United States
Environmental Protection
Agency
Office of Air Quality
Planning and Standards
Research Triangle Park, NC 27711
EPA-454/R-00-025E
May 2000
AIR
&EPA
Final Report
Hot Mix Asphalt Plants
Truck Loading and Silo Filling
Manual Methods Testing
Asphalt Plant C
Los Angeles, California
Volume 5 of 8
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FINAL REPORT
HOT MIX ASPHALT PLANTS
TRUCK LOADING AND SILO FELLING
MANUAL METHODS TESTING
ASPHALT PLANT C, LOS ANGELES, CALIFORNIA
VOLUME 5 OF 8
APPENDIX G.3
EPA Contract No. 68-D-98-004
Work Assignment No. 3-02
Prepared for:
Mr. Michael L. Toney (MD-19)
Work Assignment Manager
SMTG, EMC, OAQPS
U.S. Environmental Protection Agency
Research Triangle Park, NC 27711
May 2000
Submitted by
PACD7IC ENVIRONMENTAL SERVICES, INC.
5001 S. Miami Blvd., Suite 300
Post Office Box 12077
Research Triangle Park, NC 27709-2077
(919) 941-0333
FAX (919) 941-0234
U.S. EnvironmenTe!) Protection
J::?i'jn?'LifcrarV(PL-12J)
fc^B^ard
U^O, ปL t>0t>04-3590
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DISCLAIMER
The information in this document has been funded wholly or in part by the Office of Air
Quality Planning and Standards, U.S. Environmental Protection Agency (EPA) under contract
to Pacific Environmental Services, Inc. (PES). PES performed the work presented in this
document under three EPA contracts and seven Work Assignments; EPA Contract No. 68-D-
98-004, Work Assignment Nos. 1-08,2-07,3-02, and 3-05, EPA Contract No. 68-D-70002,
Work Assignment Nos. 0-05 and 1-07, and EPA Contract No. 68-D-70069, Work Assignment
No. 2-16. This document has been prepared by PES, reviewed following PES' internal
quality assurance procedures, and approved by PES for distribution. This document has been
subjected to the Agency's review, and has been approved by EPA for publication as an EPA
document. Mention of trade names does not constitute endorsement by the EPA or PES.
11
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TABLE OF CONTENTS
VOLUME 1 Page
1.0 INTRODUCTION 1-1
2.0 SUMMARY OF TEST RESULTS 2-1
2.1 OVERVIEW 2-1
2.2 TREATMENT OF NON-DETECTS AND ESTIMATES 2-2
2.3 TUNNEL EXHAUST DUCT 2-2
2.4 SILO EXHAUST DUCT RESULTS 2-12
2.5 PM AND MCEM DEPOSITION ESTIMATES 2-15
2.6 METEOROLOGICAL STATION RESULTS 2-15
3.0 PROCESS DESCRIPTION 3-1
3.1 COORDINATION BETWEEN TESTING AND PROCESS
OPERATIONS 3-3
3.2 PROCESS MONITORING DURING TESTING 3-3
3.3 PROCESS SAMPLES 3-4
3.4 VELOCITY OF AIR ACROSS TOP OF TRANSPORT TRUCKS
DURING LOAD-OUT 3-5
4.0 SAMPLING LOCATIONS 4-1
4.1 TUNNEL EXHAUST DUCT 4-1
4.2 SILO EXHAUST DUCT 4-1
5.0 SAMPLING AND ANALYTICAL PROCEDURES 5-1
5.1 LOCATION OF MEASUREMENT SITES AND
SAMPLE/VELOCITY TRAVERSE POINTS 5-1
5.2 DETERMINATION OF EXHAUST GAS VOLUMETRIC
FLOW RATE 5-1
5.3 DETERMINATION OF EXHAUST GAS DRY MOLECULAR
WEIGHT 5-3
5.4 DETERMINATION OF EXHAUST GAS MOISTURE CONTENT 5-3
m
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TABLE OF CONTENTS (CONTINUED)
VOLUME 1 (CONTINUED^ Page
5.5 DETERMINATION OF PM AND MCEM 5-3
5.6 DETERMINATION OF VOHAPs 5-3
5.7 DETERMINATION OF SVOHAPs 5-7
5.8 DETERMINATION OF WIND SPEED, WIND DIRECTION,
AMBIENT TEMPERATURE, AND AMBIENT HUMIDITY 5-7
5.9 ESTIMATE OF PM AND MCEM ON THE CEILING
OF THE LOAD-OUT TUNNEL DOWNSTREAM OF SILO NO. 5 5-7
5.10 ESTIMATE OF PM AND MCEM DEPOSITION ON THE INSIDE
WALLS OF THE SILO NO. 2 EXHAUST PLENUM 5-9
5.11 ESTIMATE OF PM AND MCEM DEPOSITION ON THE INSIDE
WALLS OF THE SILO EXHAUST DUCT 5-9
5.12 ESTIMATE OF PM AND MCEM DEPOSITION ON THE INSIDE
WALLS OF THE TUNNEL EXHAUST DUCT 5-10
6.0 QUALITY ASSURANCE/QUALITY CONTROL (QA/QC) PROCEDURES
AND RESULTS 6-1
6.1 CALIBRATION AND PREPARATION OF APPARATUS 6-1
6.2 REAGENTS AND GLASSWARE PREPARATION 6-2
6.3 ON-SITE SAMPLING 6-3
6.4 SAMPLE RECOVERY 6-4
6.5 LABORATORY ANALYTICAL QA/QC PROCEDURES 6-5
6.6 QA COORDINATOR FIELD AUDIT 6-7
APPENDIX A - TEST RESULTS AND CALCULATIONS 1
A.1 TED TEST RESULTS 3
A.2 SED TEST RESULTS 101
A.3 EXAMPLE CALCULATIONS 195
A.4 PARTICIPATE DEPOSITION DATA 204
A.5 CAPTURE EFFICIENCY CALCULATIONS 211
VOLUME 2
APPENDIX B - PROCESS DATA 1
B. 1 PRODUCTION RECORDS FOR 7/24/98 THROUGH 7/28/98 3
B.2 PRODUCT STORAGE RECORDS FOR 7/25/98 THROUGH 7/28/98 9
IV
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TABLE OF CONTENTS (CONTINUED)
VOLUME 2 rCONTINUED^
APPENDIX B - PROCESS DATA (CONTINUED)
B.3 LOAD-OUT RECORDS USED IN TED EMISSION CALCULATIONS . . 19
B.4 LOAD-OUT RECORDS FOR 6/18/98 THROUGH 7/26/98 33
B.5 LOAD-OUT RECORDS FOR 7/24/98 THROUGH 7/28/98 44
B.6 SILO NO. 2 LOAD-IN RECORDS USED IN SED EMISSION
CALCULATIONS 68
B.7 ASPHALT TEMPERATURES AT LOAD-OUT 90
B.8 MASS CHANGE RESULTS FROM ASTM TESTS PERFORMED ON
ASPHALT CEMENT SAMPLES 93
B.9 VELOCITY OF AIR ACROSS TOP OF TRANSPORT TRUCKS
DURING LOAD-OUT 100
B.10 METALS ANALYSIS OF PROCESS SAMPLES 104
VOLUME 3
APPENDIX C - FIELD DATA 1
C.I TED FIELD DATA 2
C.2 SED FIELD DATA 59
C.3 METEOROLOGICAL STATION DATA 89
C.4 ON-SITE GC/MS REPORT AND DATA 118
APPENDIX D - QA/QC DATA 230
APPENDIX E - PROJECT PARTICIPANTS 280
APPENDIX F - TEST METHODS
F.I EPA METHOD 1
F.2 EPA METHOD 1A
F.3 EPA METHOD 2
F.4 EPA METHOD 4
F.5 EPA METHOD 18
F.6 EPA METHOD 315
F.7 SW-846 METHOD 0010
F.8 SW-846 METHOD 0030
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TABLE OF CONTENTS (CONCLUDED)
VOLUME 4
APPENDIX G - ANALYTICAL DATA 1
G.I PM AND MCEMDATA la
G.2 PAH/SVOHAPS CASE NARRATIVE AND PAH DATA Ik
VOLUMES
APPENDIX G - ANALYTICAL DATA (CONTINUED) 659
G.3 SVOHAPS DATA 659
VOLUME 6
APPENDIX G - ANALYTICAL DATA (CONTINUED) 1248
G.3 SVOHAPS DATA (CONCLUDED) 1248
VOLUME?
APPENDIX G - ANALYTICAL DATA (CONTINUED) la
G.4 VOHAPS DATA Ic
VOLUMES
APPENDIX G - ANALYTICAL DATA (CONCLUDED) la
G.4 VOHAPS DATA (CONCLUDED) Ic
G.5 EPAMETHOD 18 REPORT AND DATA 260
VI
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LIST OF TABLES
Page
Table 1.1 Test Log Tunnel Exhaust Duct, Asphalt Plant C - California 1-4
Table 1.2 Test Log Silo Exhaust Duct, Asphalt Plant C - California 1-5
Table 2.1 Summary of Results, Production Emissions for PM, MCEM, PAH,
SVOHAP and VOHAP, Asphalt Plant C, California - July 1998 2-3
Table 2.2 Summary of Results, Average PM and MCEM Emissions,
Asphalt Plant C, California - July 1998 2-4
Table 2.3 Summary of Results, Average PAH and SVOHAP Emissions,
Asphalt Plant C, California - July 1998 2-5
Table 2.4 Summary of Results, Average VOHAP Emissions,
Asphalt Plant C, California - July 1998 2-6
Table 2.5 Summary of Results, PAHS, SVOHAPS, & VOHAPS Average
Emissions, Silo Exhaust Duct - Asphalt Plant C, California, July 1998 .... 2-7
Table 2.6 PM and MCEM Emissions Sampling and Exhaust Gas Parameters
Normal Operations, Tunnel Exhaust Duct, Asphalt Plant C - California . . 2-16
Table 2.7 PM and MCEM Exhaust Gas Concentrations and Emission Rates, Normal
Operations, Tunnel Exhaust Duct, Asphalt Plant C - California 2-17
Table 2.8 . PAHs and Semi-Volatile Organics Emissions Sampling and
Exhaust Gas Parameters, Normal Operations, Tunnel Exhaust Duct,
Asphalt Plant C - California 2-18
Table 2.9 PAHs Exhaust Gas Concentrations and Emission Rates, Normal
Operations Tunnel Exhaust Duct, Asphalt Plant C - California 2-19
Table 2.10 Semi-Volatile Organics Exhaust Gas Concentrations and Emission Rates,
Normal Operations, Tunnel Exhaust Duct, Asphalt Plant C - California . . 2-21
Table 2.11 Volatile Organics - SW-846 Method 0030 Emissions Sampling and
Exhaust Gas Parameters, Normal Operations, Tunnel Exhaust Duct,
Asphalt Plant C - California 2-30
Table 2.12 Volatile Organics - SW-846 Method 0030 Exhaust Gas Concentrations
and Emission Rates, Normal Operation, Tunnel Exhaust Duct,
Asphalt Plant C - California 2-31
Table 2.13 Volatile Organics - EPA Method 18 Emissions Sampling and
Exhaust Gas Parameters, Normal Operations, Tunnel Exhaust Duct,
Asphalt Plant C - California 2-36
Table 2.14 Volatile Organics - EPA Method 18 Exhaust Gas Concentrations
and Emission Rates, Normal Operations, Tunnel Exhaust Duct,
Asphalt Plant C - California 2-37
Table 2.15 On-Site GC/MS Volatile Organics Exhaust Gas Concentrations and
Emission Rates with Vost (SW-846 Method 0030) and EPA Method 18
Comparison, Tunnel Exhaust Duct, Asphalt Plant C - California 7/24/98 . 2-38
Table 2.16 PM and MCEM Emissions Sampling and Exhaust Gas Parameters,
Background Condition, Tunnel Exhaust Duct, Asphalt Plant C - California 2-39
Vll
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LIST OF TABLES (CONTINUED)
Page
Table 2.17 PM and MCEM Exhaust Gas Concentrations and Emission Rates,
Background Condition, Tunnel Exhaust Duct, Asphalt Plant C - California 2-40
Table 2.18 PAHs and Semi-Volatile Organics Emissions Sampling and Exhaust Gas
Parameters Background Condition, Tunnel Exhaust Duct,
Asphalt Plant C - California 2-41
Table 2.19 PAHs Exhaust Gas Concentrations and Emission Rates, Background
Condition, Tunnel Exhaust Duct, Asphalt Plant C - California 2-42
Table 2.20 Semi-Volatile Organics Exhaust Gas Concentrations and Emission Rates,
Background Condition, Tunnel Exhaust Duct, Asphalt
Plant C - California 2-44
Table 2.21 Volatile Organics - SW-846 Method 0030 Emissions Sampling and
Exhaust Gas Parameters, Background Condition, Tunnel Exhaust Duct,
Asphalt Plant C - California 2-53
Table 2.22 Volatile Organics - SW-846 Method 0030 Exhaust Gas Concentrations
and Emission Rates, Background Condition, Tunnel Exhaust Duct,
Asphalt Plant C - California 2-54
Table 2.23 Volatile Organics - EPA Method 18 Emissions Sampling and Exhaust Gas
Parameters, Background Condition, Tunnel Exhaust Duct, Asphalt
Plant C - California 2-59
Table 2.24 Volatile Organics - EPA Method 18 Exhaust Gas Concentrations and
Emission Rates, Background Condition, Tunnel Exhaust Duct,
Asphalt Plant C - California 2-60
Table 2.25 Sample Log Silo Exhaust Duct, Asphalt Plant C - California 2-61
Table 2.26 PM and MCEM Emissions Sampling and Exhaust Gas Parameters,
Silo Exhaust Duct, Asphalt Plant C - California 2-62
Table 2.27 PM and MCEM Exhaust Gas Concentrations and Emission Rates,
Silo Exhaust Duct, Asphalt Plant C - California 2-63
Table 2.28 PAHs and Semi-Volatile Organics Emissions Sampling and Exhaust Gas
Parameters, Silo Exhaust Duct, Asphalt Plant C - California 2-64
Table 2.29 PAHs Exhaust Gas Concentrations and Emission Rates, Silo Exhaust Duct,
Asphalt Plant C - California 2-65
Table 2.30 Semi-Volatile Organics Exhaust Gas Concentrations and Emission Rates,
Silo Exhaust Duct, Asphalt Plant C - California 2-67
Table 2.31 Volatile Organics - SW-846 Method 0030 Emissions Sampling and
Exhaust Gas Parameters, Silo Exhaust Duct, Asphalt Plant C - California . 2-76
Table 2.32 Volatile Organics - SW-846 Method 0030 Exhaust Gas Concentrations
and Emission Rates, Silo Exhaust Duct, Asphalt Plant C - California .... 2-77
Table 2.33 On-Site GC/MS Volatile Organics Exhaust Gas Concentrations and
Emission Rates with Vost (SW-846 Method 0030) Comparison,
Silo Exhaust Duct, Asphalt Plant C - California 7/25/98 2-82
Table 2.34 PM and MCEM Deposition Estimates, Asphalt Plant C - California 2-83
viii
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LIST OF TABLES (CONCLUDED)
Page
Table 2.35 Meteorological Data Summary, Asphalt Plant C - California 2-84
Table 3.1 Load-out Data Used in TED Emission Calculations 3-6
Table 3.2 Load-in Data for Silo No. 2 Used in SED Emission Calculations 3-7
Table 3.3 Asphalt Temperatures at Load-out, Asphalt Plant C, California 3-8
Table 3.4 Mass Change of Asphalt, Asphalt Plant C, California 3-9
Table 3.5 Results of Metals Analyses of Asphalt Samples, Asphalt Plant C,
California 3-10
Table 3.6 Air Velocity Over Transport Trucks During Load-out, Asphalt Plant C,
California 3-11
Table 5.1 Summary of Sampling and Analytical Methods, Asphalt Plant C,
California 5-2
Table 6.1 Summary of Temperature Sensor Calibration Data 6-8
Table 6.2 Summary of Pitot Tube Dimensional Data 6-9
Table 6.3 Summary of Dry Gas Meter and Orifice Calibration Data 6-10
Table 6.4 Summary of EPA Method 315 and SW-846 Method 0010
Field Sampling QA/QC Data 6-11
Table 6.5 Summary of EPA Method 315 Blank Sample Catches 6-12
Table 6.6 SW-846 Method 0010 PAHs Field and Laboratory Blanks Results,
Tunnel Exhaust Duct 6-13
Table 6.7 SW-846 Method 0010 PAHs Field and Laboratory Blanks Results,
Silo Exhaust Duct 6-14
Table 6.8 SW-846 Method 0010 PAHs Surrogate Recovery Results,
Tunnel Exhaust Duct 6-15
Table 6.9 SW-846 Method 0010 Semi-Volatile Surrogate Recovery Results
Tunnel Exhaust Duct 6-16
Table 6.10 SW-846 Method 0010 PAHs Surrogate Recovery Results,
Silo Exhaust Duct 6-17
Table 6.11 SW-846 Method 0010 Semi-Volatile Surrogate Recovery Results
Silo Exhaust Duct 6-18
Table 6.12 SW-846 Method 003 0 Field and Laboratory Blanks Results
Tunnel Exhaust Duct 6-19
Table 6.13 SW-846 Method 0030 Laboratory Blank Results, Silo Exhaust Duct 6-20
Table 6.14 SW-846 Method 0030 Surrogate Recovery Results
Tunnel Exhaust Duct 6-21
Table 6.15 SW-846 Method 0030 Surrogate Recovery Results
Silo Exhaust Duct 6-22
IX
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LIST OF FIGURES
Page
Figure 1.1 Project Organization - US EPA Hot Mix Asphalt Load-out Operation,
Asphalt Plant C, California 1-6
Figure 2.1 Load-out Tunnel and MET Station Location and Average Wind Direction 2-85
Figure 3.1 Process Flow Schematic, Asphalt Plant C, California 3-2
Figure 3.2 Velocity Measurement Locations and Dimensions of Transport Trucks ... 3-12
Figure 4.1 Tunnel Exhaust Duct Sampling Locations, Asphalt Plant C, California .... 4-2
Figure 4.2 Tunnel Exhaust Duct Traverse Point Locations,
Asphalt Plant C, California 4-3
Figure 4.3 Silo Exhaust Duct Sampling Locations, Asphalt Plant C, California 4-4
Figure 4.4 Silo Exhaust Duct Traverse Point Locations, Asphalt Plant C, California . . 4-5
Figure 5.1 EPAMethod 315 Sampling Train Schematic 5-4
Figure 5.2 SW-846 Method 0030 Sampling Train Schematic 5-6
Figure 5.3 SW-846 Method 0010 Sampling Train Schematic 5-8
Figure 5.4 Location of TED Deposition Test Plates T,, T2, and T3 5-11
GLOSSARY OF TERMS
ASTM - American Society for Testing and Materials
CEMS - Continuous Emissions Monitoring System
CTS - Calibration Transfer Standard
EMC - Emissions Measurement Center
EMAD - Emission Monitoring and Analysis Division
ESP - Electrostatic Precipitator
FID - Flame lonization Detector
FTIR - Fourier Transform Infrared Spectroscopy
HAP - Hazardous Air Pollutant
MCEM - Methylene Chloride Extractable Matter
MRI - Midwest Research Institute
PES - Pacific Environmental Services
PM - Particulate Matter
PTE - Permanent Total Enclosure
RAP - Recycled Asphalt
RTFOT - Rolling Thin Film Oven Test
SED - Silo Exhaust Duct
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GLOSSARY OF TERMS (CONTINUED)
SMTG - Source Measurement Technology Group
SVOHAP - Semi-Volatile Organic Hazardous Air Pollutant
TED - Tunnel Emissions Duct
TFOT - Thin Film Oven Test
THC - Total Hydrocarbons
VOHAP - Volatile Organic Hazardous Air Pollutant
VOST - Volatile Organic Sampling Train
XI
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VOLUME 5A
APPENDIX G
ANALYTICAL DATA (CONTINUED)
G.3 SVOHAPS DATA
-------
orgmics Raw Data P Age
-------
Sample Data.
u
-------
Client Name:
Client ID:
LAB ID:
Matrix:
Authorized:
Semivolatile Organics
Method 0010/8270
Pacific Environmental Services
S-MM5-2-F,FH,XAD,COND,BH
300681-0001-SA
AIRTRAIN Sampled: 25 JUL 98
30 JUL 98 Prepared: 31 JUL 98
Dilution Factor: 100
Parameter
Phenol
bis(2-Chloroethyl)ether
2-Chlorophenol
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Benzyl alcohol
1,2-Dichlorobenzene
2-Methylphenol
2,2'-Oxybi s(1-chloropropane)
3/4-Methylphenol
N-Nitroso-di-n-propylamine
Hexachloroethane
Nitrobenzene
Isophorone
2-Nitrophenol
2,4-Dimethylphenol
Benzoic acid
bi s(2-Chl oroethoxy)-methane
2,4-Dichlorophenol
1,2,4-Trichlorobenzene
Naphthalene
4-Chloroaniline
Hexachl orobutadi ene
4-Chloro-3-methyl phenol
2-Methyl naphtha!ene
Hexachlorocyclopentadi ene
2,4,6-Trichlorophenol
2,4,5-Trichlorophenol
2-Chloronaphthalene
2-Nitroaniline
Dimethyl phthalate
Acenaphthylene
3-Nitroaniline
Acenaphthene
2,4-Dinitrophenol
Wet wt.
Result
Units
Received: 30 JUL 98
Analyzed: 31 AUG 98
Reporting
Limit
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1600
ND
ND
ND
3600
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sampl e
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sampl e
ug/Sample
ug/Sample
ug/Sample
ug/Sample
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
15000
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
15000
3000
3000
3000
3000
15000
3000
15000
Qualifier
GR
Note G = Reporting limit(s) raised due to matrix interference.
Note J = Result is detected below the reporting limit or is an estimated concentration.
Note R = Reporting limit(s) raised due to sample volume limitations.
ND = Not Detected
Reported By: Emily Uebelhoer
Approved By: Mike Orbanosky
The cover letter is an integral part of this report.
Rev 230787
CCi
-------
Semi volatile Organics
Method 0010/8270
(cont.)
Client Name: Pacific Environmental Services
Client ID:
LAB ID:
Matrix:
Authorized:
S-MM5-2-F,FH,XAD,COND,BH
300681-0001-SA
AIRTRAIN
30 JUL 98
Sampled: 25 JUL 98
Prepared: 31 JUL 98
Dilution Factor: 100
Parameter
4-Nitrophenol
Dibenzofuran
2,4-Dinitrotoluene
2,6-Dinitrotoluene
Diethyl phthalate
4-Chlorophenyl phenyl ether
Fluorene
4-Nitroaniline
4,6-Dinitro-2-methylphenol
N-Nitrosodiphenylamine
4-Bromophenyl phenyl ether
Hexachlorobenzene
Pentachlorophenol
Phenanthrene
Anthracene
Di-n-butyl phthalate
Fluorantnene
Pyrene
Butyl benzyl phthalate
3,3'-Dichlorobenzidine
Benzo(a)anthracene
bi s(2-Ethylhexyl)-phthalate
Chrysene
Di-n-octyl phthalate
Benzo
Benzo
Benzo,
Indeno(
fluoranthene
fluoranthene
pyrene
,2,3-cd)pyrene
Dibenz(a,h)anthracene
Benzo(g,h,i)perylene
Acetopnenone
4-Aminobiphenyl
Aniline
Benzidine
3,3'-Dimethylbenzidine
N-Nitrosodimethylamine
N-Nitrosomorpholine
Wet wt.
Result
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
950
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Units
ug/Sampl e
ug/Sampl e
ug/Sampl e
ug/Sampl e
ug/Sampl e
ug/S ample
ug/ Sample
ug/Sampl e
ug/S ample
ug/S ample
ug/Sampl e
ug/Sampl e
ug/Sampl e
ug/Sampl e
ug/Sampl e
ug/Sampl e
ug/S ample
ug/Sampl e
ug/Sampl e
ug/Sampl e
ug/Sampl e
ug/Sampl e
ug/Sampl e
ug/Sampl e
ug/Sampl e
ug/Sampl e
ug/Sampl e
ug/Sampl e
ug/Sampl e
ug/Sampl e
ug/S ample
ug/Sampl e
ug/Sampl e
ug/Sampl e
ug/Sampl e
ug/S ample
ug/Sampl e
Reporting
Limit
15000
3000
3000
3000
3000
3000
3000
15000
15000
3000
3000
3000
15000
3000
3000
3000
3000
3000
3000
6000
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
15000
3000
30000
6000
3000
3000
Received: 30 JUL 98
Analyzed: 31 AUG 98
Qualifier
Note J = Result is detected below the reporting limit or is an estimated concentration.
ND - Not Detected
Reported By: Emily Uebelhoer
Approved By: Mike Orbanosky
The cover letter is an integral part of this report.
Rev 230787
fcC
-------
Semi volatile Organics
Method 0010/8270
(cont.)
Client Name:
Client ID:
LAB ID:
Matrix:
Authorized:
Pacific Environmental Services
S-MM5-2-F,FH,XAD,COND,BH
300681-0001-SA
AIRTRAIN Sampled:
30 JUL 98 Prepared:
25 JUL 98
31 JUL 98
Dilution Factor: 100
Parameter
Pentachloronitrobenzene (PCNB)
o-Toluidine
2-Methoxybenzenamine
Biphenyl
Chloroacetophenone
Cumene
DBCP (l,2-Dibromo-3-chloropropane)
Benzo(e)pyrene
N-N-Diethylaniline
Dimethyl aniline
3,3'-Dimethoxybenzidine
Hydroquinone
4,4'-Methyl-bis(2-chloroaniline)
4-Nitrodiphenyl
Trifluralin
Wet wt.
Result
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Units
ug/Sample
ug/ Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sampl e
ug/Sample
ug/Sample
ug/Sample
Reporting
Limit
15000
6000
--
--
--
--
--
--
--
--
--
--
--
--
--
Received: 30 JUL 98
Analyzed: 31 AUG 98
Qualifier
Surrogate
Nitrobenzene-d5
2-Fluorobiphenyl
Terphenyl-dl4
Phenol-d5
2-Fluorophenol
2,4,6-Tri bromophenol
Recovery
ND %
ND %
ND %
ND %
ND %
ND %
Acceptable Range
45 - 107
62 - 110
58 - 135
43 - 130
36 - 111
58 - 131
ND = Not Detected
Reported By: Emily Uebelhoer
Approved By: Mike Orbanosky
The cover letter is an integral part of this report.
Rev 230787
-------
Semivolatiles Library Search (20 Compound TID)
Method 8270
Client Name: Pacific Environmental Services
Client ID:
LAB ID:
Matrix:
Authorized:
S-MM5-2-F,FH,XAD,COND,BH
300681-0001-SA
AIRTRAIN
30 JUL 98
Sampled: 25 JUL 98
Prepared: NA
Dilution Factor: 100
Parameter
Unknown alkane
Unknown
Unknown PAH
Unknown alkene
Undecane
Unknown
Dodecane, 2,6,10-trimethyl-
Tetradecane
Unknown alkene
Heptadecane, 2,6,10,14 -tetramethyl-
Undecane, 2-methyl-
Unknown alkane
Nonadecane
Heptadecane, 2,6-dimethyl-
Heptadecane, 2,6-dimethyl-
Heptadecane, 2,6-dimethyl-
2,6-dimethyl-
Heptadecane,
Nonadecane
Heptadecane,
Nonadecane
2,6,10,14 -tetramethyl-
Result
7900
13000
15000
8900
8600
8400
17000
22000
12000
18000
19000
13000
24000
15000
32000
10000
14000
7700
9700
7500
Units
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
Received: 30 JUL 98
Analyzed: 31 AUG 98
Reporting
Limit
Qualifier
0
0
0
0
0
0
0
0
0
0
0
0
Note 0 = Or structurally similar compound (isomer).
NA = Not Applicable
Reported By: Emily Uebelhoer
Approved By: Mike Orbanosky
The cover letter is an integral part of this report.
Rev 230787
e
-------
OUANTERRA GC/HS
Target Compound Data Summary Sheet
Sample: S-MM5-2 1/3SA/100M 1NST. ID:
Client: PAC1F1
Analyst: DAT Instrument ID: F16
Quan List Threshold: 0.95
Data File: 30068101
Std Id: ST16980831
F16
Date Analyzed: PB'31/98 19:00
Run Factor: 300.
Surrogate Vol.: 100.
Surrogate
===s==========
CS20 NITROBENZENE-05
CS25 2-FLUOROBIPHENY
CS30 TERPHENYL-D14
CS45 PHENOL-D5
CS50 2-FLUOROPHENOL
CS55 2,4,6-TRIBROMOP
Surrogate Spike Recoveries
8270-G, LIMS 10/10/96
Surrogate Amount (ug)
Spiked Measured
X Recovery
Measured QC limits
-05
ENY
4
OL
MOP
50.0
50.0
50.00
100.
100.
100.0
BDL
BDL
135.0
BDL
BDL
120.0
120.
Target Compounds: SAP9
Parameter Scan
HEXACHLOROBENZENE-C13
C310 N-NITROSOOIMETHYLAMINE
PYRIDINE
2-P1COL1NE
N-NITROSOMETHYLETHYLAMINE
METHYLMETHANESULFONATE
N-NITROSOOIETHYLAMINE
ETHYLMETHANE SULFONATE
PENTACHLOROETHANE
C320 ANILINE
C315 PHENOL
C325 BIS(2-CHLOROETHYL)ETHER
C330 2-CHLOROPHENOL
C335 1,3-DlCHLOROBENZENE
C340 1,4-DICHLOROBENZENE
C345 BENZYL ALCOHOL
C350 1,2-D1CHLOROBENZENE
C355 2-METHYLPHENOL
C360 2,2'-OXYBIS(1-CLPROPAN)
C361 ACETOPHENONE
N-NITROSOPYRROLIDINE
N-NITROSOMORPHOLINE
3-METHYL PHENOL
C365 4-METHYLPHENOL
C370 N-NITROSO-DI-N-PROPYLAM
0-TOLUIDINE
C375 HEXACHLOROETHANE
C410 NITROBENZENE
N-N1TROSOPIPERID1NE
Reporting
n Result
Units
ND UG/A
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
Reviewed by:
Limit
3000.
3000.
6000.
3000.
3000.
3000.
3000.
3000.
3000.
3000.
3000.
3000.
3000.
3000.
3000.
= = =
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
3000.0
3000.
3000.
3000.
3000.
3000.
3000.
3000.
3000.
3000.
3000.
3000.
3000.
3000.
J\AAM^
0
0
0
0
0
0
0
0
0
0
0
0
0
*(
I
-------
OUANTERRA GC/MS
Target Compound Data Summary Sheet
Sample: S-MM5-2
Client: PACIFI
Analyst: DAT
1/3SA/100M
1NST. ID:
Instrument ID: F16
Data File: 30068101
Std Id: ST16980831
F16
Date Analyzed: 08/31/98 19:00
Run Factor: 300.
Quan List Threshold: 0.95
Surrogate Vol.:
100.
Target Compounds: SAP9
Parameter
Scan
C415 ISOPHORONE
C420 2-NITROPHENOL
C425 2,4-DIMETHYLPHENOL
C435 BIS(2-CHLOROETHOXY)METH
C440 2,4-DICHLOROPHENOL
C430 BENZ01C ACID
AA-D1METHYLPHENETHYLAMINE
C445 1,2,4-TRICHLOROBENZENE
C450 NAPHTHALENE
C455 4-CHLOROANALINE
2,6-DICHLOROPHENOL
HEXACHLOROPROPENE
C460 HEXACHLOROBUTADIENE
P-PHENYLENE DIAMINE
N-NITROSOOI-N-BUTYLAMINE
C465 4-CHLORO-3-METHYLPHENO
SAFROLE
C470 2-METHYLNAPHTHALENE
1,2,4,5- TETRACHLOROBENZENE
ISOSAFROLE (#1)
C510 HEXACHLOROCYCLOPENTADI
C515 2,4,6-TRICHLOROPHENOL
C520 2,4,5-TRICHLOROPHENOL
ISOSAFROLE (#2)
C525 2-CHLORONAPHTHALENE
1 -CHLORONAPHTHALENE
C530 2-NITROANALINE
1,4-NAPHTHOOUINONE
C535 DIMETHYLPHTHALATE
1,3-DINITROBENZENE
C540 ACENAPHTHYLENE
C543 2,6-DlNITROTOLUENE
C545 3-NITROANILINE
C550 ACENAPHTHENE
C555 2,4-DINITROPHENOL
C565 DIBENZOFURAN
C560 4-NITROPHENOL
PENTACHLOROBENZENE
C570 2,4-DINITROTOLUENE
1-NAPHTHYLAMINE
2-NAPHTHYLAMINE
2,3,4,6-TETRACHLOROPHENOL
C580 DIETHYLPHTHALATE
C590 FLUORENE
652
A#
Result
ND
ND
ND
ND
ND
ND
ND
ND i/- '
-ar/6oo
Units
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
XJG/A
JIG/A
NB" UG/A
ND
ND
ND
ND
ND
ND
Mt-^
;*3600.^>
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND JV-j^
o -xfWQ)
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
Reporting
Limit
3000.0
3000.0
3000.0
3000.0
3000.0
15000.0
3000.0
3000.0
3000.0
3000.0
3000.0
3000.0
3000.0
3000.0
3000.0
3000.0
3000.0
3000.0
3000.0
6000.0
3000.0
3000.0
3000.0
6000.0
3000.0
1500.0
15000.0
3000.0
3000.0
3000.0
3000.0
3000.0
15000.0
3000.0
15000.0
3000.0
15000.0
3000.0
3000.0
3000.0
3000.0
6000.0
3000.0
3000.0
-------
OUANTERRA GC/MS
Target Compound Data Summary Sheet
Sample: S-MM5-2 1/3SA/100M INST. ID:
Client: PAC1FI
Analyst: DAT Instrument ID: F16
Quan List Threshold: 0.95
Target Compounds: SAP9
Data File: 30068101
Std Id: ST16980831
F16
Date Analyzed: 08/31/98 19:00
Run Factor: 300.
Surrogate Vol.: 100.
Parameter
Scan
C585 4-CHLOROPHENYL-PHENYLE
5-NITRO-O-TOLUIDINE
C595 4-NITROANAL1NE
C610 4.6-DINITRO-2-METHYLPH
C615 N-NITROSOOIPHENYLAMINE
C620 AZOBENZENE
SYM-TRINITROBENZENE
C625 4-BROMOPHENYL-PHENYLET
PHENACETIN
D1ALLATE 234
C630 HEXACHLOROBENZENE
4-AMINOB1PHENYL
C635 PENTACHLOROPHENOL
PRONAMIDE
PENTACHLORONITROBENZENE
C640 PHENANTHRENE
C645 ANTHRACENE
2SECBUTYL-4.6-DIN1TROPHENOL
C647 CARBAZOLE
C650 DI-N-BUTYLPHTHALATE
4-NITROOUINOLINE-1-OXIDE
METHAPYRILENE
ISODRIN
C655 FLUORANTHENE
CHLOROBENZILATE
C710 BENZIDINE
C715 PYRENE
ARAMITE (#1)
ARAMITE (#2)
P-DIMETHYLAMINOAZOBENZENE
3,3'-DIMETHYLBENZIDINE
KEPONE
C720 BUTYLBENZYLPHTHALATE
2-ACETYLAMINOFLUORENE
C730 BENZO(A)ANTHRACENE
C725 3,3'-DICHLOROBENZIDINE
C740 CHRYSENE
C745 BIS(2-ETHYLHEXYL)PHTHA
3-METHYLChOLANTHRENE
C760 DI-N-OCTYL PHTHALATE
C765 BENZO(8)FLUORANTHENE
7,12-DIMETHYLBENZANTHRACENE
C770 BENZO(K)FLUORANTHENE
HEXACHLOROPHENE
Result
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND ^
jtfฐl&
N&-1--
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Units
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
^UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
Reporting
Limit
3000.0
3000.0
15000.0
15000.0
3000.0
3000.0
3000.0
3000.0
3000.0
3000.0
3000.0
3000.0
15000.0
3000.0
15000.0
3000.0 T
3000.0
3000.0
3000.0
3000.0
3000.0
3000.0
3000.0
3000.0
3000.0
30000.0
3000.0
3000.0
3000.0
3000.0
3000.0
15000.0
3000.0
3000.0
3000.0
6000.0
3000.0
3000.0
3000.0
3000.0
3000.0
3000.0
3000.0
3000.0
-;*-'
-------
OUANTERRA GC/HS
Target Compound Data Summary Sheet
Sample: S-MM5-2
Client: PACIF1
Analyst: DAT
1/3SA/100M
INST. ID:
Instrument ID: F16
Data File: 30068101
Std Id: ST16980831
F16
Date Analyzed: 08/31/98 19:00
Run Factor: 300.
Quan List Threshold: 0.95
Surrogate Vol.:
100.
Target Compounds: SAP9
Parameter
Scan Result
Reporting
Limit
C775 BENZO(A)PYRENE
C780 INDENO(1,2,3-CD)PYRENE
C785 DIBEN2(A,H)ANTHRACENE
C790 BฃNZO(G,H,1)PERYLENE
ND
ND
ND
ND
UG/A
UG/A
UG/A
UG/A
3000.0
3000.0
3000.0
3000.0
bi
-------
DATA FROM FILE: 38068181 SCANS 93 TO 1203 ACQUIRED: 08/31/98 19:08:00
CALI: 30068101 #3
SAMPLE: S-MM5-2 1/3SA/100M INST. ID: F16
CONDS.: UG/ML *100ML * 10072/100?. */l/3SA NA M
200
2:13
[TC
j_
j_
JL
J
100.02 < 1069060.)
CI30 1.4-DICHLOROBENZENE-D4 152IS1* 01
CI40 NAPHTHALENE-08
136IS2# 01
2-FLUOROBIPHENYL 172SS3# 03
TC
150 ACENAPHTHENE-D10 164IS3* 01
3855-82-1
1146-65-2
321-60-8
15067-26-2
c:
C";
CD
-------
DATA FROM FILE: 30068101
SCANS 1203 TO 2158 ACQUIRED: 08/31/98 19:00:00
CALI: 30068101 #3
SAMPLE: S-MM5-2 1/3SA/100M INST. ID: F16
CONDS.: UG/ML *100ML *100Z/100Z *
-------
STANDARD USED FOR THIS REPORT IS ST16980831 REPORT PRINTED: 9/01/98 11:51:51
ADDITIONAL STANDARD USED FOR THIS REPORT IS: ST16980831A
OUANTERRA QUANT I TAT ION SUMMARY File: 30068101
Sample: S-
MM5-2 1/3SA/100H
Analyst: DAT Instrument
lompounds with amounts less than 0
No
1
2
3
i.
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
Library
Entry
S1# 1
S2# 1
S3# 1
S4# 1
S5# 1
S6# 1
S2# 2
S3# 3
S5# 2
S1# 3
S1# 2
S3# 2
S4# 4
S1# 15
S1# 20
S1# 30
S1# 40
S1# 60
S1# 70
S1# 85
S1# 95
S1#100
S1#105
S1#110
S1#115
51*125
S1#130
S1HM45
S1#150
S1#160
S1#165
S1#170
S1#175
S1ซ180
S1#182
S1#185
S1S190
S1#195
S1#200
S2# 10
S2# 15
S2# 20
S2# 25
S2# 30
S2# 35
INST
Id:
.20
ID:
F16
F16
Analyzed:
08/31/98
19:00
reported as NOT FOUND
Units:
Name Mass
CI30 1,4-DICHLOROBENZENE
CI40 NAPHTHALENE-D8
CI50 ACENAPHTHENE-D10
CI60 PHENANTHRENE-D10
CI70 CHRrSENE-012
CI75 PERYLENE-D12
CS20 NITROBENZENE -05
CS25 2-FLUOROBIPHENYL
CS30 TERPHENYL-D14
CS45 PHENOL-D5
CS50 2-FLUOROPHENOL
CS55 2,4,6-TRIBROMOPHENO
HEXACHLOROBENZENE-C13
C310 N-NITROSOD1METHYLAM
PYRIDIME
2-PICOLINE
N-NITROSOMETHYLETHYLAMIN
METHYLMETHANESULFONATE
N-NITROSOD1ETHYLAMINE
ETHYLMETHANE SULFONATE
PENTACHLOROETHANE
C320 ANILINE
C315 PHENOL
C325 BIS(2-CHLOROETHYL)E
C330 2-CHLOROPHENOL
C335 1,3-DICHLOROBENZENE
C340 1,4-DICHLOROBENZENE
C345 BENZYL ALCOHOL
C350 1,2-DICHLOROBENZENE
C355 2-METHYLPHENOL
C360 2,2'-OXYBIS(1-CLPRO
C361 ACETOPHENONE
N-NITROSOPYRROLIDINE
N - N I TROSOMORPHOL I NE
3-METHYL PHENOL
C365 4-METHYLPHENOL
C370 N-NITROSO-D1-N-PROP
0-TOLUIDINE
C375 HEXACHLOROETHANE
C410 NITROBENZENE
N-NITROSOPIPERIDINE
C415 ISOPHORONE
C420 2-NITROPHENOL
C425 2,4-DIMETHYLPHENOL
C435 BISC2-CHLOROETHOXY)
152
136
164
188
240
264
82
172
244
99
112
330
294
74
79
93
42
80
102
79
117
93
94
93
128
146
146
108
146
108
45
105
100
56
108
108
70
106
117
77
42
82
139
107
93
Meth
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
BV
BB
BB
BB
88
BB
BB
BB
BB
BB
VB
BB
BB
VB
BV
BB
VB
VV
BB
BB
BB
Scan Ref
341 1
530 2
829 3
1087 4
1552 5
1783 6
424 2
723 3
1384 5
1 NOT
1 NOT
971 3
4 NOT
1 NOT
1 NOT
1 NOT
180 1
201 1
1 NOT
1 NOT
1 NOT
1 NOT
1 NOT
319 1
1 NOT
1 NOT
1 NOT
374 1
1 NOT
392 1
394 1
1 NOT
1 NOT
1 NOT
423 1
419 1
414 1
413 1
1 NOT
2 NOT
2 NOT
2 NOT
2 NOT
500 2
2 NOT
Area
25865.
96183.
53596.
95242.
57183.
44948.
355.
1150.
1924.
FOUND
FOUND
380.
FOUND
FOUND
FOUND
FOUND
405.
448.
FOUND
FOUND
FOUND
FOUND
FOUND
216.
FOUND
FOUND
FOUND
268.
FOUND
1488.
1758.
FOUND
FOUND
FOUND
363.
452.
1123.
332.
FOUND
FOUND
FOUND
FOUND
FOUND
714.
FOUND
RRF(L)
1.
1.
1.
1.
1.
1.
0.
1.
0.
0.
000
000
000
000
000
000
470
234
995
236
0.811
0.636
1,
.368
0.854
1
.175
2.539
2
1
0
2
0
.252
.276
.906
.160
.330
UG/ML
Amount
40.
40.
40.
40.
40.
40.
0.
0.
1.
1.
0.
1.
0.
0.
000
000
000
000
000
000
314
695
352
203
.772
,089 '
.244
.485
1.959
1
0
0
1
0
0
.071
.249
.548
.917-
.238
.900
I'***' ?
t> /I
-------
46 S2# 40 C440 2,4-OICHLOROPHENOL 162 A BB 519 2 200. 0.308 0.270
47 S2# 45 C430 BENZOIC ACID 122 2 NOT FOUND
48 S2# 50 AA-DIMETHYLPHENETHYLAMIN 58 2 NOT FOUND
49 S2# 55 C445 1,2.4-TRICHLOROBENZ 180 2 NOT FOUND
-------
50
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
69
70
71
72
73
74
75
76
77
78
79
80
81
82
83
84
85
86
87
88
89
90
91
92
93
94
95
96
97
98
99
100
101
102
103
104
105
106
107
108
109
110
S2# 60,
S2* 80
S2# 85
S2* 90
S2# 95
52*115
S2#120
52*130
S2#140
52*145
S3* 10
S3* 15
S3* 20
S3* 25
S3* 30
S3* 35
S3* 40
S3* 42
S3* 45
S3* 50
S3* 55
S3* 60
S3* 65
S3* 70
S3* 75
S3* 80
S3* 85
S3* 90
S3* 95
53*100
53*105
S3#110
53*115
53*120
53*130
53*135
53*140
53*145
53*150
S4# 10
S4# 15
S4* 20
S4# 25
54* 30
54* 35
S4# 37
S4# 40
54* 45
S4* 50
54* 55
S4# 60
54* 65
54* 70
54* 75
S4* 80
S4ซ 85
54*100
54*105
54*106
54*110
54*120
;C450 NAPHTHALENE X
C45b 4-CHLOROANALINE
2,6-DICHLOROPHENOL
HEXACHLOROPROPENE
C460 HEXACHLOROBUTADIENE
P-PHENYLENE DIAMINE
N-N1TROSOOI-N-BUTYLAM1NE
C465 4-CHLORO-3-METHYLPH
SAFROLE
C470 2-METHYLNAPHTHALENE
1,2,4,5-TETRACHLOROBENZE
ISOSAFROLE <*1 )
C510 HEXACHLOROCYCLOPENT
C515 2,4,6-TRICHLOROPHEN
C520 2,4,5-TRICHLOROPHEN
ISOSAFROLE (#2)
C525 2-CHLORONAPHTHALENE
1-CHLORONAPHTHALEN
C530 2-NITROANALINE
1,4-NAPHTHOOUINONE
C535 D1METHYLPHTHALATE
1,3-DINITROBENZENE
C540 ACENAPHTHYLENE
C543 2,6-DINITROTOLUENE
C545 3-NITROANILINE
C550 ACENAPHTHENE
C555 2,4-DINITROPHENOL
C565 DIBENZOFURAN
C560 4-NITROPHENOL
PENTACHLOROBENZENE
C570 2,4-DINITROTOLUENE
1-NAPHTHYLAM1NE
2-NAPHTHYLAMINE
2,3,4,6-TETRACHLOROPHENO
CSSODIEUIY^PHTHALATE
C59(jLUORENT>
C585 4-CHLOROPHENYL-PHEN
5-NITRO-O-TOLUIDINE
C595 4-NITROANALINE
C610 4.6-DINITRO-2-METHY
C615 N-NITROSODIPHENYLAM
C620 AZOBENZENE
SYM-TRINITROBENZENE
C625 4-BROMOPHENYL-PHENY
PHENACETIN
D1ALLATE
C630 HEXACHLOROBENZENE
4-AMINOBIPHENYL
C635 PENTACHLOROPHENOL
PRONAMIDE
PFNTAfHI ORONlTPnRFN7FNF
C6
C645 ANTHRACENE
2SECBUTYL-4.6-D1NITROPHE
C647 CARBAZOLE
C650 DI-N-BUTYLPHTHALATE
4-N1TROQUINOLINE-1-OXIDE
METHAPYRILENE
ISOOR1N
C655 FLUORANTHENE
CHLOROBENZILATE
128
127
162
213
225
108
84
107
162
142
214
162
237
196
196
104
162
162
65
158
163
168
152
165
138
153
184
168
109
250
165
143
143
232
149
166
204
152
138
198
169
77
75
248
108
234
284
169
266
173
237
178
178
211
167
149
190
58
193
202
139
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A*
A
A
A
A
A
A
A
A
A
A
A
BV
BB
BV
BB
BB
BB
VB
BB
VB
BB
BB
BV
BB
BB
BV
BB
BB
BB
BB
BB
BB
BB
BB
VB
BB
BB
BB
BB
533 2
556 2
552 2
2 NOT
2 NOT
2 NOT
2 NOT
2 NOT
648 2
652 2
3 NOT
697 3
3 NOT
3 NOT
3 NOT
738 3
3 NOT
3 NOT
764 3
772 3
3 NOT
3 NOT
808 3
816 3
3 NOT
834 3
857 3
867 3
887 3
3 NOT
881 3
3 NOT
3 NOT
896 3
3 NOT
926 3
3 NOT
941 3
948 3
4 NOT
963 4
4 NOT
4 NOT
1022 4
4 NOT
4 NOT
4 NOT
1076 4
1063 4
4 NOT
1064 4
1091 4
4 NOT
4 NOT
1148 4
4 NOT
4 NOT
4 NOT
1270 4
4 NOT
4 NOT
13016.
389.
1164.
FOUND
FOUND
FOUND
FOUND
FOUND
852.
21609.
FOUND
418.
FOUND
FOUND
FOUND
394.
FOUND
FOUND
755.
450.
FOUND
FOUND
533.
267.
FOUND
943.
70.
838.
343.
FOUND
483.
FOUND
FOUND
118.
FOUND
2574.
FOUND
2148.
373.
FOUND
2520.
FOUND
FOUND
320.
FOUND
FOUND
FOUND
1557.
156.
FOUND
54.
7792.
FOUND
FOUND
364.
FOUND
FOUND
FOUND
504.
FOUND
FOUND
1.
0.
0.
0.
0.
0.
0.
0.
0.
1.
0.
1.
0.
1.
0.
0.
0.
1.
0.
0.
0.
0.
0.
0.
o.,~.
022
454
257
248
751
044
195
502
415
838
324
159
189
669
173
397
297
298
356
307
551
222
609
155
nan
1.033
0.764
0.
127
5.
f
T).
1.
1.
CjjT
7.
1.
1.
0.
0.
0.
0.
0.
0.
1.
0.
0.
]_.
4.
0.
1.
0.
1.
0.
o.
3.
29S"
S4-
880
43J
96Z}
156'
508
122
810
216
615
608
276
375
483
908
297
j
4801
509-
907
922
604
074
,423
,282
0.200
1.
,671
-------
111 S5# 10 C710 BENZIDINE 184 5 NOT FOUND
112 S5# 15 C715 PYRENE 202 A BB 1335 5 1175. 1.323 0.622
113 S5# 20 ARAMITE (#1) 185 5 NOT FOUND
114 S5# 25 ARAMITE (#2) 185 5 NOT FOUND
115 S5# 30 P-D1METHYLAMINOAZOBENZEN 120 5 NOT FOUND
116 S5# 35 3,3'-DIMETHYLBENZIDINE 212 A BV 1472 5 120. 0.418 0.201
117 S5# 37 KEPONE 272 5 NOT FOUND
118 S5# 40 C720 BUTYLBENZYLPHTHALAT 149 5 NOT FOUND
119 S5# 45 2-ACETYLAMINOFLUORENE 181 5 NOT FOUND
120 S5# 50 C730 BENZO(A)ANTHRACENE 228 5 NOT FOUND
121 S5# 55 C725 3,3'-DICHLOROBENZID 252 5 NOT FOUND
122 S5# 60 C740 CHRYSENE 228 A VB 1554 5 825. 1.014 0.569
123 S5# 65 C745 BISC2-ETHYLHEXYDPH 149 5 NOT FOUND
124 S5# 85 3-METHYLCHOLANTHRENE 268 5 NOT FOUND
125 S6# 10 C760 Dl-N-OCTYL PHTHALAT 149 6 NOT FOUND
126 S6# 15 C765 BENZO(B)FLUORANTHEN 252 6 NOT FOUND
127 S6# 20 7,12-DIMETHYLBENZANTHRAC 256 6 NOT FOUND
128 S6# 25 C770 BENZO(K)FLUORANTHEN 252 6 NOT FOUND
129 S6# 30 HEXACHLOROPHENE 196 6 NOT FOUND
130 S6# 35 C775 BENZO(A)PYRENE 252 6 NOT FOUND
131 S6# 55 C780 INDENO(1,2,3-CD)PYR 276 6 NOT FOUND
132 S6# 60 C785 DIBENZ(A,H)ANTHRACE 278 6 NOT FOUND
133 S6# 65 C790 BENZO(G,H, DPERYLEN 276 6 NOT FOUND
-------
iiuii 30 apisino si 'S'l ue saieoipui -
ZlO-3N3-U83d S/I3 = 9 #SI
Zld-3N3SAiJH3 OZIO = S #SI
Old-3N38HlNVN3Hd 0913 = V #S!
ฃ8'6l|88 = '8*6W I 9Z'2l|l6 ='ฃ8l/S I 60'Zl|96 =-ZVZS6 I 1018900ฃ
ฃฃ'61|OS +=-S/ฃSZ I 9/'9l|OS +=-S
-------
TARGET COMPOUND COMPARISON
COMPOUND: C450 NAPHTHALENE
128 S2tt 60
RAM DATA: 30068101 #533
08/31/98 19:00
SAMPLE: S-MM5-2 1/3SA/100M INST, ID: F16
CONDS.: UG/ML *100ML *100Z/100Z *
-------
14.4-
7.2~.
11.3-
5.7-:
TARGET COMPOUND COMPARISON
COMPOUND: C470 2-METHYLNAPHTHALENE
142 S2#145
RAM DATA: 38068181 #652
08x31/98 19:00
SAMPLE: S-MM5-2 1/3SA/100M
CONDS.: UG/ML *100ML
91-57-6
BASE M/Z: 142
RIC: 97280.
INST. ID: F16
*' I-
ENHANCED DATA: 30068101,,#52
H-
i ' i ' i ' I ' i ' i ' i ' i '
BASE M/Z: 141
i ' i ' i ' i ' I * i ' i ' i ' i '
RIC: 21568.
7152.
5648.
I * I I I I I llll'l'l'l'l'l'l'l'l'l'l1!'!*] T^ I T
STANDARD FILE: ST16980831 #651 BASE M/Z: 142 RIC: 198144.
08/31/98 12:31
100.07
50.0-:
M/Z
100.0-
50.0-:
0 .
-50.0^
100.0-
>
y J 1
t.. i .j .lvi. .... . i 1 . ill.
1 "1* J'l'l'l'l 'I'l'l' 1 ' 1 '|' I * 1 ' 1 ' 1 '!' '"1 '!' '"(* I'l '!' '"I 'I' 1*1* *'| '1* I'l ' 1 '
50 100 150 200 250 300 350
|
1 i ' \
r 49792.
-------
5.7-
2.9-:
100.0-
50.0-:
TARGET COMPOUND COMPARISON
COMPOUND: C640 PHENANTHRENE
RAM DATA: 30068101 #1091
08/31/98 19:00
SAMPLE: S-MM5-2 1/3SA/100M
CONDS.: UG/ML *100ML *100Z/100Z
178 S4# 65 85-01-8
BASE M/Z: 41
INST. ID: F16 /
)/l/3SA NA M /
f
RIC: 87680.
V
..,..Jll|l lJ|llll|nll>|lL.,|J|L|,l.
'!''"[ 'T'v '['
ENHANCED DATA: 30068101 #1091
"I I I I"
"T
' ' ' ' ' ' I
BASE M/Z: 178 RIC: 15456.
STANDARD FILE: ST16980831 #1091
08/31/98 12:31
BASE M/Z: 178 RIC: 204544.
I ' i
4200.
3.3-
1.7-:
II.., ,,,,.,,
1 1 1 1 1 1 I 1 1 1 1 1
/*"
1 1 1 1 1 1 . I 1 1 1 1 1 1 I 1 1 1 1 1 1 1 1 1 1 1 1
2448.
r 73344.
M/Z
100.0-
50.0-:
0 .
-50.0-:
100. 0-3
50 100 150 200 250 300
ll 1 l ,
.11. . . ||. Mil ,,||. i .I.,.., i.. i i, . .., , .
- **OUT**
. -I
-------
Data Reduced by: y^-Date:fifo
Data Reviewed by: \UfVUbate: (%
Data File: 30068101
QUANTERRA GC/HS TIC REPORT ( Part 1 )
Sample: S-MM5-2 1/3SA/100M INST. ID: F16
Analyst: DAT Date Analyzed: 08/31/98 19:00
Run Factor: 300.
Concentration
in Sample
# SCAN (UG/A) CAS #
i J\A^.W. &t>luu*4- S^m^M
2 473 7900.
-------
11 738 17000. 3891-98-3
OOOECANE, 2,6,10-TRIMETHYL-
12 763 22000. 629-59-4
TETRADECANE Uซ- \'<
13 776 12000. 00-00-0
UNKNOWN
14 820 18000. 18344-37-1
HEPTADECANE, 2,6,10,14-TETRAMETHYL-
15 858 19000. 7045-71-8
UNDECANE, 2-METHYL- O V ^
16 904 13000.
17 948 24000. 629-92-5
NONADECANE
18 987 15000. 54105-67-8
HEPTADECANE, 2,6-DlMETHYL- f
19 1035 32000. 54105-67-8
HEPTADECANE, 2,6-DIMETHYL- _ y. i'
20 1114 10000. 54105-67-8
HEPTADECANE, 2,6-DIMETHYL- Q
-------
74
s unu
,1264 6400.
NONAOECANE Of
629-92-5
24 1335
HEPTAOECANE,
9700.
2,6,10,14-
25 H02
7500.
18344-37-1
ETRAMETHri-
, 629-92-5
NONAOECANE
-------
DATA FILE: 30068101
QUANTERRA GC/MS TIC REPORT ( Part 2 )
CONCENTRATION = AREA(TIC)*CONC(IS)/AREA(1S)
#
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
FIT
947
862
964
883
954
963
962
900
887
830
981
959
946
975
945
938
956
949
975
910
950
969
969
910
961
PURITY
652
667
839
598
748
692
868
393
401
396
834
739
550
831
752
674
833
817
872
791
823
756
773
691
716
INT.
STD.
1
1
1
1
1
1
1
1
2
2
2
2
2
2
2
2
2
3
3
3
3
3
3
4
4
AMOUNT
AS ANALYZED
RT
4:56
5:15
6:11
6:51
7:02
7:16
7:21
7:32
7:47
7:56
8:12
8:29
8:37
9:07
9:32
10:03
10:32
10:58
11:30
12:23
12:26
13:14
14:03
14:50
15:35
RRT
0.838
0.892
1.049
1.164
1.194
1.234
1.249
1.279
0.844
0.861
0.890
0.920
0.936
0.989
1.035
1.090
1.144
0.908
0.952
1.025
1.029
1.096
1.163
0.860
0.903
AREA
178482.
198048.
160442.
331968.
368896.
224000.
215296.
167552.
197952.
144707.
411520.
522729.
294272.
421760.
441984.
301824.
567424.
404224.
897408.
279936.
383872.
213440.
179442.
160448.
123776.
HEIGHT
55205.
49344.
59857.
36544.
98560.
40832.
76160.
38144.
27102.
34489.
117376.
149934.
40960.
107008.
145920.
48512.
133632.
103040.
162304.
81024.
114688.
62304.
48179.
34827.
25984.
(UG/HL )
23.
26.
21.
44.
49.
29.
28.
22.
27.
20.
58.
73.
41.
59.
62.
42.
80.
48.
107.
33.
45.
25.
21.
32.
760
364
358
192
108
819
660
305
953
434
111
815
554
557
413
621
127
343
325
479
909
526
460
250
24.879
LIB
NB
NB
NB
UK
NB
NB
NB
UK
UK
UK
NB
NB
UK
NB
NB
NB
NB
NB
NB
NB
NB
NB
NB
NB
NB
LIB #
14793.
22482.
11607.
1.
19523.
21962.
11607.
1.
1.
1.
25991.
22530.
1.
42196.
15352.
40233.
37465.
37462.
37462.
37462.
37462.
37465.
37465.
42196.
37465.
-------
Library Search Data: 30068101 # 444 Base m/z: 43
08/31/9819:00:00+ 4:56 Calf: 30068101 # 3 RIC: 45952.
Sample: S-MM5-2 1/3SA/100M 1NST. ID: F16
Conds.: UG/ML '100ML *100X/100% *(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
740 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 14793 1-UNDECENE, 4-METHYL-
2 19015 DECANE, 2,5,6-TRIMETHYL-
3 11607 UNDECANE
4 19523 1-DECANOL, 2-ETHYL-
5 12074 1-HEPTANOL, 2-PROPYL-
6 11602 OCTANE, 2,4,6-TRIMETHYl-
7 8104 OCTANE, 3,5-OIMETHYL-
8 15969 HYOROXYLAMINE, 0-DECYL-
9 8089 NONANE, 2-METHYL-
Rank
1
2
3
4
5
6
7
8
9
Formula
C12.H24
C13.H28
C11.H24
C12.H26.0
C10.H22.0
C11.H24
C10.H22
C10.H23.0.N
C10.H22
M.Wt B.Pk Purity Fit RFit
168
184
156
186
158
156
142
173
142
43
57
43
57
43
57
57
43
43
652
651
646
636
631
625
623
620
620
947
939
979
922
936
948
930
928
941
652
651
653
661
640
627
635
658
628
Rank
1
2
3
i,
5
6
7
8
9
Ret.Time
B.P.Int.
US.Par.1
US.Par.2
C.A.S
74630
62108
1120
21078
10042
62016
15869
29812
871
. #
39-0
23-0
21-4
65-9
59-8
37-9
93-9
79-1
83-0
-------
1143
SAMPLE
MID LIBRARY SEARCH CLIBRARYNB) DATA:
88/31/38 19:00:00 + 4:56 CALL-
SAMPLE: S-MM5-2 1/3SA/100M INST. ID: F16
CONDS.: UG/ML *100ML *100Z/100Z */l/3SA NA M
ENHANCED
30068101
30068101
# 444
# 3
BASE M/Z: 43
RIC: 45952.
C12.H24
1143
M WT 168
B PK 43
RANK 1
# 14793
PUR 652
1-UNDECENE, 4-METHYL-
C13.H28
1143 T
M WT 184
B PK 57
RANK 2
* 19015
PUR 651
DECANE, 2,5,6-TRIMETHYL-
C11.H24
1143
M WT
B PK
15
4
RANK 3
tt 11607
PUR 646
UNDECANE
M/H
50
100
150
200
250
300
350
400
450
-------
Library Search Data: 30068101 # 473 Base m/z: 43
08/31/98 19:00:00 + 5:16 Cali: 30068101 # 3 RIC: 40896.
Sample: S-MM5-2 1/3SA/100M 1NST. ID: F16
Conds.: UG/ML *100ML *100X/100X *(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
459 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 22482 2-TRIDECEN-1-OL, (E)-
2 39230 9-EICOSYNE
3 25971 OX1RANE, DOOECYL-
4 34800 (R)-(-)-(Z)-14-METHYL-8-HEXADECEN-1-OL
5 37449 OCTADECANAL
6 29222
-------
1515
SAMPLE
MID LIBRARY SEARCH -
C20.H38
1515
M WT 278
B PK 81
RANK 2
ป 39230
PUR 661
9-EICOSYNE
li I. i.
C14.H28.0
1515
M WT 212
B PK 41
RANK 3
# 25971
PUR 658
M/Z
OXIRANE, DODECYL-
50
100
150
200
250
-------
Library Search Data: 30068101 ซ 556
08/31/98 19:00:00 + 6:11 Cali: 30068101 # 3
Sample: S-MM5-2 1/3SA/100M INST. ID: F16
Conds.: UG/ML "100ML *100X/100% "(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
Base m/z: 43
RIC: 54144.
62231 spectra in LIBRARYNB searched for maximun PURITY
890 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 11607 UNDECANE
2 15353 2,6-DlMETHYLDECANE
3 19016 UNDECANE, 4,7-DlMETHYL-
4 15357 DECANE, 2,9-DIMETHYL-
5 15352 UNDECANE, 2-METHYL-
6 19015 DECANE, 2,5,6-TRIMETHYL-
7 11602 OCTANE, 2,4,6-TRIMETHYL-
8 19028 DECANE, 2,4,6-TRIMETHYL-
9 22530 TETRADECANE
Rank
1
2
3
4
5
6
7
8
9
Rank
1
2
3
4
5
6
7
8
9
Formula
C11.H24
C12.H26
C13.H28
C12.H26
C12.H26
C13.H28
C11.H24
C13.H28
C14.H30
Ret.Time
B.P.Int.
US.Par.1
.wt
156
170
184
170
170
184
156
184
198
B.Pk Purity Fit
43
43
43
43
43
57
57
43
43
US. Par. 2
839 964
836 924
835 959
832 967
829 949
825 929
822 967
822 941
821 923
C.A.S. *
1120-21-4
13150-81-7
17301-32-5
1002-17-1
7045-71-8
62108-23-0
62016-37-9
62108-27-4
629-59-4
RFit
864
842
836
842
845
826
822
828
876
bJ
-------
1083
SAMPLE
MID LIBRARY SEARCH CLIBRARYNB)
08/31/98 19:00:00 + 6:11
SAMPLE: S-MM5-2 1/3SA/108M INST. ID: FIG
CONDS.: UG/ML *100ML *100Z/1007Z *
DATA: 30068101 * 556 BASE M/Z: 43
CALI: 30068101 * 3 RIC: 54144.
C11.H24
1083
M WT 156
B PK 43
RANK 1
tt 11687
PUR 839
UNDECANE
C12.H26
1083 i
M WT 170
B PK 43
RANK 2
# 15353
PUR 836
2, 6-DIMETHYLDECANE
r
1 i
i
ll
h
|l |i
C13.H28
1083
M WT 184
B PK 43
RANK 3
ft 19016
PUR 835
UNDECANE, 4,7-DIMETHYL-
M/2
40
60
80
100
120
140
160
180
cr
cr>
-------
Library Search Data: 30068101 # 617 Base m/z: 41
08/31/9819:00:00+ 6:52 Cali: 30068101 * 3 RIC: 33216.
Sample: S-MM5-2 1/3SA/100M INST. ID: F16
Conds.: UG/ML *100ML *100X/100% *(NA/NA J/1/3SA NA M
Enhanced (S 15B 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
207 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 24994 1,1'-BICYCLOHEXYL, 2-(1-MฃTHYLETHrL)-, TRANS-
2 33979 BORINIC ACID, DIETHYL-, 1-CYCLOOODECEN-1-YL ESTER
3 24993 1,1'-BICYCLOHEXYL, 2-O-METHYLETHYL)-, CIS-
4 39227 NAPHTHALENE, OECAHYDRO-2,6-DIMETHYL-3-OCTYL-
5 39519 CYCLOHEXANE, 1-(1,5-DIMETHYLHEXYL)-4-(4-METHYLPENTYL)-
6 24990 MUUROLANE-B
7 31486 ACETAMIDE, N-METHYL-N- [4- [4-METHOXY-1-HEXAHYDROPYRIDYL]-2-BUTYNYL] -
8 24987 AMORPHANE-A
9 24991 AMORPHANE-B
Rank
1
2
3
4
5
6
7
8
9
Formula
C15.H28
C16.H31.0.B
C15.H28
C20.H38
C20.H40
C15.H28
C13.H22.02.N2
C15.H28
C15.H28
Rank
1
2
3
5
6
7
8
9
M.Wt
208
250
208
278
280
208
238
208
208
B.Pk
83
83
83
109
43
109
43
109
95
Purity
598
589
575
539
537
534
527
519
518
Fit
883
911
868
820
741
830
732
817
804
RFit
622
617
615
606
636
586
606
552
581
Ret. Time
B.P.lnt.
US.Par.1 US.Par.2
C.A.S. #
50991-16-7
61142-73-2
50991-15-6
54964-85-1
56009-20-2
-------
MID LIBRARY SEARCH (LIBRARYNB)
08/31x98 19:00:00 + 6:52
SAMPLE: S-MM5-2 1/3SA/100M INST. ID: F16
CONDS.: UG/ML *100ML *1002/1002 */l/3SA NA M
ENHANCED
DATA: 30068101 # 617 BASE M/Z: 41
CALI: 30068101 # 3 RIC: 33216.
1200
SAMPLE
I I
4-
C15.H28
1200 i
M WT 208
B PK 83
RANK 1
# 24994
PUR 598
1,I1-BICYCLOHEXYL, 2-<1-METHYLETHYL>-, TRANS-
C16.H31.0.B
1200
M WT 250
B PK 83
RANK 2
ป 33979
PUR 589
BORINIC ACID, DIETHYL-, 1-CYCLODODECEN-1-YL ESTER
C15.H28
1200
M WT 208
B PK 83
RANK 3
ป 24993
PUR 575
M/Z
1,1'-BICYCLOHEXYL, 2-
-------
Library Search Data: 30068101 # 633 Base m/z: 57
08/31/98 19:00:00 + 7:02 Cali: 30068101 # 3 RIC: 84096.
Sample: S-MM5-2 1/3SA/100M INST. ID: F16
Conds.: UG/ML *100ML *100*/100X ป
-------
1179
SAMPLE
MID LIBRARY SEARCH (LIBRARYNB) DATA:
08/31/98 19:80:08 + 7:02 CALL-
SAMPLE: S-MM5-2 1/3SA/180M INST. ID: F16
CONDS.: UG/ML *100ML *1007./100/1 *
30068101
30068181
# 633 BASE M/Z: 57
# 3 RIC: 84096.
II
O
C12.H26.0
1179 -
M WT 186 :
B PK 57
RANK 1
tt 19523 '.
PUR 748
C19.H40
1-DECANOL/ 2-ETHYL-
Ili
In
C12.H24
1179
M WT 168
B PK 57
RANK 3
# 14799
PUR 731
M/Z
HEPTADECANE, 2,6-DIMETHYL-
11 f 3
M WT 268
B PK 57
RANK 2
# 37462 '
PUR 734
r
|
,
h
J ,. .. ,
1-DECENE, 3,4-DIMETHYL-
II
50
100
150
200
250
CO
-------
Library Search Data: 30068101 # 654
08/31/98 19:00:00 + 7:16 Cali: 30068101 # 3
Sample: S-MM5-2 1/3SA/100M INST. ID: F16
Conds.: UG/ML *100ML *100X/100% "(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
Base m/z: 41
R1C: 39104.
62231 spectra in LIBRARYNB searched for maximum PURITY
687 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 21962 3-TETRADECENE, (Z)-
2 21963 3-TETRADECENE, (E)-
3 28772 7-HEXADECENE, (Z)-
4 11084 CYCLOPROPANE, 1-HEPTYL-2-METHYL-
5 28768 3-HEXADECENE, (Z>-
6 21973 7-TETRADECENE, (Z)-
7 34411 5-OCTADECENE, -
8 34410 3-OCTADECENE, (E)-
9 21961 5-TETRADECENE, (E>-
Rank
1
2
3
i,
5
6
7
8
9
Formula
C14.H28
C14.H28
C16.H32
C11.H22
C16.H32
C14.H28
C18.H36
C18.H36
C14.H28
M.Wt B.Pk Purity Fit RFit
196
196
224
154
224
196
252
252
196
41
41
55
56
55
55
55
69
55
692
690
686
685
685
683
682
681
680
963
959
923
943
925
952
917
904
949
695
693
710
689
711
687
708
708
683
Rank
1
2
3
4
5
6
7
8
9
Ret.Time
B.P.Int.
US.Par.1
US.Par.2
C.A.S
41446
41446
35507
74663
34303
41446
7206
7206
41446
. #
67-7
68-8
09-6
91-5
81-6
60-0
21-5
19-1
66-6
bC-3
-------
MID LIBRARY SEARCH CLIBRARYNB)
08/31/98 19:00:00 + 7:16
SAMPLE: S-MM5-2 1/3SA/100M INST. ID: F16
CONDS.: UG/ML *100ML *10072/100Z *- ^ .- ^ ^tsS
r 0 f t *) CTV^-~-*X^
II 1 1. .
3-TETRADECENE,
-------
Library Search Data: 3006S101 # 662 Base m/z: 57
08/31/98 19:00:00 + 7:22 Cati: 30068101 # 3 RIC: 75264.
Sample: S-MM5-2 1/3SA/100M 1NST. ID: F16
Conds.: UG/ML "100ML *100%/100% *(NA/NA )/1/3SA NA M
Enhanced (S 158 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
632 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 11607 UNOECANE
2 19006 OECANE, 6-ETHYL-2-METHYL-
3 19016 UNDECANE, 4,7-DIMETHYL-
4 22530 TETRAOECANE
5 11602 OCTANE, 2,4,6-TRIMETHYL-
6 15357 DECANE, 2,9-DlMETHYL-
7 18998 UNDECANE, 3,7-DIMETHYL-
8 19028 DECANE, 2,4,6-TRIMETHYL-
9 18985 TRIDECANE
Rank
1
2
3
4
5
6
7
8
9
Rank
1
2
3
i,
5
6
7
8
9
Formula
C11.H24
C13.H28
C13.H28
CH.H30
C11.H24
C12.H26
C13.H28
C13.H28
C13.H28
Ret.Time
B.P.Int.
US.Par.1
H.Ut B
156
184
184
198
156
170
184
184
184
US
.Pk Purity Fit
43
57
43
43
57
43
43
43
57
.Par. 2
868 962
847 943
846 934
831 908
830 945
826 943
826 925
825 915
819 923
C.A.S. #
1120-21-4
62108-21-8
17301-32-5
629-59-4
62016-37-9
1002-17-1
17301-29-0
62108-27-4
629-50-5
RFit
878
862
863
897
850
848
850
858
851
-------
1084
SAMPLE
MID LIBRARY SEARCH CLIBRARYNB)
08/31/98 19:00:00 + 7:22
SAMPLE: S-MM5-2 1/3SA/100M INST. ID: F16
CONDS.: UG/ML *100ML *100Z/100Z *
DATA: 30068101 # 662 BASE M/Z: 57
CALI: 30068101 # 3 RIC: 75264.
C11.H24
1084
M WT 156
B PK 43
RANK 1
* 11607
PUR 868
C13.H28
1084
M WT 184
B PK 57
RANK 2
ft 19006
PUR 847
C13.H28
1084
M WT 184
B PK 43
RANK 3
# 19016
PUR 846
UNDECANE
DECANE, 6-ETHYL-2-METHYL-
UNDECANE, 4,7-DIMETHYL-
M/Z
40
80
100
120
140
160
180
-------
Library Search Data: 30068101 # 678 Base m/z: 57
08/31/98 19:00:00 + 7:32 Cali: 30068101 # 3 RIC: 36736.
Sample: S-MM5-2 1/3SA/100M INST. ID: F16
Conds.: UG/ML *100ML *100%/100% *
-------
1196
SAMPLE
C11.H24
1196
M WT
B PK
15
5
RANK 1
# 11597
PUR 393
C9.H20
1196
M WT 128
B PK 43
RANK 2
* 5159
PUR 393
C10.H21.I
1196
M WT 268
B PK 43
RANK 3
# 37251
PUR 388
M/Z
MID LIBRARY SEARCH (LIBRARYNB)
08/31/98 19:00:00 + 7:32
SAMPLE: S-MM5-2 1/3SA/100M INST. ID: FIG
CONDS.: UG/ML *100ML *100Z/100Z *
DATA: 30068101 # 678 BASE M/Z: 57
CALI: 30068101 # 3 RIC: 36736.
r
I
j
v / i/ocy^
i ป \(fj^
\ It I ^"^
, ,i i 1. 1,| i,. ,n i| i {in |. , i|. ..,,...
NONANE, 3,7-DIMETHYL-
NONANE
1 - I ODO-2-METHYLNONANE
50
100
150
280
250
300
-------
Library Search Data: 30068101 # 700
08/31/98 19:00:00 + 7:47 Cali: 30068101 # 3
Sample: S-MM5-2 1/3SA/100M 1NST. ID: F16
Conds.: UG/ML *100ML *100%/100% *(NA/NA )/1/3SA NA M
Enhanced (S 158 2N OT)
Base m/z: 81
R1C: 25344.
62231 spectra in L1BRARYNB searched for maximum PURITY
294 matched at least 6 of the 16 largest peaks in the unknown
Rank In. Name
1 6996 1-ETHYNYL-1-CYCLOHEPTANOL
2 28273 8-HEXAOECYNE
3 36677 7-OCTAOECYNE, 2-METHYL-
4 18371 5,7-DIMETHYLOCTAHYDROCOUMARIN
5 10423 3-UNDECYNE
6 28267 3-HEXADECYNE
7 14158 3-DOOECYNE
8 25001 CYCLOHEXANE, 1-(CYCLOHEXYLMETHYL)-2-ETHYL-, TRANS-
9 34010 3-OCTADECYNE
Rank
1
2
3
4
5
6
7
8
9
Rank
1
2
3
5
6
7
8
9
Formula
C9.H14.0
C16.H30
C19.H36
C11.H18.02
C11.H20
C16.H30
C12.H22
C15.H28
C18.H34
Ret .Time
M.Ut B.Pk Purity Fit RFit
138
222
264
182
152
222
166
208
250
81
81
81
95
67
67
67
55
67
401
395
394
392
389
388
378
375
374
887
777
749
863
893
732
832
707
810
401
436
439
412
389
405
380
426
395
B.P.Int.
US.Par.1
US.Par.2
C.A.S. #
2809-78-1
19781-86-3
35354-38-2
60212-30-8
61886-62-2
6790-27-8
54934-92-8
61886-64-4
I \J <-*
-------
MID LIBRARY SEARCH (LIBRARYNB)
08/31/98 19:00:00 + 7:47
SAMPLE: S-MM5-2 1/3SA/100M INST. ID: F16
CONDS.: UG/ML *100ML *100Z/100?: *CNA/NA V1/3SA NA M
ENHANCED
-------
Library Search Data: 30068101 # 714 Base m/z: 159
08/31/98 19:00:00 + 7:57 Cali: 30068101 # 3 RIC: 35264.
Sample: S-MM5-2 1/3SA/100M 1NST. ID: F16
Conds.: UG/ML *100ML *100%/100% "(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
310 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 31486 ACETAMIDE, N-METHYL-N-[4-[4-METHOXY-1-HEXAHYDROPYRIDYL]-2-BUTYNYLJ-
2 56499 9-OCTADECENOIC ACID (Z)-, 2-(ACETYLOXY)-1-C(ACETYLOXY)METHYL]ETHYL *
3 50599 PENTALENE, OCTAHYDRO-1-(2-OCTYLDECYL)-
4 56413 9,12-OCTADECADIENOIC ACID (Z,Z)-, 2-(ACETYLOXY)-1-[(ACETYLOXY)METHY*
5 56303 9,12,15-OCTADECATRIENOIC ACID, 2-(ACETYLOXY)-1-C(ACETYLOXY)METHYL]E*
6 40193 CIS-9,10-EPOXYOCTADECAN-1-OL
7 32052 OXIRANE, TETRADECYL-
8 46251 DOOECANE, 1,2-DIBROMO-
9 5032 3,4-DIMETHYLCYCLOHEXANOL
Rank
1
2
3
4
5
6
7
8
9
Formula
C13.H22.02.N2
C25.H44.06
C26.H50
C25.H42.06
C25.H40.06
C18.H36.02
C16.H32.0
C12.H24.BR2
C8.H16.0
M.Wt B.Pk Purity
Fit RFit
238
440
362
438
436
284
240
326
128
43
43
43
43
43
55
41
41
71
396
394
382
380
369
367
366
351
339
830
705
847
708
718
848
847
778
834
457
496
415
454
449
415
411
432
357
Rank
1
2
3
4
5
6
7
Ret.Time
B.P.Int.
US.Par.1
US.Par.2
C.A.S. #
55401-63-3
55401-65-5
55320-03-1
55320-01-9
13980-12-6
7320-37-8
55334-42-4
5715-23-1
-------
MID LIBRARY SEARCH (LIBRARYNB)
08/31/98 19:00:00 + 7:57
SAMPLE: S-MM5-2 1/3SA/100M INST. ID: FIG
CONDS.: UG/ML *100ML *100Z/10072 *-, 2- - , - , , 4-
PENTALENE , OCT AHYDRO- 1 - < 2-OCT YLDECYL ) -
1 I
II II 1. Jll , |l, ,1,, ,,l , ... , ,^,_^_-^__^_ , , . ,
M/Z
50
100
150
208
250
-vj
cS
in
-------
Library Search Data: 30068101 # 738 Base m/z: 57
08/31/98 19:00:00 * 8:13 Call: 30068101 # 3 R1C: 103296.
Sample: S-MM5-2 1/3SA/100M INST. ID: F16
Conds.: UG/ML "100ML *100%/100% *(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
712 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 25991 DOOECANE, 2,6,10-TRIMETHYL-
2 42196 HEPTADECANE, 2,6,10,14-TETRAMETHYL-
3 37462 HEPTADECANE, 2,6-DIMETHYL-
4 25997 PENTADECANE
5 26001 DOOECANE, 2,7,10-TRIMETHYL-
6 22535 DOOECANE, 4,6-DIMETHYL-
7 37465 NONADECANE
8 25994 DOOECANE, 2,6,11-TRIMETHYL-
9 22530 TETRADECANE
Rank
1
2
3
4
5
6
7
8
9
Formula
C15.H32
C21.H44
C19.H40
C15.H32
C15.H32
C14.H30
C19.H40
C15.H32
C14.H30
M.Wt B.Pk Purity Fit RFit
212
296
268
212
212
198
268
212
198
57
57
57
57
57
57
57
57
43
834
829
829
817
815
811
811
805
802
981
944
950
948
982
953
929
968
928
834
850
846
829
821
817
841
814
813
Rank
1
2
3
4
5
6
7
8
9
Ret.Time
B.P.Int.
US.Par.1
US.Par.2
C.A.S
3891
18344
54105
629
74645
61141
629
31295
629
98-3
37-1
67-8
62-9
98-0
72-8
92-5
56-4
59-4
-------
MID LIBRARY SEARCH
08/31/98 19:00:00 + 8:13
SAMPLE: S-MM5-2 1/3SA/100M INST. ID: F16
CONDS.: UG/ML *100ML *100Z/100Z */l/3SA NA M
ENHANCED
DATA: 30068101 # 738 BASE M/Z: 57
CALI: 30068101 # 3 RIC: 103296.
1188
SAMPLE
C15.H32
1188
M WT 212
B PK 57
RANK 1
# 25991
PUR 834
C21.H44
1188
M WT 296
B PK 57
RANK 2
# 42196
PUR 829
C19.H40
1188
M WT 268
B PK 57
RANK 3
# 37462
PUR 829
DODECANE, 2,6,10-TRIMETHYL-
HEPTADECANE, 2,6,10,14-TETRAMETHYL-
HEPTADECANE, 2,6-DIMETHYL-
M/Z
50
100
150
200
250
-------
Library Search Data: 30068101 # 763 Base m/z: 43
08/31/98 19:00:00 + 8:29 Call: 30068101 # 3 RIC: 136960.
Sample: S-MM5-2 1/3SA/100M INST. ID: F16
Conds.: UG/ML '100ML *100%/100% *(NA/NA )/1/3SA NA M
Enhanced (S 156 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
611 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 22530 TETRADECANE
2 19006 DECANE, 6-ETHYL-2-METHYL-
3 19007 DODECANE, 3-METHYL-
4 11607 UNDECANE
5 11612 NONANE, 2,5-DIMETHYL-
6 15358 UNDECANE, 3-METHYL-
742196 HEPTADECANE, 2,6,10,14-TETRAMETHYL-
8 18990 UNDECANE, 2,9-DIMETHYL-
9 39681 1-IODOUNDECANE
Rank
1
2
3
4
5
6
7
8
9
Formula
C14.H30
C13.H28
C13.H2S
C11.H24
C11.H24
C12.H26
C21.H44
C13.H28
C11.H23.I
M.Ut B.Pk Purity Fit RFit
Rank
1
2
3
4
5
6
7
8
9
198
184
184
156
156
170
296
184
282
43
57
57
43
57
57
57
57
57
739
727
712
711
708
703
700
699
697
959
964
904
968
871
924
918
876
875
739
727
712
711
708
703
729
699
704
Ret.Time
B.P.Int.
US.Par.1
US.Par.2
C.A.S. #
629-59-4
62108-21-8
17312-57-1
1120-21-4
17302-27-1
1002-43-3
18344-37-1
17301-26-7
4282-44-4
-------
1204
SAMPLE
MID LIBRARY SEARCH
08/31/98 19:00:00 + 8:29
SAMPLE: S-MM5-2 1/3SA/100M INST. ID: F16
CONDS.: UG/ML *100ML * 10972/100Z *
DATA: 30068101 # 763 BASE M/Z: 43
CALI: 30068101 # 3 RIC: 136960.
C14.H30
1204
M WT 198
B PK 43
RANK 1
# 22530
PUR 739
C13.H28
TETRADECANE
I I
DECANE, 6-ETHYL-2-METHYL-
1204 i
M WT 184
B PK 57
RANK 2
# 19006
PUR 727
C13.H28
1204 -I
M WT 184
B PK 57
RANK 3
# 19007
PUR 712
M/Z
r
II
r
50
M . n .. ,i .,
DODECANE, 3-METHYL-
i 11 _. - 1 ป_ ^ .. _ . ..... ,.- '1- , . -- - -.- . j--- - - - ,- -, ,-
100 150 200 25
-------
Library Search Data: 30068101 # 776 Base m/z: 156
08/31/98 19:00:00 + 8:38 Cali: 30068101 # 3 RIC: 36864.
Sample: S-MM5-2 1/3SA/100M INST. ID: F16
Conds.: UG/ML *100ML *100%/100% *(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
205 matched at least 5 of the 16 largest peaks in the unknown
Rank In. Name
1 11618 NAPHTHALENE,
2 11619 NAPHTHALENE,
3 11625 NAPHTHALENE,
4 11629 NAPHTHALENE,
5 11624 NAPHTHALENE,
6 11620 NAPHTHALENE,
7 11628 NAPHTHALENE,
8 11615 NAPHTHALENE,
9 11626 NAPHTHALENE,
Rank Formula
1 C12.H12
2 C12.H12
3 C12.H12
4 C12.H12
5 C12.H12
6 C12.H12
7 C12.H12
8 C12.H12
9 C12.H12
Rank Ret. Time
1
2
3
4
5
6
7
8
9
2,3-DIMETHYL
1,2-DIMETHYL
1,3-DlMETHYL
1,5-DIMETHYL
1,7-DIMETHYL
2,6-DIMETHYL
1,6-OIMETHYL
2,7-DIMETHYL
1,4-DIMETHYL
B.P.lnt. U
US.Par.1
M.Wt
156
156
156
156
156
156
156
156
156
1
B.Pk
156
156
156
156
156
156
156
156
141
US. Par.
Purity
550
549
547
540
539
537
537
537
536
.2 C
Fit
946
944
941
928
927
938
924
923
936
.A.S. #
581-40-8
573-98-8
575-41-7
571-61-9
575-37-1
581-42-0
575-43-9
582-16-1
571-58-4
RFit
569
570
576
571
574
568
564
564
567
-------
MID LIBRARY SEARCH CLIBRARYNB)
08/31/98 19:00:08 + 8:38
SAMPLE: S-MM5-2 1/3SA/100M INST. ID: F16
CONDS.: UG/ML *100ML *1007Z/100Z *
DATA: 30068101 # 776 BASE M/Z: 156
CALI: 30068101 # 3 RIC: 36864.
1237
SAMPLE
C12.H12
1237 n
M WT 156
B PK 156
RANK 1
# 11618 '
PUR 550
C12.H12
1237 1
M WT 156
B PK 156
RANK 2
# 11619
PUR 549
C12.H12
1237 i
M WT 156
B PK 156
RANK 3
tt 11625
PUR 547
M/Z
II li| ,> 1 l|l |l i l|l i , l|l <|> i l|l 1 i I
1, II
NAPHTHALENE , 2, 3-D I METHYL-
1 II,
NAPHTHALENE, 1,2-DIMETHYL-
i i1 1 ..... Hi ,.--...-.. ,...-,....,.- -'I' i
II,
NAPHTHALENE , 1 , 3-D I METHYL-
I ,1 ,l| |l| iii
Hi
^
IP . , | . ,. , , , , ... ,
i i i i i
' i i ---- | - - - - - - - . -
i - i ---- i - - - - ,....,..-.,.
40 60 80 100 120 140 160 180 200 220
-------
Library Search Data: 30068101 # 820 Base m/z: 57
08/31/98 19:00:00 + 9:07 Cali: 30068101 # 3 RIC: 98176.
Sample: S-MM5-2 1/3SA/100M INST. ID: F16
Conds.: UG/ML *100ML *100%/100% *(NA/NA )/1/3SA HA H
Enhanced (S 15B 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
760 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 42196 HEPTADECANE, 2,6,10,14-TETRAMETHYL-
2 37462 HEPTADECANE, 2,6-DIMETHYL-
3 25997 PENTADECANE
4 37465 NONADECANE
5 19016 UMOECANE, 4,7-DIMETHYL-
6 25991 DOOECANE, 2,6,10-TRIMETHYL-
7 18987 UNDECANE, 2,8-DIMETHYL-
8 15353 2,6-DIMETHYLDECANE
9 29263 HEXADECANE
M.Wt B.Pk Purity Fit RFit
Rank
1
2
3
4
5
6
7
8
9
Formula
C21.H44
C19.H40
C15.H32
C19.H40
C13.H28
C15.H32
C13.H28
C12.H26
C16.H34
296
268
212
268
184
212
184
170
226
57
57
57
57
43
57
43
43
57
831
804
783
783
779
778
778
774
768
975
949
945
930
954
958
965
920
915
842
823
795
815
780
781
782
783
784
Rank
1
2
3
u
5
6
7
8
9
Ret.Time
B.P.Int.
US.Par.1
US.Par.2
C.A.S
18344
54105
629
629
17301
3891
17301
13150
544
#
37-1
67-8
62-9
92-5
32-5
98-3
25-6
81-7
76-3
-------
MID LIBRARY SEARCH CLIBRARYNB)
08/31/98 19:00:00 + 9:07
SAMPLE: S-MM5-2 1/3SA/100M
CONDS.: UG/ML *100ML
ENHANCED
DATA: 30068101
CALI: 30068101
INST. ID: F16
*
-------
Library Search Data: 30068101 # 858
08/31/98 19:00:00 + 9:33 Cali: 30068101 # 3
Sample: S-MM5-2 1/3SA/100M 1NST. ID: F16
Conds.: UG/ML *100ML *100%/100% *(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
Base m/z: 43
RIC: 130176.
62231 spectra in L1BRARYNB searched for maximum PURITY
835 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 15352 UNDECANE, 2-METHYL-
2 19007 DOOECANE, 3-METHYL-
3 25997 PENTADECANE
4 19006 OECANE, 6-ETHYL-2-METHYL-
5 18998 UNDECANE, 3,7-DIMETHYL-
6 22530 TETRADECANE
7 15353 2,6-DIMETHYLDECANE
8 15343 DOOECANE
9 37465 NONADECANE
Rank
1
2
3
4
5
6
7
Rank
1
2
3
4
5
6
7
8
9
Formula
C12.H26
C13.H28
C15.H32
C13.H28
C13.H28
C14.H30
C12.H26
C12.H26
C19.H40
Ret.Time
M.Ut B.Pk Purity Fit RFit
B.P.Int.
US.Par.1
170
184
212
184
184
198
170
170
268
43
57
57
57
43
43
43
57
57
US. Par. 2
752 945
748 962
748 954
742 965
738 950
738 936
737 914
734 984
732 925
C.A.S. #
7045-71-8
17312-57-1
629-62-9
62108-21-8
17301-29-0
629-59-4
13150-81-7
112-40-3
629-92-5
752
749
753
742
738
772
737
739
759
711
-------
MID LIBRARY SEARCH (LIBRARYNB) DATA:
08/31/98 19:00:00 + 9:33 CALI:
SAMPLE: S-MM5-2 1/3SA/100M INST. ID: F16
CONDS.: UG/ML *100ML *100?./100Z *
-------
Library Search Data: 30068101 # 904
08/31/98 19:00:00 + 10:03 Cali: 30068101 * 3
Sample: S-MM5-2 1/3SA/100M INST. ID: F16
Conds.: UG/ML *100ML *100%/100% *(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
Base m/z: 43
RIC: 47040.
62231 spectra in LIBRARYNB searched for maximum PURITY
751 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 40233 NONADECANOL
2 42521 1-EICOSANOL
3 42180 OCTADECANE, 1-(ETHENYLOXY)-
4 15969 HYDROXYLAMINE, 0-DECYL-
5 25971 OXIRANE, OOOECYL-
6 58380 DECANEDIOIC ACID, DIDECYL ESTER
7 37444 OXIRANE, HEXADECYL-
8 37449 OCTADECANAL
9 19520 1-OCTANOL, 2-BUTYL-
Rank Formula
1
2
3
4
5
6
7
8
9
C19.H40.0
C20.H42.0
C20.H40.0
C10.H23.0.N
C14.H28.0
C30.H58.04
C18.H36.0
C18.H36.0
C12.H26.0
M.Wt B.Pk Purity Fit RFit
284
298
296
173
212
482
268
268
186
43
43
43
43
41
57
57
43
57
674
670
647
638
636
634
634
633
633
938
931
941
906
902
919
841
852
921
703
705
677
649
648
649
687
687
642
Rank
1
2
3
4
5
6
7
8
9
Ret.Time
B.P.Int.
US.Par.1
US.Par.2
C.A.S. *
52783-43-4
629-96-9
930-02-9
29812-79-1
3234-28-4
2432-89-5
7390-81-0
638-66-4
3913-02-8
-------
1132
SAMPLE
MID LIBRARY SEARCH (LIBRARYNB)
08/31/98 19:00:00 + 10:03
SAMPLE: S-MM5-2 1/3SA/100M INST. ID: F16
CONDS.: UG/ML *100ML *100Z/100Z *CNA/NA )/l/3SA NA M
ENHANCED -
M/2
50
100
150
200
250
-------
Library Search Data: 30068101 # 948 Base m/z: 57
08/31/98 19:00:00 + 10:33 Call: 30068101 # 3 RIC: 114816.
Sample: S-MM5-2 1/3SA/100M INST. ID: F16
Conds.: UG/ML *100ML *100%/100% '(NA/NA }/1/3SA NA M
Enhanced (S 15B 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
343 matched at least 8 of the 16 largest peaks in the unknown
Rank In. Name
1 37465 NONADECANE
2 37462 HEPTADECANE, 2,6-DlMETHYL-
3 15969 HYDROXYLAMINE, 0-DECYL-
4 42196 HEPTADECANE, 2,6,10,14-TETRAMETHYL-
5 25997 PENTADECANE
6 19016 UNDECANE, 4,7-DIMETHYL-
7 25994 DOOECANE, 2,6,11-TR1METHYL-
8 26001 DODECANE, 2,7,10-TRIMETHYL-
9 19523 1-DECANOL, 2-ETHYL-
Rank
1
2
3
4
5
6
7
8
9
Formula
C19.H40
C19.H40
C10.H23.0.N
C21.H44
C15.H32
C13.H28
C15.H32
C15.H32
C12.H26.0
M.Ut B.Pk Purity Fit RFit
268
268
173
296
212
184
212
212
186
57
57
43
57
57
43
57
57
57
833
817
817
806
803
799
792
783
782
956
936
966
944
949
966
961
956
925
854
844
817
830
833
800
795
788
795
Rank
1
2
3
4
5
6
7
8
9
Ret.Time
B.P.Int.
US.Par.1
US.Par.2
C.A.S
629
54105
29812
18344
629
17301
31295
74645
21078
92-5
67-8
79-1
37-1
62-9
32-5
56-4
98-0
65-9
JL '
-------
MID LIBRARY SEARCH (LIBRARYNB)
08/31/98 19:80:00 + 10:33
SAMPLE: S-MM5-2 1/3SA/100M INST. ID: FIG
CONDS.: UG/ML *100ML *10072/1007* */l/3SA NA M
ENHANCED
DATA: 30068101 # 948
CALI: 30068101 tt 3
BASE M/Z: 57
RIC: 114816.
1022 i
SAMPLE
1
C19.H40
1022 i
M WT 268
B PK 57
RANK 1
# 37465
PUR 833
C19.H40
1022 -j
M WT 268
B PK 57
RANK 2
# 37462
PUR 817
C10.H23.0.K
1022
M WT 173
B PK 43
RANK 3
# 15969
PUR 817
l_l
L, Jl
" n-iii - .-''. i --- - --
NONADECANE Or t Sow^V ' ....
ll
1
, ll
, . H
, ll ..1 ... . .. ...
HEPTADECANE, 2,6-DIMETHYL-
. . ll
ii i i -il
1 HYDROXYLAMINE, 0-DECYL-
|l
II
.h ,. .,
M/Z
50
100
150
200
250
-J
-------
Library Search Data: 30068101 # 987
08/31/98 19:00:00 + 10:59 Cali: 30068101 # 3
Sample: S-MM5-2 1/3SA/100M INST. ID: F16
Conds.: UG/ML *100ML *100%/100% *(NA/NA )/1/3SA NA M
Enhanced (S 158 2N OT)
Base m/z: 57
RIC: 96384.
62231 spectra in L1BRARYNB searched for maximum PURITY
644 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 37462 HEPTADECANE, 2,6-DIMETHYL-
2 37465 NONADECANE
3 25997 PENTADECANE
4 42196 HEPTADECANE, 2,6,10,14-TETRAMETHYL-
5 25996 TRIDECANE, 4,8-DIMETHYL-
6 22530 TETRADECANE
7 32059 HEPTADECANE
8 29263 HEXADECANE
9 22527 DOOECANE, 2,5-DIMETHYL-
Rank
1
2
3
4
5
6
7
8
9
Formula
C19.H40
C19.H40
C15.H32
C21.H44
C15.H32
C14.H30
C17.H36
C16.H34
C14.H30
H.Ut
268
268
212
296
212
198
240
226
198
B.Pk
57
57
57
57
57
43
57
57
57
Purity
817
812
806
805
803
801
801
799
796
Fit
949
938
952
951
936
942
935
934
942
RFit
825
831
810
812
814
806
811
808
797
Rank
1
2
3
4
5
6
7
8
9
Ret.Time
B.P.Int.
US.Par.1
US.Par.2
C.A.S.
54105-
629-
629-
18344
55030-
629-
629
544-
56292
#
67-8
92-5
62-9
37-1
62-1
59-4
78-7
76-3
65-0
71'
-------
MID LIBRARY SEARCH CLIBRARYNB)
08/31/98 19:00:00 + 10:59
SAMPLE: S-MM5-2 1/3SA/100M INST. ID: FIG
CONDS.: KG/ML *100ML *100Z/100Z *
DATA: 30068101 # 987 BASE M/Z: 57
CALI: 30068101 # 3 RIC: 96384.
1000
SAMPLE
C19.H40
1000
M WT 268
B PK 57
RANK 1
# 37462
PUR 817
C19.H40
1000
M WT 268
B PK 57
RANK 2
# 37465
PUR 812
C15.H32
1000
M WT 212
B PK 57
RANK 3
# 25997
PUR 806
M/Z
HEPTADECANE, 26-DIMETHYL-
NONADECANE
-" ^"T~
PENTADECANE
|
50
-JT-
100
150
200
250
-------
Library Search Data: 30068101 #1035 Base m/z: 57
08/31/98 19:00:00 + 11:31 Call: 30068101 # 3 RIC: 149504.
Sample: S-MM5-2 1/3SA/100M INST. 10: F16
Conds.: UG/ML *100ML *100%/100% *
-------
MID LIBRARY SEARCH CLIBRARYNB)
08/31/98 19:00:00 + 11:31
SAMPLE: S-MM5-2 1/3SA/100M
CONDS.: UG/ML *100ML
ENHANCED
DATA: 30068101 #1035
CALI: 30068101 # 3
INST. ID: F16
*
-------
Library Search Data: 30068101 #1114 Base m/z: 57
08/31/98 19:00:00 + 12:23 Cali: 30068101 # 3 RIC: 60416.
Sample: S-MM5-2 1/3SA/100M INST. ID: F16
Conds.: UG/ML *100ML *100%/100% *(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
651 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 37462 HEPTADECANE, 2,6-DIMETHYL-
2 37465 NONADECANE
3 19016 UNDECANE, 4,7-DIMETHYl-
4 19006 DECANE, 6-ETHYL-2-METHYL-
5 19056 UNDECANE, 2,7-DIMETHYL-
6 8102 HEXANE, 2,2,3,3-TETRAMETHYL-
7 19028 DECANE, 2,4,6-TRlMETHYL-
8 15356 OECANE, 2,4-DIMETHYL-
9 22530 TETRADECANE
Rank
1
2
3
4
5
6
7
8
9
Formula
C19.H40
C19.H40
C13.H28
C13.H28
C13.H28
C10.H22
C13.H28
C12.H26
C14.H30
M.Ut B.Pk Purity Fit RFit
Rank
1
2
3
4
5
6
7
8
9
268
268
184
184
184
142
184
170
198
57
57
43
57
43
57
43
43
43
791
775
769
768
767
767
767
765
763
910
896
922
934
942
920
938
944
899
847
852
805
799
779
774
789
776
841
Ret.Time
B.P.Int.
US.Par.1 US.Par.2
C.A.S. #
54105-67-8
629-92-5
17301-32-5
62108-21-8
17301-24-5
13475-81-5
62108-27-4
2801-84-5
629-59-4
-------
MID LIBRARY SEARCH
08/31/98 19:09:09 + 12:23
SAMPLE: S-MM5-2 1/3SA/100M INST. ID: F16
CONDS.: UG/ML *100ML *100Z/1007> *
DATA: 30868101 #1114 BASE M/Z: 57
CALI: 30068101 # 3 RIC: 60416.
1199
SAMPLE
I I
C19.H40
1199
M WT 268
B PK 57
RANK 1
# 37462
PUR 791
HEPTADECANE, 2,6-DIMETHYL-
C19.H40
1199-j
M WT 268
B PK 57
RANK 2
tt 37465
PUR 775
NONADECANE
1
II
M | , . '''. . ...-.. I - . . M , . .., . | . . , ^-. . , . , 1 , 1 , , . . , r^-, .
C13.H28
1199 i
M WT 184
B PK 43
RANK 3
ป 19016
PUR 769
M/Z
|
r
UNDEC ANE , 4 , 7-D I METHYL-
L
II
,1
50 100 150 200 250
ro
-------
Library Search Data: 30068101 #1119 Base m/z: 57
08/31/98 19:00:00 + 12:27 Call: 30068101 # 3 RIC: 88576.
Sample: S-MM5-2 1/3SA/100M INST. ID: F16
Conds.: UG/ML *100ML *100%/100% *(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
590 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 37462 HEPTADECANE,
2,6-DIMETHYL-
2,6,10,14-TETRAMETHYL-
2 37465 NONADECANE
3 42196 HEPTADECANE,
4 46161 TRICOSANE
5 25991 DODECANE, 2,6,10-TRIMETHYL-
6 37466 PENTADECANE, 2,6,10,14-TETRAMETHYL-
7 42192 HEPTADECANE, 2,6,10,15-TETRAMETHYL-
8 26001 DOOECANE, 2,7,10-TRiMETHYL-
9 32059 HEPTADECANE
Rank
1
2
3
4
5
6
7
8
9
Rank
1
2
3
i.
5
6
7
a
9
Formula
C19.H40
C19.H40
C21.H44
C23.H48
C15.H32
C19.H40
C21.H44
C15.H32
C17.H36
Ret .Time
M.Wt B.Pk Purity Fit RFit
B.P.Int.
US.Par.1
268
268
296
324
212
268
296
212
240
57
57
57
43
57
71
57
57
57
US. Par. 2
823 950
820 956
815 944
804 921
797 970
795 939
794 956
789 971
788 927
C.A.S. #
54105-67-8
629-92-5
18344-37-1
638-67-5
3891-98-3
1921-70-6
54833-48-6
74645-98-0
629-78-7
828
838
828
845
798
801
819
789
820
-------
MID LIBRARY SEARCH
08/31/98 19:00:00 + 12:27
SAMPLE: S-MM5-2 1/3SA/180M INST. ID: F16
CONDS.: UG/ML *100ML * 100Z/100?. */l/3SA NA M
ENHANCED (S 15B 2N 0T)
DATA: 30068101 #1119 BASE M/Z: 57
CALI: 30068101 # 3 RIC: 88576.
1145
SAMPLE
J~
C19.H40
1145
M WT 268
B PK 57
RANK 1
ft 37462
PUR 823
HEPTADECANE, 2,6-DIMETHYL-
C19.H40
1145 i
M WT 268
B PK 57
RANK 2
ft 37465 '
PUR 820
NONADECANE
1,
, n
. II
, . 1.1. . ...1 , , 1 . . . '
C21.H44
1145
M WT 296
B PK 57
RANK 3
ft 42196
PUR 815
M/Z
HEPTADECANE, 2,6,10,14-TETRAMETHYL-
T
50
109
150
200
250
-------
Library Search Data: 30068101 #1191 Base m/z: 57
08/31/98 19:00:00 + 13:15 Cali: 30068101 # 3 RIC: 54912.
Sample: S-MM5-2 1/3SA/100M INST. ID: F16
Conds.: UG/ML *100ML *100%/100% *(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
62231 spectra in L1BRARYNB searched for maximum PURITY
294 matched at least 8 of the 16 largest peaks in the unknown
Rank In. Name
1 37465 NONADECANE
2 37462 HEPTADECANE, 2,6-DIMETHYL-
3 42196 HEPTADECANE, 2,6,10,14-TETRAMETHYL-
4 15969 HYDROXYLAMINE, 0-DECYL-
5 25997 PENTADECANE
6 46161 TR1COSANE
7 19016 UNDECANE, 4,7-DIMETHYL-
8 25994 DODECANE, 2,6,11-TRIMETHYL-
9 19523 1-DECANOL, 2-ETHYL-
Rank Formula
1
2
3
4
5
6
7
8
9
C19.
C19.
C21.
C10.
C15.
C23.
C13.
C15.
C12,
.H40
.H40
. H44
.H23.0.N
.H32
.H48
. H28
.H32
.H26.0
M.Wt B.Pk Purity Fit RFit
268
268
296
173
212
324
184
212
186
57
57
57
43
57
43
43
57
57
756
742
736
729
725
724
719
706
703
969
941
952
968
958
910
962
958
937
766
760
758
729
747
786
720
709
707
Rank
1
2
3
4
5
6
7
8
9
Ret.Time
B.P.Int.
US.Par.1
US.Par.2
C.A.S
629
54105
18344
29812
629
638
17301
31295
21078
#
92-5
67-8
37-1
79-1
62-9
67-5
32-5
56-4
65-9
-------
MID LIBRARY SEARCH (LIBRARYHB)
08/31/98 19:00:00 + 13:15
SAMPLE: S-MM5-2 1/3SA/100M INST. ID: F16
CONDS.: UG/ML *100ML *100Z/10072 */l/3SA NA M
ENHANCED
DATA: 30068101 #1191 BASE M/Z: 57
CALI: 30068101 # 3 RIC: 54912.
1044
SAMPLE
C19.H40
1044
M WT 268
B PK 57
RANK 1
# 37465
PUR 756
NONADECANE
C19.H40
1044 i
M WT 268
B PK 57
RANK 2
# 37462
PUR 742
|
||
HEPTADECANE, 2,6-DIMETHYL-
1
,i , i .il , . ., . ... ... .. .,.
C21.H44
1044
M WT 296
B PK 57
RANK 3
# 42196
PUR 736
M/Z
HEPTADECANE, 2,6,10,14-TETRAMETHYL-
50
100
150
200
250
si
-------
Base m/z: 57
R1C: 45120.
Library Search Data: 30068101 #1264
08/31/98 19:00:00 + 14:04 Cali: 30068101 # 3
Sample: S-MM5-2 1/3SA/100M INST. ID: F16
Conds.: UG/ML *100ML *100%/100% *(NA/NA )/1/3SA NA M
Enhanced (S 158 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
298 matched at Least 8 of the 16 largest peaks in the unknown
Rank In. Name
1 37465 NONADECANE
2 46161 TRICOSANE
3 37462 HEPTADECANE
4 42196 HEPTADECANE
5 25997 PENTADECANE
6 49555 PENTACOSANE
7 42192 HEPTADECANE
8 32059 HEPTADECANE
9 15969 HYDROXYLAMINE, 0-DECYL-
2,6-DIMETHYL-
2,6,10,14-TETRAMETHYL-
2,6,10,15-TETRAMETHYL-
Rank
1
2
3
4
5
6
7
8
9
Rank
1
2
3
t.
5
6
7
8
9
Formula
C19.H40
C23.H48
C19.H40
C21.H44
C15.H32
C25.H52
C21.H44
C17.H36
C10.H23.0.N
Ret .Time
M.Ut B.Pk Purity Fit RFit
268
324
268
296
212
352
296
240
173
57
43
57
57
57
43
57
57
43
773
760
758
755
748
745
731
731
730
969
923
931
947
982
901
932
928
967
791
816
778
771
753
819
759
759
732
B.P.Int.
US.Par.1
US.Par.2
C.A.S,
629-
638-
54105-
18344-
629
629-
54833-
629-
29812-
#
92-5
67-5
67-8
37-1
62-9
99-2
48-6
78-7
79-1
-------
MID LIBRARY SEARCH (LIBRARYNB)
08/31'98 19:00:00 + 14:04
SAMPLE: S-MM5-2 1/3SA/100M INST. ID: F16
CONDS.: UG/ML *100ML *100Z/100Z *
DATA: 30068101 #1264 BASE M/Z: 57
CALI: 30068101 # 3 RIC: 45120.
1132
SAMPLE
C19.H40
1132
M WT 268
B PK 57
RANK 1
# 37465
PUR 773
C23.H48
1132
M WT 324
B PK 43
RANK 2
* 46161
PUR 760
NONADECANE O
II
TRICOSANE
C19.H40
1132 T
M WT 268
B PK 57
RANK 3
# 37462
PUR 758
M/2
HEPTADECANE, 2,6-DIMETHYL-
50
100
150
200
250
300
Vj
-------
Library Search Data: 30068101 #1335
08/31/98 19:00:00 + 14:51 Call: 30068101 # 3
Sample: S-MM5-2 1/3SA/100M 1NST. ID: F16
Conds.: UG/ML *100ML *100%/100% *(NA/NA )/1/3SA NA M
Enhanced (S 158 2N OT)
Base m/z: 57
RIC: 29728.
62231 spectra in LIBRARYNB searched for maximum PURITY
474 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 42196 HEPTADECANE, 2,6,10,14-TETRAMETHYL-
2 37456 2-METHYLOCTADECANE
3 37462 HEPTADECANE, 2,6-DIMETHYL-
4 29263 HEXADECANE
5 37465 NONADECANE
6 25997 PENTADECANE
7 32058 HEXADECANE, 3-METHYl-
8 46161 TRICOSANE
9 42192 HEPTADECANE, 2,6,10,15-TETRAMETHYL-
M.Wt B.Pk Purity Fit RFit
Rank
1
2
3
4
5
6
7
8
9
Rank
1
2
3
4
5
6
7
8
9
Formula
C21.H44
C19.H40
C19.H40
C16.H34
C19.H40
C15.H32
C17.H36
C23.H48
C21.H44
Ret .T ime
296
268
268
226
268
212
240
324
296
57
43
57
57
57
57
57
43
57
691
689
683
683
682
672
664
660
657
910
925
889
939
951
968
919
896
922
713
709
712
700
707
680
691
725
687
B.P.Int.
US.Par.1
US.Par.2
C.A.S. #
18344-37-1
54105-67-8
544-76-3
629-92-5
629-62-9
6418-43-5
638-67-5
54833-48-6
7ฃ
-------
MID LIBRARY SEARCH
-------
Library Search Data: 30068101 #1402
08/31/98 19:00:00 + 15:36 Cati: 30068101 * 3
Sample: S-MM5-2 1/3SA/100M INST. ID: f16
Conds.: UG/ML *100ML *100%/100% *(NA/NA J/1/3SA NA M
Enhanced (S 158 2N OT)
Base m/z: 57
RIC: 23168.
62231 spectra in LIBRARYNB searched for maximum PURITY
850 matched at Least 7 of the 16 largest peaks in the unknown
2,6-OIMETHYL-
2,6,10,14-TETRAMETHYL-
Rank In. Name
1 37465 NONADECANE
2 37462 HEPTADECANE,
3 42196 HEPTADECANE,
4 46161 TRICOSANE
5 37456 2-METHYLOCTADECANE
6 25997 PENTADECANE
7 42192 HEPTADECANE, 2,6,10,15-TETRAMETHYL-
8 15969 HYDROXYLAMINE, 0-DECYL-
9 49555 PENTACOSANE
Rank
1
2
3
L,
5
6
7
8
9
Formula
C19.H40
C19.H40
C21 .H44
C23.H48
C19.H40
C15.H32
C21.H44
C10.H23.0.N
C25.H52
M.Wt B.Pk Purity Fit RFit
Rank
1
2
3
4
5
6
7
Ret.Time
B.P.Int.
US.Par.1
268
268
296
324
268
212
296
173
352
US,
57
57
57
43
43
57
57
43
43
.Par. 2
716 961
702 934
696 945
694 920
685 942
684 967
680 940
676 966
673 885
C.A.S. #
629-92-5
54105-67-8
18344-37-1
638-67-5
629-62-9
54833-48-6
29812-79-1
629-99-2
738
715
709
749
711
691
703
678
756
-------
MID LIBRARY SEARCH CLIBRARYNB)
08/31/98 19:00:00 + 15:36
SAMPLE: S-MM5-2 1/3SA/100M
CONDS.: UG/ML *100ML
ENHANCED
-------
TIC SELECTION REPORT
DATA FILE: 30068101
THE FOLLOWING PEAKS WERE REJECTED BECAUSE
AT LEAST 40 % OF THEIR SIZE WAS ACCOUNTED FOR BY
TARGET COMPOUNDS ELUTING WITHIN 4 SCANS OF THE
PEAK TOP.
SCAN SIZE AMOUNT
341
530
829
1087
1552
1783
170240.
300480.
283264.
334464.
199007.
185564.
22.662
40.000
40.000
40.000
40.000
40.000
TOTAL NUMBER OF UNIDENTIFIED PEAKS WITH SIZE
GREATER THAN 10 % OF THE CLOSEST INTERNAL STANDARD
THAT DOES NOT HAVE INTERFERENCES = 94
INTERNAL STANDARDS THAT HAVE RIC SIZE LESS THAN
50 % OR GREATER THAN 200 % OF THE ESTIMATED RIC SIZE
ARE CONSIDERED TO HAVE INTERFERENCES AND WILL NOT BE USED
FOR QUANT I TAT I ON.
PERCENT OF
ESTIMATED
# INTERNAL STANDARD RIC SIZE RIC SIZE SCAN
1 C140 NAPHTHALENE-08
2 CI50 ACENAPHTHENE-D10
3 CI60 PHENANTHRENE-D10
4 CI70 CHRYSENE-D12
5 CI75 PERYLENE-D12
300480.
283264.
334464.
199007.
185564.
196
147
154
142
154
530
829
1087
1552
1783
* INDICATES INTERFERENCE
SIZE = AREA
-------
Semi volatile Organics
Method 0010/8270
Client Name: Pacific Environmental Services
Client ID: S-MM5-1B-F,FH,XAD,COND,BH
LAB ID: 300681-0002-SA
Matrix: AIRTRAIN Sampled: 25 JUL 98
Authorized: 30 JUL 98 Prepared: 31 JUL 98
Dilution Factor: 100
Parameter
Phenol
bis(2-Chloroethyl)ether
2-Chlorophenol
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Benzyl alcohol
1,2-Dichlorobenzene
2-Methylphenol
2,2'-Oxybis(l-chloropropane)
3/4-Methylphenol
N-Nitroso-di-n-propylamine
Hexachloroethane
Nitrobenzene
Isophorone
2-Nitrophenol
2,4-Dimethylphenol
Benzoic acid
bi s(2-Chloroethoxy)-methane
2,4-Dichlorophenol
1,2,4-Trichlorobenzene
Naphthalene
4-Chloroaniline
Hexachlorobutadiene
4-Chloro-3-methyl phenol
2-Methylnaphtha!ene
Hexachlorocyclopentadi ene
2,4,6-Trichlorophenol
2,4,5-Trichlorophenol
2-Chloronaphthalene
2-Nitroaniline
Dimethyl phthalate
Acenaphthylene
3-Nitroaniline
Acenaphthene
2,4-Dinitrophenol
4-Nitrophenol
Wet wt.
Result
Units
Received: 30 JUL 98
Analyzed: 31 AUG 98
Reporting
Limit
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
4700
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
15000
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
15000
3000
3000
3000
3000
15000
3000
15000
15000
Qualifier
RG
Note G = Reporting limit(s) raised due to matrix interference.
Note R = Reporting limit(s) raised due to sample volume limitations.
ND = Not Detected
Reported By: Emily Uebelhoer
Approved By: Mike Orbanosky
The cover letter is an integral part of this report.
Rev 230787
-------
Semivolatile Organics
Method 0010/8270
Client Name: Pacific Environmental Services
Client ID: S-MM5-1B-F,FH,XAD,COND,BH
LAB ID: 300681-0002-SA
Matrix: AIRTRAIN Sampled: 25 JUL 98
Authorized: 30 JUL 98 Prepared: 31 JUL 98
(cont.)
Dilution Factor: 100
Parameter
Dibenzofuran
2,4-Dinitrotoluene
2,6-Dinitrotoluene
Diethyl phthalate
4-Chlorophenyl phenyl ether
Fluorene
4-Nitroanil ine
4,6-Dinitro-2-methylphenol
N-Nitrosodiphenylamine
4-Bromophenyl phenyl ether
Hexachlorobenzene
Pentachlorophenol
Phenanthrene
Anthracene
Di-n-butyl phthalate
Fluoranthene
Pyrene
Butyl benzyl phthalate
3,3'-Dichlorobenzidine
Benzo(a)anthra-:ene
bis(2-Ethylhexyl)-phthalate
Chrysene
Di-n-octyl phthalate
Benzo b fluoranthene
Benzo k fluoranthene
Benzo a pyrene
Indeno(l,2,3-cd)pyrene
Dibenz(a,h)anthracene
Benzo(g,h,i)perylene
Acetophenone
4-Aminobiphenyl
Aniline
Benzidine
3,3'-Dimethylbenzidine
N-Nitrosodimethyl amine
N-Nitrosomorpholine
Pentachloronitrobenzene (PCNB)
o-Toluidine
Wet wt.
Result
Units
Received: 30 JUL 98
Analyzed: 31 AUG 98
Reporting
Limit
Qualifier
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
3000
3000
3000
3000
3000
3000
15000
15000
3000
3000
3000
15000
3000
3000
3000
3000
3000
3000
6000
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
15000
3000
30000
6000
3000
3000
15000
6000
ซ: r-
ND = Not Detected
Reported By: Emily Uebelhoer
Approved By: Mike Orbanosky
The cover letter is an integral part of this report.
Rev 230787
-------
Semivolatile Organics
Method 0010/8270
Client Name: Pacific Environmental Services
Client ID: S-MM5-1B-F,FH,XAD,COND,BH
LAB ID: 300681-0002-SA
Matrix: AIRTRAIN Sampled: 25 JUL 98
Authorized: 30 JUL 98 Prepared: 31 JUL 98
Dilution Factor: 100
Wet wt.
Parameter Result Units
2-Methoxybenzenamine ND ug/Sample
Biphenyl ND ug/Sample
Chloroacetophenone ND ug/Sample
Cumene ND ug/Sample
DBCP U,2-Dibromo-3-chloropropane) ND ug/Sample
Benzo(e)pyrene ND ug/Sample
N-N-Diethylaniline ND ug/Sample
Dimethylaniline ND ug/Sample
3,3'-Dimethoxybenzidine ND ug/Sample
Hydroquinone ND ug/Sample
4,4'-Methyl-bis(2-chloroaniline) ND ug/Sample
4-Nitrodiphenyl ND ug/Sample
Trifluralin ND ug/Sample
(cont.)
Received: 30 JUL 98
Analyzed: 31 AUG 98
Reporting
Limit
Qualifier
Surrogate
Nitrobenzene-d5
2-Fluorobiphenyl
Terphenyl-dl4
Phenol-d5
2-Fluorophenol
2,4,6-Tribromophenol
Recovery
ND
ND
ND
ND %
ND
ND
Acceptable Range
45
62
58
43
36
58
107
110
135
130
111
131
Note H = Spiked analyte not detected because of required sample dilution.
ND = Not Detected
Reported By: Emily Uebelhoer
Approved By: Mike Orbanosky
The cover letter is an integral part of this report.
Rev 230787
-------
Semivolatiles Library Search (20 Compound TID)
Method 8270
Client Name: Pacific Environmental Services
Client ID: S-MM5-1B-F,FH,XAD,COND,BH
LAB ID: 300681-0002-SA
Matrix: AIRTRAIN Sampled: 25 JUL 98
Authorized: 30 JUL 98 Prepared: NA
Dilution Factor: 100
Parameter Result Units
Unknown alkane 7800 ug/Sample
Dodecane 7800 ug/Sample
Unknown 15000 ug/Sample
Unknown hydrocarbon 17000 ug/Sample
3-Hexadecene, (z)- 10000 ug/Sample
Undecane 11000 ug/Sample
Unknown alkane 20000 ug/Sample
Unknown alkane 26000 ug/Sample
Unknown 14000 ug/Sample
Heptadecane, 2,6,10,14 -tetramethyl- 22000 ug/Sample
Dodecane, 3-methyl- 22000 ug/Sample
Unknown alkane 9900 ug/Sample
Nonadecane 26000 ug/Sample
Nonadecane 18000 ug/Sample
Heptadecane, 2,6-dimethyl- 40000 ug/Sample
Unknown alkane 12000 ug/Sample
Nonadecane 17000 ug/Sample
Nonadecane 8100 ug/Sample
Nonadecane 9800 ug/Sample
Nonadecane 7800 ug/Sample
Received: 30 JUL 98
Analyzed: 31 AUG 98
Reporting
Limit
Qualifier
0
0
0
0
0
0
0
0
0
0
0
Note 0 = Or structurally similar compound (isomer).
NA = Not Applicable
*-, <
/ C
Reported By: Emily Uebelhoer
Approved By: Mike Orbanosky
The cover letter is an integral part of this report.
Rev 230787
-------
O?
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O'OOOE
O'OOOE
O'OOOE
O'OOOE
O'OOOE
O'OOOE
O'OOOE
O'OOOE
O'OOOE
O'OOOE
O'OOOE
O'OOOE
O'OOOE
O'OOOE
O'OOOE
O'OOOE
O'OOOE
O'OOOE
O'OOOE
O'OOOE
O'OOOE
O'OOOE
O'OOOE
O'OOOE
O'OOOE
O'OOOE
0'0009
O'OOOE
O'OOOE
:Aq p3ซ3!A3Jj
v/on
v/on
v/on
v/on
v/on
v/on
v/on
v/on
v/on
v/on
v/on
v/on
v/on
v/on
v/on
v/on
v/on
v/on
v/on
v/on
v/on
v/on
v/on
v/on
v/on
v/on
v/on
v/on
v/on
ON
ON
ON
ON
ON
ON
ON
ON
ON
ON
ON
ON
ON
ON
ON
ON
ON
ON
ON
ON
ON
ON
ON
ON
ON
ON
ON
ON
ON
3Niai83dIdOSOaiIN-N
3N3ZN3SOH1IN DIM
3NVH130i)01H3VX3H S/E3
3Niainioi-o
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lONSHdlAHiSW-1? S9E3
10N3Hd 1AHX3W-E
3N 1 lOHdaONOSOUl I N - N
3Niai10aaAdOSOiUIN-N
3NON3HdCU33V L9E3
(NVdO!Jd13-L)S!flAXO-ie'Z 09E3
10N3Hd1AHi3H-Z SSE3
3N3ZN380ii01H3!a-Z'l OSE3
10H031V 1AZN38 S^EO
3N3ZN3BOa01H3IO-V'L 0^3
3N3ZN3BOป01H3IO-E'l 5EE3
10N3HdO!i01H3-Z OEE3
a3Hi3C1AHi30ป01H3-Z)SI8 SZE3
10N3Hd SLE3
3NI1INV OZE3
3NVH130M01H3ViN3d
31VNOdinS 3NVHi3W1AH13
3NIWV1AH13IOOSOi)iIN-N
3iVNOdinS3NVH13W1AHi3W
3NIWV1AH131AHi3WOSO!)lIN-N
3NI103Id-Z
3NIOI!IAd
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85
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OU Z9 ป0 108 O'OS AN3Hd!80aonid-Z SZS3
/Ol <& Vl ป0 108 O'OS SO-3N3ZN3808)iIN OZS3
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(6n) junouiv
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IE80869US =PI PIS
E018900E :31H BIBQ
laaqs Ajeuuns ejeo punoduK>3
SW/33
-------
OUANTERRA GC/MS
Target Compound Data Summary Sheet
Sample: S-MM5-1B
Client: PACIF1
Analyst: DAT
1/3SA/100M
INST. ID:
Instrument ID: F16
Data File: 30068102
Std Id: ST16980831
F16
Date Analyzed: 08/31/98 19:31
Run Factor: 300.
Quan List Threshold: 0.95
Surrogate Vol.:
100.
Parameter
Target Compounds: SAP9
Scan
C415 1SOPHORONE
C420 2-N1TROPHENOL
C425 2,4-DIMETHYLPHENOL
C435 BIS(2-CHLOROETHOXY)METH
C440 2,4-DICHLOROPHENOL
C430 BENZOIC ACID
AA-DIMETHYLPHENETHYLAMINE
C445 1,2,4-TRICHLOROBENZENE
C450 NAPHTHALENE
C455 4-CHLOROANALINE
2,6-DICHLOROPHENOL
HEXACHLOROPROPENE
C460 HEXACHLOROBUTADIENE
P-PHENYLENE DIAM1NE
N-NITROSOOI-N-BUTYLAMINE
C465 4-CHLORO-3-METHYLPHENO
SAFROLE
C470 2-METHYLNAPHTHALENE
1,2,4,5-TETRACHLOROBENZENE
1SOSAFROLE (#1)
C510 HEXACHLOROCYCLOPENTAD I
C515 2,4,6-TRICHLOROPHENOL
C520 2,4,5-TRICHLOROPHENOL
ISOSAFROLE (#2)
C525 2-CHLORONAPHTHALENE
1-CHLORONAPHTHALENE
C530 2-NITROANALINE
1,4-NAPHTHOQUINONE
C535 DIMETHYLPHTHALATE
1,3-DINITROBENZENE
C540 ACENAPHTHYLENE
C543 2,6-DINITROTOLUENE
C545 3-NITROANILINE
C550 ACENAPHTHENE
C555 2,4-DlNITROPHENOL
C565 DIBENZOFURAN
C560 4-NITROPHENOL
PENTACHLOROBENZENE
C570 2,4-DINITROTOLUENE
1-NAPHTHYLAMINE
2-NAPHTHYLAMINE
2,3,4,6-TETRACHLOROPHENOL
C580 DIETHYLPHTHALATE
C590 FLUORENE
652
Result
:==== = == =
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
JW \
/4700./
^Sr
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Units
r=========
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
Reporting
Limit
=============:
3000.0
3000.0
3000.0
3000.0
3000.0
15000.0
3000.0
3000.0
3000.0
3000.0
3000.0
3000.0
3000.0
3000.0
3000.0
3000.0
3000.0
3000.0
3000.0
6000.0
3000.0
3000.0
3000.0
6000.0
3000.0
1500.0
15000.0
3000.0
3000.0
3000.0
3000.0
3000.0
15000.0
3000.0
15000.0
3000.0
15000.0
3000.0
3000.0
3000.0
3000.0
6000.0
3000.0
3000.0
: C
-------
QUANTERRA GC/MS
Target Compound Data Summary Sheet
Data File: 30068102
Std Id: ST16980831
Sample: S-MM5-1B
Client: PAC1FI
Analyst: DAT
1/3SA/100M
INST. ID: F16
Instrument ID: F16
Date Analyzed: 08/31/98 19:31
Run Factor: 300.
Quan List Threshold: 0.95
Surrogate Vol.:
100.
Target Compounds: SAP9
Parameter
C585 4-CHLOROPHENYL-PHENYLE
5-NITRO-O-TOLUIDINE
C595 4-N1TROANALINE
C610 4.6-DINITRO-2-METHYLPH
C615 N-N1TROSODIPHENYLAMINE
C620 AZOBENZENE
SYM-TRINITROBENZENE
C625 4-BROMOPHENYL-PHENYLET
PHENACETIN
01ALLATE
C630 HEXACHLOROBENZENE
4-AMINOBIPHENYL
C635 PENTACHLOROPHENOL
PRONAMIDE
PENTACHLORONITROBENZENE
C640 PHENANTHRENE
C645 ANTHRACENE
2SECBUTYL-4.6-DIN1TROPHENOL
C647 CARBAZOLE
C650 DI-N-BUTYLPHTHALATE
4-NITROOUINOLINE-1-OXIDE
METHAPYRILENE
ISODRIN
C655 FLUORANTHENE
CHLOROBENZILATE
C710 BENZID1NE
C715 PYRENE
ARAMITE (#1)
ARAMITE (#2)
P-DIMETHYLAMINOAZOBENZENE
3,3'-DIMETHYLBENZIDINE
KEPONE
C720 BUTYLBENZYLPHTHALATE
2-ACETYLAMINOFLUORENE
C730 BENZO(A)ANTHRACENE
C725 3,3'-DICHLOROBENZIDINE
C740 CHRYSENE
C745 B1S(2-ETHYLHEXYL)PHTHA
3-METHYLCHOLANTHRENE
C760 DI-N-OCTYL PHTHALATE
C765 BENZO(B)FLUORANTHENE
7,12-DIMETHYLBENZANTHRACENE
C770 BENZOCK)FLUORANTHENE
HEXACHLOROPHENE
Scan Result
E ND
ND
ND
H NO
E ND
ND
NO
T ND
ND
34 ND
ND
NO
ND
ND
ND
ND
ND
L ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
NO
E NO
NO
A ND
NO
ND
ND
E ND
ND
NO
Units
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
Reporting
Limit
3000.0
3000.0
15000.0
15000.0
3000.0
3000.0
3000.0
3000.0
3000.0
3000.0
3000.0
3000.0
15000.0
3000.0
15000.0
3000.0
3000.0
3000.0
3000.0
3000.0
3000.0
3000.0
3000.0
3000.0
3000.0
30000.0
3000.0
3000.0
3000.0
3000.0
3000.0
15000.0
3000.0
3000.0
3000.0
6000.0
3000.0
3000.0
3000.0
3000.0
3000.0
3000.0
3000.0
3000.0
-------
QUANTERRA GC/MS
Target Compound Data Summary Sheet
Data File: 30068102
Std Id: ST16980831
Sample: S-MM5-1B 1/3SA/100M INST. ID: F16
Client: PACIFI Date Analyzed: 08/31/98 19:31
Analyst: DAT Instrument ID: F16 Run Factor: 300.
Quan List Threshold: 0.95 Surrogate Vol.: 100.
Target Compounds: SAP9
Parameter Scan Result Units
C775 BENZO(A)PYRENE NO UG/A
C780 INDENO(1,2,3-CD)PYRENE ND UG/A
C785 DIBENZ(A,H)ANTHRACENE ND UG/A
C790 BENZO(G,H,I)PERYLENE ND UG/A
Reporting
Limit
3000.0
3000.0
3000.0
3000.0
741
-------
DATA FROM FILE: 30068102 SCANS 93 TO 1203 ACQUIRED: 08/31/98 19:31:00
CALI: 30068102 #3
SAMPLE: S-MM5-1B 1/3SA/100M INST. ID: F16
CONDS.: UG/ML *100ML *100Z/1007. *
-------
DATA FROM FILE: 30068102 SCANS 1203 TO 2158 ACQUIRED: 08/31/98 19:31:00
CALI: 30068102 #3
SAMPLE: S-MM5-1B 1/3SA/100M INST. ID: F16
CONDS.: UG/ML *100ML *100Z/100Z *
-------
STANDARD USED FOR THIS REPORT IS ST16980831 REPORT PRINTED: 9/01/98 13:16:54
ADDITIONAL STANDARD USED FOR THIS REPORT IS: ST16980831A
OUANTERRA QUANT I TAT ION SUMMARY
File: 30068102
Sample: S-MM5-1B 1/3SA/100M INST. ID: F16
Analyst: DAT Instrument Id: F16 Analyzed: 08/31/98 19:31
Compounds with amounts less than 0.20 reported as NOT FOUND
Library
No
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
Entry
S1# 1
S2# 1
S3# 1
S4# 1
S5# 1
S6# 1
S2# 2
S3# 3
S5# 2
S1# 3
S1# 2
S3# 2
S4# 4
S1# 15
S1# 20
S1# 30
S1# 40
S1# 60
S1# 70
S1# 85
S1# 95
S1#100
S1#105
S1#110
S1#115
S1#125
S1#130
S1#145
S1#150
S1#160
S1#165
S1#170
S1#175
S1#180
S1#182
S1#185
S1#190
S1#195
SI #200
S2# 10
S2# 15
S2# 20
S2# 25
S2# 30
S2# 35
Name Mass
CI30 1,4-DICHLOROBENZENE
CI40 NAPHTHALENE-D8
CI50 ACENAPHTHENE-D10
CI60 PHENANTHRENE-D10
CI70 CHRYSENE-D12
CI75 PERYLENE-D12
CS20 NITROBENZENE-D5
CS25 2-FLUOROBIPHENYL
CS30 TERPHENYL-D14
CS45 PHENOL-D5
CS50 2-FLUOROPHENOL
CS55 2,4,6-TRIBROMOPHENO
HEXACHLOROBENZENE-C13
C310 N-NITROSODIMETHYLAM
PYRIDINE
2-PICOLINE
N-NITROSOMETHYLETHYLAMIN
METHYLMETHANESULFONATE
N-NITROSOD1ETHYLAMINE
ETHYLMETHANE SULFONATE
PENTACHLOROETHANE
C320 ANILINE
C315 PHENOL
C325 BIS(2-CHLOROETHYL)E
C330 2-CHLOROPHENOL
C335 1,3-DICHLOROBENZENE
C340 1,4-DICHLOROBENZENE
C345 BENZYL ALCOHOL
C350 1,2-DICHLOROBENZENE
C355 2-METHYLPHENOL
C360 2,2'-OXYBIS(1-CLPRO
C361 ACETOPHENONE
N-NITROSOPYRROLIDINE
N-N1TROSOMORPHOLINE
3-METHYL PHENOL
C365 4-METHYLPHENOL
C370 N-NITROSO-DI-N-PROP
0-TOLUIDINE
C375 HEXACHLOROETHANE
C410 NITROBENZENE
N-NITROSOPIPERIDINE
C415 ISOPHORONE
C420 2-NITROPHENOL
C425 2,4-DlMETHYLPHENOL
C435 BIS(2-CHLOROETHOXY)
152
136
164
188
240
264
82
172
244
99
112
330
294
74
79
93
42
80
102
79
117
93
94
93
128
146
146
108
146
108
45
105
100
56
108
108
70
106
117
77
42
82
139
107
93
Meth
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
BV
BB
BB
BB
BB
BB
BB
BB
BB
BV
BB
BB
VV
BB
BB
BB
BB
BB
BB
Scan Ref Area
340 1
530 2
829 3
1088 4
1552 5
1782 6
425 2
724 3
1384 5
1 NOT
198 1
971 3
4 NOT
1 NOT
1 NOT
1 NOT
1 NOT
1 NOT
1 NOT
1 NOT
306 1
1 NOT
1 NOT
1 NOT
1 NOT
1 NOT
1 NOT
372 1
1 NOT
392 1
1 NOT
1 NOT
1 NOT
1 NOT
1 NOT
418 1
414 1
1 NOT
1 NOT
422 2
2 NOT
473 2
2 NOT
500 2
2 NOT
26359.
96109.
54125.
95829.
57388.
44375.
385.
1292.
1156.
FOUND
1262.
242.
FOUND
FOUND
FOUND
FOUND
FOUND
FOUND
FOUND
FOUND
210.
FOUND
FOUND
FOUND
FOUND
FOUND
FOUND
546.
FOUND
1048.
FOUND
FOUND
FOUND
FOUND
FOUND
1628.
618.
FOUND
FOUND
1481.
FOUND
4288.
FOUND
621.
FOUND
Units:
RRF(L)
1.
1.
1.
1.
1.
1.
0.
1.
0.
1.
0.
0.
0.
1.
1.
0.
000
000
000
000
000
000
470
234
995
368
236
602
854
175
276
,906
0.445
0.
.741
0.330
UG/ML
Amount
40.
40.
40.
40.
40.
40.
0.
0.
0.
1.
0.
0.
0.
1.
000
000
000
000
000
000
341
774
810
400
759
530
970
354
1.936
1.
1.
2.
0,
.035
.385
.407
.784
-------
46 S2# 40 C440 2,4-OICHLOROPHENOL 162 A BB 520 2 306. 0.308 0.414
47 S2# 45 C430 BENZ01C ACID 122 2 NOT FOUND
48 S2# 50 AA-DIMETHYLPHENETHYLAMIN 58 2 NOT FOUND
49 S2# 55 C445 1,2.4-TRICHLOROBENZ 180 2 NOT FOUND
-------
50 S2# 60 C450 NAPHTHALENE
51 S2# 80 C455 4-CHLOROANALINE
52 S2# 85 2,6-DICHLOROPHENOL
53 S2# 90 HEXACHLOROPROPENE
54 S2# 95 C460 HEXACHLOROBUTADIENE
55 S2#115 P-PHENYLENE DIAMINE
56 S2#120 N-NITROSODI-N-BUmAMINE
57 S2#130 C465 4-CHLORO-3-METHYLPH
58 S2HM40 SAFROLE
59 S2#145 C470 2-HETHYLNAPHTHALENE
60 S3# 10 1,2,4,5-TETRACHLOROBENZE
61 S3# 15 ISOSAFROLE (#1)
62 S3* 20 C510 HEXACHLOROCYCLOPENT
63 S3# 25 C515 2,4,6-TRICHLOROPHEN
64 S3# 30 C520 2,4,5-TRICHLOROPHEN
65 S3# 35 ISOSAFROLE (#2)
66 S3# 40 C525 2-CHLORONAPHTHALENE
67 S3# 42 1-CHLORONAPHTHALEN
68 S3# 45 C530 2-NITROANALINE
69 S3# 50 1,4-NAPHTHOOUlNONE
70 S3# 55 C535 DIMETHYLPHTHALATE
71 S3# 60 1,3-DINITROBENZENE
72 S3# 65 C540 ACENAPHTHYLENE
73 S3# 70 C543 2,6-DINITROTOLUENE
74 S3# 75 C545 3-N1TROAN1L1NE
75 S3# 80 C550 ACENAPHTHENE
76 S3# 85 C555 2,4-DINITROPHENOL
77 S3# 90 C565 DIBENZOFURAN
78 S3# 95 C560 4-NITROPHENOL
79 S30100 PENTACHLOROBENZENE
80 S3#105 C570 2,4-DINITROTOLUENE
81 S3#110 1-NAPHTHYLAHINE
82 S3#115 2-NAPHTHYLAM1NE
83 53*120 2,3,4,6-TETRACHLOROPHENO
84 S3#130 C580 DIETHYLPHTHALATE
85 S3#135 C590 FLUORENE
86 S3#140 C585 4-CHLOROPHENYL-PHEN
87 S3#145 5-NITRO-O-TOLUIDINE
88 S3#150 C595 4-NITROANALINE
89 S4# 10 C610 4.6-DIN1TRO-2-METHY
90 S4# 15 C615 N-NITROSODIPHENYLAM
91 S4# 20 C620 AZOBENZENE
92 S4# 25 SYM-TR1NITROBENZENE
93 S4# 30 C625 4-BROMOPHENYL-PHENY
94 S4# 35 PHENACETIN
95 S4# 37 DIALLATE
96 S4# 40 C630 HEXACHLOROBENZENE
97 S4# 45 4-AM1NOB1PHENYL
98 S4# 50 C635 PENTACHLOROPHENOL
99 S4# 55 PRONAMIDE
100 S4# 60 PENTACHLORONITROBENZENE
101 S4# 65 C640 PHENANTHRENE
102 S4# 70 C645 ANTHRACENE
103 S4# 75 2SECBUTYL-4.6-DINITROPHE
104 S4# 80 C647 CARBAZOLE
105 S4# 85 C650 DI-N-BUTYLPHTHALATE
106 S4#100 4-NITROQUINOLINE-1-OXIDE
107 S4#105 METHAPYRILENE
108 S40106 ISODRIN
109 S4#110 C655 FLUORANTHENE
110 54*120 CHLOROBENZ1LATE
12S
127
162
213
225
108
84
107
162
142
214
162
237
196
196
104
162
162
65
158
163
168
152
165
138
153
184
168
109
250
165
143
143
232
149
166
204
152
138
198
169
77
75
248
108
234
284
169
266
173
237
178
178
211
167
149
190
58
193
202
139
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
BV
BB
BB
BB
BB
BB
BB
BB
BB
BV
BV
BB
BB
BB
BB
VB
BB
BV
BB
BB
BB
BV
533 2
556 2
2 NOT
2 NOT
2 NOT
2 NOT
2 NOT
2 NOT
648 2
652 2
3 NOT
3 NOT
3 NOT
3 NOT
3 NOT
738 3
3 NOT
3 NOT
764 3
3 NOT
3 NOT
807 3
808 3
817 3
3 NOT
835 3
860 3
867 3
3 NOT
3 NOT
881 3
882 3
3 NOT
3 NOT
3 NOT
926 3
3 NOT
942 3
3 NOT
4 NOT
964 4
4 NOT
1025 4
4 NOT
4 NOT
4 NOT
4 NOT
4 NOT
4 NOT
4 NOT
1066 4
1091 4
4 NOT
4 NOT
1149 4
4 NOT
4 NOT
4 NOT
1267 4
4 NOT
4 NOT
17654.
496.
FOUND
FOUND
FOUND
FOUND
FOUND
FOUND
1275.
28264.
FOUND
FOUND
FOUND
FOUND
FOUND
390.
FOUND
FOUND
655.
FOUND
FOUND
258.
622.
391.
FOUND
1132.
308.
1063.
FOUND
FOUND
551.
280.
FOUND
FOUND
FOUND
3536.
FOUND
1876.
FOUND
FOUND
3648.
FOUND
464.
FOUND
FOUND
FOUND
FOUND
FOUND
FOUND
FOUND
106.
11034.
FOUND
FOUND
538.
FOUND
FOUND
FOUND
201.
FOUND
FOUND
1.
0.
0.
0.
0.
0.
0.
1.
0.
1.
0.
1.
0.
0.
1.
0.
0.
0.
022
454
248
751
195
502
197
838
324
159
189
669
397
837
298
356
,551
.162
0.080
1,
0
0
.033
.764
.127
7.
0.
2.
15.
1.
0.
0.
0.
0.
0.
1.
0.
1.
0.
2.
3.
2.
1.
188
455
142
658-
482
965
966
250
892
722
202
471
025
247
014
899
.765
.198
0.551
4.460
0
0
.294
.662
716
-------
111 S5# 10 C710 BENZIDINE 184 5 NOT
112 S5# 15 C715 PYRENE 202 A BB 1335 5
113 S5# 20 ARAMITE (#1) 185 5 NOT
114 S5# 25 ARAMITE (#2) 185 5 NOT
115 S5# 30 P-DIMETHYLAMINOAZOBENZEN 120 5 NOT
116 S5# 35 3,3'-OIMETHYLBENZIDINE 212 5 NOT
117 S5# 37 KEPONE 272 A BB 1461 5
118 S5# 40 C720 BUTYLBENZYLPHTHALAT 149 5 NOT
119 S5# 45 2-ACETYLAMlNOFLUORENE 181 5 NOT
120 S5# 50 C730 BENZO(A)ANTHRACENE 228 5 NOT
121 S5# 55 C725 3,3'-DICHLOROBENZID 252 5 NOT
122 S5# 60 C740 CHRYSENE 228 A BB 1555 5
123 S5# 65 C745 BIS(2-ETHYLHEXYL)PH 149 5 NOT
124 S5# 85 3-METHYLCHOLANTHRENE 268 5 NOT
125 ,S6# 10 C760 DI-N-OCTYL PHTHALAT 149 6 NOT
126 S6# 15 C765 BENZO(B)FLUORANTHEN 252 6 NOT
127 S6# 20 7,12-DIMETHYLBENZANTHRAC 256 6 NOT
128 S6# 25 C770 BENZO
-------
TARGET COMPOUND COMPARISON
COMPOUND: C470 2-METHYLNAPHTHALENE
142 S2#145
RAW DATA: 30068182 #652
08/31x98 19:31
SAMPLE: S-MM5-1B 1/3SA/100M INST. ID: F16
CONDS.: UG/ML *100ML * 100Z/100Z */l/3SA NA M
91-57-6
BASE M/Z: 142
RIC: 114048.
18. 5-
9.3-;
16.3-
8.1-:
100.0-
50.0-;
M/Z
100.0-
50.0-:
0.0-:
-50.0-:
100.0-^
,,,,,,,1,
...... 1 1 ,...,..
ENHANCED
.,,... i ,....,..
STANDARD
08/31/98
40
1
. . , 1 1 ,
50
!' .V.1!
II .,.,
DATA: 30068102
1 ...
||, |
#652
FILE: ST16980831 #651
12:31
.l,ii..
60
i1
1 ,
,.iii,....,..
80
i" '
il i l,i
i j i i i | i i
i -i 'i -i
r '''
. . ( i ..... i
100
(|
i
. , i
BASE M/Z:
BASE M/Z:
i i 'i
I , ,
i i i I i ... | i . i ... i i . | i ..,,,.,.
142 RIC: 29408.
<ฃ_ <\ [idi0^
142 RIC: 198144.
i.
1 ' 1 1 ' ' ' 1 ' ' 1 1
120 140 150 160 180
i i ......
9216.
r 8112.
<- 49792.
O)
-------
SNA, S LIBRARIES ANALYST: DATE:
OUAHTERRA Internal Standard Check
Standard Filename: ST16980831 Analyzed: 08/31/98 12:31
| IS# 1 | IS# 2 | IS# 3 |
Standard j Area % | RT j Area X | RT j Area X | RT |
ST16980831 | 28649. | 3.78 | 100432. | 5.90 | 54347. | 9.21 |
Upper Limit j 57297.=+200| 4.28 j 200864.=+200j 6.40 j 108695.=+200| 9.71 |
Lower Limit j 14324.=+ 50| 3.28 j 50216.=+ 50| 5.40 | 27174.=+ 50| 8.71 |
Filename | | | | | | |
= ======= = ===================3:=========:===s==============s=====s===s===========
I II II II
1 30068102 | 26359.= 92| 3.78 | 96109.= 95| 5.90 | 54125.= 99| 9.22 j
IS# 1 = CI30 1,4-DICHLOROBENZENE-D4
IS# 2 = CI40 NAPHTHALENE-OS
IS# 3 = CI50 ACENAPHTHENE-010
* - indicates an I.S. is outside QC limit(s)
I IS# 4 | IS# 5 | IS# 6 |
Standard j Area X | RT | Area X | RT j Area % | RT j
ST16980831 | 98520. |12.08 | 62289. |17.26 | 50750. |19.83 |
Upper Limit j 197059.=+200|12.58 j 124578.=+200|17.76 j 101500.=+200|20.33 |
Lower Limit | 49260.=+ 50J11.58 j 31145.=+ 50J16.76 | 25375.=+ 50|19.33 |
Filename I II II II
1 30068102 | 95829.= 97|12.10 | 57388.= 92J17.26 | 44375.= 87|19.82
1S# 4 = CI60 PHENANTHRENE-D10
IS# 5 = CI70 CHRYSENE-D12
IS# 6 = CITS PERYLENE-D12
* - indicates an I.S. is outside QC limit(s)
-------
Data Reduced by: >- Date:
Data Reviewed by: UW^Date:
Data File: 30068102
OUANTERRA GC/MS TIC REPORT ( Part 1 )
Sample: S-MH5-1B 1/3SA/100H INST. ID: F16
Analyst: DAT Date Analyzed: 08/31/98 19:31
Run Factor: 300.
Concentration
in Sample
# SCAN (UG/A) CAS #
1 444
7800.
A-TBIIIETHYI
-62W8-
73 7100.
K1ULLLH I OL, ILJ'
3 556 7800.
DOOECANE OV \,
112-40-3
0 6700.
DECANE, 2,6-DIMETHrL-
17301-23-4
5 617 15000.
UNKNOWN
00-00-0
6 633 17000. 5_QBZUIiJ>
UO6C6HE, 3/i-DlMETHYU-^
7 654 10000.
3-HEXADECENE, (2)-
34303-81-6
X 67a 71,00.
UNKNOWN
00-00-0
10 738 20000. -.5U05-t7.
fKYT-^
Ml*
663 11000.
UNDECANE y
1120-21-4
r-, C
-------
11 764
SECANC. fr-
26000. ซ-- - 63100 21 fr-
12 777 14000.
UNKNOWN
00-00-0
13 820 22000. 18344-37-1 ^
HEPTAOECANE, 2,6,10, 14-TETRAMETHYL- flTV \
X
858 22000. 17312-57-1
DODECANE, 3-METHYL-
904 9900. f| 527S3-43'4 .,
948 26000. 629-92-5
NONADECANE &L.
988 18000. 629-92-5
NONADECANE
! 1036 40000. 54105-67-8
HEPTADECANE, 2,6-DIMETHYL-
^1054 7000. 7206-19-1
3-OCTADECENE, (E>-
Ju=~* ^4UMOC
j*^
20 1114 12000. c 29812^79-
21 1119 17000.
NONADECANE
629-92-5
22 1191 8100.
NONADECANE
629-92-5
-------
1265 6900. . 54105-67-8
EH-AUELANb, 2,6-UfflETHTE-
24 1335 9800.
* '\\S\\1S i
U02 7800. 629-92-5
NONADECANE
I
-------
DATA FILE: 50068102
QUANTERRA GC/MS TIC REPORT ( Part 2 )
CONCENTRATION = AREA(TIC)*CONC(IS)/AREA(IS)
#
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
FIT
941
874
943
972
901
948
930
960
944
950
953
911
972
964
938
958
943
970
906
957
964
971
924
933
965
PURITY
658
669
842
853
595
721
700
846
401
826
716
347
826
773
661
847
830
865
703
799
842
792
763
740
690
INT.
STD.
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
3
3
3
3
3
3
3
4
4
AMOUNT
AS ANALYZED
RT
4:56
5:15
6:11
6:20
6:51
7:02
7:16
7:22
7:32
8:12
8:29
8:38
9:07
9:32
10:03
10:32
10:59
11:31
11:43
12:23
12:26
13:14
14:04
14:50
15:35
RRT
0.536
0.571
0.671
0.688
0.744
0.764
0.789
0.800
0.818
0.890
0.922
0.937
0.989
1.035
1.090
1.144
0.908
0.952
0.969
1.024
1.028
1.095
1.163
0.860
0.903
AREA
197944.
180512.
196010.
168832.
367872.
429472.
262912.
268288.
186752.
495104.
666007.
363392.
552366.
565839.
250112.
648704 .
500650.
1137280.
200704.
336000.
471552.
231936.
195456.
167008.
132416.
HEIGHT
59360.
46417.
69931.
54235.
39360.
115616.
45696.
94208.
43392.
127744.
189300.
50048.
122822.
173725.
56832.
177408.
128483.
201472.
46336.
104960.
141056.
77312.
57749.
42891 .
30848.
(UG/ML )
26.
23.
25.
22.
48.
56.
34.
35.
24.
65.
87.
47.
72.
74.
32.
85.
58.
133.
23.
39.
115
815
860
274
534
661
687
396
639
320
868
943
875
652
998
585
597
109
491
326
55.191
27.146
22.876
32.701
25.927
LIB
NB
NB
NB
NB
UK
NB
NB
NB
UK
NB
NB
UK
NB
NB
NB
NB
NB
NB
NB
NB
NB
NB
NB
NB
NB
LIB #
19015.
22482.
15343.
19054.
1.
14799.
28768.
11607.
1.
37462.
19006.
1.
42196.
19007.
40233.
37465 .
37465.
37462.
34410.
15969.
37465.
37465 .
37462.
37456.
374 i5.
-------
Library Search Data: 30068102 # 444 Base m/z: 43
08/31/98 19:31:00 + 4:56 Cali: 30068102 # 3 RIC: 49216.
Sample: S-MM5-1B 1/3SA/100M INST. ID: F16
Conds.: UG/ML *100Ml *100X/100X *(NA/NA )/1/3SA NA M
Enhanced (S 158 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
897 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 19015 DECANE, 2,5,6-TRIMETHYL-
2 11607 UNDECANE
3 15969 HYDROXYLAMINE, 0-DECYL-
4 19523 1-DECANOL, 2-ETHYL-
5 11602 OCTANE, 2,4,6-TRIMETHYL-
6 14793 1-UNDECENE, 4-METHYL-
7 8104 OCTANE, 3,5-OIMETHYL-
8 5151 HEPTANE, 3,4-DIMETHrL-
9 12074 1-HEPTANOL, 2-PROPYL-
Rank
1
2
3
4
5
6
7
8
9
Rank
1
2
3
4
5
6
7
8
9
Formula
C13.H28
C11.H24
C10.H23.0.N
C12.H26.0
C11.H24
C12.H24
C10.H22
C9.H20
C10.H22.0
Ret. Time B.P.Int.
M.Wt
184
156
173
186
156
168
142
128
158
US. Par. 1
B.Pk
57
43
43
57
57
43
57
43
43
US. Par
Pur i ty Fit
658 941
656 979
653 948
641 915
638 949
638 915
637 932
632 920
629 922
.2 C.A.S. #
62108-23-0
1120-21-4
29812-79-1
21078-65-9
62016-37-9
74630-39-0
15869-93-9
922-28-1
10042-59-8
RFit
660
664
675
670
638
672
649
634
648
754
-------
1120
SAMPLE
C13.H28
1120
M WT 184
B PK 57
RANK 1
ft 19015
PUR 658
C11.H24
1120
M WT 156
B PK 43
RANK 2
# 11607
PUR 656
MID LIBRARY SEARCH (LIBRARYNB)
08/31x98 19:31:00 + 4:56
SAMPLE: S-MM5-1B 1/3SA/100M
CONDS.: UG/ML *100ML
ENHANCED
-------
Library Search Data: 30068102 # 473 Base m/z: 43
08/31/98 19:31:00 + 5:16 Cali: 30068102 * 3 RIC: 41024.
Saddle: S-MM5-1B 1/3SA/100M 1NST. ID: F16
Conds.: UG/ML *100ML *100X/100X *(NA/NA )/1/3SA NA M
Enhanced
-------
MID LIBRARY SEARCH
08/31/98 19:31:00 + 5:16
SAMPLE: S-MM5-1B 1/3SA/100M INST. ID: F16
CONDS.: UG/ML *100ML *100Z/100Z *
DATA: 30068102 # 473
CALI: 30068102 # 3
BASE M/Z: 43
RIC: 41024.
1350
SAMPLE
r
C13.H26.0
1350 I
M WT 198
B PK 57
RANK 1
tt 22482
PUR 669
C14.H28.0
1350 -i
M WT 212
B PK 41
RANK 2
# 25971
PUR 660
C18.H36.0
1350 I
M WT 268
B PK 57
RANK 3
* 37444 '
PUR 656
M/Z
~^"
\U^^
ll III ll ฐ
ii|l illl illlj ..In 1. 1. . ..i. . I.. ,.!.. I-.
2-TRIDECEN-l-OL, -
r
r
r
1 ll|l ill II ,, .. ,
OXIRANE, DODECYL-
1 ll| III |ll V
OXIRANE, HEXADECYL-
'
1
|l nil illi ill ,,.
50 100 150 200 250
en
-------
Library Search Data: 30068102 # 556
08/31/98 19:31:00 + 6:11 Cali: 30068102 # 3
Sample: S-MM5-1B 1/3SA/100M INST. ID: F16
Conds.: UG/ML ป100ML *100%/100% *(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
Base m/z: 43
RIC: 62784.
62231 spectra in L1BRARYNB searched for maximum PURITY
990 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 15343 DOOECANE
2 11607 UNDECANE
3 19006 DECANE, 6-ETHYL-2-METHYL-
4 11602 OCTANE, 2.4,6-TRIMETHYL-
5 19016 UNDECANE, 4,7-DIMETHYL-
6 19015 DECANE, 2.5,6-TRIMETHYL-
7 19028 DECANE, 2,4,6-TRlMETHYL-
8 22530 TETRADECANE
9 15359 UNDECANE, 5-METHYL-
Rank Formula
1 C12.H26
2 C11.H24
3 C13.H28
4 C11.H24
5 C13.H28
6 C13.H28
7 C13.H28
8 C14.H30
9 C12.H26
Rank Ret. Time B.P.Int. US. Par
1
2
3
A
5
6
7
8
9
M.Ut B.Pk
170 57
156 43
184 57
156 57
184 43
184 57
184 43
198 43
170 43
.1 US. Par
Purity Fit
842 943
835 955
830 945
825 957
819 933
817 917
812 916
810 904
808 929
.2 C.A.S. #
112-40-3
1120-21-4
62108-21-8
62016-37-9
17301-32-5
62108-23-0
62108-27-4
629-59-4
1632-70-8
RFit
868
856
842
836
845
833
852
883
829
-------
MID LIBRARY SEARCH (LIBRARYNB)
08/31/98 19:31:00 + 6:11
SAMPLE: S-MM5-1B 1/3SA/100M INST. ID: F16
CONDS.: UG/ML *100ML *100Z/100Z *
DATA: 30068102 # 556
CALI: 30068102 # 3
BASE M/Z: 43
RIC: 62784.
1067
SAMPLE
C12.H26
C11.H24
1067
M WT 156
B PK 43
RANK 2
* 11607
PUR 835
DODECANE o v
IBbi'
M WT 170
B PK 57
RANK 1
# 15343
PUR 842
r
1
|
l|
1
, 1- r-, , U, ..... I
UNDECANE
C13.H28
1067 i
M WT 184
B PK 57
RANK 3
* 19006
PUR 830
DECANE, 6-ETHYL-2-METHYL-
II
i U
M/Z
40
60
80
100
120
140
160
cn
CD
-------
Library Search Data: 30068102 # 570
08/31/98 19:31:00 + 6:20 Cali: 30068102 # 3
Sample: S-MM5-1B 1/3SA/100H INST. ID: F16
Conds.: UG/ML *100HL *100X/100X *(NA/NA )/1/3SA NA H
Enhanced (S 15B 2N OT)
Base m/z: 57
RIC: 47680.
62231 spectra in LIBRARYNB searched for maximum PURITY
876 matched at least 7 of the 16 Largest peaks in the unknown
Rank In. Name
1 19054 UNDECANE, 2,6-DIMETHYL-
2 19013 DECANE, 2,5,9-TRIMETHYL-
3 19052 UNDECANE, 2,5-DIMETHYL-
4 19002 DOOECANE, 6-METHYL-
5 19026 DECANE, 2,6,8-TRIMETHYL-
6 8104 OCTANE, 3,5-DIMETHYL-
7 18996 UNDECANE, 3,6-DIMETHYL-
8 19015 DECANE, 2,5,6-TRIMETHYl-
9 8071 NONANE, 3-METHYL-
Rank
1
2
3
4
5
6
7
8
9
Rank
1
2
3
4
5
6
7
8
9
Formula
C13.H28
C13.H28
C13.H28
C13.H28
C13.H28
C10.H22
C13.H28
C13.H28
C10.H22
Ret.Time
B.P.Int.
US.Par.1
M.Wt
184
184
184
184
184
142
184
184
142
B.Pk Purity Fit
57
57
57
57
57
57
57
57
57
I US. Par. 2
853 972
837 977
837 972
834 971
833 969
820 959
815 968
796 935
793 979
C.A.S. #
17301-23-4
62108-22-9
17301-22-3
6044-71-9
62108-26-3
15869-93-9
17301-28-9
62108-23-0
5911-04-6
RFit
859
837
842
839
838
820
817
798
793
76C
-------
MID LIBRARY SEARCH
08/31/98 19:31:80 + 6:20
SAMPLE: S-MM5-1B 1/3SA/190M INST. ID: F16
CONDS.: UG/ML *100ML *1007./1007. *
-------
Library Search Data: 30068102 # 617
08/31/9819:31:00+ 6:52 Cali : 30068102 # 3
Sample: S-MM5-1B 1/3SA/100M INST. ID: F16
Conds.: UG/ML *100ML *100%/100% '(NA/NA )/1/3SA NA M
Enhanced (S 158 2N OT)
Base m/z: 41
RIC: 34752.
62231 spectra in LIBRARYNB searched for maximum PURITY
207 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 24994 1,1'-BICYCLOHEXYL, 2-(1-METHYLETHYL)-, TRANS-
2 33979 BORINIC ACID, DIETHYL-, 1-CYCLOOODECEN-1-YL ESTER
3 24993 1,1'-BICYCLOHEXYL, 2-C1-METHYLETHYL)-, CIS-
4 40193 CIS-9.10-EPOXYOCTADECAN-1-OL
5 39227 NAPHTHALENE, DECAHYDRO-2,6-OIMETHYL-3-OCTYL-
6 31486 ACETAM1DE, N-METHYL-N- [4- [4-METHOXY- 1-HEXAHYDROPYRIDYL] -2-BUTYNYL] -
7 24990 HUUROLANE-B
8 39519 CYCLOHEXANE, 1-(1 ,5-DIMETHYLHEXYL)-4-(4-METHYlPENTYL)-
9 24987 AMORPHANE-A
Rank Formula
1
2
3
4
5
6
7
8
9
C15.H28
C16.H31.0.B
C15.H28
C18.H36.02
C20.H38
C13.H22.02.N2
C15.H28
C20.H40
C15.H28
M.Ut B.Pk Purity Fit RFit
208
250
208
284
278
238
208
280
208
83
83
83
55
109
43
109
43
109
595
584
580
530
521
519
516
515
512
901
913
877
912
806
736
817
737
811
619
612
621
555
586
597
566
619
539
Rank
1
2
3
t,
5
6
7
8
9
Ret.Time
B.P.Int.
US.Par.1
US.Par.2
C.A.S. #
50991-16-7
61142-73-2
50991-15-6
13980-12-6
54964-85-1
56009-20-2
-------
C15.H28
1229
M WT 208
B PK 83
RANK 1
# 24994
PUR 595
MID LIBRARY SEARCH CLIBRARYNB)
88/31/98 19:31:08 + 6:52
SAMPLE: S-MM5-1B 1/3SA/100M INST. ID: F16
CONDS.: UG/ML *100ML *100Z/100Z */l/3SA NA M
ENHANCED
DATA: 30068102 # 617
CALI: 30068102 # 3
BASE M/Z: 41
RIC: 34752.
1229
SAMPLE
ll
II , 1
1
ll ,
1
1 i
1
i l| . i li| , .. .1
u*v-
1 , 1 ' -B I CYCLOHEXYL , 2- < 1 -METHYLETHYL ) - , TRANS-
BORINIC ACID, DIETHYL-, 1-CYCLODODECEN-1-YL ESTER
C16.H31.0.B
1229
M WT 250
B PK 83
RANK 2
# 33979
PUR 584
C15.H28
1229 i
M WT 208
B PK 83
RANK 3
# 24993
PUR 580
1,1' -E
||
3 I CYCLOHEXYL, 2-
-------
Library Search Data: 30068102 # 633 Base m/z: 57
08/31/98 19:31:00 + 7:02 Call: 30068102 # 3 R1C: 94336.
Sample: S-MM5-1B 1/3SA/100M 1NST. ID: F16
Conds.: UG/ML *100ML *100%/100ซ *(NA/NA >/1/3SA NA M
Enhanced (S 15B 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
735 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 14799 1-DECENE, 3,4-DIMETHYL-
2 19523 1-DECANOL, 2-ETHYL-
3 26408 2-ETHYL-1-DOOECANOL
4 37462 HEPTADECANE, 2,6-DIHETHYL-
5 26409 2-HEXYL-1-OCTANOL
6 32418 2-HEXYL-1-DECANOL
7 22534 TRIDECANE, 7-METHYL-
8 14751 2-UNDECENE, 5-METHYL-
9 8539 1-PENTANOL, 4-METHYL-2-PROPYL-
Rank
1
2
3
L.
5
6
7
8
9
Formula
C12.H24
C12.H26.0
C14.H30.0
C19.H40
C14.H30.0
C16.H34.0
C14.H30
C12.H24
C9.H20.0
M.Wt
168
186
214
268
214
242
198
168
144
B.Pk
57
57
57
57
57
57
57
57
57
Purity
721
721
714
713
712
706
704
700
699
Fit
948
936
919
920
921
915
910
960
982
RFit
721
731
719
743
726
719
714
700
699
Rank
1
2
3
4
5
6
7
8
9
Ret.Time
B.P.Int.
US.Par.1
US.Par.2
C.A.S. #
50871-03-9
21078-65-9
54105-67-8
26730-14-3
56851-34-4
54004-41-0
7G4
-------
1018
SAMPLE
MID LIBRARY SEARCH (LIBRARYNB)
08/31/98 19:31:00 + 7:02
SAMPLE: S-MM5-1B 1/3SA/100M INST. ID:
CONDS.: UG/ML *100ML * 100Z/100Z *
DATA:
CALI:
F16
NA M
30068102 # 633
30068102 # 3
BASE M/2: 57
RIC: 94336.
in
C12.H24
1018
(1 WT 168
B PK 57
RANK 1
# 14799
PUR 721
1-DECENE, 3,4-DIMETHYL-
II
C12.H26.0
1018 i
M WT 186
B PK 57
RANK 2
ซ 19523
PUR 721
1-DECANOL, 2-ETHYL-
_h
C14.H30.0
1018
M WT 214
B PK 57
RANK 3
# 26408
PUR 714
M/Z
2-ETHYL-1-DODECANOL
50
100
150
200
250
o
CM
-------
Library Search Data: 30068102 # 654 Base m/z: 41
08/31/98 19:31:00 + 7:16 Cali: 3006810Z # 3 RIC: 44224.
Sample: S-HM5-1B 1/3SA/100M INST. ID: F16
Conds.: UG/ML *100ML *100X/100X ซ(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
687 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 28768 3-HEXADECENE,
2 28772 7-HEXADECENE,
3 21962 3-TETRAOECENE
4 21963 3-TETRADECENE
5 34410 3-OCTADECENE,
6 32420 1-HEXADECANOL
7 34411 5-OCTADECENE,
8 21973 7-TETRADECENE
9 19526 1-DODECANOL
Rank Formula
1 C16.H32
2 C16.H32
3 C14.H28
4 C14.H28
5 C18.H36
6 C16.H34.0
7 C18.H36
8 C14.H28
9 C12.H26.0
(Z)-
(Z)-
, (Z)
.
-------
MID LIBRARY SEARCH (LIBRARYNB)
08/31/98 19:31:00 + 7:16
SAMPLE: S-MM5-1B 1/3SA/100M
CONDS.: UG/ML *100ML
ENHANCED (S 15B 2N 0T>
DATA:
CALI:
INST. ID: F16
*- p v <^-^-o/ ' ' .......
III! I I |i . .. . ,
7-HEXADECENE, -
1, 1 1
|l 1, 1, 1 ,
3-TETRADECENE,
-------
Library Search Data: 30068102 # 663 Base m/z: 57
08/31/98 19:31:00 + 7:22 Cali: 30068102 # 3 RIC: 86528.
Sample: S-MM5-1B 1/3SA/100M INST. ID: F16
Conds.: UG/ML *100ML *100X/100X *(NA/NA )/1/3SA NA M
Enhanced (S 158 2N OT)
62231 spectra in LIBRARYN8 searched for maximum PURITY
787 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 11607 UNDECANE
2 19013 DECANE, 2
3 8104 OCTANE, 3
4 5159 NONANE
5 11602 OCTANE, 2
6 8073 DECANE
7 15356 DECANE, 2
8 19016 UNDECANE,
9 19026 DECANE, 2
Rank Formula
1 C11.H24
2 C13.H28
3 C10.H22
4 C9.H20
5 C11.H24
6 C10.H22
7 C12.H26
8 C13.H28
9 C13.H28
Rank Ret. Time
1
2
3
4
5
6
7
8
9
,5,9-TRIMETHYL
,5-DIMETHYL-
,4,6-TRIMETHYL
,4-DIMETHYL-
4,7-DIMETHYL-
,6,8-TRIMETHYL
8. P. Int.
US.Par.1
M.Ut
156
184
142
128
156
142
170
184
184
I
B.Pk Purity Fit RFit
43
57
57
43
57
43
43
43
57
US. Par. 2
846 960
806 921
804 913
803 929
799 938
797 922
794 930
793 904
792 907
C.A.S. #
1120-21-4
62108-22-9
15869-93-9
111-84-2
62016-37-9
124-18-5
2801-84-5
17301-32-5
62108-26-3
858
820
832
842
831
850
823
846
826
-------
MID LIBRARY SEARCH
08/31/98 19:31:00 + 7:22
SAMPLE: S-MM5-1B 1/3SA/100M INST. ID: F16
CONDS.: UG/ML *100ML *1007>/100Z *(NA/NA V1/3SA NA M
ENHANCED
DATA: 30068102 * 663
CALI: 30068102 # 3
BASE M/Z: 57
RIC: 86528.
1462 i
SAMPLE
C11.H24
1462 i
M WT 156
B PK 43
RANK 1
# 11607
PUR 846
C13.H28
1462 i
M WT 184
B PK 57
RANK 2
tt 19013
PUR 806
C10.H22
1462 i
M WT 142
B PK 57
RANK 3
tt 8104
PUR 804
M/Z
|
r
I,
r
i
r
1
i I1
r
1
i.
, h
. i . .. i . .... .... ....
UNDECANE ฃ> f i*>ov~<-V
J.
II
i ......
DECANE , 2 , 5 , 9-TR I METHYL-
il
OCTANE, 3,5-DIMETHYL-
|
h
I
ill .1 n .1
40 68 80 100 120 140 160 180 200
cn
cr>
-------
Library Search Data: 30068102 # 678
08/31/98 19:31:00 + 7:32 Cali: 30068102 # 3
Sample: S-MM5-1B 1/3SA/100M INST. ID: F16
Conds.: UG/ML *100ML *100%/100X *(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
Base m/z: 57
RIC: 45056.
62231 spectra in LIBRARYNB searched for maximum PURITY
672 matched at least 6 of the 16 largest peaks in the unknown
Rank In. Name
1 5159 NONANE
2 12534 NAPHTHALENE, 1,2,3,4-TETRAHYDRO-2,6-OIMETHYL-
3 37251 1-IOOO-2-METHYLNONANE
4 11597 NONANE, 3,7-DIMETHYL-
5 11602 OCTANE, 2,4,6-TRIMETHYL-
6 8089 NONANE, 2-METHYL-
7 15343 DOOECANE
8 11607 UNDECANE
9 5041 3-HEXANONE, 2,4-OIMETHYL-
Rank
1
2
3
4
5
6
7
8
9
Formula
C9.H20
C12.H16
C10.H21.I
C11.H24
C11.H24
C10.H22
C12.H26
C11.H24
C8.H16.0
M.Wt
128
160
268
156
156
142
170
156
128
B.Pk
43
118
43
57
57
43
57
43
57
Purity
401
398
388
381
377
376
373
373
372
Fit
944
832
918
903
912
894
884
906
916
RFit
401
413
404
390
386
388
409
394
375
Rank
1
2
3
4
5
6
7
8
9
Ret.Time
8.P.Int.
US.Par. 1 US.Par.2
C.A.S. #
111-84-2
7524-63-2
17302-32-8
62016-37-9
871-83-0
112-40-3
1120-21-4
18641-70-8
-------
1299
SAMPLE
C9.H20
1299
M WT 128
B PK 43
RANK 1
* 5159
PUR 401
MID LIBRARY SEARCH CLIBRARYNB)
08/31/98 19:31:80 + 7:32
SAMPLE: S-MM5-1B 1/3SA/100M INST. ID: F16
CONDS.: UG/ML *100ML *100Z/1007. */l/3SA NA M
ENHANCED
DATA: 30068102 # 678
CALI: 30068102 # 3
BASE M/Z: 57
RIC: 45056.
r
1
,,li
i>
,. i 1 i .1. ii i i Hi . n. .. .. ..). . i ...........
NONANE
,
C12.H16
1299 i
M WT 160
B PK 118
RANK 2
# 12534
PUR 398
C10.H21.I
1299 -i
M WT 268
B PK 43
RANK 3
# 37251
PUR 388
M/Z
NAPHTHALENE , 1,2,3, 4-TETRAHYDRO-2 , 6-D I METHYL-
r
.., . | | 1 1 Ii ป . < i
1 - I ODO-2-METHYLNONANE
r
i 1 |l I, . . i, . . ,
50 100 150 200 250
vl
h-"
-------
Library Search Data: 30068102 # 738 Base m/z: 57
08/31/9819:31:00+ 8:13 Call: 30068102 * 3 RIC: 119808.
Sample: S-MM5-1B 1/3SA/100M INST. ID: F16
Conds.: UG/ML *100ML *100%/100X *(NA/NA )/1/3SA NA M
Enhanced
-------
MID LIBRARY SEARCH CLIBRARYNB)
08/31/98 19:31:00 + 8:13
SAMPLE: S-MM5-1B 1/3SA/100M IMST. ID: FIG
CONDS.: UG/ML *100ML *100Z/100Z *
-------
Library Search Data: 30068102 # 764 Base m/z: 43
08/31/98 19:31:00 + 8:30 Cali: 30068102 # 3 RIC: 162304.
Sample: S-HMS-1B 1/3SA/100H INST. 10: F16
Conds.: UG/ML *100ML ซ100%/100X *(NA/NA )/1/3SA NA H
Enhanced (S 156 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
672 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 19006 DECANE, 6-ETHYL-2-METHYL-
2 22530 TETRADECANE
3 19007 DOOECANE, 3-METHYL-
4 18990 UNDECANE, 2,9-DIMETHYL-
5 11612 NONANE, 2,5-DIMETHYL-
6 39681 1-IOOOUNOECANE
7 37252 DECANE, 1-IODO-
8 11607 UNDECANE
9 22532 TRIOECANE, 2-METHYL-
Rank
1
2
3
4
5
6
7
8
9
Rank
1
2
3
4
5
6
7
8
9
Formula
C13.H28
C14.H30
C13.H28
C13.H28
C11.H24
C11.H23.I
C10.H21.I
C11.H24
C14.H30
Ret. Time B.P.Int.
M.Ut
184
198
184
184
156
282
268
156
198
B.Pk
57
43
57
57
57
57
57
43
57
US. Par. 1 US. Par
Purity Fit
716 953
702 936
689 893
683 362
683 848
681 853
678 876
677 956
670 859
.2 C.A.S. #
62108-21-8
629-59-4
17312-57-1
17301-26-7
17302-27-1
4282-44-4
2050-77-3
1120-21-4
1560-96-9
RFit
716
712
689
683
688
687
684
683
695
774
-------
MID LIBRARY SEARCH (LIBRARYNB) DATA:
08/31/98 19:31:00 + 8:30 CALI:
SAMPLE: S-MM5-1B 1/3SA/100M INST. ID: F16
CONDS.: UG/ML *100ML *100Z/100Z *
30068102 # 764
30068102 # 3
BASE M/Z: 43
RIC: 162304.
1293 I
SAMPLE
C13.H28
1293 i
M WT 184
B PK 57
RANK 1
* 19006 '
PUR 716
C14.H30
1293 i
M WT 198
B PK 43
RANK 2
# 22530
PUR 702
C13.H28
1293 n
M WT 184
B PK 57
RANK 3
* 19007
PUR 689
M/Z
r
1
r
II
.l|
^
DECANE, 6-ETHYL-2-METHYL-
ii
ii .. .1 ..
TETRADECANE
r
1
LI . !,"ซ-. , M
r
DODECANE, 3-METHYL-
i . .. .1. .. -
50 .100 150 200 250
CM
-------
Library Search Data: 30068102 # 777 Base ffl/z: 41
08/31/98 19:31:00 + 8:39 Cali: 30068102 * 3 RIC: 34368.
Sample: S-MM5-1B 1/3SA/100M 1NST. ID: F16
Conds.: UG/ML ซ100ML ซ100%/100X *(NA/NA J/1/3SA NA M
Enhanced (S 158 2N OT)
62231 spectra in L1BRARYNB searched for maximum PURITY
154 matched at least 6 of the 16 largest peaks in the unknown
Rank In. Name
1 32052 OXIRANE, TETRADECYL-
2 29187 BUTAN01C ACID, 3.7-DIMETHYL-6-OCTENYL ESTER
3 29986 7-HYDROXY-3-(1,1-DIMETHYLPROP-2-ENYL)COUMARIN
4 11518 CYCLOHEXANOL, 5-METHYL-2-(1-METHYLETHYL)-, [1S-(1.ALPHA.,2.BETA.,5.
5 35931 HEXAOECANE, 1-CHLORO-
6 50016 CETYLPYRIDINIUM CHLORIDE
7 46252 UNDECANE, 1,2-DIBROMO-2-METHYL-
8 32792 FALCARINOL (Z)-(-)-1,9-HEPTADECADIENE-4,6-DIYNE-3-OL
9 40866 OCTADECANE, 1-CHLORO-
M.Ut B.Pk Purity Fit RFit
Rank
1
2
3
4
5
6
7
8
9
Rank
1
2
3
4
5
6
7
8
9
Formula
C16.H32.0
C14.H26.02
C14.H14.03
C10.H20.0
C16.H33.CL
C21.H40.0.N.CL
C12.H24.BR2
C17.H24.0
C18.H37.CL
Ret. Time I
240
226
230
156
260
357
326
244
288
41
41
43
71
57
55
41
55
57
347
326
323
313
311
305
294
288
288
911
870
696
833
813
824
808
706
749
359
343
420
333
344
334
349
388
338
B.P.Int.
US.Par. 1 US.Par.2
C.A.S. #
7320-37-8
141-16-2
56881-08-4
23283-97-8
4860-03-1
6004-24-6
55334-43-5
3386-33-2
7r* ฃ
{t
-------
1425
SAMPLE
C16.H32.0
1425
M WT 240 :
B PK 41 .
RANK 1
# 32052 I
PUR 347
MID LIBRARY SEARCH (LIBRARYNB)
08/31/98 19:31:80 + 8:39
SAMPLE: S-MM5-1B 1/3SA/100M INST. ID: F16
CONDS.: UG/ML *180ML * 10072/100?: *
DATA: 30068102 # 777 BASE M/Z: 41
CALI: 30068102 # 3 RIC: 34368.
IU
i ,1:
..ijli. .1.1, lil.i IH.I, LL, ,11, .. ,iil i
OXIRANE, TETRADECYL-
_L
^T
BUTANOIC ACID, 3,7-DIMETHYL-6-OCTENYL ESTER
C14.H26.02
1425 i
M WT 226
B PK 41
RANK 2
# 29187
PUR 326
1
_L
C14.H14.03
1425
M WT 230
B PK 43
RANK 3
# 29986
PUR 323
M/Z
7-HYDROXY-3-< 1 , 1-0 I METHYLPROP-2-ENYL) COUMAR IN
50
100
150
200
250
300
-------
Library Search Data: 30068102 # 820 Base m/z: 57
08/31/98 19:31:00 + 9:07 Call: 30068102 * 3 RIC: 117760.
Sample: S-MM5-1B 1/3SA/100M IHST. ID: F16
Conds.: UG/ML *100ML *100%/100% *(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
855 matched at least 7 of the 16 largest peaks in the unknown
Rank In
1 42196
2 37462
3 37465
4 25997
5 18987
6 19016
7 25991
8 26001
9 15353
Name
HEPTADECANE,
HEPTADECANE,
NONAOECANE
PENTADECANE
UNOECANE, 2,
UNDECANE, 4,
2,6,10,14-TETRAMETHYL-
2,6-DIMETHYL-
8-DIMETHYL-
7-DIMETHYL-
DODECANE, 2,6,10-TRIMETHYL-
DOOECANE, 2,7,10-TRIMETHYL-
2,6-DIMETHYLDECANE
Rank
1
2
3
4,
5
6
7
8
9
Formula
C21.H44
C19.H40
C19.H40
C15.H32
C13.H28
C13.H28
C15.H32
C15.H32
C12.H26
M.Wt B.Pk Purity Fit RFit
296
268
268
212
184
184
212
212
170
57
57
57
57
43
43
57
57
43
826
825
800
777
776
775
774
773
773
972
959
943
943
964
951
958
956
924
841
838
832
800
779
781
783
785
788
Rank
1
2
3
4
5
6
7
8
9
Ret.Time
B.P.Int.
US.Par.1
US.Par.2
C.A.S. #
18344-37-1
54105-67-8
629-92-5
629-62-9
17301-25-6
17301-32-5
3891-98-3
74645-98-0
13150-81-7
I t
-------
MID LIBRARY SEARCH
08/31/98 19:31:00 + 9:07
SAMPLE: S-MM5-1B 1/3SA/100M INST. ID: F16
CONDS.: UG/ML *100ML *100Z/1007J *
DATA: 30068102 # 820
CALI: 30068102 # 3
BASE M/Z: 57
RIC: 117760.
1199
SAMPLE
C21.H44
1199
M WT 296
B PK 57
RANK 1
# 42196
PUR 826
C19.H40
1199 i
M WT 268
B PK 57
RANK 2
# 37462
PUR 825
C19.H40
1199 i
M WT 268
B PK 57
RANK 3
# 37465
PUR 800
M/Z
L
, .1
I
1
L
I
"I -i-i- - ' --
HEPTADECANE, 2,6, 10, 14-TETRAMETHYL- ^ ,-ve^~ ^
HEPTADECANE, 2,6-DIMETHYL-
ll
n ii .il
NONADECANE
ll
II
II MI ..i .1 ........
50 100 150 200 250
tP
-------
Library Search Data: 30068102 * 858 Base m/z: 57
08/31/98 19:31:00 + 9:33 Call: 30068102 # 3 RIC: 162816.
Sample: S-MM5-1B 1/3SA/100M INST. ID: F16
Conds.: UG/ML *100ML *100X/100X *(NA/NA )/1/3SA NA M
Enhanced (S 158 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
835 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 19007 DCOECANE, 3-METHYL-
2 15352 UNDECANE, 2-METHYl-
3 15353 2,6-DlMETHYLDECANE
4 22535 DOOECANE, 4,6-DIMETHYL-
5 18998 UNDECANE, 3.7-DIMETHYL-
6 22530 TETRADECANE
7 18990 UNDECANE, 2,9-OIMETHrL-
8 39681 1-IODOUNDECANE
9 19006 DECANE, 6-ETHYL-2-METHYL-
Rank
1
2
3
4
5
6
7
8
9
Formula
C13.H28
C12.H26
C12.H26
C14.H30
C13.H28
C14.H30
C13.H28
C11.H23.I
C13.H28
M.Wt B.Pk Purity Fit RFit
184
170
170
198
184
198
184
282
184
57
43
43
57
43
43
57
57
57
773
771
753
753
752
751
750
-749
746
964
935
908
946
938
928
958
965
949
774
771
757
755
752
762
751
756
747
Rank
1
2
3
4
5
6
7
8
9
Ret-Time
B.P.Int.
US.Par.1
US.Par.2
C.A.S
17312
7045
13150
61141
17301
629
17301
4282
62108
, #
57-1
71-8
81-7
72-8
89-0
59-4
26-7
44-4
21-8
7ฃi
-------
MID LIBRARY SEARCH (LIBRARYNB)
08/31/98 19:31:00 + 9:33
SAMPLE: S-MM5-1B 1/3SA/100M INST. ID: F16
CONDS.: UG/ML *100ML * 1002/100?: *
-------
Library Search Data: 30068102 # 904 Base m/z: 43
08/31/9819:31:00+10:03 Cali: 30068102 # 3 RIC: 58816.
Sample: S-MM5-1B 1/3SA/100H INST. ID: F16
CondS.: UG/ML ซ100ML * 100V100% *(NA/NA )/1/3SA NA M
Enhanced (S 158 2N 01)
62231 spectra in LIBRARYNB searched for maximum PURITY
650 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 40233 NONAOECANOL
2 42521 1-EICOSANOL
3 42180 OCTADECANE, I-(ETHENYLOXY)-
4 37444 OXIRANE, HEXADECYL-
5 25971 OXIRANE, DOOECYL-
6 58380 DECANEDIOIC ACID, D1DECYL ESTER
7 37449 OCTADECANAL
8 28772 7-HEXADECENE, (Z)-
9 19525 2-METHYL-1-UNDECANOL
Rank
1
2
3
4
5
6
7
8
9
Rank
1
2
3
4
5
6
7
8
9
Formula
C19.H40.0
C20.H42.0
C20.H40.0
C18.H36.0
C14.H28.0
C30.H58.04
C18.H36.0
C16.H32
C12.H26.0
Ret. Time
B.P.Int.
US.Par.1
M.Ut
284
298
296
268
212
482
268
224
186
B.Pk Purity Fit
43
43
43
57
41
57
43
55
57
US. Par. 2
661 938
659 935
657 948
648 853
630 889
629 917
626 850
625 894
624 935
C.A.S. #
52783-43-4
629-96-9
930-02-9
7390-81-0
3234-28-4
2432-89-5
638-66-4
35507-09-6
10522-26-6
RFit
693
695
684
693
656
643
688
634
634
782
-------
1292
SAMPLE
C19.H40.0
1202 n
M WT 284
B PK 43
RANK 1
# 40233
PUR 661
C20.H42.0
1202 ^
M WT 298
B PK 43
RANK 2
ft 42521
PUR 659
MID LIBRARY SEARCH
08/31/98 19:31:08 + 10:03
SAMPLE: S-MM5-1B 1/3SA/100M INST. ID: FIG
CONDS.: UG/ML *100ML *100Z/1007J */l/3SA NA M
ENHANCED
-------
Library Search Data: 30068102 # 948 Base m/z: 57
08/31/98 19:31:00 + 10:33 Cali: 30068102 # 3 R1C: 154112.
Sample: S-MM5-1B 1/3SA/100M 1NST. 10: F16
Conds.: UG/ML *100ML *100%/100X *(NA/NA )/1/3SA NA M
Enhanced (S 158 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
360 matched at least 8 of the 16 largest peaks in the unknown
Rank In. Name
1 37465 NONADECANE
2 37462 HEPTADECANE, 2,6-DIMETHYL-
3 42196 HEPTADECANE, 2,6,10,14-TETRAMETHYL-
4 15969 HYDROXYLAMINE, 0-DECYL-
5 25997 PENTADECANE
6 19016 UNDECANE, 4,7-DIMETHYL-
7 22535 DOOECANE, 4,6-DIMETHYL-
8 25994 OODECAME, 2,6,11-TRIMETHYL-
9 15353 2,6-DIMETHYLDECANE
Rank
1
2
3
t.
5
6
7
8
9
Formula
C19.H40
C19.H40
C21.H44
C10.H23.0.N
C15.H32
C13.H28
C14.H30
C15.H32
C12.H26
M.Ut
268
268
296
173
212
184
198
212
170
B.Pk
57
57
57
43
57
43
57
57
43
Purity
847
834
827
825
817
812
801
799
797
Fit
958
942
950
967
954
964
951
965
927
RFit
866
858
846
827
842
813
805
802
807
Rank
1
2
3
4
5
6
7
8
9
Ret.Time
B.P.Int.
US.Par.1
US.Par.2
C.A.S
629
54105
18344
29812
629
17301
61141
31295
13150
, #
92-5
67-8
37-1
79-1
62-9
32-5
72-8
56-4
81-7
784
-------
MID LIBRARY SEARCH
08/31/98 19:31:00 + 10:33
SAMPLE: S-MM5-1B 1/3SA/100M INST. ID: F16
CONDS.: UG/ML *100ML *100Z/100Z *
DATA: 30068102 # 948
CALI: 30068102 * 3
BASE M/2: 57
RIC: 154112.
1032 -
SAMPLE
C19.H40
1032 i
M WT 268
B PK 57
RANK 1
* 37465
PUR 847
C19.H40
1032 i
M WT 268
B PK 57
RANK 2
# 37462
PUR 834
C21.H44
1032 i
M WT 296
B PK 57
RANK 3
# 42196
PUR 827
L
1
NONADECANE 0 f vt^crvv-t-V
i
1
ill hi ..i .. ........
HEPTADECANE , 2 , 6-D I METHYL-
I
h
.1 nil
HEPTADECANE, 2, 5, IQ, 14-TETRAMETHYL-
,
II
1 .. , . .
M/Z
50
100
150
200
250
Co
CM
-------
Library Search Data: 30068102 tt 988 Base m/z: 57
08/31/98 19:31:00 + 10:59 Cali: 30068102 # 3 RIC: 114816.
Sample: S-MM5-1B 1/3SA/100M 1NST. ID: F16
Conds.: UG/ML *100HL *100X/100X *(NA/NA J/1/3SA NA M
Enhanced (S 15B 2N OT)
62231 spectra in L1BRARYNB searched for maximum PURITY
644 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 37465 NONADECANE
2 25997 PENTADECANE
3 19054 UNDECANE, 2,6-DIMETHYL-
4 22530 TETRADECANE
5 37462 HEPTADECANE, 2,6-DIMETHYL-
6 25996 TRIDECANE, 4,8-DIMETHYL-
7 42196 HEPTADECANE, 2,6,10,14-TETRAMETHYL-
8 29263 HEXADECANE
9 32059 HEPTADECANE
Rank
1
2
3
4
5
6
7
8
9
Rank
1
2
3
4
5
6
7
8
9
Formula
C19.H40
C15.H32
C13.H28
C14.H30
C19.H40
C15.H32
C21.H44
C16.H34
C17.H36
Ret. Time
B.P.Int.
US.Par.1
H.Ut
268
212
184
198
268
212
296
226
240
B.Pk Purity Fit RFit
57
57
57
43
57
57
57
57
57
US. Par. 2
830 943
825 959
823 951
820 947
819 945
818 944
816 950
809 933
807 929
C.A.S. #
629-92-5
629-62-9
17301-23-4
629-59-4
54105-67-8
55030-62-1
18344-37-1
544-76-3
629-78-7
849
828
830
825
841
826
830
821
821
786
-------
MID LIBRARY SEARCH (LIBRARYNB)
08/31/98 19:31:80 + 10:59
SAMPLE: S-MM5-1B 1/3SA/100M
CONDS.: DC/ML *100ML
ENHANCED /l/3SA NA M
BASE M/Z: 57
RIC: 114816.
1014 i
SAMPLE
C19.H40
1014 i
M WT 268
B PK 57
RANK 1
# 37465
PUR 830
C15.H32
1014 n
M WT 212
B PK 57
RANK 2
# 25997
PUR 825
C13.H28
1014
M WT 184
B PK 57
RANK 3
tt 19054 "
PUR 823
M/Z
r
II
.11 M . .... . ... ... - --. . - . ~ ~ . ~
NONADECANE '0>v ^orv>xX
r
II
it ..I ... .. .. .. . ..__. _ _
U r*-"-' 1 ซ i 1 r- , i i i
PENTADECANE
r
I
r
,1,1
.1 .. .. .. .. .. .. .
UNDECANE , 2 , 6-D I METHYL-
ll
. , n . .. . .
50 ' ' 100 150 200 250
00
-------
Library Search Data: 30068102 #1036 Base m/z: 57
08/31/98 19:31:00 + 11:31 Cali: 30068102 # 3 RIC: 176640.
Sample: S-MM5-1B 1/3SA/100M INST. ID: F16
Conds.: UG/ML *100ML ซ100X/100X *(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
840 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 37462 HEPTADECANE, 2,6-DIMETHYL-
2 42196 HEPTADECANE, 2,6,10,14-TETRAMETHYL-
3 22535 DOOECANE, 4,6-DIMETHYL-
4 26001 DOOECANE, 2,7,10-TRIMETHYL-
5 25991 DOOECANE, 2.6,10-TRIMETHYL-
6 37465 NONADECANE
7 37466 PENTADECANE, 2,6,10,14-TETRAMETHYL-
8 25994 DOOECANE, 2,6,11-TRIMETHYl-
9 29264 TR1DECANE, 5-PROPYL-
Rank
1
2
3
L,
5
6
7
8
9
Formula
C19.H40
C21.H44
C14.H30
C15.H32
C15.H32
C19.H40
C19.H40
C15.H32
C16.H34
Rank
1
2
3
4
5
6
7
8
9
M.Wt B,
268
296
198
212
212
268
268
212
226
.Pk
57
57
57
57
57
57
71
57
57
Purity
865
829
823
822
820
815
806
803
791
Fit
970
948
969
970
972
930
937
948
934
RFit
875
853
824
828
824
838
826
814
833
Ret.Time
B.P.Int.
US.Par.1
US.Par.2
C.A.S
54105
18344
61141
74645
3891
629
1921
31295
55045
67-8
37-1
72-8
98-0
98-3
-92-5
70-6
-56-4
11-9
7ฃฃ
-------
MID LIBRARY SEARCH
08/31/98 19:31:00 + 11:31
SAMPLE: S-MM5-1B 1/3SA/100M INST. ID: F16
CONDS.: UG/ML *100ML *1007./100Z *
DATA: 30068102 #1036
CALI: 30068102 # 3
BASE M/Z: 57
RIC: 176640.
1146
SAMPLE
C19.H40
1146
M WT 268
B PK 57
RANK 1
# 37462
PUR 865
C21.H44
HEPTADECANE, 2,6-DIMETHYL-
HEPTADECANE, 2,6,10,14-TETRAMETHYL-
11 4b
M WT 296
B PK 57
RANK 2
# 42196
PUR 829
C14.H30
1146 i
M WT 198
B PK 57
RANK 3
# 22535
PUR 823
M/Z
r
I
r
50
1
i
j
DODECANE , 4 , 6-0 I METHYL-
100 150 200 258
en
-------
Library Search Data: 30068102 #1054 Base m/z: 55
08/31/98 19:31:00 + 11:43 Cali: 30068102 # 3 R1C: 48576.
Sample: S-MM5-1B 1/3SA/100M INST. ID: F16
Conds.: UG/ML *100ML *100X/100X *(NA/NA J/1/3SA NA M
Enhanced (S 158 2N OT)
62231 spectra in L1BRARYNB searched for maximum PURITY
648 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 34410 3-OCTADECENE, (E)-
2 34411 5-OCTADECENE, (E>-
3 34418 9-OCTADECENE, (E>-
4 28768 3-HEXADECENE, (Z)-
5 32425 1-DECANOL, 2-HEXYL-
6 26409 2-HEXYL-1-OCTANOL
7 28772 7-HEXADECENE, (Z)-
8 21963 3-TETRADECENE, -
9 32418 2-HEXYL-1-DECANOL
Rank
1
2
3
4
5
6
7
8
9
Formula
C18.H36
C18.H36
C18.H36
C16.H32
C16.H34.0
C14.H30.0
C16.H32
C14.H28
C16.H34.0
M.Wt
252
252
252
224
242
214
224
196
242
B.Pk
69
55
55
55
57
57
55
41
57
Purity
703
702
700
700
698
696
694
693
692
Fit
906
904
901
903
911
924
895
925
916
RFit
717
713
711
722
720
703
713
696
704
Rank
1
2
3
4
5
6
7
8
9
Ret.Time
B.P.Int.
US.Par.1
US.Par.2
C.A.S. #
7206-19-1
7206-21-5
7206-25-9
34303-81-6
2425-77-6
35507-09-6
41446-68-8
'SC
-------
MID LIBRARY SEARCH CLIBRARYNB)
88/31/98 19:31:00 + 11:43
SAMPLE: S-MM5-1B 1/3SA/100M INST. ID: FIG
CONDS.: UG/ML *100ML * 100Z/1 W?. *
DATA: 30068102 #1054
CALI: 30068102 # 3
BASE M/Z: 55
RIC: 48576.
1167
SAMPLE
C18.H36
1167 i
M WT 252
B PK 69
RANK 1
tt 34410 '
PUR 703
C18.H36
1167 i
M WT 252
B PK 55
RANK 2
# 34411
PUR 702
C18.H36
1167 i
M WT 252
B PK 55
RANK 3
# 34418
PUR 700
, ll
II .Illll 1,11, .l.i II . . i
3-OCTADECENE, - ฃ> r vV^-
|
II ill 1 ,,
9-OCTADECENE, -
|
, .ll , 1
M/Z
50
100
150
200
250
CD
-------
Library Search Data: 30068102 #1114
08/31/98 19:31:00 + 12:23 Call: 30068102 # 3
Sample: S-MM5-1B 1/3SA/100M INST. ID: F16
Conds.: DC/ML *100HL ป100X/100Z *(NA/NA )/1/3SA NA M
(S 158 2N OT)
Base m/z: 57
RIC: 80128.
62231 spectra in L1BRARYNB searched for maximum PURITY
360 matched at least 8 of the 16 largest peaks in the unknown
Rank In. Name
1 15969 HYDROXYLAMINE, 0-DECYL-
2 19016 UNDECANE, 4,7-DIMETHYL-
3 42196 HEPTADECANE, 2,6,10,14-TETRAMETHYL-
4 37462 HEPTADECANE, 2,6-DIMETHYl-
5 37465 NONADECANE
6 11602 OCTANE, 2,4,6-TRIMETHYL-
7 11612 NONANE, 2,5-DIMETHYL-
8 25997 PENTADECANE
9 15353 2,6-DIMETHrLDECAWE
Rank
1
2
3
4
5
6
7
8
9
Formula
C10.H23.0.N
C13.H28
C21.H44
C19.H40
C19.H40
C11.H24
C11.H24
C15.H32
C12.H26
M.Wt B.Pk Purity Fit RFit
173
184
296
268
268
156
156
212
170
43
43
57
57
57
57
57
57
43
799
790
782
777
773
765
762
761
760
957
966
940
917
919
968
913
930
916
808
792
814
823
829
765
762
807
775
Rank
1
2
3
4
5
6
7
8
9
Ret.lime
B.P.Int.
US.Par.1
US.Par.2
C.A.S
29812
17301
18344
54105
629
62016
17302
629
13150
, #
79-1
32-5
37-1
67-8
92-5
37-9
27-1
62-9
81-7
732,
-------
MID LIBRARY SEARCH
DATA: 30068102 #1114
CALI: 30068102 tt 3
BASE M/Z: 57
RIC: 80128.
1196 i
SAMPLE
C10.H23.0
1196 i
M WT 173
B PK 43
RANK 1
ซ 15969 '
PUR 799
C13.H28
1196 -.
M WT 184
B PK 43
RANK 2
* 19016
PUR 790
C21.H44
1196 i
M WT 296
B PK 57
RANK 3
ft 42196
PUR 782
r
.1
. ,1 , .
N HYDROXYLAMINE, 0-DECYL-
r
I
r
_J
,il ,iJ ...
UNDECANE , 4 , 7-D I METHYL-
II
HEPTADECANE, 2,6, 10, 14-TETRAMETHYL-
r
li
j
. . u L . .... . ,.., . , -
M/Z
50
100
150
200
250
CD
Co
-------
Library Search Data: 30068102 #1119 Base m/z: 57
08/31/98 19:31:00 + 12:27 Cali: 30068102 # 3 RIC: 112896.
Sample: S-MM5-1B 1/3SA/100M INST. ID: F16
Conds.: UG/ML ป100ML *100X/100X *(NA/NA )/1/3SA NA M
Enhanced (S 158 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
840 matched at least 7 of the 16 largest peaks in the unknown
2,6-DIMETHYL-
2,6,10,14-TETRAMETHYL-
Rank In. Name
1 37465 NONADECANE
2 37462 HEPTADECANE,
3 42196 HEPTADECANE,
4 46161 TRICOSANE
5 32059 HEPTADECANE
6 25991 DODECANE, 2,6,10-TRIMETHYL-
7 26001 DODECANE, 2,7,10-TRIMETHYl-
8 42192 HEPTADECANE, 2,6,10,15-TETRAMETHYL-
9 37466 PENTADECAN6, 2,6,10,14-TETRAMETHYL-
Rank
1
2
3
4
5
6
7
8
9
Formula
C19.H40
C19.H40
C21.H44
C23 . H48
C17.H36
C15.H32
C15.H32
C21.H44
C19.H40
Rank
1
2
3
4
5
6
7
8
9
M.Ut
268
268
296
324
240
212
212
296
268
B.Pk
57
57
57
43
57
57
57
57
71
Purity
842
840
823
819
809
807
803
802
800
Fit
964
953
943
924
940
973
972
953
935
RFit
842
844
835
856
816
808
803
828
807
Ret.Time B.P.Int.
US.Par.1
US.Par.2
C.A.S
629
54105
18344
638
629
3891
74645
54833
1921
, #
92-5
67-8
37-1
67-5
78-7
98-3
98-0
48-6
70-6
C!
-------
1128
SAMPLE
MID LIBRARY SEARCH (LIBRARYNB)
88/31/98 19:31:00 + 12:27
SAMPLE: S-MM5-1B 1/3SA/100M INST. ID: F16
CONDS.: UG/ML *100ML *100Z/100?! */l/3SA NA M
ENHANCED
DATA: 300E8102 #1119
CALI: 30068102 # 3
BASE M/Z: 57
RIC: 112896.
C19.H40
1128
M WT 268
B PK 57
RANK 1
tt 37465
PUR 842
NONADECANE
C19.H40
1128 I
M WT 268
B PK 57
RANK 2
# 37462
PUR 840
C21.H44
1128 i
M WT 296
B PK 57
RANK 3
# 42196
PUR 823
M/Z
ll
,
U-l 1 l|l i I "I
II
50
HEPTADECANE, 2,6-DIMETHYL-
,i ii . . ., ._ _.. , .- .,.,-.-.. , , , . , , , . , , ,
HEPTADECANE, 2, 6, 10, 14-TETRAMETHYL-
.1 tl _ .. ,1 ., _ -_ . , . , . . r- , I- ^, , , M., , 1 ' | 1 1 ' 1
'l00 150 200 250 300
CM
-------
Library Search Data: 30068102 #1191
08/31/98 19:31:00 + 13:15 Cali: 30068102 * 3
Sample: S-MM5-1B 1/3SA/100M INST. ID: F16
Conds.: UG/ML *100ML *100%/100X *(NA/NA )/1/3SA MA M
Enhanced (S 15B 2N OT)
Base m/z: 57
RIC: 71424.
62231 spectra in LIBRARYNB searched for maximum PURITY
879 matched at least 7 of the 16 largest peaks in the unknown
2,6-DIMETHYL-
2,6.10,14-TETRAMETHYL-
Rank In. Name
1 37465 NONADECANE
2 37462 HEPTADECANE,
3 42196 HEPTADECANE.
4 46161 TRJCOSANE
5 32058 HEXADECANE, 3-METHYL-
6 22530 TETRADECANE
7 22536 TRIDECANE, 3-METHYL-
8 25997 PENTADECANE
9 42192 HEPTADECANE, 2,6,10,15-TETRAMETHYL-
Rank
1
2
3
4
5
6
7
8
9
Rank
1
2
3
4
5
6
7
8
9
Formula
C19.H40
C19.H40
C21.H44
C23.H48
C17.H36
C14.H30
C14.H30
C15.H32
C21.H44
Ret. Time
B.P.Int.
US.Par.1
M.Wt
268
268
296
324
240
198
198
212
296
B.Pk Purity Fit
57
57
57
43
57
43
57
57
57
US. Par. 2
792 971
778 942
759 955
749 91 1
748 932
743 948
740 928
736 948
736 933
C.A.S. #
629-92-5
54105-67-8
18344-37-1
638-67-5
6418-43-5
629-59-4
6418-41-3
629-62-9
54833-48-6
RFit
798
788
773
808
758
752
748
764
764
7ฃ8
-------
C19.H40
1040
M NT 268
B PK 57
RANK 1
# 37465
PUR 792
C19.H40
1040
M WT 268
B PK 57
RANK 2
# 37462
PUR 778
MID LIBRARY SEARCH (LIBRARYNB)
08/31/98 19:31:00 + 13:15
SAMPLE: S-MM5-1B 1/3SA/100M INST. ID: F16
CONDS.: UG/ML *100ML *100Z/1007> *
DATA: 30068102 #1191
CALI: 30068102 # 3
BASE M/Z: 57
RIC: 71424.
1048
SAMPLE
1
|
, Jl
i ,.ll
. . I.
,.!.! . , .... . .,.. ., ... ., ......
NONADECANE
HEPTADECANE, 2,6-DIMETHYL-
C21.H44
1040 -I
M WT 296
B PK 57
RANK 3
# 42196
PUR 759
M/Z
1
ll
HEPTADECANE , 2 , 6 , 1 0 , 1 4-TETRAMETHYL-
1
50
100 150 200 250
-------
Library Search Data: 30068102 #1265
08/31/98 19:31:00 + 14:04 Cali: 30068102 # 3
Sample: S-MM5-1B 1/3SA/100M INST. ID: F16
Conds.: UG/ML *100ML *100V100X *
-------
MID LIBRARY SEARCH
08/31/98 19:31:00 + 14:04
SAMPLE: S-MM5-1B 1/3SA/100M INST. ID: F16
CONDS.: UG/ML *100ML *100Z/100Z *
DATA: 30068102 #1265
CALI: 30068102 # 3
BASE M/Z: 57
RIC: 53184.
1075
SAMPLE
C19.H40
1075 i
M WT 268
B PK 57
RANK 1
* 37462
PUR 763
C21.H44
1075 1
M WT 296
B PK 57
RANK 2
# 42192
PUR 759
C15.H32
1075 i
M WT 212
B PK 57
RANK 3
# 25997
PUR 749
M/Z
r
1
r
r
_4
i ! i, ,
HEPTADECANE , 2 , 6-D I METHYL-
ll
ll 1 i j| i . .j *~ -- - -- - -
HEPTADECANE , 2,6,10,1 5-TETRAMETHYL-
r
1
J ' '
PENTADECANE
ll
i il it .........
50 100 150 200 250 300
CO
c.o
-------
Library Search Data: 30068102 #1335 Base m/z: 57
08/31/98 19:31:00 + 14:51 Cali: 30068102 # 3 RIC: 40704.
Sample: S-MH5-1B 1/3SA/100H INST. ID: F16
CondS.: UG/ML *100Ml ป100X/100% *(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
715 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 37456 2-METHYLOCTADECANE
2 37465 NONADECANE
3 50998 HENEICOSANE, 11-(1-ETHYLPROPYL)-
4 37462 HEPTAOECANE, 2,6-DIMETHYL-
5 32058 HEXADECANE, 3-METHYL-
6 49555 PENTACOSANE
7 46161 TRICOSANE
8 29263 HEXADECANE
9 34808 HEPTADECANE, 3-METHYL-
Rank
1
2
3
4
5
6
7
8
9
Formula
C19.H40
C19.H40
C26.H54
C19.H40
C17.H36
C25.H52
C23.H48
C16.H34
C18.H38
Rank
1
2
3
4
5
6
7
8
9
M.Ut B.Pk Purity Fit RFit
268
268
366
268
240
352
324
226
254
43
57
43
57
57
43
43
57
57
740
712
709
708
707
703
701
697
695
933
942
885
872
928
889
901
919
894
758
748
738
755
723
782
770
737
714
Ret.Time
B.P.Int.
US.Par.1 US.Par.2
C.A.S. #
629-92-5
55282-11-6
54105-67-8
6418-43-5
629-99-2
638-67-5
544-76-3
6418-44-6
8CC
-------
1000
SAMPLE
MID LIBRARY SEARCH (LIBRARYNB)
08/31x98 19:31:00 + 14:51
SAMPLE: S-MM5-1B 1/3SA/100M INST. ID: F16
CONDS.: UG/ML *100ML *100Z/100Z *
DATA: 30068102 #1335
CALI: 30068102 * 3
BASE M/Z: 57
RIC: 40704.
C19.H40
1000
M WT 268
B PK 43
RANK 1
# 37456
PUR 740
2-METHYLOCTADECANE
C19.H40
1000 i
M WT 268
B PK 57
RANK 2
# 37465
PUR 712
C26.H54
1000 -j
M WT 366
B PK 43
RANK 3
* 50998
PUR 709
/ NONADECANE /
' i
V ^-^
HENEICOSANE, 1 l-(l-ETHYLPROPYL)-
i ,i
M/Z
CO
O
50
100
150
200
250
300
-------
Library Search Data: 30068102 #1402 Base m/z: 57
08/31/98 19:31:00 + 15:36 Cali: 30068102 # 3 RIC: 29856.
Sample: S-MM5-1B 1/3SA/100M INST. ID: F16
Conds.: UG/ML *100HL *100X/100X ซ(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
714 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 37465 NONAOECANE
2 37462 HEPTADECANE, 2,6-DIHETHYL-
3 46161 TR1COSANE
4 49555 PENTACOSANE
5 32059 HEPTAOECANE
6 42193 EICOSANE, 10-METHYL-
7 37456 2-METHYLOCTADECANE
8 44314 DOCOSANE
9 42197 HENEICOSANE
Rank
1
2
3
4
5
6
7
8
9
Formula
C19.H40
C19.H40
C23.H48
C25.H52
C17.H36
C21.H44
C19.H40
C22.H46
C21.H44
M.Wt B.Pk Purity Fit RFit
268
268
324
352
240
296
268
310
296
57
57
43
43
57
57
43
57
57
690
682
675
664
660
658
658
656
654
965
938
923
898
954
914
948
912
912
706
692
727
734
671
679
677
701
692
Rank
1
2
3
4
5
6
7
8
9
Ret.Time
B.P.Int.
US.Par.1 US.Par.2
C.A.S. #
629-92-5
54105-67-8
638-67-5
629-99-2
629-78-7
54833-23-7
629-97-0
629-94-7
&!
-------
1115
SAMPLE
MID LIBRARY SEARCH (LIBRARYNB)
08/31/98 19:31:00 + 15:36
SAMPLE: S-MM5-1B 1/3SA/100M INST. ID: F16
CONDS.: UG/ML *100ML *100Z/100/2 *(NA/NA V1/3SA NA M
ENHANCED <5 15B 2N 0T)
DATA: 30068102 #1402
CALI: 30068102 * 3
BASE M/Z: 57
RIC: 29856.
C19.H40
1115
M WT 268
B PK 57
RANK 1
# 37465
PUR 690
C19.H40
1115
M WT 268
B PK 57
RANK 2
# 37462
PUR 682
C23.H48
1115
M WT 324
B PK 43
RANK 3
ซ 46161
PUR 675
M/2
NONADECANE
II
1.1
HEPTADECANE, 2,6-DIMETHYL-
TRICOSANE
Jl
ll
50 100 150 200 250 300
OT
-------
TIC SELECTION REPORT
DATA FILE: 30068102
THE FOLLOWING PEAKS WERE REJECTED BECAUSE
AT LEAST 40 X OF THEIR SIZE WAS ACCOUNTED FOR BY
TARGET COMPOUNDS ELUTING WITHIN 4 SCANS OF THE
PEAK TOP.
SCAN
341
530
829
1088
1552
1783
SIZE
188320.
398528.
303185.
341760.
204287.
192640.
AMOUNT
24.846
52.579
40.000
40.000
40.000
40.000
TOTAL NUMBER OF UNIDENTIFIED PEAKS WITH SIZE
GREATER THAN 10 X OF THE CLOSEST INTERNAL STANDARD
THAT DOES NOT HAVE INTERFERENCES = 95
INTERNAL STANDARDS THAT HAVE RIC SIZE LESS THAN
50 % OR GREATER THAN 200 X OF THE ESTIMATED RIC SIZE
ARE CONSIDERED TO HAVE INTERFERENCES AND WILL NOT BE USED
FOR QUANT I TAT ION.
PERCENT OF
ESTIMATED
# INTERNAL STANDARD RIC SIZE RIC SIZE SCAN
1 C140 NAPHTHALENE-OS 398528. 260 * 530
2 CI50 ACENAPHTHENE-D10 303185. 156 829
3 CI60 PHENANTHRENE-D10 341760. 157 1088
4 CI70 CHRYSENE-012 204287. 145 1552
5 CI75 PERYLENE-D12 192640. 162 1783
* INDICATES INTERFERENCE
SIZE = AREA
8C4
-------
Semivolatile Organics
Method 0010/8270
Client Name: Pacific Environmental Services
Client ID: T-MM5-2-F,FH,XAD,COND,BH
LAB ID: 300681-0003-SA
Matrix: AIRTRAIN Sampled:
Authorized: 30 JUL 98 Prepared:
25 JUL 98
31 JUL 98
Dilution Factor: 1.0
Parameter
Phenol
bi s(2-Chloroethyl)ether
2-Chlorophenol
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Benzyl alcohol
1,2-Dichlorobenzene
2-Methylphenol
2,2'-Oxybis(l-chloropropane)
3/4-Methylphenol
N-Nitroso-di-n-propylamine
Hexachloroethane
Nitrobenzene
Isophorone
2-Nitrophenol
2,4-Dimethylphenol
Benzoic acid
bi s(2-Chloroethoxy)-methane
2,4-Di chlorophenol
1,2,4-Tri chlorobenzane
Naphthalene
4-Chloroaniline
Hexachlorobutadiene
4-Chloro-3-methyl phenol
2-Methylnaphtha!ene
Hexachlorocyclopentadi ene
2,4,6-Trichlorophenol
2,4,5-Trichlorophenol
2-ChloronaphthaIene
2-Nitroaniline
Dimethyl phthalate
Acenaphthylene
3-Nitroaniline
Acenaphthene
2,4-Dinitrophenol
4-Nitrophenol
Dibenzofuran
Wet wt.
Result
Units
Received: 30 JUL 98
Analyzed: 31 AU6 98
Reporting
Limit
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
60
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
150
30
30
30
30
30
30
30
30
30
30
150
30
30
30
30
150
30
150
150
30
Qualifier
R
Note R = Reporting limit(s) raised due to sample volume limitations.
ND = Not Detected
Reported By: Emily Uebelhoer
Approved By: Karin Yee
813
The cover letter is an integral part of this report.
Rev 230787
-------
Semivolatile Organics
Method 0010/8270
(cont.)
Client Name: Pacific Environmental Services
Client ID:
LAB ID:
Matrix:
Authorized:
T-MM5-2-F,FH,XAD,COND,BH
300681-0003-SA
AIRTRAIN
30 JUL 98
Sampled: 25 JUL 98
Prepared: 31 JUL 98
Dilution Factor: 1.0
Parameter
2,4-Dinitrotoluene
2,6-Dinitrotoluene
Diethyl phthalate
4-Chlorophenyl phenyl ether
Fluorene
4-Nitroaniline
4,6-Dinitrp-2-methylphenol
N-Nitrosodiphenylamine
4-Bromophenyl phenyl ether
Hexachlorobenzene
Pentachlorophenol
Phenanthrene
Anthracene
Di-n-butyl phthalate
Fluoranthene
Pyrene
Butyl benzyl phthalate
3,3'-Dichlorobenzidine
Benzo(a)anthracene
bis(2-Ethylhexyl)-phthalate
Chrysene
Di-n-octyl phthalate
Benzofb fluoranthene
Benzofk fluoranthene
Benzo(a pyrene
Indeno( ,2,3-cd)pyrene
Dibenz(a,h)anthracene
Benzo(g,h,i)perylene
Acetppnenone
4-Aminobiphenyl
Aniline
Benzidine
3,3'-Dimethylbenzidine
N-Nitrosodimethyl amine
N-Nitrosomorpholine
Pentachloronitrobenzene (PCNB)
o-Toluidine
Wet wt.
Result
Units
Received: 30 JUL 98
Analyzed: 31 AUG 98
Reporting
Limit
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
30
30
30
30
30
150
150
30
30
30
150
30
30
30
30
30
30
60
30
30
30
30
30
30
30
30
30
30
30
150
30
300
60
30
30
150
60
Qualifier
ND = Not Detected
Reported By: Emily Uebelhoer
Approved By: Karin Yee
8C6
The cover letter is an integral part of this report.
Rev 230787
-------
Semivolatile Organics
Method 0010/8270
(cont.)
Client Name: Pacific Environmental Services
Client ID:
LAB ID:
Matrix:
Authorized:
T-MM5-2-F,FH,XAD,COND,BH
300681-0003-SA
AIRTRAIN
30 JUL 98
Sampled: 25 JUL 98
Prepared: 31 JUL 98
Dilution Factor: 1.0
Parameter
2-Methoxybenzenamine
Biphenyl
Chioroacetophenone
Cumene
DBCP (l,2-Dibromo-3-chloropropane)
Benzo(e)pyrene
N-N-Dietnylaniline
Dimethylaniline
3,3'-Dimethoxybenzidine
Hydroquinone
4,4'-Methyl-bis(2-chloroaniline)
4-Nitrodiphenyl
Trifluralin
Wet wt.
Result
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Units
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
Received: 30 JUL 98
Analyzed: 31 AUG 98
Reporting
Limit
Qualifier
K
K
K
K
K
K
K
K
K
K
K
K
K
Surrogate
Nitrobenzene-d5
2-Fluorobiphenyl
Terphenyl-dl4
Phenol-d5
2-Fluorophenol
2,4,6-Tribromophenol
Recovery
87 %
105 %
78 %
67 %
62 %
49 %
Acceptable Range
45
62
58
43
36
58
107
110
135
130
111
131
Note i = Surrogate recovery is outside of control limits.
Note K = Identified by mass spectrum only; quantitation based on 1:1 response with
internal standard.
ND = Not Detected
Reported By: Emily Uebelhoer
Approved By: Karin Yee
8C7
The cover letter is an integral part of this report.
Rev 230787
-------
Semivolatiles Library Search (20 Compound TID)
Method 8270
Client Name: Pacific Environmental Services
Client ID: T-MM5-2-F,FH,XAD,COND,BH
LAB ID: 300681-0003-SA
Matrix: AIRTRAIN Sampled:
Authorized: 30 JUL 98 Prepared:
Dilution Factor: 1.0
25 JUL 98
NA
Parameter Result
4-Hydroxy-4-methyl-2-pentanone 450
n-Nonane 370
Unknown alkane 180
IH-Indene, 1-ethylidene- 240
Undecane 180
Heptadecane, 2,6,10,14 -tetramethyl- 220
Unknown alkane 320
Unknown 200
Heptadecane, 2,6,10,14 -tetramethyl- 260
Pentadecane 320
Nonadecane 290
Heptadecane, 2,6-dimethyl- 190
Heptadecane, 2,6-dimethyl- 460
Unknown alkane 160
Nonadecane 200
Nonadecane 110
Heptadecane, 2,6-dimethyl- 130
Nonadecane 110
3-Octadecene, (E)- 160
Unknown 120
Units
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
Received: 30 JUL 98
Analyzed: 31 AUG 98
Reporting
Limit
Qualifier
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Note 0 = Or structurally similar compound (isomer).
NA = Not Applicable
Reported By: Emily Uebelhoer
Approved By: Karin Yee
The cover letter is an integral part of this report.
Rev 230787
-------
Sample: T-MM5-2
Client: PAC1FI
Analyst: DAT
QUANTERRA GC/MS
Target Compound Data Summary Sheet
1/3SA/1ML
Instrument ID: F16
Quan List Threshold: 0.95
Data File: 30068103
Std Id: ST16980831
INST. ID: F16
Date Analyzed: 08/31/98 20:01
Run Factor: 3.00
Surrogate Vol.:
1.00
Surrogate Spike Recoveries
8270-G, LIMS 10/10/96
Surrogate
CS20 N1TROBENZENE-D5
CS25 2-FLUOROBIPHENY
CS30 TERPHENYL-D14
CS45 PHENOL-05
CS50 2-FLUOROPHENOL
CS55 2,4,6-TRIBROMOP
Surrogate Amount (ug)
Spi ked Measured
43.50
53.50
38.80
67.20
61.90
48.90
% Recovery
Measured QC limits
50.00
50.00
50.00
100.0
100.0
100.0
87.0
105.
77.6
67.2
61.9
48.9
45 107
62 110
58 135
43 130
36 111
58 131
Target Compounds: SAP9
Reporting
Parameter Scan Result Units Limit
HEXACHLOROBENZENE-C13 ND
C310 N-NITROSOOIMETHYLAMINE
PYRIDINE
2-PICOLINE
N-NITROSOMETHYLETHYLAMINE
METHYLMETHANESULFONATE
N-NITROSOOIETHYLAMINE
ETHYLMETHANE SULFONATE
PENTACHLOROETHANE
C320 ANILINE
C315 PHENOL
C325 B1S(2-CHLOROETHYL)ETHER
C330 2-CHLOROPHENOL
C335 1,3-DICHLOROBENZENE
C340 1,4-DICHLOROBENZENE
C345 BENZYL ALCOHOL
C350 1,2-DlCHLOROBENZENE
C355 2-METHYLPHENOL
C360 2,2'-OXYBIS(1-CLPROPAN)
C361 ACETOPHENONE
N-NITROSOPYRROLIDINE
N-NITROSOMORPHOLINE
3-METHYL PHENOL
C365 4-METHYLPHENOL
C370 N-NITROSO-DI-N-PROPYLAM
0-TOLUIDINE
C375 HEXACHLOROETHANE
C410 NITROBENZENE
N-NITROSOPIPERIDINE
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
UG/A 30.0
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
Reviewed by:
30.0
60.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
Nn
-------
OUANTERRA GC/MS
Target Compound Data Summary Sheet
Data File: 30068103
Std Id: ST16980831
Sample: T-MM5-2
Client: PAC1FI
Analyst: DAT
1/3SA/1ML
INST. ID: F16
Instrument ID: F16
Date Analyzed: 08/31/98 20:01
Run Factor: 3.00
Quan List Threshold: 0.95
Surrogate Vol.:
1.00
Parameter
C415 ISOPHORONE
C420 2-NITROPHENOL
C425 2,4-OIMETHYLPHENOL
C435 BIS(2-CHLOROETHOXY)METH
C440 2,4-DlCHLOROPHENOL
C430 BEN20IC ACID
AA-DIMETHYLPHENETHYLAMINE
C445 1,2,4-TRICHLOROBENZENE
C450 NAPHTHALENE
C455 4-CHLOROANALINE
2,6-OICHLOROPHENOL
HEXACHLOROPROPENE
C460 HEXACHLOROBUTADIENE
P-PHENYLENE DIAMINE
N-NITROSOOI-N-BUTYLAMINE
C465 4-CHLORO-3-METHYLPHENO
SAFROLE
C470 2-METHYLNAPHTHALENE
1,2,4,5-TETRACHLOROBENZENE
ISOSAFROLE (#1)
C510 HEXACHLOROCYCLOPENTADI
C515 2,4,6-TRICHLOROPHENOL
C520 2.4,5-TRICHLOROPHENOL
ISOSAFROLE (#2)
C525 2-CHLORONAPHTHALENE
1-CHLORONAPHTHALENE
C530 2-NITROANALINE
1,4-NAPHTHOOUINONE
C535 D1METHYLPHTHALATE
1,3-DlNlTROBENZENE
C540 ACENAPHTHYLENE
C543 2,6-DINITROTOLUENE
CS45 3-NITROANILINE
CSSO ACENAPHTHENE
C555 2,4-DINITROPHENOL
C565 DIBENZOFURAN
C560 4-NITROPHENOL
PENTACHLOROBENZENE
C570 2,4-DINITROTOLUENE
1-NAPHTHYLAMINE
2-NAPHTHYLAMINE
2,3,4,6- TETRACHLOROPHENOL
C580 DIETHYLPHTHALATE
C590 FLUORENE
Target Compounds: SAP9
Scan
653
Result
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND_"\
^60X
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Units
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
Reporting
Limit
30.0
30.0
30.0
30.0
30.0
150.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
60.0
30.0
30.0
30.0
60.0
30.0
15.0
150.0
30.0
30.0
30.0
30.0
30.0
150.0
30.0
150.0
30.0
150.0
30.0
30.0
30.0
30.0
60.0
30.0
30.0
L
-------
OUANTERRA GC/MS
Target Compound Data Surmary Sheet
Data File: 30068103
Std Id: ST16980831
Sample: T-MM5-2 1/3SA/1ML INST. ID: F16
Client: PACIFI Date Analyzed: 08/31/98 20:01
Analyst: DAT Instrument ID: F16 Run Factor: 3.00
Quan List Threshold: 0.95 Surrogate Vol.: 1.00
Target Compounds: SAP9
Reporting
Parameter Scan Result Units Limit
C585 4-CHLOROPHENYL-PHENYLE
5-N1TRO-0-TOLUIDINE
C595 4-N1TROANALINE
C610 4.6-DINITRO-2-METHYLPH
C61S N-NITROSOD1PHENYLAMINE
C620 AZOBENZENE
SYM-TRINITROBENZENE
C625 4-BROMOPHENYL-PHENYLET
PHENACETIN
DIALLATE 234
C630 HEXACHLOROBENZENE
4-AM1NOBIPHENYL
C635 PENTACHLOROPHENOL
PRONAM1DE
PENTACHLORON1TROBENZENE
C640 PHENANTHRENE
C645 ANTHRACENE
2SECBUTYL-4,6-DINITROPHENOL
C647 CARBAZOLE
C650 DI-N-BUTYLPHTHALATE
4-NITROOUINOLINE-1-OXIDE
METHAPYRILENE
1SCORIN
C655 FLUORANTHENE
CHLOROBENZILATE
C710 BENZIDINE
C715 PYRENE
ARAMITE (#1)
ARAMITE (#2)
P-DIMETHYLAMINOAZOBENZENE
3,3'-DIMETHYLBENZIDINE
-------
OUANTERRA GC/MS
Target Compound Data Summary Sheet
Data File: 30068103
Std Id: ST16980831
Sample: T-MM5-2
Client: PACIFI
Analyst: DAT
1/3SA/1HL
INST. ID: F16
Instrument ID: F16
Date Analyzed: 08/31/98 20:01
Run Factor: 3.00
Ouan List Threshold: 0.95
Surrogate Vol.:
1.00
Parameter
Target Compounds: SAP9
Scan Result Units
C775 BENZO(A)PYRENE
C780 INDENO(1,2,3-CO)PYRENE
C785 DIBENZ(A,H)ANTHRACENE
C790 BENZO(G,H,I)PERYLENE
NO
ND
ND
ND
UG/A
UG/A
UG/A
UG/A
Reporting
Limit
======3:====
30.0
30.0
30.0
30.0
1 -
-------
DATA FROM FILE: 30068103 SCANS 93 TO 1203 ACQUIRED: 08/31/98 20:01:00
CALI: 30068103 #3
SAMPLE: T-MM5-2 1/3SA/1ML INST. ID: F16
CONDS.: UG/ML *1ML *100Z/100Z *
-------
DATA FROM FILE: 30068103 SCANS 1203 TO 2158 ACQUIRED: 08/31/98 20:01:00
CALI: 30368103 #3
SAMPLE: T-MM5-2 1/3SA/1ML INST. ID: F16
CONDS.: UG/ML *1ML *100Z/100Z *
-------
STANDARD USED FOR THIS REPORT IS ST16980831 REPORT PRINTED: 9/01/98 15:07:43
ADDITIONAL STANDARD USED FOR THIS REPORT IS: ST16980831A
OUANTERRA QUANT I TAT ION SUMMARY
File: 30068103
Sample: T-MM5-2 1/3SA/1ML INST. ID: F16
Analyst: DAT Instrument Id: F16 Analyzed: 08/31/98 20:01
Compounds with amounts less than 0.20 reported as NOT FOUND
Library Units: UG/ML
No Entry Name Mass Meth Scan Ref Area RRF(L) Amount
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
S1# 1
S2# 1
S3# 1
S4# 1
S5# 1
S6# 1
S2# 2
S3* 3
S5# 2
Sl# 3
S1# 2
S3# 2
S4# 4
S1# 15
S1# 20
S1# 30
S1# 40
Sl# 60
S1# 70
S1# 85
Sl# 95
S1#100
S1#105
sumo
S1#115
S1#125
S1#130
S1#145
S1#150
Sl#160
Sl#165
Sl#170
Sl#175
S 1*180
S1#182
SI #185
S1#190
S1#195
SI #200
S2# 10
S2# 15
S2# 20
S2# 25
S2# 30
S2# 35
CI30 1,4-DICHLOROBENZENE
CI40 NAPHTHALENE-OS
CI50 ACENAPHTHENE-D10
C160 PHENANTHRENE-D10
CI70 CHRYSENE-D12
CITS PERYLENE-D12
CS20 NITROBENZENE-D5
CS25 2-FLUOROBIPHENYL
CS30 TERPHENYL-D14
CS45 PHENOL-D5
CS50 2-FLUOROPHENOL
CS55 2,4,6-TRIBROMOPHENO
HEXACHLOROBENZENE-C13
C310 N-NITROSODIMETHYLAM
PYRIDINE
2-PICOLINE
N- NITROSOMETHYLETHYLAMIN
METHYLMETHANESULFONATE
N-NITROSOD1ETHYLAMINE
ETHYLMETHANE SULFONATE
PENTACHLOROETHANE
C320 ANILINE
C315 PHENOL
C325 BIS(2-CHLOROETHYL)E
C330 2-CHLOROPHENOL
C335 1,3-DICHLOROBENZENE
C340 1,4-DICHLOROBENZENE
C345 BENZYL ALCOHOL
C350 1,2-DICHLOROBENZENE
C355 2-METHYLPHENOL
C360 2,2'-OXYBIS(1-CLPRO
C361 ACETOPHENONE
N-NITROSOPYRROLIDINE
N-NITROSOMORPHOLINE
3-METHYL PHENOL
C365 4-METHYLPHENOL
C370 N-NITROSO-DI-N-PROP
0-TOLUIDINE
C375 HEXACHLOROETHANE
C410 NITROBENZENE
N-NITROSOPIPERIDINE
C415 ISOPHORONE
C420 2-NITROPHENOL
C425 2,4-DIMETHYLPHENOL
C435 B1SC2-CHLOROETHOXY)
152
136
164
188
240
264
82
172
244
99
112
330
294
74
79
93
42
80
102
79
117
93
94
93
128
146
146
108
146
108
45
105
100
56
108
108
70
106
117
77
42
82
139
107
93
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
BV
BB
BB
BB
BB
BB
BB
BB
BB
BB
BB
BB
BB
BB
BB
BB
VB
BB
VB
VV
VB
BB
BB
341 1
531 2
830 3
1088 4
1554 5
1784 6
422 2
724 3
1386 5
310 1
199 1
971 3
4 NOT
1 NOT
1 NOT
1 NOT
1 NOT
1 NOT
1 NOT
1 NOT
307 1
1 NOT
311 1
320 1
1 NOT
1 NOT
343 1
370 1
1 NOT
1 NOT
1 NOT
401 1
402 1
410 1
1 NOT
1 NOT
404 1
1 NOT
1 NOT
423 2
2 NOT
2 NOT
2 NOT
500 2
2 NOT
31920.
111468.
58555.
96270.
92258.
85395.
56985.
94839.
89070.
108633.
67610.
16861.
FOUND
FOUND
FOUND
FOUND
FOUND
FOUND
FOUND
FOUND
821.
FOUND
11667.
634.
FOUND
FOUND
532.
5992.
FOUND
FOUND
FOUND
11312.
224.
3898.
FOUND
FOUND
1437.
FOUND
FOUND
1534.
FOUND
FOUND
FOUND
820.
FOUND
1.000
1
1
1
1
1
0
1
0
2
1
0
0
1
1
1
0
1
0
0
0
0
0
.000
.000
.000
.000
.000
.470
.234
.995
.025
.368
.236
.602
.968
.368
.617
.854
.934
.553
.821
.906
.445
.330
40
40
40
40
40
40
43
52
38
67
61
48
1
7
0
0
8
7
0
5
1
1
0
.000
.000
.000
.000
.000
.000
.550
.489
.803
.210
.923
.877
.710
.430
.581
.412
.789
.330
.508
.952
.988
.237
.892
815
-------
46 S2# 40 C440 2,4-DICHLOROPHENOL 162 A BB 519 2 346. 0.308 0.404
47 S2# 45 C430 BENZOIC ACID 122 2 NOT FOUND
48 S2# 50 AA-DIMETHYLPHENETHYLAHIN 58 2 NOT FOUND
49 S2# 55 C445 1,2,4-TRlCHLOROBENZ 180 AW 527 2 220. 0.331 0.239
-------
50 S2* 60 C450 NAPHTHALENE
51 52* 80 C455 4-CHLOROANAL1NE
52 52* 85 2,6-DICHLOROPHENOL
53 S2* 90 HEXACHLOROPROPENE
54 S2# 95 C460 HEXACHLOROBUTAD1ENE
55 52*115 P-PHENYLENE DIAMINE
56 52*120 N-NITROSOD1-N-BUTYLAMINE
57 52*130 C465 4-CHLORO-3-METHYLPH
58 52*140 SAFROLE
59 S2#145 C470 2-METHYLNAPHTHALENE
60 S3* 10 1,2,4,5-TETRACHLOROBENZE
61 S3* 15 ISOSAFROLE (#1)
62 S3* 20 C510 HEXACHLOROCYCLOPENT
63 S3* 25 C515 2,4.6-TRICHLOROPHEN
64 S3* 30 C520 2,4.5-TRICHLOROPHEN
65 S3* 35 ISOSAFROLE (#2)
66 S3* 40 C525 2-CHLORONAPHTHALENE
67 S3* 42 1-CHLORONAPHTHALEN
68 S3* 45 C530 2-NITROANAL1NE
69 S3* 50 1,4-NAPHTHOQUINONE
70 S3* 55 C535 D1METHYLPHTHALATE
71 S3* 60 1,3-D[NITROBENZENE
72 S3* 65 C540 ACENAPHTHYLENE
73 S3* 70 C543 2,6-DlNITROTOLUENE
74 S3* 75 C545 3-NITROANILINE
75 S3* 80 C550 ACENAPHTHENE
76 S3* 85 C555 2,4-DINITROPHENOL
77 S3* 90 C565 DIBENZOFURAN
78 S3* 95 C560 4-NITROPHENOL
79 S3#100 PENTACHLOROBENZENE
80 S3#105 C570 2,4-DINITROTOLUENE
81 53*110 1-NAPHTHYLAMINE
82 S3*115 2-NAPHTHYLAMINE
83 S3#120 2,3,4,6-TETRACHLOROPHENO
84 S3*130 C580 DIETHYLPHTHALATE
85 S3#135 C590 FLUORENE
86 53*140 C585 4-CHLOROPHENYL-PHEN
87 53*145 5-NITRO-O-TOLUIDINE
88 53*150 C595 4-NITROANALINE
89 S4* 10 C610 4.6-DINITRO-2-METHY
90 S4# 15 C615 N-NITROSODIPHENYLAM
91 54* 20 C620 AZOBENZENE
92 S4# 25 SYM-TRINITROBENZENE
93 54* 30 C625 4-BROMOPHENYL-PHENY
94 54* 35 PHENACETIN
95 54* 37 DIALLATE
96 S4* 40 C630 HEXACHLOROBENZENE
97 54* 45 4-AMINOBIPHENYL
98 54* 50 C635 PENTACHLOROPHENOL
99 S4* 55 PRONAM1DE
100 S4# 60 PENTACHLORONITROBENZENE
101 54* 65 C640 PHENANTHRENE
102 S4# 70 C645 ANTHRACENE
103 54* 75 2SEC8UTYL-4,6-DlNiTROPHE
104 S4# 80 C647 CARBAZOLE
105 54* 85 C650 DI-N-BUTYLPHTHALATE
106 S4ซ100 4-N1TROOU1NOLINE-1-OXIDE
107 S4#105 METHAPYRILENE
108 54*106 ISODRIN
109 S4#110 C655 FLUORANTHENE
110 S4*120 CHLOROBENZ1LATE
128
127
162
213
225
108
84
107
162
142
2H
162
237
196
196
104
162
162
65
158
163
168
152
165
138
153
184
168
109
250
165
143
143
232
149
166
204
152
138
198
169
77
75
248
108
234
284
169
266
173
237
178
178
211
167
149
190
58
193
202
139
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
BV
BB
BB
BB
BB
BB
BB
VV
BB
VB
VB
BV
BB
BB
VB
BB
BB
BB
BB
BB
BB
534 2
556 2
2 NOT
2 NOT
2 NOT
2 NOT
2 NOT
2 NOT
649 2
653 2
3 NOT
698 3
3 NOT
3 NOT
3 NOT
3 NOT
3 NOT
3 NOT
765 3
3 NOT
3 NOT
808 3
3 NOT
3 NOT
3 NOT
836 3
858 3
868 3
3 NOT
3 NOT
882 3
882 3
903 3
3 NOT
3 NOT
927 3
3 NOT
942 3
950 3
4 NOT
965 4
4 NOT
1026 4
4 NOT
4 NOT
4 NOT
4 NOT
4 NOT
4 NOT
4 NOT
4 NOT
1092 4
4 NOT
4 NOT
1149 4
4 NOT
4 NOT
4 NOT
4 NOT
1300 4
4 NOT
27047. 1.022
596. 0.454
FOUND
FOUND
FOUND
FOUND
FOUND
FOUND
1150. 0.248
42032. 0.751
FOUND
451. 0.044
FOUND
FOUND
FOUND
FOUND
FOUND
FOUND
848. 0.502
FOUND
FOUND
398. 0.197
FOUND
FOUND
FOUND
1939. 1.159
158. 0.189
1797. 1.669
FOUND
FOUND
891. 0.397
394. 0.837
418. 0.966
FOUND
FOUND
5465. 1.298
FOUND
1762. 0.356
223. 0.307
FOUND
4015. 0.551
FOUND
132. 0.162
FOUND
FOUND
FOUND
FOUND
FOUND
FOUND
FOUND
FOUND
17905. 1.033
FOUND
FOUND
650. 0.764
FOUND
FOUND
FOUND
FOUND
550. 0.900
FOUND
9.495
0.471
1.666
20.077
7.066
1.155
1.378
1.143
0.570
0.735
1.532
0.321
0.296
2.877
3.386
0.495
3.029
0.340
7.205
0.354
0.254
-------
111 S5# 10 C710 BENZI01NE 184 5 NOT FOUND
112 S5# 15 C715 PYRENE 202 A BB 1336 5 2225. 1.323 0.729
113 S5# 20 ARAMITE (#1) 185 5 NOT FOUND
114 S5# 25 ARAM1TE (#2) 185 5 NOT FOUND
115 S5# 30 P-DIMETHYLAHINOAZOBENZEN 120 5 NOT FOUND
116 S5# 35 3,3'-DIMETHYLBENZIDINE 212 5 NOT FOUND
117 S5# 37 KEPONE 272 5 NOT FOUND
118 S5# 40 C720 BUTYLBENZYLPHTHALAT 149 5 NOT FOUND
119 S5# 45 2-ACETYLAMINOFLUORENE 181 5 NOT FOUND
120 S5# 50 C730 BENZO(A)ANTHRACENE 228 A BB 1557 5 1896. 1.125 0.731
121 S5# 55 C725 3.3'-DICHLOROBENZIO 252 5 NOT FOUND
122 S5# 60 C740 CHRYSENE 228 A BB 1557 5 1896. 1.014 0.811
123 S5# 65 C745 BIS(2-ETHYLHEXYL)PH 149 A BB 1604 5 3863. 0.980 1.710
124 S5# 85 3-METHYLCHOLANTHRENE 268 AซBV 1832 5 454. 0.548 0.359
125 S6# 10 C760 DI-N-OCTYL PHTHALAT 149 6 NOT FOUND
126 S6# 15 C765 BENZO(B)FLUORANTHEN 252 6 NOT FOUND
127 S6* 20 7,12-DlMETHYLBENZANTHRAC 256 A BB 1742 6 376. 0.610 0.289
128 S6# 25 C770 BENZO((C)FLUORANTHEN 252 6 NOT FOUND
129 S6# 30 HEXACHLOROPHENE 196 6 NOT FOUND
130 S6# 35 C775 BENZO(A)PYRENE 252 6 NOT FOUND
131 S6# 55 C780 INDENOd ,2,3-CD)PYR 276 6 NOT FOUND
132 S6# 60 C785 DIBENZ(A,H)ANTHRACE 278 6 NOT FOUND
133 S6# 65 C790 BENZO(G,H,I)PERYLEN 276 6 NOT FOUND
-------
BNA, S LIBRARIES ANALYST: DATE:
OUANTERRA Internal Standard Check
Standard Filename: ST16980831 Analyzed: 08/31/98 12:31
| IS# 1 | IS# 2 | IS# 3 |
Standard | Area X | RT j Area X | RT j Area X | RT j
SI16980831 | 28649. | 3.78 | 100432. | 5.90 | 54347. | 9.21 |
Upper Limit j 57297. =+200) 4.28 j 200864 . =+200 j 6.40 j 1 08695 . =+200 | 9.71 j
Lower Limn j 14324.=+ 50| 3.28 j 50216.=+ 50) 5.40 j 27174.=+ 50| 8.71 j
Filename |
I II II I
1 50068103 | 31920.= 111 1 3.79 | 111468.= 110| 5.91 | 58555.= 107| 9.23
1S# 1 = CI30 1,4-OICHLOROBENZENE-D4
IS# 2 = CI40 NAPHTHALENE-OS
IS# 3 = CI50 ACENAPHTHENE-D10
* - indicates an I.S. is outside QC limit(s)
| IS# 4 | IS# 5 | IS# 6 |
Standard j Area X | RT j Area X | RT j Area X | RT j
ST16980831 | 98520. |12.08 | 62289. |17.26 | 50750. |19.83 |
Upper Limit j 197039.=+200)12.58 j 124578.=+200j17.76 | 101500.=+200)20.33 |
Lower Limit | 49260.=+ 50J11.58 j 31145.=+ 50J16.76 j 25375.=+ 50)19.33 j
Filename |
I II II II
1 30068103 | 96270.= 97)12.10 | 92258.= 148)17.29 | 85395.= 168)19.84 |
I II II II
IS# 4 = CI60 PHENANTHRENE-D10
IS# 5 = CI70 CHRYSENE-D12
IS# 6 = CI75 PERYLENE-D12
* - indicates an I.S. is outside QC limit(s)
-------
TARGET COMPOUND COMPARISON
COMPOUND: C470 2-METHYLNAPHTHALENE
RAM DATA: 30068103 #653
08/31/98 20:01
142 S2#145
91-57-6
BASE M/Z: 142
RIC: 179200.
SAMPLE: T-MM5-2
1/3SA/1ML
INST. ID: F16
CONOS.: UG/ML *1ML * 1 00Z/ 1 007. */l/3SA NA M
25.0-
12. 5-.
i
ill il i
' 1 ' 1 i '
II,,
1 1 1 1 1 1
ENHANCED DATA: 30068103
22.4-
:
i'i i i'i l i1 'i
1 -,-
1 1 . 1 1 1
|
n. ,.i. I. i.l II i.
,,'rM-
1 " " ' ' '
#653
I'i'l '" ' '
''"'
STANDARD FILE: ST16980831 #651
08/31/98 12:31
100.0-
50.0-:
:
M/Z 40 50 60
100.0-
50.0-:
0.0-:
-50.0-:
100.0-1
'* ' " 1
Or
r*>
c>
i ....i..
1 1 1 1 1 1
80
i
1
1 i1'!'' ' > '
i ' i
1 ' ' ' i ' '
100
I
I , ...I
,
i i 1 i i i i 1 i t i i ,....,.... l ......... 1 ....,..,. 1 .
BASE M/Z: 142 RIC: 43904.
i
^ Q^
1 ' 1 ' ' ' ' ซ ' l [ | | ......... | .
BASE M/Z: 142 RIC: 198144.
i i 'l
1 ' 1 ' 1 | | ,....,.... | .
120 140 150 160 180 200
i i i
r 12448.
r 11136.
r 49792.
-------
Data Reduced by: jlL/Date: ^ I I "M/^ / Data File: 30068103
Data Reviewed by: \J Date: C^\\*\ jfjf
-f ! '/ 18
QUANTERRA GC/MS TIC REPORT ( Part 1 )
Sample: T-MM5-2 1/3SA/1ML INST. ID: F16
Analyst: DAT Date Analyzed: 08/31/98 20:01
Run Factor: 3.00
Concentration
in Sample
# SCAN (UG/A) CAS #
1 171 450. 123-42-2
2-PENTANONE, 4-HYDROXY-4-METHYL- Of '
2 222 370. 111-84-2
NONANE *rv ป\{JV>~-<ซ>/
444 110. 00-00-0
UNKNOWN
S 473 99. 71899-38-2
9-EICOSYNE
5 633 180. ^.105 67^
4iฃP'TAnFr.AMF ? J^4l IMF III11 ^
6 653 240. 2471-83-2
1H-1NDENE, 1-ETHYLIDENE- (^ f
7 663 180. 1120-21-4
UNDECANE
^
8 739 220. 18344-37-1
HEPTAOECANE, 2,6,10,14-TETRAMETHYL-
10 778 200. 00-00-0
UNKNOWN
9 765 320. ^___6.2J.08-2+-8 51HV.MDQ
MCAHi, 6-ETIIYU P MCTIlfir t/ , .-
o.l 1
-------
11 821 260. 18344-37-1
HEPTAOECANE, 2,6,10,14-TETRAMETHYL- Of
12 859 320.
PENTADECANE u^
629-62-9
13 949 290.
NONADECANE Or
629-92-5
14 989 190. 54105-67-8
HEPTADECANE, 2,6-DIMETHYL- Of .
15 1037 460. 54105-67-8
HEPTADECANE. 2,6-DIMETHYL- r
629-92-5
1192 110.
NONADECANE O V ("<
629-92-5
19^266 110. 18344-37-1
' HEPTADECANE, 2,6,10,14-TETRAMETHYL-
20 1336 130. 54105-67-8
HEPTADECANE, 2,6-OIMETHYL- (3 f
1386 140.
-TERPHENYL-D14
1718-51-0
1404
NONADECANE
100.
629-92-5
-------
23 1531 110.
NONADECANE Cry
629-92-5
2(. 1587 160. 7206-19-1
3-OCTADECENE, (E)- ,
25 1609 120.
UNKNOWN
00-00-0
-------
DATA FILE: 30068103
QUANTERRA GC/MS TIC REPORT ( Part 2 )
CONCENTRATION = AREA(TIC)*CONC(IS)/AREA(IS)
0
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
FIT
954
988
905
900
940
934
971
928
944
682
965
947
965
949
971
924
966
967
959
888
976
931
945
968
755
PURITY
915
937
600
659
770
735
876
808
680
318
833
756
853
820
854
767
858
784
808
698
782
695
731
767
342
INT.
STD.
2
2
2
2
2
2
2
2
2
2
2
2
2
3
3
3
3
3
3
4
4
4
4
4
5
AMOUNT
AS ANALYZED
RT
1:54
2:28
4:56
5:15
7:02
7:15
7:22
8:13
8:30
8:39
9:07
9:33
10:33
11:00
11:32
12:24
12:27
13:15
14:04
14:51
15:24
15:36
17:01
17:39
20:07
RRT
0.206
0.267
0.535
0.570
0.763
0.787
0.799
0.890
0.922
0.937
0.989
1.035
1.143
0.909
0.953
1.025
1.029
1.096
1.164
0.860
0.892
0.903
0.985
1.021
1.013
AREA
1275650.
1058960.
311232.
280064.
524416.
681600.
517888.
615424.
912896.
556544.
750848.
919808.
825600.
541952.
1300990.
443904 .
572928.
324480.
306688.
340129.
376192.
272768.
297984.
421120.
234560.
HEIGHT
442368.
304107.
78208.
64471.
118784.
76288.
111232.
133888.
219904.
73216.
136960.
206592.
197632.
136192.
226560.
134912.
170752.
112256.
96256.
83833.
105344.
66706.
50304.
74240.
24576.
(UG/ML )
149
124
36
32
61
80
60
72
107
65
88
108
96
.865
.408
.564
.902
.609
.075
.842
.301
.248
.383
.211
.060
.992
63.383
152
51
67
37
35
42
47
34
37
53
38
.156
.916
.006
.949
.868
.894
.441
.399
.579
.107
.447
LIB
NB
NB
UK
NB
NB
NB
NB
NB
NB
UK
NB
NB
NB
NB
NB
NB
NB
NB
NB
NB
NB
NB
NB
NB
UK
LIB #
3241.
5159.
1.
39230.
37462.
8109.
11607.
42196.
19006.
1.
42196.
25997.
37465 .
37462.
37462.
15969.
37465 .
37465 .
42196.
37462.
32801.
37465.
37465 .
34410.
1.
5' " -'
o,.-i
-------
Library Search Data: 30068103 # 171
08/31/98 20:01:00 + 1:54 Cali: 30068103 # 3
Sample: T-MH5-2 1/3SA/1ML 1NST. ID: F16
Conds.: UG/ML *1ML *100%/100% *(NA/NA )/1/3SA NA M
Enhanced (S 158 2N OT)
Base m/z: 43
RIC: 323072.
6223" spectra in LIBRARYNB searched for maximum PURITY
630 matched at least 6 of the 16 largest peaks in the unknown
Rank In. Name
1 3241 2-PENTANONE, 4-HYDROXY-4-METHYL-
2 5791 1,3-D10XOLANE-2-METHANOt, 2,4-DlMETHYL-
3 3366 2-PENTANOL, 2,4-DIMETHYL-
4 3288 ACETIC ACID, 1 , 1 -DIMETHYLETHYL ESTER
5 3349 2-HEXANOL, 2-METHYL-
6 919 TERT-BUTYL HYDROPEROXIDE
7 5594 2-PROPANOL, 2-NITROSO-, ACETATE (ESTER)
8 8432 2-HEXANONE, 3-HYDROXY-3.5-DIMETHYL-
9 8425 2-HEPTANONE, 3-HYDROXY-3-METHYL-
Rank
1
2
3
4
5
6
7
8
9
Rank
1
2
3
5
6
7
8
9
Formula
C6.H12.02
C6.H12.03
C7.H16.0
C6.H12.02
C7.H16.0
C4.H10.02
C5.H9.03.N
C8.H16.02
C8.H16.02
Ret.Time
M.Wt B.Pk Purity Fit RFit
B.P.Int.
116 43
US. Par. 1
132
116
116
116
90
131
144
144
43
59
43
59
59
43
59
59
US. Par. 2
915 954
758 833
744 767
728 780
709 744
709 864
708 819
670 733
657 713
C.A.S. #
123-42-2
53951-43-2
625-06-9
540-88-5
625-23-0
75-91-2
6931-04-0
6321-14-8
13757-91-0
928
785
744
742
709
732
799
697
678
a:.
-------
1800
SAMPLE
MID LIBRARY SEARCH (LIBRARYNB) DATA:
08/31/98 20:01:00 + 1:54 CALI:
SAMPLE: T-MM5-2 1/3SA/1ML INST. ID: F16
CONDS.: UG/ML *1ML *100Z/100Z *CNA/NA >/l/3SA NA M
ENHANCED
30068103 #171 BASE M/Z: 43
30068103 # 3 RIC: 323072.
C6.H12.02
1000
M WT 116
B PK 43
RANK 1
# 3241
PUR 915
2-PENTANONE, 4-HYDROXY-4-METHYL-
C6.H12.03
1060
M WT 132
B PK 43
RANK 2
# 5791
PUR 758
,3-DIOXOLANE-2-METHANOL, 2,4-DIMETHYL-
I I
C7.H16.0
1000
M WT 116
B PK 59
RANK 3
# 3366
PUR 744
2-PENTANOL, 2,4-DIMETHYL-
M/Z
20
49
60
80
100
120
OC
I'
C"'
-------
L'ibrary Search Data: 30068103 # 222 Base m/z: 43
08/31/98 20:01:00 + 2:28 Cali: 30068103 # 3 RIC: 227328.
Sample: T-MM5-2 1/3SA/1HL INST. 10: F16
Conds.: UG/ML *1ML *100%/100% *(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
921 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 5159 NONANE
2 5151 HEPTANE, 3,4-DIMETHYL-
3 3086 HEXANE, 2,4-DIMETHYL-
4 5141 HEPTANE, 2,4-DIMETHYL-
5 19015 DECANE, 2,5,6-TRIMETHYL-
6 11607 UNDECANE
7 8085 HEPTANE, 2,4,6-TRIMETHYL-
8 19028 DECANE, 2,4,6-TRIMETHYL-
9 5144 HEPTANE, 4-ETHYL-
M.Ut B.Pk Purity Fit RFit
Rank
1
2
3
4
5
6
7
8
9
Formula
C9.H20
C9.H20
C8.H18
C9.H20
C13.H28
C11.H24
C10.H22
C13.H28
C9.H20
128
128
114
128
184
156
142
184
128
43
43
43
43
57
43
43
43
43
937
899
894
879
874
868
865
861
861
988
925
964
933
914
929
909
890
910
937
899
904
888
884
905
881
906
868
Rank
1
2
3
4
5
6
7
8
9
Ret.Time
B.P.Int.
US.Par.1
US.Par.2
C.A.S. #
111-84-2
922-28-1
589-43-5
2213-23-2
62108-23-0
1120-21-4
2613-61-8
62108-27-4
2216-32-2
-------
MID LIBRARY SEARCH (LIBRARYNB)
08/31/98 20:01:00 + 2:28
SAMPLE: T-MM5-2 1/3SA/1ML INST. ID:
CONDS.: UG/ML *1ML *100Z/100Z */l/3SA
ENHANCED
-------
Library Search Data: 30068103 tt 444 Base m/z: 43
08/31/98 20:01:00 + 4:56 Cali: 30068103 # 3 RIC: 66688.
Sample: T-MM5-2 1/3SA/1ML INST. ID: F16
Conds.: UG/ML *1ML *100%/100% *(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
463 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 19523 1-DECANOL, 2-ETHYL-
2 14793 1-UNDECENE, 4-METHYL-
3 35931 HEXADECANE. 1-CHLORO-
4 12074 1-HEPTANOL. 2-PROPYL-
5 15969 HYDROXYLAMINE, 0-DECYL-
6 19015 DECANE, 2,5,6-TRIMETHYL-
7 40866 OCTADECANE, 1-CHLORO-
8 11607 UNDECANE
9 11602 OCTANE, 2,4,6-TRIMETHYL-
Rank
1
2
3
4
5
6
7
8
9
Rank
1
2
3
4
5
6
7
8
9
Formula
C12.H26.0
C12.H24
C16.H33.CL
C10.H22.0
C10.H23.0.N
C13.H28
C18.H37.CL
C11.H24
C11.H24
Ret.Time
B.P.Int.
US.Par.1
M.Wt
186
168
260
158
173
184
288
156
156
I
B.Pk Purity Fit
57
43
57
43
43
57
57
43
57
US. Par. 2
600 905
597 909
595 824
589 928
588 929
583 916
583 816
579 957
576 939
C.A.S. it
21078-65-9
74630-39-0
4860-03-1
10042-59-8
29812-79-1
62108-23-0
3386-33-2
1120-21-4
62016-37-9
RFit
627
635
635
607
624
596
648
600
585
8f .-
., v>
-------
MID
LIBRARY SEARCH CLIBRARYNB) DATA: 30068103 # 444 BASE M/Z: 43
08/3 1/98 20:81
:00 + 4:56 CALI: 30068103 # 3 RIC: 66688.
SAMPLE: T-MM5-2 1/3SA/1ML INST. ID: FIG
CONDS. : UG/ML
*1ML *100Z/100Z */l/3SA NA M
ENHANCED (S 15B 2N 0T>
1000
SAMPLE
r
1
C12.H26.0
1000 i
M WT 186
B PK 57
RANK 1
# 19523 '
PUR 600
r
1
C12.H24
1000 1
M WT 168
B PK 43
RANK 2
# 14793 '
PUR 597
r
1
C16.H33.CL
1000
M WT 260
B PK 57
RANK 3
# 35931
PUR 595
r
: , , : . , r-l
[
||
i i .ll i 1 1 I iii. i i i . . . .
1-DECANOL, 2-ETHYL- ,,r ,Sy^~4^/
j.
1
Ill 1 1 1 1 . i .
1-UNDECENE, 4-METHYL-
4.
1
HEXADECANE, 1-CHLORO-
M/Z 40
CC
ro
o
I
1 1
II l.ill,.
L-H_ , . . . i P . - | . . 1 . 1 - -i - - i 1 - - | i - - - - i - . - -
60 80 100 120 140 160
-------
Library Search Data: 30068103 # 473 Base m/z: 43
08/31/98 20:01:00 + 5:16 Cali: 30068103 # 3 RIC: 59200.
Sample: T-MM5-2 1/3SA/1HL 1NST. ID: F16
Conds.: UG/ML *1ML *100%/100% *(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
459 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 39230 9-EICOSYNE
2 22482 2-TRIDECEN-1-OL, (E>-
3 34800 (R)-(-)-(Z)-14-MฃTHYL-8-HEXADECEN-1-OL
4 25971 OX1RANE, DOOECYL-
5 29222 (Z)6-PENTADECEN-1-OL
6 37449 OCTAOECANAL
7 36677 7-OCTADECYNE, 2-METHYL-
8 37444 OXIRANE, HEXADECYL-
9 17938 1,12-TRlDECADIENE
Rank
1
2
3
4
5
6
7
8
9
Formula
C20.H38
C13.H26.0
C17.H34.0
C14.H28.0
C15.H30.0
C18.H36.0
C19.H36
C18.H36.0
C13.H24
Rank
1
2
3
t,
5
6
7
Ret.Time
B.P.Int.
US.Par.1
M.Ut
278
198
254
212
226
268
264
268
180
B.Pk Purity Fit
81
57
55
41
67
43
81
57
55
US. Par. 2
659 900
656 854
653 850
650 918
636 869
635 828
626 889
624 808
624 876
C.A.S. #
71899-38-2
74962-98-4
30689-78-2
3234-28-4
68797-95-5
638-66-4
35354-38-2
7390-81-0
Z1964-48-7
RFit
677
662
663
650
654
677
642
667
627
-------
C13.H26.0
C17.H34.0
1368
M WT 254
B PK 55
RANK 3
# 34800 '
PUR 653
M/Z
MID LIBRARY SEARCH CLIBRARYNB)
08/31/98 20:01:00 + 5:16
SAMPLE: T-MM5-2 1/3SA/1ML INST. ID:
CONDS.: UG/ML *1ML *100Z/1007ป *
F16
NA M
DATA: 30068103 # 473
CALI: 30068103 # 3
BASE M/Z: 43
RIC: 59290.
1368 i
SAMPLE
C20.H38
1368 i
M WT 278
B PK 81
RANK 1
# 39230
PUR 659
r
r
1
1 1 ,
ill i
Ih .
ii !!. "1. . 1 I-.
9-EICOSYNE
OW
ll
ll
ll 1
-, J| r-ll , .JU-, -. , M . ^^ , _- . ^ , ^_ . ^ _^.
2-TRIDECEN-l-OL, -
Ubป
M WT 198
B PK 57
RANK 2
* 22482
PUR 656
r
lip ll II , ..
-------
Library Search Data: 30068103 # 633
08/31/98 20:01:00 + 7:02 Cali: 30068103 # 3
Sample: T-MM5-2 1/3SA/1ML INST. ID: F16
Conds.: UG/ML *1ML *100%/100X *(NA/NA )/1/3SA NA M
Enhanced (S 158 2N OT)
Base m/z: 57
RIC: 109056.
62231 spectra in LIBRARYNB searched for maximum PURITY
862 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 37462 HEPTAOECANE, 2,6-DIMETHYL-
2 22534 TRIDECANE, 7-METHYL-
3 14799 1-DECENE, 3,4-DIMETHYL-
4 15969 HYDROXYLAMINE, 0-DECYL-
5 19523 1-OECANOL, 2-ETHYl-
6 42196 HEPTADECANE, 2,6,10,14-TETRAMETHYL-
7 14751 2-UNDECENE, 5-METHYL-
8 32422 OCTANE, 1,1'-OXYBIS-
9 8539 1-PENTANOL, 4-METHYL-2-PROPYL-
Rank Formula
1
2
3
U
5
6
7
8
9
C19.H40
C14.H30
C12.H24
C10.H23.0.N
C12.H26.0
C21.H44
C12.H24
C16.H34.0
C9.H20.0
M.Wt
268
198
168
173
186
296
168
242
144
B.Pk
57
57
57
43
57
57
57
57
57
Purity
770
763
760
738
736
735
732
728
727
Fit
940
928
958
943
925
926
957
961
971
RFit
780
763
761
740
755
750
740
736
733
Rank
1
2
3
u
5
6
7
Ret.Time
B.P.Int.
US.Par.1
US.Par.2
C.A.S
54105
26730
50871
29812
21078
18344
56851
629
54004
, #
67-8
14-3
03-9
79-1
65-9
37-1
34-4
82-3
41-0
8,
-------
MID LIBRARY SEARCH CLIBRARYNB) DATA:
08/31/98 20:01:00 + 7:02 CALI:
SAMPLE: T-MM5-2 1/3SA/1ML INST. ID: F16
CONDS.: UG/ML *1ML *100Z/100Z *
-------
Library Search Data: 30068103 # 653 Base m/z: 142
08/31/98 20:01:00 + 7:16 Cali: 30068103 # 3 RIC: 43008.
Sample: T-MM5-2 1/3SA/1HL INST. ID: F16
Conds.: UG/ML *1ML *100%/100% *
-------
1866
SAMPLE
MID LIBRARY SEARCH (LIBRARYNB)
08/31/98 20:01:00 + 7:16
SAMPLE: T-MM5-2 1/3SA/1ML INST. ID:
CONDS.: UG/ML *1ML *10072/100Z */l/3SA
ENHANCED
-------
Library Search Data: 30068103 # 663
08/31/98 20:01:00 + 7:22 Call: 30068103 # 3
Sample: T-MM5-2 1/3SA/1ML INST. ID: F16
Conds.: UG/ML *1ML *100%/100% "(NA/NA )/1/3SA NA M
Enhanced (S 15B HN OT)
Base m/z: 57
RIC: 109824.
62231 spectra in LIBRARYNB searched for maximum PURITY
723 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 11607 UNDECANE
2 11602 OCTANE, 2,
3 15356 OECANE, 2,
4 19016 UNDECANE,
5 8104 OCTANE, 3,
6 19015 DECANE, 2,
7 19026 DECANE, 2,
8 19028 DECANE, 2,
9 19013 DECANE, 2,
Rank Formula
1 C11.H24
2 C11.H24
3 C12.H26
A C13.H28
5 C10.H22
6 C13.H28
7 C13.H28
8 C13.H28
9 C13.H28
Rank Ret. Time
1
2
3
t.
6
7
8
9
4,6-TRIMETHYL
4-01METHYL-
4,7-DIMETHYL-
5-DIMETHYL-
5,6-TRlMETHYL
6,8-TRIMETHYL
4,6-TRIMETHYL
5,9-TRIMETHYL
B.P.Int.
M.Ut B.Pk Purity Fit RFit
156
156
170
184
142
184
184
184
184
43
57
43
43
57
57
57
43
57
876
847
846
846
845
841
840
839
838
971
966
955
934
936
924
933
932
935
882
849
850
869
853
844
849
852
838
US.Par.1
US.Par.2
C.A.S. #
1120-21-4
62016-37-9
2801-84-5
17301-32-5
15869-93-9
62108-23-0
62108-26-3
62108-27-4
62108-22-9
-------
1266
SAMPLE
MID LIBRARY SEARCH CLIBRARYNB) DATA:
08/31/98 20:01:00 + 7:22 CALI:
SAMPLE: T-MM5-2 1/3SA/1ML INST. ID: F16
CONDS.: UG/ML *1ML *100Z/1007Z *
30068103 # 663
30068103 # 3
BASE M/Z: 57
RIC: 109824.
C11.H24
1266
M WT 156
B PK 43
RANK 1
# 11607
PUR 876
UNDECANE
r
_ . .1.
... . II
-^ \-
C11.H24
1266 I
M WT 156
B PK 57
RANK 2
# 11602
PUR 847
C12.H26
1266 i
M WT 170
B PK 43
RANK 3
# 15356
PUR 846
I
I ' i
r
iJ
OCTANE, 2,4,6-TRIMETHYL-
il
M i j i
DECANE, 2,4-DIMETHYL-
ll
_ .hi II . <
M/Z
40
80
100
120
140
160
180
OC
-------
Library Search Data: 30068103 # 739
08/31/9820:01:00+ 8:13 Cal i: 30068103 # 3
Sample: T-MM5-2 1/3SA/1ML INST. ID: F16
Conds.: UG/ML *1ML *100%/100% *(NA/NA )/1/3SA NA M
Enhanced CS 15B 2N OT)
Base m/z: 57
RIC: 131328.
62231 spectra in LIBRARYNB searched for maximum PURITY
799 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 42196 HEPTADECANE, 2,6,10, 14-TETRAMETHYL-
2 25991 DODECANE, 2,6,10-TRIMETHYL-
3 25997 PENTADECANE
4 37462 HEPTADECANE, 2,6-DIMETHYL-
5 22535 DODECANE, 4,6-DIMETHYL-
6 26001 DOOECANE, 2,7,10-TRlMETHYL-
7 22530 TETRADECANE
8 18998 UNDECANE, 3,7-DIMETHYL-
9 37465 NONADECANE
Rank
1
2
3
i.
5
6
7
8
9
Formula
C21.H44
C15.H32
C15.H32
C19.H40
C14.H30
C15.H32
C14.H30
C13.H28
C19.H40
M.Ut B.Pk Purity Fit RFit
296
212
212
268
198
212
198
184
268
57
57
57
57
57
57
43
43
57
808
804
799
792
789
782
781
779
776
928
960
941
924
941
972
916
929
904
839
809
812
825
796
792
796
781
829
Rank
1
2
3
4
5
6
7
8
9
Ret.Time
B.P.lnt.
US.Par.1
US.Par.2
C.A.S
18344
3891
629
54105
61141
74645
629
17301
629
. #
37-1
98-3
62-9
67-8
72-8
98-0
59-4
29-0
92-5
8
-------
1248 n
SAMPLE
MID LIBRARY SEARCH (LIBRARYNB)
08/31/98 20:01:00 + 8:13
SAMPLE: T-MM5-2 1/3SA/1ML INST. ID:
CONDS.: UG/ML *1ML *100Z/100Z *
DATA: 30068103 # 739
CALI: 30068103 # 3
BASE M/Z: 57
RIC: 131328.
F16
NA M
Jj
J|
C21.H44
1248
M WT 296
B PK 57
RANK 1
# 42196
PUR 808
C15.H32
1248
M WT 212
B PK 57
RANK 2
tt 25991
PUR 804
, l .i i ii*
HEPTADECANE, 2,6,10,14-TETRAMETHYL-
O f
DODECANE, 2,6,10-TRIMETHYL-
C15.H32
1248 ^
M WT 212
B PK 57
RANK 3
# 25997
PUR 799
M/Z
PENTADECANE
50
100
150
200
250
CC
>->,.
O
-------
Library Search Data: 30068103 # 765 Base m/z: 43
08/31/9820:01:00+ 8:31 Cali: 30068103* 3 RIC: 193536.
Sample: T-MM5-2 1/3SA/1ML INST. ID: F16
Conds.: UG/ML *1ML *100%/100% *(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
513 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 19006 OECANE, 6-ETHYL-2-METHYL-
2 22530 TETRADECANE
3 19007 DODECANE, 3-METHYL-
4 29249 TETRADECANE, 6,9-DIMETHYL-
5 39681 1-IOOOUNDECANE
6 42196 HEPTADECANE, 2,6,10,14-TETRAMETHYL-
7 37252 DECANE, 1-1000-
8 25996 TRIDECANE, 4,8-DlMETHYl-
9 11607 UNDECANE
Rank
1
2
3
4
5
6
7
8
9
Formula
C13.H28
C14.H30
C13.H28
C16.H34
C11.H23.I
C21.H44
C10.H21.I
C15.H32
C11.H24
M.Wt
184
198
184
226
282
296
268
212
156
B.Pk
57
43
57
57
57
57
57
57
43
Purity
680
679
662
659
656
654
654
654
652
Fit
944
942
882
852
848
914
877
918
957
RFit
680
680
662
673
660
667
657
662
652
Rank
1
2
3
4
5
6
7
8
9
Ret.Time
B.P.Int.
US.Par.1
US.Par.2
C.A.S. #
62108-21-8
629-59-4
17312-57-1
55045-13-1
4282-44-4
18344-37-1
2050-77-3
55030-62-1
1120-21-4
-------
MID LIBRARY SEARCH
08/31/98 20:01:00 + 8:31
SAMPLE: T-MM5-2 1/3SA/1ML INST. ID:
CONDS.: UG/ML *1ML S100Z/100Z *
-------
Library Search Data: 30068103 # 778 Base m/z: 141
08/31/9820:01:00+ 8:39 Cali: 30068103 * 3 RIC: 61952.
Sample: T-MM5-2 1/3SA/1HL INST. 10: F16
Conds.: UG/ML *1ML *100%/100% *(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
554 matched at least 5 of the 16 largest peaks in the unknown
Rank In. Name
1 29224 11-OOOECEN-1-OL, 2,4,6-TRlMETHYL-, (R,R,R)-
2 46107 2H-PYRAN-2-CARBOXYLIC ACID, 3,6-DIHYDRO-6-PROPOXY-, 4-(1-METHYLETHY*
3 56499 9-OCTADECENOIC ACID (Z)-, 2-(ACETYLOXY)-1-t(ACETYLOXY)METHYL]ETHYL *
4 32188 NONYLAMINE. 1-HEPTYL-
5 16353 INDAN, 1,1,6,7-TETRAMETHYL-
6 16347 1H-INDENE, 2.3-DIHYDRO-1.1,4,7-TETRAMETHYL-
7 21930 CYCLOPROPANOL, 1-(3,7-DIMETHYL-l-OCTENYL)-
8 56413 9,12-OCTADECADIENOlC ACID (Z,Z)-, 2-(ACETYLOXY)-1-[(ACETYLOXY)METHY*
9 56303 9,12,15-OCTADECATRIENOIC ACID, 2-(ACETYLOXY)-1-t(ACETYLOXY)HETHYL]E*
Rank
1
2
3
4
5
&
7
8
9
Formula
C15.H30.0
C19.H32.04
C25.H44.06
C16.H35.N
C13.H18
C13.H18
C13.H24.0
C25.H42.06
C25.H40.06
M.Ut B.Pk Purity Fit RFit
226
324
440
241
174
174
196
438
436
55
83
43
128
159
159
83
43
43
318
318
305
288
276
270
269
266
264
682
752
649
723
591
591
768
741
759
384
378
386
305
280
275
315
323
319
Rank
1
2
3
4
5
6
7
8
9
Ret.Time
B.P.lnt.
US.Par.1
US.Par.2
C.A.S. #
27829-54-5
55124-82-8
55401-63-3
24539-83-1
16204-58-3
1078-04-2
65147-72-0
55320-03-1
55320-01-9
A r-
i.O
-------
MID LIBRARY SEARCH (LIBRARYNB)
08/31/98 20:01:00 + 8:39
SAMPLE: T-MM5-2 1/3SA/1ML INST. ID:
CONDS. : UG/ML *1ซL *100Z/1002 *
F16
HA M
DATA: 30068103 # 778
CALI: 30068103 # 3
BASE M/Z: 141
RIC: 61952.
2539
SAMPLE
i
.,
i,.
ll-DODECEN-l-OL, 2,4,6-TRIMETHYL-, -
C15.H30.0
2539
M WT 226
B PK 55
RANK 1
# 29224
PUR 318
_L
C19.H32.04
2539 T
M WT 324
B PK 83
RANK 2
# 46107
PUR 318
2H-PYRAN-2-CARBOXYL 1C ACID, 3,6-DIHYDRO-6-PROPOXY-, 4-<1-METHYLETHYL)!
il. , II
.1.1 . ,
C25.H44.06
2539
M WT 440
B PK 43
RANK 3
# 56499
PUR 305
M/Z
9-OCTADECENOIC ACID (Z)-, 2-METHYLJETHYL ES!
50
|H
100
150
200
250
300
CC
-------
Library Search Data: 30068103 # 821 Base m/z: 57
08/31/98 20:01:00 + 9:08 Cati: 30068103 # 3 RIC: 128128.
Sample: T-HM5-Z 1/3SA/1ML INST. ID: F16
Conds.: UG/ML *1ML *100%/100% *(NA/NA )/1/3SA NA M
Enhanced (S 158 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
284 matched at least 8 of the 16 largest peaks in the unknown
Rank In. Name
1 42196 HEPTADECANE, 2,6,10,14-TETRAMETHYL-
2 37462 HEPTADECANE, 2,6-DIMETHYL-
3 19016 UNDECANE, 4,7-DIMETHYL-
4 18987 UNDECANE, 2,8-DIMETHYL-
5 15353 2,6-DIMETHYLDECANE
6 19022 UNDECANE, 4,8-DlMETHYL-
7 37465 NONADECANE
8 19023 DECANE, 2,6,7-TRIMETHYL-
9 19004 UNDECANE, 4,6-DlMETHYL-
Rank
1
2
3
4
5
6
7
8
9
Formula
C21.H44
C19.H40
C13.H28
C13.H28
C12.H26
C13.H28
C19.H40
C13.H28
C13.H28
Rank
1
2
3
/.
5
6
7
8
9
Ret.Time
M.Wt B.Pk Purity
Fit RFit
296
268
184
184
170
184
268
184
184
57
57
43
43
43
43
57
57
57
833
824
796
795
790
790
787
786
785
965
946
948
966
924
960
917
950
964
854
847
802
799
802
791
840
786
785
B.P.Int.
US.Par.1 US.Par.2
C.A.S. #
18344-37-1
54105-67-8
17301-32-5
17301-25-6
13150-81-7
17301-33-6
629-92-5
62108-25-2
17312-82-2
-------
1393
SAMPLE
C21.H44
1393 i
M WT 296
B PK 57
RANK 1
# 42196
PUR 833
C19.H40
1393 i
M WT 268
B PK 57
RANK 2
# 37462
PUR 824
C13.H28
1393 i
M WT 184
B PK 43
RANK 3
tt 19016
PUR 796
M/E
Oc
CT>
r
i
r
r
r
MID LIBRARY SEARCH DATA: 30068103 # 821 BASE M/Z: 57
08/31/98 20:01:00 + 9:08 CALI: 30068103 # 3 RIC: 128128.
SAMPLE: T-MM5-2 1/3SA/1ML INST. ID: F16
CONDS.: UG/ML *1ML * 100Z/1 00Z *
. .1
.1
- II -'-I- "1- - - -i - -
HEPTADECANE/ 2,6, 10,1 4-TETRAMETHYL- or %Vis>ซoซ-V
II
ll.l
HEPTADECANE , 2, 6-D IMETHYL-
ll
h
UNDECANE , 4,7-DIMETHYL-
II
50 100 150 200 250
-------
Library Search Data: 30068103 # 859 Base m/z: 57
08/31/98 20:01:00 + 9:33 Cali: 30068103 * 3 R1C: 195328.
Sample: T-MM5-2 1/3SA/1ML INST. ID: F16
Conds.: UG/ML *1ML *100%/100% *
-------
MID LIBRARY SEARCH /l/3SA NA M
ENHANCED
-------
Library Search Data: 30068103 # 949 Base m/z: 57
08/31/98 20:01:00 + 10:33 Call: 30068103 # 3 RIC: 184064.
Sample: T-MM5-2 1/3SA/1ML INST. ID: F16
Conds.: UG/ML *1ML *100%/100% "(NA/NA )/1/3SA NA M
Enhanced (S 158 2N OT)
62231 spectra in L1BRARYNB searched for maximum PURITY
338 matched at least 8 of the 16 largest peaks in the unknown
Rank In. Name
1 37465 NONADECANE
2 37462 HEPTAOECANE, 2,6-OIMETHYL-
3 25997 PENTADECANE
4 42196 HEPTADECANE, 2,6,10,14-TETRAMETHYL-
5 15969 HYOROXYLAMINE, 0-OECYL-
6 19016 UNDECANE, 4,7-DIMETHYL-
7 46161 TRICOSANE
8 25994 DOOECANE, 2,6,11-TRIMETHYL-
9 15353 2,6-DIMETHYLDECANE
Rank
1
2
3
4
5
6
7
8
9
Formula
C19.H40
C19.H40
C15.H32
C21 .H44
C10.H23.0.N
C13.H28
C23.H48
C15.H32
C12.H26
M.Wt B.
268
268
212
296
173
184
324
212
170
.Pk
57
57
57
57
43
43
43
57
43
Purity
853
830
827
823
821
806
801
793
792
Fit
965
942
967
950
967
963
904
962
927
RFit
868
855
830
844
823
806
873
795
801
Rank
1
2
3
4
5
6
7
8
9
Ret.Time
B.P.Int.
US.Par.1
US.Par.2
C.A.S
629
54105
629
18344
29812
17301
638
31295
13150
, #
92-5
67-8
62-9
37-1
79-1
32-5
67-5
56-4
81-7
8!
-------
MID LIBRARY SEARCH /l/3SA
ENHANCED
-------
Library Search Data: 30068103 # 989
08/31/98 Z0:01:00 + 11:00 Cati: 30068103 * 3
Sample: T-MM5-2 1/3SA/1ML INST. ID: F16
Conds.: UG/ML *1ML *100%/100% *(NA/NA }/1/3SA NA M
Enhanced (S 158 2N OT)
Base m/z: 57
RIC: 133376.
62231 spectra in LIBRARYNB searched for maximum PURITY
644 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 37462 HEPTADECANE, 2,6-DIMETHYL-
2 19054 UNDECANE, 2,6-DIMETHYL-
3 25996 TRIDECANE, 4,8-DIMETHYL-
4 37465 NONADECANE
5 25997 PENTADECANE
6 42196 HEPTADECANE, 2,6,10,14-TETRAMETHYL-
7 22530 TETRADECANE
8 22536 TRIDECANE, 3-METHYL-
9 29263 HEXADECANE
Rank
1
2
3
4
5
6
7
8
9
Formula
C19.H40
C13.H28
C15.H32
C19.H40
C15.H32
C21.H44
C14.H30
C14.H30
C16.H34
H.Ut B.Pk Purity Fit RFit
268
184
212
268
212
296
198
198
226
57
57
57
57
57
57
43
57
57
820
819
819
816
809
809
807
801
800
949
949
945
935
951
948
940
961
928
832
826
826
841
817
820
816
801
815
Rank
1
2
3
4
5
6
7
8
9
Ret.Time
B.P.Int.
US.Par.1 US.Par.2
C.A.S
54105
17301-
55030-
629-
629-
18344-
629-
6418-
544-
#
67-8
23-4
62-1
92-5
62-9
37-1
59-4
41-3
76-3
8r c
oi.
-------
MID LIBRARY SEARCH DATA: 30068103 # 989 BASE M/Z: 57
08/31/98 20:01:00 + 11:00 CALI: 30068103 # 3 RIC: 133376.
SAMPLE: T-MM5-2 1/3SA/1ML INST. ID: F16
CONDS.: UG/ML *1ML *108Z/100Z *
1002
SAMPLE
C19.H40
1002 i
M WT 268
B PK 57
RANK 1
ป 37462
PUR 820
C13.H28
1002 i
M WT 184
B PK 57
RANK 2
# 19054
PUR 819
C15.H32
1002 n
M WT 212
B PK 57
RANK 3
tt 25996 '
PUR 819
M/Z
r
.II
II
1 1. . ill. . -ii. . ... . . .1.. .. .. . .
HEPTADECANE, 2,6-DIMETHYL- Cr+ i^X-e^
r
1
r
II ,
Li |
UNDECANE , 2 , 6-D I METHYL-
1
il .Ii il ... . . .
TR I DECANE , 4 , 8-D I METHYL-
r
1
I
,
50
100 150 200 250
CO
cn
-------
Library Search Data: 30068103 #1037 Base m/z: 57
08/31/98 20:01:00 + 11:32 Call: 30068103 # 3 RIC: 209920.
Sample: T-MM5-2 1/3SA/1ML INST. ID: F16
Conds.: UG/ML *1ML *100%/100% *(NA/NA )/1/3SA NA M
Enhanced (S 158 2N OT)
62231 spectra in L1BRARYNB searched for maximum PURITY
840 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 37462 HEPTADECANE, 2,6-DlMETHYL-
2 42196 HEPTADECANE, 2,6, 10, 14-TETRAMETHYL-
3 37465 NONADECANE
4 26001 DODECANE, 2,7,10-TRlMETHYL-
5 25991 DOOECANE, 2,6, 10-TRIMETHYL-
6 22535 DOOECANE, 4,6-DIMETHYL-
7 37466 PENTADECANE, 2,6, 10, 14-TETRAMETHYL-
8 25994 DOOECANE, 2,6,11-TRIMETHYL-
9 42192 HEPTADECANE, 2,6, 10, 15-TETRAMETHYL-
Rank
1
2
3
4
5
6
7
8
9
Rank
1
2
3
4
5
6
7
8
9
Formula
C19.H40
C21 .H44
C19.H40
C15.H32
C15.H32
C14.K30
C19.H40
C15.H32
C21.H44
Ret. Time B.P.Int.
M.Ut
268
296
268
212
212
198
268
212
296
B.Pk
57
57
57
57
57
57
71
57
57
US. Par. 1 US. Par.
Purity Fit
854 971
815 950
807 937
805 968
803 970
800 961
796 943
786 945
782 934
.2 C.A.S. #
54105-67-8
18344-37-1
629-92-5
74645-98-0
3891-98-3
61U1-72-8
1921-70-6
31295-56-4
54833-48-6
RFit
863
831
824
809
806
801
814
795
810
-------
MID LIBRARY SEARCH (LIBRARYNB) DATA:
08/31/98 20:01:00 + 11:32 CALI:
SAMPLE: T-MM5-2 1/3SA/1ML INST. ID: F16
CONDS.: UG/ML *1ML *100Z/100Z *
-------
Library Search
08/31/98 20:01:00 + 12:24
Sample: T-MM5-2 1/3SA/1ML
Conds.: UG/ML *1ML *100%/100%
Enhanced (S 158 2N OT)
Data: 30068103 #1115
Cali: 30068103 # 3
1NST. ID: F16
*(NA/NA )/1/3SA NA M
Base m/z: 57
RIC: 109696.
62231 spectra in LIBRARYNB searched for maximum PURITY
766 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 15969 HYDROXYLAMINE, 0-DECYL-
2 37462 HEPTADECANE, 2,6-DIMETHYL-
3 22536 TRIDECANE, 3-METHYL-
4 11607 UNDECANE
5 42196 HEPTADECANE, 2,6,10,14-TETRAMETHYL-
6 19035 DOOECANE, 2-METHYL-
7 37465 NONADECANE
8 19022 UNDECANE, 4,8-DIMETHYL-
9 18987 UNDECANE, 2,8-DIMETHYL-
Rank
1
2
3
4
S
6
7
8
9
Formula
C10.H23.0.N
C19.H40
C14.H30
C11.H24
C21.H44
C13.H28
C19.H40
C13.H28
C13.H28
M.Wt B.Pk Purity Fit RFit
173
268
198
156
296
184
268
184
184
43
57
57
43
57
43
57
43
43
767
757
749
743
743
737
736
736
729
924
888
910
945
902
946
884
925
931
803
824
779
764
804
756
819
740
742
Rank
1
2
3
4
5
6
7
8
9
Ret.T ime
B.P.Int.
US.Par.1
US.Par.2
C.A.S
29812
54105
6418
1120
18344
1560
629
17301
17301
#
79-1
67-8
41-3
21-4
37-1
97-0
92-5
33-6
25-6
-------
1092 ^
SAMPLE
MID LIBRARY SEARCH (LIBRARYNB) DATA:
08/31/98 20:01:00 + 12:24 CALI:
SAMPLE: T-MM5-2 1/3SA/1ML INST. ID: F16
CONDS.: UG/ML *1ML *10072/100Z *
30068103 #1115
30068103 # 3
BASE M/Z: 57
RIC: 109696.
C10.H23.0.N
1092
M WT
B PK
173
43
RANK 1
# 15969
PUR 767
HYDROXYLAMINE, 0-DECYL-
HEPTADECANE, 2,6-DIMETHYL-
C19.H40
1092 i
M WT 268
B PK 57
RANK 2
# 37462
PUR 757
C14.H30
1092 T
M WT 198
B PK 57
RANK 3
# 22536
PUR 749
TRIDECANE, 3-METHYL-
M/Z
58
-V-
100
150
200
250
300
cc
en
-------
O O t- <-ป
O O
ro ro z -c\j*-N-oo
inin--*r'-roป-ซ-roซ-
u-cococooooooocoooco
*-ป -O O O>> N. *- 00
u- O> O O> O O- O
*- in
5! 2
*-*m-4-r\if\iป-ซ-r-ซ o
cotooococococooooo
% ro I
O* HJ ro
(/)OviA-4'COrO'ซ inOปซ
pjo-sjroroo^ojpj
<^3ป-ro^Oooeo>O'OO^
st oo -st ro >* ซ-
o in ซ- m N-
<
z
*^
g
o
ป?
.
o
L, 0)
?
o
o
11
(J O
a g
(_) UJ UJ < UJ
LLJ a a c/) o
S< < o <
t t- o H-
z a. CL a.
O UJ UJ QC UJ
u u
UJ UJ
8 8
O O
co -4- r\j oj ^o o
^* -J ro ro ro 'J
x x x x x x
ซ- - O *O
O^ o in NO
04 04
O ^
-------
MID LIBRARY SEARCH (LIBRARYNB)
08/31/98 28:01:00 + 12:27
SAMPLE! T-MM5-2 1/3SA/1ML INST. ID:
CONDS.: UG/ML *1ML *1007.x 1002 *
-------
Library Search Data: 30068103 #1192 Base m/z: 57
08/31/98 20:01:00 + 13:16 Cali: 30068103 # 3 RIC: 108288.
Sample: T-MM5-2 1/3SA/1ML INST. ID: F16
Conds.: UG/ML *1ML *100%/100% "(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
62231 spectra in L1BRARYNB searched for maximum PURITY
294 matched at least 8 of the 16 largest peaks in the unknown
Rank In. Name
1 37465 NONADECANE
2 37462 HEPTADECANE. 2,6-DlMETHYL-
3 42196 HEPTADECANE, 2,6, 10, 14-TETRAMETHYL-
4 15969 HYDROXYLAMINE, 0-DECYL-
5 25997 PENTADECANE
6 19016 UNDECANE, 4,7-DIMETHYL-
7 46161 TRICOSANE
8 19523 1-DECANOL, 2-ETHYL-
9 15353 2,6-DIMETHYLDECANE
Rank
1
2
3
4
5
6
7
8
9
Rank
1
2
3
A
5
6
7
8
9
Formula
C19.H40
C19.H40
C21.H44
C10.H23.0.N
C15.H32
C13.H28
C23.H48
C12.H26.0
C12.H26
Ret. Time B.P.Int.
M.Wt
268
268
296
173
212
184
324
186
170
US. Par. 1
B.Pk
57
57
57
43
57
43
43
57
43
US. Par
Purity Fit
784 967
762 935
754 944
748 961
741 950
735 956
735 892
726 934
724 922
.2 C.A.S. #
629-92-5
54105-67-8
18344-37-1
29812-79-1
629-62-9
17301-32-5
638-67-5
21078-65-9
13150-81-7
RFit
795
784
780
750
769
736
813
726
733
&5C
-------
1063
SAMPLE
MID LIBRARY SEARCH (LIBRARYNB) DATA:
08/31/98 20:01:00 + 13:16 CALI:
SAMPLE: T-MM5-2 1/3SA/1ML INST. ID: F16
CONDS.: UG/ML *1ML *100Z/100Z *
30068103 #1192
30068103 # 3
BASE M/Z: 57
RIC: 108288.
C19.H40
1063
M WT 268
B PK 57
RANK 1
# 37465
PUR 784
C19.H40
1063
M WT 268
B PK 57
RANK 2
tt 37462
PUR 762
C21.H44
1063 -i
M WT 296
B PK 57
RANK 3
# 42196
PUR 754
M/Z
NONADECANE
HEPTADECANE, 2,6-DIMETHYL-
1
ll
ll
. .ll . ,.l. ,ll .. , . , , T r- '
HEPTADECANE, 2,6,10,14-TETRAMETHYL-
50
100
150
200
250
CO
cn
c >
-------
Library Search Data: 30068103 #1266 Base m/z: 57
08/31/98 20:01:00 + 14:05 Call: 30068103 # 3 RIC: 91520.
Sample: T-MM5-2 1/3SA/1ML INST. ID: F16
Conds.: UG/ML ซ1ML *100%/100% *(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
883 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 42196 HEPTADECANE, 2,6,10,14-TETRAMETHYL-
2 37465 NONADECANE
3 25997 PENTADECANE
4 37462 HEPTADECANE, 2,6-DIMETHYL-
5 32058 HEXADECANE, 3-METHYL-
6 39858 E1COSANE
7 46161 TR1COSANE
8 42192 HEPTADECANE, 2,6,10,15-TETRAMETHYL-
9 49555 PENTACOSANE
Rank
1
2
3
4
5
6
7
8
9
Formula
C21 .H44
C19.H40
C15.H32
C19.H40
C17.H36
C20.H42
C23.H48
C21.H44
C25.H52
M.Ut B.Pk Purity Fit RFit
296
268
212
268
240
282
324
296
352
57
57
57
57
57
57
43
57
43
808
803
798
797
785
785
784
768
765
959
971
988
950
953
921
929
939
903
815
816
798
807
789
809
837
790
837
Rank
1
2
3
4
5
6
7
8
9
Ret.Time
B.P.lnt.
US.Par.1
US.Par.2
C.A.S.
18344-
629-
629-
54105-
6418-
112-
638-
54833-
629-
#
37-1
92-5
62-9
67-8
43-5
95-8
67-5
48-6
99-2
-------
MID LIBRARY SEARCH
08/31/98 20:01:00 + 14:05
SAMPLE: T-MM5-2 1/3SA/1ML INST. ID:
CONDS. : UG/ML *1ML * 100Z/100Z *
F16
NA M
DATA: 30068103 #1266
CALI: 30068103 # 3
BASE M/Z: 57
RIC: 91520.
1080
SAMPLE
I
C21.H44
HEPTADECANE, 2,6,10,14-TETRAMETHYL- Ov
IkJBU
M WT 296
B PK 57
RANK 1
# 42196 '
PUR 808
r
1
1
||
C19.H40
1080 i
M WT 268
B PK 57
RANK 2
# 37465
PUR 803
.1 M . i
NONADECANE
r
C15.H32
1080 i
M WT 212
B PK 57
RANK 3
# 25997
PUR 798
M/Z
.
|
II
11 111 uJ J ........
PENTADECANE
r
ll
ll
1 u ll .......
50 100 150 200 250 300
CC
-------
Library Search
08/31/98 20:01:00 + 14:52
Sample: T-MM5-2 1/3SA/1ML
Conds.: UG/ML *1ML *100%/100%
Enhanced (S 158 2N OT)
Data: 30068103 #1336
Cali: 30068103 # 3
1NST. ID: F16
*(NA/NA )/1/3SA NA M
Base m/z: 57
RIC: 80896.
62231 spectra in LIBRARYNB searched for maximum PURITY
743 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 37462 HEPTADECANE, 2,6-DIMETHYL-
2 37465 NONADECANE
3 37456 2-METHYLOCTADECANE
4 29263 HEXADECANE
5 42196 HEPTADECANE, 2,6,10,14-TETRAMETHYL-
6 46161 TRICOSANE
7 32058 HEXADECANE, 3-METHYL-
8 19523 1-DECANOL, 2-ETHYL-
9 15969 HYDROXYLAMINE, 0-DECYL-
Rank
1
2
3
A
5
6
7
8
9
Formula
C19.H40
C19.H40
C19.H40
C16.H34
C21.H44
C23.H48
C17.H36
C12.H26.0
C10.H23.0.N
M.Ut B
268
268
268
226
296
324
240
186
173
.Pk
57
57
43
57
57
43
57
57
43
Purity
698
697
697
690
688
682
674
672
672
Fit
888
954
918
942
907
907
929
949
962
RFit
727
723
722
712
710
739
693
672
675
Rank
1
2
3
4
5
6
7
8
9
Ret.Time
B.P.Int.
US.Par.1 US.Par.2
C.A.S. #
54105-67-8
629-92-5
54A-76-3
8344-37-1
638-67-5
6418-43-5
21078-65-9
29812-79-1
-------
MID LIBRARY SEARCH /l/3SA
ENHANCED
-------
Library Search Data: 30068103 #1386
08/31/98 20:01:00 + 15:25 Cali: 30068103 # 3
Sample: T-MM5-2 1/3SA/1ML 1NST. ID: F16
Conds.: UG/ML *1ML *100%/100% *
-------
MID LIBRARY SEARCH CLIBRARYNB) DATA: 30068103 #1386 BASE M/Z: 244
08/31/98 20:01:00 + 15:
25 CALI: 30068103 # 3 RIC: 87808.
SAMPLE: T-MM5-2 1/3SA/1ML INST. ID: FIG
CONDS. : UG/ML *1ML *1007./100Z * . 1.. . ..
> ' ' '/!
~~-\ o***^
. -.,. 7 -I- i-1-- --.- -41
1
C18.D14 / P-TERPHENYL-D14 /
1145 -
M WT 244
B PK 244
RANK 1
# 32801
PUR 782
/
[ V
v V ^
^ \~ -^
' ' i ' ' - ~ i * " i . - *
/
y
^
1 ! i . , f , '"M
C14.H19.02.N2.F3 PYRIDINE, l-ACETYL-l,2,3,4-TETRAHYDRO-5-n--2-PIPERI !
1145 i
M WT 304
B PK 244
RANK 2
# 43382
PUR 414
.1 . , i,
1.
C13.H16.0.FE FERROCENE, (3-HYDROXYPROPYD-
1145
M WT 244
B PK 244
RANK 3
# 32670
PUR 413
ll . , .,. i. 1.
M/Z
50
100
150
200
250
300
Or
-------
Library Search Data: 30068103 #1404 Base m/z: 57
08/31/98 20:01:00 + 15:37 Cali: 30068103 # 3 R1C: 62528.
Sample: T-MM5-2 1/3SA/1ML INST. ID: F16
Conds.: UG/ML *1ML *100X/100% *(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
62231 spectra in LI8RARYNB searched for maximum PURITY
793 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 37465 NONAOECANE
2 37462 HEPTADECANE, 2,6-DIMETHYL-
3 18985 TRIDECANE
4 25997 PENTADECANE
5 42192 HEPTADECANE, 2,6,10,15-TETRAMETHYL-
6 19016 UNDECANE, 4,7-DlMETHYl-
7 15969 HYDROXYLAMINE, 0-DECYL-
8 25994 DOOECANE, 2,6,11-TRIMETHYL-
9 22530 TETRADECANE
Rank
1
2
3
4
5
6
7
8
9
Rank
1
2
3
4
5
6
7
8
9
Formula
C19.H40
C19.H40
C13.H28
C15.H32
C21.H44
C13.H28
C10.H23.0.N
C15.H32
C14.H30
Ret. Time
M.Wt B.Pk Purity Fit RFit
B.P.lnt.
268
268
184
212
296
184
173
212
198
57
57
57
57
57
43
43
57
43
695
688
687
686
684
684
681
680
680
931
912
970
953
924
951
950
956
938
741
729
689
714
723
684
697
685
714
US.Par.1
US.Par.2
C.A.S,
629-
54105-
629-
629-
54833
17301-
29812-
31295-
629
#
92-5
67-8
50-5
62-9
48-6
32-5
79-1
56-4
59-4
-------
MID LIBRARY SEARCH (LIBRARYNB) DATA:
08/31/98 20:01:00 + 15:37 CALI:
SAMPLE: T-MM5-2 1/3SA/1ML INST. ID: F16
CONDS.: UG/ML *1ML *100Z/100Z */l/3SA NA M
ENHANCED (S 15B 2N 0T)
30068103 #1404
30068103 # 3
BASE M/Z: 57
RIC: 62528.
1149 -
SAMPLE
r
. .1
Ji j . . i.i .11 |- ... . , . .... ., . ........ , .. ... .
C19.H40 NONADECANE , sitr^s-t-sS
1149 1
M WT 268
B PK 57
RANK 1
# 37465
PUR 695
r ^"^ ป
1
C19.H40
1149 1
M WT 268
B PK 57
RANK 2
# 37462 '
PUR 688
r
||
II iJ ri ,,.,....
HEPTADECANE, 2,6-DIMETHYL-
C13.H28 TRIDECANE
1149 n
M WT 184
B PK 57
RANK 3
tt 18985
PUR 687
M/Z
r
L. j W
50
100 150 200 250 300 350 400
c
-------
Library Search Data: 30068103 #1531
08/31/98 20:01:00 + 17:02 Calf: 30068103 # 3
Sample: T-MM5-2 1/3SA/1ML INST. ID: F16
Corids.: UG/ML *1ML *100%/100% *(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
Base m/z: 57
RIC: 41152.
62231 spectra in LIBRARYMB searched for tnaxinnum PURITY
783 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 37465 NONADECANE
2 15969 HYDROXYLAM1NE, 0-DECYL-
3 37462 HEPTAOECAKE. 2,6-OlMETHYL-
4 25997 PENTADECANE
5 19523 1-DECANOL, 2-ETHYL-
6 42196 HEPTADECANE, 2,6,10,14-TETRAMETHYl-
7 19016 UNDECANE, 4,7-DIHETHYL-
8 19006 DECANE, 6-ETHYL-2-METHYL-
9 22530 TETRADECANE
Rank
1
2
3
4
5
6
7
8
9
Rank
1
2
3
5
6
r
8
9
Formula
C19.H40
C10.H23.0.N
C19.H40
C15.H32
C12.H26.0
C21.H44
C13.H28
C13.H28
C14.H30
Ret . Time
B.P.Int.
US.Par.1
M.Ut
268
173
268
212
186
296
184
184
198
B.Pk Purity Fit
57
43
57
57
57
57
43
57
43
US. Par. 2
731 945
721 957
708 924
698 949
698 929
694 948
692 953
691 948
688 935
C.A.S. #
629-92-5
29812-79-1
54105-67-8
629-62-9
21078-65-9
18344-37-1
17301-32-5
62108-21-8
629-59-4
RFit
759
723
735
726
702
715
693
697
725
-------
1098
SAMPLE
MID LIBRARY SEARCH
08/31/98 20:01:00 + 17:02
SAMPLE: T-MM5-2 1/3SA/1ML INST. ID:
CONDS.: UG/ML *1ML *10072/100Z *
F16
NA M
DATA: 30068103 #1531
CALI: 30068103 # 3
BASE M/Z: 57
RIC: 41152.
. ill . .1 M. . ...
C19.H40
1098 i
M WT 268
B PK 57
RANK 1
# 37465
PUR 731
NONADECANE
C10.H23.0.N
1098 i
M WT 173
B PK 43
RANK 2
# 15969
PUR 721
HYDROXYLAMINE, 0-DECYL-
J ., ,
C19.H40
1098 n
M WT 268
B PK 57
RANK 3
ซ 37462
PUR 708
M/Z
50
HEPTADECANE , 2 , 6-D I METHYL-
100 150 200 250 300 350 400 450
O
-------
Library Search Data: 30068103 #1587
08/31/98 20:01:00 + 17:39 Call: 30068103 * 3
Sample: T-MM5-2 1/3SA/1ML INST. ID: F16
Conds.: UG/ML *1ML *100%/100% *(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
Base m/z: 43
R1C: 68864.
62231 spectra in LIBRARYNB searched for maximum PURITY
950 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 34410 3-OCTADECENE, (E)-
2 39515 9-EICOSENE, (E)-
3 39516 5-EICOSENE, (E>-
4 34418 9-OCTADECENE, (E>-
5 34411 5-OCTADECENE, (E)-
6 31653 1-HEPTADECENE
7 39517 3-E1COSENE, (E)-
8 28772 7-HEXADECENE, (Z)-
9 32420 1-HEXADECANOL
Rank
1
2
3
4
5
6
7
8
9
Rank
1
2
3
4
5
6
7
8
9
Formula
C18.H36
C20.H40
C20.H40
C18.H36
C18.H36
C17.H34
C20.H40
C16.H32
C16.H34.0
Ret.Time
M.Wt B.Pk Purity
252
280
280
252
252
238
280
224
242
69
55
55
55
55
55
57
55
55
B.P.lnt.
US.Par.1
US.Par.2
i ty Fit
767 968
766 979
765 978
763 963
762 962
756 970
755 982
749 945
748 973
C.A.S. #
7206-19-1
74685-29-3
74685-30-6
7206-25-9
7206-21-5
6765-39-5
74685-33-9
35507-09-6
36653-82-4
RFit
782
770
771
777
777
770
760
766
758
fc1
-------
MID LIBRARY SEARCH (LIBRARYNB) DATA:
08/31/98 20:01:90 + 17:39 CALI:
SAMPLE: T-MM5-2 1/3SA/1ML INST. ID: F16
CONDS.: UG/ML *1ML *100Z/100?: */l/3SA NA M
ENHANCED - _ . _
1098 1
M WT 252
B PK 69
RANK 1
# 34410 "
PUR 767
of* v>ปv^
C20.H40
1098 ]
M WT 280
B PK 55
RANK 2
# 39515 '
PUR 766
C20.H40
1098 -i
M WT 280
B PK 55
RANK 3
# 39516
PUR 765
M/Z
'
1
__J
1
9-EICOSENE, -
1
1
1 -
5-EICOSENE,
-------
Library Search Data: 30068103 #1809 Base m/z: 43
08/31/98 20:01:00 + 20:07 Cali: 30068103 # 3 RIC: 20672.
Sample: T-MM5-2 1/3SA/1ML 1NST. ID: F16
Conds.: UG/ML *1ML *100%/100% *(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
761 matched at least 5 of the 16 largest peaks in the unknown
Rank In. Name
1 52672 SI LANE. TRICHLOROOCTADECYL-
2 51637 CHOLESTANE
3 31486 ACETAMIDE, N-METHYL-N-[4-[4-METHOXY-1-HEXAHYDROPYRIDYL]-2-BUTYNYL]-
4 40940 PREGNANE
5 54646 SQUALENE
6 50599 PENTALENE, OCTAHYDRO-1-(2-OCTYLDฃCYL>-
7 46251 DODECANE, 1,2-DIBROMO-
8 40165 HEXADECANOIC ACID, 2-0X0-, METHYL ESTER
9 48865 5.ALPHA.-ANDROSTAN-3.BETA.-OL, 4,4-DlMETHYL-, ACETATE
Rank
1
2
3
4
5
6
7
8
9
Rank
1
2
3
4
5
6
7
8
9
Formula
C18.H37.CL3.SI
C27.H48
C13.H22.02.N2
C21.H36
C30.H50
C26.H50
C12.H24.BR2
C17.H32.03
C23.H38.02
Ret. Time
M.Ut
386
372
238
288
410
362
326
284
346
B.Pk
57
43
43
55
69
43
41
57
43
Purity
342
316
305
300
294
292
290
286
283
Fit
755
625
813
677
687
863
770
817
672
RFit
375
402
348
376
347
320
345
337
393
B.P.Int.
US.Par.1 US.Par.2
C.A.S. #
112-04-9
481-21-0
481-26-5
7683-64-9
55401-65-5
55334-42-4
55836-30-1
7761-08-2
-------
MID LIBRARY SEARCH DATA: 30068103 #1809 BASE M/Z: 43
08/31/98 20:01:00 + 20:07 CALI: 30068103 # 3 RIC: 20672.
SAMPLE: T-MM5-2 1/3SA/1ML INST. ID: F16
CONDS.: UG/ML *1ML * 100Z/1 00Z */l/3SA NA M
ENHANCED
1000
SAMPLE
1 ll "III ll II i ll i N-i In.' Ji . ..! I- - ]. ..I.. .Hi ..i.i . . .. . . ,
C18.H37.CL3.SI SILANE, TR I CHLOROOCT ADECYL- ''
1000 n
M WT 386
B PK 57
RANK 1
# 52672
PUR 342
1
1 II ll 1 ,, II . Hi II, ii ,,
C27.H48 CHOLESTANE
1000 -.
M WT 372
B PK 43
RANK 2
# 51637
PUR 316
II 1 1 III ll 1 ll, ... , i .1. ... I. I,
C 1 3. H22. 02. N2 ACETAM I DE , N-METHYL-N- C 4- [ 4-METHOXY- 1 -HEXAHYDROPYR I DYL ] -2-BUTYNYL ] -
1000
M WT 238
B PK 43
RANK 3
# 31486 "
PUR 305
ill .1
ll| |l ll I, . . .
M/Z
50
100
150
200
250
300
350
400
-------
TIC SELECTION REPORT
DATA FILE: 30068103
THE FOLLOWING PEAKS WERE REJECTED BECAUSE
AT LEAST 40 % OF THEIR SIZE WAS ACCOUNTED FOR BY
TARGET COMPOUNDS ELUTING WITHIN 4 SCANS OF THE
PEAK TOP.
SCAN
SIZE
AMOUNT
:= === =
199
310
341
398
402
422
531
724
830
1088
1554
1785
===========
205984.
455754.
148864.
55273.
58805.
191616.
377600.
383252.
340480.
342016.
317184.
244032.
24.199
53.543
17.489
6.494
6.908
22.511
44.361
45.025
40.000
40.000
40.000
40.000
TOTAL NUMBER OF UNIDENTIFIED PEAKS WITH SIZE
GREATER THAN 10 % OF THE CLOSEST INTERNAL STANDARD
THAT DOES NOT HAVE INTERFERENCES = 121
INTERNAL STANDARDS THAT HAVE RIC SIZE LESS THAN
50 % OR GREATER THAN 200 % OF THE ESTIMATED RIC SIZE
ARE CONSIDERED TO HAVE INTERFERENCES AND WILL NOT BE USED
FOR OUANTITATION.
PERCENT OF
ESTIMATED
# INTERNAL STANDARD RIC SIZE RIC SIZE SCAN
1 CI40 NAPHTHALENE-08
2 CI50 ACENAPHTHENE-D10
3 CI60 PHENANTHRENE-D10
4 CI70 CHRYSENE-012
5 CI75 PERYLENE-D12
377600.
340480.
342016.
317184.
244032.
212 *
162
156
140
106
531
830
1088
1554
1785
* INDICATES INTERFERENCE
SIZE = AREA
c, -
o *
-------
QUANTERRA GC/MS
Target Compound Data Summary Sheet
Sample: T-MM5-2 1/3SA/1ML
Client: PACIFI
Analyst: DAT Instrument ID: F16
Quan List Threshold: 0.95
INST. ID:
Data File: 300681RI03
Std Id: ST16980902
F16
Date Analyzed: 09/02/98 19:59
Run Factor: 3.00
Surrogate Vol.: 1.00
Surrogate
Surrogate Spike Recoveries
8270-G, LIMS 10/10/96
Surrogate Amount (ug)
Spiked Measured
% Recovery
Measured QC limits
CS20 NITROBENZENE-05 50.00
CS25 2-FLUOROBIPHENY 50.00
CS30 TERPHENYL-D14 50.00
CS45 PHENOL-D5 100.0
CS50 2-FLUOROPHENOL 100.0
CS55 2,4,6-TRIBROMOP 100.0
40
53
39
64
58
45
.80
.80
.50
.50
.30
.00
81
108
79
64
58
45
.6
.
.0
.5
.3
.0 *
45
62
58
43
36
58
107
110
135
130
111
131
Target Compounds: SAP9
Parameter
CS70 2-CHLOROPHENOL-D4
CS75 1,2-DICHLOROBNZN-D4
HEXACHLOROBENZENE-Cl3
C310 N-NITROSODIMETHYLAMINE
PYRIDINE
2-PICOLINE
N-NITROSOMETHYLETHYLAMINE
METHYLMETHANE SUL FONATE
N-NITROSODIETHYLAMINE
ETHYLMETHANE SULFONATE
PENTACHLOROETHANE
C320 ANILINE
C315 PHENOL
C325 BIS(2-CHLOROETHYL)ETHER
C330 2-CHLOROPHENOL
C335 1,3-DICHLOROBENZENE
C340 1,4-DICHLOROBENZENE
C345 BENZYL ALCOHOL
C350 1,2-DICHLOROBENZENE
C355 2-METHYLPHENOL
C360 2,2'-OXYBIS(l-CLPROPAN)
C361 ACETOPHENONE
N-NITROSOPYRROLIDINE
N-NITROSOMORPHOLINE
3-METHYL PHENOL
C365 4-METHYLPHENOL
C370 N-NITROSO-DI-N-
O-TOLUIDINE
C375 HEXACHLOROETHANE
Scan Result
4 ND
-D4 342 130.
ND
LAMINE ND
ND
ND
MINE ND
(E ND
ND
'E ND
ND
ND
ND
li ) ETHER ND
ND
;ENE ND
;ENE ND
ND
;ENE ND
ND
,PROPAN) ND
ND
ND
ND
ND
ND
'ROPYLAM ND
ND
! ND
Units
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
Reporting
Limit
30.0
30.0
30.0
30.0
60.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
&7G
Reviewed by:
-------
QUANTERRA GC/MS
Target Compound Data Summary Sheet
Data File: 300681RI03
Std Id: ST16980902
Sample: T-MM5-2 1/3SA/1ML INST. ID: F16
Client: PACIFI Date Analyzed: 09/02/98 19:59
Analyst: DAT Instrument ID: F16 Run Factor: 3.00
Quan List Threshold: 0.95 Surrogate Vol.: 1.00
Parameter
Target Compounds: SAP9
Scan Result Units
C410 NITROBENZENE
N-NITROSOPIPERIDINE
C415 ISOPHORONE
C420 2-NITROPHENOL
C425 2,4-DIMETHYLPHENOL
C435 BIS(2-CHLOROETHOXY)METH
C440 2,4-DICHLOROPHENOL
C430 BENZOIC ACID
AA-DIMETHYLPHENETHYLAMINE
C445 1,2,4-TRICHLOROBENZENE
C450 NAPHTHALENE
C455 4-CHLOROANALINE
2,6-DICHLOROPHENOL
HEXACHLOROPROPENE
C460 HEXACHLOROBUTADIENE
P-PHENYLENE DLAMINE
N-NITROSODI-N-BUTYLAMINE
C465 4-CHLORO-3-METHYLPHENO
SAFROLE
C470 2-METHYLNAPHTHALENE
1,2,4,5-TETRACHLOROBENZENE
ISOSAFROLE (#1)
C510 HEXACHLOROCYCLOPENTADI
C515 2,4,6-TRICHLOROPHENOL
C520 2,4,5-TRICHLOROPHENOL
ISOSAFROLE (#2)
C525 2-CHLORONAPHTHALENE
1-CHLORONAPHTHALENE
C530 2-NITROANALINE
1,4-NAPHTHOQUINONE
C535 DIMETHYLPHTHALATE
1,3-DINITROBENZENE
C540 ACENAPHTHYLENE
C543 2,6-DINITROTOLUENE
C545 3-NITROANILINE
C550 ACENAPHTHENE
C555 2,4-DINITROPHENOL
C565 DIBENZOFURAN
C560 4-NITROPHENOL
P ENTACHLOROBENZENE
C570 2,4-DINITROTOLUENE
1-NAPHTHYLAMINE
2-NAPHTHYLAMINE
2,3,4,6-TETRACHLOROPHENOL
654
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
60.
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
Reporting
Limit
30.0
30.0
30.0
30.0
30.0
30.0
30.0
150.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
60.0
30.0
30.0
30.0
60.0
30.0
15.0
150.0
30.0
30.0
30.0
30.0
30.0
150.0
30.0
150.0
30.0
150.0
30.0
30.0
30.0
30.0
60.0
-------
QUANTERRA GC/MS
Target Compound Data Summary Sheet
Sample: T-MM5-2 1/3SA/1ML
Client: PACIFI
Analyst: DAT Instrument ID: F16
Quan List Threshold: 0.95
INST. ID:
Data File: 300681RI03
Std Id: ST16980902
F16
Date Analyzed: 09/02/98 19:59
Run Factor: 3.00
Surrogate Vol.: 1.00
Parameter
Target Compounds: SAP9
Scan Result
C580 DIETHYLPHTHALATE
C590 FLUORENE
C585 4-CHLOROPHENYL-PHENYLE
5-NITRO-0-TOLUIDINE
C595 4-NITROANALINE
C610 4,6-DINITRO-2-METHYLPH
C615 N-NITROSODIPHENYLAMINE
C620 AZOBENZENE
SYM-TRINITROBENZENE
C625 4-BROMOPHENYL-PHENYLET
PHENACETIN
DIALLATE 234
C630 HEXACHLOROBENZENE
4-AMINOBIPHENYL
C635 PENTACHLOROPHENOL
PRONAMIDE
PENTACHLORONITROBENZENE
C640 PHENANTHRENE
C645 ANTHRACENE
2SECBUTYL-4,6-DINITROPHENOL
C647 CARBAZOLE
C650 DI-N-BUTYLPHTHALATE
4-NITROQUINOLINE-1-OXIDE
METHAPYRILENE
ISODRIN
C655 FLUORANTHENE
CHLOROB ENZILATE
C710 BENZIDINE
C715 PYRENE
ARAMITE (#1)
ARAMITE (#2)
P-DIMETHYLAMINOAZOBENZENE
3,3'-DIMETHYLBENZIDINE
KEPONE
C720 BUTYLBENZYLPHTHALATE
2 -ACETYLAMINOFLUORENE
C730 BENZO(A)ANTHRACENE
C725 3,3'-DICHLOROBENZIDINE
C740 CHRYSENE
C745 BIS(2-ETHYLHEXYL)PHTHA
3-METHYLCHOLANTHRENE
C760 DI-N-OCTYL PHTHALATE
C765 BENZO(B)FLUORANTHENE
7,12-DIMETHYLBENZANTHRACENE
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Units
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
Reporting
Limit
30.0
30.0
30.0
30.0
150.0
150.0
30.0
30.0
30.0
30.0
30.0
30. 0
30.0
30.0
150.0
30. 0
150.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
300 .0
30.0
30.0
30 .0
30.0
30. 0
150 . 0
30.0
30.0
30.0
60.0
30.0
30.0
30.0
30.0
30.0
30.0
. c
-------
QUANTERRA GC/MS
Target Compound Data Summary Sheet
Sample: T-MM5-2 1/3SA/1ML
Client: PACIFI
Analyst: DAT Instrument ID: F16
Quan List Threshold: 0.95
INST. ID:
Data File: 300681RI03
Std Id: ST16980902
F16
Date Analyzed: 09/02/98 19:59
Run Factor: 3.00
Surrogate Vol.: 1.00
Parameter
Target Compounds: SAP9
Scan Result
C770 BENZO(K)FLUORANTHENE
HEXACHLOROPHENE
C775 BENZO(A)PYRENE
C780 INDENO(1,2,3-CD)PYRENE
C785 DIBENZ(A,H)ANTHRACENE
C790 BENZO(G,H,I)PERYLENE
ND
ND
ND
ND
ND
ND
Units
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
Reporting
Limit
30.0
30.0
30.0
30.0
30.0
30. 0
-------
DATA FROM FILE: 300681R103 SCANS 94 TO 1204 ACQUIRED: 09/02/98 19:59:00
CALI: 300681RI03 #3
SAMPLE: T-MM5-2 1/3SA/1ML INST. ID: FIG
CONDS.: UG/ML *1ML *100Z/100Z */l/3SA NA M
I
200 _
2:13
400 _
4:27
G00 _
6:40
800 _
8:54
1000 _
11:07
fffl J
r CS50 2-FLUOROPHENOL
112SS1#02
CI30 1.4-DICHLOROBENZENE-D4 152IS1* 01
' CS20 NITROBENZENE-05
TC
CI40 NAPHTHALENE-08
TCS25 2-FLUOROBIPHENYL
TC
'CI50 ACENAPHTHENE-D10
[TC
H60 PHENANTHRENE-D10
82SS2* 02
136IS2* 01
172SS3# 03
164IS3# 01
188IS4tt 01
J
100.0Z < 3969020.)
367-12-4
3855-82-1
4165-60-0
1146-65-2
321-60-8
15067-26-2
1517-22-2
CO
CD
O
-------
DATA FROM FILE: 300681RI03 SCANS 1204 TO 2158 ACQUIRED: 09x02/98 19:59:00
CALI: 300681RI03 #3
SAMPLE: T-MM5-2 1/3SA/1ML INST. ID: F16
CONDS.: UG/ML *1ML *100Z/100Z *
-------
STANDARD USED FOR THIS REPORT IS ST16980902
REPORT PRINTED: 9/03/98 12:47:25
ADDITIONAL STANDARD USED FOR THIS REPORT IS: ST16980902A
QUANTERRA QUANTITATION SUMMARY
File: 300681RI03
Sample: T-MM5-2
Analyst: DAT
1/3SA/1ML INST. ID: F16
Instrument Id: F16 Analyzed: 09/02/98 19:59
Compounds with amounts less than 0.20 reported as NOT FOUND
Library
No Entry Name
Mass Meth Scan Ref
Units: UG/ML
Area RRF(L) Amount
1 Sift 1 CI30 1,4-DICHLOROBENZENE 152 A BV
2 S2# 1 CI40 NAPHTHALENE-D8
3 S3# 1 CI50 ACENAPHTHENE-D10
4 S4ft 1 CI60 PHENANTHRENE-D10
5 S5ft 1 CI70 CHRYSENE-D12
6 S6# 1 CI75 PERYLENE-D12
7 S2# 2 CS20 NITROBENZENE-D5
8 S3# 3 CS25 2-FLUOROBIPHENYL
9 S5# 2 CS30 TERPHENYL-D14
10 Sift 3 CS45 PHENOL-D5
11 Sift 2 CS50 2-FLUOROPHENOL
12 S3# 2 CS55 2,4,6-TRIBROMOPHENO
13 Sift 5CS70 2-CHLOROPHENOL-D4
14 Sl# 6 CS75 1,2-DICHLOROBNZN-D4
15 S4# 4 HEXACHLOROBENZENE-C13
16 Sift 15 C310 N-NITROSODIMETHYLAM
17 Sift 20 PYRIDINE
18 Sift 30 2-PICOLINE
19 Sift 40 N-NITROSOMETHYLETHYLAMIN
20 Sift 60 METHYLMETHANESULFONATE
21 Sift 70 N-NITROSODIETHYLAMINE
22 Sift 85 ETHYLMETHANE SULFONATE
23 Sift 95 PENTACHLOROETHANE
24 SlftlOO C320 ANILINE
25 SlftlOS C315 PHENOL
26 SlftllO C325 BIS(2-CHLOROETHYL)E
27 SlftllS C330 2-CHLOROPHENOL
28 Slttl25 C335 1,3-DICHLOROBENZENE
29 SlftlSO C340 1,4-DICHLOROBENZENE
30 Sl#145 C345 BENZYL ALCOHOL
31 Sl#150 C350 1,2-DICHLOROBENZENE
32 Sl#160 C355 2-METHYLPHENOL
33 Sl#165 C360 2,2'-OXYBIS(1-CLPRO
34 Slftl70 C361 ACETOPHENONE
35 Sl#175 N-NITROSOPYRROLIDINE
36 SlftlSO N-NITROSOMORPHOLINE
37 Sl#182 3-METHYL PHENOL
38 Slftl85 C365 4-METHYLPHENOL
39 Sl#190 C370 N-NITROSO-DI-N-PROP
40 Slftl95 0-TOLUIDINE
41 Sl#200 C375 HEXACHLOROETHANE
42 S2ft 10 C410 NITROBENZENE
43 S2# 15 N-NITROSOPIPERIDINE
44 S2tt 20 C415 ISOPHORONE
45 S2# 25 C420 2-NITROPHENOL
152
136
164
188
240
264
82
172
244
99
112
330
132
152
294
74
79
93
42
80
102
79
117
93
94
93
128
146
146
108
146
108
45
105
100
56
108
108
70
106
117
77
42
82
139
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
BV
BB
BB
BB
BB
BB
BV
VB
BB
BV
BB
BB
BV
VB
BB
VB
VB
BB
BB
BB
A*VB
A
A
A
A
A
W
VB
BB
VB
BB
342 1
531 2
831 3
1089 4
1555 5
1786 6
423 2
725 3
1386 5
312 1
200 1
973 3
1 NOT
342 1
4 NOT
1 NOT
1 NOT
1 NOT
1 NOT
1 NOT
1 NOT
1 NOT
307 1
1 NOT
313 1
321 1
321 1
1 NOT
1 NOT
373 1
1 NOT
1 NOT
395 1
402 1
403 1
411 1
1 NOT
1 NOT
404 1
1 NOT
1 NOT
424 2
2 NOT
467 2
473 2
27571.
95690.
49039.
81651.
77811.
72812.
45877.
81379.
76441.
90022.
55021.
13000.
FOUND
27571.
FOUND .
FOUND
FOUND
FOUND
FOUND
FOUND
FOUND
FOUND
448.
FOUND
10332.
808.
310.
FOUND
FOUND
4387.
FOUND
FOUND
3495.
8684.
350.
2422.
FOUND
FOUND
1369.
FOUND
FOUND
1347.
FOUND
449.
817.
1.
1.
1.
1.
1.
1.
0.
1.
0.
2 .
1.
0.
0 .
0.
1.
1.
1.
0.
2,
1
0
0
0
0
0
0
000
000
000
000
000
000
470
234
995
025
368
236
920
602
968
368
497
,854
.539
.934
.553
.821
. 906
.445
.741
.213
40.
40.
40.
40.
40.
40.
40.
53.
39.
64.
58.
44.
43.
1
7
0
0
7
1
6
0
4
2
1
0
1
000
000
000
000
000
000
841
778
485
480
341
998
476
.081
.617
.857
.300
.449
.997
.'515
.918
.281
.192
.266
.253
.600
-------
46 S2# 30 C425 2,4-DIMETHYLPHENOL 107 A BB 501 2 737. 0.330 0.934
47 S2# 35 C435 BIS(2-CHLOROETHOXY) 93 2 NOT FOUND
48 S2# 40 C440 2,4-DICHLOROPHENOL 162 A BB 520 2 340. 0.308 0.462
49 S2# 45 C430 BENZOIC ACID 122 A BB 543 2 6945. 0.276 10.527
< -
O
-------
50 S2# 50 AA-DIMETHYLPHENETHYLAMIN
51 S2# 55 C445 1,2,4-TRICHLOROBENZ
52 S2# 60 C450 NAPHTHALENE
53 S2# 80 C455 4-CHLOROANALINE
54 S2# 85 2,6-DICHLOROPHENOL
55 S2# 90 HEXACHLOROPROPENE
56 S2# 95 C460 HEXACHLOROBUTADIENE
57 S2#115 P-PHENYLENE DIAMINE
58 S2#120 N-NITROSODI-N-BUTYLAMINE
59 S2#130 C465 4-CHLORO-3-METHYLPH
60 S2#140 SAFROLE
61 S2#145 C470 2-METHYLNAPHTHALENE
62 S3# 10 1,2,4,5-TETRACHLOROBENZE
63 S3# 15 ISOSAFROLE (#1)
64 S3# 20 C510 HEXACHLOROCYCLOPENT
65 S3# 25 C515 2,4,6-TRICHLOROPHEN
66 S3# 30 C520 2,4,5-TRICHLOROPHEN
67 S3# 35 ISOSAFROLE (#2)
68 S3# 40 C525 2-CHLORONAPHTHALENE
69 S3# 42 1-CHLORONAPHTHALEN
70 S3# 45 C530 2-NITROANALINE
71 S3# 50 1,4-NAPHTHOQUINONE
72 S3# 55 C535 DIMETHYLPHTHALATE
73 S3# 60 1,3-DINITROBENZENE
74 S3# 65 C540 ACENAPHTHYLENE
75 S3# 70 C543 2,6-DINITROTOLUENE
76 S3# 75 C545 3-NITROANILINE
77 S3# 80 C550 ACENAPHTHENE
78 S3# 85 C555 2,4-DINITROPHENOL
79 S3# 90 C565 DIBENZOFURAN
80 S3# 95 C560 4-NITROPHENOL
81 S3#100 PENTACHLOROBENZENE
82 S3#105 C570 2,4-DINITROTOLUENE
83 S3#110 1-NAPHTHYLAMINE
84 S3#115 2-NAPHTHYLAMINE
85 S3#120 2,3,4,6-TETRACHLOROPHENO
86 S3#130 C580 DIETHYLPHTHALATE
87 S3#135 C590 FLUORENE
88 S3#140 C585 4-CHLOROPHENYL-PHEN
89 S3#145 5-NITRO-O-TOLUIDINE
90 S3#150 C595 4-NITROANALINE
91 S4# 10 C610 4,6-DINITRO-2-METHY
92 S4# 15 C615 N-NITROSODIPHENYLAM
93 S4# 20 C620 AZOBENZENE
94 S4# 25 SYM-TRINITROBENZENE
95 S4# 30 C625 4-BROMOPHENYL-PHENY
96 S4# 35 PHENACETIN
97 S4# 37 DIALLATE
98 S4# 40 C630 HEXACHLOROBENZENE
99 S4# 45 4-AMINOBIPHENYL
100 S4# 50 C635 PENTACHLOROPHENOL
101 S4# 55 PRONAMIDE
102 S4# 60 PENTACHLORONITROBENZENE
103 S4# 65 C640 PHENANTHRENE
104 S4# 70 C645 ANTHRACENE
105 S4ft 75 2SECBUTYL-4,6-DINITROPHE
106 S4# 80 C647 CARBAZOLE
107 S4# 85 C650 DI-N-BUTYLPHTHALATE
108 S4#100 4-NITROQUINOLINE-1-OXIDE
109 S4#105 METHAPYRILENE
110 S4#106 ISODRIN
58
180
128
127
162
213
225
108
84
107
162
142
214
162
237
196
196
104
162
162
65
158
163
168
152
165
138
153
184
168
109
250
165
143
143
232
149
166
204
152
138
198
169
77
75
248
108
234
284
169
266
173
237
178
178
211
167
149
190
58
193
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
BB
BV
BB
BB
VB
BB
BV
BB
BB
BB
BV
VB
BB
BB
BB
BB
VB
W
BV
BB
BB
BB
BB
BB
707 2
2 NOT
534 2
557 2
553 2
2 NOT
2 NOT
2 NOT
620 2
2 NOT
650 2
654 2
3 NOT
699 3
3 NOT
3 NOT
3 NOT
3 NOT
3 NOT
3 NOT
766 3
3 NOT
3 NOT
3 NOT
3 NOT
3 NOT
3 NOT
836 3
860 3
868 3
895 3
3 NOT
883 3
3 NOT
3 NOT
3 NOT
3 NOT
928 3
941 3
943 3
3 NOT
954 4
960 4
4 NOT
4 NOT
4 NOT
4 NOT
4 NOT
4 NOT
1078 4
1068 4
4 NOT
1066 4
1093 4
4 NOT
4 NOT
1150 4
4 NOT
4 NOT
4 NOT
4 NOT
3330.
FOUND
23287.
540.
453.
FOUND
FOUND
FOUND
1528.
FOUND
808.
35943.
FOUND
481.
FOUND
FOUND
FOUND
FOUND
FOUND
FOUND
848.
FOUND
FOUND
FOUND
FOUND
FOUND
FOUND
2115.
386.
1281.
788.
FOUND
553.
FOUND
FOUND
FOUND
FOUND
4501.
161.
1742.
FOUND
178.
4922.
FOUND
FOUND
FOUND
FOUND
FOUND
FOUND
2317.
242.
FOUND
216.
14817.
FOUND
FOUND
482.
FOUND
FOUND
FOUND
FOUND
1.
1.
0.
0.
0.
0.
0.
0.
0.
1.
0 .
1.
0.
0.
1.
0.
0.
0 .
0 .
0.
0.
0.
1.
0.
285
022
454
257
213
248
751
044
502
159
189
669
173
397
298
613
356
132
551
609
155
080
033
.764
1
9
0
0
2
1
19
8
1
1
1
0
3
1
2
0
3
0
4
1
0
1
7
0
.083
.523
.498
.736
.997
.363
.999
.988
.378
.489
.663
.626
.723
.136
.829
.214
.998
.662
.378
.864
.765
.317
.030
.309
-------
Ill S4#110 C655 FLUORANTHENE 202 A BB
112 S4#120 CHLOROBENZILATE 139
113 S5# 10 C710 BENZIDINE 184
114 S5tt 15 C715 PYRENE 202 A BB
115 S5# 20 ARAMITE (#1) 185
116 S5# 25 ARAMITE (#2) 185
117 S5tt 30 P-DIMETHYLAMINOAZOBENZEN 120
118 S5# 35 3,3'-DIMETHYLBENZIDINE 212 A BV
119 S5# 37 KEPONE 272
120 S5# 40 C720 BUTYLBENZYLPHTHALAT 149
121 S5tt 45 2-ACETYLAMINOFLUORENE 181
122 S5# 50 C730 BENZO(A)ANTHRACENE 228 A BB
123 S5# 55 C725 3,3'-DICHLOROBENZID 252
124 S5# 60 C740 CHRYSENE 228 A BB
125 S5# 65 C745 BIS(2-ETHYLHEXYL)PH 149 A BB
126 S5# 85 3-METHYLCHOLANTHRENE 268 A*BB
127 S6# 10 C760 DI-N-OCTYL PHTHALAT 149
128 S6ft 15 C765 BENZO(B)FLUORANTHEN 252
129 S6# 20 7,12-DIMETHYLBENZANTHRAC 256 A BB
130 S6tt 25 C770 BENZO(K)FLUORANTHEN 252
131 S6# 30 HEXACHLOROPHENE 196
132 S6# 35 C775 BENZO(A)PYRENE 252
133 S6# 55 C780 INDENO(1,2,3-CD)PYR 276
134 S6tt 60 C785 DIBENZ(A,H)ANTHRACE 278
135 S6tt 65 C790 BENZO(G,H,I)PERYLEN 276
1301 4
4 NOT
5 NOT
1337 5
5 NOT
5 NOT
5 NOT
1474 5
5 NOT
5 NOT
5 NOT
1558 5
5 NOT
1558 5
1605 5
1841 5
6 NOT
6 NOT
1743 6
6 NOT
NOT
NOT
NOT
NOT
6
6
6
6
6
NOT
404.
FOUND
FOUND
2218.
FOUND
FOUND
FOUND
510.
FOUND
FOUND
FOUND
1798.
FOUND
1799.
3055.
287.
FOUND
FOUND
337,
FOUND
FOUND
FOUND
FOUND
FOUND
FOUND
0.900
1.323
0.418
1.125
1.014
0.980
0.548
0.610
0.220
0.862
0.628
0.822
0.912
1.603
0.270
0.303
-------
BNA, S LIBRARIES ANALYST: DATE:
QUANTERRA Internal Standard Check
Standard Filename: ST16980902 Analyzed: 09/02/98 14:53
| IS# 1 | IS# 2 | IStt 3 |
Standard j Area % | RT j Area % | RT j Area % | RT j
ST16980902 | 23319. | 3.78 | 79260. | 5.91 | 43605. | 9.22 |
Upper Limit j 46638.=+200J 4.28 j 158519.=+200| 6.41 | 87211.=+200| 9.72 |
Lower Limit j 11659.=+ 50J 3.28 j 39630.=+ 50| 5.41 | 21803.=+ 50j 8.72 |
Filename | | | | | | |
_ _ _ _ _ _ .
1 300681RI03 | 27571.= 118| 3.80 | 95690.= 120| 5.91 49039.= 1129.24
IS# 1 = CI30 1,4-DICHLOROBENZENE-D4
IS# 2 = CI40 NAPHTHALENE-D8
IS# 3 = CI50 ACENAPHTHENE-DIO
* - indicates an I.S. is outside QC limit(s)
| IStt 4 | IStt 5 | IS# 6
Standard I Area % I RT Area % I RT Area % I RT
ST16980902 | 76218. |12.09 | 51424. |l7.27
Upper Limit j 152436.=+200j12.59 j 102848.=+200j17 . 77
Lower Limit | 38109.=+ 50J11.59 | 25712.=+ 50J16.77
Filename I II I
44306. [19.84
88612.=+200J20.34
22153.=+ 50 19.34
1 300681RI03 I 81651.= 107
12.11 77811.= 151 17.30 72812.= 164 19.87
IS# 4 = CI60 PHENANTHRENE-D10
IStt 5 = CI70 CHRYSENE-D12
IS# 6 = CI75 PERYLENE-D12
* - indicates an I.S. is outside QC limit(s)
-------
Semi volatile Organics
Method 0010/8270
Client Name: Pacific Environmental Services
Client ID: T-MM5-FB-F,FH,XAD,COND,BH
LAB ID: 300681-0004-SA
Matrix: AIRTRAIN Sampled:
Authorized: 30 JUL 98 Prepared:
Dilution Factor: 1.0
25 JUL 98
31 JUL 98
Parameter
Phenol
bi s(2-Chloroethyl)ether
2-Chlorophenol
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Benzyl alcohol
1,2-Dichlorobenzene
2-Methylphenol
2,2'-Oxybis(l-chloropropane)
3/4-Methylphenol
N-Nitroso-di-n-propylamine
Hexachloroethane
Nitrobenzene
Isophorone
2-Nitrophenol
2,4-Dimethylphenol
Benzoic acid
bis(2-Chloroethoxy)-methane
2,4-Dichlorophenol
1,2,4-Trichlorobenzene
Naphthalene
4-Chloroaniline
Hexachlorobutadiene
4-Chloro-3-methyl phenol
2-Methylnaphthalene
Hexachl orocyclopentadi ene
2,4,6-Trichlorophenol
2,4,5-Trichlorophenol
2-Chloronaphthalene
2-Nitroaniline
Dimethyl phthalate
Acenaphthylene
3-Nitroaniline
Acenaphthene
2,4-Dinitrophenol
4-Nitrophenol
Dibenzofuran
Wet wt.
Result
Units
Received: 30 JUL 98
Analyzed: 31 AUG 98
Reporting
Limit
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
150
30
30
30
30
30
30
30
30
30
30
150
30
30
30
30
150
30
150
150
30
Qualifier
R
Note R = Reporting limit(s) raised due to sample volume limitations.
ND = Not Detected
Reported By: Emily Uebelhoer
Approved By: Karin Yee
The cover letter is an integral part of this report.
Rev 230787
-------
Semi volatile Organics
Method 0010/8270
Client Name: Pacific Environmental Services
Client ID: T-MM5-FB-F,FH,XAD,COND,BH
LAB ID: 300681-0004-SA
Matrix: AIRTRAIN Sampled: 25 JUL 98
Authorized: 30 JUL 98 Prepared: 31 JUL 98
(cont.)
Dilution Factor: 1.0
Parameter
2,4-Dinitrotoluene
2,6-Dinitrotoluene
Diethyl phthalate
4-Chlorophenyl phenyl ether
Fluorene
4-Nitroaniline
4,6-Dinitro-2-methylphenol
N-Nitrosodiphenylamine
4-Bromophenyl phenyl ether
Hexachlorobenzene
Pentachlorophenol
Phenanthrene
Anthracene
Di-n-butyl phthalate
Fluoranthene
Pyrene
Butyl benzyl phthalate
3,3'-Dichlorobenzidine
Benzo(a)anthracene
bis(2-Ethylhexyl)-phthalate
Chrysene
Di-n-octyl phthalate
Benzofb fluoranthene
Benzo(k fluoranthene
Benzo(a pyrene
Indeno( ,2,3-cd)pyrene
Dibenz(a,h)anthracene
Benzo(g,h,i)perylene
Acetopnenone
4-Aminobiphenyl
Aniline
Benzidine
3,3'-Dimethylbenzidine
N-Nitrosodimethylamine
N-Nitrosomorpholine
Pentachloronitrobenzene (PCNB)
o-Toluidine
Wet wt.
Result
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Reporting
Units
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample ,
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
Limit
30
30
30
30
30
150
150
30
30
30
150
30
30
30
30
30
30
60
30
30
30
30
30
30
30
30
30
30
30
150
30
300
60
30
30
150
60
Received: 30 JUL 98
Analyzed: 31 AUG 98
Qualifier
ND = Not Detected
Reported By: Emily Uebelhoer
Approved By: Karin Yee
The cover letter is an integral part of this report.
Rev 230787
-------
Semivolatile Organics
Method 0010/8270
Client Name: Pacific Environmental Services
Client ID: T-MM5-FB-F,FH,XAD,COND,BH
LAB ID: 300681-0004-SA
Matrix: AIRTRAIN Sampled: 25 JUL 98
Authorized: 30 JUL 98 Prepared: 31 JUL 98
Dilution Factor: 1.0
Wet wt.
Parameter Result Units
2-Methoxybenzenamine ND ug/Sample
Biphenyl ND ug/Sample
Chloroacetophenone ND ug/Sample
Cumene ND ug/Sample
DBCP (l,2-Dibromo-3-chloropropane) ND ug/Sample
Benzo(e)pyrene ND ug/Sample
N-N-Diethylaniline . ND ug/Sample
Dimethyl aniline ND ug/Sample
3,3'-Dimethoxybenzidine ND ug/Sample
Hydroquinone ND ug/Sample
4,4'-Methyl-bis(2-chloroaniline) ND ug/Sample
4-Nitrodiphenyl ND ug/Sample
Trifluralin ND ug/Sample
(cont.)
Received: 30 JUL 98
Analyzed: 31 AUG 98
Reporting
Limit
Qualifier
K
K
K
K
K
K
K
K
K
K
K
K
K
Surrogate
Nitrobenzene-d5
2-Fluorobiphenyl
Terphenyl-dl4
Phenol-d5
2-Fluorophenol
2,4,6-Tribromophenol
Recovery
60 %
85 %
94 %
65 %
56 %
70 %
Acceptable Range
45 - 107
62 - 110
58 - 135
43 - 130
36 - 111
58 - 131
Note K = Identified by mass spectrum only; quantitation based on 1:1 response with
internal standard.
ND = Not Detected
Reported By: Emily Uebelhoer
Approved By: Karin Yee
The cover letter is an integral part of this report.
Rev 230787
\J
-------
Semivolatiles Library Search (20 Compound TID)
Method 8270
Client Name: Pacific Environmental Services
Client ID: T-MM5-FB-F,FH,XAD,COND,BH
LAB ID: 300681-0004-SA
Matrix: AIRTRAIN Sampled: 25 JUL 98
Authorized: 30 JUL 98 Prepared: NA
Dilution Factor: 1.0
Received: 30 JUL 98
Analyzed: 31 AUG 98
Parameter
4-Hydroxy-4-methyl-2-pentanone
n-Nonane
Benzaldehyde
Unknown
Hexadecanoic acid
Unknown
Unknown
Unknown
Unknown
5-Eiconsene,(E) -
Unknown
Unknown
Unknown
Unknown
Unknown
Unknown alkene
Unknown
Unknown alkene
Unknown
Unknown
Result
260
260
22
23
29
54
48
42
62
160
55
40
20
58
73
75
74
46
40
29
Units
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
Reporting
Limit Qualifier
0
0
0
0
0
Note 0 = Or structurally similar compound (isomer).
NA = Not Applicable
Reported By: Emily Uebelhoer
Approved By: Karin Yee
The cover letter is an integral part of this report.
Rev 230787
BC
-------
OUANTERRA GC/MS
Target Compound Data Summary Sheet
Sample: T-MM5-FB 1/3SA/1ML INST. ID:
Client: PACIFI
Analyst: DAT Instrument ID: F16
Quan List Threshold: 0.95
Data File: 30068104
Std Id: ST16980831
F16
Date Analyzed: 08/31/98 20:30
Run Factor: 3.00
Surrogate Vol.: 1.00
Surrogate
======================
CS20 NITROBENZENE-D5
CS25 2-FLUOROBIPHENY
CS30 TERPHENYL-D14
CS45 PHENOL-D5
CS50 2-FLUOROPHENOL
CS55 2,4,6-TRIBROMOP
Surrogate Spike Recoveries
8270-G, LIMS 10/10/96
Surrogate Amount (ug)
Spiked Measured
% Recovery
Measured QC limits
50.00
50.00
50.00
100.0
100.0
100.0
29.90
42.70
47.00
65.10
55.70
69.90
59.8
85.4
94.0
65.1
55.7
69.9
45 107
62 110
58 135
43 130
36 111
58 131
Target Compounds: SAP9
Parameter Scan Result Units
HEXACHLOROBENZENE-C13
C310 N-NITROSODIMETHYLAMINE
PYRIDINE
2-PICOLINE
N-NITROSOMETHYLETHYLAM1NE
METHYLMETHANESULFONATE
N-N1TROSODIETHYLAMINE
ETHYLMETHANE SULFONATE
PENTACHLOROETHANE
C320 ANILINE
C315 PHENOL
C325 BIS(2-CHLOROETHYL)ETHER
C330 2-CHLOROPHENOL
C335 1,3-DICHLOROBENZENE
C340 1,4-DICHLOROBENZENE
C345 BENZYL ALCOHOL
C350 1,2-DICHLOROBENZENE
C355 2-METHYLPHENOL
C360 2,2'-OXYBIS(1-CLPROPAN)
C361 ACETOPHENONE
N-NITROSOPYRROLIDINE
N-NITROSOMORPHOLINE
3-METHYL PHENOL
C365 4-METHYLPHENOL
C370 N-NITROSO-DI-N-PROPYLAM
0-TOLUIDINE
C375 HEXACHLOROETHANE
C410 NITROBENZENE
N-NITROSOPIPERIDINE
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
Reporting
Limit
30.0
30.0
60.0
30.0
30.0
30.0
:o.o
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
Reviewed by:
k c, -;
O ^ -1.
-------
Sample: T-MM5-FB
Client: PACIFI
Analyst: DAT
QUANTERRA GC/MS
Target Compound Data Summary Sheet
1/3SA/1ML
INST. ID:
Instrument ID: F16
Ouan List Threshold: 0.95
Data File: 30068104
Std Id: ST16980831
F16
Date Analyzed: 08/31/98 20:30
Run Factor: 3.00
Surrogate Vol.:
1.00
Parameter
ฃZ = = = ฃฃ = S = S5:=::ฃS =
C415 ISOPHORONE
C420 2-NITROPHENOL
C425 2,4-DIMETHYLPHENOL
C435 BIS(2-CHLOROETHOXY
C440 2,4-DICHLOROPHENOL
C430 BENZOIC ACID
AA-DIMETHYLPHENET
C445 1,2,4-TRICHU
C450 NAPHTHALENE
C455 4-CHLOROANALINE
2,6-DICHLOROPHENOL
HEXACHLOROPROPENE
C460 HEXACHLOROBU
P-PHENYLENE DIAMINE
N-NITROSODI-N-BI
C465 4-CHLORO-3
SAFROLE
C470 2-METHYLNA
1,2,4,5-TETRACH
ISOSAFROLE (#1)
C510 HEXACHLORO
C515 2,4,6-TRIC
C520 2,4,5-TRIC
ISOSAFROLE (#2)
C525 2-CHLORONAPHTH
1-CHLORONAPHT
C530 2-NITROANALINE
1,4-NAPHTHOQU1NONE
C535 DIMETHYLPHTHALATE
1,3-DINITROBENZENE
C540 ACENAPHTHYLENE
C543 2,6-DINITROTOLUENE
C545 3-NITROAN1LINE
C550 ACENAPHTHENE
C555 2,4-DINITROPHENOL
C565 D1BENZOFURAN
C560 4-NITROPHENOL
PENTACHLOROBENZENE
C570 2,4-DlNITROTOLUENE
1-NAPHTHYLAMINE
2-NAPHTHYLAMINE
2,3,4,6-TETRACH
C580 DIETHYLPHTHALATE
C590 FLUORENE
Target Compounds: SAP9
Scan Result
ND
NO
HENOL ND
THOXY)METH ND
HENOL ND
ND
YLAMINE ND
ROBENZENE ND
ND
NE ND
ND
ND
ADIENE ND
E ND
LAMINE ND
THYLPHENO ND
ND
HALENE ND
:OBENZENE ND
ND
ILOPENTADI ND
IROPHENOL ND
1ROPHENOL ND
#2) NO
'HALENE ND
ITHALENE ND
IE ND
; ND
(LATE ND
: ND
IE ND
5LUENE ND
JE ND
ND
HENOL ND
ND
ND
H ND
DLUENE ND
ND
ND
ROPHENOL ND
LATE ND
ND
Units
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
Reporting
Limit
30.0
30.0
30.0
30.0
30.0
150.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
60.0
30.0
30.0
30.0
60.0
30.0
15.0
150.0
30.0
30.0
30.0
30.0
30.0
150.0
30.0
150.0
30.0
150.0
30.0
30.0
30.0
30.0
60.0
30.0
30.0
-------
QUANTERRA GC/MS
Target Compound Data Summary Sheet
Data File: 30068104
Std Id: ST16980831
Sample: T-MM5-FB 1/3SA/1ML 1NST. ID: F16
Client: PACIFI Date Analyzed: 08/31/98 20:30
Analyst: DAT Instrument ID: F16 Run Factor: 3.00
Ouan List Threshold: 0.95 Surrogate Vol.: 1.00
Target Compounds: SAP9
Reporting
Parameter Scan Result Units Limit
C585 4-CHLOROPHENYL-PHENYLE ND UG/A 30.0
5-NITRO-O-TOLUIDINE ND UG/A 30.0
C595 4-NITROANAL1NE ND UG/A 150.0
C610 4.6-DINITRO-2-METHYLPH ND UG/A 150.0
C615 N-NITROSOOIPHENYLAMINE ND UG/A 30.0
C620 AZOBENZENE ND UG/A 30.0
SYM-TR1NITROBENZENE ND UG/A 30.0
C625 4-BROMOPHENYL-PHENYLET ND UG/A 30.0
PHENACETIN ND UG/A 30.0
DIALLATE 234 ND UG/A 30.0
C630 HEXACHLOROBENZENE ND UG/A 30.0
4-AMINOBIPHENYL ND UG/A 30.0
C635 PENTACHLOROPHENOL ND UG/A 150.0
PRONAMIDE ND UG/A 30.0
PENTACHLORONITROBENZENE ND UG/A 150.0
C640 PHENANTHRENE ND UG/A 30.0
C645 ANTHRACENE ND UG/A 30.0
2SECBUTYL-4,6-DINITROPHENOL ND UG/A 30.0
C647 CARBAZOLE ND UG/A 30.0
C650 DI-N-BUTYLPHTHALATE ND UG/A 30.0
4-NITROQU1NOLINE-1-OXIDE ND UG/A 30.0
METHAPYRILENE ND UG/A 30.0
1SODRIN ND UG/A 30.0
C655 FLUORANTHENE ND UG/A 30.0
CHLOROBENZILATE ND UG/A 30.0
C710 BENZ1DINE ND UG/A 300.0
C715 PYRENE ND UG/A 30.0
ARAMITE (#1) ND UG/A 30.0
ARAMITE (#2) ND UG/A 30.0
P-DIMETHYLAMINOAZOBENZENE ND UG/A 30.0
3,3'-01METHYLBENZIDINE ND UG/A 30.0
KEPONE ND UG/A 150.0
C720 BUTYLBENZYLPHTHALATE ND UG/A 30.0
2-ACETYLAMINOFLUORENE ND UG/A 30.0
C730 BENZO(A)ANTHRACENE ND UG/A 30.0
C725 3,3'-DICHLOROBENZIDINE ND UG/A 60.0
C740 CHRYSENE ND UG/A 30.0
C745 BIS(2-ETHYLHEXYL)PHTHA ND UG/A 30.0
3-METHYLCHOLANTHRENE ND UG/A 30.0
C760 DI-N-OCTYL PHTHALATE ND UG/A 30.0
C765 8ENZO(B)FLUORANTHENE ND UG/A 30.0
7,12-DIMETHYLBENZANTHRACENE ND UG/A 30.0
C770 BENZOdOFLUORANTHENE ND UG/A 30.0
HEXACHLOROPHENE ND UG/A 30.0
-------
QUANTERRA GC/MS
Target Compound Data Summary Sheet
Data File: 30068104
Std Id: ST16980831
Sample: T-MM5-FB 1/3SA/1ML INST. ID: F16
Client: PAC1FI Date Analyzed: 08/31/98 20:30
Analyst: DAT Instrument ID: F16 Run Factor: 3.00
Quan List Threshold: 0.95 Surrogate Vol.: 1.00
Parameter
Target Compounds: SAP9
Reporting
Scan Result Units Limit
C775 BENZO(A)PYRENE
C780 INDENO(1,2,3-CD)PYRENE
C785 DIBENZ(A,H)ANTHRACENE
C790 BENZO(G,H,I)PERYLENE
NO
ND
ND
ND
UG/A
UG/A
UG/A
UG/A
30.0
30.0
30.0
30.0
-------
DATA FROM FILE: 30968104 SCANS 93 TO 1203 ACQUIRED: 08/31/98 20:30:00
CALI: 30068104 #3
SAMPLE: T-MM5-FB 1/3SA/1ML INST. ID: F16
CONDS.: UG/ML *1ML *100Z/100Z *- CI40 NAPHTHALENE-OS
600 _
6:40
800 _
8:54
1000 _
11:07
ffli J
CS50 2-FLUOROPHENOL
112SS1* 02
82SS2* 02
136IS2# 01
- CS25 2-FLUOROBIPHENYL
- CI50 ACENAPHTHENE-D10
172SS3* 03
164IS3# 01
- CS55 2,4,6-TRIBROMOPHENOL 330SS3* 62
- CI60 PHENANTHRENE-D10
188IS4* 01
j
100.0Z < 4964350.)
367-12-4
4165-62-2
3855-82-1
4165-60-0
1146-65-2
321-60-8
15067-26-2
118-79-6
1517-22-2
CT
("-
CM
-------
DATA FROM FILE: 30068164 SCANS 1203 TO 2158 ACQUIRED: 08/31/98 20:30:00
CALI: 30068104 #3
SAMPLE: T-MM5-FB 1/3SA/1ML INST. ID: F16
CONDS.: UG/ML *1ML *100Z/100Z *
-------
STANDARD USED FOR THIS REPORT IS ST16980831 REPORT PRINTED: 9/01/98 16:35:13
ADDITIONAL STANDARD USED FOR THIS REPORT IS: ST16980S31A
QUANTERRA QUANT 1 TAT ION SUMMARY
File: 30068104
Sample: T-MM5-FB 1/3SA/1ML INST. ID: F16
Analyst: DAT Instrument Id: F16 Analyzed: 08/31/98 20:30
Compounds with amounts less than 0.20 reported as NOT FOUND
Library
No Entry Name Mass Meth Scan Ref
1 S1# 1 CI30 1,4-DICHLOROBENZENE 152 A BB
2 S2# 1 CI40 NAPHTHALENE-D8
3 S3# 1 CI50 ACENAPHTHENE-D10
4 S4# 1 CI60 PHENANTHRENE-D10
5 S5# 1 CI70 CHRYSENE-D12
6 S6# 1 CI75 PERYLENE-D12
7 S2# 2 CS20 NITROBENZENE-05
8 S3# 3 CS25 2-FLUOROBIPHENYL
9 S5# 2 CS30 TERPHENYL-D14
10 S1# 3 CS45 PHENOL-05
11 S1# 2 CS50 2-FLUOROPHENOL
12 S3# 2 CS55 2,4,6-TRIBROMOPHE
13 S4# 4 HEXACHLOROBENZENE-C13
14 S1# 15 C310 N-NITROSODIMETHYLAM
15 S1# 20 PYRIDINE
16 S1# 30 2-PICOLINE
17 S1# 40 N-NITROSOMETHYLETHYLAMIN
18 S1# 60 METHYLMETHANESULFONATE
19 S1# 70 N-NITROSODIETHYLAMINE
20 S1# 85 ETHYLMETHANE SULFONATE
21 S1# 95 PENTACHLOROETHANE
22 S1#100 C320 ANILINE
23 S1#105 C315 PHENOL
24 S1#110 C325 BIS(2-CHLOROETHYL)E
25 S1#115 C330 2-CHLOROPHENOL
26 S1#125 C335 1,3-DICHLOROBENZENE
27 S1#130 C340 1,4-DICHLOROBENZENE
28 S1#145 C345 BENZYL ALCOHOL
29 S1#150 C350 1,2-DICHLOROBENZENE
30 S1#160 C355 2-METHYLPHENOL
31 S1#165 C360 2,2'-OXYBIS(1-CLPRO
32 SI#170 C361 ACETOPHENONE
33 S1#175 N-NITROSOPYRROLIDINE
34 S1#180 N-NITROSOMORPHOLINE '
35 S1#182 3-METHYL PHENOL
36 S1#185 C365 4-METHYLPHENOL
37 S1#190 C370 N-NITROSO-DI-N-PROP
38 S1#195 0-TOLUIDINE
39 S1#200 C375 HEXACHLOROETHANE
40 S2# 10 C410 NITROBENZENE
41 S2# 15 N-NITROSOPIPERIDINE
42 S2# 20 C415 ISOPHORONE
43 S2# 25 C420 2-NITROPHENOL
44 S2# 30 C425 2,4-OIMETHYLPHENOL
45 S2# 35 C435 BISC2-CHLOROETHOXY)
Units: UG/ML
Area RRF(L) Amount
152
136
164
188
240
264
82
172
244
99
112
330
294
74
79
93
42
80
102
79
117
93
94
93
128
146
146
108
146
108
45
105
100
56
108
108
70
106
117
77
42
82
139
107
93
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
BB
BB
BB
BB
BB
BB
BB
BB
BB
BB
BB
BB
VB
BB
BB
BB
BB
BB
341
529
828
1085
1551
1782
421
722
1383
308
199
968
4
1
1
1
159
1
1
1
1
1
309
1
1
1
1
369
1
1
1
404
1
1
2
3
4
5
6
2
3
5
1
1
3
NOT
NOT
NOT
NOT
1
NOT
NOT
NOT
NOT
NOT
1
NOT
NOT
NOT
NOT
1
NOT
NOT
NOT
1
NOT
413 1
422 1
1
1
1
1
2
2
2
2
2
2
NOT
NOT
NOT
NOT
NOT
NOT
NOT
NOT
NOT
NOT
33946.
129608.
68092.
115982.
71692.
58915.
45553.
89717.
83889.
111982.
64661.
28049.
FOUND
FOUND
FOUND
FOUND
3558.
FOUND
FOUND
FOUND
FOUND
FOUND
388.
FOUND
FOUND
FOUND
FOUND
2780.
FOUND
FOUND
FOUND
412.
FOUND
224.
402.
FOUND
FOUND
FOUND
FOUND
FOUND
FOUND
FOUND
FOUND
FOUND
FOUND
1.
1.
1.
1.
1.
1.
0.
1.
0.
2.
1.
0.
0.
1.
0.
000
000
000
000
000
000
470
234
995
025
368
236
811
968
854
1.934
0.821
2.
,252
40.
40.
40.
40.
40.
40.
29.
42.
47.
65.
55.
69.
5.
0.
000
000
000
000
000
000
940
699
030
145
686
918
169
232
3.834
0.251
0.322
0,
.210
Ovx <
-------
46 S2# 40 C440 2,4-DICHLOROPHENOL 162 2 NOT FOUND
47 S2# 45 C430 BENZOIC ACID 122 2 NOT FOUND
48 S2# 50 AA-DIMETHYLPHENETHYLAMIN 58 2 NOT FOUND
49 S2# 55 C445 1,2,4-TRlCHLOROBENZ 180 2 NOT FOUND
-------
50 S2* 60 C450 NAPHTHALENE
51 S2# 80 C455 4-CHLOROANALINE
52 S2* 85 2,6-OICHLOROPHENOL
53 S2# 90 HEXACHLOROPROPENE
54 S2# 95 C460 HEXACHLOROBUTADIENE
55 S2#115 P-PHENYLENE DIAMINE
56 52*120 N-NITROSOOI-N-BUTYLAMINE
57 S2#130 C465 4-CHLORO-3-METHYLPH
58 S2#140 SAFROLE
59 52*145 C470 2-METHYLNAPHTHALENE
60 S3* 10 1,2,4,5-TETRACHLOROBENZE
61 S3* 15 ISOSAFROLE (#1)
62 S3* 20 C510 HEXACHLOROCYCLOPENT
63 S3* 25 C515 2,4,6-TRICHLOROPHEN
64 S3* 30 C520 2,4,5-TRICHLOROPHEN
65 S3* 35 ISOSAFROLE (#2)
66 S3* 40 C525 2-CHLORONAPHTHALENE
67 S3* 42 1-CHLORONAPHTHALEN
68 S3* 45 C530 2-NITROANALINE
69 S3* 50 1,4-NAPHTHOQUINONE
70 S3* 55 C535 OIMETHYLPHTHALATE
71 S3# 60 1,3-OINITROBENZENE
72 S3* 65 C540 ACENAPHTHYLENE
73 S3# 70 C543 2,6-DINITROTOLUENE
74 S3* 75 C545 3-N1TROAN1LINE
75 S3* 80 C550 ACENAPHTHENE
76 S3* 85 C555 2,4-DINITROPHENOL
77 S3* 90 C565 OIBENZOFURAN
78 S3* 95 C560 4-NITROPHENOL
79 S3#100 PENTACHLOROBENZENE
80 S3#105 C570 2,4-DINITROTOLUENE
81 53*110 1-NAPHTHYLAMINE
82 53*115 2-NAPHTHYLAM1NE
83 S3*120 2,3,4,6-TETRACHLOROPHENO
84 S3#130 C580 DIETHYLPHTHALATE
85 S3#135 C590 FLUORENE
86 S3#140 C585 4-CHLOROPHENYL-PHEN
87 S3#145 5-N1TRO-0-TOLUIDINE
88 53*150 C595 4-NITROANALINE
89 S4# 10 C610 4,6-DINlTRO-2-METHY
90 S4# 15 C615 N-NITROSOOIPHENYLAM
91 S4# 20 C620 AZOBENZENE
92 S4# 25 SYM-TRIN1TROBENZENE
93 S4* 30 C625 4-BROMOPHENYL-PHENY
94 S4# 35 PHENACETIN
95 S4* 37 DIALLATE
96 S4# 40 C630 HEXACHLOROBENZENE
97 S4# 45 4-AMINOBIPHENYL
98 S4# 50 C635 PENTACHLOROPHENOL
99 S4* 55 PRONAMIDE
100 S4# 60 PENTACHLORON1TROBENZENE
101 S4* 65 C640 PHENANTHRENE
102 S4# 70 C645 ANTHRACENE
103 S4* 75 2SECBUTYL-4,6-DINITROPHE
104 S4# 80 C647 CARBAZOLE
105 S4# 85 C650 DI-N-BUTYLPHTHALATE
106 54*100 4-NITROQUINOLINE-1-OXIDE
107 S4#105 METHAPYRILENE
108 S4#106 ISOORIN
109 S4#110 C655 FLUORANTHENE
110 S4#120 CHLOROBENZILATE
128
127
162
213
225
108
84
107
162
142
214
162
237
196
196
104
162
162
65
158
163
168
152
165
138
153
184
168
109
250
165
143
143
232
149
166
204
152
138
198
169
77
75
248
108
234
284
169
266
173
237
178
178
211
167
149 A BB
190
58
193
202
139
2 NOT FOUND
2 NOT FOUND
2 NOT FOUND
2 NOT FOUND
2 NOT FOUND
2 NOT FOUND
2 NOT FOUND
2 NOT FOUND
2 NOT FOUND
2 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
4 NOT FOUND
4 NOT FOUND
4 NOT FOUND
4 NOT FOUND
4 NOT FOUND
4 NOT FOUND
4 NOT FOUND
4 NOT FOUND
4 NOT FOUND
4 NOT FOUND
4 NOT FOUND
4 NOT FOUND
4 NOT FOUND
4 NOT FOUND
4 NOT FOUND
4 NOT FOUND
1226 4 2068
4 NOT FOUND
4 NOT FOUND
4 NOT FOUND
4 NOT FOUND
4 NOT FOUND
1.247
0.572
-------
111 S5# 10 C710 BENZIDINE
112 S5# 15 C715 PYRENE
113 S5# 20 ARAMITE (#1)
114 S5# 25 ARAMITE (#2)
115 S5# 30 P-DIMETHYLAMINOAZOBENZEN
116 S5# 35 3,3'-DlMETHYLBENZIDlNE
117 S5# 37 KEPONE
118 S5# 40 C720 BUTYLBENZYLPHTHALAT
119 S5# 45 2-ACETYLAMINOFLUORENE
120 S5# 50 C730 BENZO(A)ANTHRACENE
121 S5# 55 C725 3,3'-DICHLOROBENZ1D
122 S5# 60 C740 CHRYSENE
123 S5# 65 C745 BIS(2-ETHYLHEXYL)PH
124 S5# 85 3-METHYLCHOLANTHRENE
125 S6# 10 C760 OI-N-OCTYL PHTHALAT
126 S6# 15 C765 BENZO(B)FLUORANTHEN
127 S6# 20 7,12-DIMETHYLBENZANTHRAC
128 S6# 25 C770 BENZOCK)FLUORANTHEN
129 S6# 30 HEXACHLOROPHENE
130 S6# 35 C775 BENZO(A)PYRENE
131 S6# 55 C780 INDENOC1,2,3-CD)PYR
132 S6# 60 C785 D1BENZ(A,H)ANTHRACE
133 S6# 65 C790 BENZO(G,H,I)PERYLEN
184
202
185
185
120
212
272
149 A BB
181
228
252
228
149 A BB
268
149
252
256
252
196
252
276
278
276
5
5
5
5
5
5
5
NOT FOUND
NOT FOUND
NOT FOUND
NOT FOUND
NOT FOUND
NOT FOUND
NOT FOUND
1487 5 344
5
5
5
5
1603
5
6
6
6
6
6
6
6
6
6
NOT FOUND
NOT FOUND
NOT FOUND
NOT FOUND
5 3064
NOT FOUND
NOT FOUND
NOT FOUND
NOT FOUND
NOT FOUND
NOT FOUND
NOT FOUND
NOT FOUND
NOT FOUND
NOT FOUND
0.685 0.280
0.980
1.745
9C
-------
BNA, S LIBRARIES ANALYST: DATE:
QUANTERRA Internal Standard Check
Standard Filename: ST16980831 Analyzed: 08/31/98 12:31
| IS# 1 | 1S# 2 ) IS# 3
Standard | Area % | RT j Area % | RT j Area % | RT
ST16980831 | 28649. | 3.78 | 100432. | 5.90 | 54347. | 9.21
Upper Limit j 57297.=+200| 4.28 j 200864.=+200| 6.40 | 108695.=+200| 9.71
Lower Limit | 14324.=+ 50| 3.28 | 50216.=+ 50| 5.40 | 27174.=+ 50| 8.71
Filename I II II I
1 30068104 | 33946.= 118J 3.79 | 129608.= 129J 5.88 | 68092.= 125| 9.21
IS# 1 = CI30 1,4-DICHLOROBENZENE-D4
IS# 2 = CI40 NAPHTHALENE-08
IS# 3 = CI50 ACENAPHTHENE-D10
* - indicates an I.S. is outside QC limit(s)
| IS# 4 | IS# 5 | IS# 6
Standard | Area % | RT j Area % | RT j Area % | RT
ST16980831 | 98520. |12.08 | 62289. |17.26 | 50750. |19.83
Upper Limit j 197039.=+200j12.58 j 124578.=+200j17.76 j 101500.=+200)20.33
Lower Limit | 49260.=+ 50J11.58 | 31145.=+ 50J16.76 j 25375.=+ 50|19.33
Filename! I II II I
1 30068104 | 115982.= 117|12.07 | 71692.= 115J17.25 j 58915.= 116J19.82
IS# 4 = C160 PHENANTHRENE-D10
ISO 5 = CI70 CHRYSENE-D12
IS* 6 = CI75 PERYLENE-D12
* - indicates an I.S. is outside QC limit(s)
-------
Data Reduced by: **ซ-, X>ate: JJJJ^IS
Data Reviewed by: f Date:
>K
Data File: 30068104
QUANTERRA GC/MS TIC REPORT ( Part 1 )
Sanple: T-MM5-FB 1/3SA/1ML
Analyst: DAT
Concentration
in Sample
# SCAN (UG/A) CAS #
INST. ID: F16
Date Analyzed: 08/31/98 20:30
Run Factor: 3.00
1 170 260. 123-42-2
2-PENTANONE, 4-HYDROXY-4-METHYL-
2 222 260.
NONANE & r
111-84-2
286 22.
BENZALDEHYDE & '
100-52-7
932 23.
"Trmrminiir nrrn. ?-MFTHYI-
5 1235 29.
HEXADECANOIC ACID
57-10-3
6 1333 54.
UNKNOWN
00-00-0
7 1357
UNKNOWN
48.
00-00-0
XT
\c
1466 12. 62108-23-0
CANE, 2,5,6-TRIMETHYL- o r , 4
21.
00-00-0
KNOWN
10 1509 42.
UNKNOWN
00-00-0
-------
11 1528 62.
UNKNOWN
00-00-0
12 1586 160.
5-E1COSENE, (E)-
74685-30-6
13 1661 55.
UNKNOWN
00-00-0
14 1686 40.
UNKNOWN
00-00-0
V"l704 21.
XwjllfL I UllAIJut
19 1914 75.
O
1741 20. 00-00-0
UNKNOWN
1799 58. 00-00-0
UNKNOWN
! 1804 73. 00-00-0
UNKNOWN
V
\f
,
V
20 1932 74.
UNKNOWN
00-00-0
21 2012 46.
, (L~
22 2049 40.
UNKNOWN
00-00-0
-------
2056 29. 00-00-0
UNKNOWN
-------
DATA FILE: 30068104
QUANTERRA GC/MS TIC REPORT ( Part 2 )
CONCENTRATION = AREA(TIC)*CONC(IS)/AREA
-------
Library Search
08/31/98 20:30:00 + 1:53
Sample: T-MH5-FB 1/3SA/1ML
Conds.: UG/ML *1ML *100%/100%
Enhanced (S 15B 2N OT)
Data: 30068104 # 170
Cati: 30068104 # 3
INST. ID: F16
*(NA/NA )/1/3SA NA M
Base m/z: 43
RIC: 236032.
62231 spectra in UBRARYNB searched for maximum PURITY
495 matched at least 6 of the 16 largest peaks in the unknown
Rank In. Name
1 3241 2-PENTANONE, 4-HYDROXY-4-METHYL-
2 5791 1,3-DIOXOLANE-2-METHANOL, 2,4-DIMETHYL-
3 3366 2-PENTANOL. 2,4-DJMETHYL-
4 3288 ACETIC ACID, 1,1-DIMETHYLETHYL ESTER
5 919 TERT-BUTYL HYDROPEROXIDE
6 5594 2-PROPANOL, 2-NITROSO-, ACETATE (ESTER)
7 3349 2-HEXANOL, 2-METHYL-
8 11889 2-HEXANONE, 6-(ACETYLOXY)-
9 1576 OX1RANE, TETRAMETHYL-
M.Wt B.Pk Purity Fit RFit
Rank Formula
1
2
3
4
5
6
7
8
9
C6.H12.02
C6.H12.03
C7.H16.0
C6.H12.02
C4.H10.02
C5.H9.03.N
C7.H16.0
C8.H14.03
C6.H12.0
116
132
116
116
90
131
116
158
100
43
43
59
43
59
43
59
43
59
918
739
731
731
723
705
686
651
635
954
813
753
778
870
817
719
681
781
941
805
749
745
742
793
722
711
676
Rank
1
2
3
4
5
6
7
8
9
Ret.Time
B.P.Int.
US.Par.1
US.Par.2
C.A.S
123
53951
625
540
75
6931
625
4305
5076
, #
42-2
43-2
06-9
88-5
91-2
04-0
23-0
26-4
20-0
-------
MID LIBRARY SEARCH (LIBRARYNB)
08/31/98 20:30:09 + 1:53
SAMPLE: T-MM5-FB 1/3SA/1ML INST. ID:
CONDS.: UG/ML *1ML *100Z/100Z */l/3SA
ENHANCED
F16
NA M
DATA: 30068104 # 170
CALI: 30068104 # 3
BASE M/Z: 43
RIC: 236032.
1000
SAMPLE
C6.H12.02
1000 -
M WT 116
B PK 43
RANK 1
# 3241
PUR 918
C6.H12.03
1000 1
M WT 132
B PK 43
RANK 2
# 5791
PUR 739
C7.H16.0
1000 I
M WT 116
B PK 59
RANK 3
# 3366
PUR 731
M/Z
r
-i1
- * _ _. - . . . . ...
2-PENTANONE, 4-HYDROXY-4-METHYL- Q< \\p*s*S
ill I ,
ii. . i
1 , 3-D I OXOLANE-2-METHANOL , 2 , 4-D I METHYL-
r
,|l 1 . 1 ,
ill
2-PENTANOL, 2, 4-D I METHYL-
r
i iii i 1
i i I i i
20 40 60 ' 80 100
cr
-------
Library Search Data: 30068104 # 222 Base m/z: 43
08/31/98 20:30:00 + 2:28 Cali: 30068104 it 3 RIC: 214784.
Sample: T-MM5-FB 1/3SA/1ML INST. ID: F16
Conds.: UG/ML *1ML *100%/100% *(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
921 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 5159 NONANE
2 5151 HEPTANE, 3,4-DIMETHYL-
3 5141 HEPTANE, 2,4-OIMETHYL-
4 3086 HEXANE, 2,4-DlMETHYL-
5 19015 DECANE, 2,5,6-TRIMETHYL-
6 11607 UNDECANE
7 5154 HEXANE, 4-ETHYL-2-METHYL-
8 8085 HEPTANE, 2,4,6-TRIMETHYL-
9 5144 HEPTANE, 4-ETHYL-
Rank
1
2
3
4
5
6
7
8
9
Formula
C9.H20
C9.H20
C9.H20
C8.H18
C13.H28
C11.H24
C9.H20
C10.H22
C9.H20
M.Wt B.Pk Purity Fit RFit
128
128
128
114
184
156
128
142
128
43
43
43
43
57
43
57
43
43
933
901
883
880
873
866
860
857
857
987
933
941
960
918
931
920
904
910
933
901
884
891
883
902
860
872
865
Rank
1
2
3
4
5
6
7
8
9
Ret.Time B.P.Int.
US.Par.1
US.Par.2
C.A.S
11V
922
2213
589
62108
1120
3074
2613
2216
. #
84-2
28-1
23-2
43-5
23-0
21-4
75-7
61-8
32-2
-------
1141 -
SAMPLE
C9. H20
1141 i
M WT 128
B PK 43
RANK 1
# 5159
PUR 933
C9.H20
1141 i
M WT 128
B PK 43
RANK 2
# 5151
PUR 901
C9.H20
1141 i
M WT 128
B PK 43
RANK 3
# 5141
PUR 883
MID LIBRARY SEARCH (LIBRARYNB) DATA: 30068104 # 222 BASE M/Z: 43
08/31/98 20:30:00 + 2:28 CALI: 30068104 # 3 RIC: 214784.
SAMPLE: T-MM5-FB 1/3SA/1ML INST. ID: F16
CONDS.: UG/ML *1ML *100Z/100Z *
r
1
. 1
NONANE o r i\j^ 3,4-DIMETHYL-
r
1
HEPTANE, 2,4-DIMETHYL-
r
1
. i
1 i
M/Z
40
80
100
120
-------
Library Search
08/31/98 20:30:00 ^
Sample: T-MM5-FB
Conds.: UG/HL *1ML
Data: 30068104 # 286
3:11 Cali: 30068104 # 3
1/3SA/1ML INST. ID: F16
* 100V100% *(NA/NA )/1/3SA NA H
Base m/z: 77
RIC: 12928.
Enhanced (S 15B 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
354 matched at least 5 of the 16 largest peaks in the unknown
Rank In.
Name
1 2017 BENZALDEHYDE
2 7284 BENZOYL CHLORIDE
3 6466 ETHANONE, 2-HYDROXY-1-PHENYL-
4 2014 2.4-HEPTAD1EN-6-YNAL, (E,E)-
5 9645 BENZOYLFORMIC ACID
6 13112 BENZOYL ISOTHIOCYANATE
7 6857 BENZENECARBOTHIOIC ACID
8 6111 1,2-BENZENEDICARBOXALDEHYDE
9 13359 BENZENEACETIC ACID, .ALPHA.-0X0-, METHYL ESTER
Rank
1
2
3
4
5
6
7
8
9
Formula
C7.H6.
C7.H5.
C8.H8.
C7.H6.
C8.H6.
C8.H5.
C7.H6.
C8.H6.
C9.H8.
')
02
0
03
O.N.S
O.S
02
03
M.Ut
1 OA
lUo
140
136
106
150
163
138
134
164
B.Pk
105
105
105
105
105
77
105
105
Purity
soi^_
806
805
779
767
760
759
758
Fit
f*IJ. ~r
-~ TO/
871
~~8*3
844
849
818
846
806
834
RFit
"94-1^
az6-
822
809
803
785
807
915
786
Rank
1
2
3
4
5
6
7
8
9
Ret.Time
B.P.lnt.
US.Par.1
US.Par.2
C.A.S
100-
98
582
7200
611
532
98
643
15206
52-7
88-4
24-1
04-6
73-4
55-8
91-9
79-8
55-0
-------
MID LIBRARY SEARCH (LIBRARYNB) DATA:
08/31/9820:30:00+ 3:11 CALI:
SAMPLE: T-MM5-FB 1/3SA/1ML INST. ID: FIG
CONDS.: UG/ML *1ML *100Z/100Z *
30068104 # 286
30068104* 3
BASE M/Z: 77
RIC: 12928.
1496
SAMPLE
C7.H6.0
1496
M WT
B PK
106
77
RANK 1
# 2017
PUR 920
BENZALDEHYDE (X
C7.H5.0.CL
1496
M WT
B PK
140
105
RANK 2
# 7284
PUR 809
C8.H8.02
1496
M WT 136
B PK 105
RANK 3
* 6466
PUR 806
M/Z
ETHANONE, 2-HYDROXY- 1-PHENYL-
40
60
80
100
120
140
160
180
200
CD
-------
Library Search Data: 30068104 # 932 Base m/z: 71
08/31/98 20:30:00 + 10:22 Cali: 30068104 * 3 R1C: 17504.
Sample: T-MM5-FB 1/3SA/1ML INST. ID: M6
Conds.: UG/ML *1ML *100%/100% *(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
410 matched at least 6 of the 16 largest peaks in the unknown
Rank In. Name
1 40501 PROPANOIC ACID, 2-METHYL-, 1-(1,1-DIMETHYLETHYD-2-METHYL-1,3-PROPA*
2 40500 PROPANOIC ACID, 2-METHYL-, 2-ETHYL-1-PROPYL-1,3-PROPANEDIYL ESTER
3 26739 PROPANOIC ACID, 2-METHYL-, 2,2-DIMETHYL-1-(2-HYDROXY-1-METHYLETHYL)*
4 26740 PROPANOIC ACID, 2-METHYL-, 3-HYDROXY-2,4,4-TRIMETHYLPENTYL ESTER
5 4625 1-HEXENE, 3,4,5-TRIMETHYL-
6 11945 PROPANOIC ACID, 2-METHYL-, 1-METHYLBUTYL ESTER
7 19470 BUTANOIC ACID, 1-METHYLHEXYL ESTER
8 26737 PROPANOIC ACID, 2-METHYL-, 2-ETHYL-3-HYDROXYHEXYL ESTER
9 14787 1-NONENE, 4,6,8-TRIMETHYL-
Rank
1
2
3
4
5
6
7
8
9
Formula
C16.H30.04
C16.H30.04
C12.H24.03
C12.H24.03
C9.H18
C9.H18.02
C11.H22.02
C12.H24.03
C12.H24
M.Wt
286
286
216
216
126
158
186
216
168
B.Pk
71
43
71
71
43
71
71
71
43
Purity
779
699
695
638
575
539
539
528
519
Fit
930
866
883
794
800
799
755
691
715
RFit
800
726
714
643
658
610
578
551
531
Rank
1
2
3
4
5
6
7
8
9
Ret.Time
B.P.Int.
US.Par.1
US.Par.2
C.A.S.
74381
74367
74367
74367
56728
54340
39026
74367
54410
, #
40-1
30-9
33-2
34-3
10-0
93-1
94-3
31-0
98-9
-------
1145
SAMPLE
MID LIBRARY SEARCH (LIBRARYNB)
08/31/98 20:30:00 + 10:22
SAMPLE: T-MM5-FB 1/3SA/1ML INST. ID:
CONDS.: UG/ML *1ML *100Z/100Z *
F16
NA M
DATA: 30068104 # 932
CALI: 30068104 # 3
BASE M/Z: 71
RIC: 17504.
-4 4-
C16.H30.04
1145
M MT 286
B PK 71
RANK 1
* 40501
PUR 779
I ' I
PROPANO1C ACID, 2-METHYL-, 1-<1, 1-DIMETHYLETHYL)-2-METHYL-1,3-PROPANE!
C16.H30.04
1145
M WT 286
B PK 43
RANK 2
* 40500
PUR 699
PROPANO1C ACID, 2-METHYL-, 2-ETHYL-1-PROPYL-1,3-PROPANEDIYL ESTER
-4
C12.H24.03
1145
M WT 216
B PK 71
RANK 3
# 26739
PUR 695
M/Z
PROPANO1C ACID, 2-METHYL-, 2,2-DIMETHYL-l-<2-HYDROXY-l-METHYLETHYL)PR!
50
100
150
200
CT
-------
Library Search Data: 30068104 #1235 Base m/z: 43
08/31/98 20:30:00 + 13:44 Call: 30068104 # 3 RIC: 16144.
Sample: T-MM5-FB 1/3SA/1ML INST. ID: F16
Conds.: UG/ML *1ML *100%/100% *(NA/NA J/1/3SA NA M
Enhanced (S 15B 2N OT)
62231 spectra in L1BRARYNB searched for maximum PURITY
912 matched at least 6 of the 16 largest peaks in the unknown
Rank In. Name
1 35182 HEXADECANOIC ACID
2 37913 GLYCINE, N-METHYL-N-(I-OXOOODECYL)-
3 40669 DODECANAMIDE, N,N-BIS(2-HYDROXYETHYL)-
4 29642 TETRADECANOIC ACID
5 40184 OCTADECANOIC ACID
6 22949 DODECAN01C ACID
7 26351 TRIDECANOIC ACID
8 19469 UNDECANOIC ACID
9 32392 PENTADECANOIC ACID
Rank Formula M.Ut B.Pk Purity Fit RFit
1 C16.H32.02 256 43 752 957 774
2 C15.H29.03.N 271 73 669 982 669
3 C16.H33.03.N 287 73 643 966 655
4 C14.H28.02 228 73 625 898 673
5 C18.H36.02 284 43 607 767 770
6 C12.H24.02 200 60 602 902 660
7 C13.H26.02 214 73 595 878 616
8 C11.H22.02 186 60 586 941 598
9 C15.H30.02 242 43 573 801 688
Rank Ret.Time B.P.Int. US.Par.1 US.Par.2 C.A.S. #
1 57-10-3
2 97-78-9
3 120-40-1
4 544-63-8
5 57-11-4
6 143-07-7
7 638-53-9
8 112-37-8
9 1002-84-2
-------
MID LIBRARY SEARCH DATA:
08/31/98 20:30:00 + 13:44 CALL-
SAMPLE: T-MM5-FB 1/3SA/1ML INST. ID: F16
CONDS.: UG/ML *1ML *10072/1007. *
30068104 #1235
30068104 # 3
BASE M/Z: 43
RIC: 16144.
1259
SAMPLE
/
/
J,
f
\
/
^
\\
/
I .hi I .111, i/ ,i., 1. .,.,...,. . I. i . . 1 . i
C16.H32.02 HEXADECANOIC-ACID ev ?*cr*~ป**f
1259 i
M WT 256
B PK 43
RANK 1
# 35182
PUR 752
/
h
/
\
1
||
M Q , , (
C15.H29.03.N
1259 i
M WT 271
B PK 73
RANK 2
# 37913
PUR 669
GLYCINE, N-P1ETHYL-N- < 1 -OXODODECYL) -
j I
I
C16.H33.03.N
1259
M WT 287
B PK 73
RANK 3
ซ 40669
PUR 643
M/Z
DODECANAMIDE, N,N-BIS<2-HYDROXYETHYL>-
50
100
150
200
250
CT
M
CM
-------
Library Search Data: 30068104 #1333 Base m/z: 59
08/31/98 20:30:00 + 14:50 Cali: 30068104 # 3 RIC: 7024.
Sample: T-MM5-FB 1/3SA/1ML INST. ID: F16
Conds.: UG/ML *1ML *100%/100% *(NA/NA )/1/3SA NA M
Enhanced
-------
1000 1
SAMPLE
MID LIBRARY SEARCH DATA:
08/31/98 20:30:00 + 14:50 CALI:
SAMPLE: T-MM5-FB 1/3SA/1ML INST. ID: F16
CONDS.: UG/ML *1ML *100Z/100Z *-1-METHYLETHOXY 3 -
Jn
I
C9.H18.03
1000
M WT 174
B PK 59
RANK 2
# 16192 '
PUR 534
C5.H10.03
1000
M WT 118
B PK 59
RANK 3
# 3502 '
PUR 532
2-PROPANOL, 1-Cl-METHYL-2-<2-PROPENYLOXY>ETHOXY]-
lil
BUTANOIC ACID, 3-HYDROXY-3-METHYL-
M/Z
50
100
150
200
-------
Library Search
08/31/98 20:30:00
Sample: T-MM5-FB
Conds.: UG/ML *1ML
Data: 30068104 #1357
15:06 Cali: 30068104 # 3
1/3SA/1ML INST. ID: F16
*100%/100% *(NA/NA )/1/3SA NA M
Base m/z: 59
RIC: 4152.
Enhanced (S 15B 2N OT)
62231 spectra in L1BRARYNB searched for maximum PURITY
803 matched at least 5 of the 16 largest peaks in the unknown
Rank In. Name
1 24247 2-PROPANOL, 1-[2-(2-METHOXY-1-METHYLETHOXY)-1-METHYLETHOXY]-
2 16192 2-PROPANOL, 1-[1-METHYL-2-(2-PROPENYLOXY)ETHOXY] -
3 20626 2-PROPANOL, 1.1' - [(1-METHYL-1,2-ETHANEDIYL)BlS(OXY)]BIS-
4 9229 2-PROPANOL, 1-(2-METHOXYPROPOXY)-
5 9228 1-PROPANOL, 2-C2-METHOXYPROPOXY)-
6 36537 2,5,8,11-TETRAOXATETRADECAN-13-OL, 4,7,10-TR1METHYL-
7 9235 1-PROPANOL, 2-(2-METHOXY-1-METHYLETHOXY)-
8 9234 2-PROPANOL, 1-(2-METHOXY-1-METHYLETHOXY)-
9 5786 PROPANOIC ACID, 2-HYDROXY-2-METHYL-, ETHYL ESTER
Rank
1
2
3
4
5
6
7
8
9
Formula
C10.H22.04
C9.H18.03
C9.H20.04
C7.H16.03
C7.H16.03
C13.H28.05
C7.H16.03
C7.H16.03
C6.H12.03
Rank
1
2
3
4
5
6
7
8
9
H.Wt
206
174
192
148
148
264
148
148
132
B.Pk
59
59
59
59
59
59
59
59
59
Purity
655
654
649
643
624
617
585
584
581
Fit
816
807
858
942
853
755
768
749
861
RFit
728
681
674
650
652
732
594
595
606
Ret.Time
B.P.Int.
US.Par.1
US.Par.2
C.A.S
20324
55956
1638
13429
13588
20324
55956
20324
80
#
33-8
25-7
16-0
07-7
28-8
34-9
21-3
32-7
55-7
fj.
-------
MID LIBRARY SEARCH CLIBRARYNB)
08/31/98 20:30:08 + 15:06
SAMPLE: T-MM5-FB 1/3SA/1ML INST. ID:
CONDS.: UG/ML *1ML *100Z/100Z */l/3SA
ENHANCED
F16
NA M
DATA: 30068104 #1357
CALI: 30068104 # 3
BASE M/2: 59
RIC: 4152.
Itttttt
SAMPLE
C10.H22.0
1000
M WT 206
B PK 59
RANK 1
# 24247
PUR 655
C9.H18.03
1000 I
M WT 174
B PK 59
RANK 2
* 16192
PUR 654
C9.H20.04
1000 I
M WT 192
B PK 59
RANK 3
# 20626
PUR 649
M/Z
r
.III n
VjLAA-^^"*'
ป- -^jJ > >
4 2-PROPANOL, l-C2-<2-METHOXY-l-METHYLETHOXY)-l -METHYLETHOXY]- , /
r
. |l ll'.l. . , . . ,i|
i 1 . . ... i
2-PROPANOL, 1-Cl -METHYL-2- < 2-PROPENYLOXY > ETHOX YD-
r
i,,i 1,
2-PROPANOL, 1, !'-[
-------
Library Search
08/31/98 20:30:00 + 16:18
Sample: T-MM5-FB 1/3SA/1ML
Conds.: UG/ML *1ML *100%/100%
Enhanced (S 15B 2N OT)
Data: 30068104 #1466
Cali: 30068104 # 3
1NST. ID: F16
*(NA/NA )/1/3SA NA M
Base m/z: 57
RIC: 2364.
62231 spectra in LIBRARYNB searched for maximum PURITY
603 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 19015 DECANE, 2,5,6-TRIMETHYL-
2 19056 UNDECANE, 2,7-DIMETHYL-
3 11612 NONANE, 2,5-DIMETHYL-
4 19006 DECANE, 6-ETHYL-2-METHYL-
5 11602 OCTANE, 2,4,6-TRIMETHYL-
6 19045 DECANE, 2,3,8-TRIMETHYL-
7 19000 UNDECANE, 5,6-DIMETHYL-
8 15969 HYDROXYLAMINE, 0-DECYL-
9 19523 1-OECANOL, 2-ETHYL-
Rank
1
2
3
4
5
6
7
8
9
Formula
C13.H28
C13.H28
C11.H24
C13.H28
C11.H24
C13.H28
C13.H28
C10.H23.0.N
C12.H26.0
M.Wt
184
184
156
184
156
184
184
173
186
B.Pk
57
43
57
57
57
57
57
43
57
Purity
707
700
699
695
693
692
678
676
674
Fit
905
872
882
877
898
881
889
842
837
RFit
730
729
732
722
711
713
697
756
766
Rank
1
2
3
4
5
6
7
8
9
Ret.Time
B.P.lnt.
US.Par.1
US.Par.2
C.A.S. #
62108-23-0
17301-24-5
17302-27-1
62108-21-8
62016-37-9
62238-14-6
17615-91-7
29812-79-1
21078-65-9
<ป; r
ซ-/ frw (_
-------
MID LIBRARY SEARCH (LIBRARYNB) DATA: 30068104 #1466 BASE M/Z: 57
08/31/9820:30:00+ 16:18 CALI: 30068104 # 3 RIC: 2364.
SAMPLE: T-MM5-FB 1/3SA/1ML INST. ID: F16
CONDS.: UG/ML *1ML * 100Z/100Z */l/3SA NA M
ENHANCED
-------
Library Search
08/31/98 20:30:00 H
Sample: T-MM5-FB
Conds.: UG/ML *1ML
Data: 30068104 #1502
16:42 Cali: 30068104 # 3
1/3SA/1ML INST. ID: F16
*100%/100% *(NA/NA )/1/3SA NA M
Base m/z: 45
RIC: 2424.
Enhanced (S 15B 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
384 matched at least 5 of the 16 largest peaks in the unknown
Rank In. Name
1 5446 2-HEXANONE, 6-METHOXY-
2 1573 1-PENTENE, 2-METHOXY-
3 3188 N-N1TROSO-2-METHYL-OXAZOL1DINE
4 1567 2-PENTENE, 2-METHOXY-
5 6418 2-PENTANOL, 3-CHLORO-4-METHYL-,
-------
MID LIBRARY SEARCH CLIBRARYNB) DATA: 30068104 #1502 BASE M/Z: 45
08/31/98 20:30:00 + 16:42 CALI: 30068104 # 3 RIC: 2424.
SAMPLE: T-MM5-FB 1/3SA/1ML INST. ID: F16
CONDS. : UG/ML *1ML * 100Z/100Z *
1495
SAMPLE
C7.H14.02
1495 i
M WT 130
B PK 43
RANK 1
# 5446
PUR 295
C6.H12.0
1495 -i
M WT 100
B PK 43
RANK 2
# 1573 '
PUR 289
C4.H8.02.h
1495
M WT 116
B PK 43
RANK 3
# 3188
PUR 282
M/Z
11
Jl
*ป"r~
, il ,1 II, . ,l\ 1 , I.I - , ,1 .
2-HEXANONE, 6-METHOXY- ' ....
1 .
1-PENTENE, 2-METHOXY- ' ......
1
42
i i .
N-H I TROSO-2-METHYL-OXAZOL I D I NE
II i .1 i
50 100 150 200
CT
70
C)
-------
Library Search Data: 30068104 #1509 Base m/z: 59
08/31/98 20:30:00 + 16:47 Cati: 30068104 # 3 R1C: 8624.
Sample: T-MH5-FB 1/3SA/1ML INST. ID: F16
Conds.: UG/ML ป1ML *100%/100% "(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
62231 spectra in L1BRARYNB searched for maximum PURITY
570 matched at least 6 of the 16 largest peaks in the unknown
Rank In. Name
1 3502 BUTANOIC ACID, 3-HYDROXY-3-METHYL-
2 24247 2-PROPANOL, 1-[2-(2-METHOXY-1-METHYLETHOXY)-1-METHYLETHOXY]-
3 3522 2,3-BUTANEDIOL, 2,3-DIMETHYL-
4 5522 2-HEXANOL, 2,3-DIMETHYL-
5 16192 2-PROPANOL, 1-[1-METHYL-2-(2-PROPENYLOXY)ETHOXY]-
6 5506 2,3,3-TRIMETHYL-2-PENTANOL
7 8460 SILANE, OCTYL-
8 20626 2-PROPANOL, 1,1'- [(1-METHYL-1,2-ETHANEDIYL)BIS(OXY)JBIS-
9 8805 1,3-DIOXAN-5-OL, 4,4,5-TRIMETHYL-
M.Wt B.Pk Purity Fit RFit
Rank
1
2
3
4
5
6
7
8
9
Formula
C5.H10.03
C10.H22.04
C6.H14.02
C8.H18.0
C9.H18.03
C8.H18.0
C8.H20.S1
C9.H20.04
C7.H14.03
118
206
118
130
174
130
144
192
146
59
59
59
59
59
59
59
59
59
583
526
511
506
479
471
467
458
442
842
741
937
831
692
931
848
714
903
598
581
511
514
513
471
517
506
467
Rank
1
2
3
4
5
6
7
8
9
Ret.Time
B.P.Int.
US.Par.1
US.Par.2
C.A.S.
625-
20324-
76-
19550-
55956-
23171-
871-
1638-
54063-
n
08-1
33-8
09-5
03-9
25-7
85-9
92-1
16-0
14-8
-------
MID LIBRARY SEARCH DATA:
08/31/98 20:30:80 + 16:47 CALI:
SAMPLE: T-MM5-FB 1/3SA/1ML INST. ID: FIG
CONDS.: UG/ML *1ML * 100Z/100Z *
30068104 #1509
30068104 # 3
BASE M/Z: 59
RIC: 8624.
1297
SAMPLE
C5.H10.03
1297
M WT 118
B PK 59
RANK 1
# 3502
PUR 583
C10.H22.04
1297 T
M WT 206
B PK 59
RANK 2
# 24247
PUR 526
C6.H14.02
1297
M WT 118
B PK 59
RANK 3
# 3522
PUR 511
BUTANOIC ACID, 3-HYDROXY-3-METHYL-
ill ,.l
,1.
2-PROPANOL, 1-C 2-(2-METHOXY-1-METHYLETHOXY)-1-METHYLETHOXY]-
1 1,,
1 1 . ..
2,3-BUTANEDIOL, 2,3-DIMETHYL-
M/Z
50
100
150
200
I'I
C1"!
-------
Library Search
08/31/98 20:30:00
Sample: T-MM5-FB
Conds.: UG/ML *1ML
Data: 30068104 #1528
17:00 Cali: 30068104 # 3
1/3SA/1ML INST. ID: F16
*100%/100% *(NA/NA )/1/3SA NA M
Base m/z: 59
RIC: 7552.
Enhanced (S 15B 2N OT)
62231 spectra in L1BRARYNB searched for maximum PURITY
904 matched at least 6 of the 16 largest peaks in the unknown
Rank In. Name
1 5522 2-HEXANOL. 2,3-DIMETHYL-
2 5527 2-HEPTANOL, 2-METHYL-
3 16192 2-PROPANOL, 1 -C1-METHYL-2-(2-PROPENYLOXY)ETHOXY]-
4 8506 4,5-DIMETHYL-3-HEPTANOL
5 9228 1-PROPANOL, 2-(2-METHOXYPROPOXY)-
6 26482 4-0-ACETYL-2,5-DI-0-MฃTHYL-3,6-DIDEOXY-D-GLUCONITRILE
7 3528 2-METHYL-2,3-PENTANEOIOL
8 3502 BUTANOIC ACID, 3-HYDROXY-3-METHYL-
9 5497 3-ETHYL-2-METHYL-2-PENTANOL
Rank
1
2
3
4
5
6
7
8
9
Formula
C8.H18.0
C8.H18.0
C9.H18.03
C9.H20.0
C7.H16.03
C10.H17.04.N
C6.H14.02
C5.H10.03
C8.H18.0
M.Ut
130
130
174
144
148
215
118
118
130
B.Pk
59
59
59
59
59
59
59
59
59
Purity
536
527
523
503
499
496
496
496
495
Fit
873
903
745
846
790
844
896
749
952
RFit
562
544
541
520
521
522
524
574
508
Rank
1
2
3
4
5
6
7
8
9
Ret.Time
B.P.Int.
US.Par.1
US.Par.2
C.A.S. #
19550-03-9
625-25-2
55956-25-7
13588-28-8
7795-80-4
625-08-1
D2
-------
MID LIBRARY SEARCH DATA: 30068104 #1528 BASE M/Z: 59
08/31/98 20:30:00 + 17:00 CALI: 30068104 # 3 RIC: 7552.
SAMPLE: T-MM5-FB 1/3SA/1ML INST. ID: F16
CONDS.: UG/ML *1ML *100Z/100Z */l/3SA NA M
ENHANCED
1098 -
SAMPLE
C8.H18.0
1098 -i
M WT 130
B PK 59
RANK 1
# 5522
PUR 536
C8.H18.0
1098 i
M WT 130
B PK 59
RANK 2
# 5527
PUR 527
C9.H18.03
1098 i
M WT 174
B PK 59
RANK 3
# 16192
PUR 523
M/Z
r
1 I It I
r
1 1 i ,
1 ' 'i V ' 1 1 1 u
r
III 1 | In
^^^^
2-HEXANOL , 2 , 3-D I METHYL-
2-HEPTANOL, 2-METHYL-
1
2-PROPANOL , 1 - C 1 -METH YL-2- < 2-PROPENYLOXY ) ETHOXY ] -
r
1 , ,,|
50 100 150 200
cr
-------
Library Search Data: 30068104 #1586 Base m/z: 55
08/31/98 20:30:00 + 17:38 Cali: 30068104 # 3 RIC: 52032.
Sample: T-MM5-FB 1/3SA/1ML 1NST. ID: F16
Conds.: UG/ML *1ML ป100%/100% *-
4 37062 1-NONADECENE
5 34411 5-OCTADECENE, (E)-
6 39517 3-EICOSENE, (E)-
7 34418 9-OCTADECENE, (E)-
8 26416 4-TETRADECANOL
9 31653 1-HEPTADECENE
Rank
1
2
3
4
5
6
7
8
9
Formula
C20.H40
C20.H40
C18.H36
C19.H38
C18.H36
C20.H40
C18.H36
C14.H30.0
C17.H34
M.Wt B.Pk Purity Fit RFit
280
280
252
266
252
280
252
214
238
55
55
69
97
55
57
55
43
55
808
805
797
794
793
793
792
792
792
983
982
962
971
961
985
960
989
977
812
808
812
804
807
796
806
798
800
Rank
1
2
3
4
5
6
7
8
9
Ret.Time
B.P.Int.
US.Par.1
US.Par.2
C.A.S.
74685-
74685-
7206-
18435-
7206-
74685-
7206-
1653-
6765-
#
30-6
29-3
19-1
45-5
21-5
33-9
25-9
33-4
39-5
-------
MID LIBRARY SEARCH
30068104 #1586 BASE M/Z: 55
30068104 # 3 RIC: 52032.
1189
SAMPLE
C20.H40
1189 i
M WT 280
B PK 55
RANK 1
# 39516
PUR 808
C20.H40
1189 i
M WT 280
B PK 55
RANK 2
# 39515 '
PUR 805
C18.H36
1189 i
M WT 252
B PK 69
RANK 3
# 34410
PUR 797
M/Z
i
., 1
. \
II ,i
1, M J,
5-EICOSENE, - ov ^ "*^
ฃ*>&
III
" ^/
9-EICOSENE, -
\
50
1
li . .
3-OCTADECENE, -
1
,, [
100 150 200 250
CT
l-'i
cn
-------
Library Search Data: 30068104 #1661 Base m/z: 59
08/31/98 20:30:00 + 18:29 Cali: 30068104 # 3 R1C: 7296.
Sample: T-MM5-FB 1/3SA/1ML INST. ID: F16
Conds.: UG/ML *1ML *100%/100X *(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
221 matched at Least 6 of the 16 largest peaks in the unknown
Rank In. Name
1 16192 2-PROPANOL, 1 -[1-METHYL-2-(2-PROPฃNYLOXY)ETHOXY]-
2 1909 2-PROPANOL, 1-METHOXY-2-METHYL-
3 20626 2-PROPANOL, 1,1'-[(1-METHYL-1,2-ETHANEDIYL)BIS(OXY)]BIS-
4 6083 2-PROPANOL, 1,1'-OXYB1S-
5 3528 2-METHYL-2,3-PENTANEDIOL
6 5809 1-ETHOXYPENTAN-3-OL
7 16651 DIETHYLENE GLYCOL TERT-BUTYL ETHER METHYL ETHER
8 8460 SI LANE, OCTYL-
9 6082 1-PROPANOL, 2-(2-HYDROXYPROPOXY)-
Rank
1
2
3
4
5
6
7
8
9
Formula
C9.H18.03
C5.H12.02
C9.H20.04
C6.H14.03
C6.H14.02
C7.H16.02
C9.H20.03
C8.H20.SI
C6.H14.03
I.Wt
174
104
192
134
118
132
176
144
134
B.Pk
59
59
59
59
59
59
57
59
59
Purity
502
485
477
452
445
440
438
430
421
Fit
788
945
819
889
860
868
824
863
818
RFit
513
490
494
464
476
480
462
455
429
Rank Ret.Time B.P.Int. US.Par.1 US.Par.2 C.A.S. #
1 55956-25-7
2 3587-64-2
3 1638-16-0
k 110-98-5
5 7795-80-4
6 - -
7 52788-79-1
8 871-92-1
9 106-62-7
-------
1399
SAMPLE
MID LIBRARY SEARCH (LIBRARYNB)
08/31/98 28:39:90 + 18:29
SAMPLE: T-MM5-FB 1/3SA/1ML INST. ID:
CONDS.: UG/ML *1ML *100Z/1092 */l/3SA
ENHANCED
DATA: 30068194 #1661
CALI: 39968104 * 3
BASE M/Z: 59
RIC: 7296.
F16
NA M
III
C9.H18.03
1399 T
M WT 174
B PK 59
RANK 1
# 16192
PUR 592
2-PROPANOL, l-[l-METHYL-2-<2-PROPENYLOXY)ETHOXY]-
C5.H12.02
1390
M WT 104
B PK 59
RANK 2
ป 1909
PUR 485
2-PROPANOL, l-METHOXY-2-METHYL-
JL
*M
2-PROPANOL,
l,r-C(l-METHYL-l,2-ETHANEDIYL)BIS(OXY)]BIS-
C9.H20.04
1390
M NT 192
B PK 59
RANK 3
* 20626
PUR 477
M/Z
40
60
80
109
129
140
169
189
290
220
-------
Library Search Data: 30068104 #1686
08/31/98 20:30:00 + 18:45 Cali: 30068104 # 3
Sample: T-MM5-FB 1/3SA/1ML 1NST. ID: F16
Conds.: UG/ML *1MU *100%/100X *(NA/NA )/1/3SA NA H
Enhanced (S 158 2N OT)
Base m/z: 59
RIC: 3724.
62231 spectra in LIBRARYNB searched for maximum PURITY
301 matched at least 4 of the 16 largest peaks in the unknown
Rank In. Name
1 43635 TRIETHYL (S)-2-(CARBOXYMETHOXYMETHYL)OXYDIACETATE
2 8432 2-HEXANONE, 3-HYDROXY-3.5-DIMETHYL-
3 42663 2,4,6,8,9-PENTATHlATRICYCLO[3.3.1.13,7]DECANE-1-THlOL, 3,5,7-TRIMET*
4 5826 2-PROPANOL, 1 -ISQPROPOXY-2-METHYL-
5 5815 1-TERT-BUTOXY-2-METHOXYETHANE
6 51383 4-HEXADECEN-2-OL, 1- C(2,2-D1METHYL-') ,3-DIOXOLAN-4-YL)METHOXY) -
7 60820 2,4,6,8,9-PENTATHIATRICYCLO[3.3.1.13,7]DECANE, 3,3'-DITHIOB1SH ,5,7*
8 5778 BUTANOIC ACID, 3-HYDROXY-3-METHYL-, METHYL ESTER
9 5916 BUTANOIC ACID, 4-N1TRO-
Rank
1
2
3
4
5
6
7
8
9
Formula
C13
C8.
C8.
C7.
C7.
C22
C16
C6.
C4.
.H22
H16.
H12.
H16.
H16.
.H42
.H22
H12.
.08
02
S6
02
02
.04
.512
03
H7.04.N
M.Ut
306
144
300
132
132
370
598
132
133
B.Pk
59
59
59
59
57
117
59
43
59
Purity
481
400
400
384
372
347
330
328
309
Fit
621
683
517
512
480
453
400
446
404
RFit
627
552
690
636
524
412
735
722
586
Rank
1
2
3
4
5
6
7
8
9
Ret.Time B.P.Int.
US.Par.1
US.Par.2
C.A.S. #
6321-14-8
57274-31-4
3587-75-5
66728-50-5
56256-43-0
57274-52-9
6149-45-7
16488-43-0
-------
MID LIBRARY SEARCH (LIBRARYNB) DATA: 30068104 #1686 BASE M/Z: 59
08/31/98 20:30:00 + 18:45 CALI: 30068104 # 3 RIC: 3724.
SAMPLE: T-MM5-FB 1/3SA/1ML INST. ID: F16
CONDS.: UG/ML *1ML *100Z/100Z *
1000
SAMPLE
C13.H22.0
1000 i
M WT 306
B PK 59
RANK 1
# 43635
PUR 481
C8.H16.02
1000 1
M WT 144
B PK 59
RANK 2
# 8432
PUR 400
C8.H12.S6
1000 -I
M WT 308
B PK 59
RANK 3
# 42663
PUR 400
M/Z
^
3 TR I ETHYL
-------
Library Search
08/31/98 20:30:00 H
Sample: T-MH5-FB
Conds.: UG/ML *1ML
Data: 30068104 #1704
18:57 Cali: 30068104 # 3
1/3SA/1ML INST. ID: F16
ป100%/100% *(NA/NA )/1/3SA NA M
Base m/z: 57
RIC: 7400.
Enhanced (S 158 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
922 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 26409 2-HEXYL-1-OCTANOL
2 32418 2-HEXYL-1-DECANOL
3 19523 1-DECANOL, 2-ETHYL-
4 32425 1-DECANOL, 2-HEXYL-
5 34410 3-OCTADECENE, (E)-
6 34418 9-OCTADECENE, (E)-
7 34411 5-OCTADECENE,
-------
MID LIBRARY SEARCH
1442
SAMPLE
C14.H30.0
1442 i
M WT 214 :
B PK 57
RANK 1
# 26409 !
PUR 726
C16.H34.0
1442 -.
M WT 242
B PK 57
RANK 2
# 32418
PUR 715
C12.H26.0
1442 -i
M WT 186
B PK 57
RANK 3
# 19523 '
PUR 710
M/Z
r
lllll illl . Mil. .,ln i .t.i . . .
2-HEXYL-l-OCTANOL
r
r
r*
r
1
I |l|l 1 1 1 'i . i
2-HEXYL-l-DECANOL
l[l |l|l l| 'I ... .'i ..... -'i ---... i - ., ,....,.. i ., ... j i i
1-DECANOL, 2-ETHYL-
1 III
40 60 89 100 120 140 160 180 200 220
fo
C ]
-------
Library Search
08/31/98 20:30:00 + 19:22
Sample: T-MM5-FB 1/3SA/1ML
Conds.: UG/ML *1ML *100X/100%
Enhanced (S 15B 2N OT)
Data: 30068104
Cati: 30068104 # 3
INST. ID: F16
*(NA/NA )/1/3SA NA M
Base m/z: 59
RIC: 7064.
62231 spectra in LIBRARYNB searched for maximum PURITY
544 matched at least 6 of the 16 largest peaks in the unknown
Rank In. Name
1 39622 9-OCTADECENAMIDE, (Z)-
2 22656 DOOECANAM1DE
3 15482 HEPTANAMIDE, 4-ETHYL-5-METHYL-
4 11721 NONANAMIDE
5 3133 PENTANAMIDE, 4-METHYL-
6 19516 1-DECANOL, 5,9-DlMETHYL-
7 16267 1,7-OCTANEDIOL, 3,7-DIMETHYL-
8 7998 TRANS-3,4-EPOXYNONANE
9 11584 7-OCTEN-2-OL, 2,6-DIMETHYL-
Rank
1
2
3
4
5
6
7
8
9
Formula
C18.H35.0.N
C12.H25.0.N
C10.H21.0.N
C9.H19.0.N
C6.H13.0.N
C12.H26.0
C10.H22.02
C9.H18.0
C10.H20.0
M.Wt
281
199
171
157
115
186
174
142
156
B.Pk
59
59
59
59
59
41
59
41
59
Purity
568
484
472
472
444
436
433
419
412
Fit
866
883
867
867
892
747
887
748
921
RFit
647
523
488
487
456
488
473
480
433
Rank
1
2
3
4
5
6
7
8
9
Ret.Time
B.P.Int.
US.Par.1
US.Par.2
C.A.S. #
301-02-0
1120-16-7
54789-40-1
1120-07-6
1119-29-5
91482-38-1
107-74-4
18479-58-8
-------
1407 i
SAMPLE
MID LIBRARY SEARCH
-------
Library Search
08/31/98 20:30:00 + 20:01
Sample: T-MM5-FB 1/3SA/1ML
Conds.: UG/HL *1ML *100X/100X
Enhanced (S 15B 2N OT)
Data: 30068104 #1799
Cali: 30068104 # 3
1NST. ID: F16
*(NA/NA )/1/3SA NA M
Base m/z: 45
RIC: 4152.
62231 spectra in LIBRARYNB searched for maximum PURITY
996 matched at least 4 of the 16 largest peaks in the unknown
Rank In. Name
1 9227 1,3,3-TRIMETHOXYBUTANE
2 41700 1,2,3,5,6-PENTA-0-METHYL-4-0-ACETYL-GLUCITOL
3 27502 15-CROWN-5
4 41712 3,6,9,12,15-PENTAOXANONADECAN-1-OL
5 21103 ETHANOL, 2,2'-COXYBIS(2,1-ETHANEDIYLOXY)] BIS-
6 43636 .BETA.-D-MANNOPYRANOSE, 2,4,6-TRI-0-METHYL-, DIACETATE
7 33841 3,6,9,12-TETRAOXAHEXADECAN-1-OL
8 36510 1,4,7,10,13,16-HEXAOXACYCLCXDCTADECANE
9 34224 2,5,8,11,14-PENTAOXAHEXADECAN-16-OL
M.Ut B.Pk Purity Fit RFit
Rank Formula
1
2
3
4
5
6
7
8
9
C7.H16.03
C13.H26.07
C10.H20.05
C14.H30.06
C8.H18.05
C13.H22.08
C12.H26.05
C12.H24.06
C11.H24.06
148
294
220
294
194
306
250
264
252
45
43
45
45
45
45
45
45
45
326
321
314
304
294
293
292
281
277
678
748
686
678
718
610
588
660
580
424
370
435
398
343
353
414
404
433
Rank
1
2
3
4
5
6
7
8
9
Ret.Time
8.P.Int.
US.Par.1
US.Par.2
C.A.S. #
6607-66-5
33100-27-5
1786-94-3
112-60-7
55255-81-7
1559-34-8
17455-13-9
23778-52-1
-------
1038
SAMPLE
MID LIBRARY SEARCH
08/31/98 20:30:00 + 20:01
SAMPLE: T-MM5-FB 1/3SA/1ML INST. ID:
CONDS.: UG/ML *1ML *100Z/100Z *
DATA: 30068104 #1799
CALI: 30068104 # 3
BASE M/Z: 45
RIC: 4152.
F16
NA M
-U-
.
C7.H16.03
1038
M WT 148
B PK 45
RANK 1
* 9227
PUR 326
1 , 3, 3-TRIMETHOXYBUTANE
C13.H26.07
1038
M WT 294
B PK 43
RANK 2
# 41700
PUR 321
1,2,3,5, 6-PENTA-0-METHYL-4-0-ACETYL-GLUCITOL
JL
C10.H20.05
1038 t
M WT 220
B PK 45
RANK 3
# 27502
PUR 314
M/Z
15-CROWN-5
,11 ,||
50
100
150
200
250
CT
f .'.
-------
Library Search
08/31/98 20:30:00 + 20:04
Sample: T-MM5-FB 1/3SA/1ML
Conds.: UG/ML *1ML *100%/100%
Enhanced (S 15B 2N OT)
Data: 30068104 #1804
Cali: 30068104 * 3
INST. ID: F16
*(NA/NA )/1/3SA NA M
Base m/z: 59
R1C: 6872.
62231 spectra in LIBRARYNB searched for maximum PURITY
221 matched at least 6 of the 16 largest peaks in the unknown
Rank In. Name
1 9228 1-PROPANOL, 2-C2-METHOXYPROPOXY)-
2 5826 2-PROPANOL, 1-ISOPROPOXY-2-METHYL-
3 1909 2-PROPANOL, 1-METHOXY-2-METHYL-
4 5786 PROPANOIC ACID, 2-HYDROXY-2-METHYL-, ETHYL ESTER
5 1905 2-BUTANOL, 3-METHOXY-
6 1919 1-BUTANOL, 3-METHOXY-
7 3502 BUTANOIC ACID, 3-HYDROXY-3-METHYL-
8 3528 2-METHYL-2.3-PENTANEDIOL
9 36510 1,4,7,10,13,16-HEXAOXACYCLOOCTADECANE
Rank
1
2
3
4
5
6
7
8
9
Formula
C7.H16.03
C7.H16.02
C5.H12.02
C6.H12.03
C5.H12.02
C5.H12.02
C5.H10.03
C6.H14.02
C12.H24.06
M.Ut
148
132
104
132
104
104
118
118
264
B.Pk
59
59
59
59
59
59
59
59
45
Purity
474
419
419
412
404
403
402
401
398
Fit
865
676
930
760
860
877
801
860
608
RFit
479
492
441
422
418
429
439
430
450
Rank
1
2
3
4
5
6
7
8
9
Ret.Time
B.P.Int.
US.Par.1
US.Par.2
C.A.S. #
13588-28-8
3587-75-5
3587-64-2
80-55-7
53778-72-6
2517-43-3
625-08-1
7795-80-4
17455-13-9
/= r
ฑ w
-------
1385
SAMPLE
MID LIBRARY SEARCH
-------
Library Search
08/31/98 20:30:00 H
Sample: T-MM5-FB
Conds.: UG/ML *1ML
Data: 30068104 #1914
21:17 Cali: 30068104 # 3
1/3SA/1ML INST. 10: F16
*100X/100% *(NA/NA )/1/3SA NA M
Base m/z: 43
RIC: 22720.
Enhanced (S 15B 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
818 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 26416 4-TETRADECANOL
2 37062 1-NONADECENE
3 39515 9-E1COSENE, (E)-
4 39516 5-EICOSENE, (E)-
5 31653 1-HEPTADECENE
6 34410 3-OCTADECENE, (E)-
7 34418 9-OCTADECENE, (E)-
8 58701 17-PENTATRlACONTENE
9 34411 5-OCTADECENE, (E)-
Rank
1
2
3
i,
5
6
7
8
9
Rank
1
2
3
4
5
6
7
8
9
Formula
C14.H30.0
C19.H38
C20.H40
C20.H40
C17.H34
C18.H36
C18.H36
C35.H70
C18.H36
Ret.Time
B.P.lnt.
US.Par.1
M.Wt
214
266
280
280
238
252
252
490
252
I
B.Pk Purity Fit RFit
43
97
57
55
55
69
55
43
55
US. Par. 2
754 982
754 963
752 958
750 956
750 961
747 945
745 942
745 935
745 942
C.A.S. #
1653-33-4
18435-45-5
74685-29-3
74685-30-6
6765-39-5
7206-19-1
7206-25-9
6971-40-0
7206-21-5
758
768
764
764
754
761
758
785
758
-------
MID LIBRARY SEARCH
30068104 #1914
30068104 # 3
BASE M/Z: 43
RIC: 22720.
1044 -j
SAMPLE
C14.H30.0
1044 -i
M WT 214
B PK 43
RANK 1
# 26416 "
PUR 754
C19.H38
1044 i
M WT 266 :
B PK 97
RANK 2
* 37062
PUR 754
C20.H40
1044 -i
M WT 288
B PK 57
RANK 3
# 39515
PUR 752
M/Z
Hu, i U-
1
ll ,1
i . i 1. ii i. . .il .- - .... . . . ____ - .
4-TETRADECANOL
1
II 1
1
ih ..... .. . .
LJ-- 1 ^iJ I r 1 1 i i i . i | . . . ,
1-NONADECENE
50
II 1
ll
1 i i, .. . ~
9-EICOSENE, -
'
1
ll
1 ..... - . u.
100 150 200 250
-------
Library Search Data: 30068104 #1932 Base m/z: 59
08/31/98 20:30:00 + 21:29 Cali: 30068104 # 3 RIC: 7480.
Sample: T-HM5-FB 1/3SA/1ML INST. ID: F16
Conds.: DC/ML *1HL *100%/100%<"*(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
62231 spectra in L1BRARYNB searched for maximum PURITY
816 matched at least 5 of the 16 largest peaks in the unknown
Rank In. Name
1 1909 2-PROPANOL, 1-METHOXY-2-METHYL-
2 3528 2-METHYL-2,3-PENTANEDIOL
3 27502 15-CROWN-5
4 5825 2-PROPANOL, 1-(2-METHYLPROPOXY)-
5 5809 1-ETHOXYPENTAN-3-OL
6 41712 3,6,9,12,15-PENTAOXANONADECAN-1-OL
7 1760 2-PENTANOL, 2-METHYL-
8 8813 ETHENE, C2-ETHOXY-1-METHOXYETHOXY)-
9 34224 2,5,8,11,14-PENTAOXAHEXADECAN-16-OL
Rank Formula
1
2
3
4
5
6
7
8
9
C5.H12.02
C6.H14.02
C10.H20.05
C7.H16.02
C7.H16.02
C14.H30.06
C6.H14.0
C7.H14.03
C11.H24.06
M.Ut
104
118
220
132
132
294
102
146
252
B.Pk
59
59
45
57
59
45
59
59
45
Purity
435
418
414
400
400
393
391
390
388
Fit
910
848
719
777
892
727
858
826
840
RFit
447
435
462
441
425
445
397
401
424
Rank
1
2
3
4
5
6
7
8
9
Ret-Time
B.P.Int.
US.Par.1
US.Par.2
C.A.S. #
3587-64-2
7795-80-4
33100-27-5
23436-19-3
1786-94-3
590-36-3
54063-18-2
23778-52-1
/ .
i -ฑ
-------
MID LIBRARY SEARCH
DATA: 30068104 #1932
CALI: 30068104 # 3
BASE M/Z: 59
RIC: 7480.
F16
NA M
1588 i
SAMPLE
A,
C5.H12.02
1588
M NT 104
B PK 59
RANK 1
# 1909 '
PUR 435
C6.H14.02
1588
M NT 118
B PK 59
RANK 2
# 3528
PUR 418
2-PROPANOL , 1 -METHOXY-2-METHYL-
dU
2-METHYL-2, 3-PENTANEDIOL
C10.H20.05
1588
M NT 220
B PK 45
RANK 3
# 27502
PUR 414
M/Z
15-CRONN-5
50
100
150
200
250
C !
-------
Library Search
08/31/98 20:30:00
Sample: T-MM5-FB
Conds.: UG/ML ป1ML
Data: 30068104 #2012
- 22:23 Cali: 30068104 # 3
1/3SA/1ML INST. ID: F16
*100%/100% *(NA/NA )/1/3SA NA M
Base m/z: 57
R1C: 11760.
Enhanced (S 15B 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
818 matched at least 7 of the 16 largest peaks in the unknown
Rank In.
1 39515 9-
2 39516 5-
3 26416 4-
34410 3-
34418 9-
6 37062
7 37049
8 34411
9 31653 1-
Name
E1COSENE, (E)-
EICOSENE, (E)-
TETRADECANOL
OCTADECENE, (E)-
OCTADECENE. (E)-
NONADECENE
OCTADECENAL
OCTADECENE, (E)-
HEPTADECENE
Rank
1
2
3
4
5
6
7
8
9
Formula
C20.H40
C20.H40
C14.H30.0
C18.H36
C18.H36
C19.H38
C18.H34.0
C18.H36
C17.H34
M.Ut B,
280
280
214
252
252
266
266
252
238
.Pk
55
55
43
69
55
97
43
55
55
Purity
692
691
691
690
689
687
687
687
685
Fit
945
943
973
941
939
943
909
937
945
RFit
708
708
701
707
704
710
731
704
700
Rank
1
2
3
4
5
6
7
8
9
Ret.Time
B.P.lnt.
US.Par.1
US.Par.2
C.A.S
74685
74685
1653
7206
7206
18435
56554
7206
6765
#
29-3
30-6
33-4
19-1
25-9
45-5
96-2
21-5
-39-5
<-/ ฃ
-------
MID LIBRARY SEARCH
30068104 #2012
30068104 # 3
BASE M/Z: 57
RIC: 11760.
1145
SAMPLE
,l'l|li . ,llll| , .lllll, . .|lli. , ,l|h, ...l|, . ,
9-EICOSENE, -
C20.H40
1145
M NT 280
B PK 55
RANK 1
# 39515
PUR 692
C20.H40
5-EICOSENE, -
11<ป3
M WT 280
B PK 55
RANK 2
# 39516
PUR 691
C14.H30.0
1145 -i
M NT 214
B PK 43
RANK 3
* 26416
PUR 691
M/Z
1
I
1 I, ,, ,
4-TETRADECANOL
1 1
1
i
50 100 150 200 250 300 350
..7
-------
Library Search
08/31/98 20:30:00 + 22:47
Sample: T-MM5-FB 1/3SA/1ML
Conds.: UG/ML *1ML *100%/100%
Enhanced (S 158 2N OT)
Data: 30068104 #2049
Cali: 30068104 # 3
1NST. ID: F16
*(NA/NA )/1/3SA NA M
Base m/z: 59
RIC: 4808.
62231 spectra in LIBRARYNB searched for maximum PURITY
932 matched at least 5 of the 16 largest peaks in the unknown
Rank In. Name
1 12385 BUTYRIC ACID, 4-ISOPROPOXY-, METHYL ESTER
2 16199 BUTYRIC ACID, 4-BUTOXY-, METHYL ESTER
3 8822 BUTANOIC ACID, 4-ETHOXY-, METHYL ESTER
4 9227 1,3,3-TRIMETHOXYBUTANE
5 1909 2-PROPANOL, 1-METHOXY-2-METHYL-
6 8425 2-HEPTANONE, 3-HYDROXY-3-METHYL-
7 5825 2-PROPANOL, 1-C2-METHYLPROPOXY)-
8 27502 15-CROWN-5
9 1760 2-PENTANOL, 2-METHYL-
Rank
1
2
3
4
5
6
7
8
9
Formula
C8.H16.03
C9.H18.03
C7.H14.03
C7.H16.03
C5.H12.02
C8.H16.02
C7.H16.02
C10.H20.05
C6.H14.0
M.Ut
160
174
146
148
104
144
132
220
102
B.Pk
85
57
59
45
59
59
57
45
59
Purity
463
454
432
408
388
382
379
369
367
Fit
814
787
802
712
913
793
804
643
877
RFit
464
464
448
420
399
385
408
429
372
Rank
1
2
3
4
5
6
7
8
9
Ret.Time B.P.Int.
US.Par.1 US.Par.2
C.A.S.
29006-
29006-
29006-
6607-
3587-
13757-
23436-
33100-
590
#
05-1
06-2
04-0
66-5
64-2
91-0
19-3
27-5
36-3
-------
MID LIBRARY SEARCH (LIBRARYNB) DATA: 30068104 #2049 BASE M/Z: 59
08/31/98 20:30:00 + 22:47 CALI: 30068104 * 3 RIC: 4808.
SAMPLE: T-MM5-FB 1/3SA/1ML INST. ID: F16
CONDS.: UG/ML *1ML * 100Z/1 007. *^
CO
-------
Library Search Data: 30068104 #2056 Base m/z: 59
08/31/98 20:30:00 + 22:52 Cali: 30068104 # 3 R1C: 5416.
Sample: T-MM5-FB 1/3SA/1ML INST. ID: M6
Conds.: UG/ML *1ML *100X/100% *(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
62231 spectra in L1BRARYNB searched for maximum PURITY
338 matched at least 6 of the 16 largest peaks in the unknown
Rank In. Name
1 27502 15-CROWN-5
2 41712 3,6,9,12,15-PENTAOXANONADECAN-1-OL
3 1909 2-PROPANOL, 1 -METHOXY-2-METHYL-
4 9227 1,3,3-TRIMETHOXYBUTANE
5 36510 1,4,7,10,13,16-HEXAOXACYCLOOCTADECANE
6 34224 2,5.8,11,14-PENTAOXAHEXADECAN-16-OL
7 12385 BUTYRIC ACID, 4- ISOPROPOXY- , METHYL ESTER
8 5825 2-PROPANI
9 3528 2-METHYL
Rank
1
2
3
4
5
6
7
8
9
Rank
1
2
3
4
5
6
7
8
9
Formula
C10.H20.05
C14.H30.06
C5.H12.02
C7.H16.03
C12.H24.06
C11.H24.06
C8.H16.03
C7.H16.02
C6.H14.02
Ret .Time
B.P.Int.
US.Par.1
H.Wt
220
294
104
148
264
252
160
132
118
B.Pk Purity Fit
45
45
59
45
45
45
85
57
59
US. Par. 2
429 717
416 727
406 906
401 715
396 725
378 834
377 751
373 777
373 812
C.A.S. #
33100-27-5
1786-94-3
3587-64-2
6607-66-5
17455-13-9
23778-52-1
29006-05-1
23436-19-3
7795-80-4
RFit
481
470
410
414
441
407
416
418
383
-------
1729
SAMPLE
MID LIBRARY SEARCH
08/31/98 20:30:09 + 22:52
SAMPLE: T-MM5-FB 1/3SA/1ML INST. ID:
CONDS.: UG/ML *1ML *100Z/100Z *
DATA:
CALI:
30068104 #2056
30068104 # 3
BASE M/Z: 59
RIC: 5416.
F16
NA M
Oil
C10.H20.05
1729
M WT 220
B PK 45
RANK 1
# 27502
PUR 429
15-CROMN-5
C14.H30.06
1729 T
M WT 294
B PK 45
RANK 2
# 41712
PUR 416
3,6,9,12,15-PENTAOXANONADECAN-l-OL
C5.H12.02
1729 i
M NT 104
B PK 59
RANK 3
# 1909
PUR 406
M/Z
2-PROPANOL, l-METHOXY-2-METHYL-
50
100
150
200
258
CT
cn
-------
TIC SELECTION REPORT
DATA FILE: 30068104
THE FOLLOWING PEAKS WERE REJECTED BECAUSE
AT LEAST 40 % OF THEIR SIZE WAS ACCOUNTED FOR BY
TARGET COMPOUNDS ELUTING WITHIN 4 SCANS OF THE
PEAK TOP.
SCAN SIZE AMOUNT
199
308
341
421
529
722
828
968
1086
1383
1383
1551
1782
232884.
294104.
217648.
128124.
322720.
288940.
318724.
253508.
319320.
309316.
311820.
228100.
194188.
28.865
36.453
26.977
15.881
40.000
36.262
40.000
31.756
40.000
54.242
54.681
40.000
40.000
TOTAL NUMBER OF UNIDENTIFIED PEAKS WITH SIZE
GREATER THAN 10 % OF THE CLOSEST INTERNAL STANDARD
THAT DOES NOT HAVE INTERFERENCES = 23
INTERNAL STANDARDS THAT HAVE R1C SIZE LESS THAN
50 X OR GREATER THAN 200 % OF THE ESTIMATED RIC SIZE
ARE CONSIDERED TO HAVE INTERFERENCES AND WILL NOT BE USED
FOR QUANT I TAT ION.
PERCENT OF
ESTIMATED
# INTERNAL STANDARD RIC SIZE RIC SIZE SCAN
1 CI40 NAPHTHALENE -D8
2 CI50 ACENAPHTHENE-D10
3 CI60 PHENANTHRENE-D10
4 CI70 CHRYSENE-D12
5 CI75 PERYLENE-D12
322720.
318724.
319320.
228100.
194188.
156
130
121
130
123
529
828
1086
1551
1782
* INDICATES INTERFERENCE
SIZE = AREA
-------
Semivolatile Organics
Method 0010/8270
Client Name: Pacific Environmental Services
Client ID:
LAB ID:
Matrix:
Authorized:
T-MM5-4-F,FH,XAD,COND,BH
300681-0005-SA
AIRTRAIN
30 JUL 98
Sampled: 26 JUL 98
Prepared: 31 OUL 98
Dilution Factor: 1.0
Parameter
Phenol
bis(2-Chloroethyl)ether
2-Chlorophenol
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Benzyl alcohol
1,2-Dichlorobenzene
2-Methylphenol
2,2'-Oxybis(l-chloropropane)
3/4-Methylphenol
N-Nitroso-di-n-propylamine
Hexachloroethane
Nitrobenzene
Isophorone
2-Nitrophenol
2,4-Dimethylphenol
Benzoic acid
bis(2-Chloroethoxy)-methane
2,4-Dichlorophenol
1,2,4-Trichlorobenzene
Naphthalene
4-Chloroaniline
Hexachlorobutadiene
4-Chloro-3-methyl phenol
2-Methyl naphthalene
Hexachlorocyclopentadiene
2,4,6-Trichlorophenol
2,4,5-Trichlorophenol
2-Chioronaphtha!ene
2-Nitroaniline
Dimethyl phthalate
Acenaphthylene
3-Nitroaniline
Acenaphthene
2,4-Dinitrophenol
4-Nitrophenol
Dibenzofuran
Wet wt.
Result
Units
Received: 30 JUL 98
Analyzed: 31 AUG 98
Reporting
Limit
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
150
30
30
30
30
30
30
30
30
30
30
150
30
30
30
30
150
30
150
150
30
Qualifier
R
Note R = Reporting limit(s) raised due to sample volume limitations.
ND = Not Detected
Reported By: Emily Uebelhoer
Approved By: Karin Yee
The cover letter is an integral part of this report.
Rev 230787
-------
Semivolatile Organics
Method 0010/8270
(cont.)
Client Name: Pacific Environmental Services
Client ID:
LAB ID:
Matrix:
Authorized:
T-MM5-4-F,FH,XAD,COND,BH
300681-0005-SA
AIRTRAIN
30 JUL 98
Sampled: 26 JUL 98
Prepared: 31 JUL 98
Dilution Factor: 1.0
Parameter
2,4-Dinitrotoluene
2,6-Dinitrotoluene
Diethyl phthalate
4-Chlorophenyl phenyl ether
Fluorene
4-Nitroaniline
4,6-Dinitro-2-methylphenol
N-Nitrosodiphenylamine
4-Bromophenyl phenyl ether
Hexachlorobenzene
Pentachlorophenol
Phenanthrene
Anthracene
Di-n-butyl phthalate
Fluoranthene
Pyrene
Butyl benzyl phthalate
3,3'-Dichlorobenzidine
Benzo(a)anthracene
bi s(2-Ethylhexyl)-phthalate
Chrysene
Di-n-octyl phthalate
Wet wt.
Result
Benzo
Benzo
Benzo
Indeno(
fluoranthene
fluoranthene
pyrene
,2,3-cd)pyrene
Dibenz(a,h)anthracene
Benzo(g,h,i)perylene
Acetophenone
4-Aminobiphenyl
Aniline
Benzidine
3,3'-Dimethylbenzidine
N-Nitrosodimethyl amine
N-Nitrosomorpholine
Pentachloronitrobenzene
o-Toluidine
(PCNB)
Units
Received: 30 JUL 98
Analyzed: 31 AUG 98
Reporting
Limit
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
30
30
30
30
30
150
150
30
30
30
150
30
30
30
30
30
30
60
30
30
30
30
30
30
30
30
30
30
30
150
30
300
60
30
30
150
60
Qualifier
ND = Not Detected
Reported By: Emily Uebelhoer
Approved By: Karin Yee
The cover letter is an integral part of this report.
Rev 230787
-------
Client Name:
Client ID:
LAB ID:
Matrix:
Authorized:
Semivolatile Organics
Method 0010/8270
Pacific Environmental
T-MM5-4-F,FH,XAD,COND
300681-0005-SA
AIRTRAIN
30 JUL 98
Dilution Factor: 1.0
Services
BH
Sampled:
Prepared:
26
31
JUL
JUL
98
98
(cont.)
Received: 30 JUL 98
Analyzed: 31 AUG 98
Wet wt.
Parameter Result Units
2-Methoxybenzenamine ND ug/Sample
Biphenyl ND ug/Sample
Chloroacetophenone ND ug/Sample
Cumene ND ug/Sample
DBCP (l,2-Dibromo-3-chloropropane) ND ug/Sample
Benzo(e)pyrene ND ug/Sample
N-N-Dietnylaniline ND ug/Sample
Dimethylaniline ND ug/Sample
3,3'-Dimethoxybenzidine ND ug/Sample
Hydroquinone ND ug/Sample
4,4'-Methyl-bis(2-chloroaniline) ND ug/Sample
4-Nitrodiphenyl ND ug/Sample
Trifluralin ND ug/Sample
Reporting
Limit
Qua! ifier
K
K
K
K
K
K
K
K
K
K
K
K
K
Surrogate
Nitrobenzene-d5
2-Fluorobiphenyl
Terphenyl-dl4
Phenol-d5
2-Fluorophenol
2,4,6-Tribromophenol
Recovery
62 %
86 %
110 %
61 %
54 %
65 %
Acceptable Range
45 - 107
62 - 110
58 - 135
43 - 130
36 - 111
58 - 131
Note K = Identified by mass spectrum only; quantitation based on 1:1 response with
internal standard.
ND = Not Detected
Reported By: Emily Uebelhoer
Approved By: Karin Yee
The cover letter is an integral part of this report.
Rev 230787
ticrrr
-------
Semivolatiles Library Search (20 Compound TID)
Method 8270
Client Name: Pacific Environmental Services
Client ID:
LAB ID:
Matrix:
Authorized:
T-MM5-4-F,FH,XAD,COND,BH
300681-0005-SA
AIRTRAIN
30 JUL 98
Sampled: 26 JUL 98
Prepared: NA
Dilution Factor: 1.0
Parameter
2,6-dimethyl-
2,6-dimethyl-
Benzaldehyde
Pentadecane
Nonadecane
Heptadecane,
Heptadecane,
Nonadecane
Nonadecane
Unknown
Unknown
Unknown
Tricosane
4-Hydroxy-4-methyl-2-pentanone
Unknown
Unknown
5-Eiconsene,(E) -
Unknown
n-Nonane
Unknown
3-Octadecene, (E)-
Unknown
Result
43
61
66
41
120
45
36
36
97
40
37
320
63
58
120
42
350
63
38
47
Units
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
Received: 30 JUL 98
Analyzed: 31 AUG 98
Reporting
Limit Qualifier
0
0
0
0
0
0
0
0
0
0
0
0
Note 0 = Or structurally similar compound (isomer).
NA = Not Applicable
Reported By: Emily Uebelhoer
Approved By: Karin Yee
The cover letter is an integral part of this report.
Rev 230787
1)58
-------
QUANTERRA GC/MS
Target Compound Data Summary Sheet
Sample: T-MM5-4 1/3SA/1ML 1NST. ID:
Client: PAC1FI
Analyst: DAT Instrument ID: F16
Ouan List Threshold: 0.95
Data File: 30068105
Std Id: ST16980831
F16
Date Analyzed: 08/31/98 21:00
Run Factor: 3.00
Surrogate Vol.: 1.00
Surrogate
Surrogate Spike Recoveries
8270-G, LIMS 10/10/96
Surrogate Amount (ug)
Spiked Measured
CS20 NITR08ENZENE-D5
CS25 2-FLUOROBIPHENY
CS30 TERPHENYL-D14
CS45 PHENOL -05
CS50 2-FLUOROPHENOL
CS55 2,4,6-TRIBROMOP
50.00
50.00
50.00
100.0
100.0
100.0
31.20
43.00
55.00
61.10
53.90
65.00
62.4
86.0
110.
61.1
53.9
65.0
X Recovery
Measured QC limits
45 107
62 110
58 135
43 130
36 111
58 131
Target Compounds: SAP9
Parameter Scan
HEXACHLOROBENZENE-C13
C310 N-NITROSOOIMETHYLAMINE
PYRIDINE
2-PICOLINE
N-NITROSOMETHYLETHYLAMINE 153
METHYLMETHANESULFONATE
N-NITROSOOIETHYLAMINE
ETHYLMETHANE SULFONATE
PENTACHLOROETHANE
C320 ANILINE
C315 PHENOL
C325 BIS(2-CHLOROETHYL)ETHER
C330 2-CHLOROPHENOL
C335 1,3-DICHLOROBENZENE
C340 1,4-DICHLOROBENZENE
C345 BENZYL ALCOHOL
C350 1,2-DICHLOROBENZENE
C355 2-METHYLPHENOL
C360 2,2'-OXYBIS(1-CLPROPAN)
C361 ACETOPHENONE
N-NITROSOPYRROLIDINE
N-NITROSOMORPHOLINE
3-METHYL PHENOL
C365 4-METHYLPHENOL
C370 N-NITROSO-DI-N-PROPYLAM
0-TOLUIDINE
C375 HEXACHLOROETHANE
C410 NITROBENZENE
N-NITROSOP1PERIDINE
Result
ND
ND
ND
ND
~&0)
V<
ND .
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Units
UG/A
UG/A
UG/A
UG/A
PO UG/A
3. ,UG/A
^Vaf* UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
Reporting
Limit
30.0
30.0
60.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0 /
Reviewed by:
'v, 4
-------
OUANTERRA GC/MS
Target Compound Data Summary Sheet
Data File: 30068105
Std Id: ST16980831
Sample: T-MM5-4
Client: PACIFI
Analyst: DAT
1/3SA/1ML
INST. ID: F16
Instrument ID: F16
Date Analyzed: 08/31/98 21:00
Run Factor: 3.00
Quan List Threshold: 0.95
Surrogate Vol.:
1.00
Target Compounds: SAP9
Parameter Scan
C415 ISOPHORONE
C420 2-NITROPHENOL
C425 2,4-DIMETHYLPHENOL
C435 BIS(2-CHLOROETHOXY)METH
C440 2,4-DICHLOROPHENOL
C430 BENZOIC ACID
AA-DIMETHYLPHENETHYLAMINE
C445 1,2,4-TRICHLOROBENZENE
C450 NAPHTHALENE
C455 4-CHLOROANAL1NE
2,6-DICHLOROPHENOL
HEXACHLOROPROPENE
C460 HEXACHLOROBUTADIENE
P-PHENYLENE DIAMINE
N-NITROSODI-N-BUTYLAMINE
C465 4-CHLORO-3-METHYLPHENO
SAFROLE
C470 2-METHYLNAPHTHALENE
1 ,2,4,5-TETRACHLOROBENZENE
ISOSAFROLE (#1)
C510 HEXACHLOROCYCLOPENTAD1
C515 2,4.6-TRICHLOROPHENOL
C520 2,4,5-TRICHLOROPHENOL
ISOSAFROLE (ซ)
C525 2-CHLORONAPHTHALENE
1-CHLORONAPHTHALENE
C530 2-NITROANAL1NE
1,4-NAPHTHOQUINONE
C535 DIMETHYLPHTHALATE
1,3-DINITROBENZENE
C540 ACENAPHTHYLENE
C543 2,6-DINITROTOLUENE
C54S 3-NITROANILINE
C550 ACENAPHTHENE
C555 2,4-DINITROPHENOL
C565 DIBENZOFURAN
C560 4-NITROPHENOL
PENTACHLOROBENZENE
C570 2,4-DINITROTOLUENE
1-NAPHTHYLAMINE
2-NAPHTHYLAMINE
2,3,4,6-TETRACHLOROPHENOL
C580 DIETHYLPHTHALATE
C590 FLUORENE
Result
NO
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Units
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
Reporting
Limit
30.0
30.0
30.0
30.0
30.0
150.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
60.0
30.0
30.0
30.0
60.0
30.0
15.0
150.0
30.0
30.0
30.0
30.0
30.0
150.0
30.0
150.0
30.0
150.0
30.0
30.0
30.0
30.0
60.0
30.0
30.0
t: -
-------
QUANTERRA GC/MS
Target Compound Data Summary Sheet
Sample: T-MM5-4 1/3SA/1ML INST. ID:
Client: PACIF1
Analyst: DAT Instrument ID: F16
Quan List Threshold: 0.95
Data File: 30068105
Std Id: ST16980831
F16
Date Analyzed: 08/31/98 21:00
Run Factor: 3.00
Surrogate Vol.: 1.00
Target Compounds: SAP9
Parameter
C585 4-CHLOROPHENYL-PHENYLE
5-NITRO-O-TOLUIDINE
C595 4-NITROANALINE
C610 4,6-DINITRO-Z-METHYLPH
C615 N-NITROSODIPHENYLAMINE
C620 AZOBENZENE
SYM-TRINITROBENZENE
C625 4-BROMOPHENYL-PHENYLET
PHENACETIN
01ALLATE 234
C630 HEXACHLOROBENZENE
4-AMINOBIPHENYL
C635 PENTACHLOROPHENOL
PRONAMIDE
PENTACHLORONITROBENZENE
C640 PHENANTHRENE
C645 ANTHRACENE
2SECBUTYL- 4,6-DINITROPHENOL
C647 CARBAZOLE
C650 DI-N-BUTYLPHTHALATE
4-NITROQUINOL1NE-1-OX1DE
KETHAPYRILENE
ISODR1N
C655 FLUORANTHENE
CHLOROBENZILATE
C710 BENZIDINE
C715 PYRENE
ARAM1TE (#1)
ARAMITE (#2)
P-DIMETHYLAMINOAZOBENZENE
3,3'-DIMETHYLBENZIDINE
KEPONE
C720 BUTYLBENZYLPHTHALATE
2-ACETYLAMINOFLUORENE
C730 BENZO(A)ANTHRACENE
C725 3,3'-DICHLOROBENZIDINE
C740 CHRYSENE
C745 BIS(2-ETHYLHEXYL)PHTHA
3-METHYLCHOLANTHRENE
C760 DI-N-OCTYL PHTHALATE
C765 BENZO(B)FLUORANTHENE
7,12-DIMETHYLBENZANTHRACENE
C770 BENZOdOFLUORANTHENE
HEXACHLOROPHENE
Scan
Result
Units
Reporting
Limit
NO
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
30.0
30.0
150.0
150.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
150.0
30.0
150.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
300.0
30.0
30.0
30.0
30.0
30.0
150.0
30.0
30.0
30.0
60.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
-------
QUANTERRA GC/MS
Target Compound Data Summary Sheet
Data File: 30068105
Std Id: ST16980831
Sample: T-MM5-4 1/3SA/1ML INST. ID: F16
Client: PACIFI Date Analyzed: 08/31/98 21:00
Analyst: DAT Instrument ID: F16 Run Factor: 3.00
Quan List Threshold: 0.95 Surrogate Vol.: 1.00
Target Compounds: SAP9
Parameter
C775 BENZO(A)PYRENE
C780 INDENO(1,2,3-CD)PYRENE
C785 DIBENZ(A,H)ANTHRACENE
C790 BENZO(G,H,I)PERYLENE
Scan Result
~=========~===s::
NO
ND
ND
ND
Reporting
Units Limit
UG/A
UG/A
UG/A
UG/A
30.0
30.0
30.0
30.0
-------
DATA FROM FILE: 30068105 SCANS 93 TO 1203 ACQUIRED: 08/31/98 21:00:00
CALI: 30068105 #3
SAMPLE: T-MM5-4 1/3SA/1ML INST. ID: F16
CONDS.: UG/ML *1ML *100Z/100Z *
-------
DATA FROM FILE: 30068105 SCANS 1203 TO 2158 ACQUIRED: 08/31/98 21:00:00
CALI: 38068105 #3
SAMPLE: T-MM5-4 1/3SA/1ML INST. ID: F16
CONDS.: UG/ML *1ML *100Z/100Z *(NA/NA )/l/3SA NA M
1400 .
15:34
1600 .
17:48
1800 J
20:01
2000 _
22:15
I
I
I
J 100.07. < 110208.)
CCOQ TERPHENYL-D14
244SS5* 02
1718-51-0
CI70 CHRYSENE-D12
240IS5* 01
1719-03-5
CI75 PERYLENE-D12
164IS6* 01
1520-96-3
-------
STANDARD USED FOR THIS REPORT IS ST16980831 REPORT PRINTED: 9/01/98 17:44:30
ADDITIONAL STANDARD USED FOR THIS REPORT IS: ST16980831A
QUANTERRA QUANT I TAT I ON SUMMARY
File: 30068105
Sample: T-MM5-4 1/3SA/1ML INST. ID: F16
Analyst: DAI Instrument Id: F16 Analyzed: 08/31/98 21:00
Compounds with amounts less than 0.20 reported as NOT FOUND
Library
No
1
2
3
A
5
6
7
8
9
10
11
12
13
H
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
Entry
S1# 1
S2# 1
S3# 1
S4# 1
S5# 1
S6# 1
S2# 2
S3# 3
S5# 2
S1# 3
S1# 2
S3# 2
S4# 4
S1# 15
S1# 20
S1# 30
S1# 40
S1# 60
S1# 70
S1# 85
S1# 95
S1#100
S1#105
S1#110
S1#115
S1#125
S1#130
S1#145
S1#150
S1#160
S1#165
S1#170
S1#175
S1#180
S1#182
S1#185
S1#190
S1#195
S1#200
S2# 10
S2# 15
S2# 20
S2# 25
S2# 30
S2# 35
Name Mass
C130 1,4-DICHLOROBENZENE
CI40 NAPHTHALENE-08
CI50 ACENAPHTHENE-D10
C160 PHENANTHRENE-D10
CI70 CHRYSENE-D12
CI75 PERYLENE-D12
CS20 NITROBENZENE-OS
CS25 2-FLUOROBIPHENYL
CS30 TERPHENYL-D14
CS45 PHENOL-D5
CS50 2-FLUOROPHENOL
CS55 2,4,6-TRIBROMOPHENO
HEXACHLOROBENZENE-C13
C310 N-NITROSOOIMETHYLAM
PYRIDINE
2-PICOLINE
N-NITROSOMETHYLETHYLAMIN
METHYLMETHANESULFONATE
N-NITROSOOIETHYLAMINE
ETHYLMETHANE SULFONATE
PENTACHLOROETHANE
C320 ANILINE
C315 PHENOL
C325 BIS(2-CHLOROETHYL)E
C330 2-CHLOROPHENOL
C335 1,3-DICHLOROBENZENE
C340 1,4-DICHLOROBENZENE
C345 BENZYL ALCOHOL
C350 1,2-DICHLOROBENZENE
C355 2-METHYLPHENOL
C360 2,2'-OXYBIS(1-CLPRO
C361 ACETOPHENONE
N-NITROSOPYRROLIDINE
N-NITROSOMORPHOLINE
3-METHYL PHENOL
C365 4-METHYLPHENOL
C370 N-NITROSO-DI-N-PROP
0-TOLUIDINE
C375 HEXACHLOROETHANE
C410 NITROBENZENE
N-NITROSOPIPERIDINE
C415 ISOPHORONE
C420 2-NITROPHENOL
C425 2,4-DIMETHYLPHENOL
C435 BIS(2-CHLOROETHOXY)
152
136
164
188
240
264
82
172
244
99
112
330
294
74
79
93
42
80
102
79
117
93
94
93
128
146
146
108
146
108
45
105
100
56
108
108
70
106
117
77
42
82
139
107
93
Meth
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
BB
BB
BB
BB
BB
BB
BB
BB
BB
BB
BB
BV
BV
BB
BB
BB
BV
BB
BB
BB
BB
BB
Scan Ref Area
340 1
529 2
828 3
1086 4
1551 5
1782 6
421 2
722 3
1383 5
308 1
198 1
968 3
4 NOT
1 NOT
1 NOT
1 NOT
153 1
1 NO!
212 1
253 1
1 NOT
301 1
309 1
1 NOT
1 NOT
1 NOT
342 1
370 1
1 NOT
1 NOT
1 NOT
400 1
1 NOT
1 NOT
422 1
1 NOT
1 NOT
1 NOT
1 NOT
2 NOT
449 2
2 NOT
2 NOT
2 NOT
2 NOT
35775.
135276.
72725 .
117535.
55639.
42978.
49476.
96577.
76073.
110653.
65971 .
27845.
FOUND
FOUND
FOUND
FOUND
7174.
FOUND
332.
338.
FOUND
408.
1292.
FOUND
FOUND
FOUND
812.
4056.
FOUND
FOUND
FOUND
1325.
FOUND
FOUND
825.
FOUND
FOUND
FOUND
FOUND
FOUND
348.
FOUND
FOUND
FOUND
FOUND
Units:
RRF(L)
1
1
1
1
1
1
0
1
0
2
1
0
0
0
1
1
1
1
0
1
2
0
.000
.000
.000
.000
.000
.000
.470
.234
.995
.025
.368
.236
.811
.521
.108
.846
.968
.617
.854
.934
.252
.320
UG/ML
Amount
40
40
40
40
40
40
31
43
54
61
53
64
9
0
0
0
0
0
5
0
0
0
.000
.000
.000
.000
.000
.000
.156
.036
.953
.081
.910
.989
.890
.712
.341
.247
.734
.561
.308
.766
.410
.321
-------
46 S2# 40 C440 2,4-DlCHLOROPHENOL 162 2 NOT FOUND
47 S2# 45 C430 BENZOIC ACID 122 2 NOT FOUND
48 S2# 50 AA-DIMETHYLPHENETHYLAMIN 58 2 NOT FOUND
49 S2# 55 C445 1,2,4-TRICHLOROBENZ 180 2 NOT FOUND
iฃ4
-------
50 S2# 60 C450 NAPHTHALENE
51 S2# 80 C455 4-CHLOROANALINE
52 S2# 85 2,6-DICHLOROPHENOL
53 S2# 90 HEXACHLOROPROPENE
54 S2# 95 C460 HEXACHLOROBUTADIENE
55 S2#115 P-PHENYLENE DIAMINE
56 S2#120 N-NITROSOOl-N-BUTYLAMINE
57 S2#130 C465 4-CHLORO-3-METHYLPH
58 S2#140 SAFROLE
59 S2#145 C470 2-METHYLNAPHTHALENE
60 S3# 10 1,2,4,5-TETRACHLOROBENZE
61 S3# 15 1SOSAFROLE (#1)
62 S3# 20 C510 HEXACHLOROCYCLOPENT
63 S3# 25 C515 2,4,6-TRICHLOROPHEN
64 S3# 30 C520 2,4,5-TRICHLOROPHEN
65 S3# 35 ISOSAFROLE (#2)
66 S3# 40 C525 2-CHLORONAPHTHALENE
67 S3# 42 1-CHLORONAPHTHALEN
68 S3# 45 C530 2-NITROANALINE
69 S3# 50 1,4-NAPHTHOQUINONE
70 S3# 55 C535 DIMETHYLPHTHALATE
71 S3# 60 1,3-DINITROBENZENE
72 S3# 65 C540 ACENAPHTHYLENE
73 S3# 70 C543 2,6-DINITROTOLUENE
74 S3# 75 C545 3-NITROANILINE
75 S3# 80 C550 ACENAPHTHENE
76 S3# 85 C555 2,4-DINlTROPHENOL
77 S3# 90 C565 DIBENZOFURAN
78 S3# 95 C560 4-NITROPHENOL
79 S3#100 PENTACHLOROBENZENE
80 S3#105 C570 2,4-DlNITROTOLUENE
81 S3#110 1-NAPHTHYLAMINE
82 S3#115 2-NAPHTHYLAM1NE
83 S3#120 2,3,4,6-TETRACHLOROPHENO
84 S3HM30 C580 DIETHYLPHTHALATE
85 S3#135 C590 FLUORENE
86 S3#140 C585 4-CHLOROPHENYL-PHEN
87 S3#145 5-N1TRO-0-TOLUIDINE
88 S3#150 C595 4-N1TROANALINE
89 S4# 10 C610 4.6-DIN1TRO-2-METHY
90 S4# 15 C615 N-NITROSODIPHENYLAM
91 S4# 20 C620 AZOBENZENE
92 S4# 25 SYM-TRINITROBENZENE
93 S4# 30 C625 4-BROMOPHENYL-PHENY
94 S4# 35 PHENACETIN
95 S4# 37 DIALLATE
96 S4# 40 C630 HEXACHLOROBENZENE
97 S4# 45 4-AMINOB1PHENYL
98 S4# 50 C635 PENTACHLOROPHENOL
99 S4# 55 PRONAMIDE
lOO S4# 60 PENTACHLORONITROBENZENE
01 S4# 65 C640 PHENANTHRENE
02 S4# 70 C645 ANTHRACENE
03 S4# 75 2SECBUTYL-4.6-DINITROPHE
04 S4# 80 C647 CARBAZOLE
05 S4# 85 C650 DI-N-BUTYLPHTHALATE
06 S4#100 4-NITROQUINOLINE-1-OXIDE
07 S4#105 METHAPYRILENE
08 S4#106 1SCOR1N
09 S4#110 C655 FLUORANTHENE
10 S4#120 CHLOROBENZILATE
128 A BB
127
162
213
225
108
84
107 A BB
162
142 A BB
214
162
237
196
196
104
162
162
65
158
163 A BB
168
152
165
138
153
184
168
109
250
165
143
143
232
149
166 A BB
204
152 A VB
138
198
169 A BB
77
75 A VV
248
108
234
284
169
266
173
237
178 A BB
178
211
167
149 A BB
190
58 A BB
193
202
139
532 2 2438. 1.022
2 NOT FOUND
2 NOT FOUND
2 NOT FOUND
2 NOT FOUND
2 NOT FOUND
2 NOT FOUND
649 2 496. 0.338
2 NOT FOUND
651 2 2124. 0.751
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
804 3 549. 1.341
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
925 3 880. 1.298
3 NOT FOUND
940 3 425. 0.356
3 NOT FOUND
4 NOT FOUND
956 4 479. 0.551
4 NOT FOUND
1023 4 404. 0.162
4 NOT FOUND
4 NOT FOUND
4 NOT FOUND
4 NOT FOUND
4 NOT FOUND
4 NOT FOUND
4 NOT FOUND
4 NOT FOUND
1090 4 3844. 1.033
4 NOT FOUND
4 NOT FOUND
4 NOT FOUND
1226 4 3511. 1.247
4 NOT FOUND
1264 4 552. 0.305
4 NOT FOUND
4 NOT FOUND
4 NOT FOUND
0.705
0.434
0.836
0.225
0.373
0.658
0.296
0.851
1.267
0.959
0.617
-------
111 S5# 10 C710 BENZ1DINE
112 S5# 15 C715 PYRENE
113 S5# 20 ARAMITE (#1)
114 S5# 25 ARAMITE (#2)
115 S5# 30 P-DIMETHYLAMINOAZOBSKZEN
116 S5# 35 3,3'-DIMETHYLBENZlDHIE
117 S5# 37 KEPONE
118 S5# 40 C720 BUTYLBENZYLPHTKALAT
119 S5# 45 2-ACETYLAMINOFLUOREME
120 S5# 50 C730 BENZO(A)ANTHRAENE
121 S5# 55 C725 3,3'-OICHLOROBENZID
122 S5# 60 C740 CHRYSENE
123 S5# 65 C745 BIS(2-ETHYLHEXYL)PH
124 S5# 85 3-METHYLCHOLANTHRENE
125 S6# 10 C760 Dl-N-OCTYL PHTHALAT
126 S6# 15 C765 BENZO(B)FLUORANTHEN
127 S6# 20 7,12-DIMETHYLBENZANTHRAC
128 S6# 25 C770 BENZO(K)FLUORANTHEN
129 S6# 30 HEXACHLOROPHENE
130 S6# 35 C775 BENZO(A)PYRENE
131 S6# 55 C780 1NDENOC1,2,3-CD)PYR
132 S6# 60 C785 OIBENZ(A,H)ANTHRACE
133 S6# 65 C790 BENZOCG.H,I )PERYLEN
184
202 A BB
185 A BV
185 A VB
120
212
272
149 A BB
181
228 A BB
252
228
149 A BB
268
149
252
256
252
196
252
276
278
276
5 NOT FOUND
1335 5 572. 1.323
1398 5 96. 0.061
1417 5 346. 0.087
5 NOT FOUND
5 NOT FOUND
5 NOT FOUND
1487 5 234. 0.685
5 NOT FOUND
1552 5 438. 1.125
5 NOT FOUND
5 NOT FOUND
1603 5 2203. 0.980
5 NQT FOUND
6 NOT FOUND
6 NOT FOUND
6 NOT FOUND
6 NOT FOUND
6 NOT FOUND
6 NOT FOUND
6 NOT FOUND
6 NOT FOUND
6 NOT FOUND
0.311
1.125
2.871
0.246
0.280
1.616
-------
30 apisano si $'! ue saaeaipui -
ZlO-3N3-Ua3d S2I3 = 9 #SI
210-3N3SJ18H3 OZI3 = S #SI
Oia-3N3aHiNVN3Hd 0913 =
-------
Data Reduced by: Date:
Data Reviewed by: \/ Date:
Data FUe: 30068105
OUANTERRA GC/HS TIC REPORT ( Part 1 )
Sample: T-MM5-4 1/3SA/1ML INST. ID: F16
Analyst: DAT Date Analyzed: 08/31/98 21:00
Run Factor: 3.00
Concentration
/ in Sample
|D # SCAN (UG/A)
rxirv 1 7n "*9n
lo
^
0V 222 350.
I NONANE OV vStfH ซ
3 285 43.
BENZALDEHYDE fr^- ^
CAS #
^VHIV, C^':K-^'
\>NjฃV\
111-84-2
jf
100-52-7
^
761 31. 629-59-4
T'ETRADECANE i^ 11
5 856 61 .
PENTADECANE
6 946 66.
NONADECANE
7 986 41 .
HEPTADECANE, 2,6-OIMETHY
8 1032 120.
HEPTADECANE, 2,6-DlMETHK
9 1113 45.
NONADECANE
10 1117 36.
NONADECANE
629-62-9
629-92-5
54105-67-8
54105-67-8
629-92-5
629-92-5
y
-------
190 29.
NONADECANE 0*
12 1236 36.
HCXADECANOIC ACID
629-92-5
13 1334 97.
UNKNOWN
00-00-0
14 1360 40.
UNKNOWN
15 1402 37.
TRICOSANE O r ( J(
17 1508 63.
UNKNOWN
00-00-0
638-67-5
31. 00-00-0
18 1529 58.
UNKNOWN
00-00-0
19 1587 120.
5-EICOSENE, (E)
74685-30-6
20 1662 42.
UNKNOWN
00-00-0
2X1688
UNKNOWN
32. 00-00-0
22 1804 63.
UNKNOWN
00-00-0
-------
23 1916 38. 7206-19-1
3-OCTADECENE, -
2A 1933 47. 00-00-0
UNKNOWN
2057 29. 00-00-0
NKNOWN
\
-------
DATA FILE: 30068105
QUANTERRA GC/MS TIC REPORT ( Part 2 )
CONCENTRATION = AREA(TIC)*CONC(IS)/AREA(IS)
#
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
FIT
956
986
975
960
965
963
957
972
939
941
971
975
881
725
890
891
772
913
974
916
646
799
930
677
704
PURITY
919
938
926
762
792
834
814
850
785
811
746
682
596
270
654
588
423
506
771
471
240
436
699
407
420
INT.
STD.
1
1
1
2
2
2
3
3
3
3
3
3
4
4
4
4
4
4
4
4
5
5
5
5
5
AMOUNT
AS ANALYZED
RT
1:53
2:28
3:10
8:27
9:31
10:31
10:58
11:28
12:22
12:25
13:14
13:44
14:50
15:07
15:35
16:19
16:46
17:00
17:39
18:29
18:46
20:03
21:18
21:30
22:52
RRT
0.321
0.420
0.539
0.919
1.034
1.143
0.908
0.950
1.025
1.029
1.096
1.138
0.860
0.877
0.904
0.946
0.972
0.986
1.023
1.072
0.947
1.012
1.075
1.085
1.154
AREA
915820.
976832.
120816.
86560.
171391.
185824.
134784.
391552.
144896.
116416.
92992.
118352.
144384.
58976.
55232.
45440.
93120.
85616.
177728.
62400.
37296.
73392.
44560.
54336.
33762.
HEIGHT
389859.
382976.
35462.
25764.
43553.
58432.
36544 .
70400.
41984.
38400.
30528.
27355.
22400.
5928.
10688.
8408.
9152.
10128.
31680.
6960.
3821.
5788.
9603.
5944.
4298.
(UG/ML )
108
115
14
10
20
21
13
40
14
11
9
12
32
13
12
10
20
19
39
14
10
21
12
15
9
.038
.236
.253
.201
.199
.900
.810
.118
.846
.928
.528
.126
.404
.236
.396
.198
.899
.214
.887
.004
.683
.023
.764
.565
.671
LIB
NB
NB
NB
NB
NB
NB
NB
NB
NB
NB
NB
NB
UK
UK
NB
UK
UK
UK
NB
UK
UK
UK
NB
UK
UK
LIB #
3241.
5159.
2017.
22530.
25997.
37465 .
37462.
37462.
37465 .
37465 .
37465 .
35182.
1.
1.
46161.
1.
1.
1.
39516.
1.
1.
1.
34410.
1.
1.
-------
Library Search Data: 30068105 # 170 Base m/z: 43
08/31/98 21:00:00 + 1:53 Cali: 30068105 # 3 RIC: 278528.
Sample: T-MM5-4 1/3SA/1ML INST. ID: F16
Conds.: UG/ML *1ML *100%/100% *(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
617 matched at least 6 of the 16 largest peaks in the unknown
Rank In. Name
1 3241 2-PENTANONE, 4-HYDROXY-4-METHYL-
2 5791 1,3-DIOXOLANE-2-METHANOL, 2,4-DIMETHYL-
3 3366 2-PENTANOL, 2,4-DIMETHYL-
4 3288 ACETIC ACID, 1,1-DIMETHYLETHYL ESTER
5 919 TERT-BUTYL HYDROPEROXIDE
6 5594 2-PROPANOL, 2-NITROSO-, ACETATE (ESTER)
7 3349 2-HEXANOL, 2-METHYL-
8 8432 2-HEXANONE, 3-HYDROXY-3,5-DIMETHYL-
9 8425 2-HEPTANONE, 3-HYDROXY-3-METHYL-
Rank
1
2
3
4
5
6
7
8
9
Formula
C6.H12.02
C6.H12.03
C7.H16.0
C6.H12.02
C4.H10.02
C5.H9.03.N
C7.H16.0
C8.H16.02
C8.H16.02
M.Wt
116
132
116
116
90
131
116
144
144
B.Pk
43
43
59
43
59
43
59
59
59
Purity
919
755
746
729
714
711
708
667
661
Fit
956
828
768
777
866
824
741
729
715
RFit
932
798
746
742
736
763
708
694
677
Rank
1
2
3
4
5
6
7
8
9
Ret.Time
B.P.Int.
US.Par.1
US.Par.2
C.A.S.
123-
53951-
625-
540-
75-
6931-
625-
6321-
13757-
#
42-2
43-2
06-9
88-5
91-2
04-0
23-0
14-8
91-0
ti ^ ~
U i 6,
-------
1000
SAMPLE
MID LIBRARY SEARCH
30068105 #
30068105 #
170
3
BASE M/Z: 43
RIC: 278528.
C6.H12.02
1000
M NT 116
B PK 43
RANK 1
* 3241
PUR 919
2-PENTANONE, 4-HYDROXY-4-METHYL-
.11.1 . ..'
r^-i I-*- , ' I1 1 1 1 i 1 . 1 .
1,3-DIOXOLANE-2-METHANOL, 2,4-DIMETHYL-
C6.H12.03
1000
M WT
B PK
132
43
RANK 2
ป 5791
PUR 755
C7.H16.0
1000
M WT 116
B PK 59
RANK 3
# 3366
PUR 746
2-PENTANOL, 2,4-DIMETHYL-
M/Z
50
100
150
200
250
CT
. i
C i
-------
Library Search Data: 30068105 # 222 Base m/z: 43
08/31/9821:00:00+ 2:28 Call: 30068105 # 3 R1C: 282112.
Sample: T-MM5-4 1/3SA/1ML 1NST. ID: F16
Conds.: UG/HL *1ML *100%/100% *(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
921 matched at least 7 of the 16 largest peaks in the unknown
Rank In.
Name
1 5159 NONANE
2 5151 HEPTANE, 3,4-DIMETHYL-
3 5141 HEPTANE. 2,4-DIMETHYL-
4 3086 HEXANE, 2,4-OtMETHYL-
5 3081 OCTANE
6 11607 UNDECANE
7 19015 DECANE, 2,5,6-TRIMETHYL-
8 5154 HEXANE, 4-ETHYL-2-METHYL-
9 19028 DECANE, 2,4,6-TRlMETHYL-
Rank
1
2
3
4
5
6
7
8
9
Formula
C9.H20
C9.H20
C9.H20
C8.H18
C8.H18
C11.H24
C13.H28
C9.H20
C13.H28
M.Ut 8
128
128
128
114
114
156
184
128
184
.Pk
43
43
43
43
43
43
57
57
43
Purity
938
912
892
884
870
867
866
856
853
Fit
986
940
944
956
945
926
906
907
884
RFit
938
912
893
894
893
905
876
856
898
Rank
1
2
3
4
5
6
7
8
9
Ret.Time
B.P.Int.
US.Par.1
US.Par.2
C.A.S.
111-
922-
2213-
589-
111-
1120-
62108-
3074
62108-
#
84-2
28-1
23-2
43-5
65-9
21-4
23-0
75-7
27-4
(J74
-------
1814
SAMPLE
MID LIBRARY SEARCH 1
CM
-------
Library Search
08/31/98 21:00:00 + 3:10
Sample: T-MM5-4 1/3SA/1ML
Conds.: UG/ML *1ML *100%/100%
Enhanced (S 15B 2N OT)
Data: 30068105 # 285
Cali: 30068105 # 3
INST. ID: F16
*(NA/NA )/1/3SA NA M
Base m/z: 77
RIC: 28832.
62231 spectra in LIBRARYNB searched for maximum PURITY
416 matched at least 5 of the 16 largest peaks in the unknown
Rank In.
Name
1 2017 BENZALDEHYDE
2 7284 BENZOYL CHLORIDE
3 2014 2.4-HEPTAD1EN-6-YNAL, (E,E)-
4 6466 ETHANONE, 2-HYDROXY-1-PHENYL-
5 13112 BENZOYL ISOTHIOCYANATE
6 6857 BENZENECARBOTHIOIC ACID
7 9645 BENZOYLFORM1C ACID
8 6111 1,2-BENZENEDICARBOXALDEHYDE
9 13359 BENZENEACETIC ACID, .ALPHA.-0X0-. METHYL ESTER
Rank
1
2
3
4
5
6
7
8
9
Formula
C7.H6.0
C7.H5.0.CL
C7.H6.0
C8.H8.02
C8.H5.0.N.S
C7.H6.0.S
C8.H6.03
C8.H6.02
C9.H8.03
M.Wt
106
140
106
136
163
138
150
134
164
B.Pk
77
105
105
105
105
77
105
105
105
Purity
926
825
805
793
784
779
775
773
773
Fit
975
889
854
842
835
865
849
825
846
RFit
941
825
810
812
790
805
800
908
791
Rank
1
2
3
4
5
6
7
8
9
Ret.Time
B.P.lnt.
US.Par.1
US.Par.2
C.A.S
100
98
7200
582
532
98
611
643
15206
, #
52-7
88-4
04-6
24-1
55-8
91-9
73-4
79-8
55-0
-------
MID LIBRARY SEARCH (LIBRARYNB) DATA: 30068105 # 285 BASE M/Z: 77
08/31/98 21:00:00 + 3:10 CALI: 30068105 # 3 RIC: 28832.
SAMPLE: T-MM5-4 1/3SA/1ML INST. ID: F16
CONDS.: UG/ML *1ML *100Z/100?i: *
1706
SAMPLE
C7.H6.0
1706 i
M WT 106
B PK 77
RANK 1
ป 2017
PUR 926
C7.H5.0.CI
1706
M WT 140
B PK 105
RANK 2
* 7284
PUR 825
C7.H6.0
1706 i
M WT 106
B PK 105
RANK 3
* 2014
PUR 805
M/Z
r
III 1
1 . , . . . . , . i . .
BENZALDEHYDE or vL,-
P
1 . . .....
30 40 50 60 70 80 90 100 110 12
CT
1
-------
Library Search Data: 30068105 # 761 Base m/z: 57
08/31/98 21:00:00 + 8:28 Cali: 30068105 # 3 RIC: 22976.
Sample: T-MM5-4 1/3SA/1ML INST. ID: F16
Conds.: UG/ML *1ML *100%/100% *(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
611 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 22530 TETRADECANE
2 19006 DECANE, 6-ETHYL-2-METHYL-
3 11607 UNDECANE
4 19007 DOOECANE, 3-METHYL-
5 19016 UNDECANE, 4,7-DIMETHYL-
6 42196 HEPTADECANE, 2,6,10,14-TETRAMETHYL-
7 15358 UNDECANE, 3-METHYL-
8 11612 NONANE, 2,5-DIMETHYL-
9 25997 PENTADECANE
Rank
1
2
3
4
5
6
7
8
9
Formula
C14.H30
C13.H28
C11.H24
C13.H28
C13.H28
C21.H44
C12.H26
C11.H24
C15.H32
M.Ut B.Pk Purity Fit RFit
198
184
156
184
184
296
170
156
212
43
57
43
57
43
57
57
57
57
762
755
737
734
727
727
724
724
722
960
975
980
927
938
927
934
887
932
773
755
737
738
727
760
728
724
753
Rank
1
2
3
4
5
6
7
8
9
Ret.Time
B.P.Int.
US.Par.1 US.Par.2
C.A.S. #
629-59-4
62108-21-8
1120-21-4
17312-57-1
17301-32-5
18344-37-1
1002-43-3
17302-27-1
629-62-9
O
-------
1343 -
SAMPLE
C14.H30
1343 i
M WT 198
B PK 43
RANK 1
ft 22530
PUR 762
C13.H28
1343 1
M WT 184
B PK 57
RANK 2
ft 19006
PUR 755
C11.H24
1343 -i
M WT 156
B PK 43
RANK 3
ft 11607
PUR 737
M/Z
1
MID LIBRARY SEARCH DATA: 30068105 ft 761 BASE M/Z: 57
08/31/98 21:00:00 + 8:28 CALI: 30068105 ft 3 RIC: 22976.
SAMPLE: T-MM5-4 1/3SA/1ML INST. ID: F16
CONDS.: UG/ML *1ML * 10072/100Z *
-------
Library Search Data: 30068105 # 856 Base m/z: 57
08/31/98 21:00:00 + 9:31 Cali: 30068105 # 3 R1C: 35840.
Sample: T-MM5-4 1/3SA/1HL INST. ID: F16
Conds.: UG/HL *1ML *100%/100X *(NA/NA )/1/3SA NA H
Enhanced (S 15B 2N OT)
62231 spectra in LIBRARYN8 searched for maximum PURITY
792 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 25997 PENTADECANE
2 22530 TETRADECANE
3 19006 DECANE, 6-ETHYL-2-METHYL-
4 15343 DODECANE
5 42196 HEPTADECANE, 2,6,10,14-TETRAMETHYL-
6 19007 DODECANE, 3-METHYL-
7 39681 1-IODOUNDECANE
8 15352 UNDECANE, 2-METHYL-
9 18990 UNDECANE, 2,9-DIMETHYL-
M.wt B.Pk Purity
Rank
1
2
3
4
5
6
7
8
9
Rank
1
2
3
4
5
6
7
8
9
Formula
C15.H32
C14.H30
C13.H28
C12.H26
C21.H44
C13.H28
C11.H23.I
C12.H26
C13.H28
Ret .Time
212
198
184
170
296
184
282
170
184
B.P.Int.
US.Par.1
57
43
57
57
57
57
57
43
57
US.Par.2
ity Fit
792 965
770 939
765 966
764 989
759 930
755 954
755 971
754 939
754 957
C.A.S. #
629-62-9
629-59-4
62108-21-8
112-40-3
18344-37-1
17312-57-1
4282-44-4
7045-71-8
17301-26-7
RFit
798
804
765
764
783
763
760
762
756
-------
MID LIBRARY SEARCH (LIBRARYNB) DATA:
08/31/98 21:00:00 + 9:31 CALI:
SAMPLE: T-MM5-4 1/3SA/1ML INST. ID: F16
CONDS. : UG/ML *1ML *100Z/100Z *
-------
Library Search Data: 30068105 # 946 Base m/z: 57
08/31/98 21:00:00 + 10:31 Cali: 30068105 # 3 RIC: 52608.
Sample: T-MM5-4 1/3SA/1ML INST. ID: F16
Cortds.: UG/ML *1ML *100X/100% "(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
360 matched at least 8 of the 16 largest peaks in the unknown
2,6-DIMETHYL-
2,6,10,14-TETRAMETHYL-
Rank In. Name
1 37465 NONADECANE
2 37462 HEPTADECANE
3 42196 HEPTADECANE
4 25997 PENTADECANE
5 15969 HYDROXYLAMINE, 0-DECYL-
6 25994 DODECANE, 2,6,11-TRIMETHYL-
7 26001 DODECANE, 2,7,10-TRIMETHYL-
8 19016 UNDECANE, 4,7-DIMETHYL-
9 22535 DODECANE, 4,6-DIMETHYL-
Rank
1
2
3
4
5
6
7
8
9
Formula
C19.H40
C19.H40
C21.H44
C15.H32
C10.H23.0.N
C15.H32
C15.H32
C13.H28
C14.H30
M.Ut
268
268
296
212
173
212
212
184
198
B.Pk
57
57
57
57
43
57
57
43
57
Purity
834
830
810
801
797
794
791
790
789
Fit
963
954
955
957
962
971
972
965
956
RFit
848
844
827
819
799
795
792
791
793
Rank
1
2
3
4
5
6
7
8
9
Ret.Time
B.P.Int.
US.Par.1
US.Par.2
C.A.S
629
54105
18344
629
29812
31295
74645
17301
61141
, #
92-5
67-8
37-1
62-9
79-1
56-4
98-0
32-5
72-8
-------
C19.H48
1024
M WT 268
B PK 57
RANK 1
# 37465
PUR 834
C19.H40
1024
M WT 268
B PK 57
RANK 2
# 37462
PUR 838
C21.H44
1024
M WT 296
B PK 57
RANK 3
# 42196
PUR 810
M/Z
MID LIBRARY SEARCH (LIBRARYNB) DATA:
88/31/98 21:88:88 + 10:31 CALI:
SAMPLE: T-MM5-4 1/3SA/1ML INST. ID: F16
CONDS.: UG/ML *1ML *100Z/100Z * V
1 1 1
NONADECANE
HEPTADECANE, 2,6-DIMETHYL-
1
ll
58
1
ll 1 1 -ll . - ., - |- -r - - T^T -I 1 1 1 <~
HEPTADECANE , 2,6/10,1 4-TETRAMETHYL-
i .1 it .. ,1 ., -- r- t- ,^-- , , . ,- , -
100 150 288 250
CT
ft-i
C '
-------
Library Search
08/31/98 21:00:00 + 10:58
Sample: T-MM5-4 1/3SA/1ML
Conds.: UG/ML *1ML *100%/100%
Enhanced (S 15B 2N OT)
Data: 30068105 # 986
Cali: 30068105 # 3
INST. ID: F16
*(NA/NA )/1/3SA NA M
Base m/z: 57
R1C: 33280.
62231 spectra in LIBRARYNB searched for maximum PURITY
644 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 37462 HEPTADECANE, 2,6-DlMETHYL-
2 37465 NONADECANE
3 42196 HEPTADECANE, 2,6,10,14-TETRAMETHYL-
4 19054 UNDECANE, 2,6-DIMETHYL-
5 22530 TETRADECANE
6 25997 PENTADECANE
7 19026 DECANE, 2,6,8-TRIMETHYL-
8 26001 DOOECANE, 2,7,10-TRIMETHYL-
9 22535 DODECANE, 4,6-DIMETHYL-
Rank
1
2
3
4
5
6
7
8
9
Formula
C19.H40
C19.H40
C21.H44
C13.H28
C14.H30
C15.H32
C13.H28
C15.H32
C14.H30
M.Ut B
268
268
296
184
198
212
184
212
198
.Pk
57
57
57
57
43
57
57
57
57
Purity
814
790
788
787
781
773
771
770
766
Fit
957
933
946
947
941
939
953
970
953
RFit
825
820
806
798
793
805
776
772
769
Rank
1
2
3
4
5
6
7
8
9
Ret.Time
B.P.Int.
US.Par.1
US.Par.2
C.A.S.
54105-
629-
18344-
17301-
629-
629-
62108-
74645-
61141-
#
67-8
92-5
37-1
23-4
59-4
62-9
26-3
98-0
72-8
>ฃ4
-------
MID LIBRARY SEARCH (LIBRARYNB)
08/31/98 21:00:00 + 10:58
SAMPLE: T-MM5-4 1/3SA/1ML INST. ID:
CONDS.: UG/ML *1ML * 100Z/100Z *
DATA: 30068105 # 986
CALI: 30068105 # 3
F16
HA M
BASE M/Z: 57
RIC: 33280.
1000
SAMPLE
C19.H40
1000
M WT 268
B PK 57
RANK 1
# 37462
PUR 814
C19.H40
1000
M WT 268
B PK 57
RANK 2
# 37465
PUR 790
C21.H44
1000
M WT 296
B PK 57
RANK 3
# 42196
PUR 788
M/Z
HEPTADECANE, 2,6-DIMETHYL-
ii
NONADECANE
1
II
ll
HEPTADECANE , 2,6,10,1 4-TETRAMETHYL-
II
50 100 150 200 250 300
f-o
c/i
-------
Library Search Data: 30068105 #1032 Base m/z: 57
08/31/98 21:00:00 + 11:29 Call: 30068105 # 3 R1C: 62400.
Sample: T-MM5-4 1/3SA/1HL 1NST. ID: F16
Conds.: UG/ML *1ML *100%/100% *(NA/NA )/1/3SA NA M
Enhanced (S 158 2N OT)
62231 spectra in L1BRARYNB searched for maximum PURITY
360 matched at least 8 of the 16 largest peaks in the unknown
2,6-DIMETHYL-
2,6,10,14-TETRAMETHYL-
Rank In. Name
1 37462 HEPTADECANE
2 42196 HEPTADECANE
3 37465 NONADECANE
4 32059 HEPTADECANE
5 46161 TR1COSANE
6 25991 DOOECANE, 2,6,10-TRIMETHYL-
7 26001 DOOECANE, 2,7,10-TRIMETHYL-
8 25997 PENTADECANE
9 22535 DOOECANE, 4,6-DIMETHYL-
Rank
1
2
3
4
5
6
7
8
9
Rank
1
2
3
4
5
6
7
8
9
Formula
C19.H40
C21.H44
C19.H40
C17.H36
C23.H48
C15.H32
C15.H32
C15.H32
C14.H30
Ret. Time
B.P.Int.
US.Par.1
M.Wt
268
296
268
240
324
212
212
212
198
B.Pk Purity Fit
57
57
57
57
43
57
57
57
57
US. Par. 2
850 972
822 963
816 948
788 925
785 901
783 958
781 959
778 938
778 954
C.A.S. #
54105-67-8
18344-37-1
629-92-5
629-78-7
638-67-5
3891-98-3
74645-98-0
629-62-9
61141-72-8
RFit
861
838
849
821
854
795
795
819
788
-------
MID LIBRARY SEARCH
08/31/98 21:00:00 + 11:29
SAMPLE: T-MM5-4 1/3SA/1ML INST. ID:
CONDS.: UG/ML *1ML *100Z/10072 *
-------
Library Search Data: 30068105 #1113 Base m/z: 57
08/31/9821:00:00+12:23 Cali: 30068105 # 3 RIC: 34816.
Sample: T-MM5-4 1/3SA/1ML INST. ID: F16
Conds.: UG/ML *1ML *100%/100% *(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
312 matched at least 8 of the 16 largest peaks in the unknown
Rank In. Name
1 37465 NONADECANE
2 42196 HEPTADECANE. 2,6,10,14-TETRAMETHYL-
3 25997 PENTADECANE
4 19016 UNDECANE, 4,7-DlMETHYl-
5 37462 HEPTADECANE, 2,6-DIMETHYL-
6 15969 HYDROXYLAMINE, 0-DECYL-
7 15352 UNDECANE, 2-METHYL-
8 18998 UNDECANE, 3,7-DlMETHYL-
9 46161 TRICOSANE
Rank
1
2
3
4
5
6
7
8
9
Rank
1
2
3
5
6
7
8
9
Formula
C19.H40
C21.H44
C15.H32
C13.H28
C19.H40
C10.H23.0.N
C12.H26
C13.H28
C23.H48
Ret .Time
B.P.Int.
US. Par.
M.Ut
268
296
212
184
268
173
170
184
324
,1
B.Pk Purity Fit RFit
57
57
57
43
57
43
43
43
43
US. Par. 2
785 939
783 940
777 951
777 958
775 924
775 958
767 955
766 954
759 893
C.A.S. #
629-92-5
18344-37-1
629-62-9
17301-32-5
54105-67-8
29812-79-1
7045-71-8
17301-29-0
638-67-5
829
811
809
777
815
785
773
770
844
-------
MID LIBRARY SEARCH
-------
Library Search Data: 30068105 #1117 Base m/z: 57
08/31/98 21:00:00 + 12:25 Cali: 30068105 # 3 RIC: 29952.
Sample: T-MM5-4 1/3SA/1HL INST. ID: F16
CondS.: UG/ML *1ML *100%/100X *(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
774 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 37465 NONADECANE
2 37462 HEPTADECANE, 2,6-DIMETHYL-
3 42196 HEPTADECANE, 2,6,10,14-TETRAMETHYL-
4 25991 DOOECANE, 2,6,10-TR1METHYL-
5 26001 DOOECANE, 2,7,10-TRIMETHYL-
6 37466 PENTADECANE, 2,6,10,14-TETRAMETHYL-
7 29264 TRIDECANE, 5-PROPYL-
8 32059 HEPTADECANE
9 46161 TR1COSANE
M.Ut B.Pk Purity Fit RFit
Rank
1
2
3
4
5
6
7
8
9
Formula
C19.H40
C19.H40
C21.H44
C15.H32
C15.H32
C19.H40
C16.H34
C17.H36
C23.H48
268
268
296
212
212
268
226
240
324
57
57
57
57
57
71
57
57
43
811
808
788
782
780
779
775
770
770
941
932
923
958
959
924
928
909
888
838
819
809
784
780
798
777
813
835
Rank
1
2
3
A
5
6
7
8
9
Ret.Time
B.P.Int.
US.Par.1
US.Par.2
C.A.S,
629-
54105-
18344-
3891-
74645-
1921-
55045-
629-
638-
#
92-5
67-8
37-1
98-3
98-0
70-6
11-9
78-7
67-5
-------
MID LIBRARY SEARCH /l/3SA NA M
ENHANCED | ' " '| ' I"' ' * * f ป I * f 1 ' 1 1 ' T- - | T --- - T- - T - T - v r - -, . , , ,
HEPTADECANE , 2,6,10,1 4-TETRAMETHYL-
II
-i ! H> i *r rซ 1 | i i i 1 i i i ' i - ' "- f - - i
50 100 150 200 250
o
-------
Library Search Data: 30068105 #1190 Base m/z: 57
08/31/98 21:00:00 + 13:14 Cali: 30068105 # 3 RIC: 26400.
Sample: T-MM5-4 1/3SA/1ML INST. ID: F16
Conds.: UG/HL *1ML *100%/100% *(NA/NA )/1/3SA NA M
Enhanced (S 158 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
294 matched at least 8 of the 16 largest peaks in the unknown
Rank In. Name
1 37465 NONADECANE
2 37462 HEPTADECANE, 2,6-DlMETHYL-
3 46161 TRICOSANE
4 42196 HEPTADECANE, 2,6,10,14-TETRAMETHYL-
5 15969 HYDROXYLAMINE, 0-DECYL-
6 25997 PENTADECANE
7 15353 2,6-DIMETHYLDECANE
8 19016 UNDECANE, 4,7-DIMETHYL-
9 32059 HEPTADECANE
Rank
1
2
3
4
5
6
7
8
9
Rank
1
2
3
4
5
6
7
8
9
Formula
C19.H40
C19.H40
C23.H48
C21.H44
C10.H23.0.N
C15.H32
C12.H26
C13.H28
C17.H36
Ret .Time
B.P.Int.
US.Par.1
M.Ut
268
268
324
296
173
212
170
184
240
I
B.Pk Purity Fit RFit
57
57
43
57
43
57
43
43
57
US. Par. 2
746 971
721 941
701 902
700 946
699 961
698 954
689 932
684 950
676 914
C.A.S. #
629-92-5
54105-67-8
638-67-5
18344-37-1
29812-79-1
629-62-9
13150-81-7
17301-32-5
629-78-7
757
743
770
722
702
722
689
684
714
-------
1077
SAMPLE
MID LIBRARY SEARCH DATA:
08/31/98 21:00:00 + 13:14 CALI:
SAMPLE: T-MM5-4 1/3SA/1ML INST. ID: F16
CONDS.: UG/ML *1ML *100Z/1007. */l/3SA NA M
ENHANCED
30068105 #1190
30068105 # 3
BASE M/Z: 57
RIC: 26400.
C19.H40
1077
M WT 268
B PK 57
RANK 1
# 37465
PUR 746
NONADECAHE
C19.H40
1077 I
M WT 268
B PK 57
RANK 2
# 37462
PUR 721
HEPTADEC ANE , 2 , 6-D I METHYL-
ll
-i, . ll , , , J L , -ill , . ,1 , , ,ซ ..ป.. | '* . i t '"' 1 '"' 1 I1 1 ''* I "T- *-ป" | ^-.I. . | , , , ----- . - ,
C23.H48
1077 i
M WT 324
B PK 43
RANK 3
# 46161
PUR 701
M/Z
TRICOSANE
|
L- i ^
50
||
U-, . IfJ
ll || .1 .. r ., .- ... t .. ,- _ -| , .-. . i- . , . . . | , , , . , , r *
100 150 200 250 300
CT
f*.
-------
Library Search Data: 30068105 #1236 Base m/z: 73
08/31/98 21:00:00 + 13:45 Cali: 30068105 # 3 R1C: 23072.
Sample: T-MM5-4 1/3SA/1ML 1NST. ID: F16
Conds.: UG/ML *1ML *100%/100% *(NA/NA )/1/3SA NA M
Enhanced (S 158 2N OT)
62231 spectra in L1BRARYNB searched for maximum PURITY
747 matched at least 6 of the 16 largest peaks in the unknown
Rank In. Name
1 35182 HEXADECANOIC ACID
2 37913 GLYC1NE, N-METHYL-N-(I-OXODCOECYL)-
3 40669 DODECANAMIDE, N,N-B1S(2-HYDROXYETHYL)-
4 22949 DODECANOIC ACID
5 26351 TR1DECAN01C ACID
6 29642 TETRADECANOIC ACID
7 40184 OCTADECANOIC ACID
8 19469 UNDECANOIC ACID
9 15784 DECANOIC ACID
Rank Formula M.Ut B.Pk Purity Fit RFit
1 C16.H32.02 256 43 682 975 688
2 C15.H29.03.N 271 73 588 974 588
3 C16.H33.03.N 287 73 567 959 573
4 C12.H24.02 200 60 542 916 566
5 C13.H26.02 214 73 542 887 558
6 C14.H28.02 228 73 532 871 589
7 C18.H36.02 284 43 514 753 665
8 C11.H22.02 186 60 506 912 531
9 C10.H20.02 172 60 504 939 506
Rank Ret.Time B.P.Int. US.Par.1 US.Par.2 C.A.S. #
1 57-10-3
2 97-78-9
3 120-40-1
4 143-07-7
5 638-53-9
6 544-63-8
7 57-11-4
8 112-37-8
9 334-48-5
-------
MID LIBRARY SEARCH (LIBRARYNB) DATA: 30068105 #1236 BASE M/Z: 73
08/31/98 21:00:00 + 13:45 CALI: 30068105 # 3 RIC: 23072.
SAMPLE: T-MM5-4 1/3SA/1ML INST. ID: F16
CONDS.: UG/ML *1ML * 100Z/1 002 */l/3SA NA M
ENHANCED
1311 -
SAMPLE
C16.H32.0
1311
M WT 256
B PK 43
RANK 1
# 35182
PUR 682
C15.H29.0;
1311
M WT 271
B PK 73
RANK 2
* 37913 '
PUR 588
C16.H33.0;
1311 -i
M WT 287
B PK 73
RANK 3
# 40669
PUR 567
M/Z
1 1,1
nlil 1 l III i 1 . ... i . .1 . . i. . i .H. i.
2 HEXADECANOIC ACID
1 II
3.N
i
||
3.N
ll
50
||
1 1 ll i 1 i i | ... I. i.
GLYC I NE , N-METHYL-N- < 1 -OXODODECYL ) -
ill 1 1 1 1
DODECANAM I DE , N , N-B I S < 2-HYDROXYETHYL ) -
II
ill I 1 1 , 1 ,
100 150 200 250
C/1
-------
Library Search Data: 30068105 #1334 Base m/z: 57
08/31/98 21:00:00 + 14:50 Cali: 30068105 # 3 RIC: 18240.
Sample: T-MM5-4 1/3SA/1ML INST. ID: F16
Conds.: UG/ML *1ML *100%/100% *(NA/NA )/1/3SA NA M
Enhanced (S 158 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
439 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 37462 HEPTADECANE, 2,6-DIMETHYL-
2 37456 2-METHYLOCTADECANE
3 37465 NONADECANE
4 19523 1-DECANOL, 2-ETHYL-
5 14793 1-UNDECENE, 4-METHYL-
6 37458 OCTADECANE, 2-METHYL-
7 29263 HEXADECANE
8 46161 TRICOSANE
9 42481 OXIRANE, [(HEXADECYLOXY)METHYL]-
M.Wt B.Pk Purity Fit RFit
Rank
1
2
3
4
5
6
7
8
9
Rank
1
2
3
4
5
6
7
8
9
Formula
C19.H40
C19.H40
C19.H40
C12.H26.0
C12.H24
C19.H40
C16.H34
C23.H48
C19.H38.02
Ret. Time
268
268
268
186
168
268
226
324
298
57
43
57
57
43
43
57
43
57
596
593
585
582
581
577
577
577
576
881
901
919
931
957
864
899
863
872
632
640
628
593
581
639
621
659
583
B.P.Int.
US.Par.1
US.Par.2
C.A.S. #
54105-67-8
629-92-5
21078-65-9
74630-39-0
1560-88-9
544-76-3
638-67-5
15965-99-8
-------
MID LIBRARY SEARCH (LIBRARYNB) DATA: 30068105 #1334 BASE M/Z: 57
08/31/98 21:00:00 + 14:50 CALI: 30068105 # 3 RIC: 18240.
SAMPLE: T-MM5-4 1/3SA/1ML INST. ID: F16
CONDS. : UG/ML *1ML *1 00Z/100Z */l/3SA NA M
ENHANCED
1141 1
SAMPLE
C19.H40
1141 -i
M WT 268
B PK 57
RANK 1
* 37462
PUR 596
C19.H40
1141 I
M WT 268
B PK 43
RANK 2
# 37456
PUR 593
C19.H40
1141 i
M WT 268
B PK 57
RANK 3
# 37465 1
PUR 585
i
0~"^'
1 ill 1 I.L. 1 . 1. . .... . . .1 - , -| - ." - - ! - -M- , * 1 -*
HEPTADECANE , 2,6-DIMETHYL-
, i il . . .. ... - , , ,
1 r-"l 1 ' '| ?**- 1 -"i f " 'I11 ' ' | 1 i i .,-,-.. i
2-METHYLOCTADECANE
1
" i H
i ,| . i , . , ... ... , , ^ , _,
NONADECANE
.^-^U . .nl. , ...i ...... i' i '
M/Z
50
100
150
200
250
CT
-------
Library Search Data: 30068105 #1360 Base m/z: 57
08/31/98 21:00:00 + 15:08 Call": 30068105 # 3 RIC: 3440.
Sample: T-MM5-4 1/3SA/1ML INST. ID: F16
Conds.: UG/ML *1ML *100%/100% *(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
144 matched at least 5 of the 16 largest peaks in the unknown
Rank In. Name
1 16268 PROPANE, 1,1'-[ETHYLIDENEBIS(OXY)]B1S[2-METHYL-
2 3365 2-PENTANOL, 4,4-DIMETHYL-
3 13863 PHOSPHINOUS CHLORIDE, TERT-BUTYLISOPROPYL-
4 7691 BUTANE, 2-AZIDO-2,3,3-TRIMETHYL-
5 38965 PHENOL, 2,6-815(1,1-DIMETHYLETHYL)-4-METHYL-, METHYLCARBAMATE
6 3052 OXIRANE, (2,2-DIMETHYLPROPYL)-
7 5791 1.3-DIOXOLANE-2-METHANOL, 2,4-DIMETHYL-
8 5551 Dl-SEC-BUTYL ETHER
9 29529 THIOPHENE, 2,5-BlS(1,1-DIHETHYLETHOXY)-
Rank
1
2
3
4
5
6
7
8
9
Formula
C10.H22.02
C7.H16.0
C7.H16.CL.P
C7.H15.N3
C17.H27.02.N
C7.H14.0
C6.H12.03
C8.H18.0
C12.H20.02.S
M.Ut
174
116
166
141
277
114
132
130
228
B.Pk
57
57
57
57
205
57
43
45
41
Purity
270
252
229
228
221
214
213
212
207
Fit
725
722
707
753
521
741
697
628
700
RFit
292
295
243
264
308
274
235
252
282
Rank
1
2
3
4
5
6
7
8
9
Ret.Time
B.P.Int.
US.Par.1
US.Par.2
C.A.S.
5669-
6144-
29949-
51677-
1918-
2245-
53951-
6863-
55162-
#
09-0
93-0
66-4
41-9
11-2
29-6
43-2
58-7
43-1
-------
MID LIBRARY SEARCH CLIBRARYNB) DATA:
08/31/98 21:00:00 + 15:08 CALI:
SAMPLE: T-MM5-4 1/3SA/1ML INST. ID: F16
CONDS.: UG/ML *1ML * 100Z/1 002 *
30068105 #1360
30068105 # 3
BASE M/Z: 57
RIC: 3440.
1883
SAMPLE
C1Q.H22.0
1883 -
M WT 174
B PK 57
RANK 1
# 16268
PUR 270
C7.H16.0
1883 1
M WT 116
B PK 57
RANK 2
# 3365 '
PUR 252
C7.H16.CL
1883 i
M WT 166
B PK 57
RANK 3
# 13863 '
PUR 229
2
1,
r
r
i 1
r
P
r
I
. i
1 1. . i .1. J i . , , . . i i i 1 ... . 1
PROPANE , 1 , 1' - C ETHYL I DEHEB I S < OXY > ] B I S C 2-METHYL-
L
,
2-PENTANOL , 4 , 4-D I METHYL-
iJi
,1
PHOSPHINOUS CHLORIDE, TERT-BUTYL I SOPROPYL-
1
i ... . i..
M/Z
50
100
150
200
250
cr
r-
-------
Library Search Data: 30068105 #1402 Base m/z: 57
08/31/98 21:00:00 + 15:36 Cali: 30068105 # 3 RIC: 10224.
Sample: T-MM5-4 1/3SA/1ML INST. ID: F16
Conds.: UG/ML *1ML *100%/100% *(NA/NA )/1/3SA HA M
Enhanced (S 158 2N OT)
62231 spectra in L1BRARYNB searched for maximum PURITY
488 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 46161 TRICOSANE
2 37462 HEPTADECANE, 2,6-DlMETHYL-
3 49555 PENTACOSANE
4 37465 NONADECANE
5 42197 HENEICOSANE
6 58739 PENTATRIACONTANE
7 42196 HEPTADECANE, 2,6,10,14-TETRAMETHYL-
8 42192 HEPTADECANE, 2,6,10,15-TETRAMETHYL-
9 39858 EICOSANE
Rank
1
2
3
4
5
6
7
8
9
Formula
C23.H48
C19.H40
C25.H52
C19.H40
C21.H44
C35.H72
C21.H44
C21.H44
C20.H42
M.Ut
324
268
352
268
296
492
296
296
282
B.Pk
43
57
43
57
57
57
57
57
57
Purity
654
653
651
635
633
627
625
612
612
Fit
890
895
870
914
879
882
877
885
852
RFit
721
688
734
684
689
698
671
661
706
Rank
1
2
3
4
5
6
7
8
9
Ret.Time
B.P.lnt.
US.Par.1
US.Par.2
C.A.S
638
54105
629
629
629
630
18344
54833
112
#
67-5
67-8
99-2
92-5
94-7
07-9
37-1
48-6
95-8
IOC
-------
MID LIBRARY SEARCH
08/31/98 21:00:00 + 15:36
SAMPLE: T-MM5-4 1/3SA/1ML INST. ID:
CONDS.: UG/ML *1ML *100Z/100Z *
-------
Library Search
08/31/98 21:00:00 + 16:19
Sample: T-MM5-4 1/3SA/1ML
Conds.: UG/ML *1HL *100%/100%
Enhanced (S 15B 2N OT)
Data: 30068105 #1467
Cali: 30068105 * 3
INST. ID: F16
*
-------
1239 i
SAMPLE
MID LIBRARY SEARCH CLIBRARYHB)
08/31/98 21:00:00 + 16:19
SAMPLE: T-MM5-4 1/3SA/1ML INST. ID:
CONDS.: UG/ML *1ML * 100Z/1 002 *
-------
Library Search Data: 30068105 #1508 Base m/z: 59
08/31/98 21:00:00 + 16:46 Cali: 30068105 # 3 RIC: 7352.
Sample: T-MM5-4 1/3SA/1ML INST. ID: F16
Conds.: UG/ML *1ML *100%/100% *(NA/NA )/1/3SA NA M
Enhanced (S 158 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
179 matched at least 6 of the 16 largest peaks in the unknown
Rank In. Name
1 24247 2-PROPANOL,
2 20265 3-HEXANOL,
3 16192 2-PROPANOL,
4 20626 2-PROPANOL,
5 9228 1-PROPANOL,
1 - [2- (2-METHOXY- 1 -METHYLETHOXY ) - 1 -METHYLETHOXY] -
1,5-DIMETHOXY-2,4-DIMETHYL-
1-[1 -METHYL -2- (2-PROPENYLOXY)ETHOXYJ-
1,1'- [( 1 -METHYL -1,2-ETHANED I YL)BIS(OXY)] BI S-
2-(2-METHOXYPROPOXY)-
6 3522 2,3-BUTANEDIOL, 2,3-DlMETHYL-
7 8432 2-HEXANONE,
8 9235 1-PROPANOL,
9 5832 2-PROPANOL,
Rank Formula
1 C10.H22.04
2 C10.H22.03
3 C9.H18.03
4 C9.H20.04
5 C7.H16.03
6 C6.H14.02
7 C8.H16.02
8 C7.H16.03
9 C7.H16.02
Rank Ret. Time
1
2
3
k
5
6
7
8
9
3-HYDROXY-3.5-D [METHYL-
S' (2-METHOXY- 1 -METHYLETHOXY) -
1-(1-METHYLPROPOXY)-
M.Wt B.Pk Purity Fit
206 59 423 772
190 59 423 782
174 59 421 756
192 59 404 794
148 59 397 799
118 59 384 901
144 59 378 922
148 59 378 740
132 43 375 689
B.P.Int. US. Par. 1 US. Par. 2 C.A.S. #
20324-33-8
13897-22-8
55956-25-7
1638-16-0
13588-28-8
76-09-5
6321-14-8
55956-21-3
53907-95-2
RFit
466
466
441
427
414
391
385
388
400
i (i r /
A. v.' ^ -.1
-------
1000
SAMPLE
MID LIBRARY SEARCH (LIBRARYNB)
08/31/98 21:00:00 + 16:46
SAMPLE: T-MM5-4 1/3SA/1ML INST. ID:
CONDS.: UG/ML *1ML *100Z/1002 *
F16
NA M
DATA: 30068105 #1508
CALI: 30068105 # 3
BASE M/Z: 59
RIC: 7352.
f
C10.H22.04
1000
M WT 206
B PK 59
RANK 1
# 24247
PUR 423
2-PROPANOL, 1 -C 2- (2-METHOXY-l -METHYLETHOXY >-l -METHYLETHOXY]-
U-J
.
,L
C10.H22.03
1000
M WT 190
B PK 59
RANK 2
# 20265
PUR 423
3-HEXANOL, l,5-DIMETHOXY-2,4-DIMETHYL-
C9.H18.03
1000
M WT 174
B PK 59
RANK 3
# 16192
PUR 421
M/Z
2-PROPANOL, 1 -Cl -METHYL-2- (2-PROPENYLOXY > ETHOXY ]-
i ii
| f 1.1
50
100
150
200
250
300
C'
("
C. ซ
-------
Library Search
08/31/98 21:00:00 + 17:00
Sample: T-MM5-4 1/3SA/1ML
Conds.: UG/ML *1ML *100%/100%
Enhanced (S 15B 2N OT)
Data: 30068105 #1529
Cali: 30068105 # 3
INST. ID: F16
*(NA/NA )/1/3SA NA M
Base m/z:
R1C:
59
8976.
62231 spectra in LIBRARYNB searched for maximum PURITY
562 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 37462 HEPTADECANE, 2.6-DIMETHYL-
2 37465 NONADECANE
3 42196 HEPTADECANE, 2,6,10,14-TETRAMETHYL-
4 46161 TRICOSANE
5 3000 OXIRANE, 2.2-DIMETHYL-3-PROPYL-
6 19515 5,9-DIMETHYL-3-DECANOL
7 25991 DODECANE, 2,6,10-TRIMETHYl-
8 32059 HEPTADECANE
9 25997 PENTADECANE
Rank
1
2
3
4
5
6
7
8
9
Formula
C19.H40
C19.H40
C21.H44
C23.H48
C7.H14.0
C12.H26.0
C15.H32
C17.H36
C15.H32
M.Wt
268
268
296
324
114
186
212
240
212
B.Pk
57
57
57
43
43
57
57
57
57
Purity
506
500
497
496
488
481
479
478
476
Fit
913
915
913
871
860
837
918
888
915
RFit
526
530
516
556
508
521
484
518
505
Rank
1
2
3
4
5
6
7
8
9
Ret.Time
B.P.lnt.
US.Par.1
US.Par.2
C.A.S. #
54105-67-8
629-92-5
18344-37-1
638-67-5
17612-35-0
3891-98-3
629-78-7
629-62-9
10
-------
MID LIBRARY SEARCH CLIBRARYNB) DATA:
08/31/98 21:00:00 + 17:00 CALI:
SAMPLE: T-MM5-4 1/3SA/1ML INST. ID: F16
CONDS.: UG/ML *1ML * 100Z/1 QQ7. *
30968165 #1529
30068105 # 3
BASE M/Z: 59
RIC: 8976.
1000 I
SAMPLE
C19.H40
1000 I
M WT 268
B PK 57
RANK 1
# 37462
PUR 506
C19.H40
1000 i
M WT 268
B PK 57
RANK 2
# 37465
PUR 500
,|
(
ll
,1,
\\fJ**~^'
i i. . .1.1. .1 1 ... ... . - -
HEPTADECANE, 2,6-DIMETHYL-
li
. i ii ... ... ... .. ... .. ...
'-i T r ซ 1 ] 1 ' i 1 "i 1 1 ' ' ' ' ' i
NONADECANE
1
. . II . i.l. . .... i i '
C21.H44
1000 1
M WT 296
B PK 57
RANK 3
# 42196
PUR 497
M/Z
HEPTADECANE , 2,6,10,1 4-TETRAMETHYL-
1
ll
II
IU_, , |U_, . If . p-H , . , . 1 , . 1 . 1 i 1 ' 1 1 1 T ........ . . - ,
50 100 150 200 250 300
f)
-------
Library Search Data: 30068105 #1587 Base m/z: 43
08/31/98 21:00:00 + 17:39 Cali: 30068105 # 3 RIC: 27744.
Sample: T-MM5-4 1/3SA/1ML INST. ID: F16
Conds.: UG/ML *1ML *100%/100% *(NA/NA )/1/3SA NA M
Enhanced (S 158 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
965 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 39516 5-EICOSENE, (E)-
2 39515 9-EICOSENE, (E)-
3 34410 3-OCTADECENE, (E)-
4 37062 1-NONADECENE
5 28776 CYCLOHEXADECANE
6 34418 9-OCTADECENE, (E)-
7 34411 5-OCTADECENE,
-------
MID LIBRARY SEARCH DATA:
08/31/98 21:80:00 + 17:39 CALI:
SAMPLE: T-MM5-4 1/3SA/1ML INST. ID: FIG
CONDS.: UG/ML *1ML *100Z/10072 *
30068105 #1587
30068105 # 3
BASE M/Z: 43
RIC: 27744.
1112
SAMPLE
C20.H40
1112 I
M WT 280
B PK 55
RANK 1
# 39516
PUR 771
C20.H40
1112 i
M WT 280
B PK 55
RANK 2
# 39515
PUR 768
C18.H36
1112 I
M WT 252
B PK 69
RANK 3
# 34410
PUR 766
M/Z
i
, ,
L^JJ , j~
il
\ i
ll ,1
ii j ii .. ili . ..ii.. ....... . ... . i-
5-EICOSENE, - 4 ^^^JL^/
1
II ll , I.
J 1 MJ | ปt* 1 "'1 1 i | ' 1 ' 1 1 1 1 1 1 " ' ' | ' ' ' ' - I '
9-EICOSENE, -
1 i1 ' i ^
ll
i 1. .. .. .. .. ... .. .. . ~
J ,__ l^J 1 . | 1" 1 ' i 1 1 ' 1 > ' ' - T -!
3-OCTADECENE, -
ll
i i, .. .. .. ..
50 100 150 200 250
-------
Library Search Data: 30068105 #1662 Base m/z: 59
08/31/98 21:00:00 + 18:29 Cali: 30068105 # 3 R1C: 5128.
Sample: T-MM5-4 1/3SA/1ML INST. ID: F16
Conds.: UG/ML *1ML *100%/100% *(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
62231 spectra in L1BRARYNB searched for maximum PURITY
707 matched at least 5 of the 16 largest peaks in the unknown
Rank In.
1 1909
2 20626
3 9235
4 24247 2
5 36537 2
6 6083
7 9228 1
8 16192 2
9 12856 2
Name
PROPANOL,
1-METHOXY-2-METHYL-
2
2-PROPANOL, 1,1'-[(1-METHYL-1,2-ETHANEDIYL)BIS(OXY)]BIS-
1-PROPANOL,
2-
2-(2-METHOXY-1-METHYLETHOXY)-
PROPANOL, 1 -[2-(2-METHOXY-1-METHYLETHOXY)-1-METHYLETHOXY]
5,8,11-TETRAOXATETRADECAN-13-OL, 4,7,10-TRIMETHYL-
PROPANOL, 1,1'-OXYB1S-
PROPANOL, 2-C2-METHOXYPROPOXY)-
PROPANOL, 1-[1-METHYL-2-(2-PROPENYLOXY)ETHOXY] -
PROPANOL, 1-(2-ETHOXYPROPOXY)-
Rank
1
2
3
4
5
6
7
Rank
1
2
3
4
5
6
7
8
9
Formula
C5.H12.02
C9.H20.04
C7.H16.03
C10.H22.04
C13.H28.05
C6.H14.03
C7.H16.03
C9.H18.03
C8.H18.03
Ret.Time
B.P.Int.
US.Par.1
M.Wt
104
192
148
206
264
134
148
174
162
I
B.Pk Purity Fit RFit
59
59
59
59
59
59
59
59
59
US. Par. 2
471 916
453 812
448 773
447 757
441 705
440 886
439 776
438 746
436 732
C.A.S. #
3587-64-2
1638-16-0
55956-21-3
20324-33-8
20324-34-9
110-98-5
13588-28-8
55956-25-7
10143-32-5
491
475
455
513
530
447
467
466
482
1U1C
-------
MID LIBRARY SEARCH (LIBRARYNB) DATA: 30068105 #1804 BASE M/Z: 59
08/31/98 21:00:00 + 20:04 CALI: 30068105 tt 3 RIC: 4592.
SAMPLE: T-MM5-4 1/3SA/1ML INST. ID: F16
CONDS. : UG/ML *1ML *100Z/100Z * - 1 -METHYLETHOXY ] -
. 1. .. .. .
BUTANOIC ACID, 4-ETHOXY-, METHYL ESTER
r
H .
..ll 1.
50 100 150 200 250
-------
Library Search Data: 30068105 #1916 Base m/z:
08/31/98 21:00:00 + 21:19 Cali: 30068105 # 3 R1C:
Sample: T-MM5-4 1/3SA/1ML 1NST. ID: F16
Conds.: UG/ML *1ML *100%/100% *(NA/NA J/1/3SA NA M
Enhanced (S 15B 2N OT)
62231 spectra in L1BRARYNB searched for maximum PURITY
950 matched at least 7 of the 16 largest peaks in the unknown
A3
8736.
Rank In. Name
1 34410 3-OCTADECENE, (E)-
2 34418 9-OCTADECENE. (E)-
3 34411 5-OCTADECENE, (E)-
4 39515 9-E1COSENE, (E)-
5 39516 5-E1COSENE, (E)-
6 26416 4-TETRADECANOL
7 31653 1-HEPTADECENE
8 37062 1-NONADECENE
9 40232 1-NONADECANOL
Rank
1
2
3
4
5
6
7
8
9
Formula
C18.H36
C18.H36
C18.H36
C20.H40
C20.H40
C14.H30.0
C17.H34
C19.H38
C19.H40.0
M.Ut
252
252
252
280
280
214
238
266
284
B.Pk
69
55
55
55
55
43
55
97
55
Purity
699
697
695
693
691
689
687
687
684
Fit
930
927
925
942
939
955
933
933
965
RFit
723
719
718
717
716
711
710
722
703
Rank
1
2
3
4
5
6
7
8
9
Ret.Time
B.P.Int.
US.Par.1
US.Par.2
C.A.S
7206
7206
7206
74685
74685
1653
6765
18435
1454
#
19-1
25-9
21-5
29-3
30-6
33-4
39-5
45-5
84-8
1012
-------
MID LIBRARY SEARCH (LIBRARYNB) DATA:
08/31/98 21:00:00 + 21:19 CALI:
SAMPLE: T-MM5-4 1/3SA/1ML INST. ID: F16
CONDS.: UG/ML *1ML *100Z/1002 *^
Cfr^
ll
ll ,1
ll ,1
o^
ll 1 ll 1. ..Illl .1 1 ..... . 1
3-OCTADECENE, '(E)- Q < ^<*^-t/
1
I,
ll
1 1.
9-OCTADECENE, -
1
1
1
5-OCTADECENE, -
|
1
ll
1 I,
M/Z
50
100
150
200
250
-------
Library Search
08/31/98 21:00:00 + 21:30
Sample: T-MM5-4 1/3SA/1ML
Conds.: UG/ML *1ML *100%/100%
Enhanced (S 15B 2N OT)
Data: 30068105 #1933
Cali: 30068105 # 3
INST. ID: F16
*(NA/NA )/1/3SA NA M
Base m/z: 59
RIC: 5008.
62231 spectra in LIBRARYNB searched for maximum PURITY
705 matched at least 5 of the 16 largest peaks in the unknown
Rank In. Name
1 59575 1S,20S-BICYCLO[18.16.0]-3,6,9,12,15,18,21,24,27,30,33,36-DOOECAOXAH*
2 41712 3,6,9,12,15-PENTAOXANONADECAN-1-OL
3 33841 3,6,9,12-TETRAOXAHEXADECAN-1-OL
4 5825 2-PROPANOL, 1-(2-METHYLPROPOXY)-
5 16648 1-BUTOXYETHOXY-2-PROPANOL
6 5832 2-PROPANOL, 1-<1-METHYLPROPOXY)-
7 31381 6-0-METHYL-2,4-METHYLENE-.BETA.-SEDOHEPTITOL
8 16651 D1ETHYLENE GLYCOL TERT-BUTYL ETHER METHYL ETHER
9 1909 2-PROPANOL, 1-METHOXY-2-METHYL-
Rank
1
2
3
4
5
6
7
8
9
Formula
C24.H46.012
C14.H30.06
C12.H26.05
C7.H16.02
C9.H20.03
C7.H16.02
C9.H18.07
C9.H20.03
C5.H12.02
Rank
1
2
3
4
5
6
7
8
9
M.Wt
526
294
250
132
176
132
238
176
104
B.Pk
73
45
45
57
57
43
58
57
59
Purity
407
381
381
380
378
376
372
372
371
Fit
677
704
696
798
864
795
676
840
904
RFit
475
423
437
410
395
402
431
389
382
Ret.Time
B.P.Int.
US.Par.1
US.Par.2
C.A.S. #
1786-94-3
1559-34-8
23436-19-3
124-16-3
53907-95-2
52788-79-1
3587-64-2
1014
-------
MID LIBRARY SEARCH CLIBRARYNB) DATA: 30068105 #1933 BASE M/Z: 59
08/31/98 21:00:00 + 21:30 CALI: 30068105 # 3 RIC: 5008.
SAMPLE: T-MM5-4 1/3SA/1ML INST. ID: F16
CONDS.: UG/ML *1ML * 100Z/100Z *
1188 -
SAMPLE
r "i
I
o^'
C24.H46.012 1S,20S-BICYCLOC18. 16. 03-3, 6, 9, 12, 15, 18, 2 1,24, 27, 30, 33, 36-DODECAOXAHEX!
1188 i
M WT 526
B PK 73
RANK 1
tป 59575
PUR 407
r t
1 II
C 1 4 . H30 . 06 3,6,9,12,1 5-PENTAOXANONADECAN- 1 -OL
1188
M WT 294
B PK 45
RANK 2
* 41712
PUR 381
r
T
ii li . .1 . . . i
C 1 2 . H26 . 05 3,6,9,1 2-TETRAOXAHEXADECAN- 1 -OL
1188
M WT 250
B PK 45
RANK 3
# 33841
PUR 381
M/Z
r
"
59
| |t Ji - I . .". , i . -. - . - . r i .,-.-,-.-..-...-.-,.... | i i
100 150 200 250 300 350 400 450 500
0
("1
-------
Library Search Data: 30068105 #2057 Base m/z: 59
08/31/9821:00:00+22:53 Cali: 30068105 # 3 RIC: 3196.
Sample: T-MM5-4 1/3SA/1ML INST. ID: F16
Conds.: UG/ML *1ML *100X/100% *(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
62231 spectra in L1BRARYNB searched for maximum PURITY
352 matched at least 5 of the 16 largest peaks in the unknown
Rank In. Name
1 33841 3,6,9,12-TETRAOXAHEXADECAN-1-OL
2 8813 ETHENE, (2-ETHOXY-1-METHOXYETHOXY)-
3 41712 3,6,9,12,15-PENTAOXANONADECAN-1-OL
4 16651 DIETHYLENE GLYCOL TERT-BUTYL ETHER METHYL ETHER
5 34224 2,5,8,11,14-PENTAOXAHEXADECAN-16-OL
6 5832 2-PROPANOL, 1-<1-METHYLPROPOXY)-
7 8871 METHANE, TERT-BUTOXYISOPROPOXY-
8 16648 1-BUTOXYETHOXY-2-PROPANOL
9 1909 2-PROPANOL, 1-METHOXY-2-HETHYL-
Rank
1
2
3
4
5
6
7
8
9
Formula
C12.H26.05
C7.H14.03
C14.H30.06
C9.H20.03
C11.H24.06
C7.H16.02
C8.H18.02
C9.H20.03
C5.H12.02
Rank
1
2
3
4
5
6
7
8
9
M.Wt
250
146
294
176
252
132
146
176
104
B.Pk
45
59
45
57
45
43
57
57
59
Purity
420
403
401
397
394
383
381
380
375
Fit
704
823
735
782
809
863
748
780
832
RFit
492
409
469
436
438
419
410
444
405
Ret.Time
B.P.Int.
US.Par.1
US.Par.2
C.A.S.
1559-
54063-
1786-
52788-
23778-
53907-
4346-
124-
3587
#
34-8
18-2
94-3
79-1
52-1
95-2
01-4
16-3
64-2
101
-------
MID LIBRARY SEARCH (LIBRARYNB) DATA:
08/31/98 21:00:00 + 22:53 CALI:
SAMPLE: T-MM5-4 1/3SA/1ML INST. ID- F16
CONDS.: UG/ML *1ML *100Z/100Z * i > . |.i .1. i i . . i
3,6,9,1 2-TETRAOXAHEXADECAN- 1 -OL
.
1 | |hl ,li . . I, . . . . ,.
ETHENE , < 2-ETHOXY- 1 -METHOXYETHOX Y ) -
1.
3,6,9, 12, 15-PENTAOXANONADECAN-l-OL
1
1 I. hi 1. . ., , ,
M/Z
50
100
150
200
250
cr
-------
TIC SELECTION REPORT
DATA FILE: 30068105
THE FOLLOWING PEAKS WERE REJECTED BECAUSE
AT LEAST 40 % OF THEIR SIZE WAS ACCOUNTED FOR BY
TARGET COMPOUNDS ELUTING WITHIN 4 SCANS OF THE
PEAK TOP.
SCAN SIZE AMOUNT
198
308
340
421
529
722
828
969
1086
1384
1384
1551
1782
221024.
308392.
226080.
158208.
339072.
329502.
339403.
255936.
390400.
295584.
285536.
178232.
139640.
26.074
36.381
26.670
18.664
40.000
38.833
40.000
26.223
40.000
66.337
64.082
40.000
40.000
TOTAL NUMBER OF UNIDENTIFIED PEAKS WITH SIZE
GREATER THAN 10 % OF THE CLOSEST INTERNAL STANDARD
THAT DOES NOT HAVE INTERFERENCES = 41
INTERNAL STANDARDS THAT HAVE R1C SIZE LESS THAN
50 % OR GREATER THAN 200 % OF THE ESTIMATED R1C SIZE
ARE CONSIDERED TO HAVE INTERFERENCES AND WILL NOT BE USED
FOR QUANT I TAT ION.
PERCENT OF
ESTIMATED
# INTERNAL STANDARD RIC SIZE RIC SIZE SCAN
1 CI40 NAPHTHALENE-D8
2 CI50 ACENAPHTHENE-D10
3 CI60 PHENANTHRENE-D10
4 CI70 CHRYSENE-D12
5 CI75 PERYLENE-D12
339072.
339403.
390400.
178232.
139640.
157
130
146
130
121
529
828
1086
1551
1782
INDICATES INTERFERENCE
SIZE = AREA
101
-------
Semi volatile Organics
Method 0010/8270
Cl ient Name
Client ID:
LAB ID:
Matrix:
Authorized:
Pacific Environmental
T-MM5-3-F,FH,XAD,COND
300681-0006-SA
AIRTRAIN
30 JUL 98
Dilution Factor: 1.0
Parameter
Phenol
bis(2-Chloroethyl)ether
2-Chlorophenol
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Benzyl alcohol
1,2-Dichlorobenzene
2-Methylphenol
2,2'-Oxybis(l-chloropropane)
3/4-Methylphenol
N-Nitroso-di-n-propylamine
Hexachloroethane
Nitrobenzene
Isophorone
2-Nitrophenol
2,4-Dimethylphenol
Benzoic acid
bis(2-Chloroethoxy)-methane
2,4-Dichlorophenol
1,2,4-Trichlorobenzene
Naphthalene
4-Chloroaniline
Hexachlorobutadiene
4-Chloro-3-methyl phenol
2-Methylnaphthalene
Hexachlorocyclopentadiene
2,4,6-Trichlorophenol
2,4,5-Trichlorophenol
2-Chloronaphthalene
2-Nitroaniline
Dimethyl phthalate
Acenaphthylene
3-Nitroaniline
Acenaphthene
2,4-Dinitrophenol
4-Nitrophenol
Dibenzofuran
Services
BH
Sampled:
Prepared:
Wet wt.
Result
53
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
39
ND
ND
ND
74
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
27 JUL 98
31 JUL 98
Units
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
Received: 30 JUL 98
Analyzed: 31 AUG 98
Reporting
Limit
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
150
30
30
30
30
30
30
30
30
30
30
150
30
30
30
30
150
30
150
150
30
Qua! ifier
R
Note R = Reporting limit(s) raised due to sample volume limitations.
ND = Not Detected
Reported By: Emily Uebelhoer
Approved By: Karin Yee
The cover letter is an integral part of this report
Rev 230787
-------
Semivolatile Organics
Method 0010/8270
(cont.)
Client Name
Client ID:
LAB ID:
Matrix:
Authorized:
Pacific Environmental Services
T-MM5-3-F,FH,XAD,COND,BH
300681-0006-SA
AIRTRAIN
30 JUL 98
Dilution Factor: 1.0
Parameter
2,4-Dinitrotoluene
2,6-Dinitrotoluene
Diethyl phthalate
4-Chlorophenyl phenyl ether
Fluorene
4-Nitroaniline
4,6-Dinitro-2-methylphenol
N-Nitrosodiphenylamine
4-Bromophenyl phenyl ether
Hexachlorobenzene
Pentachlorophenol
Phenanthrene
Anthracene
Di-n-butyl phthalate
Fluoranthene
Pyrene
Butyl benzyl phthalate
3,3'-Dichlorobenzidine
Benzo(a)anthracene
bi s(2-Ethylhexyl)-phthalate
Chrysene
Di-n-octyl phthalate
Benzo b)fluoranthene
Benzo k)fluoranthene
Benzo a)pyrene
Indeno(l,2,3-cd)pyrene
Dibenz(a,hjanthracene
Benzo(g,h,i)perylene
Acetophenone
4-Aminobiphenyl
Aniline
Benzidine
3,3'-Dimethylbenzidine
N-Nitrosodimethyl amine
N-Nitrosomorphol ine
Pentachloronitrobenzene (PCNB)
o-Toluidine
Sampled:
Prepared:
Wet wt.
Result
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
27 JUL 98
31 JUL 98
Units
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
Received: 30 JUL 98
Analyzed: 31 AUG 98
Re
porting
Limit
30
30
30
30
30
150
150
30
30
30
150
30
30
30
30
30
30
60
30
30
30
30
30
30
30
30
30
30
30
150
30
300
60
30
30
150
60
Qualifier
ND = Not Detected
Reported By: Emily Uebelhoer
Approved By: Karin Yee
The cover letter is an integral part of this report.
Rev 230787
102
-------
Semi volatile Organics
Method 0010/8270
(cont.J
Client Name: Pacific Environmental Services
Client ID:
LAB ID:
Matrix:
Authorized:
T-MM5-3-F,FH,XAD,COND,BH
300681-0006-SA
AIRTRAIN
30 JUL 98
Sampled: 27 JUL 98
Prepared: 31 JUL 98
Dilution Factor: 1.0
Parameter
2-Methoxybenzenamine
Biphenyl
Chloroacetophenone
Cumene
DBCP (l,2.-Dibromo-3-chloropropane)
Benzo(e)pyrene
N-N-Diethylaniline
Dimethylaniline
3,3'-Dimethoxybenzidine
Hydroquinone
4,4'-Methyl-bis(2-chloroaniline)
4-Nitrodiphenyl
Triflural in
Wet wt.
Result
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Units
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
Received: 30 JUL 98
Analyzed: 31 AUG 98
Reporting
Limit
Qualifier
K
K
K
K
K
K
K
K
K
K
K
K
K
Surrogate
Nitrobenzene-d5
2-Fluorobiphenyl
ferphenyl-d!4
Phenol-d5
2-Fluorophenol
2,4,6-Tribromophenol
Recovery
78 %
106 %
80 %
69 %
71 %
52 %
Acceptable Range
45 - 107
62 - 110
58 - 135
43 - 130
36 - 111
58 - 131
Jote i = Surrogate recovery is outside of control limits.
Jote K = Identified by mass spectrum only; quantitation based on 1:1 response with
internal standard.
ID = Not Detected
teported By: Emily Uebelhoer
Approved By: Karin Yee
The cover letter is an integral part of this report.
Rev 230787
-------
Semivolatiles Library Search (20 Compound TID)
Method 8270
Client Name:
Client ID:
LAB ID:
Matrix:
Authorized:
Pacific Environmental Services
T-MM5-3-F,FH,XAD,COND,BH
300681-0006-SA
AIRTRAIN Sampled:
30 JUL 98 Prepared:
27 JUL 98
NA
Dilution Factor: 1.0
Parameter
n-Nonane
Unknown
Undecane
Dodecane
Unknown alkane
IH-Indene, 1-ethylidene-
Undecane,4,7-dimethyl-
4-Hydroxy-4-methyl-2-pentanone
Heptadecane, 2,6,10,14 -tetramethyl
Tetradecane
Unknown aromatic hydrocarbon
Heptadecane, 2,6,10,14 -tetramethyl
Pentadecane
Nonadecane
Heptadecane,
Heptadecane.
Nonadecane
2,6-dimethyl-
2,6-dimethyl-
Nonadecane
Nonadecane
9-Eicosene
(E)-
Result
390
270
180
160
240
170
240
350
250
430
230
300
440
400
230
520
170
180
150
240
Units
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
Received: 30 JUL 98
Analyzed: 31 AUG 98
Reporting
Limit
Qualifier
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Note 0 = Or structurally similar compound (isomer).
NA = Not Applicable
Reported By: Emily Uebelhoer
Approved By: Karin Yee
The cover letter is an integral part of this report.
Rev 230787
10::;
-------
Sample: T-MM5-3
Client: PACIFI
Analyst: DAT
QUANTERRA GC/MS
Target Compound Data Summary Sheet
1/3SA/1ML
Instrument ID: F16
Ouan List Threshold: 0.95
Data File: 30068106
Std Id: ST 16980831
INST. ID: F16
Date Analyzed: 08/31/98 21:30
Run Factor: 3.00
Surrogate Vol.:
1 .00
Surrogate
CS20 NlTROBENZENE-05
CS25 2-FLUOROBIPHENY
CS30 TERPHENYL-DH
CS45 PHENOL-D5
CS50 2-FLUOROPHENOL
CS55 2,4,6-TRIBROMOP
Surrogate Spike Recoveries
8270-G, LIMS 10/10/96
Surrogate Amount (ug)
Spiked Measured
50.00 39.20
50.00 52.90
50.00 39.90
100.0 68.90
100.0 71.40
100.0 52.50
Target Compounds: SAP9
% Recovery
Measured QC limits
78.4
106.
79.8
68.9
71.4
52.5
45 107
62 110
58 135
43 130
36 111
58 131
157
311
Parameter Scan
HEXACHLOROBENZENE-C13
C310 N-NITROSOOIMETHYLAMINE
PYRIDINE
2-PICOLINE
N-NITROSOMETHYLETHYLAMINE
METHYIMETHANESULFONATE
N-NITROSODIETHYLAMINE
ETHYLMETHANE SULFONATE
PENTACHLOROETHANE
C320 ANILINE
C315 PHENOL
C325 BIS<2-CHLOROETHYL)ETHER
C330 2-CHLOROPHENOL
C335 1,3-DICHLOROBENZENE
C340 1,4-DICHLOROBENZENE
C345 BENZYL ALCOHOL
C350 1,2-DICHLOROBENZENE
C355 2-METHYLPHENOL
C360 2,2'-OXYBIS(1-CLPROPAN)
C361 ACETOPHENONE 401
N-NITROSOPYRROLIDINE
N-NITROSOMORPHOLINE 410
3-METHYL PHENOL
C365 4-METHYLPHENOL
C370 N-NITROSO-DI-N-PROPYLAM
0-TOLUIDINE
C375 HEXACHLOROETHANE
C410 NITROBENZENE
N-NITROSOPIPERIDINE
Result
Units
Reporting
Limit
ND
ND
ND
NJ>-
^
>i5^
ND
ND
ND
ND/
/53
"^
ND
ND
ND
ND
ND
ND
ND
Jป-
m.
&
W^
ND
ND
ND
ND
ND
ND
UG/A
UG/A
UG/A
-^ UG/A
TTif) UG/A
,- UG/A
^
^UG/A
UG/A
- UG/A
.^} UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
-^ UG/A
x'*'"* UG/A
^ UG/A
T^Ni'O UG/A
ซi ^ . UG/A
''<-AIG/A
BG/A
UG/A
UG/A
UG/A
UG/A
30.0
30.0
60.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
Reviewed by:
hfufc
*~ \s
-------
MID LIBRARY SEARCH
08/31/98 21:00:80 + 18:29
SAMPLE: T-MM5-4 1/3SA/1ML INST. ID:
CONDS.: UG/ML *1ML *100Z/100Z */l/3SA
ENHANCED ] BIS-
C7.H16.03
1309
M WT 148
B PK 59
RANK 3
# 9235
PUR 448
1-PROPANOL, 2-< 2-METHOXY-1-METHYLETHOXY)-
M/Z
i
50
100
150
200
250
O
I
-------
Library Search
08/31/98 21:00:00 + 18:47
Sample: T-MM5-4 1/3SA/1ML
Conds.: UG/ML *1ML *100%/100%
Enhanced (S 15B 2N OT)
Data: 30068105 #1688
Call: 30068105 # 3
INST. ID: F16
*(NA/NA )/1/3SA NA M
Base m/z: 41
RIC: 2780.
62231 spectra in LIBRARYNB searched for maximum PURITY
246 matched at least 5 of the 16 largest peaks in the unknown
Rank In. Name
1 15753 2,2-DIMETHYL-3-HEXANOL ACETATE
2 43380 BUTAN01C ACID, 4-(2,4-DlCHLOROPHENOXY)-, 2-METHYLPROPYL ESTER
3 43381 2,4-DB BUTYL ESTER
4 11858 1,3,2-DIOXABOROLANE, 4-METHYL-2-(2-METHYLPROPOXY)-
5 11857 1,3,2-DlOXABORINANE, 2-C2-METHYLPROPOXY)-
6 3130 2-BUTANONE, 3-METHYL-, 0-METHYLOXIME
7 12049 4-OCTANOL, 4,7-DIMETHYL-
8 3139 2-PFNTANONE, 0-METHYLOXIME
9 52020 D-MANNITOL, 2,4-DI-0-METHYL-, TETRAACETATE
Rank
1
2
3
4
5
6
7
8
9
Formula
C10.H?0.02
C14.H18.03.CL2
C14.H18.03.CL2
C7.H15.03.B
C7.H15.03.B
C6.H13.0.N
C10.H22.0
C6.H12..0.N
C16.H26.010
M.Wt
172
304
304
158
158
115
158
115
378
B.Pk
43
87
87
115
115
42
87
42
43
Purity
240
224
220
208
199
198
187
185
175
Fit
646
660
664
609
557
758
660
707
622
RFit
291
270
247
273
237
211
234
196
217
Rank
1
2
3
4
5
6
7
8
9
Ret. Time
B.P.Int.
US.Par.1
US. Par. 2
C.A.S. #
51550-64-2
6753-24-8
52910-21-1
55162-67-9
27685-13-8
19781-13-6
31377-00-1
24406-90-4
-------
Library Search Data: 30068105 #1804 Base m/z: 59
08/31/98 21:00:00 + 20:04 Call: 30068105 # 3 RIC: 4592.
Sample: T-MM5-4 1/3SA/1ML 1NST. ID: F16
Conds.: UG/ML *1ML *100%/100% *(NA/NA )/1/3SA NA M
Enhanced (S 158 2N OT)
62231 spectra in LIBRARYMB searched for maximum PURITY
465 matched at least 5 of the 16 largest peaks in the unknown
Rank In. Name
1 9228 1-PROPANOL
2 24247 2-PROPANOL
, 2-C2-METHOXYPROPOXY)-
, 1-[2-(2-METHOXY-1-METHYLETHOXY)-1-METHYLETHOXY]-
3 8822 BUTANOIC ACID, 4-ETHOXY-, METHYL ESTER
4 8432 2-HEXANONE
5 1760 2-PENTANOL
6 1905 2-BUTANOL,
7 16649 1-PROPANOL
8 5832 2-PROPANOL
9 9235 1-PROPANOL
Rank Formula
1 C7.H16.03
2 C10.H22.04
3 C7.H14.03
4 C8.H16.02
5 C6.H14.0
6 C5.H12.02
7 C9.H20.03
8 C7.H16.02
9 C7.H16.03
Rank Ret. Time
1
2
3
4
5
6
7
8
9
, 3-HYDROXY-3,5-DIMETHYL-
, 2-METHYL-
3-METHOXY-
, 3- t3-(1-METHYLETHOXY)PROPOXY]-
, 1-(1-METHYLPROPOXY)-
, 2-C2-METHOXY-1-METHYLETHOXY)-
M.Wt B.Pk
148 59
206 59
146 59
144 59
102 59
104 59
176 59
132 43
148 59
B.P.Int. US. Par. 1 US. Par.
Purity Fit RFit
436 799 454
397 681 490
392 687 433
369 851 391
365 867 385
362 825 392
356 768 413
354 624 433
349 668 423
2 C.A.S. #
13588-28-8
20324-33-8
29006-04-0
6321-14-8
590-36-3
53778-72-6
54518-03-5
53907-95-2
55956-21-3
iu;:e
-------
MID LIBRARY SEARCH CLIBRARYNB) DATA:
08/31/98 21:00:00 + 18:47 CALI:
SAMPLE: T-MM5-4 1/3SA/1ML INST. ID: F16
CONDS.: UG/ML *1ML *100Z/100Z *-, 2-METHYLPROPYL ESTER
r
.11.
1 1 1 i M'" 1 | ' 1 'l 1 i 1 ' I* i [ ' '!' T"1-' ' 1 ' > 1 ' ' | 1 '' ' ' ' 1 1 1 ' 1 ' ~1 ' ' 1
3.CL2 2,4-DB BUTYL ESTER
r
1
II i.l..... 1 ' i
M/Z
50
100
150
200
250
300
O
I'
-------
QUANTERRA GC/MS
Target Compound Data Summary Sheet
Data File: 30068106
Std Id: ST16980831
Sample: T-MM5-3 1/3SA/1ML INST. ID: F16
Client: PAC1FI Date Analyzed: 08/31/98 21:30
Analyst: DAT Instrument ID: F16 Run Factor: 3.00
Quan List Threshold: 0.95 Surrogate Vol.: 1.00
Parameter
Target Compounds: SAP9
Reporting
Scan Result Units Limit
C415 ISOPHORONE
C420 2-NITROPHENOL
C425 2,4-DIMETHYLPHENOL
C435 BIS(2-CHLOROETHOXY)METH
C440 2,4-DICHLOROPHENOL
C430 8ENZOIC ACID
AA-DIMETHYLPHENETHYLAMINE
C445 1,2,4-TRICHLOROBENZENE
C450 NAPHTHALENE 534
C455 4-CHLOROANALINE
2,6-DICHLOROPHENOL
HEXACHLOROPROPENE
C460 HEXACHLOROBUTADIENE
P-PHENYLENE DIAMINE
N-NITROSCOI-N-BUTYLAMINE
C465 4-CHLORO-3-METHYLPHENO
SAFROLE
C470 2-METHYLNAPHTHALENE 653
1 ,2,4,5-TETRACHLOROBENZENE
ISOSAFROLE (#1)
C510 HEXACHLOROCYCLOPENT AD I
C515 2,4,6-TRlCHLOROPHENOL
C520 2,4,5-TRICHLOROPHENOL
ISOSAFROLE (#2)
C525 2-CHLORONAPHTHALENE
1-CHLORONAPHTHALENE
C530 2-NITROANALINE
1,4-NAPHTHOQUINONE
C535 DIMETHYLPHTHALATE
1,3-DINITROBENZENE
C540 ACENAPHTHYLENE
C543 2,6-DINITROTOLUENE
C545 3-NITROANILINE
C550 ACENAPHTHENE
C555 2,4-DINITROPHENOL
C565 DIBENZOFURAN
C560 4-NITROPHENOL
PENTACHLOROBENZENE
C570 2,4-DINITROTOLUENE
1-NAPHTHYLAMINE
2-NAPHTHYLAMINE
2,3,4,6-TETRACHLOROPHENOL
C580 DIETHYLPHTHALATE
C590 FLUORENE
ND
ND
ND
ND
ND
ND
ND
"P~\
/39y
mr
ND
ND
ND
ND
ND
ND
ND_
I74)
Vo-/
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
30.0
30.0
30.0
30.0
30.0
150.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
60.0
30.0
30.0
30.0
60.0
30.0
15.0
150.0
30.0
30.0
30.0
30.0
30.0
150.0
30.0
150.0
30.0
150.0
30.0
30.0
30.0
30.0
60.0
30.0
30.0
-------
QUANTERRA GC/MS
Target Compound Data Summary Sheet
Data File: 30068106
Std Id: ST16980831
Sample: T-MM5-3 1/3SA/1ML INST. ID: F16
Client: PACIFI Date Analyzed: 08/31/98 21:30
Analyst: DAT Instrument ID: F16 Run Factor: 3.00
Quan List Threshold: 0.95 Surrogate Vol.: 1.00
Target Compounds: SAP9
Reporting
Parameter Scan Result Units Limit
C585 4-CHLOROPHENYL-PHENYLE NO UG/A 30.0
5-NITRO-O-TOLUIDINE NO UG/A 30.0
C595 4-NITROANALINE ND UG/A 150.0
C610 4.6-DINITRO-2-METHYLPH ND UG/A 150.0
C615 N-NITROSODIPHENYLAMINE ND UG/A 30.0
C620 AZOBENZENE ND UG/A 30.0
SYM-TRINITROBENZENE ND UG/A 30.0
C625 4-BROMOPHENYL-PHENYLET ND UG/A 30.0
PHENACET1N , ND UG/A 30.0
DIALLATE 234 ND UG/A 30.0
C630 HEXACHLOROBENZENE ND UG/A 30.0
4-AMINOBIPHENYL ND UG/A 30.0
C635 PENTACHLOROPHENOL ND UG/A 150.0
PRONAHIDE ND UG/A 30.0
PENTACHLORON1TROBENZENE ND UG/A 150.0
C640 PHENANTHRENE ND UG/A 30.0
C645 ANTHRACENE ND UG/A 30.0
2SECBUTYL-4,6-DINITROPHENOL ND UG/A 30.0
C647 CARBAZOLE ND UG/A 30.0
C650 DI-N-8UTYLPHTHALATE ND UG/A 30.0
4-NITROQUINOLINE-1-OXIDE ND UG/A 30.0
METHAPYRILENE ND UG/A 30.0
ISOORIN ND UG/A 30.0
C655 FLUORANTHENE ND UG/A 30.0
CHLOROBENZILATE ND UG/A 30.0
C710 BENZIDINE ND UG/A 300.0
C715 PYRENE ND UG/A 30.0
ARAMITE (#1) ND UG/A 30.0
ARAM1TE (#2) ND UG/A 30.0
P-D1METHYLAMINOAZOBENZENE ND UG/A 30.0
3,3'-DIMETHYLBENZIDINE ND UG/A 30.0
-------
croฃ
0'0ฃ
o-0ฃ
0'0ฃ
v/on
V/DPI
won
V/30
ON
ON
ON
06/3
3N3DVDHiNV(H'V)ZN3aiO S8/3
3N3aAd(V)OZN38
00'I :
O0'ฃ
3ฃ=IZ 86/IE/80 :
Lฃ80869US :p
9018900E =ai !d
satun iinsay ueos
6dVS :spunoduw3
3je6ojjns 56'0
ma 9U :ai
ueno
1Nl/VSฃ/l ฃ-SWW-l :;
PJS
A-ieuuns EIBQ punoduno id6jei
SW/3D
-------
DATA FROM FILE: 39068106 SCANS 93 TO 1203 ACQUIRED: 08/31/98 21:30:00
CALI: 30068106 #3
SAMPLE: T-MM5-3 1/3SA/1ML INST. ID: F16
CONDS.: UG/ML *1ML *100Z/100Z *
-------
DATA FROM FILE: 30068106 SCANS 1203 TO 2158 ACQUIRED: 08/31/98 21:30:00
CALI: 30068106 #3
SAMPLE: T-MM5-3 1/3SA/1ML INST. ID: F16
CONDS.: UG/ML *1ML S1002/100Z *
-------
STANDARD USED FOR THIS REPORT IS ST16980831 REPORT PRINTED: 9/01/98 19:04:45
ADDITIONAL STANDARD USED FOR THIS REPORT IS: ST16980831A
QUANTERRA QUANT I TAT I ON SUMMARY
File: 30068106
Sample: T-MM5-3 1/3SA/1ML INST. ID: F16
Analyst: DAT Instrument Id: F16 Analyzed: 08/31/98 21:30
Compounds with amounts less than 0.20 reported as NOT FOUND
Library
No Entry
1 S1#
2 S2#
3 S3#
4 S4#
5 S5#
6 S6#
7 S2#
8 S3#
9 S5#
10 S1#
11 S1#
12 S3#
13 S4#
1
1
1
1
1
1
2
3
2
3
2
2
4
Name Mass
CI30
CI40
CI50
CI60
CI70
CI75
CS20
CS25
CS30
CS45
CS50
CS55
1,4-DICHLOROBENZENE
NAPHTHALENE-D8
ACENAPHTHENE-D10
PHENANTHRENE-D10
CHRYSENE-D12
PERYLENE-D12
NITROBENZENE-05
2-FLUOROBIPHENYL
TERPHENYL-D14
PHENOL-D5
2-FLUOROPHENOL
2,4,6-TRIBROMOPHENO
HEXACHLOROBENZENE-C13
152
136
164
188
240
264
82
172
244
99
112
330
294
Meth
A
A
A
A
A
A
A
A
A
A
A
A
BB
BB
BB
BB
BB
VB
BV
VB
BB
BB
BB
BB
Scan
341
531
831
1088
1553
1784
422
724
1385
310
198
972
4
Ref Area
1
2
3
4
5
6
2
3
5
1
1
3
NOT
33301.
120808.
61921.
101964.
101687.
95704.
55580.
101124.
100901.
116232.
81364.
19151.
FOUND
Units: UG/ML
RRF(L)
1.000
1.000
1.000
1.000
1.000
1.000
0.470
1.234
0.995
2.025
1.368
0.236
Amount
40.000
40.000
40.000
40.000
40.000
40.000
39.192
52.925
39.882
68.929
71.429
52.497
14 S1# 15 C310 N-NITROSODIMETHYLAM
15 S1# 20 PYRIDINE
16 SDK 30 2-PICOLINE
17 S1# 40 N-NITROSOMETHYLETHYLAMIN
18 S1# 60 METHYLMETHANESULFONATE
19 S1# 70 N-NITROSODIETHYLAMINE
20 S1# 85 ETHYLMETHANE SULFONATE
21 S1# 95 PENTACHLOROETHANE
22 S1#100 C320 ANILINE
23 S1#105 C315 PHENOL
24 S1#110 C325 BIS(2-CHLOROETHYL)E
25 51*115 C530 2-CHLOROPHENOL
26 S1#125 C335 1,3-DICHLOROBENZENE
27 S1#130 C340 1,4-DlCHLOROBENZENE
28 S1#145 C345 BENZYL ALCOHOL
29 S1#150 C350 1,2-DICHLOROBENZENE
30 S1#160 C355 2-METHYLPHENOL
31 S1#165 C360 2,2'-OXYBIS(1-CLPRO
32 S1#170 C361 ACETOPHENONE
33 S1#175 N-NITROSOPYRROLIDINE
34 S1#180 N-NITROSOMORPHOL1NE
35 S1#182 3-METHYL PHENOL
36 S1#185 C365 4-METHYLPHENOL
37 S1#190 C370 N-NITROSO-DI-N-PROP
38 S1#195 0-TOLUIDINE
39 S1#200 C375 HEXACHLOROETHANE
40 S2# 10 C410 NITROBENZENE
41 S2# 15 N-NITROSOPIPERIDINE
42 S2# 20 C415 ISOPHORONE
43 S2# 25 C420 2-NITROPHENOL
44 S2# 30 C425 2,4-DIMETHYLPHENOL
45 S2# 35 C435 BISC2-CHLOROETHOXY)
74
79
93
42
80
102
79
117
93
94
93
128
146
146
108
146
108
45
105
100
56
108
108
70
106
117
77
42
82
139
107
93
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
ป'V
UB
BB
BB
BB
BV
VB
BV
BB
BB
BB
BB
VB
VB
BB
BB
BB
1
1
1
157
183
1
1
307
1
311
320
315
1
1
370
1
1
386
401
404
410
420
1
404
1
1
423
2
473
2
501
516
NOT
NOT
NOT
1
1
NOT
NOT
1
NOT
1
1
1
NOT
NOT
1
NOT
NOT
1
1
1
1
1
NOT
1
NOT
NOT
2
NOT
2
NOT
2
2
FOUND
FOUND
FOUND
8518.
468.
FOUND
FOUND
1144.
FOUND
28734.
3814.
330.
FOUND
FOUND
6573.
FOUND
FOUND
640.
16818.
250.
7023.
4135.
FOUND
1969.
FOUND
FOUND
2891.
FOUND
10146.
FOUND
1308.
744.
0
0
0
1
1
1
0
2
1
0
0
2
0
0
0
0
0
.811
.636
.602
.968
.368
.497
.854
.539
.934
.553
.821
.252
.906
.445
.741
.330
.511
12
0
2
17
3
0
9
0
10
0
10
2
2
2
4
1
0
.614
.884
.285
.540
.349
.265
.241
.303
.446
.543
.279
.206
.611
.151
.532
.313
.483
-------
46 S2# 40 C440 2,4-DlCHLOROPHENOt 162 A BB 520 2 548. 0.308 0.590
47 S2# 45 C430 BENZOIC ACID 122 2 NOT FOUND
48 S2# 50 AA-DIMETHYLPHENETHYLAMIN 58 2 NOT FOUND
49 S2# 55 C445 1,2,4-TRICHLOROBENZ 180 2 NOT FOUND
-------
50 S2# 60 C450 NAPHTHALENE
51 S2# 80 C455 4-CHLOROANALINE
52 S2# 85 2,6-OICHLOROPHENOL
53 S2# 90 HEXACHLOROPROPENE
54 S2# 95 C460 HEXACHLOROBUTAD1ENE
55 S2#115 P-PHENYLENE DIAMINE
56 S2#120 N-NITROSOOI-N-BUTYLAMINE
57 S2#130 C465 4-CHLORO-3-METHYLPH
58 S2#140 SAFROLE
59 S2#145 C470 2-METHYLNAPHTHALENE
60 S3# 10 1,2,4,5-TETRACHLOROBENZE
61 S3# 15 ISOSAFROLE (#1)
62 S3# 20 C510 HEXACHLOROCYCLOPENT
63 S3# 25 C515 2,4.6-TRlCHLOROPHEN
64 S3# 30 C520 2,4,5-TRICHLOROPHEN
65 S3# 35 ISOSAFROLE (#2)
66 S3# 40 C525 2-CHLORONAPHTHALENE
67 S3# 42 1-CHLORONAPHTHALEN
68 S3# 45 C530 2-NITROANALINE
69 S3# 50 1,4-NAPHTHOQUINONE
70 S3# 55 C535 DIMETHYLPHTHALATE
71 S3# 60 1,3-DINITROBENZENE
72 S3# 65 C540 ACENAPHTHYLENE
73 S3# 70 C543 2,6-DINITROTOLUENE
74 S3# 75 C545 3-N1TROANILINE
75 S3# 80 C550 ACENAPHTHENE
76 S3# 85 C555 2,4-DINITROPHENOL
77 S3# 90 C565 DIBENZOFURAN
78 S3# 95 C560 4-NITROPHENOL
79 S3#100 PENTACHLOROBENZENE
80 S3#105 C570 2,4-DINITROTOLUENE
81 S3#110 1-NAPHTHYLAMINE
82 S3#115 2-NAPHTHYLAMINE
63 S3#120 2,3,4,6-TETRACHLOROPHENO
84 S3#130 C580 DIETHYLPHTHALATE
85 S3#135 C590 FLUORENE
86 S3#140 C585 4-CHLOROPHENYL-PHEN
87 S3#145 5-NITRO-O-TOLUIDINE
88 S3#150 C595 4-NITROANALINE
89 S4# 10 C610 4.6-DINITRO-2-METHY
90 S4# 15 C615 N-NITROSOOIPHENYLAM
91 S4# 20 C620 AZOBENZENE
92 S4# 25 SYM-TRINITROBENZENE
93 SA*ป 30 C625 4-BROMOPHENYL-PHENY
94 S4# 35 PHENACETIN
95 S4# 37 DIALLATE
96 S4# 40 C630 HEXACHLOROBENZENE
97 S4# 45 4-AMINOBIPHENYL
98 S4# 50 C635 PENTACHLOROPHENOL
99 S4*f 55 PRONAMIDE
00 S4# 60 PENTACHLORONITROBENZENE
01 S4# 65 C640 PHENANTHRENE
02 S4# 70 C645 ANTHRACENE
03 S4# 75 2SECBUTYL-4,6-OINITROPHE
D4 S4# 80 C647 CARBAZOLE
35 S4# 85 C650 DI-N-BUTYLPHTHALATE
36 S4#100 4-NITROQUINOLINE-1-OXIDE
37 S4#105 METHAPYRILENE
J8 S4#106 ISOOR1N
)9 54*110 C655 FLUORANTHENE
10 S4#120 CHLOROBENZILATE
128
127
162
213
225
108
84
107
162
142
214
162
237
196
196
104
162
162
65
158
163
168
152
165
138
153
184
168
109
250
165
143
143
232
149
166
204
152
138
198
169
77
75
248
108
234
284
169
266
173
237
178
178
211
167
149
190
58
193
202
139
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
BV
BB
SB
BB
BB
BB
BB
BB
BB
VB
BV
BB
BB
BV
VB
BB
VB
VB
VB
BV
VB
BB
VB
BB
BB
534 2
557 2
2 NOT
2 NOT
2 NOT
2 NOT
2 NOT
2 NOT
649 2
653 2
3 NOT
699 3
3 NOT
3 NOT
3 NOT
3 NOT
3 NOT
3 NOT
765 3
3 NOT
3 NOT
808 3
809 3
818 3
3 NOT
836 3
859 3
868 3
3 NOT
3 NOT
882 3
883 3
3 NOT
3 NOT
934 3
927 3
3 NOT
943 3
3 NOT
4 NOT
965 4
966 4
1026 4
4 NOT
4 NOT
1021 4
4 NOT
1077 4
1064 4
4 NOT
4 NOT
1092 4
4 NOT
4 NOT
4 NOT
4 NOT
4 NOT
4 NOT
4 NOT
1300 4
4 NOT
40335.
1230.
FOUND
FOUND
FOUND
FOUND
FOUND
FOUND
1554.
56007.
FOUND
1059.
FOUND
FOUND
FOUND
FOUND
FOUND
FOUND
1407.
FOUND
FOUND
278.
1258.
645.
FOUND
2658.
224.
1768.
FOUND
FOUND
682.
602.
FOUND
FOUND
1179.
5987.
FOUND
2476.
FOUND
FOUND
5818.
643.
206.
FOUND
FOUND
156.
FOUND
3167.
261.
FOUND
FOUND
18337.
FOUND
FOUND
FOUND
FOUND
FOUND
FOUND
FOUND
602.
FOUND
1
0
0
0
0
0
0
1
0
1
0
1
0
0
1
1
0
0
1
0
0
0
0
1
0
.022
.454
.248
.751
.044
.502
.197
.838
.324
.159
.189
.669
.397
.837
.369
.298
.356
.551
.171
.162
.090
.609
.155
.033
.900
13
0
2
24
15
1
0
0
1
1
0
0
1
0
0
2
4
4
0
0
0
2
0
6
0
.065
.898
.077
.684
.673
.812
.909
.442
.287
.482
.764
.684
.109
.464
.556
.980
.499
.145
.216
.501
.678
.040
.660
.966
.263
i-j
-------
111 S5# 10 C710 BENZ1DINE 184 5 NOT FOUND
112 S5# 15 C715 PYRENE 202 A BB 1336 5 2881. 1.323 0.857
113 S5# 20 ARAMITE (#1) 185 5 NOT FOUND
114 S5# 25 ARAMITE (#2) 185 5 NOT FOUND
115 S5# 30 P-D1METHYLAMINOAZOBENZEN 120 5 NOT FOUND
116 S5# 35 3,3'-DIMETHYL8ENZIDlNE 212 5 NOT FOUND
117 S5# 37 KEPONE 272 5 NOT FOUND
118 S5# 40 C720 BUTYLBENZYLPHTHALAT 149 5 NOT FOUND
119 S5# 45 2-ACETYLAMINOFLUORENE 181 5 NOT FOUND
120 S5# 50 C730 BENZO(A)ANTHRACENE 228 A BB 1556 5 2250. 1.125 0.787
121 S5# 55 C725 3,3'-DICHLOROBENZID 252 5 NOT FOUND
122 S5# 60 C740 CHRYSENE 228 A BB 1556 5 2250. 1.014 0.873
123 S5# 65 C745 B1S(2-ETHYLHEXYL)PH 149 A BB 1604 5 6255. 0.980 2.511
124 S5# 85 3-METHYLCHOLANTHRENE 268 5 NOT FOUND
125 S6# 10 C760 DI-N-OCTYL PHTHALAT 149 A VB 1717 6 1093. 1.925 0.237
126 S6# 15 C765 BENZO(B)FLUORANTHEN 252 A BV 1728 6 1158. 1.443 0.335
127 S6# 20 7,12-DIMETHYLBENZANTHRAC 256 6 NOT FOUND
128 S6# 25 C770 BENZO(K)FLUORANTHEN 252 6 NOT FOUND
129 S6# 30 HEXACHLOROPHENE 196 6 NOT FOUND
130 S6# 35 C775 BENZO(A)PYRENE 252 A BB 1787 6 643. 1.182 0.227
131 S6# 55 C780 INDENOd ,2,3-CD)PYR 276 6 NOT FOUND
132 S6# 60 C785 DIBENZ(A,H)ANTHRACE 278 6 NOT FOUND
133 S6# 65 C790 BENZOCG,H,1)PERYLEN 276 6 NOT FOUND
-------
SNA, S LIBRARIES ANALYST: DATE:
QUANTERRA Internal Standard Check
Standard Filename: ST16980831 Analyzed: 08/31/98 12:31
j 1S# 1 | IS# 2 j IS# 3
Standard j Area % | RT j Area % | RT | Area % | RT
ST16980831 | 28649. | 3.78 | 100432. | 5.90 | 54347. | 9.21
Upper Limit | 57297.=+200j 4.28 j 200864.=+200j 6.40 j 108695.=+200j 9.71
Lower Limit | 14324.=+ 50j 3.28 | 50216.=+ 50j 5.40 j 27174.=+ 50| 8.71
Filename | | | | | |
I I I II I
1 30068106 | 33301.= 116| 3.79 | 120808.= 120| 5.91 | 61921.= 113| 9.24
IS*1 1 = CI30 1,4-DICHLOROBENZENE-D4
IS# 2 = C140 NAPHTHALENE-OS
IS*1 3 = CI50 ACENAPHTHENE-D10
* - indicates an I.S. is outside QC limit(s)
| IS# 4 | IS# 5 | IS# 6 |
Standard j Area % | RT j Area % | RT j Area % | RT j
ST16980831 | 98520. |12.08 | 62289. |17.26 | 50750. |19.83 |
Upper Limit | 197039.=+200j12.58 j 124578.=+200|17.76 j 101500.=+200|20.33 j
Lower Limit j 49260.=+ 50J11.58 j 31145.=+ 50)16.76 | 25375.=+ 50|19.33 |
Filename. | | | | | | |
I II II II
1 30068106 | 101964.= 103|12.10 | 101687.= 163|17.27 | 95704.= 188|19.84 |
IS# 4 = CI60 PHENANTHRENE-010
1S# 5 = CI70 CHRYSENE-D12
IS# 6 = C175 PERYLENE-D12
* - indicates an I.S. is outside DC limit(s)
1UC7
-------
TARGET COMPOUND COMPARISON
COMPOUND: C315 PHENOL
RAW DATA: 30868106 #311
08/31/98 21:30
94 S1#105CC
108-95-2
BASE M/Z:
93
RIC: 170752.
53.9-
27.0-i
40.5-
20.3-:
100.0-
50.0-:
M/Z
100.0-
50.0":
0.0J
-50.0-:
100.0^
SAMPLE: T-MM5-3 1/3S
CONDS.: UG/ML *1ML *10
,..J|II,,. .iilll....|llil|l ,.,,!>, - |il>
ENHANCED DATA: 3006810
.I) hi |/1
STANDARD FILE: ST 1698.0
08/31/98 12:31 J
,||,|i. , i. Lul -.-- /ซ
V1ML INST. ID: F16
37./100Z *(NA/NA )/l/3SA NA M
i I1' i i "I1 i''1|'|i|>i'i'i'i'i'il~i"ri>|'fl~~
B #311 BASE M/Z: 99 RIC: 96384.
\C.<7
XVoV >1
^
, '1 i i , i ' 1 1 i i i i i ' i ~~" i ' i ' i ' | ' i '
B31 #309 BASE M/Z: 94 RIC: 170752.
i , ,,ni|iiii,,i. jini| ., ,.,1,11,1111. .,.. ., , r-,, ) , | i i i i i i < | i i i i i i i , , | i
50 100 150 200 250
, |. , | I), ,. | . .11 , ... ..Ill 1. . . ...
r 17568.
r 13206.
r 32576.
r **OUT**
C 5
-------
TARGET COMPOUND COMPARISON
COMPOUND: C450 NAPHTHALENE
128 S2# 60
RAN DATA: 30068106 #534
08/31/98 21:30
SAMPLE: T-MM5-3 1/3SA/1ML INST. ID: F16
CONDS.: UG/ML *1ML *100/2/100Z * 1 1 1 i I 1 i 1 . 1 i | 1 i
150 200 250
I i
', ,..." . . . . . ...
r 10384.
9152.
r 79232.
b **OUT**
-------
TARGET COMPOUND COMPARISON
COMPOUND: C470 2-METHYLNAPHTHALENE
142 S2#145
RAW DATA: 30068106 #653
08/31/98 21:30
SAMPLE: T-MM5-3 1/3SA/1ML INST. ID: F16
CONDS.: UG/ML *1ML *100Z/100Z */l/3SA NA M
91-57-6
BASE M/Z: 142
RIC: 218368.
31.1-
15.6-i
28.8-
14. 4~.
1 1 | 1 1 1 1
I
1
ii.h
Hi. ...i.i.
ENHANCED DATA:
1 '
i-i 1 i i1
1 ' ' 1 ' ' ' ' 1 ' ' '
11 1 ,. i.i.lllii i . l.-illli. ....I,..!)!,.
30068106 #653 BASE
MI 'I'l'i-i i i'| I'i'i i | ii i i'| ii ii | ii ii ii i ii | i
M/Z: 142 RIC: 59904.
i ..
1 1 1 1 | 1 1 . ...... 1 . 1 1 1 I 1 1 . . | . ........ | . . . . | . . . ' | ' ' ! . | T , , . I--T T--J T 1 1 -f-t
STANDARD FILE: ST16980831 #651
08/31/98 12:31
BASE M/Z: 142
RIC: 198144.
r 15504.
r 14336.
100.0-
50. 0^
M/Z
100.0-
50. Q-.
0.0-
-50.0-:
100.0-
1 1 1 1 1 I'l'l 1 1 1 1 I'l'l 1 1 I'l'l'l I'l'l'l'l'l 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1
40 50 60 80 190 120 141
. | it. .1.1 i
i i i ' 1
1 ' i ' ' I i ,. | .,..,.
3 150 160 180 200
r 49792.
0
^
O
-------
Data Reduced by:*"^. O^te:
Data Reviewed by: rf Date:
~~r*~
Data File: 30068106
QUANTERRA GC/MS TIC REPORT ( Part 1 )
Sample: T-MM5-3 1/3SA/1ML INST. ID: F16
Analyst: DAT Date Analyzed: 08/31/98 21:30
Run Factor: 3.00
Concentration
in Sample
(UG/A) CAS #
350. 123-42-2
2-PENTANONE, 4-HYDROXY-4-METHYL- (J f
2 221 390.
NONANE OY
111-84-2
3 311
UNKNOWN
270.
00-00-0
4 445
UNDECANE
180.
(
1120-21-4
5 557
DODECANE
112-40-3
6 634
240. -54-100 67 "8
7 653 170. 2471-83-2
1H-INDENE, 1-ETHYLIDENE-
8 664 240. 17301-32-5
UNDECANE, 4, 7-DIMETHYL- O r
2X724 150.
1,1'-B1PHENYL, :
321-60-8
> r
10 739 250. 18344-37-1
HEPTAOECANE, 2,6,10,14-TETRAMETHYL- O
lUli
-------
11 765 430.
TETRADECANE
629-59-4
12 778 230. -ee-wtr
13 822 300. 18344-37-1
HEPTADECANE, 2,6,10,14-TETRAMETHYL- O V
14 860 440.
PENTADECANE &V
629-62-9
905 120.
NADECANOL U ^
52783-43-4
16 949 400.
NONADECANE
629-92-5
HEPTADECANE, 2,6-DIMETHYL-
19 1115 170.
NONADECANE
629-92-5
1336 130.
2-METHYLOCTADECANE
17 989 230.
HEPTADECANE, 2,6-DIMETHY
18 1037 520.
54105-67-8
'54105-67-8
1120 180.
NONADECANE
1192 140.
NONADECANE
629-92-5
629-92-5
-------
23 1531 150.
NONADECANE
629-92-5
1587 240.
9-EICOSENE, (E)-
74685-29-3
/
ซ5 1
UN
1809 120.
KNOWN
00-00-0
lOlo
-------
DATA FILE: 30068106
OUANTERRA GC/MS TIC REPORT ( Part 2 )
CONCENTRATION = AREA(TIC)ปCOปซC( IS)/AREA( IS)
#
1
2
3
4
5
6
7
8
9
10
11
12
13
U
15
16
17
18
19
20
21
22
23
24
25
FIT
948
986
829
975
970
938
956
939
994
930
960
910
959
963
934
952
955
974
947
952
950
908
935
984
706
PURITY
906
942
529
722
895
687
760
829
843
812
744
451
792
816
653
842
834
872
806
822
774
662
663
795
329
INT.
STD.
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
4
4
4
4
5
AMOUNT
AS ANALYZED
RT
1:53
2:27
3:27
4:56
6:11
7:03
7:15
7:23
8:03
8:13
8:30
8:39
9:08
9:33
10:03
10:33
11:00
11:32
12:24
12:27
13:15
14:51
17:01
17:39
20:07
RRT
0.205
0.266
0.375
0.536
0.671
0.764
0.787
0.800
0.872
0.890
0.922
0.937
0.990
1.036
1.090
1.143
1.192
1.249
1.343
1.349
0.768
0.860
0.986
1.022
1.014
AREA
1066940.
1174820.
827993.
541092.
494208.
724224 .
513280.
715264.
444928.
768256.
1312510.
701952.
914944.
1321220.
375040.
1198340.
708891 .
1565700.
528896.
551424.
357120.
335488.
392960.
617728.
281792.
HEIGHT
387584.
346624.
123904.
131657.
143104.
159488.
72192.
174336.
87552.
166144.
320000.
90624 .
165632.
301056.
81152.
266752.
168771.
264192.
153600.
169472.
115968.
76717.
48384.
115968.
23360.
(UG/ML )
117
129
91
59
54
79
56
78
48
84
144
77
100
145
41
131
77
172
58
60
45
43
50
79
41
.319
.180
.044
.497
.342
.634
.439
.649
.923
.476
.321
.185
.605
.278
.239
.766
.948
.160
.156
.633
.964
.180
.577
.506
.621
LIB
NB
NB
UK
NB
NB
NB
NB
NB
NB
NB
NB
UK
NB
NB
NB
NB
NB
NB
NB
NB
NB
NB
NB
NB
UK
LIB #
3241.
5159.
1.
11607.
15343.
37462.
8109.
19016.
15856.
42196.
22530.
1.
42196.
25997.
40233.
37465 .
37462.
37462.
37465 .
37465 .
37465 .
37456.
37465 .
39515.
1.
Itlli
-------
Library Search Data: 30068106 # 170 Base m/z: 43
08/31/9821:30:00+ 1:53 Cali: 30068106 # 3 RIC: 273920.
Sample: T-MM5-3 1/3SA/1ML INST. ID: F16
Conds.: UG/ML *1ML *100%/100% *(NA/NA 5/1/3SA NA M
Enhanced (S 15B 2N OT)
62231 spectra in L1BRARYNB searched for maximum PURITY
495 matched at least 6 of the 16 largest peaks in the unknown
Rank In.
Name
1 3241 2-PENTANONE, 4-HYDROXY-4-METHYL-
2 3366 2-PENTANOL, 2,4-DIMETHYL-
3 919 TERT-BUTYL HYDROPEROXIDE
4 5791 1,3-DIOXOLANE-2-METHANOL, 2,4-DIMETHYL-
5 3288 ACETIC ACID, 1 , 1 -D1METHYLETHYL ESTER
6 5594 2-PROPANOL, 2-NITROSO-, ACETATE (ESTER)
7 3349 2-HEXANOL, 2-METHYl-
B 1576 OXIRANE, TETRAMETHYL-
9 3353 2-PENTANOL, 2,3-DIMETHYL-
Rank
1
>_
5
4
"l
:>
7
5
?
!ank
1
>
5
,
)
b
7
i
)
Formula
C6.H12.02
C7.H16.0
C4.H10.02
C6.H12.03
C6.H12.02
C5.H9.03.N
C7.H16.0
C6.H12.0
C7.H16.0
Ret. Time B.P.Int.
M.Ut
116
116
90
132
116
131
116
100
116
B.Pk
43
59
59
43
43
43
59
59
59
US. Par. 1 US. Par.
Purity Fit
906 948
751 778
742 894
734 805
729 779
713 830
698 736
653 805
643 689
.2 C.A.S. #
123-42-2
625-06-9
75-91-2
53951-43-2
540-88-5
6931-04-0
625-23-0
5076-20-0
4911-70-0
RFit
928
769
761
800
742
760
750
705
706
1015
-------
MID LIBRARY SEARCH (LIBRARYNB) DATA: 30068106 # 170 BASE M/Z: 43
08/31/98 21:30:60 + 1:53 CALI: 30068106 # 3 RIC: 273920.
SAMPLE: T-MM5-3 1/3SA/1ML INST. ID: F16
CONDS.: UG/ML *1ML * 100Z/1 007: *
1000
SAMPLE
C6.H12.02
1000 1
M WT 116
B PK 43
RANK 1
* 3241
PUR 906
C7.H16.0
M WT 116
B PK 59
RANK 2
* 3366 "
PUR 751
C4.H10.02
1000 -I
M WT 90
B PK 59
RANK 3
# 919
PUR 742
M/Z
r
,1,1
. i
2-PENTANONE , 4-HYDROXY-4-METHYL-
r
ill i 1 i
,
i ''''' i i * ' * * i * * * i ' * [ 1 ' i
i . I
2-PENTANOL, 2,4-DIMETHYL- / ' " '
1 III 1 1
i , i 1 .
l .1
TERT-BUTYL HYDROPEROXIDE
r
i , i 1 i
. ..II
20 30 40 50 60 70 80 90 100 110
o
>>ป
r>
-------
Library Search Data: 30068106 # 221 Base m/z: 43
08/31/9821:30:00+ 2:27 Cali: 30068106 # 3 R1C: 275968.
Sample: T-MM5-3 1/3SA/1ML INST. ID: F16
Conds.: UG/ML *1ML *100%/100% *(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
921 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 5159 NONANE
2 5151 HEPTANE, 3,4-DlMETHYL-
3 3086 HEXANE, 2,4-DIMETHYL-
4 5141 HEPTANE, 2,4-DlMETHYL-
5 19015 DECANE, 2,5,6-TRIMETHYL-
6 5144 HEPTANE, 4-ETHYL-
7 8085 HEPTANE, 2,4,6-TRIMETHYL-
8 11607 UNDECANE
9 5154 HEXANE, 4-ETHYL-2-METHYL-
Rank
1
2
3
4
5
6
7
8
9
Formula
C9.H20
C9.H20
C8.H18
C9.H20
C13.H28
C9.H20
C10.H22
C11.H24
C9.H20
M.Ut
128
128
114
128
184
128
142
156
128
B.Pk
43
43
43
43
57
43
43
43
57
Purity
942
905
897
877
871
869
865
863
862
Fit
986
928
962
926
907
912
903
918
909
RFit
942
905
908
890
891
869
881
919
862
Rank
1
2
3
A
5
6
7
8
9
Ret.Time
B.P.Int.
US.Par.1
US.Par.2
C.A.S. #
111-84-2
922-28-1
589-43-5
2213-23-2
62108-23-0
2216-32-2
2613-61-8
1120-21-4
3074-75-7
1017
-------
MID LIBRARY SEARCH
08/31/98 21:30:00 + 2:27
SAMPLE: T-MM5-3 1/3SA/1ML INST. ID:
CONDS.: UG/ML *1ML *100Z/100Z *
-------
Library Search Data: 30068106 # 311 Base m/z: 99
08/31/9821:30:00+ 3:28 Cali: 30068106 # 3 R1C: 84864.
Sample: T-MM5-3 1/3SA/1ML INST. ID: F16
Conds.: UG/ML *1ML *100%/100% *(NA/NA )/1/3SA NA M
Enhanced (S 158 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
346 matched at least 6 of the 16 largest peaks in the unknown
Rank In. Name
1 15124 2,5-FUR AND I ONE, 3-(1,1-DIMETHYLPROPYDD1HYDRO-
2 1394 2-PIPERIDINONE
3 18863 CIS-4-HYDROXY-3-METHYLDECANOIC ACID LACTONE
4 18864 TRANS-4-HYDROXY-3-METHYLDECANOIC ACID LACTONE
5 1501 PHENOL-D6-
6 11410 5-HYDROXYNONANOIC ACID LACTONE
7 22383 C1S-4-HYDROXY-3-METHYLUNDECANOIC ACID LACTONE
8 1399 1-PYRROLIDINECARBOXALDEHYDE
9 4906 2H-PYRAN-2-ONE, 6-ETHYLTETRAHYDRO-
Rank Formula
1
2
3
4
5
6
7
8
9
C9.
C5.
C11
C11
C6.
C9.
C12
C5.
C7.
H14.03
H9.0.N
.H20.02
.H20.02
O.D6
H16.02
.H22.02
H9.0.N
H12.02
M.Ut B.
170
99
184
184
100
156
198
99
128
.Pk
99
30
99
99
99
99
99
99
42
Purity
529
527
517
514
512
501
495
494
478
Fit
829
870
819
814
879
856
856
868
871
RFit
553
544
587
598
549
555
548
514
525
Rank
1
2
3
4
5
6
7
8
9
Ret.Time
B.P.lnt.
US.Par.1
US.Par.2
C.A.S. #
56666-76-3
675-20 7
13127-88-3
3760-54-1
3301-90-4
101-E
-------
MID LIBRARY SEARCH /l/3SA NA M
ENHANCED
-------
Library Search Data: 30068106 # 445 Base m/z: 43
08/31/98 21:30:00 + 4:57 Cali: 30068106 # 3 R1C: 110592.
Sample: T-MM5-3 1/3SA/1ML INST. ID: F16
Conds.: UG/ML *1ML *100%/100% *
-------
MID LIBRARY SEARCH (LIBRARYNB) DATA: 30068106 # 445 BASE M/Z: 43
08/31/98 21:30:00 + 4:57 CALI: 30068106 # 3 RIC: 110592.
SAMPLE: T-MM5-3 1/3SA/1ML INST. ID: F16
CONDS.: UG/ML *1ML *100Z/100Z */l/3SA NA M
ENHANCED H - ... ... 1 .
UNDECANE ' ' '
J.
II
OCTANE, 3,5-DIMETHYL-
i
ill 1 i 1 .1
DECANE, 2,5,9-TRIMETHYL-
1
40 60 80 100 120 140 160
-------
Library Search Data: 30068106 # 557 Base m/z: A3
08/31/9821:30:00+ 6:12 Cati: 30068106 # 3 R1C: 132352.
Sample: T-MM5-3 1/3SA/1ML INST. ID: F16
Conds.: UG/ML *1ML *100%/100% *(NA/NA )/1/3SA NA M
Enhanced (S 158 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
990 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 15343 DOOECANE
2 11607 UNDECANE
3 19016 UNDECANE, 4,7-DIMETHYL-
4 15353 2,6-DIMETHYLDECANE
5 8104 OCTANE, 3,5-DIMETHYL-
6 19015 DECANE, 2,5,6-TRIMETHYL-
7 22530 TETRADECANE
8 19028 DECANE, 2,4,6-TRIMETHYL-
9 11602 OCTANE, 2,4,6-TRIMETHYL-
Rank
1
2
3
4
5
6
7
8
9
Rank
1
2
3
4
5
6
7
8
9
Formula
C12.H26
C11.H24
C13.H28
C12.H?6
C10.H22
C13.H28
C14.H30
C13.H28
C11.H24
Ret.Time
B.P.Int.
US.Par.1
M.Ut
170
156
184
170
142
184
198
184
156
B.Pk Purity Fit
57
43
43
43
57
57
43
43
57
US. Par. 2
895 970
874 966
871 962
862 923
860 946
860 933
855 924
855 941
855 965
C.A.S. #
112-40-3
1120-21-4
17301-32-5
13150-81-7
15869-93-9
62108-23-0
629-59-4
62108-27-4
62016-37-9
RFit
895
901
872
869
860
861
912
861
855
-------
MID LIBRARY SEARCH (LIBRARYNB) DATA:
08/31/98 21:30:00 + 6:12 . CALI:
SAMPLE: T-MM5-3 1/3SA/1ML INST. ID: F16
CONDS.: UG/ML *1ML *100Z/100Z *
-------
Library Search Data: 30068106 # 634 Base m/z: 57
08/31/9821:30:00+ 7:03 Cali: 30068106 # 3 RIC: 136960.
Sample: T-MM5-3 1/3SA/1ML IKIST. ID: F16
Conds.: UG/ML *1ML *100%/100% "(NA/NA )/1/3SA NA M
Enhanced (S 158 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
748 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 37462 HEPTADECANE, 2,6-DIMETHYL-
2 14799 1-DECENE, 3,4-DIMETHYL-
3 19523 1-DECANOL, 2-ETHYL-
4 22534 TRIDECANE, 7-METHYL-
5 15353 2,6-DIMETHYLDECANE
6 26408 2-ETHYL-1-DOOECANOL
7 42196 HEPTADECANE, 2,6,10,14-TETRAMETHYL-
8 26409 2-HEXYL-1-OCTANOL
9 32418 2-HEXYL-1-DECANOL
Rank
1
2
3
t.
5
6
7
8
9
Formula
C19.H40
C12.H24
C12.H26.0
C14.H30
C12.H26
C14.H30.0
C21.H44
C14.H30.0
C16.H34.0
M.Ut B,
268
168
186
198
170
214
296
214
242
.Pk
57
57
57
57
43
57
57
57
57
Purity
687
686
679
667
659
656
654
653
652
Fit
938
940
928
913
918
899
910
899
897
RFit
702
686
692
681
664
675
675
683
680
Rank
1
2
3
i,
5
6
7
8
9
Ret.Time
B.P.Int.
US.Par.1
US.Par.2
C.A.S. #
54105-67-8
50871-03-9
21078-65-9
26730-14-3
13150-81-7
18344-37-1
-------
MID LIBRARY SEARCH DATA: 30068106 # 634 BASE M/Z: 57
08/31/98 21:30:00 + 7:03 CALI: 30068106 # 3 RIC: 136960.
SAMPLE: T-MM5-3 1/3SA/1ML INST. ID: F16
CONDS. : UG/ML *1ML *100Z/100Z *(NA/NA >/l/3SA NA M
ENHANCED
1126 i
SAMPLE
C19.H40
1126 1
M WT 268
B PK 57
RANK 1
# 37462
PUR 687
C12.H24
1126 -i
M WT 168
B PK 57
RANK 2
# 14799
PUR 686
C12.H26.0
1126 -I
M WT 186
B PK 57
RANK 3
# 19523
PUR 679
M/Z
r
I
r
1
r
**"*-
.III i .1. .. .11 . 1 1 .ii. .1.. i . . .. .. ... . ...
HEPT ADEC ANE , 2 , 6-D I METHYL-
ll Lj jJ 1 ^ -. KU . .-^M- , .
1-DECENE, 3,4-OIMETHYL-
1. . ,1
1-DECANOL, 2-ETHYL-
r
1
50
1 III ll. .. .- ..-- -
100 150 200 250
-------
Library Search Data: 30068106 # 653
08/31/98 21:30:00 + 7:16 Cali: 30068106 # 3
Sample: T-MM5-3 1/3SA/1ML INST. ID: F16
Conds.: UG/ML *1ML *100%/100% *(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
Base m/z: 142
RIC: 57920.
62231 spectra in LIBRARYNB searched for maximum PURITY
298 matched at least 4 of the 16 largest peaks in the unknown
Rank In. Name
1 8109 1H-INDENE, 1-ETHYLIDENE-
2 8107 NAPHTHALENE, 1-METHYL-
3 8108 1,4-METHANONAPHTHALENE, 1,4-DIHYDRO-
4 8111 NAPHTHALENE, 2-METHYL-
5 8110 BENZOCYCLOHEPTATRIENE
6 12521 2-CYCLOPENTEN-1-OL, 1-PHENYL-
7 7992 BENZENEACETONITRILE, 4-CYANO-
8 15865 1-NAPHTHALENEETHANOL
9 15368 BICYCLOC2.2.11HEPT-2-ENE, 2-PHENYL-
Rank
1
2
3
4
5
6
7
S
9
Formula
C11.H10
C11.H10
C11.H10
C11.H10
C11.H10
C11.H12.0
C9.H6.N2
C12.H12.0
C13.H14
M.Wt
142
142
142
142
142
160
142
172
170
B.Pk
141
142
141
142
141
142
142
141
142
Purity
760
746
740
728
706
577
574
563
562
Fit
956
938
932
926
931
758
790
733
738
RFit
779
787
767
779
721
743
622
677
622
Ret.rime
B.P.Int.
US.Par.1
US.Par.2
C.A.S.
2471-
90-
4453-
91-
264-
56667-
876-
773-
4237-
#
83-2
12-0
90-1
57-6
09-5
10-8
31-3
99-9
08-5
10:
-------
MID LIBRARY SEARCH 1 , .'
1 .. . . . , .. ... ii.
1 ... .......
1H-INDENE/ 1-ETHYLIDENE- ^v {^^-^/
i ,, 1 . ,
1 .1
i 1 .
I
NAPHTHALENE, 1 -METHYL-
1 .1
* .11
1 , 4-METHANONAPHTHALENE , 1 , 4-D I HYDRO-
1 ll . . . . ll.l. .
1. u .1
1 1,
i
M/Z
40
60
80
100
120
140
160
180
200
cn
-------
Library Search
08/31/98 31:30:00 + 7:23
Sample: T-MM5-3 1/3SA/1ML
Conds.: UG/ML *1ML *100%/100%
Enhanced (S 15B 2N OT)
Data: 30068106 # 664
Cali: 30068106 # 3
INST. ID: F16
*(NA/NA )/1/3SA NA M
Base m/z: 57
R1C: 165888.
62231 spectra in LIBRARYNB searched for maximum PURITY
324 matched at least 8 of the 16 largest peaks in the unknown
Rank In. Name
1 19016 UNDECANE, 4,7-DIMETHYL-
2 8104 OCTANE, 3,5-DIMETHYL-
3 19015 DECANE, 2,5,6-TRIMETHYL-
4 19026 DECANE, 2,6,8-TRIMETHYL-
5 11602 OCTANE, 2,4,6-TRIMETHYL-
6 19013 DECANE, 2,5,9-TRIMETHYL-
7 18985 TRI DECANE
8 8089 NONANE, 2-METHYL-
9 8102 HEXANE, 2,2,3,3-TETRAMETHYL-
Rank
1
2
3
i,
5
6
7
3
9
Rank
1
Formula
C13.H28
C10.H22
C13.H28
C13.H28
C11.H24
C13.H28
C13.H2B
C10.H22
C10.H22
Ret.Time
B.P.lnt.
US.Par.1
M.Ut
184
142
184
184
156
184
184
142
142
B.Pk Purity Fit
43
57
57
57
57
57
57
43
57
US. Par. 2
829 939
828 941
826 931
823 940
823 965
816 935
815 948
798 934
795 918
C.A.S. #
17301-32-5
15869-93-9
62108-23-0
62108-26-3
62016-37-9
62108-22-9
629-50-5
871-83-0
13475-81-5
RFit
845
836
826
827
825
816
831
808
795
-------
1210
SAMPLE
MID LIBRARY SEARCH (LIBRARYNB)
08/31/98 21:38:00 + 7:23
SAMPLE: T-MM5-3 1/3SA/1ML INST. ID:
CONDS.: UG/ML *1ML *1007./100Z */l/3SA
ENHANCED
DATA: 30068106 # 664
CALI: 30068106 # 3
BASE M/Z: 57
RIC: 165888.
F16
NA M
C13.H28
1210
M WT 184
B PK 43
RANK 1
# 19016
PUR 829
C10.H22
1210
UNDECANE , 4 , 7-0 I METHYL-
M WT
B PK
142
57
RANK 2
# 8104
PUR 828
OCTANE > 3, 5-0 I METHYL-
C13.H28
1210 1
M WT 184
B PK 57
RANK 3
ซ 19015 '
PUR 826
M/Z
r
.1,
1
DECANE , 2 , 5 , 6-TR I METHYL-
. ill II
50 100 150 200 250 300
c:
(D
O
-------
Library Search Data: 30068106 # 724 Base m/z: 172
08/31/9821:30:00+ 8:03 Cali: 30068106 # 3 RIC: 82816.
Sample: T-MMS-3 1/3SA/1ML INST. ID: F16
Conds.: UG/Ml *1ML *100%/100% *(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
224 matched at least 4 of the 16 largest peaks in the unknown
Rank In. Name
1 15856 1,1'-BIPHENYL, 2-FLUORO-
2 15857 1,1'-BIPHENYL, 4-FLUORO-
3 15721 4-(2-HYDROXYPHENYL)PYRIMIDINE
4 15828 1,8-NAPHTHYRIDINE, 2,4,7-TRIMETHYL-
5 15722 2-(2-HYDROXYPHENYL)PYRIMIDINE
6 15004 BENZENE, 1-BROMO-4-METHYL-
7 15719 5-(4-HYDROXYPHENYL)PYRIHIDINE
S 39206 1-(2-(2-METHYL-5-PYRIDYL)ETHYL)-2,3,5-TRIMETHYLINDOLE
? 14964 IMIDAZOLE, 4-CHLORO-2-TRIFLUOROMETHYL-
Formula
C12.H9.F
C12.H9.F
C10.H8.0.N2
C11.H12.N2
C10.H8.0.N2
C7.H7.BR
C10.H8.0.N2
C19.H22.N2
C4.H2.N2.CL.F3
M.Wt
172
172
172
172
172
170
172
278
170
B.Pk
172
172
172
172
172
91
172
172
170
Purity,;
Sr
S5ft^
596
507
474
431
426
379
378
=*ซ=
994
989
854
885
755
596
684
571
542
' IHit-
-------
1138
SAMPLE
MID LIBRARY SEARCH (LIBRARYNB) DATA:
08/31/98 21:30:00 + 8:03 CALI:
SAMPLE: T-MM5-3 1/3SA/1ML INST. ID: F16
CONDS.: UG/ML *1ML *100Z/100Z * PYR I M I D I NE
40
60
80
100
120
140
160
180
200
r >
-------
Library Search Data: 30068106 # 739
08/31/98 21:30:00 + 8:13 Call: 30068106 # 3
Sample: T-MM5-3 1/3SA/1ML INST. ID: F16
Conds.: UG/ML *1ML *100%/100X *(NA/NA )/1/3SA NA M
Enhanced (S 158 2N OT)
Base m/z: 57
R1C: 158720.
62231 spectra in L1BRARYNB searched for maximum PURITY
712 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 42196 HEPTADECANE, 2,6,10,14-TETRAMETHYL-
2 25991 OODECANE, 2,6,10-TRIMETHYL-
3 25997 PENTADECANE
4 22535 DODECANE, 4,6-DIMETHYL-
5 37462 HEPTADECANE, 2,6-DIMETHYL-
6 19007 DOOECANE, 3-METHYL-
7 26001 DOOECANE, 2,7,10-TR1METHYL-
8 22530 TETRADECANE
9 18998 UNDECANE, 3,7-DIMETHYL-
Rank
1
2
5
4
5
b
7
3
Formula
C21.H44
C15.H32
C15.H32
C14.H30
C19.H40
C13.H28
C15.H32
C14.H30
C13.H28
M.Ut
296
212
212
198
268
184
212
198
184
B.Pk
57
57
57
57
57
57
57
43
43
Purity
812
805
800
796
791
787
785
782
777
Fit
930
959
936
940
924
931
973
912
924
RFit
835
810
815
800
824
788
795
799
778
Ret.Time
B.P.Int.
US.Par.1 US.Par.2
C.A.S.
18344-
3891-
629-
61141-
54105-
17312-
74645-
629
17301-
37-1
98-3
62-9
/2-8
67-8
57-1
98-0
59-4
29-0
101:
-------
1212
SAMPLE
MID LIBRARY SEARCH (LIBRARYNB)
08/31/98 21:30:00 + 8:13
SAMPLE: T-MM5-3 1/3SA/1ML INST. ID:
CONDS. : UG/ML *1ML *100Z/100?: *
DATA: 30068106 # 739
CALI: 30068106 # 3
F16
NA M
BASE M/Z: 57
RIC: 158720.
jj
C21.H44
1212
M WT 296
B PK 57
RANK 1
# 42196
PUR 812
C15.H32
1212
M WT 212
B PK 57
RANK 2
* 25991
PUR 805
C15.H32
1212
M WT 212
B PK 57
RANK 3
# 25997
PUR 800
HEPTADECANE, 2,6,10,14-TETRAMETHYL-
DODECANE, 2,6,10-TRIMETHYL-
PENT ADECANE
M/Z
59
100
150
200
250
C'
-------
Library Search Data: 30068106 # 765 Base m/z: 43
08/31/9821:30:00+ 8:31 Cali: 30068106 # 3 RIC: 285184.
Sample: T-MM5-3 1/3SA/1ML INST. ID: F16
Conds.: UG/ML *1ML *100%/100% *(NA/NA }/1/3SA NA M
Enhanced (S 15B 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
634 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 22530 TETRADECANE
2 19006 DECANE, 6-ETHYL-2-METHYL-
3 19007 DOOECANE, 3-METHYL-
4 11607 UNDECANE
5 11612 NONANE, 2,5-DIMETHYL-
6 42196 HEPTADECANE, 2,6,10,14-TETRAMETHYL-
7 25996 TRIDECANE, 4,8-DIMETHYL-
8 39681 1-IOOOUNDECANE
9 25997 PENTADECANE
Rank
1
2
3
4
5
6
7
8
9
Formula
C14.H30
C13.H28
C13.H28
C11.H24
C11.H24
C21.H44
C15.H32
C11.H23.I
C15.H32
Rank
1
2
3
4
5
6
7
8
9
M.Wt
198
184
184
156
156
296
212
282
212
B.Pk
43
57
57
43
57
57
57
57
57
Purity
744
734
715
711
708
706
705
703
703
Fit
960
963
917
977
877
925
929
888
928
RFit
744
734
715
711
708
726
710
707
722
Ret.Time
B.P.Int.
US.Par.1
US.Par.2
C.A.S. #
629-59-4
62108-21-8
17312-57-1
1120-21-4
17302-27-1
18344-37-1
55030-62-1
4282-44-4
629-62-9
-------
1331
SAMPLE
MID LIBRARY SEARCH
DATA:
CALI:
30068106 # 765
30068106 # 3
BASE M/Z: 43
RIC: 285184.
F16
NA M
C14.H30
1331
M WT 198
B PK 43
RANK 1
# 22530
PUR 744
C13.H28
1331
M WT 184
B PK 57
RANK 2
tt 19006
PUR 734
TETRADECANE
DECANE, 6-ETHYL-2-METHYL-
C13.H28
1331 1
M WT 184
B PK 57
RANK 3
# 19007 "
PUR 715
DODECANE, 3-METHYL-
1
, J ,1 . i - . .. . , ii i i
M/Z
60
Q0
100
120
140
160
180
200
220
-------
Library Search
08/31/98 21:30:00 + 8:39
Sample: T-MM5-3 1/3SA/1ML
Conds.: UG/ML *1ML *100%/100%
Enhanced (S 15B 2N OT)
Data: 30068106 # 778
Cali: 30068106 # 3
INST. ID: F16
*(NA/NA )/1/3SA NA M
Base m/z: 141
RIC: 79232.
62231 spectra in L1BRARYNB searched for maximum PURITY
421 matched at least 5 of the 16 largest peaks in the unknown
Rank In. Name
1 11622 NAPHTHALENE, 1-ETHYL-
2 11614 NAPHTHALENE, 2-ETHYL-
3 11626 NAPHTHALENE, 1 ,4-DIMETHYL-
4 11619 NAPHTHALENE, 1 ,2-DIMETHYL-
5 11625 NAPHTHALENE, 1 ,3-DIMETHYL-
6 11618 NAPHTHALENE, 2,3-DIMETHYL-
7 11621 NAPHTHALENE, 1 ,8-DIMETHYL-
8 11624 NAPHTHALENE, 1 ,7-DIMETHYL-
9 11620 NAPHTHALENE, 2,6-DIMETHYL-
Rank
1
2
3
4
5
6
7
8
9
Rank
1
2
3
4
5
6
7
8
9
Formula
C12.H12
C12.H12
C12.H12
C12.H12
C12.H12
C12.H12
C12.H12
C12.H12
C12.H12
Ret. Time B.P.Int.
M.Wt
156
156
156
156
156
156
156
156
156
B.Pk
141
141
141
156
156
156
156
156
156
US. Par. 1 US. Par,
Purity
451
443
429
429
421
417
408
408
407
.2 C
Fit
910
892
882
866
850
841
840
823
838
.A.S. n
1127-76-0
939-27-5
571-58-4
573-98-8
575-41-7
581-40-8
569-41-5
575-37-1
581-42-0
RFit
477
480
481
477
483
474
471
484
479
10117
-------
MID LIBRARY SEARCH DATA: 30068106 # 778 BASE M/Z: 141
08/31/98 21:30:00 + 8:39 CALI: 30068106 # 3 RIC: 79232.
SAMPLE: T-MM5-3 1/3SA/1ML INST. ID: F16
CONDS.: UG/ML *1ML * 100Z/1 08?; * ^ ^
1471 -
SAMPLE
C12.H12
1471 i
M WT 156
B PK 141
RANK 1
# 11622
PUR 451
C12.H12
1471 1
M WT 156
B PK 141
RANK 2
# 11614
PUR 443
C12.H12
1471 -,
M WT 156
B PK 141
RANK 3
# 11626 '
PUR 429
M/Z
I
_l i L
1
1 1
ll II III 1 III ill
ii i ill 1 1 1
1. ll
Uง^^
1 1 ll 1
NAPHTHALENE, 1 -ETHYL- fcv ^^fj- *^s
ii
.1.
1
NAPHTHALENE, 2-ETHYL-
.h
NAPHTHALENE, 1,4-DIMETHYL-
ii
i i
40
.1,
60
M
80 100
M.I
120 140 160 180 200
-------
Library Search Data: 30068106 # 822 Base m/z: 57
08/31/9821:30:00+ 9:09 Call: 30068106 # 3 RIC: 145152.
Sample: T-MM5-3 1/3SA/1ML INST. ID: F16
Conds.: UG/ML *1ML *100%/100% *(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
62231 spectra in L1BRARYNB searched for maximum PURITY
855 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 42196 HEPTADECANE, 2,6,10,14-TETRAMETHYL-
2 19016 UNDECANE, 4,7-DIMETHYL-
3 37462 HEPTADECANE, 2,6-OIMETHYL-
4 15353 2,6-DIMETHYLDECANE
5 18987 UNDECANE, 2,8-DIMETHYL-
6 19023 DECANE, 2,6,7-TRIMETHYL-
,7 8104 OCTANE, 3,5-DIMETHYL-
8 19035 DODECANE, 2-METHYL-
9 19054 UNDECANE, 2,6-DIMETHYL-
Rank
1
2
3
4
5
6
7
8
9
Formula
C21.H44
C13.H28
C19.H40
C12.H26
C13.H28
C13.H28
C10.H22
C13.H28
C13.H28
M.Wt
296
184
268
170
184
184
142
184
184
B.Pk
57
43
57
43
43
57
57
43
57
Purity
792
758
757
754
753
749
747
745
742
Fit
959
947
923
916
959
948
961
950
897
RFit
816
765
803
774
758
749
747
755
757
Rank
1
2
3
4
5
6
7
8
9
Ret.Time
B.P.Int.
US.Par.1 US.Par.2
C.A.S.
18344-
17301-
54105-
13150-
17301-
62108-
15869-
1560-
17301-
#
37-1
32-5
67-8
81-7
25-6
25-2
93-9
97-0
23-4
1 (j r
JL \J '^,
-------
MID LIBRARY SEARCH
DATA: 30068106 # 822
CALI: 30068106 # 3
BASE M/Z: 57
RIC: 145152.
F16
NA M
1387
SAMPLE
JU1
44
^_ , , H~. 1 .. i.
HEPTADECANE, 2,6,10,14-TETRAMETHYL-
C21.H44
1387
M WT 296
B PK 57
RANK 1
ft 42196
PUR 792
C13.H28
1387
M WT 184
B PK 43
RANK 2
ft 19016
PUR 758
C19.H40
1387
M WT 268
B PK 57
RANK 3
# 37462
PUR 757
M/Z
UNDECANE , 4 , 7-D I METHYL-
HEPTADECANE , 2,6-01 METHYL-
p
1
II
ll
. .Hi . O . 4L, _-_ . ^-, .-* . r ~-l 1 1 " l T- -* 1 '
50
100
150
200
250
o
. 1
C ')
-------
Library Search
08/31/98 21:30:00 + 9:34
Sample: T-MM5-3 1/3SA/1ML
Conds.: UG/ML *1ML *100%/100%
Enhanced (S 15B 2N OT)
Data: 30068106 # 860
Cali: 30068106 # 3
INST. ID: F16
*(NA/NA )/1/3SA NA H
Base m/z: 57
RIC: 246528.
62231 spectra in LIBRARYNB searched for maximum PURITY
792 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 25997 PENTADECANE
2 19007 DOOECANE, 3-METHYL-
3 22530 TETRADECANE
4 15352 UNDECANE, 2-METHYL-
5 15343 DOOECANE
6 19006 OECANE, 6-ETHYL-2-METHYL-
7 42196 HEPTADECANE. 2,6,10,14-TETRAMETHYL-
8 15353 2,6-DIMETHYLDECANE
9 18998 UNOECANE, 3,7-DIMETHYL-
Rank
1
2
3
4
S
5
7
3
?
Formula
C15.H32
C13.H28
C14.H30
C12.H26
C12.H26
C13.H28
C21.H44
C12.H26
C13.H28
M.Wt
212
184
198
170
170
184
296
170
184
B.Pk
57
57
43
43
57
57
57
43
43
Purity
816
808
807
807
800
799
797
796
790
Fit
963
965
945
952
985
967
939
923
949
RFit
823
808
841
807
800
799
819
796
791
?ank
Ret.Time
B.P.Int.
US.Par.1
US.Par.2
C.A.S
629-
17312-
629-
7045-
112-
62108-
18344-
13150-
17301-
62-9
57-1
59-4
71-8
40-3
21-8
37-1
81-7
29-0
107
-------
MID LIBRARY SEARCH
08/31x98 21:30:09 + 9:34
SAMPLE: T-MM5-3 1/3SA/1ML INST. ID:
CONDS.: UG/ML *1ML * 10072/1007. */l/3SA
ENHANCED
-------
Library Search Data: 30068106 # 905 Base m/z: 41
08/31/98 21:30:00 + 10:04 Cali: 30068106 # 3 RIC: 89088.
Sample: T-MM5-3 1/3SA/1ML INST. ID: F16
Conds.: UG/ML *1ML *100%/100% *(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
751 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 40233 NONADECANOL
2 42521 1-EICOSANOL
3 37444 OXIRANE, HEXADECYL-
4 40193 CIS-9,10-EPOXYOCTADECAN-1-OL
5 37449 OCTADECANAL
6 42180 OCTADECANE, 1-(ETHENYLOXY)-
7 25971 OXIRANE, DOOECYL-
8 22482 2-TRIDECEN-1-OL, (E)-
9 32052 OXIRANE, TETRADECYL-
Rank
1
2
3
i,
5
6
7
8
9
Rank
1
2
3
4
5
6
7
8
9
Formula
C19.H40.0
C20.H42.0
C18.H36.0
C18.H36.02
C18.H36.0
C20.H40.0
C14.H28.0
C13.H26.0
C16.H32.0
Ret .Time
B.P.Int.
US.Par.1
M.Wt
284
298
268
284
268
296
212
198
240
B.Pk Purity Fit
43
43
57
55
43
43
41
57
41
US. Par. 2
653 934
647 928
638 853
638 904
628 851
625 939
625 891
621 898
619 935
C.A.S. #
52783-43-4
629-96-9
7390-81-0
13980-12-6
638-66-4
930-02-9
3234-28-4
74962-98-4
7320-37-8
RFit
682
680
674
668
687
650
643
644
619
ป
lu
, o
-------
1127
SAMPLE
MID LIBRARY SEARCH (LIBRARYNB)
08/31/98 21:38:00 + 10:04
SAMPLE: T-MM5-3 1/3SA/1ML INST. ID:
CONDS.: UG/ML *1ML *1002/1007. *
DATA: 30068106 * 905
CALI: 30068106 # 3
BASE M/Z: 41
RIC: 89088.
F16
NA M
C19.H40.0
1127 n
M WT 284
B PK 43
RANK 1
# 40233
PUR 653
NONADECANOL
C20.H42.0
1127
M WT 298
B PK 43
RANK 2
# 42521
PUR 647
C18.H36.0
1127
M WT 268
B PK 57
RANK 3
# 37444 '
PUR 638
M/Z
1-EICOSANOL
OXIRANE, HEXADECYL-
50
108
150
200
250
300
350
400
-------
Library Search Data: 30068106 # 949 Base m/z: 57
08/31/9821:30:00+10:33 Cali: 30068106 # 3 RIC: 260096.
Sample: T-MM5-3 1/3SA/1ML INST. ID: F16
Conds.: UG/ML *1ML *100%/100% *(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
360 matched at least 8 of the 16 largest peaks in the unknown
Rank In. Name
1 37465 NONADECANE
2 37462 HEPTADECANE, 2,6-DIMETHYL-
3 42196 HEPTADECANE, 2,6,10, 14-TETRAMETHYL-
4 15969 HYDROXYLAMINE, 0-DECYL-
5 19016 UNDECANE, 4,7-DIMETHYL-
6 25997 PENTADECANE
7 19054 UNDECANE, 2,6-DIMETHYL-
8 18985 TRIDECANE
9 19523 1-OECANOL, 2-ETHYL-
Rank
1
2
5
4
3
i
7
i
)
Formula
C19.H40
C19.H40
C21.H44
C10.H23.0.N
C13.H28
C15.H32
C13.H28
C13.H28
C12.H26.0
M.Wt
268
268
296
173
184
212
184
184
186
B.Pk
57
57
57
43
43
57
57
57
57
Purity
842
840
831
823
819
819
805
804
800
Fit
952
944
951
962
962
953
919
964
927
RFit
867
865
849
826
819
844
805
807
813
lank
Ret.Time
B.P.Int.
US.Par.1
US.Par.2
C.A.S.
629-
54105-
18344-
29812-
17301-
629-
17301-
629-
21078-
92-5
67-8
37-1
79-1
32-5
62-9
23-4
50-5
65-9
107
-------
MID LIBRARY SEARCH CLIBRARYNB) DATA: 30068106 # 949 BASE M/Z: 57
08/31/98 21:30:00 + 10:33 CALI: 30068106 # 3 RIC: 260096.
SAMPLE: T-MM5-3 1/3SA/1ML INST. ID: F16
CONDS.: UG/ML *1ML * 100Z/1 00Z *
1044
SAMPLE
C19.H40
1044 -
M WT 268
B PK 57
RANK 1
# 37465
PUR 842
C19.H48
1044 i
M WT 268
B PK 57
RANK 2
# 37462
PUR 840
C21.H44
1044 i
M WT 296
B PK 57
RANK 3
# 42196
PUR 831
1,
, jl
, .1
Ji -HI -- .. .
NONADECANE fr f tVr^> C^-^- ' ......
1,
1
||
||
11
11 nl ..i .. ........
HEPT ADECANE , 2 , 6-D I METHYL-
I i i ..1
HEPTADECANE , 2,6,10,1 4-TETRAMETHYL-
||
M/Z
50
100
150
200
258
300
-------
Library Search Data: 30068106 # 989 Base m/z: 57
08/31/98 21-30:00 + 11:00 Cali: 30068106 # 3 RIC: 157440.
Sample: T-MM5-3 1/3SA/1ML INST. ID: F16
Conds.: UG/ML *1ML *100%/100% *(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
691 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 37462 HEPTADECANE, 2,6-DIMETHYL-
2 25996 TRIDECANE, 4,8-DIMETHYL-
3 19054 UNDECANE, 2,6-DIMETHYL-
4 22536 TRIDECANE, 3-METHYL-
5 37465 NONADECANE
6 25997 PENTADECANE
7 42196 HEPTADECANE, 2,6,10,14-TETRAMETHYL-
8 22530 TETRADECANE
9 29264 TRIDECANE, 5-PROPYL-
Rank
1
2
3
4
5
6
7
8
9
Formula
C19.H40
C15.H32
C13.H28
C14.H30
C19.H40
C15.H32
C21 .H44
C14.H30
C16.H34
M.Ut
268
212
184
198
268
212
296
198
226
B.Pk
57
57
57
57
57
57
57
43
57
Purity
834
824
820
816
814
807
807
803
803
Fit
955
949
948
968
930
936
943
925
957
RFit
844
825
830
816
842
830
823
823
807
Rank
1
2
3
4
5
6
7
8
9
Ret.Time
B.P.Int.
US.Par.1
US.Par.2
C.A.S
54105
55030
17301
6418
629
629
18344
629
55045
67-8
62-1
23-4
41-3
92-5
62-9
37-1
59-4
11-9
1077
-------
MID LIBRARY SEARCH CLIBRARYNB) DATA: 30068106 # 989 BASE M/Z: 57
08/31/98 21:30:00 + 11:00 CALI: 30068106 # 3 RIC: 157440.
SAMPLE: T-MM5-3 1/3SA/1ML INST. ID: F16
CONDS.: UG/ML *1ML * 100Z/1 00Z */l/3SA NA M
ENHANCED
1000 1
SAMPLE
C19.H40
1000 I
M NT 268
B PK 57
RANK 1
# 37462
PUR 834
C15.H32
1000 i
M WT 212
B PK 57
RANK 2
# 25996
PUR 824
C13.H28
1000 1
M WT 184
B PK 57
RANK 3
# 19054 '
PUR 828
r
r
r
,|
r
i
II
..il
HEPTADECANE, 2,6-DIMETHYL- Ov \!^^^/
1
II
h
,, . 1 .11 . - -- - * ... ~ -
TRIDECANE, 4,8-DIMETHYL-
I
,
.h - ' --
UNDECAHE, 2,6-DIMETHYL-
,
a
. Il . ,.ll. ,H , . r-^ , ,
M/Z
50
100
150
200
250
O
- i
C '
-------
Library Search Data: 30068106 #1037
08/31/98 21:30:00 + 11:32 Cali: 30068106 # 3
Sample: T-HM5-3 1/3SA/1ML INST. ID: F16
Conds.: UG/ML *1ML *100%/100% *(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
Base m/z: 57
RIC: 239616.
62231 spectra in LIBRARYNB searched for maximum PURITY
713 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 37462 HEPTADECANE, 2,6-DlMETHYL-
2 42196 HEPTADECANE, 2,6,10.14-TETRAMETHYL-
3 26001 DOOECANE, 2,7,10-TRIMETHYL-
4 25991 DOOECANE, 2,6,10-TRIMETHYL-
5 22535 DOOECANE, 4,6-DIMETHYL-
6 37466 PENTADECANE, 2,6,10.14-TETRAMETHYL-
7 37465 NONADECANE
8 25994 DOOECANE, 2,6,11-TR1HETHYL-
9 22534 TRIDECANE, 7-METHYL-
Rank
1
2
3
4
5
6
7
8
9
Formula
C19.H40
C21.H44
C15.H32
C15.H32
C14.H30
C19.H40
C19.H40
C15.H32
C14.H30
M.Ut B,
268
296
212
212
198
268
268
212
198
.Pk
57
57
57
57
57
71
57
57
57
Purity
872
830
818
818
818
816
812
796
792
Fit
974
945
966
968
962
944
928
941
914
RFit
880
855
824
823
819
832
836
807
805
Rank
1
2
3
4
5
6
7
8
9
Ret.Time
B.P.Int.
US.Par.1
US.Par.2
C.A.S
54105-
18344-
74645-
3891-
61141-
1921-
629-
31295-
26730-
#
67-8
37-1
98-0
98-3
72-8
70-6
92-5
56-4
14-3
10 TL
-------
1232
SAMPLE
MID LIBRARY SEARCH (LIBRARYNB)
08/31/98 21:30:00 + 11:32
SAMPLE: T-MM5-3 1/3SA/1ML INST. ID:
CONDS.: UG/ML *1ML * 100Z/1 00Z *
-------
Library Search Data: 30068106 #1115 Base m/z: 57
08/31/98 21:30:00 + 12:24 Call: 30068106 # 3 RIC: 131328.
Sample: T-MM5-3 1/3SA/1ML INST. ID: F16
Conds.: UG/ML *1ML *100%/100% *(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
934 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 37465 NONADECANE
2 22530 TETRADECANE
3 25997 PENTADECANE
4 19016 UNDECANE, 4,7-DIMETHYL-
5 19006 DECANE, 6-ETHYL-2-METHYL-
6 15969 HYDROXYLAMINE, 0-DECYL-
7 15358 UNDECANE, 3-METHYl-
8 37462 HEPTADECANE, 2,6-DIMETHYL-
9 42196 HEPTADECANE, 2,6,10,14-TETRAMETHYL-
Rank
1
2
3
4
5
6
7
8
9
Formula
C19.H40
C14.H30
C15.H32
C13.H28
C13.H28
C10.H23.0.N
C12.H26
C19.H40
C21.H44
Rank
1
2
3
4
5
6
7
Ret.Time
B.P.Int.
US.Par.1
M.Wt
268
198
212
184
184
173
170
268
296
B.Pk Purity Fit
57
43
57
43
57
43
57
57
57
US. Par. 2
806 947
801 950
800 959
788 958
785 966
780 949
780 945
780 917
778 937
C.A.S. #
629-92-5
629-59-4
629-62-9
17301-32-5
62108-21-8
29812-79-1
1002-43-3
54105-67-8
18344-37-1
RFit
832
835
823
789
785
798
783
826
812
-------
MID LIBRARY SEARCH DATA:
08/31/98 21:30:00 + 12:24 CALI:
SAMPLE: T-MM5-3 1/3SA/1ML INST. ID: F16
CONDS.: UG/ML *1ML * 100Z/100Z */l/3SA NA M
ENHANCED
-------
Base m/z: 57
RIC: 135680.
Library Search Data: 30068106 #1120
08/31/98 21:30:00 + 12:27 Cali: 30068106 * 3
Sample: T-MM5-3 1/3SA/1ML INST. ID: F16
Conds.: UG/ML *1ML *100%/100% *(NA/NA )/1/3SA NA M
Enhanced (S 158 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
840 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 37465 NONADECANE
2 37462 HEPTADECANE, 2,6-DIMETHYL-
3 42196 HEPTADECANE, 2,6,10,14-TETRAMETHYL-
4 46161 TRICOSANE
5 25991 DOOECANE, 2,6,10-TRIMETHYL-
6 42192 HEPTADECANE, 2,6,10,15-TETRAMETHYL-
7 26001 DOOECANE, 2,7,10-TRIMETHYL-
8 29264 TR1DECANE, 5-PROPYL-
9 39859 OCTADECANE, 2,6-DIMETHYL-
Rank
1
2
3
4
5
6
7
8
9
Rank
1
2
3
4
5
6
7
8
9
Formula
C19
C19
C21
C23
CIS
C21
C15
C16
C20
.H40
.H40
.H44
.H48
.H32
.H44
.H32
.H34
.H42
Ret. Time
B.P.Int.
US.Par.1
M.Ut
268
268
296
324
212
296
212
226
282
B.Pk Purity Fit
57
57
57
43
57
57
57
57
57
US. Par. 2
822 952
816 937
802 934
792 905
788 961
782 945
782 964
782 931
781 920
C.A.S. #
629-92-5
54105-67-8
18344-37-1
638-67-5
3891-98-3
54833-48-6
74645-98-0
55045-11-9
75163-97-2
RFit
841
829
818
847
791
810
782
784
795
v^ O
-------
MID LIBRARY SEARCH (LIBRARYNB)
08/31/98 21:30:80 + 12:27
SAMPLE: T-MM5-3 1/3SA/1ML INST. ID:
CONDS.: UG/ML *1ML *100Z/100Z *
-------
Library Search Data: 30068106 #1192 Base m/z: 57
08/31/98 21:30:00 + 13:16 Cali: 30068106 # 3 RIC: 107648.
Sample: T-MM5-3 1/3SA/1ML INST. ID: F16
Conds.: UG/ML *1ML *100%/100% *(NA/NA )/1/3SA NA M
Enhanced (S 158 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
294 matched at least 8 of the 16 largest peaks in the unknown
Rank In. Name
1 37465 NONADECANE
2 37462 HEPTADECANE, 2,6-DlMETHYL-
3 15969 HYDROXYLAMINE, 0-DECYL-
4 19016 UNDECANE, 4,7-DlMETHYL-
5 42196 HEPTADECANE, 2,6,10,14-TETRAMETHYL-
6 25997 PENTADECANE
7 19523 1-DECANOL, 2-ETHYL-
8 15353 2,6-DIMETHYLDECANE
9 22535 DODECANE, 4,6-DIMETHYL-
Rank Formula
1
2
3
4
5
6
7
8
9
C19.H40
C19.H40
C10.H23.0.N
C13.H28
C21.H44
C15.H32
C12.H26.0
C12.H26
C14.H30
Rank
1
2
3
4
5
6
7
8
9
M.Wt
268
268
173
184
296
212
186
170
198
B.Pk
57
57
43
43
57
57
57
43
57
Purity
774
771
760
746
744
732
732
732
729
Fit
950
940
957
955
938
936
929
921
947
RFit
802
796
768
747
778
771
739
743
736
Ret.Time B.P.Int.
US.Par.1
US.Par.2
C.A.S
629
54105
29812
17301
18344
629
21078
13150
61141
92-5
67-8
79-1
32-5
37-1
62-9
65-9
81-7
72-8
-------
MID LIBRARY SEARCH (LIBRARYNB) DATA:
08/31/98 21:30:00 + 13:16 CALI:
SAMPLE: T-MM5-3 1/3SA/1ML INST. ID: F16
CONDS.: UG/ML *1ML *100Z/100Z *
-------
Library Search Data: 30068106 #1336 Base m/z: 57
08/31/9821:30:00+14:53 Cati : 30068106 # 3 RIC: 73216.
Sample: T-MM5-3 1/3SA/1ML INST. ID: F16
Conds.: UG/ML *1ML *100%/100% *(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
429 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 37456 2-METHYLOCTADECANE
2 32058 HEXADECANE, 3-METHYL-
3 49555 PENTACOSANE
4 37462 HEPTADECANE, 2,6-DlMETHYL-
5 46161 TR1COSANE
6 29263 HEXADECANE
7 42197 HENEICOSANE
8 37465 NONADECANE
9 42196 HEPTADECANE, 2,6, 10, 14-TETRAMETHYL-
Rank
1
2
3
4
5
6
7
8
9
Formula
C19.H40
C17.H36
C25.H52
C19.H40
C23.H48
C16.H34
C21.H44
C19.H40
C21.H44
Rank
1
2
3
4
5
6
7
8
9
Ret.Time
B.P.Int.
US.Par.1
M.Wt
268
240
352
268
324
226
296
268
296
B.Pk Purity Fit
43
57
43
57
43
57
57
57
57
US. Par. 2
662 908
642 922
638 877
637 850
632 888
629 904
629 894
627 917
626 861
C.A.S. #
6418-43-5
629-99-2
54105-67-8
638-67-5
544-76-3
629-94-7
629-92-5
18344-37-1
RFit
690
661
716
682
703
672
668
675
671
-------
MID LIBRARY SEARCH (LIBRARYNB) DATA:
88/31/98 21:30:00 + 14:52 CALI:
SAMPLE: T-MM5-3 1/3SA/1ML INST. ID: F16
CONDS.: UG/ML *1ML *100Z/100Z */l/3SA NA M
ENHANCED
30068106 #1336
30068106 tt 3
BASE M/Z: 57
RIC: 73216.
1100
SAMPLE
C19.H40
1100 1
M WT 268
B PK 43
RANK 1
# 37456 '
PUR 662
C17.H36
1100 -I
M WT 240
B PK 57
RANK 2
# 32058 '
PUR 642
C25.H52
1100 1
M WT 352
B PK 43
RANK 3
# 49555
PUR 638
M/Z
1,
,
1
Ji. . JiL n. i ... i . i. . . .
2-METHYLOCTADECANE
I
Ji
HEXADECANE, 3-METHYL-
ll
i .1 .1 . . .... .1. ..
PENTACOSANE
ll
50 100 150 200 250 300 350
CT
-------
Library Search Data: 30068106 #1531 Base m/z: 57
08/31/98 21:30:00 + 17:02 Cali: 30068106 # 3 RIC: 37056.
Sample: T-MM5-3 1/3SA/1ML INST. ID: F16
Conds.: UG/ML *1ML *100%/100% *(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
238 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 37465 NONADECANE
2 37462 HEPTADECANE, 2,6-DlMETHYL-
3 15969 HYDROXYLAMINE, 0-DECYL-
4 22536 TRIDECANE, 3-METHYL-
5 42196 HEPTADECANE, 2,6,10,14-TETRAMETHYL-
6 19035 DODECANE, 2-METHYL-
7 19007 DODECANE, 3-METHYL-
8 46161 TRICOSANE
9 32058 HEXADECANE, 3-METHYL-
Rank
1
2
3
4
5
6
7
8
9
Rank
1
2
3
4
5
6
7
8
9
Formula
C19.H40
C19.H40
C10.H23.0.N
C14.H30
C21.H44
C13.H28
C13.H28
C23.H48
C17.H36
Ret .Time
B.P.Int.
US.Par.1
M.Ut
268
268
173
198
296
184
184
324
240
1
B.Pk Purity Fit
57
57
43
57
57
43
57
43
57
US. Par. 2
663 935
651 911
639 934
634 910
625 922
622 941
621 907
618 874
617 894
C.A.S. #
629-92-5
54105-67-8
29812-79-1
6418-41-3
18344-37-1
1560-97-0
17312-57-1
638-67-5
6418-43-5
RFit
694
681
654
658
651
624
629
696
651
-------
MID LIBRARY SEARCH (LIBRARYNB) DATA:
08/31/98 21:30:00 + 17:02 CALI:
SAMPLE: T-MM5-3 1/3SA/1ML INST. ID: F16
CONDS.: UG/ML *1ML *100Z/100Z *
-------
Library Search
08/31/98 21:30:00 + 17:39
Sample: T-MH5-3 1/3SA/1ML
Conds.: UG/ML *1ML ป100%/100%
Enhanced (S 15B 2N OT)
Data: 30068106 #1587
Cali: 30068106 * 3
1NST. ID: F16
"(NA/NA )/1/3SA NA M
Base m/z: 43
RIC: 106112.
62231 spectra in LIBRARYNB searched for maximum PURITY
950 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 39515 9-EICOSENE, (E)-
2 34410 3-OCTADECENE, (E)-
3 39516 5-EICOSENE, (E)-
4 34418 9-OCTADECENE, (E)-
5 34411 5-OCTADECENE, (E)-
6 31653 1-HEPTADECENE
7 39517 3-EICOSENE, (E)-
8 26416 4-TETRADECANOL
9 32420 1-HEXADECANOL
Rank
1
2
3
4
5
6
7
8
9
Rank
1
2
3
4
5
6
7
8
9
Formula
C20.H40
C18.H36
C20.H40
C18.H36
C18.H36
C17.H34
C20.H40
C14.H30.0
C16.H34.0
Ret.Time
B.P.Int.
US.Par.1
M.Ut
280
252
280
252
252
238
280
214
242
B.Pk Purity Fit
55
69
55
55
55
55
57
43
55
US. Par. 2
795 984
795 975
794 983
794 974
792 971
781 973
781 984
781 986
777 975
C.A.S. #
74685-29-3
7206-19-1
74685-30-6
7206-25-9
7206-21-5
6765-39-5
74685-33-9
1653-33-4
36653-82-4
RFit
799
800
799
797
796
794
786
788
788
10 ฃ
-------
1138
SAMPLE
MID LIBRARY SEARCH CLIBRARYNB)
08/31/98 21:30:00 + 17:39
SAMPLE: T-MM5-3 1/3SA/1ML INST. ID:
CONDS.: UG/ML *1ML *100Z/100Z *
DATA: 30068106 #1587
CALI: 30068106 # 3
F16
NA M
BASE M/Z: 43
RIC: 106112.
O
C20.H40
1138
M WT 280
B PK 55
RANK 1
# 39515
PUR 795
C18.H36
1138
M WT 252
B PK 69
RANK 2
# 34410
PUR 795
C20.H40
1138
M WT 280
B PK 55
RANK 3
# 39516
PUR 794
M/Z
9-EICOSENE, -
3-OCTADECENE, -
_L
5-EICOSENE,
-------
Library Search Data: 30068106 #1809 Base m/z: 57
08/31/9821:30:00+20:07 Cali: 30068106 # 3 RIC: 18560.
Sample: T-MM5-3 1/3SA/1ML INST. ID: F16
Conds.: UG/ML *1ML *100%/100% *(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
334 matched at least 6 of the 16 largest peaks in the unknown
Rank In. Name
1 52672 SILANE, TRICHLOROOCTADECYL-
2 40165 HEXADECANOIC ACID, 2-0X0-, METHYL ESTER
3 46251 DOOECANE, 1,2-DIBROMO-
4 31486 ACETAMIDE, N-METHYL-N-[4-[4-METHOXY-1-HEXAHYDROPYRIDYL]-2-BUTYNYL]
5 5049 OXIRANE, (3,3-DIMETHYLBUTYL)-
6 27504 1-BROMO-3,7-DIMETHYLOCTANE
7 41993 1-1000-2-METHYLUNDECANE
8 20601 2-BROMO-6-METHYLHEPTANE
9 40866 OCTADECANE, 1-CHLORO-
Rank
1
2
3
4
5
6
7
8
9
Formula
C18.H37.CL3.SI
C17.H32.03
C12.H24.BR2
C13.H22.02.N2
C8.H16.0
C10.H21.BR
C12.H25.I
C8.H17.BR
C18.H37.CL
M.Wt B
386
284
326
238
128
220
296
192
288
.Pk
57
57
41
43
57
57
57
57
57
Purity
329
311
302
292
284
283
281
276
275
Fit
706
873
796
793
954
856
872
921
649
RFit
393
324
353
349
288
299
306
278
340
Rank
1
2
3
4
5
6
7
8
9
Ret.Time
B.P.Int.
US.Par.1
US.Par.2
C.A.S. #
112-04-9
55836-30-1
55334-42-4
53907-77-0
3383-83-3
73105-67-6
4730-24-9
3386-33-2
-------
MID LIBRARY SEARCH
30068106 #1809
30068106 # 3
BASE M/Z: 57
RIC: 18560.
1000 I
SAMPLE
C18.H37.CL
1000
M WT 386
B PK 57
RANK 1
# 52672 '
PUR 329
C17.H32.03
1000
M WT 284
B PK 57
RANK 2
# 40165 '
PUR 311
C12.H24.BR
1000
M WT 326
B PK 41
RANK 3
# 46251 '
PUR 302
M/Z
I
3. SI
|
t '' 1 M
2
|
1 1
SILANE, TRICHLOROOCTADECYL-
i ' . - . - | i i i i l ' i ' r^
DODECANE, 1,2-DIBROMO-
1
1 III 1 .. --
50 ' ' 'l00 150 200 250 300 350 406
-------
TIC SELECTION REPORT
DATA FILE: 30068106
THE FOLLOWING PEAKS WERE REJECTED BECAUSE
AT LEAST 40 % OF THEIR SIZE WAS ACCOUNTED FOR BY
TARGET COMPOUNDS ELUTING WITHIN 4 SCANS OF THE
PEAK TOP.
SCAN SIZE AMOUNT
198
341
422
531
830
1088
1386
1386
1553
280160.
222336.
289280.
426880.
363776.
480256.
389632.
383744 .
310784.
30.806
24.448
31.809
46.939
40.000
52.808
50.148
49.390
40.000
TOTAL NUMBER OF UNIDENTIFIED PEAKS WITH SIZE
GREATER THAN 10 % OF THE CLOSEST INTERNAL STANDARD
THAT DOES NOT HAVE INTERFERENCES = 123
INTERNAL STANDARDS THAT HAVE RIC SIZE LESS THAN
50 % OR GREATER THAN 200 % OF THE ESTIMATED RIC SIZE
ARE CONSIDERED TO HAVE INTERFERENCES AND WILL NOT BE USED
FOR OUANriTATION.
PERCENT OF
ESTIMATED
ซ INTERNAL STANDARD RIC SIZE RIC SIZE SCAN
1 CI40 NAPHTHALENE-DS 426880. 222 * 531
2 CI50 ACENAPHTHENE-D10 363776. 163 830
3 CI60 PHENANTHRENE-D10 480256. 207 * 1088
4 CI70 CHRYSENE-D12 310784. 124 1553
5 CI75 PERYLENE-D12 270816. 105 1784
* INDICATES INTERFERENCE
SIZE = AREA
-------
Sample: T-MM5-3
Client: PACIFI
Analyst: DAT
QUANTERRA GC/MS
Target Compound Data Summary Sheet
1/3SA/1ML INST. ID:
Instrument ID: F16
Quan List Threshold: 0.95
Data File.- 300681RI06
Std Id: ST16980902
F16
Date Analyzed: 09/02/98 20:29
Run Factor: 3.00
Surrogate Vol.:
1.00
Surrogate
Surrogate Spike Recoveries
8270-G, LIMS 10/10/96
Surrogate Amount (ug)
Spiked Measured
% Recovery
Measured QC limits
CS20
CS25
CS30
CS45
CS50
CS55
NITROBENZENE-D5
2-FLUOROBIPHENY
TERPHENYL-D14
PHENOL-D5
2 -FLUORO PHENOL
2,4,6-TRIBROMOP
50
50
50
100
100
100
.00
.00
.00
.0
.0
.0
39
54
41
63
57
49
.60
.20
.40
.90
.20
.30
79
108
82
63
57
49
.2
.8
.9
.2
.3
45
62
58
43
36
* 58
107
110
135
130
111
131
Target Compounds : SAP9
Parameter Scan
CS70 2-CHLOROPHENOL-D4
CS75 1,2-DICHLOROBNZN-D4 342
HEXACHLOROBENZENE - C13
C310 N-NITROSODIMETHYLAMINE
PYRIDINE
2-PICOLINE
N - NITROSOMETHYLETHYLAM INE
METHYLMETHANESULFONATE
N-NITROSODIETHYLAMINE
ETHYLMETHANE SULFONATE
PENTACHLOROETHANE
C320 ANILINE
C315 PHENOL 313
C325 BIS (2 -CHLOROETHYL} ETHER
C330 2-CHLOROPHENOL
C335 1, 3-DICHLOROBENZENE
C340 1,4-DICHLOROBENZENE
C345 BENZYL ALCOHOL
C350 1,2-DICHLOROBENZENE
C355 2 -METHYL PHENOL
C360 2,2' -OXYBIS (1-CLPROPAN)
C361 ACETOPHENONE 401
N-NITROSOPYRROLIDINE
N-NITROSOMORPHOLINE
3 -METHYL PHENOL
C365 4 -METHYL PHENOL
C370 N-NITROSO-DI -N- PROPYLAM 423
0-TOLUIDINE
C375 HEXACHLOROETHANE
Result
ND
130.
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
49.
ND
ND
ND
ND
ND
ND
ND
ND
30.
ND
ND
ND
ND
31.
ND
ND
Units
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
Reporting
Limit
30.0
30.0
30.0
30.0
60.0
30.0
30.0
30.0
30.0
30.0
30.0
30. 0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30. 0
Reviewed by:
-------
QUANTERRA GC/MS
Target Compound Data Summary Sheet
Sample: T-MM5-3 1/3SA/1ML
Client: PACIFI
Analyst: DAT Instrument ID: F16
Quan List Threshold: 0.95
INST. ID;
Data File: 300681RI06
Std Id: ST16980902
F16
Date Analyzed: 09/02/98 20:29
Run Factor: 3.00
Surrogate Vol.: 1.00
Target Compounds: SAP9
Parameter
Scan
C410 NITROBENZENE
N-NITROSOPIPERIDINE
C415 ISOPHORONE
C420 2-NITROPHENOL
C425 2,4-DIMETHYLPHENOL
C435 BIS(2-CHLOROETHOXY)METH
C440 2,4-DICHLOROPHENOL
C430 BENZOIC ACID
AA-DIMETHYLPHENETHYLAMINE
C445 1,2,4-TRICHLOROBENZENE
C450 NAPHTHALENE
C455 4-CHLOROANALINE
2, 6-DICHLOROPHENOL
HEXACHLOROPROPENE
C460 HEXACHLOROBUTADIENE
P-PHENYLENE DIAMINE
N-NITROSODI-N-BUTYLAMINE
C465 4-CHLORO-3-METHYLPHENO
SAFROLE
C470 2-METHYLNAPHTHALENE
1,2,4,5-TETRACHLOROBENZENE
ISOSAFROLE (#1)
C510 HEXACHLOROCYCLOPENTADI
C515 2,4,6-TRICHLOROPHENOL
C520 2,4,5-TRICHLOROPHENOL
ISOSAFROLE (#2)
C525 2-CHLORONAPHTHALENE
1-CHLORONAPHTHALENE
C530 2-NITROANALINE
1,4-NAPHTHOQUINONE
C535 DIMETHYLPHTHALATE
1,3 -DINITROBENZENE
C540 ACENAPHTHYLENE
C543 2,6-DINITROTOLUENE
C545 3-NITROANILINE
C550 ACENAPHTHENE
C555 2,4-DINITROPHENOL
C565 DIBENZOFURAN
C560 4-NITROPHENOL
PENTACHLOROBENZENE
C570 2,4-DINITROTOLUENE
1-NAPHTHYLAMINE
2-NAPHTHYLAMINE
2,3,4,6-TETRACHLOROPHENOL
535
654
Result
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
42.
ND
ND
ND
ND
ND
ND
ND
ND
77.
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Units
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
Reporting
Limit
30.0
30.0
30.0
30.0
30.0
30.0
30.0
150.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
60.0
30.0
30.0
30.0
60.0
30.0
15.0
150.0
30.0
30.0
30.0
30.0
30.0
150.0
30.0
150.0
30.0
150.0
30.0
30.0
30.0
30.0
60.0
-------
QUANTERRA GC/MS
Target Compound Data Summary Sheet
Data File: 300681RI06
Std Id: ST16980902
Sample: T-MM5-3 1/3SA/1ML INST. ID: F16
Client: PACIFI Date Analyzed: 09/02/98 20:29
Analyst: DAT Instrument ID: F16 Run Factor: 3.00
Quan List Threshold: 0.95 Surrogate Vol.: 1.00
Parameter
Target Compounds: SAP9
Reporting
Scan Result Units Limit
C580 DIETHYLPHTHALATE
C590 FLUORENE
C585 4-CHLOROPHENYL-PHENYLE
5-NITRO-O-TOLUIDINE
C595 4-NITROANALINE
C610 4, 6-DINITRO-2-METHYLPH
C615 N-NITROSODIPHENYLAMINE
C620 AZOBENZENE
SYM-TRINITROBENZENE
C625 4-BROMOPHENYL-PHENYLET
PHENACETIN
DIALLATE 234
C630 HEXACHLOROBENZENE
4-AMINOBIPHENYL
C635 PENTACHLOROPHENOL
PRONAMIDE
PENTACHLORONITROBENZENE
C640 PHENANTHRENE
C645 ANTHRACENE
2SECBUTYL-4, 6-DINITROPHENOL
C647 CARBAZOLE
C650 DI-N-BUTYLPHTHALATE
4 -NITROQUINOLINE- 1 -OXIDE
METHAPYRILENE
ISODRIN
C655 FLUORANTHENE
CHLOROBENZILATE
C710 BENZIDINE
C715 PYRENE
ARAMITE (#1)
ARAMITE (#2)
P-DIMETHYLAMINOAZOBENZENE
3,3' -DIMETHYLBENZIDINE
KEPONE
C720 BUTYLBENZYLPHTHALATE
2 - ACETYLAMINO FLUORENE
C730 BENZO (A) ANTHRACENE
C72S 3,3' -DICHLOROBENZIDINE
C740 CHRYSENE
C745 BIS(2- ETHYLHEXYL } PHTHA
3 -METHYLCHOLANTHRENE
C760 DI-N-OCTYL PHTHALATE
C7 6 5 BENZO ( B ) FLUORANTHENE
7 , 12 -DIMETHYLBENZANTHRACENE
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
30.0
30.0
30.0
30.0
150.0
150.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
150.0
30.0
150.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
300.0
30.0
30.0
30.0
30.0
30.0
150.0
30.0
30.0
30.0
60.0
30.0
30.0
30.0
30.0
30. 0
30.0
-------
QUANTERRA GC/MS
Target Compound Data Summary Sheet
Data File: 300681RI06
Std Id: ST16980902
INST. ID: F16
Date Analyzed: 09/02/98 20:29
Run Factor: 3.00
Surrogate Vol.: 1.00
Sample: T-MM5-3 1/3SA/1ML
Client: PACIFI
Analyst: DAT Instrument ID: F16
Quan List Threshold: 0.95
Parameter
Target Compounds: SAP9
Scan Result Units
C7 7 0 BENZO(K)FLUORANTHENE
HEXACHLOROPHENE
C775 BENZO(A)PYRENE
C780 INDENO(1,2,3-CD)PYRENE
C785 DIBENZ(A,H)ANTHRACENE
C790 BENZO(G,H,I)PERYLENE
1777
ND
40
ND
ND
ND
ND
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
Reporting
Limit
30.0
30.0
30.0
30.0
30.0
30.0
(> f
-------
DATA FROM FILE: 398681RI06 SCANS 94 TO 1204 ACQUIRED: 09/02/98 20:29:00
CALI: 300681RI06 #3
SAMPLE: T-MM5-3 1/3SA/1ML INST. ID: F16
CONDS.: UG/ML *1ML *100Z/1002 *(NA/NA )/l/3SA NA M
200 .
2:13
400 _
4:27
600 _
6:40
800 _
8:54
1000 _
11:07
TI&E1 J
_L
I
r CS50 2-FLUOROPHENOL
112SS1# 02
ฃ~CS45 PHENOL-D5 99SS1* 03
CI30 1,4-DICHLOROBENZENE-D4 1521SI# 01
TC
320 NITROBENZENE-D5 82SS2* 02
CI40 NAPHTHALENE-OS 136IS2* 01
TC
t_CS25 2-FLUOROBIPHENYL 172SS3# 03
TC
C
ACENAPHTHENE-D10 164IS3* 01
iTC
j
100.07. < 4251650.)
367-12-4
4165-62-2
3855-82-1
4165-60-0
1146-65-2
321-60-8
15067-26-2
O
-------
DATA FROM FILE: 300681RI06 SCANS 1204 TO 2158 ACQUIRED: 09/02/98 20:29:00
CALI: 300681RI06 #3
SAMPLE: T-MM5-3 1/3SA/1ML INST. ID: F16
CONDS.: UG/ML *1ML *100Z/100Z */l/3SA NA M
1400 _
15:34
1600 _H
17:48
1800 _
20:01
2000 _
22:15
I
I
I
CI70 CHRYSENE-D12
100.0?: < 184576.)
CS30 TERPHENYL-D14
244SS5* 02
1718-51-0
240IS5tt 01
1719-03-5
H*
H.
O
-------
STANDARD USED FOR THIS REPORT IS ST16980902
REPORT PRINTED: 9/02/98 23:00:30
ADDITIONAL STANDARD USED FOR THIS REPORT IS: ST16980902A
QUANTERRA QUANTITATION SUMMARY
File: 300681RI06
Sample: T-MM5-3
Analyst: DAT
1/3SA/1ML INST. ID: F16
Instrument Id: F16 Analyzed: 09/02/98 20:29
Compounds with amounts less than 0.20 reported as NOT FOUND
Library
No Entry Name
Mass Meth Scan Ref
Units: UG/ML
Area RRF(L) Amount
1 Sl# 1 CI30 1,4-DICHLOROBENZENE 152 A BV
2 S2# 1 CI40 NAPHTHALENE-D8
3 S3# 1 CI50 ACENAPHTHENE-D10
4 S4# 1 CI60 PHENANTHRENE-D10
5 S5# 1 CI70 CHRYSENE-D12
6 S6# 1 CI75 PERYLENE-D12
7 S2# 2 CS20 NITROBENZENE-OS
8 S3# 3CS25 2-FLUOROBIPHENYL
9 S5# 2 CS30 TERPHENYL-D14
10 Sl# 3 CS45 PHENOL-D5
11 Sl# 2 CS50 2-FLUOROPHENOL
12 S3# 2 CS55 2,4,6-TRIBROMOPHENO
13 Sl# 5 CS70 2-CHLOROPHENOL-D4
14 Sl# 6 CS75 1,2-DICHLOROBNZN-D4
15 S4# 4 HEXACHLOROBENZENE-C13
16 Sltt 15 C310 N-NITROSODIMETHYLAM
17 Sl# 20 PYRIDINE
18 Sl# 30 2-PICOLINE
19 Sl# 40 N-NITROSOMETHYLETHYLAMIN
20 Sl# 60 METHYLMETHANESULFONATE
21 Sl# 70 N-NITROSODIETHYLAMINE
22 Sl# 85 ETHYLMETHANE SULFONATE
23 Sl# 95 PENTACHLOROETHANE
24 Sl#100 C320 ANILINE
25 Sl#105 C315 PHENOL
26 SltfllO C325 BIS(2-CHLOROETHYL)E
27 Sl#115 C330 -2-CHLOROPHENOL
28 Sl#125 C335 1,3-DICHLOROBENZENE
29 Sl#130 C340 1,4-DICHLOROBENZENE
30 Sl#145 C345 BENZYL ALCOHOL
31 Sl#150 C350 1,2-DICHLOROBENZENE
32 Sl#160 C355 2-METHYLPHENOL
33 Sl#165 C360 2,2'-OXYBIS(1-CLPRO
34 Sl#170 C361 ACETOPHENONE
35 Sl#175 N-NITROSOPYRROLIDINE
36 Sl#180 N-NITROSOMORPHOLINE
37 Sl#182 3-METHYL PHENOL
38 Sl#185 C365 4-METHYLPHENOL
39 Sl#190 C370 N-NITROSO-DI-N-PROP
40 Sl#195 0-TOLUIDINE
41 Sl#200 C375 HEXACHLOROETHANE
42 S2# 10 C410 NITROBENZENE
43 S2# 15 N-NITROSOPIPERIDINE
44 S2# 20 C415 ISOPHORONE
45 S2# 25 C420 2-NITROPHENOL
152
136
164
188
240
264
82
172
244
99
112
330
132
152
294
74
79
93
42
80
102
79
117
93
94
93
128
146
146
108
146
108
45
105
100
56
108
108
70
106
117
77
42
82
139
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
BV
BB
BB
BB
BB
VB
BV
BB
BB
BB
BV
BB
BV
BB
BB
VB
BB
VB
BB
BB
BV
BV
BB
342
531
831
1089
1554
1785
423
725
1386
312
200
973
1
342
4
1
1
1
1
1
1
1
1
1
313
320
320
1
344
372
1
1
1
1
2
3
4
5
6
2
3
5
1
1
3
NOT
1
NOT
NOT
NOT
NOT
NOT
NOT
NOT
NOT
NOT
NOT
1
1
1
NOT
1
1
NOT
NOT
NOT
401 1
404 1
411 1
1
1
NOT
NOT
423 1
1 NOT
1
2
NOT
NOT
457 2
2
2
NOT
NOT
27901.
94024.
49022 .
82021.
80400.
74618.
43753 .
82055.
82840.
90260.
54614.
14231.
FOUND
27901.
FOUND
FOUND
FOUND
FOUND
FOUND
FOUND
FOUND
FOUND
FOUND
FOUND
22451.
3280.
396.
FOUND
388.
5339.
FOUND
FOUND
FOUND
13534.
120.
4290.
FOUND
FOUND
6576.
FOUND
FOUND
FOUND
1528.
FOUND
FOUND
1.
1.
1.
1.
1.
1.
0.
1.
0.
2.
1.
0.
0.
1.
1.
1.
1.
0.
1.
0.
0.
0.
0,
000
000
000
000
000
000
470
234
995
025
368
236
920
968
368
497
617
854
934
553
821
,906
.320
40.
40.
40.
40.
40.
40.
39.
54.
41.
63.
57.
49.
43.
16.
3,
0,
0
8
10
0
7
10
2
000
000
000
000
000
000
640
245
412
885
224
275
476
.356
.438
.379
.344
.959
.033
.311
.494
iTc
.028
-------
46 S2# 30 C425 2,4-DIMETHYLPHENOL 107 A BB 501 2 1507. 0.330 1.943
47 S2# 35 C435 BIS(2-CHLOROETHOXY) 93 2 NOT FOUND
48 S2# 40 C440 2,4-DICHLOROPHENOL 162 A BB 520 2 560. 0.308 0.775
49 S2# 45 C430 BENZOIC ACID 122 2 NOT FOUND
lie
-------
50 S2# 50 AA-DIMETHYLPHENETHYLAMIN
51 S2# 55 C445 1,2,4-TRICHLOROBENZ
52 S2# 60 C450 NAPHTHALENE
53 S2# 80 C455 4-CHLOROANALINE
54 S2# 85 2,6-DICHLOROPHENOL
55 S2# 90 HEXACHLOROPROPENE
56 S2# 95 C460 HEXACHLOROBUTADIENE
57 S2#115 P-PHENYLENE DIAMINE
58 S2#120 N-NITROSODI-N-BUTYLAMINE
59 S2#130 C465 4-CHLORO-3-METHYLPH
60 S2#140 SAFROLE
61 S2#145 C470 2-METHYLNAPHTHALENE
62 S3# 10 1,2,4,5-TETRACHLOROBENZE
63 S3# 15 ISOSAFROLE (#1)
64 S3# 20 C510 HEXACHLOROCYCLOPENT
65 S3# 25 C515 2,4,6-TRICHLOROPHEN
66 S3# 30 C520 2,4,5-TRICHLOROPHEN
67 S3# 35 ISOSAFROLE (#2)
68 S3# 40 C525 2 -CHLORONAPHTHALENE
69 S3# 42 1-CHLORONAPHTHALEN
70 S3# 45 C530 2-NITROANALINE
71 S3# 50 1,4-NAPHTHOQUINONE
72 S3# 55 C535 DIMETHYLPHTHALATE
73 S3# 60 1,3-DINITROBENZENE
74 S3# 65 C540 ACENAPHTHYLENE
75 S3# 70 C543 2,6-DINITROTOLUENE
76 S3# 75 C545 3-NITROANILINE
77 S3# 80 C550 ACENAPHTHENE
78 S3# 85 C555 2,4-DINITROPHENOL
79 S3# 90 C565 DIBENZOFURAN
80 S3# 95 C560 4-NITROPHENOL
81 S3 #100 PENTACHLOROBENZENE
82 S3#105 C570 2,4-DINITROTOLUENE
83 S3#110 1-NAPHTHYLAMINE
84 S3#115 2-NAPHTHYLAMINE
85 S3#120 2,3,4,6-TETRACHLOROPHENO
86 S3#130 C580 DIETHYLPHTHALATE
87 S3#135 C590 FLUORENE
88 S3#140 C585 4-CHLOROPHENYL-PHEN
89 S3#145 5-NITRO-O-TOLUIDINE
90 S3#150 C595 4-NITROANALINE
91 S4# 10 C610 4,6-DINITRO-2-METHY
92 S4# 15 C615 N-NITROSODIPHENYLAM
93 S4# 20 C620 AZOBENZENE
94 S4# 25 SYM-TRINITROBENZENE
95 S4# 30 C625 4-BROMOPHENYL-PHENY
96 S4# 35 PHENACETIN
97 S4# 37 DIALLATE
98 S4# 40 C630 HEXACHLOROBENZENE
99 S4# 45 4-AMINOBIPHENYL
100 S4# 50 C635 PENTACHLOROPHENOL
101 S4# 55 PRONAMIDE
102 S4# 60 PENTACHLORONITROBENZENE
103 S4# 65 C640 PHENANTHRENE
104 S4# 70 C645 ANTHRACENE
105 S4# 75 2SECBUTYL-4,6-DINITROPHE
106 S4# 80 C647 CARBAZOLE
107 S4# 85 C650 DI-N-BUTYLPHTHALATE
108 S4#100 4-NITROQUINOLINE-l-OXIDE
109 S4#105 METHAPYRILENE
110 S4#106 ISODRIN
58
180
128
127
162
213
225
108
84
107
162
142
214
162
237
196
196
104
162
162
65
158
163
168
152
165
138
153
184
168
109
250
165
143
143
232
149
166
204
152
138
198
169
77
75
248
108
234
284
169
266
173
237
178
178
211
167
149
190
58
193
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
BB
BV
BV
BB
BB
BV
BB
BB
BB
BB
VB
VB
VB
VB
VB
VB
BB
BB
VB
VB
BV
BB
VB
BB
BB
W
707 2
525 2
535 2
557 2
2 NOT
2 NOT
2 NOT
2 NOT
2 NOT
2 NOT
650 2
654 2
3 NOT
699 3
3 NOT
3 NOT
3 NOT
3 NOT
3 NOT
3 NOT
766 3
3 NOT
806 3
809 3
3 NOT
3 NOT
3 NOT
836 3
860 3
868 3
3 NOT
3 NOT
883 3
3 NOT
3 NOT
896 3
934 3
928 3
3 NOT
943 3
3 NOT
4 NOT
965 4
968 4
1031 4
4 NOT
4 NOT
4 NOT
4 NOT
1078 4
4 NOT
4 NOT
1063 4
1093 4
4 NOT
4 NOT
4 NOT
4 NOT
1241 4
4 NOT
1272 4
2424.
185.
33489.
848.
FOUND
FOUND
FOUND
FOUND
FOUND
FOUND
1794.
45517.
FOUND
296.
FOUND
FOUND
FOUND
FOUND
FOUND
FOUND
721.
FOUND
905.
261.
FOUND
FOUND
FOUND
1302.
150.
1263.
FOUND
FOUND
549.
FOUND
FOUND
298.
948.
4654.
FOUND
3609.
FOUND
FOUND
4111.
512.
900.
FOUND
FOUND
FOUND
FOUND
2522.
FOUND
FOUND
53.
14391.
FOUND
FOUND
FOUND
FOUND
114.
FOUND
572.
1.
0.
1.
0.
0.
0.
0.
0.
1.
0.
1.
0.
1.
0.
0.
1.
1.
0,
0
1
0
0
0
1
0
0
285
331
022
454
248
751
044
502
341
197
159
189
669
,397
.297
.369
.298
.356
.551
.171
.162
.609
.080
.033
.073
.127
0.
0.
13.
0.
3.
25.
5.
1.
0.
1.
0.
0.
0.
1.
0.
0.
2.
8.
3.
0,
2,
2
0
6
0
2
803
238
937
795
081
775
533
173
551
078
917
647
617
127
818
565
,926
.284
.641
.213
.718
.020
.322
.797
.770
.201
-------
Ill S4ttllO C655 FLUORANTHENE
112 S4#120 CHLOROBENZILATE
113 S5tt 10 C710 BENZIDINE
114 S5tt 15 C715 PYRENE
115 S5tt 20 ARAMITE (#1)
116 S5tt 25 ARAMITE (#2)
117 S5# 30 P-DIMETHYLAMINOAZOBENZEN
118 S5tt 35 3,3'-DIMETHYLBENZIDINE
119 S5tt 37 KEPONE
120 S5tt 40 C720 BUTYLBENZYLPHTHALAT
121 S5tt 45 2-ACETYLAMINOFLUORENE
122 S5# 50 C730 BENZO(A)ANTHRACENE
123 S5tt 55 C725 3,3'-DICHLOROBENZID
124 S5tt 60 C740 CHRYSENE
125 S5# 65 C745 BIS (2-ETHYLHEXYL)PH
126 S5tt 85 3-METHYLCHOLANTHRENE
127 S6tt 10 C760 DI-N-OCTYL PHTHALAT
128 S6# 15 C765 BENZO(B)FLUORANTHEN
129 S6tt 20 7,12-DIMETHYLBENZANTHRAC
130 S6# 25 C770 BENZO(K)FLUORANTHEN
131 S6tt 30 HEXACHLOROPHENE
132 S6tt 35 C775 BENZO(A)PYRENE
133 S6# 55 C780 INDENO(1,2,3-CD)PYR
134 S6tt 60 C785 DIBENZ(A,H)ANTHRACE
135 S6tt 65 C790 BENZO(G,H,I)PERYLEN
202
139
184
202
185
185
120
212
272
149
181
228
252
228
149
268
149
252
256
252
196
252
276
278
276
A
A
A
A
A
A
A
A
A
BB
BB
BB
BB
BB
BB
W
BB
VB
1301
4
5
1337
5
5
5
5
1508
5
5
1557
5
1557
1605
1831
6
6
6
6
1777
1775
6
6
6
4
NOT
NOT
5
NOT
NOT
NOT
NOT
5
NOT
NOT
5
NOT
5
5
5
NOT
NOT
NOT
NOT
6
6
NOT
NOT
NOT
FOUND
FOUND
410.
1903.
FOUND
FOUND
FOUND
FOUND
FOUND
FOUND
53.
1764.
FOUND
1764.
5223.
FOUND
FOUND
FOUND
FOUND
FOUND
FOUND
FOUND
300.
101.
519.
0
1
0
1
1
0
0
0
1
.900
.323
.082
.125
.014
.980
.548
.004
.182
0
0
0
0
0
2
0
13
0
.222
.716
.322
.780
.865
.652
.273
.492
.235
-------
BNA, S LIBRARIES ANALYST:
QUANTERRA Internal Standard Check
Standard Filename: ST16980902
DATE:
Analyzed: 09/02/98 14:53
IS#
Standard
Area
RT
IS# 2
Area % | RT
IS# 3
Area %
RT
ST16980902
Upper Limit
Lower Limit
23319. I 3.78
46638.=+200| 4.28
11659.=+ 50 3.28
79260.
158519.=+200
39630.=+ 50
5.91 | 43605. | 9.22
6.41 j 87211.=+200| 9.72
5.41 21803.=+ 50 8.72
Filename
1 300681RI06 j 27901.= 119J 3.80
I I
94024.= 118 5.91
49022.= 112
9.24
IS# 1 = CI30 1,4-DICHLOROBENZENE-D4
IS# 2 = CI40 NAPHTHALENE-D8
IS# 3 = CI50 ACENAPHTHENE-DIO
* - indicates an I.S. is outside QC limit(s)
1
Standard |
Area
IS#
S
4
k 1
RT
Area
IS#
<
5
ซ 1
RT
Area
IS# 6
% 1
RT
ST16980902
Upper Limit
Lower Limit
76218. |12.09
152436.=+200|l2.59
38109.=+ 50|11.59
51424. |17.27
102848.=+200J17.77
25712.=+ 50 16.77
44306. J19.84
88612.=+200|20.34
22153.=+ 50 19.34
Filename
1 300681RI06
82021.= 107 12 . 11
80400.= 156J17.29
74618.= 168 19.85
IS# 4 = CI60 PHENANTHRENE-D10
IS# 5 = CI70 CHRYSENE-D12
IS# 6 = CI75 PERYLENE-D12
* - indicates an I.S. is outside QC limit(s)
HOB
-------
Semivolatile Organics
Method 0010/8270
Client Name: Pacific Environmental Services
Client ID:
LAB ID:
Matrix:
Authorized:
S-MM5-3-F,FH,XAD,COND,BH
300681-0007-SA
AIRTRAIN
30 JUL 98
Sampled: 27 JUL 98
Prepared: 31 JUL 98
Dilution Factor: 100
Parameter
Phenol
bis(2-Chloroethyl)ether
2-Chlorophenol
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Benzyl alcohol
1,2-Dichlorobenzene
2-Methylphenol
2,2/-Oxybis(l-chloropropane)
3/4-Methyl phenol
N-Nitroso-di-n-propylamine
Hexachl oroethane
Nitrobenzene
Isophorone
2-Nitrophenol
2,4-Dimethylphenol
Benzoic acid
bi s (2-Chl oroethoxy) -methane
2,4-Dichlorophenol
1,2,4-Trichlorobenzene
Naphthalene
4-Chloroaniline
Hexachl orobutadi ene
4-Chloro-3-methyl phenol
2-Methyl naphthalene
Hexachl orocycl opentadi ene
2,4,6-Trichlorophenol
2,4,5-Trichlorophenol
2-Chloronaphthalene
2-Nitroani line
Dimethyl phthalate
Acenaphthylene
3-Nitroaniline
Acenaphthene
2,4-Dinitrophenol
4-Nitrophenol
Note G = Reporting limit(s)
Note R = Reporting limit(s)
Wet wt.
Result
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
3200
ND
ND
ND
6300
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
raised due to matrix
raised due to sample
Units
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
dg/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
Reporting
Limit
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
15000
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
15000
3000
3000
3000
3000
15000
3000
15000
15000
interference.
volume limi
tations.
Received: 30 JUL 98
Analyzed: 31 AUG 98
Qualifier
GR
ND = Not Detected
Reported By: Emily Uebelhoer
Approved By: Mike Orbanosky
The cover letter is an integral part of this report.
Rev 230787
11
-------
Semi volatile Organics
Method 0010/8270
(cont.)
Client Name: Pacific Environmental Services
Client ID:
LAB ID:
Matrix:
Authorized:
S-MM5-3-F,FH,XAD,COND,BH
300681-0007-SA
AIRTRAIN
30 JUL 98
Sampled: 27 JUL 98
Prepared: 31 JUL 98
Dilution Factor: 100
Parameter
Dibenzofuran
2,4-Dinitrotoluene
2,6-Dinitrotoluene
Diethyl phthalate
4-Chlorophenyl phenyl ether
Fluorene
4-Nitroaniline
4,6-Dinitro-2-methylphenol
N-Nitrosodiphenylamine
4-Bromophenyl phenyl ether
Hexachlorobenzene
Pentachlorophenol
Phenanthrene
Anthracene
Di-n-butyl phthalate
Fluorantnene
Pyrene
Butyl benzyl phthalate
3,3'-Dichlorobenzidine
Benzo(a)anthracene
bi s(2-Ethyl hexyl)-phthalate
Chrysene
Di-n-octyl phthalate
Benzo b fluoranthene
Benzo k fluoranthene
Benzo a pyrene
Indeno(l,2,3-cd)pyrene
Di benz(a,h)anthracene
Benzo(g,h,i)perylene
Acetophenone
4-Aminobiphenyl
Aniline
Benzidine
3,3'-Dimethylbenzidine
N-Nitrosodimethyl amine
N-Nitrosomorpholine
Pentachloronitrobenzene (PCNB)
o-Toluidine
Wet wt.
Result
Units
Received: 30 JUL 98
Analyzed: 31 AUG 98
Reporting
Limit
Qua! ifier
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
3000
3000
3000
3000
3000
3000
15000
15000
3000
3000
3000
15000
3000
3000
3000
3000
3000
3000
6000
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
3000
15000
3000
30000
6000
3000
3000
15000
6000
ND = Not Detected
Reported By: Emily Uebelhoer
Approved By: Mike Orbanosky
The cover letter is an integral part of this report.
Rev 230787
1105
-------
Semivolatile Organics
Method 0010/8270
(cent.)
Client Name: Pacific Environmental Services
Client ID:
LAB ID:
Matrix:
Authorized:
S-MM5-3-F,FH,XAD,COND,BH
300681-0007-SA
AIRTRAIN
30 JUL 98
Sampled: 27 JUL 98
Prepared: 31 JUL 98
Dilution Factor: 100
Parameter
2-Methoxybenzenamine
Biphenyl
Chloroacetophenone
Cumene
DBCP (l,2-Dibromo-3-chloropropane)
Benzo(e)pyrene
N-N-Diethylaniline
Dimethylaniline
3,3'-Dimethoxybenzidine
Hydroquinone
4,4'-Methyl-bis(2-chloroaniline)
4-Nitrodiphenyl
Trifluralin
Wet wt.
Result
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Units
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
Received: 30 JUL 98
Analyzed: 31 AUG 98
Reporting
Limit
Qualifier
Surrogate
Nitrobenzene-d5
2-Fluorobiphenyl
Terphenyl-dl4
Phenol-d5
2-Fluorophenol
2,4,6-Tribromophenol
Recovery
ND %
ND
ND
ND
ND
ND
Acceptable Range
45 - 107
6?. - 110
58 - 135
43 - 130
36 - 111
58 - 131
H
Note H = Spiked analyte not detected because of required sample dilution.
ND = Not Detected
Reported By: Emily Uebelhoer
Approved By: Mike Orbanosky
The cover letter is an integral part of this report.
Rev 230787
-------
Semivolatiles Library Search (20 Compound TID)
Method 8270
Client Name:
Client ID:
LAB ID:
Matrix:
Authorized:
Pacific Environmental Services
S-MM5-3-F,FH,XAD,COND,BH
300681-0007-SA
AIRTRAIN Sampled:
30 JUL 98 Prepared:
27 JUL
NA
98
Dilution Factor: 100
Parameter Result Units
Undecane 10000 ug/Sample
Decane, 2,5,6-trimethyl- 12000 ug/Sample
Undecane,'2,6-dimethyl- 9900 ug/Sample
Unknown 11000 ug/Sample
Heptadecane, 2,6-dimethyl- 19000 ug/Sample
Unknown 13000 ug/Sample
Decane, 2,4-dimethyl 19000 ug/Sample
Unknown 9100 ug/Sample
Unknown alkane 22000 ug/Sample
Unknown alkane 36000 ug/Sample
Naphthalene, 1,3-dimethyl- 16000 ug/Sample
Heptadecane, 2,6,10,14 -tetramethyl- 26000 ug/Sample
Dodecane, 3-methyl- 35000 ug/Sample
Unknown alkane 11000 ug/Sample
Nonadecane 35000 ug/Sample
Nonadecane 22000 ug/Sample
Heptadecane, 2,6-dimethyl- 46000 ug/Sample
Unknown alkane 14000 ug/Sample
Nonadecane 17000 ug/Sample
Heptadecane, 2,6-dimethyl- 10000 ug/Sample
Received: 30 JUL 98
Analyzed: 31 AUG 98
Reporting
Limit
Qualifier
0
0
0
0
0
0
0
0
0
0
0
0
0
Note 0 = Or structurally similar compound (isomer).
NA = Not Applicable
Reported By: Emily Uebelhoer
Approved By: Mike Orbanosky
The cover letter is an integral part of this report.
Rev 230787
-------
OUANTERRA GC/MS
Target Compound Data Summary Sheet
Sample: S-MM5-3 1/3SA/100M INST. ID:
Client: PAC1F1
Analyst: DAT Instrument ID: F16
Quan List Threshold: 0.95
Data File: 30068107
Std Id: ST16980831
F16
Date Analyzed: 08/31/98 21:59
Run Factor: 300.
Surrogate Vol.: 100.
Surrogate Spike Recoveries
8270-G, LIMS 10/10/96
Surrogate
Surrogate Amount (ug)
Spiked Measured
CS20 NITROBENZENE-DS
CS25 2-FLUOROBIPHENY
CS30 TERPHENYL-D14
CS45 PHENOL-D5
CS50 2-FLUOROPHENOL
CS55 2,4,6-TRIBROMOP
50.0
50.00
50.00
100.
100.0
100.0
BDL
95.10
101.0
BDL
153.0
123.0
0*
190.
202.
0*
153.
123.
% Recovery
Measured QC limits
45 107
* 62 110
* 58 135
43 130
* 36 111
58 131
Target Compounds: SAP9
Parameter Scan Result Units
HEXACHLOR08ENZENE-C13
C310 N-NITROSOOIMETHYLAMINE
PYRIDINE
2-PICOLINE
N-NITROSOMETHYLETHYLAMINE
METHYLMETHANESULFONATE
N-NITROSODIETHYLAMINE
ETHYLMETHANE SULFONATE
PENTACHLOROETHANE
C320 ANILINE
C315 PHENOL
C325 BIS(2-CHLOROETHYL)ETHER
C330 2-CHLOROPHENOL
C335 1,3-DICHLOROBENZENE
C340 1,4-DICHLOROBENZENE
C345 BENZYL ALCOHOL
C350 1,2-DICHLOROBENZENE
C355 2-METHYLPHENOL
C360 2,2'-OXYBIS(1-CLPROPAN>
C361 ACETOPHENONE
N-NITROSOPYRROLIDINE
N-NITROSOMORPHOLINE
3-METHYL PHENOL
C365 4-METHYLPHENOL
C370 N-NITROSO-DI-N-PROPYLAM
0-TOLUIDINE
C375 HEXACHLOROETHANE
C410 NITROBENZENE
N-NITROSOPIPERIDINE
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
Reporting
Limit
3000.0
3000.0
6000.0
3000.0
3000.0
3000.0
3000.0
3000.0
3000.0
3000.0
3000.0
3000.0
3000.0
3000.0
3000.0
3000.0
3000.0
3000.0
3000.0
3000.0
3000.0
3000.0
3000.0
3000.0
3000.0
3000.0
3000.0
3000.0
I 3000.0
Reviewed by:
111!
-------
Sample: S-MM5-3
Client: PACIFI
Analyst: DAT
QUANTERRA GC/MS
Target Compound Data Summary Sheet
Data File: 30068107
Std Id: ST16980831
1/3SA/100M INST. ID: F16
Date Analyzed: 08/31/98 21:59
Instrument ID: F16 Run Factor: 300.
Quan List Threshold: 0.95
Surrogate Vol.:
100.
Target Compounds: SAP9
Parameter
C415 ISOPHORONE
C420 2-NITROPHENOL
C425 2,4-DIMEWLPHENOL
C435 B1S(2-CHLOROETHOXY)METH
C440 2,4-DICHLOROPHENOL
C430 BENZOIC ACID
AA-DJHETHYLPHENETHYLAMINE
C445 1,2,4-TRICHLOROBENZENE
C450 NAPHTHALENE
C455 4-CHLOROANALINE
2,6-DlCHLOROPHENOL
HEXACHLOROPROPENE
C460 HEXACHLOROBUTADIENE
P-PHENYLENE DIAMINE
N-NITROSOOI-N-BUTYLAMINE
C465 4-CHLORO-3-METHYLPHENO
SAFROLE
C470 2-METHYLNAPHTHALENE
1 , 2 , 4 , 5- TETRACHLOROBENZENE
ISOSAFROLE (#1)
C510 HEXACHLOROCYCLOPENTADI
C515 2,4,6-TRICHLOROPHENOL
C520 2,4,5-TRICHLOROPHENOL
1SOSAFROLE (#2)
C525 2-CHLORONAPHTHALENE
1-CHLORONAPHTHALENE
C530 2-NITROANALINE
1,4-NAPHTHOOUINONE
C535 DIMETHYLPHTHALATE
1,3-OINITROBENZENE
C540 ACENAPHTHYLENE
C543 2,6-OINITROTOLUENE
C545 3-NITROANILINE
C550 ACENAPHTHENE
C555 2,4-DINITROPHENOL
C565 DIBENZOFURAN
C560 4-NITROPHENOL
PENTACHLOROBENZENE
C570 2,4-DINITROTOLUENE
1-NAPHTHYLAMINE
2-NAPHTHYLAHINE
2,3,4.6- TETRACHLOROPHENOL
C580 DIETHYLPHTHALATE
C590 FLUORENE
533
652
tesut
ND
ND
ND
ND
ND
ND
ND
-JO-
3200
s"ซr
ND
ND
ND
ND
ND
ND
*#tr
6300
~^irP
No
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
t Units
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
-UG/A
.^X UG/A
s=r"^ UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
"x UG/A
_. ) UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
Reporting
Limit
3000.0
3000.0
3000.0
3000.0
3000.0
15000.0
3000.0
3000.0
3000.0
3000.0
3000.0
3000.0
3000.0
3000.0
3000.0
3000.0
3000.0
3000.0
3000.0
6000.0
3000.0
3000.0
3000.0
6000.0
3000.0
1500.0
15000.0
3000.0
3000.0
3000.0
3000.0
3000.0
15000.0
3000.0
15000.0
3000.0
15000.0
3000.0
3000.0
3000.0
3000.0
6000.0
3000.0
3000.0
-------
QUANTERRA GC/MS
Target Compound Data Summary Sheet
Data File: 30068107
Std Id: ST16980831
300.
100.
Sample: S-MM5-3 1/3SA/100M
Client: PACIFI
Analyst: DAT Instrument
Quan List Threshold: 0.95
INST. ID:
F16
Date Analyzed: 08/31,
ID: F16
Run Factor
Surrogate
Vol.:
Target Compounds: SAP9
Parameter Scan
C585 4-CHLOROPHENYL-PHENYLE
5-NITRO-O-TOLUIDINE
C595 4-NITROANALINE
C610 4.6-DINITRO-2-METHYLPH
C615 N-N1TROSOD1PHENYLAMJNE
C620 AZOBENZENE
SYM-TR1NITROBENZENE
C625 4-BROMOPHENYL-PHENYLET
PHENACETIN
D1ALLATE 234
C630 HEXACHLOR08ENZENE
4-AMINOBIPHENYL
C635 PENTACHLOROPHENOL
PRON AMIDE
PENTACHLORON I TROBENZENE
C640 PHENANTHRENE
C645 ANTHRACENE
2SECBUTYL-4.6-DINITROPHENOL
C647 CARBAZOLE
C650 DI-N-BUTYLPHTHALATE
4-N1TROOU1NOLINE-1 -OXIDE
METHAPYRILENE
ISOORIN
C655 FLUORANTHENE
CHLOROBENZILATE
C710 BENZIDINE
C715 PYRENE
ARAMITE (#1)
ARAMITE (#2)
P-DIMETHYUAHINOAZOBENZENE
3,3'-DlMETHYUBENZIDINE
-------
QUANTERRA GC/MS
Target Compound Data Summary Sheet
Data File: 30068107
Std Id: ST16980831
Sample: S-MM5-3
Client: PACIF1
Analyst: DAT
1/3SA/100M
INST. ID: F16
Instrument ID: F16
Date Analyzed: 08/31/98 21:59
Run Factor: 300.
Quan List Threshold: 0.95
Surrogate Vol.:
100.
Parameter
Target Compounds: SAP9
Scan Result Units
Reporting
Limit
C775 BENZO(A)PYRENE
C780 INDENO(1,2,3-CD)PYRENE
C785 DIBENZ(A,H)ANTHRACENE
C790 BENZO(G,H,I)PERYLENE
ND
ND
ND
ND
UG/A
UG/A
UG/A
UG/A
3000.0
3000.0
3000.0
3000.0
1114
-------
DATA FROM FILE: 30068107 SCANS 93 TO 1203 ACQUIRED: 08/31/98 21:59:00
CALI: 30068107 #3
SAMPLE: S-MM5-3 1/3SA/100M INST. ID: F16
CONDS.: UG/ML *100ML *100Z/100Z */l/3SA NA M
200 ->
2:13
400 .
4:27
600 .
6:40
800 .
8:54
1000 .
11:07
ffll J
I
I
I
I
100.02 < 395264.)
PS50 2-FLUOROPHENOL
112SS1# 02
CI30 1,4-DICHLOROBENZENE-D4 152IS1* 01
CI40 NAPHTHALENE-OS
136IS2* 01
CI60 PHENANTHRENE-D10
367-12-4
3855-82-1
1146-65-2
172SS3* 03
TC
321-60-8
164IS3* 01
188IS4* 01
15067-26-2
1517-22-2
CM
-------
DATA FROM FILE: 30068107 SCANS 1203 TO 2158 ACQUIRED: 08/31/98 21:59:00
CALI: 30068107 #3
SAMPLE: S-MM5-3 1/3SA/100M INST. ID: F16
CONDS.: UG/ML *100ML *100Z/"1007. *
-------
STANDARD USED FOR THIS REPORT IS ST16980831 REPORT PRINTED: 9/01/98 20:38:02
ADDITIONAL STANDARD USED FOR THIS REPORT IS: ST16980831A
OUANTERRA QUANT I TAT ION SUMMARY
File: 30068107
Sample: S-MH5-3 1/3SA/100M 1NST. ID: F16
Analyst: OAT Instrument Id: F16 Analyzed: 08/31/98 21:59
Compounds with amounts less than 0.20 reported as NOT FOUND
Library
No
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
Entry
S1# 1
S2# 1
S3# 1
S4# 1
S5# 1
S6# 1
S2# 2
S3# 3
S5# 2
S1# 3
S1# 2
S3# 2
S4# 4
S1# 15
S1# 20
S1# 30
S1# 40
S1# 60
S1# 70
S1# 85
S1# 95
S1#100
S1#105
S1#110
SU115
S1#125
S1#130
S1#145
S1#150
S1#160
S1#165
S1#170
S1#175
S1#180
S1#182
S1#185
S1#190
S1#195
S1#200
S2# 10
S2# 15
S2# 20
S2# 25
S2# 30
S2# 35
Name Mass
CI30 1,4-DICHLOROBENZENE
CI40 NAPHTHALENE-D8
CI50 ACENAPHTHENE-D10
CI60 PHENANTHRENE-D10
CI70 CHRYSENE-D12
CI75 PERYLENE-D12
CS20 NITROBENZENE-05
CS25 2-FLUOROBIPHENYL
CS30 TERPHENYL-D14
CS45 PHENOL -D5
CS50 2-FLUOROPHENOL
CS55 2,4,6-TRIBROMOPHENO
HEXACHLOROBENZENE-C13
C310 N-NITROSODIMETHYLAM
PYRIDINE
2-PICOLINE
N-NITROSOMETHYLETHYLAMIN
METHYLMFTHANESULFONATE
N-NITROSODIETHYLAMINE
ETHYLMETHANE SULFONATE
PENTACHLOROETHANE
C320 ANILINE
C315 PHENOL
C325 BIS(2-CHLOROETHYL)E
C330 2-CHLOROPHENOL
C335 1,3-DICHLOROBENZENE
C340 1,4-DICHLOROBENZENE
C345 BENZYL ALCOHOL
C350 1,2-DICHLOROBENZENE
C355 2-METHYLPHENOL
C360 2,2'-OXYBIS(1-CLPRO
C361 ACETOPHENONE
N-NITROSOPYRROLIDINE
N-NITROSOMORPHOL1NE
3-METHYL PHENOL
C365 4-METHYLPHENOL
C370 N-N1TROSO-DI-N-PROP
0-TOLUIDINE
C375 HEXACHLOROETHANE
C410 NITROBENZENE
N-NITROSOPIPERIOINE
C415 ISOPHORONE
C420 2-NITROPHENOL
C425 2,4-DlMETHYLPHENOL
C435 BIS(2-CHLOROETHOXY)
152
136
164
188
240
264
82
172
244
99
112
330
294
74
79
93
42
80
102
79
117
93
94
93
128
146
146
108
146
108
45
105
100
56
108
108
70
106
117
77
42
82
139
107
93
Meth
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
BB
BB
BB
BB
BB
BV
BB
BB
VV
BB
BB
BB
BB
BB
BB
BB
VB
BB
BB
Scan Ref Area
340 1
530 2
829 3
1088 4
1552 5
1782 6
2 NOT
723 3
1384 5
1 NOT
205 1
971 3
4 NOT
1 NOT
1 NOT
1 NOT
1 NOT
1 NOT
1 NOT
1 NOT
305 1
1 NOT
1 NOT
1 NOT
1 NOT
1 NOT
1 NOT
1 NOT
1 NOT
392 1
394 1
400 1
1 NOT
1 NOT
418 1
418 1
1 NOT
1 NOT
1 NOT
422 2
449 2
2 NOT
2 NOT
500 2
2 NOT
30514.
110082.
60039.
106261.
67833.
51078.
FOUND
1762.
1708.
FOUND
1595.
436.
FOUND
FOUND
FOUND
FOUND
FOUND
FOUND
FOUND
FOUND
157.
FOUND
FOUND
FOUND
FOUND
FOUND
FOUND
FOUND
FOUND
2412.
3276.
8775.
FOUND
FOUND
2022.
2003.
FOUND
FOUND
FOUND
2364.
1186.
FOUND
FOUND
3534.
FOUND
Units: UG/h
RRF(L) Amount
1
1
.000
.000
1.000
1
1
1
1
0
1
0
0
1
2
1
2
1
0
0
0
.000
.000
.000
.234
.995
.368
.236
.602
.175
.539
.934
.252
.276
.445
.320
.330
40
40
40
40
40
40
0
1
1
1
0
.000
.000
.000
.000
.000
.000
.951
.012
.528
.233
.343
2.692
1
5
1
2
1
1
3
.691
.948
.177
.059
.930
.345
.893
111
-------
46 S2# 40 C440 2,4-DlCHLOROPHENOL 162 A BB 519 2 256. 0.308 0.302
47 S2# 45 C430 BENZOIC ACID 122 A BB 548 2 438. 0.276 0.577
48 S2# 50 AA-DIMETHYLPHENETHYLAM1N 58 2 NOT FOUND
49 S2# 55 C445 1,2,4-TRICHLOROBENZ 180 A*B8 523 2 252. 0.331 0.277
111E
-------
50 S2# 60 C450 NAPHTHALENE
51 S2# 80 C455 4-CHLOROANALINE
52 S2# 85 2,6-DICHLOROPHENOL
53 S2# 90 HEXACHLOROPROPENE
54 S2# 95 C460 HEXACHLOROBUTAD1ENE
55 S2#115 P-PHENYLENE DIAMINE
56 S2#120 N-NITROSODI-N-BUTYLAMINE
57 S2#130 C465 4-CHUORO-3-METHYLPH
58 S2#140 SAFROLE
59 S2#145 C470 2-METHYLNAPHTHALENE
60 S3# 10 1,2,4,5-TETRACHLOROBENZE
61 S3# 15 ISOSAFROLE (#1)
62 S3# 20 C510 HEXACHLOROCYCLOPENT
63 S3# 25 C515 2,4,6-TRlCHLOROPHEN
64 S3# 30 C520 2,4,5-TRICHLOROPHEN
65 S3# 35 ISOSAFROLE (#2)
66 S3# 40 C525 2-CHLORONAPHTHALENE
67 S3# 42 1-CHLORONAPHTHALEN
68 S3# 45 C530 2-NITROANALINE
69 S3# 50 1,4-NAPHTHOQUINONE
70 S3# 55 C535 D1METHYLPHTHALATE
71 S3# 60 1,3-DINITROBENZENE
72 S3# 65 C540 ACENAPHTHYLENE
73 S3# 70 C543 2,6-DINITROTOLUENE
74 S3# 75 C545 3-NITROANILINE
75 S3# 80 C550 ACENAPHTHENE
76 S3* 85 C555 2,4-DINITROPHENOL
77 S3* 90 C565 D1BENZOFURAN
78 S3# 95 C560 4-NITROPHENOL
79 S3#100 PENTACHLOROBENZENE
80 S3#105 C570 2,4-DINITROTOLUENE
81 S3#110 1-NAPHTHYLAMINE
82 S3#115 2-NAPHTHYLAMINE
83 53*120 2,3,4,6-TETRACHLOROPHENO
84 53*130 C580 DIETHYLPHTHALATE
85 53*135 C590 FLUORENE
86 53*140 C585 4-CHLOROPHENYL-PHEN
87 53*145 5-NITRO-O-TOLUIDINE
88 53*150 C595 4-NITROANALINE
89 54* 10 C610 4.6-DINITRO-2-METHY
90 54* 15 C615 N-N1TROSODIPHENYLAM
91 S4* 20 C620 AZOBENZENE
92 S4* 25 SYM-TR1NITROBENZENE
93 S4* 30 C625 4-BROMOPHENYL-PHENY
94 S4# 35 PHENACETIN
95 S4# 37 D1ALLATE
96 S4* 40 C630 HEXACHLOROBENZENE
97 S4* 45 4-AMINOBIPHENYL
98 S4# 50 C635 PENTACHLOROPHENOL
99 S4# 55 PRONAM1DE
100 54* 60 PENTACHLORONITROBENZENE
101 S4# 65 C640 PHENANTHRENE
102 54* 70 C645 ANTHRACENE
103 S4# 75 2SECBUTYL-4.6-DIN1TROPHE
104 S4* 80 C647 CARBAZOLE
105 S4* 85 C650 DI-N-BUTYLPHTHALATE
106 54*100 4-NITROQUINOLINE-1-OXIDE
107 S4#105 METHAPYR1LENE
108 54*106 ISODRIN
109 S4*110 C655 FlUORANTHENE
110 S4#120 CHLOROBENZILATE
128
127
162
213
225
108
84
107
162
142
214
162
237
196
196
104
162
162
65
158
163
168
152
165
138
153
184
168
109
250
165
143
143
232
149
166
204
152
138
198
169
77
75
248
108
234
284
169
266
173
237
178
178
211
167
149
190
58
193
202
139
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
BV
BB
BB
BB
BV
BB
BB
BB
BB
BV
BB
BB
VB
BV
BB
BB
BB
VB
VB
VV
BB
BB
BB
533 2
556 2
2 NOT
2 NOT
2 NOT
2 NOT
2 NOT
2 NOT
648 2
652 2
3 NOT
697 3
3 NOT
3 NOT
3 NOT
746 3
3 NOT
3 NOT
764 3
3 NOT
3 NOT
807 3
3 NOT
817 3
3 NOT
834 3
858 3
867 3
3 NOT
3 NOT
881 3
882 3
902 3
3 NOT
3 NOT
926 3
3 NOT
942 3
949 3
4 NOT
964 4
966 4
4 NOT
4 NOT
4 NOT
4 NOT
4 NOT
4 NOT
4 NOT
4 NOT
1062 4
1091 4
4 NOT
4 NOT
1148 4
4 NOT
4 NOT
4 NOT
4 NOT
4 NOT
4 NOT
29645.
677.
FOUND
FOUND
FOUND
FOUND
FOUND
FOUND
1458.
43357.
FOUND
592.
FOUND
FOUND
FOUND
1306.
FOUND
FOUND
838.
FOUND
FOUND
340.
FOUND
429.
FOUND
1539.
129.
1304.
FOUND
FOUND
770.
547.
425.
FOUND
FOUND
4384.
FOUND
4181.
213.
FOUND
5183.
1221.
FOUND
FOUND
FOUND
FOUND
FOUND
FOUND
FOUND
FOUND
250.
13289.
FOUND
FOUND
571.
FOUND
FOUND
FOUND
FOUND
FOUND
FOUND
1
0
0
0
0
0
0
0
0
1
0
1
0
0
0
1
0
0
0
1
0
1
0
.022
.454
.248
.751
.044
.195
.502
.197
.324
.159
.189
.669
.397
.837
.966
.298
.356
.307
.551
.171
.080
.033
.764
10
0
2
20
9
4
1
1
0
0
0
0
1
0
0
2
7
0
3
0
1
4
.538
.542
.140
.970
.033
.467
.112
.148
.883
.885
.456
.521
.291
.435
.293
.251
.835
.463
.543
.392
.171
.845
0.281
1 1 1 C
J. JL _^ 0
-------
111 S5# 10 C710 BENZIDINE 184 5 NOT FOUND
112 S5# 15 C715 PYRENE 202 A BB 1335 5 1633. 1.323 0.728
113 S5# 20 ARAMITE (#1) 185 5 NOT FOUND
1U S5# 25 ARAMITE (#2) 185 5 NOT FOUND
115 S5# 30 P-D1METHYLAMINOAZOBENZEN 120 5 NOT FOUND
116 S5# 35 3,3'-DIMETHYLBENZIDINE 212 5 NOT FOUND
117 S5# 37 KEPONE 272 A BV H60 5 234. 0.082 1.684
118 S5# 40 C720 BUTYLBENZYLPHTHALAT 149 5 NOT FOUND
119 S5# 45 2-ACETYLAMINOFLUORENE 181 5 NOT FOUND
120 S5# 50 C730 BENZO(A)ANTHRACENE 228 5 NOT FOUND
121 S5# 55 C725 3,3'-DICHLOROflENZID 252 5 NOT FOUND
122 S5# 60 C740 CHRYSENE 228 A BB 1555 5 916. 1.014 0.533
123 S5# 65 C745 B1S(2-ETHYLHEXYL)PH 149 5 NOT FOUND
124 S5# 85 3-METHYLCHOLANTHRENE 268 5 NOT FOUND
125 S6# 10 C760 DI-N-OCTYL PHTHALAT 149 6 NOT FOUND
126 S6# 15 C765 BENZO(B)FLUORANTHEN 252 6 NOT FOUND
127 S6# 20 7,12-DIMETHYLBENZANTHRAC 256 A BB 1741 6 218. 0.610 0.280
128 S6# 25 C770 BENZO(K)FLUORANTHEN 252 6 NOT FOUND
129 S6# 30 HEXACHLOROPHENE 196 6 NOT FOUND
130 S6# 35 C775 BENZO(A)PYRENE 252 6 NOT FOUND
131 S6# 55 C780 INDENO(1,2,3-CD)PYR 276 6 NOT FOUND
132 S6# 60 C785 DIBENZ(A,H)ANTHRACE 278 6 NOT FOUND
133 S6# 65 C790 BENZO(G.H,I)PERYLEN 276 6 NOT FOUND
1120
-------
SNA, S LIBRARIES ANALYST: DATE:
QUANTERRA Internal Standard Check
Standard Filename: ST16980831 Analyzed: 08/31/98 12:31
I IS# 1 | 1S# 2 | IS# 3 |
Standard | Area % | RT | Area % | RT | Area X | RT j
ST16980831 | 28649. | 3.78 | 100432. | 5.90 | 54347. | 9.21 |
Upper Limit | 57297.=+200| 4.28 j 200864.=+200j 6.40 j 108695.=+200| 9.71 j
Lower Limit | 14324.=+ 50| 3.28 | 50216.=+ 50| 5.40 | 27174.=+ 50| 8.71 j
F iIename | | | | | (I
1 30068107 | 30514.= 106J 3.78 | 110082.= 109J 5.90 | 60039.= 110| 9.22
IS# 1 = CI30 1,4-DICHLOROBENZENE-D4
IS# 2 = CI40 NAPHTHALENE-OS
IS# 3 = CI50 ACENAPHTHENE-D10
* - indicates an I.S. is outside QC limit(s)
| IS# 4 | IS* 5 | IS# 6 |
Standard j Area % | RT | Area % | RT j Area % | RT |
ST16980831 | 98520. |12.08 | 62289. |17.26 | 50750. |19.83 |
Upper Limit j 1 97039. =+200 j 12. 58 j 124578. =+200|17. 76 | 1 01 500. =+200 j 20. 33 j
Lower Limit j 49260.=+ 50J11.58 j 31145.=+ 50J16.76 | 25375.=+ 50(19.33 j
Filename | | | | |
1 30068107 | 106261.= 107(12.10 | 67833.= 108|17.26 | 51078.= 100|19.82
IS# 4 = CI60 PHENANTHRENE-D10
1S# 5 = CI70 CHRYSENE-D12
IS# 6 = CITS PERYLENE-D12
* - indicates an I.S. is outside QC limit(s)
-------
TARGET COMPOUND COMPARISON
COMPOUND: C450 NAPHTHALENE
128 52* 60
RAM DATA: 30988107 #533
08x31x98 21:59
SAMPLE: S-MM5-3 1/3SA/100M INST. ID: F16
CONDS.: UG/ML *100ML *1007Z/1007> */l/3SA NA M
91-20-3
BASE M/Z: 128
RIC: 88448.
11.
5.
9.
4.
100.
50.
M/Z
100.
50.
0.
-50.
100.
4-
7-.
B-.
0-
0-:
0-
*~
0-:
0-i
0-
.1.1.1 .u
ll liJlliLiulii,
llii.....l...ln,..il..i...!i, .. i...i...i..il
i r"' r "*" i i i i i i i i
ENHANCED DATA: 30068 I 07 #533
.,! ,l
i ' i ' J i i i
STANDARD FILE:
08/31/98 12:31
i ' i ' | " '
50
.1 i
M
..ii ...
i ' i ' i
. .. . 1.. ii. . il
i , i i i | i | i
ST 16980831 #533
1 ' 1 ' i i ' i i i ' i < i i | i i "-1
BASE M/Z: 128 RIC: 25600.
1 i i i 1 i - i i i i i i > i -j~ ป r-i-
BASE M/Z: 128 RICs 195840.
1 I 1 1 | 1 | ' i [ . | | , | | , i i | i | i | i | . . T -p.. i 1 i
100 150 200 250
1
9072.
7768.
r 79232.
-------
TARGET COMPOUND COMPARISON
COMPOUND! C470 2-METHYLNAPHTHALENE
142 S2#145
RAN DATA: 30068107 #652
08/31/98 21:59
SAMPLE: S-MM5-3 1/3SA/100M INST. ID: F16
CONDS.: UG/ML *100ML *100Z/100Z */l/3SA NA M
91-57-6
BASE M/Z: 142
RIC: 144896.
29.5-
14.7-
26.4-q
13. 2-:
100.0-
50.0-:
M/Z
100.0-
50.0-;
0.0-:
-50.0-i
100.0-3
,1,
i
i
.1.1. Illi. ..i.i.l,
II ... .1.1.1 III.. .. i 1 .. . ll 1. 1 .. , ll 1.
ENHANCED DATA: 30068107 #652
.,,.,, .',
. . .1 4-. .ll _
I
STANDARD FILE: ST16980831 #651
08/31/98 12:31
40
.1 1 .1 ,
1 ' ' 1 ' '
50 60
. ,. 1
111 1
80 100
1 1" I
,
BASE M/Z:
BASE M/Z:
I
142 RIC: 49600.
^~
.. i ,...., i ...,,,., 4 ....,.,.
142 RIC: 198144.
120 140 150 160 180
, .. . i ,..,.... .
r 14688.
r 13136.
r 49792.
-------
Data Reduced by: ~ Date:
Data Reviewed by: _ Date:
Data File: 30068107
QUANTERRA GC/MS TIC REPORT ( Part 1 )
Sample: S-MM5-3 1/3SA/100M INST. ID: F16
Analyst: DAT Date Analyzed: 08/31/98 21:59
Run Factor: 300.
Concentration
in Sample
# SCAN (UG/A) CAS #
1 444 10000. 1120-21-4
UNDECANE Of
2 556 12000. 62108-23-0
DECANE, 2,5,6-TRIMETHYL-
3 569 9900. 17301-23-4
UNDECANE, 2,6-DIMETHYL-
4 616 11000.
UNKNOWN
00-00-0
1 7500. 2809-64-5
NAPHTHALENE, 1,2,3,4-TETRAHYDRO-5-METHYL-
6 632 19000. 54105-67-8
HEPTADECANE, 2,6-DIMETHYL- O V
7 653
13000.
8 663 19000.
DECANE, 2,4-DIMETHYL-
2801-84-5
^678 8100. 00-00-0 5"^
UNKNOWN
10 700 9100. 00-00-0
UNKNOWN
-Co
i
1 "' r- A
-L JL^'i
-------
ii 'jo d'T*TMrnrr^> /i 0 I/ r-i_H-^G_ C-/^ V_,A (ซ M C
12 764 36000.
___^629 J9 4
\ /
13 776 16000. 575-41-7
NAPHTHALENE, 1 ,3-DIMETHYL- Of f^CJV* tV
14 820 26000. 18344-37-1 ^
HEPTADECANE, 2,6, 10, 14-TETRAMETHYL- ฐ> iSCTV-C^r'
15 859 35000.
DOOECANE, 3-METHYL- C
17 948 35000.
NONADECANE. _ ,
18 988 22000.
NONADECANE
19 1036 46000.
HEPTADECANE, 2,6-DIMETHYL
17312-57-1
s^'/ai 4i 4 "^^ I \V\C^
-
629-92-5
629-92-5
54105-67-8
-I/
^SU054 7400. C
" "CJ(ADC(:CI1C' (^
"34303 -8TTT r\-")jO^ฐ^
cJLti^^xc- ^
21 1114 14000. ^
OLA^JA'
22 1119 17000.
NONADECANE
629-92-5
-------
1191 9000. 629-92-5
NONADECANE ฃ> v
24 1335 10000. 54105-67-8
HEPTADECANE, 2,6-DIMETHYL-
U02 8000. 629-92-5
ONADECANE
1 'ซ
J. J
-------
DATA FILE: 30068107
QUANTERRA GC/MS TIC REPORT ( Part 2 )
CONCENTRATION = AREA(TIC)*CONC(IS)/AREA(IS)
#
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
FIT
990
945
979
819
898
945
869
966
884
824
975
951
958
980
960
923
948
945
976
914
962
964
938
890
953
PURITY
746
884
888
392
644
794
653
848
466
399
822
723
638
837
803
647
843
832
875
722
804
839
769
720
662
INT.
STD.
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
3
3
3
3
3
3
4
4
AMOUNT
AS ANALYZED
RT
4:56
6:11
6:19
6:51
6:54
7:01
7:15
7:22
7:32
7:47
8:12
8:29
8:37
9:07
9:33
10:03
10:32
10:59
11:31
11:43
12:23
12:26
13:14
14:50
15:35
RRT
0.536
0.671
0.686
0.743
0.749
0.762
0.788
0.800
0.818
0.844
0.890
0.922
0.936
0.989
1.036
1.090
1.144
0.908
0.952
0.969
1.024
1.028
1.095
0.860
0.903
AREA
283914.
328256.
277376.
312896.
210688.
538176.
364315.
544896.
227072.
256768.
620928.
1009280.
451456.
738048.
993536.
323072.
969600.
712448.
1498370.
243136.
445568.
572544.
294144.
194624.
154880.
HEIGHT
85573.
110848.
87296.
46976.
47232.
133888.
73034.
138240.
58419.
30080.
165376.
270848.
64768.
155392.
249088.
72192.
241408.
182016.
258304.
57504.
136192.
170240.
98688.
47580.
34688.
(UG/ML )
33
38
32
37
24
63
43
64
26
30
73
119
53
87
117
38
115
72
151
24
45
58
29
33
26
.684
.945
.908
.122
.996
.850
.223
.647
.940
.463
.667
.742
.561
.563
.874
.330
.034
.262
.977
.661
.193
.072
.834
.353
.542
LIB
NB
NB
NB
UK
NB
NB
NB
NB
UK
UK
NB
NB
NB
NB
NB
NB
NB
NB
NB
NB
NB
NB
NB
NB
NB
LIB #
11607.
19015.
19054.
1.
8945.
37462.
22336.
15356.
1.
1.
25991.
22530.
11625.
42196.
19007.
40233.
37465 .
37465 .
37462.
28768.
15969.
37465 .
37465 .
37462.
37465 .
11
-------
Library Search Data: 30068107 # 444 Base m/z: 43
08/31/98 21:59:00 + 4:56 Cali: 30068107 # 3 RIC: 68608.
Sample: S-MM5-3 1/3SA/100M INST. ID: F16
Conds.: UG/ML *100ML *100X/100% *(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
736 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 11607 UNDECANE
2 19015 DECANE, 2,5,6-TRIMETHYL-
3 8104 OCTANE. 3,5-DIMETHYL-
4 11602 OCTANE, 2,4,6-TRIMETHYL-
5 19016 UNDECANE, 4,7-OIMETHYL-
6 22530 TETRADECANE
7 14793 1-UNDECENE, 4-METHYL-
8 19013 DECANE, 2,5,9-TRIMETHYL-
9 5151 HEPTANE, 3,4-DIMETHYL-
Rank
1
2
3
4
5
6
7
8
9
Rank
1
2
3
4
5
6
7
8
9
Formula
C11.H24
C13.H28
C10.H22
C11.H24
C13.H28
C14.H30
C12.H24
C13.H28
C9.H20
Ret. Time B.P.lnt.
M.Wt
156
184
142
156
184
198
168
184
128
US. Par. 1
B.Pk
43
57
57
57
43
43
43
57
43
US. Par.
Purity Fit
746 990
721 933
712 938
708 958
704 942
702 913
699 921
697 924
695 915
2 C.A.S. #
1120-21-4
62108-23-0
15869-93-9
62016-37-9
17301-32-5
629-59-4
74630-39-0
62108-22-9
922-28-1
RFit
749
723
718
708
710
755
735
697
697
-------
MID LIBRARY SEARCH
08/31/98 21:59:80 + 4:56
SAMPLE: S-MM5-3 1/3SA/100M INST. ID: F16
CONDS.: UG/ML *100ML *100Z/100Z *
DATA: 30068187 # 444
CALI: 30068107 # 3
BASE M/Z: 43
RIC: 68608.
1094 -
SAMPLE
C11.H24
1094 I
M WT 156
B PK 43
RANK 1
# 11607
PUR 746
C13.H28
1094 i
M WT 184
B PK 57
RANK 2
# 19015
PUR 721
C10.H22
1094 i
M WT 142
B PK 57
RANK 3
* 8104
PUR 712
M/Z
r
1
1
.11
. i . / . ., ... . .. 1
UNDECANE' o< ^cr^^
r
1
1
1
1 . . . . . i .
DECANE, 2,5,6-TRIMETHYL-
r
i
L
ill II ii . ..
OCTANE , 3,5-DIMETHYL-
r
1
1
ll
L. iJ J I
40 60 80 100 120 140 160
r.n
CO
-------
Library Search Data: 30068107 # 556 Base m/z: 43
08/31/9821:59:00+ 6:11 Cali: 30068107 # 3 R1C: 96896.
Sample: S-MM5-3 1/3SA/100H INST. ID: F16
Conds.: UG/ML *100ML *100%/100X *(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
206 matched at least 8 of the 16 largest peaks in the unknown
Rank In. Name
1 19015 DECANE. 2,5.6-TRIMETHYL-
2 11602 OCTANE, 2,4.6-TRIMETHYL-
3 19016 UNDECANE, 4.7-DIMETHYL-
4 8104 OCTANE, 3,5-DIMETHYL-
5 8089 NONANE, 2-METHYL-
6 5151 HEPTANE, 3.4-DIMETHYL-
7 19013 DECANE, 2,5,9-TRIHETHYL-
8 15353 2,6-DlMETHYLDECANE
9 8074 OCTANE, 2,7-DIMETHYL-
M.Wt B.Pk Purity Fit RFit
Rank Formula
1
2
3
4
5
6
7
8
9
C13.H28
C11.H24
C13.H28
C10.H22
C10.H22
C9.H20
C13.H28
C12.H26
C10.H22
184
156
184
142
142
128
184
170
142
57
57
43
57
43
43
57
43
43
884
870 /
868 \
858
853
845
840
837
836
/9$5^
971
.952y
934
951
923
926
893
923
885
| 870
874
866
856
848
850
878
836
Rank
1
2
3
A
5
6
7
&
9
Ret.Time
B.P.Int.
US.Par.1
US.Par.2
C.A.S. #
62108-23-0
62016-37-9
17301-32-5
15869-93-9
871-83-0
922-28-1
62108-22-9
13150-81-7
1072-16-8
II
-------
1139
SAMPLE
MID LIBRARY SEARCH
-------
Library Search Data: 30068107 # 569 Base m/z: 57
08/31/9821:59:00+ 6:20 Cali: 30068107 # 3 RIC: 76800.
Sample: S-MM5-3 1/3SA/100M INST. ID: F16
Conds.: UG/ML *100ML *100%/100% *(NA/NA )/1/3SA NA M
Enhanced (S 158 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
860 matched at least 7 of the 16 largest peaks in the unknown
Rank In-. Name
1 19054 UNOECANE, 2,6-DIMETHYL-
2 19052 UNOECANE, 2,5-DIMETHYL-
3 19013 DECANE, 2,5,9-TRIMETHYL-
4 19002 DOOECANE, 6-METHYL-
5 19026 DECANE, 2,6,8-TRIMETHYL-
6 8104 OCTANE, 3,5-DIMETHYL-
7 18996 UNDECANE, 3,6-DIMETHYL-
8 19004 UNDECANE, 4,6-DIMETHYL-
9 8099 OCTANE, 2,6-DIMETHYL-
Rank
1
2
3
4
5
6
7
8
9
Formula
C13.H28
C13.H28
C13.H28
C13.H28
C13.H28
C10.H22
C13.H28
C13.H28
C10.H22
M.Ut
184
184
184
184
184
142
184
184
142
B.Pk
57
57
57
57
57
57
57
57
57
Purity
888
859
856
854
850
842
831
824
823
Fit
979
975
975
972
968
960
967
959
946
RFit
888
862
856
857
855
842
834
824
829
Rank
1
2
3
A
5
6
7
8
9
Ret.Time
B.P.Int.
US.Par.1
US.Par.2
C.A.S
17301
17301
62108
6044
62108
15869
17301
17312
2051
, #
23-4
22-3
22-9
71-9
26-3
93-9
28-9
82-2
30-1
II
-------
MID LIBRARY SEARCH (LIBRARYNB)
08/31/98 21:59:00 +6:20
SAMPLE: S-MM5-3 1/3SA/100M INST. ID: F16
CONDS.: UG/ML *100ML *100Z/100Z */l/3SA NA M
ENHANCED ^
0* v*^
UNDECANE , 2 , 5-D I METHYL-
il
.1 , , .1 1.
DECANE, 2,5,9-TRIMETHYL-
i
i iL i d -
M/Z 40 60 80 100 120 140 160 180 200
t
CO
cv->
-------
Library Search Data: 30068107 # 616
08/31/9821:59:00+ 6:51 Call: 30068107 # 3
Sample: S-MW5-3 1/3SA/100M 1NST. ID: F16
Conds.: UG/ML *100ML *100%/100X *(NA/NA )/V3SA NA M
Enhanced (S 15B 2N OT)
Base m/z: 131
RIC: 35968.
62231 spectra m LIBRARYNB searched for maximum PURITY
789 matched at least 5 of the 16 largest peaks in the unknown
Rank In. Name
1 8953 7-ETHYLlDENEBICYCLO[4.2.1]NONA-2,4-DlENE
2 24994 1,1'-B1CYCLOHEXYL, 2-(1-METHYLETHYL)-, TRANS-
3 8915 PROPANEDINITRILE, CYCLOHEXYL1DENE-
4 24993 1,1'-BICYCLOHEXYL. 2-(1-METHYLETHYL)-, CIS-
5 47544 BENZENE, 1,1' - [3-(3-CYCLOPENTYLPROPYL)-1,5-PENTANEDIYUBIS-
6 8902 7,7-NORCARANEDICARBONITRILE, CIS-
7 33979 BORINIC ACID, DIETHYL-, 1-CYCLODODECEN-1-YL ESTER
8 24997 1,1'-BICYCLOHEXYL, 2-PROPYL-, TRANS-
9 16369 BENZENE, (3.3-D1METHYL-4-PENTENYL)-
M.Wt B.Pk Purity Fit RFit
Rank
1
2
3
4
5
6
7
8
9
Formula
C11.H14
C15.H28
C9.H10.N2
C15.H28
C25.H34
C9.H10.N2
C16.H31.0.B
C15.H28
C13.H18
146
208
146
208
334
146
250
208
174
91
83
55
83
92
55
83
41
104
392
351
341
339
339
335
327
313
312
819
876
733
863
584
722
845
765
647
456
365
395
356
364
388
365
332
334
Rank
1
2
3
4
5
6
7
8
9
Ret.Time
B.P.Int.
US.Par.1
US.Par.2
C.A.S. #
94400-10-9
50991-16-7
4354-73-8
50991-15-6
55191-62-3
29782-28-3
61142-73-2
54934-89-3
61142-18-5
11
-------
MID LIBRARY SEARCH
88/31/98 21:59:00 + 6:51
SAMPLE: S-MM5-3 1/3SA/100M INST. ID: F16
CONDS.: UG/ML *100ML *100Z/1002 *
DATA: 30068107 #616
CALI: 30068107 # 3
BASE M/Z: 131
RIC: 35968.
1625
SAMPLE
ป *-y*i i * -|fc
7-ETHYLIDENEBICYCLO C 4.2.1]NONA-2,4-DIENE
B
C11.H14
1625
WT 146
PK 91
RANK 1
# 8953
PUR 392
C15.H28
1625
M WT 208
B PK 83
RANK 2
# 24994
PUR 351
C9.H10.N2
1625 -
M WT 146
B PK 55
RANK 3
# 8915 :
PUR 341
M/Z
1 , 1 ' -B I CYCLOHEXYL , 2- < 1 -METHYLETHYL ) - , TRANS-
PROPANED I N I TR I LE , CYCLOHEXYL I DENE-
I II ill il h I
50
100
150
200
250
300
350
400
CO
cn
-------
Library Search Data: 30068107 # 621
08/31/98 21:59:00 + 6:54 Cati: 30068107 # 3
Sample: S-MM5-3 1/3SA/100M INST. ID: F16
Conds.: UG/ML *100ML *100%/100% *(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
Base m/z: 118
RIC: 31552.
62231 spectra in LIBRARYNB searched for maximum PURITY
740 matched at least 5 of the 16 largest peaks in the unknown
Rank In. Name
1 8945 NAPHTHALENE. 1,2,3,4-TETRAHYDRO-5-METHYL-
2 8960 NAPHTHALENE, 1,2,3,4-TETRAHYDRO-6-METHYL-
3 8953 7-ETHYLIDENEBICYCLu[4.2.1]NONA-2,4-DIENE
4 8929 NAPHTH[1,2-B]OX1RENE, 1A,2,3,7B-TETRAHYDRO-
5 8938 NAPHTHALENE, 1,2,3,4-TETRAHYDRO-1-METHYL-
6 8944 BENZENE, (1-METHYLENEBUTYL)-
7 8932 H2H)-NAPHTHALENONE, 3,4-DIHYDRO-
8 8973 BENZENE, 2-ETHENYL-1,3,5-TRlMETHYL-
9 32808 BENZENE, (1-PROPYL-1-NONENYL)-
Rank Formula
2
3
i>
5
6
7
8
9
C11.H14
C11.H14^.
C10.H10.0
C11.H14
C11.H14
C10.H10.0
C11.H14
C18.H28
M.Wt
146
146
146
146
146
146
146
146
244
B.Pk
131
131
91
146
131
118
118
131
118
Purity
644
602
516
504
502
499
489
488
484
Fit
898
947
833
799
861
846
767
871
696
RFit
650
609
535
580
516
520
547
492
605
Rank
1
2
3
U
5
6
7
8
9
Ret.Time
B.P.Int.
US.Par.1
US.Par.2
C.A.S
2809
1680
94400
2461
1559
5676
529
769
54986
. #
64-5
51-9
10-9
34-9
81-5
32-4
34-0
25-5
39-9
126
-------
MID LIBRARY SEARCH (LIBRARYNB)
08/31/98 21:59:08 + 6:54
SAMPLE: S-MM5-3 1/3SA/100M INST. ID: F16
CONDS.: UG/ML *100ML *100Z/100Z *
DATA: 30068107 # 621
CALI: 30068107 # 3
BASE M/Z: 118
RIC: 31552.
1451 i
SAMPLE
C11.H14
1451 -I
M WT 146
B PK 131
RANK 1
# 8945
PUR 644
C11.H14
1451 1
M WT 146
B PK 131
RANK 2
* 8960
PUR 602
C11.H14
1451 i
M WT 146
B PK 91
RANK 3
# 8953
PUR 516
M/Z
r
r
r
u
r
1
,
'i i1
r-r
LL
III 1 i 1,
A
1
.
j L
r-vrf^-""
KVฐ
1
1 , 1
1
,11
NAPHTHALENE, l,2,3,4-TETRAHYDRO-5-METHYL- ฃ>< <\O\A-
ii h 1
NAPHTHALENE , 1,2,3, 4-TETRAHYDRO-6-METHYL-
i
III i
II,
.1. .1, .'1
1 1
-t/
1
1.
II
1
1
7-ETHYLIDENEBICYCLOC4.2.1]NONA-2,4-DIENE
40
1 II 1
60
88
100
ll
1
1
126 140 160 180
CO
-------
Base m/z: 57
RIC: 116992.
Library Search Data: 30068107 # 632
08/31/98 21:59:00 + 7:02 Cali: 30068107 # 3
Sample: S-MM5-3 1/3SA/100M 1NST. ID: F16
Conds.: UG/ML *100ML *100%/100% *(NA/NA 5/1/3SA NA M
Enhanced (S 15B 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
323 matched at least 8 of the 16 largest peaks in the unknown
Rank In. Name
1 37462 HEPTADECANE, 2,6-DIMETHYL-
2 22534 TR1DECANE, 7-HETHYL-
3 14799 1-DECENE, 3,4-DIMETHYL-
4 42196 HEPTADECANE, 2,6, 10, 14-TETRAMETHYL-
5 22535 DOOECANE, 4,6-DIMETHYL-
6 15353 2,6-DIMETHYLDECANE
7 19023 DECANE, 2,6,7-TRIMETHYL-
8 19523 1-OECANOL, 2-ETHYL-
9 25994 DODECANE, 2,6,11-TRIMETHYL-
Rank
1
2
3
4
5
6
7
8
9
Formula
C19.H40
C14.H30
C12.H24
C21.H44
C14.H30
C12.H26
C13.H28
C12.H26.0
C15.H32
M.Ut B,
268
198
168
296
198
170
184
186
212
.Pk
57
57
57
57
57
43
57
57
57
Purity
794
787
769
766
763
762
762
760
758
Fit
945
937
948
928
945
927
969
935
956
RFit
819
790
770
787
765
762
762
764
760
Rank
1
2
3
4
5
6
7
8
9
Ret.T ime
B.P.Int.
US.Par.1
US.Par.2
C.A.S,
54105-
26730-
50871
18344
61141
13150
62108
21078
31295
#
67-8
14-3
03-9
37-1
72-8
81-7
25-2
65-9
56-4
11
-------
MID LIBRARY SEARCH /l/3SA NA M
ENHANCED
-------
Library Search Data: 30068107 # 653 Base m/z: 142
08/31/9821:59:00+ 7:16 Cali: 30068107 # 3 RIC: 73600.
Sample: S-MM5-3 1/3SA/100M INST. ID: F16
Conds.: UG/ML *100ML *100%/100% *(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
439 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 22336 1,5-DIOXASPIRO[5.5]UNDECAN-9-ONE, 3.3-DIMETHYL-
2 7849 3(2H)-FURANONE. 4-METHOXY-2.5-DIMETHYL-
3 15148 1,3,2-DIOXABORINANE, 2,4-DIETHYL-5,6-DlMETHYL-
4 27506 DECANE, 3-BROMO-
5 22434 CYCLOHEXANECARBOXYLIC ACID, 1-BUTYL-, METHYL ESTER
6 11522 HEPTANE, 3-[(ETHENYLOXY)METHYL]-
7 32423 HEPTANE, 3,3'-[OXYBIS(METHYLENE)]BIS-
8 14759 CYCLOPROPANE, 1-(2-METHYLBUTYL)-1-<1-METHYLPROPYL>-
9 42522 OECANE, 1,1'-OXYBIS-
Rank
1
2
3
t.
5
6
7
8
9
Formula
C11.H18.03
C7.H10.03
C9.H19.02.B
C10.H21.BR
C12.H22.02
C10.H20.0
C16.H34.0
C12.H24
C20.H42.0
Rank
1
2
3
4
5
6
7
8
9
Ret.Time
M.Wt
198
142
170
220
198
156
242
168
298
B.Pk
141
43
56
57
83
57
57
57
43
Purity
653
510
449
434
406
400
387
364
358
Fit
869
706
623
600
634
556
537
491
643
RFit
657
544
528
444
494
421
407
394
406
B.P.Int.
US.Par.1 US.Par.2
C.A.S
69225
4077
74744
30571
7362
103
10143
64723
2456
. #
59-8
47-8
56-2
71-2
81-4
44-6
60-9
36-0
28-2
114C
-------
MID LIBRARY SEARCH (LIBRARYNB)
88/31/98 21:59:00 + 7:16
SAMPLE: S-MM5-3 1/3SA/100M
CONDS.: UG/ML *100ML
ENHANCED
DATA:
CALI:
INST. ID: F16
*
-------
Library Search Data: 30068107 # 663
08/31/9821:59:00+ 7:22 Cali: 30068107 # 3
Sample: S-HM5-3 1/3SA/100M INST. ID: M6
Conds.: UG/ML *100ML *100X/100% *(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
Base m/z: 57
RIC: 119168.
62231 spectra in LIBRARYNB searched for maximum PURITY
372 matched at least 8 of the 16 largest peaks in the unknown
Rank In,
1 15356
19016
19015
11602
8104
6 15359
7 18985
8 19013
9 19026
Name
DECANE, 2,4
UNDECANE, 4
DECANE, 2,5
OCTANE, 2,4
OCTANE, 3,5
UNDECANE, 5
TRIDECANE
DECANE, 2,5
DECANE, 2,6
-DIMETHYL-
,7-DIMETHYL-
,6-TRIMETHYL-
,6-TRIMETHYL-
-DIMETHYL-
-METHYL-
,9-TRIMETHYL-
,8-TRIMETHYL-
Rank
1
2
3
4
5
6
7
8
9
Formula
C12.H26
C13.H28
C13.H28
C11.H24
C10.H22
C12.H26
C13.H28
C13.H28
C13.H28
M.Ut
170
184
184
156
142
170
184
184
184
B.Pk
43
43
57
57
57
43
57
57
57
Purity
848
846
843
836
836
835
831
826
824
Fit
966
941
937
971
938
953
950
935
930
RFit
849
861
843
837
844
840
846
826
841
Rank
1
2
3
4
5
6
7
8
9
Ret.Time
B.P.Int.
US.Par.1
US.Par.2
C.A.S
2801
17301
62108
62016
15869
1632
629
62108
62108
. #
84-5
32-5
23-0
37-9
93-9
70-8
-50-5
22-9
-26-3
-------
MID LIBRARY SEARCH CLIBRARYNB)
08/31/98 21:59:00 + 7:22
SAMPLE: S-MM5-3 1/3SA/100M
CONDS.: UG/ML *100ML
ENHANCED
DATA: 30068107 ft 663
CALI: 30068107 ft 3
INST. ID: F16
*/l/3SA NA M
BASE M/Z: 57
RIC: 119168.
1250 i
SAMPLE
C12.H26
1250 i
M WT 170
B PK 43
RANK 1
ft 15356
PUR 848
C13.H28
1250 i
M WT 184
B PK 43
RANK 2
ft 19016
PUR 846
C13.H28
1250 i
M WT 184
B PK 57
RANK 3
ft 19015
PUR 843
M/Z
|
i
r
1
r
r
r
1
.ii . 1 1 . ..... ... . . . . .... ..^^
DECANE, 2,4-DIMETHYL- Q \ ^ ^
i
.1 ....
UNDECANE, 4,7-DIMETHYL-
II
l . .. .. ... , .
DECANE, 2,5,6-TRIMETHYL-
1
,ll II
40 60 80 100 120 140 160 180
-------
Library Search Data: 30068107 # 678 Base m/z: 57
08/31/9821:59:00+ 7:32 Cati: 30068107 # 3 RIC: 56960.
Sample: S-MM5-3 1/3SA/100M INST. ID: F16
Conds.: UG/ML *100ML *100X/100X *(NA/NA )/1/3SA NA M
Enhanced (S 158 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
427 matched at least 6 of the 16 largest peaks in the unknown
Rank In. Name
1 12534 NAPHTHALENE, 1,2,3,4-TETRAHYDRO-2,6-DIMETHYL-
2 12552 NAPHTHALENE, 1,2,3,4-TETRAHYDRO-2.7-DIMETHYL-
3 32792 FALCARINOL (Z)-(-)-1,9-HEPTADECADIENE-4,6-D!YNE-3-OL
4 12526 1,4-DIMETHYL-1.2,3,4-TETRAHYDRONAPHTHALENE
5 30843 4,4,6-TRIMETHYL-6-PHENYLTETRAHYDRO-1.3-OXAZINE-2-THIONE
6 5159 NONANE
7 30039 BENZENE, (4-METHYL-1-DECENYL)-
8 12576 1H-INDENE, 1-ETHYL-2,3-DIHYDRO-1-METHYL-
9 37251 1-IOOO-2-METHYLNONANE
Rank Formula M.Ut B.Pk Purity Fit RFit
1 C12.H16 160 118 466 884 468
2 C12.H16 160 118 447 959 450
3 C17.H24.0 244 55 414 733 449
4 C12.H16 160 118 400 914 418
5 C13.H17.0.N.S 235 118 398 744 492
6 C9.H20 128 43 394 945 394
7 C17.H26 230 104 389 615 444
8 C12.H16 160 131 387 669 387
9 C10.H21.I 268 43 385 923 401
Rank Ret.Time B.P.Int. US.Par.1 US.Par.2 C.A.S. #
1 7524-63-2
2 13065-07-1
3
4 - -
5 - -
6 111-84-2
7 62337-88-6
8 56298-75-0
9 - -
1144
-------
1000
SAMPLE
MID LIBRARY SEARCH CLIBRARYNB)
08/31/98 21:59:08 + 7:32
SAMPLE: S-MM5-3 1/3SA/100M INST. ID: F16
CONDS.: UG/ML *100ML *100Z/100Z *
DATA: 30068107 # 678
CALI: 30068107 # 3
BASE M/Z: 57
RIC: 56960.
4JL
J^
C12.H16
1000
M WT 160
B PK 118
RANK 1
# 12534
PUR 466
C12.H16
1000
M WT 160
B PK 118
RANK 2
# 12552
PUR 447
C17.H24.0
1000
M WT 244
B PK 55
RANK 3
# 32792
PUR 414
NAPHTHALENE, 1,2, 3, 4-TETRAHYDRO-2,6-DI METHYL-
NAPHTHALENE, l,2,3,4-TETRAHYDRO-2,7-DIMETHYL-
FALCARINOL < Z)-<-)-1,9-HEPTADECADIENE-4,6-DIYNE-3-OL
50
100
150
200
250
300
350
400
450
CM
-------
Library Search Data: 30068107 # 700
08/31/9821:59:00+ 7:47 Cali: 30068107 # 3
Sample: S-MM5-3 1/3SA/100M 1NST. ID: F16
Conds.: UG/ML *100ML *100%/100% *(NA/NA )/1/3SA NA H
Enhanced (S 158 2N OT)
Base m/z: 81
R!C: 28224.
62231 spectra in LIBRARYNB searched for maximum PURITY
897 matched at least 4 of the 16 largest peaks in the unknown
Rank In. Name
1 12534 NAPHTHALENE, 1,2,3,4-TETRAHYDRO-2.6-DIMETHYL-
2 12552 NAPHTHALENE, 1,2.3,4-TETRAHYDRO-2,7-DIMETHYL-
3 12536 81PHENYLENE, 1,2,3,6,7,8,8A,8B-OCTAHYORO-, TRANS-
4 41258 6,9-OCTADECADIYNOIC ACID, METHYL ESTER
5 12526 1,4-D1METHYL-1,2,3,4-TETRAHYDRONAPHTHALENE
6 12577 BENZENE, 4-(2-BUTENYL)-1,2-DIMETHYL-, -
7 12573 NAPHTHALENE, 1,2,3,4-TETRAHYDRO-!,5-DIMETHYL-
8 16368 BENZENE, (2,2-DIMETHYLCYCLOPENTYL)-
9 12557 NAPHTHALENE, 1,2,3,4-TETRAHYDRO-6,7-DIMETHYL-
Rank
1
2
3
4
5
6
7
8
9
Formula
C12.H16
C12.H16
C12.H16
C19.H30.02
C12.H16
C12.H16
C12.H16
C13.H18
C12.H16
M.Wt
160
160
160
290
160
160
160
174
160
B.Pk
118
118
91
91
118
145
145
104
145
Purity
399
399
399
371
363
352
349
335
329
Fit
824
841
804
638
839
703
734
688
738
RFit
438
442
447
516
413
417
383
399
369
Rank
1
2
3
4
5
6
7
8
9
Ret.Time
B.P.Int.
US.Par.1 US.Par.2
C.A.S. #
7524-63-2
13065-07-1
28229-15-4
56847-03-1
54340-86-2
21564-91-0
19960-99-7
1076-61-5
146
-------
MID LIBRARY SEARCH (LIBRARYNB)
08/31/98 21:59:00 + 7:47
SAMPLE: S-MM5-3 1/3SA/108M INST. ID: F16
CONDS.: UG/ML *100ML *1002/100Z */l/3SA NA M
ENHANCED
DATA: 30068187 # 709
CALI: 30068107 # 3
BASE M/Z: 81
RIC: 28224.
1380 i
SAMPLE
C12.H16
1380 i
M WT 160
6 PK 118
RANK 1
# 12534
PUR 399
C12.H16
1380 i
M WT 160
B PK 118
RANK 2
# 12552
PUR 399
C12.H16
1380 i
M WT 160
B PK 91
RANK 3
# 12536
PUR 399
M/Z
r
r
I
' ' i ' ' ^
r
1
r
I
T
,
^
1
NAPHTHALENE,
.
NAPHTHALENE,
hi
BIPHENYLENE,
49
n
60
k
i
I
ll 1
!
1 , 2, 3, 4-TETRAHYDRO-2, 6-D
111
II
t , .1
o^'
i
.1 ....
IMETHYL-
1
ll
i i
, ,
n
1,2,3, 4-TETRAHYDRO-2, 7-DIMETHYL-
,1
ll
i
1,2,3,6,7,8,8A, 8B-OCT AHYDRO- , TRANS-
ll
' i '
80
100
II
120
1 ,
140 160 180 200
-------
Library Search Data: 30068107 # 738 Base m/z: 57
08/31/9821:59:00+ 8:13 Cali: 30068107 # 3 RIC: 147968.
Sample: S-MM5-3 1/3SA/100M INST. ID: F16
Conds.: UG/ML *100ML *100%/100X *(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
712 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 25991 DODECANE, 2,6,10-TRIMETHYL-
2 42196 HEPTADECANE, 2,6,10.14-TETRAMETHYL-
3 26001 DOOECANE, 2,7,10-TRIMETHYL-
4 37462 HEPTADECANE, 2,6-DIMETHYL-
5 22535 DODECANE, 4,6-DIMETHYL-
6 25997 PENTADECANE
7 25994 DOOECANE, 2,6,11-TRIMETHYL-
8 22530 TETRADECANE
9 15352 UNDECANE, 2-METHYL-
H.Wt B.Pk Purity Fit RFit
Rank
1
2
3
4
5
6
7
8
9
Rank
1
2
3
4
5
6
7
8
9
Formula
C15.H32
C21.H44
C15.H32
C19.H40
C14.H30
C15.H32
C15.H32
C14.H30
C12.H26
Ret. Time
212
296
212
268
198
212
212
198
170
57
57
57
57
57
57
57
43
43
822
821
816
814
812
806
804
791
790
975
940
988
941
955
942
977
922
942
823
842
816
838
812
821
807
803
796
B.P.Int.
US.Par.1
US.Par.2
C.A.S.
3891-
18344-
74645-
54105-
61141-
629-
31295-
629
7045'
#
98-3
37-1
98-0
67-8
72-8
62-9
56-4
59-4
71-8
1148
-------
1210 i
SAMPLE
MID LIBRARY SEARCH (LIBRARYNB)
08/31/98 21:59:00 + 8:13
SAMPLE: S-MM5-3 1/3SA/100M INST. ID: F16
CONDS.: UG/ML *100ML *100Z/1002 */l/3SA NA M
ENHANCED
DATA:
CALI:
30068107 # 738
30068107 # 3
BASE M/Z: 57
RIC: 147968.
I l|i , [ 1'"', ,' " I' ! 1
DODECANE, 2,6,10-TRIMETHYL-
C15.H32
1210
M WT 2
B PK
RANK 1
# 25991
PUR 822
C21.H44
1210
M WT 296
B PK 57
RANK 2
ป 42196
PUR 821
C15.H32
1210
M WT 212
B PK 57
RANK 3
tt 26001
PUR 816
M/Z
HEPTADECANE, 2, S, 10,14-TETRAMCTHYL-
DODECANE, 2,7,10-TRIMETHYL-
50
100
150
200
250
K*
K-'
CO
-------
Base m/z: 43
RIC: 227584.
Library Search Data: 30068107 # 764
08/31/9821:59:00+ 8:30 Call: 30068107 # 3
Sample: S-MM5-3 1/3SA/100M 1NST. ID: F16
Conds.: UG/ML *100ML *100%/100% *(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
672 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 22530 TETRADECANE
2 19006 DECANE. 6-ETHYL-2-METHYL-
3 19007 DODECANE, 3-METHYL-
4 11612 NONANE, 2,5-DIMETHYl-
5 11607 UNDECANE
6 42196 HEPTADECANE, 2,6.10,14-TETRAMETHYL-
7 39681 1-IODOUNDECANE
8 18990 UNDECANE, 2,9-DIMETHYL-
9 37252 DECANE, 1-IODO-
Rank
1
2
3
4
5
6
7
8
9
Rank
1
2
3
4
5
6
7
8
9
Formula
C14
C13
C13
C11
C11
C21
C11
C13
C10
.H30
.H28
.H28
.H24
.H24
.H44
.H23.I
.H28
.H21.I
Ret. Time
B.P.Int.
M.Ut
US. Par. 1
198
184
184
156
156
296
282
184
268
B.Pk Purity Fit
43
57
57
57
43
57
57
57
57
US. Par. 2
723 951
722 956
702 896
701 861
698 966
688 915
688 860
688 867
686 883
C.A.S. #
629-59-4
62108-21-8
17312-57-1
17302-27-1
1120-21-4
18344-37-1
4282-44-4
17301-26-7
2050-77-3
RFit
726
722
702
701
698
715
694
688
691
II
err
-------
MID LIBRARY SEARCH (LIBRARYNB)
08x31/98 21:59s00 + 8:30
SAMPLE: S-MM5-3 1/3SA/100M INST. ID: F16
CONDS.: UG/tlL *100ML *100Z/1007> *
DATA: 30068107 # 764
CALI: 30068107 # 3
BASE M/Z: 43
RIC: 227584.
1289
SAMPLE
C14.H30
1289 i
M WT 198
B PK 43
RANK 1
# 22530 '
PUR 723
C13.H28
1289 1
M WT 184
B PK 57
RANK 2
ซ 19006 '
PUR 722
C13.H28
1289
M WT 184
B PK 57
RANK 3
# 19007
PUR 702
M/Z
r
_, l_J
, ,h
TETRADECANE
r
1
h
r
,
n
r
I
1 i
DECANE, 6-ETHYL-2-METHYL-
i 'I i I' '
DODECANE, 3-METHYL-
i . .. ii.
40 60 80 100 120 140 160 180 200 226
h-
C/l
-------
Library Search Data: 30068107 # 776 Base m/z: 156
08/31/9831:59:00+ 8:38 Cali: 30068107 # 3 RIC: 56512.
Sample: S-MM5-3 1/3SA/100M 1NST. ID: F16
Conds.: UG/ML *100ML *100%/100X *(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
277 matched at least 5 of the 16 largest peaks in the unknown
Rank In. Name
1 11625 NAPHTHALENE, 1,3-DIMETHYL-
2 11618 NAPHTHALENE, 2,3-DIMETHYL-
3 11629 NAPHTHALENE, 1,5-DIMETHYL-
4 11619 NAPHTHALENE, 1,2-OIMETHYL-
5 11615 NAPHTHALENE, 2.7-DIMETHYL-
6 11628 NAPHTHALENE, 1,6-DIMETHYL-
7 11621 NAPHTHALENE, 1,8-DIMETHYL-
8 11620 NAPHTHALENE, 2,6-DIMETHYL-
9 11624 NAPHTHALENE, 1,7-DlMETHYL-
Rank Formula M.Wt B.Pk Purity Fit RFit
1 C12.H12 156 156 638 958 660
2 C12.H12 156 156 636 957 651
3 C12.H12 156 156 632 950 658
4 C12.H12 156 156 630 948 646
5 C12.H12 156 156 627 943 653
6 C12.H12 156 156 624 939 649
7 C12.H12 156 156 619 943 647
8 C12.H12 156 156 617 949 648
9 C12.H12 156 156 616 936 652
Rank Ret.Time B.P.lnt. US.Par.1 US.Par.2 C.A.S. #
1 575-41-7
2 581-40-8
3 571-61-9
i. 573-98-8
5 582-16-1
6 575-43-9
7 569-41-5
8 581-42-0
9 575-37-1
11
-------
MID LIBRARY SEARCH (LIBRARYNB)
08/31/"98 21:59:80 + 8:38
SAMPLE: S-MM5-3 1/3SA/100M INST. ID: F16
CONDS.: UG/ML *100ML *100Z/100Z *
-------
Library Search Data: 30068107 it 820 Base m/z: 57
08/31/9821:59:00+ 9:07 Cali: 30068107 # 3 RIC: 145408.
Sample: S-MM5-3 1/3SA/100M INST. ID: F16
Conds.: UG/ML "100ML *100%/100X ซ(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
855 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 42196 HEPTADECANE, 2,6,10,14-TETRAMETHYL-
2 37462 HEPTADECANE, 2,6-DIMETHYL-
3 25997 PENTADECANE
4 25991 DOOECANE, 2,6,10-TRIMETHYL-
5 22530 TETRADECANE
6 18987 UNDECANE, 2,8-DlMETHYL-
7 19016 UNDECANE, 4,7-DIMETHYL-
8 15353 2,6-DIMETHYLDECANE
9 37465 NONADECANE
Rank
1
2
3
4
5
6
7
8
9
Formula
C21.H44
C19.H40
C15.H32
C15.H32
C14.H30
C13.H28
C13.H28
C12.H26
C19.H40
H.Ut
296
268
212
212
198
184
184
170
268
B.Pk
57
57
57
57
43
43
43
43
57
Purity
837
808
787
782
782
782
780
779
778
Fit
980
952
946
964
938
964
950
925
928
RFit
844
824
799
783
793
785
781
788
810
Rank
1
2
3
4
5
6
7
8
9
Ret.Time
B.P.Int.
US.Par.1
US.Par.2
C.A.S.
18344-
54105-
629-
3891-
629-
17301-
17301-
13150-
629-
#
37-1
67-8
62-9
98-3
59-4
25-6
32-5
81-7
92-5
1154
-------
MID LIBRARY SEARCH (LIBRARYNB)
08/31/98 21:59:00 + 9:07
SAMPLE: S-MM5-3 1/3SA/100M
CONDS.: UG/ML *100ML
ENHANCED
DATA:
CALI:
INST. ID: F16
*/l/3SA NA M
30068107 # 820
30068107 # 3
BASE M/Z: 57
RIC: 145408.
1171
SAMPLE
r
J
, J. I t tl i . .
C21.H44 HEPTADECANE, 2,6, 10, 14-TETRAMETHYL- rrr \^(r^^^
1171 -i
M WT 296
B PK 57
RANK 1
ft 42196 :
PUR 837
r
C19.H40
1171 -I
M WT 268
B PK 57
RANK 2
# 37462 '
PUR 808
1
r
^^ ^
,
'
HEPTADECANE , 2 , 6-D I METHYL-
1
C15.H32 PENTADECANE
1171 i
M WT 212
B PK 57
RANK 3
# 25997
PUR 787
r
,1
M/Z 50 100 150 200 250
V-
I.
c -
c".
-------
Library Search Data: 30068107 # 859 Base m/z: 57
08/31/98 21:59:00 + 9:33 Call': 30068107 # 3 RIC: 195840.
Sample: S-MM5-3 1/3SA/100M INST. ID: F16
Conds.: UG/ML *100ML *100%/100% *(NA/NA )/1/3SA HA M
Enhanced CS 15B 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
559 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 19007 OODECANE, 3-METHYL-
2 25997 PENTADECANE
3 18990 UNDECANE, 2,9-DlMETHYL-
4 19026 DECANE, 2,6,8-TRIMETHYL-
5 29249 TETRADECANE, 6,9-DIMETHYL-
6 39661 1-IODOUNDECAME
7 15352 UNDECANE, 2-METHYL-
8 19006 DECANE, 6-ETHYL-2-METHYL-
9 15357 DECANE, 2,9-DIMETHYL-
Rank
1
2
3
4
5
6
7
8
9
Formula
C13.H28
C15.H32
C13.H28
C13.H28
C16.H34
C11.H23.I
C12.H26
C13.H28
C12.H26
M.wr
184
212
184
184
226
282
170
184
170
B.Pk
57
57
57
57
57
57
43
57
43
Pur i ty
803
799
797
796
792
792
792
792
790
Fit
960
941
957
946
934
968
936
958
962
RFit
810
818
799
799
810
800
803
800
790
Rank
1
2
3
4
5
6
7
8
9
Ret.Time
8.P.Int.
US.Par.1
US.Par.2
C.A.S.
17312-
629-
17301-
62108-
55045-
4282-
7045-
62108-
1002-
#
57-1
62-9
26-7
26-3
13-1
44-4
71-8
21-8
17-1
1156
-------
MID LIBRARY SEARCH
08/31/98 21:59:09 + 9:33
SAMPLE: S-MM5-3 1/3SA/100M INST. ID: F16
CONDS.: UG/ML *100ML * 100Z/100?; */l/3SA NA M
ENHANCED
DATA: 30068107 # 859 BASE M/Z: 57
CALI: 30068107 # 3 RIC: 195840.
1186 -
SAMPLE
r
1
. Ji
^fl^oC^^1^*^ >c- *^
1 . It . . 1. .111.. ..!.. ... ....1. . . . ....
C13.H28 DODECANE, 3-METHYL- erV ilov^*^
1186 n
M WT 184
B PK 57
RANK 1
# 19007
PUR 803
r
1
,1
C15.H32 PENTADECANE
1186 ]
M WT 212
B PK 57
RANK 2
# 25997
PUR 799
r
II
C13.H28 UNDECANE, 2,9-DIMETHYL-
1186 i
M WT 184
B PK 57
RANK 3
* 18990
PUR 797
r
1
M/Z 40 60 80 100 120 140 160 180 200
en
-------
Base m/z: 57
RIC: 73344.
Library Search Data: 30068107 # 904
08/31/98 21:59:00 + 10:03 Cali: 30068107 # 3
Sample: S-MM5-3 1/3SA/100M INST. ID: F16
Conds.: UG/ML *100ML *100%/100% *(NA/NA )/1/3SA NA M
Enhanced (S 158 2N OT)
62231 spectra in L1BRARYNB searched for maximum PURITY
782 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 40233 NONADECANOL
2 42521 1-EICOSANOL
3 37444 OXIRANE, HEXADECYL-
4 37449 OCTADECANAL
5 22482 2-TRIDECEN-1-OL, (E)-
6 40193 CIS-9,10-EPOXYOCTADECAN-1-OL
7 25971 OXIRANE, DOOECYL-
8 32052 OXIRANE, TETRADECYL-
9 42180 OCTADECANE, I-(ETHENYLOXY)-
Rank
1
2
3
4
5
6
7
8
9
Formula
C19.H40.0
C20.H42.0
C18.H36.0
C18.H36.0
C13.H26.0
C18.H36.02
C14.H28.0
C16.H32.0
C20.H40.0
Rank
1
2
3
4
5
6
7
8
9
Ret.Time
M.Wt
284
298
268
268
198
284
212
240
296
B.Pk
43
43
57
43
57
55
41
41
43
Purity
647
645
643
640
637
636
636
630
621
Fit
923
919
867
873
923
906
911
942
930
RFit
686
688
672
683
648
666
642
630
656
B.P.Int.
US.Par.1
US.Par.2
C.A.S
52783
629
7390
638
74962
13980
3234
7320
930
, #
43-4
96-9
81-0
66-4
98-4
12-6
28-4
37-8
02-9
1 ป err
<*. * ซ f^
-------
1194
SAMPLE
MID LIBRARY SEARCH
08/31/98 21:59:00 + 10:03
SAMPLE: S-MM5-3 1/3SA/100M INST. ID: F1S
CONDS.: UG/ML *100ML * 100Z/100?; */l/3SA NA M
ENHANCED
-------
Library Search Data: 30068107 # 948 Base m/z: 57
08/31/9821:59:00+10:33 Call: 30068107 # 3 RIC: 229888.
Sample: S-MM5-3 1/3SA/100M INST. ID: F16
Conds.: UG/ML *100ML *100%/100% *
-------
MID LIBRARY SEARCH
08/31/98 21:59:00 + 10:33
SAMPLE: S-MM5-3 1/3SA/100M INST. ID: F16
CONDS.: UG/ML *100ML *100JJ/10072 *
-------
Library Search Data: 30068107 # 988 Base m/z: 57
08/31/98 21:59:00 + 10:59 Cali: 30068107 # 3 RIC: 164608.
Sample: S-MM5-3 1/3SA/100M 1NST. ID: F16
Conds.: UG/ML *100ML *100%/100% *(NA/NA )/1/3SA NA H
Enhanced (S 15B 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
644 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 37465 NONADECANE
2 37462 HEPTADECANE, 2,6-DIMETHYL-
3 42196 HEPTADECANE, 2.6,10,14-TETRAMETHYL-
4 32059 HEPTADECANE
5 25997 PENTADECANE
6 19054 UNDECANE, 2,6-DIMETHYL-
7 22530 TETRADECANE
8 25996 TRIDECANE, 4,8-DIMETHYL-
9 29263 HEXADECANE
Rank
1
2
3
4
5
6
7
8
9
Formula
C19.H40
C19.H40
C21.H44
C17.H36
C15.H32
C13.H28
C14.H30
C15.H32
C16.H34
M.Wt
268
268
296
240
212
184
198
212
226
B.Pk
57
57
57
57
57
57
43
57
57
Puri ty
832
832
826
824
824
822
820
814
810
Fit
945
956
957
941
953
951
947
935
928
RFit
852
843
838
836
846
829
824
830
849
Rank
1
2
3
4
5
6
7
8
9
Ret.Time 8.P.Int.
US.Par.1
US.Par.2
C.A.S.
629-
54105-
18344-
629-
629-
17301-
629
55030'
544
#
92-5
67-8
37-1
78-7
62-9
23-4
59-4
62-1
76-3
-------
MID LIBRARY SEARCH (LIBRARYNB)
08/-31/-98 21:59:00 + 10:59
SAMPLE: S-MM5-3 1/3SA/100M INST. ID: F16
CONDS.: UG/tIL *100ML *100Z/100Z *
DATA: 30068107 # 988
CALI: 30068107 # 3
BASE M/Z: 57
RIC: 164608.
1000
SAMPLE
C19.H40
1000 I
M WT 268
B PK 57
RANK 1
# 37465 '
PUR 832
C19.H40
1000 1
M WT 268
B PK 57
RANK 2
# 37462 '
PUR 832
C21.H44
1000 -
M WT 296
B PK 57
RANK 3
* 42196
PUR 826
M/Z
NONADECANE ^ ^$&^LS
|
|
I
II
HEPTADECANE , 2 , 6-D I METHYL-
ft
|
50
I
HEPTADECANE , 2,6,10,1 4-TETRAMETHYL-
I
i ,i .1 . . _ ., ^ ._ .. - . ,- t i- . , . --. . . . i
100 150 200 250
CD
-------
Library Search Data: 30068107 #1036 Base m/z: 57
08/31/9821:59:00+11:31 Call: 30068107 # 3 RIC: 240640.
Sample: S-MM5-3 1/3SA/100M INST. ID: F16
Conds.: UG/ML *100ML *100%/100% *(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
713 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 37462 HEPTADECANE, 2,6-DlMETHYL-
2 42196 HEPTADECANE, 2.6,10,14-TETRAMETHYL-
3 37465 NONADECANE
4 26001 DOOECANE, 2,7,10-TRIMETHYL-
5 25991 DOOECANE, 2,6,10-TR1METHYL-
6 37466 PENTADECANE, 2,6,10.14-TETRAMETHYL-
7 22535 DOOECANE, 4,6-DIMETHYL-
8 25994 DODECANE, 2,6,11-TRIMETHYL-
9 29264 TRIDECANE, 5-PROPYL-
Rank
1
2
3
4
5
6
7
8
9
Formula
C19.H40
C21.H44
C19.H40
C15.H32
C15.H32
C19.H40
C14.H30
C15.H32
C16.H34
H.Wt
268
296
268
212
212
268
198
212
226
B.Pk
57
57
57
57
57
71
57
57
57
Purity
875
833
831
826
825
820
818
809
806
Fit
976
949
940
970
973
946
961
949
947
RFit
882
857
844
830
827
834
820
816
827
Rank
1
2
3
4
5
6
7
8
9
Ret.Time B.P.lnt.
US.Par.1
US.Par.2
C.A.S
54105
18344
629
74645
3891
1921
61141
31295
55045
, #
67-8
37-1
92-5
98-0
98-3
-70-6
-72-8
56-4
-11-9
164
-------
MID LIBRARY SEARCH /l/3SA NA M
ENHANCED
DATA: 30068107 #1036
CALI: 30068107 # 3
BASE M/Z: 57
RIC: 240640.
1128 1
SAMPLE
C19.H40
1128 -,
M NT 268
B PK 57
RANK 1
# 37462 '
PUR 875
C21.H44
1128 i
M WT 296
B PK 57
RANK 2
# 42196
PUR 833
C19.H40
1128
M WT 268
B PK 57
RANK 3 ,
ft 37465
PUR 831
M/Z
I
I
|
n, ,- UJ
1
I i | Ml
!
1
j
50
.1
U.i.l. ..il. . .1. . . . - 1 . - - . - . ,- ... . ., T . , ,
HEPTADECANE, 2,6-DIMETHYL- ^ crw-*^'
|
,i 1 1 j| , . ., ... ... , .,. - ,-.-, , ,
HEPTADECANE , 2,6,10,1 4-TETRAMETHYL-
NONADECANE
1
"-i M
li i,| ,., .. ,. .. - ,--, , . , , , ^ , , ,
100 159 200 250
h-
o
CM
-------
Library Search Data: 30068107 #1054 Base m/z: 55
08/31/9821:59:00+11:43 Call: 30068107 # 3 RIC: 63616.
Sample: S-MM5-3 1/3SA/100M 1NST. 10: F16
Conds.: UG/ML *100ML *100%/100% *(NA/NA )/1/3SA NA M
Enhanced CS 15B 2N OT)
62231 spectra in LIBRARYN8 searched for maximum PURITY
796 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 28768 3-HEXADECENE. (2)-
2 21963 3-TETRADECENE,
-------
MID LIBRARY SEARCH /l/3SA NA M
ENHANCED
DATA: 30968107 #1054
CALI: 30068107 # 3
BASE M/Z: 55
RIC: 63616.
1236
SAMPLE
1
li
, II
f. . . 1^0^**'
,ll
oy^~
\\ . ..III. lj Hi . ,....!..,
C16.H32
1236 1
M WT 224
B PK 55
RANK 1
# 28768
PUR 722
C14.H28
1236 1
M WT 196
B PK 41
RANK 2
# 21963 '
PUR 718
3-HEXADECENE, -
lll 1 . -, , ,
1 . ,-UH , ^i-j , ,u , , M ,__ -t . , ^ i . ' ' ' ^T ' ' ' ' ^ '
3-TETRADECENE, -
1 . . II, . ll. . Ji . . i. ' i ^ i r , , , .
C16.H32
1236 i
M WT 224
B PK 55
RANK 3
# 28772 '
PUR 716
M/Z
1
50
7-HEXADECENE, -
|
I
1 r^
| 1 . . , - '
100 156 200 250
CD
-------
Library Search Data: 30068107 #1114 Base m/z: 57
08/31/9821:59:00+12:23 Cali: 30068107 # 3 RIC: 105344.
Sample: S-MM5-3 1/3SA/100M INST. ID: F16
Conds.: UG/ML *100ML *100%/100% *(NA/NA )/1/3SA NA H
Enhanced (S 158 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
360 matched at least 8 of the 16 largest peaks in the unknown
Rank In.
Name
1 15969 HYDROXYLAMINE, 0-DECYL-
2 37465 NONADECANE
3 37462 HEPTADECANE, 2,6-DIMETHYL-
4 19016 UNDECANE, 4,7-DIMETHYL-
5 42196 HEPTADECANE. 2.6,10,14-TETRAMETHYL-
6 25997 PENTADECANE
7 19523 1-DECANOL, 2-ETHYL-
8 11602 OCTANE, 2,4,6-TRIMETHYL-
9 46161 TRICOSANE
Rank
1
2
3
4
5
6
7
8
9
Formula
C10.H23.0.N
C19.H40
C19.H40
C13.H28
C21.H44
C15.H32
C12.H26.0
C11.H24
C23.H48
M.Wt B.Pk Purity Fit RFit
Rank
1
2
3
4
5
6
7
8
9
Ret.Time 8.P.Int.
173
268
268
184
296
212
186
156
324
US. Par. 1 US
43
57
57
43
57
57
57
57
43
.Par. 2
804
797
794
781
780
767
763
760
758
962
940
930
963
939
937
921
968
886
C.A.S
29812
629
54105
17301
18344
629
21078
62016
638
806
820
828
782
811
805
776
760
842
#
79-1
92-5
67-8
32-5
37-1
62-9
65-9
37-9
67-5
11
r-
C
-------
1047
SAMPLE
Jl
MID LIBRARY SEARCH (LIBRARYNB)
08/31x98 21:59:00 + 12:23
SAMPLE: S-MM5-3 1/3SA/100M
CONDS.: UG/ML *100ML
ENHANCED
DATA:
CALI:
INST. ID: F16
*/l/3SA NA M
30068107 #1114
30068107 # 3
BASE M/Z: 57
RIC: 105344.
C10.H23.0.N
1047
M WT 173
B PK 43
RANK 1
ft 15969
PUR 804
C19.H40
1047
M WT 268
B PK 57
RANK 2
# 37465
PUR 797
HYDROXYLAMINE, 0-DECYL-
1
ll
,11
ill 1 . .1
^r -!--- | | | . , . T t- i . i 1 . i i i
NONADECANE
C19.H40
1047
M WT 268
B PK 57
RANK 3
# 37462
PUR 794
M/Z
HEPTADECANE, 2,6-DIMETHYL-
1
-, 1
50
100
150
200
250
CO
-------
Base m/z: 57
RIC: 136704.
Library Search Data: 30068107 #1119
08/31/98 21:59:00 + 12:27 Cali: 30068107 # 3
Sample: S-MM5-3 1/3SA/100M INST. ID: F16
Conds.: UG/ML *100ML *100%/100X *(NA/NA )/1/3SA NA M
Enhanced (S 158 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
840 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 37465 NONADECANE
2 37462 HEPTADECANE, 2,6-DIMETHYL-
3 42196 HEPTADECANE. 2,6,10,14-TETRAMETHYL-
4 46161 TRICOSANE
5 37466 PENTADECANE, 2,6,10,14-TETRAMETHYL-
6 25991 DOOECANE, 2,6,10-TRIMETHYL-
7 32059 HEPTADECANE
8 39859 OCTADECANE, 2,6-DIMETHYL-
9 26001 DOOECANE, 2,7,10-TR1METHYL-
Rank
1
2
3
4
5
6
7
8
9
Formula
C19.H40
C19.H40
C21.H44
C23.H48
C19.H40
C15.H32
C17.H36
C20.H42
C15.H32
H.Ut
268
268
296
324
268
212
240
282
212
B.Pk
57
57
57
43
71
57
57
57
57
Purity
839
835
816
815
802
799
796
794
794
Fit
964
948
937
920
937
968
929
931
967
RFit
839
839
830
856
806
800
822
799
794
Rank
1
2
3
4
5
6
7
8
9
Ret.Time
B.P.Int.
US.Par.1 US.Par.2
C.A.S
629
54105
18344
638
1921
3891
629
75163
74645
, n
92-5
67-8
37-1
67-5
70-6
98-3
78-7
97-2
98-0
1170
-------
MID LIBRARY SEARCH
88/31/98 21:59:00 + 12:27
SAMPLE: S-MM5-3 1/3SA/100M
CONDS.: UG/ML *100ML
ENHANCED
DATA:
CALI:
INST. ID: F16
*
-------
Library Search Data: 30068107 #1191
08/31/98 21:59:00 + 13:15 Cati: 30068107 # 3
Sample: S-MM5-3 1/3SA/100M 1NST. ID: F16
Conds.: UG/ML *100Mt *100%/100% *(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
Base m/z: 57
RIC: 91264.
62231 spectra in LIBRARYNB searched for maximum PURITY
294 matched at least 8 of the 16 largest peaks in the unknown
Rank In. Name
1 37465 NONADECANE
2 15969 HYDROXYLAMINE, 0-OECYL-
3 37462 HEPTADECANE. 2,6-DIMETHYL-
4 19016 UNDECANE, 4,7-DIMETHYL-
5 42196 HEPTADECANE, 2,6,10.14-TETRAMETHYL-
6 11602 OCTANE, 2,4,6-TRIMETHYL-
7 19015 DECANE, 2,5,6-TRIMETHYL-
8 12074 1-HEPTANOL, 2-PROPYL-
9 25997 PENTADECANE
Rank
1
2
3
4
5
6
7
8
9
Formula
C19.H40
C10.H23.0.N
C19.H40
C13.H28
C21.H44
C11.H24
C13.H28
C10.H22.0
C15.H32
M.Wt B.Pk Purity Fit RFit
268
173
268
184
296
156
184
158
212
57
43
57
43
57
57
57
43
57
769
766
753
750
747
737
731
731
728
938
949
907
955
922
965
928
950
922
806
782
809
755
796
737
731
731
779
Rank
1
2
3
4
5
6
7
8
9
Ret.Time
8.P.Int.
US.Par.1
US.Par.2
C.A.S. #
629-92-5
29812-79-1
54105-67-8
17301-32-5
18344-37-1
62016-37-9
62108-23-0
10042-59-8
629-62-9
117,
-------
MID LIBRARY SEARCH
OS/Sl/SS 21:59:00 + 13:15
SAMPLE: S-MM5-3 1/3SA/100M INST. ID: F16
CONDS.: UG/ML *100ML *100Z/100Z */l/3SA NA M
ENHANCED
DATA: 30068107 #1191
CALI: 30068107 # 3
BASE M/Z: 57
RIC: 91264.
1096
SAMPLE
C19.H40
1096
M WT 268
B PK 57
RANK 1
# 37465
PUR 769
NONADECANE
C10.H23.0.N
1096
M NT 173
B PK 43
RANK 2
# 15969
PUR 766
HYDROXYLAMINE, 0-DECYL-
J_
C19.H40
1096
WT 268
PK 57
RANK 3
# 37462
PUR 753
M/Z
50
1 "
HEPTADECANE, 2,6-DIMETHYL-
100
150
200
250
-------
Library Search Data: 30068107 #1335 Base m/z: 57
08/31/98 21:59:00 + 14:51 Cali: 30068107 # 3 RIC: 45504.
Sanple: S-MM5-3 1/3SA/100M INST. ID: F16
Conds.: UG/ML *100ML *100%/100% *
-------
MID LIBRARY SEARCH CLIBRARYNB)
08/31/98 21s59:00 + 14:51
SAMPLE: S-MM5-3 1/3SA/100M INST. ID: FIG
CONDS.: UG/ML *100ML * 100Z/100Z */l/3SA NA M
ENHANCED
-------
Library Search Data: 30068107 #1402 Base m/z: 57
08/31/98 21:59:00 + 15:36 Cali: 30068107 # 3 RIC: 34624.
Sample: S-MM5-3 1/3SA/100M INST. ID: F16
Conds.: UG/ML *100ML *100%/100% *
-------
MID LIBRARY SEARCH
08/31/98 21:59:08 + 15:36
SAMPLE: S-MM5-3 1/3SA/100M INST. ID: F16
CONDS.: UG/ML *100ML *100Z/100Z *
DATA: 30068107 #1402
CALI: 30068107 tt 3
BASE M/Z: 57
RIC: 34624.
1173 -I
SAMPLE
C19.H40
1173 i
M WT 268
B PK 57
RANK 1
# 37465
PUR 662
C19.H40
1173 -I
M WT 268
B PK 57
RANK 2
# 37462
PUR 644
C23.H48
1173 i
M WT 324
B PK 43
RANK 3
* 46161
PUR 635
M/Z
,
"* i '
50
. .1
Lhl. .. ...1 il ....... . .. - - .... .. . . .... ^^ . 1
NONADECANE 0 r v^cTV^*^
||
n i.l .1 .. -
HEPTADECANE , 2 , 6-D I METHYL-
h
.... .1 . ........ ... . .^ -
J-i '!' "! i-- i1 1 -l ' i r ' | -T -i l 1
TRICOSANE
||
*-i <-Jป
h || .1 ., f ., . .. ,. ., .. .. - ,. , ....,-l-^l ^_, , , , ,__
100 150 200 250 300 350
-------
TIC SELECTION REPORT
DATA FILE: 30068107
THE FOLLOWING PEAKS WERE REJECTED BECAUSE
AT LEAST 40 % OF THEIR SIZE UAS ACCOUNTED FOR BY
TARGET COMPOUNDS ELUTING WITHIN 4 SCANS OF THE
PEAK TOP.
SCAN SIZE AMOUNT
340
530
8Z9
1088
1552
1783
178208.
370816.
337152.
394368.
233408.
216272.
============:
21.143
43.994
40.000
40.000
40.000
40.000
TOTAL NUMBER OF UNIDENTIFIED PEAKS WITH SIZE
GREATER THAN 10 % OF THE CLOSEST INTERNAL STANDARD
THAT DOES NOT HAVE INTERFERENCES = 103
INTERNAL STANDARDS THAT HAVE RIC SIZE LESS THAN
50 % OR GREATER THAN 200 % OF THE ESTIMATED RIC SIZE
ARE CONSIDERED TO HAVE INTERFERENCES AND WILL NOT BE USED
FOR OUANT1TATION.
PERCENT OF
ESTIMATED
* INTERNAL STANDARD RIC SIZE RIC SIZE SCAN
1 CI40 NAPHTHALENE-D8
2 CI50 ACENAPHTHENE-D10
3 CI60 PHENANTHRENE-D10
4 CI70 CHRYSENE-D12
5 CI75 PERYLENE-D12
370816.
337152.
394368.
233408.
216272.
211 *
156
163
140
158
530
829
1088
1552
1783
* INDICATES INTERFERENCE
SIZE = AREA
176
-------
Cllent Name
Client ID:
LAB ID:
Matrix:
Authorized:
Semivolatile Organics
Method 0010/8270
Pacific Environmental Services
S-MM5-FB-F,FH,XAD,COND,BH
300681-0008-SA
AIRTRAIN Sampled: 26 JUL 98
30 JUL 98 Prepared: 31 JUL 98
Dilution Factor: 1.0
Received: 30 JUL 98
Analyzed: 31 AUG 98
Parameter
Phenol
bis(2-Chloroethyl)ether
2-Chlorophenol
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Benzyl alcohol
1,2-Di chlorobenzene
2-Methylphenol
2,2'-Oxybis(l-chloropropane)
3/4-Methylphenol
N-Nitroso-di-n-propylamine
Hexachloroethane
Nitrobenzene
Isophorone
2-Nitrophenol
2,4-Dimethylphenol
Benzoic acid
bi s(2-Chloroethoxy)-methane
2,4-Dichlorophenol
1,2,4-Tri chlorobenzene
Naphthalene
4-Chloroaniline
Hexachlorobutadiene
4-Chloro-3-methyl phenol
2-Methylnaphthalene
Hexachlorocyclopentadi ene
2,4,6-Trichlorophenol
2,4,5-Trichlorophenol
2-Chloronaphthalene
2-Nitroaniline
Dimethyl phthalate
'Acenaphthylene
3-Nitroaniline
Acenaphthene
2,4-Dinitrophenol
4-Nitrophenol
Dibenzofuran
Wet wt.
Result
Units
Reporting
Limit
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
150
30
30
30
30
30
30
30
30
30
30
150
30
30
30
30
150
30
150
150
30
Qualifier
R
Note R = Reporting limit(s) raised due to sample volume limitations.
ND = Not Detected
Reported By: Emily Uebelhoer
Approved By: Karin Yee
The cover letter is an integral part of this report.
Rev 230787
-------
Semivolatile Organics
Method 0010/8270
(cont.)
Client Name:
Client ID:
LAB ID:
Matrix:
Authorized:
Pacific Environmental Services
S-MM5-FB-F,FH,XAD,COND,BH
300681-0008-SA
AIRTRAIN Sampled:
30 JUL 98 Prepared:
26 JUL 98
31 JUL 98
Dilution Factor: 1.0
Parameter
2,4-Dinitrotoluene
2,6-Dinitrotoluene
Diethyl phthalate
4-Chlorophenyl phenyl ether
Fluorene
4-Nitroaniline
4,6-Dinitro-2-methyl phenol
N-Nitrosodiphenylamine
4-Bromophenyl phenyl ether
Hexachlorobenzene
Pentachlorophenol
Phenanthrene
Anthracene
Di-n-butyl phthalate
Fluoranthene
Pyrene
Butyl benzyl phthalate
3,3'-Dichlorobenzidine
Benzo(a)anthracene
bi s(2-Ethylhexyl)-phthalate
Chrysene
Di-n-octyl phthalate
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Benzo(a)pyrene
Indeno(l,2,3-cd)pyrene
Di benz(a,h)anthracene
Benzo(g,h,i)perylene
Acetophenone
4-Aminobiphenyl
Aniline
Benzidine
3,3'-Dimethylbenzidine
N-Nitrosodimethylamine
N-Nitrosomorphol ine
Pentachloronitrobenzene (PCNB)
o-Toluidine
Wet vrt.
Result
Units
Received: 30 JUL 98
Analyzed: 31 AUG 98
Reporting
Limit
Qualifier
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ug/Sample
ug/ Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
30
30
30
30
30
150
150
30
30
30
150
30
30
30
30
30
30
60
30
30
30
30
30
30
30
30
30
30
30
150
30
300
60
30
30
150
60
ND = Not Detected
Reported By: Emily Uebelhoer
Approved By: Karin Yee
The cover letter is an integral part of this report.
Rev 230787
1180
-------
Semivolatile Organics
Method 0010/8270
(cont.)
Client Name: Pacific Environmental Services
Client ID: S-MM5-FB-F,FH,XAD,COND,BH
LAB ID: 300681-0008-SA
Matrix: AIRTRAIN Sampled: 26 JUL 98
Authorized: 30 JUL 98 Prepared: 31 JUL 98
Dilution Factor: 1.0
Wet wt.
Parameter Result Units
2-Methoxybenzenamine ND ug/Sample
Biphenyl ND ug/Sample
Chloroacetophenone ND ug/Sample
Cumene ND ug/Sample
DBCP (l,2-Dibromo-3-chloropropane) ND ug/Sample
Benzo(e)pyrene ND ug/Sample
N-N-Diethylaniline ND ug/Sample
Dimethyl aniline ND ug/Sample
3,3'-Dimethoxybenzidine ND ug/Sample
Hydroquinone ND ug/Sample
4,4'-Methyl-bis(2-chloroaniline) ND ug/Sample
4-Nitrodiphenyl ND ug/Sample
Trifluralin ND ug/Sample
Received: 30 JUL 98
Analyzed: 31 AUG 98
Reporting
Limit
Qualifier
K
K
K
K
K
K
K
K
K
K
K
K
K
Surrogate
Nitrobenzene-d5
2-Fluorobiphenyl
Terphenyl-dl4
Phenol-d5
2-Fluorophenol
2,4,6-Tri bromophenol
Recovery
58 %
79
101
59
54
74 %
Acceptable Range
45 - 107
62 - 110
58 - 135
43 - 130
36 - 111
58 - 131
Note K = Identified by mass spectrum only; quantitation based on 1:1 response with
internal standard.
ND = Not Detected
Reported By: Emily Uebelhoer
Approved By: Karin Yee
The cover letter is an integral part of this report.
Rev 230787
1161
-------
Semivolatiles Library Search (20 Compound TID)
Method 8270
Client Name: Pacific Environmental Services
Client ID: S-MM5-FB-F,FH,XAD,COND,BH
LAB ID: 300681-0008-SA
Matrix: AIRTRAIN Sampled: 26 JUL 98
Authorized: 30 JUL 98 Prepared: NA
Dilution Factor: 1.0
Parameter
n-Nonane
Benzaldehyde
Heptadecane, 2,6-dimethyl-
4-Hydroxy-4-methyl-2-pentanone
Hexadecanoic acid
Unknown alkane
Tricosane
Unknown alkane
Unknown
Unknown alkane
5-Eiconsene,(E) -
Unknown
Unknown
Unknown alkane
Unknown
Unknown
Unknown
Unknown
Unknown alkene
Unknown
Result
360
29
52
380
33
51
31
30
36
45
150
49
34
26
57
77
58
42
30
27
Units
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
ug/Sample
Received: 30 JUL 98
Analyzed: 31 AUG 98
Reporting
Limit Qualifier
0
0
0
0
0
0
Note 0 = Or structurally similar compound (isomer).
NA = Not Applicable
Reported By: Emily Uebelhoer
Approved By: Karin Yee
The cover letter is an integral part of this report.
Rev 230787
f c r-
-------
Sample: S-MM5-FB
Client: PACIF1
Analyst: DAT
OUANTERRA GC/HS
Target Compound Data Summary Sheet
1/3SA/1ML
1NST. ID:
Instrument ID: F16
Quan List Threshold: 0.95
Data File: 30068108
Std Id: ST16980831
F16
Date Analyzed: 08/31/98 22:29
Run Factor: 3.00
Surrogate Vol.:
1.00
Surrogate
Surrogate Spike Recoveries
8270-G, LIMS 10/10/96
Surrogate Amount (ug)
Spiked Measured
CS20 NITROBENZENE-DS
CS25 2-FLUOROBIPHENY
CS30 TERPHENYL-D14
CS45 PHENOL -D5
CS50 2-FLUOROPHENOL
CS55 2,4,6-TRIBROMOP
50.00
50.00
50.00
100.0
100.0
100.0
29.00
39.30
50.70
58.80
53.80
74.20
58.0
78.6
101.
58.8
53.8
74.2
X Recovery
Measured QC limits
45 107
62 110
58 135
43 130
36 111
58 131
Target Compounds: SAP9
Parameter Scan Result Units
HEXACHLOROBENZENE-C13 NO UG/A
C310 N-NITROSODIMETHYLAMINE NO UG/A
PYRIDINE ND UG/A
2-PICOLINE ND UG/A
N-NITROSOMETHYLETHYLAMINE ND UG/A
METHYLMETHANESULFONATE ND UG/A
N-NITROSODIETHYLAMINE ND UG/A
ETHYLMETHANE SULFONATE ND UG/A
PENTACHLOROETHANE ND UG/A
C320 ANILINE ND UG/A
C315 PHENOL ND UG/A
C325 BIS(2-CHLOROETHYL)ETHER ND UG/A
C330 2-CHLOROPHENOL ND UG/A
C335 1,3-OICHLOROBENZENE ND UG/A
C340 1,4-DlCHLOROBENZENE ND UG/A
C345 BENZYl ALCOHOL ND UG/A
C350 1,2-DICHLOROBENZENE ND UG/A
C355 2-METHYLPHENOL ND UG/A
C360 2,2'-OXYBIS(1-CLPROPAN) ND UG/A
C361 ACETOPHENONE ND UG/A
N-NITROSOPYRROLIDINE ND UG/A
N-NITROSOMORPHOLINE ND UG/A
3-METHYL PHENOL ND UG/A
C365 4-METHYLPHENOL ND UG/A
C370 N-NITROSO-DI-N-PROPYLAM ND UG/A
0-TOLUID1NE ND UG/A
C375 HEXACHLOROETHANE ND UG/A
C410 NITROBENZENE ND UG/A
N-NITROSOPIPERIDINE ND UG/A
Reviewed by:
Reporting
Limit
30.0
30.0
60.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
-------
Sample: S-MM5-FB
Client: PACIFI
Analyst: DAT
GUANTERRA GC/MS
Target Compound Data Summary Sheet
Data File: 30068108
Std Id: ST16980831
1/3SA/1ML INST. ID: F16
Date Analyzed: 08/31/98 22:29
Instrument ID: F16 Run Factor: 3.00
Quan List Threshold: 0.95
Surrogate Vol.:
1.00
Parameter
Target Compounds: SAP9
Scan
C415 ISOPHORONE
C420 2-NITROPHENOL
C425 2,4-DIMETHYLPHENOL
C435 B1S(2-CHLOROETHOXY)METH
C440 2,4-DICHLOROPHENOL
C430 BENZOIC ACID
AA-OIMETHYLPHENETHYLAMINE
C445 1,2,4-TRICHLOROBENZENE
C450 NAPHTHALENE
C455 4-CHLOROANALINE
2,6-DICHLOROPHENOL
HEXACHLOROPROPENE
C460 HEXACHLOROBUTADIENE
P-PHENYLENE D1AMINE
N-NITROSODl-N-BUTYLAMINE
C465 4-CHLORO-3-METHYLPHENO
SAFROLE
C470 2-METHYLNAPHTHALENE
1,2,4,5-TETRACHLOROBENZENE
ISOSAFROLE (#1)
C510 HEXACHLOROCYCLOPENTAOJ
C515 2,4,6-TRICHLOROPHENOL
C520 2,4,5-TRlCHLOROPHENOL
ISOSAFROLE (#2)
C525 2-CHLORONAPHTHALENE
1-CHLORONAPHTHALENE
C530 2-NITROANALINE
1,4-NAPHTHOQUINONE
C535 DIMETHYLPHTHALATE
1,3-OINITROBENZENE
C540 ACENAPHTHYLENE
C543 2,6-DINITROTOLUENE
C545 3-NITROANILINE
C550 ACENAPHTHENE
C555 2,4-DINlTROPHENOL
C565 DIBENZOFURAN
C560 4-NITROPHENOL
PENTACHLOROBENZENE
C570 2,4-DINITROTOLUENE
1-NAPHTHYLAMINE
2-NAPHTHYLAMINE
2,3,4,6-TETRACHLOROPHENOL
C580 OIETHYLPHTHALATE
C590 FLUORENE
Result
Units
Reporting
Limit
:==================================:
ND
NO
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
UG/A
30.0
30.0
30.0
30.0
30.0
150.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0
60.0
30.0
30.0
30.0
60.0
30.0
15.0
150.0
30.0
30.0
30.0
30.0
30.0
150.0
30.0
150.0
30.0
150.0
30.0
30.0
30.0
30.0
60.0
30.0
30.0
-------
QUANTERRA GC/MS
Target Compound Data Summary Sheet
Data File: 30068108
Std Id: ST16980831
Sample: S-MM5-FB 1/3SA/1ML INST. ID: F16
Client: PACIFI Date Analyzed: 08/31/98 22:29
Analyst: DAT Instrument ID: F16 Run Factor: 3.00
Quan List Threshold: 0.95 Surrogate Vol.: 1.00
Target Compounds: SAP9
Reporting
Parameter Scan Result Units Limit
C585 4-CHLOROPHENYL-PHENYLE ND UG/A 30.0
5-NITRO-O-TOLUIDINE ND UG/A 30.0
C595 4-N1TROANALINE ND UG/A 150.0
C610 4.6-DIN1TRO-2-METHYLPH ND UG/A 150.0
C615 N-NITROSODIPHENYLAMINE ND UG/A 30.0
C620 AZOBENZENE ND UG/A 30.0
SYM-TR1NITROBENZENE ND UG/A 30.0
C625 4-BROMOPHENYL-PHENYLET ND UG/A 30.0
PHENACET1N ND UG/A 30.0
DIALLATE 234 ND UG/A 30.0
C630 HEXACHLOROBENZENE ND UG/A 30.0
4-AMINOBIPHENYL ND UG/A 30.0
C635 PENTACHLOROPHENOL ND UG/A 150.0
PRONAMIDE ND UG/A 30.0
PENTACHLORONITR08ENZENE ND UG/A 150.0
C640 PHENANTHRENE ND UG/A 30.0
C645 ANTHRACENE ND UG/A 30.0
2SECBUTYL-4.6-DINITROPHENOL ND UG/A 30.0
C647 CARBAZOLE ND UG/A 30.0
C650 DI-N-BUTYLPHTHALATE ND UG/A 30.0
4-NITROQUINOLINE-1-OXIDE ND UG/A 30.0
METHAPYRILENE ND UG/A 30.0
ISODRIN ND UG/A 30.0
C655 FLUORANTHENE ND UG/A 30.0
CHLOROBENZILATE ND UG/A 30.0
C710 BENZIDINE ND UG/A 300.0
C715 PYRENE ND UG/A 30.0
ARAMITE (#1) ND UG/A 30.0
ARAMITE (#2) ND UG/A 30.0
P-DIMETHYLAMINOAZOBENZENE ND UG/A 30.0
3,3'-DIMETHYLBENZIDINE ND UG/A 30.0
KEPONE ND UG/A 150.0
C720 BUTYLBENZYLPHTHALATE ND UG/A 30.0
2-ACETYLAMINOFLUORENE ND UG/A 30.0
C730 BENZO(A)ANTHRACENE ND UG/A 30.0
C725 3,3'-DICHLOROBENZIDINE ND UG/A 60.0
C740 CHRYSENE ND UG/A 30.0
C745 BIS(2-ETHYLHEXYL)PHTHA ND UG/A 30.0
3-METHYLCHOLANTHRENE ND UG/A 30.0
C760 DI-N-OCTYL PHTHALATE ND UG/A 30.0
C765 BENZO(B)FLUORANTHENE ND UG/A 30.0
7,12-DIMETHYLBENZANTHRACENE ND UG/A 30.0
C770 BENZOCK)FLUORANTHENE ND UG/A 30.0
HEXACHLOROPHENE ND UG/A 30.0
11,
-------
QUANTERRA GC/MS
Target Compound Data Summary Sheet
Sample: S-MM5-FB
Client: PAC1FI
Analyst: DAT
1/3SA/1ML
INST. ID:
Instrument ID: F16
Quan List Threshold: 0.95
Data File: 30068108
Std Id: ST16980831
F16
Date Analyzed: 08/31/98 22:29
Run Factor: 3.00
Surrogate Vol.: 1.00
Target Compounds: SAP9
Parameter
Scan
C775 BENZO(A)PYRENE
C780 INDENO(1,2,3-CD)PYRENE
C785 DIBENZ(A,H)ANTHRACENE
C790 BENZO(G,H,I)PERYLENE
Result
========
ND
ND
ND
ND
Units
======
UG/A
UG/A
UG/A
UG/A
Reporting
Limit
s~s==
30.0
30.0
30.0
30.0
IE;
-------
DATA FROM FILE: 30068188 SCANS 93 TO 1203 ACQUIRED: 88/31/98 22:29:88
CALI: 30868188 #3
SAMPLE: S-MM5-FB 1/3SA/1ML INST. ID: F16
CONDS.: UG/ML *1ML *188Z/188Z *
-------
DATA FROM FILE: 30068108 SCANS 1203 TO 2158 ACQUIRED: 08x31/98 22:29:00
CALI: 30068108 ซ3
SAMPLE: S-MM5-FB ixSSAxlML INST. ID: F16
COHDS.: UGXML *1ML * 100Zxl 007. *
-------
STANDARD USED FOR THIS REPORT IS ST16980831 REPORT PRINTED: 9/01/98 22:17:16
ADDITIONAL STANDARD USED FOR THIS REPORT IS: ST16980831A
OUANTERRA QUANTITATION SUMMARY File: 30068108
Sample: S-MM5-FB 1/3SA/1ML INST. ID: F16
Analyst: DAT Instrument Id
Compounds with amounts less than 0.20
Library
No Entry Name Mass
1 S1# 1 CI30 1,4-DlCHLOROBENZENE 152
2 S2# 1 C140 NAPHTHALENE-OS 136
3 S3# 1 CI50 ACENAPHTHENE-D10 164
4 S4# 1 CI60 PHENANTHRENE-D10 188
5 S5# 1 CI70 CHRYSENE-D12 240
6 S6# 1 CI75 PERYLENE-D12 264
7 S2# 2 CS20 NITROBENZENE-DS 82
8 S3# 3 CS25 2-FLUOROBIPHENYL 172
9 S5# 2 CS30 TERPHENYL-D14 244
10 S1# 3 CS45 PHENOL-D5 99
11 S1# 2 CS50 2-FLUOROPHENOL 112
12 S3# 2 CS55 2,4,6-TRlBROMOPHENO 330
13 S4# 4 HEXACHLOROBENZENE-C13 294
14 S1# 15 C310 N-NITROSODIMETHYLAM 74
15 SDK 20 PYRIDINE 79
16 S1# 30 2-PICOLINE 93
17 S1# 40 N-NITROSOMETHYLETHYLAMIN 42
18 S1# 60 METHYLMETHANESULFONATE 80
19 S1# 70 N-NITROSOOIETHYLAMINE 102
20 S1# 85 ETHYLMETHANE SULFONATE 79
21 S1# 95 PENTACHLOROETHANE 117
22 S1#100 C320 ANILINE 93
23 S1#105 C315 PHENOL 94
24 S1#110 C325 BIS(2-CHLOROETHYL)E 93
25 S1#115 C330 2-CHLOROPHENOL 128
26 S1#125 C335 1 ,3-DICHLOROBENZENE 146
27 S1#130 C340 1 ,4-DICHLOROBENZENE 146
28 S1#145 C345 BENZYL ALCOHOL 108
29 S1#150 C350 1 ,2-DICHLOROBENZENE 146
30 S1#160 C355 2-METHYLPHENOL 108
31 S1#165 C360 2,2'-OXYBIS(1-CLPRO 45
32 S1#170 C361 ACETOPHENONE 105
33 S1#175 N-NITROSOPYRROLIDINE 100
34 SHป180 N-NITROSOMORPHOLINE 56
35 S1#182 3-METHYL PHENOL 108
36 S1#185 C365 4-METHYLPHENOL 108
37 S1#190 C370 N-NITROSO-DI-N-PROP 70
38 S1#195 0-TOLUIDINE 106
39 S1#200 C375 HEXACHLOROETHANE 117
40 S2# 10 C410 NITROBENZENE 77
41 S2# 15 N-NITROSOPIPERIDINE 42
42 S2# 20 C415 ISOPHORONE 82
43 S2# 25 C420 2-NITROPHENOL 139
44 S2# 30 C425 2,4-DIMETHYLPHENOL 107
45 S2# 35 C435 BIS(2-CHLOROETHOXY) 93
: F16 Analyzed:
reported as NOT FOUND
Meth Scan Ref Area
A BB 340 1 36214.
A BB 529 2 139245.
A BB 827 3 74547.
A BB 1086 4 121683.
A BB 1551 5 65622.
A BV 1782 6 53016.
A BB 421 2 47363.
A BB 722 3 90468.
A BB 1383 5 82729.
A BB 308 1 107781.
A BB 198 1 66619.
A BB 968 3 32579.
4 NOT FOUND
1 NOT FOUND
1 NOT FOUND
1 NOT FOUND
AW 159 1 5080.
1 NOT FOUND
1 NOT FOUND
1 NOT FOUND
1 NOT FOUND
1 NOT FOUND
A BB 309 1 604.
1 NOT FOUND
1 NOT FOUND
1 NOT FOUND
1 NOT FOUND
A BB 370 1 2842.
1 NOT FOUND
1 NOT FOUND
1 NOT FOUND
1 NOT FOUND
1 NOT FOUND
1 NOT FOUND
1 NOT FOUND
1 NOT FOUND
1 NOT FOUND
1 NOT FOUND
1 NOT FOUND
2 NOT FOUND
2 NOT FOUND
2 NOT FOUND
2 NOT FOUND
2 NOT FOUND
2 NOT FOUND
08/31/98 22:29
Units: UG/ML
RRF(L) Amount
1.000 40.000
1.000 40.000
1.000 40.000
1.000 40.000
1.000 40.000
1.000 40.000
0.470 28.975
1.234 39.328
0.995 50.670
2.025 58.774
1.368 53.779
0.236 74.180
0.811 6.918
1.968 0.339
0.854 3.674
-------
46 S2# 40 C440 2,4-DICHLOROPHENOL 162 2 NOT FOUND
47 S2# 45 C430 BENZOIC ACID 122 2 NOT FOUND
48 S2# 50 AA-DIHETHYLPHENETHYLAHIN 58 2 NOT FOUND
49 S2# 55 C445 1,2,4-TRICHLOROBENZ 180 2 NOT FOUND
-------
50 S2# 60 C450 NAPHTHALENE
51 S2# 80 C455 4-CHLOROANALINE
52 S2# 85 2,6-DICHLOROPHENOL
53 S2# 90 HEXACHLOROPROPENE
54 S2# 95 C460 HEXACHLOROBUTADIENE
55 S2#115 P-PHENYLENE DIAMINE
56 S2#120 N-NITROSODI-N-BUTYLAMINE
57 S2#130 C465 4-CHLORO-3-HETHYLPH
58 S2#140 SAFROLE
59 S2#145 C470 2-METHYLNAPHTHALENE
60 S3# 10 1,2,4,5-TETRACHLOROBENZE
61 S3# 15 ISOSAFROLE (#1)
62 S3# 20 C510 HEXACHLOROCYCLOPENT
63 S3# 25 C515 2,4,6-TRICHLOROPHEN
64 S3# 30 C520 2,4,5-TRICHLOROPHEN
65 S3# 35 ISOSAFROLE (#2)
66 S3# 40 C525 2-CHLORONAPHTHALENE
67 S3# 42 1-CHLORONAPHTHALEN
68 S3# 45 C530 2-NITROANALINE
69 S3# 50 1,4-NAPHTHOQUINONE
70 S3# 55 C535 DIMETHYLPHTHALATE
71 S3# 60 1,3-DINlTROBENZENE
72 S3# 65 C540 ACENAPHTHYLENE
73 S3# 70 C543 2,6-DINITROTOLUENE
74 S3# 75 C545 3-N1TROANILINE
75 S3# 80 C550 ACENAPHTHENE
76 S3# 85 C555 2,4-DINITROPHENOL
77 S3# 90 C565 DIBENZOFURAN
78 S3* 95 C560 4-NITROPHENOL
79 S3#100 PENTACHLOROBENZENE
80 S3#105 C570 2,4-DINITROTOLUENE
81 S3#110 1-NAPHTHYLAMINE
82 S38115 2-NAPHTHYLAM1NE
83 S3#120 2,3,4,6-TETRACHLOROPHENO
84 S3#130 C580 DIETHYLPHTHALATE
85 S3#135 C590 FLUORENE
86 S3#140 C585 4-CHLOROPHENYL-PHEN
87 S3#145 5-NITRO-0-TOLU1DINE
88 S3#150 C595 4-NITROANALINE
89 S4# 10 C610 4,6-DINITRO-2-METHY
90 S4# 15 C615 N-NITROSOOIPHENYLAM
91 S4# 20 C620 AZOBENZENE
92 S4# 25 SYM-TRtNITROBENZENE
93 S4# 30 C625 4-BROMOPHENYL-PHENY
94 S4# 35 PHENACETIN
95 S4# 37 DIALLATE
96 S4# 40 C630 HEXACHLOROBENZENE
97 S4# 45 4-AMINOBIPHENYL
98 S4# 50 C635 PENTACHLOROPHENOL
99 S4# 55 PRONAMIDE
100 S4# 60 PENTACHLORONITROBENZENE
101 S4# 65 C640 PHENANTHRENE
102 S4# 70 C645 ANTHRACENE
103 S4# 75 2SECBUTYL-4.6-DINITROPHE
104 S4# 80 C647 CAR8AZOLE
105 S4# 85 C650 DI-N-BUTYLPHTHALATE
106 S4#100 4-NITROQUINOLINE-1-OXIDE
107 S4#105 METHAPYRILENE
108 S4#106 ISOOR1N
109 S4#110 C655 FLUORANTHENE
110 S4#120 CHLOROBENZILATE
128
127
162
213
225
108
8A
107
162
142
214
162
237
196
196
104
162
162
65 A VB
158
163
168
152
165 A SB
138
153
184
168
109
250
165 A BB
143
143
232
149 A VB
166
204
152 A VB
138 A BB
198
169
77 A BB
75
248
108 A W
234
284
169
266
173
237
178 A BB
178
211
167
149 A BB
190 A BB
58 A BB
193
202
139
2 NOT FOUND
2 NOT FOUND
2 NOT FOUND
2 NOT FOUND
2 NOT FOUND
2 NOT FOUND
2 NOT FOUND
2 NOT FOUND
2 NOT FOUND
2 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
761 3 298. 0.502
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
814 3 460. 0.324
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
879 3 222. 0.397
3 NOT FOUND
3 NOT FOUND
3 NOT FOUND
931 3 1395. 1.369
3 NOT FOUND
3 NOT FOUND
939 3 208. 0.356
948 3 118. 0.307
4 NOT FOUND
4 NOT FOUND
966 4 1071. 1.171
4 NOT FOUND
4 NOT FOUND
1035 4 320. 0.317
4 NOT FOUND
4 NOT FOUND
4 NOT FOUND
4 NOT FOUND
4 NOT FOUND
4 NOT FOUND
1089 4 1753. 1.033
4 NOT FOUND
4 NOT FOUND
4 NOT FOUND
1226 4 4322. 1.247
1237 4 272. 0.073
1263 4 803. 0.305
4 NOT FOUND
4 NOT FOUND
4 NOT FOUND
0.319
0.762
0.300
0.547
0.314
0.206
0.301
0.332
0.558
1.140
1.233
0.867
US!
-------
111 S5# 10 C710 BENZID1NE 184 5 NOT FOUND
112 S5# 15 C715 PYRENE 202 5 NOT FOUND
113 S5# 20 ARAMITE (#1) 185 5 NOT FOUND
114 S5# 25 ARAMITE (#2) 185 5 NOT FOUND
115 S5# 30 P-DIMETHYLAMINOAZOBENZEN 120 5 NOT FOUND
116 S5# 35 3,3'-DlMETHYLBENZIDINE 212 5 NOT FOUND
117 S5# 37 KEPONE 272 5 NOT FOUND
118 S5# 40 C720 BUTYLBENZYLPHTHALAT 149 5 NOT FOUND
119 S5# 45 2-ACETYLAMINOFLUORENE 181 A W 1516 5 330.
120 S5# 50 C730 BENZO(A)ANTHRACENE 228 A BB 1551 5 574.
121 S5# 55 C725 3,3'-DICHLOROBENZID 252
122 S5# 60 C740 CHRYSENE 228
123 S5# 65 C745 B1S(2-ETHYLHEXYL)PH 149 A BB
124 S5# 85 3-METHYLCHOLANTHRENE 268 5 NOT FOUND
125 S6# 10 C760 DI-N-OCTYL PHTHALAT 149 6 NOT FOUND
126 S6# 15 C765 BENZO(B)FLUORANTHEN 252 6 NOT FOUND
127 S6# 20 7,12-DIMETHYLBENZANTHRAC 256 6 NOT FOUND
128 S6# 25 C770 BENZO(IOFLUORANTHEN 252 6 NOT FOUND
129 S6# 30 HEXACHLOROPHENE 196 6 NOT FOUND
130 S6# 35 C775 BENZO(A)PYRENE 252 6 NOT FOUND
131 S6# 55 C780 INDENO(1,2,3-CD)PYR 276 6 NOT FOUND
132 S6# 60 C785 DIBENZ(A.H)ANTHRACE 278 6 NOT FOUND
133 S6# 65 C790 BENZO(G,H(I)PERYLEN 276 6 NOT FOUND
5 NOT FOUND
5 NOT FOUND
1603 5 9579.
0.432
1.125
0.980
0.465
0.311
5.959
1192
-------
BNA, S LIBRARIES ANALYST: DATE:
QUANTERRA Internal Standard Check
Standard Filename: ST16980831 Analyzed: 08/31/98 12:31
| IS* 1 | IS* 2 | IS* 3
Standard j Area % | RT j Area % | RT j Area % | RT
ST16980831 | 28649. | 3.78 | 100432. | 5.90 | 54347. | 9.21
Upper Limit j 57297.=+200| 4.28 j 200864.=+200j 6.40 j 108695.=+200j 9.71
Lower Limit j 14324.=+ 50| 3.28 | 50216.=+ 50| 5.40 j 27174.=+ 50| 8.71
Filename I II II I
I II II I
1 30068108 | 36214.= 126| 3.78 | 139245.= 138| 5.88 | 74547.= 137| 9.20
IS* 1 = CI30 1.4-DICHLOROBENZENE-D4
IS* 2 = CI40 NAPHTHALENE-08
IS* 3 = CI50 ACENAPHTHENE-D10
* - indicates an I.S. is outside QC limit(s)
| IS* 4 | IS* 5 | IS* 6
Standard j Area % | RT j Area % | RT j Area % | RT
ST16980831 | 98520. (12.08 | 62289. |17.26 | 50750. |19.83
Upper Limit j 1 97039. =+200 j 12. 58 j 124578. =+200| 17.76 j 101500. =+200|20. 33
Lower Limit | 49260.=+ 50J11.58 j 31145.=+ 50J16.76 | 25375.=+ 50J19.33
Filename | | |
1 30068108 | 121683.= 123|12.08 | 65622.= 105|17.25 | 53016.= 104|19.82
IS* 4 = CI60 PHENANTHRENE-D10
IS# 5 = CI70 CHRYSENE-D12
IS* 6 = C175 PERYLENE-D12
* - indicates an I.S. is outside QC limit(s)
1 "ป<
JLJL.
-------
Data Reduced by:1
Data Reviewed by:
Data File: 30068108
QUANTERRA GC/MS TIC REPORT ( Part 1 )
Sample: S-MM5-FB 1/3SA/1HL INST. ID: F16
Analyst: DAT Date Analyzed: 08/31/98 22:29
Run Factor: 3.00
Concentration
in Sample
# SCAN (UG/A) CAS #
170 \~ ' 380. 123-42-2
'2-PENTANONE, 4-HYDROXY-4-METHYL-
2 222 360.
3 285 29.
BENZALDEHYDE ซ*"
\
^C?32 22.
'
^985 20.
NONADECANE C?"^ vS 6
6 1033 52.
HEPTADECANE, 2,6-DIMETHYL
S~
7 vm 24.
XNONADECANE
8 1235 33.
HEXADECANOIC ACID
9 1334 51. ,
^.1361 20.
UNKNOWN
111-84-2
100-52-7
rc?381-*e-1 __
\ ^N/VAAL<>\n(\-^^ SrVtD
629-92-5
r 0~S
105-67-8
629-92-5
57-10-3
J
.- 5T M.UHOC
C^ljf-^^^-^-- -
oo-oo-o C'2^/33b
1S4
-------
11 KOI 31.
TRICOSANE & ^ V
638-67-5
12 1467 30.
TBlCOSAMf
1501
UNKNOWN
24. 00-00-0
14 1509 36.
UNKNOWN
00-00-0
15 1529
MOHADCCAMC
45.
<
16 1588 150.
5-EICOSENE, (E)-
17 1661 49.
UNKNOWN
74685-30-6
00-00-0
18 1688 34. 00-00-0
UNKNOWN
19 1703 26.
20 1741 57.
UNKNOWN
21 1809
UNKNOWN
?2 1917 58.
4-TE'IHAUELANUL
00-00-0
77. 00-00-0
Jx
S
: JL V^'
-------
23 1934 42.
UNKNOWN
24 2016 30.
25 2052
UNKNOWN
00-00-0
27. 00-00-0
-i -i-
-------
DATA FILE: 30068108
QUANTERRA GC/MS TIC REPORT ( Part 2 )
CONCENTRATION = AREA(TIC)*CONC(1S)/AREA(IS)
#
1
2
3
4
5
6
7
8
9
10
11
12
13
H
15
16
17
18
19
20
21
22
23
24
25
FIT
955
986
967
915
926
939
955
977
892
664
903
900
696
816
955
975
800
687
941
895
904
966
722
927
839
PURITY
916
935
923
728
763
746
779
722
621
194
624
695
200
451
643
742
345
232
723
502
537
729
399
696
412
INT.
STD.
1
1
1
2
3
3
3
3
4
4
4
4
4
4
4
4
4
5
5
5
5
5
5
5
5
AMOUNT
AS ANALYZED
RT
1:53
2:28
3:10
10:21
10:57
11:29
12:24
13:44
14:50
15:08
15:34
16:19
16:41
16:47
17:00
17:39
18:28
18:46
18:56
19:21
20:07
21:19
21:30
22:25
22:49
RRT
0.321
0.420
0.539
1.127
0.907
0.951
1.028
1.137
0.860
0.877
0.903
0.946
0.968
0.973
0.986
1.024
1.071
0.947
0.956
0.977
1.015
1.076
1.085
1.131
1.152
AREA
906380.
859436.
69204.
63056.
58112.
152832.
72432.
97728.
92576.
36800.
56608.
54816.
43920.
64912.
80832.
263344.
88976.
49792.
37936.
83508.
112176.
85264.
61840.
44000.
39200.
HEIGHT
388608.
372736.
17724.
21101.
13152.
27072.
21408.
22656.
15968.
6272.
12576.
11600.
7152.
9296.
15072.
45632.
7792.
4368.
6944.
23117.
10848.
16481.
5968.
6658.
3904.
(UG/ML )
126
120
9
7
6
17
8
11
17
6
10
10
8
11
14
48
16
11
8
19
25
19
14
10
8
.768
.203
.679
.252
.546
.215
.159
.008
.096
.796
.454
.123
.111
.987
.927
.631
.431
.377
.668
.081
.631
.482
.130
.053
.957
LIB
NB
NB
NB
NB
NB
NB
NB
NB
NB
UK
NB
NB
UK
UK
NB
NB
UK
UK
NB
UK
UK
NB
UK
NB
UK
LIB #
3241.
5159.
2017.
40501 .
37465.
37462.
37465 .
35182.
37462.
1.
46161.
46161 .
1.
1.
37465.
39516.
1.
1.
37465.
1.
1.
26416.
1.
34410.
1.
-, c ="7
t
-------
Library Search Data: 30068108 # 170 Base m/z: 43
08/31/9822:29:00+ 1:53 Cati: 30068108 # 3 R1C: 278528.
Sample: S-MM5-FB 1/3SA/1ML INST. ID: F16
Conds.: UG/ML *1ML *100%/100% ซ(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
630 matched at least 6 of the 16 largest peaks in the unknown
Rank In. Name
1 3241 2-PENTANONE, 4-HYDROXY-4-METHYL-
2 5791 1,3-DIOXOLANE-2-METHANOL, 2,4-DIHEfHYL-
3 3366 2-PENTANOt. 2,4-DIMETHYL-
4 3288 ACETIC ACID, 1, 1-DIMETHYLETHYL ESTER
5 5594 2-PROPANOL, 2-NITROSO-, ACETATE (ESTER)
6 919 TERT-BUTYL HYDROPEROXIDE
7 3349 2-HEXANOL, 2-METHYL-
8 8432 2-HEXANONE, 3-HYDROXY-3.5-DIMETHYL-
9 8425 2-HEPTANONE, 3-HYDROXY-3-METHYL-
Rank
1
2
3
4
5
6
7
8
9
Rank
1
2
3
4
5
6
7
8
9
Formula
C6.H12.02
C6.H12.03
C7.H16.0
C6.H12.02
C5.H9.03.N
C4.H10.02
C7.H16.0
C8.H16.02
C8.H16.02
Ret. Time B.P.Int.
M.Ut
116
132
116
116
131
90
116
144
144
B.Pk
43
43
59
43
43
59
59
59
59
US. Par. 1 US. Par
Purity Fit
916 955
749 823
741 764
725 774
718 821
705 856
704 738
662 725
659 715
.2 C.A.S. #
123-42-2
53951-43-2
625-06-9
540-88-5
6931-04-0
75-91-2
625-23-0
6321-14-8
13757-91-0
RFit
929
793
741
739
810
727
704
688
675
1]
'ป C:
G
-------
MID LIBRARY SEARCH DATA: 30068108 # 170 BASE M/Z: 43
88/31/98 22:29:00 + 1:53 CALI: 30068108 # 3 RIC: 278528.
SAMPLE: S-MM5-FB 1/3SA/1ML INST. ID: F16
CONDS.: UG/ML *1ML * 100Z/1 002 *
1000 1
SAMPLE
C6.H12.02
1000 -I
M WT 116
B PK 43
RANK 1
# 3241 '
PUR 916
C6.H12.03
1000 I
M WT 132
B PK 43
RANK 2
# 5791
PUR 749
C7.H16.0
1000 I
M WT 116
B PK 59
RANK 3
* 3366
PUR 741
M/Z
r
,,i
oo*
2-PENTANONE, 4-HYDROXY-4-METHYL-
r
Ml i l|
n
. i i_l '. i . .
1 , 3-DIOXOLANE-2-METHANOL, 2, 4-DIMETHYL-
r
,|i 1 . 1,
i i
2-PENTANOL , 2,4-DIMETHYL-
r
1,1 i 1
..i.
20 40 60 80 100 120 140 160 180 200
CO
CO
-------
Library Search Data: 30068108 # 222 Base m/z: 43
08/31/98 22:29:00 + 2:28 Cali: 30068108 # 3 RIC: 253952.
Sample: S-MM5-FB 1/3SA/1HL INST. ID: F16
Conds.: UG/ML *1ML *100%/100% *(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
921 matched at least 7 of the 16 largest peaks in the unknown
Rank In.
Name
1 5159 NONANE
2 5151 HEPTANE, 3,4-DIMETHYL-
3 3086 HEXANE, 2,4-DIMETHYL-
4 5141 HEPTANE, 2,4-DIMETHYL-
5 19015 DECANE, 2,5,6-TRIMETHYL-
6 8085 HEPTANE, 2,4,6-TRIMETHYL-
7 5144 HEPTANE, 4-ETHYL-
8 11607 UNDECANE
9 3081 OCTANE
Rank
1
2
3
4
5
6
7
8
9
Formula
C9.H20
C9.H20
C8.H18
C9.H20
C13.H28
C10.H22
C9.H20
C11.H24
C8.H18
Rank
1
2
3
4
5
6
7
8
9
M.Wt
128
128
114
128
184
142
128
156
114
B.Pk
43
43
43
43
57
43
43
43
43
Purity
935
897
887
885
868
864
863
859
857
Fit
986
926
963
938
910
909
914
921
935
RFit
935
897
898
890
887
879
871
908
878
Ret.Time
B.P.Int.
US.Par.1
US.Par.2
C.A.S
111
922
589
2213-
62108
2613-
2216-
1120-
111-
#
84-2
28-1
43-5
23-2
23-0
61-8
32-2
21-4
65-9
120
-------
MID LIBRARY SEARCH DATA: 30068108 # 222 BASE M/Z: 43
08/31/98 22:29:00 + 2:28 CALI: 30068108 # 3 RIC: 253952.
SAMPLE: S-MM5-FB 1/3SA/1ML INST. ID: F16
CONDS.: UG/ML *1ML *100Z/100Z *
1000 -
SAMPLE
C9.H20
1000 1
M WT 128
B PK 43
RANK 1
# 5159
PUR 935
C9.H20
1000 1
M WT 128
B PK 43
RANK 2
# 5151
PUR 897
C8.H18
1000 i
M WT 114
B PK 43
RANK 3
ft 3086
PUR 887
M/Z
r
r
r
r
S
*<
'^T
NONANE
\ 1 .1 1 -
HEPTANE, 3,4-DIMETHYL-
i 1 1 1 J L_J . 1 1
HEXANE, 2,4-DIMETHYL-
.1 1 .
40 60 80 100 120
JO
O
-------
Library Search
08/31/98 22:29:00 <
Sample: S-MM5-FB
Conds.: UG/ML *1ML
Data: 3006S108 # 285
3:10 Cali: 30068108 # 3
1/3SA/1ML 1NST. ID: F16
*100%/100% *(NA/NA )/1/3SA NA M
Base m/z: 77
R1C: 13744.
Enhanced (S 15B 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
366 matched at least 5 of the 16 largest peaks in the unknown
Rank In.
Name
1 2017 BENZALDEHYDE
2 7284 BENZOYL CHLORIDE
3 6466 ETHANONE, 2-HYDROXY-1-PHENYL-
4 2014 2.4-HEPTADIEN-6-YNAL, (E,E)-
5 9645 BENZOYLFORMIC ACID
6 13112 BENZOYL ISOTHIOCYANATE
7 6857 BENZENECARBOTHIOIC ACID
8 13359 BENZENEACETIC ACID, .ALPHA.-0X0-
9 6111 1,2-BENZENEDICARBOXALDEHYDE
METHYL ESTER
Rank Formula
1
2
3
4
5
6
7
8
9
C7.H6.0
C7.H5.0.CL
C8.H8.02
C7.H6.0
C8.H6.03
C8.H5.0.N.S
C7.H6.0.S
C9.H8.03
C8.H6.02
H.Wt
106
140
136
106
150
163
138
164
134
B.Pk
77
105
105
105
105
105
77
105
105
Purity
923
817
806
805
779
773
763
759
758
Fit
967
874
842
846
846
820
845
832
807
RFit
944
830
822
810
804
788
810
787
915
Rank
1
2
3
i,
5
6
7
8
9
Ret.Time
B.P.Int.
US.Par.1
US.Par.2
C.A.S
100
98
582
7200
611
532
98
15206
643
. #
52-7
88-4
24-1
04-6
73-4
55-8
91-9
55-0
79-8
-------
ARCH
DATA:
. INST. ID=
CONDS.: UG/ML *1ML * 100^/1 00?? *
30068108 ft 285
' 3
BASE M/Z: 77
NA M
1517
SAMPLE
C7.H6.0
1517 -
M WT 106
B PK 77
RANK 1
ft 2017
PUR 923
C7.H5.0.CI
1517
SWT 140
PK 105
RANK 2
ft 7284
PUR 817
C8.H8.02
1517 T
M WT 136
B PK 105
RANK 3
ft 6466 '
PUR 806
M/Z
r
,\
s
ll. . . ...
1.
/
BENZALDEHYDE
-------
Library Search
08/31/98 22:29:00 + 10:22
Sample: S-MM5-FB 1/3SA/1ML
Conds.: UG/ML *1ML *100%/100%
Enhanced (S 15B 2N OT)
Data: 30068108 # 932
Cali: 30068108 # 3
INST. ID: F16
*(NA/NA )/1/3SA NA M
Base m/z: 71
RIC: 18880.
62231 spectra in LIBRARYNB searched for maximum PURITY
540 matched at least 6 of the 16 largest peaks in the unknown
Rank In. Name
1 40501 PROPANOIC ACID, 2-METHYL-, 1-(1,1-DIMETHYLETHYL)-2-METHYL-1,3-PROPA*
2 40500 PROPANOIC ACID, 2-METHYL-, 2-ETHYL-1-PROPYL-1,3-PROPANEDIYL ESTER
3 26739 PROPANOIC ACID, 2-METHYL-, 2,2-DIMETHYL-1-(2-HYDROXY-1-METHYLETHYL)*
4 26740 PROPANOIC ACID, 2-METHYL-, 3-HYDROXY-2,4,4-TRIMETHYLPENTYL ESTER
5 4625 1-HEXENE, 3,4,5-TRIHETHYL-
6 2720 4.4-DIMETHYL-1-HEXENE
7 4556 ETHANONE, 1-(3-ETHYLCYCLOBUTYL)-
8 4677 2,4,4-TRIMETHYL-1-HEXENE
9 26737 PROPANOIC ACID, 2-METHYL-, 2-ETHYL-3-HYDROXYHEXYL ESTER
M.Wt B.Pk Purity Fit RFit
Rank
1
2
3
4
5
6
7
8
9
Formula
C16.H30.04
C16.H30.04
C12.H24.03
C12.H24.03
C9.H18
C8.H16
C8.H14.0
C9.H18
C12.H24.03
286
286
216
216
126
112
126
126
216
71
43
71
71
43
71
43
71
71
728
676
675
626
557
552
546
527
514
915
875
888
800
798
788
735
721
694
748
712
693
631
652
617
625
637
538
Rank
1
2
3
4
5
6
7
8
9
Ret.Time
B.P.lnt.
US.Par.1
US.Par.2
C.A.S.
74381
74367-
74367-
74367-
56728
1647
56335
51174
74367
#
40-1
30-9
33-2
34-3
-10-0
08-1
71-8
12-0
31-0
12C4
-------
CM
1184
SAMPLE
MID LIBRARY SEARCH (LIBRARYNB) DATA:
08/31/98 22:29:08 + 10:22 CALI:
SAMPLE: S-MM5-FB 1/3SA/1ML INST. ID: F16
CONDS.: UG/ML *1ML *100Z/ 100Z *PR!
M/H
50
100
150
200
-------
Library Search Data: 30068108 # 985 Base m/z: 57
08/31/9822:29:00+10:57 Cali: 30068108 # 3 RIC: 12368.
Sample: S-MM5-FB 1/3SA/1HL INST. ID: F16
Conds.: UG/ML *1ML *100%/100X *(NA/NA )/1/3SA NA M
Enhanced (S 158 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
548 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 37465 NONADECANE
2 22527 DOOECANE, 2,5-DlMETHYL-
3 22530 TETRADECANE
4 29264 TRIDECANE, 5-PROPYL-
5 25997 PENTADECANE
6 29263 HEXADECANE
7 32059 HEPTADECANE
8 37462 HEPTADECANE, 2,6-DIMETHYL-
9 19054 UNDECANE, 2,6-DIMETHYL-
Rank
1
2
3
4
5
6
7
8
9
Formula
C19.H40
C14.H30
C14.H30
C16.H34
C15.H32
C16.H34
C17.H36
C19.H40
C13.H28
M.Ut
268
198
198
226
212
226
240
268
184
B.Pk
57
57
43
57
57
57
57
57
57
Purity
763
754
752
750
750
749
749
747
740
Fit
926
934
933
977
934
916
915
936
943
RFit
787
759
759
757
775
793
787
763
746
Rank
1
2
3
4
5
6
7
8
9
Ret.Time
B.P.lnt.
US.Par.1
US.Par.2
C.A.S,
629-
56292-
629-
55045-
629-
544-
629'
54105
17301-
#
92-5
65-0
59-4
11-9
62-9
76-3
78-7
67-8
23-4
12CG
-------
1134
SAMPLE
MID LIBRARY SEARCH DATA:
08/31/98 22:29:00 + 10:57 CALI:
SAMPLE: S-MM5-FB 1/3SA/1ML INST. ID: F16
CONDS.: UG/ML *1ML *100Z/100Z *
30068108 # 985
30068108 # 3
BASE M/Z: 57
RIC: 12368.
erf
C19.H40
1134
M WT 268
B PK 57
RANK 1
# 37465
PUR 763
C14.H39
1134
M WT 198
B PK 57
RANK 2
# 22527
PUR 754
C14.H30
1134
M WT 198
B PK 43
RANK 3
# 22530
PUR 752
M/Z
NONADECANE
..I
DODECANE, 2,5-DIMETHYL-
TETRADECANE
II
50
100
150
200
250
300
O
vl
-------
Library Search Data: 30068108 #1033 Base m/z: 57
08/31/9822:29:00+11:29 Cali: 30068108 # 3 RIC: 23872.
Sample: S-MM5-FB 1/3SA/1ML INST. ID: F16
Conds.: UG/ML *1ML *100%/100% *(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
450 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 37462 HEPTADECANE,
2 42196 HEPTADECANE,
3 29253 PENTADECANE,
4 32058 HEXADECANE,
5 37466 PENTADECANE,
6 37465 NONADECANE
7 25991 DODECANE, 2,
8 22535 DODECANE, 4,
9 42192 HEPTADECANE,
Rank Formula
1 C19.H40
2 C21.H44
3 C16.H34
4 C17.H36
5 C19.H40
6 C19.H40
7 C15.H32
8 C14.H30
9 C21.H44
Rank Ret. Time
1
2
3
4
5
6
7
8
9
2.6-D1METHYL-
2,6,10,14-TETRAMETHYL-
2-METHYL-
3-METHYL-
2,6,10,14-TETRAMETHYL-
6,10-TRIMETHYL-
6-DIMETHYL-
2,6,10,15-TETRAMETHYL-
M.Wt
268
296
226
240
268
268
212
198
296
8. P. Int. US. Par. 1
B.Pk
57
57
43
57
71
57
57
57
57
US. Par
Purity Fit
746 939
727 932
702 925
701 932
697 933
697 930
692 950
690 952
687 915
.2 C.A.S. *
54105-67-8
18344-37-1
1560-93-6
6418-43-5
1921-70-6
629-92-5
3891-98-3
61141-72-8
54833-48-6
RFit
758
744
723
714
721
730
696
690
720
12CS
-------
1175
SAMPLE
MID LIBRARY SEARCH
08/31/98 22:29:00 + 11:29
SAMPLE: S-MM5-FB 1/3SA/1ML INST. ID:
CONDS.: UG/ML *1ML *1007./1007. */l/3SA
ENHANCED
DATA:
CALI:
30068108 #1033
30068108 # 3
BASE M/Z: 57
RIC: 23872.
F16
NA M
. III.
C19.H40
1175
M WT 268
B PK 57
RANK 1
# 37462
PUR 746
C21.H44
1175
M WT 296
B PK 57
RANK 2
# 42196
PUR 727
C16.H34
1175
M WT 226
B PK 43
RANK 3
# 29253
PUR 702
M/Z
HEPTADECANE, 2,6-DIMETHYL-
,
HEPTADECANE, 2,6, 10, 14-TETRAMETHYL-
^L
Tp-"r
PENTADECANE, 2-METHYL-
50
100
150
200
250
cn
-------
Library Search Data: 30068108 #1116
08/31/98 22:29:00 + 2:25 Cali: 3006)
Sample: S-MH5-FBg'
Conds.: UG/ML *1ML '
Enhanced (S 15B 2N (
62231 spectra in Lll
848 matched at lei
Rank In. Name
1 37465 NONADECANE
2 37462 HEPTADECANE1
3 42196 HEPTADECAJJE
4 32059 HEPTADEC/ffi-
5 29263 HEXADECANE
6 25991 DOOECANE, 2,
7 37466 PENTADECANE
8 42192 HEPTADECANE.
9 25997 PENTADECANE
Rank Formula
1 C19.H40
2 C19.H40
3 C21.H44 ^
4 C17.H36 oi-
5 C16.H34 ฎ
6 C15.H32
7 C19.H40
8 C21.H44
9 C15.H32
Rank Ret. Time
1
Is)
N)
UI
O
3SA/1HL INSr
Iflfl3fr/100% *(NA/NA )/
BARYNB searched for i
t 7 of the 16 large
m
-0
^
2,6-DIMETHYL- g
2,6,10,14-TETRAM^J)
Z
m
6.10-TRIMETHYL- " .
2,6,10,14-TETRAMirV
2,6,10.15-TETRAMffH;
O
* i
m
i
3>
m-
i
-c
i
B.P.Int. US. Par. 1
08 # 3
ID: F16
*3SA NA M
ax i mum PURIT
peaks in t
.-
-
.
Wt B.Pk F
268 57
268 57
296 57
240 57
226 57
212 57
268 71
296 57
212 57
. US. Par. 2
Base m/z: ,5? .^
RIC: L,
/"
/ '
J
ie unkno
m'
2^
O
m
0
z
m
\ ^
\ '
\ ฐ
\ 3
uri*y^'
779rS
765 V
765 ^
754 -
754
743 .
743
742
739
C.A.
^18752.
-
0
.ฃ.
o
m
o
m
Fit RFit
955 799
932 776
ฃ32 775
9M 786
929VXS789
961 7?5 ^
934 758
945 770
964 747
. #
\
\
\
\
\
/
'
~ \
1
1
o /
/
-y
/^
/*!
/ 1
}
V
\
\
ZOIXปป-i
IZ3 \ O
o- m \ i-t
u> oo
a cox?
i u>m
00
cn
-------
Library Search
08/31/98 22:29:00 + 13:44
Sample: S-MM5-FB 1/3SA/1ML
Conds.: UG/ML *1ML *100%/100%
Enhanced (S 158 2N OT)
Data: 30068108 #1235
Cali: 30068108 * 3
1NST. ID: F16
*(NA/NA )/1/3SA NA M
Base m/z: 43
R1C: 19456.
62231 spectra in LIBRARYNB searched for maximum PURITY
912 matched at least 6 of the 16 largest peaks in the unknown
Rank In. Name
1 35182 HEXADECANOIC ACID
2 29642 TETRADECANOIC ACID
3 37913 GLYCINE, N-METHYL-N-(I-OXODODECYL)-
4 40669 DOOECANAMIDE, N,N-BIS(2-HYDROXYETHYL)-
5 22949 DODECANOIC ACID
6 40184 OCTADECANOIC ACID
7 26351 TR1DECAN01C ACID
8 19469 UNOECANOIC ACID
9 32392 PENTADECANOIC ACID
Rank
1
2
3
4
5
6
7
8
9
Formula
C16.H32.02
C14.H28.02
C15.H29.03.N
C16.H33.03.N
C12.H24.02
C18.H36.02
C13.H26.02
C11.H22.02
C15.H30.02
M.Ut B.Pk Purity Fit RFit
256
228
271
287
200
284
214
186
242
43
73
73
73
60
43
73
60
43
722
600
599
585
579
561
550
539
525
977
936
975
967
941
776
885
940
810
722
607
599
589
590
707
568
548
626
Rank
1
2
3
4
5
6
7
8
9
Ret.Time
B.P.Int.
US.Par.1 US.Par.2
C.A.S. #
57-10-3
544-63-8
97-78-9
120-40-1
143-07-7
57-11-4
638-53-9
112-37-8
1002-84-2
1211
-------
MID LIBRARY SEARCH
1279 i
SAMPLE
C16.H32.0:
1279
M WT 256
B PK 43
RANK 1
* 35182 !
PUR 722
C14.H28.0;
1279 i
M WT 228
B PK 73
RANK 2
# 29642
PUR 600
C15.H29.CK
1279 i
M WT 271
B PK 73
RANK 3
ft 37913
PUR 599
M/Z
1
1 b*
i-lill ill. I ."-I .1 , . , ....... .1. ...... i.
2 HEXADECANOIC ACID
2
UI
1 1 ll i i . . .... I. .. i.
TETRADECANOIC ACID
3.N
50
| |
1 1 II | , .... |. .( I.
GL YC I NE , N-METHYL-N- < 1 -OXODODECYL ) -
1 1 i i 1 1
100 150 200 250
ro
-------
Library Search Data: 30068108 #1334 Base m/z: 57
08/31/9822:29:00+14:50 Cali: 30068108 # 3 RIC: 13856.
Sample: S-MM5-FB 1/3SA/1ML INST. ID: F16
Conds.: UG/ML *1ML *100X/100% *(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
62231 spectra in L1BRARYNB searched for maximum PURITY
416 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 37462 HEPTADECANE, 2,6-DIMETHYL-
2 37465 NONADECANE
3 42196 HEPTADECANE, 2,6,10,14-TETRAMETHYL-
4 15969 HYDROXYLAMINE, 0-DECYL-
5 46161 TRICOSANE
6 32058 HEXADECANE, 3-HETHYL-
7 39858 EICOSANE
8 37456 2-METHYLOCTADECANE
9 49555 PENTACOSANE
Rank
1
2
3
4
5
6
7
8
9
Rank
1
2
3
4
5
6
7
8
9
Formula
C19.H40
C19.H40
C21.H44
C10.H23.0.N
C23.H48
C17.H36
C20.H42
C19.H40
C25.H52
Ret. Time B.P.Int
US.Par.1
M.Wt
268
268
296
173
324
240
282
268
352
B.Pk Purity Fit
57
57
57
43
43
57
57
43
43
US. Par. 2
621 892
605 954
604 898
598 968
598 885
594 922
594 867
591 903
589 864
C.A.S. #
54105-67-8
629-92-5
18344-37-1
29812-79-1
638-67-5
6418-43-5
112-95-8
RFit
637
627
622
598
664
610
653
633
672
629-99-2
lo
-------
MID LIBRARY SEARCH DATA: 30068108 #1334 BASE M/Z: 57
08/31x98 22:29:00 + 14:50 CALI: 30068108 # 3 RIC: 13856.
SAMPLE: S-MM5-FB 1/3SA/1ML INST. ID: F16
CONDS.: UG/ML *1ML *100Zxl00Z */lx3SA NA M
ENHANCED
1156
SAMPLE
1 1 1
nil
v**^
"V - , r - T-- - -ฅ- -* -i | i i 1 I 1 1 f 1 1 r i 1 i | 1 """
C19.H40 HEPTADECANE, 2,6-DIMETHYL-
1156
M WT 268
B PK 57
RANK 1
# 37462
PUR 621
||
h
J ,
C19.H40 NONADECANE
1156 i
M WT 268
B PK 57
RANK 2
# 37465 :
PUR 605
1
II
II III ..1 .. ........
C21.H44 HEPTADECANE, 2,6, 10, 14-TETRAMETHYL-
1156 1
M WT 296
B PK 57
RANK 3
# 42196 '
PUR 604
I
1
II
, . J , -U. . r^ . .1 , , H . . S , . , , r~^, , 1 . . M i . . .
M/Z
50
100
150
200
250
!-*
-------
Library Search
08/31/98 22:29:00 H
Sample: S-MM5-FB
Conds.: UG/ML *1ML
Data: 30068108 #1361
15:08 Cali: 30068108 # 3
1/3SA/1ML INST. ID: F16
*100%/100% "(NA/NA )/1/3SA NA M
Base m/z: 59
RIC: 4168.
Enhanced (S 15B 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
483 matched at least 3 of the 16 largest peaks in the unknown
Rank In. Name
1 20265 3-HEXANOL, 1,5-DlMETHOXY-2,4-DIMETHYL-
2 36537 2,5,8,11-TETRAOXATETRADECAN-13-OL, 4,7,10-TRIMETHYL-
3 16192 2-PROPANOL, 1-t1-METHYL-2-(2-PROPENYLOXY)ETHOXY]-
4 20626 2-PROPANOL, 1,1'- [(1-METHYL-1,2-ETHANEDlYL)BIS(OXY)]BIS-
5 9235 1-PROPANOL, 2-(2-METHOXY-1-METHYLETHOXY)-
6 5826 2-PROPANOL, 1-1SOPROPOXY-2-METHYL-
7 5786 PROPANOIC ACID, 2-HYDROXY-2-METHYL-, ETHYL ESTER
8 12385 BUTYRIC ACID, 4-ISOPROPOXY-, METHYL ESTER
9 5790 BUTANOIC ACID, 2-HYDROXY-, ETHYL ESTER
M.Ut B.Pk Purity Fit RFit
Rank
1
2
3
4
5
6
7
8
9
Formula
C10.H22.03
C13.H28.05
C9.H18.03
C9.H20.04
C7.H16.03
C7.H16.02
C6.H12.03
C8.H16.03
C6.H12.03
190
264
174
192
148
132
132
160
132
59
59
59
59
59
59
59
85
59
194
188
185
184
182
178
174
173
172
664
462
715
763
756
717
778
663
797
256
250
214
211
189
197
192
199
193
Rank
1
2
3
4
5
6
7
8
9
Ret.Time
B.P.Int.
US.Par.1
US.Par.2
C.A.S. #
13897-22-8
20324-34-9
55956-25-7
1638-16-0
55956-21-3
3587-75-5
80-55-7
29006-05-1
52089-54-0
-------
MID LIBRARY SEARCH 5,8,11-TETRAOXATETRADECAN-13-OL, 4,7, 10-TRIMETHYL-
1000 i
M WT 264
B PK 59
RANK 2
# 36537
PUR 188
C9.H18.03
1000 1
M WT 174
B PK 59
RANK 3
# 16192 '
PUR 185
M/Z
r
It III 1
i
1 ll . 1 ... .1. . 1. ...
2-PROPANOL , 1 - C 1 -METHYL-2- < 2-PROPENYLOXY ) ETHOXY 3 -
r
\ ll \
, .1 i ......
50 108 150 288 258
H-
to
O'>
-------
Library Search Data: 30068108 #1401 Base m/z: 57
08/31/98 22:29:00 + 15:35 Cali: 30068108 # 3 RIC: 11632.
Sample: S-MM5-FB 1/3SA/1ML INST. ID: F16
Conds.: UG/ML *1ML *100%/100% *(NA/NA J/1/3SA NA M
Enhanced (S 156 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
743 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 46161 TRICOSANE
2 49555 PENTACOSANE
3 42196 HEPTADECANE, 2,6,10,14-TETRAMETHYL-
4 37462 HEPTADECANE, 2,6-DIMETHYL-
5 37465 NONADECANE
6 58739 PENTATRIACONTANE
7 42197 HENEICOSANE
8 42193 EICOSANE, 10-METHYL-
9 44314 DOCOSANE
Rank
1
2
3
4
5
6
7
8
9
Formula
C23.H48
C25.H52
C21.H44
C19.H40
C19.H40
C35.H72
C21.H44
C21.H44
C22.H46
M.Wt
324
352
296
268
268
492
296
296
310
B.Pk
43
43
57
57
57
57
57
57
57
Purity
624
615
604
603
601
596
591
589
588
Fit
903
883
915
896
944
891
877
878
869
RFit
676
684
623
627
630
654
646
636
659
Rank
1
2
3
A
5
6
7
8
9
Ret.Time
B.P.Int.
US.Par.1
US.Par.2
C.A.S
638
629
18344
54105
629
630
629
54833
629
, #
67-5
99-2
37-1
67-8
92-5
07-9
94-7
23-7
97-0
.21
-------
MID LIBRARY SEARCH (LIBRARYNB) DATA:
08/31/98 22:29:00 + 15:35 CALI:
SAMPLE: S-MM5-FB 1/3SA/1ML INST. ID: F16
CONDS.: UG/ML *1ML *100Z/100Z *
-------
Library Search Data: 30068108 #1467 Base m/z: 57
08/31/9822:29:00+16:19 Call: 30068108 # 3 RIC: 10384.
Sample: S-MM5-FB 1/3SA/1ML INST. ID: F16
Conds.: UG/ML *1ML *100%/100% *(NA/NA )/1/3SA NA M
Enhanced (S 15B 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
928 matched at least 7 of the 16 largest peaks in the unknown
Rank In. Name
1 46161 TRICOSANE
2 37465 NONADECANE
3 49555 PENTACOSANE
4 39858 EICOSANE
5 42193 EICOSANE, 10-METHYL-
6 37462 HEPTADECANE, 2,6-DIMETHYL-
7 42197 HENEICOSANE
8 42196 HEPTADECANE, 2,6,10,14-TETRAMETHYL-
9 58739 PENTATRIACONTANE
Rank
1
2
3
4
5
6
7
8
9
Rank
1
2
3
4
5
6
7
8
9
Formula
C23.H48
C19.H40
C25.H52
C20.H42
C21.H44
C19.H40
C21.H44
C21.H44
C35.H72
Ret .Time
M.Wt B.Pk Purity Fit RFit
324
268
352
282
296
268
296
296
492
43
57
43
57
57
57
57
57
57
695
676
674
665
661
659
657
649
647
900
941
875
870
877
883
882
895
879
753
705
757
745
706
687
704
673
722
B.P.Int.
US.Par.1
US.Par.2
C.A.S,
638-
629
629-
112-
54833-
54105-
629-
18344-
630-
#
67-5
92-5
99-2
95-8
23-7
67-8
94-7
37-1
07-9
01 C
-------
MID LIBRARY SEARCH (LIBRARYNB) DATA: 30068108 #1467 BASE M/Z: 57
08/31/98 22:29:00 + 16:19 CALI: 30068108 # 3 RIC: 10384.
SAMPLE: S-MM5-FB 1/3SA/1ML INST. ID: F16
CONDS.: UG/ML *1ML *100Z/1007. *
1062 -
SAMPLE
C23.H48
1062 i
M WT 324
B PK 43
RANK 1
ซ 46161
PUR 695
C19.H40
1062 i
M WT 268
B PK 57
RANK 2
# 37465
PUR 676
C25.H52
1062 -,
M WT 352
B PK 43
RANK 3
# 49555 '
PUR 674
M/Z
J
1
J
VlS^
1, nil. ,L .1,1. . . .1..
TRICOSANE
1
|| iJ il .1
NONADECANE
50
J
PENTACOSANE
100 150 200 250 300 350
o
-------
Library Search
08/31/98 22:29:00 <
Sample: S-MM5-FB
Conds.: UG/ML *1ML
Data: 30068108 #1501
16:42 Cali: 30068108 # 3
1/3SA/1ML INST. ID: M6
*100%/100% *(NA/NA )/1/3SA NA M
Base m/z: 55
RIC: 4408.
Enhanced (S 15B 2N OT)
62231 spectra in LIBRARYNB searched for maximum PURITY
742 matched at least 5 of the 16 largest peaks in the unknown
Rank In. Name
1 22686 TRIDECYLAMINE
2 39622 9-OCTADECENAMIDE, (Z)-
3 39623 9-OCTADECENAMIDE
4 29380 PENTADECYLAMINE
5 58185 9-HEXADECENOIC ACID, 9-HEXADECENYL ESTER, (Z,Z)-
6 36536 PHOSPHONOCHLORIDOUS ACID, (1-METHYLETHYL)-, 5-METHYL-2-(1-METHYLETH*
7 38358 HEXANAL, 4-BROMO-6,6-DICHLORO-2,2-DIMETHYL-
8 8851 CYCLOPROPANE, 1-CHLORO-1-ETHYL-2,2,3-TRIMETHYL-
9 48422 1,22-DOCOSANEDIOL
Rank
1
2
3
4
5
6
7
8
9
Formula
C13.H29.N
C18.H35.0.N
C18.H35.0.N
C15.H33.N
C32.H60.02
C13.H26.0.CL.P
C8.H13.0.CL2.BR
C8.H15.CL
C22.H46.02
M.Wt B.Pk Purity Fit RFit
199
281
281
227
476
264
274
146
342
30
59
41
30
55
83
72
41
55
200
192
192
189
184
181
176
171
169
696
586
594
683
656
687
621
744
587
256
308
296
243
260
228
249
210
272
Rank
1
2
3
4
5
6
7
8
9
Ret.Time
B.P.Int.
US.Par.1
US.Par.2
C.A.S. #
2869-34-3
301-02-0
3322-62-1
2570-26-5
22393-97-1
74630-89-0
61142-56-1
22513-81-1
-------
9999
SAMPLE
MID LIBRARY SEARCH CLIBRARYNB) DATA:
08/-31/98 22:29:00 + 16:42 CALI:
SAMPLE: S-MM5-FB 1/3SA/1ML INST. ID: F16
CONDS.: UG/ML *1ML *100Z/100Z *
30068108 #1501
30068198 * 3
BASE M/Z: 55
RIC: 4408.
O
I.hi
C13.H29.N
9999
M WT
B PK
1!
RANK 1
ft 22686
PUR 200
TRIDECYLAMINE
C18.H35.0.N
9999
M WT 281
B PK 59
RANK 2
ft 39622
PUR 192
9-OCTADECENAMIDE, |