United States
Environmental Protection
Agency
Office of Air Quality
Planning and Standards
Research Triangle Park, NC 27711
EPA-454/R-00-025D
May 2000
AIR
&EPA
Final Report
Hot Mix Asphalt Plants
Truck Loading and Silo Filling
Manual Methods Testing
Asphalt Plant C
Los Angeles, California
Volume 4 of 8
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o
FINAL REPORT
NjJ HOT MIX ASPHALT PLANTS
X TRUCK LOADING AND SILO FILLING
^ MANUAL METHODS TESTING
j ASPHALT PLANT C, LOS ANGELES, CALIFORNIA
VOLUME 4 OF 8
APPENDICES G.I AND G.2
EPA Contract No. 68-D-98-004
Work Assignment No. 3-02
Prepared for:
Mr. Michael L. Toney (MD-19)
Work Assignment Manager
SMTG, EMC, OAQPS
U.S. Environmental Protection Agency
Research Triangle Park, NC 27711
May 2000
Submitted by
PACIFIC ENVIRONMENTAL SERVICES, INC.
5001 S. Miami Blvd., Suite 300
Post Office Box 12077
Research Triangle Park, NC 27709-2077
(919) 941-0333
FAX (919) 941-0234
U.S. Environmental Protection Agency
Region 5, Library (PL-12J)
77 West Jackson Boulevard, 12Ul Float
Chicago, \L 60604-3590
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DISCLAIMER
The information in this document has been funded wholly or in part by the Office of Air
Quality Planning and Standards, U.S. Environmental Protection Agency (EPA) under contract
to Pacific Environmental Services, Inc. (PES). PES performed the work presented in this
document under three EPA contracts and seven Work Assignments; EPA Contract No. 68-D-
98-004, Work Assignment Nos. 1-08,2-07,3-02, and 3-05, EPA Contract No. 68-D-70002,
Work Assignment Nos. 0-05 and 1-07, and EPA Contract No. 68-D-70069, Work Assignment
No. 2-16. This document has been prepared by PES, reviewed following PES' internal
quality assurance procedures, and approved by PES for distribution. This document has been
subjected to the Agency's review, and has been approved by EPA for publication as an EPA
document. Mention of trade names does not constitute endorsement by the EPA or PES.
n
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TABLE OF CONTENTS
VOLUME 1 Page
1.0 INTRODUCTION 1-1
2.0 SUMMARY OF TEST RESULTS 2-1
2.1 OVERVIEW , 2-1
2.2 TREATMENT OF NON-DETECTS AND ESTIMATES . . . 2-2
2.3 TUNNEL EXHAUST DUCT 2-2
2.4 SILO EXHAUST DUCT RESULTS 2-12
2.5 PM AND MCEM DEPOSITION ESTIMATES 2-15
2.6 METEOROLOGICAL STATION RESULTS 2-15
«
3.0 PROCESS DESCRIPTION 3-1
3.1 COORDINATION BETWEEN TESTING AND PROCESS
OPERATIONS 3-3
3.2 PROCESS MONITORING DURING TESTING 3-3
3.3 PROCESS SAMPLES 3-4
3.4 VELOCITY OF ATR ACROSS TOP OF TRANSPORT TRUCKS
DURING LOAD-OUT 3-5
4.0 SAMPLING LOCATIONS 4-1
4.1 TUNNEL EXHAUST DUCT 4-1
4.2 SILO EXHAUST DUCT 4-1
5.0 SAMPLING AND ANALYTICAL PROCEDURES 5-1
5.1 LOCATION OF MEASUREMENT SITES AND
SAMPLE/VELOCITY TRAVERSE POINTS 5-1
5.2 DETERMINATION OF EXHAUST GAS VOLUMETRIC
FLOW RATE 5-1
5.3 DETERMINATION OF EXHAUST GAS DRY MOLECULAR
WEIGHT 5-3
5.4 DETERMINATION OF EXHAUST GAS MOISTURE CONTENT 5-3
in
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TABLE OF CONTENTS (CONTINUED)
VOLUME 1 ^CONTINUED') Page
5.5 DETERMINATION OF PM AND MCEM 5-3
5.6 DETERMINATION OF VOHAPs 5-3
5.7 DETERMINATION OF SVOHAPs 5-7
5.8 DETERMINATION OF WIND SPEED, WIND DIRECTION,
AMBIENT TEMPERATURE, AND AMBIENT HUMIDITY 5-7
5.9 ESTIMATE OF PM AND MCEM ON THE CEILING
OF THE LOAD-OUT TUNNEL DOWNSTREAM OF SILO NO. 5 5-7
5.10 ESTIMATE OF PM AND MCEM DEPOSITION ON THE INSIDE
WALLS OF THE SILO NO. 2 EXHAUST PLENUM 5-9
5.11 ESTIMATE OF PM AND MCEM DEPOSITION ON THE INSIDE
WALLS OF THE SILO EXHAUST DUCT 5-9
5.12 ESTIMATE OF PM AND MCEM DEPOSITION ON THE INSIDE
WALLS OF THE TUNNEL EXHAUST DUCT 5-10
6.0 QUALITY ASSURANCE/QUALITY CONTROL (QA/QC) PROCEDURES
AND RESULTS 6-1
6.1 CALIBRATION AND PREPARATION OF APPARATUS 6-1
6.2 REAGENTS AND GLASSWARE PREPARATION 6-2
6.3 ON-SITE SAMPLING 6-3
6.4 SAMPLE RECOVERY 6-4
6.5 LABORATORY ANALYTICAL QA/QC PROCEDURES 6-5
6.6 QA COORDINATOR FIELD AUDIT 6-7
APPENDIX A - TEST RESULTS AND CALCULATIONS 1
A. I TED TEST RESULTS 3
A.2 SED TEST RESULTS 101
A.3 EXAMPLE CALCULATIONS 195
A.4 PARTICULAR DEPOSITION DATA 204
A.5 CAPTURE EFFICIENCY CALCULATIONS 211
VOLUME 2
APPENDIX B-PROCESS DATA 1
B.I PRODUCTION RECORDS FOR 7/24/98 THROUGH 7/28/98 3
B.2 PRODUCT STORAGE RECORDS FOR 7/25/98 THROUGH 7/28/98 9
IV
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TABLE OF CONTENTS (CONTINUED)
VOLUME 2 rCONTINUED)
APPENDIX B - PROCESS DATA (CONTINUED)
B.3 LOAD-OUT RECORDS USED IN TED EMISSION CALCULATIONS . . 19
B.4 LOAD-OUT RECORDS FOR 6/18/98 THROUGH 7/26/98 33
B.5 LOAD-OUT RECORDS FOR 7/24/98 THROUGH 7/28/98 44
B.6 SILO NO. 2 LOAD-IN RECORDS USED IN SED EMISSION
CALCULATIONS '. 68
B.7 ASPHALT TEMPERATURES AT LOAD-OUT 90
B.8 MASS CHANGE RESULTS FROM ASTM TESTS PERFORMED ON
ASPHALT CEMENT SAMPLES 93
B.9 VELOCITY OF AIR ACROSS TOP OF TRANSPORT TRUCKS
DURING LOAD-OUT 100
B.10 METALS ANALYSIS OF PROCESS SAMPLES 104
VOLUME 3
APPENDIX C - FIELD DATA 1
C.I TED FIELD DATA 2
C.2 SED FIELD DATA 59
C.3 METEOROLOGICAL STATION DATA 89
C.4 ON-SITE GC/MS REPORT AND DATA 118
APPENDIX D - QA/QC DATA 230
APPENDIX E - PROJECT PARTICIPANTS 280
APPENDIX F - TEST METHODS
F.I EPA METHOD 1
F.2 EPA METHOD 1A
F.3 EPA METHOD 2
F.4 EPA METHOD 4
F.5 EPA METHOD 18
F.6 EPA METHOD 315
F.7 SW-846 METHOD 0010
F.8 SW-846 METHOD 0030
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TABLE OF CONTENTS (CONCLUDED)
VOLUME 4
APPENDIX G-ANALYTICAL DATA , 1
G.I PM AND MCEMDATA la
G.2 PAH/SVOHAPS CASE NARRATIVE AND PAHDATA Ik
VOLUMES
APPENDIX G - ANALYTICAL DATA (CONTINUED) 659
G.3 SVOHAPS DATA 659
VOLUME 6
APPENDLX G - ANALYTICAL DATA (CONTINUED) 1248
G.3 SVOHAPS DATA (CONCLUDED) 1248
VOLUME?
APPENDIX G - ANALYTICAL DATA (CONTINUED)".". la
G.4 VOHAPSDATA . .:..... '..... Ic
VOLUMES
APPENDIX G- ANALYTICAL DATA (CONCLUDED) la
G.4 VOHAPS DATA (CONCLUDED) Ic
G.5 EPAMETHOD 18 REPORT AND DAT A 260
VI
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LIST OF TABLES
Page
Table 1.1 Test Log Tunnel Exhaust Duct, Asphalt Plant C - California 1-4
Table 1.2 Test Log Silo Exhaust Duct, Asphalt Plant C - California 1-5
Table 2.1 Summary of Results, Production Emissions for PM, MCEM, PAH,
SVOHAP and VOHAP, Asphalt Plant C, California - July 1998 2-3
Table 2.2 Summary of Results, Average PM and MCEM Emissions,
Asphalt Plant C, California - July 1998 2-4
Table 2.3 Summary of Results, Average PAH and SVOHAP Emissions,
Asphalt Plant C, California - July 1998 2-5
Table 2.4 Summary of Results, Average VOHAP Emissions,
Asphalt Plant C, California - July 1998 2-6
Table 2.5 Summary of Results, PAHS, SVOHAPS, & VOHAPS Average
Emissions, Silo Exhaust Duct - Asphalt Plant C, California, July 1998 .... 2-7
Table 2.6 PM and MCEM Emissions Sampling and Exhaust Gas Parameters
Normal Operations, Tunnel Exhaust Duct, Asphalt Plant C - California . . 2-16
Table 2.7 PM and MCEM Exhaust Gas Concentrations and Emission Rates, Normal
Operations, Tunnel Exhaust Duct, Asphalt Plant C - California 2-17
Table 2.8 PAHs and Semi-Volatile Organics Emissions Sampling and
Exhaust Gas Parameters, Normal Operations, Tunnel Exhaust Duct,
Asphalt Plant C - California 2-18
Table 2.9 PAHs Exhaust Gas Concentrations and Emission Rates, Normal
Operations Tunnel Exhaust Duct, Asphalt Plant C - California 2-19
Table 2.10 Semi-Volatile Organics Exhaust Gas Concentrations and Emission Rates,
Normal Operations, Tunnel Exhaust Duct, Asphalt Plant C - California . . 2-21
Table 2.11 Volatile Organics - SW-846 Method 0030 Emissions Sampling and
Exhaust Gas Parameters, Normal Operations, Tunnel Exhaust Duct,
Asphalt Plant C - California 2-30
Table 2.12 Volatile Organics - SW-846 Method 0030 Exhaust Gas Concentrations
and Emission Rates, Normal Operation, Tunnel Exhaust Duct,
Asphalt Plant C - California 2-31
Table 2.13 Volatile Organics - EPA Method 18 Emissions Sampling and
Exhaust Gas Parameters, Normal Operations, Tunnel Exhaust Duct,
Asphalt Plant C - California 2-36
Table 2.14 Volatile Organics - EPA Method 18 Exhaust Gas Concentrations
and Emission Rates, Normal Operations, Tunnel Exhaust Duct,
Asphalt Plant C - California 2-37
Table 2.15 On-Site GC/MS Volatile Organics Exhaust Gas Concentrations and
Emission Rates with Vost (SW-846 Method 0030) and EPA Method 18
Comparison, Tunnel Exhaust Duct, Asphalt Plant C - California 7/24/98 . 2-38
Table 2.16 PM and MCEM Emissions Sampling and Exhaust Gas Parameters,
Background Condition, Tunnel Exhaust Duct, Asphalt Plant C - California 2-39
Vll
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LIST OF TABLES (CONTINUED)
Page
Table 2.17 PM and MCEM Exhaust Gas Concentrations and Emission Rates,
Background Condition, Tunnel Exhaust Duct, Asphalt Plant C - California 2-40
Table 2.18 PAHs and Semi-Volatile Organics Emissions Sampling and Exhaust Gas
Parameters Background Condition, Tunnel Exhaust Duct,
Asphalt Plant C - California 2-41
Table 2.19 PAHs Exhaust Gas Concentrations and Emission Rates, Background
Condition, Tunnel Exhaust Duct, Asphalt Plant C - California 2-42
Table 2.20 Semi-Volatile Organics Exhaust Gas Concentrations and Emission Rates,
Background Condition, Tunnel Exhaust Duct, Asphalt
Plant C - California 2-44
Table 2.21 Volatile Organics - SW-846 Method 0030 Emissions Sampling and
Exhaust Gas Parameters, Background Condition, Tunnel Exhaust Duct,
Asphalt Plant C - California 2-53
Table 2.22 Volatile Organics - SW-846 Method 0030 Exhaust Gas Concentrations
and Emission. Rates, Background Condition, Tunnel Exhaust Duct,
Asphalt Plant C-Cafifbmia 2-54
Table 2.23 > Volatile Ckganks- EPA Method 18 Emissions Sampling and Exhaust Gas
Parameters, Background Condition, Tunnel Exhaust Duct, Asphalt
Plant C - California 2-59
Table 2.24 Volatile Organics - EPA Method 18 Exhaust Gas Concentrations and
Emission Rates, Background Condition, Tunnel Exhaust Duct,
Asphalt Plant C - California 2-60
Table 2.25 Sample Log Silo Exhaust Duct, Asphalt Plant C - California 2-61
Table 2.26 PM and MCEM Emissions Sampling and Exhaust Gas Parameters,
Silo ExhaustDuct, Asphalt Plant C - California 2-62
Table 2.27 PM and MCEM Exhaust Gas Concentrations and Emission Rates,
Silo Exhaust Duct, Asphalt Plant C - California 2-63
Table 2.28 PAHs and Semi-Volatile Organics Emissions Sampling and Exhaust Gas
Parameters, Silo Exhaust Duct, Asphalt Plant C - California 2-64
Table 2.29 PAHs Exhaust Gas Concentrations and Emission Rates, Silo Exhaust Duct,
Asphalt Plant C - California 2-65
Table 2.30 Semi-Volatile Organics Exhaust Gas Concentrations and Emission Rates,
Silo Exhaust Duct, Asphalt Plant C - California 2-67
Table 2.31 Volatile Organks -SW-846 Method 003a Emissions Samphng and
Exhaust Gas Parameters, Silo Exhaust Duct, Asphalt Plant C - California . 2-76
Table 2.32 Volatile Organks-SW-*46 Method.Q03Q Exhaust Gas Concentrations
and Emission Rates, Sflo Exhaust Duct, Asphalt Plant C - California .... 2-77
Table 2.33 On-SiteGC/MS VolatikOrganics.Exhaust.Gas Concentrations .and
Emission Rates with Vost (SW-846 Method 0030) Comparison,
Silo Exhaust Duct, Asphalt Plant C - California 7/25/98 2-82
Table 2.34 PM and MCEM Deposition Estimates, Asphalt Plant C - California 2-83
viii
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LIST OF TABLES (CONCLUDED)
Page
Table 2.35 Meteorological Data Summary, Asphalt Plant C - California 2-84
Table 3.1 Load-out Data Used in TED Emission Calculations 3-6
Table 3.2 Load-in Data for Silo No. 2 Used in SED Emission Calculations 3-7
Table 3.3 Asphalt Temperatures at Load-out, Asphalt Plant C, California 3-8
Table 3.4 Mass Change of Asphalt, Asphalt Plant C, California 3-9
Table 3.5 Results of Metals Analyses of Asphalt Samples, Asphalt Plant C,
California 3-10
Table 3.6 Air Velocity Over Transport Trucks During Load-out, Asphalt Plant C,
California 3-11
Table 5.1 Summary of Sampling and Analytical Methods, Asphalt Plant C,
California 5-2
Table 6.1 Summary of Temperature Sensor Calibration Data 6-8
Table 6.2 Summary of Pitot Tube Dimensional Data 6-9
Table 6.3 Summary of Dry Gas Meter and Orifice Calibration Data 6-10
Table 6.4 Summary of EPA Method 315 and S W-846 Method 0010
Field Sampling QA/QC Data 6-11
Table 6.5 Summary of EPA Method 315 Blank Sample Catches 6-12
Table 6.6 SW-846 Method 0010 PAHs Field and Laboratory Blanks Results,
Tunnel Exhaust Duct 6-13
Table 6.7 SW-846 Method 0010 PAHs Field and Laboratory Blanks Results,
Silo Exhaust Duct 6-14
Table 6.8 SW-846 Method 0010 PAHs Surrogate Recovery Results,
Tunnel Exhaust Duct 6-15
Table 6.9 SW-846 Method 0010 Semi-Volatile Surrogate Recovery Results
Tunnel Exhaust Duct 6-16
Table 6.10 SW-846 Method 0010 PAHs Surrogate Recovery Results,
Silo Exhaust Duct 6-17
Table 6.11 SW-846 Method 0010 Semi-Volatile Surrogate Recovery Results
Silo Exhaust Duct 6-18
Table 6.12 SW-846 Method 0030 Field and Laboratory Blanks Results
Tunnel Exhaust Duct 6-19
Table 6.13 SW-846 Method 0030 Laboratory Blank Results, Silo Exhaust Duct .... 6-20
Table 6.14 SW-846 Method 003 0 Surrogate Recovery Results
Tunnel Exhaust Duct 6-21
Table 6.15 SW-846 Method 0030 Surrogate Recovery Results
Silo Exhaust Duct 6-22
IX
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LIST OF FIGURES
Figure 1.1 Project Organization - US EPA Hot Mix Asphalt Load-out Operation,
Asphalt Plant C, California 1-6
Figure 2.1 Load-out Tunnel and MET Station Location and Average Wind Direction 2-85
Figure 3.1 Process Flow Schematic, Asphalt Plant C, California 3-2
Figure 3.2 Velocity Measurement Locations and Dimensions of Transport Trucks ... 3-12
Figure 4.1 Tunnel Exhaust Duct Sampling Locations, Asphalt Plant C, California .... 4-2
Figure 4.2 Tunnel Exhaust Duct Traverse Point Locations,
Asphalt Plant C, California 4-3
Figure 4.3 Silo Exhaust Duct Sampling Locations, Asphalt Plant C, California 4-4
Figure 4.4 Silo Exhaust Duct Traverse Point Locations, Asphalt Plant C, California . . 4-5
Figure 5.1 EPAMethod 315 Sampling Train Schematic 5-4
Figure 5.2 SW-846 Method 0030 Sampling Train Schematic 5-6
Figure 5.3 SW-846 Method 0010 Sampling Train Schematic 5-8
Figure 5.4 Location of TED Deposition Test Plates Tt, T2, and T3 5-11
GLOSSARY OF TERMS
ASTM - American Society for Testing and Materials
CEMS - Continuous Emissions Monitoring System
CTS - Calibration Transfer Standard
EMC - Emissions Measurement Center
EMAD - Emission Monitoring and Analysis Division
ESP - Electrostatic Precipitator
FID - Flame lonization Detector
FTIR - Fourier Transform Infrared Spectroscopy
HAP - Hazardous Air Pollutant
MCEM - Methylene Chloride Extractatte Matter
MRI - Midwest Research Institute
PES - Pacific Environmental Services
PM - Paniculate Matter
PTE - Permanent Total Enclosure
RAP - Recycled Asphalt
RTFOT - Rolling Thin Film Oven Test
SED - Silo Exhaust Duct
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GLOSSARY OF TERMS (CONTINUED)
SMTG - Source Measurement Technology Group
SVOHAP - Semi-Volatile Organic Hazardous Air Pollutant
TED - Tunnel Emissions Duct
TFOT - Thin Film Oven Test
THC - Total Hydrocarbons
VOHAP - Volatile Organic Hazardous Air Pollutant
VOST - Volatile Organic Sampling Train
XI
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VOLUME 4
APPENDIX G
ANALYTICAL DATA
G. 1 PM AND MCEM DATA
G.2 PAH/SVOHAPS CASE NARRATIVE AND PAH DATA
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APPENDIX G.I
PM AND MCEM DATA
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P.O. Box 2010
Morrisville, NC 27560
EASTERN RESEARCH GROUP. INC. Ph. (919) 468-7800
Narrative
Site: Asphalt Plant C
Prepared for: Frank Phoenix (PES)
Prepared by: Link Nguyen
Description of Procedures for EPA Method 315 and Observations:
Filters -
Procedure:
The filters (including any loose particles) were transferred to a tared amber jar. The amber jars were placed into
a desiccator overnight in a temperature controlled environment. The following day, the samples were weighed
and initial weights were taken. To ensure that all conditions remained the same, the samples were placed back
into the desiccator and allowed to sit overnight and the second weighings were taken at the same time the next
day. Once constant weight had been attained, 100 mL of methylene chloride was added to each jar. The jars
were placed in a sonicator and allowed to sonicate for 3 minutes. After sonication was complete, the samples
were taken out of the sonicator. Each sample was filtered through a buchner funnel reinforced with an additional
Whatman 934-AH filter to prevent cross contamination on the buchner funnels. Once the solutions were
vacuum filtered, the extract was placed into a triple rinsed beaker (methylene chloride solvent). The beaker
containing the extract was placed onto a hotplate at low heat and the solvent was allowed to evaporate. Once the
samples almost reached dryness, the samples were taken off the hotplate and poured into a tared aluminum pan.
The beakers were triple rinsed with methylene chloride and then the solvent was poured into the aluminum pan.
The rinse was performed to ensure that no material remained in the beaker. The aluminum weighing pan was
heated to complete dryness, placed into a desiccator and allowed to sit in the desiccator overnight. The
following day, the samples were weighed and the weights recorded.
Observations:
The filters had dark gray/black discoloration, especially in places where the air flowed through the filters. All
contents of the filters and any loose particles were transferred to a tared 250 mL amber jar.
Acetone Front Half Rinse-
Procedure:
The rinses were poured into 400 mL tared beakers that were triple rinsed with methylene chloride. The weights
of the beakers including the rinses were taken to give an initial and a final weight from which the volumes of the
rinses were calculated. A separate sheet (attached) explains how the volumes were calculated. The beakers
containing the rinses were allowed to sit overnight in a hood to allow the acetone solvent to evaporate. The next
day the beakers, which now contained no solvent, were placed into the desiccator and allowed to sit in the
desiccator overnight. The next day, initial weighings for the samples were taken. The samples were then allowed
to sit in the desiccator again for 24 hours. The next day at approximately the same time, the samples were
weighed again for the second weighings. Once constant weight was attained, the weights were recorded for the
Page 1 of 4
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Paniculate Mass (PM) portion of the analysis. Next, 25 mL of methylene chloride was added to each beaker.
Aluminum foil was placed over the tops of the beakers. The beakers were then placed into a sonicator and
allowed to sonicate for 3 minutes. This fraction was combined with the methylene chloride Front Half Rinse.
Observations:
There were some particulates present in the rinse.
Methylene Chloride Front Half Rinse-
Procedure:
The rinses were poured into 400 mL tared beakers triple rinsed with methylene chloride. The weights of the
beakers including the rinses were taken to give an initial and a final weight from which the volumes of the
rinses were calculated. At this point, the extracts from the Acetone Front Half Rinse were combined with this
fraction. The combined fractions were placed onto a hotplate and allowed to heat gently at a low temperature
setting. Once the solution had almost reached dryness, the solution was poured into a tared aluminum pan. The
pan was then placed back onto the hotplate and taken to complete dryness. The pans were then transferred to the
desiccator and allowed to sit overnight. The following day, Ac samples were weighed and the weights recorded
for the MCEM analysis.
Observations:
No conditions out of the ordinary were noted.
Impinger, Back Half Water-
Procedure:
The samples were poured into a clean, pre-w.eighed, 500 mL amber jar. After the impinger contents had been
emptied into the jar, a second weight was obtained. The difference was then used to calculate the volume of the
sample. Once the volume had been determined, each sample was poured into a clean, 1000 mLseparatory ,
funnel. Once in the separatpry funnel, the arafacr jars containing the original samples were triple rinsed with
methylene chloride and the rinsesjpoured into the teparatory funnel. The approximate volume of this rinse was
50 mL. The samples were^ihen shaken for 1 minute. After 1 minute, the bottom methylene chloride layer was
drained into a clean, 250 mL beaker.. After the methylene chloride was drained, an additional 25 mL of MeCl2
was added. The solution was then shaken for another minute and the bottom methylene chloride layer-drained
into the same 250 mL beaker. This process was repeated once more. Once the third shake was completed and
the methylene chloride drained into the 250 mL beaker, the beaker was placed onto a hotplate and gently heated
to evaporate the solvent. Once the solution was evaporated almost to dryness, the solution was transferred to a
tared aluminum pan. The pan was then placed back onto the hotplate and heated to complete dryness. After
heating, the pans were placed into the desiccator to sit overnight. The following day, the pans were weighed and
the weights recorded for the MCEM analysis of the Imping"*, Back Half Water Rinse.
Observations:
The samples looked cloudy upon initial inspection. They did not seem to consist solely of water. During the
extraction of these samples, the solution formed what seemed like an emulsion between the water and
methylene chloride layer. When the methylene chloride was drained, this emulsion layer was left behind, so that
only the methylene chloride layer was taken.
Page 2 of 4
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Solvent, Back Half Rinse-
Procedure:
The exact same procedure was used for the Back Half Rinse as was used for the Front Half Rinse. The only
difference was that since PM analysis was not required, when the solvent dried down in the beaker, constant
weight was not taken for these samples. After the solvent had evaporated, 25 mL of methylene chloride was
added to each beaker and sonicated for 3 minutes each. The rest of the procedure was the same as the Acetone
Front Half Rinse.
Observations:
There didn't seem to be total miscibility with the solvents. It seemed that there might have been some water in
the solvent rinse.
Field Reagent Blanks-
Procedure:
The samples were poured into tared beakers. Weights were taken after the reagent blank rinses were poured in.
These final weights were used to calculated the volumes of the reagent blanks. The reagent blanks were allowed
to sit on a hotplate at low heat. After the solvents had evaporated, the final weights of the Beakers with any
contents remaining were taken. Paniculate Mass was calculated. For the filter blank, 100 mL of methylene
chloride was added to the beaker and sonicated for 3 minutes. Afterwards, the methylene chloride was filtered
and poured into a clean beaker. The beaker containing the solvent was heated down to near dryness. The solvent
was then transferred to a tared aluminum pan. The pan was placed onto the hotplate and redliced to dryness. The
pan was desiccated and weighed the next day for Particulate Mass.
Observations:
No observations out of the ordinary were noticed.
Laboratory Reagent Blanks-
Procedure:
The same procedures were used for Laboratory Reagent blanks as for the Field Reagent Blanks. Solvents that
were used during the extraction process were tested in the reagent blank. A filter from the same lot that was sent
to the field was used to go through the extraction process.
Observations:
No observations out of the ordinary were noticed
Deposition Samples-
Procedure:
Initial inspection of the deposition samples showed them to have a lot of sedimentation and paniculate matter at
the bottom of each of the jars. Each one of the deposition samples was poured into a pre-weighed beaker. If the
entire sample did not fit into one beaker, then it was separated into 2 or more beakers. The samples were
allowed to sit in the hood overnight to allow the solvent to evaporate. Once the solvent had evaporated, the
Page 3 of 4
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remaining sample had to be heated very gently to allow the sample to go to dryness. The next day, initial
weights were taken on the beakers containing the samples. The samples were allowed to sit overnight before a
second weighing was taken. Once the samples had attained constant weights, the weights were recorded for the
Paniculate Mass (PM) analysis. Once the PM analyses were finished, 25 mL of methylene chloride was added
to each beaker. The samples were covered with aluminum foil and placed into a sonicator to sonicate for 3
minutes. After sonication was complete, the samples were filtered through a buchner funnel and MCEM
analysis was done using the same method as described in methylene chloride FHR (for MCEM analysis).
Observations:
Some of the samples had very high volumes and so they had to be separated into 2 or more beakers. Slow
heating of the samples had to be performed to prevent any of the samples from popping or cracking, .Once all the
solvent had evaporated, there remained a large amount paniculate deposit. It resembled ground sedimentation
deposits. The samples had to be slow heated over a 6-8 hour period with constant supervision, because as the
sample volumes decreased, the samples started to crack and pop. Some of the samples had very high masses, so
longer periods of heating were required. Since the samples had to be completely dry, the samples were initially
allowed to sit on the hotplate at low heat. After this period of time, some of the sample still had some "tar-like"
properties, which indicated that the sample was still not completely dry. This coagulation into a tar-like property
raised the question of how long to heat the samples since low heat would not cause the "tar" to evaporate.
Eventually, the heat was increased in order to drive the samples to complete dryness. Once the judgment was
made that the samples were dry, the samples were desiccated overnight to get constant weights. For the MCEM
analysis portion of the extraction process, the same complications arose. Once the samples had evaporated to
almost dryness, there remained a small portion of a "tar-like" residue. The samples would not produce a valid
weight when weighed '!a&is" because in doing so, some samples produced an MCEM value which was greater
than the PM value, which is not possible. Upon observation of this anomaly, the samples ^ere.allowed to sit at
high heat until all the.ttar-iifce" appearance had evaporated leaving only a black organic residue. During the
evaporation process of this stage, the sample produced smoke, indicating that there might be some organics
being driven off as aerosolized particles. One can not conclude, however, how much, if any, organic analytes are
being driven off. In conclusion, the values produced for the MCEM analysis for the deposition samples
represent minimum values for this analysis.
Page 4 of 4
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Notes
P.O. Box 2010
Morrisville, NC 27560
,MC. Ph.(919)468-7800
Phoenix (Asphalt Plant C)
Notes on Samples:
The volumes for the Methylene Chloride FHR and the Water Rinses were not taken. This was due
to the fact that it was not known that volumes would be used for these samples. For this reason
the volumes were not taken. For future samples, all volumes will be taken for any rinses. This
includes both the Acetone and Methylene Chloride FHR, the Water Rinse as well as the
Solvent BHR.
Although actual volumes for the MeCI2 FHR rinse was not taken, approximate volumes for these
samples are about 100-120 mL for each of the Rinses. The conclusion came from the fact that
each of the rinses were in 250 ml jars and the almost all the jars were less than half full. This
approximates the volumes to be -100-120 mL per rinse.
The Water Rinses were not taken as well. Volume approximations ranged from 400-1000 mL.
The volumes for the Water Rinses were fairly large. The volumes for each of these rinses were
not consistent and so the approximation of volumes for these fractions would be difficult.
Calculations for volumes were done gravimetrically. The initial mass of the container is taken, the
rinse is poured into the container, then a final mass is taken. The final mass is subtracted from
the initial mass to obtain the mass of the Rinse. Depending on the identity of the Rinse
(i.e. Acetone or MeCI2), the proper density is used to calculate the volume.
Calculation:
Volume = Mass of rinse / density of rinse
For the Solvent Rinse, this procedure had to be changed since the density of the rinse was not
known. In order to obtain the density of the rinse, three arbitrary Solvent Rinse samples were taken
and one mL aliquots were taken from each Rinse. Masses for each of these rinses were taken and
averaged together to obtain a calculated average for the density of the Solvent Rinse. Using this
calculated average for the density of the Solvent Rinse, the volumes were then determined
gravimetrically using the above calculation. The calculated average density for the Solvent Rinse
was 1.1555 g/mL.
Page 1 of 1
-------
EASTERN RESEARCH GROUP. INC
P.O. Box2010
Morrisville, NC 27560
Ph.(919)468-7800
Phoenix (Asphalt Plant C)
Matrix =
Method =
Sample ID:
T-M315-1-F
T-M315-2-F
T-M315-3-F
T-M315-4-F
T-M315-FB-F
S-M315-1-F
S-M315-2-F
S-M315-4-F
S-M315-FB-F
Method =
Sample ID:
T-M315-1-F
T-M315-2-F
T-M315-3-F
T-M315-4-F
T-M315-FB-F
S-M315-1-F
S-M315-2-F
S-M315-4-F
S-M315-FB-F
FILTERS
PM
Weight of Petri Filter Pre-
dish (g) weight (g)
146.9268 0.4491
202.8661
162.1919
157.3657
155.6757
156.5417
187.4323
165.7223
166.5507
MCEM
Weight of
Alum, pan (g)
1 1.6303
2
3
4
5
6
7
8
9
1.6458
1.6390
T.6384
1.6474
1.6478
1.6454
1.6501
1.6501
0.4489
0.4530
0.4527
0.4463
0.4481
0.4466
0.4494
0.4500
Weight after
evaporation (g)
1.6326
1.6459
1.6396 .
- '"* .1.6384 .---••
1.6474 ;•'
. 1JB484
1.6461
1.6516
1.6504
*my «J*'$er fMily
Avg. wtOf
fifter+dish (g)
147.37945
203.31780
162.64775
157.82035
156.12630
157.08355
187.93760
166.21560
167.00225
Faial Weight of
PM(g)
0.0036
0.0028
0.0028
0.0020
0.0043
0.0938
0.0587
0.0439
0.0015
Final weight of
MCEM (g)
0.0023
0.0001
0.0006
0.0000
0.0000
0.0006
0.0007
0.0015
0.0003
its
Page 1 of 5
/F
-------
EASTERN RESEARCH CROUP. INC
P.O. Box2010
Morrisville, NC 27560
Ph.(919)468-7800
Phoenix (Asphalt Plant C>
Matrix =
Method =
Sample ID:
Old SED Acet Rins
New SED Acet Rin:
CPE
CPC
CPW
T1
T2
T3
TP Blank
BoxWN
Box WC
BoxWS
Box EN
Box EC
BoxES
TP Acetone Blank
CP Blank
Box Pipe Blank
Acetone Rinses
EM
1
1
3
4
5
1A
2A
3A
4A
5A
6A
7A
6
8A
7
9A
10A
11A
8
12A
13A
14A
9
10
Volume of
liquid (ml)
943.0
1876.0
65.2927
143.6877
91.1349
241.6473
229.0183
244.7422
209.1469
338.1920
311.4067
332.3489
76.5556
274.3465
135.2032
257.1522
216.4568
232.5808
97.2118
250.9097
269.1434
208.7190
40.4942
126.2837
Weight of
beaker (g)
102.9535
108.4430
111.1123
177.5570
177.5465
186.6089
173.2648
177.8901
177.9773
177.8120
113.6445
164.9919
111.8543
162.8926
163.0827
167.1286
104.8055
137.6304
177.7076
173.0033
107.0691
104.9096
Avg. wt. of
beaker+cont. (g)
102.96775
108.50105
111.14225
182.04745
195.26995
187.30955
187.02055
185.32105
186.33975
178.14335
113.67305
165.20975
111.98480
162.92600
164.05875
167.25685
104.92560
140.02965
177.79090
173.00340
107.07590
104.95170
Final weight of
PM(g)
98.5125
188.0179
0.0142
0.0580
0.0299
4.4905
17.7235
0.7006
13.7558
7.4310
8.3624
0.3313
0.0285
0.2178
0.1305
0.0334
0.9761
0.1282
0.1201
2.3992
0.0833
0.0001
0.0068
0.0421
Page 2 of 5
-------
EASTERN RESEARCH CROUP. INC.
P.O. Box2010
Morrisville, NC 27560
Ph.(919)468-7800
Phoenix (Asphalt Plant C)
Matrix =
Method =
Sample ID:
Old SED Acet Bins
New SED Acet Rin:
CPE
CPC
CPW
T1
T2
T3
TP Blank
BoxWN
Box WC
BoxWS
Box EN
Box EC
BoxES
TP Acetone Blank
CP Blank
Box Pipe Blank
Acetone Rinses
MCEM
1
1
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
t
2
Volume of
liquid (ml_)
943.0
1876.0
65.2927
143.6877
91.1349
241.6473
229.0183
244.7422
209.1469
338.1920
311.4067
332.3469
76.555u
274.3465
135.2032
257.1522
216.4568
232.5808
97.2118
250.9097
269.1434
208.7190
40.4942
126.2837
Weight of
Alum, pan (g)
0.9989
0.9935
1.6361
1.6348
1.6172
1.6063
1.6060
1.6263
1.6369
1.6265
1.6288
1.6067
1.6557
1.5922
1.6528
1.6529
1.6298
1.6400
1.6739
1.6492
1.5927
1.6196
1.6207
1.6314
Weight after
evaporation (g)
1.2878
1.0778
1.6451
1.6480
1.6259
1.9269
2.1379
1.6589
1.7848
1.7776
1.7784
1.6157
1.6658
1.5964
1.6540
1.6650
1.6513
1.6459
1.6763
1.7300
1.6053
1.6196
1.6219
1.6396
Final weight of
MCEM (g)
7.2225
2.9505
0.0090
0.0132
0.0087
0.3206
0.5319
0.0326
0.1479
0.1511
0.1496
0.0090
0.0101
0.0042
0.0012
O.Q121
CL0215
0.0059
0.0024
0.0808
0.0126
0.0000
0.0012
0.0082
Sit
If.
Page 3 of 5
-------
EASTERN RESEARCH CROUP, INC.
P.O. Box 2010
Morrisville, NC 27560
Ph.(919)468-7800
Phoenix (Asphalt Plant C)
Matrix =
Method =
Sample ID:
T-M315-1-FH-A
T-M315-2-FH-A
T-M315-3-FH-A
T-M315-4-FH-A
T-M315-FB-FH-A
S-M315-1-FH-A
S-M315-2-FH-A
S-M315-4-FH-A
S-M315-FB-FH-A
Matrix =
Method =
Sample ID:
T-M315-1-FH-M
T-M315-2-FH-M
T-M315-3-FH-M
T-M315-4-FH-M
T-M315-FB-FH-M
S-M315-1-FH-M
S-M315-2-FH-M
S-M315-4-FH-M
S-M315-FB-FH-M
4cetone FHR
PM
Volume of
liquid (mL)
55.1
40.9
125.4
136.0
213.4
46.0
71.1
141.7
79.7
Methvlene Chloride FHR
MCEM
Weight of
Alum, pan (g)
Weight of
beaker (g)
175.6216
165.8707
164.9791
177.8025
183.1263
167.6280
178.6901
179.7039
170.4733
1
2
3
4
5
6
7
8
9
1.6209
1 .6273
1 .6402
1.6392
1.6299
1.6363
1.6599
1.6598
1.6511
Weight after
evaporation (g)
1.6262
1.6294
1.6420
1.6422
1.6340
1.6760
1.6874
1.6671
1.6531
Avg. wt. Of
beaker+cont. (g)
175.63080
165.87565
164.98480
177.80915
183.13095
167.66835
178.72105
179.71340
170.47540
Final weight of
PM(g)
0.0092
0.0050
0.0057
0.0066
0.0046
0.0404
0.0309
0.0095
0.0021
Final weight of
MCEM (g)
0.0053
0.0021
0.0018
0.0030
0.0041
0.0397
0.0275
0.0073
0.0020
faz
Page 4 of 5
-------
EASTERN RESEARCH CROUP. INC.
P.O. 80X2010
Morrisville, NC 27560
Ph.(919)468-7800
Phoenix (Asphalt Plant C)
Matrix =
Method =
Sample ID:
T-M315-1-BH-W
T-M315-2-BH-W
T-M315-3-BH-W
T-M315-4-BH-W
T-M315-FB-BH-W
S-M315-1-BH-W
S-M315-2-BH-W
S-M315-4-BH-W1
S-M315-4-BH-W2
S-M315-4-BH-W3
S-M315-4-BH-W4
S-M315-FB-BH-W
Matrix =
Method =
Sample ID:
T-M315-1-BH-S
T-M315-2-BH-S
T-M315-3-BH-S
T-M315-4-BH-S
T-M315-FB-BH-S
S-M315-1-BH-S
S-M315-2-BH-S
S-M315-4-BH-S
S-M315-FB-BH-S
H20 Impincier rinses
MCEM
Weight of
Alum, pan (g)
1 1 .6620
2
3
4
5
6
7
8
9
10
11
12
1 .6373
1.6064
1.5923
1.5989
1.6170
1.6145
1.6000
1.6061
1.6134
1.5936
1.6239
Weight after
evaporation (g)
1 .6621
1.6374
1 .6065
1.5927
1.5989
1.6210
1.6180
1.6011
1.6064
1.6139
1.5938
1.6240
Acetone & MeCl2 Impincier rinses
MCEM
13
14
15:.
16;
17
18
19
20
21
Volume of
liquid (mi.)
238.2
181.0
258.6
199.0
125.9
258.3
186.8
226.0
148.2
Weight of
Alum, pan (g)
1.0200
1.0227
1.0258
1.0267
1.0268
1.01S9
1.0281
1.0291
1.0197
Weight after
evaporation (g)
1.0236
1.0229
1.0261
1 .0274
1.0268
1.0212
1.0292
1.0305
1.0198
Final weight of
MCEM (g)
0.0001
0.0001
0.0001
0.0004
0.0000
0.0040
0.0035
0.0011
0.0003
0.0005
0.0002
0.0001
Final weight of
MCEM (g)
0.0036
0.0002
0.0003
0.0007
0.0000
0.0023
0.0011
0.0014
0.0001
Page 5 of 5
'j
-------
APPENDIX G.2
PAH/SVOHAPS CASE NARRATIVE AND PAH DATA
-------
Quanterra
^orporated
tde Parkway
.ramento, California 95605
3 73-5600 Telephone
16 372-1059 Fax
October 22, 1998
QUANTERRA INCORPORATED PROJECT NUMBER: 300681
PO/CONTRACT: 104-98-0239
Frank Phoenix
Pacific Environmental Services
5001 South Miami Boulevard
Suite 300
Research Triangle Park, NC 277092077
Dear Mr. Phoenix:
This report contains the analytical results for the eleven samples which were received under
chain of custody by Quanterra Incorporated on 30 July 1998.
The case narrative is an integral part of this report.
If you have any questions, please feel free to call.
Sincerely,
Robert Weidenfeld
Project Manager
Advanced Technology
RW/tw
-------
TABLE OF CONTENTS
QUANTERRA INCORPORATED PROJECT NUMBER 300682
Cover Letter 1
Table of Contents la
Chain of Custody Documentation 2-4
This page was left blank due to numbering error 5
Case Narrative 6-8
Sample Description Information 9
Summary Report 10-77
PolynuclearAromatk Hydrocarbons - MemodHRGC/HRMS .78-658
Sample(s): 1,3-6,8-11
Method Blank Raw Data
Sample Raw Data
Laboratory Control Sample Data
Initial Calibration
Continuing Calibration
Sample Extraction/Preparation Log Copies
Semivolatile Organics - Method 0010/8270 659-1794
Sample(s): 1-11
Sample Raw Data
Initial Calibration
Continuing Calibration
Method Blank Raw Data
Laboratory/Duplicate Control Sample Data
Sample Extraction/Preparation Log Copies
Analysis Log Copies
Instrument Tune
-------
O PACIFIC ENVIRONMENTAL SERVICES, INC.
Central Park West
5001 South Miami Boulevard, P.O. Box 12077
Research Triangle Park, North Carolina 27709-2077
(919) 941-0333 FAX: (919) 941-0234
Sample Chain of Custody Record
PLANT: US EPA HOT MIX ASPHALT PLANT C
RECOVERY PERSON: D.D. Holzschuh
PROJECT NO.: R01 2.001
SAMPLERS: J. Rubio, D.D. Holzschuh
Sample
Identification
S-MM5-1-F
S-MM5-1-FH
S-MM5-1-XAD
S-MM5-1-COND
S-MM5-1-BH
T-MM5-1-F
T-MM5-1-FH
T-MM5-1-XAD
T-MM5-1-COND
T-MM5-1-BH
S-MM5-2-F
S-MM5-2-FH
S-MM5-2-XAD y
S-MM5-2-COND
S-MM5-2-BH
S-MM5-1B-F
S-MM5-1B-FH
S-MM5-1B-XAD
S-MM5-1B-COND
S-MM5-1B-BH
T-MM5-2-F
T-MM5-2-FH
T-MM5-2-XAD i/
T-MM5-2-COND
T-MM5-2-BH
T-MM5-FB-F
T-MM5-FB-FH
T-MM5-FB-XAD
T-MM5-FB-COND
T-MMS-FB-BHp.
T-MM5-4-F
Collection
Date
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/25/98
7/25/98
' 7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/26/98
Time
Sample
Name
Filter
Front Half/MeOH MeCI2
XAD Trap
Condensate and Rinses
Back Half Rinse
Filter ^
Front Half/MeOH MeCI2
XAD Trap
Condensate and Rinses
Back Half Rinse
Filter
Front Half/MeOH MeCI2
XAD Trap
Condensate and Rinses
Back Half Rinse
Filter
Front Half/MeOH MeCI2
XAD Trap
Condensate and Rinses
Back Half Rinse
Filter
Front Half/MeOH MeCI2
XAD Trap
Condensate and Rinses
Back Half Rinse
Filter
Front Half/MeOH MeCI2
XAD Trap
Condensate and Rinses
Back Half Rinse
Filter
Number of
Containers
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
Analytical Re<
uest
Comments
Page 1 of 3
-------
O PACIFIC ENVIRONMENTAL SERVICES, INC.
Central Park West
5001 South Miami Boulevard, P.O. Box 12077
Research Triangle Park, North Carolina 27709-2077
(919) 941-0333 FAX: (919) 941-0234
Sample Chain of Custody Record
PLANT: US EPA HOT MIX
RECOVERY PERSON: D.D. Hoiz«chu
Sample
Identification
T-MM5-4-FH
T-MM5-4-XAD y
T-MM5-4-COND
T-MM5-4-BH
T-MM5-3-F
T-MM5-3-FH
T-MM5-3-XAD /
T-MM5-3-COND
T-MM5-3-BH
S-MM5-3-F
S-MM5-3-FH
S-MM5-3-XAD \/
S-MM5-3-COND
S-MM5-3-BH
S-MM5-FB-F
S-MM5-FB-FH
S-MM5-FB-XAD
S-MM5-FB-COND
S-MM5-FB-BH
S-MM5-RB-F
S-MM5-RB-FH
S-MM5-RB-XAD
S-MM5-RB-COND
S-MM5-RB-BH
S-MM5-4-F
S-MM5-4-FH
S-MM5-4-XAD /
S-MM5-4-COND
S-MM5-4-BH
S-MM5-5-F
S-MM5-5-FH
ASPHALT PLANT C
« ''* -,
PROJECT NO.: R01 2.001
SAMPLERS: J. Rubio, D.O. Holzschuh
Collection
Date
7/2B/98
k 7/26/98
7/26/98
7/26/98
7/27/98
^ 7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/28/98
, 7/28/98
7/28/98
7/28/98
7/28/98
7/28/98
7/28/98
Time
Sample
Name
Front Half/MeOH MeC|2
XAD Trap
Condensate and Rinses
Back Half Rinse
Filter
Front Half/MeOH MeCI2
XAD Trap
Condensate and Rinses
Back Half Rinse
Filter
Front Half/MeOH MeCl2
XAD Trap
Condensate and Rinses
Back Half Rinse
Filter
Front Half/MeOH MeCI2
XAD Trap
Condensate and Rinses
Back Half Rinse
Filter
Front Half/MeOH MeCI2
XAD Trap
Condensate and Rinses
Back Half Rinse
Filter
Front Half/MeOH MeCI2
XAD Trap
Condensate and Rinses
Back Half Rinse
Filter
Front Half/MeOH MeCI2
Number of
Containers
\
t
'
1
f
' *
1
1
1
1
1
1
1
1
•
1
f *
1
Analytical Request
Comments
Field Blank
Field Blank
Field Blank
Field Blank
Field Blank
Reagent Blank
Reagent Blank
Reagent Blank
Reagent Blank
Reagent Blank
CO
Page 2 of 3
-------
nni—7
O PACIFIC ENVIRONMENTAL SERVICES, INC.
Central Park West
5001 South Miami Boulevard, P.O. Box 12077
Research Triangle Park, North Carolina 27709-2077
(919) 941-0333 FAX: (919) 941-0234
Sample Chain of Custody Record
PLANT: US EPA HOT MIX ASPHALT PLANT C
RECOVERY PERSON: D.D. Holzschuh
PROJECT NO.: R012.001
SAMPLERS: J. Rubio, D.D. Holzschuh
Sample
Identification
S-MM5-5-XAD v/
S-MM5-5-COND
S-MM5-5-BH
Relinquished by
Collection
, Date
7/28/98
7/28/98
7/28/98
vJ
Time
} 9 1
lwX/U>
Sample
Name
XAD Trap
Condensate and Rinses
Back Half Rinse
Number of
Containers
1
>• 3
1
t
Relinquished by
Analytical Rec
Date Time
Date Time
GTbtfl% HSQ
uest
Comments
Received by
Re]c«tved foc4=atiby
30rbr
Page 3 of 3
-------
This page was left blank due to numbering error.
-------
CASE NARRATIVE
QUANTERRA INCORPORATED PROJECT NUMBER 300681
All air train samples were split after extraction into three equal aliquots for analysis by 8270,
PAH analysis by HRGC/HRMS, and archive.
Polynuclear Aromatic Hydrocarbons - Method HRGC/HRMS
Initial analysis of samples 300681-1, 2,7, 10 and 11 (referenced in subsequent telephone
conversations as 'Silo' samples) were significantly compromised by extensive matrix
interferences, including retention-time shifts and co-eluting interferences, and saturated analyte
levels. No usable data could be obtained from the initial analysis. Although matrix
intereferences and some high analyte levels were also observed in samples 3, 4, 5, 6, 8, and 9
(referenced as 'Tunnel' samples) the impact was substantially less. Selected 'Silo' sample
extracts (1, 10, and 11) were therefore diluted 1000X relative to the 'Tunnel' samples and
reanalyzed. Since the originally spiked internal standards (IS) used for quantitation were diluted
out, the IS were respiked at normal levels for calculation of target analyte levels. The adverse
consequence of re-spiking the ISs into the final extract is the loss of the 'recovery correction'
feature of the isotope dilution technique as well as information regarding the efficiency of
sample extraction and cleanup. The net result is a potential low bias in the reported
concentrations for samples 1,10, and 11.
Some (IS) recoveries in multiple field samples are outside the method recovery goals of 50-
150%, as noted on the data sheets. IS recoveries in laboratory QC aliquots are within these limits
and the anomalous sample recoveries are attributed to matrix related interferences. For
recoveries that are above the upper limit, quantitation by isotope dilution generally precludes any
adverse effect on data quality due to elevated internal standard recoveries. For recoveries below
the lower control limit, data quality is not considered affected if internal standard signal-to-noise
is greater than 10:1, which is achieved for all internal standards in all samples.
Detectable concentrations of Naphthalene, 2-Methylnaphthalene, Acenaphthene, Fluorene, and
Fluoranthene are reported in the Method Blank associated with these samples. These
concentrations are consistent with levels routinely determined in XAD resin. Positives for these
analytes in the associated samples are flagged with "B" qualifier and should be reviewed for
significance
The concentration of several analytes in multiple samples exceeds the method calibration range,
as indicated with an "E" footnote on the appropriate data sheets. The concentration of these
analytes are within then linear response range of the detector and dilutions were not performed.
-------
CASE NARRATIVE
Continued
QUANTERRA INCORPORATED PROJECT NUMBER 300681
Semivolatiles by Method 8270C
Sample Surrogate recoveries-Samples 300681-1, 2, 7, 10, and 11 all had severe matrix
interferences that required dilutions. As a consequence, the surrogates spiked at the time of
extraction, were diluted to the point where they could not be quantitated and are reported as ND.
Samples300681-0003 and 0006 have a 2, 4, 6-Tribromophenol recovery that is slightly below the
targeted limits. Re-injection of the sample extracts confirmed the original resuls which are
reported.
QC Samples-Two procedures (Soxhlet and Seperatory funnel) were utilized in the extraction of
these airtrains. Each procedure generated a method blank and DCS pair (duplicate control
samples). The DCS and method blank associated with the Soxhlet extraction is labeled 31 JUL
98-16A and is part of the summary package. This set of QC is associated with the extraction of
the XAD resin and filter. All of the surrogates associated with this QC set have recoveries within
control limits. One of the DCS spike components (Pentachlorophenol) has an RPD of 12 which
is slightly above the target limit of 10. The QC set associated with the aqueous samples is found
only in the raw data. The method blank has two components with recoveries below targeted
limits and the DCS has one surrogate recovery below limits. Re-injection of,the QC sample
extracts confirmed the original results.
J Values-Due to the difficulty of the matrix, samples 300681-0001,0010, and0010 all required
high dilutions which resulted in mostly non-detects for the analytes of interest. Per client request,
the data aquired for these samples were re-processed and recalculated to include J values. This
re-processing allowed the laboratory to report positives down"tothe method detection limit
(MDL). Results reported in this manner are flagged with a "J" indicatingthaLtfaerTesultis
reported below the reporting limit and should be considered an estimated concentration.
-------
QUANTERRA INCORPORATED QUALITY CONTROL PROGRAM
Quanterra has implemented an extensive Quality Control (QC) program to ensure the production
of scientifically sound, legally defensible data of known documentable quality. This QC
program is based upon requirements in "Test Methods for Evaluating Solid Waste", USEPA
SW-846, Third Edition. It applies whenever SW-846 analytical methods are used. It also applies
in whole or in part whenever project requirements fail to specify some aspect of QC practices
described here. It does not apply when other well defined QC programs (e.g. CLP or CLP-like)
are specified. This is Quanterra's base QC program for environmental analysis.
Definitions:
Quality Control Batch. The quality control (QC) batch is a set of up to 20 field samples plus
associated laboratory QC samples that are similar in composition (matrix) and that are processed
within the same time period with the same reagent and standard lots.
Surrogate. A surrogate (or internal standard) is an organic compound similar in chemical
behavior to the target analyte, but not normally found in environmental samples. Surrogates (or
IS) are added to all samples in a batch to monitor the effects of both the matrix and the analytical
process on accuracy.
Method Blank. A method blank (MB) is a control sample prepared using the same reagents used
for the samples. As part of the QC batch, it accompanies the samples through all steps of the
sample extraction and cleanup procedure. The method blark is used to monitor the level of
contamination introduced to a batch of samples as a result of processing in the laboratory.
Laboratory Control Sample. A laboratory control sample (LCS) is prepared using a well
characterized matrix (e.g., reagent water or Ottawa sand) that is spiked with known amounts of
representative analytes. Alternate matrices (e.g., glass beads) may be used for soil analyses when
Ottawa sand is not appropriate. As part of a QC batch, it accompanies the samples through all
steps of the sample extraction and cleanup process. The LCS is used to monitor the accuracy of
the analytical process independent of possible interference effects due to sample matrix.
Duplicate Control Sample. A duplicate laboratory control sample (DCS) consists of a pair of
LCSs analyzed within the same QC batch to monitor precision and accuracy independent of
sample matrix effects.
8
-------
SAMPLE DESCRIPTION INFORMATION
for
Pacific Environmental Services
Lab ID Client ID Matrix
300681-0001-SA S-MM5-2-F,FH,XAD,COND,BH AIRTRAIN
300681-0001-MB Method Blank AIRTRAIN
300681-0002-SA S-MM5-1B-F,FH,XAD,COND,BH AIRTRAIN
300681-0003-SA T-MM5-2-F,FH,XAD,COND,BH AIRTRAIN
300681-0004-SA T-MM5-FB-F,FH,XAD,COND,BH AIRTRAIN
300681-0005-SA T-MM5-4-F,FH,XAD,COND,BH AIRTRAIN
300681-0006-SA T-MM5-3-F,FH,XAD,COND,BH AIRTRAIN
300681-0007-SA S-MM5-3-F,FH,XAD,COND,BH AIRTRAIN
300681-0008-SA S-MM5-FB-F,FH,XAD,COND,BH AIRTRAIN
300681-0009-SA S-MM5-R8-F,FH,XAD,COND,BH AIRTRAIN
300681-0010-SA S-MM5-4-F,FH,XAD,COND,BH AIRTRAIN
300681-0011-SA S-MM5-5-F,FH,XAD,COND,BH AIRTRAIN
Sampled
Date Time
25 JUL 98
25 OUL 98
25 JUL 98
25 JUL 98
25 JUL 98
26 JUL 98
27 JUL 98
27 JUL 98
26 JUL 98
25 JUL 98
25 JUL 98
28 JUL 98
Received
Date
30 JUL 98
30 JUL 98
30 JUL 98
30 JUL 98
30 JUL 98
30 JUL 98
30 JUL 98
30 JUL 98
30 JUL 98
30 JUL 98
30 JUL 98
30 JUL 98
-------
Semivolatile Organics
Method 0010/8270
Client Name: Pacific Environmental Services
Client ID:
LAB ID:
Matrix:
Authorized:
S-MM5-2-F,FH,XAD,COND,BH
300681-0001-SA
AIRTRAIN
30 JUL 98
Sampled: 25 JUL 98
Prepared: 31 JUL 98
Dilution Factor: 100
Parameter
Phenol
bis(2-Chloroethyl)ether
2-Chlorophenol
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Benzyl alcohol
1,2-Di chlorobenzene
2-Methylphenol
2,2'-Oxybis(l-chloropropane)
3/4-Methylphenol
N-Nitroso-di-n-propylamine
Hexachloroethane
Nitrobenzene
Isophorone
2-Nitrophenol
2,4-Dimethylphenol
Benzoic acid
bi s(2-Chloroethoxy)-methane
2,4-Dichlorophenol
1,2,4-Trichlorobenzene
Naphthalene
4-Chloroaniline
Hexachlorobutadiene
4-Chloro-3-methylphenol
2-Methylnaphthalene
Hexachlorocyclopentadiene
2,4,6-Trichlorophenol
2,4,5-Trichlorophenol
2-Chloronaphthalene
2-Nitroaniline
Dimethyl phthalate
Acenaphthylene
3-Nitroaniline
Acenaphthene
2,4-Dinitrophenol
Wet wt.
Result
Units
Received: 30 JUL 98
Analyzed: 31 AUG 98
Reporting
Limit
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1600
ND
ND
ND
3600
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sampl e
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
15000
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
15000
3000
3000
3000
3000
15000
3000
15000
Qualifier
GR
Note G = Reporting limit(s) raised due to matrix interference.
Note J = Result is detected below the reporting limit or is an estimated concentration.
Note R = Reporting limit(s) raised due to sample volume limitations.
ND = Not Detected
Reported By: Emily Uebelhoer
Approved By: Mike Orbanosky
10
The cover letter is an integral part of this report.
Rev 230787
-------
Semivolatile Organics
Method 0010/8270
(ctmt.)
Client Name: Pacific Environmental Services
Client ID:
LAB ID:
Matrix:
Authorized:
S-MM5-2-F,FH,XAD,COND,BH
300681-0001-SA
AIRTRAIN
30 JUL 98
Sampled: 25 JUL 98
Prepared: 31 JUL 98
Dilution Factor: 100
Parameter
4-Nitrophenol
Dibenzofuran
2,4-Dinitrotoluene
2,6-Dinitrotoluene
Diethyl phthalate
4-Chlorophenyl phenyl ether
Fluorene
4-Nitroaniline
4,6-Dinitro-2-methylphenol
N-Nitrosodiphenylamine
4-Bromophenyl phenyl ether
Hexachlorobenzene
Pentachlorophenol
Phenanthrene
Anthracene
Di-n-butyl phthalate
Fluoranthene
Pyrene
Butyl benzyl phthalate
3,3'-Dichlorobenzidine
Benzo(a)anthracene
bi s(2-Ethylhexyl^-pfcthalate
Chrysene
Di-n-octyl phthalate
Wet wt.
Result
Benzofb
Benzoik
Benzo(a
Indeno(
fluoranthene
fluorantftene
pyrene
iiiviciiwi ,2,3-cd)pyrene
Dibenz(a,h)anthracene
Benzo(q,h,i)perylene
Acetophenone
4-Aminobiphenyl
Aniline
Benzidine
3,3'-Dimethylbenzidine
N - N i t ro s od i met hylaurme
N-Nitrosomorpholine
Units
Received: 30 JUL 98
Analyzed: 31 AUG 98
Reporting
Limit
Qualifier
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
950
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ug/Sampl e
ug/Sample
ug/Sampl e
ug/Sampl e
ug/Sampl e
ug/Sampl e
ug/Sample
ug/Sampl e
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sampl e
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sarapl e
ug/Saraple
ug/S ample
ug/Sampl e
ug/ Sample
tig/Sample
ug/Sample
ug/Sampl e
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sampl e
ug/Sampl e
ug/Sample
ug/Sample
ug/Sample
ug/Sample
15000
3000
3000
3000
3000
3000
3000
15000
15000
3000
3000
3000
15000
3000
3000
3000
3000
3000
30DO
6000
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
1 5000
3000
30000
6000
3000
3000
Note J = Result is detected below the reporting limit or
ND - Not Detected
Reported By: Emily Uebelhoer
arr estimated concentration,
Approved By: Mike Orbanosky
The cover letter is an integral part of this report.
Rev 230787
-------
Semivolatile Organics
Method 0010/8270
(cont.)
Client Name: Pacific Environmental Services
Client ID:
LAB ID:
Matrix:
Authorized:
S-MM5-2-F,FH,XAD,COND,BH
300681-0001-SA
AIRTRAIN
30 JUL 98
Sampled: 25 JUL 98
Prepared: 31 JUL 98
Dilution Factor: 100
Parameter
(PCNB)
Pentachloron i trobenzene
o-Toluidine
2-Methoxybenzenamine
Biphenyl
Chioroacetophenone
Cumene
DBCP U,2-Dibromo-3-chloropropane)
Benzo(e)pyrene
N-N-Diethylaniline
Dimethyl aniline
3,3'-Dimethoxybenzidine
Hydroquinone
4,4'-Methyl-bis(2-chloroaniline)
4-Nitrodiphenyl
Trifluralin
Wet wt.
Result
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Units
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sampl e
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
Reporting
Limit
15000
6000
--
--
--
--
--
--
--
--
--
--
--
--
--
Received: 30 JUL 98
Analyzed: 31 AUG 98
Qualifier
Surrogate
Nitrobenzene-d5
2-Fluorobiphenyl
Terphenyl-dl4
Phenol-d5
2-Fluorophenol
2,4,6-Tri bromophenol
Recovery
ND %
ND %
ND %
ND %
ND %
ND %
Acceptable Range
45 - 107
62 - 110
58 - 135
43 - 130
36 - 111
58 - 131
ND = Not Detected
Reported By: Emily Uebelhoer
i:
Approved By: Mike Orbanosky
The cover letter is an integral part of this report.
Rev 230787
-------
Semivolatiles Library Search (20 Compound TID)
Method 8270
Client Name: Pacific Environmental Services
Client ID:
LAB ID:
Matrix:
Authorized:
S-MM5-2-F,FH,XAD,COND,BH
300681-0001-SA
AIRTRAIN
30 JUL 98
Sampled: 25 JUL 98
Prepared: NA
Dilution Factor: 100
Parameter
Unknown alkane
Unknown
Unknown PAH
Unknown alkene
Undecane
Unknown
Dodecane, 2,6,10-trimethyl-
Tetradecane
Unknown alkene
Heptadecane, 2,6,10,14 -tetramethyl'
Undecane, 2-methyl-
Unknown alkane
Nonadecane
Heptadecane, 2,6-dimethyl-
Heptadecane, 2,6-dimethyl-
Heptadecane, 2,6-dimethyl-
" ' 2,6-dimethyl-
Heptadecane,
Nonadecane
Heptadecane,
Nonadecane
2,6,10,14 -tetramethyl-
Result
7900
13000
15000
8900
8600
8400
17000
22000
12000
18000
19000
13000
24000
15000
32000
10000
14000
7700
9700
7500
Units
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
Received: 30 JUL 98
Analyzed: 31 AUG 98
Reporting
Limit
Qualifier
0
0
0
0
0
0
0
0
0
0
0
0
Note 0 = Or structurally similar compound (isomer).
NA = Not Applicable
Reported By: Emily Uebelhoer
Approved By: Mike Orbanosky
The cover letter is an integral part of this report.
Rev 230787
-------
Semivolatile Organics
Method 0010/8270
Client Name: Pacific Environmental Services
Client ID: S-MM5-1B-F,FH,XAD,COND,BH
LAB ID: 300681-0002-SA
Matrix: AIRTRAIN Sampled: 25 JUL 98
Authorized: 30 JUL 98 Prepared: 31 JUL 98
Dilution Factor: 100
Parameter
Phenol
bis(2-Chloroethyl)ether
2-Chlorophenol
1,3-Dichlorobenzene
1,4-Di chlorobenzene
Benzyl alcohol
1,2-Dichlorobenzene
2-Methylphenol
2,2'-Oxybis(l-chloropropane)
3/4-Methylphenol
N-Nitroso-di-n-propylamine
Hexachloroethane
Nitrobenzene
Isophorone
2-Nitrophenol
2,4-Dimethylphenol
Benzoic acid
bis(2-Chloroethoxy)-methane
2,4-Dichlorophenol
1,2,4-Trichlorobenzene
Naphthalene
4-Chloroaniline
Hexachlorobutadi ene
4-Chloro-3-methyl phenol
2-Methylnaphthalene
Hexachlorocyclopentadiene
2,4,6-Trichlorophenol
2,4,5-Trichlorophenol
2-Chloronaphthalene
2-Nitroaniline
Dimethyl phthalate
Acenaphthylene
3-Nitroaniline
Acenaphthene
2,4-Dinitrophenol
4-Nitrophenol
Wet wt.
Result
Units
Received: 30 JUL 98
Analyzed: 31 AU6 98
Reporting
Limit
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
4700
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
15000
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
15000
3000
3000
3000
3000
15000
3000
15000
15000
Qualifier
RG
Note G = Reporting limitfs
Note R = Reporting limit(s
ND = Not Detected
raised due to matrix interference.
raised due to sample volume limitations.
14
Reported By: Emily Uebelhoer
Approved By: Mike Orbanosky
The cover letter is an integral part of this report.
Rev 230787
-------
Semi volatile Organics
Method 0010/8270
(cont.)
Client Name: Pacific Environmental Services
Client ID: S-MM5-1B-F,FH,XAD,COND,BH
LAB ID: 300681-0002-SA
Matrix: AIRTRAIN Sampled: 25 JUL 98
Authorized: 30 JUL 98 Prepared: 31 JUL 98
Dilution Factor: 100
Parameter
Dibenzofuran
2,4-Dinitrotoluene
2,6-Dinitrotoluene
Diethyl phthalate
4-Chlorophenyl phenyl ether
Fluorene
4-Nitroaniline
4,6-Di ni tro-2-methyl phenol
N-Nitrosodiphenylamine
4-Bromophenyl phenyl ether
Hexachlorobenzene
Pentachlorophenol
Phenanthrene
Anthracene
Di-n-butyl phthalate
Fluoranthene
Pyrene
Butyl benzyl phthalate
3,3'-Dichlorobenzidine
Benzo(a)anthracene
bis(2-Ethylhexyl)-phthalate
Chrysene
Di-n-octyl phthalate
Benzo b fluoranthene
Benzo k fluoranthene
Benzo a pyrene
Indenofl,2,3-cd)pyrene
Dibenz(a,h)anthracene
Benzo(g,h,i)perylene
Acetophenone
4-Aminobiphenyl
Aniline
Benzidine
3,3'-Dimethylbenzidine
N-Nitrosodimethy'tatnrine
N-Nitrosomorpholine
Pentachloronitrobenzene (PCNB)
o-Toluidine
Wet wt.
Result
Units
Received: 30 JUL 98
Analyzed: 31 AUG 98
Reporting
Limit
Qualifier
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
tig/Sample
ug/ Sample
ug/Sampl e
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sampl e
ug/Sampl e
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/ Sample
ug/Sample
ug/Sanple
3000
3000
3000
3000
3000
3000
15000
15000
3000
3000
3000
15000
3000
3000
3000
3000
3000
3000
6000
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
15000
3000
30000
6000
3000
3000
15000
6000
ND = Not Detected
Reported By: Emily Uebelhoer
Approved By: Mike Orbanosky
The cover letter is an integral part of this report.
Rev 230787
-------
Semivolatile Organics
Method 0010/8270
(cont.)
Client Name: Pacific Environmental Services
Client ID: S-MM5-1B-F,FH,XAD,COND,BH
LAB ID: 300681-0002-SA
Matrix: AIRTRAIN Sampled: 25 JUL 98
Authorized: 30 JUL 98 Prepared: 31 JUL 98
Dilution Factor: 100
Wet wt.
Parameter Result Units
2-Methoxybenzenamine ND ug/Sample
Biphenyl ND ug/Sample
Chloroacetophenone ND ug/Sample
Cumene ND ug/Sample
DBCP (l,2-Dibromo-3-chloropropane) ND ug/Sample
Benzo(e)pyrene ND ug/Sample
N-N-Diethylaniline ND ug/Sample
Dimethylaniline ND ug/Sample
3,3'-Dimethoxybenzidine ND ug/Sample
Hydroquinone ND ug/Sample
4,4'-Methyl-bis(2-chloroaniline) ND ug/Sample
4-Nitrodiphenyl ND ug/Sample
Trifluralin ND ug/Sample
Received: 30 JUL 98
Analyzed: 31 AUG 98
Reporting
Limit
Qualifier
Surrogate
Nitrobenzene-d5
2-Fluorobiphenyl
Terphenyl-dl4
Phenol-d5
2-Fluorophenol
2,4,6-Tribromophenol
Recovery
ND %
ND %
ND %
ND %
ND %
ND %
Acceptable Range
45 - 107
62 - 110
58 - 135
43 - 130
36 - 111
58 - 131
Note H = Spiked analyte not detected because of required sample dilution.
ND = Not Detected
Reported By: Emily Uebelhoer
Approved By: Mike Orbanosky
16
The cover letter is an integral part of this report.
Rev 230787
-------
Semivolatiles Library Search (20 Compound TID)
Method 8270
Client Name: Pacific Environmental Services
Client ID: S-MM5-1B-F,FH,XAD,COND,BH
LAB ID: 300681-0002-SA
Matrix: AIRTRAIN Sampled: 25 JUL 98
Authorized: 30 JUL 98 Prepared: NA
Dilution Factor: 100
Parameter Result Units
Unknown alkane 7800 ug/Sample
Dodecane 7800 ug/Sample
Unknown 15000 ug/Sample
Unknown hydrocarbon 17000 ug/Sample
3-Hexadecene, (z)- 10000 ug/Sample
Undecane 11000 ug/Sample
Unknown alkane 20000 ug/Sample
Unknown alkane 26000 ug/Sample
Unknown 14000 ug/Sample
Heptadecane, 2,6,10,14 -tetramethyl- 22000 ug/Sample
Dodecane, 3-methyl- 22000 ug/Sample
Unknown alkane 9900 ug/Sample
Nonadecane 26000 ug/Sample
Nonadecane 18000 ug/Sample
Heptadecane, 2,6-dimethyl- 40000 ug/Sample
Unknown alkane 12000 ug/Sample
Nonadecane 17000 ug/Sample
Nonadecane 8100 ug/Sample
Nonadecane 9800 ug/Sample
Nonadecane 7800 ug/Sample
Received: 30 JUL 98
Analyzed: 31 AUG 98
Reporting
Limit
Qualifier
0
0
0
0
0
0
0
0
0
0
0
Note 0 = Or structurally similar compound (isomer).
NA = Not Applicable
Reported By: Emily Uebelhoer
Approved By: Mike Orbanosky
The cover letter is an integral part of this report.
Rev 230787
-------
Semivolatile Organics
Method 0010/8270
Client Name:
Client ID:
LAB ID:
Matrix:
Authorized:
Pacific Environmental Services
T-MM5-2-F,FH,XAD,COND,BH
300681-0003-SA
AIRTRAIN
30 JUL 98
Sampled: 25 JUL 98
Prepared: 31 JUL 98
Dilution Factor: 1.0
Parameter
Phenol
bis(2-Chloroethyl)ether
2-Chlorophenol
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Benzyl alcohol
1,2-Dichlorobenzene
2-Methylphenol
2,2'-Oxybis(l-chloropropane)
3/4-Methylphenol
N-Nitroso-di-n-propylamine
Hexachloroethane
Nitrobenzene
Isophorone
2-Nitrophenol
2,4-Dimethylphenol
Benzoic acid
bis(2-Chloroethoxy)-methane
2,4-Dichlorophenol
1,2,4-Trichlorobenzene
Naphthalene
4-Chloroaniline
Hexachlorobutadiene
4-Chloro-3-methyl phenol
2-Methyl naphthalene
Hexach1orocyclopentadi ene
2,4,6-Trichlorophenol
2,4,5-Trichlorophenol
2-Chloronaphthalene
2-Nitroaniline
Dimethyl phthalate
Acenaphthylene
3-Nitroaniline
Acenaphthene
2,4-Dinitrophenol
4-Nitrophenol
Dibenzofuran
Wet wt.
Result
Units
Received: 30 JUL 98
Analyzed: 31 AUG 98
Reporting
Limit
Qualifier
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
60
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
150
30
30
30
30
30
30
30
30
30
30
150
30
30
30
30
150
30
150
150
30
Note R = Reporting limit(s) raised due to sample volume limitations.
ND = Not Detected
Reported By: Emily Uebelhoer
Approved By: Karin Yee
18
The cover letter is an integral part of this report.
Rev 230787
-------
Semivolatile Organics
Method 0010/8270
(cont.)
Client Name: Pacific Environmental Services
Client ID:
LAB ID:
Matrix:
Authorized:
T-MM5-2-F,FH,XAD,COND,BH
300681-0003-SA
AIRTRAIN
30 JUL 98
Sampled: 25 JUL 98
Prepared: 31 JUL 98
Dilution Factor: 1.0
Parameter
2,4-Dinitrotoluene
2,6-Dinitrotoluene
Diethyl phthalate
4-Chlorophenyl phenyl ether
Fluorene
4-Nitroaniline
4,6-Dinitro-2-methylphenol
N-Nitrosodiphenylamine
4-Bromophenyl phenyl ether
Hexachlorobenzene
Pentachlorophenol
Phenanthrene
Anthracene
Di-n-butyl phthalate
Fluoranthene
Pyrene
Butyl benzyl phthalate
3,3'-Dichlorobenzidine
Benzo(a)anthracene
bi s(2-Ethylhexyl)-phthalate
Chrysene
Di-n-octyl phthalate
Benzo
Benzo
Benzo
fluoranthene
fluoranthene
pyrene
Indeno( ,2,3-cd)pyrene
Dibenz(a,h)anthracene
Benzo(g,h,i)perylene
Acetopnenone
4-Aminobiphenyl
Aniline
Benzidine
3,3'-Dimethylbenzidine
N-Nitrosodimethylamine
N-Nitrosomorpholine
Pentachloroni troberczene
o-Toluidine
(PCNB)
Wet wt.
Result
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Units
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sarapl e
ug/Sampl e
ug/Sampl e
ug/Sampl e
ug/Sample
ug/Sampl e
ug/Sampl e
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sampl e
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sarapl e
ug/Sample
ug/Sarapl e
ug/Sampl e
ug/Sample
Reporting
Limit
30
30
30
30
30
150
150
30
30
30
150
30
30
30
30
30
30
60
30
30
30
30
30
30
30
30
30
30
30
150
30
300
60
30
30
150
60
Received: 30 JUL 98
Analyzed: 31 AUG 98
Qualifier
ND = Not Detected
Reported By: Emily Uebelhoer
Approved By: Karin Yee
The cover letter is an integral part of this report.
Rev 230787
-------
Semivolatile Organics
Method 0010/8270
(cont.)
Client Name: Pacific Environmental Services
Client ID:
LAB ID:
Matrix:
Authorized:
T-MM5-2-F,FH,XAD,COND,BH
300681-0003-SA
AIRTRAIN
30 JUL 98
Sampled: 25 JUL 98
Prepared: 31 JUL 98
Dilution Factor: 1.0
Parameter
2-Methoxybenzenamine
Biphenyl
Chloroacetophenone
Cumene
DBCP (1,2-Di bromo-3-chloropropane)
Benzo(e)pyrene
N-N-Diethylaniline
Dimethylaniline
3,3'-Dimethoxybenzidine
Hydroquinone
4,4'-Methyl-bis(2-chloroaniline)
4-Nitrodiphenyl
Trifluralin
Wet wt.
Result
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Units
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
Received: 30 JUL 98
Analyzed: 31 AUG 98
Reporting
Limit
Qualifier
K
K
K
K
K
K
K
K
K
K
K
K
K
Surrogate
Nitrobenzene-d5
2-Fluorobiphenyl
Terphenyl-dl4
Phenol-d5
2-Fluorophenol
2,4,6-Tri bromophenol
Recovery
87 %
105 %
78 %
67 %
62 %
49 %
Acceptable Range
45 - 107
62 - 110
58 - 135
43 - 130
36 - 111
58 - 131
Note i
Note K
Surrogate recovery is outside of control limits.
Identified by mass spectrum only; quantitation based on 1:1 response with
internal standard.
ND = Not Detected
Reported By: Emily Uebelhoer
Approved By: Karin Yee
20
The cover letter is an integral part of this report.
Rev 230787
-------
S.1,.Ut,l« "bgg-SMrch (20 Co^nd TIO)
Client Name:
Client ID:
LAB ID:
Matrix:
Authorized:
Pacific Environmental Services
T-MM5-2-F,FH,XAD,COND,BH
3AIRT8RAi°N003"SA Campled: 25 OUL 98
30 JUL 98 PreP^ed: NA
Dilution Factor: 1.0
Parameter
j.
4-Hydroxy-4-methyl -2-pentanone
n-Nonane
Unknown alkane
IH-Indene, 1-ethylidene-
Undecane tetramethyl
Heptadecane, 2,6,10,14 -teirameuijri
Unknown alkane
Unknown tptramethyl
Heptadecane, 2,6,10,14 -tetrameiny
Pentadecane
Nonadecane
Heptadecane
,
2,6-dimetnyi-
Heptadecane, 2,6-dimettiyi-
Unknown alkane
Nonadecane
Nonadecane j.m.H.|,vi
Heptadecane, 2,6-dimernyi-
Nonadecane
3-Octadecene,
Unknown
Result
Units
450
370
180
240
180
220
200
260
290
190
160
200
111)
130
160
120
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sampl e
ug/Sample
Received: 30 JUL 98
Analyzed: 31 AUG 98
Reporting
Limit
Qualifier
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Note 0 = Or structurally similar compound (isomer).
NA = Not Applicable
Approved By:
Reported By: Emily Uebelhoer Pp
The cover letter is an integral part of
Karin Yee
-------
Semivolatile Organics
Method 0010/8270
Client Name: Pacific Environmental Services
Client ID: T-MM5-FB-F,FH,XAD,COND,BH
LAB ID: 300681-0004-SA
Matrix: AIRTRAIN Sampled: 25 JUL 98
Authorized: 30 JUL 98 Prepared: 31 JUL 98
Dilution Factor: 1.0
Parameter
Phenol
bis(2-Chloroethyl)ether
2-Chlorophenol
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Benzyl alcohol
1,2-Dichlorobenzene
2-Methylphenol
2,2'-Oxybi s(1-chloropropane)
3/4-Methylphenol
N-Nitroso-di-n-propylamine
Hexachloroethane
Nitrobenzene
Isophorone
2-Nitrophenol
2,4-Dimethylphenol
Benzoic acid
bi s(2-Chloroethoxy)-methane
2,4-Dichlorophenol
1,2,4-Trichlorobenzene
Naphthalene
4-Chloroaniline
Hexachlorobutadiene
4-Chloro-3-methylphenol
2-Methyl naphthalene
Hexachlorocyclopentadi ene
2,4,6-Trichlorophenol
2,4,5-Trichlorophenol
2-Chloronaphthalene
2-Nitroaniline
Dimethyl phthalate
Acenaphthylene
3-Nitroaniline
Acenaphthene
2,4-Dinitrophenol
4-Nitrophenol
Dibenzofuran
Wet wt.
Result
Units
Received: 30 JUL 98
Analyzed: 31 AU6 98
Reporting
Limit
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
150
30
30
30
30
30
30
30
30
30
30
150
30
30
30
30
150
30
150
150
30
Qualifier
R
Note R = Reporting limit(s) raised due to sample volume limitations.
ND = Not Detected
Reported By: Emily Uebelhoer
22
Approved By: Karin Yee
The cover letter is an integral part of this report.
Rev 230787
-------
Semivolatile Organics
Method 0010/8270
(cont.)
Client Name: Pacific Environmental Serv :es
Client ID: T-MM5-FB-F,FH,XAByCaNa,BH
LAB ID: 300681-0004-SA -
Matrix: AIRTRAIN Campled: IS JUL 98
Authorized: 30 JUL 98 *repared: 31 JUL 9a
Dilution Factor: 1.0
Parameter
2,4-Dinitrotoluene
2,6-Dinitrotoluene
Diethyl phthalate
4-Chlorophenyl phenyl ether
Fluorene
4-Nitroaniline
4,6-Dinitro-2-methyl phenol
N-Nitrosodiphenylamine
4-Bromophenyl phenyl ether
Hexachlorobenzene
Pentachlorophenol
Phenanthrene
Anthracene
Di-n-butyl phthalate
Fluoranthene
Pyrene
Butyl benzyl phthalate
3,3'-Dichlorobenzidine
Benzo(a)anthracene
bi s(2-Ethylhexyl)-phthalate
Chrysene
Di-n-octyl phthalate
Benzo b fluoranthene
Benzo k fluoranthene
Benzo a pyrene
Indeno( ,2,3-cd)pyrene
Dibenz(a,h)anthracene
Benzo(g,h,i)perylene
Acetophenone
4-Aminobiphenyl
Aniline
Benzidine
3,3'-Dimethylbenzidine
N-Nitrosodimethylamine
N-Nitrosomorpholine
Pentachloronitrobenzene (PCNB)
o-Toluidine
Wet wt.
Result
ffeceiwefc: 30 JUL 98
.Analyzed: 31 AUG 98
Reporting
Qu;
ID
,U)
\'0
ND
ND
ND
ND
HO
ID
r,
::o
= SD
ro
-in
rtD
HD
ND
ND
ND
ND
ND
ND
jO
^0
r-
NO
-:0
;D
MD
ND
ND
ND
ND
ND
ND
ND
ND
ug/Sample
ug/ Sample
ug/ Sample
ug/Sample
ug/Sample.
ug/Sample
ug/Sample
ug/Sample
ug/Sarople
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sampl e
tig/Sample
ug/Sample
ug/Sample
ug/Sample
i „, Sample
ug/Sample
ug/Sampl e
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
30
3Q
30
, ->o.
-. - '30
.. . £50
-.. rso
„• 30
30
30
150
30
30
30
30
30
:~30
^60
* :.?-
30
30
30
30
30
30
30
30
30
.30
150
so,:
300
60
30
30
150
60
ND = Not Detected
Reported By: Emily Jebelhoer
23
Approved By: Karin Yee
The cover letter"4s an integral part of this report.
Rev Z30787
-------
Semivolatile Orqanics
Method 0010/8270
Client Name: Pacific Environmental Services
Client ID: T-MM5-FB-F,FH,XAD,COND,BH
LAB ID: 300681-0004-SA
Matrix: AIRTRAIN Sampled: 25 JUL 98
Authorized: 30 JUL 98 Prepared: 31 JUL 98
Dilution Factor: 1.0
Wet wt.
Parameter Result Units
Jt-Hethoxybenzenamine ND ug/Sample
ftiphenyl ND ug/Sample
Ctotoroacetoph-enone ND ug/Sample
Cumene ND ug/Sample
SBCP (l,2-Dibromo-3-chloropropane) ND ug/Sample
lfenzo(e)pyrene ND ug/Sample
t*N-Diethyl aniline ND ug/Sample
limethylaniline ND ug/Sample
3,3'-Dimethoxybenzidine ND ug/Sample
Hydroquinone ND ug/Sample
4»4'-Methyl-bis(2-chloroaniline) ND ug/Sample
4-Nitrodiphenyl ND ug/Sample
Trifluralin ND ug/Sample
Received: 30 JUL 98
Analyzed: 31 AUG 98
Reporting
Limit Qualifier
K
K
K
K
K
K
K
K
K
K
K
K
K
Surrogate
Ritrobenzene-d5
2-Fluorobiphenyl
Terphenyl-d!4
Phenol-d5
Z-Fluorophenol
Z,4,6-Tri bromophenol
Recovery
60 %
85 %
94 %
65
56
70
Acceptable Range
45 - 107
62 - 110
58 - 135
43 - 130
36 - 111
58 - 131
Itote K = Identified by mass spectrum only; quantitation based on 1:1 response with
internal standard.
MD = Not Detected
24
Seported By: Emily Uebelhoer
Approved By: Karin Yee
The cover letter is an integral part of this report.
Rev 230787
-------
Semivolatiles Library Search (20 Compound TID)
Method 8270
Pacific Environmental Services
T-MM5-FB-F,FH,XAD,CONO,BH
300681-0004-SA
AIRTRAIN Sampled:
30 JUL 98 Prepared:
25 JUL 98
-NA
.cion Factor: 1.0
Parameter
4-Hydroxy-4-methyl-2-pentanone
n-Nonane
Benzaldehyde
Unknown
Hexadecanoic acid
Unknown
Unknown
Unknown
Unknown
5-Eiconsene,(E) -
Unknown
Unknown
Unknown
Unknown
Unknown
Unknown alkene
Unknown
Unknown alkene
Unknown
Unknown
Pasult •.-
260 -.
260 •;'
22 .
23 ;
62
160
55
40
20
58
73
75
. 74
;40
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Saraple
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ng/Sairp1?
Received:
Analyzed:
Report tnq
Qu
Note 0 = Or structurally similar compound
NA = Not Applicable
Reported By: Emily Uebelhoer
The cover letter is anHntegral part »,f Vi
Rev 230787
-------
Semi volatile Organics
Method 0010/8270
Client Name:
Client ID:
LAB ID:
Matrix:
Authorized:
Pacific Environmental Services
T-MM5-4-F,FH,XAD,COND,BH
300681-0005-SA
AIRTRAIN Sampled: 26 JUL 98
30 JUL 98 Prepared: 31 JUL 98
Dilution Factor: 1.0
Parameter
Phenol
bis(2-Chloroethyl)ether
2-Chlorophenol
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Benzyl alcohol
1,2-Dichlorobenzene
2-Methylphenol
2,2'-Oxybis(l-chloropropane)
3/4-Methylphenol
N-Nitroso-di-n-propylamine
Hexachloroethane
Nitrobenzene
Isophorone
2-Nitrophenol
2,4-Dimethylphenol
Benzoic acid
bis(2-Chloroethoxy)-methane
2,4-Dichlorophenol
1,2,4-Trichlorobenzene
Naphthalene
4-Chloroaniline
Hexachlorobutadiene
4-Chloro-3-methyl phenol
2-Methylnaphthalene
HexachIorocycl opentadi ene
2,4,6-Trichlorophenol
2,4,5-Trichlorophenol
2-Chloronaphthaiene
2-Nitroaniline
Dimethyl phthalate
Acenaphthylene
3-Nitroanil ine
Acenaphthene
2,4-Dinitrophenol
4-Nitrophenol
Dibenzofuran
Wet wt.
Result
Units
Received: 30 JUL 98
Analyzed: 31 AUG 98
Reporting
Limit
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ug/ Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
150
30
30
30
30
30
30
30
30
30
30
150
30
30
30
30
150
30
150
150
30
Qualifier
Note R = Reporting limit(s) raised due to sample volume limitations.
ND = Not Detected
26
Reported By: Emily Uebelhoer
Approved By: Karin Yee
The cover letter is an integral part of this report.
Rev 230787
-------
Semivolatile Organics
Method 0010/8270
(cont.)
Client Name: Pacific Environmental Services
Client ID:
LAB ID:
Matrix:
Authorized:
T-MM5-4-F,FH,XAD,COND,BH
300681-0005-SA
AIRTRAIN
30 JUL 98
Sampled: 26 JUL 98
Prepared: 31 JUL 98
Dilution Factor: 1.0
Parameter
2,4-Dinitrotoluene
2,6-Dinitrotoluene
Diethyl phthalate
4-Chlorophenyl phenyl ether
Fluorene
4-Nitroaniline
4,6-Dinitro-2-methylphenol
N-Nitrosodiphenylamine
4-Bromophenyl phenyl ether
Hexachlorobenzene
Pentachlorophenol
Phenanthrene
Anthracene
Di-n-butyl phthalate
Fluoranthene
Pyrene
Butyl benzyl phthalate
3,3'-Dichlorobenzidine
Benzo(a)anthracene
bi s(2-Ethylhexyl)-phthalate
Chrysene
Di-n-octyl phthalate
Benzo b fluoranthene
Benzo k fluoranthene
Benzo a pyrene
Indeno( ,2,3-cd)pyrene
Di benz(a,h)anthracene
Benzo(g,h,i)perylene
Acetopnenone
4-Aminobiphenyl
Aniline
Benzidine
3,3'-Dimethylbenzidine
N-Nitrosodimethyl amine
N-Nitrosomorpholine
Pentachloronitrobenzene (PCNB)
o-Toluidine
Wet wt.
Result
Units
Received: 30 JUL 98
Analyzed: 31 AUG 98
Reporting
Limit
Qualifier
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sampl e
ug/Sample
ug/Sample
ug/Sampl e
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sampl e
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sampl e
ug/Sample
ug/Sample
ug/Sampl e
ug/Sample
ug/Sample
ug/Sample
30
30
30
30
30
150
150
30
30
30
150
30
30
30
30
30
30
60
30
30
30
30
30
30
30
30
30
30
30
150
30
300
60
30
30
150
60
ND = Not Detected
Reported By: Emily Uebelhoer
Approved By: Karin Yee
The cover letter is an integral part of this report.
Rev 230787
-------
Semivolatile Organics
Method 0010/8270
(cont.)
Client Name: Pacific Environmental Services
Client ID:
LAB ID:
Matrix:
Authorized:
T-MM5-4-F,FH,XAD,COND,BH
300681-0005-SA
AIRTRAIN
30 JUL 98
Sampled: 26 JUL 98
Prepared: 31 JUL 98
Dilution Factor: 1.0
Parameter
2-Methoxybenzenamine
Biphenyl
Chi oroacetophenone
Cumene
DBCP (l,2-Dibromo-3-chloropropane)
Benzo(e)pyrene
N-N-Diethylaniline
Dimethylaniline
3,3'-Dimethoxybenzidine
Hydroquinone
4,4' -Methyl-bis(2-chloroaniline)
4-Nitrodiphenyl
Trifluralin
Wet wt.
Result
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Units
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
Received: 30 JUL 98
Analyzed: 31 AUG 98
Reporting
Limit
Qualifier
K
K
K
K
K
K
K
K
K
K
K
K
K
Surrogate
Nitrobenzene-d5
2-Fluorobiphenyl
Terphenyl-dl4
Phenol-d5
2-Fluorophenol
2,4,6-Tribromophenol
Recovery
62 %
86
110
61
54
65
Acceptable Range
45 - 107
62 - 110
58 - 135
43 - 130
36 - 111
58 - 131
Note K = Identified by mass spectrum only; quantitation based on 1:1 response with
internal standard.
ND = Not Detected
Reported By: Emily Uebelhoer
Approved By: Karin Yee
The cover letter is an integral part of this report.
Rev 230787
28
-------
Semivolatiles Library Search (20 Compound TID)
Method 8270
Client Name: Pacific Environmental Services
Client ID:
LAB ID:
Matrix:
Authorized:
T-MM5-4-F,FH,XAD,COND,BH
300681-0005-SA
AIRTRAIN
30 JUL 98
Sampled: 26 JUL 98
Prepared: NA
Dilution Factor: 1.0
Parameter
2,6-dimethyl-
2,6-dimethyl-
Benzaldehyde
Pentadecane
Nonadecane
Heptadecane,
Heptadecane,
Nonadecane
Nonadecane
Unknown
Unknown
Unknown
Tricosane
4-Hydroxy-4-methyl-2-pentanone
Unknown
Unknown
5-Eiconsene,(E) -
Unknown
n-Nonane
Unknown
3-Octadecene, (E)-
Unknown
Result
43
61
66
41
120
45
36
36
97
40
37
320
63
58
120
42
350
63
38
47
Units
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
Received: 30 JUL 98
Analyzed: 31 AUG 98
Reporting
Limit
Qualifier
0
0
0
0
0
0
0
0
0
0
0
0
Note 0 = Or structurally similar compound (.isomer).
NA = Not Applicable
Reported By: Emily Uebelhoer
Approved By: Karin Yee
The cover letter is an integral part of this report.
Rev 230787
-------
Semivolatile Organics
Method 0010/8270
Client Name: Pacific Environmental Services
Client ID:
LAB ID:
Matrix:
Authorized:
T-MM5-3-F,FH,XAD,COND,BH
300681-0006-SA
AIRTRAIN
30 JUL 98
Sampled: 27 JUL 98
Prepared: 31 JUL 98
Dilution Factor: 1.0
Parameter
Phenol
bis(2-Chloroethyl)ether
2-Chlorophenol
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Benzyl alcohol
1,2-Dichlorobenzene
2-Methylphenol
2,2'-Oxybis(l-chloropropane)
3/4-Methylphenol
N-Nitroso-di-n-propylamine
Hexachloroethane
Nitrobenzene
Isophorone
2-Nitrophenol
2,4-Dimethylphenol
Benzoic acid
bis(2-Chloroethoxy)-methane
2,4-Dichlorophenol
1,2,4-Tri chlorobenzene
Naphthalene
4-Chloroaniline
Hexachlorobutadiene
4-Chloro-3-methyl phenol
2-Methylnaphthalene
Hexachlorocyclopentadi ene
2,4,6-Trichlorophenol
2,4,5-Trichlorophenol
2-Chloronaphthalene
2-Nitroaniline
Dimethyl phthalate
Acenaphthylene
3-Nitroaniline
Acenaphthene
2,4-Dinitrophenol
4-Nitrophenol
Dibenzofuran
Wet wt.
Result
Units
Received: 30 JUL 98
Analyzed: 31 AUG 98
Reporting
Limit
Qualifier
53
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
39
ND
ND
ND
74
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
150
30
30
30
30
30
30
30
30
30
30
150
30
30
30
30
150
30
150
150
30
Note R = Reporting limit(s) raised due to sample volume limitations.
ND = Not Detected
Reported By: Emily Uebelhoer
Approved By: Karin Yee
30
The cover letter is an integral part of this report.
Rev 230787
-------
Semivolatile Organics
Method 0010/8270
(cont.)
Client Name: Pacific Environmental Services
Client ID:
LAB ID:
Matrix:
Authorized:
T-MM5-3-F,FH,XAD,COND,BH
300681-0006-SA
AIRTRAIN
30 JUL 98
Sampled: 27 JUL 98
Prepared: 31 JUL 98
Dilution Factor: 1.0
Parameter
2,4-Dinitrotoluene
2,6-Dinitrotoluene
Diethyl phthalate
4-Chlorophenyl phenyl ether
Fluorene
4-Nitroaniline
4,6-Dinitro-2-methylphenol
N-Nitrosodiphenylamine
4-Bromophenyl phenyl ether
Hexachlorobenzene
Pentachlorophenol
Phenanthrene
Anthracene
Di-n-butyl phthalate
Fluoranthene
Pyrene
Butyl benzyl phthalate
3,3'-Di chlorobenztdine
Benzo(a)anthracene
bis(2-Ethylhexyl)-phthala-te
Chrysene
Di-n-octyl phthalate
Benzofb)fluoranthene
Benzo(kmuoranthene
Benzo(a)pyrene
Indeno(l,2,3-cd)pyrene
Di benz(a,h)anthracene
Benzo(q,h,i)pery1ene
Acetopnenone
4-Aminobiphenyl
Aniline
Benzidine
3,3'-Dimethylbenzidine
N-Nitrosodimethyl amine
N-Nitrosomorpholine
Pentachloronitrobenzene (PCNB)
o-Toluidine
Wet wt.
Result
Units
Received: 30 JUL 98
Analyzed: 31 AUG 98
Reporting
Limit
Qualifier
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ug/Sampl e
ug/Sample
ug/Sampl e
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sampl e
ug/Sampl e
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
30
30
30
30
30
150
150
30
30
30
150
30
30
30
30
30
30
60
30
30
30
30
30
30
30
30
30
30
30
150
30
300
60
30
30
150
60
ND = Not Detected
Reported By: Emily Uebelhoer
Approved By: Karin Yee
The cover letter is an integral part of this report.
Rev 230787
-------
Semivolatile Organics
Method 0010/8270
(cont.
Client Name: Pacific Environmental Services
Client ID: T-MM5-3-F,FH,XAD,COND,BH
LAB ID: 300681-0006-SA
Matrix: AIRTRAIN
Authorized: 30 JUL 98
Dilution Factor: 1.0
Parameter
2-Methoxybenzenamine
Biphenyl
Chloroacetophenone
Cumene
DBCP (1,2-Dibromo-3-chloropropane)
Benzo(e)pyrene
N-N-Diethylaniline
Dimethylaniline
3,3'-Dimethoxybenzidine
Hydroquinone
4,4'-Methyl-bis(2-chloroaniline)
4-Nitrodiphenyl
Trifluralin
Sampled:
Prepared:
Wet wt.
Result
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
27 JUL 98
31 JUL 98
Units
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
Received: 30 JUL 98
Analyzed: 31 AUG 98
Reporting
Limit
Qualifier
K
K
K
K
K
K
K
K
K
K
K
K
K
Surrogate
Nitrobenzene-d5
2-Fluorobiphenyl
Terphenyl-d!4
Phenol-d5
2-Fluorophenol
2,4,6-Tribromophenol
Recovery
78
106
80
69
71
52
Acceptable Range
45 - 107
62 - 110
58 - 135
43 - 130
36 - 111
58 - 131
Note i = Surrogate recovery is outside of control limits.
Note K = Identified by mass spectrum only; quantitation based on 1:1 response with
internal standard.
ND = Not Detected
Reported By: Emily Uebelhoer
Approved By: Karin Yee
The cover letter is an integral part of this report.
Rev 230787
-------
Semivolatiles Library Search (20 Compound TID)
Method 8270
Client Name: Pacific Environmental Services
Client ID:
LAB ID:
Matrix:
Authorized:
T-MM5-3-F,FH,XAD,COND,BH
300681-0006-SA
AIRTRAIN
30 JUL 98
Sampled: 27 JUL 98
Prepared: NA
Dilution Factor: 1.0
Parameter
n-Nonane
Unknown
Undecane
Dodecane
Unknown alkane
IH-Indene, 1-ethylidene-
Undecane,4,7-dimethyl-
4-Hydroxy-4-methyl-2-pentanone
Heptadecane, 2,6,10,14 -tetramethyl-
Tetradecane
Unknown aromatic hydrocarbon
Heptadecane, 2,6,10,14 -tetramethyl
Pentadecane
Nonadecane
Heptadecane,
Heptadecane,
Nonadecane
2,6-dimethyl-
2,6-dimethyl-
Nonadecane
Nonadecane
9-Eicosene (E)-
Result
390
270
180
160
240
170
240
350
250
430
230
300
.440
400
230
520
170
180
150
240
Units
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
Received: 30 JUL 9fi
Analyzed: 31 AUG 88
Reporting
Limit
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Note 0 = Or structurally similar compound (isomer).
NA = Not Applicable
Reported By: Emily Uebelhoer
Approved By: Karin Yee
The cover letter is an integral part of this report.
Rev 230787
-------
Semivolatile Organics
Method 0010/8270
Client Name: Pacific Environmental Services
Client ID:
LAB ID:
Matrix:
Authorized:
S-MM5-3-F,FH,XAD,COND,BH
300681-0007-SA
AIRTRAIN
30 JUL 98
Sampled: 27 JUL 98
Prepared: 31 JUL 98
Dilution Factor: 100
Parameter
Phenol
bis(2-Chloroethyl)ether
2-Chlorophenol
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Benzyl alcohol
1,2-Dichlorobenzene
2-Methylphenol
2,2'-Oxybi s(1-chloropropane)
3/4-Metnylphenol
N-Nitroso-di-n-propylamine
Hexachloroethane
Nitrobenzene
Isophorone
2-Nitrophenol
2,4-Dimethylphenol
Benzoic acid
bis(2-Chloroethoxy)-methane
2,4-Dichlorophenol
1,2,4-Trichlorobenzene
Naphthalene
4-Chloroaniline
Hexachlorobutadiene
4-Chloro-3-methylphenol
2-Methylnaphtha!ene
Hexachlorocyclopentadi ene
2,4,6-Trichlorophenol
2,4,5-Trichlorophenol
2-Chloronaphthalene
2-Nitroaniline
Dimethyl phthalate
Acenaphthylene
3-Nitroaniline
Acenaphthene
2,4-Dinitrophenol
4-Nitrophenol
Wet wt.
Result
Units
Received: 30 JUL 98
Analyzed: 31 AUG 98
Reporting
Limit
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
3200
ND
ND
ND
6300
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
15000
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
15000
3000
3000
3000
3000
15000
3000
15000
15000
Qualifier
GR
Note G = Reporting limitfs
Note R = Reporting limitis
ND = Not Detected
raised due to matrix interference.
raised due to sample volume limitations.
Reported By: Emily Uebelhoer
Approved By: Mike Orbanosky
The cover letter is an integral part of this report.
Rev 230787
34
-------
Semivolatile Organics
Method 0010/8270
(cent.)
Client Name: Pacific Environmental Services
Client ID:
LAB ID:
Matrix:
Authorized:
S-MM5-3-F,FH,XAD,COND,BH
300681-0007-SA
AIRTRAIN
30 JUL 98
Sampled: 27 JUL 98
Prepared: 31 JUL 98
Dilution Factor: 100
Parameter
Dibenzofuran
2,4-Dinitrotoluene
2,6-Dinitrotoluene
Diethyl phthalate
4-Chlorophenyl phenyl ether
Fluorene
4-Nitroaniline
4,6-Dinitro-2-methylphenol
N-Nitrosodiphenylamine
4-Bromophenyl phenyl ether
Hexachlorobenzene
Pentachlorophenol
Phenanthrene
Anthracene
Di-n-butyl phthalate
Fluoranthene
Pyrene
Butyl benzyl phthalate
3,3'-Dichlorobenzidine
Benzo(a)anthracene
bi s(2-Ethylhexyl)-phthalate
Chrysene
Di-n-octyl phthalate
Benzofb fluoranthene
Benzolk fluoranthene
Benzo(a pyrene
Indeno(1,2,3-cd)pyrene
Di benz(a,hj anthracene
Benzo(q,h,i)perylene
Acetopnenone
4-Aminobiphenyl
Aniline
Benzidine
3,3'-Dimethylbenzidine
N-Nitrosodimethyl amine
N-Ni trosomorpholi ne
Pentachloronitrobenzene (PCNB)
o-Toluidine
Wet wt.
Result
Units
Received: 30 JUL 98
Analyzed: 31 AUG 98
Reporting
Limit
Qualifier
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
NO
NO
ND
ND
ND
ND
ND
ND
ug/Sampl e
ug/Sample
ug/Sampl e
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/ Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Saraple
ug/Sample
ug/Sampl e
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
3000
3000
3000
3000
3000
3000
15000
15000
3000
3000
3000
15000
3000
3000
3000
3000
3000
300Q
6000
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
15000
3000
30000
6000
3000
3000
15000
6000
ND = Not Detected
Reported By: Emily Uebelhoer
Approved By: Mike Orbanosky
The cover letter is an integral part of this report.
Rev 230787
-------
Setnivolatile Organics
Method 0010/8270
(cont.)
Client Name: Pacific Environmental Services
Client ID:
LAB ID:
Matrix:
Authorized:
S-MM5-3-F,FH,XAD,COND,BH
300681-0007-SA
AIRTRAIN
30 JUL 98
Sampled: 27 JUL 98
Prepared: 31 JUL 98
Dilution Factor: 100
Parameter
2-Methoxybenzenamine
Biphenyl
Chloroacetophenone
Cumene
DBCP (1,2-Di bromo-3-chloropropane)
Benzo(e)pyrene
N-N-Diethylaniline
Dimethylaniline
3,3'-Dimethoxybenzidine
Hydroquinone
4,4'-Methyl-bis(2-chloroaniline)
4-Nitrodiphenyl
Trifluralin
Wet wt.
Result
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Units
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
Received: 30 JUL 98
Analyzed: 31 AUG 98
Reporting
Limit Qualifier
Surrogate
Nitrobenzene-d5
2-Fluorobiphenyl
Terphenyl-dl4
Phenol-d5
2-Fluorophenol
2,4,6-Tri bromophenol
Recovery
ND %
ND %
ND %
ND %
ND %
ND %
Acceptable Range
45
62
58
43
36
58
107
110
135
130
111
131
Note H = Spiked analyte not detected because of required sample dilution.
ND = Not Detected
Reported By: Emily Uebelhoer
Approved By: Mike Orbanosky
The cover letter is an integral part of this report.
Rev 230787
36
-------
Semivolatiles Library Search (20 Compound TID)
Method 8270
Client Name: Pacific Environmental Services
Client ID:
LAB ID:
Matrix:
Authorized:
S-MM5-3-F,FH,XAD,COND,BH
300681-0007-SA
AIRTRAIN
30 JUL 98
Sampled: 27 JUL 98
Prepared: NA
Dilution Factor: 100
Parameter
Undecane
Decane, 2,5,6-trimethyl-
Undecane, 2,6-dimethyl-
Unknown
Heptadecane, 2,6-dimethyl-
Unknown
Decane, 2,4-dimethyl
Unknown
Unknown alkane
Unknown alkane
Naphthalene, 1,3-dimethyl-
Heptadecane, 2,6,10,14 -tetramethyl
Dodecane, 3-methyl-
Unknown alkane
Nonadecane
Nonadecane
Heptadecane, 2,6-diraethyl-
Unknown alkane
Nonadecane
Heptadecane, 2,6-dimethyl-
Result
10000
12000
9900
11000
19000
13000
19000
9100
22000
36000
16000
26000
35000
11000
35000
22000
46000
14000
17000
10000
Units
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
Received: 30 JUL 98
Analyzed: 31 AUG 98
Reporting
Limit
Qualifier
0
0
0
0
0
0
0
0
0
0
0
0
0
Note 0 = Or structurally swilar compound (isomer).
NA = Not Applicable
Reported By: Emily Uebeliroer
Approved By: Mike Orbanosky
The cover letter is an integral part of this report.
Rev 230787
37
-------
Semivolatile Organics
Method 0010/8270
Client Name: Pacific Environmental Services
Client ID: S-MM5-FB-F,FH,XAD,COND,BH
LAB ID: 300681-0008-SA
Matrix: AIRTRAIN Sampled: 26 JUL 98
Authorized: 30 JUL 98 Prepared: 31 JUL 98
Dilution Factor: 1.0
Parameter
Phenol
bis(2-Chloroethyl)ether
2-Chlorophenol
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Benzyl alcohol
1,2-Di chlorobenzene
2-Methylphenol
2,2'-Oxybis(l-chloropropane)
3/4-Methylphenol
N-Nitroso-di-n-propylamine
Hexachloroethane
Nitrobenzene
Isophorone
2-Nitrophenol
2,4-Dimethylphenol
Benzoic acid
bis(2-Chloroethoxy)-methane
2,4-Dichlorophenol
1,2,4-Trichlorobenzene
Naphthalene
4-Chloroaniline
Hexachlorobutadiene
4-Chloro-3-methylphenol
2-Methylnaphthalene
Hexachlorocyclopentadi ene
2,4,6-Trichlorophenol
2,4,5-Trichlorophenol
2-Chloronaphthalene
2-Nitroaniline
Dimethyl phthalate
Acenaphthylene
3-Nitroaniline
Acenaphthene
2,4-Dinitrophenol
4-Nitrophenol
Dibenzofuran
Wet wt.
Result
Units
Received: 30 JUL 98
Analyzed: 31 AUG 98
Reporting
Limit
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
150
30
30
30
30
30
30
30
30
30
30
150
30
30
30
30
150
30
150
150
30
Qualifier
R
Note R = Reporting limit(s) raised due to sample volume limitations.
ND = Not Detected
Reported By: Emily Uebelhoer
Approved By: Karin Yee
The cover letter is an integral part of this report.
Rev 230787
38
-------
Semivolatile Organics
Method 0010/8270
(cont.)
Client Name: Pacific Environmental Services
Client ID: S-MM5-FB-F,FH,XAD,COND,BH
LAB ID: 300681-0008-SA
Matrix: AIRTRAIN Sampled: 26 JUL 98
Authorized: 30 OUL 98 Prepared: 31 JUL 98
Dilution Factor: 1.0
Parameter
2,4-Dinitrotoluene
2,6-Dinitrotoluene
Diethyl phthalate
4-Chlorophenyl phenyl ether
Fluorene
4-Nitroaniline
4,6-Dinitro-2-methyl phenol
N-Nitrosodiphenylamine
4-Bromophenyl phenyl ether
Hexachlorobenzene
Pentachlorophenol
Phenanthrene
Anthracene
Di-n-butyl phthalate
Fluoranthene
Pyrene
Butyl benzyl phthalate
3,3'-Dichlorobenzidine
Benzo(a)anthracene
bi s(2-Ethylhexyl)-phthalate
Chrysene
Di-n-octyl phthalate
Wet wt.
Result
Benzofb
Benzofk
Benzo(a
Indeno(
fluoranthene
fluoranthene
pyrene
,2,3-cd)pyrene
Dibenz(a,hjanthracene
Benzo(g,h,i)perylene
Acetophenone
4-Aminobiphenyl
Aniline
Benzidine
3,3'-Di methylbenzidine
N-Nitrosodimethylamine
N-Nitrosomorpholine
Pentachloronitrobenzene (PCNB)
o-Toluidine
Units
Received: 30 JUL 98
Analyzed: 31 AUG 9fl
Reporting
Limit
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ug/Sample
ug/S ample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sampl e
ug/Sample
ug/Sampl e
ug/Sample
ug/Sampl e
ug/Sample
ug/Sample
ug/Sampl e
ug/Sample
ug/Sampl e
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sampl e
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
30
30
30
30
30
150
150
30
30
30
150
30
30
30
30
30
30
60
30
30
30
30
30
30
30
30
30
30
30
150
30
300
60
30
30
150
60
Qualifier
ND = Not Detected
Reported By: Emily Uebelhoer
Approved By: Kartn Yee
The cover letter is an integral part of this report.
Rev 230787
3<
-------
Semivolatile Organics
Method 0010/8270
Client Name: Pacific Environmental Services
Client ID: S-MM5-FB-F,FH,XAD,COND,BH
LAB ID: 300681-0008-SA
Matrix: AIRTRAIN Sampled: 26 JUL 98
Authorized: 30 JUL 98 Prepared: 31 JUL 98
(cent.)
Dilution Factor: 1.0
Parameter
2-Methoxybenzenamine
Biphenyl
Chioroacetophenone
Cumene
DBCP (1,2-Dibromo-3-chloropropane)
Benzo(e)pyrene
N-N-Diethylaniline
Dimethyl aniline
3,3'-Dimethoxybenzidine
Hydroquinone
4,4'-Methyl-bis(2-chloroaniline)
4-Nitrodiphenyl
Trifluralin
Wet wt.
Result
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Units
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
Received: 30 JUL 98
Analyzed: 31 AUG 98
Reporting
Limit
Qualifier
K
K
K
K
K
K
K
K
K
K
K
K
K
Surrogate
Nitrobenzene-d5
2-Fluorobiphenyl
Terphenyl-dl4
Phenol-d5
2-Fluorophenol
2,4,6-Tribromophenol
Recovery
58 %
79 %
101 %
59 %
54 %
74 %
Acceptable Range
45 - 107
62 - 110
58 - 135
43 - 130
36 - 111
58 - 131
Note K - Identified by mass spectrum only; quantitation based on 1:1 response with
internal standard.
ND = Not Detected
Reported By: Emily Uebelhoer
Approved By: Karin Yee
The cover letter is an integral part of this report.
Rev 230787
40
-------
Semivolatiles Library Search (20 Compound TID)
Method 8270
Client Name: Pacific Environmental Services
Client ID: S-MM5-FB-F,FH,XAD,COND,BH
LAB ID: 300681-0008-SA
Matrix: AIRTRAIN Sampled: 26 JUL 98
Authorized: 30 JUL 98 Prepared: NA
Dilution Factor: 1.0
Parameter
n-Nonane
Benzaldehyde
Heptadecane, 2,6-dimethyl-
4-Hydroxy-4-methyl-2-pentanone
Hexadecanoic acid
Unknown alkane
Tricosane
Unknown alkane
Unknown
Unknown alkane
5-Eiconsene,(E) -
Unknown
Unknown
Unknown alkane
Unknown
Unknown
Unknown
Unknown
Unknown alkene
Unknown
Result
360
29
52
380
33
51
31
30
36
45
150
49
34
26
57
77
58
42
30
27
Units
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
Received: 30 JUL 98
Analyzed: 31 AUG 98
Reporting
Limit Qualifier
0
0
0
0
0
0
Note 0 = Or structurally similar compound (isomer).
NA « Not Applicable
Reported By: Emily Uebelhoer
Approved By: Karin Yee
41
The cover letter is an integral part of this report.
Rev 230787
-------
Semlvolatile Organics
Method 0010/8270
Client Name: Pacific Environmental Services
Client ID: S-MM5-RB-F,FH,XAD,COND,BH
LAB ID: 300681-0009-SA
Matrix: AIRTRAIN Sampled: 25 JUL 98
Authorized: 30 JUL 98 Prepared: 31 OUL 98
Dilution Factor: 1.0
Parameter
Phenol
bis(2-Chloroethyl)ether
2-Chlorophenol
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Benzyl alcohol
1,2-Dichlorobenzene
2-Methylphenol
2,2'-Oxybi s(1-chloropropane)
3/4-Metnylphenol
N-Nitroso-di-n-propylamine
Hexachloroethane ;
Nitrobenzene
Isophorone
2-Nitrophenol
2,4-Di methyl phenol
Benzoic acid
bi s(2-Chloroethoxy)-methane
2,4-Dichlorophenol
1,2,4-Trichlorobenzene
Naphthalene
4-Chloroaniline
Hexachlorobutadiene
4-Chloro-3-methylphenol
2-Methylnaphtha!ene
Hexachlorocyclopentadiene
2,4,6-Tri chlorophenol
2,4,5-Trichlorophenol
2-Chloronaphthalene
2-Nitroaniline
Dimethyl phthalate
Acenaphthylene
3-Nitroaniline
Acenaphthene
2,4-Dinitrophenol
4-Nitrophenol
Dibenzofuran
Wet wt.
Result
Units
Received: 30 OUL 98
Analyzed: 31 AUG 98
Reporting
Limit
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ug/Sampl e
ug/Sampl e
ug/Sampl e
ug/Sampl e
ug/Sampl e
ug/Sampl e
ug/Sampl e
ug/Sampl e
ug/ Sample
ug/ Sample
ug/ Sample
ug/S ample
ug/Sampl e
ug/Sampl e
ug/Sampl e
ug/Sampl e
ug/Sampl e
ug/Sampl e
ug/Sampl e
ug/Sampl e
ug/S ample
ug/Sampl e
ug/S ample
ug/Sampl e
ug/Sampl e
ug/Sampl e
ug/Sampl e
ug/Sampl e
ug/Sampl e
ug/S ample
ug/Sampl e
ug/Sampl e
ug/Sampl e
ug/Sampl e
ug/Sampl e
ug/S ample
ug/S ample
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
150
30
30
30
30
30
30
30
30
30
30
150
30
30
30
30
150
30
150
150
30
Qualifier:
R
Note R = Reporting limit{s) raised due to sample volume limitations.
ND = Not Detected
Reported By: Emily Uebelhoer
Approved By: Karin Yee
The cover letter is art integral part of this report.
Rev 230787
-------
Semi volatile Organics
Method 0010/8270
(cont.)
Client Name: Pacific Environmental Services
Client ID: S-MM5-RB-F,FH,XAD,COND,BH
LAB ID: 300681-0009-SA
Matrix: AIRTRAIN Sampled: 25 JUL 98
Authorized: 30 JUL 98 Prepared: 31 JUL 98
Dilution Factor: 1.0
Parameter
2,4-Dinitrotoluene
2,6-Dinitrotoluene
Diethyl phthalate
4-Chlorophenyl phenyl ether
Fluorene
4-Nitroaniline
4,6-Dinitro-2-methylphenol
N-Nitrosodiphenylamine
4-Bromophenyl phenyl ether
Hexachlorobenzene
Pentachlorophenol
Phenanthrene
Anthracene
Di-n-butyl phthalate
Fluoranthene
Pyrene
Butyl benzyl phthalate
3,3'-Dichlorobenzidine
Benzo(a)anthracene
bi s(2-Ethylhexyl)-phthalate
Chrysene
Di-n-octyl phthalate
Benzo b)fluoranthene
Benzo k)fluoranthene
Benzo ajpyrene
Indeno(1,2,3-cd)pyrene
Dibenz(a,h)anthracene
Benzo(g,h,i)perylene
Acetophenone
4-Aminobiphenyl
Aniline
Benzidine
3,3'-Dimethylbenzidine
N-Nitrosodimethyl amine
N-Nitrosomorphol ine
Pentachloronitrobenzene (PCNB)
o-Toluidine
Wet wt.
Result
Units
Received: 30 JUL 98
Analyzed: 31 AUG 98
Reporting
Limit
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
30
30
30
30
30
150
150
30
30
30
150
30
30
30
30
30
30
60
30
30
30
30
30
30
30
30
30
30
30
150
30
300
60
30
30
150
60
Qualifier
ND = Not Detected
Reported By: Emily Uebelhoer
Approved By: Karin Yee
The cover letter is an integral part of this report.
Rev 230787
43
-------
Semivolatile Organics
Method 0010/8270
(cont.)
Client Name: Pacific Environmental Services
Client ID: S-MM5-RB-F,FH,XAD,COND,BH
LAB ID: 300681-0009-SA
Matrix: AIRTRAIN Sampled: 25 JUL 98
Authorized: 30 JUL 98 Prepared: 31 JUL 98
Dilution Factor: 1.0
Wet wt.
Parameter Result Units
2-Methoxybenzenamine ND ug/Sample
Biphenyl ND ug/Sample
Chloroacetophenone ND ug/Sample
Cumene ND ug/Sample
DBCP (l,2-Dibromo-3-chloropropane) ND ug/Sample
Benzo(e)pyrene ND ug/Sample
N-N-Dietnylaniline ND ug/Sample
Dimethyl aniline ND ug/Sample
3,3'-Dimethoxybenzidine ND ug/Sample
Hydroquinone ND ug/Sample
4,4'-Methyl-bis(2-chloroaniline) ND ug/Sample
4-Nitrodiphenyl ND ug/Sample
Trifluralin ND ug/Sample
Received: 30 JUL 9fl
Analyzed: 31 AUG 98
Re
imit Qualifier
K
K
K
K
K
K
K
K
K
K
K
K
K
Surrogate
Nitrobenzene-d5
2-Fluorobiphenyl
Terphenyl-dl4
Phenol-d5
2-Fluorophenol
2,4,6-Tri bromophenol
Recovery
61 %
86 %
97 %
67 %
62 %
84 %
Acceptable Range
45 - 107
62 - 110
58 - 135
43 - 130
36 - 111
58 - 131
Note K = Identified by mass spectrum only; quantitation based on 1:1 response with
internal standard.
ND = Not Detected
Reported By: Emily Uebelhoer
Approved By: Karin Yee
The cover letter is an integral part of this report,
Rev 230787
44
-------
Semivolatiles Library Search (20 Compound TID)
Method 8270
Client Name:
Client ID:
LAB ID:
Matrix:
Authorized:
Pacific Environmental Services
S-MM5-RB-F,FH,XAD,COND,BH
300681-0009-SA
AIRTRAIN Sampled: 25 JUL 98
30 JUL 98 Prepared: NA
Dilution Factor: 1.0
Parameter
n-Nonane
Unknown
Unknown
Unknown
Unknown
Unknown
Unknown
5-Eiconsene,(E) -
Unknown
Unknown
Unknown alkane
Unknown
Unknown
4-Hydroxy-4-methyl-2-pentanone
Unknown
Unknown
Unknown
9-Eicosene (E)-
Unknown
Unknown
Result
400
51
77
71
42
63
99
250
94
63
27
35
140
270
110
81
26
57
61
72
Units
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
Received: 30 JUL 98
Analyzed: 31 AUG 98
Reporting
Limit
Qualifier
0
0
Note 0 = Or structurally similar compound (isomer).
NA = Not Applicable
Reported By: Emily Uebelhoer
Approved By: Karin Yee
The cover letter is an integral part of this report.
Rev 230787
-------
Semlvolatile Organics
Method 0010/8270
Client Name: Pacific Environmental Services
Client ID: S-MM5-4-F,FH,XAD,COND,BH
LAB ID: 300681-0010-SA
Matrix: AIRTRAIN Sampled:
Authorized: 30 JUL 98 Prepared:
25 JUL 98
31 JUL 98
Dilution Factor: 100
Parameter
Phenol
bis(2-ChloroethylJether
2-Chlorophenol
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Benzyl alcohol
1,2-Dichlorobenzene
2-Methylphenol
2,2'-Oxybi s(1-chloropropane)
3/4-Methylphenol
N-Nitroso-di-n-propylaraine
Hexachloroethane
Nitrobenzene
Isophorone
2-Nitrophenol
2,4-Dimethylphenol
Benzole acid
bi s(2-Chl oroethoxy)-methane
2,4-Dichlorophenol
1,2,4-Trichlorobenzene
Naphthalene
4-Chloroaniline
Hexachlorobutadi ene
4-Chloro-3-methylphenol
2-Methylnaphthalene
Hexachlorocyclopentadi ene
2,4,6-Tri chlorophenol
2,4,5-Trichl orophenol
2-ChloronaphthaJene
2-Nitroaniline
Dimethyl phthalate
Acenaphthylene
3-Nitroaniline
Acenaphthene
2,4-Dinitrophenol
Wet wt.
Result
Units
Received: 30 JUL 98
Analyzed: 31 AUG 98
Reporting
Limit
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
1500
ND
ND
ND
2300
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ug/S ample
ug/S ample
ug/Sample
ug/Sample
ug/S amp 1 e
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/S amp 1 e
ug/Sample
ug/Sampl e
ug/Sample
ug/Sample
ug/Sample
ug/Sampl e
ug/Sampl e
ug/Sample
ug/Sample
ug/Sampl e
ug/Sample
ug/Sampl e
ug/Sample
ug/Sample
ug/Sampl e
ug/Sample
ug/Sampl e
ug/Sampl e
ug/Sample
ug/Sampl e
ug/Sampl e
ug/Sample
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
15000
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
15000
3000
3000
3000
3000
15000
3000
15000
Qualifier
GR
Note G = Reporting limit(s) raised due to matrix interference.
Note J = Result is detected below the reporting limit or is an estimated, concentration.
Note R = Reporting-Mmit(s) raised due to sample volume limitations.
ND = Not Detected
Reported By: Emily Uebelhoer
Approved By: Mike Orbanosky
The cover letter is an interal part of this report.
Rev 23
egral
30787
-------
Semi volatile Organics
Method 0010/§270
(cont.)
Client Name: Pacific Environmental Services
Client ID:
LAB ID:
Matrix:
Authorized:
S-MM5-4-F,FH,XAD,COND,BH
300681-0010-SA
AIRTRAIN
30 JUL 98
Sampled: 25 JUL 98
Prepared: 31 JUL 98
Dilution Factor: 100
Parameter
4-Nitrophenol
Dibenzofuran
2,4-Dinitrotoluene
2,6-Dinitrotoluene
Di ethyl phthalate
4-Chlorophenyl phenyl ether
Fluorene
4-Nitroaniline
4,6-Dinitro-2-methylphenol
N-Ni trosodi phenylami ne
4-Bromophenyl phenyl ether
Hexachlorobenzene
Pentachlorophenol
Phenanthrene
Anthracene
Di-n-butyl phthalate
Fluorantnene
Pyrene
Butyl benzyl phthalate
3,3'-Dichlorobenzidine
Benzo(a)anthracene
bis(2-Ethylhexyl)-phthalate
Chrysene
Di-n-octyl phthalate
Wet wt.
Result
Benzo
Benzo
Benzo
Indenof
fluoranthene
fluoranthene
pyrene
*nuc,,w, ,2,3-cd)pyrene
Dibenz(a,h)anthracene
Benzo(g,h,i)perylene
Acetophenone
4-Aminobiphenyl
Aniline
Benzidine
3,3'-Dimethylbenzidine
N-Nitrosodimethylamine
N-Nitrosomorphol ine
Units
Received: 30 JUL 98
Analyzed: 31 AUG 98
Reporting
Limit
Qualifier
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
590
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ug/Sampl e
ug/Sample
ug/Sampl e
ug/Sampl e
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sampl e
ug/Sample
ug/Sampl e
ug/Sampl e
ug/Sample
ug/Sampl e
ug/Sampl e
ug/Sampl e
ug/Sample
ug/Sample
ug/Sample
ug/Sampl e
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sampl e
ug/Sample
ug/Sample
ug/Sample
ug/Sampl e
ug/Sample
ug/Sample
ug/Sampl e
ug/Sample
ug/Sampl e
ug/Sample
ug/Sample
15000
3000
3000
3000
3000
3000
3000
15000
15000
3000
3000
3000
15000
3000
3000
3000
3000
3000
3000
6000
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
15000
3000
30000
6000
3000
3000
Note J = Result is detected below the reporting limit or is an estimated concentration.
ND = Not Detected
Reported By: Emily Uebelhoer
Approved By: Mike Orbanosky
The cover letter is an integral part of this report.
Rev 230787
-------
Client Name:
Client ID:
LAB ID:
Matrix:
Authorized:
Semi volatile Organics
Method 0010/8270
Pacific Environmental Services
S-MM5-4-F,FH,XAD,COND,BH
300681-0010-SA
AIRTRAIN Sampled: 25 JUL 98
30 JUL 98 Prepared: 31 JUL 98
(cont.)
Dilution Factor: 100
Parameter
(PCNB)
Pentachloronitrobenzene
o-Toluidine
2-Methoxybenzenami ne
Biphenyl
Chloroacetophenone
Cumene
DBCP (l,2-Dibromo-3-chloropropane)
Benzo(e)pyrene
N-N-Diethylaniline
Dimethylaniline
3,3'-Dimethoxybenzidine
Hydroquinone
4,4'-Methyl-bis(2-chloroani1ine)
4-Nitrodiphenyl
Trifluralin
Wet wt.
Result
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
NO
ND
ND
NO
Units
ug/Sample
ug/Sampl e
ug/Sampl e
ug/Sampl e
ug/Sampl e
ug/Sampl e
ug/Sampl e
ug/Sampl e
ug/Sample
ug/Sample
ug/Sampl e
ug/Sampl e
ug/Sample
ug/Sample
ug/Sample
Reporting
Limit
15000
6000
--
--
--
--
--
--
--
--
—
—
—
--
--
Received: 30 JUL 98
Analyzed: 31 AUG 98
Qualifier
Surrogate
Nitrobenzene-d5
2-Fluorobiphenyl
Terphenyl-dl4
Phenol-d5
2-Fluorophenol
2,4,6-Tri bromophenol
Recovery
ND %
ND %
ND %
ND %
ND %
ND %
Acceptable Range
45 - 107
62 - 110
58 -.135
43 - 130
36 - 111
58 - 131
Note H = Spiked analyte not detected tecause of required sample dilution.
ND = Not Detected
Reported By: Enrily Uebelhoer
Approved By: Mike Orfaanosky
The cover letter is an integral part of this report.
Rev 230787
-------
Semivolatiles Library Search (20 Compound TID)
Method 8270
Client Name: Pacific Environmental Services
Client ID:
LAB ID:
Matrix:
Authorized:
S-MM5-4-F,FH,XAD,COND,BH
300681-0010-SA
AIRTRAIN
30 JUL 98
Sampled: 25 JUL 98
Prepared: NA
Dilution Factor: 100
Parameter Result Units
Undecane 7600 ug/Sample
Unknown 7500 ug/Sample
Unknown alkane 7100 ug/Sample
Decane, 2,5,9-Trimethyl- 6200 ug/Sample
Unknown 12000 ug/Sample
Unknown alkane 12000 ug/Sample
Unknown hydrocarbon 6900 ug/Sample
Octane, 3,5-dimethyl- 9800 ug/Sample
Unknown 6400 ug/Sample
Heptadecane, 2,6-dimethyl- 13000 ug/Sample
Tetradecane 18000 ug/Sample
Unknown 8600 ug/Sample
Heptadecane, 2,6,10,14 -tetramethyl- 12000 ug/Sample
Pentadecane 14000 ug/Sample
Unknown 6400 ug/Sample
Nonadecane 16000 ug/Sample
Undecane, 2,6-dimethyl- 13000 ug/Sample
Heptadecane, 2,6-dimethyl- 28000 ug/Sample
Unknown alkane 7600 ug/Samole
Heptadecane, 2,6-dimethyl- 9800 ug/Sample
Received: 30 JUL 98
Analyzed: 31 AUG 98
Reporting
Limit Qualifier
0
0
0
0
0
0
Note 0 = Or structurally similar compound (isomer).
NA = Not Applicable
Reported By: Emily Uebelhoer
Approved By: Mike Orbanosky
The cover letter is an integral part of this report.
Rev 230787
-------
Semi volatile Organics
Method 0010/8270
Client Name:
Client ID:
LAB ID:
Matrix:
Authorized:
Pacific Environmental Services
S-MM5-5-F,FH,XAD,COND,BH
300681-0011-SA
AIRTRAIN
30 JUL 98
Dilution Factor: 100
Parameter
Phenol
bi s (2-Chl oroethyl )ether
2-Chl orophenol
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Benzyl alcohol
1,2-Dichlorobenzene
2-Methyl phenol
2,2' -Oxybi s ( 1 -chl oropropane)
3/4-Methyl phenol
N-Nitroso-di -n-propyl amine
Hexachloroethane
Nitrobenzene
Isophorone
2-Nitrophenol
2, 4-Dimethyl phenol
Benzole acid
bi s (2-Chl oroethoxy) -methane
2,4-Dichlorophenol
1 , 2 , 4-Tr i chl orobenzene
Naphthalene
4-Chloroaniline
Hexachlorobutadiene
4-Chloro-3-methl henol
2-Methyl naphtha! ene
Hexachlorocyclopentadiene
2,4,6-Trichlorophenol
2, 4, 5-Tri chl orophenol
2-Chl oronaphthalene
2-Nitroaniline
Dimethyl phthalate
Acenaphthylene
3-Nitroaniline
Acenaphthene
2,4-Dinitrophenol
Sampl ed :
Prepared:
Wet wt.
Result
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
2600
ND
ND
ND
4400
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
28 JUL 98
31 JUL 98
Units
ug/Sampl e
ug/Sample
ug/Sampl e
ug/Sampl e
ug/Sample
ug/Sample
ug/Sample
ug/Sampl e
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sampl e
ug/Sampl e
ug/Sampl e
ug/Sampl e
ug/Sampl e
ug/Sampl e
ug/Sampl e
ug/Sampl e
ug/Sample
ug/Sampl e
ug/Sampl e
ug/Sampl e
ug/Sample
ug/Sample
ug/Sampl e
ug/Sampl e
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sampl e
Received: 30 JUL 98
Analyzed: 31 AUG 98
Reporting
Limit
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
15000
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
15000
3000
3000
3000
3000
15000
3000
15000
Qualifier
GR
Note G = Reporting limit(s) raised due to matrix interference.
Note J = Result is detected below the reporting limit or; .is, an estimated concentration.
Note R = Reporting limit(s) raised due ta sample volume limitations.
NO = Not Detected
Reported By: Emily UebeUraer
Approved By: Mike Orbanosky
The cover letter is an integral part of this report.
Rev 230787
-------
Semi volatile Organics
Method 0010/8270
(cent.)
Client Name:
Client ID:
LAB ID:
Matrix:
Authorized:
Pacific Environmental Services
S-MM5-5-F,FH,XAD,COND,BH
300681-0011-SA
AIRTRAIN Sampled:
30 JUL 98 Prepared:
28 JUL 98
31 JUL 98
Dilution Factor: 100
Parameter
4-Nitrophenol
Dibenzofuran
2,4-Dinitrotoluene
2,6-Dinitrotoluene
Diethyl phthalate
4-Chlorophenyl phenyl ether
Fluorene
4-Nitroaniline
4,6-Dinitro-2-methylphenol
N-Nitrosodiphenylamine
4-Bromophenyl phenyl ether
Hexachlorobenzene
Pentachlorophenol
Phenanthrene
Anthracene
Di-n-butyl phthalate
Fluoranthene
Pyrene
Butyl benzyl phthalate
3,3'-Dichlorobenzidine
Benzo(a)anthracene
bi s(2-Ethylhexyl)-phthalate
Chrysene
Di-n-octyl phthalate
Wet wt.
Result
Benzo
Benzo
Benzo
fluoranthene
fluoranthene
pyrene
Indenofl,2,3-cd)pyrene
Dibenz(a,h)anthracene
Benzo(g, h, i)perylene
Acetopnenone
4-Aminobiphenyl
Aniline
Benzidine
3,3'-Dimethylbenzidine
N-Ni trosodimethylami ne
N-Nitrosomorpholine
Units
Received: 30 JUL 98
Analyzed: 31 AUG 98
Re
imit Qualifier
ND
NO
ND
ND
ND
ND
560
ND
ND
ND
ND
ND
ND
1200
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sampl e
ug/Sampl e
ug/Sample
ug/Sampl e
ug/Sampl e
ug/Sample
ug/Sampl e
ug/Sampl e
ug/Sample
ug/Sampl e
ug/Sample
ug/Sampl e
ug/Sample
ug/Sample
ug/Sampl e
ug/Sample
ug/Sampl e
ug/Sampl e
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sampl e
ug/Sample
ug/Sample
ug/Sampl e
ug/Sample
ug/Sampl e
ug/Sampl e
ug/Sample
ug/Sample
ug/Sample
ug/Sampl e
15000
3000
3000
3000
3000
3000
3000
15000
15000
3000
3000
3000
15000
3000
3000
3000
3000
3000
3000
6000
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
15000
3000
30000
6000
3000
3000
Note J = Result is detected below the reporting limit or is an estimated concentration.
ND = Not Detected
Reported By: Emily Uebelhoer
Approved By: Mike Orbanosky
The cover letter is an integral part of this report.
Rev 230787
-------
Semivolatile Organics
Method 0010/8270
(cont.)
Client Name: Pacific Environmental Services
Client ID: S-MM5-5-F,FH,XAD,COND,BH
LAB ID: 300681-0011-SA
Matrix: AIRTRAIN Sampled:
Authorized: 30 JUL 98 Prepared:
Dilution Factor: 100
28 JUL 98
31 JUL 98
Parameter
(PCNB)
Pentachloroni trobenzene
o-Toluidine
2-Methoxybenzenamine
Biphenyl
Chioroacetophenone
Cumene
DBCP n,2-Dibromo-3-chloropropane)
Benzo(e)pyrene
N-N-Diethylaniline
Dimethyl aniline
3,3'-Dimethoxybenzidine
Hydroquinone
4,4'-Methyl-bis(2-chloroaniline)
4-Nitrodiphenyl
Trifluralin
Wet wt.
Result
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Units
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sampl e
ug/Sampl e
Reporting
Limit
15000
6000
--
--
--
--
--
--
__
--
—
--
—
--
--
Received: 30 JUL 98
Analyzed: 31 AU6 98
Qualifier
Surrogate
Nitrobenzene-d5
2-Fluorobiphenyl
Terphenyl-dl4
Phenol-d5
2-Fluorophenol
2,4,6-Tri bromophenol
Recovery
ND %
ND %
ND %
ND %
ND %
ND %
Acceptable Range
45 - 107
62 - 110
58 - 135
43 - 130
36 - 111
58 - 131
Note H = Spiked analyte not detected because of required sample dilution.
ND = Not Detected
Reported By: Emily Uebeliioer
Approved By: ilike Orbanosky
52
The cover letter is an integral part of this report.
Rev 235787
-------
Semivolatiles Library Search (20 Compound TID)
Method 8270
Client Name: Pacific Environmental Services
Client ID: S-MM5-5-F,FH,XAD,COND,BH
LAB ID: 300681-0011-SA
Matrix: AIRTRAIN Sampled:
Authorized: 30 JUL 98 Prepared:
Dilution Factor: 100
28 JUL 98
NA
Parameter Result Units
Unknown 11000 ug/Sample
Unknown 13000 ug/Sample
Decane. 2,9-dimethyl- 9200 ug/Sample
Undecane, 2,6-dimethyl- 9500 ug/Sample
Unknown 15000 ug/Sample
Unknown alkane 20000 ug/Sample
Unknown 12000 ug/Sample
Unknown alkane 11000 ug/Sample
Unknown 10000 ug/Sample
Unknown 12000 ug/Sample
Dodecane, 2,6,10-trimethyl- 19000 ug/Sample
Tetradecane 25000 ug/Sample
Unknown 15000 ug/Sample
Heptadecane, 2,6,10,14 -tetramethyl- 22000 ug/Sample
Dodecane, 3-methyl- 25000 ug/Sample
Oxirane, hexadecyl- 13000 ug/Sample
Unknown alkane 27000 ug/Sample
Unknown alkane 14000 ug/Sample
Heptadecane, 2,6-dimethyl- 28000 ug/Sample
Nonadecane 11000 ug/Sample
Received: 30 JUL 98
Analyzed: 31 AUG 98
Reporting
Limit Qualifier
0
0
0
0
0
0
0
0
0
Note 0 = Or structurally similar compound (isomer).
NA = Not Applicable
Reported By: Emily Uebelhoer
Approved By: Mike Orbanosky
53
The cover letter is an integral part of this report.
Rev 230787
-------
QC LOT ASSIGNMENT REPORT - MS QC
Semivolatile Organics by 6C/MS
Laboratory QC Lot Number QC Run Number MS QC Run Number
Sample Number QC Matrix QC Category (DCS) (SCS/BLANK/LCS) (SA,MS,SD,DU)
300681-0003-SA FILTER 8270-G 31 JUL 98-16A 31 JUL 98-16A
300681-0004-SA FILTER 8270-G 31 JUL 98-16A 31 JUL 98-16A
300681-0005-SA FILTER 8270-G 31 JUL 98-16A 31 JUL 98-16A
300681-0006-SA FILTER 8270-G 31 JUL 98-16A 31 JUL 98-16A
300681-0008-SA FILTER 8270-G 31 JUL 98-16A 31 JUL 98-16A
300681-0009-SA FILTER 8270-G 31 JUL 98-16A 31 JUL 98-16A
-------
METHOD BLANK REPORT
Semi volatile Organics by GC/MS
Project: 300681
Test:
Method:
Matrix:
QC Lot:
8270-TCL-G
0010/8270
FILTER
31 JUL 98-16A
Semivolatile Organics
Analyzed: 31 AUG 98
Analyte
Phenol
bis(2-Chloroethyl)ether
2-Chlorophenol
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Benzyl alcohol
1,2-Di chlorobenzene
2-Methylphenol
2,2'-Oxybi s(1-chloropropane)
3/4-Metnylphenol
N-Ni troso-di-n-propylamine
Hexachloroethane
Nitrobenzene
Isophorone
2-Nitrophenol
2,4-Dimethylphenol
Benzoic acid
bis(2-Chloroethoxy)-methane
2,4-Dichlorophenol
1,2,4-Trichlorobenzene
Naphthalene
4-Chloroaniline
Hexachlorobutadiene
4-Chloro-3-methylphenol
2-Methylnaphtha 1ene
Hexachlorocyclopentadiene
2,4,6-Trichlorophenol
2,4,5-Trichlorophenol
2-Chloronaphthalene
2-Nitroaniline
Dimethyl phthalate
Acenaphthylene
3-Nitroaniline
Acenaphthene
2,4-Dinitrophenol
4-Nitrophenol
Dibenzofuran
2,4-Dinitrotoluene
2,6-Dinitrotoluene
Diethyl phthalate
4-Chlorophenyl phenyl ether
Fluorene
4-Nitroaniline
4,6-Dinitro-2-methylphenol
N-Nitrosodiphenylamine
NO = Not Detected
QC Run:
Time:
31 JUL 98-16A
16:02
Result
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Units
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
Reporting
Limit
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
50
10
10
10
10
10
10
10
10
10
10
50
10
10
10
10
50
10
50
50
10
10
10
10
10
10
50
50
10
Qualifier
-------
METHOD BLANK REPORT (cont.)
Semi volatile Organics by GC/MS
Project: 300681
Test:
Method:
Matrix:
QC Lot:
8270-TCL-G
0010/8270
FILTER
31 JUL 98-16A
Semi volatile Organics
Analyzed: 31 AUG 98
Analyte
4-Bromophenyl phenyl ether
Hexachlorobenzene
Pentachlorophenol
Phenanthrene
Anthracene
Di-n-butyl phthalate
Fluoranthene
Pyrene
Butyl benzyl phthalate
3,3'-Dichlorobenzidine
Benzo(a)anthracene
bi s(2-Ethylhexyl)-phthalate
Chrysene
Di-n-octyl phthalate
QC Run: 31 OUL 98-16A
Time: 16:02
Benzo
Benzo
Benzo
Indenof
fluoranthene
fluoranthene
pyrene
,2,3-cd)pyrene
Dibenz(a,hjanthracene
Benzo(g,h,i)perylene
Acetophenone
4-Aminobiphenyl
Aniline
Benzidine
3,3'-Dimethylbenzidine
N-Nitrosodimethylamine
N-Nitrosomorpholine
Pentachloronitrobenzene (PCNB)
o-Toluidine
2-Methoxybenzenamine
Biphenyl
Chioroacetophenone
Cumene
DBCP (1,2-Dibromo-3-chloropropane)
Benzo(e)pyrene
N-N-Diethylaniline
Dimethylaniline
3,3'-Dimethoxybenzidine
Hydroquinone
4,4'-Methyl-bis(2-chloroaniline)
4-Nitrodiphenyl
Trifluralin
Result
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Units
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
Re
porting
Limit
Qualifier
10
10
50
10
10
10
10
10
10
20
10
10
10
10
10
10
10
10
10
10
10
50
10
100
20
10
10
50
20
ND = Not Detected
-------
METHOD BLANK REPORT (cont.)
Semi volatile Organics by GC/MS
Project: 300681
Surrogate
Nitrobenzene-d5
2-Fluorobiphenyl
Terphenyl-d!4
Phenol-d5
2-Fluorophenol
2,4,6-Tribromophenol
% Recovery
86
102
106
85
82
94
Acceptable Range
45 -107
62 -110
58 -135
43 -130
36 -111
58 -131
57
-------
DUPLICATE CONTROL SAMPLE REPORT
Semi volatile Organics by GC/MS
Project: 300681
Category: 8270-G Acid, Base and Neutrals by GC/MS.
Testcode: 8270-TCL-G Method: 0010/8270
Matrix- FILTER Concentration Units: ug/sample
31 JUL 98-16A Analyzed Date: 31 AUG 98 Time: 18:30
QC Lot:
Analyte
Phenol
2-Chlorophenol
1,4-Dichlorobenzene
N-Nitroso-di-
n-propylamine
1,2,4-
Trichlorobenzene
4-Chloro-3-
methylphenol
Acenaphthene
4-Nitrophenol
2,4-Dinitrotoluene
Pentachlorophenol
Pyrene
Surrogate
Nitrobenzene-d5
2-Fluorobiphenyl
Terphenyl-dl4
Phenol-d5
2-Fluorophenol
2,4,6-Tribromophenol
Spiked
100
100
50.0
50.0
50.0
100
50.0
100
50 rO
100
50.0
-ouin-enur
DCS1
83.4
83.7
43.4
38.3
43.1
78.6
46.6
78.8
45^3
83.4
48.0
at IUM
MaaciivoH_«*_ — —
• PlcaS UlcU--- —
DCS2
87.9
87.9
44.9
40.9
45.9
85.8
50.2
89.6
49.0
93.6
50.7
Spiked
50
50
50
100
100
100
•-ULMH-CIIUI au iuu
DCS1
40
45
40
80
77
84
DCS2
40
46
40
81
74
84
Accuracy
DCS1
83
84
87
77
86
79
93
79
91
83
96
0)
DCS2
88
88
90
82
92
86
100
90
98
94
101
Accuracy (%)
DCS1
79
90
79
80
77
84
DCS2
79
92
80
81
74
84
Precision
(RPD)
Limits DCS Limit
47-108
47-113
42-114
46-107
45-118
55-118
54-119
43-166
^9-113
59-128
45-140
Limits
45-107
62-110
58-135
43-130
36-111
58-131
5.3 18
4.9 20
3.4 22
6.6 15
6.3 16
8.8
7.4
13
7.8
12
5.5
13
10
17
10
10
11
Note *: Outside of RPD limits. .
Calculations are performed before rounding to avoid round-off errors in calculated results,
-------
Client Name:
Client ID:
Lab ID:
Matrix:
Authorized:
Parameter
POLYNUCLEAR AROMATIC HYDROCARBONS
HIGH RESOLUTION GC/MS
Method HRGC/HRMS
Pacific Environmental Services
Method Blank
300681-0001-MB
AIRTRAIN Sampled: NA
30 JUL 98 Prepared: 31 JUL 98
Received: NA
Analyzed: 20 AUG 98
Naphthalene
2-Methylnaphtha!ene
Acenaphthylene
Acenaphthene
Fluorene
Phenanthrene
Anthracene
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
Benzo
Benzo
Benzo
fluoranthene
fluoranthene
pyrene
Benzo a pyrene
Perylene
IndenoH, 2,3-cd) pyrene
Di benz(a, h)anthracene
Benzo(g,h,i)perylene
Surrogate
Naphthalene-d8
Acenaphthylene-d8
Acenaphthene-dlO
Fluorene-dlO
Phenanthrene-dlO
Fluoranthene-dlO
Pyrene-dlO
Benzo(a)anthracene-dl2
Chrysene-dl2
fluoranthene-d!2
fluoranthene-d!2
pyrene-d!2
Benzo
Benzo
Benzo _
Perylene-d!2
Indeno(123-cd)pyrene-dl2
Dibenz(a,h)anthracene-dl4
Benzo(g,h,i)perylene-d!2
Field Surrogate
13C-Fluorene
ND = Not detected
NA = Not applicable
Reported By: Mike Flournoy
Result
280
120
ND
43
43
82
ND
16
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Recovery
86
62
71
77
72
82
84
77
92
92
100
80
87
92
84
98
96
Units
Re
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
Limit
6.6
7.2
8.6
0.85
1.4
2.8
2.2
4.3
3.2
2.5
5.5
3.1
3.7
Approved By: Andre Algazi
The cover letter is an integral part of this report.
Rev 230787
59
Y
-------
Client Name:
Client ID:
Lab ID:
Matrix:
Authorized:
Parameter
POLYNUCLEAR AROMATIC HYDROCARBONS
HIGH RESOLUTION GC/MS
Method HRGC/HRMS
Pacific Environmental Services
S-MM5-2-F,FH,XAD,COND,BH
300681-0001-SA
AIRTRAIN Sampled: 25 JUL 98
30 JUL 98 Prepared: 31 JUL 98
Received: 30 JUL 98
Analyzed: 06 OCT 98
Naphthalene
2-Methylnaphthalene
Acenaphthylene
Acenaphthene
Fluorene
Phenanthrene
Anthracene
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
Benzo b)fluoranthene
Benzo k fluoranthene
Benzo e pyrene
Benzo a pyrene
Perylene
Indeno(l,2,3-cd)pyrene
Dibenz(a,h)anthracene
Benzo(g,h,i)perylene
Surrogate
Naphtha!ene-d8
Acenaphthylene-d8
Acenaphthene-dlO '
Fluorene-dlO
Phenanthrene-dlO
Fluoranthene-dlO
Pyrene-dlO
Benzo(a)anthracene-dl2
Perylene-dl2
Indeno(123-cd)pyrene-dl2
Chrysene-dl2
Benzo(b)f1uoranthene-d!2
Benzo(k)f1uoranthene-d!2
Benzo(a)pyrene-dl2
Oibenz(a,h)anthracene-dl4
Benzo(g,h,i)perylene-d!2
Result
800
2800
ND
190
600
970
57
55
230
17
64
ND
ND
ND
ND
21
ND
ND
ND
Recovery
90
140
127
96
102
34
33
38
98
95
32
128
101
98
87
86
Units
ug/sample
ug/sample
ug/sample
ug/sample
ug/sample
ug/sample
ug/sample
ug/sample
ug/sample
ug/sample
ug/sample
ug/sample
ug/sample
ug/sample
ug/sample
ug/sample
ug/sample
ug/sample
ug/sample
Reporting
Limit
15
15
15
15
15
15
15
15
15
15
15
15
15
15
15
15
15
15
15
m
m
m
m
ND = Not detected
NA = Not applicable
(continued on following page)
Reported By: Mike Flournoy
Approved By: Eric Redman
The cover letter is an integral part of this report.
Rev 230787
60
-------
POLYNUCLEAR AROMATIC HYDROCARBONS
HIGH RESOLUTION GC/MS (CONT.)
Method HRGC/HRMS
Client Name: Pacific Environmental Services
Client ID: S-MM5-2-F,FH,XAD,COND,BH
Lab ID: 300681-0001-SA
Matrix: AIRTRAIN Sampled: 25 JUL 98 Received: 30 JUL 98
Authorized: 30 JUL 98 Prepared: 31 JUL 98 Analyzed: 06 OCT 98
Field Surrogate
13C-Fluorene NA %
Note m : Internal Standard recovery is outside method recovery goal.
NO = Not detected
NA = Not applicable
Reported By: Mike Flournoy Approved By: Eric Redman
The cover letter is an integral part of this report. 6l
Rev 230787
-------
Client Name:
Client ID:
Lab ID:
Matrix:
Authorized:
Parameter
POLYNUCLEAR AROMATIC HYDROCARBONS
HIGH RESOLUTION GC/MS
Method HRGC/HRMS
Pacific Environmental Services
T-MM5-2-F,FH,XAD,COND,BH
300681-0003-SA
AIRTRAIN Sampled: 25 JUL 98
30 JUL 98 Prepared: 31 JUL 98
Received: 30 JUL 98
Analyzed: 21 AUG 98
Naphthalene
2-Methylnaphtha!ene
Acenaphthylene
Acenaphthene
Fluorene
Phenanthrene
Anthracene
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
Benzo
Benzo
Benzo
Benzo
fluoranthene
fluoranthene
pyrene
pyrene
Perylene
Indenofl,2,3-cd)pyrene
Dibenz(a,hjanthracene
Benzo(g, h, i)perylene
Surrogate
Naphtha!ene-d8
Acenaphthylene-d8
Acenaphthene-dlO
Fluorene-dlO
Phenanthrene-dlO
Fluoranthene-dlO
Pyrene-dlO
Benzo(a)anthracene-dl2
Chrysene-dl2
Benzo
Benzo
Benzo
fluoranthene-dl2
fluoranthene-d!2
pyrene-d!2
Perylene-d!2
Indeno(123-cd)pyrene-dl2
Dibenz(a,h)anthracene-dl4
Benzo(g,h,i)perylene-d!2
Result
19000
38000
470
4500
21000
21000
1700
1200
3200
370
2100
160
47
180
48
530
20
16
44
Recovery
65
73
56
42
61
30
30
62
52
101
67
83
62
174
181
177
Units
Reporting
Limit
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
EB
EB
EB
EB
EB
E
EB
E
m
m
m
m
m
m
NO = Not detected
NA = Not applicable
Reported By: Mike Flournoy
(continued on following page)
Approved By: Andre Algazi
The cover letter is an integral part of this report.
Rev 230787
-------
POLYNUCLEAR AROMATIC HYDROCARBONS
HIGH RESOLUTION GC/MS (CONT.)
Method HRGC/HRMS
Client Name: Pacific Environmental Services
Client ID: T-MM5-2-F,FH,XAD,COND,BH
Lab ID: 300681-0003-SA
Matrix: AIRTRAIN Sampled: 25 JUL 98 Received: 30 JUL 98
Authorized: 30 JUL 98 Prepared: 31 JUL 98 Analyzed: 21 AUG 98
Field Surrogate
13C-Fluorene 134 %
Note E : Concentration exceeds calibration range. Value is
estimated.
Note B : Compound is also detected in the blank.
Note m : Internal Standard recovery is outside method recovery goal.
ND = Not detected
NA = Not applicable
Reported By: Mike Flournoy Approved By: Andre Algazi
The cover letter is an integral part of this report.
Rev 230787
-------
Client Name:
Client ID:
Lab ID:
Matrix:
Authorized:
Parameter
POLYNUCLEAR AROMATIC HYDROCARBONS
HIGH RESOLUTION GC/MS
Method HRGC/HRMS
Pacific Environmental Services
T-MM5-FB-F,FH,XAD,COND,BH
300681-0004-SA
AIRTRAIN Sampled: 25 JUL 98
30 JUL 98 Prepared: 31 JUL 98
Naphthalene
2-Methylnaphthalene
Acenaphthylene
Acenaphthene
Fluorene
Phenanthrene
Anthracene
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
Benzo
Benzo
Benzo
Benzo
fluoranthene
fluorantheire
pyrene
pyrene
Perylene
Indeno(l,2,3-cd)pyrene
Dibenz(a,h]anthracene
Benzo(g,h, i)perylene
Surrogate
Naphthalene-dS
Acenaphthylene-d8
Acenaphthene-dlO
Fluorene-dlO
Phenanthrene-dlO
Fluoranthene-dlO
Pyrene-dlO
Benzo(a)anthracene-dl2
Chrysene-dl2
Received: 30 JUL 98
Analyzed: 24 AUG 98
Benzo
Benzo
Benzo
fluoranthene-d!2
fluoranthene-d!2
pyrene-d!2
Perylene-d!2
Indeno(123-cd)pyrene-dl2
Dibenz(a,h)antnracene-dl4
Benzo(g,h,i)perylene-d!2
Result
Recovery
54
78
84
60
77
105
104
157
145
104
105
85
79
107
110
108
Units
Reporting
Limit
290
280
ND
60
160
320
ND
42
40
ND
22
ND
ND
ND
ND
ND
ND
ND
ND
ng/s ample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sampl e
ng/sample
ng/sample
ng/sample
--
--
6.1
--
--
--
11
--
--
3.7
--
4.5
2.3
5.0
2.2
3.8
4.2
2.9
5.6
B
B
B
B
B
nt
ND - Not detected
NA = Not applicable
(continued on foilowing page)
Reported By: Mike Flournoy
Approved By: Andre Algazi
The cover letter is an integral part of this report.
Rev 230787
-------
POLYNUCLEAR AROMATIC HYDROCARBONS
HIGH RESOLUTION GC/MS (CONT.)
Method HRGC/HRMS
Client Name: Pacific Environmental Services
Client ID: T-MM5-FB-F,FH,XAD,COND,BH
Lab ID: 300681-0004-SA
Matrix: AIRTRAIN Sampled: 25 JUL 98 Received: 30 JUL 98
Authorized: 30 JUL 98 Prepared: 31 JUL 98 Analyzed: 24 AUG 98
Field Surrogate
13C-Fluorene 102 %
Note B : Compound is also detected in the blank.
Note m : Internal Standard recovery is outside method recovery goal.
NO = Not detected
NA = Not applicable
Reported By: Mike Flournoy Approved By: Andre Algazi
The cover letter is an integral part of this report.
Rev 230787
-------
Client Name:
Client ID:
Lab ID:
Matrix:
Authorized:
Parameter
POLYNUCLEAR AROMATIC HYDROCARBONS
HIGH RESOLUTION 6C/MS
Method HRGC/HRMS
Pacific Environmental Services
T-MM5-4-F,FH,XAD,COND,BH
300681-0005-SA
AIRTRAIN Sampled: 26 JUL 98
30 JUL 98 Prepared: 31 JUL 98
Naphthalene
2-Methylnaphthalene
Acenaphthylene
Acenaphthene
Fluorene
Phenanthrene
Anthracene
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
Benzo
Benzo
Benzo
Benzo
fluoranthene
fluoranthene
pyrene
pyrene
Perylene
Indeno(1,2,3-cd)pyrene
Dibenz(a,h)anthracene
Benzo(g,h,i)perylene
Surrogate
Naphthalene-d8
Acenaphthylene-d8
Acenaphthene-dlO
Fluorene-dlO
Phenanthrene-dlO
Fluoranthene-dlO
Pyrene-dlO
Benzo(a)anthracene-dl2
Chrysene-dl2
Received: 30 JUL 98
Analyzed: 24 AUG 98
Benzo
Benzo
Benzo
fluoranthene-d!2
fluoranthene-d!2
pyrene-d!2
Perylene-d!2
Indeno(123-cd)pyrene-dl2
Di benz(a,h)anthracene-d!4
Benzo(g,h,i)perylene-d!2
Result
Recovery
90
88
86
62
74
100
98
148
130
108
94
90
82
90
84
94
Units
Reporting
Limit
1400
2600
80
550
1600
4000
220
300
600
15
310
18
ND
13
ND
ND
ND
ND
7.5
ng/s ample
ng/ sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
-_
--
--
--
--
.-
—
--
__
—
--
--
4.8
--
2.0
3.4
3.4
3.3
EB
EB
EB
EB
EB
B
E
ND = Not detected
NA = Not applicable
(continued on following page)
Reported By: Mike Flournoy
Approved By: Andre Algazi
The cover letter is an integral part of this report.
Rev 230787
66
-------
POLYNUCLEAR AROMATIC HYDROCARBONS
HIGH RESOLUTION GC/MS (CONT.)
Method HRGC/HRMS
Client Name: Pacific Environmental Services
Client ID: T-MM5-4-F,FH,XAD,COND,BH
Lab ID: 300681-0005-SA
Matrix: AIRTRAIN Sampled: 26 JUL 98 Received: 30 JUL 98
Authorized: 30 JUL 98 Prepared: 31 JUL 98 Analyzed: 24 AUG 98
Field Surrogate
13C-Fluorene . 104 %
Note E : Concentration exceeds calibration range. Value is
estimated.
Note B : Compound is also detected in the blank.
Note m : Internal Standard recovery is outside method recovery goal.
ND = Not detected
NA = Not applicable
Reported By: Mike Flournoy Approved By: Andre Algazi
The cover letter is an integral part of this report. - '
Rev 230787
-------
Client Name:
Client ID:
Lab ID:
Matrix:
Authorized:
Parameter
POLYNUCLEAR AROMATIC HYDROCARBONS
HIGH RESOLUTION GC/MS
Method HRGC/HRMS
Pacific Environmental Services
T-MM5-3-F,FH,XAD,COND,BH
300681-0006-SA
AIRTRAIN Sampled: 27 JUL 98
30 JUL 98 Prepared: 31 JUL 98
Naphthalene
2-Methylnaphthalene
Acenaphthylene
Acenaphthene
Fluorene
Phenanthrene
Anthracene
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
Benzo
Benzo
Benzo
Benzo
fluoranthene
fluoranthene
pyrene
pyrene
Perylene
Indeno(l,2,3-cd)pyrene
Dibenz(a,h)anthracene
Benzo(g,h,i)perylene
Surrogate
Naphtha!ene-d8
Acenaphthylene-d8
Acenaphthene-dlO
Fluorene-dlO
Phenanthrene-dlO
Fluoranthene-dlO
Pyrene-dlO
Benzo(a)anthracene-dl2
Chrysene-dl2
Benzo(b fluoranthene-d!2
Benzojk fluoranthene-d!2
Benzo(a pyrene-d!2
Perylene-dl2
Indeno(123-cd)pyrene-dl2
Dibenz(a,h)anthracene-dl4
Benzo(g,h,i)perylene-d!2
Received: 30 JUL 98
Analyzed: 25 AUG 98
Result
Recovery
25
57
40
49
61
96
80
121
103
97
89
73
67
95
103
92
Units
Reporting
Limit
24000
47000
590
5000
9800
13000
1100
930
2700
310
1900
130
34
120
35
280
ND
ND
33
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample 11
ng/sample 7.6
ng/sample
EB
EB
EB
EB
EB
EB
E
m
m
m
ND = Not detected
NA = Not applicable
(continued on following page)
Reported By: Mike Flournoy
Approved By: Andre Algazi
The cover letter is an integral part of this report.
Rev 230787
-------
POLYNUCLEAR AROMATIC HYDROCARBONS
HIGH RESOLUTION GC/MS (CONT.)
Method HRGC/HRMS
Client Name: Pacific Environmental Services
Client ID: T-MM5-3-F,FH,XAD,COND,BH
Lab ID: 300681-0006-SA
Matrix: AIRTRAIN Sampled: 27 JUL 98 Received: 30 JUL 98
Authorized: 30 JUL 98 Prepared: 31 JUL 98 Analyzed: 25 AUG 98
Field Surrogate
13C-Fluorene 85 %
Note E : Concentration exceeds calibration range. Value is
estimated.
Note B : Compound is also detected in the blank.
Note m : Internal Standard recovery is outside method recovery goal.
ND = Not detected
NA = Not applicable
Reported By: Mike Flournoy Approved By: Andre Algazi
69
The cover letter is an integral part of this report. "
Rev 230787
-------
Client Name;
Client ID:
Lab ID:
Matrix:
Authorized:
Parameter
POLYNUCLEAR AROMATIC HYDROCARBONS
HIGH RESOLUTION GC/MS
Method HRGC/HRMS
Pacific Environmental Services
S-MM5-FB-F,FH,XAD,COND,BH
300681-0008-SA
AIRTRAIN Sampled: 26 JUL 98
30 JUL 98 Prepared: 31 JUL 98
Naphthalene
2-Methylnaphthalene
Acenaphthylene
Acenaphthene
Fluorene
Phenanthrene
Anthracene
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
Benzo
Benzo
Benzo
Benzo
fluoranthene
fluoranthene
pyrene
pyrene
Perylene
IndenoH, 2,3-cd) pyrene
Dibenz(a,h)anthracene
Benzo(g,h,i)perylene
Surrogate
Naphthalene-d8
Acenaphthylene-d8
Acenaphthene-dlO
Fluorene-dlO
Phenanthrene-dlO
Fluoranthene-dlO
Pyrene-dlO
Benzo(a)anthracene-dl2
Chrysene-dl2
Received: 30 JUL 98
Analyzed: 25 AUG 98
Benzol
Benzoi
Benzo(a
fluoranthene-dlZ
fluoranthene-dlZ
pyrene-d!2
Perylene-dl2
Indeno(123-cd)pyrene-dl2
Dibenz(a,h)anthracene-dl4
Benzo(g,n,i)perylene-d!2
Result
Recovery
61
77
80
62
77
113
111
151
125
106
101
93
90
118
124
115
Units
Reporting
Limit
410
490
ND
150
420
1600
100
130
350
53
300
26
ND
25
ND
70
ND
ND
21
ng/ sample
ng/s ample
ng/ sample
ng/s ample
ng/s ample
ng/sample
ng/sample
ng/sample
rig/sample
ng/sampl e
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
_.
--
11
--
-.
_.
-.
-.
_.
—
__
--
4.5
--
7.8
--
6.0
2.4
--
B
B
B
B
B
m
ND = Not detected
NA = Not applicable
(continued on following page)
Reported By: Mike Flournoy
Approved By: Andre Algazi
The cover letter is an integral part of this report.
Rev 230787
-------
POLYNUCLEAR AROMATIC HYDROCARBONS
HIGH RESOLUTION GC/MS (CONT.)
Method HRGC/HRMS
Client Name: Pacific Environmental Services
Client ID: S-MM5-FB-F,FH,XAD,COND,BH
Lab ID: 300681-0008-SA
Matrix: AIRTRAIN Sampled: 26 JUL 98 Received: 30 JUL 98
Authorized: 30 JUL 98 Prepared: 31 JUL 98 Analyzed: 25 AUG 98
Field Surrogate
13C-Fluorene 94 %
Note B : Compound is also detected in the blank.
Note m : Internal Standard recovery is outside method recovery goal.
ND = Not detected
NA = Not applicable
Reported By: Mike Flournoy Approved By: Andre Algazi
The cover letter is an integral part of this report. 7.1
Rev 230787
-------
Client Name:
Client ID:
Lab ID:
Matrix:
Authorized:
Parameter
POLYNUCLEAR AROMATIC HYDROCARBONS
HIGH RESOLUTION 6C/MS
Method HRGC/HRMS
Pacific Environmental Services
S-MM5-RB-F,FH,XAD,COND,BH
300681-0009-SA
AIRTRAIN Sampled: 25 JUL 98
30 JUL 98 Prepared: 31 JUL 98
Received: 30 JUL 98
Analyzed: 25 AUG 98
Naphthalene
2-Methylnaphtha!ene
Acenaphthylene
Acenaphthene
Fluorene
Phenanthrene
Anthracene
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
Benzo
Benzo
Benzo
Benzo
b)fluoranthene
1 fluoranthene
pyrene
pyrene
Perylene
Indeno(1,2,3-cd)pyrene
Dibenz(a,h)anthracene
Benzo(g,h,i)perylene
Surrogate •
Naphthalene-dS
Acenaphthylene-d8
Acenaphthene-dlO
Fluorene-dlO
Phenanthrene-dlO
Fluoranthene-dlO
Pyrene-dlO
Benzo(a)anthracene-dl2
Chrysene-dl2
Benzo(b;
Benzo(k(
Benzo(a'
fluoranthene-d!2
fluoranthene-d!2
pyrene-dl2
Perylene-dl2
Indeno(123-cd)pyrene-dl2
Dibenz(a,h)antnracene-dl4
Benzo(g,h,i)pery1ene-d!2
Result
Recovery
59
71
74
63
75
86
88
139
127
105
102
93
90
121
120
119
Units
Reporting
Limit
270
140
NO
38
43
110
ND
26
18
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ng/sample
ng/ sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sampl e
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
--
--
6.1
--
--
--
7.9
--
—
1.1
4.6
1.7
0.58
1.2
0.85
1.1
0.57
0.31
1.3
B
B
B
B
B
ND - Not detected
NA = Not applicable
(continued on following page)
Reported By: Mike Flournoy
Approved By: Andre Algazi
The cover letter is an integral part of this report.
Rev 230787
-------
POLYNUCLEAR AROMATIC HYDROCARBONS
HIGH RESOLUTION GC/MS (CONT.)
Method HRGC/HRMS
Client Name: Pacific Environmental Services
Client ID: S-MM5-RB-F,FH,XAD,COND,BH
Lab ID: 300681-0009-SA
Matrix: AIRTRAIN Sampled: 25 JUL 98 Received: 30 JUL 98
Authorized: 30 JUL 98 Prepared: 31 JUL 98 Analyzed: 25 AUG 98
Field Surrogate
13C-Fluorene 113 %
Note B : Compound is also detected in the blank.
ND = Not detected
NA = Not applicable
Reported By: Mike Flournoy Approved By: Andre Algazi 73
The cover letter is an integral part of this report.
Rev 230787
-------
Client'Name:
Client ID:
Lab ID:
Matrix:
Authorized:
Parameter
POLYNUCLEAR AROMATIC HYDROCARBONS
HIGH RESOLUTION GC/MS
Method HRGC/HRMS
Pacific Environmental Services
S-MM5-4-F,FH,XAD,COND,BH
300681-0010-SA
AIRTRAIN Sampled: 25 JUL 98
30 JUL 98 Prepared: 31 JUL 98
Received: 30 JUL 98
Analyzed: 06 OCT 98
Naphthalene
2-Methylnaphthalene
Acenaphthylene
Acenaphthene
Fluorene
Phenanthrene
Anthracene
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
Benzo b fluoranthene
Benzo k fluoranthene
Benzo e pyrene
Benzo(a)pyrene
Perylene
Indeno(1,2,3-cd}pyrene
Di benz(a, h janthracene
Benzo(g,h,i}perylene
Surrogate
Naphtha!ene-d8
Acenaphthylene-d8
Acenaphthene-dlO
Fluorene-dlO
Phenanthrene-dlO
Fluoranthene-dlO
Pyrene-dlO
Benzo(a)anthracene-dl2
Perylene-dl2
Indeno(123-cd)pyrene-dl2
Chrysene-dl2
Benzo
Benzo
Benzo
fluoranthene-d!2
fluoranthene-d!2
pyrene-d!2
Di benz(a,h)anthracene-d!4
Benzo(g,h,i)perylene-dl2
Result
720
2000
ND
170
340
640
56
67
170
26
97
ND
ND
ND
ND
ND
ND
ND
ND
Recovery
85
121
113
92
98
49
47
52
94
85
44
134
98
98
80
78
Units
Re
porting
Limit
ug/sample
ug/sample
ug/sample
ug/sample
ug/sample
ug/sample
ug/sample
ug/sample
ug/sample
ug/sample
ug/sample
ug/sample
ug/sample
ug/sample
ug/sample
ug/sample
ug/sample
ug/sample
ug/sample
15
15
15
15
15
15
15
15
15
15
15
15
15
15
15
15
15
15
15
nr
m
m
ND = Not detected
NA = Not applicable
(continued on following page)
Reported By: Mike Flournoy
Approved By: Eric Redman
The cover letter is an integral part of this report.
Rev 230787
74
-------
POLYNUCLEAR AROMATIC HYDROCARBONS
HIGH RESOLUTION GC/MS (CONT.)
Method HRGC/HRMS
Client Name: Pacific Environmental Services
Client ID: S-MM5-4-F,FH,XAD,COND,BH
Lab ID: 300681-0010-SA
Matrix: AIRTRAIN Sampled: 25 JUL 98 Received: 30 JUL 98
Authorized: 30 JUL 98 Prepared: 31 JUL 98 Analyzed: 06 OCT 98
Field Surrogate
13C-Fluorene NA %
Note m : Internal Standard recovery is outside method recovery goal.
ND = Not detected
NA = Not applicable
Reported By: Mike Flournoy Approved By: Eric Redman 75
The cover letter is an integral part of this report.
Rev 230787
-------
Client Name:
Client ID:
Lab ID:
Matrix:
Authorized:
Parameter
POLYNUCLEAR AROMATIC HYDROCARBONS
HIGH RESOLUTION GC/MS
Method HRGC/HRMS
Pacific Environmental Services
S-MM5-5-F,FH,XAD,COND,BH
300681-0011-SA
AIRTRAIN Sampled: 28 JUL 98
30 JUL 98 Prepared: 31 JUL 98
Received: 30 JUL 98
Analyzed: 06 OCT 98
Naphthalene
2-Methyl naphthalene
Acenaphthylene
Acenaphthene
Fluorene
Phenanthrene
Anthracene
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
Benzo b fluoranthene
Benzo k fluoranthene
Benzo e pyrene
Benzo ajpyrene
Perylene
Indeno(1,2,3-cd)pyrene
Dibenz(a,hjanthracene
Benzo(g,h,i)perylene
Surrogate
Naphthalene-dS
Acenaphthylene-d8
Acenaphthene-dlO
Fluorene-dlO
Phenanthrene-dlO
Fluoranthene-dlO
Pyrene-dlO
Benzo(a)anthracene-dl2
Perylene-dl2
Indeno(123-cd)pyrene-d!2
Chrysene-dl2
Benzo(b
Benzo(k
Benzofa
fluoranthene-d!2
fluoranthene-d!2
pyrene-d!2
Dibenz(a,h)anthracene-dl4
Benzo(g,h,i)perylene-d!2
Result
1300
3400
22
370
640
1200
94
100
290
43
160
ND
ND
15
ND
28
ND
ND
ND
Recovery
84
122
108
88
93
50
48
51
94
82
4-2
125
96
95
76
73
Units
Reporting
Limit
ug/sample
ug/sample
ug/sample
ug/sample
ug/sample
ug/sample
ug/sample
ug/sample
ug/sample
ug/sample
ug/sample
ug/sample
ug/sample
ug/sample
ug/sample
ug/sample
ug/sample
ug/sample
ug/sample
15
15
15
15
15
15
15
15
15
15
15
15
15
15
15
15
15
15
15
m
m
ND = Not detected
NA = Not applicable
(continued on following page)
Reported By: Mike Flournoy
Approved By: Eric Redman
The cover letter is an integral part of this report.
Rev 230787
-------
POLYNUCLEAR AROMATIC HYDROCARBONS
HIGH RESOLUTION GC/MS (CONT.)
Method HRGC/HRMS
Client Name: Pacific Environmental Services
Client ID: S-MM5-5-F,FH,XAD,COND,BH
Lab ID: 300681-0011-SA
Matrix: AIRTRAIN Sampled: 28 JUL 98 Received: 30 JUL 98
Authorized: 30 JUL 98 Prepared: 31 JUL 98 Analyzed: 06 OCT 98
Field Surrogate
13C-Fluorene NA %
Note m : Internal Standard recovery is outside method recovery goal.
ND = Not detected
NA = Not applicable
Reported By: Mike Flournoy Approved By: Eric Redman 77
The cover letter is an integral part of this report.
Rev 230787
-------
Method Blank
78
-------
02-SEP-1998 07:49:40 PM Dioxin Furan Unknown RESULTS
GC Column : DB-5
Data file : 20AU98U
Weight : 0.333
Name
dlO-2-Methylnaphthalene
-/ d8-Naphthalene
Naphthalene
2-Methylnaphthalene
., d8-Acenaphthylene
Acenaphthylene
dlO-Acenaphthene
Acenaphthene
dlO-Anthracene
dlO-Fluorene
Fluorene
dlO-Phenanthrene
Phenanthrene
Anthracene
d!2-Benzo(e)pyrene
. dlO-Fluoranthene
Fluoranthene
- dlO-Pyrene
Pyrene
dl2-Benzo(a)anthracene
Benzo(a)anthracene
d!2-Chrysene
Chrysene
d!2-Benzo(e)pyrene
d!2-Benzo(b)fluoranthene
Benzo(b)fluoranthene
d!2-Benzo(k)fluoranthene
Benzo(k)fluoranthene
d!2-Benzo(a)pyrene
Benzo(e)pyrene
Benzo(a)pyrene
dl2-Perylene
Perylene
d!2-Indeno(12 3 -cd)pyrene
Indeno(123 -cd)pyrene
d!4-Dibenz(ah)anthracene
Dibenz(ah)anthracene
dl2-Benzo(ghi)perylene
Benzo(ghi)perylene
d8-Naphthalene
13C-Naphthalene
Results
300681-1MS
Total
Response
20AU98U071.RES
Date analyzed
:Method Blank Ex Cal
Isotope R. T. RRF
Ratio
PAHX.TRG
20-AUG-98
PAHX081998U.RRF
ng/ Rec/
160610600 1.00 Y
172466600 1.00 Y
343308000 1.00 Y
103999400 1.00 Y
154601600 1.00 Y
5844000 1.00 Y
99425200 1.00 Y
26403400 1.00 Y
101642400 1.00 Y
88692000 1.00 Y
26730400 1.00 Y
193517000 1.00 Y
89206800 1.00 Y
7740000 1.00 Y
294980000 1.00 Y
193255000 1.00 Y
20916800 1.00 Y
201750000 1.00 Y
12764140 1.00 Y
148246400 1.00 Y
888458 1.00 Y
230106000 1.00 Y
2039180 1.00 Y
294980000 1.00 Y
169046000 1.00 Y
3413480 1.00 Y
263266000 1.00 Y
4565960 1.00 Y
178354000 1.00 Y
7488380 1.00 Y
3851580 1.00 Y
157592000 1.00 Y
4200000 1.00 Y
192155200 1.00 Y
4320000 1.00 Y
109863200 1.00 Y
2523940 1.00 Y
182400000 1.00 Y
4460000 1.00 Y
172466600 1.00 Y
* No Peak 0.00 N
nun
11
8
9
11
14
14
14
14
19
16
16
19
19
19
32
23
23
24
24
28
28
28
28
32
31
31
31
31
32
32
32
33
33
3.8
38
38
38
39
39
8
8
as
8
56
0
15
13
15
46
52
47
28
34
37
42
50
38
32
35
14
18
6
10
13
18
38
39
44
44
49
51
45
57
9
16
0
9
1
13
19
28
56
60
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
N
N
Y
N
1
1
1
0
1
0
0
0
1
1
1
2
0
0
1
0
1
0
1
0
1
0
0
1
0
1
0
1
0
1
1
0
1
0
0
0
1
0
0
1
1
.00
.25
.05
.77
.55
.86
.88
.93
.00
.13
.05
.63
.84
.83
.00
.80
.04
.81
.11
.65
.06
.85
.97
.00
.63
.07
.90
.16
.75
.46
.02
.61
.62
.71
.61
.44
.11
.63
.99
.00
.00
C3Mlvlf
50.
43.
283.
117.
31.
6.
35.
4-2.
50.
38.
43.
36.
-<*-8-2"T
1\
50.
40.
*5T
42.
8.
38.
0.
45.
1.
50.
45.
2.
49.
2.
40.
4.
3.
43.
2.
46.
5.
42.
3.
49.
3.
50.
0.
fi
00
10
71
47i
05
57=DL
28
881
00
63
10 J
21
19"*
24=DL
00
78
62r
23
58=DL
64
85 = DL
98
37=DL
00
77
84=DL
80
25=DL
25
31=DL
17=DL
47
47=DL
10
52=DL
21
10=DL
05
71=DL
ooTO
00
L>Lt
86
62
71
77
72
82
84
77
92
92
100
80
87
92
84
98
0
-------
02-SEP-1998 07:49:40 PM Dioxin Furan Unknown RESULTS ^ .
r *•* J "~
,l'
dlO-Fluorene 88692000 1.00 Y 16: 28 Y l.OO' 50.00
13C-Fluorene 72085200 1.00 Y 16: 34 Y -6-rS±; 50.35
'
-------
Ol-SEP-1998 05:
HX.TRG
-AUG-98
HX081998U.RRF
ng/ Rec/
SAMP MDL
50
43
283
117
31
6
35
42
50
38
43
36
82
7
50
40
15
42
8
38
0
45
1
50
45
2
49
2
40
4
3
43
2
46
5
42
3
49
3
.00
.10
.77
.47
.05
.57
.28
.88
.00
.63
.10
.21
.19
.24
.00
.78
.62
.23
.58
.64
.85
.98
.37
.00
.77
.84
.80
.25
.25
.31
.17
.47
.47
.10
.52
.21
.10
.05
.71
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
86
.000
.000
62
.000
71
.000
77
.000
72
.000
.000
82
.000
84
.000
77
.000
92
.000
92
.000
100
.000
80
.000
.000
87
.000
92
.000
84
.000
98
.000
49:39 PM
0.333
80305300
86233300
171654000
51999700
77300800
2922000
49712600
13201700
50821200
44346000
13365200
96758500
44603400
3870000
147490000
96627500
10458400
100875000
6382070
74123200
444229
115053000
1019590
147490000
84523000
1706740
131633000
2282980
89177000
3744190
1925790
78796000
2100000
96077600
2160000
54931600
1261970
91200000
2230000
Dioxin Fur
80305300
86233300
171654000
51999700
77300800
2922000
49712600
13201700
50821200
44346000
13365200
96758500
44603400
3870000
147490000
96627500
10458400
100875000
6382070
74123200
444229
115053000
1019590
147490000
84523000
1706740
131633000
2282980
89177000
3744190
1925790
78796000
2100000
96077600
2160000
54931600
1261970
91200000
2230000
-------
Ol-SEP-1998 05:51:12 PM Dioxin Furan Unknown RESULTS
50.00 44346000 44346000
50.36 101 36042600 36042600
8;
-------
>4-AUG-1998 01:05:53 PM
PAH Unknown RESULTS
lass Spec : ULTIMA
3C Column : DB-5
Data file -. 20AU98U
height : 0.333
Name
dlO-2-Methylnaphthalene
d8-Naphthalene
Naphthalene
2-Methylnaphthalene
d8-Acenaphthylene
Acenaphthylene
dlO-Acenaphthene
Acenaphthene
dlO-Anthracene
dlO-Fluorene
Fluorene
dl0-Phenanthrene
Phenanthrene
Anthracene
d!2-Benzo(e)pyrene
dlO-Fluoranthene
Fluoranthene
dlO-Pyrene
Pyrene
d!2-Benzo(a)anthracene
Benzo(a)anthracene
d!2-Chrysene
Chrysene
d!2-Benzo(e)pyrene
d!2-Benzo(b)fluoranthene
Benzo(b)fluoranthene
d!2-Benzo(k)fluoranthene
Benzo(k)fluoranthene
dl2-Benzo(a)pyrene
Benzo(e)pyrene
Benzo(a)pyrene
d!2-Perylene
Perylene
d!2-Indeno(123-cd)pyrene
Indeno(123-cd)pyrene
d!4-Dibenz(ah)anthracene
Dibenz(ah)anthracene
d!2-Benzo(ghi)perylene
Benzo(ghi)perylene
d8-Naphthalene
l3C-Naphthalene
Results : 20AU98U071.RES
Date analyzed
300681-IMS -.Method Blank Ex Cal
Total Isotope R. T. RRF
Response Ratio mm:ss
PAHX. TRG
20-AUG-98
PAHX081998U.RRF
ng/ Rec/
SAMP MDL
*
*
*
*
*
160610600
172466600
343308000
103999400
154601600
5844000
99425200
26403400
101642400
88692000
26730400
193517000
89206800
No Peak
294980000
193255000
20916800
201750000
12764140
148246400
888458
230106000
2039180
294980000
169046000
3413480
263266000
4565960
178354000
7488380
3851580
157592000
3314100
192155200
No Peak
109863200
2523940
No Peak
No Peak
172466600
No Peak
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
0.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
0.00
1.00
1.00
0.00
0.00
1.00
0.00
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
N
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
N
Y
Y
N
N
Y
N
11:
8:
9:
11:
14:
14:
14:
14:
19:
16:
16:
19:
19:
19:
32:
23:
23:
24:
24:
28:
28:
28:
28:
32:
31:
31:
31:
31:
32:
32:
32:
33:
33:
38:
38:
38:
38:
39:
39:
8:
8:
8
56
0
15
13
15
46
52
47
28
34
37
42
50
38
32
35
14
18
6
10
13
18
38
39
44
44
49
51
45
57
9
16
0
2
1
13
19
28
56
60
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
N
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
N
Y
Y
N
N
Y
N
1
1
1
0
1
0
0
0
1
1
1
2
0
0
1
0
1
0
1
0
1
0
0
1
0
1
0
1
0
1
1
0
1
0
0
0
1
0
0
1
1
.00
.25
.05
.77
.55
.86
.88
.93
.00
.13
.05
.63
.84
.83
.00
.80
.04
.81
.11
.65
.06
.85
.97
.00
.63
.07
.90
.16
.75
.46
.02
.61
.62
.71
.61
.44
.11
.63
.99
.00
.00
50
43
283
117
31
6
35
42
50
38
43
36
82
0
50
40
15
42
8
38
0
45
1
50
45
2
49
2
40
4
3
43
1
46
0
42
3
0
•*•
50
0
.00
.10
.77
.47
.05
.57
.28
.88
.00
.63
.10
.21
.19
.00
.00
.78
.62
.23
.58
.64
.85
.98
.37
.00
.77
.84
.80
.25
.25
.31
.17
.47
.95
.10
.00
.21
.10
.00
Noll
.00
.00
86
0.000
0.000
62
0.000
71
0.000
77
0.000
72
0.000
0.000
82
0.000
84
0.000
77
0.000
92
0.000
92
0.000
100
0.000
80
0.000
0.000
87
0.000
92
0.000
84
0.000
fl^ 0
tf<§Tg
Q
-------
24-AUG-1998 01:05:53 PM PAH Unknown RESULTS ;-:''
dlO-Fluorene 88692000 1.00 Y 16: 28 Y 1.00; 50.00
13C-Fluorene 72085200 1.00 Y 16: 34 Y 0.81's 50.36 101
84
-------
24-AUG-1998 12:39:59 PM
PAH Unknown RESULTS
Mass Spec : ULTIMA
GC Column : DB-5
Data file : 20AU98U
Weight : 0.333
Name
dlO-2-Methylnaphthalene
d8-Naphthalene
Naphthalene
2-Methylnaphthalene
d8-Acenaphthylene
Acenaphthylene
dlO-Acenaphthene
Acenaphthene
dl0-Anthracene
dlO-Fluorene
Fluorene
dlO-Phenanthrene
Phenanthrene
Anthracene
d!4-Terphenyl
dl0-Fluoranthene
Fluoranthene
dlO-Pyrene
Pyrene
d!2-Benzo(a)anthracene
Benzo(a)anthracene
d!2-Chrysene
Chrysene
d!2-Benzo(e)pyrene
dl2-Benzo(b)fluoranthene
Benzo(b)fluoranthene
dl2-Benzo(k)fluoranthene
Benzo(k)fluoranthene
d!2-Benzo(a)pyrene
Benzo(e)pyrene
Benzo(a)pyrene
d!2-Perylene
Perylene
d!2-Indeno(123-cd)pyrene
Indeno(12 3 -cd)pyrene
dl4-Dibenz(ah)anthracene
Dibenz(ah)anthracene
d!2-Benzo(ghi)perylene
Benzo(ghi)perylene
d8-Naphthalene
13C-Naphthalene
Results
300681-1MS
Total
Response
20AU98U071.RES
Date analyzed
:Method Blank Ex Cal
Isotope R. T. RRF
Ratio mm:ss
PAHPRESPIKED.TRG
20-AUG-98
PAHAIR081998U.RR
ng/ Rec/
SAMP MDL
160610600 1.00 Y
172466600 1.00 Y
343308000 1.00 Y
103999400 1.00 Y
154601600 1.00 Y
5844000 1.00 Y
99425200 1.00 Y
26403400 1.00 Y
101642400 1.00 Y
88692000 1.00 Y
26730400 1.00 Y
193517000 1.00 Y
89206800 1.00 Y
* No Peak 0.00 N
214170000 1.00 Y
193255000 1.00 Y
20916800 1.00 Y
201750000 1.00 Y
12764140 1.00 Y
148246400 1.00 Y
888458 1.00 Y
230106000 1.00 Y
2039180 1.00 Y
294980000 1.00 Y
169046000 1.00 Y
3413480 1.00 Y
263266000 1.00 Y
4565960 1.00 Y
178354000 1.00 Y
7488380 1.00 Y
3851580 1.00 Y
157592000 1.00 Y
3314100 1.00 Y
192155200 1.00 Y
4324000 1.00 Y
109863200 1.00 Y
2523940 1.00 Y
182477600 1.00 Y
4459200 1.00 Y
172466600 1.00 Y
* No Peak 0.00 N
11:
8:
9:
11:
14:
14:
14:
14:
19:
16:
16:
19:
19:
19:
24:
23:
23:
24:
24:
28:
28:
28:
28:
32:
31:
31:
31:
31:
32:
32:
32:
33:
33:
38:
38:
38:
38:
39:
39:
8:
8:
8
56
0
15
13
15
46
52
47
28
34
37
42
51
53
32
35
14
18
6
10
13
18
38
39
44
44
49
51
45
57
9
16
0
9
1
13
24
35
56
60
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
N
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
N
1
1
1
0
1
0
0
0
1
1
1
2
0
0
1
1
1
1
1
0
1
1
0
1
0
1
0
1
0
1
1
0
1
0
0
0
1
0
0
1
1
.00
.25
.05
.77
.55
.86
.88
.93
.00
.13
.05
.63
.84
.83
.00
.01
.04
.01
.11
.82
.06
.06
.97
.00
.63
.07
.90
.16
.75
.46
.02
.61
.62
.71
.61
.44
.11
.63
.99
.00
.00
50
43
283
117
31
6
35
42
50
38
43
36
82
0
50
44
15
46
8
42
0
50
1
50
45
2
49
2
40
4
3
43
1
46
5
42
3
49
3
50
0
.00
.10
.77
.47
.05
.57
.28
.88
.00
.63
.10
.21
.19
.00
.00
.83
.62
.54
.58
.46
.85
.47
.37
.00
.77
.84
.80
.25
.25
.31
.17
.47
.95
.10
.53
.21
.10
.07
.70
.00
.00
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
86
.000
.000
62
.000
71
.000
77
.000
72
.000
.000
90
.000
93
.000
85
.000
101
.000
92
.000
100
.000
80
.000
.000
87
.000
92
.000
84
.000
8<|8
.000
0
-------
24-AUG-1998 12:39:59 PM PAH Unknown RESULTS _' ."'
fr
dlO-Fluorene 88692000 1.00 Y 16: 28 Y 1.00 50.00
13C-Fluorene 72085200 1.00 Y 16: 34 Y 1.00 40.64 81
6G
-------
CO
File:20AU98U #1-476 Acq:20-AUG-1998 20:00:06 GC EI+ Voltage SIR Autospec-Ultima
Sample*? Text:30068MMS -.Method Blank Exp:PAHALR
128.0626 S:7 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
1002
80 J
60 J
40 :
•TV —
20 J
n A
> Al.
A4.97E7
A
ZE.5
/
UJ ,-. 1 i 1 | 1
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142.0782 S:7 SMO(1,3) PKD(5,3,3,0.
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60 J
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152.1410 S:7 SMO(1,3) PKD(5,3,3,0.
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0 :
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9:00
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10:00 11:00 12:60 13:1
-3.9E7
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r2.5E7
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-------
CO
File:20AU98U #1-476 Acq:20-AUG-l998 20:00:06 GC EI+ Voltage SIR Autospec-Ultima
Sampled Text:300681-lMS :Method Blank ExprPAHAIR
152.0626 S:7 SMO(1,3) PKD(5^,3,0.10%,10000.0,0.00%,F,T)
100%
1.8E6
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160.1128 S:7 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
80 J
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20
A7.73E7
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:8.8E6
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100%
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12.3E6
1.5E6
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13:60 13:ii 13:24 13:36 13:48 14:1)0 14:i2 14:24 14:36 14:48 15:00 15:12 15:24 15:36 Time
164.1410 S:7 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100% A4.97E7 1.4E7
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13:60 13:12 13:24 13:36 13:48 14:00 14:i2 14:24 14:36 14:48 15:00 15:12 15:24 15:36 Time
-------
File:20AU98U #1-476 Acq:20-AUG-1998 20:00:06 GC EI+ Voltage SIR Autospec-Ultima
Sample*? Text:300681-lMS :Method Blank Exp:PAHAIR
130.9920 S:7 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
002
95 J
90 1
85^
80-
75 J
-
70 J
65 J
60 J
55 J
50 J
45 J
40 J
35 J
30-
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20 J
15 J
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-9.7E7
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-6.9E7
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Time
-------
FiIe:20AU98U #1-666 Acq:20-AUG-I998 20:00:06 GC EI+ Voltage SIR Autospec-UItima
Sample*? Text:30068l-lMS :Method Blank Exp:PAHAIR
166.0798 S:7 F:2 SMO(l,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100% , - A144E7
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17:36 17.-48 18:00 18:12 18:24
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176.1410 S:7 F:2 SMO(1,3)
100S.
90 J
80 J
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50-
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301
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15:48 ' 16:60 ' ' 16:b 16:24 16:36 16:48 17:00 17:i2 17:24 17:36 17:48 18:6o 18:12
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7.2E6
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3.6E6
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1.5E7
1.4E7
1.2E7
1.1E7
9.1E6
7.5E6
6.0E6
4.5E6
3.0E6
1.5E6
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Time
18
-------
File:20AU98U #1-666 Acq:20-AUG-1998 20:00:06 GC EI+ Voltage SIR Autospec-Ultima
Sample*? Text:300681-lMS :Method Blank Exp:PAHAlR
178.0782 S:7 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 % A4.4.6E7
90
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70
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50
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20
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0
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9m 19:12 19:^4 19:36 19?48
188.1410 S:7 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
A9.68E7
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2.6E7
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1.9E7
: 1.6E7
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Time
-------
File:20AU98U #1-666 Acq:20-AUG-19»8 20:00:06 GC E1+ Voltage SLR Autospec-UHima
Sample*? Text:300681-lMS :Method Blank Exp:PAHAIR
178.0782 S:7 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
SKT
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70_
60
50
40
30
20
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188.1410 S:7 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
90 _
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File:20AU98U #1-934 Ac«:20-AUG-1998 20:00:06 GC E1+ Voltage SIR Autospec-Ultima
Sampled Text:3006ll-JMS :Method Blank Exp:PAHAlR
202.0782 S:7 F:3 §M
-------
File:20AU98U #1-934 Acq:20-AUG-1998 20:00:06 GC E1+ Voltage SIR Autospec-Ultima
Sample/?? Text:300681-lMS .-Method Blank Exp.-PAHAIR
228.0939 S:7 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
A1.02E6
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240.1692 S:7 F:3 SMO(1,3) PKD(S,3,3,0.10%,10000.0,0.00%,F,T)
100%
90 J
80
70
60 ,
50 j
40
30-
201
10
28:li 28-^4 28:36 28:48 29:00 29:1:2 29:24 29:37" 29:48
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30:00 Time
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-2.0E7
11.8E7
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L5.1E6
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-O.OEO
:00 Time
-------
File:20AU98U #1-934 Acq:20-AUG-1998 20:00:06 GC EI+ Voltage SIR Autospec-Ultima
Sampled? Text:30068HMS .-Method Blank Exp:PAHAlA
230.9856 S:7 F:3 SMQtt.3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
loos
95:
90:
85:
80:
75:
70:
65:
60:
55:
50:
45:
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35:
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-4.7E7
-4.0E7
-3.4E7
-2.7E7
_2.0E7
-1.3E7
6.7E6
O.OEO
0 Time
-------
File:20AU98U #1-955 Acq:20-AUG-1998 20:00:06 GC EI+ Voltage SIR Autospec-Ultima
Sample*? Text:300681-lMS :Method Blank Exp:PAHAlR
252.0939 S:7 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
90 -
80 J
70 j
60
50.;
401
30 J
20 j
10 J
A3.74E6
A1.71E6
8.0E5
L7.2E5
-6.4E5
5.6E5
4.8E5
-4.0ES
13.2E5
-2AE5
A.6E5
LS.OE4
O.OEO
Time
A8.45E7
30:00 31.-bo 32:i
264.1692 S:7 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
90
80 -
70 J
60
50
40-:
30-
201
10J
33:t
34:1
0
30:00
A1.47E8
31:4
A7.88E7
32:1
33
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34:0
3.3E7
-3.0E7
-2.6E7
-2.3E7
2.0E7
-1.6E7
A.3E7
-9.9E6
6.6E6
3.3E6
O.OEO
Time
-------
A2.10E6
File:20AU98U #1-955 Acq:20-AUG-1998 20:00:06 GC EI+ Voltage SIR Autospec-Ultima
Sample*? Text:30068J-lMS :Method Blank Exp:PAHAlR
252.0939 S:7 F:4 SMO(I,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100% • A3.14E6
90
80
70
60 J
50
40
30
20
10 J
32:48
264.1692 S:7 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100^. A1.47E8
90
80 J
70
60
50
40
30
20
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33: ll"
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—i—|—
33:48
8.0E5
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5.6E5
4.8E5
4.0E5
3.2E5
2.4E5
1.6E5
8.0E4
lO.OEO
34:12 Time
-3.3E7
t3.0E7
^2.6E7
L2.3E7
-2.0E7
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19.9E6
6.6E6
L3.3E6
, -O.OEO
34:12 Time
32:24
32:36
32:48
33:00
3302
33:24
33:36
33:48
34:00
-------
FHe:20AU98U #1-955 Acq:20-AUG-1998 20:00:06 GC EI+ Voltage SIR Autospec-Uliima
Sampled Text:30068MMS :Method Blank Exp:PAHAlR
276.0939 S:7 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
80
36:00 37:00 38:00
288.1692 S:7 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
A9.61E7
36:00 37:00
278.1096 S:7 F:4 SMO(1,3)
100%
42:00 Time
36:00 37:00 38-5fl
292.1974 S:7 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
A5.49E7
Time
-------
o
o
FiIe:20AU98U #1-955 Acq:20-AUG-1998 20:00:06 GC EI+ Voltage SIR Autospec-Ultima «. •«•
Sample#7 Text:30068MMS :Method Blank Exp:PAHAIR
268.9824 S:7 F:4 SMO(1,3) PKD(S,3»3»0.10%,10000.0,0.00%,F,T)
A1.36E7 A1.23E7 A7.83E6 A8.35E6 A4.62E6 A1.08E7 A8.46E6
~ \nrrrrPfn^TrTY^^
80J
40 J
30
20 4
10
30:
' 31:60 32:60 ' 33:6fl 34:6o
35:00 36:1)0 37:60
39:6fl 40:60 41:6o 42:
280.9824 S:7 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
'
17.0E6
L4.6E6
L2.3E6
LO.OEO
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00 S
90
80 j
70 J
60 J
50 J
40 J
30 J
20 J
10-;
30:
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0 ' '31:60 ' '32:00' 33:60 ' 34:6fl 35:6o '36:6o 37:6o 38:6o 39:6fl 40:6fl 41:00 42:
7.4E7
L6.5E7
L5.7E7
L4.9E7
:4.1E7
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L2.5E7
L1.6E7
L8.2E6
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1)0 Time
-------
-------
-------
Sample Data
-------
15-OCT-1998 10:26:08 AM Dioxin Furan Unknown RESULTS
GC Column : DB-5
Data file : 050C98U
Weight : 0.00033
Name
dlO-2-Methylnaphthalene
d8-Naphthalene
Naphthalene
2-Methylnaphthalene
d8-Acenaphthylene
Acenaphthylene
dlO-Acenaphthene
Acenaphthene
dlO-Anthracene
dlO-Fluorene
Fluorene
dl0 -Phenanthrene
Phenanthrene
Anthracene
d!4-Terphenyl
dlO-Fluoranthene
Fluoranthene
dlO-Pyrene
Pyrene
d!2-Benzo(a)anthracene
Benzo(a)anthracene
d!2-Chrysene
Chrysene
d!2-Benzo(e)pyrene
d!2-Benzo(b)fluoranthene
Benzo(b)fluoranthene
d!2-Benzo(k)fluoranthene <•'
Benzo(k)fluoranthene
dl2-Benzo(a)pyrene t
Benzo (e) pyrene
Benzo(a)pyrene
d!2-Perylene
Perylene
dl2 -Indeno(123 -cd)pyrene
Indeno(123-cd)pyrene
d!4-Dibenz(ah)anthracene
Dibenz(ah)anthracene
d!2-Benzo(ghi)perylene
Benzo(ghi)perylene
Results : 050C98U271.RES
Date analyzed
PAHAIR.TEG
05-OCT-98
300681-1DI :1000X S-MM5-2-
Total Isotope R. T.
Response Ratio
87453800
139709200
889458000
1719680000
142923600
13040000
75989000
111200000
58496600
76622400
348000000
163762800
994324000
59600000
352630000
177834000
79386200
182455600
347368000
108326400
15560000
13 02 754 00
63800000
* 152767800
i 94234800"
5460000
151677600
3720000
110385800
9983200
3086660
.96580200
'23538200
53871600
944000
27068800
548000
53827000
1138000
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
.1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
,,00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
y
Y
Y
Y
Y
Y
Y
y
Y
y
Y
Y
Y
Y
Y
Y
Y
Y
mm:
10:
8:
8:
10:
13:
13:
14:
14:
19:
15:
15:
18:
18:
19:
24:
22 :
22:
23:
23:
27:
27:
27:
',27-
31:
30:
30:
30:-
30:
31:"
31:
' 31:
32 :
32:
36:
36:
36:
36:
37:
37:
SS
27
18
21
34
29
31
3
10
2
45
51
52
57
5
10
46
49
28
31
20
24
26
31
40
45
50
51
50
51
,46
56
J$
14
33
-41
39
49
49
58
Ex Cal
RRF
: PAHAlfcl00198U.RR
ug/ Rec/
"-c > SAUPLE
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
¥•&;<£
Y -.;:.". "" '
Y - •
Y
Y-..i ,
Y-.? '-•
Y
,YV .-V -.
Y." ':-.•''
Y
,Y •"
y
YKV^v
Y
Y
Y
Y
Y
1.
1.
1.
0.
1.
1.
0.
1.
1.
1.
1.
2 .
0.
0.
1.
1.
1.
1.
1.
0.
1.
00
78
20
66
16
02
68
14'
00
36
15 '
74
95
97
00
49
23
58
26
81
28
•JL.17
•>!..
1.
0.
.1-
•Q.
1.
0.
16
00
48
30
99
20
74
1.62
1.
0.
11
65
1.74"
.t).
0.
0.
1.
0.
1.
37
60
20
28,.
41 l
11
0
0
803
2839
0
13
0
'• 194
0
0
600
0
965
56
0
0
54
0
229
0
17
0
63
0
0
6
0
3
0
8
3
.To
21
0
4
0
'- 2
0
2
.05
.04
.60
.41
.07
MDL
V^J:
90
140
.49
-------
15-OCT-1998 10:27:33 AM Dioxin Furan Unknown RESULTS
050C98U271.RES
Date analyzed
1000X S-MM5-2- Ex Cal
Isotope R. T. RRF
Ratio tran:ss
PAHAIR.TRG
05-OCT-98
PAHAIR100198U.RRF
ug/ Rec/
SAMPLE MDL
0.00033
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
10:
8:
8:
10:
13:
13:
14:
14:
19:
15:
15:
18:
18:
19:
24:
22:
22:
23:
23:
27:
27:
27:
27:
31:
30:
30:
30:
30:
31:
31:
31:
32:
32:
36:
36:
36:
36:
37:
37:
27
18
21
34
29
31
3
10
2
45
51
52
57
5
10
46
49
28
31
20
24
26
31
40
45
50
51
50
51
46
56
9
14
33
41
39
49
49
58
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
1
1
1
0
1
1
0
1
1
1
1
2
0
0
1
1
1
1
1
0
1
1
1
1
0
1
0
1
0
1
1
0
1
0
0
0
1
0
1
.00
.78
.20
.66
.16
.02
.68
.14
.00
.36
.15
.74
.95
.97
.00
.49
.23
.58
.26
.81
.28
.17
.16
.00
.48
.30
.99
.20
.74
.62
.11
.65
.74
.37
.60
.20
.28
.41
.11
0
0
803
2839
0
13
0
194
0
0
600
0
965
56
0
0
54
0
229
0
17
0
63
0
0
6
0
3
0
8
3
0
21
0
4
0
2
0
2
.05
.04
.60
.41
.07
90
140
.49
-------
13-OCT-1998 10:37:32 AM Dioxin Furan Unknown RESULTS
Results
GC Column : DB-5
Data file : 050C98.U
Weight : O.OOOS^
Name '
300681-1DI
Total
Response
050C98U271.RES
Date analyzed
:1000X S-MM5-2- Ex Cal
Isotope R. T. RRF
Ratio tnm:ss
PAHAIR.TRG
05-OCT-98
PAHAIR100198U.RRF
ug/ Rec/
-i SAMPLE MDL
dlO-2-Methylnaphthalene
d8-Naphthalene
Naphthalene
2-Methylnaphthalene
d8-Acenaphthylene
Acenaphthylene
dl0-Acenaphthene
Acenaphthene
dlO-Anthracene
dlO-Fluorene
Fluorene
dl0 -Phenanthrene
Phenanthrene
Anthracene
d!4-Terphenyl
dlO-Fluoranthene
Fluoranthene
dlO-Pyrene
Pyrene
d!2-Benzo(a)anthracene
Benzo(a)anthracene
d!2-Chrysene
Chrysene
d!2-Benzo(e)pyrene
d!2-Benzo(b)fluoranthene f
Benzo (b) fluoranthene $>
dl2-Benzo (k) fluoranthene,,
Benzo(k)fluoranthene'
dl2 -Benz o(a)pyrene|
Benzo (e) pyrene;
Benzo(a)pyrene
d!2-Perylene-
Perylene5
d!2-Indeno(123 -cd)pyrene,
Indeno(123-cdjpyrene
d!4-Dibenz(ah)anthracene
Dibenz(ah)anthracene
d!2-Benzo(ghi)perylene
Benzo(ghi)perylene
87453800 1.00 Y
139709200 1.00 Y
889458000 1.00 Y
1719680000 1.00 Y
142923600 1.00 Y
13040000 1.00 Y
75989000 1.00 Y
111200000 1.00 Y
58496600 1.00 Y
76622400 1.00 Y
348000000 1.00 Y
163762800 1.00 Y
994324000 1.00 Y
59600000 1.00 Y
352630000 1.00 Y
177834000 l.OO.Y
79386200 1.00 Y
182455600 1.00 Y
347368000 1.00 Y
108326400 1.00 Y
15560000 1.00 Y
130275400 1.00 Y
63800000 il.00 Y
152767800 1.00 Y
94234800'1.00 Y
' 5460000 1.00 Y
151677600 1.00 Y
3720000 1.00 Y
110385800 1.00 Y
9983200 l.QO Y
3086660 1.00 Y
96580200 1.00 Y
- 23538200;1.00 Y
53871600 1.00 Y
944000 1.00 Y
27068800 1.00 Y
548000 1.00 Y
53827000 1.00 Y
1138000 1.00 Y
10:
8:
8:
10:
13:
13:
14:
14:
19:
15:
15:
18:
18:
19:
24:
22:
22:
23:
23:
27:
27:
27':
,27:
31:
SO-
SO:
30:
30r
31:
31:
31:
32:
32:
36:
36:
36:
36:
37:
37:
27
18
21
34
29
31
3
10
2
45
51
52
57
5
10
46
49
28
31
20
24
26
co-
45
50
51
50
51
46
56
9
14
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
1.
1.
1.
0.
1.
1.
0.
1.
1.
1.
1.
2.
0.
0.
;i 1-
* J 1-
'"-• 1.
1.
1.
0.
1.
. #:.-!.
£*$?-*'.
r ;-i-
00
0.
7 3" A 0.
20;
6S
16
02
68
14,.,
00
36
15'
74
95"
97
00
49
23
58
26
81
28
17
16
00
530.
1874.
0.
8.
. 0.
;. 128.
0.
0.
396.
0.
637.
37.
0.
0.
36.
0.
151.
0.
11.
0.
42.
0;
05
04
38
01
07
90«c2i*>
^fctVI
06
41
05
05
37
05
50
43ioo -
34,
-ilQQ-
33*
38 '
-*mr
32 '
i* •: -
,128"
-Lv-
10i
r
98,
-D * O o < .KJUT^^TTjp
2-
0.
52
-------
13-OCT-1998 10:37:26 AM Dioxin Furan Unknown RESULTS
050C98U271.RES
Date analyzed
1000X S-MM5-2- Ex Cal
Isotope R. T. RRF
Ratio ram:ss
PAHAIR.TRG
05-OCT-98
PAHAIR100198U.RRF
ug/ Rec/
SAMPLE MDL
0.0005
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
10:
8:
8:
10:
13:
13:
14:
14:
19:
15:
15:
18:
18:
19:
24:
22:
22:
23:
23:
27:
27:
27:
27:
31:
30:
30:
30:
30:
31:
31:
31:
32:
32:
36:
36:
36:
36:
37:
37:
27
18
21
34
29
31
3
10
2
45
51
52
57
5
10
46
49
28
31
20
24
26
31
40
45
50
51
50
51
46
56
9
14
33
41
39
49
49
58
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
1
1
1
0
1
1
0
1
1
1
1
2
0
0
1
1
1
1
1
0
1
1
1
1
0
1
0
1
0
1
1
0
1
0
0
0
1
0
1
.00
.78
.20
.66
.16
.02
.68
.14
.00
.36
.15
.74
.95
.97
.00
.49
.23
.58
.26
.81
.28
.17
.16
.00
.48
.30
.99
.20
.74
.62
.11
.65
.74
.37
.60
.20
.28
.41
.11
0
0
530
1874
0
8
0
128
0
0
396
0
637
37
0
0
36
0
151
0
11
0
42
0
0
4
0
2
0
5
2
0
13
0
2
0
1
0
1
.05
.04
.38
.01
.07
90
140
. 90
-------
07-OCT-1998 05:13:25 PM Dioxin Furan Unknown RESULTS
Mass Spec : ULTIMA
GC Column : DB-5
Data file : 050C98U
Weight : 0.5
Name
dlO-2-Methylnaphthalene
d8-Naphthalene
Naphthalene
2-Methylnaphthalene
d8-Acenaphthylene
Acenaphthylene
dlO-Acenaphthene
Acenaphthene
dlO-Anthracene
dlO-Fluorene
Fluorene
dl0-Phenanthrene
Phenanthrene
Anthracene
d!4-Terphenyl
dl0-Fluoranthene
Fluoranthene
dlO-Pyrene
Pyrene
d!2-Benzo(a)anthracene
Benzo(a)anthracene
d!2-Chrysene
Chrysene
d!2-Benzo(e)pyrene
d!2-Benzo(b)fluoranthene
Benzo(b)fluoranthene
d!2-Benzo (k) fluoranthene;:
Benzo(k)fluoranthene"
dl2-Benzo(a)pyrene?
Benzo (e) pyrene;,
Benzo(a)pyrene
d!2-Perylene
Perylenei
d!2-Indeno(123-cd)pyrene,
Indeno(123-cd)pyrene
d!4-Dibenz(ah)anthracene
Dibenz(ah)anthracene
d!2-Benzo(ghi)perylene
Benzo(ghi)perylene
Results : 050C98U271.RES
Date analyzed
PAHAIR.TRG
05-OCT-98
300681-1DI :100X S-MM5-2- Ex
Total Isotope R. T.
Response Ratio
87453800
139709200
889458000
1719680000
142923600
* No Peak
75989000
120826600
58496600
76622400
363956000
163762800
994324000
* No Peak
352630000
177834000
79386200
182455600
347368000
108326400
23512800
130275400
78755600
f 152767800,
i 94234800*
'• 9206940*
<•
j 151677600
9206940
F 110385800
998320Q
3086660
96580200
i 23538200
53871600
439952
27068800
338982
53827000
685812
1.00
1.00
1.00
1.00
1.00
0.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
0.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
Y
Y
Y
Y
Y
N
Y
Y
Y
Y
Y
Y
Y
N
Y
.Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Cal :
RRF
PAHAIR100198U.RR
ng/ Rec/
mm: ss
10:
8:
8:
10:
13:
13:
14:
14:
19:
15:
15:
18:
18:
19:
24:
22:
22:
23:
23:
27:
27:
'27:
27V
31:
30.
30:
30:
30:
31i
31:
31:
32:
'••32:
36:
36V
36:
36:
37:
37:
27
18
21
34
29
31
3
10
2
45
51
52
57
5
10
46
49
28
31
20
24
26
31
40
45
50
51
50
51
46
56'
9_
14.
33
4i
39
49
49
58
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
N
Y
Y
Y
Y
Y
Y
Y
Y >
**.-.-;*
•Y •";*--
\
Y
Y- -;'-*•*••
Y-'"
YVv
Y""3-'
Y —
Y.-,
Y'
Y* «X
YV'.r
Y
Y
Y
Y
1
1
1
0
1
1
0
1
1
1
1
2
0
0
1
1
1
1
1
0
1
; 1
>1
- 1
0
1
•^tl
"1
0
1. 1
' i
0
1
VI.D
*' *0
0
1
.00
.78
.20
.66
.16
.02
.68
.14
.00
.36
.15-
.74
.95
.97
.00
.49
.23
.58
.26,
.81
.28
.17
:ie
.00
.48
.30
.99
^20
.74
.62
.11
.65
.74
-37
.60
.20
.28
SAMPLE
.50
44
530
1B74
70
0
63
' 139
50
48
414
51
637
0
50
16
36
16
151
18
16
15
. 52
50
64
7
50
5
48
5
2
-' 48
'13
47
1
" 43
•'• o
.00
.79
.38
.01
.22
.00
.70
.53
.00
.08
.54
.12
.50
.00
.00
.91
.24
.42
.42
.91
.95
.82
.10
.00
~i2
'.52
.34
.05
.90
.58
.52
.90
.98
.36
.35
.56
.98
MDL
0
90
.000
0.000
0
0
0
0
0
0
0
0
0
.-.--
"V
0
0
0
0
Jo
0
0
J.40
.000
127
.000
96
.000
102
.000
.000
"34^
.000
33
.000
38
.000
32
- °°A
= ?
*- 128
.000
101
.000
98
,000
.000
98
.000
95
.000
87
.000
0.41- ;' 43.05IO&6
1.11
1
.15
0
.000
-------
File:05OC98U #1-509 Acq: 6-OCT-1998 13:56:44 GC EI+ Voltage SIR Autospec-Ultima
Sample#27 Text:300681-lDI :100X S-MM5-2- Exp:PAHAIR
128.0626 S:27 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
o
1002
80 J
60 J
40J
20 J
0 :
A4.45E8
\
\ ^^
1-"= — i *•" j 1 i 1 1 1 T —
8:00 9:00
134.0827 S:27 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0
100 3A6. 2E4
80 J
60 J
40 J
20 J
o-
/
__ —s~^^-^~^^__s^_^___, — ^.s^S
8:do 9:do
136.1128 S:27 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0
100%
80 1
60 J
40J
20 J
0 "
A6.99E7
^
A5.83E6 J
/"\ 1 ^
8:dfl 9:do
142.0782 S:27 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0
1002
80 J
60 J
40J
20 J
0
8:do 9:do
1.4E8
A4.93E7_ A^^1^__A1J55Z^_^— . _~J^3^L_-^ ~
L1.2E8
i8.7E7
-5.8E7
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File:05OC98U #1-509 Acq: 6-OCT-1998 13:56:44 GC EI+ Voltage SIR Autospec-Ultima
Sample#27 Text:30068MDI :100X S-MM5-2- Exp:PAHAIR
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File:05OC98U #1-509 Acq: 6-OCT-1998 13:56:44 GC EI+ Voltage SIR Autospec-UItima
Sample#27 Text:300681-lDI :100X S-MM5-2- Exp:PAHAlR
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File:05OC98U #1-509 Acq: 6-OCT-1998 13:56:44 GC EI+ Voltage SIR Autospec-Ultima
Sample#27 Text:30068MDI :100X S-MM5-2- Exp:PAHAIR
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File:05OC98U #1-509 Acq: 6-OCT-1998 13:56:44 GC EI+ Voltage SIR Autospec-Ultima
Sample#27 Text:300681-lDI :100X S-MM5-2- Exp:PAHAIR
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File:05OC98U #1-585 Acq: 6-OCT-1998 13?56:44 GC EI+ Voltage SIR Autospec-Ultima
Sample#27 Text:300681-lDI :100X S-MM5-2- ExprPAHAIR
166.0798 S:27 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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File:05OC98U #1-585 Acq: 6-OCT-1998 13:56:44 GC EI+ Voltage SIR Autospec-Ultima
Sample#27 Text:30068MDI :100X S-MM5-2- ExprPAHAIR
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-------
File:05OC98U #1-585 Acq: 6-OCT-1998 13:56:44 GC E1+ Voltage SIR Autospec-Ultima
Sample#27 Text:30068MDI :100X S-MM5-2- Exp:PAHAlR
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File:050C98U #1-585 Acq: 6-OCT-1998 13:56:44 GC E1+ Voltage SIR Autospec-Ultima
Sample#27 Text:300681-101:100X S-MM5-2- Exp:PAHAIR
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File:050C98U #1-1052 Acq: 6-OCT-1998 13:56:44 GC EI+ Voltage SIR Autospec-Ultima
Sample#27 Text:30068MDI :100X S-MM5-2- Exp:PAHAlR
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File:05OC98U #1-1052 Acq: 6-OCT-1998 13:56:44 GC EI+ Voltage SIR Autospec-Ultima
Sample#27 Text:30068MDI :100X S-MM5-2- Exp:PAHAIR
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File:05OC98U #1-1052 Acq: 6-OCT-1998 13:56:44 GC EI+ Voltage SIR Autospec-Ultima
Sample*27 Text:300681-lDI :100X S-MM5-2- Exp:PAHAIR
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-------
File:05OC98U #1-1052 Acq: 6-OCT-1998 13:56:44 GC EI+ Voltage SIR Autospec-Ultima
Sample#27 Text:300681-lDI :100X S-MM5-2- Exp:PAHAIR
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File:05OC98U #1-915 Acq: 6-OCT-1998 13:56:44 GC EI+ Voltage SIR Autospec-Ultima
Sample/T27 Text:300681-lDI :100X S-MM5-2- Exp.-PAHAIR
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-1.8E7
L1.6E7
Ll.4E7
L1.3E7
1.1E7
9.0E6
t-7.2E6
5.4E6
31
32:4
^ 33:60
34:1
1.8E6
1 O.OEO
)0 Time
-------
s s
b 121
-------
File:050C98U #1-915 Acq: 6-OCT-1998 13:56:44 GC E1+ Voltage SIR Autospec-Ultima
Sampled? Text:300681-IDI :100X S-MM5-2- Exp:PAHAlR
276.0939 S:27 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 % A3.43E5
80
60
40
20 J
0.
36:0037:6fl 38:00
288.1692 S:27 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 % A2.69E7
A2.69E7
80.
60 -
40
20 J
39:C
36:00 37:00 38:1)0
278.1096 S:27 F:4 SMO(1,3) PKD(S,3,3,0.10%,10000.0,0.00%,F,T)
100 % ^fy, A1.69E5
80 J
60
40
20 J
0
39:00
40:00
—1 1 r 1 1 1 1 1 r 1 1 , , , r
36:00 37:00 38:00
292.1974 S:27 F:4 SMO(1,3) PKD(S,3,3,0.10%,10000.0,0.00%,F,T)
100 % A1.35E7
80 J
60
40
20
So"
40:00
41 :<
8.0E4
6.4E4
4.8E4
L3.2E4
A.6E4
LO.OEO
)0 Time
2.9E6
41:
.1.7E6
-1.2E6
L5.8E5
O.OEO
)0 Time
3.6E4
t.2.7E4
1.8E4
-9.0E3
.O.OEO
)0 Time
_1.4E6
L1.1E6
8.2E5
-5.4E5
:.2.7E5
O.OEO
)0 Time
39
0-
36:00
37:6fl "
38:6o
41:
39:00
40:00
41:(
-------
F!le:05OC98U #1-915 Acq: 6-OCT-1998 13:56:44 GC E1+ Voltage S» Autospec-UItima
Sampled? Text:300681-lDI :100X S-MM5-2- £xp:PAHAIR
276.0939 S:27 F:4SMO(1,3) PKD(5,3,3,0.10%>10000.0,0.00%,F,T)
100%
90-
80
70
60 j
50 j
40J
30 j
20
10-
OJ
A5.69E5
A4.72E5
36:6b 36:ii 36:24 36:36 36:48 37:66 37:ii 37:24 37:36 37:48 38:00 38:li 38:24 38:36 38:48 39:66
r8.0E4
17.2E4
6.4E4
L5.6E4
4.8E4
14.0E4
L3.2E4
2.4E4
-1.6E4
8.0E3
O.OEO
Time
2.9E6
2.6E6
2.3E6
-2.0E6
1.7E6
M.5E6
1.2E6
8.7E5
5.8E5
2.9E5
288.1692 S:27 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
90
80 -
70 J
60
SO
40J
30
20 _
A2.69E7
A2.69E7
'ni i i i"i i'i i r i i i i i i i i i i i i i i i i , i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i i
36:60 36:12 36:24 36:36 36:48 37:00 37:12 37:24 37:36 37:48 38:00 38:12 38:24 38:36 38:48 39:00
O.OEO
Time
-------
File:050C98U #1-915 Acq: 6-OCT-1998 13:56:44 GC EI+ Voltage SIR Autospec-Ultima
Sample#27 Text:300681-lDI :100X S-MM5-2- Exp:PAHAlR
478.1096 S:27 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
A2.74E5
90
80 j
70 j
60 -
50
40-
30 J
20 J
10
0
4.5E4
4.004
L3.6E4
L3.1E4
2.7E4
2.2E4
il.8E4
i-1.3E4
L9.0E3
4.5E3
O.OEO
' ' 36:66 36:ii 36:24 ' 36:36 ' ' 36:48 ' 37:66 ' 37:lz 37:24^ ' 37:36 ' 37:48 ' 38?00 ^38:14 ' ' 38:24 38:36 "38:48 ' 39:66 Time
292.1974 S:27 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
A1.35E7
100 S
90.:
80 J
70
60
50 4
40
30 J
20
10
0
.-1.4E6
1.2E6
L1.1E6
-9.5E5
L8.2E5
6.8E5
5.4E5
-4.1E5
L2.7E5
L1.4E5
LO.OEO
' ' 36:00 ' ' 36:^2 ' ' 36:24 ' ' 36:36 ' ' 36:48' ' ' 37:66 ' ' 37:ki ' ' 37:24 ' ' 37:36 ' 37:48 38:6o 38:^2 38:24 38:36 ' 38:48 39:6o Time
-------
to
FHe:050C98U #1-915 Acq: 6-OCT-1998 13:56:44 GC EI+ Voltage SIR Autospec-Ultima
Sample#27 Text:300681-lDI :100X S-MM5-2- Exp:PAHAlR
268.9824 S:27 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
A1.28E6
v-rrrvm
100 S>
90 J
80 j
70 J
60 J
sol
40-
30-
201
101
0:
A3.65E6 A3.86E6 A1.15E6
A8.34E6
30:60 31:00 32:6o 33:00 34:00
280.98245:27 F:4SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
90-:
80 J
70 J
60 J
50 J
40 J
30 j
20
10
04
35:6o'
A2.11E7
"30:00 37:UO 38:00 39:6fl
A3.02E7 A1.87E7
4o7ooT~"~"
A2.56E7
, ,-J-
41:0
30:
h6o ' ' '32:60 ' '33:00' ' ' '34:6o' ' '35:6o'
41:
.-6.3E6
5.7E6
5.0E6
4.4E6
-3.8E6
3.1E6
:1.9E6
1.3E6
( v--
O.UhO
iO Time
,_2.2E7
2.0E7
1.7E7
1.5E7
-1.3E7
1.1E7
I-8.7E6
6.5E6
t-4.4E6
2.2E6
O.OEO
)0 Time
-------
02-SEP-1998 07:05:35 PM Dioxin Furan Unknown RESULTS
GC Column -. DB-5
Data file : 20AU98U
Weight : 0.333
Name
dlO-2-Methylnaphthalene
d8-Naphthalene
Naphthalene
2-Methylnaphthalene
d8-Acenaphthylene
Acenaphthylene
dlO-Acenaphthene
Acenaphthene
dlO-Anthracene
dlO-Fluorene
Fluorene
dlO-Phenanthrene
Phenanthrene
Anthracene
d!2-Benzo(e)pyrene
dl0-Fluoranthene
Fluoranthene
dlO-Pyrene
Pyrene
dl2-Benzo(a)anthracene
Benzo(a)anthracene
d!2-Chrysene
Chrysene
d!2-Benzo(e)pyrene
d!2-Benzo(b)fluoranthene
Benzo(b)fluoranthene
^
d!2-Benzo(k)fluoranthene
Benzo(k)fluoranthene
d!2-Benzo(a)pyrene
Benzo(e)pyrene
Benzo(a)pyrene
dl2-Perylene
Perylene
d!2-Indeno(123-cd)pyrene
Indeno(123-cd)pyrene
dl4-Dibenz(ah)anthracene
Dibenz(ah)anthracene
d!2-Benzo(ghi)perylene
Benzo(ghi)perylene
d8-Naphthalene
13C-Naphthalene
Results : 20AU98U171.RES : PAHX.TRG
Date analyzed : 20-AUG-98
300681-3 --T-MM5-2-F
Total Isotope
--. Response Ratio
65564600
53317400
6996500000
10409320000
i 1 ft c HI *? n n
202000000
32254800
900880000
27200000
12997740
1880666000
43964200
5240000000
424000000
198459000
47800000
402000000
48600000
1140000000
80200000
206000000
88200000
1206000000
f 198459000
f, 125629800
t 142400000
/ 119946200
43000000
f 123865000
<; 218000000
40200000
75828400
) 434000000
244686000
20200000
158472400
18280000
220988000
64842800
53317400
446652
1.
1.
1.
1.
T
• -L .
l.
1.
l.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
.a.
,1.
,1.
i.
i.
i.
i.
i.
i.
i.
i.
i.
i.
i .
i.
i.
i.
i.
i.
00
00
00
00
nn
uu
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
0D
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
,00
Y
Y
Y
y
v
X
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
y
Y
Y
Y
Y
Y
Y
Y
Y
Y .
Y
Y
Y
Y
Y
Y
Y
Y
Y
:Trai Ex Cal :
R. T. RRF
PAHX081998U.RRF
ng/ Rec/
mm:ss
11:
8:
9:
11:
1 A -
Xfr I
14:
14:
14:
19:
16:
16:
19:
19:
19:
32:
23:
23 :
24:
24:
28:
28:
28:
28;
32:
31:
31:
31:
31:
32:
32:
32:
33 •
33:
37:
38:
37:
38:
39:
39:
8:
9:
11
57
1
17
i f,
-Lo
18
49
55
46
31
37
41
40
46
39
33
38
16
20
7
11
14
.18
39
39
45
45
48
51
45
57
10
15
sa
6
59
9
22
31
57
1
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y--."
Y •
Y
Y
Y.
TT ,- -
Y
Y*-*
Y 'i
Y
1.
1.
1.
0.
T
X .
0.
0.
0.
1.
1.
1.
2 .
0.
0.
1.
0.
1.
0.
1.
0.
1.
rr-a.
Vtfb\
- "• i .
o'
. 1.
•-**;o .
""i.
»«;-' o
.'-, i
i
00
25
05
77
C c:
D D
86
88'
93.
00
13
05--
63,
84
83.
00
80
04
81
11
65
,06
.as
;9T
.00
^63
.07
.90
.16
.75
.46
.02
SATiP
50,
32.
MDL
00
64
1.96+04 €1
.
65
o .
• ir
*.y u .
28.
4510.
50.
21.
'j>&
\J "^
A r" """""^'^
ID
04
28 &
00
15 _
^ n
56
s
42 ^
2.16+04 t p>
30.
74
61
2 .16+04 C '&>
1746.
50.
14.
1213.
15.
3180.
31.
365.
26
2113.
50.
65 ^
00
99
66 ^
12
44 C.
07
48
20
76 e
.00 ::'
50.56" '
159.
33 .
46.
41
180
47
,19
.72
.58
.54
.47
.60
,Y 0.-61 .31.09V '
r
- Y- <-,
Y
Y
Y
Y
Y
Y
Y
i
,^>;0
" 0
0
1
0
0
1
1
.62
.71
!ei
.44
.11
.63
.99
.00
.00
531
87
20
90
15
. 08 '
.24
.27
.50
.57
;: ..azl&fi
'• 44
50
0
.47"
.00
.42
3dt: w
B -
30 „
62
52
5,
- «- -
101"
67
83
62 \
174
181
177 ,
1
-------
02-SEP-1998 07:05:35 PM Dioxin Furan Unknown RESULTS
dlO-Fluorene 12997740 1.00 Y 16: 31 Y 1.00 50.00
13C-Fluorene 14759680 1.00 Y 16: 37 Y -0-r6± ?0.3G
127
-------
02-SEP-1998 07:05:33 PM Dioxin Furan Unknown RESULTS
20AU98U171.RES
Date analyzed
MM5-2-F :Trai Ex Cal
Isotope R. T. RRF
Ratio mmrss
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
11:
8:
9:
11:
14:
14:
14:
14:
19:
16:
16:
19:
19:
19:
32:
23:
23:
24:
24:
28:
28:
28:
28:
32:
31:
31:
31:
31:
32:
32:
32:
33:
33:
37:
38:
37:
38:
39:
39:
8:
9:
11
57
1
17
16
18
49
55
46
31
37
41
40
46
39
33
38
16
20
7
11
14
18
39
39
45
45
48
51
45
57
10
15
58
6
59
9
22
31
57
1
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
PAHX.TRG
20-AUG-98
PAHX081998U.RRF
ng/ Rec/
SAMP MDL
0.333
1.00 50.00
1.25 32.64
1.05 1.96+04
0.77 3.86+04
1.55 58.30
0.86 296.45
0.88 28.04
0.93 4510.28
1.00 50.00
1.13 21.15
1.05 2.16+04
2.63 30.74
0.84 2.16+04
0.83 1746.65
1.00 50.00
0.80 14.99
1.04 1213.66
0.81 15.12
1.11 3180.44
0.65
1.06
31.07
365.48
0.85 26 ..20
0.97 2113'-76
1.00) 50. Ou
0.63K 50.56
LOT 159.19
0.90
1.16
33.72
46.58
0.7S 41.54
1.46 180.47
1.02 47.60
0.61
1.62
0.71
0.61
0.44
1.11
0.63
0.99
1.00
1.00
31.09
531.08
87.24
20.27
90.50
15.57
88.33
44.47
50.00
0.42
32782300 32782300-j
65 26658700 26658700.-
3498250000 3498250000^
5204660000 5204660000.
117 59251600 59251600
101000000 101000000
56
42
61
30
30
62
52
16127400
450440000
13600000
6498870
940333000
21982100
2620000000
212000000
99229500
23900000
201000000
24300000
570000000
40100000
103000000
44100000
16127400 ,
450440000 '
13600000
6498870,
940333000-
•.;» '
2198210o'->
2620000000:t'
212000000'.,
99229500
23900000,
201000000K
24300000
570000000:
40100000
103000000
44100000*
101
67
83
62
174
181
177
,603000000 ^ 6Q30OQOOO
99229500^*'-99229500
62814900 62814900'
71200000. . 71200000.
59973100
21500000
59973100
21500000
61932500' 6.1932500
109000000 109000000
20100000 20100000
37914200;
217000000
122343000
10100000
79236200
9140000
110494000
32421400
26658700
223326
-.-37914200
217000000 -
122343t>00
10100000 ,
79236200-"-.
9140000 ".-
110494000. ,
32421400
26658700
223326
-------
02-SEP-1998 07:05:33 PM Dioxin Furan Unknown RESULTS
1.00 Y 16: 31 Y 1.00 50.00 6498870 6498870
1.00 Y 16: 37 Y 0.81 70.36 141 7379840 7379840
128
-------
24-AUG-1998 01:10:32 PM
PAH Unknown RESULTS
Mass Spec : ULTIMA
GC Column : DB-5
Data file : 20AU98U
Weight : 0.333
Name
dlO-2-Methylnaphthalene
d8-Naphthalene
Naphthalene
2-Methylnaphthalene
d8-Acenaphthylene
Acenaphthylene
dl0-Acenaphthene
Acenaphthene
dlO-Anthracene
dlO-Fluorene
Fluorene
dl0-Phenanthrene
Phenanthrene
Anthracene
d!2-Benzo(e)pyrene
dlO-Fluoranthene
Fluoranthene
dlO-Pyrene
Pyrene
d!2-Benzo(a)anthracene
Benzo(a)anthracene
d!2-Chrysene
Chrysene
dl2-Benzo(e)pyrene r
d!2-Benzo(b)fluoranthene 1
Benzo(b)fluoranthene !
d!2-Benzo (k) f luoranthenef
Benzo(k)fluoranthene
d!2-Benzo(a) py r en*.
Benzo (e) pyrene^-
Benzo (a) pyrene
d!2-Perylene.
Perylene!
d!2 - Indeno (12 3 - cd) pyrene-
Indeno(12 3 -cd)pyrene
d!4-Dibenz(ah)anthracene
Dibenz(ah)anthracene
d!2-Benzo(ghi)perylene
Benzo(ghi)perylene
d8-Naphthalene
13C-Naphthalene
Results : 20AU98U171.RES
Date analyzed
300681-3 .-T-MM5-2-F :Trai Ex Cal
Total Isotope R. T. RRF
Response Ratio mm:ss
PAHX.TRG
20-AUG-98
PAHX081998U.RRF
ng/ Rec/
SAHP MDL
65564600
53317400
6996500000
10409320000
*
*
*
*
118503200
440010000
32254800
900880000
No Peak
12997740
1880666000
43964200
No Peak
5239680000
198459000
No Peak
488552000
No Peak
1270632000
75165200
379224000
.80027800
1438530000
198459000
125629800
206552000
119946200
206552000
123865000
270934000
107968000
75828400
494680000
244686000
27197600
158472400
41365000
220988000
64842800
53317400
446652
1.
1
1
1
1
1
1
1
0
1
1
1
0
1
.1
0
'1
0
1
1
1
1
,a
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
:oo
.00
.00
.00
.00
.00
wOD
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
Y
Y
Y
Y
Y
Y
Y
Y
N
Y
Y
Y
N
Y
Y
N
Y
N
Y
Y
Y
Y
,T
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
11:
8:
9:
11:
14:
14:
14:
14:
19:
16:
16:
19:
19:
19:
32:
23:
23:
24:
24:
28:
28:
28;'
ia^
32:
31:
31.:
31:
31:
32:
32:..
32:
33-,
33:
37:
38:
37:
38:
39:
39:
8:
9:
11
57
1
17
16
18
49
55
46
31
37
41
40
46
39
33
38
16
20
7
11
14
18
39
39
45
45
45
51
45
57
10
15
58
6
59
9
22
31
57
1
Y
Y
Y
Y
Y
Y
Y
Y
N
Y
Y
Y
Y
Y
Y
N
Y
N
Y
Y
Y
Y;
.Yi.
Y
Y
Y..
Y
Y
¥;
Y:*
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
1.00
1.25
1.05
0.77
1.55
0.86
0.88
0.93
1.00
1.13
1.05 ,
2.63
0.84
0.83
1.00
0.80
1.04
0.81
1.11
0.65
1.06
V-X-.',Q~S5
.•o.;*i,~90
l!l6
„*'»•*- Q.-75
^:'vC;rl46
1.02
0.61
1.62
*W'OV71
'•'" o!ei
0.44
1.11
30.00
32.64
1.96+04
3.8e+04
58.30
645.74
28.04
4510.28
50.00
' *NoR?
2.16+04
*NoR?
0.00
2.26+04
50.00
0.00
0.
0.
0.
0.
0.
0.
0.
65
000
000
117
000
56
000
.000
.000
.000
o"
*NoINoIS
0.00
0
*NoINoIs
29.12
717.87
23.77
277B.78
50.00;
50.56
230.91
33.72
223.77
41.54
224.28
127.84
31.09
605 .33
87.24
27.29
. 90.50
• 35.23
0
0
* ~ ~ -,
0
0
0
0
0
0
0
0.63-* 88.33
0.99
1.00
1.00
58
.000
48
.000
101
.000
67
.000
83
.000
.000
62'
.000
174
.000
181
.000
177
44.471&gOO
50.00
0.42
1
-------
24-AUG-1998 01:10:32 PM PAH Unknown RESULTS
dlO-Fluorene 12997740 1.00 Y 16: 31 Y 1.00 50.00
13C-Fluorene 14759680 1.00 Y 16: 37 Y 0.81 70.36 141
131
-------
FHe:20AU98U #1-476 Acq:21-AUG-1998 03:44:49 GC EI+ Voltage SIR Autospec-Ultima
Sample#17 Text:300681-3 :T-MM5-2-F :Trai Exp:PAHAIR
128.0626 S:17 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
80
60
40J
20 J
0
A3.50E0
A3.56E8
9:00 10:00
134.0827 S:17 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%,
80 J
60 J
40J
20 J
OJ , , , _^ , , , | - r=_
9:00 10:00
136.1128 S:17 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100% A3.S
on :
w- A2.67E7
60J
40J
20.
A2.23E5
A4.58E4 / \ _ A3.49E4
9:00 10-60
142.0782 S:17 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
11:00
A8.65E4
A1.72E5
=F
12:00
11:00
' 12:60
13:00
9.4E8
L7.5E*
LS.6E8
3.7E8 "
L1.9E8
LO.OEO
Time
13:
2.1E5
L1.7E5
il.3E5
8.6E4
U.3E4
LO.OEO
)0 Time
1.1E7
L9.1E6
L6.8E6
L4.5E6
L2.3E6
LO.OEO
13:00 Time
iv\> ze
80 J
60 J
40J
20 1
0
' ns.fju&y
\ l\
j v_ y
V
9:00 10:6o 11:00 12:00 13:
_i.ic,y
L6.4E8
L4.3E8
L2.1E8
O.OEO
bo Time
152.1410 S:17 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F>T)
100 S
80 J
60 i
40J
20 1
o -
A3.2
J
JE7
V_
9:(JO 10:6o ll:6o 12:6fl 13:'
8.7E6
L6.9E6
L5.2E6
L3.5E6
L1.7E6
O.OEO
)0 Time
-------
File:20AU98U #1-476 Acq:21-AUG-1998 03:44:49 GC EI+ Voltage SIR Autospec-Ultima
Samp!e#17 Text:300681-3 .-T-MM5-2-F :Trai Exp.-PAHAIR
152.0626 S:17 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 % A3.42E8 A6.C
13:00 13:12 13:24 13:36 13:48 14:66 14:i2 14:24
154.0782 S:17 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
A2.92E8
14:48 15:00
A4.50E8
15:24 15:36
A4.40E8
A1.72E8
.36E7
A1.27E8
13:00 13:12 13:24 13:36 13:48 14:6o 14:i2T 14-24
164.1410 S:17 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
80
60
40-
20 J
0
14:36 14:48 15:00 15:12 15:24 15:36
A1.61E7
A4.54E5
13:00 13:12 13:24 13:36 13:48 14:00
160.1128 S:17 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
15:24 15:36
A2.15E7
A1.32E7
OEO
Time
4.1E6
L3.3E6
L2.4E6
U.6E6
L8.2E5
O.OEO
" 1—i—i—r—i—I—i—i—!—I—i—I—i—I—I—r—i—I—i—l—I—I—i—1—i—i—i—i—i—|—i—i—i—i—i—I—i—i—i—i—i—i—i—r-i—I—i—[—i—i—i—i—i—I—i—i—l—i—i—[—i—i—i—c—l—r—i—i—I—i—r—i—I—I—i—i—\—i—i—i—i—pJ-w.w^w
13:00 13:12 13:24 13:36 13:48 14:00 14:12 14:24 14:36 14:48 15:00 15:12 15:24 15:36 Time
-------
CO
File:20AU98U #1-476 Acq:21-AUG-1998 03:44:49 GC E1+ Voltage SIR Autospec-Ultima
Sample#17 Text:300681-3 :T-MM5-2-F ;Trai Exp:PAHAIR
152.0626 S:17 SMO(1,3) PKD(5,3,3,0.10%,5000.0,0.00%,F,T)
100 % A6.02EI
13:36 •••-•- '"
160.1128 S:17 SMO(1,3) PKD(5,3,3,0.10%,5000.0,0.00%,F,T)
1003
"T—i i •r"Tii"T~Ji i -r i i 11—i—r r—v r i—i—i—r—i—i i ' i—i—i—i—i—i—i—r—i—i—i—i—i—i—r—T—i—i—i—i—i—i—i—T—r—T—i
13:36 13:42 13:48 13:54 14:00 14:06 14:12 14:18 14:24
14:
r~r
:30
14:3
O.OEO
14:42 Time
-------
03
File:20AU98U #1-476 Acq:21-AUG-1998 03:44:49 GC EI+ Voltage SIR Autospec-Ultima
Sample#17 Text:300681-3 :T-MM5-2-F :Trai Exp:PAHAIR
130.9920 S:17 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
A1.94E8
A8.64E7 A5.80E7
A4\17E7
10
:00
11:00 12:00 13:1)0 14:00^ 15:00
-O.OEO
Time
-------
File:20AU98U #1-666 Acq:21-AUG-1998 03:44:49 GC EI+ Voltage SIR Autospec-Ultima
Sample#17 Text:300681-3 :T-MM5-2-F sTral Exp:PAHAIR
166.0798 S:17 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 % A9.4JQE8
TT~ji" i i I I I i i i i i i i' i I i i i i i i i i I i
16:00 16:12 16:24 16:36 16:48
172.0984 S:17 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.
100 % A7.38E6
90-
80 J
70^
60-
50-
40-
30-
20
10 J
15:48
16:00
16:
•\2 1^:24 16:36 16:48 17:66 17:i2 17:24 17:36 17:48 18:l)o' ' ' 18:li ' 18:24
176.1410 S:17 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
2.3E6
L2.1E6
L1.8E6
L1.6E6
L1.4E6
.1.1E6
L9.1E5
6.9E5
L4.6E5
L2.3E5
O.OEO
Time
1002
90 J
80 J
70 J
60 J
50 J
40J
30 J
20-
10 J
0-
-
]
p A6.50E6
fi
/
^ J \ _
5:48 16:66 16:i2 16:24 ' 16:36 16:48 17:66 17:12 17:24 17:36 17:48 18:66 18:ii 18:24
^2.0E6
-1.6E6
1.4E6
_1.2E6
L1.0E6
L8.1E5
L6.1E5
-4.1E5
2.0E5
O.OEO
Time
-------
F«e:20AU98U #1-666 Acq:21-AUG-1998 03:44:49 GC EI+ Voltage SIR Autospec-Ultima
Sample#17 Text:300681-3 :T-MM5-2-F :Trai Exp:PAHAIR
178.0782 S:17 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 ft A2.62E9
90
80
70 4
60
50
40
30 j
20.:
10
18:00
A3.13E8
A3.00E8 A
A
19
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20:i
21:11
22:
8.3E8
_7.5E8
-6.6E8
5.8E8
15.0E8
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3.3E8
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1.7E8
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O.OEO
30 Time
88.1410 S:17 F:Z SMOU,3) rKLH5,3,J,o.iuyc,iww"w-"»w-ww«)>1'>1'
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20:60 21:00 22:1
-6.9E6
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L5.5E6
L4.8E6
L4.1E6
L3.4E6
L2.7E6
L2.1E6
L1.4E6
L6.9E5
O.OEO
JO Time
-------
File:20AU98U #1-666 Acq:21-AUG-1998 03:44:49 GC EI+ Voltage SIR Autospec-Ultima
Samplem Text:300681-3 :T-MM5-2-F :Trai Exp:PAHAffi
178.0782 S:17 F:2 SMO(1,3) PKD(5,3,3>0.10%>5000.0,0.00%,F,T)
lop a
90
80 4
70
60 J
50-;
401
301
20 '-
101
0
A2.62E9
19:30
19:i6
19:42
188.1410 S:17 F:2 SMO(1,3) PKD(5,3,3,0.10%,5000.0,0.00%,F,T)
100
904
80
704
60
50-
tol
30-:
20
10-
19:30
19:48
19:54
20:00
20:00
A1.38E7
20:
19:36
19:42
19:48
19:54
20:06
8.3E8
L7.5E8
16.6E8
5.8E8
5.0E8
4.1E8
L.3.3E8
L2.5E8
L1.7E8
8.3E7
tO.OEO
2 Time
_6.9E6
L6.2E6
L5.5E6
4.8E6
4.1E6
3.4E6
2.7E6
2.1E6
L1.4E6
L6.9E5
O.OEO
20:il Time
-------
File:20AU98U #1-666 Acq:21-AUG-1998 03:44:49 GC EI+ Voltage SIR Autospec-Ultima
Sample#17 Text:300681-3 .-T-MM5-2-F :Trai Exp:PAHAIR
204.9888 S:17 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
16:60
17:60
18:00
O.OEO
0 Time
-------
O
File:20AU98U #1-935 Acq:21-AUG-1998 03:44:49 GC EI+ Voltage SIR Autospec-Ultima
Sample#17 Text:300681-3 :T-MM5-2-F ;Trai Exp:PAHAIR
202.0782 S:17 Fj3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 r
22:00 23-Jo24:6o
212.1410 S:17 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
90 J
80 J
70 J
60 J
50 J
40-J
30 J
20 J
10 J
OJ
A2.39E7
y\
A2.43E7
' i i ' i i 1 i r~—'i i i
22:00 23:00 24:6o
244.1974 S:17 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
90_
80-
70
60 j
50
40.:
30 J
20 J
10 J
0
T I I
I " I ' I ' I
26:00
22:00
23:(
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26:t
1.4E8
L1.3E8
L1.1E8
L9.7E7
L8.3E7
7.0E7
L5.6E7
L4.2E7
L2.8E7
L1.4E7
-O.OEO
Time
-1.1E9
-9.7E8
-8.6E8
.7.5E8
6.4E8
5.4E8
.4.3E8
3.2E8
2.1E8
1.1E8
O.OEO
Time
-------
File:20AU98U #1-935 Acq:21-AUG-1998 03:44:49 GC EI+ Voltage SIR Autospec-Ultima
Sample#17 Text:300681-3 :T-MM5-2-F :Trai Exp:PAHAIR
202.0782 S:17 F:3 SMO(1,3) PKD(5,3,3,0.10%,5000.0,0.00%,F,T)
100%
90-;
80
70 J
60 j
501
40
30
20
10
A5.70E8
A2.01E8
A1.27E8
86E8
o r., ,-r,,,, r^-A
23:66 ' ' 23:i2 23:i8 ' ' 23:24 ' ' 23:30 ' ' 23:36 ' 23:42 23:48 23:54 24:66 ' 24:06 24:ii 24:l8 24:24 24:30
212.1410 S:17 F:3 SMO(1,3) PKD(5,3,3,0.10%,5000.0,0.00%,F,T)
100 ^ A2.39E7
90
80
70
60 J
50-;
40
30
20
10 J
24:36
-1.9E8
L1.7E8
Ll.SES
1.3E8
11.1E8
L9.6E7
_7.7E7
L5.7E7
13.8E7
L1.9E7
O.OEO
0
A2.43E7
A6.20E5
A4.26E5
A4.41E5
Time
8.8E6
7.9E6
L7.0E6
L6.1E6
5.3E6
L.4.4E6
L3.5E6
L2.6E6
1.8E6
23:66 23:ii ' 23:i8 23:24 ' 23:30 ' 23:36 23:42 23:48 ' 23:54 24:66 24:66 24:ii 24:18 24:24 24:30
, ,-iO.OEO
24:36 Time
-------
File:20AU98U #1-935 Acq;21-AUG-1998 03:44:49 GC EI+ Voltage SIR Autospec-Ultima
Sample*!? Text:300681-3 tT-MM5-2-F :Trai Exp:PAHAIR
228.0939 S:17 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
A7.19E8
90_
80 j
70-
60^
501
40
30-
20 J
10 J
0
A4.75E7
A5.29E7
1.6E8
1.4E8
1.3E8
A7.48E7
J.05E7
26:36 26:48 27:66 27:12 27:24 27:36 27:48' 28:6o " 28:ii " 28:24 " 28:36 28:41 29:JW' ' 29:ii 29:24 29& ' 29:48 30:
-9.5E7
L7.9E7
L6.3E7
L4.7E7
L3.2E7
L1.6E7
O.OEO
)0 Time
*tv.i
00 S
90:
80 J
70 -
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50 J
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20-:
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26:36 "26:48" 27:66 "27:ii" 27:24 '27:36 "27:48 '28:66 28:ii 28:24 28:36 28:48 29:66 29:ii 29:24 29:36 29:48 30:1
1.5E7
L1.3E7
L1.2E7
L1.0E7
L8.8E6
-7.3E6
-S.9E6
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_2.9E6
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O.OEO
)0 Time
-------
-------
w-
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-------
FiIe:20AU98U #1-955 Acq:21-AUG-1998 03:44:49 GC EI+ Voltage SIR Autospec-Ultima
Sample#17 Text:300681-3 .-T-MM5-2-F :Trai Exp.-PAHAIR
252.0939 S:17 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
***
30:
A2.47E8
0
264.1692
100%
90 Jj
80
70 jj
60
50 J
40
30 4
20
10 J
31:00 32:00
S:17 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
33:00
34:00
0
30:
A6.28E7
A7.69E6
-O.OEO
Time
2.5E7
L2.2E7
L2.0E7
1.7E7
H.5E7
1.2E7
19.9E6
L7.4E6
4.9E6
2.5E6
-i r 1 1 1 r-
33:00
34:00
O.OEO
Time
)0
31 :C
32:
-------
FiIe:20AU98U #1-955 Acq:21-AUG-1998 03:44:49 GC EI+ Voltage SIR Autospec-Ultima
Sample#17 Text:300681-3 :T-MM5-2-F :Trai Exp:PAHAIR
252.0939 S:17 F:4
100 % A7.12
90
80 4
70
60
50 4
40
30 -
20 J
10
0-;
31:30 31:36 31:42
264.1692 S:17 F:4 SMO(1,3) PKD(5,3,3,0.10%,5000.0,0.00%,F,T)
100 % A6.2.8E7
31:48
31:54
32:00
90
80
70.;
60-
50.;
40J
30-
201
10
A6.00E7
A2.74E6
32:66
L.IJE7
L1.7E7
Ll.5E7
_1.3E7
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-8.6E6
6.5E6
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2.2E6
.O.OEO
Time
.1.7E7
_1.5E7
-1.3E7
-1.2E7
-1.0E7
-8.4E6
-6.7E6
-5.1E6
-3.4E6
1.7E6
lO.OEO
Time
31:30
31:36
"31:42
31:48
31:*
32:0
-------
File:20AU98U #1-955 Acq:21-AUG-1998 03:44:49 GC EI+ Voltage SIR Autospec-UItima
Sample#17 Text:300681-3 :T-MM5-2-F :Trai Exp:PAHAIR
252.0939 S:17 F:4
100 S>
90 J
801
70
60 J
50 J
40J
30 J
20 '-
10
A2.17E8
A1.09E8
5.9E7
15.3E7
4.7E7
-4.1E7
L3.5E7
L2.9E7
L2.4E7
1.8E7
1.2E7
5.9E6
, -O.OEO
33:36 Time
2.5E7
12.2E7
L2.0E7
Ll.7E7
L1.5E7
1.2E7
\-9.9E6
7.4E6
t-4.9E6
2.5E6
32:24 32:30 32:36 32:42 ' ' 32:48 ' ' '32:54
264.1692 S:17 F:4 SMO(1,3) PKD(5,3,3,0.10%,5000.0,0.00%,F,T)
33:6o 33:66 33:i2 33:is 33:24 33:30
100
90-:
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70 J
60 J
50 J
40
30-
201
10
0
A9.92E7
A6.19E7
.79E7
32:24 32:30 32:36 32:42 '32:48 32:54 33:6o 33:66 33:i2 ' 33:is 33:24 33:30 ' 33:36
O.OEO
Time
-------
'•GQ
FUe:20AU98U #1-955 Acq:21-AUG-1998 03:44:49 GC EI+ Voltage SIR Autospec-Ultima
Sample/ft? Text:300681-3:T-MMS-2-F:TraiExp:PAHAIR
276.0939 S:17 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 S> , A3
80-
60
20 J
A1.36E7
A2.10E6
A1.00E6
A8.37E5
—I 1 , 1 1 r ! 1 1 1 , r 1 1 —
36:00 37:00 38:00
288.1692 S:17 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 a A1.2J2E8
80
60
40J
20
39
I
:60
P40:o¥
-i 1 r
AI.10E8
—i 1 1 1 1 r 1 1 1 1 P -T 1 1
36:00 37:00 38:60
278.1096 S:17 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 % A2.0;
80 -
60-
4flJ
20 j
1 - r —
39:60
40:00
o
41
&
41:00
5.0E6
-4.0E6
L3.0E6
L2.0E6
A4.96E5
^
A5.48E5
42:
42:1
1.0E6
O.OEO
K) Time
1.5E7
Ll.2E7
9.2E6
16.1E6
L3.1E6
O.OEO
)0 Time
2.3E6
1.1.9E6
A.4E6
;.9.4E5
:4.7E5
LO.OEO
36:60 37:0038:00
292.1974 S:17 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 ft A7.92E7
80_
60 J
40
20 J
39:00
40
So~
o
36:00
, i i
37:
38:60
39:60
40
^
41
41:00
42:00 Time
9.6E6
L7.6E6
L5.7E6
L3.8E6
i.l.9E6
LO.OEO
)0 Time
42:
-------
File:20AU98U #1-955 Acq:21-AUG-1998 03:44:49 GC EI+ Voltage SIR Autospec-UItima
Sample#17 Text:300681-3 :T-MM5-2-F :Trai Exp:PAHAER
276.0939 S:17 F:4 SMO(1,3) PKD(5,3,3,0.10%,5000.0,0.00%,F,T)
100%
90
80
70 4
60
50 4
40
30 4
20
10 4
0
A3.24E7
A1.01E7
A4.68E6
A2.15E5
A5.32E5
c—I I I I—i—r-1—I—I—I—I—I—I—r—i—I—i—r-i—r—i—i—i—i—i I i—i—i—i—i—r—i—i—i—r-1—i—r—i—i—I—I I I—I I I i I i—r-i—i—I—I i I—I I i i i I I—i—i | i i I—i—I I i
37:36 37:48 38:00 38:12 38:24 38:36 38:48 39:00 39:12 39:24 39:36 39:48 40:00
-5.0E6
U.5E6
4.0E6
L3.5E6
3.0E6
L2.5E6
-2.0E6
1.5E6
P-1.0E6
5.0E5
.O.OEO
Time
1.5E7
1.1.4E7
L1.2E7
Ll.lE?
9.2E6
7.7E6
6.1E6
L4.6E6
13.1E6
L1.5E6
288.1692 S:17 F:4 SMO(1,3) PKD(5,3,3,0.10%,5000.0,0.00%,F,T)
1002
90 J
80
70 4
60
50 J
40
30_
20 -
A1.22E8
A1.10E8
i—i—I—i—i—i—i—i—i—i—i—i—i—i—!—i—i—i—i—i—I—i—i—i—i—i—I—i—i—i—i—i—i—i—i—i—i—i—I—r—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—r—i—i—i—i—i—i—i—i—i—i—i—;—i—i—i—i—i—i—i—i—r-
37:36 37:48 38:00 38:12 38:24 38:36 38:48 39:6fl 39:12 39:24 39:36 39:48 40:00
O.OEO
Time
-------
o
40
File:20AU98U #1-955 Acq:21-AUG-1998 03:44:49 GC EI+ Voltage SIR Autospec-Ultima
Sample#17 Text:300681-3 :T-MM5-2-F ;Trai Exp:PAHAIR
278.1096 S:17 F:4 SMO(1,3) PKD(5,3,3,0.10%,5000.0,0.00%,F,T)
A9.14E6
.41E6
A8.46E6
A6.54E6 / \A4.94E6
\^
y^"^
{ \
"^\A3
.t>5E6
A3.27E6
A3.44L6
37:36 37:48 38:66 38:i2 38:24 38:36
292.1974 S:17 F:4 SMO(1,3) PKD(5,3,3,0.10%,5000.0,0.00%,F,T)
100 % A7.92E7
90 j
80
70 J
60
50-
30 J
20 J
10-
0
38:48
39:66 39:U 39:24 39:
39:4» ' '40:00
2.3E6
-2.1E6
L1.9E6
:1.6E6
1.4E6
-1.2E6
L9.4E5
L7.0E5
:4.7E5
2.3E5
O.OEO
Time
9.6E6
-8.6E6
7.6E6
6.7E6
:5.7E6
L4.8E6
-3.8E6
2.9E6
-1.9E6
9.6E5
37:36 37:48 38:66 38:i2 38:24 38:36 38:48 39:66 39:h 39:24 39:36 39:48 40:66
O.OEO
Time
-------
File:20AU98U #1-955 Acq:21-AUG-1998 03:44:49 GC EI+ Voltage SIR Autospec-Ultima
Sample#17 Text:300681-3 :T-MM5-2-F :Trai Exp:PAHAIR
268.9824 S:17 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
90-
80_
70-
60 J
50^
40 1
30 1
20 J
10 J
0
30:^
A4.72E6 /\//\AA/\/
tftiTrfNlU ml
[
i T i i i [ i i r~~i i — i — '
0 31:00 32:00
A
A
f
f
A
I\ff
y
1
M
33:00
A ^
y
'34:60
A1.63E7 7Y
/v. ft A A /
^r
/
w
u
VY
(Y
U
f
A4.3.6E7 _S.4E6
-~^. >^/"Xv
/r
T
/
Y\
VY
/v//v
YT
YYlY
lY
YT
YYYT
i
/'V*v*
/\/Yy/>
T — l — i — i — r— i — i — i — I — i — r— i — i — i — i — i — r— i — i — r — i — i — r— i — i — i — i — i — r—i — i — i — i — i — p- 1 — i — i — i — i — i T 'i — I — r-
35:60 36:60 37:00 38:00 39:00 40:00 41:00 '
Y "
4.8E6
.4.3E6
-3.8E6
_3.2E6
-2.7E6
L2.2E6
L1.6E6
L1.1E6
1.5.4E5
O.OEO
12:00 Time
280.9824 S:17 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
1003
90 1
90l
70 J
60-:
50 J
40,
30 J
20 J
10 J
0:
30:i
A A A A
0 31:60 32:00
r\
1
„ A
J V^
1
r
33:
A
/\ A A
Vfl
1
n
oo' ' '
tl\ A
| p
\
i
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\
;
/A
w
/-r-v/rVV
iff
"p.'
sT
/\
1
"Y-
YT^
/
iT^
rr/Y^n
or T
T
35:6o 36:6fl 37:6o 38:6o 39:6o 40:6o 41:00 4
>yrL8E7
L1.6E7
L1.4E7
L1.2E7
L1.1E7
-8.8E6
L7.0E6
-5.3E6
1.3.5E6
L1.8E6
O.OEO
2:00 Time
-------
02-SEP-1998 07:11:04 PM Dioxin Furan Unknown RESULTS
GC Column : DB-5
Data file : 24AU98U
Weight : 0.333
Name
dlO-2-Methylnaphthalene
d8-Naphthalene
Naphthalene
2-Methylnaphthalene
d8-Acenaphthylene
Ac enaphthy1ene
dlO-Acenaphthene
Acenaphthene
dlO-Anthracene
dlO-Fluorene
Fluorene
dlO-Phenanthrene
Phenanthrene
Anthracene
d!2-Benzo(e)pyrene
dlO-Fluoranthene
Fluoranthene
dlO-Pyrene
Pyrene
di2-Benzo(a)anthracene
Benzo(a)anthracene
d!2-Chrysene
Chrysene
dl2 -Benz o(e)pyrene
dl2-Benzo(b)fluoranthene .
Benzo(b)fluoranthene '
dl2-Benzo(k)fluoranthene/
Benzo(k)fluoranthene "
d!2-Benzo (a)pyrene;
Benzo(e)pyrenei
Benz o(a)pyrene'
d!2-Perylene
Perylene .
d!2-Indeno (123-cd) pyrene..
Indeno(123-cd)pyrene
d!4-Dibenz(ah)anthracene
Dibenz(ah)anthracene
d!2-Benzo(ghi)perylene
Benzo(ghi)perylene
d8-Naphthalene
13C-Naphthalene
Results : 24AU98U081.RES
Date analyzed
300681-4 :T-MM5-FB-F :Tra Ex Cal
Total Isotope R. T. RRF
Response Ratio mmrss
104767800 1.00 Y
70141200 1.00 Y
140673800 1.00 Y
102381200 1.00 Y
126385800 1.00 Y
4460000 1.00 Y
11: 10 Y
8: 57 Y
9: 1 Y
11: 15 Y
14:
14:
13 Y
17 Y
77644800 1.00 Y 14: 47 Y
29066000 1.00 Y 14: 53 Y
80746800 1.00 Y
54876400 1.00 Y
60400000 1.00 Y
19: 48 Y
16: 29 Y
16: 35 Y
164315400 1.00 Y 19: 38 Y
294000000 1.00 Y 19: 42 Y
10300000 1.00 Y 19: 51 Y
142613400 1.00 Y .32: 39 Y
120354200 1.00 Y 23: 32 Y
35000000 1.00 Y 23: 36 Y
120510200 1.00 Y 24: 14 Y
36000000 1.00 Y 24: 18 Y
145946000 1.00 Y 28: 6 Y
3840000 1.00 Y 28: 11 Y
175288800 1.00 Y 28: 13 Y
24800000 1*00 .Y .28:
* 142613400 1.00 Y 32:
93249400 1.00 Y 31:
2960000 1.00 Y 31.:
133T660QO 1.00 Y 31:
2340000 1.00 Y 31:
90750000 1.00 Y 32:
4420000 1.00 Y 32:
1370000 1.00 Y 32:
69289800 1.00 Y 33:
2820000 1.00 Y 33:
107388200 1.00 Y 38:
1848000 1.00 Y 38:
69200000 1.00 Y 38:
1496000 1.00 Y 38:
96800000 1.00 Y 39:
3560000 1.00 Y 39:
70141200 1.00 Y 8:
* No Peak 0.00 N 9:
:,Y
39 Y
45 Y.
4S T
51 Y
52 Y
45 -Y2
58 Y
11 Y-
17 Y
"T ^^"'
4 Y
2 Y
13 Y
20 Y
29 Y
57 Y
1 N
PAS3C.TRG
24-AUG-98
PAHX081998U.RRF
ng/ Rec/
SAMPLE MDL
1.00.
1.25
1.05
0.77
1.55
0.86
0.88
0.93
1.00
1.13 "
1.05
2.63
0.84
0.83
; i.oo
0.80
1.04
0.81
1.11
0.65
1.06
.1 QL85
•.*-i,0:S7
* M.OO
0.63
1.07
^.-*"or90
1.16
:'. .". 0..75
' *.1.46
1.02
... 0.61
1.62
s'.j't-OlTl
0.61.
0.44
1.11
0 . 63.
0.99
1.00
0.98
50.00
26.87 54
285.91 S
'284.35 B
38.91 78
6.14=DL
42.23 84
60.45 £>
50.00
30.09 60
157.40 ^
38.70 77
319.02 *B
11.35=DL
50.00 . ... •
52.53 105C
41.97 "g,
52.18 104
40.50
78.69 157 '
3.74=DL
72.45 145
21,87 ». M
' 50. 00-- ' '•'
52.22 " 104
4.46=DL
52,34 105
2.27=DL
42.36 85
4 . 99=DL
2.21=DL
, 39153 < 79.-' •
53.28 107
4.23=DL
55.00 110
2.92=DL
53.84/10a/
^-^fn/ f ' ^ C* o
50.00 T' 152
0.00 0
-------
02-SEP-1998 07:11:04 PM Dioxin Furan Unknown RESULTS
dlO-Fluorene 54876400 1.00 Y 16: 29 Y 1.00 50.00
13C-Fluorene 42566400 1.00 Y 16: 34 Y 0.76 51.17 102
153
-------
02-SEP-1998 07:11:00 PM Dioxin Furan Unknown RESULTS
24AU98U081.RES
Date analyzed
MM5-FB-F :Tra Ex Cal
Isotope R. T. RRF
Ratio inm.-ss
PAHX.TRG
24-AUG-98
PAHX081998U.RRF
ng/ Rec/
SAMPLE MDL
0.333
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
0.00
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
N
11:
8:
9:
11:
14:
14:
14:
14:
19:
16:
16:
19:
19:
19:
32:
23:
23:
24:
24:
28:
28:
28:
28:
32:
31:
31:
31:
31:
32:
32:
32:
33:
33:
38:
38:
38:
38:
39:
39:
8:
9:
10
57
1
15
13
17
47
53
48
29
35
38
42
51
39
32
36
14
18
6
11
13
17
39
39
45
45
51
52
45
58
11
17
1
4
2
13
20
29
57
1
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
N
1
1
1
0
1
0
0
0
1
1
1
2
0
0
1
0
1
0
1
0
1
0
0
1
0
1
0
1
0
1
1
0
1
0
0
0
1
0
0
1
0
.00
.25
.05
.77
.55
.86
.88
.93
.00
.13
.05
.63
.84
.83
.00
.80
.04
.81
.11
.65
.06
.85
.97
.00
.63
.07
.90
.16
.75
.46
.02
.61
.62
.71
.61
.44
.11
.63
.99
.00
.98
50
26
285
284
38
6
42
60
50
30
157
38
319
11
50
52
41
52
40
78
3
72
21
50
52
4
52
2
42
4
2
39
3
53
4
55
2
53
5
50
0
.00
.87
.91
.35
.91
54
78
.14=DL
.23
.45
.00
.09
.40
.70
.02
.35=DL
.00
.53
.97
.18
.50
.69
.74=DL
.45
.87
.00
.22
.46=DL
.34
.27=DL
.36
.99=DL
.21=DL
.53
. 78=DL
.28
.23=DL
.00
. 92=DL
.84
.57=DL
.00
.00
84
60
77
105
104
157
145
104
105
85
79
107
110
108
0
52383900
35070600
70336900
51190600
63192900
2230000
38822400
14533000
40373400
27438200
30200000
82157700
147000000
5150000
71306700
60177100
17500000
60255100
18000000
72973000
1920000
87644400
12400000
71306700
46624700
1480000
66883000
1170000
45375000
2210000
685000
34644900
1410000
53694100
924000
34600000
748000
48400000
1780000
35070600
0
52383900
35070600
70336900
51190600
63192900
2230000
38822400
14533000
40373400
27438200
30200000
82157700
147000000
5150000
71306700
60177100
17500000
60255100
18000000
72973000
1920000
87644400
12400000
71306700
46624700
1480000
66883000
1170000
45375000
2210000
685000
34644900
1410000
53694100
924000
34600000
748000
48400000
1780000
35070600
0
154
-------
02-SEP-1998 07:11:00 PM Dioxin Furan Unknown RESULTS
1.00 Y 16: 29 Y 1.00 50.00 27438200 27438200
1.00 Y 16: 34 Y 0.76 51.17 102 21283200 21283200
155
-------
25-AUG-1998 09:28:32 AM
PAH Unknown RESULTS
Mass Spec : ULTIMA
GC Column : DB-5
Data file -. 24AU98U
Weight : 0.333
Name
dlO-2-Methylnaphthalene
d8-Naphthalene
Naphthalene
2-Methylnaphthalene
d8-Acenaphthylene
Acenaphthylene
dlO-Acenaphthene
Acenaphthene
dlO-Anthracene
dlO-Fluorene
Fluorene
dl0-Phenanthrene
Phenanthrene
Anthracene
d!2-Benzo(e)pyrene
dl0-Fluoranthene
Fluoranthene
dlO-Pyrene
Pyrene
d!2-Benzo(a)anthracene
Benzo(a)anthracene
d!2-Chrysene
Chrysene
d!2-Benzo(e)pyrene
d!2-Benzo(b)fluoranthene
Benzo(b)fluoranthene
d!2-Benzo(k)fluoranthene
Benzo(k)fluoranthene
dl2-Benzo(a)pyrene
Benzo(e)pyrene
Benzo(a)pyrene
d!2-Perylene
Perylene
d!2-Indeno(123 -cd)pyrene
Indeno(12 3 -cd)pyrene
d!4-Dibenz(ah)anthracene
Dibenz(ah)anthracene
d!2-Benzo(ghi)perylene
Benzo(ghi)perylene
d8-Naphthalene
13C-Naphthalene
Results : 24AU98U081.RES
Date analyzed
300681-4 :T-MM5-FB-F :Tra Ex Cal
Total Isotope R. T.' RRF
Response Ratio mm:ss
PAHX.TRG
24-AUG-98
PAHX081998U.RRF
ng/ Rec/
SAMPLE MDL
104767800
70141200
140673800
102381200
126385800
7182220
77644800
29066000
80746800
54876400
64376000
164315400
308956000
* No Peak
142613400
120354200
42686600
120510200
40310800
145946000
4884160
175288800
25155800
142613400
93249400
5083260
133766000
5083260
90750000
4472620
1319906
69289800
2398900
107388200
* No Peak
66604400
1052704
* No Peak
* No Peak
70141200
* No Peak
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
0.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
0.00
1.00
1.00
0.00
0.00
1.00
0.00
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
N
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
N
Y
Y
N
N
Y
N
11:
8:
9:
11:
14:
14:
14:
14:
19:
16:
16:
19:
19:
19:
32:
23:
23:
24:
24:
28:
28:
28:
28:
32:
31:
31:
31:
31:
32:
32:
32:
33:
33:
38:
38:
38:
38:
39:
39:
8:
9:
10
57
1
15
13
17
47
53
48
29
35
38
42
51
39
32
36
14
18
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11
13
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39
39
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-------
25-AUG-1998 09:28:32 AM PAH Unknown RESULTS
dlO-Fluorene 54876400 1.00 Y 16: 29 Y 1.00 50.00
13C-Fluorene 42566400 1.00 Y 16: 34 Y 0.76 51.17 102
157
-------
File:24AU98U #1-476 Acq:24-AUG-1998 23:01:10 GC EI+ Voltage SIR Autospec-Ultima
Sample#8 Text:300681-4 :T-MM5-FB-F :Tra Exp:PAHAIR
128.0626 S:8 SMO(1,3) PKD(5,3,3>0.10%,10000.0,0.00%,F,T)
134.0827 S:8 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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80
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136.1128 S:8 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
152.1410 S:8 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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-------
File:24AU98U 11-476 Acq:24-AUG-1998 23:01:10 GC EI+ Voltage SIR Aulospec-Ultima
Sampled Text:300681-4 :T-MM5-FB-F :Tra Exp:PAHAlR
152.0626 S:8 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
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13:00 13:12 13:24 13:36 13:48 14:00 14:12 14:24 14:36 14:48 15:00 15:12 15:24 15:36
160.1128 S:8 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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13:60 13:12 13:24 13:36 13:48 14:00 14:12 14:24 14:36 14:48 15:00 15:12 15:24 15:36
154.0782 S:8 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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164.1410 S:8 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0
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13:00 13:12 13:24 13:36 13:48 14:66 14:i2 14:24 14:36 14:48 15:6o 15:12 15:24 15:36
-------
o
File:24AU98U #1-476 Acq:24-AUG-1998 23:01:10 GC EI+ Voltage SIR Autospec
Sampled Text:300681-4 :T-MM5-FB-F :Tra Exp:PAHAIR
152.0626 S:8 SMO(1,3) PKD(5,3,3,0.10%,5000.0,0.00%,F,T)
100%
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701
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Time
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13:54 14:00 14:06
160.1128 S:8 SMO(1,3) PKD(5,3,3,0.10%,5000.0,0.00%,F,T)
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Time
-------
File:24AU98U #1-476 Acq:24-AUG-1998 23:01:10 GC E1+ Voltage SIR Autospec-Ultima
Samplers Text:300681-4 :T-MM5-FB-F :Tra Exp:PAHAIR
130.9
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Time
-------
File:24AU98U #1-665 Acq:24-AUG-1998 23:01:10 GC EI+ Voltage SIR Autospec-Ultima
Sample#8 Text:300681-4 :T-MM5-FB-F :Tra Exp:PAHAlR
166.0798 S:8 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 % A3.22E7
15:48 16:66 16:i2 16:24 16:36 16:48
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-------
FiIe:24AU98U #1-665 Acq:24-AUG-1998 23:01:10 GC EI+ Voltage SIR Autospec-Ultima
Sample#8 Text:300681-4 :T-MM5-FB-F :Tra Exp:PAHAIR
166.0798 S:8 F:2 SMO(1,3) PKD(5,3,3,0.10%,5000.0,0.00%,F,T)
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File:24AU98U #1-665 Acq:24-AUG-1998 23:01:10 GC EI+ Voltage SIR Autospec-Ultima
Sample#8 Text:300681-4 :T-MM5-FB-F :Tra Exp:PAHAIR
178.0782 S:8 F:2 SMO(1,3) PKD(5,3,3,0.10%,5000.0,0.00%,F,T)
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0 Time
-------
File:24AU98U #1-665 Acq:24-AUG-1998 23:01:10 GC EI+ Voltage SIR Autospec-UItima
Sample#8 Text:300681-4 :T-MM5-FB-F :Tra Exp:PAHAIR
178.0782 S:8 F:2 SMO(1,3) PKD(5,3,3,0.10%,5000.0,0.00%,F,T)
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-------
F«e:24AU98U #1-665 Acq:24-AUG-1998 23:01:10 GC EI+ Voltage SIR Autaspec-UWima
Sample#8 Text:300681-4 :T-MM5-FB-F :Tra Exp:PAHAIR
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-------
File:24AU98U #1-935 Acq:24-AUG-1998 23:01:10 GC EI+ Voltage SIR Autospec-UItima
Sampled Text:300681-4 :T-MM5-FB-F :Tra Exp:PAHAIR
202.0782 S:8 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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212.1410 S:8 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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-------
File:24AU98U #1-935 Acq:24-AUG-1998 23:01:10 GC EI+ Voltage SIR Autospec-Ultima
Sampled Text:300681-4 :T-MM5-FB-F :Tra Exp:PAHAIR
202.0782 S:8 F:3 SMO(1,3) PKD(5,3,3,0.10%,5000.0,0.00%,F,T)
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O.OEO
Time
' ' 23:24 ' ' 23\30 ' ' 23:36 ^^3:42 ' ' 23:48' ' ' 23:54 ' ' 24:6o ' ' 24:66 ' ' Mill' ' ' 24:i8 ' ' '24^4 ' ' 24:30 ' ' 24:36
-------
-------
o
File:24AU98U #1-935 Acq:24-AUG-1998 23:01:10 GC EI+ Voltage SIR Autospec-Ultima
Sample#8 Text:300681-4 :T-MM5-FB-F :Tra Exp:PAHAIR
228.0939 S:8 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 % Al.
90
80
70_
60-:
50
40-
30-
20 J
101
0-
A2.62E6
A1.01E6
-O.ES
AU.E5
2.8E6
L2.5E6
L2.3E6
L2.0E6
L1.7E6
L1.4E6
L1.1E6
8.4E5
-5.6E5
L2.8E5
O.OEO
)0 Time
2.5E7
L2.3E7
L2.0E7
L1.8E7
Ll.5E7
L1.3E7
L1.0E7
7.6E6
15.1E6
L2.5E6
26:36 26:48 27:6o 27:12 27:24 27^36 27:48 28:66 28:ii 28:24 28:36 28:48 29:66 29:12 29:24 29:36 29:48
240.1692 S:8 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 % A8.76E7
90
80 j
70
60-
50 j
30 A
20
30:
0
~i r~[ i i—l l i—l i i—I i l ] i—i—i i—i—l—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—r—i—i—i—i—i—i—i—i—i—1—i—i—i—l—i—I—i—i—i—i—r~i—I—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—I—i—i—I—i—i—i—i—i—i—i—i—
26:36 26:48 27:6o 27:12 27:24 27:36 27:48 28:6fl 28:12 28:24 28:36 28:48 29:6o 29:12 29:24 29:36 29:48 30;i
O.OEO
0 Time
-------
File:24AU98U #1-935 Acq:24-AUG-1998 23:01:10 GC EI+ Voltage SIR Autospec-Ultima
Sample#8 Text:300681-4 :T-MM5-FB-F :Tra Exp:PAHAlR
228.0939 S:8 F:3 SMO(1,3) PKD(5,3,3,0.10%,5000.0,0.00%,F,T)
100 % A1.34E7
90
80 J
70
60
SO.;
40-
30 J
20
10
0.
A9.87E5
A7.15E5
:30 28:36 28:42
2.8E6
-2.5E6
-2.3E6
12.0E6
11.7E6
1.4E6
L1.1E6
L8.4E5
L5.6E5
L2.8E5
lO.OEO
28:48 Time
2.5E7
-2.3E7
L2.0E7
L1.8E7
L1.5E7
11.3E7
-1.0E7
L7.6E6
L5.1E6
i.2.5E6
27:48 27:54
240.1692 S:8 F:3 SMO(1,3)
100%
90 J
80 J
101
601
50.
40_
30_
20-
28:00 ' 28:66 28:i2 28:i8
28:24'
28:
28:42
lO.OEO
28:48 Time
27:48' ' ' 27:54 28:6o ' 28:66 ' 28:12
28:1
28:24
28:3
28:3
-------
f- p~
rrr;?:r:«^'~f~f^^
!-£
(M
P
6-7
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OB ** O
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sis
ill
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ve
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^
-------
U> i— M
o o o o
I I I I . . I
-------
File:24AU98U #1-954 Acq:24-AUG-1998 23:01:10 GC EI+ Voltage SIR Autospec-Ultima
Sampled Text:300681-4 :T-MM5-FB-F :Tra Exp:PAHAIR
252.0939 S:8 F:4 SMO(1,3) PKD(5,3,3,0.10%,5000.0,0.00%,F,T)
100% A1.4&E6
90-
80
70
60 4
50
40
30 -
201
10-
OJ
A1.98E5
31:24'
264.1692 S:8F:4
100%
90
80 4
70
60
50-
40-
30-
20-
10
—i r—I 1—1 1 1 r—i 1 1 1 1 1 r
31:30 31:36 31:42
31:39
]—i—i—i—r—i—r—r-
31:54
-i 1 1 r—r-
32:00
32:06
2:i2
3.8E5
L2.9E5
L2.5E5
2.1E5
1.7E5
-1.3E5
-8.4E4
U.2E4
.O.OEO
Time
1.3E7
11.2E7
L1.1E7
L9.4E6
-8.0E6
6.7E6
5.4E6
_4.0E6
-2.7E6
L1.3E6
O.OEO
Time
31:48
32
0
31:45
31:^4
31:30
32:
31:36
31:42
31:48
31:*
1 r—i
32:66
~32:k2'
32:
-------
4:3
File:24AU98U #1-954 Acq:24-AUG-1998 23:01:10 GC EI+ Voltage SIR Autospec-Ultima
Sample#8 Text:300681-4 :T-MM5-FB-F :Tra Exp:PAHAIR
252.0939 S:8 F:4 SMO(1,3) PKD(5,3,3,0.10%,5000.0,0.00%,F,T)
100 % A2.21E6
90 J
80 j
70 '-
60 j
50 j
40J
30 J
201
10
0
A1.41E6
1 ' I I L ' ' ' ' ' I I ' ' ' ' ' I L I i i i i i I i i i i i I ii i i i i ii i i i i ii i i i i ii
32:18 32:24 32:30 32:36 32:42 32:48 32:54 33:00 33:06 33:12 33:18 33:24 33:30 33:36
264.1692 S:8 F:4 SMO(1,3) PKD(5,3,3,0.10%,5000.0,0.00%,F,T)
100 % A7.13E7
90
80 J
70
60
50
40
30
20 J
10
r-SAES
4.8E5
4.3E5
3.8E5
3.2E5
.2.7E5
L2.2E5
1.6E5
1.1E5
5.4E4
i < i i i i ' ' i i
33:42 33:48
.O.OEO
Time
.1.6E7
L1.5E7
1.1.3E7
A.IE7
9.8E6
-8.2E6
6.6E6
-4.9E6
L3.3E6
L1.6E6
A3.46E7
O.OEO
Time
32:18 ' 32:24 32:30 32:36 ' 32:42 32:48 32:54 ' 33:66 ' 33:66 ' 33:ii ' ' 33:i8 ' ' 33:24 ' 33:30 ' 33^6
i i i i i
33:42 33:48
-------
F11e:24AU98U #1-954 Acq:24-AUG-I998 23:01:10 GC EI+ Voltage SIR Autospec-Uttiraa
Sampled Text:300681-4 :T-MM5-FB-F :Tra ExprPAHAIR
276.0939 S:8 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 ft A1.53E6
80 J
60 J
40
20 J
A9.69E5
—j 1 j 1 1 1 | 1 1 1 1 1 1 1
36:00 37:60 38:6o
288.1692 S:8 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
41:6o
2.0E5
1.6E5
-1.2E5
L7.9E4
13.9E4
O.OEO
)0 Time
39:6o
40:6o
36:00 37:60 ' 38:00
292.1974 S:8 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
UU 1
sol
60.:
40_
20:
0
36:
> AJ.JJC,/
A
\
» 37:6o 38:6o
42:1
)0 Time
278.1096 S:8 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
A5.26E5
)0 Time
40:00 41:00 42:i
3.3E6
2.6E6
:2.0E6
:1.3E6
:6.6E5
O.OEO
)0 Time
-------
File:24AU98U #1-954 Acq:24-AUG-1998 23:01:10 GC EI+ Voltage SIR Autospec-Ultima
Sample#8 Text:300681-4 :T-MM5-FB-F :Tra Exp:PAHAIR
276.0939 S:8 F:4 SMO(1,3) PKD(S,3,3,0.10%,5000.0,0.00%,F,T)
100%
90 J
80 j
70-
60 j
50 J
40
30-
20 J
10 J
A9.24E5
2.0E5
Ll.SES
1.6E5
L1.4E5
L1.2E5
L9.9E4
L7.9E4
5.9E4
L3.9E4
12.0E4
O.OEO
Time
n 38:0039:00
288.1692 S:8 F:4 SMO(1,3) PKD(5,3,3,0.10%,5000.0,0.00%,F,T)
40:0
100%
90
80 J
70
60 -
50-
40
30-
20 J
10
0
47E7
A4.84E7
5.4E6
4.9E6
14.3E6
13.8E6
3.2E6
t2.7E6
2.2E6
1.6E6
t-l.lE6
5.4E5
C.O.OEO
38:t
,, .. ,, .,
•1 .... |
39:*
40:00
Time
-------
File:24AU98U #1-954 Acq:24-AUG-1998 23:01:10 GC EI+ Voltage SIR Autospec-Ultima
Sampled Text:300681-4 :T-MM5-FB-F :Tra Exp:PAHAIR
278.1096 S:8 F:4 SMO(1,3) PKD(5,3,3,0.10%,5000.0,0.00%,F,T)
100 % A7.48E5
90
80 J
70.;
60-:
50 J
40J
30 j
20
10
Od
38:00
»-*
8.4E4
L7.6E4
L6.8E4
L5.9E4
15.1E4
L4.2E4
L3.4E4
L2.5E4
L1.7E4
L8.4E3
O.OEO
Time
3.3E6
-2.9E6
L2.6E6
L2.3E6
L2.0E6
L1.6E6
1.3E6
19.8E5
:6.6E5
L3.3E5
O.OEO
Time
39:60
40:
292.1974 S:8 F:4 SMO(1,3) PKD(5,3,3,0.10%,5000.0,0.00%,F,T)
A3.46E7
38:00
39
-------
File:24AU98U #1-954 Acq:24-AUG-1998 23:01:10 GC EI+ Voltage SIR Autospec-Ultima
Sample#8 Text:300681-4 :T-MM5-FB-F :Tra Exp:PAHAIR
268.9824 S:8 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 S
90-
80-
70-
60-
50 J
40 J
30 j
20 J
10 J
rrrrm
A2.41E7
A2.55E7
:6o' ' '41:00 ' '42:
_2.4E7
-2.2E7
-1.9E7
.1.7E7
-1.4E7
-1.2E7
19.6E6
L7.2E6
4.8E6
L2.4E6
O.OEO
)0 Time
'-\—r—i—i—i—i—1—i—i—i—i—i—r—i—i—i—i—i—r—i—i—i—i—i—[—i—i—i—i—i—["""
30:00 31:00 32:00 33:60 34:60 35:00
280.9824 S:8 F:4 SMO(1,3) PKD(S,3,3,0.10%,10000.0,0.00%,F,T)
30:
36:60 '37:6o' 38:6o 39:6o
A9.82E7 A7,82E7
40
^00 '31:60' 32:60 33:6o 34:6o 35:6o 36:6o '37:00 38:6fl 39:1)0
O.OEO
)0 Time
-------
02-SEP-1998 07:16:49 PM Dioxin Furan Unknown RESULTS
GC Column : DB-5
Data file : 24AU98U
Weight : 0.333
Name
dlO- 2-Methylnaphthalene
d8-Naphthalene
Naphthalene
2-Methylnaphthalene
d8-Acenaphthylene
Acenaphthylene
dlO-Acenaphthene
Acenaphthene
dlO-Anthracene
dlO-Fluorene
Fluorene
dlO-Phenanthrene
Phenanthrene
Anthracene
d!2-Benzo(e)pyrene
dlO-Fluoranthene
Fluoranthene
dlO-Pyrene
Pyrene
d!2-Benzo(a)anthracene
Benzo(a)anthracene
d!2-Chrysene
Chrysene
dl2-Benzo(e)pyrene
d!2-Benzo(b)fluoranthene
Benzo(b)fluoranthene
d!2-Benzo(k)fluoranthene
Benzo(k)fluoranthene
d!2-Benzo(a)pyrene
Benzo(e)pyrene
Benzo(a)pyrene
d!2-Perylene
Perylene
d!2-Indeno(12 3 -cd)pyrene
Indeno(123-cd)pyrene
d!4-Dibenz(ah)anthracene
Dibenz(ah)anthracene
d!2-Benzo(ghi)perylene
Benzo(ghi)perylene
d8-Naphthalene
13C-Naphthalene
Results : 24AU98U091.RES
Date analyzed
300681-5 :T-MM5-4-F :Trai Ex Cal
Total Isotope R. T. RRF
Response Ratio
99343800 1.00 Y
55920200 1.00 Y
1115000000 1.00 Y
1454668000 1.00 Y
68118600 1.00 Y
64000000 1.00 Y
37745000 1.00 Y
249634000 1.00 Y
73659200 1.00 Y
26158200 1.00 Y
594000000 1.00 Y
71184000 1.00 Y
3224660000 1.00 Y
167600000 1.00 Y
156000600 1.00 Y
62400000 1.00 Y
264000000 1.00 Y
62200000 1.00 Y
566000000 1.00 Y
74666000 1.00 Y
15780000 1.00 Y
85421400 1.00 Y
342000000 1.00 Y
156000600 1.00 Y
52330400 1.00 Y
13460000 1.00 Y
65366400 1.00 Y
4860000 1.00 Y
52342800 1.00 Y
13380000 1.00 Y
1384000 1.00 Y
39740800 1.00 Y
2880000 1.00 Y
50000000 1.00 Y
1340000 1.00 Y
29212000 1.00 Y
566000 1.00 Y
45800000 1.00 Y
4660000 1.00 Y
55920200 1.00 Y
* No Peak 0.00 N
PAHX. TRG
24-AUG-98
PAHX081998U.RRF
ng/ Rec/
UUU
11
8
9
11
14
14
14
14
19
16
16
19
19
19
32
23
23
24
24
28
28
28
28
32
31
31
31
31
32
32
32
33
33
37
38
38
38
39
39
8
9
st>
9
57
1
15
13
16
46
53
47
29
34
38
42
50
39
33
35
16
18
6
16
13
16
39
40
45
45
45
51
45
57
10
16
57
4
3
13
20
29
57
1
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
N
1
1
1
0
1
0
0
0
1
1
1
2
0
0
1
0
1
0
1
0
1
0
0
1
0
1
0
1
0
1
1
0
1
0
0
0
1
0
0
1
0
.00
.25
.05
.77
.55
.86
.88
.93
.00
.13
.05
.63
.84
.83
.00
.80
.04
.81
.11
.65
.06
.85
.97
.00
.63
.07
.90
.16
.75
.46
.02
.61
.62
.71
.61
.44
.11
.63
.99
.00
.98
a>uvjf
50
22
2842
5067
22
163
21
1068
50
15
3247
18
8077
426
50
24
610
24
1233
3CJ
30
32
618
50
26
36
23
9
22
26
3
20
6
22
6
21
2
23
15
50
0
jjn in
.00
.59
.50 e
.60 £
.12
.40
.65
•01 ^\
.00
.72
.36 &
.38
.06 £ '
.41
.00
.90
.55 ^
.62
•80 &-
.80
.07
.28
.92
.00
.79
.12
.38
.66=DL
.33
.21
.88=DL
.73
.72=DL
.68
.58=DL
.22
. 61|=Bl#
J. 0 L
.29
.42
.00
.00
LJLi
45
'P?
3
44
43
^>
31
^
37
£>
50
*>
49
74
65
54
47
45
41
45
42
)
i
47
0
-------
02-SEP-1998 07:16:49 PM Dioxin Furan Unknown RESULTS
dlO-Fluorene 26158200 1.00 Y 16: 29 Y 1.00 50 00
13C-Fluorene 41184800 1.00 Y 16: 34 Y 0.76 103.86 208
181
-------
02-SEP-1998 07:16:46 PM Dioxin Furan Unknown RESULTS
24AU98U091.RES
Date analyzed
MM5-4-F :Trai Ex Cal
Isotope R. T. RRF
Ratio nun:ss
PAHX. TRG
24-AUG-98
PAHX081998U.RRF
ng/ Rec/
SAMPLE MDL
0.333
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1. 00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
0.00
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
N
11:
8:
9:
11:
14:
14:
14:
14:
19:
16:
16:
19:
19:
19:
32:
23:
23:
24:
24:
28:
28:
28:
28:
32:
31:
31:
31:
31:
32:
32:
32:
33:
33 :
37:
38:
38:
38:
39:
39:
8:
9:
9
57
I
15
13
16
46
53
47
29
34
38
42
50
39
33
35
16
18
6
16
13
16
39
40
45
45
45
51
45
57
10
16
57
4
3
13
20
29
57
1
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
N
1
1
1
0
1
0
0
0
1
1
1
2
0
0
1
0
1
0
1
0
1
0
0
1
0
1
0
1
0
1
1
0
1
0
0
0
1
0
0
1
0
.00
.25
.05
.77
.55
.86
.88
.93
.00
.13
.05
.63
.84
.83
.00
.80
.04
.81
.11
.65
.06
.85
.97
.00
.63
.07
.90
.16
.75
.46
.02
.61
.62
.71
.61
.44
.11
.63
.99
.00
.98
50
22
2842
5067
22
163
21
1068
50
15
3247
18
8077
426
50
24
610
24
1233
36
30
32
618
50
26
36
23
9
22
26
3
20
6
22
6
21
2
23
15
50
0
.00
.59
.50
.60
.12
.40
.65
.01
.00
.72
.36
.38
.06
.41
.00
.90
.55
.62
.80
.80
.07
.28
.92
.00
.79
.12
.38
.66=DL
.33
.21
.88=DL
.73
.72=DL
.68
.58=DL
.22
.61=DL
.29
.42
.00
.00
45
44
43
31
37
50
49
74
65
54
47
45
41
45
42
47
0
49671900
27960100
557500000
727334000
34059300
32000000
18872500
124817000
36829600
13079100
297000000
35592000
1612330000
83800000
78000300
31200000
132000000
31100000
283000000
37333000
7890000
42710700
171000000
78000300
26165200
6730000
32683200
2430000
26171400
6690000
692000
19870400
1440000
25000000
670000
14606000
283000
22900000
2330000
27960100
0
49671900
27960100
557500000
727334000
34059300
32000000
18872500
124817000
36829600
13079100
297000000
35592000
1612330000
83800000
78000300
31200000
132000000
31100000
283000000
37333000
7890000
42710700
171000000
78000300
26165200
6730000
32683200
2430000
26171400
6690000
692000
19870400
1440000
25000000
670000
14606000
283000
22900000
2330000
27960100
0
182
-------
02-SEP-1998 07:16:46 PM Dioxin Furan Unknown RESULTS
1.00 Y 16: 29 Y 1.00 50.00 13079100 13079100
1.00 Y 16: 34 Y 0.76 103.86 208 20592400 20592400
183
-------
25-AUG-1998 09:29:47 AM
PAH Unknown RESULTS
Mass Spec : ULTIMA
GC Column .- DB-5
Data file : 24AU98U
Weight .- 0.333
Name
dlO-2-Methylnaphthalene
d8-Naphthalene
Naphthalene
2-Methylnaphthalene
d8-Acenaphthylene
Acenaphthylene
dl0-Acenaphthene
Acenaphthene
dlO-Anthracene
dlO-Fluorene
Fluorene
dl0 -Phenanthrene
Phenanthrene
Anthracene
d!2-Benzo(e)pyrene
dlO-Fluoranthene
Fluoranthene
dlO-Pyrene
Pyrene
d!2-Benzo(a)anthracene
Benzo(a)anthracene
d!2-Chrysene
Chrysene
d!2-Benzo(e)pyrene
d!2-Benzo(b)fluoranthene
Benzo(b)fluoranthene
d!2-Benzo(k)fluoranthene
Benzo(k)fluoranthene
d!2-Benzo(a)pyrene
Benzo(e)pyrene
Benzo(a)pyrene
d!2-Perylene
Perylene
d!2-Indeno(123 -cd)pyrene
Indeno(123-cd)pyrene
d!4-Dibenz(ah)anthracene
Dibenz(ah)anthracene
d!2-Benzo(ghi)perylene
Benzo(ghi)perylene
d8-Naphthalene
13C-Naphthalene
Results : 24AU98U091.RES
Date analyzed
300681-5 :T-MM5-4-F :Trai Ex Cal
Total Isotope R. T. RRF
Response Ratio mm:ss
99343800 1.00 Y
55920200 1.00 Y
1115000000 1.00 Y
1454668000 1.00 Y
68118600 1.00 Y
114581800 1.00 Y
37745000 1.00 Y
249634000 1.00 Y
73659200 1.00 Y
26158200 1.00 Y
646362000 1.00 Y
* No Peak
* No Peak
29212000 1.00 Y
380264 1.00 Y
* No Peak
* No Peak
0.00 N
0 .00 N
11: 9 Y
8: 57 Y
9: 1 Y
11: 15 Y
14: 13 Y
14: 16 Y
14: 46 Y
14: 53 Y
19: 47 Y
16: 29 Y
16: 34 Y
71184000 1.00 Y 19:
3224660000 1.00 Y 19;
* No Peak 0.00 N 19:
156000600 1.00 Y 32:
* No Peak 0.00 N 23:
292896000 1.00 Y 23:
* No Peak 0.00 N 24:
622024000 1.00 Y 24:
74666000 1.00 Y 28
368396000 1.00 Y 28:
85421400 1.00 Y 28
368396000 1.00 Y 28
156000600 1.00 Y 32
52330400 1.00 Y 31
18821300 1.00 Y 31
65366400 1.00 Y 31
18821300 1.00 Y 31
52342800 1.00 Y 32
15255920 1.00 Y 32
2425520 1.00 Y 32
39740800 1.00 Y 33
4054260 1.00 Y 33
0.00 N 37
0.00 N 38
55920200 1.00 Y
* No Peak 0.00 N
38
38
39
39
8
9
38 Y
42 Y
50 N
39 Y
33 N
35 Y
16 N
18 Y
6 Y
16 Y
13 Y
16 Y
39 Y
40 Y
45 Y
45 Y
45 Y
51 Y
45 Y
57 Y
10 Y
16 Y
57 N
4 N
3
13
Y
Y
20 N
29 N
57 Y
1 N
: PAHX.TRG
: 24-AUG-98
: PAHX081998U.RRF
ng/ Rec/
SAMPLE MDL
1.00 50.00
1.25 22.59 45
1.05 2842.50 0.000
0.77 5067.60 0.000
1.55 22.12 44
0.86 292.54 0.000
0.88 21.65 43
0.93 1068.01 0.000
1.00 50.00
1.13 15.72 31
1.05 3533.62 0.000
2.63 18.38 37
0.84 8077.06 0.000
0.83 0.00 0.000
1.00
0.80
1.04
0.81
1.11
0.65
1.06
0.85
0.97
1.00
0.63
1.07
0.90
1.16
0.75
1.46
1.02
0.61
1.62
0.71
0.61
0.44
1.11
0.63
0.99
1.00
0.98
50.00
0.00 0
*NoINoIs
0.00 0
*NoINoIs
36.80 74
702.03 0.000
32.28 65
666.69 0.000
50.00
26.79 54
50.51 0.000
23.38 47
37.41 0.000
22.33 45
29.89 0.000
6.80 0.000
20.73 41
9.47 0.000
0.00 0
*NoINoIS
21.22 42
1.76 0.000
50.00
0.00
0
-------
25-AUG-1998 09:29:47 AM PAH Unknown RESULTS
dlO-Fluorene 26158200 1.00 Y 16: 29 Y 1.00 50.00
13C-Fluorene 41184800 1.00 Y 16: 34 Y 0.76 103.86 208
185
-------
DO
File:24AU98U #1-476 Acq:24-AUG-1998 23:47:39 GC EI+ Voltage SIR Autospec-UItima
Sampled Text:300681-5 :T-MM5-4-F :Trai Exp:PAHAIR
128.0626 S:9 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
UU3
80 J
60 J
40J
20
0 :
p A5.i>8
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9:00
C.8
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10:00 11:00 12:00 13:
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L1.4E8
-1.0E8
-6.9E7
L3.5E7
- O.OEO
)0 Time
134.0827 S:9 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
1002
80 J
60 J
40 J
20 -
o-
p A1.65E5
A
A4.67E4
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9:dfl 10:6fl ll:bo
136.1128 S:9 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 % A2.8pE7
80 j
60-
40-
20 \
0
A3.05E6 I
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9:dfl 10:6o 11:00
rS.7E4
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12:60 13:
-4.5E4
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10 Time
r8.6E6
12:00 13:
L6.9E6
L5.2E6
L3.4E6
L1.7E6
O.OEO
JO Time
142.0782 S:9 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 % A7. k7E8 r2.2E8
80 J
60 -i
40 J
20 J
0
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9:do 10:6o ll:6o
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12:00 13:i
1.8E8
L1.3E8
L8.9E7
" O.OEO
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152.1410 S:9 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100% A4.9X7E7 rl.SE7
80 J
60 J
40:
20 J
0
11
9:do 10:00 11:00
12:00 13:1
A.2E1
L9.1E6
L6.1E6
L3.0E6
: O.OEO
10 Time
-------
File:24AU98U #1-476 Acq:24-AUG-1998 23:47:39 GC EI+ Voltage SIR Autospec-Ultima
Sample#9 Text:300681-5 :T-MM5-4-F :Trai Exp:PAHAIR
152.0626 S:9 SMO(1,3) PKD(5,3,3,0.10%,10000.0)0.00%,F,T)
80:
40
20 J
A7.83E7
A1.12E8
A4.25E7
A5.73E7
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A8.32E7
2.6E7
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-1.0E7
-5.2E6
O.OEO
13:16 13:i2 13:24^^3^6 13:48 14:66 l^Ti 14:24 14:36 14:48 15:66 15:h 15:24 15:36
160.1128 S:9 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100!
80:
60
40
20
A3.41E7
A8.89E6
A
Time
.-9.6E6
7.7E6
L5.1E6
3.8E6
1.9
13:00 ^73:i2 ' 13:24 \3:tii ^^13:48 l^ST 14:i2 14&' lk^6 14:48 'llid 15:12 15:24 15:36
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154.0782 S:9 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
80:
60:
40:
20:
A4.73E7
A8.29E7
A1.43E7
A3.48E7
1.10E7
A2.41E7
A1.05E8
Time
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1.6E7
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14:00 14
164.1410 S:9 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
i i i i i i I1 i'*rl"i'T"i''-[—f
00 14:12 14:24
80
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14:36 14:48
A1.89E7
15:66 15:^2 15:24 15:36
Time
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O.OEO
Time
-------
QO
File:24AU98U #1-476 Acq:24-AUG-1998 23:47:39 GC E1+ Voltage SIR Autospec-Ultima
Sampled Text:300681-5 :T-MM5-4-F :Trai Exp:PAHAlR
152.0626 S:9 SMO(1,3) PKD(5,3,3,0.10%,5000.0,0.00%,F,T)
13:54 14:00 14:06 14:h 14:i8
160.1128 S:9 SMO(1,3) PKD(5,3,3,0.10%,5000.0,0.00%,F,T)
100 % A3.41E7
80 J
70
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301
10
T r—i 1 1 1 1 r 1
14:30 14:36
14:42
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Time
13:54
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14:24
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Time
-------
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File:24AU98U #1-476 Acq:24-AUG-1998 23:47:39 GC EI+ Voltage SIR Autospec-Ultima
Sample#9 Text:300681-5 :T-MM5-4-F :Trai Exp:PAHAIR
130.9920 S:9 SMO(1,3) PKD(S,3,3,0.10%,10000.0,0.00%,F,T)
100
95
90
85 _
80-
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70:
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Time
-------
File:24AU98U #1-666 Acq:24-AUG-I998 23:47:39 GC E1+ Voltage SIR Autospec-UItima
Sample#9 Text:300681-5 :T-MM5-4-F :Trai Exp:PAHAlR
166.0798 S:9 F:2 SMO(1,3) PKD(5,3,3,0.10%,5000.0,0.00%,F,T)
100 % A2.9.7E8
90-
80:
70
60
50
40-
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20-
10
0
16:20 16:22 16:24 16:26 16:28 16:30 16:32 16:54
176.1410 S:9 F:2 SMO(1,3) PKD(5,3,3,0.10%,5000.0,0.00%,F,T)
100 % A1.3JLE7
90-
80 J
70
60 -
50-
40J
30 J
20_
10.
0
O.OEO
Time
5.2E6
4.7E6
4.2E6
3.6E6
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2.1E6
1.6E6
1.0E6
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Time
16:20 16:22 16:24 16:26 16:ST 16:lo 16:32 16:34 16:36 16:38 16:
40 16:42 16:44 16:46
16:
-------
o
File:24AU98U #1-666 Acq:24-AUG-1998 23:47:39 GC EI+ Voltage SIR Autospec-UItima
Sample#9 Text:300681-5 :T-MM5-4-F :Trai Exp:PAHAlR
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70_
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50^
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30
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10
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15:48 16:00 16:12 16:24 16:36 16:48
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100^
90
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60
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10
18:24
176.1410 S:9 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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1.1E8
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2.4E7
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O.OEO
Time
p A2.0pE7
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L5.7E6
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L2.4E6
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-------
File:24AU98U #1-666 Acq:24-AUG-1998 23:47:39 GC EI+ Voltage SIR Autospec-UItima
Sampled Text:300681-5 :T-MM5-4-F :Trai Exp:PAHAIR
••CD
l/O.U
100 3
90:
80 J
70-
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50:
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-------
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File:24AU98U #1-666 Acq:24-AUG-1998 23:47:39 GC EI+ Voltage SIR Autospec-Ultima
Sampled Text:300681-5 :T-MM5-4-F :Trai Exp:PAHAlR
178.0782 S:9 F:2 SMO(1,3) PKD(5,3,3,0.10%,5000.0,0.00%,F,T)
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9.8E6
18.4E6
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5.6E6
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19:24 19:30 19:36
188.1410 S:9 F:2 SMO(1,3) PKD(5,3,3,0.10%,5000.0,0.00%,F,T)
100 % A3.5.6E7
90
80-
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-------
File:24AU98U #1-666 Acq:24-AUG-1998 23:47:39 GC EI+ Voltage SIR Autospec-Ultima
Sample#9 Text:300681-5 :T-MM5-4-F :Trai Exp:PAHAiR
178.0782 S:9 F:2 SMO(1,3) PKD(5,3,3,0.10%,5000.0,0.00%,F,T)
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0
19:45 19:46 19:47 19:48 19:49
188.1410 S:9 F:2 SMO(1,3) PKD(5,3,3,0.10%)5000.0,0.00%,F,T)
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80
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60
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19
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19:*
: O.OEO
Time
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6.7E6
5.4E6
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2.7E6
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19:57 Time
19:45
19:46
19:47
19:48
19:49
19:50 19:5119:52 19^3 19:54 19:55 19:56
-------
o
File:24AU98U #1-666 Acq:24-AUG-1998 23:47:39 GC EI+ Voltage SIR Autospec-Ultima
Sample#9 Text:300681-5 :T-MM5-4-F :Trai Exp:PAHAIR
204.9888 S:9 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
95
90:
85 J
80 j
75 J
70 J
651
601
55-
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35 J
30 J
25
20-
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5
0
A6.11E6
A4.64E6
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16:60
17:60
18:00
19:6o
20:00
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5.8E6
L5.5E6
5.2E6
4.9E6
4.7E6
4.4E6
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3.8E6
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:2.3E6
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-1.2E6
8.7E5
5.8E5
2.9E5
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)0 Time
-------
File:24AU98U #1-934 Acq:24-AUG-1998 23:47:39 GC E1+ Voltage SIR Autospec-UHima
Sample#9 Text:300681-5 :T-MM5-4-F :Trai Exp:PAHADt
202.0782 S:9 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 ft A3.1JE8
22:00 23:6o 24:00
212.1410 S:9 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
90 J
80 J
70 J
60 J
50 J
40 J
30 J
20 J
101 A3.12E7 A3.11E7
A A
1.6E8
1.4E8
1.3E8
.1E8
9.4E7
7.9E7
6.3E7
4.7E7
3.1E7
1.6E7
O.OEO
Time
1.1E9
9.7E8
1 1 1 1 1 r 1 1 1— 1 1 r 1-
22:00 23:00 24:00
244.1974 S:9 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
90.
80-
50^
40
30.;
20 J
10
0
26:i
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26:i
7.5E8
6.4E8
5.4E8
4.3E8
3.2E8
2.1E8
1.1E8
O.OEO
Time
-------
File:24AU98U #1-934 Acq:24-AUG-1998 23:47:39 GC EI+ Voltage SIR Autospec-Ultima
Sample#9 Text:300681-5 .-T-MM5-4-F :Trai Exp:PAHAlR
202.0782 S:9 F:3 SMO(1,3) PKD(5,3,3,0.10%,5000.0,0.00%,F,T)
e*-
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' 23:24' ' ' '23:30 ' ' 23:36 ' ' 23:42 ' ' 23:48'
212.1410 S:9 F:3 SMO(1,3) PKD(S,3,3,0.10%,5000.0,0.00%,F,T)
100 * A3.12E7
90
80 J
70
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40 J
30
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Time
1.2E7
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7.4E6
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5.0E6
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23:24 23:30 23:36 23:42 23:48 ' 23:^4 ' 24:6fl 24:66 ' 'u^T 24:18 24:24 ' 24:30 ' 24:36
Time
-------
File:24AU98U #1-934 Acq:24-AUG-1998 23:47:39 GC EI+ Voltage SIR Autospec-Ultima
Sampled Text:300681-5 :T-MMS-4-F :Trai Exp.-PAHAIR
228.0939 S:9 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
26:36 26:48 27:66 27:ll2 27:24 27:36 27:48 28:66 28:ii 28:24 28:36 28:48 29:66 29:11 29:24 29:36 29^48 30:00 Time
240.1692 S:9 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
A4.2
100^
90
80
70
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26:36 26:4^ 27:66 27:i2 27:24 27:36 27:48^ 28:66 28:li 28:24 28:36 28:48 29-oT^29:i2 29-& 29-$6 29:58 30:00 Time
-------
File:24AU98U #1-934 Acq:24-AUG-1998 23:47:39 GC EI+ Voltage SIR Autospec-Ultima
Sample#9 Text:300681-5 :T-MM5-4-F :Trai Exp:PAHAlR
228.0939 S:9 F:3 SMO(1,3) PKD(5,3,3,0.10%,5000.0,0.00%,F,T)
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-------
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File:24AU98U #1-955 Acq:24-AUG-1998 23:47:39 GC EI+ Voltage SIR Autospec-Ultima
Sampled Text:300681-5 :T-MM5-4-F :Trai Exp:PAHAIR
252.0939 S:9 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 % A9.4JE6
90 j
801
70 -
60
50 -
40J
30 j
20
10 J
A7.63E6
A3.03E6
34:60
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.1.2E6
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-8.3E5
.6.6E5
-5.0E5
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Time
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.1.6E7
.1.4E7
.1.2E7
1.0E7
30:00
264.1692
100%
90
80 _
70_
60
50
40
30
20
10 J
~1'''31:00''''32:00
S:9 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
33:(1
A7.80E7
A2.62E7
.7.0E6
5.2E6
3.5E6
1.7E6
O.OEO
Time
30:00
31:C
32:
33:
34:t
-------
File:24AU98U #1-955 Acq:24-AUG-1998 23:47:39 GC EI+ Voltage SIR Autospec-Ultima
Sampled Text:300681-5 :T-MM5-4-F :Trai Exp:PAHAlR
252.0939 S:9 F:4SMO(1,3) PKD(5,3,3,0.10%,5000.0,0.00%,F,T)
31:30 31:36 31:42 31:48
264.1692 S:9 F:4 SMO(1,3) PKD(5,3,3,0.10%,5000.0,0.00%,F,T)
100 % A2.62E7
1.5E6
1.3E6
1.2E6
9.9E5
_8.3E5
L6.6E5
L5.0E5
3.3E5
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31:3
31:36
31:42
Th48 31:54
32:i
32:i
32:
32:18 Time
6.7E6
6.1E6
15.4E6
U.7E6
4.0E6
3.4E6
2.7E6
2.0E6
1.3E6
L6.7E5
^O.OEO
32:18 Time
-------
•'J
File:24AU98U #1-955 Acq:24-AUG-1998 23:47:39 GC EI+ Voltage SIR Aulospec-Ultima
Sampled Text:300681-5 :T-MM5-4-F :Trai Exp:PAHAlR
252.0939 S:9 F:4 SMO(1,3) PKD(5,3,3,0.10%,5000.0,0.00%,F,T)
A6.69E6
90
80
70 J
60
50-
30.:
20 -
10
OJ
A1.27E5
-1.6E6
-I.4E6
:1.3E6
T i jri ,i i | r ' i i i i | i i i i i | i i i—i—i—i—i—r—i—f—i—i—r—i—i—i—i—i—i—i—i—r—i—i—i—i—r—r~i—i—i—i—i—i—i—I—i—i—r—i—i—[—i—i—i—i—i—i—r
32:30 32:36 32:42 32:48 32:54 33:00 33:66 33:12 33:18 33:24 33:30 33:36
264.1692 S:9 F:4 SMO(1,3) PKD(5,3,3,0.10%,5000.0,0.00%,F,T)
L9.6E5
8.0E5
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Time
-------
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4AU98U #1-955 Acq:24-AUG-1998 23:47:39 GC EI+ Volta
le#9 Text:300681-5 :T-MM5-4-F :Trai Exp:PAHAlR
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-4.5E6
L2.2E6
O.OEO
10 Time
8.3E7
L7.5E7
-6.6E7
L5.8E7
-5.0E7
L4.2E7
L3.3E7
12.5E7
Ll.7E7
L8.3E6
O.OEO
)0 Time
-------
02-SEP-1998 07:25:03 PM Dioxin Furan Unknown RESULTS
DB-5
24AU98U
: 0.333
GC Column
Data file
Weight
dlO-2-Methylnaphthalene
d8-Naphthalene
Naphthalene
2-Methylnaphthalene
d8-Acenaphthylene
Acenaphthylene
dl0-Acenaphthene
Acenaphthene
dlO-Anthracene
dlO-Fluorene
Fluorene
dl0-Phenanthrene
Phenanthrene
Anthracene
d!2-Benzo(e)pyrene
dlO-Fluoranthene
Fluoranthene
dlO-Pyrene
Pyrene
dl2-Benzo(a)anthracene
Benzo(a)anthracene
d!2-Chrysene
Chrysene
d!2-Benzo(e)pyrene
d!2-Benzo(b)fluoranthene
Benzo(b)fluoranthene
d!2-Benzo(k)fluoranthene
Benzo(k)fluoranthene
d!2-Benzo(a)pyrene
Benzo(e)pyrene
Benzo(a)pyrene
d!2-Perylene
Perylene
d!2-Indeno(123-cd)pyrene
Indeno(123 -cd)pyrene
d!4-Dibenz(ah)anthracene
Dibenz(ah)anthracene
dl2-Benzo(ghi)perylene
Benzo(ghi)perylene
d8-Naphthalene
13C-Naphthalene
Results : 24AU98U101.RES
Date analyzed
300681-6 :T-MM5-3-F :Trai Ex Cal
Total Isotope R. T. RRF
Ratio
PAHX.TRG
24-AUG-98
PAHX081998U.RRF
ng/ Rec/
87413600 1.00 Y
26897800 1.00 Y
4466820000 1.00 Y
6528200000 1.00 Y
77362800 1.00 Y
264000000 1.00 Y
30784800 1.00 Y
945242000 1.00 Y
59406600 1.00 Y
32678000 1.00 Y
2240000000 1.00 Y
94854200 1.00 Y
6888660000 1.00 Y
570000000 1.00 Y
119666800 1.00 Y
92488200 1.00 Y
598000000 1.00 Y
77570800 1.00 Y
1562000000 1.00 Y
94022600 1.00 Y
204000000 1.00 Y
104285400 1.00 Y
1310000000 1.00 Y
119666800 1.00 Y
72696800 1.00 Y
67200000 1.00 Y
94960600 1.00 Y
25000000 1.00 Y
65459600 1.00 Y
78800000 1.00 Y
15600000 1.00 Y
49583200 1.00 Y
149800000 1.00 Y
80130600 1.00 Y
1.00 Y
°(^° •j *>teOe>OO
54138400 1.00 Y
3040000 1.00 Y
69200000 1.00 Y
15040000 1.00 Y
26897800 1.00 Y
* No Peak 0.00 N
uuu
11
8
9
11
14
14
14
14
19
16
16
19
19
19
32
23
23
24
24
28
28
28
28
32
31
31
31
31
32
32
32
33
33
38
38
—f \J
38
38
39
39
8
Q
ss
9
58
2
16
13
16
47
53
47
29
35
37
42
50
38
32
35
14
17
5
10
13
16
38
39
44
44
50
51
45
57
9
15
0
2
1
10
19
28
58
2
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
N
1
1
1
0
1
0
0
0
1
1
1
2
0
0
1
0
1
0
1
0
1
0
0
1
0
1
0
1
0
1
1
0
1
0
n
\J
0
1
0
0
1
0
.00
.25
.05
.77
.55
.86
.88
.93
.00
.13
.05
.63
.84
.83
.00
.80
.04
.81
.11
.65
.06
.85
.97
.00
.63
.07
.90
.16
.75
.46
.02
.61
.62
.71
61
• *J J-
.44
.11
.63
.99
.00
.98
bANJf
50
12
LU W
.00
.35
UJb
25
2.46+04 ^B
4.76+04 £~ ^
28
593
20
4958
50
24
9802
30
.55
.47
.07
•36 £
.00
.35
.67 &•
.37
57
40
"5>
49
"6
61
1.36+04 G
-------
02-SEP-1998 07:25:03 PM Dioxin Furan Unknown RESULTS
dlO-Fluorene 32678000 1.00 Y 16: 29 Y 1.00 50.00
13C-Fluorene 20996200 1.00 Y 16: 35 Y 0.76 42.38 85
-------
02-SEP-1998 07:25:01 PM Dioxin Furan Unknown RESULTS
24AU98U101.RES
Date analyzed
MM5-3-F :Trai Ex Cal
Isotope R. T. RRF
Ratio mm:ss
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
0
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
N
11:
8:
9:
11:
14:
14:
14:
14:
19:
16:
16:
19:
19:
19:
32:
23:
23:
24:
24:
28:
28:
28:
28:
32:
31:
31:
31:
31:
32:
32:
32:
33:
33:
38:
38:
38:
38:
39:
39:
8:
9:
9
58
2
16
13
16
47
53
47
29
35
37
42
50
38
32
35
14
17
5
10
13
16
38
39
44
44
50
51
45
57
9
15
0
2
1
10
19
28
58
2
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
N
PAHX.TRG
24-AUG-98
PAHX081998U.RRF
ng/ Rec/
SAMPLE MDL
0.333
1.00 50.00
1.25 12.35
1.05 2.46+04
0.77 4.76+04
1.55 28.55
0.86 593.47
0.88 20.07
0.93 4958.36
1.00 50.00
1.13 24.35
1.05 9802.67
2.63 30.37
0.84 1.36+04
0.83 1088.32
1.00 50.00
0.80 48.11
1.04 933.07
0.81 40.03
1.11 2730.25
0.65 60.42
1.06 308.72
0.85 51.37
0.97 1941.89
43706800 43706800
25 13448900 13448900
2233410000 2233410000
3264100000 3264100000
57
40
1
0
1
0
1
0
1
1
0
1
0
0
0
1
0
0
1
0
.00
.63
.07
.90
.16
.75
.46
.02
.61
.62
.71
.61
.44
.11
.63
.99
.00
.98
50
48
129
44
34
36
123
34
33
280
47
15
51
7
45
32
50
0
.00
.52
.82
.28
.21
.41
.43
.95
.71
.34
.38
.57
.28
.58=DL
.87
.94
.00
.00
97
89
73
67
95
103
92
0
38681400 38681400
132000000 132000000
15392400
472621000
15392400
472621000
29703300 29703300
49 16339000 16339000
1120000000 1120000000
61 47427100 47427100
3444330000 3444330000
285000000 285000000
96
80
121
103
97
89
73
67
95
103
I
92
0
59833400
46244100
299000000
38785400
781000000
47011300
102000000
52142700
655000000
59833400
36348400
33600000
47480300
12500000
32729800
39400000
7800000
24791600
74900000
40065300
2540000
27069200
1520000
34600000
7520000
13448900
0
59833400
46244100
299000000
38785400
781000000
47011300
102000000
52142700
655000000
59833400
36348400
33600000
47480300
12500000
32729800
39400000
7800000
24791600
74900000
40065300
2540000
27069200
1520000
34600000
7520000
13448900
0
-------
02-SEP-1998 07:25:01 PM Dioxin Furan Unknown RESULTS
1.00 Y 16: 29 Y 1.00 50.00 16339000 16339000
1.00 Y 16: 35 Y 0.76 42.38 85 10498100 10498100
-------
25-AUG-1998 09:31:13 AM
PAH Unknown RESULTS
Mass Spec : ULTIMA
GC Column : DB-5
Data file : 24AU98U
Weight : 0.333
Name
dlO-2-Methylnaphthalene
d8-Naphthalene
Naphthalene
2-Methylnaphthalene
d8-Acenaphthylene
Acenaphthylene
dlO-Acenaphthene
Acenaphthene
dlO-Anthracene
dlO-Fluorene
Fluorene
dlO-Phenanthrene
Phenanthrene
Anthracene
d!2-Benzo(e)pyrene
dl0 -Fluoranthene
Fluoranthene
dlO-Pyrene
Pyrene
d!2-Benzo(a)anthracene
Benzo(a)anthracene
d!2-Chrysene
Chrysene
dJ2-Benzo(e)pyrene
d!2-Benzo(b)fluoranthene
Benzo(b)fluoranthene
d!2-Benzo(k)fluoranthene
Benzo(k)fluoranthene
d!2-Benzo(a)pyrene
Benzo(e)pyrene
Benzo(a)pyrene
dl2-Perylene
Perylene
d!2-Indeno(123-cd)pyrene
Indeno(12 3 -cd)pyrene
d!4-Dibenz(ah)anthracene
Dibenz(ah)anthracene
d!2-Benzo(ghi)perylene
Benzo(ghi)perylene
d8-Naphthalene
l3C-Naphthalene
Results : 24AU98U101.RES
Date analyzed
300681-6 :T-MM5-3-F :Trai Ex Cal
Total Isotope R. T. RRF
Response Ratio mm:ss
87413600 1.00 Y 11: 9 Y
26897800 1.00 Y 8: 58 Y
4466820000 1.00 Y 9: 2 Y
6528200000 1.00 Y 11: 16 Y
77362800 1.00 Y 14: 13 Y
436756000 1.00 Y 14: 16 Y
30784800 1.00 Y 14: 47 Y
945242000 1.00 Y 14: 53 Y
59406600 1.00 Y
32678000 1.00 Y
2352100000 1.00 Y
49583200 1.00 Y
188974400 1.00 Y
80130600 1.00 Y
* No Peak 0.00 N
54138400 1.00 Y
5245900 1.00 Y
19: 47 Y
16: 29 Y
16: 35 Y
94854200 1.00 Y 19:
6888660000 1.00 Y 19:
* No Peak 0.00 N 19:
119666800 1.00 Y 32:
92488200 1.00 Y 23:
697630000 1.00 Y 23:
77570800 1.00 Y 24:
1734654000 1.00 Y 24:
94022600 1.00 Y 28;
404070000 1.00 Y 28:
104285400 1.00 Y 28:
1508610000 1.00 Y 28:
119666800 1.00 Y 32:
72696800 1.00 Y 31:
124186600 1.00 Y 31:
94960600 1.00 Y 31
124186600 1.00 Y 31
65459600 1.00 Y 32
104472800 1.00 Y 32
36812400 1.00 Y 32
* No Peak
* No Peak
0.00 N
0.00 N
26897800 1.00 Y
* No Peak 0.00 N
33:
33:
38:
38:
38
38
39
39
8
9
37 Y
42 Y
50 N
38 Y
32 Y
35 Y
14 Y
17 Y
5 Y
10 Y
13 Y
16 Y
38 Y
39 Y
44 Y
44 Y
44 Y
51 Y
45 Y
57 Y
9 Y
15 Y
0 Y
2 N
1 Y
10 Y
19 N
28 N
58 Y
2 N
: PAHX.TRG
: 24-AUG-98
: PAHX081998U.RRF
ng/ Rec/
SAMPLE MDL
1.00 50.00
1.25 12.35 25
1.05 2.46+04 0.000
0.77 4.7e+04 0.000
1.55 28.55 57
0.86 981.83 0.000
0.88 20.07 40
0.93 4958.36 0.000
1.00 50.00
1.13 24.35 49
1.05 l.Oe+04 0.000
2.63 30.37 61
0.84 1.3e-)-04 0.000
0.83 0.00 0.000
1.00 50.00
0.80 48.11 96
1.04 1088.52 0.000
0.81 40.03 80
1.11 3032.03 0.000
0.65 60.42 121
1.06 611.49 0.000
0.85 51.37 103
0.97 2236.30 0.000
1.00
0.63
1.07
0.90
1.16
0.75
1.46
1.02
0.61
1.62
0.71
0.61
0.44
1.11
0.63
0.99
1.00
0.98
50.00
48.52
239.92
44.28
169.93
36.41
163.65
82.48
33.71
353.65
47.38
0.00
51.28
13.08
0.00
50.00
0.00
97
0.000
89
0.000
73
0.000
0.000
67
0.000
95
0.000
103
0.000
L^
"^
-------
25-AUG-1998 09:31:13 AM PAH Unknown RESULTS
dlO-Fluorene 32678000 1.00 Y 16: 29 Y 1.00 50.00
13C-Fluorene 20996200 1.00 Y 16: 35 Y 0.76 42.38 85
-------
File:24AU98U #1-477 Acq:2S-AUG-1998 00:34:10 GC EI+ Voltage SIR Autospec-Ultima
Sample/CIO Text:300681-6 :T-MM5-3-F :Trai Exp:PAHAlR
100 % A2.2?E9
80-
60-
40_
20_
OJ
A
A
'^ i* ~ i i 1 T I i 1 1 1 1 1 i ' i — r ' 1 '
9:00 10:6o 11:00
134.0827 S:10 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 % A8.72E5
80 J
60-
40-,
20 1
OJ
136.1
100 S
80 J
60 J
40J
20 J
0
142.0
100 S
80 _
60-
40-
20 J
0
f\l
A9.05E5
A1.03E6 A A4<49E5
/V\ / \ A2.65E5 A
I /\l\, A A
1 f=±=-t i i j . i i i i i — -T '
9:00 10:00 11:00
128 S:l
. A8.7
J
0 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
»E7
A1.34E7
L /x A
1 "~^ 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 r
9:00 10:00 11:00
782 S:10 SMO(1,3) PKD(5>3,3,0.10%,10000.0,0.00%,F,T)
A:
9:do 10:00 ll:6o
7.2E8
12:60 13:
-5.7E8
L4.3E8
L2.9E8
A.4ES
O.OEO
)0 Time
2.9E5
12:00 13:
12:6o 13:J
L26E9
A A2.78E9
l\
11 A
12:60 13:
L2.3E5
L1.7E5
L1.2E5
L5.8E4
O.OEO
30 Time
2.8E7
L2.2E7
L1.7E7
L1.1E7
O.OEO
)0 Time
1.0E9
L8.0E8
L6.0E8
J-4.0E8
-2.0ES
- O.OEO
)0 Time
152.1410 S:10 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100% A4. (7E7 r1.4E7
80 J
60 J
40 J
20 J
'
1 "•"! 1 1 j 1 1 1 1 1 1 1 1 1 1 1 1 — r
9:00 10:6o 11:00
-^=— 1 1 1 1 T- 1 1 1 1 '
12:00 13:(
L1.1E7
L8.4E6
L5.6E6
L2.8E6
-O.OEO
)0 Time
-------
File:24AU98U #1-477 Acq:25-AUG-1998 00:34:10 GC E1+ Voltage SIR Autospec-Ultima
SampleiflO Text:300681-6 :T-MM5-3-F :Trai Exp:PAHAIR
152.0626 S:10 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
13:00 13:i2 13:24 13:36 13:48 14:66 14:i2 14:24
160.1128 S:10 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 % A3.8.7E7
80:
60
20
i3:i2 13:24 13:36 13:1
A7.98E6
y\
O.OEO
Time
^1.1E7
9.0E6
:6.7E6
:4.5E6
L2.2E6
LO.OEO
Time
.-1.5E8
1.2E8
:9.0E7
:6.0E7
L3.0E7
O.C
. . . . , I I '"(I r i""i—i—|—i—i i ~i i | I i f~7 i ii i1 i~i—i—I 'i i i' i i I 'i i i i i i TT . ' i i 1i~ I i I I i i'
13:00 13:12 13:24 13:36 13:48 14:6o 14:12 14:24 14:36 14:48 15:6o 15:12 15:24 15:36
154.0782 S:10 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 % A4.73E8
80
60:
40:
20:
A1.60E8
A2.67E8
A2.02E8
.30E7
A1.28E8
A1.09E8
13:00 13:i2 13:24 T3:36 13:48 14:66
164.1410 S:10 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
80:
60
40:
20:
A5.08E7
.:l2 ' 'U:24
14:12
0:
t . \ i i i <-\\< .
14:36 14:48
A1.54E7
-^-r~r~T~T ' ' L ' ' ' ' ' I ' ' ' ' ' i. '
15:00 15:12 15:24 15:36
Time
4.8E6
:3.8E6
:2.9E6
Ll.9E6
:9.6E5
13:00 13:i2 T 13:24 13:36 13:48
T-I—r~i—i i i i I i i i i i—i i i i i i i i i i 'i i i i i* i i i i i i i i i ~i—r~i—~T-i i i' i i i i / i i i
14:00 14:12 14:24 14:36 14:48 15:6o 15:12 15:24 15:36
LO.OEO
Time
-------
File:24AU98U #1-477 Acq:25-AUG-1998 00:34:10 GC EI+ Voltage SIR Autospec-Ultima
Sample#10 Text:300681-6 :T-MM5-3-F :Trai Exp:PAHAlR
152.0626 S:10 SMO(1,3) PKD(5,3,3,0.10%,5000.0,0.00%,F,T)
r 1—-1 1 1 1 r 1 1 1 1 I r 1 1 1 1 1 r 1 1 r
13:54 14:00 14:66 14:12
160.1128 S:10 SMO(1,3) PKD(5,3,3,0.10%,5000.0,0.00%,F,T)
100 % A3.8.7E7
90
80
70 J
60
50 jj
40
30 J
20
10
14:1
14:2
14
5o~
14:
0
^rLO.OEO
Time
1.1E7
_1.0E7
9.0E6
7.8E6
6.7E6
:5.6E6
4.5E6
-3.4E6
2.2E6
H.1E6
I I I I ii I 1 I I i ' i [ i r—i 1 i I 1 1 i
13:54 14:00 14:06 14:12
-O.OEO
Time
14:i8
14:24
14::
14::
-------
File:24AU98U #1-477 Acq:25-AUG-1998 00:34:10 GC EI+ Voltage SIR Autospec-UMima
Sample#10 Text:300681-6 :T-MM5-3-F :Trai Exp:PAHAIR
130.9920 S:10 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
951
90
85
80-
75.;
70:
65 :
60 J
55 J
sol
45:
40:
35-^
30-
25-
20
15
10
5_
A5.96E8 A7.97E8
A8.73E8
A9.24E8
A3.83E8
A8.88E8
A1.00E9
11
A
10:t
12:0
14:fl
CO
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1.4E8
:1.3E8
1.3E8
M.2E8
1.1E8
1.0E8
-9.8E7
9.1E7
:8.4E7
:7,7E7
7.0E7
6.3E7
t:5.6E7
4.9E7
4.2E7
-3.5E7
L2.8E7
2.1E7
1.4E7
L7.0E6
O.OEO
Time
-------
File:24AU98U #1-665 Acq:25-AUG-1998 00:34:10 GC E1+ Voltage SIR Autospec-UUima
SampleiflO Text:300681-6 :T-MM5-3-F :Trai Exp:PAHAIR
166.0798 S:10 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100% A1.18E9
90 J
80 J
70 J
60 J
50 J
40^
30 J
20 J
10.;
OJ
A1.18E8
A1.18E8
-^i—|—I i I i i i—i—i—I—I I I I T~TiTT~| ~i I i 'i—i—i—i IM i—i—i T i—i—Hi—i iT*"i i—i—i—r-T—1—i i pT i i Pi I r i FT i pi
15:48 16:00 16:12 16:24 16:36 16:48 17:00 17:12 17:24 17:36 17:48
172.0984 S:10 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 % A1.05E7
90 J
80,
70
50-
40
304
20
10 Jj
18:6o 18:i2 18:24
-4.2E8
L3.7E8
M.3E8
L2.9E8
L2.5E8
M.1E8
L1.7E8
L1.2E8
,8.3E7
L4.2E7
LO.OEO
Time
-4.0E6
-3.6E6
_3.2E6
-2.8E6
-2.4E6
-2.0E6
.1.6E6
-1.2E6
-7.9E5
-4.0E5
LO.OEO
Time
O
A5.71E5
\_^"\
15:48 16:6fl 16:12 16:24 16:36 16:48 ' 17:66
176.1410 S:10 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
17:i2 17:24 17:36 17:48 18:66 18:iz 18:24
A2.38E6
15:48
i — i — r — i — i — i — i — i — i — i — i — i — i — i — i — , — i — i — , — , — i — i — i — i — i — i — i — i — i — , — i — i — i — i — , — i — i — i — i — i — i — i — i — i — i — i — i — i — i — i — i — r — I — I — I — i — I — I — I — I — i — i — pn
16:24 16:36 16:48 17:00 17:12 17:24 17:36 17:48 18:00 18:12 18:24
-6.5E6
5.8E6
-5.2E6
-4.5E6
-3.9E6
^3.2E6
^2.6E6
L1.9E6
L1.3E6
6.5E5
O.OEO
Time
-------
File:24AU98U #1-665 Acq:25-AUG-1998 00:34:10 GC E1+ Voltage SIR Autospec-Ultima
Sample#10 Text:300681-6 :T-MM5-3-F :Trai Exp:PAHAlR
166.0798 S:10 F:2 SMO(1,3) PKD(5,3,3,0.10%,5000.0,0.00%,F,T)
100% A1.12E9
••—i 1 1 1 i 1— I '—i 1 l i 1 r—
16:18 16:24 16:30
176.1410 S:10 F:2 SMO(1,3) PKD(5,3,3,0.10%,5000.0,0.00%,F,T)
100 % A1.69E7
90
80
70
60 4
50
40
30.;
20 j
10 -
16:
0.
16:18
16:42
16:48
A8.15E5
16:2
16:30
16
36"
16:42
A1.34E6
16:48
O.OEO
Time
6.5E6
-5.8E6
5.2E6
4.5E6
L3.9E6
3.2E6
^2.6E6
-1.9E6
L1.3E6
L6.5E5
O.OEO
Time
-------
FiIe:24AU98U #1-665 Acq:25-AUG-1998 00:34:10 GC EI+ Voltage SIR Autospec-Ultima
Sample#10 Text:300681-6 :T-MM5-3-F :Trai Exp:PAHAIR
178.0782 S:10 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
1003
90:
80:
70:
60:
50:
40:
30:
20:
10:
A3.4
A4.47E8
A4.52E8/1 A1.89E8
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-8.6E8
:7.5E8
:6.4E8
:5.4E8
:4.3E8
:3.2E8
L2.1E8
:1.1E8
O.OEO
)0 Time
188.1410 S:10 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
1005
90:
80:
70:
60:
50 j
40:
30:
20:
10:
0
18:
, A4
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L8.8E6
:7.0E6
L5.3E6
L3.5E6
1.8E6
: O.OEO
)0 Time
-------
File:24AU98U #1-665 Acq:25-AUG-1998 00:34:10 GC EI+ Voltage SIR Autospec-Ultima
Sample#10 Text:300681-6 :T-MM5-3-F :Trai Exp:PAHAlR
178.0782 S:10 F:2 SMO(1,3) PKD(5,3,3,0.10%,5000.0,0.00%,F,T)
100 % A3.44E9
90
80
704
60
504
40
30-:
20 J
10
0
" 'I i • i I i i I i * i—i—i—r—i—i—i—i—i—r—i—i—i—i—i—i—
19:18 19:24 19:30 19:36 19:42
188.1410 S:10 F:2 SMO(1,3) PKD(5,3,3,0.10%,5000.0,0.00%,F,T)
100 % A4.74E7
90 J
80
70 4
60
504
40
30 -
20-
10
19:48
19:5
20:i
20:1
20:1
0
19
A2.97E7
:\8 19:2^
o
-------
File:24AU98U #1-665 Acq:2S-AUG-1998 00:34:10 GC EI+ Voltage SIR Autospec-Ultima
SamplellO Text:300681-6 :T-MM5-3-F :Trai Exp:PAHAIR
204.9888 S:10 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
16:60
O.OEO
(0 Time
-------
File:24AU98U #1-934 Acq:25-AUG-1998 00:34:10 GC EI+ Voltage SIR Autospec-Ultima
SamplellO Text:300681-6 :T-MM5-3-F :Trai Exp:PAHAlR
202.0782 S:10 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
90 _
80
70
60 j
50
40
30.
20 J
10.
0.
A8.67E8
A1.35E8
A4.68E7
A3.49E8
A1.81E8
C\.>
Sf
-2.7E8
-2.4E8
-2.2E8
-1.9E8
1.6E8
-1.4E8
.1.1E8
8.2E7
.5.4E7
-2.7E7
-O.OEO
Time
-1.2E8
.1.1E8
9.9E7
8.6E7
7.4E7
6.2E7
4.9E7
3.7E7
2.5E7
-1.2E7
O.OEO
Time
1.1E9
9.7E8
8.6E8
7.5E8
6.4E8
5.4E8
4.3E8
3.2E8
2.1E8
22:00 23:6o 24:1)0
212.1410 S:10 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 S.
90 J
80 J
70 J
60 J
50 J
40 J
30 J
20 J
lft ^ A4.62E7 A3.88E7
!i .__.. _ __ A . .A.
26:00
22:00 23:00 24:00
244.1974 S:10 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
90.
80.
70^
50 J
40 J.
30 J
201
10 J
OJ
22:60 23:
26:00
24:60
25:t
26:t
-O.OEO
Time
-------
cv
File:24AU98U #1-934 Acq:25-AUG-1998 00:34:10 GC EI+ Voltage SLR Autospec-Ultima
Sample#10 Text:300681-6 :T-MM5-3-F :Trai Exp:PAHAlR
202.0782 S:10 F:3 SMO(1,3) PKD(5,3,3,0.10%,5000.0,0.00%,F,T)
100'
23:66 ' ' 23:ii 23:18 23:24 ' 23^6 23:36 23:42 23:48 23:^4 ' 24:6o 24:66 24:li 24:is 24:24 24:30
tO.OEO
Time
212.1410 S:10 F:3 SMO(1,3) PKD(5(3,3,0.10%,5000.0,0.00%,F,T)
23:66 23:ii 23:il8 23:24 23:30 23:36 23:42 23:48 23:^4 24:66 24:66 24:12 24:18 24:^4 24:30
LO.OEO
Time
-------
File:24AU98U #1-934 Acq:25-AUG-1998 00:34:10 GC EI+ Voltage SIR Autospec-Ultima
Sample#10 Text:300681-6 :T-MM5-3-F :Trai Exp:PAHAIR
228.0939 S:10 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
A7.54E8
26:36 26:48 27:66 27:ki 27:24 27:36 27:48 28:66 28:ii 28:24 28:36 28:48 29:66 29:ii 29:24 29:36 29:48 30;
240.1692 S:10 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 % A5.2JE7
90 j
80 J
70 J
60 J
50 J
401
30 J
20 J
10J
0
O.OEO
DO Time
1.6E7
A.4E7
11.3E7
1.1E7
-9.0E6
26:36 26:48 ' 27:66 27:ii 27:24 ' 27:36 IW^lsioT ' 28:il 28:24 28^6 28:48 29:66 29^2 29:24 29:36 29?48 30:
5.4E6
L3.6E6
1.8E6
O.OEO
)0 Time
-------
File:24AU98U #1-934 Acq:25-AUG-1998 00:34:10 GC EI+ Voltage SIR Autospec-UItima
Sample#10 Text:300681-6 :T-MM5-3-F :Trai Exp:PAHAlR
228.0939 S:10 F:3 SMO(1,3) PKD(5,3,3,0.10%,5000.0,0.00%,F,T)
A6.55E8
cv?
27:36 27:42 27:48 27:54 28:66 28:06 28:i2 28:18 28:24 28:30
240.1692 S:10 F:3 SMO(1,3) PKD(5,3,3,0.10%,5000.0,0.00%,F,T)
100 % A4.88E7 A5.60E7
90
80
70 4
60
50 4
40
30 4
20
10 4
0
28:36 28:42 28:48 28:54
O.OEO
29:00 Time
1.8E7
L1.6E7
:1.4E7
Ll.3E7
L1.1E7
9.0E6
7.2E6
5.4E6
-3.6E6
.8E6
27:36 27:42 27:48 27:54 ' 28:66 28:66 izsTli ' 28:l8 ' 28:24 ' ' 28:30 28:36 28:42 ' ' 28:48 28:54
-O.OEO
29:00 Time
-------
A/
File:24AU98U #1-934 Acq:25-AUG-1998 00:34:10 GC EI+ Voltage SIR Autospec-Uttima
Sample#10 Text:300681-6 :T-MM5-3-F :Trai Exp:PAHAlR
230.9856 S:10 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
IUW3
95_
90-,
85 J
80 1
75 1
70.;
65-:
60-;
55 1
sol
45 J
40:
35-:
30-
25 J
20
15 J
10J
sJ
0
22:
A1.30E
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ill
1
0
8
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i
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if
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AA
/
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/
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yl
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23:6o 24:00 25:6o 26:6o 27:6o 28:6o 29:6o 30:
1.1E8
L1.0E8
L9.4E7
L8.9E7
-8.3E7
L7.7E7
:7.2E7
L6.6E7
L6.1E7
15.5E7
LS.OE7
;.4.4E7
:3.9E7
-3.3E7
L2.8E7
" 2.2E7
Ll.7E7
L1.1E7
-5.5E6
O.OEO
0 Time
-------
File:24AU98U #1-955 Acq:25-AUG-1998 00:34:10 GC EI+ Voltage SIR Autospec-Ultima
Sample#10 Text:300681-6 :T-MM5-3-F :Trai Exp:PAHAlR
252.0939 S:10 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
A3.63E7
264.1692 S:10 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
90
80 jj
70
60 -
50 j
40
30-
20-
10-
0
30:60
A5.98E7
A6.50E6
A2.88E6
31:4
32:<]
33:t
34;
i-oT
O.OEO
Time
1.4E7
-1.3E7
L1.1E7
-9.9E6
L8.5E6
L7.1E6
L5.7E6
L4.3E6
L2.8E6
1.4E6
O.OEO
Time
-------
CO
File:24AU98U #1-955 Acq:25-AUG-1998 00:34:10 GC EI+ Voltage SIR Autospec-UUima
Sample#10 Text:300681-6 :T-MM5-3-F :Trai Exp:PAHAIR
252.0939 S:10 F:4 SMO(1,3) PKD(5,3,3,0.10%,5000.0,0.00%,F,T)
100% A3.3
-•i 1 1 r 1 1 1 1 1 r 1 1 1 1 \ | 1 1 1 1 1 1 1 1 1 1 1 r
31:30 31:36 31:42 31:48 31:54
264.1692 S:10 F:4 SMO(1,3) PKD(5,3,3,0.10%,5000.0,0.00%,F,T)
32:00
32:t
32:
-O.OEO
Time
32:66
32:12 Time
-------
File:24AU98U #1-955 Acq:25-AUG-1998 00:34:10 GC EI+ Voltage SIR Autospec-Ultima
SamplellO Text:300681-6 :T-MM5-3-F :Trai ExprPAHAIR
252.0939 S:10 F:4 SMO(1,3) PKD(5,3,3,0.10%,5000.0,0.00%,F,T)
100 S
90-
80-
70 J
601
50
40 4
30
20
10
0
A7.49E7
A3.94E7
A6.38E6
A5.61E6
A7.80E6
A6.45E6
A4.19E6
~T '
32:24 32:36 32:48 33:00
264.1692 S:10 F:4 SMO(1,3) PKD(5,3,3,0.10%,5000.0,0.00%,F,T)
33:b
33:24 33:36 33:48 34:6(T
•cv
.-1.7E7
L1.5E7
-1.3E7
L1.2E7
1.0E7
8.4E6
L6.7E6
S.OE6
L3.4E6
A3.94E6
,. O.OEO
34:12 Time
1.4E7
-1.3E7
L1.1E7
L9.9E6
8.5E6
7.1E6
5.7E6
4.3E6
U.8E6
1.4E6
100 S
90 J
80
70
60
40
30
20 _i
10
0
A5.98E7
A2.48E7
32:2
32:36
32:48
33
:6o'
33
:12'
$3:24
33
33:3
33:48
T 34:6o
-i—i—i—
34:12
O.OEO
Time
-------
FiIe:24AU98U #1-955 Acq:25-AUG-1998 00:34:10 GC EI+ Voltage SIR
Sample#10 Text:300681-6 :T-MM5-3-F :Trai Exp:PAHAIR
276.0939 S:10 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 S>
80:
60:
40-
20:
0:
36:
288.1
1002
80:
60:
40:
20:
0:
36:1
278.1
100 S
80:
60:
40:
20:
0
36:(
292.1
1002
80:
60J
40:
20:
oJ
36:
A2.54E6^_ ^
^^ _^ A4.78E5 ASJiOES^ J JV^J^
— i 1 1 . 1 r 1 1 1 1 1 r 1 1 1
)0 37:00 38:00
692 S:10 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
A4.01E7
\
I \
J \^__
M ' 37:00 ' ~~" ^38:00^
096 S:10 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
A2.62E6
A
A A562E5 A6.17E5 / \
1 A_ S~***-S- ^ il^vxC^-^^1— [ ^ — ^
>0 37:6o 38:6o
974 S:10 F:4 SMO(1,3) PKDtS^.S.O.lO^c.lOOOO.O^.OO^o^.T)
» A2.71E7
A
\
\
J \^_
)0 37:00 38:00
O
cv?
Autospec-Ultima
A7.52E6 p9.6E5
A
.X 1 \
A6.54E4 y V^_
~
'39:00 40:6o 41:6fl 42:1
A3.46E7
|\
1 \
/ v_
39:60 40:6o 41:6o 42:1
A5.46E5
„
39:60 40:6fl 41:6fl 42:
39:00 40:00 41:00 42:1
:7.7E5
:5.7E5
:3.8E5
:1.9E5
O.OEO
)0 Time
4.7E6
:3.7E6
L2.8E6
A.9E6
:9.4E5
:O.OEO
W Time
3.5E5
:2.8E5
:2.1E5
:1.4E5
L7.0E4
LO.OEO
)0 Time
_2.9E6
L2.3E6
:1.8E6
:1.2E6
L5.9E5
O.OEO
)0 Time
-------
FiIe:24AU98U #1-955 Acq:25-AUG-1998 00:34:10 GC EI+ Voltage SIR Autospec-Ultima
Sample#10 Text:300681-6 :T-MM5-3-F :Trai Exp:PAHAlR
276.0939 S:10 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 % ALJ8E6
90
80
70
60 -
501
40-
30.:
20 j
10 j
-4.4E5
4.0E5
13.5E5
3.1E5
2.6E5
12.2E5
Ll.SES
L1.3E5
8.8E4
-4.4E4
lO.OEO
Time
,_3.5E5
L3.2E5
L2.8E5
L2.5E5
L2.1E5
1.8E5
1.4E5
^I.IES
_7.0E4
L3.5E4
37:48 37:54 38:6o 38:66
278.1096 S:10 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100S
90 1
80 J
70 J
60
50 JJ
40
30 J
20
10 J
38
:i2
38:
38:2
38:3
38::
.O.OEO
Time
37
:48 37:54' ' ' 38:6fl
38:t
38:1
38:
38:2
38:30
38:
-------
File:24AU98U #1-955 Acq:25-AUG-1998 00:34:10 GC EI+ Voltage SIR Autospec-Ultima
Sample#10 Text:30068I-6 :T-MM5-3-F :Trai Exp:PAHAIR
278.1096 S:10 F:4SMO(1,3) PKD(5,3,3,0.10%,5000.0,0.00%,F,T)
A1.52E6
37:24 37:36 37:48 38:6fl 38: b 38:24 38:36
292.1974 S:10 F:4 SMO(1,3) PKD(5,3,3,0.10%,5000.0,0.00%,F,T)
100 % A2.7.6E7
90
80
70-
60 j
50
40
30 j
201
38:48
39:00
39:12
cv
CO
cv
37:2
37:3
37:48
38:C
38:i2
38:2
38:
38:48
39
3)? 39:b
_^
39:24 Time
-2.9E6
:.2.6E6
1.2.3E6
:2.0E6
L1.8E6
-1.5E6
-1.2E6
-8.8E5
[-5.9E5
2.9E5
_O.OEO
39:24 Time
-------
«• J
cv
File:24AU98U #1-955 Acq:25-AUG-1998 00:34:10 GC EI+ Voltage SIR Autospec-Ultima
Sample#10 Text:300681-6 :T-MM5-3-F :Trai Exp:PAHAIR
268.9824 S:10 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 % A9.94E6
90_
80
70 -
60-
50-
40J
30 -
201
101
A2.
^58E7
A1.90E6
VryrnvV
30:00 31:6o 32:6o 33:6fl ~34:6o 35:6o
280.9824 S:10 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
l°0% ..,„„„ A«nm7 A5.55E7
90.:
40:6fl '41:6o'
A7.58E7
-1.7E7
L1.5E7
1.4E7
1.2E7
19.7E6
7.7E6
.3.9E6
1.9E6
O.OEO
)0 Time
7.1E7
L6.4E7
-5.7E7
-5.0E7
-4.3E7
1.3.5E7
L2.8E7
-2.1E7
1.4E7
-7.1E6
-O.OEO
)0 Time
A4.10E7
36:60 37:6o ' 38:6o 39:6fl
5.1j6E7 _ A5.36E7
42:
'31:60' 32:6fl 33:6o 34:6o 35:6o 36:6o 37:6o 38:6o 39:6o 40:6o
'41:6o'
42:
-------
02-SEP-1998 07:30:51 PM Dioxin Furan Unknown RESULTS
GC Column : DB-5
Data file : 24AU98U
Weight : 0.333
Name
dlO-2-Methylnaphthalene
d8-Naphthalene
Naphthalene
2-Methylnaphthalene
d8-Acenaphthylene
Acenaphthylene
dlO-Acenaphthene
Acenaphthene
dlO-Anthracene
dlO-Fluorene
Fluorene
dlO-Phenanthrene
Phenanthrene
Anthracene
dl2 -Benz o(e)pyrene
dlO-Fluoranthene
Fluoranthene
dlO-Pyrene
Pyrene
d!2-Benzo(a)anthracene
Benzo(a)anthracene
d!2-Chrysene
Chrysene
d!2-Benzo(e)pyrene
d!2-Benzo(b)fluoranthene
Benzo(b)fluoranthene
d!2-Benzo(k)fluoranthene
Benzo(k)fluoranthene
dl2-Benzo(a)pyrene
Benzo(e)pyrene
Benzo(a)pyrene
d!2-Perylene
Perylene
d!2-Indeno(123 -cd)pyrene
Indeno(12 3 -cd)pyrene
dl4-Dibenz(ah)anthracene
Dibenz(ah)anthracene
d!2-Benzo(ghi)perylene
Benzo(ghi)perylene
d8-Naphthalene
13C-Naphthalene
Results : 24AU98U121.RES
Date analyzed
300681-8 :T-MM5-FB-F :Tra Ex Cal
Total Isotope R. T. RRF
Response Ratio mm:ss
127604400 1.00 Y 11: 8 Y
96473200 1.00 Y 8: 57 Y
276950000 1.00 Y 9: 1 Y
243898000 1.00 Y 11: 15 Y
152959000 1.00 Y 14: 13 Y
9800000 1.00 Y 14: 15 Y
89953800 1.00 Y 14: 47 Y
83223400 1.00 Y 14: 53 Y
106331600 1.00 Y 19: 47 Y
74490000 1.00 Y 16: 28 Y
220950000 1.00 Y 16: 35 Y
216098000 1.00 Y 19: 37 Y
1968318000 1.00 Y 19: 42 Y
119800000 1.00 Y 19: 50 Y
201406000 1.00 Y 32: 38 Y
183424000 1.00 Y 23: 31 Y
169600000 1.00 Y 23: 35 Y
180294600 1.00 Y 24: 14 Y
464000000 1.00 Y 24: 17 Y
197985600 1.00 Y 28: 5 Y
73800000 1.00 Y 28: 10 Y
213452000 1.00 Y 28: 13 Y
412000000 1.00 Y 28: 16 Y
201406000 1.00 Y 32: 38 Y
133893000 1.00 Y 31: 39 Y
24400000 1.00 Y 31: 44 Y
182007200 1.00 Y 31: 44 Y
6280000 1.00 Y 31: 51 Y
140511400 1.00 Y 32: 51 Y
33600000 1.00 Y 32: 45 Y
7500000 1.00 Y 32: 57 Y
111083000 1.00 Y 33: 9 Y
83400000 1.00 Y 33: 16 Y
167561800 1.00 Y 38: 0 Y
4120000 1.00 Y 38: 2 Y
110062000 1.00 Y 38: 1 Y
1930082 1.00 Y 38: 12 Y
145600000 1.00 Y 39: 19 Y
20000000 1.00 Y 39: 28 Y
96473200 1.00 Y 8: 57 Y
* No Peak 0.00 N 9: IN
PAHX. TRG
24-AUG-98
PAHX081998U.RRF
ng/ Rec/
SAMPLE MDL
1.00
1.25
1.05
0.77
1.55
0.86
0.88
0.93
1.00
1.13
1.05
2.63
0.84
0.83
1.00
0.80
1.04
0.81
1.11
0.65
1.06
0.85
0.97
1.00
0.63
1.07
0.90
1.16
0.75
1.46
1.02
0.61
1.62
0.71
0.61
0.44
1.11
0.63
0.99
1.00
0.98
50.00
30.35 61
409. 25^
492.50 P,
38.67 77
11.14=DL
40.17 80
149.40 *&
50.00
31.01 62
424.18 •£
38.65 77
1624.04 rb
100.40
50.00
56.69 113
133.43 fb
55.28 111
348.94
75.59 151*1
53.04
62.47 125
298.38
50.00
53.10 106
25.59
50.43 101
4.48=DL
46.44 93
24.52
7.83=DL
44.87 90
69.67
58.87 118
6.04=DL
61.94 12^34
2.37=DL ^
57.34 115
20.82
50.00
0.00 0
-------
02-SEP-1998 07:30:51 PM Dioxin Furan Unknown RESULTS
dlO-Fluorene 74490000 1.00 Y 16: 28 Y 1.00 50 00
13C-Fluorene 52979000 1.00 Y 16: 34 Y 0.76 4e!91 94
-------
02-SEP-1998 07:30:49 PM Dioxin Furan Unknown RESULTS
24AU98U121.RES
Date analyzed
MM5-FB-F :Tra Ex Cal
Isotope R. T. RRF
Ratio ram:ss
PAHX.TRG
24-AUG-98
PAHX081998U.RRF
ng/ Rec/
SAMPLE MDL
0.333
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
0.00
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
N
11:
8:
9:
11:
14:
14:
14:
14:
19:
16:
16:
19:
19:
19:
32:
23:
23:
24:
24:
28:
28:
28:
28:
32:
31:
31:
31:
31:
32:
32:
32:
33:
33:
38:
38:
38:
38:
39:
39:
8:
9:
8
57
1
15
13
15
47
53
47
28
35
37
42
50
38
31
35
14
17
5
10
13
16
38
39
44
44
51
51
45
57
9
16
0
2
1
12
19
28
57
1
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
N
1
1
1
0
1
0
0
0
1
1
1
2
0
0
1
0
1
0
1
0
1
0
0
1
0
1
0
1
0
1
1
0
1
0
0
0
1
0
0
1
0
.00
.25
.05
.77
.55
.86
.88
.93
.00
.13
.05
.63
.84
.83
.00
.80
.04
.81
.11
.65
.06
.85
.97
.00
.63
.07
.90
.16
.75
.46
.02
.61
.62
.71
.61
.44
.11
.63
.99
.00
.98
50
30
409
492
38
11
40
149
50
31
424
38
1624
100
50
56
133
55
348
75
53
62
298
50
53
25
50
4
46
24
7
44
69
58
6
61
2
57
20
50
0
.00
.35
.25
.50
.67
61
77
.14=DL
.17
.40
.00
.01
.18
.65
.04
.40
.00
.69
.43
.28
.94
.59
.04
.47
.38
.00
.10
.59
.43
.48=DL
.44
.52
.83=DL
.87
.67
.87
.04=DL
.94
.37=DL
.34
.82
.00
.00
80
62
77
113
111
151
125
106
101
93
90
118
124
115
0
63802200
48236600
138475000
121949000
76479500
4900000
44976900
41611700
53165800
37245000
110475000
108049000
984159000
59900000
100703000
91712000
84800000
90147300
232000000
98992800
36900000
106726000
206000000
100703000
66946500
12200000
91003600
3140000
70255700
16800000
3750000
55541500
41700000
83780900
2060000
55031000
965041
72800000
10000000
48236600
0
63802200
48236600
138475000
121949000
76479500
4900000
44976900
41611700
53165800
37245000
110475000
108049000
984159000
59900000
100703000
91712000
84800000
90147300
232000000
98992800
36900000
106726000
206000000
100703000
66946500
12200000
91003600
3140000
70255700
16800000
3750000
55541500
41700000
83780900
2060000
55031000
965041
72800000
10000000
48236600
0
236
-------
02-SEP-1998 07:30:49 PM Dioxin Furan Unknown RESULTS
1.00 Y 16: 28 Y 1.00 50.00 37245000 37245000
1.00 Y 16: 34 Y 0.76 46.91 94 26489500 26489500
-------
25-AUG-1998 09:34:36 AM
PAH Unknown RESULTS
Mass Spec : ULTIMA
GC Column : DB-5
Data file : 24AU98U
Weight : 0.333
Name
dlO-2-Methylnaphthalene
d8-Naphthalene
Naphthalene
2-Methylnaphthalene
d8-Acenaphthylene
Acenaphthylene
dlO-Acenaphthene
Acenaphthene
dl0-Anthracene
dlO-Fluorene
Fluorene
dl0-Phenanthrene
Phenanthrene
Anthracene
d!2-Benzo(e)pyrene
dl0-Fluoranthene
Fluoranthene
dlO-Pyrene
Pyrene
d!2-Benzo(a)anthracene
Benzo(a)anthracene
d!2-Chrysene
Chrysene
d!2-Benzo(e)pyrene
dl2-Benzo(b)fluoranthene
Benzo(b)fluoranthene
d!2-Benzo(k)fluoranthene
Benzo(k)fluoranthene
d!2-Benzo(a)pyrene
Benzo(e)pyrene
Benzo(a)pyrene
d!2-Perylene
Perylene
d!2-Indeno(123-cd)pyrene
Indeno(123-cd)pyrene
d!4-Dibenz(ah)anthracene
Dibenz(ah)anthracene
d!2-Benzo(ghi)perylene
Benzo(ghi)perylene
d8-Naphthalene
13C-Naphthalene
Results : 24AU98U121.RES
Date analyzed
300681-8 :T-MM5-FB-F :Tra Ex Cal
Total Isotope R. T. RRF
Response Ratio mm:ss
127604400
96473200
276950000
243898000
152959000
19471860
89953800
83223400
106331600
74490000
220950000
216098000
1968318000
*
*
*
*
*
No Peak
201406000
183424000
195685400
180294600
553542000
197985600
170168000
213452000
521800000
201406000
133893000
45782600
182007200
45782600
140511400
44698200
15387420
111083000
100512800
167561800
No Peak
110062000
1930082
No Peak
No Peak
96473200
No Peak
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
l.
1.
1.
0.
1.
1.
1.
1.
1.
1.
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
,00
.00
1.00
1.
1.
1.
1.
1.
1
1
1
1
1
1
1
1
0
1
1
0
0
1
0
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
N
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
N
Y
Y
N
N
Y
N
11:
8:
9:
11:
14:
14:
14:
14:
19:
16:
16:
19:
19:
19:
32:
23:
23:
24:
24:
28:
28:
28:
28:
32:
31:
31:
31:
31:
32:
32:
32:
33:
33:
38:
38:
38:
38:
39:
39:
8:
9:
8
57
- 1
15
13
15
47
53
47
28
35
37
42
50
38
31
35
14
17
5
10
13
16
38
39
44
44
44
51
45
57
9
16
0
2
1
12
19
28
57
1
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
N
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
N
Y
Y
N
N
Y
N
: PAHX.TRG
: 24-AUG-98
: PAHX081998U.RRF
ng/ Rec/
SAMPLE MDL
1.00 50.00
1.25 30.35 61
1.05 409.25 0.000
0.77 492.50 0.000
1.55 38.67 77
0.86 22.14 0.000
0.88 40.17 80
0.93 149.40 0.000
1.00 50.00
1.13 31.01 62
1.05 424.18 0.000
2.63 38.65 77
0.84 1624.04 0.000
0.83 0.00 0.000
1.00 50.00
0.80 56.69 113
1.04 153.96 0.000
0.81 55.28 111
1.11 416.28 0.000
0.65 75.59 151
1.06 122.30 0.000
0.85 62.47 125
0.97 377.90 0.000
1.00 50.00
0.63 53.10 106
1.07 48.02 0.000
0.90 50.43 101
1.16 32.69 0.000
0.75 46.44 93
1.46 32.62 0.000
1.02 16.06 0.000
0.61 44.87 90
1.62 83.96 O.QOO
0.71 58.87 118
0.61 0.00 0.000
0.44 61.94
1.11 2.37 0.
0.63 0.00 0
0.99 *NoINoIs
1.00 50.00
0.98 0.00 0
-------
25-AUG-1998 09:34:36 AM PAH Unknown RESULTS
dlO-Fluorene 74490000 1.00 Y 16: 28 Y 1.00 50.00
13C-Fluorene 52979000 1.00 Y 16: 34 Y 0.76 46.91 94
231
-------
240
-------
WWW
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3
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• m en
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•«»>
-------
FiIe:24AU98U #1-476 Acq:25-AUG~1998 02:07:07 GC EI+ Voltage SIR Autospec-Ultima
Sample#12 Text:300681-8 :T-MM5-FB-F :Tra Exp:PAHAIR
152.0626 S:12 SMO(1,3) PKD(5,3,3,0.10%,5000.0,0.00%>F,T)
100 %
A4.90E6
"-1—r—i < 1 ' ' r—' ' ' ' ' r—' ' ' ' ' [ ' ' ' "
13:54 14:00 14:06 14:12
160.1128 S:12 SMO(1,3) PKD(5,3,3,0.10%,5000.0,0.00%,F,T)
14:
14:2
14:3
IOCS
90 J
80
70_
60 J
50
40J
30 J
20
10
0
A7.65E7
13:54
14
I
:00
14:
I
:06
14:i2
14:
14:30
14:36
-O.OEO
Time
2.2E7
2.0E7
1.8E7
1.6E7
1.1E7
9.0E6
-6.7E6
4.5E6
2.2E6
O.OEO
Time
-------
File:24AU98U #1-476 Acq:25-AUG-1998 02:07:07 GC EI+ Voltage SIR Autospec-UItima
Sample#12 Text:300681-8 :T-MM5-FB-F :Tra Exp:PAHAIR
130.9!
100 S
95 J
90-
85 1
15-
70 J
65-
60l
55-
50 J
45 J
40.:
35 J
30 J
25 J
20J
15.:
10^
5J
0 "
»20 S:12 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
n /\ A
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A1.55E9 ^ A A
A1.18E9
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9:dfl 10:6o ll:6o 12:6o 13:00 14:6o 15:00
_1.5E8
-1.4E8
-1.3E8
_1.2E8
-1.2E8
L1.1E8
-1.0E8
-9.5E7
-8.8E7
_8.1E7
-7.3E7
-6.6E7
_5.9E7
-5.1E7
_4.4E7
_3.7E7
_2.9E7
12.2E7
Ll.5E7
L7.3E6
1 O.OEO
Time
-------
File:24AU98U #1-666 Acq:25-AUG-1998 02:07:07 GC EI+ Voltage SIR Autospec-UItima
Sample#12 Text:300681-8 :T-MM5-FB-F :Tra Exp:PAHAIR
166.0798 S:12 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100
90
80
70-
60-
50-
40J
30 J
20
10 J
A1.10E8
I—i i r i i I—i—i—r-i—i I i i I' I i I i iT*! i I i i' I i i i**f~i—i TH I T r i i i i i i' i i i* I i i i 'I i i I i Pi i T^r*
15:48 16:00 16:12 16:24 16:36 16:48 17:00 17:12 17:24 17:36 17:48
172.0984 S:12 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
18
i-00
18:12
100
90
80 J
70 J
60 J
50 J
40 J
30 J
20 J
10 J
0
A2.65E7
.1.0E7
.9.3E6
8.3E6
.7.2E6
6.2E6
5.2E6
4.1E6
.3.1E6
.2.1E6
1.0E6
O.OEO
Time
15:48 16:00 16:12 16:24 16:36 16:48 17:00 17:12 17:24 17:36 17:48
176.1410 S:12 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 % A3.72E7
90
80.
60 J
50 J
40J
30 J
20 J
10J
18:6fl 18:12 18:24
-H—i—i—i—i—i—i—|—i—i—i—i—i—I—i—i—i—i—i—pT—r—i—i i i I i—i I i 1 i i i i—i—r—T—i—i—r—i—r—i—i—i—i—i—r—i—i—i—i—i—i r*i—i—i—i—i—i—i—i—i—i—i i i—i—I—i—r—r
15:48 16:00 16:12 16:24 16:36 16:48 17:00 17:12 17:24 17:36 17:48 18:60 18:12
:24
1.3E7
E.1.1E7
L9.9E6
L8.5E6
L7.1E6
5.7E6
L4.3E6
2.8E6
1.4E6
O.OEO
Time
18
-------
cv*
FiIe:24AU98U #1-666 Acq:25-AUG-1998 02:07:07 GC EI+ Voltage SIR Autospec-Ultima
Sample#12 Text:300681-8 :T-MM5-FB-F :Tra ExprPAHAIR
l/O.U
100 S
90_
80.:
70 J
60 -i
50 j
40J
30 J
20 J
10 J
OJ
18:
188.1
100 S
90-
80_
70 1
60 '-
50 J
40J
30 J
20 J
10 J
oJ
18:
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p A9.84E8
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1
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410 S:12 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
9 A1.08E8
1
)0 19:00
A5.32
1
11
'
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20:00 21:00 22:1
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20:00 21:bO 22:(
3.7E8
-3.4E8
L3.0E8
.2.6E8
:2.2E8
.1.9E8
-1.5E8
-1.1E8
-7.SE7
-3.7E7
O.OEO
)0 Time
4.3E7
:3.9E7
-3.5E7
-3.0E7
-2.6E7
_2.2E7
_1.7E7
_1.3E7
_8.7E6
_4.3E6
: O.OEO
10 Time
-------
File:24AU98U #1-666 Acq:25-AUG-1998 02:07:07 GC EI+ Voltage SIR Autospec-UItima
Sample#12 Text:300681-8 :T-MM5-FB-F :Tra Exp:PAHAlR
178.0782 S:12 F:2 SMO(1,3) PKD(5,3,3,0.10%,5000.0,0.00%,F,T)
100!
90_
80
70-
60_
50
40
30
20_
10-
0
A5.99E7
A4.59E7
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_3.6E7
_3.2E7
2.9E7
-2.SE7
L2.1E7
-1.8E7
1.4E7
U.1E7
7.1E6
3.6E6
.O.OEO
Time
19:44 19:45 19:46 19:47 19:48
188.1410 S:12 F:2 SMO(1,3) PKD(5,3,3,0.10%,5000.0,0.00%,F,T)
A5.32
90
80 j
70 j
60-
50
40
30
20-
10 J
0.
19:49
19:5
19:52
19:*
19:S
19:44
19:45
19:46
19:47
19:48
19:49
19:50
19:51
19:52
19:53
19:54
1.8E7
L1.6E7
L1.4E7
L1.3E7
L1.1E7
L8.9E6
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3.6E6
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Time
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File:24AU98U #1-934 Acq:25-AUG-1998 02:07:07 GC EI+ Voltage SIR Autospec-Ultlma
Sample#12 Text:300681-8 :T-MM5-FB-F :Tra Exp:PAHALR
202.0782 S:12 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
0 , , , , , , , , , , r
22:60 23:00 24:60
212.1410 S:12 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
90
80 J
70 J
60
50 J|
40
30
20
10 J
A9.17E7
A9.01E7
_1.6E8
.1.5E8
-1.3E8
-1.1E8
,9.8E7
_8.2E7
-6.5E7
-4.9E7
.3.3E7
-1.6E7
.O.OEO
Time
.1.1E9
.9.7E8
8.6E8
.7.5E8
.6.4E8
5.4E8
4.3E8
3.2E8
2.1E8
1.1E8
O.OEO
Time
22:00 23:00 24:00
244.1974 S:12 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
80 J
70 J
60 J
50 J
40J
30 J
20 J
10 J
OJ
26:00
22:
)0
23:00
24:6o
25:00
26:00
-------
File:24AU98U #1-934 Acq:25-AUG-1998 02:07:07 GC EI+ Voltage SIR Autospec-Ultima
Sample#12 Text:300681-8 :T-MM5-FB-F :Tra Exp:PAHAIR
202.0782 S:12 F:3 SMO(1,3) PKD(5,3,3,0.10%,5000.0,0.00%,F,T)
IOCS
A4.24E7 A5.88E7
A2.42E7
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23:60 23:66 23:12 23:18 23:24 23:30 23:36 23:42 23:48 23:54 24:00 24:06 24:12 24:18 24:24 24:30 24:36
212.1410 S:12 F:3 SMO(1,3) PKD(5,3,3,0.10%,5000.0,0.00%,F,T)
100S.
90 J
80
70 j
60
50.:
40-:
30
20
10
A9.17E7
A9.01E7
i i I i i i i i I I i i i i i I I I i i i i i I i i i i i i i i i i i i i I i i i I i i i i i i i i r i i i i I i i i i I | i i i i i i i i i i i I i
23:00 23:06 23:12 23:18 23:24 23:30 23:36 23:42 23:48 23:54 24:6fl 24:06 24:12 24:18 24:24 24:30 24:36
O.OEO
Time
3.5E7
3.2E7
2.8E7
2.5E7
2.1E7
1.8E7
.1.1E7
.7.1E6
.3.5E6
.O.OEO
Time
-------
File:24AU98U #1-934 Acq:25-AUG-1998 02:07:07 GC EI+ Voltage SIR Autospec-Ultima
Sample#12 Text:300681-8 :T-MM5-FB-F :Tra ExprPAHAIR
228.0939 S:12 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
o
10
cv
' I I I I I I ' I I I I I I I I I I I I I I I I I I I I I 1 I I 1 I 1 I I I I I I I I I I I I 1 I I 1 1 I I I I I I I I I 1 I I I I I I I I
26:36 26:48 27:00 27:12 27:24 27:36 27:48 28:00 28:12 28:24 28:36 28:48 29:
240.1692 S:12 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
O.OEO
29:ii 29:24 29:36 29:48 30:00 Time
100
90 -
80 J
70.;
60
50 j
40.:
30 j
20 J
A1.Q7E8
3.6E7
L3.2E7
-2.9E7
-2.5E7
-2.2E7
1.8E7
il.4E7
Ll.lE?
7.2E6
3.6E6
~i i""i-in i"T i I t i i i i~v r~i—i • r-r i I~T- i ~r-1 i i r i I—T PT I-T i-r1! T't'r-i i—r 1-1 i i t i i i ri i T-i-r-i -ri •[ r i i i i i i i i r-'i pr r-1 i-i'pi i t i i r~r i-i-i 1-1 t i i i i i i T r i T
26:36 26:48 27:00 27:12 27:24 27:36 27:48 28:00 28:12 28:24 28:36 28:48 29:6o 29:12 29:24 29:36 29:48 30:
O.OEO
0 Time
-------
File:24AU98U #1-934 Acq:25-AUG-1998 02:07:07 GC EI+ Voltage SIR Autospec-Ultima
Sample#12 Text:300681-8 :T-MMS-FB-F :Tra ExprPAHAIR
228.0939 S:12 F:3 SMO(1,3) PKD(5,3,3,0.10%,5000.0,0.00%,F,T)
100 % A2.C
" -*-r -I -i i i" i i — i • T- i • 'irr7 t r—r—i—i—i—i—i—i—i—i—i—i—i—t—i—i—t—i—i—i—i—i—<—i—i—i—i—i i—( i T—T i i r i i i i 'r ' '' ' ' | '
27:42 27:48 27:54 28:6o 28:66 28:12 28:18 28:24 28:30 28:36 28:42
28:48
240.1692 S:12 F:3 SMO(1,3) PKD(5,3,3,0.10%,5000.0,0.00%,F,T)
1002
90 J
80
60,:
50 j
40
30_
20_
10
A9.90E7
A1.07E8
'28:54
O.OEO
Time
-3.6E7
L3.2E7
L2.9E7
L2.5E7
2.2E7
-1.8E7
1.4E7
7.2E6
0 -I——— - '" .,.,,.',,,.,,, "TT1 TTTTTT", .,,,,,,,,.,,,,,.... , T ^-0-OEfl
27:52 ' '27:48 '27:54 '28:bfl' 28:06 ' 28:b' 28:18 28:24 ' 28:30 28:36 28:42 28:48 28:54 Time
-------
Flle:24AU98U #1-934 Acq:25-AUG-1998 02:07:07 GC EI+ Voltage SIR Autospec-Ultima
Sample#12 Texf.300681-8 :T-MM5-FB-F :Tra Exp:PAHAlR
230.9856 S:12 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
10
CM
100 S
95J
90 j
85 J
80 1
75 1
70-
65 J
60 1
55 1
50 J
45 1
40J
35 J
30 J
25 1
20 J
15
10J
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A
A
/I
4.8C
ff1
IE8
IV
iff
f
A
rVy
rf
1 r*
A
A
IL8.4E7
L7.9E7
E.7.5E7
23:00 24:6fl 25:00 26:bo 27:6o 28:6o 29:00 30:
L7.0E7
L6.6E7
L6.2E7
L5.7E7
:5.3E7
-4.8E7
L4.4E7
-4.0E7
L3.5E7
-3.1E7
L2.6E7
L2.2E7
L.1.8E7
Ll.3E7
L8.8E6
4.4E6
O.OEO
)0 Time
-------
Flle:24AU98U #1-955 Acq:25-AUG-1998 02:07:07 GC EI+ Voltage SIR Autospec-Ultima
Sample#12 Text:300681-8 :T-MM5-FB-F :Tra Exp:PAHAIR
252.0939 S:12 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
10
30:00 31:00 32:00
264.1692 S:12 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
90
80
70_
60 J
50
40
30
20
10 J
0
30:
A1.01E8
A6.69E7
A5.55E7
00
31:60
32:t
33
:60
34:0
O.OEO
Time
.2.4E7
.2.2E7
.1.9E7
.1.7E7
.1.4E7
.1.2E7
.9.6E6
.7.2E6
4.8E6
2.4E6
O.OEO
Time
-------
File:24AU98U #1-955 Acq:25-AUG-1998 02:07:07 GC EI+ Voltage SIR Autospec-Ultima
Sample#12 Text:300681-8 :T-MM5-FB-F :Tra Exp:PAHAIR
252.0939 S:12 F:4 SMO(1,3) PKD(5,3,3,0.10%>5000.0,0.00%,F,T)
31:i8 31:24 31:30 31:36 31:42 31:48
264.1692 S:12 F:4 SMO(1,3) PKD(5,3,3>0.10%,5000.0,0.00%,F,T)
O.OEO
8 Time
31:18 31:24 31:30 31:36
31:42
31:48
-I 1 1 1 1 1 1 1 1 1 1 1 r—1I [ i I I I 1 I r
31:54 32:00 32:06 32:12
O.OEO
32:18 Time
-------
File:24AU98U #1-955 Acq:25-AUG-1998 02:07:07 GC EI+ Voltage SIR Autospec-Ultima
Sample#12 Text:300681-8 :T-MM5-FB-F :Tra Exp:PAHAIR
252.0939 S:12 F:4 SMO(1,3) PKD(5,3,3,0.10%,5000.0>0.00%,F,T)
100 % ' A4.1.7E7
90
804
70
60 j
50 -
A1.68E7
30
20 1
A6.03E6
A2.85E6
A3.75E6
A2.43E6
A2.62E6 A2.36E6
33:66 ' 33:li ' ' 33:^8 33:24 ' ' 33:30 ' ' 33:36 ' ' 33:42 ' 33:48 ' 33:54 '
9.8E6
8.9E6
7.9E6
-6.9E6
-5.9E6
-4.9E6
L3.9E6
3.0E6
-2.0E6
L9.8E5
O.OEO
Time
v ' r iiti r-"i i i l "i i i l i i l f i r1 r i i r i i T i i i i i i i i i i~t—r-i"-|-| i i I i
32:18 32:24 32:30 32:36 32:42 32:48 32:54 33:00
264.1692 S:12 F:4 SMO(1,3) PKD(5,3,3,0.10%,5000.0,0.00%,F,T)
100 % Al.C
90
804
70
604
50
40
30-
20 J
10 J
.01E8
A5.55E7
^2.4E7
-2.2E7
_1.9E7
-1.7E7
_1.4E7
-1.2E7
9.6E6
17.2E6
4.8E6
L2.4E6
^r^r.. , , , , ., . ,.,^-y—,-. T-r-.r-T. .,.,., .-.., 7—, , , , ,—J-T—i i-1 i i i i r i—i I i i i' i T-r-T-r"r~i""> I ' i I-I-T~'[ i~i~i r r~i i r-r "i r~r T t-i-i"i^i T -r i i i T "i—r"r i T~ r r r i i '"'I ' i
32:18 32:24 32:30 32:36 32:42 32:48 32:54 33:00 33:06 33:12 33:18 33:24 33:30 33:36 33:42 33:48 33:54
lO.OEO
Time
-------
40
File:24AU98U #1-955 Acq:25-AUG-1998 02:07:07 GC EI+ Voltage SIR Autospec-Uttima
Sample#12 Text:300681-8 :T-MM5-FB-F :Tra Exp:PAHAIR
288.1692 S:12 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 % A8.3J8E7
/O.wyjy a:** r:i amwni,j; ri\jj^,j,j,u.iv /c,ivvuv.v,u.uv
00%
80 J
60 J
40J
7,0
0-
36:
A1.ME7 F1.3E«
A
A2.06E6 1 \
A6.44E4 A7.67E5 J
( j ? ( j , , , , , . ..... .
HI 37:1)0 38:00
V, A4.28E4 7 ^^_
39:00 40:6fl 41:6o 42:1
L1.0E6
L7.7E5
L5.1E5
L2.6E5
LO.OEO
)0 Til
O.OEO
)0 Time
00 5
80 J
60 J
401
20 J
36:
,7/T LJl'-Af i «^ kJATAV'X-M-Jfc'^ » *.*-»^\*^J*'J*7)V* AV /*/J*WWW*VjV. W /VJi J *,/
A5.50E7
A
\
| \
I V
y — .
(0 37:60 38:00 39:00 40:00 41:60 42:1
6.1E6
L4.8E6
L3.6E6
L2.4E6
Ll.2E6
O.OEO
}0 Time
-------
File:;
Samj
268.9
100 S
90
80-
70-
60 J
50 J
40J
30 j
20 J
10 J
0:
30:i
280.9
100 S
90 J
sol
70 1
60-
50 J
40 j
30 -
20 J
10 J
0:
30:1)
,4AU98U #1-955 Acq:25-AUG-1998 02:07:07 GC EI+ Voltage SIR Autospec-Ultima
»le#12 Text:300681-8 :T-MM5-FB-F :Tra Exp:PAHAIR
824 S:12 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
0 ' '31:6o 32:6o ' ' 33:6o ' 34:6o 35:6o 36:6o 37:6o 38:6o 39:6o 40:6o 41:00 42:
J24 S:12 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
' A286E7 A6.06E7 A5.69E7 A1.25E8 A3-3^17
^ A xv^vv^ ^ XT\/^>-A, ^/WN^/vVYXn^Vn^rrSYV^VvxA^r^VYyVt^^^^
fnrmmirm^
0 '31:00 32:60 33:6o 34:6fl 35:6fl 36:6o 37:6fl 38:6o 39:6fl 40:6o '41:00 42:C
40
A*
1.5E7
1.3E7
L1.2E7
11.0E7
L9.0E6
_7.5E6
.6.0E6
-4.5E6
-3.0E6
L1.5E6
O.OEO
»0 Time
5.5E7
L4.9E7
L4.4E7
L3.8E7
L3.3E7
L2.7E7
-2.2E7
L1.6E7
-1.1E7
-5.5E6
O.OEO
0 Time
-------
02-SEP-1998 07:36:11 PM Dioxin Furan Unknown RESULTS
GC Column : DB-5
Data file : 24AU98U
Weight : 0.333
Name
dlO-2-Methylnaphthalene
d8-Naphthalene
Naphthalene
2-Methylnaphthalene
d8-Acenaphthylene
Ac enaphthy1ene
dlO-Acenaphthene
Acenaphthene
dlO-Anthracene
dlO-Fluorene
Fluorene
dl0-Phenanthrene
Phenanthrene
Anthracene
d!2-Benzo(e)pyrene
dlO-Fluoranthene
Fluoranthene
dl0-Pyrene
Pyrene
d!2-Benzo(a)anthracene
Benzo(a)anthracene
d!2-Chrysene
Chrysene
d!2-Benzo(e)pyrene
d!2-Benzo(b)fluoranthene
Benzo(b)fluoranthene
d!2-Benzo(k)fluoranthene
Benzo(k)fluoranthene
dl2-Benzo(a)pyrene
Benz o(e)pyrene
Benz o (a)pyrene
d!2-Perylene
Perylene
d!2-Indeno(123-cd)pyrene
Indeno(12 3-cd)pyrene
d!4-Dibenz(ah)anthracene
Dibenz(ah)anthracene
d!2-Benzo(ghi)perylene
Benzo(ghi)perylene
d8-Naphthalene
13C-Naphthalene
Results : 24AU98U131.RES
Date analyzed
300681-9 :T-MM5-RB-F :Tra Ex Cal
Total Isotope R. T. RRF
Response Ratio mm:ss
113045000 1.00 Y
8'2611800 1.00 Y
156143800 1.00 Y
60369000 1.00 Y
123628200 1.00 Y
4333480 1.00 Y
73728400 1.00 Y
17222860 1.00 Y
79508400 1.00 Y
56298800 1.00 Y
17037640 1.00 Y
157294800 1.00 Y
97862800 1.00 Y
6840000 1.00 Y
203564000 1.00 Y
139915800 1.00 Y
25211800 1.00 Y
144803200 1.00 Y
18780600 1.00 Y
183998400 1.00 Y
1364272 1.00 Y
219514000 1.00 Y
6599460 1.00 Y
203564000 1.00 Y
134007000 1.00 Y
1586000 1.00 Y
186158600 1.00 Y
838000 1.00 Y
142422000 1.00 Y
1700000 1.00 Y
830000 1.00 Y
112626400 1.00 Y
1316000 1.00 Y
173347200 1.00 Y
400000 1.00 Y
107648800 1.00 Y
* No Peak 0.00 N
152800000 1.00 Y
1308000 1.00 Y
82611800 1.00 Y
* No Peak 0.00 N
PAHX.TRG
24-AUG-98
PAHX081998U.RRF
ng/ Rec/
SAMPLE MDL
11:
8:
9:
11:
14:
14:
14:
14:
19:
16:
16:
19:
19:
19:
32:
23:
23:
24:
24:
28:
28:
28:
28:
32:
31:
31:
31:
31:
32:
32:
32:
33:
33:
38:
38:
38:
38:
39:
39:
8:
9:
9
57
1
16
14
16
47
53
47
29
35
38
42
50
39
32
36
14
18
6
11
13
18
39
40
45
45
45
51
45
57
10
16
1
4
2
10
20
29
57
1
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
N
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
N
Y
Y
Y
N
1
1
1
0
1
0
0
0
1
1
1
2
0
0
1
0
1
0
1
0
1
0
0
1
0
1
0
1
0
1
1
0
1
0
0
0
1
0
0
1
0
.00
.25
.05
.77
.55
.86
.88
.93
.00
.13
.05
.63
.84
.83
.00
.80
.04
.81
.11
.65
.06
.85
.97
.00
.63
.07
.90
.16
.75
.46
.02
.61
.62
.71
.61
.44
.11
.63
.99
.00
.98
50
29
269
142
35
6
37
37
50
31
43
37
110
7
50
42
26
43
17
69
1
63
4
50
52
1
51
0
46
1
0
45
1
60
0
59
.00
.33
.45 *£
.36 §
.28
59
71
.10=DL
.17
.72 «Pj
.00
.35
.28
.63
.93 e>
.88=DL
.00
.78
.00 £
.93
.59 ££
.50
.06=DL
.57
-65=DL
.00
.58
.66=DL
.03
.58=DL
.57
.22=DL
.85=DL
.02
.08=DL
.26
-57=DL
.94
74
I
63
75
86
88
,uuSO
139
127
105
102
93
90
121
120
EDL=0.31
59
1
50
0
CA t
• ~J " jf
.30=DC
.00
.00
1*9;
-------
02-SEP-1998 07:36:11 PM Dioxin Furan Unknown RESULTS
dlO-Fluorene 56298800 1.00 Y 16: 29 Y 1.00 50.00
13C-Fluorene 48381200 1.00 Y 16: 35 Y 0.76 56.69 113
-------
02-SEP-1998 07:36:09 PM Dioxin Furan Unknown RESULTS
24AU98U131.RES
Date analyzed
MM5-RB-F :Tra Ex Cal
Isotope R. T. RRF
Ratio mm:ss
PAHX.TRG
24-AUG-98
PAHX081998U.RRF
. ng/ Rec/
SAMPLE MDL
0.333
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
0.00
1.00
1.00
1.00
0.00
Y
y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
N
Y
Y
Y
N
11:
8:
9:
11:
14:
14:
14:
14:
19:
16:
16:
19:
19:
19:
32:
23:
23:
24:
24:
28:
28:
28:
28:
32:
31:
31:
31:
31:
32:
32:
32:
33:
33:
38:
38:
38:
38:
39:
39:
8:
9:
9
57
1
16
14
16
47
53
47
29
35
38
42
50
39
32
36
14
18
6
11
13
18
39
40
45
45
45
51
45
57
10
16
1
4
2
10
20
29
57
1
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
N
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
N
Y
Y
Y
N
1
1
1
0
1
0
0
0
1
1
1
2
0
0
1
0
1
0
1
0
1
0
0
1
0
1
0
1
0
1
1
0
1
0
0
0
1
0
0
1
0
.00
.25
.05
.77
.55
.86
.88
.93
.00
.13
.05
.63
.84
.83
.00
.80
.04
.81
.11
.65
.06
.85
.97
.00
.63
.07
.90
.16
.75
.46
.02
.61
.62
.71
.61
.44
.11
.63
.99
.00
.98
50
29
269
142
35
6
37
37
50
31
43
37
110
7
50
42
26
43
17
69
1
63
4
50
52
1
51
0
46
1
0
45
1
60
0
59
.00
.33
.45
.36
.28
59
71
.10=DL
.17
.72
.00
.35
.28
.63
.93
.88=DL
.00
.78
.00
.93
.59
.50
.06==DL
.57
.65=DL
.00
.58
.66=DL
.03
.58=DL
.57
.22=DL
.85=DL
.02
.08=DL
.26
.57=DL
.94
74
63
75
86
88
139
127
105
102
93
90
121
120
EDL=0.31
59
1
50
0
.54
.30=DL
.00
.00
119
0
56522500
41305900
78071900
30184500
61814100
2166740
36864200
8611430
39754200
28149400
8518820
78647400
48931400
3420000
101782000
69957900
12605900
72401600
9390300
91999200
682136
109757000
3299730
101782000
67003500
793000
93079300
419000
71211000
850000
415000
56313200
658000
86673600
200000
53824400
0
76400000
654000
41305900
0
56522500
41305900
78071900
30184500
61814100
2166740
36864200
8611430
39754200
28149400
8518820
78647400
48931400
3420000
101782000
69957900
12605900
72401600
9390300
91999200
682136
109757000
3299730
101782000
67003500
793000
93079300
419000
71211000
850000
415000
56313200
658000
86673600
200000
53824400
0
76400000
654000
41305900
0
260
-------
02-SEP-1998 07:36:09 PM Dioxin Furan Unknown RESULTS
1.00 Y 16: 29 Y 1.00 50.00 28149400 28149400
1.00 Y 16: 35 Y 0.76 56.69 113 24190600 24190600
-------
25-AUG-1998 09:35:45 AM
PAH Unknown RESULTS
Mass Spec ULTIMA
GC Column DB-5
Data file 24AU98U
Weight : 0.333
Name
dlO-2-Methylnaphthalene
d8-Naphthalene
Naphthalene
2-Methylnaphthalene
d8-Acenaphthylene
Acenaphthylene
dlO-Acenaphthene
Acenaphthene
dlO-Anthracene
dlO-Fluorene
Fluorene
dl0-Phenanthrene
Phenanthrene
Anthracene
d!2-Benzo(e)pyrene
dlO-Fluoranthene
Fluoranthene
dlO-Pyrene
Pyrene
d!2-Benzo(a)anthracene
Benzo(a)anthracene
dl2-Chrysene
Chrysene
dl2-Benzo(e)pyrene
d!2-Benzo(b)fluoranthene
Benzo(b)fluoranthene
d!2-Benzo(k)fluoranthene
Benzo(k)fluoranthene
dl2-Benzo{a)pyrene
Benzo(e)pyrene
Benzo(a)pyrene
d!2-Perylene
Perylene
d!2-Indeno(123-cd)pyrene
Indeno(12 3 -cd)pyrene
d!4-Dibenz(ah)anthracene
Dibenz(ah)anthracene
d!2-Benzo(ghi)perylene
Benzo(ghi)perylene
d8-Naphthalene
13C-Naphthalene
Results : 24AU98U131.RES
Date analyzed
300681-9 :T-MM5-RB-F :Tra Ex Cal
Total Isotope R. T. RRF
Response Ratio mm:ss
PAHX.TRG
24-AUG-98
PAHX081998U.RRF
ng/ Rec/
SAMPLE MDL
*
*
*
*
*
*
113045000
82611800
156143800
60369000
123628200
4333480
73728400
17222860
79508400
56298800
17037640
157294800
97862800
No Peak
203564000
139915800
25211800
144803200
18780600
183998400
1364272
219514000
6599460
203564000
134007000
2372980
186158600
2372980
142422000
1475188
784302
112626400
1310596
173347200
No Peak
107648800
No Peak
No Peak
No Peak
82611800
No Peak
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
0.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
0.00
1.00
0.00
0.00
0.00
1.00
0.00
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
N
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
N
Y
N
N
N
Y
N
11:
8:
9:
11:
14:
14:
14:
14:
19:
16:
16:
19:
19:
19:
32:
23:
23:
24:
24:
28:
28:
28:
28:
32:
31:
31:
31:
31:
32:
32:
32:
33:
33:
38:
38:
38:
38:
39:
39:
8:
9:
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13
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0
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0
-------
25-AUG-1998 09:35:45 AM
PAH Unknown RESULTS
dlO-Fluorene
13C-Fluorene
56298800 1.00 Y
48381200 1.00 Y
16: 29 Y
16: 35 Y
1.00
0.76
50.00
56.69
113
262
-------
File:24AU98.U #1-476 Acq:25-AUG-1998 02:53:36 GC
CO
EI+ Voltage SIR Autospec-Ultima r\>
Sample#13 Text:300681-9 :T-MM5-RB-F :Tra Exp:PAHAIR
128.0626 S:13 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.
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-------
FiIe:24AU98U #1-476 Acq:25-AUG-1998 02:53:36 GC EI+ Voltage SIR Autospec-UItima
Sample#13 Text:300681-9 :T-MM5-RB-F :Tra ExprPAHAIR
152.0626 S:13 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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154.0782 S:13 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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80
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0
-------
File:24AU98U #1-476 Acq:25-AUG-1998 02:53:36 GC EI+ Voltage SDR Autospec-Ultima
Sample#13 Text:300681-9 :T-MM5-RB-F :Tra Exp:PAHAIR
isu.y
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Time
-------
File:24AU98U #1-666 Acq:25-AUG-1998 02:53
Sample#13 Text:300681-9 :T-MM5-RB-F :Tra
CO
:36 GC EI+ Voltage SIR Autospec-Ultima C\J
Exp:PAHAIR
166.0798 S:13 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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-------
<£>
File:24AU98U #1-666 Acq:25-AUG-1998 02:53:36 GC E1+ Voltage SIR Autospec-UItima
Sample#13 Text:300681-9 :T-MM5-RB-F :Tra Exp:PAHAER
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-------
FiIe:24AU98U #1-666 Acq:25-AUG-1998 02:53:36 GC EI+ Voltage SIR Autospec-UItima
Sample#13 Text:300681-9 :T-MM5-RB-F :Tra Exp:PAHAlR
178.0782 S:13 F:2 SMO(1,3) PKD(5,3,3,0.10%,5000.0,0.00%,F,T)
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O.OEO
Time
-------
File:24AU98U #1-666 Acq:25-AUG-1998 02:53:36 GC EI+ Voltage SIR Autospec-Ultima
Sample#13 Text:300681-9 :T-MM5-RB-F :Tra ExprPAHAIR
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-------
File:24AU98U #1-934 Acq:25-AUG-1998 02:53:36 GC EI+ Voltage SIR Autospec-UItima
Sample#13 Text:300681-9 :T-MM5-RB-F :Tra Exp:PAHAIR
202.0782 S:13 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
CM
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212.1410 S:13 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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-------
File:24AU98U #1-934 Acq:25-AUG-1998 02:53:36 GC EI+ Voltage SIR Autospec-Ultima
Sample#13 Text:300681-9 :T-MM5-RB-F :Tra Exp:PAHAIR
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-------
Be
-------
File:24AU98U #1-955 Acq:25-AUG-1998 02:53:36 GC EI+ Voltage SIR Autospec-UHima
Sample#13 Text:300681-9 :T-MM5-RB-F :Tra Exp:PAHAIR
252.0939 S:13 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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30:00 31:00 32:i
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33:00
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Time
-------
File:24AU98U #1-955 Acq:25-AUG-1998 02:53:36 GC EI+ Voltage SIR Autospec-Ultima
Sample#13 Text:300681-9 :T-MM5-RB-F :Tra Exp:PAHAIR
252.0939 S:13 F:4 SMO(1,3) PKD(5,3,3,0.10%,5000.0,0.00%,F,T)
100 % A7.93E5
90 J
80 j
70
60
50 J
40
30 -
20 j
10
Od
10
r-
CM
31:12 31:i8 31:24 31:30 31:36 31:42 31:48 31:54 32:00 32:66 32:i2 32:i8
264.1692 S:13 F:4 SMO(1,3) PKD(5,3,3,0.10%,5000.0,0.00%,F,T)
A6.7.0E7
. , A9.31E7
90 JJ
80
70 J
60
50-
40J
30 J
20
10
0
2.6E5
12.4E5
2.1E5
-1.9ES
1.6E5
1.3E5
il.OES
L7.9E4
-5.2E4
-2.6E4
O.OEO
Time
1.8E7
1.6E7
1.4E7
L1.3E7
L1.1E7
L9.0E6
7.2E6
5.4E6
3.6E6
1.8E6
O.OEO
Time
31:1
31:1
31
"T"1 ' ' ' ' I i i i "i i—i i i i i i r i—i—i—i—i—i—i—i—i i i i i i i i i
:24 31:30 31:36 31:42 31:48 31:54 32:
I' I 'I I ["'T"
32:66
32
|— r
:12
32:1
-------
File:24AU98U #1-955 Acq:25-AUG-1998 02:53:36 GC E1+ Voltage SIR Autospec-Ultima
Sample#13 Text:300681-9 :T-MM5-RB-F :Tra Exp:PAHAIR
252.0939 S:13 F:4SMO(1,3) PKD(5,3,3,0.10%,5000.0,0.00%,F,T)
CM
—r—i—i—i—r—i—r—i—i—r—i—i—|—i—i—r
32:24 32:36 32:48
264.1692 S:13 F:4SMO(1,3) PKD(5,3,3,0.10%,5000.0,0.00%,F,T)
J3:i)0
33
33:1
33:24
-i 1—r—i
33:36
33:48
100 S.
90 j
80.:
70 j
60-
50 1
40 J
30 j
20 J
10 J
o
A1.02E8
A5.63E7
_r_O.OEO
34:00 Time
2.1E7
1.9E7
1.6E7
1.4E7
H.2E7
9.4E6
H-7.1E6
4.7E6
12.4E6
O.OEO
Time
32:
32:48
33:t
33:1
33:24'
J3:36
33
33:48
-------
File:24AU98U #1-955 Acq:25-AUG-1998 02:53:36 GC EI+ Voltage SIR Autospec-Ultima
Sampled Text:300681-9 .-T-MM5-RB-F :Tra Exp:PAHAIR
276.0939 S:13 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 % A4.
80 j
60
40
20 J
41:60
CM
LIES
L8.8E4
-6.6E4
L4.4E4
L2.2E4
.O.OEO
)0 Time
36:00 ~" ' '' 37:60 ' ' ' 38:6o
39
:00
40:0
278.1096 S:13 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
42:
AOO.l
100 S
80 J
60 J
40J
20 J
36:i
\)7£, L7.J..7 r-."» O1V1W\J.).?S i J»A/V^jJjJjV.J.V YPjJ.VVVU«U}V«UV /»>* J *J
p A8.67E7
A A7.64E7
\ 1 \
1 \ 1 \
IV / V
/ \-~_ J ^-_^
)0 37:00 38:00 j >-39:00 40:60 41:00 42:
9.2E6
L7.3E6
15.5E6
-3.7E6
L1.8E6
: O.OEO
)0 Time
1002
80 -
60 J
40J
20 -
36:
292.1
100 2
80 J
60-
40J
20 J
OJ
36:
P,»n. _ A^^"
/^>^'/' N^VV^^/~^/\A/ Vvv^v^ /\/"u * V-^^^1 /v-^/v yv /J\s^,\ ^x\
WVWVv^A/v--^^
K) 37:60 38:6fl 39:6fl 40:6fl 41:6o 42:
974 S:13 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0)0.00%,F>T) .
A5.38E7 C,
A
1
\
/ V__
10 37:60 38:60 39:6o 40:60 41:00 42:i
4.6E4
:3.7E4
L2.8E4
-1.9E4
-9.3E3
O.OEO
)0 Time
rs^.
4.4E6
L3.3E6
L2.2E6
:1.1E6
O.OEO
)0 Time
-------
CO
A2.00E5
Fi!e:24AU98U #1-955 Acq:25-AUG-1998 02:53:36 GC EI+ Voltage SIR Autospec-UItima
Sample#13 Text:300681-9 :T-MM5-RB-F :Tra ExprPAHAIR
276.0939 S:13 F:4 SMO(1,3) PKD(S,3,3,0.10%,5000.0,0.00%,F,T)
100%
90
80-
70
60-
50-
40-
30
20 J
10
0
A6.54E5
i—i "i-r-r r r~T t r-r~r r~ i i [ i i r i i i i i t i-T-T i 'T'T t i"r t t ( t t t t i i f f f i i t t i i "i~r-f t i r i i i i i i r r r i i f t i j i i—i • r~i t \ i I i i i t i"[ r i"T r i ~r f i~ri i -r-j~i t
37:24 37:36 37:48 38:00 38:12 38:24 38:36 38:48 39:00 39:12 39:24 39:36 39:48 40:00 40:12 40:24 40:36
1.1E5
9.9E4
8.8E4
7.7E4
6.6E4
4.4E4
3.3E4
2.2E4
O.OEO
Time
r9.2E6
L8.2E6
7.3E6
16.4E6
5.5E6
4.6E6
3.7E6
12.7E6
L1.8E6
L9.2E5
288.1692
100%
90
80:
70
60 J
50 j
40.
30
20 4
10
0
S:13 F:4 SMO(1,3) PKD(5,3,3,0.10%,5000.0,0.00%,F,T)
A8.67E7
A7.64E7
O.OEO
i i i i i i i i i i | i i "I i i i i i i i rr-r-r-r-^rT i i i i i i i | i n' i i , i i i . . i , , , , , , , , , , , , ,,,,,,,,,,, i , i i i .' V.VCM
37:24 37:36 37:48 38:00 38:12 38:24 38:36 38:48 39:00 39:12 39:24 39:36 39:48 40:00 40:12 40:24 40:36 Time
-------
File:24AU98U #1-955 Acq:25-AUG-1998 02:53:36 GC EI+ Voltage SIR Autospec-UItima
Sample#13 Text:300681-9 :T-MM5-RB-F :Tra Exp:PAHAlR
268.9824 S:13 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F>T)
100%A2.54E6 A4.5£E6 A2.97E6 A1.62E6 A2.11E6
90 J
80
70 -
60 J
50-:
40
30 J
20 J
10 J
cv
A5.99E6
A4.07E6
39:60 40:6o 41:00 42:
1.3E7
-1.2E7
-9.3E6
-8.0E6
6.6E6
_5.3E6
4.0E6
_2.7E6
L1.3E6
.O.OEO
)0 Time
1-4.8E7
.L4.4E7
30:00 '31:60' 32:6o ' 33:6o 34:6o 35:00
280.9824 S:13 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
90J
801
70 J
60
50-1
40
30
20 4
10
36:60
A7.61E6
37:60 38:60
A1.49E7
ST
^
L3.9E7
3.4E7
J1.9WJ
:.2.4E7
L1.9E7
L1.5E7
:9.7E6
4.8E6
O.OEO
(0 Time
30:
10
T—I—I—I—I—I—I—I—I—I—I—i—I—I—I—I—I—I—i—i—i—i—I—i—I—I—I—i—I—i I I T I i I I I [ r-
32:00 33:60 34:00 35:00 36:00 37:00 38:60
39
^Q
40
41
42:
-------
15-OCT-1998 10:29:36 AM Dioxin Furan Unknown RESULTS
GC Column : DB-5
Data file : 050C98U
Weight : 0.00033
Name
dlO-2-Methylnaphthalene
d8-Naphthalene
Naphthalene
2-Methylnaphthalene
d8-Acenaphthylene
Acenaphthylene
dlO-Acenaphthene
Acenaphthene
dlO-Anthracene
dlO-Fluorene
Fluorene
dl0-Phenanthrene
Phenanthrene
Anthracene
d!4-Terphenyl
dlO-Fluoranthene
Fluoranthene
dlO-Pyrene
Pyrene
d!2-Benzo(a)anthracene
Benzo(a)anthracene
d!2-Chrysene
Chrysene
d!2-Benzo(e)pyrene
d!2-Benzo(b)fluoranthene
Benzo(b)fluoranthene
dl2-Benzo(k)fluoranthene
Benzo(k)fluoranthene
d!2-Benzo(a)pyrene
Benzo(e)pyrene
Benzo(a)pyrene
d!2-Perylene
Perylene
d!2-Indeno(123-cd)pyrene
Indeno(123-cd)pyrene
d!4-Dibenz(ah)anthracene
Dibenz(ah)anthracene
d!2-Benzo(ghi)perylene
Benzo(ghi)perylene
Results : 050C98U301.RES
Date analyzed
300681-10DI :1000X S-MM5-4 Ex Cal
Total Isotope R. T. RRF
Response Ratio mm:ss
PAHAIR.TRG
05-OCT-98
PAHAIR100198U.RR
ug/ Rec/
SAMPLE MDL
95034400 1.00 Y
144626200 1.00 Y
828332000 1.00 Y
1266176000 1.00 Y
133899800 1.00 Y
9160000 1.00 Y
73552600 1.00 Y
91400000 1.00 Y
62004600 1.00 Y
78009600 1.00 Y
202000000 1.00 Y
166579800 1.00 Y
666000000 1.00 Y
60000000 1.00 Y
255524000 1.00 Y
185352800 1.00 Y
10080'OQOO 1.00 Y
190982600 1.00 Y
274000000 1.00 Y
106954200 1.00 Y
23200000 1.00 Y
130870600 1.00 Y
97000000 1.00 Y
146982000 1.00 Y
94644600 1.00 Y
7300000 1.00 Y
142458400 1.00 Y
3080000 1.00 Y
105998000 1.00 Y
10380000 1.00 Y
2560000 1.00 Y
89078400 1.00 Y
14880000 1.00 Y
46754200 1.00 Y
* No Peak 0.00 N
23771000 1.00 Y
* No Peak 0.00 N
46992600 1.00 Y
* No Peak 0.00 N
10:
8:
8:
10:
13:
13:
14:
14:
19:
15:
15:
18:
18:
19:
24:
22:
22:
23:
23:
27:
27:
27:
27:
31:
30:
30:
30:
30:
31:
31:
31:
32:
32:
36:
36:
36:
36:
37:
37:
27 Y
18 Y
21 Y
34 Y
29 Y
31 Y
3 Y
10 Y
2 Y
45 Y
51 Y
52 Y
57 Y
5 Y
10 Y
46 Y
49 Y
28 Y
31 Y
20 Y
24 Y
27 Y
31 Y
40 Y
46 Y
50 Y
51 Y
50 Y
51 Y
46 Y
56 Y
8 Y
14 Y
34 Y
37 N
40 Y
45 N
50 Y
54 N
1.00 0.05
1.78 0.04
1.20 722.94
0.66 2019.54
1.16
1.02
0.68
1.14
1.00
1.36
1.15
2.74
0.95
0.97
1.00
1.49
1.23
1.58
1.26
0.81
1.28
1.17
1.16
1.00
0.48
1.30
0.99
1.20
0.74
1.62
1.11
0.65
1.74
0.37
0.60
0.20
1.28
0.41
1.11
0.06
10.12<
0.06
165.22
0.05
0.05
342.40
0.05
636.02
56.13
0.05
0.02
66.89
0.02
172.89
0.03
25.67
0.02
96.78
0.05
0.07
8.99.
0.05
2.72
0.05
9.15
3.29
0.05
14.51
0.04
0.00
0.04
0.00
0.04
0.00
85
121
113
92
98
49 wv
47
52-
44
134
98
98
94
85
80
-------
15-OCT-1998 10:29:32 AM Dioxin Furan Unknown RESULTS
050C98U301.RES
Date analyzed
rlOOOX S-MM5-4 Ex Cal
Isotope R. T. RRF
Ratio mm:ss
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
0
1
0
1
0
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
N
Y
N
Y
N
10:
8:
8:
10:
13:
13:
14:
14:
19:
15:
15:
18':
18:
19:
24:
22:
22:
23:
23:
27:
27:
27:
27:
Jl:
30:
30:
30:
30:
31:
31:
31:
32:
32:
36:
36:
36:
36:
37:
37:
27
18
21
34
29
31
3
10
2
45
51
52
57
5
10
46
49
28
31
20
24
27
31
40
46
50
51
50
51
46
56
8
14
34
37
40
45
50
54
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
N
Y
N
Y
N
1
1
1
0
1
1
0
1
1
1
1
2
0
0
1
1
1
1
1
0
1
1
1
1
0
1
0
1
0
1
1
0
1
0
0
0
1
0
1
.00
.78
.20
.66
.16
.02
.68
.14
.00
.36
.15
.74
.95
.97
.00
.49
.23
.58
.26
.81
.28
.17
.16
.00
.48
.30
.99
.20
.74
.62
.11
.65
.74
.37
.60
.20
.28
.41
.11
0
0
722
2019
0
10
0
165
0
0
342
0
636
56
0
0
66
0
172
0
25
0
96
0
0
8
0
2
0
9
3
0
14
0
0
0
0
0
.05
.04
.94
.54
.06
.12<
.06
.22
.05
.05
.40
.05
.02
.13
.05
.02
.89
.02
.89
.03
.67
.02
.78
.05
.07
.99.
.05
.72
.05
.15
.29
.05
.51
.04
.00
.04
.00
.04
0.00
PAHAIR.TRG
05-OCT-98
PAHAIR100198U.RRF
ug/ Rec/
SAMPLE MDL
85
121
113
92
98
49
47
52
44
134
98
98
94
85
80
78
0.00033
47517200
72313100
414166000
633088000
66949900
4580000
36776300
45700000
31002300
39004800
101000000
83289900
333000000
30000000
127762000
92676400
50400000
95491300
137000000
53477100
11600000
65435300
48500000
73491000
47322300
3650000
71229200
1540000
52999000
5190000
1280000
44539200
7440000
23377100
0
11885500
0
23496300
0
47517200
72313100
414166000
633088000
66949900
4580000
36776300
45700000
31002300
39004800
101000000
83289900
333000000
30000000
127762000
92676400
50400000
95491300
137000000
53477100
11600000
65435300
48500000
73491000
47322300
3650000
71229200
1540000
52999000
5190000
1280000
44539200
7440000
23377100
0
11885500
0
23496300
0
281
-------
13-OCT-1998 11:01:55 AM Dioxin Furan Unknown RESULTS
GC Column
Data file
Weight
Name
DB-5
050C98U
0.000/15
Results :
300681-10DI
Total
Response
050C98U301.RES
Date analyzed
rlOOOX S-MM5-4 Ex Cal
Isotope R. T. RRF
Ratio mmrss
PAHAIR.TRG
05-OCT-98
PAHAIR100198U.RRF
pa -eg/ Rec/
-SAMPLE MDL
dlO-2-Methylnaphthalene
d8-Naphthalene
Naphthalene
2-Methylnaphthalene
d8-Acenaphthylene
Acenaphthylene
dlO-Acenaphthene
Acenaphthene
dlO-Anthracene
dlO-Fluorene
Fluorene
dl0-Phenanthrene
Phenanthrene
Anthracene
d!4-Terphenyl
dlO-Fluoranthene
Fluoranthene
dlO-Pyrene
Pyrene
d!2-Benzo(a)anthracene
Benzo(a)anthracene
d!2-Chrysene
Chrysene
dl2-Benzo(e)pyrene
d!2-Benzo(b)fluoranthene
Benzo(b)fluoranthene
d!2-Benzo(k)fluoranthene
Benzo(k)fluoranthene
d!2-Benzo(a)pyrene
Benzo(e)pyrene
Benzo(a)pyrene
d!2-Perylene
Perylene
d!2-Indeno(123-cd)pyrene
Indeno(123-cd)pyrene
d!4-Dibenz(ah)anthracene
Dibenz(ah)anthracene
d!2-Benzo(ghi)perylene
Benzo(ghi)perylene
10:
8:
8:
10:
13:
13:
14:
14:
19:
15:
15:
18:
18:
19 :
24:
22:
22 •
A <£> •
23:
23:
27:
27:
27:
27 :
31:
30:
30:
30:
30:
31:
•a i
-Jl :
31:
32:
32 :
36:
36:
36:
36:
37:
37:
27
18
21
34
29
31
3
10
2
45
51
52
57
5
10
46
49
^ _ /
28
31
20
24
27
31
40
46
50
51
50
51
A C.
4o
56
8
14
34
37
40
45
50
54
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
JL
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
N
Y
N
Y
N
1
1
.00
.78
1.20
0
.66
1.16
1
0
1
1
1
1
2
0
0
1
1
1
^»
1
1
0
1
1
1
1
0
1
0
1
0
1
0
1
0
0
0
1
0
1
.02
.68
.14
.00
.36
.15
.74
.95
.97
.00
.49
23
* £* +J
.58
.26
.81
.28
.17
. 16
.00
.48
.30
.99
.20
.74
C *}
. b2
.11
.65
. 74
.37
.60
.20
.28
.41
.11
0.
0.
477.
1332.
0.
6.
0.
109.
0.
0.
225.
0.
419.
37 .
0.
0.
A A
0.
114.
0.
16.
0.
63
w «J •
0.
0.
5 .
0.
1 .
0.
!:
0.
Q
0.
0.
0.
0,
0.
0 .
05
04
14
90
06
CQ^JST.
06
04
05
05
98
05
78
05«-?Ti
05
02
-| c -— OT
02
11
03
94N
98
,-irvr)=*\.
98
1mJ. \J I/**- 111
94
—in rv"^v
85
u«i&ef
. 80
fr^rOO
78
f=±QQ
-------
13-OCT-1998 11:01:49 AM Dioxin Furan Unknown RESULTS
05OC98U301.RES
Date analyzed
:1000X S-MM5-4 Ex Cal
Isotope R. T. RRF
Ratio mm:ss
PAHAIR.TRG
05-OCT-98
PAHAIR100198U.RRF
ng/ Rec/
SAMPLE MDL
0.0005
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
0.
1.
0.
1.
0.
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
N
Y
N
Y
N
10:
8:
8:
10:
13:
13:
14:
14:
19:
15:
15:
18:
18:
19:
24:
22:
22:
23:
23:
27:
27:
27:
27:
31:
30:
30:
30:
30:
31:
31:
31:
32:
32:
36:
36:
36:
36:
37:
37:
27
18
21
34
29
31
3
10
2
45
51
52
57
5
10
46
49
28
31
20
24
27
31
40
46
50
51
50
51
46
56
8
14
34
37
40
45
50
54
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
N
Y
N
Y
N
1
1
1
0
1
1
0
1
1
1
1
2
0
0
1
1
1
1
1
0
1
1
1
1
0
1
0
1
0
1
1
0
1
0
0
0
1
0
1
.00
.78
.20
.66
.16
.02
.68
.14
.00
.36
.15
.74
.95
.97
.00
.49
.23
.58
.26
.81
.28
.17
.16
.00
.48
.30
.99
.20
.74
.62
.11
.65
.74
.37
.60
.20
.28
.41
.11
0
0
477
1332
0
6
0
109
0
0
225
0
419
37
0
0
44
0
114
0
16
0
63
0
0
5
0
1
0
6
2
0
9
0
0
0
0
0
0
.05
.04 85
.14
.90
.06 121
.68
-------
07-OCT-1998 05:17:23 PM Dioxin Furan Unknown RESULTS
Mass Spec : ULTIMA
GC Column : DB-5
Data file : 050C98U
Weight : 0.5
Name
dl0-2-MethyInaphthalene
d8-Naphthalene
Naphthalene
2-MethyInaphthalene
d8-Acenaphthylene
Acenaphthylene
dl0-Acenaphthene
Acenaphthene
dlO-Anthracene
dlO-Fluorene
Fluorene
dl0-Phenanthrene
Phenanthrene
Anthracene
d!4-Terphenyl
dlO-Fluoranthene
Fluoranthene
dlO-Pyrene
Pyrene
d!2-Benzo(a)anthracene
Benzo(a)anthracene
d!2-Chrysene
Chrysene
dl2-Benzo(e)pyrene
dl2-Benzo(b)fluoranthene
Benzo{b)fluoranthene
d!2-Benzo(k)fluoranthene
Benzo(k)fluoranthene
d!2-Benzo(a)pyrene
Benzo(e)pyrene
Benzo(a)pyrene
d!2-Perylene
Perylene
d!2-Indeno(123-cd)pyrene
Indeno(123-cd)pyrene
d!4-Dibenz(ah)anthracene
Dibenz(ah)anthracene
d!2-Benzo(ghi)perylene
Benzo(ghi)perylene
Results : 050C98U301.RES
Date analyzed
300681-10DI :100X S-MM5-4 Ex Cal
Total Isotope R. T. RRF
Response Ratio mm:ss
95034400
144626200
828332000
1266176000
*
*
*
*
*
133899800
No Peak
73552600
100862800
62004600
78009600
222580000
166579800
701316000
No Peak
255524000
185352800
122494000
190982600
372234000
106954200
36411400
130870600
106381400
146982000
94644600
13066720
142458400
13066720
105998000
13246580
3693180
89078400
17416420
46754200
No Peak
23771000
No Peak
46992600
No Peak
1.
1.
1.
1.
1.
0.
1.
1.
1.
1.
1.
1.
1.
0.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
0.
1.
0.
1.
0.
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
Y
Y
Y
Y
Y
N
Y
Y
Y
Y
Y
Y
Y
N
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
.Y
Y
Y
Y
Y
Y
Y
N
Y
N
Y
N
10:
8:
8:
10:
13:
13:
14:
14:
19:
15:
15:
18:
18:
19:
24:
22:
22:
23:
23:
27:
27:
27:
27:
31:
30:
30:
30:
30:
31:
31:
31:
32:
32:
36:
36:
36:
36:
37:
37:
27
18
21
34
29
31
3
10
2
45
51
52
57
5
10
46
49
28
31
20
24
27
31
40
46
50
51
50
51
46
56
8
14
34
37
40
45
50
54
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
N
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
N
Y
N
Y
N
: PAHAIR.TRG
: 05-OCT-98
: PAHAIR100198U.RR
ng/ Rec/
SAMPLE MDL
1.00 50.00
1.78 42.67 85
1.20 477.14 0.000
0.66 1332.90 0.000
1.16 60.54 121
1.02 0.00 0.000
0.68 56.74 113
1.14 120.33 0.000
1.00 50.00
1.36 46.18 92
1.15 249.01 0.000
2.74 49.06 98
0.95 442.04 0.000
0.97 0.00 0.000
1.00
1.49
1.23
1.58
1.26
0.81
1.28
1.17
1.16
1.00
0.48
1.30
0.99
1.20
0.74
1.62
1.11
0.65
1.74
0.37
0.60
0.20
1.28
0.41
1.11
50.00
24.32 49
53.65 0.000
23.72 47
155.02 0.000
25.77 52
26.59 0.000
21.94 44
70.05 0.000
50.00
66.93 134
10.63 0.000
49.14 98
7.63 0.000
48.80 98
7.71 0.000
3.14 0.000
46.88 94
11.21 0.000
42.72 85
0.00 0.000
39.76 _ 80
o.oo o£®4
39.06 78
0.00 0.000
-------
FUe:05OC98U #1-509 Acq: 6-OCT-1998 16:15:48 GC EI+ Voltage SIR Autospec-Ultima
10
00
.^ *
Sample#30 Text:300681-10Dl :100X S-MM5-4 Exp:PAHAlR ^^
128.0626 S:30 SMO(1,3)
1002
80 J
60 J
40J
20 J
0 :
>
— „
8:do
134.0827 S:30 SMO(1,3)
100 S
80 J
60J
40-i
20 J
0 :
A8.9
E4
_: i
8:do
136.1128 S:30 SMO(1,3)
100%
80 1
60 J
40J
20 J
0
A5.21E6
XX
8:do
142.0782 S:30 SMO(1,3)
100 S
80 J
60 J
40J
20:
0
PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
A4. 4E8
V
>
i
1.3E8
^ A5.70E7 A6.68E7 A5.81E7 A6.43E7 ^
/ V — — ^V •— — — -r^~^i*~~— -^^-—^
9:00 10:00
PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
s^ /\ ^ ^__^^ ^^ __ _ _^__^-^ _
9:00 10:bO
PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
A7.23E7
y
t
ij_
9:do 10:6o
PKD(5,3,3>0.10%,10000.0,0.00%,F,T)
'~N^B ^^^__ >*"*• f^^S ^- ^_ • -^^, • T- — -^ ^T *~s^i
il.lES
L.8.1E7
L5.4E7
L2.7E7
• A /t!7A
O.OEO
ll:6o 12:6o Time
/\__^-^~ '-^—^^—^ — . ^-^-^— . ^^
3.2E4
L2.5E4
L1.9E4
L1.3E4
L6.4E3
O.OEO
ll:6o 12:60 Time
2.4E7
L1.9E7
L1.4E7
i9.7E6
-4.8E6
: O.OEO
11:00 12:60 Time
A6.33E8 r2.1E8
8:00
152.1410 S:30 SMO(1,3)
100 S
80 J
60 J
40J
20 1
0
8:do
9:do 10:bfl
PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
A4.7
!
9:00 10:00
A3.74E8
i A
r
/ 1 / 1
-1.7E8
-1.3E8
-8.4E7
-4.2E7
n.oRo
ll:6o 12:6o Time
E7 1.5E7
il.2E7
L9.2E6
L6.1E6
L3.1E6
O.OEO
11:00 12:00 Time
-------
File:05OC98U #1-509 Acq: 6-OCT-1998 16:15:48 GC EI+ Voltage SIR Autospec-Ultima
Sample#30 Text:300681-10DI :100X S-MM5-4 ExprPAHAIR
152.0626 S:30 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
80-
60.
40-
20_
A2.57E7
A4.90E7
A2.36E7
CD
00
cv
1.1E7
8.9E6
L6.7E6
-4.5E6
L2.2E6
O.OEO
)0 Time
2.1E7
-1.7E7
L1.3E7
8.4E6
L4.2E6
O.OEO
DO Time
12:36 12:48 13:00 13:12 13:24 13:36
160.1128 S:30 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 % A6.69E7
80
60 J
40
20 J
13:48
14:00 14:12 14:24 14:36
14:48
A1.41E7
15:
12:36 12:48 13:6o 13:12 13:24 13:36
154.0782 S:30 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
13:48 14:00 14:12 14:24 14:36
A5.04E7
14:48
-1—I—r—l—I—I—I—1—|—1—I—1—1—I—I I I—1—I—I—r—i—I—1—I—1—[—i—i
12:36 12:48 13:00 13:12 13:24
164.1410 S:30 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
80 J
60
40-
20 J
0
A3.68E7
15:
-1—r-1—i—1—I—I—r—I—1—i—I—i I I—i—1 I r
14:00 14:12 14:24 14
0 Time
9.6E6
4.8E6
L2.4E6
O.OEO
0 Time
12:36 12:48 13:00 13:i2 13:24 13:36 13:48 14:00 14:i2 14:24 14:36 14:48
15:0i
-------
File:05OC98U #1-509 Acq: 6-OCT-1998 16:15:48 GC EI+ Voltage SIR Autospec-Ultima
Sample#30 Text:300681-10DI :100X S-MM5-4 Exp:PAHAlR
152.0626 S:30 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
cvj
-i r——i 1 1 1 1 r 1 1 1 1 1 r r
13:12 13:18 13:24
160.1128 S:30 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
90-
80-
70
60 J
50 J
40
30 4
20
10
13::
13:42
13:48
-O.OEO
Time
t-2.1E7
1.9E7
1.7E7
_1.5E7
_1.3E7
1.1E7
-6.3E6
-4.2E6
-2.1E6
O.OEO
Time
13:1
13:l8
I I I I
13:24
13:30
13:36
13:42
13:48
-------
CO
File:05OC98U #1-509 Acq: 6-OCT-1998 16:15:48 GC EI+ Voltage SIR Autospec-Ultima
Sample#30 Text:300681-10DI :100X S-MM5-4 Exp:PAHAlR
154.0782 S:30 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
90-
80-
70:
60 j
50 j
40
30 J
20
10 J
A4.57E7
:i2 14:i4
14:i8
1.4E7
1.2E7
L9.2E6
7.7E6
-6.1E6
L4.6E6
13.1E6
:1.5E6
O.OEO
Time
13:56 13:58 14:6o 14:62 14:64
164.1410 S:30 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
14:66
14:1
14:io
14
14:
100 S
90 J
80
70_
60.
50 J
40_
30
20 J
10
0.
A3.68E7
13:5
13:5
14:t
14:62
14
^4 14:66 14:1
14:1
14:1
14:1
14:
14:1
1.1E7
-9.6E6
8.4E6
17.2E6
L6.0E6
4.8E6
I.3.6E6
2.4E6
-1.2E6
O.OEO
Time
-------
File:05OC98U #1-509 Acq: 6-OCT-1998 16:15:48 GC EI+ Voltage SIR Autospec-UItima
Sample#30 Text:30068MODI :100X S-MM5-4 Exp:PAHAIR
130.9920 S:30 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100S.
95:
90:
85:
80:
75:
70
65
60:
55:
50:
45-
40
35-
30-
25:
20:
15
10 J
5
0
7:00
A1.27E8
A3.01E7
/TX
A1.44E8
A
CO
CvJ
A5.81E7 A1.92E8
12:6o
14-00^ 15:
7.7E7
t7.3E7
6.9E7
6.5E7
6.1E7
:5.8E7
:5.4E7
:5.0E7
4.6E7
4.2E7
-3.8E7
L3.5E7
:3.1E7
:2.7E7
b.3E7
11.9E7
Ll.5E7
1.2E7
L7.7E6
3.8E6
O.OEO
»0 Time
-------
o
File:05OC98U #1-584 Acq: 6-OCT-1998 16:15:48 GC El+ Voltage SIR Autospec-Ultima
Sample#30 Text:300681-10DI :100X S-MM5-4 Exp:PAHAlR
166.0798 S:30 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
1002
90 J
80 J
70 J
60 J
50 J
40J
30 J
20 J
10 J
15:
, A1.11E8
A
I
^ 1
'~ 1
*~
-------
File:05OC98U #1-584 Acq: 6-OCT-1998 16:15:48 GC EI+ Voltage SIR Autospec-Ultima
SamplejOO Text:300681-10DI :100X S-MM5-4 Exp:PAHAlR
166.0798 S:30 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100
90 -
80-
70 j
60
50_
40J
30 J
201
10J
A1.71E7
' 16:00
_
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:3.8E7
L3.3E7
L2.9E7
2.5E7
-2.1E7
L1.7E7
1.3E7
8.4E6
4.2E6
-—-r 1 1 1 1 1 r P r- 1 1 1 1 1 1 1— r-
15:30 15:36 15:42
176.1410 S:30 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 % A3.9.0E7
90
80
70 J
60
50
40
30.
20-
10-
15:48
15:54
0
15
16
Time
1.7E7
L1.5E7
1.4E7
-1.2E7
L1.0E7
L8.5E6
L6.8E6
L5.1E6
3.4E6
L1.7E6
O.OEO
Time
lo"
i - 1
15:36
1 - 1 - 1 - 1 - 1 - r™^ — i - r-
15:42
15:48
15:54
16:C
16:t
-------
C\»
File:05OC98U #1-584 Acq: 6-OCT-1998 16:15:48 GC EI+ Voltage SIR Autospec-Ultima
Sample#30 Text:300681-10DI :100X S-MM5-4 Exp:PAHAlR
178.0782 S:30 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 % A3.5JE8
~i ~r i i i
18:00 18:
188.1410 S:30
100%
90-
80 J
70J
60
50
40 J
30
204
10
18:54 18::
PKD(5,3,3,0.10%,10000.0,0
0
18:00
18:48
,F,T)
A8.33E7
A3.10E7
19:36
00 Time
3.5E7
L3.1E7
-2.8E7
2.4E7
12.1E7
A.7E7
1.4E7
1.0E7
_7.0E6
-3.5E6
LO.OEO
)0 Time
18:i2 18:24
18
:36
18:48
19
ST
19
-&
19
^
19:48
20:
-------
File:05OC98U #1-584 Acq: 6-OCT-1998 16:15:48 GC EI+ Voltage SIR Autospec-UItima
Sample#30 Text:300681-10DI :100X S-MM5-4 Exp:PAHAlR
178.0782 S:30 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
CJ
Of
18:00
188.1410 S:30
i i i 'i i i ' i i ' i i i i r i ii i ' i i i
18:12 18:24 18:36 18:48
F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T>
19:36
19:48
O.OEO
Time
002
90 J
80-
70 J
60 1
50-
40J
30 J
20-
10 1
0 '
18:
A8.33E7
H
A3.10E7
A
11 l\
— r~ i r— T 1 1 1 1 1 r— T 1 1 1 1 1 1 1 1 1 r 1 1 r— "S — i 1 — i ""1 r\ — r r-H1 i I i — r1 i "T i i • I i ' i — r— i — i [" i i ' I ' | ' ' ' ' '
>0 18:12 18:i4 18:36 18:48 19:00 19:12 19:24 19:36 19:48
3.5E7
L3.1E7
-2.8E7
:2.4E7
L.2.1E7
L1.7E7
L1.4E7
L.1.0E7
L7.0E6
L3.5E6
" O.OEO
Time
-------
C?20 J
\o \o
Ed W
i- t^
-------
File:050C98U #1-1052 Acq: 6-OCT-1998 16:15:48 GC EI+ Voltage SIR Autospec-Ultima
Sample#30 Text:30068MODI :100X S-MM5-4 ExprPAHAIR
202.0782 S:30 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
o
c\j
21:36 2i:48 22:6o 22:ii 22:24 22:36 22:48 ' ' 23:66 ' 23:ii 23:24 ' 23:36 23:48 24:66 24:i2 24^T
212.1410 S:30 F:3 SMO(1,3) PKD(5)3,3,0.10%,10000.0,0.00%,F,T)
100
90
80
70_
60_
50_
40-
30
20
10 j
0
A9.27E7
A9.55E7
izi:36 2i:48 22:66 22:ii 22:24 22:36 22:48
244.1974 S:30 F:3 SMO(1,3) PKD(5)3,3>0.10%,10000.0,0.00%,F,T)
5.8E7
5.2E7
4.6E7
4.1E7
3.5E7
2.9E7
2.3E7
1.7E7
1.2E7
5.8E6
O.OEO
Time
3.9E7
3.5E7
3.1E7
2.7E7
-2.3E7
2.0E7
1.6E7
7.8E6
3.9E6
O.OEO
Time
23:66 23:i2 ' ' 23:24 ^3:36 23:48 24:66
i i i i
24:2
90_
80_
70
60_
50_
40-
30
20
:36 21:48 22:6o 22:il 22:i4 ' 22:36 22:48 ' 23:6fl 23:ii 23:24 23:36 ' 23:48 ' 24:66 24
-5.3E7
-4.7E7
-4.2E7
-3.7E7
_3.2E7
-2.6E7
.2.1E7
.1.6E7
1.1E7
.5.3E6
O.OEO
Time
21
24
:24
-------
a
File:05OC98U #1-1052 Acq: 6-OCT-1998 16:15:48 GC EI+ Voltage SIR Autospec-Ultima
Sample#30 Text:30068MODI :100X S-MM5-4 Exp:PAHAIR
202.0782 S:30 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
22:18
212.1410
100%
90
80
70
60
50-
40J
30 J
20 j
10
0
22:24 22:30 22:36 22:42 ' 22:48 22:54 ' ' 23:00 ' 23:06 23:ii ' 23:is 23:24 23:30
S:30 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
A9.27E7 A9.55E7
23
I I I
:36
23:42 23:48
-O.OEO
Time
,-3.9E7
3.5E7
L3.1E7
L2.7E7
2.3E7
2.0E7
1.6E7
1.2E7
7.8E6
3.9E6
O.OEO
Time
22:18 22:24 22:30 22:36 22:42 ' ' 22:48 ' ' 22:54 23:66 23^6 23:ii 23:i8 23:24 23:30 23:36 23:42
23:48
-------
0}
File:050C98U #1-1052 Acq: 6-OCT-1998 16:15:48 GC EI+ Voltage SIR Autospec-Ultima
Sample#30 Text:300681-10DI :100X S-MM5-4 Exp:PAHAIR
228.0939 S:30 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
90 -
80
70 J
60 j
50 J
40J
301
20
10
1.3E7
11.2E7
1.0E7
-9.0E6
L7.7E6
6.4E6
5.1E6
3.9E6
-2.6E6
-1.3E6
26:ii 26:24 26:36 26:48 27:66 27:i2 27:24 27:36 27:48 28:66 28:ll2 28:24 28:36 28:48 29:'
S:30 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
A5.35E7
O.OEO
10 Time
r-2.0E7
1.8E7
A.6E1
L1.4E7
Ll.2E7
9.8E6
L7.8E6
L5.9E6
3.9E6
L2.0E6
26:
0
240.1692
100%
90 J
80 J
70 J
601
50 J
40 J
30 J
20-
10 J
O.OEO
26:
)0
26
i • • ' ' ' I ' ' ' ' ' i ' ' ' ' ' I ' ' ' ' i i i i i i i i 'i i i i > i i i ii i r~] i' i i i i i i i i i i i i i i i i i i i i i i i i
:12 26:24 26:36 26:48 27:00 27:12 27:24 27:36 27:48 28:00 28:12 28:24 28:36
I I j I
28:48
29:00 Time
-------
FiIe:05OC98U #1-1052 Acq: 6-OCT-1998 16:15:48 GC EI+ Voltage SIR Autospec-Ultima
Sampled Text:30068MODI :100X S-MM5-4 Exp:PAHAlR
228.0939 S:30 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 % A4.85E7
27:00 27:66 27:i2 27:is 27:24 27:30
240.1692 S:30 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
A5.35E7 A6.54E7
27:3
27:42
27:48
27:
O.OEO
Time
2.0E7
L1.8E7
L1.6E7
Ll.4E7
1I.2E7
9.8E6
7.8E6
_5.9E6
3.9E6
2.0E6
O.OEO
Time
-------
File:050C98U #1-1052 Acq: 6-OCT-1998 16:15:48 GC EI+ Voltage SIR Autospec-Ultima
Sample#30 Text:300681-10DI :100X S-MM5-4 Exp:PAHAlR
230.9856 S:30 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
95-
90
85
80-
75 J
70
65-
60 -
55
50 J
45 J
40J
351
30:
25
204
15
10
s
0
A1.84E7
A2.85E6
.-2.8E7
L2.7E7
L2.6E7
-2.4E7
_2.3E7
2.1E7
-2.0E7
1.8E7
1.7E7
1.6E7
11.4E7
1.3E7
11.1E7
19.9E6
L8.5E6
:7.1E6
L5.7E6
4.3E6
2.8E6
21:t
22:C
23:00 24:00 25:6o 26:00
27:00
28:t
29
^xT
O.OEO
Time
-------
O
O
File:05OC98U #1-915 Acq: 6-OCT-1998 16:15:48 GC EI+ Voltage SIR Autospec-Ultima
SamplelJO Text:30068MODI :100X S-MM5-4 Exp:PAHAlR
252.0939 S:30 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 ft A8.7JIE6
90-
80-
70
60
50 J
40
30 J
A6.53E6
20 -
10-
A3.14E6
30:60 31ho 32:00
264.1692 S:30 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 ft A7.35E7
90 -
80 J
70 j
60
50 j
40
30
20
10 j
2.0E6
1.8E6
11.6E6
1.4E6
-1.2E6
-9.8E5
7.8E5
_5.9E5
-3.9E5
-2.0E5
^O.OEO
t)0 Time
33:1)0
30:00
A4.73E7
A4.45E7
34:
1.8E7
L1.6E7
1.4E7
M.2E7
I.IE7
8.9E6
-7.1E6
L5.3E6
13.6E6
1.8E6
32:<]
33:00
34:t
O.OEO
0 Time
-------
O
File:05OC98U #1-915 Acq: 6-OCT-1998 16:15:48 GC EI+ Voltage SIR Autospec-Ultima
Sample#30 Text:30068MODI :100X S-MM5-4 Exp:PAHAIR
252.0939 S:30 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100
30:24 30:36 30:48 31:66 31:i2 31:24 31:36 31:48 32:00 32:ii 32:24
264.1692 S:30 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
T—I 1 I I
32:36
32:48
30:24 30:36 30:48 31:00 31:
i i i i i—| i i i i i—I i i r i i I i i i i i | i i i i—i i i
6 31:48 32:60 32:12 32:24 32:36
_T_r_O.OEO
33:00 Time
1.8E7
L1.6E7
:1.4E7
L1.2E7
1.1E7
t_8.9E6
7.1E6
-5.3E6
L3.6E6
L1.8E6
_O.OEO
33:00 Time
-------
ej
File:05OC98U #1-915 Acq: 6-OCT-1998 16:15:48 GC EI+ Voltage SIR Autospec-Uttima
Sample#30 Text:300681-10Dl :100X S-MM5-4 Exp:PAHAlR
252.0939 S:30 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
30:36 30:42 30:48
S:30 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
A4.73E7
O.OEO
Time
-------
FHe:050C98U #1-915 Acq: 6-OCT-1998 16:15:48 GC E1+ Voltage SIR Autospec-Ultima
Sample#30 Text:300681-10Dl :100X S-MM5-4 Exp:PAHAIR
276.0939 S:30 F:4 SMO(1,3) PKD(5,3,3,O.W%,IQOQO.O,OM%,F,T)
100%
80 j
60-
40
20 J
O
36:00 37:0038:00
288.1692 S:30 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 % A2.35E7
A2.34E7
80
60
40J
20 J
3.8E4
-3.0E4
_2.3E4
L1.5E4
L7.6E3
LO.OEO
)0 Time
36:00 37:60 38:00
278.1096 S:30 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
80
60 4
40
20 J
39:t
40:t
41:
39:6fl 40:00 41:
2.6E6
L2.1E6
L1.5E6
A.OE6
L5.1E5
O.OEO
)0 Time
l.6E4
1.2E4
4.1 E3 -
O.OEO
)0 Time
36:60 37:00 38:00
292.1974 S:30 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
80
60 J
40 J
20 J
0
A1.19E7
39:00
40:00
41:1
1.2E6
L9.2E5
6.9E5
-4.6E5
:2.3E5
O.OEO
)0 Time
36:00
37:00
38:00
39:00
40:00
41:1
-------
File:050C98U #1-915 Acq: 6-OCT-1998 16:15:48 GC EI+ Voltage SIR Autospec-Ultima
Sample#30 Text:300681-10DI :100X S-MM5-4 Exp:PAHAIR
268.9824 S:30 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
90
80-
70 _
60 J
50 J
40
30 J
20 J
10 J
0
O
CO
A6.27ES
5.4E6
14.9E6
L4.4E6
3.8E6
-3.3E6
12.7E6
2.2E6
t-1.6E6
1.1E6
5.4E5
30:6o 31:00 32:00 33:6o 34:i)0
280.9824 S:30 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
90 J
SO
70
60-
50 J
40J
30 J
20 J
10
0
LO.OEO
)0 Time
35:6o 36:6o 37:6o 38:00 39:6o 40:6o 41 :i
A1.85E7
30:6o
31:
33:6o 34:6fl 35:6o
36:C
37:'
38:t
39:t
I—I—[—I—1—I—1—1—
40:00 41:
-1.3E7
-1.1E7
9.3E6
_7.5E6
:5.6E6
L3.7E6
L1.9E6
-O.OEO
0 Time
-------
15-OCT-1998 10:33:06 AM Dioxin Furan Unknown RESULTS
GC Column : DB-5
Data file : 050C98U
Weight : 0.00033
Name
dlO-2-Methylnaphthalene
d8-Naphthalene
Naphthalene
2-Methylnaphthalene
d8-Acenaphthylene
Acenaphthylene
dlO-Acenaphthene
Acenaphthene
dlO-Anthracene
dlO-Fluorene
Fluorene
dlO-Phenanthrene
Phenanthrene
Anthracene
dl4-Terphenyl
dlO-Fluoranthene
Fluoranthene
dlO-Pyrene
Pyrene
d!2-Benzo(a)anthracene
Benzo(a)anthracene
d!2-Chrysene
Chrysene
d!2-Benzo(e)pyrene
dl 2-Benzo(b)fluoranthene
Benzo(b)fluoranthene
d!2-Benzo(k)fluoranthene
Benzo(k)fluoranthene
d!2-Benzo(a)pyrene
Benz o(e)pyrene
Benzo(a)pyrene
dl2-Perylene
Perylene
d!2-Indeno(12 3 -cd)pyrene
Indeno(12 3 -cd)pyrene
d!4-Dibenz(ah)anthracene
Dibenz(ah)anthracene
d!2-Benzo(ghi)perylene
Benzo(ghi)perylene
Results : 050C98U311.RES
Date analyzed
300681-11DI :100X S-MM5-5 Ex Cal
Total Isotope R. T. RRF
Response Ratio mm:ss
91866200
137456400
1369832000
2033900000
130839800
19200000
67575400
189400000
65326000
78420200
380000000
166487400
1240000000
*
*
*
100400000
252396000
188868000
161000000
191930200
456000000
105184000
38400000
123979800
153800000
144089800
86927800
10420000
136496800
4880000
100709800
16420000
4730780
87642800
28257400
43906200
No Peak
22166000
No Peak
43166400
No Peak
1.
1.
1.
1.
l.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
,00
.00
.00
.00
1.00
1
1
.00
.00
1.00
1
1
1
0
1
0
1
0
.00
.00
.00
.00
.00
.00
.00
.00
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
N
Y
N
Y
N
10:
8:
8:
10:
13:
13:
14:
14:
19:
15:
15:
18:
18:
19:
24:
22:
22:
23:
23:
27:
27:
27:
27:
31:
30:
30:
30:
30:
31:
31:
31:
32:
32:
36:
36:
36:
36:
37:
37:
27
18
22
34
30
31
4
10
2
45
51
53
57
5
10
46
49
28
31
20
24
27
31
41
46
50
51
56
51
46
56
9
15
35
38
40
46
51
56
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
N
Y
Y
Y
Y
Y
Y
N
Y
N
Y
N
PAHAIR.TRG
05-OCT-98
PAHAIR100198U.RR
ug/ Rec/
SAMPLE MDL
1.00 0.05
1.78 0.04
1.20 1257.90
0.66 3413.27
1.16
1.02
0.68
1.14
0.06
21.70
0.05
372.64
1.00 0.05
1.36 0.04
1.15 640.75
2.74 0.05
0.95 1184.85
0.97 93.97
1.00 0.05
1.49 0.03
1.23 104.85
1.58
1.26
0.81
1.28
1.17
1.16
1.00
0.48
1.30
0.99
1.20
0.74
1.62
1.11
0.65
1.74
0.37
0.60
0.20
1.28
0.41
1.11
0.02
286.31
0.03
43.20
0.02
161.97
84
122
108
88
93
50
48
51
42
0.05
0.06 125
13.98
-------
15-OCT-1998 10:33:02 AM Dioxin Furan Unknown RESULTS
050C98U311.RES
Date analyzed
:100X S-MM5-5 Ex Cal
Isotope R. T. RRF
Ratio Ttun:ss
PAHAIR.TRG
05-OCT-98
PAHAIR100198U.RRF
ug/ Rec/
SAMPLE MDL
0.00033
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
0.00
1.00
0.00
1.00
0.00
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
N
Y
N
Y
N
10:
8:
8:
10:
13:
13:
14:
14:
19:
15:
15:
18:
18:
19:
24:
22:
22:
23:
23:
27:
27:
27:
27:
31:
30:
30:
30:
30:
31:
31:
31:
32:
32:
36:
36:
36:
36:
37:
37:
27
18
22
34
30
31
4
10
2
45
51
53
57
5
10
46
49
28
31
20
24
27
31
41
46
50
51
56
51
46
56
9
15
35
38
40
46
51
56
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
N
Y
Y
Y
Y
Y
Y
N
Y
N
Y
N
1
1
1
0
1
1
0
1
1
1
1
2
0
0
1
1
1
1
1
0
1
1
1
1
0
1
0
1
0
1
1
0
1
0
0
0
1
0
1
.00
.78
.20
.66
.16
.02
.68
.14
.00
.36
.15
.74
.95
.97
.00
.49
.23
.58
.26
.81
.28
.17
.16
.00
.48
.30
.99
.20
.74
.62
.11
.65
.74
.37
.60
.20
.28
.41
.11
0
0
1257
3413
0
21
0
372
0
0
640
0
1184
93
0
0
104
0
286
0
43
0
161
0
0
13
0
4
0
15
6
0
28
0
0
0
0
0
0
.05
.04
.90
.27
.06
.70
.05
.64
.05
.04
.75
.05
.85
.97
.05
.03
.85
.02
.31
.03
.20
.02
.97
.05
.06
84
122
108
88
93
50
48
51
42
125
.98
-------
13-OCT-1998 12:01:40
Dioxin Furan Unknown RESULTS
GC Column
Data file
Weight
DB-5
050C98U
Name
Results :
300681-11DI
Total
Response
050C98U311.RES
Date analyzed
:100X S-MM5-5 Ex Cal
Isotope R. T. RRF
Ratio mm:ss
PAHAIR.TRG
05-OCT-98
PAHAIR100198U.RRF
f Rec/
PLE MDL
dlO - 2 -Methylnaphthalene
d8 -Naphthalene
Naphthalene
2 -Methylnaphthalene
d8 -Acenaphthylene
Acenaphthylene
dlO -Acenaphthene
Acenaphthene
dlO -Anthracene
dlO-Fluorene
Fluorene
dlO - Phenanthrene
Phenanthrene
Anthracene
d!4 -Terphenyl
dl 0 - Fluoranthene
Fluoranthene
dlO- Pyrene
Pyrene
d!2 -Benzo (a) anthracene
Benzo (a) anthracene
d!2-Chrysene
Chrysene
d!2 -Benzo (e) pyrene
dl2 -Benzo (b) f luoranthene
Benzo (b) f luoranthene
d!2 -Benzo (k) f luoranthene
Benzo (k) f luoranthene
d!2 -Benzo (a) pyrene
Benzo (e) pyrene
Benzo (a) pyrene
d!2-Perylene
Perylene
d!2 - Indeno ( 123 -cd) pyrene
I ndeno ( 1 2 3 - cd ) pyrene
d!4-Dibenz (ah) anthracene
Dibenz (ah) anthracene
d!2 -Benzo (ghi)perylene
Benzo (ghi)perylene
91866200
137456400
1369832000
2033900000
130839800
19200000
67575400
189400000
65326000
78420200
380000000
166487400
1240000000
100400000
252396000
188868000
161000000
191930200
456000000
105184000
38400000
123979800
153800000
144089800
86927800
10420000
136496800
4880000
100709800
16420000
4730780
87642800
28257400
43906200
* No Peak
22166000
* No Peak
43166400
* No Peak
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
0
1
0
1
0
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
N
Y
N
Y
N
10:
8:
8:
10:
13:
13:
14:
14:
19:
15:
15:
18:
18:
19:
24:
22:
22:
23:
23:
27:
27:
27:
27:
31:
30:
30:
30:
30 :
31:
31:
31:
32:
32:
36:
36:
36:
36:
37:
37:
27
18
22
34
30
31
4
10
2
45
51
53
57
5
10
46
49
28
31
20
24
27
31
41
46
50
51
56
51
46
56
9
15
35
38
40
46
51
56
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
N
Y
Y
Y
Y
Y
Y
N
Y
N
Y
N
1.00
1.78
1.20
0.66
1.16
1.02
0.68
1.14
1.00
1.36
1.15
2.74
0.95
0.97
1.00
1.49
1.23
1.58
1.26
0.81
1.28
1.17
1.16
1.00
0.48
1.30
0.99
1.20
0.74
1.62
1.11
0.65
1.74
0.37
0.60
0.20
1.28
0.41
1.11
.CSO
«CA1
830
2252
,051
14
,C53
245
.CSO
*C44
422
.ae
782
62
C50
25
69
.C24
188
£25
28
.Cei
106
,C50
62
9
.0*8
2
.07
10
4
.Q47
' 18
££0
0
.CB7
0
.•C36
0
.00
.95
.21
.76
.19
84
122
.32«RL-10tT
.92
.95
.00
.06
.89
.54
.00
.00
.09
.14
.96
.65
.04
.90
.00
.71
.23
.03
97
.30
. 05
.23
.05
.49
.92
108
88
93
c^L-*6^-
50
-------
13-OCT-1998 12:01:35 PM Dioxin Furan Unknown RESULTS
050C98U311.RES
Date analyzed
:100X S-MM5-5 Ex Cal
Isotope R. T. RRF
Ratio mm:ss
PAHAIR.TRG
05-OCT-98
PAHAIRl00198U.RRF
ng/ Rec/
SAMPLE MDL
1.00 50.00
1.78 41.95
1.20 830.21
0.66 2252.76
84
0.5
45933100 45933100
68728200 68728200
684916000 684916000
1016950000 1016950000
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
0.00
1.00
0.00
1.00
0.00
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
N
Y
N
Y
N
13:
13:
14:
14:
19:
15:
15:
18:
18:
19:
24:
22:
22:
23:
23:
27:
27:
27:
27:
31:
30:
30:
30:
30:
31:
31:
31:
32:
32:
36:
36:
36:
36:
37:
37:
30
31
4
10
2
45
51
53
57
5
10
46
49
28
31
20
24
27
31
41
46
50
51
56
51
46
56
9
15
35
38
40
46
51
56
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
N
Y
Y
Y
Y
Y
Y
N
Y
N
Y
N
1.
1.
0.
1.
1.
1,
1,
2
0
0
1
1
1
1
1
0
1
1
1
1
0
1
0
1
0
1
1
0
1
0
0
0
1
0
1
,16
,02
.68
.14
.00
.36
.15
.74
.95
.97
.00
.49
.23
.58
.26
.81
.28
.17
.16
.00
.48
.30
.99
.20
.74
.62
.11
.65
.74
.37
.60
.20
.28
.41
.11
61.
14.
53.
245.
50.
44.
422.
46.
782.
62.
50.
25.
69.
24.
188.
25.
28.
21.
106,
50,
62
19
122
32
-------
07-OCT-1998 05:18:37 PM Dioxin Furan Unknown RESULTS
Mass Spec : ULTIMA
GC Column : DB-5
Data file : 050C98U
Weight : 0.5
Name
dlO-2-Methylnaphthalene
d8-Naphthalene
Naphthalene
2-Methylnaphthalene
d8-Acenaphthylene
Acenaphthylene
dlO-Acenaphthene
Acenaphthene
dlO-Anthracene
dlO-Fluorene
Fluorene
dl0 -Phenanthrene
Phenanthrene
Anthracene
dl4-Te rpheny1
dl0-Fluoranthene
Fluoranthene
dlO-Pyrene
Pyrene
d!2-Benzo(a)anthracene
Benzo(a)anthracene
d!2-Chrysene
Chrysene
d!2-Benzo(e)pyrene
d!2-Benzo(b)fluoranthene
Benzo(b)fluoranthene
d!2-Benzo(k)fluoranthene
Benzo(k)fluoranthene
d!2-Benzo(a)pyrene
Benzo(e)pyrene
Benzo(a)pyrene
d!2-Perylene
Perylene
d!2-Indeno(12 3 -cd)pyrene
Indeno(123-cd)pyrene
d!4-Dibenz(ah)anthracene
Dibenz(ah)anthracene
d!2-Benzo(ghi)perylene
Benzo(ghi)perylene
Results : 050C98U311.RES
Date analyzed
300681-11DI :100X S-MM5-5 Ex Cal
Total Isotope R. T. RRF
Response Ratio mm:ss
91866200 1.00 Y 10: 27 Y
137456400 1.00 Y 8: 18 Y
1369832000 1.00 Y 8: 22 Y
2033900000 1.00 Y 10: 34 Y
130839800 1.00 Y 13: 30 Y
* No Peak 0.00 N 13: 31 Y
67575400 1.00 Y 14: 4 Y
207610000 1.00 Y 14: 10 Y
65326000 1.00 Y 19: 2 Y
78420200 1.00 Y 15: 45 Y
415472000 1.00 Y 15: 51 Y
166487400 1.00 Y 18: 53 Y
1300970000 1.00 Y 18: 57 Y
* No Peak 0.00 N 19: 5 N
252396000 1.00 Y 24:
188868000 1.00 Y 22:
184300800 1.00 Y 22:
191930200 1.00 Y 23:
553388000 1.00 Y 23:
105184000 1.00 Y 27:
53193800 1.00 Y 27:
123979800 1.00 Y 27:
162916600 1.00 Y 27;
144089800 1.00 Y 31:
86927800 1.00 Y 30:
15492440 1.00 Y 30:
136496800 1.00 Y 30:
* No Peak 0.00 N 30:
100709800 1.00 Y 31:
17986300 1.00 Y 31
4730780 1.00 Y 31
87642800 1.00 Y
28257400 1.00 Y
43906200 1.00 Y
* No Peak 0.00 N
22166000 1.00 Y
* No Peak 0.00 N
43166400 1.00 Y
* No Peak 0.00 N
32
32
36
36
36
36
37
37
10 Y
46 Y
49 Y
28 Y
31 Y
20 Y
24 Y
27 Y
31 Y
41 Y
46 Y
50 Y
51 Y
56 N
51 Y
46 Y
56 Y
9 Y
15 Y
35 Y
38 N
40 Y
46 N
51 Y
56 N
: PAHAIR.TRG
: 05-OCT-98
: PAHAIR100198U.RR
ng/ Rec/
SAMPLE MDL
1.00 50.00
1.78 41.95 84
1.20 830.21 0.000
0.66 2252.76 0.000
1.16 61.19 122
1.02 0.00 0.000
0.68 53.92 108
1.14 269.59 0.000
1.00 50.00
1.36 44.06 88
1.15 462.37 0.000
2.74 46.54 93
0.95 820.45 0.000
0.97 0.00 0.000
1.00 50.00
1.49 25.09 50
1.23 79.22 0.000
1.58 24.14 48
1.26 229.32 0.000
0.81 25.65 51
1.28 39.50 0.000
1.17 21.04 42
1.16 113.24 0.000
1.00 50.00
0.48 62.71 125
1.30 13.72 0.000
0.99 48.03 96
1.20 0.00 0.000
0.74 47.30 95
1.62 11.01 0.000
1.11 4.23 0.000
0.65 47.05 94
1.74 18.49 0.000
0.37 40.9&G5 82
0.60 0.00 0.000
0.20 37.82 76
1.28 0.00 0.000
0.41 36.60 73
1.11 0.00 0.000
-------
File:05OC98U #1-508 Acq: 6-OCT-1998 17:02:10 GC E1+ Voltage SIR Autospec-Ultima
Sample#31
Text:300681-llDI :100X S-MM5-5 Exp:PAHAlR
128.0626 S:31 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
80 J
60 J
40J
20 J
0-
A6.85E8
/
\
r-ii
C<3
V **
2.2E8
V _ A7.»E7_ MJttS*^ J^f^l^-^^J1^^^^
8:dfl 9:do 10:6o
L1.8E8
L1.3E8
i8.8E7
L4.4E7
O.OEO
ll:6o 12:00 Time
134.0827 S:31 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 S
80_
60.
40-
20 J
0:
A9.9
,
)E4
_\____^_^^^^_^/~-^_^A^_ y-^^ /-^~\ ^ _^ -^-^/\-^ _^
8:3o 9:do 10:6o
3.4E4
_^___ y\ ^_^^_^__^^__-__^^ — — . -— ^~
_2.8E4
i2.1E4
L1.4E4
L6.9E3
O.OEO
ll:6o 12:6o Time
136.1128 S:31 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 S.
80 J
60 J
40 -
20 J
Oj
A6.87E7
A
A6.25E6
/\
8:dfl 9:do 10:6o
2.3E7
L1.9E7
L1.4E7
L9.3E6
L4.6E6
O.OEO
ll:6o 12:6o Time
142.0782 S:31 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
1002
80 J
60 1
40 J
20 1
0
A1.02E9 _3.3E8
\
8:do 9:do 10:00
/
A6.26E8
\ A
L2.7E8
L2.0E8
L1.3E8
L6.7E7
O.OEO
11:00 12:00 Time
152.1410 S:31 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 2
80 J
60 J
401
20 J
o:
,
A4.59E7 1.5E7
A
1
/
J v
8:do 9:do 10:6o
L1.2E7
L9.3E6
L6.2E6
L3.1E6
: O.OEO
ll:6o 12:6o Time
-------
File:05OC98U #1-508 Acq: 6-OCT-1998 17:02:10 GC EI+ Voltage SIR Autospec-Ultima
Sample#31 Text:300681-llDI :100X S-MM5-5 Exp:PAHAIR
152.0626 S:31 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
CO
12:36 12:48 13:00
160.11285:31 SMO(1,3) PKD(5,3,3,0.1
100%
80
60
40
20 J
13:\2 13:24 13:36
b,10000.0,0.00%,F,T)
A6.54E7
A
V
A1.28E7
O.OEO
>0 Time
_2.1E7
Ll.7E7
1.3E7
-8.6E6
L4.3E6
10.0EO
)0 Time
.-3.1E7
;.2.4E7
1.8E7
11.2E7
L6.1E6
i 'i i i i i—i—i i i i i i ri i i i i i i—i—i i i i i i i i i i i pi i i i i i i
12:36 12:48 13:6o 13:12 13:24 13:36 13:48
154.0782 8:31 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
IOCS.
80 J
60
40J
20 J
I i i f\—i 1*1 I* i i i i i i i i i i i i ii—i i i i "j r
14:00 14:12 14:24 14:36 14:48
A1.04E8
A4.12E7
A6.69E7
A2.83E7
A1.75E7
LO.OEO
)0 Time
12:36 12:48 13:00 13:i2 13:24
164.14108:31 SMO(1,3) PKD(5,3>3,0.10%,10000.0,0.00%,F,T)
1005.
80 J
60
40 J
20
0
13:36
13:48 14:6d 14:i2 14:24 14:36 14:48
A3.38E7
15:
1.1E7
19.0E6
6.8E6
4.5E6
2.3E6
-O.OEO
)0 Time
12:36 12:48 13:00 13:12 13:24 13:36 13:48 14:6o 14:i2 14:24 14:36
14:48
15:
-------
Cvl
rH
CO
FiIe:05OC98U #1-508 Acq: 6-OCT-1998 17:02:10 GC EI+ Voltage SIR Autospec-UItima
Sample#31 Text:300681-llDI :100X S-MM5-5 Exp:PAHAlR
152.0626 S:31 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 % A3.0JE7
13:i213:i813:24
160.1128 S:31 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
90 -
80 -
70 -
60 J
50 j
40 J
30 J
20 J
10 J
13:
13:42
13:48
Time
_2.1E7
-1.9E7
L1.7E7
-1.5E7
Ll.3E7
L1.1E7
L8.6E6
L6.4E6
L4.3E6
L2.1E6
i-O.OEO
Time
13:i2 ' 13:i8
'l3:24~T"
13:3
13:
13:42
13:48
-------
File:05OC98U #1-508 Acq: 6-OCT-1998 17:02:10 GC EI+ Voltage SIR Autospec-Uldma
Sample#31 Text:300681-llDI :100X S-MM5-5 Exp:PAHAlR
154.0782 S:31 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
A9.47E7
CO
•rH
CO
O.OEO
Time
13:48 13:54
164.1410 S:31 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
1003
O.OEO
Time
-------
File:05OC98U #1-508 Acq: 6-OCT-1998 17:02:10 GC EI+ Voltage SIR Autospec-UKima
Sample#31 Text:300681-llDI :100X S-MM5-5 Exp:PAHAIR
130.9920 S:31 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100'
95 J
90 J
85 J
sol
75:
70:
65:
60:
55:
50:
45:
40
35:
30:
25
20:
15:
10:
5:
0
7:00 8:dO 9:00 10:60 11:
CO
A1.07E8
A
37E//S
A6.09E7
A9.30E7
PfV\A/YV"
12:i
14:(
15:
-7.2E7
6.8E7
16.5E7
6.1E7
5.7E7
5.0E7
-4.7E7
L4.3E7
L3.9E7
L3.6E7
L3.2E7
2.9E7
U.5E7
2.2E7
1.8E7
L1.4E7
17.2E6
3.6E6
O.OEO
)0 Time
-------
File:05OC98U #1-585 Acq: 6-OCT-1998 17:02:10 GC EI+ Voltage SIR Autospec-Ultima
Sample#31 Text:300681-llDl :100X S-MM5-5 Exp:PAHAIR
166.0798 S:31 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
10
^
CO
172.0984 S:31 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
90
80
70 j
60
50 j
40
30 J
20 J
10
0
A1.97E4
15:00 15:^2 15:24 ' ' 15:36 15:48 16:00
176.1410 S:31 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
T r—I 1 1 1 1 r—i , 1 1 1 r—r-
16:12 16:24 16:36
2.1E4
1.9E4
1.7E4
U.5E4
1.3E4
1.0E4
L8.4E3
-6.3E3
L4.2E3
L2.1E3
O.OEO
DO Time
16
16:48
17:
100?
90 J
80 J
70^
60:
50-
40-
30 J
20 _
10 J
0:
I5:i
•> A3.92E7
ft
j \
)0 15:12 15:24 15:36 15:48 16:00 16:12 16:24 16:36 16:48 17:(
1
LI
LI
LI
LI
*
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L5
L3
LI
E0
)0
1.2E7
1.0E7
8.4E6
6.8E6
5.1E6
3.4E6
1.7E6
O.OEO
Time
-------
File:05OC98U #1-585 Acq: 6-OCT-1998 17:02:10 GC EI+ Voltage SIR Autospec-UItima
Sample#31 Text:300681-HDI :100X S-MM5-5 Exp.-PAHAIR
166.0798 S:31 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 9>
90:
80 J
70
60-
50-;
40J
30 J
20 J
10 J
CO
A1.90E8
A2.89E7
-7.5E7
-6.7E7
-6.0E7
.5.2E7
.4.5E7
.3.7E7
.3.0E7
.2.2E7
.1.5E7
-7.5E6
O.OEO
Time
15:32 15:34 15:36 15:38 15:40 ' 15:42 15:44 15:46 15:48 15:50 15:52 15:54 15:56 15:58 16:6o 16:62 16:64
176.1410 S:31 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100S.
90 J
80 J
70 J
60 '-
50 -
40-
30 J
20 J
10 J
A3.92E7
Q - ^> ^*^.
15:32 15:34 15:36 15:38 15:40 15:42 15:44 15:46 15:48 15:50 15:52 15:54 15:56 15:58 16:6fl 16:^2 16:64
.1.5E7
1.4E7
.1.2E7
.1.0E7
8.4E6
5.1E6
3.4E6
1.7E6
O.OEO
Time
-------
-------
-------
File:05OC98U #1-585 Acq: 6-OCT-1998 17:02:10 GC EI+ Voltage SIR Autospec-Ultima
Sample#31 Text:300681-llDI :100X S-MM5-5 Exp:PAHAIR
oo
zui.vi
100 S
95:
90:
85:
80:
75:
70:
65:
60:
55-
50:
45:
40:
35:
30:
25:
20:
15:
10:
5:
0_
15
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-------
•O
File:05OC98U #1-1052 Acq: 6-OCT-1998 17:02:10 GC EI+ Voltage SIR Autospec-Ultima
Sample#31 Text:300681-llDI :100X S-MM5-5 Exp:PAHAIR
202.0782 S:31 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
A2.77E8
10
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21:36 21:48 22:6o 22:12 22:24 22:36 22:48
212.1410 S:31 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
1002
90-i
80 J
70 J
60 J
50 J
40J
30 J
20 J
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A9.44E7
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23:48 24:0
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i_7.9E7
L7.0E7
6.2E7
15.3E7
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H3.5E7
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1.8E7
8.8E6
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Time
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3.2E7
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8.0E6
4.0E6
O.OEO
Time
21:36 2i:48 22:66 22:ii 22:24 22:36 22:48
244.1974 S:31 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
90
80
23:6o 23:12 23:24 23:36 23:48 24:6o 24:12 24:24
10
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L3.1E7
L2.6E7
L2.1E7
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L1.0E7
L5.2E6
O.OEO
Time
-------
File:05OC98U #1-1052 Acq: 6-OCT-1998 17:02:10 GC EI+ Voltage SIR Autospec-Ultima
Sample#31 Text:300681-llDI :100X S-MM5-5 Exp:PAHAlR
202.0782 S:31 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
22:24 ' 22:36 22:48 23:00
212.1410 S:31 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 %f A9.44E7
90-:
80
70
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501
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Time
22:24'
22:3
22:48
23:00
23:1
23:24'
23:3
23:48
24:fl
-------
File:05OC98U #1-1052 Acq: 6-OCT-1998 17:02:10 GC EI+ Voltage SLR Autospec-Ultima
Sampled 1 Text:300681-llDI :100X S-MM5-5 Exp:PAHAlR
228.0939 S:31 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
26:00
240.1692
100%
90
80
70 J
60
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201
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0-
26:ii 26:24 26:36 26:48 27:66 27:12 27:24 27:36 27:48 28:00 28:i2 28:24 28:36 28:48 29:
S:31 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
A5.26E7
CM
2.0E7
-1.8E7
1.6E7
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8.0E6
6.0E6
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1.9E7
1.7E7
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-------
File:050C98U #1-1052 Acq: 6-OCT-1998 17:02:10 GC EI+ Voltage SIR Autospec-Ultima
Sample#31 Text:300681-HDI :100X S-MM5-5 Exp:PAHAIR
228.0939 S:31 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
03
Of
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Time
27:42' ' ' '27:48' ' ' 27:54
26:54
240.1692 S:31 F:3
100%
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Time
-------
CO
File:05OC98U #1-1052 Acq: 6-OCT-1998 17:02:10 GC EI+ Voltage SIR Autospec-UWma
SampleiOl Text:300681-llDI :100X S-MM5-5 Exp:PAHAlR
230.9856 S:31 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
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Time
-------
File:05OC98U #1-915 Acq: 6-OCT-1998 17:02:10 GC EI+ Voltage SIR Autospec-Ultima
Sample#31 Text:300681-llDI :100X S-MM5-5 Exp:PAHAIR
252.0939 S:31 F:4 SMO(1,3) PKD(5,3,3,0.10%>10000.0,0.00%,F,T)
100% A1.41E7
30:00 31:50'' ' ' 32:1)0
264.1692 S:31 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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100 S
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80 J
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)0 Time
-------
Fiie:05OC98U #1-915 Acq: 6-OCT-1998 17:02:10 GC EI+ Voltage SIR Autospec-UItima
Sample#31 Text:300681-llDI :100X S-MM5-5 Exp:PAHAIR
252.0939 S:31 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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30:24 30:30 30:36
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100%
30:42 30:48 30:54 31:00
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A6.82E7
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1:06 31:12 31:18 31:24
CO
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A5.35E5 A5.13E5 A4.66E5
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Time
30:24
30:30
30:36
30:42
30:48
30:54
31:6o
31:66 31:12 31:18 31:24
O.OEO
Time
-------
File:05OC98U #1-915 Acq: 6-OCT-1998 17:02:10 GC EI+ Voltage SIR Autospec-Ultima
S«mple#31 Text:300681-llDI :100X S-MM5-5 Exp:PAHAIR
252.0939 S:31 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
90 J
80
70-
60:
50 J
40J
30 j
201
10
0
A1.41E7
A8.21E6
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1.9E6
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1.4E7
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31:24 31:30 31:36 31:42 31:48 31:54 32:00
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80
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30-
20-
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0
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32:42
-------
File:OSOC98U #1-915 Acq: 6-OCT-1998 17:02:10 GC E1+ Voltage SIR Autospec-UHima
Sample#31 Text:300681-llDI :100X S-MM5-5 Exp:PAHAIR
276.09395:31 F:4SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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80
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288.1692 S:31 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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39:t
40:00
41:
LO.OEO
)0 Time
-------
CO
File:05OC98U #1-915 Acq: 6-OCT-1998 17:02:10 GC E1+ Voltage SIR Autospec-UItima
Sample#31 Text:300681-llDI :100X S-MM5-5 Exp:PAHAlR
268.98248:31 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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:1.8E6
O.OEO
)0 Time
-------
Laboratory Control Sample
380
-------
LABORATORY CONTROL SAMPLE REPORT
Advanced Technology Group - High Resolution
Project: 300681
Category: PAH-HR-AIR PAH by HRGC/HRMS
Test: PAH-HR-AIR
Matrix: AIR
QC Lot: 18 AUG 98-A
Concentration Units: ng/sample
Analyte
Naphthalene
2-Methylnaphthalene
Acenaphthylene
Acenaphthene
Fluorene
Phenanthrene
Anthracene
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
Benzoi
Benzoi
Benzo
Benzo(a
fluoranthene
fluoranthene
pyrene
pyrene
Perylene
Indeno(1,2,3-cd)pyrene
Dibenz(a,h)anthracene
Benzo(g,h,i)perylene
Naphthalene-d8
Acenaphthylene-d8
Acenaphthene-dlO
Fluorene-dlO
Phenanthrene-dlO
Fluoranthene-dlO
Pyrene-dlO
Benzo(a)anthracene-dl2
Chrysene-dl2
Benzoi
Benzoi
Benzoi
k
fluoranthene-d!2
fluoranthene-d!2
pyrene-d!2
Perylene-dl2
Indeno(123-cd)pyrene-dl2
Dibenz(a,h]anthracene-dl4
Benzo(g,h,i)perylene-d!2
QC Run: 20 AUG 98-A
Concentration
Spiked Measured
200
200
200
200
200
200
200
200
200
200
200
200
200
200
200
200
200
200
200
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
170
130
170
170
210
160
160
150
160
150
160
140
140
160
140
120
140
160
150
107
83
85
86
85
106
110
97
106
98
99
88
92
96
89
105
Accuracy(%)
LCS Limits
85
67
83
85
107
79
79
77
79
77
82
70
72
82
72
58
69
81
77
107
83
85
86
85
106
110
97
106
98
99
88
92
96
89
105
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
Calculations are performed before rounding to avoid round-off errors in calculated results
-------
02-SEP-1998 06:58:31 PM Dioxin Furan Unknown RESULTS
GC Column : DB-5
Data file : 20AU98U
Weight .- 0.333
Name
dlO-2-Methylnaphthalene
d8-Naphthalene
Naphthalene
2-Methylnaphthalene
d8-Acenaphthylene
Acenaphthylene
dlO-Acenaphthene
Acenaphthene
dlO-Anthracene
dlO-Fluorene
Fluorene
dl0 -Phenanthrene
Phenanthrene
Anthracene
d!4-Terphenyl
dl0 -Fluoranthene
Fluoranthene
dlO-Pyrene
Pyrene
dl2-Benzo(a)anthracene
Benzo(a)anthracene
d!2-Chrysene
Chrysene
d!2-Benzo(e)pyrene
d!2-Benzo(b)fluoranthene
Benzo(b)fluoranthene
d!2-Benzo(k)fluoranthene
Benzo(k)fluoranthene
d!2-Benzo(a)pyrene
Benzo(e)pyrene
Benzo(a)pyrene
dl2-Perylene
Perylene
d!2-Indeno(123 -cd)pyrene
Indeno(123-cd)pyrene
d!4-Dibenz(ah)anthracene
Dibenz(ah)anthracene
d!2-Benzo(ghi)perylene
Benzo(ghi)perylene
Results : 20AU98U081.RES
Date analyzed
300681-1LS :LCS :Train :P Ex Cal
Total Isotope R. T. RRF
Response Ratio mm:ss
124826200
165852400
196776400
114115800
160170400
153484800
92737800
97812800
81470000
78697000
117807400
183094800
163132000
160563400
161216800
172409400
183518800
179174800
207492000
127227200
137158200
182689000
194576400
229824000
141316600
140955000
204608000
226856000
151954400
244286000
148278000
129968400
163100800
156502800
87400000
90660000
109157800
151570800
154271200
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
11:
8:
9:
11:
14:
14:
14:
14:
19:
16:
16:
19:
19:
19:
24:
23:
23:
24:
24:
28:
28:
28:
28:
32:
31:
31:
31:
31:
32:
32:
32:
33 :
33:
37:
38:
38:
38:
39:
39:
9
56
0
15
13
16
46
52
47
28
34
37
42
51
53
32
35
14
17
5
10
13
18
37
38
44
44
49
50
44
56
9
15
59
7
0
12
23
33
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
1
1
1
0
1
0
0
0
1
1
1
2
0
0
1
1
1
1
1
0
1
1
0
1
0
1
0
1
0
1
1
0
1
0
0
0
1
0
0
.00
.25
.05
.77
.55
.86
.88
.93
.00
.13
.05
.63
.84
.83
.00
.01
.04
.01
.11
.82
.06
.06
.97
.00
.63
.07
.90
.16
.75
.46
.02
.61
.62
.71
.61
.44
.11
.63
.99
50
53
169
134
41
166
42
170
50
42
214
42
158
158
50
53
153
54
157
48
153
53
164
50
49
140
49
144
44
164
143
46
116
48
137
44
162
52
154
.00
.33
.14
.04
.39
.65
.34
.32
.00
.76
.08
.74
.86
.82
.00
.13
.61
.91
.02
.41
.39
.23
.65
.00
.11
.08
.68
.07
.01
.84
.12
.01
.45
.19
.12
.71
.49
.31
.27
PAHAIR.TRG
20-AUG-98
PAHAIRO81998U.RR
ng/ Rec/
SAMP MDL
107
83
85
86
85
106
110
97
106
98
99
88
92
96
105
-------
02-SEP-1998 06:58:28 PM Dioxin Furan Unknown RESULTS
20AU98U081.RES
Date analyzed
LCS :Train :P Ex Cal
Isotope R. T. RRF
Ratio itim:ss
1.00 Y 11: 9 Y
1.00 Y 8: 56 Y
1.00 Y 9: 0 Y
1.00 Y 11: 15 Y
PAHAIR.TRG
20-AUG-98
PAHAIR081998U.RRF
ng/ Rec/
SAMP MDL
1.00 50.00
1.25 53.33
1.05 169.14
0.77 134.04
0.333
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
14:
14:
14:
14:
19:
16:
16:
19:
19:
19:
24:
23:
23:
24:
24:
28:
28:
28:
28:
32:
31:
31:
31:
31:
32:
32:
32:
33:
33:
37:
38:
38:
38:
39:
39:
13
16
46
52
47
28
34
37
42
51
53
32
35
14
17
5
10
13
18
37
38
44
44
49
50
44
56
9
15
59
7
0
12
23
33
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
1
0
0
0
1
1
1
2
0
0
1
1
1
1
1
0
1
1
0
1
0
1
0
1
0
1
1
0
1
0
0
0
1
0
0
.55
.86
.88
.93
.00
.13
.05
.63
.84
.83
.00
.01
.04
.01
.11
.82
.06
.06
.97
.00
.63
.07
.90
.16
.75
.46
.02
.61
.62
.71
.61
.44
.11
.63
.99
41
166
42
170
50
42
214
42
158
158
50
53
153
54
157
48
153
53
164
50
49
140
49
144
44
164
143
46
116
48
137
44
162
52
154
.39
.65
.34
.32
.00
.76
.08
.74
.86
.82
.00
.13
.61
.91
.02
.41
.39
.23
.65
.00
.11
.08
.68
.07
.01
.84
.12
.01
.45
.19
.12
.71
.49
.31
.27
107
83
85
86
85
106
110
97
106
98
99
88
92
96
89
105
62413100
82926200
98388200
57057900
80085200
76742400
46368900
48906400
40735000
39348500
58903700
91547400
81566000
80281700
80608400
86204700
91759400
89587400
103746000
63613600
68579100
91344500
97288200
114912000
70658300
70477500
102304000
113428000
75977200
122143000
74139000
64984200
81550400
78251400
43700000
45330000
54578900
75785400
77135600
62413100
82926200
98388200
57057900
80085200
76742400
46368900
48906400
40735000
39348500
58903700
91547400
81566000
80281700
80608400
86204700
91759400
89587400
103746000
63613600
68579100
91344500
97288200
114912000
70658300
70477500
102304000
113428000
75977200
122143000
74139000
64984200
81550400
78251400
43700000
45330000
54578900
75785400
77135600
-------
22-AUG-1998 05:40:09 PM
PAH Unknown RESULTS
Mass Spec : ULTIMA
GC Column : DB-5
Data file : 20AU98U
Weight : 0.333
Name
dlO-2-Methylnaphthalene
d8-Naphthalene
Naphthalene
2-Methylnaphthalene
d8-Acenaphthylene
Acenaphthylene
dlO-Acenaphthene
Acenaphthene
dlO-Anthracene
dlO-Fluorene
Fluorene
dl0-Phenanthrene
Phenanthrene
Anthracene
d!4-Terphenyl
dlO-Fluoranthene
Fluoranthene
dlO-Pyrene
Pyrene
d!2-Benzo(a)anthracene
Benzo(a)anthracene
d!2-Chrysene
Chrysene
d!2-Benzo(e)pyrene
d!2-Benzo(b)fluoranthene
Benzo(b)fluoranthene
d!2-Benzo(k)fluoranthene
Benzo(k)fluoranthene
d!2-Benzo(a)pyrene
Benzo(e)pyrene
Benzo(a)pyrene
d!2-Perylene
Perylene
d!2-Indeno(123-cd)pyrene
Indeno(12 3 -cd)pyrene
d!4-Dibenz(ah)anthracene
Dibenz(ah)anthracene
d!2-Benzo(ghi)perylene
Benzo(ghi)perylene
Results : 20AU98U081.RES
Date analyzed
-J- Cal
RRF
300681-1LS :LCS :Train :P Ex
Total Isotope R. T.
Response Ratio
124826200
165852400
196776400
114115800
160170400
153484800
92737800
97812800
81470000
78697000
117807400
183094800
163132000
160563400
161216800
172409400
183518800
179174800
207492000
127227200
137158200
182689000
194576400
229824000
141316600
140955000
204608000
226856000
151954400
244286000
148278000
129968400
163100800
156502800
159101000
90660000
109157800
151570800
154271200
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
nun: ss
11:
8:
9:
11:
14:
14:
14:
14:
19:
16:
16:
19:
19:
19:
24:
23:
23:
24:
24:
28:
28:
28:
28:
32:
31:
31:
31:
31:
32:
32:
32:
33:
33:
37:
38:
38:
38:
39:
39:
9
56
0
15
13
16
46
52
47
28
34
37
42
51
53
32
35
14
17
5
10
13
18
37
38
44
44
49
50
44
56
9
15
59
7
0
12
23
33
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y'
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
: PAHAIR.TRG
: 20-AUG-98
: PAHAIR081998U.RR
ng/ Rec/
SAMP MDL
1.00 50.00
1.25 53.33 107
1.05 169.14 0.000
0.77 134.04 0.000
1.55 41.39 83
0.86 166.65 0.000
0.88 42.34 85
0.93 170.32 0.000
1.00 50.00
1.13 42.76 86
1.05 214.08 0.000
2.63 42.74 85
0.84 158.86 0.000
0.83 158.82 0.000
1.00 50.00
1.01 53.13 106
1.04 153.61 0.000
1.01 54.91 110
1.11 157.02 0.000
0.82 48.41 97
1.06 153.39 0.000
1.06 53.23 106
0.97 164.65 0.000
1.00 50.00
0.63 49.11 98
1.07 140.08 0.000
0.90 49.68 99
1.16 144.07 0.000
0.75 44.01 88
1.46 164.84 0.000
1.02 143.12 0.000
0.61 46.01 92
1.62 116.45 0.000
0.71 48.19 96
0.61 249.61 0.000
0.44 44.71
1.11 162.49
0.63 52.31 105
0.99 154.27 0.000
-------
File:20AU98U #1-476 Acq:20-AUG-1998 20:46:35 GC EI+ Voltage SIR Autospec-Ultima
Sample#8 Text:300681-lLS :LCS :Train :
128.0626 5:8
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-------
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File:20AU98U #1-476 Acq:20-AUG-1998 20:46:35 GC EI+ Voltage SIR Autospec-Ultima
Samplers Text:300681-lLS :LCS :Train :PExp:PAHAlR
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-------
File:20AU98U #1-476 Acq:20-AUG-1998 20:46:35 GC EI+ Voltage SIR Autospec-Ultima
Sample/PS Text:300681-lLS :LCS :Train :P ExprPAHAIR
CO
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-------
CO
FiIe:20AU98U #1-665 Acq:20-AUG-1998 20:46:35 GC EI+ Voltage SIR Autospec-UItima
Sample#8 Text:300681-lLS :LCS :Traln :P Exp:PAHAER
166.0798 S:8 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 % A5.89E7
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File:20AU98U #1-665 Acq:20-AUG-1998 20:46:35 GC EI+ Voltage SIR Autospec-Ultlma
Sample#8 Text:30068MLS :LCS :Train :P Exp:PAHAIR
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-------
•Hf
File:20AU98U #1-935 Acq:20-AUG-1998 20:46:35 GC EI+ Voltage SIR Autospec-Ultima
Sampled Text:300681-lLS :LCS :Train :P Exp:PAHAIR
202.0782 S:8 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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File:20AU98U #1-935 Acq:20-AUG-1998 20:46:35 GC EI+ Voltage SIR Autospec-UItima
Sampled Text:300681-lLS :LCS :Train :P Exp:PAHAlR
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FHe:20AU98U #1-935 Acq:20-AUG-1998 20:46:35 GC EI+ Voltage SIR Autospec-Ultima
Sampled Text:300681-lLS :LCS -.Train :P Exp:PAHAIR
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File:20AU98U #1-955 Acq:20-AUG-1998 20:46:35 GC EI+ Voltage SIR Autospec-Ultima
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FUe:20AU98U #1-955 Acq:20-AUG-1998 20:46:35 GC EI+ Voltage SIR Autospec-Ultima
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File:20AU98U #1-955 Acq:20-AUG-1998 20:46:35 GC EI+ Voltage SIR Autospec-UItima
Sampled Text:300681-lLS :LCS :Train :P Exp:PAHAlR
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File:20AU98U #1-955 Acq:20-AUG-1998 20:46:35 GC EH- Voltage SIR Autospec-Ultima
Sample#8 Text:300681-lLS :LCS -.Train :P Exp:PAHAIR
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€tj>uanterra
QUANTERRA INCORPORATED
West Sacramento
Initial Calibration Checklist
High Resolution
ICAL ID?rtVlXog/qq3U.gfcf' Method ID
Column ID ^P3'5 _ Instrument ID L?
STD rr>'
Analyzed By ft .
Prepared By f}
j ?g5-Q^D t?Hgiytnltiplier Setting
Date Analyzed
Date Prepared
Reviewed By
Date Reviewed
COMMENTS:.®.
?AVl
Environmental
Services
v/ .
- y ^AXXStStGKiKAL--- ; - «; 'w,^, -- -
Curve summary present?
CS1-CS5, CPSM, solvent blank present?
Copy of logfile present?
CPSM Blow-up/Static resolution check present?
Target file RT's correct?
RRFs within method-specified limits?
Signal-to-noise criteria met?
Isotopic ratios within limits?
High point free of saturation?
Chromatographic windows correct?
CPSM valley < 25%?
Manual reintegrations checked and hardcopies
included?
*, - mmAsmmim
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Method 8290: %RSD < 20% for natives, < 30% for labelled analytes: S/N > 10
Method 1613A: %CV< 35% (See Table 7, Method 1613A); S/N > 10
Method 23: %RSD < values specified in Table 5, Method 23; S/N > 2.5
PAH: %RSD < 30% for natives and labelled compounds: S/N > 10
PCB: %RSD < 25% for natives. < 30% for labelled compounds: S/N > 2.5
NCASI 551: %RSD < 20% for natives and labelled compounds: > 5
DBD/DBF: %RSD < 30% for natives and labelled compounds; S/N > 10
QA-384NE2/97
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20-AUG-1998 02:19:39 PN
PAH CALIBRATION TASLE
10
Mass Spec : ULTIMA
GC Column : DB-5
265-04A.-04B. 651-21, 265-04D.-04E; Multiplier a 260V.
Dibenz(ah)anthracene
d12-Benzo(ghi)perylene
Benzo(ghi)perylene
13C-Naphthalene
13C-Fluorene
File name : PAHA1R081998U.RRF
Date analyzed : 19-AUG-98
INITIAL CALIBRATION CURVE
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Mean
1.11
0.63
0.99
1.00
1.00
S.O.
0.036
0.060
0.034
0.000
0.000
XRSO
3.270
9.532
3.467
0.000
0.000
1
10.00
10.79
1.08
100.00
60.66
0.61
10.00
10.00
1.00
100.00
1.00
1.00
100.00
1.00
1.00
2
50.00
56.20
1.12
100.00
64.91
0.65
50.00
50.38
1.01
100.00
1.00
1.00
100.00
1.00
1.00
3
100.00
115.84
1.16
100.00
61.14
0.61
100.00
103.43
1.03
100.00
1.00
1.00
100.00
1.00
1.00
4
200.00
225.91
1.13
100.00
56.21
0.56
200.00
190.98
0.95
100.00
1.00
1.00
100.00
1.00
1.00
5
500.00
535.81
1.07
100.00
72.26
0.72
500.00
478.29
0.96
100.00
1.00
1.00
100.00
1.00
1.00
10
-------
20-AUG-1998 09:38:36 AM
PAH leal RESULTS
Mass Spec : ULTIMA
3C Column : DB-5
Data file : 19AU98U
tfeight : 1
Name
dlO-2-Methylnaphthalene
d8-Naphthalene
Naphthalene
2-Methylnaphthalene
d8-Acenaphthylene
Acenaphthylene
dlO-Acenaphthene
Acenaphthene
dlO-Anthracene
dlO-Fluorene
Fluorene
dl0-Phenanthrene
Phenanthrene
Anthracene
d!4-Terphenyl
dl 0-Fluoranthene
Fluoranthene
dlO-Pyrene
Pyrene
d!2-Benzo(a)anthracene
Benzo(a)anthracene
d!2-Chrysene
Chrysene
d!2-Benzo(e)pyrene
d!2-Benzo(b)fluoranthene
Benzo(b)fluoranthene
d!2-Benzo(k)fluoranthene
Benzo(k)fluoranthene
d!2-Benzo(a)pyrene
Benzo(e)pyrene
Benzo(a)pyrene
d!2-Perylene
Perylene
d!2-Indeno(123-cd)pyrene
Indeno(123-cd)pyrene
d!4-Dibenz(ah)anthracene
Dibenz(ah)anthracene
d!2-Benzo(ghi)perylene
Benzo(ghi)perylene
dlO-Fluorene
13C-Fluorene
Results : 19AU98U011.RES
Date analyzed
ST0819 :PAH CS-1 :265-4A Ex
Total Isotope R. T. RRF
Response Ratio tnmrss
384118000 1.00 Y 11: 9 Y
480650000 1.00 Y 8: 58 Y
65289400 1.00 Y 9: 2 Y
44629600 1.00 Y 11: 16 Y
648198000 1.00 Y 14: 13 Y
55444200 1.00 Y 14: 16 Y
331750000 1.00 Y 14: 47 Y
33717200 1.00 Y 14: 53 Y
241516000 1.00 Y 19: 47 Y
312842000 1.00 Y 16: 29 Y
34982600 1.00 Y 16: 35 Y
PAHAIRCAL1.TRG
19-AUG-98
632978000 1.00 Y
57229600 1.00 Y
54911200 1.00 Y
596780000 1.00 Y
567796000 1.00 Y
62147000 1.00 Y
588356000 1.00 Y
67727800 1.00 Y
508128000 1.00 Y
53508800 1.00 Y
608616000 1.00 Y
64472400 1.00 Y
19: 38 Y
19: 42 Y
19: 51 Y
24: 54 Y
23: 32 Y
23: 35 Y
24:
24:
28:
28:
28
28
705306000 1.00 Y 32:
454992000 1.00 Y 31:
49181800 1.00 Y 31:
622060000 1.00 Y 31:
79232400 1.00 Y 31:
532350000 1.00 Y 32:
80983000 1.00 Y 32:
59236000 1.00 Y 32:
429470000 1.00 Y 33:
75514600 1.00 Y 33:
483778000 1.00 Y 37:
30600000 1.00 Y 38:
308436000 1.00 Y 37:
33295000 1.00 Y 38:
427814000 1.00 Y 39:
42781000 1.00 Y 39:
312842000 1.00 Y 16:
* No Peak 0.00 N 16
14 Y
18 Y
5 Y
10 Y
12 Y
18 Y
37 Y
38 Y
43 Y
43 Y
49 Y
49 Y
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55 Y
8 Y
15 Y
56 Y
4 Y
58 Y
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30 Y
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.00
0
0
0
0
0
0
.000
.000
.000
.000
.000
•«B>
-------
20-AUG-1998 02:16:09 PM
PAH leal RESULTS
Spec : ULTIMA
3C Column : DB-5
Data file : 19AU98U
height : 1
Name
dlO-2-Methylnaphthalene
d8-Naphthalene
Naphthalene
2-Methylnaphthalene
d8-Acenaphthylene
Acenaphthylene
dlO-Acenaphthene
Ac enaphthene
dlO-Anthracene
dlO-Fluorene
Fluorene
dl0-Phenanthrene
Phenanthrene
Anthracene
d!4-Terphenyl
dl0-Fluoranthene
Fluoranthene
dlO-Pyrene
Pyrene
d!2-Benzo(a)anthracene
Benzo(a)anthracene
d!2-Chrysene
Chrysene
d!2-Benzo(e)pyrene
d!2-Benzo(b)fluoranthene
Benzo(b)fluoranthene
d!2-Benzo(k)fluoranthene
Benzo(k)fluoranthene
d!2-Benzo(a)pyrene
Benzo(e)pyrene
Benzo(a)pyrene
d!2-Perylene
Perylene
d!2-Indeno(123-cd)pyrene
Indeno(123-cd)pyrene
d!4-Dibenz(ah)anthracene
Dibenz(ah)anthracene
d!2-Benzo(ghi)perylene
Benzo(ghi)perylene
Results : 19AU98U261.RES
Date analyzed
ST0819G :PAH CS-2 :265-4B Ex
Total Isotope R. T. RRF
Response Ratio mm:ss
PAHAIRCAL2.TRG
19-AUG-98.
pg
Rec/
MDL
70655800
97661000
52821400
33092000
102593200
45561000
63379400
30235400
41622200
44113200
19334800
108617000
45664000
44457200
93803800
106255000
54752600
102265800
56310800
84111400
44511000
107935800
54051800
144534400
94962200
49402200
118742400
71234400
107118000
79505400
54722200
88007400
70882600
105228000
35200000
63324600
35590600
93810400
47258200
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.po
.00
.00
.00
.00
.00
.00
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
11:
8:
9:
11:
14:
14:
14:
14:
19:
16:
16:
19:
19:
19:
24:
23:
23:
24:
24:
28:
28:
28:
28:
32:
31:
31:
31:
31:
32:
32:
32:
33:
33:
37:
38:
37:
38:
39:
39:
8
58
2
15
12
15
45
52
46
28
34
37
41
50
52
31
34
13
17
5
9
12
17
37
38
43
44
48
49
43
55
8
14
58
6
59
10
22
32
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
-1.00 100.00
1.38 100.00
1.08 50.00 0.000
0.68 50.00 0.000
1.45 100.00
0.89 50.00 0.000
0.90 100.00
0.95 50.00 0.000
-1.00 100.00
1.06 100.00
0.88 50.00 0.000
2.61
0.84
0.82
-2.00
1.13
1.03
1.09
1.10
0.90
1.06
1.15
1.00
0.00
0.66
1.04
0.82
1.20
0.74
,48
.02
0.61
1.61
0.73
0.67
0.44
1.12
0.65
1.01
100.00
50.00
50.00
100.00
100.00
50.00
100.00
50.00
100.00
50.00
100.00
50.00
100.00
100.00
50.00
100.00
50.00
100.00
50.00
50.00
100.00
50.00
100.00
50.00
100.00
50.00
100.00
50.00
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
-------
20-AUG-1998 09:56:11 AM
PAH leal RESULTS
Mass Spec : ULTIMA
GC Column : DB-5
Data file : 19AU98U
Weight : 1
Name
dlO-2-Methylnaphthalene
d8-Naphthalene
Naphthalene
2-Methylnaphthalene
d8-Acenaphthylene
Acenaphthylene
did-Acenaphthene
Acenaphthene
dlO-Anthracene
dlO-Fluorene
Fluorene
dl0-Phenanthrene
Phenanthrene
Anthracene
d!4-Terphenyl
dlO-Fluoranthene
Fluoranthene
dlO-Pyrene
Pyrene
d!2-Benzo(a)anthracene
Benzo(a)anthracene
d!2-Chrysene
Chrysene
d!2-Benz o(e)pyrene
d!2-Benzo(b)fluoranthene
Benzo(b)fluoranthene
d!2-Benzo(k)fluoranthene
Benzo(k)fluoranthene
dl2-Benzo(a)pyrene
Benzo(e)pyrene
Benzo(a)pyrene
d!2-Perylene
Perylene
d!2-Indeno(12 3-cd)pyrene
Indeno(123-cd)pyrene
d!4-Dibenz(ah)anthracene
Dibenz(ah)anthracene
d!2-Benzo(ghi)perylene
Benzo(ghi)perylene
dlO-Fluorene
13C-Fluorene
Results : 19AU98U031.RES
Date analyzed
ST0819B :PAH CS-3 :651-21 Ex
Total Isotope R. T. RRF
Response Ratio mm:ss
PAHAIRCAL3.TRG
19-AUG-98
pg
Rec/
MDL
422174000
471190000
454076000
400296000
626304000
593376000
350080000
354614000
251124000
285868000
328294000
666764000
601400000
591890000
699008000
671478000
751932000
681704000
797574000
501406000
553002000
641272000
664328000
748758000
474608000
528214000
675052000
814150000
556188000
853248000
588556000
450492000
656086000
522654000
328000000
331568000
384096000
457822000
473540000
285868000
* No Peak
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
0
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
N
11:
8:
9:
11:
14:
14:
14:
14:
19:
16:
16:
19:
19:
19:
24:
23:
23:
24:
24:
28:
28:
28:
28:
32:
31:
31:
31:
31:
32:
32:
32:
33:
33:
37:
38:
37:
38:
39:
39:
16:
16:
8
58
2
15
12
15
46
52
46
28
34
36
41
50
52
30
34
13
16
4
8
11
16
35
36
42
42
46
47
41
53
6
12
52
0
55
6
16
25
28
33
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
N
-1
1
0
0
1
0
0
1
-1
1
1
2
0
0
-2
0
1
0
1
0
1
0
1
-2
0
1
0
1
0
1
1
0
1
0
0
0
1
0
1
-1
0
.00
.12
.96
.85
.48
.95
.83
.01
.00
.14
.15
.66
.90
.89
.00
.96
.12
.98
.17
.72
.10
.92
.04
.00
.63
.11
.90
.21
.74
.53
.06
.60
.46
.70
.63
.44
.16
.61
.03
.00
.00
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
°>9*$
-------
20-AUG-1998 09:57:46 AM
PAH leal RESULTS
Mass Spec ULTIMA
GC Column DB-5
Data file 19AU98U
Weight : l
Name
dlO-2-Methylnaphthalene
d8-Naphthalene
Naphthalene
2-Methylnaphthalene
d8-Acenaphthylene
Acenaphthylene
dlO-Acenaphthene
Acenaphthene
dlO-Anthracene
dlO-Fluorene
Fluorene
dlO-Phenanthrene
Phenanthrene
Anthracene
d!4-Terphenyl
dl0-Fluoranthene
Fluoranthene
dlO-Pyrene
Pyrene
d!2-Benz o(a)anthracene
Benzo(a)anthracene
d!2-Chrysene
Chrysene
dl2-Benzo(e)pyrene
d!2-Benzo(b)fluoranthene
Benzo(b)fluoranthene
d!2-Benzo(k)fluoranthene
Benzo(k)fluoranthene
d!2-Benzo(a)pyrene
Benzo(e)pyrene
Benzo(a)pyrene
d!2-Perylene
Perylene
d!2-Indeno(123-cd)pyrene
Indeno(12 3 -cd)pyrene
d!4-Dibenz(ah)anthracene
Dibenz(ah)anthracene
d!2-Benzo(ghi)perylene
Benzo(ghi)perylene
dlO-Fluorene
13C-Fluorene
Results : 19AU98U041.RES
Date analyzed
ST0819C :PAH CS-4 :265-4D Ex
Total Isotope R. T. RRF
Response Ratio mm:ss
PAHAIRCAL4.TRG
19-AUG-98
pg
Rec/
MDL
258178000
321956000
600734000
450720000
407948000
663388000
239254000
376688000
157468200
170668400
358400000
424762000
639548000
637000000
393644000
391988000
782484000
402524000
853790000
306152000
634006000
424138000
744400000
493252000
310836000
662032000
458844000
998720000
370004000
1063608000
730246000
305370000
1016530000
309102000
350000000
187749200
424146000
277246000
529478000
170668400
* No Peak
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
0.00
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
N
11:
8:
9:
11:
14:
14:
14:
14:
19:
16:
16:
19:
19:
19:
24:
23:
23:
24:
24:
28:
28:
28:
28:
32:
31:
31:
31:
31:
32:
32:
32:
33:
33:
37:
38:
37:
38:
39:
39:
16:
16:
9
57
1
15
12
15
46
53
46
28
34
36
41
50
52
30
34
12
16
4
8
11
16
35
36
42
42
46
47
41
53
6
12
53
0
54
6
16
25
28
33
Y
Y
Y
Y
Y
Y
Y
Y ,
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
N
0
1
0
0
1
0
0
0
-1
1
1
2
0
0
-2
1
1
1
1
0
1
1
0
-2
0
1
0
1
0
1
0
0
1
0
0
0
1
0
0
-1
0
.00
.25
.93
.70
.58
.81
.93
.79
.00
.08
.05
.70
.75
.75
.00
.00
.00
.02
.06
.78
.04
.08
.88
.00
.63
.06
.93
.09
.75
.44
.99
.62
.66
.63
.57
.38
.13
.56
.95
.00
.00
100
100
200
200
100
200
100
200
100
100
200
100
200
200
100
100
200
100
200
100
200
100
200
100
100
200
100
200
100
200
200
100
200
100
200
100
200
100
200
100
100
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
o
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
ft
3®8
-------
20-AUG-1998 09:59:14 AM
PAH leal RESULTS
Mass Spec : ULTIMA
GC Column : DB-5
Data file : 19AU98U
Weight : 1
Name
dlO-2-Methylnaphthalene
d8-Naphthalene
Naphthalene
2-Methylnaphthalene
d8-Acenaphthylene
Acenaphthylene
dlO-Acenaphthene
Acenaphthene
dlO-Anthracene
dlO-Fluorene
Fluorene
dl0-Phenanthrene
Phenanthrene
Anthracene
d!4-Terphenyl
dl0-Fluoranthene
Fluoranthene
dlO-Pyrene
Pyrene
d!2-Benzo(a)anthracene
Benzo(a)anthracene
d!2-Chrysene
Chrysene
dl2-Benzo(e)pyrene
d!2-Benzo(b)fluoranthene
Benzo(b)fluoranthene
dl2-Benzo(k)fluoranthene
Benzo(k)fluoranthene
d!2-Benzo(a)pyrene
Benzo(e)pyrene
Benzo(a)pyrene
dl2-Perylene
Perylene
d!2-Indeno(12 3-cd)pyrene
Indeno(123-cd)pyrene
d!4-Dibenz(ah)anthracene
Dibenz(ah)anthracene
d!2-Benzo(ghi)perylene
Benzo(ghi)perylene
dlO-Fluorene
13C-Fluorene
Results : 19AU98U051.RES
Date analyzed
ST0819D :PAH CS-5 :265-4E Ex
Total Isotope R. T. RRF
Response Ratio mm:ss
PAHAIRCAL5.TRG
19-AUG-98
pg
Rec/
MDL
312318000
384698000
1787952000
1342716000
483206000
1963764000
271792000
1193762000
196074200
209792000
1108328000
502286000
2036380000
2063520000
451978000
448256000
2150020000
445760000
2349400000
376244000
1931110000
522746000
2305500000
571326000
322248000
1685828000
539896000
2725660000
438166000
2945800000
2058000000
362286000
2899860000
453826000
1276000000
289594000
1551682000
412828000
1974510000
209792000
60319
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
1.00
1.
00
1.00
1.00
1.
1.
.00
.00
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
11:
8:
9:
11:
14:
14:
14:
14:
19:
16:
16:
19:
19:
19:
24:
23:
23:
24:
24:
28:
28:
28:
28:
32:
31:
31:
31:
31:
32:
32:
32:
33:
33:
37:
37:
37:
38:
39:
39:
16:
16:
8
58
2
15
12
14
46
52
45
28
33
36
40
49
52
30
34
13
16
4
8
11
15
35
36
41
42
46
47
41
52
5
11
51
59
54
4
15
24
28
33
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
-1.
1.
0.
0.
1.
0.
0.
0.
-2.
1.
1.
2.
0.
0.
-2.
0.
0.
0.
1.
0.
1.
1.
0.
-2.
0.
1.
0.
1.
0.
1.
0.
0.
1.
0.
0.
0.
1.
0.
0,
-1
0
00
23
93
70
55
81
87
88
00
07
06
56
81
82
00
99
96
99
05
83
03
16
88
00
56
05
94
01
77
34
94
.63
.60
,79
.56
.51
.07
.72
.96
.00
.00
100.
100.
500.
500.
100.
500.
100.
500.
100.
100.
500.
100.
500.
500.
100.
100.
500.
100.
500.
100.
500.
100.
500.
100.
100.
500.
100.
500.
100.
500.
500.
100.
500.
100.
500.
100.
500.
100.
500.
100.
100.
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
.00
.00
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
oVo-ot
-------
:0m<:?20 J
FILE SAMP
No.
(1)
LAB.
SAMP No
CUSTOMER
ID
CLEAN CLEAN
UP 1 UP 2
(SDS) (D2)
TYPE CONCn.
(1)
19AU98U
19AU98U
19AU98U
19AU98U
19AU98U
19AU98U
19AU98U
19AU98U
19AU98U
19AU98U
19AU98U
19AU98U
19AU98U
19AU98U
19AU98U
19AU98U
19AU98U
19AU98U
19AU98U
19AU98U
19AU98U
19AU98U
19AU98U
19AU98U
19AU98U
19AU98U
19AU98U
19AU98U
19AU98U
19AU98U
19AU98U
19AU98U
19AU98U
19AU98U
19AU98U
19AU98U
19AU98U
19AU98U
19AU98U
19AU98U
19AU98U
19AU98U
19AU98U
19AU98U
19AU98U
19AU98U
19AU98U
19AU98U
19AU98U
19AU98U
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
ST0819
ST0819A
ST0819B
ST0819C
ST0819D
SB0819
ST0819E
ST0819F :
SB0819A
300569-1MB
300569-1LC
300533-1
300533-3
300533-6
300533-2
300533-5
300533-8
300569-1
300569-2
300569-3
300569-4
300569-5
300569-6
300569-7
SB0819B
ST0819G
PAH CS-1
PAH CS-2
PAH CS-3
PAH CS-4
PAH CS-5
Solvent Blank
PAH CS-3
respike Cal Std
Solvent Blank
Method Blank
LCS
G-2056,58
G-2059,61
G-2072,74
G-2057
G-2060
G-2073
ARF-001-05
ARF-001-06
ARF-001-07
ARF-001-08
ARF-001-09
ARF-001-10
ARR-001-01
Solvent Blank
PAH CS-2
AMA 08/19/98
265-4A
265-4B
651-21
265-4D
265-4E
C8
651-21
C8
Soil
Soil
Air
Air
Air
Air
Air
Air
Soil
Soil
Soil
Soil
Soil
Soil
Soil
C8
265-4B
PAH
PAH
PAH
PAH
PAH
PAH
PAH
PAH
PAH
PAH
PAH
PAH
PAH
PAH
PAH
VSE-22
VSE-22
VSE-22
1
1
1
1
1
1
1
1
1
5.0
5.0
0.50
0.50
0.50
0.50
0.50
0.50
,01
,00
.01
,02
.00
5.05
5.02
1
1
5,
5
5
5
5
355
-------
*
Peak Locate Examination:19-AUG-1998:15:44 File:19AU98U
Experiment:PAHAIR Function:! Reference:PFK
Volts
1.8422
118.98012 118.99202 119.00392
Volts
3.6155
130.97892 130.99202 131.00512
PPM
200
142.97772 142.99202 143.00632
Volts
0.2406
149.97542 149.99042 150.00542
PPM
200
Volts
0.0354
154.97652 154.99202 155.00752
PPM
200
_/
* — •
n
/
/
fi
Volts
1.4556
\
1.
^ v^.
168.97192 168.98882 169.00571
-------
o
CO
CO
Peak Locate Examination:19-AUG-1998:15:46 File:19AU98U
Experiment:PAHAIR Function:2 Reference:PFK
PPM
200
Volts
0.0261
154.97652 154.99202 155.00752
PPM
200
Volts
1.2518
168.97192 168.98882 169.00571
Volts
4.2005
180.97072 180.98882 181.00691
Volts
0.2511
192.96952 192.98882 193.00811
PPM
200
Volts
0.0955
204.96832 204.98882 205.00931
-------
CO
00
Peak Locate Examination:19-AUG-1998:15:47 File:19AU98U
Experiment:PAHAIR Function:3 Reference:PFK
Volts
0.2180
192.96952 192.98882 193.00811
Volts
1.5087
230.96253 230.98563 231.00872
Volts
0.0746
204.96832 204.98882 205.00931
Volts
0.5128
218.96373 218.98563 219.00752
Volts
0.7095
242.96133 242.98563 243.00992
254.96013 254.98563 255.01112
-------
Peak Locate Examination:19-AUG-1998:15:50 File:19AU98U
Experiment:PAHAIR Function:4 Reference:PFK
Volts
0.6461
242.96133 242.98563 243.00992
Volts
0.1339
254.96013 254.98563 255.01112
Volts
0.2158
268.95555 268.98245 269.00935
Volts
0.8690
280.95435 280.98245 281.01055
-------
CD
File:19AU98U #1-476 Acq:19-AUG-1998 15:50:38 GC EI+ Voltage SIR Autospec-Ultima
Sample#l Text:ST0819 :PAH CS-1 :265-4A Exp:PAHAlR
128.0626 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
00 S
80-
60
40
20 J
A3.2
9:00
SE7
10:6fl H:6o 12:6o 13:(
134.0827 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
80
60-
40_
20
U_l 1 , , , 1 , , , , , r
9:00 10:00
136.1128 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
L8.4E6
6.3E6
-4.2E6
L2.1E6
LO.OEO
Time
100 9
80 J
60 J
40J
2Q1
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, A2.40E8
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L4.7E7
L3.1E7
Ll.6E7
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1003
80 J
60 J
40J
20 J
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0-
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L1.3E6
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410 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
A1.92E8 F6.2E7
9:60
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10:6o 11:00 12:6o 13:1
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-------
File:19AU98U #1-476 Acq:19-AUG-1998 15:50:38 GC EI+ Voltage SIR Autospec-Ultima
Sample*! Text:ST0819 :PAH CS-1:265-4A Exp:PAHAlR
152.0626 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
80
60
40:
20:
o
A2.77E7
A2.49E6
A8.89E6
CD
8.9E6
:7.1E6
5.4E6
:3.6E6
:1.8E6
O.OEO
Time
1*06 ' ' U:ll ' ' '13:24 ' ' 'l3:ti ' ' 'l3:48 ' ' 'l4:66 ' ' 'l4:i2 ' ' 14:24 ' ' 'l4:36 14:48 15:6o 15:12 15:24 15:36
160.1128 SMO(1,3) PKD(5,3>3,0.10%,10000.0,0.00%,F,T)
100%
80
60 4
40
20 J
A3.24E8
A6.02E7
" 1—i—i—i—i—i—i—i—i—i—i—I—i—i—i—i—r—i—i—i—i—i—i—i—i—i—r—i—i—i—i—i—i—i '\ i—i—if I I—i—\—i—i—i—i—I—i—i—i—r-i—i r" l—I—i—i r—i i i i i I i i i i ' i • i i i ' I '
13:60 13:12 13:24 13:36 13:48 14:6fl 14:12 14:24 14:36 14:48 15:00 15:12 15:24 15:36
154.0782 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 S.
80:
60
40
20 J
.8.2E7
:6.1E7
:4.1E7
-2.0E7
O.OEO
Time
A1.69E7
A5.58E5
A1.11E6
A5.89E5 A1.22E5
A2.72E5
A2.92E5
—i—i—i—r—i—i—i—i—i—i—l—i—r—l—I—i—i—I—i—I—i—i—i—I—t—i—i—i—i—i—i—I—i—i—i—i—i—i—I—i—i—I—i—i—i—i—i—[—i—i—i—i—i—I—i—i—r—i—r—r—i i—r r r r—i i i i I r~i ' " ''T~*r~
)0 13:12 13:24 13:36 13:48 14:6o 14:12 14:24 14:36 14:48 15:00 15:12 15:24 15:36
5.4E6
4.4E6
-3.3E6
:2.2E6
- O.OEO
Time
13:
164.1410 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
00 S
80:
60:
40:
20:
0
13:
p A1.66E8
A
A
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5.2E7
:4.2E7
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O.OEO
Time
-------
to
File:19AU98U #1-476 Acq:19-AUG-199815:50:38 GC EI+ Voltage SIR Autospec-Ultima
Sample*! Text:ST0819 :PAH CS-1 :265-4A Exp:PAHAlR
U0.9
100 S
95:
90:
85:
80:
75:
70:
65:
60:
55:
50:
45:
40:
35:
30:
25:
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15-
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5_
0-
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3.2E8
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12.3E8
:2.1E8
-2.0E8
:1.8E8
Ll.6E8
1.4E8
-1.2E8
-1.1E8
:8.9E7
17.1E7
:5.3E7
L3.6E7
:1.8E7
O.OEO
Time
-------
File:19AU98U #1-666 Acq:19-AUG-1998 15:50:38 GC EI+ Voltage SIR Autospec-Ultima
Sample*! Text:ST08I9 :PAH CS-1 :265-4A Exp:PAUAlR
166.0798 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 % A1.73E7
90 j
80 J
70 J
60_
50
40
30 j II A5.20E6
20 J
A2.62E6
_J\
18:66 18:i2
CD
6.8E6
6.1E6
L5.4E6
L4.7E6
L4.1E6
L3.4E6
L2.7E6
L2.0E6
L1.4E6
L6.8E5
LO.OEO
Time
i 1*1*1 i i I i i i i i I i i i i i i i i i i i | i i i i i I i
15:48 16:00 16:12 16:24 16:36 16:48
172.0984 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
17
iKT
17
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17:48
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80 J
70 J
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50
40
30
20-
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16:29
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176.1410 F:2 SMO(1,3) PKD(5,3,3I0.10%,10000.0,0.00%,F,T)
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7:6o 17:12 *7:24 17:36 17:48 18:6fl 18:12 18:24
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L4.7E3
L4.1E3
3.4E3
L2.7E3
L2.0E3
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6.8E2
O.OEO
Time
6.2E7
L5.6E7
L5.0E7
L4.3E7
3.7E7
L3.1E7
2.5E7
L1.9E7
1.2E7
6.2E6
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Time
17
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80 J
10 :
60 1
401
30^
20 1
10^
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j ^
15:48 16:6o 16:12 16:24 16:36 16:48 17:6o 17:12 17:24 17:36 17:48 18:00 18:12 18:24
-------
File:19AU98U #1-666 Acq:19-AUG-1998 15:50:38 GC EI+ Voltage SIR Autospec-Uttima
Sample'! Text:ST0819 :PAH CS-1 :265-4A Exp:PAHAIR
CO
I/8.U
1009
90J
80.
70:
60:
50:
40:
30 J
20 1
10 J
18:
188.1
1002
90:
80:
70:
60:
50 J
40J
30:
20:
10 J
o
18:
lot r.t om\j\.i,j) riwL»v3,.j>;>,w.iw7»,iwww.v,u.vu70,r,i;
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L 19:60 20:60 21:00 22:i
410 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
A3.16E8
.
A1.21E8
W
^
10 19:60 20:60 21:6o 22:1
1.1E7
_1.0E7
-9.0E6
:7.9E6
L6.8E6
5.6E6
4.5E6
L3.4E6
2.3E6
1.1E6
1)0 Time
1.3E8
-1.1E8
-1.0E8
-8.9E7
_7.7E7
-6.4E7
-5.1E7
-3.8E7
L2.6E7
L1.3E7
: O.OEO
M) Time
-------
File:19AU98U #1-666 Acq:19-AUG-1998 15:50:38 GC EI+ Voltage SIR Autospec-Ultima
Sample*! Text:ST0819 :PAH CS-1 :265-4A Exp:PAHAIR
ui.ye
009
95:
!
on
xv -
85:
80:
•
75:
•
70:
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17:6fl
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-------
File:19AU98U #1-934 Acq:19-AUG-1998 15:50:38 GC EI+ Voltage SIR Autospec-Ultima
Sample*! Text:ST0819 :PAH CS-1 :265-4A £xp:PAHAIR
202.0782 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
90
80,
70-
60
50-
40_
30-
20 J
10 J
0
22:
212.
100
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80 J
70 J
60 J
50 J
40 J
30 J
20
10
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03
CD
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L1.1E7
L9.6E6
L8.4E6
L7.2E6
L6.0E6
L4.8E6
L3.6E6
L2.4E6
L1.2E6
LO.OEO
Time
-1.1E8
L1.0E8
L9.0E7
L7.9E7
L6.8E7
L5.6E7
L4.5E7
L3.4E7
L2.3E7
L1.1E7
LO.OEO
Time
-1.2E8
L1.1E8
L9.4E7
L8.2E7
L7.0E7
L5.9E7
L4.7E7
L3.5E7
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LO.OEO
Time
i i i i i I i I1" ' ' i i
)0 23:60
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A2.84E8
24:C
25:fl
26:1
A2.94E8
1 p 1 1 1 r 1 1 "T =r~
22:00 23:00
244.1974 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 S.
90 J
80 J
70 J
60 J
50 J
40J
30 J
20 J
10 J
24:C
0
22:00
26:1
23:(
24:1
25:C
26:1
-------
File:19AU98U #1-934 Acq:19-AUG-1998 15:50:38 GC EI+ Voltage SIR Autospec-UHima
Sample*! Text:ST0819 :PAH CS-1 :26S-4A Exp:PAHAIR
228.0939 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 S
90-
80-
70-
60_
50-
40J
30 j
20.:
10 1
0
240.1
100 S
90-
80_
70-
60-
50:
40J
30-
20-
0-
' A2.68E7
I (1
'
11
1 I V___
26:36 26:48 27:66 27: ii 27:24 27:36 27:48 28:66 28: ii 28:24 28:36 28:48 29:66 29:ii 29:24 29:36 29:48 30:1
692 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
p A2 4E8
|
1
1 V—
26:36 26:48 27:66 27:ii 27:24 27:36 27:48 28:6fl 28:ii 28:24 28:36 28:48 29:66 29:ii 29:24 29:36 29:48 30:
8.9E6
L8.1E6
:7.2E6
-6.3E6
5.4E6
L4.5E6
L3.6E6
:.2.7E6
:1.8E6
:8.9E5
O.OEO
)0 Time
8.9E7
L8.1E7
1.7.2E7
L6.3E7
L5.4E7
-4.5E7
-3.6E7
-2.7E7
-1.8E7
-8.9E6
-O.OEO
0 Time
-------
SB^S
oeg ?T
-------
File:19AU98U #1-955 Acq:19-AUG-1998 15:50:38 GC EI+ Voltage SIR Autospec-UItima
Sample*! Text:ST0819 :PAH CS-1 :265-4A Exp:PAHAIR
252.0939 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
UU3
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264.1692 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
90 4
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30
20 4
10
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A3.53E8
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8.6E7
1.7.8E7
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JLO.OEO
Time
-------
00
File:19AU98U #1-955 Acq:19-AUG-1998 15:50:38 GC EI+ Voltage SIR Autospec-Ultima
Sample*! Text:ST0819 :PAH CS-1 :265-4A Exp:PAHAIR
276.0939 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 % A1.53E7
90:
80
70
60
50 j
40J
30-
201
10 J
2.1E6
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1.7E6
1.5E6
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O.OEO
Time
36:48 37:60 37: U 37:24 37:36 37:48 38:66 38:12
278.1096 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
A1.66E7
90_
80
70
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40
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38:24 38:36 38:48 39:00
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1.3E6
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36:48
37:00 37:12 37:24 37:36 37:48 38:00 38:12 38:24 ' 38:36 38:48 39:66 39:12
-------
e:19AU98U #1-955 Acq:19-AUG-1998 15:50:38 GC EI+ Voltage SIR Autospec-Ultima
Sample*! Text:ST0819 :PAH CS-1 :265-4A Exp:PAHAlR
276.0939 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
80
60
40
20
0.
36:(
A2.39E7
14E7
10
37:00
38:6o
288.1692 F:4SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 % A2.42E8
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39:00
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278.1096 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 % A1.66E7
60:
40
20
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36:60 37:60 38:6o
292.1974 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 % A1.54E8
80
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-------
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JfN.
e:19AU98U #1-477 Acq:20-AUG-1998 11:12:26 GC EI+ Voltage SIR Autospec-UItima
Sample#26 Text:ST0819G :PAH CS-2 :265-4B Exp:PAHAIR
128.0626 S:26 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
1003
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L2.8E3
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r1.4E7
12:6fl 13:1
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0 Time
-------
File:19AU98U #1-477 Acq:20-AUG-1998 11:12:26 GC EI+ Voltage SIR Autospec-Ultima
Sample#26 Text:ST0819G :PAH CS-2 :265-4B Exp:PAHAIR
152.0626 S:26 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 % A2.28E7
80-
60.
40:
20:
A7.45E6
13:66 13:i2 13:24 13:36 13:48 14:66 14:i2 \4:24 14:36 14:48 15:66 15:12 15:24 15:36
160.1128 S:26 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 % A5.13E7
80
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13:00 13:12 13:24 13:36 13:48 14:6o 14:12
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6.5E6
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14:24 14:36 14:48 15:66 15:i2 15:24 15:36
A1.51E7
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-1.2E7
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-3.0E6
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4.6E6
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164.1410 S:26 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
O.OEO
Time
80
60 J
40
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A3.17E7
v 1—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—I—i—i—i—r-i—i—i—i—p-i—i—i—ii I i—i—|—i—i—i—i—i—r—i—i i i i r~" i i i • i •
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9.6E6
1.7.7E6
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Time
-------
Flle:19AU98U #1-477 Acq:20-AUG-1998 11:12:26 GC EI+ Voltage SIR Autospec-Ultima
Sample#26 Text:ST0819G :PAH CS-2 :265-4B Exp:PAHAIR
130.9920 S:26 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
95:
90:
85:
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65
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7.6E7
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1
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15
-------
File:19AU98U #1-664 Acq:20-AUG-1998 11:12:26 GC EI+ Voltage SIR Autospec-Ultima
Samplel26 Text:ST0819G :PAH CS-2 :265-4B ExprPAHAIR
166.0798 5:26 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 % A9.6.7
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Time
15:48 16:00 16:ii 16:24 16:36 16:48 17:00 17:12 17:24 17:36
172.0984 5:26 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
17:48 18:00 18:12 18:24
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Time
-------
co
File:19AU98U #1-664 Acq:20-AUG-1998 11:12:26 GC EI+ Voltage SIR Autospec-Ultuna
Sample#26 Text:ST0819G :PAH CS-2 :265-4B Exp:PAHAlR
178.0'
1002
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90 -
80 j
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1.9E7
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O.OEO
>0 Time
-------
File:19AU98U 11-664 Acq:20-AUG-1998 11:12:26 GC EI+ Voltage SIR Autospec-Ultima
Sample*26 Text:ST0819G :PAH CS-2 :265-4B Exp:PAHAIR
204.9888 S:26 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
95_
90
85
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75:
70
65:
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0 Time
-------
CO
CO
Flle:19AU98U #1-935 Acq:20-AUG-1998 11:12:26 GC EI+ Voltage SIR Autospec-Ultima
Sample#26 Text:ST0819G :PAH CS-2 :265-4B Exp:PAHAIR
202.0
1002
90-
80-
70-
60_
50-
40-
30-
20-
10 J
0:
22:
212.1
1002
90-
80_
70-
60-
50-
40_
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0-
22:
244.1
1002
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80_
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40-
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22:
782 S:26 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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974 S:26 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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-------
Flle:19AU98U #1-935 Acq:20-AUG-1998 11:12:26 GC EI+ Voltage SIR Autospec-Ultima
Sample#26 Text:ST0819G :PAH CS-2 :26S-4B Exp:PAHAIR
ZZ8.U
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70-
60.
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O.OEO
)0 Time
-------
File:19AU98U #1-935 Acq:20-AUG-1998 11:12:26 GC EI+ Voltage SIR Autospec-UItima
Sample#26 Text:ST0819G :PAH CS-2 :265-4B Exp:PAHAlR
eg
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FHe:19AU98U #1-955 Acq:20-AUG-199811:12:26 GC EI+ Voltage SIR Aulospec-UItiraa
Sample#26 Text:ST0819G -PAH CS-2 :265-4B Exp:PAHAlR
252.0939 8:26 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100
90
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70
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50
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30:
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31:00
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31:00
33:t
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-------
(.0
F11e:19AU98U (Cl-955 Acq:20-AUG-1998 11:12:26 GC EI+ Voltage SIR Autospec-Ultima
Sample#26 Text:ST0819G :PAH CS-2 :265-4B Exp:PAHAlR
276.0
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278.1096 S:26 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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19AU98U #1-955 Acq:20-AUG-1998 11:12:26 GC EI+ Voltage SIR Autospec-Ultima 03
iM16 Text:ST0819G :PAH CS-2 :265-4B Exp:PAHAIR
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-------
File:19AU98U #1-955 Acq:20-AUG-1998 11:12:26 GC EI+ Voltage SIR Autospec-Ultima
Sample#26 Text:ST0819G :PAH CS-2 :265-4B Exp:PAHAIR
268.9824 S:26 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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Flle:19AU98U #1-476 Acq:19-AUG-1998 17:23:34 GC EI+ Voltage SIR Autospec-UItima
Sampled Text:ST0819B :PAH CS-3 :651-21 Exp:PAHAIR
128.0626 5:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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134.0827 5:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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142.0782 5:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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152.1410 5:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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File:l
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9AU98U #1-476 Acq:19-AUG-1998 17:23:34 GC EI+ Voltage
le#3 Text:ST0819B :PAH CS-3 :651-21 Exp:PAHAIR
626 5:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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-------
Flle:19AU98U 11-476 Acq:19-AUG-1998 17:23:34 GC EI+ Voltage SIR Autospec-Ultima
Sampled Text:ST0819B :PAH CS-3 :651-21 ExprPAHAIR
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File:19AU98U #1-666 Acq:19-AUG-1998 17:23:34 GC EI+ Voltage SIR Autospec-UItima
Sampled Text:ST0819B :PAH CS-3 :651-21 ExprPAHAIR
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File:!
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9AU98U #1-666 Acq:19-AUG-1998 17:23:34 GC EI+ Voltage SIR Autospec-Ultima
le#3 Text:ST0819B :PAH CS-3 :651-21 Exp:PAHAIR
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-------
File:19AU98U #1-666 Acq:19-AUG-1998 17:23:34 GC EI+ Voltage SIR Autospec-Ultima
Sampled Text:ST0819B :PAH CS-3 :6S1-21 Exp:PAHAIR
204.9888 S:3 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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-------
File:19AU98U #1-935 Acq:19-AUG-1998
03
00
17:23:34 GC EI+ Voltage SIR Autospec-Ultima
Sampled Text:ST0819B :PAH CS-3 :651-21 Exp:PAHAIR
202.0782 S:3 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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-------
to
CD
File:19AU98U #1-935 Acq:19-AUG-1998 17:23:34 GC EI+ Voltage SIR Autospec-UItima
Sampled Text:ST0819B :PAH CS-3 :651-21 Exp:PAHAIR
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0 Time
-------
File:19AU98U #1-935 Acq:19-AUG-1998 17:23:34 GC EI+ Voltage SIR Autospec-Ultima
Sampled Text:ST0819B :PAH CS-3 :651-21 Exp:PAHAIR
230.9856 S:3 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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„ * 10 Aiir 1998 17-23-34 GC EI+ Voltage SIR Autospec-Ultima
S:3 F:4 SMOU.3) rKD(5,3,3,0.10%,10000.0,0.00%,F,T>
O.OEO
Time
-------
File:19AU98U #1-954 Acq:19-AUG-1998 17:23:34 GC EI+ Voltage SIR Autospec-Ultima
Sampled Text:ST0819B :PAH CS-3 :651-21 Exp:PAHAlR
276.0939 S:3 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 ft A1.64E8
90
80
70-
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20:
101
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-------
File:19AU98U #1-954 Acq:19-AUG-1998 17:23:34 GC EI+ Voltage SIR Autospec-Ultima
Sampled Text:ST0819B :PAH CS-3 :651-21 Exp:PAHAlR
276.0939 S:3 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100% A2.67E8 A2.37E8
80
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288.16925:3 F:4SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 % A2.6JE8
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278.1096 S:3 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 % A1.97E8
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-------
File:19AU98U #1-954 Acq:19-AUG-1998 17:23:34 GC EI+ Voltage SIR Autospec-Ultima
Sampled Text:ST0819B :PAH CS-3 :651-21 ExprPAHAIR
268.9824 S:3 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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o
File:19AU98U #1-476 Acq:19-AUG-1998 18:10:03 GC EI+ Voltage SIR Autospec-UUima
Sample#4 Text:ST0819C :PAH CS-4 :265-4D ExprPAHAIR
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-------
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File:19AU98U #1-476 Acq:19-AUG-1998 18:10:03 GC EI+ Voltage SIR Autospec-Ultima
Sampled Text:ST0819C :PAH CS-4 :26S-4D ExpiPAHAIR
1005
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-------
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File:19AU98U #1-476 Acq:19-AUG-1998 18:10:03 GC EI+ Voltage SIR Autospec-Ultima
Sampled Text:ST0819C :PAH CS-4 :265-4D Exp:PAHAIR
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-------
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File:19AU98U #1-665 Acq:19-AUG-1998 18:10:03 GC EI+ Voltage SIR Autospec-Ultima
Sampled Text:ST0819C :PAH CS-4 :265-4D Exp:PAHAlR
166.0798 S:4 F:2 SMO(1,3) PKD(S,3,3,0.10%,10000.0,0.00%,F,T)
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-------
<£>
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File:19AU98U #1-665 Acq:19-AUG-1998 18:10:03 GC EI+ Voltage SIR Autospec-Ultima
Sample#4 Text:ST0819C :PAH CS-4 :265-4D Exp:PAHAlR
178.0782 S:4 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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-------
File:19AU98U #1-665 Acq:19-AUG-1998 18:10:03 GC EI+ Voltage SIR Autospec-Ultima
Sampled Text:ST0819C :PAH CS-4 :265-4D ExprPAHAIR
204.9888 S:4 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,1
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-------
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File:19AU98U #1-935 Acq:19-AUG-1998 18:10:03 GC EI+ Voltage SIR Autospec-Ultima
Sampled Text:ST0819C :PAH CS-4 :265-4D Exp: PAH AIR
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24:60 25:60 26:00 Time
-------
File:19AU98U #1-935 Acq:19-AUG-1998 18:10:03 GC EI+ Voltage SIR Autospec-UItima
Sampled Text:ST0819C :PAH CS-4 :265-4D Exp:PAHAIR
228.0939 S:4 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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Flle:19AU98U #1-935 Acq:19-AUG-1998 18:10:03 GC EI+ Voltage SIR Autospec-UItima
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File:19AU98U 11-955 Acq:19-AUG-1998 18:10:03 GC EI+ Voltage SIR Autospec-Ultima
Sampled Text:ST0819C :PAH CS-4 :265-4D Exp:PAHAER
252.0939 S:4 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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-------
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File:19AU98U #1-955 Acq:19-AUG-1998 18:10:03 GC E1+ Voltage SIR Autospec-Ultima
Sampled Text:ST0819C :PAH CS-4 :265-4D Exp:PAHAIR
276.0939 S:4 F:4 SMO(1,3) PKD(5,3>3,0.10%,10000.0>0.00%,F,T)
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-------
File:19AU98U #1-955 Acq:19-AUG-1998 18:10:03 GC EI+ Voltage SIR Autospec-Ultima
Sampled Text:ST0819C :PAH CS-4 :265-4D Exp: PAH AIR
276.0939 S:4 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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288.1692 S:4 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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-------
File:19AU98U #1-955 Acq:19-AUG-1998 18:10:03 GC EI+ Voltage SIR Autospec-Ultima
Sampled Text:ST0819C :PAH CS-4 :265-4D Exp:PAHAIR
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-------
10
File:19AU98U #1-476 Acq:19-AUG-1998 18:56:31 GC EI+ Voltage SIR Autospec-Ultima
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-------
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File:19AU98U #1-476 Acq:19-AUG-1998 18:56:31 GC EI+ Voltage SIR Autospec-Ultima
Sampled Text:ST0819D :PAH CS-5 :265-4E Exp:PAHAIR
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-------
FHe:19AU98U #1-476 Acq:19-AUG-1998 18:56:31 GC EI+ Voltage SIR Autospec-Ultima
Samplers Text:ST0819D :PAH CS-5 :265-4E Exp:PAHAIR
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-------
00
File:19AU98U #1-666 Acq:19-AUG-1998 18:56:31 GC EI+ Voltage SIR Autospec-Ullima
SampleiCS Text:ST0819D :PAH CS-5 :265-4E Exp:PAHAIR
166.0798 S:5 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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File:19AU98U 11-666 Acq:19-AUG-1998 18:56:31 GC EI+ Voltage SIR Autospec-UItima
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-------
File:19AU98U #1-935 Acq:19-AUG-1998 18:56:31 GC EI+ Voltage SIR Autospec-Ultima
Samplers Text:ST0819D :PAH CS-5 :26S-4E ExprPAHAIR
202.0782 S:5 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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-------
CV
File:19AU98U #1-935 Acq:19-AUG-1998 18:56:31 GC E1+ Voltage SIR Autospec-Ultlma
Sampled Text:ST0819D :PAH CS-5 :265-4E Exp:PAHAlR
228.0939 S:S F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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-------
-------
A8.43E8
File:19AU98U #1-954 Acq:19-AUG-1998 18:56:31 GC EI+ Voltage SIR Autospec-Ultima
Sampled Text:ST0819D :PAH CS-5 :265-4E Exp:PAHAlR
252.0939 S:5 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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Time
30:
0
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264.1692 S:5 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
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Time
-------
File:19AU98U #1-954 Acq:19-AUG-1998 18:56:31 GC EI+ Voltage SIR Autospec-Ultima
Samplers Text:ST0819D :PAH CS-5 :265-4E Exp:PAHAlR
276.0939 S:5 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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100%
38:24 38:36 38:48 39:00 39:i2
.O.OEO
Time
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8.8E6
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4.4E6
2.2E6
O.OEO
Time
-------
File:19AU98U #1-954 Acq:19-AUG-1998 18:56:31 GC EI+ Voltage SIR Autospec-UItima
Sampled Text:ST0819D :PAH CS-5 :265-4E Exp:PAHAIR
276.0939 S:5 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
A1.08E9
80
60-
40
20
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0
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288.1692 S:5 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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60
40
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278.1096 S:5 F:4SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
39:00
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292.1974 S:5 F:4SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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-------
UCdEdEdCdtdUtdtd
wooist^iNvopNvoi-i
111111 < 11111 • • < i • • 111111. i. i.. i.,,, i,
o-l
U] H
-------
ICAL ID
QUANTERRA INCORPORATED
West Sacramento
Initial Calibration Checklist
High Resolution
Method ID PftH
Environmental
Services
Column ID I>£-5
STD ID'S.
266
Instrument ID 0(((Me\
Multiplier Setting ZtO \J.
Analyzed By Q<
Prepared By (j
Date Analyzed IP I61 /a &
Date Prepared \l
Reviewed By.
A
Date Reviewed / 6 / o 2>/ ?£*
: % - ", , " s -4.' < AtfALVSlSSQiSIiEAl.- ^ * * ,* & „ ^
Curve summary present?
CS1-CS5, CPSM, solvent blank present?
Copy of logfile present?
CPSM Blow-up/Static resolution check present?
Target file RTs correct?
•RRFff within method-specified limits?
Signal-to-noise criteria met?
Isotopic ratios within limits?
High point free of saturation?
Chromatographic windows correct?
CPSM valley < 25%?
Manual reintegrations checked and hardcopies
included?
;- IMEElSaEEn^^^M
/
f £&3
^
X&Q/ S
[^
^
^
AJA-
^^x-
^
MA 61
X
i/
t/CDfe
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^
^
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,/
^^
A//» (P
,/
COMMENTS:.
Method 8290: %RSD < 20% for natives. < 30% for labelled analvtes: S/N > 10
Method 1613A: %CV< 35% (See Table 7, Method 1613A); S/N > 10
Method 23: %RSD < values specified in Table 5. Method 23: S/N > 2.5
PAH: %RSD < 30% for natives and labelled compounds: S/N > 10
PCB: %RSD < 25% for natives, < 30% for labelled compounds: S/N > 2.5
NCASI 551: %RSD < 20% for natives and labelled compounds: > 5
DBD/DBF: %RSD < 30% for natives and labelled compounds: S/N > 10
QA-384 HE 2/97
-------
02-OCT-1998 09:56:32 AH
Mass Spec : ULTIMA
GC CoIurn : DB-5
265-04A --> 265-04E;
Multiplier 8 260V.
PAH CALIBRATION TABLE
File name : PAHAIR100198U.RRF
Date analyzed : 01-OCT-98
INITIAL CALIBRATION CURVE
to
d8-Naphtha(ene
Naphthalene
2-Nethylnaphthalene
d8-Acenaphthylene
Acenaphthylene
d10-Aeenaphthene
Acenaphthene
d10-Fluorene
Fluorene
d10-Phenanthrene
Phenanthrene
Anthracene
dlO-Fluoranthene
Fluoranthene
dIO-Pyrene
Pyrene
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Mean
1
1
0
1
1
0
.78
.20
.66
.16
.02
.68
1.14
1.36
1.15
2.74
0.95
0.97
1.
1.
1.
1.
49
23
58
26
S.
0
0
0
0
0
0
0
0,
0.
0.
0.
0.
0.
0.
0.
0.
D.
.143
.205
.138
.071
.034
.040
.071
.169
,078
,383
041
179
154
044
157
067
XRSD
8.020
17.067
21.003
6.092
3.301
5.815
6.206
12.415
6.809
13.988
4.325
18.441
10.335
3.570
9.978
5.306
1
100.00
171.18
1.71
10.00
15.52
1.55
10.00
8.86
0.89
100.00
123.71
1.24
10.00
10.33
1.03
100.00
73.42
0.73
10.00
12.61
1.26
100.00
144.89
1.45
10.00
11.96
1.20
100.00
304.73
3.05
10.00
9.77
0.98
10.00
8.51
0.85
100.00
122.27
1.22
10.00
12.21
1.22
100.00
130.84
1.31
10.00
12.63
1.26
2
100.00
160.04
1.60
50.00
59.91
1.20
50.00
34.41
0.69
100.00
113.60
1.14
50.00
53.17
1.06
100.00
68.27
0.68
50.00
55.92
1.12
100.00
152.54
1.53
50.00
61.81
1.24
100.00
301.29
3.01
50.00
48.56
0.97
50.00
44.48
0.89
100.00
157.80
1.58
50.00
64.63
1.29
100.00
165.10
1.65
50.00
63.04
1.26
3
100.00
180.53
1.81
100.00
112.12
1.12
100.00
57.75
0.58
100.00
106.71
1.07
100.00
98.02
0.98
100.00
62.70
0.63
100.00
108.02
1.08
100.00
146.61
1.47
100.00
104.48
1.04
100.00
297.96
2.98
100.00
88.92
0.89
100.00
80.92
0.81
100.00
158.48
1.58
100.00
118.10
1.18
100.00
166.15
1.66
100.00
116.69
1.17
4
100.00
181.12
1.81
200.00
218.51
1.09
200.00
113.66
0.57
100.00
114.85
1.15
200.00
200.11
1.00
100.00
66.67
0.67
200.00
226.76
1.13
100.00
124.50
1.24
200.00
217.93
1.09
100.00
241.46
2.41
200.00
186.76
0.93
200.00
215.19
1.08
100.00
157.22
1.57
200.00
241.31
1.21
100.00
169.44
1.69
200.00
248.31
1.24
5
100.00
198.82
1.99
500.00
518.93
1.04
500.00
282.14
0.56
100.00
122.99
1.23
500.00
523.04
1.05
100.00
69.97
0.70
500.00
552.29
1.10
100.00
112.61
1.13
500.00
581.04
1.16
100.00
223.55
2.24
500.00
495.42
0.99
500.00
618.06
1.24
100.00
149.99
1.50
500.00
629.15
1.26
100.00
156.09
1.56
500.00
676.95
1.35
10
-------
02-OCT-1998 09:56:34 AH
PAH CALIBRATION TABLE
Mass Spec : ULTIMA
GC Column : DB-5
265-04A --> 265-04E; Multiplier 8 260V.
Filename : PAHAIR100198U.RRF
Date analyzed : 01-OCT-98
INITIAL CALIBRATION CURVE
O
00
d12-Benzo(a)anthracene
Benzo( a ) anth racene
d12-Chrysene
Chrysene
d12-Benzo(b)fluoranthene
Benzo(b)fluoranthene
d12-Benzo(k)f luoranthene
Benzo(k)fluoranthene
d12-Benzo(a)pyrene
Benzo(e)pyrene
Benzo(a)pyrene
d12-Perylene
Perylene
d12-Indeno(123-cd)pyrene
Indeno(123-cd)pyrene
dU-Dibenz(ah)anthracene
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Mean
0
1
1
1
0
1
0
1
0
1
1
0
1
0
0
0
.81
.28
.17
.16
.48
.30
.99
.20
.74
.62
.11
.65
.74
.37
.60
.20
S.D.
0.051
0.069
0.075
0.057
0.026
0.085
0.022
0.061
0.023
0.085
0.084
0.029
0.145
0.040
0.031
0.031
XRSD
6
5
6
4
5
6
2
5
3
5
7
4
8
10
5
15
.243
.356
.438
.881
.475
.540
.196
.111
.065
.216
.550
.558
.315
.705
.150
.283
1
100.00
81.86
0.82
10.00
12.57
1.26
100.00
115.99
1.16
10.00
11.72
1.17
100.00
48.56
0.49
10.00
13.55
1.35
100.00
96.32
0.96
10.00
12.67
1.27
100.00
71.22
0.71
10.00
17.26
1.73
10.00
12.23
1.22
100.00
60.50
0.60
10.00
18.19
1.82
100.00
37.05
0.37
10.00
5.81
0.58
100.00
19.47
0.19
2
100.00
73.87
0.74
50.00
65.11
1.30
100.00
107.11
1.07
50.00
62.55
1.25
100.00
46.43
0.46
50.00
66.19
1.32
100.00
96.76
0.97
50.00
63.60
1.27
100.00
75.03
0.75
50.00
82.73
1.65
50.00
58.74
1.17
100.00
67.68
0.68
50.00
93.11
1.86
100.00
32.97
0.33
50.00
32.63
0.65
100.00
17.67
0.18
3
100.00
80.14
0.80
100.00
117.72
1.18
100.00
112.39
1.12
100.00
112.19
1.12
100.00
46.37
0.46
100.00
117.89
1.18
100.00
98.32
0.98
100.00
115.65
1.16
100.00
71.96
0.72
100.00
150.84
1.51
100.00
104.99
1.05
100.00
66.13
0.66
100.00
154.60
1.55
100.00
34.97
0.35
100.00
58.18
0.58
100.00
18.57
0.19
4
100.00
82.24
0.82
200.00
260.77
1.30
100.00
122.50
1.23
200.00
221.26
1.11
100.00
46.62
0.47
200.00
249.84
1.25
100.00
100.62
1.01
200.00
233.26
1.17
100.00
74.50
0.74
200.00
313.45
1.57
200.00
205.81
1.03
100.00
66.18
0.66
200.00
326.69
1.63
100.00
37.60
0.38
200.00
117.22
0.59
100.00
20.38
0.20
5
100.00
88.02
0.88
500.00
680.79
1.36
100.00
125.72
1.26
500.00
575.40
1.15
100.00
52.52
0.53
500.00
695.00
1.39
100.00
101.05
1.01
500.00
575.34
1.15
100.00
76.72
0.77
500.00
826.10
1.65
500.00
539.70
1.08
100.00
62.72
0.63
500.00
929.14
1.86
100.00
43.56
0.44
500.00
308.65
0.62
100.00
25.60
0.26
10
-------
02-OCT-1998 09:56:35 AM
PAH CALIBRATION TABLE
Mass Spec : ULTIMA
GC Column : DB-5
265-04* --> 265-04E; Multiplier a 260V.
D ibenz(ah)anth racene
d12-Benzo(gh<)perylene
Benzo(ghi)perylene
Filename : PAHAIR100198U.RRF
Date analyzed : 01-OCT-98
INITIAL CALIBRATION CURVE
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Mean
1.28
0.41
1.11
S.D.
0.051
0.035
0.030
XRSD
3.957
8.601
2.671
1
10.00
12.64
1.26
100.00
45.17
0.45
10.00
10.73
1.07
2
50.00
60.24
1.20
100.00
37.67
0.38
50.00
56.16
1.12
3
100.00
129.39
1.29
100.00
38.08
0.38
100.00
107.43
1.07
4
200.00
268.11
1.34
100.00
39.49
0.39
200.00
227.28
1.14
5
500.00
651.39
1.30
100.00
44.20
0.44
500.00
559.79
1.12
10
-------
02-OCT-1998 09:38:06 AM
PAH leal RESULTS
Mass Spec : ULTIMA
3C Column : DB-5
Data file : 010C98U
weight : 1
Name
dlO-2-Methylnaphthalene
d8-Naphthalene
Naphthalene
2-Methylnaphthalene
d8-Acenaphthylene
Acenaphthylene
dlO-Acenaphthene
Acenaphthene
dlO-Anthracene
dlO-Fluorene
Fluorene
dl0-Phenanthrene
Phenanthrene
Anthracene
d!4-Terphenyl
dl0-Fluoranthene
Fluoranthene
dlO-Pyrene
Pyrene
d!2-Benzo(a)anthracene
Benzo(a)anthracene
d!2-Chrysene
Chrysene
d!2-Benzo(e)pyrene
d!2-Benzo(b)fluoranthene
Benzo(b)fluoranthene
dl2-Benzo(k)fluoranthene
Benzo(k)fluoranthene
dl 2-Benzo(a)pyrene
Benzo(e)pyrene
Benzo(a)pyrene
d!2-Perylene
Perylene
d!2-Indeno(123-cd)pyrene
Indeno(123-cd)pyrene
d!4-Dibenz(ah)anthracene
Dibenz(ah)anthracene
d!2-Benzo(ghi)perylene
Benzo(ghi)perylene
Results : 010C98U011.RES
Date analyzed
ST1001 :CS-1 .-265-04A : : Ex
Total Isotope R. T. RRF
Response Ratio mm:ss
PAHAIRCAL1.TRG
Ol-OCT-98
pg
Rec/
MDL
110799200
189666000
29434600
16800660
137066800
14160260
81344200
10258380
66290800
96050000
11491020
202010000
19738800
17184620
223606000
273396000
33374600
292556000
36964000
183043000
23008400
259364000
30400400
371336000
180333000
24427600
357682000
45322800
264468000
45637600
32356800
224648000
40866400
137581800
8000000
72286600
9140000
167734200
18000000
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
10:
8:
8:
10:
13:
13:
14:
14:
19:
15:
15:
18:
18:
19:
24:
22:
22:
23:
23:
27:
27:
27:
27:
31:
30:
30:
30:
30:
31:
31:
31:
32:
32:
36:
36:
36:
36:
37:
37:
28
19
23
35
31
33
5
11
3
47
52
54
58
7
11
47
50
29
32
21
25
28
33
41
46
51
51
55
51
46
56
9
15
31
39
37
46
47
56
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
0,
1.
1.
0
1
1.
0
1
0
1
1
3
0
0
-1
1
1
1
1
0
1
1
1
0
0
1
0
1
0
1
1
0
1
0
0
0
1
0
1
.00
.71
.55
.89
.24
.03
.73
.26
.00
.45
.20
.05
.98
.85
.00
.22
.22
.31
.26
.82
.26
.16
.17
.00
.49
.35
.96
.27
.71
.73
.22
.60
.82
.37
.58
.19
.26
.45
.07
100.
100.
10.
10.
100.
10.
100.
10.
100.
100.
10.
100.
10.
10.
100.
100.
10.
100.
10.
100.
10.
100.
10.
100.
100.
10.
100.
10.
100.
10.
10.
100.
10.
100.
10 ;
100.
10.
100,
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
,00
,00
,00
,00
.00
.00
.00
10.00
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
,000
.000
•4&>
-------
02-OCT-1998 09:37:59 AM
PAH leal RESULTS
Mass Spec : ULTIMA
GC Column : DB-5
Data file : 010C98U
Weight : 1
Name
dlO-2-Methylnaphthalene
d8-Naphthalene
Naphthalene
2-Methylnaphthalene
d8-Acenaphthylene
Acenaphthylene
dlO-Acenaphthene
Acenaphthene
dlO-Anthracene
dlO-Fluorene
Fluorene
dl0-Phenanthrene
Phenanthrene
Anthracene
d!4-Terphenyl
dlO-Fluoranthene
Fluoranthene
dlO-Pyrene
Pyrene
d!2-Benzo(a)anthracene
Benzo(a)anthracene
d!2-Chrysene
Chrysene
d!2-Benzo(e)pyrene
d!2-Benzo(b)fluoranthene
Benzo(b)fluoranthene
d!2-Benzo(k)fluoranthene
Benzo(k)fluoranthene
d!2-Benzo(a)pyrene
Benzo(e)pyrene
Benzo(a)pyrene
d!2-Perylene
Perylene
d!2-Indeno(123-cd)pyrene
Indeno(123-cd)pyrene
d!4-Dibenz(ah)anthracene
Dibenz(ah)anthracene
dl2-Benzo(ghi)perylene
Benzo(ghi)perylene
Results : 010C98U021.RES
Date analyzed
ST1001A :CS-2 :265-04B : Ex
Total Isotope R. T. RRF
Response Ratio mm:ss
134307600 1.00 Y
214944000 1.00 Y
128782200 1.00 Y
73971800 1.00 Y
152576600 1.00 Y
81117800 1.00 Y
91695800 1.00 Y
51273200 1.00 Y
75224800 1.00 Y
114746200 1.00 Y
70928400 1.00 Y
226644000 1.00 Y
110062200 1.00 Y
100803600 1.00 Y
143463400 1.00 Y
226392000 1.00 Y
146312600 1.00 Y
236858000 1.00 Y
149305600 1.00 Y
105981000 1.00 Y
69000600 1.00 Y
153666800 1.00 Y
96114400 1.00 Y
228652000 1.00 Y
106163600 1.00 Y
70270400 1.00 Y
221236000 1.00 Y
140696200 1.00 Y
171550000 1.00 Y
141922600 1.00 Y
100767200 1.00 Y
154760400 1.00 Y
144099400 1.00 Y
75380600 1.00 Y
24600000 1.00 Y
40401400 1.00 Y
24336000 1.00 Y
86132400 1.00 Y
48371600 1.00 Y
PAHAIRCAL2.TRG
Ol-OCT-98
pg
Rec/
MDL
10: 28 Y
8: 19 Y
8: 23 Y
10: 35 Y
13: 31 Y
13: 34 Y
14: 5 Y
14: 11 Y
19: 3 Y
15: 46 Y
15: 52 Y
18: 54 Y
18: 58 Y
19: 7 Y
24: 11 Y
22: 47 Y
22: 51 Y
23: 28 Y
23: 32 Y
27: 21 Y
27: 25 Y
27: 28 Y
27: 32 Y
31: 40 Y
30: 46 Y
30: 50 Y
30: 51 Y
30: 55 Y
31: 51 Y
31: 46 Y
31: 56 Y
32: 9 Y
32: 14 Y
36: 32 Y
36: 38 Y
36: 36 Y
36: 46 Y
37: 47 Y
37: 56 Y
0.00
1.60
1.20
0.69
1.14
1.06
0.68
1.12
• o.oo
1.53
1.24
3.01
0.97
0.89
0.00
1.58
1.29
1.65
1.26
0.74
1.30
1.07
1.25
-1.00
0.46
1.32
0.97
1.27
0.75
1.65
1.17
0.68
1.86
0.33
0.65
0.18
1.20
0.38
1.12
100.00
100.00
50.00 0.000
50.00 0.000
100.00
50.00 0.000
100.00
50.00 0.000
100.00
100.00
50.00 0.000
100.00
50.00 0.000
50.00 0.000
100.00
100.00
50.00 0.000
100.00
50.00 0.000
100.00
50.00 0.000
100.00
50.00 0.000
100.00
100.00
50.00 0.000
100.00
50.00 0.000
100.00
50.00 0.000
50.00 0.000
100.00
50.00 0.000
100.00
50.00 0.000
100.00
50.00 0.000
A *"* ^
100.00*^0
50.00 0.000
-------
02-OCT-1998 09:42:57 AM
PAH leal RESULTS
Mass Spec : ULTIMA
GC Column : DB-5
Data file : 010C98U
Weight : 1
Name
dlO-2-Methylnaphthalene
d8-Naphthalene
Naphthalene
2-Methylnaphthalene
d8-Acenaphthylene
Acenaphthylene
dlO-Acenaphthene
Acenaphthene
dlO-Anthracene
dlO-Fluorene
Fluorene
dl 0-Phenanthrene
Phenanthrene
Anthracene
d!4-Terphenyl
dl 0-Fluoranthene
Fluoranthene
dlO-Pyrene
Pyrene
d!2-Benzo(a)anthracene
Benzo(a)anthracene
d!2-Chrysene
Chrysene
d!2-Benzo(e)pyrene
d!2-Benzo(b)fluoranthene
Benzo(b)fluoranthene
d!2-Benzo(k)fluoranthene
Benzo(k)fluoranthene
dl2-Benzo(a)pyrene
Benzo(e)pyrene
Benzo(a)pyrene
d!2-Perylene
Perylene
dl2 -Indeno(12 3 -cd)pyrene
Indeno(12 3 -cd)pyrene
d!4-Dibenz(ah)anthracene
Dibenz(ah)anthracene
d!2-Benzo(ghi)perylene
Benzo(ghi)perylene
Results : 010C98U031.RES
Date analyzed
ST1001B :CS-3 :265-04C : Ex
Total Isotope R. T. RRF
Response Ratio mm:ss
PAHAIRCAL3.TRG
Ol-OCT-98
pg
Rec/
MDL
132646200 1.00 Y
239460000 1.00 Y
268480000 1.00 Y
138281000 1.00 Y
141540200 1.00 Y
138743400 1.00 Y
83168600 1.00 Y
89837400 1.00 Y
74035200 1.00 Y
108542800 1.00 Y
113410400 1.00 Y
220596000 1.00 Y
196147600 1.00 Y
178499800 1.00 Y
155127000 1.00 Y
245840000 1.00 Y
290336000 1.00 Y
257736000 1.00 Y
300752000 1.00 Y
124313600 1.00 Y
146343000 1.00 Y
174354000 1.00 Y
195614600 1.00 Y
268388000 1.00 Y
124457200 1.00 Y
146725000 1.00 Y
263876000 1.00 Y
305166000 1.00 Y
193132800 1.00 Y
291316000 1.00 Y
202776000 1.00 Y
177478000 1.00 Y
274382000 1.00 Y
93849400 1.00 Y
54600000 1.00 Y
49851200 1.00 Y
64502600 1.00 Y
102197600 1.00 Y
109793600 1.00 Y
10:
8:
8:
10:
13:
13:
14:
14:
19:
15:
15:
18:
18:
19:
24:
22:
22:
23:
23:
27:
27:
27:
27:
31:
30:
30:
30:
30:
31:
31:
31:
32:
32:
36:
36:
36:
36:
37:
37:
29
19
23
35
30
33
4
11
3
47
52
54
58
7
11
47
50
29
32
20
24
27
32
40
45
50
51
54
51
46
55
8
13
31
38
36
45
46
55
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
1.
1.
1.
0.
1.
0.
0.
1.
0.
1.
1.
00
81
12
58
07
98
63
08
00
47
04
2.98
0.
0.
0.
1.
1.
1,
1
0
1
1
1
0
0
1
0
1
0
1
1
0
1
0
0
0
1
0
1
89
,81
,00
.58
.18
.66
.17
.80
.18
.12
.12
.00
.46
.18
.98
.16
.72
.51
.05
.66
.55
.35
.58
.19
.29
.38
.07
100.
100.
100.
100.
100.
100.
100.
100.
100.
100.
100.
100.
100.
100.
100.
100.
100.
100.
00
00
00
00
00
00
00
00
00
00
00
00
00
00
,00
,00
.00
.00
100.00
100.
100,
100
.00
.00
.00
100.00
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0
0
0
0
0
0
4
0
000
000
000
000
000
000
000
000
000
.000
.000
.000
.000
.000
.000
.000
.000
2>4°
.000
-------
02-OCT-1998 09:49:30 AM
PAH leal RESULTS
viass spec : ULTIMA
3C Column : DB-5
Data file : 010C98U
Weight : 1
Name
dlO-2-Methylnaphthalene
d8-Naphthalene
Naphthalene
2-Methylnaphthalene
d8-Acenaphthylene
Acenaphthylene
dlO-Acenaphthene
Acenaphthene
dlO-Anthracene
dlO-Fluorene
Fluorene
dl 0-Phenanthrene
Phenanthrene
Anthracene
d!4-Terphenyl
dlO-Fluoranthene
Fluoranthene
dlO-Pyrene
Pyrene
d!2-Benzo(a)anthracene
Benzo(a)anthracene
d!2-Chrysene
Chrysene
d!2-Benzo(e)pyrene
d!2-Benzo(b)fluoranthene
Benzo(b)fluoranthene
d!2-Benzo(k)fluoranthene
Benzo(k)fluoranthene
d!2-Benzo(a)pyrene
Benzo(e)pyrene
Benzo(a)pyrene
d!2-Perylene
Perylene
d!2-Indeno(12 3 -cd)pyrene
Indeno(12 3 -cd)pyrene
d!4-Dibenz(ah)anthracene
Dibenz(ah)anthracene
d!2-Benzo(ghi)perylene
Benzo(ghi)perylene
dlO-Fluorene
13C-Fluorene
Results : 010C98U041.RES
Date analyzed
ST1001C :CS-4 :265-04D : Ex
Total Isotope R. T. RRF
Response Ratio mnuss
110680200 1.00 Y 10: 28 Y
200462000 1.00 Y 8: 19 Y
438038000 1.00 Y 8: 23 Y
227838000 1.00 Y 10: 35 Y
127112400 1.00 Y 13: 31 Y
254366000 1.00 Y 13: 33 Y
73792200 1.00 Y 14: 5 Y
167331600 1.00 Y 14: 11 Y
78481800 1.00 Y 19: 3 Y
97709200 1.00 Y 15: 46 Y
212938000 1.00 Y 15: 52 Y
PAHAIRCAL4.TRG
Ol-OCT-98
189505800 1.00 Y
353918000 1.00 Y
407796000 1.00 Y
166994600 1.00 Y
262546000 1.00 Y
633544000 1.00 Y
282962000 1.00 Y
702634000 1.00 Y
137340200 1.00 Y
358144000 1.00 Y
204576000 1.00 Y
452646000 1.00 Y
308084000 1.00 Y
143642200 1.00 Y
358870000 1.00 Y
310008000 1.00 Y
723118000 1.00 Y
18: 53 Y
18: 58 Y
19: 7 Y
24: 11 Y
22: 46 Y
22: 50 Y
23: 28 Y
23: 32 Y
27:
27:
27:
27:
31:
30:
30
30
30
229512000 1.00 Y 31:
719408000 1.00 Y 31:
472362000 1.00 Y 31:
203898000 1.00 Y 32:
666124000 1.00 Y 32:
115847600 1.00 Y 36:
135800000 1.00 Y 36:
62783600 1.00 Y 36:
168330400 1.00 Y 36:
121648200 1.00 Y 37:
276482000 1.00 Y 37:
97709200 1.00 Y 15
* No Peak 0.00 N 15
20 Y
25 Y
27 Y
32 Y
40 Y
45 Y
49 Y
50 Y
55 Y
50 Y
45 Y
56 Y
8 Y
14 Y
31 Y
37 Y
35 Y
45 Y
46 Y
54 Y
46 Y
51 N
pg
Rec/
MDL
1.
1.
1.
0.
1.
1.
0.
1.
0.
1.
1.
2.
0.
1.
0.
1.
1.
1.
1.
0.
1.
1.
1.
0,
0.
1.
00
81
09
57
15
00
67
13
00
24
09
41
93
08
00
57
21
69
24
.82
.30
.23
.11
.00
.47
.25
1.01
1
0
1
1
0
1
0
0
0
1
0
1
.17
.74
.57
.03
.66
.63
.38
.59
.20
.34
.39
.14
100.
100.
200.
200.
100.
200.
100.
200.
100.
100.
200.
100.
200.
200.
100.
100.
200.
100.
200.
100.
200
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
.00
.00
.00
.00
.00
.00
0.
0.
0.
0.
0.
0.
0.
0.
0.
0
000
000
000
000
000
000
000
.000
.000
.000
100.00
200
100
100
200
100
200
100
200
200
100
200
100
200
100
200
100
200
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
•°°<
.00
.00
0
0
0
0
0
0
0
.000
.000
.000
.000
.000
.000
.000
30>&00
0
.000
-1.00
0.00
100.00
100.00
-------
02-OCT-1998 09:52:36 AM
PAH leal RESULTS
Mass Spec : ULTIMA
GC Column : DB-5
Data file : 010C98U
Weight : 1
Name
dlO-2-MethyInaphthalene
d8-Naphthalene
Naphthalene
2-MethyInaphthalene
d8-Acenaphthylene
Acenaphthylene
dlO-Acenaphthene
Acenaphthene
dlO-Anthracene
dlO-Fluorene
Fluorene
dl0-Phenanthrene
Phenanthrene
Anthracene
d!4-Terphenyl
dlO-Fluoranthene
Fluoranthene
dlO-Pyrene
Pyrene
d!2-Benzo(a)anthracene
Benzo(a)anthracene
d!2-Chrysene
Chrysene
dl2 -Benz o(e)pyrene
dl2-Benzo(b)fluoranthene
Benzo(b)fluoranthene
d!2-Benzo(k)fluoranthene
Benzo(k)fluoranthene
d!2-Benzo(a)pyrene
Benzo(e)pyrene
Benzo(a)pyrene
d!2-Perylene
Perylene
d!2-Indeno(123 -cd)pyrene
Indeno(123 -cd)pyrene
d!4-Dibenz(ah)anthracene
Dibenz(ah)anthracene
d!2-Benzo(ghi)perylene
Benzo(ghi)perylene
Results : 010C98U051.RES
Date analyzed
ST1001D :CS-5 -.265-04E : Ex
Total Isotope R. T. RRF
Response Ratio mm:ss
PAHAIRCAL5.TRG
Ol-OCT-98
pg Rec/
MDL
107764600
214262000
1111880000
604524000
132535200
693206000
75400800
416428000
90130400
101497800
589742000
201484000
998200000
1245296000
185488200
278218000
1750396000
289520000
1959900000
163268600
1111520000
233188000
1341774000
345112000
181269200
1259814000
348738000
2006440000
264770000
2187260000
1428976000
216440000
2011040000
150332800
464000000
88335000
575408000
152552400
853976000
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
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.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
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.00
.00
.00
.00
.00
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.00
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.00
.00
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Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
10:
8:
8:
10:
13:
13:
14:
14:
19:
15:
15:-
18:
18:
19:
24:
22:
22:
23:
23:
27:
27:
27:
27:
31:
30:
30:
30:
30:
31:
31:
31:
32:
32:
36:
36:
36:
36:
37:
37:
29
18
23
34
31
33
5
11
3
46
52
53
58
7
11
46
50
28
32
20
24
27
32
39
45
50
50
54
50
45
55
8
13
30
38
35
45
45
55
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
1
1
1
0
1
1
0
1
0
1
1
2
0
1
0
1
1
1
1
0
1
1
1
-1
0
1
1
1
0
1
1
0
1
0
0
0
1
0
1
.00
.99
.04
.56
.23
.05
.70
.10
.00
.13
.16
.24
.99
.24
.00
.50
.26
.56
.35
.88
.36
.26
.15
.00
.53
.39
.01
.15
.77
.65
.08
.63
.86
.44
.62
.26
.30
.44
.12
100
100
500
500
100
500
100
500
100
100
500
100
500
500
100
100
500
100
500
100
500
100
500
100
100
500
100
500
100
500
500
100
500
100
500
100
500
100
500
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
O.QOQ
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
138
0.000
-------
File:01OC98U #1-508 Acq: l-OCT-1998 17:35:45 GC EI+ Voltage SIR Autospec-Ultima
Sample*! Text:ST1001 :CS-1 :265-04A : : Exp:PAHAIR
1.4B.U
100 2
80 1
60-
40_
20^
-------
File:01OC98U #1-508 Acq: l-OCT-1998 17:35:45 GC EI+ Voltage SIR Autospec-Ultima
Sample*! Text:ST1001 :CS-1 .-265-04A :: Exp.-PAHAIR
152.0626 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
1009
80-
60-
40-
20-
A7.08E6
A
/ 1
1 1
\ A1.85E6
l\ A
12:36 12:48 13:00 13:h 13:24 13:36 13:48 14:6o 14:12
160.1128 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
1009
80.
60:
40:
20 :
0 :
p A6.8SE7
n
A
1 \ A1.29E7
/ L /\
12:36 12:48 13:00 13:12 13:24 13:36 13:48 14:00 14:12
154.0782 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 S
80:
60:
40:
20:
0
P A5.13E6
A
A
/ V
2.4E6
14:24 14:36 14:48 15:
1.9E6
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DO Time
<*
14:24 14:36 14:48 15:1
r2.3E7
-1.8E7
Ll.4E7
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O.OEO
bo Time
A6.36E4 A1.68E5 AI.JIES A7.57E4 1 VAI.82ES A6.74E4
v~i — i — i — i — i — i — i — i — i — i — i — i — i — i — i — i — i — i — i — r— i — 1 — i — i — i — i — i — i — i — i — i — i — i — i — i — i — i — i — i — i — i — i — i — i — i — r~ i — i — i — i — r— i — i — i — r-
12:36 12:48 13:00 13:12 13:24 13:36 13:48 14:00 14:12
164.1410 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
1005
80:
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14:24 14:36 14:48 15:1
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5<~~~~i i I i i r~i r~~i r~-i i "r i ' ' i i —
14:36 14:48 15.4
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-------
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-------
File:010C98U #1-586 Acq: l-OCT-1998 17:35:45 GC EI+ Voltage SIR Autospec-UItima
Sample*! Text:ST1001 :CS-1:265-04A :: Exp:PAHAlR
166.0798 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 % A5.75E6
90.
80
70-
60
50,
40
30 j
20
10 J
2.4E6
-2.2E6
2.0E6
-1.7E6
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-1.2E6
-9.8E5
-7.3E5
_4.9E5
L2.4E5
LO.OEO
)0 Time
15:
)0
15:24
15:36
15:48
16:C
16:12
16:24
16:36
16:48
172.0984 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
15:46
16:13 16:22 16:29
i 1—i—i—i r—i—i 1 1 i r—i—i—i 1 1 r—i—i—i 1 1—I—i—i-
15:00 15:12 15:24 15:36 15:48
176.1410 F:2 SMO(1,3) PKD(5,3>3,0.10%,10000.0,0.00%,F,T)
100 % A4.8JOE7
90_
80
70
60-
50-
40
30
20 J
10J
0
i—i—i—i—i—i—i—i—i—i—i—i—i—r—<—r—i—i—i—i—i—r—
16:00 16:12 16:24 16:36
17:
1.9E3
-1.7E3
-1.5E3
-1.3E3
_1.1E3
L9.5E2
L7.6E2
L5.7E2
L3.8E2
L1.9E2
LO.OEO
(0 Time
2.0E7
.1.8E7
-1.6E7
-1.4E7
-1.2E7
.1.0E7
-8.0E6
L6.0E6
L4.0E6
L2.0E6
LO.OEO
»0 Time
16:48
—I 1 1 1 1—T 1 1 1 1—T
15:12
-i - 1 - 1 - 1 i T i - 1 - r
15:24 15:36
i - 1 — i™ 1 ' I T ' i — i — r-
15:48 16:00
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16:12 16:2
16:36
15:00
16:48
-------
File:01OC98U #1-586 Acq: l-OCT-1998 17:35:45 GC EI+ Voltage SIR Autospec-Ultima
Sampled! Text:ST1001 :CS-1 :265-04A : : ExprPAHAIR
178.0782 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
A9.87E6
90:
80:
70:
60:
50:
40J
30:
20:
10:
0:
A8.59E6
4.2E6
:3.7E6
:3.3E6
L2.9E6
L2.5E6
L2.1E6
L1.7E6
il.2E6
-8.3E5
-4.2E5
O.OEO
0 Time
18:00 18:12 18:24 18:36 18:48
188.1410 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,FfT)
100 % A1.04E8
90 J
80
70:
60:
50:
40
30:
20:
10:
0
19:00
19:12
19:24
19:36
19:48
A3.31E7
18:i2
18:24
18:36
1— I11 |ir^ I "T '
19:00
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19:12 19:24
20:
4.3E7
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-3.4E7
:3.0E7
-2.6E7
:2.1E7
-1.7E7
1.3E7
8.6E6
L4.3E6
O.OEO
0 Time
18:00
18:48
—J r~"'T—I 1 T T
19:36
19:48
20:
-------
File:01OC98U #1-586 Acq: l-OCT-199817:35:45 GC EI+ Voltage SIR Autospec-Ultima
Sample*! Text:ST1001 :CS-1 :265-04A :: Exp:PAHAIR
204.9888 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
A1.42E6
95 J f&.yiKS nl$E? ,1/H
A1.34E6 • • ' ^^ "^ f^'A i« v
90 J A5.13E5 . A9.61E5 '^1.474
851
80
75 J
70
65
60
55 J
50 J
45 J
40J
35 J
30 J
251
20
15
0-
15:
A3.41E5
A5.51E5
2.0E6
)0
-i 1 1 r-
' 16:00
17:i
18:bo
19:0
20:00
-1.9E6
-1.8E6
-1.7E6
-1.6E6
A.5E6
-1.4E6
-1.3E6
-1.2E6
1.1E6
-9.7E5
L8.6E5
17.5E5
16.5E5
-5.4E5
-4.3E5
-3.2E5
-2.2E5
-1.1E5
O.OEO
Time
-------
File:010C98U #1-1051 Acq: l-OCT-1998 17:35:45 GC EI+ Voltage SIR Autospec-Ultima
Sample*! Text:ST1001 :CS-1 :265-04A : : Exp:PAHAIR
202.0782 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
80
70 J
60 J
SO:
40J
30:
20 J
10 J
0
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7.2E6
L6.4E6
L5.7E6
L5.0E6
L4.3E6
L3.6E6
L2.9E6
2.1E6
Ll.4E6
7.2E5
O.OEO
Time
21:36 21:48 22:00 22:12 22:24 22:36 22:48 23:00
212.1410 F:3 SMO(1,3) PKD(5,3f3,0.10%,10000.0,0.00%,F,T)
100 S.
90:
80,
70.
60:
sol
40:
30-
201
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244.1974 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
90
80 j
70
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50-
40
30-
20 J
10 J
0
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L4.7E7
L4.1E7
L3.5E7
L2.9E7
2.3E7
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24:4
24:2
A1.12E8
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L3.9E7
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L3.0E7
L2.6E7
L2.1E7
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L1.3E7
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4.3E6
O.OEO
Time
-------
File:01OC98U #1-1051 Acq: l-OCT-1998 17:35:45 GC EI+ Voltage SIR Autospec-UItima
Sample*! Text:ST1001 :CS-1:265-04A:: Exp:PAHAlR
1009
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80.:
70 J
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50:
40:
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-------
10
File:01OC98U #1-1051 Acq: l-OCT-1998 17:35:45 GC E1+ Voltage SIR Autospec-UItima
Sampled Text:ST1001 :CS-1 :265-04A :: ExprPAHAIR
1009
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Time
-------
Flle:01OC98U #1-915 Acq: l-OCT-1998 17:35:45 GC EI+ Voltage SIR Autospec-Ultima
Sample*! Text:ST1001 :CS-1 -.265-04A :: Exp:PAHAK
252.0939 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
90
80
70 J
60
50 -
40_
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10
A2.28E7
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31
32:00
33:C
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264.1692 F:4SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
90.
80
70
60
50 J
40
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0.
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-------
File:01OC98U #1-915 Acq: l-OCT-1998 17:35:45 GC EI+ Voltage SIR Autospec-
Samplell Text:ST1001 :CS-1 :265-04A :: Exp:PAHAIR
276.0939 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
90.
80
70-
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50-
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30 j
20-
10
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36:60 37:60
278.1096 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
40:60
8.0E5
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-6.4E5
15.6E5
L4.8E5
4.0E5
13.2E5
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_1.6E5
8.0E4
O.OEO
Time
100 S
901
80
70 -
60:
50-
40
30
20
10
A4.57E6
38:«
39:00
36:t
37:0
38:0
39:60
40:00
_4.9E5
4.4E5
L3.9E5
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L9.8E4
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O.OEO
Time
-------
F!le:01OC98U #1-915 Acq: l-OCT-1998 17:35:45 GC EI+ Voltage SIR Autospec-Ultima
Sample*! Text:ST1001 :CS-1:265-04A :: Exp:PAHAIR
276.0939 F:4 SMO(1,3) PKD(5,3,3,0.10%, 10000.0,0.00%,F,T)
100 Z
80 J
60 J
40:
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A6.08E6 A
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36:00 37:00 38:6o 39:00 40:00 41:(
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6.4E5
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288.1692 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100
80
60
40-
20.
0:
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IOC98U #1-915 Acq: l-OCT-1998 17:35:45 GC EI+ Voltage SIR Autospec-Ultima
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File:01OC98U 11-508 Acq: l-OCT-1998 18:22:05 GC EI+ Voltage SIR Autospec-Ultima
Sample*2 Text:ST1001A :CS-2 :265-04B : Exp:PAHAIR
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File:010C98U #1-508 Acq: l-OCT-1998 18:22:05 GC EI+ Voltage SIR Autospec-Ultima ^
Sampled Text:ST1001A :CS-2 :265-04B : Exp:PAHAIR
130.9920 S:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F(T)
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File:010C98U #1-585 Acq: l-OCT-1998 18:22:05 GC EI+ Voltage SIR Autospec-Ultima
Sample/ft Text:ST1001A :CS-2 :265-04B : ExprPAHAIR
166.0798 S:2 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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File:01OC98U 11-585 Acq: l-OCT-199818:22:05 GC EI+ Voltage SIR Airtospec-Ulthna
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File:01OC98U #1-585 Acq: l-OCT-1998 18:22:05 GC EI+ Voltage SIR Autospec-Ultlma
Sampled Text:ST1001A :CS-2 :265-04B : Exp:PAHAIR
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File:01OC98U #1-1052 Acq: l-OCT-1998 18:22:05 GC EI+ Voltage SIR Autospec-UItima
Sampled Text:ST1001A :CS-2 :265-04B : Exp:PAHAIR
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Flle:01OC98U #1-1052 Acq: l-OCT-1998 18:22:05 GC EI+ Voltage SIR Autospec-Ultima
Sampled Text:ST1001A :CS-2 :265-04B : Exp:PAHAIR
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File:01OC98U #1-915 Acq: l-OCT-1998 18:22:05 GC EI+ Voltage SIR Autospec-Ultlma
Sample*! Text:ST1001A :CS-2 :265-04B : Exp:PAHAIR
276.0939 S:2 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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-------
File:010C98U #1-915 Acq: l-OCT-1998 18:22:05 GC EI+ Voltage SIR Autospec-Ultima
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F1le:01OC98U 11-915 Acq: l-OCT-1998 18:22:05 GC EI+ Voltage SIR Autospec-Ultima
Sampled Text:ST1001 A :CS-2 :265-04B : Exp:PAHAIR
268.9824 S:2 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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-------
F!le:01OC98U #1-508 Acq: 1-OCT-I998 19:08:27 GC EI+ Voltage SIR Autospec-Ultima
Sampled TextrSTlOOlB :CS-3 :265-04C : ExprPAHAIR
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File:01OC98U #1-508 Acq: l-OCT-1998 19:08:27 GC EI+ Voltage SIR Autospec-UHima
Sampled Text:ST1001B :CS-3 :265-04C : Exp:PAHAIR
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-------
File:010C98U #1-508 Acq: l-OCT-1998 19:08:27 GC EH- Voltage SIR Autospec-Uttima
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File:01OC98U #1-586 Acq:
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File:01OC98U #1-586 Acq: l-OCT-1998 19:08:27 GC EI+ Voltage SIR Autospec-Ultima
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Time
-------
File:01OC98U #1-1052 Acq: l-OCT-1998 19:08:27 GC E1+ Voltage SIR Autospec-Ultima
Sampled Text:ST1001B :CS-3 :265-04C : Exp:PAHAlR
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-------
F1le:01OC98U #1-1052 Acq: l-OCT-1998 19:08:27 GC EI+ Voltage SIR Autospec-Ultima
Sampled Text:ST1001B :CS-3 :265-04C : Exp:PAHAlR
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File:01OC98U #1-915 Acq: l-OCT-1998 19:08:27 GC E1+ Voltage SIR Autospec-Ultitna
Sampled Text:ST1001B :CS-3 :265-04C : Exp:PAHAIR
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-------
File:010C98U #1-915 Acq: l-OCT-1998 19:08:27 GC EI+ Voltage SIR Autospec-Ultima
Sample*? Text:ST 100IB :CS-3 :265-04C : Exp:PAHAIR
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L3.3ES
O.OEO
Time
'35:48 ' 36:00 '36:i2 ' ' 36:24 '36:36 36:48' 37:00 37:i2 37:24
37:36
37:48
38:00
-------
F1le:01OC98U # 1-915 Acq: l-OCT-1998 19:08:27 GC E1+ Voltage SIR Autospec-Ultima
Sampled Text:ST1001B :CS-3 :26S-04C : Exp:PAHAIR
276.0939 S:3 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
80
60:
40
20 J
0
A5.49E7
A5.04E7
5.3E6
4.2E6
:3.2E6
-2.1E6
-1.1E6
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I- -1 | 'T' "I '"' I "•!•' —I "— r i i 1
36:00 37:00 38:
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39:00
40:
41:
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&OO.1
100 S
80:
60:
40:
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0:
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-------
File:010C98U #1-915 Acq: l-OCT-1998 19:08:27 GC El+ Voltage SIR Autospec-Ultima
Sampled TextrSTlOOlB :CS-3 :265-04C : Exp:PAHAIR
268.9824 S:3 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 % "
90 j
80
70 j
«OJ
50:
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30 j
20 J
10 J
0
A1.51E6
A5.77E6 A2.39E6
- •-
A1.59E6
A5.06E5
30:6o 31:00 32:00 33:6fl 34:00
280.9824 S:3 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 % A7.83E6 A1.30E7
90
80 J
701
60 J
SO:
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30 J
20.:
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0-
_7.6E6
6.9E6
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3J5:00 36:60 37:6o 38:6o 39:00 40:00 41:00 Time
A1.27E7 A1.67E7 _ A8t33E6 . „ ^2.6E7
6.1E6
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4.6E6
3.8E6
3.1E6
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32:60 '33:6o '34:00 ' 35:6o ' '36:00 ' 37:6fl ' ' '38:60 39:6o 40:6o ' '
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L1.SE7
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10 Time
30:<
31:
1:i
-------
File:010C98U #1-508 Acq: l-OCT-1998 19:54:48 GC EI+ Voltage SIR Autospec-UItima
Sampled Text:ST1001C :CS-4:265-04D : ExprPAHAIR
128.0626 5:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
1009
80-
60-
40_
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0
134.0
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80-
60_
40-
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60 j
40-
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142.0
100 S
902
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782 S:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
7 Al
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A1.65E7
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8:00 9:do 10:00 11:00 12:6o
110 S:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
AS. 3E7
8:do 9:do 10:6o ll:6o 12:6o
F7.4E7
L5.9E7
L4.4E7
L3.0E7
L1.5E7
: O.OEO
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9.8E2
L7.8E2
L5.9E2
L3.9E2
L2.0E2
; O.OEO
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L2.7E7
L2.0E7
L1.4E7
L6.8E6
: O.OEO
Time
F3.8E7
L3.0E7
L2.3E7
L1.5E7
L7.6E6
-O.OEO
Time
-1.8E7
-1.5E7
-1.1E7
-7.4E6
.3.7E6
O.OEO
Time
-------
F1le:010C98U #1-508 Acq: l-OCT-1998 19:54:48 GC EI+ Voltage SIR Autospec-Ultima
Sampled Text:ST1001C :CS-4 :265-04D : Exp:PAHAIR
152.0626 S:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100S.
80:
60:
40:
20:
12:36 12:48 13:00 13:12 13:24
160.1128 S:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 a A
80:
60
40:
20-
12:36 12:48 13:00 13:12 13:24
154.0782 S:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
80:
60:
40:
20 J
12:36 12:48 13:6o 13:i2 13:24
164.1410 S:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
80:
60:
40:
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0 ,,,,,,,, , ,
12:36 12:48 13:00 13:ll 13:24
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i6.36E7
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13:36 13:48 14:6o 14:12 14:24 14:36 14:48 15:
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13:36 13:48 14:6o 14:12 14:24 14:36 14:48 15:0
4.2E7
:3.4E7
:2.5E7
-1.7E7
8.5E6
O.OEO
10 Time
2.1E7
-1.7E7
-1.3E7
-8.5E6
.4.2E6
O.OEO
K) Time
2.8E7
L2.2E7
:1.7E7
-1.1E7
-5.6E6
O.OEO
)0 Time
-1.2E7
L9.9E6
L7.4E6
-5.0E6
-2.5E6
O.OEO
0 Time
-------
File:01OC98U (H-508 Acq: l-OCT-1998 19:54:48 GC EI+ Voltage SIR Autospec-Uttima
Sampled Text:ST1001C :CS-4 -.265-04D : Exp:PAHAIR
130.9920 S:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 S
95
90-
85_
80.
75-
70:
65:
60:
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40:
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:5.6E7
:5.0E7
L4.5E7
^3.9E7
-3.4E7
2.8E7
2.2E7
1.7E7
1.1E7
5.6E6
O.OEO
0 Time
-------
File:01OC98U #1-586 Acq: l-OCT-1998 19:54:48 GC EI+ Voltage SIR Autospec-UItima
Sampled Text:ST1001C :CS-4 .-265-04D : ExprPAHAIR
166.0798 S:4 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
1005
90-
80-
70-
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20 J
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0 =
15:
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A1.06E8 r4.7E7
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t)0 15:i2 15:24 15:36 15:48 16:00 16:12 16:24 16:36 16:48 17:
L4.2E7
L3.8E7
L3.3E7
L2.8E7
L2.3E7
L1.9E7
J.1.4E7
L9.4E6
L4.7E6
'•• O.OEO
K) Time
172.0984 S:4 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
1009
90 J
80 J
70 J
60 J
50 J
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0 15:i2 15:24 15:36 15:48 16:00 16:12 16:24 16:36 16:48 17:1
L2.2E3
L1.9E3
L1.7E3
L1.4E3
L1.2E3
L9.6E2
L7.2E2
L4.8E2
L2.4E2
O.OEO
0 Time
176.1410 S:4 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 %
90 -i
80 J
70 J
60-
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20 J
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-8.6E6
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-------
File:010C98U #1-586 Acq: l-OCT-1998 19:54:48 GC EI+ Voltage SIR Autospec-Ultima
Sampled Text:ST1001C :CS-4 .-265-04D : ExprPAHAIR
178.0782 S:4 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100
90
80
70-
60_
50
40-
30
20 _
10:
A1.77E8
A2.C
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-8.0E7
-7.2E7
-6.4E7
-S.6E7
4.8E7
-4.0E7
L3.2E7
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1.6E7
8.0E6
O.OEO
)0 Time
w-f—i—i—i—i—i—I—i—i—i—i—i—i—i—i—i—i—i—I—r—i—i—i—i—I—i—i—r*—i—i—r—r
18:00 18:12 18:24 18:36 18:48 19:00
188.1410 S:4 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
19:12
19:24
19::
19:48
100 S.
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19:48
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-------
CO
FHe:01OC98U #1-586 Acq: l-OCT-1998 19:54:48 GC EI+ Voltage SIR Autospec-Ultima
Sampled TexCSTlOOIC :CS-4 :265-04D : Exp:PAHAlR
ut.yi
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16.9E5
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Time
-------
CO
Fiie:01OC98U #1-1051 Acq: l-OCT-1998 19:54:48 GC EI+ Voltage SIR Autospec-Ultima
Sampled Text:ST1001C :CS-4:265-04D : Exp:PAHAIR
202.0782 S:4 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
To! A3-17E8
80
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40
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'23:48 ' ' 24:66 ' ' 24:^2 24:24
1.4E8
1.3E8
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2.8E7
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Time
A1.31E8
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212.1410 S:4 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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90 J
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21:36 21:48 22:00 22:12 22:24 22:36 22:48
244.1974 S:4 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 S.
90 J
80 J
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23:b 23:14 23:36 23:48 24:00
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5.2E7
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L4.0E7
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0.
A8.35E7
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3.2E7
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Time
-------
File:01OC98U #1-1051 Acq: l-OCT-1998 19:54:48 GC EI+ Voltage SIR Autospec-Ultima
Sampled Text:ST1001C :CS-4:265-04D : Exp:PAHAIR
228.0939 S:4 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
90-
80
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26:
M) ' ' 26:12 ' ' 26:24 ' ' 26:36 ' ' 26:48 ' ' 27:00 ' ' 27:12 ' ' 27:24 27:36 27^48 " 28:00 28:ii '28:24 28:36 ' ' 28:48 29:-
240.1692 S:4 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
90
80
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40
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26:
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' ' :i2
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File:01OC98U #1-915 Acq: l-OCT-1998 19:54:48 GC EI+ Voltage SIR Autospec-Ultima
Sample** Text:ST1001C :CS-4 :265-04D : Exp:PAHAlR
252.0939 S:4 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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264.1692 S:4 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
32:00
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-------
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File:010C98U #1-915 Acq: l-OCT-1998 19:54:48 GC EI+ Voltage SIR Autospec-Ultima
Sampled Text:ST1001C :CS-4:265-04D : Exp:PAHAIR
276.0939 S:4 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
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278.1096 S:4 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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-------
A1.38E8
File:01OC98U #1-915 Acq: l-OCT-1998 19:54:48 GC EI+ Voltage SIR Autospec-Ultima
Sample*! Text:ST1001C :CS-4:265-04D : Exp:PAHAIR
276.0939 S:4 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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292.1974 S:4 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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File:01OC98U #1-915 Acq: l-OCT-1998 19:54:48 GC EI+ Voltage SIR Autospec-Ultima
Sampled Text:ST1001C :CS-4 :265-04D : Exp:PAHAlR
268.9824 S:4 F.-4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 9
90:
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70 j
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50.
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-6.7E6
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36:00 37:00
30:00 31:00 32:00 33:60 34:00 35:6o
280.9824 S:4 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100% A1.52E7 A7.68E6 A1.47E7 A1.5JE7 A1.77E? A7.71E6
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30:00 31:00 32:00 33:6o 34:00 35:00 36:00 37:00 38:00 39:00 40:00 41:
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0 Time
-------
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File:01OC98U #1-508 Acq: l-OCT-1998 20:41:10 GC EI+ Voltage SIR Autospec-Uttima
Sampled Text:ST1001D :CS-5 :265-04E : Exp:PAHAIR
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134.0827 5:5 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T) t 1I71
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3.5E7
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782 5:5 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
. A3.02E8
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8:do 9:do 10:6o 11:00 12:00 Time
152.1410 5:5 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100% A5.39E7
80 J
60 J
40 J
20 1
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1.8E7
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R.rin 9:do 10:00 11:00 12:00 Time
-------
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File:01OC98U #1-508 Acq: l-OCT-1998 20:41:10 GC EI+ Voltage SIR Autospec-Ultima
Sampled Text:ST1001D :CS-5 :265-04E : Exp:PAHAIR
152.0626 S:5 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 S
80:
60:
40:
20:
0:
160.1
100 S
80:
60:
40:
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154.0
100 S
80:
60:
40:
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0:
1(4.1
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80-
60-
40-
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12:36 12:48 13:00 13:12 13:24 13:36 13:48 14:00 14:12
128 5:5 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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12:36 12:48 13:00 13:12 13:24 13:36 13:48 14:00 14:12
782 S:5 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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410 S:5 SMO(1,3) PKD(5>3,3,0.10%,10000.0,0.00%,F,T)
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Flle:01OC98U #1-585 Acq: l-OCT-1998 20:41:10 GC EI+ Voltage SIR Autospec-Ultima
Sample/ft Text:ST1001D :CS-5 :265-04E : Bxp:PAHAIR
166.0798 S:5 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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172.0984 S:5 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100
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70 j
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16:55
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176.1410 S:5 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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Flle:01OC98U #1-1052 Acq: l-OCT-1998 20:41:10 GC EI+ Voltage SIR Autospec-Ultima
Sampled Text:ST1001D :CS-5 :265-04E : Exp:PAHAlR
202.0782 S:5 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
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23:66 ' 23:ii ' ' 23:24 23-36 ' 23:48 ' 24:66 24:ii ' ' 24:24
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Time
-5.9E7
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-4.1E7
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Time
i i I i i i—iii I i i i i i I i i i i i I i i i i i I i i i i i i i
21:36 21:48 22:60 22:12 22:24 22:36 22:48
212.14108:5 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 S.
90 J
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701
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40
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21:36 21:48 22:00 22:12 22:24 22:36 22:48
244.19748:5 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 3.
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L2.2E7
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Time
21:36 2i:48
-------
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CO
File:01OC98U #1-1052 Acq: l-OCT-1998 20:41:10 GC EI+ Voltage SIR Autospec-UHima
Sampled Text:ST1001D :CS-5 :26S-04E : Exp:PAHAlR
228.0939 S:5 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 % A6.71E8
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692 S:5 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0>0.00%,F,T)
A1.17E8
A8.16E7
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10 26:12 26:24 26:36 26:48 27:00 27:12 27:24 27:36 27:48 28:00 28:12 28:24 28:36 28:48 29:
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-------
File:01OC98U ffl-1052 Acq: l-OCT-1998 20:41:10 GC E1+ Voltage SIR Autospec-UItima
Samplers Text:ST1001D :CS-5 :265-04E : Exp:PAHAlR
230.9856 S:5 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,D
100%
C}
95
90:
85:
80:
75:
70:
65:
60:
55
50
45
40
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15
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2.8E7
2.6E7
2.4E7
-2.2E7
2.0E7
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1.6E7
1.4E7
1.2E7
9.8E6
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3.9E6
2.0E6
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Time
21:6o
22:00 23:60
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28
29
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Flle:010C98U #1-915 Acq: l-OCT-1998 20:41:10 GC EI+ Voltage SIR Autospec-Uitima
Sampled Text:ST1001D :CS-5 :265-04E : Exp:PAHAlR
252.0939 S:5 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100% A1.09E9
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70:
60
50
40
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10:
A1.00E9
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2.4E8
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1.9E8
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1.3E8
1.1E8
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30:00 n 31:6o ' ' 32:6o
264.1692 S:5 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
90
80:
70:
60
50-
40:
30 J
20:
10
0
30:60
A1.73E8
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33:i
34:
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33:C
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4.0E7
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2.8E7
t2.4E7
2.0E7
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8.0E6
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0 Time
-------
File:010C98U #1-915 Acq: l-OCT-1998 20:41:10 GC E1+ Voltage SIR Autospec-Ultima
Sample#5 Text:ST1001D :CS-5 :265-04E : Exp:PAHAlR
276.0939 S:5 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
90 J
80
70 -
60 j
501
40
30-
201
10 J
A4.27E8
A2.32E8
38:6o
4.6E7
Z.4.2E7
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L3.2E7
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L2.3E7
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Ll.4E7
L9.3E6
14.6E6
O.OEO
Time
"-H—i—i—|—i—i—i—i—i—p-1—I—I—l—i—r—i—l—l—l—i—r—i—i—f—i—i—r—l—r
35:48 36:00 36:12 36:24 36:36 36:48
278.1096 S:5 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 % A2.88E8
90
80 _
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60
50
404
30
20
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37:6o
37
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37:48
35:48
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Time
36
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37:1
37:2
37:
38:4
-------
File:01OC98U #1-915 Acq: l-OCT-1998 20:41:10 GC EI+ Voltage SIR Autospee-UMma
Sampled TexCSTlOOlD :CS-5 :265-04E : ExprPAHAIR
276.0939 S:5 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
288.1692 S:5 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 % A7.63E7
80 J
60
40
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O
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10
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80 J
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40J
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, A4.27E8
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36:6o 37:00 38:00 39:00 40:00 41:1
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7.5E6
4.5E6
13.0E6
1.5E6
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>0 Time
—i 1 r 1 r—« 1 1 1 r 1 1 I • I I I i
36:00 37:00 38:60
278.1096 S:5 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 5
801
60
40
20
0
A2.88E8
39:fl
36:00 37:00 ^8:00
292.1974 S:5 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 % A4.42E7
39:C
40:
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36:00
37:00
38:60
39:C
40:00
41:1
41:
2.9E7
L2.3E7
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)0 Time
.-4.3E6
3.5E6
2.6E6
U.7E6
8.7E5
_ :O.OEO
41 :C
0 Time
-------
File:01OC98U #1-915 Acq: l-OCT-1998 20:41:10 GC EI+ Voltage SIR Autospec-Ultima
Sampled Text:ST1001D :CS-5 :265-04E : Exp:PAHAlR
268.9824 S:5 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
90
80 -
70 -
60-
50
40-
30-
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37:6o 38:00 39:6fl 40:6o
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)0 Time
I—I—I—I—1—1—1—1—I—I—1—p—1—1—I—1—I—1—1—1—I—I—1—1—1—I—I—I—1—1—1—I—I—1—I—1—1 I [ I
30:00 31:00 32:00 33:00 34:6o 35:00 36:00
280.9824 S:5 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 % „ A5.95E6 A3.66E6 A1.25E7 A7.
90
80 J
70
60
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1.4E7
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19.5E6
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-2.4E6
O.OEO
0 Time
-------
File:01OC98U #1-509 Acq: l-OCT-1998 21:27:31 GC E1+ Voltage SIR Autospec-Ultlma
Sampled Text:SB1001 :Solvent Blank :C- Exp:PAHAlR
128.0626 5:6 SMO(1,3) PKD(5,3,3,0.10%, 10000.0,0.00%, F,T)
100% Al.65
8*00 9*00
136.1128 S:6 SMO(1,3) PKD(5,3,3,0.10%,10000.6,0.00%,F,T)
8*00 9*00
142.0782 S:6 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 S.
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60 J
40
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0
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134.0827 S:6 SMO(1,3) PKD(5,3,3,0.
100%
-5.0E4
4.0E4
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-T -] 1 1 1 1 1 J . 1—
8:00 9:00
152.1410 S:6 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
80
9:00
10:C
TT-bo
12:0
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-------
c.O
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File:01OC98U #1-509 Acq: l-OCT-1998 21:27:31 GC EI+ Voltage SIR Autospec-Ultima
Sampled Text:SB1001 :Solvent Blank :C- Exp:PAHAlR
152.0626 S:6 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
80
60.
40
20
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14:38
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12:36 12:48 13:00 13:12 13:24 13:36 13:48 14:00 14:12 14:24 14:36
160.1128 S:6 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
13:30 14:17
2.6E4
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-6.5E3
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12:36 12:48 13:6o 13:12 13:24 13:36 13:48 14:6o 14:h 14:24 14:36 14:48 15:00 Time
154.0782 S:6 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
A1.03E5
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164.1410 S:6 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
1.1E5
17.6E4
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40
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13:14
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14:17
4:52
15:00 Time
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t-3.2E2
L2.4E2
-1.6E2
J-7.9EI
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-------
O
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File:01OC98U #1-509 Acq: l-OCT-1998 21:27:31 GC EI+ Voltage SIR Autospec-Ultima
Sampled Text:SB1001 :Solvent Blank :C- Exp:PAHAlR
130.9920 S:6 SMO(1,3
,0.10%,10000.0,0.00%,F,T)
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90:
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File:01OC98U #1-584 Acq: l-OCT-1998 21:27:31 GC EI+ Voltage SIR Autospec-Ultima
Sample#6 Text:SB1001 :Solvent Blank :C- Exp:PAHAIR
166.0798 S:6 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
T 1 1 1 1 I 1 1 1
15:24 15:36
15:00
172.0984 S:6 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
15:00 15:12 15:24 15:36 15:48 16:00
176.1410 S:6 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
15:46
16:
16:24 16:36
16:
16:48
17:
5.5E2
L4.9E2
L4.4E2
L3.8E2
L3.3E2
L2.7E2
2.2E2
1.6E2
-1.1E2
L5.5E1
O.OEO
)0 Time
15:00
-------
F»e:01OC98U #1-584 Acq: l-OCT-1998 21:27:31 GC E1+ Voltage SIR Autospec-UItima
Sampled Text:SB1001 :Solvent Blank :C- Exp:PAHAlR
178.0782 S:6 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
90-
80
70-
60-
50-
40
30 _i
20
10
0-
O
LO
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-2.4E4
-2.1E4
1.8E4
-1.5E4
L1.2E4
-9.1E3
:6.1E3
L3.0E3
LO.OEO
)0 Time
18:00 18: b 18:24 18:36 18:48 19:00
188.1410 S:6 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 * 18:55
90 J
80-
70
60
501
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30 J
20 j
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19:h
19:2
19:
19:48
20:
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20:
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2.4E3
2.1E3
:1.9E3
1.6E3
L1.3E3
1.1E3
8.0E2
L5.3E2
L2.7E2
O.OEO
0 Time
-------
-------
FHe:01OC98U #1-1052 Acq: l-OCT-1998 21:27:31 GC EI+ Voltage SIR Autospec-Ultima
Sampled Text:SB1001 :Solvent Blank :C- Exp:PAHAlR
202.0782 S:6 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
o
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21:36 21:48 22:00 22:12 22:24 22:36 22:48 23:00 23:12 23:24 23:36 23:48 24:00
212.1410 S:6 F:3 SMO(1,3) PKD(S,3,3,0.10%,10000.0,0.00%,F,T)
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24:12 24:24
21:36 21:48 22:66 22:12 22^T^22^6 ' ' 22?48 ' ' 23:66 ' ' 23:ii ' ' 23:24 2*36 ' iz&S ' ' 24:66 24:12 ' ' 24:24
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90 .J
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L6.9E3
S.9E3
5.0E3
14.0E3
-3.0E3
-2.0E3
9.9E2
O.OEO
Time
24:11
-------
File:01OC98U #1-1052 Acq: l-OCT-1998 21:27:31 GC EI+ Voltage SIR Autospec
Sampled Text:SB1001 :Solvent Blank :C- Exp:PAHAlR
228.0939 S:6 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 ft A3,
90
80_
70-
60
50 4
40
30-
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10 J
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A2.66E5
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26M 26-M ' 26:24 26:36 ' ' 26:48 ' 27:66 ' ' 27:li ' 27:24 ' ' 27:36 27:48 28:66 ' 28:li ' ' 28:24 ' 28:36 ' 28:48 29:
240.1692 S:6 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
9.1E4
8.1E4
L7.1E4
L6.1E4
L5.1E4
4.1E4
3.0E4
2.0E4
1.0E4
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0 Time
26:1
I I I I I I I I I I I I I I I [ >-| I I I I I | I I I I 1 p-TS—l-T- T-l—r ..III l-l I I I I I
0 26:12 26:24 26:36 26:48 27:00 27:12 27:24 27:36 27:48 28:
O.OEO
0 Time
-------
O
File:01OC98U #1-1052 Acq: l-OCT-1998 21:27:31 GC EI+ Voltage SIR Autospec-Ultima
Sampled Text:SB1001 :Solvent Blank :C- Exp:PAHAIR
230.9856 S:6 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,FJ)
100%
95 A1.37E7
90
85 J
80
75_
70 J
65 j
60
55 J
50
45
40
35 J
30
25 _
20 _
15J
10 J
5
0
A1.52E7
.-3.9E7
3.7E7
L3.5E7
L3.3E7
1.3.1E7
:2.9E7
2.7E7
:2.5E7
2.3E7
12.1E7
L1.9E7
L1.7E7
i.l.5E7
-1.4E7
L1.2E7
.9.6E6
7.7E6
5.8E6
3.9E6
1.9E6
O.OEO
Time
21:C
22:0
23:0
24:(
25:60 26:60 IT-fitT 28:00 29:
-------
FiIe:01OC98U #1-915 Acq: l-OCT-1998 21:27:31 GC EI+ Voltage SIR Autospec-Ultima
Sampled Text:SB1001 :Solvent Blank :C- Exp:PAHAIR
252.0939 S:6 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100
90J
80
70-
60-
50 J
40-
30 J
20:
A1.56E6
A1.17E6
A1.17E6
3.6E5
L3.3E5
L.2.9E5
2.5E5
2.2E5
il.SES
Ll. 5E5
Ll.lES
:7.3E4
3.6E4
-O.OEO
0 Time
5.6E4
-5.1E4
4.5E4
-3.9E4
3.4E4
2.8E4
L2.3E4
1.7E4
1.1E4
_5.6E3
O.OEO
0 Time
30:00 ' 31:00
264.1692 S:6 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.
32:60
,F,T)
A2.42E5
33:60
34:
-------
File:01OC98U #1-915 Acq: l-OCT-1998 21:27:31 GC EI+ Voltage SIR Autospec-Ultima
Sampled TextrSBlOOJ :Solven( Blank :C- Exp:PAHAlR
276.0939 S:6 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 % A4.47E5
80 j
60
40
20
A2.60E5
36:00 37:00 38:00
288.1692 S:6 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,FIT)
37:47
39:fi
1009
801
60:
40:
20 :
36:32
36:00 37:00 38:00
278.1096 S:6 F:4SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 % A2.07E5
80
60:
40:
20.:
39:00
40:(
41:
.6.7E4
5.4E4
1.3E4
O.OEO
(0 Time
1.5E4
L1.2E4
L8.7E3
L5.8E3
2.9E3
O.OEO
)0 Time
4.1E4
:3.3E4
:2.5E4
1.6E4
:8.2E3
36:00 ' ' ' 37:00 ' ' '
292.19745:6 F:4SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
80
60:
40:
20
0
40:C
40:00
41:
O.OEO
)0 Time
9.7E3
:7.8E3
:5.8E3
-3.9E3
1.9E3
O.OEO
41:00 Time
39:00
41:
40:51
36:00
37:00 38:00
39:00
40:t
-------
r-J
r-H
0:
File:OIOC98U #1-915 Acq: l-OCT-1998 21:27:31 GC EI+ Voltage SIR Autospec-UItima
Sampled Text:SB1001 :Solvent Blank :C- Exp:PAHAIR
268.9824 S:6 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100% A3.00E6 A2.97E6 A1.23E6 A1.82E6
90-
80
70:
60:
50:
40:
30:
20:
10:
A2.95E6 A2.55E6 A1.35E6
16.6E6
5.8E6
t-5.1E6
4.4E6
3.6E6
12.9E6
L2.2E6
L1.5E6
17.3E5
O.OEO
)0 Time
30:00 31:6o 32:6o 33:6o 34:00 35:6o
280.9824 S:6 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100% A1.73E7 A1.56E7 A1.08E7
90:
80
70
60 J
50
40J
30
20:
10:
36:6fl 37:00 38:i
A1.6JE7. A6.46E6
39:00 40:00
A9.06E6 Al
41:(
45E7 .-2.4E7
1
t2.1E7
1.9E7
:1.7E7
1.4E7
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7.1E6
t-4.7E6
2.4E6
30:6o '31:60' 32:6fl 33:6o 34:6o 35:6o 36:00 37:6fl 38:4
39:C
40:0
41:
O.OEO
0 Time
-------
Continuing Calibration
514
-------
QUANTERRA INCORPORATED
West Sacramento
Daily Standard Checklist
Dioxin/Furan High Res
STD ID <;rtaos-a
_Method ID
Column ID
Standard Solution
Analyzed By_
Reviewed By IA>
_Prepared By &tCA(.&-
Date Reviewed /
AWMOfSa^OFPAl^T^^W^AK^^^^ -' - , ° :
Standard, CPSM, and solvent blank present?
Copy of Instrument logfile present?
CPSM blow up and peak profile present?
Curve summary present?
Summary of 1613A criteria present?
Daily standard within method specified limits*?
Daily ion abundance ratios within limits?
CPSM valley < 25%?
CPSM window correct?
Samples analyzed within 1 2 hrs of daily standard?
>**, •wnxNxm*?*: m.
S/CD
/
y0
/
*to
y
/Ofl
A/A CD
/rO
/
^^^XRfinpnPr
/£>
/
XP)
S
A/ A-
/
VA
^'^fO
^(?j
^
COMMENTS:
Oft
For NCASI 551, Control Limit (CD = +1- 20% from curve RRFs for all analytes.
For Method 8290, CL = +/- 20% from curve RRFs for native analytes, CL = +/- 30% from curve RRFs fo
labeled compounds.
For Method 1613A, see 3rd Revision to Method 1613 Performance Specifications, Table 7.
OA-231 get
-------
08-OCT-1998 05:06:33 PM Dioxin Furan ConCal RESULTS
Mass Spec : ULTIMA
GC Column : DB-5
Data file : 050C98U
Weight : 1
Name
dlO-2-MethyInaphthalene
d8-Naphthalene
Naphthalene
2-Methylnaphthalene
d8-Acenaphthylene
Acenaphthylene
dlO-Acenaphthene
Acenaphthene
dlO-Anthracene
dlO-Fluorene
Fluorene
dl0-Phenanthrene
Phenanthrene
Anthracene
d!4-Terphenyl
dlO-Fluoranthene
Fluoranthene
dlO-Pyrene
Pyrene
d!2-Benzo(a)anthracene
Benzo(a)anthracene
d!2-Chrysene
Chrysene
d!2-Benzo(e)pyrene
d!2-Benzo(b)fluoranthene
Benzo(b)fluoranthene
d!2-Benzo(k)fluoranthene
Benzo(k)fluoranthene
dl2-Benzo(a)pyrene
Benzo(e)pyrene
Benzo(a)pyrene
d!2-Perylene
Perylene
d!2-Indeno(123 -cd)pyrene
Indeno(12 3 -cd)pyrene
d!4-Dibenz(ah)anthracene
Dibenz(ah)anthracene
d!2-Benzo(ghi)perylene
Benzo(ghi)perylene
Results : 050C98U191A.RES
Date analyzed
ST1005A :CS-3 :265-04C : Ex
Total Isotope R. T. RRF
Response Ratio mm:ss
81518800 1.00 Y
112288600 1.00 Y
128959200 1.00 Y
80905200 1.00 Y
112023200 1.00 Y
95701800 1.00 Y
64072200 1.00 Y
64509200 1.00 Y
54703600 1.00 Y
66098400 1.00 Y
69408600 1.00 Y
153558000 1.00 Y
126066600 1.00 Y
117413800 1.00 Y
142614800 1.00 Y
171990400 1.00 Y
195860200 1.00 Y
174999400 1.00 Y
206378000 1.00 Y
105010600 1.00 Y
107742200 1.00 Y
136000800 1.00 Y
128763000 1.00 Y
184142400 1.00 Y
111668600 1.00 Y
133092400 1.00 Y
157235400 1.00 Y
178773800 1.00 Y
125085400 1.00 Y
204634000 1.00 Y
130062000 1.00 Y
97250400 1.00 Y
175006400 1.00 Y
72248800 1.00 Y
46600000 1.00 Y
38514000 1.00 Y
42946000 1.00 Y
70462600 1.00 Y
68319800 1.00 Y
PAHAIRCAL3.TRG
05-OCT-98
Dev
10:
8:
8:
10:
13:
13:
14:
14:
19:
15:
15:
18:
18:
19:
24:
22:
22:
23:
23:
27:
27:
27:
27:
31:
30:
30:
30:
30:
31:
31:
31:
32:
32:
36:
36:
36:
36:
37:
37:
28
17
22
33
29
32
4
10
2
45
51
53
56
5
10
46
49
27
31
19
23
26
31
38
44
49.
49
53
49
44
54
6
12
29
35
33
43
43
52
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
0.
1.
1.
0.
1.
0.
0.
1.
-1.
1.
1.
2.
0.
0.
-1.
1.
1.
1.
1.
0.
1.
0.
0.
-2.
0.
1.
0,
1
0
1
1
0
1
0
0
0
1
0
0
00
38
15
72
37
85
79
01
00
21
05
81
82
76
00
21
14
23
18
74
,03
,95
,95
.00
.61
.19
.85
.14
.68
.64
.04
.53
.80
.39
.64
.21
.12
.38
.97
100.
100.
100.
100.
100.
100.
100.
100.
100.
100.
100.
100.
100.
100.
100.
100.
100.
100.
100.
100.
100.
100.
100.
100.
100.
100.
100.
100.
100.
100.
100.
100.
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
,00
.00
.00
.00
100.00
100
100
100
100
100
100
.00
00
b:
.00
.00
.00
.00
-23
-4
10
18
-17
15
-12
-11
-8
3
-14
-21
-19
-8
-22
-6
-9
-20
-18
-18
26
-8
-13
-5
-8
1
-6
-18
3
5
, r. 7
3
-13
-6
-12
-------
OmC?20 J
FILE
SAMP LAB.
No. SAMP No
(1)
050C98U
050C98U
050C98U
050C98U
050C98U
050C98U
050C98U
050C98U
050C98U
050C98U
050C98U
050C98U
050C98U
050C98U
050C98U
050C98U
050C98U
050C98U
050C98U
050C98U
050C98U
050C98U
050C98U
050C98U
05OC98U
050C98U
050C98U
050C98U
050C98U
05OC98U
050C98U
050C98U
050C98U
050C98U
05OC98U
05OC98U
050C98U
050C98U
050C98U
050C98U
050C98U
050C98U
050C98U
050C98U
050C98U
050C98U
050C98U
050C98U
050C98U
050C98U
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
ST1005
SB1005
301361-MBB
301361-B
301361-MBC
301361-C
301361-MBD
301361-D
301361-DD
301361-E
301361-MBE
301361-CD
301361-ED
301361-5
301361-6
301361-7
301361-9
SB1005A
ST1005A
SB1005B
301361-11
301361-12
301361-13
301361-14
301361-15
301361-BD
300681-lDI
300681-2DI
300681-7DI
300681-10D
300681-llD
SB1005C
301361-ED
CUSTOMER CLEAN
ID UP 1
(SDS)
CS-3 265-04C
Solvent Blank C-8
METHOD BLANK-B TRAIN
LCS-B
METHOD BLANK -C
LCS-C
METHOD BLANK -D
LCS-D
DCS-D
LCS-E
METHOD BLANK -E
DCS-C
DCS-E
2097-2101
2104-2108
2111-2114
2118-2121
Solvent Blank C-8
CS-3 265-04C
Solvent Blank C-8
2128-2132
2139-2140
2141-2145
2146-2150
2151-2155
DCS-B
100X S-MM5-2-F TRAIN
100X S-MM5-1B-F
100X S-MM5-3-F
100X S-MM5-4-F
100X S-MM5-5-F
Solvent Blank C-8
DCS-E
CLEAN
UP 2
(D2)
PAH
PAH
PAH
PAH
PAH
PAH
PAH
PAH
PAH
PAH
PAH
PAH
PAH
PAH
PAH
PAH
PAH
PAH
PAH
PAH
PAH
PAH
PAH
PAH
PAH
PAH
PAH
TYPE CONCn .
(1)
1
1
VSE-25 0.500
0.500
0.333
0.333
0.500
0.500
0.500
0.333
0.333
0.333
0.333
0.333
0.333
0.500
0.500
1
1
1
0.333
0.500
0.333
0.333
0.333
0.500
VSE-23 0.500
0.500
0.500
0.500
0.500
1
0.333
10-05-98 CP
bl'
-------
Peak Locate Examination: 5-OCT-1998 :17:47 File.-050C98U
Experiment:PAHAIR Function:! Reference:PFK
PPM
200
Volts
0.6874
118.99202
PPM
200
Volts
1.2594
130.99202
Volts,
o.osooi
142.99202
PPM
200
Volts
0.0811
149.99042
PPM
200
Volts
0.0165
154.99202
PPM
200
Volts
0.3822
168.98882
bio
-------
Peak Locate Examination: 5-OCT-1998:17:48 File:050C98U
Experiment:PAHAIR Function:2 Reference:PFK
-------
Peak Locate Examination: 5-OCT-1998:17:49 File:050C98U
Experiment:PAHAIR Function:3 Reference:PFK
PPM
200
Volts
0.0975
192.98882
PPM
200
Volts
0.0320
204.98882
PPM
200
Volts
0.1556
218.98563
PPM
200
Volts
0.4717
230.98563
PPM
200
Volts
0.2316
242.98563
PPM
200
Volts)
0.0523!
254.98563
-------
Peak Locate Examination: 5-OCT-1998:17:50 File:050C98U
Experiment:PAHAIR Function:4 Reference:PFK
Volts
0.2746
242.98563
Volts
0.0499
254.98563
268.98245
Volts
0.2646
280.98245
-------
OCO
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h-
>o
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o
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9
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•—in i
t— » ^
^ m to
30"
Ogg
S.5S
-------
06-OCT-1998 05:44:50 PH
Mass Spec : ULTIMA
GC Column : DB-5
MULT 3260V
d12-Benzo(a)anthracene
Benzo(a)anthracene
d12-Chrysene
Chrysene
d12-Benzo(b)fluoranthene
Benzo(b)fluoranthene
dt2-Benzo(k)fluoranthene
Benzo(k)fluoranthene
d12-Benzo(a)pyrene
Benzo(e)pyrene
Benzo(a)pyrene
d12-Perylene
Perylene
d12-Indeno(123-cd)pyrene
Indeno(123-cd)pyrene
d14-Dibenz(ah)anthracene
Dioxin Furan CALIBRATION TABLE
File name
Date analyzed
PAHX100198U.RRF
01-OCT-98
C-l
INITIAL CALIBRATION CURVE
Mean
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
0
1
0
1
0
1
.47
.28
.67
.16
.48
.30
0.99
1
0
1
1
0
1
0
0
0
.20
.74
.62
.11
.65
.74
.37
.60
.20
S.D
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
017
069
018
057
026
085
022
061
023
085
084
029
145
040
031
031
%RSD
3.678
5.356
2.660
4.881
5.475
6.540
2.196
5.111
3.065
5.216
7.550
4.558
8.315
10.705
5.150
15.283
1
100.00
49.29
0.49
10.00
12.57
1.26
100.00
69.85
0.70
10.00
11.72
1.17
100.00
48.56
0.49
10.00
13.55
1.35
100.00
96.32
0.96
10.00
12.67
1.27
100.00
71.22
0.71
10.00
17.26
1.73
10.00
12.23
1.22
100.00
60.50
0.60
10.00
18.19
1.82
100.00
37.05
0.37
10.00
5.81
0.58
100.00
19.47
0.19
2
100.00
46.35
0.46
50.00
65.11
1.30
100.00
67.21
0.67
50.00
62.55
1.25
100.00
46.43
0.46
50.00
66.19
1.32
100.00
96.76
0.97
50.00
63.60
1.27
100.00
75.03
0.75
50.00
82.73
1.65
50.00
58.74
1.17
100.00
67.68
0.68
50.00
93.11
1.86
100.00
32.97
0.33
50.00
32.63
0.65
100.00
17.67
0.18
3
100.00
46.32
0.46
100.00
117.72
1.18
100.00
64.96
0.65
100.00
112.19
1.12
100.00
46.37
0.46
100.00
117.89
1.18
100.00
98.32
0.98
100.00
115.65
1.16
100.00
71.96
0.72
100.00
150.84
1.51
100.00
104.99
1.05
100.00
66.13
0.66
100.00
154.60
1.55
100.00
34.97
0.35
100.00
58.18
0.58
100.00
18.57
0.19
4
100.00
44.58
0.45
200.00
260.77
1.30
100.00
66.40
0.66
200.00
221.26
1.11
100.00
46.62
0.47
200.00
249.84
1.25
100.00
100.62
1.01
200.00
233.26
1.17
100.00
74.50
0.74
200.00
313.45
1.57
200.00
205.81
1.03
100.00
66.18
0.66
200.00
326.69
1.63
100.00
37.60
0.38
200.00
117.22
0.59
100.00
20.38
0.20
5
100
47
0
500
680
6
.00
.31
.47
.00
.79
1.36
100
67
0
500
575
1
100
52
0
500
695
1
100
101
1
500
575
1
100
76
0
500
826
1
500
539
1
100
62
0
500
929
1
100
43
0
500
308
0
100
25
0
.00
.57
.68
.00
.40
.15
.00
.52
.53
.00
.00
.39
.00
.05
.01
.00
.34
.15
.00
.72
.77
.00
.10
.65
.00
.70
.08
.00
.72
.63
.00
.14
.86
.00
.56
.44
.00
.65
.62
.00
.60
.26
10
-------
06-OCT-1998 05:44:52 PM
Hats Spec : ULTIMA
GC Column : OB-5
MULT 3260V
Dibenz(ah)anthracene
d12-Benzo(ghi)perylene
Benzo(ghi )perylene
13C-Fluorene
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Mean
Dioxin Furan CALIBRATION TABLE
File name : PAHX100198U.RRF
Date analyzed : 01-OCT-98
INITIAL CALIBRATION CURVE
1
22
41
06
S.O
0.
0.
0.
%RSO
152
035
125
12
8
11
.443
.601
.769
1
10
9
0
100
45
0
10
8
0
.00
.64
.96
.00
.17
.45
.00
.40
.84
2
50.00
60.24
1.20
100.00
37.67
0.38
50.00
56.16
1.12
3
100.00
129.39
1.29
100.00
38.08
0.38
100.00
107.43
1.07
4
200
.00
268.11
1
100
39
0
200
227
1
.34
.00
.49
.39
.00
.28
.14
5
500.00
651.39
1.30
100.00
44.20
0.44
500.00
559.79
1.12
100
100
100
100
100
0.00 0.000 0.000
tvl
10
-------
06-OCT-1998 11:38:23 AH
Dioxin Furan CALIBRATION TABLE
C-l
Mass Spec : ULTIMA
GC Column : DB-5
265-04A --> 265-04E;
da-Naphthalene
Naphthalene
2-Hethylnaphthalene
d8-Acenaphthylene
Acenaphthylene
d10-Acenaphthene
Acenaphthene
dIO-Fluorene
Fluorene
dIO-Phenanthrene
Phenanthrene
Anthracene
d10-Fluoranthene
Fluoranthene
d10-Pyrene
Pyrene
Multiplier 3 260V.
File name
Date analyzed
PAHAIR100198U.RRF
01-OCT-98
INITIAL CALIBRATION CURVE
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Mean
1.78
1.20
0.66
1.16
1.02
0.68
1.H
1.36
1.15
2.74
0.95
0.97
1.49
1.23
1.58
1.26
S.O.
0.143
0.205
0.138
0.071
0.034
0.040
0.071
0.169
0.078
0.383
0.041
0.179
0.154
0.044
0.157
0.067
%RSD
8.020
17.067
21.003
6.092
3.301
5.815
6.206
12.415
6.809
13.988
4.325
18.441
10.335
3.570
9.978
5.306
1
100.00
171.18
1.71
10.00
15.52
1.55
10.00
8.86
0.89
100.00
123.71
1.24
10.00
10.33
1.03
100.00
73.42
0.73
10.00
12.61
1.26
100.00
144.89
1.45
10.00
11.96
1.20
100.00
304.73
3.05
10.00
9.77
0.98
10.00
8.51
0.85
100.00
122.27
1.22
10.00
12.21
1.22
100.00
130.84
1.31
10.00
12.63
1.26
2
100.00
160.04
1.60
50.00
59.91
1.20
50.00
34.41
0.69
100.00
113.60
1.14
50.00
53.17
1.06
100.00
68.27
0.68
50.00
55.92
1.12
100.00
152.54
1.53
50.00
61.81
1.24
100.00
301.29
3.01
50.00
48.56
0.97
50.00
44.48
0.89
100.00
157.80
1.58
50.00
64.63
1.29
100.00
165.10
1.65
50.00
63.04
1.26
3
100.00
180.53
1.81
100.00
112.12
1.12
100.00
57.75
0.58
100.00
106.71
1.07
100.00
98.02
0.98
100.00
62.70
0.63
100.00
108.02
1.08
100.00
146.61
1.47
100.00
104.48
1.04
100.00
297.96
2.98
100.00
88.92
0.89
100.00
80.92
0.81
100.00
158.48
1.58
100.00
118.10
1.18
100.00
166.15
1.66
100.00
116.69
1.17
4
100.00
181.12
1.81
200.00
218.51
1.09
200.00
113.66
0.57
100.00
114.85
1.15
200.00
200.11
1.00
100.00
66.67
0.67
200.00
226.76
1.13
100.00
124.50
1.24
200.00
217.93
1.09
100.00
241.46
2.41
200.00
186.76
0.93
200.00
215.19
1.08
100.00
157.22
1.57
200.00
241.31
1.21
100.00
169.44
1.69
200.00
248.31
1.24
5
100.00
198.82
1.99
500.00
518.93
1.04
500.00
282.14
0.56
100.00
122.99
1.23
500.00
523.04
1.05
100.00
69.97
0.70
500.00
552.29
1.10
100.00
112.61
1.13
500.00
581.04
1.16
100.00
223.55
2.24
500.00
495.42
0.99
500.00
618.06
1.24
100.00
149.99
1.50
500.00
629.15
1.26
100.00
156.09
1.56
500.00
676.95
1.35
10
-------
06-OCT-199B 11:38:24 AM
Mass Spec : ULTIMA
GC Column : DB-5
265-04A --> 265-04E; Multiplier 3 260V.
d12-Benzo(a)anthracene
Benzo(a)anthracene
d12-Chrysene
Chrysene
dl 2-Benzo(b)fIuoranthene
Benzo(b)fluoranthene
d12-Benzo(k)fluoranthene
Benzo(k)fIuoranthene
d12-Benzo(a)pyrene
Benzo(e)pyrene
Benzo(a)pyrene
d12-Perylene
Perylene
d12-lndeno(123-cd)pyrene
lndeno(123-cd)pyrene
d14-Dibenz(ah)anthracene
Dioxin Furan CALIBRATION TABLE
file name : PAHA1R100198U.RRF
Date analyzed : 01-OCT-98
INITIAL CALIBRATION CURVE
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Mean
0.81
1.28
1.17
1.16
0.48
1.30
0.99
1.20
0.74
1.62
1.11
0.65
1.74
0.37
0.60
0.20
S.D.
0.051
0.069
0.075
0.057
0.026
0.085
0.022
0.061
0.023
0.085
0.084
0.029
0.145
0.040
0.031
0.031
XRSD
6.243
5.356
6.438
4.881
5.475
6.540
2.196
5.111
3.065
5.216
7.550
4.558
8.315
10.705
5.150
15.283
1
100.00
81.86
0.82
10.00
12.57
1.26
100.00
115.99
1.16
10.00
11.72
1.17
100.00
48.56
0.49
10.00
13.55
1.35
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96.32
0.96
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12.67
1.27
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71.22
0.71
10.00
17.26
1.73
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12.23
1.22
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60.50
0.60
10.00
18.19
1.82
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37.05
0.37
10.00
5.81
0.58
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19.47
0.19
2
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73.87
0.74
50.00
65.11
1.30
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107.11
1.07
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62.55
1.25
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46.43
0.46
50.00
66.19
1.32
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96.76
0.97
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63.60
1.27
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75.03
0.75
50.00
82.73
1.65
50.00
58.74
1.17
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67.68
0.68
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93.11
1.86
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32.97
0.33
50.00
32.63
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17.67
0.18
3
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80.14
0.80
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117.72
1.18
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112.39
1.12
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112.19
1.12
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46.37
0.46
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117.89
1.18
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98.32
0.98
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115.65
1.16
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71.96
0.72
100.00
150.84
1.51
100.00
104.99
1.05
100.00
66.13
0.66
100.00
154.60
1.55
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34.97
0.35
100.00
58.18
0.58
100.00
18.57
0.19
4
100.00
82.24
0.82
200.00
260.77
1.30
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122.50
1.23
200.00
221.26
1.11
100.00
46.62
0.47
200.00
249.84
1.25
100.00
100.62
1.01
200.00
233.26
1.17
100.00
74.50
0.74
200.00
313.45
1.57
200.00
205.81
1.03
100.00
66.18
0.66
200.00
326.69
1.63
100.00
37.60
0.38
200.00
117.22
0.59
100.00
20.38
0.20
5
100.00
88.02
0.88
500.00
680.79
1.36
1GC.OO
125.72
1.26
500.00
575.40
1.15
100.00
52.52
0.53
500.00
695.00
1.39
100.00
101.05
1.01
500.00
575.34
1.15
100.00
76.72
0.77
500.00
826.10
1.65
500.00
539.70
1.08
100.00
62.72
0.63
500.00
929.14
1.86
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43.56
0.44
500.00
308.65
0.62
100.00
25.60
0.26
10
-------
06-OCT-1998 11:38:26 AH
Dioxin Furan CALIBRATION TABLE
f -
Mass Spec : ULTIMA
GC Column : DB-5
265-04A --> 265-04E; Multiplier
Dibenz(ah)anthracene
d12-Benzo(ghi)perylene
Benzo(ghi)perylene
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
260V.
Mean
File name : PAHAIR100198U.RRF
Date analyzed : 01-OCT-98
INITIAL CALIBRATION CURVE
I
28
41
11
S.
0
0
0
D.
.051
.035
.030
XRSD
3.957
8.601
2.671
1
10
12
1
100
45
0
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10
1
.00
.64
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.17
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.73
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2
50
60
1
100
37
0
50
56
1
.00
.24
.20
.00
.67
.38
.00
.16
.12
3
100.00
129.39
1.29
100.00
38.08
0.38
100.00
107.43
1.07
4
200.00
268.11
1.34
100.00
39.49
0.39
200.00
227.28
1.14
5
500.00
651.39
1.30
100.00
44.20
0.44
500.00
559.79
1.12
10
-------
c.O
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File:050C98U #1-508 Acq: 6-OCT-1998 07:45:49 GC E1+ Voltage SIR Autospec-Ultima
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File:05OC98U #1-585 Acq: 6-OCT-1998 07:45:49 GC EI+ Voltage SIR Autospec-Ultima
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File:05OC98U #1-585 Acq: 6-OCT-1998 07:45:49 GC EI+ Voltage SIR Autospec-Ultima
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File:050C98U #1-1052 Acq: 6-OCT-1998 07:45:49 GC EI+ Voltage SIR Autospec-Ultima
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-------
File:05OC98U #1-915 Acq: 6-OCT-1998 07:45:49 GC EI+ Voltage SIR Autospec-Ultima
Sampled9 Text:ST1005A :CS-3 .-265-04C : ExprPAHAIR
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p A3.52E7
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A2.15E7
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974 S:19 F:4 SMO(1,3) PKD(S,3,3,Q.W%,mOQ.O,OM%,F,T)
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2.1E6
:1.7E6
:1.3E6
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_2.0E6
Ll.6E6
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-4.1E5
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0 Time
-------
File:05OC98U #1-915 Acq: 6-OCT-1998 07:45:49 GC EI+ Voltage SIR Autospec-Ultima
Sample#19 Text:ST1005A :CS-3 :265-04C : Exp:PAHAIR
276.0939 S:19 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 % A2.33E7
90-
80
70 4
60
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36:00 36:06 36:12 36:18 36:24 36:30 36:36 36:42 36:48 36:54 37:00 37:66 37:12 37:18
278.1096 S:19 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 % A2.15E7
90
80
70
60
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r3.2E6
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9.7E5
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1.3E6
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Time
-------
PJ
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-------
File:05OC98U if 1-508 Acq: 6-OCT-1998 08:32:12 GC EI+ Voltage SIR Autospec-Ultima
Sample«0 Text:SB1005B .-Solvent Blank :C Exp.-PAHAIR
128.0626 S:20 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100% A5.15E4
80
60-
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—i 1 -i 1 i 1 1 1 -j 1 i—
8:00 9:00
134.0827 S:20 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
10:t
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136.1128 S:20 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
-i 1 T 1 1 1 1 1 J r
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142.0782 S:20 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
n-oT
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12
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8:0*0
152.1410 S.-20 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
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Time
-------
12:37
12:55
File:05OC98U #1-508 Acq: 6-OCT-I998 08:32:12 GC EI+ Voltage SIR Aulospec-Ultima
Samplel20 Text:SBI005B :Solvent Blank :C Exp:PAHAlR
152.0626 S:20 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
80
60
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160.1128 S:20 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
14:48
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154.0782 5:20 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 % A1.15E5
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File:05OC98U #1-585 Acq: 6-OCT-1998 08:32:12 GC EI+ Voltage SIR Autospec-Uttima
Samplel20Text:SB1005B :Solvent Blank :C Exp:PAHAIR
166.0798 S:20 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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1 1 r—i 1 1—I 1 r—r
15:24 15:36
15:48
-------
File:05OC98U #1-585 Acq: 6-OCT-I998 08:32:12 GC EI+ Voltage SIR Autospec-Ultima
Sampled Text:SB1005B :Solvent Blank :C Exp:PAHAIR
178.0782 S:20 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0I0.00%,F,T)
)0 Time
188.1410 S:20 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
19:32 19:42 i9:52
18:00
18
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-------
A9.38E5
A6.31E5 A4.77E5
File:05OC98U #1-585 Acq: 6-OCT-1998 08:32:12 GC EI+ Voltage SIR Autospec-Ultima
Samplef20 Text:SB1005B :Solvent Blank :C Exp-.PAHAlR
204.9888 5:20 F:2 SMO(1,3) PKD(S,3,3,0.10%,10000.0,0.00%,F,T)
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File:05OC98U #1-1052 Acq: 6-OCT-1998 08:32:12 GC EI+ Voltage SIR Autospec-Ultima
Sample#20 Text:SB1005B :Solvent Blank :C Exp:PAHAlR
202.07828:20 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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-------
File:05OC98U 11-1052 Acq: 6-OCT-1998 08:32:12 GC EI+ Voltage SIR Autospec-Uitima
Sample*20 Text:SB1005B -.Solvent Blank :C Exp:PAHAlR
228.0939 S:20 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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-------
File:05OC98U #1-1052 Acq: 6-OCT-1998 08:32:12 GC EI+ Voltage SIR Autospec-UKima
Sample#20 Text:SB1005B :Solvent Blank :C Exp:PAHAlR
230.9856
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Time
-------
-------
LQ
File:05OC98U #1-915 Acq: 6-OCT-1998 08:32:12 GC EI+ Voltage SIR Aulospec-Ultima
Samplel20 Text:SB1005B :Solvent Blank :C Exp:PAHAIR
276.0939 S:20 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
36:6o37:00
288.1692 S:20 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
37:49
)0 Time
37:60
278.1096 S:20 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
36:51
36:00 37:1)0
292.19748:20 F:4SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
0 Time
7=23 37:50 38:06
36:6fl
O.OEO
41:00 Time
-------
u;
File:05OC98U 11-915 Acq: 6-OCT-1998 08:32:12 GC EI+ Voltage SLR Autospec-Ultima
Samplel20 Text:SB1005B :Solvent Blank :C Exp:PAHAIR
268.9824 S:20 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100% A1.45E6 A9.41E5... A2.0JE6 A1.31E6 AI.84E6 A9.41E5 A9.45E5 ^ ^^^^^-^w^F
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Time
-------
GUANTERRA INCORPORATED
VwttSi '
Analyzed 3y £/ Ct
Reviewed 3y n e{r^ t
S-4 £•
iu
r*<_
• Prepared By A -£
Date Analyzed
Date Reviewed
O /i '
X^cvyu?^
SY^ArS?
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f i-l-V
Prepared Dati
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Standard. CPSM, and solvent blank present?
Copy of Instrument logfile oresent?
CPSM blow UP and peak crofiie oresent?
Curve summarv present?
Summarv of 1 51 3A criteria present?
Daily standard within method specified limits*?
Daily ion abundance ratios within limits?
CPSM valley < 25%?
CPSM window correct?
Samples analyzed within 12 hrs of daily standard?
•1 ^;il^!^~^-t3sfStJ^^*
S fa
^
M |^ (\)/
-------
24-AUG-1998 01:02:52 PM
PAH ConCal RESULTS
Mass Spec : ULTIMA Results : 20AU98U031A.RES : PAHXCAL3.TRG
GC Column : DB-5 Date analyzed : 20-AUG-98
Data file : 20AU98U ST0820B :PAH CS-3 :265-4C Ex
Weight : 1 Total Isotope R. T. RRF ng
Name
dlO-2-Methylnaphthalene
d8 -Naphthalene
Naphthalene
2 -Methylnaphthalene
d8 - Acenaphthylene
Acenaphthylene
dlO -Acenaphthene
Acenaphthene
dlO- Anthracene
dlO-Fluorene
Fluorene
dlO-Phenanthrene
Phenanthrene
Anthracene
d!2-Benzo (e) pyrene
dl 0 - Fluoranthene
Fluoranthene
dlO- Pyrene
Pyrene
d!2-Benzo (a) anthracene
Benzo (a) anthracene
d!2-Chrysene
Chrysene
d!2 -Benzo (e) pyrene
d!2 -Benzo (b) fluoranthene
Benzo (b) fluoranthene
d!2 -Benzo (k) fluoranthene
Benzo (k) fluoranthene
d!2 -Benzo (a) pyrene
Benzo (e) pyrene
Benzo (a) pyrene
d!2-Perylene
Perylene
d!2 - Indeno ( 123 -cd) pyrene
Indeno (123-cd) pyrene
dl4-Dibenz (ah) anthracene
Dibenz (ah) anthracene
d!2 -Benzo (ghi) perylene
Benzo (ghi) perylene
d8 -Naphthalene
13C-Naphthalene
Response Ratio
178181200
304808000
310530000
176051400
229314000
188234200
138806400
124705000
106282600
125946600
170098800
271414000
208010000
205610000
354976000
277606000
251926000
257016000
273526000
193234800
194037400
275306000
243904000
354976000
205540000
220732000
315650000
316406000
250392000
357770000
230158000
213958000
325562000
255206000
131800000
156165400
164497000
251268000
217510000
314000000
316000000
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
mm: ss
11:
8:
9:
11:
14:
14:
14:
14:
19:
16:
16:
19:
19:
19:
32:
23:
23:
24:
24:
28:
28:
28:
28:
32:
31:
31:
31:
31:
32:
32:
32:
33 :
33:
37:
38:
38:
38:
39:
39:
16:
16:
9
58
2
15
13
15
46
52
47
28
34
37
42
51
37
31
35
14
17
5
10
12
17
37
38
44
44
48
50
43
55
8
15
58
6
0
10
23
32
28
33
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
0.
1.
1.
0.
1.
0.
0.
0.
0.
1.
1.
2.
0.
0.
0.
0.
0.
0.
1.
0.
1.
0.
0.
0.
0,
1.
0
1
0
1
0
0
1
0
0
0
1
0
0
-1
1
00
71
02
58
29
82
78
90
00
19
35
55
77
76
00
78
91
72
06
54
00
,78
,89
.00
.58
.07
.89
.00
.71
.43
.92
.60
.52
.72
.52
.44
.05
.71
.87
.00
.01
100.
100.
100.
100.
100.
100.
100.
100.
100.
100.
100.
100.
100.
100.
100.
100.
100.
100,
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
%
oev
00
00
00
00
00
00
00
00
00
00
00
00
00
,00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.oob
.00
.00
.00
37
-3
-25
-17
-5
-11
-3
5
29
-3
-9
-9
-3
-13
-11
-4
-16
-5
-9
-9
-8
0
-1
-13
-6
-2
-10
-2
-6
2
-16
0
-5
5412
-13
0
-------
24-AUG-1998 01:02:52 PM PAH ConCal RESULTS
dlO-Fluorene 136600000 1.00 Y 16: 29 Y -1.00 100.00
13C-Fluorene 116000000 1.00 Y 16: 34 Y 0.85 100.00
-------
FILE
SAMP
No.
(1)
LAB.
SAMP No
CUSTOMER
ID
CLEAN
UP 1
(SDS)
CLEAN
UP 2
(D2)
TYPE CONCn.
(1)
20AU98U
20AU98U
20AU98U
20AU98U
20AU98U
20AU98U
20AU98U
20AU98U
20AU98U
20AU98U
20AU98U
20AU98U
20AU98U
20AU98U
20AU98U
2CAUSSU
20AU98U
20AU98U
20AU98U
20AU98U
20AU98U
20AU98U
20AU9SU
20AU98U
20AU98U
20AU98U
20AU98U
20AU98U
20AU98U
20AU98U
20AU98U
20AU98U
20AU98U
20AU98U
20AU9SU
20AU98U
20AU58U
2CAU98U
20AU98U
20AU98U
20AU98U
20AU98U
20AU9SU
20AU98U
20AU9SU
20AU98U
20AU98U
20AUS3U
20ATJS8U
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
'25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
ST0820
ST0820A
ST0820B
SB0820
300681-1MF
300681-1LF
300681-1MS
300681-1LS
300569-6
300569-7
300569-8
300569-9
300664-1
300664-2
300631-1DL
300581-2DL
300581-3
SB0820A
QC0820
SB0820B
PAH CS-3
Prespike Cal Std
PAH CS-3
Solvent Blank
Method Blank
LCS
Method Blank
LCS
ARF-001-10
ARR-001-01
ARR-001-02
ARR-001-03
ARK-001-01
ARH-001-02
S-MM5-2-F 10x
S-MM5-1B-F lOx
T-MM5-2-F
Solvent Blank
081998PAHQC
Solvent Blank
651-21
AMA 08/20/98
265-4C
C8
Train
Train
Train
Train
Soil
Soil
Soil
Soil
Soil
Soil
Train
Train
Train
ca
Native
C8
PAH
PAH
PAH
PAH
PAH
PAH
PAH
PAH
PAH
PAH
PAH
PAH
PAH
PAH
VSE-23
VSE-23
VSS-23
1
1
1
1
0.333
0.333
0.333
0.333
5.05
5.02
5.03
4.99
5
5
,02
03
0.333
0.333
0.333
1
1
1
-------
Volts
2.0320
Peak Locate Examination:20-AUG-1998:15:19 File:20AU98U
Experiment:PAHAIR Function:! Reference:PFK
Volts
118.98012 118.99202 119.00392
Volts
0.2458
149.97542 149.99042 150.00542
Volt::
0.069'.
154.97652
168.97192 168.98882 169.0057
-------
Peak Locate Examination: 20-AUG-1998:15 -.19 File-. 20AU98U
Experiment: PAHAIR Function.- 2 Reference: PFK
___ volifsl PPM
1.4122 200
Volts
0.2432
192.96952 192.98882 193.00811
168.97192 168.98882 169.00571
Volts
0.0929
204.96832 204.98882 _205_.,00931,
Volt!
4.3701
180.97072 180.98882 181.00691
-------
LO
Peak Locate Examination:20-AUG-1998:15:20 File:20AU98U
Experiment:PAHAIR Function:3 Reference:PFK
PPM
200
Volts
0.2319
192.96952 192.98882 193.00811
204.96832
Volts
0.0783
.
\
^C_
)82 205.00931
PPM
200
218.96
Volt;
0.56K'
218.98563 219.0075:
Volt:
0.162!'
254.90563 255.0111;.
-------
O
Peak Locate Examination:20-AUG-1998:15:20 File:20AU98U
Experiment:PAHAIR Function:4 Reference:PFK
PPM
200
292.95315 292.90245 293.01175
-------
20-AUG-199S 02:19:36 PM
Mass Spec : ULTIMA
GC Column : DB-5
265-04A,-04B, 651-21, 265-040,-04E; Multiplier a 260V.
da-Naphthalene
Naphthalene
2-Methylnaphthalene
d8-Acenaphthylene
Acenaphthylene
dIO-Acenaphthene
Acenaphthene
d10-Fluorene
Fluorene
dIO-Phenanthrene
Phenanthrene
Anthracene
dIO-Fluoranthene
Fluoranthene
d10-Pyrene
Pyrene
PAH CALIBRATION TABLE
File name : PAHAIR081998U.RRF
Date analyzed : 19-AUG-98
INITIAL CALIBRATION CURVE
CO
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Mean
1.25
1.05
0.77
1.55
0.86
0.88
0.93
1.13
1.05
2.63
0.84
0.83
1.01
1.04
1.01
1.11
S.D.
0.094
0.181
0.112
0.092
0.057
0.037
0.097
0.098
0.105
0.051
0.064
0.053
0.073
0.067
0.047
0.052
XRSD
7.579
17.228
14.514
5.934
6.560
4.178
10.478
8.636
10.040
1.934
7.599
6.428
7.268
6.394
4.667
4.714
1
100.00
125.13
1.25
10.00
13.58
1.36
10.00
9.29
0.93
100.00
168.75
1.69
10.00
8.55
0.86
100.00
86.37
0.86
10.00
10.16
1.02
100.00
129.53
1.30
10.00
11.18
1.12
100.00
262.09
2.62
10.00
9.04
0.90
10.00
8.68
0.87
100.00
95.14
0.95
10.00
10.95
1.09
100.00
98.59
0.99
10.00
11.51
1.15
2
100.00
138.22
1.38
50.00
54.09
1.08
50.00
33.88
0.68
100.00
145.20
1.45
50.00
44.41
0.89
100.00
89.70
0.90
50.00
47.71
0.95
100.00
105.98
1.06
50.00
43.83
0.88
100.00
260.96
2.61
50.00
42.04
0.84
50.00
40.93
0.82
100.00
113.27
1.13
50.00
51.53
1.03
100.00
109.02
1.09
50.00
55.06
1.10
3
100.00
111.61
1.12
100.00
96.37
0.96
100.00
84.95
0.85
100.00
148.35
1.48
100.00
94.74
0.95
100.00
82.92
0.83
100.00
101.30
1.01
100.00
113.84
1.14
100.00
114.84
1.15
100.00
265.51
2.66
100.00
90.20
0.90
100.00
88.77
0.89
100.00
96.06
0.96
100.00
111.98
1.12
100.00
97.52
0.98
100.00
117.00
1.17
4
100.00
124.70
1.25
200.00
186.59
0.93
200.00
139.99
0.70
100.00
158.01
1.58
200.00
162.62
0.81
100.00
92.67
0.93
200.00
157.44
0.79
100.00
108.38
1.08
200.00
210.00
1.05
100.00
269.74
2.70
200.00
150.57
0.75
200.00
149.97
0.75
100.00
99.58
1.00
200.00
199.62
1.00
100.00
102.26
1.02
200.00
212.11
1.06
5
100.00
123.18
1.23
500.00
464.77
0.93
500.00
349.03
0.70
100.00
154.72
1.55
500.00
406.40
0.81
100.00
87.02
0.87
500.00
439.22
0.88
100.00
107.00
1.07
500.00
528.30
1.06
100.00
256.17
2.56
500.00
405.42
0.81
500.00
410.83
0.82
100.00
99.18
0.99
500.00
479.64
0.96
100.00
98.62
0.99
500.00
527.05
1.05
10
-------
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-------
O-AUG-1998 02:19:39 PM
PAH CALIBRATION TABLE
ass Spec : ULTIMA
C Column : DB-5
65-04A.-04B, 651-21, 265-040, -04E; Multiplier a 260V.
i benz(ah)anthracene
12-Benzo(ght)perylene
enzo(ghi)perylene
3C-Naphthalene
3C-Fluorene
File name
Date analyzed
PAHAIR081998U.RRF
19-AUG-98
INITIAL CALIBRATION CURVE
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Mean
1.11
0.63
0.99
1.00
1.00
S.D.
0.036
0.060
0.034
0.000
0.000
XRSD
3.270
9.532
3.467
0.000
0.000
1
10.00
10.79
1.08
100.00
60.66
0.61
10.00
10.00
1.00
100.00
1.00
1.00
100.00
1.00
1.00
2
50.00
56.20
1.12
100.00
64.91
0.65
50.00
50.38
1.01
100.00
1.00
1.00
100.00
1.00
1.00
3
100.00
115.84
1.16
100.00
61.14
0.61
100.00
103.43
1.03
100.00
1.00
1.00
100.00
1.00
1.00
4
200.00
225.91
1.13
100.00
56.21
0.56
200.00
190.98
0.95
100.00
1.00
1.00
100.00
1.00
1.00
5
500.00
535.81
1.07
100.00
72.26
0.72
500.00
478.29
0.96
100.00
1.00
1.00
100.00
1.00
1.00
10
-------
20-AUG-1998 02:31:54 PM
Mass Spec : ULTIMA
GC Column : DB-5
265-04A.-04B. 651-21, 265-040,-04E; Multiplier 8 260V.
da-Naphthalene
Naphthalene
2-Methylnaphthalene
dS-Acenaphthylene
Acenaphthylene
d10-Acenaphthene
Acenaphthene
d10-Fluorene
Fluorene
dIO-Phenanthrene
Phenanthrene
Anthracene
d10-Fluoranthene
Fluoranthene
dlO-Pyrene
Pyrene
PAH CALIBRATION TABLE
File name
Date analyzed
PAHX081998U.RRF
19-AUG-98
INITIAL CALIBRATION CURVE
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Mean
1.25
1.05
0.77
1.55
0.86
0.88
0.93
1.13
1.05
2.63
0.84
0.83
0.80
1.04
0.81
1.11
S.D.
0.094
0.181
0.112
0.092
0.057
0.037
0.097
0.098
0.105
0.051
0.064
0.053
0.059
0.067
0.074
0.052
XRSD
7.579
17.228
14.514
5.934
6.560
4.178
10.478
8.636
10.040
1.934
7.599
6.428
7.315
6.394
9.179
4.714
1
100.00
125.13
1.25
10.00
13.58
1.36
10.00
9.29
0.93
100.00
168.75
1.69
10.00
8.55
0.86
100.00
86.37
0.86
10.00
10.16
1.02
100.00
129.53
1.30
10.00
11.18
1.12
100.00
262.09
2.62
10.00
9.04
0.90
10.00
8.68
0.87
100.00
80.50
0.81
10.00
10.95
1.09
100.00
83.42
0.83
10.00
11.51
1.15
2
100.00
138.22
1.38
50.00
54.09
1.08
50.00
33.88
0.68
100.00
145.20
1.45
50.00
44.41
0.89
100.00
89.70
0.90
50.00
47.71
0.95
100.00
105.98
1.06
50.00
43.83
0.88
100.00
260.96
2.61
50.00
42.04
0.84
50.00
40.93
0.82
100.00
73.52
0.74
50.00
51.53
1.03
100.00
70.76
0.71
50.00
55.06
1.10
3
100.00
111.61
1.12
100.00
96.37
0.96
100.00
84.95
0.85
100.00
148.35
1.48
100.00
94.74
0.95
100.00
82.92
0.83
100.00
101.30
1.01
100.00
113.84
1.14
100.00
114.84
1.15
100.00
265.51
2.66
100.00
90.20
0.90
100.00
88.77
0.89
100.00
89.68
0.90
100.00
111.98
1.12
100.00
91.04
0.91
100.00
117.00
1.17
4
100.00
124.70
1.25
200.00
186.59
0.93
200.00
139.99
0.70
100.00
158.01
1.58
200.00
162.62
0.81
100.00
92.67
0.93
200.00
157.44
0.79
100.00
108.38
1.08
200.00
210.00
1.05
100.00
269.74
2.70
200.00
150.57
0.75
200.00
149.97
0.75
100.00
79.47
0.79
200.00
199.62
1.00
100.00
81.61
0.82
200.00
212.11
1.06
5
100.00
123.18
1.23
50" 00
464.77
0.93
500.00
349.03
C.70
100.00
154.72
1.55
500.00
406.40
0.81
100.00
87.02
0.87
500.00
439.22
0.88
100.00
107.00
1.07
500.00
528.30
1.06
100.00
256.17
2.56
500.00
405.42
0.81
500.00
410.83
0.82
100.00
78.46
0.78
500.00
479.64
0.96
100.00
78.02
0.78
500.00
527.05
1.05
10
-------
20-AUG-1998 02:31:55 PM
Mass Spec : ULTIMA
GC Column : OB-5
265-04A.-04B, 651-21, 265-040,-04E; Multiplier 9 260V.
d12-Benzo(a)anthracene
Benzo(a)anthrecene
d12-Chrysene
Chrysene
dl 2-Benzo(b)fluoranthene
Benzo(b)fluoranthene
d12-Benzo(k)fluoranthene
Benzo(k)fluoranthene
d1H-Benzo(a)pyrene
Benzo(e)pyrene
Benzo(a)pyrene
d12-Perylene
Perylene
d12-Indeno(123-cd)pyrene
lndeno(123-cd)pyrene
d14-Dibenz(ah)anthracene
PAH CALIBRATION TABLE
File name
Date analyzed
PAHXOB1998U.RRF
19-AUG-98
INITIAL CALIBRATION CURVE
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Mean
0.65
1.06
0.85
0.97
0.63
1.07
0.90
1.16
0.75
1.46
1.02
0.61
1.62
0.71
0.61
0.44
S.D.
0.052
0.030
0.062
0.086
0.036
0.029
0.048
0.105
0.010
0.077
0.066
0.013
0.110
0.061
0.046
0.045
XRSD
8.032
2.804
7.259
8.856
5.785
2.735
5.393
9.104
1.385
5.243
6.478
2.048
6.792
8.681
7.531
10.143
1
100.00
72.04
0.72
10.00
10.53
. 1.05
100.00
86.29
0.86
10.00
10.59
1.06
100.00
64.51
0.65
10.00
10.81
1.08
100.00
88.20
0.88
10.00
12.74
1.27
100.00
75.48
0.75
10.00
15.21
1.52
10.00
11.13
1.11
100.00
60.89
0.61
10.00
17.58
1.76
100.00
68.59
0.69
10.00
6.33
0.63
100.00
43.73
0.44
2
100.00
58.19
0.58
50.00
52.92
1.06
100.00
74.68
0.75
50.00
50.08
1.00
100.00
65.70
0.66
50.00
52.02
1.04
100.00
82.16
0.82
50.00
59.99
1.20
100.00
74.11
0.74
50.00
74.22
1.48
50.00
51.09
1.02
100.00
60.89
0.61
50.00
80.54
1.61
100.00
72.80
0.73
50.00
33.45
0.67
100.00
43.81
0.44
3
100.00
66.97
0.67
100.00
110.29
1.10
100.00
85.64
0.86
100.00
103.60
1.04
100.00
63.39
0.63
100.00
111.29
1.11
100.00
90.16
0.90
100.00
120.61
1.21
100.00
74.28
0.74
100.00
153.41
1.53
100.00
105.82
1.06
100.00
60.17
0.60
100.00
145.64
1.46
100.00
69.80
0.70
100.00
62.76
0.63
100.00
44.28
0.44
4
100.00
62.07
0.62
200.00
207.09
1.04
100.00
85.99
0.86
200.00
175.51
0.88
100.00
63.02
0.63
200.00
212.98
1.06
100.00
93.02
0.93
200.00
217.66
1.09
100.00
75.01
0.75
200.00
287.46
1.44
200.00
197.36
0.99
100.00
61.91
0.62
200.00
332.88
1.66
100.00
62.67
0.63
200.00
113.23
0.57
100.00
38.06
0.38
5
100.00
65.85
0.66
500.00
513.26
1.03
100.00
91.50
0.91
500.00
441.04
0.88
100.00
56.40
0.56
500.00
523.15
1.05
100.00
94.50
0.94
500.00
504.85
1.01
100.00
76.69
0.77
500.00
672.30
1.34
500.00
469.69
0.94
100.00
63.41
0.63
500.00
800.43
1.60
100.00
79.43
0.79
500.00
281.17
0.56
100.00
50.69
0.51
10
-------
20-AUG-1998 02:31:56 PH
PAH CALIBRATION TABLE
Mass Spec : ULTIMA
GC Column : DB-5
265-04A.-04B, 651-21, 265-040, -04E; Multiplier a 260V.
Dibenz(ah)anthracene
d12-Benzo(ghi)perylene
Benzo(ghi)perylene
13C-Fluorene
File name
Date analyzed
PAHX081998U.P"F
19-AUG-98
INITIAL CALIBRATION CURVE
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Mean
1.11
0.63
0.99
0.00
S.D.
0.036
0.060
0.034
0.000
XRSD
3.270
9.532
3.467
0.000
1
10.00
10.79
1.08
100.00
60.66
0.61
10.00
10.00
1.00
100
2
50.00
56.20
1.12
100.00
64.91
0.65
50.00
50.38
1.01
100
3
100.00
115.84
1.16
100.00
61.14
0.61
100.00
103.43
1.03
100
4
200.00
225.91
1.13
100.00
56.21
0.56
200.00
190.98
0.95
100
5
500.00
535.81
1.07
100.00
72.26
0.72
500.00
478.29
0.96
100.00
0.03
0.00
10
-------
Fiie:20AU98U #1-476 Acq:20-AUG-1998 16:54:06 GC EI+ Voltage SIR Autospec-UItima
Sampled Text:ST0820B :PAH CS-3 :265-4C Exp:PAHAIR
128.0626 S:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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File:20AU98U #1-476 Acq:20-AUG-1998 16:54:06 GC EI+ Voltage SIR Autospec-Ultima
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152.0626 5:3 SMO(1,3) PKD(5,3,3,0.10%(10000.0,0.00%,F(T)
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100%
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154.0782 S:3 SMO(1,3) PKD(5,3,3,O.IO%,10000.0,0.00%,F,T)
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-------
Ffle:20AU98U #1-476 Acq:20-AUG-1998 16:54:06 GC EI+ Voltage Sill Aiilospec-UItiiiia
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Ftle:20AU98U #1-666 Acq:20-AUG-1998 16:54:06 GC EI+ Voltage SIR Autospec-UHImn
Sampled Tcxt:ST0820B :PAH CS-3 :265-4C Exp:PAHAIR
166.0798 S:3 F:2 SMO(l,3) PKD(5,3,3,0.10%,IOOOO.O,0.00%,F,T)
100 % A8.50E7
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File:20AU98U #1-666 Acq:20-AUG-1998 16:54:06 GC E1+ Voltage SIR Autospec-Ultiina
Sample*) Text:ST0820B .'PAH CS-3 :265-4C Exp:PAHAIR
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File:20AU98U if 1-934 Acq:20-AUC-1998 16:54:06 GO EI+ Voltage SIR Autospec-Ullima
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Flle:20AU98U #1-934 Acq:20-AUG-1998 16:54:06 GC E1 + Voltage SIR Aulospec-Ultiuia
Sampled Text:ST0820B :PAH CS-3 :265-4C Exp:PAHAIR
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FHe:20AU98U #1-954 Acq:20-AUG-1998 16:54:06 GC EI+ Voltage SIR Autospec-UUIma
Sampled Text:ST0820B :PA11 CS-3 :26S-4C Exp:PAHAIR
252.09398:3 F:4SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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90
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264.1692 S:3 F:4 SMO(1,3) PKD(5>3,3,0.10%,10000.0,0.00%,F,T)
100%
90
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-------
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File:20AU98U #1-954 Acq:20-AUG-1998 16:54:06 GC EI+ Voltage SIR Autospec-Ultima
Sampled Text:ST0820B :PAH CS-3 :265-4C Exp:PAHAIR
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278.1096 S:3 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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-------
File:20AU98U 11-954 Acq:20-AUG-1998 16:54:06 GC El f Voltage SIR Autospec-Ulliiua
Sampled Text:ST0820B :PAH CS-3 :265-4C Exp:PAHAlK
268.9824 S:3 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 ^KX^^T-V A1.22E7 A1.29E7 A6 06E6 A1.6.7E7
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-------
Flle:20AU98U #1-954 Acq:20-AUG-1998 16:54:06 GC EI+ Voltage SIR Autospec-Ultiina
Sampled Text:ST0820B :PAH CS-3 :265-4C Exp:PAHAlR
276.0939 S:3 F:4SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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Time
-------
File:20AU98U #1-476 Acq:20-AUG-1998 16:07:37 GC EI+ Voltage SIR Autospec-Ullima
Sampled Text:ST0820A :Prespike Cal Sid Exp:PAHAIR
128.0626 S:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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File:20AU98U #1-665 Acq:20-AUG-1998 16:07:37 GC EI+ Voltage SIR Autospec-UItima
Sampled Text:ST0820A :Prespike Cat Sid Exp:PAMAIR
166.0798 S:2 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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100 % A6.8^E7
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Time
-------
F!le:20AU98U #1-665 Acq:20-AUG-1998 16:07:37 GC E1+ Voltage SIR
Sample*! Text:ST0820A :Prespike Cat Std Exp:PAHAIR
204.9888 S:2 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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0 Time
-------
File:20AU98U #1-477 Acq:20-AUG-l998 17:40:37 GC EI+ Voltage SIR Autospec-Ultima
Sampled Text:SB0820 .-Solvent Blank :C8 Exp:PAHAIR
128.0626 S:4SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 Sj. A6.5.7E5
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134.0827 S:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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136.1128 S:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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-------
File:20AU98U #1-477 Acq:20-AUG-l998 17:40:37 GC EI+ Voltage SIR Autospec-Ullima
Sampled Text:SB0820 :Solvent Blank :C8 ExprPAHAIR
152.0626 S:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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File:20AU98U #1-665 Acq:20-AUG-1998 17:40:37 GC E1+ Voltage SIR Autospec-Ultiiua
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166.0798 S:4 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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172.0984 S:4 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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Flle:20AU98U #1-665 Acq:20-AUG-1998 17:40:37 GC E1+ Voltage SIR Autospec-Ultiina
Sampled Text:SB0820 .-Solvent Blank :C8 Exp.-PAHAIR
178.0782 S:4 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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-------
File:20AU98U #1-665 Acq:20-AUG-1998 17:40:37 GC E1 + Voltage SIR AuIospec-UHiuia
Sampled Text:SB0820 :Solvent Blank :C8 Exp:PAHAIR
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File:20AU98U #1-934 Acq:20-AUG-1998 17:40:37 GC EI+ Voltage SIR Autospec-Ultima
Sampled Text:SB0820 .'Solvent Blank :C8 Exp:PAHAlR
202.0782 S:4 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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F!le:20AU98U #1-934 Acq:20-AUG-1998 17:40:37 GC E1+ Voltage SIR Autospec-Ultiina
Sampled Text:SB0820 :Solvent Blank :C8 Exp: PAH AIR
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0 Time
-------
(.vl
File:20AU98U #1-934 Acq:20-AUG-1998 17:40:37 GC E1+ Voltage SIR Autospec-Ultima
Sampled Text:SB0820 :Solvent Blank :C8 Exp:PAHAIR
230.9856 S:4 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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-------
File:20AU98U #1-955 Acq:20-AUG-1998 17:40:37 GC E1+ Voltage SIR Autospec-Uitinia
Sampled Text:SB0820 :Solvent Blank :C8 Exp.-PAHAIR
252.0939 S:4 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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-------
File:20AU98U if 1-955 Acq:20-AUG-1998 17:40:37 CC EI+ Voltage SIR Autospec-Ultima
Sampled Text:SB0820 :Solvent Blank :C8 Exp:PAHA]R
276.0939 S:4 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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-------
File:20AU98U #1-955 Acq:20-AUG-1998 17:40:37 GC EI+ Voltage SIR Autospec-Ultima
Sampled Text:SB0820 :Solvent Blank :C8 ExptPAHAIR
268.9824 S:4 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
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-------
QUANTEHRA INCORPORATED
West Sacramento
Daily Standard Checklist
Dfoxin/Furan High Res
STD ID & TO S24/Wo£7ufl Method ID Pfl \\ /
7
Standard Solution 1 fet> -
Analyred By &
—
_Prepared By_
Q .
oi^.
J ¥
Date Analyzed
Reviewed 3y
Date Reviewed
Co/umn ID
Inatr ID
Prepared Data
«KKyS.i.£i;
Standard, CPSM. and solvent blank oresent?
CODY of Instrument loafile oresent?
CPSM blow LID and Desk orofile oresent?
Curve summary present?
Summary of 1613A criteria present?
aily standard within method specified limits*?
Daily ion abundance ratios within limits?
CPSM valley < 25%?
CPSM window correct?
Samples analyzed within 12 hrs of dally standard?
©
COMMENTS:
_Q^o PAH
©
(H
For NCABl 5=1, Control Limit (CD « -f/- 20% from curve RRFs for all anaiytes.
For Method 8290, CL = •*•/- 20% from curve RRFs for native ana.'vtss. CL = •*•/- 30% from curve 3RH5 fpr
cr 'v
-------
25-AUG-1998 09:15:29 AM
PAH ConCal RESULTS
Mass Spec : ULTIMA
GC Column : DB-5
Data file : 24AU98U
Weight : 1
Name
dlO-2-MethyInaphthalene
d8-Naphthalene
Naphthalene
2-Methylnaphthalene
d8-Acenaphthylene
Acenaphthylene
dlO-Acenaphthene
Acenaphthene
dl0-Anthracene
dlO-Fluorene
Fluorene
dl0 -Phenanthrene
Phenanthrene
Anthracene
d!2-Benzo(e)pyrene
dlO-Fluoranthene
Fluoranthene
dlO-Pyrene
Pyrene
d!2-Benzo(a)anthracene
Benzo(a)anthracene
d!2-Chrysene
Chrysene
d!2-Benzo(e)pyrene
dl2-Benzo(b)fluoranthene
Benzo(b)fluoranthene
d!2-Benzo(k)fluoranthene
Benzo(k)fluoranthene
d!2-Benzo(a)pyrene
Benzo(e)pyrene
Benzo(a)pyrene
d!2-Perylene
Perylene
d!2-Indeno(123-cd)pyrene
Indeno(123-cd)pyrene
d!4-Dibenz(ah)anthracene
Dibenz(ah)anthracene
dl2-Benzo(ghi)perylene
Benzo(ghi)perylene
d8-Naphthalene
13C-Naphthalene
Results : 24AU98U011A.RES
Date analyzed
ST0824 :PAH CS-3 :265-4C Ex
Total Isotope R. T. RRF
Response Ratio mm:ss
PAHXCAL3.TRG
24-AUG-98
ng
Dev
193339600 1.00 Y
232554000 1.00 Y
211426000 1.00 Y
155842800 1.00 Y
241682000 1.00 Y
203188000 1.00 Y
163963200 1.00 Y
140967400 1.00 Y
101388600 1.00 Y
119416200 1.00 Y
118973000 1.00 Y
273562000 1.00 Y
211432000 1.00 Y
195559400 1.00 Y
226910000 1.00 Y
237798000 1.00 Y
201012000 1.00 Y
210234000 1.00 Y
203282000 1.00 Y
179273000 1.00 Y
171483800 1.00 Y
250420000 1.00 Y
212988000 1.00 Y
226910000 1.00 Y
124938800 1.00 Y
127032600 1.00 Y
190276400 1.00 Y
176402800 1.00 Y
154846400 1.00 Y
206110000 1.00 Y
133261000 1.00 Y
127401600 1.00 Y
179952000 1.00 Y
173996000 1.00 Y
95200000 1.00 Y
107370000 1.00 Y
100283200 1.00 Y
190623000 1.00 Y
169400200 1.00 Y
191800000 1.00 Y
188800000 1.00 Y
11: 10 Y
8: 58 Y
9: 2 Y
11: 15 Y
14: 13 Y
14: 16 Y
14: 47 Y
14: 53 Y
19: 47 Y
16: 29 Y
16: 35 Y
19: 38 Y
19 : 42 Y
19: 51 Y
32: 39 Y
23: 32 Y
23 : 35 Y
24: 15 Y
24: 18 Y
28: 7 Y
28: 11 Y
28: 13 Y
28: 18 Y
32: 39 Y
31: 40 Y
31: 45 Y
31: 45 Y
31: 50 Y
32 : 52 Y
32: 45 Y
32: 57 Y
33: 11 Y
33: 17 Y
38: 1 Y
38: 9 Y
38: 2 Y
38: 13 Y
39: 25 Y
39: 35 Y
8: 58 Y
9: 2 Y
1.00
1.20
0.91
0.67
1.25
0.84
0.85
0.86
0.00
1.18
1.00
2.70
0 .77
0.71
2.00
1.05
0.85
0.93
0.97
0.79
0.96
1.10
0.85
2 .00
0.55
1.02
0.84
0.93
0.68
1.33
0.86
0.56
1.41
0.77
0.55
0.47
0.93
0.84
0.89
0.00
0.98
100.00
100.00
100.00
100.00
100.00
100.00
100.00
100.00
100.00
100.00
100.00
100.00
100.00
100.00
100.00
100.00
100.00
100.00
100.00
100.00
100.00
100.00
100.00
100.00
100.00
100.00
100.00
100.00
100.00
100.00
100.00
100.00
100.00
100.00
100.00
100.00
100.00
100 ..00
100.00
100.00
100.00
-3
-14
-13
-19
-3
-3
-8
4
-5
3
-8
-14
30
-19
14
-13
22
_c
3C
-i:
-i:
-J
_(
-21
_ i
-!
-1'
_
-1
-1
-1
3
b£l
-------
25-AUG-1998 09:15:29 AM PAH ConCal RESULTS
dlO-Fluorene $2400000 1.00 Y 16: 29 Y 0.00 100.00
13C-Fluorene 70000000 1.00 Y 16: 34 Y 0.76 100.00
-------
C0m<:?20 J
FILE
SAMP
No.
(1)
LAB.
SAMP No
CUSTOMER
ID
CLEAN CLEAN
UP 1 UP 2
(SDS) (D2)
TYPE CONCn.
(1)
24AU98U
24AU98U
24AU98U
24AU98U
24AU98U
24AU98U
24AU98U
24AU98U
24AU98U
24AU98U
24AU98U
24AU98U
24AU98U
24AU98U
24AU98U
24AU98U
24AU98U
24AU98U
24AU98U
24AU98U
24AU98U
24AU98U
24AU98U
24AU98U
24AU98U
24AU98U
24AU98U
24AU98U
24AU98U
24AU98U
24AU98U
24AU98U
24AU98U
24AU98U
24AU98U
24AU98U
24AU98U
24AU98U
24AU98U
24AU98U
24AU98U
24AU98U
24AU98U
24AU98U
24AU98U
24AU98U
24AU98U
24AU98U
24AU98U
24AU98U
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
ST0824 PAH CS-3
ST0824A Prespike Cal Std
SB0824
300413-1BX
300413-1LX
300753-1MB
300753-1LC
300681-4
300681-5
300681-6
300681-7
300681-8
300681-9
300681-10
300681-11
300413-1RX
300753-1
SB0824A
QC0824
Solvent Blank
Method Blank
LCS
Method Blank
LCS
T-MM5-FB-F
T-MM5-4-F
T-MM5-3-F
T-MM5-3-F
T-MM5-FB-F
T-MM5-RB-F
T-MM5-4-F
T-MM5-5-F
BAK-101
ARJ-001-01
Solvent Blank
QC081998
AMA 08/24/98
265-4C
C8
Soil
Soil
Soil
Soil
Train
Train
Train
Train
Train
Train
Train
Train
Soil
Soil
C8
DCM
PAH
PAH
PAH
PAH
PAH
PAH
PAH
PAH
PAH
PAH
PAH
PAH
PAH
PAH
PAH
VSE-23
VSE-23
VSE-23
1
1
1
5.0
5.0
5.0
5.0
0.333
0.333
0.333
0.333
0.333
0.333
0.333
0.333
4.96
5.0
1
1
-------
o;
Peak Locate Examination:24-AUG-1998 :17 :34 File-.24AU98U
Experiment:PAHAIR Function:! Reference:PFK
Voltr,
0.075?'
Volts
3.5202
Volts
1.9690
142.99202
143.00632,
142.97772
130.99202
131.00512
118.99202
119.00392
130.97892
118.98012
Voltiji
1.7107.'
Volts
0.0434
Volts
0.2297
149.97542 149.99042 150.00542
154.97652 154.99202 155.00752
168.97192 168.98882 169.0057:'
-------
Peak Locate Examination:24-AUG-1998:17:34 File:24AU98U
Experiment:PAHAIR Function:2 Reference:PFK
PPM
200
Volts
1.4780
168.97192 168.98882 169.00571
Volts
0.2711
192.96952 192.98882 193.00811
Volts
0.1095
2j) 4 .96832 204.98882 205.00931
PPM
200
180.97072 180.98882 181.0069!'
-------
O
Peak Locate Examination:24-AUG-1998:17:35 File:24AU98U
Experiment:PAHAIR Function:3 Reference:PFK
Volts
0.1925
192.96952 192.98882 193.00811
Volts
1.6410
230.96253 230.98563 231.00872
Volte
0.0828
204.96832 204.98882 205.00931
Volts
0.7671
242.96133 242.98563 243.00992
Volt;
0.623
218.96373 218.98563 219.0075
PPM
200
Volt:
0.192'/
254.96013 254.98563 255.0111:'
-------
Peak Locate Examination:24-AUG-1998:17:35 File:24AU98U
Experiment:PAHAIR Function:4 Reference:PFK
Volts
0.5551
242.96133 242.98563 243.00992
Volts
0.8921
280.95435 280.98245 281.01055
Volts
0.1444
254.96013 254.98563 255.01112
Volts
0.5000
292.95315 292.98245 293.01175
Volts'
0.238C>;
268.95555 268.98245 269.0093!
-------
20-AUO-1998 OZ:31:54 PM
Mass Spec : ULTIMA
GC Column : DB-5
265-04A.-04B, 651-21, 265-040,-04E; Multiplier 8 260V.
dS-Naphthalene
Naphthalene
2-Methylnaphthalene
d8-Acenaphthylene
Acenaphthylene
dIO-Acenaphthene
Acenaphthene
d10-Fluorene
Fluorene
dIO-Phenanthrene
Phenanthrene
Anthracene
d10-Fluoranthene
Fluoranthene
d10-Pyrene
Pyrene
PAH CALIBRATION TABLE
File name
Date analyzed
PAHX081998U.RRF
19-AUG-98
INITIAL CALIBRATION CURVE
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Mean
1.25
1.05
0.77
1.55
0.86
0.88
0.93
1.13
1.05
2.63
0.84
0.83
0.80
1.04
0.81
1.11
S.O.
0.094
0.181
0.112
0.092
0.057
0.037
0.097
0.098
0.105
0.051
0.064
0.053
0.059
0.067
0.074
0.052
XRSO
7.579
17.228
14.514
5.934
6.560
4.178
10.478
8.636
10.040
1.934
7.599
6.428
7.315
6.394
9.179
4.714
1
100.00
125.13
1.25
10.00
13.58
1.36
10.00
9.29
0.93
100.00
168.75
1.69
10.00
8.55
0.86
100.00
86.37
0.86
10.00
10.16
1.02
100.00
129.53
1.30
10.00
11.18
1.12
100.00
262.09
2.62
10.00
9.04
0.90
10.00
8.68
0.87
100.00
80.50
0.81
10.00
10.95
1.09
100.00
83.42
0.83
10.00
11.51
1.15
2
100.00
138.22
1.38
50.00
54.09
1.08
50.00
33.88
0.68
100.00
145.20
1.45
50.00
44.41
0.89
100.00
89.70
0.90
50.00
47.71
0.95
100.00
105.98
1.06
50.00
43.83
0.88
100.00
260.96
2.61
50.00
42.04
0.84
50.00
40.93
0.82
100.00
73.52
0.74
50.00
51.53
1.03
100.00
70.76
0.71
50.00
55.06
1.10
3
100.00
111.61
1.12
100.00
96.37
0.96
100.00
84.95
0.85
100.00
148.35
1.48
100.00
94.74
0.95
100.00
82.92
0.83
100.00
101.30
1.01
100.00
113.84
1.14
100.00
114.84
1.15
100.00
265.51
2.66
100.00
90.20
0.90
100.00
88.77
0.89
100.00
89.68
0.90
100.00
111.98
1.12
100.00
91.04
0.91
100.00
117.00
1.17
4
100.00
124.70
1.25
200.00
186.59
0.93
200.00
139.99
0.70
100.00
158.01
1.58
200.00
162.62
0.81
100.00
92.67
0.93
200.00
157.44
0.79
100.00
108.38
1.08
200.00
210.00
1.05
100.00
269.74
2.70
200.00
150.57
0.75
200.00
149.97
0.75
100.00
79.47
0.79
200.00
199.62
1.00
100.00
81.61
0.82
200.00
212.11
1.06
5
100.00
123.18
1.23
500.00
464.77
0.93
500.00
349.03
0.70
100.00
154.72
1.55
500.00
406.40
0.81
100. GO
87.02
0.87
500.00
439.22
O.SS
100.00
107.00
1.07
500.00
528.30
1.06
100.00
256.17
2.56
500.00
405.42
0.81
500.00
410.83
0.82
100.00
78.46
0.78
500.00
479.64
0.96
100.00
78.02
0.78
500.00
527.05
1.05
t,'.)
o
CO
10
-------
20-AUG-1998 02:31:55 PM
Mass Spec : ULTIMA
GC Column : OB-5
265-04A.-04B, 651-21, 265-040,-04E; Multiplier a 260V.
d12-Benzo(a)anthracene
Benzo(a)anthracene
d12-Chrysene
Chrysene
d12-Benzo(b)fluoranthene
Benzo(b)fIuoranthene
d12-Benzo(k)fluoranthene
Benzo(k)fIuoranthene
d12-Benzo(a)pyrene
3enzo(e)pyrene
3enzo(a)pyrene
d12-Perylene
Perylene
312-IndenoC123-cd)pyrene
lndeno(123-cd)pyrene
dU-Dibenz(ah)anthracene
PAH CALIBRATION TABLE
File name
Date analyzed
t.J
PAHX081998U.RRF
19-AUG-98
INITIAL CALIBRATION CURVE
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Mean
0.65
1.06
0.85
0.97
0.63
1.07
0.90
1.16
0.75
1.46
1.02
0.61
1.62
0.71
0.61
0.44
S.D.
0.052
0.030
0.062
0.086
0.036
0.029
0.048
0.105
0.010
0.077
0.066
0.013
0.110
0.061
0.046
0.045
XRSD
8.032
2.804
7.259
8.856
5.785
2.735
5.393
9.104
1.385
5.243
6.478
2.048
6.792
8.681
7.531
10.143
1
100.00
72.04
0.72
10.00
10.53
1.05
100.00
86.29
0.86
10.00
10.59
1.06
100.00
64.51
0.65
10.00
10.81
1.08
100.00
88.20
0.88
10.00
12.74
1.27
100.00
75.48
0.75
10.00
15.21
1.52
10.00
11.13
1.11
100.00
60.89
0.61
10.00
17.58
1.76
100.00
68.59
0.69
10.00
6.33
0.63
100.00
43.73
0.44
2
100.00
58.19
0.58
50.00
52.92
1.06
100.00
74.68
0.75
50.00
50.08
1.00
100.00
65.70
0.66
50.00
52.02
1.04
100.00
82.16
0.82
50.00
59.99
1.20
100.00
74.11
0.74
50.00
74.22
1.48
50.00
51.09
1.02
100.00
60.89
0.61
50.00
80.54
1.61
100.00
72.80
0.73
50.00
33.45
0.67
100.00
43.81
0.44
3
100.00
66.97
0.67
100.00
110.29
1.10
100.00
85.64
0.86
100.00
103.60
1.04
100.00
63.39
0.63
100.00
111.29
1.11
100.00
90.16
0.90
100.00
120.61
1.21
100.00
74.28
0.74
100.00
153.41
1.53
100.00
105.82
1.06
100.00
60.17
0.60
100.00
145.64
1.46
100.00
69.80
0.70
100.00
62.76
0.63
100.00
44.28
0.44
4
100.00
62.07
0.62
200.00
207.09
1.04
100.00
85.99
0.86
200.00
175.51
0.88
100.00
63.02
0.63
200.00
212.98
1.06
100.00
93.02
0.93
200.00
217.66
1.09
100.00
75.01
0.75
200.00
287.46
1.44
200.00
197.36
0.99
100.00
61.91
0.62
200.00
332.88
1.66
100.00
62.67
0.63
200.00
113.23
0.57
100.00
38.06
0.38
5
100.00
65.85
0.66
500.00
513.26
1.03
100.00
91.50
0.91
500.00
441.04
0.88
100.00
56.40
0.56
500.00
523.15
1.05
100.00
94.50
0.94
500.00
504.85
1.01
100.00
76.69
0.77
500.00
672.30
1.34
500.00
469.69
0.94
100.00
63.41
0.63
500.00
800.43
1.60
100.00
79.43
0.79
500.00
281.17
0.56
100.00
50.69
0.51
10
-------
O-AUG-1998 02:31:56 PH
ass Spec : ULTIMA
C Column : DB-5
65-04A.-04B, 651-21, 265-04D.-04E; Multiplier a 260V.
PAH CALIBRATION TABLE
File name
Date analyzed
PAHX081998U.RRF
19-AUG-98
INITIAL CALIBRATION CURVE
ibenz(ah)anthracene
12-Benzo(ght)perylene
enzo(ghi)perylene
3C-Fluorene
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
Amount
RF
RRF
1
11
,63
,99
,00
S.O.
0.036
0.060
0.034
0.000
XRSD
3.270
9.532
3.467
0.000
1
10.00
10.79
1.08
100.00
60.66
0.61
10.00
10.00
1.00
100
2
50.00
56.20
1.12
100.00
64.91
0.65
50.00
50.38
1.01
100
3
100.00
115.84
1.16
100.00
61.14
0.61
100.00
103.43
1.03
100
4
200.00
225.91
1.13
100.00
56.21
0.56
200.00
190.98
0.95
100
5
500.00
535.81
1.07
100.00
72.26
0.72
500.00
478.29
0.96
100.00
0.03
0.00
I/D
O
10
-------
CJ
FiIe:24AU98U #1-476 Acq:24-AUG-1998 17:35:49 GC EI+ Voltage SIR Autospec-Ultima
Sample*! Text:ST0824 :PAH CS-3 .-265-4C Exp:PAHAlR
128.0626 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 1
80-
60-
40-
20_
0_
134.0
1003
80-
60-
40J
20 J
0
136.1
100 S
80-
60-
40
20 J
0
142.0
100?
80 J
60 J
40J
201
0
152.1
100 S
801
60-
40J
20 J
o:
Al.
06E8
V
1 , 1 , , 1. , , , , , 1 1 , , 1 , 1 , r , — i - - i i , . . . .
9:00 10:00 11:00 12:00 13:
827 SMO(1,3) PKD(5,3,3,0.10%)10000.0,0.00%,F,T)
^ ^—-^~ s ^^^ ^
^T ~^^~' /^N ^ ^ ^^ ^ \ /^ j
V
9:bo 10:6o 11:00 12:00 13:
128 SMO(1,3) PKD(5,3,
Al.l
3,0.10%,10000.0,0.00%,F,T)
E8
L
1 1 ™ 1 1 ' 1 1 T^" I 1 1 1 1 1 1 1 1 1 1 1 1 1 1 — - —[ - i - ,- , , ,
9:00 10:60 11:00 12:6o 13:1
782 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
, A7. 9E7
A1.10E7
/ L A
1 , ,. , .,_ ., . — , — ,,,,-T 1 , , , ] j 1 — "I1- i — r 1— 1 1 1 1 r 1— i -r- — i — • i
9:00 10:00 11:00 12:60 13:(
410 SMO(1,3) PKD(5,3,3,0.107o,10000.0,0.00%,F,T)
f A9.6 E7
/ *
•^
9:do 10:1)0 11:00 12:00 13:
3.4E7
i2.7E7
-2.0E7
il.3E7
L6.7E6
O.OEO
)0 Time
3.4E4
L2.7E4
L2.0E4
L1.4E4
L6.8E3
O.OEO
bo Time
3.7E7
L3.0E7
L2.2E7
L1.5E7
L7.4E6
O.OEO
)0 Time
:.2.4E7
L1.9E7
Ll.4E7
L9.5E6
L4.8E6
: O.OEO
)0 Time
_3.0E7
L2.4E7
11.8E7
L1.2E7
-6.1E6
O.OEO
10 Time
-------
File:24AU98U #1-476 Acq:24-AUG-1998 17:35:49 GC EI+ Voltage SIR AuCospec-UUima
Sampled! Text:ST0824 :PAH CS-3 :265-4C Exp:PAHAIR
152.0626 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 % A1.02E8
80-
60
40:
20
A3.55E7
A
3.1E7
2.5E7
L1.8E7
1.2E7
6.1E6
O.OEO
Time
3.7E7
:2.9E7
-2.2E7
Ll.5E7
-7.4E6
13:66 13:12 13:24 13:36 13:48 14:66 14:i2; 14:24 14:36 14:48 15:66 15:h
160.1128 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100% A1.2JE8
80:
60:
40:
20
0
15:24 15:36
A3.00E7
i—i i ' I i I i i 1—r~~i—i—i—i—I—r—T—i—l—i—l—i—i—i—i—i—i—i—i—i—i—r—f—i—i—i—i i—I I—i—i—i—i—i—i—i—i—i—r—i—i—i*T""i I—l—r—i—r—i—r—r—i—r-
13:60 13:12 13:24 13:36 13:48 14:00 14:12 14:24 14:36 14:48 15:00 15:12
154.0782 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%>F,T)
100 % A7.05E7
80
60
40:
20:
0
i i i i i i i i i i i
15:24 15:36
O.OEO
Time
^2.3E7
1.8E7
1.4E7
9.0E6
-4.5E6
"r~* ' 'F"1' ' • r—T—ii i i i r-i i i i i i—i—i—r—i—i—i—i—i—i—i—i—i—i—r—i—i—i—i—r—i—i—r-i—r—T—r~i—i—i—r"T—i—i—i iH i i i "i T •[• i •
J:00 13:12 13:24 13:36 13:48 14:6o 14:12 14:24 14:36 14:48 15:00 15:12
164.1410 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
O.OEO
Time
i — i — i — i — i — i — i — i — i — | — i — i "i-'-
15:24 15:36
100
80
60
40
20
0
A8.20E7
2.6E7
:2.1E7
1.6E7
1.0E7
15.2E6
:00 13:12 13:24 13:36 13:48 14:66 14:^2 14:24 14:36 14:48 15:66 15:12 15:24 15:36
O.OEO
Time
-------
File:24AU98U #1-476 Acq:24-AUG-1998 17:35:49 GC EI+ Voltage SIR Autospec-Ultima
Sample/Cl Text:ST0824 :PAH CS-3 :265-4C Exp:PAHAlR
30.9920 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T) Ag 9gE9 A2.9,4E9
OOS
95:
90:
85 J
80:
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75-
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70:
65:
60:
55:
50:
45:
40-
35:
30:
25-
20-
15-
10-
5
0.
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A3.89E9 A f\ Hi
A3.17E9 r\
A2.88ET p\ A /
A2.20E9 ^ A
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:3.3E8
:3.1E8
.2.8E8
.2.6E8
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•
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-------
File:24AU98U 11-665 Acq:24-AUG-1998 17:35:49 GC EI+ Voltage SIR Autospec-Ultima
Sample*! Text:ST0824 :PAH CS-3 :265-4C Exp:PAHAlR
166.0798 F:2 SMO(1,3) PKD(5>3,3,0.10%,10000.0,0.00%,F,T)
003
90_
80-
70_
60_
50-
40_
30_
20-
10-
o
1
A5.95E7
A
1
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/ v_
h — 1 — 1 — 1 — 1 — 1 — 1 — [ — 1 — 1 — 1 — 1 — 1 — 1 — 1 — I — 1 — 1 — 1 — | — 1 — 1 — 1 — T — 1 — I — 1 1 '1 1 1 1 — 1 — 1 — 1 — 1 — I — 1 — 1 — 1 — 1 — 1 — 1 — I — 1 — 1 — 1 — 1 — 1 — [ — 1 — 1 — 1 — I — I — [ — I — 1 — 1 — I — 1 — \ — 1 1 1 ' ' T~l ' ' ' 1 [ " ' ' ' ' | ' '"
5:48 16:00 16:12 16:24 16:36 16:48 17:00 17:12 17:24 17:36 17:48 18:00 18:12 18:24
2.3E7
L2.1E7
L1.9E7
-1.6E7
L1.4E7
1.2E7
9.3E6
L6.9E6
.4.6E6
_2.3E6
O.OEO
Time
172.0984 F:2 SMO(1,3) PKD(5,3>3,0.10%,10000.0,0.00%,F,T)
1002
90 J
80
70
50
40J
30 J
20 1
10 J
OJ
17:40
18:19
15:48 16:66 16:i2 16:24 16:36 16:fi 17:66 17^2 17:24 "^17:56 17:48"
176.1410 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
18:1)0 18:12 18:24
4.3E3
3.9E3
3.5E3
3.0E3
2.6E3
2.2E3
1.7E3
1.3E3
8.7E2
4.3E2
O.OEO
Time
100 S
90:
80 J
70 J
60.
50:
40J
30 J
20 J
10J
0
1
p A5.97E7
Ijiliilliliiiliiiiililil 1 ~~ [' " 1 I 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 ( 1 1 1 1 1 1 1 1 T 1 1 1 1 1 1 1 1 1 1 1 1 1
5:48 16:60 16:12 16:24 16:36 16:48 17:00 17:12 17:24 17:36 17:48 18:00 18:12 18:24
2.4E7
L2.2E7
L1.9E7
L1.7E7
^l.4E7
I.2E7
9.6E6
L7.2E6
4.8E6
L2.4E6
O.OEO
Time
-------
File:24AU98U #1-665 Acq:24-AUG-1998 17:35:49 GC EI+ Voltage SIR Autospec-UItima
Sample*! Text:ST0824 :PAH CS-3 :265-4C Exp:PAHAlR
178.0782 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0)0.00%,F,T)
100 S
90-
80.
70_
60 _
50-
40J
30.:
20 J
10-
0
18:
188.1
100 °j
90-
80-
10-
60-
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40-
30-
20 1
10^
0
, A1.06E8
i
V9.7
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u
8E7
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0 19:00 20:00 21:1)0 22:
410 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
» A1.37E8
1
J
0 19:00
AS.
I
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i
i 1 1 i 1 1 : 1 1 1 1 1 1 i i
20:00 21:00 22:'
4.0E7
:3.6E7
-3.2E7
:2.8E7
:2.4E7
L.2.0E7
L1.6E7
-1.2E1
-7.9E6
4.0E6
O.OEO
)0 Time
5.3E7
L4.8E7
L4.2E7
-3.7E7
-3.2E7
-2.7E7
-2.1E7
-1.6E7
-1.1E7
-5.3E6
O.OEO
0 Time
-------
P1Ie:24AU98U #1-665 Acq:24-AUG-1998 17:35:49 GC EI+ Voltage SIR Autospec-Ultima
Sample*! Text:ST0824 :PAH CS-3 .-265-4C Exp.-PAHAIR
204.9888 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
OOS
95:
90:
85
VtJ —
80:
75:
70:
65:
60-
55-
50:
45:
40:
35-
30:
25_
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15:
10
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AA1.94E7A-,
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10
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87
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1.3E7
:1.2E7
-1.1E7
:1.0E7
:
:9.6E6
8.8E6
8.0E6
-7.2E6
:6.4E6
:5.6E6
-4.8E6
:4.0E6
:3.2E6
2.4E6
1.6B6
8.0E5
O.OEO
0 Time
-------
File:24AU98U #1-935 Acq:24-AUG-1998 17:35:49 GC E1+ Voltage SIR Autospec-Ultima
Sample*! Text:ST0824 :PAH CS-3 :265-4C Exp:PAHALR
202.0782 F:3 SMO(1,3) PKD(5,3,3,0.10%>10000.0,0.00%,F,T)
1003
90 J
80 J
70 J
60
50-
40:
30 J
20 J
10 J
0:
_:
22:
Al.
/
1 1 1 1 1 r 1 1 r-" —
X) 23:00
E8 A1.02E8
I 11
24:60 25:00 26:00
212.1410 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100% A1.19E8
90 J
80.
70.
60 J
50 J
30 J
20 J
10
A1.05E8
3.5E7
3.2E7
2.8E7
2.5E7
2.1E7
1.8E7
1.4E7
1.1E7
7.1E6
3.5E6
O.OEO
Time
.4.4E7
3.9E7
-3.5E7
J.1E7
.2.6E7
.2.2E7
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1.3E7
.8.7E6
4.4E6
O.OEO
Time
.4.4E7
3.9E7
J.5E7
.3.1E7
.2.6E7
2.2E7
I.7E7
.1.3E7
8.7E6
4.4E6
O.OEO
Time
1 r —' i 1 1 r 1 1 T r™
22:60 23:00
244.1974 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100^
90.
804
60
SQ
40J
30 J
20
10
O
24
:6fl
22:
26:C
00
23:t
24:00
25:t
26:0
-------
File:24AU98U #1-935 Acq:24-AUG-1998 17:35:49 GC E1+ Voltage SIR Autospec-Ultima
Sample*! Text:ST0824 :PAH CS-3 :265-4C Exp:PAHAlR
228.0939 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 % A8.5.7E7
90J
80
70 J
60
50
40
30_
20 J
10 J
oJ
2.8E7
-2.5E7
2.3E7
12.0E7
11.7E7
-1.4E7
1.1E7
L&.SE6
5.7E6
2.8E6
26:36 26:48 27:00 27:12 27:24 27:36 27:48 28:00 28:12 28:24 28:36 28:48
240.1692 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 % A1.25E8
9Q-
80
70
60-:
50.:
40J
30 J
20 J
10 J
0
29:24 29:36 29:48
O.OEO
30:00 Time
-3.4E7
L3.1E7
L2.8E7
L2.4E7
L2.1E7
:1.7E7
L1.4E7
1.0E7
26:36 26:48 27:66 27:12 27:i4 27:36 27:48 28:6o 28:ii 28:24 28^^28748 29:0«T 29:li 29:24 29:36 29:48
3.4E6
-O.OEO
30:00 Time
-------
-------
I.O
File:24AU98U #1-954 Acq:24-AUG-1998 17:35:49 GC EI+ Voltage SIR Autospec-UItima
Sample*! Text:ST0824 :PAH CS-3 :265-4C Exp:PAHAIR
252.0939 F:4SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
A6.25E7
30:00 31:00 32:00
264.1692 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
90_
80_
70 J
60 J
50 J
40:
30 J
20 J
10 J
33:00
30:00
31:00
~t r~
32
33:^0
34:00
-O.OEO
Time
-2.6E7
-2.4E7
.2.1E7
.1.8E7
.1.6E7
1.3E7
1.1E7
7.9E6
5.3E6
2.6E6
O.OEO
Time
-------
File:24AU98U #1-954 Acq:24-AUG-1998 17:35:49 GC EI+ Voltage SIR Autospec-UUima
Sample*! Text:ST0824 :PAH CS-3 :265-4C Exp:PAHAlR
276.0939 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 % A4.76E7
90
80
70J
60
50 J
40
30-
20 j
10
0
i i i i i i I—i—i i i i I—i i i—i—i—i i i i i i i—r~T-T"T~~i i I I—r
36:48 37:00 37:12 37:24 37:36 37:48
278.1096 F:4SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
90 -
70
60
50 JJ
40
30 J
20
10
0
I i I — I — <—r-\ 111111 ..... ,,.,,111
:36 38:48 39:00 39:12 39:24
6.9E6
6.2E6
5.5E6
4.8E6
4.1E6
3.5E6
2.8E6
-1.4E6
6.9E5
-i—i i i i—i—i—i i i i i i—i i i i i i i—i—i—i i i i—i—i—i—i—t—i—r-i-
36:48 37:60 37:12 37:24 37:36 37:48
38:00 38:12 38:24 38:36
^S^TT-T
38:48 39:00
39:24
.O.OEO
Time
.5.1E6
.4.6E6
.4.1E6
.3.6E6
3.IE6
2.6E6
2.0E6
1.5E6
I.OE6
5.1E5
O.OEO
Time
-------
File:24AU98U #1-954 Acq:24-AUG-1998 17:35:49 GC E1+ Voltage SIR Autospec-Ultima
Sample/Cl Text:ST0824 :PAH CS-3 :265-4C Exp:PAHAIR
276.0939 F:4 SMO(1,3) PKD(5,3,3,6.10%,16000.0,0.00%,F,T)
100 % A8.47E7
80:
60
20
A7.27E7
—i 1 1 1 1 r 1 1 1 1 1 r* 1
36:66 37:60 38:00
288.1692 F:4SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
39
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41 :t
80
60
40
204
A8.70E7
A9.53E7
42:(
8.9E6
7.1E6
15.3E6
3.5E6
I.8E6
O.OEO
10 Time
1.1E7
8.4E6
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:4.2E6
2.1E6
O.OEO
)0 Time
,_5.1E6
4.1E6
3.1E6
:2.0E6
1.0E6
O.OEO
»0 Time
—I 1 1 1 1 1 1 1 1 1 1—* 1 r-
36:60 37:60 38:00
278.1096 F:4SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
39
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i i i r-
100 °j
80
60:
40:
0:
36:1
A5.01E7
A
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1)0 37:00 38:00 39:1)0 40:00 41:00
292.1974 F:4 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
42:
42:1
100 S
80:
60
401
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S.5E6
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-2.2E6
I.IE6
-O.OEO
)0 Time
-------
•1111
-------
CO
File:24AU98U #1-476 Acq:24-AUG-1998 18:22:16 GO E1+ Voltage SIR Autospec-UItima
Sample*! Text:ST0824A :Prespike Cat Std Exp:PAHAIR
128.0626 S:2 SMO(1,3) PKD(5,3.3,0.10%,10000.0,0.00%,F,T)
9:3o ^loST
134.0827 S:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
136.1128 S:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
142.0782 S:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 S>
SOL
60 L
40L
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11:00
12
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152.1410 S:2 SMO(1,3) PKD(S,3,3,0.10%,10000.0,0.00%,F,T)
100%
80
60 L
40
20 L
Oj
11:
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13:
1.3ES
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60 L
40 L
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CM
File:24AU98U #1-666 Acq:24-AUG-1998 18:22:16 GC E1+ Voltage SIR Autospec-Ultima
Sampled Text:ST0824A .-Prespike Cal Std Exp.-PAHAIR
166.0798 S:2 F:2 SMO(1,3) PKD(S,3,3,0.10%,10000.0,0.00%,F,T)
100%
90 J
80
70
sol
40
30
20 J
10 J
0
15:48 16:00 16:i2 16:24 16:36
172.0984 S:2 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0
100 % A3.5QE7
90
80 J
70 J
60
50
40
30
20
10
0
16:48
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17:00 17:12 17:24 17:36 17:48 18:00
15:48 16:00 16:b 16:24 16:36 16:48
176.1410 S:2 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
A4.62E7
80 J
70 J
60
40J
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20 J
10 i
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1.2E7
L9.3E6
8.1E6
7.0E6
5.8E6
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1.2E6
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18:12
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1.3E7
1.2E7
9.9E6
8.2E6
6.6E6
4.9E6
3.3E6
1.6E6
O.OEO
Time
-------
File:24AU98U #1-666 Acq:24-AUG-1998 18:22:16 GC EI+ Voltage SIR Autospec-Ultima
Sampled Text:ST0824A :Prespike Cal Std Exp:PAHAIR
204.9888 S:2 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
\
100 S
95 _
90 _
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:O.OEO
>0 Time
-------
File:24AU98U #1-476 Acq:24-AUG-1998 19:08:46 GC E1+ Voltage SIR Autospec-Ultima
Sample*) Text:SB0824 :Solvent Blank :C8 Exp:PAHAIR
128.0626 S:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 % A2.98E5
80 J
60 J
40
20
9:do 10:00
134.0827 S:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
1.2E5
L9.5E4
7.1E4
-4.8E4
2.4E4
O.OEO
K) Time
11:
12:(1
13:4
136.1128 S:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 % 8:22 8
142.0782 S:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
1002
80
60
40
20
0 ,
--, , , ,___,-, , , , ^ ^
152.1410 S:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100'
-------
File:24AU98U #1-476 Acq:24-AUG-1998 19:08:46 GC EI+ Voltage SIR Autospec-Ultima
Sampled Text:SB0824 .-Solvent Blank :C8 Exp:PAHAlR
152.0626 S:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 % 14:]
80
60 J
40:
201
0
14:54
3.8E4
15:28 15:40
"—i i i i i i i i i i i ] i i i i i i i i i i i i i i i i i I i
13:00 13:12 13:24 13:36 13:48 14:00
160.1128 S:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%)F,T)
100%
80 J
60
40
204
0
I I I I I I I I I I I I I I I I I I I I I | I I I I I—T— I I I I I I I I I I I I I
14:12 14:24 14:36 14:48 15:00 15:12 15:24 15:36
14:14
15:33
;-2.3E4
1.5E4
L7.5E3
O.OEO
Time
.-7.4E3
5.9E3
t-4.4E3
2.9E3
-1.5E3
13:05
13:00 13:h 13:24 13:36 13:48 WbO \4-\2 14:24 14:36 14:48 15:00 IS.-li 15:24 15:36
.O.OEO
Time
154.0782 S:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100', x
A4.76E5 A3.02E5
A3.10E5 A3.35E5
A1.60E5 A2.33E5
13:12 13:24 13:36 ' 13:48 14:00
164.1410 S:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100
14:24 "^14:56 14:48 15:00 15:T2
14:30
14:18
A2.38E5
1 i \ /
4 ' ' 15:36
2.6E5
L2.1E5
i-1.6E5
Ll.lES
5.3E4
O.OEO
Time
13:
O.OEO
Time
-------
File:24AU98U #1-476 Acq:24-AUG-1998 19:08:46 GC EI+ Voltage SIR Autospec-Ultima
Sampled Text:SB0824 :Solvent Blank :C8 Exp:PAHAlR
130.9920 S:3 SMO(1,3) PKD(S,3,3,0.10%,10000.0,0.00%,F,T)
100%
95.:
90 j
85
80
75:
70 J
65 J
60:
55
50 4
45
40
35
30 J
25
20 4
15
10-
5
0
A6.49E8
A1.83E8
A4.89E8
l\
A4.56E8
\
^ 10:00
11:00
12:<1
13:1)0
14^00
IS-fllT
2.5E8
2.3E8
2.2E8
2.1E8
2.0E8
1.8E8
-1.7E8
1.6E8
1.5E8
L1.4E8
Ll.2E8
1.1E8
9.8E7
8.6E7
_7.4E7
L6.1E7
4.9E7
-3.7E7
-2.5E7
-1.2E7
-O.OEO
Time
-------
File:24AU98U #1-666 Acq:24-AUG-1998 19:08:46 GC EI+ Voltage SIR Autospec-UItima
Sampled Text:SB0824 .-Solvent Blank :C8 Exp:PAHAlR
166.0798 S:3 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
-H—1—i—i—i—i—i—I—i—i—i—i—i—|—i—i—i—i—i—1—i—i—i—i—i—I—i—i—i—i—i—1—i—i—i—i—i—i—i—i—i—i—i—1—i—i—i—i—i—i—i—i—i—i—I—T—i—i—i—i—I~T~I—'—'i'r~< ' 'r-i—i—r-
15:48 16:00 16:12 16:24 16:36 16:48 17:00 17:12 17:24 17:36 17:48 18:00 18:12
172.09848:3 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
18:2
100
90
80
704
60
SO
40
30 j
20
10
OJ
16:36
15:48 16:1)0 ' 16:12 ' ' 16:24 ' ' '16:36^ 'l6-48 T7:6o 17:il2 ' 17:24 "77:36 'iT^T^Ts^HJ 18:ll2 18:54
176.1410 S:3 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
18:25
15:48 16:1)0 16:b 16:24 '16^3/^^16:48 ^IT-fo ll-M '""17:24 'iT-K^^T?:^ ^"Is-Oo" 18:^2 18:24
4.0E3
L3.6E3
3.2E3
L2.8E3
L2.4E3
2.0E3
1.6E3
1.2E3
8.0E2
4.0E2
O.OEO
Time
r3.5E3
L3.1E3
L2.8E3
L2.4E3
L2.1E3
L.I.7E3
LI.4E3
L1.0E3
L7.0E2
-3.5E2
-O.OEO
Time
-------
File:24AU98U if 1-666 Acq:24-AUG-1998 19:08:46 GC EI+ Voltage SIR AutospeoUltima
Sampled Text:SB0824 :Solvent Blank :C8 Exp:PAHAIR
178.0782 S:3 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
19:47
18:00 19:6o
188.1410 S:3 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
20:t
21
21:04 21:18 21:36 21:54
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2.8E4
L2.5E4
L2.3E4
L2.0E4
L1.7E4
L1.4E4
.1.1E4
L8.5E3
I.5.6E3
L2.8E3
O.OEO
)0 Time
100%
90
80
70
60
50
40
30-
20 j
10
0
19:41
18:06
)0 Time
-------
File:24AU98U #1-666 Acq:24-AUG-1998 19:08:46 GC E1+ Voltage SIR Autospec-UItima
Sampled Text:SB0824 .-Solvent Blank :C8 ExprPAHAIR
204.9888 S:3 F:2 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
0 Time
-------
File:24AU98U #1-934 Acq:24-AUG-1998 19:08:46 GC E1+ Voltage SIR Autospec-Ultima
Sampled Text:SB0824 :Solvent Blank :C8 Exp:PAHAlR
202.0782 S:3 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
24:21
22:27
90
80
70 j
60
50 j
40
30
20 J
10
0
22:00 23:6024:6o
212.1410 S:3 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 % A6.23E4
90.
80-
A3.50E4
25:(1
26:00
22:00 23:1)0 24:6o
244.19748:3 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100
90
804
70
60
50
40
30
20
22:
03
.-I
r1.6E4
L1.4E4
L1.3E4
I.1E4
L9.4E3
L7.9E3
L6.3E3
L4.7E3
M.1E3
L1.6E3
LO.OEO
Time
-------
File:24AU98U #1-934 Acq:24-AUG-1998 19:08:46 GC E1+ Voltage SIR Autospec-Ultima
Sampled Text:SB0824 :Solvent Blank :C8 Exp:PAHAIR
228.0939 S:3 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100 ft 28 20
90:
80:
70:
60
50:
40:
30:
20
10
0:
29:35
,9:46
26:40
26:35
i i i i i i i i i i i i i i •! i -i i i i i I < i i i i I i i i » i i~i '» ii i '' ' '' I '''•>' I *
26:36 26:48 27:00 27:12 27:24 27:36 27:48 28:00 28:12
240.1692 S:3 F:3 SMO(1,3) PKD(5,3,3,0.10%,10000.0,0.00%,F,T)
100%
' 28:48 ' 29:1(0^19^2^29124^29^6 29:48 "Ifc
1.8E4
1.6E4
_1.SE4
L1.3E4
1.1E4
-9.2E3
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L5.5E3
-3.7E3
-1.8E3
O.OEO
M) Time
90 -
80:
70 J
60
50-
40:
30
20
10
OJ
A5.34E5
26:36 26?48 27:66 ' ' 27:i2 ' ' 27:24
,_9.9E4
8.9E4
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L4.9E4
L3.9E4
L3.0E4
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9.9E3
r ^^^-^^O.OEO
):24 29:36 29:48 30:00 Time
-------
File:24AU98U if 1-934 Acq:24-AUG-1998 19:08:46 GC E1+ Voltage SIR Autospec-Ultima
Sampled Text:SB0824 :Solvent Blank :C8 Exp:PAHAlR
230.9856 S:3 F:3 SMO(1,3) PKD(S,3,3,0.10%,10000.0,0.00%,F,T)
100%
95:
90:
85:
80:
75:
70:
65:
60
55
50:
45:
40
35_|
30:
25:
20:
15-
10
5-
0
22:
A6.58E7
A1.59E8
A2.25E8
A2.14E8
A1.91E8
A8.65E7
23:60 24:00
25^)0
^9:00^
30:1
-9.9E7
9.0E7
8.1E7
:7.2E7
:6.3E7
-5.4E7
-4.5E7
3.6E7
2.7E7
1.8E7
9.0E6
O.OEO
0 Time
-------
Sample Extraction/
Preparation Log Copies
632
-------
QUANTERRA INCORPORATED
West Sacramento
ADVANCED TECHNOLOGY
HIGH RESOLUTION ANALYSIS
CLIENT NAME:
PROJECT #:
DATE RECEIVED:
ANALYSIS: __^_i___
DATE TO SUBBING: a03^& DATE IN PREP: ft-QLj *?£"
LOCATION: lJJll0A&-r1> MATRIX: Afr^ThuV^ TAT: dOAOlA C
INITIALS:
HOLD TIME UP ON:
PAGE
\ OF
SOXHLET
WW/EE
SOLVENT QC
-------
Quanterra Environmental Services, Sacramento
880 Riverside Parkway
West Sacramento, California 95605
(916) 373-5600
CALLAB-300681
Date Received
: 30 JUL 98 10:50
Mr. Frank Phoenix
Pacific Environmental Services
Suite 300
Research Triangle Park, North Carolina
277092077
(919) 941-0333 Fax: (919) 941-0234
Project ID,
EPA Case, RMA Lot
P.O. Number
Delivered By
Storage Location
Logged in by
PAH/8270
104-98-0239
W16ABD
MDYAS
Airtrain(ll) samples received under Chain-of-Custody in good
condition. Delivered by client.
Sample ID
Client's label info
300681-
300681-
300681-
300681-
300681-
300681-
300681-
300681-
300681-
300681-
300681-
300681-
0001-SA
0001-MB
0002-SA
0003-SA
0004-SA
0005-SA
0006-SA
0007-SA
0008-SA
0009-SA
0010-SA
0011-SA
S-MM5-
S-MM5-
S-MM5-
T-MM5-
T-MM5-
T-MM5-
T-MM5-
S-MM5-
S-MM5-
S-MM5-
S-MM5-
S-MM5-
2-F,FH,
2-F,FH,
1B-F.FH
2-F.FH,
FB-F.FH
4-F.FH,
3-F.FH,
3-F.FH,
FB-F,FH
RB-F,FH
4-F,FH,
5-F,FH,
XAD,COND,BH
XAD,COND,BH
,XAD,COND,BH
XAD,COND,BH
,XAD,COND,BH
XAD,COND,BH
XAD,COND,BH
XAD,COND,BH
,XAD,COND,BH
,XAD,COND,BH
XAD,COND,BH
XAD,COND,BH
Date/Time Samp. Containers
25 JUL 98 AGJ 3-500AGJ XAD
25 JUL 98 AGJ 3-500AGJ XAD
25 JUL 98 AGJ 3-250AGJ XAD
25 JUL 98 2-500AGJ 2-250AGJ XAD
25 JUL 98 500AGJ 3-250AGJ XAD
26 JUL 98 500AGJ 3-250AGJ XAD
27 JUL 98 500AGJ 3-250AGJ XAD
27 JUL 98 3-AGJ 3-250AGJ XAD
26 JUL 98 AGJ 3-250AGJ XAD
25 JUL 98 4-250AGJ XAD
25 JUL 98 3-500AGJ 3-250AGJ XAD
28 JUL 98 3-500AGJ 3-250AGJ XAD
Samples not destroyed in testing are retained a maximum
of thirty (30) days unless otherwise requested.
Project Manager: Robert Weidenfeld
-------
QUANTERRA INCORPORATED
West Sacramento
ADVANCED TECHNOLOGY
HIGH RESOLUTION PREP
Methods 23, 428, 429,1668, and T-O IX
BENCHSHEET FOR EXTRACTION OF AIR MEDIA
PROJECT #:
MATRIX:
ANALYSIS:.
TAT:
PAH
DATE RECEIVED:
DATE IN PREP:
DUE DATE:
GCMS LOCATION:
EXTRACTION TYPE: SOXHLET
SOLVENT TYPE: TOLUENE
2-2- DATE TO GCMS: fr - (?"9 S
613 DILUTION OTHER:.
HEXANE DCM OTHER:
SAMPLE ID
- \
-a
-7
-lo-
-u-
-/«*&
- \*(S*e
- |Lt*J
- ll#
-•5
-^
-5
Sample Size
*ii*
BpH *-!»
>
f
M
X
^*n
>K
613
Daie'Int
^
Soxhlei
Date'lnt
Silica Cel
Date/Int
8-i*«n
*»**
i
r
Upper IFB
Date/ Int.
Lower IFB
Date,' Int.
IFB
Date/Int
Special D2
Date.- Int.
(All Samples)
I.S. Added:
(LCS/MS/SD)
PAR/Nat. Added:
(MB Only)
Surrogate Added:
(All Samples)
R.S. Added:
Associated QC:
bv:
by:
by:
by:
Witness:
Witness:
Witness:
Witness:
Date:
Date:
Date:
Date:
Associated Projects:
b;
Dilution @ Extraction?
Split of Extract?
Dilution 3 Final Volume?
No
No
No
Yes (describe)
(^describe) «
Yes 1:5
-, ,fi
( V'
1:10
10
,4
QA-236-MF 11/9'
-------
QUANTERRA INCORPORATED
West Sacramento
ADVANCED TECHNOLOGY
HIGH RESOLUTION PREP
Methods 23, 428, 429,1668, and T-O IX
BENCHSHEET FOR EXTRACTION OF AIR MEDIA
PROJECT*:
ANALYSIS:
MATRIX:
TAT:
DATE RECEIVED:
DATE IN PREP:
GCMS LOCATION: _
EXTRACTION TYPE. SOXHLET 613
SOLVENT TYPE. TOLUENE HEXANE
DATE TO GCMS: _
DILUTION
DCM
DUE DATE:
OTHER:.
OTHER:
SAMPLE ID
-£
-f
-?
•
Sample Size
,
613
Date/Int.
Soxhlet
Datilni.
Silica Gel
Date.' Int.
*'1BO%*
\
w
Upper IFB
DatoTnL
Lower IFB
Date'Int.
IFB
Data Int.
Special D2
Date/Int.
(All Samples)
I.S. Added: bv: Witness: Date'
(LCS/MS/SD)
PAR/Nat. Added: bv: Witness: Date-
(MB Only)
Surrogate Added: bv: Witness' Date-
(All Samples) A/
R.S. Added: JodU ZfcS" -O^ bv: &OU Witness: Date-
Associated QC:
Associated Projects:
Dilution @ Extraction?
Split of Extract?
Dilution •© Final Volume''
No
No
No
Yes (describe)
Yes (describe)
Yes 1:5
1:10
ClO Cj; CM
QA-236-MF 11/97
-------
OT
Quanterra - Sacramento
Data Checklist
High Resolution Analyses
Scrn'oa
CAL ID:
Method ID:
Data Analyst:.
Date initiated:.
Reviewer:.
Date reviewed:
DB-5
t^/ff f*3, •>,:>.. <^_
C «.!VtX
'Tkt.
-£i^
&"
Recovery limits:
NCASI 551:
Method 8290:
Method 1613:
Method 23:
CARB 428:
CARB 429
PCBs:
DBD/DBF:
Sec
**
40-120% (20-39% OK if S/N-10:1 for IS)
40-135%
25-150%
40-130%(C14-C16), 25-130%(C17-8), 70-130%(surr
40-120% (out of limits OK if S/N-10:1 for IS)
50-150%
25-150%
20-150%
QA-371,10/96,NE
RPD limit
50%
20%
50% f,
50%
50%
50%
50%
-------
** NOT LOG RELEASED! **
QUANTERRA-CALLAB LABORATORY
•^ VU/ /-r7" Chromatography Assignment Sheet
Project I: 300681 Due Date: 19 AUG 98
Analysis: P-PAH-HR-AIR Ver: 1 Receipt Date: 30 JUL 98
Client: Pacific Environmental Services Log Released:
PA: RWEIDENFELD Turnaround: NORMAL
Delivery Accepted: MDYAS 30 JUL 98 Storage Location: W16ABD
Number of Samples: 11 Earliest Holding Time: 15 AUG 98
Program: General Airtox
Project Description:
Airtrain samples to be split and analyzed for Hi res PAHs and
0010/8270.
Note there are a number of 8270 compounds that will need to be
reported by library search. These compounds will be designated
by -- in place of a reporting limit.
Full paginated raw data package reuqired
Test Modified: N
Sample Instructions: N
Test Instructions: N
Group Instructions: N
QAS i:
Date Delivered to PA:
Comments:
No Problems Occurred with Analysis
v'See Anomaly Sheet
-------
QUANTERRA-CALLAB LABORATORY
Bottle Descriptions
Project I: 300681 Test: P-PAH-HR-AIR
000ISA - AGO 3-500AGJ XAD
0002SA - AGO 3-250AGO XAD
0003SA - 2-500AGJ 2-250AGJ XAD
0004SA - 500AGJ 3-250AGJ XAD
0005SA - 500AGO 3-250AGJ XAD
0006SA - 500AGJ 3-250AGJ XAD
0007SA - 3-AGJ 3-250AGJ XAD
0008SA - AGJ 3-250AGJ XAD
0009SA - 4-250AGJ XAD
0010SA - 3-500AGJ 3-250AGJ XAD
001 ISA - 3-500AGJ 3-250AGJ XAD
-------
OUANTERRA-CALLAB LABORATORY
Analytical Bench Sheet
Project Number: 300681 Date: 31 JUL 98 Page 1 of 1
Test Code: P-PAH-HR-AIR Test Description: Prep - Polynuclear Aromatic Hydrocarbons by HRMS
Turnaround Status: NORMAL Sample Matrix: AIRTRAIN Date Assigned: f/3 I prep Completion Due:
SOP-Sect ion/Page (Revision): j.fl'1-'C/!l,'?\fO*
Extractions: [ ] Separatory Funnel [ ] Continuous Liquid/Liquid [ ] Sonication L^Soxhlet [ ] KD
C 1 Roto Vap t ] Shaker [ ] Other
Samp
ID
0001 SA
0002SA
0003SA
0004SA
0005 S A
0006SA
0007SA
0008SA
0009SA
0010SA
0011SA
m&
jt$
Nfi
Holding
Time
15 AUG 98
15 AUG 98
15 AUG 98
15 AUG 98
16 AUG 98
17 AUG 98
17 AUG 98
16 AUG 98
15 AUG 98
15 AUG 98
18 AUG 98
/V/>
I
Sample
Size
/lit-
ftfAiv .
(W
yfiKfJ
*!/
A/A
Extractn
Date/
Initials
tf7/*
tM*t
i
\
%!/
Adj pH
Date/
Initials
/
/
/
/
Hydrolysis
Date/
Initials
1
Mi
w
/
/
Acid Ext
Date/
Initials
1
I
I
Cone
Date/
Initials
Wit
t/*hi
t
CH2N2
Date/
Initials
N2
Date/
Initials
jfiK
tfav
\^
f
Final
Sample
Concentn
#*£<
S$*>-
f
S
Project Due: 19 AUG 98
Method Blank With Project:,
DCS With Project:_
LCS With Project:
DCS Code:
LCS tote
-. 3 i J\J L^l
Notes/Comments :
** PLEASE PUT COMMENTS ON ANOMALY SHEET **
,0
Extraction Includes Project(s): •*'
MSQC with Project:
MSQC Code:
Peer Approval By:_
-------
QUANTERRA-CALLAB LABORATORY
Quality Assurance Sheet
Project I: 300681 Test: P-PAH-HR-AIR
Quality Assurance/Quality Control:
Sample ID; ftLL Spiking Standard Name;/#^? Pfctf -£,
Spike Code ID; ££5^o'*- Volume: /^&£. Cone:
Spiked By; /hjf Witness:
\f if*~-J~-~~—
^y
Sample ID; ffl& OA/Ly Spiking Standard Name; ffi*f*fd£&{C
Spike Code ID; ty£%~l*l Volume: f£2)j,JL, Cone: _/j
Spiked By; ff[/f Witness:
Sample ID; > Spiking Standard Name ;
Spike Code ID;:-^ Volume: ^ Cone:
Spiked By; fLfl Witness: _
W
Sample ID: Spiking Standard Name:
Spike Code ID: Volume: Cone:
Spiked By: Witness:
Solvent: Manufacturer And Lot Number:
Extracting Solvent:
Solvent Keeper:
Transfer Solvent:
Derivatizing Reagent:
Final Solvent:
Other:
_
What was the sample concentration before al i quot? ££ I > 3
Was an aliquot taken? (j?/ N
If yes, how much was aliquoted? _ jf mL// ¥ .mL
Why was the aliquot taken? 3f(~ffu/S'l''7Q
-------
QUANTERRA-CALLAB LABORATORY
Instruction Sheet
Project I: 300681 Test: P-PAH-HR-AIR
Sample Instructions:
None.
Test Instructions:
None.
Group Instructions;
None.
-------
QUANTERRA-CALLAB LABORATORY
Anomaly Report Form
Project #: 300681 Test: P-PAH-HR-AIR
Anomalies: Sample(s) Affected:
Sample broken during shipping.
Limited sample volume.
Matrix required a subsample to facilitate extraction.
pH of sample required excess acid/base (please circle).
Solvent and sample were miscible.
_ Emulsion problems.
_ Emulsion problem required centrifuging.
Sample lost during preparation.
Re-extraction performed? Yes/No
Concentration volume went lower than specified in the
SOP.
Concentration time longer than normal.
_ Extraction solvent saturated with organic material,
therefore sample volume was not concentrated but
adjusted based on the screening.
Final concentration greater than specified in the SOP
due to the screening results.
Precipitate observed in the extract.
^_ Other, please comment below. / I 7 JO. //
Comments:
/7/A//_
Submitted By:_/7//_ _ Date;
-------
QUANTERRA-CALLAB LABORATORY
Prep (Extraction) Check List
Project #: 300681 Test: P-PAH-HR-AIR
Chemist: /ffo^' Date: //T/?/
lrt_/rf '
Reviewer:
Date:
Number of samples: 11 Number of extracts:
Benchsheet;
SOP section and page number filled out properly.
Each step of extraction procedure initial'ed and dated.
Anomalies or deviations from SOP documented.
pH adjustments noted.
Solvent manufacturer and lot number completed.
Volumes and weights of samples to two sig. figs.
QA/QC;
DCS/MS forms filled out properly.
Spike information correct on bench sheet.
Spike witness?
If not spiked per SOP, were spike amounts verified?
LIMS;
Extraction date (complete date) correct.
QC lot number present and correct.
QC Run number present and correct.
Prep released (date extract goes to Inst.).
Extracts;
Number of extracts agree with benchsheet.
Concentrations of extract agree with benchsheet.
Testtube rack labelled with project id and test.
Initiated
Reviewed
Y N
Y N
Y N
Y N
Y N
Y N
Initiated
Y N
Y N
Y N
Y N
Initiated
Y N
Y N
Y N
Y N
Initiated
Y N
Y N
Y N
Y N
Y N
Y N
Y N
Y N
Y N
Reviewed
Y N
Y N
Y N
Y N
Reviewed
Y N
Y N
Y N
Y N
Reviewed
Y N
Y N
Y N
Comments:
-------
QUANTERRA-CALLAB LABORATORY
Client Descriptions
Project I: 300681 Test: P-PAH-HR-AIR
0001SA - S-MM5-2-F,FH,XAD,COND,BH
0002SA - S-MM5-1B-F,FH,XAD,COND,BH
0003SA - T-MM5-2-F,FH,XAD,COND,BH
0004SA - T-MM5-FB-F,FH,XAD,COND,BH
0005SA - T-MM5-4-F,FH,XAD,COND,BH
0006SA - T-MM5-3-F,FH,XAD,COND,BH
0007SA - S-MM5-3-F,FH,XAD,COND,BH
0008SA - S-MM5-FB-F,FH,XAD,COND,BH
0009SA - S-MM5-RB-F,FH,XAD,COND,BH
0010SA - S-MM5-4-F,FH,XAD,COND,BH
0011SA - S-MM5-5-F,FH,XAD,COND,BH
-------
QUANTERRA / W. SACRAMENTO
PROJECT QC LIMITS
Pacific Environmental Services
Project: CALLAB-300681
Matrix: AIR
Test Code: PAH-HR-AIR
Version: 1
QC Category: PAH-HR-AIR
OAS#
Modified
Component
1 * Naphthalene
2 * 2-Methylnaphthalene
3 * Acenaphthylene
4 * Acenaphthene
5 * Fluorene
6 * Phenanthrene
7 Anthracene
8 * F luoranthene
9 * Pyrene
10 (Jenzo(a)anthracene
11 * Chrysene
12 * Benzo(b)f luoranthene
13 * Benzo(k)f luoranthene
14 * Benzo(e)pyrene
15 * Benzo(a)pyrene
16 * Perylene
17 lndeno(1,2,3-cd)pyrene
18 * Dibenz(a,h)anthracene
19 * Benzo(g,h,i)perylene
20 Naphthalene-dS
21 * 2-Methylnaphthalene-dlO
22 * Acenaphthylene-d8
23 * Acenaphthene- d10
24 * Fluorene-d10
25 * Phenanthrene-dIO
26 * Fluoranthene-d10
27 * Pyrene-d10
28 * Benzo(a)anthracene-d12
29 * Chrysene-d12
30 * Benzo(b)fluoranthene-d12
31 * Benzo(k)fluoranthene-d12
32 * Benzo(a)pyrene-d12
33 * Perylene-d12
34 * Indeno(123-cd)pyrene-d12
35 * Dibenz(a,h)anthracene-d1
36 * Benzo(g,h,Operylene-d12
37 * Anthr«eene-d10
38 * TerphentfTrdH
RL Surrogate/SCS Lab Control (LCS) Lab Control (DCS) Matrix Spike
Date:
CASN wns oth wns othwns othwns oth wns othwns othwns oth wns othwns othwns othwns oth wns othwns othwns othwns oth
91203
91576
208968
83329
86737
85018
120127
206440
129000
56553
218019
205992
207089
192972
50328
198550
193395
53703
191242
1146652
91576
93951974
15067202
81103799
1517222
93951690
1718521
1718532
1719035
93951985
93952013
63466717
1520963
-559943396
13250981
93951667
1719068
1718510
50
50
50
*
50
50
ng
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
*
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
150
150
150
* ^^
150
150
150
150
150
150
150
150
150
150
150
150
150
150
150
-------
** NOT LOG RELEASED! **
QUANTERRA-CALLAB LABORATORY
Chromatography Assignment Sheet
Project #: 300681 Due Date: 19 AUG 98
Analysis: P-PAH-HR-AIR Ver: 1 Receipt Date: 30 JUL 98
Client: Pacific Environmental Services Log Released:
PA: RWEIDENFELD Turnaround: NORMAL
Delivery Accepted: MDYAS 30 JUL 98 Storage Location: W16ABD
Number of Samples: 11 Earliest Holding Time: 15 AUG 98
Program: General Airtox
Project Description:
Airtrain samples to be split and analyzed for Hi res PAHs and
0010/8270.
Note there are a number of 8270 compounds that will need to be
reported by library search. These compounds will be designated
by -- in place of a reporting limit.
Full paginated raw data package reuqired
Test Modified: N
Sample Instructions: N
Test Instructions: N
Group Instructions: N
QAS #:
Date Delivered to PA:
Comments:
No Problems Occurred with Analysis
See Anomaly Sheet
-------
QUANTERRA-CALLAB LABORATORY
Bottle Descriptions
Project #: 300681 Test: P-PAH-HR-AIR
000ISA - AGJ 3-500AGJ XAD
0002SA - AGJ 3-250AGJ XAD
0003SA - 2-500AGJ 2-250AGJ XAD
0004SA - 500AGJ 3-250AGJ XAD
0005SA - 500AGJ 3-250AGJ XAD
0006SA - 500AGJ 3-250AGJ XAD
0007SA - 3-AGJ 3-250AGJ XAD
0008SA - AGJ 3-250AGJ XAD
0009SA - 4-250AGJ XAD
0010SA - 3-500AGJ 3-250AGJ XAD
00USA - 3-500AGJ 3-250AGJ XAD
-------
QUANTERRA-CALLAB LABORATORY
Analytical Bench Sheet
Project Number: 300681 Date: 31 JUL 98 Page 1 of 1
Test Code: P-PAH-HR-AIR Test Description: Prep - Polynuclear Aromatic Hydrocarbons by HRHS
Turnaround Status: NORMAL Sample Matrix: AIRTRAIN Date Assigned: '/I' Prep Completion Due:_
(Re
/00
Extractions: ( N/'Separatory Funnel) t 3 Continuous Liquid/Liquid [ ] Sonication [ ] Soxhlet C ] KD
Samp
ID
0001 SA
0002SA
0003SA
0004SA
0005SA
0006SA
0007SA
0008SA
0009SA
001 OSA
001 1SA
ttfc
LC&
A/H-
IV T •
t 1 R<
Holding
Time
15 AUG 98
15 AUG 98
15 AUG 98
15 AUG 98
16 AUG 98
17 AUG 98
17 AUG 98
16 AUG 98
15 AUG 98
15 AUG 98
18 AUG 98
n/JV
i
no Vap
Sample
Size J
^fafr
*
Lo<-
1
t )
Extractn
Date/
Initials
b/.l««
•^
Shaker
Adj pH
Date/
Initials
%l \0ft
^
Hydrolysis
Date/
Initials
%V/*
N-
t 1 Ot
Acid Ext
Date/
Initials
w««
T
i
j
^
:her
Cone
Date/
Initials
;/%/w;
Uffb
i/r/u
I
Final
Sample
Concentn
'# j
f't T/v'A*'
^%£
i
///h
: (J
/ &/(, w
Extraction Includes Project(s): /«"<• ^
Notes/Comments:
** PLEASE PUT COMMENTS ON ANOMALY SHEET ** MSQC with Project:
MSQC Code:
Date To-lnotpumcntfc4. /
By:
Peer Approval By:_
-------
QUANTERRA-CALLAB LABORATORY
Quality Assurance Sheet
Project I: 300681 Test: P-PAH-HR-AIR
Quality Assurance/Quality Control:
Sample ID; £& \$)/\j.$ *?p&ing Standard Name: HW -bcu
Spike Code ID; 3(£> -QX Volume: 150iA Cone: \
Witness:
Spiked By:
Sample ID; LjO^, cr>U
vA
'
Spike Code IQ_M-
Spiked By:
Spiking Standard Name:
Volume: "?*5^ y^ Cone:
Witness:
Sample ID:
Spike Code ID:
Spiked By:
Spiking Standard Name:
Volume: Cone:
Witness:
Sample ID:
Spike Code ID:
Spiked By:
Spiking Standard Name:
Volume: Cone:
Witness:
"C SkV^JL
Solvent: Manufacturer And Lot Number:
Extracting Solvent;
Solvent Keeper:
Transfer Solvent:
Derivatizing Reagent:
Final Solvent:
Other:
Was an aliquot taken? (jjf N
If yes, how much was aliquoted?
What was the sample concentration before aliquot^
f*./!* .
mL
Why was the aliquot taken? JfLlf
li!
-------
QUANTERRA-CALLAB LABORATORY
Instruction Sheet
Project #: 300681 Test: P-PAH-HR-AIR
Sample Instructions:
None.
Test Instructions:
None.
Group Instructions;
None.
-------
QUANTERRA-CALLAB LABORATORY
Anomaly Report Form
Project #: 300681 Test: P-PAH-HR-AIR
Anomalies: Sample(s) Affected:
_ Sample broken during shipping.
Limited sample volume.
_ Matrix required a subsample to facilitate extraction.
pH of sample required excess acid/base (please circle).
Solvent and sample were miscible.
Emulsion problems.
Emulsion problem required centrifuging.
Sample lost during preparation.
Re-extraction performed? Yes/No
_ Concentration volume went lower than specified in the
SOP.
Concentration time longer than normal.
Extraction solvent saturated with organic material,
therefore sample volume was not concentrated but
adjusted based on the screening.
Final concentration greater than specified in the SOP
due to the screening results,
Precipitate observed in the extract.
x/ Other, please comment below. / 2, 7 /O 11
•7 7 '7~
Comments:
o/C-
Submitted By: fJf/lJ Date:
-------
QUANTERRA-CALLAB LABORATORY
Prep (Extraction) Check List
Project #: 300681 Test: P-PAH-HR-AIR
Chemist: fl/U)~T Date:
v s '
Reviewer: Date:
Number of samples r^W^Number of extracts:
Benchsheet;
SOP section and page number filled out properly.
Each step of extraction procedure initial'ed and dated.
Anomalies or deviations from SOP documented.
pH adjustments noted.
Solvent manufacturer and lot number completed.
Volumes and weights of samples to two sig. figs.
QA/QC;
DCS/MS forms filled out properly.
Spike information correct on bench sheet.
Spike witness?
If not spiked per SOP, were spike amounts verified?
Extraction date (complete -late) correct.
QC lot number present and correct.
QC Run number present and correct.
Prep released (date extract goes to Inst.).
Extracts:
Number of extracts agree with benchsheet.
Concentrations of extract agree with benchsheet.
Testtube rack labelled with project id and test.
Initiated
Reviewed
Y N
Y N
Y N
Y N
Y N
Y N
Initiated
Y N
Y N
Y N
Y N
Initiated
Y N
Y N
Y N
Y N
Initiated
Y N
Y N
Y N
Y N
Y N
Y N
Y N
Y N
Y N
Reviewed
Y N
Y N
Y N
Y N
Reviewed
Y N
Y N
Y N
Y N
Reviewed
Y N
Y N
Y N
Comments:
bt, -
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QUANTERRA-CALLAB LABORATORY
Client Descriptions
Project #: 300681 Test: P-PAH-HR-AIR
0001SA - S-MM5-2-F,FH,XAD,COND,BH
0002SA - S-MM5-1B-F,FH,XAD,COND,BH
0003SA - T-MM5-2-F,FH,XAD,COND,BH
0004SA - T-MM5-FB-F,FH,XAD,COND,BH
0005SA - T-MM5-4-F,FH,XAD,COND,BH
0006SA - T-MM5-3-F,FH,XAD,COND,BH
0007SA - S-MM5-3-F,FH,XAD,COND,BH
0008SA - S-MM5-FB-F,FH,XAD,COND,BH
0009SA - S-MM5-RB-F,FH,XAD,COND,BH
0010SA - S-MM5-4-F,FH,XAD,COND,BH
0011SA - S-MM5-5-F,FH,XAD,COND,BH
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QUANTERRA / W. SACRAMENTO
PROJECT QC LIMITS
Pacific Environmental Services
Project: CALLAB-300681 Test Code: PAH-HR-AIR
Matrix: AIR Version: 1
QC Category: PAH-HR-AIR
QAS# RL Surrogate/SCS Lab Control (LCS) Lab Control (DCS) Matrix Spike
Modified Date:
Component CASN wns oth wns othuns othwns oth wns othwns othwns oth wns othwns othwns othwns oth wns othwns othwns othwns oth
1 * Naphthalene
2 * 2-Methylnaphthalene
3 * Acenaphthylene
4 * Acenaphthene
5 * Fluorene
6 * Phenanthrene
7 Anthracene
8 * Fluoranthene
9 * Pyrene
10 Benzo(a)anthracene
11 * Chrysene
12 * Benzo(b)f luoranthene
13 * Benzo(k)f luoranthene
14 * Benzo(e)pyrene
15 * Benzo(a)pyrene
16 * Perylene
17 Indeno(1.2,3-cd)pyrene
18 * Dibenz(a,h)anthracene
19 * Benzo(g,h,i)perylene
20 Naphthalene-da
21 * 2-Methylnaphthalene-d10
22 * Acenaphthylene-d8
23 * Acenaphthene- d10
24 * fluorene-dIO
25 * Phenanthrene-dIO
26 * Fluoranthene -did
27 * Pyrene-d10
28 * Benzo(a)anthracene-d12
29 * Chrysene-d12
30 * Benzo(b)fluoranthene-d12
31 * Benzo(k)fluor»nthene-d12
32 * Benzo(a)pyrene-d12
33 • Perylene-d12
34 * Indeno(123-cd)pyrene-d12
35 * Oibenz(a,h)anthracene-d1
36 * Benzo(gJ^.f)perylene-d12
37 * Anthrec«^-d10
38 * Terphenk-d14
91203
91576
208968
83329
86737
85018
120127
206440
129000
56553
218019
205992
207089
192972
50328
198550
193395
53703
191242
1146652
91576
93951974
15067202
81103799
1517222
93951690
1718521
1718532
1719035
93951985
93952013
63466717
1520963
-559943396
13250981
93951667
1 719068
1718510
50
50
50
*
50
50
ng
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
*
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
150
150
150
*
150
150
150
150
150
150
150
150
150
150
150
150
150
150
150
-------
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-------
1. REPORT NO.
EPA-454/R-00-025D
4. TITLE AND SUBTITLE
Final Report
Hot Mix Asphalt Plants,
Truck Loading and Silo Filling,
Manual Methods Testing,
Asphalt Plant C,
Los Angeles, California
Volume 4 of 8
TECHNICAL REPORT DATA
Please read instructions on the reverse before completing
2.
7. AUTHOR(S)
Frank J. Phoenix
9. PERFORMING ORGANIZATION NAME AND ADDRESS
Pacific Environmental Services, Inc.
Post Office Box 12077
Research Triangle Park, North Carolina 27709-2077
1 2. SPONSORING AGENCY NAME AND ADDRESS
U.S Environmental Protection Agency
Office of Air Quality Planning and Standards
Emissions, Monitoring and Analysis Division
Research Triangle Park, North Carolina 2771 1
3. RECIPIENT'S ACCESSION NO.
5. REPORT DATE
May 2000
6. PERFORMING ORGANIZATION CODE
8. PERFORMING ORGANIZATION REPORT NO.
10. PROGRAM ELEMENT NO.
11. CONTRACT/GRANT NO.
68-D-98004
13. TYPE OF REPORT AND PERIOD COVERED
Final
14. SPONSORING AGENCY CODE
EPA/200/04
15. SUPPLEMENTARY NOTES
16. ABSTRACT
The United States Environmental Protection Agency (EPA) Office of Air Quality Planning and Standards (OAQPS) is investigating hot mix
asphalt plants to identify and quantify paniculate matter (PM), methylene chloride extractable matter (MCEM), and organic hazardous air pollutant
(HAP) emissions during asphalt concrete loading operations. In support of this investigation, the OAQPS issued Pacific Environmental Services, Inc.
(PES) a series of work assignments to conduct emissions testing at a hot mix asphalt plant during load-out operations
The primary objective of the emissions testing was to characterize the uncontrolled emissions of PM, MCEM, polynuclear aromatic hydrocarbons
(PAHs), semi-volatile organic hazardous air pollutants (SVOHAPS), and volatile organic hazardous air pollutants (VOHAPS) from a box mix
production plant during loading operations. An asphalt plant south of Los Angeles, California was selected by EPA as the host facility. Testing
was performed over five consecutive days beginning on July 24, 1998. Testing was performed under two conditions. Under normal operations, testing
was performed to characterize load-out emissions from the tunnel exhaust and load-in emissions from the asphalt concrete storage silo. Under
background conditions, testing was performed to characterize emissions from the combustion of diesel fuel in transport trucks.
The entire report consists of eight volumes totaling 4,234 pages, Vol. 1 (388 pages), Vol. 2 (308 pages), Vol. 3 (573 pages), Vol. 4 (694 pages),
Vol. 5 (606 pages), Vol. 6 (564 pages), Vol. 7 (570 pages), and Vol. 8 (531 pages).
17.
a. DESCRIPTIONS
Hazardous Air Pollutants
Methylene Chloride Extractable
Matter
Particulate Matter
Polynuclear Aromatic Hydrocarbons
Semi-volatile Organic Hazardous Air
Pollutants
Volatile Organic Hazardous Air
Pollutants
18. DISTRIBUTION STATEMENT
Unlimited
KEY WORDS AND DOCUMENT ANALYSIS
b. IDENTIFIERS/OPEN ENDED TERMS
19. SECURITY CLASS (This Report)
Unclassified
20. SECURITY CLASS (This page} ,
Unclassified
c. COASTI Field/Group
21. NO. OF PAGES
Vol. 4 - 694
22. /RICE ,
EPA Form 2220-1 (Rev. 4-77) PREVIOUS EDITION IS OBSOLETE
F:\U\FMeadows\TRD.Frm\WP 6.1
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