene-d!4
Benzo (g, h, i) perylene-dl2
22
23
26
26
28
30
30
33
34
34
38
39
45
46
0
61
61
65
.24
.97
.30
.72
.02
.45
.58
.58
.26
.59
.89
.04
.89
.09
.00
.52
.46
.08
136
152
160
164
176
188
188
212
212
244
240
240
264
264
264
288
292
288
3409149
12972380
3135459
2208367
2569556
3416597
371730
3594848
3709634
17226962
2263675
3356358
2677827
3024238
0
2404872
1320918
1134080
Target Compounds
3)
6)
8)
10)
12)
14)
16)
18)
21)
23)
25)
27)
29)
31)
33)
35)
Naphthalene (CCC)
Acenaphthylene
Acenaphthene (CCC)
Fluorene
Phenanthrene
Anthracene
Fluoranthene (CCC)
Pyrene
Benzo (a) anthracene
Chrysene(CCC)
Benzo (b) f luoranthene
Benzo (k) f luoranthene
Benzo (a) pyrene (CCC)
Indeno ( 1 , 2 , 3 - cd) pyrene
Dibenz.(a,h) anthracene
Benzo (g,h, i)perylene
22
0
0
0
30
0
0
0
0
0
0
0
0
0
0
0
.30
.00
.00
.00
.50
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
128
152
154
166
178
178
202
202
228
228
252
252
252
276
278
276
3200394
610.4
5.00 ng/uL
0
.01
%Recovery
3.20 ng/uL
22.98 ng/uL
2.79 ng/uL
2.97 ng/uL
3.18 ng/uL
2.73 ng/uL
0.34 ng/uL
2.90 ng/uL
2.73 ng/uL
16.75 ng/uL
2.59 ng/uL
3.17 ng/uL
3.44 ng/uL
2.85 ng/uL
0.00 ng/uL
2.54 ng/uL
2.38 ng/uL
1.52 ng/uL
80
57
69
74
79
68
8
72
68
41
64
79
85
71
0
63
59
37
.06%
.44%
.84%
.19%
.56%
.26%
.55%
.54%
.19%
.87%
.85%
.36%
.98%
.32%
.00%
.61%
.51%
.89%
Qvalue
2.59 ng/uL
Not Detected
Not Detected
Not Detected
0.00 ng/uL#
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
occ
<"j f
89
56
5 ,> r-
(#) = qualifier out of range (m) = manual integration
ENG1323.D PES.M Wed May 26 14:06:04 1999 HP 5989B
Page l
-------
Quantitation Report
C:\HPCHEM\1\DATA\9919\ENG1323.D
19 May 99 1:22 pm
XAD/FILTER RUN BLANK 4/2/99
Data File
Acg On
Sample
Misc :
Quant Time: May 26 14:05 1999
Method
Title
Last Update
Response via
C:\HPCHEM\1\METHODS\PES.M
Mon May 24 16:23:27 1999
Multiple Level Calibration
Vial-. 3
Operator: JEMcCartney
Inst : HP 5989B
Multiplr: 1.00
Abundance
8000000-
7000000-
6000000-
5000000-
4000000.
3000000.
2000000 J
1000000 i
0 '
Time-->
TIC: ENG1323.D
1<
4s
,i
.jjLF
3
2s
i
L
1
5s
11s
If*
9s
7s
20.00
i:
i
30.
is
2
00
>S
s
22s
20s 2£g
(34s
/I .
40.00 50.00 60.00
ENG1323.D PES.M
Wed May 26 14:06:11 1999
HP 5989B
Page 2
-------
Abundance
2000000j
1500000J
1000000:
500000:
rime--> 22.10
TIC: ENG1323.D
22.20
22.30
Abundance Ion 136. OT) (135.70 to 136.70) : ENG
lion 68.00 (67.70 to 68.70): ENG13
j 22.24
•j
T
1000000 1
500000.
rime-->
22120
22:30
Abundance
2000000 -i
1500000 J
1000000:
sooooo:
rime-->
TIC: ENG1323.D
22:20
22.30
22:40
Abundancelon 128.00 (127.70 to 128.70): ENG
#2
Naphthalene-d8
Concen: 3.20 ng/uL
RT: 22.24 min Scan# 1568
Delta R.T. 0.02 min
Lab File: ENG1323.D
Acq: 19 May 99 1:22 pm
Tgt Ion:136 Resp: 3409149
Ion Ratio
136 100
68 0.0
0 0.0
0 0.0
Lower Upper
10.1
0.0
0.0
30.1#
0.0
0.0
1500000J
1000000 .
500000j
0.
Ion 127.00 (126.70 to 127.70): ENG
22.30
rime-->
22.20
22:30
ENG1323 .D PES . M
#3
Naphthalene(CCC)
Concen: 2.59 ng/uL
RT: 22.30 min Scan# 1577
Delta R.T. 0.02 min
Lab File: ENG1323.D
Acq: 19 May 99 1:22 pm
Tgt Ion:128 Resp: 3200394
Ion Ratio Lower Upper
128 100
127 14.2 0.0 60.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Wea May 2b 14:06:14
HP 5989B
Page 3
-------
Abundance
4000000 :
3000000 :
2000000:
1000000 :
o :
rime-->
Abundance
4000000 '.
2000000.
0 '
Iime-->
TIC: EMG1323.D
J \
23.80 24.00 24.20
Ion 152.00 (151.70 to 152.70): ENG
23.97
A
Jl
23 led 24.00 ' ' 24l 20
Abundance
1000000 J
500000 .
0
rime-->
TIC: ENG1323.D
J\
26120 ' ' 26 Ud
Abundancelon 160.00 (159.70 to 160.70): ENG
1500000 .
1000000 -
500000.
0
Time-->
26.30
A
i \
J\^
26120 ' ' 26140
#4
2-Methlynaphthalene-dlO
Concen: 22.98 ng/uL
RT: 23.97 min Scan# 1934
Delta R.T. 0.02 min
Lab File: ENG1323.D
Acq: 19 May 99 1:22 pm
Tgt Ion:152 Resp:12972380
Ion Ratio Lower Upper
100
152
0
0
0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
#5
Acenaphthylene-d8
Concen: 2.79 ng/uL
RT: 26.30 min Scan# 2452
Delta R.T. 0.01 min
Lab File: ENG1323.D
Acq: 19 May 99 1:22 pm
Tgt Ion:160 Resp: 3135459
Ion
160
0
0
0
Ratio
100
0.0
0.0
0.0
Lower Upper
0.0
0.0
0.0
0.0
0.0
0.0
OCC38-2S
ENGT323.DPBS.M
wea way 26 i4:0t>:iv iyyy
HP 5989B
Page 4
-------
Abundance
1000000 .
500000 '.
0
lime - - >
Abundance
80000 J
60000 .
40000 .
20000 .
0
rime-->
TIC: Et
~A ^J
IG1323.D
1 1
'25.50' Veio'o' ^isis'o' '2?! do' ' ' '
Ion 152.00 (151.70 to 152.70): ENG
Ion 153.00 (152.70 to 153.70): ENG
1
11
- . / \
1 1 1 1 1 1 1 1 I 1 I i T -T 1 1 1 1 1 1 1 \ —
25 50 26.00 26.50 27.00
#6
Acenaphthylene
Concen: 0.00 ng/uL
Expected RT: 26.32 min
Lab File: ENG1323.D
Acg: 19 May 99 1:22 pm
Tgt Ion: 152
Ion Exp Ratio
152 100
153 15.0
0 0.0
0 0.0
Abundance TIC: ENG1323.D
800000 .
600000 .
400000 :
200000.
0 .
.
rime--> 26160 26170 26!s6
Abundance
1000000 .
500000.
0.
Ion 164.00 (163.70 to 164.70): ENG
26.72
A
J V
Time--> 26le6 26170 ' 26!s6
#7
Acenapht hene - dl 0
Concen: 2.97 ng/uL
RT: 26.72 min Scan# 2515
Delta R.T. 0.01 min
Lab File: ENG1323.D
Acq: 19 May 99 1:22 pm
Tgt Ion: 164 Resp: 2208367
Ion Ratio Lower Upper
164 100
0 0.0 0.0 0.0
On n on no
u . u u . u u.u
0 0.0 0.0 0.0
0003813
HP 5989B
Page 5
-------
Abundance
1000000.
500000 .
0 .
Time-->
Abundance
80000 J
60000 :
40000 :
20000 :
o
Time-->
^~A
1
r*s^
PIC: ENG1323.D
1
'26100 26150 27^00 27^50 '
Ion 154.00 (153.70 to 154.70): ENG
Ion 153.00 (152.70 to 153.70): ENG
/
u
/|
\
- r A n /w\
/ "\
2(5 loo 26l50 27!oO 27i50
#8
Acenaphthene(CCC)
Concen: 0.00 ng/uL
Expected RT: 26.79 min
Lab File: ENG1323.D
Acq: 19 May 99 1:22 pm
Tgt Ion: 154
Ion Exp Ratio
154 100
153 86.8
0 0.0
0 0.0
Abundance
1000000 .
500000.
0 .
Time-->
Abundance
.
1000000^
500000.
0 "
Time-->
TIC: ENG1323.D
1
/
J V
2 VI 80 27190 28 100 28llO 28120
Ion 176.00 (175.70 to 176.70): ENG
28.02
A
J \
27|80' 27190' '28loo' 28ll'o' Velio' '
#9
Flu
Con
RT:
T-\ — n
1JG-L
Lab
Acq
Tgt
Ion
176
0
0
0
Concen: 3.18 ng/uL
28.02 min Scan# 2711
a R.T. 0.01 min
File: ENG1323.D
Acq: 19 May 99 1:22 pm
Tgt Ion:176 Resp: 2569556
Ratio Lower Upper
100
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
ENG1323.DPES.M
Wea May 26 14:06:23 1999
HP 5989B
Page 6
-------
Abundance
1000000-
500000 .
0.
rime - - >
Abundance
6000 :
4000:
2000 .
0
Time-->
TIC: El
j
1G1323 .D
27l bo' 271 50 28.00 28150 29! 00
Ion 166.00
Ion 165.00
27lbo' '27!5
(165.70 to 166.70): ENG
(164.70 to 165.70) : ENG
I
rd^fcjv^^
o' '28.00' '218! so ' '29! bo'
#10
Fluorene
Concen: 0.00 ng/uL
Expected RT: 28.08 min
Lab File: ENG1323.D
Acq: 19 May 99 1:22 pm
Tgt Ion: 166
Ion Exp Ratio
166 100
165 76.2
0 0.0
0 0.0
ENC
Sundance
1500000 :
1000000 :
500000 :
o :
Time-->
Abundance
1500000 .
1000000 .
500000 .
0
rime - - >
TIC: ENG1323.D
1 1
J V ^
' s'olsb ' ' ioUb ' ' s'olsb ' ' s'oleb '
Ion 188.00 (187.70 to 188.70): ENG
Ion 94.00 (93.70 to 94.70): ENG13
30.45
A
_J\_^_
' s'oisb ' 'soUo' 'iolsb' ' ioleb '
ri323.D PES.M wea May 26 14:06:26 iyyy
#11
Phenanthrene-dl0
Concen: 2.73 ng/uL
RT: 30.45 min Scan# 3080
Delta R.T. 0.01 min
Lab File: ENG1323.D
Acq: 19 May 99 1:22 pm
Tgt Ion:188 Resp: 3416597
Ion
188
94
0
0
Ratio
100
30.1
0.0
0.0
Lower Upper
15.1
0.0
0.0
45.1
0.0
0.0
OC03S5:
HP 5989B
Page 7
-------
Abundance
1500000 J
1000000 :
500000:
o :
Time -->
Abundance
8000 :
6000.
4000 .
2000 .
0 -
Time -->
' ' TIC: ENG1323.D
' \
v_
30.45 30150 30.55
Ion 178.00 (177.70 to 178.70): ENG
Ion 176.00 (175.70 to 176.70): ENG
30.50 ^
y^\^ ^/L
3ol45 ' ' 30l50 ' ' 30l55
Abundance
1500000 .
1000000 .
500000 J
0 "
Time-->
Abundance
1500000 .
1000000.
500000.
0
rime-->
TIC: ENG1323.D
7 L yv
'abl-io' 'sblso' 'sb'e'o 'sblvo' so! so'
Ion 188.00 (187.70 to 188.70): ENG
Ion 94.00 (93.70 to 94.70): ENG13
A
\
L\
//\\ 30.58
/ \^ ^
'3o!4o' 'sbls'o' sbleo' 'sblvo' 'so! so'
#12
Phenanthrene
Concen: 0.00 ng/uL
RT: 30.50 min Scan# 3089
Delta R.T. 0.01 min
Lab File: ENG1323.D
Acq: 19 May 99 1:22 pm
Tgt Ion:178 Resp: 6104
Ion Ratio Lower Upper
178 100
176 0.0 10.1 30.1#
0 0.0 0.0 0.0
0 0.0 0.0 0.0
#13
Anthracene-dl0
Concen: 0.34 ng/uL
RT: 30.58 min Scan# 3101
Delta R.T. 0.01 min
Lab File: ENG1323.D
Acq: 19 May 99 1:22 pm
Tgt Ion:188 Resp: 371730
Ion
188
94
0
0
Ratio
100
30.3
0.0
0.0
Lower Upper
15.1
0.0
0.0
45.1
0.0
0.0
ENGITZ3TD
Wea May 2b 14:06:29 1999
HP 5989B
Page 8
-------
Abundance
1500000 J
1000000 :
500000 :
0 '
Time-->29
Abundance
10000.
'
5000 1
0
rime-->29
TIC:
1
ENG1323 .D
u
! 50 ' ' 30 ! 00 ' ' 30 1 50 ' ' 31 1 00 ' ' 31 1 50 '
Ion 178.00 (177.70 to 178.70): ENG
Ion 176.00 (175.70 to 176.70): ENG
ft Ik A ,
1HA»JU^^
1 50 ' ' 30 1 00 ' 30 1 50 ' 31 ! 00 ' ' 31 1 50
#14
Anthracene
Concen: 0.00 ng/uL
Expected RT: 30.62 rain
Lab File: ENG1323.D
Acq: 19 May 99 1:22 pm
Tgt Ion: 178
Ion Exp Ratio
178 100
176 20.0
0 0.0
0 0.0
ENb
Abundance
1500000 J
1000000 J
500000 .
0 '
Time-->
Abundance
1500000.
1000000.
500000 -
0
Time-->
TIC: ENG1323.D
]{
33U6 ' ' 33!e6 ' ' 33ls6
Ion 212.00 (211.70 to 212.70): ENG
Ion 106.00 (105.70 to 106.70): ENG
33.58
ft
A
33140 33!e6 33180
l.i2.i.D PES.M Wea May 26 14:06:32 1999
#15
Fluoranthene-dl0
Concen: 2.90 ng/uL
RT: 33.58 min Scan# 3621
Delta R.T. 0.01 rain
Lab File: ENG1323.D
Acq: 19 May 99 1:22 pm
Tgt Ion:212 Resp: 3594848
Ion
212
106
0
0
Ratio
100
35.6
0.0
0.0
Lower
15.1
0.0
0.0
Upper
45.1
0.0
0.0
HP 5989B
Page 9
-------
Abundance
6000000 J
4000000 :
2000000 J
o :
Time--> 3
Abundance
20000 .
10000 _
0
Time--> 3
t\
HC: ENG1323.D
I
A A
r 1 i — i — i — i — i — i — i — i — T"' | i i i i 1 i i i i | ii
2150 33.00 33.50 34100 34.50
Ion 202.00
Ion 101.00
(201.70 to 202.70): ENG
(100.70 to 101.70) : ENG
rAyW^Wb^rArW
I
L
2! so' 'sslo'o' '33! so' '34lo'o' '34 50 '
#16
Fluoranthene(CCC)
Concen: 0.00 ng/uL
Expected RT: 33.62 min
Lab File: ENG1323.D
Acq: 19 May 99 1:22 pm
Tgt Ion: 202
Ion Exp Ratio
202 100
101 27.0
0 0.0
0 0.0
ENG
Abundance
6000000 J
4000000 :
2000000:
0."
Time-->
Abundance
1000000-
500000.
0
Time-->
TIC: ENG1323.D
M
A r
34lo6 34120 34140 '
Ion 212.00 (211.70 to 212.70): ENG
Ion 106.00 (105.70 to 106.70): ENG
34.26
n
A
Al A
34lo6 34120 34140 '
1323. D PES.M Wed May 26 14:Ob:35 1999
#17
Pyrene-dlO
Concen: 2.73 ng/uL
RT: 34.26 min Scan# 3723
Delta R.T. 0.01 min
Lab File: ENG1323.D
Acq: 19 May 99 1:22 pm
Tgt Ion:212 Resp: 3709634
Ion
212
106
0
0
Ratio
100
39.9
0.0
0.0
Lower Upper
17.1
0.0
0.0
51.1
0.0
0.0
HP 5989B
Page 10
-------
Abundance
^
6000000 :
4000000 :
2000000 :
0 -
rime-->
Abundance
20000 .
10000 .
0 .
Titne-->
TIC: ENG1323.D
1
t\ t\ \
33.50 34 00 34.50 35.00
Ion 202.00 (201.70 to 202.70): ENG
Ion 101.00 (100.70 to 101.70): ENG
,/W\£\rr£^rAW
.J
<=-- — ^r^^r~
'33! SO' 34 loo' 34!50' 'sslo'o' ' ' '
#18
Pyrene
Concen: 0.00 ng/uL
Expected RT: 34.30 min
Lab File: ENG1323.D
Acg: 19 May 99 1:22 pm
Tgt Ion: 202
Ion Exp Ratio
202 100
101 32.0
0 0.0
0 0.0
ENC
Abundance
6000000 J
4000000 -
2000000 J
0 -
Time-->
Abundance
4000000 .
2000000 .
0
rime-->
TIC: ENG1323.D
I
/\ / I
34 40 34.60 34 80
Ion 244.00 (243.70 to 244.70): ENG
Ion 122.00 (121.70 to 122.70): ENG
34.59
A
H
34140 34160 34180
1323. D PES.M Wed May 26 14:06:39 lyyy
#19
p-Terphenyl-d!4
Concen: 16.75 ng/uL
RT-. 34.59 min Scan# 3772
Delta R.T. 0.02 min
Lab File: ENG1323.D
Acq: 19 May 99 1:22 pm
Tgt Ion:244 Resp:17226962
Ion Ratio
244 100
122 27.7
0 0.0
0 0.0
Lower Upper
13.6 40.6
0.0 0.0
0.0 0.0
OCC3S55
HP 5989B
Page 11
-------
Abundance
800000 .
600000.
400000.
200000 .
Time--> 38!70 38 i 80 38 ! 90' '39! 00 '
TIC: ENG1323.D
T
Abundance I on 240.00 (239.70 to 240.70)
Ion 120.00 (119.70 to 120.70)
800000 J
ENG
ENG
Time--> 38.70 38.80 38.90 39.00
#20
Benzo(a)anthracene-d!2
Concen: 2.59 ng/uL
RT: 38.89 min Scan# 4419
Delta R.T. 0.01 min
Lab File: ENG1323.D
Acq: 19 May 99 1:22 pm
Tgt Ion:240 Resp: 2263675
Ion
240
120
0
0
Ratio
100
32.9
0.0
0.0
Lower Upper
15.1
0.0
0.0
45.1
0.0
0.0
ENG
Abundance
800000 :
600000 .
400000 :
200000 .
0
Time - - >
Abundance
15000 J
10000 :
5000 :
0 '
rime-->
TIC: ENG1323.D
II
1
«l
'33 o'o' Vsls'o' '319 loo' Vgls'o' '
Ion 228.00 (227.70 to 228.70): ENG
Ion 114.00 (113.70 to 114.70): ENG
/
r-JU
1
h
\
V
[" " ~ -
Vs o'o ' Vslso' '39! o'o ' 's'gls'o' '
1323. D PES.M Wed May 26 14:06:42 1999
#21
Benzo(a)anthracene
Concen: 0.00 ng/uL
Expected RT: 38.98 min
Lab File: ENG1323.D
Acq: 19 May 99 1:22 pm
Tgt Ion: 228
Ion Exp Ratio
228 100
114 25.0
0 0.0
0 0.0
OCC3S5S
HP 5989B
Page 12
-------
Abundance '
800000 :
rime - - >
TIC: ENG1323.D
38.80
39.00
39.20
(AbundanceIon 240.00 (239.70 to 240.70)
Ion 120.00 (119.70 to 120.70)
39.04
800000 j
ENG
ENG
600000 J
400000
200000:
Time - - >
38.80
39.00
39.20
#22
Chrysene-dl2
Concen: 3.17 ng/uL
RT: 39.04 min Scan# 4443
Delta R.T. 0.01 min
Lab File: ENG1323.D
Acq: 19 May 99 1:22 pm
Tgt Ion:240 Resp: 3356358
Ion Ratio Lower Upper
240 100
120 29.5 15.1 45.1
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance
800000 :
600000 J
400000:
200000:
rime-->
TIC: ENG1323.D
38.50 39.00 39.50 40.00
Abundance Ion 228.00 (227.70 to 22877(3): ENG
lion 114.00 (113.70 to 114.70): ENG
15000 J
10000:
5000:
o:
rime-->
38.50 39.00 3SK504C)TOO
ENGT3~2~3TB
#23
Chrysene(CCC)
Concen: 0.00 ng/uL
Expected RT: 39.16 min
Lab File: ENG1323.D
Acq: 19 May 99 1:22 pm
Tgt Ion: 228
Ion Exp Ratio
228 100
114 25.0
0 0.0
0 0.0
OCC335?
b . M
Wed May 2b 14:0b :45 1999
HP 5989B
Page 13
-------
Abundance
600000 .
400000 .
200000 .
Time-->
TIC: EWG1323.D
45.70 45.80
45.90 46.00
46:iO
ISbundancelon 264. 00 (263.70 to 264.70): ENG
Jlon 132.00 (131.70 to 132.70): ENG
45.70 45 80 45.90 46.00 46.10
#24
Benzo(b)fluoranthene-d!2
Concen: 3.44 ng/uL
RT: 45.89 min Scan# 5495
Delta R.T. 0.02 min
Lab File: ENG1323.D
Acq: 19 May 99 1:22 pm
Tgt Ion:264 Resp: 2677827
Ion Ratio
264 100
132 35.4
0 0.0
0 0.0
Lower Upper
15.1
0.0
0.0
45.1
0.0
0.0
Abundance
600000 '.
400000 .
200000 .
Time--> 45.00 45.50 46.00 46.50 47.00
TIC: ENG1323.D
Abundancelon 252.00 (251.70 to 252.70): ENG
Ion 126.00 (125.70 to 126.70): ENG
10000 J
5000.
rime--> 45.00
i—i—I—i—i—i—I—1—i—i—i—r—|—i—r
45.50 46.00 46.50 47100
ENG1J23.D—FESTRT
Wed May 2fc 14:06:48 1999
#25
Benzo(b)fluoranthene
Concen: 0.00 ng/uL
Expected RT: 46.07 min
Lab File: ENG1323.D
Acq: 19 May 99 1:22 pm
Tgt Ion: 252
Ion Exp Ratio
252 100
126 25.0
0 0.0
0 0.0
HP 5989B
Page 14
-------
Abundance
600000.
400000.
200000 1
Time--> 45.80
TIC: ENG1323.D
46.00
46.20
Abundance Ion 264.00 (263.70 to 264.70)
Ion 132.00 (131.70 to 132.70)
46.09
400000.
200000 -
ENG
ENG
Time--> 45.80
46.00
46.20
Abundance
600000 .
400000 -
200000 1
Iime-->
TIC: ENG1323.D
0
45 so eoo eso 47 oo
Abundance Ion 252.00 (251.70 to 252.70): ENG
Ion 126.00 (125.70 to 126.70): ENG
10000 J
#26
Benzo(k)fluoranthene-d!2
Concen: 2.85 ng/uL
RT: 46.09 min Scan# 5526
Delta R.T. 0.01 min
Lab File: ENG1323.D
Acq: 19 May 99 1:22 pm
Tgt Ion:264 Resp: 3024238
Ion Ratio
264 100
132 38.7
0 0.0
0 0.0
Lower Upper
15.1
0.0
0.0
45.1
0.0
0.0
5000 .
rime-->
4550 46oo es 47oo
. D PES.M
Wed May
14:0b:51 1999
#27
Benzo(k)fluoranthene
Concen: 0.00 ng/uL
Expected RT: 46.23 min
Lab File: ENG1323.D
Acq: 19 May 99 1:22 pm
Tgt Ion: 252
Ion Exp Ratio
252 100
126 25.0
0 0.0
0 0.0
HP 5989B
Page 15
-------
Abundance
20000:
15000 :
10000:
5000:
Time--> 4?!50 48.00 48.50 49.00 49.50
TIC: ENG1323.D
Abundancelon 264.00 (263.70 to 264.70): ENG
132.00 (131.70 to 132.70): ENG
5000 -
Time--> 47150 48.00 48150 49.00 49.50
Abundance
20000 :
15000:
10000:
5000:
TIC: ENG1323.D
0
Time-->
48lod
49.00
50.00
#28
Benz o(a)pyrene-dl2
Concen: 0.00 ng/uL
Expected RT: 48.54 min
Lab File: ENG1323.D
Acq: 19 May 99 1:22 pm
Tgt Ion: 264
Ion Exp Ratio
264 100
132 30.0
0 0.0
0 0.0
Abundance Ion 252.00 (251.70 to 252.70): ENG
Ion 126.00 (125.70 to 126.70): ENG
80004
6000
4000 :
2000:
rime-->
48.00
49100
50.00
ENG1323.DPES.M
Wed May 26 14:06:54 1999
#29
Benzo(a)pyrene(CCC)
Concen: 0.00 ng/uL
Expected RT: 48.74 min
Lab File: ENG1323.D
Acq: 19 May 99 1:22 pm
Tgt Ion: 252
Ion Exp Ratio
252 100
126 25.0
0 0.0
0 0.0
HP 5989B
Page 16
-------
[Abundance
200000.
100000 .
TIC: ENG1323.D
Time--> 60.50
i — i — I — i — i
61.00
61.50 62.00 62.50
Abundance Ion 288.00 (287.70 to 288.70): ENG
200000 -i
61.52
150000 J
100000:
50000:
o:
Time--> 60.50 61.00 61.50 62.00 62.50
Abundance
200000 .
100000 .
Time-->
TIC: ENG1323.D
61.00
62.00
63.00
Abundance Ion 276.05 (275.75 to 276.75): ENG
SOUO lion 138.00 (137.70 to 138.70): ENG
6000 J
4000 J
2000:
o:
rime-->
61.00
62.00
63100
#30
Indeno(l,2,3-cd)pyrene-dl2
Concen: 2.54 ng/uL
RT: 61.52 min Scan# 8111
Delta R.T. 0.04 min
Lab File: ENG1323.D
Acq: 19 May 99 1:22 pm
Tgt Ion:288 Resp: 2404872
Ion Ratio Lower Upper
288 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
ENGTJ2T7D PES .M
#31
Indeno(1,2,3 -cd)pyrene
Concen: 0.00 ng/uL
Expected RT: 61.83 min
Lab File: ENG1323.D
Acq: 19 May 99 1:22 pm
Tgt Ion: 276.05
Ion Exp Ratio
276 100
138 64.0
0 0.0
0 0.0
wed May 2b 14:06:be
HP 5989B
OCC33>ci
Page 17
-------
Abundance
200000-
100000.
TIC: EMG1323.L)
Time-->
-I 1 1 r
61.00
61.50
62lo6
Abundancelon 292.00 (291.70 to 292.70): ENG
100000 .
61.46
50000 -
Time - - >
61.00
6i:so
62.00
Abundance
200000.
100000 -
TIC: ENG1323.D
0
-i 1 1 r
61.00
Time--> 6i:OQ 62.00 63.00
Abundancelon 278.00 (277.70 to 278.70): ENG
jlon 139.00 (138.70 to 139.70): ENG
6000 J
4000 J
2000:
rime--> 61.00 62lOO 63lOO
#32
Dibenz (a, h) anthracene-d!4
Concen: 2.38 ng/uL
RT: 61.46 min Scan# 8099
Delta R.T. 0.02 min
Lab File: ENG1323.D
Acq: 19 May 99 1:22 pm
Tgt Ion:292 Resp: 1320918
Ion Ratio Lower Upper
292 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
ENGT3~2T7]
#33
Dibenz(a,h)anthracene
Concen: 0.00 ng/uL
Expected RT: 61.85 min
Lab File: ENG1323.D
Acq: 19 May 99 1:22 pm
Tgt Ion: 278
Ion Exp Ratio
278 100
139 25.0
0 0.0
0 0.0
wea way ^b ii:u/:ui
HP 5989B
Page 18
-------
Abundance
80000:
eoooo:
40000:
20000:
Time - - >
TIC: ENG1323.D
64:50
65.00
65.50
Abundance I on 288.00 (287.70 to 288.70)
65.08
50000 .
ENG
0 .
Time-->
64150
65.00
65.50
#34
Benzo(g,h,i)perylene-d!2
Concen: 1.52 ng/uL
RT: 65.08 min Scantt 8836
Delta R.T. 0.02 min
Lab File: ENG1323.D
Acq: 19 May 99 1:22 pm
Tgt Ion:288 Resp: 1134080
Ion Ratio Lower Upper
288 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance
soooo:
60000 :
40000:
20000 :
0 '
Time- -> 64
Abundance
6000 1
4000 J
2000.
0.
rime-->64
TIC: ENG1323.D
l\
\
1 J v_
iod ' ' esiod ' ' 66 loo
Ion 276.00 (275.70 to 276.70): ENG
Ion 138.00 (137.70 to 138.70): ENG
y\_
j*™fn* ^/~^~~~~^^
tlod ' ' eslod ' ' eelod
#35
Benzo(g,h,i)perylene
Concen: 0.00 ng/uL
Expected RT: 65.44 min
Lab File: ENG1323.D
Acq: 19 May 99 1:22 pm
Tgt Ion: 276
Ion Exp Ratio
276 100
138 25.0
0 0.0
0 0.0
000386
PES.M
wea way
i4:07:Ub iyyy
HP 5989B
Page 19
-------
ENG1324.XLS
Quantitation Report Summary
Data File
Date Analyzed:
Sample ID
Method ID
Operator
Instrument
Compounds
Naphthalene(CCC)
Acenaphthylene
Acenaphthene(CCC)
Fluorene
Phenanthrene
Anthracene
Fluoranthene(CCC)
Pyrene
Benzo(a)anthracene
Chrysene(CCC)
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Benzo(a)pyrene(CCC)
lndeno(1,2,3-cd)pyrene
Dibenz(a,h)anthracene
Benzo(g,h,i)perylene
ENG1324.D
05/19/99|
PES INLET BLANK 4/2/99
PES
JEMcCartney
HP 5989B
Area
2830282
0
0
0
52748
0
0
33271
0
52986
0
0
0
0
0
0
* PQL - practical quantitation limit
Surrogate Recoveries
Compound
Naphthalene-d8
Acenaphthylene-d8
Acenaphthene-d10
Fluorene-d10
Phenanthrene-d10
Anthracene-d10
Fluoranthene-d10
Pyrene-d10
Benzo(a)anthracene-d12
Chrysene-d12
Benzo(b)fluoranthene-d12
Benzo(k)fluoranthene-d12
Benzo(a)pyrene-d12
Indeno(1,2,3-cd)pyrene-d12
Dibenz(a,h)anthracene-d14
Benzo(g,h,i)perylene-d12
Recovery Standard
Compound
2-Methlynaphthalene-d10
p-Terphenyl-d14
Compiled by:
Reviewed by:
Reviewed by:
Cone, (ng/
2.97
1.93
2.80
2.95
2.78
0.41
3.04
2.83
2.74
3.41
4.35
3.28
0.00
3.07
3.29
2.13
Cone.
(ng/ML)
2.489
0.000
0.000
0.000
0.038
0.000
0.000
0.020
0.000
0.039
0.000
0.000
0.000
0.000
0.000
0.000
ML)
Concentration (ng/uL)
24.18
17.55
/
^"
PQL*
(ng/ML)
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
tsiz. >*r/3.
sn ^&&t*»* \////"t
-^^L^^^JS^L^r^. ^>\d?b
Cone.
(ng/sample)
2489.4
0.0
0.0
0.0
37.9
L_ 0'°
0.0
20.4
0.0
39.3
0.0
0.0
0.0
0.0
0.0
0.0
% Recovery
74.26
48.14
69.91
73.79
69.62
10.29
76.10
70.69
68.38
85.34
108.82
81.96
0.00
76.66
82.32
53.15
% Recovery
60.45
43.88
\CirFS
Cone, (ng/sample)
w/ Surr. correction
3352.2
0.0
0.0
0.0
54.4
0.0
0.0
28.9
0.0
46.1
0.0
0.0
0.0
0.0
0.0
0.0
-------
Quantitation Report
Data File
Acg On
Sample
Misc :
Quant Time: May 26 14:13 1999
C:\HPCHEM\1\DATA\9919\ENG1324.D
19 May 99 2:37 pm
PES INLET BLANK 4/2/99
Vial: 4
Operator: JEMcCartney
Inst : HP 5989B
Multiplr: 1.00
Method
Title
Last Update
Response via
C:\HPCHEM\1\METHODS\PES.M
Mon May 24 16:23:27 1999
Multiple Level Calibration
Internal Standards
R.T. Qlon Response Cone Units Dev(Min)
1)
2 , 2 -Dif luorobiphenyl
24
.60
190
3206849
System Monitoring Compounds
2)
4)
5)
7)
9)
11)
13)
15)
17)
19)
20)
22)
24)
26)
28)
30)
32)
34)
Naphthalene-d8
2-Methlynaphthalene-dlO
Acenaphthylene-d8
Acenapht hene - dl 0
Fluorene-dlO
Phenant hrene - dl 0
Anthracene-dlO
Fluor ant hene - dl 0
Pyrene-dlO
p-Terphenyl-d!4
Benzo (a) anthracene -dl 2
Chrysene-dl2
Benzo (b) f Iuoranthene-dl2
Benzo (k) f Iuoranthene-dl2
Benzo (a) pyrene-d!2
Indenod, 2, 3-cd)pyrene-dl2
Dibenz (a, h) anthracene -d!4
Benzo (g, h, i) perylene-d!2
22
23
26
26
28
30
30
33
34
34
38
39
45
46
0
61
61
65
.24
.97
.30
.72
.02
.45
.58
.58
.26
.60
.89
.05
.90
.10
.00
.53
.47
.08
136
152
160
164
176
188
188
212
212
244
240
240
264
264
264
288
292
288
2903976
12536730
1984677
1910998
2188741
3200436
411025
3463258
3531763
16582645
2192094
3314701
3112515
3191755
0
2661551
1678032
1461208
Target Compounds
3)
6)
8)
10)
12)
14)
16)
18)
21)
23)
25)
27)
29)
31)
33)
35)
Naphthalene (CCC)
Acenaphthylene
Acenaphthene (CCC)
Fluorene
Phenanthrene
Anthracene
Fluoranthene (CCC)
Pyrene
Benzo (a) anthracene
Chrysene(CCC)
Benzo (b) f luoranthene
Benzo (k) f luoranthene
Benzo(a)pyrene(CCC)
Indeno ( 1 , 2 , 3 - cd ) py r ene
Dibenz (a, h) anthracene
Benzo (g,h, i)perylene
22
0
0
0
30
0
0
34
0
39
0
0
0
0
0
0
.30
.00
.00
.00
.50
.00
.00
.32
.00
.13
.00
.00
.00
.00
.00
.00
128
152
154
166
178
178
202
202
228
228
252
252
252
276
278
276
2830282
52748
33271
52986
5.00 ng/uL
0.
02
%Recovery
2.97 ng/uL
24.18 ng/uL
1.93 ng/uL
2.80 ng/uL
2.95 ng/uL
2.78 ng/uL
0.41 ng/uL
3 . 04 ng/uL
2.83 ng/uL
17.55 ng/uL
2.74 ng/uL
3.41 ng/uL
74.
60.
48.
69.
73.
69.
10.
76.
70.
43.
68.
85.
4.35 ng/uL 108.
3.28 ng/uL
0.00 ng/uL
3.07 ng/uL
3.29 ng/uL
2 . 13 ng/uL
81.
0.
76.
82.
53.
26%
45%
14%
91%
79%
62%
29%
10%
69%
88%
38%
34%
82%
96%
00%
66%
32%
15%
Qvalue
2.49 ng/uL
Not Detected
Not Detected
Not Detected
0 . 04 ng/uL
Not Detected
Not Detected
0.02 ng/uL
Not Detected
0.04 ng/uLm
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
000
38:
89
94
98
50
""* *~*
(#) = qualifier out of range (m) = manual integration
ENG1324.D PES.M Wed May 26 14:14:29 1999 HP 5989B
Page 1
-------
Quantitation Report
C:\HPCHEM\1\DATA\9919\ENG1324 .D
19 May 99 2:37 pm
PES INLET BLANK 4/2/99
Data File
Acg On
Sample
Misc :
Quant Time: May 26 14:13 1999
Method
Title
Last Update
Response via
C:\HPCHEM\1\METHODS\PES.M
Mon May 24 16:23:27 1999
Multiple Level Calibration
Vial: 4
Operator: JEMcCartney
Inst : HP 5989B
Multiplr: 1.00
Abundance
8000000 .
7500000-
7000000-
6500000.
6000000-
5500000 -
5000000 .
4500000-
4000000:
3500000:
3000000 :
2500000:
2000000 :
1500000-
1000000:
500000:
0 :
Time-->
, , Jj.
4s
23s
J
LtW
20^00
1
5?
TIC: ENG1324.D
1.
Us i^
9
%
s
i:
i
30.
is
2
00
1
L
'S
s
22s
20s 24&
3Q8
5 23 j 34S
_ 1 11 .
40.00 50.00 60.00
000386"
ENG1324.D PES.M
Wed May 26 14:14:37 1999
HP 5989B
Page 2
-------
Abundance
1500000.
1000000.
500000 .
rime--> 22110
TIC :ENG1324.D
22.20
22.30
Abundance!on 136.00 (135.70 to 136.70): ENG
Ion 68.00 (67.70 to 68.70): ENG13
22.24
1000000.
500000 -
rime-->
22:iO
22.20
22.30
Abundance
1500000 .
1000000 .
500000 .
rime-->
TIC: ENG1324.D
22.20
22:30
#2
Naphthalene-d8
Concen: 2.97 ng/uL
RT: 22.24 min Scan# 1568
Delta R.T. 0.01 min
Lab File: ENG1324.D
Acq: 19 May 99 2:37 pm
Tgt Ion:136 Resp: 2903976
Ion Ratio Lower Upper
100
136
68
0
0
0.0
0.0
0.0
10.1
0.0
0.0
30.1#
0.0
0.0
AbundanceIon 128.00 (127.70 to 128.70)
Ion 127.00 (126.70 to 127.70)
1000000J 22.30
500000 .
0-
ENG
ENG
rime-->
22:20
22:30
ENG1TZ9TD PES.M
#3
Naphthalene(CCC)
Concen: 2.49 ng/uL
RT: 22.30 min Scan# 1576
Delta R.T. 0.01 min
Lab File: ENG1324.D
Acq: 19 May 99 2:37 pm
Tgt Ion:128 Resp: 2830282
Ion
128
127
0
0
Ratio
100
14.2
0.0
0.0
Lower Upper
0.0
0.0
0.0
60.0
0.0
0.0
Wed. May 2614:14:4l) 1999
HP 5989B
OCC3358
Page 3
-------
Abundance
4000000 :
3000000:
2000000:
1000000:
TIC: ENG1324.&
Time-->
23.80
24.00
24.20
Abundance Ion 152.00 (151.70 to 152.70): ENG
4000000 -
2000000 .
23.97
Time-->
23.80
24 00
24.20
Time-->
TIC: ENG1324.D
€00000:
400000:
200000:
26.10 26.20 26 30 26.40 26.50
Abundance I on 160.00 (159.70 to 160.70): ENG
800000.
600000.
400000.
200000-
26.30
rime-->
2(5 lio' 2 is! 20' 215 lio'
#4
2-Methlynaphthalene-dlO
Concen: 24.18 ng/uL
RT: 23.97 min Scan# 1932
Delta R.T. 0.02 min
Lab File: ENG1324.D
Acq: 19 May 99 2:37 pm
Tgt Ion:152 Resp:12536730
Ion Ratio Lower Upper
152 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
ENG1324.DPES.M
#5
Acenaphthylene-d8
Concen: 1.93 ng/uL
RT: 26.30 min Scan# 2451
Delta R.T. 0.01 min
Lab File: ENG1324.D
Acq: 19 May 99 2:37 pm
Tgt Ion:160 Resp: 1984677
Ion Ratio
160 100
0 0.0
0 0.0
0 0.0
Lower Upper
0.0
0.0
0.0
0.0
0.0
0.0
0003833
wea May 26 14:14:43
HP 5989B
Page 4
-------
^TOBS6
eooooo :
400000:
200000 .
0-
Time-->
Abundance
60000-
40000 .
20000.
0
Time-->
TIC: EN
sJ\ /
G1324.
I 1
D
A_
'25! so' '26 loo' Yelso' '27 loo' ' ' '
Ion 152.00 (
Ion 153.00 (
_J
151.70 to 152.70): ENG
152.70 to 153.70) : ENG
1
^Sj^-^L^-e^sar^V^-- /
TIC: ENG1324.D
26.60
26.70
26180
Abundancelon 164.00 (163.70 to 164.70): ENG
800000 :
600000 J
400000:
200000:
26.72
Time-->
2670
#6
Acenaphthy1ene
Concen: 0.00 ng/uL
Expected RT: 26.32 min
Lab File: ENG1324.D
Acq: 19 May 99 2:37 pm
Tgt Ion: 152
Ion Exp Ratio
152 100
153 15.0
0 0.0
0 0.0
ENG1324.DPES.M
Wed May 26 14:14:46
#7
Acenaphthene-dlO
Concen: 2.80 ng/uL
RT: 26.72 min Scan# 2514
Delta R.T. 0.01 min
Lab File: ENG1324.D
Acq: 19 May 99 2:37 pm
Tgt Ion:164 Resp: 1910998
Ion Ratio
164 100
0 0.0
0 0.0
0 0.0
Lower Upper
0.0
0.0
0.0
0.0
0.0
0.0
OCC
HP 5989B
33 rQ
Page 5
-------
Abundance TIC: ENG1324.D
800000.
600000.
400000:
200000.
0 J
Time - - >
Abundance
60000.
40000 J
20000-
0 '
Time - - >
n
^JU
'26lo'o' VelsV
Ion 1
Ion 1
/
54.00 (153.
53.00 (152.
I
ul
I
'26 loo' ^Isls'o'
i ,
27 loo 27! 50
70 to 154.70) : ENG
70 to 153.70) : ENG
W_^_ — J
L,
'27! do' '27150'
#8
Acenaphthene(CCC)
Concen: 0.00 ng/uL
Expected RT: 26.79 min
Lab File: ENG1324.D
Acg: 19 May 99 2:37 pm
Tgt Ion: 154
Ion Exp Ratio
154 100
153 86.8
0 0.0
0 0.0
ENG
Abundance
800000 .
600000 -
400000 .
200000 -
0.
Time-->
TIC: ENG1324.D
J {
27180 ' ' 28100 ' ' 28120
Abundancelon 176.00 (175.70 to 176.70): ENG
1000000 „
500000 .
0
Time-->
28.02
j[
27l80 ' ' 28lo6 ' ' 28120
1324. D PES.M wea May 2b 14:14:bU 1999
#9
Fluorene-dlO
Concen: 2.95 ng/uL
RT: 28.02 min Scan# 2710
Delta R.T. 0.01 min
Lab File: ENG1324.D
Acq: 19 May 99 2:37 pm
Tgt Ion:176 Resp: 2188741
Ion
176
0
0
0
Ratio
100
0.0
0.0
0.0
Lower Upper
0.0
0.0
0.0
0.0
0.0
0.0
oc
'C3S71
HP 5989B
Page 6
-------
Abundance
800000:
600000 .
400000 .
200000 .
0.
Time-->
Abundance
200000 .
150000 :
100000 :
50000 :
0 '
Time - - >
TIC : E]
J
STG1324.D
/I
1 J .
27 ido' '27 [so' '28.00' Vsls'o' Vsldo'
Ion 166.00 (165.70 to 166.70): ENG
Ion 165.00 (164.70 to 165.70): ENG
I . ... J.LA
2?1 do' '27 [so' '28 do' Vsls'o' 'islo'o'
Abundance
1500000J
1000000 J
500000:
rime-->
T1C:ENG1324.D
30.30
30.40
30.50
30.60
#10
Fluorene
Concen: 0.00 ng/uL
Expected RT: 28.08 min
Lab File: ENG1324.D
Acg: 19 May 99 2:37 pm
Tgt Ion: 166
Ion Exp Ratio
166 100
165 76.2
0 0.0
0 0.0
Abundance Ion 188.00 (187.70 to 188.70): ENG
1500000J
1000000.
500000J
Ion
94.00 (93.70 to 94.70): ENG13
30.45
Time-->
30.30
30!40
30.50
30.60
ENG1324 .D PEii . M
Wed. May 2b 14:14:53
#11
Phenanthrene-dl0
Concen: 2.78 ng/uL
RT: 30.45 min Scan# 3079
Delta R.T. 0.01 min
Lab File: ENG1324.D
Acq: 19 May 99 2:37 pm
Tgt Ion:188 Resp: 3200436
Ion
188
94
0
0
Ratio
100
31.6
0.0
0.0
Lower Upper
15.1
0.0
0.0
45.1
0.0
0.0
HP 5989B
OCC3872
Page 7
-------
TIC: ENG1324.D
Abundance
1500000J
1000000 '.
500000 J
0
Time--> 30140 30:45 30150
30160
Abundanceton 176.00 (177.70 to 178.70): ENG
Ion 176.00 (175.70 to 176.70): ENG
30.50
30000 .
20000:
10000 J
Time--> 30.40 30.45 30!50 30.55 30160
#12
Phenanthrene
Concen: 0.04 ng/uL
RT: 30.50 min Scan# 3088
Delta R.T. 0.01 min
Lab File: ENG1324.D
Acq: 19 May 99 2:37 pm
Tgt Ion:178 Resp: 52748
Ion Ratio Lower Upper
178 100
176 22.9 10.1 30.1
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance
15000004
1000000 .
500000-
rime - - >
TIC: ENG1324.D
30:50 30155 30.60 30165
Abundance Ion 188.00 (187.70 to 188.70): ENG
Jlon 94.00 (93.70 to 94.70): ENG13
1000000 .
500000-
0-
30.58
Time-->
30.50 30.55 30.60 30165
ENG1324 .D
#13
Anthracene-dl0
Concen: 0.41 ng/uL
RT: 30.58 min Scan# 3100
Delta R.T. 0.01 min
Lab File: ENG1324.D
Acq: 19 May 99 2:37 pm
Tgt Ion:188 Resp: 411025
Ion Ratio
188 100
94 29.9
0 0.0
0 0.0
Lower Upper
15.1
0.0
0.0
45.1
0.0
0.0
.M
Wed May 26 14:14:56 1999
HP 5989B
Page 8
-------
Abundance
1500000 :
1000000 :
500000 :
o :
rime-->29
Abundance
30000 .
20000 J
10000 J
0 ."
Time-->29
TIC:
^ j
ENG1324.D
LA
is'o' 's'o loo' 'a'ols'o' 'siio'o' 'sils'o'
Ion 178.00 (177
Ion 176.00 (175
^^^-~^7^-~f^=^=^^J/
.70 to 178.70) : ENG
.70 to 176.70) : ENG
LA^
Is'o' 's'olo'o' 's'o. so' 'siio'o' 'siis'o'
#14
Anthracene
Concen: 0.00 ng/uL
Expected RT: 30.62 min
Lab File: ENG1324.D
Acq: 19 May 99 2:37 pm
Tgt Ion: 178
Ion Exp Ratio
178 100
176 20.0
0 0.0
0 0.0
Abundance
1500000 J
1000000 J
500000 J
Time-->
TIC: ENG1324.D
33.40
33.60
33.80
Abundance Ion 212.00 (211.70 to 212.70) : ENG
3UUUUU"Ion 106.00 (105.70 to 106.70): ENG
33.58
1000000-
500000.
#15
Fluoranthene-dl0
Concen: 3.04 ng/uL
RT: 33.58 min Scan# 3619
Delta R.T. 0.01 min
Lab File: ENG1324.D
Acq: 19 May 99 2:37 pm
Tgt Ion:212 Resp: 3463258
Ion
212
106
0
0
Ratio
100
36.2
0.0
0.0
Lower Upper
15.1
0.0
0.0
45.1
0.0
0.0
ritne-->
33.40
33!60
33.80
ENG1324.DPES.M
wea May
14:14:53 iyyy
HP 5989B
Page 9
-------
Abundance
6000000:
4000000 '.
2000000 '.
0 '.
lime - - > 3
Abundance
150000 '.
100000^
50000 :
0
rime - - > 3
TIC: KNG1324.D
* A A 11
2.50 33100 33150 34:00 34.50
Ion 202.00 (201.70 to 202.70): ENG
Ion 101.00 (100.70 to 101.70): ENG
1
F^
H 1 1 1 1 1 1 1 1 — 1 P • ' I T " ! 1 1 ' i i i i ill
2.50 33.00 33.50 34.00 34.50
#16
Fluoranthene(CCC)
Concen: 0.00 ng/uL
Expected RT: 33.62 min
Lab File: ENG1324.D
Acq: 19 May 99 2:37 pm
Tgt Ion: 202
Ion Exp Ratio
202 100
101 27.0
0 0.0
0 0.0
Abundance
6000000 :
4000000 :
2000000:
o:
Time-->
Abundance
1000000^
500000.
0-
rime-->
TIC: ENG1324.D
1
A j
\
I
34100 341 20 34140 34160
Ion 212.00 (211.70 to 212.70):
Ion 106.00 (105.70 to 106.70):
34.26
A
A /
ENG
ENG
\
34100 34120 34l 40 34160
ENG1324.DFES.M
Pyrene-dlO
Concen: 2.83 ng/uL
RT: 34.26 min Scan# 3721
Delta R.T. 0.02 min
Lab File: ENG1324.D
Acq: 19 May 99 2:37 pm
Tgt Ion:212 Resp: 3531763
Ion Ratio Lower Upper
212 100
106 39.8 17.1 51.1
0 0.0 0.0 0.0
0 0.0 0.0 0.0
wea May 26 14:ib:02
HP 5989B
Page 10
-------
Abundance
1500000J
1000000.
500000.
0
rime--> 34!20
TIC: ENG1324.D
34:30
34:40
Abundance Ion 202.00 (201.70 to 202.70)
20000JIon 101.00 (100.70 to 101.70)
ENG
ENG
34.32
150004
10000J
5000:
rime--> 34.20
34.30
34.40
#18
Pyrene
Concen: 0.02 ng/uL
RT: 34.32 min Scan# 3729
Delta R.T. 0.02 min
Lab File: ENG1324.D
Acq: 19 May 99 2:37 pm
Tgt Ion:202 Resp: 33271
Ion Ratio Lower Upper
202 100
101 33.1 16.1 48.1
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance
6000000 '.
4000000 .
2000000 '.
rime-->
TIC: ENG1324.D
34i40
34:80
Abundance Ion 244.00 (243.70 to 244.70) : ENG
Ion 122.00 (121.70 to 122.70): ENG
34.60
4000000-
2000000.
ritne-->
34:40
34:60
34:80
#19
p-Terphenyl-d!4
Concen: 17.55 ng/uL
RT: 34.60 min Scan# 3771
Delta R.T. 0.03 min
Lab File: ENG1324.D
Acq: 19 May 99 2:37 pm
Tgt Ion:244 Resp:16582645
Ion
244
122
0
0
Ratio
100
27.6
0.0
0.0
Lower Upper
13.6
0.0
0.0
40.6
0.0
0.0
PEb.M
Wea May 26 14:15:0b 1999
HP 5989B
Page 11
-------
Abundance
1000000 J
rime- ->
TIC: ENG1324.D
500000 J
38.70 38.80 38.90 39.00 39.10
Abundancelon 240.00 (239.70 to 240.70): ENG
lion 120.00 (119.70 to 120.70): ENG
800000J
600000:
400000:
200000:
Time - - >
38.70 38.80 38.9039:00
#20
Benzo(a)anthracene-d!2
Concen: 2.74 ng/uL
RT: 38.89 min Scan# 4417
Delta R.T. 0.01 min
Lab File: ENG1324.D
Acq: 19 May 99 2:37 pm
Tgt Ion:240 Resp: 2192094
Ion Ratio
240 100
120 31.4
0 0.0
0 0.0
Lower Upper
15.1
0.0
0.0
45.1
0.0
0.0
ENG
Abundance
1000000.
500000.
o
TIC : ENG
. 1
1324. D
'I
-T 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 r
Time--> 38.00 38.50 39 00 39.50
Abundance
80000 :
60000 .
40000 :
20000 .
o :
ion 228.00 (227.70
Ion 114.00 (113.70
, /J
r
to 228.70) : ENG
to 114.70) : ENG
^"^
Time--> 38loO 38150 39.00 39! 50 T"
J.J^4.D FJSb.M Wed May 26 14:lb:08 1999
#21
Benzo(a)anthracene
Concen: 0.00 ng/uL
Expected RT: 38.98 min
Lab File: ENG1324.D
Acq: 19 May 99 2:37 pm
Tgt Ion: 228
Ion Exp Ratio
228 100
114 25.0
0 0.0
0 0.0
HP 5989B
Page 12
-------
Abundance
1000000J
rime--> 38.80
TIC: ENG1324.D
500000 .
0
39.00
39.20
Abundance I on ^40 . DO (239.70 to 240.70)
Ion 120.00 (119.70 to 120.70)
800000 .
600000 .
400000 .
200000:
ENG
ENG
39.05
Time--> 38.80
39.00
39.20
#22
Chrysene-dl2
Concent 3.41 ng/uL
RT: 39.05 min Scan# 4442
Delta R.T. 0.02 min
Lab File: ENG1324.D
Acq: 19 May 99 2:37 pm
Tgt Ion:240 Resp: 3314701
Ion Ratio Lower Upper
240 100
120 30.1 15.1 45.1
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance
1000000J
TIC: ENG1324.D
500000 .
rime-->
39.00
39.10
39.20
Abunaancelon 228.00 (227.70 to 228.70)
80000JIon 114-00 (113.70 to 114.70)
60000J
40000:
20000:
ENG
ENG
Time-->
39.00
39:iO
39.20
ENG1324.D—FEST1
Wed May 2b 14:lb:ll
#23
Chrysene(CCC)
Concen: 0.04 ng/uL m
RT: 39.13 min Scan# 4455
Delta R.T. -0.03 min
Lab File: ENG1324.D
Acq: 19 May 99 2:37 pm
Tgt Ion:228 Resp: 52986
Ion
228
114
0
0
Ratio
100
62.9
0.0
0.0
Lower Upper
12.6
0.0
0.0
37.6#
0.0
0.0
OCi
HP 5989B
Page 13
-------
Abundance TIC: ENG1324.D
600000 '.
400000 '.
200000 '.
0
Time--> 45^70 45!80 45190 46:00 46!lO
Abundance I on 264.00 [263.70 to 264.70): ENG
Ion 132.00 (131.70 to 132.70): ENG
45.90
400000 .
200000 _
Time-->
#24
Benzo(b)fluoranthene-dl2
Concen: 4.35 ng/uL
RT: 45.90 min Scantf 5494
Delta R.T. 0.03 min
Lab File: ENG1324.D
Acq: 19 May 99 2:37 ptn
Tgt Ion:264 Resp: 3112515
Ion
264
132
0
0
Ratio
100
35.6
0.0
0.0
Lower Upper
15.1
0.0
0.0
45.1
0.0
0.0
Abundance
600000J
400000 '.
200000 J
rime-->
TIC: ENG1324.D
0
—I—1—i—1—1—I—I—I—I—I—T—I—I—1—!—i—I—i—I—i—I—i—i—r
45.00 45.50 46.00 46.50 47.00
Abundance I on 252.00 (251.70 to 252.70): ENG
20000JIon 126-°° (125.70 to 126.70): ENG
rime--> 45.00 45.50
1 1 1 I "I 1 1
46iOQ 46150
\—|—i—r
47100
ENG13.24.D—PES.M
Wed May 2b 14:IS:14 1999
#25
Benzo(b)fluoranthene
Concen: 0.00 ng/uL
Expected RT: 46.07 min
Lab File: ENG1324.D
Acq: 19 May 99 2:37 pm
Tgt Ion: 252
Ion Exp Ratio
252 100
126 25.0
0 0.0
0 0.0
HP 5989B
Page 14
-------
Abundance
600000 :
400000:
200000:
rime--> 45.80
TIC: ENG1324.D
46.00
46.20
\
Abundancelon 264.00 (263.70 to 264.70)
Ion 132.00 (131.70 to 132.70)
46.10
r\
400000 .
200000 .
ENG
ENG
Time--> 45.80
46100
46.20
Abundance
600000 :
400000 J
200000:
TIC: ENG1324.D
rime-->
0
45.50 46.00 46.50 47100
T
#26
Benzo(k)fluoranthene-dl2
Concen: 3.28 ng/uL
RT: 46.10 min Scantt 5524
Delta R.T. 0.02 min
Lab File: ENG1324.D
Acq: 19 May 99 2:37 pm
Tgt Ion:264 Resp: 3191755
Ion Ratio
264 100
132 38.0
0 0.0
0 0.0
Lower Upper
15.1
0.0
0.0
45.1
0.0
0.0
Abundance Ion 252.00 (251.70 to 252.70)
Ion 126.00 (125.70 to 126.70):
15000:
10000.
5000 .
0.
ENG
ENG
rime-->
45.50 46.00 46150 47100
ENGT3"2~4~7E
Wed May 2b 14:15:17 1939
#27
Benzo(k)fluoranthene
Concen: 0.00 ng/uL
Expected RT: 46.23 rain
Lab File: ENG1324.D
Acq: 19 May 99 2:37 pm
Tgt Ion: 252
Ion Exp Ratio
252 100
126 25.0
0 0.0
0 0.0
HP 5989B
OCC5850
Page 15
-------
Abundance
30000J
20000 '.
10000 '.
Time--> 47.50 48.00
TIC: ENG1324.D
0
Abundancelon 264.00 (263.70 to 264.70)
lion 132.00 (131.70 to 132.70)
10000.
5000 .
0 .
ENG
ENG
Time--> 47150 48100 48150 49lOO 49l50
Time-->
Abundance
30000J
20000J
10000 J
•TIC: ENGl324.t)
48.00
49.00
50:00
AJDundancelon 252.00 (251.70 to 252.70).- ENG
Ion 126.00 (125.70 to 126.70): ENG
15000 J
10000:
5000:
Time-->
48.00
sooo
#28
Benzo(a)pyrene-dl2
Concen: 0.00 ng/uL
Expected RT: 48.54 min
Lab File: ENG1324.D
Acq: 19 May 99 2:37 pm
Tgt Ion: 264
Ion Exp Ratio
264 100
132 30.0
0 0.0
0 0.0
ENG1324.DPES.M
Wed May 2fe 14:15:21
#29
Benzo(a)pyrene(CCC)
Concen: 0.00 ng/uL
Expected RT: 48.74 min
Lab File: ENG1324.D
Acq: 19 May 99 2:37 pm
Tgt Ion: 252
Ion Exp Ratio
252 100
126 25.0
0 0.0
0 0.0
HP 5989B
Page 16
-------
Abundance
300000J
200000.
100000-
rime--> 60.50 61.00 61.50 62.00
TIC: ENG1324.D
Abundance Ion 288.00 (287.70 to 288.70): ENG
200000.
150000
100000 J
j
-i
61.53
50000
1
Time-->60.50 61.00 61.50 62.00
#30
Indeno(1,2,3-cd)pyrene-dl2
Concen: 3.07 ng/uL
RT: 61.53 min Scan# 8109
Delta R.T. 0.05 min
Lab File: ENG1324.D
Acq: 19 May 99 2:37 pm
Tgt Ion:288 Resp: 2661551
Ion Ratio Lower Upper
288 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
ENG
Abundance
300000 .
200000 '.
100000 -
0 .
TIC: ENG1324.D
Jl
Time--> 6lioO 62io6 63lo6
Abundance
8000 _
6000 .
4000.
2000 .
0 .
Time-->
ion 276.05 (275.75 to 276.75): ENG
Ion 138.00 (137.70 to 138.70): ENG
____^^
6llo6 ' ' 62lo6 ' ' 63lo6
J.J24.D PES.M wed May 26 14:15:24 1999
#31
Indeno(1,2,3-cd)pyrene
Concen: 0.00 ng/uL
Expected RT: 61.83 min
Lab File: ENG1324.D
Acq: 19 May 99 2:37 pm
Tgt Ion: 276.05
Ion Exp Ratio
276 100
138 64.0
0 0.0
0 0.0
OCI
HP 5989B
Page 17
-------
'imdance
300000 _
200000.
100000
TIC: ENG1324.D
0
Time - - >
61.00
[Abundance I on 292.00
J
100000 _
50000 j
61.50 62.00
[291.70 to 252.70}: ENG
61.47
#32
Dibenz(a,h)anthracene-d!4
Concen: 3.29 ng/uL
RT: 61.47 min Scan# 8098
Delta R.T. 0.03 min
Lab File: ENG1324.D
Acq: 19 May 99 2:37 pm
Tgt Ion:292 Resp: 1678032
Ion Ratio Lower Upper
292 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 ' <*—
Time--> 61.00
6lls6 ' 62100
'Abundance TIC:
300000- A
-
i 1
200000J l
1
H
1
loooooJ
\ 1
.
0 -
/
J
rime--> 61 loo
. Abundancelon 278.00 (27
5000-
•
l
0_
ENG1324TD
1
\
\
\
^-—~__
62:00 ' esloo
7.70 to 278.70) : ENG
Ion 139.00 (138.70 to 139.70): ENG
A
^^^^^J
/*
l.»1ime--> 61.00
SG1J24.D PKS.M Wed
v j*^*V
^^ ^^^>^~^
62.00 63.00
May 2fc 14:lb:2y 1999
#33
Dibenz (a/h) anthracene
Concen: 0.00 ng/uL
Expected RT: 61.85 min
Lab File: ENG1324.D
Acq: 19 May 99 2:37 pm
Tgt Ion: 278
Ion Exp Ratio
278 100
139 25.0
0 0.0
0 0.0
Q s0^
••J-^^
HP 5989B Page
-------
Abundance
100000.
TIC: ENG1324.D
50000J
Time-->
64.50
65.00
65.50
Abundance Ion 288700 (287/70 to 288.70}
65.08
100000J
50000 _
ENG
tTime-->
64!50
65.00
65.50
#34
Benzo(g,h,i)perylene-d!2
Concen: 2.13 ng/uL
RT: 65.08 min Scan# 8832
Delta R.T. 0.01 min
Lab File: ENG1324.D
Acq: 19 May 99 2:37 pm
Tgt Ion:288 Resp: 1461208
Ion Ratio Lower Upper
288 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
[Abundance
ENG
100000 .
.
50000 .
.
0
Time- -> 64
Abundance
6000.
4000
2000.
0.
rime-->64
TIC: ENG1324.D
r\
\
\
.00 65.00 66.00
Ion 276.00 (275.70 to 276.70): ENG
Ion 138.00 (137.70 to 138.70): ENG
— >—~J Vy^.^ ,._,,,,,
^"-" " / \ "»»-»»HM».Hi til.wso.XV. .f
y^ \^
1 1 J 1 III — 1 1 1 1 [-• -I-
.00 65.00 66.00
J.J24.U PES.M Wed May 2b 14:15:31 1999
#35
Benzo(g,h, Dperylene
Concen: 0.00 ng/uL
Expected RT: 65.44 min
Lab File: ENG1324.D
Acq: 19 May 99 2:37 pm
Tgt Ion.- 276
Ion Exp Ratio
276 100
138 25.0
0 0.0
0 0.0
HP 5989B
Page 19
-------
ENG1329.XLS
Quantitation Report Summary
Data File
Date Analyzed:
Sample ID
Method ID
Operator
nstrument
Compounds
Naphthalene(CCC)
Acenaphthylene
Acenaphthene(CCC)
Fluorene
Phenanthrene
Anthracene
Fluoranthene(CCC)
3yrene
Benzo(a)anthracene
Chrysene(CCC)
3enzo(b)fluoranthene
Benzo(k)fluoranthene
Benzo(a)pyrene(CCC)
lndeno(1,2,3-cd)pyrene
Dibenz(a,h)anthracene
Benzo(g,h,i)perylene
ENG1329.D
05/19/99
PES INLET 1 4/2/99
PES
JEMcCartney
HP 5989B
Area
5941180
243389
128350
292727
669009
0
0
0
0
0
0
0
0
0
0
0
* PQL - practical quantitation limit
Surrogate Recoveries
Compound
Naphthalene-dS
Acenaphthylene-d8
Acenaphthene-d10
Fluorene-d10
Phenanthrene-d10
Anthracene-d10
Fluoranthene-d10
Pyrene-d10
Benzo(a)anthracene-d12
Chrysene-d12
Benzo(b)fluoranthene-d12
Benzo(k)fluoranthene-d12
Benzo(a)pyrene-d12
Indeno(1,2,3-cd)pyrene-d12
Dibenz(a,h)anthracene-d14
Benzo(g,h,i)perylene-d12
Recovery Standard
Compound
2-Methlynaphthalene-d1 0
p-Terphenyl-d14
Compiled by:
Reviewed by:
Reviewed by:
Cone.
(ng/HL)
18.041
0.731
0.578
1.130
1.658
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Cone. (ng/uL)
4.88
2.15
3.36
3.74
3.73
0.00
3.70
3.38
2.37
0.00
0.00
0.00
0.00
1.95
2.01
1.60
Concentration (ng/uL)
^
32.36
31.09
,/
PQL*
(ng/HL)
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
^-//^
J>{ Jfrfs^i* ( /•' '*
Tife^S'C^^U^ *\a^y«
I
Cone.
(ng/sample)
18040.6
731.2
577.8
1130.2
1657.6
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
Cone, (ng/sample)
w/ Surr. correction
18040.6**
1363.4
688.8
1207.4
1777.9
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
** No surrogate correction made
% Recovery
121.92
53.63
83.89
93.61
93.23
0.00
92.43
84.59
59.18
0.00
0.00
0.00
0.00
48.76
50.14
40.03
% Recovery
80.89
77.74
'C" f
**7
-------
Quantitation Report
C:\HPCHEM\1\DATA\9919\ENG1329.D
19 May 99 8:55 pm
PES INLET 1 4/2/99
Data File
Acg On
Sample
Misc :
Quant Time: May 26 15:04 1999
Vial: 9
Operator: JEMcCartney
Inst : HP 5989B
Multiplr: 1.00
Method
Title
Last Update
Response via
C:\HPCHEM\1\METHODS\PES.M
Mon May 24 16:23:27 1999
Multiple Level Calibration
Internal Standards
R.T. Qlon Response Cone Units Dev(Min)
1)
2, 2-Dif luorobiphenyl
24
.62
190
928902
System Monitoring Compounds
2)
4)
5)
7)
9)
11)
13)
15)
17)
19)
20)
22)
24)
26)
28)
30)
32)
34)
Naphthalene - d8
2 -Methlynaphthalene - dl 0
Acenaphthylene-d8
Acenaphthene-dlO
Fluorene-dlO
Phenan t hrene - dl 0
Anthracene-dlO
Fluoranthene - dl 0
Pyrene -dlO
p-Terphenyl-d!4
Benzo (a) anthracene-d!2
Chrysene-dl2
Benzo (b) f Iuoranthene-dl2
Benzo (k) f Iuoranthene-dl2
Benzo (a) pyrene-d!2
Indenod, 2, 3-cd)pyrene-dl2
Dibenz (a, h) anthracene-d!4
Benzo (g,h, i)perylene-d!2
22
24
26
26
28
30
0
33
34
34
38
0
0
0
0
62
62
65
.28
.00
.33
.76
.06
.48
.00
.61
.28
.61
.91
.00
.00
.00
.00
.05
.02
.69
136
152
160
164
176
188
188
212
212
244
240
240
264
264
264
288
292
288
1381039
4859624
640432
664277
804237
1241343
0
1218540
1224212
8509001
549563
0
0
0
0
490309
296017
318743
Target Compounds
3)
6)
8)
10)
12)
14)
16)
18)
21)
23)
25)
27)
29)
31)
33)
35)
Naphthalene (CCC)
Acenaphthylene
Acenaphthene (CCC)
Fluorene
Phenanthrene
Anthracene
Fluoranthene (CCC)
Pyrene
Benzo (a) anthracene
Chrysene (CCC)
Benzo (b) f luoranthene
Benzo (k) f luoranthene
Benzo (a) pyrene (CCC)
Indeno ( 1 , 2 , 3 - cd) pyrene
Dibenz (a, h) anthracene
Benzo (g,h, i)perylene
22
26
26
28
30
0
0
0
0
0
0
0
0
0
0
0
.33
.38
.83
.12
.53
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
128
152
154
166
178
178
202
202
228
228
252
252
252
276
278
276
5941180
243389
128350
292727
669009
5.00 ng/uL
0
.04
%Recovery
4.88 ng/uL 121
32.36 ng/uL
2.15 ng/uL
3.36 ng/uL
3.74 ng/uL
3.73 ng/uL
0.00 ng/uL
3 .70 ng/uL
3.38 ng/uL
31.09 ng/uL
2.37 ng/uL
0.00 ng/uL
0.00 ng/uL
0.00 ng/uL
0.00 ng/uL
1.95 ng/uL
2 .01 ng/uL
1.60 ng/uL
80
53
83
93
93
0
92
84
77
59
0
0
0
0
48
50
40
.92%
.89%
.63%
.89%
.61%
.23%
.00%
.43%
.59%
.74%
.18%
.00%
.00%
.00%
.00%
.76%
.14%
.03%
Qvalue
18.04 ng/uL
0.73 ng/uLm
0.58 ng/uLm
1.13 ng/uL
1.66 ng/uL
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
QC£-3-Q
•^
•—- iJ
79
64
26
62
93
(#) = qualifier out of range (m) = manual integration
ENG1329.D PES.M Wed May 26 15:04:42 1999 HP 5989B
Page 1
-------
Quantitation Report
C:\HPCHEM\1\DATA\9919\ENG1329.D
19 May 99 8:55 pm
PES INLET 1 4/2/99
Data File
Acq On
Sample
Misc :
Quant Time: May 26 15:04 1999
Method
Title
Last Update
Response via
C:\HPCHEM\1\METHODS\PES.M
Mon May 24 16:23:27 1999
Multiple Level Calibration
Vial: 9
Operator: JEMcCartney
Inst : HP 5989B
Multiplr: 1.00
Sundance
200000 :
1000000:
TIC: EMG1329.D
2"800000
600000 J
?400000:
2200000 J
]
DOOOOOj
1300000
1600000 J
• tooooo^
j
1700000J
1000000 j
i
300000 j
BOOOOO q
400000:
;ooooo:
19S
34s
3lTrl329.D PES.M
Wed May 26 15:04:50 1999
HP 5989B
Page 2
-------
Abundance
2000000 H
TIC: ENG1329.D
rime--> 22 .00
22.20
22.40
Sundance Ion 136.00 (135.70 to 136 .70) : ENG
Jlon 68.00 (67.70 to 68.70): ENG13
1000000 -
500000-]
,Time--> 22 '. 00
22.20
22.40
[Abundance
2000000H
1500000 J
1000000:
500000:
Time--> 22.00
TIC: ENG1329.£>
22.20
22.40
22.60
#2
Naphthalene-d8
Concen: 4.88 ng/uL
RT: 22.28 min Scan# 1573
Delta R.T. 0.05 min
Lab File: ENG1329.D
Acq: 19 May 99 8:55 pm
Tgt Ion:136 Resp: 1381039
Ion Ratio
136 100
68 0.0
0 0.0
0 0.0
Lower Upper
10.1
0.0
0.0
30.1#
0.0
0.0
Abundanceion 128.00 (127.70 tcT128.70):ENG
1500000Jlon 127.00 (126.70 to 127.70): ENG
22.33
1000000 .
500000 .
0-
Time--> 22.00
22120
22!40
—i 1 1 r
22160
ENG1J29.DPES.M
Wed May 2b lb:U4:53
#3
Naphthalene(CCC)
Concen: 18.04 ng/uL
RT: 22.33 min Scan# 1581
Delta R.T. 0.05 min
Lab File: ENG1329.D
Acq: 19 May 99 8:55 pm
Tgt Ion:128 Resp: 5941180
Ion Ratio
128 100
127 17.8
0 0.0
0 0.0
Lower Upper
0.0 60.0
0.0 0.0
0.0 0.0
oc
'03883
HP 5989B
Page 3
-------
Abundance
sooooo:
600000 .
400000.
200000-
TIC: ENG1329.D
Abundance Ion 152.00 (151.70 to 152.70): ENG
ime-->
23.80
24.00
24.20
1000000 .
24.00
500000 _!
0 .
fTime - - >
23.80
24.00
24.20
Abundance
! 1
200000.
150000.
100000 .
50000 .
TIC: ENG1329.D
Time- - >
Abundancelon 160.00 (159.70 to l€o.?0): ENG
26.20 26.30 26.40 '26150
#4
2-Methlynaphthalene-dlO
Concen: 32.36 ng/uL
RT: 24.00 min Scan# 1943
Delta R.T. 0.04 min
Lab File: ENG1329.D
Acq: 19 May 99 8:55 pm
Tgt Ion:152 Resp: 4859624
Ion Ratio Lower Upper
152 100
0 0.0 0.0 0.0
0 0.0 0.0 . 0.0
0 0.0 0.0 0.0
150000j
100000J
50000.
26.33
Time - - >
26.20
-i 1 1—|—I 1 1—i r
26:30 26.40 26.50
SNGTJZFTD
Wed May 2* lb:04:bb 1999
#5
Acenaphthylene-d8
Concen: 2.15 ng/uL
RT: 26.33 min Scan# 2456
Delta R.T. 0.04 min
Lab File: ENG1329.D
Acq: 19 May 99 8:55 pm
Tgt Ion:160 Resp: 640432
Ion
160
0
0
0
Ratio
100
0.0
0.0
0.0
Lower Upper
0.0
0.0
0.0
0.0
0.0
0.0
OOCjSr;
HP 5989B
Page 4
-------
Abundance TIC: ENG1329.D
200000 :
150000:
100000:
50000:
0
Time--> 26!20 ' '26130' '26Uo' '26 I 50
Abundance Ion
jlon
80000j
60000
40000
152.00 (151.7D to 152.70): ENG
153.00 (152.70 to 153.70): ENG
26.38
zuu*.
i
[Time--:
JU J
\
\
0 j
> 26 1 20 ' ' 26 ! 30 ' 26 1 40 ' ' 26 1 50 '
[Abundance
]
200000 .
150000 .
100000
50000 .
0
Time-->
TIC: ENG1329.D
Abundance ion 164.00 (163.70 to 164.70): ENG
i—I—i~~i—i—i—I—i—i—I—i—I—i—i—i—i—i—i—i—i—r
26.60 26.70 26.80 26.90
#6
Acenaphthylene
Concen: 0.73 ng/uL m
RT: 26.38 min Scan# 2464
Delta R.T. 0.06 min
Lab File: ENG1329.D
Acg: 19 May 99 8:55 pm
Tgt Ion:152 Resp: 243389
Ion Ratio Lower Upper
152 100
153 65.8 7.6 22.6#
0 0.0 0.0 0.0
0 0.0 0.0 0.0
150000
100000 .
50000 .
Time-->
26.76
26.60 26.70
]—i—i—i—i—i—i—i—i—r
26.80 26.90
ENG1J29.D PES.M
Wed May '2k lb:U4:b«
#7
Acenaphthene-dl0
Concen: 3.36 ng/uL m
RT: 26.76 min Scantf 2521
Delta R.T. 0.05 min
Lab File: ENG1329.D
Acq: 19 May 99 8:55 pm
Tgt Ion:164 Resp: 664277
Ion
164
0
0
0
Ratio
100
0.0
0.0
0.0
Lower Upper
0.0
0.0
0.0
0 .0
0.0
0.0
OCC
'C3580
HP 5989B
Page 5
-------
Abundance
200000:
150000.
100000 .
50000 .
TIC: ENG1329.D
0
?ime--> 26.70 26.80 26.90
Abundance Ion 154.00 (153.70 to 154.70)
Ion 153.00 (152.70 to 153.70): ENG
60000:
40000 J
20000
fTime--> 26.70
26.80
26.90
TIC: ENG1329.D
Time-->
27.90 28.00 28.10 28.20
#8
Acenaphthene(CCC)
Concen: 0.58 ng/uL m
RT: 26.83 min Scan# 2532
Delta R.T. 0.05 min
Lab File: ENG1329.D
Acq: 19 May 99 8:55 ptn
Tgt Ion:154 Resp: 128350
Ion Ratio Lower Upper
154 100
153 141.4 43.5 130.3#
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance Ion 176.00 (175.70 to 176.70): ENG
150000 .
100000 .
50000.
28.06
0.
rime-->
27.90 28100 28.10 28.20
ENG1TZ5TB PES .M
Wed May 25 15:05:01 1399
#9
Fluorene-dlO
Concen: 3.74 ng/uL
RT: 28.06 min Scan# 2717
Delta R.T. 0.05 min
Lab File: ENG1329.D
Acq: 19 May 99 8:55 pm
Tgt Ion:176 Resp:
Ion Ratio Lower
176 100
0 0.0 0.0
0 0.0 0.0
0 0.0 0.0
804237
Upper
0.0
0.0
0.0
HP 5989B
Page 6
-------
TIC: ENG1329.D
200000.
100000 -I
Time--> 27190 28.00 28.10 28.20 28.30
pUDundancelon 166.00 (165.70 to 165770): ENG
Ion 165.00 (164.70 to 165.70): ENG
100000J
50000
fTime--> 27.90 28.00 28.10 28.20 28.30
#10
Fluorene
Concen: 1.13 ng/uL
RT: 28.12 min Scan# 2727
Delta R.T. 0.05 min
Lab File: ENG1329.D
Acq: 19 May 99 8:55 pm
Tgt Ion:166 Resp: 292727
Ion Ratio Lower Upper
166 100
165 108.5 38.2 114.4
0 0.0 0.0 0.0
0 0.0 0.0 0.0
(Abundance
600000:
TIC: ENG1329.D
400000 J
200000 J
n '
Time- - > 30 .30 30 ! 40 ' 30 50 ' ' 30 ! 60
Abundancelon 188.00 (187.70 to 188.70): EtfG
j
400000:
300000 .
200000 :
100000.
0.
Ion 94.00 (93.70 to 94.70): ENG13
/ ^^ _
' ~\
30.48
/ \_
S "~~
Time--> 30130 3o!40 3ol50 's'oieb'
Ion
188
94
0
0
ENGj..i^y .U FKb.M Wed May 2fe 15:05:04 1999
#11
Phenanthrene-dl0
Concen: 3.73 ng/uL
RT: 30.48 min Scan# 3085
Delta R.T. 0.05 min
Lab File-. ENG1329.D
Acq: 19 May 99 8:55 pm
Tgt Ion:188 Resp: 1241343
Ratio
100
29.6
0.0
0.0
Lower Upper
15.1
0.0
0.0
45.1
0.0
0.0
OCC3S
HP 5989B
Page 7
-------
Abundance
600000 .
400000 .
200000 .
TIC: EMG1329.D
fTime--> 30.30 30.40 30.50 30.60 30.70
Kb1
'undancelon 178.00 (177.70 to 178.70)
ENG
150000 .
100000 -
50000
-lion 176.00 (175.70 to 176.70): ENG
30.53
[Time--> 30.30 30.40 30.50 30.60 30.70
#12
Phenanthrene
Concen: 1.66 ng/uL
RT: 30.53 min Scan# 3093
Delta R.T. 0.04 min
Lab File: ENG1329.D
Acg: 19 May 99 8:55 pm
Tgt Ion:178 Resp: 669009
Ion
178
176
0
0
Ratio
100
23.1
0.0
0.0
Lower Upper
10.1
0.0
0.0
30.1
0.0
0.0
(Abundance
600000 J
400000:
200000:
TIC: ENG1329.D
Time--> 29.50 30.00
?UDundanceIon
188.00 (187.70 to
Ion 94.00 (93.70 to 94.70): ENG13
31.00 31.50
188.70): ENG
400000 .
300000 .
200000.
100000.
, ' i I i i i r-li—i—i—i—r—i—i—i—i—I—i—i—i—i—I—i—i
Titne--> 29.50 30.00 30.50 31.00 31.50
PES.M
Wed May 2b ib:Ub:Ob 1999
#13
Anthracene-dl0
Concen: 0.00 ng/uL
Expected RT: 30.57 min
Lab File: ENG1329.D
Acg: 19 May 99 8:55 pm
Tgt Ion: 188
Ion Exp Ratio
188 100
94 30.0
0 0.0
0 0.0
HP 5989B
Page 8
-------
Abundance
600000:
400000 :
200000:
TIC: ENG1329.D
Time-->29.50 30:00 30.50 31.00 31.50
Sundance Ion 178.00
150000 jlon 176-°°
100000
50000 J
(177.70 to 178.70): ENG
70 to 176.70): ENG
rrime-->29.50 30.00 30.50 31.00 31.50
(Abundance
! 600000J
400000 J
200000
Time - - >
TIC: ENG1329.D
33.40
~i 1 r
33.60
33.80
Abundance Ion 212.00 (211.70 to 212.70): ENG
ilon 106.00 (105.70 to 106.70): ENG
400000 .
200000 .
#14
Anthracene
Concen: 0.00 ng/uL
Expected RT: 30.62 min
Lab File: ENG1329.D
Acq: 19 May 99 8:55 pm
Tgt Ion: 178
Ion Exp Ratio
178 100
176 20.0
0 0.0
0 0.0
0 .
33.61
33140
~i 1 1 1 1 i 1 1 r-
33.60 33.80
ENG1329.D—PES.M
Wed May 2b 15:05:0y
#15
Fluoranthene-dl0
Concen: 3.70 ng/uL
RT: 33.61 min Scan# 3624
Delta R.T. 0.04 min
Lab File: ENG1329.D
Acq: 19 May 99 8:55 pm
Tgt Ion:212 Resp: 1218540
Ion Ratio
212 100
106 41.4
0 0.0
0 0.0
Lower Upper
15.1
0.0
0.0
45 .1
0 .0
0.0
OCi
HP 5989B
Page 9
-------
E*
Abundance
2000000.
1500000.
1000000 .
500000.
TIC: ENG1329.D
Time--> 32:50 33;00 33150 34100 34.50
(AbundanceIon 202.00 (201.70 to 202.70): ENG
lion 101.00 (100.70 to 101.70): ENG
400000 J /I
200000 -
0
iTime--> 32.50 33.00 33.50 34.00 34.50
Time-->
'undance
2000000:
1500000:
1000000;
500000:
TIC: ENG1329.D
34.00
34:20
34.40
#16
Fluoranthene(CCC)
Concen-. 0.00 ng/uL
Expected RT: 33.62 tnin
Lab File: ENG1329.D
Acq: 19 May 99 8:55 pm
Tgt Ion: 202
Ion Exp Ratio
202 100
101 27.0
0 0.0
0 0.0
Abundanceion 212.00 (211.70 to 212.70): ENG
Jlon 106.00 (105.70 to 106.70): ENG
400000.
200000 .
0.
Time--> 34100
34.20
i i i r i 1 r
34.40
. M
Wed May 2fe 15:05:12 1999
#17
Pyrene-dlO
Concen: 3.38 ng/uL
RT: 34.28 min Scan# 3725
Delta R.T. 0.04 min
Lab File: ENG1329.D
Acq: 19 May 99 8:55 pm
Tgt Ion:212 Resp: 1224212
Ion
212
106
0
0
Ratio
100
0.0
0.0
0.0
Lower Upper
17.1
0.0
0.0
51.1#
0.0
0.0
HP 5989B
Page 10
-------
(Abundance
2000000 :
1500000:
1000000:
500000:
c
Time-->
TIC: EMG1329.D
T—i—I—i—i—i—i—I—i—I—i—i—I—i—i—iI I i r
33.50 34.00 34.50 35.00
Abundancelon 202.00 (261.70 to 202.70): ENG
Jlon 101.00 (100.70 to 101.70): ENG
400000 J
200000 -
ime-->
i—i i i—i—i—i—i—i—i i >—i—i—\—:—i—\—i—i—r
33.50 34.00 34.50 35100
(Abundance
2000000:
1500000:
1000000:
sooooo:
TIC: ENG1329.b
Time-->
34.40
34.60
34180
Abundance Ion 244TDO(243.70 to 244.7 0)
Ion 122.00 (121.70 to 122.70)
34.61
1000000 .
500000 .
0 .
ENG
ENG
34:40
34160
34!80
#18
Pyrene
Concen: 0.00 ng/uL
Expected RT: 34.30 min
Lab File: ENG1329.D
Acq: 19 May 99 8:55 pm
Tgt Ion: 202
Ion Exp Ratio
202 100
101 32.0
0 0.0
0 0.0
ENGTJZSTB PES .M
p-Terphenyl-d!4
Concen: 31.09 ng/uL
RT: 34.61 min Scan# 3774
Delta R.T. 0.04 min
Lab File: ENG1329.D
Acq: 19 May 99 8:55 pm
Tgt Ion:244 Resp: 8509001
Ion
244
122
0
0
Ratio
100
31.0
0.0
0.0
Lower Upper
13 .6
0.0
0.0
40.6
0.0
0 .0
wea May 26is:05:is iyyy
HP 5989B
Page 11
-------
Abundance
400000 :
300000:
200000:
100000:
TIC: ENG1229.D
Time--> 38.70 38180 38.90 39.00 39.10
Abundance Ion 240.00 (239.70 to 240.70): ENG
Ion 120.00 (119.70 to 120.70): ENG
300000 J
200000 J
100000
#20
Benzo(a)anthracene-d!2
Concen: 2.37 ng/uL
RT: 38.91 min Scan# 4421
Delta R.T. 0.03 min
Lab File: ENG1329.D
Acq: 19 May 99 8:55 pm
Tgt Ion:240 Resp: 549563
Ion Ratio
240 100
120 0.0
0 0.0
0 0.0
Lower Upper
15.1
0.0
0.0
45.1#
0.0
0.0
0 J
fTime - - >
38
70 '
38
:so
'SB!
90
39
loo
39
lio
Abundance
600000 _
400000 .
^
V
j
200000 i
.
•
n
Time--> 38
TIC: ENG1329.D
kyv^/
\,
V
\^
v^-_^_^
oo 's'e! so' 's'gio'o' 'sis! so' '
Abundancelon 228.00 (227.70 to 228.70): ENG
-
150000 1
-
100000 ^
'
50000:
0 '
Time-->
Ion 114.00 (113.70 to 114.70): ENG
Vs.
ENGl.i2y.D PES.M
— . — ^J
n
i
-~~_^
r~~-^-
' ' i ' > i * i i -i- -I^T—T-T •••! -i— -r— i— i — i — i
00 38.50 39.00 39.50
Wed May'
26
#21
Ben
Con
Exp
Lab
Acq
Tgt
Ion
228
114
o
0
lb:Ub:iy 1999
Benzo (a) anthracene
Concen: 0.00 ng/uL
Expected RT: 38.98 min
le: ENG1329.D
Acq: 19 May 99 8:55 pm
Exp Ratio
100
25.0
0.0
0.0
OCi
HP 5989B
Page 12
-------
Abundance
600000j
400000.
200000.
T1C: ENG1329.D
Time--> 38.00 38.50 39.00 39.50 40.00
Abundancelon 240.00 (239.70 to 240.70): ENG
400000 Jjlon 120.00 (119.70 to 120.70): ENG
300000 -;
j
200000J
100000 J
o
ime--> 38^00 38.50 39.00 39.50 40.00
IC: ENG1329.D
rime--> 38.50 39^00 39^50 40^00
Abundance Ion 228
150000 J
100000.
50000J
.00 (227.VO to 228.70): ENG
Ion 114.00 (113.70 to 114.70): ENG
rime-->
38.50 39.00
i i I i i i i I i i
39.50 40.00
#22
Chrysene-dl2
Concen: 0.00 ng/uL
Expected RT: 39.03 min
Lab File: ENG1329.D
Acg: 19 May 99 8:55 pm
Tgt Ion: 240
Ion Exp Ratio
240 100
120 30.0
0 0.0
0 0.0
Wed May 2b 15:05:21
#23
Chrysene(CCC)
Concen: 0.00 ng/uL
Expected RT: 39.16 min
Lab File: ENG1329.D
Acq: 19 May 99 8:55 pm
Tgt Ion: 228
Ion Exp Ratio
228 100
114 25.0
0 0.0
0 0.0
OC038
'
HP 5989B
O
Page 13
-------
[Abundance
300000:
200000.
100000^
TIC: ENG132$.D
0
Time-->
'45!o'o' 45.50 46.00' '46! 50
Abundance Ion 264.00 (263.70 to 264.70)
150000JIOn 132-°° (131.70 to 132.70)
ENG
ENG
fTime-->
45100 45.50 46!00 46lso' ' ' '
#24
Benzo(b)fluoranthene-d!2
Concen: 0.00 ng/uL
Expected RT: 45.87 min
Lab File: ENG1329.D
Acq: 19 May 99 8:55 pm
Tgt Ion: 264
Ion Exp Ratio
264 100
132 30.0
0 0.0
0 0.0
Abundance
300000 ^
!
i
J!NG
200000 :
100000 :
0 '
Time-->
Abundance
150000 :
100000 :
soooo :
0 '
Time-->
TIC: ENG1329.D
-------
Abundance
300000J
200000J
100000 .
TIC: ENG1329.D
Time--> 45.00 45.50 46.00 46.50 47.00
Dundancelon 264.00 (263.70 to 264.70)
150000JIOn 132-°° (131.70 to 132.70)
100000
ENG
ENG
50000 J
1
-i
0-LJ
fTime--> 45.00 45.50 46.00 46.50 47.00
(Abundance
300000 J
200000
100000:
Time-->
TIC: ENGl329.t>
1—i—I—i—i—i—'—I—i—i—i—i—i—i—i—i—i—i—i—i—i—r
45.50 46.00 46.50 47.00
Abundancelon 252.00 (251.70 to 252.70): EHG
Ion 126.00 (125.70 to 126.70): ENG
150000 J
100000 .
50000 J
#26
Benzo(k)fIuoranthene-dl2
Concen: 0.00 ng/uL
Expected RT: 46.07 min
Lab File: ENG1329.D
Acq: 19 May 99 8:55 pm
Tgt Ion: 264
Ion Exp Ratio
264 100
132 30.0
0 0.0
0 0.0
0 .
Time-->
7ET"
T i | i—i—i—i—I—i—i—i—i—i—i—i—i—i—i—i—i
45.50 46.00 46.50 47.00
PES.M
Wed May 2b lb:US:2V
#27
Benzo(k)fluoranthene
Concen: 0.00 ng/uL
Expected RT: 46.23 min
Lab File: ENG1329.D
Acg: 19 May 99 8:55 pm
Tgt Ion: 252
Ion Exp Ratio
252 100
126 25.0
0 0.0
0 0.0
HP 5989B
Page 15
-------
Abundance
200000.
100000.
0
Time - - >
Abundance
100000-
r
TIC: ENG1329.D
47!50' 48ido' 48! SO' 49!do' 49!50'
Ion 264.00 (263.70 to 264.70): ENG
Ion 132.00 (131.70 to 132.70): ENG
-— - -^x^____^
50000 J
}
1
Time- ->
47150 '48loo' ^els'o' 49ldo' '49!5'o'
#28
Ben
Con
Exp
Lab
Acq
Tgt
Ion
264
132
0
0
Benzo(a)pyrene-dl2
Concen: 0.00 ng/uL
Expected RT: 48.54 min
Lie: ENG1329.D
Acq: 19 May 99 8:55 pm
3n: 264
Exp Ratio
100
30.0
0.0
0.0
Abundance TIC: ENG1329.D
200000 J
i
j
j
100000 -
1
1
0 '
Time - - >
Abundance
150000 .
100000.
50000 J
0 J
Time-->
48100 49.00 50.00
ion 252.00 (251.70 to 252.70): ENG
Ion 126.00 (125.70 to 126.70): ENG
k^-x^-~^^^V.
48.00 49.00 50.00
.u PKb.M wed May 26 15:Ub:Jl 1999
#29
Benzo(a)pyrene(CCC)
Concen: 0.00 ng/uL
Expected RT: 48.74 min
Lab File: ENG1329.D
Acq: 19 May 99 8:55 pm
Tgt Ion: 252
Ion Exp Ratio
252 100
126 25.0
0 0.0
0 0.0
OCi
HP 5989B
Page 16
-------
Abundance
150000J
100000J
50000J
TIC: ENG1329.D
Time-->
61.50
62.00
62!50
Abundancelon 288.00 (287.70 to 288.70): ENG
62.05
20000 J
10000 J
i j
! oj
L ' ' ' ' ' '
rTime--> 61.50
l
62.00 62.50
[Abundance
! 150000 J
100000 .
50000 .
TIC: ENG1329.D
0
\
K
Time - - >
61.00
62.00
63.00
#30
Indeno(l,2,3-cd)pyrene-dl2
Concen: 1.95 ng/uL m
RT: 62.05 min Scant 8207
Delta R.T. 0.56 min
Lab File: ENG1329.D
Acq: 19 May 99 8:55 pm
Tgt Ion:288 Resp: 490309
Ion Ratio Lower Upper
288 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundancelon 276.05 (275.75 to 276 .75) : ENG
Ion 138.00 (137.70 to 138.70): ENG
60000 J
40000 .
20000 J
0.
Time-->
61.00
62100
63100
ENGT3~2"9~TBPES .M
#31
Indeno(1,2,3 -cd)pyrene
Concen: 0.00 ng/uL
Expected RT: 61.83 min
Lab File: ENG1329.D
Acq: 19 May 99 8:55 pm
Tgt Ion: 276.05
Ion Exp Ratio
276 100
138 64.0
0 0.0
0 0.0
0005302
wea May 26 ib : us : .34
HP 5989B
Page 17
-------
Abundance
150000 J
100000 J
j
50000 J
Time-->
TIC: ENG1329.D
61.50
62.00
62.50
Abundancelon 292.00 (291.70 to 292.70): ENG
20000 J
62.02
i
15000
10000
5000 j
Time-->
61.50
62:00
62150
Abundance
\ 150000.
100000 .
50000J
TIC: ENG1329.D
Time-->
Abundancelon 278.00 (277.70 to 278.70) : ENG
100000JIon 139.00 (138.70 to 139.70): ENG
61.00
62.00
63.00
#32
Dibenz(a,h)anthracene-d!4
Concen: 2.01 ng/uL m
RT: 62.02 min Scan# 8203
Delta R.T. 0.58 min
Lab File: ENG1329.D
Acq: 19 May 99 8:55 pm
Tgt Ion:292 Resp: 296017
Ion Ratio
292 100
0 0.0
0 0.0
0 0.0
Lower Upper
0.0
0.0
0.0
0.0
0.0
0.0
50000 .
0.
Time - - >
6l!00
62.00
63!00
ENGITZ9TDPEb .M
Wed May 2fe lb:Ub:JV 1999
#33
Dibenz(a,h)anthracene
Concen: 0.00 ng/uL
Expected RT: 61.85 min
Lab File: ENG1329.D
Acq: 19 May 99 8:55 pm
Tgt Ion: 278
Ion Exp Ratio
278 100
139 25.0
0 0.0
0 0.0
HP 5989B
OC05903
Page 18
-------
Abundance
40000 :
30000 :
20000:
10000:
TIC: ENG1329.D
Time-->
65.00
65.50
66.00
Abu
28596
elon 288.00 (287.70 to 288.70)
ENG
65.69
Time-->
esloo
65.50
66.00
iAbundance
! w
soooo:
60000 J
40000 :
20000:
TIC: ENG1329.D
Time-->64100
ion 276
65.00 66.00
(275.70 to 276
..danceon 275.00 (275.70 to 276.70)
40000-jlon 138.00 (137.70 to 138.70)
30000.
20000.
10000.
#34
Benzo(g,h,i)perylene-d!2
Concen: 1.60 ng/uL m
RT: 65.69 min Scant 8985
Delta R.T. 0.63 min
Lab File: ENG1329.D
Acg: 19 May 99 8:55 pm
Tgt Ion:288 Resp: 318743
Ion Ratio Lower Upper
288 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0.
ENG
Time-->64.00
65.00
66100
ENG1J29.D—PEiJ.M
Wed May 2b lb:0b:41
#35
Benzo(g,h,i)perylene
Concen: 0.00 ng/uL
Expected RT: 65.44 min
Lab File: ENG1329.D
Acq: 19 May 99 8:55 pm
Tgt Ion: 276
Ion Exp Ratio
276 100
138 25.0
0 0.0
0 0.0
OGCD904
HP 5989B
Page 19
-------
ENG1350.XLS
Quantitation Report Summary
Data File
Date Analyzed:
Sample ID
Method ID
Operator
Instrument
Compounds
Naphthalene(CCC)
Acenaphthylene
Acenaphthene(CCC)
Fluorene
Phenanthrene
Anthracene
Fluoranthene(CCC)
Pyrene
Benzo(a)anthracene
Chrysene(CCC)
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Benzo(a)pyrene(CCC)
lndeno(1 ,2,3-cd)pyrene
Dibenz(a,h)anthracene
Benzo(g,h,i)perylene
ENG1350.D
05/25/99L
PES INLET 1 REPLICATEANALYSIS 4/2/99
PES
JEMcCartney
HP 5989B
Area
2637394
0
52839
110068
164935
0
0
28655
7495
19965
0
0
0
0
0
0
* PQL - practical quantitation limit
Surrogate Recoveries
Compound
Naphthalene-d8
Acenaphthylene-d8
Acenaphthene-d1 0
Fluorene-d10
Phenanthrene-d10
Anthracene-d10
Ftuoranthene-d10
Pyrene-d10
Benzo(a)anthracene-d12
Chrysene-d12
Benzo(b)fluoranthene-d12
Benzo(k)fluoranthene-d12
Benzo(a)pyrene-d12
lndeno(1 ,2,3-cd)pyrene-d12
Dibenz(a,h)anthracene-d14
Benzo(g,h,i)perylene-d12
Recovery Standard
Compound
2-Methlynaphthalene-d10
p-Terphenyt-d14
Compiled by:
Reviewed by:
Reviewed by:
Cone.
(ng/uL)
14.215
0.000
0.531
1.077
1.270
0.000
0.000
0.219
0.082
0.212
0.000
0.000
0.000
0.000
0.000
0.000
Cone. (ng/uL)
3.31
2.06
2.80
3.42
3.19
1.14
3.74
3.66
4.28
5.77
3.92
3.45
0.37
2.30
2.52
1.88
Concentration (ng/uL)
_-.xf
27.15
36.39
- /
PQL*
(ng/ML)
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
Slf ^
^sS^/'
^LdPPZs^t&f < / -&Y / 7*1
Cone.
(ng/sample)
14214.9
0.0
531.2
1077.2
1270.4
0.0
0.0
218.9
81.7
212.0
0.0
0.0
0.0
0.0
0.0
0.0
Cone, (ng/sample)
w/ Surr. correction
17154.7
0.0
758.8
1261.3
1592.1
0.0
0.0
239.3
81.7**
212.0**
0.0
0.0
0.0
0.0
0.0
0.0
** No surrogate correction made
% Recovery
82.86
51.40
70.01
85.41
79.80
28.55
93.62
91.47
106.98
144.26
97.97
86.37
9.37
57.53
62.93
46.89
% Recovery
67.87
90.99
-------
Quantitation Report
Data File :
Acg On :
Sample :
Misc :
Quant Time:
Method
Title
Last Update
Response via
C:\HPCHEM\1\DATA\9919\ENG1350.D
25 May 99 5:07 pm
PES INLET 1 REPLICATEANALYSIS 4/2/99
May 26 9:52 1999
: C:\HPCHEM\1\METHODS\PES1.M
Vial: 5
Operator: JEMcCartney
Inst : HP 5989B
Multiplr: 1.00
Tue May 25 13:51:07 1999
Multiple Level Calibration
Internal Standards
1)
2 , 2-Dif luorobiphenyl
R.T. Qlon
24.
.58
190
Response
480433
System Monitoring Compounds
2)
4)
5)
7)
9)
11)
13)
15)
17)
19)
20)
22)
24)
26)
28)
30)
32)
34)
Naphthalene -d8
2-Methlynaphthalene-dlO
Acenaphthylene-d8
Acenaphthene - dl 0
Fluorene-dlO
Phenanthrene - dl 0
Anthracene - dl 0
Fluoranthene-dlO
Pyrene-dlO
p-Terphenyl-d!4
Benzo (a) anthracene-d!2
Chrysene-dl2
Benzo (b) f Iuoranthene-dl2
Benzo (k) f luoranthene -d!2
Benzo (a) pyrene-d!2
Indenod, 2, 3-cd)pyrene-dl2
Dibenz (a,h) anthracene -d!4
Benzo (g,h, i)perylene-dl2
22,
23,
26.
26.
28.
30
30
33
34
34
38
39
46
46
48
61
61
65
.24
.96
.29
.71
.00
.44
.58
.59
.27
.59
.93
.09
.02
.21
.73
.84
.74
.45
136
152
160
164
176
188
188
212
212
244
240
240
264
264
264
288
292
288
585296
2486575
298401
285176
326435
374762
111945
389033
415758
3371875
338473
448673
294960
293965
27042
205834
143934
141794
Target Compounds
3)
6)
8)
10)
12)
14)
16)
18)
21)
23)
25)
27)
29)
31)
33)
35)
Naphthalene (CCC)
Acenaphthylene
Acenaphthene (CCC)
Fluorene
Phenanthrene
Anthracene
Fluoranthene (CCC)
Pyrene
Benzo (a) anthracene
Chrysene(CCC)
Benzo (b) f luoranthene
Benzo (k) f luoranthene
Benzo (a) pyrene (CCC)
Indeno (1 , 2 , 3 - cd) pyrene
Dibenz (a, h) anthracene
Benzo (g, h, i) perylene
22
0
26
28
30
0
0
34
38
39
0
0
0
0
0
0
.29
.00
.79
.07
.50
.00
.00
.32
.96
.08
.00
.00
.00
.00
.00
.00
128
152
154
166
178
178
202
202
228
228
252
252
252
276
278
276
2637394
52839
110068
164935
28655
7495
19965
Cone Units Dev(Min)
5.00 ng/uL
0.
05
%Recovery
3 .31 ng/uL
27.15 ng/uL
2.06 ng/uL
2 .80 ng/uL
3 .42 ng/uL
3.19 ng/uL
1.14 ng/uL
3 . 74 ng/uL
3.66 ng/uL
36.39 ng/uL
82.
67.
51.
70.
85.
79.
28.
93.
91.
90.
4.28 ng/uL 106.
5.77 ng/uL 144.
3.92 ng/uL
3.45 ng/uL
0.37 ng/uL
2.30 ng/uL
2.52 ng/uL
1.88 ng/uL
97.
86.
9.
57.
62.
46.
86%
87%
40%
01%
41%
80%
55%
62%
47%
99%
98%
26%
97%
37%
37%
53%
93%
89%
Qvalue
14.21 ng/uL
Not Detected
0.53 ng/uLm
1.08 ng/uL
1.27 ng/uL
Not Detected
Not Detected
0.22 ng/uL
0.08 ng/uL#
0.21 ng/uL#
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
yr
98
63
96
90
87
69
1
(#) = qualifier out of range (m) = manual integration
ENG1350.D PES1.M Wed May 26 09:53:38 1999 HP 5989B
Page 1
-------
Quantitation Report
Data File : C:\HPCHEM\1\DATA\9919\ENG1350.D
Acq On : 25 May 99 5:07 pm
Sample : PES INLET 1 REPLICATEANALYSIS 4/2/99
Misc :
Quant Time: May 26 9:52 1999
Method
Title
Last Update
Response via
C:\HPCHEM\1\METHODS\PES1.M
Tue May 25 13:51:07 1999
Multiple Level Calibration
Vial: 5
Operator: JEMcCartney
Inst : HP 5989B
Multiplr: 1.00
(Abundance
2000000J
1800000^
I
i
J
J
1600000J
1 1400000 J
1200000 I
1000000J
800000.
600000.
400000.
200000 J
TIC: ENG1350.D
(Ti
me-->
4s
2o!oo
IIS
(
3o!od
4oloo
5oioo
,_
eolod
ENG1350.D PES1.M
Wed May 26 09:53:46 1999
HP 5989B
Page 2
-------
Abundance
800000 :
TIC: ENG1350.D
Time-->
22.10 22.20 22.30
22.40
Abundance Ion 136.00 (135.70 to 136.70TTENG
Jlon 68.00 (67.70 to 68.70): ENG13
200000-
100000-
k
ime - - >
800000:
eooooo:
400000:
200000:
Time--> 22.10 22.20 22.30
TIC: ENG13SO.D
T—i—i—i—r
22.40
Abundancelon 128.00 (127.70 to 128.70): Etffl
800000JIon 127.00 (126.70 to 127.70): ENG
22.29
600000 .
400000.
200000:
Naph t hal ene - <38
Concen: 3.31 ng/uL
RT: 22.24 min Scan# 1567
Delta R.T. 0.06 min
Lab File: ENG1350.D
Acq: 25 May 99 5:07 pm
Tgt Ion-.136 Resp:
Ion Ratio Lower
100
136
68
0
0
0.0
0.0
0.0
3.9
0.0
0.0
585296
Upper
11.5#
0.0
0.0
0.
Time--> 22110
ENGl^bU.D—PEb'l.M
—i—I—i—i—i—i—i—i—i—i—r—i—i—i—i—i—r
22.20 22.30 22.40
Wed May '2h 09:53:49
#3
Naphthalene(CCC)
Concen: 14.21 ng/uL
RT: 22.29 min Scan# 1575
Delta R.T. 0.06 min
Lab File: ENG1350.D
Acq: 25 May 99 5:07 pm
Tgt Ion.-128 Resp: 2637394
Ion
128
127
0
0
Ratio
100
12.9
0.0
0.0
Lower Upper
0.0
0.0
0.0
62.0
0.0
0.0
OCi
HP 5989B
Page 3
-------
Abundance
600000J
400000 '.
200000.
T1C: ENG1J50.D
[Time - - > 23.80
23.90
24.00
24! 10
Abundance Ion 152.00 (151.70 to 152.70):
600000
400000 J
200000
ENG
j
fTime-->
u -t-
23
180 '
23:90
24
!oo '
' 24!
10
(Abundance
100000.
50000 J
TIC: ENG1350.D
Time-->
Abundance Ion 160.00 (159.70 to 160.70): ENG
26.20
26.30
26.40
100000 -
26.29
50000.
Time - - >
26120
26130
26.40
EMGUbU.D—PES1.M
Wed May
#4
2-Methlynaphthalene-dlO
Concen: 27.15 ng/uL
RT: 23.96 min Scan# 1930
Delta R.T. 0.06 min
Lab File: ENG1350.D
Acq: 25 May 99 5:07 ptn
Tgt Ion:152 Resp: 2486575
Ion Ratio Lower Upper
152 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
#5
Acenaphthylene-d8
Concen: 2.06 ng/uL
RT: 26.29 min Scan# 2451
Delta R.T. 0.06 min
Lab File: ENG1350.D
Acq: 25 May 99 5:07 pm
Tgt Ion:160 Resp: 298401
Ion
160
0
0
0
Ratio
100
0.0
0.0
0.0
Lower Upper
0.0
0.0
0.0
0.0
0.0
0.0
0003903
HP 5989B
Page 4
-------
Abundance
100000 .
50000.
T1C: ENG1350.D
Time-->
25.50 26.00 26.50 27. Oo
'
Abundancelon 152.00 (151.70 to 152.70):
Ion 153.00 (152.70 to 153.70): ENG
40000 J
30000
I
20000 J
i
10000 J
i
ime-->
25.50 2600 26.50
i — i — i — i — i — i — r
27.00
jAbundance
100000 .
TIC: ENG1350.D
50000 .
Time - - >
26.60
ie!7o
"i 1 1 1 1 r
26.80
Abundancelon 164.00 (163.70 to 164.70): ENG
100000 J
50000.
26.71
Time-->
26i60
26!70
—i 1 1 1 r
26180
#6
Acenaphthy1ene
Concen: 0.00 ng/uL
Expected RT: 26.27 min
Lab File: ENG1350.D
Acg: 25 May 99 5:07 pm
Tgt Ion: 152
Ion Exp Ratio
152 100
153 14.0
0 0.0
0 0.0
ENG13SU.D
Wed May
09:53:5b 1999
#7
Acenaphthene-dl0
Concen: 2.80 ng/uL m
RT: 26.71 min Scantf 2513
Delta R.T. 0.05 min
Lab File: ENG1350.D
Acq: 25 May 99 5:07 pm
Tgt Ion:164 Resp: 285176
Ion Ratio
164 100
0 0.0
0 0.0
0 0.0
Lower Upper
0.0
0.0
0.0
0.0
0.0
0.0
HP 5989B
0003910
Page 5
-------
Abundance
100000 .
TIC: ENG1350.D
50000 -
0
Time-->
26.70 26.75 26.80 26.85
Abundancelon 154.00 (153.70 to 154.70)
Jlon 153.00 (152.70 to 153.70)
ENG
30000 J
20000
10000
OJ
#8
Acenaphthene(CCC)
Concen: 0.53 ng/uL m
RT: 26.79 min Scan# 2525
Delta R.T. 0.05 min
Lab File: ENG1350.D
Acq: 25 May 99 5:07 pm
Tgt Ion:154 Resp: 52839
Ion Ratio Lower Upper
154 100
153 113.4 43.3 129.7
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Time--:
26.70 26.
T—i—r—i—i—i—i—i—i—i—i—r
26.80 26.85
(Abundance
.
100000 -
50000 -
TIC: ENG1350.D
Time-->
ADundanceion I7b.oo (175.70 to 176.70): ENG
0
27:90
1 - 1 - 1 - 1
28.00
1 - 1 - 1 - 1 - 1 - r
28llO
100000 .
50000.
28.00
PKS1.M
Wed May 2b
1999
#9
Fluorene-dlO
Concen: 3.42 ng/uL
RT: 28.00 min Scan# 2709
Delta R.T. 0.05 min
Lab File: ENG1350.D
Acq: 25 May 99 5:07 pm
Tgt Ion:176 Resp: 326435
Ion Ratio Lower Upper
176 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
HP 5989B
39'j
Page 6
-------
Abundance
100000 .
50000 .
TIC: ENG1350.D
Time-->
27.90 28.00 28.10 28.20 28.30
Abundance Ion 16 67 00 (165.70 to 166.70) : ENG
40000JIon 165.00 (164.70 to 165,70): ENG
I 30000J
20000 J
10000
Time-->
27:90 28.00 28.10 28.20 28.30
#10
Fluorene
Concen-. 1.08 ng/uL
RT: 28.07 min Scan# 2720
0.05 min
ENG1350.D
Delta R.T.
Lab File:
Acq: 25 May 99 5:07 ptn
Tgt Ion:166 Resp: 110068
Ion Ratio Lower Upper
166 100
165 83.1 40.0 119.9
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance
200000
150000 J
100000:
50000 J
TIC: EUG1350.D
Time--> 30.30
30.40
3o!so
Abundancelon 188.00 (187.70 to 188.70): ENG
Ion 94.00 (93.70 to 94.70): ENG13
30.44
100000 .
50000 .
Time--> 30.30
—i 1 1 1 r
30.40
ENG1350.D—PES1.M
•T 1 1 1 r
30.50
Wed May 2b 09:54:01
#11
Phenanthrene-dl0
Concen: 3.19 ng/uL
RT: 30.44 min Scan# 3079
Delta R.T. 0.06 min
Lab File: ENG1350.D
Acq: 25 May 99 5:07 pm
Tgt Ion:188 Resp: 374762
Ion Ratio
188 100
94 15.3
0 0.0
0 0.0
Lower Upper
5.8
0.0
0.0
17.2
0.0
0.0
000-3212
HP 5989B Page 7
-------
Abundance
200000 J
150000 J
100000:
50000:
Time - - >
TIC: ENG1350.D
30.50
30.60
Abundance Ion 178.00 (177.70 to 178.70}
Ion 176.00 (175.70 to 176.70)
30.50
60000:
40000
ENG
20000
0 J
Time-->
30.40
30.50
30.60
#12
Phenanthrene
Concen: 1.27 ng/uL
RT: 30.50 min Scan#"3088
Delta R.T. 0.06 min
Lab File: ENG1350.D
Acq: 25 May 99 5:07 pm
Tgt Ion-.178 Resp: 164935
Ion Ratio Lower Upper
178 100
176 12.6 8.5 25.4
0 0.0 0.0 0.0
0 0.0 0.0 0.0
'Abundance
I 200000^
150000:
100000:
50000 J
01
TIC: ENG1350.D
Time-->30.45 30.50 30.55 30.60 30.65
Abundance Ion 188.Do (187.70 to 188.70): ENG
94.00 (93.70 to 94.70): ENG13
100000.
50000
Tirae-->30.45 30.50 30.55 30.60 30.65
ENGTJSDTDPESl.
wea
#13
Anthracene-dl0
Concen: 1.14 ng/uL m
RT: 30.58 min Scan# 3100
Delta R.T. 0.06 min
Lab File: ENG1350.D
Acq: 25 May 99 5:07 pm
Tgt Ion:188 Resp: 111945
Ion Ratio
188 100
94 109.3
0 0.0
0 0.0
Lower Upper
6.6
0.0
0.0
19. 6#
0.0
0.0
HP 5989B
Page 8
-------
Abundance
200000 J
TIC: ENG1350.D
Time--> 29.50 30.00, 30.50 31.00 31.50
[Abundance Ion 178700 (177770 to 178.70): ENG
.Ion 176.00 (175.70 to 176.70): ENG
60000:
40000
20000 -i
ime-->29.50 30.00 30.50
T—r
31150
#14
Anthracene
Concen: 0.00 ng/uL
Expected RT: 30.57 min
Lab File: ENG1350.D
Acq: 25 May 99 5:07 pm
Tgt Ion: 178
Ion Exp Ratio
178 100
176 16.2
0 0.0
0 0.0
TIC: ENG1350.D
Time-->
33140
33160
33180
Abundance Ion 212.00 (211.70 to 212.70): ENG
Ion 106.00 (105.70 to 106.70): ENG
150000 J
100000 '.
50000 .
rime-->
33.40
33160
ENGUbO.D—PKS1.M
Wed May
U9:54:UB
#15
Fluoranthene-dl0
Concen: 3.74 ng/uL
RT: 33.59 min Scan# 3622
Delta R.T. 0.08 min
Lab File: ENG1350.D
Acq: 25 May 99 5:07 pm
Tgt Ion:212 Resp: 389033
Ion Ratio Lower Upper
212 100
106 7.3 8.0 23.8#
0 0.0 0.0 0.0
0 0.0 0.0 0.0
OCC-33II
HP 5989B Page 9
-------
Abundance
1500000-
1000000.
500000 1
0.
Time-->
tom?8ge
150000 -
i
i
TIC: ENGl3bO.D
^__^v_/v_JL
32150 33! do' 33!50 '34!do 34150
Ion 202.00 (201.70 to 202.70): ENG
Ion 101.00 (100.70 to 101.70): ENG
j
100000 J
50000-j ^
Time-->
i ^__JA_^_|_
32150' '33:00 '33 50' '34.001 '34.501
100000.
Time-->34.00
34.20
34.40
#16
Fluoranthene(CCC)
Concen: 0.00 ng/uL
Expected RT: 33.56 min
Lab File: ENG1350.D
Acq: 25 May 99 5:07 pm
Tgt Ion: 202
Ion Exp Ratio
202 100
101 13.7
0 0.0
0 0.0
tlC: ENG1350.D
Abundancelon 212.00 (211.70 to 212.70): ENG
Ion 106.00 (105.70 to 106.70): ENG
34.27
100000.
50000 -
Time-->34 .00
34120
34:40
ENG1350.DPES1. M
#17
Pyrene-dlO
Concen: 3.66 ng/uL
RT: 34.27 min Scan# 3724
Delta R.T. 0.09 min
Lab File: ENG1350.D
Acq: 25 May 99 5:07 pm
Tgt Ion:212 Resp: 415758
Ion Ratio Lower Upper
212 100
106 5.2 8.6 25.6#
0 0.0 0.0 0.0
0 0.0 0.0 0.0
r\-'r-
u*J £ - >
wea May 26 uy:34:11 iyyy
HP 5989B
Page 10
-------
TIC: ENG1350.D
Abundance
200000 J
150000:
100000:
50000:
Time--> 34:20 34!25 34l30 34.35 34.40
Abundancelon 202.00 (201.70 to 202.70):
lion 101.00 (100.70 to 101.70):
34.32
20000 .
10000 .
0 -
ENG
rrime--> 34 .20 34.25 34.30 34.35 34.40
#18
Pyrene
Concen: 0.22 ng/uL
RT: 34.32 min Scan# 3732
Delta R.T. 0.09 min
Lab File: ENG1350.D
Acq: 25 May 99 5:07 pm
Tgt Ion:202 Resp: 28655
Ion Ratio Lower Upper
202 100
101 20.8 7.8 23.3
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance
1500000 '.
1000000 '.
500000 J
0
Time-->
TIC: ENG1350.D
34.40
34:60
34.80
(Abundance I on 244.00 (243.70 to244.70): ENG
Ion 122.00 (121.70 to 122.70): ENG
34.59
1000000.
500000-
0.
Time-->
34.40
34:60
34.80
ENG1350.DPES1.M
#19
p-Terphenyl-d!4
Concen: 36.39 ng/uL
RT: 34.59 min Scan# 3772
Delta R.T. 0.09 min
Lab File: ENG1350.D
Acq: 25 May 99 5:07 pm
Tgt lon:244 Resp: 3371875
Ion Ratio
244 100
122 20.4
0 0.0
0 0.0
Lower Upper
6.7
0.0
0.0
19. 9#
0.0
0.0
occ
Wed May 2b 09:54:14^ 1999
HP 5989B
Page 11
-------
Abundance
400000 .,
300000:
200000 J
100000:
TIC: ENG1350.D
Time--:38l70 38180 38:90 39100 39.10
Abundance I on 2 40. (Jo (239.70 to 240.70): ENG
]Ion 120.00 (119.70 to 120.70): ENG
150000 J
100000
50000 J
ime--;38.70 38.80 38.90 39.00 39.10
#20
Benzo(a)anthracene-d!2
Concen: 4.28 ng/uL m
RT: 38.93 min Scan# 4425
Delta R.T. 0.16 min
Lab File: ENG1350.D
Acq: 25 May 99 5:07 pm
Tgt Ion:240 Resp: 338473
Ion Ratio Lower Upper
240 100
120 93.9 7.3 21.8#
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance
j
300000J
200000 '.
100000
Time-->
TIC: ENG1350.D
38190
38195
39.00
Abundance Ion 228.00 (227.^70 to 228.70) : ENG
200000Jlon 114.00 (113.70 to 114.70): ENG
150000 J
100000:
rime - - >
38.90
38195
ENGlJbO.D—PBS1.M
Wed May 26 09:b4:17
#21
Benzo(a)anthracene
Concen: 0.08 ng/uL
RT: 38.96 min Scan# 4431
Delta R.T. 0.08 min
Lab File: ENG1350.D
Acq: 25 May 99 5:07 pm
Tgt Ion:228 Resp:
Ion
228
114
0
0
Ratio
100
0.0
0.0
0.0
7495
Lower Upper
6.2
0.0
0.0
18.5#
0.0
0.0
HP 5989B
Page 12
-------
Abundance
400000 H
TIC: ENG1350.D
Time--> 38:90 39.00 39.10 39:20
(Abundance Ion 240 .00 (23 9770 to 240.70)
Jlon 120.00 (119.70 to 120.70)
150000 J
100000 J
50000 J
Time--> 38.90 39:00 39:iO 39.20
ENG
ENG
Abundance
400000^
300000 :
200000:
100000
Time-->
TIC: ENG1350.D
39.00
39:iO
39:20
#22
Chrysene-dl2
Concen: 5.77 ng/uL
RT: 39.09 min Scan# 4450
Delta R.T. 0.15 min
Lab File: ENG1350.D
Acq: 25 May 99 5:07 pm
Tgt Ion:240 Resp: 448673
Ion Ratio Lower Upper
240 100
120 90.6 6.4 19.0#
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundancelon 228.00 (227.70 to 228.70): ENG
Ion 114.00 (113.70 to 114.70): ENG
200000 J
150000 -
100000.
[•itne-->
ENGlJbU.D
39:00 39:iO
IWed May 26 09:54:20
#23
Chrysene(CCC)
Concen: 0.21 ng/uL
RT: 39.08 min Scan# 4449
Delta R.T. 0.02 min
Lab File: ENG1350.D
Acq: 25 May 99 5:07 pm
Tgt Ion:228 Resp: 19965
Ion Ratio Lower Upper
228 100
114 4169.7 5.5 16.3#
0 0.0 0.0 0.0
0 0.0 0.0 0.0
000.3918
HP 5989B
Page 13
-------
Abundance
80000 :
60000 :
TIC: ENG1350.D
40000:
20000:
Time-->
45.80
46.00
46.20
Abundance Ion 264.00 (263.70 to 264.70)
Ion 132.00 (131.70 to 132.70)
46.02
40000
2 0 0 0 0 J
ENG
ENG
!Time-->
45.80
46.00
46.20
#24
Benzo(b)fIuoranthene-dl2
Concen: 3.92 ng/uL m
RT: 46.02 min Scan# 5515
Delta R.T. 0.31 min
Lab File: ENG1350.D
Acq: 25 May 99 5:07 pm
Tgt Ion:264 Resp: 294960
Ion Ratio Lower Upper
264 100
132 44.1 8.0 23.9#
0 0.0 0.0 0.0
0 0.0 0.0 0.0
'Abundance
80000:
eoooo:
40000 j
j
20000:
TIC: ENG1350.D
0 J
' I ''l~~'II—1~1—I—I—I I I—I—I—I—I—I-
45.00 45.50 46.00 46.50
Time-->
Abundance Ion 252.00 (251.70 to 252.70)
20000 .
10000 .
Ion 126.00 (125.70 to 126.70): ENG
Time-->
'45loo' '45!so' Velo'o
i — i — i — i — i
46.50
Wed May
#25
Benzo(b)fluoranthene
Concen: 0.00 ng/uL
Expected RT: 45.92 min
Lab File: ENG1350.D
Acq: 25 May 99 5:07 pm
Tgt Ion: 252
Ion Exp Ratio
252 100
126 14.5
0 0.0
0 0.0
HP S989B
Page 14
-------
Abundance
80000:
60000:
40000:
20000:
TIC: ENG1350.D
Time--> 46.00 46.10 46.20 46.30 46.40
Abundance I on 264.00(263 . 70to^64 .70) : ENG
Ion 132.00 (131.70 to 132.70): ENG
46.21
I
40000 '
20000
!Time--> 46.00 46.10 46.20 46.30 46.40
#26
Benzo(k)fluoranthene-d!2
Concen: 3.45 ng/uL m
RT: 46.21 min Scan# 5545
Delta R.T. 0.28 min
Lab File: ENG1350.D
Acq: 25 May 99 5:07 pm
Tgt Ion:264 Resp: 293965
Ion Ratio Lower Upper
264 100
132 42.2 8.5 25.3#
0 0.0 0.0 0.0
0 0.0 0.0 0.0
[Abundance
i 1
TIC: ENG135CJ.D
[Time--> 45: 00 45:50 46:o'o' '46 I 50' V? I 00'
Abundancelon 252.06 (251.70 to 252.70): ENG
•lion 126.00 (125.70 to 126.70): ENG
20000 .
10000 .
O.J
rime-->45.00 45.50 46.00 46.50 47.00
ENGUbU.D—PBS1.I
Wed May '2k 09:54:2fe
#27
Benzo(k)fluoranthene
Concen: 0.00 ng/uL
Expected RT: 46.09 min
Lab File: ENG1350.D
Acg: 25 May 99 5:07 pm
Tgt Ion: 252
Ion Exp Ratio
252 100
126 15.4
0 0.0
0 0.0
OGO
HP 5989B
Page 15
-------
Abundance
40000.
30000 _
20000 _
10000_
0
Time-->
Abundance
15000^
.
•
10000 :
.
5000 .
"
Time- ->
TIC: ENG1350.D
48160 48.80
Ion 264.00 (263.70 to 264.70): ENG
Ion 132.00 (131.70 to 132.70): ENG
48.73
48160 ' ' 48180
#28
Benzo (a) pyrene-d!2
Concen: 0.37 ng/uL m
RT: 48.73 min Scan# 5931
Delta R.T. 0.36 min
Lab File: ENG1350.D
Acq: 25 May 99 5:07 pm
Tgt Ion:264 Resp: 27042
Ion Ratio Lower Upper
264 100
132 146.6 8.7 25.9#
0 0.0 0.0 0.0
0 0.0 0.0 0.0
(Abundance TIC: ENG1350.D
ENG
40000 |-^-v^^-^/ V^NA^
i
30000 j
1
20000 .]
10000 _
0
Time - - >
Abundance
20000 :
isooo:
10000 :
sooo :
o:
Time - - >
48.00 ' ' 49100 '
Ion 252.00 (251.70 to 252.70): ENG
Ion 126.00 (125.70 to 126.70): ENG
"^"^-S^^^^
~-~~_~-~-^-~-/V__
• i i i i i i i i i i i • -i 1 —
48.00 49100
IJbU.U PEK1.M Wed May 2t> 09:b4:30 1999
#29
Benzo(a)pyrene(CCC)
Concen: 0.00 ng/uL
Expected RT: 48.59 min
Lab File: ENG1350.D
Acq: 2 5 May 99 5:0 7 pm
Tgt Ion: 252
Ion Exp Ratio
252 100
126 15.0
0 0.0
0 0.0
HP 5989B
Page 16
-------
Abundance
60000 j
40000.
20000-
TIC: ENG1350.D
Time-->
61.50
62.00
Abundance Ion 288.00 (287.70 to 288.70): ENG
20000J
j 61.84
15000
10000 J
5000 J
Time--> 61.50 62.00
(Abundance
60000
TIC: ENG1350.D
Time--> 60. 00 6l!00 62^00
Abundance ion 276.05 (275.75 to 276.75
63 .00
15000 J
10000 .
5000 .
6 .
Ion 138.00
275.75 to 276.75) :
137.70 to 138.70):
ENG
J
rime-->60.00
6llo6
62:00
ENGJLJbU.D—PKS1.M
63.00
#30
Indenod, 2, 3-cd)pyrene-dl2
Concen: 2.30 ng/uL m
RT: 61.84 min Scant 8170
Delta R.T. 0.57 min
Lab File: ENG1350.D
Acg: 25 May 99 5:07 pm
Tgt Ion:288 Resp: 205834
Ion Ratio Lower Upper
288 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
#31
Indeno(1,2,3 -cd)pyrene
Concen: 0.00 ng/uL
Expected RT: 61.62 min
Lab File: ENG1350.D
Acq: 25 May 99 5:07 pm
Tgt Ion: 276.05
Ion Exp Ratio
276 100
138 30.0
0 0.0
0 0.0
00033-2
Wed May 2b U9:B4:33 1999
HP 5989B
Page 17
-------
Sundance
60000 -i
40000 .,
20000 .
TIC: ENG1350.D
Time-->
61.50
62.00
Abundance Ion232..00 (291.70 to 292.70)
61.74
ENG
5000
fTime-->
61.50
62.00
#32
Dibenz(a,h)anthracene-d!4
Concen: 2.52 ng/uL m
RT: 61.74 min Scan# 8151
Delta R.T. 0.54 min
Lab File: ENG1350.D
Acq: 25 May 99 5:07 pro
Tgt Ion:292 Resp: 143934
Ion Ratio Lower Upper
292 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance
60000 -j
'
40000 .
•
•
20000.
0 "
Time-->
Abundance
20000-
15000 J
10000:
5000:
o:
Time - - >
TIC: ENG1350.D
/ \
v-^^s^^ v^xx^
61.00 62.00
Ion 278.00 (277.70 to 276.70): ENG
Ion 139.00 (138.70 to 139.70): ENG
'VA"*k^^
"T i i i i , , , | , , , , — | . —
61.00 62.00
iJiU.D PESI.M Wed May 26 U9:b4:JV 1999
#33
Dibenz(a,h)anthracene
Concen: 0.00 ng/uL
Expected RT: 61.63 min
Lab File: ENG1350.D
Acq: 2 5 May 99 5:0 7 pm
Tgt Ion: 278
Ion Exp Ratio
278 100
139 21.0
0 0.0
0 0.0
HP 5989B
Page 18
-------
Abundance
20000.
15000:
10000:
TIC: ENG1350.D
Time-->
65.00
65.50
66100
Abundance Ion 288.00 (287.70 to 288.70)
15000-1
J 65.45
ENG
10000 J
5000
J
OJ
Time--> 65 loo' ' ' 65lsO
66 100
#34
Benzo(g,h,i)perylene-d!2
Concen: 1.88 ng/uL m
RT: 65.45 min Scan# 8926
Delta R.T. 0.67 min
Lab Pile: ENG1350.D
Acq: 25 May 99 5:07 pm
Tgt lon:288 Resp: 141794
Ion Ratio Lower Upper
288 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance
30000 :
20000 :
10000 :
0 '
Time-->
Abundance
10000.
5000.
i
1
0.
rime-->
TIC: ENG1350.D
t^n
___V\_____
64 loo ' ' 65 loo ' ' eel od
Ion 276.00 (275.70 to 276.70): ENG
Ion 138.00 (137.70 to 138.70): ENG
^^^N^ . _
^^ ^^.fi^i^^^
64ioo ' ' eslod ' ' eelod
#35
Benzo(g,h,i)perylene
Concen: 0.00 ng/uL
Expected RT: 65.19 min
Lab File: ENG1350.D
Acq: 25 May 99 5:07 pm
Tgt Ion: 276
Ion Exp Ratio
276 100
138 26.6
0 0.0
0 0.0
00015^4
HP 59S9B
Page 19
-------
SUMMARY1.XLS
2uantitation Report Summary
Data File
Date Analyzed:
Sample ID
Method ID
Operator
Instrument
Compounds
Naphthalene(CCC)
Acenaphthylene
Acenaphthene(CCC)
rluorene
Dhenanthrene
Anthracene
Fluoranthene(CCC)
Pyrene
3enzo(a)anthracene
Chrysene(CCC)
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Benzo(a)pyrene(CCC)
lndeno(1,2,3-cd)pyrene
Dibenz(a, h)anthracene
3enzo(g,h,i)perylene
ENG1330.D
05/19/99
PES INLET 2 4/2/99
PES
JEMcCartney
HP 5989B
Area
1870681
55130
17761
0
287844
0
62498
80284
0
0
0
0
0
0
0
0
* PQL - practical quantitation limit
Surrogate Recoveries
Compound
Naphthalene-d8
Acenaphthylene-d8
Acenaphthene-d10
Fluorene-d10
Phenanthrene-d10
Anthracene-d10
Fluoranthene-d10
Pyrene-d10
Benzo(a)anthracene-d12
Chrysene-d12
Benzo(b)fluoranthene-d12
Benzo(k)fluoranthene-d12
Benzo(a)pyrene-d12
lndeno(1 ,2,3-cd)pyrene-d12
Dibenz(a,h)anthracene-d14
Benzo(g,h,i)perylene-d12
Recovery Standard
Compound
2-Methlynaphthalene-d1 0
p-Terphenyl-d14
Compiled by:
Reviewed by:
Reviewed by:
Cone.
(ng/pL)
10.537
0.307
0.148
0.000
1.323
0.000
0.266
0.316
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Cone. (ng/uL)
3.85
2.31
3.30
3.88
4.63
1.19
5.48
5.33
4.45
5.02
5.72
5.09
0.51
2.80
3.18
2.30
Concentration (ng/uL)
s
31.30
46.30
/
_^,
PQL*
(ng/pL)
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
/" x** ^
x^Y ^fibtt^^l < /'/ 7 / '"
o >
Cone.
(ng/sample)
10537.4
307.2
148.3
0.0
1323.0
0.0
266.1
316.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
Cone, (ng/sample)
w/ Surr. correction
10933.9
531.3
179.8
0.0
1323.0**
0.0
266.1**
316.0**
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
** No surrogate correction made
% Recovery
96.37
57.82
82.50
97.00
115.81
29.77
136.94
133.17
111.34
125.38
143.07
127.20
12.72
70.01
79.61
57.39
% Recovery
78.26
115.74
r
^
-------
Quantitation Report
Data File :
Acq On :
Sample :
Misc :
Quant Time;
C:\HPCHEM\1\DATA\9919\ENG1330.D
19 May 99 10:11 pm
PES INLET 2 4/2/99
May 25 9:51 1999
Vial: 10
Operator: JEMcCartney
Inst : HP 5989B
Multiplr: 1.00
Method
Title
Last Update
Response via
C:\HPCHEM\1\METHODS\PES .M
Mon May 24 16:23:27 1999
Multiple Level Calibration
Internal Standards
R.T. Qlon Response Cone Units Dev(Min)
1)
2 , 2-Dif luorobiphenyl
24.
62
190
500742
System Monitoring Compounds
2)
4)
5)
7)
9)
11)
13}
15)
17)
19)
20)
22)
24)
26)
28)
30)
32)
34)
Naphthalene -d8
2-Methlynaphthalene-dlO
Acenaphthylene-d8
Ac enaphthene - dl 0
Fluorene-dlO
Phenant hr ene - dl 0
Anthracene- dlO
Fluor anthene-dlO
Pyrene-dlO
p-Terphenyl-d!4
Benzo (a) anthracene-dl2
Chrysene-dl2
Benzo (b) f Iuoranthene-dl2
Benzo (k) f Iuoranthene-dl2
Benzo (a)pyrene-dl2
Indenod, 2, 3-cd)pyrene-dl2
Dibenz (a, h) anthracene-d!4
Benzo (g,h, i)perylene-d!2
22.
24.
26.
26.
28.
30.
30.
33.
34.
34.
38.
39.
46.
46.
48.
61.
61.
65.
26
00
32
74
04
48
61
63
32
64
98
14
07
27
,77
.97
,89
,58
136
152
160
164
176
188
188
212
212
244
240
240
264
264
264
288
292
288
588463
2534418
372248
352153
449264
831257
185683
973206
1038935
6829315
557320
760410
638958
773504
51425
379548
253393
246353
Target Compounds
3)
6)
8)
10)
12)
14)
16)
18)
21)
23)
25)
27)
29)
31)
33)
35)
Naphthalene (CCC)
Acenaphthylene
Acenaphthene (CCC)
Fluorene
Phenanthrene
Anthracene
Fluoranthene (CCC)
Pyrene
Benzo (a) anthracene
Chrysene(CCC)
Benzo (b) f luoranthene
Benzo (k) f luoranthene
Benzo ( a ) pyrene ( CCC )
Indeno (1,2,3- cd) pyrene
Dibenz (a, h) anthracene
Benzo (g, h, i) perylene
22,
.32
26.35
26
0
30
0
33
34
0
0
0
0
0
0
0
0
.82
.00
.54
.00
.68
.37
.00
.00
.00
.00
.00
.00
.00
.00
128
152
154
166
178
178
202
202
228
228
252
252
252
276
278
276
1870681
55130
17761
287844
62498
80284
5.00 ng/uL 0
.03
%Recovery
3 .85 ng/uL 96
31.30 ng/uL 78
2.31 ng/uL 57
3.30 ng/uL 82
3 .88 ng/uL 97
4.63 ng/uL 115
1.19 ng/uL 29
5.48 ng/uL 136
5.33 ng/uL 133
46.30 ng/uL 115
4.45 ng/uL 111
5.02 ng/uL 125
5.72 ng/uL 143
5.09 ng/uL 127
0.51 ng/uL 12
2.80 ng/uL 70
3 .18 ng/uL 79
2.30 ng/uL 57
.37%
.26%
.82%
.50%
.00%
.81%
.77%
.94%
.17%
.74%
.34%
.38%
.07%
.20%
.72%
.01%
.61%
.39%
Qvalue
10.54 ng/uL
0.31 ng/uL
0.15 ng/uLm
Not Detected
1.32 ng/uL
Not Detected
0.27 ng/uL#
0.32 ng/uL
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
ftpp 10 >;;
_y>_ \>±i'~>**~j.
88
89
93
99
31
87
(#) = qualifier out of range (m) = manual integration
ENG1330.D PES.M Tue May 25 09:52:39 1999 HP 5989B
Page 1
-------
Quantitation Report
Data File : C:\HPCHEM\1\DATA\9919\ENG1330.D
Acq On : 19 May 99 10:11 pm
Sample : PES INLET 2 4/2/99
Misc :
Quant Time: May 25 9:51 1999
Method
Title
Last Update
Response via
: C:\HPCHEM\1\METHODS\PES.M
: Mon May 24 16:23:27 1999
: Multiple Level Calibration
Vial: 10
Operator: JEMcCartney
Inst : HP 5989B
Multiplr-. 1.00
[Abundance
1 4500000 j
4000000 -
i
.• 3500000 .
3000000 n
2500000 .]
tlC: ENG1330.D
2000000
FJMG1330.D PES.M
Tue May 25 09:52:47 1999
HP 5989B
Page 2
-------
Abundance
800000:
TIC: ENG133U.D
Time - - >
22.10 22.20 22.30 22.40
kbundancelon 136.00 (135.70 to 136.70): ENG
lon 68.00 (67.70 to 68.70): ENG13
300000
200000 j
100000J
ime-->
22.10 22.20 22.30 22.40
#2
Naphthalene-d8
Concen: 3.85 ng/uL
RT: 22.26 min Scan# 1571
Delta R.T. 0.03 min
Lab File: ENG1330.D
Acq: 19 May 99 10:11 pm
Tgt Ion:136 Resp: 588463
Ion
136
68
0
0
Ratio
100
0.0
0.0
0.0
Lower Upper
10.1
0.0
0.0
30.1#
0.0
0.0
[Abundance
800000
TIC: ENG1330.D
Time-->
22.20
22.30
22.40
Abundance!on 128.00
800000J
600000:
400000:
200000:
0 j
Ion 127.00
(127.70 to 128.70)
(126.70 to 127.70)
22.32
ENG
ENG
Time- - >
22.20
22.30
22:40
ENG1JJO.D—PES.M
Tue May 2b U9:52:bO
Naphthalene(CCC)
Concen: 10.54 ng/uL
RT: 22.32 min Scan# 1579
Delta R.T. 0.03 min
Lab File: ENG1330.D
Acq: 19 May 99 10:11 pm
Tgt Ion:128 Resp: 1870681
Ion Ratio Lower Upper
128 100
127 14.3 0.0 60.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
HP 5989B
Page 3
-------
Abundance
1000000 J
TIC: ENG1330.D
I 500000.
0
Time-->
23.90
24.00
24.10
Abundance Ion 152.00 (151.7 0 to 152.70) : ENG
1000000 .
24.00
500000 J
0 _^
#4
2-Methlynaphthalene-dlO
Concen: 31.30 ng/uL
RT: 24.00 min Scan# 1941
Delta R.T. 0.04 min
Lab File: ENG1330.D
Acq: 19 May 99 10:11 pm
Tgt Ion:152 Resp: 2534418
Ion Ratio Lower Upper
152 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
- ->
23.90
24.00
(Abundance
150000 J
100000:
50000 .
TIC: ENG1330.D
Time--> 26J20 26:30 26:40
Abundance Ion 160.00 (159.70 to 160.70)
150000 -
100000 .
50000 .
o:
26.32
rime - - >
26.20
26.30
—i 1 1 1 1 r
26140
JNGT37DTD—PES.M
Tue May 2b
#5
Acenaphthylene-d8
Concen: 2.31 ng/uL
RT: 26.32 min Scan# 2454
Delta R.T. 0.03 min
Lab File: ENG1330.D
Acq: 19 May 99 10:11 pm
Tgt Ion:160 Resp:
Ion Ratio Lower
160 100
0 0.0 0.0
0 0.0 0.0
0 0.0 0.0
372248
Upper
0.0
0.0
0.0
HP 5989B
Page 4
-------
Abundance
TIC: ENG1330.D
fTime-->26.25 26130 26135
26.40
Abundanceion 152.00 (151.70 to 152.70): ENG
40000jlon 153.00 (152.70 to 153.70): ENG
26.35
30000:
20000 :
10000:
ime-->26:25 26.30 26:35 26140
#6
Acenaphthylene
Concen: 0.31 ng/uL
RT: 26.35 min Scantf 2459
Delta R.T. 0.03 min
Lab File: ENG1330.D
Acq: 19 May 99 10:11 pm
Tgt Ion:152 Resp: 55130
Ion Ratio Lower Upper
152 100
153 19.8 7.6 22.6
0 0.0 0.0 0.0
0 0.0 0.0 0.0
(Abundance
2000001
150000:
100000:
;
50000:
<
rime-->
TIC: ENG1330.D
26.65 26.70 26175 26180 26.85
Abundancelon 164.00 (163.70 to 164.70):
200000
26.74
150000
100000 :
50000J
0 J
Time-->
26.65 26170 2617526:8026:85
ENGT3TU7T3—PES.M
Tue May 2b
#7
Acenaphthene-dl0
Concen: 3.30 ng/uL m
RT: 26.74 min Scan# 2516
Delta R.T. 0.03 min
Lab File-. ENG1330.D
Acq: 19 May 99 10:11 pm
Tgt Ion:164 Resp:
Ion Ratio Lower
164 100
0 0.0 0.0
0 0.0 0.0
0 0.0 0.0
352153
Upper
0.0
0.0
0.0
HP 5989B
Page 5
-------
Abundance
100000.
50000 .
TIC: ENG1330.D
0
Time-->
26.80
26!85
Abundance ion 154.00 (153.70 to 154.70)
lion 153.00 (152.70 to 153.70)
30000 j
1NG~
ENG
|Time-->
26.80
26.85
#8
Acenaphthene(CCC)
Concen: 0.15 ng/uL m
RT: 26.82 min Scan# 2528
Delta R.T. 0.03 rain
Lab File: ENG1330.D
Acq: 19 May 99 10:11 pm
Tgt Ion:154 Resp: 17761
Ion Ratio Lower Upper
154 100
153 162.2 43.5 130.3#
0 0.0 0.0 0.0
0 0.0 0.0 0.0
TIC: ENG1330.D
[Abundance
200000.
100000 .
J
U -1—i—| 1—i—i—I—i—i :—i—I—i—i—i—i—|—!—
Time--> 27.95 28.00 28.05 28llO
Abundance Ion 176.00 (175 .70 to 176.70) :
28.04
200000 .
100000-
0.
Time--> 27 I 95 ' ' 28 I 00' 28!05
NG1J30.D—PKS.M
—I—I—i—I 1—r
28llO
Tue May '2b
#9
Fluorene-dlO
Concen: 3.88 ng/uL m
RT: 28.04 min Scan# 2713
Delta R.T. 0 . 04 rain
Lab File: ENG1330.D
Acq: 19 May 99 10:11 pra
Tgt Ion: 176 Resp:
Ion Ratio Lower
176 100
0 0.0 0.0
0 0.0 0.0
0 0.0 0.0
449264
Upper
0.0
0.0
0.0
HP 5989B
Page 6
-------
Abundance
200000-
100000-
TICT ENG1330.D
Time--> 2V!00 27.50 28.00 28.50 29.00
Abundancelon 166.00 (165.70 to 166.70): ENG
Ion 165.00 (164.70 to 165.70): ENG
60000J
40000 _
20000 J
0 1
[Time--> 27lOO 27.50 28.00 28.50 29.00
#10
Fluorene
Concen: 0.00 ng/uL
Expected RT: 28.08 min
Lab File: ENG1330.D
Acq: 19 May 99 10:11 pm
Tgt Ion: 166
Ion Exp Ratio
166 100
165 76.2
0 0.0
0 0.0
Abundance
\
600000'.
TIC: ENG1T30TD
\
400000
200000 1
1
oi
Time--> 30.30
30.40
30.50
30.60
Abundance Ion 188.00 (187.70 to 188.70): ENG
400000JIon 94.00 (93.70 to 94.70): ENG13
^ 30.48
300000J
200000
100000J
Time--> 30.30 30.40 30.50 30.60
ENGT3TDTD PES . M
#11
Phenanthrene-dl0
Concen: 4.63 ng/uL
RT: 30.48 min Scan# 3083
Delta R.T. 0.05 min
Lab File: ENG1330.D
Acq: 19 May 99 10:11 pm
Tgt Ion:188 Resp: 831257
Ion Ratio
188 100
94 33.1
0 0.0
0 0.0
Lower Upper
15.1
0.0
0.0
45 .1
0.0
0.0
TUB May 25 OS:53:02 1999
HP 5989B
Page 7
-------
Abundance
600000-
400000.
200000 J
TIC: ENG1330.D
tri
ime-->
30.50
30.60
(Abundance
150000J
100000
50000 _
Ion 178.00 (177.70 to 178770): ENG
Ion 176.00 (175.70 to 176.70): ENG
30.54
30.50
30:60
#12
Phenanthrene
Concen: 1.32 ng/uL
RT: 30.54 min Scan# 3092
Delta R.T. 0.05 min
Lab File: ENG1330.D
Acq: 19 May 99 10:11 pm
Tgt Ion:178 Resp: 287844
Lower Upper
10.1 30.1
0.0 0.0
0.0 0.0
Ion Ratio
178 100
176 20.4
0 0.0
0 0.0
[Abundance
400000
300000 H
200000 J
100000 J
TIC: ENG1330TD
Time-->
30.55
30.60
1 1 1 1 I ! 1 I—
30.65 30.70
AiDunaanceion 188.00 (187.70 to 188.70) : EHG
Ion 94.00 (93.70 to 94.70): ENG13
200000 -
100000 .
0 .
30.61
Time-->
30.55 30.60 30:65
ENG1330.DPES.M
-i—i—i—r-
30!70
Tue May 2b U9:b.i:Ub 1999
#13
Anthracene-dl0
Concen: 1.19 ng/uL m
RT: 30.61 min Scant 3104
Delta R.T. 0.04 min
Lab File: ENG1330.D
Acq: 19 May 99 10:11 pm
Tgt Ion:188 Resp: 185683
Ion Ratio Lower Upper
188 100
94 270.3
0 0.0
0 0.0
15.1
0.0
0.0
45.1#
0.0
0.0
HP 5989B
Page 8
-------
Sundance
600000.
400000 -
200000 -
TIC: ENG1330.D
0
Time-->29.50 30.00 30.50 31.00 31.50
Abundance Ion 178.00 (177.70 to 178.70):
Ion 176.00 (175.70 to 176.70):
150000 J
100000
50000 J
ENG
ENG
u
ime-->29.50 30.00 30.50 31.00 31.50
#14
Anthracene
Concen: 0.00 ng/uL
Expected RT: 30.62 min
Lab File: ENG1330.D
Acq: 19 May 99 10:11 pm
Tgt Ion: 178
Ion Exp Ratio
178 100
176 20.0
0 0.0
0 0.0
[Abundance
I
600000:
400000:
200000:
TIC: ENG1330.D
0
Time-->
33150 33160 33.70 33.80
Abundance!on 212.00 (211.70 to 212.70)
ENG
400000Jlon 106.00 (105.70 to 106.70): ENG
33.63
300000 J
200000J
100000:
rime-->
33.50 33.60 33.70 33.80
ENGT3T07I3—PES.M
Tue May 2b 09:53:08
#15
Fluoranthene-dl0
Concen: 5.48 ng/uL
RT: 33.63 min Scan# 3625
Delta R.T. 0.05 min
Lab File: ENG1330.D
Acq: 19 May 99 10:11 pm
Tgt Ion:212 Resp: 973206
Ion Ratio
212 100
106 39.4
0 0.0
0 0.0
Lower Upper
15.1
0.0
0.0
45.1
0.0
0.0
OCG:
HP 5989B
Page 9
-------
Abundance
600000.
400000 :
200000 J
0 1
TIC: ENG1330.D
Time- ->33 IBS' '33 1 60 '33 1 65 '33.70 33! 75' ' ' '
^bundancelon 202.00 (201.70 to 202.70): ENG
Ion 101.00 (100.70 to 101.70): ENG
60000^ ^-—~~-\-_
40000 .
20000 .
o :
Time-->33
33 .68
55 33.60 33 65 33 70 33175
#16
Fluoranthene (CCC)
Concen: 0.27 ng/uL
RT: 33.68 min Scan# 3633
Delta R.T. 0.05 min
Lab File: ENG1330.D
Acq: 19 May 99 10:11 pm
Tgt Ion:202 Resp: 62498
Ion Ratio Lower Upper
202 100
101 62.5 13.6 40. 6#
0 0.0 0.0 0.0
0 0.0 0.0 0.0
(Abundance
800000 J
TIC: ENG1330.D
200000 Ji
i I i—i—i—i—I—i—i—i—i—I—i—i—i—i—|—i—i—i—i—I—i—i—r
Time--> 34.10 34.20 34.30 34.40 34.50
Abundanceion 212.00 (211.70 to 212.70): ENG
Ion 106.00 (105.70 to 106.70): ENG
34.32
400000:
300000:
200000:
100000;
i_ . ' I !—'—'—'—I—'—!—i—i—I—i—i—r—i—i—i—i—i—i—i—i—i—r
Time--> 34.10 34.20 34.30 34.40 34150
PE5TFT
Tue May
Pyrene-dlO
Concen: 5.33 ng/uL
RT: 34.32 min Scan# 3728
Delta R.T. 0.07 min
Lab File: ENG1330.D
Acq: 19 May 99 10:11 pm
Tgt Ion:212 Resp: 1038935
Ion
212
106
0
0
Ratio
100
37.6
0.0
0.0
Lower Upper
17.1
0.0
0.0
51.1
0.0
0.0
HP 5989B
Page 10
-------
Abundance
800000 J
TIC: ENG1330.D
Time--> 34.25 34.30 34.35 34.40 34.45
Abundance Ion 202.00 (201.70 to 202.70): ENG
jlon 101.00 (100.70 to 101.70): ENG
60000 J
•^ "•— - —.
34.37
40000 '.
20000 J
ime--> 34:25 34.30 34.35 34:40 34.45
#18
Pyrene
Concen: 0.32 ng/uL
RT: 34.37 min Scan# 3736
Delta R.T. 0.07 min
Lab File: ENG1330.D
Acq: 19 May 99 10:11 pm
Tgt Ion:202 Resp: 80284
Ion Ratio
202 100
101 39.2
0 0.0
0 0.0
Lower Upper
16.1
0.0
0.0
48.1
0.0
0.0
Abundance
3000000:
2000000:
1000000 J
Time-->
TIC: ENG1330.D
34.40
34:60
34.80
Abundance Ion 244.00
Ion 122.00
2000000 .
1000000 -
(243.70 to 244.70): ENG
(121.70 to 122.70): ENG
34.64
riTtie-->
ENGT3TOTD
34.40
34.60
34.80
#19
p-Terphenyl-d!4
Concen: 46.30 ng/uL
RT: 34.64 min Scan# 3776
Delta R.T. 0.07 min
Lab File: ENG1330.D
Acq: 19 May 99 10:11 pm
Tgt Ion:244 Resp: 6829315
Ion Ratio
244 100
122 29.8
0 0.0
0 0.0
Lower Upper
13.6 40.6
0.0 0.0
0.0 0.0
PES .M
rue May 2509:53:14 19yy
HP 5989B
Page 11
-------
TIC: ENG1330.D
Abundance
400000J
300000:
200000
100000:
|Time--> 38180 38:90 39:00 39-10
(AbundanceIon 240.00 (239.70 to 240.70): ENG
Ion 120.00 (119.70 to 120.70): ENG
200000 J
100000 J
fTime--> 38!80 38.90
39.00
39.10
&b-
lundance
TIC: ENG1330TD
400000
300000 J
200000
100000;
Time-->
38.00 38.50 39.00 39.50
#20
Benzo(a)anthracene-dl2
Concen-. 4.45 ng/uL
RT: 38.98 min Scan# 4430
Delta R.T. 0.10 min
Lab File: ENG1330.D
Acq: 19 May 99 10:11 pm
Tgt Ion:240 Resp: 557320
Ion Ratio
240 100
120 48.2
0 0.0
0 0.0
Lower Upper
15.1
0.0
0.0
45.1#
0.0
0.0
Abundance ion 228.00 (227.70 to 228.70) : ENG
-lion 114.00 (113.70 to 114.70): ENG
100000 -I
50000.
#21
Benzo(a)anthracene
Concen: 0.00 ng/uL
Expected RT: 38.98 min
Lab File: ENG1330.D
Acq: 19 May 99 10:11 pm
Tgt Ion: 228
Ion Exp Ratio
228 100
114 25.0
0 0.0
0 0.0
-------
Abundance
400000 :
300000 :
200000J
100000:
(
Time-->
TICTENGIS 3 0.D
39.00
39.20
39.30
Abundance Ion 240.00 (239.70 to 240,70): ENG
Jlon 120.00 (119.70 to 120.70): ENG
200000 .
100000 H
[Time--> 39.00 39.10
—i 1 1 r
39.20
39.30
Abundance
•I
400000 -5
300000:
200000:
100000:
TIC: ENG1330.D
rime--> 38.50 39.00 39.50 40.00
Abundance Ion 228.00 (227.70 to 228.70): ENG
•|Ion 114.00 (113.70 to 114.70): ENG
0 i
100000 J
50000 -
IH
.itne-->
ENGl3TD~nr
i—i—i—i—i—P—i—r—i—i—i
38!50 39:00 39l50 40lOO
#22
Chrysene-dl2
Concen: 5.02 ng/uL m
RT: 39.14 min Scan# 4455
Delta R.T. 0.11 min
Lab File: ENG1330.D
Acq: 19 May 99 10:11 pm
Tgt Ion:240 Resp: 760410
Ion Ratio
240 100
120 113.9
0 0.0
0 0.0
Lower Upper
15.1
0.0
0.0
45. l#
0.0
0.0
May
#23
Chrysene(CCC)
Concen: 0.00 ng/uL
Expected RT: 39.16 min
Lab File: ENG1330.D
Acq: 19 May 99 10:11 pm
Tgt Ion: 228
Ion Exp Ratio
228 100
114 25.0
0 0.0
0 0.0
HP 5989B
Page 13
-------
[Abundance
200000.
150000 .
100000 .
50000 .
TIC: ENG1330.D
Time-->
45:90 46.00 46.10 46.20
Abundancelon 264.00 (263.70 to 264.70)
Ion 132.00 (131.70 to 132.70)
100000 .
1
50000 J
~ENG~
ENG
46.07
1 ^
\ 0 J
S
Time--> '45:90' 46 loo 46lio' 46l2o'
#24
Benzo(b)fIuoranthene-dl2
Concen: 5.72 ng/uL m
RT: 46.07 min Scan# 5519
Delta R.T. 0.20 min
Lab File: ENG1330.D
Acq: 19 May 99 10:11 pm
Tgt Ion:264 Resp: 638958
Ion Ratio
264 100
132 76.9
0 0.0
0 0.0
Lower Upper
15.1
0.0
0.0
45.1#
0.0
0.0
[Abundance TIC: ENG1330.D
' ] A
1 A / I
ENG
200000 1 A |\
] \ i \
150000 :j I \j \
] / \
100000 - L/"^ — — — ~^^J \-^_^--^^__
1
50000 J
1
•
0 1
Time-->
'45.00 '45150' '45:00' Velso' '47 loo'
Abundancelon 252.00 (251.70 to 252.70): ENG
60000 '.
40000 '.
20000 .
0 "
Time-->
Ion 126.00 (125.70 to 126.70): ENG
^WV\_^^
'45 loo '45l50 46 loo' '46l5'o' ^Vlo'o'
U-iU.D PES.M llie May 25 09:53:^4 1999
#25
Benzo(b)fluoranthene
Concen: 0.00 ng/uL
Expected RT: 46.07 min
Lab File: ENG1330.D
Acq: 19 May 99 10:11 pm
Tgt Ion: 252
Ion Exp Ratio
252 100
126 25.0
0 0.0
0 0.0
HP 5989B
Page 14
-------
Abundance
200000 :
150000 :
100000:
50000:
Time--> 46.00
TIC: ENG1330.D
46.20
46.40
Abundance Ion 264.00 (263.70 to 264.70): ENG
Ion 132.00 (131.70 to 132.70): ENG
46.27
100000 J
50000 J
#26
Benzo(k)fluoranthene-dl2
Concen: 5.09 ng/uL m
RT: 46.27 min Scan# 5550
Delta R.T. 0.20 min
Lab File: ENG1330.D
Acq: 19 May 99 10:11 pm
Tgt Ion:264 Resp: 773504
Ion Ratio
264 100
132 75.5
0 0.0
0 0.0
Lower Upper
15.1
0.0
0.0
45.1#
0.0
0.0
! o J
fTime--> 46loO
46120
T
46140 '
[Abundance
200000:
TIC: ENG1330.D
Time - - >
45.50 46.00 46.50 47.00
Abundancelon 252.00 (251.70 to 252.70): ENG
Ion 126.00 (125.70 to 126.70): ENG
60000 J
40000.
20000.
Time-->
45.50 46.00 46.50 47.00
ENGTJJDTD PES .M
#27
Benzo(k)fluoranthene
Concen: 0.00 ng/uL
Expected RT: 46.23 min
Lab File: ENG1330.D
Acq: 19 May 99 10:11 pm
Tgt Ion: 252
Ion Exp Ratio
252 100
126 25.0
0 0.0
0 0.0
OOG3:
Tue May 2509:53:27 iyyy
HP 5989B
Page 15
-------
Abundance
soooo:
60000 :
40000 _
20000 .
0
Time-->
Abundance
40000 .
30000 .
TIC: ENG1330.D
•^ ^— ^~N-/X~v
^— — ^^ ^x_^_^~^_
n 1 1 1 1 1 r ii 11,1 i i i i I I i i i | i
48160 48.70 48.80 48.90
Ion 264.00 (263.70 to 264.70): ENG
Ion 132.00 (131.70 to 132.70): ENG
"^_- v.- — ~~'— ^-/~^ — v.
^—^ N ^__^---^-~
20000 -j
i
48.77
10000 J
0 -n
ime-->
48160 48170 48.80 48.90
#28
Benzo(a)pyrene-d!2
Concen: 0.51 ng/uL tn
RT: 48.77 min Scan# 5934
Delta R.T. 0.23 min
Lab File: ENG1330.D
Acq: 19 May 99 10:11 pm
Tgt Ion:264 Resp: 51425
Ion Ratio Lower Upper
264 100
132 274.2 15.1 45.1#
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance
80000
60000 J
i
40000 j
j
20000 J
TIC: ENG1330.D
Time-->
0 J_
4800
4900
5000
Abundance Ion 252.00 (251.70 to 252 .70) : ENG
Ion 126.00 (125.70 to 126.70): ENG
40000 .
20000 .
0^
Time - - >
48o
soo
ENG1330.DPES.M
#29
Benzo(a)pyrene(CCC)
Concen: 0.00 ng/uL
Expected RT: 48.74 min
Lab File: ENG1330.D
Acq: 19 May 99 10:11 pm
Tgt Ion: 252
Ion Exp Ratio
252 100
126 25.0
0 0.0
0 0.0
f|f>-n;~<,
-------
Abundance
80000 :
TIC: ENG133 0.D
20000J
Time-->
6l!50
62.00
62150
Abundancelon 288.00 (287.70 to 288.70): ENG
1
30000 J
20000 j
J
10000 J
61.97
ime-->
61.50
62.00
62.50
Abundance
TFC: ENG1330.D
20000
Time - - >
61.00
62.00
63.00
Abundance Ion 276.05 (275.75 to 276.75) : ENG
Jlon 138.00 (137.70 to 138.70): ENG
20000.
10000 .
#30
Indeno(l,2,3-cd)pyrene-dl2
Concen: 2.80 ng/uL
RT: 61.97 min Scan# 8190
Delta R.T. 0.49 min
Lab File: ENG1330.D
Acq: 19 May 99 10:11 pm
Tgt Ion:288 Resp: 379548
Ion Ratio Lower Upper
288 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Time-->
61.00
62.00
63.00
ENG133U.D—PES.M
Tue May '2b U9:b3:34
#31
Indeno(1,2,3 -cd)pyrene
Concen: 0.00 ng/uL
Expected RT: 61.83 min
Lab File: ENG1330.D
Acq: 19 May 99 10:11 pm
Tgt Ion: 276.05
Ion Exp Ratio
276 100
138 64.0
0 0.0
0 0.0
HP 5989B
Page 17
-------
Abundance
80000 :
60000:
40000:
20000
Time - - >
TIC: ENG1330.D
61.50
62.00
Abundance Ion 292.00 (291.70 to 292.70) : ENG
61.89
20000
Time-->
10000 J
0 J
61^50
62.00
#32
Dibenz(a,h)anthracene-d!4
Concen: 3.18 ng/uL m
RT: 61.89 min Scan# 8175
Delta R.T. 0.45 min
Lab Pile: ENG1330.D
Acq: 19 May 99 10:11 pm
Tgt Ion:292 Resp: 253393
Ion Ratio
292 100
0 0.0
0 0.0
0 0.0
Lower Upper
0.0
0.0
0.0
0.0
0.0
0.0
Abundance
80000
TIC: ENG1330.D
40000 J
20000 .,
Time-->
61.00
62.00
63.00
Abundance Ion 278.00 (277.70 to 27S.70) : ENG
Ion 139.00 (138.70 to 139.70): ENG
30000J
20000.
10000 -
o J
Time - - >
61.00
62.00
-i 1 1 r
63100
ENG1J30.D—PES.M
TUB May 2b 09:53:37 1999
#33
Dibenz(a,h)anthracene
Concen: 0.00 ng/uL
Expected RT: 61.85 min
Lab File: ENG1330.D
Acq: 19 May 99 10:11 pm
Tgt Ion: 278
Ion Exp Ratio
278 100
139 25.0
0 0.0
0 0.0
HP 5989B
Page 18
-------
Abundance
30000J
20000-
10000 .
fTime--> 65.00
TIC: ENG1330.D
65.50
66.00
lAbundancelon 288.00 (287.70 to 288.70): ENG
20000J
j
15000
10000 .j
j
5000
65.58
0 J
fTime--> 65^00
65.50
66.00
jAbundance
40000 J")
TIC: ENG1330.D
Time-->64.00
65.00
66.00
#34
Benzo(g,h,i)perylene-dl2
Concen: 2.30 ng/uL m
RT: 65.58 min Scan# 8956
Delta R.T. 0.52 min
Lab File: ENG1330.D
Acq: 19 May 99 10:11 pm
Tgt Ion:288 Resp: 246353
Ion Ratio Lower Upper
288 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance ion 276.00 (275.70 to 276.70): ENG
•Liuuu- 138.00 (137.70 to 138.70): ENG
10000.
5000.
0.
["ime-->64.00
ENG'UJU.D PES.M
65.00 66.00
'I'ue May '2b 09:53:41
#35
Benzo(g,h,i)perylene
Concen: 0.00 ng/uL
Expected RT: 65.44 min
Lab File: ENG1330.D
Acq: 19 May 99 10:11 pm
Tgt Ion: 276
Ion Exp Ratio
276 100
138 25.0
0 0.0
0 0.0
OCi
HP 5989B
Page 19
-------
ENG1349.XLS
Quantitation Report Summary
Data File
Date Analyzed:
Sample ID
Method ID
Operator
Instrument
Compounds
Naphthalene(CCC)
Acenaphthylene
Acenaphthene(CCC)
Fluorene
Phenanthrene
Anthracene
Fluoranthene(CCC)
Pyrene
Benzo(a)anthracene
Chrysene(CCC)
Benzo(b)fluoranthene
Benzo(k)f)uoranthene
Benzo(a)pyrene(CCC)
lndeno(1,2,3-cd)pyrene
Dibenz(a,h)anthracene
Benzo(g,h,i)perylene
ENG1349.D
05/25/99!
PES INLET 3 4/2/99
PES
JEMcCartney
HP 5989B
Area
2059866
0
0
32942
109895
0
0
0
0
0
0
0
0
0
0
0
* PQL - practical quantitation limit
Surrogate Recoveries
Compound
Naphthalene-d8
Acenaphthylene-d8
Acenaphthene-d10
Fiuorene-d10
Phenanthrene-d10
Anthracene-d10
Fluoranthene-d10
Pyrene-d10
Benzo(a)anthracene-d12
Chrysene-d12
Benzo(b)fluoranthene-dl2
Benzo(k)fluoranthene-d12
Benzo(a)pyrene-d12
Indeno(1,2,3-cd)pyrene-d12
Dibenz(a,h)anthracene-d14
Benzo(g,h,i)perylene-d12
Recovery Standard
Compound
2-Methlynaphthalene-d10
p-Terphenyl-d14
Compiled by:
Reviewed by:
Reviewed by:
Cone.
(ng/pl)
9.993
0.000
0.000
0.290
0.762
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Cone. (ng/uL)
3.56
2.31
2.89
3.65
3.50
1.37
4.06
3.98
4.38
4.53
4.53
4.33
0.77
2.45
2.80
2.16
Concentration (ng/pL)
,'
28.55
32.53
I
Cone.
(ng/sample)
9993
0
0
290
762
0
0
0
0
0
0
0
0
0
0
0
% Recovery
88.96
57.68
72.29
91.15
87.58
34.20
101.42
99.57
109.56
113.18
113.30
108.37
19.25
61.22
69.97
54.09
% Recovery
71.37
81.33
?
Cone, (ng/sample)
w/ Surr. correction
11233
0
0
318
870
0
0
0
0
0
0
0
0
0
0
0
QCC33i5
-------
Quantitation Report
Data File
Acq On
Sample
Misc :
Quant Time: May 26
C:\HPCHEM\1\DATA\9919\ENG1349.D
25 May 99 3:51 pm
PES INLET 3 4/2/99
9:44 1999
Vial: 4
Operator: JEMcCartney
Inst : HP 5989B
Multiplr: 1.00
Method
Title
Last Update
Response via
C : \HPCHEM\1\METHODS\PES1 .M
Tue May 25 13:51:07 1999
Multiple Level Calibration
Internal Standards
R.T. Qlon Response Cone Units Dev(Min)
1)
2 , 2-Dif luorobiphenyl
24,
.58
190
533762
System Monitoring Compounds
2)
4)
5)
7)
9)
11)
13)
15)
17)
19)
20)
22)
24)
26)
28)
30)
32)
34)
Naphthalene-d8
2 -Me t hlynaphthalene - dl 0
Acenaphthyl ene - d8
Acenaphthene - dl 0
Fluorene-dlO
Phenant hrene - dl 0
Anthracene - dl 0
Fluoranthene - dl 0
Pyrene -dlO
p-Terphenyl-d!4
Benzo (a) anthracene-d!2
Chrysene-dl2
Benzo (b) f Iuoranthene-dl2
Benzo (k) fluoranthene-d!2
Benzo (a) pyrene -dl 2
Indeno (1,2, 3-cd)pyrene-dl2
Dibenz (a, h) anthracene-d!4
Benzo (g, h, i)perylene-d!2
22
23
26
26
28
30
30
33
34
34
38
39
46
46
48
61
61
65
.23
.96
.29
.70
.00
.43
.57
.58
.26
.58
.90
.06
.00
.18
.72
.82
.77
.43
136
152
160
164
176
188
188
212
212
244
240
240
264
264
264
288
292
288
698128
2904780
372012
327138
387055
456994
149007
468244
502829
3348424
385137
391084
378973
409795
61762
243350
177818
181694
Target Compounds
3)
6)
8)
10)
12)
14)
16)
18)
21)
23)
25)
27)
29)
31)
33)
35)
Naphthalene (CCC)
Acenaphthyl ene
Acenaphthene (CCC)
Fluorene
Phenanthrene
Anthracene
Fluoranthene (CCC)
Pyrene
Benzo (a) anthracene
Chrysene (CCC)
Benzo (b) f luoranthene
Benzo (k) f luoranthene
Benzo (a) pyrene (CCC)
Indeno (1,2,3- cd) pyrene
Dibenz (a,h) anthracene
Benzo (g, h, i) perylene
22
0
0
28
30
0
0
0
0
0
0
0
0
0
0
0
.28
.00
.00
.07
.49
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
128
152
154
166
178
178
202
202
228
228
252
252
252
276
278
276
2059866
32942
109895
5.00 ng/uL 0
.05
%Recovery
3.56 ng/uL 88
28.55 ng/uL 71
2.31 ng/uL 57
2.89 ng/uL 72
3.65 ng/uL 91
3.50 ng/uL 87
1.37 ng/uL 34
4.06 ng/uL 101
3.98 ng/uL 99
32.53 ng/uL 81
4.38 ng/uL 109
4.53 ng/uL 113
4.53 ng/uL 113
4.33 ng/uL 108
0.77 ng/uL 19
2.45 ng/uL 61
2.80 ng/uL 69
2.16 ng/uL 54
.96%
.37%
.68%
.29%
.15%
.58%
.20%
.42%
.57%
.33%
.56%
.18%
.30%
.37%
.25%
.22%
.97%
.09%
Qvalue
9.99 ng/uL
Not Detected
Not Detected
0.29 ng/uLm
0.76 ng/uL
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
97
76
97
.">
b
(#) = qualifier out of range (m) = manual integration
ENG1349.D PES1.M Wed May 26 09:45:50 1999 HP 5989B
Page 1
-------
Quantitation Report
I ita File : C:\HPCHEM\1\DATA\9919\ENG1349.D
i :q On : 25 May 99 3:51 pm
Sample : PES INLET 3 4/2/99
rj.sc :
c lant Time: May 26 9:44 1999
Method
'. -tie
List Update
Response via
C:\HPCHEM\1\METHODS\PES1.M
Tue May 25 13:51:07 1999
Multiple Level Calibration
Vial: 4
Operator: JEMcCartney
Inst : HP 5989B
Multiplr: 1.00
3i '.dance
-I
2000000 J
1800000 1
\
1600000
1400000 J
12,00000
TIC: ENG134S.D
-0,00000
€-°0000
2 '0000 -
19S
2 is
IIS
10
JjJ-ljN
288
a*
28s
30s
2000
30.00
4ooo
sooo
6ooo
TG 349.D PES1.M
00033*7
Wed May 26 09:45:57 1999
HP 5989B
Page 2
-------
Abundance
eooooo:
400000 J
200000.
TIC: ENG1349.D
Time-->
22llO 22:20 22.30 22.40
Abundancelon 136.00 (135.70 to 136.70): ENG
200000JIon 68.00 (67.70 to 68.70): ENG13
22.23
150000
100000
50000 J
"ime - - >
22.10
22130 22.40
Abundance
•I
600000 1
400000:
200000 .
TIC: ENG1349.D
rime-->
22:iO 22:20 22.30 22.40
#2
Naphthalene-d8
Concen: 3.56 ng/uL
RT: 22.23 min Scan# 1566
Delta R.T. 0.05 min
Lab File: ENG1349.D
Acq: 25 May 99 3:51 pm
Tgt Ion:136 Resp:
Ion Ratio Lower
100
136
68
0
0
16.9
0.0
0.0
3.9
0.0
0.0
698128
Upper
11.5#
0.0
0.0
Abundance Ion 128.00 (127.70 to 128.70)
600000.
lon 127.00 (126.70 to 127.70):
22.28
400000-
200000-
0.
ENG
ENG
Time-->
22.10 22.20 22.30 22140
ENG1J49.D—PES1.M
Wed May '2k Uy:4b:Ul
#3
Naphthalene(CCC)
Concen: 9.99 ng/uL
RT: 22.28 min Scan# 1574
Delta R.T. 0.05 min
Lab File: ENG1349.D
Acq: 25 May 99 3:51 pm
Tgt Ion:128 Resp: 2059866
Ion Ratio Lower Upper
128 100
127 13.1 0.0 62.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
HP 5989B
Page 3
-------
Abundance
600000.
400000
200000
TIC: ENG1349.D
w ' I I ; I I I i 1 1 1 1 1 1 1 1 1 1 1 1—
fTime--> 23^80 23.90 24.00 24.10
lAbundancelon 152.00 (151.70 to 152.70): ENG
800000
600000
400000 -j
1
200000 J
23.96
! o:-
fTime-->
23.80 23.
24.00 24.10
Abundance
100000 .,
50000 .
TIC: ENG1349.D
lime-->
AJDunaancelon 160.00 (159.70 to 160.70):ENG
26.20
26:30
26.40
100000 .
50000 .
0.
26.29
rime - - >
26.20
26.30
-i 1 1 r
26.40
#4
2 -Methlynaphthalene-dlO
Concen: 28.55 ng/uL
RT: 23.96 min Scantf 1928
Delta R.T. 0.05 min
Lab File: ENG1349.D
Acq: 25 May 99 3:51 pro
Tgt Ion:152 Resp: 2904780
Ion Ratio Lower Upper
152 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
ING1J49.D—PKS1.M
Wed May
#5
Acenaphthylene-d8
Concen: 2.31 ng/uL
RT: 26.29 min Scantf 2450
Delta R.T. 0.06 min
Lab File: ENG1349.D
Acq: 25 May 99 3:51 pm
Tgt Ion:160 Resp:
Ion Ratio Lower
160 100
0 0.0 0.0
0 0.0 0.0
0 0.0 0.0
372012
Upper
0.0
0.0
0.0
1999
HP 5989B
Page 4
-------
Abundance
100000.
50000-
Time-->
TIC : EN<
I
p\y
'25! SO' '26 loo'
31349
1
D
|
K^^
26! SO' 27 loo' ' ' '
Abundancelon 152.00 (151.70 to 152.70): ENG
SOOOO^Ion 153.00 (152.70 to 153.70): ENG
20000J J\ .
1 h \ /\
10000 Jj
1
,
.
[rime-->
w
25 I SO' '26 loo'
U
l/W^
^\S^\1 ^
'26150' '27 loo' ' ' '
#6
Acei
Con
Exp<
Lab
Acq
Tgt
Ion
152
153
0
0
iAbundance
1
j
100000 -
50000 -
TIC: ENG1349.D
Time-->
Abundance ion 164.00 (163.70 to 164.70): ENG
26.60
26.70
26.80
100000^
50000^
26.70
Time-->
26.60
26i70
26180
Acenaphthylene
Concen: 0.00 ng/uL
Expected RT: 26.27 min
Lie: ENG1349.D
Acq: 25 May 99 3:51 pm
3n: 152
Exp Ratio
100
14.0
0.0
0.0
ENG1J49.D—PES1.M
Wed May 26 09:46:07
#7
Acenaphthene-dl0
Concen: 2.89 ng/uL m
RT: 26.70 min Scan# 2511
Delta R.T. 0.04 min
Lab File: ENG1349.D
Acq: 25 May 99 3 .-51 pm
Tgt Ion:164 Resp: 327138
Ion Ratio Lower Upper
164 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
HP 5989B
Page 5
-------
Abundance
100000 .
50000^
TIC: ENG1349.D
Time-->25.50 26.00
I—|—i—i—I—i
27100 27150
Abundance Ion 154.00 (153.70 to 154.70): ENG
Ion 153.00 (152.70 to 153.70): ENG
40000 J
30000^
20000 1
10000 1
IT
ime-->25!50 26.00 26150 27.00 27.50
lAbunaance
I \
100000 .
50000 .
TIC: ENG1349.D
Time-->
27180
28.00
28.20
Abundancelon 176.00 (175.70 to 176.70): ENG
100000 -
50000.
28.00
1
0 J
rime-->
27180
28:00
28l20
#8
Acenaphthene(CCC)
Concen: 0.00 ng/uL
Expected RT: 26.73 min
Lab File: ENG1349.D
Acq: 25 May 99 3:51 pm
Tgt Ion: 154
Ion Exp Ratio
154 100
153 86.4
0 0.0
0 0.0
ENG1349.D
#9
Fluorene-dlO
Concen: 3.65 ng/uL
RT: 28.00 min Scan# 2708
Delta R.T. 0.05 min
Lab File: ENG1349.D
Acq: 25 May 99 3:51 pra
Tgt Ion:176 Resp: 387055
Ion Ratio Lower Upper
176 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
OCC3951
Wed May 2t> Uy-.4b:lU 1999
HP 5989B
Page 6
-------
Abundance
100000.
50000.
TIC: ENG1349.D
0
Time - - >
28.00
28.10
Abu
elon 166.00 (165.70 to 166.70)
lion 165.00 (164.70 to 165.70}
ENG
ENG
20000 j
10000-
ime-->
28^00
28.10
Fluorene
Concen: 0.29 ng/uL m
RT: 28.07 min Scantf 2718
Delta R.T. 0.04 min
Lab File: ENG1349.D
Acq: 25 May 99 3:51 pm
Tgt Ion: 166 Resp.- 32942
Ion Ratio Lower Upper
166 100
165 116.1 40.0 119.9
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance
200000 J
TIC: ENG1349.D
rime--> 30.30
30.40
30:50
Abundance Ion 188.00 (187770 to 188.70): ENG
Ion 94.00 (93.70 to 94.70): ENG13
30.43
150000 '.
100000.
50000.
rime--> 30.30
30.40
30.50
ENG1J49.D—PES1.M
Wed May 2fe 09:4fe;13
Phenanthrene-dlO
Concen-. 3.50 ng/uL
RT: 30.43 min Scan# 3077
Delta R.T. 0.05 min
Lab File: ENG1349.D
Acq: 2 5 May 99 3:51 pm
Tgt Ion:188 Resp: 456994
Ion
188
94
0
0
Ratio
100
8.6
0.0
0.0
Lower Upper
5.8
0.0
0.0
17.2
0.0
0.0
HP 5989B
Page 7
-------
Abundance
200000 J
TIC: ENG1349.D
0
Time-->
30:40
30.50
30.60
(Abundance Ion 178 .00 (177 . 70 to 178770) : ENG
lion 176.00 (175.70 to 176.70): ENG
30.49
40000
20000 .
ime-->
30.40
30150
30.60
#12
Phenanthrene
Concen: 0.76 ng/uL
RT: 30.49 min Scan# 3086
Delta R.T. 0.05 min
Lab File: ENG1349.D
Acq: 25 May 99 3:51 pm
Tgt Ion:178 Resp: 109895
Ion Ratio Lower Upper
178 100
176 18.1 8.5 25.4
0 0.0 0.0 0.0
0 0.0 0.0 0.0
SNG
Abundance
200000
150000.
,
100000:
soooo :
o :
rime-->
Abundance
150000 '.
100000 :
50000 .
0 J
Time-->
TIC: ENG1349.D
/ \
\
V'-x^x\_
30 50 30 60 30.70
Ion 188.00 (187.70 to 188.70): EN<3
Ion 94.00 (93.70 to 94.70): ENG13
A\
\ 30.57
\^_^ v
30.50 30 60 30.70
iJ4y.D PBSI.M Wed May '2k 09:4b:lS 19^5
#13
Anthracene-dlO
Concen: 1.37 ng/uL
RT: 30.57 min Scan# 3099
Delta R.T. 0.06 min
Lab File: ENG1349.D
Acq: 25 May 99 3:51 pm
Tgt Ion:188 Resp: 149007
Ion Ratio Lower Upper
188 100
94 16.0 6.6 19.6
0 0.0 0.0 0.0
0 0.0 0.0 0.0
00039S3
HP 5989B
Page 8
-------
Abundance
200000 J
TIC: ENG1349.D
Time-->29.50 30.00 30.50 31.00 31.50
Abundance Ion 178.00 (177.70 to 178 .70) : ENG
Ion 176.00 (175.70 to 176.70): ENG
40000 J
20000
fTime--> 29.50 30!00 30.50 31.00 31.50
#14
Anthracene
Concen: 0.00 ng/uL
Expected RT: 30.57 min
Lab File: ENG1349.D
Acq: 25 May 99 3:51 pm
Tgt Ion: 178
Ion Exp Ratio
178 100
176 16.2
0 0.0
0 0.0
[Abundance
\
150000.
100000
50000
Time-->
TIC: ENG1349.D
33.40 33.50 33.60 33.70
Abundancelon 212.00 (211.70 to 2127TO) :
150000Jlon 106.00 (105.70 to 106.70):
ENG
ENG
33.58
100000.
50000 .
Time-->
ENG1J49.D—PES1.M
Wed May 2b 09:4fe:19
#15
Fluoranthene-dlO
Concen: 4.06 ng/uL
RT: 33.58 min Scan# 3619
Delta R.T. 0.07 min
Lab File: ENG1349.D
Acq: 2 5 May 99 3:51 pm
Tgt Ion.-212 Resp.-
Ion Ratio Lower
100
212
106
0
0
10.4
0.0
0.0
8.0
0.0
0.0
468244
Upper
23.8
0.0
0.0
HP 5989B
Page 9
-------
Abundance
1000000.
500000 _|
TIC: ENG1349.D
Time--> 32.50 33.00 33.50 34.00 34.50
Abundance Ion 202.00 (201.70 to 202.70): ENG
•lion 101.00 (100.70 to 101.70): ENG
80000j
60000
40000
20000J
ime--> 32^50 33.00 33.50 34.00 34!50
[Abundance
1000000 .
500000
TIC: ENG1349.D
Time - - >
Abundancelon 212.00 (211.70 to 212.70): ENG
150000JIon 106.00 (105.70 to 106.70): ENG
0
34.00
34.20
34.40
#16
Fluoranthene(CCC)
Concen: 0.00 ng/uL
Expected RT: 33.56 min
Lab File: ENG1349.D
Acg: 25 May 99 3:51 pm
Tgt Ion: 202
Ion Exp Ratio
202 100
101 13.7
0 0.0
0 0.0
34.26
100000 .
50000 '.
Time--> 34.00
34i20
34140
Pyrene-dlO
Concen: 3.98 ng/uL
RT: 34.26 min Scan# 3721
Delta R.T. 0.07 min
Lab File: ENG1349.D
Acq-. 25 May 99 3:51 pm
Tgt Ion:212 Resp:
Ion Ratio Lower
100
212
106
0
0
10.4
0.0
0.0
8.6
0.0
0.0
502829
Upper
25.6
0.0
0.0
Wed May 2fe U9:4fe:22 1999
HP 5989B
Page 10
-------
Abundance
1000000 .
500000 -
TIC: ENG1349.D
Time-->33:00 33.50 34.00 34.50 35.00
Abundance Ion 202.00 (201.70 to 202.70): ENG
^lon 101.00 (100.70 to 101.70): ENG
80000:
60000
•4
40000 .j
20000
frime-->33.00 33^50 34.00 34.50 35.00
(Abundance
1000000 _
500000 -
TIC: ENG1349.D
Time-->
34.40
34i60
34.80
#18
Pyrene
Concen: 0.00 ng/uL
Expected RT: 34.24 min
Lab File: ENG1349.D
Acq: 25 May 99 3:51 pm
Tgt Ion: 202
Ion Exp Ratio
202 100
101 15.5
0 0.0
0 0.0
#19
p-Terphenyl-d!4
Concen: 32.53 ng/uL
RT: 34.58 min Scan# 3769
Delta R.T. 0.08 min
Lab File: ENG1349.D
Acq.- 25 May 99 3:51 pm
Tgt Ion:244 Resp: 3348424
Ion Ratio Lower Upper
244 100
122
0
Abundance Ion 244.00 (243.70 to 244.70):
Ion 122.00 (121.70 to 122.70):
1000000 .
500000 .
Jfe
0 .
ENG
ENG
34.58
34.40
34160
34.80
ENG1J49.D PES1.I
Wed May 26 09:4fe:2b
0
15.3
0.0
0.0
6.7
0.0
0.0
19.9
0.0
0.0
HP 5989B
Page 11
-------
Abundance
100000.
50000.
TIC: ENG1349.D
0
Time--> 38170 38.80
T—\—I—i—r
38.90
T 1 1 1—I I—I |—~l
39.00 39.10
Abundance Ion 240.00 (239.70 to 240.70):
100000-
38.00 38.50 39.00 39.50
(Abundance Ion 228.00 (227.70 to 228.70) : ENG
Ion 114.00 (113.70 to 114.70): ENG
20000 J
15000 J
10000:
5000:
Time-->
38.00 38.50 39.00 39150
ENG1J49.D
Wed May 26 U9:4fc:2B
#21
Benzo(a)anthracene
Concen: 0.00 ng/uL
Expected RT: 38.89 min
Lab File: ENG1349.D
Acq: 25 May 99 3:51 pm
Tgt Ion: 228
Ion Exp Ratio
228 100
114. 12.3
0 0.0
0 0.0
^3257
HP 5989B
Page 12
-------
Abundance
100000 .
50000 -
TIC: ENG1349.D
Time-->
i—i—i—r—i—i—i—r
39.00 39.10
39.20
Abundanc
100000
elon 240700 (239.70 to 240.70): ENG
lion 120.00 (119.70 to 120.70): ENG
39.06
50000 .
fri
ime-->
38.90 39.00 39.10 39.20
#22
Chrysene-dl2
Concen: 4.53 ng/uL
RT: 39.06 min Scant 4445
Delta R.T. 0.12 min
Lab File: ENG1349.D
Acq: 25 May 99 3:51 pm
Tgt Ion: 240 Resp:
Ion Ratio Lower
240 100
10.0
0.0
0.0
120
0
0
6.4
0.0
0.0
391084
Upper
19.0
0.0
0.0
[Abundance
100000 -
50000 -
TIC: ENG1349TD
Time--> 38.00 38.50 39.00 39.50 40.00
lAbundancelon 228.00 (227.70 to 228.70): ENG
Ion 114.00 (113.70 to 114.70): ENG
20000 4
15000 :
10000:
5000
o:J
rime--> 38.00 38.50 39.00 39.50 40.00
ENG1349.D—PES1.M
Wed May 2fe U9:4fe;J2
Chrysene(CCC)
Concen: 0.00 ng/uL
Expected RT: 39.06 min
Lab File: ENG1349.D
Acq: 25 May 99 3:51 pm
Tgt Ion: 228
Ion Exp Ratio
228 100
114 10.8
0 0.0
0 0.0
HP 5989B
0003958
Page 13
-------
Abundance
100000 .
TIC: ENG1349.D
50000 J
Time-->
45l~80
46.00
46.20
Abundance Ion 264.00 (263.70 to 264.70):
jlon 132.00 (131.70 to 132.70):
60000
40000 j
20000
ENG
45180
46.00
46.20
(Abundance
! 100000
TIC: ENG1349.D
50000 J
rime- ->
45.00 45.50 46.00 46.50
#24
Benzo
45.00 45.50 46.00 46.50
#25
Benzo(b)fluoranthene
Concen: 0.00 ng/uL
Expected RT: 45.92 min
Lab File: ENG1349.D
Acq: 25 May 99 3:51 pm
Tgt Ion: 252
Ion Exp Ratio
252 100
126 14.5
0 0.0
0 0.0
.DPES1.M
Wea May 26
HP 5989B
Page 14
-------
Abundance
100000.
TIC: ENG1349.D
50000 M
Time-->
46.00
46.20
46.40
lAbundancelon 264.00 (263.70 to 264.70):
Ion 132.00 (131.70 to 132.70):
60000 n 46.18
40000 J
20000 J
ENG
ENG
Time - - >
46.00
46.20
46.40
#26
Benzo(k)fluoranthene-d!2
Concen: 4.33 ng/uL m
RT: 46.18 min Scan# 5539
Delta R.T. 0.25 min
Lab File: ENG1349.D
Acq: 25 May 99 3:51 pm
Tgt Ion:264 Resp: 409795
Ion Ratio Lower Upper
264 100
132 37.6 8.5 25.3#
0 0.0 0.0 0.0
0 0.0 0.0 0.0
[Abundance
100000 -
TIC: ENG1349.D
Time-->45.00 45.50 46.00 46.50 47iOO
50000 „
Abundance Ion 252.00 (251.70 to 252770): ENG
•lion 126.00 (125.70 to 126.70): ENG
20000 -
10000 .
0 ._
Time-->45.00 45.50 46.00 46.50 47.00
ENGT3T9TD—PEbil.M
Wed May 2fe 09;4&:3U
#27
Benzo(k)fluoranthene
Concen: 0.00 ng/uL
Expected RT: 46.09 min
Lab File.- ENG1349.D
Acq: 25 May 99 3:51 pm
Tgt Ion: 252
Ion Exp Ratio
252 100
126 15.4
0 0.0
0 0.0
HP 5989B
Page 15
-------
Abundance
40000 .
20000 .
0
Time-->48
TIC: ENG1349.D
.40 48.60 48.80
Abundancelon 264.00 (263. vu to 264. vu; : JSJNU
Jlon 132.00 (131.70 to 132.70): ENG
15000
10000
5000
0 j
fTime-->48.40
48.60
48.80
#28
Benzo(a)pyrene-d!2
Concen: 0.77 ng/uL tn
RT: 48.72 min Scan# 5927
Delta R.T. 0.34 min
Lab File: ENG1349.D
Acq: 25 May 99 3:51 pm
Tgt Ion:264 Resp: 61762
Ion Ratio Lower Upper
264 100
132 114.8 8.7 25.9#
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance TIC: ENG1349.D
1 Ar
40000 .
20000 _
.
.
.
0
Time - - >
Abundance
20000 .
15000-
10000.
5000.
0.
Time - - >
V"1"^ V*A*VTv
48100 ' 49loO '
Ion 252.00 (251.70 to 252.70): ENG
Ion 126.00 (125.70 to 126.70): ENG
-j-AAv /^Vw/V
^^<*^^~^^^ \_
__ ^
48100 ' ' 49 100 ' ' ' '
#29
Ben
Con
Exp
Lab
Acq
Tgt
Ion
252
126
0
0
Benzo(a)pyrene(CCC)
Concen: 0.00 ng/uL
Expected RT: 48.59 min
-le: ENG1349.D
Acq: 25 May 99 3:51 pm
m: 252
Exp Ratio
100
15.0
0.0
0.0
HP 5989B
Page 16
-------
Abundance
60000.
40000J
20000 J
TIC: ENG1349.D
Time-->
0
T 1 i 1 r
61.50
-i 1 r
62.00
^bundancelon 266.00 (287.70 to 288.70)
61.82
20000 J
10000 .
hrime-->
61.50
62.00
(Abundance
60000 .
40000 .
20000 .
TIC: ENG1349.D
Time--> 60.00
61.00
62100
63.00
Abundancelon 2T5.T55 (275.75 to 276.75): ENG
jlon 138.00 (137.70 to 138.70): ENG
15000J
10000 .
5000 J
Time-->60.00
—i i 1 1 1 1 < 1
61.00 62.00
63.00
#30
Indeno(l,2, 3-cd)pyrene-dl2
Concen: 2.45 ng/uL m
RT: 61.82 min Scan# 8164
Delta R.T. 0.55 min
Lab File: ENG1349.D
Acq: 25 May 99 3:51 pm
Tgt Ion:288 Resp:
Ion Ratio Lower
288 100
0.0
0.0
0.0
0
0
0
0.0
0.0
0.0
243350
Upper
0.0
0.0
0.0
ENGl.349 .D PES1 .M
Indeno(1,2,3-cd)pyrene
Concen: 0.00 ng/uL
Expected RT: 61.62 min
Lab File: ENG1349.D
Acq: 25 May 99 3:51 pm
Tgt Ion: 276.05
Ion Exp Ratio
276 100
138 30.0
0 0.0
0 0.0
0003962
May 2b 09:46:45
HP 5989B
Page 17
-------
Abundance
60000 -
40000
20000 .
TIC: ENG1349.D
[rime - - >
62oo
Sundance ion 292.00 (291.70 to 292.70): ENG
61.77
15000 .
10000 J
5000 :
0
Time-->
eiso
62 oo
Abundance
60000 J
-
40000 .
20000
TIC: ENG1349.D
Time-->
n
eioo
62o
Abundance Ion 278.00 (277.70 to 278 .70) :
Ion 139.00 (138.70 to 139.70):
15000J
10000.
sooo:
o :
ENG
ENG
Time-->
61.00
"•—1—'
62.00
#32
Dibenz(a,h)anthracene-d!4
Concen: 2.80 ng/uL m
RT: 61.77 min Scan# 8154
Delta R.T. 0.56 min
Lab File: ENG1349.D
Acq: 25 May 99 3:51 pm
Tgt Ion:292 Resp: 177818
Ion Ratio Lower Upper
292 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
wed May 2b 09:46:48 1999
#33
Dibenz(a,h)anthracene
Concen: 0.00 ng/uL
Expected RT: 61.63 min
Lab File: ENG1349.D
Acq: 25 May 99 3:51 pm
Tgt Ion: 278
Ion Exp Ratio
278 100
139 21.0
0 0.0
0 0.0
HP 5989B
Page 18
-------
Abundance
20000.
10000 -
TIC: ENG1349.D
fTime-->
65.00
65.50
66.00
Abundancelon 288.00 (287.70 to 288.70): ENG
65.43
ime- ->
65.00
65.50
66.00
(Abundance
30000 .
20000 J
10000 J
TIC: ENGl349.£)
: I 1 1 1 1 1 1 1 1 i 1 i r
Time--> 64.00 65.00 66.00
Abundancelon 276.00 (275.70 to 276.70): ENG
-lion 138.00 (137.70 to 138.70): ENG
100004
'*HfW*^^
5000.
0.
—I—r
Time--> 64.00
-I 1 r
65.00
ENGlJ4y.D
66.00
Wed May 2fe 09:4fe:b2
#34
Benzo(g,h,i)perylene-dl2
Concen: 2.16 ng/uL m
RT: 65.43 min Scan# 8921
Delta R.T. 0.66 min
Lab File: ENG1349.D
Acq: 25 May 99 3:51 pm
Tgt Ion:288 Resp: 181694
Ion Ratio Lower Upper
288 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
#35
Benzo(g,h,i)perylene
Concen: 0.00 ng/uL
Expected RT: 65.19 min
Lab File: ENG1349.D
Acq: 25 May 99 3:51 pm
Tgt Ion: 276
Ion Exp Ratio
276 100
138 26.6
0 0.0
0 0.0
HP 5989B
Page 19
-------
ENG1348.XLS
Quantitation Report Summary
Data File
Date Analyzed:
Sample ID
Method ID
Operator
Instrument
Compounds
Naphthalene(CCC)
Acenaphthylerte
Acenaphthene(CCC)
Fluorene
Phenanthrene
Anthracene
Fluoranthene(CCC)
Pyrene
Benzo(a)anthracene
Chrysene(CCC)
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Benzo(a)pyrene(CCC)
indeno(1,2,3-cd)pyrene
Dibenz(a,h)anthracene
Benzo(g,h,i)perylene
ENG1348.D
05/25/99|
PES OUTLET 1 REPLICATE ANALYSIS 4/2/99
PES
JEMcCartney
HP 5989B
Area
1430537
55473
0
50663
100790
0
0
0
0
0
0
0
0
0
0
0
* PQL - practical quantitation limit
Surrogate Recoveries
Compound
Naphthalene-d8
Acenaphthylene-d8
Acenaphthene-d10
Fluorene-d10
Phenanthrene-d10
Anthracene-d10
Fluoranthene-d10
Pyrene-d10
Benzo(a)anthracene-d12
Chrysene-d12
Benzo(b)fluoranthene-d12
Benzo(k)fluoranthene-d12
Benzo(a)pyrene-d12
Indeno(1,2,3-cd)pyrene-d12
Dibenz(a,h)anthracene-d14
Benzo(g, h, i)perylene-d1 2
Recovery Standard
Compound
2-Methlynaphthalene-d10
p-Terphenyl-d14
Compiled by:
Cone.
(ng/uL)
6.899
0.341
0.000
0.444
0.695
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Cone. (ng/nL)
3.09
1.92
3.84
3.64
3.47
0.86
3.55
3.40
3.10
4.14
4.23
3.93
0.30
2.46
2.67
2.12
Concentration (ng/uL)
27.51
29.39
/
PQL*
(ng/ML)
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
/
^. '-) / *
Cone.
(ng/sample)
6899
341
0
444
695
0
0
0
0
0
0
0
0
0
0
0
% Recovery
77.24
48.10
96.12
90.95
86.64
21.41
88.86
84.92
77.46
103.46
105.82
98.21
7.41
61.57
66.77
52.98
% Recovery
68.78
73.48
y
Cone, (ng/sample)
w/ Surr. correction
8931
709
0
488
802
0
0
0
0
0
0
0
0
0
0
0
AJfe'fV E ffc-~'
-------
Quantitation Report
Data File :
Acg On ;
Sample :
Misc :
Quant Time:
Method
Title
Last Update
Response via
C:\HPCHEM\1\DATA\9919\ENG1348.D
25 May 99 2:36 pm
PES OUTLET 1 REPLICATE ANALYSIS 4/2/99
May 27 10:44 1999
: C:\HPCHEM\1\METHODS\PES1.M
Vial: 3
Operator: JEMcCartney
Inst : HP 5989B
Multiplr: 1.00
Mon May 24 15:51:53 1999
Multiple Level Calibration
Internal Standards
R.T. Qlon Response Cone Units Dev(Min)
1)
2, 2-Dif luorobiphenyl
24
.57
190
536958
System Monitoring Compounds
2)
4)
5)
7)
9)
11)
13)
15)
17)
19)
20)
22)
24)
26)
28)
30)
32)
34)
Naphthalene-d8
2-Methlynaphthalene-dlO
Acenaphthy 1 ene - d8
Acenapht hene - dl 0
Fluorene-dlO
Phenanthrene - dl 0
Anthracene -dlO
Fluoranthene - dl 0
Pyrene-dlO
p-Terphenyl-dl4
Benzo (a) anthracene -dl 2
Chrysene-dl2
Benzo (b) f Iuoranthene-dl2
Benzo (k) f Iuoranthene-dl2
Benzo (a) pyrene-d!2
Indenod, 2, 3-cd)pyrene-dl2
Dibenz (a, h) anthracene -d!4
Benzo (g, h, i) perylene-d!2
22
23
26
26
27
30
30
33
34
34
38
39
45
46
48
61
61
65
.22
.94
.27
.69
.98
.42
.56
.56
.24
.56
.86
.02
.90
.10
.59
.64
.56
.20
136
152
160
164
176
188
188
212
212
244
240
240
264
264
264
288
292
288
609761
2816278
312066
437579
388518
454755
93838
412719
431406
3043504
273929
359621
356068
373595
23928
246207
170696
179038
Target Compounds
3)
6)
8)
10)
12)
14)
16)
18)
21)
23)
25)
27)
29)
31)
33)
35)
Naphthalene (CCC)
Acenaphthylene
Acenaphthene (CCC)
Fluorene
Phenanthrene
Anthracene
Fluoranthene (CCC)
Pyrene
Benzo (a) anthracene
Chrysene (CCC)
Benzo (b) f luoranthene
Benzo (k) f luoranthene
Benzo (a) pyrene (CCC)
Indeno ( 1 , 2 , 3 - cd) pyrene
Dibenz (a,h) anthracene
Benzo (g,h, i)perylene
22
26
0
28
30
0
0
0
0
0
0
0
0
0
0
0
.27
.31
.00
.06
.48
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
128
152
154
166
178
178
202
202
228
228
252
252
252
276
278
276
1430537
55473
50663
100790
5.00 ng/uL
0
.04
%Recovery
3.09 ng/uL
27.51 ng/uL
1.92 ng/uL
3 . 84 ng/uL
3 . 64 ng/uL
3 .47 ng/uL
0.86 ng/uL
3.55 ng/uL
3.40 ng/uL
29.39 ng/uL
3 . 10 ng/uL
77
68
48
96
90
86
21
88
84
73
77
4.14 ng/uL 103
4.23 ng/uL 105
3.93 ng/uL
0.30 ng/uL
2.46 ng/uL
2.67 ng/uL
2 . 12 ng/uL
98
7
61
66
52
.24%
.78%
.10%
.12%
.95%
.64%
.41%
.86%
.92%
.48%
.46%
.46%
.82%
.21%
.41%
.57%
.77%
.98%
Qvalue
6.90 ng/uL
0.34 ng/uL
Not Detected
0 . 44 ng/uL
0.69 ng/uL
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
98
91
78
97
000.1005
(#) = qualifier out of range (m) = manual integration
ENG1348.D PES1.M Thu May 27 10:45:33 1999 HP 5989B
Page 1
-------
Quantitation Report
Data File : C:\HPCHEM\1\DATA\9919\ENG1348.D
Acq On : 25 May 99 2:36 pm
Sample : PES OUTLET 1 REPLICATE ANALYSIS 4/2/99
Misc
Quant Time: May 27 10:44 1999
Vial: 3
Operator: JEMcCartney
Inst : HP 5989B
Multiplr: 1.00
Method
Title
Last Update
Response via
C:\HPCHEM\1\METHODS\PES1.M
Mon May 24 15:51:53 1999
Multiple Level Calibration
Abundance
j
j
1200000 j
1
-j
^100000 :
oooooo :
900000 :
i
800000 J
700000 j
-
eooooo:
500000:
400000 :
300000:
200000 .
100000:
0 '
|r'me-->
EJJG1348.D
I
i
juJT
JJdPfi*'
PES]
y
20
L.M
2
||
(
!od
4
5
S
I
3
1
5l
6
I)
ULT
Thi
9
F
1
tki
u
s
0
-l
30
M
LI
a
1
i
.
&2
1
•s 1
IE
&
00
r 27
T
(
•/
>!
1C: ENG1348.D
!
s
s
yK 5
3Bs
1 28S 34s
UA^ 1
Wk*wjvL^A^Ji___^ r • A
^^ ^_A
4o!od ' ' soloo ' 6o!od
OOGJLOC
10:45:40 1999 HP 5989B Page
'7
> 2
-------
Abundance
400000.
200000 .
TIC: ENG1348.D
0
Time-->
22.00 22.10 22.20 22.30 22.40
[AbundanceIon 136.00 (135.70 to 136.70): ENG
68.00 (67.70 to 68.70): ENG13
200000
150000 :
100000 4
50000
2.22
Time--> 22.00 22.10 22.20 22.3022.40
lAbunaance
400000 J
200000
TIC: ENG1348.D
Time - - >
22.10 22.20 22.30 22.40
400000 .
200000 .
128.00 (127.70 to 128.70): ENG
Ion 127.00 (126.70 to 127.70): ENG
22.27
Time-->
22.10 22.20 22.30 22140
#2
Naphthalene-d8
Concen: 3.09 ng/uL
RT: 22.22 min Scant 1565
Delta R.T. 0.05 min
Lab File: ENG1348.D
Acq: 25 May 99 2:36 pm
Tgt Ion:136 Resp: 609761
Ion Ratio
136 100
68 23.7
0 0.0
0 0.0
Lower Upper
3.9
0.0
0.0
11. 5#
0.0
0.0
ENG1J48.D—PES1.M
Thu May 2V 10:4B:44
#3
Naphthalene(CCC)
Conceii: 6.90 ng/uL
RT: 22.27 min Scan# 1573
Delta R.T. 0.04 min
Lab File: ENG1348.D
Acq: 25 May 99 2:36 pm
Tgt Ion-. 128 Resp: 1430537
Ion Ratio Lower Upper
128 100
127 12.6 0.0 62.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
HP 5989B
• rs ~ *••>
It- : -i *.'K
- Vc - -. U V v.)
Page 3
-------
Abundance
600000:
400000:
200000:
TIC: 6NG1348.D
0
Time-->
23.80
24.00
24.20
Abundancelon 152.00 (151.70 to 152.70): ENG
800000
600000 J
23.94
400000
200000 J
Abundance
100000 .
TIC: ENG1348.D
50000 _
Time--> 26.00
Abundancelon 160.00 (159.70 to 16U.70): ENG
26.20
26.40
#4
2-Methlynaphthalene-dlO
Concen: 27.51 ng/uL
RT: 23.94 min Scanfl 1923
Delta R.T. 0.04 tain
Lab File: ENG1348.D
Acq: 25 May 99 2:36 pm
Tgt Ion:152 Resp: 2816278
Ion Ratio
152 100
0 0.0
0 0.0
0 0.0
Lower Upper
0.0
0.0
0.0
0.0
0.0
0.0
! Q 1 ^ V
fTime- ->
23
!so '
24
loo '
24
120 '
100000 .
26.27
ENG1J48.D—PES1.M
#5
Acenaphthy1ene-d8
Concen: 1.92 ng/uL
RT: 26.27 min Scantf 2448
Delta R.T. 0.04 min
Lab File: ENG1348.D
Acq: 25 May 99 2:36 pm
Tgt Ion:160 Resp: 312066
Ion
160
0
0
0
Ratio
100
0.0
0.0
0.0
Lower Upper
0.0
0.0
0.0
0.0
0.0
0.0
Thu May 2V lU:4b:4V 1999
HP 5989B
Page 4
-------
jAbundance
100000.
TIC: ENG1348.D
50000.
26.20
26.30
26.40
Sundance Ion 152.00 (151.70 to 152.70)
30000Hion 153.00 (152.70 to 153.70)
1 26.31
20000
10000 J
ENG
ENG
ime-->
26.20
26.30
26140
(Abundance
TIC: ENG134S.D
Time-->
Abundancelon 164.00 (163.70 to 164.70): ENG
26.60
26.70
26.80
100000-
50000 .
26.69
rime-->
26.60
26.70
ENG1J48.D
26.80
Thu May 2V 10:45:5U
#6
Acenaphthylene
Concen: 0.34 ng/uL
RT: 26..31 min Scan# 2453
Delta R.T. 0.04 min
Lab File: ENG1348.D
Acq: 2 !3 May 99 2 :3 6 pm
Tgt Ion:152 Resp: 55473
Ion Ratio
152 100
153 10.3
0 0.0
0 0.0
Lower Upper
7.1
0.0
0.0
21.1
0.0
0.0
#7
Acenaphthene-dl0
Concen: 3.84 ng/uL
RT: 26.69 min Scan# 2511
Delta R.T. 0.04 min
Lab File: ENG1348.D
Acq: 25 May 99 2:36 pm
Tgt Ion:164 Resp: 437579
Ion Ratio Lower Upper
164 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
HP 5989B
OCCJ.010
Page 5
-------
Abundance
100000
50000 .
TIC: ENG1348.D
Time-->25.50 26.00 26.50 27.00 27.50
[AbundanceIon 154.00 (153.70 to 154.70) : ENG
! Jlon 153.00 (152.70 to 153.70): ENG
20000 J
l
]
10000 J
#8
Acenaphthene(CCC)
Concen: 0.00 ng/uL
Expected RT: 26.73 min
Lab File: ENG1348.D
Acq: 25 May 99 2:36 pm
Tgt Ion: 154
Ion Exp Ratio
154 100
153 86.4
0 0.0
0 0.0
Time-
n H
->25
!s'o
26 loo' Vels'o' '27! do' 27! so'
Abundance
100000 .
TIC: ENG1348.D
Time--> 27.80 27.90 28.00 28.10 28.20
Abundancelon 176.00 (175.70 to 176.70): ENG
100000.
50000.
0.
27.98
Time-->
27180' '27190'
E1JG1J48.D
I—i—I—i—i—i—r-1—i—i—i—i—i—i—
28100 28.10 28:20
Thu May '2'l !U:4b;faJ 1999
Fluorene-dlO
Concen: 3.64 ng/uL
RT: 27.98 min Scan# 2706
Delta R.T. 0.03 min
Lab File: ENG1348.D
Acq: 2 5 May 99 2:3 6 pm
Tgt Ion:176 Resp: 388518
Ion Ratio Lower Upper
176 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
OOP *<*•;•
V ^. Vf ..'=., 5
HP 5989B
Page 6
-------
Abundance
100000.
50000.
TIC: ENG1348.D
Time-->27.90
28.00
28.10
28.20
Abundance Ion 166.00 (165.70 to 166.7 OT: ENG
Ion 165.00 (164.70 to 165.70): ENG
20000 .
10000
06
iTime-->27.90
28.00
28.10
28.20
Abundance
200000:
isoooo:
100000:
TIC: ENG1348.D
50000 J
Time-->
30.30
30.40
30.50
#10
Fluorene
Concen: 0.44 ng/uL
RT: 28.06 min Scan# 2718
Delta R.T. 0.04 min
Lab File: ENG1348.D
Acq: 25 May 99 2:36 pm
Tgt Ion:166 Resp: 50663
Ion Ratio
166 100
165 99.2
0 0.0
0 0.0
Lower Upper
40.0
0.0
0.0
119.9
0.0
0.0
Abundance Ion 188.00 (187.70 to 188.70): ENG
Ion 94.00 (93.70 to 94.70): ENG13
.50000J 30'42
100000:
50000 .
Time-->
30.30 30.40 30:50
ENG1J48.D—PES1.M
Thu May W lU:4b;bb
#11
Phenanthrene-dl0
Concen: 3.47 ng/uL
RT: 20.42 min Scan# 3076
Delta R.T. 0.04 min
Lab File: ENG1348.D
Acq: 25 May 99 2:36 pm
Tgt "on:188 Resp: 454755
Ion
188
94
0
0
Ratio
100
10.7
0.0
0.0
Lower Upper
5.8
0.0
0.0
17.2
0 .0
0.0
000.1912
HP 5989B Page 7
-------
Abundance
200000 :
TIC: ENG1348.D
Time--> 30.30 30.40 30.50 30.60
Abundance I on 178.00 (177.70 to 178.70T:BNG
lion 176.00 (175.70 to 176.70): ENG
400004 30-48
30000 J
20000 J
10000:
#12
Phenanthrene
Concen: 0.69 ng/uL
RT: 30.48 min Scan# 3085
Delta R.T. 0.04 min
Lab File: ENG1348.D
Acq: 25 May 99 2:36 pra
Tgt Ion:178 Resp: 100790
Ion Ratio Lower Upper
178 100
176 15.7 8.5 25.4
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 J
frime--> 30:30 30.40 30.50 30.60
(Abundance
200000 A
150000
100000:
50000:
TIC: ENG1348.D
Time-->
30.50
30.60
Abundancelon 168.00 (187.70 to 188.70): ENG
Ion 94.00 (93.70 to 94.70): ENG13
150000 J
100000:
50000.
Time-->
BNG1J4B.D—PES1.M
Thu May '2'/ 10:4b:b9
#13
Anthracene-dl0
Concen: 0.86 ng/uL m
RT: 30.56 min Scant 3097
Delta R.T. 0.04 min
Lab File: ENG1348.D
Acq: 25 May 99 2:36 pm
Tgt Ion-.188 Resp: 93838
Ion Ratio Lower Upper
188 100
94 84.5 6.6 19.6$
0 0.0 0.0 0.0
0 0.0 0.0 0.0
OCi
HP 5989B
Page 8
-------
TIC: ENG1348.D
Abundance
200000J
150000 :
100000:
soooo:
rrime--> 29.50 30.00 30.50 31.00 31.50
(Abundance I on 178.00 (177770 to 178.70): ENG
Ion 176.00 (175.70 to 176.70): ENG
40000 :
30000
20000 J|
10000
ime--> 29.50 30.00 30:50 31.00 31.50
Sundance
150000 J
100000 J
50000:
(
Time-->
TIC: ENG1348.D
33.40
33.60
33.80
Abundancelon 212.00 (211.70 to 212.70): ENG
Ion 106.00 (105.70 to 106.70): ENG
33.56
100000 .
50000.
#14
Anthracene
Concert: 0.00 ng/uL
Expected RT: 30.57 man
Lab File: ENG1348.D
Acq: 25 May 99 2:36 pm
Tgt Ion: 178
Ion Exp Ratio
178 100
176 16.2
0 0.0
0 0.0
Time-->
33140
33160
33180
ENG1348 .D PiSSl .M
#15
Fluoranthene-dlO
Concen: 3.55 ng/uL
RT: 23.56 min Scan# 3617
Delta R.T. 0.05 min
Lab File: ENG1348.D
Acq: 25 May 99 2:36 pm
Tgt Ion:212 Resp: 412719
Ion Ratio Lower Upper
212 100
106 10.0 8.0 23.8
0 0.0 0.0 0.0
0 0.0 0.0 0.0
May 2V 10:4b:02
HP 5989B
Page 9
-------
i&bundance
1000000.
TIC: ENG1348.D
500000 J
0
»Time--> 32.50 33.00 33.50 34.00 34.50
Abundance ion 202 .00~T201."70' to ~2CT2~. 70) : ENG
15000 1Ion 101-°° (100.70 to 101.70): ENG
10000
5000
?ime--> 32:50 33.00 33.50 34.00 34.50
#16
Fluoranthene(CCC)
Concen: 0.00 ng/uL
Expected RT: 33.56 min
Lab File: ENG1348.D
Acq: 25 May 99 2:36 pm
Tgt Ion: 202
Ion Exp Ratio
202 100
101 13.7
0 0.0
0 0.0
[Abundance
1000000 _i
TIC: ENG1348.D
500000
#17
Pyrene-dlO
Concen: 3.40 ng/uL
RT: 34.24 min Scan# 3719
Delta R.T. 0.05 min
Lab File: ENG1348.D
Acq: 25 May 99 2:36 pm
0
Time--> 34.00 34.20 34.40
Abundancelon 212.00 (211.70 to 212.70):
Ion 106.00
(105.70 to 106.70)
34.24
ENG
100000 .
50000-
Time-->
34.00
1 1~ 1 1
34.40
ENG1J48 .D
.M
Thu May 2V ll):4fe:Ub 1999
Tgt Ion:212 Resp.-
Ion Ratio Lower
100
212
106
0
0
13.2
0.0
0.0
8.6
0.0
0.0
431406
Upper
25.6
0.0
0.0
OCC.13I3
HP 5989B Page 10
-------
Abundance
1000000 .
TIC: EMG1348.D
500000 .
i — i — i — I
Time-->33 iOO 33.50
i — i — i
34.00 34.50
35.00
Abundance I on 202.00 (201.70 to 202.70): ENG
15000JIon 101-00 (100.70 to 101.70): ENG
10000
5000
-->33:00 33150 34lOO 34.50 35.00
#18
Pyrene
Concen: 0.00 ng/uL
Expected RT: 34.24 min
Lab File: ENG1348.D
Acq: 25 May 99 2:36 pm
Tgt Ion: 202
Ion Exp Ratio
202 100
101 • 15.5
0 0.0
0 0.0
Abundance
1000000 .
TIC: ENG1348.D
500000 .
Time--> 34.20
34.40
34.60
34.80
Abundance Ion 244TOO (243T70 to 244.70): ENG
Ion 122.00 (121.70 to 122.70): ENG
34.56
500000.
#19
p-Terphenyl-d!4
Concen: 29.39 ng/uL
RT: 34.56 min Scantf 3767
Delta R.T. 0.06 min
Lab Flule: ENG1348.D
Acq: 25 May 99 2:36 pm
Tgt Ion:244 Resp: 3043504
Ion Ratio Lower Upper
244 100
122 12.0 6.7 19.9
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Time--> 34.20 34.40 34.60 34.80
ENGT3T8TD PEbl .M
Tnu May 27 10:46:UB
HP 5989B
Page 11
-------
(Abundance
100000.
TIC: ENG1348.D
50000H
0
Time-->
38.70 38!80 38.90 39.00
Abundance ton 240.00 (239.70 to 240.70): ENG
lion 120.00 (119.70 to 120.70): ENG
80000J
60000 J
40000:
20000 J
ime-->
3870
T 1 1 1 1 1 1 ] 1 1
38.90 39100
[Abundance
100000 .
50000 .
TIC: ENG13
^/\^
j
I
Time- ->
Abundance
15000 _,
10000 1
5000 J
T. °-
Time-->
S i&Q n — tr
38
00 38
"J
ft
u
48. D
f
u__
1 i r I 1 i 1 1 T 1 1 1 1
.50 39100 39.50
ion 228.00 (227.70 to 226.70): ENG
Ion 114.00 (113.70 to 114.70): ENG
38.
GTTT — nr—
VH-W^-^
00 38
mi.
f^^r^f
n
I .
;
S
V^^xv-^^
50 39.00 39.50
#20
Benzo(a)anthracene-d!2
Concen: 3.10 ng/uL
RT: 38.86 min Scant 4415
Delta R.T. 0.09 min
Lab File: ENG1348.D
Acq: 25 May 99 2:36 pm
Tgt Ion:240 Resp: 273929
Ion Ratio Lower Upper
240 100
120 13.5 7.3 21.8
0 0.0 0.0 0.0
0 0.0 0.0 0.0
#21
Benzo(a)anthracene
Concen: 0.00 ng/uL
Expected RT: 38.89 min
Lab File: ENG1348.D
Acq: 25 May 99 2:36 pm
Tgt Ion: 228
Ion Exp Ratio
228 100
114 12.3
0 0.0
0 0.0
HP 5989B
o T
Page 12
-------
Abundance
100000 .
TIC: ENG1348.D
50000.
rime--> 38.80
39!00
39.20
Abundance Ion
lion
80000
60000
40000 :
20000 j
240700
120.00
(239.70 to
(119.70 to
39.02
240.70):
120.70):
ENG
ENG
ime--> 38.80
39.00
39.20
Abundance
100000 .
50000 _
TIC: ENG1348.D
Time--> 38.00 38.50 39!00 39.50 40:00
#22
Chrysene-d!2
Concen: 4.14 ng/uL
RT: 39.02 min Scan* 4440
Delta R.T. 0.08 min
Lab File: ENG1348.D
Acq: 25 May 99 2:36 pm
Tgt Ion:240 Resp: 359621
Ion Ratio Lower Upper
240 100
120 13.6 6.4 19.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance Ion 228 .00 (227.70 to 228.To): ENG
Ion 114.00 (113.70 to 114.70): ENG
15000:
10000 J
5000 J
0 —
Time--> 38.00 38.50 39!00 39:50 40:00
ENG1348 .D
#23
Chrysene(CCC)
Concert: 0.00 ng/uL
Expected RT: 39.06 min
Lab File: ENG1348.D
Acq: 25 May 99 2:36 pm
Tgt Ion: 228
Ion Exp Ratio
228 100
114 10.8
0 0.0
0 0.0
. M
rnu May 27 10 :4t>: ID iyyy
HP 5989B
Page 13
-------
Abundance
80000 .
60000 .
40000 .
20000 .
TIC: ENG1348.D
Time-->
45.80
46.00
Abundance Ion 264.00 (263.70 to 264.70): ENG
60000Jlon 132.00 (131.70 to 132.70): ENG
40000 n
20000 _!
[Time- ->
45.80
46.00
#24
Benzo(b)fluoranthene-d!2
Concen: 4.23 ng/uL m
RT: 45.90 min Scan# 5496
Delta R.T. 0.19 min
Lab File: ENG1348.D
Acq: 2 5 May 99 2:3 6 pm
Tgt Ion:264 Resp: 356068
Ion Ratio Lower Upper
264 100
132 33.5 8.0 23.9#
0 0.0 0.0 0.0
0 0.0 0.0 0.0
(Abundance
80000
60000
40000
20000 J
Time-->
TIC: ENG1348.D
45.00 45.50 46.00 46.50
Abundancelon 252.00 (251.70 to 252.70): ENG
20000JIon 126.00 (125.70 to 126.70): ENG
15000 J
10000:
5000:
rime-->
45.00 45.50
i—i—I—i—i—i—i—|—i—i—r
46.00 46.50
ENG 13 4 8 . D
. M
Thu May 27 10:46:18 1999
#25
Benzo(b)fluoranthene
Concen: 0.00 ng/uL
Expected RT: 45.92 min
Lab File: ENG1348.D
Acq: 25 May 99 2:36 pm
Tgt Ion: 252
Ion Exp Ratio
252 100
126 14.5
0 0.0
0 0.0
HP 5989B
Page 14
-------
Abundance
soooo:
eoooo:
40000:
20000:
TIC: ENG1348.D
7ime - - >
46.00
46.20
Sundance Ion 264.00 (263.70 to 264.70; : ENG
60000JIon 132.00 (131.70 to 132.70): ENG
46.10
40000 j
20000 J
Time - - >
46.00
46.20
#26
Benzo(k)fluoranthene-d!2
Concent 3.93 ng/uL m
RT: 46.10 rain Scan# 5527
Delta R.T. 0.17 min
Lab File: ENG1348.D
Acq: 25 May 99 2:36 pm
Tgt Ion: 264 Resp.- 373595
Ion Ratio Lower Upper
264 100
132 33.8 8.5 25.3#
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance
80000
60000:
TIC: ENG1348.D
Time-->45 .00 45.50 46.00 46.50 47.00
Abundance Ion 252.00 (251.70 to 252.70}: ENG
20000 J'Ion 126.00 (125.70 to 126.70): ENG
isooo:
10000:
5000:
o :J
rime-->45.00 45.50 46.00 46.50 47.00
ENG134B.D—PES1.M
Thu May 2V 10:46:21
#27
Benzo(k)fluoranthene
Concen: 0.00 ng/uL
Expected RT: 46.09 min
Lab File: ENG1348.D
Acq: 25 May 99 2:36 pm
Tgt Ion: 252
Ion Exp Ratio
252 100
126 15.4
0 0.0
0 0.0
HP 5989B
Page 15
-------
Abundance
30000 .
20000 J
10000 .
TIC: ENG1348.D
rime-->
48.40
48.60
48.80
[Abundance Ion 264.00 (263.70 to 264.70): ENG
Ion 132.00 (131.70 to 132.70): ENG
j
10000
5000
[Time--:
48.40
48:60
48.80
#28
Benz o(a)pyrene-dl2
Concen: 0.30 ng/uL m
RT: 48.59 rain Scant 5909
Delta R.T. 0.22 min
Lab File: ENG1348.D
Acq: 25 May 99 2:3€ pm
Tgt Ion:264 Resp: 23928
Ion Ratio Lower Upper
264 100
132 133.1 8.7 25.9#
0 0.0 0.0 0.0
0 0.0 0.0 0.0
$Wi>
2
,
.
..
:
Abundance
30000 _
20000 I
-
-
10000 :
TIC: ENG1348.D
v^^V^ /^SV/^X. y\ /"V^A
^^w^y >^v ^v^ V ,w ^^X
48 00 49.00
Abundancelon 252.00 (251.70 to 252.70): ENG
15000 _
]
10000 .
5000 J
0-
Ion 126.00 (125.70 to 126.70): ENG
V-Wvv^ f\^]\. /A/\
^^^^ ^^
_^___^^
Time--> 48.00 49.00
#29
Ben
Con
Exp
Lab
Acq
Tgt
Ion
252
126
o
0
,£NGi.mti.u FJSbi.M Tnu May 27 10:46:25 1999
Benzo(a)pyrene(CCC)
Concen: 0.00 ng/uL
Expected RT: 48.59 min
-le: ENG1348.D
Acq: 25 May 99 2:36 pm
Exp Ratio
100
15.0
0.0
0.0
HP 5989B
Page 16
-------
Abundance
40000.
20000.
T1C: ENG1348.D
Time-->
0
6i:50
62.00
Abundance Ion 288.00 (287.70 to 288.70): ENG
20000 .
10000J
61.64
ime-->
61.50
62.00
(Abundance
40000 .
20000 .
TIU: ENG1348.D
Time-->60.00
0
61.00
62100
63100
#30
Indeno(1,2,3-cd)pyrene-d!2
Concen: 2.46 ng/uL m
RT: 61.64 min Scan# 8131
Delta R.T. 0.37 min
Lab File: ENG1348.D
Acq: 25 May 99 2:36 pm
Tgt Ion:288 Resp: 246207
Ion Ratio Lower Upper
288 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance Ion 276 .T05 (275.75 to 276775): ENG
lion 138.00 (137.70 to 138.70): ENG
10000 .
5000 .
0-
«*» • 11
rime-->60.00
61.00
62100
63100
ENGl3~?F7B
#31
Indeno(1,2,3 -cd)pyrene
Concern-. 0.00 ng/uL
Expected RT: 61.62 min
Lab File: ENG1348.D
Acq: 25 May 99 2:36 pm
Tgt Ion: 276.05
Ion Exp Ratio
276 100
138 30.0
0 0.0
0 0.0
Tnu May 27 10:46:^8
HP 5989B
Page 17
-------
Abundance
40000 .
20000.
TIC: EMG1348.D
Time-->61.00
6l!50
62100
Abundance Ion 292.00 (291.70 to 292.70): ENG
61.56
15000:
^
10000 J
5000
--> 6l!oo
61.50
62.00
lADunaance
40000 _,
20000 .
TIC: ENG1348.D
Time-->
61.00
62.00
ADunaancelon 278.00 (277.70 to 278.70) : ENG
lion 139.00 (138.70 to 139.70): ENG
10000 ;'>V*^^
5000.
0-
rime-->
61.00
62.00
ENG1348.D—PE5T71
Thu May 27 10:4€>:J1 1999
#32
Dibenz (a, h) anthracene-d!4
Concen: 2.67 ng/uL m
RT: 61.56 min Scan# 8117
Delta R.T. 0.36 min
Lab File: ENG1348.D
Acq: 25 May 99 2:36 ptn
Tgt Ion:292 Resp: 170696
Ion Ratio Lower Upper
292 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
#33
Dibenz(a,h)anthracene
Concen: 0.00 ng/uL
Expected RT: 61.63 min
Lab File: ENG1348.D
Acq: 25 May 99 2:36 pm
Tgt Ion-. 278
Ion Exp Ratio
278 100
139 21.0
0 0.0
0 0.0
OGG.13.53
HP 5989B
Page 18
-------
Abundance
20000-
10000-
TIC: ENG1348.D
0
Time-->
65.00
65.50
Abundancelon 288TOD (287.70 to 288.70}
65.20
15000 .
ENG
10000 J
5000 J
E
line - - >
65.00
65.50
(Abundance
i 30000j
20000 1
TIC: ENG1348
'• 1 1 i 1 1 j 1 1 1 1 1 1 r
Time--> 64.00 65.00 66.00
Abundancelon 276.00
Ion 138.00
10000 J
8000 .
6000 .
4000.
2000.
'4*''M^^
o:
(275.70 to 276.70): EUG
(137.70 to 138.70): ENG
Time-->
64 Io6
65,00
66.00
PES1.M
Thu May '2'l 10:46:3b
#34
Benzo(g,h,i)perylene-dl2
Concen: 2.12 ng/uL m
RT: 65.20 min Scan# 8864
Delta R.T. 0.42 min
Lab File: ENG1348.D
Acq: 25 May 99 2:36 pm
Tgt Ion:288 Resp: 179038
Ion Ratio Lower Upper
288 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
#35
Benzo(g,h,i)perylene
Conceii: 0.00 ng/uL
Expected RT: 65.19 min
Lab File: ENG1348.D
Acq: 25 May 99 2:36 pm
Tgt Ion: 276
Ion Exp Ratio
276 100
138 26.6
0 0.0
0 0.0
HP 5989B
Page 19
-------
SUMMARY1.XLS
3uantitation Report Summary
Data File
Date Analyzed:
Sample ID
Method ID
Operator
Instrument
Compounds
Naphthalene(CCC)
Acenaphthylene
Acenaphthene(CCC)
Fluorene
Phenanthrene
Anthracene
Fluoranthene(CCC)
Pyrene
Benzo(a)anthracene
Chrysene(CCC)
Benzo(b)fluoranthene
8enzo(k)fluoranthene
Benzo(a)pyrene(CCC)
lndeno(1,2,3-cd)pyrene
Dibenz(a,h)anthracene
Benzo(g,h,i)perylene
ENG1327.D
05/19/99
PES OUTLET 2 4/2/99
PES
JEMcCartney
HP 5989B
Area
5346408
232812
0
0
306605
29753
0
0
0
0
0
0
0
0
0
0
* PQL - practical quantitation limit
Surrogate Recoveries
Compound
Naphthalene-d8
Acenaphthylene-d8
Acenaphthene-d10
Fluorene-d10
Phenanthrene-d10
Anthracene-d10
Fluoranthene-d10
Pyrene-d10
Benzo(a)anthracene-d12
Chrysene-d12
Benzo(b)fluoranthene-d12
Benzo(k)fluoranthene-d12
Benzo(a)pyrene-d12
lndeno(1 ,2,3-cd)pyrene-d12
Dibenz(a,h)anthracene-d14
Benzo(g,h,i)perylene-d12
Recovery Standard
Compound
2-Methlynaphthalene-d10
p-Terphenyl-d14
Compiled by:
Reviewed by:
Reviewed by:
Cone.
(ng/uL)
8.056
0.347
0.000
0.000
0.377
0.038
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Cone. (ng/uL)
4.42
2.78
3.74
3.97
2.76
1.37
2.67
2.60
2.43
2.84
0.00
0.00
1.26
1.95
2.14
1.83
Concentration (ng/uL)
33.00
23.86
,/
PQL*
(ng/uL)
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
s ,
j7Stof^r^ / /O / >
Cone.
(ng/sample)
8056
347
0
0
377
38
0
0
0
0
0
0
0
0
0
0
Cone, (ng/sample)
w/ Surr. correction
8056**
500
0
0
547
110
0
0
0
0
0
0
0
0
0
0
** No surrogate correction made
% Recovery
110.50
69.46
93.41
99.20
68.94
34.36
66.74
64.90
60.76
70.98
0.00
0.00
31.54
48.77
53.56
45.63
% Recovery
82.51
59.65
7
T
-------
Quantitation Report
Data File
Acq On
Sample
Misc
Quant Time: May 25
C:\HPCHEM\1\DATA\9919\ENG1327.D
19 May 99 6:24 ptn
PES OUTLET 2 4/2/99
Vial: 7
Operator: JEMcCartney
Inst : HP 5989B
Multiplr: 1.00
Method
Title
Last Update
Response via
9:44 1999
C:\HPCHEM\1\METHODS\PES.M
Mon May 24 16:23:27 1999
Multiple Level Calibration
Internal Standards
1)
2 , 2 -Dif luorobiphenyl
R
24
.T. Qlon
.62
190
Response
1872038
System Monitoring Compounds
2)
4)
5)
7)
9)
11)
13)
15)
17)
19)
20)
22)
24)
26)
28)
30)
32)
34)
Naphthalene-d8
2-Methlynaphthalene-dlO
Acenaphthylene-d8
Acenaphthene - dl 0
Fluorene-dlO
Phenanthrene - dlO
Anthracene -dlO
Fluor anthene - dl 0
Pyrene-dlO
p-Terphenyl-d!4
Benzo (a) anthracene -d!2
Chrysene-dl2
Benzo (b) f luoranthene -d!2
Benzo (k) fluoranthene-d!2
Benzo (a) pyrene-d!2
Indeno(l, 2, 3-cd)pyrene-dl2
Dibenz (a, h) anthracene-d!4
Benzo (g,h, i)perylene-d!2
22
23
26
26
28
30
30.
33
34
34
38
39
0
0
48
61
61
65
.26
.99
.33
.75
.04
.47
.60
.60
.27
.60
.94
.08
.00
.00
.80
.99
.93
.59
136
152
160
164
176
188
188
212
212
244
240
240
264
264
264
288
292
288
2522549
9989893
1671613
1490627
1717724
1849873
801181
1773217
1893042
13158625
1137008
1609300
0
0
476784
988508
637292
732274
Target Compounds
3)
6)
8)
10)
12)
14)
16)
18)
21)
23)
25)
27)
29)
31)
33)
35)
Naphthalene (CCC)
Acenaphthylene
Acenaphthene (CCC)
Fluorene
Phenanthrene
Anthracene
Fluoranthene (CCC)
Pyrene
Benzo (a) anthracene
Chrysene (CCC)
Benzo (b) f luoranthene
Benzo (k) f luoranthene
Benzo (a) pyrene (CCC)
Indeno ( 1 , 2 , 3 - cd) pyrene
Dibenz (a, h) anthracene
Benzo (g,h, i)perylene
22
26
0
0
30
30
0
0
0
0
0
0
0
0
0
0
.32
.36
.00
.00
.53
.65
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
128
152
154
166
178
178
202
202
228
228
252
252
252
276
278
276
5346408
232812
306605
29753
Cone Units Dev(Min)
5.00 ng/uL
0
.04
%Recovery
4.42 ng/uL 110
33.00 ng/uL
2.78 ng/uL
3.74 ng/uL
3.97 ng/uL
2.76 ng/uL
1.37 ng/uL
2 . 67 ng/uL
2 .60 ng/uL
23.86 ng/uL
2.43 ng/uL
2.84 ng/uL
0.00 ng/uL
0.00 ng/uL
1.26 ng/uL
1.95 ng/uL
2 . 14 ng/uL
1.83 ng/uL
82
69
93
99
68
34
66
64
59
60
70
0
0
31
48
53
45
.50%
.51%
.46%
.41%
.20%
.94%
.36%
.74%
.90%
.65%
.76%
.98%
.00%
.00%
.54%
.77%
.56%
.63%
Qvalue
8.06 ng/uL
0.35 ng/uL
Not Detected
Not Detected
0.38 ng/uL
0.04 ng/uL#
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not DeAs^ed,
);i
88
99
97
1
™
.(#) = qualifier out of range (m) = manual integration
ENG1327.D PES.M Thu May 27 10:51:48 1999 HP 5989B
Page 1
-------
Quantitation Report
Data File : C:\HPCHEM\1\DATA\9919\ENG1327.D
Acg On : 19 May 99 6:24 pm
Sample : PES OUTLET 2 4/2/99
Misc :
Quant Time: May 25 9:44 1999
Method
Title
Last Update
Response via
C:\HPCHEM\1\METHODS\PES.M
Mon May 24 ID:23:27 1999
Multiple Level Calibration
Vial: 7
Operator: JEMcCartney
Inst : HP 5989B
Multiplr: 1.00
iAbundance
TIC: ENG1327.1D
4000000 J
-I
3500000 .
3000000 j
2500000 J
2000000.
1500000 .
1000000.
500000 .
Us
32s
34s
-SNG1327.D PES.M
Thu May 27 10:51:55 1999
HP 5989B
Page 2
-------
Abundance
2000000-
1000000 .
TIC: ENG1327.D
lime - - >
—r—I—i—i—i—i—I—i—i—i—r—I—i—i—i—I—I—I—
22.10' 22.20 22.30 22i40
Abundance ion 136.00(135.70 to 136.70): ENG
68.00 (67.70 to 68.70): ENG13
22.20 22.30 22.40
Abundance
2000000 -
1000000 _
TIC: ENG1327.D
Time - - >
22.20
22:30
22.40
#2
Naphthalene-d8
Concen: 4.42 ng/uL
RT: 22.26 min Scan# 1571
Delta R.T. 0.03 min
Lab File: ENG1327.D
Acg: 19 May 99 6:24 pm
Tgt 1011:136 Resp: 2522549
Ion
136
68
0
0
Ratio
100
0.0
0.0
0.0
Lower Upper
10.1
0.0
0.0
30.1#
0.0
0.0
Abundance Ion 128.00 (127.70 to 128.70)
Ion 127.00 (126.70 to 127.70)
2000000 J
1500000:
1000000:
500000:
o:
ENG
ENG
22.32
Time - - >
22:20
22:30
22UO
ENGTJ2T7D
#3
Naphthalene(CCC)
Conceri: 8.06 ng/uL
RT: 22.32 min Scan# 1579
Delta R.T. 0.03 min
Lab File: ENG1327.D
Acq: 19 May 99 6:24 pm
Tgt Ion:128 Resp: 5346408
Ion Ratio
128 100
127 14.6
0 0.0
0 0.0
Lower Upper
0.0 60 .0
0.0 0.0
0.0 0.0
000.13;'
. M
Tnu May 27 10:51:58 1999
HP 5989B
Page 3
-------
Abundance
3000000 '.
2000000:
1000000:
TIC: ENG1327.D
Time--> 23!80 23190 24100 24.10
(AbundanceIon 152.00 (151.70 to 152.70)
4000000J 23.99
3000000 j
2000000
ENG
1000000 _
04-
ime--> 23.80 23.90 24.00 24!lO
Abundance
400000 J
200000 J
TIC: ENG1327.D
Time-->
26.20
26130
26.40
Abunaanceion 160.00 (159.70 to 160.70): ENG
400000 :
300000:
200000:
100000:
o:
26.33
Time-->
26.20
—I—I—I—I—I—I—1—I—
26130 26140
EWGIJ^V.D
Thu May 2V 10;b2:01 1999
#4
2-Methlynaphthalene-dlO
Concen: 33.00 ng/uL
RT: 23.99 min Scan# 1939
Delta R.T. 0.03 min
Lab File: ENG1327.D
Acg: 19 May 99 6:24 pm
Tgt Ion:152 Resp: 9989893
Ion Ratio Lower Upper
152 100
0 0.0 0.0 ' 0.0
0 0.0 0.0 0.0
.0 0.0 0.0 0.0
#5
Acenaphthylene-d8
Concen: 2.78 ng/uL
RT: 26.33 min Scan# 2456
Delta R.T. 0.04 min
Lab File: ENG1327.D
Acq: 19 May 99 6:24 pm
Tgt Ion:160 Resp: 1671613
Ion Ratio Lower Upper
160 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
OCC.lt
HP 5989B
Page 4
-------
Abundance
400000.
200000 -
TIC: ENG1327.D
Time--> 26.20
26:30
26.40
26.50
Abundance ion 152.00 (151.70 to 152,70): ENG
100000^ 153.00 (152.70 to 153.70): ENG
26.36
50000
0 .
(Time - - > 26120
26:30
26.40
26:50
(Abundance
400000.
TIC: ENG1327.D
Time-->
26.60 26:70 26:80 26:90
#6
Acenaphthylene
Concen: 0.35 ng/uL
RT: 26.36 min Scan# 2461
Delta R.T. 0.04 min
Lab File: ENG1327.D
Acq: 19 May 99 6:24 pm
Tgt 1011:152 Resp: 232812
Ion Ratio Lower Upper
152 100
153 15.2 7.6 22.6
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance Ion 164.00 (163.70 to 164.7u) : ENG
400000 :
300000;
200000:
100000;
26.75
Time-->
26.60 26.70 26180 26190
ENGT3~2~7TDPES .i
#7
Acenaphthene-dl0
Concen: 3.74 ng/uL m
RT: 26.75 min Scan# 2519
Delta R.T. 0.04 min
Lab File: ENG1327.D
Acq: 19 May 99 6:24 pm
Tgt Ion:164 Resp: 1490627
Ion Ratio
164 100
0 0.0
0 0.0
0 0.0
Lower Upper
0.0
0.0
0.0
0.0
0.0
0.0
inu way z/ 10:52:04
HP 5989B
Page 5
-------
Abundance
400000 .
200000
"TIC: ENG1327.D
Time-->
26.00 26.50 27.00 27.50
Abundanceion 154.00 (153.70 to 154.70): ENG
jlon 153.00 (152.70 to 153.70): ENG
100000
50000
7ime - - >
26:00 26.50 27.00 27.50
(Abundance
400000 4
200000 _
!
TIC: ENG1327.D
Time-->27.80 27.90 28:00 28.10 28.20
Abundance Ion 176.00 (175.70 to 176.70) : ENG
400000 :
300000:
200000:
100000:
o:
28.04
. "ii i i I i—i—r—i—i—i—i—i—i—i—i—r—i—i—i—r—i—i—r
ime-->27.80 27.90 28.00 28.10 28.20
ENG13T7TD—PES.M
Thu May 2V !U:b2:OV 1999
#8
Acenaphthene(CCC)
Concen: 0.00 ng/uL
Expected RT: 26.79 min
Lab File: ENG1327.D
Acq: 19 May 99 6:24 pm
Tgt Ion: 154
Ion Exp Ratio
154 100
153 86.8
0 0.0
0 0.0
#9
Fluorene-dlO
Concen.- 3.97 ng/uL
RT: 28.04 min Scan# 2715
Delta R.T. 0.04 min
Lab File: ENG1327.D
Acq: 19 May 99 6:24 pm
Tgt Ion:176 Resp: 1717724
Ion Ratio Lower Upper
100
0.0
0.0
176
0
0
0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
OCG
HP 5989B
Page €
-------
Abundance
400000.
200000-
T1C: ENG1327.D
Time-->
—i—i—i—i—i—;—i—r
27.00 27.50
28.00
Vsls'o' 29! do'
Abundance Ion 166.00 (165.70 to 166.70;.- ENG
Jlon 165.00 (164.70 to 165.70): ENG
100000 _
1
50000j
1
b?ime--> 27.00 27.50 28!00 28.50 29.00
Abundance
800000:
600000:
400000:
200000:
Time-->30*.30
TIC: ENG1327.D
Abundance Ion 188.00 (187.70 to 188.70; : ENG
Ion .94.00 (93.70 to 94.70): ENG13
400000J 30.47
30:40
30.50
30.60
#10
Fluorene
Concert: 0.00 ng/uL
Expected RT: 28.08 min
Lab File: ENG1327.D
Acq: 19 May 99 6:24 pm
Tgt Ion: 166
Ion Exp Ratio
166 100
165 76.2
0 0.0
0 0.0
rime-->30.30
30.40
30150
30.60
ENG1327.DPBS.M
#11
Phenanthrene-dl0
Concen: 2.76 ng/uL
RT: 30.47 min Scan# 3084
Delta R.T. 0.04 min
Lab File: ENG1327.D
Acq: 19 May 99 6:24 pm
Tgt Ion:188 Resp: 1849873
Ion Ratio
188 100
94 34.6
0 0.0
0 0.0
Lower Upper
15.1
0.0
0.0
45.1
0.0
0.0
THU May 27 10:52:10 1999
HP 5989B
Page 7
-------
Abundance
800000:
TIC: ENG1327.D
Time--> 30.40
30.50
30.60
lAbundance Ion 1Y8.0U(177.70 to 178.70)
i ilon 176.00 (175.70 to 176.70): ENG
i 30.53
100000 .,
50000
#12
Phenanthrene
Concen: 0.38 ng/uL
RT: 30.53 min Scan# 3093
Delta R.T. 0.04 min
Lab File: ENG1327.D
Acq: 19 May 99 6:24 pm
Tgt Ion:178 Resp: 306605
Ion Ratio Lower Upper
178 100
176 18.7 10.1 30.1
0 0.0 0.0 0.0
0 0.0 0.0 0.0
JTime--> 30.40
30.50
30.60
Abundance
800000 :
600000:
400000
200000
Time-->
TIC: ENG1327.D
30.50
30160
30.70
Abundance Ion 188.00
•lion 94.00
400000:
300000:
200000:
100000:
o:
(187.70 to 188.70):
(93.70 to 94.70): ENG13
30.50
30.60
30.70
ENG1327.DPEb.M
#13
Anthracene-dl0
Concen: 1.37 ng/uL
RT: 30.60 min Scan# 3104
Delta R.T. 0.03 min
Lab File: ENG1327.D
Acq: 19 May 99 6:24 pm
Tgt Ion:188 Resp: 801181
Ion Ratio Lower Upper
188 100
94 44.5 15.1 45.1
0 0.0 0.0 0.0
0 0.0 0.0 0.0
no^^"^
UtUJ.J^
inu way
iu:t)2:ij
HP 5989B
Page 8
-------
Abundance
400000 .
200000 .
TIC: ENG1327.D
Time--> 30.55 30:60 30.65 30.70 30.75
Abundancelon 17S.OO (177.70 to 178.70): ENG
Ion 176.00 (175.70 to 176.70): ENG
100000
50000 .,
30.65
0 J
Time-->
30 1 5
5 30
:eo
30
les'
'30!
70
30
175
#14
Anthracene
Concen: 0.04 ng/uL
RT: 30.65 min Scan# 3112
Delta R.T. 0.03 min
Lab File: ENG1327.D
Acq: 19 May 99 6:24 pm
Tgt Ion:178 Resp: 29753
Ion Ratio Lower Upper
178 100
176 67.6 10.1 30.1#
0 0.0 0.0 0.0
0 0.0 0.0 0.0
(Abundance
600000 '.
400000 '.
200000 -
TIC: ENG1327.D
-FK
Time-->
Abundancelon 212.00 (211.70 to 212.70): ENG
400000JIon I'OS.OO (105.70 to 106.70): ENG
0
33.40
33.60
33.80
300000 J
200000:
100000:
rime - - >
33.60
33.40
33!60
33180
ENG1327.DPES. M
#15
Fluoremthene-dl0
Concen: 2.67 ng/uL
RT: 33.60 min Scan# 3623
Delta R.T. 0.02 min
Lab File: ENG1327.D
Acq: :.9 May 99 6:24 pm
Tgt Ion:212 Resp: 1773217
Ion Ratio Lower Upper
212 100
106 35.3 15.1 45.1
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Tnu May 27 10:52:16
HP 5989B
Page 9
-------
TIC: ENG1327.D
[Abundance
3000000:
2000000J
1000000 :
fTime--> 32150 33100 33!50 34^00 34^50
Abundance Ion 202.00 (201.70 to 202770):
j ;jlon 101.00 (100.70 to 101.70):
400000
300000
200000 1
100000 J
0 1
ENG
ENG
fTime--> 32:50 33.00
34 00 34 So
#16
Fluoranthene(CCC)
Concen: 0.00 ng/uL
Expected RT: 33.62 min
Lab File: ENG1327.D
Acq: 19 May 99 6:24 pro
Tgt Ion: 202
Ion Exp Ratio
202 100
101 27.0
0 0.0
0 0.0
iundance
3000000
J
2000000 _1
j
1
1
1000000 J
TIC: ENG1327.D
Y
Time-->
34.00
34.20
34.40
Abundancelon 212.00 (211.70 to 2l2.70): ENG
lion 106.00 (105.70 to 106.70): ENG
400000 .
200000 J
rime-->
34:00
34:20
ENG1J27.D
. M
Thu May 2V !U:b2:iy 1999
Pyrene-dlO
Concen: 2.60 ng/uL
RT: 34.27 min Scan# 3724
Delta R.T. 0.02 min
Lab File: ENG1327.D
Acq: 19 May 99 6:24 pm
Tgt Ion:2l2 Resp: 1893042
Ion
212
106
0
0
Ratio
100
24.8
0.0
0.0
Lower Upper
17.1
0.0
0.0
51.1
0.0
0.0
flPfi'n^r
*-*-v>.-'-o^-D
HP 5989B
Page 10
-------
Abundance
3000000J
2000000 '.
1000000
Time-->
TIC: ENG1327.D
33.50 34.00 34.50 35.00
Abundancelon 202.00 (201.70 to^02.70T: ENG
lion 101.00 (100.70 to 101.70): ENG
400000 "
300000:
200000
100000 J
ime-->
3350 34.00 34!50 35.00
#18
Pyrene
Concen: 0.00 ng/uL
Expected RT: 34.30 tnin
Lab File: ENG1327.D
Acq: 19 May 99 6:24 pm
Tgt Ion: 202
Ion Exp Ratio
202 100
101 32.0
0 0.0
0 0.0
rime-->
34.40
34!60
34.80
[Abundancelon 244.00 (243 .70 to 244.70) :
Ion 122.00 (121.70 to 122.70):
34.60
2000000.
1000000,
0.
ENG
ENG
rime-->
34140
—i 1 1 r
34] 60
—i 1 1 1 1 r
34.80
ENGT
:DPtlS.M
Thu May "2't !U:b2:23 1999
#19
p-Terphenyl-d!4
Conceri: 23.86 ng/uL
RT: 34.60 min Scan# 3774
Delta R.T. 0.04 min
Lab File: ENG1327.D
Acq: 19 May 99 6:24 pm
Tgt Ion:244 Resp:13158625
Ion Ratio Lower Upper
244 LOO
122
0
0
27.2
0.0
0.0
13.6
0.0
0.0
40.6
0.0
0.0
OCi
HP 5989B
Page 11
-------
Abundance
400000 .
200000 .
TIC: EMG132V.D
rime-->
38.80 38.90 39:00 39.10
Abundance ion 240.00 (239.70 to 240.70):
]Ion 120.00 (119.70 to 120.70):
ENG
ENG
300000 4
200000:
100000
ime- ->
38.94
#20
Benzo(a)anthracene-dl2
Concen: 2.43 ng/uL
RT: 38.94 min Scan# 4427
Delta R.T. 0.06 min
Lab File: ENG1327.D
Acq: 19 May 99 6:24 pm
Tgt Ion:240 Resp: 1137008
Ion Ratio Lower Upper
240 100
120 52.7 15.1 45.1#
0 0.0 0.0 0.0
0 0.0 0.0 0.0
38.80 38.90 39!00 39.10
TIC: ENG1327.D
Time-->
Abundance Ion 228.00 (227.70 to 228.70) : ENG
Ion 114.00 (113.70 to 114.70): ENG
100000 -I
38.00 38.50 39.00 39.50
0
Time-->
38.00 38.50 39.00 39.50
ENGTT2T7D—PEb'.M
Thu May 2V 10:b2:2E> 1999
#21
Benzo(a)anthracene
Concen: 0.00 ng/uL
Expected RT: 38.98 min
Lab File: ENG1327.D
Acq: 19 May 99 6:24 pm
Tgt Ion: 228
Ion Exp Ratio
228 100
114 25.0
0 0.0
0 0.0
HP 5989B
Page 12
-------
Abundance
400000.
200000.
TIC: ENG1327.D
fTime--> 38.80
39!00
39.20
Abundancelon 240.00 (239.70 to 240.70):
Ion 120.00 (119.70 to 120.70): ENG
300000J
200000 .
100000 J
Time--> 38.80
39.00
39.20
#22
Chrysene-dl2
Concen: 2.84 ng/uL
RT: 39.08 min Scan# 4449
Delta R.T. 0.05 min
Lab File: ENG1327.D
Acq: 19 May 99 6:24 pm
Tgt Ion:240 Resp: 1609300
Ion Ratio Lower Upper
240 100
45.1#
0.0
120
0
0
0.0
0.0
0.0
15.1
0.0
0.0
0.0
Abundance
400000
200000 J
TIC: ENG1327.D
Tirae--> 38.50 39. DO' 39.50 40.00
Abundancelon 228.00 (227770 to 228.70) : ENG
Ion 114.00 (113.70 to 114.70): ENG
100000 J
50000 _,
0 .
rime-->
38.50 39.00 39.50 40.00
ENG1327.DPEb.M
#23
Chrysene(CCC)
Concen: 0.00 ng/uL
Expected RT: 39.16 min
Lab File: ENG1327.D
Acq: 19 May 99 6:24 pm
Tgt Ion: 228
Ion Exp Ratio
228 100
114 25.0
0 0.0
0 0.0
Tnu May 27
HP 5989B
Page 13
-------
Abundance
400000:
300000:
200000:
100000j
"TIC: t!NGl327.D
•^
fTime-->
45loo '45!so Yeio'o Veis'o'
(263 .70 to 264.70)
Abundance ion 264.00
F ZUUUU01Ion 132_00 d3i.70
150000 J
"BUG"
132.70): ENG
100000J
50000:
o
ime-->
45lOO 45.50 46.00 46.50
Abundance
400000
300000
200000 :
100000:
TIC: ENGl327.t>
Time--> 45.00 45.50 46.00 46.50 47100
Abundance Ion 252.00 (251.70 to 252.70): ENG
Jlon 126.00 (125.70 to 126.70): ENG
150000 :
1
100000:
50000 j
Time--> 45.00 45.50 46.00 46.50 47.00
#24
Benzo(b)fluoranthene-dl2
Concen: 0.00 ng/uL
Expected RT: 45.87 min
Lab File: ENG1327.D
Acq: 19 May 99 6:24 pm
Tgt Ion: 264
Ion Exp Ratio
264 100
132 30.0
0 0.0
0 0.0
ENGTJ2T7D PES .M
#25
Benzo(b)fluoranthene
Concen: 0.00 ng/uL
Expected RT: 46.07 min
Lab File: ENG1327.D
Acq: 19 May 99 6:24 pm
Tgt Ion: 252
Ion Exp Ratio
252 100
126 25.0
0 0.0
0 0.0
Tnu May 27
19F9
HP 5989B
•'£',359
Page 14
-------
Abundance
400000:
300000:
J
200000 .
100000
I °
Time--> 45 1 00
TIC: ENG1327.D
4600 4650 4700
Abundance Ion 264.00 (263.70 to 2S4.70) : ENG
lion 132.00 (131.70 to 132.70): ENG
1
150000 J
100000:
50000 J
#26
Benzo(k)fluoranthene-dl2
Concen: 0.00 ng/uL
Expected RT: 46.07 min
Lab File: ENG1327.D
Acq: 19 May 99 6:24 pm
Tgt Ion: 264
Ion Exp Ratio
264 100
132 30.0
0 0.0
0 0.0
0 J_
Time--> 45:00 45.50 46.00 46.50 47.00
Abundance TIC: ENG1327.D
j A.
400000 : fJ \
] 1 \
soooooi-— ^-_^___y \
-,
200000 :
J
100000 J
-
1
0 1
Time--> 45.50 46.00 46.50 47.00
Abundanceton 252.00 (251.70 to 252.70): ENG
Jlon 126.00 (125.70 to 126.70): ENG
150000 : S^~\
100000 :
soooo :
o :
T~~I i \ i \ i r— i i i i i i i , i i i i i i i i i
Time--> 45.50 46.00 46.50 47.00
#27
Benzo (k)
Concen:
Expected
Lab File
Acq: 19
Tgt I on :
Ion
252
126
o
0
f luoranthene
0.00 ng/uL
RT: 46.23 min
: ENG1327.D
May 99 6:24 pm
252
Exp Ratio
100
25.0
0 . 0
0.0
oee.i.o.
Page 15
-------
Abundance
200000 '.
100000
TIC: ENG1327.D
0
Time-->
AbundanceIon264.00 (263.70 to 264.70): ENG
lion 132.00 (131.70 to 132.70): ENG
100000
50000 J
48.80
t
0 j
ime - - >
#28
Benzo(a)pyrene-d!2
Concen: 1.26 ng/uL m
RT: 48.80 min Scan# 5942
Delta R.T. 0.26 min
Lab File: ENG1327.D
Acq: 19 May 99 6:24 pm
Tgt Ion:264 Resp: 476784
Ion Ratio Lower Upper
264 100
132 258.0 15.1 45.1#
0 0.0 0.0 0.0
0 0.0 0.0 0.0
(Abundance TIC: ENG1327.D
TlXT^I
"k~"'""'~v~x-^^ __f-sJ*~^ V ^^~~~~\
\ "~ "
200000H
1
1
100000 I,
•
•
'
n 1
Time--> 48^00 49 00 5olo6
Abundancelon 252.00 (251.70 to 252.70): ENG
150000 :
100000 J
50000.
o:
Time-->
Ion 126.00 (125.70 to 126.70): ENG
^^^ /—,
i i i ] i i i i ] 1 1 1 1 1 r
48.00 49.00 50.00
#29
Ben
±J\^-H
Con
Exp
Lab
Acq
Tgt
Ion
252
126
o
0
ENGJ.J^/.JJ Phiy.M Tnu May 2'/ 10:b2:jy 1995"
Benz o(a)pyrene(CCC)
Concen: 0.00 ng/uL
Expected RT: 48.74 min
Lie: ENG1327.D
Acq: 19 May 99 6:24 pm
311: 252
Exp Ratio
100
25.0
0.0
0.0
HP 5989B
000.3.941
Page 16
-------
Abundance
200000 .
100000.
TIC: ENG1327.D
Time-->
61.50
62.00
62.50
Abundance I on 288.00 (287.70 to 288.70): ENG
60000^
61.99
40000 J
20000
frime- ->
61.50
62o
6250
[Abundance
200000 J
100000
TIC: ENG1327.D
Time-->
61.00
62.00
63.00
Abundance Ion 276.05
Ion 138.00
100000j
50000 .
0 .
(275.75 to 276.75): ENG
(137.70 to 138.70): ENG
#30
Indenod, 2, 3-cd)pyrene-dl2
Concen: 1.95 ng/uL m
RT: 61.99 min Scan# 8197
Delta R.T. 0.50 min
Lab File: ENG1327.D
Acq: 19 May 99 6:24 pm
Tgt Ion:288 Resp: 988508
Ion Ratio
288 100
0 0.0
0 0.0
0 0.0
Lower Upper
0.0
0.0
0.0
0.0
0.0
0.0
rime-->
61.00
62:00
63.00
ENGTT27TD PES .M
Indeno(1,2,3 -cd)pyrene
Concen: 0.00 ng/uL
Expected RT: 61.83 min
Lab File: ENG1327.D
Acq: 19 May 99 6:24 pm
Tgt Ion: 276.05
Ion Exp Ratio
276 100
138 64.0
0 0.0
0 0.0
000.1013
THU May 27 10:52:42 1999
HP 5989B
Page 17
-------
Abundance
200000.
100000J
TIC: ENG1327.D
Time-->
61.50
62.00
62.50
Abundance Ion292 .00 (291.70 to 292.70): ENG
-i
40000
30000 _
20000:
10000
61.93
#32
Dibenz(a,h)anthracene-d!4
Concen: 2 .14 ng/uL tn
RT: 61.93 min Scan# 8187
Delta R.T. 0.49 min
Lab File: ENG1327.D
Acq: 19 May 99 6:24 pm
Tgt Ion:292 Resp: 637292
Ion Ratio Lower Upper
292 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 -
frime-->
61.50
62.00
62.50
Abundance
200000
TIC: ENG1327.D
#33
Dibenz(a,h)anthracene
Concen: 0.00 ng/uL
Expected RT: 61.85 min
Lab File: ENG1327.D
Acq: 19 May 99 6:24 pm
i
100000 Jj
]
1
I
n 1
Time--> 61 loo 62
Abundancelon 278.00 (277.70
isoooo:
100000 J
50000.
.
0'
Ion 139.00 (138.70
WWvv
^^^Wjv^
L
Time--> 61.00 62
ia/.D PEfa.M xnu May 1
1 ' ! 1 1 1
00 63.00
to 278.70) : ENG
to 139.70) : ENG
/A\
f \.
^-^AAV^ X-
00 63 lod
Tgt Ion: 278
Ion Exp Ratio
278 100
139 25.0
o on
w w • w
0 0.0
> !U:b2:4b 1999 HP 5989B
Page 18
-------
Abundance TIC: EtfGl327.D
-
80000 :
60000.
.
40000 .
20000 :
_
.
o :
-A.
/ \
/ \
/ \
^^S^^~~^ ^~^~*-^-^-v-s_
frime--> esloo ' ' eslso ' ' eeloo
r undancelon 288.00 (287.70 to 288.70): ENG
i
•1 65 59
40000^ /\
1 / \
J / \
20000 J / \
J / V
] _y V__
oj
Time--> 6sloO 65150 ' 66.00
Abundance TIC: EMG1327.D
150000 J
-
100000 J
•
50000 -
"
o :
V
x\
f \
S*~~\AS\. r "i.
K^^ ^V-v^~-— V_ ^_^_^_^
i ' • ' ' i > i ~~i i — i — i — i — i — i —
Time-->64.00 65.00 66.00
Abundancelon 276.00 (275.70 to 276.70): EMG
60000 .
40000 .
20000 .
0.
Ion 138.00 (137.70 to 138.70): ENG
-/*^A
vV Vi
w^ ^^^^^^^
^^^^^^^
Time-->64.00 65^00 66lo6 ' ' '
m/.D PBb.M Tnu May 2'/ 10:b2:49 199'9"
#34
Benzo (g, h, i)perylene-d!2
Concen: 1.83 ng/uL m
RT: 6f5.59 min Scan# 8962
Delta R.T. 0.53 min
Lab File: ENG1327.D
Acg: 19 May 99 6:24 pm
Tgt Ion: 288 Resp: 732274
Ion Ratio Lower Upper
288 100
0 0.0 0.0 0.0
0 oo n n n n
V w.w \J t \J V.W
0 0.0 0.0 0.0
#35
Benzc (g, h, i) perylene
Concen: 0.00 ng/uL
Expected RT: 65.44 min
Lab File: ENG1327.D
Acg: 19 May 99 6:24 pm
Tgt Ion: 276
Ion Exp Ratio
276 100
138 25.0
o n n
*J \J . w
0 0.0
OCf 7/>
VL t*.,.^
HP 5989B Pacre :
-------
SUMMARY1.XLS
Quantitation Report Summary
Data File
Date Analyzed:
Sample ID
Method ID
Operator
Instrument
Compounds
Naphthalene(CCC)
Acenaphthylene
Acenaphthene(CCC)
Fluorene
Phenanthrene
Anthracene
Fluoranthene(CCC)
Pyrene
Benzo(a)anthracene
Chrysene(CCC)
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Benzo(a)pyrene(CCC)
lndeno(1,2,3-cd)pyrene
Dibenz(a,h)anthracene
Benzo(g,h,i)perylene
ENG1328.D
05/19/99]
PES OUTLET 3 4/2/99
PES
JEMcCartney
HP 5989B
Area
2644835
106427
0
0
202506
0
0
0
0
0
0
0
0
0
0
0
* PQL - practical quantitation limit
Surrogate Recoveries
Compound
Naphthalene-d8
Acenaphthylene-d8
Acenaphthene-d10
Fluorene-d10
Phenanthrene-d10
Anthracene-d10
Fiuoranthene-d10
Pyrene-d10
Benzo(a)anthracene-d12
Chrysene-d12
Benzo(b)fluoranthene-d12
Benzo(k)fluoranthene-d12
Benzo(a)pyrene-d12
Indeno(1,2,3-cd)pyrene-d12
Dibenz(a,h)anthracene-d14
Benzo(g,h,i)perylene-d12
Recovery Standard
Compound
2-Methlynaphthalene-d10
p-Terphenyl-d14
Compiled by:
Reviewed by:
Cone.
(ng/uL)
8.069
0.321
0.000
0.000
0.504
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Cone. (ng/uL)
4.69
2.51
3.46
3.98
3.54
2.00
4.36
4.28
4.50
4.60
5.02
4.27
1.88
2.85
3.24
2.82
Concentration (ng/uL)
^
38.00
42.76
/
PQL*
(ng/uL)
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
^/ /4ftfjL#>6T ^ f/?*f
s*
Cone.
(ng/sample)
8069
321
0
0
504
0
0
0
0
0
0
0
0
0
0
0
Cone, (ng/sample)
w/ Surr. correction
8069**
512
0
0
570
0
0
0
0
0
0
0
0
0
0
0
** No surrogate correction made
% Recovery
117.20
62.76
86.47
99.50
88.44
49.96
108.92
107.09
112.51
115.08
125.38
106.84
47.12
71.37
80.91
70.41
% Recovery
95.00
106.91
1
-------
Quantitation Report
Data File
Acq On
Sample
Misc :
Quant Time: May 25
C:\HPCHEM\1\DATA\9919\ENG1328.D
19 May 99 7:40 pm
PES OUTLET 3 4/2/99
Vial: 8
Operator: JEMcCartney
Inst . : HP 5989B
Multiplr: 1.00
Method
Title
Last Update
Response via
9:26 1999
C:\HPCHEM\1\METHODS\PES.M
Mon May 24 16:23:27 1999
Multiple Level Calibration
Internal Standards
1)
2 , 2 -Dif luorobiphenyl
R
24
.T. Qlon
.62
190
Response
924577
System Monitoring Compounds
2)
4)
5)
7)
9)
11)
13)
15)
17)
19)
20)
22)
24)
26)
28)
30)
32)
34)
Naphthalene -d8
2-Methlynaphthalene-dlO
Acenaphthylene-d8
Acenaphthene - dl 0
Fluorene-dlO
Phenant hr ene - dl 0
Anthracene -dlO
Fluorant hene - dl 0
Pyrene-dlO
p-Terphenyl-d!4
Benzo (a) anthracene-d!2
Chrysene-dl2
Benzo (b) f luoranthene -d!2
Benzo (k) f Iuoranthene-dl2
Benzo (a) pyrene-d!2
Indenod, 2, 3-cd)pyrene-dl2
Dibenz (a,h) anthracene-d!4
Benzo (g,h, i)perylene-d!2
22
23
26
26
28
30
30
33
34
34
38
39
46
46
48
61
61
65
.26
.99
.32
.74
.04
.47
.61
.61
.30
.62
.96
.12
.05
.25
.77
.96
.88
.61
136
152
160
164
176
188
188
212
212
244
240
240
264
264
264
288
292
288
1321361
5681038
746008
681538
850930
1172069
575365
1429278
1542668
11647522
1039857
1288611
1033937
1199652
351751
714365
475478
558032
Target Compounds
3)
6)
8)
10)
12)
14)
16)
18)
21)
23)
25)
27)
29)
31)
33)
35)
Naphthalene (CCC)
Acenaphthylene
Acenaphthene (CCC)
Fluorene
Phenanthrene
Anthracene
Fluor anthene (CCC)
Pyrene
Benzo (a) anthracene
Chrysene(CCC)
Benzo (b) f luoranthene
Benzo (k) f luoranthene
Benzo (a) pyrene (CCC)
Indeno ( 1 , 2 , 3 - cd) pyrene
Dibenz (a, h) anthracene
Benzo (g,h, i)perylene
22
26
0
0
30
0
0
0
0
0
0
0
0
0
0
0
.32
.35
.00
.00
.53
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
128
152
154
166
178
178
202
202
228
228
252
252
252
276
278
276
2644835
106427
202506
Cone Units Dev(Min)
5.00 ng/uL
0 .03
%Recovery
4.69 ng/uL #
38.00 ng/uL
2.51 ng/uL
3 .46 ng/uL m
3.98 ng/uL .
3 . 54 ng/uL
2.00 ng/uL m
4.36 ng/uL
4.28 ng/uL
42.76 ng/uL
4.50 ng/uL
4.60 ng/uL
5 .02 ng/uL m
4.27 ng/uL m
1.88 ng/uL m
2.85 ng/uL
3 .24 ng/uL m
2 . 82 ng/uL m
Qvalue
8.07 ng/uL
0.32 ng/uL#
Not Detected
Not Detected
0.50 ng/uL
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
OPPifl
V?C- v^Vi^
89
64
87
: > .';
(#) = qualifier out of range (m) = manual integration
ENG1328.D PES.M Tue May 25 09:27:34 1999 HP 5989B
Paae 1
-------
Quantitation Report
Data File : C:\HPCHEM\1\DATA\9919\ENG1328.D
Acq On : 19 May 99 7:40 pm
Sample : PES OUTLET 3 4/2/99
Misc :
Quant Time: May 25 9:26 1999
Method
Title
Last Update
Response via
C:\HPCHEM\1\METHODS\PES .M
Mon May 24 16:23:27 1999
Multiple Level Calibration
Vial: 8
Operator: JEMcCartney
Inst : HP 5989B
Multiplr: 1.00
Abundance
TIC: ENG1328.D
5500000J
1
5000000J
4500000 J
4000000
3500000J
3000000J
2500000 J
2000000:
1500000:
1000000:
500000:
rTime - - >
4s
1JIS
lls
13s
15£
32s
34s
20.00
30.00
40.00
50.00
60.00
ENG1328.D PES.M
Tue May 25 09:27:42 1999
000.101?
HP 5989B Page 2
-------
i\bundance
1000000.
500000 .
TIC: ENG1328.D
Time-->
22.10 22.20 22:30 22.40
Abundance Ion 136.00 (135.70 to 136.70): ENG
1000000-lon 68.00 (67.70 to 68.70): ENG13
500000 _.
fTime-->
22.10 22:20 22:30
(Abundance
! 1000000 .
500000 .
TIC: ENG1328.D
Titne-->
22:20
22:30
22.40
Abundance Ion 128.00 (127.70 to 128.70)
Ion 127.00 (126.70 to 127.70)
1000000 J
500000-
0 .
ENG
ENG
#2
Naphthalene -d8
Concen: 4.69 ng/uL
RT: 22.26 min Scantf 1571
Delta R.T. 0.03 min
Lab File: ENG1328.D
Acq: 1<> May 99 7:40 pm
Tgt Ion: 136 Resp: 1321361
Ion
136
68
0
0
Rcitio
100
0.0
0.0
0.0
Lower Upper
10.1
0.0
0.0
30.1#
0.0
0.0
22.32
Time - - >
22:20
22:30
ENGTJZTTTB PES .
#3
Naphthalene(CCC)
Concen: 8.07 ng/uL
RT: 22.32 min Scantf 1579
Delta R.T. 0.03 min
Lab File: ENG1328.D
Acq: 19 May 99 7:40 pm
Tgt Ion:128 Resp: 2644835
Ion Ratio Lower Upper
128 100
127 14.2 0.0 60.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
TUB May 25 09:27:45 1999
HP 5989B
Page 3
-------
Abundance
2000000 J
1500000 :
1000000:
500000:
TIC: ENG1J28.D
0
rime - - >
23.80
Abundance Ion 152.00
2000000 J
1000000 -
j
1
24.00 24.20
;i5l.70 to 152.70) : ENG
23.99
iTime-->
23.80
24.00
24120
[Abundance
200000_
100000.
TIC: ENG1328.D
rime-->
Abundancelon 160.00 (159.70 to 160.70)
26.20
26.30
26140
ENG
200000.
100000.
0.
26.32
rime-->
26.20 26.30
26.40
#4
2-Methlynaphthalene-dlO
Concen: 38.00 ng/uL
RT: 23.99 min Scan# 1938
Delta R.T. 0.03 min
Lab File: ENG1328.D
Acq: 19 May 99 7:40 ptn
Tgt Ion:152 Resp: 5681038
Ion Ratio Lower Upper
100
152
0
0
0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
ENGTJZBTD
j . M
TUB May 25 09:27:48 1999
#5
Acenaphthylene-d8
Concen: 2.51 ng/uL
RT: 26.32 min Scan# 2454
Delta R.T. 0.03 min
Lab File: ENG1328.D
Acq: 19 May 99 7:40 pm
Tgt Ion:160 Resp: 746008
Ion Ratio Lower Upper
160 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
HP 5989B
000.1819
Page 4
-------
Abundance
200000.
100000 .
TIC: ENG1328.D
Time-->
26.20
26.30
26.40
26.50
Abundance Ion 152.00 (151.70 to 152.70)
Jlon 153.00 (152.70 to 153.70)
26.35
40000J
20000
ENG
ENG
fTime-->
26.20
26.30
26140
26i50
(Abundance
200000-
100000 -
TIC: ENG1328.D
Time - -
Abundancelon 164.00 (163.70 to 164.70): ENG
26.60
26.70
26.80
#6
Acenaphthylene
Concen: 0.32 ng/uL
RT: 26.35 min Scan# 2459
Delta R.T. 0.03 min
Lab File: ENG1328.D
Acq: 19 May 99 7:40 pm
Tgt Ion:152 Resp: 106427
Ion Ratio Lower Upper
152 100
153 0.0 7.6 22.6#
0 0.0 0.0 0.0
0 0.0 0.0 0.0
200000.
100000 .
26.74
rime - - >
26.60
26.70
26.80
ENGTSTBTEPEb .M
#7
Acenaphthene-dl0
Concen: 3.46 ng/uL m
RT: 26.74 min Scan# 2516
Delta R.T. 0.03 min
Lab File: ENG1328.D
Acq: 19 May 99 7:40 pm
Tgt Ion:164 Resp: 681538
Ion
164
0
0
0
Ratio
100
0.0
0.0
0.0
Lower Upper
0.0
0.0
0.0
0.0
0.0
0.0
TUe May 25 OSTZTTSx 1999
HP 5989B
Page 5
-------
Abundance
300000 J
200000
TIC: ENG1328.D
Sundance Ion 154.00
i lion 153.00
40000 J
20000 .!
(153.70 to 154.70): ENG
(152.70 to 153.70): ENG
#8
Acenaphthene(CCC)
Concen: 0.00 ng/uL
Expected RT: 26.79 min
Lab File: ENG1328.D
Acq: 19 May 99 7:40 pm
Tgt Ion: 154
Ion Exp Ratio
154 100
153 86.8
0 0.0
0 0.0
I
fTime-->
26.00 26:50 27.00 27.50
(Abundance
300000 '.
TIC: ENG1328.D
Time--> 27.80
Abundancelon 176.00 (175.70 to 176.70): ENG
300000 j
200000 .
100000 .
28.04
°i
Time--> 27.80
28.00
28:20
TTGT378TD—FEST7T
Tue May 2b Uy:27:b4
#9
Fluorene-dlO
Concen: 3.98 ng/uL
RT: 28.04 min Scant 2712
Delta R.T. 0.03 min
Lab File: ENG1328.D
Acq: 19 May 99 7:40 pm
Tgt Ion:176 Resp: 850930
Ion Ratio Lower Upper
176 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
HP 5989B
Page 6
-------
Abundance
300000 .
200000 .
100000 .
TIC: ENG1328.D
Time--> 27!00 27.50 28.00 28.50 29.00
Abundance Ion 166.00 (165.70 to 166.70): ENG
•lion 165.00 (164.70 to 165.70): ENG
60000:
i
1
40000:
20000 -
fTitne--> 27100 27:50 28.00 28.50 29.00
Abundance
600000 J
400000:
TIC: ENG1328.D
200000:
Time-->
30:30
30.40
30:50
#10
Fluorene
Conceri: 0.00 ng/uL
Expected RT: 28.08 min
Lab File: ENG1328.D
Acq: 19 May 99 7:40 pm
Tgt Ion: 166
Ion Exp Ratio
166 100
165 76.2
0 0.0
0 0.0
Abundancelon 188.00 (187.70 to 188.70): ENG
Ion 94.00 (93.70 to 94.70): ENG13
30.47
400000:
300000 :
200000 J
100000:
rime--> 30l30 30.40 30,50
30.60
ENGlTZBTE PES.M
#11
Phenanthrene-dl0
Concen: 3.54 ng/uL
RT: 30.47 min Scan# 3081
Delta R.T. 0.03 min
Lab File: ENG1328.D
Acq: 19 May 99 7:40 pm
Tgt Ion:188 Resp: 1172069
Ion Ratio Lower Upper
188 100
94 39.5 15.1 45.1
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Tue way 25
iyyy
HP 5989B
r Ta.TO
- >.'•** *- .4
Page 7
-------
Abundance
TIC: ENG1328.D
rime--> 30.40
30.50
30.60
(Abundance I on 178.00 (177.70 to 178770)
100000Jlon 176.00 (175.70 to 176.70)
' 30.53
50000
ENG
ENG
I
(Time -
- >
30
Uo '
30
!so
30
!eo ' ' '
#12
Phenanthrene
Concen: 0.50 ng/uL
RT: 30.53 min Scan# 3091
Delta R.T. 0.04 min
Lab File: ENG1328.D
Acq: 19 May 99 7:40 pm
Tgt Ion:178 Resp: 202506
Ion Ratio Lower Upper
178 100
176 26.0 10.1 30.1
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance
600000:
400000:
200000:
TIC: ENG13ZFTD
Time-->
30:50
30.60
30.70
Abunaancelon 188.00 (187.70 to 188.70) : ENG
400000J10n 94-°° (93.70 to 94.70): ENG13
300000 :
200000J
100000 .
Time--> 30^50
ENGIJ2B.DPES.M
30.60
May 2b 09:28:00 1999
#13
An thracene-dl0
Concen-. 2.00 ng/uL m
RT: 30.61 min Scan# 3103
Delta R.T. 0.04 min
Lab File: ENG1328.D
Acq: 19 May 99 7:4 0 pm
Tgt Ion:188 Resp: 575365
Ion
188
94
0
0
Ratio
100
161.0
0.0
0.0
Lower Upper
15 .1
0.0
0.0
45. 1#
0.0
0.0
r\r\o r f* .^_
Illi-t'S . «».vO
\J\r V> ! \J-- •<£
HP 5989B
Page 8
-------
Abundance
TIC: ENG1328.D
Time-->29:50 30.00 30.50 31.00 31.50
Abundance Ion 178.00 (177.70 to 178.70): ENG
lOOOOOJIon 176.00 (175.70 to 176.70): ENG
#14
Anthracene
Concen: 0.00 ng/uL
Expected RT: 30.62 min
Lab File: ENG1328.D
Acq: 19 May 99 7:40 pm
Tgt Ion: 178
Ion Exp Ratio
178 100
176 20.0
0 0.0
0 0.0
50000 .,
ime-->29.50 30!00 30.50
Abundance
800000J
TIC: ENG1328.D
Time--> 33.40 33.50 33.60 33.70 33.80
ADundanceTon 212.00 (211.70 to 212.70): ENG
Ion 106.00 (105.70 to 106.70): ENG
400000:
33.61
Time-->33.40 33.50 33.60 33.70 33.80
ENGT3~2~8~7EPEb . M
#15
Fluoranthene-dl0
Concen: 4.36 ng/uL
RT: 33.61 min Scan# 3623
Delta R.T. 0.04 min
Lab File: ENG1328.D
Acq: 19 May 99 7:40 pm
Tgt Ion:212 Resp: 1429278
Ion Ratio
212 100
106 41.0
0 0.0
0 0.0
Lower Upper
15.1
0.0
0.0
45.1
0.0
0.0
OOC.lSc4
TUe May 25 09:28:03
HP 5989B
Page 9
-------
Abundance
4000000.
TIC
fTime--> 32150 33:00 33.50 34.00 34.50
[Abundance I on 202.00 (201.70 to 202.70): ENG
Ion 101.00 (100.70 to 101.70): ENG
80000 J
60000:
40000
20000 J
-I
!Time--> 32.50 33.00 33.50 34.00 34.50
[Abundance
4000000
3000000 *
2000000:
1000000:
TIC: ENG1328.D
Time--> 34 .00
0±
34:20
34.40
#16
Fluoranthene(CCC)
Concen: 0.00 ng/uL
Expected RT: 33.€2 min
Lab File: ENG1328.D
Acq: 19 May 99 7:40 pm
Tgt Ion: 202
Ion Exp Ratio
202 100
101 27.0
0 0.0
0 0.0
Abundance ion 212.00 (211.70 to 212.7D): ENG
-lion 106.00 (105.70 to 106.70): ENG
400000 .
200000
rime--> 34.00
34.20
34.40
ENG1328
me May
U9:2e:ut> 1999
#17
Pyrene-dlO
Concen: 4.28 ng/uL
RT: 34.30 min Scan# 3726
Delta R.T. 0.05 min
Lab File: ENG1328.D
Acq: 19 May 99 7:40 pm
Tgt Ion:212 Resp: 1542668
Ion Ratio
212 100
106 41.8
0 0.0
0 0.0
Lower Upper
17.1
0.0
0.0
51.1
0.0
0.0
HP S989B
Page 10
-------
Abundance
4000000.
TIC: ENG1328.D
Time-->
33:50 34.00 34!50
T—i—I—i—i—i—r
35.00
Abundancelon 202.00 (201.70 to 202.70): EtfG
lion 101.00 (100.70 to 101.70): ENG
oO 000_
frime - - >
33.50 34.00 34.50
i—i—|—i—i—i—r
35.00
#18
Pyrene
Concen: 0.00 ng/uL
Expected RT: 34.30 min
Lab File: ENG1328.D
Acq: 19 May 99 7:40 pm
Tgt Ion: 202
Ion Exp Ratio
202 100
101 32.0
0 0.0
0 0.0
ENG
Abundance TIC: ENG1328.D
i
4000000 ;
-
3000000 ^
i I
2000000 J
.
1000000 .
:
o :
^\^ ^J
Time--> 34 40 34
Abundancelon 244.00 (243
3000000 J
2000000 .
1000000 :
0 .
Ion 122.00 (121
•5
3
J
A
\
\
\
\
\
\
V
I i 1 i 1 1 i i 1 r
.60 34 80
.70 to 244.70) : ENG
.70 to 122.70) : ENG
A"
1
H.
Time--> 34140 34leo ' ' 34.80
I^b .D tftib.M Tue May 2b 09:28:10 199'9
#19
p-Terphenyl
Concen: 42.
-di4
76 ng/uL
RT: 34.62 min Scan# 3774
Delta R.T.
Lab File:
Acq: 19 May
Tgt Ion: 244
Ion Ratio
244 100
122 30 . 3
0 00
w \J * \J
0 0.0
0.05 min
ENG1328 .D
99 7:40 pm
Resp:11647522
Lower Upper
13 . 6 40.6
on n n
\J . W U . U
0.0 0.0
^^ ^^ XV •» ^-
OGe. ; Ooi
HP 5989B Paqe
-------
PIC: ENG1328.D
400000 J
200000 .
rime-->
38:80 38.90 39.00 39.10
Abundance Ion 240.00 (239.70 to 240.70): ENG
lion 120.00 (119.70 to 120.70): ENG
300000
200000 J
100000 J
T
#20
Benzo(a)anthracene-d!2
Concen: 4.50 ng/uL
RT: 38.96 min Scan# 4428
Delta R.T. 0.08 min
Lab File: ENG1328.D
Acg: 19 May 99 7:40 pm
Tgt Ion:240 Resp: 1039857
Ion Ratio
240 100
120 42.8
0 0.0
0 0.0
Lower Upper
15.1
0.0
0.0
45.1
0.0
0.0
ime-->
38.80
38.90 39.00
39.10
TIC: ENG1328.D
400000 .
200000
0
Time-->
38.00 38.50 39.00 39.50
Abundance Ion 228.00 (227.70 to 228.70)
lion 114.00 (113.70 to 114.70)
100000
50000 .
ENG
ENG
Time-->
38.00 38.50 39.00 39.50
ENG1328.D—PES71
Tue May 2b 09:20:13 1999
#21
Benzo(a)anthracene
Concen: 0.00 ng/uL
Expected RT: 38.98 min
Lab File: ENG1328.D
Acq: 19 May 99 7:40 pm
Tgt Ion: 228
Ion Exp Ratio
228 100
114 25.0
0 0.0
0 0.0
HP 5989B
Page 12
-------
TIC: ENG132B.D
400000 .
j 2000004
Time--> 38.90 39.00 39.10 39.20 39.30
Abundance Ion 240.00 (239.70 to 240.70) :
Ion 120.00 (119.70 to 120.70):
300000 .
200000 _
100000 -i
ENG
ENG
ime-->
38.90 39^00 39.10 39120 39.30
#22
Chrysene-dl2
Concen: 4.60 ng/uL
RT: 39.12 min Scan# 4453
Delta R.T. 0.09 min
Lab File: ENG1328.D
Acq: 19 May 99 7:40 pm
Tgt Ion:240 Resp: 1288611
Ion
240
120
0
0
Ratio
100
38.9
0.0
0.0
Lower Upper
15.1
0.0
0.0
45.1
0.0
0.0
400000 .
200000
TIC: ENG1328.D
0 -L
Time-->
38.50 39.00 39.50 40.00
Abundancelon 228.00 (227.70 to 228.70): ENG
lion 114.00 (113.70 to 114.70): ENG
100000 .
50000 .
rime-->
38.50 39.00 39.50 40.00
ENGl3~2"8TBPES .M
#23
Chrysene(CCC)
Concen: 0.00 ng/uL
Expected RT: 39.16 min
Lab File: ENG1328.D
Acq: 19 May 99 7:40 pm
Tgt Ion: 228
Ion Exp Ratio
228 100
114 25.0
0 0.0
0 0.0
ooc
Tue May 25 09:28:16
HP 5989B
Page 13
-------
Abundance
400000.1
TIC: ENG1328.D
Time--> 45.80
46.00
46.20
Abundancelon 264.00 (263. TO to 264.7T)} : ENG
Ion 132.00 (131.70 to 132.70): ENG
150000 '.
100000 J
50000
[Time--> 45! 80
46.00
46.20
TIC
[Abundance
I 400000
300000 J
200000
100000:
Time--> 45100 45.50 46.00 46.50 47.00
#24
Benzo(b)fIuoranthene-dl2
Concen: 5.02 ng/uL m
RT: 46.05 min Scan# 5518
Delta R.T. 0.18 min
Lab File: ENG1328.D
Acq: 19 May 99 7:40 pm
Tgt Ion:264 Resp: 1033937
Ion Ratio Lower Upper
264 100
132 111.0 15.1 45.1#
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance Ion 252.00 (251.70 to 252.70): ENG
Jlon 126.00 (125.70 to 126.70): ENG
100000 .
50000 .
Time--> 45.00 45.50 46.00 46.50 47.00
NGl3~2~8~7D
Tue May 25 09:2B:iy 1999
#25
Benzo(b)fluoranthene
Concen: 0.00 ng/uL
Expected RT: 46.07 min
Lab File: ENG1328.D
Acq: 19 May 99 7:40 pm
Tgt Ion.- 252
Ion Exp Ratio
252 100
126 25.0
0 0.0
0 0.0
HP 5989B
Page 14
-------
Abundance
400000J
TIC: ENG132U.D
Time-->
46.00
46.20
46.40
[AbundanceIon 264.00 (263.70 to 264.70): ENG
]Ion 132.00 (131.70 to 132.70): ENG
150000
100000:
50000 .
#26
Benzo(k)fIuoranthene-dl2
Concen: 4.27 ng/uL m
RT: 46.25 min Scan# 5549
Delta R.T. 0.18 min
Lab File: ENG1328.D
Acq: 19 May 99 7:40 pm
Tgt Ion:264 Resp: 1199652
Ion Ratio Lower Upper
264 100
132 107.2 15.1 45.1#
0 0.0 0.0 0.0
0 0.0 0.0 0.0
trims-->
46.00
46.20
46.40
Abundance
400000
300000 J
200000:
100000
Time-->
TIC: ENG1328.D
45:50 46.00 46.50 47iOO
#27
Benzc(k)fluoranthene
Concen: 0.00 ng/uL
Expected RT: 46.23 min
Lab File: ENG1328.D
Acq: 19 May 99 7:40 pm
Tgt Ion: 252
Ion Exp Ratio
252 100
126 25.0
0 0.0
0 0.0
Abundanceion 252701) (251770 to 252.70) : ENG
Jlon 126.00 (125.70 to 126.70): ENG
100000 _,
50000 .
0 .
Time-->
45.50 46.00 46:50 47!00
ENG1378TD
OOC.'.OrO
TUB May 25 U9:28:22 1999
HP 5989B
Page 15
-------
Abundance
200000
150000 :
100000:
50000:
TIC: ENG1328.D
ritne--> 48.40
— i — I — i — i
48.60
48.80
T—i—i—i—r
49.00
Abundance Ion 264.00 (263.70 to 264.70): ENG
100000Jlon 132.00 (131.70 to 132.70): ENG
50000 J
0
?ime--> 48^40 48.60 48.80 49.00
#28
Benzo(a)pyrene-d!2
Concen: 1.88 ng/uL tn
RT: 48.77 min Scan# 5935
Delta R.T. 0.23 min
Lab File: ENG1328.D
Acq: 19 May 99 7:40 pm
Tgt Ion:264 Resp: 351751
Ion Ratio
264 100
132 209.7
0 0.0
0 0.0
Lower Upper
15.1
0.0
0.0
45.1#
0.0
0.0
Abundance
200000 j
150000
100000 J
1
1
50000 J
(
Time-->
TIC: ENG1328.D
4800
49oO
Abundance Ion 252.00 (251.70 to 252.70): ENG
Ion 126.00 (125.70 to 126.70): ENG
100000 .
50000 J
rime - - >
48o
49o
50 o
ENGiJ2TT7E PES .M
#29
Benzo(a)pyrene(CCC)
Concen: 0.00 ng/uL
Expected RT: 48.74 min
Lab File: ENG1328.D
Acq: 19 May 99 7:40 pm
Tgt Ion: 252
Ion Exp Ratio
252 100
126 25.0
0 0.0
0 0.0
Tue May 25 09:28:25 1999
HP 5989B
Page 16
-------
Abundance
150000-
100000.
50000J
TIC: ENG132S.D
Time-->
61.50
62.00
62150
Abu.
el on 288.0(5 T287.70 to 288.70): ENG
61.96
40000 -
20000 -
Time-->
61.50
62100
62150
Abundance
150000 J
100000 .
50000 '.
TIC: ENG1328.D
Time-->
Abu
0
61.00
62.00
63100
#30
Indeno(1,2,3-cd)pyrene-dl2
Concen:: 2.85 ng/uL
RT: 61,96 min . Scan# 8191
Delta R.T. 0.48 min
Lab File: ENG1328.D
Acq: 19 May 99 7:40 pm
Tgt Ion:288 Resp: 714365
Ion Ratio Lower Upper
288 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
elon 276.05 (275.75 to 275.75): ENG
lion 138.00 (137.70 to 138.70): ENG
60000 J
40000
20000:
Time-->
61.00
62:00
63.00
ENG1328.DPES. M
#31
Indeno(1,2,3-cd)pyrene
Concen: 0.00 ng/uL
Expected RT: 61.83 min
Lab File: ENG1328.D
Acq: 19 May 99 7:40 pm
Tgt Ion: 276.05
Ion Exp Ratio
276 100
138 64.0
0 0.0
0 0.0
Tue May 25 U9:2b:i29 1999
HP 5989B
Page 17
-------
TIC: ENG1328.D
Time-->
61.50
62.00
Abundancelon 292.00 (291.70 to 292.70)
ENG
40000
30000 j
20000j
10000 i
61.88
0 J
?ime-->
61.50
62:00
Abundance
150000
100000
50000 J
Time-->
TIC: ENG1328.D
Abundance Ion 278.00 (277.70 to 278.70): ENG
100000JIOn 139-°° (138.70 to 139.70): ENG
61.00
62!00
63.00
#32
Dibenz(a,h)anthracene-dl4
Concen: 3.24 ng/uL m
RT: 61.88 min Scan# 8175
Delta R.T. 0.44 min
Lab File: ENG1328.D
Acq: 19 May 99 7:40 pm
Tgt Ion:292 Resp: 475478
Ion Ratio Lower Upper
292 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
50000 .,
Time - - >
61.00
62.00
eslod
ENGl3'2.8 .D FES .M
TU6
1999
#33
Dibenz(a,h)anthracene
Concen: 0.00 ng/uL
Expected RT: 61.85 min
Lab File: ENG1328.D
Acq: 19 May 99 7:40 pm
Tgt Ion: 278
Ion Exp Ratio
278 100
139 25.0
0 0.0
0 0.0
HP 5989B
Page 18
-------
Abundance
60000J
40000.
20000 1
TIC: ENGl32ti.D
! o
Time-->
Abundancelon 288.00 (267.70 to 288.70): ENG
65.00
65.50
66.00
40000 .
30000 J
I i
1 20000:
10000:
65.61
OJ
Time--> 65.00
65.50
66.00
[Abundance
80000:
60000 :
40000:
20000 :
Time-->64 .00
TIC: ENG1328.D
65.00
66.00
Abundance Ion 276.00 (275.70 to 276.70): ENG
Jlon 138.00 (137.70 to 138.70): ENG
30000J
20000:
10000:
#34
Benzo(g,h,i)perylene-d!2
Concen: 2.82 ng/uL m
RT: 65.61 min Scan# 8963
Delta R.T. 0.54 min
Lab File: ENG1328.D
Acg: 19 May 99 7:40 pm
Tgt Ion:288 Resp: 558032
Ion
288
0
0
0
Ratio
100
0.0
0.0
0.0
Lower Upper
0.0
0.0
0.0
0.0
0.0
0.0
o:
Time-->64.00
ENGTI2TT7T3 PES.M
65.00
66.00
#35
Benzo(g,h,i)perylene
Conce:n: 0.00 ng/uL
Expected RT: 65.44 min
Lab File: ENG1328.D
Acq: 19 May 99 7:40 pm
Tgt lion: 276
Ion Exp Ratio
276 100
138 25.0
0 0.0
0 0.0
Tue May 25 09 :2b:
HP 5989B
Page 19
-------
APPENDIX D
CARS 429 FIELD DATA
-------
APPENDIX D.I
CARS 429 FIELD DATA SHEETS
-------
Circularftack Method 1 Calculation Bgsults
Date: 04/01/99 Time: 14:45:23
Br
™
Facility: Cooper Bessmer
Source ID: Catalyst
Source Name: Cat Inlet 1-in port
Date: 03/31/99
Calculated By: Brian Urban
Input Values
Traverse Point Type: Sample - M5
Inside of far wall to outside of nipple: 1 3 even
Nipple Length: 1 even
Distance from Upstream Disturbance: 48 1/2
Distance from Downstream Disturbance: 26 1/2
Number of ports: 2 ports at 90
(inches)
(inches)
(inches)
(inches)
degrees
Calculated Values
Inside Diameter: 12
Upstream Duct Diameters: 4.04
Downstream Duct Diameters: 2.20
Mininum Traverse Points: 24
(inches)
Traverse Fraction Product of Nipple Traverse Point
Point of Length Columns Length Location
Number Length (inches) 2 & 3 (inches) Sum of Col. 4 & 5
1
2
3
4
5
6
7
8
9
10
11
12
0.021
0.067
0.118
0.177
0.250
0.356
0.644
0.750
0.823
0.882
0.933
0.979
12 even
12 even
12 even
12 even
12 even
12 even
12 even
12 even
12 even
12 even
12 even
12 even
0 1/2
013/16
1 7/16
2 1/8
3 even
4 1/4
7 3/4
9 even
9 7/8
10 9/16
11 3/16
11 1/2
1 even
1 even
1 even
1 even
1 even
1 even
1 even
1 even
1 even
1 even
1 even
1 even
1 1/2
1 13/16
2 7/16
3 1/8
4 even
5 1/4
8 3/4
10 even
10 7/8
11 9/16
12 3/16
12 1/2
-------
Circulaj^tack Method 1 Calculation Bttsults
^^ Date: 04/01/99 Time: 14:43:49 ^^
Facility: Cooper Bessmer
Source ID: Catalyst
Source Name: Cat Inlet 3-in port
03/31/99
Brian Urban
Date:
Calculated By:
Input Values
Traverse Point Type: Sample - M5
Inside of far wall to outside of nipple: 14 even (inches)
Nipple Length: 2 even (inches)
Distance from Upstream Disturbance: 23 even (Inches)
Distance from Downstream Disturbance: 52 even (inches)
Number of ports: 2 ports at 90 degrees
Calculated Values
Inside Diameter: 12
Upstream Duct Diameters: 1.91
Downstream Duct Diameters: 4.33
Mininum Traverse Points: 24
(inches)
Traverse Fraction Product of Nipple Traverse Point
Point of Length Columns Length Location
Number Length (inches) 2 & 3 (inches) Sum of Col. 4 & 5
1
2
3
4
5
6
7
8
9
10
11
12
0.021
0.067
0.118
0.177
0.250
0.356
0.644
0.750
0.823
0.882
0.933
0.979
12 even
12 even
1 2 even
12 even
12 even
1 2 even
12 even
12 even
12 even
12 even
1 2 even
12 even
0 1/2
013/16
1 7/16
2 1/8
3 even
4 1/4
7 3/4
9 even
9 7/8
10 9/16
11 3/16
11 1/2
2 even
2 even
2 even
2 even
2 even
2 even
2 even
2 even
2 even
2 even
2 even
2 even
2 1/2
213/16
3 7/16
4 1/8
Seven
6 1/4
9 3/4
11 even
11 7/8
12 9/16
13 3/16
13 1/2
WARNING: This sampling location does not meet EPA Sampling Criteria
-------
i i
£7 PACIFIC ENVIRONMENTAL SERVICES, INC.
i '_ _ iral Ft *Vesf
5001 South Miami Boulevard, P.O. Box 12077
Research Triangle Park, North Carolina 27709
(919) 941-0333 FAX: (919) 941-0234
Plant:
US EPA RICE HAP TESTING - GARB 429 FIELD DATA SHEET
Nozzle ID:
Sampling Location:
Run Number: eft
Date:
Sample Type: y^s Operator(s). j^y\
Pbar- 3V.-8-V P.." i- t
CO2: lb O2: / 9
Pretest Leak Rate:
cfm @ /g in. Hg Probe Length/Type:
Pretest Leak Check: Pitot: ,X Orsat: O)A Stack Diameter: /.
As:
Pitot #: _
/13.. 10
Assumed B^:
Meter Box No.:
Posttest Leak Rate:
Thermocouple No.:
Filter No.:
JLE_
_£SL
/••sc.
2 ?£
-254'
•fi
<•*/
SS
J-SU
SI 3.155
Vf
« .
•SO
•7*
-13L.
< .Sc.
•5o
7f
S I
50
t.VS
y.
^S^
51
So
to
1.4S
^JL
so
to
1-C.J
^53
5" /
J5J
fOS
/•(>3
_£jL
_£L
-7J^-
7-S
AH
Ts:
Tm:
Page.
of
Pages
-------
Page
ol
Plant Name:
Run Number:
Test Date:
Operator:
Tnvene
Foint
Number
Sampling /Clock Time
Time. / (24 hour
(rain.) / clock)
| ^ / l^Or-
t3t? 1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
Gas Meier
Reading
(U)ft'
654,-spo
C,-sl.7fo
Velocity
lleadtP,
in. IhO
.^o
.^0
Orifice Ptes. Differential
(All) in. 11,0
Desired
AC. 3
'•Olj
Actual
/- C*"*.
i.e. •?
Stack
Temp. • F
m
to (flO
Ls. iO
Probe
Temp./ Filter
Temp." F
«3Se> i#5c3
^So.^^,0
/
/
/
/
/
/
/
/
/
/
/
/
/
/
A
/
/
/
/
/
/
/
Impingei
Temp.
•F
*/S
Uuilel
(^•J0'7
•?G»
*? c.
Pump
Vacuum
In. l/g
^
H
-------
PACIFIC ENVIRONMENTAL SERVICES, INC.
Central Park West
5001 South Miami Boulevard, P.O. Box 12077
Research Triangle Park, North Carolina 27709
(919) 941-0333 FAX: (919) 941-0234
Sample Train Recovery Data
CARB Method 429
Determination of Polycyclic Aromatic Hydrocarbons (PAH) from Stationary Sources
Facility: (tf d'A
Date: A/
Clean-up person:
Field Team Leader:
Comments:
rW
Project No.:.
Run No.:CL
- ftofl
Sampling Location: Cocfel
Samplers: §V\\ f jj
Filter No.:_
Filter No.:
/A
Front-Half Data
Filter Media: Tare Wt (mg): N /ft
Filter Media: Tate Wt (mg):
Back-Half Data
Contents:
Final mass (g):
Initial mass (g):
Net Mass (g)
XAD-2 Sorbent Resin
Trap
XAD-2 Sorbent Resin
*4»fl
347.3
0-4
Knock-out Impinger
MT
4%. I
^B4.1
€6-6
Impinger No. 1
100mlHPLCH2O
•W*4
^63.0
76-6
Contents:
Final mass (g):
Initial mass (g):
Net Mass (g)
Impinger No. 2
100mlHPLCH2O
TO.T-
^^.Z
**
Impinger No. 3
MT
638- »
6404
7-3
Impinger No. 4
Silica Gel
eifc.>
21&.B
?o. \
Total Moisture Collected: (g):_
Description of Impinger Catch:_
-------
OPAC
PACIFIC ENVIRONMENTAL SERVICES, INC.
Central Park West
5001 South Miami Boulevard, P.O. Box 12077
Research Triangle Park, North Carolina 27709
(919) 941-0333 FAX: (919) 941-0234
Plant:
US EPA RICE HAP TESTING - GARB 429 FIELD DATA SHEET
Sample Type: y/3°\ Operator(s): V^V^)^ Nozzle ID: *<2ife Thermocouple No.:
Sampling Location: L. tumour ftc
Run Number: JT-yjy- j. Date: _
Pretest Leak Rate: o.p^o cfm @
CO2:
y
Ps: -V ^-o Assumed B^: /o Filter No. : t
. O2: LS Meter Box No.f^gjj^ y: I>^QV AH@: /_;
Prelesl Leak Check: Pilot:
/•S" in. Hg Probe Length/Type: f
Orsat: ^M Stack Diameter: 1^-" As:
Pilot #: s-
Posttest Leak Rate: n .n^c\ cfm @ ff" in. Hg
Posttest Leak Check Rate: Pilot: ^-Orsat:
AH:
Tm:
Page V of A Pages
-------
t 1
Page
of
Plant Name:
Run Number:
r-
Test Date:
Operator:
Traverse
Point
Number
Sampling /dock Time
Time, / (24 hour
(min.) / clock)
l\5 ' ,5130
'^> ' fg>S
/
/
/
/
/
/
/
/
/
/
/
/
/
/
/
/
/
/
/
/
/
/
Gas Meier
Reading
(*)fti
7^. 3 SO
•» BJ//^ /
Velocity
lleadtP,
in.II}0
.•8^5
•"80
Orifice Pies. Differential
(^11) in. 11,0
Desired
I.T\
/.-> ^
Actual
(.T\
\.Tcx
Slack
Temp. • F
m
& V^
C*vS
Probe
Temp./ Filler
Temp.0 F
JJ5C/ ^»5o
P^c/ ^so
/
/
/
/
/
/
/
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
Iropingcr
Temp.
•F
'(&>
4S
Dry Gas Meier Temp.
Inlet
(*h)*F
•*! J-
T ' "^
;S^>
\
UUIICl
C«Al*P
5~(
S I
Pump
Vacuum
ln.llg
^
s
-------
$
PACIFIC ENVIRONMENTAL SERVICES, INC.
Central Park West
5001 South Miami EJoulevard, P.O. Box 12077
Research Triangle Park, North Carolina 27709
(919) 941-0333 FAX: (919) 941-0234
Sample Train Recovery Data
CARB Method 429
Determination of Poiycyctic Aromatic Hydrocarbons (PAH) from Stationary Sources
Facility:
Date:
Clean-up person:
Field Team Leader:
Comments:
Project No.:_
Run No.:
Sampling Location: t tVrfo
Samplers:
Filter No.:_
Filter No.:
Front-Half Data
Filter Media: ~fc( W. W^U. Tare Wt (mg):
Filter Media:
Tate Wt (maV.
Back-Half Data
Contents:
Final mass (g):
Initial mass (g):
Net Mass (g)
XAD-2 Sorbent Resin
\(%~l Trap
XAD-2 Sorbent Resin
m&
30>
?.\
Knock-out Impinger
MT
4&S-Z
-^W4
)I6. I
Impinger No. 1
100mlHPLCH2O
6?3-^
6"*'-*'
(7.Z)
Contents:
Final mass (g):
Initial mass (g):
Net Mass (g)
Impinger No. 2
100mlHPLCH2O
^c.S
««?.•*
(I-O
Impinger No. 3
MT
6^.4
6?T-^
1-4
Impinger No. 4
Silica Gel
66*. 4-
mz
KA
Total Moisture Collected: (g):_
Description of Impinger Catch:.
-------
O PACIFIC ENVIRONMENTAL SERVICES, INC.
| I » *- ; | ~|ntra^r'--J/A Stack Diameter: ,
_ Operator(s):
D • +-
.02: ,
'
As:
Pitot #: 3-0
Nozzle ID:
Assumed E
Thermocouple No.:
. Filter No. :
Y:_LI
iAH@:
~7
Meter Box No.:
Posttest Leak Rate: O.QQI cfm @ /S" in. Hg
Posttest Leak Check Rate: Pitot: ^-- Orsat:
Page of.
,Pages
-------
Page
Ol
Plant Name:
Run Number:
* C.L
Test Date: ---- a.^fc«
Operator: _ll
Traverse
Point
Number
Sampling /dock Time
Time, / (24-hour
(rain) / clock)
i i c. 1 I.SK.IZ.
1 }O ' e?«3C^O
/
/
/
/
/
/
/
/
/
/
/
/
/
/
/
/
/
/
/
/
/
/
Gas Meier
Reading
(\t)fti
8-£i£S£>
{?1
/. r= (
Actual
/.(*!
y-c,(
Stack
Temp. * F
m
4 Jo
r^j>o
Piobc
Temp./ Filler
Temp* F
JS^7 J5fe
j
-------
O PACIFIC ENVIRONMENTAL SERVICES, INC.
Central Park West
5001 South Miami Boulevard, P.O. Box 12077
Research Triangle Park, North Carolina 27709
(919) 941-0333 FAX: (919) 941-0234
Sample Train Recovery Data
CARB Method 429
Determination of Polycyclic Aromatic Hydrocarbons (PAH) from Stationary Sources
Facility: US efft
Date: 4 h
Project No.: x
Run No.: C fe - 474 -
Clean-up person:
Field Team Leader: V\Mlf\fl
Comments:
Sampling Location: Wurr
Samplers: _
Filter No.:_
Filter No.:
Front-Half Data
Filter Media: TtfUjo Tare Wt (mg):.
Filter Media:
Tate Wt (ma):
Back-Half Data
Contents:
Final mass (g):
Initial mass (g):
Net Mass (g)
XAD-2 Sorbent Resin
Trap
XAD-2 Sorbent Resin
Z4
-------
TRAVERSE POINT LOCATION FOR CIRCULAR DUCTS
Plant:
Date:
Sampling Location:.
Inside of Far Wall to Outside of Nipple:.
Inside of Near Wall to Outside of Nipple (Nipple Length):,
Stack I.D.: >*"
Distance Downstream from Flow Disturbance (Distance B):
%-5 inches / Stack I.D. » g.o? dd
Distance Upstream from Flow Disturbance (Distance A):
TV &?•£ inches / Stack I.D.
Calculated Bv: tf&
Schematic of
Sampling Location
Traverse
Point
Number
i
z.
5
f
Fraction
of
Length
.«.?-
,2S7>
.?*Z>
•9SS
Length
(inches)
\i
12.
)Z
H.
Product of
Columns 2 & 3
(To nearest 1/8")
&" J3//4*1
3"
f"
// 3//4-
Nipple
Length
(inches;)
2"
r'
2"
2"
Traverse Point
Location
(Sum of Col. 4 & 5)
2 •@^>'/3/'i
g-"
i r
/^ S//i"
/
-------
Circulafetack Method 1 Calculation (Bsults
Date: 03/30/99 Time:05:56:43
Facility: Cooper Bessmer
Source ID: Catalyst
Source Name: Outlet
Date: 03/29/99
Calculated By: Brian Urban
Traverse Point Type:
Inside of far wall to outside of nipple:
Nipple Length:
Distance from Upstream Disturbance:
Distance from Downstream Disturbance:
Number of ports:
Sample - M5
13 even
1 even
1051/2
801/2
(inches)
(inches)
(inches)
(inches)
2 ports at 90 degrees
Inside Diameter: 12
Upstream Duct Diameters: 8.79
Downstream Duct Diameters: 6.70
Mininum Traverse Points: 8
(inches)
0.067
12 even
013/16
1 even
1 13/16
0.250
12 even
Seven
1 even
4 even
0.750
12 even
9 even
1 even
10 even
0.933
12 even
11 3/16
1 even
12 3/16
-------
itack Method 1 Calculation
Date: 03/30/99 Time: 10:22:08
Facility: Cooper Bessmer
Source ID: CB
Source Name: Cat Out 3-in port
Date: 03/30/99
Calculated By: MDM
Input
Traverse Point Type:
Inside of far wall to outside of nipple:
Nipple Length:
Distance from Upstream Disturbance:
Distance from Downstream Disturbance:
Number of ports:
Values
Sample - MS
14 even
2 even
96 1/2
89 1/2
2 ports at 90
(inches)
(inches)
(inches)
(inches)
degrees
Calculated Values
Inside Diameter:
Upstream Duct Diameters:
Downstream Duct Diameters:
Mininum Traverse Points:
12
8.04
7.45
8
(inches)
Traverse Fraction Product of Nipple Traverse Point
Point of Length Columns Length Location
Number Length (inches) 2 & 3 (inches) Sum of Col. 4 & 5
1
2
3
4
0.067
0.250
0.750
0.933
12 even
12 even
12 even
12 even
0 13/16
3 even
9 even
11 3/16
2 even
2 even
2 even
2 even
213/16
5 even
11 even
13 3/16
-------
1 s
f 1
OPACIRC ENVIRONMENTAL SERVICES, INC.
t 1 f - * * * i
Central Park West
5001 South Miami Boulevard, P.O. Box 12077
Research Triangle Park, North Carolina 27709
(919) 941-0333 FAX: (919) 941-0234
Plant:
US EPA RICE HAP TESTING - GARB 429 FIELD DATA SHEET
Sample Type: VJ"! Operator(s): j^\\ Nozzle ID: .as?
Sampling Location:
Run Number:
Pretest Leak Rate:
Pretest Leak Check: Pilot:
-D Date: 4 -A
cfm@_JL5__
^ Orsat:
Pbar-' .
C02:
V 7.o
Assumed B
3,
0,:
in. Hg Probe Length/Type:
Stack Diameter: /,
Pilot #:
Meter Box No.:
Posttest Leak Rate:
Thermocouple No.:
Filter No.: /oM
r-
AH@:
cfm @
in. Hg
Posttest Leak Check Rate: Pilot:
Orsat:
AH:
Page | of ^ Pages
-------
Page
ol
Plant Name:
Run Number:
Test Date:
Operator:
Traverse
Point
Number
Sampling /dock Time
Time, / (24-hour
(rain.) / clock)
.,< /
130 f
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
I
1
1
1
1
1
Gas Meter
Reading
OL)ftJ
/TT.CeOl
f*l.'7££>
Velocity
IcadfP.)
in-lljO
.V*
.«^
Orifke Pres
(a") 1
Desired
l Ao
l.=iO
p.-^— .^— ^-^^—— —
. Differential
n.11,0
Actual
S .*\Ci
1.^0
Stack
Temp. • F
m
S'KO
•SHO
.^M^mw^^x^—
Probe
Temp. / Filler
Temp* F
J>-5». ^-SJL
j-st ' -?'s;»-
/
/
/
/
/
/
/
/
/
/
/
/
/
/
/
/
/
/
7
/
Impinger
Temp.
•F
st
•51
__ — "-
Inlet
f&ta)'F
•7*5
^"5
DulTel
C^«,,)*n
14
~> <
-------
PACIFIC ENVIRONMENTAL SERVICES. INC.
Central Park West
5001 South Miami Boulevard, P.O. Box 12077
Research Triangle Park, North Carolina 27709
(919) 941-0333 FAX: (919) 941-0234
Sample Train Recovery Data
CARB Method 429
Determination of Polycyclic Aromatic Hydrocarbons (PAH) from Stationary Sources
Facility:
Date:
/ 1 \Cf(
Clean-up person:
Field Team Leader:
Comments:
Project Ni
Run No.:
- 4W-0-
Sampling Location:.
Samplers: _
Front-Half Data
Filter No.: - Filter Media: TareWt(mg):.
Filter No.: Filter Media: TateWt(mg):.
Back-Half Data
Contents:
Final mass (g):
Initial mass (g):
Net Mass (g)
XAD-2 Sorbent Resin
Trap
XAD-2 Sorbent Resin
?9l.6
?63.>
2- 1
Knock-out Impinger
MT
4^8
kMr.'Z
m->
Impinger No. 1
100mlHPLCH2O
Gi).^
6»'-I
CO. 3)
I
Contents:
Final mass (g):
Initial mass (g):
Net Mass (g)
Impinger No. 2
100mlHPLCH2O
•&Hr
-------
OPAC
PACIRC ENVIRONMENTAL SERVICES, INC.
Central Park West
5001 South Miami Boulevard, P.O. Box 12077
Research Triangle Park, North Carolina 27709
(919) 941-0333 FAX: (919) 941-0234
US EPA RICE HAP TESTING - CARB 429 FIELD DATA SHEET
Plant:
Sampling Location. <-^P«4
Sample Type:
Pbar-' -tt.-S
CO2: 3
Operator(s):
PS-'
t- 7.0
Run Number: T-4&}~^ Date: y -j -^
Pretest Leak Rate: 6. of.? cfm @ /s in. Hg Probe Length/Type:
Pretest Leak Check: Pitot: v^ Orsat: i-^l*. Stack Diameter: /
O2:
Nozzle ID: JS") Thermocouple No.: ff.T-do
Assumed B^: JO Filter No.:_
Meter Box No.: /D •
Pitot*. <,-
As:
. AH@:_^
Posttest Leak Rate: Q.QQ,J cfm @ ts *'in. Hg
Posttest Leak Check Rate: Pitot: __^jOrsat:
Page / of ^ Pages
-------
Page
of
Plant Name:
Run Number:
r -
Test Date:
Operator: i>
Traverse
Point
Number
Sampling /dock Time
Time, / (24-hour
(rain.) / clock)
»S>o ' i-V^
I •?£& 1 K5-O
«/-£4er- '
/
/
/
/
/
/
/
/
/
1
1
1
1
1
1
1
1
1
1
1
1
Gas Meier
Reading
OL)ft)
*^"7l. 1 -X
t^SS, 30Cj
Velocity
llead(P,)
ialhO
.^o.
• 2O
Orifice Pies. Differential
l/JI)ial!20
Desired
\.1\
\ . ->°i
Actual
i.T\
1. •?«=!
Slack
Temp. • F
«)
SKS
5*1
Piobe
Temp. / Filler
Temp* F
£ "s 3 ^sa
^>?>^ f ~JS(
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
I
1
1
1
1
1
Impinge r
Temp.
•F
>y>
^
Dry Gas Meter Temp.
Inlet
f&b)*F
-13
•n
UUllCl
(*«,,) -F
1 l
•~t ^
Pump
Vacuum
lo Hg
<
^
-------
PACIFIC ENVIRONMENTAL SERVICES, INC.
Central Park West
5001 South Miami Boulevard, P.O. Box 12077
Research Triangle Park, North Carolina 27709
(919) 941-0333 FAX: (919) 941-0234
Sample Train Recovery Data
CARB Method 429
Determination of Polycyclic Aromatic Hydrocarbons (PAH) from Stationary Sources
Facility:
Date:
Clean-up person:
Field Team Leader:
Comments:
Project No.:_
Run No.: _£ld2lrrP_l_l
Sampling Location:
Samplers:
Filter No,: ^_
Filter No.:
Front-Half Data
Filter Media: TctU V\M. Tare Wt (mg):.
Filter Media: Tate Wt (mg):.
Back-Half Data
Contents:
Final mass (g):
Initial mass (g):
Net Mass (g)
XAD-2 Sorbent Resin
\OV3 Trap
XAD-2 Sorbent Resin
306.1
3oe-3
U
Knock-out Impinger
MT
4^6 -3
S0H
\?M*A
\. V
Impinger No. 4
Silica Gel
C\ld.V(
%).>
W.6
t
Total Moisture Collected: (g):_
Description of Impinger Catch:.
-------
O PACIFIC ENVIRONMENTAL SERVICES, INC.
50U1 iiouth Miami bouievara, r.u. uox
rf. ferchf !iglep. ?, Nol arolif F709-
(919) 941-0333 FAX: (919) 941-0234
F-C.LU
US EPA RICE HAP TESTING - GARB 429 FIELD DATA SHEET
Sample Type: Va^cfm @ J$ in. Hg Probe Length/Type:
Pretest Leak Check: Pitot: ___L^Orsat: N>|A Stack Diameter: i^'' A,.
Pbaf: ^S."g4
C02:____3_
.Ps:_
_02:.
-J- ~?.o
Thermocouple No.:
Assumed Bws: /Q Filter No.:
Meter Box No.: /C^ y: i,&& AH@:
Pitot #: <,— I Posttest Leak Rate: Q.ocQ cfm @ 15 in. Hg
Posttest Leak Check Rate: Pitot:
Page of Pages
-------
Page
of
Plant Name:
Run Number:
E.GLCV-
Test Date:
Operator:
Tnvene
Point
Number
Sampling /dock Time
Time, / (24-hour
(rain.) / clock)
it* '
Uo 1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
Gas Meter
Reading
(\fc)ft>
J 77.^30
381 4£v
Velocity
HcadfP,
in.lliO
- »S
••as
Orifice Pies. Differential
(£ll)in.H2O
Dewed
1 <\o
/.^O
Actual
\^
I -90
Slack
Temp. • F
m
-------
PACIFIC ENVIRONMENTAL SERVICES, INC.
Central Park West
5001 South Miami Boulevard, P.O. Box 12077
Research Triangle Park, North Carolina 27709
(919) 941-0333 FAX: (919) 941-0234
Sample Train Recovery Data
CARB Method 429
Determination of Polycyclic Aromatic Hydrocarbons (PAH) from Stationary Sources
Facility: US Eft* EKE
Date: 4
Clean-up person:.
Field Team Leader:.
Comments:
Project No.: *$"
Run No.: Cft -
Sampling Location:.
Samplers: _
T? .
Filter No.:_
Filter No.:
Front-Half Data
Filter Media: Te^too Tare Wt (mg):
Filter Media:
Tate Wt (ma):
Back-Half Data
Contents:
Final mass (g):
Initial mass (g):
Net Mass (g)
XAD-2 Sorbent Resin
Trap
XAD-2 Sorbent Resin
-=>10- 0
3<^sT
Z-C
Knock-out Impinger
MT
^.3,G
•^ob.^
0.^)
Impinger No. 3
MT
&tiA
^3-^
Cc.^
Impinger No. 4
Silica Gel
4K-C
^\1(
z?.^
Total Moisture Collected: (g):_
Description of Impinger Catch:.
-C
-------
APPENDIX D.2
CARB 429 CALCULATIONS AND COMPUTER SUMMARIES
-------
Summary of Stack Gas Parameters and Test Results
PAHs - CARB Method 429
Catalyst Inlet
Cooper Bessemer GMV-4-TF
Y
AH
Pbar
vm
Tm
"static
Ts
V,c
CO2
02
N2
CP
AP1/2
©
Dn
bhp-hr
An
Vm(std)
Vm(std)
PS
Bws
Vwstd
1-Bws
Md
Ms
vs
A
Qa
Qs
^»s(cmm)
I
RUN NUMBER
RUN DATE
RUN TIME
MEASURED DATA
Meter Box Correction Factor
Avg Meter Orifice Pressure, in. H2
Barometric Pressure, inches Hg
Sample Volume, ft3
Average Meter Temperature, °F
Stack Static Pressure, inches H2O
Average Stack Temperature, °F
Condensate Collected, ml
Carbon Dioxide content, % by volu
Oxygen content, % by volume
Nitrogen content, % by volume
Pitot Tube Coefficient
Average Square Root Ap, (in. H2O)
Sample Run Duration, minutes
Nozzle Diameter, inches
Load, bhp-hr
CALCULATED DATA
Nozzle Area, ft2
Standard Meter Volume, dscf
Standard Meter Volume, dscm
Stack Pressure, inches Hg
Moisture, % by volume
Standard Water Vapor Volume, ft3
Dry Mole Fraction
Molecular Weight (d.b.), Ib/lb-mole
Molecular Weight (w.b.), Ib/lb-mole
Stack Gas Velocity, ft/s
Stack Area, ft2
Stack Gas Volumetric flow, acfm
Stack Gas Volumetric flow, dscfm
Stack Gas Volumetric flow, dscmm
Isokinetic Sampling Ratio, %
CB-429-1-1
4/2/99
1204-1404
1.001
1.575
24.84
88.789
70.3
9.00
600
143.5
3.44
14.58
82.0
0.99
0.9240
120
0.248
377
0.000335
73.787
2.089
25.50
8.4
6.755
0.916
29.13
28.20
95.0
0.785
4,473
1,738
49.2
82.8
CB-429-1-2
4/2/99
1625-1825
1.001
1.767
24.84
93.615
71.1
9.00
616
135.8
3.00
15.40
81.6
0.99
0.9126
120
0.248
377
0.000335
77.723
2.201
25.50
7.6
6.392
0.924
29.10
28.25
94.4
0.785
4,446
1,717
48.63
88.3
CB-429-1-3
4/2/99
2000-2200
1.001
1.625
24.84
89.602
77.5
9.00
620
124.0
3.05
15.25
81.7
0.99
0.9242
120
0.248
378
0.000335
73.475
2.081
25.50
7.4
5.837
0.926
29.10
28.28
95.7
0.785
4,508
1,740
49.26
82.4
Average
1.001
1.66
24.84
90.669
73
9.00
612
134.4
3.16
15.08
81.8
0.99
0.9203
120
0.248
377
0.000335
74.995
2.124
25.50
7.8
6.328
0.922
29.11
28.24
95.0
0.785
4,476
1,732
49.04
84.5
Cooper-Bessemer GMV-4-TF
Cb429in.xls Summary
7/27/00
-------
Isokinetic Sampling Data Reduction Spreadsheet
Catalyst Inlet
Cooper Bessemer GMV-4-TF
Metered Sample Volume
Run Start
Run End
Leak Check 1 Stan
Leak Check 1 End
Leak Check 2 Stan
Leak Check 2 End
Volume Metered
CB-429-1-1
550.951
639.740
88.789
Leak Check 3 Start
Leak Check 3 End
Impinger/XAD H20
CB-429-1-1
CB-429-I-2
639.846
733.461
93.615
CB-429-I-3
734.560
824.162
89.602
Init Tare Final Net ICO Gain
41.9 42.3
496.1 584.7
36.4 63
1.7 7.2
38.1 40.4
78.7 98.8
Condensate Collected:
0.4
88.6
26.6
5.5
2.3
20.1
143.5
H2O%
8.4
CB-429-I-2
Init Tare Final
Net H2O Gain
Impinger/XAD H2O
309.6 311.7
468.2 578.4
633.4 631.2
560.8 559.7
624.4 625.8
869.4 894.8
Condensate Collected:
2.1
110.2
-2.2
-1.1
1.4
25.4
135.8
H2O% =
7.6
CB-429-I-3
Init Tare Final
Net H2O Gain
Impinger/XAD H2O
293.2 295.9
497.2 600.5
740.4 735.3
747.1 744.9
640.3 640.6
898.9 923.9
Condensate Collected:
2.7
103.3
-5.1
-2.2
0.3
25
124
H20% =
7.4
...\DataVCb429inJdt. DoMown
-------
Effluent Gas Velocity Head, (AP)
CB-429-
Pt
1
2
3
4
5
6
7
8
g
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
Average
Ap
0.85
0.85
0.85
0.85
0.85
0.85
0.85
0.80
0.80
0.85
0.85
0.85
0.85
0.85
0.85
0.85
0.80
0.80
0.90
0.90
0.90
0.90
0.90
0.90
AP1'
1-1
.-1/2
Ap
0.922
'0.922
0.922
0.922
0.922
0.922
0.922
0.894
0.894
0.922
0.922
0.922
0.922
0.922
0.922
0.922
0.894
0.894
0.949
0.949
0949
0.949
0.949
0.949
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.9240
CB-429-I-2
Pt
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
Average
Ap
0.85
0.85
0.85
0.85
0.85
0.85
0.85
0.85
0.90
0.90
0.90
0.90
0.80
0.80
0.80
0.80
0.80
0.80
0.80
080
0.80
0.80
0.80
0.80
APIJ
Ap1*
0.922
0.922
0.922
0.922
0.922
0.922
0.922
0.922
0.949
0.949
0.949
0.949
0.894
0.894
0.894
0.894
0.894
0.894
0.894
0.894
0.894
0.894
0.894
0.894
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.9126
CB-429-I-3
R
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
Average
Ap
0.85
0.85
0.85
0.85
0.85
0.85
0.85
0.90
0.90
0.85
0.85
0.85
0.85
0.85
0.85
0.85
0.85
0.85
085
0.85
085
0.85
0.85
0.85
APIJ
AP1/Z
0.922
0.922
0.922
0.922
0.922
0.922
0.922
0.949
0.949
0.922
0.922
0.922
0.922
0.922
0.922
0.922
0.922
0.922
0.922
0.922
0.922
0.922
0.922
0.922
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.9242
0.8539
0.8329
0.8541
Dry Gas Meter Orifice Differential, (AH)
CB-429-1-1
Pt
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
AvgAH
AH
1.61
1.61
1.61
1.61
1.61
1.61
1.60
1.47
1.47
1.56
1.56
1.56
1.56
1.56
1.56
1.56
1.45
1.45
1.62
1.63
1.63
1.63
1.63
1.63
1.575
CB-429-I-2
R
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
AvgAH
AH
1.61
1.61
1.61
1.61
1.61
1.61
1.61
1.61
2.01
2.01
2.01
2.01
1.79
1.79
1.79
1.79
1.79
1.79
1.79
1.79
1.79
1.79
1.79
1.79
1.767
CB-429-I-3
R
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
AvgAH
AH
1.61
1.61
1.61
1.61
1.61
1.61
1.79
1.79
1.61
1.61
1.61
1.61
1.61
1.61
1.61
1.61
1.61
1.61
1.61
1.61
1.61
1.61
1.61
1.61
1
1.625
...\DMa\CM29iiuilt. boBdown
-------
Effluent Gas Temperature, (°F)
Dry Gas Meter Temperature, (*F)
CB-429-1-1
Pt Ts
1 580
2 580
3 580
4 580
5 580
6 585
7 585
8 585
9 585
10 585
11 600
12 600
13 600
14 600
15 610
16 610
17 620
18 620
19 620
20 622
21 622
22 622
23 620
24 620
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
Avg Ts 600.5
CB-429-I-2
Pt Ts
1 615
2 615
3 615
4 620
5 620
6 615
7 615
8 615
9 620
10 620
11 620
12 615
13 615
14 615
15 615
16 615
17 615
18 615
19 615
20 615
21 615
22 615
23 615
24 615
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
Avg Ts 616.0
CB-429-I-3
Pt Ts
1 621
2 621
3 620
4 620
5 620
6 620
7 620
8 620
9 620
10 620
11 620
12 620
13 620
14 620
15 620
16 620
17 620
18 620
19 620
20 620
21 620
22 620
23 620
24 620
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
Avg Ts 620.1
CB-429-1-1
Pt Inlet Outlet
1 65 64
2 65 64
3 65 64
4 65 64
5 65 64
6 65 64
7 65 64
8 65 64
9 65 64
10 64 64
11 74 73
12 74 73
13 74 74
14 74 74
15 74 73
16 74 73
17 74 73
18 74 73
19 76 74
20 76 74
21 76 75
22 76 75
23 76 76
24 75 76
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
AvgTm 70.3
CB-429-I-2
Pt Inlet Outlet
1 70 69
2 70 69
3 70 70
4 70 71
5 71 70
6 71 71
7 72 71
8 72 72
9 71 71
10 71 70
11 72 71
12 72 71
13 72 71
14 72 71
15 71 71
16 72 71
17 72 71
18 72 71
19 71 71
20 72 71
21 72 71
22 72 71
23 72 71
24 71 71
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
AvgTm 71.1
CB-429-I-3
R Inlet Outlet
1 77 78
2 77 78
3 77 78
4 78 77
5 78 77
6 78 77
7 78 77
8 78 77
9 78 77
10 78 77
11 78 77
12 78 77
13 78 77
14 78 77
15 78 78
16 78 78
17 78 78
18 78 78
19 78 78
20 78 77
21 77 77
22 77 77
23 77 74
24 77 77
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
Avg Tm 77.5
...\Data\Cb42Sinjds. boildown
-------
Summary of Stack Gas Parameters and Test Results
PAHs - CARB Method 429
Catalyst Inlet
Cooper Bessemer GMV-4-TF
Acenaphthene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Concentration, g/bhp-hr c
Emission Rate, Ib/hour d
Acenaphthylene
Molecular Weight, g/g-mole
Target Catch, pg <
Concentration, mg/dscm a <
Concentration, ppbvd b <
Concentration, g/bhp-hr c <
Emission Rate, Ib/hour d <
Anthracene
Molecular Weight, g/g-mole
Target Catch, pg <
Concentration, mg/dscm * <
Concentration, ppbvd b <
Concentration, g/bhp-hr c <
Emission Rate, Ib/hour d <
Benzo(a)anthracene
Molecular Weight, g/g-mole
Target Catch, ug <
Concentration, mg/dscm B <
Concentration, ppbvd b <
Concentration, g/bhp-hr c <
Emission Rate, Ib/hour d
Benzo(b)fluoranthene
Molecular Weight, g/g-mole
Target Catch, ug <
Concentration, mg/dscm a <
Concentration, ppbvd b <
Concentration, g/bhp-hr c <
Emission Rate, Ib/hour d <
CB-429.M
154.21
0.759 <
3.63E-04 <
5.67E-02 <
2.85E-06 <
2.37E-06 <
154.21
0.500
2.39E-04
3.73E-02
1.87E-06
1 .56E-06
178.22
0.500 <
2.39E-04 <
3.23E-02 <
1 .87E-06 <
1 .56E-06 <
228.29
0.500 <
2.39E-04 <
2.52E-02 <
1.87E-06 <
1.56E-06 <
252.32
0.500 <
2.39E-04 <
2.28E-02 <
1.87E-06 <
1.56E-06 <
CB-429-I-2
154.21
0.500 <
2.27E-04 <
3.54E-02 <
1.76E-06 <
1 .46E-06 <
154.21
0.531 <
2.41 E-04 <
3.76E-02 <
1.87E-06 <
1.55E-06 <
178.22
0.500 <
2.27E-04 <
3.07E-02 <
1.76E-06 <
1.46E-06 <
228.29
0.500 <
2.27E-04 <
2.39E-02 <
1.76E-06 <
1.46E-06 <
252.32
0.500 <
2.27E-04 <
2.17E-02 <
1.76E-06 <
1.46E-06 <
CB-429-I-3
154.21
0.500 <
2.40E-04 <
3.75E-02 <
1.88E-06 <
1.57E-06 <
154.21
0.500 <
2.40E-04 <
3.75E-02 <
1.88E-06 <
1.57E-06 <
178.22
0.500 <
2.40E-04 <
3.24E-02 <
1 .88E-06 <
1.57E-06 <
228.29
0.500 <
2.40E-04 <
2.53E-02 <
1.88E-06 <
1.57E-06 <
252.32
0.500 <
2.40E-04 <
2.29E-02 <
1.88E-06 <
1.57E-06 <
Averaae
0.586
2.77E-04
4.32E-02
2.16E-06
1.80E-06
0.510
2.40E-04
3.75E-02
1.87E-06
1.56E-06
0.500
2.36E-04
3.18E-02
1.84E-06
1.53E-06
0.500
2.36E-04
2.48E-02
1.84E-06
1.53E-06
0.500
2.36E-04
2.25E-02
1.84E-06
1.53E-06
Cooper-Bessemer GMV-4-TF
Cb429in.xls Emissions
7/27/00
-------
Summary of Stack Gas Parameters and Test: Results
PAHs - CARB Method 429
Catalyst Inlet
Cooper Bessemer GMV-4-TF
Benzo(k)fluoranthene
Molecular Weight, g/g-mole
Target Catch, ug <
Concentration, mg/dscm a <
Concentration, ppbvd b <
Concentration, g/bhp-hr e <
Emission Rate, Ib/hour d <
3enzo(g,h,i)perylene
Molecular Weight, g/g-mole
Target Catch, ug <
Concentration, mg/dscm " <
Concentration, ppbvd b <
Concentration, g/bhp-hr c <
Emission Rate, Ib/hour d
Benzo(a)pyrene
Molecular Weight, g/g-mote
Target Catch, ug <
Concentration, mg/dscm a <
Concentration, ppbvd b <
Concentration, g/bhp-hr c <
Emission Rate, Ib/hour d <
Benzo(e)pyrene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm *
Concentration, ppbvd b
Concentration, g/bhp-hr c
Emission Rate, Ib/hour d
Chrysene
Molecular Weight, g/g-mole
Target Catch, ug <
Concentration, mg/dscm * <
Concentration, ppbvd b <
Concentration, g/bhp-hr c <
Emission Rate, Ib/hour d
CB-429-1-1
252.32
0.500 <
2.39E-04 <
2.28E-02 <
1.B7E-06 <
1.56E-06 <
276.34
1.000 <
4.79E-04 <
4.17E-02 <
3.75E-06 <
3.12E-06 <
252.30
0.500 <
2.39E-04 <
2.28E-02 <
1.87E-06 <
1.56E-06 <
252.30
228.28
0.500 <
2.39E-04 <
2.52E-02 <
1.87E-06 <
1.56E-06 <
CB-429-1-2
252.32
0.500
2.27E-04
2.17E-02
1.76E-06
1.46E-06
276.34
1.000
4.54E-04
3.95E-02
3.52E-06
2.92E-06
252.30
0.500
2.27E-04
2.17E-02
1 .76E-06
1.46E-06
252.30
228.28
0.500
2.27E-04
2.39E-02
1.76E-06
1.46E-06
CE1-429-I-3
252.32
< 0.500 <
< :>.40E-04 <
< :>.29E-02 <
< 1.88E-06 <
< 1.57E-06 <
276.34
< 1.000 <
< 4.81 E-04 <
< 4.18E-02 <
< 3.76E-06 <
< 3.13E-06 <
252.30
< 0.500 <
< 2.40E-04 <
< 2.29E-02 <
< 1.88E-06 <
< 1.57E-06 <
252.30
228.28
< 0.500 <
< 2.40E-04 <
< 2.53E-02 <
< 1.88E-06 <
< 1.57E-06 <
Average
0.500
2.36E-04
2.25E-02
1.84E-06
1.53E-06
1.000
4.71 E-04
4.10E-02
3.67E-06
3.06E-06
0.500
2.36E-04
2.25E-02
1 .84E-06
1.53E-06
ND
ND
ND
ND
ND
0.500
2.36E-04
2.48E-02
1 .84E-06
1.53E-06
Cooper-Bessemer GMV-4-TF
Cb429in.xls Emissions
7/27/00
-------
Summary of Stack Gas Parameters and Test Results
PAHs - CARB Method 429
Catalyst Inlet
Cooper Bessemer GMV-4-TF
Dibenz(a,h)anthracene
Molecular Weight, g/g-mole
Target Catch, yg <
Concentration, mg/dscm " <
Concentration, ppbvd b <
Concentration, g/bhp-hr c <
Emission Rate, Ib/hour d <
Fluoranthene
Molecular Weight, g/g-mole
Target Catch, ug <
Concentration, mg/dscm a <
Concentration, ppbvd b <
Concentration, g/bhp-hr c <
Emission Rate, Ib/hour d <
Fluorene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm "
Concentration, ppbvd b
Concentration, g/bhp-hr c
Emission Rate, Ib/hour d
lndeno(1 ,2,3-cd)py rene
Molecular Weight, g/g-mole
Target Catch, ug <
Concentration, mg/dscm a <
Concentration, ppbvd b <
Concentration, g/bhp-hr c <
Emission Rate, Ib/hour d <
2-Methy I naphthalene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm *
Concentration, ppbvd b
Concentration, g/bhp-hr c
Emission Rate, Ib/hour d
CB-429-1-1
278.33
1.000 <
4.79E-04 <
4.14E-02 <
3.75E-06 <
3.12E-06 <
202.26
0.500 <
2.39E-04 <
2.85E-02 <
1 .87E-06 <
1.56E-06 <
166.21
1.26 <
6.03E-04 <
8.73E-02 <
4.73E-06 <
3.93E-06 <
290.34
1.000 <
4.79E-04 <
3.97E-02 <
3.75E-06 <
3.12E-06 <
142.20
CB-429-1-2
278.33
1.000 <
4.54E-04 <
3.93E-02 <
3.52E-06 <
2.92E-06 <
202.26
0.500 <
2.27E-04 <
2.70E-02 <
1.76E-06 <
1.46E-06 <
166.21
0.500 <
2.27E-04 <
3.29E-02 <
1.76E-06 <
1.46E-06 <
290.34
1.000 <
4.54E-04 <
3.76E-02 <
3.52E-06 <
2.92E-06 <
142.20
CB-429-I-3
278.33
1.000 <
4.81 E-04 <
4.15E-02 <
3.76E-06 <
3.13E-06 <
202.26
0.500 <
2.40E-04 <
2.86E-02 <
1.88E-06 <
1.57E-06 <
166.21
0.500 <
2.40E-04 <
3.48E-02 <
1.88E-06 <
1.57E-06 <
290.34
1.000 <
4.81 E-04 <
3.98E-02 <
3.76E-06 <
3.13E-06 <
142.20
Average
1.000
4.71 E-04
4.07E-02
3.67E-06
3.06E-06
0.500
2.36E-04
2.80E-02
1.84E-06
1.53E-06
0.754
3.57E-04
5.17E-02
2.79E-06
2.32E-06
1.000
4.71 E-04
3.90E-02
3.67E-06
3.06E-06
ND
ND
ND
ND
ND
Cooper-Bessemer GMV-4-TF
Cb429in.xls Emissions
7/27/00
-------
Summary of Stack Gas Parameters and Test Results
PAHs - CARB Method 429
Catalyst Inlet
Cooper Bessemer GMV-4-TF
Naphthalene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Concentration, g/bhp-hr c
Emission Rate, to/hour d
3erylene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Concentration, g/bhp-hr c
Emission Rate, Ib/hour d
Phenanthrene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm *
Concentration, ppbvd b
Concentration, g/bhp-hr °
Emission Rate, Ib/hour d
Pyrene
Molecular Weight, g/g-mole
Target Catch, ug <
Concentration, mg/dscm a <
Concentration, ppbvd b <
Concentration, g/bhp-hr c <
Emission Rate, Ib/hour d <
CB-429-1-1
128.16
17.2
8.21 E-03
1.54E+00
6.43E-05
5.35E-05
252.30
178.22
1.59
7.62E-04
1.03E-01
5.97E-06
4.96E-06
202.24
0.500
2.39E-04
2.85E-02
1.87E-06
1.56E-06
CB-429-I-2
128.16
10.9
4.97E-03
9.32E-01
3.85E-05
3.20E-05
252.30
178.22
1.32
6.01 E-04
8.11E-02
4.65E-06
3.87E-06
202.24
< 0.500
< 2.27E-04
< 2.70E-02
< 1.76E-06
< 1.46E-06
CB-429-1-3
128.16
11.2
J3.40E-03
1.01E+00
4.22E-05
:j.52E-05
252.30
178.22
0.870
4.18E-04
5.64E-02
3.27E-06
2.72E-06
202.24
< 0.500 <
< 2.40E-04 <
< 2.86E-02 <
< 188E-06 <
< 1.57E-06 <
Average
13.1
6.19E-03
1.16E+00
4.83E-05
4.Q2E-05
ND
ND
ND
ND
ND
1.26
5.94E-04
8.01 E-02
4.63E-06
3.85E-06
0.500
2.36E-04
2.80E-02
1.84E-06
1.53E-06
Milligrams per dry standard cubic meter at 68* F (20* C) and 1 aim.
b Parts per billion by volume.
0 Grams per brake horsepower hour.
Pounds per hour.
NO Not Detected. Results are less than analyte detection limit. DL used in calculation of average.
Cooper-Bessemer GMV-4-TF
Cb429in.xls Emissions
7/27/00
-------
Summary of Stack Gas Parameters and Test Results
PAHs-CARB Method 429
Oxidizer Outlet
Cooper Bessemer GMV-4-TF
RUN NUMBER CB-429-O-1 CB-429-O-2 CB-429-O-3
RUN DATE 4/2/99 4/2/99 4/2/99
RUNTIME 1204-1404 1625-1825 2000-2200
Y
AH
Pbar
vm
Tm
'static
Ts
V,c
CO2
02
N2
CP
AP1*
©
Dn
bhp-hr
An
"m(std)
Vm(std)
PS
BWS
Vwstd
1-Bws
Md
Ms
Vs
A
Qa
Qs
Qs(cmm)
I
MEASURED DATA
Meter Box Correction Factor
Avg Meter Orifice Pressure, in. H20
Barometric Pressure, inches Hg
Sample Volume, ft3
Average Meter Temperature, °F
Stack Static Pressure, inches H2O
Average Stack Temperature, "F
Condensate Collected, ml
Carbon Dioxide content, % by volum
Oxygen content, % by volume
Nitrogen content, % by volume
Pitot Tube Coefficient
Average Square Root Ap, (in. H2O)1/
Sample Run Duration, minutes
Nozzle Diameter, inches
Load, bhp-hr
CALCULATED DATA
Nozzle Area, ft2
Standard Meter Volume, dscf
Standard Meter Volume, dscm
Stack Pressure, inches Hg
Moisture, % by volume
Standard Water Vapor Volume, ft3
Dry Mole Fraction
Molecular Weight (d.b.), Ib/lb-mole
Molecular Weight (w.b.), Ib/lb-mole
Stack Gas Velocity, ft/s
Stack Area, ft2
Stack Gas Volumetric flow, acfm
Stack Gas Volumetric flow, dscfm
Stack Gas Volumetric flow, dscmm
Isokinetic Sampling Ratio, %
1.015
1.901
24.84
94.600
73.1
7.00
586
148.5
3.35
14.73
81.9
0.99
0.9173
120
0.257
377
0.000360
79.366
2.247
25.35
8.1
6.990
0.919
29.13
28.22
93.8
0.785
4,420
1,737
49.2
83.0
1.015
1.891
24.84
101.214
72.6
7.00
582
151.5
2.92
15.50
81.6
0.99
0.9195
120
0.257
377
0.000360
84.998
2.407
25.35
7.7
7.131
0.923
29.09
28.23
93.9
0.785
4,422
1,752
49.60
88.1
1.015
1.923
24.84
98.052
80.1
7.00
582
137.5
3.00
15.40
81.6
0.99
0.9275
120
0.257
378
0.000360
81.198
2.299
25.35
7.4
6.472
0.926
29.10
28.28
94.6
0.785
4,457
1,772
50.19
83.2
Average
1.015
1.905
24.84
97.955
75.3
7.00
583
145.8
3.1
15.2
81.7
0.99
0.9214
120
0.257
377
0.000360
81.854
2.318
25.35
7.7
6.864
0.923
29.10
28.24
94.1
0.785
4,433
1,754
49.66
84.8
Cooper-Bessemer GM V-4-TF
Cb429outxte Summary
7/27/00
-------
Isokinetic Sampling Data Reduction Spreadsheet
Oxidizer Outlet
Cooper Bessemer GMV-4-TF
Metered Sample Volume
Run Start
Run End
Leak Check 1 Start
Leak Check 1 End
Leak Check 2 Start
Leak Check 2 End
Volume Metered
Leak Check 3 Start
Leak Check 3 End
Impinger/XAD H2O
CB-429-0-1
87.150
181.750
94.600
CB-429-O-1
CB-429-O-2
181.986
283.200
, 101.214
CB-429-0-3
283.500
381.552
98.052
Init Tare Final Net H2O Gain
281.6 283.7
476.8 604.5
611.6 611.3
707.4 707.2
541.5 541.8
894.3 913.2
Condensate Colle
2.1
127.7
-0.3
-0.2
0.3
18.9
148.5
H20% =
8.1
CB-429-0-2
Init Tare
Final
Net H2O Gain
Impinger/XAD H2O
306.9
458.3
734.4
729.7
645.3
920.9
308.3
587.4
734.6
729.6
646.4
940.7
Condensate Colle
1.4
129.1
0.2
-0.1
1 1
19.8
151.5
H2O% =
7.7
CB-429-O-3
Init Tare
Final
Net H2O Gain
Impinger/XAD H2O
307.5 310
478 595.5
617.7 616.2
706.5 703.8
543.2 542.4
913.1 935.6
Condensate Collected:
2.5
117.5
-1.5
-2.7
-0.8
22.5
137.5
H2O%
7.4
\DaU\Cb429out xts, boiktawn
-------
Effluent Gas Velocity Head, (AP)
Dry Gas Meter Orifice Differential, ( Effluent Gas Temperature,
CB-429-O-1
Pt Ap Ap1/2
1 0.85 0.922
2 0.85 0.922
3 0.85 0.922
4 0.85 0.922
5 0.85 0.922
6 0.85 0.922
7 0.85 0.922
8 0.85 0.922
9 0.80 0.894
10 0.80 0.894
11 0.80 0.894
12 0.80 0.894
13 0.80 0.894
14 0.80 0.894
15 0.80 0.894
16 0.90 0.949
17 0.90 0.949
18 0.90 0.949
19 0.85 0.922
20 0.85 0.922
21 0.85 0.922
22 0.85 0.922
23 0.85 0.922
24 0.85 0.922
25 0 000
26 0.000
27 0.000
28 0.000
29 0.000
30 0.000
31 0.000
32 0.000
33 0.000
34 0.000
35 0.000
36 0.000
37 0.000
38 0.000
39 0.000
40 0.000
41 0.000
42 0.000
43 0.000
44 0.000
45 0.000
46 0.000
47 0.000
48 0.000
49 0.000
50 0.000
Average AP1' 0.9173
0.8414
CB-429-O-2
Ap AP10
0.85 0.922
0.85 0.922
0.85 0.922
0.90 0.949
0.90 0.949
0.90 0.949
0.90 0.949
0.90 0.949
0.80 0.894
0.80 0.894
0.80 0.894
0.80 0.894
0.85 0.922
0.85 0.922
0.85 0.922
0.85 0.922
0.85 0.922
0.85 0.922
0.85 0.922
0.85 0.922
0.85 0.922
0.80 0.894
0.80 0.894
0.80 0.894
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.9195
0.8455
CB-429-0-3 CB-429-0-1 CB-429-O-2 29-O-3
Ap Ap10
0.85 0.922
0.85 0.922
0.85 0.922
0.85 0.922
0.85 0.922
0.85 0.922
0.90 0.949
0.90 0.949
0.90 0.949
0.90 0.949
0.90 0.949
0.85 0.922
0.85 0.922
0.85 0.922
0.85 0.922
0.85 0.922
0.85 0.922
0.85 0.922
0.85 0.922
0.85 0.922
0.85 0 922
0.85 0.922
0.85 0 922
0.85 0.922
0000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.9275
R AH AH AH
1 1.86
2 1.83
3 1.83
4 2.03
5 2.03
6 2.03
7 2.03
8 2.03
9 1.79
10 1.79
11 1.79
12 1.79
13 1.79
14 1.79
15 1.79
16 2.01
17 2.01
18 2.01
19 1.90
20 1.90
21 1.90
22 1.90
23 1.90
24 1.90
1.90
1.90
1.90
2.01
2.01
2.01
2.01
2.01
1.79
1.79
1.79
1.79
1.90
1.90
1.90
1.90
1.90
1.90
1.90
1.90
1.90
1.79
179
1 79
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
AvgAH 1.901
1.891
1.90
1.90
1.90
1.90
1.90
1.90
2.01
2.01
2.01
2.01
2.01
1.90
1.90
1.90
1.90
1.90
1.90
1.90
1.90
1.90
1.90
1.90
1.90
1.90
1.923
CB-429-OX3B-429-O-2 29-O-3
Pt Ts Ts Ts
1 580
2 580
3 580
4 580
5 580
6 580
7 585
8 585
9 585
10 585
11 585
12 585
13 585
14 585
15 590
16 590
17 590
18 590
19 590
20 590
21 590
22 590
23 590
24 590
575
575
575
580
580
580
585
585
585
580
580
580
580
582
582
581
582
580
585
585
585
585
585
585
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
Avg Ts 585.8
581.5
580
580
580
582
584
584
584
582
582
582
582
582
582
582
582
581
581
581
581
581
581
581
581
581
5816
0.8603
. \Data\CM29ouLxlt, boildown
-------
Dry Gas Meter Temperature, f/9
Pt
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
AvgT
CB-429-O-1
Inlet
71
71
71
71
72
72
71
71
74
74
74
74
74
74
74
75
75
75
75
75
75
75
75
75
m
Outlet
69
71
71
71
71
71
71
71
73
73
73
73
73
73
73
74
74
74
74
75
75
75
74
74
CB-429-0-2 CB-429-O-3
Inlet
74
74
74
74
74
74
74
74
74
74
74
74
73
72
71
72
71
71
72
72
72
72
72
71
73.1
Outlet Inlet
73
73
73
73
73
73
73
72
73
74
73
74
73
72
71
71
71
70
71
72
72
72
71
71
80
80
80
80
80
80
80
80
80
80
80
80
80
81
81
81
81
81
81
81
81
81
78
78
72.6
Outlet
80
80
80
80
80
80
80
81
80
81
80
81
80
80
80
80
80
80
80
80
81
80
79
78
80.1
.. lDatMCb429out xls, boMown
-------
Summary of Stack Gas Parameters and Test Results
PAHs - GARB Method 429
Oxidizer Outlet
Cooper Bessemer GMV-4-TF
CB-429-O-1 CB-429-O-2 CB-429-O-3
Acenaphthene
Molecular Weight, g/g-mole
Target Catch, ug <
Concentration, mg/dscm a <
Concentration, ppbvd b <
Emission Rate g/bhp-hr c <
Emission Rate, Ib/hour d <
Acenaphthylene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm "
Concentration, ppbvd b
Emission Rate g/bhp-hr c ,
Emission Rate, Ib/hour d
Anthracene
Molecular Weight, g/g-mole
Target Catch, ug <
Concentration, mg/dscm a <
Concentration, ppbvd b <
Emission Rate g/bhp-hr ° <
Emission Rate, Ib/hour d <
Benzo(a)anthracene
Molecular Weight, g/g-mole
Target Catch, ug <
Concentration, mg/dscm " <
Concentration, ppbvd b <
Emission Rate g/bhp-hr c <
Emission Rate, Ib/hour d <
Benzo(b)fluoranthene
Molecular Weight, g/g-mole
Target Catch, ug <
Concentration, mg/dscm a <
Concentration, ppbvd b <
Emission Rate g/bhp-hr c <
Emission Rate, Ib/hour d <
154.21
0.500 <
2.22E-04 <
3.47E-02 <
1.74E-06 <
1.45E-06 <
154.21
0.614
2.73E-04
4.26E-02
2.14E-06
1.78E-06
178.22
0.500 <
2.22E-04 <
3.00E-02 <
1.74E-06 <
1.45E-06 <
228.29
0.500 <
2.22E-04 <
2.34E-02 <
1.74E-06 <
1.45E-06 <
252.32
0.500 <
2.22E-04 <
2.12E-02 <
1.74E-06 <
1.45E-06 <
154.21
0.500 <
2.08E-04 <
3.24E-02 <
1.64E-06 <
1.36E-06 <
154.21
0.500
'2.08E-04
3.24E-02
1.64E-06
1.36E-06
178.22
0.500 <
2.08E-04 <
2.80E-02 <
1 .64E-06 <
1.36E-06 <
228.29
0.500 <
2.08E-04 <
2.19E-02 <
1.64E-06 <
1.36E-06 <
252.32
0.500 <
2.08E-04 <
1.98E-02 <
1.64E-06 <
1.36E-06 <
154.21
0.500 <
2.17E-04 <
3.39E-02 <
1.73E-06 <
1 .44E-06 <
154.21
0.512
2.23E-04
3.47E-02
1.77E-06
1.48E-06
178.22
0.500 <
2.17E-04 <
2.93E-02 <
1.73E-06 <
1 .44E-06 <
228.29
0.500 <
2.17E-04 <
2.29E-02 <
1.73E-06 <
1.44E-06 <
252.32
0.500 <
2.17E-04 <
2.07E-02 <
1.73E-06 <
1.44E-06 <
Averaae
0.500
2.16E-04
3.37E-02
1.70E-06
1.42E-06
0.542
2.35E-04
3.66E-02
1.85E-06
1.54E-06
0.500
2.16E-04
2.91 E-02
1.70E-06
1.42E-06
0.500
2.16E-04
2.27E-02
1.70E-06
1.42E-06
0.500
2.16E-04
2.06E-02
1.70E-06
1.42E-06
Cooper-Bessemer GMV-4-TF
Cb429out.xls Emissions
7/27/00
-------
Summary of Stack Gas Parameters and Test Results
PAHs - CARB Method 429
Oxidizer Outlet
Cooper Bessemer GMV-4-TF
CB-429-0-1 CB-429-0-2 CB-429-O-3
Benzo(k)fluoranthene
Molecular Weight, g/g-mole
Target Catch, ug <
Concentration, mg/dscm " <
Concentration, ppbvd b <
Emission Rate g/bhp-hr c <
Emission Rate, Ib/hour d <
Benzo(g,h,i)perylene
Molecular Weight, g/g-mole
Target Catch, ug <
Concentration, mg/dscm " <
Concentration, ppbvd b <
Emission Rate g/bhp-hr c <
Emission Rate, Ib/hour d <
Benzo(a)pyrene
Molecular Weight, g/g-mote
Target Catch, ug <
Concentration, mg/dscm " <
Concentration, ppbvd b <
Emission Rate g/bhp-hr c <
Emission Rate, Ib/hour " <
Benzo(e)pyrene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm *
Concentration, ppbvd b
Emission Rate g/bhp-hr c
Emission Rate, Ib/hour *
Chrysene
Molecular Weight, g/g-mole
Target Catch, ug <
Concentration, mg/dscm * <
Concentration, ppbvd b <
Emission Rate g/bhp-hr c <
Emission Rate, Ib/hour d <
252.32
0.500 <
2.22E-04 <
2.12E-02 <
1.74E-06 <
1.45E-06 <
276.34
1.000 <
445E-04 <
3.87E-02 <
3.48E-06 <
2.90E-06 <
252.30
0.500 <
2.22E-04 <
2.12E-02 <
1.74E-06 <
1.45E-06 <
252.30
228.28
0.500 <
2.22E-04 <
2.34E-02 <
1.74E-06 <
1.45E-06 <
252.32
0.500 <
2.08E-04 <
1.98E-02 <
1.64E-06 <
1.36E-06 <
276.34
1.000 <
4.15E-04 <
3.62E-02 <
3.28E-06 <
2.73E-06 <
252.30
0.500 <
2.08E-04 <
1.98E-02 <
1.64E-06 <
1.36E-06 <
252.30
228.28
0.500 <
2.08E-04 <
2.19E-02 <
1.64E-06 <
1.36E-06 <
252.32
0.500 <
2.17E-04 <
2.07E-02 <
1.73E-06 <
I.44E-06 <
276.34
1.000 <
4.35E-04 <
3.79E-02 <
3.46E-06 <
2.89E-06 <
252.30
0.500 <
2.17E-04 <
2.07E-02 <
1.73E-06 <
1 .44E-06 <
252.30
228.28
0.500 <
2.17E-04 <
2.29E-02 <
1.73E-06 <
1.44E-06 <
Average
0.500
2.16E-04
2.06E-02
1.70E-06
1.42E-06
1.000
4.32E-04
3.76E-02
3.41 E-06
2.84E-06
0.500
2.16E-04
2.06E-02
1.70E-06
1.42E-06
ND
ND
ND
ND
ND
0.500
2.16E-04
2.27E-02
1.70E-06
1.42E-06
Cooper-Bessemer GMV-4-TF
Cb429out.xls Emissions
7/27/00
-------
Summary of Stack Gas Parameters and Test Results
PAHs - CARB Method 429
Oxidizer Outlet
Cooper Bessemer GMV-4-TF
CB-429-O-1 CB-429-O-2 CB-429-Q-3
Dibenz(a,h)anthracene
Molecular Weight, g/g-mole
Target Catch, ug <
Concentration, mg/dscm a <
Concentration, ppbvd b <
Emission Rate g/bhp-hr c <
Emission Rate, Ib/hour d <
Fluoranthene
Molecular Weight, g/g-mole
Target Catch, ug <
Concentration, mg/dscm a <
Concentration, ppbvd b <
Emission Rate g/bhp-hr c <
Emission Rate, Ib/hour d
Fluorene
Molecular Weight, g/g-mole
Target Catch, ug <
Concentration, mg/dscm 8 <
Concentration, ppbvd b <
Emission Rate g/bhp-hr c <
Emission Rate, Ib/hour d <
lndeno(1 ,2,3-cd)py rene
Molecular Weight, g/g-mole
Target Catch, ug <
Concentration, mg/dscm " <
Concentration, ppbvd b <
Emission Rate g/bhp-hr c <
Emission Rate, Ib/hour d <
2-Methylnaphthalene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm *
Concentration, ppbvd b
Emission Rate g/bhp-hr c
Emission Rate, Ib/hour d
278.33
1.000 <
4.45E-04 <
3.85E-02 <
3.48E-06 <
2.90E-06 <
202.26
0.500 <
2.22E-04 <
2.65E-02 <
1.74E-06 <
1.45E-06 <
166.21
0.500 <
2.22E-04 <
3.22E-02 <
1.74E-06 <
1.45E-06 <
290.34
1.000 <
4.45E-04 <
3.69E-02 <
3.48E-06 <
2.90E-06 <
142.20
278.33
1.000 <
4.15E-04 <
3.59E-02 <
3.28E-06 <
2.73E-06 <
202.26
0.500 <
2.08E-04 <
2.47E-02 <
1.64E-06 <
1 .36E-06 <
166.21
0.500 <
2.08E-04 <
3.01 E-02 <
1.64E-06 <
1.36E-06 <
290.34
1.000 <
4.15E-04 <
3.44E-02 <
3.28E-06 <
2.73E-06 <
142.20
278.33
1.000 <
4.35E-04 <
3.76E-02 <
3.46E-06 <
2.89E-06 <
202.26
0.500 <
2.17E-04 <
2.59E-02 <
1.73E-06 <
1.44E-06 <
166.21
0.500 <
2.17E-04 <
3.15E-02 <
1.73E-06 <
1.44E-06 <
290.34
1.000 <
4.35E-04 <
3.60E-02 <
3.46E-06 <
2.89E-06 <
142.20
Averaae
1.000
4.32E-04
3.73E-02
3.41 E-06
2.84E-06
0.500
2.16E-04
2.57E-02
1.70E-06
1.42E-06
0.500
2.16E-04
3.12E-02
1.70E-06
1.42E-06
1.000
4.32E-04
3.58E-02
3.41 E-06
2.84E-06
ND
ND
ND
ND
ND
Cooper-Bessemer GMV-4-TF
Cb429out.xls Emissions
7/27/00
-------
Summary of Stack Gas Parameters and Test Results
PAHs - CARB Method 429
Oxidizer Outlet
Cooper Bessemer GMV-4-TF
CB-429-O-1 CB-429-O-2 CB-129-O-3
Naphthalene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate g/bhp-hr c
Emission Rate, Ib/hour d
Perylene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm "
Concentration, ppbvd b
Emission Rate g/bhp-hr c
Emission Rate, Ib/hour d
Phenanthrene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm B
Concentration, ppbvd b
Emission Rate g/bhp-hr c
Emission Rate, Ib/hour d
Pyrene
Molecular Weight, g/g-mole
Target Catch, ug <
Concentration, mg/dscm * <
Concentration, ppbvd b <
Emission Rate g/bhp-hr c <
Emission Rate, Ib/hour d <
128.16
8.802
3.92E-03
7.35E-01
3.07E-05
2.55E-05
252.30
178.22
0.792
3.52E-04
4.76E-02
2.76E-06
2.29E-06
202.24
0.500 <
2.22E-04 <
2.65E-02 <
1.74E-06 <
1.45E-06 <
128.16
8.056
3.35E-03
6.28E-01
2.64E-05
2.20E-05
252.30
178.22
0.547
2.27E-04
3.07E-02
1.79E-06
1 .49E-06
202.24
0.500 <
2.08E-04 <
2.47E-02 <
1.64E-06 <
1.36E-06 <
128.16
8.069
3.51 E-03
6.59E-01
2.80E-05
2.33E-05
252.30
178.22
0.570
2.48E-04
3.35E-02
1 .97E-06
1 .65E-06
202.24
0.500 <
217E-04 <
2.59E-02 <
1 .73E-06 <
1 .44E-06 <
Average
8.309
3.59E-03
6.74E-01
2.83E-05
2.36E-05
ND
ND
ND
ND
ND
0.636
2.76E-04
3.72E-02
2.18E-06
1.81E-06
0.500
2.16E-04
2.57E-02
1.70E-06
1.42E-06
8 Milligrams per dry standard cubic meter at 68* F (20* C) and 1 atm.
Parts per billion by volume.
c Grams per brake horsepower hour.
d Pounds per hour.
ND Not Detectable - Resutts are betow target analyte detection limit. Values are counted as zero.
Cooper-Bessemer GMV-4-TF
Cb429out.xls Emissions
7/27/00
-------
APPENDIX D.3
CARB 429 CALIBRATION DATA
-------
TEMPERATURE SENSOR CALIBRATION FORM
Temperature Sensor No.
Ambient Temp. °F
Sensor Type \? -Tc. Length
Reference Temp. Sensor:
Barometric Pressure, "Hg ~3 c.-c v
Date
i-ti'^B
.1
••
Ref.
Point
No.
1
2
3
1
2
3
1
2
3
1
2
3
1
2
3
1
2
3
Temp.
Source
I-U ^
KAA \^ A
nr\ t J •
HT.O,
Temp. °F
Ref.
Sensor
-Vt
-72.
-L\ o
Test
Sensor
-st
^
tvi
Temp.
Diff. %
o
-.c*
.ov-S
Within
Limits
Y/N
X
r
r
Calibrated
By
\U>>>
V^
xu"^
% Tenp. Diff
. Temp •*• 460) - ( Test Temp. * 46u) x 10Q
'. Tenip. + 460)
-------
TEMPERATURE SENSOR CALIBRATION FORM
Temperature Sensor No. RT -
Ambient Temp. °F ~i\
Reference Temp. Sensor: ____H
Sensor Type VL-TC Length
Barometric Pressure, "Hg
Date
,0-W
Ref.
Point
No.
1
2
3
1
2
3
1
2
3
1
2
3
1
2
3
1
2
3
Temp.
Source
**£»
*£*r
*t£o
Temp. °F
Ref.
Sensor
•5.2
-70
5MO
Test
Sensor
•53
-*>
*IO
Temp.
Diff. %
.-30>
o
O
Within
limits
Y/N
vy
>
>
Calibrated
By
^^Sk
^S^W
\rt^
'
% Temp. Diff
<***'
40) " ( Teat
460)
(Ref. Temp. * 460)
x 100 * 1.5 %
-------
TEMPERATURE SENSOR CALIBRATION FORM
jj' t
Temperature Sensor No. DG.M - \ P Sensor Type K-TC Length '
Ambient Temp. °F _ "7^- _ Barometric Pressure, "Hg "So.
Reference Temp. Sensor:
Date
-Ifc-^fc'
c,
«•'
Ref.
Point
No.
1
2
3
1
2
3
1
2
3
1
2
3
1
2
3
1
2
3
Temp.
Source
ilo
M£'
?£o
Temp. °F
Ref.
Sensor
33
7*r
7.0*
Test
Sensor
SS*
1*r
-L\ O
Temp.
Diff. %
.40<-
o
.111
Within
Limits
Y/N
1
V
x
Calibrated
By
X^
\iS
)i^
% Temp. Diff = (R*fm Temp * 4!0) " ( Tegt Tfng?' *
(J?ef. Teinp. + 460)
460)
x 10Q
-------
TEMPERATURE SENSOR CALIBRATION FORM
Temperature Sensor No.
Ambient Temp. °F
, _ ,
Sensor Type IK - ic • Length
_ Barometric Pressure, "Hg
Reference Temp. Sensor.
Date
MM*
/.
• •
Ref.
Point
No.
1
2
3
1
2
3
1
2
3
1
2
3
1
2
3
1
2
3
Temp.
Source
ICc.
R£
%lo
Temp. °F
Ref.
Sensor
53
•7-t .
^o•6
Test
Sensor
3.3
T<
•ton
•
Temp*
DifT. %
o
. IB7
o
Within
Y/N
V
Y
1
Calibrated
By
?\l^
y^
kuj%
^
j
% Temp. Diff
*^
<***' Teaip + 40) "
TTeap.
-------
TEMPERATURE SENSOR CALIBRATION FORM
Temperature Sensor No. I\A\»>>
Ambient Temp. °F
Sensor Type <- ( ^ Length _1
Barometric Pressure, "Hg ?**. c./
Reference Temp. Sensor:
J
Date
^-^
<•
"
Ref.
Point
No.
1
2
3
1
2
3
1
2
3
1
2
3
1
2
3
1
2
3
Temp.
Source
ivl
*a?i§
^
,
Temp. °F
Ref.
Sensor
Vi
IG
•u><-
Test
Sensor
3^-
76
^>5-
-
Temp.
Diff. %
-•
o
Within
Limits
Y/N
Calibrated
By
Tenp. Diff
*^
<***'
460)
-------
TEMPERATURE SENSOR CALIBRATION FORM
Temperature Sens
Ambient Temp. °
Reference Temp.
Date
Vlo-TV
'•
"
Ref.
Point
No.
1
2
3
1
2
3
1
2
3
1
2
3
1
2
3
1
2
3
•or No. ^-10 Sensor Tyne fc>7c_ Length I'2'
F 7 C. Ba
Sensnr:
rometric Pressure, "H
g •Z.^.G,/ "
Temp.
Source •
(Ct£
£T*'
Kit
Temp. °F
Ref.
Sensor
3>i-
1<*
*U><-
Test
Sensor
3^-
17
7^>^
Temp.
Diff. %
' '.<+(*.
./*
-------
TEMPERATURE SENSOR CALIBRATION FORM
Temperature Sensor No.
Ambient Temp. °F t
Sensor Type K- -TC, Length
Barometric Pressure, "Hg
Reference Temp. Sensor:
Date
f(- j . qj?
//-«?-? S
/K3-tf
Ref.
Point
No.
1
2
3
1
2
3
1
2
3
1
2
3
1
2
3
1
2
3
Temp.
Source
rcfe
/.
A,'f
fi*»'l
M*o
Temp. °F
Ref.
Sensor
3^
~7Cc
,s?02
Test
Sensor
3^
7&
-50^
Temp.
Diff. %
o
C5
O
Within
Limits
Y/N
Y
Y
Y
Calibrated
By
rv^A
•\>>^M
T^hM
% Temp. Diff
. remp + 460) - ( Test Temp
460)
(Ref. Temp. + 460)
x 100
-------
TEMPERATURE SENSOR CALIBRATION FORM
Temperature Sensor No. ^M-
Ambient Temp. °F "?i
Sensor Type
-7~c
Length
K
Barometric Pressure, "Hg
Reference Temp. Sensor:
•*.(=•
Date
/A*?-f*
ft-3'iy
a ^-5$
Ref.
Point
No.
1
2
3
1
2
3
1
2
3
1
2
3
1
2
3
1
2
3
Temp.
Source
/VJO
>%£•
***>
Temp. °F
Ref.
Sensor
•S.5
"71
-50 7
Test
Sensor
^
7/
J>0-7
Temp.
Diff. %
,'joS
0
o
I
Within
Limits
Y/N
V
Y
y
Calibrated
By
?SNvV
b^M
•^^^4
-------
TEMPERATURE SENSOR CALIBRATION FORM
Temperature Sensor No.
Ambient Temp. °F
Reference Temp. Sensor:
T2.
Sensor Type
- T c.
Length s
- .
Barometric Pressure, "Hg "Z.q.s
Date
,-S *X
n
n
Ref.
Point
No.
1
2
3
1
2
3
1
2
3
1
2
3
1
2
3
1
2
3
Temp.
Source
IC«£
Mrt-
\\1-V
Temp. °F
Ref.
Sensor
bT-
L-\T,
-Z.I O
Test
Sensor
"bz
It-
*T-\ O
Temp.
Diff. %
o
o
o
Within
Limits
Y/N
1
N
N
Calibrated
By
v$>
N^
^\>
\J
-
% Temp. Diff
(Ref'
" ( Te8t
' * 460)
(Ref. Temp. •»• 460)
x 100 * 1.5 %
-------
TEMPERATURE SENSOR CALIBRATION FORM
Temperature Sensor No.
Ambient Temp. °F
Sensor Type
Length
Reference Temp. Sensor:
Barometric Pressure, "Hg
Date
\ -Zi^V
tt
t 1
•
Ref.
Point
No.
1
2
3
1
2
3
1
2
3
1
2
3
1
2
3
1
2
3
Temp.
Source
tCii
H*-°
kt*&.
«TN fU
^,C,VCJ
Hz_e>
Temp. °F
Ref.
Sensor
•^-^
"IT.
1. 10
Test
Sensor
I>T-
(^
•^.\ o
Temp.
Diff. %
o
- .G-S"
-------
9/30/94: CD2b-1
CAUBRATION DATA SHEET 2b
Verification of Standard Phot Tube Design Specifications
Shape of tip » (/) Hemispherical / Ellipsoidal Conical
Size of static pressure holes » about 0.1 DJ
Static pressure holes equally spaced in a piezometer ring configuration?
Tube diameter (Dt) » . 31 inch
Junction « 30° 90*?
Distance A (DA) « 5"" inch DA/Dt «
Distance B (Dt) « J%? inch
Yes
Yes
No.
No
Yes X No
Yes »^No
Yes • No
bnpMi opening •
Inner «ut» only N.
Completeness
legbHty
Accuracy
Specifications.
Reasonableness
Ctrtfficition
I certify that the Standard pfcot tube/probe ID*
meets or exceeds al specifications, criteria
and/or applicable design features and is hereby assigned a pttot tube coefficient Cp of 0.99.
Certified by:
Personnel ISignature/Datw)
Team Leader (Signature/Date)
-------
9/30/94: CD2b-1
CALIBRATION DATA SHEET 2b
Verification of Standard Phot Tube Design Specmcatkma
Shape of tip « Ul(L
Personnel (Signature/Dal
Team Leader (Signature/Date)
-------
NOZZLE CALIBRATION SHEET
DA If f(~tt TO UrMUDrVM iwm V I .
Nozzle
Identification
Number
D 1 , in.
D2,in.
Dg.ln.
AD, in.
Davg
Where:
. 0
1 ,fc,
= nozzle diameter measured on a different diameter, in.
Tolerance = measure within 0:001 in.
AD = maximum difference in any two measurements, in.
Tolerance = 0.004 in.
Davg= average of D.,, D2, Dg.
-------
NOZZLE CALIBRATION SHEET
CALIBRATION BY:.
Nozzle
Identification
Number
G<-frj*5:xzr
Dvin.
D.-LSL
D2, in.
6 /IS*
D3.,in.
d.-z.^"^
AD, in,
O.&O-SL
avg
o .t_-S"i
Where:
2 3 = nozzle diameter measured on a different diameter, in.
Tolerance - measure within 0.001 in.
AD = maximum difference in any two measurements, in.
Tolerance = 0.004 in.
avgf
^' D
-------
CRITICAL ORIFICE CALIBRATION
CRITICAL ORIFICE SET S/N:| 1323S
ENVIRONMENTAL SUPPLY COMPANY
GAS ME1
•30
SS
•24
SS
*tl
SS
*1(
SS
DATE:
rERP/N:
1
2
3
1
2
3
1
2
3
1
2
i
3/14/97
S-275
CRITICAL
VACUUM
O.Hg)
U
16
16
16
11
15
18
18
18
1f
16
•M
TESTED
VACUUM
«• HO-
IS
11
18
11
1t
18
11
11
18
is
11
It
(Ml
SS
1
2
3
16
16
16
18
16
18
REFERENCE DRY OA!
SERIAL NUMBER:
n
INITIAL
830341
636448
843.114
6S0428
868.183
681467
888.122
673438
878468
683.676
884 J8
MUEAOMOSf
FMAL
$36.848
841.114
848477
858.103
881J87
887J48
873436
878460
883X71
888438
88440
700482
(METER
36238S4
«H(VJ
640
6488
6483
6477
6484
6.873
6.113
6.116
6.121
BAROMETRIC PRESSURE (In Hg):
LEAK CHECK:
6468
6470
6482
86TIAL
29.6
FMAL
2t.6
' OK |
TEMPERATURES T
AMBEHT
84
84
84
83
84
M
84
84
84
84
84
84
DGMMLET
INITIAL FINAL
86
67
88
88
71
73
72
73
74
73
74
74
88
68
70
71
73
73
73
74
74
74
74
74
DOB OUTLET
•HTML FMAL
88
86
86
65
88
«
88
88
88
88
70
70
87
67
67
66
87
67
88
6*
8*
70
78
70
DOM
AVG
8846
88.76
674
87.76
8848
70
7048
71
7148
714
72
72
ELAPSED
TIME (MM)
e
6.00
640
6.00
740
740
740
840
8.60
8.00
1840
1040
1040
AVI
AVI
AV
AVO(P*r)
28.6
DGMAH
fit HiO)
340
340
340
1 1C PACT
240
240
240
a ic PACT
140
140
140
9 1C PACT
140
140
140
K FACTOR
*
04138
04084
040CB
OR-| 0.8096 "
04486
04433
0.8434
OR -| 0.6442
04887
04882
04888
OR -1 04884
04168
04186
04176
IC FACTOR
VARIATION (%)
049
41.16
4144
1
047
41.14
41.13
I
044
41.08
041
41.18
4141
841
i
AVOICPACTOR-I 0.4186 |
70U07
786728
711431
708.728
711.831
718424
4418
4406
4483
66
66
86
67
68
88
66
80
60
87
67
66
67
66
68
8748
6846
68
1240
1240
1240
047
047
647
041N
04164
04172
^•••••••i
048
443
4142
I
AVO VOLUME
FLOW RATE
fTWN)
148
044
044
646
AVO VOLUME
FLOW RATE
(UTER8MN)
2942
23.76
16.11
1846
641
1148
AVO 1C FACTOR -1 0.3188 1
USING THE CRITICAL ORBTCE8 AS CALIBRATION STANDARDS:
WcU»to»»itanderd»rijinetofafrpaMd»rcutft»D^
to aquafom In US EPA Mated 5. Srfon 77.3.3 Oheee equafcra am pmgramn^on»»«piMd*ee«lncWBd«»lh*achorifcesBl}
•Critical Orifice Coefficient* *?•
K. V. Y (Pw * A.
OHM Office Set number 1SW
w»callbi»1adlnaeee*daiM»*mtheCodeofFedet»l
3vy-f?
6tfln«tur»
Data
K,« 1744 TWIn. HfldnotWi)
• 04886 •K/mmHg (Metric)
T«*B AbeomteemMenttempentara,
•R(EnglMi),1((MeMe)
T.« AbeoluteDOMayg. tempemhire.
•K|6>i«IMl).*K(MeWe)
C0.1329SJ08
-------
PACIFIC ENVIRONMENTAL SERVICES, IMC.
Central Park West
5001 South Miami Boulevard, P.O. Box 12077
Research Triangle Park. North Carolina 27709-2077
(919) 941-0333 FAX: (919) 941-0234
METHOD 5 DRY GAS METER CALIBRATION USING CRITICAL ORIFICES
Original Gamma « 1.015
DATE
METER PART*:
ORIFICE »| RUN*
3/29/99
MB-10
1C
FACTOR
(AVO)
TESTED
VACUUM
(InHg)
30
1
2
3
0.809*
OJ096
O.MM
15
15
15
1«
1
2
3
04166
04160
04166
11
It
1*
n
1
2
3
04108
OJ18S
OJ1W
18
11
11
METER SERIAL*:
CRITICAL ORIFICE SET SERIAL*
1323S
DOM READINGS (Ff)
INITIAL
FINAL
S60.1M
570.604
M1.0M
870.604
SS1.0M
581.507
581.567
687.0
002428
S»7.0
802428
007J80
807.880
I11JM
»1«.M1
811.888
610.001
•20.177
NET(V.|
10470
10X85
10478
5433
5428
5482
4.008
4.082
4.088
INITIAL
BAROMETRIC PRESSURE (hi Hg|:| 29.72
TEMPERATURES *F
AMBIENT
DOM INLET
INITIAL FINAL
DOM OUTLET
INITIAL FMAL
70
70
70
82
S3
87
S3
67
88
63
63
88
63
66
67
72
72
72
87
88
88
88
68
88
67
67
88
70
88
68
70
70
70
88
88
88
•8
•a
68
66
86
66
66
66
66
DOM
AVO
62.75
64.75
67 .25
68.25
68.25
68.5
67
67
67
FINAL .
2S.72
ELAPSED
TIME(MIN)
e
AVO(Pte)
29.72
DOM AH
(InHjO)
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.0(1
10.00
3.8
3.8
3.8
1
1
1
0.57
0.57
0.57
(D
V.(STD)
10.8053
10.580
10.5227
5408S
54038
54348
4.0868
4.0788
4.0828
IF Y VARIATION EXCEEDS 2.00%
ORIFICE SHOULD BE RECAL0RATED
(2)
V.(STD)
104546
104546
104548
AVO-
5.3686
5.3686
5.3686
AVO-
4.1128
4.1128
4.1128
AVO-
(3)
Y
0.8858
0.8882
0.8635
8.8882
OJ828
OJ837
OJOM
OJ81S
14088
1.0083
1JW74
1.0074
Y
VARIATION (*)
•048
•045
1.14
AH,
1J556
1J55S
1J654
1J50S
1J608
1J0W
1J854
1J864
1.8054
IKINC THE cnmCAL ORIFICES AS CALIBRATION STANDARDS:
Tta (bbnlng aquofcm an us»d to csbutato tie cHndard vo»m«o( air p«««dt«jugh»i«DGHVB(sld). and (h» critical
V, («M). and 17.64 "Ft/In. Hg (English), 0 3858 IVmm HD (Metric)
Tm = Absolut* DGM avg tamptretura (*R - English, °K - Metric)
Vtr(»td)
Vm(std)
» VohJina of gas sample passed through the critical orifice, corrected to standard conditions
^mt • Absolute ambient temperature ("R - English. "K - Metric)
tC« Average 1C factor from Critteal Orifice Calibration
DOM calibration factor
AVERAGE AH.- 1J340
0.789 AH
Viatel)
Critorl
-------
PACIFIC ENVIRONMENTAL SERVICES, INC.
Central Park West
5001 South Miami Boulevard, P.O. Box 12077
Research Triangle Park, North Carolina 27709-2077
(919) 941-0333 FAX: (919) 941-O234
METHOD 5 DRY GAS METER CALIBRATION USING CRITICAL ORIFICES
Original Gamma « 1.001
DATE:
METER PART*
ORIFICE*
RUN*
3/29/99
RMB-15
1C
FACTOR
(AVO)
TESTED
VACUUM
On Ho)
GRIT
METER SERIAL*:
CAL ORIFICE SET SERIAL *:
MB-15
1323S
DOM READINGS (FT9)
INITIAL
FMAL
30
1
2
3
04098
04090
04090
16
15
15
7(3.012
773.7(0
784435
773.7(0
714435
795.175
1<
1
2
3
041*0
(41(0
041M
18
18
18
12
1
2
3
041(5
04185
04186
18
11
18
744.254
74(425
755422
749425
755422
7(1425
795420
799.720
(04415
799.720
804.015
808.2M
USING THE CRITICAL ORIFICES AS CALIBRATION STANDARDS:
The fotmfcxi aouatbnt m used to eahuMa t» cfarNtard intimtc of air mscad tnxx
NETfVJ
10.748
10475
10.740
5471
5497
5403
440
4.295
4.281
ihfhoDGM V.
ktr
INITIAL
BAROMETRIC PRESSURE (In Hg):| 29.52
TEMPERATURES *F
AMBIENT
DOM INLET
INITIAL FINAL
DOM OUTLET
INITIAL FINAL
•8
(8
(8
(3
(4
(8
•4
(8
70
•3
(3
(5
(3
85
(5
70
70
70
(7
•9
(9
(9
«
89
(7
(7
(8
70
88
n
70
70
70
(7
(7
(7
(7
(7
(7
(5
(5
((
85
85
(«
DOM
AVO
«3.25
(5
87
68.25
(8.25
•8.5
86
8*4
FINAL
2942
ELAPSED
TIME (MM)
e
AVO (P..)
2942
DOM AH
(m.H.0)
10.00
10.00
1040
34
34
34
10.00
10.00
10.00
1
1
1
10.00
10.00
10.00
047
047
0.57
(1)
V.ISTD)
104039
10.8948
10.7190
5.508*
54343
5.5377
4.2*55
4.2*05
4.242*
IF Y VARIATION EXCEEDS 2.00%
ORIFICE SHOULD BE RECAUBRATED
(2)
V,(STD)
104039
104039
104039
AVO-
54435
54435
54435
AVO-
44(52
4.0852
44(52
AVO-
(3) 1
Y VAMAT
r
KM(%) AH0
04(30 14747
04728 14747
0470* 14747
034*8 OJ8
0470 14700
04(55 14700
03*41 14700
03»*8 0.17
04577 14212
03581 14212
04(29 14212
04598 4M
orifoe, Va (ltd), and the DGM csfcration factor. Y. That* equator* m automatical/ cafaubled in the spreadsheet above.
AVERAGE DRY GAS METER CALIBRATION FACTOR, Y »| «-M»1
(1) V.(«td)«
(2) V«r(«td)-
(3) Y"
K, V, P>,*(AH/13.<)
T.
: Net volume of gas sample passed through DGM, corrected to standard conditions
K, = 17.64 'Rfln. Hg (English), 0.3858 °K/mm Hg (Metric)
Tn = Absolute DOM avg. temperatura fR - English. "K - Metric)
» Volume of gas sample passed through the critical orifice, corrected to standard conditions
!„. « Absolute «mbtent temperature (°R - English. °K - Metric)
«•« Average IChctor from Critical Office Calibration
: DGM calibration factor
AVERAGE AH0» 13553
0.769 AH
V«,
-------
REFERENCE METER CALIBRATION
ENGLISH REFERENCE METER UNITS
Barometric Pressure 29.82
Meter Yw 1.00000
K i deg R/ inches Hg) 17.64
Time Pressure
(mln) (in. H20)
20.50 -8.000
5.00 -8.000
13.00 -8.000
8.50
27.50
26.50
14.00
15.50
12.50
23.50
17.50
15.00
32.00
35. C',
15.00
-5.400
-5.400
-5.400
-3.800
-3.800
-3.800
-2.
-2.
-2.
-1.
-1.
-1.
400
400
400
600
600
600
OGM Serial
Date
Dry Gas Meter (DGM) Temperature
Meter Readings Volcme Initial Final 1
Initial Final (cubic feet) (deg F) (deg F)
742.719 768.193 25.474 78.0 79.0
768.193 774.402 6.209 79.0 79.0
774.402 790.575 16.173 79.0 79.0
790.575
798.821
825.423
850.983
861.899
953.219
962.970
976.611
986.740
995.413
1008.596
1022.986
798.821
825.423
850.983
861.899
873.960
962.970
976.
986.
995.
1008.
1022.
1029.
611
740
413
596
986
158
8.246
26.602
25.560
10.916
12.061
9.751
13.
10.
8.
13.
14.
6.
641
129
673
183
390
172
79.0
79.0
80.0
81.0
81.0
86.0
86.
87.
87.
88.
89.
89.
0
0
0
0
0
0
79.0
80.0
81.0
81.0
82.0 ;
86.0 1
87.
87.
88.
89.
89.
90.
0 1
0 1
0 <
0 1
0 1
0 1
6841495
10/5/97
Filename: F:\OATAFILE\CALIBRAT\CAL MENU.DSKXDGM REF.
Revised: 06/08/95
Wet Test Meter (UTM)
Meter Readings Volime
Initial Final (cubic feet)
671.890
697.180
703.325
697.180
703.325
719.309
25.290
6.U5
15.984
OGN
Temp Coefficient
(deg F) Yds
77.0 1.016
77.0 1*013
77.0 1.012
Coefficient
Variation
Yds-(Avg.Yds)
0.002
0.000
-0.002
Flow
Rate
(CFM)
1.208
1.204
1.204
Max Yds - Nin Yds -0.003626886 Must be no greater than 0.030
Average Yds -1.013636253 Must be between 0.95 to 1.05
719.309 727.485
727.485 753.809
753.809 779.025
779.025 789.820
789.820 801.740
879.651 889.205
889.205 902.599
902.599 912.545
912.545 921.069
921.069 934.025
934.025 948.175
948.175 954.255
8.176 77.0 1.009
26.324 77.0 1.008
25.216 77.0 1.006
Max Yds - Mln Yds -0.002262496 Must
0.001 0.942
0.000 0.938
0.001 0.932
be no greater than 0,
030
Average Yds -1.007525980 Must be between 0.95 to 1.05
10.795 77.0 1.006 0.001 0.755
11.920 77.0 1.006 0.001 0.753
9.554 78.0 1.004 -0.001 0.747
Max Yds - Mln Yds -0.002245979 Must be no greater than 0.030
Average Yds -1.005144785 Must be between 0.95 to 1.05
13.394 78.0 1.003 -0.001 0.557
9.946 78.0 1.004 0.000 0.556
8.524 78.0 1.006 0.002 0.556
Max Yds - Ntn Yds -0.002785363 Must be no greater than 0.030
Average Yds -1.004591811 Must be between 0.95 to 1.05
12.956 78.0 1.006 -0.002 0.396
14.150 78.0 1.007 0.000 0.395
6.080 78.0 1.010 0.002 0.396
Max Yds - Mln Yds -0.004205886 Must be no greater than 0.030
Average Vox •1.007822494 Must be between 0.95 to 1.05
Overall Average Yds -1.007748265
I certify that the above Dry Gas Meter was calibrated in accordance with E.P.A. Method 5 . paragraph 7.1 :CFR 40 Part 60.
using the Precision Wet Test Meter # 11AE6. which in turn was calibrated using the American Belt Prover * 3785.
certificate i F107, wMcK* is traceable to the National Bureau of Standards (N.I.S.T.).
/?/ .. \ ... -_
Date SQ->
'Is v
Signature 1>K-^ N
-------
REFERENCE METER CALIBRATION
TWO POINT VERIFICATION CHECK
ENGLISH REFERENCE METER UNITS
DGN Serial # 6841495
Barometric Pressure 29.65
Meter Yw 1.00000
K ( deg R/inches Hg) 17.64
Date
Time Pressure
(min) (in. H20)
11.50 -5.400
Dry Gas Meter (DGM) Temperature
Meter Readings Volume Initial Final
Initial Final (cubic feet) (deg F) (deg F)
719.141 730.515 11.374 81.0 82.0
9/28/98
Wet
Meter Readings
Initial Final
433.448 444.710
0.50
-1.600 730.515 736.355
5.840
82.0
Filename:
Revised:
Test Meter (UTM)
Volume Temp
(cubic feet) (deg F)
11.262 80.0
F:\DATAFILE\CALIBRATNCAL MENU.DSK\DGM_2VER\6841495
1/5/98
PREVIOUS
DATA
DGM
Coefficient
Yds
82.0 444.710 450.550
5.840
80.0
1.006
1.008
Flow DGM
Rate Coefficient
(CFM) Yds
0.949 1.007
XCHANGE 0.0579819 X
11.313 1.007
XCHANGE -0.069724 X
XCHANGE MUST BE +/- 1.5X, ELSE PERFORM 15PT CAL
I certify that the above Dry Gas Meter was calibrated in accordance with E.P.A. Method 5 , paragraph 7.1 :CFR 40 Part 60,
using the Precision wet Test Meter * 11AE6, which in turn was calibrated using the American Bell Proven * 3785,
certificate I F107, whcjt is traceable to the National Bureau of Standards (N.I.S.T.).
Signature //^
Date
-
-------
of2
PACIFIC ENVIRONMENTAL SERVICES, INC.
Central Park West
5001 South Miami Bouteviird, P.O. Box 12077
Research Triangle Park. North Carolina 27709-2077
(919) 941-0333 FAX: (919)941-0234
Date:
03/19/99
„ in Hg: 29.73
Calibrator. DDH Meter Box (DGM) No.: RMB-10
Reference Meter Correction Factor. 1.0077 (10/5/97 & 09/28/98)
AH = 0.5
Trial
1
2
3
Trial
Duration
(min)
15
15
15
Dry Gas Meter RMB-10
Gas Volume (ft )
Initial
658.152
664.050
670.030
Final
664.050
670.030
676.056
Net
5.898
5.980
6.026
Meter Temperatures (°F)
Inlet
initial
73
75
77
Final
75
77
78
Avg.
74
76
77.5
Outlet
Initial
71
73
74
Final
73
74
75
Avg.
72
73.5
74.5
Trial
1
2
3
Reference Meter
Gas Volume (ft*)
Initial
480.269
486.290
492.320
Final
486.29
492.320
498.378
Net
6.021
6.030
6.058
Meter Temperatures (*F)
Initial
72
73
74
Final
73
74
75
Avg.
72.5
73.5
74.5
DGM Correction
Factor
r
1.028
1.017
1.015
Reference
Orifice Press
AHe (in. H2O)
1.747
1.742
1.729
AH = 0.75
Trial
1
2
3
Trial
Duration
(min)
11
11
11
Dry Gas Meter RMB-10
Gas Volume (ft3)
Initial
710.100
715.339
720.574
Final
715.339
720.574
725.805
Net
5.239
5.235
5.231
Meter Temperatures (CF)
Inlet
Initial
71
72
74
Final
72
73
72
Avg.
71.5
72.5
73
Outlet
Initia'
69
71
72
Final
71
72
72
Avg.
70
71.5
72
Trial
1
2
3
Reference Meter
Gas Volume (ft3)
Initial
532.612
537.872
543.128
Final
537.872
543.128
548.386
Net
5.260
5.256
5.258
Meter Temperatures (°F)
Initial
69
70
71
Final
70
71
71
Avg.
69.5
70.5
71
DGM Correction
Factor
Y
1.012
1.013
1.014
Reference
Orifice Press
AHe (in. H2O)
1.834
1.840
1.840
AH = 1.0
Trial
1
2
3
Trial
Duration
(min)
10
10
10
Dry Gas Meter RMB-10
Gas Volume (ft5)
Initial
727.152
732.656
738.207
Final
732.656
738.207
743.766
Net
5.504
5.551
5.559
Meter Temperatures (*F)
Inlet
Initial
73
75
75
Final
75
75
77
Avg.
74
75
76
Outlet
Initial
7Z
72
74
Final
72
74
74
Avg.
72
73
74
Trial
1
2
3
Reference Meter
Gas Volume (ft3)
Initial
549.741
555.269
560.829
Final
555.269
560.829
566.406
Net
5.528
5.560
5.577
Meter Temperatures ("F)
Initial
71
71
72
Final
71
72
72
Avg.
71
71.5
72
DGM Correction
Factor
T
1.013
1.012
1.014
Reference
Orifice Press
AH0 (in. H2O)
1.834
1.813
1.802
10 03199.xls
Printed: 04/09/99
-------
2of2
PACIFIC ENVIRONMENTAL SERVICES. INC.
Central Park West
5001 South Miami Boulevard. P.O. Box 12077
Research Triangle Park, North Carolina 27709-2077
(919) 941-0333 FAX: (919) 941-0234
Date:
« -i •
03/19/99
29.73
Calibrator. DDH
Meter Box (DGM) No.: RMB-10
Reference Meter Correction Factor 1.0077 (10/5/97 & 09/28/98)
AH = 2.0
Trial
1
2
3
Trial
Duration
(min)
7
7
7
Dry Gas Meter RMB-10
Gas Volume (ft3)
Initial
753.831
759.152
764.498
Final
759.152
764.498
769.843
Net
5.321
5.346
5.345
Meter Temperatures (eF)
Inlet
Initial
78
78
78
Final
78
78
79
Avg.
78
78
78.5
Outlet
Initial
74
75
75
Final
75
75
76
Avg.
74.5
75
75.5
Trial
1
2
3
Reference Meter
Gas Volume (fts)
Initial
576.512
581.855
587.202
Final
581.855
587.202
592.550
Net
5.343
5.347
5.348
Meter Temperatures (°F)
Initial
72
72
72
Final
72
72
72
Avg.
72
72
72
DGM Correction
Factor
Y
1.015
1.011
1.013
Reference
Orifice Press
AHe (in. H2O)
1.924
1.920
1.918
AH = 4.0
Trial
1
2
3
Trial
Duration
(min)
5
5
5
Dry Gas Meter RMB-10
Gas Volume (ft3)
Initial
771.500
776.948
782.384
Final
776.948
782.384
787.837
Net
5.448
5.436
5.453
Meter Temperatures (°F)
Inlet
Initial
78
78
78
Final
78
78
78
Avg.
78
78
78
Outlet
Initial
75
75
75
Final
75
75
75
Avg.
75
75
75
Trial
1
2
3
Reference Meter
Gas Volume (ft3)
Initial
594.239
599.727
605.224
Final
599.727
605.224
610.705
Net
5.488
5.497
5.481
Meter Temperatures (°F)
Initial
72
72
72
Final
72
72
72
Avg.
72
72
72
DGM Correction
Factor
T
1.014
1.018
1.011
Reference
Orifice Press
AHe (in. H2O)
1.869
1.863
1.874
Calibration Results
AH
0.50
0.75
1.0
2.0
4.0
y
1.020
1.013
1.013
1.013
1.014
AHa |
1.74
1.84
1.82
1.92
1.87
Dry Gas Meter RMB-10 on 03/19/99
Meter Box Calibration Factor
Meter Box Reference Orifice Pressure
1.0147
1.84
10 O3199.xte
Printed: 04/09/99
-------
'PACIFIC ENVIRONMENTAL SERVICES, INC.
Posttest Dry Gas Meter Calibration Form (English Units)
Central Park West
5001 South Miami Boulevard, P.O. Box 12077
Research Triangle Park, North Carolina 27709-2077
(919) 941-0333 FAX: (919) 941-0234
Pretest Calibration Factor 1.015
System Vacuum Setting, (in Hg) 4
Reference Meter Correction Factor 1.0077
Date: 4/16/99 Pb>. In Hg 29.70
(10/5/97 & 09/28/98)
Calibrator D. Holzschuh
Meter Box No.: MB-10
AH= 1.84
Trial
1
2
3
Duration
(mln)
8
8
8
Dr
Initial
(ff)
407.384
413.442
419.468
Final
(ft3)
413.442
419.468
425.47
Net
(ft1)
6.058
6.026
6.002
Initial. Inlet
CF)
77
79
81
y Gas Meter MB-10
Final, Inle
(°F)
79
81
82
Avg. Inlet
CF)
78
80
81.5
Initial. Outlet
CF)
74
75
76
Final. Outlet
CF)
75
76
76
Avg. Outlet
CF)
74.5
75.5
76
Trial
1
2
3
Reference Meter
Gas Volume
Initial
(ft3)
897.152
903.175
909.174
Final
(ft3)
903.175
909.174
915.165
Net
(ft5)
6.023
5.999
5.991
Meter Temperature
Initial
CF)
70
70
70
Final
CF)
70
71
71
Avg.
CF)
70
70.5
70.5
Meter Box
Correction
Factor
r
1.009
1.012
1.017
Reference
Orifice Press
AH0
(in. H2O)
1.807
1.820
1.821
10 03199
Printed. 5/3/99
-------
1of2
PACIFIC ENVIRONMEKTAL SERVICES, INC.
Cental Park West
5001 South Miami Boulevard. P.O. Box 12077
Research Triangle Park, North Carolina 27709-2077
(919)941-0333 FAX: (919) 941-0234
Date: 10/13/98
PI*, in Hg 29.57
Caibrator. AFL
Meter Box No.: RMB-15
Reference Meter Correction Factor 1.0077 (10/5/97)
AH = 0.5
Trial
1
2
3
Trial
Duration
(minL
13
13
13
Dry Gas Meter RMB-15
Gas Volume
Initial
(ft3)
300.136
305.318
310.509
Final
(ft3)
305.318
310.509
315.701
Net
(ft3)
5.182
5.191
5.192
Meter Temperatures
Initial, Inlet
CF)
66
68
71
Final, Inlet
CF)
68
71
73
Avg. Inlet
CF)
67
69.5
72
Initial, Outlet
CF)
67
68
70
inal, Outle
CF)
68
69
70
Avg. Outlet
CF)
67.5
68.5
70
Trial
1
2
3
Reference Meter
Gas Volume
Initial
(ft3)
186.312
191.438
196.556
Final
(ft3)
191.438
196.556
201.709
Net
(ft3)
5.126
5.118
5.153
Meter Temperature
Initial
CF)
66
67
69
Final
CF)
67
69
70
Avg.
CF)
66.5
68
69.5
Meter Box
Correction
Factor
y
0.997
0.994
1.002
Reference
Orifice Press
AHa
(in. H20)
1.80
1.81
1.79
AH = 0.75
Trial
1
2
3
Trial
Duration
(min)
11
11
11
Dry Gas Meter RMB-15
Gas Volume
Initial
(ft3)
316.109
321.517
326.919
Final
(ft*)
321.517
326.919
332.337
Net
(ft3)
5.408
5.402
5.418
Meter Temperatures
Initial. Inlet
CF)
73
74
75
Final, Inlet
CF)
75
76
77
Avg. Inlet
CF)
74
75
76
Initial, Outlet
CF)
71
72
73
inal, Outle
CF)
72
73
73
Avg. Outlet
CF)
71.5
72.5
73
Trial
1
2
3
Reference Meter
Gas Volume
Initial
(ft3)
202.112
207.467
212.822
Final
(ft3)
207.467
212.822
218.183
Net
(ft3)
5.355
5.355
5.361
Meter Temperature
Initial
CF)
71
72
73
Final
CF)
72
73
74
Avg.
CF)
71.5
72.5
73.5
Meter Box
Correction
Factor
r
0.998
0.999
0.997
Reference
Orifice Press
AH0
(in. HjO)
1.79
1.79
1.79
AH= 1.0
Trial
1
2
3
Trial
Duration
(min)
9.5
9.5
9.5
Dry Gas Meter RMB-15
Gas Volume
Initial
(ft3)
333.008
338.360
343.709
Final
^
338.360
343.709
349.070
Net
^
5.352
5.349
5.361
Meter Temperatures
Initial, Inlet
CF)
75
76
77
Final, Inlet
CF)
77
78
78
Avg. Inlet
CF)
76
77
77.5
Initial, Outlet
CF)
74
74
74
inal, Outle
CF)
74
74
75
Avg. Outlet
CF)
74
74
74.5
Trial
1
2
3
Reference Meter
Gas Volume
Initial
(ft3)
218.842
224.155
229.469
Final
(ft3)
224.155
229.469
234.780
Net
(ft3)
5.313
5.314
5.311
Meter Temperature
Initial
CF)
73
74
74
Final
CF)
74
74
75
Avg.
CF)
73.5
74
74.5
Meter Box
Correction
Factor
y
1.001
1.001
0.999
Reference
Orifice Press
AH0
fin. HjO)
1.81
1.81
1.82
15_10128
Printed: 10/14/98
-------
2of2
PACIFIC ENVIRONMENTAL SERVICES. INC.
Central Park West
5001 South Miami Boulevard, P.O. Box 12077
Research Triangle Park, North Caroina 27709-2077
(919)941-0333 FAX: (919) 941-0234
AH* 2.0
Trial
1
2
3
Trial
Duration
(min)
7
7
7
Dry Gas Meter RMB-15
Gas Volume
Initial
(ft3)
349.600
354.902
360.229
Final
<«*)
354.902
360.229
365.563
Net
(ft3)
5.302
5.327
5.334
Meter Temperatures
Initial. Inlet
CF)
76
. 78
78
Final. Inlet
CF)
78
89
80
Avg. Inlet
CF)
77
83.5
79
Initial, Outlet
CF)
75
75
75
inat. Outle
CF)
75
75
75
Avg. Outlet
CF)
75
75
75
Trial
1
2
3
Reference Meter
Gas Volume
Initial
(ft3)
235.29
240.576
245.870
Final
(ft3)
240.576
245.870
251.171
Net
(ft3)
5.286
5.294
5.301
Meter Temperature
Initial
CF)
73
74
74
Final
CF)
74
74
75
Avg.
CF)
73.5
74
74.5
Meter Box
Correction
Factor
Y
1.004
1.006
1.001
Reference
Orifice Press
AHo
(in. HjO)
1.99
1.97
1.98
AH * 4.0
Trial
1
2
3
Trial
Duration
(min)
5
5
5
Dry Gas Meter RMB-15
Gas Volume
Initial
(ft3)
366.500
371.861
377.264
Final
<«*>
371.861
377.264
382.658
Net
(ft*)
5.361
5.403
5.394
Meter Temi>eratures
Initial, Inlet
CF)
78
79
78
Final. Inlet
CF)
80
79
79
Avg. Inlet
CF)
79
79
78.5
Initial, Outlet
CF)
75
75
75
inal, Outle
CF)
75
75
75
Avg. Outlet
CF)
75
75
75
Trial
1
2
3
Reference Meter
Gas Volume
Initial
(ft3)
252.094
257.458
262.869
Final
(ft3)
257.458
262.869
268.275
Net
(ft3)
5.364
5.411
5.406
Meter Temperature
Initial
CF)
74
74
75
Final
CF)
75
75
75
Avg.
CF)
74.5
74.5
75
Meter Box
Correction
Factor
y
1.003
1.004
1.003
Reference
Orifice Press
AH*
(to-HzO)
1.98
1.95
1.96
Calibration Results
| AH* I
0.50
0.75
1.0
2.0
4.0
T I
0.998
0.998
1.000
1.004
1.003
AHft j Dry Gas Meter RMB-1S on 10/13/98
1 .80 Meter Box Calibration Factor
1 .79 Meter Box Reference Orifice Pressure
1.81
1.98
1.96
1.001
1.87
Printed: 10/14/98
-------
1 of 1
PACIFIC ENVIRONMENTAL SERVICES, INC.
Central Park West
5001 South Miami Boulevard, P.O. Box 12077
Research Triangle Parfc, North Carolina 27709-2077
(919)941-0333 FAX: (919)941-0234
Posttest Dry Gas Meter Calibration Form (English Units)
Pretest Calibration Factor 1.001
System Vacuum Setting, (in Hg) 4
Reference Meter Correction Factor 1.0077
Date: 4/16/99 Pb». in Hg 29.70
(10/5/97 & 09/28/98)
Calibrator D. Holzschuh
Meter Box No.: RMB-15
AH * 1.87
Trial
1
2
3
Duration
(min)
10
10
10
Dr>
Initial
(fP)
828.35
835.789
843.225
Final
(ft3)
835.789
843.225
850.663
Net
(fP)
7.439
7.436
7.438
Initial. Inlet
CF)
70
71
72
Gas Meter RMB-15
Final, Inle
CF)
71
72
73
Avg. Inlet
(°F)
70.5
71.5
72.5
Initial. Outlet
CF)
69
70
71
Final. Outlet
CF)
70
71
72
Avg. Outlet
(°F)
69.5
70.5
71.5
Trial
1
2
3
Reference Meter
Gas Volume
Initial
(ft1).
919.025
926.412
933.797
Final
(ft1)
926.412
933.797
941.179
Net
(ft1)
7.387
7.385
7.382
Meter Temperature
Initial
(T)
70
70
70
Final
CF)
70
70
70
Avg.
CF)
70
70
70
Meter Box
Correction
Factor
Y
0.996
0.998
0.999
Reference
Orifice Press
AH0
(in. H2O)
1.93
1.93
1.93
15 10128
Printed 5/3/99
-------
1. REPORT NO.
EPA-454/R-00-036b
4. TITLE AND SUBTITLE
Final Report
Testing of a 2-Stroke I can Burn Gas-Fin
Combustion Engine to Determine the Efl
Catalyst System for Reduction of Hazard
Volume 2 of 2
TECHNICAL REPORT DATA
Please read instructions on the reverse before completing
2.
:d Reciprocating Internal
ectiveness of an Oxidation
ous Air Pollutant Emissions
7. AUTHOR(S)
Dennis Falgout
Michael D. Maret
9. PERFORMING ORGANIZATION NAME AND ADDRESS
Pacific Environmental Services, Inc.
Post Office Box 12077
Research Triangle Park, North Carolina 27709-2077
12. SPONSORING AGENCY NAME AND ADDRESS
U.S. Environmental Protection Agency
Office of Air Quality Planning and Standards
Emissions, Monitoring and Analysis Division
Research Triangle Park, North Carolina 2771 1
3. RECIPIENT'S ACCESSION NO.
5. REPORT DATE
July 2000
6. PERFORMING ORGANIZATION CODE
8. PERFORMING ORGANIZATION REPORT NO.
10. PROGRAM ELEMENT NO.
11. CONTRACT/GRANT NO.
68-D-98004
13. TYPE OF REPORT AND PERIOD COVERED
Final
14. SPONSORING AGENCY CODE
EPA/200/04
15. SUPPLEMENTARY NOTES
16. ABSTRACT
The United States Environmental Protection Agency (EPA) is investigating Reciprocating Internal Combustion Engines (RICE) to characterize
engine emissions and catalyst control efficiencies of hazardous air pollutants (HAPs). This document describes the results of emissions testing conducted
on a Cooper-Bessemer GMV-4-TF natural-gas-fired 2-stroke, lean-bum (2SLB) engine. Early in 1998, several industry and EPA representatives agreed
that the Cooper-Bessemer GMV-4-TF engine, at the Colorado State University's Engine and Energy Conversion Laboratory (CSU EECL) is adequately
representative of existing and new natural-gas-fired 2SLB engines. The group agreed that a matrix of test results from testing conducted at the EECL
could be used to develop Maximum Achievalbe Control Technology (MAVT) standards for RICE. The group further agreed that an oxidation catalyst
installed on the Cooper-Bessemer GMV-4-TF could be used to determine the effectiveness of oxidation catalysts for these engines, and that the EPA
could use the results from testing at the 2SLB matrix conditions at CSU as the basis for developing the MAVT standard for natural-gas-fired 2SLB
engines.
Emissions testing was conducted to measure pollutant concentrations in the exhaust gas both up- and downstream of an oxidation catalyst. Miratech
Corporation manufactured the catalyst and CSU personnel installed it on the engine. Several sampling and analysis methodologies were used to measure
HAP emissions before and after the oxidation catalyst. Fourier transform infrared spectroscopy, or FTIRS, was used to measure formaldehyde,
acetaldehyde, and acrolein. Bezene, toluene, ethyl benzene, (o.m,p)-xylenes, styrene, hexane, and 1,3-butadiene, were measured using a direct-interface
gas chromatograph with a mass spectrometer detector, or GCMS. Continues emission monitors (CEMs) were used to measure oxygen (©2), carbon
dioxide (COJ, nitrogen oxides (NOJ, carbon monoxide (CO), total hydrocarbons (THC), and methane. Naphthalene and polycyclic aromatic
hydrocarbons (PAHs) 1 acenaphthene, acenapthylene, anthracene, benzo(k)anthracene, benzo(a)pyrene, benzo(b)fluoranthene, benzo(e)pyrene,
benzo(k)fluoranthene, benzo(g,h,i)perylene, chrysene, dibenzo(a,h)anthrene, fluoranthene, fluorene, indeno(l,2,3-cd)pyrene, 2-methylnapthalene,
perylene, phenanthrene, and pyrenej were determined using California Air Resources Board (CARB) Method 429
This report consists of two volumes totaling 1,328 pages, Volume 1 (752 pages) and Volume 2 (576 pages).
17.
a. DESCRIPTIONS
FTIRS
Hazardous Air Pollutants
Oxidation Catalyst
Polycyclic Aromatic Hydrocarbons
Reciprocating Internal Combustion
Engines
Total Hydrocarbons
18. DISTRIBUTION STATEMENT
Unlimited
KEY WORDS AND DOCUMENT ANALYSIS
b. IDENTIFIERS/OPEN ENDED TERMS
19. SECURITY CLASS (This Report)
Unclassified
20. SECURITY CLASS (This page)
Unclassified
c. COASTI Field/Group
21. NO. OF PAGES
1,328
22. PRICE
EPA Form 2220-1 (Rev. 4-77) PREVIOUS EDITION IS OBSOLETE
F:\U\FMcadows\TRD-Fnn\WP 6.1
------- |