United States
Environmental Protection
Agency
Office of Air Quality
Planning and Standards
Research Triangle Park, NC 27711
EPA-454/R-00-025G
May 2000
AIR
&EPA
Final Report
Hot Mix Asphalt Plants
Truck Loading and Silo Filling
Manual Methods Testing
Asphalt Plant C
Los Angeles, California
Volume 7 of 8
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o
FINAL REPORT
HOT MIX ASPHALT PLANTS
TRUCK LOADING AND SILO FILLING
MANUAL METHODS TESTING
ASPHALT PLANT C, LOS ANGELES, CALIFORNIA
VOLUME 7 OF 8
APPENDIX G.4
EPA Contract No. 68-D-98-004
Work Assignment No. 3-02
Prepared for:
Mr. Michael L. Toney (MD-19)
Work Assignment Manager
SMTG, EMC, OAQPS
U.S. Environmental Protection Agency
Research Triangle Park, NC 27711
MAY 2000
Submitted by
PACIFIC ENVIRONMENTAL SERVICES, INC.
5001 S. Miami Blvd., Suite 300
Post Office Box 12077
Research Triangle Park, NC 27709-2077
(919) 941-0333
FAX (919) 941-0234
U.S. Environmental Protection Agency
Region 5, Library (PL-12J)
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DISCLAIMER
The information in this document has been funded wholly or in part by the Office of Air
Quality Planning and Standards, U.S. Environmental Protection Agency (EPA) under contract
to Pacific Environmental Services, Inc. (PES). PES performed the work presented in this
document under three EPA contracts and seven Work Assignments; EPA Contract No. 68-D-
98-004, Work Assignment Nos. 1-08,2-07, 3-02, and 3-05, EPA Contract No. 68-D-70002,
Work Assignment Nos. 0-05 and 1-07, and EPA Contract No. 68-D-70069, Work Assignment
No. 2-16. This document has been prepared by PES, reviewed following PES' internal
quality assurance procedures, and approved by PES for distribution. This document has been
subjected to the Agency's review, and has been approved by EPA for publication as an EPA
document. Mention of trade names does not constitute endorsement by the EPA or PES.
11
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TABLE OF CONTENTS
VOLUME 1 Page
1.0 INTRODUCTION 1-1
2.0 SUMMARY OF TEST RESULTS 2-1
2.1 OVERVIEW 2-1
2.2 TREATMENT OF NON-DETECTS AND ESTIMATES 2-2
2.3 TUNNEL EXHAUST DUCT 2-2
2.4 SILO EXHAUST DUCT RESULTS 2-12
2.5 PM AND MCEM DEPOSITION ESTIMATES 2-15
2.6 METEOROLOGICAL STATION RESULTS 2-15
3.0 PROCESS DESCRIPTION 3-1
3.1 COORDINATION BETWEEN TESTING AND PROCESS
OPERATIONS 3-3
3.2 PROCESS MONITORING DURING TESTING 3-3
3.3 PROCESS SAMPLES 3-4
3 4 VELOCITY OF AIR ACROSS TOP OF TRANSPORT TRUCKS
DURING LOAD-OUT 3-5
4.0 SAMPLING LOCATIONS 4-1
4.1 TUNNEL EXHAUST DUCT 4-1
4.2 SILO EXHAUST DUCT 4-1
5.0 SAMPLING AND ANALYTICAL PROCEDURES 5-1
5.1 LOCATION OF MEASUREMENT SITES AND
SAMPLE/VELOCITY TRAVERSE POINTS 5-1
5.2 DETERMINATION OF EXHAUST GAS VOLUMETRIC
FLOW RATE 5-1
5.3 DETERMINATION OF EXHAUST GAS DRY MOLECULAR
WEIGHT 5-3
5.4 DETERMINATION OF EXHAUST GAS MOISTURE CONTENT 5-3
in
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TABLE OF CONTENTS (CONTINUED)
VOLUME i (CONTINUED^ page
5.5 DETERMINATION OF PM AND MCEM 5-3
5.6 DETERMINATION OF VOHAPs 5-3
5.7 DETERMINATION OF SVOHAPs 5-7
5.8 DETERMINATION OF WIND SPEED, WIND DIRECTION,
AMBIENT TEMPERATURE, AND AMBIENT HUMIDITY 5-7
5.9 ESTIMATE OF PM AND MCEM ON THE CEILING
OF THE LOAD-OUT TUNNEL DOWNSTREAM OF SILO NO. 5 5-7
5.10 ESTIMATE OF PM AND MCEM DEPOSITION ON THE INSIDE
WALLS OF THE SILO NO. 2 EXHAUST PLENUM 5-9
5.11 ESTIMATE OF PM AND MCEM DEPOSITION ON THE INSIDE
WALLS OF THE SILO EXHAUST DUCT 5-9
5.12 ESTIMATE OF PM AND MCEM DEPOSITION ON THE INSIDE
WALLS OF THE TUNNEL EXHAUST DUCT 5-10
6.0 QUALITY ASSURANCE/QUALITY CONTROL (QA/QC) PROCEDURES
AND RESULTS 6-1
6.1 CALIBRATION AND PREPARATION OF APPARATUS 6-1
6.2 REAGENTS AND GLASSWARE PREPARATION 6-2
6.3 ON-SITE SAMPLING 6-3
6.4 SAMPLE RECOVERY 6-4
6.5 LABORATORY ANALYTICAL QA/QC PROCEDURES 6-5
6.6 QA COORDINATOR FIELD AUDIT 6-7
APPENDIX A - TEST RESULTS AND CALCULATIONS 1
A.1 TED TEST RESULTS 3
A.2 SED TEST RESULTS 101
A.3 EXAMPLE CALCULATIONS 195
A.4 PARTICIPATE DEPOSITION DATA 204
A.5 CAPTURE EFFICIENCY CALCULATIONS 211
VOLUME 2
APPENDIX B - PROCESS DATA 1
B.I PRODUCTION RECORDS FOR 7/24/98 THROUGH 7/28/98 3
B.2 PRODUCT STORAGE RECORDS FOR 7/25/98 THROUGH 7/28/98 9
IV
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TABLE OF CONTENTS (CONTINUED)
VOLUME 2 rCONTINUEDI
APPENDIX B - PROCESS DATA (CONTINUED)
B.3 LOAD-OUT RECORDS USED IN TED EMISSION CALCULATIONS . . 19
B.4 LOAD-OUT RECORDS FOR 6/18/98 THROUGH 7/26/98 33
B.5 LOAD-OUT RECORDS FOR 7/24/98 THROUGH 7/28/98 44
B.6 SILO NO. 2 LOAD-IN RECORDS USED IN SED EMISSION
CALCULATIONS 68
B.7 ASPHALT TEMPERATURES AT LOAD-OUT 90
B.8 MASS CHANGE RESULTS FROM ASTM TESTS PERFORMED ON
ASPHALT CEMENT SAMPLES 93
B.9 VELOCITY OF AIR ACROSS TOP OF TRANSPORT TRUCKS
DURING LOAD-OUT 100
B.10 METALS ANALYSIS OF PROCESS SAMPLES 104
VOLUME 3
APPENDIX C - FIELD DATA 1
C.I TED FIELD DATA 2
C.2 SED FIELD DATA 59
C.3 METEOROLOGICAL STATION DATA 89
C.4 ON-SITE GC/MS REPORT AND DATA 118
APPENDIX D - QA/QC DATA 230
APPENDIX E - PROJECT PARTICIPANTS 280
APPENDIX F - TEST METHODS
F.I EPA METHOD 1
F.2 EPA METHOD 1A
F.3 EPA METHOD 2
F.4 EPA METHOD 4
F.5 EPA METHOD 18
F.6 EPA METHOD 315
F.7 SW-846 METHOD 0010
F.8 SW-846 METHOD 0030
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TABLE OF CONTENTS (CONCLUDED)
VOLUME 4
APPENDIX G - ANALYTICAL DATA 1
G.I PM AND MCEM DATA la
G.2 PAH/SVOHAPS CASE NARRATIVE AND PAH DATA Ik
VOLUMES
APPENDIX G - ANALYTICAL DATA (CONTINUED) 659
G.3 SVOHAPS DATA 659
VOLUME 6
APPENDIX G - ANALYTICAL DATA (CONTINUED) 1248
G.3 SVOHAPS DATA (CONCLUDED) 1248
VOLUME?
APPENDIX G - ANALYTICAL DATA (CONTINUED) la
G.4 VOHAPS DATA Ic
VOLUMES
APPENDIX G - ANALYTICAL DATA (CONCLUDED) la
G.4 VOHAPS DATA (CONCLUDED) Ic
G.5 EPAMETHOD 18 REPORT AND DATA 260
VI
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LIST OF TABLES
Page
Table 1.1 Test Log Tunnel Exhaust Duct, Asphalt Plant C - California 1-4
Table 1.2 Test Log Silo Exhaust Duct, Asphalt Plant C - California 1-5
Table 2.1 Summary of Results, Production Emissions for PM, MCEM, PAH,
SVOHAP and VOHAP, Asphalt Plant C, California - July 1998 2-3
Table 2.2 Summary of Results, Average PM and MCEM Emissions,
Asphalt Plant C, California - July 1998 2-4
Table 2.3 Summary of Results, Average PAH and SVOHAP Emissions,
Asphalt Plant C, California - July 1998 2-5
Table 2.4 Summary of Results, Average VOHAP Emissions,
Asphalt Plant C, California - July 1998 2-6
Table 2.5 Summary of Results, PAHS, SVOHAPS, & VOHAPS Average
Emissions, Silo Exhaust Duct - Asphalt Plant C, California, July 1998 .... 2-7
Table 2.6 PM and MCEM Emissions Sampling and Exhaust Gas Parameters
Normal Operations, Tunnel Exhaust Duct, Asphalt Plant C - California . . 2-16
Table 2.7 PM and MCEM Exhaust Gas Concentrations and Emission Rates, Normal
Operations, Tunnel Exhaust Duct, Asphalt Plant C - California 2-17
Table 2.8 PAHs and Semi-Volatile Organics Emissions Sampling and
Exhaust Gas Parameters, Normal Operations, Tunnel Exhaust Duct,
Asphalt Plant C - California 2-18
Table 2.9 PAHs Exhaust Gas Concentrations and Emission Rates, Normal
Operations Tunnel Exhaust Duct, Asphalt Plant C - California 2-19
Table 2.10 Semi-Volatile Organics Exhaust Gas Concentrations and Emission Rates,
Normal Operations, Tunnel Exhaust Duct, Asphalt Plant C - California . . 2-21
Table 2.11 Volatile Organics - SW-846 Method 0030 Emissions Sampling and
Exhaust Gas Parameters, Normal Operations, Tunnel Exhaust Duct,
Asphalt Plant C - California 2-30
Table 2.12 Volatile Organics - SW-846 Method 0030 Exhaust Gas Concentrations
and Emission Rates, Normal Operation, Tunnel Exhaust Duct,
Asphalt Plant C - California 2-31
Table 2.13 Volatile Organics - EPA Method 18 Emissions Sampling and
Exhaust Gas Parameters, Normal Operations, Tunnel Exhaust Duct,
Asphalt Plant C - California 2-36
Table 2.14 Volatile Organics - EPA Method 18 Exhaust Gas Concentrations
and Emission Rates, Normal Operations, Tunnel Exhaust Duct,
Asphalt Plant C - California 2-37
Table 2.15 On-Site GC/MS Volatile Organics Exhaust Gas Concentrations and
Emission Rates with Vost (SW-846 Method 0030) and EPA Method 18
Comparison, Tunnel Exhaust Duct, Asphalt Plant C - California 7/24/98 . 2-38
Table 2.16 PM and MCEM Emissions Sampling and Exhaust Gas Parameters,
Background Condition, Tunnel Exhaust Duct, Asphalt Plant C - California 2-39
vn
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LIST OF TABLES (CONTINUED)
Page
Table 2.17 PM and MCEM Exhaust Gas Concentrations and Emission Rates,
Background Condition, Tunnel Exhaust Duct, Asphalt Plant C - California 2-40
Table 2.18 PAHs and Semi-Volatile Organics Emissions Sampling and Exhaust Gas
Parameters Background Condition, Tunnel Exhaust Duct,
Asphalt Plant C - California 2-41
Table 2.19 PAHs Exhaust Gas Concentrations and Emission Rates, Background
Condition, Tunnel Exhaust Duct, Asphalt Plant C - California 2-42
Table 2.20 Semi-Volatile Organics Exhaust Gas Concentrations and Emission Rates,
Background Condition, Tunnel Exhaust Duct, Asphalt
Plant C - California 2-44
Table 2.21 Volatile Organics - SW-846 Method 0030 Emissions Sampling and
Exhaust Gas Parameters, Background Condition, Tunnel Exhaust Duct,
Asphalt Plant C - California 2-53
Table 2.22 Volatile Organics - SW-846 Method 0030 Exhaust Gas Concentrations
and Emission Rates, Background Condition, Tunnel Exhaust Duct,
Asphalt Plant C - California 2-54
Table 2.23 Volatile Organics - EPA Method 18 Emissions Sampling and Exhaust Gas
Parameters, Background Condition, Tunnel Exhaust Duct, Asphalt
Plant C - California 2-59
Table 2.24 Volatile Organics - EPA Method 18 Exhaust Gas Concentrations and
Emission Rates, Background Condition, Tunnel Exhaust Duct,
Asphalt Plant C - California 2-60
Table 2.25 Sample Log Silo Exhaust Duct, Asphalt Plant C - California 2-61
Table 2.26 PM and MCEM Emissions Sampling and Exhaust Gas Parameters,
Silo Exhaust Duct, Asphalt Plant C - California 2-62
Table 2.27 PM and MCEM Exhaust Gas Concentrations and Emission Rates,
Silo Exhaust Duct, Asphalt Plant C - California 2-63
Table 2.28 PAHs and Semi-Volatile Organics Emissions Sampling and Exhaust Gas
Parameters, Silo Exhaust Duct, Asphalt Plant C - California 2-64
Table 2.29 PAHs Exhaust Gas Concentrations and Emission Rates, Silo Exhaust Duct,
Asphalt Plant C - California 2-65
Table 2.30 Semi-Volatile Organics Exhaust Gas Concentrations and Emission Rates,
Silo Exhaust Duct, Asphalt Plant C - California 2-67
Table 2.31 Volatile Organics - SW-846 Method 0030 Emissions Sampling and
Exhaust Gas Parameters, Silo Exhaust Duct, Asphalt Plant C - California . 2-76
Table 2.32 Volatile Organics - SW-846 Method 0030 Exhaust Gas Concentrations
and Emission Rates, Silo Exhaust Duct, Asphalt Plant C - California .... 2-77
Table 2.33 On-Site GC/MS Volatile Organics Exhaust Gas Concentrations and
Emission Rates with Vost (SW-846 Method 0030) Comparison,
Silo Exhaust Duct, Asphalt Plant C - California 7/25/98 2-82
Table 2.34 PM and MCEM Deposition Estimates, Asphalt Plant C - California 2-83
viii
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LIST OF TABLES (CONCLUDED)
Page
Table 2.35 Meteorological Data Summary, Asphalt Plant C - California 2-84
Table 3.1 Load-out Data Used in TED Emission Calculations 3-6
Table 3.2 Load-in Data for Silo No. 2 Used in SED Emission Calculations 3-7
Table 3.3 Asphalt Temperatures at Load-out, Asphalt Plant C, California 3-8
Table 3.4 Mass Change of Asphalt, Asphalt Plant C, California 3-9
Table 3.5 Results of Metals Analyses of Asphalt Samples, Asphalt Plant C,
California 3-10
Table 3.6 Air Velocity Over Transport Trucks During Load-out, Asphalt Plant C,
California 3-11
Table 5.1 Summary of Sampling and Analytical Methods, Asphalt Plant C,
California 5-2
Table 6.1 Summary of Temperature Sensor Calibration Data 6-8
Table 6.2 Summary of Pitot Tube Dimensional Data 6-9
Table 6.3 Summary of Dry Gas Meter and Orifice Calibration Data 6-10
Table 6.4 Summary of EPA Method 315 and SW-846 Method 0010
Field Sampling QA/QC Data 6-11
Table 6.5 Summary of EPAMethod 315 Blank Sample Catches 6-12
Table 6.6 SW-846 Method 0010 PAHs Field and Laboratory Blanks Results,
Tunnel Exhaust Duct 6-13
Table 6.7 SW-846 Method 0010 PAHs Field and Laboratory Blanks Results,
Silo Exhaust Duct 6-14
Table 6.8 SW-846 Method 0010 PAHs Surrogate Recovery Results,
Tunnel Exhaust Duct 6-15
Table 6.9 SW-846 Method 0010 Semi-Volatile Surrogate Recovery Results
Tunnel Exhaust Duct 6-16
Table 6.10 SW-846 Method 0010 PAHs Surrogate Recovery Results,
Silo Exhaust Duct 6-17
Table 6.11 SW-846 Method 0010 Semi-Volatile Surrogate Recovery Results
Silo Exhaust Duct 6-18
Table 6.12 SW-846 Method 0030 Field and Laboratory Blanks Results
Tunnel Exhaust Duct 6-19
Table 6.13 SW-846 Method 0030 Laboratory Blank Results, Silo Exhaust Duct .... 6-20
Table 6.14 SW-846 Method 0030 Surrogate Recovery Results
Tunnel Exhaust Duct 6-21
Table 6.15 SW-846 Method 0030 Surrogate Recovery Results
Silo Exhaust Duct 6-22
IX
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LIST OF FIGURES
Page
Figure 1.1 Project Organization - US EPA Hot Mix Asphalt Load-out Operation,
Asphalt Plant C, California 1-6
Figure 2.1 Load-out Tunnel and MET Station Location and Average Wind Direction 2-85
Figure 3.1 Process Flow Schematic, Asphalt Plant C, California 3-2
Figure 3.2 Velocity Measurement Locations and Dimensions of Transport Trucks ... 3-12
Figure 4.1 Tunnel Exhaust Duct Sampling Locations, Asphalt Plant C, California .... 4-2
Figure 4.2 Tunnel Exhaust Duct Traverse Point Locations,
Asphalt Plant C, California 4-3
Figure 4.3 Silo Exhaust Duct Sampling Locations, Asphalt Plant C, California 4-4
Figure 4.4 Silo Exhaust Duct Traverse Point Locations, Asphalt Plant C, California . . 4-5
Figure 5.1 EPA Method 315 Sampling Train Schematic 5-4
Figure 5.2 SW-846 Method 0030 Sampling Train Schematic 5-6
Figure 5.3 SW-846 Method 0010 Sampling Train Schematic 5-8
Figure 5.4 Location of TED Deposition Test Plates Tb T2, and T3 5-11
GLOSSARY OF TERMS
ASTM - American Society for Testing and Materials
CEMS - Continuous Emissions Monitoring System
CTS - Calibration Transfer Standard
EMC - Emissions Measurement Center
EMAD - Emission Monitoring and Analysis Division
ESP - Electrostatic Precipitator
FID - Flame lonization Detector
FTIR - Fourier Transform Infrared Spectroscopy
HAP - Hazardous Air Pollutant
MCEM - Methylene Chloride Extractable Matter
MRI - Midwest Research Institute
PES - Pacific Environmental Services
PM - Paniculate Matter
PTE - Permanent Total Enclosure
RAP - Recycled Asphalt
RTFOT - Rolling Thin Film Oven Test
SED - Silo Exhaust Duct
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GLOSSARY OF TERMS (CONTINUED)
SMTG - Source Measurement Technology Group
SVOHAP - Semi-Volatile Organic Hazardous Air Pollutant
TED - Tunnel Emissions Duct
TFOT - Thin Film Oven Test
THC - Total Hydrocarbons
VOHAP - Volatile Organic Hazardous Air Pollutant
VOST - Volatile Organic Sampling Train
XI
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VOLUME 7
APPENDIX G
ANALYTICAL DATA (CONTINUED)
G.4 VOHAPS DATA
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APPENDIX G.4
VOHAPS DATA
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CASE NARRATIVE
Analysis of Samples for the Presence of
Volatile Analytes by
High-Resolution Gas Chromatography / Low-Resolution Mass Spectrometry
METHOD 8260
Date:
August 24, 1998
Client ID
Pacific Environmental Services
TLI Project Number : 46297
This report should only be reproduced in full. Any partial reproduction of this report requires permission from
Triangle Laboratories, Inc.
\e
Triangle Laboratories, Inc.
801 Capitola Drive P.O. Box 13485
Durham, NC 27713-4411 Research Triangle Park, NC 27709-3481
919-544-5729 Fax # 919-544-5491
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Triangle Laboratories, Inc. August 24,1998
Case Narrative 46297
Objective: Analysis of four VOST tube pairs (T-V-1-1-A&-B, T-V-1-2-A&-B, T-V-1-3-A&-B,
T-V-1-4-A&-B) for a client specified list of volatile compounds, using Method 8260.
Method:
Eight VOST tube pairs were received at Triangle Laboratories, Inc. on July 25,1998 on ice at
6°C in good condition. The samples were stored in a refrigerator at 4°C prior to 'analysis. The
VOST tube sample pairs were analyzed according to the guidelines of Methods 8260 and 5040.
£Per client request, the compounds 1,3-butadiene, vinyl bromide, methyl-t-butylether (MTBE), n-
hexane, 1,2-epoxybutane, iso-octane, and ethyl acrylate were additional target compounds. A one
point calibration was analyzed for these additional compounds and the resulting response factor
used for quantitation^ The internal standards and surrogate standards were added in the amount
of 0.25 micrograms (ug) immediately prior to analysis by GC/MS. The internal standards are
pentafluorobenzene, 1,4-difluorobenzene, and chlorobenzene-dj and l,4-dichlorobenzene-d4. The
surrogate standards reported are dibromofluoromethane, toluene-dg, and 4-bromofluorobenzene.
The results reported relate only to the items tested.
The GC/MS analysis conditions are listed below:
Purge and trap: Tekmar LSC-2000
Purge: 11 min.
Desorb Temperature: 250 C
Desorb Time: 4 min.
GC Conditions:
Column: 30 m x .53 mm x 0.3w J&W DB624
0 C hold .5 min, 10 C/min to 45C, 6 C/min to 90C, hold 1.5 min,
50 C/min to 200C.
MS Conditions:
Instrument: VG-TRIO-1 Lab Base data system
Scan: 35-350 amu at .6s/scan
Interface: Jet Separator, 200 C
Report:
Enclosed with the case narrative are copies of the sample identification index, the project
summary sheets, client paperwork, sample log-in sheets, and log book pages. A sample
identification index summarizes the client sample name, TLI sample number, and analytical file
name for each sample and blank. The project summary lists the amounts for detected analytes in
gray. The estimated detection limits will be listed in parentheses when the target analytes are not
detected.
The data are reported as quantitation reports, chromatograms, interim reports, and spectra of
detected target. The quantitation report header lists the TLI project number, analysis method,
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Triangle Laboratories, Inc. August 24, 1998
Case Narrative 46297
instrument sample file name, client sample name, client project number, TLI sample number,
calibration file, date received, and analysis date. The response factors used for all calculations are
from the calibration file listed in the header. All initial and continuing calibration data are located
in the back of the data package. The amount is reported in total ug for the VOST tubes. The
retention time (RT) will be listed for all internal standards and analytes which are detected. If a
target analyte is not detected, it will be flagged with a "U" and a detection limit will be listed.
Estimated detection limits are calculated for all analytes which were not found in the samples by
using an area of 2000. The estimated detection limits reported are the average detection limits
achievable over time on an instrument type. The actual detection limit for a given compound on a
given day may vary from the estimate reported. The quantitation limit for all analytes is half of
the low point of the initial calibration. Below this point the calibration cannot be considered to be
linear. Any amount reported at a level below the quantitation limit will be flagged with a " J" and
should be considered estimated. If any compounds are found at a level above the upper
calibration range, the analyte will be flagged with an "E" and the amounts reported should be
considered estimated. If any target analytes found in the laboratory blanks are detected in the
associated samples, they will be flagged with a "B" on each sample topsheet. All analytes are
quantitated against the internal standard preceding them on the target analyte list. Surrogate
standards are quantitated against the internal standard with the matching internal standard
reference number. For example, toluene-dg has 2 in the IS Ref column and would be quantitated
against the internal standard which has IS2 listed in the flag column. If an internal standard area is
above or below the quality control limits as defined by the continuing calibration, it will be flagged
with "High" or "Low" in the flag column.
Results:
The VOST tube pairs were analyzed ten days outside the fourteen day sampling to analysis
holding time. The VOST tubes were analyzed separately per client request. -
/
The surrogate percent recoverie/met all quality control criteria for all sample and blank analyses
with the exception of samples(iv-M-A and T-V-1-2-A. ^f£VT^i£: /^fr ^o-/
The area for internal standard met quality control criteria for all sample and blank analyses with
the exception of sample T-V-1-3-B. In this sample the area of pentafluorobenzene was high in
comparison to the one point calibration standard.
Sample T-V-1-2-A was analyzed one minute outside the instrument's twelve hour tune time
criteria. *-TS
No data was collected for sample T-V-1-4-A, due to GC oven shutting off and not ramping,
during the acquisition.
The laboratory blanks contained several target analytes at amounts below the quantitation limit.
The target analytes in the laboratory blanfeshould not be considered as^ruly present in the native
samples unless found at a level at least five times the amount |otmd in the associated blank. In the
event that the amount of a target analyte found in the samplesis twenty times the amount found in
the associated blank, the contribution from the blank can be considered negligible.
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Triangle Laboratories, Inc. August 24,1998
Case Narrative 46297
Sample Calculations:
Response Factor (RF) = (area analyte) x (amt IS)
(area IS) x (amt analyte)
Amount (ug) = (area analyte in sample) x (amt IS)
(area IS) x (avg ical RF)
Where:
amt IS = amount of internal standard = 0.25 ug
ical = initial calibration
The data in this package has been judged to be valid according to the guidelines of Methods 8260
and 5040 except as noted above. Should you have any questions, please feel free to contact our
Project Scientist, Deb. Smith, at (919) 544-5729, ext. 267.
For Triangle Laboratories, Inc.,
Report Preparation: Quality Control:
ft .
.
Valgena Respass Penny A. Brock
Report Preparation Chemist Report Preparation Chemist
The total number of pages in this data package is £$ 3 .
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Triangle Laboratories, Inc.
Sample Identification Index for Project: 46297
Client Tdt
File Manse:
T-V-1-l-A T
T-V-1-l-B TC
T-V-1-2-A T
T-V-1-2-B TC
T-V-1-3-A T
T-V-1-3-B TC
T-V-1-4-B TC
VOSTBLK081798
VOSTBLK081898
VOSTBLK081998
214-1-6A
214-1-6B
214-1-7A
214-1-7B
214-1-8A
214-1-8B
214-1-9B
VOSTBLK08179
VOSTBLK08189
VOSTBLK08199
FX883
FX879
FX895
FX880
HW713
FX882
FX881
FX878
FX894
HW705
Triangle Laboratories, Inc.
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Proj_Sum v4.0
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Triangle Laboratories, Inc.
Project Summary for Project 46297
Client ID: T-V-1-l-A
T
Filename : FX883
TLIId : 214-1-6A
Matrix : VOST
Units : ug
Chloromethane
Vinyl Chloride
Bromomethane
Chloroethane
Trichlorofluoromethane :
1 ,1 -Dichloroethene
Methylene chloride ft (,''J"^
trans- 1 ,2-Dichloroethene
1,1-Dichloroethane
cis-l,2-Dichloroethene
Chloroform
1,1,1-Trichloroethane
lodomethane
Carbon disulfide ;
Acetone ••• • '
Allyl chloride
Acrylonitrile
Vinyl acetate
2-Butanone
Carbon tetrachloride
Benzene
1 ,2-Dichloroethane
Trichloroethene
1,2-Dichloropropane
Bromodichloromethane
cis-l,3-Dichloropropene
Toluene •>.
trans-l,3-Dichloropropene
1 ,1 ,2-Trichloroethane
Methyl methacrylate
4-Methyl-2-pentanone
Tetrachloroethene
Dibromochloromethane
1,2-Dibromoethane
Chlorobenzene
(0.001)
(0.001)
(0.001)
(0.001)
4X008
v1"" (0.001)
^'" &3Q3
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
:'j;.:>-:r'"- &0t3
• '-•' ''$i&f
(0.001)
(0.015)
(0.002)
;, ••'.-, &o&
(0.001)
•' ,;':';:..r:'-0#i2
'••••'• "•' 0589
(0.001)
(0.003)
(0.001)
:..;•• :: > 0^9
(0.001)
.-• -::-'.:,: 9M6
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
.:v'
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Triangle Laboratories, Inc.
Project Summary for Project 46297
Client ID:
Filename :
TLIId :
Matrix :
Units :
Ethylbenzene :5v
m-/p-Xylene :-.';.?
o-Xylene v.
Styrene
Bromoform
2-Hexanone
Cumene
1,1,2,2-Tetrachloroethane
T-V-1-l-A
T
FX883
214-1-6A
VOST
ug
;.i::; •.:'•;&$$
';.""• "^'&®
-.• :"'":.'!:;-.l^^
(0.001)
(0.002)
(0.005)
(0.001)
(0.002)
T-V-1-l-B
TC
FX879
214-1-6B
VOST
ug
(0.001)
(0.001)
(0.001)
(0.001)
(0.003)
(0.006)
(0.001)
(0.003)
T-V-1-2-A
T
FX895
214-1-7A
VOST
ug
0428
0*77 |
033$
(0.001)
(0.003)
(0.006)
(0.001)
(0.002)
T-V-1-2-B
TC
FX880
214-1-7B
VOST
ug
(0.001) :
i::v:;3 &o«i :
(0.001)
(0.001)
(0.003)
(0.006)
(0.001)
(0.002)
T-V-1-3-A
T
HW713
214-1-8A
VOST
ug
8405
&75S
8.181
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
Triangle Laboratories, Inc.
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
( (-Estimated Detection Limit Page 2
Savarv3.7
Printed: 18:04:56 08/24/98
7
-------
Triangle Laboratories, Inc.
Project Summary for Project 46297
Client ID: T-V-1-3-B
TC
Filename : FX882
TLIId : 214-1-8B
Matrix : VOST
Units : ug
Chloromethane ; . \ '•
Vinyl Chloride
Bromomethane :.''•••'
Chloroethane
Trichlorofluoromethane
1 ,1 -Dichloroethene
Methylene chloride :•:
trans-l,2-Dichloroethene
1 ,1 -Dichloroethane
cis- 1 ,2-Dichloroethene
Chloroform
1,1,1-Trichloroethane
lodomethane
Carbon disulfide
Acetone r. •'..'
Allyl chloride
Acrylonitrile
Vinyl acetate
2-Butanone
Carbon tetrachloride
Benzene
1 ,2-Dichloroethane
Trichloroethene
1,2-Dichloropropane
Bromodichloromethane
cis- 1 ,3-Dichloropr opene
Toluene
trans-l^-Dichloropropene
1,1,2-Trichloroethane
Methyl methacrylate
4-Methyl-2-pentanone
Tetrachloroethene
Dibromochloromemane
1 ,2-Dibromoethane
Chlorobenzene
-::v> :-?'i^
(0.001)
&109
(0.001)
(0.001)
(0.001)
4626
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
:r;;;.-'|CfeQ06:
': ^.; l^yjj^1!
(0.001)
(0.016)
(0.002)
(0.004)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
0*00$
(0.001)
(0.002)
(0.006)
(0.005)
(0.001)
(0.001)
(0.002)
(0.001)
<
T-V-1-4-B VOSTBLK081
TC 798
FX881 FX878
214-1-9B VOSTBLK08179
VOST VOST
ug ug
•f^&'*mfa.
(0.001)
0-045
(0.001)
(0.001)
(0.001)
\'& "":]£$$$..
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
•'.•: :• •: : *y:.':jjj%j/J2
(0.001)
(0.016)
(0.002)
(0.004)
(0.001)
(o.ooi) !: '':::
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
&0t?
(0.001)
(0.002)
(0.006)
(0.005)
(0.001)
(0.001)
(0.001)
(0.001)
)-Estimated Detection Limit
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.004)
y v* w *y
(0.001)
(0.016)
(0.002)
(0.004)
(0.001)
Mssis ;,\i-:
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
0.005
(0.001)
(0.001)
(0.006)
(0.004)
(0.001)
(0.001)
(0.001)
(0.001)
Pages
VOSTBLK081
898
FX894
VOSTBLK08189
VOST
(0.001) i>: :;-y
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(O.ooi) .. ::
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.006)
\ v* w wy
(0.001)
(0.021)
(0.002)
(0.005)
(0.001)
.;.:;-: . !• «#&'
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
0-008
(0.002)
(0.002)
(0.007)
(0.006)
(0.001)
(0.001)
(0.002)
(0.001)
VOSTBLK081
998
HW705
VOSTBLK08199
VOST
-i;\T;,M03
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
.:..: 9,02
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.004)
(0.001)
(0.006)
(0.001)
(0.003)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
0.003
(0.001)
(0.001)
(0.002)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
Triangle Laboratories, Inc.
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Savar v3.!
Printed: 18:04:56 08/24/9)
-------
Client ID:
Triangle Laboratories, Inc.
Project Summary for Project 46297
T-V-1-3-B T-V-1-4-B VOSTBLK081
TC TC 798
VOSTBLK081
898
VOSTBLK081
998
Filename :
TLIId :
Matrix :
Units :
Ethylbenzene
m-/p-Xylene
o-Xylene
Styrene
Bromoform
2-Hexanone
Cumene
1 ,1 ,2,2-Tetrachloroethane
FX882
214-1-8B
VOST
ug
(0.001)
(0.001)
(0.001)
(0.001)
(0.003)
(0.006)
(0.001)
(0.003)
FX881
214-1-9B
VOST
"g
(0.001)
(0.001)
(0.001)
(0.001)
(0.002)
(0.006)
(0.001)
(0.002)
FX878
VOSTBLK08179
VOST
ug
(0.001)
(0.001)
(0.001)
(0.001)
(0.003)
(0.006)
(0.001)
(0.003)
FX894
VOSTBLK08189
VOST
ug
(0.001)
(0.001) l %
(0.001)
(0.001)
(0.004)
(0.008)
(0.001) •: :,:
(0.004)
HW705
VOSTBLK08199
VOST
ug
(0.001)
•::;;;;;':.;:vli@t
(0.001)
(0.001)
(0.001)
(0.002)
; I.. :.••• \-8ffll
(0.001)
( )-Estimated Detection Limit
Page 4
Triangle Laboratories, Inc.
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Savarv3.7
Printed: 18:04:56 08/24/98
-------
Triangle Laboratories, Inc.
Project Summary for Project 46297
Client ID:
Filename :
TLIId :
Matrix :
Units :
1,3-Butadiene
Vinyl bromide
MTBE
n-Hexane
1,2-Epoxybutane
Iso-Octane
Ethyl acrylate
T-V-1-l-A
TC
FX883
214-1-6A
VOST
Ug
(0.001)
(0.001)
(0.001)
'.'-..:;:...!..'. '..'.'.-QJLT?
(0.010)
(0.001)
(0.002)
T-V-1-l-B
TC
FX879
214-1-6B
VOST
ug
(0.001)
(0.001)
(0.001)
Q.M1
(0.011)
(0.001)
(0.003)
T-V-1-2-A
T
FX895
214-1-7A
VOST
Ug
(0.001)
(0.001)
(0.001)
&147
(0.015)
(0.001)
(0.004)
T-V-1-2-B
TC
FX880
214-1-7B
VOST
ug
(0.001)
(0.001)
(0.001)
0,001
(0.010)
(0.001)
(0.002)
T-V-1-3-A
T
HW713
214-1-8A
VOST
ug
(0.001)
(0.001)
&*£»
0*121
(0.011)
(0.001)
(0.001)
( )-Estimated Detection Limit Page 1
Triangle Laboratories, Inc.
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Savar v3.!
Printed: 18:34:39 08/24/9!
W
-------
Client ID:
Triangle Laboratories, Inc.
Project Stunmary for Project 46297
T-V-1-3-B T-V-1-4-B VOSTBLK081
TC TC 798
VOSTBLK081
898
VOSTBLK081
998
Filename :
TLIId :
Matrix :
Units :
FX882
214-1-8B
VOST
FX881
214-1-9B
VOST
ug
FX878 FX894 HW705
VOSTBLK08179 VOSTBLK08189 VOSTBLK08199
VOST VOST VOST
1,3-Butadiene
Vinyl bromide
MTBE
n-Hexane
1,2-Epoxybutane
Iso-Octane
Ethyl acrylate
(0.001)
(0.001)
(0.001)
(0.011)
(0.001)
(0.003)
(0.001)
(0.001)
(0.001)
0.004
(0.011)
(0.001)
(0.003)
(0.001)
(0.001)
(0.001)
(0.001)
(0.011)
(0.001)
(0.002)
(0.001)
(0.001)
(0.001)
(0.001)
(0.020)
(0.001)
(0.004)
(0.001)
(0.001)
(0.001)
0J0Q1
(0.017)
(0.001)
(0.001)
11
( )-Estimated Detection Limit Page 2
Triangle Laboratories, Inc.
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Savarv3.7
Printed: 18:34:39 08/24/98
-------
TRIANGLE LABORATORIES, INC.
LIST OF CERTIFICATIONS AND ACCREDITATIONS
ENVIRONMENTAL
American Association for Laboratory Accreditation. Accredidation pending. Certificate
Number 0226-01. Accreditation for technical competence in Environmental Testing. (Including
Waste Water, Sol/Haz Waste, Pulp/Paper, and Air Matrices) Parameters are AOX/TOX, and
Dioxin/Furan. Method 1613 for Drinking Water Currently re-applying..
State of Alabama, Department of Environmental Management. Expires December 31, 1998.
Laboratory I.D. # ^0950. Dioxin in drinking water.
State of Alaska, Department of Environmental Conservation. Expires December 21, 1998.
Certificate number OS-006-98. Dioxin in drinking water.
State of Arizona, Department of Health Services. Expires May 26, 1998. Certificate
#AZ0423. Drinking Water for Dioxin, Dioxin in WW and S/H Waste. Currently appying for
renewal.
State of Arkansas, Department of Pollution Control and Ecology. Expires February 19,
1999. Pulp/paper, soil, water, and Hazardous Waste for Dioxin/Furan; AOX/TOX, Volatiles,
Semi-volatiles, and Metals.
State of California, Department of Health Services. Expires August 31, 1999. Certificate
#1922. Selected Metals in Waste Water; Volatiles, Semi-volatiles, and Dioxin/furan in WW and
Sol/Haz Waste. Dioxin in drinking water.
State of Connecticut, Department of Health Services. Expires September 30, 1999.
Registration #PH-0117. Dioxin in drinking water.
Delaware Health and Social Services. Expires December 31,1998. Certificate #NC 140.
Dioxin in drinking water.
Florida Department of Health and Rehabilitative Services. Expires June 30, 1998. Dioxin in
SDW. Drinking Water ID HRS# 87424. Pending new certificate.
Triangle Laboratories, Inc.
Capitola Drive P.O. Box 13485
.*•• . Durham, NC 27713-4411 Research Triangle Park, NC 2770.
y:certmc\certlist.mem 919.544-5729 Fax #919-544-5491
-------
Hawaii Department of Health. Expires March 1, 1999. Dioxin in drinking water. "Accepted"
status for regulatory purposes.
Idaho Department of Health and Welfare. Expires December 31, 199S. Dioxin in drinking
water.
State of Kansas, Department of Health and Environment. Expires January 31, 1999.
Method 1613 for drinking water. ED #'s - Drinking water and/or pollution control - E-10215.
Solid or Hazardous Waste - E-101209.
Commonwealth of Kentucky, Department for Environmental Protection.
Expires December 31, 1998. ID#90060. Dioxin in drinking water.
Maryland Department of Health and Mental Hygiene. Expires September 30, 1998.
Certification #235 Drinking water by Method 1613 A. Currently applying for renewal.
State of Michigan, Department of Public Health. Expires June 30, 1999. Drinking water by
Method 1613. Current certification is extended, based on New York certificate renewal.
Mississippi State Department of Health. No expiration date. Dioxin in drinking water.
Montana Department of Health and Environmental Services. Expires December 31, 1998.
Dioxin in drinking water.
State of New Jersey, Department of Environmental Protection and Energy. Expires June 30,
1998. Extended until July 31, 1998 per letter dated May 29, 1998. ID #67851. BNAs and
Volatiles. Dioxin in drinking water. Currently applying for renewal.
State of New Mexico, Environment Department. Still certified, awaiting information from
A2LA Dioxin in drinking water.
New York State Department of Health. Received updated certificates. ED #11026.
Environmental Analyses of potable water, non-potable Water, Solid and Hazardous Waste.
Method 1613 in DW.
State of North Carolina, Department of Environment Health and Natural Resources
Expires. August 31, 1998. Certificate # 37751. Dioxin in drinking water.
State of North Carolina, Department of Environment, Health, and Natural Resources,
Division of Environmental Management. Expires December 31, 2000. Certificate # 485.
Metals, pesticides & PCBs, semi-volatiles and volatiles; TCLP.
Revised 8/3/98 dss
y: certific\certl ist. mem
13
-------
North Dakota State Department of Health and Consolidated Laboratories. Expires
December 31, 1998. Certificate # R-076. Effective October 4,1993. Dioxin in drinking water.
Oklahoma Department of Environmental Quality. Expires August 31, 1998. Laboratory
#9612. Dioxin by 1613 A, 8290 and 8280. Submitted renewal application 7/1.
State of South Carolina, Department of Health and Environmental Control. Expires
June 30, 1998. Extended August 31, 1999. Certificate number #99040001 (drinking water).
Expires August 31, 1999. Certificate number #99040002 (other parameters). Dioxin/Furans,
SNA, Volatiles, and PCBs/pesticides under Clean Water Act, 2,3,7,8-TCDD for Drinking Water,
and Organic extractables for Solid and Hazardous Waste.
State of Tennessee. Department of Environment and Conservation. Expires
February 5, 1999. ID #02992. Method 1613 Drinking water only.
U.S. Department of Agriculture Soil Permit Expires September 30, 2001. Permit No. S-
3790. Under the authority of the Federal Plant Pest Act, permission is granted to receive foreign
soil samples for use in laboratory analysis.
U.S. Army Corps of Engineers. Expires October 19, 1999. Validated to perform analyses for
the Fort Belvoir, VA (Contract Number DACA31-97-D-0029), Vint Hill Farms Station, Vint Hill,
VA (Contract Number DACA31-95-D-0083), and Selma Pressure Treating Superfund Site,
Selma, CA (Contract number DACW45-94-D-0054).
U.S. EPA Region V. Expires November 14, 1999. Dioxin in drinking water.
U.S. EPA Region Vm, for the State of Wyoming. Expires November 12, 1998. Dioxin in
drinking water.
State of Utah, Department of Health. Expires May 30,2000. Certificate Number E-166.
Certification for the following parameters: Semi-Volatiles and Volatiles under RCRA; Volatiles
under Clean Water Act; Dioxin/furans by Method 8280; Drinking water for Dioxin by Method
1613; Metals including Mercury and Microwave Digestion.
Commonwealth of Virginia, Department of General Services, Division of Consolidated
Laboratory Services. Expires June 30,1999. ID #00341. Dioxin in drinking water.
State of Washington, Department of Ecology. Expires September 11,1998. Lab
Accreditation Number C067. Scope of Accreditation applies to water analyses for
Revised 8/3/98 dss
y:certific\certlist. mem
-------
Polychlorinated Dibenzo-p-dioxins and Polychlorinated Dibenzofurans, SNA Extr (Semivolatile)
Organics and Purgeable (Volatile) Organics.
State of Washington, Department of Health. Expires April 30, 1999. Dioxin in drinking
water. Lab I.D. 129.
State of West Virginia, Department of Health. Expires December 31, 1998. Certificate No.
9923 (C). Dioxin in drinking water.
State of Wisconsin, Department of Natural Resources. Expires August 31, 1998. Laboratory
ID Number 999869530. Certification for the following categories of Organics: Purgeable,
Base/Neutral, Acid, PCBs, and Dioxin. Expires November 14, 1999. Laboratory ED 999869530.
Dioxin in drinking water.
PHARMACEUTICAL
Drug Enforcement Agency (DEA). Expires November 30, 1998. Registration number
RT01195835. Controlled substance registration for schedules 1,2,3,3N,4,5.
N.C. Department of Human Resources. Expires October 31, 1998. Registration number
NC-PT 0000 0031. North Carolina controlled substances registration. Application submitted for
renewal.
Food & Drug Administration (FDA) Registration. Expires June 1998. ID #'s 001500
1053481. Annual registration of drug establishment.
OTHER
Clinical Laboratory Improvement Amendments (CLIA) Registration. Expires May 30,
1999. ID # 34D0705123. Department of Health & Human Services, Health Care Financing
Administration.
U.S. EPA Large Quantity Hazardous Waste Generator. No expiration date. EPA ID
#NCD982156879. Permit indicates that the laboratory is a large generator of hazardous waste.
North Carolina General License for Radiation Protection. No expiration date. No License.
032-875-OG. The general license applies only to radioactive material contained in devices which
have been manufactured and labeled in accordance with specific requirements.
Revised 8/398
-------
DOCUMENT
CONTROL
Triangle Laboratories, Inc.
801 Capitols Drive P.O. Box 13485 ' —-•
Durham, NC 27713-4411 Research Triangle Park, NC 273
919-544-5729 Fax * 919-544-5491
-------
_._
O PACIFIC ENVIRONMENTAL SERVICES, INC.
Central Park West
5001 South Miami Boulevard, P.O. Box 12077
Research Triangle Park, North Carolina 27709-2077
(919) 941-0333 FAX: (919) 941-0234
Sample Chain of Custody Record
Sample
Identification
S-V-1-1-A
S-V-1-1-B
S-V-1-2-A
S-V-1-2-B
S-V-1-3-A
S-V-1-3-B
S-V-1-4-A
S-V-1-4-B
T-V-1-1-A
T-V-1-1-B
T-V-1-2-A
T-V-1-2-B
T-V-1-3-A
T-V-1-3-B
T-V-1-4-A
T-V-1-4-B
Collection
Date
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
Time
Sample
Name
Silo 2 Run 1 Set1
Silo 2 Run 1 Set1
Silo 2 Run 1 Set2
Silo 2 Run 1 Set2
Silo 2 Run 1 Set3
Silo 2 Run 1 Set3
Silo 2 Run 1 Set4
Silo 2 Run 1 Set4
Tunnel Run 1 Set 1
Tunnel Run 1 Set 1
Tunnel Run 1 Set 2
Tunnel Run 1 Set 2
Tunnel Run 1 Set 3
Tunnel Run 1 Set 3
Tunnel Run 1 Set 4
Tunnel Run 1 Set 4
Number of
Containers
1
1
1
1
1
1
1
Relinquished by
Relinquished by v — ^
Analytical Request
*'£?P
/s
^
/>
-^
fs
i~
•/,
V
A
/,
•i
-^
vl^
^
^
Date Time
f^l/W ^/2>~)
Date. Time
Comments
Tenax
Tenax/Charcoal
Tenax
Tenax/Charcoal
Tenax
Tenax/Charcoal
Tenax
Tenax/Charcoal
Tenax
Tenax/Charcoal
Tenax
Tenax/Charcoal
Tenax
Tenax/Charcoal
Tenax
Tenax/Charcoal
Received by:
Received for Lab by.
T/r
-------
Custody Seal : Absent Sample Seals: Absent ^^ ^ TLI
Chain of Custody : Present Container...: Intact /V^O /?"SN ("i~^YS\/y cli
Sample Tags : Absent \N>7 \N-^ I t~^^ II
Sample Tag Numbers: Not Listed on Chain of Custody ^•^ Y"** M ^ U |
SMO Forms : N/A j^/V^) / O C/'/xJ Dat
Project Number 46297
ent: PES03 - Pacific Environmental Services
e Received | 07/25/98 | By >j^2^2*4-
I 1 ^7/ ^- ^SJ^
.' BdT>k ||
.'•• U
J^- 1
^•PT
Ice Chest ICE/ICE PACKS Temp 6.0 C Carrier and Number j FedEx/ ' \1>' '1
TLI Number Client Sample ID Matrix) To LAB
mR/H:CPM Client COC ID . * Location . . | DatP/Init
I
1
|214-1-ZA S-V-1-l-A TENAX)
S-V-1-l-A R03 |
i
- 1
(214-1-1B S-V-1-l-B TNX/CHAR|
S-V-1-l-B R03 j
1
' • • 1
214-1-2A S-V-1-2-A TENAX)
S-V-1-2-A R03 |
I
I
214-1-2B S-V-1-2-B TNX/CHARJ
S-V-1-2-B R03 |
I
1
214-1-3A S-V-1-3-A TENAX)
S-V-1-3-A R03 |
|
1
214-1-3B S-V-1-3-B TNX/CIIAR)
S-V-1-3-B R03 |
1
214-1-4A S-V-1-4-A TENAX|
S-V-1-4-A R03 j
t
1
214-1-48 S-V-1-4-B TNX/CHAR)
S-V-1-4-B R03 j
j
214-1-5A S-V-1-3-A (Typed label) TENAX)
S-V-1-3-A (Typed label) R03 j
i
1
214-1-5B S-V-1-3-B (Typed label) TNX/CI1AR|
S-V-1-3-B (Typed label) R03 j
i
214-1-6A T-V-1-l-A TENAX|
T-V-1-l-A R03 j
1
214-1-6B T-V-1-l-B TNX/CHAR)
T-V-1-l-B R03 |
|
J214-1-7A T-V-1-2-A TEHAX |
j T-V-1-2-A R03 j
i i
1 1
|214-1-7B T-V-1-2-B TNX/CHAR|
| T-V-1-2-B R03 |
To STORAGE
Date/Init
To LAB
Date/Init
TO STORAGE| TO LAB
Date/Init Date/Init
i
\
To STORAGE
Date/Init
I To LAB
Date/Init
•
- -
I
To STORAGE j DISPOSED
Date/Init Date/In J.t
»
»
/
•
d
I
l
| Receiving Remarks: 2 set of samples labelled S-V-1-3-A & S-V-1-3-B arrived. ID~S were hand
| printed on 1 set and Typed on the other.
1
| Archive Remarks :
-------
=TRIANOLE LABORATORIES, INC, -- LOTS IN RECORD/CHAIN OF CUSTODY*-
H Custody Seal : Absent Sample Seals: Absent
|| Chain of Custody : Present Container . . • Intact
H S.imple Tags : Absent
| Sample Tag Numbers: Not Listed on Chain of Custody
| SMO Forms : N/A
TLI Project Number 46297 ,• f Book
Client: PES03 - Pacific Environmental Services . 1 ^'
f 214
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Date Received j 07/25/98 j *Y^fa£2*~l>~*^+ iPage
i i SJ* S JJ^^KSjr J^ a i 1
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| Ice Chest ICE/ICE PACKS Temp 6.0 C Carrier and Number | FedEx/ £^C^ j 1
UTLI Number Client Sample ID Matrix
||mR/H:CPM. Client COC ID * Location
.
R214-1-8A T-V-1-3-A TENAX
| T-V-1-3-A R03
R
(214-1-BB T-V-1-3-B TNX/CHAR
H T-V-1-3-B R03
H
||214-1-9A T-V-1-4-A TENAX
U T-V-1-4-A R03
JJ214-1-9B T-V-1-4-B TNX/CHAR
| T-V-1-4-B R03
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| Receiving Remarks: 2 set of samples labelled S-V-1-3-A & S-V-1-3-B arrived. ID'S were hand
|| printed on 1 set and Typed on the other.
II
|| Archive Remarks: ,' :'
-------
Triangle Laboratories, Inc.
Run Log
Column Type
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615-2661
Analysis*
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Column Type
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£-2-Go
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Run Log
Column Type
Column #
Analysis*
Acquisition
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GC Method'
Find DBs*
Other*
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Internal / Surrogate / Recovery Internal/ Surrogate / Recovery
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Page 26
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SRVR4\\AP\MSRL\LRRUNLOG DOC (KVI6/97)
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Page 96
-------
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