United States
Environmental Protection
Agency
Office of Air Quality
Planning and Standards
Research Triangle Park, NC 27711
EPA-454/R-00-025F
May 2000
AIR
&EPA
Final Report
Hot Mix Asphalt Plants
Truck Loading and Silo Filling
Manual Methods Testing
Asphalt Plant C
Los Angeles, California
Volume 6 of 8
VIST***
-------
FINAL REPORT
HOT MIX ASPHALT PLANTS
TRUCK LOADING AND SILO FILLING
MANUAL METHODS TESTING
ASPHALT PLANT C, LOS ANGELES, CALIFORNIA
VOLUME 6 OF 8
APPENDIX G.3 (CONCLUDED)
EPA Contract No. 68-D-98-004
Work Assignment No. 3-02
Prepared for:
Mr. Michael L. Toney (MD-19)
Work Assignment Manager
SMTG, EMC, OAQPS
U.S. Environmental Protection Agency
Research Triangle Park, NC 27711
May 2000
Submitted by
PACIFIC ENVIRONMENTAL SERVICES, INC.
5001 S. Miami Blvd., Suite 300
Post Office Box 12077
Research Triangle Park, NC 27709-2077
(919) 941-0333
FAX (919) 941-0234
-------
DISCLAIMER
The information in this document has been funded wholly or in part by the Office of Air
Quality Planning and Standards, U.S. Environmental Protection Agency (EPA) under contract
to Pacific Environmental Services, Inc. (PES). PES performed the work presented in this
document under three EPA contracts and seven Work Assignments; EPA Contract No. 68-D-
98-004, Work Assignment Nos. 1-08,2-07, 3-02, and 3-05, EPA Contract No. 68-D-70002,
Work Assignment Nos. 0-05 and 1-07, and EPA Contract No. 68-D-70069, Work Assignment
No. 2-16. This document has been prepared by PES, reviewed following PES' internal
quality assurance procedures, and approved by PES for distribution. This document has been
subjected to the Agency's review, and has been approved by EPA for publication as an EPA
document. Mention of trade names does not constitute endorsement by the EPA or PES.
11
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TABLE OF CONTENTS
VOLUME 1
1.0 INTRODUCTION 1-1
2.0 SUMMARY OF TEST RESULTS 2-1
2.1 OVERVIEW 2-1
2.2 TREATMENT OF NON-DETECTS AND ESTIMATES 2-2
2.3 TUNNEL EXHAUST DUCT 2-2
2.4 SILO EXHAUST DUCT RESULTS 2-12
2.5 PM AND MCEM DEPOSITION ESTIMATES 2-15
2.6 METEOROLOGICAL STATION RESULTS 2-15
3.0 PROCESS DESCRIPTION 3-1
3.1 COORDINATION BETWEEN TESTING AND PROCESS
OPERATIONS 3-3
3.2 PROCESS MONITORING DURING TESTING 3-3
3.3 PROCESS SAMPLES 3-4
3.4 VELOCITY OF AIR ACROSS TOP OF TRANSPORT TRUCKS
DURING LOAD-OUT 3-5
4.0 SAMPLING LOCATIONS 4-1
4.1 TUNNEL EXHAUST DUCT 4-1
4.2 SILO EXHAUST DUCT 4-1
5.0 SAMPLING AND ANALYTICAL PROCEDURES 5-1
5.1 LOCATION OF MEASUREMENT SITES AND
SAMPLE/VELOCITY TRAVERSE POINTS 5-1
5.2 DETERMINATION OF EXHAUST GAS VOLUMETRIC
FLOW RATE 5-1
5.3 DETERMINATION OF EXHAUST GAS DRY MOLECULAR
WEIGHT 5-3
5.4 DETERMINATION OF EXHAUST GAS MOISTURE CONTENT 5-3
in
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TABLE OF CONTENTS (CONTINUED)
VOLUME 1 rCONTINUED^ Page
5.5 DETERMINATION OF PM AND MCEM 5-3
5.6 DETERMINATION OF VOHAPs 5-3
5.7 DETERMINATION OF SVOHAPs 5-7
5.8 DETERMINATION OF WIND SPEED, WIND DIRECTION,
AMBIENT TEMPERATURE, AND AMBIENT HUMIDITY 5-7
5.9 ESTIMATE OF PM AND MCEM ON THE CEILING
OF THE LOAD-OUT TUNNEL DOWNSTREAM OF SILO NO. 5 5-7
5.10 ESTIMATE OF PM AND MCEM DEPOSITION ON THE INSIDE
WALLS OF THE SILO NO. 2 EXHAUST PLENUM 5-9
5.11 ESTIMATE OF PM AND MCEM DEPOSITION ON THE INSIDE
WALLS OF THE SILO EXHAUST DUCT 5-9
5.12 ESTIMATE OF PM AND MCEM DEPOSITION ON THE INSIDE
WALLS OF THE TUNNEL EXHAUST DUCT 5-10
6.0 QUALITY ASSURANCE/QUALITY CONTROL (QA/QC) PROCEDURES
AND RESULTS 6-1
6.1 CALIBRATION AND PREPARATION OF APPARATUS 6-1
6.2 REAGENTS AND GLASSWARE PREPARATION 6-2
6.3 ON-SITE SAMPLING 6-3
6.4 SAMPLE RECOVERY 6-4
6.5 LABORATORY ANALYTICAL QA/QC PROCEDURES 6-5
6.6 QA COORDINATOR FIELD AUDIT 6-7
APPENDIX A - TEST RESULTS AND CALCULATIONS 1
A.1 TED TEST RESULTS 3
A.2 SED TEST RESULTS 101
A.3 EXAMPLE CALCULATIONS 195
A.4 PARTICIPATE DEPOSITION DATA 204
A.5 CAPTURE EFFICIENCY CALCULATIONS 211
VOLUME 2
APPENDIX B - PROCESS DATA 1
B. 1 PRODUCTION RECORDS FOR 7/24/98 THROUGH 7/28/98 3
B.2 PRODUCT STORAGE RECORDS FOR 7/25/98 THROUGH 7/28/98 9
IV
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TABLE OF CONTENTS (CONTINUED)
VOLUME 2 rCQNTINUED^
APPENDIX B - PROCESS DATA (CONTINUED)
B.3 LOAD-OUT RECORDS USED IN TED EMISSION CALCULATIONS . . 19
B.4 LOAD-OUT RECORDS FOR 6/18/98 THROUGH 7/26/98 33
B.5 LOAD-OUT RECORDS FOR 7/24/98 THROUGH 7/28/98 44
B.6 SILO NO. 2 LOAD-IN RECORDS USED IN SED EMISSION
CALCULATIONS 68
B.7 ASPHALT TEMPERATURES AT LOAD-OUT 90
B.8 MASS CHANGE RESULTS FROM ASTM TESTS PERFORMED ON
ASPHALT CEMENT SAMPLES 93
B.9 VELOCITY OF AIR ACROSS TOP OF TRANSPORT TRUCKS
DURING LOAD-OUT 100
B.10 METALS ANALYSIS OF PROCESS SAMPLES 104
VOLUME 3
APPENDIX C - FIELD DATA 1
C.I TED FIELD DATA 2
C.2 SED FIELD DATA 59
C.3 METEOROLOGICAL STATION DATA 89
C.4 ON-SITE GC/MS REPORT AND DATA 118
APPENDIX D - QA/QC DATA 230
APPENDIX E - PROJECT PARTICIPANTS 280
APPENDIX F - TEST METHODS
F.I EPA METHOD 1
F.2 EPA METHOD 1A
F.3 EPA METHOD 2
F.4 EPA METHOD 4
F.5 EPA METHOD 18
F.6 EPA METHOD 315
F. 7 SW-846 METHOD 0010
F.8 SW-846 METHOD 0030
-------
TABLE OF CONTENTS (CONCLUDED)
VOLUME 4
APPENDIX G - ANALYTICAL DATA 1
G.I PM AND MCEMDATA la
G.2 PAH/SVOHAPS CASE NARRATIVE AND PAH DATA Ik
VOLUMES
APPENDIX G - ANALYTICAL DATA (CONTINUED) 659
G.3 SVOHAPS DATA 659
VOLUME 6
APPENDIX G - ANALYTICAL DATA (CONTINUED) 1248
G.3 SVOHAPS DATA (CONCLUDED) 1248
VOLUME?
APPENDIX G - ANALYTICAL DATA (CONTINUED) la
G.4 VOHAPS DATA lc
VOLUMES
APPENDIX G - ANALYTICAL DATA (CONCLUDED) la
G.4 VOHAPS DATA (CONCLUDED) lc
G.5 EPA METHOD 18 REPORT AND DATA 260
VI
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LIST OF TABLES
Page
Table 1.1 Test Log Tunnel Exhaust Duct, Asphalt Plant C - California 1-4
Table 1.2 Test Log Silo Exhaust Duct, Asphalt Plant C - California 1-5
Table 2.1 Summary of Results, Production Emissions for PM, MCEM, PAH,
SVOHAP and VOHAP, Asphalt Plant C, California - July 1998 2-3
Table 2.2 Summary of Results, Average PM and MCEM Emissions,
Asphalt Plant C, California - July 1998 2-4
Table 2.3 Summary of Results, Average PAH and SVOHAP Emissions,
Asphalt Plant C, California - July 1998 2-5
Table 2.4 Summary of Results, Average VOHAP Emissions,
Asphalt Plant C, California - July 1998 2-6
Table 2.5 Summary of Results, PAHS, SVOHAPS, & VOHAPS Average
Emissions, Silo Exhaust Duct - Asphalt Plant C, California, July 1998 2-7
Table 2.6 PM and MCEM Emissions Sampling and Exhaust Gas Parameters
Normal Operations, Tunnel Exhaust Duct, Asphalt Plant C - California . . 2-16
Table 2.7 PM and MCEM Exhaust Gas Concentrations and Emission Rates, Normal
Operations, Tunnel Exhaust Duct, Asphalt Plant C - California 2-17
Table 2.8 PAHs and Semi-Volatile Organics Emissions Sampling and
Exhaust Gas Parameters, Normal Operations, Tunnel Exhaust Duct,
Asphalt Plant C - California 2-18
Table 2.9 PAHs Exhaust Gas Concentrations and Emission Rates, Normal
Operations Tunnel Exhaust Duct, Asphalt Plant C - California 2-19
Table 2,10 Semi-Volatile Organics Exhaust Gas Concentrations and Emission Rates,
Normal Operations, Tunnel Exhaust Duct, Asphalt Plant C - California . . 2-21
Table 2.11 Volatile Organics - SW-846 Method 0030 Emissions Sampling and
Exhaust Gas Parameters, Normal Operations, Tunnel Exhaust Duct,
Asphalt Plant C - California 2-30
Table 2.12 Volatile Organics - SW-846 Method 0030 Exhaust Gas Concentrations
and Emission Rates, Normal Operation, Tunnel Exhaust Duct,
Asphalt Plant C - California 2-31
Table 2.13 Volatile Organics - EPA Method 18 Emissions Sampling and
Exhaust Gas Parameters, Normal Operations, Tunnel Exhaust Duct,
Asphalt Plant C - California 2-36
Table 2.14 Volatile Organics - EPA Method 18 Exhaust Gas Concentrations
and Emission Rates, Normal Operations, Tunnel Exhaust Duct,
Asphalt Plant C - California , 2-37
Table 2.15 On-Site GC/MS Volatile Organics Exhaust Gas Concentrations and
Emission Rates with Vost (SW-846 Method 0030) and EPA Method 18
Comparison, Tunnel Exhaust Duct, Asphalt Plant C - California 7/24/98 . 2-38
Table 2.16 PM and MCEM Emissions Sampling and Exhaust Gas Parameters,
Background Condition, Tunnel Exhaust Duct, Asphalt Plant C - California 2-39
Vll
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LIST OF TABLES (CONTINUED)
Page
Table 2.17 PM and MCEM Exhaust Gas Concentrations and Emission Rates,
Background Condition, Tunnel Exhaust Duct, Asphalt Plant C - California 2-40
Table 2.18 PAHs and Semi-Volatile Organics Emissions Sampling and Exhaust Gas
Parameters Background Condition, Tunnel Exhaust Duct,
Asphalt Plant C - California 2-41
Table 2.19 PAHs Exhaust Gas Concentrations and Emission Rates, Background
Condition, Tunnel Exhaust Duct, Asphalt Plant C - California 2-42
Table 2.20 Semi-Volatile Organics Exhaust Gas Concentrations and Emission Rates,
Background Condition, Tunnel Exhaust Duct, Asphalt
Plant C - California 2-44
Table 2.21 Volatile Organics - SW-846 Method 0030 Emissions Sampling and
Exhaust Gas Parameters, Background Condition, Tunnel Exhaust Duct,
Asphalt Plant C - California 2-53
Table 2.22 Volatile Organics - SW-846 Method 0030 Exhaust Gas Concentrations
and Emission Rates, Background Condition, Tunnel Exhaust Duct,
Asphalt Plant C - California 2-54
Table 2.23 Volatile Organics - EPA Method 18 Emissions Sampling and Exhaust Gas
Parameters, Background Condition, Tunnel Exhaust Duct, Asphalt
Plant C - California 2-59
Table 2.24 Volatile Organics - EPA Method 18 Exhaust Gas Concentrations and
Emission Rates, Background Condition, Tunnel Exhaust Duct,
Asphalt Plant C - California 2-60
Table 2.25 Sample Log Silo Exhaust Duct, Asphalt Plant C - California 2-61
Table 2.26 PM and MCEM Emissions Sampling and Exhaust Gas Parameters,
Silo Exhaust Duct, Asphalt Plant C - California 2-62
Table 2.27 PM and MCEM Exhaust Gas Concentrations and Emission Rates,
Silo Exhaust Duct, Asphalt Plant C - California 2-63
Table 2.28 PAHs and Semi-Volatile Organics Emissions Sampling and Exhaust Gas
Parameters, Silo Exhaust Duct, Asphalt Plant C - California 2-64
Table 2.29 PAHs Exhaust Gas Concentrations and Emission Rates, Silo Exhaust Duct,
Asphalt Plant C - California 2-65
Table 2.30 Semi-Volatile Organics Exhaust Gas Concentrations and Emission Rates,
Silo Exhaust Duct, Asphalt Plant C - California 2-67
Table 2.31 Volatile Organics - SW-846 Method 0030 Emissions Sampling and
Exhaust Gas Parameters, Silo Exhaust Duct, Asphalt Plant C - California . 2-76
Table 2.32 Volatile Organics - SW-846 Method 0030 Exhaust Gas Concentrations
and Emission Rates, Silo Exhaust Duct, Asphalt Plant C - California .... 2-77
Table 2.33 On-Site GC/MS Volatile Organics Exhaust Gas Concentrations and
Emission Rates with Vost (SW-846 Method 0030) Comparison,
Silo Exhaust Duct, Asphalt Plant C - California 7/25/98 2-82
Table 2.34 PM and MCEM Deposition Estimates, Asphalt Plant C - California 2-83
viii
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LIST OF TABLES (CONCLUDED)
Page
Table 2.35 Meteorological Data Summary, Asphalt Plant C - California 2-84
Table 3.1 Load-out Data Used in TED Emission Calculations 3-6
Table 3.2 Load-in Data for Silo No. 2 Used in SED Emission Calculations 3-7
Table 3.3 Asphalt Temperatures at Load-out, Asphalt Plant C, California 3-8
Table 3.4 Mass Change of Asphalt, Asphalt Plant C, California 3-9
Table 3.5 Results of Metals Analyses of Asphalt Samples, Asphalt Plant C,
California 3-10
Table 3.6 Air Velocity Over Transport Trucks During Load-out, Asphalt Plant C,
California 3-11
Table 5.1 Summary of Sampling and Analytical Methods, Asphalt Plant C,
California 5-2
Table 6.1 Summary of Temperature Sensor Calibration Data 6-8
Table 6.2 Summary of Pitot Tube Dimensional Data 6-9
Table 6.3 Summary of Dry Gas Meter and Orifice Calibration Data 6-10
Table 6.4 Summary of EPA Method 315 and SW-846 Method 0010
Field Sampling QA/QC Data 6-11
Table 6.5 Summary of EPA Method 315 Blank Sample Catches 6-12
Table 6.6 SW-846 Method 0010 PAHs Field and Laboratory Blanks Results,
Tunnel Exhaust Duct 6-13
Table 6.7 SW-846 Method 0010 PAHs Field and Laboratory Blanks Results,
Silo Exhaust Duct 6-14
Table 6.8 SW-846 Method 0010 PAHs Surrogate Recovery Results,
Tunnel Exhaust Duct 6-15
Table 6.9 SW-846 Method 0010 Semi-Volatile Surrogate Recovery Results
Tunnel Exhaust Duct 6-16
Table 6.10 SW-846 Method 0010 PAHs Surrogate Recovery Results,
Silo Exhaust Duct 6-17
Table 6.11 SW-846 Method 0010 Semi-Volatile Surrogate Recovery Results
Silo Exhaust Duct 6-18
Table 6.12 SW-846 Method 0030 Field and Laboratory Blanks Results
Tunnel Exhaust Duct 6-19
Table 6.13 SW-846 Method 0030 Laboratory Blank Results, Silo Exhaust Duct 6-20
Table 6.14 SW-846 Method 0030 Surrogate Recovery Results
Tunnel Exhaust Duct 6-21
Table 6.15 SW-846 Method 0030 Surrogate Recovery Results
Silo Exhaust Duct 6-22
IX
-------
LIST OF FIGURES
Page
Figure 1.1 Project Organization - US EPA Hot Mix Asphalt Load-out Operation,
Asphalt Plant C, California 1-6
Figure 2.1 Load-out Tunnel and MET Station Location and Average Wind Direction 2-85
Figure 3.1 Process Flow Schematic, Asphalt Plant C, California 3-2
Figure 3.2 Velocity Measurement Locations and Dimensions of Transport Trucks ... 3-12
Figure 4.1 Tunnel Exhaust Duct Sampling Locations, Asphalt Plant C, California .... 4-2
Figure 4.2 Tunnel Exhaust Duct Traverse Point Locations,
Asphalt Plant C, California 4-3
Figure 4.3 Silo Exhaust Duct Sampling Locations, Asphalt Plant C, California 4-4
Figure 4.4 Silo Exhaust Duct Traverse Point Locations, Asphalt Plant C, California . . 4-5
Figure 5.1 EPA Method 315 Sampling Train Schematic 5-4
Figure 5.2 SW-846 Method 0030 Sampling Train Schematic 5-6
Figure 5.3 SW-846 Method 0010 Sampling Train Schematic 5-8
Figure 5.4 Location of TED Deposition Test Plates Tt, T2, and T3 5-11
GLOSSARY OF TERMS
ASTM - American Society for Testing and Materials
CEMS - Continuous Emissions Monitoring System
CTS - Calibration Transfer Standard
EMC - Emissions Measurement Center
EMAD - Emission Monitoring and Analysis Division
ESP - Electrostatic Precipitator
FID - Flame lonization Detector
FTIR - Fourier Transform Infrared Spectroscopy
HAP - Hazardous Air Pollutant
MCEM - Methylene Chloride Extractable Matter
MRJ - Midwest Research Institute
PES - Pacific Environmental Services
PM - Paniculate Matter
PTE - Permanent Total Enclosure
RAP - Recycled Asphalt
RTFOT - Rolling Thin Film Oven Test
SED - Silo Exhaust Duct
-------
GLOSSARY OF TERMS (CONTINUED)
SMTG - Source Measurement Technology Group
SVOHAP - Semi-Volatile Organic Hazardous Air Pollutant
TED - Tunnel Emissions Duct
TFOT - Thin Film Oven Test
THC - Total Hydrocarbons
VOHAP - Volatile Organic Hazardous Air Pollutant
VOST - Volatile Organic Sampling Train
XI
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VOLUME 5B
APPENDIX G
ANALYTICAL DATA (CONTINUED)
G.3 SVOHAPS DATA (CONCLUDED)
-------
Semivolatile Organics
Method 0010/8270
Client Name: Pacific Environmental Services
Client ID: S-MM5-RB-F,FH,XAD,COND,BH
LAB ID: 300681-0009-SA
Matrix: AIRTRAIN Sampled:
Authorized: 30 JUL 98 Prepared:
Dilution Factor: 1.0
Parameter
Phenol
bis(2-Chloroethyl)ether
2-Chlorophenol
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Benzyl alcohol
1,2-Dichlorobenzene
2-Methylphenol
2,2'-Oxybis(l-chloropropane)
3/4-Methylphenol
N-Nitroso-di-n-propylamine
Hexachloroethane
Nitrobenzene
Isophorone
2-Nitrophenol
2,4-Dimethylphenol
Benzoic acid
bi s(2-Chloroethoxy)-methane
2,4-Dichlorophfinol
1,2,4-Trichlorobenzene
Naphthalene
4-Chloroaniline
Hexachlorobutadi ene
4-Chloro-3-methyl phenol
2-Methylnaphtha! ene
Hexachlorocyclopentadi ene
2,4,6-Trichlorophenol
2,4,5-Trichlorophenol
2-Chloronaphthalene
2-Nitroaniline
Dimethyl phthalate
Acenaphthylene
3-Nitroaniline
Acenaphthene
2,4-Dinitrophenol
4-Nitrophenol
Dibenzofuran
Wet wt.
Result
25 JUL 98
31 JUL 98
Units
Received: 30 JUL 98
Analyzed: 31 AUG 98
Reporting
Limit
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
30 '
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
150
30
30
30
30
30
30
30
30
30
30
150
30
30
30
30
150
30
150
150
30
Qualifier
R
Note R = Reporting limit(s) raised due to sample volume limitations.
ND = Not Detected
Reported By: Emily Uebelhoer
Approved By: Karin Yee
The cover letter is an integral part of this report.
Rev 230787
.2-13
-------
Semi volatile Organics
Method 0010/8270
Client Name: Pacific Environmental Services
Client ID: S-MM5-RB-F,FH,XAD,COND,BH
LAB ID: 300681-0009-SA
Matrix: AIRTRAIN Sampled: 25 JUL 98
Authorized: 30 JUL 98 Prepared: 31 JUL 98
(cont,
Dilution Factor: 1.0
Parameter
2,4-Dinitrotoluene
2,6-Dinitrotoluene
Diethyl phthalate
4-Chlorophenyl phenyl ether
Fluorene
4-Nitroaniline
4,6-Dinitro-2-methylphenol
N-Nitrosodiphenylamine
4-Bromophenyl phenyl ether
Hexachlorobenzene
Pentachlorophenol
Phenanthrene
Anthracene
Di-n-butyl phthalate
Fluoranthene
Pyrene
Butyl benzyl phthalate
3,3'-Dichlorobenzidine
Benzo(a)anthracene
bis(2-Ethylhexyl)-phthalate
Chrysene
Di-n-octyl phthalate
Benzofb fluoranthene
Benzolk fluoranthene
Benzo(a pyrene
Indenof ,2,3-cd)pyrene
Dibenz(a,h)anthracene
Benzo(g,h,i)perylene
Acetopnenone
4-Aminobiphenyl
Aniline
Benzidine
3,3'-Dimethylbenzidine
N-Nitrosodimethylamine
N-Nitrosomorphol ine
Pentachloronitrobenzene (PCNB)
o-Toluidine
Wet wt.
Result
Units
Received: 30 JUL 98
Analyzed: 31 AUG 98
Reporting
Limit
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ug/Sampl e
ug/Sample
ug/Sampl e
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sampl e
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
30
30
30
30
30
150
150
30
30
30
150
30
30
30
30
30
30
60
30
30
30
30
30
30
30
30
30
30
30
150
30
300
60
30
30
150
60
Qualifier
ND = Not Detected
Reported By: Emily Uebelhoer
Approved By: Karin Yee
The cover letter is an integral part of this report.
Rev 230787
1 p /* •
JL A.> 'i. '
-------
Semivolatile Organics
Method 0010/8270
(cont.)
Client Name:
Client ID:
LAB ID:
Matrix:
Authorized:
Pacific Environmental Services
S-MM5-RB-F,FH,XAD,COND,BH
300681-0009-SA
AIRTRAIN Sampled:
30 JUL 98 Prepared:
25 OUL 98
31 JUL 98
Dilution Factor: 1.0
Wet wt.
Parameter Result Units
2-Methoxybenzenamine ND ug/Sample
Biphenyl ND ug/Sample
Chloroacetophenone ND ug/Sample
Cumene ND ug/Sample
DBCP (l,2-Dibromo-3-chloropropane) ND ug/Sample
Benzo(e)pyrene ND ug/Sample
N-N-Diethyl aniline ND ug/Sample
Dimethylani1ine ND ug/Sample
3,3'-Dimethoxybenzidine ND ug/Sample
Hydroquinone ND ug/Sample
4,4'-Methyl-bis(2-chloroaniline) ND ug/Sample
4-Nitrodiphenyl ND ug/Sample
Trifluralin ND ug/Sample
Received: 30 JUL 98
Analyzed: 31 AUG 98
Reporting
Limit
Qualifier
K
K
K
K
K
K
K
K
K
K
K
K
K
Surrogate
Nitrobenzene-d5
2-Fluorobiphenyl
Terphenyl-dl4
Phenol-d5
2-Fluorophenol
2,4,6-Tribromophenol
Recovery
61 %
86 %
97 %
67 %
62 %
84 %
Acceptable Range
45 - 107
62 - 110
58 - 135
43 - 130
36 - 111
58 - 131
Note K = Identified by mass spectrum only; quantitation based on 1:1 response with
internal standard.
ND = Not Detected
Reported By: Emily Uebelhoer
Approved By: Karin Yee
The cover letter is an integral part of this report.
Rev 230787
125C
-------
Semivolatiles
Library Search
Method 8270
(20 Compound TID)
Client Name: Pacific Environmental Services
Client ID: S-MM5-RB-F,FH,XAD,COND,BH
LAB ID: 300681-0009-SA
Matrix: AIRTRAIN Sampled: 25 JUL 98
Authorized: 30 JUL 98 Prepared: NA
Dilution Factor: 1.0
Parameter
n-Nonane
Unknown
Unknown
Unknown
Unknown
Unknown
Unknown
5-Eiconsene,(E) -
Unknown
Unknown
Unknown alkane
Unknown
Unknown
4-Hydroxy-4-methyl-2-pentanone
Unknown
Unknown
Unknown
9-Eicosene (£)-
Unknown
Unknown
Result
400
51
77
71
42
63
99
250
94
63
27
35
140
270
110
81
26
57
61
72
Units
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
Received: 30 JUL 98
Analyzed: 31 AUG 98
Reporting
Limit
Qualifier
0
0
0
Note 0 = Or structurally similar compound (isomer).
NA = Not Applicable
Reported By: Emily Uebelhoer
Approved By: Karin Yee
The cover letter is an integral part of this report.
Rev 230787
-------
Sample: S-MM5-RB
Client: PACIFI
Analyst: DAT
QUANTERRA GC/HS
Target Compound Data Summary Sheet
1/3SA/1ML
Instrument ID: F16
Quan List Threshold: 0.95
Data File: 30068109
Std Id: ST 16980831
INST. ID: F16
Date Analyzed: 08/31/98 22:58
Run Factor: 3.00
Surrogate Vol.:
1.00
Surrogate
Surrogate Spike Recoveries
8270-G, LIMS 10/10/96
Surrogate Amount (ug)
Spiked Measured
CS20 NITROBENZENE-05 50.00 30.60
CS25 2-FLUOROBIPHENY 50.00 43.00
CS30 TERPHENYL-D14 50.00 48.60
CS45 PHENOL-D5 100.0 66.90
CS50 2-FLUOROPHENOL 100.0 62.40
CS55 2,4,6-TRIBROMOP 100.0 84.30
X Recovery
Measured QC limits
61.2
86.0
97.2
66.9
62.4
84.3
45 107
62 110
58 135
43 130
36 111
58 131
Target Compounds: SAP9
Parameter Scan Result Units
HEXACHLOROBENZENE-C13
C310 N-NITROSOD1METHYLAMINE
PYR1DINE
2-PICOLINE
N-NITROSOMETHYLETHYLAMINE
METHYLMETHANESULFONATE
N-NITROSODIETHYLAMINE
ETHYLMETHANE SULFONATE
PENTACHLOROETHANE
C320 ANILINE
C315 PHENOL
C325 BIS(2-CHLOROETHYL)ETHER
C330 2-CHLOROPHENOL
C335 1,3-D1CHLOROBENZENE
C340 1,4-DICHLOROBENZENE
C345 BENZYL ALCOHOL
C350 1,2-DICHLOROBENZENE
C355 2-METHYLPHENOL
C360 2,2'-OXYBIS(1-CLPROPAN)
C361 ACETOPHENONE
N-NITROSOPYRROLIDINE
N-NITROSOMORPHOLINE
3-METHYL PHENOL
C365 4-METHYLPHENOL
C370 N-NITROSO-DI-N-PROPYLAM
0-TOLUIDINE
C375 HEXACHLOROETHANE
C410 NITROBENZENE
N-NITROSOPIPERIDINE
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
Reporting
Limit
30.0
30.0
60.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0 /
Reviewed by:
10 r f*
f^^fL
-------
OUANTERRA GC/MS
Target Compound Data Summary Sheet
Data File: 30068109
Std Id: ST16980831
Sample: S-MM5-RB
Client: PACIFI
Analyst: DAT
1/3SA/1ML
INST. ID: F16
Instrument ID: F16
Date Analyzed: 08/31/98 22:58
Run Factor: 3.00
Quan List Threshold: 0.95
Surrogate Vol.:
1.00
Target Compounds: SAP9
Parameter Scan
C415 ISOPHORONE
C420 2-NITROPHENOL
C425 2,4-DIMETHYLPHENOL
C435 BIS(2-CHLOROETHOXY)METH
C440 2,4-DICHLOROPHENOL
C430 BENZOIC ACID
AA-DIMETHYLPHENETHYLAMINE
C445 1,2,4-TRICHLOROBENZENE
C450 NAPHTHALENE
C455 4-CHLOROANALINE
2,6-DICHLOROPHENOL
HEXACHLOROPROPENE
C460 HEXACHLOROBUTAD1ENE
P-PHENYLENE DIAM1NE
N-NITROSOD1-N-BUTYLAMINE
C465 4-CHLORO-3-METHYLPHENO
SAFROLE
C470 2-METHYLNAPHTHALENE
1,2,4,5-TETRACHLOROBENZENE
1SOSAFROLE (#1)
C510 HEXACHLOROCYCLOPENTADI
C515 2,4,6-TRICHLOROPHENOL
C520 2,4,5-TRICHLOROPHENOL
ISOSAFROLE (#2)
C525 2-CHLORONAPHTHALENE
1-CHLORONAPHTHALENE
C530 2-NITROANALINE
1,4-NAPHTHOQUINONE
C535 DIMETHYLPHTHALATE
1,3-DIN1TROBENZENE
C540 ACENAPHTHYLENE
C543 2,6-DINITROTOLUENE
C545 3-NITROANILINE
C550 ACENAPHTHENE
C555 2,4-DINITROPHENOL
C565 DIBENZOFURAN
C560 4-NITROPHENOL
PENTACHLOROBENZENE
C570 2,4-DINITROTOLUENE
1-NAPHTHYLAMINE
2-NAPHTHYLAMINE
2,3,4,6-TETRACHLOROPHENOL
C580 D1ETHYLPHTHALATE
C590 FLUORENE
Result
Units
Reporting
Limit
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
30.0
30.0
30.0
30.0
30.0
150.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
60.0
30.0
30.0
30.0
60.0
30.0
15.0
150.0
30.0
30.0
30.0
30.0
30.0
150.0
30.0
150.0
30.0
150.0
30.0
30.0
30.0
30.0
60.0
30.0
30.0
-------
OUANTERRA GC/MS
Target Compound Data Summary Sheet
Data File: 30068109
Std Id: ST16980831
Sample: S-MM5-RB 1/3SA/1ML INST. ID: F16
Client: PACIFI Date Analyzed: 08/31/98 22:58
Analyst: DAT Instrument ID: F16 Run Factor: 3.00
Quan List Threshold: 0.95 Surrogate Vol.: 1.00
Parameter
Target Compounds: SAP9
Reporting
Scan Result Units Limit
C585 4-CHLOROPHENYL-PHENYLE
5-NITRO-O-TOLUIDINE
C595 4-NITROANALINE
C610 4.6-DINITRO-2-METHYLPH
C615 N-NITROSODIPHENYLAMINE
C620 AZOBENZENE
SYM-TRINITROBENZENE
C625 4-BROMOPHENYL-PHENYLET
PHENACETIN
DIALLATE 234
C630 HEXACHLOROBENZENE
4-AM1NOBIPHENYL
C635 PENTACHLOROPHENOL
PRONAMIDE
PENTACHLORONITROBENZENE
C640 PHENANTHRENE
C645 ANTHRACENE
2SECBUTYL-4.6-D1NITROPHENOL
C647 CARBAZOLE
C650 DI-N-BUTYLPHTHALATE
4-NITROQUINOLINE-1-OXIDE
METHAPYR1LENE
1SOOR1N
C655 FLUORANTHENE
CHLOROBENZ1LATE
C710 BENZIDINE
C715 PYRENE
ARAMITE (#1)
ARAMITE (#2)
P-DIMETHYLAMINOAZOBENZENE
3,3'-OIMETHYLBEN2IDINE
KEPONE
C720 BUTYLBENZYLPHTHALATE
2-ACETYLAMINOFLUORENE
C730 BENZO(A)ANTHRACENE
C725 3,3'-DICHLOROBENZIDINE
C740 CHRYSENE
C745 BIS(2-ETHYLHEXYL)PHTHA
3-METHYLCHOLANTHRENE
C760 DI-N-OCTYL PHTHALATE
C765 BENZO(B) FLUORANTHENE
7, 12-DIMETHYLBENZANTHRACENE
C770 BENZOdOFLUORANTHENE
HEXACHLOROPHENE
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
30.0
30.0
150.0
150.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
150.0
30.0
150.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
300.0
30.0
30.0
30.0
30.0
30.0
150.0
30.0
30.0
30.0
60.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
12
-------
Sample: S-MM5-RB
Client: PACIF1
Analyst: DAT
QUANTERRA GC/MS
Target Compound Data Summary Sheet
Data File: 30068109
Std Id: ST16980831
1/3SA/1ML INST. ID: F16
Date Analyzed: 08/31/98 22:58
Instrument ID: F16 Run Factor: 3.00
Quan List Threshold: 0.95
Surrogate Vol.:
1.00
Parameter
Target Compounds: SAP9
Scan Result Units
Reporting
Limit
C775 BENZO(A)PYRENE
C780 INDENO(1,2,3-CD)PYRENE
C785 DIBENZ(A,H)ANTHRACENE
C790 BENZO(G,H,I)PERYLENE
ND
ND
ND
ND
UG/A
UG/A
UG/A
UG/A
30.0
30.0
30.0
30.0
-------
DATA FROM FILE: 30068109 SCANS 93 TO 1203 ACQUIRED: 08/31/98 22:58:00
CALI: 30068109 #3
SAMPLE: S-MM5-RB 1/3SA/1ML INST. ID: F16
CONDS.: UG/ML *1ML *100Z/100Z *
-------
DATA FROM FILE: 30068109
SCANS 1203 TO 2158 ACQUIRED: 08/31/98 22:58:60
CALI: 30068109 #3
SAMPLE: S-MM5-RB 1/3SA/1ML INST. ID: F16
CONDS.: UG/ML *1ML *100£/100Z *
-------
STANDARD USED FOR THIS REPORT IS ST16980831 REPORT PRINTED: 9/01/98 23:44:29
ADDITIONAL STANDARD USED FOR THIS REPORT IS: ST16980831A
QUANTERRA QUANTITATION SUMMARY File: 30068109
Sample: S-MM5-RB 1/3SA/1ML INST. ID: F16
Analyst: DAT Instrument Id: F16 Analyzed: 08/31/98 22:58
Compounds with amounts less than 0.20 reported as NOT FOUND
No
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
Library
Entry
S1# 1
S2# 1
S3# 1
S4# 1
S5# 1
S6# 1
S2# 2
S3# 3
S5# 2
S1# 3
SI* 2
S3# 2
S4# 4
S1# 15
S1# 20
S1# 30
S1# 40
S1# 60
S1# 70
S1# 85
S1# 95
S1#100
S1#105
S1#110
S1#115
S1#125
S1#130
S1#145
S1#150
SDK160
S1#165
S1#170
S1#175
S1#180
S1#182
S1#185
S1#190
S1#195
S1#200
S2# 10
S2# 15
S2# 20
S2# 25
S2# 30
S2# 35
Units: UG/K
Name Mass
CI30 1,4-DICHLOROBENZENE
CI40 NAPHTHALENE-08
CI50 ACENAPHTHENE-D10
CI60 PHENANTHRENE-D10
CI70 CHRYSENE-D12
CI75 PERYLENE-D12
CS20 NITROBENZENE-05
CS25 2-FLUOROBIPHENYL
CS30 TERPHENYL-D14
CS45 PHENOL-D5
CS50 2-FLUOROPHENOL
CS55 2,4,6-TRIBROMOPHENO
HEXACHLOROBENZENE-C13
C310 N-NITROSOOIMETHYLAM
PYRIDINE
2-PICOLINE
N-NITROSOMETHYLETHYLAMIN
METHYLMETHANESULFONATE
N-NITROSOD1ETHYLAMINE
ETHYLMETHANE SULFONATE
PENTACHLOROETHANE
C320 ANILINE
C315 PHENOL
C325 BIS(2-CHLOROETHYL)E
C330 2-CHLOROPHENOL
C335 1,3-DICHLOROBENZENE
C340 1,4-DICHLOROBENZENE
C345 BENZYL ALCOHOL
C350 1,2-DICHLOROBENZENE
C355 2-METHYLPHENOL
C360 2,2'-OXYBIS(1-CLPRO
C361 ACETOPHENONE
N-NITROSOPYRROLIDINE
N-NITROSOMORPHOLINE
3-METHYL PHENOL
C365 4-METHYLPHENOL
C370 N-NITROSO-DI-N-PROP
0-TOLUIDINE
C375 HEXACHLOROETHANE
C410 NITROBENZENE
N-NITROSOPIPERIDINE
C415 ISOPHORONE
C420 2-NITROPHENOL
C425 2.4-DIMETHYLPHENOL
C435 BIS(2-CHLOROETHOXY)
152
136
164
188
240
264
82
172
244
99
112
330
294
74
79
93
42
80
102
79
117
93
94
93
128
146
146
108
146
108
45
105
100
56
108
108
70
106
117
77
42
82
139
107
93
Meth
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
BB
BB
BB
BB
BB
BB
BB
BB
BB
BB
BB
BB
BB
VB
BB
BB
BB
Scan
340
529
827
1085
1551
1782
421
722
1383
308
198
968
4
1
1
146
159
1
1
1
1
1
309
1
1
1
1
372
1
1
1
1
1
1
421
1
1
1
1
2
2
2
2
2
2
Ref
1
2
3
4
5
6
2
3
5
1
1
3
NOT
NOT
NOT
1
1
NOT
NOT
NOT
NOT
NOT
1
NOT
NOT
NOT
NOT
1
NOT
NOT
NOT
NOT
NOT
NOT
1
NOT
NOT
NOT
NOT
NOT
NOT
NOT
NOT
NOT
NOT
Area
36331 .
137829.
74485.
122676.
71172.
56685.
49520.
98741.
86030.
123023.
77514.
36995.
FOUND
FOUND
FOUND
449.
4136.
FOUND
FOUND
FOUND
FOUND
FOUND
486.
FOUND
FOUND
FOUND
FOUND
2329.
FOUND
FOUND
FOUND
FOUND
FOUND
FOUND
568.
FOUND
FOUND
FOUND
FOUND
FOUND
FOUND
FOUND
FOUND
FOUND
FOUND
RRF(L)
1.000
1.000
1.000
1.000
1.000
1.000
0.470
1.234
0.995
2.025
1.368
0.236
1.565
0.811
1.968
0.854
2.252
Ai
40
40
40
40
40
40
30
42
48
66
62
84
0
5
0
mount
.000
.000
.000
.000
.000
.000
.606
.961
.582
.871
.374
.305
.316
.614
.272
3.001
0.278
-------
46 S2# 40 C440 2,4-OICHLOROPHENOL 162 2 NOT FOUND
47 S2# 45 C430 BENZOIC ACID 122 2 NOT FOUND
48 S2# 50 AA-DIMETHYLPHENETHYLAMIN 58 2 NOT FOUND
49 S2# 55 C445 1,2,4-TRICHLOROBENZ 180 2 NOT FOUND
1^5
-------
50 S2# 60 C450 NAPHTHALENE
51 S2# 80 C455 4-CHLOROANALINE
52 S2# 85 2,6-DICHLOROPHENOL
53 S2# 90 HEXACHLOROPROPENE
54 S2# 95 C460 HEXACHLOROBUTADIENE
55 S2#115 P-PHENYLENE D1AMINE
56 S2#120 N-NITROSODI-N-BUTYLAMINE
57 S2#130 C465 4-CHLORO-3-METHYLPH
58 S2#140 SAFROLE
59 S2#145 C470 2-METHYLNAPHTHALENE
60 S3# 10 1,2,4,5-TETRACHLOROBENZE
61 S3* 15 ISOSAFROLE (#1)
62 S3# 20 C510 HEXACHLOROCYCLOPENT
63 S3# 25 C515 2,4,6-TRICHLOROPHEN
64 S3# 30 C520 2,4,5-TRICHLOROPHEN
65 S3# 35 ISOSAFROLE (#2)
66 S3# 40 C525 2-CHLORONAPHTHALENE
67 S3# 42 1-CHLORONAPHTHALEN
68 S3# 45 C530 2-NITROANALINE
69 S3# 50 1,4-NAPHTHOQUINONE
70 S3# 55 C535 DIMETHYLPHTHALATE
71 S3# 60 1,3-DINITROBENZENE
72 S3# 65 C540 ACENAPHTHYLENE
73 S3# 70 C543 2,6-DINITROTOLUENE
74 S3# 75 C545 3-NITROAN1LINE
75 S3# 80 C550 ACENAPHTHENE
76 S3# 85 C555 2,4-DINlTROPHENOL
77 S3# 90 C565 DIBENZOFURAN
78 S3# 95 C560 4-NITROPHENOL
79 S3#100 PENTACHLOROBENZENE
80 S3#105 C570 2,4-DINITROTOLUENE
81 S3#110 1-NAPHTHYLAM1NE
82 53*115 2-NAPHTHYLAMINE
83 S3#120 2,3,4,6-TETRACHLOROPHENO
84 S3#130 C580 D1ETHYLPHTHALATE
85 S3#135 C590 FLUORENE
86 S3#140 C585 4-CHLOROPHENYL-PHEN
87 S3#145 5-NITRO-0-TOLUID1NE
88 S3#150 C595 4-NITROANALINE
89 S4# 10 C610 4.6-DINITRO-2-METHY
90 S4# 15 C615 N-N1TROSODIPHENYLAM
91 S4# 20 C620 AZOBENZENE
92 S4# 25 SYM-TR[NITROBENZENE
93 S4# 30 C625 4-BROMOPHENYL-PHENY
94 S4# 35 PHENACETIN
95 S4# 37 DIALLATE
96 S4# 40 C630 HEXACHLOROBENZENE
97 S4# 45 4-AMINOBIPHENYL
98 S4# 50 C635 PENTACHLOROPHENOL
99 S4# 55 PRONAMIDE
100 S4# 60 PENTACHLORONITROBENZENE
101 S4# 65 C640 PHENANTHRENE
102 S4# 70 C645 ANTHRACENE
103 S4# 75 2SECBUTYL-4.6-DINITROPHE
104 S4# 80 C647 CARBAZOLE
105 S4# 85 C650 Dl-N-BUTYLPHTHALATE
106 S4#100 4-NITROQUINOLINE-1-OXIDE
107.54*105 METHAPYRILENE
108 54*106 ISODRIN
109 S4#110 C655 FLUORANTHENE
110 S4#120 CHLOROBENZILATE
128
127
162
213
225
108
84
107
162
U2
214
162
237
196
196
104
162
162
65
158
163
168
152
165
138
153
184
168
109
250
165
143
143
232
149
166
204
152
138
198
169
77
75
248
108
234
284
169
266
173
237
178
178
211
167
149 A BB
190
58
193
202
139
2
2
2
2
2
2
2
2
2
2
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
NOT FOUND
NOT FOUND
NOT FOUND
NOT FOUND
NOT FOUND
NOT FOUND
NOT FOUND
NOT FOUND
NOT FOUND
NOT FOUND
NOT FOUND
NOT FOUND
NOT FOUND
NOT FOUND
NOT FOUND
NOT FOUND
NOT FOUND
NOT FOUND
NOT FOUND
NOT FOUND
NOT FOUND
NOT FOUND
NOT FOUND
NOT FOUND
NOT FOUND
NOT FOUND
NOT FOUND
NOT FOUND
NOT FOUND
NOT FOUND
NOT FOUND
NOT FOUND
NOT FOUND
NOT FOUND
NOT FOUND
NOT FOUND
NOT FOUND
NOT FOUND
NOT FOUND
NOT FOUND
NOT FOUND
NOT FOUND
MOT FOUND
NOT FOUND
NOT FOUND
NOT FOUND
NOT FOUND
NOT FOUND
NOT FOUND
NOT FOUND
NOT FOUND
NOT FOUND
NOT FOUND
NOT FOUND
NOT FOUND
1226 4 4688. 1.247
4
4
4
4
4
NOT FOUND
NOT FOUND
NOT FOUND
NOT FOUND
NOT FOUND
1.226
1L'6G
-------
111 S5# 10 C710 BENZ1DINE 184 5 NOT FOUND
112 S5# 15 C715 PYRENE 202 5 NOT FOUND
113 S5# 20 ARAMITE (#1) 185 5 NOT FOUND
114 S5# 25 ARAMITE (#2) 185 5 NOT FOUND
115 S5# 30 P-D1METHYLAMINOAZOBENZEN 120 5 NOT FOUND
116 S5# 35 3,3'-DIMETHYLBENZlDINE 212 5 NOT FOUND
117 S5# 37 KEPONE 272 5 NOT FOUND
118 S5# 40 C720 BUTYLBENZYLPHTHALAT 149 5 NOT FOUND
119 S5# 45 2-ACETYLAMINOFLUORENE 181 5 NOT FOUND
120 S5# 50 C730 8ENZO(A)ANTHRACENE 228 5 NOT FOUND
121 S5# 55 C725 3,3'-DICHLOROBENZlD 252 5 NOT FOUND
122 S5# 60 C740 CHRYSENE 228 5 NOT FOUND
123 S5# 65 C745 B1S(2-ETHYLHEXYL)PH 149 A BB 1603 5 3310. 0.980
124 S5# 85 3-METHYLCHOLANTHRENE 268 5 NOT FOUND
125 S6# 10 C760 DI-N-OCTYL PHTHALAT 149 6 NOT FOUND
126 S6# 15 C765 BENZO(B)FLUORANTHEN 252 6 NOT FOUND
127 S6# 20 7,12-DlMETHYLBENZANTHRAC 256 6 NOT FOUND
128 S6# 25 C770 BENZO(K)FLUORANTHEN 252 6 NOT FOUND
129 S6# 30 HEXACHLOROPHENE 196 6 NOT FOUND
130 S6# 35 C775 BENZO(A)PYRENE 252 6 NOT FOUND
131 S6# 55 C780 INDENOC1,2,3-CO)PYR 276 6 NOT FOUND
132 S6# 60 C785 DIBENZ(A,H)ANTHRACE 278 6 NOT FOUND
133 S6# 65 C790 BENZO(G,H,1)PERYLEN 276 6 NOT FOUND
1.899
126
-------
BNA, S LIBRARIES ANALYST: DATE:
QUANTERRA Internal Standard Check
Standard Filename: ST16980831 Analyzed: 08/31/98 12:31
| IS# 1 | IS# 2 | IS# 3 |
Standard j Area % \ RT j Area % | RT j Area % | RT j
ST16980831 | 28649. | 3.78 | 100432. | 5.90 | 54347. | 9.21 |
Upper Limit | 57297.=+200| 4.28 j 200864.=+200j 6.40 | 108695.=+200| 9.71 |
Lower Limit j 14324.=+ 50) 3.28 | 50216.=+ 50| 5.40 j 27174.=+ 50| 8.71 |
Filename |
I II II II
1 30068109 | 36331.= 126| 3.78 | 137829.= 137| 5.88 | 74485.= 137) 9.20 |
I II II II
IS# 1 = CI30 1.4-DICHLOROBENZENE-D4
IS# 2 = CI40 NAPHTHALENE-D8
IS# 3 = CI50 ACENAPHTHENE-D10
* - indicates an I.S. is outside QC limit(s)
| IS# 4 | IS# 5 | IS# 6
Standard j Area % | RT j Area % | RT j Area % | RT
ST16980831 | 98520. |12.08 | 62289. |17.26 | 50750. |19.83
Upper Limit j 197039.=+200|12.58 | 124578.=+200|17.76 j 101500.=+200|20.33
Lower Limit j 49260.=+ 50J11.58 j 31145.=+ 50(16.76 | 25375.=+ 50|19.33
Filename I II II I
1 30068109 | 122676.= 124J12.07 j 71172.= 114J17.25 j 56685.= 111J19.82
I II II I
IS# 4 - C160 PHENANTHRENE-010
IS# 5 = C170 CHRYSENE-012
IS# 6 = C175 PERYLENE-D12
* - indicates an I.S. is outside QC limit(s)
126,
-------
Data Reduced by: *^» Xate:
Data Reviewed by: If Date
Data File: 30068109
QUANTERRA GC/MS TIC REPORT ( Part 1 )
Sample: S-MM5-RB 1/3SA/1ML INST. ID: F16
Analyst: DAT Date Analyzed: 08/31/98 22:58
Run Factor: 3.00
Concentration
in Sample
# SCAN \\ll (UG/A) CAS it
69 270. 123-42-2
2-PENTANONE, 4-HYDROXY-4-METHYL-
2 222 400.
NONANE fry-
111-84-2
X285 25.
NZALDEHYDE
«
100-52-7
.^
S^932 17.
7f 3 8 1 ~ ' 0 1
TT-^^^, .
1 5VfvUi>>^Nj^- ^'stOO
51. ^F^T^ \
•ntXAUklANUlC AC IB
6 1333 77.
UNKNOWN
00-00-0
7 1358 71.
UNKNOWN
00-00-0
V
X^6
9 1502 42.
UNKNOWN
00-00-0
10 1509 63.
UNKNOWN
oo-oo-o
i;
-------
11 1529 99.
UNKNOWN
00-00-0
12 1587 250. 74685-30-6
5-EICOSENE, (E>- 0>f ^ts-^C*/
13 1661 94. 00-00-0 L)'^)O
UNKNOWN
14 1687 63. 00-00-0
UNKNOWN ,
15 1706 27. ztVV l/'Ti
CYCLOTETRAOECANE \i * •
6LftJI(iUUA-e
S^t-HC
16 1741 35. 00-00-0
UNKNOWN C^2rt5O
17 1801 140. 00-00-0
UNKNOWN
18 1834 / 14. 00-00-0
UNKNOWN
/
19 1916 110.
-------
23 2014 57. 74685-29-3
9-EICOSENE, (E)-
24 2051 61. 00-00-0
UNKNOWN
25 2057 72. 00-00-0
UNKNOWN
-------
DATA FILE: 30068109
QUANTERRA GC/MS TIC REPORT ( Part 2 )
CONCENTRATION = AREA(TIC)*CONC(IS)/AREA(IS)
#
1
2
3
A
5
6
7
8
9
10
11
12
13
K
15
16
17
18
19
20
21
22
23
24
25
FIT
957
986
966
918
976
891
763
957
760
796
931
986
925
800
871
866
876
924
980
775
695
789
949
922
749
PURITY
921
940
921
803
775
556
578
689
383
590
516
810
476
573
684
561
591
556
781
478
441
391
729
471
477
INT.
STD.
1
1
1
2
3
4
4
4
4
4
4
4
4
5
5
5
5
5
5
5
5
5
5
5
5
AMOUNT
AS ANALYZED
RT
1:52
2:28
3:10
10:21
13:44
14:49
15:06
16:18
16:42
16:47
17:00
17:39
18:28
18:45
18:58
19:21
20:01
20:23
21:18
21:30
21:34
21:52
22:24
22:48
22:52
RRT
0.319
0.420
0.539
1.127
1.139
0.859
0.876
0.945
0.968
0.973
0.986
1.023
1.071
0.947
0.957
0.977
1.011
1.029
1.075
1.085
1.089
1.103
1.130
1.151
1.154
AREA
648508.
946332.
59934.
49207.
139728.
135216.
124360.
39434.
73824.
110512.
174176.
437632.
164160.
97552.
41976.
55048.
221408.
21952.
175464.
125664.
41056.
32442.
89076.
94560.
111664.
HEIGHT
251136.
411648.
18879.
16122.
35968.
12976.
9168.
6486.
12016.
17856.
15312.
79488.
15600.
7632.
5648.
13486.
17472.
2816.
34566.
16368.
9312.
3297.
16549.
12016.
13104.
(UG/ML )
90
132
.815
.522
8.393
5
16
25
23
7
14
21
33
83
31
20
9
11
47
4
37
26
8
6
19
20
23
.755
.915
.735
.669
.505
.050
.033
.150
.292
.244
.916
.000
.803
.472
.707
.621
.943
.803
.956
.099
.274
.942
LIB
KB
NB
NB
NB
NB
UK
UK
NB
UK
UK
UK
NB
UK
UK
NB
UK
UK
UK
NB
UK
UK
UK
NB
UK
UK
LIB #
324V
5159,
2017
40501,
35182
1,
1
58380
1
1
1
39516
1
1
21960
1
1
1
26416
1
1
1
39515
1
1
'» P
. (*, v>
-------
Library Search Data: 30068109 # 169 Base m/z: 43
08/31/98 22:58:00 + 1:53 Cali: 30068109 # 3 R1C: 229120.
Sample: S-MM5-RB 1/3SA/1ML INST. ID: F16
Conds.: UG/ML *1HL *100V100X *(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
630 matched at least 6 of the 16 largest peaks in the unknown
Rank In. Name
1 3241 2-PENTANONE, 4-HYDROXY-4-METHYL-
2 5791 1.3-DIOXOLANE-2-METHANOL, 2,4-DIMETHYL-
3 3366 2-PENTANOL, 2,4-DIMETHYL-
4 3288 ACETIC ACID, 1,1-DIMETHYLETHYL ESTER
5 919 TERT-BUTYL HYDROPEROX1DE
6 5594 2-PROPANOL, 2-NITROSO-, ACETATE (ESTER)
7 3349 2-HEXANOL, 2-METHYL-
8 8432 2-HEXANONE, 3-HYDROXY-3.5-DIMETHYL-
9 3234 OXIRANE, [(I-METHYLETHOXY)METHYU -
Rank Formula M.Ut B.Pk Purity Fit RFit
1 C6.H12.02 116 43 921 957 934
2 C6.H12.03 132 43 757 825 800
3 C7.H16.0 116 59 740 760 740
4 C6.H12.02 116 43 722 769 735
5 C4.H10.02 90 59 719 861 741
6 C5.H9.03.N 131 43 706 818 796
7 C7.H16.0 116 59 701 732 701
8 C8.H16.02 144 59 666 722 693
9 C6.H12.02 116 43 658 703 676
Rank Ret.Time B.P.Int. US.Par.1 US.Par.2 C.A.S. #
1 123-42-2
2 53951-43-2
3 625-06-9
4 540-88-5
5 ' 75-91-2
6 6931-04-0
7 625-23-0
8 6321-14-8
9 4016-14-2
-------
MID LIBRARY SEARCH
08/31/98 22:58:00 + 1:53
SAMPLE: S-MM5-RB 1/3SA/1ML INST. ID:
CONDS.: UG/ML *1ML *100Z/1007Z *
-------
Library Search Data: 30068109 # 222 Base m/z: 43
08/31/9822:58:00+ 2:28 Cali: 30068109 # 3 RIC: 312320.
Sample: S-MM5-RB 1/3SA/1ML 1NST. ID: F16
Conds.: UG/ML *1HL *100%/100% *(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
921 matched at least 7 of the 16 largest peaks in the unknown
Rank In.
Name
1 5159 NONANE
2 5151 HEPTANE, 3,4-DIMETHYL-
3 3086 HEXANE, 2,4-DIMETHYL-
4 19015 DECANE, 2,5,6-TRIHETHYL-
5 5141 HEPTANE, 2,4-DIMETHYL-
6 5154 HEXANE, 4-ETHYL-2-METHYL-
7 11607 UNOECANE
8 5160 PENTANE, 2,2,3,4-TETRAMETHYL-
9 5144 HEPTANE, 4-ETHYL-
Rank
1
2
3
4
5
6
7
8
9
Formula
C9.H20
C9.H20
C8.H18
C13.H28
C9.H20
C9.H20
C11.H24
C9.H20
C9.H20
Rank
1
2
3
4
5
6
7
8
9
M.Wt B.Pk Purity Fit RFit
128
128
114
184
128
128
156
128
128
43
43
43
57
43
57
43
57
43
940
914
887
885
883
875
869
866
865
986
939
957
921
932
923
925
924
909
940
914
898
895
884
875
913
866
872
Ret.Time B.P.Int.
US.Par.1 US.Par.2
C.A.S,
111-
922
589
62108
2213
3074
1120
1186
2216
#
84-2
28-1
•43-5
•23-0
23-2
•75-7
•21-4
•53-4
•32-2
rc
-------
1060
SAMPLE
MID LIBRARY SEARCH
08/31/98 22:58:00 + 2:28
SAMPLE: S-MM5-RB 1/3SA/1ML INST. ID:
CONDS.: UG/ML *1ML *100Z/100Z */l/3SA
ENHANCED
DATA: 30068109 # 222
CALI: 30068109 # 3
BASE M/Z: 43
RIC: 312320.
F16
NA M
C9.H20
1000
M NT 128
B PK 43
RANK 1
# 5159
PUR 940
C9.H20
1000
M NT 128
B PK 43
RANK 2
* 5151
PUR 914
NONANE
HEPTANE , 3,4-DIMETHYL-
C8.H18
1000 I
M WT 114
B PK 43
RANK 3
tt 3086
PUR 887
HEXANE, 2,4-DIMETHYL-
r
1 1
-L
„ , L
_ 4J , 1
-*— r -— • • 1 • • '—• ' - - i '
M/Z
40
60
80
100
120
•si
O
-------
Library Search Data: 30068109 # 285 Base m/z: 77
08/31/9822:58:00+ 3:10 Cali: 30068109 # 3 RIC: 15136.
Sample: S-MM5-RB 1/3SA/1ML INST. ID: F16
Conds.: UG/ML *1ML *100X/100% *(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
352 matched at least 5 of the 16 largest peaks in the unknown
Rank In. Name
1 2017 BENZAUDEHYDE
2 7284 BENZOYL CHLORIDE
3 6466 ETHANONE, 2-HYDROXY-1-PHENYL-
4 2014 2.4-HEPTAD1EN-6-YNAL, (E,E)-
5 9645 BENZOYLFORMIC ACID
6 9261 1,2-PROPANEDIONE, 1-PHENYL-
7 13112 BENZOYL ISOTHIOCYANATE
8 6857 BENZENECARBOTHIOIC ACID
9 13359 BENZENEACETIC ACID, .ALPHA.-OXO-, METHYL ESTER
Rank
1
2
3
4
5
6
7
8
9
Formula
C7.H6.0
C7.H5.0.CL
C8.H8.02
C7.H6.0
C8.H6.03
C9.H8.02
C8.H5.0.N.S
C7.H6.0.S
C9.H8.03
M.Ut
106
140
136
106
150
148
163
138
164
B.Pk
77
105
105
105
105
105
105
77
105
Purity
921
816
798
793
781
775
773
763
761
Fit
966
876
839
838
848
822
821
846
835
RFit
942
829
819
803
806
801
789
809
788
Rank
1
2
3
4
5
6
7
8
9
Ret.Time
B.P.Int.
US.Par.1
US.Par.2
C.A.S
100
98
582
7200
611
579
532
98
15206
, #
•52-7
•88-4
•24-1
•04-6
•73-4
•07-7
•55-8
•91-9
•55-0
1271
-------
MID LIBRARY SEARCH (LIBRARYNB) DATA: 30068109 # 285 BASE M/Z: 77
08/31/98 22:58:00 + 3:10 CALI: 30068109 # 3 RIC: 15136.
SAMPLE: S-MM5-RB 1/3SA/1ML INST. ID: F16
CONDS.: UG/ML *1ML *100Z/100Z */l/3SA NA M
ENHANCED
1497 •
SAMPLE
C7.H6.0
1497 i
M NT 106
B PK 77
RANK 1
# 2017 '
PUR 921
C7.H5.0.CI
1497 •
M WT 140
B PK 105
RANK 2
# 7284 '
PUR 816
C8.H8.02
1497 i
M WT 136
B PK 105
RANK 3
» 6466
PUR 798
M/Z
r
m.lll. ..... ,1.
BENZALDEHYDE
r
.. |l
0< ^^^
BENZOYL CHLORIDE
r
. . jl
ETHANONE, 2-HYDR
r
.... 1.
1 'i' • "1 • H*-" r-^ 1 " i-1i • 1 • 1— <
50 100
\ — . , ,— , • r-
•^ 1 1 ' "^ 1 !-.-•- | I 1
OXY-1-PHENYL-
150 200 250
-------
Library Search Data: 30068109 # 932
08/31/98 22:58:00 + 10:22 Cali: 30068109 # 3
Sample: S-MM5-RB 1/3SA/1ML INST. ID: F16
Conds.: UG/ML *1ML *100X/100% *(NA/NA }/1/3SA NA M
Enhanced (S 15B 2N OT)
Base m/z: 71
RIC: 14704.
62231 spectra in L1BRARYNB searched for maximum PURITY
552 matched at least 6 of the 16 largest peaks in the unknown
Rank In. Name
1 40501 PROPANOIC ACID, 2-METHYL-, 1-(1,1-DIMETHYLETHYD-2-METHYL-1,3-PROPA*
2 26739 PROPANOIC ACID, 2-METHYL-, 2.2-DIMETHYL-1-(2-HYDROXY-1-METHYLETHYL)*
3 40500 PROPANOIC ACID, 2-METHYL-, 2-ETHYL-1-PROPYL-1,3-PROPANEDIYL ESTER
4 4625 1-HEXENE, 3,4,5-TRIMETHYL-
5 4556 ETHANONE, 1-(3-ETHYLCYCLOBUTYL>-
6 2720 4,4-DIMETHYL-1-HEXENE
7 4677 2,4,4-TRIHETHYL-1-HEXENE
8 15779 1,2-CYCLOHEXANEDIOL, 1-METHYL-4-(1-METHYLETHYL)-
9 14787 1-NONENE, 4,6,8-TRIMETHYL-
M.Ut B.Pk Purity Fit RFit
Rank
1
2
3
4
5
6
7
8
9
Formula
C16.H30.04
C12.H24.03
C16.H30.04
C9.H18
C8.H14.0
C8.H16
C9.H18
C10.H20.02
C12.H24
286
216
286
126
126
112
126
172
168
71
71
43
43
43
71
71
71
43
803
722
693
608
593
592
556
528
519
918
883
841
810
745
789
716
696
694
825
741
748
687
622
645
656
642
556
Rank
1
2
3
4
5
6
7
8
9
Ret.Time
B.P.Int.
US.Par.1
US.Par.2
C.A.S.
74381•
74367-
74367-
56728-
56335-
1647-
51174
33669
54410
#
40-1
33-2
30-9
10-0
71-8
08-1
12-0
76-0
98-9
-------
1193
SAMPLE
MID LIBRARY SEARCH
DATA: 30068109 # 932
CALI: 30068109 ft 3
BASE M/Z: 71
RIC: 14704.
il.. .. i
*^
C16.H30.04
1190
M WT 286
B PK 71
RANK 1
ft 40501
PUR 803
PROPAND1C AC ID, 2-METHYL-, 1-<1,1-DIMETHYLETHYL >-2-METHYL-1,3-PROPANE!
C12.H24.03
1190
M WT 216
B PK 71
RANK 2
ft 26739
PUR 722
PROPANOIC ACID, 2-METHYL-, 2,2-DIMETHYL-l-<2-HYDROXY-1-METHYLETHYL)PR!
I. i
C16.H30.04
1190
M WT 286
B PK 43
RANK 3
ft 40500
PUR 693
M/Z
50
PROPANOIC ACID, 2-METHYL-, 2-ETHYL-l-PROPYL-l,3-PROPANEDIYL ESTER
100
150
200
250
300
-------
Library Search Data: 30068109 #1236 Base m/z: 73
08/31/98 22:58:00 + 13:45 Cali: 30068109 # 3 RIC: 27392.
Sample: S-MM5-RB 1/3SA/1ML INST. ID: F16
Conds.: UG/ML *1ML *100X/100% *(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
62231 spectra in L1BRARYNB searched for maximum PURITY
750 matched at least 6 of the 16 largest peaks in the unknown
Rank In. Name
1 35182 HEXADECANOIC ACID
2 37913 GLYCINE. N-METHYL-N-(I-OXOOOOECYL)-
3 40669 DODECANAMIDE, N,N-BIS(2-HYDROXYETHYL)-
4 29642 TETRADECANOIC ACID
5 26351 TRIDECANOIC ACID
6 40184 OCTADECANOIC ACID
7 22949 DOOECANOIC ACID
8 19469 UNDECANOIC ACID
9 15784 DECANOIC ACID
Rank Formula M.Wt B.Pk Purity Fit RFit
1 C16.H32.02 256 43 775 976 778
2 C15.H29.03.N 271 73 665 979 665
3 C16.H33.03.N 287 73 642 968 650
4 C14.H28.02 228 73 623 900 671
5 C13.H26.02 214 73 607 892 627
6 C18.H36.02 284 43 604 768 766
7 C12.H24.02 200 60 604 907 655
8 C11.H22.02 186 60 597 949 603
9 C10.H20.02 172 60 573 955 577
Rank Ret.Time B.P.Int. US.Par.1 US.Par.2 C.A.S. M
1 57-10-3
2 97-78-9
3 120-40-1
4 544-63-8
5 638-53-9
6 57-11-4
7 143-07-7
8 112-37-8
9 334-48-5
1
-------
MID LIBRARY SEARCH CLIBRARYNB) DATA:
08/31/98 22:58:00 + 13:45 CALI:
SAMPLE: S-MM5-RB 1/3SA/1ML INST. ID: F16
CONDS.: UG/ML *1ML *10071/100?; */l/3SA NA M
ENHANCED
30068109 #1236
30068109 # 3
BASE M/Z: 73
RIC: 27392.
1239 •
SAMPLE
C16.H32.02
1239 •
M WT 256
B PK 43
RANK 1
# 35182 '
PUR 775
C15.H29.03
1239 1
M WT 271
B PK 73
RANK 2
# 37913
PUR 665
C16.H33.03
1239 -i
M WT 287
B PK 73
RANK 3
* 40669
PUR 642
M/Z
.N
.N
•
M
50
In
^s—
illl 1 .ilii i .1.. L ....... i. ... .. i. i. 1. . i.
HEXADECANOIC ACID
||
| |
1 | ll i 1 i 1. i.
GLYCINE, N-METH YL-N- < 1 -OXODODEC YL > -
1 1 i i 1
DODECANAM I DE , N , N-B I S < 2-HYDROXYETHYL ) -
II
1 1 i 1 1 .1.1
100 150 200 250
CTJ
-------
Library Search
08/31/98 22:58:00 + 14:50
Sample: S-MM5-RB 1/3SA/1ML
Conds.: UG/ML *1ML *100%/100%
Enhanced (S 158 2N OT)
Data: 30068109 #1333
Cati: 30068109 # 3
INST. ID: F16
*(NA/NA )/1/3SA NA M
Base m/z: 59
RIC: 7896.
62231 spectra in LIBRARYNB searched for maximum PURITY
289 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 8460 SI LANE, OCTYL-
2 3000 OXIRANE, 2.2-DIMETHYL-3-PROPYL-
3 8805 1,3-DIOXAN-S-OL, 4,4,5-TRIMETHYL-
4 1513 OXIRANE, 3-ETHYL-2.2-DIMETHYL-
5 19877 BUTANE, 1.1'-[(1-METHYLETHYLIDENE)BIS(OXY)]BIS-
6 8544 2-OCTANOL, 2-METHYL-
7 1576 OXIRANE, TETRAMETHYL-
8 1556 OXIRANE, 2,3-DIETHYL-
9 12073 2-METHYL-2-NONANOL
Rank
1
2
3
4
5
6
7
8
9
Formula
C8.H20.
C7.H14.
C7.H14.
C6.H12.
C11.H24
C9.H20.
C6.H12.
C6.H12.
SI
0
03
0
.02
0
0
0
C10.H22.0
M.Ut
144
114
146
100
188
144
100
100
158
B.Pk
59
43
59
59
59
59
59
58
59
Purity
556
530
495
495
488
483
483
464
454
Fit
891
828
896
853
690
827
853
749
839
RFit
577
546
530
506
504
495
491
477
497
Rank
1
2
3
4
5
6
7
8
9
Ret.Time B.P.Int.
US.Par.1
US.Par.2
C.A.S. #
871-92-1
17612-35-0
54063-14-8
1192-22-9
141-72-0
628-44-4
5076-20-0
4468-66-0
10297-57-1
1 r»"5
_L £~ i
-------
MID LIBRARY SEARCH DATA: 30068109 #1333 BASE M/Z: 59
08/31/98 22:58:00 + 14:50 CALI: 30068109 # 3 RIC: 7896.
SAMPLE: S-MM5-RB 1/3SA/1ML INST. ID: F16
CONDS.: UG/ML *1ML *100?:/100Z */l/3SA NA M
ENHANCED
1600
SAMPLE
C8.H20.SI
1000 1
M WT 144
B PK 59
RANK 1
# 8460
PUR 556
C7.H14.0
1000 1
M WT 114
B PK 43
RANK 2
* 3000 :
PUR 530
C7.H14.03
1000 I
M WT 146
B PK 59
RANK 3
# 8805
PUR 495
M/Z
r
ill l|
i i.l.i .... .. i ... i. .
SI LANE, OCTYL-
r
1 ||
1
OXIRANE, 2,2-DIMETHYL-3-PROPYL-
r
1 i . h'l
1 , 3-DIOXAN-5-OL, 4,4, 5-TRIMETHYL-
r
1,
II , ,l|
40 60 80 106 120 140 160 180 200
*.(
-------
Library Search Data: 30068109 #1358 Base m/z: 59
08/31/9822:58:00+15:06 Cali: 30068109 # 3 R1C: 5376.
Sample: S-MM5-RB 1/3SA/1ML INST. ID: F16
Conds.: UG/ML *1ML MOOX/100X *(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
875 matched at least 5 of the 16 largest peaks in the unknown
Rank In. Name
1 24247 2-PROPANOL, 1 -[2-(2-METHOXY-1-METHYLETHOXY)-1-METHYLETHOXY]-
2 9228 1-PROPANOL, 2-(2-METHOXYPROPOXY)-
3 36537 2,5,8,11-TETRAOXATETRADECAN-13-OL, 4,7,10-TRIMETHYL-
4 5826 2-PROPANOL, 1-ISOPROPOXY-2-METHYL-
5 1775 PENTANE, 2-METHOXY-
6 5786 PROPANOIC ACID, 2-HYDROXY-2-METHYL-, ETHYL ESTER
7 1905 2-BUTANOL, 3-METHOXY-
8 9229 2-PROPANOL, 1-(2-METHOXYPROPOXY)-
9 848 3-PENTANOL
Rank
1
2
3
4
5
6
7
8
9
Formula
C10.H22.04
C7.H16.03
C13.H28.05
C7.H16.02
C6.H14.0
C6.H12.03
C5.H12.02
C7.H16.03
C5.H12.0
M.Ut B.Pk Purity Fit RFit
206
148
264
132
102
132
104
148
88
59
59
59
59
59
59
59
59
59
578
575
531
517
511
510
504
503
499
763
824
753
745
903
817
904
841
916
646
595
624
540
530
539
521
558
537
Rank
1
2
3
4
5
6
7
8
9
Ret.Time B.P.Int.
US.Par.1
US.Par.2
C.A.S.
20324-
13588-
20324-
3587-
6795-
80
53778-
13429-
584
#
33-8
28-8
34-9
75-5
88-6
55-7
72-6
07-7
02-1
"^ C
i'b
-------
MID LIBRARY SEARCH (LIBRARYNB) DATA:
08/31/98 22:58:00 + 15:06 CALI:
SAMPLE: S-MM5-RB 1/3SA/1ML INST. ID: F16
CONDS.: UG/ML *1ML * 108Z/ 10072 */l/3SA NA M
ENHANCED (S 15B 2N 0T>
30868109 #1358
30068109 # 3
BASE M/Z: 59
RIC: 5376.
1000 "I
SAMPLE
C10.H22.0-
1000 1
M WT 206
B PK 59
RANK 1
# 24247
PUR 578
C7.H16.03
1000 1
M WT 148
B PK 59
RANK 2
# 9228
PUR 575
C13.H28.0!
1000 1
M WT 264
B PK 59
RANK 3 ,
# 36537
PUR 531
r
In ll
^^
4 2-PROPANOL, l-[ 2- <2-METHOXY-l -METHYLETHOXY)-! -METHYLETHOXY]-
r
i 1..
1 ... 1. -
1 -PROPANOL , 2- < 2-METHOXYPROPOX Y > -
r
1 i..
LV , ,111-1 1 r^J
r
2,5,8,1 1 -TETRAOXATETRADECAN- 1 3-OL , 4,7,1 0-TR I METHYL-
II l"l 1-
1 • r^ • • i 1 i -i 1 i 1 i'" i • 1 — i • I1' ' i •' r • "i - i ' . - '!" - . ' - . - i
M/Z
50
100
150
200
250
en
0
-------
Library Search Data: 30068109 #1466 Base m/z: 57
08/31/98 22:58:00 f 16:18 Call: 30068109 # 3 RIC: 5872.
Sanple: S-MM5-RB 1/3SA/1ML INST. ID: F16
Conds.: UG/ML *1ML *100%/100X *(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
920 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 58380 DECANEDIOIC ACID, DIDECYL ESTER
2 15969 HYDROXYLAMINE, 0-OECYL-
3 19520 1-OCTANOL, 2-BUTYL-
4 19525 2-HETHYL-1-UNDECANOL
5 42180 OCTADECANE, I-(ETHENYLOXY)-
660775 HEXADECANE, 1. I-BIS(DOOECYLOXY)-
7 60679 PHOSPHONIC ACID, D10CTADECYL ESTER
8 19523 1-DECANOL, 2-ETHYL-
9 40233 NONADECANOL
Rank
1
2
3
4
5
6
7
8
9
Rank
1
2
3
i.
5
6
7
8
9
Formula
C30.H58
C10.H23
C12.H26
C12.H26
C20.H40
C40.H82
C36.H75
C12.H26
C19.H40
.04
.O.N
.0
.0
.0
.02
.03.P
.0
.0
Ret. Time B.P.Int.
M.Ut
482
173
186
186
296
594
586
186
284
US. Par. 1
B.Pk
57
43
57
57
43
43
55
57
43
US. Par
Purity Fit
689 957
671 918
659 918
652 935
652 925
647 873
646 917
645 928
639 915
.2 C.A.S. it
2432-89-5
29812-79-1
3913-02-8
10522-26-6
930-02-9
56554-64-4
19047-85-9
21078-65-9
52783-43-4
RFit
699
681
701
681
690
730
677
669
680
1281
-------
MID LIBRARY SEARCH DATA: 30068109 #1466 BASE M/Z: 57
08/31/98 22:58:00 + 16:18 CALI: 30068109 # 3 RIC: 5872.
SAMPLE: S-MM5-RB 1/3SA/1ML INST. ID: F16
CONDS. : UG/ML *1ML *100Z/100Z */l/3SA NA M
ENHANCED
1535
SAMPLE
C30.H58.0
1535 i
11 WT 482
B PK 57
RANK 1
* 58380
PUR 689
C10.H23.0
1535 •
M WT 173
B PK 43
RANK 2
# 15969 '
PUR 671
C12.H26.0
1535 i
M WT 186
B PK 57
RANK 3
# 19520
PUR 659
M/Z
I
^^—
.lllli .III . 1 I . i . 1., . 1 i .
4 DECANEDIOIC ACID, DIDECYL ESTER
I
1
1,1
llll III,.
.N HYDROXYLAMINE, 0-DECYL-
ll
ill i i i . .1 .. •-
1-OCTANOL, 2-BUTYL-
III .III i. 1. . •
40 60 80 100 120 140 160
oo
JV>
-------
Library Search Data: 30068109 #1502 Base m/z: 45
08/31/98 22:58:00 + 16:42 Cali: 30068109 # 3 RIC: 3992.
Sample: S-MM5-R8 1/3SA/1ML 1NST. ID: F16
Conds.: UG/ML *1ML *100X/100% *(NA/NA )/1/3SA NA M
Enhanced (S 158 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
325 matched at least 6 of the 16 largest peaks in the unknown
Rank In. Name
1 3365 2-PENTANOL, 4,4-DIMETHYL-
2 3362 4-METHYL-2-HEXANOL
3 1789 2-HEXANOL
4 6417 2-PENTANOL, 3-CHLORO-4-METHYL-, -(.+/-.)-
5 8510 2-NONANOL
6 3188 N-NITROSO-2-METHYL-OXAZOLIDINE
7 3060 OXIRANE, 2-BUTYL-3-METHYL-, CIS-
8 23326 2-PROPANONE, 1,1-DIBUTOXY-
9 15842 2-UNDECANOL
Rank Formula
1
2
3
4
5
6
7
8
9
C7.
C7.
C6.
C6.
C9.
C4.
C7.
C11
C11
H16.
H16.
H14.
H13.
H20.
0
0
0
O.CL
0
H8.02.N2
H14.
.H22
.H24
0
.03
.0
M.Wt B.Pk Purity Fit RFit
Rank
1
2
3
4
5
6
7
8
9
Ret.Time
B.P.Int.
116
116
102
136
144
116
114
202
172
57
45
45
45
45
43
43
57
45
383
382
373
369
367
362
358
354
345
760
818
741
792
786
703
722
655
739
443
437
405
412
431
406
465
383
443
US.Par.1
US.Par.2
C.A.S
6144-
2313-
626
74685-
628
39884-
56052
19255-
1653-
#
93-0
61-3
93-7
47-5
99-9
53-2
93-8
82-4
30-1
-------
MID LIBRARY SEARCH (LIBRARYNB) DATA: 30068109 #1502 BASE M/Z: 45
08/31/98 22:58:00 + 16:42 CALI: 30068109 ft 3 RIC: 3992.
SAMPLE: S-MM5-RB 1/3SA/1ML INST. ID: F16
CONDS.: UG/ML *1ML *100Z/1002 *
2226 •
SAMPLE
C7.H16.0
2226 1
M WT 116
B PK 57
RANK 1
ft 3365 '
PUR 383
C7.H16.0
2226 1
M WT 116
B PK 45
RANK 2
ft 3362 '
PUR 382
C6.H14.0
2226 i
M WT 102
B PK 45
RANK 3
ft 1789
PUR 373
M/Z
r
1,1
W*'
.1, I II... 1. . . ....
2-PENTANOL , 4 , 4-D I METHYL-
r
| 1 I'l
1 h j i i
4-METHYL-2-HEXANOL
r
II iii
r
III h, I , ,
2-HEXANOL
40 60 80 100 120 140 160 180 200
-------
Library Search Data: 30068109 #1509
08/31/98 22:58:00 + 16:47 Cali: 30068109 # 3
Sample: S-MM5-RB 1/3SA/1ML INST. ID: F16
Conds.: UG/ML *1ML *100%/100% "(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
Base m/z: 59
RIC: 12128.
62231 spectra in LIBRARYNB searched for maximum PURITY
329 matched at least 6 of the 16 largest peaks in the unknown
Rank In. Name
1 24247 2-PROPANOL, 1-[2-(2-METHOXY-1-METHYLETHOXY)-1-METHYLETHOXY]•
2 16192 2-PROPANOL, 1 - [1-METHYL-2-(2-PROPENYLOXY)ETHOXY]-
3 20626 2-PROPANOL, 1,1'-[<1-METHYL-1,2-ETHANEDIYL)BIS(OXY)]B1S-
4 3522 2,3-BUTANEDIOL, 2,3-DIMETHYL-
5 9235 1-PROPANOL, 2-(2-METHOXY-1-METHYLETHOXY)-
6 5778 BUTANOIC ACID, 3-HYDROXY-3-METHYL-, METHYL ESTER
7 12385 BUTYRIC ACID, 4-ISOPROPOXY-, METHYL ESTER
8 8432 2-HEXANONE, 3-HYDROXY-3.5-DIMETHYL-
9 8822 BUTANOIC ACID, 4-ETHOXY-, METHYL ESTER
Rank
1
2
3
4
5
6
7
8
9
Formula
C10.H22.04
C9.H18.03
C9.H20.04
C6.H14.02
C7.H16.03
C6.H12.03
C8.H16.03
C8.H16.02
C7.H14.03
Rank
1
2
3
t,
5
6
7
8
9
Ret.Time
B.P.Int.
US.Par.1
M.Wt
206
174
192
118
148
132
160
144
146
B.Pk Purity Fit
59
59
59
59
59
43
85
59
59
I US. Par. 2
590 796
534 748
520 780
509 919
485 727
479 827
467 682
466 933
457 685
C.A.S. #
20324-33-8
55956-25-7
1638-16-0
76-09-5
55956-21-3
6149-45-7
29006-05-1
6321-14-8
29006-04-0
RFit
614
564
546
522
488
496
496
475
483
-------
MID LIBRARY SEARCH (LIBRARYNB) DATA:
08/31/98 22:58:00 + 16:47 CALI:
SAMPLE: S-MM5-RB 1/3SA/1ML INST. ID: F16
CONDS.: UG/ML *1ML *100Z/10075 */l/3SA NA M
ENHANCED
30068109 #1599
30068109 # 3
BASE M/Z: 59
RIC: 12128.
1006 i
SAMPLE
C10.H22.0'
1006 I
M WT 206
B PK 59
RANK 1
* 24247
PUR 590
C9.H18.03
1006 i
M WT 174
B PK 59
RANK 2
# 16192
PUR 534
C9.H20.04
1006 1
M WT 192
B PK 59
RANK 3
« 20626 '
PUR 520
M/Z
r
III t.
.1 . . 1. ... .
t 2-PROPANOL, l-[ 2- < 2-METHOXY- 1 -METHYLETHOXY) -1 -METHYLETHOXY 3-
r
i.
2-PROPANOL , 1 - [ 1 -METHYL-2- < 2-PROPENYLOXY ) ETHOXY ] -
r
1 ll i
r
„ . Ill 1
50
2-pROPANOL , 1 , 1 ' - C < 1 -METHYL- 1 , 2-ETHANED I YL ) B I S < OXY ) ] B I S-
100 150 200 250
cr>
-------
Library Search
08/31/98 22:58:00 H
Sample: S-MM5-R8
Conds.: UG/ML *1ML
Data: 30068109 #1529
17:00 Cati: 30068109 # 3
1/3SA/1ML INST. ID: F16
•100X/100X *
-------
1094
SAMPLE
MID LIBRARY SEARCH
08x31/98 22:58:00 + 17:00
SAMPLE: S-MM5-RB 1/3SA/1ML INST. ID:
CONDS.: DC/ML *1ML *100Z/1007: */l/3SA
ENHANCED
F16
NA M
DATA: 30068109 #1529
CALI: 30068109 # 3
BASE M/Z: 59
RIC: 10864.
Ill
C6.H14.02
1094
M WT 118
B PK 59
RANK 1
# 3522
PUR 516
2,3-BUTANEDIOL, 2,3-DIMETHYL-
C10.H22.04
1094
M NT 206
B PK 59
RANK 2
# 24247
PUR 495
2-PROPANOL , 1 - [ 2- ( 2-METHOXY- 1 -METHYLETHOXY ) - 1 -METHYLETHOXY ] -
C9.H18.03
1094 n
M NT 174
B PK 59
RANK 3
tt 16192
PUR 494
2-PROPANOL, l-[ l-METHYL-2-(2-PROPENYLOXY)ETHOXY3-
M/Z
50
100
150
200
250
300
rr
o>
-------
Library Search Data: 30068109 #1587 Base m/z: 57
08/31/9822:58:00+17:39 Cali: 30068109 # 3 RIC: 68224.
Sample: S-MM5-RB 1/3SA/1ML IMST. ID: F16
Conds.: UG/ML *1ML *100%/100% *(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
950 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 39516 5-E1COSENE, (E)-
2 34410 3-OCTADECENE, (E)-
3 39515 9-E1COSENE, (E)-
4 34411 5-OCTADECENE,
-------
MID LIBRARY SEARCH CLIBRARYNB) DATA:
08/31/98 22:58:00 + 17:39 CALI:
SAMPLE: S-MM5-RB 1/3SA/1ML INST. ID: FIG
CONDS.: UG/ML *1ML *100Z/100Z *- ^ *.*>a~^*-<*S
ll
1 . 1. .. .. .. —
l' ' • | •!• • 1 1 ' ' ' 1 • I • 1""1 1 • • ' ' ' • ' r - | ••••••-•- i •
3-OCTADECENE, -
1
' • i —
50
I
ll
1 li „ , „ * . 1. . . . , . r-
9-EICOSENE, -
'
ll
'
100 150 200 250
CO
c -i
-------
Library Search Data: 30068109 #1661 Base m/z: 59
08/31/98 22:58:00 + 18:29 Cali: 30068109 # 3 RIC: 9856.
Sample: S-MM5-RB 1/3SA/1ML INST. ID: F16
Conds.: UG/ML *1ML *100%/100% *(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
217 matched at least 6 of the 16 largest peaks in the unknown
Rank In. Name
1 3528 2-METHYL-2.3-PENTANEDIOL
2 1909 2-PROPANOL, 1-METHOXY-2-METHYL-
3 1905 2-BUTANOl, 3-METHOXY-
4 3502 BUTANOIC ACID, 3-HYDROXY-3-METHYL-
5 9227 1,3,3-TRIMETHOXYBUTANE
6 8822 BUTANOIC ACID, 4-ETHOXY-, METHYL ESTER
7 5826 2-PROPANOL, 1-1SOPROPOXY-2-METHYL-
8 1919 1-BUTANOL, 3-METHOXY-
9 36510 1,4,7,10,13,16-HEXAOXACYCLOOCTADECANE
Rank
1
2
3
4
5
6
7
8
9
Formula
C6.H14.02
C5.H12.02
C5.H12.02
C5.H10.03
C7.H16.03
C7.H14.03
C7.H16.02
C5.H12.02
C12.H24.06
H.Wt
118
104
104
118
148
146
132
104
264
B.Pk
59
59
59
59
45
59
59
59
45
Purity
476
473
435
432
429
427
426
424
423
Fit
925
946
870
815
674
743
677
893
678
RFit
476
477
435
489
442
515
490
437
455
Rank
1
2
3
4
5
6
7
8
9
Ret.Time
B.P.Int.
US.Par.1
US.Par.2
C.A.S.
7795-
3587-
53778-
625-
6607-
29006-
3587
2517-
17455-
#
80-4
64-2
72-6
08-1
66-5
04-0
75-5
43-3
13-9
l
«J JL
-------
MID LIBRARY SEARCH DATA: 30068109 #1661 BASE M/Z: 59
08/31/98 22:58:00 + 18:29 CALI: 30068109 # 3 RIC: 9856.
SAMPLE: S-MM5-RB 1/3SA/1ML INST. ID: F16
CONDS.: UG/ML *1ML * 10072/100Z */l/3SA NA M
ENHANCED
1644 •
SAMPLE
C6.H14.02
1644 i
M WT 118
B PK 59
RANK 1
# 3528 '
PUR 476
C5.H12.02
1644 i
M WT 104
B PK 59
RANK 2
# 1909 '
PUR 473
C5.H12.02
1644 i
M WT 104
B PK 59
RANK 3
# 1905
PUR 435
M/Z
r
1.1 1 , 1,
^v>~
2-METHYL-2, 3-PENTANEDIOL
r
ll . .
2-PROPANOL/ l-METHOXY-2-METHYL-
r
.1 . . 1 i .
r
.1 . .
50
, , .1
2-BUTANOL, 3-METHOXY-
100 150 200 250
CD
-------
Library Search
08/31/98 22:58:00 + 18:46
Sample: S-MM5-R8 1/3SA/1ML
Conds.: UG/ML *1ML *100X/100%
Enhanced (S 158 2N OT)
Data: 30068109 #1687
Cali: 30068109 # 3
INST. ID: F16
"(NA/NA )/1/3SA NA M
Base m/z: 59
RIC: 6712.
62231 spectra in LIBRARYNB searched for maximum PURITY
613 matched at least 5 of the 16 largest peaks in the unknown
Rank In. Name
1 5786 PROPAN01C ACID, 2-HYDROXY-2-METHYL-, ETHYL ESTER
2 24247 2-PROPANOL, 1- [2-(2-METHOXY-1-METHYLETHOXY)-1-METHYLETHOXY]•
3 9228 1-PROPANOL, 2-<2-METHOXYPROPOXY)-
4 20626 2-PROPANOL, 1,1'-U1-METHYL-1,2-ETHANEDIYL)BIS(OXY)]BIS-
5 36537 2,5,8,11-TETRAOXATETRADECAN-13-OL, 4,7,10-TRIMETHYL-
6 926 1-PROPANOL, 2-METHOXY-
7 334 2-PROPANOL, 2-METHYL-
8 8432 2-HEXANONE, 3-HYDROXY-3.5-DIMETHYL-
9 848 3-PENTANOL
Rank
1
2
3
4
5
6
7
8
9
Rank
1
2
3
4
5
6
7
8
9
Formula
C6.
C10
C7.
C9.
C13
C4.
C4.
C8.
C5.
H12.03
.H22.04
H16.03
H20.04
.H28.05
H10.02
H10.0
H16.02
H12.0
Ret. Time B.P.Int
US.Par.1
M.Ut
132
206
148
192
264
90
74
144
88
B.Pk Purity Fit
59
59
59
59
59
59
59
59
59
US. Par. 2
573 800
557 664
554 737
546 698
536 667
534 944
524 915
517 867
514 907
C.A.S. #
80-55-7
20324-33-8
13588-28-8
1638-16-0
20324-34-9
1589-47-5
75-65-0
6321-14-8
584-02-1
RFit
620
767
744
681
770
551
548
552
553
128,
-------
MID LIBRARY SEARCH
08/31/98 22:58:00 + 18:46
SAMPLE: S-MM5-RB 1/3SA/1ML INST. ID:
CONDS.: UG/ML *1ML *100Z/100Z */l/3SA
ENHANCED
F16
NA M
DATA:
CALI:
30068109 #1687
30068109 ft 3
BASE M/Z: 59
RIC: 6712.
1092
SAMPLE
C6.H12.03
1092
M WT 132
B PK 59
RANK 1
# 5786
PUR 573
PROPANOIC ACID, 2-HYDROXY-2-METHYL-, ETHYL ESTER
,u
C10.H22.04
1092
M WT 206
B PK 59
RANK 2
# 24247
PUR 557
,
2-PROPANOL , 1 - [ 2- < 2-METHOXY- 1 -METHYLETHOXY > - 1 -METHYLETHOXY ] -
Ji
"H
1
C7.H16.03
1092
M WT
B PK
'£
RANK 3
# 9228
PUR 554
M/2
1-PROPANOL, 2- < 2-METHOXYPROPOXY >-
*4
50
100
150
200
250
300
350
CO
-------
Library Search Data: 30068109 #1706 Base m/z: 43
08/31/98 22:58:00 + 18:59 Cali: 30068109 # 3 RIC: 5680.
Sample: S-MM5-RB 1/3SA/1ML INST. ID: F16
Conds.: UG/ML *1ML *100X/100% *(NA/NA )/1/3SA NA M
Enhanced (S 158 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
482 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 21960 CYCLOTETRADECANE
2 18479 CYCLOTRIDECANE
3 25479 CYCLOPENTADECANE
4 14780 CYCLCOOOECANE
5 15841 1-UNDECANOL
6 32420 1-HEXADECANOL
7 11075 CYCLODECANE. METHYL-
8 25482 CYCLOPENTANE, DECYL-
9 14765 CYCLOPROPANE, NONYL-
Rank
1
2
3
4
5
6
7
8
9
Formula
C14.H28
C13.H26
C15.H30
C12.H24
C11.H24.0
C16.H34.0
C11.H22
C15.H30
C12.H24
M.Wt
196
182
210
168
172
242
154
210
168
B.Pk
55
41
55
55
55
55
55
41
55
Purity
684
662
661
661
632
628
628
628
620
Fit
871
885
868
882
895
855
904
827
835
RFit
760
729
748
717
670
719
662
720
673
Rank
1
2
3
t>
5
6
7
8
9
Ret.Time
B.P.Int.
US.Par.1
US.Par.2
C.A.S.
295-
295-
295-
294-
112-
36653-
13151-
1795-
74663-
#
17-0
02-3
48-7
62-2
42-5
82-4
43-4
21-7
85-7
-------
MID LIBRARY SEARCH /l/3SA NA M
ENHANCED
-------
Library Search Data: 30068109 #1741 Base m/z: 59
08/31/98 22:58:00 + 19:22 Call: 30068109 # 3 RIC: 11328.
Sample: S-MM5-RB 1/3SA/1ML INST. ID: F16
Conds.: UG/ML *1ML *100%/100% *(NA/NA )/1/3SA NA M
Enhanced (S 15B ZN OT)
62231 spectra in L1BRARYNB searched for maximum PURITY
615 matched at least 6 of the 16 largest peaks in the unknown
Rank In. Name
1 39622 9-OCTADECENAM1DE, (Z)-
2 11721 WONANAMIDE
3 3133 PENTANAMIDE, 4-METHYL-
4 15482 HEPTANAMIDE, 4-ETHYL-5-METHYL-
5 22656 DODECANAHIDE
6 19516 1-DECANOL, 5,9-OIMETHYL-
7 7998 TRANS-3.4-EPOXYNONANE
8 3132 HEXANAMIOE
9 1617 PENTANAMIDE
Rank
1
2
3
4
5
6
7
8
9
Formula
C18.H35.0.N
C9.H19.0.N
C6.H13.0.N
C10.H21.0.N
C12.H25.0.N
C12.H26.0
C9.H18.0
C6.H13.0.N
C5.H11.0.N
Rank
1
2
3
4
5
6
7
8
9
Ret.Time
B.P.Int.
US.Par.1
M.Wt
281
157
115
171
199
186
142
115
101
I
B.Pk Purity Fit RFit
59
59
59
59
59
41
41
59
59
US. Par. 2
561 866
487 894
472 913
461 860
458 852
454 767
438 769
432 866
419 858
C.A.S. #
301-02-0
1120-07-6
1119-29-5
54789-40-1
1120-16-7
91482-38-1
628-02-4
626-97-1
644
498
477
485
515
497
482
437
428
-------
MID LIBRARY SEARCH
08/31/98 22:58:00 + 19:22
SAMPLE: S-MM5-RB 1/3SA/1ML INST. ID:
CONDS.: UG/ML *1ML *100Z/100Z */l/3SA
ENHANCED -
I 1
C9.H19.0.N
1698
M WT 157
B PK 59
RANK 2
# 11721
PUR 487
NONANAMIDE
-Jr-
-4-4
J_
C6.H13.0.N
1698
M WT 115
B PK 59
RANK 3
ft 3133
PUR 472
PENTANAMIDE, 4-METHYL-
M/Z
50
100
150
200
250
300
CO
O)
-------
Library Search Data: 30068109 #1801 Base m/z: 59
08/31/98 22:58:00 + 20:02 Cali: 30068109 # 3 RIC: 8960.
Sample: S-MM5-RB 1/3SA/1ML INST. ID: F16
Conds.: UG/ML *1ML *100%/100% *(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
62231 spectra in L1BRARYNB searched for maximum PURITY
752 matched at least 5 of the 16 largest peaks in the unknown
Rank In. Name
1 34224 2,5,8,11,14-PENTAOXAHEXADECAN-16-OL
2 27502 15-CROWN-5
3 13307 ETHANOL, 2-[2-(2-METHOXYETHOXY)ETHOXY]-
4 17070 2,5,8,11-TETRAOXAOODECANE
5 28000 2,5,8,11,14-PENTAOXAPENTADECANE
6 36510 1,4,7,10,13,16-HEXAOXACYCLOOCTADECANE
7 8813 ETHENE, (2-ETHOXY-1-METHOXYETHOXY)-
8 36865 2,5,8,11,14,17-HEXAOXAOCTADECANE
9 1909 2-PROPANOL, 1-METHOXY-2-METHYL-
Rank
1
2
3
4
5
6
7
8
9
Formula
C11
CIO
C7.
C8.
C10
C12
C7.
C12
C5.
.H24
.H20
H16.
H18.
.H22
.H24
H14.
.H26
H12.
.06
.05
04
04
.05
.06
03
.06
02
M.Wt
252
220
164
178
222
264
146
266
104
B.Pk
45
45
45
59
59
45
59
59
59
Purity
591
538
525
511
506
498
488
484
476
Fit
876
772
827
814
742
767
838
737
864
RFit
632
590
565
532
533
555
504
520
510
Rank Ret.Time B.P.Int. US.Par.1 US.Par.2 C.A.S. #
1 23778-52-1
2 33100-27-5
3 112-35-6
4 112-49-2
5 143-24-8
6 17455-13-9
7 54063-18-2
8 1191-87-3
9 3587-64-2
1 2 ° -
JL (~ *-,\s
-------
MID LIBRARY SEARCH DATA: 30068109 #1801 BASE M/Z: 59
08/31/98 22:58:00 + 20:02 CALI: 30068109 # 3 RIC: 8960.
SAMPLE: S-MM5-RB 1/3SA/1ML INST. ID: F16
CONDS.: UG/ML *1ML * 1002/1 003 */l/3SA NA M
ENHANCED
1048 •
SAMPLE
C11.H24.0
1048 i
M WT 252
B PK 45
RANK 1
# 34224
PUR 591
C10.H20.0!
1048
M WT 220
B PK 45
RANK 2
# 27502
PUR 538
C7.H16.04
1048 -I
gWT 164
PK 45
RANK 3
* 13307
PUR 525
M/2
r
5
r
II 1
..|ll
Y^^*
2,5,8,11, 1 4-PENT AOXAHEXADECAN- 1 6-OL
1,1 J ,
5 15-CROWN-5
r
i
r
II „
i
,11 ,il III , .1. ..
ETHANOL , 2- C 2- < 2-METHOXYETHOXY ) ETHOXY ] -
ii i ii) ii
50 100 150 200 250
CO
O
O
-------
Library Search Data: 30068109 #1834 Base m/z: 59
08/31/9822:58:00+20:24 Cati: 30068109 # 3 RIC: 2840.
Sample: S-MM5-RB 1/3SA/1ML INST. ID: F16
Conds.: UG/ML *1ML *100X/100X *(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
435 matched at least 5 of the 16 largest peaks in the unknown
Rank In. Name
1 329 PROPANE, 2-METHOXY-
2 3132 HEXANAMIDE
3 1618 BUTANAMIDE. 3-METHYL-
4 11721 NONANAMIDE
5 8432 2-HEXANONE. 3-HYDROXY-3.5-DIMETHYL-
6 1694 3-HYDROXY-3-METHYL-2-BUTANONE
7 1617 PENTANAMIDE
8 8871 METHANE, TERT-BUTOXYISOPROPOXY-
9 22656 DOOECANAMIDE
Rank Formula
1
2
3
4
5
6
7
8
9
C4.
C6.
C5.
C9.
C8.
C5.
C5.
C8.
C12
H10.
H13.
H11.
H19.
H16.
H10.
H11.
H18.
.H25
0
O.N
O.N
O.N
02
02
O.N
02
.O.N
M.Wt B.Pk Purity Fit RFit
74
115
101
157
144
102
101
146
199
59
59
59
59
59
59
59
57
59
556
523
510
502
499
474
470
467
463
924
726
780
713
818
834
734
690
640
590
621
614
610
574
541
595
527
633
Rank
1
2
3
4
5
6
7
8
9
Ret.Time
B.P.Int.
US.Par.1
US.Par.2
C.A.S
598
628
541
1120
6321
115
626
4346
1120
, #
53-8
•02-4
46-8
•07-6
•14-8
•22-0
•97-1
•01-4
•16-7
130
-------
1000
SAMPLE
MID LIBRARY SEARCH
08/31/98 22:58:00 + 20:24
SAMPLE: S-MM5-RB 1/3SA/1ML INST. ID:
CONDS.: UG/ML *1ML *1007Z/100Z */l/3SA
ENHANCED
F16
NA M
DATA: 30068109 #1834
CALI: 30068109 # 3
BASE M/Z: 59
RIC: 2840.
-V*
C4.H10.0
1000
M WT 74
B PK 59
RANK 1
# 329
PUR 556
C6.H13.0.
1000
M WT 115
B PK 59
RANK 2
# 3132
PUR 523
PROPANE, 2-METHOXY-
Jbl
,4-
HEXANAMIDE
B
M/Z
C5.H11.0.N
1000
WT 101
PK 59
RANK 3
* 1618
PUR 510
BUTANAMIDE, 3-METHYL-
40
80
100
120
140
160
180
200
220
CO
o
-------
Library Search Data: 30068109 #1916 Base m/z: 43
08/31/98 22:58:00 + 21:19 Cati: 30068109 # 3 RIC: 29632.
Sample: S-MM5-RB 1/3SA/1HL INST. ID: F16
Conds.: UG/ML »1ML *100X/100% *(NA/NA )/1/3SA NA M
Enhanced (S 158 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
818 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 26416 4-TETRADECANOL
2 58701 17-PENTATRIACONTENE
3 39517 3-EICOSENE, (E)-
4 31653 1-HEPTADECENE
5 35206 1-HEPTADECAMOL
6 40232 1-NONADECANOL
7 39516 5-EICOSENE, (E)-
8 39515 9-EICOSENE, (E)-
9 32420 1 -HEXADECANOL
M.Wt B.Pk Purity Fit RFit
Rank
1
2
3
4
5
6
7
8
9
Formula
C14.H30.0
C35.H70
C20.H40
C17.H34
C17.H36.0
C19.H40.0
C20.H40
C20.H40
C16.H34.0
214
490
280
238
256
284
280
280
242
43
43
57
55
55
55
55
57
55
781
777
771
769
769
758
757
757
756
980
941
962
955
978
982
943
944
967
787
812
780
778
773
767
779
780
760
Rank
1
2
3
4
5
6
7
8
9
Ret.Time
B.P.Int.
US.Par.1
US.Par.2
C.A.S
1653
6971
74685
6765
1454
1454
74685
74685
36653
#
33-4
40-0
33-9
39-5
85-9
•84-8
•30-6
29-3
•82-4
1 or
loV.
-------
1428
SAMPLE
C14.H30.0
1428 -.
M WT 214
B PK 43
RANK 1
# 26416
PUR 781
C35.H70
1428 i
M WT 490
B PK 43
RANK 2
# 58701
PUR 777
C20.H40
1428 i
M NT 280
8 PK 57
RANK 3
# 39517 :
PUR 771
W-,J
I
MID LIBRARY SEARCH /l/3SA NA M
ENHANCED
Ul 1 4 f*-^^
^^^
, J 4 ., . .
4-TETRADECANOL
II
1 7-PENTATR I ACONTENE
1
l|l j , ... ;. r , .... f. ...... ( .,.
3-EICOSENE,
-------
Library Search Data: 30068109 #1934 Base m/z: 59
08/31/9822:58:00+21:31 Cali: 30068109 # 3 RIC: 11856.
Sample: S-HM5-RB 1/3SA/1ML INST. ID: F16
Conds.: UG/ML *1ML *100%/100% *(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
265 matched at least 6 of the 16 largest peaks in the unknown
Rank In. Name
1 41712 3,6,9,12,15-PENTAOXANONADECAN-1-OL
2 36510 1,4,7,10,13,16-HEXAOXACYCLOOCTADECANE
3 1909 2-PROPANOL, 1-METHOXY-2-METHYL-
4 34224 2,5,8,11,14-PENTAOXAHEXADECAN-16-OL
5 9227 1,3,3-TRIMETHOXYBUTANE
6 5825 2-PROPANOL, 1-<2-METHYLPROPOXY)-
7 5832 2-PROPANOL, 1-(1-METHYLPROPOXY>-
8 3528 2-METHYL-2,3-PENTANEDIOL
9 8813 ETHENE, (2-ETHOXY-1-METHOXYETHOXY)-
Rank
1
2
3
4
5
6
7
8
9
Formula
C14.H30.06
C12.H24.06
C5.H12.02
C11.H24.06
C7.H16.03
C7.H16.02
C7.H16.02
C6.H14.02
C7.H14.03
Rank
1
2
3
4
5
6
7
8
9
M.Ut B.
294
264
104
252
148
132
132
118
146
.Pk
45
45
59
45
45
57
43
59
59
Purity
478
465
460
447
444
443
433
426
422
Fit
775
776
937
872
718
823
827
846
853
RFit
489
466
464
464
454
457
450
443
422
Ret.Time B.P.Int.
US.Par.1 US.Par.2
C.A.S.
1786-
17455-
3587-
23778
6607
23436
53907
7795
54063
#
94-3
13-9
64-2
52-1
66-5
19-3
95-2
•80-4
•18-2
-------
1560
SAMPLE
MID LIBRARY SEARCH
08x31/98 22:58:00 + 21:31
SAMPLE: S-MM5-RB 1/3SA/1ML INST. ID:
CONDS.: UG/ML *1ML *IQQ7./IQQ7. *
F16
NA M
DATA: 30068109 #1934
CALI: 30068109 # 3
BASE M/Z: 59
RIC: 11856.
.I
C14.H30.06
1560
M WT 294
B PK 45
RANK 1
# 41712
PUR 478
3,6,9,12,15-PENTAOXANONADECAN-l-OL
I I
C12.H24.06
1560
M WT 264
B PK 45
RANK 2
tt 36510
PUR 465
1,4,7,10,13,16-HEXAOXACYCLOOCTADECANE
C5.H12.02
M/Z
2-PROPANOL, 1-METHOXY-2-METHYL-
IDbtf i
M WT 104
B PK 59
RANK 3
* 1909
PUR 460
r
,ll. .il| ,1.
, • -1
50
100
150
200
250
-------
Library Search Data: 30068109 #1940 Base m/z: 59
08/31/9822:58:00+21:35 Cali: 30068109 # 3 RIC: 8400.
Sample: S-MM5-RB 1/3SA/1ML INST. ID: F16
Conds.: UG/ML «1ML *100X/100% *(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
400 matched at least 5 of the 16 largest peaks in the unknown
Rank In. Name
1 9227 1,3,3-TRIMETHOXYBUTANE
2 27502 15-CROUN-5
3 1909 2-PROPANOL, 1-METHOXY-2-METHYL-
4 24247 2-PROPANOL, 1-[2-(2-METHOXY-1-METHYLETHOXY)-1-METHYLETHOXY]-
5 1919 1-BUTANOL, 3-METHOXY-
6 36510 1,4,7,10,13,16-HEXAOXACYCLOOCTADECANE
7 41712 3,6,9,12,15-PENTAOXANONADECAN-1-OL
8 9235 1-PROPANOL, 2-(2-METHOXY-1-METHYLETHOXY)-
9 3528 2-METHYL-2.3-PENTANEDIOL
Rank Formula
1
2
3
4
5
6
7
8
9
C7.H16.03
C10.H20.05
C5.H12.02
C10.H22.04
C5.H12.02
C12.H24.06
C14.H30.06
C7.H16.03
C6.H14.02
Rank
1
2
3
4
5
6
7
8
9
M.Ut
148
220
104
206
104
264
294
148
118
B.Pk
45
45
59
59
59
45
45
59
59
Purity
441
438
436
418
418
406
404
398
394
Fit
695
648
882
738
811
661
648
763
793
RFit
488
528
457
448
431
487
496
408
432
Ret.Time
B.P.Int.
US.Par.1 US.Par.2
C.A.S
6607
33100
3587
20324
2517
17455
1786
55956
7795
. #
•66-5
•27-5
•64-2
33-8
•43-3
•13-9
94-3
21-3
•80-4
1307
-------
MID LIBRARY SEARCH (LIBRARYNB)
08/31/98 22:58:00 + 21:35
SAMPLE: S-MM5-RB 1/3SA/1ML INST. ID:
CONDS.: UG/ML *1ML *100Z/100Z *
0)
-------
Library Search Data: 30068109 #1966
08/31/98 22:58:00 + 21:52 Cali: 30068109 # 3
Sample: S-MM5-RB 1/3SA/1ML INST. ID: F16
Conds.: UG/ML *1ML *100%/100% *(NA/NA )/1/3SA NA H
Enhanced (S 15B 2N OT)
Base m/z: 59
RIC: 3004.
62231 spectra in LIBRARYNB searched for maximum PURITY
783 matched at least 5 of the 16 largest peaks in the unknown
Rank In. Name
1 19528 3-DOOECANOL
2 12059 4-ETHYL-3-OCTANOL
3 12057 3-DECANOL
4 3237 4-HYDROXY-3-HEXANONE
5 9228 1-PROPANOL, 2-(2-METHOXYPROPOXY)-
6 12062 3-OCTANOL, 6-ETHYL-
7 15851 2-METHYL-2-DECANOL
8 15839 5-ETHYL-3-NONANOL
9 8506 4,5-OIMETHYL-3-HEPTANOL
Rank
1
2
3
4
5
6
7
8
9
Formula
C12
C10
C10
C6.
C7.
C10
C11
C11
C9.
.H26.0
.H22.0
.H22.0
H12.02
H16.03
.H22.0
.H24.0
.H24.0
H20.0
M.Ut B.Pk Purity Fit RFit
186
158
158
116
148
158
172
172
144
59
59
59
59
59
59
59
57
59
391
365
356
355
348
341
339
338
338
789
887
792
770
792
755
731
719
824
450
397
401
366
380
401
400
398
403
Rank
1
2
3
4
5
6
7
8
9
Ret.Time B.P.lnt.
US.Par.1
US.Par.2
C.A.S. *
10203-30-2
19781-26-1
1565-81-7
4984-85-4
13588-28-8
19781-27-2
3396-02-9
-{ r< r •:
_L o ^ *.
-------
MID LIBRARY SEARCH CLIBRARYNB) DATA: 30068109 #1966 BASE M/Z: 59
08/31/98 22:58:00 + 21:52 CALI: 30068109 # 3 RIC: 3004.
SAMPLE: S-MM5-RB 1/3SA/1ML INST. ID: F16
CONDS.: UG/ML *1ML *100Z/100Z *
1000 •
SAMPLE
C12.H26.0
1000 1
M WT 186
B PK 59
RANK 1
* 19528 '
PUR 391
C10.H22.0
1000 1
M WT 158
B PK 59
RANK 2
tt 12059 '
PUR 365
C10.H22.0
1000 I
M WT 158
B PK 59
RANK 3
# 12057
PUR 356
1
J
r
' ' ' ' 1'
r
r
,
r
i
,
1
UV>L^
ill ll ll 1 Illl . ,1. I.I ... .,.11 . . I.. 1 . L-
3-DODECANOL
1
1
1
4-ETHYL-3-OCTANOL
,
1
1 1 .
ii'i'i i i • • i i i i • • • • — i • --•••--- i • - • i • i
3-DECANOL
I
k
. ll .. . , JL , , , , , , r-
M/Z
40
60
80
100
120
140
160
180
200
Co
c >
-------
Library Search
08/31/98 22:58:00 •
Sample: S-MM5-RB
Conds.: UG/ML *1ML
Data: 30068109 #2014
• 22:24 Cali: 30068109 # 3
1/3SA/1ML INST. ID: F16
*100%/100% *(NA/NA )/1/3SA NA M
Base m/z: 43
R1C: 14592.
Enhanced (S 15B 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
950 matched at least 7 of the 16 largest peaks in the unknown
Rank In.
1 39515 9-
2 39516 5-
3 34410 3
4 37062 1-
5 34418 9-
6 34411 5-
7 31653 1-
8 39517 3-
9 26416 4
Name
EICOSENE, (E)-
EICOSENE, (E)-
OCTADECENE, (E)-
NONADECENE
OCTADECENE, (E)-
OCTADECENE, (E)-
HEPTADECENE
EICOSENE, (E)-
TETRADECANOL
Rank
1
2
3
4
5
6
7
8
9
Formula
C20.H40
C20.H40
C18.H36
C19.H38
C18.H36
C18.H36
C17.H34
C20.H40
C14.H30.0
Rank
1
2
3
4
5
6
7
8
9
H.Wt B.Pk Purity Fit RFit
280
280
252
266
252
252
238
280
214
55
55
69
97
55
55
55
57
43
729
728
718
717
716
716
715
713
711
949
947
938
948
935
934
942
951
970
741
741
734
737
730
730
728
725
721
Ret.Time
B.P.lnt.
US.Par.1
US.Par.2
C.A.S
74685
74685
7206
18435
7206
7206
6765
74685
1653
, #
29-3
•30-6
•19-1
•45-5
•25-9
•21-5
-39-5
•33-9
-33-4
-------
MID LIBRARY SEARCH (LIBRARYNB) DATA:
08/31/98 22:58:00 + 22:24 CALI:
SAMPLE: S-MM5-RB 1/3SA/1ML INST. ID: F16
CONDS.: UG/ML *1ML *100Z/100Z *-
||
1
1 » li i.
C18.H36
1111 -i
M WT 252
B PK 69
RANK 3
* 34410
PUR 718
3-OCTADECENE, -
||
1 1 .„ ,
M/Z
50
100
150
200
250
r \
-------
Library Search Data: 30068109 #2051 Base m/z: 59
08/31/9822:58:00+22:49 Cati: 30068109 # 3 RIC: 5984.
Sample: S-MM5-RB 1/3SA/1ML INST. ID: F16
Conds.: UG/ML *1ML *100%/100% *(NA/NA }/1/3SA NA H
Enhanced (S 15B 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
363 matched at least 6 of the 16 largest peaks in the unknown
Rank In. Name
1 1909 2-PROPANOL, 1-METHOXY-2-METHYL-
2 27502 15-CROWN-5
3 9228 1-PROPANOL, 2-{2-METHOXYPROPOXY)-
4 9227 1,3,3-TRlMETHOXYBUTANE
5 8822 BUTANOIC ACID, 4-ETHOXY-, METHYL ESTER
6 8871 METHANE, TERT-BUTOXYISOPROPOXY-
7 36510 1,4,7,10,13,16-HEXAOXACYCLOOCTADECANE
8 12385 BUTYRIC ACID, 4-ISOPROPOXY-, METHYL ESTER
9 5826 2-PROPANOL, 1-ISOPROPOXY-2-METHYL-
Rank
1
2
3
4
5
6
7
8
9
Formula
C5.H12.02
C10.H20.05
C7.H16.03
C7.H16.03
C7.H14.03
C8.H18.02
C12.H24.06
C8.H16.03
C7.H16.02
M.Wt
104
220
148
148
146
146
264
160
132
B.Pk
59
45
59
45
59
57
45
101
59
Purity
471
458
443
430
425
419
413
413
412
Fit
922
634
798
661
719
791
654
694
641
RFit
486
535
461
457
522
435
477
459
484
Rank
1
2
3
4
5
6
7
8
9
Ret.Time
B.P.Int.
US.Par.1 US.Par.2
C.A.S. #
3587-64-2
33100-27-5
13588-28-8
6607-66-5
29006-04-0
4346-01-4
17455-13-9
29006-05-1
3587-75-5
_L O JL O
-------
MID LIBRARY SEARCH (LIBRARYNB)
08/31/98 22:58:00 + 22:49
SAMPLE: S-MM5-RB 1/3SA/1ML INST. ID:
CONDS.: UG/ML *1ML *100Z/100Z *
F16
NA M
DATA: 300G8109 #2051
CALI: 30068109 # 3
BASE M/Z: 59
RIC: 5984.
1479
SAMPLE
C5.H12.02
1479
M WT 104
B PK 59
RANK 1
tt 1909
PUR 471
2-PROPANOL, l-METHOXY-2-METHYL-
C10.H20.05
1479
M WT 220
B PK 45
RANK 2
# 27502
PUR 458
15-CROWN-5
_JL
C7.H16.03
1479
M WT 148
B PK 59
RANK 3
# 9228
PUR 443
1-PROPANOL, 2-< 2-METHOXYPROPOXY >-
M/Z
50
100
150
200
259
-------
Library Search
08/31/98 22:58:00 <
Sample: S-MM5-RB
Conds.: UG/HL *1ML
Data: 30068109 #2057
22:53 Cali: 30068109 # 3
1/3SA/1ML 1NST. ID: F16
*100%/100X *
-------
MID LIBRARY SEARCH -^
1 , 3 , 3-TR I METHOXYBUTANE
3.6,9, 12, 15-PENTAOXANONADECAN-l-OL
1
ll ll ll _.._. .1 . : — , . . . . .—
1 -ETHOXYPENTAN-3-OL
h
j i.
50
100 150 200 250 300
I-1
-------
TIC SELECTION REPORT
DATA FILE: 30068109
THE FOLLOWING PEAKS WERE REJECTED BECAUSE
AT LEAST 40 % OF THEIR SIZE WAS ACCOUNTED FOR BY
TARGET COMPOUNDS ELUTING WITHIN 4 SCANS OF THE
PEAK TOP.
SCAN SIZE AMOUNT
198
308
340
421
529
722
827
968
1085
1383
1383
1551
1782
273224.
328440.
229200.
136284.
285638.
317824.
341992.
294902.
330432.
308168.
308168.
210168.
186560.
38.262
45.994
32.097
19.085
40.000
37.173
40.000
35.699
40.000
58.652
58.652
40.000
40.000
TOTAL NUMBER OF UNIDENTIFIED PEAKS WITH SIZE
GREATER THAN 10 % OF THE CLOSEST INTERNAL STANDARD
THAT DOES NOT HAVE INTERFERENCES = 25
INTERNAL STANDARDS THAT HAVE RIC SIZE LESS THAN
50 % OR GREATER THAN 200 % OF THE ESTIMATED RIC SIZE
ARE CONSIDERED TO HAVE INTERFERENCES AND WILL NOT BE USED
FOR QUANT ITAT ION.
PERCENT OF
ESTIMATED
# INTERNAL STANDARD RIC SIZE RIC SIZE SCAN
1 CI40 NAPHTHALENE-08
2 CI50 ACENAPHTHENE-D10
3 CI60 PHENANTHRENE-D10
4 CI70 CHRYSENE-D12
5 CI75 PERYLENE-D12
285638.
341992.
330432.
210168.
186560.
130
127
118
120
122
529
827
1085
1551
1782
* INDICATES INTERFERENCE
SIZE = AREA
lo
ol
-------
Semivolatile Organics
Method 0010/8270
Client Name:
Client ID:
LAB ID:
Matrix:
Authorized:
Pacific Environmental Services
S-MM5-4-F,FH,XAD,COND,BH
300681-0010-SA
AIRTRAIN Sampled: 25 JUL 98
30 JUL 98 Prepared: 31 JUL 98
Dilution Factor: 100
Parameter
Phenol
bis(2-Chloroethyl)ether
2-Chlorophenol
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Benzyl alcohol
1,2-Di chlorobenzene
2-Methylphenol
2,2'-Oxybis(l-chloropropane)
3/4-Methylphenol
N-Nitroso-di-n-propylamine
Hexachloroethane
Nitrobenzene
Isophorone
2-Nitrophenol
2,4-Dimethylphenol
Benzoic acid
bi s(2-Chloroethoxy)-methane
2,4-Dichlorophenol
1,2,4-Tri chlorobenzene
Naphthalene
4-Chloroaniline
Hexachlorobutadi ene
4-Chloro-3-methylphenol
2-Methyl naphtha!ene
HexachIorocyclopentadi ene
2,4,6-Tri chlorophenol
2,4,5-Trichlorophenol
2-Chloronaphthalene
2-Nitroaniline
Dimethyl phthalate
Acenaphthylene
3-Nitroaniline
Acenaphthene
2,4-Dinitrophenol
Wet wt.
Result
Units
Re
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1500
ND
ND
ND
2300
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ug/Sampl e
ug/ Sample
ug/Sampl e
ug/Sampl e
ug/Sampl e
ug/Sampl e
ug/Sampl e
ug/Sampl e
ug/Sampl e „
ug/ Sample
ug/Sampl e
ug/Sampl e
ug/Sampl e
ug/Sampl e
ug/Sampl e
ug/Sampl e
ug/ Sample
ug/Sampl e
ug/Sampl e
ug/Sampl e
ug/ Sample
ug/Sampl e
ug/Sampl e
ug/Sampl e
ug/Sampl e
ug/Sampl e
ug/Sampl e
ug/ Sample
ug/Sampl e
ug/Sampl e
ug/Sampl e
ug/ Sample
ug/ Sample
ug/Sampl e
ug/ Sample
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
15000
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
15000
3000
3000
3000
3000
15000
3000
15000
Received: 30 JUL 98
Analyzed: 31 AUG 98
Qualifier
GR
Note G = Reporting limit(s) raised due to matrix interference.
Note J = Result is detected below the reporting limit or is an estimated concentration.
Note R = Reporting limit(s) raised due to sample volume limitations.
ND = Not Detected
Reported By: Emily Uebelhoer
Approved By: Mike Orbanosky
The cover letter is an integral part of this report.
Rev 230787
-------
Semivolatile Organics
Method 0010/8270
(cont.
Client Name: Pacific Environmental Services
Client ID:
LAB ID:
Matrix:
Authorized:
S-MM5-4-F,FH,XAD,COND,BH
300681-0010-SA
AIRTRAIN
30 JUL 98
Sampled: 25 JUL 98
Prepared: 31 JUL 98
Dilution Factor: 100
Parameter
4-Nitrophenol
Dibenzofuran
2,4-Dinitrotoluene
2,6-Dinitrotoluene
Diethy] phthalate
4-Chlorophenyl phenyl ether
Fluorene
4-Nitroaniline
4,6-Dinitro-2-methylphenol
N-Nitrosodiphenylamine
4-Bromophenyl phenyl ether
Hexachlorobenzene
Pentachlorophenol
Phenanthrene
Anthracene
Di-n-butyl phthalate
Fluoranthene
Pyrene
Butyl benzyl phthalate
3,3'-Dichlorobenzidine
Benzo(a)anthracene
bi s(2-Ethylhexyl)-phthalate
Chrysene
Di-n-octyl phthalate
Wet wt.
Result
Benzo(b.
Benzofk
Benzo(a
Indenof
fluorantnene
fluoranthene
pyrene
,2,3-cd)pyrene
Dibenz(a,hjanthracene
Benzo(g,h,i)perylene
Acetophenone
4-Aminobiphenyl
Aniline
Benzidine
3,3'-Dimethylbenzidine
N-Nitrosodimethylamine
N-Nitrosomorpholine
Units
Received: 30 JUL 98
Analyzed: 31 AU6 98
Re
porting
Limit
Qualifier
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
590
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sampl e
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sampl e
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sampl e
ug/Sample
ug/Sampl e
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sampl e
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
15000
3000
3000
3000
3000
3000
3000
15000
15000
3000
3000
3000
15000
3000
3000
3000
3000
3000
3000
6000
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
15000
3000
30000
6000
3000
3000
Note J = Result is detected below the reporting limit or is an estimated concentration.
ND = Not Detected
Reported By: Emily Uebelhoer
Approved By: Mike Orbanosky
The cover letter is an integral part of this report.
Rev 230787
-------
Semi volatile Organics
Method 0010/8270
(cont.)
Client Name:
Client ID:
LAB ID:
Matrix:
Authorized:
Pacific Environmental Services
S-MM5-4-F,FH,XAD,COND,BH
300681-0010-SA
AIRTRAIN Sampled:
30 JUL 98 Prepared:
25 JUL 98
31 JUL 98
Dilution Factor: 100
Parameter
Pentachloronitrobenzene (PCNB)
o-Toluidine
2-Methoxybenzenamine
Biphenyl
Chioroacetophenone
Cumene
DBCP (l,2-Dibromo-3-chloropropane)
Benzo(e)pyrene
N-N-Diethylaniline
Dimethylaniline
3,3'-Dimethoxybenzidine
Hydroquinone
4,4'-Methyl-bis(2-chloroaniline)
4-Nitrodiphenyl
Trifluralin
Wet wt.
Result
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Units
ug/Sample
ug/Sampl e
ug/Sample
ug/Sample
ug/Sample
ug/Sampl e
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sampl e
ug/Sample
Reporting
Limit
15000
6000
--
--
--
--
--
--
--
--
--
--
--
--
--
Received: 30 JUL 98
Analyzed: 31 AUG 98
Qualifier
Surrogate
Nitrobenzene-d5
2-Fluorobiphenyl
Terphenyl-dl4
Phenol-d5
2-Fluorophenol
2,4,6-Tri bromophenol
Recovery
ND %
ND %
ND
ND
ND
ND
Acceptable Range
45 - 107
62 - 110
58 - 135
43 - 130
36 - 111
58 - 131
H
Note H = Spiked analyte not detected because of required sample dilution.
ND = Not Detected
Reported By: Emily Uebelhoer
Approved By: Mike Orbanosky
The cover letter is an integral part of this report.
Rev 230787
-------
Semivolatiles Library Search (20 Compound TID)
Method 8270
Client Name:
Client ID:
LAB ID:
Matrix:
Authorized:
Pacific Environmental Services
S-MM5-4-F,FH,XAD,COND,BH
300681-0010-SA
AIRTRAIN Sampled;
30 JUL 98 Prepared:
25 JUL 98
NA
Dilution Factor: 100
Parameter Result Units
Undecane 7600 ug/Sample
Unknown 7500 ug/Sample
Unknown alkane 7100 ug/Sample
Decane, 2,5,9-Trimethyl- 6200 ug/Sample
Unknown 12000 ug/Sample
Unknown alkane 12000 ug/Sample
Unknown hydrocarbon 6900 ug/Sample
Octane, 3,5-dimethyl- 9800 ug/Sample
Unknown 6400 ug/Sample
Heptadecane, 2,6-dimethyl- 13000 ug/Sample
Tetradecane 18000 ug/Sample
Unknown 8600 ug/Sample
Heptadecane, 2,6,10,14 -tetramethyl- 12000 ug/Sample
Pentadecane 14000 ug/Sample
Unknown 6400 ug/Sample
Nonadecane 16000 ug/Sample
Undecane, 2,6-dimethyl- 13000 ug/Sample
Heptadecane, 2,6-dimethyl- 28000 ug/Sample
Unknown alkane 7600 ug/Sample
Heptadecane, 2,6-dimethyl- 9800 ug/Sample
Received: 30 JUL 98
Analyzed: 31 AUG 98
Reporting
Limit Qualifier
0
0
0
0
0
0
0
0
0
Note 0 = Or structurally similar compound (isomer).
NA = Not Applicable
Reported By: Emily Uebelhoer
Approved By: Mike Orbanosky
The cover letter is an integral part of this report.
Rev 230787
-------
Sample: S-MM5-4
Client: PACIF1
Analyst: DAT
OUANTERRA GC/MS
Target Compound Data Summary Sheet
1/3SA/100M
Instrument ID: F16
Quan List Threshold: 0.95
Data File: 30068110
Std Id: ST16980831
INST. ID: F16
Date Analyzed: 08/31/98 23:28
Run Factor: 300.
Surrogate Vol.:
100.
Surrogate
CS20 NITROBENZENE-DS
CS25 2-FLUOROBIPHENY
CS30 TERPHENYL-D14
CS45 PHENOL-D5
CS50 2-FLUOROPHENOL
CS55 2,4,6-TRIBROMOP
Surrogate Spike Recoveries
8270-G, LIMS 10/10/96
Surrogate Amount (ug)
Spiked Measured
X Recovery
Measured OC limits
50.0
50.0
50.00
100.
190.0
100.0
BDL
BDL
122.0
BDL
116.0
127.0
o* H
0*
244.
0*
116.
127. \
45
62
*
43
*
/
107
110
58
130
36
58
135
111
131
Parameter
Target Compounds: SAP9
Scan
HEXACHLOROBENZENE-C13
C310 N-NITROSOOIMETHYLAMINE
PYRIDINE
2-PICOLINE
N-NITROSOMETHYLETHYLAMINE
METHYLMETHANESULFONATE
N-NITROSODIETHYLAMINE
ETHYLMETHANE SULFONATE
PENTACHLOROETHANE
C320 ANILINE
C315 PHENOL
C325 BIS(2-CHLOROETHYL)ETHER
C330 2-CHLOROPHENOL
C335 1,3-DICHLOROBENZENE
C340 1,4-DICHLOROBENZENE
C345 BENZYL ALCOHOL
C350 1,2-DICHLOROBENZENE
C355 2-METHYLPHENOL
C360 2,2'-OXYBIS(1-CLPROPAN)
C361 ACETOPHENONE
N-N1TROSOPYRROL1DINE
N-NITROSOMORPHOLINE
3-METHYL PHENOL
C365 4-METHYLPHENOL
C370 N-NITROSO-Dl-N-PROPYLAM
0-TOLUIDINE
C375 HEXACHLOROETHANE
C410 NITROBENZENE
N-NITROSOPIPERIDINE
Reporting
Result
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Units
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
Reviewed by:
Limit
3000.
3000.
0
0
6000.0
3000.
3000.
3000.
3000.
0
0
0
0
3000.0
3000.
0
3000.0
3000.0
3000.0 /
3000.
3000.
3000.
3000.
3000.
3000.
3000.
3000.
0 '
0
0
0
0
0
0
0
3000.0
3000.0
3000.0
3000.
3000.
3000.
3000.
3000.
3000.
II .
m
0
0
0
0
0
0
\
» °h\\
vUr *>/'/''
•
-------
QUANTERRA GC/MS
Target Compound Data Summary Sheet
Sample: S-MM5-4
Client: PAC1FI
Analyst: OAT
1/3SA/100M
INST. ID:
Instrument ID: F16
Data File: 30068110
Std Id: ST16980831
F16
Date Analyzed: 08/31/98 23:28
Run Factor: 300.
Quan List Threshold: 0.95
Surrogate Vol.:
100.
Target Compounds: SAP9
Parameter
C415 ISOPHORONE
C420 2-NITROPHENOL
C425 2,4-DIMETHYLPHENOL
C435 BIS(2-CHLOROETHOXY)METH
C440 2,4-DlCHLOROPHENOL
C430 BENZOIC ACID
AA-DIMETHYLPHENETHYLAMINE
C445 1,2.4-TRICHLOROBENZENE
C450 NAPHTHALENE
C455 4-CHLOROANALINE
2,6-DICHLOROPHENOL
HEXACHLOROPROPENE
C460 HEXACHLOR08UTADIENE
P-PHENYLENE DIAMINE
N-NITROSOOI-N-BUTYLAMINE
C465 4-CHLORO-3-METHYLPHENO
SAFROLE
C470 2-METHYLNAPHTHALENE
1,2,4,5-TETRACHLOROBENZENE
ISOSAFROLE (#1)
C510 HEXACHLOROCYCLOPENTAD I
C515 2,4,6-TRICHLOROPHENOL
C520 2,4,5-TRICHLOROPHENOL
ISOSAFROLE (#2)
C525 2-CHLORONAPHTHALENE
1-CHLORONAPHTHALENE
C530 2-NITROANALINE
1,4-NAPHTHOQUINONE
C535 D1METHYLPHTHALATE
1,3-OINITROBENZENE
C540 ACENAPHTHYLENE
C543 2,6-OINITROTOLUENE
C545 3-NITROAN1LINE
C550 ACENAPHTHENE
C555 2,4-DINITROPHENOL
C565 DIBENZOFURAN
C560 4-NITROPHENOL
PENTACHLOROBENZENE
C570 2,4-DINITROTOLUENE
1-NAPHTHYLAMINE
2-NAPHTHYLAMINE
2,3,4,6-TETRACHLOROPHENOL
C580 DIETHYLPHTHALATE
C590 FLUORENE
lesutt Units
NO UG/A
ND UG/A
NO UG/A
NO UG/A
ND UG/A
ND UG/A
NO UG/A
NO^-— -V UG/A
W/£«3W UG/A
NCT-— — UG/A
NO UG/A
ND UG/A
ND UG/A
ND UG/A
ND UG/A
ND UG/A
ND^—- — *VUG/A
,MF2-3^/UG/A
Nff*-— — ^ UG/A
ND UG/A
ND UG/A
NO UG/A
ND UG/A
ND UG/A
ND UG/A
ND UG/A
NO UG/A
NO UG/A
NO UG/A
ND UG/A
ND UG/A
NO UG/A
ND UG/A
NO UG/A
ND UG/A
ND UG/A
ND UG/A
ND UG/A
ND UG/A
ND UG/A
ND UG/A
ND UG/A
ND UG/A
ND UG/A
Reporting
Limit
3000.0
3000.0
3000.0
3000.0
3000.0
15000.0
3000.0
3000.0
3000.0 "5~
3000.0
3000.0
3000.0
3000.0
3000.0
3000.0
3000.0
3000.0
3000.0 1
3000.0
6000.0
3000.0
3000.0
3000.0
6000.0
3000.0
1500.0
15000.0
3000.0
3000.0
3000.0
3000.0
3000.0
15000.0
3000.0
15000.0
3000.0
15000.0
3000.0
3000.0
3000.0
3000.0
6000.0
3000.0
3000.0
-------
OUANTERRA GC/MS
Target Compound Data Summary Sheet
Data File: 30068110
Std Id: ST16980831
Sample: S-MM5-4
Client: PACIF1
Analyst: DAT
1/3SA/100M
INST. ID: F16
Instrument ID: F16
Date Analyzed: 08/31/98 23:28
Run Factor: 300.
Quan List Threshold: 0.95
Surrogate Vol.:
100.
Target Compounds: SAP9
Parameter
C585 4-CHLOROPHENYL-PHENYLE
5-NITRO-O-TOLUIDINE
C595 4-NITROANALINE
C610 4.6-DINITRO-2-METHYLPH
C615 N-NITROSODIPHENYLAM1NE
C620 AZOBENZENE
SYM-TRINITROBENZENE
C625 4-BROMOPHENYL-PHENYLET
PHENACETIN
DIAL LATE 234
C630 HEXACHLOROBENZENE
4-AMINOBIPHENYL
C635 PENTACHLOROPHENOL
PRONAMIDE
PENTACHLORONITROBENZENE
C640 PHENANTHRENE
C645 ANTHRACENE
2SECBUTYL-4,6-DINITROPHENOL
C647 CARBAZOLE
C650 DI-N-BUTYLPHTHALATE
4-NITROQUINOLINE-1-OXIDE
METHAPYRILENE
ISODRIN
C655 FLUORANTHENE
CHLOROBENZILATE
C710 BENZIDINE
C715 PYRENE
ARAM1TE (#1)
ARAMITE (#2)
P-DIMETHYLAMINOAZOBENZENE
3,3'-DIMETHYLBENZIDINE
KEPONE
C720 BUTYLBENZYLPHTHALATE
2-ACETYLAMINOFLUORENE
C730 BENZO(A)ANTHRACENE
C725 3,3'-DICHLOROBENZIDINE
C740 CHRYSENE
C745 BIS(2-ETHYLHEXYL)PHTHA
3-METHYLCHOLANTHRENE
C760 DI-N-OCTYL PHTHALATE
C765 BENZO(B)FLUORANTHENE
7,12-DlMETHYLBENZANTHRACENE
C770 BENZO(K)FLUORANTHENE
HEXACHLOROPHENE
!SUlt
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND^- — -^
Wf£2jO
NF '
ND
NO
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Units
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
) UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
Reporting
Limit
3000.0
3000.0
15000.0
15000.0
3000.0
3000.0
3000.0
3000.0
3000.0
3000.0
3000.0
3000.0
15000.0
3000.0
15000.0
3000.0
3000.0
3000.0
3000.0
3000.0
3000.0
3000.0
3000.0
3000.0
3000.0
30000.0
3000.0
3000.0
3000.0
3000.0
3000.0
15000.0
3000.0
3000.0
3000.0
6000.0
3000.0
3000.0
3000.0
3000.0
3000.0
3000.0
3000.0
3000.0
-------
QUANTERRA GC/MS
Target Compound Data Summary Sheet
Data File: 30068110
Std Id: ST16980831
Sample: S-MM5-4 1/3SA/100H INST. ID: F16
Client: PACIFI Date Analyzed: 08/31/98 23:28
Analyst: DAT Instrument ID: F16 Run Factor: 300.
Quan List Threshold: 0.95 Surrogate Vol.: 100.
Parameter
Target Compounds: SAP9
Scan Result Units
Reporting
Limit
C775 BENZO(A)PYRENE
C780 INDENO(1,2,3-CD)PYRENE
C785 DIBENZ(A,H)ANTHRACENE
C790 BENZO(G,H,I)PERYLENE
ND
ND
ND
ND
UG/A
UG/A
UG/A
UG/A
3000.0
3000.0
3000.0
3000.0
-------
DATA FROM FILE: 30068110 SCANS 33 TO 1203 ACQUIRED: 08/31/98 23:28:90
CALI: 30068110 #3
SAMPLE: S-MM5-4 1/3SA/100M INST. ID: F16
CONDS.: UG/ML *100ML *100Z/100Z *
-------
DATA FROM FILE: 30068110 SCANS 1203 TO 2158 ACQUIRED: 08/31/98 23:28:00
CALI: 30068110 #3
SAMPLE: S-MM5-4 1/3SA/100M INST. ID: F16
CONDS.: UG/ML *100ML *100Z/100Z *
-------
STANDARD USED FOR THIS REPORT IS ST16980831 REPORT PRINTED: 9/02/98 1:09:56
ADDITIONAL STANDARD USED FOR THIS REPORT IS: ST16980831A
QUANTERRA QUANT1TATION SUMMARY File: 30068110
Sample: S-MM5-4 1/3SA/100M
Analyst:
Compounds
INST.
DAT Instrument Id:
with amounts less than
0.20
ID
F16
: F16
reported as
Analyzed
NOT FOUND
: 08/31/98
Library
No
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
Entry
S1# 1
S2# 1
S3# 1
S4# 1
S5# 1
S6# 1
S2# 2
S3# 3
S5# 2
S1# 3
S1# 2
S3# 2
S4# 4
S1# 15
S1# 20
S1# 30
S1# 40
S1# 60
S1# 70
S1# 85
S1# 95
S1#100
sinos
S1#110
S1#115
S1#125
S1#130
S1#145
S10150
SU160
S1#165
S1#170
51*175
S1#180
S13182
S1#185
S1#190
SKK195
S1#200
S2# 10
S2# 15
S2# 20
S2# 25
S2# 30
S2# 35
Name
CI30 1,4-DICHLOROBENZENE
CI40 NAPHTHALENE -D8
CI50 ACENAPHTHENE-D10
CI60 PHENANTHRENE-D10
CI70 CHRYSENE-D12
CI75 PERYLENE-D12
CS20 NITROBENZENE-DS
CS25 2-FLUOROBIPHENYL
CS30 TERPHENYL-D14
CS45 PHENOL -D5
CS50 2-FLUOROPHENOL
CS55 2,4,6-TRIBROMOPHENO
HEXACHLOROBENZENE-C13
C310 N-NITROSOOIMETHYLAM
PYRIDINE
2-PICOLINE
N-NITROSOMETHYLETHYLAMIN
METHYLMETHANESULFONATE
N-NITROSODIETHYLAMINE
ETHYLMETHANE SULFONATE
PENTACHLOROETHANE
C320 ANILINE
C315 PHENOL
C325 8IS(2-CHLOROETHYL)E
C330 2-CHLOROPHENOL
C335 1,3-D1CHLOROBENZENE
C340 1,4-DICHLOROBENZENE
C345 BENZYL ALCOHOL
C350 1,2-DICHLOROBENZENE
C355 2-METHYLPHENOL
C360 2,2'-OXYBIS(1-CLPRO
C361 ACETOPHENONE
N-NITROSOPYRROLIDINE
N-NITROSOMORPHOLINE
3-METHYL PHENOL
C365 4-METHYLPHENOL
C370 N-NITROSO-OI-N-PROP
0-TOLUIDINE
C375 HEXACHLOROETHANE
C410 NITROBENZENE
N-NITROSOPIPERIDINE
C415 ISOPHORONE
C420 2-NJTROPHENOL
C425 2,4-DIMETHYLPHENOL
C435 BIS(Z-CHLOROETHOXY)
Mass
152
136
164
188
240
264
82
172
244
99
112
330
294
74
79
93
42
80
102
79
117
93
94
93
128
146
146
108
146
108
45
105
100
56
108
108
70
106
117
77
42
82
139
107
93
Meth
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
VB
BB
SB
BB
BB
BV
BB
BB
VB
VV
B8
BB
BV
BB
BV
BB
VB
BB
BB
BB
Scan Ref Area
340 1
530 2
829 3
1087 4
1552 5
1783 6
424 2
723 3
1384 5
1 NOT
206 1
970 3
4 NOT
1 NOT
1 NOT
1 NOT
1 NOT
1 NOT
1 NOT
1 NOT
306 1
1 NOT
311 1
318 1
1 NOT
1 NOT
1 NOT
1 NOT
1 NOT
392 1
394 1
1 NOT
1 NOT
1 NOT
1 NOT
419 1
412 1
1 NOT
1 NOT
2 NOT
449 2
2 NOT
2 NOT
499 2
2 NOT
31781 .
115218.
63489.
109667.
68491.
54962.
535.
1682.
2079.
FOUND
1264.
474.
FOUND
FOUND
FOUND
FOUND
FOUND
FOUND
FOUND
FOUND
252.
FOUND
1812.
221.
FOUND
FOUND
FOUND
FOUND
FOUND
1358.
2002.
FOUND
FOUND
FOUND
FOUND
1696.
677.
FOUND
FOUND
FOUND
763.
FOUND
FOUND
791.
FOUND
Units:
RRF(L)
1.000
1
1
.000
.000
1.000
1
1
0
.000
.000
.470
1.234
0.995
1
0
0
1
1
1
2
1
0
0
0
.368
.236
.602
.968
.368
.175
.539
.276
.906
.320
.330
23:28
UG/ML
Amount
40
40
40
40
40
40
0
0
1
1
1
0
1
0
1
0
1
0
0
0
.000
.000
.000
.000
.000
.000
.396
.859
.220
.163
.267
.527
.159-
.203
.455-
.992
.673
.941
.827
.833
rv
x v>\
-------
46 S2# 40 C440 2,4-DICHLOROPHENOL 162 2 NOT FOUND
47 S2# 45 C430 BENZOIC ACID 122 2 NOT FOUND
48 S2# 50 AA-DIMETHYLPHENETHYLAMIN 58 2 NOT FOUND
49 S2# 55 C445 1,2,4-TRICHLOROBENZ 180 AW 523 2 334. 0.331 0.350
1 o r C,
-------
50
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
69
70
71
72
73
74
75
76
77
78
79
80
81
82
83
84
85
86
87
88
89
90
91
92
93
94
95
96
97
98
99
100
101
102
103
104
105
106
107
108
109
110
S2# 60
S2# 80
S2* 85
S2* 90
S2* 95
52*115
S2#120
52*130
52*140
52*145
S3* 10
S3* 15
S3* 20
S3* 25
S3* 30
S3* 35
S3* 40
S3* 42
S3* 45
S3* 50
S3* 55
S3* 60
S3* 65
S3* 70
S3* 75
S3* 80
S3* 85
S3* 90
S3* 95
S3#100
53*105
S3#110
S3#115
53*120
S3#130
33*135
53*140
S3#145
S3#150
S4* 10
S4* 15
54* 20
S4# 25
54* 30
S4# 35
54* 37
54* 40
54* 45
54* 50
S4# 55
54* 60
S4# 65
S4# 70
S4* 75
S4* 80
S4* 85
54*100
S4#105
54*106
S4*110
S4#120
C4^0NAPHTHALENE^-^'
C455 4-CHLOROANALINE
2,6-DICHLOROPHENOL
HEXACHLOROPROPENE
C460 HEXACHLOROBUTADIENE
P-PHENYLENE DIAMINE
N-NITROSODI-N-BUTYLAMINE
C465 4-CHLORO-3-METHYLPH
SAFROLE-— • ~~_
1/2,4,5-TETRACHLOROBENZE
ISOSAFROLE (#1)
C510 HEXACHLOROCYCLOPENT
C515 2,4,6-TRICHLOROPHEN
C520 2,4,5-TRICHLOROPHEN
ISOSAFROLE (#2)
C525 2-CHLORONAPHTHALENE
1-CHLORONAPHTHALEN
C530 2-NITROANALINE
1,4-NAPHTHOQUINONE
C535 DIMETHYLPHTHALATE
1,3-DINITROBENZENE
C540 ACENAPHTHYLENE
C543 2,6-DINlTROTOLUENE
C545 3-NITROANILINE
C550 ACENAPHTHENE
C555 2,4-DINITROPHENOL
C565 DIBENZOFURAN
C560 4-NITROPHENOL
PENTACHLOROBENZENE
C570 2,4-DlNITROTOLUENE
1-NAPHTHYLAMINE
2-NAPHTHYLAMINE
2,3,4,6- TETRACHLOROPHENO
C580 DIETHYLPHTHALATE
C590 FLUORENE
C585 4-CHLOROPHENYL-PHEN
5-NITRO-0-TOLUID1NE
C595 4-NITROANALINE
C610 4,6-DINITRO-2-METHY
C615 N-NITROSODIPHENYLAM
C620 AZOBENZENE
SYM-TRINITROBENZENE
C625 4-BROMOPHENYL-PHENY
PHENACETIN
01ALLATE
C630 HEXACHLOROBENZENE
4-AMINOBIPHENYL
C635 PENTACHLOROPHENOL
PRONAMIDE
PFNTftrHJJ1RnNITR9RFN7FNF
C645 ANTHRACENE
2SECBUTYL-4.6-DINITROPHE
C647 CARBAZOLE
C650 DI-N-BUTYLPHTHALATE
4-NITROQUINOLINE-1 -OXIDE
METHAPYRILENE
ISODRIN
C655 FLUORANTHENE
CHLOROBENZILATE
128
127
162
213
225
108
84
107
162
1)42
214
162
237
196
196
104
162
162
65
158
163
168
152
165
138
153
184
168
109
250
165
143
143
232
149
166
204
152
138
198
169
77
75
248
108
234
284
169
266
173
237
178
178
211
167
149
190
58
193
202
139
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
BV
BB
VB
BB
BB
BB
BV
BB
BB
BB
BB
BV
VB
BB
BB
BB
VB
BB
BV
BB
VB
VB
BB
533 2
555 2
2 NOT
2 NOT
2 NOT
2 NOT
619 2
2 NOT
647 2
652 2
3 NOT
697 3
3 NOT
3 NOT
715 3
738 3
3 NOT
3 NOT
763 3
3 NOT
3 NOT
806 3
3 NOT
816 3
3 NOT
834 3
3 NOT
866 3
3 NOT
3 NOT
881 3
3 NOT
901 3
3 NOT
3 NOT
926 3
3 NOT
942 3
947 3
950 4
963 4
4 NOT
4 NOT
1021 4
4 NOT
4 NOT
4 NOT
4 NOT
1063 4
4 NOT
4 NOT
1090 4
4 NOT
4 NOT
4 NOT
4 NOT
4 NOT
4 NOT
4 NOT
4 NOT
4 NOT
14749.
464.
FOUND
FOUND
FOUND
FOUND
1201.
FOUND
942.
16754.
FOUND
518.
FOUND
FOUND
406.
283.
FOUND
FOUND
579.
FOUND
FOUND
283.
FOUND
221.
FOUND
1111.
FOUND
1273.
FOUND
FOUND
292.
FOUND
357.
FOUND
FOUND
1855.
FOUND
1344.
162.
318.
1849.
FOUND
FOUND
184.
FOUND
FOUND
FOUND
FOUND
332.
FOUND
FOUND
5600.
FOUND
FOUND
FOUND
FOUND
FOUND
FOUND
FOUND
FOUND
FOUND
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
1.
0.
0.
1.
022
454
213
248
751
044
412
195
502
197
324
159
669
397
966
,298
0.356
0.307
0.
.132
0.551
0,
0
1
.222
.155
.033
0-
0.
1.
1.
7.
m •
7.
0.
0.
0.
0.
0.
Q09-I
355
957
320
742
•"• >*
c
477
621
915
727
904
430
0.604
0.480
0.464
0.233
0.
.901
2.382
0.333
0.879
1,
.225
0.302
0
1
^
.781
.978
r\
. O
-------
111 S5# 10 C710 BENZID1NE 184 5 NOT FOUND
112 S5# 15 C715 PYRENE 202 A BB 1335 5 1384. 1.323 0.611
113 S5# 20 ARAMITE (#1) 185 5 NOT FOUND
114 S5# 25 ARAMITE (#2) 185 5 NOT FOUND
115 S5# 30 P-DIMETHYLAMINOAZOBENZEN 120 5 NOT FOUND
116 S5# 35 3,3'-DIMETHYLBENZIDINE 212 5 NOT FOUND
117 S5# 37 KEPONE 272 5 NOT FOUND
118 S5# 40 C720 BUTYLBENZYLPHTHALAT 149 5 NOT FOUND
119 S5# 45 2-ACETYLAMINOFLUORENE 181 5 NOT FOUND
120 S5# 50 C730 BENZO(A)ANTHRACENE 228 A BB 1554 5 667.1.125 0.346
121 S5# 55 C725 3,3'-DICHLOROBENZID 252 A VB 1564 5 342. 0.408 0.490
122 S5# 60 C740 CHRYSENE 228 A BB 1554 5 667. 1.014 0.384
123 S5# 65 C745 BISC2-ETHYLHEXYDPH 149 5 NOT FOUND
124 S5# 85 3-METHYLCHOLANTHRENE 268 5 NOT FOUND
125 S6# 10 C760 DI-N-OCTYL PHTHALAT 149 6 NOT FOUND
126 S6# 15 C765 BENZO(B)FLUORANTHEN 252 6 NOT FOUND
127 S6# 20 7,12-DIMETHYLBENZANTHRAC 256 A BB 1740 6 194. 0.610 0.231 ~v
128 S6# 25 C770 BENZO(K)FLUORANTHEN 252 6 NOT FOUND
129 S6# 30 HEXACHLOROPHENE 196 6 NOT FOUND
130 S6# 35 C775 BENZO(A)PYRENE 252 A BB 1783 6 522. 1.182 0.321
131 S6# 55 C780 INDENOd ,2,3-CD)PYR 276 6 NOT FOUND
132 S6# 60 C785 DIBENZ(A,H)ANTHRACE 278 6 NOT FOUND
133 S6# 65 C790 BENZO(G,H, DPERYLEN 276 6 NOT FOUND
13;
-------
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-------
TARGET COMPOUND COMPARISON
COMPOUND: C450 NAPHTHALENE
128 S2ft 60
RAM DATA: 30068116 #533
08X31/-98 23:28
SAMPLE: S-MM5-4 1/3SA/100M INST. ID: F16
CONDS.: UG/ML *100ML *100Z/1002 */l/3SA NA M
91-20-3
BASE M/Z: 41
RIC: 80128.
6.0-
3.0-;
3.9-
2.0-:
100.0-
50.0-:
M/Z
100.0-
50.0-i
0.0-
-50.0-:
•100.0J
1,11
1 ll ll
II Jilil 1,1,11,1.... I,,
II ,,,
/ \Xn^
, 1 1 iiui
i • • i • i • , • , i • • i •
ENHANCED DATA: 30068110 #533
1
I
i .. n ,1 ,i, i i .
,,
i. ii
I • | • •I>|ll>,'|
STANDARD FILE: ST 16980831 #533
08/-31/98 12:31
1
50
..,1 .i.,.
i""' i i i • i
,,. ,1.... 1
• •' i
1 '
100
. ,i
xvAy y
I.I,,,. 1.. . ,1... 1. . ..!..
1 i 1 ' | • 1 ' i • 1 • i • i • I ' i ' i " i ' | > i »•"'
BASE M/Z: 128 RIC: 12608.
, i 1
, . , i ,. i .,.,.,- , .,.,.,.,.,.,-
BASE M/Z: 128 RIC: 195840.
T ' ( ^ I • I • | • i • i • i • i • I • i • i • i • I • | • I
150 200 250
.. .. ... .. 1
4720.
3108.
r 79232.
r **OUT**
-------
TARGET COMPOUND COMPARISON
COMPOUND: C470 2-METHYLNAPHTHALENE
142 S2#145
RAW DATA: 30068116 #652
08/31/98 23:28
SAMPLE: S-MM5-4 1/3SA/108M INST. ID: FIG
CONDS.: UG/ML *100ML *100Z/10072 *
-------
TARGET COMPOUND COMPARISON
COMPOUND: C640 PHENANTHRENE
178 S4# 65
RAM DATA: 38868110 #1090
08/31/98 23:28
SAMPLE: S-MM5-4 1/3SA/100M INST. ID: F16
CONDS.: UG/ML *100ML *100Z/10072 *
-------
Data Reduced by:
Data Reviewed by:
Data File: 30068110
QUANTERRA GC/MS TIC REPORT ( Part 1 )
Sample: S-MM5-4 1/3SA/100M INST. ID: F16
Analyst: DAT Date Analyzed: 08/31/98 23:28
Run Factor: 300.
Concentration
in Sample
# SCAN (UG/A) CAS #
1 444 7600. 1120-21-4
UNDECANE O *""
2 473 7500. i, 74962-90 *
•0 TR1PCCCN 1 OL, (C?-—^
3 555
OCTAHC. L/
7100.
.(I TfltCTII
4 569 6200. 62108-22-9
DECANE, 2,5,9-TRIMETHYL- Qf
5 616 12000.
UNKNOWN
00-00-0
6 632 12000.
7 654
6900.
8 662 9800.
OCTANE, 3,5-DIMETHYL-
15869-93-9
9 699 6400.
UNKNOWN
00-00-0
L 714 4800. 00-00-0
UNKNOWN
t
j
-------
11 737 13000. 54105-67-8
HEPTADECANE, 2,6-DIMETHYL-
12 763 18000.
TETRADECANE
629-59-4
13 776 8600.
UNKNOWN
00-00-0
H 820 12000. 18344-37-1
HEPTADECANE, 2,6,10,14-TETRAMETHYL-
15 857 14000.
PENTADECANE
629-62-9
16 903 6400.
OXUEAilE^pODECYL-
17 947 16000.
NONADECANE
629-92-5
18 987 13000. 17301-23-4
UNDECANE, 2,6-DIMETHYL-
1035 28000. 54105-67-8
HEPTADECANE, 2,6-DIMETHYL-
\_
f
21 1113 7600. ?Qfti7-70-1
HXM-.OAIUH1IIL. UULLIL^^
22 1118 9800. 54105-67-8
HEPTADECANE, 2,6-DIMETHYL-
13
37
-------
1190 6400.
NONAOECANE 6 f
629-92-5
/
1264 6400.
-------
DATA FILE: 30068110
QUANTERRA GC/MS TIC REPORT ( Part 2 )
CONCENTRATION = AREA(TIC)*CONC(IS)/AREA(IS)
#
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
FIT
984
883
966
964
866
931
922
939
786
865
953
960
902
957
955
918
958
949
971
901
948
941
940
921
855
PURITY
701
667
816
831
467
784
681
825
462
422
832
734
440
792
770
641
842
827
867
704
794
834
728
706
571
INT.
STD.
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
3
3
3
3
3
3
3
4
RT
4:56
5:15
6:10
6:19
6:51
7:01
7:16
7:21
7:46
7:56
8:11
8:29
8:37
9:07
9:31
10:02
10:32
10:58
11:30
11:42
12:22
12:26
13:14
14:03
14:50
RRT
0.536
0.571
0.669
0.686
0.743
0.762
0.789
0.799
0.843
0.861
0.889
0.920
0.936
0.989
1.034
1.089
1.142
0.908
0.952
0.969
1.024
1.029
1.095
1.163
0.860
AREA
231686.
230400.
218304.
190400.
356160.
370112.
211506.
300032.
194560.
146432.
403712.
555008.
263296.
380416.
436116.
197120.
479616.
400256.
844160.
161024.
228224.
295680.
191872.
194304.
110720.
AS
HEIGHT
64883.
53289.
73600.
68571.
34752.
103303.
41371.
94196.
23981 .
35328.
103936.
162304.
38272.
103424.
137255.
44544.
139008.
105216.
153344.
34944.
70016.
89856.
48640.
38592.
22639.
AMOUNT
ANALYZED
(UG/ML )
25
25
23
20
38
40
23
32
21
15
43
60
28
41
47
21
52
44
93
17
25
32
21
21
.245
.105
.787
.746
.808
.328
.046
.692
.199
.955
.989
.474
.689
.450
.520
.478
.259
.229
.281
.793
.219
.673
.202
.471
17.169
LIB
NB
NB
NB
NB
UK
NB
NB
NB
UK
UK
NB
NB
UK
NB
NB
NB
NB
NB
NB
NB
NB
NB
NB
NB
UK
LIB #
11607.
22482.
11602.
19013.
1.
37462.
32420.
8104.
1.
1.
37462.
22530.
1.
42196.
25997.
25971 .
37465.
19054.
37462.
34410.
15969.
37462.
37465.
37462.
1.
«;, c\ r
-------
Library Search Data: 30068110 # 444. Base m/z: 43
08/31/98 23:28:00 + 4:56 Cali: 30068110 # 3 RIC: 54464.
Sample: S-MM5-4 1/3SA/100M INST. ID: F16
Conds.: UG/ML *100ML *100%/100% *(NA/NA )/1/3SA NA M
Enhanced (S 158 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
892 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 11607 UNDECANE
2 19015 DECANE, 2,5,6-TRIMETHYL-
3 11565 ISOOCTANE, (ETHENYLOXY)-
4 8104 OCTANE, 3,5-DIMETHYL-
5 19523 1-DECANOL, 2-ETHYL-
6 14793 1-UNDECENE, 4-METHYL-
7 5151 HEPTANE, 3,4-DIMETHYL-
8 15969 HYDROXYLAHINE, 0-DECYL-
9 12050 1-OCTANOL, 2,7-DIMETHYL-
Rank
1
2
3
4
5
6
7
8
9
Formula
C11.H24
C13.H28
C10.H20.0
C10.H22
C12.H26.0
C12.H24
C9.H20
C10.H23.0.N
C10.H22.0
Rank
1
2
3
4
5
6
7
8
9
Ret.Time
M.Wt
156
184
156
142
186
168
128
173
158
B.Pk
43
57
43
57
57
43
43
43
43
Purity
701
692
681
677
677
670
668
665
665
Fit
984
934
975
932
922
925
922
930
935
RFit
703
692
686
683
697
673
670
698
665
B.P.Int.
US.Par.1
US.Par.2
C.A.S
1120
62108
37769
15869
21078
74630
922
29812
15250
#
21-4
23-0
62-3
•93-9
•65-9
•39-0
•28-1
•79-1
•22-3
£l>
-------
MID LIBRARY SEARCH
08/31/98 23:28:00 + 4:56
SAMPLE: S-MM5-4 1/3SA/100M INST. ID: F16
CONDS.: UG/ML *100ML *100Z/100Z *
DATA: 30068110 # 444
CALI: 30068110 # 3
BASE M/Z: 43
RIC: 54464.
1000 I
SAMPLE
C11.H24
1000 -I
M WT 156
B PK 43
RANK 1
tt 11607
PUR 701
C13.H28
1000 1
M WT 184
B PK 57
RANK 2
* 19015
PUR 692
C10.H20.0
1000 i
M WT 156
B PK 43
RANK 3
# 11565 '
PUR 681
M/Z
r
1
.h
i i, 1 1 1 . . M .1.1. — i .. __*_. — ^ — i^^. . i . . — _ — . —
UNDECANE o< i«>6r^--e-V
1
ii
I 1 . . ^j ^ _ L-_
DECANE, 2,5,6-TRIMETHYL-
r
i
ill II
ISOOCTANE, -
r
1
ll
|| || . . . . . _
49 60 80 100 120 140
co
-------
Library Search Data: 30068110 # 473
08/31/9823:28:00+ 5:16 Cali: 30068110 # 3
Sample: S-MM5-4 1/3SA/100M INST. ID: F16
Conds.: UG/ML *100HL *100%/100% *(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
Base m/z: 43
RIC: 45440.
62231 spectra in UBRARYNB searched for maximum PURITY
367 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 22482 2-TR1DECEN-1-OL, (E)-
2 25971 OXIRANE, DODECYL-
3 18944 OXIRANE, DECYL-
4 39230 9-EICOSYNE
5 15294 TRANS-2-UNDECEN-1-OL
6 37449 OCTADECANAL
7 28267 3-HEXADECYNE
8 28261 7-HEXADECYNE
9 34010 3-OCTADECYNE
Rank
1
2
3
4
5
6
7
8
9
Formula
C13.H26.0
C14.H28.0
C12.H24.0
C20.H38
C11.H22.0
C18.H36.0
C16.H30
C16.H30
C18.H34
M.Wt
198
212
184
278
170
268
222
222
250
B.Pk
57
41
41
81
57
43
67
67
67
Purity
667
621
612
609
609
599
598
597
597
Fit
883
892
919
876
894
811
916
900
908
RFit
674
654
612
642
609
671
603
603
602
Rank
1
2
3
4
5
6
7
8
9
Ret.Time
B.P.lnt.
US.Par.1 US.Par.2
C.A.S. #
74962-98-4
3234-28-4
2855-19-8
71899-38-2
638-66-4
61886-62-2
74685-28-2
61886-64-4
.342
-------
MID LIBRARY SEARCH (LIBRARYNB)
08/31/98 23:28:00 + 5:16
SAMPLE: S-MM5-4 1/3SA/100M INST. ID: F16
CONDS.s UG/ML *100ML *108Z/100Z *
DATA: 30068110 ft 473
CALI: 30068110 # 3
BASE M/Z: 43
RIC: 45440.
1212 i
SAMPLE
C13.H26.0
1212 i
M WT 198
B PK 57
RANK 1
# 22482
PUR 667
C14.H28.0
1212 -i
M WT 212
B PK 41
RANK 2
# 25971 '
PUR 621
C12.H24.0
1212 1
M WT 184
B PK 41
RANK 3
# 18944
PUR 612
r
ii
1 MM Ii M nil. ..Il - -1 1 1
2-TRIDECEN-l-OL, -
r
r
In il
Illll III II
OXIRANE, DODECYL-
III III II
OXIRANE, DECYL-
r
ii ill .1
II
1 ll!| II 1,
M/Z
40
60
80
100
120
140
160
180
CO
-------
Library Search Data: 30068110 # 555 Base m/z: 43
08/31/98 23:28:00 + 6:10 Cali: 30068110 # 3 RIC: 71808.
Sample: S-MM5-4 1/3SA/100M INST. ID: F16
Conds.: UG/ML *100ML *100%/100% *(NA/NA )/1/3SA NA M
Enhanced (S 158 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
988 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 11602 OCTANE, 2,4.6-TRIMETHYL-
2 15969 HYDROXYLAMINE, 0-DECYL-
3 11607 UNDECANE
4 19016 UNDECANE, 4,7-OIMETHYL-
5 19006 DECANE, 6-ETHYL-2-METHYL-
6 19015 DECANE, 2,5,6-TRIMETHYL-
7 14793 1-UNDECENE, 4-METHYL-
8 22530 TETRADECANE
9 19028 DECANE, 2,4,6-TRIMETHYL-
Rank
1
2
3
4
5
6
7
8
9
Formula
C11.H24
C10.H23.0.N
C11.H24
C13.H28
C13.H28
C13.H28
C12.H24
C14.H30
C13.H28
M.Wt
156
173
156
184
184
184
168
198
184
B.Pk
57
43
43
43
57
57
43
43
43
Purity
816
816
814
813
807
807
800
798
796
Fit
966
940
952
946
940
926
932
910
924
RFit
816
834
851
821
826
817
812
866
812
Rank
1
2
3
4
5
6
7
8
9
Ret.Time
B.P.Int.
US.Par.1
US.Par.2
C.A.S,
62016-
29812-
1120-
17301-
62108-
62108-
74630-
629
62108-
#
37-9
79-1
21-4
32-5
21-8
23-0
39-0
59-4
27-4
1314
-------
MID LIBRARY SEARCH (LIBRARYNB)
08/31/98 23:28:00 + 6:10
SAMPLE: S-MM5-4 1/3SA/100M INST. ID: F16
CONDS.: UG/ML *100ML * 100/5/100?! */l/3SA NA M
ENHANCED
DATA:
CALI:
30068110 # 555 BASE M/Z: 43
30068110 # 3 RIC: 71808.
1298
SAMPLE
Jh
C11.H24
1298
156
57
RANK 1
* 11602
PUR 816
OCTANE, 2,4,6-TRIMETHYL-
M WT
B PK
C10.H23.0.N
1298
173
43
RANK 2
* 15969
PUR 816
HYDROXYLAMINE, 0-DECYL-
SK
C11.H24
1298
M WT 156
B PK 43
RANK 3
# 11607
PUR 814
M/E
UNDECANE
r
i
1
II
40 60 80 100 120 140 160 18
-------
.ibrary Search Data: 30068110 # 569 Base m/z: 57
18/31/9823:28:00+ 6:20 Call: 30068110 # 3 RIC: 62144.
Sample: S-MM5-4 1/3SA/100M INST. ID: F16
;onds.: UG/ML *100ML *100X/100X *(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
S2231 spectra in LIBRARYNB searched for maximum PURITY
259 matched at least 8 of the 16 largest peaks in the unknown
Rank In. Name
1 19013 DECANE, 2,5,9-TRIMETHYL-
2 19054 UNDECANE, 2.6-DIMETHYL-
5 8104 OCTANE, 3,5-DIMETHYL-
U 19026 DECANE, 2,6,8-TRIMETHYL-
5 8077 HEPTANE, 2,3,5-TRIMETHYL-
6 8092 HEPTANE, 2,3,6-TRIHETHYL-
7 5154 HEXANE, 4-ETHYL-2-METHYL-
8 8081 OCTANE, 2,3-DIMETHYL-
9 11602 OCTANE, 2,4,6-TRIMETHYL-
M.Wt B.Pk Purity Fit RFit
Rank
1
2
3
it
5
$
7
B
9
Formula
C13.H28
C13.H28
C10.H22
C13.H28
C10.H22
C10.H22
C9.H20
C10.H22
C11.H24
Rank
1
2
3
4
5
6
7
8
9
184
184
142
184
142
142
128
142
156
57
57
57
57
57
57
57
57
57
831
826
816
815
810
809
801
796
788
964
935
949
949
954
955
947
940
933
841
863
824
836
810
809
806
798
798
Ret.Time B.P.Int.
US.Par.1 US.Par.2
C.A.S
62108
17301
15869
62108
20278
4032
3074
7146
62016
, #
•22-9
•23-4
93-9
•26-3
•85-7
•93-3
•75-7
•60-3
37-9
1 f+ /
_L O -„'
-------
MID LIBRARY SEARCH
88/31/98 23:28:09 + 6:20
SAMPLE: S-MM5-4 1/3SA/100M
CONDS.: UG/ML *100ML
ENHANCED
DATA:
CALI:
INST. ID: F16
*/l/3SA NA M
30068110 ft 569 BASE M/Z: 57
30068110 ft 3 RIC: 62144.
1175
SAMPLE
*4
M iii
C13.H28
1175
M WT 184
B PK 57
RANK 1
ft 19013
PUR 831
C13.H28
1175
M WT 184
B PK 57
RANK 2
ft 19054
PUR 826
C10.H22
1175
DECANE, 2,5,9-TRIMETHYL- £>\f
UNDECANE , 2 / 6-D I METHYL-
M WT
B PK
142
57
RANK 3
ft 8104
PUR 816
M/Z
OCTANE, 3,5-DIMETHYL-
ll|
40
60
80
100
120
140
160
180
-------
Library Search Data: 30068110 # 616 Base m/z: 55
08/31/98 23:28:00 •*• 6:51 Cali: 30068110 # 3 R1C: 31296.
Sample: S-MM5-4 1/3SA/100M INST. ID: F16
Conds.: UG/ML *100HL *100%/100% *(NA/NA )/1/3SA NA H
Enhanced (S 15B 2N OT)
62231 spectra in L1BRARYNB searched for maximum PURITY
457 matched at least 6 of the 16 largest peaks in the unknown
Rank In. Name
1 24994 1,1'-BICYCLOHEXYL, 2-(1-METHYLETHYL)-, TRANS-
2 33979 BORINIC ACID. DIETHYL-, 1-CYCLODOOECEN-1-YL ESTER
3 24997 1,1'-BICYCLOHEXYL, 2-PROPYL-, TRANS-
4 24993 I.T-BICYCLOHEXYL. 2-(1-METHYLETHYL)-, C!S-
5 24996 1,1'-BICYCLOHEXYL, 2-PROPYL-, CIS-
6 39230 9-EICOSYKE
7 32770 1,15-PENTADECANEDIOL
8 29229 CYCLOPENTADECANOL-
9 14159 1,11-DOOECADIENE
Rank
1
2
3
4
5
6
7
8
9
Rank
1
2
3
4
5
6
7
8
9
Formula
C15.H28
C16.H31.0.B
C15.H28
C15.H28
C15.H28
C20.H38
C15.H32.02
C15.H30.0
C12.H22
Ret. Time
B.P.Int.
US.Par.1
M.Ut
208
250
208
208
208
278
244
226
166
B.Pk Purity Fit
83
83
41
83
69
81
55
55
55
I US. Par. 2
467 866
455 875
440 789
430 834
416 787
413 753
410 890
408 743
405 838
C.A.S. #
50991-16-7
61142-73-2
54934-89-3
50991-15-6
54934-88-2
71899-38-2
4727-17-7
5876-87-9
RFit
496
492
448
477
435
464
426
451
421
-------
MID LIBRARY SEARCH
DATA: 30068110 # 616
CALI: 30068110 * 3
BASE M/Z: 55
RIC: 31296.
1105
SAMPLE
I I
ll
jUi
C15.H28
1105
M NT 208
B PK 83
RANK 1
tt 24994
PUR 467
1,1'-BICYCLOHEXYL, 2--, TRANS-
C16.H31.0.B
1105
250
RANK 2
# 33979
PUR 455
C15.H28
1105
M WT 208
B PK 41
RANK 3
# 24997
PUR 440
BORINIC ACID, D I ETHYL-, 1-CYCLODODECEN-l-YL ESTER
III
1,1'-BICYCLOHEXYL, 2-PROPYL-, TRANS-
M/Z
50
100
150
200
250
h*
-------
Library Search Data: 30068110 # 632 Base m/z: 57
08/31/9823:28:00+ 7:02 Cati: 30068110 # 3 RIC: 90240.
Sample: S-MM5-4 1/3SA/100M 1NST. ID: F16
Conds.: UG/ML *100ML *100%/100% *(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
312 matched at least 8 of the 16 largest peaks in the unknown
Rank In. Name
1 37462 HEPTADECANE, 2,6-DIMETHYL-
2 14799 1-DECENE, 3,4-DIMETHYL-
3 19523 1-DECANOL, 2-ETHYL-
4 14751 2-UNDECENE, 5-METHYL-
5 22534 TRIDECANE, 7-METHYL-
6 8539 1-PENTANOL, 4-METHYL-2-PROPYL-
7 15353 2,6-DIMETHYLDECANE
8 25994 DODECANE, 2,6,11-TRIMETHYL-
9 42196 HEPTADECANE, 2,6,10,14-TETRAMETHYL-
Rank
1
2
3
4
5
6
7
8
9
Rank
1
2
3
4
5
6
7
8
9
Formula
C19.H40
C12.H24
C12.H26.0
C12.H24
C14.H30
C9.H20.0
C12.H26
C15.H32
C21.H44
Ret. Time
B.P.Int.
US.Par.1
M.Wt
268
168
186
168
198
144
170
212
296
B.Pk Purity Fit
57
57
57
57
57
57
43
57
57
US. Par. 2
784 931
782 953
773 934
768 966
766 921
756 974
753 915
751 947
748 908
C.A.S. #
54105-67-8
50871-03-9
21078-65-9
56851-34-4
26730-14-3
54004-41-0
13150-81-7
31295-56-4
18344-37-1
RFit
815
785
779
768
780
756
762
756
788
1350
-------
1119
SAMPLE
MID LIBRARY SEARCH
08/31/98 23:28:80 + 7:02
SAMPLE: S-MM5-4 1/3SA/100M
CONDS.: UG/ML *100ML
ENHANCED
-------
.ibrary Search Data: 30068110 # 654 Base m/z: 41
)8/31/98 23:28:00 + 7:16 Call": 30068110 # 3 RIC: 43584.
Sample: S-MM5-4 1/3SA/100M 1NST. ID: F16
:onds.: UG/ML *100ML *100%/100% *(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT>
S2231 spectra in LIBRARYNB searched for maximum PURITY
820 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 32420 1-HEXADECANOL
2 21962 3-TETRADECENE. CZ)-
3 19526 1-DOOECANOL
4 21963 3-TETRADECENE, <£)-
5 28772 7-HEXADECENE, (Z)-
6 31653 1-HEPTADECENE
7 28768 3-HEXADECENE. (Z)-
8 40193 CIS-9,10-EPOXYOCTADECAN-1-OL
9 34411 5-OCTADECENE, (E)-
Rank
1
2
3
4
5
6
7
8
9
Formula
C16.H34.0
C14.H28
C12.H26.0
C14.H28
C16.H32
C17.H34
C16.H32
C18.H36.02
C18.H36
H.Ut
242
196
186
196
224
238
224
284
252
B.Pk
55
41
43
41
55
55
55
55
55
Purity
681
680
678
677
677
676
674
674
672
Fit
922
948
950
944
912
922
915
903
905
RFit
692
689
687
687
707
699
707
706
704
Rank
1
2
3
4
5
6
7
8
9
Ret.Time
B.P.Int.
US.Par.1
US.Par.2
C.A.S
36653
41446
112
41446
35507
6765
34303
13980
7206
, #
•82-4
•67-7
•53-8
•68-8
09-6
•39-5
•81-6
•12-6
•21-5
-------
MID LIBRARY SEARCH (LIBRARYNB)
08/31x98 23:28:00 + 7:16
SAMPLE: S-MM5-4 1/3SA/100M INST. ID: F16
CONDS.: UG/ML *100ML *100Z/100Z *
DATA: 30068119 # 654
CALI: 30868110 # 3
BASE M/Z: 41
RIC: 43584.
1000 I
SAMPLE
C16.H34.0
1000 1
M WT 242
B PK 55
RANK 1
# 32420
PUR 681
C14.H28
1000 I
M WT 196
B PK 41
RANK 2
ft 21962
PUR 680
C12.H26.0
1000 1
M WT 186 :
B PK 43
RANK 3
* 19526
PUR 678
M/Z
r
Li
ll III' 111' 1. i .. ..!._„ _l_ ... ..
1-HEXADECANOL
r
r
r
4«
•
ll 1
II i. .....
3-TETRADECENE, -
1-DODECANOL
5
1 i • -, • i . '• i . -1-
60
III,..
80 100 120 140 160 180 200 220
CO
CT
Co
-------
Base m/z: 43
RIC: 88832.
Library Search Data: 30068110 # 662
08/31/98 23:28:00 + 7:22 Call: 30068110 # 3
Sample: S-MM5-4 1/3SA/100M INST. ID: F16
Conds.: UG/ML *100ML *100X/100% *(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
346 matched at least 8 of the 16 largest peaks in the unknown
Rank In. Name
1 8104 OCTANE, 3,5-DIMETHYL-
2 19015 DECANE, 2,5,6-TRIMETHYL-
3 11602 OCTANE. 2, 4,6- TR I METHYL -
4 19016 UNDECANE, 4,7-DIMETHYL-
5 19013 DECANE, 2,5,9-TRIMETHYL-
6 19026 DECANE, 2,6,8-TRlMETHYL-
7 18985 TRIDECANE
8 8102 HEXANE, 2,2,3,3-TETRAMETHYL-
9 19054 UNDECANE, 2,6-DIMETHYL-
Rank Formula
1 C10.H22
2 C13.H28
3 C11.H24
4 C13.H28
5 C13.H28
6 C13.H28
7 C13.H28
8 C10.H22
9 C13.H28
Rank Ret. Time B.P.Int. US. Par
1
2
3
4
5
6
7
8
9
M.Ut B.Pk
142 57
184 57
156 57
184 43
184 57
184 57
184 57
142 57
184 57
.1 US. Par
Purity Fit
825 939
824 931
823 968
822 934
815 935
81 1 928
808 939
800 923
797 889
.2 C.A.S. #
15869-93-9
62108-23-0
62016-37-9
17301-32-5
62108-22-9
62108-26-3
629-50-5
13475-81-5
17301-23-4
RFit
832
828
825
843
815
828
830
800
822
1354
-------
MID LIBRARY SEARCH CLIBRARYNB)
08/31/98 23:28:80 + 7:22
SAMPLE: S-MM5-4 1/3SA/100M INST. ID: F16
CONDS.: UG/ML *100ML *100Z/100Z */l/3SA NA M
ENHANCED
DATA: 30068110 # 662
CALI: 30068110 # 3
BASE M/Z: 43
RIC: 88832.
1399 •
SAMPLE
C10.H22
1309 1
M WT 142
B PK 57
RANK 1
ft 8184
PUR 825
C13.H28
1389 1
M WT 184
B PK 57
RANK 2
ft 19015
PUR 824
C11.H24
1309 I
M WT 156
B PK 57
RANK 3
ft 11602
PUR 823
M/Z
r
1
r
1
11 I1
r
r
I
..ll
. . ll ^j_L J - - • • - -
OCTANE, 3,5-DIMETHYL- or OCT"^^
I
ll
ill ll .1 .1
DECANE, 2,5,6-TRIMETHYL-
1
'l^i i i | i . • i '
0(
il
. ill |l ,. ,
;TANE, 2,4,6-TRIMETHYL-
. 1 1 L .1 - -
40 ' 60 80 100 120 140 160 180
M
CO
C'l
en
-------
Library Search Data: 30068110 # 699
08/31/98 23:28:00 + 7:46 Cati: 30068110 it 3
Sample: S-MM5-4 1/3SA/100H INST. ID: F16
Conds.: UG/ML *100ML *100%/100% *(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
Base m/z: 81
R1C: 23040.
62231 spectra in LIBRARYNB searched for maximum PURITY
366 matched at least 6 of the 16 largest peaks in the unknown
Rank In. Name
1 28273 8-HEXADECYNE
2 36677 7-OCTADECYNE, 2-METHYL-
3 28267 3-HEXADECYNE
4 34010 3-OCTAOECYNE
5 36681 1H-INDENE, 2-BUTYL-5-HEXYLOCTAHYDRO-
6 10423 3-UNDECYNE
7 25001 CYCLOHEXANE, 1-(CYCLOHEXYLMETHYL)-2-ETHYL-, TRANS-
8 25003 CYCLOHEXANE, 1-(CYCLOHEXYLMETHYL)-2-ETHYL-, CIS-
9 21386 2(1H)-BENZOCYCLOOCTENONE, DECAHYDRO-10A-METHYL-, TRANS-
Rank
1
2
3
4
5
6
7
8
9
Formula
C16.H30
C19.H36
C16.H30
C18.H34
C19.H36
C11.H20
C15.H28
C15.H28
C13.H22.0
M.Wt
222
264
222
250
264
152
208
208
194
B.Pk
81
81
67
67
95
67
55
55
55
Purity
462
459
447
434
433
425
424
420
418
Fit
786
760
731
821
747
894
722
714
766
RFit
509
506
464
455
544
425
452
451
459
Rank
1
2
3
4
5
6
7
8
9
Ret.Time B.P.Int.
US.Par.1
US.Par.2
C.A.S,
19781-
35354
61886-
61886
55044-
60212-
54934-
54934-
55103-
#
86-3
38-2
62-2
64-4
33-2
30-8
92-8
93-9
68-9
1356
-------
MID LIBRARY SEARCH (LIBRARYNB)
08x31/98 23:28:00 + 7:46
SAMPLE: S-MM5-4 1/3SA/100M INST. ID: F16
CONDS.: DC/ML *100ML *100Z/100/! */l/3SA NA M
ENHANCED
DATA: 36068110 # 699
CALI: 30068110 # 3
BASE M/Z: 81
RIC: 23040.
1074 •
SAMPLE
C16.H30
1074 i
B ffi 2i?
RANK 1
# 28273 '
PUR 462
C19.H36
1074 1
M WT 264
B PK 81
RANK 2
# 36677
PUR 459
C16.H30
1074 -i
M WT 222
B PK 67
RANK 3
# 28267
PUR 447
M/Z
,1 „
,1 ,
1 III
II 1
( ,
III i M i .1. . . ii . i •
8-HEXADECYNE ' ' ' ' " '
H
. 1 " 1' ' . U
7-OCTADECYNE, 2-METHYL- .....
ll
3-HEXADECYNE
50 100 150 200 25£
CO
en
-------
Library Search Data: 30068110 # 714 Base m/z: 41
08/31/98 23:28:00 + 7:57 Call: 30068110 # 3 RIC: 36480.
Sample: S-MM5-4 1/3SA/100M INST. ID: F16
Conds.: UG/ML *100ML *100%/100% *(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
212 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 21927 TRANS-2-TRIDECENAL
2 32052 OXIRANE, TETRADECYL-
3 31486 ACETAMIDE, N-METHYL-N- [4- [4-METHOXY-1-HEXAHYDROPYRIDYU-2-BUTYNYL] -
4 35931 HEXADECANE, 1-CHLORO-
5 40193 CIS-9.10-EPOXYOCTADECAN-1-OL
6 46251 DODECANE, 1,2-DIBROMO-
7 40233 NONADECANOL
8 42521 1-E1COSANOL
9 56499 9-OCTADECENOIC ACID (Z)-, 2-(ACETYLOXY)-1- [(ACETYLOXY)METHYL]ETHYL *
Rank Formula M.Wt B.Pk Purity Fit RFit
1 C13.H24.0 196 41 422 865 444
2 C16.H32.0 240 41 417 918 431
3 C13.H22.02.N2 238 43 409 829 472
4 C16.H33.CL 260 57 408 921 419
5 C18.H36.02 284 55 406 883 439
6 C12.H24.BR2 326 41 403 802 482
7 C19.H40.0 284 43 401 898 431
8 C20.H42.0 298 43 398 892 430
9 C25.H44.06 440 43 394 731 497
Rank Ret.Time B.P.Int. US.Par.1 US.Par.2 C.A.S. #
1 - -
2 7320-37-8
3
4 4860-03-1
5 13980-12-6
6 55334-42-4
7 52783-43-4
8 629-96-9
9 55401-63-3
-------
1015
SAMPLE
MID LIBRARY SEARCH
30068110 # 714
30068110 # 3
BASE M/Z: 41
RIC: 36480.
.
.
li.l. .III.
II HI
C13.H24.0
1015 •
M NT 196
B PK 41
RANK 1
* 21927 '
PUR 422
TRANS-2-TRIDECENAL
C16.H32.0
1015 1
M WT 240
B PK 41
RANK 2
# 32852 '
PUR 417
C13.H22.0:
1015 •
M WT 238
B PK 43
RANK 3
* 31486
PUR 409
M/Z
2.N
2
11 i • * •'
40 60
||
OXIRANE, TETRADECYL-
II III I
' ACETAM I DE , N-METHYL-N- C 4- C 4-METHOXY- 1 -HEXAHYDROPYR I DYL ] -2-BUTYNYL ] -
ll ll il
80 100 128 140 160 180 200 220 24
CO
CO
-------
Library Search Data: 30068110 # 737 Base m/z: 57
08/31/9823:28:00+ 8:12 Cali: 30068110 # 3 RIC: 99328.
Sample: S-MM5-4 1/3SA/100M INST. ID: F16
Conds.: UG/ML *100ML *100%/100% *(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
712 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 37462 HEPTADECANE, 2.6-DIMETHYL-
2 25991 DODECANE, 2,6,10-TRIMETHYL-
3 22535 DODECANE, 4,6-DIMETHYL-
4 26001 DODECANE, 2,7,10-TRIHETHYL-
5 42196 HEPTADECANE, 2,6,10,14-TETRAMETHYL-
6 25994 DODECANE, 2,6,11-TRlMETHYL-
7 15352 UNDECANE, 2-METHYL-
8 37465 NONADECANE
9 18998 UNDECANE, 3,7-DIMETHYL-
Rank
1
2
3
4
5
6
7
8
9
Formula
C19.H40
C15.H32
C14.H30
C15.H32
C21.H44
C15.H32
C12.H26
C19.H40
C13.H28
M.Ut
268
212
198
212
296
212
170
268
184
B.Pk
57
57
57
57
57
57
43
57
43
Purity
832
825
820
816
814
805
797
795
794
Fit
953
976
959
981
932
969
947
917
940
RFit
849
830
821
823
853
814
801
837
796
Rank
1
2
3
4
5
6
7
8
9
Ret.Time
B.P.Int.
US.Par.1
US.Par.2
C.A.S
54105
3891
61141
74645
18344
31295
7045
629
17301
. #
•67-8
•98-3
•72-8
•98-0
•37-1
•56-4
•71-8
•92-5
•29-0
-------
1214
SAMPLE
MID LIBRARY SEARCH
88/31/98 23:28:80 + 8:12
SAMPLE: S-MM5-4 1/3SA/100M
CONDS.: UG/ML *100ML
ENHANCED /l/3SA NA M
30068110 # 737
30068110 tt 3
BASE M/Z: 57
RIC: 99328.
C19.H40
1214
M WT 268
B PK 57
RANK 1
tt 37462
PUR 832
C15.H32
1214
M WT 212
B PK 57
RANK 2
* 25991
PUR 825
C14.H30
1214
HEPTADECANE, 26-DIMETHYL-
ii| ,—. 11, . ,.il,
T —r
DODECANE , 2 / 6 , 1 0-TR I METHYL-
WT
PK
1
RANK 3
# 22535
PUR 820
M/Z
DODECANE, 4,6-DIMETHYL-
50
100
150
200
250
CJ
CTD
-------
.ibrary Search Data: 30068110 # 763 Base m/z: 43
38/31/9823:28:00+ 8:29 Cali: 30068110 # 3 RIC: 140800.
sample: S-MM5-4 1/3SA/100M INST. ID: F16
Conds.: UG/ML *100ML *100%/100% *(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
611 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 22530 TETRADECANE
2 19006 DECANE. 6-ETHYL-2-METHYL-
5 19007 OOOECANE, 3-METHYL-
<• 42196 HEPTADECANE, 2,6,10,14-TETRAMETHYL-
5 15358 UNDECANE, 3-METHYL-
$ 11607 UNDECANE
7 39681 1-IOOOUNDECANE
3 11612 NONANE, 2,5-OIMETHYL-
? 37252 DECANE, 1-ICOO-
M.Wt B.Pk Purity Fit RFit
?ank
1
I
5
*
5
^
r
3
?
Formula
C14.
C13.
C13.
C21.
C12.
C11.
C11.
C11.
C10.
H30
H28
H28
H44
H26
H24
H23.I
H24
H21.1
198
184
184
296
170
156
282
156
268
43
57
57
57
57
43
57
57
57
734
721
715
709
706
705
704
701
694
960
951
908
928
919
977
889
871
911
736
721
716
736
709
705
710
701
700
?ank
1
3
5
Ret.Time
B.P.Int.
US.Par.1
US.Par.2
C.A.S
629
621 on
17312
18344
1002
1120
4282
17302
2050
. #
•59-4
•21-8
•57-1
•37-1
•43-3
•21-4
•44-4
•27-1
77-3
1382
-------
MID LIBRARY SEARCH
08x31/98 23:28:00 + 8:29
SAMPLE: S-MM5-4 lx3SAxl00M INST. ID: F16
CONDS.: UGxML *100ML *100ZxlQQZ *
DATA: 30068110 # 763
CALI: 30068110 # 3
BASE MxZ: 43
RIC: 140800.
1196
SAMPLE
C14.H30
1196 •
M MT 198
B PK 43
RANK 1
# 22530
PUR 734
C13.H28
1196 i
M NT 184
B PK 57
RANK 2
# 19006 '
PUR 721
C13.H28
1196 I
tl NT 184
B PK 57
RANK 3
# 19007
PUR 715
MxZ
r
1,
II
. i .1
TETRADECANE Ov ,-JcTv^-tV ' ' '
r
1
ll
i
II II. . LJ .-1 ^ ._, .. i .
DECANE, 6-ETHYL-2-METHYL- ' .....
r
II
n
II .. .1
DO'DECANE, S-METHYL- ' ' ' '
r -
1
40 60 80 100 120 140 160 180 200
CO
-------
Library Search Data: 30068110 # 776 Base m/z: 41
08/31/98 23:28:00 + 8:38 Cali: 30068110 # 3 RIC: 31936.
Sample: S-MMS-4 1/3SA/100M INST. ID: F16
Conds.: UG/ML *100ML *100%/100% *(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
677 matched at least 6 of the 16 largest peaks in the unknown
Rank In. Name
1 40193 CIS-9.10-EPOXYOCTADECAN-1-OL
2 32052 OXIRANE, TETRADECYL-
3 25971 OXIRANE, DOOECYL-
4 42521 1-EICOSANOL
5 37449 OCTADECANAL
6 40233 NONADECANOL
7 37444 OXIRANE. HEXADECYL-
3 29226 PENTADECANAL-
? 29187 BUTANOIC ACID, 3.7-DIMETHYL-6-OCTENYL ESTER
?ank Formula M.Wt B.Pk Purity Fit RFit
1 C18.H36.02 284 55 440 902 464
> C16.H32.0 240 41 431 915 446
5 C14.H28.0 212 41 429 870 460
. C20.H42.0 298 43 409 886 440
i C18.H36.0 268 43 404 813 465
> C19.H40.0 284 43 401 897 432
' C18.H36.0 268 57 398 793 467
i C15.H30.0 226 82 393 860 415
> C14.H26.02 226 41 389 865 410
Sank Ret.Time B.P.Int. US.Par.1 US.Par.2 C.A.S. #
13980-12-6
! 7320-37-8
i 3234-28-4
629-96-9
638-66-4
. 52783-43-4
7390-81-0
i 2765-11-9
1 141-16-2
13C4
-------
MID LIBRARY SEARCH CLIBRARYNB)
08/31/98 23:28:00 + 8:38
SAMPLE: S-MM5-4 1/3SA/100M INST. ID: F16
CONDS.: UG/ML *100ML *100Z/1002 */l/3SA NA M
ENHANCED
DATA: 30068110 # 776 BASE M/Z: 41
CALI: 30068110 # 3 RIC: 31936.
1459 i
SAMPLE
C18.H36.0:
1459
M WT 284
B PK 55
RANK 1
# 40193
PUR 440
C16.H32.0
1459 -I
M WT 240
B PK 41
RANK 2
# 32052
PUR 431
C14.H28.0
1459 i
M WT 212
B PK 41
RANK 3
# 25971
PUR 429
M/Z
r
2
r
r
r
M
CO
CTi
Crl
. MW^'
1
• 1 II III 1 1 ll .1 Li 1 , ll 1 1. i. .. 1..
CIS-9, 10-EPOXYOCTADECAN-l-OL
1 , III
ll II H III n, ,. .
OXIRANE, TETRADECYL-
Ill III in ,
OXIRANE, DODECYL-
40 60 80 100 120 140 160 180 200
-------
Library Search Data: 30068110 # 820
08/31/98 23:28:00 + 9:07 Cali: 30068110 # 3
Sample: S-MM5-4 1/3SA/100M 1NST. ID: F16
Conds.: UG/ML *100ML *1005C/100X *(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
Base m/z: 57
RIC: 91136.
62231 spectra in LIBRARYNB searched for maximum PURITY
760 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 42196 HEPTADECANE, 2,6, 10,14-TETRAMETHYL-
2 37462 HEPTADECANE, 2,6-DIMETHYL-
3 18987 UNDECANE, 2,8-DIMETHYL-
4 15344 DECANE, 3.6-DIMETHYL-
5 8104 OCTANE, 3,5-DIMETHYL-
6 19004 UNDECANE, 4,6-DIMETHYL-
7 19023 DECANE, 2,6,7-TRIMETHYL-
8 19039 DECANE, 2,3,5-TRIMETHYL-
9 15358 UNDECANE, 3-METHYL-
M.Ut B.Pk Purity Fit RFit
Rank
1
2
3
4
5
6
7
8
9
Formula
C21.H44
C19.H40
C13.H28
C12.H26
C10.H22
C13.H28
C13.H28
C13.H28
C12.H26
296
268
184
170
142
184
184
184
170
57
57
43
57
57
57
57
57
57
792
776
762
757
755
755
752
751
751
957
932
955
952
963
955
937
942
938
816
805
768
764
755
757
752
752
756
Rank
1
2
3
4
5
6
7
B
9
Ret.Time
8.P.Int.
US.Par.1
US.Par.2
C.A.S,
18344-
54105-
17301-
17312-
15869-
17312-
62108-
62238-
1002-
#
37-1
67-8
25-6
53-7
93-9
82-2
25-2
11-3
43-3
13
66
-------
MID LIBRARY SEARCH
DATA: 30068116 # 820
CALI: 30068110 * 3
BASE M/Z: 57
RIC: 91136.
1237 -i
SAMPLE
C21.H44
1237 i
M NT 296 :
B PK 57
RANK 1
# 42196 :
PUR 792
C19.H40
1237 i
M WT 268
B PK 57
RANK 2
# 37462
PUR 776
C13.H28
1237 i
M WT 184
B PK 43
RANK 3
ft 18987
PUR 762
M/Z
r
r
r
r
i \
1
I
1
||
59
\
|
J
l|
1 i * 'i
1
'
,
HEPTADECANE / 2 , 6 , 1 0 , 1 4-TETRAMETHYL- O V v <$&^~-4S
HEPTADECANE , 2 , 6-D I METHYL-
II 1 1 -ll . . ., - •—, , ^"-j (• , •-" , -T , 1 1
JNDECANE, 2,8-DIMETHYL-
i ' •• i i1 i - • i — • — i — — i 1 1 1 1 1 1 1
100 150 200 250
en
-------
.ibrary Search Data: 30068110 # 857 Base m/z: 57
38/31/9823:28:00+ 9:32 Cali: 30068110 # 3 RIC: 132352.
Sample: S-MM5-4 1/3SA/100M INST. ID: F16
:onds.: UG/ML *100ML *1003t/100% *(NA/NA )/1/3SA NA M
Enhanced (S 158 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
242 matched at least 8 of the 16 largest peaks in the unknown
Rank In. Name
1 25997 PENTADECANE
2 19007 DOOECANE, 3-METHYL-
3 42196 HEPTADECANE, 2,6,10,14-TETRAMETHYL-
4 37465 NONADECANE
5 39681 1-IODOUNDECANE
6 18990 UNDECANE, 2.9-DIMETHYL-
7 19016 UNDECANE, 4,7-OIMETHYL-
8 19026 DECANE, 2,6,8-TRIMETHYL-
9 37252 DECANE, 1-1000-
Rank
1
2
3
4
5
6
7
8
9
Formula
C15.H32
C13.H28
C21.H44
C19.H40
C11.H23.I
C13.H28
C13.H28
C13.H28
C10.H21.I
M.Wt
212
184
296
268
282
184
184
184
268
B.Pk
57
57
57
57
57
57
43
57
57
Purity
770
767
761
753
748
747
744
741
738
Fit
955
961
941
926
970
954
936
939
972
RFit
773
769
778
783
754
749
744
744
743
Rank
1
2
3
4
5
6
7
8
9
Ret.Time B.P.Int.
US.Par.1 US.Par.2
C.A.S,
629-
17312-
18344-
629-
4282-
17301-
17301-
62108-
2050-
#
62-9
57-1
37-1
92-5
44-4
26-7
32-5
26-3
77-3
.368
-------
MID LIBRARY SEARCH
08/31/98 23:28:00 + 9:32
SAMPLE: S-MM5-4 1/3SA/100M INST. ID: F16
CONDS.: UG/ML *100ML *100Z/100Z *
DATA: 30068110 # 857
CALI: 30068110 # 3
BASE M/Z: 57
RIC: 132352.
1254
SAMPLE
C15.H32
1254 i
M WT 212
B PK 57
RANK 1
# 25997
PUR 778
C13.H28
1254 -i
M WT 184
B PK 57
RANK 2
# 19007
PUR 767
C21.H44
1254 i
M WT 296
B PK 57
RANK 3
# 42196
PUR 761
M/Z
r
, . i,
, ,1
L, ..il. .1, . ,...i, i. .
PENTADECANE £> r c^t^-^<-^ '
r
r
OODECANEi 3-METHYL-
i ii . .1 . .. ii.
HEPTADECANE , 2 , 6 , 1 0 , 1 4-TETRAMETHYL-
r _
II
50 100 150 200 250
CO
-------
Library Search Data: 30068110 # 903 Base m/z: 41
08/31/9823:28:00+10:03 Cali: 30068110 # 3 RIC: 46592.
Sample: S-MM5-4 1/3SA/100M INST. ID: F16
Conds.: UG/ML *100ML *100X/100% *(NA/NA }/1/3SA NA M
Enhanced (S 15B 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
606 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 25971 OX1RANE, DODECYL-
2 37449 OCTADECANAL
3 37444 OXIRANE, HEXADECYL-
4 40233 NONADECANOL
5 42521 1-EICOSANOL
6 58380 DECANEDIOIC ACID, DIDECYL ESTER
7 40193 CIS-9,10-EPOXYOCTADECAN-1-OL
8 42180 OCTADECANE, I-(ETHENYLOXY)-
9 15969 HYDROXYLAMINE, 0-DECYL-
Rank
1
2
3
4
5
6
7
3
?
Rank
1
Formula
C14.H28.0
C18.H36.0
C18.H36.0
C19.H40.0
C20.H42.0
C30.H58.04
C18.H36.02
C20.H40.0
C10.H23.0.N
Ret. Time
H.Ut
212
268
268
284
298
482
284
296
173
B.Pk
41
43
57
43
43
57
55
43
43
Purity
641
626
624
612
609
603
602
599
592
Fit
918
872
855
926
920
923
898
930
891
RFit
646
669
675
651
653
612
631
633
600
B.P.Int.
US.Par.1
US.Par.2
C.A.S,
3234
638
7390-
52783-
629-
2432-
13980-
930-
29812-
28-4
66-4
81-0
43-4
96-9
89-5
12-6
02-9
79-1
o
-------
1407
SAMPLE
MID LIBRARY SEARCH
DATA:
CALI:
INST. ID: F16
* HEXADECYL-
50
100
150
200
250
-------
Library Search Data: 30068110 # 947 Base m/z: 57
08/31/98 23:28:00 + 10:32 Cali: 30068110 # 3 R1C: 123136.
Sample: S-MM5-4 1/3SA/100M INST. ID: F16
Conds.: UG/ML *100ML *100%/100% *(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
343 matched at least 8 of the 16 largest peaks in the unknown
Rank In. Name
1 37465 NONADECANE
2 37462 HEPTADECANE, 2,6-DIMETHYL-
3 25997 PENTADECANE
4 42196 HEPTADECANE, 2,6.10,14-TETRAMETHYL-
5 15969 HYDROXYLAMINE. 0-DECYL-
6 19016 UNDECANE, 4,7-DIMETHYL-
7 25994 DODECANE, 2.6.11-TRIMETHYL-
8 19523 1-DECANOL, 2-ETHYL-
9 26001 DOOECANE, 2,7,10-TRIMETHYL-
Rank
1
2
3
4
5
6
7
8
9
Formula
C19.H40
C19.H40
C15.H32
C21.H44
C10.H23.0.N
C13.H28
C15.H32
C12.H26.0
C15.H32
Rank
1
2
3
4
5
6
7
8
9
Ret.Time
M.Wt
268
268
212
296
173
184
212
186
212
B.Pk
57
57
57
57
43
43
57
57
57
Purity
842
827
813
813
802
802
796
791
789
Fit
958
940
957
944
950
964
963
928
959
RFit
864
854
826
838
820
804
800
804
794
B.P.Int.
US.Par.1 US.Par.2
C.A.S,
629-
54105-
629-
18344-
29812-
17301-
31295-
21078-
74645-
92-5
67-8
62-9
37-1
79-1
32-5
56-4
65-9
98-0
13
-------
1857
SAMPLE
MID LIBRARY SEARCH
08/31x98 23:28:80 + 10:32
SAMPLE: S-MM5-4 1/3SA/100M INST. ID: F16
CONDS.: UG/ML *100ML *100Z/100Z *
-------
Jbrary Search Data: 30068110 # 987 Base m/z: 57
08/31/98 23:28:00 + 10:59 Cali: 30068110 # 3 RIC: 93568.
Sample: S-MM5-4 1/3SA/100M INST. ID: F16
Conds.: UG/HL *100ML *100X/100% *(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
644 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 19054 UNDECANE, 2.6-DIMETHYL-
2 42196 HEPTADECANE, 2,6,10,14-TETRAMETHYL-
3 37462 HEPTADECANE, 2,6-DIMETHYL-
4 25996 TRIDECANE, 4,8-DIMETHYL-
5 25997 PENTADECANE
6 29263 HEXADECANE
7 22530 TETRADECANE
8 32059 HEPTADECANE
9 19026 DECANE, 2,6,8-TRIMETHYL-
Rank
1
2
3
4
5
6
7
8
9
Formula
C13.H28
C21.H44
C19.H40
C15.H32
C15.H32
C16.H34
C14.H30
C17.H36
C13.H28
M.Wt
184
296
268
212
212
226
198
240
184
B.Pk
57
57
57
57
57
57
43
57
57
Purity
827
826
824
819
819
816
812
810
805
Fit
949
957
943
936
945
931
936
923
953
RFit
834
837
845
834
833
834
826
831
813
Rank
1
2
3
4
5
6
7
8
9
Ret.Time B.P.Int.
US.Par.1
US.Par.2
C.A.S
17301-
18344
54105-
55030-
629
544-
629
629
62108
if
23-4
37-1
67-8
62-1
62-9
76-3
59-4
78-7
26-3
-------
MID LIBRARY SEARCH
DATA: 30068110 # 987
CALI: 30068110 # 3
BASE M/Z: 57
RIC: 93568.
1000
SAMPLE
Jjl
C13.H28
UNDECANE, 2,6-DIMETHYL-
IttUU
M WT 184
B PK 57
RANK 1
# 19054
PUR 827
,11 .
, H
il .1 ii
C21.H44
1000
M WT 296
B PK 57
RANK 2
tt 42196
PUR 826
C19.H40
1000
M WT 268
B PK 57
RANK 3
# 37462
PUR 824
M/Z
HEPTADECANE, 2,6, 10, 14-TETRAMETHYL-
]
II
,1
HEPTADECANE, 2,6-DIMETHYL-
50
100
150
200
250
CO
-.1
C'f
-------
.ibrary Search Data: 30068110 #1035 Base m/z: 57
J8/31/98 23:28:00 + 11:31 Cali: 30068110 # 3 RIC: 132608.
Sample: S-MM5-4 1/3SA/100M INST. 10: F16
:onds.: UG/ML *100HL *100%/100X *
-------
1128
SAMPLE
MID LIBRARY SEARCH
08/31/98 23:28:00 + 11:31
SAMPLE: S-MM5-4 1/3SA/100M INST. ID: FIG
CONDS.: UG/ML *100ML * 1002/1097! *
-------
Library Search Data: 30068110 #1053 Base m/z: 69
08/31/9823:28:00+11:43 Cali: 30068110 # 3 RIC: 38336.
Sample: S-MM5-4 1/3SA/100M 1NST. ID: F16
Conds.: UG/ML *100ML *100%/100% *(NA/NA )/1/3SA NA M
Enhanced (S 15B ,2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
725 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 34410 3-OCTADECENE, (E>-
2 40233 NONADECANOL
3 34418 9-OCTADECENE, -
4 28768 3-HEXADECENE, (Z)-
5 34411 5-OCTADECENE, (E)-
6 26409 2-HEXYL-1-OCTANOL
7 28772 7-HEXADECENE, (Z)-
8 21963 3-TETRADECENE, (E)-
9 21962 3-TETRADECENE,
-------
MID LIBRARY SEARCH
08/31/98 23:28:00 + 11:43
SAMPLE: S-MM5-4 1/3SA/100M
CONDS.: UG/ML *100ML
ENHANCED /l/3SA NA M
30068118 #1053
30068118 # 3
BASE M/Z: 69
RIC: 38336.
1274 1
SAMPLE
C18.H36
1274 i
M WT 252
B PK 69
RANK 1
# 34410
PUR 704
C19.H40.0
1274 1
M WT 284
B PK 43
RANK 2
* 40233 '
PUR 703
C18.H36
1274 i
M WT 252
B PK 55
RANK 3
# 34418
PUR 708
M/Z
r
1
. ll
JV/v/JN^N/
,1 ll. ,,, II °
3-OCTADECENE, -
r
r
r
50
I ill
NONADECANOL
I ll .
9-OCTADECENE, -
1 ill
100 150 200 250
CO
-vl
tn
-------
Library Search Data: 30068110 #1113 Base m/z: 57
08/31/98 23:28:00 + 12:23 Cati: 30068110 # 3 RIC: 55040.
Sample: S-MM5-4 1/3SA/100M 1NST. ID: F16
Conds.: UG/ML *100ML *100X/100% *(NA/NA )/1/3SA NA M
Enhanced (S 158 2N OT)
62231 spectra in LIBRARVNB searched for maximum PURITY
938 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 15969 HYDROXYLAMINE, 0-DECYL-
2 15358 UNDECANE, 3-METHYL-
3 37462 HEPTADECANE, 2,6-DIMETHYL-
4 22536 TRIDECANE, 3-METHYL-
5 37465 NONADECANE
6 22530 TETRADECANE
7 19016 UNDECANE, 4,7-DIMETHYL-
8 25997 PENTADECANE
9 42196 HEPTADECANE, 2,6,10,14-TETRAMETHYL-
Rank
1
2
3
4
5
6
7
8
9
Formula
C10.H23.0.N
C12.H26
C19.H40
C14.H30
C19.H40
C14.H30
C13.H28
C15.H32
C21.H44
Rank
1
2
3
4
5
6
7
8
9
Ret.Time B.P.Int.
US.Par.1
H.Ut
173
170
268
198
268
198
184
212
296
B.Pk Purity Fit
43
57
57
57
57
43
43
57
57
US. Par. 2
794 948
789 943
782 913
778 932
775 919
772 930
771 954
766 933
762 929
C.A.S. #
29812-79-1
1002-43-3
54105-67-8
6418-41-3
629-92-5
629-59-4
17301-32-5
629-62-9
18344-37-1
RFit
813
792
827
791
829
821
778
809
802
1380
-------
MID LIBRARY SEARCH (LIBRARYNB)
08/31/98 23:28:80 + 12:23
SAMPLE: S-MM5-4 1/3SA/100M INST. ID: F16
CONDS.: UG/ML *100ML *100Z/100Z *
-------
Library Search Data: 30068110 #1118 Base m/z: 57
08/31/9823:28:00+12:26 Cali: 30068110 # 3 RIC: 73216.
Sample: S-MM5-4 1/3SA/100M 1NST. ID: F16
Conds.: UG/ML *100ML *100%/100% *(NA/NA )/1/3SA NA H
Enhanced (S 15B 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
590 matched at least 7 of the 16 largest peaks in the unknown
2,6-DIMETHYL-
2,6,10,14-TETRAMETHYL-
Rank In. Name
1 37462 HEPTADECANE,
2 37465 NONADECANE
3 42196 HEPTADECANE.
4 46161 TRICOSANE
5 32059 HEPTADECANE
5 25991 DODECANE, 2,6,10-TR1METHYL-
7 37466 PENTADECANE, 2.6,10,14-TETRAMETHYL-
B 42192 HEPTADECANE, 2,6,10,15-TETRAMETHYL-
9 26001 DCOECANE, 2,7,10-TRIMETHYL-
?ank
1
2
5
+
3
S
r
3
?
Formula
C19.H40
C19.H40
C21.H44
C23.H48
C17.H36
C15.H32
C19.H40
C21.H44
C15.H32
lank
1
3
5
j
b
T
3
M.Wt
268
268
296
324
240
212
268
296
212
B.Pk
57
57
57
43
57
57
71
57
57
Purity
834
833
823
813
802
802
801
801
800
Fit
941
957
935
915
927
962
930
952
963
RFit
842
853
838
860
836
804
814
828
800
Ret.Time
B.P.Int.
US.Par.1
US.Par.2
C.A.S.
54105-
629-
18344-
638-
629-
3891-
1921-
54833-
74645-
#
67-8
92-5
37-1
67-5
78-7
98-3
70-6
48-6
98-0
1
-------
MID LIBRARY SEARCH
98/31x98 23:28:09 + 12:26
SAMPLE: S-MM5-4 1/3SA/100M INST. ID: F16
CONDS.: UG/ML *100ML * 100Z/1 W?. *
DATA: 38868110 #1118
CALI: 38068110 ft 3
BASE M/Z: 57
RIC: 73216.
1210 -
SAMPLE
C19.H40
1210 i
M WT 268
B PK 57
RANK 1
ft 37462
PUR 834
C19.H40
1210 i
M WT 268
B PK 57
RANK 2
ft 37465
PUR 833
C21.H44
1210 1
M WT 296
B PK 57
RANK 3
ft 42196
PUR 823
M/Z
,1
,1
|
ll
HEPTADECANE, 2,6-DIMETHYL- c? V \C,CTV^eV
||
|
NONADECANE
111 ,• i
[1 ll| _ III _..! ,,.-'.. |- , 'I .-••...•.,-•,....-.-..,. *—^l • 1 — 1 •-'
HEPTADECANE , 2,6,10,1 4-TETRAMETHYL-
50
100 150 200 250
h*
CO
G'l
-------
Library Search Data: 30068110 #1190 Base m/z: 57
08/31/9823:28:00+13:14 Cati: 30068110 # 3 RIC: 45056.
Sample: S-MM5-4 1/3SA/100M INST. ID: F16
Conds.: UG/ML *100ML *100%/100% *(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
62231 spectra in L1BRARYNB searched for maximum PURITY
294 matched at least 8 of the 16 largest peaks in the unknown
Rank In. Name
1 37465 NONADECANE
2 37462 HEPTADECANE, 2,6-DIMETHYL-
3 15969 HYDROXYLAMINE, 0-DECYL-
4 42196 HEPTADECANE, 2,6.10,14-TETRAMETHYL-
5 19016 UNDECANE, 4,7-DIMETHYL-
6 15353 2,6-DIMETHYLDECANE
7 19005 IWDECANE, 3.8-D1METHYL-
8 19523 1-DECANOL, 2-ETHYL-
9 46161 TRICOSANE
Rank
1
2
3
4
5
6
7
8
9
Rank
1
2
3
4
5
6
7
8
9
Formula
C19.H40
C19.H40
C10.H23.0.N
C21.H44
C13.H28
C12.H26
C13.H28
C12.H26.0
C23.H48
Ret. Time
B.P.Int.
US.Par.1
H.Ut
268
268
173
296
184
170
184
186
324
B.Pk Purity Fit
57
57
43
57
43
43
57
57
43
US. Par. 2
728 940
727 920
727 962
707 931
698 959
693 926
689 970
687 925
686 877
C.A.S. #
629-92-5
54105-67-8
29812-79-1
18344-37-1
17301-32-5
13150-81-7
17301-30-3
21078-65-9
638-67-5
RFit
761
759
727
738
704
697
689
696
772
13S4
-------
MID LIBRARY SEARCH
08/31/98 23:28:08 + 13:14
SAMPLE: S-MM5-4 1/3SA/100M
CONDS.: UG/ML *100ML
ENHANCED /l/3SA NA M
30068110 #1190
30068110 tt 3
BASE M/Z: 57
RIC: 45056.
1073 i
SAMPLE
C19.H40
1073 n
M WT 268
B PK 57
RANK 1
# 37465
PUR 728
C19.H40
1073 i
M WT 268
B PK 57
RANK 2
tt 37462
PUR 727
C10.H23.0
1973
M WT 173
B PK 43
RANK 3
* 15969
PUR 727
M/Z
.N
1
50
1 ov ^
NONADECANE
III ill ..i .. ........
HEPTADECANE , 2,6-DIMETHYL-
Ill LJ jl •
HYDROXYLAMINE, 0-DECYL-
''I
100 150 200 250
CO
Cr>
CM
-------
Library Search Data: 30068110 #1264 Base m/z: 57
08/31/98 23:28:00 + 14:04 Cali: 30068110 # 3 RIC: 34496.
Sample: S-HH5-4 1/3SA/100M INST. ID: F16
Conds.: UG/ML *100ML *100%/100% *(NA/NA )/1/3SA NA H
Enhanced (S 15B 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
819 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 37462 HEPTADECANE, 2,6-DIMETHYL-
2 42196 HEPTADECANE, 2,6,10,14-TETRAMETHYL-
3 32058 HEXADECANE, 3-METHYL-
4 15969 HYDROXYLAMINE, 0-DECYL-
5 37465 NONADECANE
6 25997 PENTADECANE
7 34811 HEPTADECANE, 2-METHYL-
8 34816 HEPTADECANE, 4-METHYL-
9 42192 HEPTADECANE, 2,6.10,15-TETRAMETHYL-
Rank
1
2
3
4
5
6
7
8
9
Rank
1
2
3
4
5
6
7
8
9
Formula
C19.H40
C21.H44
C17.H36
C10.H23.0.N
C19.H40
C15.H32
C18.H38
C18.H38
C21.H44.
Ret. Time
B.P.Int.
US.Par.1
M.Wt
268
296
240
173
268
212
254
254
296
B.Pk Purity Fit
57
57
57
43
57
57
43
43
57
US. Par. 2
706 921
701 933
698 928
687 968
685 936
674 947
673 885
669 894
669 904
C.A.S. #
54105-67-8
18344-37-1
6418-43-5
29812-79-1
629-92-5
629-62-9
1560-89-0
26429-11-8
54833-48-6
RFit
728
725
717
690
723
704
725
704
706
1
-------
MID LIBRARY SEARCH
-------
Library Search Data: 30068110 #1335 Base m/z: 57
08/31/9823:28:00+14:51 Cali: 30068110 # 3 RIC: 22112.
Sample: S-MM5-4 1/3SA/100M 1NST. ID: F16
Conds.: UG/ML *100ML *100%/100% *(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
470 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 37456 2-METHYLOCTADECANE
2 37462 HEPTADECANE, 2,6-DIMETHYL-
3 19523 1-DECANOL, 2-ETHYL-
4 29263 HEXADECANE
5 42196 HEPTADECANE, 2,6,10,14-TETRAMETHYL-
6 32058 HEXADECANE, 3-METHYL-
7 37458 OCTADECANE, 2-METHYL-
8 37465 NONADECANE
9 15969 HYDROXYLAMINE, 0-DECYL-
M.Wt B.Pk Purity Fit RFit
Rank
1
2
3
4
5
6
7
8
9
Formula
C19.H40
C19.H40
C12.H26.0
C16.H34
C21.H44
C17.H36
C19.H40
C19.H40
C10.H23.0.N
Rank
1
2
3
4
5
6
7
8
9
268
268
186
226
296
240
268
268
173
43
57
57
57
57
57
43
57
43
571
568
548
547
542
541
534
533
532
855
831
935
863
823
885
819
900
926
615
599
557
599
582
584
607
578
554
Ret.Time B.P.lnt.
US.Par.1
US.Par.2
C.A.S. #
54105-67-8
21078-65-9
544-76-3
18344-37-1
6418-43-5
1560-88-9
629-92-5
29812-79-1
-j <;
-L O
-------
MID LIBRARY SEARCH (LIBRARYNB)
88/31/98 23:28:00 + 14:51
SAMPLE: S-MM5-4 1/3SA/100M
CONDS.: UG/ML *180ML
ENHANCED
DATA:
CALI:
INST. ID: F16
*
-------
TIC SELECTION REPORT
DATA FILE: 30068110
THE FOLLOWING PEAKS WERE REJECTED BECAUSE
AT LEAST 40 % OF THEIR SIZE WAS ACCOUNTED FOR BY
TARGET COMPOUNDS ELUTING WITHIN 4 SCANS OF THE
PEAK TOP.
SCAN
340
530
829
1087
1552
1783
SIZE
197830.
455680.
367104.
361984.
257952.
238432.
AMOUNT
21.556
49.651
40.000
40.000
40.000
40.000
TOTAL NUMBER OF UNIDENTIFIED PEAKS WITH SIZE
GREATER THAN 10 % OF THE CLOSEST INTERNAL STANDARD
THAT DOES NOT HAVE INTERFERENCES = 84
INTERNAL STANDARDS THAT HAVE RIC SIZE LESS THAN
50 % OR GREATER THAN 200 % OF THE ESTIMATED RIC SIZE
ARE CONSIDERED TO HAVE INTERFERENCES AND WILL NOT BE USED
FOR QUANT I TAT ION.
PERCENT OF
ESTIMATED
# INTERNAL STANDARD RIC SIZE RIC SIZE SCAN
1 CI40 NAPHTHALENE-OS 455680. 248 * 530
2 CI50 ACENAPHTHENE-D10 367104. 161 829
3 CI60 PHENANTHRENE-D10 361984. 145 1087
4 CI70 CHRYSENE-D12 257952. 153 1552
5 CITS PERYLENE-D12 238432. 162 1783
* INDICATES INTERFERENCE
SIZE = AREA
iSSG
-------
Semivolatile Organics
Method 0010/8270
Client Name:
Client ID:
LAB ID:
Matrix:
Authorized:
Pacific Environmental Services
S-MM5-5-F,FH,XAD,COND,BH
300681-0011-SA
AIRTRAIN Sampled:
30 JUL 98 Prepared:
28 JUL 98
31 JUL 98
Dilution Factor: 100
Parameter
Phenol
bis(2-Chloroethyl)ether
2-Chlorophenol
1,3-Di chIorobenzene
1,4-Di chlorobenzene
Benzyl alcohol
1,2-Dichlorobenzene
2-Methylphenol
2,2' -Oxybi s(1-chloropropane)
3/4-Methylphenol
N-Nitroso-di-n-propylamine
Hexachloroethane
Nitrobenzene
Isophorone
2-Nitrophenol
2,4-Dimethylphenol
Benzoic acid
bi s(2-Chloroethoxy)-methane
2,4-Dichlorophenol
1,2,4-Trichlorobenzene
Naphthalene
4-Chloroaniline
Hexachlorobutadi ene
4-Chloro-3-methylphenol
2-Methylnaphthalene
Hexachlorocyclopentadi ene
2,4,6-Trichlorophenol
2,4,5-Tri chlorophenol
2-Chloronaphthalene
2-Nitroaniline
Dimethyl phthalate
Acenaphthylene
3-Nitroaniline
Acenaphthene
2,4-Dinitrophenol
Wet wt.
Result
Units
Received: 30 JUL 98
Analyzed: 31 AUG 98
Reporting
Limit
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
2600
ND
ND
ND
4400
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ug/Sampl e
ug/Sampl e
ug/Sampl e
ug/Sampl e
ug/Sampl e
ug/Sampl e
ug/Sampl e
ug/Sampl e
ug/Sampl e
ug/Sampl e
ug/ Sample
ug/ Sample
ug/Sampl e
ug/Sampl e
ug/Sampl e
ug/Sampl e
ug/Sampl e
ug/Sampl e
ug/Sampl e
ug/Sampl e
ug/Sampl e
ug/ Sample
ug/Sampl e
ug/Sampl e
ug/Sampl e
ug/Sampl e
ug/ Sample
ug/Sampl e
ug/Sampl e
ug/Sampl e
ug/ Sample
ug/Sampl e
ug/Sampl e
ug/ Sample
ug/Sampl e
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
15000
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
15000
3000
3000
3000
3000
15000
3000
15000
Qualifier
GR
Note G
Note J
Note R ...r_. ..
ND = Not Detected
Reporting limit(s) raised due to matrix interference.
Result is detected below the reporting limit or is an estimated concentrati
Reporting limit(s) raised due to sample volume limitations.
ifii* a/*+"a/4
on.
Reported By: Emily Uebelhoer
Approved By: Mike Orbanosky
The cover letter is an integral part of this report.
Rev 230787
1391
-------
Client Name:
Client ID:
LAB ID:
Matrix:
Authorized:
Semivolatile Organics
Method 0010/8270
Pacific Environmental Services
S-MM5-5-F,FH,XAD,COND,BH
300681-0011-SA
AIRTRAIN Sampled: 28 JUL 98
30 JUL 98 Prepared: 31 JUL 98
(cont.)
Dilution Factor: 100
Parameter
4-Nitrophenol
Dibenzofuran
2,4-Dinitrotoluene
2,6-Dinitrotoluene
Diethyl phthalate
4-Chlorophenyl phenyl ether
Fluorene
4-Nitroaniline
4,6-Dinitro-2-methylphenol
N-Nitrosodiphenylamine
4-Bromophenyl phenyl ether
Hexachlorobenzene
Pentachlorophenol
Phenanthrene
Anthracene
Di-n-butyl phthalate
Fluorantnene
Pyrene
Butyl benzyl phthalate
3,3'-Dichlorobenzidine
Benzo(a)anthracene
bis(2-Ethylhexyl)-phthalate
Chrysene
Di-n-octyl phthalate
Wet wt.
Result
Benzofb
Benzofk
Benzo(a
Indenof
fluoranthene
fluoranthene
pyrene
,2,3-cd}pyrene
Dibenz(a,h)anthracene
Benzo(g,h,i)perylene
Acetophenone
4-Aminobiphenyl
Aniline
Benzidine
3,3'-Dimethylbenzidine
N-Nitrosodimethylamine
N-Nitrosomorpholine
Units
Received: 30 JUL 98
Analyzed: 31 AU6 98
Reporting
Limit
Qualifier
ND
ND
ND
ND
ND
ND
560
ND
ND
ND
ND
ND
ND
1200
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sampl e
ug/Sample
ug/Sampl e
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sampl e
ug/Sample
ug/Sample
ug/Sample
ug/Sampl e
ug/Sample
ug/Sample
ug/Sample
ug/Sampl e
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
15000
3000
3000
3000
3000
3000
3000
15000
15000
3000
3000
3000
15000
3000
3000
3000
3000
3000
3000
6000
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
15000
3000
30000
6000
3000
3000
Note J = Result is detected below the reporting limit or is an estimated concentration.
ND = Not Detected
Reported By: Emily Uebelhoer
Approved By: Mike Orbanosky
The cover letter is an integral part of this report.
Rev 230787
'< c -•:
-------
Semivolatile Organics
Method 0010/8270
(cont,
Client Name: Pacific Environmental Services
Client ID:
LAB ID:
Matrix:
Authorized:
S-MM5-5-F,FH,XAD,COND,BH
300681-0011-SA
AIRTRAIN
30 JUL 98
Sampled: 28 JUL 98
Prepared: 31 JUL 98
Dilution Factor: 100
Parameter
(PCNB)
Pentachloronitrobenzene
o-Toluidine
2-Methoxybenzenami ne
Biphenyl
Chloroacetophenone
Cumene
DBCP (l,2-Dibromo-3-chloropropane)
Benzo(e)pyrene
N-N-Diethylaniline
Dimethyl aniline
3,3'-Dimethoxybenzidine
Hydroquinone
4,4'-Methyl-bis(2-chloroaniline)
4-Nitrodiphenyl
Trifluralin
Wet wt.
Result
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Units
ug/Sampl e
ug/Sample
ug/S ample
ug/Sampl e
ug/Sampl e
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sampl e
ug/Sampl e
ug/Sample
ug/Sampl e
ug/Sampl e
ug/Sampl e
Reporting
Limit
15000
6000
--
--
--
--
--
--
--
--
--
--
--
--
--
Received: 30 JUL 98
Analyzed: 31 AUG 98
Qualifier
Surrogate
Nitrobenzene-d5
2-Fluorobiphenyl
Terphenyl-dl4
Phenol-d5
2-Fluorophenol
2,4,6-Tri bromophenol
Recovery
ND %
ND %
ND %
ND %
ND %
ND %
Acceptable Range
45
62
58
43
36
58
107
110
135
130
111
131
Note H = Spiked analyte not detected because of required sample dilution.
ND = Not Detected
Reported By: Emily Uebelhoer
Approved By: Mike Orbanosky
The cover letter is an integral part of this report.
Rev 230787
f:> o
ot
-------
Semivolatiles Library Search (20 Compound TID)
Method 8270
Client Name: Pacific Environmental Services
Client ID:
LAB ID:
Matrix:
Authorized:
S-MM5-5-F,FH,XAD,COND,BH
300681-0011-SA
AIRTRAIN
30 JUL 98
Sampled: 28 JUL 98
Prepared: NA
Dilution Factor: 100
Parameter
Unknown
Unknown
Decane. 2,9-dimethyl-
Undecane, 2,6-dimethyl-
Unknown
Unknown alkane
Unknown
Unknown alkane
Unknown
Unknown
Dodecane, 2,6,10-trimethyl-
Tetradecane
Unknown
Heptadecane, 2,6,10,14 -tetramethyl
Dodecane, 3-methyl-
Oxi rane, hexadecyl-
Unknown alkane
Unknown alkane
Heptadecane, 2,6-dimethyl-
Nonadecane
Result
11000
13000
9200
9500
15000
20000
12000
11000
10000
12000
19000
25000
15000
22000
25000
13000
27000
14000
28000
11000
Units
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
Received: 30 JUL 98
Analyzed: 31 AUG 98
Reporting
Limit Qualifier
0
0
0
0
0
0
0
0
0
Note 0 = Or structurally similar compound (isomer).
NA = Not Applicable
Reported By: Emily Uebelhoer
Approved By: Mike Orbanosky
The cover letter is an integral part of this report.
Rev 230787
r f'
-------
Sample: S-MM5-5
Client: PACIF1
Analyst: DAT
QUANTERRA GC/HS
Target Compound Data Summary Sheet
1/3SA/100M
Instrument ID: F16
Quan List Threshold: 0.95
Data File: 30068111
Std Id: ST16980831
INST. ID: F16
Date Analyzed: 08/31/98 23:58
Run Factor: 300.
Surrogate Vol.:
100.
Surrogate
Surrogate Spike Recoveries
8270-G, LIMS 10/10/96
Surrogate Amount (ug)
Spiked Measured
CS20 NITROBENZENE-05
CS25 2-FLUOR08IPHENY
CS30 TERPHENYL-D14
CS45 PHENOL -D5
CS50 2-FLUOROPHENOL
CS55 2,4,6-TRIBROMOP
50.0
50.00
50.0
100.
100.
100.
BDL
108.0
BDL
BDL
BDL
BDL
X Recovery
Measured QC limits
=======«=================
0* H 45 107
* 62 110
58 135
A3 130
36 111
216.
0*
0*
0*
0*
58 131
Parameter
=================:s:====
HEXACHLOROBENZENE-C13
C310 N-NITROSOOIMETHYLAMINE
PYRIDINE
2-PICOLINE
M-NITROSOMETHYLETHYLAMINE
METHYLMETHANESULFONATE
N-NITROSODIETHYLAMINE
ETHYLMETHANE SULFONATE
PENTACHLOROETHANE
C320 ANILINE
C315 PHENOL
C325 BIS(2-CHLOROETHYL)ETHER
C330 2-CHLOROPHENOL
C335 1,3-DICHLOROBENZENE
C340 1,4-DICHLOROBENZENE
C345 BENZYL ALCOHOL
C350 1,2-DICHLOROBENZENE
C355 2-METHYLPHENOL
C360 2,2'-OXYBIS(1-CLPROPAN)
C361 ACETOPHENONE
N-NITROSOPYRROLIOINE
N-NITROSOMORPHOLINE
3-METHYL PHENOL
C365 4-METHYLPHENOL
C370 N-NITROSO-DI-N-PROPYLAM
0-TOLUIDINE
C375 HEXACHLOROETHANE
C410 NITROBENZENE
N-NITROSOPIPERIDINE
Target Compounds: SAP9
Reporting
Scan Result Units Limit
ND
MINE ND
ND
ND
NE ND
ND
ND
ND
ND
ND
ND
ETHER ND
ND
E ND
E ND
ND
E ND
ND
OPAN) ND
ND
NO
ND
ND
ND
PYLAM ND
ND
ND
ND
ND
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
Reviewed by:
3000
3000
6000
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
.0
3000.0
3000
.0
3000.0
3000
3000
3000
3000
3000
1
m
.0
.0
.0
.0
.0
M> V\J
Vf/^ t*k
aV^
13 c r
-L O t, , j
-------
OUANTERRA GC/MS
Target Compound Data Summary Sheet
Data File: 30068111
Std Id: ST16980831
Sample: S-MM5-5 1/3SA/100M
Client: PACIFI
Analyst: DAT Instrument ID:
Quan List Threshold: 0.95
INST. ID:
F16
Date Analyzed: 08/31/98 23:
F16
Run Factor
Surrogate
: 300.
Vol.: 100.
Target Compounds: SAP9
Parameter Scan
C415 ISOPHORONE
C420 2-NITROPHENOL
C425 2,4-DIMETHYLPHENOL
C435 BIS(2-CHLOROETHOXY)METH
C440 2,4-DICHLOROPHENOL
C430 BENZOIC ACID
AA-DIMETHYLPHENETHYLAMINE
C445 1,2,4-TRICHLOROBENZENE
C450 NAPHTHALENE
C455 4-CHLOROANALINE
2,6-DICHLOROPHENOL
HEXACHLOROPROPENE
C460 HEXACHLOROBUTADIENE
P-PHENYLENE DIAMINE
N-NITROSODI-N-BUTYLAMINE
C465 4-CHLORO-3-METHYLPHENO
SAFROLE
C470 2-METHYLNAPHTHALENE 653 /
1,2,4,5-TETRACHLOROBENZENE
ISOSAFROLE (#1)
C510 HEXACHLOROCYCLOPENTADI
C515 2,4,6-TRICHLOROPHENOL
C520 2,4,5-TRICHLOROPHENOL
ISOSAFROLE (#2)
C525 2-CHLORONAPHTHALENE
1-CHLORONAPHTHALENE
C530 2-NITROANALINE
1,4-NAPHTHOQUINONE
C535 DIMETHYLPHTHALATE
1,3-DINITROBENZENE
C540 ACENAPHTHYLENE
C543 2,6-DINITROTOLUENE
C545 3-NITROANILINE
C550 ACENAPHTHENE
C555 2,4-DINITROPHENOL
C565 DIBENZOFURAN
C560 4-NITROPHENOL
PENTACHLOROBENZENE
C570 2,4-DlNITROTOLUENE
1-NAPHTHYLAMINE
2-NAPHTHYLAMINE
',3,4.6-TETRACHLOROPHENOL
:580 DIETHYLPHTHALATE
!590 FLUORENE
Result
ND
ND
ND
ND
ND
ND
ND
ND^
>*C^2^
ND
ND
ND
ND
ND
ND
ND
^mj~^\
4400. )
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
Units
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
"YlG/A
•'UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
1 UG/A
Reporting
Limit
3000.0
3000.0
3000.0
3000.0
3000.0
15000.0
3000.0
3000.0
3000.0 ^»
3000.0
3000.0
3000.0
3000.0
3000.0
3000.0
3000.0
3000.0
3000.0 *^
3000.0
6000.0
3000.0
3000.0
3000.0
6000.0
3000.0
1500.0
15000.0
3000.0
3000.0
3000.0
3000.0
3000.0
15000.0
3000.0
15000.0
3000.0
15000.0
3000.0
3000.0
3000.0
3000.0
6000.0
3000.0
3000.0 3"
i
3S6
-------
QUANTERRA GC/MS
Target Compound Data Summary sheet
Data File: 30068111
Std Id: ST16980831
Sample: S-MM5-5 1/3SA/100M 1NST. ID: F16
Client: PACIFI Date Analyzed: 08/31/98 23:58
Analyst: DAT Instrument ID: F16 Run Factor: 300.
Quan List Threshold: 0.95 Surrogate Vol.: 100.
Parameter
Target Compounds: SAP9
Scan Result
Reporting
Units Limit
C585 4-CHLOROPHENYL-PHENYLE
5-NITRO-O-TOLUIDINE
C595 4-NITROANALINE
C610 4.6-DINITRO-2-METHYLPH
C615 N-NITROSODIPHENYLAMINE
C620 AZOBENZENE
SYH-TRINITROBENZENE
C625 4-BROMOPHENYL-PHENYLET
PHENACETIN
DIALLATE 234
C630 HEXACHLOROBENZENE
4-AMINOBIPHENYL
C635 PENTACHLOROPHENOL
PRONAMIDE
PENTACHLORON I TROBENZENE
C640 PHENANTHRENE „
C645 ANTHRACENE ffi
2SECBUTYL -4 , 6-D I N 1 TROPHENOL
C647 CARBAZOLE
C650 DI-N-BUTYLPHTHALATE
4-NITROQUINOLINE-1-OXIDE
METHAPYRILENE
ISOORIN
C655 FLUORANTHENE
CHLOROBENZILATE
C710 BENZIDINE
C715 PYRENE
ARAMITE (#1)
ARAMITE (#2)
P-DIMETHYLAMINOAZOBENZENE
3,3'-DIMETHYLBENZIDINE
KEPONE
C720 BUTYLBENZYLPHTHALATE
2-ACETYLAMINOFLUORENE
C730 BENZO(A)ANTHRACENE
C725 3,3'-DlCHLOROBENZIDINE
C740 CHRYSENE
C745 BIS(2-ETHYLHEXYL)PHTHA
3-METHYLCHOLANTHRENE
C760 Dl-N-OCTYL PHTHALATE
C765 BENZO(B)FLUORANTHENE
7, 12-OIMETHYLBENZANTHRACENE
C770 BENZO(K) FLUORANTHENE
HEXACHLOROPHENE 1761
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
,s (JtCft^P^1
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
/*°~~\
^MOAN
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
1 UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
j« UG/A
Vn. /_
3000.0
3000.0
15000.0
15000.0
3000.0
3000.0
3000.0
3000.0
3000.0
3000.0
3000.0
3000.0
15000.0
3000.0
15000.0
3000.0
3000.0
3000.0
3000.0
3000.0
3000.0
3000.0
3000.0
3000.0
3000.0
30000.0
3000.0
3000.0
3000.0
3000.0
3000.0
15000.0
3000.0
3000.0
3000.0
6000.0
3000.0
3000.0
3000.0
3000.0
3000.0
3000.0
3000.0
3000.0
13£7
-------
QUANTERRA GC/MS
Target Compound Data Summary Sheet
Data File: 30068111
Std Id: ST16980831
Sample: S-MM5-5 1/3SA/100M INST. ID: F16
Client: PACIFI Date Analyzed: 08/31/98 23:58
Analyst: OAT Instrument ID: F16 Run Factor: 300.
Quan List Threshold: 0.95 Surrogate Vol.: 100.
Target Compounds: SAP9
Reporting
Parameter Scan Result Units Limit
C775 8ENZO(A)PYRENE ND UG/A 3000.0
C780 INDENO(1,2,3-CD)PYRENE ND UG/A 3000.0
C785 D1BENZ(A,H)ANTHRACENE ND UG/A 3000.0
C790 BENZO(G,H,I)PERYLENE ND UG/A 3000.0
-------
DATA FROM FILE: 38068111 SCANS 93 TO 1203 ACQUIRED: 08/31/98 23:58:00
CALI: 30068111 #3
SAMPLE: S-MM5-5 1/3SA/100M INST. ID: F16
CONDS.: UG/ML *100ML *100Z/100Z *CNA/NA V1/3SA NA M
200 _
2:13
400 .
4:27
600 .
6:40
800 _
8:54
1000 _
11:07
_L
J_
JL
J 100.0?; ( 963584.)
CI30 1,4-DICHLOROBENZENE-D4 152IS1* 01
3855-82-1
CI40 NAPHTHALENE-08
136IS2# 01
2-FLUOROBIPHENYL
172SS3* 03
50 ACENAPHTHENE-010
164IS3* 01
CI60 PHENANTHRENE-D10
188IS4* 01
1146-65-2
321-60-8
15067-26-2
1517-22-2
CO
CD
-------
DATA FROM FILE: 30968111 SCANS 1203 TO 2158 ACQUIRED: 08/31/98 23:58:00
CALI: 30068111 #3
SAMPLE: S-MM5-5 1/3SA/100M INST. ID: F16
CONDS.: UG/ML *100ML *100Z/100Z *
-------
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46 S2# 40 C440 2,4-DICHLOROPHENOL 162 A BB 520 2 312. 0.308 0.372
47 S2# 45 C430 BENZOIC ACID 122 2 NOT FOUND
48 S2# 50 AA-DIMETHYLPHENETHYLAMIN 58 2 NOT FOUND
49 S2# 55 C445 1,2,4-TRICHLOROBENZ 180 AW 524 2 454. 0.331 0.503
14CS
-------
50
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
69
70
71
72
73
74
75
76
77
78
79
80
81
82
83
84
85
86
87
88
89
90
91
92
93
94
95
96
97
98
99
100
101
102
103
104
105
106
107
108
109
110
S2* 60
52* 80
S2* 85
52* 90
S2* 95
52*115
52*120
52*130
S2*140
52*145
S3* 10
S3* 15
S3* 20
S3* 25
S3* 30
S3* 35
S3* 40
S3* 42
S3* 45
S3# 50
S3* 55
S3* 60
S3* 65
S3* 70
S3* 75
S3* 80
S3* 85
S3* 90
S3* 95
S3#100
53*105
53*110
53*115
S3#120
S3#130
53*135
S3#140
S3#145
S3#150
54* 10
S4# 15
S4* 20
S4* 25
S4* 30
54* 35
54* 37
54* 40
S4# 45
S4# 50
54* 55
C480 NAPHTHALENE/
C4W-*rCHC5ROANAL I NE
2,6-DICHLOROPHENOL
HEXACHLOROPROPENE
C460 HEXACHLOROBUTADIENE
P-PHENYLENE DIAMINE
N-NITROSODI -N-BUTYLAMINE
C465 4-CHLORO-3-METHYLPH
SAFROtE *^~->
C47«2-MeTHYLNAPHTHALENE_
1 , 2 , 4>^EflWCHTOROBENZE
ISOSAFROLE (#1)
C510 HEXACHLOROCYCLOPENT
C515 2,4,6-TRICHLOROPHEN
C520 2.4,5-TRICHLOROPHEN
ISOSAFROLE (#2)
C525 2-CHLORONAPHTHALENE
1-CHLORONAPHTHALEN
C530 2-NITROANALINE
1,4-NAPHTHOQUINONE
C535 DIMETHYLPHTHALATE
1,3-DINITROBENZENE
C540 ACENAPHTHYLENE
C543 2,6-DINITROTOLUENE
C545 3-NITROANILINE
C550 ACENAPHTHENE
C555 2,4-DINITROPHENOL
C565 DIBENZOFURAN
C560 4-NITROPHENOL
PENTACHLOROBENZENE
C570 2,4-DINITROTOLUENE
1-NAPHTHYLAMINE
2-NAPHTHYLAMINE
2,3,4.6-TETRACHLOROPHENO
CSSODlEIMteajJIALATE
C59"o"~FLUORENE J^
C5B5-*-CTCOROPHENY L - PHEN
5-NITRO-O-TOLUIDINE
C595 4-N1TROANAL1NE
C610 4.6-DINITRO-2-METHY
C615 N-NITROSOOIPHENYLAM
C620 AZOBENZENE
SYM-TRINITROBENZENE
C625 4-BROMOPHENYL-PHENY
PHENACETIN
01ALLATE
C630 HEXACHLOROBENZENE
4-AMINOB1PHENYL
C635 PENTACHLOROPHENOL
PRONAMIDE
54* 60 PENTACJiLOBON 1 TROPiMZ|NE
54* 65-
S4* 70"
S4* 75
54* 80
54* 85
S4#100
54*105
JS4*106
54*110
S4*120
-C640 PHENANTHRENE^_^X
T645\»m«ACCTF"""'~~'^
2SECBUTYL-4.6-DINITROPHE
C647 CARBAZOLE
C650 DI-N-BUTYLPHTHALATE
4-N1TROQU1NOL1NE-1 -OXIDE
METHAPYRILENE
ISODRIN
C655 FLUORANTHENE
CHLOROBENZILATE
128
127
162
213
225
108
84
107
j*2
214
162
237
196
196
104
162
162
65
158
163
168
152
165
138
153
184
168
109
250
165
143
143
232
149
166
204
152
138
198
169
77
75
248
108
234
284
169
266
173
237
178
178
211
167
149
190
58
193
202
139
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
BV
BB
BB
BB
BB
BB
BB
BV
BV
BB
BB
BB
BB
BB
VB
BB
VB
BB
BB
BB
BB
W
BB
533 2
556 2
2 NOT
2 NOT
2 NOT
2 NOT
2 NOT
2 NOT
652 2
653 2
3 NOT
698 3
3 NOT
3 NOT
3 NOT
739 3
3 HOT
3 NOT
764 3
3 NOT
3 NOT
3 NOT
3 NOT
3 NOT
3 NOT
835 3
859 3
867 3
3 NOT
3 NOT
882 3
3 NOT
902 3
898 3
3 NOT
927 3
3 NOT
942 3
949 3
4 NOT
964 4
4 NOT
4 NOT
4 NOT
4 NOT
4 NOT
4 NOT
4 NOT
4 NOT
4 NOT
1064 4
1091 4
4 NOT
4 NOT
1149 4
4 NOT
1240 4
4 NOT
1272 4
1300 4
4 NOT
24195 .
439.
FOUND
FOUND
FOUND
FOUND
FOUND
FOUND
1274.
30297.
FOUND
1034.
FOUND
FOUND
FOUND
420.
FOUND
FOUND
476.
FOUND
FOUND
FOUND
FOUND
FOUND
FOUND
1969.
206.
1131.
FOUND
FOUND
391.
FOUND
472.
155.
FOUND
3769.
FOUND
1772.
396.
FOUND
3698.
FOUND
FOUND
FOUND
FOUND
FOUND
FOUND
FOUND
FOUND
FOUND
72.
11634.
FOUND
FOUND
472.
FOUND
183.
FOUND
2153.
591.
FOUND
1.
0.
0.
0.
0.
0.
0.
1.
0.
022
454
248
75V
v~-.
044
195
502
159
189
1.669
0.397
0.
0.
1.
966
,297
.298
0.356
0.
0.
0
1
0
0
0
0
.307
.551
.080
.033
.764
.073
.127
.900
JL:
0.
1.
•—— !-•
15.
1.
0.
670<
354
8fif~
772 i
— — "
245
388
611
1.094
0.
0.
0.
700
436
634
0.314
0.
1.
3,
0.
2
.336
.869
.209
.830
.422
0.323
4
0
0
6
0
.063
.223
.910
.130
.237
14C
-------
111 S5# 10 C710 BENZ1DINE 184
112 S5# 15 C715 PYRENE 202 A BB
113 S5# 20 ARAMITE (#1) 185
114 S5# 25 ARAMITE (#2) 185
115 S5# 30 P-DIMETHYLAMINOAZOBENZEN 120
116 S5# 35 3,3'-DIMETHYLBENZIDINE 212
117 S5# 37 KEPONE 272
118 S5# 40 C720 BUTYLBENZYLPHTHALAT 149
119 S5# 45 2-ACETYLAMINOFLUORENE 181
120 S5# 50 C730 BENZO(A)ANTHRACENE 228 A BB
121 S5# 55 C725 3,3'-DlCHLOROBENZID 252
122 S5# 60 C740 CHRYSENE 228 A BB
123 S5# 65 C745 BIS(2-ETHYLHEXYL)PH 149
124 S5# 85 3-METHYLCHOLANTHRENE 268
125 S6# 10 C760 DI-N-OCTYL PHTHALAT 149
126 S6# 15 C765 BENZO(B)FLUORANTHEN 252
127 S6# 20 7,12-DIMETHYLBENZANTHRAC 256
128 S6# 25 C770 BENZO(K)FLUORANTHEN 252
129 S6# 30 HEXACHLOROPHENE 196 A VB
130 S6# 35 C775 BENZO(A)PYRENE 252
131 S6# 55 C780 INDENOC1,2,3-CD)PYR 276
132 S6# 60 C785 DIBENZ(A,H)ANTHRACE 278
133 S6# 65 C790 BENZO(G,H,I)PERYLEN 276
5 NOT FOUND
1336 5 2966. 1.323 1.004
5 NOT FOUND
5 NOT FOUND
5 NOT FOUND
5 NOT FOUND
5 NOT FOUND
5 NOT FOUND
5 NOT FOUND
1556 5 1877. 1.125 0.747
5 NOT FOUND
1556 5 1877. 1.014 0.828
5 NOT FOUND
5 NOT FOUND
6 NOT FOUND
6 NOT FOUND
6 NOT FOUND
6 NOT FOUND
1761 6 130. 0.004 17.527
6 NOT FOUND
6 NOT FOUND
6 NOT FOUND
6 NOT FOUND
14C4
-------
BNA, S LIBRARIES ANALYST: DATE:
QUANTERRA Internal Standard Check
Standard Filename: ST16980831 Analyzed: 08/31/98 12:31
| IS* 1 | IS* 2 | IS* 3 |
Standard | Area % | RT j Area X | RT | Area X | RT j
ST16980831 | 28649. | 3.78 | 100432. | 5.90 | 54347. | 9.21 |
Upper Limit j 57297.=+200) 4.28 | 200864.=+200) 6.40 j 108695.=+200) 9.71 j
Lower Limit | 14324.=+ 50| 3.28 | 50216.=+ 50) 5.40 j 27174.=+ 50| 8.71 j
Filename | | | | | | |
——————————————————————————————————————————3—————————S———————————————————————————
I II II II
1 30068111 | 30555.= 106| 3.78 | 109200.= 108| 5.90 | 62156.= 114| 9.23 |
I II I I I I
IS* 1 = CI30 1.4-D1CHLOROBENZENE-D4
IS* 2 = CI40 NAPHTHALENE-OS
IS* 3 = CI50 ACENAPHTHENE-D10
* - indicates an I.S. is outside QC linrit(s)
| IS* 4 | IS* 5 | IS* 6 |
Standard j Area % | RT j Area X | RT j Area X | RT j
ST16980831 | 98520. J12.08 | 62289. |17.26 | 50750. J19.83 |
Upper Limit j 197039.=+200j12.58 | 124578.=+200)17.76 j 101500.=+200)20.33 j
Lower Limit j 49260.=+ 50J11.58 j 31145.=+ 50J16.76 | 25375.=+ 50)19.33 |
Filename | | | | | | )
I II II II
1 30068111 | 110919.= 112)12.10 | 89347.= 143)17.27 | 73934.= 145)19.83 |
I II II II
IS* 4 = CI60 PHENANTHRENE-010
IS* 5 = CI70 CHRYSENE-D12
IS* 6 = CITS PERYLENE-D12
* - indicates an I.S. is outside QC limit(s)
14Cc
00
-------
TARGET COMPOUND COMPARISON
COMPOUND: C450 NAPHTHALENE
RAW DATA: 30068111 #533
08/31/98 23:58
SAMPLE: S-MM5-5 1/3SA/100M
CONDS.: UG/ML *100ML
128 S2# 60 91-20-3
BASE M/Z: 41
INST. ID: F16
'. */l/3SA NA M
RIC: 134400.
10.6-
5.3-:
7.1-
3.6-j
100.0-
50.0-:
M/Z
100.0-
50.0-:
0.0-:
-50.0-:
100. 0J
.
1.. .,1,11
, ll
II .uJllll 1,1
jlbi
ll,..,..,.,.
f^
v— -^
I.. ,...,..,ll,ll
ENHANCED DATA: 30068111 #533
,1
ii .1, i
.. ,1
1 ' ' ' 1 ' ' ' ' 1 ' ' ' '
STANDARD FILE: ST 16980831 #533
08/31/98 12:31
L .• 1 1.
1 ' 1 ' | '
50
i" ' i 'I'1' i ' i '
1 '
100
,
. ,1
N. J
\ $
I.!..,,!!.,,..,,. .L ,.,1
1 • 1 ' 1 • 1 • 1 • 1 • 1 • 1 • 1 • 1 • 1 • I • 1 • 1 •
BASE M/Z: 128 RIC: 19840.
l .1 1 .1
BASE M/Z: 128 RIC: 195840.
i
I • 1 | • l • i • l • l • | • l • l • i • i • | • i •
150 200 250
,i 1 . 1
8368.
5648.
r 79232.
b- **OUT**
o
en
-------
TARGET COMPOUND COMPARISON
COMPOUND! C478 2-METHYLNAPHTHALENE
142 S2#145
RAM DATA: 30068111 #653
08/31/98 23:58
SAMPLE: S-MM5-5 1/3SA/100M
CONDS.: UG/ML *100ML
91-57-6
BASE M/Z: 41
RIC: 194304.
INST. ID: F16
* ' • r r* t'i'|-i i i i [ i i i i -
: 142 RIC: 37952.
A—
i .. ,i . .
• • • i • • • • i ' • • • i ' - ' ' I-'-'-T-
: 142 RIC: 198144.
' ' 1 ••'•'•••• 1 ' ' ' 1 ' ' ' ' 1 | .••,,,, 1-,-y
120 140 150 160 180 201
. It 1. 1 i ii .1 , ,
r- 12368.
_
8608.
-
- 49792.
-
3
'- **OUT**
L
-------
TARGET COMPOUND COMPARISON
COMPOUND: C599 FLUORENE
166 S3#135
RAW DATA: 30068111 #927
08/31/98 23:58
SAMPLE: S-MM5-5 1/3SA/100M INST. ID: F16
CONDS.: UG/ML *100ML *100£/1007: *
i1'1 1
/
i • i
1 1
• i • i • i • | • i i • i • i • 'i ' i ' — r ~" — r — ' —
100 150 200
ll i 1 i i
.... 1 II . il.. il ll ,1 . . 1 il 1 i 1, HI i i, i 1 .
1 II
'II
9104.
1710.
r 52224.
r **oum
-------
TARGET COMPOUND COMPARISON
COMPOUND: C640 PHENANTHRENE
178 S4# 65
RAW DATA: 38068111 #1091
88/31/98 23:58
SAMPLE: S-MM5-5 1/3SA/100M INST. ID: F16
CONDS.: UG/ML *100ML *100Z/100Z */l/3SA NA M
85-01-8
BASE M/Z: 41
RIC: 155392.
11.4-
5.7-
4.3-
2.1-:
100.0-
50.0-:
M/Z
100.0-
50.0-:
0.0-
-50.0-:
100.0-
1
.. ......
Jll ....Jll,
1 ' i • \ • r • i • i
ENHANCED DATA:
I,
ill , p
. . .
1*1 * | ' 1 '
STANDARD
08/31/98
1*1 * | * 1 '
50
|
. II
.
.1 , ,,
i ' i
FILE:
12:31
•I1-
1 . i
r
l.i I.H III- LI.'
,V #
1. ..i ., .1 .1 .1, i. ,i 1.1 .1 .1 .1 ... 1. 1. 1 ..i ,i ii ,.l ...... i. ,i i
• i • 1 . . | . | . | . | . | . | i
30068111 #1091 BA
,1 i
ST 16980831
..1
, • 1 • ,
100
il 1 i
. l . ..... . ....... in. i.. i. h
1 i • i • i ' | • i ' i •
#1091 BA
. .,.,. ,h
i.i .1 ., ., i, .. .. [, ... .. .( ... .. , ,_t .. .. ... r .. ... .( (. .. .
SE M/Z: 178 RIC: 27648.
h . |. . ... .
I ' I < I ' I ' I < | • | • | • | • 1 •
5E M/Z: 178 RIC: 204544.
150 200 259
1
r 8352
r 3148
-
r 73344
- **OUT*^
—
c/
-------
Data Reduced by:^L.
Data Reviewed by: Date:
Data File: 30068111
QUANTERRA GC/HS TIC REPORT ( Part 1 )
Sample: S-MM5-5 1/3SA/100M INST. ID: F16
Analyst: DAT Date Analyzed: 08/31/98 23:58
Run Factor: 300.
Concentration
in Sample
# SCAN (UG/A) CAS #
1 444
11000.
<. -&8TF-79^\
4 557 9200. 1002-17-1
DECANE, 2,9-DIMETHYL- t> T
\/ 600 7600. 00-00-0
'ONKNOWN
7 618 15000.
8 633
20000.
7 MCTIIYL
9 655 12000. _—36653 SB 4.
^.1 IICKADCCAHOI
10 663 11000.
IIYOnOXYLAMINt, U ULLVL U VV-VM/Un-*,
3 473 13000. 71899-38-2
9-EICOSYNE
/
\
570 9500. 17301-23-4
UNDECANE, 2,6-DIHETHYL-
/
141
u
-------
00-00-0
UNKNOWN J '
1 701 12000. 00-00-0
UNKNOWN
5^715 8100. 00-00-0
-*->
U 739 19000. 3891-98-3
OOOECANE, 2,6,10-TRlMETHYL-
15 764 25000.
TETRADECANE
629-59-4
16 778 15000.
UNKNOWN
00-00-0
809 7500.
UNKNOWN
00-00-0
18 821 22000. 18344-37-1
HEPTADECANE, 2,6,10,U-TETRAMETHYL- ° ^
19 859 25000.
DODECANE, 3-METHYL-
17312-57-1
20 904 13000.
OX1RANE, HEXADECYL-
7390-81-0
21 948 27000.
22 988
TMDCCMr, , . ^
,
1411
-------
13 1036 28000. 54105-67-8
HEPTADECANE, 2,6-DIMETHYL-
1114 7500.
iTMfmYi fininr, n pFrY
25 1119 11000.
NONADECANE $*"
629-92-5
—a.
-------
DATA FILE: 30068111
OUANTERRA GC/MS TIC REPORT ( Part 2 )
CONCENTRATION = AREA(TIC)*CONC(IS)/AREA(IS)
#
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
FIT
934
971
906
958
941
827
923
923
923
959
874
887
904
956
950
837
949
967
953
880
958
923
973
960
958
PURITY
591
771
673
860
828
659
673
768
655
854
355
427
453
817
710
424
562
804
759
641
828
808
865
765
834
INT.
STD.
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
3
3
3
3
RT
4:56
5:04
5:15
6:11
6:20
6:40
6:52
7:02
7:17
7:22
7:33
7:47
7:57
8:13
8:29
8:39
8:59
9:07
9:33
10:03
10:32
10:59
11:31
12:23
12:26
RRT
0.535
0.549
0.570
0.671
0.687
0.723
0.745
0.763
0.789
0.799
0.818
0.845
0.861
0.890
0.920
0.937
0.975
0.989
1.035
1.089
1.142
0.908
0.952
1.024
1.028
AREA
320640.
201408.
358080.
259712.
268160.
216448.
413696.
569856.
345108.
298496.
289024.
350208.
228352.
537600.
719104.
431872.
212992.
613120.
706304.
359680.
754944.
519680.
1063170.
286976.
421376.
AS
HEIGHT
84352.
45952.
80768.
77696.
77952.
37376.
49810.
136550.
61049.
96768.
57344.
52736.
50432.
135936.
193280.
61440.
42240.
137984.
171008.
56576.
160256.
129024.
190464.
90112.
126720.
AMOUNT
ANALYZED
(UG/ML )
37.
23.
42.
30.
31.
25.
48.
67.
40.
35.
34.
41.
26.
63.
84.
50.
25.
72.
83.
42.
88.
45.
93.
25.
36.
754
715
163
580
575
486
711
099
635
147
032
236
888
301
672
852
079
193
165
351
892
516
117
135
906
LIB
NB
NB
NB
NB
NB
UK
NB
NB
NB
NB
UK
UK
UK
NB
NB
UK
UK
NB
NB
NB
NB
NB
NB
NB
NB
LIB #
15969.
10432.
39230.
15357.
19054.
1.
24994.
22534.
32420.
11607.
1.
1.
1.
25991.
22530.
1.
1.
42196.
19007.
37444.
37465.
25996.
37462.
15969.
37465.
Ul.
-------
ibrary Search Data: 30068111 # 444 Base m/z: 43
3/31/9823:58:00+ 4:56 CaIi: 30068111 # 3 RIC: 73216.
ample: S-MM5-5 1/3SA/100M INST. ID: F16
ands.: UG/HL *100ML "100X/100X *(NA/NA )/1/3SA NA M
nhanced (S 15B 2N OT)
2231 spectra in L1BRARYNB searched for maximum PURITY
797 matched at least 7 of the 16 largest peaks in the unknown
ank In. Name
15969 HYDROXYLAM1NE, 0-DECYL-
19523 1-DECANOL, 2-ETHYL-
5049 OXIRANE, (3,3-DIMETHYLBUTYL)-
19015 DECANE. 2,5,6-TRIMETHYL-
12050 1-OCTANOL, 2,7-DIMETHYL-
11565 ISOOCTANE, (ETHENYLOXY)-
14793 1-UNDECENE. 4-METHYL-
12074 1-HEPTANOL, 2-PROPYL-
12492 DECANE, 1-FLUORO-
ank
Formula
C10.H23.0.N
C12.H26.0
C8.H16.0
C13.H28
C10.H22.0
C10.H20.0
C12.H24
C10.H22.0
C10.H21.F
M.Wt B.Pk Purity Fit RFit
173
186
128
184
158
156
168
158
160
43
57
57
57
43
43
43
43
43
591
591
585
583
579
579
573
573
572
934
921
939
926
931
951
901
915
914
623
621
585
589
584
601
610
600
592
ank
Ret.Time
B.P.Int.
US.Par.1
US.Par.2
C.A.S
29812
21078
53907
62108
15250
37769
74630
10042
334
, #
79-1
•65-9
•77-0
•23-0
22-3
•62-3
•39-0
•59-8
56-5
1414
-------
MID LIBRARY SEARCH (LIBRARYNB)
08/31/98 23:58:00 + 4:56
SAMPLE: S-MM5-5 1/3SA/100M INST. ID: F16
CONDS.: UG/ML *100ML *100?Z/1007. */l/3SA HA M
ENHANCED
DATA: 30068111 * 444
CALI: 30068111 * 3
BASE M/Z: 43
RIC: 73216.
1000 1
SAMPLE
C10.H23.0
1000 i
M WT 173
B PK 43
RANK 1
# 15969 '
PUR 591
C12.H26.0
1000 ]
M WT 186
B PK 57
RANK 2
# 19523 :
PUR 591
C8.H16.0
1000 1
M WT 128
B PK 57
RANK 3
* 5049
PUR 585
M/Z
r
1
.N
r
r
r
h
1,11, , I, h i . I i. . 1. . . . . . . . 1. ....
HYDROXYLAMINE, 0-DECYL-
|,
ill .ll i • • --
1-DECANOL, 2-ETHYL-
|,
II 1 1..
OXIRANE, <3,3-DIMETHYLBUTYL>-
40
, ,1,
60 80 100 120 140 160
h-
CM
-------
Base m/z: 81
R1C: 40192.
brary Search Data: 30068111 # 456
i/31/98 23:58:00 + 5:04 Cati: 30068111 # 3
imple: S-MM5-5 1/3SA/100M INST. ID: F16
>nds.: UG/ML *100ML *100X/100% *(NA/NA )/1/3SA NA M
ihanced (S 15B 2N OT)
J231 spectra in LIBRARYNB searched for maximum PURITY
475 matched at least 7 of the 16 largest peaks in the unknown
ank In. Name
10432 NAPHTHALENE. DECAHYDRO-2-METHYL-
10376 BICYCLOC4.1.0JHEPTAN-3-ONE, 4,7.7-TRIMETHYL-, C1R-(1.ALPHA.,4.ALPHA*
10357 BICYCLO[4.1.0]HEPTAN-3-ONE, 4,7,7-TRIMETHYL-, [1R-(1.ALPHA.,4.BETA.*
10304 CYCLOHEXANONE, 2-METHYL-5-(1-METHYLETHENYL)-
10349 2H-INDEN-2-ONE, OCTAHYDRO-3A-METHYL-. CIS-
10358 CYCLOHEXANONE, 2-METHYL-5-(1-METHYLETHENYL)-, TRANS-
10352 CYCLOHEXANONE, 5-METHYL-2-(1-METHYLETHYLIDENE)-
17938 1,12-TRIDECADIENE
10355 CYCLOHEXANONE, 5-METHYL-2-(1-METHYLETHENYL)-, TRANS-
anlc
Formula
C11.H20
C10.H16.0
C10.H16.0
C10.H16.0
C10.H16.0
C10.H16.0
C10.H16.0
C13.H24
C10.H16.0
M.Wt B.Pk Purity Fit RFit
152
152
152
152
152
152
152
180
152
95
81
81
67
95
95
81
55
81
771
757
752
715
714
709
704
703
695
971
948
941
938
914
930
934
851
925
771
757
752
715
714
709
704
713
695
ank
Ret.Time B.P.Int.
US.Par.1 US.Par.2
C.A.S
2958
4176
4176
7764
13351
5948
15932
21964
29606
. #
•76-1
•04-9
•01-6
•50-3
•29-6
•04-9
•80-6
•48-7
•79-9
-------
MID LIBRARY SEARCH (LIBRARYNB)
08/31x98 23:58:00 + 5:04
SAMPLE: S-MM5-5 1/3SA/-100M INST. ID: F16
CONDS.: UG/ML *100ML * 100Z/1007Z *
DATA: 30068111 tt 456
CALI: 30068111 # 3
BASE M/Z: 81
RIC: 48192.
1000 •
SAMPLE
C11.H20
1000 i
M WT 152
B PK 95
RANK 1
# 10432 '
PUR 771
C16.H16.0
1000 I
M WT 152
B PK 81
RANK 2
« 10376 '
PUR 757
C19.H16.0
1000 I
M WT 152
B PK 81
RANK 3
* 10357
PUR 752
M/Z
r
r
M II
II
1
II i h
LJ_
O*1*^"
1 .. .11.
*^~
i
NAPHTHALENE, DECAHYDRO-2-METHYL-
II
1
1
BICYCLOC4. 1 . 03HEPTAN-3-ONE, 4,7,7-TRIMETHYL-, [ 1R-(1. ALPHA. > 4. ALPHA. , !
r
r
'
ll
1
,
ll II
1
BICYCLOC4.1.0]HEPTAN-3-ONE, 4,7,7-TRIMETHYL-, UR-<1. ALPHA. > 4. BETA. ,6!
ll .
1
40 60
1
80
ll II
100 120
1
140
-------
ibrary Search Data: 30068111 # 473
8/31/9823:58:00+ 5:16 Cali: 30068111 # 3
ample: S-MM5-5 1/3SA/100M INST. ID: F16
onds.: UG/ML *100ML *100%/100% *(NA/NA )/1/3SA NA M
nhanced (S 15B 2N 07}
Base m/z: 41
RIC: 70016.
2231 spectra in LIBRARYNB searched for maximum PURITY
459 matched at least 7 of the 16 largest peaks in the unknown
ank In. Name
39230 9-EICOSYNE
34800 (R)-(-)-(Z)-14-METHYL-8-HEXADECEN-1-OL
22482 2-TRIDECEN-1-OL, (E)-
25971 OXIRANE, DOOECYL-
36677 7-OCTADECYNE, 2-METHYL-
29222 (Z)6-PENTADECEN-1-OL
34010 3-OCTADECYNE
37449 OCTADECANAL
28267 3-HEXADECYNE
ank
Formula
C20.H38
C17.H34.0
C13.H26.0
C14.H28.0
C19.H36
C15.H30.0
C18.H34
C18.H36.0
C16.H30
M.Ut
278
254
198
212
264
226
250
268
222
B.Pk
81
55
57
41
81
67
67
43
67
Purity
673
667
658
658
649
645
638
637
637
Fit
906
857
850
906
906
869
926
828
934
RFit
690
676
664
658
666
664
644
680
642
ank
Ret.Time
B.P.Int.
US.Par.1
US.Par.2
C.A.S
71899
30689
74962
3234
35354
68797
61886
638
61886
, #
•38-2
•78-2
•98-4
•28-*
•38-2
•95-5
•64-4
•66-4
•62-2
-------
MID LIBRARY SEARCH (LIBRARYNB)
08/31/98 23:58:00 + 5:16
SAMPLE: S-MM5-5 1/3SA/100M INST. ID: F16
CONDS.: UG/ML *100ML *1007Z/100Z *
DATA: 30068111 # 473 BASE M/Z: 41
CALI: 30068111 tt 3 RIC: 70016.
1371
SAMPLE
r
hi
llll llll „
0-^^
n iJi, ,,l. . ,.!.. . •- i. . , , , j , , —
C20.H38
1371
M WT 278
B PK 81
RANK 1
* 39230
PUR 673
C17.H34.0
1371 •
M WT 254 :
B PK 55 .
RANK 2
ft 34800 '
PUR 667
C13.H26.0
1371 •
M WT 198
B PK 57
RANK 3
# 22482 '.
PUR 658
M/Z
9-EICOSYNE
I
ll .1. , ,
-
r
'
50
I, 1, ,
100 150 200 250
k-
>x>
I -
-------
jrary Search Data: 30068111 # 557 Base m/z: 43
'31/98 23:58:00 + 6:12 Cati: 30068111 # 3 RIC: 75008.
nple: S-MM5-5 1/3SA/100M INST. ID: F16
ids.: UG/ML *100ML *100X/100% *(NA/NA J/1/3SA MA M
lanced (S 15B 2N OT)
231 spectra in LIBRARYNB searched for maximum PURITY
731 matched at least 7 of the 16 largest peaks in the unknown
nk In. Name
15357 DECANE, 2,9-OIMETHYL-
8089 NONANE, 2-METHYL-
11607 UNDECANE
19013 DECANE, 2,5,9-TRIMETHYL-
15343 DOOECANE
8074 OCTANE, 2,7-DIMETHYL-
11602 OCTANE, 2,4,6-TRIMETHYL-
19006 DECANE, 6-ETHYL-2-METHYL-
19035 DODECANE, 2-METHYL-
nk
Formula
C12.H26
C10.H22
C11.H24
C13.H28
C12.H26
C10.H22
C11.H24
C13.H28
C13.H28
M.Wt
170
142
156
184
170
142
156
184
184
B.Pk
43
43
43
57
57
43
57
57
43
Purity
860
838
832
830
829
828
825
824
819
Fit
958
941
941
916
923
917
944
930
932
RFit
870
842
860
840
868
828
844
847
848
ink
Ret.Time
B.P.Int.
US.Par.1 US.Par.2
C.A.S. #
1002-17-1
871-83-0
1120-21-4
62108-22-9
112-40-3
1072-16-8
62016-37-9
62108-21-8
1560-97-0
-------
MID LIBRARY SEARCH CLIBRARYNB)
08x31/98 23:58:00 + 6:12
SAMPLE: S-MM5-5 1/3SA/108M INST.
CONDS.: UG/ML *100ML *1007>/100Z *
-------
brary Search Data: 30068111 # 570 Base m/z: 57
/31/98 23:58:00 + 6:20 Call: 30068111 # 3 RIC: 75520.
mple: S-MM5-5 1/3SA/100M INST. ID: F16
nds.: UG/ML *100ML *100%/100% *(NA/NA )/1/3SA NA M
hanced (S 15B 2N OT)
231 spectra in LIBRARYNB searched for maximum PURITY
718 matched at least 7 of the 16 largest peaks in the unknown
ink In. Name
19054 UNDECANE, 2,6-DIMETHYL-
19013 DECANE, 2,5,9-TRIMETHYL-
8104 OCTANE, 3,5-DIMETHYL-
19026 DECANE, 2,6,8-TRlMETHYL-
8077 HEPTANE, 2,3,5-TRIMETHYL-
19015 DECANE, 2,5,6-TRlMETHYl-
8092 HEPTANE, 2,3,6-TRIMETHYL-
19006 DECANE, 6-ETHYL-2-METHYL-
5154 HEXANE, 4-ETHYL-2-METHYL-
mk
Formula
C13.H28
C13.H28
C10.H22
C13.H28
C10.H22
C13.H28
C10.H22
C13.H28
C9.H20
M.wt B.Pk Purity Fit RFit
184
184
142
184
142
184
142
184
128
57
57
57
57
57
57
57
57
57
828
818
808
802
797
797
791
787
786
941
962
953
948
950
928
946
935
941
861
828
816
823
797
806
791
796
792
unk
Ret.Time
B.P.lnt.
US.Par.1
US.Par.2
C.A.S
17301
62108
15869
62108
20278
62108
4032
62108
3074
, #
23-4
22-9
93-9
26-3
•85-7
•23-0
93-3
•21-8
•75-7
1422
-------
MID LIBRARY SEARCH
DATA:
CALI:
INST. ID: F16
*/l/3SA NA M
30068111 # 570 BASE M/Z: 57
30068111 # 3 RIC: 75520.
1219 i
SAMPLE
C13.H28
1219 ]
M WT 184
B PK 57
RANK 1
tt 19054 '
PUR 828
C13.H28
1219 i
M WT 184
B PK 57
RANK 2
tt 19013
PUR 818
C10.H22
1219 i
M WT 142
B PK 57
RANK 3
ft 8104
PUR 808
M/Z
r
1,
r
,
r
1
L i1
r
1 1
4.
.11
UNDECANE, 2,6-DIMETHYL- frf \fr*^
J II
DEC
i
i| |i . |i |i • r . T i i - • -r-!— r—
;ANE, 2, 5,9-TRi METHYL-
i ii i . i ..
OCTANE, 3,5-DIMETHYL-
1
ll
Jl 1 1 1 1 .1 — .
40 60 80 100 120 140 160 180
-------
brary Search Data: 30068111 # 600 Base m/z: 41
/31/98 23:58:00 + 6:40 Cali: 30068111 # 3 RIC: 53760.
mple: S-MM5-5 1/3SA/100M INST. ID: F16
nds.: UG/ML *100ML *100%/100% *(NA/NA 5/1/3SA NA M
ihanced (S 15B 2N OT>
231 spectra in LIBRARYNB searched for maximum PURITY
340 matched at least 7 of the 16 largest peaks in the unknown
ink In. Name
39230 9-E1COSYNE
17938 1,12-TRIDECADIENE
21421 1.13-TETRADECADIENE
25960 CIS-9-TETRADECEN-1-OL
44549 ETHANOL. 2-<9-OCTADECENYLOXY)-, (Z)-
25963 CIS-11-TETRADECEN-1-OL
22481 CYCLODODECANEMETHANOL
29222 (Z)6-PENTADECEN-1-OL
29229 CYCLOPENTADECANOL-
ink
ank
Formula
C20.H38
C13.H24
C14.H26
C14.H28.0
C20.H40.02
C14.H28.0
C13.H26.0
C15.H30.0
C15.H30.0
Ret.Time
M.Wt
278
180
194
212
312
212
198
226
226
B.Pk
81
55
55
55
55
41
55
67
55
Purity
659
626
616
614
612
609
606
606
606
Fit
827
872
810
860
758
805
771
824
776
RFit
685
636
636
628
683
630
635
636
658
B.P.Int.
US.Par.1 US.Par.2
C.A.S
71899-
21964-
21964-
35153-
5353-
34010-
1892-
68797-
4727-
#
38-2
48-7
49-8
15-2
25-3
15-6
12-2
95-5
17-7
-------
MID LIBRARY SEARCH
BS/Sl/SS 23:58:00 + 6:40
SAMPLE: S-MM5-5 1/3SA/100M INST. ID: F16
CONDS.: UG/ML *100ML *1007./100Z *
DATA: 30068111 # 609
CALI: 30068111 # 3
BASE M/Z: 41
RIC: 53760.
1027
SAMPLE
111
C20.H38
1027
9-EICOSYNE
M WT 278
B PK 81
RANK 1
» 39230 '
PUR 659
L 1 .11, . .... , , - • —
C13.H24
1027
M WT 180
B PK 55
RANK 2
# 17938
PUR 626
,12-TRIDECADIENE
C14.H26
1027 i
M WT 194
B PK 55
RANK 3
* 21421
PUR 616
M/H
r
'
50
1, 13-TETRADECADIENE
1
|l l| -- , -
100 150 200 250
-------
ibrary Search Data: 30068111 # 618 Base tn/z: 41
8/31/98 23:58:00 + 6:52 Cali: 30068111 # 3 RIC: 54528.
ample: S-MM5-5 1/3SA/100H INST. ID: F16
onds.: UG/ML *100ML *100%/100% *(NA/NA )/1/3SA NA M
nhanced (S 15B 2N OT)
2231 spectra in LIBRARYNB searched for maximum PURITY
375 matched at least 7 of the 16 largest peaks in the unknown
ank In. Name
24994 1,1'-B1CYCLOHEXYL, 2-(1-METHYLETHYL)-, TRANS-
24993 1,T-BICYCLOHEXYL. 2-(1-METHYLETHYL)-, CIS-
33979 BOR1NIC ACID, DIETHYL-, 1-CYCLOOODECEM-1-YL ESTER
24996 1,1'-BICYCLOHEXYL, 2-PROPYL-, CIS-
24997 1,1'-B1CYCLOHEXYL, 2-PROPYL-, TRANS-
18965 11-DOOECENOL
22482 2-TRIDECEN-1-OL, (E)-
18944 OXIRANE, DECYL-
24990 MUUROLANE-B
ank
ank
Formula
C15.H28
C15.H28
C16.H31.0.B
C15.H28
C15.H28
C12.H24.0
C13.H26.0
C12.H24.0
C15.H28
Ret.Time
M.Wt B.Pk Purity Fit RFit
208
208
250
208
208
184
198
184
208
83
83
83
69
41
55
57
41
109
673
648
623
576
568
558
553
547
546
923
900
875
786
774
879
823
841
812
693
676
675
609
595
558
581
570
582
B.P.Int.
US.Par.1
US.Par.2
C.A.S. #
50991-16-7
50991-15-6
61142-73-2
54934-88-2
54934-89-3
35289-31-7
74962-98-4
2855-19-8
14;
-------
MID LIBRARY SEARCH (LIBRARYNB)
08/31x98 23:58:00 + 6:52
SAMPLE: S-MM5-5 1/3SA/100M
CONDS.: UG/ML *100ML
ENHANCED
DATA: 30068111
CALI: 30068111
INST. ID: F16
*/l/3SA NA M
# 618 BASE M/Z: 41
# 3 RIC: 54528.
1076 i
SAMPLE
C15.H28
1076 i
M NT 208
B PK 83
RANK 1
* 24994
PUR 673
C15.H28
1076 i
M WT 208
B PK 83
RANK 2
# 24993 '
PUR 648
C16.H31.0.E
1076 i
M NT 250
B PK 83
RANK 3
* 33979
PUR 623
M/Z
|(
I
ll ,
1 li
'
1.,
{*\/~^—
i ... V "^
Gv/^^^
1 , 1 ' -B I CYCLOHEXYL , 2- < 1 -METH YLETH YL > - , TRANS-
1
1,1
|
1,1'-BICYCLOHEXYL, 2--, CIS-
i.
,11
1
3 BORINIC ACID, D I ETHYL-, 1 -CYCLODODECEN- 1 -YL ESTER
ll,
hi
50 100
150 200 250
-------
Library Search Data: 30068111 # 633 Base m/z: 57
08/31/98 23:58:00 + 7:02 Cali: 30068111 # 3 RIC: 127872.
Sample: S-MM5-5 1/3SA/100M INST. ID: F16
Conds.: UG/ML *100ML "100X/100X *(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
781 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 22534 TRIDECANE, 7-METHYL-
2 H799 1-DECENE. 3,4-DIMETHYL-
3 37462 HEPTADECANE, 2.6-DIMETHYL-
4 19523 1-DECANOL, 2-ETHYL-
5 8539 1-PENTANOL, 4-METHYL-2-PROPYL-
6 14751 2-UNDECENE, 5-METHYL-
7 26408 2-ETHYL-1-DOOECANOL
8 14793 1-LWDECENE, 4-METHYL-
9 8071 NONANE, 3-METHYL-
Rank
1
2
3
4
5
6
7
8
9
Rank
1
2
3
4
5
6
7
8
9
Formula
C14.H30
C12.H24
C19.H40
C12.H26.0
C9.H20.0
C12.H24
C14.H30.0
C12.H24
C10.H22
Ret. Time
B.P.Int.
M.Ut
US. Par. 1
"-
198
168
268
186
144
168
214
168
142
B.Pk Purity Fit
57
57
57
57
57
57
57
43
57
US. Par. 2
--
768 923
763 949
754 922
749 928
746 981
746 958
734 906
728 936
728 949
C.A.S. #
26730-14-3
50871-03-9
54105-67-8
21078-65-9
54004-41-0
56851-34-4
74630-39-0
5911-04-6
RFit
774
767
787
764
746
746
740
728
734
-------
MID LIBRARY SEARCH
DATA: 30068111
CALI: 30068111
INST. ID: F16
* 6-D I METHYL-
50
100
150
200
250
-------
.ibrary Search Data: 30068111 # 655 Base m/z: 41
38/31/98 23:58:00 + 7:17 Cali: 30068111 # 3 RIC: 70912.
Sample: S-MM5-5 1/3SA/100M INST. ID: F16
:onds.: UG/ML *100ML *100%/100% *(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
i2231 spectra in LIBRARYNB searched for maximum PURITY
744 matched at least 7 of the 16 largest peaks in the unknown
?ank In. Name
1 32420 1-HEXADECANOL
2 28772 7-HEXADECENE. (Z)-
5 34410 3-OCTADECENE, -
i 21960 CYCLOTETRAOECANE
3 34411 5-OCTADECENE, (E)-
b 40233 NONADECANOL
? 28768 3-HEXADECENE, (Z>-
3 7515 2-NONENAL, (E)-
? 14780 CYCLCOODECANE
tank
I
3
5
+
>
i
T
3
)
Formula
C16.H34.0
C16.H32
C18.H36
C14.H28
C18.H36
C19.H40.0
C16.H32
C9.H16.0
C12.H24
H.Ut
242
224
252
196
252
284
224
140
168
B.Pk
55
55
69
55
55
43
55
41
55
Purity
655
654
652
652
652
650
650
649
649
Fit
923
911
891
911
908
881
917
927
933
RFit
667
675
674
671
673
682
673
649
662
tank
Ret.Time
B.P.Int.
US.Par.1
US.Par.2
C.A.S
36653
35507
7206
295
7206
52783
34303
18829
294
82-4
•09-6
•19-1
17-0
•21-5
•43-4
81-6
56-6
•62-2
1420
-------
MID LIBRARY SEARCH
08/31x98 23:58:00 + 7:17
SAMPLE: S-MM5-5 1/3SA/100M
CONDS.! UG/ML *100ML
ENHANCED
DATA:
CALI:
INST. ID: F16
*/l/3SA NA M
30068111
30068111
# 655 BASE M/Z: 41
# 3 RIC: 70912.
1000
SAMPLE
,
1,1,
C16.H34.0
1000
M WT 242
B PK 55
RANK 1
ft 32420
PUR 655
1-HEXADECANOL
ll
C16.H32
1000
M WT 224
B PK 55
RANK 2
ft 28772
PUR 654
C18.H36
1000
M WT 252
B PK 69
RANK 3
ft 34410
PUR 652
M/Z
7-HEXADECENE, -
lh I I
3-OCTADECENE, -
50
100
150
200
250
CO
-------
Library Search Data: 30068111 # 663 Base m/z: 57
08/31/9823:58:00+ 7:22 Cali: 30068111 # 3 RIC: 107264.
Sample: S-MM5-5 1/3SA/100M INST. ID: F16
Conds.: UG/ML "100ML *100%/100% *(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
560 matched at least 7 of the 16 largest peaks in the unknown
Rank in. Name
1 11607 UNDECANE
2 19013 DECANE, 2,5.9-TRIMETHYL-
3 19026 DECANE, 2,6.8-TRIMETHYL-
4 15357 DECANE, 2,9-DIMETHYL-
5 11602 OCTANE, 2,4.6-TRIMETHYL-
6 8104 OCTANE, 3,5-DIMETHYl-
7 8089 NONANE, 2-METHYL-
8 5159 NONANE
9 8074 OCTANE, 2,7-DIMETHYL-
Rank
1
2
3
4
5
6
7
8
9
Formula
C11.H24
C13.H28
C13.H28
C12.H26
C11.H24
C10.H22
C10.H22
C9.H20
C10.H22
M.Wt B.Pk Purity Fit RFit
156
184
184
170
156
142
142
128
142
43
57
57
43
57
57
43
43
43
854
815
813
811
801
798
797
795
794
959
914
911
932
933
902
913
914
901
859
829
839
841
822
826
827
834
807
Rank
1
2
3
4
5
6
7
8
9
Ret.Time
B.P.Int.
US.Par.1 US.Par.2
C.A.S.
1120-
62108-
62108-
1002-
62016-
15869-
871-
11V
1072-
21-4
22-9
26-:
17-1
37-9
93-9
83-0
84-2
16-8
14;
-------
MID LIBRARY SEARCH (LIBRARYNB)
08/31/98 23:58:80 + 7:22
SAMPLE: S-MM5-5 1/3SA/100M INST. ID: F16
CONDS.: UG/ML *100ML *100Z/100Z *
DATA: 30068111 # 663 BASE M/Z: 57
CALI: 30068111 # 3 RIC: 107264.
1496 •
SAMPLE
C11.H24
1496 i
M WT 156
B PK 43
RANK 1
# 11607 '
PUR 854
C13.H28
1496 i
M WT 184
B PK 57
RANK 2
tt 19013 '
PUR 815
C13.H28
1496 i
M WT 184
B PK 57
RANK 3
tt 19026
PUR 813
M/Z
p
I
r
1
p
1
r
1
..ll
V*~
UNDECANE
J.
11
DEC
il
ttNE, 2,5,9-TRIMETHYL-
DECANE , 2.6, 8-TR I METHYL-
ll
n I .1 • -
40 60 80 100 120 140 160 180
Co
-------
Library Search Data: 30068111 # 679 Base m/z: 57
08/31/98 23:58:00 + 7:33 Cali: 30068111 « 3 RIC: 62656.
Sample: S-MM5-5 1/3SA/100M INST. ID: F16
Conds.: UG/ML *100ML *100%/100% *(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
324 matched at least 6 of the 16 largest peaks in the unknown
Rank In. Name
1 5159 NONANE
2 37251 1-IODO-2-METHYLNONANE
3 40866 OCTADECANE, 1-CHLORO-
4 5151 HEPTANE, 3,4-DIMETHYL-
5 19826 OCTANETHIOIC ACID, S-ETHYL ESTER
6 30843 4,4,6-TRIMETHYL-6-PHENYLTETRAHYDRO-1,3-OXAZINE-2-THIONE
7 11607 UNDECANE
8 35931 HEXADECANE, 1-CHLORO-
9 5154 HEXANE, 4-ETHYL-2-METHYL-
Rank Formula
1
2
3
4
5
6
7
B
9
C9.H20
C10.H21.I
C18.H37.CL
C9.H20
C10.H20.0.S
C13.H17.0.N.S
C11.H24
C16.H33.CL
C9.H20
M.Ut
128
268
288
128
188
235
156
260
128
B.Pk
43
43
57
43
57
118
43
57
57
Purity
355
353
339
334
334
334
333
333
332
Fit
874
871
782
836
744
676
852
774
831
RFit
375
381
416
349
345
441
367
414
364
Rank
1
2
3
Ret.Time
B.P.Int.
US.Par.1
US.Par.2
C.A.S. #
111-84-2
3386-33-2
922-28-1
2432-84-0
1120-21-4
4860-03-1
3074-75-7
1424
-------
MID LIBRARY SEARCH
DATA: 30968111 # 679 BASE M/Z: 57
CALI: 30068111 ft 3 RIC: 62656.
1315 •
SAMPLE
C9.H20
1315 •
gWT 128
PK 43
RANK 1
* 5159
PUR 355
C10.H21.I
1315 i
B K *8
RANK 2
* 37251 '
PUR 353
C18.H37.Cl
1315 i
M WT 288
B PK 57
RANK 3
# 40866
PUR 339
r
r
ll „
m *. J_
_, , ^
NONANE
,11.
1 - I ODO-2-METHYLNONANE
T
I 1
1 .
OCTADECANE, 1-CHLORO-
r
1
1
!,l i 1. 1
M/Z
59
100
150
200
250
CO
CM
-------
.ibrary Search Data: 30068111 # 701 Base m/z: 41
18/31/9823:58:00+ 7:48 Cali: 30068111 # 3 RIC: 54272.
iample: S-MM5-5 1/3SA/100M INST. ID: F16
:onds.: UG/ML *100ML *100%/100% *(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
>2231 spectra in LIBRARYNB searched for maximum PURITY
976 matched at least 5 of the 16 largest peaks in the unknown
lank In.
Name
I 10423 3-UNDECYNE
! 14158 3-DOOECYNE
i 28273 8-HEXADECYNE
> 6996 1-ETHYNYL-1-CYCLOHEPTANOL
i 7028 1,3-HEXADIENE, 3-ETHYL-2.5-DIMETHYL-
> 28267 3-HEXADECYNE
' 10438 1,4-UNDECADIENE, (Z)-
i 10408 THUJONE
» 18371 5,7-DIMETHYLOCTAHYDROCOUMARIN
'.ank Formula
C11.H20
C12.H22
i C16.H30
C9.H14.0
C10.H18
C16.H30
C11.H20
i C10.H16.0
' C11.H18.02
ank Ret.Time B.P.Int. US.Par.1 US.Par.2
M.Wt
152
166
222
138
138
222
152
152
182
B.Pk
67
67
81
81
67
67
67
81
95
Purity
427
421
421
417
414
408
407
404
397
Fit
887
831
764
836
859
713
889
896
827
RFit
427
422
467
438
414
437
431
416
432
C.A.S. #
60212-30-8
6790-27-8
19781-86-3
2809-78-1
62338-07-2
61886-62-2
55976-14-2
546-80-5
-------
MID LIBRARY SEARCH
-------
Library Search Data: 30068111 # 715
08/31/98 23:58:00 + 7:57 Cali: 30068111 * 3
Sample: S-MM5-5 1/3SA/100M INST. ID: F16
Conds.: UG/ML *100ML *100%/100X "(NA/NA )/1/3SA MA M
Enhanced (S 158 2N OT)
Base m/z: 41
RIC: 58944.
62231 spectra in LIBRARYNB searched for maximum PURITY
309 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 32052 OXIRANE, TETRADECYL-
2 40193 CIS-9.10-EPOXYOCTADECAN-1-OL
3 31486 ACETAMIDE, N-METHYL-N-[4-[4-METHOXY-1-HEXAHYDROPYRIDYL]-2-BUTYNYL]-
4 21927 TRANS-2-TRIDECENAL
5 50599 PENTALENE, OCTAHYDRO-1-(2-OCTYLDECYL)-
6 46251 DODECANE, 1,2-DIBROMO-
7 56499 9-OCTADECENOIC ACID (Z)-, 2-(ACETYLOXY)-!-[(ACETYLOXY)METHYL]ETHYL *
3 37035 9-OCTADECENAL, -
? 18445 2-DODECENAL
Formula
C16.H32.0
C18.H36.02
C13.H22.02.N2
C13.H24.0
C26.H50
C12.H24.BR2
C25.H44.06
C18.H34.0
C12.H22.0
H.Wt
240
284
238
196
362
326
440
266
182
B.Pk
41
55
43
41
43
41
43
55
70
Purity
453
438
436
433
428
414
414
407
403
Fit
904
896
817
863
833
790
709
848
874
RFit
468
466
497
455
487
490
515
467
425
iank
Ret.Time B.P.Int.
US.Par.1
US.Par.2
C.A.S. #
7320-37-8
13980-12-6
55401-65-5
55334-42-4
55401-63-3
2423-10-1
4826-62-4
142
«2
tS
-------
MID LIBRARY SEARCH CLIBRARYNB)
08x31/98 23:58:00 + 7:57
SAMPLE: S-MM5-5 1/3SA/100M INST. ID: F16
CONDS.: UG/ML *100ML *100Z/100Z *
DATA: 30068111 #715
CALI: 30068111 * 3
BASE M/Z: 41
RIC: 58944.
1107 •
SAMPLE
C16.H32.0
1107 i
SWT 240
PK 41
RANK 1
# 32052 '
PUR 453
C18.H36.0:
1107 1
M WT 284
B PK 55
RANK 2
tt 40193 '
PUR 438
C13.H22.0:
1107
M WT 238
B PK 43
RANK 3
# 31486
PUR 436
M/Z
h
i
II llll 1 III 1 Mill 1 ... ...ll
OXIRANE, TETRADECYL- ' '
1 1
1 ill
1 11 III
1 C I S-9, 10-EPOXYOCTADECAN-l-OL ' ' ••••.-.
l.l
1
ll III III 1, . I .
2 ACETAM I DE , N-METHYL-N- C 4- C 4-METHOXY- 1 -HEXAHYDROPYR I DYL ] -2-BUTYNYL ] -
ll .1
II ll
40 60 80 100 120 140 160 180 200 220 24(
CO
CD
-------
.ibrary Search Data: 30068111 # 739 Base m/z: 57
38/31/98 23:58:00 + 8:13 Cali: 30068111 # 3 RIC: 131072.
Sample: S-MM5-5 1/3SA/100M INST. ID: F16
:onds.: UG/ML *100ML *100X/100% *(NA/NA )/1/3SA NA M
Enhanced (S 158 2N OT)
S2231 spectra in LIBRARYNB searched for maximum PURITY
748 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 25991 DOOECANE, 2,6,10-TRIMETHYL-
2 37462 HEPTADECANE, 2,6-DIMETHYL-
3 42196 HEPTADECANE, 2,6,10,14-TETRAMETHYL-
i 22535 DOOECANE, 4,6-DIMETHYL-
5 26001 DODECANE, 2,7,10-TRIMETHYL-
!> 25997 PENTADECANE
7 19026 DECANE, 2,6,8-TRIMETHYL-
3 25994 DOOECANE, 2,6.11-TRIMETHYL-
? 18998 UNDECANE, 3,7-DlMETHYL-
?ank
1
j
5
»
>
i
7
5
?
Formula
C15.H32
C19.H40
C21.H44
C14.H30
C15.H32
C15.H32
C13.H28
C15.H32
C13.H28
M.Ut
212
268
296
198
212
212
184
212
184
B.Pk
57
57
57
57
57
57
57
57
43
Purity
817
816
815
803
794
789
787
782
781
Fit
956
931
927
940
960
918
919
944
919
RFit
834
852
858
815
815
825
795
808
790
iank
Ret.Time B.P.Int.
US.Par.1
US.Par.2
C.A.S.
3891-
54105-
18344-
61141-
74645-
629-
62108-
31295-
17301-
98-3
67-8
37-1
72-8
98-0
62-9
26-3
56-4
29-0
144G
-------
MID LIBRARY SEARCH
08/31/98 23:58:00 + 8:13
SAMPLE: S-MM5-5 1/3SA/100M
CONDS.: UG/ML *100ML
ENHANCED
DATA: 30068111
CALI: 30068111
INST. ID: F16
*
-------
.ibrary Search Data: 30068111 # 764 Base m/z: 43
>8/31/98 23:58:00 + 8:30 Cali: 30068111 # 3 RIC: 187392.
Jample: S-MM5-5 1/3SA/100M INST. ID: F16
:onds.: UG/ML *100ML *100%/100% *(NA/NA )/1/3SA NA M
•nhanced (S 158 2N OT)
>2231 spectra in LIBRARYNB searched for maximum PURITY
634 matched at least 7 of the 16 largest peaks in the unknown
iank In. Name
I 22530 TETRAOECANE
> 19006 DECANE, 6-ETHYL-2-METHYL-
! 11612 NONANE, 2,5-DIMETHYL-
. 11607 UNDECANE
i 19007 DOOECANE, 3-METHYL-
> 15358 UNDECANE, 3-METHYL-
' 22532 TRIDECANE, 2-METHYL-
1 42196 HEPTADECANE, 2,6,10,14-TETRAMETHYL-
» 39681 1-IOOOUNDECANE
'ank
Formula
C14.H30
C13.H28
C11.H24
C11.H24
C13.H28
C12.H26
C14.H30
C21.H44
C11.H23.I
M.Wt
198
184
156
156
184
170
198
296
282
B.Pk
43
57
57
43
57
57
57
57
57
Purity
710
708
687
684
684
682
676
676
675
Fit
950
954
865
970
896
911
878
921
864
RFit
715
708
687
684
686
682
679
696
682
ank
Ret.Time B.P.Int.
US.Par.1
US.Par.2
C.A.S
629
62108
17302
1120
17312
1002
1560
18344
4282
, n
•59-4
•21-8
•27-1
•21-4
57-1
43-3
96-9
37-1
•44-4
L-C
-------
MID LIBRARY SEARCH CLIBRARYNB)
88/31/98 23:58:00 + 8:30
SAMPLE: S-MM5-5 1/3SA/100M INST. ID: F16
CONDS.: UG/ML *100ML * 100J2/100Z *
DATA:
CALI:
30068111
30068111
# 764
BASE M/Z: 43
RIC: 187392.
1281
SAMPLE
C14.H30
1281
M WT 198
B PK 43
RANK 1
# 22530
PUR 710
C13.H28
1281
M NT 184
B PK 57
RANK 2
# 19006
PUR 708
C11.H24
1281
M WT 156
B PK 57
RANK 3
tt 11612
PUR 687
M/Z
TETRADECANE
ll
DECANE, 6-ETHYL-2-METHYL-
NONANE, 2,5-DIMETHYL-
r
1 1,
il
, .11 1 ll
40
60
80
100
120
140
160
180
208
-------
Library Search Data: 30068111 * 778 Base m/z: 41
08/31/98 23:58:00 + 8:39 Cali: 30068111 # 3 RIC: 59520.
Sample: S-MM5-5 1/3SA/100M INST. ID: F16
Conds.: UG/ML *100ML *100%/100X *(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
618 matched at least 6 of the 16 largest peaks in the unknown
Rank In. Name
1 31174 1-HEPTADECYNE
2 40193 CIS-9.10-EPOXYOCTADECAN-1-OL
3 56499 9-OCTADECENOIC ACID (Z)-, 2-CACETYLOXY)-1-[(ACETYLOXY)METHYL]ETHYL *
4 37444 OXIRANE, HEXADECYL-
5 34009 1-OCTADECYNE
6 31486 ACETAMIDE, N-METHYL-N-[4-[4-METHOXY-1-HEXAHYDROPYRIDYL1-2-BUTYNYL]-
7 22481 CYCLODOOECANEMETHANOL
8 28275 1-HEXADECYNE
9 25010 1-PENTADECYNE
M.Ut B.Pk Purity Fit RFit
Rank
1
2
3
4
5
6
7
8
9
Formula
C17.H32
C18.H36.02
C25.H44.06
C18.H36.0
C18.H34
C13.H22.02.N2
C13.H26.0
C16.H30
C15.H28
236
284
440
268
250
238
198
222
208
81
55
43
57
81
43
55
81
81
424
416
414
412
410
405
404
404
402
837
839
744
783
837
798
808
830
825
439
476
520
479
435
472
463
420
418
Rank
1
2
3
4
5
6
7
8
9
Ret.Time
B.P.Int.
US.Par.1
US.Par.2
C.A.S. #
26186-00-5
13980-12-6
55401-63-3
7390-81-0
629-89-0
1892-12-2
629-74-3
765-13-9
-------
MID LIBRARY SEARCH
88/31x98 23:58:00 + 8:39
SAMPLE: S-MM5-5 1/3SA/100M INST. ID: F16
CONDS.: UG/ML *100ML *100Z/100Z *
DATA: 30068111 # 778 BASE M/Z: 41
CALI: 30068111 # 3 RIC: 59520.
2182
SAMPLE
1
„ ll, , 1
, ill
1 1 J*/*~
\\N*»
' .'• I'l . I-'.' .-". '. '.'•"• 1
C17.H32
2182
M WT 236
B PK 81
RANK 1
# 31174
PUR 424
1-HEPTADECYNE
ILL
ll
C18.H36.02
2182
M WT 284
B PK 55
RANK 2
« 40193
PUR 416
CIS-9,10-EPOXYOCTADECAN-l-OL
In
C25.H44.06
2182
M WT 440
B PK 43
RANK 3
* 56499
PUR 414
M/Z
9-OCTADECENOIC ACID (Z)-, 2-METHYL]ETHYL ES!
JiL
hi
100
150
200
259
O!
-------
Library Search Data: 30068111 # 809 Base m/z: 41
08/31/9823:58:00+ 9:00 Cali: 30068111 # 3 RIC: 56000.
Sample: S-MM5-5 1/3SA/100M INST. ID: F16
Conds.: UG/ML *100ML *100%/100% *(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
345 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 40193 CIS-9,10-EPOXYOCTADECAN-1-OL
2 25971 OX1RANE, DCOECYL-
3 37444 OXIRANE, HEXADECYL-
4 37449 OCTADECANAL
5 22482 2-TRIDECEN-1-OL. (E)-
6 39230 9-EICOSYNE
7 31486 ACETAMIDE, N-METHYL-N-[4-[4-METHOXY-1-HEXAHYDROPYRIDYL]-2-BUTYNYL]•
8 11590 6-OCTEN-1-OL, 3,7-DlMETHYL-
9 44549 ETHANOL, 2-(9-OCTADECENYLOXY)-, (2)-
Rank
1
2
3
4
5
6
7
8
9
Formula
C18.H36.02
C14.H28.0
C18.H36.0
C18.H36.0
C13.H26.0
C20.H38
C13.H22.02.N2
C10.H20.0
C20.H40.02
Rank
1
2
3
4
5
6
7
8
9
H.Wt
284
212
268
268
198
278
238
156
312
B.Pk
55
41
57
43
57
81
43
41
55
Purity
562
548
530
526
524
513
509
507
503
Fit
949
898
861
850
891
856
865
897
806
RFit
571
560
573
565
537
533
542
515
562
Ret.Time B.P.Int.
US.Par.1
US.Par.2
C.A.S. #
13980-12-6
3234-28-4
7390-81-0
638-66-4
74962-98-4
71899-38-2
106-22-9
5353-25-3
1416
-------
MID LIBRARY SEARCH (LIBRARYHB)
08/31/98 23:58:00 + 9:00
SAMPLE: S-MM5-5 1/3SA/100M INST. ID: F16
CONDS.: UG/tIL *100ML *100Z/100Z *
DATA: 30068111 # 809
CALI: 30068111 * 3
BASE M/Z: 41
RIC: 56000.
1482 i
SAMPLE
r
,
,
i. il III ,il., .1,1. Li. . i ..I.. .. ,1.1 , . i
C 1 8 . H36 . 02 C I S-9 > 1 0-EPOX YOCTADECAN- 1 -OL
1482
gWT 284
PK 55
RANK 1
* 40193
PUR 562
r
,i
Ji
IN in
Ilil III in .. . .
C14.H28.0 OXIRANE, DODECYL-
1482 i
M WT 212
B PK 41
RANK 2
# 25971
PUR 548
r
.
1 1
II 111 III II
C18.H36.0 OXIRANE, HEXADECYL-
1482 T
M WT 268
B PK 57
RANK 3
* 37444 :
PUR 530
r
1 1
i II ..i
-Hi-
M/Z
50
100
150
200
250
-------
Library Search Data: 30068111 # 821 Base m/z: 43
08/31/9823:58:00+ 9:08 Cali: 30068111 it 3 RIC: 133632.
Sample: S-MM5-5 1/3SA/100M INST. ID: F16
Conds.: UG/ML *100ML *100%/100% *(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
855 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 42196 HEPTADECANE, 2,6,10,14-TETRAMETHYL-
2 37462 HEPTADECANE, 2,6-DIMETHYL-
3 19016 UNDECANE, 4,7-DIMETHYL-
4 18987 UNDECANE, 2,8-DlMETHYL-
5 19023 DECANE, 2,6,7-TRIMETHYL-
6 8104 OCTANE, 3.5-DIMETHYL-
7 19054 UNDECANE, 2,6-DIMETHYL-
3 15353 2,6-DIMETHYLDECANE
? 19004 UNDECANE, 4,6-DIMETHYL-
*anl
1
5
5
*
;
3
7
3
?
c Formula
C21.H44
C19.H40
C13.H28
C13.H28
C13.H28
C10.H22
C13.H28
C12.H26
C13.H28
M.Wt
296
268
184
184
184
142
184
170
184
B.Pk
57
57
43
43
57
57
57
43
57
Purity
804
790
756
756
755
754
754
754
750
Fit
967
949
940
955
951
966
909
916
960
RFit
822
811
762
760
755
754
763
774
750
tank
Ret.Time B.P.Int.
US.Par.1
US.Par.2
C.A.S,
18344-
54105-
17301-
17301-
62108-
15869-
17301-
13150-
17312-
#
37-1
67-8
32-5
25-6
25-2
93-9
23-4
81-7
82-2
1418
-------
MID LIBRARY SEARCH
08/31/98 23:58:08 + 9:08
SAMPLE: S-MM5-5 1/3SA/100M INST. ID: F16
CONDS.: UG/ML *100ML *100^/100?! */l/3SA NA M
ENHANCED
-------
Library Search Data: 30068111 # 859 Base m/z: 57
08/31/98 23:58:00 + 9:33 Cali: 30068111 # 3 RIC: 151040.
Sample: S-MM5-5 1/3SA/100M INST. ID: F16
Conds.: UG/ML *100ML *100X/100% *(HA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
663 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 19007 DOOECANE, 3-METHYL-
2 18990 UNDECANE, 2,9-DlMETHYL-
3 15352 UNDECANE, 2-HETHYL-
4 39681 1-IOOOUNDECANE
5 22536 TRIDECANE. 3-METHYL-
6 46040 TETRADECANE, 1-1000-
7 37252 DECANE, 1-1000-
8 19006 DECANE, 6-ETHYL-2-METHYL-
9 19032 UNDECANE, 5-ETHYL-
M.Wt B.Pk Purity Fit RFit
Rank
1
2
3
4
5
6
7
8
9
Formula
C13
C13
C12
C11
C14
C14
C10
C13
C13
.H28
.H28
.H26
.H23.I
.H30
.H29.I
.H21.I
.H28
.H28
184
184
170
282
198
324
268
184
184
57
57
43
57
57
57
57
57
57
759
753
750
747
743
742
741
737
736
953
956
925
966
940
983
971
949
963
766
753
760
755
748
746
747
745
736
Rank Ret.Time B.P.Int. US.Par.1 US.Par.2 C.A.S. #
1 17312-57-1
2 17301-26-7
3 7045-71-8
4 4282-44-4
5 6418-41-3
6 19218-94-1
7 2050-77-3
8 62108-21-8
9 17453-94-0
145G
-------
MID LIBRARY SEARCH (LIBRARYNB)
08/31/98 23:58:00 + 9:33
SAMPLE: S-MM5-5 1/3SA/100M INST. ID: F16
COHDS.: UG/ML *100ML *100Z/1007. */l/3SA NA M
ENHANCED
DATA: 30068111 # 859 BASE M/Z: 57
CALI: 30068111 # 3 RIC: 151040.
1252
SAMPLE
C13.H28
1252 i
M NT 184
B PK 57
RANK 1
# 19007 '
PUR 759
C13.H28
1252 i
M NT 184
B PK 57
RANK 2
tt 18990
PUR 753
C12.H26
1252 i
M WT 170
B PK 43
RANK 3
* 15352 '
PUR 750
M/Z
r
1
. ..Ii
r
1
r
r
1
II
|
ll
- l| ... . , , |. ..,.., .......
DODECANE, 3-METHYL- £>y- ^y>y^-eV
,, . .1 . .. .(
UNDECANE , 2 , 9-D I METHYL-
i| ,1 , - . -1 • , ••••-,
UNDECANE, 2-METHYL-
ii t i_i . ii-
50 100 150 200
cn
-------
-ibrary Search Data: 30068111 # 904 Base m/z: 41
38/31/96 23:58:00 + 10:03 Cati: 30068111 # 3 R1C: 68864.
Sample: S-MM5-5 1/3SA/100M 1NST. ID: F16
:onds.: UG/ML «100ML *100%/100X "(NA/NA )/1/3SA NA H
Enhanced (S 15B 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
551 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 37444 OX1RANE, HEXADECYL-
2 37449 OCTADECANAL
3 40233 NONADECANOL
4 42521 1-EICOSANOL
5 42180 OCTADECANE, I-(ETHENYLOXY)-
6 40193 CIS-9.10-EPOXYOCTADECAN-1-OL
760775 HEXADECANE. 1,1-BIS(OOOECYLOXY)-
B 48775 OCTADECANAL, 2-BROMO-
9 31486 ACETAHIDE, N-METHYL-N-[4-[4-METHOXY-1-HEXAHYDROPYRIDYL]-2-BUTYNYL] •
Rank Formula M.Wt B.Pk Purity Fit RFit
1 C18.H36.0 268 57 641 880 675
I C18.H36.0 268 43 626 892 657
5 C19.H40.0 284 43 599 945 623
4 C20.H42.0 298 43 595 941 623
5 C20.H40.0 296 43 587 942 610
5 C18.H36.02 284 55 580 898 607
7 C40.H82.02 594 43 575 900 612
B C18.H35.0.BR 346 43 575 821 663
? C13.H22.02.N2 238 43 571 865 633
Rank Ret.Time B.P.Int. US.Par.1 US.Par.2 C.A.S. #
1 7390-81-0
2 638-66-4
5 52783-43-4
<• 629-96-9
5 930-02-9
6 13980-12-6
7 56554-64-4
B 56599-95-2
9 - -
-------
1023
SAMPLE
C18.H36.0
1023 •
268
57
RANK 1
* 37444
PUR 641 1
M WT
B PK
MID LIBRARY SEARCH CLIBRARYNB)
08/31/98 23s58s00 + 10:03
SAMPLE: S-MM5-5 1/3SA/100M INST. ID: F16
CONDS.: UG/ML *100ML *100Z/100J; *
-------
Library Search Data: 30068111 # 948 Base m/z: 57
08/31/9823:58:00+10:33 Cali: 30068111 # 3 R1C: 154880.
Sample: S-MM5-5 1/3SA/100M INST. ID: F16
Conds.: UG/ML *100ML *100X/100% *(NA/NA )/1/3SA NA M
Enhanced (S 158 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
338 matched at least 8 of the 16 largest peaks in the unknown
Rank In. Name
1 37465 NONADECANE
2 15969 HYDROXYLAMINE, 0-DECYL-
3 37462 HEPTADECANE, 2,6-DIMETHYL-
4 42196 HEPTADECANE, 2,6,10,14-TETRAMETHYL-
5 25997 PENTADECANE
6 19016 UNDECANE, 4,7-DlMETHYL-
7 19523 1-DECANOL, 2-ETHYL-
8 46161 TRICOSANE
9 15353 2.6-DIMETHYLDECANE
Rank
1
2
3
c.
5
5
7
3
?
Formula
C19.H40
C10.H23.0.N
C19.H40
C21.H44
C15.H32
C13.H28
C12.H26.0
C23.H48
C12.H26
?ank Ret.Time B.P.Int.
1
US.Par.1
M.Ut
268
173
268
296
212
184
186
324
170
B.Pk Purity Fit
57
43
57
57
57
43
57
43
43
US. Par. 2
828 958
809 967
809 935
799 941
793 952
786 958
783 933
778 898
775 922
C.A.S. #
629-92-5
29812-79-1
54105-67-8
18344-37-1
629-62-9
17301-32-5
21078-65-9
638-67-5
13150-81-7
RFit
848
811
842
824
817
787
796
845
784
1434
-------
MID LIBRARY SEARCH
88/31/98 23:58:80 + 10:33
SAMPLE: S-MM5-5 1/3SA/100M
CONDS.: UG/ML *100ML
ENHANCED
DATA: 30068111
CALI: 30068111
INST. ID: F16
*
-------
Library Search Data: 30068111 # 988 Base m/z: 57
08/31/98 23:58:00 + 10:59 Call: 30068111 # 3 RIC: 118144.
Sample: S-MM5-5 1/3SA/100M INST. ID: F16
Conds.: UG/ML *100ML *100%/100% *(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
446 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 25996 TRIDECANE, 4,8-DIMETHYL-
2 22530 TETRADECANE
3 19054 UNDECANE, 2,6-DIMETHYL-
4 25997 PENTADECANE
5 42196 HEPTADECANE, 2,6,10,14-TETRAMETHYL-
6 32059 HEPTADECANE
7 37462 HEPTADECANE, 2,6-DIMETHYL-
8 29263 HEXADECANE
9 22527 DOOECANE, 2.5-DIMETHYL-
Rank
1
2
3
4
5
6
7
8
9
Rank
1
2
3
4
5
6
7
8
9
Formula
C15.H32
C14.H30
C13.H28
C15.H32
C21.H44
C17.H36
C19.H40
C16.H34
C14.H30
Ret. Time B.P.Int
M.Ut B
212
198
184
212
296
240
268
226
198
US. Par. 1 US
.Pk Purity Fit
57
43
57
57
57
57
57
57
57
.Par. 2
808 923
805 927
804 919
803 932
802 920
796 908
795 914
786 898
782 913
C.A.S. #
55030-62-1
629-59-4
17301-23-4
629-62-9
18344-37-1
629-78-7
54105-67-8
544-76-3
56292-65-0
RFit
835
828
833
829
838
829
834
846
800
1456
-------
MID LIBRARY SEARCH CLIBRARYNB)
08/31/98 23:58:00 + 10:59
SAMPLE: S-MM5-5 1/3SA/100M INST. ID: F16
CONDS.: UG/ML *100ML *100Z/100?. */l/3SA NA M
ENHANCED
DATA:
CALI:
30068111
30068111
# 988
BASE M/Z: 57
RIC: 118144.
1024
SAMPLE
i I
TRIDECANE, 4,8-DIMETHYL-
CIS. H32
1024
M WT 212
B PK 57
RANK 1
* 25996
PUR 808
C14.H30
1024
M WT 198
B PK 43
RANK 2
# 22530
PUR 805
C13.H28
1024
M WT 184
B PK 57
RANK 3
tt 19054
PUR 804
M/Z
il
TETRADECANE
II
UNDECANE, 2,6-DIMETHYL-
50
100
150
200
250
-------
.ibrary Search Data: 30068111 #1036 Base m/z: 57
38/31/98 23:58:00 + 11:31 Call: 30068111 # 3 RIC: 180992.
sample: S-MM5-5 1/3SA/100H 1NST. ID: F16
:onds.: UG/ML *100ML *100X/100% *(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
52231 spectra in LIBRARYNB searched for maximum PURITY
840 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 37462 HEPTADECANE. 2,6-DIMETHYl-
2 42196 HEPTADECANE, 2,6,10,14-TETRAMETHYL-
3 37465 NONADECANE
4 26001 DODECANE, 2,7,10-TRIMETHYL-
5 25991 DOOECANE, 2,6,10-TRIMETHYl-
6 22535 DOOECANE, 4,6-DIMETHYL-
7 37466 PENTADECANE, 2,6,10,14-TETRAMETHYL-
3 25994 DODECANE, 2,6,11-TRIMETHYL-
9 42192 HEPTADECANE, 2,6,10,15-TETRAMETHYL-
Rank
1
2
5
(,
5
i>
7
3
?
Formula
C19.H40
C21.H44
C19.H40
C15.H32
C15.H32
C14.H30
C19.H40
C15.H32
C21.H44
M.Wt
268
296
268
212
212
198
268
212
296
B.Pk
57
57
57
57
57
57
71
57
57
Purity
865
829
822
811
809
808
805
791
788
Fit
973
955
943
967
971
963
944
944
932
RFit
873
841
833
815
811
809
820
799
820
Rank
1
2
5
i
5
i
7
a
9
Ret.Time B.P.Int.
US.Par.1
US.Par.2
C.A.S
54105
18344
629
74645
3891
61141
1921
31295
54833
. #
•67-8
•37-1
•92-5
•98-0
•98-3
•72-8
•70-6
•56-4
•48-6
1458
-------
MID LIBRARY SEARCH CLIBRARYNB)
08/31/98 23:58:00 + 11:31
SAMPLE: S-MM5-5 1/3SA/180M INST. ID: F16
CONDS.: UG/ML *100ML *100Z/1007Z */l/-3SA HA M
ENHANCED
DATA: 38068111 #1036
CALI: 30068111 # 3
BASE M/Z: 57
RIC: 180992.
1160 •
SAMPLE
C19.H40
1160 •
M WT 268
B PK 57
RANK 1
# 37462 '
PUR 865
C21.H44
1160 I
M WT 296
B PK 57
RANK 2
* 42196
PUR 829
C19.H49
1160 i
M WT 268
B PK 57
RANK 3
* 37465 '
PUR 822
M/Z
,1
,
1
• ii - -i 1- -ii. ..1. .. ...... .
HEPTADECANE, 2,6-DIMETHYL- , ,,/V^O^
n 1|
'1 Lj •'! , u . i** ^. „ ^. ^ .
HEPTADECANE , 2,6,18,1 4-TETRAMETHYL-
II
1
1 .1 ll .. jl -, . ... ... J-- ,. .....
NONADECANE
II
1
hi i.l ... .. ........
50 100 150 200 250
tt*
en
en
-------
Library Search Data: 30068111 #1114 Base m/z: 57
08/31/98 23:58:00 + 12:23 Cali: 30068111 # 3 RIC: 76160.
Sample: S-MM5-5 1/3SA/100M 1NST. ID: F16
Conds.: UG/ML *100ML *100*/100% *(NA/NA )/1/3SA HA M
Enhanced (S 15B 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
317 matched at least 8 of the 16 largest peaks in the unknown
Rank In. Name
1 15969 HYDROXYLAMINE, 0-DECYL-
2 19523 1-DECANOL, 2-ETHYL-
3 37465 NONADECANE
\ 12074 1-HEPTANOL, 2-PROPYL-
5 19015 DECANE, 2,5,6-TRlMETHYL-
<> 19016 UNDECANE, 4,7-DIMETHYL-
7 42196 HEPTADECANE, 2,6,10, 14-TETRAMETHYL-
3 8104 OCTANE, 3,5-DIMETHYL-
19520 1-OCTANOL, 2-BUTYL-
iank
I
>
5
»
»
)
'
I
i
Formula
C10.H23.0.N
C12.H26.0
C19.H40
C10.H22.0
C13.H28
C13.H28
C21.H44
C10.H22
C12.H26.0
H.Wt B.Pk Purity Fit RFit
173
186
268
158
184
184
296
142
186
43
57
57
43
57
43
57
57
57
765
763
745
733
713
711
711
710
710
960
947
928
953
929
937
911
942
890
773
763
780
733
713
724
760
717
723
ank
Ret.Time
B.P.Int.
US.Par.1 US.Par.2
C.A.S. #
29812-79-1
21078-65-9
629-92-5
10042-59-8
62108-23-0
17301-32-5
18344-37-1
15869-93-9
3913-02-8
14BG
-------
MID LIBRARY SEARCH (LIBRARYNB)
08x31 'SB 23:58:80 + 12:23
SAMPLE: S-MM5-5 1/3SA/109M INST.
CONDS.: UG/ML *100ML *100Z/100?Z *
ID:
DATA:
CALI:
F16
NA M
30068111 #1114
30068111 # 3
BASE M/2: 57
RIC: 76160.
1074 i
SAMPLE
C10.H23.0
1074 i
SWT 173
PK 43
RANK 1
# 15969
PUR 765
C12.H26.0
1074 i
M WT 186
B PK 57
RANK 2
* 19523
PUR 763
C19.H40
1074 -I
M WT 268
B PK 57
RANK 3
# 37465 "
PUR 745
M/Z
r
I
.N
r
r
r
, .v-
HYDROXYLAMINE, 0-DECYL-
J_. — r>, 4
50
ll i
ill ill i . .i .. - _,.-..
1-DECANOL, 2-ETHYL-
|l li| ii. ..,.., ^ ,
NONADECANE
100 150 200 250
-------
Library Search Data: 30068111 #1119 Base m/z: 57
08/31/9823:58:00+12:27 Cali: 30068111 # 3 RIC: 107648.
Sample: S-MM5-5 1/3SA/100M 1NST. 10: M6
Conds.: UG/ML *100ML *100X/100X *
-------
1186
SAMPLE
MID LIBRARY SEARCH (LIBRARYNB)
08/31/98 23:58:00 + 12:27
SAMPLE: S-MM5-5 1/3SA/100M INST. ID: F16
CONDS.: UG/ML *100ML *100Z/100Z */l/3SA NA M
ENHANCED
DATA: 38068111 #1119 BASE M/Z: 57
CALI: 30068111 # 3 RIC: 107648.
i ii. ii.i.
gffi
C19.H40
1186
268
57
RANK 1
* 37465
PUR 834
C19.H48
1186
II WT 268
B PK 57
RANK 2
» 37462
PUR 824
C21.H44
1186
M WT 296
B PK 57
RANK 3
# 42196
PUR 808
M/Z
NONADECANE
II
HEPTADECANE, 2,6-DIMETHYL-
HEPTADECANE, 2,6,18,14-TETRAMETHYL-
50
100
150
200
250
-------
TIC SELECTION REPORT
DATA FILE: 30068111
THE FOLLOWING PEAKS WERE REJECTED BECAUSE
AT LEAST 40 X OF THEIR SIZE WAS ACCOUNTED FOR BY
TARGET COMPOUNDS ELUTING WITHIN 4 SCANS OF THE
PEAK TOP.
SCAN SIZE AMOUNT
340
531
830
1088
1553
1783
249568.
398976.
339712.
456704.
344352 .
292571 .
29.386
46.978
40.000
40.000
40.000
40.000
TOTAL NUMBER OF UNIDENTIFIED PEAKS WITH SIZE
GREATER THAN 10 % OF THE CLOSEST INTERNAL STANDARD
THAT DOES NOT HAVE INTERFERENCES = 97
INTERNAL STANDARDS THAT HAVE RIC SIZE LESS THAN
50 % OR GREATER THAN 200 % OF THE ESTIMATED RIC SIZE
ARE CONSIDERED TO HAVE INTERFERENCES AND WILL NOT BE USED
FOR QUANT I TAT I ON.
PERCENT OF
ESTIMATED
# INTERNAL STANDARD RIC SIZE RIC SIZE SCAN
1 CI40 NAPHTHALENE-OS
2 CI50 ACENAPHTHENE-010
3 CI60 PHENANTHRENE-D10
4 CI70 CHRYSENE-D12
5 CITS PERYLENE-D12
398976.
339712.
456704.
344352.
292571 .
229 *
152
181
157
147
531
830
1088
1553
1783
* INDICATES INTERFERENCE
SIZE = AREA
-------
initial Ctttibration
1465
-------
QUANTERRA GC/MS
SEMIVOLATILE HSL CALIBRATION CHECK
TIAL CALIBRATION: 10 UG/ML HSL STD ST16980827A
TIAL CALIBRATION: 20 UG/ML HSL STO ST16980827B
TIAL CALIBRATION: 50 UG/ML HSL STD ST16980827C
TIAL CALIBRATION: 80 UG/ML HSL STD ST16980827
TIAL CALIBRATION: 120 UG/ML HSL STD ST 169808270
:TIAL CALIBRATION: 160 UG/ML HSL STD ST16980827E
Initial Calibration
>rary
itry Compound
15 C310 N-NITROSODIMETN
100 C320 ANILINE
105 C315 PHENOL
110 C325 BIS(2-CHLOROETH
115 C330 2-CHLOROPHENOL
125 C335 1,3-DICHLOROBEN
130 C340 1,4-DICHLOROBEN
145 C345 BENZYL ALCOHOL
150 C350 1,2-DICHLOROBEN
160 C355 2-METHYLPHENOL
165 C360 2,2'-OXYBIS(1-C
185 C365 4-METHYLPHENOL
190 C370 N-NITROSO-DI-N-
200 C375 HEXACHLOROETHAN
10 C410 NITROBENZENE
20 C415 ISOPHORONE
25 C420 2-NITROPHENOL
30 C425 2,4-DIMETHYLPHE
45 C430 BENZOIC ACID
35 C435 BIS(2-CHLOROETH
40 C440 2,4-DICHLOROPHE
55 CMS 1,2,4-TRICHLORO
60 C450 NAPHTHALENE
80 C455 4-CHLOROANALINE
95 C460 HEXACHLOROBUTAD
130 C465 4-CHLORO-3-METH
145 C470 2-METHYLNAPHTHA
20 C510 HEXACHLOROCYCLO
25 C515 2,4,6-TRICHLORO
30 C520 2,4,5-TRICHLORO
40 C525 2-CHLORONAPHTHA
45 C530 2-NITROANALINE
55 CS35 DIMETHYLPHTHALA
65 C540 ACENAPHTHYLENE
70 C543 2,6-OIHITROTOLU
75 C545 3-NITROANILINE
80 C550 ACENAPHTHENE
85 C555 2,4-DINITROPHEN
Response Factor
Avg Min
1.019
1.846
1.968
1.368
1.497
1.586
1.618
0.854
1.500
1.174
2.539
1.276
0.906 0.050
0.708
0.445
0.742
0.213
0.330
0.276
0.511
0.308
0.331
1.022
0.454
0.168
0.338
0.751
0.372 0.050
0.404
0.412
1.193
0.502
1.341
1.839
0.324
0.383
1.158
0.189 0.050
X RSD
Max
4.4
6.2
7.8 30.0
6.1
5.5
4.5
4.8 30.0
9.3
5.0
7.4
3.9
9.0
5.1
3.5
7.2
5.5
7.9 30.0
16.9
4.7
4.1
6.6 30.0
5.0
6.6
4.5
5.1 30.0
9.0 30.0
10.8
10.1
10.6 30.0
7.1
6.6
2.9
6.1
8.2
8.5
1.4
6.9 30.0
10.3
08/27/98 9:56:00
08/27/98 10:21:00
08/27/98 10:51:00
08/27/98 9:22:00
08/27/98 11:20:00
08/27/98 11:50:00
Continuing Calibration
Response Factor X Diff
Min Max
14€S
-------
QUANTERRA GC/MS
SEMIVOLATILE HSL CALIBRATION CHECK
INITIAL CALIBRATION: 10 UG/HL HSL STD ST16980827A 08/27/98 9:56:00
INITIAL CALIBRATION: 20 UG/ML HSL STD ST16980827B 08/27/98 10:21:00
INITIAL CALIBRATION: 50 UG/ML HSL STD ST16980827C 08/27/98 10:51:00
INITIAL CALIBRATION: 80 UG/ML HSL STD ST 16980827 08/27/98 9:22:00
INITIAL CALIBRATION: 120 UG/ML HSL STD ST16980827D 08/27/98 11:20:00
INITIAL CALIBRATION: 160 UG/ML HSL STD ST16980827E 08/27/98 11:50:00
Initial Calibration Continuing Calibration
Library Response Factor X RSD Response Factor X Diff
Entry
S3
S3
S3
S3
S3
S3
54
S4
54
S4
S4
54
S4
54
S4
54
S4
S5
S5
S5
S5
55
55
S5
S6
56
56
56
56
56
56
51
S2
S3
55
51
51
51
S3
90
105
130
140
135
150
10
15
20
30
40
50
65
70
80
85
110
10
15
40
55
50
60
65
10
15
25
35
55
60
65
6
2
3
2
3
2
5
2
Compound
C565
C570
C580
C585
C590
C595
C610
C615
C620
C625
C630
C635
C640
C645
C647
C650
C655
C710
C715
C720
C725
C730
C740
C745
C760
C765
C770
C775
C780
C785
C790
CS75
CS20
CS25
CS30
CS45
CS50
CS70
CS55
DIBENZOFURAN
2,4-DINITROTOLU
D1ETHYLPHTHALAT
4-CHLOROPHENYL-
FLUORENE
4-NITROANALINE
4.6-DINITRO-2-M
N-NITROSODIPHEN
AZOBENZENE
4-BROMOPHENYL-P
HEXACHLOROBENZE
PENTACHLOROPHEN
PHENANTHRENE
ANTHRACENE
CARBAZOLE
DI-N-BUTYLPHTHA
FLUORANTHENE
BENZIDINE
PYRENE
BUTYLBENZYLPHTH
3,3'-DICHLOROBE
BENZO(A)ANTHRAC
CHRYSENE
BISC2-ETHYLHEXY
DI-N-OCTYL PHTH
BENZO(B)FLUORAN
BENZOdOFLUORAN
BENZO(A)PYRENE
INDENO(1,2,3-CD
DIBENZCA.HJANTH
BENZO(G,H,I)PER
1,2-DICHLOROBNZ
NITROBENZENE-OS
2-FLUOROBIPHENY
TERPHENYL-D14
PHENOL-D5
2-FLUOROPHENOL
2-CHLOROPHENOL-
2,4,6-TRlBROMOP
Avg Min
1.
0.
1.
0.
1.
0.
0.
0.
1.
0.
0.
0.
1.
0.
0.
1.
0.
0.
1.
0.
0.
1.
1.
0.
1.
1.
1.
669
397
369
613
298
307
132
551
171
223
260
155
033
987
764
247
900
129
323
685
408
125
014
980
925
444
159
1.182
1.279
1.267
1.331
0.
920
0.470
1.234
0.995
2.026
1.368
1.482
0.236
6.
8.
7.
5.
6.
8.
7.
4.
3.
3.
6.
5.
5.
11.
10.
9.
13.
23.
6.
7.
5.
5.
6.
9.
7.
5.
9.
2
8
7
4
8
4
6
2
9
9
7
9
2
0
3
4
5
7
5
7
7
4
7
4
4
0
8
5.3
6.
6
Max Min Max
30.0
30.0
30.0
30.0
30.0
8.1
8.2
6.5
5.2
6.2
5.3
2.0
4.4
4.1
6.9
0 CCC and SPCC compounds are out
146
-------
OUAMTERRA GC/NS
SEHIVOLATILE HSL CALIBRATION CHECK
miAL CALIBRATION: 10 UG/HL HSL STD ST16980827A 08/27/98 9:56:00
UITIAL CALIBRATION: 20 UG/ML HSL STD ST16980827B 08/27/98 10:21:00
1ITIAL CALIBRATION: 50 UG/ML HSL STD ST16980827C 08/27/98 10:51:00
1ITIAL CALIBRATION: 80 UG/ML HSL STD ST16980827 08/27/98 9:22:00
miAL CALIBRATION: 120 UG/ML HSL STD ST16980827D 08/27/98 11:20:00
1ITIAL CALIBRATION: 160 UG/ML HSL STD ST16980827E 08/27/98 11:50:00
ST16980827A ST16980827B ST16980827C ST16980827 ST16980827D ST16980827E
ib # Cone RRF Cone RRF Cone RRF Cone RRF Cone RRF Cone RRF
======================================x====3==========r=======3=======3a
1 15 10, 0.952 20. 1.010 50, 1.016 80, 1.087 120, 1.008 160, 1.042
1 100 10, 1.947 20, 1.988 50, 1.814 80, 1.876 120, 1.778 160, 1.674
I 105 10, 1.699 20, 2.037 50, 2.035 80, 2.148 120, 1.907 160, 1.982
I 110 10, 1.336 20, 1.465 50, 1.438 80, 1.414 120, 1.291 160, 1.261
I 115 10, 1.386 20, 1.569 50, 1.522 80, 1.603 120, 1.450 160, 1.451
I 125 10, 1.515 20, 1.668 50, 1.618 80, 1.659 120, 1.546 160, 1.510
I 130 10, 1.580 20, 1.695 50, 1.666 80, 1.697 120, 1.549 160, 1.518
I 145 10, 0.702 20, 0.851 50, 0.872 80, 0.913 120, 0.866 160, 0.922
I 150 10, 1.475 20, 1.606 50, 1.482 80. 1.573 120, 1.454 160, 1.409
I 160 10, 0.998 20, 1.206 50, 1.221 80. 1.209 120, 1.199 160, 1.213
I 165 10, 2.393 20, 2.676 50, 2.597 80, 2.582 120, 2.502 160, 2.486
I 185 10, 1.049 20, 1.298 50, 1.355 80, 1.287 120, 1.316 160, 1.351
I 190 10, 0.819 20, 0.934 50, 0.938 80, 0.940 120, 0.913 160, 0.890
I 200 10, 0.665 20, 0.740 50, 0.713 80, 0.720 120, 0.706 160, 0.706
! 10 10, 0.423 20, 0.477 50, 0.455 80, 0.486 120, 0.419 160, 0.410
! 20 10, 0.685 20, 0.778 50, 0.774 80, 0.778 120, 0.726 160, 0.708
> 25 10, 0.182 20, 0.212 50, 0.218 80, 0.232 120, 0.219 160, 0.217
'. 30 10, 0.234 20, 0.309 50, 0.334 80, 0.400 120, 0.349 160, 0.353
2 « 20, 0.257 50, 0.279 80, 0.270 120, 0.280 160, 0.292
> 35 10, 0.481 20, 0.529 50, 0.517 80, 0.538 120, 0.502 160, 0.498
> 40 10. 0.270 20, 0.313 50, 0.314 80, 0.332 120, 0.311 160, 0.306
! 55 10, 0.319 20, 0.350 50, 0.334 80, 0.350 120, 0.322 160, 0.310
! 60 10, 1.008 20, 1.090 50, 1.038 80, 1.102 120, 0.960 160, 0.935
: 80 10, 0.419 20, 0.466 50, 0.454 80, 0.480 120, 0.449 160, 0.455
! 95 10, 0.160 20, 0.178 50, 0.170 80, 0.177 120, 0.167 160, 0.157
146:
-------
52
S2
S3
S3
S3
S3
S3
S3
S3
S3
S3
S3
S3
S3
130
145
20
25
30
40
45
55
65
70
75
80
85
95
10.
10,
10,
10,
10,
10.
10,
10,
10,
10,
0.279
0.773
0.329
0.327
0.397
1.172
1.257
1.751
0.274
1.140
20.
20,
20.
20.
20.
20,
20.
20.
20.
20.
20,
20.
20.
20.
0.337
0.840
0.387
0.389
0.437
1.275
0.491
1.423
1.959
0.339
0.382
1.227
0.156
0.164
50.
50,
50,
50,
50,
50,
50,
50,
50,
50.
50,
50,
50,
50,
0.353
0.827
0.376
0.405
0.429
1.208
0.510
1.392
1.896
0.341
0.392
1.182
0.190
0.178
80,
80,
80,
80,
80,
80,
80,
80,
80,
80,
80.
80,
80,
80,
0.365
0.757
0.428
0.435
0.443
1.283
0.523
1.426
2.047
0.351
0.382
1.261
0.202
0.184
120,
120,
120,
120,
120,
120,
120,
120,
120,
120,
120,
120,
120.
120,
0.347
0.671
0.379
0.417
0.401
1.128
0.487
1.297
1.707
0.321
0.379
1.075
0.203
0.168
160.
160.
160,
160,
160,
160.
160.
160.
160,
160,
160,
160,
160,
160,
0.346
0.639
0.330
0.448
0.366
1.089
0.497
1.251
1.671
0.317
0.379
1.066
0.196
0.169
14CC,
J- i v^ \J
-------
QUANTERRA GC/MS
SENIVOLATILE HSL CALIBRATION CHECK
NITIAL CALIBRATION: 10 UG/ML HSL STD ST16980827A 08/27/98 9:56:00
NITIAL CALIBRATION: 20 UG/ML HSL STO ST16980827B 08/27/98 10:21:00
NITIAL CALIBRATION: 50 UG/NL HSL STD ST16980827C 08/27/98 10:51:00
NITIAL CALIBRATION: 80 UG/ML HSL STD ST16980827 08/27/98 9:22:00
NITIAL CALIBRATION: 120 UG/ML HSL STD ST16980827D 08/27/98 11:20:00
NITIAL CALIBRATION: 160 UG/ML HSL STD ST16980827E 08/27/98 11:50:00
ST16980S27A ST16980827B ST16980827C ST16980827 ST16980827D ST16980827E
ib # Cone RRF Cone RRF Cone RRF Cone RRF Cone RRF Cone RRF
3 90 10, 1.617 20, 1.782 50, 1.736 80, 1.762 120, 1.556 160, 1.561
3 105 10, 0.339 20, 0.412 50, 0.420 80, 0.437 120, 0.396 160, 0.378
3 130 10, 1.300 20, 1.462 50, 1.452 80. 1.462 120, 1.328 160, 1.209
3 140 10, 0.597 20, 0.647 50, 0.631 80, 0.646 120, 0.579 160, 0.575
3 135 10, 1.251 20, 1.398 50, 1.340 80, 1.386 120, 1.224 160, 1.188
3 150 20, 0.326 50, 0.320 80, 0.306 120, 0.263 160. 0.321
4 10 ,:0, 0.121 50, 0.139 80, 0.145 120, 0.124 160. 0.130
4 15 10, 0.568 20, 0.582 50, 0.562 80, 0.539 120, 0.530 160, 0.523
4 20 10, 1.150 20, 1.222 50, 1.186 80, 1.212 120, 1.098 160. 1.158
4 30 10, 0.224 20, 0.231 50, 0.223 80, 0.232 120, 0.215 160, 0.210
4 40 10, 0.273 20, 0.281 50, 0.255 80, 0.268 120, 0.238 160, 0.242
4 50 20, 0.148 50, 0.156 80, 0.170 120, 0.155 160, 0.147
:4 65 10, 1.017 20. 1.081 50, 1.044 80. 1.096 120, 0.948 160, 1.010
:4 70 10, 1.019 20, 1.100 50, 1.026 80, 1.059 120, 0.908 160, 0.809
!4 80 10, 0.914 20, 0.763 50, 0.729 80, 0.769 120, 0.707 160, 0.701
:4 85 10. 1.233 20, 1.366 50, 1.332 80, 1.333 120, 1.137 160. 1.080
'A 110 10, 1.013 20, 1.008 50, 0.925 80, 0.950 120, 0.788 160, 0.715
S 10 20, 0.155 50, 0.143 80, 0.077 120, 0.141 160, 0.131
3 15 10,1.209 20,1.310 50,1.295 80,1.468 120,1.295 160,1.358 1470
'5 40 10, 0.587 20, 0.673 50, 0.692 80, 0.722 120, 0.700 160, 0.734
;5 55 20, 0.441 50, 0.421 80, 0.383 120, 0.405 160, 0.391
3 50 10, 1.058 20, 1.195 50. 1.116 80, 1.203 120, 1.086 160, 1.092
5 60 10, 1.034 20, 1.068 50, 1.005 80, 1.102 120, 0.959 160, 0.919
-------
S6
S6
S6
S6
S6
S6
S1
S2
S3
S5
S1
S1
S1
S3
15
25
35
55
60
65
6
2
3
2
3
2
5
2
10,
10,
10,
10,
10,
10,
10.
10,
10,
10,
1.322
1.185
1.168
1.253
1.254
1.339
0.832
0.446
1.252
0.932
20,
20,
20,
20.
20.
20.
20.
20.
20,
20,
20,
20,
20,
20.
1.536
1.223
1.257
1.355
1.386
1.436
0.999
0.494
1.315
1.002
2.057
1.291
1.561
0.261
50.
50,
50.
50,
50,
50,
50,
50.
50,
50,
50.
50.
50.
50,
1.448
1.171
1.206
1.312
1.288
1.356
0.946
0.469
1.253
0.976
2.059
1.332
1.501
0.239
80,
80.
80,
80,
80.
80,
80,
80,
80,
80,
80,
80,
80,
80,
1.453
1.264
1.229
1.368
1.360
1.426
0.959
0.504
1.299
1.082
2.046
1.448
1.503
0.233
120,
120,
120,
120.
120,
120,
120,
120,
120,
120,
120,
120,
120,
120,
1.490
1.171
1.147
1.241
1.212
1.289
0.902
0.452
1.171
0.960
1.995
1.376
1.437
0.228
160,
160,
160,
160,
160,
160,
160,
160,
160,
160,
160,
160,
160,
160,
1.412
0.940
1.084
1.144
1.105
1.139
0.882
0.452
1.116
1.019
1.971
1.394
1.407
0.217
1471
-------
DATA FROM FILE: ST16980827A SCANS 230 TO 1200 ACQUIRED: 08x27x98 9:56:00
CALI: ST16980827A *3
SAMPLE: SSTD010 10UGxML CALI UI 070698D
CONDS.: INST. ID: F16
FTIITROBENZENE-D5
800 _
8:54
1000 .
11:07
J 100.8Z < 117248.)
ENOL-D5
99SS1# 03
4165-62-2
3855-82-1
CI40 NAPHTHALENE-OS
136IS2* 01
.CS25 2-FLUOROBIPHENYL
172SS3# 03
2,4,6-TRIBROMOPHENOL 330SS3* 02
321-60-8
CI50 ACENAPHTHENE-D10
118-79-6
164IS3* 01
1146-65-2
15067-26-2
CI60 PHENANTHRENE-D10
183IS4* 01
1517-22-2
to
-------
DATA FROM FILE: ST16980827A SCANS 1200 TO 2158 ACQUIRED: 08/27x98 9:56:00
CALI: ST16980827A #3
SAMPLE: SSTD010 10UG/ML CALI UI 0766980
COHDS.i INST. ID: F16
1200 .
13:21
1400 .
15:34
1600 .
17:48
1800 .
20:01
2000
22:15
_L
CS30 TERPHENYL-D14
I
J 100.07. < 109184.)
244SS5* 02
1718-51-0
CI70 CHRYSENE-012
240IS5« 01
1719-03-5
CI75 PERYLENE-D12
164IS6* 01
1520-96-3
ffflg
co
-------
antitation Report File: ST16980827A
ta: ST16980827A.TI
727/98 9:56:00
mple: SSTD010 10UG/ML CALI VI 0706980
>nds.: INST. ID: F16
irmula: 1UL INJ. Instrunent: F16
ifamitted by: QES Analyst: DAT
IOUNT=AREA * REF AHNT/(REF AREA * RESP FACT)
;sp. fac. from Library Entry
lo Name
1 CI30
CI40
CI50
CI60
CI70
6 CITS
7 CS20
8 CS2S
9 CS30
10 CS75
!1 C310
12 C320
13 C315
14 C325
15 C330
16 C335
17 C340
18 C345
19 C350
20 C355
21 C360
22 C365
23 C370
24 C375
25 C410
26 C415
27 C420
28 C425
29 C435
30 C440
31 C445
32 C450
33 C455
34 C460
35 C465
36 C470
37 C510
38 C515
39 C520
40 CS25
41 CS35
42 CS40
43 C543
44 C550
45 C565
46 C570
47 C580
NAPHTHALENE-D8
ACENAPHTHENE-D10
PHENANTHRENE-D10
CHRYSENE-D12
PERYLENE-D12
NITROBENZENE-DS
2-FLUOR08IPHENYL
TERPHENYL-D14
1.2-DICHLOROBNZN-D4
N-NITROSOOIHETHYLAMINE
ANILINE
PHENOL
BIS(2-CHLOROETHYL)ETHE
2-CHLOROPHENOL
1,3-DICHLOROBENZENE
1,4-DICHLOROBENZENE
BENZYL ALCOHOL
1,2-DICHLOROBENZENE
2-METHYLPHENOL
2,2'-OXYBIS<1-CLPROPAN
4-METHYLPHENOL
N-NITROSO-DI-N-PROPYLA
HEXACHLOROETHANE
NITROBENZENE
ISOPNORONE
2-NITROPHENOL
2,4-DINETHYLPHENOL
BIS(2-CHLOROETHOXY)MET
2,4-DICHLOROPHENOL
1,2,4-TRICHLOROBENZENE
NAPHTHALENE
4-CHLOROANALINE
HEXACHLOROBUTADIENE
4-CHLORO-3-METHYLPHENO
2-METHYLNAPHTHALENE
HEXACHLOROCYCLOPENTADI
2,4,6-TRICHLOROPHENOL
2,4,5-TRICHLOROPHENOL
2-CHLORONAPHTHALENE
DIMETHYLPHTHALATE
ACENAPHTHYLENE
2,6-OINITROTOLUENE
ACENAPHTHENE
DIBENZOFURAN
2,4-DINITROTOLUENE
DIETHYLPHTHALATE
Weight: 0.000
Acct. No.: FIN
152IS1* 01
136IS2* 01
164IS3* 01
188IS4* 01
240IS5* 01
164IS6* 01
82SS2* 02
172SS3* 03
244SS5* 02
152 S1# 06
74 S1* 15
93 S1*100
94 S1#105CC
! 93 S1#110
128 S2#115
146 S1*125
146 S1#130CC
108 S1*145
146 81*150
108 S1#160
45 81*165
108 81*185
I 70 S1#190SP
117 81*200
77 82* 10
82 82* 20
139 82* 25CC
107 S2# 30
I 93 S2# 35
162 S2# 40
180 S2* 55
128 S2# 60
127 S2* 80
225 S2* 95CC
107 S2*130CC
142 82*145
237 S3* 20
196 S3* 25CC
196 S3# 30
162 S3* 40
163 S3* 55
152 S3* 65
165 S3* 70
153 S3* 80CC
168 S3* 90
165 S3*105
149 S3*130
3855-82-1
1146-65-2
15067-26-2
1517-22-2
1719-03-5
1520-96-3
4165-60-0
321-60-8
1718-51-0
62-75-9
62-53-3
108-95-2
111-44-4
95-57-8
541-73-1
106-46-7
100-51-6
95-50-1
95-48-7
108-60-1
106-44-5
621-64-7
67-72-1
98-95-3
75-59-1
88-75-5
105-67-9
111-91-1
120-83-2
120-82-1
91-20-3
106-47-8
87-68-3
59-50-7
91-57-6
77-47-4
88-06-2
95-95-4
91-58-7
131-11-3
208-96-8
606-20-2
83-32-9
132-64-9
121-14-2
84-66-2
-------
No
48
49
50
No
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
Name
C590
C585
C615
m/z
152
136
164
188
240
264
82
172
244
152
74
93
94
93
128
146
146
108
146
108
45
108
70
117
77
82
139
107
93
162
180
128
127
225
107
142
237
196
196
162
163
152
165
153
168
165
149
166
204
169
FLUORENE 166 S30135
4-CHLOROPHENYL-PHENYLE 204 53*140
N-NITROSOOIPHENYLAMINE 169 S4# 15CC
Scan
350
541
840
1098
1565
1797
431
733
1395
369
109
310
316
323
323
341
352
377
371
399
399
425
418
418
434
475
484
506
520
526
535
544
563
571
659
662
692
718
724
744
815
813
820
845
877
889
943
936
948
971
Time
3:54
6:01
9:21
12:13
17:24
19:59
4:48
8:09
15:31
4:06
1:13
3:27
3:31
3:36
3:36
3:48
3:55
4:12
4:08
4:26
4:26
4:44
4:39
4:39
4:50
5:17
5:23
5:38
5:47
5:51
5:57
6:03
6:16
6:21
7:20
7:22
7:42
7:59
8:03
8:17
9:04
9:03
9:07
9:24
9:45
9:53
10:29
10:25
10:33
10:48
Ref
1
2
3
4
5
6
2
3
5
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
2
2
2
2
2
2
2
2
2
2
2
2
3
3
3
3
3
3
3
3
3
3
3
3
3
4
RRT
1.000
1.000
1.000
1.000
1.000
1.000
0.797
0.873
0.891
1.054
0.311
0.886
0.903
0.923
0.923
0.974
1.006
1.077
1.060
1.140
1.140
1.214
1.194
1.194
0.802
0.878
0.895
0.935
0.961
0.972
0.989
1.006
1.041
1.055
1.218
1.224
0.824
0.855
0.862
0.886
0.970
0.968
0.976
1.006
1.044
1.058
1.123
1.114
1.129
0.884
Meth
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
-------
lo
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
Ret(L)
3:54
6:01
9:21
12:13
17:25
19:59
4:49
8:11
15:32
4:07
1:12
3:27
3:33
3:36
3:36
3:48
3:55
4:13
4:08
4:27
4:26
4:44
4:40
4:39
4:51
5:19
5:24
5:39
5:48
5:52
5:57
6:04
6:16
6:22
7:20
7:22
7:42
8:00
8:03
8:17
9:06
9:03
9:09
9:25
9:46
9:55
10:31
10:26
10:33
10:50
Ratio
1.00
1.00
1.00
1.00
1.00
.00
.00
.00
.00
.00
1.01
1.00
0.99
1.00
1.00
1.00
1.00
0.99
1.00
1.00
1.00
1.00
1.00
1.00
1.00
0.99
1.00
1.00
.00
.00
.00
.00
.00
.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
RRT(L)
1.000
1.000
1.000
1.000
1.000
1.000
0.800
0.875
0.891
1.057
0.309
0.886
0.911
0.926
0.926
0.974
1.006
1.083
1.063
1.143
1.140
1.217
1.200
1.194
0.806
0.884
0.896
0.939
0.965
0.974
0.989
1.007
1.043
1.057
1.220
1.226
0.824
0.856
0.862
0.887
0.974
0.969
0.980
1.007
1.045
1.061
1.126
1.117
1.130
0.886
Ratio
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.01
1.00
0.99
1.00
1.00
.00
.00
0.99
.00
.00
.00
1.00
1.00
1.00
1.00
0.99
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
Amnt
40.00
40.00
40.00
40.00
40.00
40.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
Amnt(L)
40.00
40.00
40.00
40.00
40.00
40.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
R.Fac R
1.000
1.000
1.000
1.000
1.000
1.000
0.446
1.252
0.932
0.832
0.952
1.947
1.699
1.336
1.386
1.515
1.580
0.702
1.475
0.998
2.393
1.049
0.819
0.665
0.423
0.685
0.182
0.234
0.481
0.270
0.319
1.008
0.419
0.160
0.279
0.773
0.329
0.327
0.397
1.172
1.257
1.751
0.274
1.140
1.617
0.339
1.300
1.251
0.597
0.568
.Fac(L)
1.000
1.000
1.000
1.000
1.000
1.000
0.446
1.252
0.932
0.832
0.952
1.947
1.699
1.336
1.386
1.515
1.580
0.702
1.475
0.998
2.393
1.049
0.819
0.665
0.423
0.685
0.182
0.234
0.481
0.270
0.319
1.008
0.419
0.160
0.279
0.773
0.329
0.327
0.397
1.172
1.257
1.751
0.274
1.140
1.617
0.339
1.300
1.251
0.597
0.568
Ratio
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
l47i
-------
Quantitat ion Report File: ST16980827A
Data: ST16980827A.TI
08/27/98 9:56:00
Sample: SST0010 10UG/ML CALI VI 0706980
Conds.: INST. ID: M6
Formula: 1UL 1NJ. Instrument: F16
Submitted by: QES Analyst: DAT
AMOUNTsAREA * REF AMNT/CREF AREA * RESP FACT)
Resp. fac. from Library Entry
No Name
51 C620 AZOBENZENE 77 S4# 20
52 C625 4-BROMOPHENYL-PHENYLET 248 S4# 30
53 C630 HEXACHLOROBENZENE 284 S4# 40
54 C640 PHENANTHRENE 178 S4# 65
55 C645 ANTHRACENE 178 S4# 70
56 C647 CARBAZOLE 167 S4# 80
57 C650 DI-N-BUTYLPHTHALATE 149 S4# 85
58 C655 FLUORANTHENE 202 S4#110CC
59 C715 PYRENE 202 S5# 15
60 C720 BUTYLBENZYLPHTHALATE 149 S5# 40
61 C730 8ENZO( A) ANTHRACENE 228 S5# 50
62 C740 CHRYSENE 228 S5# 60
63 C745 BIS(2-ETHYLHEXYL)PHTHA 149 S5# 65
64 C760 DI-N-OCTYL PHTHALATE 149 S6# 10CC
65 C765 BENZO(B) FLUORANTHENE 252 S6# 15
66 C770 BENZO(IC) FLUORANTHENE 252 S6# 25
67 C775 BENZO(A)PYRENE 252 S6# 35
68 C780 INDENO(1,2,3-CD)PYRENE 276 S6# 55
69 C785 DIBENZ(A,H)ANTHRACENE 278 So* 60
70 C790 BENZO(G,H,I}PERYLENE 276 S6# 65
No
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
69
70
m/z
77
248
284
178
178
167
149
202
202
149
228
228
149
149
252
252
252
276
278
276
Scan
974
1032
1030
1102
1111
1149
1238
1310
1346
1499
1564
1569
1616
1726
1740
1744
1787
1942
1949
1973
Time
10:50
11:29
11:27
12:15
12:21
12:47
13:46
14:34
14:58
16:40
17:24
17:27
17:58
19:12
19:21
19:24
19:53
21:36
21:41
21:57
Ref
4
4
4
4
4
4
4
4
5
5
5
5
5
6
6
6
6
6
6
6
RRT
0.887
0.940
0.938
1.004
1.012
1.046
1.128
1.193
0.860
0.958
0.999
1.003
1.033
0.960
0.968
0.971
0.994
1.081
1.085
1.098
Meth
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
BB
BB
BB
BV
VB
BB
BB
BB
BB
BB
BV
VB
BB
BB
BV
VB
BV
BV
VB
BB
Weight: 0.000
Acct. No.: FIN
103-33-3
101-55-3
118-74-1
85-01-8
120-12-7
86-74-8
84-74-2
206-44-0
129-00-0
85-68-7
56-55-3
218-01-9
117-81-7
117-84-0
205-99-2
207-08-9
50-32-8
193-39-5
53-70-3
191-24-2
Area(Hght) Amount
30384.
5922.
7204.
26864.
26934.
24164.
32570.
26774.
28050.
13618.
24540.
23974.
18824.
31870.
25726.
23064.
22740.
24388.
24406.
26073.
10.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
UG/ML
UG/NL
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
XTot
1.14
1.14
1.14
1.14
1.14
1.14
1.14
.14
.14
.14
.14
.14
1.14
1.14
1.14
1.14
1.14
1.14
1.14
1.14
1477
-------
Mo
51
52
53
54
55
56
57
58
59
60
61
62
a
64
55
56
57
S8
59
ro
Ret(L)
10:51
11:29
11:29
12:17
12:22
12:47
13:47
14:36
15:00
16:41
17:24
17:28
17:58
19:13
19:23
19:26
19:54
21:38
21:43
21:59
Ratio
1.00
1.00
1.00
.00
.00
.00
.00
.00
.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
RRT(L) Ratio
0.888 1.00
0.940 1.00
0.939
1.005
1.012
1.046
1.127
1.194
0.861
0.958
0.999
1.003
1.032
0.961
0.969
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
0.972 1.00
0.996 1.00
1.082 1.00
1.086 1.00
1.100 1.00
Aunt
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
AlWlt(L)
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
R.
1
0
0
1
1
0
0
1
1
1
1
1
1
1
Fee R.
.150
.224
.273
.017
.019
.914
.233
.013
.209
.587
.058
.034
.812
.637
.322
.185
.168
.253
.254
.339
Fac(L) Ratio
1.150 1.00
0.224 1.00
0.273 1.00
1.017 1.00
1.019 1.00
0.914 1.00
1.233 1.00
1.013 1.00
1.209
0.587
1.058
1.034
0.812
1.637
1.322
1.185
1.168
1.253
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
1.254 1.00
1.339 1.00
.lANUAL EDIT CUUtS
i. PEAK NOT FOUND
2. POORCHROMATOGRAPh,
3. WROiNG ISOMER
ML MANUAL EDFTS MUST BF.
™i.5D, DATED, AMD OH. •'
-------
3WI1
•8889
80S-0
V0T
0Q9
• I i
01 :Z
St-9
i
l i I I
•T098
•1903
c '0s n «3sya 0 r e?9'9 y »Nyno 0-3
0W
zti
-0-00T
01 0*9 snyos
T#
N naayi BQIZ'I o
9id *ai -ISNI «
08690Z9 in tiyo in/one i 0100155
«nyo 00*95*6
»yiya swyaooiywoaHo ssyw
-------
DATA FROM FILE: ST16988827B SCANS 238 TO 1280 ACQUIREDi 88x27/98 18:21:00
CALI: ST16980827B #3
SAMPLE: SSTD020 20UG/ML CALI U 070698E
CONDS.i INST. ID: F16
600 _
6:40
880 .
8s 54
1000 .
11:07
100.0Z < 122752.)
99SS1* 03 4165-62-2
CJ38 Xi4-DICHLORgBENZENE-D4 152IS1* 01
2-DICHLOROBNZN-04 152 Sli 06
3855-82-1
82SS2# 02
4165-60-0
CI40 NAPHTHALENE-08
136IS2* 01
^=.CS25 2-FLUOROBIPHENYL
172SS3# 03
321-60-8
CI50 ACENAPHTHENE-D10
164IS3* 01
Lb33 ^,4
-------
DATA FROM FILE: ST16980827B SCANS 1260 TO 2158 ACQUIRED: 08/27x98 10:21:60
CALI: ST16980827B #3
SAMPLE: SSTD028 20UGXML CALI V 070698E
CONDS.: INST. ID: F16
1200
13:21 L
1400 .
15:34
1600 _
17:48
1800 .
20:01
2000
22:15
J 100.0JZ < 119424.)
-CS30 TERPHENYL-D14
244SS5* 02
1718-51-0
CI70 CHRYSENE-D12
240IS5* 01
1719-03-5
CI75 PERYLENE-D12
164IS6* 01
1520-96-3
i i
-------
uantitation Report File: ST16980827B
ata: ST16980827B.TI
8/27/98 10:21:00
ample: SST0020 20UG/ML CALI V 070698E
onds.: 1NST. ID: F16
ormula: 1UL INJ. Instrument: F16
utaritted by: QES Analyst: DAT
MOUNT=AREA * REF AMNT/CREF AREA * RESP FACT)
esp. fac. from Library Entry
Weight: 0.000
Acct. No.: FIN
No
1
2
3
4
5
6
7
8
9
10
11
12
!3
14
15
16
17
8
9
!0
!1
!2
3
:4
5
!6
:7
:8
!9
;o
11
,2
3
4
5
6
7
8
9
0
1
2
3
4
5
6
7
Name
C130
CI40
C150
CI60
CI70
CITS
CS20
CS25
CS30
CS45
CS50
CS55
CS70
CS75
1 , 4-DICHLOROBENZENE-D4
NAPHTHALENE-OS
ACENAPHTHENE-D10
PHENANTHRENE-D10
CHRYSENE-D12
PERYLENE-D12
NITROBENZENE-DS
2-FLUOROBIPHENYL
TERPHENYL-D14
PHEHOL-OS
2-FLUOROPHENOL
2,4,6-TRIBROMOPHENOL
2-CHLOROPHENOL-D4
1.2-DICHLOROBNZN-D4
152IS1* 01
1361 S2# 01
1641 S3* 01
188154* 01
240IS5* 01
164IS6* 01
82SS2* 02
172SS3* 03
244SS5* 02
99SS1* 03
112SS1* 02
330SS3* 02
132
152
S1# 05
S1* 06
3855-82-1
1146-65-2
15067-26-2
1517-22-2
1719-03-5
1520-96-3
4165-60-0
321-60-8
1718-51-0
4165-62-2
367-12-4
118-79-6
HEXACHLOROBENZENE-C13
C310
C320
C315
C325
C330
C335
C340
C345
C350
C355
C360
C365
C370
C375
C410
C415
C420
C42S
C435
C440
C430
C445
C450
C455
C460
C465
C470
C510
C515
CS20
C525
C530
N-NITROSOOIMETHYLAMINE
ANILINE
PHENOL
BIS(2-CHLOROETHYL)ETHER
2-CHLOROPHENOL
1,3-DICHLOROBENZENE
1,4-DICHLOROBENZENE
BENZYL ALCOHOL
1,2-DICHLOROBENZENE
2-METHYLPHENOL
2,2'-OXYBIS<1-CLPROPAN>
4-METHYLPHENOL
74 S1# 15
93
94
93
128
146
146
108
146
108
45
108
N-NITROSO-DI-N-PROPYLAM 70
HEXACHLOROETHANE
NITROBENZENE
ISOPHORONE
2-NITROPHENOL
2,4-DIMETHYLPHENOL
117
77
82
139
107
BIS(2-CHLOROETHOXY)METH 93
2,4-DICHLOROPHENOL
BENZOIC ACID
1 . 2,4-TRICHLOROBEHZENE
NAPHTHALENE
4-CHLOROANALINE
HEXACHLOROBUTAOIENE
4-CHLORO-3-METHYLPHENO
2-METHYLNAPHTHALENE
HEXACHLOROCYCLOPENTAD I
2 , 4 , 6- TR I CHLOROPHENOL
2,4,5-TRICHLOROPHENOL
2-CHLORONAPHTHALENE
2-NITROANALINE
162
122
180
128
127
225
107
142
237
196
196
162
65
S10100
S1#105CC
51*110
S2#115
S1#125
S10130CC
S1#145
S1#150
S1#160
S1#165
S1#185
S1#190SP
S1#200
S2# 10
S2* 20
S2# 25CC
S2# 30
S2# 35
S2«f 40
S2# 45
S2# 55
S2# 60
S2# 80
S2# 95CC
S2#130CC
52*145
S3* 20
S3* 25CC
S3* 30
S3* 40
S3* 45
62-75-9
62-53-3
108-95-2
111-44-4
95-57-8
541-73-1
106-46-7
100-51-6
95-50-1
95-48-7
108-60-1
106-44-5
621-64-7
67-72-1
98-95-3
75-59-1
88-75-5
105-67-9
111-91-1
120-83-2
65-85-0
120-82-1
91-20-3
106-47-8
87-68-3
59-50-7
91-57-6
77-47-4
88-06-2
95-95-4
91-58-7
88-74-4
-------
No
48
49
50
No
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
Name
C535 DIMETHYLPHTHALATE
C540 ACENAPHTHYLENE
C543 2,6-OINlTROTOLUENE
m/z
152
136
164
188
240
264
82
172
244
99
112
330
132
152
NOT
74
93
94
93
128
146
146
108
146
108
45
108
70
117
77
82
139
107
93
162
122
180
128
127
225
107
142
237
196
196
162
65
163
152
165
Scan
350
541
840
1099
1565
1797
432
734
1395
315
204
980
321
369
FOUND
109
310
317
323
323
341
352
377
371
399
399
425
418
418
434
476
484
506
520
526
542
535
544
563
571
659
662
692
718
724
744
772
816
813
821
Time
3:54
6:01
9:21
12:13
17:24
19:59
4:48
8:10
15:31
3:30
2:16
10:54
3:34
4:06
1:13
3:27
3:32
3:36
3:36
3:48
3:55
4:12
4:08
4:26
4:26
4:44
4:39
4:39
4:50
5:18
5:23
5:38
5:47
5:51
6:02
5:57
6:03
6:16
6:21
7:20
7:22
7:42
7:59
8:03
8:17
8:35
9:05
9:03
9:08
Ref
1
2
3
4
5
6
2
3
5
1
1
3
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
2
2
2
2
2
2
2
2
2
2
2
2
2
3
3
3
3
3
3
3
3
RRT
1.000
1.000
1.000
1.000
1.000
1.000
0.799
0.874
0.891
0.900
0.583
1.167
0.917
1.054
0.311
0.886
0.906
0.923
0.923
0.974
1.006
1.077
1.060
1.140
1.140
1.214
1.194
1.194
0.802
0.880
0.895
0.935
0.961
0.972
1.002
0.989
1.006
1.041
1.055
1.218
1.224
0.824
0.855
0.862
0.886
0.919
0.971
0.968
0.977
163 S3*
152 S3*
165 S3*
Heth
A BB
A BB
A BB
A BV
A BB
A BB
A BV
A BB
A BV
A BB
A BB
A BB
A BV
A BB
A BB
A BV
A VB
A VB
A BB
A BV
A VB
A BB
A BB
A BB
A BB
A BB
A BV
A BB
A VB
A BV
A BB
A BB
A BV
A BB
qedt ^
A BB ,
A BB 4
A BB ^
A BB *
A BB
qedt^j
A BB
A BV
A VB
A BB
A BV
A BB
A BB
A BB
55
65
70
131-11-3
208-96-8
606-20-2
Area(Hght) Amount
34646.
125585.
68486.
117544.
91058.
75628.
31049.
45046.
45608.
35638.
22364.
8930.
27038.
17300.
17503.
34446.
35279.
25381.
27177.
28889.
29367.
14744.
27815.
20889.
46351.
22478.
16174.
12820.
29943.
48830.
13326.
19411.
33193.
19655.
b) 16146.
. 21964.
£ 68435.
$ 29283.
^ 11206.
V 21143.
H. 52750.
13238.
13337.
14963.
43660.
16816.
48724.
67074.
11592.
40.
40.
40.
40.
40.
40.
20.
20.
20.
20.
20.
20.
20.
20.
20.
20.
20.
20.
20.
20.
20.
20.
20.
20.
20.
20.
20.
20.
20.
20.
20.
20.
20.
20.
20.
20.
20.
20.
20.
20.
20.
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
20.000
20.
20.
20.
20.
000
000
000
000
20.000
20.000
20.000
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/HL
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/HL
UG/ML
UG/HL
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
XTot
2.22
2.22
2.22
2.22
2.22
2.22
1.11
1.11
1.11
1.11
1.11
1.11
1.11
1.11
1.11
1.11
1.11
1.11
1.11
1.11
1.11
1.11
1.11
1.11
1.11
1.11
1.11
1.11
1.11
1.11
1.11
1.11
1.11
1.11
1.11
1.11
1.11
1.11
1.11
1.11
1.11
1.11
1.11
1.11
1.11
1.11
1.11
1.11
1.11
-------
lo
1
2
3
4
5
6
7
8
9
0
1
2
3
4
5
6
7
8
9
0
1
2
3
4
5
6
7
8
9
0
1
2
3
t
5
6
7
3
?
D
1
2
5
'»
5
S
f
3
?
3
Ret
-------
Quant itation Report File: ST16980827B
Data: ST16980827B.TI
08/27/98 10:21:00
Sample: SSTD020 20UG/ML CALI V 070698E
Conds.: INST. ID: F16
Formula: 1UL IMJ. Instrument: F16
Submitted by: QES Analyst: DAT
AMOUNT=AREA * REF AMNT/(REF AREA * RESP FACT)
Resp. fac. from Library Entry
No
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
69
70
71
72
73
74
75
76
77
78
79
80
81
82
83
84
85
No
51
52
53
54
55
56
57
58
Name
C545
C550
C555
C565
C560
C570
C580
C590
C585
C595
C610
C615
C620
C625
C630
C635
C640
CMS
C647
C650
C655
C710
C715
C720
C730
C725
C740
C745
C760
C765
C770
C775
C780
C785
C790
m/z
138
153
184
168
109
165
149
166
3-NITROANILINE
ACENAPHTHENE
2,4-DINITROPHENOL
DIBENZOFURAN
4-NITROPHENOL
2,4-DINITROTOLUENE
DIETHYLPHTHALATE
FLUORENE
4-CHLOROPHENYL-PHENYLE
4-NITROANALINE
4,6-DINITRO-2-METHYLPH
N-NITROSOOIPHENYLAMINE
AZOBENZENE
4-BROMOPHENYL-PHENYLET
HEXACHLOROBENZENE
PENTACHLOROPHENOL
PHENANTHRENE
ANTHRACENE
CARBAZOLE
DI-N-BUTYLPHTHALATE
FLUORANTHENE
BENZIDINE
PYRENE
BUTYLBENZYLPHTHALATE
BENZO(A)ANTHRACENE
3,3'-OICHLOROBEMZIDINE
CHRYSENE
BIS(2-ETHYLHEXYL)PHTHA
DI-N-OCTYL PHTHALATE
BENZO( B) FLUORANTHENE
BENZO-72-3
100-01-6
534-52-1
87-30-6
103-33-3
101-55-3
118-74-1
87-86-5
85-01-8
120-12-7
86-74-8
84-74-2
206-44-0
92-81-5
129-00-0
85-68-7
56-55-3
91-94-1
218-01-9
117-81-7
117-84-0
205-99-2
207-08-9
50-32-8
193-39-5
53-70-3
191-24-2
Amount
20.000 UG/ML
20.000 UG/ML
20.000 UG/ML
20.000 UG/ML
20.000 UG/ML
20.000 UG/ML
20.000 UG/ML
20.000 UG/ML
XTot
1.11
1.11
1.11
1.11
1.11
1.11
1.11
1.11
-------
(0
>9
SO
J1
52
S3
54
S5
S6
S7
58
S9
70
n
72
73
7t>
75
76
77
78
79
30
31
32
33
34
35
Ho
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
69
70
71
72
73
74
75
76
77
m/z
204
138
198
169
77
248
284
266
178
178
167
149
202
184
202
149
228
252
228
149
149
252
252
252
276
278
276
Scan
948
953
959
972
975
1032
1031
1073
1102
1111
1149
1238
1310
1352
1347
1499
1564
1574
1569
1615
1726
1740
1745
1787
1943
1950
1974
Time Ref RRT
10:
10:
10:
10:
10:
11:
11:
11:
12:
12:
12:
13:
14:
15:
14:
16:
17:
17:
17:
17:
19:
19:
19:
19:
21:
21:
21:
33
36
40
49
51
29
28
56
15
21
47
46
34
02
59
40
24
30
27
58
12
21
25
53
37
41
57
Ret(L) Ratio RRT(L)
9:26
9:25
9:39
9:46
9:59
9:55
10:31
10:26
10:33
10:39
10:42
10:50
10:51
11:29
11:29
11:57
12:17
12:22
12:47
13:47
14:36
15:03
15:00
16:41
17:24
17:31
17:28
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1
1
1
1
1
1
1
1
1
1
0
0
0
0
0
0
1
1
1
1
1
0
0
0
0
1
1
.010
.007
.032
.045
.068
.061
.126
.117
.130
.139
.875
.886
.888
.940
.939
.977
.005
.012
.046
.127
.194
.864
.861
.958
.999
.006
.003
3 1.129
3 1.135
4 0.873
4 0.884
4 0.887
4 0.939
4 0.938
4 0.976
4 1.003
4 1.011
4 1.045
4 1.126
4 1.192
5 0.864
5 0.861
5 0.958
5 0.999
5 1.006
5 1.003
5 1.032
6 0.960
6 0.968
6 0.971
6 0.994
6 1.081
6 1.085
6 1.098
Ratio
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
Meth
A BB
A BB
A BV
A BV
A BB
A BB
A BB
A BB
A BV
A VB
A BB
A BB
A BB
A BB
A BB
A BB
A BV
A BB
A VB
A BB
A BB
A BV
A VB
A BV
A BV
A BB
A BB
Amnt
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
Area(Hght)
22148.
11167.
7140.
34182.
71792.
13566.
16534.
8694.
63550.
64657.
44833.
80264.
59268.
7046.
59638.
30622.
54385.
20062.
48636.
44542.
74084.
58084.
46263.
47524.
51246.
52402.
54312.
Amnt(L)
20.00
20.00
20.00
20.00
20.00
20.30
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
R.
Amount
20.000
20.000
20.000
20.000
20.000
20.000
20.000
20.000
20.000
20.000
20.000
20.000
20.000
20.000
20.000
20.000
20.000
20.000
20.000
20.000
20.000
20.000
20.000
20.000
20.000
20.000
20.000
UG/ML
UG/NL
UG/NL
UG/NL
UG/NL
UG/ML
UG/ML
UG/HL
UG/NL
UG/NL
UG/NL
UG/ML
UG/ML
UG/NL
UG/ML
UG/NL
UG/NL
UG/ML
UG/ML
UG/ML
UG/ML
UG/HL
UG/HL
UG/ML
UG/ML
UG/ML
UG/ML
XTot
.11
.11
.11
.11
.11
1.11
1.11
1.11
1.11
1.11
1.11
1.11
1.11
1.11
1.11
1.11
1.11
1.11
1.11
1.11
1.11
1.11
1.11
1.11
1.11
1.11
1.11
Fac R.Fac(L) Ratio
0.382 0
1
0
1
0
0
1
1
0
0
0
0
1
0
0
0
1
1
0
1
1
0
1
0
1
0
1
.227 1
.156 0
.782 1
.164 0
.412 0
.462 1
.398 1
.647 0
.326 0
.121 0
.582 0
.222 1
.231 0
.281 0
.148 0
.081 1
.100 1
.763 0
.366 1
.008 1
.155 0
.310 1
.673 0
.195 1
.441 0
.068 1
.382
.227
.156
.782
.164
.412
.462
.398
.647
.326
.121
.582
.222
.231
.281
.148
.081
.100
.763
.366
.008
.155
.310
.673
.195
.441
.068
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
l4£t
-------
No Ret(L) Ratio RRT(L) Ratio Aunt Amnt(L) R.Fac R.Fac(L) Ratio
78
79
80
81
82
83
84
85
17:58
19:13
19:23
19:26
19:54
21:38
21:43
21:59
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.032
0.961
0.969
0.972
0.996
1.082
1.086
1.100
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
20
20
20
20
20
20
20
20
.00
.00
.00
.00
.00
.00
.00
.00
20
20
20
20
20
20
20
20
.00
.00
.00
.00
.00
.00
.00
.00
0.978
1.959
1.536
1.223
1.257
1.355
1.386
1.436
0.978
1.959
1.536
1.223
1.257
1.355
1.386
1.436
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
.!ANUAL£Dii
i. PEAK NOT FOUND
2. POORCHROMATOGRAPh,
3. WRONG ISOMER
" LL MANUAL EDITS MUST BF
DATED, AMD CD
-------
RIC+MASS CHROMATOGRAM
08/27/98 10:21:00
SAMPLE: SSTD020 20UG/ML CALI U
CONDS.: INST. ID: F16
RANGE: G 1/2158 LABEL: N 0/
DATA: ST16980827B #1
CALI: ST16980827B #3
070698E
2.0 QUAN:
SCANS 510 TO 580
BASE: U 20/ 3
100.0-
122
RIC
1628.
122.037
± 0.500
122752.
570
6:20
580 SCAN
6:27 TIME
0*1
Co
-------
DATA: ST16980827B #1
CALI: ST16980827B #3
070698E
SCANS 650 TO 689
39.5-1
MASS CHROMATOGRAMS
08/27/98 10:21:00
SAMPLEt SSTD020 20UG/ML CALI
CONOS.: INST. ID: F16
RANGE: G 1,2158 LABEL: N 2/2.0 QUAN: A 6, 2.0 J 0 BASE: U 20, 3
659
6603.
22425.
107
100.0-1
142
650
7»14
Co
662
16733.
62963.
6608.
107.032
± 0.500
16736.
142.042
± 0.500
OS
1 1 1 1
670
7:27
£ 677
170.
561.
'675
7:30
680
7:34
i • | • . i .
685
7:37
SCAN
TIME
-------
DATA FROM FILE: ST16980827C SCANS 230 TO 1208 ACQUIRED! 08/27x98 10:51800
CALI: ST16980827C #3
SAMPLE: SSTD050 50UGXML CALI IV 070698F
CONDS.j INST. IDs F16
400 _
4i27
800 _{
8i54
1000 _f
11:07
fffll J
j_
J 100.02 < 196864.)
99SS1* 03 4165-62-2
452 Sit 063855-82-1
82SS2* 02 4165-60-0
ALENE-D8
136IS2* 01
1146-65-2
-CS25 2-FLUOROBIPHENYL
172SS3# 03
321-60-8
164153ft 01
15067-26-2
L 330SS3* 02
118-79-6
ITHRENE-D10
188IS4M 01
1517-22-2
CO
o
-------
DATA FROM FILE: ST16980827C SCANS 1208 TO 2158 ACQUIREDi 88x27/98 18:51s08
CALI: ST16980827C #3
SAMPLE* SSTD050 58UG/ML CALI IU 870698F
CONDS.i INST. IDi F16
1280 .
13:21
1408 .
15:34
1600 -
17:48
1880 .
20101
2000 .
22:15
J_
100.02 < 134912.)
CS30 TERPHENYL-D14
244SS5* 02
1718-51-0
CI70 CHRYSENE-D12
240IS5* 01
1719-03-5
TT75TERYLENE-D12
164IS6* 01
1528-96-3
f_0
-------
antitation Report File: ST16980827C
ta: ST16980827C.TI
/27/98 10:51:00
wple: SSTD050 50UG/ML CALI IV 070698F
ods.: INST. ID: F16
innula: 1UL INJ.
bmitted by: QES
Instrument: F16
Analyst: DAT
OUNT=AREA * REF AMNT/(REF AREA * RESP FACT)
sp. fac. from Library Entry
Weight: 0.000
Acct. No.: FIN
io
1
2
3
4
5
6
7
8
9
0
1
2
3
4
5
6
7
8
9
:o
!1
!2
3
!4
!5
!6
!7
!8
!9
!0
11
52
53
54
55
56
57
58
59
10
11
12
13
14
15
V6
17
152IS1* 01
1361 S2* 01
164IS3* 01
188IS4* 01
240IS5* 01
164IS6* 01
82SS2* 02
172SS3* 03
244SS5* 02
99SS1* 03
112SS1* 02
330SS3* 02
132 SI* 05
152 S1# 06
3855-82-1
1146-65-2
15067-26-2
1517-22-2
1719-03-5
1520-96-3
4165-60-0
321-60-8
1718-51-0
4165-62-2
367-12-4
118-79-6
CI40 NAPHTHALENE-OS
CI50 ACENAPHTHENE-D10
CI60 PHENANTHRENE-D10
CI70 CHRYSENE-D12
CITS PERYLENE-D12
CS20 NITROBENZENE-DS
CS25 2-FLUOROBIPHENYL
CS30 TERPHENYL-D14
CS45 PHENOL-D5
CS50 2-FLUOROPHENOL
CS55 2,4,6-TRIBROHOPHENOL
CS70 2-CHLOROPHENOL-D4
CS75 1.2-DICHLOROBNZN-D4
HEXACHLOROBENZENE-C13
C310 N-NITROSOOIMETHYLAMINE 74 S1# 15 62-75-9
C320 ANILINE 93 S1#100 62-53-3
C315 PHENOL 94 S1*105CC 108-95-2
C325 BIS(2-CHLOROETHYL)ETHER 93 S1#110 111-44-4
C330 2-CHLOROPHENOL 128 S2#115 95-57-8
C335 1,3-DICHLOROBENZENE 146 S1#125 541-73-1
C340 1,4-DICHLOROBENZENE 146 S1#130CC 106-46-7
C345 BENZYL ALCOHOL 108 S1#145 100-51-6
C350 1,2-DICHLOROBENZENE 146 S1#150 95-50-1
C355 2-METHYLPHENOL 108 S1#160 95-48-7
C360 2,2'-OXYBIS(1-CLPROPAN> 45 S1#165 108-60-1
C365 4-METHYLPHENOL 108 S1#185 106-44-5
C370 N-NITROSO-DI-N-PROPYLAH 70 S1#190SP 621-64-7
C375 HEXACHLOROETHANE 117 S1«00 67-72-1
C410 NITROBENZENE 77 S2# 10 98-95-3
C415 ISOPHORONE 82 S2# 20 75-59-1
C420 2-NITROPHENOL 139 S2# 25CC 88-75-5
C425 2,4-DIMETHYLPHENOL 107 S2# 30 105-67-9
C435 BIS(2-CHLOROETHOXY)METH 93 S20 35 111-91-1
C440 2.4-DICHLOROPHENOL 162 S2# 40 120-83-2
C430 BENZOIC ACID 122 S2# 45 65-85-0
C445 1,2,4-TRICHLOROBENZENE 180 S2# 55 120-82-1
C450 NAPHTHALENE 128 S2# 60 91-20-3
C455 4-CHLOROANALINE 127 S2# 80 106-47-8
C460 HEXACHLOROBUTADIENE 225 S2# 95CC 87-68-3
C465 4-CHLORO-3-METHYLPHENO 107 S2#130CC 59-50-7
C470 2-METHYLNAPHTHALENE 142 S2#145 91-57-6
C510 HEXACHLOROCYCLOPENTADI 237 S3* 20 77-47-4
C515 2,4,6-TRICHLOROPHENOL 196 S3* 25CC 88-06-2
C520 2,4,5-TRICHLOROPHENOL 196 S3* 30 95-95-4
C525 2-CHLORONAPHTHALENE 162 S3* 40 91-58-7
C530 2-NITROANALINE 65 S3* 45 88-74-4
14S2
-------
No
48
49
50
No
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
Name
C535 DIMETHYLPHTHALATE 163 S3* 55
C540 ACENAPHTHYLENE 152 S3* 65
C543 2,6-DINITROTOLUENE 165 S3* 70
m/z
152
136
164
188
240
264
82
172
244
99
112
330
132
152
NOT
74
93
94
93
128
146
146
108
146
108
45
108
70
117
77
82
139
107
93
162
122
180
128
127
225
107
142
237
196
196
162
65
163
152
165
Scan
350
541
840
1099
1566
1797
433
734
1396
316
204
981
321
370
FOUND
109
310
318
324
324
341
352
378
372
400
399
426
420
418
436
477
484
507
521
527
552
535
545
564
572
659
663
692
719
724
745
773
817
814
823
Time
3:54
6:01
9:21
12:13
17:25
19:59
4:49
8:10
15:32
3:31
2:16
10:55
3:34
4:07
1:13
3:27
3:32
3:36
3:36
3:48
3:55
4:12
4:08
4:27
4:26
4:44
4:40
4:39
4:51
5:18
5:23
5:38
5:48
5:52
6:08
5:57
6:04
6:16
6:22
7:20
7:22
7:42
8:00
8:03
8:17
8:36
9:05
9:03
9:09
Ref
1
2
3
4
5
6
2
3
5
1
1
3
1
1
1
1
1
1
1
1
2
2
2
2
2
2
2
2
2
2
2
2
2
3
3
3
3
3
3
3
3
RRT
1.000
1.000
1.000
1.000
1.000
1.000
0.800
0.874
0.891
0.903
0.583
1.168
0.917
1.057
0.311
0.886
0.909
0.926
0.926
0.974
1.006
1.080
1.063
1.143
1.140
1.217
1.200
1.194
0.806
0.882
0.895
0.937
0.963
0.974
1.020
0.989
1.007
1.043
1.057
1.218
1.226
0.824
0.856
0.862
0.887
0.920
0.973
0.969
0.980
Meth
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
q<
A
A
A
A
A
q
A
A
A
BB
BB
BB
BV
W
BB
BB
BB
BB
BB
BB
BB
BB
BB
VB
BV
VB
VB
BB
BV
VB
BB
BB
BB
BB
BB
BV
BB
VB
BB
BB
BB
BV
BB
sdt£
BB
BB
BB •
BB
BB
edt{;
BB
BV
VB
BB
BB
BV
BB
BB
131-11-3
208-96-8
606-20-2
Area(Hght) Amount
31156.
114584.
63340.
109036.
77798.
63787.
67191 .
99214.
94942.
80179.
51862.
18938.
58440.
36852.
39558.
70664.
79234.
56008.
59290.
63015.
64864.
33967.
57718.
47563.
101138.
52789.
36545.
27750.
65237.
110794.
31214.
47890.
74000.
44945.
t) 39970.
-0 47850.
^ 148742.
is. 65035.
i 24296.
& 50489.
*JN 18484.
29806.
32070.
33958.
95618.
40406.
110200.
150122.
27004.
40.000
40.000
40.000
40.000
40.000
40.000
50.000
50.000
50.000
50.000
50.000
50.000
50.000
50.000
50.000
50.000
50.000
50.000
50.000
50.000
50.000
50.000
50.000
50.000
50.000
50.000
50.000
50.000
50.000
50.000
50.000
50.000
50.000
50.000
50.000
50.000
50.000
50.000
50.000
50.000
50.000
50.000
50.000
50.000
50.000
50.000
50.000
50.000
50.000
UG/HL
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/HL
UG/ML
UG/ML
UG/ML
UG/HL
UG/ML
UG/HL
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/HL
UG/HL
UG/HL
UG/ML
UG/HL
UG/HL
UG/ML
UG/ML
UG/ML
UG/HL
UG/HL
UG/HL
UG/HL
UG/HL
UG/ML
UG/HL
UG/HL
UG/ML
UG/ML
XTot
0.97
0.97
0.97
0.97
0.97
0.97
1.21
1.21
1.21
1.21
1.21
1.21
1.21
1.21
1.21
1.21
1.21
1.21
1.21
1.21
1.21
1.21
1.21
1.21
1.21
1.21
1.21
1.21
1.21
1.21
1.21
1.21
1.21
1.21
1.21
1.21
1.21
1.21
1.21
1.21
1.21
1.21
1.21
1.21
1.21
1.21
1.21
1.21
1.21
-------
;
I
>
r
i
>
j
1
>
j
i
5
5
7
8
9
0
1
2
3
4
5
A
,7
A
.9
50
Ret(L)
3:54
6:01
9:21
12:13
17:25
19:59
4:49
8:11
15:32
3:32
2:15
10:55
3:34
4:07
12:39
1:12
3:27
3:33
3:36
3:36
3:48
3:55
4:13
4:03
4:27
4:26
4:44
4:40
4:39
4:51
5:19
5:24
5:39
5:48
5:52
6:10
5:57
6:04
6:16
6:22
7:20
7:22
7:42
8:00
8:03
8:17
8:37
9:06
9:03
9:09
Ratio
1.00
1.00
1.00
.00
.00
.00
.00
.00
.00
.00
1.00
1.00
1.00
1.00
1.01
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
RRT(L)
1.000
1.000
1.000
1.000
1.000
1.000
0.800
0.875
0.891
0.906
0.580
1.168
0.917
1.057
0.941
0.309
0.886
0.911
0.926
0.926
0.974
.006
.083
.063
.143
.140
.217
.200
.194
0.806
0.884
0.896
0.939
0.965
0.974
1.024
0.989
1.007
1.043
1.057
1.220
1.226
0.824
0.856
0.862
0.887
0.921
0.974
0.969
0.980
Ratio
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.01
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1,00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
Aunt
40.00
40.00
40.00
40.00
40.00
40.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
Aimt(L)
40.00
40.00
40.00
40.00
40.00
40.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
R.Fac R
1.000
1.000
1.000
1.000
1.000
1.000
0.469
1.253
0.976
2.059
1.332
0.239
1.501
0.946
1.016
1.814
2.035
1.438
1.522
1.618
1.666
0.872
1.482
1.221
2.597
1.355
0.938
0.713
0.455
0.774
0.218
0.334
0.517
0.314
0.279
0.334
1.038
0.454
0.170
0.353
0.827
0.376
0.405
0.429
1.208
0.510
1.392
1.896
0.341
.Fac(L)
1.000
1.000
1.000
1.000
1.000
1.000
0.469
1.253
0.976
2.059
1.332
0.239
1.501
0.946
1.016
1.814
2.035
1.438
1.522
1.618
1.666
0.872
1.482
1.221
2.597
1.355
0.938
0.713
0.455
0.774
0.218
0.334
0.517
0.314
0.279
0.334
1.038
0.454
0.170
0.353
0.827
0.376
0.405
0.429
1.208
0.510
1.392
1.896
0.341
Ratio
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
14£4
-------
uantitation Report File: ST16980827C
ata: ST16980827C.TI
8/27/98 10:51:00
ample: SSTD050 50UG/ML CALI IV 070698F
:onds.: INST. ID: F16
ormula: 1UL INJ. Instrument: F16
Submitted by: QES Analyst: DAT
y«3UNT=AREA * REF AMNT/(REF AREA * RESP FACT)
*esp. fac. from Library Entry
No
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
69
70
71
72
73
74
75
76
77
78
79
80
81
82
83
84
85
No
51
52
53
54
55
56
57
58
Name
C545
C550
C555
C565
C560
C570
C580
C590
C585
C595
C610
C615
C620
C625
C630
C635
C640
C645
C647
C650
C655
C710
C715
C720
C730
C725
C740
C745
C760
C765
C770
C775
C780
C785
C790
m/z
138
153
184
168
109
165
149
166
3-NITROANILINE
ACENAPHTHENE
2,4-OINITROPHENOL
DIBENZOFURAN
4-NITROPHENOL
2,4-OINITROTOLUENE
D1ETHYLPHTHALATE
FLUORENE
4-CHLOROPHENYL-PHENYLE
4-NITROANALINE
4.6-DINITRO-2-METHYLPH
N-NITROSOOIPHENYLANINE
AZOBENZENE
4-BROMOPHENYL-PHENYLET
HEXACHLOROBENZENE
PENTACHLOROPHENOL
PHENANTHRENE
ANTHRACENE
CARBAZOLE
Pl-N-BUTYLPHTHALATE
FLUORANTHENE
BENZIOINE
PYRENE
BUTYLBENZYLPHTHALATE
BENZO(A)ANTHRACENE
3,3' -DICHLOROBENZIDINE
CHRYSENE
BtS(2-ETHYLHEXYL)PHTHA
DI-N-OCTYL PHTHALATE
BEHZO(B) FLUORANTHENE
BENZO(IC)FLUORANTHENE
BENZO(A)PYRENE
1NDENO(1,2,3-CO)PYRENE
D1BENZ(A,H}ANTHRACENE
BENZO(G,H,nPERYLENE
Scan Time Ref RRT
847 9:25 3 1.008
846 9:25 3 1.007
867 9:39 3 1.032
878 9:46 3 1.045
896 9:58 3 1.067
891 9:55 3 1.061
945 10:31 3 1.125
938 10:26 3 1.117
138 S3* 75
153 S3* 80CC
184 S3* 85SP
168 S3* 90
109 S3* 95SP
165 S3*105
149 S3*130
166 S3*135
204 S3*140
138 S3#150
198 S4* 10
169 S4* 15CC
77 S4* 20
248 S4# 30
284 S4* 40
266 S4* 50
178 S4# 65
178 S4* 70
167 S4* 80
149 S4* 85
202 S4*110CC
184 SS* 10
202 S5* 15
149 S5* 40
228 SS* 50
252 S5* 55
228 S5* 60
149 SS* 65
149 S6* 10CC
252 S6* 15
252 S6* 25
252 S6* 35
276 S6* 55
278 S6* 60
276 S6* 65
Neth Area(Hght)
A BV 31064.
A BB 93562.
A BB 15019.
A BB 137484.
A BB 14092.
A BB 33286.
A BB 114985.
A BV 106082.
Weight: 0.000
Acct. No.: FIN
99-09-2
83-32-9
51-28-5
132-64-9
100-02-7
121-14-2
84-66-2
86-73-7
7005-72-3
100-01-6
534-52-1
87-30-6
103-33-3
101-55-3
118-74-1
87-86-5
85-01-8
120-12-7
86-74-8
84-74-2
206-44-0
92-81-5
129-00-0
85-68-7
56-55-3
91-94-1
218-01-9
117-81-7
117-84-0
205-99-2
207-08-9
50-32-8
193-39-5
53-70-3
191-24-2
Amount
50.000 UC/ML
50.000 UG/ML
50.000 UG/ML
50.000 UG/ML
50.000 UG/ML
50.000 UG/ML
50.000 UG/ML
50.000 UG/ML
XTot
1.21
1.21
1.21
1.21
1.21
1.21
1.21
1.21
I4SC
-------
CO
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o o o o o
o o o o o
O O O O O li.
o o o
o o o o o
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•
«- »- o «-
«- o «- o •-
ooooooooooooooo
o
isi
oooooooooo
«-o«-oo»-»-oooo»-ooo»-
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• • • ^ooooooooooooooooooooooooooo
S.OOO -JOOOOOOOOOOOOOOOOOOOOOOOOOOO
o o o i
ooooooooooooooooooooo
minininminininminminminininminininminininminin
mm>^oammmmm>>maim>m>>m> c
ooooooooooooooooooooooooooo
ooooooooooooooooooooooooooo
ooooooooooooooooooooooooooo
ininininmininininmiAininiAtnintrttrtmtninmintnininm
• •••••_?• •' "OOOOOOOOOOOOOOOOOOOOOOOOOOO
»-»-OOOOOO«-^-«-«-«-OOOO«-»-»-OOOO«-«-«- VOOOOOOOOOOOOOOOOOOOOOOOOOOO
CQ*k««i.**i««.**i.ii*ii».»i*«
t- o o
Z~r
s
o>
«§§§888888888888§§§§g8ggg§gg
«•••••••• ••••••»••....,
rsj«-T-»-
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S- U
CM ae
-------
Ho RetCL) Ratio RRT(L) Ratio Amnt Amnt(L) R.Fac R.Fac(L) Ratio
78
79
80
81
82
83
84
85
17:58
19:13
19:23
19:26
19:54
21:38
21:43
21:59
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.032
0.961
0.969
0.972
0.996
1.082
1.086
1.100
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
50
50
50
50
50
50
50
50
.00
.00
.00
.00
.00
.00
.00
.00
50
50
50
50
50
50
50
50
.00
.00
.00
.00
.00
.00
.00
.00
0.986
1.985
1.448
1.171
1.206
1.312
1.288
1.356
0.986
1.985
1.448
1.171
1.206
1.312
1.286
1.356
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
. n ouutc*
(. PEAK NOT FOUND
2- POORCHROMATOGRAPh,
3. WRCiNG 1SOMER
•ML MANUAL EDITS MUST BZ
"••'.?D. DATED, AND CCr.-
1437
-------
100.0-1
RIC+MASS CHROMATOGRAM DATA. ST16980827C #1 SCANS 510 TO 575
08x27/98 10«51s00 CALIs ST16980827C #3
SAMPLE: SSTD050 50UGXML CALI IU 070698F
LABEL: N 0,2.0 QUAN. A 6, 2.0 J 0 BASE: 20, 3
122
RIC
3040.
122.037
± 8.500
148224.
SCAN
TIME
CO
en
-------
3WI1
90S'0
zwzn
•09868
00S'0
280 V0T
•2TS9I
'0s n .'3sya 0 r 0-2 '9
L0'08I
689 01 0S9 SNyDS
8« 0/280869 I IS
I* D/ 38 08 69 1 IS
J8690/0 ni
9ld »QI '1SNI «'SONOO
iw/ones 0200155 !3idwys
00«I9«0T 86//Z/80
SM^901W02IH3 SSUW
-------
DATA FROM FILE: ST16980827 SCANS 230 TO 1200 ACQUIRED: 08/27/98 9:22:00
CALI: ST16980827 #3
SAMPLE: SSTD080 80UG/ML CALI III 082198A
CONDS.: INST. ID: F16
800 _
8:54
1000 _
11(07
I
I
J
100.02 ( 226816.)
99SS1* 03
4165-62-2
82SS2M 02
136IS2* 01
=_CS25 2-FLUOROBIPHENYL
164IS3* 01
330SS3« 02
188IS4* 01
4165-60-0
1146-65-2
172SS3* 03
15067-26-2
118-79-6
1517-22-2
321-60-8
01
O
O
-------
DATA FROM FILE: ST16980827 SCANS 1200 TO 2158 ACQUIREDi 08/27/98 9i22;00
CALI: ST16980827 #3
SAMPLE: SSTD080 80UG/ML CALI III 082198A
CONDS.: INST. ID: F16
1200
1400 .
15:34
I
J 100.0Z < 137216.)
CS30 TERPHENYL-D14
244SS5* 02
1718-51-0
1600 _
17:48
1800 .
20:01
2000 .
22:15
CHRYSENE-D12
164IS6* 01
240IS5* 01
1520-96-3
1719-03-5
M
cn
o
-------
ntitation Report File: ST16980827
a: ST16980827.TI
27/98 9:22:00
pie: SST0080 80UG/ML CALI III 082198A
ds.: INST. ID: F16
nula: 1UL INJ.
mitted by: QES
Instrument: F16
Analyst: DAT
*JNT=AREA * REF AMNT/CREF AREA * RESP FACT)
ip. fac. from Library Entry
> Name
Weight: 0.000
Acct. No.: FIN
I
)
5
»
5
<,
r
5
9
3
1
2
3
t>
5
6
7
8
9
0
;1
2
3
%
>5
!6
27
28
29
50
51
52
53
34
35
36
37
38
39
40
41
42
43
44
45
46
47
CI30
CI40
CI50
CI60
CI70
CITS
CS20
CS25
CS30
CS45
CS50
CS55
CS70
CS75
1 .4-DICHLOROBENZENE-D4
NAPHTHALENE-OS
ACENAPHTHENE-D10
PHENANTHRENE-D10
CHRYSENE-D12
PERYLENE-D12
NITROBENZENE-DS
2-FLUOROBIPHENYL
TERPHENYL-D14
PHENOL-OS
2-FLUOROPHENOL
1521S1* 01
136IS2* 01
164IS3* 01
188IS4* 01
240IS5* 01
164IS6* 01
82SS2* 02
172SS3* 03
244SS5* 02
99SS1# 03
112SS1* 02
2,4,6-TRIBRCMOPHENOL 330SS3* 02
2-CNLOROPNENOL-D4
1.2-DICHLOROBNZN-D4
132
152
S1# 05
S1# 06
3855-82-1
1146-65-2
15067-26-2
1517-22-2
1719-03-5
1520-96-3
4165-60-0
321-60-8
1718-51-0
4165-62-2
367-12-4
118-79-6
HEXACHLOROBENZENE - C1 3
C310
C320
C315
C325
C330
C335
C340
C345
C350
C355
C360
C365
C370
C375
C410
C415
C420
C425
C435
C440
C430
C445
C450
C455
C460
C465
C470
C510
C515
C520
C525
C530
N-NITROSODINETHYLAMINE
ANILINE
PHENOL
BIS(2-CHLOROETHYL)ETHER
2-CHLOROPHENOL
1,3-DICHLOROSENZENE
1,4-DICHLOROBENZENE
BENZYL ALCOHOL
1,2-DICHLOROBENZENE
2-METHYLPHENOL
2,2'-OXYBIS(1-CLPROPAN)
4-METHYLPHENOL
N - N I TROSO-D I - N - PROPYLAM
HEXACHLOROETHANE
NITROBENZENE
ISOPHORONE
2-NITROPHENOL
2,4-DIMETHYLPHENOL
BIS(2-CHLOROETHOXY)HETH
2,4-DICHLOROPHENOL
BENZOIC ACID
1 ,2,4-TRICHLOROBENZENE
NAPHTHALENE
4-CHLOROANALINE
HEXACHLOROBUTAD I ENE
4-CHLORO-3-METHYLPHENO
2-METHYLNAPHTHALENE
HEXACHLOROCYCLOPENTAD I
2,4,6-TRICHLOROPHENOL
2,4,5-TRICHLOROPHENOL
2-CHLORONAPHTHALENE
2-NITROANALINE
74 S1# 15
93
94
93
128
146
146
108
146
108
45
108
70
117
77
82
139
107
93
162
122
180
128
127
225
107
142
237
196
196
162
65
S1#100
S1#105CC
81*110
S20115
S1#125
S10130CC
S1#145
S1#150
S1#160
S1#165
S1#185
S1#190SP
S1#200
S2# 10
S2# 20
S2# 25CC
S2# 30
S2# 35
S2# 40
S2# 45
S2# 55
S2# 60
?2#80
S2# 95CC
S2#130CC
S2#U5
S3* 20
S3* 25CC
S3* 30
S3* 40
S3* 45
62-75-9
62-53-3
108-95-2
111-44-4
95-57-8
541-73-1
106-46-7
100-51-6
95-50-1
95-48-7
108-60-1
106-44-5
621-64-7
67-72-1
98-95-3
75-59-1
88-75-5
105-67-9
111-91-1
120-83-2
65-85-0
120-82-1
91-20-3
106-47-8
87-68-3
59-50-7
91-57-6
77-47-4
88-06-2
95-95-4
91-58-7
88-74-4
-------
No
48
49
50
No
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
Name
C535
C540
C543
fll/2
152
136
164
188
240
264
82
172
244
99
112
330
132
152
NOT
74
93
94
93
128
146
146
108
146
108
45
108
70
117
77
82
139
107
93
162
122
180
128
127
225
107
142
237
196
196
162
65
163
152
165
DIMETHYLPHTHALATE 163 S3* 55
ACENAPHTHYLENE 152 S3* 65
2,6-DINITROTOLUENE 165 S3* 70
Scan Time Ref RRT Meth Area(Hght)
350
541
840
1099
1566
1797
433
735
1396
317
203
981
321
370
FOUND
108
310
319
324
324
341
352
379
372
400
399
426
420
418
436
478
485
508
522
527
554
535
545
564
572
660
663
692
719
724
745
774
818
814
823
3:54
6:01
9:21
12:13
17:25
19:59
4:49
8:11
15:32
3:32
2:15
10:55
3:34
4:07
1:12
3:27
3:33
3:36
3:36
3:48
3:55
4:13
4:08
4:27
4:26
4:44
4:40
4:39
4:51
5:19
5:24
5:39
5:48
5:52
6:10
5:57
6:04
6:16
6:22
7:20
7:22
7:42
8:00
8:03
8:17
8:37
9:06
9:03
9:09
1
2
3
4
5
6
2
3
5
1
1
3
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
2
2
2
2
2
2
2
2
2
2
2
2
2
3
3
3
3
3
3
3
3
1.000
1.000
1.000
1.000
1.000
1.000
0.800
0.875
0.891
0.906
0.580
1.168
0.917
1.057
0.309
0.886
0.911
0.926
0.926
0.974
1.006
1.083
1.063
1.143
1.140
1.217
1.200
1.194
0.806
0.884
0.896
0.939
0.965
0.974
1.024
0.989
1.007
1.043
1.057
1.220
1.226
0.824
0.856
0.862
0.887
0.921
0.974
0.969
0.980
A BB
A BB
A BB
A BB
A BB
A BB
A VB
A BV
A BB
A BB
A BB
A BB
A BV
A BB
A BB
A BV
A VB
A VB
A BB
A BV
A VB
A BB
A BB
A BB
A BB
A BB
A BV
A BB
A VB
A BB
A VB
A BB
A BV
A BB
qedt(l)
A BB 9s
ABB*
ABB^
A BB
* BB A
qedt@
A BB
A BV
A VB
A BB
A BB
A BV
A BB
A BB
25488.
88640.
47354.
80196.
51312.
44290.
89306.
123006.
111089.
104277.
73823.
22048.
76599.
48888.
55404.
95626.
109518.
72104.
81692.
84592.
86508.
46538.
80185.
61644.
131645.
65587.
47937.
36710.
86151.
137948.
41152.
70834.
95388.
58887.
47914.
62130.
195384.
85089.
31304.
64626.
134249.
40564.
41178.
41938.
121530.
49570.
135082.
193878.
33232.
131-11-3
208-96-8
606-20-2
Amount XTot
40.000 UG/ML 0.62
40.000 UG/ML 0.62
40.000 UG/ML 0.62
40.000 UG/ML 0.62
40.000 UG/ML 0.62
40.000 UG/ML 0.62
80.000 UG/ML
80.000 UG/ML
80.000 UG/ML
80.000 UG/ML
80.000 UG/ML
80.000 UG/ML
80.000 UG/ML
80.000 UG/ML
80.000 UG/ML
80.000 UG/ML
80.000 UG/ML
80.000 UG/ML
80.000 UG/ML
80.000 UG/ML
80.000 UG/ML
80.000 UG/ML
80.000 UG/ML
80.000 UG/ML
80.000 UG/ML
80.000 UG/ML
.23
.23
.23
.23
.23
.23
.23
.23
.23
.23
.23
.23
.23
.23
.23
.23
.23
.23
.23
.23
80.000 UG/ML 1.23
80.000 UG/ML 1.23
80.000 UG/ML 1.23
80.000 UG/ML 1.23
80.000 UG/ML 1.23
80.000 UG/ML 1.23
80.000 UG/ML 1.23
80.000 UG/ML 1.23
80.000 UG/ML 1.23
80.000 UG/ML 1.23
80.000 UG/ML 1.23
80.000 UG/ML 1.23
80.000 UG/ML 1.23
80.000 UG/ML 1.23
80.000 UG/ML 1.23
80.000 UG/ML 1.23
80.000 UG/ML 1.23
80.000 UG/ML 1.23
80.000 UG/ML 1.23
80.000 UG/ML 1.23
80.000 UG/ML 1.23
80.000 UG/ML 1.23
80.000 UC/NL 1.23
-------
S
1
2
5
;
5
6
7
8
9
0
1
2
3
4
5
6
7
8
9
0
.1
2
3
4
5
6
:7
:s
:9
10
11
,2
i3
14
15
(6
i7
J8
!9
;o
,1
V2
'.3
14
V5
i6
17
18
49
50
RetU)
3:54
6:01
9:21
12:13
17:25
19:59
4:49
8:11
15:32
3:32
2:15
10:55
3:34
4:07
12:39
1:12
3:27
3:33
3:36
3:36
3:48
3:55
4:13
4:08
4:27
4:26
4:44
4:40
4:39
4:51
5:19
5:24
5:39
5:48
5:52
6:10
5:57
6:04
6:16
6:22
7:20
7:22
7:42
8:00
8:03
8:17
8:37
9:06
9:03
9:09
Ratio
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
RRT(L)
1.000
1.000
1.000
1.000
1.000
1.000
0.800
0.875
0.891
0.906
0.580
1.168
0.917
1.057
0.941
0.309
0.886
0.911
0.926
0.926
0.974
1.006
1.083
1.063
1.143
1.140
1.217
1.200
1.194
0.806
0.884
0.896
0.939
0.965
0.974
1.024
0.989
1.007
1.043
1.057
1.220
1.226
0.824
0.856
0.862
0.887
0.921
0.974
0.969
0.980
Ratio
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
Anrt
40.00
40.00
40.00
40.00
40.00
40.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
Arrnt(L)
40.00
40.00
40.00
40.00
40.00
40.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
R.Fac R.
1.000
1.000
1.000
1.000
1.000
1.000
0.504
1.299
1.082
2.046
1.448
0.233
1.503
0.959
1.087
1.876
2.148
1.414
1.603
1.659
1.697
0.913
1.573
1.209
2.582
1.287
0.940
0.720
0.486
0.778
0.232
0.400
0.538
0.332
0.270
0.350
1.102
0.480
0.177
0.365
0.757
0.428
0.435
0.443
1.283
0.523
1.426
2.047
0.351
Fae(L)
1.000
1.000
1.000
.000
.000
.000
0.504
.299
.082
2.046
1.448
0.233
1.503
0.959
1.087
1.876
2.148
1.414
1.603
1.659
1.697
0.913
1.573
1.209
2.582
1.287
0.940
0.720
0.486
0.778
0.232
0.400
0.538
0.332
0.270
0.350
1.102
0.480
0.177
0.365
0.757
0.428
0.435
0.443
1.283
0.523
1.426
2.047
0.351
Ratio
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00-
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
-------
Ouantitation Report File: ST16980827
Data: ST16980827.TI
08/27/98 9:22:00
Sample: SSTD080 80UG/ML CALI III 082198A
Conds.: INST. ID: F16
Formula: 1UL INJ. Instrument: F16
Submitted by: OES Analyst: DAT
AMOUNT=AREA * REF AMNT/(REF AREA * RESP FACT)
Resp. fac. from Library Entry
No Name
51 C545 3-NITROANILINE 138 S3* 75
52 C550 ACENAPHTHENE 153 S3* 80CC
53 C555 2.4-DINITROPHENOL 184 S3* 85SP
54 C565 DIBENZOFURAN 168 S3* 90
55 C560 4-NITROPHENOL 109 S3# 95SP
56 C570 2,4-DINITROTOLUENE 165 53*105
57 C580 DIETHYLPHTHALATE 149 53*130
58 C590 FLUORENE 166 53*135
59 C585 4-CHLOROPHENYL-PHENYLE 204 S3*140
60 C595 4-NITROANALINE 138 53*150
61 C610 4.6-DINITRO-2-METHYLPH 198 S4# 10
62 C615 N-NITROSOOIPHENYLAMINE 169 S4* 15CC
63 C620 AZOBENZENE 77 54* 20
64 C625 4-BROMOPHENYL-PHENYLET 248 S4* 30
65 C630 HEXACHLOROBENZENE 284 54* 40
66 C635 PENTACHLOROPHENOL 266 54* 50
67 C640 PHENANTHRENE 178 S4# 65
68 C645 ANTHRACENE 178 S4* 70
69 C647 CARBAZOLE 167 S4* 80
70 C650 DI-N-BUTYLPHTHALATE 149 S4* 85
71 C655 FLUORANTHENE 202 54*1 10CC
72 C710 BENZIDINE 184 S5* 10
73 C715 PYRENE 202 S5* 15
74 C720 BUTYLBENZYLPHTHALATE 149 55* 40
75 C730 BENZO( A) ANTHRACENE 228 55* 50
76 C725 3,3<-DICHLOROBENZIDINE 252 55* 55
77 C740 CHRYSENE 228 55* 60
78 C745 BISC2-ETHYLHEXYDPHTHA 149 S5* 65
79 C760 DI-N-OCTYL PHTHALATE 149 S6# 10CC
80 C765 BENZO(B) FLUORANTHENE 252 S6* 15
81 C770 BENZO(K)FLUORANTHENE 252 S6* 25
82 C775 BENZO(A)PYRENE 252 S6* 35
83 C780 INDENO(1,2,3-CD)PYRENE 276 S6* 55
84 C785 DIBENZ(A,H)ANTHRACENE 278 S6* 60
85 C790 BENZO(G,H,I)PERYLENE 276 S6# 65
Weight:
0.000
Acct. No.: FIN
99-09-2
83-32-9
51-28-5
132-64-9
100-02-7
121-14-2
84-66-2
86-73-7
7005-72-3
100-01-6
534-52-1
87-30-6
103-33-3
101-55-3
118-74-1
87-86-5
85-01-8
120-12-7
86-74-8
84-74-2
206-44-0
92-81-5
129-00-0
85-68-7
56-55-3
91-94-1
218-01-9
117-81-7
117-84-0
205-99-2
207-08-9
50-32-8
193-39-5
53-70-3
191-24-2
No m/z Scan Time Ref RRT Meth Area(Hght) Amount
51 138 848 9:26 3 1.010 A BB 36135.
52 153 846 9:25 3 1.007 A BB 119458.
53 184 867 9:39 3 1.032 A BB 19158.
54 168 878 9:46 3 1.045 A BB 166910.
55 109 897 9:59 3 1.068 A BB 17386.
56 165 891 9:55 3 1.061 A BB 41432.
57 149 946 10:31 3 1.126 A BB 138464.
58 166 938 10:26 3 1.117 A BV 131258.
80.000
80.000
80.000
80.000
80.000
80.000
80.000
80.000
XTot
UG/ML 1.23
UG/ML 1.23
UG/ML 1.23
UG/ML 1 .23
UG/ML 1.23
UG/ML 1.23
UG/ML 1.23
Ufi/M. 1-23
ISC 5
-------
lo
i9
•0
.1
.2
3
>4
»5
>6
>7
i8
59
•o
n
•2
•3
•4
•5
•6
•7
'8
•9
50
31
32
J3
34
35
40
51
52
53
54
55
56
57
58
59
50
61
62
63
64
65
66
67
68
69
70
71
72
73
74
75
76
77
m/z Scan
204 949
138 957
198 962
169 974
77 976
248 1033
284 1032
266 1074
178 1104
178 1112
167 1150
149 1239
202 1312
184 1353
202 1348
149 1500
228 1565
252 1575
228 1571
149 1616
149 1727
252 1742
252 1747
252 1789
276 1945
278 1952
276 1977
Time Ref
10:33 3
10:39 3
10:42 4
10:50
10
11
11
11
12
12
12
13
14
15
15
16
17
17
17
17
19
19
19
19
21
21
21
Ret(L) Ratio
9:26 1.
9:25 1.
9:39 1.
9:46 1.
9:59 1.
9:55 1.
10:31 1.
10:26 1.
10:33 1.
10:39 1.
10:42 1.
10:50 1.
10:51 1.
11:29 1.
11:29 .
11:57 .
00
00
00
00
00'
00
00
00
00
00
00
00
00
00
00
00
12:17 .00
12:22 .00
12:47 .00
13:47 .00
14:36 1.00
15:03 1.00
15:00 1.00
16:41 1.00
17:24 1.00
17:31 1.00
17:28 1.00
:51
:29
:29
:57
:17
:22
:47
:47
:36
:03
:00
:41
:24
:31
:28
:58
:13
:23
:26
:54
:38
:43
:59
4
4
4
4
4
4
4
4
4
4<
5
5
5
5
5
5
5
6
6
6
6
6
6
6
RRT
1.130
1.139
0.875
0.886
0.888
0.940
0.939
0.977
1.005
1.012
1.046
1.127
1.194
0.864
0.861
0.958
0.999
1.006
1.003
1.032
0.961
0.969
0.972
0.996
1.082
1.086
1.100
RRT(L) Ratio
1.010
1.007
1.032
1.045
1.068
1.061
1.126
1.117
1.130
1.139
0.875
0.886
0.888
0.940
0.939
0.977
1.005
1.012
1.046
1.127
1.194
0.864
0.861
0.958
0.999
1.006
1.003
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
1.00
1
1
1
.00
.00
.00
1.00
1
1
1
1
1
1
1
.00
.00
.00
.00
.00
.00
.00
Meth
K BB
A BB
A BB
A BV
A BB
A BB
A BB
A BB
A BV
A VB
A BB
A BB
A BB
A BB
A BB
A BB
A BV
A BB
A VB
A BB
A BB
A BV
A VB
A BV
A BV
A BV
A BB
Aunt
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
Area(Hght)
61220.
28966.
23256.
86506.
194334.
37192.
43018.
27210.
175815.
169868.
123401.
213776.
152339.
7938.
150637.
74136.
123435.
39292.
113108.
105344.
175103.
128697.
111928.
108866.
121168.
120479.
126303.
Amnt(L)
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
Amount
80.000
80.000
80.000
80.000
80.000
80.000
80.000
80.000
80.000
80.000
80.000
80.000
80.000
80.000
80.000
80.000
80.000
80.000
80.000
80.000
80.000
80.000
80.000
80.000
80.000
80.000
80.000
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/HL
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
R.Fac R.Fac(L)
0.382
1.261
0.202
1.762
0.184
0.437
1.462
1.386
0.646
0
0
0
1
.306
.145
.539
.212
0.232
0
0
1
1
0
1
0
0
1
0
1
0
1
.268
.170
.096
.059
.769
.333
.950
.077
.468
.722
.203
.383
.102
0.382
1.261
0.202
1.762
0.184
0.437
1.462
1.386
0.646
0.306
0.145
0.539
1.212
0.232
0.268
0.170
1.096
1.059
0.769
1.333
0.950
0.077
1.468
0.722
1.203
0.383
1.102
XTot
1.23
1.23
1.23
1.23
1.23
1.23
1.23
1.23
1.23
1.23
1.23
1.23
1.23
1.23
1.23
1.23
1.23
1.23
1.23
1.23
1.23
1.23
1.23
1.23
1.23
1.23
1.23
Ratio
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
-------
No
78
79
80
81
82
83
84
85
Ret(L)
17:58
19:13
19:23
19:26
19:54
21:38
21:43
21:59
Ratio
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
RRT(L)
1.032
0.961
0.969
0.972
0.996
1.082
1.086
1.100
Ratio
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
Amnt
80.
80.
80.
80.
80.
80.
80.
80.
00
00
00
00
00
00
00
00
Aimt(L)
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
R.Fac R.
1.027
1.977
1.453
1.264
1.229
1.368
1.360
1.426
Fac(L) Ratio
1
1
1
1
1
1
1
1
.027 1.00
.977
.453
.264
.229
.368
.360
.426
.00
.00
.00
.00
.00
.00
.00
iANUAL EDIT CODES
i. PEAK NOT FOUND
2.POORCHROMAT06RAPh»
AMD COH-
-------
100.0
RIC+MASS CHROMATOGRAM DATAi ST16980827 #1
08/27x98 9:22:00 CALI: ST16980827 #3
SAMPLE: SSTD080 80UG/tlL CALI III 082198A
COHDS.: IHST. ID: F16
RANGE: G 1,2158 LABEL: N 0, 2.0 QUAN: A 6, 2.0 J 0 BASE: U 20
554
SCANS 510 TO 580
122
RIC
3568.
122.037
± 0.508
572
-562. 566
o45
197888.
572
564
510
,5:40
r—
cr.
—I—
520
5:47
~T
530
5:54
—1
540
6:00
550
6:07
560
6:14
570
6:20
580 SCAN
6:27 TIME
-------
3WI1
NWS
'0
-8-001
Z0T
•T68S9
-rst-
e '03 n »3sya 0 r 0-3 '9 y m-wr\Q vz '<
689 01 099 SNWS
£# ^808S9T1S «nyO
T« zz89869us :yiwa
9Id IQI '1SNI
114x0008 089Q1SS
:'6 86/^3/80
-------
DATA FROM FILE: ST16980827D SCANS 230 TO 1200 ACQUIRED: 08x27/98 11:20:00
CALI: ST169808270 #3
SAMPLE: SSTD120 120UG/ML CALI II 070698H
COHDS.: INST. ID: F16
480 .
4:27
600 .
6:40
800 .
8:54
1000 .
11:07
ffflB -
FTTROBENZENE-D5
100.0Z < 348160.)
99SS1* 03
82SS2* 02
4165-62-2
4165-60-0
-136IS2* 01
1146-65-2
CS25 2-FLUOROBIPHENYL
172SS3* 03
15067-26-2
2. > H i b-1KI bIKUI'lUHHbNUL 3305S3# 02
118-79-6
188IS4* 81
1517-22-2
321-60-8
CT
M
O
-------
DATA FROM FILE* ST16980827D SCANS 1208 TO 2158 ACQUIRED: 08x27/98 11:20!00
CALI: ST169808270 «3
SAMPLE: SSTD120 120UG/ML CALI II 070698H
CONDS.: INST. ID: F16
1200
13:21
1400 .
15:34
1600 -V
17:48
1800
20:01
2000 4
22:15
J 100.02 < 209152.)
CS30 TERPHENYL-D14
244SS5* 02
1718-51-0
WE-D12
240IS5* 01
1719-03-5
164IS6# H
1520-96-3
-------
jantitation Report File: ST16980827D
ita: ST169808270.TI
5/27/98 11:20:00
ample: SSTD120 120UG/ML CALI II 070698H
Dnds.: INST. ID: F16
armula: 1UL INJ.
Jbmitted by: QES
Instrument: F16
Analyst: DAT
*JUNT=AREA * REF AMNT/CREF AREA » RESP FACT)
esp. fac. from Library Entry
Weight: 0.000
Acct. No.: FIN
Mo
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
Name
CI30 1.4-DICHLOROBENZENE-D4 152IS1* 01
CI40 NAPHTHALENE -D8 * 136IS2* 01
CI50 ACENAPHTHENE-D10 164IS3* 01
CI60 PHENANTHRENE-D10 188184* 01
CI70 CHRYSENE-D12 240IS5* 01
CITS PERYLENE-D12 164IS6* 01
CS20 NITROBENZENE-DS 82SS2* 02
CS25 2-FLUOROBIPHENYL 172SS3* 03
CS30 TERPHENYL-D14 .244SS5* 02
CS45 PHENOL-D5 99SS1* 03
CS50 2-FLUOROPHENOL 112SS1# 02
CS55 2,4,6-TRIBROMOPHENOL 330SS3* 02
CS70 2-CHLOROPHENOL-D4 132 S1# 05
CS75 1.2-DICHLOROBNZN-D4 152 S1# 06
HEXACHLOROBENZENE-C13
C310 N-NITROSOOIMETHYLAMINE 74. S1# 15
C320 ANILINE 93 S14MOO
C315 PHENOL 94 S1#105CC
C325 BIS(2-CHLOROETHYL)ETHER 93 S1#110
C330 2-CHLOROPHENOL 128 S2#115
C335 1,3-DICHLOROBENZENE 146 51*125
C340 1,4-DICHLOROBENZENE 146 S1HM30CC
C345 BENZYL ALCOHOL 108 S14M45
C350 1,2-OICHLOROBENZENE 146 S1#150
C355 2-METHYLPHENOL 108 S1#160
C360 2,2'-OXYBIS(1-CLPROPAN) 45 81*165
C365 4-METHYLPHENOL 108 S1#185
C370 N-NITROSO-DI-N-PROPYLAM 70 S1#190SP
C375 HEXACHLOROETHANE 117 S10200
C410 NITROBENZENE 77 S2# 10
C41S ISOPHORONE 82 S2# 20
C420 2-NITROPHENOL 139 S2# 25CC
C425 2,4-DIMETHYLPHENOL 107 S2# 30
C435 BIS<2-CHLOROETHOXY)METH 93 S2# 35
C440 2,4-DICHLOROPHENOL 162 S2# 40
C430 BENZOIC ACID 122 S2# 45
C445 1,2,4-TRICHLOROBENZENE 180 S2# 55
C450 NAPHTHALENE 128 S2# 60
C455 4-CHLOROANALINE 127 S2# 80
C460 HEXACHLOROBUTADIENE 225 S2# 95CC
C465 4-CHLORO-3-METHYLPHENO 107 S2#130CC
C470 2-METHYLNAPHTHALENE 142 S2#145
C510 HEXACHLOROCYCLOPENTADI 237 S3# 20
C515 2,4,6-TRICHLOROPHENOL 196 S3# 25CC
C520 2,4,5-TRICHLOROPHENOL 196 S3* 30
C525 2-CHLORONAPHTHALENE 162 S3# 40
C530 2-NITROANALINE 65 S3# 45
3855-82-1
1146-65-2
15067-26-2
1517-22-2
1719-03-5
1520-96-3
4165-60-0
321-60-8
1718-51-0
4165-62-2
367-12-4
118-79-6
62-75-9
62-53-3
108-95-2
111-44-4
95-57-8
541-73-1
106-46-7
100-51-6
95-50-1
95-48-7
108-60-1
106-44-5
621-64-7
67-72-1
98-95-3
75-59-1
88-75-5
105-67-9
111-91-1
120-83-2
65-85-0
120-82-1
91-20-3
106-47-8
87-68-3
59-50-7
91-57-6
77-47-4
88-06-2
95-95-4
91-58-7
88-74-4
-------
No
48
49
50
NO
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
Name
C535
C540
C543
m/z
152
136
164
188
240
264
82
172
244
99
112
330
132
152
NOT
74
93
94
93
128
146
146
108
146
108
45
108
70
117
77
82
139
107
93
162
122
180
128
127
225
107
142
237
196
196
162
65
163
152
165
DIMETHYLPHTHALATE 163 S3*
ACENAPHTHYLENE 152 S3*
2,6-OINITROTOLUENE 165 S3*
Scan
351
542
841
1100
1567
1798
435
736
1397
319
204
983
323
371
FOUND
109
312
321
326
325
342
353
381
373
402
400
429
423
419
438
481
486
510
523
529
564
537
546
567
572
661
664
693
720
726
747
775
820
815
825
Time
3:54
6:02
9:21
12:14
17:26
20:00
4:50
8:11
15:32
3:33
2:16
10:56
3:36
4:08
1:13
3:28
3:34
3:38
3:37
3:48
3:56
4:14
4:09
4:28
4:27
4:46
4:42
4:40
4:52
5:21
5:24
5:40
5:49
5:53
6:16
5:58
6:04
6:18
6:22
7:21
7:23
7:42
8:01
8:05
8:19
8:37
9:07
9:04
9:11
Ref
1
2
3
4
5
6
2
3
5
1
1
3
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
2
2
2
2
2
2
2
2
2
2
2
2
2
3
3
3
3
3
3
3
3
RRT
.000
.000
.000
.000
.000
.000
0.803
0.875
0.892
0.909
0.581
1.169
0.920
1.057
0.311
0.889
0.915
0.929
0.926
0.974
1.006
1.085
1.063
1.145
1.140
1.222
1.205
1.194
0.808
0.887
0.897
0.941
0.965
0.976
1.041
0.991
1.007
1.046
1.055
1.220
1.225
0.824
0.856
0.863
0.888
0.922
0.975
0.969
0.981
Meth
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
q«
A
A
A
A
A
q
A
A
A
A
A
A
A
A
BB
BB
BB
BB
BB
BB
BB
BB
VB
BB
BB
BB
BB
BB
VB
BV
VB
VB
BB
BV
VB
BB
BB
BB
BB
BB
BV
BB
VB
BB
BB
BB
BB
BB
fdtg
BB ^
BB %
BB *
BB "
BB
«K@
BB
BV
VB
BB
BB
BB
BB
BB
55
65
70
131-11-3
208-96-8
606-20-2
Area(Hght) Amount
28868.
109146.
62260.
102618.
60424.
49906.
148159.
218708.
173968.
172744.
119161.
42668.
124435.
78148.
87333.
154018.
165127.
111846.
125615.
133856.
134148.
74988.
125957.
103881.
216653.
113933.
79097.
61106.
137055.
237871.
71784.
114342.
164456.
101851.
) 91808.
a 105480.
; 314427.
s 146940.
£ 54706.
£113771.
)\219628.
70772.
77913.
74944.
210616.
90989.
242196.
318836.
59941,
40.000
40.000
40.000
40.000
40.000
40.000
120.000
120.000
120.000
120.000
120.000
120.000
120.000
120.000
120.000
120.000
120.000
120.000
120.000
120.000
120.000
120.000
120.000
120.000
120.000
120.000
120.000
120.000
120.000
120.000
120.000
120.000
120.000
120.000
120.000
120.000
120.000
120.000
120.000
120.000
120.000
120.000
120.000
120.000
120.000
120.000
120.000
120.000
17P ftQT
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML -
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
XTot
0.42
0.42
0.42
0.42
0.42
0.42
1.25
1.25
1.25
1.25
1.25
1.25
1.25
1.25
1.25
1.25
1.25
1.25
1.25
1.25
1.25
1.25
1.25
1.25
1.25
1.25
1.25
1.25
1.25
1.25
1.25
1.25
1.25
1.25
1.25
1.25
1.25
1.25
1.25
1.25
1.25
1.25
1.25
1.25
1.25
1.25
1.25
1.25
1.25
-------
No
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
Ret(L) Ratio
3:54
6:01
9:21
12:13
17:25
19:59
4:49
8:11
15:32
3:32
2:15
10:55
3:34
4:07
12:39
1:12
3:27
3:33
3:36
3:36
3:48
3:55
4:13
.00
.00
.00
.00
.00
.00
.00
.00
.00
.01
.00
.00
.01
.00
.01
.01
.01
.01
.00
.00
.00
.01
4:08 1.00
4:27 1.01
4:26 1.00
4:44 .01
4:40 .01
4:39 .00
4:51 .00
5:19 .01
5:24 .00
5:39 .00
5:48 .00
5:52 1.00
6:10 1.02
5:57 1.00
6:04 1.00
6:16 1.01
6:22 1.00
7:20 1.00
7:22 1.00
7:42 1.00
8:00 1.00
8:03 1.00
8:17 1.00
8:37 1.00
9:06 1.00
9:03 1.00
9:09 1.00
RRT(L)
1.000
1.000
1.000
1.000
1.000
1.000
0.800
0.875
0.891
0.906
0.580
1.168
0.917
1.057
0.941
0.309
0.886
0.911
0.926
0.926
0.974
1.006
.083
.063
.143
.140
.217
1.200
1.194
0.806
0.884
0.896
0.939
0.965
0.974
1.024
0.989
1.007
1.043
1.057
1.220
1.226
0.824
0.856
0.862
0.887
0.921
0.974
0.969
0.980
Ratio
.00
.00
.00
.00
.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
.01
.00
.00
.00
.00
.00
.00
.00
.00
.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.02
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
Amnt
40
40
40
40
.00
.00
.00
.00
40.00
40
120
120
120
120
120
120
120
120
120
120
120
120
120
120
120
120
120
120
120
120
120
120
120
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
120 JOO
120
120
120
120
120
120
120
120
120
120
120
120
120
120
120
120
120
120
120
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
Amnt(L)
40
40
40
40
40
40
120
120
120
120
120
120
120
120
120
120
120
120
120
120
120
120
120
120
120
120
120
120
120
120
120
120
120
120
120
120
120
120
120
120
120
120
120
120
120
120
120
120
120
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
R.Fac R.
1.000
1.000
1.000
1.000
1.000
1.000
0.452
1.171
0.960
1.995
1.376
0.228
1.437
0.902
1.008
1.778
1.907
1.291
1.450
1.546
1.549
0.866
1.454
1.199
2.502
1.316
0.913
0.706
0.419
0.726
0.219
0.349
0.502
0.311
0.280
0.322
0.960
0.449
0.167
0.347
0.671
0.379
0.417
0.401
1.128
0.487
1.297
1.707
0.321
Fac(L) Ratio
1.000
1.000
1.000
1.000
1.000
1.000
0.452
1.171
0.960
1.995
1.376
0.228
1.437
0.902
.008
.778
.907
.291
.450
.546
.549
0.866
1.454
1.199
2.502
1.316
0.913
0.706
0.419
0.726
0.219
0.349
0.502
0.311
0.280
0.322
0.960
0.449
0.167
0.347
0.671
0.379
0.417
0.401
1.128
0.487
1.297
1.707
0.321
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
.00
.00
.00
.00
.00
.00
.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1514
-------
Quantitat ion Report File: ST16980827D
Data: ST16980827D.TI
08/27/98 11:20:00
Sample: SSTD120 120UG/HL CALI
Conds.: INST. ID: F16
II 070698H
Formula: 1UL INJ. Instrument: F16
Submitted by: QES Analyst: DAT
AMOUNT=AREA * REF AHNT/(REF AREA * RESP FACT)
Resp. fac. from Library Entry
No Name
51 C545 3-MITROANILINE 138 S3* 75
52 C550 ACENAPHTHENE 153 S3* 80CC
53 C555 2,4-DINITROPHENOL 184 S3* 85SP
54 C565 DIBENZOFURAN 168 S3* 90
55 C560 4-NITROPHENOL 109 S3# 95SP
56 C570 2,4-DINITROTOLUENE 165 S3#105
57 C580 DIETHYLPHTHALATE 149 S3#130
58 C590 FLUORENE 166 S3#135
59 C585 4-CHLOROPHENYL-PHENYLE 204 53*140
60 C595 4-NITROANALINE 138 S3*150
61 C610 4,6-DINITRO-2-METHYLPH 198 S4* 10
62 C615 N-NITROSOOIPHENYLAMINE 169 S4* 15CC
63 C620 AZOBENZENE 77 S4# 20
64 C625 4-BROMOPHENYL-PHENYLET 248 S4* 30
65 C630 HEXACHLOROBENZENE 284 S4* 40
66 C635 PENTACHLOROPHENOL 266 S4# 50
67 C640 PHENANTHRENE 178 S4* 65
68 C645 ANTHRACENE 178 S4# 70
69 C647 CARBAZOLE 167 S4# 80
70 C650 DI-N-BUTYLPHTHALATE 149 S4# 85
71 C655 FLUORANTHENE 202 S4*110CC
72 C710 BENZIDINE 184 S5# 10
73 C715 PYRENE 202 S5* 15
74 C720 BUTYLBENZYLPHTHALATE 149 S5# 40
75 C730 BENZOC A) ANTHRACENE 228 S5* 50
76 C725 3,3'-DICHLOROBENZIDINE 252 S5* 55
77 C740 CHRYSENE 228 S5# 60
78 C745 BIS(2-ETHYLHEXYL)PHTHA 149 S5* 65
79 C760 DI-N-OCTYL PHTHALATE 149 So* 10CC
80 C765 BENZOC B) FLUORANTHENE 252 S6* 15
81 C770 BENZO(K) FLUORANTHENE 252 S6* 25
82 C775 BENZO(A)PYRENE 252 S6* 35
83 C780 INDENO(1.2,3-CD)PYRENE 276 S6# 55
84 C785 0 1 BENZ( A, H) ANTHRACENE 278 S6* 60
85 C790 BENZOC G,H,I)PERYLENE 27656*65
Weight:
Acct. No.
99-09-2
83-32-9
51-28-5
132-64-9
100-02-7
121-14-2
84-66-2
86-73-7
7005-72-3
100-01-6
534-52-1
87-30-6
103-33-3
101-55-3
118-74-1
87-86-5
85-01-8
120-12- T
86-74-8
84-74-2
206-44-
92-81-5
129-00-0
85-68-7
56-55-3
91-94-1
218-01-9
117-81-7
117-84-0
205-99-2
207-08-9
50-32-8
193-39-5
53-70-3
191-24-2
No m/z Scan Time Ref RRT Meth Area(Hght) Amount
51 138 850 9:27 3 1.011 A BB 70791.
52 153 848 9:26 3 1.008 A BB 200860.
53 184 870 9:41 3 1.034 A BB 37857.
54 168 880 9:47 3 1.046 A VB 290690.
55 109 899 10:00 3 1.069 A BB 31391.
56 165 893 9:56 3 1.062 A BB 74054.
57 149 948 10:33 3 1.127 A BB 24777*.
58 166 939 10:27 3 1.117 A BV 228542.
120.000
120.000
120.000
120.000
120.000
120.000
TjIftiTKH?
129.000
0.000
: FIN
XTot
UG/HL 1.25
UG/ML 1 .25
UG/ML 1.25
UG/ML 1 .25
UG/ML 1.25
UG/ML 1.25
UEAtt. 1-25
U6/NL 1.25
'1 S 1 ~
-L«J j.o
-------
No
59
60
61
62
63
64
65
66
67
68
69
70
71
72
73
74
75
76
77
78
79
80
81
82
83
84
85
No
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
69
70
71
72
73
74
75
76
77
m/z
204
138
198
169
77
248
284
266
178
178
167
149
202
184
202
149
228
252
228
149
149
252
252
252
276
278
276
Scan
950
961
965
976
978
1034
1033
1075
1105
1114
1151
1240
1313
1353
1349
1501
1565
1576
1572
1616
1728
1744
1748
1790
1946
1953
1978
Time Ref RRT
10:
10:
10:
10:
10:
11:
11:
11:
12:
12:
12:
13:
14:
15:
15:
16:
17:
17:
17:
17:
19:
19:
19:
19:
21:
21:
22:
34 3
41 3
44 4
51 4
53 4
30 4
29 4
57 4
17 4
23 4
48 4
48 4
36 4
03 5
00 5
42 5
24 5
32 5
29 5
58 5
13 6
24 6
27 6
55 6
39 6
43 6
00 6
1.130
1.143
0.877
0.887
0.889
0.940
0.939
0.977
1.005
1.013
1.046
1.127
1.194
0.863
0.861
0.958
0.999
1.006
1.003
1.031
0.961
0.970
0.972
0.996
1.082
1.086
1.100
Ret(L) Ratio RRT(L) Ratio
9:26
9:25
9:39
9:46
9:59
9:55
10:31
10:26
10:33
10:39
10:42
10:50
10:51
11:29
11:29
11:57
12:17
12:22
12:47
13:47
14:36
15:03
15:00
16:41
17:24
17:31
17:28
1.00
1.00
1.00
1.00
.00
.00
.00
.00
.00
.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
.00
.00
.00
.00
.00
.00
.00
1.00
1.00
1.00
1
1
1
1
1
1
1
1
1
1
0
0
0
0
0
.010
.007
.032
1.00
1.00
1.00
.045 1.00
.068
.00
.061 1.00
.126 '
.117 1
.130 1
.139 1
.875 1
.886 1
.888
.940
.939
0.977
1
1
1
1
1
0
0
0
0
1
1
.005
.012
.046
.127
.194
.864
.861
.958
.999
.006
.003
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
Meth
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
qe
qe
A
A
A
A
BB
VB
VB
BV
BB
BB
BB
BB
BV
VB
BB
BB
BB
BB
BB
BB
BV
BB
VB *»
BB o>
BB&
dj£)
BB I
BVQ
BB
BB
Amnt
120
120
120
120
120
120
120
120
120
120
120
120
120
120
120
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
120.00
120
120
120
120
120
120
120
120
120
120
120
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
Area(Hght)
108212.
49100.
38167.
163243.
338029.
66106.
73348.
47725.
291774.
279557.
217660.
349945.
242593.
25549.
234777.
126873.
196831.
73334.
173809.
178906.
294445.
223052.
175371.
171744.
185834.
181428.
192918.
Amnt(L)
120.00
120.00
120.00
120.00
120.00
120.00
120.00
120.00
120.00
120.00
120.00
120.00
120.00
120.00
120.00
120.00
120.00
120.00
120.00
120.00
120.00
120.00
120.00
120.00
120.00
120.00
120.00
R.
0
1
0
1
0
0
1
1
0
0
0
0
1
0
0
0
0
0
0
1
0
0
1
0
1
0
0
Amount
120.000 UG/ML
120.000 UG/ML
120.000 UG/ML
120.000 UG/ML
120.000 UG/ML
120.000 UG/ML
120.000 UG/ML
120.000 UG/ML
120.000 UG/ML
120.000 UG/ML
120.000 UG/ML
120.000 UG/ML
120.000 UG/ML
120.000 UG/ML
120.000 UG/ML
120.000 UG/ML
120.000 UG/ML
120.000 UG/ML
120.000 UG/ML
120.000 UG/ML
120.000 UG/ML
120.000 UG/ML
120.000 UG/ML
120.000 UG/ML
120.000 UG/ML
120.000 UG/ML
120.000 UG/ML
XTot
1.25
1.25
1.25
1.25
1.25
1.25
1.25
1.25
1.25
1.25
1.25
1.25
1.25
1.25
1.25
1.25
1.25
1.25
1.25
1.25
1.25
1.25
1.25
1.25
1.25
1.25
1.25
Fac R.Fac(L) Ratio
.379 0.379
.075 1.075
.203 0.203
.556 1.556
.168 0.168
.396 0.396
.328 1 .328
.224 1.224
.579 0.579
.263 0.263
.124 0.124
.530 0.530
.098 1.098
.215 0.215
.238 0.238
.155 0.155
.948 0.948
.908 0.908
.707 0.707
.137 1.137
.788 0.788
.141 0.141
.295 1.295
.700 0.700
.086 1.086
.405 0.405
.959 0.959
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
.00
.00
.00
.00
.00
ibis
-------
No
78
79
80
81
82
83
84
85
Ret(L) Rati<
17
19
19
19
19
21
21
21
:58
:13
:23
:26
:54
:38
:43
:59
1
1
1
1
1
1
1
1
.00
.00
.00
.00
.00
.00
.00
.00
1.032
0.961
0.969
0.972
0.996
1.082
1.086
1.100
Ratio
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
Amnt
120.00
120.00
120.00
120.00
120.00
120.00
120.00
120.00
Aimt(L) R.Fac R.
120.00 0.987
120.00
120.00
120.00
120.00
120.00
120.00
120.00
.967
.490
.171
.147
.241
.212
.289
Fac(L) Ratio
0.987
1.967
1.490
1.171
1.147
1.241
1.212
.00
.00
.00
.00
.00
.00
.00
1.289 1.00
,'ANUAUUIi uuut*
U PEAK NOT FOUND
2. POORCHROMATOGRAPh.
3, WRONG ISOMER
U MANUAL EDITS MUST BE
Ibi
-------
RIC+MASS CHROMATOGRAM
08/27/98 11120:00
SAMPLES SSTD120 128UG/ML CALI II
CONDS.i IHST. ID: F16
RANGE: G 1,2158 LABEL: H 8, 2.0
DATA: ST16980827D #1
CALI: ST16980827D #3
070698H
SCANS 515 TO 590
QUAN: A 6, 2.0 J 0 BASE:
160.01
122
RIC
5192.
122.037
± 0.506
297984.
590 SCAN
6:34 TIME
cr;
-------
3WI1
NWOS
90S'0
2*8'2H
008-0
•90een
e '03 n
689 01 0S9 SNUOS
0 r vz '9 v
S# Q2280869US
T# QZ280869I1S
0*2 '2I9N n3ayn esiz'i D «3DNya
9IJ «QI '1SNI «'SONOO
H8690Z0 II HUO -1UX900ZT 02TQ15S
00*02*11 86x^2/80
SSWW
-------
100.0-1
RIC+MASS CHROMATOGRAM DATAi ST16980827D #1 SCANS 1730 TO 1769
08/27/98 11:20:00 CALI: ST16980827D #3
SAMPLE! SSTD120 120UG/ML CALI II 070698H
CONDS.: INST. ID: F16
RANGE: G 1,2158 LABEL: N 2. 2.0 QUAN: A 6, 2.0 J 0 BASE: U 20, 3
1 r 48
51678.
370846.
252
51712.
252.075
± 8.500
'—T
327.7-,
1749
169385.
486410.
RIC
169472.
1765
19:38
SCAN
TIME
-------
DATA FROM FILE: ST16988827E SCANS 238 TO 1288 ACQUIRED: 88/27/98 11:58:88
CALI: ST16988827E »3
SAMPLE! SSTD160 160UG/ML CALI I 8786981
CONDS.: INST. ID: F16
-D5
82SS2* 02
20 NITROBENZENE-05
CS25 2-FLUOROBIPHENYL
J 100.0Z < 482384.)
99SS1# 83
4165-62-2
4165-68-8
1146-65-2
172SS3* 83
15867-26-2
321-68-8
33£SS3# 82
118-79-6
1B8I94» 01
1517-22-2
-------
DATA FROM FILE: ST16980827E SCANS 1200 TO 2158 ACQUIRED: 08/27/98 11:50:00
CALI: ST16980827E #3
SAMPLE: SSTD160 160UG/ML CALI I 0706981
CONDS.: INST. ID: F16
1280 .
13:21
1400 _
15:34
1600 _
17:48
1800 -
20:01
2000 .
22:15
100.0Z < 297472.)
CS30 TERPHENYL-D14
244SS5* 02
1718-51-0
E-D12
240IS5* 01
1719-03-5
164IS6* 01
1520-96-3
CT
t\:>
-------
Quantisation Report File: ST16980827E
Data: ST16980827E.TI
08/27/98 11:50:00
Sample: SSTD160 160UG/HL CALI I 0706981
Conds.: INST. ID: F16
Formula: 1UL INJ. Instrument: F16
Submitted by: QES Analyst: DAT
AHOUNT-AREA * REF AMNT/(REF AREA * RESP FACT)
Resp. fac. from Library Entry
No
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
CI40 NAPHTHALENE-OS
CI50 ACENAPHTHENE-D10
CI60 PHENANTHRENE-D10
CI70 CHRYSENE-D12
CITS PERYLENE-012
CS20 NITROBENZENE-DS
CS25 2-FLUOROBIPHENYL
CS30 TERPHENYL-D14
CS45 PHENOL-D5
CS50 2-FLUOROPHENOL
CS55 2,4,6-TRIBROMOPHENOL
CS70 2-CHLOROPHENOL-D4
CS75 1.2-DICHLOR08NZN-D4
HEXACHLOROBENZENE-C13
C310 N-NITROSOOIMETHYLAMINE 74 Slid 15
C320 ANILINE 93 51*100
C315 PHENOL 94 S1#105CC
C325 BIS(2-CHLOROETHYL)ETHER 93 S1#110
C330 2-CHLOROPHENOL 128 S2#115
C335 1,3-DICHLOROBENZENE 146 S1#125
C340 1,4-DICHLOROBENZENE 146 S1#130CC
C345 BENZYL ALCOHOL 108 S1#145
C350 1,2-DICHLOROBENZENE 146 51*150
C355 2-HETHYLPHENOL 108 S1#160
C360 2,2'-OXYBIS(1-CLPROPAN) 45 51*165
C365 4-METHYLPHENOL 108 S1#185
C370 N-NITROSO-DI-N-PROPYLAM 70 S14M90SP
C375 HEXACHLOROETHANE 117 51*200
C410 NITROBENZENE 77 52* 10
C415 ISOPHORONE 82 S2# 20
C420 2-NITROPHENOL 139 52* 25CC
C425 2,4-DIMETHYLPHENOL 107 S2# 30
C435 BIS(2-CHLOROETHOXY)METH 93 S2* 35
C440 2,4-DICHLOROPHENOL 162 S2* 40
C430 BENZOIC ACID 122 S2# 45
37 C445 1,2,4-TRICHLOROBENZENE 180 S2# 55
38 C450 NAPHTHALENE 128 52* 60
39 C455 4-CHLOROANALINE 127 52* 80
40 C460 HEXACHLOROBUTADIENE 225 S2* 95CC
41 C465 4-CHLORO-3-METHYLPHENO 107 S2*130CC
42 C470 2-HETHYLNAPHTHALENE 142 S2#145
43 C510 HEXACHLOROCYCLOPENTADI 237 S3# 20
44 C515 2,4.6-TRICHLOROPHENOL 196 S3* 25CC
45 C520 2,4,5-TRICHLOROPHENOL 196 S3* 30
46 C525 2-CHLORONAPHTHALENE 162 S3* 40
47 C530 2-NITROANALINE 65 S3* 45
Weight: 0.000
Acct. No.: FIN
152IS1* 01
136IS2* 01
164IS3* 01
188IS4* 01
240IS5* 01
164IS6* 01
82SS2* 02
172SS3* 03
244SS5* 02
99SS1* 03
112SS1* 02
330SS3* 02
132 S1* 05
152 S1* 06
3855-82-1
1146-65-2
15067-26-2
1517-22-2
1719-03-5
1520-96-3
4165-60-0
321-60-8
1718-51-0
4165-62-2
367-12-4
118-79-6
62-75-9
62-53-3
108-95-2
111-44-4
95-57-8
541-73-1
106-46-7
100-51-6
95-50-1
95-48-7
108-60-1
106-44-5
621-64-7
67-72-1
98-95-3
75-59-1
88-75-5
105-67-9
111-91-1
120-83-2
65-85-0
120-82-1
91-20-3
106-47-8
87-68-3
59-50-7
91-57-6
77-47-4
88-06-2
75-95-4
91-58-7
88-74-4
-------
10
A
,9
10
lo
1
2
3
4
5
6
7
8
9
10
11
12
13
14
IS
16
17
IB
19
20
21
22
23
24
25
26
27
28
29
SO
51
52
S3
54
55
56
J7
58
59
40
41
42
43
44
45
46
47
48
49
50
Name
C535
C540
C543
m/z
152
136
164
188
240
264
82
172
244
99
112
330
132
152
NOT
74
93
94
93
128
146
146
108
146
108
45
108
70
117
77
82
139
107
93
162
122
180
128
127
225
107
142
237
196
196
162
65
163
152
165
DIMETHYLPHTHALATE
ACENAPHTHYLENE
2,6-DINITROTOLUENE '
Scan Time Ref RRT
352
544
842
1101
1568
1798
437
737
1398
322
205
985
325
372
FOUND
109
312
323
328
327
343
354
383
374
403
401
431
426
420
440
484
487
512
525
531
571
538
548
570
573
662
666
694
722
727
748
777
822
817
828
3:55
6:03
9:22
12:15
17:26
20:00
4:52
8:12
15:33
3:35
2:17
10:57
3:37
4:08
1:13
3:28
3:36
3:39
3:38
3:49
3:56
4:16
4:10
4:29
4:28
4:48
4:44
4:40
4:54
5:23
5:25
5:42
5:50
5:54
6:21
5:59
6:06
6:20
6:22
7:22
7:24
7:43
8:02
8:05
8:19
8:39
9:09
9:05
9:13
1
2
3
4
5
6
2
3
5
1
1
3
1
1
1
1
1
2
2
2
2
2
2
2
2
2
2
2
2
2
3
3
3
3
3
3
3
3
1.000
1.000
1.000
1.000
1.000
1.000
0.803
0.875
0.892
0.915
0.582
1.170
0.923
1.057
0.310
0.886
0.918
0.932
0.929
0.974
.006
.088
.062
.145
.139
.224
1.210
1.193
0.809
0.890
0.895
0.941
0.965
0.976
1.050
0.989
1.007
1.048
1.053
1.217
1.224
0.824
0.857
0.863
0.888
0.923
0.976
0.970
0.983
163 S3* 55 131-11-3
152 S3* 65 208-96-8
165 S3* 70 606-20-2
Meth Area(Hght) Amount
A BB
A BB
A BB
A BB
A BB
A BB
A BB
A BB
A VB
A BB
A BB
A BB
A BB
A BB
A BB
A BV
A BB
A BB
A BB
A BV
A VB
A BB
A BB
A BB
A BB
A BB
A BV
A BB
A VB
qedtQ)
A BB
A BB
A BBto
A BB°~
qedt(j)
A BB\_
A BB£
A DD ^vf
A BV
A BB
qedt(«)
A BB
A BV
A VB I
A BB 4
A BB <^
A BB
A BB
qedt(7)
32486.
124189.
71932.
116804.
60904.
50722.
224354.
321084.
248225.
256146.
181194.
62460.
182800.
114576.
135427.
217517.
257557.
163916.
188486.
196267.
197247.
119784.
183117.
157686.
323096.
175498.
115670.
91776.
203653.
351500.
108037.
175563.
247182.
151820.
145098.
154240.
464474.
225820.
78174.
172070.
317611.
94850.
128899.
105318.
313318.
143092.
359876.
480732.
91334.
40.000
40.
40.
40.
40.
40.
160.
160.
160.
160.
160.
160.
160.
160.
160.
160.
160.
160.
160.
160.
160.
160.
160.
160.
160.
160.
160.
160.
160.
160.
160.
160.
160.
160.
160.
160.
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
160.000
160.
160.
160.
160.
160.
160.
160.
160.
160.
000
000
000
000
000
000
000
000
000
160.000
160.000
160.000
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
XTot
0.31
0.31
0.31
0.31
0.31
0.31
.26
.26
.26
.26
.26
.26
.26
1.26
1.26
1.26
1.26
1.26
1.26
1.26
1.26
1.26
1.26
1.26
1.26
1.26
1.26
1.26
1.26
.26
.26
.26
.26
.26
.26
1.26
1.26
1.26
1.26
1.26
1.26
1.26
1.26
1.26
1.26
1.26
1.26
1.26
1.26
-------
No Ret(L) Ratio RRT(L) Ratio
Aunt Amnt(L) R.Fac R.Fac(L) Ratio
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
3:54
6:01
9:21
12:13
17:25
19:59
4:49
8:11
15:32
3:32
2:15
10:55
3:34
4:07
12:39
1:12
3:27
3:33
3:36
3:36
3:48
3:55
4:13
4:08
4:27
4:26
4:44
4:40
4:39
4:51
5:19
5:24
5:39
5:48
5:52
6:10
5:57
6:04
6:16
6:22
7:20
7:22
7:42
8:00
8:03
8:17
8:37
9:06
9:03
9:09
1.01
1.01
1.00
1.00
1.00
1.00
1.01
1.00
1.00
1.02
1.01
1.00
1.01
1.01
1.01
1.01
1.01
1.01
1.01
1.01
1.01
1.01
1.01
1.01
1.01
1.01
1.01
1.00
1.01
1.01
1.00
1.01
1.01
1.01
1.03
1.01
1.01
1.01
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.01
1.000
1.000
1.000
1.000
1.000
1.000
0.800
0.875
0.891
0.906
0.580
1.168
0.917
1.057
0.941
0.309
0.886
0.911
0.926
0.926
0.974
1.006
1.083
1.063
1.143
1.140
1.217
1.200
1.194
0.806
0.884
0.896
0.939
0.965
0.974
1.024
0.989
1.007
1.043
1.057
1.220
1.226
0.824
0.856
0.862
0.887
0.921
0.974
0.969
0.980
1
1
1
1
1
1
1
1
1
1
1
1
1
.00
.00
.00
.00
.00
.00
.00
.00
.00
.01
.00
.00
.01
1.00
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
.00
.00
.01
.01
.00
.00
.00
.00
.00
.00
.00
.01
.01
.00
.00
.01
.00
.00
.00
.00
.03
.00
.00
.01
1.00
1
1
1
1
1
1
1
1
1
1
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
40
40
40
40
40
40
160
160
160
160
160
160
160
160
160
160
160
160
160
160
160
160
160
160
160
160
160
160
160
160
160
160
160
160
160
160
160
160
160
160
160
160
160
160
160
160
160
160
160
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
40.00
40.00
40.00
40.00
40.00
40.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
1.000
1.000
1.000
1.000
1.000
1.000
0.452
1.116
1.019
1.971
1.394
0.217
1.407
0.882
1.042
1.674
1.982
1.261
1.451
1.510
1.518
0.922
1.409
1.213
2.486
1.351
0.890
0.706
0.410
0.708
0.217
0.353
0.498
0.306
0.292
0.310
0.935
0.455
0.157
0.346
0.639
0.330
0.448
0.366
1.089
0.497
1.251
1.671
0.317
1.000
1.000
1.000
1.000
1.000
1.000
0.452
1.116
1.019
1.971
1.394
0.217
1.407
0.882
1.042
1.674
1.982
1.261
1.451
1.510
1.518
0.922
1.409
1.213
2.486
1.351
0.890
0.706
0.410
0.708
0.217
0.353
0.498
0.306
0.292
0.310
0.935
0.455
0.157
0.346
0.639
0.330
0.448
0.366
1.089
0.497
1.251
1.671
0.317
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.0C
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
-------
imitation Report File: ST16980827E
ca: ST16980827E.TI
'27/98 11:50:00
nple: SSTD160 160UG/ML CALI I 0706981
ids.: 1NST. ID: F16
rmula: 1UL INJ. Instrument: F16 Weight: 0.000
omitted by: OES Analyst: DAT Acct. No.: FIN
OUNT=AREA * REF AMNT/(REF AREA * RESP FACT)
sp. fac. from Library Entry
o
1
2
3
4
5
6
7
8
9
.0
,1
.2
3
>4
>5
*
>7
£
>9
TO
f1
n
73
74
75
76
77
78
79
80
81
82
83
84
85
No
51
52
53
54
55
56
57
58
Name
C545
C550
C555
C565
C560
C570
C580
C590
C585
C595
C610
C615
C620
C625
C630
C635
C640
C645
C647
C650
C655
C710
C715
C720
C730
C725
C740
C745
C760
C765
C770
C775
C780
C785
C790
m/z
138
153
184
168
109
165
149
166
3-NITROANILINE
ACENAPHTHENE
2,4-OINITROPHENOL
DIBENZOFURAN
4-NITROPHENOL
2,4-OINITROTOLUENE
DIETHYLPHTHALATE
FLUORENE
4-CHLOROPHENYL-PHENYLE
4-NITROANALINE
4,6-DINITRO-2-METHYLPH
N - N I TROSOO I PHEN YL AM I NE
AZOBENZENE
4- BROMOPHEN YL - PHEN YLET
HEXACHLOROBENZENE
PENTACHLOROPHENOL
PHENANTHRENE
ANTHRACENE
CARBAZOLE
DI-N-BUTYLPHTHALATE
FLUORANTHENE
BENZIDINE
PYRENE
BUTYLBENZYLPHTHALATE
BENZO(A)ANTHRACENE
3,3'-DICHLOROBENZIDINE
CHRYSENE
BIS(2-ETHYLHEXYL)PHTHA
DI-N-OCTYL PHTHALATE
BENZOC B ) FLUORANTHENE
BENZOC K ) FLUORANT HENE
BENZO(A)PYRENE
INOENO(1,2,3-CD)PYRENE
DIBENZ(A,H)ANTHRACENE
BENZO(G,H,I)PERYLENE
Scan Time Ref RRT
853 9:29 3 1.013
849 9:27 3 1.008
872 9:42 3 1.036
881 9:48 3 1.046
901 10:01 3 1.070
896 9:58 3 1.064
950 10:34 3 1.128
941 10:28 3 1.118
138
153
184
168
109
165
149
166
204
138
198
169
77
248
284
266
178
178
167
149
202
184
202
149
228
252
228
149
149
252
252
252
276
278
276
S3* 75
S3* 80CC
S3* 85SP
S3* 90
S3* 95SP
S3#105
S3*130
S3*135
S3*140
S3*150
S4* 10
S4* 15CC
S4* 20
S4* 30
S4* 40
S4* 50
S4* 65
S4* 70
S4* 80
S4* 85
S4*110CC
S5* 10
S5* 15
S5* 40
S5* 50
S5* 55
S5* 60
S5* 65
S6* 10CC
S6* 15
S6# 25
S6# 35
S6* 55
S6* 60
S6* 65
Meth Area(Hght)
A
A
A
A
9«
A
<*«
A
BB 108951 .
BB % 306695.
BB £ 56407.
BB V 449013.
dtQp 48707.
BB 108669.
4t& 347720.
W i 341839.
99-09-2
83-32-9
51-28-5
132-64-9
100-02-7
121-14-2
84-66-2
86-73-7
7005-72-3
100-01-6
534-52-1
87-30-6
103-33-3
101-55-3
118-74-1
87-86-5
85-01-8
120-12-7
86-74-8
84-74-2
206-44-0
92-81-5
129-00-0
85-68-7
56-55-3
91-94-1
218-01-9
117-81-7
117-84-0
205-99-2
207-08-9
50-32-8
193-39-5
53-70-3
191-24-2
Amount
160.000 UG/ML
160.000 UG/NL
160.000 UG/ML
160.000 UG/ML
160.000 UG/ML
160.000 UG/ML
160.000 UG/ML
160.000 UG/ML
XTot
1.26
1.26
1.26
1.26
1.26
1.26
1.26
1.26
Ov
-------
No
59
60
61
62
63
64
65
66
67
68
69
70
71
72
73
74
75
76
77
78
79
80
81
82
83
84
85
No
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
69
70
71
72
73
74
75
76
77
m/z Scan Time Ref
204 951 10:35
138 965 10:44
198 969 10:47
169 978 10:53
77 979 10:53
248 1035 11:31
284 1034 11:30
266 1076 11:58
178 1106 12:18
178 1115 12:24
167 1153 12:49
149 1241 13:48
202 1314 14:37
184 1353 15:03
202 1350 15:01
149 1502 16:42
228 1566 17:25
252 1577 17:32
228 1573 17:30
149 1617 17:59
149 1729 19:14
252 1745 19:25
252 1750 19:28
252 1792 19:56
276 1947 21:39
278 1954 21:44
276 1980 22:01
Ret(L) Ratio RRT(L)
9:26 1.01 1.010
9:25 1.00 1.007
9:39 1.01 1.032
9:46 1.00 1.045
9:59 1.00 1.068
9:55 1.01 1.061
10:31 1.00 1.126
10:26 1.00 1.117
10:33 1.00 1.130
10:39 1.01 1.139
10:42 1.01 0.875
10:50 1.00 0.886
10:51 1.00 0.888
11:29 1.00 0.940
11:29 1.00 0.939
11:57 1.00 0.977
12:17 1.00 1.005
12:22 1.00 1.012
12:47 1.00 1.046
13:47 1.00 1.127
14:36 1.00 1.194
15:03 1.00 0.864
15:00 .00 0.861
16:41 .00 0.958
17:24 .00 0.999
17:31 .00 1.006
17:28 .00 1.003
3
3
4
4
4
4
4
4
4
4
4
4
4
5
5
5
5
5
5
5
6
6
6
6
6
6
6
RRT
1.129
1.146
0.880
0.888
0.889
0.940
0.939
0.977
1.005
1.013
1.047
1.127
1.193
0.863
0.861
0.958
0.999
1.006
1.003
1.031
0.962
0.971
0.973
0.997
1.083
1.087
1.101
Ratio
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
.00
.00
.00
.00
.00
.00
.00
.00
.00
.01
.01
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
Meth
ABB/
Y
\^*j
A BB,$
A BB^
A BB
A BB
A BB
A BV
A VB
A BB
A BB
A BB
A BB
A BB
A BB
A W
A BB
A VB
A BB
A BB
A BV
A VB
A BB
A BV
A BB
A BB
Amnt
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
Area(Hght) Amount
165442.
92245.
60946.
244263.
541010.
98271.
112917.
68614.
471716.
378128.
327617.
504598.
334270.
32031.
330800.
178737.
265942.
95194.
223869.
265391 .
410452.
286447.
190774.
219973.
232127.
224248.
231038.
Amnt
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
i60.no
160.000
160.000
160.000
160.000
160.000
160.000
160.000
160.000
160.000
160.000
160.000
160.000
160.000
160.000
160.000
160.000
160.000
160.000
160.000
160.000
160.000
160.000
160.000
160.000
160.000
160.000
160.000
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/NL
R.Fac R.Fac(L)
0.379
1.066
0.196
1.561
0.169
0.378
1.209
1.188
0.575
0.321
0.130
0.523
1.158
0.210
0.242
0.147
1.010
0.809
0.701
1.080
0.715
0.131
1.358
0.734
1.092
0.391
0.919
0.379
1.066
0.196
1.561
0,169
0.378
t.209
1.188
0.575
0.321
0.130
0.523
1.158
0.210
0.242
0.147
1.010
0.809
0.701
1.080
0.715
0.131
1.358
0.734
1.092
0.391
0.919
XTot
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
.26
.26
.26
.26
.26
.26
.26
.26
.26
.26
.26
.26
.26
.26
.26
.26
.26
.26
.26
.26
.26
.26
.26
.26
.26
.26
.26
Ratio
1
. 1
1
1
1
1
1
.00
.00
.00
.00
.00
.00
.00
1.00
1
t
.00
.00
1.00
1
1
1
1
1
1
1
1
1
1
1
1
1
1
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
1.00
1.00
-------
o
8
9
a
n
12
13
&
5
Ret(l)
17:58
19:13
19:23
19:26
19:54
21:38
21:43
21:59
Ratio
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
RRT(L)
1.032
0.961
0.969
0.972
0.996
1.082
1.086
1.100
Ratio
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
Amnt
160
160
160
160
160
160
160
160
.00
.00
.00
.00
.00
.00
.00
.00
AmntU)
160
160
160
160
160
160
160
160
.00
.00
.00
.00
.00
.00
.00
.00
R.Fac R.
1.089
2.023
1.412
0.940
1.084
1.144
1.105
1.139
.Fac(L) Ratio
1.089
2.023
1.412
0.940
1.084
1.144
1.105
1.139
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
.:ANUAL 6DIT CUUtS
U PEAK NOT FOUND
>. POOR CHROMATOGRAPHi
3, WttmG ISOMER
' L MANUAL EDITS MUST BF
™i -P9, DATED, AMD CCO--
Ib r
JU V » . \J
-------
100.0-1
RIC+MASS CHROMATOGRAM DATA: ST16980827E *1 SCANS 460 TO 520
08/27x98 11:50:00 CALI: ST16980827E #3
SAMPLE: SST0160 160UG/ML CALI I 0706981
COHDS.: INST. ID: F16
RANGE: G 1,2158 LABEL: N 2, 2.0 QUAN: A B, 2.0 J 0 BASE: U 2Q, 3
484
60530.
351149.
82 _
345.9-1
RIC
487
209316.
J478620
497
7620.
22222.
460
5:67
~T
470
5:14
~T
480
5i20
~T
490
5i27
500
5:34
512
191741.
898156.
60544.
82.025
± 0.500
209408.
520 SCAN
5:47 TIME
cr
-------
100.0-1
RIOMASS CHROMATOGRAM DATA: ST16980827E #1 SCANS 515 TO 600
08/27/98 11:50:00 CALI: ST16980827E #3
SAMPLE: SSTD160 160UG/ML CALI I 0706981
RANG!;'GINSi',2158 LABEL: H 0, 2.0 QUAN: A e, 2.0 J 0 BASE: 1^20, 3
122
RIC
7168.
122.037
± 0.500
592
598
385024.
573
/
1 I '
528
5:47
i
530
5:54
1 r
540
6:00
1 '
550
6:07
1 '
560
6:14
>
I r
570
6:20
L 585
580
6:27
590
6:34
600 SCAN
6:40 TIME
CT
co
o
-------
52.3-,
107
100.0-1
142
MASS CHROMATOGRAMS
08/27/98 11:50:00
SAMPLE: SSTD160 160UG/ML CALI I
CONDS.: INST. ID: F16
RANGE: G 1,2158 LABEL: N 2, 2.9
DATA: ST16980827E #1
CALI: ST16380827E #3
0706981
SCANS 650 TO 689
QUAN: A 6, 2.0 J 0 BASE: U 20,
46293.
173074.
-r
650
7:14
655
7:17
660
7:20
665
7:24
1
670.
7i2>
679
1319.
3622.
—I—r
675
7:30
680
7:34
685
7:37
Cr
K-
46336.
107.032
± 0.500
— I 1 1 1 1'""! i 1 1 1 1 r-
A 666
88555.
451587.
-i — i — | 1 — i — i — i 1 i i i i | i i i i
88576.
142.042
± 0.500
SCAN
TIME
-------
RIC+MASS CHROMATOGRAM
08/27x98 11:50:08
SAMPLE: SST0160 160UG/ML CALI I
CONDS.i INST. ID: F16
RANGE: G 1.2158 LABEL: N 2, 2.0
DATA: ST16980827E #1
CALI: ST16980827E #3
0706981
SCANS 800 TO 850
QUAN: A 6, 2.0 J
100.0-
0 BASE: U 20,
828
21921.
66658.
165
RIC
K
CT
21952.
165.049
± 0.500
358400.
800
8:54
850 SCAN
9:27 TIME
-------
100.0-
RIC+MASS CHROMATOGRAM DATA: ST16980827E #1 SCANS 870 TO 930
08/27x98 Ili50:00 CALI: ST16980827E #3
SAMPLE: SST0160 160UG/ML CALI I 0706981
CONDS.i INST. ID: F16
RANGEi G 1,2158 LABELi N 2, 2.0 QUAN: A 6, 2.0 J 0 BASE: U 20, 3
901
7973.
47518.
109
RIC
881
275968.
1044510
896
145854.
570300.
901
81442.
435036.
916
10:07
929
10:14
8008.
109.033
± 0.500
275968.
930 SCAN
10:21 TIME
-------
3WI1 *S:
086
HS0I
•03610^
00S'0 T
•8028Z
L6'£IS
•Z8100C
0'00I
'03 n s
086 01 036 SNUOS
096
0 r 0'3 '9
8* 3Z380869US
T# 32380869TIS :yiyQ
0'3 '3
I8690Z0 I
H
89T3'T o
9TJ 5QI 'iSNI S'SQNOO
HMx9n09I 09TQ1SS «3HdWyS
00:09*TT 86/Z3/80
-------
RIC+MASS CHROMATOGRAM
08x27x98 Ili50:00
SAMPLE: SSTD160 160UGXML CALI I
COHDS.: INST. ID: F16
RANGE: G 1,2158 LABEL: N 2/2.0
DATA: ST16980827E #1
CALI: ST16980827E #3
0706981
QUAN: A 6, 2.0 J
SCANS 930 TO 990
: U 20,
100.0-
14453.
74867.
138
RIC
969
161792.
1044340.
U
138
± 9
4751
930
10:21
990 SC
11:01 TI
cr
Co
-------
RIC+MASS CHROMATOGRAM
08/27x98 11:50:00
SAMPLE: SSTD160 160UG/ML CALI I
COHDS.: INST. ID: F16
RANGE: G 1,2158 LABEL: N 2, 2.0
DATA: ST16980827E #1
CALI: ST16980827E #3
0706981
QUAN: A 6, 2.0 J 0
100.0-1
SCANS 930 TO 990
BASE: U.20,
16551.
52249.
198
16576.
198.059
± 0.500
951
401920.
1809870.
978
475136.
2051870.
RIC
969
161792.
1044340.
475136.
985
184576.
453952.
I
960
10:41
970
10147
980
10:54
990 SCAN
11:01 TIME
-------
QUANTERRA GC/HS
SENIVOLATILE APPENDIX IX CALIBRATION CHE
INITIAL CALIBRATION: 10 UG/ML APPENDIX ST1 6980831 B 08/31/98 13:35:00
INITIAL CALIBRATION: 20 UG/ML APPENDIX ST16980831C 08/31/98 14:02:00
INITIAL CALIBRATION: 50 UG/ML APPENDIX ST 1698083 10 08/31/98 14:32:00
INITIAL CALIBRATION: 80 UG/ML APPENDIX ST 16980831 A 08/31/98 13:07:00
INITIAL CALIBRATION: 120 UG/ML APPENDIX ST16980831E 08/31/98 15:02:00
INITIAL CALIBRATION: 160 UG/ML APPENDIX ST16980831F 08/31/98 15:31:00
Initial Calibration Continuing Calibration
Library Response Factor X RSD Response Factor X Diff
Entry Compound
S1 20 PYRIDINE
S1 30 2-PICOLINE
S1 40 N-NITROSOMETHYLETHYL
S1 60 METHYLMETHANESULFONA
SI 70 N-NITROSOOIETHYLAMIN
S1 85 ETHYLMETHANE SULFONA
S1 95 PENTACHLOROETHANE
SI 170 C361 ACETOPHENONE
SI 175 N-NITROSOPYRROLIDINE
SI 180 N-NITROSOMORPHOLINE
S1 182 3-METHYL PHENOL
SI 195 0-TOLUIDINE
S2 15 N-NITROSOPIPER1DINE
S2 50 AA-DIMETHYLPHENETHYL
S2 85 2,6-DICHLOROPHENOL
S2 90 HEXACHLOROPROPENE
S2 115 P-PHENYLENE DIAMINE
S2 120 N-NITROSOOI-N-BUTYLA
S2 140 SAFROLE
S3 10 1,2,4.5-TETRACHLOROS
S3 15 ISOSAFROLE (#1)
S3 35 ISOSAFROLE (#2
S3 42 1-CHLORONAPHTH
S3 50 1,4-NAPHTHOOUINONE
S3 60 1,3-DINITROBENZENE
S3 100 PENTACHLOROBENZENE
S3 110 1-NAPHTHYLAMINE
S3 115 2-NAPHTHYLAMINE
S3 120 2,3,4,6-TETRACHLOROP
S3 145 5-NITRO-O-TOLUIDINE
S4 25 SYM-TRINITROBEN2ENE
S4 35 PHENACETIN
S4 37 DIALLATE
S4 45 4-AMIN08IPHENYL
S4 55 PRONAMIDE
S4 60 PENTACHLORONITROBENZ
S4 75 2SEC8UTYL-4.6-DINITR
S4 100 4-NITROOUINOLINE-1-0
S4 105 METHAPYRILENE
S4 106 ISODRIN
S4 120 CHLOROBENZILATE
S5 20 ARAMITE (#1)
S5 25 ARAMITE (#2)
S5 30 P-DIMETHYLAMINOAZOBE
S5 35 3,3'-DIMETHYLBENZIDI
S5 37 KEPONE
S5 45 2-ACETYLAMINOFLUOREN
S5 85 3-METHYLCHOLANTHRENE
Avg Min
1.590
1.565
0.811
0.636
0.521
1.109
0.602
1.934
0.553
0.821
2.252
2.160
0.321
1.285
0.257
0.198
0.131
0.213
0.248
0.433
0.044
0.195
1.318
0.414
0.198
0.489
0.837
0.966
0.297
0.355
0.162
0.317
0.090
0.609
0.299
0.080
0.153
0.072
0.305
0.127
0.323
0.061
0.087
0.419
0.418
0.082
0.432
0.548
Max Min Max
6.5
1.3
9.2
6.2
7.6
11.0
1.4
2.8
6.5
1.4
9.9
9.2
4.9
15.6
12.8
0.9
42.2
7.2
0.9
4.4
3.4
2.2
16.5
5.6
8.6
3.8
6.6
5.8
4.5
7.2
5.3
3.2
4.4
7.6
5.2
1.8
9.3
11.5
26.8
1.5
11.1
4.4
4.4
1.1
17.0
34.6
4.0
6.1
IbSv
-------
20 7,12-DIMETHYLBENZANT 0.610 0.5
0 CCC and SPCC compounds are out
-------
WO '091 ZIZ'O 'OZl OIZ'O '08 ZOZ'O 'OS 161'0 '03 991/0 '01 09 £S
68fO '091 •WO 'OZl . /5VO '08 6Z"7'0 'OS £OVO 'OZ OS £S
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Z61'0 '091 061'0 'OZl 961'0 '08 S61'0 'OS IOZ'0 'OZ S£ £S
WO '091 WO 'OZl EVO'O '08 ZVO'O 'OS 9*TO 'OZ SI £S
61VO '091 91VO 'OZl 0£rO '08 WO 'OS LEV'O 'OZ 69VO '01 01 £S
OSZ'O '091 Stt'O 'OZl OSZ'O '08 ^Z'O 'OS 9^-0 'OZ 0^1 ZS
•>ZZ'0 '091 VZZ'O 'OZl SZZ'O '08 ElZ'O 'OS SOZ'O 'OZ 981'0 'OL OZl ZS
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Wri '091 9/ZU 'OZl 9£0'l '08 £S£'l 'OS S/S'l 'OZ OS ZS
6Z£'0 '091 /££'0 'OZl ZZ£'0 '08 9Z£'0 'OS Zl£'0 'OZ £6Z'0 '01 SI ZS
6V6'l '091 Z£0'Z 'OZl 6Zl'Z '08 SZZ'Z 'OS £9^'Z 'OZ 561 IS
WTZ '091 16£"Z 'OZl SOrZ '08 6££-Z 'OS 0£l'Z 'OZ SVS'l '01 ZSl IS
A '
918'0 '091 /18-0 'OZl S08-0 '08 IZS'O 'OS 8£8'0 'OZ 8Z8'0 '01 081 IS
S/S-0 '091 69S-0 'OZl Z9S'0 '08 SZS'O 'OS SSS'O 'OZ 18VO '01 S/l IS
£06' I '091 £06*1 'OZl SWl '08 096' I 'OS VZO'Z 'OZ 698' L '01 Oil IS
Z6S'0 '091 S65'0 'OZl S09'0 '08 S09'0 'OS Z19'0 'OZ 56 IS
V^Z'l '091 06l'l 'OZl 89l'l '08 OZl'l 'OS SOO'l 'OZ IZ6'0 '01 SB IS
SSS'O '091 /*S'0 'OZl 6V5'0 '08 IZS'O 'OS 905'0 'OZ OS^'O '01 O/ IS
709'0 '091 619'0 'OZl Z09'0 '08 S89'0 'OS 889'0 'OZ 619'0 '01 09 IS
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S^S'l '091 ZVS'l 'OZl //S'l '08 ^65' I 'OS £95' I 'OZ 0£ IS
9/S'l '091 6*T I 'OZl /8S'l '08 8/S'l 'OS £85' I 'OZ 0//'l '01 OZ IS
das ouoo JHJJ ouoo jaa auoo jas 3^03 jsa DUOO jaa ouoo # qn
d I £80869 US 3 L £80869 US VI £80869 US Q I £80869 US 3 1 £80869 US 8 1 £80869 US
00:l£:Sl 86/l£/80 Jl£80869US XIQN3ddV 1W/on 091 =
OO'ZO'Sl 86/IE/80 31E80869US XION3ddV 1W/On OZl 'NOIiVaailVD 1VI1INI
00:/0 = £l 86/l£/80 VIE80869US XION3ddV 1W/DH 08 :NOIlVaanVD IVIilNI
00 = Z£:Vl 86/IE/80 Ql£80869US XION3ddV IN/Ofl OS SNOIiVaBIIVO 1V11INI
00:ZO:^l 86/l£/80 31E80869US XION3ddV IW/OH OZ JNOIiVaSPVa IVIilNI
00:S£!£l 86/IE/80 BIE80869US XION3ddV IW/DH 01 =NOIlvaanva 1VI1IN1
3H3 Nouvaanva xi xiaNSddv STIIVIOAIHSS
sw/oo
-------
13 100 10, 0.516
!3 110 10, 0.869
;3 115 10, 0.924
!3 120
i3 145
14 25
A 35
4 37
4 45
4 55
4 60
4 75
4 100
4 105
4 106 10, 0.127
4 120 10, 0.376
5 20
5 25
5 30
5 35
5 37
5 45
5 85
6 20
20,
20.
20.
20,
20,
20,
20,
20,
20,
20,
20,
20,
20,
20,
20,
20,
20,
20,
20,
20,
20,
20,
20,
20,
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.504
.859
.974
.277
.345
.149
.305
.088
.643
.312
.081
.130
.058
.424
0.125
0
0
0
0
0
0
0
0
0
.351
.057
.081
.417
.522
.123
.404
.586
.609
50,
50,
50.
50,
50,
50,
50,
50,
50,
50,
50,
50,
50,
50,
50,
50,
50,
50,
50,
50,
50,
50,
50,
50,
0.483
0.889
1.041
0.302
0.368
0.162
0.324
0.087
0.664
0.315
0.079
0.165
0.074
0.339
0.129
0.329
0.063
0.090
0.425
0.450
0.087
0.450
0.576
0.615
80,
80,
80,
80,
80,
80,
80,
80,
80,
80,
80,
80,
80,
80,
80,
80,
80,
80,
80,
80,
80,
80,
80,
80,
0.493
0.765
0.996
0.310
0.381
0.172
0.316
0.089
0.602
0.301
0.079
0.163
0.076
0.205
0.128
0.308
0.061
0.090
0.420
0.406
0.089
0.438
0.549
0.610
120,
120.
120,
120,
120,
120.
120,
120.
120,
120,
120,
120,
120,
120,
120,
120,
120,
120,
120,
120,
120,
120,
120,
120,
0.469
0.872
0.980
0.306
0.367
0.166
0.330
0.089
0.590
0.291
0.082
0.159
0.079
0.279
0.127
0.295
0.064
0.087
0.412
0.364
0.056
0.429
0.515
0.608
160,
160.
160,
160,
160,
160.
160.
160.
160,
160,
160,
160,
160,
160,
160,
160,
160,
160,
160,
160,
160,
160,
160,
160,
0.471
0.769
0.881
0.290
0.316
0.159
0.311
0.097
0.546
0.277
0.081
0.150
0.075
0.277
0.124
0.281
0.061
0.085
0.420
0.346
0.054
0.440
0.514
0.609
-------
DATA FROM FILE: ST1698083IB SCANS 230 TO 1200 ACQUIRED: 08/31/98 13:35:00
CALI: ST1698083IB #3
SAMPLE: 10UG/ML AP9 062598C
CONDS.: INST. ID: F16
100.0Z < 95232.)
CI30 1,4-DICHLOROBENZENE-D4 152IS1# 01 3855-82-1
1000 -|
11:07
ffl* -I
CI40 NAPHTHALENE-08
136IS2* 01
CI50 ACENAPHTHENE-D10
CI60 PHENANTHRENE-D10
164IS3K 01
188IS4* 01
1146-65-2
15067-26-2
1517-22-2
CT
-------
DATA FROM FILE: ST1698083IB SCANS 1200 TO 2158 ACQUIRED: 08/31/98 13:35:00
CALI: ST1698083IB #3
SAMPLE: 10UG/ML AP9 062598C
CONDS.: INST. ID: F16
100.02 < 89600.)
1200 1 1 1 1
13:21
1400 _
15:34
1600 _
17:48
20:01
2000 .
22:15
m
z: ••»•
a« i
2, sp*mm—>
_i
ZhB«—
^•MOMMB^^V
^:^MM«V
=T-^ * - — -
CI70 CHRYSENE-D12
240IS5* 01
1719-03-5
164IS6* 01
1520-96-3
CT
-------
Quantitat ion Report File: ST169808318
Data: ST16980831B.TI
08/31/98 13:35:00
Sample: 10UG/ML AP9 062598C
Conds.: INST. ID: F16
Formula: 1UL INJ.
Submitted by: OES
AMOUNT=AREA * REF AMNT/(REF
Resp.
No
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
No
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
Instrument: F16
Analyst: DAT
AREA
Weight:
Acct. No
0.000
.: FIN
* RESP FACT)
. fac. from Library Entry
Name
CI30 1.4-DICHLOROBENZENE-D4
CI40 NAPHTHALENE-08
CI50 ACENAPHTHENE-010
CI60 PHENANTHRENE-D10
CI70 CHRYSENE-D12
CITS PERYLENE-D12
PYRIDINE
1521S1* 01
1361 52* 01
164 1 S3* 01
188IS4* 01
240 1 55* 01
164IS6* 01
N-NITROSOMETHYLETHYLAMINE
METHYLMETHANESULFONATE
N-NITROSODIETHYLAMINE
ETHYLMETHANE SULFONATE
C361 ACETOPHENONE
N-NITROSOPYRROLIDINE
N-NITROSOMORPHOLINE
3-METHYL PHENOL
N-NITROSOPIPERIDINE
2,6-DICHLOROPHENOL
79
42
80
102
79
105
100
56
51* 20
51* 40
SDK 60
S1* 70
51* 85
S1#170
S1#175
51*180
3855-82-1
1146-65-2
15067-26-2
1517-22-2
1719-03-5
1520-96-3
110-86-1
10595-95-6
55-18-5
66-27-3
930-55-2
59-89-2
108 51*182
N-NITROSOOI-N-BUTYLAMINE
1,2,4,5- TETRACHLOROBENZENE
42
162
84
214
1-CHLORONAPHTHALENE
1,3-DINITROBENZENE
PENTACHLOR08ENZENE
1-NAPHTHYLAMINE
2-NAPHTHYLAMINE
ISODRIN
CHLOR08ENZILATE
m/z Scan Time Ref
152 340 3:47 1
136 529 5:53 2
164 827 9:12 3
188 1085 12:04 4
240 1551 17:15 5
264 1782 19:49 6
79 103 1:09 1
42 157 1:45 1
80 181 2:01 1
102 216 2:24 1
79 253 2:49 1
105 401 4:28 1
100 399 4:26 1
56 407 4:32 1
108 416 4:38 1
42 447 4:58 2
162 551 6:08 2
1
1
1
1
1
1
0
0
0
0
0
1
1
1
1
0
1
RRT
.000
.000
.000
.000
.000
.000
.303
.462
.532
.635
.744
.179
.174
.197
.224
.845
.042
168
250
143
143
139
S2# 15
S2* 85
52*120
S3* 10
162 S3* 42
S3* 60
53*100
S3*110
53*115
54*120
100-T5-4
87-65-0
924-16-3
95-94-3
90-13-1
99-65-0
708-93-5
134-32-7
91-59-8
Meth Area(Hght) Amount
A
A
A
A
A
A
A
A
A
A
A
A
BB
29461
BB 109632
BB
59743
BB 100292
BB
BB
BB
BB
BB
BB
BB /
BB Y
qedt(£)
A
A
A
A
BB .A*
BB^
BB
BB
83642
69904
13033
5159
4559
3318
6780
13763
3544
6098
13612
8018
40.000
40.000
40.000
40.000
40.000
40.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
10.000
5546. 10.000
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
XTot
9.09
9.09
9
9
9
.09
.09
.09
9.09
2
2
.27
.27
2.27
2
2
2
2
2
2
2
2
.27
.27
.27
.27
.27
.27
.27
.27
-------
NO
18
19
20
21
22
23
24
25
26
No
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
!0
>1
!2
!3
!4
!5
!6
m/z
84
214
162
168
250
143
143
193
139
Scan
618
680
732
802
857
881
896
1269
1426
Time Ref RRT
6:
7:
8:
8:
9:
9:
9:
14:
15:
52 2
34 3
09 3
55 3
32 3
48 3
58 3
07 4
52 4
Ret(L) Ratio RRT(L)
3:47
5:54
9:13
12:05
17:16
19:50
1:09
1:45
2:01
2:25
2:50
4:30
4:30
4:34
4:40
5:01
6:08
6:54
7:34
8:09
8:56
9:33
9:49
10:00
14:08
15:52
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
0.99
0.99
0.99
0.99
0.99
0.99
0.99
0.99
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1
1
.000,
t
.000
1.000
1
1
1
0
0
0
0
0
1
1
1
1
0
1
1
0
.000
.000
.000
.303
.462
.535
.641
.750
.188
.191
.209
.232
.851
.042
.170
.822
0.885
0
1
1
1
1
1
.970
.036
.066
.086
.168
.313
1.168
0.822
0.885
0.970
1.036
1.065
1.083
1.170
1.314
Ratio
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
0.99
0.99
0.99
0.99
0.99
0.99
0.99
0.99
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
Heth
A BB
A BB
A BB
A BB
A BB
A BB
A BB
A BB
A BB
Amnt
40.00
40.00
40.00
40.00
40.00
40.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
Area(Hght)
5111.
6998.
22862.
2486.
7702.
12978.
13797.
3194.
9428.
Amnt(L)
40.00
40.00
40.00
40.00
40.00
40.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
10.00
R.
1
Amount
10.
10.
10.
10.
10.
10.
10.
10.
10.
Fac
.000
1.000
1
.000
1.000
1
1
1
0
0
0
0
1
0
0
1
0
0
0
0
1
0
0
0
0
0
0
.000
.000
.770
.700
.619
.450
.921
.869
.481
.828
.848
.293
.202
.186
.469
.531
.166
.516
.869
.924
000 KG/ML
000 UG/ML
000 UG/ML
000 UG/ML
000 UG/ML
000 UG/ML
000 UG/ML
000 UG/ML
000 UG/ML
R.Fac(L)
1.000
1.000
1.000
1.000
1.000
1.000
1.770
0.700
0.619
0.450
0.921
1.869
0.481
0.828
1.848
0.293
0.202
0.186
0.469
1.531
0.166
0.516
0.869
0.924
.127 0.127
.376 0.376
XTot
2.27
2.27
2.27
2.27
2.27
2.27
2.27
2.27
2.27
Ratio
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
.00
.00
.00
.00
.00
1.00
PEAK NOT FOUND
-------
188.0-
RIC+MASS CHROMATOGRAM DATA: ST1698883IB #1 SCANS 388 TO 440
08/31/98 13:35:00 CALI: ST1698083IB »3
SAMPLE: 18UG/ML AP9 062598C
CONDS.: INST. ID: F16
RANGE: G 1,2158 LABEL: N 2, 2.8 QUAN: A 6, 2.0 J 8 BASE: U 28, 3
399
856.
3544.
188
RIC
856.
188.830
± 8.588
45856.
1
448 SCAN
4:54 TIME
CT
-------
DATA FROM FILE: ST16980831C SCANS 230 TO 1200 ACQUIRED: 08/31/98 14:02:00
CALI: ST16980831C #3
SAMPLE: 20UG/ML AP9 0625980
CONDS.: INST. ID: F16
100.07. < 93952.)
CI30 1,4-DICHLOROBENZENE-D4 152ISH» 01
1000 _
11:07
ffli J
CI48 NAPHTHALENE-08
3855-82-1
136IS2tt 01
6*50 ACENAPHTHENE-010 164IS3* 01
CI60 PHENANTHRENE-D10
188IS4* 01
1146-65-2
15067-26-2
1517-22-2
CT
*>•
CO
-------
DATA FROM FILE: ST16980831C SCANS 1200 TO 2158 ACQUIRED: 08/31/98 14:02:00
CALI: ST16980831C #3
SAMPLE: 20UG/ML AP9 062598D
CONDS.: INST. ID: F16
1200 .
13:21
1400 .
15:34
1600 .
17:48
j
100.0% < 80000.)
CI70 CHRYSENE-D12
240IS5tt 01
1719-03-5
1800
26:01
2000
22:15
TT&E
CI75 F WLENE-D12
164IS6* 01
1520-96-3
cr
-------
antitat ion Report File: ST16980831C
ta: ST16980831C.TI
/31/98 14:02:00
upte: 20UG/HL AP9 0625980
nds.: INST. 10: F16
rmuta: 1UL INJ. Instrument: F16
bcmtted by: QES Analyst: DAT
OUNT=AREA * REF AMNT/(REF AREA
sp.
0
1
2
3
t>
5
6
7
8
9
0
1
2
3
4
5
6
7
8
9
'0
'1
!2
!3
14
!5
!6
!7
!8
!9
SO
>i
!2
S3
54
55
56
57
58
59
.0
il
V2
;3
w
V5
'.6
.7
fac. from Library Entry
Name
CI30 1.4-DICHLOROBENZENE-D4
CI40 NAPHTHALENE-08
CI50 ACENAPHTHENE-D10
CI60 PHENANTHRENE-D10
C170 CHRYSENE-D12
CI75 PERYLENE-D12
PYR1DINE
2-P1COLINE
N-NITROSOMETHYLETHYLAMINE
METHYLMETHANESULFONATE
N-NITROSODIETHYLAMINE
ETHYLMETHANE SULFONATE
PENTACHLOROETHANE
C361 ACETOPHENONE
N-NITROSOPYRROLIDINE
N-N1TROSOMORPHOLINE
3-METHYL PHENOL
0-TOLUIDINE
N-NITROSOPIPER1DINE
AA-DIMETHYLPHENETHYLAHINE
2,6-DICHLOROPHENOL
HEXACHLOROPROPENE
P-PHENYLENE DIAMINE
N-NITROSOOI-N-BUTYLAMINE
SAFROLE
1 ,2,4,5-TETRACHLOROBENZENE
1SOSAFROLE (#1)
ISOSAFROLE (#2)
1-CHLORONAPHTHALENE
1,4-NAPHTHOOUINONE
1,3-D1N1TROBENZENE
PENTACHLOROBENZENE
1-NAPHTHYLAMINE
2-NAPHTHYLAMINE
2,3,4,6-TETRACHLOROPHENOL
5-NITRO-O-TOLUIDINE
SYM-TR1NITROBENZENE
PHENACETIN
DIALLATE 234
4-AMINOBIPHENYL
PRONAMIDE
PENTACHLORONITROBENZENE
2SECBUTYL-4,6-DINITROPHENOL
4-NITROOUINOLINE-1-OXIDE
METHAPYRILENE
ISOOR1N
CHLOROBENZILATE
* RESP FACT)
152IS1* 01
136IS2* 01
164IS3# 01
188IS4* 01
2401S5* 01
1641S6* 01
79 S1# 20
93 S1# 30
42 S1# 40
80 S1# 60
102 S1# 70
79 S1# 85
117 S1# 95
105 S1#170
100 S1#175
56 S1#180
108 S1#182
106 S1#195
42 S2# 15
58 S2# 50
162 S2# 85
213 S2# 90
108 S2
-------
NO
48
49
50
No
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
Name
ARAMITE (#1)
ARAMITE (#2)
P-DIMETHYLAMINOAZOBENZENE
m/z
152
136
164
188
240
264
79
93
42
80
102
79
117
105
100
56
108
106
42
58
162
213
108
84
162
214
162
104
162
158
168
250
143
143
232
152
75
108
234
169
173
237
211
190
58
193
139
185
185
120
Scan
340
529
827
1086
1551
1782
103
145
156
181
216
253
301
402
400
407
416
406
447
646
551
548
656
618
647
680
698
737
732
768
802
857
881
896
894
938
1025
1030
1017
1067
1093
1060
1107
1235
1264
1269
1426
1398
1413
1410
Time
3:47
5:53
9:12
12:05
17:15
19:49
1:09
1:37
1:44
2:01
2:24
2:49
3:21
4:28
4:27
4:32
4:38
4:31
4:58
7:11
6:08
6:06
7:18
6:52
7:12
7:34
7:46
8:12
8:09
8:33
8:55
9:32
9:48
9:58
9:57
10:26
11:24
11:27
11:19
11:52
12:09
11:47
12:19
13:44
14:04
14:07
15:52
15:33
15:43
15:41
Ref
1
2
3
4
5
6
1
1
1
1
1
1
1
1
1
1
1
1
2
2
2
2
2
2
2
3
3
3
3
3
3
3
3
3
3
3
4
4
4
4
4
4
4
4
4
4
4
5
5
5
RRT
1.000
1.000
1.000
1.000
1.000
1.000
0.303
0.426
0.459
0.532
0.635
0.744
0.885
1.182
1.176
1.197
1.224
1.194
0.845
1.221
1.042
1.036
1.240
1.168
1.223
0.822
0.844
0.891
0.885
0.929
0.970
1.036
1.065
1.083
1.081
1.134
0.944
0.948
0.936
0.983
1.006
0.976
1.019
1.137
1.164
1.169
1.313
0.901
0.911
0.909
185 S5# 20
185 S5# 25
120 S5# 30
Meth
A
A
A
A
A
A
A
A
A
A
A
A
A
A
q<
A
A
A
A
q«
A
A
BB
BB
BB
BB
BV
BB
BB
BB
BB
BB
BB
BB
BB
BB
idt
BV
BB
BB
BB
xit
BB
BB
qedt
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
BB
BB
BB
BB
BB
BV
BB
BB
BB
BB
VB
BB
BB
BB
BB
BB
BB
BB
BB
BB
BB
BB
BB
BB
BB
BB
BB
Area(Hght)
28379.
104398.
58510.
99710.
75805.
63674.
22463.
22172.
10461.
9765.
7176.
14300.
8682.
28725.
(|) 7882.
11884.
v 30227.
^ 34950.
*" 16262.
(\) 82208.
^ 12238.
^10240.
\£) 8496.
10715.
12848.
12617.
1336.
5880.
32113.
11800.
5576.
14750.
25121.
28484.
8117.
10100.
7446.
15198.
4406.
32077.
15570.
4036.
6506.
2912.
21120.
6234.
17520.
2154.
3074.
15810.
140-57-8
140-57-8
60-11-7
Amount
40.000
40.000
40.000
40.000
40.000
40.000
20.000
20.000
20.000
20.000
20.000
20.000
20.000
20.000
20.000
20.000
20.000
20.000
20.000
20.000
20.000
20.000
20.000
20.000
20.000
20.000
20.000
20.000
20.000
20.000
20.000
20.000
20.000
20.000
20.000
20.000
20.000
20.000
20.000
20.000
20.000
20.000
20.000
20.000
20.000
20.000
20.000
20.000
20.000
20.000
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
XTot
3.28
3.28
3.28
3.28
3.28
3.28
1.64
1.64
1.64
1.64
1.64
1.64
1.64
1.64
1.64
1.64
1.64
1.64
1.64
1.64
1.64
1.64
1.64
1.64
1.64
1.64
1.64
1.64
1.64
1.64
1.64
1.64
1.64
T.64
1.64
1.64
1.64
1.64
1.64
1.64
1.64
1.64
1.64
1.64
1.64
1.64
1.64
1.64
1.64
1.64
-------
0
1
2
3
4
5
6
7
8
9
0
1
2
3
4
5
5
7
3
?
D
1
?
5
*
>
3
r
3
?
)
1
>
i
>
t
>
r
1
)
)
'
)
'
)
'
1
)
1
RetU)
3:47
5:54
9:13
12:05
17:15
19:49
1:09
1:37
1:45
2:01
2:25
2:50
3:22
4:30
4:30
4:34
4:40
4:32
5:01
7:54
6:08
6:06
7:25
6:54
7:12
7:34
7:46
8:12
8:09
8:34
8:56
9:33
9:49
10:00
9:57
10:27
11:24
11:30
11:19
11:53
12:11
11:48
12:19
13:45
14:05
14:08
15:52
15:34
15:44
15:42
Ratio
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
0.99
0.99
0.99
0.99
1.00
1.00
0.99
0.99
0.99
1.00
0.99
0.91
1.00
1.00
0.98
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
RRT(L)
1.000
1.000
1.000
1.000
1.000
1.000
0.303
0.426
0.462
0.535
0.641
0.750
0.888
1.188
1.191
1.209
1.232
1.200
0.851
1.340
1.042
1.036
1.258
1.170
1.223
0.822
0.843
0.890
0.885
0.930
0.970
1.036
1.066
1.086
1.081
1.135
0.943
0.951
0.937
0.983
1.008
0.976
1.019
1.137
1.165
1.168
1.313
0.902
0.912
0.910
Ratio
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
0.99
0.99
0.99
0.99
1.00
^,00
0.99
0.99
0.99
1.00
0.99
0.91
1.00
1.00
0.99
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
Amnt
40.00
40.00
40.00
40.00
40.00
40.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
Amnt(L)
40.00
40.00
40.00
40.00
40.00
40.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
20.00
R.Fac R.
1.000
1.000
1.000
1.000
1.000
1.000
1.583
1.563
0.737
0.688
0.506
1.008
0.612
2.024
0.555
0.838
2.130
2.463
0.312
1.575
0.234
0.196
0.163
0.205
0.246
0.431
0.046
0.201
1.098
0.403
0.191
0.504
0.859
0.974
0.277
0.345
0.149
0.305
0.088
0.643
0.312
0.081
0.130
0.058
0.424
0.125
0.351
0.057
0.081
0.417
Fac(L)
1.000
1.000
1.000
1.000
1.000
1.000
1.583
1.563
0.737
0.688
0.506
1.008
0.612
2.024
0.555
0.838
2.130
2.463
0.312
1.575
0.234
0.196
0.163
0.205
0.246
0.431
0.046
0.201
1.098
0.403
0.191
0.504
0.859
0.974
0.277
0.345
0.149
0.305
0.088
0.643
0.312
0.081
0.130
0.058
0.424
0.125
0.351
0.057
0.081
0.417
Ratio
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
-------
Quantitat ion Report File: ST169S0831C
Data: ST16980831C.TI
08/31/98 14:02:00
Sample: 20UG/ML AP9 0625980
Conds.: INST. ID: F16
Formula: 1UL INJ. Instrument: F16
Submitted by: QES Analyst: DAT
Weight: 0.000
Acct. No.: FIN
AMOUNT=AREA * REF AMNT/CREF AREA * RESP FACT)
Resp.
No
51
52
53
54
55
56
No
51
52
53
54
55
56
No
51
52
53
54
55
56
fac. from Library Entry
Name
3,3'-DIMETHYLBENZIDINE 212 S5# 35
KEPONE 272 S5# 37
2-ACETYLAMINOFLUORENE 181 S5# 45
3-METHYLCHOLANTHRENE 268 S5# 85
7. 12-DIMETHYLBENZANTHRACENE 256 S6# 20
HEXACHLOROPHENE 196 S6# 30
m/z Scan Time Ref RRT Meth Area(Hght)
212 1472 16:22 5 0.949 A BBft/ 19802.
272 1455 16:11 5 0.938 qedt(j) 4676.
181 1514 16:50 5 0.976 A BB .I1 15324.
268 1830 20:21 5 1.180 A BB»X 22226.
256 1729 19:14 6 0.970 A BB 19376.
NOT FOUND
Ret(L) Ratio RRT(L) Ratio Amnt Amnt(L) R
16:22 1.00 0.949 1.00 20.00 20.00
16:13 1.00 0.940 1.00 20.00 20.00
16:52 1.00 0.977 1.00 20.00 20.00
20:23 1.00 1.181 1.00 20.00 20.00
19:15 1.00 0.971 1.00 20.00 20.00
21:11 0.992
53-96-3
56-49-5
75-97-6
70-30-4
Amount
20.000 UG/ML
20.000 UG/ML
20.000 UG/ML
20.000 UG/ML
20.000 UG/ML
.Fac R.Fac(L)
0.522 0.522
0.123 0.123
0.404 0.404
0.586 0.586
0.609 0.609
XTot
1.64
1.64
1.64
1.64
1.64
Ratio
1.00
1.00
1.00
1.00
1.00
,!ANUAL EDIT CUUtb
I. PEAK NOT FOUND
>. POORCHROMATOQRAPhv
3. WRONG ISOMER
Ml MANUAL EDITS MUST BE
, DATED, AND COr;, I,
-------
100.0-
100
RIC
DATA: ST16980831C #1
CALI: ST16980831C #3
SCANS 380 TO 440
RIC+MASS CHROMATOGRAM
08/31/98 14:02:00
SAMPLE: 20UG/ML AP9 062598D
CONDS.: INST. ID: F16
RANGE: G 1,2158 LABEL: N 2, 2.0 QUAN: A 6, 2.0 J 0 BASE: U 20, 3
400
1972.
7882.
1972.
100.030
± 0.500
85632.
1
440 SCAN
4:54 TIME
-------
DATA: ST16980831C #1
CALI: ST16980831C #3
SCANS 480 TO 800
100.0-1
RIC+MASS CHROMATOGRAM
08/31/98 14:02:00
SAMPLE: 20UG/ML AP9 062598D
RANGE!'G 1*2158 LABEL: N 0, 2.9 QUAN: A 6, 2.0 j 0 BASE: u 20, 3
OHO
58
512
529
551
529
704 _ 721
«*'
2796.
58.017
± 0.500
751
f>71 789
' f^r~r ^"" f- "~
86528.
686
RIC
491
560
548
511
732
647
618
699
769
714
CT
cn
500
5:34
550
6:07
600
6148
650
7:14
700
7:47
8i21
800 SCAN
8:54 TIME
-------
RIC+MASS CHROMATOGRAM
08/31x98 14:02:00
SAMPLE: 20UG/ML AP9 062598D
CONDS.: IHST. ID: F16
RANGE: G 1,2158 LABEL: N 0,
DATA: ST16980831C #1
CALI: ST16980831C #3
2.0 QUAN: A 6, 2.0 J 0
100.0-1
SCANS 600 TO 730
BASE: U 20,
680
108
RIC
1230.
108.032
± 0.500
56384.
SCAN
TIME
-------
100.0-
RIC+MASS CHROMATOGRAM DATA: ST16980831C #1 SCANS 1430 TO 1550
08/31/98 14:02:00 CALI: ST16980831C #3
SAMPLE: 20UG/ML AP9 0625980
CONDS.: INST. ID: F16
RANGE: G 1,2158 LABEL: N 0, 2.0 QUAN: A 6, 2.0 J 0 BASE: U 20. 3
1455
272
460.
272.081
± 0.500
62080.
RIC
1455
1443 1449
I
1440
16:01
1460
16:14
1472
1480
!5:28
cr
en
01
1495 1502
I
1500
16:41
1514
153;
1520
16:54
1540
17:08
SCAN
TIME
-------
DATA FROM FILE: ST1698983ID SCANS 230 TO 1200 ACQUIRED: 08/31/98 14:32:00
CALI: ST1698083ID #3
SAMPLE: 50UG/ML AP9 062598E
CONDS.: INST. ID: F16
600 _
6:40
880
8:54
1000 _
11:07
•
I
I
I
100.0Z < 198656.)
,4-DICHLOROBENZENE-D4 152ISltt 01
3855-82-1
CI40 NAPHTHALENE-OS
136IS2* 01
CI50 ACENAPHTHENE-D10
164IS3* 01
CI60 PHENANTHRENE-D10
188IS4* 01
1146-65-2
15067-26-2
1517-22-2
cr
en
en
-------
DATA FROM FILE: ST1698083ID SCANS 1200 TO 2158 ACQUIRED: 08/31x98 14:32:00
CALI: ST1698083ID #3
SAMPLE: 50UG/ML AP9 062598E
CONDS.: INST. ID: F16
100.0Z < 86016.)
1200 I I I l
13:21
1400 .
15:34
1600 _
17:48
^__
*"^
L M
c
1800 _
28:81
2000
22:15
ffll
240IS5* 01
1719-03-5
CI75 PERYLENE-D12
164IS6* 01
1520-96-3
CT
-------
jantitation Report File: ST16980831D
ata: ST16980831D.TI
3/31/98 14:32:00
ample: 50UG/ML AP9 062S98E
snds.: INST. 10: F16
Drmula: 1UL INJ. Instrument: F16
jbmitted by: QES Analyst: DAT
10UNT=AREA * REF AMNTAREF AREA
esp
to
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
50
51
52
53
54
55
56
57
58
59
40
11
12
13
. fac. from Library Entry
Name
CI30 1.4-DICHLOROBENZENE-D4
CI40 NAPHTHALENE-.P8
C150 ACENAPHTHENE-D10
CI60 PHENANTHRENE-D10
CI70 CHRYSENE-D12
CITS PERYLENE-012
PYRIDINE
2-PICOLINE v
N-NITROSOMETHYLETHYLAMINE
METHYLMETHANESULFONATE
N-NITROSODIETHYLAMINE
ETHYLMETHANE SULFONATE
PENTACHLOROETHANE
C361 ACETOPHENONE
N-NITROSOPYRROLIDINE
N-NITROSOMORPHOLINE
3-METHYL PHENOL
0-TOLUIDINE
N-NITROSOPIPER1DINE
AA-DIMETHYLPHENETHYLAMINE
2,6-DICHLOROPHENOL
HEXACHLOROPROPENE
P-PHENYLENE DIAMINE
N-NITROSODI-N-BUTYLAMINE
SAFROLE
1 ,2,4,5-TETRACHLOROBENZENE
ISOSAFROLE (#1)
ISOSAFROLE (#2)
1 -CHLORONAPHTHALENE
1,4-NAPHTHOQUINONE
1,3-DINITROBENZENE
PENTACHLOROBENZENE
1-NAPHTHYLAMINE
2-NAPHTHYLAMINE
2.3,4,6-TETRACHLOROPHENOL
5-NITRO-O-TOLUIDINE
SYM-TR1NITROBENZENE
PHENACET1N
DIALLATE 234
4-AMINOBIPHENYL
PRONAMIDE
PENTACHLORON I TROBENZENE
2SECBUTYL-4,6-DINITROPHENOL
* RESP FACT)
152IS1* 01
136IS2* 01
164 1 S3* 01
188IS4* 01
240 I S5* 01
164IS6* 01
79 S1# 20
,93 S1# 30
' 42 31* 40
80 S1* 60
102 S1* 70
79 SI* 85
117 51* 95
105 S1#170
100 S1#175
56 51*180
108 51*182
106 51*195
42 52* 15
58 S2* 50
162 S2* 85
213 S2* 90
108 S2#115
84 S2*120
152 52*140
214 S3* 10
162 S3* 15
104 S3* 35
162 S3* 42
158 S3* 50
168 S3* 60
250 53*100
143 S3#110
143 S3#115
232 53*120
152 53*145
75 54* 25
108 S4*35
S4* 37
169 S4* 45
173 S4* 55
237 S4* 60
211 S4# 75
Weight:
Acct. No.
3855-82-1
1146-65-2
15067-26-2
1517-22-2
1719-03-5
1520-96-3
110-86-1
109-06-8
10595-95-6
55-18-5
66-27-3
76-01-7
930-55-2
59-89-2
95-53-4
100-75-4
122-09-8
87-65-0
106-50-3
924-16-3
94-59-7
95-94-3
120-58-1
120-58-1
90-13-1
130-15-4
99-65-0
708-93-5
134-32-7
91-59-8
58-90-2
99-52-5
62-44-2
92-67-1
23950-58-5
82-68-8
88-85-7
17
4-NITROQUINOLINE-1-OXIDE 190 S4#100
METHAPYRILENE 58 54*105
1SOORIN
CHLOROBENZILATE 139 S4#120
0.000
FIN
91-80-5
-------
No
48
49
50
No
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
Name
ARAMITE (#1) 185 S5# 20
ARAMITE (#2) 185 S5# 25
P-DIMETHYLAMINOAZOBENZENE 120 S5# 30
m/z
152
136
164
188
240
264
79
93
42
80
102
79
117
105
100
56
108
106
42
58
162
213
108
84
162
214
162
104
162
158
168
250
143
143
232
152
75
108
234
169
173
237
211
190
58
193
139
185
185
120
Scan
340
529
828
1086
1551
1782
103
145
157
182
217
254
302
403
402
409
417
407
449
685
551
548
618
619
647
680
698
737
732
769
802
857
882
897
895
938
1025
1032
1017
1068
1094
1060
1107
1235
1265
1270
1427
1399
1413
1411
Time
3:47
5:53
9:13
12:05
17:15
19:49
1:09
1:37
1:45
2:01
2:25
2:50
3:22
4:29
4:28
4:33
4:38
4:32
5:00
7:37
6:08
6:06
6:52
6:53
7:12
7:34
7:46
8:12
8:09
8:33
8:55
9:32
9:49
9:59
9:57
10:26
11:24
11:29
11:19
11:53
12:10
11:47
12:19
13:44
14:04
14:08
15:52
15:34
15:43
15:42
Ref
1
2
3
4
5
6
1
1
1
1
1
2
2
2
2
2
2
2
3
3
3
3
3
3
3
3
3
3
3
4
4
4
4
4
4
4
4
4
4
4
5
5
5
RRT
1.000
1.000
1.000
1.000
1.000
1.000
0.303
0.426
0.462
0.535
0.638
0.747
0.888
1.185
1.182
1.203
1.226
1.197
0.849
1.295
1.042
1.036
1.168
1.170
1.223
0.821
0.843
0.890
0.884
0.929
0.969
1.035
1.065
1.083
1.081
1.133
0.944
0.950
0.936
0.983
1.007
0.976
1.019
1.137
1.165
1.169
1.314
0.902
0.911
0.910
Meth
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
BB
BB
BV
BB
VB
66
BB
BB
BB
BB
BB
BB
BB
BV
BB
BB ^
BB >
BB -*5.
BB *"
qedt(f)
A
A
BB
BB
qedt(T)
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
BB
BB 4
BB ^
88
BB
BV
BB
BB
BB
BB
BB
BB
BB
88
BB
BB
VB
BB
BB
BV
BB
BB
BB
BB
VB
BB
BB
140-57-8
140-57-8
60-11-7
Area(Hght) Amount
28687.
104087.
58806.
103078.
69225.
57648.
56577.
57154.
29520.
24557.
18688.
40170.
21710.
70275.
20603.
29437.
83872 .
79912.
42444.
176012.
34375.
26126.
21776.
27751.
32194.
31894.
3066.
14360.
82983.
31543.
14862.
35528.
65362.
76505 .
22189.
27016.
20893.
41692.
11272.
85529.
40637.
10186.
21220.
9477.
43644.
16648.
42346.
5450.
7782.
36805.
40.000
40.000
40.000
40.000
40.000
40.000
50.000
50.000
50.000
50.000
50.000
50.000
50.000
50.000
50.000
50.000
50.000
50.000
50.000
50.000
50.000
50.000
50.000
50.000
50.000
50.000
50.000
50.000
50.000
50.000
50.000
50.000
50.000
50.000
50.000
50.000
50.000
50.000
50.000
50.000
50.000
50.000
50.000
50.000
50.000
50.000
50.000
50.000
50.000
50.000
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
XTot
1.49
1.49
1.49
1.49
1.49
.49
.86
.86
.86
.86
.86
1.86
1.86
1.86
1.86
1.86
1.86
1.86
1.86
1.86
1.86
1.86
1.86
1.86
1.86
1.86
1.86
1.86
1.86
1.86
1.86
1.86
1.86
.86
.86
.86
.86
.86
.86
1.86
1.86
1.86
1.86
1.86
1.86
1.86
1.86
1.86
1.86
1.86
-------
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-------
Quantitat ion Report
File: ST16980831D
Data: ST16980831D.TI
08/31/98 14:32:00
Sample: 50UG/ML AP9 062S98E
Conds.: INST. ID: F16
Formula: 1UL INJ. Instrument: F16
Submitted by: QES Analyst: DAT
AMOUNT=AREA * REF AMNT/CREF AREA
Resp
No
51
52
53
54
55
56
No
51
52
53
54
55
56
No
51
52
53
54
55
56
. fac. from Library Entry
Name
3,3'-DIMETHYLBENZIDlNE
KEPONE
2-ACETYLAMINOFLUORENE
3-METHYLCHOLANTHRENE
7,12-DIMETHYLBENZANTHRACENE
HEXACHLOROPHENE
m/z Scan Time Ref RRT
212 1472 16:22 5 0.949
272 1472 16:22 5 0.949
181 1515 16:51 5 0.977
268 1831 20:22 5 1.181
256 1730 19:15 6 0.971
NOT FOUND
Ret(L) Ratio RRT(L) Ratio
16:22 1.00 0.949 1.00
16:13 1.01 0.940 1.01
16:52 1.00 0.977 1.00
20:23 1.00 1.181 1.00
19:15 1.00 0.971 1.00
21:11 0.992
Weight: 0.000
Acct. No.: FIN
* RESP FACT)
212 S5#
272 S5#
181 S5*
268 S5#
256 So*
196 So*
35
37
45
85
20
30
Meth ., Area(Hght)
A 88 V 38968.
qedt(£
A BB .»
*v
A BB
Amnt
50.00
50.00
50.00
50.00
50.00
) 7520.
^ 38918.
49854.
44288.
Amnt(L) R
50.00
50.00
50.00
50.00
50.00
53-96-3
56-49-5
75-97-6
70-30-4
Amount
50.000 UG/ML
50.000 UG/ML
50.000 UG/ML
50.000 UG/ML
50.000 UG/ML
.Fac R.Fac(L)
0.450 0.450
0.087 0.087
0.450 0.450
0.576 0.576
0.615 0.615
XTot
1.86
1.86
1.86
1.86
1.86
Ratio
1.00
1.00
1.00
1.00
1.00
.1ANUAL EDIT CODES
I. PEAK NOT FOUND
2. POOR CHROMATOGRAPHV
3. WRONG ISOMER
UL MANUAL EDITS MUST BE
>, DATED, AMD COrvt.
-------
RIC+MASS CHROMATOGRAM
08/31/98 14:32:00
SAMPLE: 50UG/ML APS 0G2598E
CONDS.: INST. ID: F16
RANGE: G 1,2158 LABEL: N 0,
DATA: ST1698083ID #1
CALI: ST1698083ID #3
2.0 QUAN: A 6, 2.0 J 0
108.0-
SCANS 480 TO 800
BASE: U 20,
685
58
RIC
5152.
58.017
± 0.530
146432.
750
8:21
800 SCAN
8:54 TIME
-------
100.6-1
RIC+MASS CHROMATOGRAM DATA: ST16988831D #1 SCANS 590 TO 720
08/31/98 14:32:00 CALI: ST16980831D #3
SAMPLE: 50UG/ML AP9 062598E
CONDS.: INST. ID: F16
RANGE: G 1.2158 LABEL: N 0/2.0 QUAN: A 6, 2.0 J 0 BASE: U 20, 3
681
108
RIC
593
G00
6:40
619
638 646
,r
647
635
664
648
7s 07
660
7:20
3304.
108.032
± 0.500
146432.
1
720 SCAN
8:01 TIME
CO
-------
DATA: ST1698083ID #1
CALI: ST1698083ID *3
SCANS 1430 TO 1560
100.0-1
RIC+MASS CHROMATOGRAM
08/31/98 14:32:00
SAMPLE: 50UG/ML AP9 062598E
CONDS.: INST. ID: F16
RANGE: G 1,2158 LABEL: N Q, 2.0 QUAN: A 6, 2.0 J 0 BASE: U 20, 3
1472
1516
272
RIC
138.
272.081
± 0.500
76288.
^±= !
1440
•~* 16:01
1458 J
1 '
1460
16:14
V
1 '
1480
16:28
1502 )
T --""'•* '
1500
16:41
^__
1520
16:54
1532
1539 J
1540
17:08
^_f
1560
17:21
SCAN
TIME
cn
-------
DATA FROM FILE: ST16980831A SCANS 230 TO 1200 ACQUIRED: 08/31/98 13:07:00
CALI: ST16980831A #3
SAMPLE: 80UG/ML AP9 062598F
CONDS.: INST. ID: F16
j
100.02 < 296960.)
HLOROBENZENE-D4 152ISI* 01 3855-82-1
CTTO NAPHTHALENE-08
CI50 ACENAPHTHENE-D10
136IS2* 01 1146-65-2
164IS3* 0. 15067-26-2
60 PHENANTHRENE-D10 188IS4* 01 1517-22-2
CT!
C.fJ
CM
-------
DATA FROM FILE: ST16980831A SCANS 1200 TO 2158 ACQUIRED: 08/31/98 13:07:00
CALI: ST16980831A #3
SAMPLE: 80UG/ML AP9 062598F
CONDS.: INST. ID: F16
1268
13:21
1400 _
15:34
1600 _
17:48
1800 _|
20:01
2000 _
22:15
100.0Z < 139520.)
— CI70 CHRYSENE-D12
240155tt 01
1719-03-5
CI75 PERYLENE-D12
164IS6* 01
1520-96-3
cn
en
-------
Quantitation Report File: ST16980831A
Data: ST16980831A.TI
08/31/98 13:07:00
Sample: 80UG/ML AP9 062598F
Conds.: 1NST. ID: F16
Formula: 1UL INJ. Instrument: F16
Submitted by: QES Analyst: OAT
AMOUNT=AREA * REF AMNT/(REF AREA
Resp
No
1
2
3
4
5
6
7
a
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
. fac. from Library Entry
Name
C130 1,4-OICHLOROBENZENE-D4
CI40 NAPHTHALENE-08
CI50 ACENAPHTHENE-010
CI60 PHENANTHRENE-010
CI70 CHRYSENE-D12
CITS PERYLENE-D12
PYRIDINE
2-PICOLINE
N-NITROSOMETHYLETHYLAHINE
METHYLMETHANESULFONATE
N-N1TROSODIETHYLAMINE
ETHYLMETHANE SULFONATE
PENTACHLOROETHANE
C361 ACETOPHENONE
N-NITROSOPYRROLIDINE
N-N1TROSOMORPHOLINE
3-METHYL PHENOL
0-TOLUIDINE
N-NITROSOPIPERIDINE
AA-DIMETHYLPHENETHYLAMINE
2,6-DICHLOROPHENOL
HEXACHLOROPROPENE
P-PHENYLENE OIAMINE
N-NITROSOOI-N-BUTYLAMINE
SAFROLE
1,2,4,5-TETRACHLOROBENZENE
ISOSAFROLE (#1)
1SOSAFROLE 0*2}
1 -CHLORONAPHTHALENE
1,4-NAPHTHOQUINONE
1,3-DINITROBENZENE
PENTACHLOROBENZENE
1-NAPHTHYLAMINE
2-NAPHTHYLAMINE
2,3,4, 6- TETRACHLOROPHENOL
5-NITRO-O-TOLUIDINE
SYM-TRINITROBENZENE
PHENACETIN
DIALLATE 234
4-AMINOBIPHENYL
PRONAMIOE
PENT ACHLORON I TROBENZENE
2SEC8UTYL-4,6-OINITROPHENOL
4-NITROOUINOLINE-1 -OXIDE
METHAPYRILENE
ISODR1N
CHLOROBENZILATE
* RESP FACT)
152ISU 01
136IS2* 01
164IS3* 01
1881S4* 01
240IS5# 01
164IS6# 01
79 S1# 20
93 S1# 30
42 S1# 40
80 S1# 60
102 S1# 70
79 S1# 85
117 S1# 95
105 S1#170
100 51*175
56 S1#180
108 S1#182
106 S1#195
42 S2# 15
58 S2# 50
162 S2# 85
213 S2# 90
108 S2#115
84 S2#120
152 S2#140
214 S3# 10
162 S3# 15
104 S3# 35
162 S3# 42
158 S3# 50
168 S3* 60
250 S3#100
143 S3#110
143 S3#115
232 S3#120
152 S3#145
75 S4# 25
108 S4#35
S4# 37
169 S4# 45
173 S4# 55
237 S4# 60
211 S4# 75
190 S4#100
58 S4#105
139 S4#120
Weight:
Acct. No
3855-82-1
1146-65-2
15067-26-2
1517-22-2
1719-03-5
1520-96-3
110-86-1
109-06-8
10595-95-6
55-18-5
66-27-3
76-01-7
930-55-2
59-89-2
95-53-4
100-75-4
122-09-8
87-65-0
106-50-3
924-16-3
94-59-7
95-94-3
120-58-1
120-58-1
90-13-1
130-15-4
99-65-0
708-93-5
134-32-7
91-59-8
58-90-2
99-52-5
62-44-2
92-67-1
23950-58-5
82-68-8
88-85-7
91-80-5
0.000
FIN
-------
0
8
9
0
0
1
2
3
4
5
6
7
8
9
0
1
2
3
;
5
i
T
5
•)
)
1
>
1
1
>
•
1
i
l
;
1
.
Name
ARAHITE (#1)
ARAMITE (#2)
P-OIHETHYLAMINOAZOBENZENE
m/z
152
136
164
188
240
264
79
93
42
80
102
79
117
105
100
56
108
106
42
58
162
213
108
84
162
214
162
104
162
158
168
250
143
143
232
152
75
108
234
169
173
237
211
190
58
193
139
185
185
120
Scan
340
530
828
1087
1551
1782
103
145
157
182
218
255
302
404
405
411
419
408
451
710
552
549
667
620
648
681
698
737
733
770
803
858
883
899
895
940
1025
1034
1018
1069
1096
1061
1108
1236
1266
1270
1427
1399
1414
1412
Time
3:47
5
9
12
17
19
1
1
1
2
2
2
3
4
4
4
4
4
5
7
6
6
7
6
7
7
7
8
8
8
8
9
9
10
9
10
11
11
11
11
12
11
12
13
14
14
15
15
15
15
:54
:13
:05
:15
:49
:09
:37
:45
:01
:25
:50
:22
:30
:30
:34
:40
:32
:01
:54
:08
:06
:25
:54
:12
-.34
:46
:12
:09
:34
:56
:33
:49
:00
:57
:27
:24
:30
:19
:53
:11
:48
:19
:45
:05
:08
:52
:34
:44
:42
Ref
1
2
3
4
5
6
1(
1
1
1
1
1
1
1
1
1
1
1
2
2
2
2
2
2
2
3
3
3
3
3
3
3
3
3
3
3
4
4
4
4
4
4
4
4
4
4
4
5
5
5
RRT
1.000
1.000
1.000
1.000
1.000
1.000
0.303
0.426
0.462
0.535
0.641
0.750
0.888
1.188
1.191
1.209
1.232
1.200
0.851
1.340
1.042
1.036
1.258
1.170
1.223
0.822
0.843
0.890
0.885
0.930
0.970
1.036
1.066
1.086
1.081
1.135
0.943
0.951
0.937
0.983
1.008
0.976
1.019
1.137
1.165
1.168
1.313
0.902
0.912
0.910
185 S5# 20
185 S5# 25
120 S5# 30
Meth
A BB
A BB
A BB
A BB
A BV
A BB
A BB
A BB
A BB
A BB
A BB
A BB
A BB
A BB
A BB •
A BV
-------
No
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
Ret(L)
3:47
5:54
9:13
12:05
17:15
19:49
1:09
1:37
1:45
2:01
2:25
2:50
3:22
4:30
4:30
4:34
4:40
4:32
5:01
7:54
6:08
6:06
7:25
6:54
7:12
7:34
7:46
8:12
8:09
8:34
8:56
9:33
9:49
10:00
9:57
10:27
11:24
11:30
11:19
11:53
12:11
11:48
12:19
13:45
14:05
14:08
15:52
15:34
15:44
15:42
Ratio
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
RRT(L)
1.000
1.000
1.000
1.000
1.000
1.000
0.303
0.426
0.462
0.535
0.641
0.750
0.888
1.188
1.191
1.209
1.232
1.200
0.851
1.340
1.042
1.036
1.258
1.170
1.223
0.822
0.843
0.890
0.885
0.930
0.970
1.036
1.066
1.086
1.081
1.135
0.943
0.951
0.937
0.983
1.008
0.976
1.019
1.137
1.165
1.168
1.313
0.902
0.912
0.910
Rat i o
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
Amnt
40.00
40.00
40.00
40.00
40.00
40.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
Amnt(L) R.Fac R.Fac(L) Ratio
40.00
40.00
40.00
40.00
40.00
40.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
1.000
1.000
1.000
1.000
1.000
1.000
1.587
1.577
0.876
0.602
0.549
1.168
0.605
1.945
0.562
0.805
2.408
2.129
0.327
1.036
0.280
0.197
0.038
0.225
0.250
0.430
0.043
0.196
1.528
0.447
0.210
0.493
0.765
0.996
0.310
0.381
0.172
0.316
0.089
0.602
0.301
0.079
0.163
0.076
0.205
0.128
0.308
0.061
0.090
0.420
1.000
1.000
1.000
1.000
1.000
1.000
1.587
1.577
0.876
0.602
0.549
1.168
0.605
1.945
0.562
0.805
2.408
2.129
0.327
1.036
0.280
0.197
0.038
0.225
0.250
0.430
0.043
0.196
1.528
0.447
0.210
0.493
0.765
0.996
0.310
0.381
0.172
0.316
0.089
0.602
0.301
0.079
0.163
0.076
0.205
0.128
0.308
0.061
0.090
0.420
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
-------
jantitation Report File: ST169S0831A
ata: ST16980831A.TI
3/31/98 13:07:00
ample: 80UG/HL AP9 062598F
3nds.: INST. ID: F16
irmula: 1UL INJ. Instrument: F16
Jbmitted by: QES Analyst: DAT
10UNT=AREA * REF AMNT/(REF AREA * RESP FACT)
Jsp. fac. from Library Entry
(0
11
i2
i3
14
15
16
lo
.1
.2
•3
4
5
6
0
1
2
3
4
5
6
Name
S.S'-DIMETHYLBENZIDiW
KEPONE
2-ACETYLAMINOFLUORENE
3-METHYLCHOLANTHRENE
7,12-OIMETHYLBENZANTHRACENE
HEXACHLOROPHENE
m/z Scan Time Ref
212 1472 16:22 5
272 1458 16:13 5
181 1516 16:52 5
268 1832 20:23 5
256 1731 19:15 6
NOT FOUND
RRT
0.949
0.940
0.977
1.181
0.971
Ret(L) Ratio RRT(L) Ratio
16:22 1.00 0.949 1
16:13 1.00 0.940 1
16:52 1.00 0.977 1
20:23 1.00 1.181 1
19:15 1.00 0.971 1
21:11 0.992
.00
.00
.00
.00
.00
212 S5#
272 S5#
181 S5#
268 S5#
256 S6#
196 S6#
1
Meth ^
A BB
35
37
45
85
20
30
L^?
> Area(Hght)
56612.
qedt^j) 12434.
A BB J
A BB&
A BB
Amnt
80.00
80.00
80.00
80.00
80.00
61022.
76474.
66838.
Aimt(L) R
80.00
80.00
80.00
80.00
80.00
Weight: 0.000
Acct. No.: FIN
53-96-3
56-49-5
75-97-6
70-30-4
Amount
80.000 UG/ML
80.000 UG/ML
80.000 UG/ML
80.000 UG/ML
80.000 UG/ML
.Fac R.Fac(L)
0.406 0.406
0.089 0.089
0.438 0.438
0.549 0.549
0.610 0.610
XTot
1
1
1
1
1
.92
.92
.92
.92
.92
Ratio
1
1
.00
.00
1.00
1
1
.00
.00
i. PEAK NOT FOUND
>-. POORCHROMATOQRAPh,
3. WRONG ISOMER
ML MANUAL EDITS MUST BE
', DATED, AND COCKL
-------
RIC+MASS CHROMATOGRAM
08x31/98 13:07:00
SAMPLE: 80UG/ML AP9 062598F
CONDS.: IHST. ID: F16
DATA: ST16980831A «1
CALI: ST16980831A #3
SCANS 480 TO 850
RANGE: G
100.0-
58
1.2158 LABEL: N 0, 2.0 QUAN: A 6, 2.0 J 0 BASE: U 20,
710
7528.
620
549
591
RIC
524
549
58.017
± 0.500
829
218112.
811
829
492 y\_ 1
500
5:34
550
6:07
595 ] \-
600
6:40
j V obO }
850 I.
?'. 14 r
V f ^s~ y^^
700
7:47
750
8:21
? y i j
800
8:54
1^-1- i
850 SCAN
9:27 TIME
cr.
-------
RIC+MASS CHROMATOGRAM
08/31/98 13:07:00
SAMPLE: 80UG/ML AP9 062598F
COHDS.: INST. ID: F16
RANGE: G 1,2158 LABEL: N 0, 2.0
DATA: ST16980831A #1
CALI: ST16980831A #3
SCANS 600 TO 800
20.0n
QUAN: A
681
6, 2.0 J 0 BASE: U 20, 3
108
862.8-1
RIC
1011.
108.032
± 0.508
43622.
750
8:21
800 SCAN
8:54 TIME
-------
100.0-
272
RIC
DATA: ST16980831A #1
CALI: ST16988831A #3
SCANS 1440 TO 1590
RICH-MASS CHROMATOGRAM
08/31/98 13:07:00
SAMPLE: 80UG/ML AP9 062598F
CONDS.: INST. ID: F16
RANGE: G 1,2158 LABEL: N 0, 2.0 QUAN: A 6, 2.0 J 0 BASE: U 20, 3
1458
1487
1500
1588
1560
17:21
1580
17i34
219.
272.081
± 0.500
94592.
SCAN
TIME
-------
DATA FROM FILE: ST1698083IE SCANS 230 TO 1200 ACQUIRED: 08/31/98 15:02:00
CALI: ST1698083IE #3
SAMPLE: 120UG/ML AP9 062598G
CONDS.: INST. ID: F16
800 .
8:54
1000 _
11:0?
iBENZENE-04 152IS1* 01
_L
_L
_L
J 100.0?: < 359424.)
136IS2# 01
CI50 ACENAPHTHENE-D10
164IS3K 01
£l£a_£tOJANTHRENE-D 10
188IS4* 01
3855-82-1
1146-65-2
15067-26-2
1517-22-2
CT
-------
DATA FROM FILE: ST1698083IE SCANS 1208 TO 2158 ACQUIRED: 08/31/98 15:02:00
CALI: ST1698083IE #3
SAMPLE: 120UG/ML AP9 062598G
CONDS.: INST. ID: F16
1200 .
13:21
1400
15:34 15
1600 .
17:48
1800 _
20:01
2000 _
22:15
I
I
I
J
100.03 ( 180736.)
240IS5* 01
1719-03-5
•CI75 PERYLENE-D12
164IS6* 1
1520-96-3
CT
~3
CM
-------
jantitat ion Report File: ST16980831E
ita: ST16980831E.TI
i/31/98 15:02:00
wnple: 120UG/ML AP9 062598G
>nds.: INST. ID: F16
>rmula: 1UL INJ. Instrument: F16
ibmitted by: QES Analyst: OAT
IOUNT=AREA * REF AMNT/CREF AREA
!Sp
lo
1
2
3
4
5
6
7
8
9
0
1
2
3
4
5
6
7
S
9
3
1
5
3
4
3
i
?
3
?
3
1
>
5
t
)
')
7
!
)
)
1
>
t
. fac. from Library Entry
Name
CI30 1,4-DICm.OROBENZENE-D4
CI40 NAPHTHALENE-08
CISO ACENAPHTHENE-D10
CI60 PHENANTHRENE-010
CI70 CHRYSENE-012
C175 PERYLENE-D12
PYRIOINE
2-PICOLINE
N-MITROSOMETHYLETHYLAMINE
METHYLMETHANESULFONATE
N-NITROSOOIETHYLAMINE
ETHYLMETHANE SULFONATE
PENTACHLOROETHANE
C361 ACETOPHENONE
N-NITROSOPYRROLIOINE
N-N1TROSOMORPHOLINE
3-METHYL PHENOL
0-TOLUIDINE
N-NITROSOPIPERIOINE
AA-DIMETHYLPHENETHYLAMINE
2,6-DICHLOROPHENOL
HEXACHLOROPROPENE
P-PHENYLENE OIAMINE
N-NITROSODI-N-BUTYLAMINE
SAFROLE
1,2,4,5-TETRACHLOROBENZENE
ISOSAFROLE (#1)
ISOSAFROLE (#2)
1-CHLORONAPHTHALENE
1,4-NAPHTHOOUINONE
1,3-DINITROBENZENE
PENTACHLOROBENZENE
1-NAPHTHYLAMINE
2-NAPHTHYLAMINE
2,3,4,6-TETRACHLOROPHENOL
5-NITRO-O-TOLUIDINE
SYM-TRINITROBENZENE
PHENACET1N
DIALLATE 234
4-AMINOBIPHENYL
PRONAMIOE
PENTACHLORONITROBENZENE
2SEC8UTYL-4,6-01NITROPHENOL
* RESP FACT)
1521S1* 01
136IS2* 01
164IS3# 01
188IS4* 01
240IS5* 01
164IS6* 01
79 S1# 20
93 S1# 30
42 SMt 40
80 S1# 60
102 S1# 70
79 S1# 85
117 S1# 95
105 31*170
100 S1#175
56"S1#180
108 S1#182
106 S1#195
42 S2# 15
58 S2# 50
162 S2# 85
213 S2# 90
108 S2#115
^84 S2#120
152 S2#140
214 S3# 10
162 S3# 15
104 S3# 35
162 S3# 42
158 S3# 50
168 S3* 60
250 S3HMOO
143 S3#110
143 S3#115
232 S3#120
152 S3#145
75 S4(» 25
108 S4#35
S4# 37
169 S4# 45
173 S4# 55
237 S4# 60
211 S4# 75
Weight: 0.000
Acct. No.: FIN
3855-82-1
1146-65-2
15067-26-2
1517-22-2
1719-03-5
1520-96-3
110-86-1
109-06-8
10595-95-6
55-18-5
66-27-3
76-01-7
930-55-2
59-89-2
95-53-4
100-75-4
122-09-8
87-65-0
106-50-3
924-16-3
94-59-7
95-94-3
120-58-1
120-58-1
90-13-1
130-15-4
99-65-0
708-93-5
134-32-7
91-59-8
58-90-2
99-52-5
62-44-2
92-67-1
23950-58-5
82-68-8
88-85-7
4-NITROQUINOLINE-1-OXIDE 190 S4#100
METHAPYRILENE 58 S4j*105
ISODRIN
CHLOROBENZILATE 139 S4#120
91-80-5
-------
No
48
49
50
No
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
Name
ARAHITE (#1) 185 S5# 20
ARAHITE (#2) 185 S5# 25
P-OIHETHYLAHINOAZOBENZENE 120 S5# 30
m/z
152
136
164
188
240
264
79
93
42
80
102
79
117
105
100
56
108
106
42
58
162
213
108
84
162
214
162
104
162
158
168
250
143
143
232
152
75
108
234
169
173
237
211
190
58
193
139
185
185
120
Scan
340
530
829
1087
1551
1782
103
145
157
183
218
255
302
404
408
413
420
409
453
518
553
549
620
621
648
682
698
738
734
770
804
859
884
900
897
941
1026
1037
1018
1070
1097
1062
1109
1236
1267
1270
1428
1400
1414
1412
Time
3:47
5:54
9:13
12:05
17:15
19:49
1:09
1:37
1:45
2:02
2:25
2:50
3:22
4:30
4:32
4:36
4:40
4:33
5:02
5:46
6:09
6:06
6:54
6:54
7:12
7:35
7:46
8:13
8:10
8:34
8:57
9:33
9:50
10:01
9:59
10:28
11:25
1 1 :32
11:19
11:54
12:12
11:49
12:20
13:45
14:06
14:08
15:53
15:34
15:44
15:42
Ref
1
2
3
4
5
6
1
1
1
1
1
1
1
1
1
1
1
1
2
2
2
2
2
2
2
3
3
3
3
3
3
3
3
3
3
3
4
4
4
4
4
4
4
4
4
4
4
5
5
5
RRT
1.000
1.000
1.000
1.000
1.000
1.000
0.303
0.426
0.462
0.538
0.641
0.750
0.888
1.188
1.200
1.215
1.235
1.203
0.855
0.977
1.043
1.036
1.170
1.172
1.223
0.823
0.842
0.890
0.885
0.929
0.970
1.036
1.066
1.086
1.082
1.135
0.944
0.954
0.937
0.984
1.009
0.977
1.020
1.137
1.166
1.168
1.314
0.903
0.912
0.910
Meth
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
BB
BB
BB
BB
BB
BB
BB
BB
BB
BB
BB
BB
BB
BB
BB
BV
BB
BB
BV
qedt
A
A
BB
BB
qedt
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
BB
BB
BB
BB
BB
BV
BB
BB
BB
BB
BB
BB
BB
VB
BB
BV
BB
BB
BB
VB
BB
BB
BB
BB
BB
BB
VB
140-57-8
140-57-8
60-11-7
Area(Hght) Amount
28744.
103999.
59122.
105381.
65508.
50966.
124986.
133361 .
74200.
53349.
47209.
102579.
51302.
164114.
49105.
fc 70419.
^ 206207.
^ 175232.
~ 105075.
Q/ 398258.
l_ 87089.
& 61908.
/ "S%
(U 51610.
69976.
76372.
73776.
7754.
33662.
201116.
71569.
37561.
83210.
154679.
173906.
54245.
65110.
52333.
104180.
27989.
186405.
91956.
25788.
50397.
25074.
88136.
40006.
93332.
12488.
17022.
81049^
40.000
40.000
40.000
40.000
40.000
40.000
120.000
120.000
120.000
120.000
120.000
120.000
120.000
120.000
120.000
120.000
120.000
120.000
120.000
120.000
120.000
120.000
120.000
120.000
120.000
120.000
120.000
120.000
120.000
120.000
120.000
120.000
120.000
120.000
120.000
120.000
120.000
120.000
120.000
120.000
120.000
120.000
120.000
120.000
120.000
120.000
120.000
120.000
120.000
tzo.ooo
UG/HL
UG/ML
UG/HL
UG/ML
UG/HL
UG/HL
UG/ML
UG/ML
UG/ML
UG/HL
UG/ML
UG/HL
UG/ML
UG/ML
UG/ML
UG/ML
UG/HL
UG/HL
UG/HL
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/HL
UG/HL
UG/HL
UG/ML
UG/ML
UG/ML
UG/ML
UG/HL
UG/HL
UG/ML
UG/ML
UG/ML
UG/ML
UG/HL
UG/ML
UG/HL
UG/HL
UG/HL
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/HL
XTot
0.65
0.65
0.65
0.65
0.65
0.65
.96
.96
.96
.96
.96
.96
.96
1.96
1.96
1.96
1.96
1.96
1.96
1.96
1.96
1.96
1.96
1.96
1.96
1.96
1.96
1.96
1.96
1.96
1.96
1.96
1.96
1.96
1.96
1.96
1.96
1.96
1.96
1.96
1.96
1.96
1.96
1.96
1.96
1.96
1.96
1.96
1.96
1.96
•J £;'
lo
-------
to
1
2
3
4
5
6
7
8
9
10
11
12
13
14
IS
16
17
18
19
!0
!1
!2
!3
!4
'5
!6
!7
!8
:9
•0
1
2
3
4
5
6
7
8
>9
0
1
2
3
4
5
6
7
8
9
0
RetU)
3:47
5:54
9:13
12:05
17:15
19:49
1:09
1:37
1:45
2:01
2:25
2:50
3:22
4:30
4:30
4:34
4:40
4:32
5:01
7:54
6:08
6:06
7:25
6:54
7:12
7:34
7:46
8:12
8:09
8:34
8:56
9:33
9:49
10:00
9:57
10:27
11:24
11:30
11:19
11:53
12:11
11:48
12:19
13:45
14:05
14:08
15:52
15:34
15:44
15:42
Ratio
1.00
1.00
1.00
1.00
.00
.00
.00
.00
.00
1.01
1.00
1.00
1.00
1.00
1.01
1.00
1.00
1.00
1.00
0.73
1.00
1.00
0.93
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
RRT(L)
1.000
1.000
1.000
1.000
1.000
1.000
0.303
0.426
0.462
0.535
0.641
0.750
0.888
1.188
1.191
1.209
1.232
1.200
0.851
1.340
1.042
1.036
1.258
1.170
1.223
0.822
0.843
0.890
0.885
0.930
0.970
1.036
1.066
1.086
1.081
1.135
0.943
0.951
0.937
0.983
1.008
0.976
1.019
1.137
1.165
1.168
1.313
0.902
0.912
0.910
Ratio
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.01
1.00
1.00
1.00
t.oo
1.01
1.00
1.00
1.00
1.00
0.73
1.00
1.00
0.93
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
Amnt
40.00
40.00
40.00
40.00
40.00
40.00
120.00
120.00
120.00
120.00
120.00
120.00
120.00
120.00
120.00
120.00
120.00
120.00
120.00
120.00
120.00
120.00
120.00
120.00
120.00
120.00
120.00
120.00
120.00
120.00
120.00
120.00
120.00
120.00
120.00
120.00
120.00
120.00
120.00
120.00
120.00
120.00
120.00
120.00
120.00
120.00
120.00
120.00
120.00
120.00
Amnt(L)
40.00
40.00
40.00
40.00
40.00
40.00
120.00
120.00
120.00
120.00
120.00
120.00
120.00
120.00
120.00
120.00
120.00
120.00
120.00
120.00
120.00
120.00
120.00
120.00
120.00
120.00
120.00
120.00
120.00
120.00
120.00
120.00
120.00
120.00
120.00
120.00
120.00
120.00
120.00
120.00
120.00
120.00
120.00
120.00
120.00
120.00
120.00
120.00
120.00
120.00
R.Fac R.
1.000
1.000
1.000
1.000
1.000
1.000
1.449
1.547
0.860
0.619
0.547
1.190
0.595
1.903
0.569
0.817
2.391
2.032
0.337
1.276
0.279
0.198
0.165
0.224
0.245
0.416
0.044
0.190
1.134
0.404
0.212
0.469
0.872
0.980
0.306
0.367
0.166
0.330
0.089
0.590
0.291
0.082
0.159
0.079
0.279
0.127
0.295
0.064
0.087
0.412
Fac(L) Ratio
1.000
1.000
1.000
1.000
1.000
1.000
1.449
1.547
0.860
0.619
0.547
1.190
0.595
1.903
0.569
0.817
2.391
2.032
0.337
1.276
0.279
0.198
0.165
0.224
0.245
0.416
0.044
0.190
1.134
0.404
0.212
0.469
0.872
0.980
0.306
0.367
0.166
0.330
0.089
0.590
0.291
0.082
0.159
0.079
0.279
0.127
0.295
0.064
0.087
0.412
1.00
1.00
1.00
1.00
.00
.00
.00
.00
.00
.00
.00
.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
-------
Quantitat ion Report file: ST16980831E
Data: ST16980831E.TI
08/31/98 15:02:00
Sample: 120UG/ML AP9 062598G
Conds.: INST. ID: F16
Formula: 1UL INJ. Instrument: F16
Submitted by: QES Analyst: DAT
AMOUNT=AREA * REF AMNT/(REF AREA
Resp.
No
51
52
53
54
55
56
No
51
52
53
54
55
56
No
51
52
53
54
55
56
fac. from Library Entry
Name
3,3'-DIMETHYLBENZIDINE
KEPONE
2-ACETYLAMINOFLUORENE
3-METHYLCHOLANTHRENE
7, 12-DIMETHYLBENZANTHRACENE
HEXACHLOROPHENE
m/z Scan Time Ref RRT
212 1473 16:23 5 0.950
272 1510 16:48 5 0.974
181 1518 16:53 5 0.979
268 1833 20:23 5 1.182
256 1731 19:15 6 0.971
NOT FOUND
Ret(L) Ratio RRT(L) Ratio
16:22 1.00 0.949 1.00
16:13 1.04 0.940 1.04
16:52 1.00 0.977 1.00
20:23 1.00 1.181 1.00
19:15 1.00 0.971 1.00
21:11 0.992
* RESP FACT)
212 S5# 35
272 S5# 37
181 S5# 45
268 S5# 85
256 S6# 20
196 S6# 30
Meth Area(Hght)
A BB^ 71459.
qedt (\) 11032.
A BB •M!" 84234.
A SB** 101188.
A BV 92986.
Amnt Amnt(L) R
120.00 120.00
120.00 120.00
120.00 120.00
120.00 120.00
120.00 120.00
Weight: 0.000
Acct. No.: FIN
53-96-3
56-49-5
75-97-6
70-30-4
Amount
120.000 UG/ML
120.000 UG/ML
120.000 UG/ML
120.000 UG/ML
120.000 UG/ML
.Fac R.Fac(L)
0.364 0.364
0.056 0.056
0.429 0.429
0.515 0.515
0.608 0.608
XTot
1.96
1.96
1.96
1.96
1.96
Ratio
1.00
1.00
1.00
1.00
1.0P
JANUAL EDIT CODES
I. PEAK NOT FOUND
2, POORCHROMATOGRAPHV
3. WRONG ISOMER
UL MANUAL EDITS MUST BE
••".UED, DATED,.ANDCrr.-T.
-------
100.0-
58
RIC
RIC+MASS CHROMATOGRAM
08/31/98 15:02:00
SAMPLE: 120UG/ML AP9 062598G
CONDS.: INST. ID: F16
RANGE: G _ 1,2158 LABEL: N 0,
DATA: ST1698083IE #1
CALI: ST1698083IE #3
SCANS 480 TO 800
2.0 QUAN: A 6, 2.0 J 0 BASE: U 20, 3
725
790
7:47
750
8:21
9664.
58.017
± 0.500
330752.
I
800 SCAN
8:54 TIME
o:
en
O
-------
RIC+MASS CHROMATOGRAM
08/31/98 15:02:00
SAMPLE: 120UG/ML APS 062598G
CONDS.: INST. ID: F16
RANGE: G 1/2158 LABEL: N 0,
DATA: ST1698083IE #1
CALI: ST1698083IE #3
SCANS 600 TO 700
2.0 QUAN: A 6. 2.0 J 0 BASE: U 20, 3
100.0-1
108
RIC
682
8024.
108.032
± 0.500
330752.
700 SCAN
7:47 TIME
-------
100.9-
272
RIC
RIC+MASS CHROMATOGRAM DATA: ST1698083IE #1 SCANS 1460 TO 1600
08/31/98 15:02:00 CALI: ST16980831E #3
SAMPLE: 120UG/ML AP9 062598G
CONDS.: INST. ID: F16
RANGE: G 1,2158 LABEL: N 0, 2.0 QUAN: A 6, 2.0 J 0 BASE: U 20, 3
1510
1502
232.
272.081
± 0.500
124288.
1460
16:14
1480
16:28
1500
16:41
1520
16:54
1540
17:08
1560
17:21
1580
17:34
1600 SCAN
17:48 TIME
CT
On
IV)
-------
DATA FROM FILE: ST16980831F SCANS 230 TO 1200 ACQUIRED: 08/31/98 15:31:00
CALI: ST1698083IF #3
SAMPLE: 160UG/ML AP9 062598H
CONDS.: INST. ID: F16
1000 -
11:07
iENZENE-04 152IS1* 01
J 100.07Z < 412672.)
CI50 ACEHAPHTHENE-010
ni£a_£HEUANTHRENE-D10
136IS2* 01
164IS3* 01
i88IS4# 01
3855-82-1
1146-65-2
15067-26-2
1517-22-2
M
cr:
00
Cl
-------
1288
13:21
DATA FROM FILE: ST1698083IF SCANS 1200 TO 2158 ACQUIRED: 08/31/98 15:31:00
CALI: ST1698083IF #3
SAMPLE: 168UG/ML APS 062598H
CONDS.: INST. ID: F16
J 108.03 < 226384.)
1400
15:34
1600 _
17:48
1800 -\
20:01
2800
22:15
CI75 PERYLENE-D12
240IS5* 01
164IS64* 01
1719-03-5
1520-96-3
cr
-------
Quantiration Report File: ST16980831F
Data: ST16980831F.TI
08/31/98 15:31:00
Sample: 160UG/HL AP9 06259SH
Conds.: 1NST. ID: F16
Formula: 1UL INJ. Instrument: F16
Submitted by: QES Analyst: DAT
AMOUNT=AR£A * REF AMNT/(REF AREA
Resp. fac. from Library Entry
No Name
1 CI30 1,4-DICHLOROBENZENE-D4
2 C140 NAPHTHALENE -D8
3 CI50 ACENAPHTHENE-D10
4 CI60 PHENANTHRENE-D10
5 CI70 CHRYSENE-D12
6 CI75 PERYLENE-012
7 PYR1DINE
8 2-PICOLINE
9 N-NITROSOMETHYLETHYLAMINE
10 METHYLMETHANESULFONATE
11 N-NITROSODIETHYLAM1NE
12 ETHYLMETHANE SULFONATE
13 PENTACHLOROETHANE
14 C361 ACETOPHENONE
15 N-NITROSOPYRROLIDINE
16 N-NITROSOMORPHOLINE
17 3-METHYL PHENOL
18 0-TOLUIDINE
19 N-NITROSOPIPERIDINE
20 AA-DIMETHYLPHENETHYLAMINE
21 2,6-DICHLOROPHENOL
22 HEXACHLOROPROPENE
23 P-PHENYLENE DIAMINE
24 N-NITROSODI-N-BUTYLAMINE
25 SAFROLE
26 1,2,4,5-TETRACHLOROBENZENE
27 ISOSAFROLE (#1)
28 ISOSAFROLE (#2)
29 1-CHLORONAPHTHALENE
30 1,4-NAPHTHOQUINOME
31 1,3-D1NITROBENZENE
32 PENTACHLOROBENZENE
33 1-NAPHTHYLAMINE
34 2-NAPHTHYLAMINE
35 2,3,4,6-TETRACHLOROPHENOL
36 5-NITRO-O-TOLUIDINE
37 SYM-TR1NITROBENZENE
38 PHENACETIH
* RESP FACT)
152IS1* 01
136IS2* 01
1641 S3* 01
188IS4* 01
240 1S5* 01
1641S6* 01
79 S1# 20
93 S1# 30
42 S1# 40
80 S1# 60
102 S1# 70
79 S1# 85
117 S1# 95
105 S1#170
100 S1#175
56 S1#180
108 SU182
106 S1#195
42 S2# 15
58 S2# 50
162 S2# 85
213 S2# 90
108 S2#115
84 82*120
152 S2#140
214 S3# 10
162 S3# 15
104 S3# 35
162 S3# 42
158 S3# 50
168 S3# 60
250 S3#100
143 S3#110
143 S3#115
232 S3#120
152 S3#145
75 S4# 25
108 S4#35
Weight:
Acct. No.
3855-82-1
1146-65-2
15067-26-2
1517-22-2
1719-03-5
1520-96-3
110-86-1
109-06-8
10595-95-6
55-18-5
.66-27-3
76-01-7
930-55-2
59-89-2
95-53-4
100-75-4
122-09-8
87-65-0
106-50-3
924-16-3
94-59-7
95-94-3
120-58-1
120-58-1
90-13-1
130-15-4
99-65-0
708-93-5
134-32-7
91-59-8
58-90-2
99-52-5
62-44-2
39 OIALLATE 234 S4# 37
40 4-AMINOBIPHENYL
41 PRONAMIDE
42 PENTACHLORONITROBENZENE
43 2SECBUTYL-4,6-DINITROPHENOL
44 4-NITROOUINOLINE-1-OXIDE
45 METHAPYRILENE
46 ISODRIN
47 CHLOROBENZILATE
169 S4# 45
173 S4# 55
237 S4# 60
211 S4# 75
190 S4#100
58 S4HM05
139 S4#120
92-67-1
23950-58-5
82-68-8
88-85-7
91-M-5
0.000
-------
Name
ARAMITE (#1)
ARAM1TE (#2)
P-OIMETHYLAM1NOAZ08ENZENE
m/z
152
136
164
188
240
264
79
93
42
80
102
79
117
105
100
56
108
106
42
58
162
213
108
84
162
214
162
104
162
158
168
250
143
143
232
152
75
, 108
1 234
I 169
173
! 237
I 211
, 190
I 58
> 193
' 139
i 185
» 185
) 120
Scan
341
530
829
1088
1551
1783
103
145
157
183
219
256
303
405
410
414
422
410
454
742
553
549
621
621
649
683
698
738
734
771
805
859
884
901
897
942
1026
1038
1019
1070
1097
1062
1109
1237
1267
1271
1428
1400
1414
1413
Time
3:48
5:54
9:13
12:06
17:15
19:50
1:09
1:37
1:45
2:02
2:26
2:51
3:22
4:30
4:34
4:36
4:42
4:34
5:03
8:15
6:09
6:06
6:54
6:54
7:13
7:36
7:46
8:13
8:10
8:35
8:57
9:33
9:50
10:01
9:59
10:29
11:25
11:33
11:20
11:54
12:12
11:49
12:20
13:46
14:06
14:08
15:53
15:34
15:44
15:43
Ref
1
2
3
4
5
6
1
1
1
1
1
1
1
1
1
1
1
1
2
2
2
2
2
2
2
3
3
3
3
3
3
3
3
3
3
3
4
4
4
4
4
4
4
4
4
4
4
5
5
5
RRT
1.000
1.000
1.000
1.000
1.000
(1.000
0.302
0.425
0.460
0.537
0.642
0.751
0.889
1.188
1.202
1.214
1.238
1.202
0.857
1.400
1.043
1.036
1.172
1.172
1.225
0.824
0.842
0.890
0.885
0.930
0.971
1.036
1.066
1.087
1.082
1.136
0.943
0.954
0.937
0.983
1.008
0.976
1.019
1.137
1.165
1.168
1.312
0.903
0.912
0.911
185 S5# 20
185 S5# 25
120 S5# 30
Meth
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
q<
A
A
q«
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
BB
BB
BB
BV
BB
BV
BB
BB
BB
BB
BB
BB
BB
BB
BB
BV
884*
BB "^
BB *•
jdt(p
BB ,
sdt(y
88
BB
BB
BB
BB
BB
SB
88
BB
BB
BB
BB
BB
VB
BB
BV
BB
BB
BB
VB
BB
BB
BV
BB
BB
BV
88
140-57-8
140-57-8
60-11-7
Area(Hght) Amount
28546.
103260.
58634.
95521 .
56500.
44220.
179951.
176388.
99310.
68989.
63322.
142082.
67568.
217271 .
65650.
93134.
273406.
222560 .
135876.
489048.
117693.
81868.
^ 49954.
92687.
103119.
98348.
10361.
44958.
348940.
91288.
47740.
110577.
180448.
206685.
68020.
74228.
60745 .
118791.
36960.
208505.
105932.
30912.
57279.
28601.
106019.
47357.
107482.
13837.
19178.
94845.
40.
40.
40.
40.
40.
40.
160.
160.
160.
160.
160.
160.
160.
160.
160.
160.
160.
160.
160.
160.
160.
160.
160.
160.
160.
160.
160.
160.
160.
160.
160.
160.
160.
160.
160.
160.
160.
160.
160.
160.
160.
160.
160.
160.
160.
160.
160.
160.
160.
160.
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
XTot
0.50
0.50
0.50
0.50
0.50
0.50
1.98
1.98
1.98
1.98
1.98
1.98
1.98
1.98
1.98
1.98
1.98
1.98
1.98
1.98
1.98
1.98
1.98
1.98
1.98
1.98
1.98
1.98
1.98
1.98
1.98
1.98
1.98
1.98
1.98
1.98
1.98
1.98
1.98
1.98
1.98
1.98
1.98
1.98
1.98
1.98
1.98
1.98
1.98
1.98
-------
No
1
2
3
4
5
6
7
S
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
Ret(L)
3:47
5:54
9:13
12:05
17:15
19:49
1:09
1:37
1:45
2:01
2:25
2:50
3:22
4:30
4:30
4:34
4:40
4:32
5:01
7:54
6:08
6:06
7:25
6:54
7:12
7:34
7:46
8:12
8:09
8:34
8:56
9:33
9:49
10:00
9:57
10:27
11:24
11:30
11:19
11:53
12:11
11:48
12:19
13:45
14:05
14:08
15:52
15:34
15:44
15:42
Ratio
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.01
1.00
1.00
1.00
1.00
1.01
1.01
1.01
1.00
1.01
1.05
1.00
1.00
0.93
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
RRT(L)
1.000
1.000
1.000
1.000
1.000
1.000
0.303
0.426
0.462
0.535
0.641
0.750
0.888
1.188
1.191
1.209
1.232
1.200
0.851
1.340
1.042
1.036
1.258
1.170
1.223
0.822
0.843
0.890
0.885
0.930
0.970
1.036
1.066
1.086
1.081
1.135
0.943
0.951
0.937
0.983
1.008
0.976
1.019
1.137
1.165
1.168
1.313
0.902
0.912
0.910
Ratio
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.01
1.00
1.00
1.00
1.01
1.05
1.00
1.00
0.93
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
Amnt
40.00
40.00
40.00
40.00
40.00
40.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
Amnt(L)
40.00
40.00
40.00
40.00
40.00
40.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
160.00
R.Fac R.
1.000
1.000
1.000
1.000
1.000
1.000
1.576
1.545
0.870
0.604
0.555
1.244
0.592
1.903
0.575
0.816
2.394
1.949
0.329
1.184
0.285
0.198
0.121
0.224
0.250
0.419
0.044
0.192
1.488
0.389
0.204
0.471
0.769
0.881
0.290
0.316
0.159
0.311
0.097
0.546
0.277
0.081
0.150
0.075
0.277
0.124
0.281
0.061
0.085
0.420
Fac(L) Ratio
1.000
1.000
1.000
1.000
1.000
1.000
1.576
1.545
0.870
0.604
0.555
1.244
0.592
1.903
0.575
0.816
2.394
1.949
0.329
1.184
0.285
0.198
0.121
0.224
0.250
0.419
0.044
0.192
1.488
0.389
0.204
0.471
0.769
0.881
0.290
0.316
0.159
0.311
0.097
0.546
0.277
0.081
0.150
0.075
0.277
0.124
0.281
0.061
0.085
0.420
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
1.00
1.00
1.00
1.00
T.OO
1.00
1.00
1,00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
lb£7
-------
antitat ion Report File: ST16980831F
ta: ST16980831F.T1
/31/98 15:31:00
nple: 160UG/ML AP9 062598H
nds.: INST. ID: F16
rmula: 1UL INJ.
bmitted by: QES
OUNT=AREA * REF AMNT/(REF
sp.
0
1
2
3
4
5
6
o
1
2
3
u
5
6
o
'1
,2
.3
>4
.5
>6
Instrument: F16
Analyst: DAT
AREA
Weight: 0.000
Acct. No.: FIN
* RESP FACT)
fac. from Library Entry
Name
3,3'-DIMETHYLBENZIDINE
KEPONE
2-ACETYLAMINOFLUORENE
3-METHYLCHOLANTHRENE
7,12-OIMETHYLBENZANTHRACENE
HEXACHLOROPHENE
m/z Scan Time Ref
212 1473 16:23 5
272 1508 16:46 5
181 1518 16:53 5
268 1834 20:24 5
256 1732 19:16 6
NOT FOUND
RRT
0.950
0.972
0.979
1.182
0.971
Ret(L) Ratio RRT(L) Ratio
16:22 1.00 0.949 1.
16:13 1.03 0.940 1.
16:52 1.00 0.977 1.
20:23 1.00 1.181 1.
19:15 1.00 0.971 1.
21:11 0.992
00
03
00
00
00
212
272
181
268
256
196
SS*
S5#
S5#
S5#
S6#
S6#
Meth
A
35
37
45
85
20
30
53-96-3
56-49-5
75-97-6
70-30-
Area(Hght)
BV Of
78087.
qedt^K 12248.
A
A
A
BBJv" 99486.
BB
BB
Amnt
160
160
160
160
160
.00
.00
.00
.00
.00
116191.
107710.
Amnt(L) R
160
160
160
160
160
.00
.00
.00
.00
.00
4
Amount
160.
000
160.000
160.
160.
160.
.Fac
0.346
0.054
0.440
0.514
0.609
000
000
000
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
R.Fac(L)
0.346
0.054
0.440
0.514
0.609
XTot
1.98
1.98
1.98
1.98
1.98
Ratio
1.00
1.00
1.00
1.00
1.00
iANUALEDii
I. PEAK NOT FOUND
>. POORCHROMATOGRAPhi
3. WRONG ISOMER
UL MANUAL EDITS MUST BE
DATED, AND Crr;,;
-------
RIC+MASS CHROMATOGRAM DATA: ST16980831F #1
08/31/98 15:31:00 CALI: ST16980831F #3
SAMPLE: 160UG/ML AP9 062598H
CONDS.: INST. ID: F16
RANGE: G 1,2158 LABEL: N 0, 2.0 QUAN: A 6, 2.0 J
SCANS 480 TO 830
0 BASE: U 20, 3
100.0-1
742
58
RIC
650
7:14
700
7:47
750
8:21
800
8:54
10544.
58.017
± 0.500
366080.
SCAN
TIME
or
Cm
CO
-------
100.0-1
108
RIC
RIC+MASS CHROMATOGRAM DATA: ST16980831F #1 SCANS 600 TO 700
08/31/98 15:31:00 CALI: ST16980831F #3
SAMPLE: 160UG/ML AP9 062598H
CONDS.: INST. ID: F16
RANGE: G 1,2158 LABEL: N 0, 2.0 QUAN: A 6, 2.0 J 0 BASE: U 20, 3
683
680
7:34
18336.
108.032
± 0.500
366080.
700 SCAN
7:47 TIME
or
CO
o
-------
DATA: ST1698083IF #1
CALI: ST1698083IF #3
SCANS 1460 TO 1600
100.0-1
RIC+MASS CHROMATOGRAM
08/31/98 15:31:00
SAMPLE: 160UG/ML AP9 062598H
CONOS.: INST. ID: F16
RANGE: G 1,2158 LABEL: N 0, 2.0 QUAN: A 6, 2.0 J 0 BASE: U 20, 3
1508
1515
1523
272
RIC
1460
16:14
1480
16:28
238.
272.081
± 0.500
1500
16:41
;528
16s54
1540
17:08
1568
17:21
137216.
1600 SCAN
17:48 TIME
CT
CD
-------
Contimiw Cakltration
c/
1592
-------
QUANTERRA GC/HS
SEMI VOLATILE HSL CALIBRATION CHECK
CONT1N. CALIBRATION: 80 UG/ML HSL STD ST16980831 08/31/98 12:31:00
INITIAL CALIBRATION: 10 UG/ML HSL STD ST16980827A 08/27/98 9:56:00
INITIAL CALIBRATION: 20 UG/ML HSL STD ST16980827B 08/27/98 10:21:00
INITIAL CALIBRATION: 50 UG/ML HSL STD ST16980827C 08/27/98 10:51:00
INITIAL CALIBRATION: 80 UG/ML HSL STD ST16980827 08/27/98 9:22:00
INITIAL CALIBRATION: 120 UG/ML HSL STD ST16980827D 08/27/98 11:20:00
INITIAL CALIBRATION: 160 UG/ML HSL STD ST16980827E 08/27/98 11:50:00
Initial Calibration Continuing Calibration
Library Response Factor X RSD Amount X Diff
Entry
SI
SI
S1
S1
SI
S1
SI
S1
SI
S1
S1
S1
S1
S1
S2
S2
S2
S2
S2
S2
S2
S2
S2
S2
S2
S2
S2
S3
S3
S3
S3
S3
S3
S3
S3
S3
S3
S3
15
100
105
110
115
125
130
145
150
160
165
185
190
200
10
20
25
30
45
35
40
55
60
80
95
130
145
20
25
30
40
45
55
65
70
75
80
85
Compound
C310
C320
C315
C325
C330
C335
C340
C345
C350
C355
C360
C365
C370
C375
C410
C415
C420
C425
C430
C435
C440
C445
C450
C455
C460
C465
C470
C510
C515
C520
C525
C530
C535
C540
C543
C545
C550
C555
N-NITROSOOIMETH
ANILINE
PHENOL
BISC2-CHLOROETH
2-CHLOROPHENOL
1,3-DICHLOROBEN
1,4-DICHLOROBEN
BENZYL ALCOHOL
1,2-DlCHLOROBEN
2-METHYLPHENOL
2.2'-OXYBIS(1-C
4-METHYLPHENOL
N-NITROSO-DI-N-
HEXACHLOROETHAN
NITROBENZENE
1SOPHORONE
2-NITROPHENOL
2,4-DIMETHYLPHE
BENZOIC ACID
BISC2-CHLOROETH
2,4-DICHLOROPHE
1,2,4-TRICHLORO
NAPHTHALENE
4-CHLOROANALINE
HEXACHLOROBUTAD
4-CHLORO-3-METH
2-METHYLNAPHTHA
HEXACHLOROCYCLO
2,4,6-TRICHLORO
2,4,5-TRICHLORO
2-CHLORONAPHTHA
2-NITROANALINE
DIMETHYLPHTHALA
ACENAPHTHYLENE
2,6-DINITROTOLU
3-NITROANILINE
ACENAPHTHENE
2,4-OINITROPHEN
Avg Min
1.
1.
1.
1.
019
846
968
368
1.497
1.
1.
0.
1.
1.
2.
1.
0.
0.
586
618
854
500
174
539
276
906 0.050
708
0.445
0.742
0.213
0.330
0.276
0.511
0.308
0.331
1.022
0.454
0.168
0.338
0.751
0.372 0.050
0.404
0.412
1
0
1
1
0
0
1
0
.193
.502
.341
.839
.324
.383
.158
.189 0.050
4.4
6.2
7.8
6.1
5.5
4.5
4.8
9.3
5.0
7.4
3.9
9.0
5.1
3.5
7.2
5.5
7.9
16.9
4.7
4.1
6.6
5.0
6.6
4.5
5.1
9.0
10.8
10.1
10.6
7.1
6.6
2.9
6.1
8.2
8.5
1.4
6.9
10.3
Max Calc
69.65
81.93
30.0 84.53
83.20
85.59
83.03
30.0 83.73
78.77
82.86
79.35
79.64
77.91
79.52
81.62
85.86
79.94
30.0 84.24
92.67
48.36
81.27
30.0 83.17
84.22
84.81
82.23
30.0 84.88
30.0 82.44
104.45
88.84
30.0 84.50
80.97
86.65
83.54
85.06
87.87
90.03
83.67
30.0 86.87
84.84
Exp
80.
80.
80.
80.
80.
80.
80.
80.
80.
80.
80.
80.
80.
80.
80.
80.
Max
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80
80
80
80
80
80
80
80
.00
.00
.00
.00
.00
.00
.00
.00
12.9
-2.4
-5.7
-4.0
-7.0
-3.8
-4.7
1.5
-3.6
0.8
0.4
2.6
0.6
-2.0
-7.3
0.1
-5.3
-15.8
39.5
-1.6
-4.0
-5.3
-6.0
-2.8
-6.1
-3.0
-30.6
-11.0
-5.6
-1.2
-8.3
-4.4
-6.3
-9.8
-12.5
-4.6
-8.6
-6.0
50.0
50.0
20.0
50.0
50.0
50.0
20.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
20.0
50.0
50.0
50.0
20.0
50.0
50.0
50.0
2D.O
20.0
50.0
50.0
20.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
20.0
50.0
ib,
-------
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-------
QUANTERRA GC/MS
SEMIVOLATILE HSL CALIBRATION CHECK
CONTIN. CALIBRATION: 80 UG/ML HSL STD ST16980831 08/31/98 12:31:00
INITIAL CALIBRATION: 10 UG/ML HSL STD ST16980827A 08/27/98 9:56:00
INITIAL CALIBRATION: 20 UG/ML HSL STD ST16980827B 08/27/98 10:21:00
INITIAL CALIBRATION: 50 UG/ML HSL STD ST16980827C 08/27/98 10:51:00
INITIAL CALIBRATION: 80 UG/ML HSL STD ST16980827 08/27/98 9:22:00
INITIAL CALIBRATION: 120 UG/ML HSL STD ST 169808270 08/27/98 11:20:00
INITIAL CALIBRATION: 160 UG/ML HSL STD ST16980827E 08/27/98 11:50:00
ST16980831 ST16980827A ST16980827B ST16980827C ST16980827 ST16980827D
ST16980827E
Lib # Cone RRF Cone RRF Cone RRF Cone RRF Cone RRF Cone RRF
S1 15 80, 0.887 10, 0.952 20, 1.010 50, 1.016 80, 1.087 120, 1.008
S1 15 160, 1.042
S1 100 80, 1.891 10, 1.947 20, 1.988 50, 1.814 80, 1.876 120, 1.778
S1 100 160, 1.674
S1 105 80, 2.079 10, 1.699 20, 2.037 50, 2.035 80, 2.148 120, 1.907
S1 105 160, 1.982
SI 110 80, 1.422 10, 1.336 20, 1.465 50, 1.438 80, 1.414 120, 1.291
S1 110 160, 1.261
S1 115 80, 1.601 10, 1.386 20, 1.569 50, 1.522 80, 1.603 120, 1.450
S1 115 160, 1.451
S1 125 80, 1,646 10, 1.515 20, 1.668 50, 1.618 80, 1.659 120, 1.546
S1 125 160, 1.510
S1 130 80, 1.693 10, 1.580 20, 1.695 50, 1.666 80. 1.697 120, 1.549
S1 130 160, 1.518
SI 145 80, 0.841 10, 0.702 20, 0.851 50, 0.872 80, 0.913 120, 0-366
SI 145 160, 0.922
SI 150 80, 1.553 10, 1.475 20, 1.606 50, 1.482 80. 1.573 120, 1.454
S1 150 160, 1.409
S1 160 80, 1.165 10, 0.998 20, 1.206 50, 1.221 80. 1.209 120, 1.199
SI 160 160, 1.213
S1 165 80, 2.528 10, 2.393 20, 2.676 50, 2.597 80, 2.582 120, 2.502
SI 165 160, 2.486
S1 185 80, 1.243 10, 1.049 20, 1.298 50, 1.355 80, 1.287 120, 1.316
SI 185 160, 1.351
SI 190 80, 0.900 10, 0.819 20, 0.934 50, 0.938 80, 0.940 120, 0.913
SI 190 160, 0.890
SI 200 80, 0.723 10, 0.665 20, 0.740 50, 0.713 80. 0.720 120, 0.706
SI 200 160, 0.706
S2 10 80, 0.478 10, 0.423 20, 0.477 50, 0.455 80, 0.4M HO. 0.419 ... . . .1 b i
S2 10 160, 0.410
S2 20 80, 0.741 10, 0.685 20, 0.778 50, 0.774 80. 0.778 120, 0.726
S2 20 160, 0.708
-------
25 80, 0.225
25 160, 0.217
30 80, 0.382
30 160, 0.353
45 80, 0.167
45 160, 0.292
35 80, 0.519
35 160, 0.498
40 80, 0.320
40 160, 0.306
55 80, 0.348
55 160, 0.310
60 80, 1.084
60 160, 0.935
80 80, 0.466
80 160, 0.455
95 80, 0.178
95 160, 0.157
130 80, 0.348
130 160, 0.346
145 80, 0.981
145 160, 0.639
20 80, 0.413
. 20 160, 0.330
i 25 80, 0.426
I 25 160, 0.448
i 30 80, 0.417
i 30 160, 0.366
S 40 80, 1.292
5 40 160, 1.089
5 45 80, 0.524
5 45 160, 0.497
3 55 80, 1.426
3 55 160, 1.251
3 65 80, 2.019
3 65 160, 1.671
3 70 80, 0.364
3 70 160, 0.317
3 75 80, 0.400
3 75 160, 0.379
10, 0.182 20, 0.212 50, 0.218 80, 0.232 120, 0.219
10, 0.234 20, 0.309 50, 0.334 80, 0.400 120, 0.349
20, 0.257 50, 0.279 80, 0.270 120. 0.280
10, 0.481 20, 0.529 50, 0.517 80, 0.538 120, 0.502
10, 0.270 20, 0.313 50, 0.314 80, 0.332 120, 0.311
10, 0.319 20, 0.350 50, 0.334 80, 0.350 120, 0.322
10, 1.008 20, 1.090 50, 1.038 80, 1.102 120, 0.960
10, 0.419 20, 0.466 50, 0.454 80, 0.480 120, 0.449
10, 0.160 20, 0.178 50, 0.170 80, 0.177 120, 0.167
10, 0.279 20, 0.337 50, 0.353 80, 0.365 120, 0.347
10, 0.773 20, 0.840 50, 0.827 80, 0.757 120, 0.67]
10, 0.329 20, 0.387 50. 0.376 80, 0.428 120, 0.379
10, 0.327 20, 0.389 50, 0.405 80, 0.435 120, 0.417
10, 0.397 20, 0.437 50, 0.429 80, 0.443 120, 0.401
10, 1.172 20, 1.275 50, 1.208 80, 1.283 120, 1.128
20, 0.491 50, 0.510 80, 0.523 120, 0.487
10, 1.257 20, 1.423 50, 1.392 80, 1.426 120, 1.297
10, 1.751 20, 1.959 50, 1.896 80, 2.047 120, 1.707
10, 0.274 20, 0.339 50, 0.341 80, 0.351 120. 0.321
20, 0.382 50, 0.392 80, 0.382 120. 0.379
3 80 80, 1.258 10, 1.140 20, 1.227 50, 1.182 80, 1.261 120, 1.075
-------
S3 80 160, 1.066
S3 85 80, 0.201
S3 85 160, 0.196
S3 95 80, 0.174
S3 95 160, 0.169
20, 0.156 50, 0.190 80, 0.202 120, 0.203
20, 0.164 50, 0.178 80, 0.184 120, 0.168
1SS
-------
QUANTERRA GC/MS
SEMI VOLATILE HSL CALIBRATION CHECK
3NTIN. CALIBRATION: 80 UG/ML HSL STD ST16980831 08/31/98 12:31:00
miAL CALIBRATION: 10 UG/ML HSL STD ST16980827A 08/27/98 9:56:00
miAL CALIBRATION: 20 UG/ML HSL STD ST16980827B 08/27/98 10:21:00
miAL CALIBRATION: 50 UG/ML HSL STD ST16980827C 08/27/98 10:51:00
miAL CALIBRATION: 80 UG/ML HSL STD ST16980827 08/27/98 9:22:00
miAL CALIBRATION: 120 UG/ML HSL STD ST16980827D 08/27/98 11:20:00
miAL CALIBRATION: 160 UG/ML HSL STD ST16980827E 08/27/98 11:50:00
ST16980831 ST16980827A ST16980827B ST16980827C ST16980827 ST16980827D
ST16980827E
ib # Cone RRF Cone RRF Cone RRF Cone RRF Cone RRF Cone RRF
= = ====s======s:===:=s=s==s=:====:===========s:===========55=:5:========================
5 90 80, 1.808 10, 1.617 20, 1.782 50, 1.736 80, 1.762 120, 1.556
5 90 160, 1.561
5 105 80, 0.472 10, 0.339 20, 0.412 50, 0.420 80, 0.437 120, 0.396
5 105 160, 0.378
5 130 80, 1.508 10, 1.300 20, 1.462 50, 1.452 80, 1.462 120, 1.328
5 130 160, 1.209
5 140 80, 0.659 10, 0.597 20, 0.647 50, 0.631 80, 0.646 120, 0.579
5 140 160, 0.575
5 135 80, 1.432 10, 1.251 20, 1.398 50, 1.340 80, 1.386 120, 1.224
5 135 160, 1.188
5 150 80, 0.319 20, 0.326 50, 0.320 80, 0.306 120, 0.263
5 150 160, 0.321
V 10 80, 0.138 20, 0.121 50, 0.139 80, 0.145 120, 0.124
V 10 160, 0.130
1 15 80, 0.532 10, 0.568 20, 0.582 50, 0.562 80, 0.539 120, 0.530
4 15 160, 0.523
4 20 80, 1.150 10, 1.150 20, 1.222 50, 1.186 80, 1.212 120, 1.098
4 20 160, 1.158
4 30 80, 0.228 10, 0.224 20, 0.231 50, 0.223 80, 0.232 120, 0.215
4 30 160, 0.210
4 40 80, 0.264 10, 0.273 20, 0.281 50, 0.255 80, 0.268 120, 0.238
4 40 160, 0.242
4 50 80, 0.156 20, 0.148 50, 0.156 80, 0.170 120, 0.155
4 50 160, 0.147
4 65 80, 1.079 10, 1.017 20, 1.081 50, 1.044 80, 1.096 120, 0.948
4 65 160, 1.010
4 70 80, 1.041 10, 1.019 20, 1.100 50, 1.026 80, 1.059 120, 0.908
• 70 160, 0.809
i 80 80, 0.771 10, 0.914 20, 0.763 50, 0.729 80, 0.769 120, 0.707
; 80 160, 0.701 1 UO CT
J-O«JG
. 85 80, 1.337 10, 1.233 20, 1.366 50, 1.332 80, 1.333 120, 1.137
V 85 160, 1.080
-------
S4 110 80, 0.927
S4 110 160, 0.715
S5 10 80, 0.056
S5 10 160, 0.131
S5 15 80, 1.443
S5 15 160, 1.358
S5 40 80, 0.708
S5 40 160, 0.734
S5 55 80, 0.374
S5 55 160, 0.391
S5 50 80, 1.212
S5 50 160, 1.092
S5 60 80, 1.046
S5 60 160, 0.919
S5 65 80, 1.017
S5 65 160, 1.089
S6 10 80, 2.060
S6 10 160, 2.023
S6 15 80, 1.423
S6 15 160, 1.412
S6 25 80, 1.306
S6 25 160, 0.940
S6 35 80, 1.230
S6 35 160, 1.084
S6 55 80, 1.360
S6 55 160, 1.144
S6 60 80, 1.343
S6 60 160, 1.105
S6 65 80, 1.425
S6 65 160, 1.139
S1 6 80, 0.935
51 6 160, 0.882
S2 2 80, 0.486
S2 2 160, 0.452
S3 3 80, 1.307
S3 3 160, 1.116
S5 2 80, 1.082
S5 2 160, 1.019
S1 3 80, 2.014
S1 3 160, 1.971
SI 2 80, 1.306
10, 1.013 20, 1.008 50, 0.925 80, 0.950 120, 0.788
20, 0.155 50, 0.143 80, 0.077 120, 0.141
10, 1.209 20, 1.310 50, 1.295 80, 1.468 120, 1.295
10, 0.587 20, 0.673 50, 0.692 80, 0.722 120, 0.700
20, 0.441 50, 0.421 80, 0.383 120, 0.405
10, 1.058 20, 1.195 50, 1.116 80, 1.203 120, 1.086
10, 1.034 20, 1.068 50, 1.005 80, 1.102 120, 0.959
10, 0.812 20, 0.978 50, 0.986 80, 1.027 120, 0.987
10, 1.637 20, 1.959 50, 1.985 80, 1.977 120, 1.967
10, 1.322 20, 1.536 50, 1.448 80, 1.453 120, 1.490
10, 1.185 20, 1.223 50, 1.171 80, 1.264 120, 1.171
10, 1.168 20, 1.257 50, 1.206 80, 1.229 120, 1.147
10, 1.253 20, 1.355 50, 1.312 80, 1.368 12Dr t.Rt
10, 1.254 20, 1.386 50, 1.288 80, 1.360 12D. 1.212
10, 1.339 20, 1.436 50, 1.356 80, 1.426 120, 1.289
10, 0.832 20, 0.999 50, 0.946 80, 0.959 120, 0.902
10, 0.446 20, 0.494 50, 0.469 80, 0.504 120, 0.452
10, 1.252 20, 1.315 50, 1.253 80, 1.299 120, 1.171
10, 0.932 20, 1.002 50, 0.976 80, 1.082 120, 0.960
20, 2.057 50, 2.059 80, 2.046 TZO, 1.995
20, 1.291 50, 1.332 80, 1.448 120, 1.376
-------
51
2 160, 1.394
31 5 80, 1.483
51 5 160, 1.407
33 2 80, 0.241
33 2 160, 0.217
20, 1.561 50, 1.501 80, 1.503 120, 1.437
20, 0.261 50, 0.239 80, 0.233 120, 0.228
16
00
-------
DATA FROM FILE: ST16980831 SCANS 230 TO 1200 ACQUIRED: 08/31/98 12:31:00
CALI: ST16980831 #3
SAMPLE: SSTD880 80UG/ML CALI III 082198A
CONDS.: INST. ID: F16
400
4:27
1000 _r
11:07
TIME1 J
I
82SS2* 02
136IS2# 01
100.07Z < 218368.)
99SS1* 03
152 Sl# $t55"82"
4165-62-2
— CS25 2-FLUOROBIPHENYL
88IS4* 01
4165-60-0
1146-65-2
172SS3# 03
15067-26-2
118-79-6
1517-22-2
321-60-8
O5
O
-------
DATA FROM FILE: ST16980831 SCANS 1200 TO 2158 ACQUIRED: 08/31/98 12:31:00
CALI: ST16980831 #3
SAMPLE: SSTD080 80UG/ML CALI III 082198A
CONDS.: INST. ID: F16
1200 .
13:21
1400 _
15:34
1600 .
17:48
1800 _
20:01
2000
22:15
I
I
j
100.07. < 161024.)
•€530 TERPHENYL-D14
244SS5# 02
1718-51-0
CI70 CHRYSENE-D12
240IS5# 01
1719-03-5
164IS6* 01
1520-96-3
05
O
-------
Quantitat ion Report File: ST16980831
Data: ST16980831.TI
08/31/98 12:31:00
Sample: SSTD080 80UG/ML CALI III 082198A
Conds.: 1NST. ID: F16
Formula: 1UL INJ. Instrument: F16
Submitted by: QES Analyst: DAT
AMOUNT=AREA * REF AMNT/(REF AREA * RESP FACT)
Resp. fac. from average of whole .RL
Weight: 0.000
Acct. No.: FIN
No
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
Name
CI30
CI40
CI50
CI60
CI70
CITS
CS20
CS25
CS30
CS45
CS50
CS55
CS70
CS75
1,4-DICHLOROBENZENE-D4 152IS1* 01
NAPHTHALENE-08 136IS2* 01
ACENAPHTHENE-D10 164IS3* 01
PHENANTHRENE-D10 188IS4* 01
CHRYSENE-D12 240IS5* 01
PERYLENE-D12 164IS6* 01
NITROBENZENE -05 82SS2* 02
2-FLUOROBIPHENYL 172SS3* 03
TERPHENYL-D14 .244SS5* 02
PHENOL -D5 99SS1* 03
2-FLUOROPHENOL 112SS1* 02
2,4,6-TRIBROMOPHENOL 330SS3* 02
2-CHLOROPHENOL-D4
1.2-DICHLOROBNZN-D4
132
152
S1# 05
S1# 06
3855-82-1
1146-65-2
15067-26-2
1517-22-2
1719-03-5
1520-96-3
4165-60-0
321-60-8
1718-51-0
4165-62-2
367-12-4
118-79-6
HEXACHLOROBENZENE-C13
C310
C320
C315
C325
C330
C335
C340
C345
C350
C355
C360
C365
C370
C375
C410
C415
C420
C425
C435
C440
C430
C445
C450
C455
C460
C465
C470
C510
C515
C520
C525
C530
N-NITROSODIMETHYLAMINE
ANILINE
PHENOL
BIS(2-CHLOROETHYL)ETHER
2-CHLOROPHENOL
1,3-DICHLOROBENZENE
1,4-DICHLOROBENZENE
BENZYL ALCOHOL
1,2-DICHLOROBENZENE
2-METHYLPHENOL
2,2'-OXYBIS(1-CLPROPAN)
4-METHYLPHENOL
N-NITROSO-DI-N-PROPYLAM
HEXACHLOROETHANE
NITROBENZENE
ISOPHORONE
2-NITROPHENOL
2,4-DIMETHYLPHENOL
BIS(2-CHLOROETHOXY)METH
2,4-DICHLOROPHENOL
BENZOIC ACID
1.2,4-TRICHLOROBENZENE
NAPHTHALENE
4-CHLOROANALINE
HEXACHLOROBUT AD I ENE
4-CHLORO-3-METHYLPHENO
2-METHYLNAPHTHALENE
HEXACHLOROCYCLOPENTAD I
2,4,6-TRICHLOROPHENOL
2,4,5-TRICHLOROPHENOL
2-CHLORONAPHTHALENE
2-NITROANALINE
74 S1# 15
93
94
93
128
146
146
108
146
108
45
108
70
117
77
82
139
107
93
162
122
180
128
127
225
107
142
237
196
196
162
65
S1#100
S1#105CC
simo
S2#115
S1#125
SUM30CC
S1#145
S1#150
S1#160
S1#165
S1#185
S1#190SP
S1#200
S2# 10
S2# 20
S2# 25CC
S2# 30
S2# 35
S2# 40
S2# 45
S2# 55
S2# 60
S2# 80
S2# 95CC
S2#130CC
S2#145
S3# 20
S3# 25CC
S3# 30
S3# 40
S3# 45
62-75-9
62-53-3
108-95-2
111-44-4
95-57-8
541-73-1
106-46-7
100-51-6
95-50-1
95-48-7
108-60-1
106-44-5
621-64-7
67-72-1
98-95-3
75-59-1
88-75-5
105-67-9
111-91-1
120-83-2
65-85-0
120-82-1
91-20-3
106-47-8
87-68-3
59-50-7
91-57-6
77-47-4
88-06-2
95-95-4
91-58-7
38-74-4
-------
lo
.8
.9
iO
lo
1
2
3
4
5
6
7
8
9
0
1
'2
3
4
5
6
7
8
9
!0
:1
'2
3
'4
'5
:6
7
'8
'9
.0
,1
•2
13
14
;s
16
17
18
19
,0
.1
.2
,3
.4
.5
.6
,7
.8
.9
^0
Name
C535 DIMETHYLPHTHALATE
C540 ACENAPHTHYLENE
C543 2,6-OINITROTOLUENE
m/z
152
136
164
188
240
264
82
172
244
99
112
330
132
152
NOT
74
93
94
93
128
146
146
108
146
108
45
108
70
117
77
82
139
107
93
162
122
180
128
127
225
107
142
237
196
196
162
65
163
152
165
Scan
340
530
828
1086
1552
1783
422
723
1383
308
196
969
312
359
FOUND
103
301
309
315
314
331
342
369
361
390
389
417
410
407
425
467
474
497
511
517
546
524
533
553
560
649
651
680
708
713
733
762
806
802
812
Time
3:47
5:54
9:13
12:05
17:16
19:50
4:42
8:03
15:23
3:26
2:11
10:47
3:28
4:00
1:09
3:21
3:26
3:30
3:30
3:41
3:48
4:06
4:01
4:20
4:20
4:38
4:34
4:32
4:44
5:12
5:16
5:32
5:41
5:45
6:04
5:50
5:56
6:09
6:14
7:13
7:14
7:34
7:53
7:56
8:09
8:29
8:58
8:55
9:02
Ref
1
2
3
4
5
6
2
3
5
1
1
3
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
2
2
2
2
2
2
2
2
2
2
2
2
2
3
3
3
3
3
3
3
3
RRT
1.000
1.000
1.000
1.000
1.000
1.000
0.796
0.873
0.891
0.906
0.576
1.170
0.918
1.056
0.303
0.885
0.909
0.926
0.924
0.974
1.006
1.085
1.062
1.147
1.144
1.226
1.206
1.197
0.802
0.881
0.894
0.938
0.964
0.975
1.030
0.989
1.006
1.043
1.057
1.225
1.228
0.821
0.855
0.861
0.885
0.920
0.973
0.969
0.981
163 S3# 55
152 S3# 65
165 S3# 70
Meth
A BB
A BB
A BB
A BB
A BB
A BB
A BB
A BB
A BB
A BB
A BB
A BB
A BB
A BB
A BB
A BV
A VB
A VB
A BB
A BV
A VB
A BB
A BB
A BB
A BB
A BB
A BV
A BB
A VB
A BB
A VB
A BB
A BB
A BB
A BB
A BB
A BB
A BB
A BB
A BB
A BV
A BB
A BV
A VB
A BB
A BB
A BB
A BB
A BB
131-11-3
208-96-8
606-20-2
Area(Hght) Amount
28649.
100432.
54347.
98520.
62289.
50750.
97588.
142092.
134779.
115381.
74816.
26238.
84951.
53560.
50841.
108330.
119147.
81492.
91760.
94316.
97001 .
48199.
89006.
66743.
144852.
71198.
51578.
41410.
95928.
148832.
45121.
76740.
104239.
64246.
33466.
69958.
217673.
93696.
35840.
69925.
197003.
44842.
46323.
45345.
140394.
56935.
154975.
219486.
39614.
40
40
40
40
40
40
82
84
86
79
76
81
80
81
69
81
84
83
85
83
83
78
82
79
79
rr
79
81
85
79
84
92
81
83
48
84
84
82
84
82
104
88
84
80
86
83
85
87
90
.000
.000
.000
.000
.000
.000
.774
.729
.967
.535
.346
.946
.059
.280
.648
.918
.537
.187
.590
.030
.731
.765
.857
.332
.645
.917
.498
.636
.850
.956
.179
.634
.300
.195
.330
.196
.809
.234
.907
.458
.439
.855
.486
.983
.659
.499
.067
.869
.042
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/HL
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
XTot
0.60
0.60
0.60
0.60
0.60
0.60
1.24
1.27
1.30
1.19
1.14
1.23
1.20
1.22
1.04
1.23
1.27
1.25
1.28
1.24
1.25
1.18
1.24
1.19
1.19
1.17
1.19
1.22
1.29
1.20
1.26
1.39
1.22
1.25
0.72
1.26
1.27
1.23
1.27
1.23
1.56
1.33
1.27
1.21
1.30
1.25
1.27
1.32
1.35
-------
10
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-------
3uantitat ion Report File: ST16980831
3ata: ST16980831.TI
38/31/98 12:31:00
Sample: SSTD080 80UG/ML CAL1 III 082198A
:onds.: INST. ID: F16
Formula: 1UL INJ. Instrument: F16
Submitted by: QES Analyst: DAT
\MOUNT=AREA * REF AMNT/(REF AREA * RESP FACT)
?esp. fac. from average of whole .RL
No
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
69
70
71
72
73
74
75
76
77
78
79
80
81
82
83
84
85
No
51
52
53
54
55
56
57
58
Name
C545
C550
C555
C565
C560
C570
C580
C590
C585
C595
C610
C615
C620
C625
C630
C635
C640
C645
C647
C650
C655
C710
C715
C720
C730
C725
C740
C745
C760
C765
C770
C775
C780
C785
C790
m/z
138
153
184
168
109
165
149
166
3-NITROANILINE
ACENAPHTHENE
2,4-DlNITROPHENOL
DIBENZOFURAN
4-NITROPHENOL
2,4-DINITROTOLUENE
DIETHYLPHTHALATE
FLUORENE
4-CHLOROPHENYL-PHENYLE
4-NITROANALINE
4,6-DINITRO-2-METHYLPH
N-NITROSODIPHENYLAMINE
AZOBENZENE
4-BROMOPHENYL-PHENYLET
HEXACHLOROBENZENE
PENTACHLOROPHENOL
PHENANTHRENE
ANTHRACENE
CARBAZOLE
DI-N-BUTYLPHTHALATE
FLUORANTHENE
BENZIDINE
PYRENE
BUTYLBENZYLPHTHALATE
BENZO(A)ANTHRACENE
3,3'-DICHLOROBENZIDINE
CHRYSENE
BIS(2-ETHYLHEXYL)PHTHA
DI-N-OCTYL PHTHALATE
BENZO(B)FLUORANTHENE
BENZO(K)FLUORANTHENE
BENZO(A)PYRENE
INDENO(1,2,3-CD)PYRENE
DIBENZ(A,H)ANTHRACENE
BENZO(G,H,I)PERYLENE
Scan Time Ref RRT
837 9:19 3 1.011
834 9:17 3 1.007
856 9:31 3 1.034
866 9:38 3 1.046
887 9:52 3 1.071
880 9:47 3 1.063
935 10:24 3 1.129
926 10:18 3 1.118
138
153
184
168
109
165
149
166
204
138
198
169
S3* 75
S3* 80CC
S3* 85SP
S3* 90
S3* 95SP
53*105
S3#130
S3#135
S3#140
S3#150
S4* 10
S4* 15CC
77 S4# 20
248
284
266
178
178
167
149
202
184
202
149
228
252
228
149
149
252
252
252
276
278
276
S4* 30
S4# 40
S4* 50
S4* 65
S4* 70
S4* 80
S4* 85
S4*110CC
S5# 10
S5#, 15
S5# 40
S5# 50
S5* 55
S5* 60
S5# 65
S6* 10CC
S6# 15
S6# 25
S6# 35
S6# 55
S6* 60
S6# 65
Meth Area(Hght)
A
A
A
A
A
A
A
A
BB 43517.
BB 136730.
BB 21832.
VB 196548.
BB 18892.
BB 51300.
BB 163921 .
BB 155682.
Weight: 0.000
Acct. No.: FIN
99-09-2
83-32-9
51-28-5
132-64-9
100-02-7
121-14-2
84-66-2
86-73-7
7005-72-3
100-01-6
534-52-1
87-30-6
103-33-3
101-55-3
118-74-1
87-86-5
85-01-8
120-12-7
86-74-8
84-74-2
206-44-0
92-81-5
129-00-0
85-68-7
56-55-3
91-94-1
218-01-9
117-81-7
117-84-0
205-99-2
207-08-9
50-32-8
193-39-5
53-70-3
191-24-2
Amount
83.685 UG/ML
86.856 UG/ML
84.885 UG/ML
86.670 UG/ML
80.538 UG/ML
95.049 UG/ML
88.144 UG/ML
88.292 UG/ML
XTot
1.25
1.30
1.27
1.30
1.21
1.42
1.32
1.32
luce
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-------
40
re
r?
30
31
32
33
34
35
Ret(L) Ratio
17:50 1.00
19:05 1.00
19:13
19:17
19:45
21:28
21:33
21:49
.00
.00
.00
.00
.00
.00
RRT(L)
1.033
0.962
0.969
0.972
0.996
1.082
1.086
1.100
Ratio
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
Amnt
83
85
78
90
83
85
84
85
.00
.62
.89
.17
.29
.07
.76
.64
Aimt(L)
50
50
50
50
50
50
50
50
.00
.00
.00
.00
.00
.00
.00
.00
R.Fac R
1.627
3.296
2.277
2.090
1.969
2.176
2.149
2.280
Fac(L) Ratio
0.980
1.925
1.443
1.159
1.182
1.279
1.267
1.331
1.66
1.71
1.58
1.80
1.67
1.70
1.70
1.71
1GC
-------
QUANTERRA GC/MS
SEMI VOLATILE APPENDIX IX CALIBRATION CHE
CONTIN.
INITIAL
INITIAL
INITIAL
INITIAL
INITIAL
INITIAL
Library
Entry
S1
S1
S1
SI
S1
S1
S1
S1
S1
S1
S1
S1
S2
S2
S2
52
S2
S2
S2
S3
S3
S3
S3
S3
S3
S3
S3
S3
S3
S3
S4
S4
S4
S4
S4
S4
S4
S4
S4
S4
SA
S5
S5
S5
S5
S5
S5
20
30
40
60
70
85
95
170
175
180
182
195
15
50
85
90
115
120
140
10
15
35
42
50
60
100
110
115
120
145
25
35
37
45
55
60
75
100
105
106
120
20
25
30
35
37
45
CALIBRATION: 80 UG/HL APPENDIX ST 16980831 A 08/31/98 13:07:00
CALIBRATION: 10 UG/HL APPENDIX ST16980831B 08/31/98 13:35:00
CALIBRATION: 20 UG/ML APPENDIX ST16980831C 08/31/98 14:02:00
CALIBRATION: 50 UG/ML APPENDIX ST16980831D 08/31/98 14:32:00
CALIBRATION: 80 UG/ML APPENDIX ST16980831A 08/31/98 13:07:00
CALIBRATION: 120 UG/ML APPENDIX ST16980831E 08/31/98 15:02:00
CALIBRATION: 160 UG/ML APPENDIX ST16980831F 08/31/98 15:31:00
Initial Calibration Continuing Calibration
Response Factor X RSD Amount X Diff
Compound
PYRIDINE
2-PICOLINE
N-NITROSOMETHYLETHYL
METHYLMETHANESULFONA
N-NITROSOOIETHYLAMIN
ETHYLMETHANE SULFONA
PENTACHLOROETHANE
C361 ACETOPHENONE
N-NITROSOPYRROLIDINE
N-NITROSOMORPHOLINE
3-METHYL PHENOL
0-TOLUIDINE
N-NITROSOPIPERIDINE
AA-DIMETHYLPHENETHYL
2,6-OICHLOROPHENOL
HEXACHLOROPROPENE
P-PHENYLENE DIAMINE
N-NITROSODI-N-BUTYLA
SAFROLE
1,2,4,5-TETRACHLOROB
ISOSAFROLE (#1)
ISOSAFROLE (#2
1-CHLORONAPHTH
1,4-NAPHTHOQUINONE
1,3-DINITROBENZENE
PENTACHLOROBENZENE
1-NAPHTHYLAMINE
2-NAPHTHYLAMINE
2,3,4,6-TETRACHLOROP
5-NITRO-0-TOLU1DINE
SYM-TRINITROBENZENE
PHENACETIN
OIALLATE
4-AMINOBIPHENYL
PRONAMIDE
PENTACHLORONITROBENZ
2SECBUTYL-4.6-DINITR
4-NITROQUINOLINE-1-0
METHAPYRILENE
ISODRIN
CHLOROBENZILATE
ARAMITE (#1)
ARAMITE (#2)
P-DIMETHYLAMINOAZOBE
3,3'-DIMETHYLBENZIDI
KEPONE
2-ACETYLAMINOFLUOREN
Avg
1.590
1.565
0.811
0.636
0.521
1.109
0.602
1.934
0.553
0.821
2.252
2.160
0.321
1.285
0.257
0.198
0.131
0.213
0.248
0.433
0.044
0.195
1.318
0.414
0.198
0.489
0.837
0.966
0.297
0.355
0.162
0.317
0.090
0.609
0.299
0.080
0.153
0.072
0.305
0.127
0.323
0.061
0.087
0.419
0.418
0.082
0.432
Min Max Calc
6.5
1.3
9.2
6.2
7.6
11.0
1.4
2.8
6.5
1.4
9.9
9.2
4.9
15.6
12.8
0.9
42.2
7.2
0.9
4.4
3.4
2.2
16.5
5.6
8.6
3.8
6.6
5.8
4.5
7.2
5.3
3.2
4.4
7.6
5.2
1.8
9.3
11.5
26.8
1.5
11.1
4.4
4.4
1.1
17.0
34.6
4.0
79.82
80.59
86.37
75.73
84.19
84.32
80.36
80.44
81.36
78.49
85.54
78.86
81.55
64.54
86.94
79.65
22.98
84.49
80.91
79.47
78.49
80.49
92.76
86.39
85.21
80.60
73.13
82.51
83.39
85.81
84.96
79.69
78.88
79.14
80.55
78.96
85.15
84.40
53.79
80.73
76.29
79.45
83.30
80. U
7T.B2
87.25
81.04
Exp
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
Max
0.2
-0.7
-8.0
5.3
-5.2
-5.4
-0.5
-0.5
-1.7
1.9
-6.9
1.4
-1.9
19.3
-8.7
0.4
71.3*
-5.6
-1.1
0.7
1.9
-0.6
-16.0
-8.0
-6.5
-0.7
8.6
-3.1
-4.2
-7.3
-6.2
0.4
1.4
1.1
-0.7
1.3
-6.4
-5.5
32.8
-0.9
4.6
0.7
-4.1
- -0 .2
2.7
-9.1
-1.3
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
en *"
50. U
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50,0
50.0
50.0
50.0
ItiCS
-------
85 3-METHYLCHOLANTHRENE 0.548 6.1 80.10 80.00 -0.1 50.0
< 20 7,12-DIMETHYLBENZANT 0.610 0.5 79.97 80.00 0.0 50.0
12.2% of the compounds exceed the %RSD value 0 CCC cmpds out
of 15.0. 6 of 49 compounds are out. 1 of nonCCC exceed 50 XD
-------
OUANTERRA GC/MS
SENIVOLATILE APPENDIX IX CALIBRATION CHE
CONTIN. CALIBRATION: 80 UG/ML APPENDIX ST16980831A 08/31/98 13:07:00
INITIAL CALIBRATION: 10 UG/ML APPENDIX ST16980831B 08/31/98 13:35:00
INITIAL CALIBRATION: 20 UG/ML APPENDIX ST16980831C 08/31/98 14:02:00
INITIAL CALIBRATION: 50 UG/ML APPENDIX ST16980831D 08/31/98 14:32:00
INITIAL CALIBRATION: 80 UG/ML APPENDIX ST16980831A 08/31/98 13:07:00
INITIAL CALIBRATION: 120 UG/ML APPENDIX ST16980831E 08/31/98 15:02:00
INITIAL CALIBRATION: 160 UG/ML APPENDIX ST16980831F 08/31/98 15:31:00
ST16980831A ST16980831B ST16980831C ST16980831D ST16980831A ST16980831E
ST16980831F
Lib # Cone RRF Cone RRF Cone RRF Cone RRF Cone RRF Cone RRF
S1 20 80, 1.587 10, 1.770 20, 1.583 50, 1.578 80, 1.587 120, 1.449
S1 20 160, 1.576
S1 30 80, 1.577 20, 1.563 50, 1.594 80, 1.577 120, 1.547
S1 30 160, 1.545
S1 40 80, 0.876 10, 0.700 20, 0.737 50, 0.823 80, 0.876 120, 0.860
SI 40 160, 0.870
S1 60 80, 0.602 10, 0.619 20, 0.688 50, 0.685 80, 0.602 120, 0.619
S1 60 160, 0.604
S1 70 80, 0.549 10, 0.450 20, 0.506 50, 0.521 80, 0.549 120, 0.547
S1 70 160, 0.555
SI 85 80, 1.168 10, 0.921 20, 1.008 50, 1.120 80, 1.168 120, 1.190
S1 85 160, 1.244 .',">
SI 95 80, 0.605 20, 0.612 50, 0.605 80, 0.605 120, 0.595
S1 95 160, 0.592
S1 170 80, 1.945 10, 1.869 20, 2.024 50, 1.960 80, 1.945 120, 1.903
SI 170 160, 1.903
S1 175 80, 0.562 10, 0.481 20, 0.555 50, 0.575 80, 0.562 120. 0.569
S1 175 160, 0.575
S1 180 80, 0.805 10, 0.828 20, 0.838 50, 0.821 80, 0.805 120, 0.817
S1 180 160, 0.816
SI 182 80, 2.408 10, 1.848 20, 2.130 50, 2.339 80, 2.408 120, 2.391
S1 182 160, 2.394
S1 195 80, 2.129 20, 2.463 50, 2.228 80, 2.129 120, 2.032
S1 195 160, 1.949
S2 15 80, 0.327 10, 0.293 20, 0.312 50, 0.326 80, 0.327 120, 0.337
S2 15 160, 0.329
S2 50 80, 1.036 20, 1.575 50, 1.353 80, 1.036 120, 1.276
S2 50 160, 1.184
S2 85 80, 0.280 10, 0.202 20, 0.234 50, O.Z64 80, O.ZBO HO, O.Z79 . ,
S2 85 160, 0.285
S2 90 80, 0.197 20, 0.196 50, 0.201 80, 0.197 120, 0.198 JL b J. JL
S2 90 160, 0.198
-------
2 115 80,
2 115 160,
2 120 80,
2 120 160,
2 HO 80,
2 140 160,
3 10 80,
3 10 160,
3 15 80,
3 15 160,
3 35 80,
3 35 160,
3 42 80,
3 42 160,
3 50 80,
3 50 160,
5 60 80,
i 60 160,
5 100 80,
5 100 160,
5 110 80,
5 110 160,
0.038
0.121
0.225 10, 0.186
0.224
0.250
0.250
0.430 10, 0.469
0.419
0.043
0.044
0.196
0.192
1.528 10, 1.531
1.488
0.447
0.389
0.210 10, 0.166
0.204
0.493 10, 0.516
0.471
0.765 10, 0.869
0.769
20, 0.163 50, 0.167 80, 0.038 120, 0.165
20, 0.205 50, 0.213 80, 0.225 120, 0.224
20, 0.246 50, 0.247 80, 0.250 120, 0.245
20, 0.431 50, 0.434 80, 0.430 120, 0.416
20, 0.046 50, 0.042 80, 0.043 120, 0.044
20, 0.201 50, 0.195 80, 0.196 120, 0.190
20, 1.098 50, 1.129 80, 1.528 120, 1.134
20, 0.403 50, 0.429 80, 0.447 120, 0.404
20, 0.191 50, 0.202 80, 0.210 120, 0.212
20, 0.504 50, 0.483 80, 0.493 120, 0.469
20, 0.859 50, 0.889 80, 0.765 120, 0.872
5 115 80,
5 115 160,
0.996 10, 0.924
0.881
20, 0.974 50, 1.041 80, 0.996 120, 0.980
5 120 80,
5 120 160,
0.310
0.290
20, 0.277 50, 0.302 80, 0.310 120, 0.306
5 145 80,
5 145 160,
0.381
0.316
20, 0.345 50, 0.368 80, 0.381 120, 0.367
• 25 80,
i 25 160,
i 35 80,
. 35 160,
0.172
0.159
0.316
0.311
20, 0.149 50, 0.162 80, 0.172 120, 0.166
20, 0.305 50, 0.324 80, 0.316 120, 0.330
• 37 80,
i 37 160,
. 45 80,
> 45 160,
0.089
0.097
0.602
0.546
20, 0.088 50, 0.087 80, 0.089 120, 0.089
20, 0.643 50, 0.664 80, 0.602 120, 0.590
55 80,
55 160,
0.301
0.277
20, 0.312 50, 0.315 80, 0.301 120, 0.291
60 80,
60 160,
0.079
0.081
20, 0.081 50, 0.079 80, 0.079 120, 0.082
75 80, 0.163
20, 0.130 50, 0.165 80, 0.163 120, 0.159
-------
S4 75 160, 0.150
S4 100 80,
S4 100 160,
S4 105 80,
S4 105 160,
S4 106 80,
S4 106 160,
S4 120 80,
S4 120 160,
S5 20 80,
S5 20 160,
S5 25 80,
S5 25 160,
S5 30 80,
S5 30 160,
S5 35 80,
S5 35 160,
S5 37 80,
S5 37 160,
S5 45 80,
S5 45 160,
S5 85 80,
S5 85 160,
S6 20 80,
S6 20 160,
0.076
0.075
0.205
0.277
0.128 10, 0.127
0.124
0.308 10, 0.376
0.281
0.061
0.061
0.090
0.085
0.420
0.420
0.406
0.346
0.089
0.054
0.438
0.440
0.549
0.514
0.610
0.609
20, 0.058 50, 0.074 80, 0.076 120. 0.079
20, 0.424 50, 0.339 80, 0.205 120, 0.279
20, 0.125 50, 0.129 80, 0.128 120, 0.127
20, 0.351 50. 0.329 80, 0.308 120, 0.295
20, 0.057 50. 0.063 80. 0.061 120, 0.064
20, 0.081 50, 0.090 80, 0.090 120, 0.087
20, 0.417 50, 0.425 80, 0.420 120, 0.412
20, 0.522 50, 0.450 80, 0.406 120, 0.364
20, 0.123 50, 0.087 80, 0.089 120, 0.056
20, 0.404 50, 0.450 80, 0.438 120. 0.429
20, 0.586 50, 0.576 80, 0.549 120. 0.515
20, 0.609 50, 0.615 80. 0.610 120, 0.608
IU13
-------
DATA FROM FILE: ST16980831A SCANS 238 TO 1208 ACQUIRED: 88/31/98 13:87:88
CALI: ST16980831A #3
SAMPLE: 80UG/ML AP9 862598F
CONDS.: INST. ID: F1S
600 _
6:40
800 .
8:54
1009 .
11:07
m J
j
HLOROBENZENE-D4 1521SI# 01
100.0Z < 296960.)
3855-82-1
-CTC0 NAPHTHALENE-08
•CI50 ACENAPHTHENE-D10
,68 PHENANTHRENE-D18
136IS2* 01
164IS3* 01
188IS4* 01
1146-65-2
15067-26-2
1517-22-2
-------
DATA FROM FILE: ST16980831A SCANS 1200 TO 2158 ACQUIRED: 08/31/98 13:07:00
CALI: ST16980831A #3
SAMPLE: 80UG/ML AP9 062598F
CONDS.: INST. ID: F16
1208 __
13:21 L
1400 _]
15:34
1600
17:48
I860 -J
20:01
2000 .
22:15
I
I
— C|70 CHRYSEHE-D12
CI75 PERYLEHE-D12
j
100.0?! < 139520.)
240IS5* 01
1719-03-5
34IS6* 01
1520-96-3
ffli
h-1
L -»
-------
luantitation Report File: ST16980831A
lata: ST16980831A.TI
18/31/98 13:07:00
lample: 80UG/ML AP9 062598F
ionds.: INST. ID: F16
ormula: 1UL INJ. Instrument: F16
•ubmitted by: QES Analyst: DAT
,MOUNT=AREA * REF AMNT/CREF AREA
esp. fac. from average of whole
No Name
1 CI30 1.4-DICHLOROBENZENE-D4
2 CKO NAPHTHALENE-DS
3 CI50 ACENAPHTHENE-D10
4 CI60 PHENANTHRENE-D10
5 C170 CHRYSENE-D12
6 CITS PERYLENE-D12
7 PYRIDINE
8 2-PICOLINE
9 N-NITROSOMETHYLETHYLAMINE
10 METHYLMETHANESULFONATE
11 N-NITROSODIETHYLAMINE
12 ETHYLMETHANE SULFONATE
13 PENTACHLOROETHANE
14 C361 ACETOPHENONE
15 N-N1TROSOPYRROLIDINE
6 N-NITROSOMORPHOLINE
7 3-METHYL PHENOL
8 0-TOLUIDINE
9 N-NITROSOPIPERIDINE
10 AA-DIMETHYLPHENETHYLAMINE *
'1 2,6-DICHLOROPHENOL
'2 HEXACHLOROPROPENE
3 P-PHENYLENE DIAMINE
4 N-NITROSOOI-N-BUTYLAMINE "
5 SAFROLE
6 1,2,4,5-TETRACHLOROBENZENE
7 ISOSAFROLE (#1)
8 ISOSAFROLE (#2)
9 1-CHLORONAPHTHALENE
0 1,4-NAPHTHOQUINONE
1 1,3-DINITROBENZENE
2 PENTACHLOROBENZENE
3 1-NAPHTHYLAMINE
4 2-NAPHTHYLAMINE
5 2,3,4,6-TETRACHLOROPHENOL
5 5-NITRO-O-TOLUIDINE
7 SYM-TRINITROBENZENE
3 PHENACETIN
* RESP FACT)
.RL
152IS1* 01
1361 S2# 01
164IS3* 01
188IS4* 01
2401S5* 01
164IS6* 01
79 S1# 20
93 SDK 30
42 S1# 40
80 S1# 60
102 S1# 70
79 SU» 85
117 S1# 95
105 S1#170
100 S10175
56 S1#180
108 S1#182
106 S1#195
42 S2# 15
' 58 S2# 50
162 S2# 85
213 S2# 90
108 S2#115
• 84 S2#120
752 S2#140
214 S3# 10
162 S3# 15
104 S3# 35
162 S3# 42
158 S3# 50
168 S3# 60
250 S3#100
143 S3#110
143 S3#115
232 S3#120
152 S3#145
75 S4# 25
108 S4#35
Weight:
Acct. No
3855-82-1
1146-65-2
15067-26-2
1517-22-2
1719-03-5
1520-96-3
110-86-1
109-06-8
10595-95-6
55-18-5
66-27-3
76-01-7
930-55-2
59-89-2
95-53-4
100-75-4
122-09-8
87-65-0
106-50-3
924-16-3
94-59-7
95-94-3
120-58-1
120-58-1
90-13-1
130-15-4
99-65-0
708-93-5
134-32-7
91-59-8
58-90-2
99-52-5
62-44-2
? DIAL LATE 234 S4# 37
D 4-AMINOBIPHENYL
1 PRONAMIDE
> PENTACHLORONITROBENZENE
5 2SECBUTYL-4.6-DINITROPHENOL
169 S4# 45
173 S4# 55
237 S4# 60
211 S4# 75
92-67-1
23950-58-5
82-68-8
88-85-7
4-NITROQUINOLINE-1-OXIDE 190 S4#100
METHAPYRILENE 58 S4#105
ISODRIN
CHLOROBENZILATE 139 S4#120
0.000
FIN
91-80-5
S I * 1 •%.
jA; j.v;
-------
No
48
49
50
No
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
Name
ARAMITE (#1) 185 S5# 20
ARAMITE (#2) 185 S5# 25
P-OIMETHYLAMINOAZOBENZENE 120 S5# 30
m/z
152
136
164
188
240
264
79
93
42
80
102
79
117
105
100
56
108
106
42
58
162
213
108
84
162
214
162
104
162
158
168
250
143
143
232
152
75
108
234
169
173
237
211
190
58
193
139
185
185
120
Scan
340
530
828
1087
1551
1782
103
145
157
182
218
255
302
404
405
411
419
408
451
710
552
549
667
620
648
681
698
737
733
770
803
858
883
899
895
940
1025
1034
1018
1069
1096
1061
1108
1236
1266
1270
1427
1399
1414
1412
Time
3:47
5:54
9:13
12:05
17:15
19:49
1:09
1:37
1:45
2:01
2:25
2:50
3:22
4:30
4:30
4:34
4:40
4:32
5:01
7:54
6:08
6:06
7:25
6:54
7:12
7:34
7:46
8:12
8:09
8:34
8:56
9:33
9:49
10:00
9:57
10:27
11:24
11:30
11:19
11:53
12:11
11:48
12:19
13:45
14:05
14:08
15:52
15:34
15:44
15:42
Ref
1
2
3
4
5
6
1
1
1
1
1
1
1
1
1
1
1
1
2
2
2
2
2
2
2
3
3
3
3
3
3
3
3
3
3
3
4
4
4
4
4
4
4
4
4
4
4
5
5
5
RRT
1.000
1.000
1.000
1.000
1.000
1.000
0.303
0.426
0.462
0.535
0.641
0.750
0.888
1.188
1.191
1.209
1.232
1.200
0.851
1.340
1.042
1.036
1.258
1.170
1.223
0.822
0.843
0.890
0.885
0.930
0.970
1.036
1.066
1.086
1.081
1.135
0.943
0.951
0.937
0.983
1.008
0.976
1.019
1.137
1.165
1.168
1.313
0.902
0.912
0.910
Meth
A BB
A BB
A BB
A BB
A BV
A BB
A BB
A BB
A BB
A BB
A BB
A BB
A BB
A BB
A BB
A BV
A BB *
A BB^
A BV T*
qedt\j)
A BB ,
Area(Hght)
29680.
108356.
60104.
107988.
69686.
54786.
94198.
93595.
51975.
35745.
32568.
69355.
35884.
115427.
33375.
47803.
142918.
126404.
70838.
224618.
60603.
A BB A^ 42724.
qedt(j) • 8144.
A BB
A BB
A BB
A BB
A BB
A BB
A BB
A BB
A BB
A BB
A BB
A BB
A BB
A VB
A BB
A BV
A BB
A BB
A BB
A VB
A BB
A BB
A BV
A BB
A BB
A BB
A VB
4871 1 .
54270.
51722.
5166.
23560.
183709.
53790.
25287.
59261 .
91990.
119758.
37212.
45826.
37064.
68243.
19166.
130115.
65067.
17138.
35264.
16496.
44262.
27606.
66594.
8471.
12567.
58473.
140-57-8
140-57-8
60-11-7
Amount
40.000 UG/ML
40.000 UG/ML
40.000 UG/ML
40.000 UG/ML
40.000 UG/ML
40.000 UG/ML
79.822 UG/ML
80.606 UG/ML
86.359 UG/ML
75.724 UG/ML
84.191 UG/ML
84.324 UG/ML
80.375 UG/ML
80.441 UG/ML
81.342 UG/ML
78.504 UG/ML
85.538 UG/ML
78.852 UG/ML
81.594 UG/ML
64.531 UG/ML
86.895 UG/ML
79.594 UG/ML
22.982 UG/ML
84.388 UG/ML
80.884 UG/ML
79.457 UG/ML
78.765 UG/ML
80.505 UG/ML
92.771 UG/ML
86.357 UG/ML
85.215 UG/ML
80.576 UG/ML
73.120 UG/ML
82.503 UG/ML
83.399 UG/ML
85.785 UG/ML
84.994 UG/ML
79.750 UG/ML
78.905 UG/ML
79.141 UG/ML
80.495 UG/ML
78.989 UG/ML
85.064 UG/ML
84.279 UG/ML
53.806 UG/ML
80.734 UG/ML
76.253 UG/ML
79.616 UG/ML
83.361 UG/ML
80.139 UG/ML
XTot
0.97
0.97
0.97
0.97
0.97
0.97
1.93
1.95
2.09
1.83
2.04
2.04
1.94
1.94
1.97
1.90
2.07
1.91
1.97
1.56
2.10
1.92
0.56
2.04
1.96
1.92
1.90
1.95
2.24
2.09
2.06
1.95
1.77
1.99
2.02
2.07
2.05
1.93
1.91
1.91
1.95
1.91
2.06
2.04
1.30
1.95
1.84
1.92
2.02
1.94
i U
-------
No
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
Ret(L)
3:47
5:54
9:13
12:05
17:15
19:49
1:09
1:37
1:45
2:01
2:25
2:50
3:22
4:30
4:30
4:34
4:40
4:32
5:01
7:54
6:08
6:06
7:25
6:54
7:12
7:34
7:46
8:12
8:09
8:34
8:56
9:33
9:49
10:00
9:57
10:27
11:24
11:30
11:19
11:53
12:11
11:48
12:19
13:45
14:05
14:08
15:52
15:34
15:44
15:42
Ratio
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
RRT(L)
1.000
1.000
1.000
1.000
1.000
1.000
0.303
0.426
0.462
0.535
0.641
0.750
0.888
1.188
1.191
1.209
1.232
1.200
0.851
1.340
1.042
1.036
1.258
1.170
1.223
0.822
0.843
0.890
0.885
0.930
0.970
1.036
1.066
1.086
1.081
1.135
0.943
0.951
0.937
0.983
1.008
0.976
1.019
1.137
1.165
1.168
1.313
0.902
0.912
0.910
Ratio
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
Amnt
40
40
40
40
40
40
79
80
86
75
84
.00
.00
.00
.00
.00
.00
.82
.61
.36
.72
.19
84.32
80.38
80
81
78
85
78
81
64
86
79
22
84
80
79
78
80
92
86
85
80
73
82
83
85
84
79
78
79
80
78
85
84
53
80
76
79
83
80
.44
.34
.50
.54
.85
.59
.53
.89
.59
.98
.39
.88
.46
.76
.51
.77
.36
.22
.58
.12
.50
.40
.79
.99
.75
.90
.14
.50
.99
.06
.28
.81
.73
.25
.62
.36
.14
Amnt(L)
40
40
40
40
40
40
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
R.Fac R
1.000
1.000
1.000
1.000
1.000
1.000
2.539
2.523
1.401
0.963
0.878
1.869
0.967
3.111
0.900
1.288
3.852
3.407
0.523
1.658
0.447
0.315
0.060
0.360
0.401
0.688
0.069
0.314
2.445
0.716
0.337
0.789
1.224
1.594
0.495
0.610
0.275
0.506
0.142
0.964
0.482
0.127
0.261
0.122
0.328
0.205
0.493
0.097
0.144
0.671
Fac(L) Ratio
1.000 1.00
1.000 1.00
1.000 1.00
1.000 1.00
1.000 1.00
1.000 1.00
1.590 1.60
1.565 1.61
0.811 1.73
0.636 1.51
0.521 1.68
1.108 1.69
0.602 1.61
1.934 1.61
0.553 1.63
0.821 1.57
2.252 1.71
2.160 1.58
0.320 1.63
1.285 1.29
0.257 1.74
0.198 1.59
0.131 0.46
0.213
0.248
0.433
0.044
0.195
1.318
0.415
0.197
0.489
0.837
0.966
0.297
0.356
0.162
0.317
0.090
0.609
0.299
.69
.62
.59
.58
.61
.86
.73
.70
.61
.46
.65
.67
.72
.70
.59
.58
.58
.61
0.080 1.58
0.154 1.70
0.073 1.69
0.305 1.08
0.127 1.61
0.323 1.53
0.061 1.59
0.087 1.67
0.419 1.60
-------
Quantisation Report File: ST16980831A
Data: ST16980831A.TI
08/31/98 13:07:00
Sample: 80UG/ML AP9 062598F
Conds.: INST. ID: F16
Formula: 1UL INJ.
Submitted by: OES
Instrument: F16
Analyst: DAT
Weight: 0.000
Acct. No.: FIN
AMOUNT=AREA * REF AMNT/(REF AREA * RESP FACT)
Resp. fac. from average of whole .RL
No
51
52
53
54
55
56
No
51
52
53
54
55
56
No
51
52
53
54
55
56
Name
3,3'-DIMETHYLBENZIDINE
KEPONE
2-ACETYLAMINOFLUORENE
3-METHrLCHOLANTHRENE
7,12-DIMETHYLBENZANTHRACENE
HEXACHLOROPHENE
m/z Scan Time Ref
212 1472 16:22
272 1458 16:13
181 1516 16:52
268 1832 20:23
256 1731 19:15
NOT FOUND
Ret(L) Ratio RRT(L)
16:22 1.00 0.949
16:13 1.00 0.940
16:52 1.00 0.977
20:23 1.00 1.181
19:15 1.00 0.971
21:11 0.992
5
5
5
5
6
RRT
0.949
0.940
0.977
1.181
0.971
Ratio
1.
1.
1.
1.
1.
00
00
00
00
00
212 S5#
272 S5#
181 S5#
268 S5#
256 S6#
196 S6#
Meth^
A BB*
qedt@
A BB .
ABB(?
A BB
Amnt
77.81
87.08
81.05
80.10
79.99
35
37
45
85
20
30
53-96-3
56-49-5
75-97-6
70-30-4
j
Area(Hght)
56612.
12434.
61022.
76474.
66838.
Amnt(L) R
50.00
50.00
50.00
50.00
50.00
Amount
77.811
87.077
81.053
80.095
79.991
XTot
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
.Fac R.Fac(L)
0.650
0.143
0.701
0.878
0.976
0.418
0.082
0.432
0.548
0.610
1
2
1
1
1
.88
.10
.96
.94
.93
Ratio
1
1
1
1
1
.56
.74
.62
.60
.60
ANUAL LUU UUUt6
i. PEAK NOT FOUND
a. POORCHROMATOGRAPh.
3. WRONG tSOMER
UL MANUAL EDITS MUST BE
~), DATED, AND COJ>:i
-------
RIC+MASS CHROMATOGRAM
08x31/98 13:07:08
SAMPLE: 80UG/ML AP9 062598F
CONDS.: INST. ID: F16
RANGE: G 1,2158 LABEL: N 0,
DATA: ST16980831A #1
CALI: ST16980831A #3
2.0 QUAN: A 6, 2.0 J 0
100.0-
SCANS 480 TO 850
BASE: U 20,
710
58
RIC
7528.
58.017
± 0.500
218112.
500
5:34
550
6:07
600
6:40
700
7:47
750
8:21
800
8:54
850 SCAN
9:27 TIME
O
-------
RIC+MASS CHROMATOGRAM DATA: ST16980831A #1 SCANS 600 TO 800
08/31/98 13:07:00 CALI: ST16980831A #3
SAMPLE: 80UG/ML AP9 062598F
CONDS.: INST. ID: F16
RANGE: G 1,2158 LABEL: N 0, 2.0 QUAN: A 6, 2.0 J 0 BASE: U 20, 3
862.8n
RIC
750
8:21
1011.
108.032
± 0.500
43622.
800 SCAN
8:54 TIME
-------
100.0-
272
RIC
RIC+MASS CHROMATOGRAM DATA: ST16980831A #1 SCANS 1440 TO 1590
08/31x98 13:07:00 CALI: ST16980831A #3
SAMPLE: 80UGXML AP9 062598F
CONDS.: INST. ID: FIG
RANGE: G 1.2158 LABEL: N 0, 2.0 QUAN: A 6, 2.0 J 0 BASE: U 20, 3
1458
1487
1500
1508
14-
16
40
101
_1459 J
1460
16:14
\ lib/
V_^Iv/~x^
1480
16:28
_L3§L^ J
\ '
1500
16:41
^^.
1520
16:54
1538
— -i
1540
17:08
1560
17:21
1580
17:34
210.
272.881
± 0.500
94592.
SCAN
TIME
-------
OUANTERRA GC/MS
SEMIVOLATILE HSL CALIBRATION CHECK
CONTIN. CALIBRATION: 80 UG/ML HSL STD ST 16980902 09/02/98 14:53:00
INITIAL CALIBRATION: 10 UG/ML HSL STD ST16980827A 08/27/98 9:56:00
INITIAL CALIBRATION: 20 UG/ML HSL STD ST16980827B 08/27/98 10:21:00
INITIAL CALIBRATION: 50 UG/ML HSL STD ST16980827C 08/27/98 10:51:00
INITIAL CALIBRATION: 80 UG/ML HSL STD ST16980827 08/27/98 9:22:00
INITIAL CALIBRATION: 120 UG/ML HSL STD ST 169808270 08/27/98 11:20:00
INITIAL CALIBRATION: 160 UG/ML HSL STD ST16980827E 08/27/98 11:50:00
Initial Calibration Continuing Calibration
Library • Response Factor X RSO Amount X Diff
Entry
SI 15
S1 100
S1 105
S1 110
S1 115
S1 125
SI 130
SI 145
S1 150
SI 160
S1 165
S1 185
S1 190
SI 200
S2 10
S2 20
S2 25
S2 30
S2 45
S2 35
S2 40
S2 55
S2 60
S2 80
S2 95
S2 130
S2 145
S3 20
S3 25
S3 30
S3 40
S3 45
S3 55
S3 65
S3 70
S3 75
S3 80
S3 85
Compound
C310
C320
C315
C325
C330
C335
C340
C345
C350
C355
C360
C365
C370
C375
C410
C415
C420
C425
C430
C435
C440
C445
C450
C455
C460
C465
C470
C510
C515
C520
C525
C530
C535
C540
C543
C545
C550
C555
N-NITROSOOIMETH
ANILINE
PHENOL
BIS(2-CHLOROETH
2-CHLOROPHENOL
1,3-OICHLOROBEN
1,4-DICHLOROBEN
BENZYL ALCOHOL
1,2-DICHLOROBEN
2-METHYLPHENOL
2,2'-OXYBlS(1-C
4-METHYLPHENOL
N-N1TROSO-OI-N-
HEXACHLOROETHAN
NITROBENZENE
ISOPHORONE
2-NITROPHENOL
2,4-DIMETHYLPHE
BENZOIC ACID
BIS(2-CHLOROETH
2,4-DICHLOROPHE
1,2.4-TRICHLORO
NAPHTHALENE
4-CHLOROANALINE
HEXACHLOROBUTAD
4-CHLORO-3-METH
2-METHYLNAPHTHA
HEXACHLOROCYCLO
2.4,6-TRICHLORO
2.4,5-TRICHLORO
2-CHLOROMAPHTHA
2-NITROANALINE
DIMETHYLPHTHALA
ACENAPHTHYLENE
2,6-DINITROTOLU
3-NITROANILINE
ACENAPHTHENE
2,4-DINITROPHEN
1
1
1
1
1
1
1
0
1
1
2
1
0
0
0
0
0
0
0
0
0
0
1
0
0
0
0
0
0
0
1
0
1
1
0
0
1
0
Avg
.019
.846
.968
.368
.497
.586
.618
.854
.500
.174
.539
.276
.906
.708
.445
.742
.213
.330
.276
.511
.308
.331
.022
.454
.168
.338
.751
.372
.404
.412
.193
.502
.341
.839
.324
.383
.158
.189
Min
4
6
7
6
5
4
4
9
5
7
3
9
0.050 5
3
7
5
7
16
4
4
6
5
6
4
5
9
10
0.050 10
10
7
6
2
6
8
8
1
6
0.050 10
Max Calc
.4
.2
.8
.1
.5
.5
.8
.3
.0
.4
.9
.0
.1
.5
.2
.5
.9
.9
.7
.1
.6
.0
.6
.5
.1
.0
.8
.1
.6
.1
.6
.9
.1
.2
.5
.4
.9
.3
77.
72.
30.0 78.
84.
82.
81.
30.0 80.
71.
80.
74.
77.
71.
75.
79.
84.
80.
30.0 82.
91.
44.
80.
30.0 80.
85.
85.
82.
30.0 86.
30.0 80.
17
66
81
70
69
00
31
16
48
75
25
19
97
54
18
59
30
51
76
57
28
14
54
80
60
18
103.64
83.99
30.0 79.
80.
85.
79.
84.
86.
87.
81.
06
17
88
87
51
94
18
46
30.0 86.26
68.85
Exp
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
3.5
9.2
1.5
-5.9
-3.4
-1.3
-0.4
11.1
-0.6
6.6
3.4
11.0
5.0
0.6
-5.2
-0.7
-2.9
-14.4
•44. 1
-0.7
-0.3
-6.4
-6.9
-3-5
-8.2
-0.2
-29.5
-5.0
1.2
-0.2
-7.4
0.2
-5.6
-8.7
-9.0
-1.8
-7.8
13.9
Max
50.0
50.0
20.0
50.0
50.0
50.0
20.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
20.0
50.0
50.0
50.0
20.0
50.0
50.0
50.0
20.0
20.0
50.0
50.0
20.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
20.0
50.0
-------
OUANTERRA GC/MS
SEMIVOLATILE HSL CALIBRATION CHECK
ONTIN. CALIBRATION: 80 UG/ML HSL STD ST16980902
NITIAL CALIBRATION: 10 UG/ML HSL STD ST16980827A
NITIAL CALIBRATION: 20 UG/ML HSL STD ST16980827B
NITIAL CALIBRATION: 50 UG/ML HSL STD ST16980827C
NITIAL CALIBRATION: 80 UG/ML HSL STD ST 16980827
NITIAL CALIBRATION: 120 UG/ML HSL STD ST16980827D
NITIAL CALIBRATION: 160 UG/ML HSL STD ST16980827E
Initial Calibration
ibrary Response Factor X RSD
Entry
3
3
3
3
3
3
4
4
;
4
4
4
*
4
t
t
;
•>
i
>
>
>
j
>
b
b
b
b
b
b
b
1
>
5
3
I
1
1
5
90
105
130
140
135
150
10
15
20
30
40
50
65
70
80
85
110
10
15
40
55
50
60
65
10
15
25
35
55
60
65
6
2
3
2
3
2
5
2
Compound
C565
C570
C580
C585
C590
C595
C610
C615
C620
C625
C630
C635
C640
C645
C647
C650
C655
C710
C715
C720
C725
C730
C740
C745
C760
C765
C770
C775
C780
C785
C790
CS75
CS20
CS25
CS30
CS45
CS50
CS70
CS55
DIBENZOFURAN 1
2,4-DINITROTOLU
DIETHYLPHTHALAT
4-CHLOROPHENYL-
FLUORENE
4-NITROANALINE
4.6-DINITRO-2-H
N-NITROSODIPHEN
AZOBENZENE
4-BROMOPHENYL-P
HEXACHLOROBENZE
PENTACHLOROPHEN
PHENANTHRENE
ANTHRACENE
CARBAZOLE
DI-N-BUTYLPHTHA
FLUORANTHENE
BENZIDINE
PYRENE
BUTYLBENZYLPHTH
3,3'-DICHLOROBE
BENZO(A}ANTHRAC
CHRYSENE
BIS(2-ETHYLHEXY
DI-N-OCTYL PHTH
BENZO(B)FLUORAN
BENZO(K)FLUORAN
BENZO(A)PYRENE
INDENO(1,2,3-CD
DIBENZ(A.H)ANTH
BENZO(G,H, 1)PER
1,2-DICHLOROBNZ
NITROBENZENE-D5
2-FLUOROBIPHENY
TERPHENYL-D14
PHENOL-05
2-FLUOROPHENOL
2-CHLOROPHENOL-
2,4,6-TRIBROMOP
Avg Min Max
.669
0.397
1
.369
0.613
1
0
0
0
1
0
0
0
1
0
0
1
0
0
1
0
0
1
1
0
1
1
1
1
1
1
1
0
0
1
0
2
1
1
0
.298
.307
.132
.551
.171
.223
.260
.155
.033
.987
.764
.247
.900
.129
.323
.685
.408
.125
.014
.980
.925
.444
.159
.182
.279
.267
.331
.920
.470
.234
.995
.026
.368
.482
.236
6.2
8.8
7.7
5.4
6.8
8.4
7.6
4.2 30.0
3.9
3.9
6.7
5.9 30.0
5.2
11.0
10.3
9.4
13.5 30.0
23.7
6.5
7.7
5.7
5.4
6.7
9.4
7.4 30.0
5.0
9.8
5.3 30.0
6.6
8.1
8.2
6.5
5.2
6.2
5.3
2.0
4.4
4.1
6.9
09/02/98 14:53:00
08/27/98 9:56:00
08/27/98 10:21:00
08/27/98 10:51:00
08/27/98 9:22:00
OB/27/98 11:20:00
08/27/98 11:50:00
Continuing Calibration
Amount X Diff
Calc
85.82
93.46
86.28
88.61
88.71
78.22
82.12
79.08
80.34
87.69
87.45
75.84
84.48
85.24
84.72
86.27
84.07
12.00
82.90
82.18
76.65
87.03
82.83
80.96
80.21
77.01
86.88
82.06
80.36
81.54
81.13
79.99
82.78
84.45
84.17
75.06
71.18
76.79
88.86
Exp
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
80.00
Max
-7
-16
-7
-10
-10
2
-2
1
-0
-9
-9
5
-5
-6
-5
-7
-5
85
-3
-2
4
-8
-3
-1
-0
3
-8
-2
-0
-1
-1
0
-3
-5
-5
6
11
4
-11
.3
.8
.9
.8
.9
.2
.7
.2
.4
.6
.3
.2
.6
.6
.9
.8
.1
.0*
.6
.7
.2
.8
.5
.2
.3
.7
.6
.6
.4
.9
.4
.0
.5
.6
.2
.2
.0
.0
.1
50.0
50.0
50.0
50.0
50.0
50.0
50.0
20.0
50.0
50.0
50.0
20.0
50.0
50.0
50.0
50.0
20.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
20.0
50.0
50.0
20.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
2.6% of the compounds exceed the XRSD value
of 15.0. 2 of 78 compounds are out.
O'CCC cmpds out
1 of nonCCC exceed 50 XD
1624
-------
QUANTERRA GC/MS
SEMIVOLATILE HSL CALIBRATION CHECK
CONTIN. CALIBRATION: 80 UG/ML HSL STD ST16980902 09/02/98 14:53:00
INITIAL CALIBRATION: 10 UG/ML HSL STO ST16980827A 08/27/98 9:56:00
INITIAL CALIBRATION: 20 UG/ML HSL STD ST16980827B 08/27/98 10:21:00
INITIAL CALIBRATION: 50 UG/ML HSL STD ST16980827C 08/27/98 10:51:00
INITIAL CALIBRATION: 80 UG/ML HSL STD ST16980827 08/27/98 9:22:00
INITIAL CALIBRATION: 120 UG/ML HSL STD ST16980827D 08/27/98 11:20:00
INITIAL CALIBRATION: 160 UG/ML HSL STD ST16980827E 08/27/98 11:50:00
ST16980902 ST16980827A ST16980827B ST16980827C ST16980827 ST16980827D
ST16980827E
Lib # Cone RRF Cone RRF Cone RRF Cone RRF Cone RRF Cone RRF
S1 15 80, 0.983 10. 0.952 20. 1.010 50. 1.016 80. 1.087 120. 1.008
S1 15 160, 1.042
S1 100 80, 1.677 10. 1.947 20, 1.988 50, 1.8H 80, 1.876 120, 1.778
SI 100 160, 1.674
S1 105 80, 1.939 10, 1.699 20, 2.037 50, 2.035 80, 2.148 120, 1.907
SI 105 160, 1.982
S1 110 80, 1.448 10. 1.336 20, 1.465 50, 1.438 80, 1.414 120, 1.291
SI 110 160, 1.261
S1 115 80, 1.547 10, 1.386 20, 1.569 50. 1.522 80. 1.603 120, 1.450
SI 115 160, 1.451
SI 125 80, 1.606 10, 1.515 20, 1.668 50. 1.618 80, 1.659 120, 1.546
S1 125 160, 1.510
S1 130 80, 1.624 10, 1.580 20, 1.695 50, 1.666 80, 1.697 120, l.a«.»
SI 130 160, 1.518
SI 145 80, 0.760 10, 0.702 20, 0.851 50, 0.872 80, 0.913 120, 0.866
S1 145 160, 0.922
S1 150 80, 1.509 10, 1.475 20, 1.606 50, 1.482 80, 1.573 120, 1.454
SI 150 160, 1.409
SI 160 80. 1.097 10, 0.998 20, 1.206 50, 1.221 80, 1.209 120, 1.199
S1 160 160, 1.213
S1 165 80, 2.452 10, 2.393 20, 2.676 50, 2.597 80, 2.582 120, 2.502
SI 165 160, 2.486
SI 185 80, 1.135 10, 1.049 20, 1.298 50, 1.355 80, 1.287 120, 1.316
S1 185 160, 1.351
SI 190 80, 0.860 10, 0.819 20, 0.934 50, 0.938 80, 0.940 120, 0.913
SI 190 160, 0.890
SI 200 80, 0.704 10, 0.665 20, 0.740 50, 0.713 80. 0.720 120, 0.706
SI 200 160, 0.706
S2 10 80, 0.468 10, 0.423 20, 0.477 50, 0.455 80. 0.466 120, 0,419
S2 10 160, 0.410
S2 20 80, 0.747 10, 0.685 20, 0.778 50, 0.774 80, 0.778 120. 0.726
S2 20 160, 0.708
-------
2 25 80, 0.219
2 25 160, 0.217
2 30 80, 0.377
2 30 160, 0.353
2 45 80, 0.154
2 45 160, 0.292
2 35 80, 0.514
2 35 160, 0.498
2 40 80, 0.309
2 40 160, 0.306
2 55 80, 0.352
2 55 160, 0.310
2 60 80, 1.093
2 60 160, 0.935
2 80 80, 0.470
2 80 160, 0.455
2 95 80, 0.182
2 95 160, 0.157
2 130 80, 0.339
> 130 160, 0.346
> 145 80, 0.973
2 145 160, 0.639
5 20 80, 0.390
5 20 160, 0.330
3 25 80, 0.399
5 25 160, 0.448
3 30 80, 0.413
3 30 160, 0.366
3 40 80, 1.280
3 40 160, 1.089
3 45 80, 0.501
3 45 160, 0.497
3 55 80, 1.417
3 55 160, 1.251
3 65 80, 1.998
3 65 160, 1.671
3 70 80, 0.353
3 70 160, 0.317
3 75 80, 0.390
3 75 160, 0.379
10, 0.182 20, 0.212 50, 0.218 80, 0.232 120, 0.219
10, 0.234 20, 0.309 50, 0.334 80, 0.400 120, 0.349
20, 0.257 50, 0.279 80, 0.270 120, 0.280
10, 0.481 20, 0.529 50, 0.517 80, 0.538 120, 0.502
10, 0.270 20, 0.313 50, 0.314 80, 0.332 120, 0.311
10, 0.319 20, 0.350 50, 0.334 80, 0.350 120, 0.322
10, 1.008 20, 1.090 50, 1.038 80, 1.102 120, 0.960
10, 0.419 20, 0.466 50, 0.454 80, 0.480 120, 0.449
10, 0.160 20, 0.178 50, 0.170 80, 0.177 120, 0.167
10, 0.279 20, 0.337 50, 0.353 80, 0.365 120, 0.347
10, 0.773 20, 0.840 50, 0.827 80, 0.757 120, 0.671
10, 0.329 20, 0.387 50, 0.376 80, 0.428 120, 0.379
10, 0.327 20, 0.389 50, 0.405 80, 0.435 120, 0.417
10, 0.397 20, 0.437 50, 0.429 80, 0.443 120, 0.401
10, 1.172 20, 1.275 50, 1.208 80, 1.283 120, 1.128
20, 0.491 50, 0.510 80, 0.523 120, 0.487
10, 1.257 20, 1.423 50, 1.392 80, 1.426 120, 1.297
10, 1.751 20, 1.959 50, 1.896 80, 2.047 120, 1.707
10, 0.274 20, 0.339 50, 0.341 80, 0.351 120, 0.321
20, 0.382 50, 0.392 80, 0.382 120, 0.379
f. O .*"*
'
i(<2o
JLVy *w \J
3 80 80, 1.249 10, 1.140 20, 1.227 50, 1.182 80, 1.261 120, 1.075
-------
S3 80 160, 1.066
S3 85 80, 0.163
S3 85 160, 0.196
S3 95 80, 0.131
S3 95 160, 0.169
20, 0.156 50, 0.190 80, 0.202 120, 0.203
20, 0.164 50, 0.178 80. 0.184 120, 0.168
10;
-------
QUANTERRA GC/MS
SEMI VOLATILE HSL CALIBRATION CHECK
>NTIN. CALIBRATION: 80 UG/ML HSL STD ST16980902 09/02/98 14:53:00
IIT1AL CALIBRATION: 10 UG/ML HSL STD ST16980827A 08/27/98 9:56:00
I1TIAL CALIBRATION: 20 UG/ML HSL STD ST16980827B 08/27/98 10:21:00
I1TIAL CALIBRATION: 50 UG/ML HSL STD ST16980827C 08/27/98 10:51:00
IITIAL CALIBRATION: 80 UG/ML HSL STD ST16980827 08/27/98 9:22:00
IITIAL CALIBRATION: 120 UG/ML HSL STD ST16980827D 08/27/98 11:20:00
IITIAL CALIBRATION: 160 UG/ML HSL STD ST16980827E 08/27/98 11:50:00
ST16980902 ST16980827A ST16980827B ST16980827C ST16980827 ST16980827D
ST16980827E «
b # Cone RRF Cone RRF Cone RRF Cone RRF Cone RRF Cone RRF
. 90 80, 1.790 10, 1.617 20, 1.782 50, 1.736 80, 1.762 120, 1.556
90 160, 1.561
. 105 80, 0.464 10, 0.339 20, 0.412 50, 0.420 80, 0.437 120, 0.396
105 160, 0.378 - - '.
130 80, 1.476 10, 1.300 20, 1.462 50, 1.452 80, 1.462 120, 1.328
130 160, 1.209
140 80, 0.678 10, 0.597 20, 0.647 50, 0.631 80, 0.646 120, 0.579
140 160, 0.575
135 80, 1.439 10, 1.251 20, 1.398 50, 1.340 80, 1.386 120, 1.224
135 160, 1.188
150 80, 0.300 20, 0.326 50, 0.320 80, 0.306 120, 0.263
150 160, 0.321
10 80, 0.135 20, 0.121 50, 0.139 80, 0.145 120, 0.124
10 160, 0.130
15 80, 0.544 10, 0.568 20, 0.582 50, 0.562 80, 0.539 120, 0.530
15 160, 0.523
20 80, 1.176 10, 1.150 20, 1.222 50, 1.186 80, 1.212 120, 1.098
20 160, 1.158
30 80, 0.244 10, 0.224 20, 0.231 50, 0.223 80, 0.232 120, 0.215
30 160, 0.210
40 80, 0.284 10, 0.273 20, 0.281 50, 0.255 80, 0.268 120, 0.238
40 160, 0.242
50 80, 0.147 20, 0.148 50, 0.156 80, 0.170 120, 0.155
50 160, 0.147
65 80, 1.090 10, 1.017 20, 1.081 50, 1.044 80, 1.096 120, 0.948
65 160, 1.010
70 80, 1.051 10, 1.019 20, 1.100 50, 1.026 80, 1.059 120, 0.908
70 160, 0.809
80 80, 0.809 10, 0.914 20, 0.763 50, 0.729 80, 0.769 120, 0.707
80 160, 0.701
85 80, 1.345 10, 1.233 20, 1.366 50, 1.332 80, 1.333 120, 1.137
85 160, 1.080
-------
S4 110 80, 0.946
S4 110 160. 0.715
S5 10 80, 0.019
S5 10 160, 0.131
S5 15 80, 1.370
S5 15 160, 1.358
S5 40 80, 0.703
S5 40 160, 0.734
S5 55 80, 0.391
S5 55 160, 0.391
S5 50 80, 1.224
S5 50 160, 1.092
S5 60 80, 1.050
S5 60 160, 0.919
S5 65 80, 0.992
S5 65 160, 1.089
S6 10 80, 1.930
S6 10 160, 2.023
S6 15 80, 1.390
S6 15 160, 1.412
S6 25 80, 1.259
S6 25 160, 0.940
S6 35 80, 1.212
S6 35 160, 1.084
S6 55 80, 1.285
S6 55 160, 1.144
S6 60 80, 1.292
S6 60 160, 1.105
S6 65 80, 1.350
S6 65 160, 1.139
S1 6 80, 0.920
S1 6 160, 0.882
52 2 80, 0.486
S2 2 160, 0.452
S3 3 80, 1.303
S3 3 160, 1.116
S5 2 80, 1.047
S5 2 160, 1.019
S1 3 80, 1.900
S1 3 160, 1.971
10, 1.013 20. 1.008 50. 0.925 80. 0.950 120. 0.788
20, 0.155 50, 0.143 80. 0.077 120, O.U1
10, 1.209 20, 1.310 50, 1.295 80, 1.468 120, 1.295
10, 0.587 20, 0.673 50, 0.692 80. 0.722 120, 0.700
20, 0.441 50. 0.421 80, 0.383 120, 0.405
10, 1.058 20, 1.195 50, 1.116 80, 1.203 120, 1.086
10, 1.034 20, 1.068 50, 1.005 80. 1.102 120, 0.959
10, 0.812 20, 0.978 50, 0.986 80, 1.027 120, 0.987
10, 1.637 20, 1.959 50. 1.985 80, 1.977 120, 1.967
10, 1.322 20, 1.536 50, 1.448 80, 1.453 120, 1.490
10, 1.185 20, 1.223 50, 1.171 80, 1.264 120. 1 '""
10, 1.168 20, 1.257 50, 1.206 80, 1.229 120, 1.147
10, 1.253 20, 1.355 50, 1.312 80, 1.368 120. 1.241
10. 1.254 20, 1.386 50, 1.288 80, 1.360 120. 1.212
10, 1.339 20, 1.436 50, 1.356 80, 1.426 120, 1.289
10, 0.832 20, 0.999 50, 0.946 80, 0.959 120, 0.902
10, 0.446 20, 0.494 50, 0.469 80. 0.504 120, 0.452
10, 1.252 20, 1.315 50, 1.253 80, 1.299 120, 1.171
10. 0.932 20, 1.002 5Qr fl.976 80. 1.082 120. 0.960
20, 2.057 50, 2.059 80, 2.046 120, 1.995
S1 2 80, 1.217
20, 1.291 50, 1.332 80. 1.448 120, 1.376
-------
2 160. 1.394
5 80, 1.422
5 160. 1.407
2 80, 0.262
2 160, 0.217
20, 1.561 50, 1.501 80, 1.503 120, 1.437
20, 0.261 50, 0.239 80, 0.233 120, 0.228
•\ ttT2 ~
1U C U
-------
DATA FROM FILE: ST16980902 SCANS 230 TO 1200 ACQUIRED: 09/"02/-98 14:53:00
CALI: ST16980902 #3
SAMPLE: SSTD080 80UG/ML CALI III 082198A
CONDS.: INST. ID: F16
j 100.07Z < 188928.)
99SS1* 03
3855-82-1
1000 -
11:07
SR66eNZENE-D4 152IS1* 01
6S?5Hb2-DICHLOROBNZN-D4 152 Sl# 06
82SS2* 02
(USB riCEHnPHTHEHE-DlQ
4165-62-2
136IS2* 01
525 2-FLUOROBIPHENYL
164iS3# 01
02
188IS4tt 01
4165-60-0
1146-65-2
172SS3* 03
15067-26-2
118-79-6
1517-22-2
321-60-8
Hffi -
c:
-------
DATA FROM FILE: ST16980902 SCANS 1200 TO 2158 ACQUIRED: 09/02/98 14:53:00
CALI: ST16980902 #3
SAMPLE: SSTD080 80UG/ML CALI III 082198A
CONDS.: INST. ID: F16
1200 .
13:21
1400 _[
15:34
1600 _
17:48
1800 4
28:01
2000 _
22:15
flfil
J_
j
100.07. < 125568.)
CS30 TERPHENYL-D14
244SS5* 02
1718-51-0
CI70 CHRYSENE-D12
240IS5* 01
1719-03-5
164IS6* 01
1520-96-3
CO
-------
Quantitat ion Report File: ST16980902
Data: ST16980902.TI
09/02/98 14:53:00
Sanple: SSTD080 80UG/HL CAL1 III 082198A
Conds.: INST. ID: F16
Formula: 1UL INJ. Instrument: F16
Submitted by: QES Analyst: DAT
AMOUNT=AREA * REF AMNT/(REF AREA * RESP FACT)
Resp. fac. from average of whole .RL
Weight: 0.000
Acct. No.: FIN
No
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
Name
CI30
CI40
CI50
CI60
CI70
CITS
CS20
CS25
CS30
CS45
CS50
CS55
CS70
CS75
1.4-DICHLOROBEN2ENE-D4
NAPHTHALENE-DS
ACENAPHTHENE-D10
PHENANTHRENE-D10
CHRYSENE-D12
PERYLENE-D12
NITROBENZENE-OS
2-FLUOR08IPHENYL
TERPHENYL-D14
PHENOL-D5
2-FLUOROPHENOL
2,4,6-TRIBROMOPHENOL
2-CHLOROPHENOL-D4
1.2-DICHLOROBNZN-D4
152IS1* 01
1361 S2* 01
164IS3* 01
1881 S4* 01
240IS5* 01
164IS6# 01
82SS2* 02
172SS3* 03
244SS50 02
99SS1* 03
112SS1* 02
330SS3* 02
132
152
SI* 05
S1# 06
3855-82-1
1146-65-2
15067-26-2
1517-22-2
1719-03-5
1520-96-3
4165-60-0
321-60-8
1718-51-0
4165-62-2
367-12-4
118-79-6
HEXACHLOROBENZENE-C13
C310
C320
C315
C325
C330
C335
C340
C345
C350
C355
C360
C365
C370
C375
C410
C415
C420
C425
C435
C440
C430
C445
C450
C455
C460
C465
C470
C510
C515
C520
C525
C530
N-NITROSOOIMETHYLAMINE
ANILINE
PHENOL
BIS(2-CHLOROETHYL)ETHER
2-CHLOROPHENOL
1,3-DICHLOROBENZENE
1,4-DICHLOROBENZENE
BENZYL ALCOHOL
1,2-DICHLOROBENZENE
2-METHYLPHENOL
2,2'-OXYBIS(1-CLPROPAN)
4-METHYLPHENOL
N-NITROSO-D1-N-PROPYLAM
HEXACHLOROETHANE
NITROBENZENE
1SOPHORONE
2-NITROPHENOL
2,4-DIMETHYLPHENOL
BIS(2-CHLOROETHOXY)METH
2,4-DlCHLOROPHENOL
BENZOIC ACID
1,2,4-TRICHLOROBENZENE
NAPHTHALENE
4-CHLOROANALINE
HEXACHLOROBUTADIENE
4-CHLORO-3-METHYLPHENO
2-METHYLNAPHTHALENE
HEXACHLOROCYCLOPENTAD I
2,4,6-TRICHLOROPHENOL
2,4,5-TRICHLOROPHENOL
2-CHLORONAPHTHALENE
2-NITROANALINE
74 S1* 15
93
94
93
128
146
146
108
146
108
45
108
70
117
77
82
139
107
93
162
122
180
128
127
225
107
142
237
196
196
162
65
S1*100
S1*105CC
51*110
S20115
51*125
S1*130CC
31*145
S1#150
51*160
S1#165
S1#185
S1HM90SP
S 1*200
S2* 10
S2# 20
S2* 25CC
S2* 30
52* 35
S2# 40
S2# 45
S2# 55
S2# 60
S2# 80
S2# 95CC
S2#130CC
S20145
S3# 20
S3# 25CC
S3* 30
S3* 40
S3* 45
62-75-9
62-53-3
108-95-2
111-44-4
95-57-8
541-73-1
106-46-7
100-51-6
95-50-1
95-48-7
108-60-1
106-44-5
621-64-7
67-72-1
98-95-3
75-59-1
88-75-5
105-67-9
111-91-1
120-83-2
65-85-0
120-82-1
91-20-3
106-47-8
87-68-3
59-50-7
91-57-6
77-47-4
88-06-2
95-95-4
91-58-7
88-74-4
-------
No
48
49
50
No
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
8
9
'0
'1
2
3
4
5
6
7
8
9
0
1
2
3
4
5
i,
7
3
?
3
I
I
S
V
i
>
'
1
i
i
Name
C535 OIMETHYLPHTHALATE
C540 ACENAPHTHYLENE
C543 2,6-DINITROTOLUENE
m/z
152
136
164
188
240
264
82
172
244
99
112
330
132
152
NOT
74
93
94
93
128
146
146
108
146
108
45
108
70
117
77
82
139
107
93
162
122
180
128
127
225
107
142
237
196
196
162
65
163
152
165
Scan
340
531
829
1087
1553
1784
423
724
1384
310
197
970
313
360
FOUND
104
302
311
316
315
332
343
370
362
392
390
418
411
408
426
468
475
499
512
518
546
525
534
554
561
651
652
681
709
715
734
764
807
803
813
Time
3:47
5:54
9:13
12:05
17:16
19:51
4:42
8:03
15:24
3:27
2:11
10:47
3:29
4:00
1:09
3:22
3:28
3:31
3:30
3:42
3:49
4:07
4:02
4:22
4:20
4:39
4:34
4:32
4:44
5:12
5:17
5:33
5:42
5:46
6:04
5:50
5:56
6:10
6:14
7:14
7:15
7:34
7:53
7:57
8:10
8:30
8:59
8:56
9:03
Ref
1
2
3
4
5
6
2
3
5
1
1
3
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
2
2
2
2
2
2
2
2
2
2
2
2
2
3
3
3
3
3
3
3
3
RRT
1.000
.000
.000
.000
.000
.000
0.797
0.873
0.891
0.912
0.579
1.170
0.921
1.059
0.306
0.888
0.915
0.929
0.926
0.976
1.009
1.088
1.065
1.153
1.147
1.229
1.209
1.200
0.802
0.881
0.895
0.940
0.964
0.976
1.028
0.989
1.006
1.043
1.056
1.226
1.228
0.821
0.855
0.862
0.885
0.922
0.973
0.969
0.981
163 S3# 55
152 S3* 65
165 S3* 70
Meth
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
BB
BB
BB
BV
BB
BB
BB
BB
BB
BB
BB
BB
BB
BB
BB
BV
VB
VB
BB
BV
VB
BB
BB
BB
BB
BB
BV
BB
VB
BB
VB
BB v
BB^
BB °*
qedt©
A
A
A
A
A
A
A
A
A
A
A
A
A
A
BB i
BB ^
BB
BB
BB
BV
BB
BV
VB
BB
BB
BB
BB
BB
131-11-3
208-96-8
606-20-2
Area(Hght) Amount
23319.
79260.
43605.
76218.
51424.
44306.
77010.
113630.
107689.
88631.
56775.
22822.
66336.
42899.
45851 .
78198.
90423.
67521 .
72156.
74894.
75730.
35440.
70366.
51172.
114359.
52957.
40110.
32844.
74224.
118401.
34790.
59805.
81550.
48941.
24441 .
55810.
173260.
74460.
28856.
53671 .
154259.
34014.
34776.
36021 .
111646.
43674.
123549.
174241 .
30775.
40.000
40.000
40.000
40.000
40.000
40.000
82.769
84.449
84.168
75.060
71.178
88.836
76.805
79.981
77.168
72.648
78.820
84.679
82.688
81.001
80.312
71.152
80.476
74.726
77.250
71.200
75.951
79.548
84.170
80.599
82.243
91.475
80.594
80.305
44.726
85 . 1 1 1
85.538
82.809
86.622
80.198
103.624
84.003
79.050
80.179
85.891
79.829
84.524
86.940
87.184
UG/ML
UG/ML
UG/ML
UG/HL
UG/HL
UG/ML
UG/HL
UG/HL
UG/HL
UG/ML
UG/Ml
UG/HL
UG/HL
UG/HL
UG/ML
UG/HL
UG/ML
UG/ML
UG/HL
UG/ML
UG/ML
UG/ML
UG/HL
UG/HL
UG/ML
UG/ML
UG/ML
UG/ML
UG/HL
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/HL
UG/HL
UG/HL
UG/HL
UG/HL
UG/HL
XTot
0.61
0.61
0.61
0.61
0.61
0.61
1.27
1.30
1.29
1.15
1.09
1.36
1.18
1.23
1.18
1.11
1.21
1.30
1.27
1.24
1.23
.09
.24
.15
.19
.09
.17
1.22
1.29
1.24
1.26
1.40
1.24
1.23
0.69
1.31
1.31
1.27
1.33
1.23
1.59
1.29
1.21
1.23
1.32
1.23
1.30
1.33
1.34
1GS4
-------
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-------
uantitation Report File: ST16980902
ata: ST16980902.TI
9/02/98 14:53:00
ample: SST0080 80UG/ML CALI III 082198A
onds.: INST. 10: F16
ormula: 1UL INJ. Instrument: F16
ubmitted by: QES Analyst: DAT
MOUNT=AREA * REF AMNT/(REF AREA * RESP FACT)
esp. fac. from average of whole .RL
Weight: 0.000
Acct. No.: FIN
No
51
52
53
54
55
>6
57
58
i9
>0
>1
>2
,3
A
.5
6
7
a
9
0
1
2
3
4
5
6
7
8
9
0
1
2
3
i>
5
D
1
>
5
*
i
>
'
1
Name
C545 3-NITROANILINE 138 S3# 75
C550 ACENAPHTHENE 153 S3# 80CC
C555 2,4-OINITROPHENOL 184 S3# 85SP
C565 DIBENZOFURAN 168 S3# 90
C560 4-NITROPHENOL 109 S3# 95SP
C570 2,4-DINITROTOLUENE 165 S30105
C580 DIETHYLPHTHALATE 149 S3#130
C590 FLUORENE 166 S3#135
C585 4-CHLOROPHENYL-PHENYLE 204 S3#140
C595 4-NITROANALINE 138 S3#150
C610 4.6-DIN1TRO-2-METHYLPH 198 S4# 10
C615 N-NITROSODIPHENYLAMINE 169 S4# 15CC
C620 AZOBENZENE 77 S4# 20
C625 4-BROMOPHENYL-PHENYLET 248 S4# 30
C630 HEXACHLOROBENZENE 284 S4# 40
C635 PENTACHLOROPHENOL 266 S4# 50
C640 PHENANTHRENE 178 S4# 65
C645 ANTHRACENE 178 S4# 70
C647 CARBAZOLE 167 S4# 80
C650 DI-N-BUTYLPHTHALATE 149 S4# 85
C655 FLUORANTHENE 202 S4HM10CC
C710 BENZ1DINE 184 S5# 10
C715 PYRENE 202 S5# 15
C720 BUTYLBENZYLPHTHALATE 149 S5# 40
C730 BENZO(A)ANTHRACENE 228 S5# 50
C725 3,3'-DICHLOROBENZIDINE 252 S5# 55
C740 CHRYSENE 228 S5# 60
C745 BIS(2-ETHYLHEXYL)PHTHA 149 S5# 65
C760 DI-N-OCTYL PHTHALATE 149 S6# 10CC
C765 BENZO(B)FLUORANTHENE 252 S6# 15
C770 BENZOOOFLUORANTHENE 252 S6# 25
C775 BENZO(A)PYRENE 252 S6# 35
C780 INDENO(1,2.3-CD)PYRENE 276 S6# 55
C785 DIBENZ(A,H)ANTHRACENE 278 S6# 60
C790 BENZO(G,H,I)PERYLENE 276 S6# 65
tn/z Scan Time Ref RRT Meth Area(Hght)
138 838 9:19 3 1.011 A BB 33994.
153 835 9:17 3 1.007 A BV 108934.
184 858 9:33 3 1.035 A BB 14215.
168 867 9:39 3 1.046 A VB 156137.
109 892 9:55 3 1.076 A BB 11396.
165 881 9:48 3 1.063 A BB 40446.
149 935 10:24 3 1.128 A BB 128756.
166 926 10:18 3 1.117 A BB 125506.
99-09-2
83-32-9
51-28-5
132-64-9
100-02-7
121-14-2
84-66-2
86-73-7
7005-72-3
100-01-6
534-52-1
87-30-6
103-33-3
101-55-3
118-74-1
87-86-5
85-01-8
120-12-7
86-74-8
84-74-2
206-44-0
92-81-5
129-00-0
85-68-7
56-55-3
91-94-1
218-01-9
117-81-7
117-84-0
205-99-2
207-08-9
50-32-8
193-39-5
53-70-3
191-24-2
Amount
81.477 UG/ML
86.246 UG/ML
68.887 UG/ML
85.811 UG/ML
60.551 UG/ML
93.400 UG/ML
86.290 UG/ML
88.713 UG/ML
XTot
1.25
1.32
1.06
1.32
0.93
1.43
1.32
1.36
-------
NO
59
60
61
62
63
64
65
66
67
68
69
70
71
72
73
74
75
76
77
78
79
80
81
82
83
84
85
No
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
69
70
71
72
73
74
75
76
77
m/z Scan
204 938
138 947
198 951
169 963
77 965
248 1021
284 1020
266 1063
178 1092
178 1101
167 1139
149 1227
202 1299
184 1346
202 1335
149 1488
228 1552
252 1563
228 1558
149 1604
149 1715
252 1729
252 1734
252 1776
276 1932
278 1938
276 1963
Time Ref
10
10
:26
:32
10:35
10
10
11
11
11
12
12
12
13
14
14
14
16
17
17
17
17
19
19
19
19
21
21
21
Ret(L) Ratio
9:19 1.
9:17 1.
9:33 1.
00
00
00
9:39 1.00
9:55 1.
9:48 1.
10:24 1.
10:18 1.
10:26 1.
10:32 1.
10:35 1.
10:43 1.
10:44 1.
11:21 1.
11:21 1.
11:49 1.
12:09 1.
12:15 1.
12:40 1.
13:39 1.
14:27 1.
14:58 .
14:51
16:33 .
17:16 .
17:23
17:20 1.
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
:43
:44
:21
:21
:49
:09
:15
:40
:39
:27
:58
:51
:33
:16
:23
:20
:50
:05
:14
:17
:45
:29
:33
:50
3
3
4
4
4
4
4
4
4
4
4
4
4
5
5
5
5
5
5
5
6
6
6
6
6
6
6
RRT
1.131
1.142
0.875
0.886
0.888
0.939
0.938
0.978
1.005
1.013
1.048
1.129
1.195
0.867
0.860
0.958
0.999
1.006
1.003
1.033
0.961
0.969
0.972
0.996
1.083
1.086
1.100
RRT(L) Ratio
1.011
1.007
1.035
1.046
1.076
1.063
1.128
1.117
1.131
1.142
0.875
0.886
0.888
0.939
0.938
0.978
1.005
1.013
1.048
1.129
1.195
0.867
0.860
0.958
0.999
1.006
1.003
1
1
.00
.00
1.00
1
1
1
1
1
1
1
1
1
1
1
1
1
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
1.00
1
1
1
1
1
1
1
1
1
1
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
Meth
A BB
A 88
A BB
A BV
A BB
A BB
A BB
A BB
A BV
A VB
A BB
A BB
A BB
A BB
A BB
A BV
A BV
A BB
A VB
A BV
A BV
A BV
A VB
A BB
A BV
A BB
A BB
Amnt
81.48
86.25
68.89
85.81
60.55
93.40
86.29
88.71
88.58
78.27
81.99
79.07
80.36
87.72
87.46
75.92
84.49
85.23
84.72
86.29
84.05
11.98
82.89
82.18
87.04
76.69
82.83
Area(Hght)
59164.
26197.
20624.
82971 .
179267.
37178.
43240.
22429.
166229.
160282.
123311.
204955 .
144144.
1996.
140939.
72332.
125866.
40227.
108028.
101978.
171003.
123130.
111530.
107418.
113827.
114484.
119594.
Amnt(L)
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
Amount
88.575
78.275
81.985
79.067
80.357
87.718
87.455
75.922
84.485
85.229
84.715
86.287
84.053
11.979
82.890
82.180
87.038
76.690
82.832
80.960
80.218
77.017
86.867
82.057
80.352
81.551
81.129
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
R.Fac R.Fac(L)
0
1
0
2
0
0
2
2
1
0
0
0
1
0
0
0
1
1
1
2
1
0
2
1
1
0
1
.624
.999
.261
.865
.209
.742
.362
.303
.085
.481
.216
.871
.882
.390
.454
.235
.745
.682
.294
.151
.513
.031
.193
.125
.958
.626
.681
0.383
1.159
0.189
1.669
0.173
0.397
1.369
1.298
0.613
0.307
0.132
0.551
1.171
0.222
0.259
0.155
1.033
0.987
0.764
1.247
0.900
0.130
1.323
0.685
1.125
0.408
1.014
XTot
1.36
1.20
1.26
1.21
1.23
1.35
1.34
1.17
1.30
1.31
1.30
1.32
1.29
0.18
1.27
1.26
1.34
1.18
1.27
1.24
1.23
1.18
1.33
1.26
1.23
1.25
1.25
Ratio
1.63
1.72
1.38
1.72
1.21
1.87
1.73
1.77
1.77
1.57
1.64
1.58
1.61
1.75
1.75
1.52
1.69
1.70
1.69
1.73
1.68
0.24
1.66
1.64
1.74
1.53
1.66
-------
No Ret(L) Ratio RRT(L) Ratio
Amnt Amnt(L) R.Fac R.Fac(L) Ratio
78
79
80
81
82
83
84
85
17:50
19:05
19:14
19:17
19:45
21:29
21:33
21:50
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.033
0.961
0.969
0.972
0.996
1.083
1.086
1.100
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
80.
80.
77.
86.
82.
80.
81.
81.
96
22
02
87
06
35
55
13
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
1
3
2
2
1
2
2
2
.586 (
.088
.223
.014
.940
.055
.067
.159
1.980
.925
.443
.159
.182
.279
.267
.331
1.62
1.60
1.54
1.74
1.64
1.61
1.63
1.62
-------
100.0-
122
RIC+MASS CHROMATOGRAM DATA: ST16980902 #1
09/02/98 14:53:00 CALI: ST16980902 #3
SAMPLE: SSTD080 80UG/ML CALI III 082198A
CONDS.: INST. ID: F16
RANGE: G 1.2158 LABEL: N 0. 2.0 QUAN: A 6, 2.0 J 0
546
SCANS 515 TO 585
BASE: U 20. 3
2244.
122.037
± 0.500
561
566 570
575
581
RIC
534
518
166912.
561
554
546
/ ^-^ / \ — stf-f gflj
1 '
520
5:47
1 '
530
5:54
540
6:00
550
6:07
1 r
560
6:14
1 — i
570
6:20
580
6:27
SCAN
TIME
h-4
C?
Co
-------
QUANTERRA GC/MS
SEMI VOLATILE APPENDIX IX CALIBRATION CHE
:ONTIN. CALIBRATION: 80 UG/ML APPENDIX ST16980902A 09/02/98 15:24:00
N1T1AL CALIBRATION: 10 UG/ML APPENDIX ST1 698083 1B 08/31/98 13:35:00
NITIAL CALIBRATION: 20 UG/ML APPENDIX ST 1698083 1C 08/31/98 14:02:00
NITIAL CALIBRATION: 50 UG/ML APPENDIX ST16980831D 08/31/98 U:32:00
NITIAL CALIBRATION: 80 UG/ML APPENDIX ST 16980831 A 08/31/98 13:07:00
NITIAL CALIBRATION: 120 UG/ML APPENDIX ST16980831E 08/31/98 15:02:00
NITIAL CALIBRATION: 160 UG/ML APPENDIX ST16980831F 08/31/98 15:31:00
ST16980902A ST16980831B ST 1698083 1C ST16980831D ST 16980831 A ST16980831E
ST 16980831 F
ib # Cone RRF Cone RRF Cone RRF Cone RRF Cone RRF Cone RRF
11 20 80. 1.559 20. 1.583 50, 1.578 80. 1.587 120, 1.449
11 20 160. 1.576
11 30 80, 1.497 20, 1.563 50, 1.594 80, 1.577 120, 1.547
11 30 160, 1.545
,1 40 80, 0.792 20, 0.737 50, 0.823 80, 0.876 120, 0.860
1 40 160, 0.870
1 60 80, 0.561 20, 0.688 50, 0.685 80, 0.602 120. 0.619
1 60 160, 0.604
1 70 80, 0.512 20, 0.506 50, 0.521 80, 0.549 120, 0.547
1 70 160, 0.555
1 85 80, 1.091 20, 1.008 50, 1.120 80, 1.168 120. 1.190
1 85 160, 1.244
1 95 80, 0.582 20, 0.612 50, 0.605 80, 0.605 120, 0.595
1 95 160, 0.592
1 170 80, 1.856 20, 2.024 50, 1.960 80, 1.945 120, 1.903
1 170 160, 1.903
1 175 80, 0.540 20, 0.555 50, 0.575 80. 0.562 120, 0.569
1 175 160, 0.575
1 180 80, 0.773 20, 0.838 50, 0.821 80, 0.805 120. 0.817
1 180 160, 0.816
1 182 80, 2.218 20, 2.130 50, 2.339 80, 2.408 120, 2.391
1 182 160, 2.394
1 195 80, 2.043 20, 2.463 50, 2.228 80, 2.129 120, 2.032
1 195 160, 1.949
2 15 80, 0.324 20, 0.312 50, 0.326 80, 0.327 120, 0.337
2 15 160, 0.329
2 50 80, 1.060 20, 1.575 50, 1.353 80, 1.036 120, 1.276
2 50 160, 1.184
2 85 80, 0.272 20, 0.234 50, 0.264 80, 0.280 120. 0.279
2 85 160, 0.285
1 L* f *"
2 90 80, 0.203 20, 0.196 50, 0.201 80, 0.197 120, 0.198 *
Z 90 160, 0.198
-------
S2 115 80,
S2 115 160,
S2 120 80,
S2 120 160,
S2 140 80,
S2 140 160,
S3 10 80,
S3 10 160.
S3 15 80,
S3 15 160,
S3 35 80,
S3 35 160,
S3 42 80,
S3 42 160,
S3 50 80,
S3 50 160,
S3 60 80,
S3 60 160,
S3 100 80,
S3 100 160,
S3 110 80,
S3 110 160,
S3 115 80,
S3 115 160,
S3 120 80,
S3 120 160,
S3 145 80,
S3 145 160,
S4 25 80,
S4 25 160,
S4 35 80,
S4 35 160,
S4 37 80,
S4 37 160,
S4 45 80,
S4 45 160,
S4 55 80,
S4 55 160,
S4 60 80,
S4 60 160,
0.040
0.121
0.215
0.224
0.248
0.250
0.427
0.419
0.045
0.044
0.191
0.192
1.119
1.488
0.432
0.389
0.202
0.204
0.498
0.471
0.746
0.769
0.900
0.881
0.296
0.290
0.338
0.316
0.164
0.159
0.293
0.311
0.094
0.097
0.577
0.546
0.300
0.277
0.086
0.081
20, 0.163 50, 0.167 80, 0.038 120, 0.165
20, 0.205 50, 0.213 80, 0.225 120, 0.224
20, 0.246 50, 0.247 80, 0.250 120, 0.245
20, 0.431 50, 0.434 80, 0.430 120, 0.416
20, 0.046 50, 0.042 80, 0.043 120, 0.044
20, 0.201 50, 0.195 80, 0.196 120, 0.190
20, 1.098 50, 1.129 80, 1.528 120, 1.134
20, 0.403 50, 0.429 80, 0.447 120, 0.404
20, 0.191 50, 0.202 80, 0.210 120, 0.212
20, 0.504 50, 0.483 80, 0.493 120, 0.469
20, 0.859 50, 0.889 80, 0.765 120, 0.872
20, 0.974 50, 1.041 80, 0.996 120, 0.980
20, 0.277 50, 0.302 80, 0.310 120, 0.306
20, 0.345 50, 0.368 80, 0.381 120, 0.367
20, 0.149 50, 0.162 80, 0.172 120, 0.166
20, 0.305 50, 0.324 80, 0.316 120, 0.330
20, 0.088 50, 0.087 80, 0.089 120, 0.089
20, 0.643 50, 0.664 80, 0.602 120, 0.590
20, 0.312 50, 0.315 80, 0.301 120, 0.291
20, 0.081 50, 0.079 80, 0.079 120, 0.082
S4 75 80, 0.165
20, 0.130 50, 0.165 80, 0.163 120, 0.159
-------
809-0 'OZl 019'0 '08 S19'0 'OS 609'0 'OZ
SIS'O 'OZl 6VS'0 '08 9/S'O 'OS 98S'0 '02
6ZVO 'OZl 8£rO '08 OSrO 'OS WO 'OZ
9SO'0 'OZl 680'0 '08 /80'0 'OS £Zl'0 'OZ
V9£'0 'OZL 90^-0 '08 OSVO 'OS ZZS'O '
ziro 'ozi ozro '09 sz^-o 'os /ivo 'oz
Z80-0 'OZI 060'0 '08 060'0 'OS ISO'O 'OZ
'O 'OZt 190'0 '08 £90'0 'OS /SO'O 'OZ
S6Z'0 'OZI 80£'0 '08 6Z£'0 'OS IS£'0 'OZ
i'o 'ozi szro 'oe 6Zfo 'os szro 'oz
'O 'OZI SOZ'O '08 6££'0 'OS WO 'OZ
6/0'0 'OZI 9/0'0 '08 WO'O 'OS SSO'O 'OZ
609'0 '091 OZ 9
66S'0 '08 OZ 9
nS-0 '091 58 S
VSS'O '08 58 5
O^VO '091 SV S
S£VO '08 SV S
VSO'O '09L /£ S
£01'0 '08 Z£ S
9V£'0 '09L S£ Si
ZS£'0 '08 S£ Si
OZVO '091 0£ S'.
OOVO '08 0£ S!
SSO'O '091 SZ SS
SSO'O '08 SZ SS
L90'0 '091 OZ SS
V90'0 '08 OZ SS
LSZ'O '091 OZl VS
9/£'0 '01 IZ£'0 '08 OZl VS
VZl'O '091 901 W
6Zl'0 '08 901 «
/2Z'0 '091 SOI IS
/£Z-0 '08 SOI IS
S/0'0 '091 001 «
WO '08 001 VS
osro '091 s/ w
-------
DATA FROM FILE: ST16980902A SCANS 230 TO 1200 ACQUIRED: 09/02/98 15:24:00
CALI: ST16980902A #3
SAMPLE: 80UG/ML AP9 862598F
CONDS.: INST. ID: F16
600 _
6:40
800 .
8:54
1000 -
11:07
j
100.92 < 210688.)
DICHLOROBEHZENE-D4 152IS1* 01
NAPHTHALENE-08
CI50 ACENAPHTHENE-D10
PHENANTHRENE-D 10
136IS2* 01
164IS3* 01
188IS4* 01
3855-82-1
1146-65-2
15067-26-2
1517-22-2
C.o
-------
DATA FROM FILE: ST16980902A SCANS 1200 TO 2158 ACQUIRED: 09/02/98 15:24:00
CALI: ST16980902A #3
SAMPLE: 80UG/ML AP9 062598F
CONDS.: INST. ID: F16
1200 .
13:21
1400 _
15:34
1600 .
17:48
1800 _
20:01
2000 _
22:15
J 100.0Z < 107520.)
CI70 CHRYSENE-D12
240IS5* 01
1719-03-5
CI75 PERYLENE-D12
164IS6tt 01
1520-96-3
-------
Quantitat ion Report File: ST16980902A
Data: ST16980902A.TI
09/02/98 15:24:00
Sample: 80UG/HL AP9 062598F
Conds.: INST. ID: F16
Formula: 1UL INJ. Instrument: F16
Submitted by: OES Analyst: DAT
AHOUNT=AREA * REF AHNT/CREF AREA
Resp. fac. from average of whole
No Name
1 CI30 1.4-DICHLOROBENZENE-D4
2 CI40 NAPHTHALENE-OS
3 CI50 ACENAPHTHENE-D10
4 C160 PHENANTHRENE-D10
5 CI70 CHRYSENE-D12
6 CITS PERYLENE-012
7 PYRIDINE
8 2-PICOLINE
9 N-NITROSOMETHYLETHYLAMINE
10 METHYLMETHANESULFONATE
11 N-NITROSODIETHYLAMINE
12 ETHYLMETHANE SULFONATE
13 PENTACHLOROETHANE
14 C361 ACETOPHENONE
15 N-NITROSOPYRROLIDINE
16 N-NITROSOMORPHOLINE
17 3-METHYL PHENOL
18 0-TOLUID1NE
19 N-NITROSOPIPERIDINE
20 AA-DIMETHYLPHENETHYLAMINE
21 2,6-DICHLOROPHENOL
22 HEXACHLOROPROPENE
23 P-PHENYLENE DIAMINE
24 N-NITROSODI-N-BUTYLAMINE
25 SAFROLE
26 1,2,4,5-TETRACHLOROBENZENE
27 ISOSAFROLE <#1)
28 ISOSAFROLE (#2)
29 1-CHLORONAPHTHALENE
30 1,4-NAPHTHOQUINONE
31 1,3-DINITROBENZENE
32 PENTACHLOROBENZENE
33 1-NAPHTHYLAMINE
34 2-NAPHTHYLAMINE
35 2,3,4,6-TETRACHLOROPHENOL
36 5-NITRO-O-TOLUIDINE
37 SYM-TRINITROBENZENE
38 PHENACETIN
* RESP FACT)
.RL
152IS1* 01
136IS2# 01
164IS3* 01
188IS4* 01
240IS5* 01
164IS6* 01
79 S1# 20
93 S1# 30
42 S1# 40
80 S1# 60
102 S1# 70
79 S1# 85
117 S1# 95
105 S1#170
100 S1#175
56 S1#180
108 S1#182
106 S1#195
42 S2# 15
58 S2# 50
162 S2# 85
213 S2# 90
108 S2#115
84 S2#120
152 S2#140
214 S3# 10
162 S3# 15
104 S3# 35
162 S3# 42
158 S3# 50
168 S3# 60
250 S3#100
143 S3#110
143 S3#115
232 S3#120
152 S3#145
75 S4# 25
108 S4#35
Weight:
Acct. No.:
3855-82-1
1146-65-2
15067-26-2
1517-22-2
1719-03-5
1520-96-3
110-86-1
109-06-8
10595-95-6
55-18-5
66-27-3
76-01-7
930-55-2
59-89-2
95-53-4
100-75-4
122-09-8
87-65-0
106-50-3
924-16-3
94-59-7
95-94-3
120-58-1
120-58-1
90-13-1
130-15-4
99-65-0
708-93-5
134-32-7
91-59-8
58-90-2
99-52-5
62-44-2
39 DIALLATE 234 S4# 37
40 4-AMINOBIPHENYL
41 PRONAMIDE
42 PENTACHLORONITROBENZENE
43 2SECBUTYL-4.6-DINITROPHENOL
44 4-NITROQUINOLINE-1-OXIDE
45 METHAPYRILENE
46 ISODRIN
47 CHLOROBENZILATE
169 S4# 45
173 S4# 55
237 S4# 60
211 S4# 75
190 S4#100
58 54*105
139 S4#120
92-67-1
23950-58-5
82-68-8
88-85-7
91-80-5
0.000
-------
NO
48
49
50
No
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
!0
'1
!2
'3
'4
5
6
7
8
9
0
1
2
3
4
5
6
7
8
9
0
1
2
3
t
5
b
7
3
>
)
Name
ARAHITE (#1)
ARAMITE (#2)
P-OIMETHYLAM1NOAZOBENZENE
m/z
152
136
164
188
240
264
79
93
42
80
102
79
117
105
100
56
108
106
42
58
162
213
108
84
162
214
162
104
162
158
168
250
143
143
232
152
75
108
234
169
173
237
211
190
58
193
139
185
185
120
Scan
341
530
829
1087
1552
1783
103
146
157
183
218
255
303
404
406
412
420
409
452
706
553
549
648
620
648
682
699
738
734
770
804
858
883
899
896
941
1026
1035
1018
1069
1096
1061
1108
1237
1267
1270
1428
1400
1414
1412
Time
3:48
5:54
9:13
12:05
17:16
19:50
1:09
1:37
1:45
2:02
2:25
2:50
3:22
4:30
4:31
4:35
4:40
4:33
5:02
7:51
6:09
6:06
7:12
6:54
7:12
7:35
7:46
8:13
8:10
8:34
8:57
9:33
9:49
10:00
9:58
10:28
11:25
11:31
11:19
11:53
12:11
11:48
12:19
13:46
14:06
14:08
15:53
15:34
15:44
15:42
Ref
1
2
3
4
5
6
1
1
1
1
1
1
1
1
1
1
1
1
2
2
2
2
2
2
2
3
3
3
3
3
3
3
3
3
3
3
4
4
4
4
4
4
4
4
4
4
4
5
5
5
RRT
1.000
.000
.000
.000
.000
.000
0.302
0.428
0.460
0.537
0.639
0.748
0.889
1.185
1.191
1.208
1.232
1.199
0.853
1.332
1.043
1.036
1.223
1.170
1.223
0.823
0.843
0.890
0.885
0.929
0.970
1.035
1.065
1.084
1.081
1.135
0.944
0.952
0.937
0.983
1.008
0.976
1.019
1.138
1.166
1.168
1.314
0.902
0.911
0.910
185 S5# 20
185 S5# 25
120 S5# 30
Heth
A BV
A BB
A BB
BB
BV
BB
BB
BB
A BB
A BB
A BB
A BB
A BB
A BV
A BV
A BB
A BB C
ABV-^
A BV
qedt(l)
A BB
A BV
qedtfi)
A BB Y
A BB ^
A BB ^
A BB
A BB
A BV
A BB
A BB
A BB
A BB
A BB
A BB
A BB
A BB
A BB
A BV
BB
BB
BB
VB
BB
BB
BB
A BB
A VB
A BB
A BB
140-57-8
140-57-8
60-11-7
Area(Hght) Amount
23430.
82177.
47233.
81529.
57252.
46438.
73075.
70141.
37109.
26293.
23982.
51129.
27292.
86991.
25281 .
36244.
103957.
95752.
53309.
174290.
44702.
33370.
6560.
35296.
40806.
40306.
4260.
18010.
105725.
40775.
19068.
47076.
70446.
85044.
27957.
31963.
26738.
47788.
15382.
94094.
48872.
13992.
26967.
12009.
38678.
21038.
52292.
7298.
9760.
45827.
40
40
40
40
40
40
78
76
78
70
78
78
77
76
78
75
78
75
80
66
84
81
24
80
.000
.000
.000
.000
.000
.000
.441
.521
.106
.558
.533
.747
.437
.796
.050
.399
.816
.665
.966
.024
.515
.974
.410
.627
80.192
78
82
78
67
83
81
81
71
74
79
76
81
73
83
75
80
85
86
81
62
81
79
83
78
76
.792
.650
.310
.939
.300
.768
.449
.254
.553
.729
.138
.214
.971
.878
.804
.082
.418
.160
.269
.277
.494
.309
.488
.798
.447
UG/HL
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/HL
UG'ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
XTot
0.99
0.99
0.99
0.99
0.99
0.99
1.94
1.90
1.94
1.75
1.95
1.95
1.92
1.90
1.93
1.87
1.95
1.88
2.01
1.64
2.09
2.03
0.60
2.00
1.99
1.95
2.05
1.94
1.68
2.06
2.03
2.02
1.77
1.85
1.98
1.89
2.01
1.83
2.08
1.88
1.98
2.12
2.14
2.01
1.54
2.02
1.97
2.07
1.95
1.89
-------
No
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
Ret(L)
3:48
5:54
9:13
12:05
17:16
19:50
1:09
1:37
1:45
2:02
2:25
2:50
3:22
4:30
4:31
4:35
4:40
4:33
5:02
7:51
6:09
6:06
7:12
6:54
7:12
7:35
7:46
8:13
8:10
8:34
8:57
9:33
9:49
10:00
9:58
10:28
11:25
11:31
11:19
11:53
12:11
11:48
12:19
13:46
14:06
14:08
15:53
15:34
15:44
15:42
Ratio
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
RRT(L)
1.000
1.000
1.000
1.000
1.000
1.000
0.302
0.428
0.460
0.537
0.639
0.748
0.889
.185
.191
.208
.232
.199
0.853
1.332
1.043
1.036
1.223
1.170
1.223
0.823
0.843
0.890
0.885
0.929
0.970
1.035
1.065
1.084
1.081
1.135
0.944
0.952
0.937
0.983
1.008
0.976
1.019
1.138
1.166
1.168
1.314
0.902
0.911
0.910
Ratio
1
.00
1.00
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
1.00
1
1
1
1
1
1
1
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
.00
Amnt
40
40
.00
.00
40.00
40
40
40
78
76
78
70
78
78
77
76
78
75
78
75
80
66
84
81
24
80
80
78
82
78
67
83
81
81
71
74
.00
.00
.00
.44
.52
.11
.56
.53
.75
.44
.80
.05
.40
.82
.66
.97
.02
.51
.97
.41
.63
.19
.79
.65
.31
.94
.30
.77
.45
.25
.55
79.73
76
81
73
83
75
80
85
86
81
62
81
79
83
78
76
.14
.21
.97
.88
.80
.08
.42
.16
.27
.28
.49
.31
.49
.80
.45
Amnt(L)
40.00
40.00
40.00
40.00
40.00
40.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
R.Fac R.
1.000
1.000
1.000
1.000
1.000
1.000
2.495
2.395
1.267
0.898
0.819
1.746
0.932
2.970
0.863
1.238
3.550
3.269
0.519
1.697
0.435
0.325
0.064
0.344
0.397
0.683
0.072
0.305
1.791
0.691
0.323
0.797
1.193
1.440
0.474
0.541
0.262
0.469
0.151
0.923
0.480
0.137
0.265
0.118
0.380
0.206
0.513
0.102
0.136
0.640
Fac(L) Ratio
1.000
1.000
1.000
1.000
1.000
1.000
1.590
1.565
0.811
0.636
0.521
1.108
0.602
1.934
0.553
0.821
2.252
2.160
0.320
1.285
0.257
0.198
0.131
0.213
0.248
0.433
0.044
0.195
1.318
0.415
0.197
0.489
0.837
0.966
0.297
0.356
0.162
0.317
0.090
0.609
0.299
0.080
0.154
0.073
0.305
0.127
0.323
0.061
0.087
0.419
1.00
1.00
1.00
1.00
1.00
1.00
1.57
1.53
1.56
1.41
1.57
1.57
1.55
1.54
1.56
1.51
1.58
1.51
1.62
1.32
1.69
1.64
0.49
1.61
1.60
1.58
1.65
1.57
.36
.67
.64
.63
.43
1.49
1.59
1.52
1.62
1.48
.68
.52
.60
.71
.72
.63
1.25
1.63
1.59
1.67
1.58
1.53
-------
luantitation Report File: ST16980902A
>ata: ST16980902A.TI
i9/02/98 15:24:00
ample: 80UG/ML AP9 062598F
:onds.: INST. ID: F16
ormula: 1UL 1NJ.
ubmitted by: OES
Instrument: F16
Analyst: DAT
Weight: 0.000
Acct. No.: FIN
MOUNT=AREA * REF AMNT/CREF AREA * RESP FACT)
esp. fac. from average of whole .RL
No Name
51 3,3'-DIMETHYLBENZIDINE 212 S5# 35
52 KEPONE 272 S5# 37
53 2-ACETYLAMINOFLUORENE 181 S5# 45
54 3-METHYLCHOLANTHRENE 268 S5# 85
55 7,12-DIMETHYLBENZANTHRACENE 256 S6# 20
56 HEXACHLOROPHENE 196 S6# 30
53-96-3
56-49-5
75-97-6
70-30-4
10
51
52
53
>4
>5
>6
m/z
212
272
181
268
256
NOT
Scan
1473
1504
1518
1833
1731
FOUND
Time
16:23
16:44
16:53
20:23
19:15
Ref
5
5
5
5
6
RRT
0.949
0.969
0.978
1.181
0.971
Meth
Area(Hght) Amount
A 860^ 40357.
qedt(^
A BB jl
A BB*
A BB
11784.
K* 49800.
63472.
55616.
67.
100.
80.
80.
78.
516
447
513
915
526
UG/ML
UG/ML
UG/ML
UG/ML
UG/ML
XTot
1.67
2.49
2.00
2.01
1.95
to Ret(L) Ratio RRT(L) Ratio
.1
2
3
4
5
6
16:
16:
16:
20:
19:
21:
23
44
53
23
15
11
1
1
1
1
1
.00
.00
.00
.00
.00
0
0
0
1
0
0
.949
.969
.978
.181
.971
.992
1
1
.
.
00
00
1.00
1
1
.
w
00
00
67.
100.
80.
80.
78.
52
45
51
91
53
Amnt Amnt(L) R.Fac R.Fac(L) Ratio
50.00 0.564 0.418 1.35
50.00 0.165 0.082 2.01
50.00 0.696 0.432 1.61
50.00 0.887 0.548 1.62
50.00 0.958 0.610 1.57
iANUAL EDIT CODES
t. PEAK NOT FOUND
>. POORCHROMATOGRAPh,
3. WRONG ISOMER
UL MANUAL EDITS MUST BE
''•HALED, DATED, AND CODi-D
-------
DATA: ST16980902A #1
CALI: ST16980902A #3
100.0-1
RIC+MASS CHROMATOGRAM
09/02/98 15:24:00
SAMPLE: 80UG/ML AP9 062598F
CONDS.: INST. ID: F16
RANGE: G 1,2158 LABEL: N 0, 2.0 QUAN: A 6, 2.0 J 0 BASE: U 20
706
SCANS 480 TO 820
58
RIC
800
8:54
3948.
58.017
± 0.500
169728.
SCAN
TIME
-------
DATA: ST16980902A #1
CALI: ST16980902A #3
RIC+MASS CHROMATOGRAM
09/02/98 15:24:00
SAMPLE: 80UG/ML AP9 062598F
CONDS.: INST. ID: F16
RANGE: G 1,2158 LABEL: N 0, 2.0 QUAN: A 6, 2.0 J
25.0-
SCANS 600 TO 720
BASE: U 20, 3
682
108
RIC
1005.
108.032
± 0.500
42432.
720 SCAN
8:01 TIME
CT
cn
o
-------
DATA: ST16980902A #1
CALI: ST16980902A #3
100.0-
RIC+MASS CHROMATOGRAM DATA: ST16980902A #1 SCANS 1440 TO 1640
09/02x98 15:24:00
SAMPLE: 80UG/ML AP9 062598F
CONDS.: INST. ID: F16
RANGE: G 1,2158 LABEL: N 0,__2.0 QUAN: A 6, 2.0 J 0 BASE: U 20, 3
1483
272
RIC
168.
272.081
± 0.500
69888.
1450
16:08
1500
16:41
1550
17:14
1600
17:48
SCAN
TIME
cm
-------
Mefkol BM (w/scs)
1B52
-------
METHOD BLANK REPORT
Semi volatile Organics by GC/MS
Project: 300681
Test:
Method:
Matrix:
QC Lot:
8270-TCL-G
0010/8270
FILTER
31 JUL 98-16A
Semivolatile Organics
Analyzed: 31 AUG 98
Analyte
Phenol
bis(2-Chloroethyl)ether
2-Chlorophenol
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Benzyl alcohol
1,2-Dichlorobenzene
2-Methylphenol
2,2'-Oxybis(l-chloropropane)
3/4-Methylphenol
N-Nitroso-di-n-propylamine
Hexachloroethane
Nitrobenzene
Isophorone
2-Nitrophenol
2,4-Dimethyl phenol
Benzoic acid
bis(2-Chloroethoxy)-methane
2,4-Dichlorophenol
1,2,4-Trichlorobenzene
Naphthalene
4-Chloroaniline
Hexachlorobutadiene
4-Chloro-3-methylphenol
2-Methylnaphtha!ene
Hexachlorocyclopentadi ene
2,4,6-Tri chlorophenol
2,4,5-Trichlorophenol
2-Chloronaphthalene
2-Nitroaniline
Dimethyl phthalate
Acenaphthylene
3-Nitroaniline
Acenaphthene
2,4-Dinitrophenol
4-Nitrophenol
Dibenzofuran
2,4-Dinitrotoluene
2,6-Dinitrotoluene
Diethyl phthalate
4-Chlorophenyl phenyl ether
Fluorene
4-Nitroaniline
4,6-Dinitro-2-methylphenol
N-Nitrosodi phenylami ne
QC Run:
Time:
31 JUL 98-16A
16:02
Result
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Units
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
Reporting
Limit
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
50
10
10
10
10
10
10
10
10
10
10
50
10
10
10
10
50
10
50
50
10
10
10
10
10
10
50
50
10
Qualifier
ND = Not Detected
-------
METHOD BLANK REPORT (cont.)
Semivolatile Organics by GC/MS
Project: 300681
Test:
Method:
Matrix:
QC Lot:
8270-TCL-G
0010/8270
FILTER
31 JUL 98-16A
Semivolatile Organics
Analyzed: 31 AUG 98
Analyte
4-Bromophenyl phenyl ether
Hexachlorobenzene
Pentachlorophenol
Phenanthrene
Anthracene
Di-n-butyl phthalate
Fluoranthene
Pyrene
Butyl benzyl phthalate
3,3'-Dichlorobenzidine
Benzo(a)anthracene
bi s(2-Ethylhexyl}-phthalate
Chrysene
Di-n-octyl phthalate
Benzo b)fluoranthene
Benzo klfluoranthene
Benzo a)pyrene
Indenon,2,3-cd)pyrene
Dibenz(a,h)anthracene
Benzo(g,h,i)perylene
Acetophenone
4-Aminobiphenyl
Aniline
Benzidine
3,3'-Dimethylbenzidine
N-Nitrosodimethylamine
N-Nitrosomorpholine
Pentachloronitrobenzene (PCNB)
o-Toluidine
2-Methoxybenzenamine
Biphenyl
Chloroacetophenone
Cumene
DBCP (l,2-Dibromo-3-chloropropane)
Benzo(e)pyrene
N-N-Dietnylaniline
Dimethyl aniline
3,3'-Dimethoxybenzidine
Hydroquinone
4,4'-Methyl-bis(2-chloroaniline)
4-Nitrodiphenyl
Trifluralin
QC Run: 31 JUL 98-16A
Time: 16:02
Result
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Units
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
Reporting
Limit
10
10
50
10
10
10
10
10
10
20
10
10
10
10
10
10
10
10
10
10
10
50
10
100
20
10
10
50
20
Qualifier
ND = Not Detected
1854
-------
METHOD BLANK REPORT (cont.)
Semivolatile Organics by GC/MS
Project: 300681
Surrogate
Nitrobenzene-d5
2-Fluorobiphenyl
Terphenyl-dl4
Phenol-d5
2-Fluorophenol
2,4,6-Tribromophenol
% Recovery
86
102
106
85
82
94
Acceptable Range
45 -107
62 -110
58 -135
43 -130
36 -111
58 -131
l(j:
-------
QUANTERRA GC/MS
Target Compound Data Summary Sheet
Data File: 300681MBSX
Std Id: ST16980831
Sample: SBLKSX 31JUL98-16A 1/3SA/1ML INST. ID: F16
Client: PACIFI Date Analyzed: 08/31/98 16:02
Analyst: DAT Instrument ID: F16 Run Factor: 3.00
Quan List Threshold: 0.95 Surrogate Vol.: 1.00
Surrogate Spike Recoveries
8270-G, LIMS 10/10/96
Surrogate
Surrogate Amount (ug)
Spi ked Measured
X Recovery
Measured OC limits
CS20 NITROBENZENE-DS
CS25 2-FLUOROB1PHENY
CS30 TERPHENYL-D14
CS45 PHENOL-D5
CS50 2-FLUOROPHENOL
CS55 2,4,6-TRlBROMOP
50.00
50.00
50.00
100.0
100.0
100.0
43.20
51.20
52.90
84.60
81.80
94.50
86.4
102.
106.
84.6
81.8
94.5
45 107
62 110
58 135
43 130
36 111
58 131
Target Compounds: SAP9
Parameter Scan Result Units
HEXACHLOR08ENZENE-C13
C310 N-NITROSOOIMETHYLAMINE
PYRIDINE
2-P1COLINE
N-NITROSOMETHYLETHYLAMINE
METHYLMETHANESULFONATE
N-NITROSOOIETHYLAMINE
ETHYLMETHANE SULFONATE
PENTACHLOROETHANE
C320 ANILINE
C315 PHENOL
C325 BIS(2-CHLOROETHYL)ETHER
C330 2-CHLOROPHENOL
C335 1,3-DICHLOROBENZENE
C340 1,4-DICHLOROBENZENE
C345 BENZYL ALCOHOL
C350 1,2-DlCHLOROBENZENE
C355 2-METHYLPHENOL
C360 2,2'-OXYBlS(1-CLPROPAN)
C361 ACETOPHENONE
N-NITROSOPYRROLIDINE
N-NITROSOMORPHOLINE
3-METHYL PHENOL
C365 4-METHYLPHENOL
C370 N-NITROSO-DI-N-PROPYLAM
0-TOLUIDINE
C375 HEXACHLOROETHANE
C410 NITROBENZENE
N-N1TROSOPIPERIDINE
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
Reporting
Limit
30.0
30.0
60.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
Reviewed by:
-------
QUANTERRA GC/HS
Target Compound Data Summary Sheet
Data File: 300681MBSX
Std Id: ST16980831
Sample: SBLKSX 31JUL98-16A 1/3SA/1ML INST. ID: F16
Client: PACIF1 Date Analyzed: 08/31/98 16:02
Analyst: DAT Instrument ID: F16 Run Factor: 3.00
Quan List Threshold: 0.95
Surrogate Vol.:
1.00
Target Compounds: SAP9
Parameter Scan Result Units
C415 ISOPHORONE
C420 2-NITROPHENOL
C425 2,4-DIMETHYLPHENOL
C435 BIS(2-CHLOROETHOXY)METH
C440 2,4-DICHLOROPHENOL
C430 BENZOIC ACID
AA-DIMETHYLPHENETHYLAMINE
C445 1,2,4-TRICHLOROBENZENE
C450 NAPHTHALENE
C455 4-CHLOROANALINE
2,6-DICHLOROPHENOL
HEXACHLOROPROPENE
C460 HEXACHLOROBUTADIENE
P-PHENYLENE DIAMINE
N-NITROSODI-N-BUTYLAMINE
C465 4-CHLORO-3-METHYLPHENO
SAFROLE
C470 2-METHYLNAPHTHALENE
1,2,4,5-TETRACHLOROBENZENE
ISOSAFROLE (#1)
C510 HEXACHLOROCYCLOPENTADI
C515 2,4,6-TRICHLOROPHENOL
C520 2,4,5-TRICHLOROPHENOL
ISOSAFROLE (#2)
C525 2-CHLORONAPHTHALENE
1 -CHLORONAPHTHALENE
C530 2-N1TROANALINE
1,4-NAPHTHOQUINONE
C535 DIMETHYLPHTHALATE
1,3-OINlTROBENZENE
C540 ACENAPHTHYLENE
C543 2,6-DlNITROTOLUENE
C545 3-NITROANILINE
C550 ACENAPHTHENE
C555 2,4-DlNITROPHENOL
C565 DIBENZOFURAN
C560 4-NITROPHENOL
PENTACHLOROBENZENE
C570 2,4-DINITROTOLUENE
1-NAPHTHYLAMINE
2-NAPHTHYLAMINE
2,3,4,6- TETRACHLOROPHENOL
C580 DIETHYLPHTHALATE
C590 FLUORENE
NO
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
Reporting
Limit
30.0
30.0
30.0
30.0
30.0
150.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
60.0
30.0
30.0
30.0
60.0
30.0
15.0
150.0
30.0
30.0
30.0
30.0
30.0
150.0
30.0
150.0
30.0
150.0
30.0
30.0
30.0
30.0
60.0
30.0
30.0
-------
OUANTERRA GC/MS
Target Compound Data Summary Sheet
Data File: 300681MBSX
Std Id: ST16980831
Sample: SBLKSX 31JUL98-16A 1/3SA/1ML INST. ID: F16
Client: PACIF1 Date Analyzed: 08/31/98 16:02
Analyst: DAT Instrument ID: F16 Run Factor: 3.00
Quan List Threshold: 0.95 Surrogate Vol.: 1.00
Target Compounds: SAP9
Parameter Scan
C585 4-CHLOROPHENYL-PHENYLE
5-NITRO-O-TOLUIDINE
C595 4-NITROANALINE
C610 4,6-DINITRO-2-METHYLPH
C615 N-N1TROSODIPHENYLAMINE
C620 AZOBENZENE
SYM-TRINITROBENZENE
C625 4-BROMOPHENYL-PHENYLET
PHENACETIN
D1ALLATE 234
C630 HEXACHLOROBENZENE
4-AMINOBIPHENYL
C635 PENTACHLOROPHENOL
PRONAMIDE
PENTACHLORON 1 TROBENZENE
C6AO PHENANTHRENE
C645 ANTHRACENE
2SECBUTYL-4.6-DINITROPHENOL
C647 CARBAZOLE
C650 DI-N-BUTYLPHTHALATE
4-NITROOUINOLINE-1-OXIDE
METHAPYRILENE
1SODRIN
C655 FLUORANTHENE
CHLOROBENZILATE
C710 BENZIDINE
C715 PYRENE
ARAMITE (#1)
ARAMITE (#2)
P-DIMETHYLAMINOAZOBENZENE
3,3'-DIMETHYLBENZIDINE
KEPONE
C720 BUTYLBENZYLPHTHALATE
2-ACETYLAMINOFLUORENE
C730 BENZO(A)ANTHRACENE
C725 3,3'-DlCHLOROBENZIDINE
C740 CHRYSENE
C745 8ISC2-ETHYLHEXYDPHTHA
3-METHYLCHOLANTHRENE
C760 DI-N-OCTYL PHTHALATE
C765 BENZO(B)FLUORANTHENE
7, 12-DIMETHYLBENZANTHRACENE
C770 BENZO(K)FLUORANTHENE
HEXACHLOROPHENE
Result
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
40
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Units
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
Reporting
Limit
30.0
30.0
150.0
150.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
150.0
30.0
150.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
300.0
30.0
30.0
30.0
30.0
30.0
150.0
30.0
30.0
30.0
60.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
-------
QUANTERRA GC/MS
Target Compound Data Sunmary Sheet
Data File: 300681MBSX
Std Id: ST16980831
Sample: SBLKSX 31JUL98-16A 1/3SA/1ML 1NST. ID: F16
Client: PACIFI Date Analyzed: 08/31/98 16:02
Analyst: DAT Instrument ID: F16 Run Factor: 3.00
Quan List Threshold: 0.95 Surrogate Vol.: 1.00
Target Compounds: SAP9
Parameter
Scan
Result
Units
Report i ng
Limit
C775 BENZO(A)PYRENE
C780 INDENO(1.2,3-Ct»PYRENE
C785 DIBENZ(A,H)ANTHRACENE
C790 BENZO(G.H,I)PERYLENE
ND
ND
ND
ND
UG/A
UG/A
UG/A
UG/A
30.0
30.0
30.0
30.0
-------
DATA FROM FILE: 300681MBSX SCANS 93 TO 1203 ACQUIRED: 08/31/98 16:02:00
CALI: 300681MBSX #3
SAMPLE: SBLKSX 31JUL98-16A 1/3SA/1ML INST. ID: F16
CONDS.: UG/ML *1ML *100Z/1002 *
-------
DATA FROM FILE: 300681MBSX SCANS 1203 TO 2158 ACQUIRED: 08/31/98 16:02:00
CALI: 380681MBSX #3
SAMPLE: SBLKSX 31JUL98-16A 1/3SA/1ML INST. ID: F16
CONDS.: UG/ML *1ML *100Z/1002 */l/3SA NA M
1400 _
15:34
TC
1600
17:48
1800 -
26:61
2000 _
22:15
TC
I
J
100.07. < 97024.)
CS30 TERPHENYL-D14
244SS5* 02
1718-51-0
CI70 CHRYSEHE-D12
240IS5* 01
1719-03-5
CI75 PERYLENE-D12
164IS6* 01
1520-96-3
-------
STANDARD USED FOR THIS REPORT IS ST16980831
REPORT PRINTED: 9/01/98 8:34:49
ADDITIONAL STANDARD USED FOR THIS REPORT IS: ST16980831A
QUANTERRA-QUANTITATION SUMMARY
File: 300681MBSX
Sample: SBLKSX 3UUL98-16A 1/3SA/1ML
Analyst: DAT Instrument Id: F16
INST. ID: F16
Analyzed: 08/31/98 16:02
Compounds with amounts less than 0.20 reported as NOT FOUND
Library
No Entry Name Mass Meth
1 S1# 1 CI30 1,4-DICHLOROBENZENE 152 A BB
2 S2# 1 CI40 NAPHTHALENE-D8 136 A BB
3 S3* 1 CI50 ACENAPHTHENE-D10 164 A BB
4 S4# 1 CI60 PHENANTHRENE-D10 188 A BB
5 S5# 1 CI70 CHRYSENE-D12 240 A BB
6 S6# 1 CI75 PERYLENE-D12 264 A BB
7 S2# 2 CS20 NITROBENZENE-05 82 A BB
8 S3# 3 CS25 2-FLUOROBIPHENYL 172 A BB
9 S5# 2 CS30 TERPHENYL-D14 244 A BB
10 S1# 3 CS45 PHENOL-D5 99 A BB
11 S1# 2 CS50 2-FLUOROPHENOL 112 A BB
12 S3# 2 CS55 2,4,6-TRIBROMOPHENO 330 A BB
13 S4# 4 HEXACHLOROBENZENE-C13 294
14 S1# 15 C310 N-NITROSODIMETHYLAM 74
15 S1# 20 PYRIDINE 79
16 S1# 30 2-PICOLINE 93
17 S1# 40 N-NITROSOMETHYLETHYLAMIN 42 A W
18 S1# 60 METHYLMETHANESULFONATE 80
19 S1# 70 N-NITROSODIETHYLAMINE 102
20 S1# 85 ETHYLMETHANE SULFONATE 79
21 S1# 95 PENTACHLOROETHANE 117
22 S1#100 C320 ANILINE 93
23 S1#105 C315 PHENOL 94
24 51*110 C325 BIS(2-CHLOROETHYL)E 93
25 51*115 C330 2-CHLOROPHENOL 128
26 51*125 C335 1,3-DICHLOROBENZENE 146
27 S1#130 C340 1,4-DICHLOROBENZENE 146
28 51*145 C345 BENZYL ALCOHOL 108 A BB
29 S1#150 C350 1,2-DICHLOROBENZENE 146
30 51*160 C355 2-METHYLPHENOL 108
31 51*165 C360 2,2'-OXYBIS(1-CLPRO 45
32 51*170 C361 ACETOPHENONE 105
33 51*175 N-NITROSOPYRROLIDINE 100
34 51*180 N-NITROSOMORPHOLINE 56
35 51*182 3-METHYL PHENOL 108 A BB
36 51*185 C365 4-METHYLPHENOL 108
37 S1#190 C370 N-NITROSO-DI -N-PROP 70
38 S1#195 0-TOLUIDINE 106
39 51*200 C375 HEXACHLOROETHANE 117
40 S2* 10 C410 NITROBENZENE 77
41 52* 15 N-NITROSOPIPERIDINE 42
42 S2* 20 C415 ISOPHORONE 82
43 S2* 25 C420 2-NITROPHENOL 139
44 S2# 30 C425 2,4-DIHETHYLPHENOL 107
45 S2* 35 C435 BISC2-CHLOROETHOXY) 93
Units: UG/K
Scan Ref Area RRF(L)
342 1 36292. 1.000
530 2 131128. 1.000
828 3 72270. 1.000
1086 4 123798. 1.000
1551 5 64001. 1.000
1782 6 47432. 1.000
422 2 66532. 0.470
723 3 114183. 1.234
1383 5 84273. 0.995
309 1 155502. 2.025
201 1 101569. 1.368
968 3 40241. 0.236
4 NOT FOUND
1 NOT FOUND
1 NOT FOUND
1 NOT FOUND
162 1 2058. 0.811
1 NOT FOUND
1 NOT FOUND
1 NOT FOUND
1 NOT FOUND
1 NOT FOUND
1 NOT FOUND
1 NOT FOUND
1 NOT FOUND
1 NOT FOUND
1 NOT FOUND
372 1 2165. 0.854
1 NOT FOUND
1 NOT FOUND
1 NOT FOUND
1 NOT FOUND
1 NOT FOUND
1 NOT FOUND
421 1 1034. 2.252
1 NOT FOUND
1 NOT FOUND
1 NOT FOUND
1 NOT FOUND
2 NOT FOUND
2 NOT FOUND
2 NOT FOUND
2 NOT FOUND
2 NOT FOUND
2 NOT FOUND
Amount
40.000
40.000
40.000
40.000
40.000
40.000
43.222
51.202
52.923
84.617
81.818
94.513
2.796
2.793
0.506
it;;
-------
46 S2# 40 C440 2,4-OICHLOROPHENOL 162 2 NOT FOUND
47 S2# 45 C430 BENZOIC ACID 122 2 NOT FOUND
48 S2# 50 AA-DIMETHYLPHENETHYLAMIN 58 2 NOT FOUND
49 S2# 55 C445 1,2,4-TRICHLOROBENZ 180 2 NOT FOUND
.b'G
-------
0 S2# 60 C450 NAPHTHALENE
1 S2# 80 C455 4-CHLOROANALINE
2 S2# 85 2,6-DICHLOROPHENOL
3 S2# 90 HEXACHLOROPROPENE
4 S2# 95 C460 HEXACHLOROBUTADIENE
5 S2#115 P-PHENYLENE OIAMINE
6 S2#120 N-NITROSODI-N-BUTYLAMINE
7 S2#130 C465 4-CHLORO-3-METHYLPH
8 S2#140 SAFROLE
9 S2#145 C470 2-METHYLNAPHTHALENE
0 S3# 10 1,2,4,5-TETRACHLOROBENZE
1 S3# 15 ISOSAFROLE (#1)
2 S3# 20 C510 HEXACHLOROCYCLOPENT
3 S3# 25 C515 2,4,6-TRICHLOROPHEN
4 S3* 30 C520 2,4,5-TRICHLOROPHEN
5 S3# 35 ISOSAFROLE (#2)
6 S3# 40 C525 2-CHLORONAPHTHALENE
7 S3# 42 1-CHLORONAPHTHALEN
8 S3# 45 C530 2-NITROANALINE
9 S3# 50 1,4-NAPHTHOQUINONE
0 S3# 55 C535 DIMETHYLPHTHALATE
1 S3# 60 1,3-DlNITROBENZENE
2 S3* 65 C540 ACENAPHTHYLENE
3 S3# 70 C543 2,6-DINJTROTOLUENE
4 S3# 75 C545 3-NITROANILINE
5 S3# 80 C550 ACENAPHTHENE
6 S3# 85 C555 2,4-DINITROPHENOL
7 S3# 90 C565 DIBENZOFURAN
S S3# 95 C560 4-NITROPHENOL
9 S30100 PENTACHLOROBENZENE
0 S3#105 C570 2,4-DINITROTOLUENE
1 53*110 1-NAPHTHYLAMIME
2 S3#115 2-NAPHTHYLAMINE
3 S3#120 2,3,4,6-TETRACHLOROPHENO
U S3#130 C580 DIETHYLPHTHALATE
5 S3#135 C590 FLUORENE
6 S30140 C585 4-CHLOROPHENYL-PHEN
7 S3#145 5-NITRO-0-TOLU1DINE
B S3#150 C595 4-NITROANAL1NE
9 S4# 10 C610 4.6-DINITRO-2-HETHY
0 S4# 15 C615 N-NITROSODIPHENYLAM
1 S4# 20 C620 AZOBENZENE
2 S4# 25 SYM-TRINITROBENZENE
3 S4# 30 C625 4-BROMOPHENYL-PHENY
U S4# 35 PHENACETIN
5 S4# 37 DIALLATE
6 S4# 40 C630 HEXACHLOROBENZENE
7 S4# 45 4-AMINOB1PHENYL
8 S4# 50 C635 PENTACHLOROPHENOL
9 S4# 55 PRONAHIDE
0 S4# 60 PENTACHLORONITROBENZENE
1 S4# 65 C640 PHENANTHRENE
2 S4# 70 C645 ANTHRACENE
J S4# 75 2SECBUTYL-4.6-DINITROPHE
!. S4# 80 C647 CARBAZOLE
j S4# 85 C650 Dl-N-BUTYLPHTHALATE
S S4#100 4-NITROQUINOLINE-1-OXIDE
' S4#105 HETHAPYRILENE
J S4#106 ISODRIN
? S4#110 C655 FLUORANTHENE
3 S4#120 CHLOROBENZILATE
128
127
162
213
225
108
84
107
162
142
214
162
237
196
196
104
162
162
65
158
163
168
152
165
138
153
184
168
109
250
165
143
143
232
149
166
204
152
138
198 .
169 A BV
77
75
248
108
234
284
169
266
173
237
178
178
211
167
149 A BB
190
58 A BB
193
202
139 A BB
2 NOT FOUND
2 NOT FOUND
2 NOT FOUND
2 NOT FOUND
2 NOT FOUND
2 NOT FOUND
2 NOT FOUND
2 NOT FOUND
2 NOT FOUND
2 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 MOT FOUND
3 NOT FOUND
3 NOT FOUND
4 NOT FOUND
961 4 792. 0.551
4 NOT FOUND
4 NOT FOUND
4 NOT FOUND
4 NOT FOUND
4 NOT FOUND
4 NOT FOUND
4 NOT FOUND
4 NOT FOUND
4 NOT FOUND
4 NOT FOUND
4 NOT FOUND
4 NOT FOUND
4 NOT FOUND
4 NOT FOUND
1226 4 1220. 1.247
4 NOT FOUND
1264 4 1726. 0.305
4 NOT FOUND
4 NOT FOUND
1426 4 356. 0.313
0.465
0.316
1.830
0.368
-------
Ill S5# 10 C710 BENZIDINE 184 5 NOT FOUND
112 S5# 15 C715 PYRENE 202 5 NOT FOUND
113 S5# 20 ARAMITE (#1) 185 5 NOT FOUND
114 S5# 25 ARAMITE (#2) 185 5 NOT FOUND
115 S5# 30 P-DIMETHYLAMINOAZOBENZEN 120 A BB 1412 5 590. 0.419 0.880
116 S5# 35 3,3'-DIMETHYLBENZIDINE 212 5 NOT FOUND
117 S5*f 37 KEPONE 272 5 NOT FOUND
118 S5# 40 C720 BUTYLBENZYLPHTHALAT 149 5 NOT FOUND
119 S5# 45 2-ACETYLAMINOFLUORENE 181 A BB 1518 5 960. 0.432 1.388
120 S5# 50 C730 BENZO(A)ANTHRACENE 228 5 NOT FOUND
121 S5# 55 C725 3.3'-DICHLOROBENZID 252 A BB 1563 5 636. 0.408 0.974
122 S5# 60 C740 CHRYSENE 228 5 NOT FOUND
123 S5# 65 C745 BIS(2-ETHYLHEXYUPH 149 A BB 1603 5 350. 0.980 0.223
124 S5# 85 3-METHYLCHOLANTHRENE 268 A BB 1831 5 1012. 0.548 1.154
125 S6# 10 C760 DI-N-OCTYL PHTHALAT 149 6 NOT FOUND
126 S6# 15 C765 BENZO(B)FLUORANTHEN 252 6 NOT FOUND
127 S6# 20 7,12-DIMETHYLBENZANTHRAC 256 A BB 1730 6 688. 0.610 0.951
128 S6# 25 C770 BENZOdOFLUORANTHEN 252 6 NOT FOUND
129 S6# 30 HEXACHLOROPHENE 196 6 NOT FOUND
130 S6# 35 C775 BENZO(A)PYRENE 252 6 NOT FOUND
131 S6# 55 C780 INDENO(1,2,3-CD)PYR 276 6 NOT FOUND
132 S6# 60 C785 D1BENZ(A,H)ANTHRACE 278 6 NOT FOUND
133 S6# 65 C790 BENZO(G,H, DPERYLEN 276 6 NOT FOUND
10'
-------
333T
30 apisjno si 'S'l ue saieoipui -
Zia-3N3"Ua3d 5213 = 9 #51
Zia-3N3SJiaH3 0^13 = S #SI
Old-3N3aHlNVN3Hd 0913 = V #SI
I II II I
Z8-6l|£6 = 'Z£W I SZ'/llZOl =-100*79 | 80'ZllsZl ='8&i£ZL | XS9W18900£
I
I ££-6l|OS +='S/£SZ I 9/'9l|05 +='Sni£ I 8S'U|OS +
I £E'OZJOOZ+='OOSIOI I 92Vl|OOZ+='8/SVZL | 8S'ZIJOOZ+='6£0/61
£8'6l| "05/05
ia | X eajy
9 #SI
9ZVl| '68ZZ9 | 80'Zl| 'OZS86 I IE80869US
ig | % eajy | ia | X B8JV | pjepueas
S #SI j V #SI |
30 apisino si *S'I ue
OLO-3N3HlHdVN33V 0513 = i #SI
80-3N31VHiHdVN 0*713 = Z #SI
«7(]-3N3ZN3aoacnH3ia-y I 0£I3 = I #SI
II
\ 06'S |0£l
II
08'£
='Z6Z9£ I XS8WL8900E I
I
I
I
I
I U'8 |OS +='WIZZ I OVS lOS +='9l.ZOS I 8Z'£ |OS +
I U'6 |OOZ+=-S6980l I 0«7'9 IOOZ+='V9800Z I 8Z^ |OOZ+='Z6Z2S I J'»"n J3ddn
I 06'S I -Z£MOl | 8/'£ | '6W8Z | l£80869US
| £ #SI
ia | x BOJV
2 #SI
ia | X eajV | pjepueis
I #SI |
L£JZl 86/IE/80 i
=3iva
pjepuejs
= ISAIVNV
l£80869US :
vaaaiNvno
ssiavaan s '
-------
Data Reduced by:
Data Reviewed by:
Data File: 300681MBSX
QUANTERRA GC/MS TIC REPORT ( Part 1 )
Sample: SBLKSX 3UUL98-16A 1/3SA/1ML INST. ID: F16
Analyst: DAT Date Analyzed: 08/31/98 16:02
Run Factor: 3.00
Concentration
in Sample
# SCAN (UG/A) CAS #
1 288 29. 100-52-7
BENZALDEHYDE Cjv \
2 932
3 1338 19.
T*-HKUHANUL, \-U-(OO
5 1509 27. 00-00-0
UNKNOWN
6 1533
UNKNOWN
33.
00-00-0
7 1661 33.
UNKNOWN
00-00-0
8 1690
UNKNOWN
21.
00-00-0
9 1803
UNKNOWN
51.
00-00-0
10 1933
UNKNOWN
39.
00-00-0
-------
1 2052 15. 00-00-0
UNKNOWN
i2 2057 21. 00-00-0
UNKNOWN
ices
-------
DATA FILE: 300681MBSX
OUANTERRA GC/MS TIC REPORT ( Part 2 )
CONCENTRATION = AREA(T1C)*CONC(IS)/AREA(IS)
#
1
2
3
4
5
6
7
8
9
10
11
12
FIT
967
928
848
871
808
812
839
771
651
844
722
748
PURITY
920
789
680
757
625
599
463
524
406
425
310
422
INT.
STD.
1
2
4
4
4
4
4
5
5
5
5
5
RT
3:12
10:21
14:52
15:07
16:47
17:03
18:28
18:47
20:03
21:30
22:49
22:52
RRT
0.543
1.126
0.863
0.877
0.973
0.988
1.071
0.948
1.012
1.085
1.152
1.154
AREA
63822.
58873.
32240.
45936.
44204.
55272.
54732.
27952.
65928.
51292.
20187.
26821.
AS
HEIGHT
16736.
17802.
3764.
3636.
6352.
4496.
5216.
2224.
5408.
4584.
3052.
3087.
AMOUNT
ANALYZED
(UG/ML )
9.
7.
6.
9.
8.
11.
10.
7.
16.
13.
5.
6.
581
266
454
195
849
064
956
142
845
105
158
853
LIB
NB
NB
NB
NB
UK
UK
UK
UK
UK
UK
UK
UK
LIB #
2017.
40501 .
24247.
9228.
1.
1.
1.
1.
1.
1.
1.
1.
166S
-------
Library Search Data: 300681MBSX # 288 Base m/z: 77
08/31/98 16:02:00 + 3:12 Cali: 300681MBSX # 3 RIC: 14800.
Sample: SBLKSX 31JUL98-16A 1/3SA/1HL 1NST. ID: F16
Conds.: UG/ML *1ML »100V100% «(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
62231 spectra in L1BRARYNB searched for maximum PURITY
366 matched at least 5 of the 16 largest peaks in the unknown
Rank In. Name
1 2017 BENZALDEHYDE
2 7284 BENZOYL CHLORIDE
3 6466 ETHANONE, 2-HYDROXY-1-PHENYL-
'* 2014 2,4-HEPTAOlEN-6-YNAL, -
"> 9645 BENZOYL FORM 1C ACID
S 10676 ETHANONE, 2-CHLORO-1-PHENYL-
' 13112 BENZOYL ISOTHIOCYANATE
5 13709 N-METHOXY-N-METHYLBENZAMIDE
> 6857 BENZENECARBOTHIOIC ACID
lank Formula M.Wt B.Pk Purity Fit RFit
C7.H6.0 106 77 920 967 940
C7.H5.0.CL 140 105 817 875 830
C8.H8.02 136 105 804 845 821
C7.H6.0 106 105 802 844 808
C8.H6.03 150 105 779 850 804
C8.H7.0.CL 154 105 773 841 798
C8.H5.0.N.S 163 105 772 823 789
C9.H11.02.N 165 105 763 812 793
C7.H6.0.S 138 77 762 847 808
ank Ret.Time B.P.Int. US.Par.1 US.Par.2 C.A.S. it
100-52-7
98-88-4
582-24-1
7200-04-6
611-73-4
532-27-4
532-55-8
6919-61-5
98-91-9
lb'7
u
-------
MID LIBRARY SEARCH /-l/3SA NA M
ENHANCED
1482
SAMPLE
r
I
, . -, .Ill 1
1
ll. ... . 1.
i_ *Y
^[(toVd
1
6
-------
Library Search Data: 300681MBSX # 932
08/31/98 16:02:00 + 10:22 Cali: 300681MBSX # 3
Sample: SBLKSX 31JUL98-16A 1/3SA/1ML INST.
Conds.: UG/ML *1ML *100%/100% *(NA/NA )/1/3SA NA H
Enhanced (S 15B 2N OT)
Base m/z: 71
RIC: 16896.
ID: F16
62231 spectra in LIBRARYNB searched for maximum PURITY
691 matched at least 6 of the 16 largest peaks in the unknown
Rank In. Name
1 40501 PROPANOIC ACID, 2-METHYL-, 1-<1,1-DIMETHYLETHYL)-2-METHYL-1,3-PROPA*
2 40500 PROPANOIC ACID, 2-METHYL-, 2-ETHYL-1-PROPYL-1.3-PROPANEDIYL ESTER
3 26739 PROPANOIC ACID, 2-METHYL-, 2,2-DIMETHYL-1-(2-HYDROXY-1-METHYLETHYU*
4 4625 1-HEXENE, 3.4.5-TRIMETHYL-
5 4556 ETHANONE, 1-(3-ETHYLCYCLOBUTYL)-
6 2720 4,4-DIMETHYL-1-HEXENE
7 4677 2,4,4-TRIMETHYL-1-HEXENE
8 14787 1-NONENE, 4,6,8-TRIMETHYL-
9 15779 1,2-CYCLOHEXANEDIOL, 1-METHYt-4-(1-METHYLETHYL)-
Rank
1
2
3
4
5
6
7
8
9
Formula
C16.H30.04
C16.H30.04
C12.H24.03
C9.H18
C8.H14.0
C8.H16
C9.H18
C12.H24
C10.H20.02
M.Wt
286
286
216
126
126
112
126
168
172
B.Pk
71
43
71
43
43
71
71
43
71
Purity
789
727
704
589
586
579
546
531
518
Fit
928
882
883
807
752
794
720
715
701
RFit
811
737
723
665
623
630
644
557
641
Rank
1
2
3
i.
5
6
7
8
9
Ret.Time
B.P.Int.
US.Par.1
US.Par.2
C.A.S.
74381-
74367-
74367-
56728-
56335-
1647-
51174-
54410-
33669-
#
40-1
30-9
33-2
10-0
71-8
08-1
12-0
98-9
76-0
-------
MID LIBRARY SEARCH
08x31/98 16:02:00 + 10:22
SAMPLE: SBLKSX 31JUL98-16A 1/3SA/1ML
CONDS.: UG/ML *1ML *100Z/100Z *
DATA:
CALI:
INST. ID:
NA M
300681MBSX # 932
300681MBSX # 3
F16
BASE M/Z: 71
RIC: 16896.
1171
SAMPLE
C16.H30.04
1171
286
71
RANK 1
* 40501
PUR 789
PROPANO1C ACID, 2-METHYL-, 1-<1,1-DIMETHYLETHYL)-2-METHYL-1,3-PROPANE!
M UT
B PK
C16.H30.04
1171
UT 286
PK 43
RANK 2
tt 40500
PUR 727
PROPANOIC ACID, 2-METHYL-, 2-ETHYL-1-PROPYL-1,3-PROPANEDIYL ESTER
C12.H24.03
1171
M WT 216
B PK 71
RANK 3
tt 26739
PUR 704
M/Z
PROPANOIC ACID, 2-METHYL-, 2,2-DIMETHYL-l-<2-HYDROXY-l-METHYLETHYL)PR!
50
100
150
200
cr
-------
Library Search Data: 300681MBSX #1338
08/31/98 16:02:00 + 14:53 Cali: 300681MBSX # 3
Sample: SBLKSX 31JUL98-16A 1/3SA/1ML INST.
Conds.: UG/ML *1ML *100%/100X *(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
Base m/z: 59
RIC: 2672.
ID: F16
62231 spectra in LIBRARYNB searched for maximum PURITY
842 matched at least 6 of the 16 largest peaks in the unknown
Rank In. Name
1 24247 2-PROPANOL, 1-[2-(2-METHOXY-1-METHYLETHOXY)-1-METHYLETHOXY]-
2 16192 2-PROPANOL, 1-[1-METHYL-2-(2-PROPENYLOXY)ETHOXY]-
3 36537 2,5,8,11-TETRAOXATETRADECAN-13-OL. 4,7,10-TRIMETHYL-
4 9228 1-PROPANOL, 2-<2-METHOXYPROPOXY)-
5 5522 2-HEXANOL, 2,3-DIMETHYL-
6 20626 2-PROPANOL, 1,1'-[(1-METHYL-1,2-ETHANEDIYL)BIS
-------
MID LIBRARY SEARCH (LIBRARYNB) DATA: 300681MBSX #1338
08/31/98 16:02:00 + 14:53 CALI: 300681MBSX # 3
SAMPLE: SBLKSX 31JUL98-16A 1/3SA/1ML INST. ID: F16
CONDS.: UG/ML *1ML * 1002/1007. */l/3SA NA M
ENHANCED
BASE M/Z: 59
RIC: 2672.
1000
SAMPLE
Jill . Illl
\'
C10.H22.04
1000
RANK 1
# 24247
PUR 680
C9.H18.03
1000 •
M WT 17
B PK 5:
RANK 2
* 16192
PUR 611
2-PROPANOL , 1 - [ 2- < 2-METHOXY- 1 -METHYLETHOXY ) - 1 -METHYLETHOXY ] -
2-PROPANOL, l-Cl-METHYL-2-<2-PROPENYLOXY)ETHOXY]-
C13.H28.05
1000
M WT 264
B PK 59
RANK 3
* 36537
PUR 609
M/Z
2,5/8,11-TETRAOXATETRADECAN-13-OL, 4,7,10-TRIMETHYL-
In I
50
160
150
200
250
en
-------
Library Search Data: 300681 MBSX #1360 Base m/z: 59
08/31/98 16:02:00 + 15:08 Call: 300681 MBSX # 3 RIC: 2164.
Sample: SBLKSX 31JUL98-16A 1/3SA/1ML INST. ID: F16
Conds.: UG/ML *1ML *100%/100X *(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
469 matched at least 6 of the 16 largest peaks in the unknown
Rank In. Name
1 9228 1-PROPANOL, 2-<2-METHOXYPROPOXY>-
2 24247 2-PROPANOL, 1- [2-(2-METHOXY-1-METHYLETHOXY)-1-METHYLETHOXY] -
3 1775 PENTANE, 2-METHOXY-
'* 5826 2-PROPANOL, 1-ISOPROPOXY-2-METHYL-
5 1778 3-PENTANOL, 2-METHYL-
i 3331 HYDRAZINE, 2-BUTYL-1 ,1-DIMETHYL-
7 915 1,2-BUTANEDIOL
3 1788 BUTANE, 2-METHOXY-3-METHYL-
? 3333 HYDRAZINE, 1 , 1-DIMETHYL-2-(1-METHYLPROPYL)-
iank Formula
I C7.H16.03
! C10.H22.04
I C6.H14.0
C7.H16.02
C6.H14.0
C6.H16.N2
C4.H10.02
C6.H14.0
C6.H16.N2
ank Ret.Time B.P.Int. US.Par.1
M.Ut
148
206
102
132
102
116
90
102
116
B.Pk Purity Fit
59
59
59
59
59
59
59
59
59
I US. Par. 2
757 871
644 721
630 916
600 743
590 851
583 742
565 814
555 901
555 658
C.A.S. #
13588-28-8
20324-33-8
6795-88-6
3587-75-5
565-67-3
54007-23-7
584-03-2
62016-49-3
54007-24-8
RFit
777
798
658
669
627
625
660
595
632
Ib'76
-------
MID LIBRARY SEARCH (LIBRARYNB) DATA:
08/31/"98 16:62:00 + 15:08 CALI:
SAMPLE: SBLKSX 31JUL98-16A 1/3SA/1ML INST. ID:
CONDS.: UG/ML *1ML *100Z/100Z *-l -METHYLETHOXY]-
r -
, ,1 1
PENTANE
r
.11 .,1 , ,
1 , , -,--.- 1,1 'l 1 ,- 1,
[, 2-METHOXY-
40 60 80 100 120 140 160
•• 7
-------
Library Search Data: 300681MBSX #1509
08/31/98 16:02:00 + 16:47 Call: 300681HBSX # 3
Sample: SBLKSX 31JUL98-16A 1/3SA/1ML INST.
Conds.: UG/ML *1ML *100X/100% *(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
Base m/z: 59
RIC: 4384.
ID: F16
62231 spectra in LIBRARYNB searched for maximum PURITY
991 matched at least 5 of the 16 largest peaks in the unknown
Rank In.
1 24247
2 36537
9228
3502
16192
6 20626
7
8
9
3522
9235
5522
Rank
1
2
3
it
5
6
7
3
Name
2-PROPANOL, 1-[2-(2-METHOXY-1-METHYLETHOXY)-1-METHYLETHOXY]-
2,5,8,11-TETRAOXATETRADECAN-13-OL, 4,7,10-TRIMETHYL-
1 -PROPANOL, 2-(2-METHOXYPROPOXY)-
BUTANOIC ACID, 3-HYDROXY-3-METHYL-
2-PROPANOL, 1-[1-METHYL-2-(2-PROPENYLOXY)ETHOXY]-
2-PROPANOL, 1,1'-C(1-METHYL-1f2-ETHANEDIYL)BIS
-------
MID LIBRARY SEARCH (LIBRARYNB) DATA:
08/31/98 16:82:00 + 16:47 CALI:
SAMPLE: SBLKSX 31JUL98-16A 1/3SA/1ML INST. ID:
COHDS.: UG/ML *1ML * 100Z/100P. *-l-METHYLETHOXY3-
r
1 In
1 1. ... 1.
5 2,5,8,11 -TETRAOXATETRADECAN- 1 3-OL , 4 , 7 , 1 0-TR I METHYL-
r
ll III 1
1 .!....,..!.... . ... .
1 -PROPANOL , 2- < 2-METHOX YPROPOX Y > -
r
1 1.,
1 . . ll 1
M/Z
100
150
200
250
-------
Library Search Data: 300681MBSX #1533 Base m/z: 59
08/31/98 16:02:00 + 17:03 Cali: 300681MBSX # 3 RIC: 3384.
Sample: SBLKSX 31JUL98-16A 1/3SA/1ML INST. ID: F16
Conds.: UG/HL *1ML *100%/100X *(NA/NA )/1/3SA NA M
Enhanced (S 158 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
427 matched at least 5 of the 16 largest peaks in the unknown
Rank In. Name
1 9228 1-PROPANOL, 2-<2-METHOXYPROPOXY)-
2 5826 2-PROPANOL, 1-ISOPROPOXY-2-METHYL-
3 24247 2-PROPANOL, 1-[2-(2-METHOXY-1-METHYLETHOXY)-1-METHYLETHOXY]-
4 5506 2,3,3-TRIMETHYL-2-PENTANOL
5 334 2-PROPANOL, 2-METHYL-
6 11721 NONANAMIOE
7 1618 8UTANAMIOE, 3-METHYL-
8 3366 2-PENTANOL, 2,4-DIMETHYL-
9 329 PROPANE, 2-METHOXY-
M.Wt B.Pk Purity Fit RFit
Rank
1
2
3
4
5
6
7
8
9
Formula
C7.H16.03
C7.H16.02
C10.H22.04
C8.H18.0
C4.H10.0
C9.H19.0.N
C5.H11.0.N
C7.H16.0
C4.H10.0
148
132
206
130
74
157
101
116
74
59
59
59
59
59
59
59
59
59
599
542
523
513
508
492
487
475
475
812
721
673
844
936
755
804
863
899
663
581
699
576
536
559
570
530
525
Rank
1
2
3
4
5
6
7
8
9
Ret.Time
B.P.Int.
US.Par.1
US.Par.2
C.A.S.
13588-
3587-
20324-
23171-
75-
1120-
541-
625-
598-
#
28-8
75-5
33-8
85-9
65-0
07-6
46-8
06-9
53-8
-------
MID LIBRARY SEARCH (LIBRARYNB) DATA:
08/31/98 16:82:00 + 17:03 CALI:
SAMPLE: SBLKSX 31JUL98-16A 1/3SA/1ML INST. ID:
CONDS.: UG/ML *1ML *100Z/100Z *
300681MBSX #1533
300681MBSX # 3
F16
BASE M/Z: 59
RIC: 3384.
1000
SAMPLE
C7.H16.03
1000 1
M WT 148
B PK 59
RANK 1
* 9228
PUR 599
C7.H16.02
1000 1
M WT 132
B PK 59
RANK 2
ft 5826 '
PUR 542
C10.H22.0'
1000 1
M WT 206
B PK 59
RANK 3
# 24247
PUR 523
M/Z
r
, IM ,i
l-PROPANOL, 2-< 2-METHOX YPROPOXY)- ' ' .......
r
,1 i,, I .,
2-PROPANOL , 1 - I SOPROPOXY-2-METHYL-
r r
, 1 . . ,,
1 , .
\ 2-PROPANOL, l-C2-<:2-METHOXY-l-METHYLETHOXY)-l -METHYLETHOXY]-
r
i 1,. 1 .,
1 1
40 60 80 100 120 140 160 180 200 22C
»-'•
c:
On
-------
Library Search Data: 300681MBSX #1661 Base m/z: 59
08/31/98 16:02:00 + 18:29 Cali: 300681MBSX # 3 RIC: 3272.
Sample: SBLKSX 31JUL98-16A 1/3SA/1ML INST. ID: F16
Conds.: UG/ML *1ML »100%/100X *(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
62231 spectra in L1BRARYNB searched for maximum PURITY
295 matched at least 6 of the 16 largest peaks in the unknown
Rank In. Name
1 3502 BUTANOIC ACID, 3-HYDROXY-3-HETHYL-
2 3247 2-PENTANONE, 5-METHOXY-
3 8871 METHANE, TERT-BUTOXYISOPROPOXY-
4 16192 2-PROPANOL, 1- [1-METHYL-2-(2-PROPENYLOXY)ETHOXY] -
5 23273 ETHANEDIOIC ACID, BIS(I-METHYLPROPYL) ESTER
6 5810 2-PENTANOL, 5-METHOXY-2-METHYL-
7 9227 1,3,3-TRIMETHOXYBUTANE
8 5832 2-PROPANOL, 1-<1-METHYLPROPOXY)-
9 24247 2-PROPANOL, 1- [2-(2-METHOXY-1-METHYLETHOXY)-1-METHYLETHOXY] -
M.Wt B.Pk Purity Fit RFit
Rank Formula
1
2
3
4
5
6
7
8
9
C5.H10.03
C6.H12.02
C8.H18.02
C9.H18.03
C10.H18.04
C7.H16.02
C7.H16.03
C7.H16.02
C10.H22.04
118
116
146
174
202
132
148
132
206
59
43
57
59
57
59
45
43
59
463
462
457
453
448
447
446
445
441
839
902
852
738
696
834
717
748
755
501
468
464
477
476
478
463
519
491
Rank
1
j
5
Ret.Time
B.P.Int.
US.Par.1
US.Par.2
C.A.S,
625-
17429-
4346-
55956-
13784-
55724-
6607-
53907-
20324-
#
08-1
04-8
01-4
25-7
89-9
04-4
66-5
95-2
33-8
-------
MID LIBRARY SEARCH CLIBRARYNB) DATA:
08x31/98 16:02:09 + 18:29 CALI:
SAMPLE: SBLKSX 31JUL98-16A 1/3SA/1ML INST. ID:
CONDS.: UG/ML *1ML *100Z/100Z *
300681MBSX #1661
300681MBSX # 3
F16
BASE M/Z: 59
RIC: 3272.
1117 -j
SAMPLE
C5.H10.03
1117 -i
M UT 118
B PK 59
RANK 1
ft 3502
PUR 463
C6.H12.02
1117 i
M MT 116
B PK 43
RANK 2
ft 3247
PUR 462
C8.H18.02
1117 •
M WT 146
B PK 57
RANK 3
ft 8871
PUR 457
M/Z
li
Ji
,i 'In
ill
'
||
'• • i1'1
• '• • i i i 'i I
40
u^~
BUTANOIC ACID, 3-HYDROXY-3-METHYL-
2-PENTANONE, 5-METHOXY-
| , . ,|. . , — T , , , [ . -T-—
METHANE, TERT-BUTOXY I SOPROPOXY-
^ i i ^ , , 1 — -
60 ' 80 100 120 140 160 180 200 220
cr:
-------
Library Search Data: 300681MBSX #1690 Base m/z: 59
08/31/98 16:02:00 + 18:48 Cali: 300681MBSX # 3 RIC: 1908.
Sample: SBLKSX 31JUL98-16A 1/3SA/1ML INST. ID: F16
Conds.: UG/ML *1ML *100%/100X *(NA/NA )/1/3SA NA M
Enhanced (S 158 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
360 matched at least 5 of the 16 largest peaks in the unknown
Rank In. Name
1 5432 2-BUTANONE, 3-ETHOXY-3-METHYL-
2 1775 PENTANE, 2-METHOXY-
3 20626 2-PROPANOL, 1.1'- [(1-METHYL-1,2-ETHANEDIYL)BIS(OXY)]BIS-
4 1694 3-HYDROXY-3-METHYL-2-BUTANONE
5 5527 2-HEPTANOL, 2-METHYL-
6 1760 2-PENTANOL, 2-METHYL-
7 6082 1-PROPANOL, 2-<2-HYDROXYPROPOXY)-
8 8432 2-HEXANONE. 3-HYDROXY-3.5-DIMETHYL-
9 16649 1-PROPANOL, 3-[3-(1-METHYLETHOXY)PROPOXY]-
M.Wt B.Pk Purity Fit RFit
Rank
1
2
3
!>
3
i
7
!
)
Formula
C7.H14.02
C6.H14.0
C9.H20.04
C5.H10.02
C8.H18.0
C6.H14.0
C6.H14.03
C8.H16.02
C9.H20.03
130
102
192
102
130
102
134
144
176
59
59
59
59
59
59
59
59
59
524
519
507
496
491
490
480
478
477
771
855
769
854
784
818
782
782
748
547
587
587
550
615
540
529
581
552
lank
Ret.Time B.P.Int.
US.Par.1 US.Par.2
C.A.S
36687
6795
1638
115
625
590
106
6321
54518
, #
•99-7
88-6
16-0
22-0
25-2
36-3
62-7
•14-8
•03-5
-------
MID LIBRARY SEARCH (LIBRARYNB)
88/31/98 16:02:88 + 18:48
SAMPLE: SBLKSX 31JUL98-16A 1/3SA/1ML
CONDS.: UG/ML *1ML * 108Z/1 80* */l/3SA
ENHANCED (S 15B 2N 8T>
DATA:
CALI:
INST. ID:
NA M
38868 1MBSX #1698
388681MBSX ft 3
F16
BASE M/Z: 59
RIC: 1988.
1818
SAMPLE
4-
C7.H14.02
2-BUTANONE, 3-ETHOXY-3-METHYL-
SWT 138
PK 59
RANK 1
# 5432
PUR 524
C6.H14.0
1810 1
BUT 182
PK 59
RANK 2
# 1775
PUR 519
C9.H20.04
1010 1
M WT 192
B PK 59
RANK 3
« 20626
PUR 507
M/Z
. i.
r
••
,11 1.
r
., 1 . In
PENTANE, 2-METHOXY- ' ' - ....
j ^. . i
2-PROPANOL, l;r-[BIS]BIS- '
— "
* - ' • . .
1 "^— • ...,-,. • -, . , . , . , , , . , . , , 1 ' | • 1 • 1 • 1
50 100 150 200
c:
-------
Library Search Data: 300681MBSX #1803 Base m/z:
08/31/98 16:02:00 + 20:03 Cali: 300681MBSX # 3 RIC:
Sample: SBLKSX 3UUL98-16A 1/3SA/1ML INST. ID: F16
Conds.: UG/ML *1ML *100%/100% *(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
726 matched at least 4 of the 16 largest peaks in the unknown
59
2652.
Rank In. Name
1 3333 HYDRAZINE, 1,1-DIMETHYL-2-(1-METHYLPROPYL)-
2 9228 1-PROPANOL, 2-<2-METHOXYPROPOXY)-
3 5815 1-TERT-BUTOXY-2-METHOXYETHANE
4 1760 2-PENTANOL, 2-METHYL-
5 12782 BIS(2-METHOXYETHYL)NITROSAMINE
6 3364 ETHER, SEC-BUTYL ISOPROPYL
7 3454 ETHANED10IC ACID, DIMETHYL ESTER
8 20626 2-PROPANOL, 1,1 •- Cd-METHYL-1,2-ETHANEDIYL)BIS
-------
MID LIBRARY SEARCH (LIBRARYNB)
88/31/98 16:82500 + 20:03
SAMPLE: SBLKSX 31JUL98-16A 1/3SA/1ML
CONDS.: UG/ML *1ML *100/5/100Z */l/3SA
ENHANCED
DATA: 300681MBSX #1803
CALI: 300681MBSX # 3
INST. ID: F16
NA M
BASE M/Z: 59
RIC: 2652.
1600 -
SAMPLE
C6.H16.N2
1600 i
M WT 116
B PK 59
RANK 1
ft 3333
PUR 406
C7.H16.03
1600 1
M WT 148
B PK 59
RANK 2
ft 9228 '
PUR 358
C7.H16.02
1600 i
M WT 132
B PK 57
RANK 3
# 5815 '
PUR 356
M/Z
r
j
r
• - • * i
r
r
ll i .III
50
1 . . .. J , , . .| 1. 1 . | . j ,
HYDRAZ I NE , 1 , 1 -D I METHYL-2- < 1 -METHYLPROPYL > -
I . 1 .
1 -PROPANOL , 2- < 2-METHOXYPROPOXY ) -
1 -TERT-BUTOXY-2-METHOXYETHANE
100 150 200 250 300 350
CT
CO
•vl
-------
Library Search Data: 300681MBSX #1933 Base m/z: 59
08/31/98 16:02:00 + 21:30 Cali: 3006B1HBSX # 3 R1C: 3144.
Sample: SBLKSX 3UUL98-16A 1/3SA/1ML INST. ID: F16
Conds.: UG/ML *1ML *100%/100% *(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
580 matched at least 5 of the 16 largest peaks in the unknown
Rank In. Name
1 3528 2-METHYL-2.3-PENTANEDIOL
2 20626 2-PROPANOL. 1,1'-U1-METHYL-1,2-ETHAHEDlYL)BIS(OXY)JBIS-
3 9227 1,3,3-TRIMETHOXYBUTANE
4 1909 2-PROPANOL, 1-METHOXY-2-METHYL-
5 5809 1-ETHOXYPENTAN-3-OL
6 3247 2-PENTANONE, 5-METHOXY-
7 24247 2-PROPANOL, 1-[2-(2-METHOXY-1-METHYLETHOXY)-1-METHYLETHOXY]-
8 5810 2-PENTANOL, 5-METHOXY-2-METHYL-
9 6083 2-PROPANOL, 1,1'-OXYBIS-
Rank
1
2
3
4
5
6
7
B
9
Formula
C6.H14.02
C9.H20.04
C7.H16.03
C5.H12.02
C7.H16.02
C6.H12.02
C10.H22.04
C7.H16.02
C6.H14.03
H.Wt
118
192
148
104
132
116
206
132
134
B.Pk
59
59
45
59
59
43
59
59
59
Purity
425
422
416
403
401
391
390
389
386
Fit
844
763
675
885
845
826
695
779
840
RFit
455
451
444
432
446
411
497
437
412
Rank
1
2
3
4
5
6
7
8
9
Ret.Time
B.P.Int.
US.Par.1
US.Par.2
C.A.S. #
7795-80-4
1638-16-C
6607-66-5
3587-64-2
17429-04-8
20324-33-8
55724-04-4
110-98-5
-------
MID LIBRARY SEARCH CLIBRARYNB) DATA:
08/31/98 16:02:00 + 21:30 CALI:
SAMPLE: SBLKSX 31JUL98-16A 1/3SA/1ML INST. ID:
CONDS.: UG/ML *1ML *100Z/100Z *
30068 1MBSX #1933
300681MBSX # 3
F16
BASE M/Z: 59
RIC: 3144.
1371
SAMPLE
C6.H14.02
1371 •
M WT 118
B PK 59
RANK 1
* 3528
PUR 425
C9.H20.04
1371 i
M WT 192
B PK 59
RANK 2
tt 20626
PUR 422
C7.H16.03
1371 i
M WT 148
B PK 45
RANK 3
# 9227
PUR 416
M/Z
il
K'
C"
r
r
r
,
r
1,1
ii
,1
1 .,
i.i 1 . . i Ii .1 i i i.i i i ... . . . , .
2-METHYL-2, 3-PENTANEDIOL
1 ,.,r | II
il . ,
2-PROPANOL , 1 , 1' - C ( 1 -METHYL- 1 , 2-ETHANED I YL ) B I S < OXY ) ] B I S-
1 .
1 , 3, 3-TRIMETHOXYBUTANE
1 .. |. , i
50 100 159 200 250
-------
Library Search Data: 300681MBSX #2052 Base m/z:
08/31/98 16:02:00 + 22:49 Cali: 300681MBSX # 3 R1C:
Sample: SBLKSX 31JUL98-16A 1/3SA/1ML INST. ID: F16
Conds.: UG/ML *1ML *100X/100% *(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
159 matched at least 5 of the 16 largest peaks in the unknown
59
1154.
Rank In. Name
1 16192 2-PROPANOL, 1-[1-METHYL-2-(2-PROPENYLOXY)ETHOXY] -
2 8153 BUTANAMIDE, N-(I-OXOPROPYL)-
3 24247 2-PROPANOL. 1-[2-<2-METHOXY-1-METHYLETHOXY)-1-METHYLETHOXY] -
4 17561 GLUCOSE
5 8871 METHANE, TERT-BUTOXY1SOPROPOXY-
6 12047 BUTANE, 1.1'-OXYBISC3-METHYL-
7 16017 BOROXIN, TRIMETHOXY-
8 8519 3-HEPTANOL, 3,5-DIMETHYL-
9 3461 2-PROPANAMINE, N-METHYL-N-NITRO-
M.Wt B.Pk Purity Fit RFit
Rank
1
2
3
4
5
5
7
3
j
Formula
C9.H18.03
C7.H13.02.N
C10.H22.04
C6.H12.06
C8.H18.02
C10.H22.0
C3.H9.06.B3
C9.H20.0
C4.H10.02.N2
174
143
206
180
146
158
174
144
118
59
57
59
72
57
71
73
73
103
310
291
289
278
273
271
265
264
253
722
604
581
621
695
607
562
590
669
370
404
424
361
366
351
312
357
274
tank Ret.Time B.P.int.
I
US.Par.1
US.Par.2
C.A.S.
55956-
32796-
20324-
50-
4346-
544-
102-
19549-
30893-
#
25-7
69-3
33-8
99-7
01-4
01-4
24-9
74-7
20-0
IbSG
-------
HID LIBRARY SEARCH (LIBRARYNB) DATA:
08/31/98 16:02:00 + 22:49 CALI:
SAMPLE: SBLKSX 31JUL98-16A 1/3SA/1ML INST. ID:
CONDS.: UG/ML *1ML *100Z/100Z *
300681MBSX #2052
300681MBSX # 3
F16
BASE M/Z: 59
RIC: 1154.
1343
SAMPLE
C9.H18.03
1343 •
M WT 174
B PK 59
RANK 1
tt 16192
PUR 310
C7.H13.02
1343 i
SWT 143
PK 57
RANK 2
# 8153
PUR 291
C10.H22.0<
1343 -I
M NT 206
B PK 59
RANK 3
# 24247
PUR 289
M/Z
r
nil . ,1
Mill ill. . . ii I ,
2-PROPANOL, 1 - Cl -METH YL-2- < 2-PROPEN YLOXY) ETHOXY]- ' '
r
.,,.1
N BUTANAMIDE, N-Cl-OXOPROPYl)- ' - • .
r _
i
r
.,1
jll n ...
2-PROPANOL , 1 - C 2- < 2-METHOXY- 1 -METHYLETHOXY ) - 1 -METHYLETHOXY ] -
1
40 60 80 100 120 140 160 180 200
I-'
CT>
-------
Library Search Data: 300681HBSX #2057 Base m/z: 59
08/31/98 16:02:00 + 22:53 Cati: 300681MBSX # 3 RIC: 1700.
Sample: SBLKSX 31JUL98-16A 1/3SA/1HL INST. ID: F16
Conds.: UG/ML *1ML *100X/100X *(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
722 matched at least 5 of the 16 largest peaks in the unknown
Rank In. Name
1 3528 2-METHYL-2.3-PENTANEDIOL
2 1909 2-PROPANOL, 1-METHOXY-2-HETHYL-
3 1919 1-BUTANOL, 3-METHOXY-
4 9227 1,3,3-TRIMETHOXYBUTANE
5 3534 1-BUTANOL. 4-ETHOXY-
6 5810 2-PENTANOL. 5-METHOXY-2-METHYL-
7 5522 2-HEXANOL, 2,3-DIMETHYL-
8 36537 2,5,8,11-TETRAOXATETRADECAN-13-OL, 4,7,10-TRIMETHYL-
9 9010 ACETAMIDE, 2-METHOXY-N-C2-METHOXYETHYL)-
Rank
1
2
3
4
5
6
7
8
9
Formula
C6.H14.02
C5.H12.02
C5.H12.02
C7.H16.03
C6.H14.02
C7.H16.02
C8.H18.0
C13.H28.05
C6.H13.03.N
M.Wt
118
104
104
148
118
132
130
264
147
B.Pk
59
59
59
45
59
59
59
59
45
Purity
422
419
391
389
384
384
381
370
368
Fit
748
836
746
663
692
733
709
569
665
RFit
481
449
426
457
512
455
423
549
479
Rank Ret. Time B.P.Int. US. Par. 1 US. Par. 2
1 _ _ _ _
2 _ _ _ _
5 _ _ _ _
C.A.S
7795
3587
2517
6607
111
55724
19550
20324
55956
#
80-4
64-2
43-3
66-5
73-9
04-4
03-9
34-9
18-8
-------
MID LIBRARY SEARCH (LIBRARYNB) DATA:
08/31/98 16:02:00 + 22:53 CALI:
SAMPLE: SBLKSX 31JUL98-16A 1/3SA/1ML INST. ID:
CONDS.: UG/ML *1ML *100Z/100Z */l/3SA NA M
ENHANCED
300681MBSX #2057
300681MBSX # 3
F16
BASE M/Z: 59
RIC: 1700.
2097
SAMPLE
C6.H14.02
2097 •
M WT 118
B PK 59
RANK 1
# 3528
PUR 422
C5.H12.02
2097 -i
M WT 104
B PK 59
RANK 2
# 1909 '
PUR 419
C5.H12.02
2097 I
M WT 104
B PK 59
RANK 3
# 1919 '
PUR 391
M/Z
,li
JJ
r
1
r
r
i i I.I
Ux
i nil .i.l i i 1 • .
2-METHYL-2.3-PENTANEDIOL ' ' ....
4-
i
ll
il . ,
2-PROPANOL, l-METHOXY-2-METHYL-
1-BUTANOL, 3-METHOXY-
i
40
1 . 1
60 80 100 120 140 160 180
or-
C*'
-------
TIC SELECTION REPORT
DATA FILE: 300681HBSX
THE FOLLOWING PEAKS WERE REJECTED BECAUSE
AT LEAST 40 % OF THEIR SIZE WAS ACCOUNTED FOR BY
TARGET COMPOUNDS ELUTING WITHIN 4 SCANS OF THE
PEAK TOP.
SCAN SIZE AMOUNT
201
309
342
422
530
723
828
968
1086
1383
1383
1551
1782
344792.
406704.
223900.
183296.
266460.
358875.
324123.
355248.
334141.
308474.
307034.
199826.
156554.
51.759
61.053
33.611
27.516
40.000
44.289
40.000
42.527
40.000
61.749
61.460
40.000
40.000
TOTAL NUMBER OF UNIDENTIFIED PEAKS WITH SIZE
GREATER THAN 10 % OF THE CLOSEST INTERNAL STANDARD
THAT DOES NOT HAVE INTERFERENCES = 12
INTERNAL STANDARDS THAT HAVE RIC SIZE LESS THAN
50 % OR GREATER THAN 200 X OF THE ESTIMATED RIC SIZE
ARE CONSIDERED TO HAVE INTERFERENCES AND WILL NOT BE USED
FOR QUANT I TAT I ON.
PERCENT OF
ESTIMATED
# INTERNAL STANDARD RIC SIZE RIC SIZE SCAN
1 CI40 NAPHTHALENE-OS 266460. 127 530
2 C150 ACENAPHTHENE-D10 324123. 124 828
3 CI60 PHENANTHRENE-D10 334141. 119 1086
4 CI70 CHRYSENE-D12 199826. 127 1551
5 CITS PERYLENE-D12 156554. 123 1782
* INDICATES INTERFERENCE
SIZE = AREA
-------
QUANTERRA GC/HS
Target Compound Data Summary Sheet
Data File: 300681MBSF
Std Id: ST16980831
INST. ID: F16
Date Analyzed: 08/31/98 16:31
Run Factor: 1.00
Surrogate Vol.: 1.00
Sample: SBLKSF 01AUG98-16A 1SA/1ML
Client: PAC1FI
Analyst: DAT Instrument ID: F16
Quan List Threshold: 0.95
Surrogate Spike Recoveries
8270-G, LIMS 10/10/96
Surrogate Amount (ug)
Surrogate
CS20 NITROBENZENE-OS
CS25 2-FLUOROBIPHENY
CS30 TERPHENYL-D14
CS45 PHENOL-D5
CS50 2-FLUOROPHENOL
CS55 2,4,6-TRIBROMOP
X Recovery
Spiked
50.00
50.00
50.00
100.0
100.0
100.0
Measured
28.10
27.30
38.70
19.40
37.00
71.80
Measured
QC limits
56.2
54.6
77.4
19.4
37.0
71.8
45 107
62 110
58 135
43 130
36 111
58 131
Parameter
Target Compounds: SAP9
Scan
HEXACHLOROBENZENE-C13
C310 N-NITROSOOIMETHYLAMINE
PYRIDINE
2-PICOLINE
N-NITROSOMETHYLETHYLAMINE
METHYLMETHANESULFONATE
N-NITROSOOIETHYLAMINE
ETHYLMETHANE SULFOKATE
PENTACHLOROETHANE
C320 ANILINE
C315 PHENOL
C325 BIS(2-CHLOROETHYL)ETHER
C330 2-CHLOROPHENOL
C335 1,3-DICHLOROBENZENE
C340 1,4-DICHLOROBENZENE
C345 BENZYL ALCOHOL
C350 1,2-DICHLOROBENZENE
C355 2-METHYLPHENOL
C360 2,2'-OXYBIS(1-CLPROPAN)
C361 ACETOPHENONE
N-N1TROSOPYRROL1DINE
N-NITROSOMORPHOLINE
3-METHYL PHENOL
C365 4-METHYLPHENOL
C370 N-NITROSO-DI-N-PROPYLAM
O-TOLUIDINE
C375 HEXACHLOROETHANE
C410 NITROBENZENE
N-N1TROSOPIPERIDINE
Result
ND
NO
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Units
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
Reporting
Limit
10.0
10.0
20.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
Reviewed by:
-------
QUANTERRA GC/MS
Target Compound Data Summary Sheet
Data File: 300681MBSF
Std Id: ST16980831
Sample: SBLKSF 01AUG98-16A 1SA/1ML INST. ID: F16
Client: PACIFI Date Analyzed: 08/31/98 16:31
Analyst: DAT Instrument ID: F16 Run Factor: 1.00
Quan List Threshold: 0.95 Surrogate Vol.: 1.00
Target Compounds: SAP9
Parameter
C415 ISOPHORONE
C420 2-NITROPHENOL
C425 2,4-DIMETHYLPHENOL
C435 BIS(2-CHLOROETHOXY)METH
C440 2,4-DICHLOROPHENOL
C430 BENZOIC ACID
AA-DIMETHYLPHENETHYLAMINE
C445 1,2,4-TRICHLOROBENZENE
C450 NAPHTHALENE
C455 4-CHLOROANALINE
2,6-DICHLOROPHENOL
HEXACHLOROPROPENE
C460 HEXACHLOROBUT AD I ENE
P-PHENYLENE DIAMINE
N-NITROSOD1-N-BUTYLAMINE
C465 4-CHLORO-3-METHYLPHENO
SAFROLE
C470 2-METHYLNAPHTHALENE
1,2,4,5-TETRACHLOROBENZENE
1SOSAFROLE (#1)
C510 HEXACHLOROCYCLOPENTADI
C515 2,4,6-TRICHLOROPHENOL
C520 2,4,5-TRICHLOROPHENOL
ISOSAFROLE (#2)
C525 2-CHLORONAPHTHALENE
1-CHLORONAPHTHALENE
C530 2-NITROANAL1NE
1,4-NAPHTHOQUINONE
C535 DIMETHYLPHTHALATE
1,3-DlNITROBENZENE
C540 ACENAPHTHYLENE
C543 Z.6-DINITROTOLUENE
C545 3-NITROANILINE
C550 ACENAPHTHENE
C555 2,4-DINITROPHENOL
C565 DIBENZOFURAN
C560 4-NITROPHENOL
PENTACHLOROBENZENE
C570 2,4-DINITROTOLUENE
1-NAPHTHYLAMINE
2-NAPHTHYLAMINE
2,3,4,6-TETRACHLOROPHENOL
C580 DIETHYLPHTHALATE
:590 FLUORENE
Scan Result
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Units
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
Reporting
Limit
10.0
10.0
10.0
10.0
10.0
50.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
20.0
10.0
10.0
10.0
20.0
10.0
5.0
50.0
10.0
10.0
10.0
10.0
10.0
50.0
10.0
50.0
10.0
50.0
10.0
10.0
10.0
10.0
20.0
10.0
10.0
> V O
-------
QUANTERRA GC/MS
Target Compound Data Sunitary Sheet
Data File:
Std Id:
300681MBSf
ST16980831
Sample: SBLKSF 01AUG98-16A
Client: PACIFI
1SA/1ML
INST. ID:
F16
Date Analyzed: 08/31/98 16:
Analyst: DAT Instrument ID: F16
Quan List Threshold: 0.95
Target
Compounds: SAP9
Parameter Scan Result
C585 4-CHLOROPHENYL-PHENYLE
5-NITRO-O-TOLUIDINE
C595 4-NITROANAL1NE
C610 4.6-DINITRO-2-METHYLPH
C615 N-NITROSODIPHENYLAMINE
C620 AZOBENZENE
SYM-TRINITROBENZENE
C625 4-BROMOPHENYL-PHENYLET
PHENACETIN
DIALLATE 234
C630 HEXACHLOROBENZENE
4-AM1NOBIPHENYL
C635 PENTACHLOROPHENOL
PRONAMIDE
PENTACHLORONITROBENZENE
C640 PHENANTHRENE
C645 ANTHRACENE
2SECBUTYL-4.6-DINITROPHENOL
C647 CARBAZOLE
C650 DI-N-BUTYLPHTHALATE
4-N1TROQUINOLINE-1 -OXIDE
METHAPYRILENE
1SOOR1N
C655 FLUORANTHENE
CHLOROBENZILATE
C710 BENZIDINE
C715 PYRENE
ARAM1TE (#1)
ARAMITE (#2)
P-DIMETHYLAMINOAZ08ENZENE
3,3'-DIMETHYLBENZI01NE
KEPONE
C720 BUTYLBENZYLPHTHALATE
2-ACETYLAMINOFUIORENE
C730 BENZO(A)ANTHRACENE
C725 3,3'-DICHLOROBENZIDINE
C740 CHRYSENE
C745 BIS(2-ETHYLHEXYL)PHTHA
3-METHYLCHOLANTHRENE
C760 Dl-N-OCTYL PHTHALATE
C765 BENZO(B)FLUORANTHENE
7,12-DIMETHYLBENZAMTHRACENE
C770 BENZOdOFLUORANTHENE
HEXACHLOROPHENE
NO
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
' ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
NO
ND
ND
ND
ND
ND
ND
ND
Run Factor: 1.00
Surrogate
Units
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
Vol.: 1.00
Reporting
Limit
10.0
10.0
50.0
50.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
50.0
10.0
50.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
100.0
10.0
10.0
10.0
10.0
10.0
50.0
10.0
10.0
10.0
20.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
-------
QUANTERRA GC/MS
Target Compound Data Summary Sheet
Data File: 300681MBSF
Std Id: ST16980831
1NST. ID: F16
Date Analyzed: 08/31/98 16:31
Run Factor: 1.00
Surrogate Vol.: 1.00
Sample: SBLKSF 01AUG98-16A 1SA/1ML
Client: PACIFI
Analyst: DAT Instrument ID: F16
Quan List Threshold: 0.95
Target Compounds: SAP9
Parameter
Scan Result
Reporting
Limit
C775 BENZO(A)PYRENE
C780 INDENO(1.2,3-CD)PYRENE
C785 DIBENZ(A,H)ANTHRACENE
C790 BENZO(G,H,I)PERYLENE
ND
ND
ND
ND
UG/A
UG/A
UG/A
UG/A
10.0
10.0
10.0
10.0
IbL
-------
DATA FROM FILE: 300681MBSF SCANS 93 TO 1283 ACQUIRED: 08/31/98 16:31:00
CALI: 300681MBSF #3
SAMPLE: SBLKSF 01AUG98-16A 1SA/1ML INST. ID: F16
CONDS.: UG/ML *1ML *100Z/100Z *
-------
DATA FROM FILE: 300681MBSF SCANS 1283 TO 2158 ACQUIRED: 08/31/98 16:31:00
CALI: 300681MBSF #3
SAMPLE: SBLKSF 01AUG98-16A 1SA/1ML INST. ID: F16
CONDS.: UG/ML *1ML *180Z/1002 *
-------
STANDARD USED FOR THIS REPORT IS ST16980831
REPORT PRINTED: 9/01/98 10:50:00
ADDITIONAL STANDARD USED FOR THIS REPORT IS: ST16980831A
QUANTERRA QUANT I TAT ION SUMMARY
File: 300681MBSF
Sample: SBLKSF 01AUG98-16A 1SA/1ML INST. ID: F16
Analyst: DAT Instrument Id: F16 Analyzed: 08/31/98 16:31
Compounds with amounts less than 0.20 reported as NOT FOUND
Library
No Entry Name Mass Meth
1 S1# 1 C130 1,4-DICHLOROBENZENE 152 A BB
2 S2# 1 CKO NAPHTHALENE-08 136 A BB
3 S3# 1 CI50 ACENAPHTHENE-D10 164 A BB
4 S4# 1 CI60 PHENANTHRENE-D10 188 A BB
5 S5# 1 CI70 CHRYSENE-D12 240 A BB
6 S6# 1 CI75 PERYLENE-D12 264 A BB
7 S2# 2 CS20 NITROBENZENE-05 82 A BB
8 S3# 3 CS25 2-FLUOROBIPHENYL 172 A BB
9 S5# 2 CS30 TERPHENYL-014 244 A BB
10 S1# 3 CS45 PHENOL -05 99 A BB
11 S1# 2 CS50 2-FLUOROPHENOL 112 A BB
12 S3* 2 CS55 2,4,6-TRIBROMOPHENO 330 A BB
13 S4# 4 HEXACHLOROBENZENE-C13 294
14 S1# 15 C310 N-NITROSOOIMETHYLAM 74
15 S1# 20 PYRIDINE 79
16 S1# 30 2-P1COLINE 93
17 S1# 40 N-NITROSOMETHYLETHYLAMIN 42 A BB
18 S1# 60 METHYLMETHANESULFONATE 80
19 S1# 70 N-NITROSODIETHYLAMINE 102
20 S1# 85 ETHYLMETHANE SULFONATE 79
21 S1# 95 PENTACHLOROETHANE 117
22 S10100 C320 ANILINE 93
23 SinOS C315 PHENOL 94
24 S1#110 C325 BIS(2-CHLOROETHYL)E 93
25 S1#115 C330 2-CHLOROPHENOL 128
26 SDK125 C335 1 ,3-DICHLOROBENZENE 146
27 S1#130 C340 1,4-D1CHLOROBENZENE 146
28 S10145 C345 BENZYL ALCOHOL 108
29 S1#150 C350 1 ,2-DICHLOROBENZENE 146
30 S1#160 C355 2-METHYLPHENOL 108
31 S11K165 C360 2,2' -OXYBIS(1-CLPRO 45
32 S1/M70 C361 ACETOPHENONE 105
33 S1#175 N-NITROSOPYRROLIDINE 100
34 S1#180 N-NITROSOMORPHOLINE 56
35 S1#182 3-METHYL PHENOL 108
36 S1#185 C365 4-METHYLPHENOL 108
37 S1KM90 C370 N-NITROSO-DI-N-PROP 70
38 S1#195 0-TOLUIDINE 106
39 S1#200 C375 HEXACHLOROETHANE 117
40 S2# 10 C410 NITROBENZENE 77
41 S2# 15 N-NITROSOPIPERIDINE 42
42 S2# 20 C415 ISOPHORONE 82
43-S2# 25 C420 2-NITROPHENOL 139
44 S2# 30 C425 2,4-DIMETHYLPHENOL 107
45 S2# 35 C435 BIS(2-CHLOROETHOXY) 93
Scan Ref Area
340 1 30721 .
529 2 108221.
828 3 59070.
1086 4 102024.
1551 5 87857.
1783 6 75258.
421 2 35709.
722 3 49743.
1383 5 84547.
307 1 30107.
196 1 38883.
968 3 24984.
4 NOT FOUND
1 NOT FOUND
1 NOT FOUND
1 NOT FOUND
159 1 156.
1 NOT FOUND
1 NOT FOUND
1 NOT FOUND
1 NOT FOUND
1 NOT FOUND
NOT FOUND
NOT FOUND
NOT FOUND
NOT FOUND
NOT FOUND
1 NOT FOUND
1 NOT FOUND
1 NOT FOUND
1 NOT FOUND
1 NOT FOUND
1 NOT FOUND
1 NOT FOUND
1 NOT FOUND
1 NOT FOUND
1 NOT FOUND
1 NOT FOUND
1 NOT FOUND
2 NOT FOUND
2 NOT FOUND
2 NOT FOUND
2 NOT FOUND
2 NOT FOUND
2 NOT FOUND
Units: UG/ML
RRF(L) Amount
1.000 40.000
1.000 40.000
1.000 40.000
1.000 40.000
1.000 40.000
1.000 40.000
0.470 28.108
1.234 27.290
0.995 38.678
2.025 19.354
1.368 37.002
0.236 71.791
0.811 0.250
1 ^ r '•
J_ i L J.
-------
46 S2# 40 C440 2,4-OICHLOROPHENOL 162 2 NOT FOUND
47 S2# 45 C430 BENZOIC ACID 122 2 NOT FOUND
48 S2# 50 AA-DIMETHYLPHENETHYLAHIN 58 2 NOT FOUND
49 S2# 55 C445 1,2,4-TRlCHLOROBENZ 180 2 NOT FOUND
»-»r
-------
50 S2# 60 C450 NAPHTHALENE
51 S2# 80 C455 4-CHLOROANAL1NE
52 S2# 85 2,6-DICHLOROPHENOL •
53 S2# 90 HEXACHLOROPROPENE
54 S2# 95 C460 HEXACHLOROBUTAD1ENE
55 S2#115 P-PHENYLENE DiAHINE
56 S2#120 N-NITROSOOI-N-BUTYLAMINE
57 S2#130 C465 4-CHLORO-3-METHYLPH
58 S2#140 SAFROLE
59 S2#145 C4-70 2-METHYLNAPHTHALENE
60 S3# 10 1,2,4,5-TETRACHLOROBENZE
61 S3# 15 1SOSAFROLE Of1)
62 S3# 20 C510 HEXACHLOROCYCLOPENT
63 S3* 25 C515 2,4,6-TRICHLOROPHEN
64 S3* 30 C520 2,4,5-TRICHLOROPHEN
65 S3# 35 ISOSAFROLE (#2)
66 S3# 40 C525 2-CHLORONAPHTHALENE
67 S3# 42 1-CHLORONAPHTHALEN
68 S3# 45 C530 2-NITROANALINE
69 S3# 50 1,4-NAPHTHOQUINONE
70 S3# 55 C535 DIMETHYLPHTHALATE
71 S3# 60 1,3-DlNlTROBENZENE
72 S3# 65 C540 ACENAPHTHYLENE
73 S3# 70 C543 2,6-DINITROTOLUENE
74 S3# 75 C545 3-NITROANILINE
75 S3# 80 C550 ACENAPHTHENE
76 S3# 85 C555 2,4-DlNlTROPHENOL
77 S3# 90 C565 DIBENZOFURAN
78 S3# 95 C560 4-NITROPHENOL
79 S3#100 PENTACHLOROBENZENE
80 S3HM05 C570 2,4-DINITROTOLUENE
81 S3mO 1-NAPHTHYLAMINE
82 S3#115 2-NAPHTHYLAMINE
83 S3#120 2,3,4,6-TETRACHLOROPHENO
84 S3#130 C580 DIETHYLPHTHALATE
85 S3#135 C590 FLUORENE
86 S3#140 C585 4-CHLOROPHENYL-PHEN
87 S3#145 5-NITRO-O-TOLUIDINE
88 S3n50 C595 4-NITROANALINE
89 S4# 10 C610 4.6-DINITRO-2-METHY
90 S4# 15 C615 N-N1TROSODIPHENYLAM
91 S4# 20 C620 AZOBENZENE
92 S4# 25 SYM-TRINITROBENZENE
93 S4# 30 C625 4-BROMOPHENYL-PHEMY
94 S4# 35 PHENACETIN
95 S4# 37 DIALLATE
96 S4# 40 C630 HEXACHLOROBENZENE
97 S4# 45 4-AMINOBIPHENYL
98 S4# 50 C635 PENTACHLOROPHENOL
99 S4# 55 PRONAMIDE
100 S4# 60 PENTACHLORONITROBENZENE
101 S4# 65 C640 PHENANTHRENE
102 S4# 70 C645 ANTHRACENE
103 S4# 75 2SECBUTYL-4.6-DINITROPHE
104 S4# 80 C647 CARBAZOLE
105 S4# 85 C650 DI-N-BUTYLPHTHALATE
106 S4#100 4-NITROOUINOLINE-1-OXIDE
107 54*105 METHAPYRILENE
108 S4A106 1SODR1N
109 S4#110 C655 FLUORANTHENE
110 S4#120 CHLOROBENZILATE
128
127
162
213
225
108
84
107
162
142
214
162
237
196
196
104
162
162
65
158
163
168
152
165
138
153
184
168
109
250
165
143
143
232
149
166
204
152
138
198
169
77
75
248
108
234
284
169
266
173
237
178
178
211
167
149 A BB
190
58
193
202
139
2 NOT FOUND
2 NOT FOUND
2 NOT FOUND
2 NOT FOUND
2 NOT FOUND
2 NOT FOUND
2 NOT FOUND
2 NOT FOUND
2 NOT FOUND
2 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
4 NOT FOUND
4 NOT FOUND
4 NOT FOUND
4 NOT FOUND
4 NOT FOUND
4 NOT FOUND
4 NOT FOUND
4 NOT FOUND
4 NOT FOUND
4 NOT FOUND
4 NOT FOUND
4 NOT FOUND
4 NOT FOUND
4 NOT FOUND
4 NOT FOUND
4 NOT FOUND
1226 4 796
4 NOT FOUND
4 NOT FOUND
4 NOT FOUND
4 NOT FOUND
4 NOT FOUND
1.247 0.250
T »••} I
1< '
f
«-
-------
111 S5# 10 C710 BENZIDIME 184 5 NOT FOUND
112 S5# 15 C715 PYRENE 202 5 NOT FOUND
113 S5# 20 ARAMITE (#1) 185 5 NOT FOUND
IK S5# 25 ARAMITE (#2) 185 5 NOT FOUND
115 S5# 30 P-DIMETHYLAM1NOAZOBENZEN 120 5 NOT FOUND
116 S5# 35 3,3'-DIMETHYLBENZIDINE 212 5 NOT FOUND
117 S5# 37 KEPONE 272 5 NOT FOUND
118 S5# 40 C720 BUTYLBENZYLPHTHALAT 149 5 NOT FOUND
119 S5# 45 2-ACETYLAMINOFLUORENE 181 5 NOT FOUND
120 S5# 50 C730 BENZO(A)ANTHRACENE 228 5 NOT FOUND
121 S5# 55 C725 3,3'-DICHLOROBENZID 252 5 NOT FOUND
122 S5# 60 C740 CHRYSENE 228 5 NOT FOUND
123 S5# 65 C745 BIS(2-ETHYLHEXYL)PH 149 A BB 1603 5
124 S5# 85 3-METHYLCHOLANTHRENE 268 5 NOT FOUND
125 S6# 10 C760 DI-N-OCTYL PHTHALAT 149 6 NOT FOUND
126 S6# 15 C765 BENZO(B)FLUORANTHEN 252 6 NOT FOUND
127 S6# 20 7,12-DlMETHYLBENZANTHRAC 256 6 NOT FOUND
128 S6# 25 C770 BENZO(K)FLUORANTHEN 252 6 NOT FOUND
129 S6# 30 HEXACHLOROPHENE 196 6 NOT FOUND
130 S6# 35 C775 BENZO(A)PYRENE 252 6 NOT FOUND
131 S6# 55 C780 INOENOd ,2,3-CO)PYR 276 6 NOT FOUND
132 S6# 60 C785 DIBENZ(A,H)ANTHRACE 278 6 NOT FOUND
133 S6# 65 C790 BENZO(G,H,I)PERYLEN 276 6 NOT FOUND
576. 0.980 0.268
r £
-------
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-------
Data Reduced by: Date: Data File: 300681MBSF
Data Reviewed by: Date:
OUANTERRA GC/MS TIC REPORT ( Part 1 )
Sample: SBLKSF 01AUG98-16A 1SA/1ML INST. ID: F16
Analyst: DAT Date Analyzed: 08/31/98 16:31
Run Factor: 1.00
Concentration
in Sample
# SCAN (UG/A) CAS #
No peaks to search.
17 CB
-------
DATA FILE: 300681MBSF
QUANTERRA GC/MS TIC REPORT ( Part 2 )
CONCENTRATION = AREA(TIC)*CONC(IS)/AREA(IS)
AMOUNT
INT. AS ANALYZED
# FIT PURITY STD. RT RRT AREA HEIGHT (UG/ML ) LIB LIB #
.70?
-------
TIC SELECTION REPORT
DATA FILE: 300681MBSF
THE FOLLOWING PEAKS WERE REJECTED BECAUSE
AT LEAST 40 % OF THEIR SIZE WAS ACCOUNTED FOR BY
TARGET COMPOUNDS ELUT1NG WITHIN 4 SCANS OF THE
PEAK TOP.
SCAN SIZE AMOUNT
196
307
340
421
529
722
828
968
1086
1384
1384
1551
1783
129024.
75740.
185996.
91232.
228960.
152596.
273414.
231786.
276153.
308768.
308768.
277946.
258361 .
22.541
13.232
32.494
15.939
40.000
22.325
40.000
33.574
40.000
44.436
44.436
40.000
40.000
TOTAL NUMBER OF UNIDENTIFIED PEAKS WITH SIZE
GREATER THAN 10 % OF THE CLOSEST INTERNAL STANDARD
THAT DOES NOT HAVE INTERFERENCES = 0
INTERNAL STANDARDS THAT HAVE RIC SIZE LESS THAN
50 % OR GREATER THAN 200 % OF THE ESTIMATED RIC SIZE
ARE CONSIDERED TO HAVE INTERFERENCES AND WILL NOT BE USED
FOR QUANT 1 TAT I ON.
PERCENT OF
ESTIMATED
* INTERNAL STANDARD RIC SIZE RIC SIZE SCAN
1 CI40 NAPHTHALENE-08
2 CI50 ACENAPHTHENE-D10
3 CI60 PHENANTHRENE-D10
4 CI70 CHRYSENE-D12
5 CI75 PERYLENE-D12
228960.
273414.
276153.
277946.
258361 .
132
128
119
129
128
529
828
1086
1551
1783
* INDICATES INTERFERENCE
SIZE = AREA
17 Co
-------
Sample: SBLKSF 01AUG98-16A
Client: PACIF1
Analyst: DAT Instrument
Quan List Threshold: 0.95
OUANTERRA GC/MS
Target Compound Data Summary Sheet
Data File: 300681MBSFI
Std Id: ST16980902
1SA/1ML INST. ID: F16
Date Analyzed: 09/02/98 16:29
ID: F16 Run Factor: 1.00
Surrogate Vol.: 1.00
Surrogate
CS20 NITROBENZENE-05
CS25 2-FLUOROBIPHENY
CS30 TERPHENYL-D14
CS45 PHENOL-OS
CS50 2-FLUOROPHENOL
CS55 2,4,6-TRlBROMOP
Surrogate Spike Recoveries
8270-G, LIMS 10/10/96
Surrogate Amount (ug)
Spi ked Measured '
50.00
50.00
50.00
100.0
100.0
100.0
27.50
26.00
37.90
16.90
35.80
72.50
55.0
52.0
75.8
16.9
35.8
72.5
X Recovery
Measured QC limits
45 107
62 110
58 135
43 130
36 111
58 131
Target Compounds: SAP9
Parameter
Scan
Result
Units
CS70 2-CHLOROPHENOL-D4
CS75 1.2-D1CHLOROBNZN-D4
HEXACHLOROBENZENE-C13
C310 N-NITROSOD1METHYLAMINE
PYRIDINE
2-P1COLINE
N-NITROSOMETHYLETHYLAMINE
METHYLMETHANESULFONATE
N-NITROSOOIETHYLAMINE
ETHYLMETHANE SULFONATE
PENTACHLOROETHANE
C320 ANILINE
C315 PHENOL
C325 BIS(2-CHLOROETHYL)ETHER
C330 2-CHLOROPHENOL
C335 1,3-DICHLOROBENZENE
C340 1,4-DICHLOROBENZENE
C345 BENZYL ALCOHOL
C350 1,2-DICHLOROBENZENE
C355 2-METHYLPHENOL
C360 2,2'-OXYBIS(1-CLPROPAN)
C361 ACETOPHENONE
N-NITROSOPYRROLIDINE
N-NITROSOMORPHOL1NE
3-METHYL PHENOL
C365 4-METHYLPHENOL
C370 N-NITROSO-DI-N-PROPYLAM
0-TOLUIDINE
C375 HEXACHLOROETHANE
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
Reporting
Limit
=~===?:=s~==
10.0
10.0
10.0
10.0
20.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
17 C
Reviewed by:
-------
Sample: SBLKSF
Client: PACIFI
Analyst: DAT
OUAHTERRA GC/MS
Target Compound Data Summary Sheet
Data File: 300681MBSFI
Std Id: ST16980902
INST. ID: F16
Date Analyzed: 09/02/98 16:29
Run Factor: 1.00
01AUG98-16A 1SA/1ML
Instrument ID: F16
Quan List Threshold: 0.95
Surrogate Vol.:
1.00
Target Compounds: SAP9
Parameter Scan
C410 NITROBENZENE
N-N1TROSOPIPERIDINE
C415 ISOPHORONE
C420 2-NITROPHENOL
C425 2,4-DlMETHYLPHENOL
C435 BIS(2-CHLOROETHOXY)METH
C440 2,4-DICHLOROPHENOL
C430 BENZOIC ACID
AA-OIMETHYLPHENETHYLAMINE
C445 1,2,4-TRICHLOROBENZENE
C450 NAPHTHALENE
C455 4-CHLOROANALINE
2,6-DICHLOROPHENOL
HEXACHLOROPROPENE
1460 HEXACHLOROBUTADIENE
'-PHENYLENE DIAMINE
1-NITROSODI-N-BUTYLAMINE
:465 4-CHLORO-3-METHYLPHENO
5AFROLE
:470 2-METHYLNAPHTHALENE
1,2.4,5-TETRACHLOROBENZENE
ISOSAFROLE (#1)
:510 HEXACHLOROCYCLOPENTAD I
:515 2,4,6-TRICHLOROPHENOL
:520 2,4,5-TRICHLOROPHENOL
ISOSAFROLE (#2)
:525 2-CHLORONAPHTHALENE
1-CHLORONAPHTHALENE
:530 2-NITROANALINE
1,4-NAPHTHOQUINONE
:535 DIMETHYLPHTHALATE
1,3-DINITROBENZENE
:540 ACENAPHTHYLENE
:543 2,6-DINITROTOLUENE
:545 3-NITROANILINE
:S50 ACENAPHTHENE
.'555 2,4-DINITROPHENOL
'.565 DIBENZOFURAN
:560 4-NITROPHENOL
'ENTACHLOROBENZENE
:570 2,4-DlNITROTOLUENE
-NAPHTHYLAMINE
-NAPHTHYLAMINE
,3,4,6- TETRACHLOROPHENOL
Result
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Units
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
Reporting
Limit
10.0
10.0
10.0
10.0
10.0
10.0
10.0
50.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
20.0
10.0
10.0
10.0
20.0
10.0
5.0
50.0
10.0
10.0
10.0
10.0
10.0
50.0
10.0
50.0
10.0
50.0
10.0
10.0
10.0
10.0
20.0
lr
-------
Sample: SBLKSF 01AU
Client: PACIFI
Analyst: DAT
Ouan List Threshold:
Parameter
QUANTERRA GC/MS
Target Compound Data Summary sheet
Data File: 300681MBSFI
Std Id: ST16980902
F16
zed: 09/02/98 16:29
: 1.00
Vol.: 1.00
Reporting
Limit
C580 D1ETHYLPHTHALATE
C590 FLUORENE
C585 4-CHLOROPHENYL-PHENYLE
5-NITRO-O-TOLUIDINE
C595 4-NITROANALINE
C610 4,6-DlNITRO-2-METHYLPH
C615 N-NITROSOOIPHENYLAMINE
C620 AZOBENZENE
SYM-TRINITROBENZENE
C625 4-BROMOPHENYL-PHENYLET
PHENACETIN
D1ALLATE
C630 HEXACHLOROBENZENE
4-AMINOB1PHENYL
C635 PENTACHLOROPHENOL
PRONAMIDE
PENTACHLORONITROBENZENE
C640 PHENANTHRENE
C645 ANTHRACENE
2SECBUTYL-4.6-DINITROPHENOL
C647 CARBAZOLE
C650 OI-N-BUTYLPHTHALATE
4-NITROQUINOLINE-1-OXIDE
METHAPYRILENE
ISOORIN
C655 FLUORANTHENE
CHLOROBENZILATE
C710 BENZID1NE
C715 PYRENE
ARAMITE (#1)
ARAMITE (#2)
P-DIMETHYLAMINOAZOBENZENE
3,3'-DIMETHYLBENZIDINE
KEPONE
C720 BUTYLBENZYLPHTHALATE
2-ACETYLAMINOFLUORENE
C730 BENZO(A)ANTHRACENE
C725 3,3'-DICHLOROBENZIDINE
C740 CHRYSENE
C745 BIS(2-ETHYLHEXYL)PHTHA
3-METHYLCHOLANTHRENE
C760 DI-N-OCTYL PHTHALATE
C765 BENZO(B)FLUORANTHENE
7,12-DIMETHYLBENZANTHRACENE
S-16A 1SA/1ML
tstrument ID: F16
0.95
Target Compounds: SAP9
Scan Result
NO
ND
NYLE ND
ND
ND
YLPH ND
MINE ND
ND
ND
YLET ND
ND
234 ND
ND
ND
ND
ND
ND
ND
ND
ENOL ND
ND
E ND
E ND
ND
ND
ND
ND
ND
ND
ND
ND
NE ND
ND
ND
TE ND
ND
ND
DINE ND
ND
HTHA ND
ND
TE ND
NE ND
CENE ND
INST. ID
Date Ai
Run Fai
Surrog;
Units
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
10.0
10.0
10.0
10.0
50.0
50.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
50.0
10.0
50.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
100.0
10.0
10.0
10.0
10.0
10.0
50.0
10.0
10.0
10.0
20.0
10.0
10.0
10.0
10.0
10.0
10.0
1711
-------
QUANTERRA GC/MS
Target Ccxnpound Data Summary Sheet
Data File: 300681MBSFI
Std Id: ST16980902
INST. ID: F16
Date Analyzed: 09/02/98 16:29
Run Factor: 1.00
Surrogate Vol.: 1.00
Sample: SBLKSF 01AUG98-16A 1SA/1ML
Client: PACIFI
Analyst: DAT Instrument ID: F16
Ouan List Threshold: 0.95
Target Compounds: SAP9
Parameter
Scan Result
Reporting
Limit
C770 BENZOdOFLUORANTHENE
HEXACHLOROPHENE
C775 BENZO(A)PYRENE
C780 INDENO(1,2,3-CD)PYRENE
C765 01BENZ(A,H)ANTHRACENE
C790 BENZO(G,H,I)PERYLENE
ND
ND
ND
ND
ND
ND
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
10.0
10.0
10.0
10.0
10.0
10.0
IV
-------
DATA FROM FILE: 300681MBSFI SCANS 94 TO 1204 ACQUIRED: 09/02/98 16:29:00
CALI: 300681MBSFI #3
SAMPLE: SBLKSF 01AUG98-16A 1SA/1ML INST. ID: F16
CONDS.: UG/ML *1ML *100Z/100Z *
-------
DATA FROM FILE: 300681MBSFI SCANS 1204 TO 2158 ACQUIRED: 09/02/98 16:29:00
CALI: 300681MBSFI #3
SAMPLE: SBLKSF 01AUG98-16A 1SA/1ML INST. ID: F16
CONDS.: UG/ML *1ML * 100Z/100?! *
-------
STANDARD USED FOR THIS REPORT IS ST16980902 REPORT PRINTED: 9/02/98 17:53:59
ADDITIONAL STANDARD USED FOR THIS REPORT IS: ST16980902A
OUANTERRA QUANT I TAT ION SUMMARY File: 300681MBSFI
Sample: SBLKSF 01AUG98-16A 1SA/1ML INST. ID: F16
Analyst: DAT Instrument Id: F16 Analyzed: 09/02/98 16:29
Compounds with amounts less than 0.20 reported as NOT FOUND
Library Units: UG/ML
No Entry Name Mass Meth
1 S1# 1 C130 1,4-DICHLOROBENZENE 152 A BB
2 S2# 1 CI40 NAPHTHALENE -08 136 A BB
3 S3# 1 CI50 ACENAPHTHENE-D10 164 A BB
4 S4# 1 C160 PHENANTHRENE-D10 188 A BB
5 S5# 1 CI70 CHRYSENE-D12 240 A BB
6 S6# 1 CI75 PERYLENE-D12 264 A BB
7 S2# 2 CS20 NITROBENZENE-05 82 A BB
8 S3# 3 CS25 2-FLUOROB1PHENYL 172 A BB
9 S5# 2 CS30 TERPHENYL-D14 244 A BB
10 S1# 3 CS45 PHENOL-D5 99 A BB
11 S1# 2 CS50 2-FLUOROPHENOL 112 A BB
12 S3# 2 CS55 2,4,6-TRIBROMOPHENO 330 A BB
13 S1# 5 CS70 2-CHLOROPHENOL-D4 132
14 S1# 6 CS75 1.2-DICHLOROBNZN-D4 152
15 S4# 4 HEXACHLOROBENZENE-C13 294
16 SDK 15 C310 N-NITROSODIMETHYLAM 74
17 S1# 20 PYRIDINE 79
18 S1# 30 2-PICOLINE 93
19 S1# 40 N-NITROSOMETHYLETHYLAMIN 42
20 S1# 60 METHYLMETHANESULFONATE 80
21 S1# 70 N-NITROSODIETHYLAMINE 102
22 S1# 85 ETHYLMETHANE SULFONATE 79
23 S1# 95 PENTACHLOROETHANE 117
24 S1#100 C320 ANILINE 93
25 S1#105 C315 PHENOL 94
26 S1#110 C325 BIS(2-CHLOROETHYL)E 93
27 S1#1 15 C330 2-CHLOROPHENOL 128
28 S1KM25 C335 1,3-DICHLOROBENZENE 146
29 S1#130 C340 1,4-DICHLOROBENZENE 146
30 S1#145 C345 BENZYL ALCOHOL 108
31 S1#150 C350 1,2-DICHLOROBENZENE 146
32 S1#160 C355 2-METHYLPHENOL 108
33 S1#165 C360 2,2'-OXYB.lS(1-CLPRO 45
34 S1#170 C361 ACETOPHENONE 105
35 S1#175 N-N1TROSOPYRROLIDINE 100
36 S1#180 N-NITROSOMORPHOLINE 56
37 S1#182 3-METHYL PHENOL 108
38 SUM85 C365 4-METHYLPHENOL 108
39 S1#190 C370 N-NITROSO-DI-N-PROP 70
40 SHIM95 0-TOLUIDINE 106
41 S1#200 C375 HEXACHLOROETHANE 117
42 S2# 10 C410 NITROBENZENE 77
43 S2# 15 N-N1TROSOPIPERIDINE 42
44 S2# 20 C415 ISOPHORONE 82
45 S2# 25 C420 2-NITROPHENOL 139
Scan Ref Area RRF(L)
340 1 24026. 1.000
530 2 80168. 1.000
828 3 46995. 1.000
1086 4 81567. 1.000
1552 5 76304. 1.000
1783 6 67873. 1.000
422 2 25918. 0.470
723 3 37757. 1.234
1384 5 71990. 0.995
308 1 20583. 2.025
197 1 29385. 1.368
968 3 20063. 0.236
1 NOT FOUND
1 NOT FOUND
4 NOT FOUND
1 NOT FOUND
1 NOT FOUND
1 NOT FOUND
1 NOT FOUND
1 NOT FOUND
1 NOT FOUND
1 NOT FOUND
1 NOT FOUND
1 NOT FOUND
1 NOT FOUND
1 NOT FOUND
1 NOT FOUND
1 NOT FOUND
1 NOT FOUND
1 NOT FOUND
1 NOT FOUND
1 NOT FOUND
1 NOT FOUND
1 NOT FOUND
1 NOT FOUND
1 NOT FOUND
1 NOT FOUND
1 NOT FOUND
1 NOT FOUND
1 NOT FOUND
1 NOT FOUND
2 NOT FOUND
2 NOT FOUND
2 NOT FOUND
2 NOT FOUND
Amount
40.000
40.000
40.000
40.000
40.000
40.000
27.541
26.037
37.920
16.918
35.755
72.466
+ *')
1 I
-------
46 S2# 30 C425 2,4-DIMETHYLPHENOL 107 2 NOT FOUND
47 S2# 35 C435 BIS(2-CHLOROETHOXY) 93 2 NOT FOUND
48 S2# 40 C440 2,4-DICHLOROPHENOL 162 2 NOT FOUND
49 S2# 45 C430 BENZOIC ACID 122 2 NOT FOUND
-------
50 S2# 50 AA-DIMETHYLPHENETHYLAM1N
51 S2# 55 C445 1,2,4-TRICHLOROBENZ
52 52* 60 C450 NAPHTHALENE
53 S2* 80 C455 4-CHLOROANALINE
54 S2# 85 2,6-DICHLOROPHENOL
55 52* 90 HEXACHLOROPROPENE
56 52* 95 C460 HEXACHLOROBUTADIENE
57 52*115 P-PHENYLENE DIAMINE
58 52*120 N-NITROSOOI-N-BUTYLAMINE
59 52*130 C465 4-CHLORO-3-METHYLPH
60 52*140 SAFROLE
61 52*145 C470 2-METHYLNAPHTHALENE
62 S3* 10 1,2,4,5-TETRACHLOROBENZE
63 S3* 15 ISOSAFROLE (#1)
64 S3* 20 C510 HEXACHLOROCYCLOPENT
65 S3* 25 C515 2,4,6-TRICHLOROPHEN
66 S3* 30 C520 2,4,5-TRICHLOROPHEN
67 S3* 35 ISOSAFROLE (#2)
68 S3* 40 C525 2-CHLORONAPHTHALENE
69 S3* 42 1-CHLORONAPHTHALEN
70 S3* 45 C530 2-NITROANALINE
71 S3* 50 1,4-NAPHTHOQUINONE
72 S3* 55 C535 OIMETHYLPHTHALATE
73 S3* 60 1,3-DINITROBENZENE
74 S3* 65 C540 ACENAPHTHYLENE
75 S3* 70 C543 2,6-DINITROTOLUENE
76 S3* 75 C545 3-NITROANILINE
77 S3* 80 C550 ACENAPHTHENE
78 S3* 85 C555 2,4-OINITROPHENOL
79 S3* 90 C565 DIBENZOFURAN
80 S3* 95 C560 4-NITROPHENOL
81 53*100 PENTACHLOROBENZENE
82 53*105 C570 2,4-DINITROTOLUENE
83 53*110 1-NAPHTHYLAMINE
84 53*115 2-NAPHTHYLAMINE
85 S3#120 2,3,4,6-TETRACHLOROPHENO
86 S3#130 C580 DIETHYLPHTHALATE
87 53*135 C590 FLUORENE
88 S3#140 C585 4-CHLOROPHENYL-PHEN
89 S3#145 5-NITRO-O-TOLUIDINE
90 53*150 C595 4-NITROANALINE
91 54* 10 C610 4.6-DINITRO-2-METHY
92 54* 15 C615 N-NITROSOOIPHENYLAM
93 54* 20 C620 AZOBENZENE
94 54* 25 SYH-TRINITROBENZENE
95 S4# 30 C625 4-BROMOPHENYL-PHENY
96 S4# 35 PHENACETIN
97 S4# 37 DIALLATE
98 S4# 40 C630 HEXACHLOROBENZENE
99 S4# 45 4-AMINOBIPHENYL
100 S4# 50 C635 PENTACHLOROPHENOL
101 S4# 55 PRONAM1DE
102 S4# 60 PENTACHLORONITROBENZENE
103 54* 65 C640 PHENANTHRENE
104 S4# 70 C645 ANTHRACENE
105 S4# 75 2SECBUTYL-4.6-DINITROPHE
106 S4* 80 C647 CARBAZOLE
;07 S4# 85 C650 OI-N-BUTYLPHTHALATE
108 S4#100 4-NITROQUINOLINE-1-OXIDE
109 54*105 METHAPYRILENE
110 54*106 ISOORIN
N 58
Z 180
128
127
162
213
E 225
108
E 84
H 107
162
E 142
E 214
162
r 237
1 196
J 196
104
:. 162
1 162
65
158
163
168
152
165
138
153
184
168
109
250
165
143
143
232
149
166
204
152
138
198
169
77
75
248
108
234
284
169
266
173
237
178
178
211
167
149 A BB
190
58
193
2 NOT FOUND
2 NOT FOUND
2 NOT FOUND
2 NOT FOUND
2 NOT FOUND
2 NOT FOUND
2 NOT FOUND
2 NOT FOUND
2 NOT FOUND
2 NOT FOUND
2 NOT FOUND
2 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
4 NOT FOUND
4 NOT FOUND
4 NOT FOUND
4 NOT FOUND
4 NOT FOUND
4 NOT FOUND
4 NOT FOUND
4 NOT FOUND
4 NOT FOUND
4 NOT FOUND
4 NOT FOUND
4 NOT FOUND
4 NOT FOUND
4 NOT FOUND
4 NOT FOUND
4 NOT FOUND
1227 4 732
4 NOT FOUND
4 NOT FOUND
4 NOT FOUND
1.247 0.288
tr
-------
111 S4#110 C655 FLUORANTHENE 202
112 S4#120 CHLOROBENZILATE 139
113 S5# 10 C710 BENZIDINE 184
114 S5# 15 C715 PYRENE 202
115 S5# 20 ARAMITE (#1) 185
116 S5# 25 ARAMITE (#2) 185
117 S5# 30 P-DIMETHYLAMINOAZOBENZEN 120
118 S5# 35 3,3'-DIMETHYLBENZIDINE 212
119 S5# 37 KEPONE 272
120 S5# 40 C720 BUTYLBENZYLPHTHALAT 149
121 S5# 45 2-ACETYLAMINOFLUORENE 181
122 S5# 50 C730 BENZO(A)ANTHRACENE 228
123 S5# 55 C725 3,3'-DICHLOROBENZID 252
124 S5# 60 C740 CHRYSENE 228
125 S5# 65 C745 BIS(2-ETHYLHEXYL)PH 149 A
126 S5# 85 3-METHYLCHOLANTHRENE 268
127 S6# 10 C760 DI-N-OCTYL PHTHALAT 149
128 S6# 15 C765 BENZO(B)FLUORANTHEN 252
129 S6# 20 7,12-OIMETHYLBENZANTHRAC 256
130 S6# 25 C770 BENZOOOFLUORANTHEN 252
131 S6# 30 HEXACHLOROPHENE 196
132 S6# 35 C775 BENZO(A)PYRENE 252
133 S6# 55 C780 INDENO(1,2,3-CD)PYR 276
134 S6# 60 C785 DIBENZ(A,H)ANTHRACE 278
135 S6# 65 C790 BENZOCG.H,I)PERYLEN 276
BB
4
4
5
5
5
5
5
5
5
5
5
5
5
5
1604
5
6
6
6
6
6
6
6
6
6
NOT FOUND
NOT FOUND
NOT FOUND
NOT FOUND
NOT FOUND
NOT FOUND
NOT FOUND
NOT FOUND
NOT FOUND
NOT FOUND
NOT FOUND
NOT FOUND
NOT FOUND
NOT FOUND
5 738.
NOT FOUND
NOT FOUND
NOT FOUND
NOT FOUND
NOT FOUND
NOT FOUND
NOT FOUND
NOT FOUND
NOT FOUND
NOT FOUND
0.980
0.395
-------
BNA, S LIBRARIES ANALYST: DATE:
QUANTERRA Internal Standard Check
Standard Filename: ST16980902 Analyzed: 09/02/98 14:53
I IS# 1 I IS# 2 | IS# 3 |
Standard | Area X | RT j Area X | RT j Area X | RT j
ST16980902 | 23319. | 3.78 | 79260. | 5.91 | 43605. | 9.22 |
Upper Limit j 46638.=+200| 4.28 j 158519.=+200| 6.41 ( 87211.=+200| 9.72 j
Lower Limit j 11659.=+ 50| 3.28 | 39630.=+ 50J 5.41 ( 21803.=+ 50| 8.72 j
Filename | | | | | | |
=========:====s:===s======s:s:==========================================:============
I II II II
1 300681MBSFI| 24026.= 103( 3.78 | 80168.= 101| 5.90 | 46995.= 107| 9.21 |
IS# 1 = CI30 1.4-DICHLOROBENZENE-D4
IS# 2 = CI40 NAPHTHALENE-08
IS# 3 = CI50 ACENAPHTHENE-D10
* - indicates an I.S. is outside QC limit(s)
| IS# 4 | IS# 5 | IS# 6 |
Standard | Area X | RT j Area X | RT | Area X | RT j
ST16980902 | 76218. (12.09 | 51424. |17.27 | 44306. (19.84 |
Upper Limit | 152436. =+200 [12.59 | 102848. =+200 (17. 77 j 88612. =+200(20. 34 j
Lower Limit j 38109.=+ 50(11.59 j 25712.=+ 50(16.77 j 22153.=+ 50(19.34 j
Filename | | | |
1 300681MBSFI| 81567.= 107(12.08 | 76304.= 148(17.26 | 67873.= 153(19.83
1S# 4 = C160 PHEMANTHRENE-D10
IS* 5 = CI70 CHRYSENE-D12
IS# 6 = CITS PERYLENE-D12
* - indicates an I.S. is outside QC limit(s)
1"
-I \
-------
Data Reduced by: Date: Data File: 300681MBSFI
Data Reviewed by: Date:
QUANTERRA GC/MS TIC REPORT ( Part 1 )
Sample: SBLKSF 01AUG98-16A 1SA/1ML INST. ID: F16
Analyst: DAT Date Analyzed: 09/02/98 16:29
Run Factor: 1.00
Concentration
in Sample
# SCAN (UG/A) CAS #
1 486 4.5 541-02-6
CYCLOPENTASILOXANE, DECAMETHYL-
2 665 6.0 540-97-6
CYCLOHEXASILOXANE, DOOECAMETHYL-
-------
DATA FILE: 300681MBSFI
QUANTERRA GC/MS TIC REPORT ( Part 2 )
CONCENTRATION = AREA(TIC)*CONC(IS)/AREA(IS)
AMOUNT
INT. AS ANALYZED
# FIT PURITY STD. RT RRT AREA HEIGHT (UG/ML ) LIB LIB #
1 945 872 1 5:24 0.917 19664. 7045. 4.476 MB 51262.
2 901 836 1 7:23 1.255 26330. 9065. 5.993 NB 56707.
, — f
17 £i
-------
Library Search Data: 300681MBSFI # 486 Base m/z: 73
09/02/98 16:29:00 + 5:24 Call: 300681HBSFI # 3 RIC: 6464.
Sample: SBLKSF 01AUG98-16A 1SA/1ML 1NST. ID: F16
Conds.: UG/ML *1ML *100%/100% *(NA/NA )/1SA NA M
Enhanced (S 15B 2N OT)
S2231 spectra in LIBRARYNB searched for maximum PURITY
530 matched at least 3 of the 16 largest peaks in the unknown
tank In. Name
I 51262 CYCLOPENTASILOXANE, DECAMETHYL-
! 51292 BENZOIC ACID, 2,6-BIS[(TRIMETHYLSILYL)OXY]-, TRIMETHYLSILYL ESTER
i 55755 3,4-DlHYDROXYMANDELIC ACID, ETHYL ESTER, TRI-TMS
. 51291 BENZOIC ACID, 2,5-BIS(TRIMETHYLSILOXY)-, TRIMETHYLSILYL ESTER
• 60158 N-(TRIFLUOROACETYL)-N,0,0',0"-TETRAKIS(TRIMETHYLSILYL)NOREPINEPHRI*
. 58322 N-(TRIFLUOROACETYL)-0,0',0"-TRIS(TRIMETHYLSILYL)NOREPINEPHRINE
58803 N-(TRIFLUORACETYL)-0,0',0"-TRIS(TRIMETHYLSILYL)EPINEPHRINE
60335 BENZENEETHANAMINE, N-[(PENTAFLUOROPHENYL)METHYLENE]-.BETA.,3,4-TRIS*
49864 3,4-DIHYDROXYBENZYL ALCOHOL,TRIS(TRIMETHYLSILYL)-
ank Formula
C10.H30.05.SI5
C16.H30.04.SI3
C19.H36.05.SI3
C16.H30.04.SI3
C22.H42.04.N.F3.SI4
C19.H34.04.N.F3.SI3
C20.H36.04.N.F3.SI3
C24.H34.03.N.F5.SI3
C16.H32.03.SI3
M.Wt B.Pk Purity Fit RFit
370
370
428
370
553
481
495
563
356
73
73
355
355
73
73
73
355
73
872
664
596
592
589
577
561
558
549
945
775
677
665
749
711
710
699
792
891
728
660
660
621
628
616
607
601
ink
Ret.Time
B.P.Int.
US.Par.1
US.Par.2
C.A.S. #
541-02-6
3782-85-2
3618-20-0
55429-13-5
68595-79-9
-------
MID LIBRARY SEARCH (LIBRARYNB)
09/02/98 16:29:00 + 5:24
SAMPLE: SBLKSF 01AUG98-16A 1SA/1ML
CONDS.: UG/ML *1ML *100Z/1007. */15A
ENHANCED
INST.
NA M
DATA: 300681MBSFI # 486
CALI: 300681MBSFI # 3
ID: F16
BASE M/Z: 73
RIC: 6464.
1000 1
SAMPLE
C10.H30.0!
1000 i
M WT 370
B PK 73
RANK 1
# 51262
PUR 872
C16.H30.O
1000 1
M WT 370
B PK 73
RANK 2
tt 51292
PUR 664
C19.H36.0!
1000 1
M WT 428
B PK 355
RANK 3
# 55755 '
PUR 596
M/Z
1 '
5. 515
t.SI3
5. 513
t M , • >( • —r-i
58
-
CYCLOPENTASILOXANE, DECAMETHYL-
BENZOIC ACID, 2,6-BISC
-------
Library Search Data: 300681MBSFI # 665 Base m/z:
09/02/98 16:29:00 + 7:24 Cali: 300681MBSFI # 3 RIC:
Sample: SBLKSF 01AUG98-16A 1SA/1ML INST. ID: F16
Conds.: UG/ML *1ML *100%/100% *(NA/NA )/1SA NA M
Enhanced (S 158 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
425 matched at least 3 of the 16 largest peaks in the unknown
73
8352.
Rank In. Name
1 56707 CYCLOHEXASILOXANE. DODECAMETHYL-
59692 1,1,1,5,7,7.7-HEPTAMETHYL-3,3.5-TRIS(TRIMETHYLSILOXY)TETRASILOXANE
58659 1,1,1f3,5.7,9,11,11,11-DECAMETHYL-5-(TRIMETHYLSILOXY)HEXASILOXANE
58080 3,3,5-TRIETHOXY-1,1,1,7.7,7-HEXAMETHYL-5-(TRlMETHYLSILYLOXY)TETRASI*
48333 2H-1,4-BENZOOlAZEPIN-2-ONE, 7-CHLORO-1,3-DIHYDRO-5-PHENYL-1-(TRIHET*
6 56710 1,1,1,5,7,7,7-HEPTAMETHYL-3,3-BIS(TRIMETHYLSILOXY)TETRASILOXANE
7 49835 ACETIC ACID, [BIS[(TRIMETHYLSILYL)OXY]PHOSPHINYL]-. TRIHETHYLSILYL *
3 60248 3,3,5-TRIBUTOXY-1,1.1,7,7,7-HEXAMETHYL-5-(TRIMETHYLSILOXY)TETRASILO*
9 48319 1,3,5-TRIS(TRJHETHYLSILOXY)BENZENE
Rank
1
ank
Formula
C12.H36.06.SI6
C16.H48.06.SI7
C13.H42.06.S17
C15.H42.07.SI5
C18.H19.0.N2.CL.SI
C13.H40.05.SI6
C11.H29.05.P.SI3
C21.H54.07.SI5
C15.H30.03.SI3
M.wt B.Pk Purity Fit RFit
444
532
490
474
342
444
356
558
342
73
73
73
73
73
73
341
73
342
836
546
471
458
447
430
418
399
372
901
721
678
569
776
588
569
505
540
855
729
650
614
517
600
660
590
435
Ret.Time
B.P.Int.
US.Par.1 US.Par.2
C.A.S. #
540-97-6
34915-06-5
50694-26-3
55299-24-6
38147-00-1
53044-27-2
72439-86-2
10586-12-6
:£**
-------
MID LIBRARY SEARCH CLIBRARYNB)
09/02/98 16:29:00 + 7:24
SAMPLE: SBLKSF 01AUG98-16A 1SA/1ML
CONDS.: UG/ML *1ML *100Z/1007. *
INST.
NA M
DATA: 300681MBSFI # 665
CALI: 300681MBSFI # 3
ID: F16
BASE M/2: 73
RIC: 8352.
1000 •
SAMPLE
C12.H36.0
1000 1
M WT 444
B PK 73
RANK 1
# 56707
PUR 836
C16.H48.0<
1000 -I
M WT 532
B PK 73
RANK 2
# 59692
PUR 546
C13.H42.0*
1000 I
M WT 490
B PK 73
RANK 3
# 58659
PUR 471
M/Z
i
B.SI6 CYCLOHEXASILOXANE, DODECAMETHYL-
1. . . L. I L
3. SI7 1,1,1,5,7,7, 7-HEPTAMETHYL-3, 3, 5-TRIS I i 1 ' 1 I (
5.SI7 1, 1,1, 3, 5, 7, 9, 1 1,1 1,11 -DECAMETHYL-5-
-------
TIC SELECTION REPORT
DATA FILE: 300681MBSFI
THE FOLLOWING PEAKS WERE REJECTED BECAUSE
AT LEAST 40 % OF THEIR SIZE WAS ACCOUNTED FOR BY
TARGET COMPOUNDS ELUTING WITHIN 4 SCANS OF THE
PEAK TOP.
SCAN SIZE AMOUNT
197
308
340
422
530
723
828
969
1086
1384
1384
1552
1784
98212.
55052.
149548.
65244 .
175738.
113212.
226798.
163679.
216033.
260393.
260393.
233390 .
229389.
22.354
12.530
34.039
14.850
40.000
19.967
40.000
30.306
40.000
44.628
44.628
40.000
40.000
TOTAL NUMBER OF UNIDENTIFIED PEAKS WITH SIZE
GREATER THAN 10 X OF THE CLOSEST INTERNAL STANDARD
THAT DOES NOT HAVE INTERFERENCES = 2
INTERNAL STANDARDS THAT HAVE RIC SIZE LESS THAN
50 % OR GREATER THAN 200 % OF THE ESTIMATED RIC SIZE
ARE CONSIDERED TO HAVE INTERFERENCES AND WILL NOT BE USED
FOR QUANT I TAT ION.
PERCENT OF
ESTIMATED
# INTERNAL STANDARD RIC SIZE RIC SIZE SCAN
===sss========s=====ssss=ssss==s==s===s=======================
1 CI40 NAPHTHALENE-08 175738. 137 530
2 CI50 ACENAPHTHENE-D10 226798. 134 828
3 CI60 PHENANTHRENE-D10 216033. 116 1086
4 CI70 CHRYSENE-D12 233390. 124 1552
5 C175 PERYLENE-D12 229389. 126 1784
* INDICATES INTERFERENCE
SIZE = AREA
-*-/*:,&
-------
laboratorj/Dujilicfiie Control Si
1
JL
-------
DUPLICATE CONTROL SAMPLE REPORT
Semi volatile Organics by GC/MS
Project: 300681
Category: 8270-G Acid, Base and Neutrals by GC/MS.
Testcode: 8270-TCL-G Method: 0010/8270
Matrix: FILTER Concentration Units: ug/sample
QC Lot: 31 JUL 98-16A Analyzed Date: 31 AUG 98 Time: 18:30
Analyte
Phenol
2-Chlorophenol
1,4-Dichlorobenzene
N-Nitroso-di-
n-propylamine
1,2,4-
Trichlorobenzene
l-Chloro-3-
methylphenol
!\cenaphtnene
l-Nitrophenol
>,4-Dinitrotoluene
3entachlorophenol
3yrene
Surrogate
^itrobenzene-d5
'.-Fluorobiphenyl
Ferphenyl-dl4
'henol-d5
!-Fluorophenol
!,4,6-Tri bromophenol
Spiked
100
100
50.0
50.0
50.0
100
50.0
100
50.0
100
50.0
Spiked
50
50
50
100
100
100
•-uunueriLr at IUM
DCS1 DCS2
83.4 87.9
83.7 87.9
43.4 44.9
38.3 40.9
43.1 45.9
78.6 85.8
46.6 50.2
78.8 89.6
45.3 49.0
83.4 93.6
48.0 50.7
DCS1 DCS2
40 40
45 46
40 40
80 81
77 74
84 84
Accuracy
V
DCS1
83
84
87
77
86
79
93
79
91
83
96
°i
DCS2
88
88
90
82
92
86
100
90
98
94
101
Accuracy(%)
DCS1 DCS2
Precision
(RPD)
Limits DCS Limit
47-108
47-113
42-114
46-107
45-118
55-118
54-119
43-166
59-113
59-128
45-140
Limits
79
90
79
80
77
84
79
92
80
81
74
84
45-107
62-110
58-135
43-130
36-111
58-131
5.3 18
4.9 20
3.4 22
6.6 15
6.3 16
8.8
7.4
13
7.8
12
5.5
13
10
17
10
10
11
ote *: Outside of RPD limits.
alculations are performed before rounding to avoid round-off errors in calculated results.
172
-------
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-------
DATA FROM FILE: 300681MBXMS SCANS 230 TO 1200 ACQUIRED: 08/31/98 18:00:00
CALI: 300681MBXMS #3
SAMPLE: DCS-A 31JUL98-16A 1/3SA/1ML INST. ID: F16
CONDS.: UG/ML *1ML *100Z/100Z *
-------
DATA FROM FILE: 300681MBXMS SCANS 1200 TO 2158 ACQUIRED: 08/31/98 18:00:00
CALI: 300681MBXMS #3
SAMPLE: DCS-A 3UUL98-16A 1/3SA/1ML INST. ID: F16
CONDS.: UG/ML *1ML *100Z/1002 */l/3SA NA M
1200 .
13:21
1400 .
15:34
1600 .
17:48
1806 _V
20:01
2000 _
22:15
100.0Z < 99584.)
•SS30 TERPHENYL-D14
244SS5* 02
1718-51-0
CI70 CHRYSENE-D12
240IS5# 01
1719-03-5
CI75 PERYLENE-D12
164IS64* 01
1520-96-3
Ur-i-
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-------
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-------
BNA, S LIBRARIES ANALYST:
QUANTERRA Internal Standard Check
Standard Filename: ST16980831
DATE:
Analyzed: 08/31/98 12:31
IS# 1 | IS# 2 | IS# 3 |
Standard Area X | RT | Area X | RT | Area X | RT j
ST16980831 28649. | 3.78 | 100432. | 5.90 | 54347. | 9.21 |
Upper Limit 57297.=+200| 4.28 | 200864.=+200j 6.40 j 108695.=+200| 9.71 j
Lower Limit 14324.=+ 50| 3.28 | 50216.=+ 50| 5.40 | 27174.=+ 50| 8.71 |
Filename | | | | | | |
===s==sss====—===ss—s==ss==s:s=ss==s==s:ss===ssss==—==!s=sssssss:sss=ssss=sssss==sss=a
I II II II
1 300681MSXMS| 27622.= 96| 3.78 | 96564.= 96| 5.88 | 53847.= 99) 9.21 |
I II II II
IS# 1 = CI30 1,4-DICHLOROBENZENE-D4
IS# 2 = CI40 NAPHTHALENE-OS
IS# 3 = CI50 ACENAPHTHENE-D10
* - indicates an I.S. is outside QC limit(s)
IS# 4 | 1S# 5 | IS# 6 |
Standard Area X | RT j Area X | RT j Area X | RT j
ST16980831 98520. |12.08 | 62289. |17.26 | 50750. |19.83 |
Upper Limit 197039.=+200|12.58 j 124578.=+200|17.76 | 101500.=+200|20.33 |
Lower Limit 49260.=+ 50J11.58 j 31145.=+ 50J16.76 j 25375.=+ 50J19.33 j
Filename | | | | | | |
I II I I II
1 300681MBXMS| 91222.= 92|12.08 | 71648.= 115|17.25 | 59838.= 117|19.83 |
IS# 4 = CI60 PHENANTHRENE-D10
tS# 5 = CI70 CHRYSENE-012
IS# 6 = CITS PERYLENE-D12
* - indicates an I.S. is outside QC limit(s)
-------
QUANTERRA GC/MS
Target Compound Data Summary Sheet
Data File: 300681MBXDS
Std Id: ST16980831
ample: DCS-AD 31JUL98-16A 1/3SA/1ML INST. ID: F16
lient: PACIFI Date Analyzed: 08/31/98 18:30
-latyst: OAT Instrument ID: F16 Run Factor: 3.00
jan List Threshold: 0.95 Surrogate Vol.: 1.00
Surrogate Spike Recoveries
8270-G, L1MS 10/10/96
Surrogate
Surrogate Amount (ug)
Spi Iced Measured
X Recovery
Measured QC limits
S20 NITROBENZENE-DS
S25 2-FLUOROBIPHENY
S30 TERPHENYL-D14
S45 PHENOL -05
S50 2- FLUOROPHENOL
S55 2,4,6-TRIBROMOP
50.00
50.00
50.00
100.0
100.0
100.0
39.50
46.00
40.20
80.60
74.20
83.90
79.0
92.0
80.4
80.6
74.2
83.9
45 107
62 110
58 135
43 130
36 111
58 131
Parameter
Target Compounds: MS
Scan
Result
Units
Reporting
Limit (J values)
S70 2-CHLOROPHENOL-D4
:S75 1.2-DICHLOROBNZN-D4
315 PHENOL
:330 2-CHLOROPHENOL
340 1,4-DICHLOROBENZENE
1370 N-NITROSO-DI-N-PROPYLAM
)445 1,2,4-TRICHLOROBENZENE
:465 4-CHLORO-3-METHYLPHENO
:550 ACENAPHTHENE
:560 4-NITROPHENOL
.'570 2,4-DINITROTOLUENE
:635 PENTACHLOROPHENOL
:715 PYRENE
340
309
314
343
408
524
649
834
885
878
1061
1334
NO
130
260
260
130
120
140
260
150
270
150
280
150
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
150.0
30.0
150.0
30.0
Reviewed by:
-------
DATA FROM FILE: 300681MBXDS SCANS 230 TO 1200 ACQUIRED: 08/31/98 18:30:00
CALI: 300681MBXDS #3
SAMPLE: DCS-AD 31JUL98-16A 1/3SA/1ML INST. ID: F16
CONDS.: UG/ML *1ML *100Z/100Z *
-------
DATA FROM FILE: 300681MBXDS SCANS 1200 TO 2158 ACQUIRED: 08/31/98 18:30:00
CALI: 30068IMBXDS »3
SAMPLE: DCS-AD 31JUL98-16A 1/3SA/1ML INST. ID: F16
CONDS.: UG/ML *1ML *100Z/1007Z */l/3SA NA M
1200 .
13:21
j
1400 J
15:34
100.07. < 104576.)
CS30 TERPHENYL-D14
244SS5* 02
1718-51-0
1600 -H
17:48
1800 _
20:01
;i70 CHRYSENE-D12
240IS5* 01
1719-03-5
CI75 PERYLENE-D12
164IS64* 01
1520-96-3
2000
22:15
-------
STANDARD USED FOR THIS REPORT IS ST16980831 REPORT PRIMTED: 9/01/98 11:29:21
ADDITIONAL STANDARD USED FOR THIS REPORT IS: ST16980831A
QUANTERRA QUANT ITAT ION SUMMARY
Sample: DCS-AD 31JUL98-16A 1/3SA/1ML
Analyst: DAT Instrument Id: F16
File: 300681MBXDS
INST. ID: F16
Analyzed: 08/31/98 18:30
Compounds with amounts less than 0.20 reported as NOT FOUND
Library
No
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
Entry
S1# 1
S2# 1
S3# 1
S4# 1
S5# 1
S6# 1
S2# 2
S3# 3
S5# 2
S1# 3
S1# 2
S3# 2
SDK 5
S1# 6
S1#105
51*115
S1#130
S1IM 90
S2# 55
S2#130
S3# 80
S3# 95
S3#105
S4# 50
S5# 15
Name Mass
CI30
C140
C150
CI60
CI70
CI75
CS20
CS25
CS30
CS45
CS50
CS55
CS70
CS75
C315
C330
C340
C370
C445
C465
C550
C560
C570
C635
C715
1,4-DICHLOROBENZENE
NAPHTHALENE-OS
ACENAPHTHENE-D10
PHENANTHRENE-D10
CHRYSENE-D12
PERYLENE-D12
NITROBENZENE-D5
2-FLUOROBIPHENYL
TERPHENYL-D14
PHENOL-D5
2-FLUOROPHENOL
2,4,6-TRIBROMOPHENO
2-CHLOROPHENOL-D4
1.2-DICHLOROBN2N-D4
PHENOL
2-CHLOROPHENOL
1,4-D1CHLOROBEN2ENE
N-NITROSO-DI-N-PROP
1,2,4-TRICHLOROBENZ
4-CHLORO-3-METHYLPH
ACENAPHTHENE
4-NITROPHENOL
2,4-DINITROTOLUENE
PENTACHLOROPHENOL
PYRENE
152
136
164
188
240
264
82
172
244
99
112
330
132
152
94
128
146
70
180
107
153
109
165
266
202
Meth
A
A
A
A
A
A
A
A
A
A
A
A
BB
BB
BB
BB
BB
BB
BB
BB
BB
BB
BB
BB
Scan
340
530
828
1086
1551
1783
422
723
1384
307
196
968
Ref Area
1
2
3
4
5
6
2
3
5
1
1
3
1 NOT
A
A
A
A
A
A
A
A
A
A
A
A
BB
BB
BB
BB
BB
BB
BB
BB
BB
BB
BB
BB
340
309
314
343
408
524
649
834
885
878
1061
1334
1
1
1
1
1
2
2
3
3
3
4
5
27374.
96718.
53018.
87510.
72710.
60866.
44793.
75190.
72644.
111689.
69505.
26207.
FOUND
27374.
118368.
90015.
49710.
25370.
36709.
70056.
77035.
20493.
25792.
31741.
121860.
Units: UG/ML
RRF(L)
1.000
1.000
1.000
1.000
1.000
1.000
0.470
1.234
0.995
2.025
1.368
0.236
0.920
1.968
1.497
1.617
0.906
0.331
0.338
1.159
0.173
0.397
0.155
1.323
Amount
40.000
40.000
40.000
40.000
40.000
40.000
39.452
45.960
40.156
80.575
74.230
83.902
43.476
87.896
87.873
44.908
40.924
45.877
85.785
50.163
89.552
48.986
93.581
50.688
-------
SNA, S LIBRARIES ANALYST: DATE:
OUANTERRA Internal Standard Check
Standard Filename: ST16980831 Analyzed: 08/31/98 12:31
| IS# 1 | IS# 2 | IS* 3 |
Standard | Area % | RT | Area % | RT | Area X | RT j
ST16980831 | 28649. | 3.78 | 100432. | 5.90 | 54347. | 9.21 |
Upper Limit | 57297.=+200| 4.28 j 200864.=+200j 6.40 j 108695.=+200| 9.71 |
Lower Limit | 14324.=+ 50) 3.28 j 50216.=+ 50| 5.40 j 27174.=+ 50) 8.71 |
Filename | | | | | | |
I II II II
1 300681MBXDS| 27374.= 95| 3.78 | 96718.= 96| 5.90 | 53018.= 97| 9.21 |
I II II II
IS# 1 = CI30 1.4-DICHLOROBENZENE-D4
IS# 2 = C140 NAPHTHALENE-08
IS# 3 = CI50 ACENAPHTHENE-D10
* - indicates an I.S. is outside QC limit(s)
| IS# 4 | IS# 5 | IS# 6 |
Standard j Area % | RT j Area % | RT j Area X j RT j
ST16980831 | 98520. |12.08 | 62289. |17.26 | 50750. |19.83 |
Upper Limit j 197039.=+200)12.58 | 124578.=+200)17.76 | 101500.=+200)20.33 j
Lower Limit j 49260.=+ 50(11.58 | 31145.=+ 50)16.76 | 25375.=+ 50)19.33 |
FUename
I II II I
1 300681MBXDS) 87510.= 88(12.08 | 72710.= 116(17.25 | 60866.= 119)19.83
IS* 4 = CI60 PHENANTHRENE-010
IS# 5 = CI70 CHRYSENE-D12
IS# 6 = CI75 PERYLENE-012
* - indicates an I.S. is outside QC limit(s)
»-i o "•
I 00
-------
QC Lot ft: 01AUG98-16A Units: UG/A
QUANTERRA DCS
QC CATEGORY: 8270-G, LIMS 10/10/96
Calibration
Data File Run Factor Surr Factor Standard
Spike: 300681BFMSI 1.00 1.00 RF from Lib
Spike Dup.: 300681BFDSI 1.00 1.00 RF from Lib
Compound Spike Amount LCS1 % RPD
Limits Amount Amount LCS2 % Limit
C315 PHENOL 100. 27.2 27.2* 4.16
47-108 100. 26.0 26.0* 18
C330 2-CHLOROPHENOL 100. 64.9 64.9 0.129
47-113 100. 65.0 65.0 20
C340 1,4-DICHLOROBENZENE 50.0 27.3 54.7 6.96
42-114 50.0 29.3 58.6 22
C370 N-NITROSO-DI-N-PROP 50.0 35.6 71.1 11.1
46-107 50.0 31.8 63.6 15
C445 1,2,4-TRICHLOROBENZ 50.0 27.7 55.4 7.59
45-118 50.0 29.9 59.8 16
C465 4-CHLORO-3-METHYLPH 100. 68.9 68.9 10.0
55-118 100. 62.3 62.3 13
C550 ACENAPHTHENE 50.0 39.9 79.9 6.04
54-119 50.0 37.6 75.2 10
C560 4-NITROPHENOL 100. 20.5 20.5* 22.1
43-166 100. 16.4 16.4* 17
C570 2,4-DINITROTOLUENE 50.0 46.4 92.8 16.1
59-113 50.0 39.5 78.9 10
C635 PENTACHLOROPHENOL 100. 77.0 77.0 18.3
59-128 100. 64.1 64.1 10
C715 PYRENE 50.0 48.5 96.9 10.3
45-140 50.0 43.7 87.4 11
-------
300681BFMSI
ST16980902
QUANTERRA GC/MS
Target Compound Data Summary Sheet
Data File:
Std Id:
Sample: DCS-A 01AUG98-16A 1SA/1ML INST. ID: F16
Client: PACIFI Date Analyzed: 09/02/98 18:59
Analyst: DAT Instrument ID: F16 Run Factor: 1.00
Quan List Threshold: 0.95 Surrogate Vol.: 1.00
Surrogate
CS20 NITROBENZENE-D5
CS25 2-FLUOROBIPHENY
CS30 TERPHENYL-D14
CS45 PHENOL-D5
CS50 2-FLUOROPHENOL
CSS5 2,4,6-TRIBROMOP
Surrogate Spike Recoveries
8270-G, LIMS 10/10/96
Surrogate Amount (ug)
Spiked Measured
% Recovery
Measured QC limits
50.00
50.00
50.00
100.0
100.0
100.0
31.00
35.80
41.00
27.00
37.60
88.00
62.0
71.6
82.0
27.0
37.6
88.0
45 107
62 110
58 135
43 130
36 111
58 131
Parameter
Target Compounds : MS
Scan Result
Units
Reporting
Limit (J values)
CS70 2-CHLOROPHENOL-D4 ND
CS75 1,2-DICHLOROBNZN-D4 ND
C315 PHENOL 310 27.
C330 2-CHLOROPHENOL 314 65
C340 1,4-DICHLOROBENZENE 343 27
C370 N-NITROSO-DI-N-PROPYLAM 408 36.
C445 1,2,4-TRICHLOROBENZENE 524 28
C465 4 -CHLORO -3 -METHYLPHENO 650 69
C550 ACENAPHTHENE 834 40.
C560 4-NITROPHENOL 893 21
C570 2,4-DINITROTOLUENE 879 46
C635 PENTACHLOROPHENOL 1062 77
C715 PYRENE ~ 1335 48
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
Reviewed by:
'i *"'
JL /
-------
DATA FROM FILE: 300681BFMSI SCANS 94 TO 1284 ACQUIRED: 09/-02/-9S 18:59:00
CALI: 300681BFMSI #3
SAMPLE: DCS-A 01AUG98-16A ISA^IML INST. ID: F16
CONDS.: UG/ML *1ML *1007Z/100Z *
-------
DATA FROM FILE: 300681BFMSI SCANS 1204 TO 2158 ACQUIRED: 09x02/98 18:59:00
CALI: 300681BFMSI #3
SAMPLE: DCS-A 01AUG98-1GA 1SA/1ML INST. ID: F16
CONDS.: UG/ML *1ML *100Z/100Z *
-------
STANDARD USED FOR THIS REPORT IS ST16980902 REPORT PRINTED: 9/03/98 12:39:19
ADDITIONAL STANDARD USED FOR THIS REPORT IS: ST16980902A
QUANTERRA QUANTITATION SUMMARY File: 300681BFMSI
Sample: DCS-A
Analyst: DAT
01AUG98-16A 1SA/1ML
Instrument Id: F16
INST. ID: F16
Analyzed: 09/02/98 18:59
Compounds with amounts less than 0.20 reported as NOT FOUND
Library
No Entry Name
1 Sl# 1 CI30 1,4-DICHLOROBENZENE 152 A BB
2 S2# 1 CI40 NAPHTHALENE-OS
3 S3# 1 CI50 ACENAPHTHENE-D10
4 S4# 1 CI60 PHENANTHRENE-D10
5 S5# 1 CI70 CHRYSENE-D12
6 S6# 1 CI75 PERYLENE-D12
7 S2# 2 CS20 NITROBENZENE-D5
8 S3# 3CS25 2-FLUOROBIPHENYL
9 S5# 2 CS30 TERPHENYL-D14
10 Sl# 3 CS45 PHENOL-D5
11 Sl# 2 CS50 2-FLUOROPHENOL
12 S3# 2 CS55 2,4,6-TRIBROMOPHENO 330
13 Sl# 5 CS70 2-CHLOROPHENOL-D4
14 Sltt 6 CS75 1,2-DICHLOROBNZN-D4 152
15 Sl#105 C315 PHENOL
16 Sl#115 C330 2-CHLOROPHENOL
17 Sl#130 C340 1,4-DICHLOROBENZENE
18 Sl#190 C370 N-NITROSO-DI-N-PROP
19 S2# 55 C445 1,2,4-TRICHLOROBENZ
20 S2#130 C465 4-CHLORO-3-METHYLPH
21 S3# 80 C550 ACENAPHTHENE
22 S3# 95 C560 4-NITROPHENOL
23 S3#105 C570 2,4-DINITROTOLUENE
24 S4# 50 C635 PENTACHLOROPHENOL
25 S5# 15 C715 PYRENE
Units :
ass Meth
152
136
164
188
240
264
82
172
244
99
112
330
132
152
94
128
146
70
180
107
153
109
165
266
202
A
A
A
A
A
A
A
A
A
A
A
A
BB
BB
BB
BB
BB
BB
BB
BB
BB
BB
BB
BB
Scan Ref Area
341
530
828
1087
1552
1784
422
723
1384
308
197
969
1
2
3
4
5
6
2
3
5
1
1
3
1 NOT
1 NOT
A
A
A
A
A
A
A
A
A
A
A
BB
BB
BB
BB
BB
BB
BB
BB
BB
BB
BB
310
314
343
408
524
650
834
893
879
1062
1335
1
1
1
1
2
2
3
3
3
4
5
24660.
87031.
48399.
83148.
75605.
66009.
31682.
53531.
77124.
33750.
31682.
25098.
FOUND
FOUND
32941.
59889.
27254.
19856.
19952.
50638.
56003.
4286.
22297 .
24829.
121134.
RRF(L)
1.
1.
1.
1.
1.
1.
0.
1.
0.
2.
1.
0.
1.
1.
1.
0.
0.
0.
1.
0.
0.
0.
1.
000
000
000
000
000
000
470
234
995
025
368
236
968
497
617
906
331
338
159
173
397
155
323
UG/ML
Amount
40
40
40
40
40
40
31
35
41
27
37
88
27
64
27
35
27
68
39
20
46
77
48
.000
.000
.000
.000
.000
.000
.011
.844
.000
.028
.559
.020
.153
.898
.331
.554
.711
.909
.948
.517
.389
.041
.457
17 4 i
-------
BNA, S LIBRARIES ANALYST:
QUANTERRA Internal Standard Check
Standard Filename: ST16980902
DATE:
Analyzed: 09/02/98 14:53
IS# 1
Standard
Area
RT
I
IS# 2
IS# 3
Area
RT
Area
RT
ST16980902 |
Upper Limit |
Lower Limit |
23319
46638
11659
1
.=+200|
.=+ 50 |
3
4
3
.78
.28
.28
| 79260
| 158519
| 39630
.
.=+200
.=+ 50
5
6
5
.91
.41
.41
43605.
87211.
21803.
1
=+200 |
= + 50 |
9.22 |
9.72 |
8.72 |
Filename j
_
1 300681BFMSI| 24660.= 105
I
3.79
87031.= 109
5.90 j 48399.= 110
I
I
9.21 j
IS# 1 = CI30 1,4-DICHLOROBENZENE-D4
IS# 2 = CI40 NAPHTHALENE-D8
IS# 3 = CI50 ACENAPHTHENE-DIO
* - indicates an I.S. is outside QC limit(s)
| IS# 4
Standard j Area % | RT
IS# 5
Area % | RT
IS# 6
Area % I RT
ST16980902
Upper Limit
Lower Limit
76218.
152436. =+200
38109.=+ 50
12.09
12.59
11.59
51424.
102848. =+200
25712.=+ 50
17.27
17.77
16.77
44306.
88612. =+200
22153.=+ 50
19.84 |
20.34 |
19.34 |
Filename *[
1
1 300681BFMSIJ 83148.= 109
1
12.09
1 1
75605.= 147 17.26 | 66009.= 148
1 1
19.84
IS# 4 = CI60 PHENANTHRENE-D10
IS# 5 = CI70 CHRYSENE-D12
IS# 6 = CI75 PERYLENE-D12
* - indicates an I.S. is outside QC limit(s)
17
-------
QUANTERRA GC/MS
Target Compound Data Summary Sheet
Data File: 300681BFDSI
Std Id: ST16980902
Sample: DCS-AD 01AUG98-16A 1SA/1ML INST. ID: F16
Client: PACIFI Date Analyzed: 09/02/98 19:29
Analyst: DAT Instrument ID: F16 Run Factor: 1.00
Quan List Threshold: 0.95 Surrogate Vol.: 1.00
Surrogate
Surrogate Spike Recoveries
8270-G, LIMS 10/10/96
Surrogate Amount (ug)
Spiked Measured
% Recovery
Measured QC limits
CS20 NITROBENZENE-D5
CS25 2-FLUOROBIPHENY
CS30 TERPHENYL-D14
CS45 PHENOL-D5
CS50 2-FLUOROPHENOL
CS55 2,4,6-TRIBROMOP
50.00
50.00
50.00
100.0
100.0
100.0
30.20
33.80
36.50
26.00
38.10
74.60
60.4
67.6
73,
26,
38.1
74.6
45 107
62 110
58 135
43 130
36 111
58 131
Parameter
Target Compounds: MS
Scan Result
Units
Reporting
Limit (J values)
CS70
CS75
C315
C330
C340
C370
C445
C465
C550
C560
C570
C635
C715
2 - CHLOROPHENOL-D4
1 , 2 -DICHLOROBNZN-D4
PHENOL
2-CHLOROPHENOL
1 , 4 -DICHLOROBENZENE
N-NITROSO-DI-N-PROPYLAM
1,2,4 -TRICHLOROBENZENE
4 - CHLORO - 3 - METHYLPHENO
ACENAPHTHENE
4 -NITROPHENOL
2 , 4-DINITROTOLUENE
PENTACHLOROPHENOL
PYRENE
309
314
343
408
524
650
834
895
879
1062
1335
ND
ND
26.
65.
29.
32.
30.
62.
38.
16.
39.
64.
44.
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
50.0 J
10.0
50.0
10.0
Reviewed by:
17-^
-------
DATA FROM FILE: 300681BFDSI SCANS 94 TO 1204 ACQUIRED: 09/02/98 19:29:00
CALI: 300681BFDSI *3
SAMPLE: DCS-AD 01AUG98-16A 1SA/1ML INST. ID: F16
CONDS.: UG/ML *1ML *100Z/100Z */lSA NA M
600
6:40
1000 .
11:07
I
I
100.0Z < 92928.)
CS50 2-FLUOROPHENOL
112SSltt 02
99SS1# 03
367-12-4
4165-62-2
ei3e~l,4-DICHLOROBENZENE-D4 152ISltt 01 3855-82-1
800 _
8:54
_ fs T E
f-
TC
CS25 2-FLUOROBIPHENYL 172SS3tt 03
ACENAPHTHENE-D10
321-60-8
164IS3* 01
15067-26-2
CS55 2,4,6-TRIBROMOPHENOL 330SS3# 02
118-79-6
TC
CI60 PHENANTHRENE-D10
188154* 01
1517-22-2
H-
-------
DATA FROM FILE: 388681BFDSI SCANS 1284 TO 2158 ACQUIRED: 89/82x98 19:29:88
CALI: 380681BFDSI *3
SAMPLE: DCS-AD 81AUG98-16A 1SA/1ML INST. ID: F16
CONDS.: UG/tlL *1ML *188Z/100?Z *
-------
STANDARD USED FOR THIS REPORT IS ST16980902 REPORT PRINTED: 9/03/98 12:42:24
ADDITIONAL STANDARD USED FOR THIS REPORT IS: ST16980902A
QUANTERRA QUANTITATION SUMMARY
Sample: DCS-AD
Analyst: DAT
01AUG98-16A 1SA/1ML INST.
Instrument Id: F16
File: 300681BFDSI
ID: F16
Analyzed: 09/02/98
19:29
Compounds with amounts less than 0.20 reported as NOT FOUND
Library
No Entry Name
Units: UG/ML
Sl#
S2#
S3#
S5#
6 S6#
7 S2#
8 S3#
9 S5#
10 Sl#
11 Sl#
12 S3#
13 Sl#
14 Sltf
1 CI30 1,4-DICHLOROBENZENE 152
1 CI40 NAPHTHALENE-D8
1 CI50 ACENAPHTHENE-D10
1 CI60 PHENANTHRENE-D10
1 CI70 CHRYSENE-D12
1 CI75 PERYLENE-D12
2 CS20
3 CS25
2 CS30
3 CS45
2 CS50
2 CS55
5 CS70
6 CS75
15 SlttlOS
16 Sl#115
17 Sl#130
18 Sl#190
19 S2# 55
20 S2#130
21 S3# 80
22 S3# 95
23 S3#105
24 S4# 50
25 S5# 15
C315
C330
C340
C370
C445
C465
C550
C560
C635
C715
NITROBENZENE-DS
2 -FLUOROBIPHENYL
TERPHENYL-D14
PHENOL-D5
2-FLUOROPHENOL
2,4, 6 -TRIBROMOPHE!
2-CHLOROPHENOL-D4
1,2-DICHLOROBNZN-D4 152
PHENOL
2-CHLOROPHENOL
1,4-DICHLOROBENZENE
N-NITROSO-DI-N-PROP
1,2,4-TRICHLOROBENZ
4-CHLORO-3-METHYLPH
ACENAPHTHENE
4-NITROPHENOL
2,4-DINITROTOLUENE
PENTACHLOROPHENOL
PYRENE
lass Meth
152
136
164
188
240
264
82
172
244
99
112
330
132
152
94
128
146
70
180
107
153
109
165
266
202
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
BB
BE
BB
BB
BB
BB
BB
BB
BB
BB
BB
BB
BB
BB
BB
BB
BB
BB
BB
BB
BB
BB
BB
Scan
340
530
828
1087
1552
1784
422
723
1384
308
197
969
1
1
309
314
343
408
524
650
834
895
879
1062
1335
Ref Area
1
2
3
4
5
6
2
3
5
1
1
3
NOT
NOT
1
1
1
1
2
2
3
3
3
4
5
27115.
91722.
52118.
89087.
79298.
69584.
32551.
54422.
72015.
35704.
35344.
22909.
FOUND
FOUND
34746.
65937.
32129.
19533.
22687.
48270.
56768.
3696.
20426.
22149.
114565.
RRF (L) Amoun
1
1
1
1
1
1
0
1
0
2
1
0
1
1
1
0
0
0
1
0
0
0
1
.000
.000
.000
.000
.000
.000
.470
.234
.995
.025
.368
.236
.968
.497
.617
.906
.331
.338
.159
.173
.397
.155
.323
40
40
40
40
40
40
30
33
36
26
38
74
26
64
29
31
29
62
37
16
39
64
43
.000
.000
.000
.000
.000
.000
.232
.840
.501
.004
.106
.610
.047
.982
.302
.809
.897
.327
.604
.429
.464
.144
.694
/
o
-------
BNA, S LIBRARIES ANALYST:
QUANTERRA Internal Standard Check
Standard Filename: ST16980902
DATE:
Analyzed: 09/02/98 14:53
IS#
Standard
Area
RT
IS# 2
Area % I RT
IS# 3
Area % I RT
ST16980902 |
Upper Limit |
Lower Limit |
23319
46638
11659
.=+200
.=+ 50
3
4
3
.78
.28
.28
79260
158519
39630
.=+200
.=+ 50
5
6
5
.91
.41
.41
43605.
87211.
21803.
=+200
=+ 50
9.22
9.72
8.72
Filename |
1 300681BFDSI
27115.= 116
3.78
91722.= 115
5.90
1
52118.= 119| 9.21
1
IS# 1 = CI30 1,4-DICHLOROBENZENE-D4
IS# 2 = CI40 NAPHTHALENE-D8
IS# 3 = CI50 ACENAPHTHENE-D10
* - indicates an I.S. is outside QC limit(s)
| IS# 4 | IS# 5
Standard j Area % | RT j Area % | RT
IS# 6 |
Area % | RT j
ST16980902
Upper Limit
Lower Limit
76218.
152436. =+200
38109.=+ 50
12.09
12.59
11.59
51424.
102848. =+200
25712.=+ 50
17.27 44306.
17.77 88612. =+200
16.77 22153.=+ 50
19.84
20.34
19.34
Filename
1 1 I 1
1 300681BFDSIJ 89087.= 116J12.09 j 79298.= 154J17.26
1 1 . 1 1
69584.= 157
19.84
IS# 4 = CI60 PHENANTHRENE-D10
IStt 5 = CI70 CHRYSENE-D12
IS# 6 = CI75 PERYLENE-D12
* - indicates an I.S. is outside QC limit(s)
IV'J
-------
QUANTERRA GC/MS
Target Compound Data Summary Sheet
Data File: 300681MBFMS
Std Id: ST16980831
INST. ID: F16
Date Analyzed: 08/31/98 17:01
Run Factor: 1.00
Surrogate Vol.: 1.00
Sample: DCS-A 01AUG98-16A 1SA/1ML
Client: PACIFI
Analyst: DAT Instrument ID: F16
Quan List Threshold: 0.95
Surrogate
===s===s===
CS20 NITROBENZENE-05
CS25 2-FLUOROBIPHENY
CS30 TERPHENYL-D14
CS45 PHENOL-05
CS50 2-FLUOROPHENOL
CS55 2,4,6-TRlBROMOP
Surrogate Spike Recoveries
8270-G. LIMS 10/10/96
Surrogate Amount (ug)
Spiked Measured
50.00
50.00
50.00
100.0
100.0
100.0
31.30
35.00
41.20
28.00
38.90
83.10
X Recovery
Measured QC limits
62.6
70.0
82.4
28.0
38.9
83.1
45 107
62 110
.58 135
43 130
36 111
58 131
Parameter
Target Compounds: MS
Scan Result
Units
Reporting
Limit (J values)
:s/o
:S75
:315
330
340
370
:445
I465
:550
:560
:570
635
715
2-CHLOROPHENOL-D4
1,2-DICHLOROBNZN-D4
PHENOL
2-CHLOROPHENOL
1,4-DICHLOROBENZENE
N-NITROSO-DI-N-PROPYLAM
1 , 2 , 4 - TR I CHLOROBENZENE
4-CHLORO-3-METHYLPHENO
ACENAPHTHENE
4-NITROPHENOL
2.4-DINITROTOLUENE
PENTACHLOROPHENOL
PYRENE
340
308
313
342
408
524
649
833
887
878
1061
1334
ND
43.
29.
66.
28.
37.
28.
71.
40.
27.
44.
89.
49.
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
50.0 J
10.0
50.0
. 10.0
Reviewed by:
i >-'
1 I
-------
DATA FROM FILE: 380681MBFMS SCANS 230 TO 1200 ACQUIRED: 08/31/98 17:01:00
CALI: 300681MBFMS #3
SAMPLE: DCS-A 01AUG98-16A 1SA/1ML INST. ID: F16
CONDS.: UG/ML *1ML X1QQ7./1QQZ *
rrirt rnnini ng
99SS1# 03
4165-62-2
€130 1.4-DICHLOROBENZENE-D4 152IS1# 01
3855-82-1
C529 HITROBEHZENE-D5
82SS2* 02
CI40 NAPHTHALENE-OS
4165-60-0
136IS2* 01
1146-65-2
CS25 2-FLUOROBIPHENYL
172SS3* 03
ACENAPHTHENE-D10
321-60-8
164IS3# 01
15067-26-2
CS55 2,4,6-TRIBROMOPHENOL 330SS3# 02
118-79-6
CI60 PHENANTHRENE-D10
188IS4# 01
1517-22-2
-------
DATA FROM FILE: 300681MBFMS SCANS 1200 TO 2158 ACQUIRED: 08/31/-98 17:01:00
CALI: 30068IMBFMS #3
SAMPLE: DCS-A 01AUG98-16A 1SA/1ML INST. ID: F16
CONDS.: UG/ML *1ML *100?!xl00^ *
-------
STANDARD USED FOR THIS REPORT IS ST16980S31 REPORT PRINTED: 9/01/98 11:04:51
ADDITIONAL STANDARD USED FOR THIS REPORT IS: ST16980831A
OUANTERRA QUANT I TAT ION SUMMARY
File: 300681M8FMS
Sample: DCS-A 01AUG98-16A 1SA/1ML INST. 10: F16
Analyst: DAT Instrument Id: F16 Analyzed: 08/31/98 17:01
Compounds with amounts less than 0.20 reported as NOT FOUND
Library
No
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
Entry
S1# 1
S2# 1
S3# 1
S4# 1
S5# 1
S6# 1
S2# 2
S3# 3
S5# 2
S1# 3
S1# 2
S3# 2
S1# 5
S1# 6
S1#105
51*115
S1#130
S1#190
S2# 55
S2#130
S3# 80
S3# 95
S3HM05
S4# 50
S5# 15
Name Mass
CI30
CI40
CI50
CI60
CI70
CITS
CS20
CS25
CS30
CS45
CS50
CS55
CS70
CS75
C315
C330
C340
C370
C445
C465
C550
C560
C570
C635
C715
1,4-DICHLOROBENZENE
NAPHTHALENE-08
ACENAPHTHENE-D10
PHENANTHRENE-D10
CHRYSENE-012
PERYLENE-D12
NITROBENZENE-DS
2-FLUOROBIPHENYL
TERPHENYL-014
PHENOL-D5
2-FLUOROPHENOL
2,4,6-TRIBROMOPHENO
2-CHLOROPHENOL-D4
1.2-DICHLOROBNZN-D4
PHENOL
2-CHLOROPHENOL
1,4-DICHLOROBENZENE
N-NITROSO-DI-N-PROP
1,2.4-TRICHLOROBENZ
4-CHLORO-3-METHYLPH
ACENAPHTHENE
4-NITROPHENOL
2,4-DINITROTOLUENE
PENTACHLOROPHENOL
PYRENE
152
136
164
188
240
264
82
172
244
99
112
330
132
152
94
128
146
70
180
107
153
109
165
266
202
Meth
A
A
A
A
A
A
A
A
A
A
A
A
BB
BB
BB
BB
BB
BV
BB
BB
BB
BB
BB
BB
Scan Rei Area
340
529
828
1086
1551
1783
421
722
1383
306
196
968
1
2
3
4
5
6
2
3
5
1
1
3
1 NOT
A
A
A
A
A
A
A
A
A
A
A
A
BB
BB
BB
BB
BB
BB
BB
BB
BB
BB
BB
BB
340
308
313
342
408
524
649
833
887
878
1061
1334
1
1
1
1
1
2
2
3
3
3
4
5
28516.
101945.
56455.
91166.
75878.
63304.
37439.
60974.
77780.
40389.
37991.
27642.
FOUND
28516.
40013.
70308.
31738.
23823.
23662.
60821.
64768.
6606.
24726.
31357.
123841.
Units: UG/ML
RRF(L)
1.000
1.000
1.000
1.000
1.000
1.000
0.470
1.234
0.995
2.025
1.368
0.236
0.920
1.968
1.497
1.617
0.906
0.331
0.338
1.159
0.173
0.397
0.155
1.323
Amount
40.000
40.000
40.000
40.000
40.000
40.000
31.284
35.001
41.200
27.971
38.949
83.107
43.476
28.522
65.887
27.524
36.890
28.055
70.658
39.607
27.110
44.102
88.740
49.361
-------
SNA, S LIBRARIES ANALYST: DATE:
QUANTERRA Internal Standard Check
Standard Filename: ST16980831 Analyzed: 08/31/98 12:31
| IS# 1 | IS# 2 | IS# 3 |
Standard j Area % | RT j Area % | RT j Area % | RT j
ST16980831 | 28649. | 3.78 | 100432. | 5.90 | 54347. | 9.21 |
Upper Limit j 57297.=+200| 4.28 | 200864.=+200| 6.40 j 108695.=+200) 9.71 j
Lower Limit | 14324.=+ 50) 3.28 | 50216.=+ 50| 5.40 | 27174.=+ 50| 8.71 j
Filename | | | | | | J
I II II II
1 300681MBFMS| 28516.= 99| 3.78 | 101945.= 101| 5.88 | 56455.= 103| 9.21 |
I II II II
IS# 1 = CI30 1,4-DICHLOROBENZENE-D4
1S# 2 = CI40 NAPHTHALENE-08
IS# 3 = CI50 ACENAPHTHENE-010
* - indicates an I.S. is outside QC limit(s)
| IS# 4 | IS# 5 | IS# 6 |
Standard | Area % \ RT j Area X | RT j Area % | RT j
ST16980831 | 98520. (12.08 | 62289. |17.26 | 50750. (19.83 |
Upper Limit j 197039.=+200)12.58 j 124578.=+200|17.76 | 101500.=+200|20.33 |
Lower Limit j 49260.=+ 50)11.58 j 31145.=+ 50)16.76 j 25375.=+ 50)19.33 j
Filename
I II II II
I 300681MBFMS) 91166.= 92)12.08 | 75878.= 121|17.25 | 63304.= 124)19.83 |
I II II II
IS# 4 = CI60 PHENANTHRENE-D10
IS# 5 = CI70 CHRYSENE-D12
IS# 6 = CITS PERYLENE-012
* - indicates an I.S. is outside QC limit(s)
1754
-------
QUANTERRA GC/MS
Target Compound Data Summary Sheet
Data File: 300681MBFDS
Std Id: ST16980831
INST. ID: F16
Date Analyzed: 08/31/98 17:30
Run Factor: 1.00
Surrogate Vol.: 1.00
Sample: DCS-AD 01AUG98-16A 1SA/1ML
Client: PACIF1
Analyst: DAT Instrument ID: F16
Quan List Threshold: 0.95
Surrogate
Surrogate Spike Recoveries
8270-G, LIMS 10/10/96
Surrogate Amount (ug) X Recovery
Spiked Measured Measured QC limits
CS20 NlTROBENZENE-05 50.00 32.30
CS25 2-FLUOROBIPHENY 50.00 33.90
CS30 TERPHENYL-D14 50.00 37.80
CS45 PHENOL-D5 100.0 22.40
CS50 2-FLUOROPHENOL 100.0 39.90
CS55 2,4,6-TRIBROMOP 100.0 72.90
64.6
67.8
75.6
22.4
39.9
72.9
45 107
62 110
58 135
* 43 130
36 111
58 131
Target Compounds: MS
Parameter
Scan
Result
Units
Reporting
Limit (J values)
CS70 2-CHLOROPHENOL-D4
CS75 1.2-DICHLOROBNZN-D4
C315 PHENOL
C330 2-CHLOROPHENOL
C340 1,4-DICHLOROBENZENE
C370 N-NITROSO-OI-M-PROPYtAM
C445 1,2,4-TRICHLOROBENZENE
C465 4-CHLORO-3-METHYLPHENO
C550 ACENAPHTHENE
C560 4-NITROPHENOL
C570 2,4-DINITROTOLUENE
C635 PENTACHLOROPHENOL
C715 PYRENE
308
313
342
408
524
649
833
888
878
1061
1334
NO
NO
29.
67.
30.
33.
30.
66.
38.
24.
40.
76.
45.
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
50.0 J
10.0
50.0
10.0
Reviewed by:
*-,
t
-------
DATA FROM FILE: 300681MBFDS SCANS 230 TO 1200 ACQUIRED: 08/31/98 17:30:00
CALI: 300681MBFDS #3
SAMPLE: DCS-AD 01AUG98-16A 1SA/1ML INST. IDs FIG
CONDS.: UG/ML *1ML *\W?.'\m?. *
-------
DATA FROM FILE: 300681MBFDS SCANS 1200 TO 2158 ACQUIRED: 08/31/98 17:30:00
CALI: 300681MBFDS #3
SAMPLE: DCS-AD 01AUG98-16A 1SA/1ML INST. ID: F16
CONDS.: UG/ML *1ML * 10075/100JZ *
-------
STANDARD USED FOR THIS REPORT IS ST16980831 REPORT PRINTED: 9/01/98 11:13:00
ADDITIONAL STANDARD USED FOR THIS REPORT IS: ST16980831A
UANTERRA QUANTITATION SUMMARY
File: 300681MBFDS
Sample: DCS-AD 01AUG98-16A 1SA/1ML INST. ID: F16
Analyst: DAT Instrument Id: F16 Analyzed: 08/31/98 17:30
ompounds with amounts less than 0.20 reported as NOT FOUND
Library
No
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
JO
21
12
23
24
25
Entry
S1# 1
S2# 1
S3# 1
S4# 1
S5# 1
S6# 1
S2# 2
S3# 3
S5# 2
S1# 3
S1# 2
S3# 2
S1# 5
S1# 6
S1#105
Sims
S1#130
S1#190
S2# 55
S2#130
S3# 80
S3# 95
S3#105
S4# 50
S5# 15
Name Mass
CI30
CI40
CI50
C160
CI70
CITS
CS20
CS25
CS30
CS45
CS50
CS55
CS70
CS75
C315
C330
C340
C370
C445
C465
C550
C560
C570
C635
C715
1,4-DICHLOROBENZENE
NAPHTHALENE-08
ACENAPHTHENE-D10
PHENANTHRENE-D10
CHRYSENE-D12
PERYLENE-D12
NITROBENZENE-DS
2-FLUOROBIPHENYL
TERPHENYL-D14
PHENOL-D5
2-FLUOROPHENOL
2,4,6-TRIBROMOPHENO
2-CHLOROPHENOL-D4
1.2-DICHLOROBNZN-D4
PHENOL
2-CHLOROPHENOL
1,4-DICHLOROBENZENE
N-NITROSO-DI-N-PROP
1,2,4-TRICHLOROBENZ
4-CHLORO-3-METHYLPH
ACENAPHTHENE
4-NITROPHENOL
2.4-DINITROTOLUENE
PENTACHLOROPHENOL
PYRENE
152
136
164
188
240
264
82
172
244
99
112
330
132
152
94
128
146
70
180
107
153
109
165
266
202
Meth
A
A
A
A
A
A
A
A
A
A
A
A
BB
BB
BB
BB
BB
BV
BB
BB
BB
BV
BB
BV
Scan Ref Area
340
529
828
1086
1551
1783
421
722
1383
306
196
968
1
2
3
4
5
6
2
3
5
1
1
3
1 NOT
1 NOT
A
A
A
A
A
A
A
A
A
A
A
BB
BB
BB
BB
BB
BB
BB
BB
BB
BB
BB
308
313
342
408
524
649
833
888
878
1061
1334
1
1
1
1
2
2
3
3
3
4
5
28626.
99229.
54918.
93048.
77501.
65820.
37607.
57505.
72798.
32420.
39025.
23589.
FOUND
FOUND
40618.
71608.
34461 .
21467.
24942.
55273.
60897.
5735.
21544.
27378.
114585.
Units: UG/ML
RRF(L)
1.000
1.000
1.000
1.000
1.000
1.000
0.470
1.234
0.995
2.025
1.368
0.236
1.968
1.497
1.617
0.906
0.331
0.338
1.159
0.173
0.397
0.155
1.323
Amount
40.000
40.000
40.000
40.000
40.000
40.000
32.285
33.934
37.753
22.365
39.855
72.907
28.842
66.845
29.770
33.113
30.382
65.970
38.282
24.196
39.503
75.913
44.715
-------
BNA, S LIBRARIES ANALYST: DATE:
QUANTERRA Internal Standard Check
Standard Filename: ST16980831 Analyzed: 08/31/98 12:31
| IS* 1 | IS* 2
Standard j Area X | RT | Area X | RT
IS* 3
Area X | RT
ST16980831 | 28649. | 3.78 | 100432. | 5.90
Upper Limit j 57297.=+200| 4.28 j 200864.=+200| 6.40
Lower Limit | 14324.=+ 50| 3.28 j 50216.=+ 50| 5.40
54347. | 9.21
108695.=+200| 9.71
27174.=+ 50| 8.71
Filename | | | | |
I II II II
1 300681MBFDS| 28626.= 99| 3.78 | 99229.= 98| 5.88 | 54918.= 1011 9.21 |
I II II II
IS# 1 = CI30 1,4-D1CHLOROBENZENE-D4
IS* 2 = CI40 NAPHTHALENE-08
IS* 3 = CI50 ACENAPHTHENE-D10
* - indicates an I.S. is outside QC limit(s)
| IS* 4 | IS* 5 | IS* 6 |
Standard j Area % | RT j Area X | RT | Area % | RT j
ST16980831 | 98520. |12.08 | 62289. |17.26 | 50750. |19.83 |
Upper Limit | 197039.=+200)12.58 j 124578.=+200j17.76 j 101500.=+200|20.33 j
Lower Limit j 49260.=+ 50J11.58 j 31145.=+ 50J16.76 | 25375.=+ 50J19.33 |
Filename
I II II II
1 300681MBFDS| 93048.= 94|12.08 | 77501.= 124(17.25 | 65820.= 129(19.83 |
I'll II I I
IS# 4 = CI60 PHENANTHRENE-D10
IS* 5 = CI70 CHRYSENE-D12
IS* 6 = CITS PERYLENE-D12
* - indicates an I.S. is outside QC limit(s)
-------
Sample Extraction/Preparation Lag Coyies
17 BO
-------
Project Number: 300681
Test Code: P-8270-S
QUANTERRA-CALLAB LABORATORY
Analytical Bench Sheet
Date: 31 JUL 98
Test Description: Prep - Semivolatile Organics by GC/MS
Page 1 of 1
Turnaround Status: NORMAL Sample Matrix: A1RTRA1N Date Assigned:.
SOP -Sect ion/Page (Revision);
0 V^ 00® *
Prep Completion Due:_
Extractions: t ] Separatory Funnel [ ] Continuous Liquid/Liquid [ ] Sonication l^ Soxhlet [ ] KD
[ 3 Roto Vap [ ] Shaker [ ] Other
Samp
ID
000 ISA
0002SA
0003SA
0004SA
OOOSSA
0006SA
0007SA
OOOSSA
0009SA
0010SA
001 ISA
»M
S'ft
S'/fa
Holding
Time
08 AUG 98
08 AUG 98
08 AUG 98
08 AUG 98
09 AUG 98
10 AUG 98
10 AUG 98
09 AUG 98
08 AUG 98
08 AUG 98
11 AUG 96
Afl~
I
I
Sample
Size
ML
mM
(X#
«
W
//A
I
Spiked &
in Solvent
Date/
Initials
/
/
/
/
1st
pH
To:
,,iit/
*&
/
/
/
2nd
PH
To:
/
/
/
/
/
«
#
Extraction
Sonic/Shak
Date/
Initials
ijfii
JMV
1
\
I
/
/KD/)l2
ABN
W7/ .
T/1W
j
GPC
ft
<
/
KD^M?
ReoD?.
Ml
*MU
\
\
<
Screen
Date/
Initials
c?£
fMit
/
J
# A
i
I
Final
Concentn
Date/
Initials
^^
>i^^
i
<&^
*/^\*
{
I
fc«S
^fa»i
M&^
/-"^u
I
^
%*IS'
3sSfop3.
£*>>
SW*
\
\
3;
1
$&'
\
Project Due: 19 AUG 98
Method Blank With Project:
DCS With Project:.
LCS With Project:
DCS Code:.
LCS Code:
Notes/Comments:
** PLEASE PUT COMMENTS ON ANOMALY SHEET **
Extraction Includes Project(s):
MSQC with Project: IJA^ MSQC Code:
Date To Instruments:
By;
Peer Approval By:.
-------
QUANTERRA-CALLAB LABORATORY
Quality Assurance Sheet
Project I: 300681 Test: P-8270-S
Quality Assurance/Quality Control:
Sample ID; tfiL Spiking Standard
Spike Code ID; /%3/£W Volume: /^Oo^ Cone: /#&
Spiked By: //fidf Witness: £ o •-
Sample ID; C^#D Spiking Standard Name;
Spike Code ID; oof Volume: Vj^' Cone:
Spiked By; faff Witness:
Sample ID: Spiking Standard Name:
Spike Code ID: Volume: Cone:
Spiked By: Witness:
Sample ID: Spiking Standard Name:
Spike Code ID: Volume: Cone:
Spiked By: Witness:
Solvent: Manufacturer And Lot Number:
Extracting Solvent:
Solvent Keeper:
Transfer Solvent:
Derivatizing Reagent:
Final Solvent:
Other: *
Why was the aliquot taken?
7^
Was an aliquot taken?(^i)/ N
If yes, how much was ali quoted? ^inL / /5~ mL
What was the sample concentration before aliquot?_.
17
-------
QUANTERRA-CALLAB LABORATORY
Anomaly Report Form
Project #: 300681 Test: P-8270-S
Anomalies: Sample(s) Affected:
Sample broken during shipping.
Limited sample volume.
Matrix required a subsample to facilitate extraction.
pH of sample required excess acid/base (please circle).
Solvent and sample were miscible.
_ Emulsion problems.
Emulsion problem required centrifuging.
Sample lost during preparation.
Re-extraction performed? Yes/No
Concentration volume went lower than specified in the
SOP.
Concentration time longer than normal.
Extraction solvent saturated with organic material,
therefore sample volume was not concentrated but
adjusted based on the screening.
Final concentration greater than specified in the SOP
due to the screening results.
Precipitate observed in the extract.
OtheV, please comment below. / Lf // 1°, //
Comments:
_
f l, 7, lo - Cof/C
Submitted By; 'Ifin Date:
v ./
-------
QUANTERRA-CALLAB LABORATORY
Prep (Extraction) Check List
Project I: 300681 Test: P-8270-S
Chemist:
Reviewer:
Date
Date:
: r/r/1'
Number of samples: 11 Number of extracts:
Benchsheet;
SOP section and page number filled out properly.
Each step of extraction procedure initial'ed and dated.
Anomalies or deviations from SOP documented.
pH adjustments noted.
Solvent manufacturer and lot number completed.
Volumes and weights of samples to two sig. figs.
QA/QC;
DCS/MS forms filled out properly.
Spike information correct on bench sheet.
Spike witness?
If not spiked per SOP, were spike amounts verified?
LIMS;
Extraction date (complete date) correct.
QC lot number present and correct.
QC Run number present and correct.
Prep released,(date extract goes to Inst.).
Extracts;
Number of extracts agree with benchsheet.
Concentrations of extract agree with benchsheet.
Testtube rack labelled with project id and test.
Initialed Reviewed
Yv^/ N
Y
Y
Y
Y
Y
Ii
Y
Y
Y
Y
I
Y
Y
Y
Y
Ii
Y
Y
Y
N
N
N
N
N
itiated
N
N
N
N
itiated
N
N
N
N
itiated
N
N
' N
Y N
Y N
Y N
Y N
Y N
Y N
Revi ewed
Y N
Y N
Y N
Y N
Reviewed
Y N
Y N
Y N
Y N
Revi ewed
Y N
Y N
Y N
Comments:
-------
OUANTERRA-CALLAB LABORATORY
Analytical Bench Sheet
Project Number: 300681 Date: 31 JUL 98 Page 1 of 1
Test Code: P-8270-S Test Description: Prep • Semivolatile Orgam'cs by GC/HS
Prep Completion Due:
SOP- Sect
Extract!
Samp
ID
0001 SA
0002SA
0003SA
0004SA
0005SA
0006SA
0007SA
0008SA
0009SA
0010SA
001 1SA
MB
A*
to
ion/Page (Re
ons: [M Se
C ] Ro
Holding
Time
08 AUG 98
08 AUG 98
08 AUG 98
08 AUG 98
09 AUG 98
10 AUG 98
10 AUG 98
09 AUG 98
08 AUG 98
08 AUG 98
11 AUG^S
A//-
I
I
vision):
paratory Fu
to Vap
Sample
Size
$mi&>
\
/
i.ou
I
1
Project Due: 19 AUG 98
Method Blank With Project
Notes/Comments:
** PLEASE PUT COMMENTS Ot
Date To Instruments:
nnel [ ]
[ 1
Spiked &
n Solvent
Date/
Initials
J/O|c<4
Continue
Shaker
1st
pH
To:
w
DCS With Project:
LCS With Project:
.. ^OObff
I ANOMALY SHEET **
us Liqui
2nd
pH
To:
d/Liquid
xt raction
Sonic/Shak
Date/
Initials
V;
J*5
,
[ ] Sonication [ ] Soxhlet C ] KD
[ 3 Other
Weduc.
ABN
jfl}/7
\
— •
\
\
I
GPC
\
1
/
(
V
(
\
}
/
DCS Code:
KD/N2)
ReSfcfc.
>C0fW
5o*
$1
\
\
Screen
Date/
Initials
^/X<^?^
{teffti
A//
|
I
Final
Concentn
Date/
Initials
/iff/
^c
I
I
MAU4S&-K.A
i/ A. LCS Code: A/&
Extraction Includes Proiect(s): ?t?Oba/
MSQC with Project:
fifr MSQC Code: tffa
F'/f74r/' /3» tf
Q 1 1 I 1 9 By: fff/YJ ' Peer Approval By:
\ 1 \^
"7 /
-------
QUANTERRA-CALLAB LABORATORY
Quality Assurance Sheet
Project #: 300681 Test: P-8270-S
Quality Assurance/Quality Control:
Sample ID; ftg> fe» /At> cf%iking Standard Name ;
Spike Code I D ; ATd.^i^^A- Vol ume ; 5crx v% Cone:
* ^
Witness:
Spiked By:
Sample ID; /\/hVs Spiking Standard Name:
Spike Code ID; M gj&ffl$PVoluiiie; *5c<9 uJi Conc
Spiked By;
-------
QUANTERRA-CALLAB LABORATORY
Anomaly Report Form
Project #: 300681 Test: P-8270-S
Anomalies: Sample(s) Affected:
Sample broken during shipping.
Limited sample volume.
Matrix required a subsample to facilitate extraction.
pH of sample required excess acid/base (please circle).
Solvent and sample were miscible.
Emulsion problems.
Emulsion problem required centrifuging.
Sample lost during preparation.
Re-extraction performed? Yes/No
Concentration volume went lower than specified in the
SOP.
Concentration time longer than normal.
Extraction solvent saturated with organic material,
therefore sample volume was not concentrated but
adjusted based on the screening.
Final concentration greater than specified in the SOP
due to the screening results.
Precipitate observed in the extract.
\/ Other, please comment below.
Comments:
fa LlMll&b
Q
Submitted By; fl/JJ' Date:
-------
QUANTERRA-CALLAB LABORATORY
Prep (Extraction) Check List
Project I: 300681 Test: P-8270-S
Chemist: Date:
Reviewer: Date:
Number of samples:^>axXNumber of extracts:
Benchsheet;
SOP section and page number filled out properly.
Each step of extraction procedure initial'ed and dated.
Anomalies or deviations from SOP documented.
pH adjustments noted.
Solvent manufacturer and lot number completed.
Volumes and weights of samples to two sig. figs.
QA/QC;
DCS/MS forms filled out properly.
Spike information correct on bench sheet.
Spike witness?
If not spiked per SOP, were spike amounts verified?
Extraction date (complete date) correct.
QC lot number present and correct.
QC Run number present and correct.
Prep released (date extract goes to Inst.).
Extracts;
Number of extracts agree with benchsheet.
Concentrations of extract agree with benchsheet.
Testtube rack labelled with project id and test.
Initiated
Reviewed
Yv/ N
Y
Y
Y
Y
Y
In
Y
Y
Y
Y
In
Y
Y
Y
Y
In
Y
Y
Y
N
N
N
N
N
tiated
N
N
N
N
tiated
N
N
N
N
tiated
N
/ N
J7 N
Y N
Y N
Y N
Y N
Y N
Y N
Reviewed
Y N
Y N
Y N
Y N
Reviewed
Y N
Y N
Y N
Y N
Reviewed
Y N
Y N
Y N
Comments:
-------
fc loa Comes
U J
-------
REVIEWED BY/DATE,
INITIAL CAL DATE
UUAIM I tttttA
West Sacramento
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DATA UPLOAD/FILE ID
GC/MS INSTRUMENT LOG
SEMI-VOLATILES
INSTRUMENT ID
PAGE ' OF
UM
0^2.
-------
REVIEWED BY/DATE
INITIAL CAL DATE <;ftSL
QUANTERRA INCORPORATED
M/esf Sacramento
GC/MS INSTRUMENT LOG
SEMI-VOLATILES
PAGE*
DATA UPLOAD/FILE ID
INSTRUMENT ID £•1 fo
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-------
REVIEWED BY/DATE
UUAIMTERRA INCORPORATED
Sacramento
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DATA UPLOAD/FILE ID
INITIAL CAL DATE
-------
Instrument Tme
-------
ling Report
f27/98 9:12
strunent: F16
294
se Number:
DECAFLUOROTRIPHENYLPHOSPHINE
Data: U16980827 * 294 Base m/z:
Cali: U16980827 RIC:
Analyst: OAT Acct. No.:
Laboratory: QUANTERRA Contract:
n/z Intensity X RA
Ion Abundance Criteria
Min X Max X Hass Actual
Status
5\
68
69
70
I27
I97
198
199
275
565
141
V42
143
15536.
0.
18496.
114.
16080.
0.
28160.
1918.
6992.
800.
3580.
24000.
4512.
55.2
0.0
65.7
0.4
57.1
0.0
100.0
6.8
24.8
2.8
12.7
85.2
16.0
30.0
0.0
0.0
0.0
40.0
0.0
100.0
5.0
10.0
1.0
0.0
40.0
17.0
60.0
2.0
100.0
2.0
60.0
1.0
100.0
9.0
30.0
100.0
100.0
100.0
23.0
198
69
198
69
198
198
198
198
198
198
443
198
442
55.2
0.0
65.7
0.6
57.1
0.0
100.0
6.8
24.8
2.8
79.3
85.2
18.8
PASS
PASS
PASS
PASS
PASS
PASS
PASS
PASS
PASS
PASS
PASS
PASS
PASS
I"/'
-------
Mass List Data: U16980827 # 295
08/27/98 9:12:00 *• 3:17 Cali: F16980821 * 3
Sample: 50UG/ML DFTPP 081398A
Conds.: INST. ID: F16
#294 to #296 sunned - #290
Base m/z: 198
RIC: 264704.
35
444
Mass
38?
397
507
517
527
567
577
63?
65?
69
74
75
76
77
78
79
80
81
82
83
86
91
92
93
98
99
101
104
105
107
108
110
111
116
117
118
122
123
127
128
129
130
135
141
142
147
148
155
156
161
0.00
X RA
S 1.13
5.70
15.34
S 55.17
2.85
2.15
4.20
2.08
1.34
65.68
5.48
8.17
3.59
57.44
4.13
3.93
3.05
3.91
1.04
1.34
1.38
1.12
1.14
6.07
4.84
3.44
2.05
1.48
1.33
15.37
2.54
30.68
4.28
1.02
10.72
1.02
1.16
1.50
57.10
4.62
20.06
1.90
1.67
2.56
1.12
1.23
2.54
1.41
2.09
1.29
0.
Inten.
318.
1606.
4320.
15536.
802.
606.
1184.
586.
376.
18496.
1542.
2300.
1010.
16176.
1162.
1106.
860.
1102.
294.
378.
390.
314.
320.
1710.
1364.
970.
578.
418.
374.
4328.
714.
864Q.
1206.
286.
3020.
288.
328.
422.
16080.
1300.
5648.
536.
470.
722.
316.
346.
716.
396.
588.
362.
Minima
Maxima
Mass
165
167
168
174
175
179
180
181
185
186
187
192
193
196
198
199
204
205
206
207
211
217
221
223
224
225
227
229
244
245
246
255
256
258
273
274
275
276
277
296
323
334
365
372
423
424
441
442
443
444
Min Inten:
# 0
X RA
1.10
4.51
2.36
1.06
1.97
3.42
2.35
1.15
1.30
11.82
3.52
1.31
1.20
3.66
100.00
6.81
2.92
5.36
21.11
3.06
1.46
5.52
7.40
1.44
11.39
3.11
4.40
1.17
9.79
1.55
1.61
45.51
6.72
2.24
1.63
4.53
24.83
3.66
1.78
5.28
2.15
1.27
2.84
1.29
4.74
1.22
12.71
85.23
16.02
1.71
281.
Inten.
310.
1270.
664.
298.
554.
964.
662.
324.
366.
3328.
992.
370.
338.
1030.
28160.
1918.
822.
1508.
5944.
862.
410.
1554.
2084.
406.
3208.
876.
1240.
330.
2756.
436.
452.
12816.
1892.
630.
460.
1276.
6992.
1032.
502.
1486.
606.
358.
800.
362.
1336.
344.
3580.
24000.
4512.
482.
-------
lass List Data: U16980827 * 295 Base n/z: 198
«/27/98 9:12:00 + 3:17 Cali: F16980821 # 3 RIC: 264704.
ample: 50UG/HL DFTPP 081398A
onds.: INST. ID: F16
#294 to #296 sunned - #290
65 0.00 0. Minima Kin Inten: 0.
75 Maxima # 0
Mass X RA Inten.
65?
67?
69
70
72
73
74
75
1.34
0.09
65.68
0.40
0.09
0.82
5.48
8.17
376.
24.
18496.
114.
24.
230.
1542.
2300.
-------
Nass List Data: U16980827 # 295 Base m/z: 198
08/27/98 9:12:00 + 3:17 Cali: F16980821 * 3 RIC: 264704.
Sample: 50UG/ML OFTPP 081398A
Goods.: INST. ID: F16
#294 to #296 sunned - #290
195 0.00 0. Minima Hin Inten: 0.
200 Maxima # 0
Mass X RA Inten.
196 3.66 1030.
198 100.00 28160.
199 6.81 1918.
200 0.60 168.
-------
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•09S08I
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S8Z
083
SZ3
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;9
-------
DATA: U16980827 #294
CALI: F16980821 #3
SCANS 224 TO 514
MASS CHROMATOGRAMS
08x27/98 9:12:00
SAMPLE: 50UG/ML DFTPP 081398A
CONDS.: INST. ID: F16
RANGE: G 1/3000 LABEL: N 2, "2.0 QUAN: A 6, 2.0 J 0 BASE: U 20. 3
370
87552.
100.0-
184 _
—
i i l i
46.9-
235 _
-
251
204.
822.
-i •• i r i
2.6-
246 _
1 ' A. '
9680.
11.1-
266
35672.
\
ft
\
V
1— i r | T-
250
2:47
i OtSOO .
ll
fi
295 431
80. / 188.
108. J L 308.
llllllllllllll llllllii
431
41088.
59156.
A
295 410 |
66. 184. II
108. 512^ • /\
431
2300.
3332.
295 384
2if' 86.
4^2' H0. l\
— i " r-^i T -i ,,,,,,,,,,,
i
300 350 400 450
3:20 3:54 4:27 5:00
87552.
184.055
± 0.500
1 1 '
41088.
235.070
± 0.500
1 1 '
2300.
246.074
± 0.500
— i | i—
9680.
266.080
± 0.500
— T | r-
500 SCAN
5:34 TIME
-------
OECAFLUOROTRIPHENYLPHQSPHINE
Tuning Report
08/31/98 12:20
Instrument: F16
# 288
Case Number:
m/z intensity
Data: 1)16980831 # 288
Cali: U16980831
Analyst: DAT
Base m/z:
RIC:
Acct. No.:
Laboratory: QUANTERRA Contract:
Ion Abundance Criteria
% RA Min % Max % Mass Actual Status
51
68
69
70
127
197
198
199
275
365
441
442
443
16416.
0.
18912.
176.
16416.
0.
28800.
1914.
6792.
756.
3176.
19264.
3700.
57.0
0.0
65.7
0.6
57.0
0.0
100.0
6.6
23.6
2.6
11.0
66.9
12.8
30.0
0.0
0.0
0.0
40.0
0.0
100.0
5.0
10.0
1.0
0.0
40.0
17.0
60.0
2.0
100.0
2.0
60.0
1.0
100.0
9.0
30.0
100.0
100.0
100.0
23.0
198
69
198
69
198
198
198
198
198
198
443
198
442
57.0
0.0
65.7
0.9
57.0
0.0
100.0
6.6
23.6
2.6
85.8
66.9
19.2
PASS
PASS
PASS
PASS
PASS
PASS
PASS
PASS
PASS
PASS
PASS
PASS
PASS
-------
Mass List Data: U16980831 # 289
08/31/98 12:20:00 + 3:13 Cali: M6980821 # 3
Sample: 50UG/ML DFTPP 081398A
Conds.: INST. ID: F16
#288 to #290 sunned - #284
Base m/z: 198
RIC: 263168.
35
444
Mass
38?
39?
50?
51?
52?
56?
57?
62?
63?
65?
69
74
75
76
77
78
79
80
81
82
83
86
91
92
93
98
99
101
103
104
105
107
108
110
111
116
117
118
122
123
127
128
129
130
135
137
141
147
148
155
0.00
% RA
1.37
5.71
15.17
57.00
3.11
2.22
4.37
1.02
2.19
1.46
65.67
5.44
8.26
3.68
57.67
4.07
4.06
2.90
3.93
1.15
1.29
1.51
S 1.03
1.47
6.01
4.58
3.60
2.12
1.03
1.49
1.18
15.17
2.48
31.33
4.54
1.25
10.15
1.02
1.18
1.53
57.00
4.61
19.56
1.83
1.60
1.05
2.56
1.44
2.72
1.37
0.
Inten.
394.
1644.
4368.
16416.
896.
638.
1258.
294.
632.
420.
18912.
1566.
2380.
1060.
16608.
1172.
1170.
834.
1132.
332.
372.
434.
296.
424.
1732.
1320.
1036.
612.
298.
430.
340.
4368.
7U.
9024.
1308.
360.
2924.
294.
340.
440.
16416.
1328.
5632.
528.
460.
302.
738.
414.
784.
396.
Minima
Maxima
Mass
156
161
167
168
174
175
179
180
181
185
186
187
192
193
196
198
199
204
205
206
207
211
217
221
223
224
225
227
229
244
245
246
255
256
258
273
274
275
276
277
296
323
334
365
372
423
441
442
443
444
Min Inten:
# 0
% RA
1.97
1.22
4.35
2.35
1.11
1.82
3.29
2.39
1.20
1.72
11.75
3.52
1.24
1.17
3.90
100.00
6.65
2.83
5.09
20.83
S 2.76
1.19
5.33
7.61
1.55
10.94
2.89
4.19
1.15
9.39
1.45
1.57
44.11
6.56
2.19
1.52
4.37
23.58
3.47
1.63
5.10
2.00
1.21
2.62
1.12
4.56
11.03
66.89
12.85
1.40
293.
Inten.
568.
352.
1254.
678.
320.
524.
948.
688.
346.
494.
3384.
1014.
356.
338.
1122.
28800.
1914.
816.
1466.
6000.
794.
344.
1534.
2192.
446.
3152.
832.
1206.
332.
2704.
418.
452.
12704.
1890.
632.
438.
1258.
6792.
1000.
470.
1468.
576.
348.
756.
322.
1314.
3176.
19264.
3700.
402.
-------
Mass List Data: U16980831 # 289 Base m/z: 198
08/31/9812:20:00+ 3:13 Cali: F16980821 # 3 RIC: 263168.
Sample: 50UG/ML OFTPP 081398A
Conds.: 1NST. ID: F16
#288 to #290 sunned - #284
65 0.00 0. Minima Min Inten: 0.
75 Maxima # 0
Mass % RA Inten.
65? 1.46 420.
67? 0.11 32.
69 65.67 18912.
70 0.61 176.
73 0.85 244.
74 5.44 1566.
75 8.26 2380.
-------
ass List Data: U16980831 # 289 Base m/z: 198
8/31/98 12:20:00 + 3:13 Cali: F16980821 # 3 RIC: 263168.
ample: 50UG/ML DFTPP 081398A
onds.: INST. ID: F16
#288 to #290 sunned - #284
195 0.00 0. Minima Hin Inten: 0.
200 Maxima # 0
Mass % RA Inten.
195 0.24 70.
196 3.90 1122.
198 100.00 28800.
199 6.65 1914.
200 0.72 206.
.4.
^
-------
MASS SPECTRUM
88x31x98 12:28:00 + 3:13
SAMPLE: 50UG/ML DFTPP 081338A
CONDS.: INST. ID: F16
TEMP: 214 DEC. C
#288 TO #290 SUMMED - #284
DATA: U16980831 #289
CALI: F16980821 #3
BASE M/Z: 198
RIC: 263168.
100.0-
.
-
50.0-
"
"
39
M/Z
100.0-
-
50.0-
-
-
2;
M/Z 250
51
•45 !
57
" '" r
50
55
2'
1, 265 ,,
69
7
ll.
Jl^ — 1,
'5
i. 285
1" i » — r
7
11,1. .86 :9
'"1 "">" 1
296
300
3
..hi..,
100
315
•— i — "* — r
1
L.
i;
0
117
I
i. .1. .,,
i '
334
i:
>7
i
186
135, 1.48 161 , 179
150
1 1
so
206
L ..i
, (
200
346 3f5 . 383 403
^ r r ' • •
224
i , 1 1,
423
350 400
,1. .,. ..
r 28800
0
-
•
>
4'
1
\2
r 28800
0
-
-
•
•
1 i
450
r-
-------
RIC+MASS CHROMATOGRAM
08/31/98 12:20:00
SAMPLE: 50UG/ML DFTPP 081398A
CONDS.s INST. ID: F16 *
RANGE: G 1,3000 LABEL: N 2, 2.0
DATA: U16980831 #288
CALI: F16980821 #3
SCANS 270 TO 309
QUAN: A
0 BASE: U 20, 3
100.0-1
198
13968.
30644.
13968.
198.059
± 0.500
904.5n
-I 1 1 1—T
283
126272.
285920.
RIC
126336.
299
1175.
2241.
270
3:00
—I—r
275
3:04
280
3:07
i—I—r
285
3:10
290
3:14
295
3:17
300
3:20
305
3:24
SCAN
TIME
-------
DATA: U16980831 #283
CALI: F16980821 #3
SCANS 218 TO 508
MASS CHROMATOGRAMS
08/31/98 12:20:00
SAMPLE: 50UG/ML DFTPP 081398A
CONDS.: INST. ID: F16
RANGE: G 1.3000 LABEL: N 2, 2.0 QUAN: A 6, 2.0 J 0 BASE: U 20, 3
88960.
100.0-
184 _
..
149146.
j
289 1 403
64. (1 60.
90. IV '276. • •
T 1 1 1 1 1 1 1 1 1 1 1 1 1 1 I I . | . . . . | . .
1 424
41024.
46.1-
235 _
_
60606.
245 288 403
196. 62. 212.
792. 148. 6701 ' l\
i 1 1 1 1 1 1 1 1 1 1 1 i |— - i . . . | • • • • i • •
1 424
2320.
2.6-
246 _
3398.
289 378
202. 62.
494. 106. {\_
T 1 1 1 1 1 1 1 1 1 1 1 1 ( ' ' ' ' 1 ' ' ' ' 1
245
7688.
8.6-
266 _
_
33544.
h
\ 288
\ 56.
V_ - 142.
h 1 1- p— i 1 1 1 1 " 1 " ' |" ' ' ' ' 1 ' ' ' • i
250 300 350 400 450
2:47 3:20 3:54 4:27 5:00
88960.
184.055
± 0.500
41024.
235.070
± 0.500
2320.
246.074
± 0.500
7688.
266.080
± 0.500
500 SCAN
5:34 TIME
-A
-------
DECAFLUOROTR 1 PHENYLPHOSPH I NE
ning Report
/02/98 14:41
strgment: F16
288
se Number:
m/z Intensity
Data: U 16980902 # 288
Cali: U16980902
Analyst: DAT
Laboratory: QUANTERRA
Base m/z:
RIC:
Acct. No.:
Contract:
Ion Abundance Criteria
X RA Min X Max X Mass Actual Status
51
68
69
70
127
197
198
199
275
365
441
442
443
13072.
0.
15232.
126.
13728.
0.
24832.
1688.
6400.
722.
3212.
21024.
4024.
52.6
0.0
61.3
0.5
55.3
0.0
100.0
6.8
25.8
2.9
12.9
84.7
16.2
30.0
0.0
0.0
0.0
40.0
0.0
100.0
5.0
10.0
1.0
0.0
40.0
17.0
60.0
2.0
100.0
2.0
60.0
1.0
100.0
9.0
30.0
100.0
100.0
100.0
23.0
198
69
198
69
198
198
198
198
198
198
443
198
442
52.6
0.0
61.3
0.8
55.3
0.0
100.0
6.8
25.8
2.9
79.8
84.7
19.1
PASS
PASS
PASS
PASS
PASS
PASS
PASS
PASS
PASS
PASS
PASS
PASS
PASS
-------
Mass List Data: U16980902 # 289
09/02/98 14:41:00 * 3:13 Cali: U16980902 if 3
Sample: 50UG/HL OFTPP 081398A
Conds.: INST. ID: F16
#288 to #290 summed - #284
Base m/z: 198
RIC: 231424.
35
444
Mass
39?
50?
51?
52?
56?
57?
63?
65?
69
74
75
76
77
78
79
80
81
82
83
86
91
92
93
98
99
101
104
105
107
108
110
111
116
117
123
125
127
128
129
130
135
137
141
147
148
155
156
161
165
167
0.00
% RA
S 5.71
14.30
52.64
2.90
2.02
4.16
1.96
1.36
61.34
4.97
7.72
3.19
54.12
3.82
3.93
2.85
3.85
.10
.06
.33
.19
.35
6.05
4.46
3.33
2.09
1.54
1.36
14.11
2.46
28.80
4.19
1.19
10.07
1.46
1.01
55.28
4.74
18.94
2.00
1.68
1.08
2.54
1.37
2.75
1.43
1.94
1.31
1.11
4.49
0.
Inten.
1418.
3552.
13072.
720.
502.
1032.
486.
338.
15232.
1234.
1918.
792.
13440.
948.
976.
708.
956.
274.
264.
330.
296.
334.
1502.
1108.
826.
518.
382.
338.
3504.
612.
7152.
1040.
296.
2500;
362.
252.
13728.
1176.
4704.
496.
418.
268.
630.
340.
684.
354.
482.
326.
276.
1114.
Minima
Maxima
Mass
168
174
175
177
179
180
181
185
186
187
192
193
196
198
199
204
205
206
207
211
217
221
222
223
224
225
227
229
244
245
246
255
256
258
273
274
275
276
277
296
323
334
365
372
423
424
441
442
443
444
Min Inten:
# 0
X RA
2.24
1.21
1.90
1.10
3.14
2.42
1.30
1.78
11.66
3.70
1.17
1.23
3.97
100.00
6.80
2.79
5.28
21.55
3.09
1.68
5.56
6.97
1.29
1.71
11.39
3.12
4.17
1.15
9.78
1.60
1.81
46.65
7.03
2.38
1.83
4.43
25.77
3.76
1.79
5.38
2.09
1.32
2.91
1.26
4.85
1.25
12.93
84.66
16.20
1.80
251.
Inten.
556.
300.
472.
272.
780.
600.
322.
442.
2896.
918.
290.
306.
986.
24832.
1688.
692.
1312.
5352.
768.
416.
1380.
1732.
320.
424.
2828.
776.
1036.
286.
2428.
398.
450.
11584.
1746.
590.
454.
1100.
6400.
934.
444.
1336.
520.
328.
722.
314.
1204.
310.
3212.
21024.
4024.
446.
-------
ss List Data: U16980902 # 289 Base m/z: 198
/02/98 14:41:00 + 3:13 Cali: U16980902 # 3 R1C: 231424.
mple: 50UG/ML DFTPP 081398A
nds.: 1KST. ID: F16
288 to #290 sunned - #284
65 0.00 0. Minima Min Inten: 0.
75 Maxima # 0
ass X RA Inten.
65? 1.36 338.
69 61.34 15232.
70 0.51 126.
73 0.74 184.
74 4.97 1234.
75 7.72 1918.
-------
Mass List Data: U16980902 # 289 Base m/z: 198
09/02/98 14:41:00 + 3:13 Call: U16980902 # 3 RIC: 231424.
Sample: 50UG/ML DFTPP 081398A
Conds.: INST. ID: F16
#288 to #290 sunmed - #284
195 0.00 0. Minima Min Inten: 0.
200 Maxima # 0
Mass X RA Inten.
196 3.97 986.
198 100.00 24832.
199 6.80 1688.
200 0.92 228.
-------
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RIC+MASS CHROMATOGRAM
09/02/98 14:41:00
SAMPLE: 50UG/ML DFTPP 081398A
CONDS.: INST. ID: F16
RANGE: G 1.3000 LABEL: H 2, 2.0 QUAN: A
DATA: U16980902 #288
CALI: U16980902 #3
SCANS 270 TO 309
100.0-1
6, 2.0 J
289
12352.
27004.
0 BASE: U 20. 3
198
12352.
198.059
± 0.500
903.6-1
289
111529.
256304.
RIC
270
3:00.
\ r
275
3:04
I '
280
3:07
111616.
380
3:20
I r
305
3:24
SCAN
TIME
-------
DATA: U16988302 #288
CALI: U16980902 #3
MASS CHROMATOGRAMS
09/02/98 14:41:00
SAMPLE: 50UG/ML DFTPP 081398A
CONDS.: INST. ID: F16
RANGE: G 1,3000 LABEL: N 2, 2.0 QUAN: A 6, 2.0 J 0 BASE: U 20,
364
66048.
SCANS 218 TO 508
100.0-
184 _
-
258 289
40. 36.
114. 66.
i i i I i i i i
49.2-
235 _
-
246 289
160. 48.
672. 86.
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2.6-]
246 _
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289
198.
486.
A
i i • 1 i i i i
246
6296.
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28289.
A
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(
184.055
425 ± 0.500
197.
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Ililliilllliilillllil
425
32480.
57834 • 32480.
0 235.070
403 ± 0.500
570.
1104. • ft
I i i i i I i i . i l i i i i i i i i i l
425
1694.
31|98' 1694.
1 246.074
± 0.500
J I
| i i i i | i l l i | l i i i | i i i i |
6296.
266. 080
± 0.500
i i i i i l i i i i i i i i i i i i i i i
300 350 400 450 500 SCAN
3:20 3:54 4:27 5:00 5:34 TIME
-------
1. REPORT NO.
EPA-454/R-00-025F
TECHNICAL REPORT DATA
Please read instructions on the reverse before completing
2.
4. TITLE AND SUBTITLE
Final Report
Hot Mix Asphalt Plants,
Truck Loading and Silo Filling,
Manual Methods Testing,
Asphalt Plant C,
Los Angeles, California
Volume 6 of 8
7. AUTHOR(S)
Frank J. Phoenix
9. PERFORMING ORGANIZATION NAME AND ADDRESS
Pacific Environmental Services, Inc.
Post Office Box 12077
Research Triangle Park, North Carolina 27709-2077
12. SPONSORING AGENCY NAME AND ADDRESS
U.S. Environmental Protection Agency
Office of Air Quality Planning and Standards
Emissions, Monitoring and Analysis Division
Research Triangle Park, North Carolina 2771 1
3. RECIPIENT'S ACCESSION NO.
5. REPORT DATE
May 2000
6. PERFORMING ORGANIZATION CODE
8. PERFORMING ORGANIZATION REPORT NO.
10. PROGRAM ELEMENT NO.
11. CONTRACT/GRANT NO.
68-D-98004
13. TYPE OF REPORT AND PERIOD COVERED
Final
14. SPONSORING AGENCY CODE
EPA/200/04
15. SUPPLEMENTARY NOTES
16. ABSTRACT
The United States Environmental Protection Agency (EPA) Office of Air Quality Planning and Standards (OAQPS) is investigating hot mix
asphalt plants to identify and quantify paniculate matter (PM), methylene chloride extractable matter (MCEM), and organic hazardous air pollutant
(HAP) emissions during asphalt concrete loading operations. In support of this investigation, the OAQPS issued Pacific Environmental Services, Inc.
(PES) a series of work assignments to conduct emissions testing at a hot mix asphalt plant during load-out operations.
The primary objective of the emissions testing was to characterize the uncontrolled emissions of PM, MCEM, polynuclear aromatic hydrocarbons
(PAHs), semi-volatile organic hazardous air pollutants (SVOHAPS), and volatile organic hazardous air pollutants (VOHAPS) from a hox mix
production plant during loading operations. An asphalt plant south of Los Angeles, California was selected by EPA as the host facility. Testing
was performed over five consecutive days beginning on July 24, 1998. Testing was performed under two conditions. Under normal operations, testing
was performed to characterize load-out emissions from the tunnel exhaust and load-in emissions from the asphalt concrete storage silo. Under
background conditions, testing was performed to characterize emissions from the combustion of diesel fuel in transport trucks.
The entire*report consists of eight volumes totaling 4,234 pages. Vol. 1 (388 pages), Vol. 2 (308 pages), Vol. 3 (573 pages), Vol. 4 (694 pages),
Vol. 5 (606 pages), Vol. 6 (564 pages), Vol. 7 (570 pages), and Vol. 8 (531 pages).
17.
a. DESCRIPTIONS
Hazardous Air Pollutants
Methylene Chloride Extractable
Matter
Paniculate Matter
Polynuclear Aromatic Hydrocarbons
Semi-volatile Organic Hazardous Air
Pollutants
Volatile Organic Hazardous Air
Pollutants
18. DISTRIBUTION STATEMENT
Unlimited
KEY WORDS AND DOCUMENT ANALYSIS
b. IDENTIFIERS/OPEN ENDED TERMS
i :
19. SECURITY CLASS (This Report)
Unclassified
20. SECURITY CLASS (This page)
Unclassified
c. COASTI Field/Group
(
21. NO. OF PAGES
Vol. 6 - 564
22. PRICE
EPA Form 2220-1 (Rev. 4-77) PREVIOUS EDITION IS OBSOLETE
F:\U\FMeadows\TRD.Frm\WP 6
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