United States
Environmental Protection
Agency
Office of Air Quality
Planning and Standards
Research Triangle Park, NC 27711
EPA-454/R-00-025H
May 2000
AIR
&EPA
Final Report
Hot Mix Asphalt Plants
Truck Loading and Silo Filling
Manual Methods Testing
Asphalt Plant C
Los Angeles, California
Volume 8 of 8
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^ FINAL REPORT
HOT MIX ASPHALT PLANTS
TRUCK LOADING AND SILO FILLING
MANUAL METHODS TESTING
ASPHALT PLANT C, LOS ANGELES, CALIFORNIA
VOLUME 8 OF 8
APPENDICES G.4 (CONCLUDED) AND G.5
EPA Contract No. 68-D-98-004
Work Assignment No. 3-02
Prepared for:
Mr. Michael L. Toney (MD-19)
Work Assignment Manager
SMTG, EMC, OAQPS
U.S. Environmental Protection Agency
Research Triangle Park, NC 27711
MAY 2000
Submitted by
PACIFIC ENVIRONMENTAL SERVICES, INC.
5001 S. Miami Blvd., Suite 300
Post Office Box 12077
Research Triangle Park, NC 27709-2077
(919) 941-0333
FAX (919) 941-0234
U.S. Environmental Protection Agency
Region 5, Library (PL-12J)
77 West Jackson Boulevard, 12th Floor
Chicago, IL 60604-3590
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DISCLAIMER
The information in this document has been funded wholly or in part by the Office of Air
Quality Planning and Standards, U.S. Environmental Protection Agency (EPA) under contract
to Pacific Environmental Services, Inc. (PES). PES performed the work presented in this
document under three EPA contracts and seven Work Assignments; EPA Contract No. 68-D-
98-004, Work Assignment Nos. 1-08,2-07, 3-02, and 3-05, EPA Contract No. 68-D-70002,
Work Assignment Nos. 0-05 and 1-07, and EPA Contract No. 68-D-70069, Work Assignment
No. 2-16. This document has been prepared by PES, reviewed following PES' internal
quality assurance procedures, and approved by PES for distribution. This document has been
subjected to the Agency's review, and has been approved by EPA for publication as an EPA
document. Mention of trade names does not constitute endorsement by the EPA or PES.
11
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TABLE OF CONTENTS
VOLUME 1 Page
1.0 INTRODUCTION 1-1
2.0 SUMMARY OF TEST RESULTS 2-1
2.1 OVERVIEW 2-1
2.2 TREATMENT OF NON-DETECTS AND ESTIMATES 2-2
2.3 TUNNEL EXHAUST DUCT 2-2
2.4 SILO EXHAUST DUCT RESULTS 2-12
2.5 PM AND MCEM DEPOSITION ESTIMATES 2-15
2.6 METEOROLOGICAL STATION RESULTS 2-15
3.0 PROCESS DESCRIPTION 3-1
3.1 COORDINATION BETWEEN TESTING AND PROCESS
OPERATIONS 3-3
3.2 PROCESS MONITORING DURING TESTING 3-3
3.3 PROCESS SAMPLES 3-4
3.4 VELOCITY OF AIR ACROSS TOP OF TRANSPORT TRUCKS
DURING LOAD-OUT 3-5
4.0 SAMPLING LOCATIONS 4-1
4.1 TUNNEL EXHAUST DUCT 4-1
4.2 SILO EXHAUST DUCT 4-1
5.0 SAMPLING AND ANALYTICAL PROCEDURES 5-1
5.1 LOCATION OF MEASUREMENT SITES AND
SAMPLE/VELOCITY TRAVERSE POINTS 5-1
5.2 DETERMINATION OF EXHAUST GAS VOLUMETRIC
FLOW RATE 5-1
5.3 DETERMINATION OF EXHAUST GAS DRY MOLECULAR
WEIGHT 5-3
5.4 DETERMINATION OF EXHAUST GAS MOISTURE CONTENT 5-3
111
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TABLE OF CONTENTS (CONTINUED)
VOLUME 1 rCQNTINUED^) Page
5.5 DETERMINATION OF PM AND MCEM 5-3
5.6 DETERMINATION OF VOHAPs 5-3
5.7 DETERMINATION OF SVOHAPs 5-7
5.8 DETERMINATION OF WIND SPEED, WIND DIRECTION,
AMBIENT TEMPERATURE, AND AMBIENT HUMIDITY 5-7
5.9 ESTIMATE OF PM AND MCEM ON THE CEILING
OF THE LOAD-OUT TUNNEL DOWNSTREAM OF SILO NO. 5 5-7
5.10 ESTIMATE OF PM AND MCEM DEPOSITION ON THE INSIDE
WALLS OF THE SILO NO. 2 EXHAUST PLENUM 5-9
5.11 ESTIMATE OF PM AND MCEM DEPOSITION ON THE INSIDE
WALLS OF THE SILO EXHAUST DUCT 5-9
5.12 ESTIMATE OF PM AND MCEM DEPOSITION ON THE INSIDE
WALLS OF THE TUNNEL EXHAUST DUCT 5-10
6.0 QUALITY ASSURANCE/QUALITY CONTROL (QA/QC) PROCEDURES
AND RESULTS 6-1
6.1 CALIBRATION AND PREPARATION OF APPARATUS 6-1
6.2 REAGENTS AND GLASSWARE PREPARATION 6-2
6.3 ON-SITE SAMPLING 6-3
6.4 SAMPLE RECOVERY 6-4
6.5 LABORATORY ANALYTICAL QA/QC PROCEDURES 6-5
6.6 QA COORDINATOR FIELD AUDIT 6-7
APPENDIX A - TEST RESULTS AND CALCULATIONS 1
A.I TED TEST RESULTS 3
A.2 SED TEST RESULTS 101
A.3 EXAMPLE CALCULATIONS 195
A.4 PARTICIPATE DEPOSITION DATA 204
A.5 CAPTURE EFFICIENCY CALCULATIONS 211
VOLUME 2
APPENDIX B - PROCESS DATA 1
B.I PRODUCTION RECORDS FOR 7/24/98 THROUGH 7/28/98 3
B.2 PRODUCT STORAGE RECORDS FOR 7/25/98 THROUGH 7/28/98 9
IV
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TABLE OF CONTENTS (CONTINUED)
VOLUME 2 CCONTINUED^
APPENDIX B - PROCESS DATA (CONTINUED)
B.3 LOAD-OUT RECORDS USED IN TED EMISSION CALCULATIONS ..19
B.4 LOAD-OUT RECORDS FOR 6/18/98 THROUGH 7/26/98 33
B.5 LOAD-OUT RECORDS FOR 7/24/98 THROUGH 7/28/98 44
B.6 SILO NO. 2 LOAD-IN RECORDS USED IN SED EMISSION
CALCULATIONS 68
B.7 ASPHALT TEMPERATURES AT LOAD-OUT 90
B.8 MASS CHANGE RESULTS FROM ASTM TESTS PERFORMED ON
ASPHALT CEMENT SAMPLES 93
B.9 VELOCITY OF AIR ACROSS TOP OF TRANSPORT TRUCKS
DURING LOAD-OUT 100
B.10 METALS ANALYSIS OF PROCESS SAMPLES 104
VOLUMES
APPENDIX C - FIELD DATA 1
C.I TED FIELD DATA 2
C.2 SED FIELD DATA 59
C.3 METEOROLOGICAL STATION DATA 89
C.4 ON-SITE GC/MS REPORT AND DATA 118
APPENDIX D - QA/QC DATA 230
APPENDIX E - PROJECT PARTICIPANTS 280
APPENDIX F - TEST METHODS
F.I EPA METHOD 1
F.2 EPA METHOD 1A
F.3 EPA METHOD 2
F.4 EPA METHOD 4
F.5 EPA METHOD 18
F.6 EPA METHOD 315
F.7 SW-846 METHOD 0010
F.8 SW-846 METHOD 0030
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TABLE OF CONTENTS (CONCLUDED)
VOLUME 4
APPENDIX G - ANALYTICAL DATA 1
G. 1 PM AND MCEM DATA la
G.2 PAH/SVOHAPS CASE NARRATIVE AND PAH DATA Ik
VOLUMES
APPENDIX G - ANALYTICAL DATA (CONTINUED) 659
G.3 SVOHAPS DATA 659
VOLUME 6
APPENDIX G - ANALYTICAL DATA (CONTINUED) 1248
G.3 SVOHAPS DATA (CONCLUDED) 1248
VOLUME?
APPENDIX G - ANALYTICAL DATA (CONTINUED) la
G.4 VOHAPS DATA Ic
VOLUMES
APPENDIX G - ANALYTICAL DATA (CONCLUDED) la
G.4 VOHAPS DATA (CONCLUDED) Ic
G.5 EPA METHOD 18 REPORT AND DATA 260
VI
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LIST OF TABLES
Page
Table 1.1 Test Log Tunnel Exhaust Duct, Asphalt Plant C - California 1-4
Table 1.2 Test Log Silo Exhaust Duct, Asphalt Plant C - California 1-5
Table 2.1 Summary of Results, Production Emissions for PM, MCEM, PAH,
SVOHAP and VOHAP, Asphalt Plant C, California - July 1998 2-3
Table 2.2 Summary of Results, Average PM and MCEM Emissions,
Asphalt Plant C, California - July 1998 2-4
Table 2.3 Summary of Results, Average PAH and SVOHAP Emissions,
Asphalt Plant C, California - July 1998 2-5
Table 2.4 Summary of Results, Average VOHAP Emissions,
Asphalt Plant C, California - July 1998 2-6
Table 2.5 Summary of Results, PAHS, SVOHAPS, & VOHAPS Average
Emissions, Silo Exhaust Duct - Asphalt Plant C, California, July 1998 .... 2-7
Table 2.6 PM and MCEM Emissions Sampling and Exhaust Gas Parameters
Normal Operations, Tunnel Exhaust Duct, Asphalt Plant C - California . . 2-16
Table 2.7 PM and MCEM Exhaust Gas Concentrations and Emission Rates, Normal
Operations, Tunnel Exhaust Duct, Asphalt Plant C - California 2-17
Table 2.8 PAHs and Semi-Volatile Organics Emissions Sampling and
Exhaust Gas Parameters, Normal Operations, Tunnel Exhaust Duct,
Asphalt Plant C - California 2-18
Table 2.9 PAHs Exhaust Gas Concentrations and Emission Rates, Normal
Operations Tunnel Exhaust Duct, Asphalt Plant C - California 2-19
Table 2.10 Semi-Volatile Organics Exhaust Gas Concentrations and Emission Rates,
Normal Operations, Tunnel Exhaust Duct, Asphalt Plant C - California . . 2-21
Table 2.11 Volatile Organics - SW-846 Method 0030 Emissions Sampling and
Exhaust Gas Parameters, Normal Operations, Tunnel Exhaust Duct,
Asphalt Plant C - California 2-30
Table 2.12 Volatile Organics - SW-846 Method 0030 Exhaust Gas Concentrations
and Emission Rates, Normal Operation, Tunnel Exhaust Duct,
Asphalt Plant C - California 2-31
Table 2.13 Volatile Organics - EPA Method 18 Emissions Sampling and
Exhaust Gas Parameters, Normal Operations, Tunnel Exhaust Duct,
Asphalt Plant C - California 2-36
Table 2.14 Volatile Organics - EPA Method 18 Exhaust Gas Concentrations
and Emission Rates, Normal Operations, Tunnel Exhaust Duct,
Asphalt Plant C - California 2-37
Table 2.15 On-Site GC/MS Volatile Organics Exhaust Gas Concentrations and
Emission Rates with Vost (SW-846 Method 0030) and EPA Method 18
Comparison, Tunnel Exhaust Duct, Asphalt Plant C - California 7/24/98 . 2-38
Table 2.16 PM and MCEM Emissions Sampling and Exhaust Gas Parameters,
Background Condition, Tunnel Exhaust Duct, Asphalt Plant C - California 2-39
vn
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LIST OF TABLES (CONTINUED)
Page
Table 2.17 PM and MCEM Exhaust Gas Concentrations and Emission Rates,
Background Condition, Tunnel Exhaust Duct, Asphalt Plant C - California 2-40
Table 2.18 PAHs and Semi-Volatile Organics Emissions Sampling and Exhaust Gas
Parameters Background Condition, Tunnel Exhaust Duct,
Asphalt Plant C - California 2-41
Table 2.19" PAHs Exhaust Gas Concentrations and Emission Rates, Background
Condition, Tunnel Exhaust Duct, Asphalt Plant C - California 2-42
Table 2.20 Semi-Volatile Organics Exhaust Gas Concentrations and Emission Rates,
Background Condition, Tunnel Exhaust Duct, Asphalt
Plant C - California 2-44
Table 2.21 Volatile Organics - SW-846 Method 0030 Emissions Sampling and
Exhaust Gas Parameters, Background Condition, Tunnel Exhaust Duct,
Asphalt Plant C - California 2-53
Table 2.22 Volatile Organics - SW-846 Method 0030 Exhaust Gas Concentrations
and Emission Rates, Background Condition, Tunnel Exhaust Duct,
Asphalt Plant C - California 2-54
Table 2.23 Volatile Organics - EPA Method 18 Emissions Sampling and Exhaust Gas
Parameters, Background Condition, Tunnel Exhaust Duct, Asphalt
Plant C - California 2-59
Table 2.24 Volatile Organics - EPA Method 18 Exhaust Gas Concentrations and
Emission Rates, Background Condition, Tunnel Exhaust Duct,
Asphalt Plant C - California 2-60
Table 2.25 Sample Log Silo Exhaust Duct, Asphalt Plant C - California 2-61
Table 2.26 PM and MCEM Emissions Sampling and Exhaust Gas Parameters,
Silo Exhaust Duct, Asphalt Plant C - California 2-62
Table 2.27 PM and MCEM Exhaust Gas Concentrations and Emission Rates,
Silo Exhaust Duct, Asphalt Plant C - California 2-63
Table 2.28 PAHs and Semi-Volatile Organics Emissions Sampling and Exhaust Gas
Parameters, Silo Exhaust Duct, Asphalt Plant C - California 2-64
Table 2.29 PAHs Exhaust Gas Concentrations and Emission Rates, Silo Exhaust Duct,
Asphalt Plant C - California 2-65
Table 2.30 Semi-Volatile Organics Exhaust Gas Concentrations and Emission Rates,
Silo Exhaust Duct, Asphalt Plant C - California 2-67
Table 2.31 Volatile Organics - SW-846 Method 0030 Emissions Sampling and
Exhaust Gas Parameters, Silo Exhaust Duct, Asphalt Plant C - California . 2-76
Table 2.32 Volatile Organics - SW-846 Method 0030 Exhaust Gas Concentrations
and Emission Rates, Silo Exhaust Duct, Asphalt Plant C - California .... 2-77
Table 2.33 On-Site GC/MS Volatile Organics Exhaust Gas Concentrations and
Emission Rates with Vost (SW-846 Method 0030) Comparison,
Silo Exhaust Duct, Asphalt Plant C - California 7/25/98 2-82
Table 2.34 PM and MCEM Deposition Estimates, Asphalt Plant C - California 2-83
viii
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LIST OF TABLES (CONCLUDED)
Table 2.35 Meteorological Data Summary, Asphalt Plant C - California 2-84
Table 3.1 Load-out Data Used in TED Emission Calculations 3-6
Table 3.2 Load-in Data for Silo No. 2 Used in SED Emission Calculations 3-7
Table 3.3 Asphalt Temperatures at Load-out, Asphalt Plant C, California 3-8
Table 3.4 Mass Change of Asphalt, Asphalt Plant C, California 3-9
Table 3.5 Results of Metals Analyses of Asphalt Samples, Asphalt Plant C,
California 3-10
Table 3.6 Air Velocity Over Transport Trucks During Load-out, Asphalt Plant C,
California 3-11
Table 5.1 Summary of Sampling and Analytical Methods, Asphalt Plant C,
California 5-2
Table 6.1 Summary of Temperature Sensor Calibration Data 6-8
Table 6.2 Summary of Pitot Tube Dimensional Data 6-9
Table 6.3 Summary of Dry Gas Meter and Orifice Calibration Data 6-10
Table 6.4 Summary of EPA Method 315 and SW-846 Method 0010
Field Sampling QA/QC Data 6-11
Table 6.5 Summary of EPA Method 315 Blank Sample Catches 6-12
Table 6.6 SW-846 Method 0010 PAHs Field and Laboratory Blanks Results,
Tunnel Exhaust Duct 6-13
Table 6.7 SW-846 Method 0010 PAHs Field and Laboratory Blanks Results,
Silo Exhaust Duct 6-14
Table 6.8 SW-846 Method 0010 PAHs Surrogate Recovery Results,
Tunnel Exhaust Duct 6-15
Table 6.9 SW-846 Method 0010 Semi-Volatile Surrogate Recovery Results
Tunnel Exhaust Duct 6-16
Table 6.10 SW-846 Method 0010 PAHs Surrogate Recovery Results,
Silo Exhaust Duct 6-17
Table 6.11 SW-846 Method 0010 Semi-Volatile Surrogate Recovery Results
Silo Exhaust Duct 6-18
Table 6.12 SW-846 Method 0030 Field and Laboratory Blanks Results
Tunnel Exhaust Duct 6-19
Table 6.13 SW-846 Method 0030 Laboratory Blank Results, Silo Exhaust Duct 6-20
Table 6.14 SW-846 Method 0030 Surrogate Recovery Results
Tunnel Exhaust Duct 6-21
Table 6.15 SW-846 Method 0030 Surrogate Recovery Results
Silo Exhaust Duct 6-22
IX
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LIST OF FIGURES
Page
Figure 1.1 Project Organization - US EPA Hot Mix Asphalt Load-out Operation,
Asphalt Plant C, California 1-6
Figure 2.1 Load-out Tunnel and MET Station Location and Average Wind Direction 2-85
Figure 3.1 Process Flow Schematic, Asphalt Plant C, California 3-2
Figure 3.2 Velocity Measurement Locations and Dimensions of Transport Trucks ... 3-12
Figure 4.1 Tunnel Exhaust Duct Sampling Locations, Asphalt Plant C, California .... 4-2
Figure 4.2 Tunnel Exhaust Duct Traverse Point Locations,
Asphalt Plant C, California 4-3
Figure 4.3 Silo Exhaust Duct Sampling Locations, Asphalt Plant C, California 4-4
Figure 4.4 Silo Exhaust Duct Traverse Point Locations, Asphalt Plant C, California . . 4-5
Figure 5.1 EPA Method 315 Sampling Train Schematic 5-4
Figure 5.2 SW-846 Method 0030 Sampling Train Schematic 5-6
Figure 5.3 SW-846 Method 0010 Sampling Train Schematic 5-8
Figure 5.4 Location of TED Deposition Test Plates Tb T2, and T3 5-11
GLOSSARY OF TERMS
ASTM - American Society for Testing and Materials
CEMS - Continuous Emissions Monitoring System
CTS - Calibration Transfer Standard
EMC - Emissions Measurement Center
EMAD - Emission Monitoring and Analysis Division
ESP - Electrostatic Precipitator
FID - Flame lonization Detector
FTIR - Fourier Transform Infrared Spectroscopy
HAP - Hazardous Air Pollutant
MCEM - Methylene Chloride Extractable Matter
MRI - Midwest Research Institute
PES - Pacific Environmental Services
PM - Paniculate Matter
PTE - Permanent Total Enclosure
RAP - Recycled Asphalt
RTFOT - Rolling Thin Film Oven Test
SED - Silo Exhaust Duct
x
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GLOSSARY OF TERMS (CONTINUED)
SMTG - Source Measurement Technology Group
SVOHAP - Semi-Volatile Organic Hazardous Air Pollutant
TED - Tunnel Emissions Duct
TFOT - Thin Film Oven Test
THC - Total Hydrocarbons
VOHAP - Volatile Organic Hazardous Air Pollutant
VOST - Volatile Organic Sampling Train
XI
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VOLUME 8
APPENDDC G
ANALYTICAL DATA (CONCLUDED)
G.4 VOHAPS DATA (CONCLUDED)
G.5 EPA METHOD 18 REPORT AND DATA
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APPENDIX G.4
VOHAPS DATA (CONCLUDED)
Ic
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CASE NARRATIVE
Analysis of Samples for the Presence of
Volatile Analytes by
High-Resolution Gas Chromatography / Low-Resolution Mass Spectrometry
METHOD 8260
Date:
Client ID :
September 7, 1998
Pacific Environmental Services
TLI Project Number : 46297
This report should only be reproduced in full. Any partial reproduction of this report requires permission from
Triangle Laboratories, Inc.
Triangle Laboratories, Inc.
801 Cap/to/a Drive P.O. Box 13485
Durham, NC 27713-4411 Research Triangle Park, NC 27709-3485
919-544-5729 Fax #919-544-5491
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Triangle Laboratories, Inc. September 7, 1998
Case Narrative 46297
Objective: Analysis of three VOST tube pairs ( S-V-l-l-A&B, S-V-1-2-A&B, S-V-1-4-A&B)
for a client specified list of volatile compounds, using Method 8260.
Method:
Eight VOST tube pairs were received at Triangle Laboratories, Inc. on July 25, 1998 on ice at
6°C in good condition. The samples were stored in a refrigerator at 4°C prior to analysis. The
VOST tube sample pairs were analyzed according to the guidelines of Methods 8260 and 5040.
Per client request, the compounds 1,3-butadiene, vinyl bromide, methyl-t-butylether (MTBE), n-
hexane, 1,2-epoxybutane, iso-octane, and ethyl acrylate were additional target compounds. A one
point calibration was analyzed for these additional compounds and the resulting response factors
used for quantitation. The internal standards and surrogate standards were added in the amount
of 0.25 micrograms (ug) immediately prior to analysis by GC/MS. The internal standards are
pentafluorobenzene, 1 ,4-difluorobenzene, chlorobenzene-ds and 1 ,4-dichlorobenzene-d4. The
surrogate standards reported are dibromofluoromethane, toluene-dg, and 4-bromofluorobenzene.
The results reported relate only to the items tested.
The GC/MS analysis conditions are listed below:
Purge and trap: Tekmar LSC-2000
Purge: 11 min.
Desorb Temperature: 250 C
Desorb Time: 4 min.
GC Conditions:
Column: 30 m x .53 mm x 0.3« J&W DB624
0 C hold .5 min, 10 C/min to 45C, 6 C/min to 90C, hold 1.5 min,
50 C/min to 200C.
MS Conditions:
Instrument: VG-TRIO-1 Lab Base data system
Scan: 35-350 amu at .6s/scan
Interface: Jet Separator, 200 C
Report:
Enclosed with the case narrative are copies of the sample identification index, the project
summary sheets, client paperwork, sample log-in sheets, and log book pages. A sample
identification index summarizes the client sample name, TLI sample number, and analytical file
name for each sample and blank. The project summary lists the amounts for detected analytes in
gray. The estimated detection limits will be listed in parentheses when the target analytes are not
detected.
The data are reported as quantitation reports, chromatograms, interim reports, and spectra of the
detected target spectra. The quantitation report header lists the TLI project number, analysis
method, instrument sample file name, client sample name, client project number, TLI sample
number, calibration file, date received, and analysis date. The response factors used for all
calculations are from the calibration file listed in the header. All initial and continuing calibration
1-
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Triangle Laboratories, Inc. September 7,1998
Case Narrative 46297
data are located in the back of the data package. The amount is reported in total ug for the
VOST tubes. The retention time (RT) will be listed for all internal standards and analytes which
are detected. If a target analyte is not detected, it will be flagged with a "U" and a detection limit
will be listed. Estimated detection limits are calculated for all analytes which were not found in
the samples by using an area of 2000. The estimated detection limits reported are the average
detection limits achievable over time on an instrument type. The actual detection limit for a given
compound on a given day may vary from the estimate reported. The quantitation limit for all
analytes is half of the low point of the initial calibration. Below this point the calibration cannot
be considered to be linear. Any amount reported at a level below the quantitation limit will be
flagged with a "J" and should be considered estimated. If any compounds are found at a level
above the upper calibration range, the analyte will be flagged with an "E" and the amounts
reported should be considered estimated. If any target analytes found in the laboratory blanks are
detected in the associated samples, they will be flagged with a "B" on each sample topsheet. All
analytes are quantitated against the internal standard preceding them on the target analyte list.
Surrogate standards are quantitated against the internal standard with the matching internal
standard reference number. For example, toluene-dg has 2 in the IS Ref column and would be
quantitated against the internal standard which has IS2 listed in the flag column. If an internal
standard area is above or below the quality control limits as defined by the continuing calibration,
it will be flagged with "High" or "Low" in the flag column.
Results:
The VOST tube pairs were analyzed twenty-six days outside the fourteen day sampling to analysis
holding time. The VOST tubes were analyzed separately per client request.
The internal standard area and surrogate standard percent recoveries were outside quality control
criteria for samples S-V-1-1A and S-V-1-2-A.
Several target compound were detected at amounts above the instrument calibration range. These
compounds are flagged with "E" and the amounts reported should be considered estimated.
No data was collected for sample S-V-1-l-B, due to a computer data acquisition failure.
The laboratory blank contained several target analytes at amounts below the quantitation limit.
The target analytes in the laboratory blank should not be considered as truly present in the native
samples unless found at a level at least five times the amount found in the associated blank. In the
event that the amount of a target analyte found in the samples is twenty times the amount found in
the associated blank, the contribution from the blank can be considered negligible.
Each sample was processed twice, once against the calibrations containing 8260 compounds and
once against the calibrations containing the additional client-specified compounds. Therefore,
each sample reported contains topsheets and interim reports for both the 8260 and client-specified
analyses as well as a chromatogram and spectra for all analytes. Please note that the surrogate
standards have been reported from the 8260 analyses only.
Moisture from the VOST tube was detected during most of the analyses.
3
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Triangle Laboratories, Inc. September 7,1998
Case Narrative 46297
Due to the absence of MTBE in the standard, that compound was not included on the quantitation
reports.
Sample Calculations:
Response Factor (RF) = (area analyte) x (amt IS)
(area IS) x (amt analyte)
Amount (ug) = (area analyte in sample) x (amt IS)
(area IS) x (avg ical RF)
Where:
amt IS = amount of internal standard = 0.25 ug
ical = initial calibration
avg ical RF = average response factor from the associated initial calibration
The data in this package has been judged to be valid according to the guidelines of Methods 8260
and 5040 except as noted above. Should you have any questions, please feel free to contact our
Project Scientist, Deb. Smith, at (919) 544-5729, ext. 267.
For Triangle Laboratories, Inc.,
Released by:
Sarah A. Hubbard
Report Preparation Chemist
135
The total number of pages in this data package is °
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Triangle Laboratories, Inc.
Sample Identification Index for Project: 46297
Client Idf
S-V-1-l-A 214-1-1A HW905
S-V-1-2-A 214-1-2A HW906
S-V-1-2-B 214-1-2B HW901
S-V-1-4-A 214-1-4A HW907
S-V-1-4-B 214-1-4B HW902
VOSTBLK090498 VOSTBLK09049 HW897
Triangle Laboratories, Inc. Proj_Sum v4.0
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
' 5
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Client ID:
S-V-1-l-A
Triangle Laboratories, Inc.
Project Summary for Project 46297
S-V-1-2-A
S-V-1-2-B
S-V-1-4-A
S-V-14-B
Filename : HW905
TLIId : 214-1-1A
Matri< : VOST
Units : ug
Chloromethane
Vinyl Chloride
Bromomethane
Chloroethane
Tnchlorofluoromethane
1,1-Dichloroethene
Methyl ene chloride
trans - 1 ,2-Dichloroethene
1,1-Dichloroethane
cis-l,2-Dichloroethene
Chloroform
1,1,1-Trichloroethane
lodomethane
Carbon disulfide
Acetone
Ally1 chloride
Acrylonitrile
Vinyl acetate
2-Butanone
Carbon tetrachloride
Benzene
1,2-Dichloroethane
Tnchloroethene
1 ,2-Dichloropropane
Bromodichloromethane
cis-l,3-Dichloropropene
Toluene
trans-l,3-Dichloropropene
1 ,1 ,2-Trichloroethane
Methyl methacrylate
4-Methyl-2-pentanone
Tetrachloroethene
Dibromochloromethane
1,2-Dibromoethane
Chlorobenzene
4363
(0.001)
441$
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
0,678
(0.001)
(0.008)
(0.001)
(0.002)
(0.001)
1,206
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
••• #27*
(0.001)
(0.001)
(0.003)
(0.002)
(0.001)
(0.001)
(0.002)
(0.001)
(
HW906 HW901
214-1-2A 214-1-2B
VOST VOST
ug ug
fit 1 rfSPt
• • X^tfOftjf
(0.001)
$*&$
(0.001)
(0.001)
(0.001)
(0.001) .
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
8.€S3
(0.001)
(0.006)
(0.001)
(0.001)
(0.001)
&T28
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
;'/. ••;•'; -.';;&0J0 • • .• •
(0.001)
(0.001)
(0.002)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(-Estimated Detection Limit
•>•«£»
(0.001)
-------
Client ID:
S-V-1-l-A
Triangle Laboratories, Inc.
Project Summary for Project 46297
S-V-1-2-A
S-V-1-2-B
S-V-1-4-A
S-V-1-4-B
Filename :
TLIId :
Matrix :
Units :
Ethylbenzene
m-/p-Xylene
--Xylene
-•; v rene
Bromoform
2-Hexanone
Cumene
1,1,2,2-Tetrachloroethane
HW905
214-1-1A
VOST
ug
-' ;•• •/ - im
' •''..'.- 1Q364
:':'-':.;-2$5i
(0.001)
(0.002)
(0.003)
(0.001)
(0.003)
HW906
214-1-2A
VOST
ug
im.
7ja3»
2,0$4
(0.001)
(0.002)
(0.002)
(0.001)
(0.001)
HW901
214-1-2B
VOST
ug
(0.001)
0.0CH :
(0.001)
0*002
(0.001)
(0.001)
(0.001)
(0.001)
HW907
214-1-4A
VOST
"g
..•?:•:• ••"•• -"• QJBQ&
".:-.:•'• 4$W
•'-,':' ::": i$$
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
HW902
214-l^B
VOST
"g
(0.001)
(0.001)
(0.001)
0.081
(0.001)
(0.001)
(0.001)
(0.001)
( (-Estimated Detection Limit Page 2
Triangle Laboratories, Inc.
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Savarv3.7
Printed: 14:01:51 09/07/98
; ,.. 7
-------
Client ID:
Triangle Laboratories, Inc.
Project Summary for Project 46297
VOSTBLK090
498
Filename :
TLIId :
Matrix :
Units :
Chloromethane
Vinyl Chloride
HW897
VOSTBLK09049
VOST
O.025
(0.001)
Bromomethane
Chloroethane
Trichlorofluoromethane
1,1-Dichloroethene
Methylene chloride
trans-l,2-Dichloroethene
1,1-Dichloroethane
cis-l,2-Dichloroethene
Chloroform
1,1,1-Trichloroethane
lodomethane
Carbon disulfide
Acetone
Allyl chloride
Acrylonitrile
Vinyl acetate
2-Butanone
Carbon tetrachloride
Benzene
1,2-Dichloroethane
Trichloroethene
1,2-Dichloropropane
Bromodichloromethane
cis-l,3-Dichloropropene
Toluene ...
trans-l,3-Dichloropropene
1,1,2-Trichloroethane
Methyl methacrylate
4-Methyl-2-pentanone
Tetrachloroethene
Dibromochloromethane
1,2-Dibromoethane
Chlorobenzene
(0.001)
(0.001)
(0.001)
0.004
(0.001)
(0.001)
(0.001)
0,001
(0.001)
OJ002
(0.001)
0.005
(0.001)
(0.004)
(0.001)
0,003
(0.001)
O.OZ7
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
.. .0,004
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
( )-Estimated Detection Limit
Page 3
Triangle Laboratories, Inc.
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
SavarvS.7
Printed: 14:01:51 09/07/98
8
-------
Triangle Laboratories, Inc.
Project Summary for Project 46297
Client ID: VOSTBLK090
498
Filename: HW897
TLIId -. VOSTBLK09049
Matrix : VOST
Units : ug
Ethylbenzene
m-/p-Xylene , . iMJOI
o-Xylene , . ..
Styrene .
Bromoform (0.001)
2-Hexanone (0.001)
Cumene O.OCH
1,1,2,2-Tetrachloroethane (0.001)
( (-Estimated Detection Limit Page 4
Triangle Laboratories, Inc. Savar v3.7
801 Capitola Drive • Durham, North Carolina 27713 Printed: 14:01:51 09/07/98
Phone: (919) 544-5729 • Fax: (919) 544-5491 -.
-------
Client ID:
S-V-1-l-A
Triangle Laboratories, Inc.
Project Summary for Project 46297
S-V-1-2-A
S-V-1-2-B
S-V-14-A
S-V-1-4-B
Filename :
TLIId :
Matrix :
Units :
1,3-Butadiene
Vinyl bromide
n-Hexane
1,2-Epoxybutane
Iso-Octane
Ethyl acrylate
HW905
214-1-1A
VOST
ug
(0.001)
(0.001)
7410
(0.065)
(0.001)
(0.001)
HW906
214-1-2A
VOST
ug
(0.001)
(0.001)
.... ;. '£3*0' i
(0.049)
(0.001)
(0.001)
HW901
214-1-2B
VOST
ug
(0.001)
(0.001)
•; 4ooi
(0.039)
(0.001) .,
(0.001)
HW907
214-14A
VOST
ug
(0.001)
(0.001)
.. ' ' : '...SMI '•'.
(0.036)
ftO&S
(0.001)
HW902
214-1-4B
VOST
ug
(0.001)
(0.001)
i 0.00i
(0.038)
(0.001)
(0.001)
( (-Estimated Detection Limit Page 1
Triangle Laboratories, Inc.
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Savar v3.7
Printed: 14:56:54 09/08/98
-------
Triangle Laboratories, Inc.
Project Summary for Project 46297
Client ID: VOSTBLK090
498
Filename: HW897
TLIId : VOSTBLK09049
Matrix : VOST
Units : ug
1,3-Butadiene (0.001)
Vinyl bromide (0.001)
n-Hexane . &QOI
1,2-Epoxybutane (0.034)
Iso-Octane (0.001)
Ethyl acrylate (0.001)
( )-Estimated Detection Limit Page 2
Triangle Laboratories, Inc. Savar v3.7
801 Capitola Drive • Durham, North Carolina 27713 Printed: 14:56:54 09/08/98
Phone: (919) 544-5729 • Fax: (919) 544-5491
-------
DOCUMENT
CONTROL
Trtangfe Labontorfas, tne,
CapfBote Ortw P.aBnrfJ489
OurtMii^MC 277134*11 AMMftft7HtangfeP»fcMC27?
919-344*723 Ft* * 919-344-5491
*">
-------
'?*'
£7 PACIFIC ENVIRONMENTAL SERVICES, INC.
Central Park West
5001 South Miami Boulevard, P.O. Box 12077
Research Triangle Park, North Carolina 27709-2077
(919) 941-0333 FAX: (919) 941-0234
CO
s-i
Sample Chain of Custody Record
Sample
Identification
S-V-M-A
S-V-M-B
S-V-1-2-A
S-V-1-2-B
S-Vr1-3-A
S-NA1-3-B
S-V>1-4lA
S-V-1-4-B
T-V-1-1-A
T-V-1-1-B
T-V-1-2-A
T-V-1-2-B
T-V-1-3-A
T-V-1-3-B
T-V-1-4-A
T-V-1-4-B .
i i
t '
f '
i
t
,
Collection
Date
7/24/98
7/24/98
• 7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
Time
Sample
Name
Silo 2 Run Sell
Silo 2 Run Set1
Silo 2 Run Sel2
Silo 2 Run Set2
Silo 2 Run Set3
Silo 2 Run 1 Set3
Silo 2 Run 1 Set4
Silo 2 Run 1 Set4
Tunnel Run 1 Sot 1
Tunnel Run 1 Set 1
Tunnel Run Set 2
Tunnel Run Set 2
Tunnel Run Set 3
Tunnel Run Set 3
Tunnel Run Sot 4
Funnel Run Set 4
Number' of
Containers
1
1
1
1
1
1
1
1
1
•
Relinquished by:
faetf <\fa**AT~#$L
Relinquished by: v — -
f
Analytical Request
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S.
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tfl
-------
jj
1!
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n
H
n
i
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Custody Seal :
Chain ol Custody
Sample Tags :
SMO Forms :
Ice Cheat
Absent
Present
Absent
Not Listed
N/A
Sample Seals- AliT-nt ____
Container. . . :
ICE/ICF, PACKS T^rnp
Intact (f~^*
\\-sr
^x— S
tf/1
6.0 C
INC. -- lAXi IN KKLOKU/UHAU
(Q) [D)^/7
^v^^^^^ |^| \ 1
1 -) l
-------
=-!RJAMr:!.P 1.Anon ATOR IRS. INC. -- I,(X! IN RECORD/CHAIN OF CUSTODY--
Custody Seal : Absent Sample Sen) a: Absent
Chain of Custody : Present Container... : Intact
Sample Tags : Absent
Sample Tag Numbers: Not Mated on Chain of Custody
SMO Forms : N/A
| Tl.I Project Number 46297 ,"
j Client: PES03 - Pacific Environmental Services
1 ' •'
| Date Received | 07/25/98 | ^7^^_/.^-i^^^-
i i i /ir/^^lK^r S^ ff
Ice Chest ICE/ICE PACKS Temp 6.0 C j Carrier and Number | PedEx/ Isles'
|TLI Number Client' Sample ID . . . Matrix
|mR/H:CPM. . . . Client COC ID . * Location
.
(214-1-8A T-V-1-3-A TRNAX
T-V-1-3-A R03
214-1-8B T-V-1-3-B TMX/CIIAR
T-V-1-3-B R03
214-1-9A T-V-1-4-A TENAX
T-V-1-4-A R03
214-1-9B ' • T-V-1-4-B THX/CIIAR
T-V-1-4-B R03
\
1
1
\
>
I To f.AH
Dflte/Tnlt
To S'lORAOE
Date/Inlt
i
j To IJ\B
Dnre/Inlt
To STORAGE
DatR/Init
I To I.AB
DaLe/lnlL
To STORAGE
Date/InU.
j To LAB
Date/Init
To STORAGE
Date/Init
Book
l'
214
Page
1
1
1
| DISPOSED
Date/Init
.i
/
.
-
i,
f
.. ,., .
Receiving Remarks: 2 set of samples labelled S-V-1-3-A & S-V-1-3-B arrived. ID~S were hand
printed on- 1 set and Typed on the other.
Archive Remarks : : ,' .•
u
.
~*r
:
=Form Revised 05/27/1997 -- Page 2 OF 2=
-------
Triangle Laboratories, Inc.
Run Log
CD
Column Type
T>6^/
Column #
•3*74^5-6
Analysis*
<72£0
Acquisition
Method
tJdfi-
GC Method*
I/A**
Find DBs*
^^6,/3
Other*
»
Standards
Internal / Surrogate / Recovery
7
Internal / Surrogale / Recovery
7
Analyte
ExtrjctJ-Sample volyme
j£*
Circle unit
ul ml
alure
Date
3ate**
»
Time"
Project
Sampled
Client ID
Filename
.EHl
Operator/Date
Backup
Comments*'
17V?
r/rc
|C-30
//M/^r
ix
/
r/rc
A/A
10 r/rc
fit
jm
Xftf
r/
V
* Volatile Data Only ** Transcribed Data
SRVn4\\APWSniALRRUNLOG.DOC (10/16/97)
Dated Signature/Initials Required
Page 3(
-------
Triangle Laboratories, Inc.
Run Log
Column Type
DbC^
Column #
121 t/OCc.
Analysis'
4n,t>c>
Acquisition
Method
i/oA
GC Method*
^3
Find DBs*
<5-Z<*c)£
Other* ",
f^rf*
Standards
Internal / Surrogate / Recovery Internal / Surrogate / Recovery
'i
Analyte
Clrde unH
Extract / Sample volume
Date"
Time"
Project
• in *A i •
Sample #
Client ID
Filename
J>H:
(4 J
' '
r/rc.
UlL
r/rc
'
-T(rc
V
im
r/c
5V-1- I-B> T/C
* Volatile Data Only
SRVn4\\AP\MSFUALRRUNLOG.DOC (10/16/97)
Transcribed Data
*** Dated Signature/Initials Required
Page
-------
Triangle Laboratories, Inc.
Run Log
00
Column Type
T>t62V
Column #
327 1/0 'rc.
Analysis"
2T/60
Acquisition
Method
I/**
GC Method*
U/f3
Find DBs*
A6
Other* •*»
^2^<5X
Standards
Internal /Surrogate / Recovery Internal / Surrogate / Recovery
7
Analyte
Extract / Sample volume
——• •
/ Slgryujfe
Chela unit
L mL
3ate" Time" Project
Sampled
Client ID
Filename I pH* I Operator/Date I Bacjuup'j Proc [Comments*"
U iliht
i/
yL&
iJ-
• Volatile Data Only
SRVR4\\APWSRL\LRRUNLOG.DOC (1(V16«7)
Transcribed Data
"' Dated Signature/Initials Required
n
Page
-------
?f i3 / y* yj~ff! - —' ~:
, // i / /-P / \ J. M ~; — , -/
••
/ a.r-.
SAMPLE
DATA
Triangle Laboratories, me.
801 Capftofe Drive P.O. Box 13485
Durham, NC 277134411 Research Triangle Paris, NC 2T>
919-5444729 Fa* * 919-5444491
J- 19
-------
. •: •':•;•;••' •:'.:"•'. '". ' " ' • -f
Project Numben 46297
Sample File: HW897
Client Project: Htfintix
TU ID: VOSTBUC090498
1fV . n^'jff i«--ir*'iii •'iftiiin irW'WVi' n i~i 1f'"n1Vl^r*' ri I'M* IM rt rti~~" """
Facinc tiRvt^ru^eniai Sieppcw;
Dale Received: / /
Date Analyzed : 69/04/9$
'T^&M •'fiK-^ ••
Method 8260 VOST
Sample ID: VOSTBLK090498
Response Fi!^jfc^H904
"• -. "- • •" '. • ' .''•' .
Analyte :.
Pentafluorobenzene
Chloromethane
Vmvl Chloride
Bromomethane
Chloroethane
Trichlorofluoromethane
1 ,1-Diehloroethene
lodomethane
Carbon disulfide
Acetone
Allyl chloride
Methyiene chloride
Acry.onitrile
trans- 1 .2-Dichloroethene
1,1-Dichloroe thane
Vinyl acstate
cis-1 , 2-Dichloroethene
2-Butonone
Chloroform
1 .1 ,1-Trichloroethane
1 ,4-Difluorobenzene
Carbon cetrachloride
Benzene
1 ,2-Dichloroethane
Trichloroethene
1 ,2-Dichloropropane
;V['*^;;,*:.;-:;': «•;•.•:;'
IS 1 5.04
0.025 J 0.96
U
0.022 J 1.46
U
U
U
0.002 J 2.56
U
0.005 J 2.64
U
0.004 J 3.04
U
U
U
U
U
0.003 J 4.50
0.001 J 4.75
U
IS 2 5-77
U
0.027 J 5.24
U
U
U
Etet tuErtit i Q***«r 'tatttit
0.05
0.001 0.05
0.05
0.001 0.05
0.001 0.05
0.001 0.05
0.05
0.001 0.05
0.05
0.001 0.05
0.05
0.004 0.05
0.001 0.05
0.001 0.05
0.001 0.05
0.001 0.05
0.05
0.05
0.001 0.05
0.001 0.05
0.05
0.001 0.05
0.001 0.05
0.001 0.05
NA- Not Applicable; Det Limit Detection Limit; Quan. Limit: Quantitation Limit
IS: Internal Standard; U: Undetected; B:
Present In Blank; J: Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
Triangle Laboratories, Inc.
801 Capuola Drive • Durham, North Carc.lina 27713
Phone: (919) 544^5729 • Fax: (919) 544-5491
Savar v3.7
Printed: 13:41 09/07/1998
20
-------
• . • • : :•" " •••••• :' '"' •'•' •:'< :•:'•. IV.:
• - . ••/• , • • ••••• ..-• . Pa<
Project Number. 46297
Sample File: HW897
Qient Pro|ecfc Hofmix
TU ID: VOSTBUK090498
Analyte .: '__'",.' :.;
Methyl mechacrylate
Bromodichloromethane
cis-1 ,3-Dichloropropene
4-Methyl-2-pentanone
Toluene
trans-1 ,3-Dichloropropene
1,1 ,2-Trichloroethane
Chlorobenzene-d.
Tetrachloroethene
2-Hexanone
Dibromochloromethane
1.2-Dibromoethane
Chlorobenzene
Ethylbenzene
m-/p-Xylene
o-Xylene
Styrene
Bromoform
1 ,4-Dichlorobenzene-d
Cumene
1 ,1 ,2,2-Tetrachloroethane
.LJ^J" J_ If* £ '-',';? '••' -'- --' -- -•- - - .-'^-'— '.*:•- '^fr <*]*••:':[..', : u''ji_ftrj ' ' ' '
ciiic Eiivisoturieiiiat services
Date Received: / /
Date Analyzed 1 09/04/98
Ai»o«ttrv-Fi^3-;.V:;'/»r. ;; •-
ttg . ' ' ;; ' • :';; 'V- •' •' ' ' ' "
U
u
u
u
0.004 J 7.74
U
U
IS 3 9.94
0.001 J 8.55
U
U
U
U
0.001 J 10.29
0.001 J 10.53
0.001 J 11.24
0.002 J 11.28
U
IS 4 15.05
0.001 J 12.01
U
.,:•?. :^r.;;fii:'^ •
Method 8260 VOST
Sample ID: VOSTBLK090498
Response File: ICALH904
Pet Limit ; Quan. limit
ug : ng
0.001 0.05
0.001 0.05
0.001 0.05
0.001 0.05
0.05
0.001 " 0.05
0.001 0.05
0.05
0.001 0.05
0.001 0.05
0.001 0.05
0.001 0.05
0.05
0.10
0.05
0.05
0.001 0.05
0.05
0.001 0.05
NA- Not Applicable; Det Limit: Detection Limit; Quan. Limit: Quantitation Limit
IS: Internal Standard; U: Undetected; B: Present In Blank;): Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
Triangle Laboratories, Inc.
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Savar v3.7
Printed: 13:41 09/07/1998
! - 21
-------
Pacific
Project Number: 46297
Sample File: HW897
Method 8260 VOST
Sample ID: VOSTBLK090498
Client Project: Ifotmix
HI ID: VOSTBUC09iJ498
:': '• ' PafeRecej^dt':;:/:f.';:\.:U; ;:" •:<:
Date Analyzed: G9/04S3
•^ "• ...
Response Filer ICALH964
Surrogate Summary
Dibromofluoromethane
Toluene-d
8
4-Bromofluorobenzene
•• :A^ ;v
0.280
0.273
0.314
•• = .:«--•(
4.91
7.64
12.22
IS»ef
i
2
2
%REC ;
112
109
jfrs Date 1 / T _/
Reviewed by
NA- Not Applicable; Det Limit: Detection Limit; Quan. Limit Quantitation Limit
^_jS^nternaljtandardjJU: Undetected; B: Present In Blank; J; Estimated- Below Quantitation Limit; E; Estimated- Above Calibration Range
Triangle Laboratories, Inc. Savar v3.7
801 Capitola Drive • Durham, North Carolina 27713 Printed: 13:41 09/07/1998
Phone: (919) 544-5729 • Fax: (919) 544-5491 • - ) O
-------
Pacific lavinsiunental Sesvices
Project Number. 46297 Method 8260 VOST
Sample File: HW897 Sample ID: VOSTBLK090498
Client Project Hotmix Date Received: // Response File: ICALH904
TIJ1D: ¥OSTBUC090498
Date Analyzed: 09/04/98
Aiwlyte
Pentafluorobenzene
1 3-Butadiene
Vinyl bromide
n-Hexane
1 .2-Epoxybutane
Iso-Octane
1 ,4-Difluorobenzene
Ethyl acrylate
'•"• ;.'. Amewtrt FLAG
'•' ';• tig
IS 1
U
U
0.001 J
U
U
IS 2
U
RT
5.04
3.64
5.77
. Etefc tiolit " .": v
ttg
0.001
0.001
0.034
0.001
0.001
Quan. limit
«8
0.25
0.25
0.25
0.25
0.25
0.25
Reviewed by _ ^6A.K _ Date °\ I
NA- Not Applicable; Det Limit: Detection Limit; Quan. Limit: Quantitation Limit
IS: Internal Standard; U: Undetected; B: Present In Blank; J: Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
Triangle Laboratories, Inc. Savar v3 J
801 Capitola Drive • Durham, North Carolina 27713 Printed: 14:51 09/08/1998
Phone: (919) 544-5729 • Fax: (919) 544-5491
-------
71
89-84-98 15:53
Sanple: MOSTBLK T/TC
Triangle Laboratories, Inc. (919) 544-5729
Instrument H
HU8<
100
XFS
0
Min
?7 ^
3j "^ •
tfl T
M *
5.04
4.91$
M t
5.
I
unvi
JJP
77
64 1582948
,/) TIC
w4 A *1
9-
t. .-. t
4.0 6.0 8.8 16
1 ' ^
94 12
1
22
a
15
05
• » 'i ^
.0 12. 6 14.0 16,0 18.0 20.0
-------
QUAN DB
HW897
LAB-BASE QUAN
16:4
No. MAT FOR REV Delta
Area P.Flags
RT
QM Name
1 100 85 99
2 100 96 98
3 100 95 96
4 100 79 98
5 100 97 99
6 100 92 97
7 100 89 93
8000
9 98 74 82
10 0 0 0
11 100 91 96
12 0 0 0
13 0 0 0
14 0 0 0
15 92 70 84
1 ' 7 -*• A .'"i "* "7
J_ o / ^ *m j / .•
17 7^ 41 86
IS 0 0 0
I'1 100 77 9O
20 0 0 0
21 0 0 0
22 0 O 0
23 0 0 0
24 0 0 0
25 0 0 0
26 71 49 63
27 70 48 67
28 0 0 0
29 0 0 0
30 O 0 0
31 O 0 0
32 100 99 99
33 O 0 0
54 O O 0
35 0 0 0
36 O 0 0
37 0 0 0
38 0 0 0
39 O 0 0
40 43 3 66
41 89 62 88
42 0 0 0
43 0 0 0
44 0 0 0
45 77 58 68
46 0 0 0
47 0 0 0
48 0 0 0
49 0 0 0
50 0 0 0
-2
0
M 1
0
1
0
0
0
0
0
0
0
0
0
2
n
•J
0
0
o
0
o
0
0
0
o
1
1
0
0
0
0
1
0
0
0
0
0
0
0
0
1
0
0
0
0
0
0
0
0
0
3670831 bv
4037552 bv
3878054 bv
1886261 bv
1823460 bv
4689891 bv
2576768 bv
0
92252 bv
0
10502O bv
0
0
0
19672 bb
OfVTi KK
1020O A
0
18424 bb
0
O
0
0
0
0
7204 bb
3844 bv
0
0
0
0
495836 bv
0
O
0
0
0
0
0
47340 bb
0
0
0
3636 bb
0
0
0
0
o
5.04
5.77
9.94
15.05
4.91
7.64
12.22
0.00
0.96
0 . OO
1.46
0.00
0,00
0 . 00
2.56
~. -T , - ( <^
2 . 64
0 .OO
3.0<4
C' . OO
O . Ou
O.Od
0 . 00
0.00
0.00
4 . SO
4 . 7 3
0 . 00
O.OO
0 . 00
O.OO
5 . 24
0 . OO
O.OO
O.OO
O.OO
O.OO
O.OO
O.OO
7.74
0.00
O.OO
o.oo
8.55
0.00
0.00
O.OO
0.00
0.00
168 Pen ta f 1 uorobenzene
114 1,4-Di f luorobenzene
117 Chlorobenzene-dS
152 l,4-Dichlorobenzene-d4
113 Dibromof luoromethane
98 Toluene-dS
95 4-Bromof luorobenzene
85 Dichlorodi f luoromethar
50 Chloromethane
62 V'Lnyl Chloride
94 Sromometnane
64 Chloroechane
101 TrLchlorof I uoroma thane
Q6 1 , 1-0 Loh Loroothene
142 lodomenhane
3 76 Carbon d i^u L ^ ide
43 Acetone
41 AL _•/ L ohloi :•:"-
8 •-' ri -e t h y L a n e c h L o r I d e
5 3 A ' : r y L o n i. ~ r L >. • >
••V_. trans -J. , 2-0 Lch LOTOS th-
63 1,1-0 .oh ^oro.3t;-i.in«
a 3 VI n y '. a c e n a t: 5
77 .2 . 2-0 L'.'h loropropane
9t> ci 3 -1 , 2 -C ichior oetheni
43 2-8 uta none
3-3 Ch I rirororm
128 Bromocniorome'rhane
97 1 , 1 , L-Tr ichioroethane
117 Carbon tatrach Loride
75 1 . 1 -0 L c h L o rop rope ne
78 Benzene
62 1,2-Oichioroetharie
130 Tr Lch loroe thene
63 1 ,2-Oichioroproparie
93 Dibromoma thane
41 Methyl me thacrylare
83 Sromodich Lorome thane
75 cis-l,3-Oichloroprope
C" ^ vl"*" ,1 M o f* H v y 1 — O— f^iOr^-f"*Pf*iOr'lfi
\ r1 *4\_; H nSunyl JL. fJcJilUt^ilwItt:
92 Toluene
75 trans-l,5-Dichloroprc
97 1,1,2-Trichloroethane
69 Ethyl methacrylate
164 Tetrachloroethene
76 1,3-Oich loropropane
43 2-Hexanone
129 Dibromochloromethane
107 1,2-Dibromoethane
112 Chlorobenzene
25"
Data Review. VR
-------
No. MAT FOR REV Delta
Area P.Flags
RT
QM Name
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
o8
6^
70
71
72
73
74
75
76
77
78
79
0
43
72
62
69
0
74
0
65
0
79
15
84
79
56
72
85
74
0
9-7
0
0
68
81
0
96
62
96
88
0
21
55
55
64
0
62
0
33
0
66
10
67
63
39
59
70
St>
0
70
0
0
52
63
0
91
23
38
77
0
52
66
55
64
0
62
0
73
0
73
37
78
71
55
5^
70
06
0
81
O
O
60
75
0
1:3 2
90
91
87
0
2
2
4
c
0
3
0
1
0
3
-31
3
4
2
0
1
0
0
1
0
1)
.z
5
Q
6
{5
6
6
0
274O
11892
oO24
23120
0
15420
0
13000
0
5764
1393252
10&32
14408
18438
15250
4329o
24^88
0
37788
foTilM -3-
0
2^710
53 17c.
0
55508
14016
1206'">6
41363
bb
bv
A
A
bv
A
A
A
A
bv
bv
A
A
A
A
T^
Yfl
1 * \
A
bv
bb
A
bv
0
10
10
11
11
0
12
0
12
0
12
12
12
13
13
14
14
14
0
14
i5.i2> G-
Qte>\qtf 0
16
16
C>
19
l'rj
19
19
.00
.29
.53
.24-
.28
.00
.01
.00
.42
.00
.84
.22
.90
.13
.31
.Ot>
.22
. 71
.00
C1 '**•
^OOiX
. oo
.84
"*,'"'
. 00
.12
. 33
. 32
. 53
131
106
lOt>
106
104
173
105
33
156
75
120
75
126
126
105
ll"'
105
105
11'^
14.:.
' 1 10
'•'L
91
1 »6
75
130
^ l"i
128
180
1,1,1,2-Tetrachloroethc
E thy Lbenzene
m-/p-Xylene
o-Xy lene
Styrene
Bromof orm
Cumene
1, 1,2,2-Tetrachloroethc
Bromobenzene
1,2, 3-Tr ichloropropane
n-P ropy I benzene
trans-1 ,4~Dichioro-2-bi
2-Chloro toluene
4-Chloro to I uerie
1 , 3,5-Tr Lmethy Lbenrene
tert-Sutyl ben ,:a ne
1 , 2 , 4 - T r i ma r. hy 1 be n re ne
sec -8u ty !. ben.:'jne
p-Cymene
1 , 3-0 ich Lorofo.-;n,:ane
1 , 4-0 ich L or.; ben ~^ne
3a nzy L on ..or i' le
n-Buty I benzene
1 , 2-0 ich ;.JP :j&en.:ene
1 , 2-0 i br omo-3-chloropr'-
1 , 2 , 4 - Tr ich iorobenzane
Hexach lorobutadiane
Naph tha L.-ene
1 , 2 , 3-Tr ichlorobenzene
'J6
-------
QUA.N DB : HW897
No, MAT FOR REV Delta
LAB-BASE QUAN
Area P.Flags
09-04-98
14:5
RT
QM Name
1
2
3
4
5
6
7
8
9
10
11
12
13
14
100
10O
100
100
100
100
100
0
0
0
64
0
0
0
85
96
95
79
97
92
89
0
0
0
52
0
0
0
99
98
96
98
99
97
93
0
0
0
52
0
0
0
0
1
-2
3
1
-1
-1
0
0
0
1
0
0
0
3670831
4037552
3878054
1886261
1823460
4689891
2576768
0
0
0
5°40
0
0
0
bv
bv
bv
bv
bv
bv
bv
A
5
5
9
15
4
7
12
0
0
0
3
0
0
0
.04
.77
.94
.05
.91
.64
.22
.00
.00
.00
.64
.00
.00
.00
168
114
117
152
113
98
95
39
106
73
57
42
57
55
Pentaf luorobenzene
1 , 4-0 if luorobenzene
Chlorobenzene-d5
1 , 4-Dichlorobenzene--d':
D ibromof 1 uoromethane
Toluene-d8
4-Bromof 1 uorobenzene
1,3-Butadiene
Vinyl bromide
MTBE
n-Hexane
1,2-Epoxy butane
Iso-Octane
Ethyl aery late
Data Review:^
Date:
-------
00
r )
09-04-98 15:53
Sanple: UOSTBLK T/TC
Triangle Laboratories, Inc. (919) 544-5729
Instrument H
HU897 91
1801 5
X.FS I
fj I I1''
& (0.960)
0
52
f ___ _
H/Z 50 ' 100 ' 150 ' 200
HW897J9I
1001 5
X.FS
49
13 hi
•a '' ' •'
M/Z 5
8Z60B 9
1001 5
X.FS
44
01 i.!
& (0.961) REFINE
B
52
0 ' 100 ' 158 ' 200
(0.960) Chloronethane
0
52
i
V' i 'i"9 — • — •— i — . — . — • r— ' T •-- - ) -• — T— - T- -T---' -r •
M/z 50 100 15f* 200
18176
250 300 350
17664
250 300 350
FIND
100
250 300 350
-------
69-84-98 15:53
Sample: UOSTBLK T/TC
Triangle Laboratories, Inc. (919) 544-5729
Instrument H
HW897 146
100
X.FS
44
0 1 ', ,
M/Z 50
HW897' 146
100
XFS
0 r
M/Z 50
(1.460)
9
93
V ,
4 15232
100 150 200 250 300 350
(1.461) REFINE
9
93
?J J
4 14144
100 150 200 250 300 350
8260B 11 (1.470) Brononethane FIND
100
XFS
46
H/Z 50
9<
93
. , , ill. . t* 1
1 100
183 ijO 288 250 300 350
0-
N
-------
o
CO
09-94-98 15:53 THangle Laboratories, !nc
Sanple: MOSTBLK T/TC
(919) 544-5729
Instrument H
HUB'
100
XFS
«
}? 256 (Z.1
T ?
Y
560)
i^
6
T
^ 2608
M/Z 58 100 150 ' 280 250 ' 300 350
HUBS
100
X.FS
Q
J7'256 (2.!
7
44
B61) REFIME
i^
6
127
12 2336
H/Z 50 100 150 200 250 ' 300 350
826£
100
XFS
IB 15 (2.5!
7
44
30) lodonethane
1*
6
127
78 T
I. ,j
FIND
12 100
' ' ' '' 1 — ' ~* » — p""1 •"' "*~r' "T ""i •"•" "* ' | • - ' | .,,... , - . !•-'•! ...,....,- - , - • ,
H/2, SB lee 158 300 250 300 35W
-------
ro
09-04-98 15:53 Triable Laboratories, !nc, (919) 544-5729
e: UOSTBLK T/TC Instrument H
HW897 264 (2.640)
100
X.FS
0
M/Z
58
142
50
180
158
238
258
300
1296
350
HU89V264 (2.641) REFINE
100- 43
XFS
8
M/Z
58
50
180
150
288
250
300
1128
350
826BB 17 (2.650) Acetone
100- 43
XFS
0
M/Z
58
50
100
158
288
250
300
FIND
100
358
-------
01
0SE 00£ 8GZ 00Z 8ST ( 60T
88
98
0
j__i 1 — i 1
£8
TG
f»8
00T 6
0GE 00£ 0EE 002 0^T 80T
i i i i ... i > , - i i i • , . l . .. A L . —
t
G
jT * *•*' 'i'
"v_
&
T ill
0S
• i . < < ; ,-.
TG
8
6
V
&
Z/H
0
SJX
L00T
39Z8
i/M
0
00 T
3NU3« (Tfr0'e) ^ee^eenH
0Se 00£ 0GE 00E 0i*l . 00T
98
fr
(f
0
i .... i
TG
8 6
G
Ifl
fr
£ At
0X
00 T
jonii
(6T6)
31/I MlSISOh :
£S:ST 86-^0-60
CO
ro
-------
09-04-98 15
.
CO
p
:53 Triangle Laboratories, Inc. (919) 544-5729
Sample: WSTBLK T/TC
HU897 458 (4
100
XFS-
0
H/Z
A
3
44
50
HW897'450 (4
100
XFS
0
H/Z
4
3
7
50
.501)
it
r T
100 150
.501) REFIHE
is
f 1
100 150
8260B 26 (4.511) 2-Butanone
100
XFS
0
H/Z
i
3
Instrunent H
1008
16
200 250 ' 300 350
1008
16
230 250 300 350
FIND
100
72
44
; 5?
.«* , , -•-, , ,
50
73
160 158
233 253 300 353
-------
09-84-98 15:53
Sanple: MOSTBLK I/TC
Triangle Laboratories., Inc
(919) 544-5729
Instrument H
HW897 475 (4.751)
1001
XFS
0
H/Z
83 896
40
85
50 100 ' 150 ' 280 250 ' 300 ' 350
HW897M75 (4.751) REFINE
1001
XFS
0
H/Z
4
826BB
I00i
XFS
0-
H/Z
83 896
0
85
50 ' 100 ' 150 ' 260 250 ' 300 ' 358
27 (4.761) Chloroform FIND
83 100
85
87
50 100 159 ' 200 250 ' 300 ' 350
-------
10
09-04-98 15:53
Sanple: MOSTBLK T/TC
Triangle Laboratories, Inc. (919) 544-5729
Instrument H
HW897 524
100
XFS-
0 /9f
M/Z 50
HW897'524
100
XFS
3952
•••' ii
0 -I, , -1
H/Z 58
(5.241)
78
77
74 ?9
63 ';-i()(. . .. i^e
100 150 200
(5.241) REFINE
78
77
74 79
., ".l,. (
100 150 200
8260B 32 (5.251) Benzene
100
52
a:_M
H/2 58
78
'] 79
100 150 200
68688
258 300 358
64768
250 300 350
FIND
100
250 300 350
-------
CO
09-04-98 15:53 Triable Laboratories, Inc
Sample: UOSTBLK T/TC
(919) 544-5729
Instrument H
HW897 774 (7.741)
100
XFS
0
M/Z
98 20736
108
Y
42 54 7,8 00 II f 01
.il,l. .|.tl. mil .) "2 .,ll..illli _,„.._. - , -
50 100 138 200 250 300 350
HU897J774 (7.741) REFINE
100i
XFS
0
M/Z
9
39 89
63
l !{ l
1 7744
92
93
50 100 150 200 250 300 350
826BB 41 (7.761) Toluene FIND
100
XFS
0
M/Z
9
?9gl 65 89
1 100
93
50 10@ 153 208 250 300 350
-------
0S£ 00C 0fiS 002 0ST O0T 0fi
1 .... 1 .... 1 .... 1.. ....!. . . i • . . , 1 . ' ' 1 ' ' ' ' ' ' ' " ' 1 ... 1 . .
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eef
t
6&T
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2i9 ^y
TC
H
T
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6
(T8S'8) SI
&
?
2/W
0
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H89Z8
05
. . i . . . . i .
0
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z/w
0
SJX
001
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0
t
Z/H
0
00 T
(TSS'8) SS8 ^68rtH
(6T6)
01/I XiaiSGft :
86-^8-60
-------
oo
89-04-98 15:53 Triangle Laboratories., Inc. (919) 544-5729
Sample: MOSTBLK T/TC Instrument H
HW897 1029 (10.291)
100
x.FS-
0
M/Z
117 2384
8291
40 5£
ill
119
106
1
50 100 ' 158 ' 200 258 ' 300 350
HU897'1029 (10.291) REFINE
100
XFS
0
M/Z
826[
100
XFS
0
M/Z
9
51
54
40 ||
1 712
106
50 ' 100 ' 158 ' 200 250 ' 300 350
IB 52 (10.311)
9
51 65 77
..i. . L .4 . ...ii, .,
Ethyl benzene FIND
J 100
106
y7
50 100 158 200 250 300 358
-------
00
0SE 00C 0S2 002 0ST 00T 0S
1 ... 1 ... 1 .... 1 .... 1 .... I ... : , . j_ 1 - . . I , . 1 . . 1 ... 1 ... 1 . .
T
26
90 T
00T T
LL \9 tfS /
6
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08 T
dNIJ auaifix-d/-w (TSS'BT) ES H09Z8
0G£ 00£ 0G2 002 0CT 00T 0Q
1 .... 1 ... 1 .... 1 ... i . . . i , . . 1 .... 1 . . 1 _...... 1 ... 1 ... 1 .... I ...
ATT
90 T
88EE T
1 I
TS
LL
6
0
SJX
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1 .... 1 .... 1 .... 1 .... 1 . . . I . . . ! . . . 1 . 1 .1 I ... 1 ... 1 ...
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8E62 T
££
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— H
09-04-98 15:53
Sanple: UOSTBLK T/TC
Triangle Laboratories, Inc. (919) 544-5729
Instrument H
HW897 364 (3.640)
100
XFS
0
H/Z
i
54 5
56
\
>7 920
50 100 150 ' 200 250 ' 300 ' 350
HW897'364 (3.641) REFINE
100
0
H/Z
4,
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44
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50 180 ' 158 ' 200 ' 250 ' 300 ' 350
8Z6BX 11 (3.660) n-Hexane FIND
100
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5
I55
7 100
86
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50 100 150 ' 200 250 ' 300 ' 350
-------
;•••. '•;• ':^^^^m^^i^.-'-.m^ •••,••
Project Number 46297
Sample File: HW905
Qient Project Hofmix
TLIID: 214-1-1A ;
Method
8260 VOST
Sample ID: S-V-1-l-A
; • •; • Date Received: 87/25/98
•'•'*•• Date Analyzed: 09/04/98
Response File:
". '•;.••. - .
IC&LH904
•::••'.•
Analyte
Pentafluorobenzene
Chloromethane
Vinyl Chloride
Bromomethane
Chloroethane
Tnchlorofluoromethane
1 ,1 -Dichioroethene
lodom: ihane
Carbon di.sulfide
Acetone
Ally! chloride
Methylene chloride
Acrylonitrile
trans-1 .2- Dichioroethene
1,1-Dichloroethane
Vinyl acetate
cis-1 ,2-Dichloroethene
2-Butanone
Chloroform
1 ,1,1-Trichloroethane
1 ,4-Difluorobenzene
Carbon tetrachloride
Benzene
1 ,2-Dichloroe thane
Trichloroethene
1.2-Di. iloropropane
NA-
-.-• Amoaar.':. •»»•.:.. . RT J 1
: «8 •''•"'• .':•'. '; . '• .' "' ' .1 •••'
IS 1 Low 5.05
0.363 B 0.96
U
0.116 B 1.46
U
U
U
U
U
0.670 B 2.62
U
U
U
U
U
U
U
U
U
U
IS 2 Low 5.79
U
1.206 BE 5.25
U
U
U
E*tU»it :
*5
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.008
0.001
0.001
0.001
0.001
0.002
0.001
0.001
0.001
0.001
0.001
0.001
Qtian. limit :
ttg
o.os
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
Not Applicable; Det Limit Detection Limit; Quan. Limit: Quantitation Limit
__lS:Jnternaljtandard; U: Undetected; B: Present In Blank; J: Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Savar v3.7
Printed: 13:41 09/07/1998
44
-------
'""''. "::':: .:V':"V' Pacif ic Snvixonmcntat Services : 'v//*:\ :; '•'' ' j
Project Number. 46297
Sample File: HW905
Qient Project Hotmix
IU ID: 214-1-1A
Method 8260 VOST
Sample ID: S-V-1-l-A
Dale Received: 07/2TO
.; Date Analyzed :09/G4/S8
Response File: ICALB904
.-..•:•".'
Aualyte
Methyl methacrylate
Bromodichloromethane
tih- 1 .3- Dichloropropene
4-Methyl-2-pentanone
Toluene
trans-1 ,3-Dichloropropene
1 , 1 .2-Tnchloroe thane
Chlorobenzene-d.
Tetrachloroethene
2-Hexanone
Dibromochloromethane
1 ,2-Dibromoethane
Chlorobenzene
Ethylbenzene
m-/p-Xylene
o-Xylepc
Styrene
Bromoform
1 ,4-Dichlorobenzene-d
4
Cumene
1 ,1 ,2.2-Tetrachloroethane
• '."'-'.;':**r* ':;*uw •v;.*T"
u
U
u
u
3.278 BE 7.78
U
U
IS 3 Low 9.99
U
U
U
u
u
1.752 BE 10.35
10.364 BE 10.61
2.951 BE 11.31
U
U
IS 4 Low 15.11
U
U
Etet Limit
0.003
0.001
0.001
0.002
0.001
0.001
0.001
0.003
0.001
0.002
0.001
0.001
0.002
0.001
0.003
Qttan. Limit
0.05
0.05
0.05
o.os
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.10
0.05
0.05
0.05
0.05
0.05
NA- Not Applicable; Det Limit Detection Limit; Quan. Limit Quantitation Limit
IS: Internal Standard; U: Undetected; B: Present In Blank; J; Estimated- Below Quanritation Limit; E: Estimated- Above Calibration Range
Triangle Laboratories, Inc. Savar v3
801 Capitola Drive • Durham, North Carolina 27713 Printect 13:41 09/07/199
Phone: (919) 544-5729 • Fax: (919) 544-5491 ' •' ' 4 3
-------
Pacific Environmental Services
Project Number: 46297 Method 8260 VOST
Sample File: HW905 Sample ID: S-V-1-l-A
Client Project: Hotmix
.;-v-M^S^^£i^
Response File ICALH904
Surrogate Summary
Dibromofluoromethane
Tolucne-d
8
4-BromoHuorobenzene
: Atttotittt- ' • '" '••': ''''-•' ' ' : RT '•
0.391 4.91
0.435 7.68
1.969 12.32
^ \ •"••••:. ^KK:
1 156
2 174
2 788
Reviewed by _ VR
Date
NA- Not Applicable; Det Limit Detection Limit; Quan. Limit Quantitation Limit
__^S^ema^Standar^ In Blank; J: Estimated- Below Quantitation Limit; E: Estimated- Above Calibntion Range
Triangle Laboratories, Inc. ^^ y3 j
801 Capitola Drive • Durham, North Carolina 27713 Printed: 13:41 09/(F/1998
Phone: (919) 544-5729 • Fax: (919) 544-5491 i '• '.
^ ^ '
-------
Pacific Bnvtaanmental Services
Project Number 46297 Method 8260 VOST
Sample File: HW905 Sample ID: S-V-1-l-A
Cl ient Project: HotmLx Date Received: D7/25/98 Response File: ICALH904
Date Analyzed: 09/04/98
Analyte
• ' • ;:::.:' • ':; ;• '• Amouttt FLAG
RT :..; ••' '"'Pet.
itiXEtxt - ' • Oti^Ei* fcitntt1
Pentafluorobenzene IS 1 Low 5.05
1,3-Butadiene U 0.001 0.25
Vinyl bromide U 0.001 0.25
n-Hcxane 7.610 BE 3.67 0.25
1,2-Epoxybutane U 0.065 0.25
Iso-Oaane U 0.001 " 0.25
1,4-Dtfluorobenzene IS 2 Low 5-79
Ethyl acrylate U 0.001 0.25
Reviewed by -Xy^tT Date " /
NA- Not Applicable; Det Limit: Detection Limit; Quan. Limit Quantitation Limit
IS: Internal Standard; U: Undetected; B: Present In Blank;): Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
Triangle Laboratories, Inc. Savar v3.7
801 Capitola Drive • Durham, North Carolina 27713 Printed: 14:54 fflP/08/1998
Phone: (919) 544-5729 • Fax: (919) 544-5491 *» '
-------
:
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-------
QUAN 08
No. MAT FOP REV Delta
LA8-8A3E QUAN
Area P.Flags
RT
QH Name
.1
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4
5
6
7
3
0
10
11
12
13
14
15
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1815364 A
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•:• ~. L , 1~-0 i ' h i i . : i >.'• i'h.'f !'!•-
4-3 V L ny 1 .)'. ••. i"..i r.'
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'".•'i1-. c i •" - L "'™-O i "li l "i r"i.= t" i i"-"1 r
4.3 "'-Si it: a no. le
83 Ch\. M"' j ronn
1.28 oPi.illlOCli L Oi' i"i|Ti'- t hr'-'i ri.~r
v 7 i. , L , 1 - T r i. ' M i o i- o e r. n a n <-.
117 i .\.-ti i.^on L.ri.'i .'juh lor ide
7 5 L , 1 - D i c i i L o r o F • r o p e n •••-.
78 8 en ^en^
62 1 , 2-D i ch lor'C'.-s thane
13O T r- i oh L o r o--- 1 he ne
63 1 , 2 - D i. c h 1. o i • o p r o p a n e
93 0 i b rorrt' ./me t ha ne
O.i 3O
0 . OO
7. 78
0.00
0 . OO
0 . OO
0 . 00
0.00
O.OO
O.OO
83 8 romod i o n L o r ome t ha i ie
75 c i s~ 1 „ 3- 0 i o h i o r op roo.
•'PVa zlX .i — Micif-K'i/ 1 — "^ — •'*u-'nt"'^ru"'in»-
92 Toluene
75 t ra ns - 1 , "-0 i o h 1 o rap r
97 l,i,2-Tr ichLoroethan
C^ A O P" \~ k> % / 1 i'fi *a t" !"i 'i r*- P V 1 fl i" i-1
* » O 7 tz» l j I I y 1. lit C; i -* \ 1 1,\ '..,• i ^ i. ex i-« *•—
164 Tetrachioroethene
76 1 „ 3-D i c h L o r op r opa ne
^P 43 ° Hi~-V3 nn ne*
\ * *H O iv 1 J "C,- f\ (J. 1 l ^.j1 1 1 *•_
129 Oibromoch Loromethane
107 1 , 2-Do.bromoethane
112 Chlorobenzerie
Data Review:^ . 0
Date'/-»\-,i , j 4^
-------
No. MAT FOR REV Delta
Area P .Flag?
RT
QM Name
51
J> J-
53
54
55
So
57
58
-y->
oO
61
to 2
.".< 3
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6^
7 0
71
7 "^
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76
T V
78
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0
77
73
0
0
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0
0
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o
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61
0
9.4
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78
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0
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0
0
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0
0
0
0
0
4 '4
56
53
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0
0
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O
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0
44
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30
45
M
O
n
0
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0
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80
83
33
0
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0
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91
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0
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0
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3444^98 vv
25052^20 vv
6672621 bv
0
0
O
O
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0
0
0
0
0
31266880 vv
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1 ''HO 9 240 w
;n. 33 4 1)8 bv
l'"'7T:07fo A
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104
173
105
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120
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Bromof orrn
Curnene
i i — . -^
i , l , «. , ^
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1,2 ,3-Tr
T e t r ,.i c h 1. o r o e f. h a r
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n - P r o p y 1 b e n .r e n e
tran.T. -!„•
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2 - C h 1 ( j r o toluene
4-Ch loro
1,3 , 5--Tr
tert-Rnt:
1 . 2 ,4-Tf
>.-:>i"; — 6l ! ty
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1 - r , : . i.
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-------
QUAN DB : HW905
No. MAT FOR REV Delta
LAB-BASE QUAN
Area P.Flags
O9-04-98
RT
QM Name
1
•~>
3
4
S
6
1 l'"1
JLU
11
13
14
0
0
33
65
0
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0
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97
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1315364 A 5
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333526 vv 1=
L337t:>84 A *
3367072 bv 7
72^4060 A IS
0 C
26^97230 vv -
«^*rt<^ SM"-^ _79 114 1,4-Dif luorobenzene
',99 117 Chlorobenzene-d5
-.11 152 1. 4-Dichlorobenzene-c!4
L. 91 113 Dibromof i uorornetrhane
r.68 98 Toluene-d8
;.32 95 4-8romof 1 uor obenzene
) .. 00 106 V i ny L b rom i de
5.67 57 n-Hexane
•j .' LLt ^p 4^ / I s o - 0 c t a n e
-V&
°tWi
Data Review. \^
Date:
51
-------
-Sep-98 20:57
Sanple: S-U-1-l-A
Triangle Laboratories, Inc.
T 214-1-lA TLItt46297
(919) 544-5729
Instrument H
HU905 96 (0,960)
100
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0-
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T
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50 100 150 200 250
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100-
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0-
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49
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50 100 150 200 250
8260 9 (1.230) Chloronethane
100
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0-
M/Z
5
4.4
M 1 I U
0
52
50 100 150 200 250
1409024
300 350
133120
300 350
FIND
100
300 350
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-------
8 20:57 Trianule laboratories, T«c, (919) 544-5729
Sample: S-U-1-1 A T 214 1-1A TL]ft4b297 Instrunent H
HU905 262 (2.620)
ylO
188
53
X.FS-
B-t
57
. ...•...
H/Z 58
101
riL '
100
158
250
388
136192
350
HU905T262 (2.621) REFINE
188i 43
XFS
\
58
H/Z
100
lie
260
258
388
96256
350
8260B 17 (2,650) Acetone
188- 43
XFS
H/ Z
58
100
150
200
388
FIND
100
358
-------
10
If)
09-04-98 20:57 Triable Laboratories, Inc
Sample: 8-U-l-l-A I 214 1-tfl TL1*46297
(919) 544-5729
Instrument H
HU905 525 (5.251)
1001 7
XFS 77
4351 ?7
0'..,i,il.r ..jl..iil....i. jli.i
3
79
i"
' ' '. • • * 1 • ' . - - | • j •-!••• r .» , , • ; , . . • i , .... | .... | .
M/Z 50 108 150 280 250
HU905'525 (5.251) REFINE
7
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j 52 74
0 ..' |! $3 . 'fl
3
79
'• r
wyz 50 100 ' 150 ' 200 250
8260B 32 (5.251) Benzene
1001 7
XFS] ??
i 52 '"i
8
79
i
»/z 50 160 ' 158 ! 280 ' 250
1376256
300 356
1277952
300 350
FIND
100
300 356
-------
8£e 00£ 0£E 00E 0£T 90T OS
£6
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68 £9 T£
6£
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-------
r-
LO
89-04-98 28:57
Sample: S-U-1-l-A T
Tr i a r«q}e Laborat or i es ..
214 1-1A II, 1146297
Inc. (919) 544-5729
Instrument H
HU905 1035 (10.351)
ai 1294336
188
XFS
0
55 69
41 67 -0
.1 " "-• 8J4
...lilL.. .illi ....i.l.l! L...lli Jili.. .
J.I
97 126
if.! .= .!
H/Z 58 186 158 ' 206 258 388 358
HU905'1035 (10.351) REFINE
QI 1848576
188
XFS
•
8
51 65 77
..... ...J. ,,..1 ..,.il. .. ,
, ui.t ,. I ,. I -I -., . <'. , ..I,
18
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'• Vlll "'•*", .• i •> !• • . . 1 . - | . ' - ! .!.,.. ,....,.. .,....,....,
H/Z 58 188 158 280 258 388 358
8260B 52 (10.311) Ethulbenzene FIND
.„„ 91 100
188
XFS
•
| 51 65 77
£j j _J_ __ ^,_ _|_| (1,
106
|187
M/Z 58 188 158 280 258 388 350
-------
oo
-98 20:57
le Laboratories, hie
(919) 544-5729
Sanple: S-U-1-l-A T 214-1-lfi TL1*46291
Instrument H
HU905 1061 (10,
•f £1|~1 — t
f KrV? f
XFS
0-
H/Z
611
91
*=K 69
•3
41
.,!, t... ,4
50
-j
li...4l.
8
77
1
i!Ji
HW905'1061 (10.
100
XFS
0
H/Z
77
39 51
J..4
50
8260B 53
100
XFS
H/Z
39
•'t -.*"f '^
50
i 4
8
|,
3
f- *
)
3358720
Li
97
1
8C
16
125
!,i ii
« ISO 258 300 350
611) REFINE
9
3
1
2326528
•
i .. . j
100 150 250 ' 300 ' 350
(10
.551)
9
69 ??
1
n-/p-Xyiene FIND
100
106
92
,!
iee 158 20a 250 300 ' 350
-------
ro
89-84-98 28:57 Trianyle Laboratories, IMC, (919) 544-5729
Sample: S-U-1-l-A I 214-1-lfl TLI»46297 Instrument H
HW9B5 1131 (11.311)
188
XFS
0
M/Z
9
5.5
41 6,9
,|j ,!, .|7,7
!r.r(|(|.n.v.ji(lfj{., if-ffHfll.-JniJtlj.-ji
1 1622816
106
'! j I?4
58 188 153 208 250 300 358
HU985H131 (11.311) REFINE
188
XFS -
0
M/Z
9
¥ ^r ?i^
1 1359872
186
92 107
!i \\. .
58 180 150 ! 250 ' 380 358
8268B 54 (11,251) o-Xylene FIND
100:
1
04
M/Z
9
39 51
f •- ??
JJ /.,. j.|D ,.li, .
1 188
186
?2 107
al
58 168 258 388 ' 358
-------
C.D
09-04-98 20:57
Sanple: S-U-1-l-A T
Triangle Laboratories.! hie
214-1-1ft TL11146297
(919) 544-5729
Instrument H
HU985 367 (3.670)
„ 2678592
100-
XFS
J
M/Z
4
1
55
. J
86
71 |87
50 109 158 209 258 300 350
HU905'367 (3.671) REFINE
S7 2266992
1001
•
XFS
4
-r**-*
M/Z
1,3
55
86
71 3?
50 ' 100 ' 158 200 250 380 350
826BX 11 (3,660) n-Hexane FIND
S7 100
100^
•
X.FS
•
-
H'"'Z
a
L
56
l
l
55
!
86
71
50 iee 15S 258 300 350
-------
•• . '.;'•'•,; :; ' ';-•."' • :';':: .--' ;:;-;;:Pacllic Enviammental Services ' ' ;. ;. :.; ; :.;,,;1:; />•'.. :
Project Number: 46297
Sample File: HW906
Client Project: Hotaux
TLI ID: 214-1-2A:
Method 8260 VOST
Sample ID: S-V-1-2-A
V; '•"'. ': W 1 :^:;?j$&&&$. $j$&$^*& ;fe ;
•"v ;•:;••-..- \'*::;::J^>jli^^
" ' v ..:'. ..!.'.;.;.;. .' •.
: .. '! • -. •:'''"-':':'-:'"- '•'/'
•
te*» . •.;-;.. , ; j /;A^,|^:||^jy;T p*t«. :y -.£-«.
Pentafiuorobenzene
Chloromethane
Vinyl Chloride
Bromomethane
Chloroethane
Trichlorofluoromethane
1,1-Dichloroethene
lodomethane
Carbon disulfide
Acetone
Allyl chloride
Methylene chloride
Acrylonitrile
trans.-! ,2-Dichloroethene
1 ,1-Dichloroethane
Vinyl acetate
cis-1 ,2-Dichloroethene
2-Butanone
Chloroform
1,1,1 -Trichloroe thane
1 ,4-Difluorobenzene
Carbon tetrachloride
Benzene
1 ,2-Dichloroethane
Trichloroethene
1 ,2-Dichloropropane
IS 1 5-04
0.160 B 0.96
U
0.033 BJ 1.47
U
U
U
U
U
0.653 B 2.66
U
U
U
U
U
U
U
U
U
U
IS 2 5.78
U
0.728 B 5-24
U
U
U
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.006
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
NA- Not Applicable; Det. Limit Detection Limit; Quan. Limit: Quantitation Limit
IS: Internal Standard; U: Undetected; B: Present In Blank; J: Estimated- Below Quantitation Limit; E: Estimated- Above Calibration
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
Range
Triangle Laboratories, Inc. Savar v3.7
801 Capitola Drive • Durham, North Carolina 27713 Printed: 13:41 09/07/1998
Phone: ("19) 544-5729 • Fax: (919) 544-5491
-------
'"'.=• Pacific Envimmnetital $eivice$ ' :<
Project Number. 46297
Sample File: HW906
Qient Project Hotmix
IU ID: 214-1-2A
Date Received: 07/25/98
Dale Analyzed : 09/04/98
Method 8260 VOST
Sample ID: S-V-1-2-A
Response File: ICALH904
Aiwlyte
Methyl methacrylate
Bromodichloromethane
cis- 1 ,3-Dichloropropene
4-Methyl-2-pentanone
Toluene
trans- 1 ,3-Dichloropropene
1 ,1 ,2-Tnchloroethane
Chlorobenzene-d
Tetrachloroethene
2-Hexanone
Dibromochloromethane
1 ,2-Dibromoethane
Chlorobenzene
Ethylbenzene
m-/p-Xylene
o-Xylcne
Styrene
Bromoform
1 ,4-Dichlorobenzene-d
Cumene
1 .1 ,2,2-Tetrachloroethane
". Amount ••- .•H&jG?" ";.-•; .">KT ;.-•- i."
eg -'- ".'••;" : • ' ''- •;.:-'•'
U
U
U
U
2.010 BE 7.76
U
U
IS 3 Low 9.98
U
U
U
U
U
1.292 BE 10.33
7.039 BE 10.59
2.084 BE 11.29
U
U
IS 4 15.14
U
U
Det Limit ; "": :;'.Q«Mt. Limit
tig j '• ' ' ,.:4 ttg - i::
0.002 0.05
0.001 0.05
0.001 0.05
0.001 0.05
0.05
0.001 0.05
0.001 0.05
0.001 0.05
0.002 0.05
0.001 0.05
0.001 0.05
0.001 0.05
0.05
0.10
0.05
0.001 0.05
0.002 0.05
0.001 0.05
0.001 0.05
NA- Not Applicable; Det Limit Detection Limit; Quan. Limit Quantitation Limit
IS: Internal Standard; U: Undetected; B: Present In Blank; J: Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
Triangle Laboratories, Inc.
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Savarv3.7
Printed: 13:41 09/07/1998
-------
Pacific l&vfeonmental Services
Project Number. 46297 Method 8260 VOST
Sample File: HW906 Sample ID: S-V-1-2-A
Client Project Hoimix
rtJ ID: 214-1-2& =
Bate Received:
Date Analyzed
0W25&S
: 09/04/98
Response File:
ICALH9M
Surrogate Samm«?K ; . : :
Dibromofiuoromechane
Toluene-d
s
4-Bromofluorobenzene
•^^if':^:
0.332
0.360
1.036
'^rff^'
4.91
7.66
12.30
.Y»i»r;_,.- ....
1
2
2
%KEC
133
144
414
Reviewed by.
NA- Not Applicable; Det Limit: Detection Limit; Quan. Limit: Quantitation Limit
IS: Internal Standard; U: Undetected; B: Present In Blank;): Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
Triangle Laboratories, Inc. Savar v3.7
801 Capitola Drive • Durham, North Carolina 27713 Printed: 13:41 09/07/ 199E
Phone: (919) 544-5729 • Fax (919) 544-5491 ', 6 3
-------
Pacific Environmental Services
Project Number. 46297 Method 8260 VOST
Sample File: HW906 Sample ID: S-V-1-2-A
Client Project: HotaiJx Dale Received: &7/1&98 Response File: ICALH9G4
T131D: 214-1-2& ";:-f JV'"' . ' " . V
v Dale Analyzed: 09/04/93
Analyte
Pentafluorobenzene
1 ,3-Butadiene
Vinyl bromide
n-Hexane
1 ,2-Epoxybutane
Iso-Octane
1 ,4-Difluorobenzene
Ethvl acrvlate
. ;.A-~|;^::::
ISl
u
u
3.320 BE
U
U
IS 2
U
: ;Y;&£: '.:•: : tf:C Det Lintit . 1 :: •.
5.04
0.001
0.001
3.65
0.049
0.001
578
0.001
Qaan. Umit
0.25
0.25
0.25
0.25
0.25
0.25
Reviewed by S& Date °l I I
NA- Not Applicable; Det Limit: Detection Limit; Quart. Limit Quantitation Limit
IS; Internal Standard; U: Undetected; B: Present In Blank; J: Estimated. Below Quantitation Limit; E: Estimated- Above Calibration Range
Triangle Laboratories, Inc. Savar v3.7
801 Capitola Drive • Durham, North Carolina 27713 Printed: 14:51 09/08/1998
Phone: (919) 544-5729 • Fax: (919) 544-5491 , \ O A
-------
DO
aa
(D 0)
• •
n 3D
. CD
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i
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986HH
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CD
01
-------
."JUAN OB : HW°Oe>
No. MAT FOP REV Delta
LA8-8ASE QUAN
Area P.FLaos RT
0 9 ~o 5-'•'•'8
QM Name
1
__••
sj
4
5
,-,
7
3
••j
10
11
12
13
14
15
lr>
17
1.8
1°
•>( )
*• .t
21
2 '2
"S "?
24
*"> C
26
•7' "f
28
29
30
31
.52
T" ~
34
35
3 6
— • — r
O /
38
3°'
40
41
42
43
44
45
46
,-i~7
<-t /
48
49
50
40
"D /
•O /
0
0
4 5
0
0
0
0
u
O
0
0
0
o
98
0
O
o
0
0
i j
c>
fi
i. j
0
o
0
o
100
o
0
0
I)
4o
O
O
37
1OO
0
0
0
0
O
4-7
i
0
0
0
14
34
-..-,
0
O
2'?'
ft
0
u
O
o
l)
o
0
o
0
_, _,
0
f 1
• 7;
1 '1
i )
U
1 J
O
0
0
1 )
i J
o
o
"f ~7*
i j
O
0
l)
48
O
0
•?9
78
0
0
O
0
0
O yi
-i.^
0
0
0
51
C "7
38
O
0
45
O
O
0
0
0
0
o
0
1 )
0
88
n
r i
,1 i
•T i
O
0
1)
o
o
o
0
o
n
0
0
09
0
(D
0
0
c cr
o
0
e>6
97
0
0
O
0
0
>f*:
OO
0
0
0
•"*.
1
2
O
o
r)
0
O
f)
O
0
0
0
o
n
O
7'
i )
M
f 1
1 1
1 1
' '
1 1
0
(.1
o
1 J
n
0
0
0
0
0
0
~ 1 "l
o
0
-lo
1
o
0
0
0
0
0
. 0
0
2564508 bv
2745284 bv
1483892 bv
1082912 A
1509&88 A
4 2 1269 3 bv
5776848 A
0
MlS^ £O -**1*™
0
ni5^>3 **- 21800 vv
0
0
O
0
0
IvJ'i^iiJIJ ,f UU VV
0
0
0
5.04
5 . 78
9 . 98
15. 14
4.91
7 . 66
12 .30
O . 00
«a..oOOfl(
O.OO
Q. O'>\.M1
0 .OO
0 .00
O.OO
'.) .OO
0 .0')
2 . cv-'
i ) i : l )
O . Qi. J
• '- _r-f\
- • ••"--' TV|
O . C ; i ;
' ) . 'JO
ij . i JM
i') . ' JO
C, . Oi'i
0 .')'.'
O ,. i "iu
0 . OO
O . OM
0 . 'jrj
O .. OO
5 .24
O . OO
O ,. OO
0 . 00
0 . 00
i /iCi ?J*
O . 00
0 , OO
7.7to
0 . 00
0 . 00
0.00
0.00
0,00
O „ 7 _> P *
0.00
0.00
0.00
168 Pentaf I uoroDenzene
1 14 1 , 4-0 if 1 no robe n z.e ne
1L7 Chlorobenzene~dS
1 5 2 1,4 -D i. c h 1 o r obe n ^e ne-d4
113 Oibromot Luorome thane
i")8 Toluene-d8
95 4 -f?romof 1 uoroben^ene
35 Dlchlorodi f iuoromtetnane
p 5O C h i o r ome t ha ne
•-> 2 V 1 1 T v 1 Chi o r i d e
' 94 B r omome t. ha ne
•-J 4 C h L o r o e t h a n c>
j. f ' 1 T r i. c h 1 o r o t 1 1 jo r ome n ha oe
°6 .1 , ! - 0 t '': hlo roe t he ne
L a 1 lot -.', o m e t h a n r;-
7fj Corb.jti .i I -M.I i f ide
•4..". fv_. •-•!:' vie
j ;. :i ,. i. ':/l ch lor ide
8 4 ii ft t h v t .'5 1 1 e i : h l o r i s j c-:
l"~* il""'"*'.. !."ll — I! *~f"1 1 ''
. „' , H ' i ... i 1 ,' 1 1 '. U F L 1 '7-
'"•'^- t r .1 n'7. - j. , 1' ~ 0 i. c h Lor o." 'c f ie rj<
o--" .1. . i. -O i'. h 1 o roe thane
43 V i ny J a cat,':) .;e
'~ 7 ?: 7 - 0 i ' : h L o r op r > j pa ft-'?
•->£< c i. •: - 1 , ?-LI i '-.h I or o*:- fcner te
•43 2 - 6utd.no ne.
83 i"J in J. '.Vii furm
L 23 8r'"jmoch Lore. me thane?
1 ' 7 1 , 1 , 1 - T r L o h i o r o<~ t han'-r
1.17 C.-irbon t3 trach lor ide
75 1,1 -D L c h 1 o rop rope ne
78 3eu::ene
•-J 1' 1,2- D i c h '. o r o e t, ha n c
1 3 o T r i c h 1 o r o e then e
6 3 1,2-Dichlo r o p r ooa n Q
9.3 0 i. b r ornome t ha ne
4 L M e t h v 1 m e t h a c r v J a t s
83 Gromodlch lorornetnane
75 cis.-l , 3-DIchloroprooane
43 4~i/iethvl-2-pentanorie
9? Toluene
75 trans-1 , 3-D ichloroorope
97 1,1,2-Trichloroethane
69 Ethyl met hacry late
164 Tetrachloroethene
76 1 ,3-Oichloroprooane
43 2-Hexanone
1.29 0 ibromochioromethane
107 1,2-Dibromoethane
112 Ch iorobenzene
Data Re view:
Date.-
6r»
O
-------
No. MAT FOR REV Delta
Area P.Flags
RT
QM Name
51
52
53
54
55
56
57
58
59
60
61
c>2
63
.^4
65
o6
t'7
^ .~,
69
7O
71
7 2^
73
74
75
/ fj
~7 "T
73
79
0
75
SO
77
0
0
O
0
0
0
u
O
0
0
c, c.
o
85
U'"'
**T i-
0
0
0
77
0
0
r)
0
0
0
0
47
57
55
0
i)
ij
i)
o
0
(.>
o
0
1 J
48
0
5?
] 1
L .1.
0
f j
0
43
O
0
O
0
0
o
0
82
84
85
0
0
o
o
0
0
G
i)
0
0
•-•)?
0
05
c O;
74
i.l
0
O
83
r.)
0
o
0
G
o
0
2
4
4
O
O
0
O
O
0
0
G
f"(
G
-16
O
o
-.
--
0
0
G
~ 1
r)
fj
G
r>
G
O
0
3680059 vv
24651810 vv
6329438 bv
0
G
O
G
0
G
0
0
o
G
2&44487O vv
O
l.67i;O4lO bv
&25205^ bv
O
O
G
2U4'2t>O2 '-'V
0
O
G
( i
0
0
0.
10.
10.
11.
0.
0.
o.
G .
0.
0.
0,
0.
G.
G.
1.3.
G .
14.
IS.
i j ..
O .
G .
i<\-.
0 .
0.
G.
G .
0 .
G .
00
33
59
29
OO
GO
00
00
OO
GO
00
GO
GO
on
IS
00
3O
"'< ~J T"
i'll )
On
on
88
iX>
GO
OO
00
on
, on
131
106
1O6
106
104
173
105
33
156
-r c
120
75
126
126
1,1., 1,2-Tatrachloroett
E thy L benzene
m-/p-Xy "i ene
o-Xy lene
Styrene
Sromof of m
Cumene
1,1,2, .:•- fet rac h 1 o roe t
8 r omobe nz e ne
1 , 2 , 3- T r i c h 1 o rop rop.
n-Propy L benzene
t r a n:-.; - 1 , -4-0 i c h 1 o r o -
2 -C n i o r o to L ue ne
4 - C h i o r o toluene
an
2-
i 0 5 1,3, 5 - 1 r i fn<-:. t h v i b e n ..: e n
1.1'-'
105
'f^ 111 v~,
]Lx 1. ' ' .. '
14t
140
'? 1.
I:M
L4<,
/ — '
180
O '*i C
j/:.8
L8O
t e r t - 8 1 i r y :. b e n ^ .= r ' e
1 , 2 4 - T r i me t ny 1 be n re n
• -• — •• i * — !"•' i i t~ *• i 1 I"* i i i i ~* icj i i *
.»' '-_ ' • l ' 1- / i. ! ''',. II .._ ^ ' lc~
(:•- Oymene
1 , ~j G i ' :. 1 1 i. of o b K: n ;:. '•: n . ••
l , i - 0 i c h 1 o cabe nz -: n.- .•
i-"-;'--n::y L oh lor i. o..i
1 1— 81 i t". / 1 be n j;e ru:-
1 , I - u i > : h i. ' j f ' j b e n ,:: .:r- n •.-•.
L , 2-0 i br ornc-3~oh i<~)\-
i. 2 , 4 - T i • i c; h 1 o robe n z.
H e .- a o h i. o r o b i j t. a a i e ri e
Naphi:!ia lane
1,2,3-Triohi o r o b e ri z
or
..-u
•2t
67
-------
WUAN DB
HW906
LAB-BASE QUAN
09-07--98
09:3-1
No, MAT FOR REV Delta
Area P.i-lags
RT
QM Name
1
••*>
"7T
4
c.
6
0
9
10
11
14
40
57
57
0
0
46
0
0
70
10O
C, 1
43
14
34
22
0
0
29
0
0
5 4
1 £
t- '1
23
51
57
38
0
0
45
0
-7 TT
0
60
99
68
0 2564508 bv
2 2745284 bv
1 1483892 bv
0 1082912 A
o 0
-1 4212693 bv
0 0
0 0
-1 15633420 vv
5.04 16P
5 78 114
9.98 117
15.14 152
0.00 113
7 . 66 98
0.00 95
0 . 00 106
3.65 57
Hentaf 1 uorobenzene
1 ,4-0 if 1 uorobenzene
Chlorobenzene-d5
1 , 4-Dich Lorobenzene-d4
Dibromof 1 uoromethane
Tol uene-d8
4-Bromof Luorobenzene
1,3 B i j t A d I s n e
Vinvl bromide
MTBE
n-Hexarie
1 , i. cpo;' vbi itane
Ethyl aery late
Data Review:
63
-------
-ss
ese 00e
00T
am A
0se oee
> .... > .... i ..,
0^T9
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09-04-98 21:26
Sanple: S-U-1-2-A
Triangle Laboratories=
214-1-2A TLIff
ie,
(919) 544-5729
Instrument H
HW906 266 (2.668)
188
, 43
XFS
•jjj
146432
58
5?
8-
w/z 58
59
•i r^-l ^
180
HU906'2*66 (2,661) REFINE
I88i 43
150
260
258
388
356
XFS
0
M/Z
99328
58
58
100
158
200
258
388
358
8260B 17 (2,650) Acetone
1801 43
XFS
8
M/Z
FIND
188
58
50
100
150
208
258
308
358
-------
3
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09-04-98 21:26 Triable Laboratories
Sample: S-U-1-2-A T 214-l-2ft TLJH46297
(919) 544-5729
Instrument H
HW906 776 (7.761)
100T "L
XFS
8
?9 5565^89
I fj i iti Hi if 1 1 !* i i
•j£
97
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* I i " " i " * • " ! * ' ' " ' t • * !'-" [-
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HU906'776 (7.761) REFiNC
9j[
XFS
H-
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..... ,3i .4- -, 'i
92
93
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8260B 41 (7.761) Toluene
91
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M/Z
39
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92
93
50 108 ' 158 ' 200 250
2949120
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308 358
2588672
308 356
FIND
100
388 358
-------
]>
89-04-98 21:2& Triangle Laboratories, Inc. (y!9) 544-57Z9
Sanple-' S-U-1-2-A X 214-1-2A TL1146297 Instrument H
100
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HU9C
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9
5.1 65 77
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50
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1 1425488
111
9? 1 126
100 ' 150 ' 200 258 ' 308 350
1) REFINE
1 1179648
THI
180 158 259 308 350
Etliulbenzene FIND
1 100
TI07
i0cs 150 2^8 300 350
(H,
-------
to
89-04-98 2!:2fa THamile Laboratories, Inc. (919) 544-5729
: S-U-1-2-A T 214-1-2A TLItt4b297 Instrument H
HW986 1059 (10.591)
180]
91
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2293760
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1,5
180 150 280 250 380 350
(10.551)
69 ??
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M-/p-Xylene FIND
100
1^
92
*6
108 150 250 300 350
-------
89-84-98 21:26 Triairily Laboratories, !nc,
Sanple: S-U-l-2-fl T 21471-2n TLIH46297
(919) 544-5729
Instru.roent H
HU9E
100-
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6
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xrs-
8-
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16' 1129 (11.29
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51 £.5 ','
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1) REFINE
± 1441792
106
?5, 107
id.
58 100 150 200 250 388 350
IB 54 (11,251)
9
39 51
ts 7?
! ' i -" !
,ik li> Jl „ Ms
o-XuIene FIND
1 100
186
?2 107
i i! :
50 10Q 150 250 380 350
-------
3
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77
-------
Project Number. 46297
Sample File: HW901
Client Project: Hbim&
TLI ID: 214-1-2S
Pacific EnviEoranental Services
- ;•>• ";£":. : .",...", .-:::
'v. '. '
Method 8260 VOST
Sample ID: S-V-1-2-B
Date Kec€ived: 07&S&&
Date Analyzed 1 09/04/93
Response Kiss ICALH9M
Analyte ;
Pentafluorobenzene
Chloromethane
Vinyl Chloride
Bromomethane
Chloroethane
Trichlorofluoromethane
1 .1-Dichloroethene
lodomethane
Carbon disulfide
Acetone
Allyl chloride
Methylene chloride
Acrylonitnle
trans- 1 ,2-Dichloroethene
1 ,1-Dichloroethane
Vinyl acetate
cis-1 ,2-Dichloroethene
2-Butanone
Chloroform
1,1,1 -Trichloroethane
1 ,4-Difluorobenzene
Carbon tetrachloride
Ben/ene
1 ,2-Dichloroethane
Tnchloroethene
1 ,2-Dichloropropane
•. • ; *^»|; :*f :,;;,.;•; ^^ ;
IS 1 5.04
0.299 B 0.96
U
0.091 B 1.48
U
U
U
U
U
0.007 BJ 2.67
U
0.004 BJ 3.05
U
U
U
U
U
U
U
U
IS 2 5.77
U
0.043 BJ 5.24
U
U
U
.MO* :. -.••:
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.005
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
Quan. limit
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
NA- Not Applicable; Del. Limit: Detection Limit; Quart. Limit: Quantitation Limit
IS: Internal Standard; U: Undetected; B: Present In Blank; J: Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
Triangle Laboratories, Inc.
801 Capitals Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
7B
Savar v3.7
Printed-13:53 09/07/1998
78
-------
Pacific Baviionmental Services
Project Numben 46297
Sample File: HW901
Client Project Hotmix
TLUD: 214-1-2B
Method 8260 VOST
Sample ID: S-V-1-2-B
Date Received: 07/25/98
Dale Analyzed : 09/04/98
Response File:
ICALH904
Analyte
Methyl methacrylate
Bromodichloromethane
ci.s-1 ,3-Dichloropropene
4-Mi:thyl-2-pentanone
Toluene
tram-1 ,3-Dichloropropene
1,1 .2-Trichloroethane
Chlorobenzene-d
Tetrachloroethene
2-Hexanone
Dibromochloromechane
1 ,2-Dibromoethane
Chlorobenzene
Ethylbenzene
m-/p-Xylene
o-Xylene
Styrcne
Bromoform
1 ,4-Dichlorobenzene-d
4
Cumene
1 ,1 ,2,2-Tecrachloroethane
.-.•.-/ ;:-VAM^t^;p/^l^&;';.i/->::::^XV. ; '•'
:• •;'• -':; •"'•'•>' eg '^ /*£?';• " .^' '"'-; •'••'•'.;' • ; ' •
u
U
u
u
0.005 BJ 7.74
U
U
IS 3 9.94
U
U
u
u
u
u
0.001 BJ 10.54
U
0.002 BJ 11.29
U
IS 4 15-04
U
U
'..^Efeifcliiriit.l ^.;-7-
, •'"'.' :«g '•• •-•"•'
0.002
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
t>uan. tualt
a*
0.05
0.05
O.US
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.10
0.05
0.05
0.05
0.05
0.05
NA- Not Applicable; Det Limit: Detection Limit; Quan. Limit: Quantitation Limit
IS: Internal Standard; U: Undetected; B: Present In Blank; J: Estimated- Below QuantitaHon Limit; E: Estimated- Above Calibration Range
Triangle Laboratories, Inc.
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Savar v3.7
Printed: 13:53 09/07/1998
0 , 79
-------
Pacific Enviajmnental Services
Pro j ect Number 46297 Method 8260 VOST
Sample File: HW901 Sample ID: S-V-1-2-B
Client Project: Kotmix Date Received: 07/25/98 Response File: ICALH904
TU ID: 214-1-2B
Date Analyzed 109/04/98
Surrogate Summary ; :
Dibromofluoromethane
Toluene-d
s
4-Bromofluorobenzene
.'" *&fe
0.286
0.285
0.331
'•• ' : RT. •' j;
4.91
7.64
12.22
: '•' fSRef ' ;. '
1
2
2
%KEC -,'.
114
114
132
Reviewed by _ Date
YR
NA- Not Applicable; Det Limit Detection Limit; Quan. Limit Quantitation Limit
jjJ: Undetected; B: Present In Blank; J; Earimated- Below Quantitarion Limit; E: Estimated- Above Calibration Range
Triangle Laboratories, Inc. Savar v3 7
801 Capitola Drive • Durham, North Carolina 27713 Printed: 13:53 09/07/1998
Phone: (919) 544-5729 • Fax: (919) 544-5491 . i O ^
Bo .
-------
Project Number 46297 Method 8260 VOST
Sample File: HW901 Sample ID: S-V-1-2-B
Client ProjecfcHotmix Date Received: &7/2S/98 Response File ICALH904
TI3ID:214-1-2B
Date Analyzed: 09/04/98
AmJyte
Pe n tafluorobenzene
1,3-Butadiene
Vinyl bromide
n-Hexane
1,2-Epoxybutane
Iso-Octane
1 ,4-Difluorobenzene
Ethvl acrvlate
A»o«c* HAG
ISl
U
U
0.001 BJ
U
U
IS 2
U
RT
5.04
3.65
5-77
Det Limit "••>'"•>:
0.001
0.001
0.039
0.001
0.001
«8
0.25
0.25
0.25
0.25
0.25
0.25
Reviewed by ^^A!\J\T Date
NA- Not Applicable; Det Limit Detection Limit; Quan. Limit: Quantitation Limit
IS; Internal Standard; U: Undetected; B: Present In Blank; J: Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
Triangle Laboratories, Inc. Savar v3
801 Capitola Drive • Durham, North Carolina 27713 Printed: 14:51 09/08/191
Phone: (919) 544-5729 • Fax: (919) 544-5491
>. VJ • - Ol
-------
DO
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-------
wrea P.FLags
RT
QM Name
1
2
3
4
5
6
7
3
9
10
11
12
13
14
15
16
17
18
19
2O
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
56
37
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1
2
3
'4
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100
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100
100
100
100
100
0
100
0
100
0
0
0
0
0
63
0
0
35
0
0
0
0
0
22
0
0
0
0
0
100
0
o
0
0
51
0
0
43
91
0
0
o
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0
0
0
0
0
81
96
95
79
88
0-2
89
0
89
0
76
0
0
O
0
0
20
0
0
0
0
o
0
0
19
0
0
0
0
0
98
0
0
0
0
41
0
O
3
60
0
0
0
0
0
0
0
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0
99
98
95
98
99
97
93
0
100
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99
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88
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33
0
0
0
0
0
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0
0
0
0
41
0
0
69
89
0
0
0
0
0
0
0
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0
2
0
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0
3
0
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0
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0
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o
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0
0
1
0
0
0
0
1
0
0
1
0
o
0
o
0
0
0
0
0
3214290 bv
3092276 bv
3588320 bv
1392685 bv
1626872 bv
4475694 bv
2479848 bv
0
985143 bv
0
387988 bv
O
O
O
0
O
12552 vv
O C, >i A. ,'-,
O
O
O
O
0
0
o
0
0
0
728896 bv
0
0
0
0
•20.4.0 w-
0
0
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58456 bv
O
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0
0
0
0
0
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0
5.O4
5.
9.
15.
4.
7 ..
12.
0.
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77
94
04
91
64
22
00
96
00
48
00
00
00
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OO
67
168
114
117
152
113
98
95
85
50
62
94
64
101
96
142
76
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0 . 00
0 .OO
0 .00
0 . 00
0
. 00
o.oo
0 . 00
0 . OO
5 , 24
O.OO
0 . 00
0.00
o
o
0
7
0
0
0
0
0
0
0
0
0
.OO
. 62
.00
.00
.74
.OO
.00
.OO
.OO
.00
.OO
.00
.00
.OO
A * **
'So
43
7 7
9o
~f* 43
83
128
97
117
75
78
62
13O
63
93
fY3 41
83
75
F(P 43
92
75
97
69
164
76
43
129
107
112
Pentaf luorobenzene
1 „ 4-D i f luorobenzene
Chlorobenzene~d5
1 , 4-D ichlorobenzene-d4
Dibromof 1 uoromethane
Tol uene-dS
4-Bromof luorobenzene
Dich lorod i f 1 uoromethan<
Chlorome thane
Vinyl Chloride
8romoinethane
Oh I o roe thane
Tr I ch lor of 1 uoromethane
1 „ 1 -D I c h 1 o r oe t he ne
lodomethane
Carbon disulfide
Acetone
A I iy 1 chloride
he t hy I e ne c h tori de
Aery Ion i tr i J,e
trans-1 , J-D Ichioroetheru;
1 , 1-D i ch lor oetha ne
Vinyl acetate
2 , 2-0 ich loropropo. ne
ci 3-1 ,2-0 Lchloroetnene
2--Bu t a none
Chloroform
8 r omoc h i o r ome thane
1 , 1 H 1-Tr ichloroethane
Carbon tetrach lor ide
1, 1-Dichioropropane
Benzene
1 ., 2-Dichloroethane
Tr ichloroethene
1, 2-Dichloropropane
Dibromomethane
Methyl methaorylate
Bromodi chlorome thane
cIs-l,3-Dichioropropene
4 Methyl z pentanone
Tol uene
trans-1 ,3-Dichloropropen
1 ., 1, 2 -Tr Ichloroethane
Ethyl methacry late
Tetrachloroethene
1 ,3-Dichloropropane
2-Hexanone
Dlbromochloromethane
1 ,2-Dlbromoe thane
Chlorobenzene
Data Review: M?
Date:
-------
No. MAT FOR REV Delta
Area P.Flags
RT
QM Name
51
52
53
54
55
56
5—»
i
58
59
t>0
61
o2
63
e-4
65
66
67
t
08
69
70
71
?•"•
73
7-4
75
7o
77
73
7'r^
0
0
0
0
*52
0
A "~f
4 /
0
0
0
0
0
0
0
O
0
54
0
to 3
0
0
0
0
0
60
51
50
61
0
0
0
0
79
0
>i ,*
44
0
0
0
0
0
o
0
0
0
35
0
4 2
O
0
0
0
O
50
24
36
47
0
0
O
O
79
0
44
O
0
0
0
0
0
0
0
0
c o
54
0
64
0
O
0
0
O
'V3
73
65
73
0
0
0
0
3
0
6
0
0
O
o
0
0
0
0
0
,4
•4
~ 1
0
2
0
0
0
0
0
8
7
10
s
0
0
SX'W-**"*^
0
21660 bv
0
0
0
0
O
0
o
0
0
0
J-Xt-'U"? H
0
3732 A
0
O
0
0
0
164*56 bv
589t< bb
23396 bv
14240 bv
0.
0.
0.
11.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0 .
.£)-.
0 .
14 .
0 ,
1.1.
0.
0.
0.
1'^ .
1° .
19,
. 19,
00
00
eeuxs*
00
29
00
OO
00
oo
00
oo
oo
00
00
oo
io^s
oo
32
OOv^
Or)
00
00
OO
13
33
35
54
131
1O6
-(106
106
1O4
173
> 105
33
156
75
120
75
126
126
105
119
b 1 1^1 C
' .LOb
• j_o5
14&
146
91
91
14o
75
ISO
225
123
130
1, 1,1, 2-retrachioroethar
E thylbenzene
m-/p-Xylene
o-Xy lene
Styrene
Bromof orrn
Cumene
1 , L , 2 , 2- Te t r ac hi o roe Chan
Bromobenzene
1,2,3-Trtch Loropropane
n-Propy 1 benzene
t r a ns - 1 , 4 - 0 L c h i. o r o-2-bu t
2-Chlorotol uene
4 -C h L o r o to 1 ue ne
1 , 3 , 5-Tr i me thy I benzene
te r t -8uty 1 be n zene
L ,2-,4~Tri flie t h v 1 oe n x'e rus
'^ C5 C ~ B U fc V 1 bfenZcJDfr
p-Cymene
1 , 3-0 ich lorobenz-eri
-------
QUAN DB : HW901
No. MAT FOR REV Delta
LAB-BASE QUAN
Area P.Flags
09-04-98
19:1
RT
QM Name
1
2
3
4
5
6
7
9
1 f^l
JLU
11
1^1
Ivi
14
100
100
100
100
100
100
100
2
0
A s\
*+'-)
62
7 1>
56
43
81
96
95
79
88
92
89
•Li /
Q
-Tf,
oo
47
-jt>
<4 v.'
3 ^"
99
98
95
98
9 o
97
93
/ 1
0
/\ -\
t+±
56
* -7
to /
52
66
0
1
-2
2
1
— 1
-1
0
c
O
-i
4
-14
3214290
3692276
3588320
1892685
1626872
4475694
2479848
0
6016
J3tgk
%JX'.Jl^O
i |--,q7,-jq_
bv
bv
by
by
by
by
by
A
5*5
ImrP
168
114
117
152
113
98
95
TO
oV
106
— .—
57
-*-
T57
55
Pentaf 1 uorobenzene
1, 4-DIf 1 uorobenzene
Chlorobenzene-d5
1, 4-Dlchlorobenzene-d4
0 ibromof 1 uorome thane
Toluene-d8
4-Bromof 1 uorobenzene
1 , 3— B utad 1 e ne
Vinyl bromide
MTQfT
n i ot
n-Hexane
1,2 tpoxybutanfe
Iso-Octane
EthvJ acrvlate
Data Review:
Date: a/jfa&y
85
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O3
09-04-98 18:28 Trianyle Laboratories, Inc.
Sanple: S-U-1-2-B T/C 214-1-2B TLIH46297
(919) 544-5729
Instrument H
HU901 1129 (11.291)
100
XFS
0-
1B4 248O
183
78
7fi
48 5i
i
182
i
*
185
| . • • | .... | . 1 ' 1 ' • !•'•'! ... | ......... | .... , ......... |
Wz 50 108 158 288 258 308 358
HU901'1129 (11.291) REFINE
100
XFS
0
1«
51 77 183
78
14 1768
185
n/z 58 108 ' 158 ' 288 258 ' 308 358
8260B 55 (11.311) Styrene FIND
100
XFS
0
5
i
J... . •
1C
183
1 76?8 182
63
.
-------
-04-98 18:28 Triable Laboratories,
Sample: S-U-1-2-B T/C 214-1-2B TL1
inc. (919) 544-5729
Instrument H
HU901 365 (3,658)
100
XFS
o
H/Z
<
|
14 1728
5
7
89
IT
50 188 15S 208 258 380 358
HU901'365 (3.651) REFINE
100-
XFS
0
H/Z
43 5
56
7 956
89
50 IBS 158 258 380 359
826BX 11 (3.660) n-Hexane FIND
100
XFS-]
0-
M/Z
5
41
j
56
55
7 100
86
, V 1
50 180 ' 158 250 ' 380 350
(X
-------
raaficE^nn^Se,,.^
Project Number 46297
Sample File: HW907
Client Project Boimix
lU ID: ZS4-1-4&
Date Received: 07/25/98
Dale Analyzed : 09/04/98
Method 8260 VOST
Sample ID: S-V-1-4-A
Response File: ICALH904
Analyte : ..
Pentafluorobenzene
Chloromethane
Vinyl Chloride
Bromomethane
Chloroethane
Tnchlorofluoromethane
1 ,1-Dichloroethene
lodomethane
Carhop disulfide
Acetone
Allyl chloride
Methylene chloride
Acrylonitrile
trans- 1 ,2-Dichloroethene
1 ,1 -Dichloroethane
Vinyl acetate
cis-1 ,2-Dichloroethene
2-Butanone
Chloroform
1,1,1 -Trichloroethane
1 ,4-Difluorobenzene
Carbon tetrachloride
Benzene
1 ,2-Dichloroethane
Trichloroethene
1 ,2-Dichloropropane
.'.I '
IS 1 5.05
0.098 B 0.97
U
0.022 BJ 1 .48
U
U
U
U
U
0.349 B 2.65
U
U
U
U
U
U
U
U
U
U
IS 2 5.78
U
1.043 BE 5.25
U
U
U
!S3-"' ^:Q*a^:
0.05
0.001 0.05
0.05
0.001 0.05
0.001 0.05
0.001 0.05
0.001 0.05
0.001 0.05
0.05
0.001 0.05
0.001 0.05
0.005 0.05
0.001 0.05
0.001 0.05
0.001 0.05
0.001 0.05
0.001 0.05
0.001 0.05
0.001 0.05
0.001 0.05
0.05
0.001 0.05
0.001 0.05
0.001 0.05
NA- Not Applicable; Det Limit: Detection Limit; Quan. Limit: Quantitation Limit
IS: Internal Standard; U: Undetected; B: Present In Blank; J: Estimated- Below QuanHtation Limit; E: Estimated- Above Calibration Range
Triangle Laboratories, Inc.
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Savar v3
Printed: 13:41 09/07/19*
-------
Facife Euvironmenlal Seivices
Project Number: 46297
Sample File: HW907
Client Pi^ecfc:HoiniJ»;;
Method 8260 VOST
Sample ID: S-V-1-4-A
":^*3"-£::iJ^^
t V::"VVC'::,^D^^ '1 i:-
-: . .• "'-.-.•"' ....... . ^ .
s^^iWils^
:-'^4^''?--'^^ffi:i^
Analyte
Methyl methacrylace
Bromodichloromethane
cis-1 ,3-Dichloropropene
4-Methyl-2-pentanone
Toluene
tran.x-1 ,3-Dichloropropene
1 ,1 ,2-Trichloroethane
Chlorohenzene-d.
Tetrachloroethene
2-Hexanone
Dibromochloromethane
1 ,2-Dibromoethane
Chlorobenzene
Ethylbenzene
m-/p-Xylene
o-Xylene
Styrene
Bromoform
1 ,4-Dichlorobenzene-d
Cumene
1,1 ,2,2-Tetrachloroethane
•;-.j^:,|p|.-;..-M^.;'p
U
U
U
U
1.376 BE 7.76
U
U
IS 3 9.97
U
U
U
U
U
0.808 B 10.32
4.068 BE 10.57
1.203 BE 11.27
U
U
IS 4 15-12
U
U
^^ ;•:::. ^'^
0.002
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
.limit
l«
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.10
0.05
0.05
0.05
0.05
0.05
NA- Not Applicable; Det Limit: Detection Limit; Quan. Limit: Quantitation Limit
IS: Internal Standard; U: Undetected; B: Present In Blank;): Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
Triangle Laboratories, Inc.
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Savar v3.7
Printed: 13:41 09/07/1998
V
96
-------
Pacific Envtrqnmenlal Services
Project Numben 46297
S ;mple File: HW907
Method 8260 VOST
Sample ID: S-V-1-4-A
Client Project: Hotmix
Date Received: 07/25/98
Date Analyzed : 09/04/98
Response File: ICALH904
Surrogate SatftttuKjf T
Dibromofluoromethane
4-Bromofluorobenzene
" • • -. : '.''. •: • /.in^vV .'"• '•>:•.•:•: • .*:*:*:•:".•:•;• ':•- . •: .'. ." .' •.•' ' •: " .
. . . .- ' . . . . x mkjtf, •/. . ' . .•.,, :_:,; /"...: ;.,:-.,.... • . _ .
0.319
0.333
0.299
IftJI-
4.92
7.66
12.26
^M&
\
2
2
" %KEC
128
133
120
Reviewed by.
NA- Not Applicable; Det Limit: Detection Limit; Quan. Limit: Quantitation Limit
IS: Internal Standard; U: Undetected; B: Present In Blank; J: Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
Triangle Laboratories, Inc.
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
9*
Savar v3.7
Printed: 13:41 09/07/1998
37
-------
Pacific EnviionmentaJ Servicai^-:
Project Number. 46297 Method 8260 VOST
Sample File: HW907 Sample ID: S-V-1-4-A
Client Project: Hotmix Dale Received: &7/25/9S Response Fiie ICALH904
!
Date Analyzed: 09/04/98
Aiwlyte
• ". Aaa«^jr^' "l-;' jpEs/ySf '"/^'v-^fV' :•!%"• B*
& ' • ...""": .. " ' - -• - - ^
fc Linfcit . -"• ' -x'Ottro, tiflrft
Pencafluorobenzene IS 1 5.05
1.3-Butadiene U 0.001 0.25
Vinyl bromide U 0.001 0.25
n-Hexane 2.661 BE 3.67 0.25
1.2-Epoxybuiane U 0.036 0.25
Iso-Octanc 0.085 } 5-47 0.25
1.4-Difluorobenzene IS 2 5.78
Ethyl acrylace U 0.001 0.25
Reviewed by ___J^SfCtj Date °1 I 01
NA- Not Applicable; Det. Limit Detection Limit; Quan. Limit Quantitation Limit
__JS:Jnternaljtandard;jJ: Undetected; B: Present In Blank; J: Eatimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
Triangle Laboratories, Inc. Savar v3j
801 Capitola Drive • Durham, North Carolina 27713 Printed: 14:51 09/08/1998
Phone: (919) 544-5729 • Fax (919) 544-5491
^ . ., 93
-------
-------
OUAN DB : HW^O?
No. MAT FOP REV Delta
LAB-BASE QUAN
Area P.Fiaqs PT
Qh Name
1
^
3
4
5
o
~r
3
9
10
11
12
13
1-4
15
I'T.
17
13
I0
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_ ' t
21
'"""*
f-:, —,
24
25
26
27'
23
29
30
31
32
33
•54
35
36
37
38
3 '^
an
^T *•}
41
42
43
44
45
46
47
" «'
48
49
50
54
s.3
45
0
0
S&
43
0
O
O
78
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0
O
n
0
97
O
ri
"•••:..
— '--'
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0
o
o
n
0
0
o
n
0
0
100
0
0
0
0
47
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0
"4
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1OO
0
0
0
0
0
44
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0
0
0
21
44
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0
J-'U
25
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0
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75
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0
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0
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90
0
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43
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0
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30
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0
0
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88
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97
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34OOO3e> bv
2213572 bv
146256O A
19S6252 A
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20^2421 vv
0
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103776 bv
0
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0
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72517^ vb
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16427150 vv
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73
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26
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163
114
117
1 5 2
1. L3
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95
35
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62
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101
V
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76
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41
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128
97
117
70
73
62
130
63
93
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83
75
C f\ A~Z
YP 4xj
92
75
97
69
164
76
tsp 4-
\*~ t+o
129
107
112
i-'e n ta f i uo robe n ze ne
1 , 4-0 )- f I uoroben jene
C h 1 o r obe nze ne -d 5
1 . 4-D i c h 1 o r obe nze ne-d4
Di bromo r L uorom^tnane
fo 1. uene-dfri
4-Brornof L uorob^nzene
Dichiorodl f iuororne thane
Ch ).oromet;han^-
V i ny L G !i lor I^Je
Srofnome tha rid
C h i. or o-: thane
T f • i c h .tore ~> f i U' :> r > ->me t ha rie
I. 1-Oich i on-'>--'t;hK-nf-?
Tod off) e tnj n.-
C.:i r'r^on 1 i. •:•! 1 1 i: '. • ie
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h . :- r. h v e n e c h '! or i •-.') ^:-
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tr.inr:. - 1 , /'-i'' i ch i oroetnen?
i L-1'1 o. h !,,-)(••,.!... i~| i,.i r\>.-
V i. ny i a '.:•':•:):., it. r
2 . :-0 i.' h lor '-T^rooane
o i s -1 . 2-D Lohluroernen^
T-6i itari'.ine
C hioroi" or m
Bromoch iororn^thai ie
1 . 1 , 1 - T r i c h '. o r o r i; ha n f
C a r- bo n fc . » t r a c h Lor i. •'romoethane
Chlorobenzene
Data Review:
Date:
iao
-------
No. MAT FOR REV Delta
Area P.Flags
RT
QM Name
51
52
53
54
55
So
57
58
59
60
61
62
o3
o<4
65
o>5
67
^ 8
o9
70
71
7^
.'' ~'
74
"7 C
•' _'
76
77
78
79
0
78
84
Q2
0
0
0
0
o
0
0
0
0
0
47
0
78
0
0
0
0
0
60
0
0
0
0
0
0
0
48
59
56
0
O
0
0
0
0
0
0
0
0
4o
0
39
O
0
0
O
0
34
0
0
0
0
13
0
o
33
85
86
0
O
0
0
o
o
o
o
o
0
'•n
o
8'r-)
0
(.1
o
o
0
7'"1
o
0
0
0
0
o
0
2
3
3
0
0
0
0
0
0
(.1
0
0
0
--20
O
1
0
0
o
C'
(-1
0
0
0
o
0
>-]
(J
0
3432497 vv
21252240 w
5881031 vv
u
0
0
u
0
0
o
0
0
0
16403O70 vv
0
L 2^0 17 30 bv
0
0
0
0
0
4DO23O4 vv
•j
0
O
0
0
0
0
10
10
11
0
0
0
0
0
0
0
0
0
o
L3
0
14
0
0
o
C)
o
16
0
0
0
0
o
0
.00
. 32
.57
.. 27
.OO
.00
.00
.00
. 00
. 00
..00
, 00
.00
,00
.14
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.28
. 00
00
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131
106
106
106
104
173
1O5
83
156
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f -'
120
75
126
r:&
LO5
1 L°
105
L 0 5
11'?
146
14^
•"'L
•~) L
1.4.s
75
130
_ .„ _J
r>3
1HO
1, 1,1,2-TetrachLoroetha
Ethylbenzene
m~/p~Xylene
o-Xy Lane
Styrene
Bromof orm
Cumene
1,1,2, 2-Tetrach loroethc
8romoben,:ene
1 , 2 , 3- T r i. c h 1 o r op r opa ne
n-Propy I ban eerie
trans- i ,4 -Oioh Loro-2-bi.
2 - C h L o r o i: o L u e n e
4-Gh loroto 1 uene
1 , "i „ 5 - T r \ me t hy i. be n,-;e ne
tart-8u£ y 1. b f- n j a n e
1 ,2 , 4 - T r i ine 1: hv L b.-3 n ze i'ie
•5 e ' '' - 6 1 1 1 y i i. -• e n .;: e r i e
P-I." ymone
1 , 3-1 ' ic.'i J.'jro!:>«-.-n.^aM^
1. , 4 — D i. c h 1 o r o i.,1 e n >: e n e
8en.:v '- '"h ior i. ^1^
n-i-L utv Lbo-ri z4-: ne
I. , 2-0 i oh !.or.-ib.-;n..::^n.'-?
j. , 2 - 0 i b r n m o - 3 - c h L o r o p r
l. , 2 , 4- TV ioh Lorob'^nrene
H.°-- ,ac h J.orobut.sdi e t ie
Naphi"i'ia '. ene
1 , 2 , 3 -- T i - 1 c 1 1 1 o r o t> e i i z e n e
Date Review: ft
101
-------
3UAN DB : HW9Q7
Ho. MAT FOR REV Delta
LAB-BASE QUAN
Area P.Flags
00-07 -98
RT
QM Name
1
2
3
4
5
6
7
8
10
11
12
15
14
54
68
45
0
0
55
44
63
O
64
100
65
55
4"
21
44
27
0
0
36
25
41
0
50
Q 7
47
""fi
66
65
45
0
0
54
47
74
0
54
99
62
c, '",
69
1 35O9O64 bv 5
1 34OO036 bv 5
0 2213572 bv 9
0 146256O A
0 0
15
0
-1 4826^72 bv 7
1 2062421 w 12
0 0
V~ .L
0
0 17146230 w 3
~" ""Lcr-j_'rT':'>rift"'4'51~ "
-13 l.n,87.'T,F,?i:li-4g
V «*=«»***• Y**rfi6rt;
-te c
.05
.78
.97
.12
.00
.66
.26
-9^p
.00
.67
O^CLp
168
114
117
152
113
98
95
39
106
P -"-*
57
*J /
55
Pentaf 1 uorobenz^ne
1 , 4-DIf luorobenzene
Ch Iorobenzene-d5
1 , 4-Dichlorobenzene-cM
D ibromof 1 uorome thane
Tol uene-d8
4-8romof iuorobenzene
1,3-Butadiene
Vinyl bromide
MTBE
n-Hexane
1 -, 2-Epoxy butane
I 'so- Octane
Ethvl a cry late
Data Review. }/f
Date:
102
-------
CO
89-04-98 22:01
Sanple: S-U-1-4-A
Triangle Laboratorie
Z14-l-4ft TLIM6297
1 nc
(919) 544-5729
HU907 97 (0.970)
108 43
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108
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300
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100
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44
... . I,M
50
188
158
208
258
388
FIND
100
358
-------
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Triangle Laboratories. Inc.
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(919) 544-5729
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(919) 544-5729
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Triable Laboraropies, \uc, (919) 544-5729
Sample: S-U-1-4-A T ZH 1 4n TL 184629
97
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51 65 7J
1 1343488
106
i i K. .
50 100 15B 200 250 388 358
826BB 54 (11.251) o~Xu!ene FIND
188:
XFS
i
81
H/Z
9
39 51
*J *7
1 ! J 65 ','
. = !»..! li: . J.j. ...ill
1 100
186
92 187
i ih
58 100 150 250 388 350
-------
-•4
r-4
89 04-98 22:81 Triangle Laboratories, Inc
Sanple: S-V-1-4-A T 214-1-4A TLH46297
(919) 544-5729
Instrument H
HW9B7 367 (3=678)
100
XFS
0
H/Z
5
4156
i i I
55
7 2129929
86
50 ie@ 158 256 300 358
HU9B7'367 (3.671) REFINE
100
XFS
0'
H/Z
5
A
„
!3
i
55
7 1949696
86
71
i i 1..
50 108 158 250 300 350
826BX 11 (3.668) n-Hexane FIND
100
XFSJ
M/Z
5
41
. ']
56
55
. .."i
7 100
86
71 1
..i . i.
50 18S 158 288 258 300 356
-------
09-84-98 22:01 Triangle laboratories, Inc. (919) 544-5729
Sanplel S-M-1-4-A T 214 l-4ft TLItt4fa297 Instrument H
HU907 517 (5.171)
100
XFS
0
M/Z
4
3 7
5
55
44
7
b?
± 663552
85 180
i i I.I T
50 188 ' I5H 200 258 308 358
HU9B7'517 (5.171) REFINE
1001
XFS
0
H/Z
4
,1
3 ?
57
56
44
50
58
1 528384
85 100
.1. T .
188 ' 150 290 250 300 358
826BX 13 (5.391) Iso-Qctane FIND
100:
XFS:
0-
H/Z
5
!1.
56
. i
7 180
58
58 188 159 280 258 308 358
N
-------
"' ;'V ••'•:':'. '".. '. Pacific Environmental Services ••';'•'!• :':r''l::.-H:.:- ' : :
Project Number: 46297
Sample File: HW902
Qient Project: Hofcaux
nLIID: 214-*4B i
Method 8260 VOST
Sample ID: S-V-1-4-B
Date Received: &7&S&8
v- Date Analyzed 1 09/04/9$
Response BilklCAl
-H904
Aiwlyte 1
Pentafluorobenzene
Chloromethane
Vinyl Chloride
Bromomethane
Chloroethane
Trichlorofluoromethane
1.1-Dichloroethene
lodomethane
Carbon disulfide
Acetone
Allyl chloride
Methylene chloride
Acrylonitrile
trans- 1 .2-Dichloroethene
1.1-Dichloroe thane
Vinyl acetate
ci.s-1 ,2-Dichloroethene
2-Butai.one
Chloroform
1.1,1 -Trichloroethane
1 ,4-Difluorobenzene
Carbon tetrachloride
Benzene
1 ,2-Dichloroethane
Trichloroethene
1 ,2-Dichloropropane
. ; ':,. , Amottat, ; ";p&& ; '•.;.. .. V '.RT, • >: .
' ' •: !•: \^:-w:'^$:,^::^-f-'-^'!i "'•'•"'
IS 1 5.04
0.157 B 0.97
U
0.042 BJ 1 .48
U
U
U
U
U
0.006 BJ 2.67
U
0.002 BJ 3.06
U
U
U
U
U
U
U
U
IS 2 5.78
U
0.011 BJ 5-24
U
U
U
.•EtefcHuttit' ;y::;c$»aa.
Limit
, "ttg •• ••>• ' '••'••' ' ttg
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.005
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
NA- Not Applicable; Det Limit: Detection Limit; Quan. Limit: Quantitation Limit
IS: Internal Standard; U: Undetected; B: Present In Blank; J: Estimated- Below Quantitation Limit; E: Estimated- Above Calibration
0.05
0.05
0.05
0.05
0.05
0.05
o.os
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
Range
Triangle Laboratories, Inc.
801 Capitola Drive • Durham, North Carolina 27713
Phone: (°19) 544-5729 • Fax: (919) 544-5491
Savar v3.7
Printed: 13:41 09/07/1998
i3
-------
.;...' .,:".... ,.' ;'• .-
Project Number 46297
Sample File: HW902
Client Project: Hofmix
Til ID: 214-1-4B ;
/" - .-.-.:.' x •• '.
&;f.f - Pacific Environmental Services
Method 8260
VOST
Sample ID: S-V-1-4-B
Daie Received: &7/25/9S
^ .'•: •.
Date Analyzed ; 09/&4&8
Response Rid ICMJ3984
-
***** . . :.••;. ^^^^^^^•^^^-.^••^'f1
Methvl mcthacrylate
Bromodichloromethane
ci.s-1 ,3-Dichloropropene
4-Methyl-2-pentanone
Toluene
crans-1 ,3-Dichloropropene
1 ,1 ,2-Tnchloroethane
Chlorobenzene-d
Tetrachloroethene
2-Hcxanone
Dibromochloromethane
1 ,2-Dibromoethane
Chlorobenzene
Ethylbenzene
m-/p-Xylene
o-Xylene
Styrenc
Bromoform
1 ,4-Dichlorobenzene-d
4
Cumene
1 ,1 ,2,2-Tetrachloroe thane
U
U
U
U
0.004 BJ 7.74
U
U
IS 3 9.94
U
U
U
U
U
U
U
U
0.001 BJ 11.31
U
IS 4 15-06
U
U
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.05
0.05
0.05
0.05
0.05
0.05
0.1J5
0.05
0.05
0.05
0.05
0.05
0.05
0.10
0.05
0.05
0.05
0.05
0.05
NA- Not Applicable; Det Limit Detection Limit; Quan. Limit: Quantitation Limit
IS: Internal Standard; U: Undetected; B: Present In Blank; J: Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
Triangle Laboratories, Inc.
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
SavarvSJ
Printed: 13:41 09/07/1998
C
-------
Pacific Environmental Services
Project Number. 46297 Method 8260 VOST
Sample File: HW902 Sample ID: S-V-1-4-B
Client Projeefc Hotmix
TU IDi 2MMHH&
Pale Received:
Date Analyzed
07#5#&
: 09/04/98
Response File: ICALH9Q4
Surrogate S«mstK»y ; . . .. '. ;•' ' . ' . . :-.-. : . •';... ^Asa&i*i^$£i^'/^_ {•'s^t? '$&&: <". ",. :- '•• •'.. .":.^S-8»f : •; ''..'(>• :..>.' ... : -%KEC •
Dibromofluoromethane
Toluenc-d
3
4-Bromofluorobenzene
0.287
0.285
0.329
4.91
7.64
12.22
i
2
2
us
114
132
Reviewed by.
NA- Not Applicable; Det. Limit: Detection Limit; Quan. Limit: Qtuntitation Limit
IS: Internal Standard; U: Undetected; B: Present In Blank; J: Estimated- Below Quantttation Limit; E- Estimated- Above Calibration Range
Triangle Laboratories, Inc. Savar v3.
801 Capitola Drive • Durham, North Carolina 27713 Printed: 13:41 09/07/199
Phone: (919) 544-5729 • Fax: (919) 544-5491 ^ 1 1 5
-
-------
Pacific EsviEonmental Services
Proj ect Number. 46297 Method 8260 YOST
Sample File: HW902 Sample ID: S-V-1-4-B
*•*" •'."': C^'*^^^^^^^'^-^^S^
Pentafluorobenzene
1,3-Butadiene
Vinyl bromide
n-Hcxane
1 .2-Epoxybutane
Iso-Octane
1 ,4-Difluorobenzene
Ethyl acrylate
IS 1 5.04
U
U
0.001 BJ 3.66
U
U
IS 2 5.78
U
0.001
0.001
0.038
0.001
0.001
0.25
0.25
0.25
0.25
0.25
0.25
Reviewed bv ^JbajQ- Date °[ I < / °L f
NA- Not Applicable; Det Limit Detection Limit; Quan. Limit: Quantitation Limit
IS: Internal Standard; U; Undetected; B: Present In Blank;); Estimated- Below Quantitation Limit; E: Estimated- Above Calibtation Range
Triangl e Laboratories, Inc. Savar v3.7
801 Capitola Drive • Durham, North Carolina 27713 Printed; 14:51 09/08/1998
Phone: (919) 544-5729 • Fax: (919) 544-5491 -j - O
-------
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Data Review:^
Date:
117
-------
QUAN OB ; HW^O'Z
LAB-BASE QUAN
09-O4-98
L9-.<4i
No. MAT FOR REV Delta
Area P.Flags
RT
QM Name
1
2
3
4
5
6
t
8
9
10
11
12
13
14
15
16
17
1.3
19
20
21
22
23
24
25
."V,
27
23
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
100
100
100
100
100
100
100
0
100
0
100
0
0
0
0
0
70
0
0
0
0
0
0
0
0
0
0
o
0
0
100
0
0
0
0
0
0
0
42
95
0
0
0
0
0
0
0
0
0
84
96
95
79
06
12
89
0
91
0
75
0
0
0
0
0
33
>}
0
O
0
o
0
0
0
C, 1
— ' L
0
0
0
0
o
93
0
0
0
o
0
0
0
3
63
0
0
0
0
0
0
0
0
0
99
Qg
95
98
99
9 7
93
0
99
0
97
0
0
0
0
0
87
O
0
0
o
o
o
0
0
c, 1
— ' a.
0
0
0
0
0
99
0
0
0
o
0
0
0
66
89
0
0
0
0
0
0
0
0
o •
~2
1
~~" •£-
1
1
-2
—-7
O
1
0
2
0
0
0
0
0
o
0
o
0
o
o
f 1
0
r.)
0
o
M
0
0
0
0
0
o
o
o
o
0
1
-1
0
0
0
0
0
0
0
0
0
3304903 bv
3804952 bv
3721945 bv
1911209 bv
168324O bv
4626386 bv
2540335 bv
0
530920 bv
0
182477 bv
O
0
0
0
0
12712 vv
0
9!U'"l2~<*'rn
0
0
o
0
o
0
0
0
0
0
0
192399 bv
0
0
0
0
0
0
0
21092 — r* .
50484 bv
0
0
0
0
0
0
0
0
0
C
c
9.
15.
4.
7 .
12.
0 .
0.
0 .
1.
0.
0.
0..
0.
o .
.c_ -
0 .
0 .
0 .
o
1 J
0.
0,
o.
0.
0.
0
0,
5
0
0
0
0
0
0
0
— T
7
0
0
0
0
0
0
0
0
0
04
78
94
06
91
64
22
00
97
00
48
00
OO
, 00
00
.00
,67
, 00
pn")~
.OO
, Oi •
. 00
.00
. 00
.00
. OO
. 00
. 00
. oo
,00
. 24
. 00
. 00
.00
. 00
.00
. 00
.00
Ad
.74
.00
.00
.00
.00
.00
.00
.00
.00
.00
168
114
117
152
113
98
Q5
85
50
62
94
64
101
96
142
76
43
41
b.tflp 84
53
^0
e> 3
a 3
7 ''
e7"s -. r
rP ^
123
•37
L 1 7
75
78
62
130
63
93
41
83
75
92
75
97
69
164
76
43
129
107
112
Pentaf 1 uorobenzene
1 , 4-Oi f 1 uorobenzene
Chlorobenzane-d5
1 , 4-D ich iorobenzene-d4
Oibromof luoromethane
To L uene-dS
4-Bromof 1 uorobenzane
D iohlorodi f 1 uorome thane
Ch Ioromethane
Vinyl Chloride
Bromome thane
Chloroe thane
Fr Ichlorof 1 uoromethane
1 , 1 - 0 i c h 1 o r o e t h e f i ;-•
lodomet hane
Carbon >1icui'ri^e
Ace tone
A I ly i oh ior L. ie
ri e t h y i en e <.: h 1 o r i d e
Aery Lorn t i i.-
t r a n-.- - 1 , _ - D i c h i o r • ;>e S: ne CK-
1 ,. i. -0 ich i''> roe than.-?
'•/inyi dcetar.?.
2 , 2-0 i.ch 1 G r op rop«a (•(*=•
c i •". - 1 , ?.-0 i c h L o r oe i~ ne ne
.:. 8 1 1 1 .id no n*-:
Ch Lor of or rn
8 r ornoo h 1 o rome t ha ne
1,1, 1-Tr Lchloroethane
C a r b o n t a t r a c h 1. o r ' •• i e
1 , 1-Dichloropropene
Benzene;
1 ., 2 -O i c h 1 o r oe t ha ne
T r i c h 1 o r oe t. he ne
1 , 2-Dichloropropane
D ibromomethane
Methyl methacrylate
Bromodich Ioromethane
cis-1 , 3-Olchloropropene
4— Met hy 1 — 2— pe ntanone
Toluene
trans-1 ,3-Oichioropropei
1 , 1 ,2-Tr ich io roe thane
Ethyl methacrylate
Tetrachloroethene
1 ,3-DIchloropropane
2-Hexanone
Dlbromochloromethane
1, 2-Dibromoethane
Chlorobenzene
Data Review:
-------
No. MAT FOP REV Delta
Area P.Flags
PT
QM Name
51
52
53
54
55
56
57
58
59
60
61
62
63
e>4
65
66
67
63
69
70
71
72
/ O
74
75
76
77
78
79
0
0
0
0
56
0
50
0
0
0
0
0
0
0
0
0
65
66
0
59
O
0
0
0
0
68
63
31
56
0
0
0
0
52
0
44
0
0
0
0
0
0
0
0
0
52
S<4
0
44
0
0
0
0
0
oO
43
33
46
0
0
0
0
52
0
44
0
0
0
0
0
0
0
0
o
52
54
0
53
O
O
0
O
O
71
69
T T"
53
0
0
0
0
5
0
4
0
O
0
0
0
0
0
o
o
-1
1
0
1
0
1.)
0
0
0
7
4
11
7
0
0
0
0
8708 A
0
0
0
0
0
0
0
0
0
0
i--p A :.. t o i i j e n • *
ane
2-bi
1 , 3 , 5- T r i me t ny L be n ze ne?
t e r t - 8 u t y 1 b e n z a n «
1,2, ••'( -T r i me t hy I be n._
0 ,
: -• i - o b a «• i ,2 e n e
1 , 2-0 ibromo-3-ch i or
1 j 2 ., '4-Tr ichlorobs-iKT
Hexac h 1 o rob u carl I ene
Naphtha lene
1 , 2 , 3- Tr Lcn 1 orob.-2n«:
ene
Op PI
•-; ne
eno
119
-------
UAN DB : HW902
No. MAT FOR REV Delta
LAB-BASE QUAN
Area P,Flags
QO-04-98
19:44
RT
QM Name
1
.X.
3
4
5
6
7
8
o
1O
JU V,'
11
12
1 -?
j — '
1 4
100
100
100
100
100
100
100
58
0
7C,
-i™ v1
64
0
•-•> "r
~>7
84
96
95
79
96
92
89
30
0
12
53
0
-•c
I J ", J ^ L. 1 3. 1 I Ct-
F t* h v 1 .'3 n r \/ 1 ,4 1* ^--'
Data Review: Y£
Date:
120
-------
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09-04-98 19:04 Triangle Laboratories, Inc,
Sanple: S-U-J-4-B T/C 214-1-4B TLIJI46297
(919) 544-5729
Instrument H
HU9C
1001
XFS
0
HU9E
100:
XFS
0
M/Z
12 148 (1.480)
9.-
44
93
50 ?,i
!•!• l|l i
4 15808
SH ' IfiO ' 158 200 250 300 350
12 J 148 (1.481)
9-
44 7r";^
50
REFINE
4 12288
L08 ' 158 ' 200 250 ' 300 350
8268B 11 (1.470) Brononethane FIND
100^
XFS
0
H/Z
9,
93
46 fli i
40 / 81 J|
1 100
50 188 158 208 250 300 350
-------
07
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89-84-98 19:84 Triangle Laboratories, Inc. (919) 544-5729
Sanple: S-U-1-4-B T/C 214-1-4B TL 1*46297 Instrument H
HU902 267 (2.670)
100
XFS
0
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j!
14 27O4
58 g6 142
50 188 158 269 250 300 358
HU902'267 (2.671) REFINE
100
X.FS
0
w/z
4
3 1040
58
50 180 ISO 288 258 300 358
8260B 17 (2.650) Acetone FIND
100
XFS
0-
M/Z
4
.. i
3 100
58
50 180 153 288 258 380 358
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-------
CO
<- »
rH
09-04-98 19:84 Triangle Laboratories, Inc
Sanple: S-U-1-4-B T/C 214-1-4B TL1*46297
(919) 544-5729
Instrument H
HU902 774 (7.741)
100
5CFS-
0-
M/Z
98 22816
180
9
42 54 7,8
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50 168 158 288 258 300 356
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93
50 180 158 208 ' 258 ' 300 ' 350
-------
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-------
oo
89-84-98 19:84
Sample: S-V-1-4-B
T/C
Tr i a rig I e Laboraior i es =
Z14-1-4B TLI if 46297
inc
(919) 544-5729
Instrument H
HW902 366 (3.660)
100
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0-
H/Z
4
14 1728
5
7
T
50 108 150 200 250 300 350
HU902'366 (3.661) REFINE
100-
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5
4
I 56
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50 108 ' 150 ' 200 250 ' 300 350
826BX 11 (3.660) n-Hexane FIND
100:
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5
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.
7 180
86
50 1@0 158 208 ' 250 300 ' 350
V
-------
CALIBRATION
DATA
Triangle Laboratories, Inc.
801 Capltola Drive P.O. Box 13485
Durham, NC 277134411 Research Triangle Park, NC 277094
919-544-5729 Fax » 919*44-5491
-------
Triangle Laboratories, Inc.
Initial Calibration Curve
ICAL File: ICALH904 Date of Analysis
RF.l HW887 RP.25 HW888
RF.75 HW890 RF1.00 HW891
:09 /04 /98 Analyte List: 8260
RF.50 HW889
VOST Calibration.
Analyte ; Hag
Pentafluorobenzene I
Chloromethane P
Vinyl Chloride C
Bromomethane
Chloroethane
Tnchlorofluoro methane
1,1-Dichloroethene C
lodomethane
Carbon disulfide
Acetone
Allyl chloride
Methylene chloride
Acrylonitrile
trans-l,2-Dichloroethene
1,1-Dichloroethane P
Vinyl acetate
cis-l,2-Dichloroethene
2-Butanone
Chloroform C
1,1,1 -Trichloroethane
1,4-DifIuorobenzene I
Carbon tetrachloride
Benzene
1,2-Dichloroethane
Trichloroethene
1,2-Dichloropropane C
Methyl methacrylate
Bromodichloromethane
cis-l,3-Dichloropropene
4-Methyl-2-pentanone
Toluene C
trans-13-Dichloropropene
1 , 1 ,2-T richloroethane
Chlorobenzene-d5 I
Tetrachloroethene
2-Hexanone 1
Dibromochloromethane
1,2-Dibromoethane
::_.BRI
0.236
0.303
0.305
0.199
0.599
0.301
0.633
0.903
0.043
0.338
0.302
0.029
0.324
0.651
0.090
0.339
0.050
0.714
0.630
0.688
1.281
0.357
0.469
0.406
0.082
0.575
0.507
0.115
0.738
0.337
0.255
0.418
0.060
0.407
0.318
RE.25
0.271
0.367
0.354
0.213
0.643
0.324
0.633
0.921
0.186
0.349
0.312
0.028
0.350
0.675
0.214
0.360
0.234
0.767
0.702
0.601
1.138
0.368
0.414
0.419
0.082
0.573
0.561
0.155
0.770
0.404
0.248
0.411
0.198
0.385
0.298
/&FJ50
0.220
0.338
0.312
0.207
0.644
0.330
0.674
0.957
0.177
0.377
0.322
0.031
0.363
0.691
0.231
0.378
0.201
0.817
0.683
0.554
1.235
0.363
0.422
0.413
0.090
0.589
0.579
0.149
0.770
0.428
0.255
0.427
0.180
0.414
0.312
RE.7S RFLQQ&lEAN: •- %B^^»*e:S"^-> ••• y
0.267
0.360
0.334
0.216
0.642
0.247
0.500
0.754
0.136
0.296
0.231
0.029
0.307
0.657
0.249
0.386
0.220
0.763
0.650
0.521
1.083
0.356
0.423
0.405
0.092
0.585
0.587
0.152
0.756
0.442
0.264
0.427
0.190
0.419
0.314
0.287
0.380
0.353
0.241
0.761
0.382
0.742
0.966
0.199
0.401
0.381
0.037
0.406
0.586
0.183
0.387
0.136
0.760
0.647
0.532
1.051
0.331
0.427
0.402
0.093
0.573
0.579
0.146
0.730
0.432
0.257
0.430
0.174
0.418
0.313
0.256
0.350
0.332
0.215
0.658
0.317
0.636
0.900
0.148
0.352
0.310
0.031
0.350
0.652
0.193
0.370
0.168
0.764
0.662
0.579
1.158
0.355
0.431
0.409
0.088
0.579
0.563
0.143
0.753
0.409
0.256
0.423
0.160
0.408
0.311
10.6
8.6
6.9
7.4
9.3
15.4
13.9
9.5
42.9
11.3
17.3
11.2
10.9
6.1
32.5
5.6
45.0
4.8
4.4
11.8
8.5
4.1
5.0
1.8
6.1
1.3
5.7
11.3
2.5
10.4
2.3
1.9
35.5
3.4
2.5
_*- Fails QC Criteria for %RSD; « - RF less than minimum QC RF;» - RF greater than maximum QC RF
Triangle Laboratories, Inc.
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Savar v3.7
130
-------
Triangle Laboratories, Inc.
Initial Calibration Curve
ICAL File: ICALH904
RF.l HW887
RF.75 HW890
Date of Analysis :09/04/98
RF.25 HW888
RF1.00 HW891
Analyte List: 8260
RF.50 HW889
VOST Calibration.
.Analyte
•K&HK-'.
Chlorobenzene P
Ethylbenzene C
m-/p-Xylene
o-Xylene
Styrene
Bromoform P
l,4-Dichlorobenzene-d4 I
Cumene
1,1,2,2-Tetrachloroethane P
Average %RSD
0.923 0.954 0.987 0.956 0.954 0.955 2.4,
0.467 0.496 0.502 0.467 0.468 0.480 3.7
0.589 0.608 0.613 0.574 0.567 0.590 3.4
0.547 0.569 0.569 0.530 0.543 0.552 3.1
0.868 0.929 0.946 0.894 0.907 0.909 3.3
0.174 0.203 0.233 0.244 0.251 0.221 14.6
3.940 3.920 4.136 2.927 2.740 3.532 18.3
0.463 0.618 0.674 0.559 0.504 0.564 15.1
10.5
ISurrogate
KR1- RF.25
Rf.75 RFtOO Mean %RSD
Dibromofluoromethane S
Toluene-d8 S
4-Bromofluorobenzene S
0.423 0.489 0.436 0.438 0.427 0.443 6.0
1.024 1.072 1.078 1.087 1.062 1.065 2.3
0.498 0.524 0.516 0.502 0.500 0.508 2.3
Approved by:.
*- Fails QC Criteria for %RSD;« - RF less than minimum QC RF; » • RF greater man maximum QC RF
Triangle Laboratories, Inc. Savar v3.7
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491 131
-------
Triangle Laboratories, Inc.
Continuing Calibration Curve
CCAL File: HW894
ICAL File: ICALH904
Date of Analysis
:09/04/98
Analyte List: 8260
VOST Calibration.
Anslyte : : J*l8g.' * . -•..-. /., \ ,. • .. :•• • ";•'•• '-: / •'• - :. / •' • • .-"•.'.•• ".";:~ ••' ' -: • • : •
Pentafluorobenzene
Chloro methane
Vinyl Chloride
Bromo methane
Chloroethane
Trichlorofluoromethane
1,1-Dichloroethene
lodomethane
Carbon disulfide
Acetone
Allyl chloride
Methylene chloride
Acrylonitrile
trans-l,2-Dichloroethene
1,1-Dichloroethane
Vinyl acetate
cis-l,2-Dichloroethene
2-Butanone
Chlort form
1,1,1-Trichloroethane
1,4-Difluorobenzene
Carbon tetrachlonde
Benzene
1,2-Dichloroethane
Trichloroethene
1 ,2- Dichloropropane
Methyl methacrylate
Bromodichlorome thane
cis-l,3-Dichloropropene
4-Methyl-2-pentanone
Toluene
trans-l,3-Dichloropropene
1 ,1 ,2-Tnchloroethane
Chlorobenzene-d5
Tetrachloroethene
2-Hexanone
Dibromochloromethane
1,2-Dibromoethane
I
P 0.195
C 0.272
0.217
0.133
0.398
C 0.238
0.528
0.761
0.103
0.355
0.309
0.032
0.351
P 0.659
0.190
0.366
0.160
C 0.764
0.731
I
0.592
1.599
0.366
0.487
C 0.415
0.097
0.580
0.563
0.172
C 0.771
0.417
0.261
I
0.432
1 0.197
0.416
0.321
0.256
0.350
0.332
0.215
0.658
0.317
0.636
0.900
0.148
0.352
0.310
0.031
0.350
0.652
0.193
0.370
0.168
0.764
0.662
0.579
1.158
0.355
0.431
0.409
0.088
0.579
0.563
0.143
0.753
0.409
0.256
0.423
0.160
0.408
0.311
23.8
22.3
34.6
38.1
39.5
24.9
17.0
15.4
30.4
-0.9
0.3
-3.2
-0.3
-1.1
1.6
1.1
4.8
0.0
-10.4
-2.2
-38.1
-3.1
-13.0
-1.5
-10.2
-0.2
0.0
-20.3
-2.4
-2.0
-2.0
-2.1
-23.1
-2.0
-3.2
*- Fails QC Criteria for %D;« - Rf less than minimum QC RF;»- RF greater than maximum QC RF
Triangle Laboratories, Inc.
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Savar v3.7
13;
-------
Triangle Laboratories, Inc.
Continuing Calibration Curve
CCAL File: HW894 Date of Analysis :09/04/98 Analyte List: 8260
[CAL File: ICALH904
VOST Calibration.
Analyte '•:•''
Chlorobenzene
Ethvl benzene
m-/p-Xvlene
o-Xvlene
Stvrene
Bromoform
l,4-Dichlorobenzene-d4
Cumene
1,1,2,2-Tetrachloroethane
Surrogate
Dibromofluoromethane
Toluene-d8
4-Bromofluorobenzene
flag
P
C
P
I
P
Flag
S
S
S
.:RBL» R
0.967
0.496
0.611
0.588
0.976
0.242
3.901
0.491
RFO25 S
0.492
1.060
0.562
fsaKMs^:<
0.955
0.480
0.590
0.552
0.909
0.221
3.532
0.564
FMEAN;.::
0.443
1.065
0.508
V^^.^v^,:V-.=:;;-v-o; <-.;- 'jy.v-. " :
-1.3
-3.3
-3.6
-6.5
-7.4
-9.5
-10.4
12.9
. %D -• • . •• •
-11.1
0.5
-10.6
Approved by: >(K Date H / T / H 0
*- Fails QC Criteria for %D;« - Rf less than minimum QC RF;»- RF greater than maximum QC RF
Triangle Laboratories, Inc. Savar v3.!
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491 1 '->
-------
Triangle Laboratories, Inc.
Initial Calibration Curve
ICAL File: ICALH904 Date of Analysis :09/04/98 Analyte List: 8260
RF.5 HW893
VOST Calibration.
Analjrte •.' •. • ".<:••..•• Hag
Pentafluorobenzene I
1,3-Butadiene 0.455 0.455 0.0
Vinyl bromide 0.375 0.375 0.0
n-Hexane 0.459 0.459 0.0
1,2-Epoxybutane 0.004 0.004 0.0 «
Iso-Octane 1.767 1.767 0.0
1,4-Difluorobenzene I
Ethyl acrylate 0.194 0.194 0.0
Average %RSD 0.0
Approved by: Date / /.
*- Fails QC Criteria for %RSD; « - RF less than minimum QC RF;» - RF greater than maximum QC RF
Triangle Laboratories, Inc. Savar v3 7
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
'39 . 134
-------
Triangle Laboratories, Inc.
Continuing Calibration Curve
CCAL File. HW893 Date of Analysis :09/04/98 Analyte List: 8260
ICAL File: ICALH904
VOST Calibration.
Analyte
Pentafluorobenzene I
1,3-Butadiene 0.455 0.455 0.0
Vinyl bromide 0.375 0.375 0.0
n-Hexane 0.459 0.459 0.0
1,2-Epoxybutane 0.004 0.004 0.0 «
Iso-Octane 1.767 1.767 0.0
1,4-Difluorobenzene I
Ethyl acrylate 0.194 0.194 0.0
Approved by:
_ *• Fails QC Criteria for %D; « - Rf less man minimum QC RF; »- RF greater than maximum QC RF
Triangle Laboratories, Inc. Savar v3.'
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax (919) 544-5491 -I ')Q
-------
CASE NARRATIVE
Analysis of Samples for the Presence of
Volatile Analytes by
High-Resolution Gas Chromatography / Low-Resolution Mass Spectrometry
METHOD 8260 (7/92)
Date:
September 8, 1998
Client ID :
Pacific Environmental Services
TLI Project Number : 46323
This report should only be reproduced in full. Any partial reproduction of this report requires permission from
Triangle Laboratories, Inc.
Triangle Laboratories, Inc.
801 Capitola Drive P.O. Box 13485
Durham, NC 27713-4411 Research Triangle Park, NC 27709-3485
919-544-5729 Fax #919-544-5491
-------
Triangle Laboratories, Inc. September 8,1998
Case Narrative 46323
Objective: Analysis of two VOST tube pairs for a client-specified list of volatile compounds,
using Method 8260.
Method:
Twenty three VOST tube pairs were received at Triangle Laboratories, Inc. on July 29,1998 at
6°C. Analytical results reported in this data package pertain to the analysis of two "S" samples.
The VOST tube pairs were analyzed according to the guidelines of Methods 8260 and 5040. The
internal standards and surrogate standards were added in the amount of 0.25 micrograms (ug)
immediately prior to analysis by GC/MS. The internal standards are pentafluorobenzene, 1,4-
difluorobenzene, chlorobenzene-ds, and l,4-dichlorobenzene-d4, and the surrogate standards
reported are dibromofluoromethane, toluene-dg, and 4-bromofluorobenzene. The results reported
relate only to the items tested.
The GC/MS analysis conditions are listed below:
Purge and trap: Tekmar LSC-2000
Purge: 11 min.
Desorb Temperature: 250 C
Desorb Time: 4 min.
GC Conditions:
Column: 30 m x .53 mm x 0.3« J&W DB624
0 C hold .5 min, 10 C/min to 45C, 6 C/min to 90C, hold 1.5 min,
50 C/min to 200C.
MS Conditions:
Instrument: VG-TRIO-1 Lab Base data system
Scan: 35-350 amu at .6s/scan
Interface: Jet Separator, 200 C
Report:
Enclosed with the case narrative are copies of the sample identification index, the project
summary sheets, client paperwork, sample log-in sheets, and log book pages. A sample
identification index summarizes the client sample name, TLI sample number, and analytical file
name for each sample and blank. The project summary lists the amounts for detected analytes in
gray. The estimated detection limits will be listed in parentheses when the target analytes are not
detected.
The data are reported as quantitation reports, chromatograms, interim reports, and spectra of
detected target analytes. The quantitation report header lists the TLI project number, analysis
method, instrument sample file name, client sample name, client project number, TLI sample
number, calibration file, date received, and analysis date. The response factors used for all
calculations are from the calibration file listed in the header. All initial and continuing calibration
ar , • 2
-------
Triangle Laboratories, Inc. September 8,1998
Case Narrative 46323
data are located in the back of the data package. The amount is reported in total ug for the
VOST tubes. The retention time (RT) will be listed for all internal standards and analytes which
are detected. If a target analyte is not detected, it will be flagged with a "U" and a detection limit
will be listed. Estimated detection limits are calculated for all analytes which were not found in
the samples by using an area of 2000. The estimated detection limits reported are the average
detection limits achievable over time on an instrument type. The actual detection limit for a given
compound on a given day may vary from the estimate reported. The quantitation limit for all
analytes is half of the low point of the initial calibration. Below this point the calibration cannot
be considered to be linear. Any amount reported at a level below the quantitation limit will be
flagged with a " J" and should be considered estimated. If any compounds are found at a level
above the upper calibration range, the analyte will be flagged with an "E" and the amounts
reported should be considered estimated. If any target analytes found in the laboratory blanks are
detected in the associated samples, they will be flagged with a "B" on each sample topsheet. All
analytes are quantitated against the internal standard preceding them on the target analyte list.
Surrogate standards are quantitated against the internal standard with the matching internal
standard reference number. For example, toluene-dg has 2 in the IS Ref column and would be
quantitated against the internal standard which has IS2 listed in the flag column. If an internal
standard area is above or below the quality control limits as defined by the continuing calibration,
it will be flagged with "High" or "Low" in the flag column.
Results:
The samples were analyzed outside of the holding time. As per client request, the VOST tube
pairs were analyzed separately.
The analyst observed the presence of moisture in each of the VOST tubes during analysis. For
Tenax sample S-V-3-3-A, the level of moisture was sufficient to reduce the purge flow.
Each sample was processed twice, once against the calibrations containing compounds that are
normally found in our Method 8260 standard solutions, and once against special single point
calibrations containing six compounds. Therefore, each sample reported contains two sets of
topsheets and interim reports, as well as a chromatogram and spectra for all analytes. Please note
that the surrogate standards have been reported only on the first target analyte list. Results for the
six analytes processed against a single point calibration should be considered estimates. The client
requested analyte, Methyl-tert-butyl-ether (MTBE) was not present in the calibration standard. A
manual search for this compound was performed. It was not identified in any of the samples.
Several analytes were found at amounts above the upper calibration limit of one microgram in the
Tenax tube samples. These compounds are flagged with "E" and the amounts reported should be
considered estimated. The field samples also contained very high levels of hydrocarbons.
All internal standard areas were within quality control limits for all samples and blanks, with the
exception of low areas for 1,4-difluorobenzene, chlorobenzene-d5, and 1,4-dichlorobenzene-d4 in
Tenax tube sample S-V-3-3-A.
"* 3
-------
Triangle Laboratories, Inc. September 8,1998
Case Narrative 46323
Surrogate standard percent recoveries were within quality control limits, with the exception of
high recoveries for 4-bromofluorobenzene in both Tenax tube samples.
The laboratory blanks contained several analytes at amounts below the quantitation limit. The
target analytes in a laboratory blank should not be considered as truly present in the native
samples unless found at a level at least five times the amount found in the associated blank. In the
event that the amount of a target analyte found in the samples is twenty times the amount found in
the associated blank, the contribution from the blank can be considered negligible.
Sample Calculations:
Response Factor (RF) = (area analyte) x (amt IS)
(area IS) x (amt analyte)
Amount (ug) = (area analyte in sample) x (amt IS)
(area IS) x (avg ical RF)
Where:
amt IS = amount of internal standard = 0.25 ug
ical = initial calibration
avg ical RF = average response factor from the associated initial calibration
The data in this package has been judged to be valid according to the guidelines of Methods 8260
and 5040 except as noted above. Should you have any questions, please feel free to contact our
Client Services Representative at (919) 544-5729.
For Triangle Laboratories, Inc.,
Report Preparation: Quality Control:
Penny A. Brock Sarah A. Hubbard
Report Preparation Chemist Report Preparation Chemist
124
The total number of pages in this data package is *
-------
Triangle Laboratories, Inc.
Sample Identification Index for Project: 46323
Client Id: • •• ' TL11&
S-V-24-A T 214-27-4A HW903
S-V-24-B TC 214-27-4B HW898
S-V-3-3-A T 214-27-12A HW904
S-V-3-3-B TC 214-27-12B HW899
VOSTBLK 090498 T/TC VOSTBLK 0904 ^ ^ HW897
Triangle Laboratories, Inc. Proj_Sum v4.0
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: <919) 544.5491 U J ..• 5
-------
Triangle Laboratories, Inc.
Project Summary for Project 46323
Client ID: S-V-2-4-A
T
Filename : HW903
TLIId : 214-27-4A
Matrix : VOST
Units : ug
Chloromethane
Vinyl Chloride
Bromomethane
Chloroethane
Trichlorofluoromethane
1 , 1 -Dichloroethene
Methylene chloride
trans-l^-Dichloroethene
1,1-Dichloroethane
cis-l,2-Dichloroethene
Chloroform
1 , 1 , 1 -Trichloroethane
lodomethane
Carbon disulfide
Acetone : .
Allyl chloride
Acrylonitrile
Vinyl acetate
2-Butanone ; "•'•
Carbon tetrachloride
Benzene
1 ,2 -Dichloroethane
Trichloroethene
1,2-Dichloropropane
Bromodichloromethane
cis-l,3-DichJoropropene
^p I v' "••.•
loluene
trans- 1 ,3-Dichloropropene
1 , 1 ,2-Trichloroethane
Methvl methacrylate
4-Methyl-2-pentanone
Tetrachloroethene
Dibromochloromethane
1 ,2-Dibromoethane
Chlorobenzene
0390
(0.001)
frOS*
*K3ii
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
&S43
2.0*8
(0.001)
(0.006)
(0.001)
1402
(0.001)
0.711
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
&$Z0
(0.001)
(0.001)
(0.002)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
<
S-V-24-B S-V-3-3-A S-V-3-3-B VOSTBLK09
TC T TC 0498 T/TC
HW898 HW904 HW899 HW897
214-27-4B 214-27-12A 214-27-12B VOSTBLK0904
VOST VOST VOST VOST
ug ug ug ug
• .v;v^^-- -i^r
(0.001)
.- '-.. '";:':::'-'"04€t. ."• >0;;
(0.001)
(0.001)
(0.001)
: • ',.: 0.020
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001) "... ;-
:•.'•• ,.: r;'..?ve;io06 r^V";
(0.001)
(0.005)
(0.001)
(0.001) 1 '•: '•••• ,.
(0.001)
6,00$ :
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
•'•'•: .'•' • :':' -i- V i ' '$$$.. : . "' ' > :. ' •'
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
)-Estimated Detection Limit
;v:^5s ?••• ;r
(0.001)
. '; ;^os$ ;;.;•:'• '.
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
OJS71
-.-,:' '3A24 -'• ••^.•;
(0.001)
(0.007)
(0.001)
:..... £*& .:;;::.";
(0.001)
"". 1^27 •'
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
: ,. ...3^8- ;:.. .-••;•...
(0.001)
(0.001)
(0.003)
(0.002)
(0.001)
(0.001)
(0.002)
(0.001)
Page 1
":"$&*. /;-•::
(0.001)
: : $&n ;..-"•• ::
(0.001)
(0.001)
(0.001)
(0.001) :
(0.001)
(0.001)
(0.001)
(0.001) .
(0.001)
(0.001) ;..: ..
(0.001)
-------
Triangle Laboratories, Inc.
Project Summary for Project 46323
Client ID:
Filename :
TLIId :
Matrix :
Units :
Ethylbenzene
J
m-/p-Xylene
o-Xylene
Styrene
Bromoform
2-Hexanone
Cumene
1,1,2,2-Tetrachloroethane
S-V-2-4-A
T
HW903
214-27-4A
VOST
ug
'..•:-'0J»S
2108
'-.'. -ft;i*7lij4
:M»/.-SfT*
'~0 145
(0.001)
(0.001)
(0.001)
(0.001)
S-V-2-4-B
TC
HW898
214-27-4B
VOST
ug
"•••• •:-'.:>v8&
:-'-''<^:8$&
(0.001)
•••• •••;;:$:aia8i.
(0.001)
(0.001)
(0.001)
(0.001)
S-V-3-3-A
T
HW904
214-27-12A
VOST
ug
:;<• ••;:,;;.;. £^6
Uv-:XTi3w*2*
?iO/:':-:^'-4iS$E>
':';:;:;::"..-x-;;;:.: 0^490
(0.002)
(0.003)
(0.001)
(0.003)
S-V-3-3-B
TC
HW899
214-27-12B
VOST
ug
(0.001) S!
(0.001) ;=]
(0.001) ;>;
(0.001) 3
(0.001)
(0.001)
(0.001)
(0.001)
VOSTBLK 09
0498 T/TC
HW897
VOSTBLK 0904
VOST
ug
' ; -'-f-ViMJoi
••••4:.^ :>$m
::;;•...:;.'.• ::..'^Mi
: 9M2
(0.001)
(0.001)
aooi
(0.001)
( )-Estimated Detection Limit Page 2
Triangle Laboratories, Inc.
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544.5729 • Fax: (919) 544-5491
Savarv3.7
Printed: 17:12:59 09/08/98
7
-------
Triangle Laboratories, Inc.
Project Summary for Project 46323
Client ID:
Filename :
TLIId :
Matrix :
Units :
1,3-Butadiene
Vinyl bromide
n-Hexane
1,2-Epoxybutane
Iso-Octane
Ethyl acrylate
S-V-2-4-A
T
HW903
214-27-4A
VOST
ug
(0.001)
(0.001)
. .:143& :
(0.046)
(0.001)
(0.001)
S-V-2-4-B
TC
HW898
214-27-4B
VOST
ug
(0.001)
(0.001)
':'< ':' 7';7'&003j;- '
(0.035)
•-••""^••viv^OOl
(0.001)
S-V-3-3-A
T
HW904
214-27-12A
VOST
ug
(0.001)
(0.001)
. ..i>;V ::ls"s$0$- ;"
(0.055)
(0.001)
(0.001)
S-V-3-3-B
TC
HW899
214-27-12B
VOST
ug
(0.001)
(0.001)
•:T"";:''.r'.'#XK& ,;•
(0.036)
(0.001)
(0.001)
VOSTBLK 09
0498 T/TC
HW897
VOSTBLK 0904
VOST
ug
(0.001)
(0.001)
;; 0.001
(0.034)
(0.001)
(0.001)
( (-Estimated Detection Limit
Page 1
Triangle Laboratories, Inc.
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Savarv3.7
Printed: 16:57:14 09/08/98
8
-------
£7 PACIFIC ENVIRONMENTAL SERVICES, INC.
Central Park West
5001 South Miami Boulevard, P.O. Box 12077
Research Triangle Park, North Carolina 27709-2077
(919) 941-0333 FAX: (919) 941-0234
Sample Chain of Custody Record
PLANT: US EPA HOT MIX ASPHALT PLANT C
RECOVERY PERSON: Abernathy, Maret
PROJECT NO.: R012.001
SAMPLERS: Abernathy, Maret
Sample
Identification
T-V-3-1-B
T-V-3-2-A
T-V-3-2-B
T-V-3-3-A
T-V-3-3-B
S-V-FB-A
S-V-FB-B
T-V-4-1-A
T-V-4-1-B
T-V-4-2-A
T-V-4-2-B
T-V-4-3-A
T-V-4-3-B
T-V-4-4-A
T-V-4-4-B
( — T' N
Collection
Date
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
/n n
Time
Sample
Name
Tunnel Run 3 Set 1
Tunnel Run 3 Set 2
Tunnel Run 3 Set 2
Tunnel Run 3 Set 3
Tunnel Run 3 Set 3
Silo Field Blank
Silo Field Blank
Tunnel Run 4 Set 1
Tunnel Run 4 Set 1
Tunnel Run 4 Set 2
Tunnel Run 4 Set 2
Tunnel Run 4 Set 3
Tunnel Run 4 Set 3
Tunnel Run 4 Set 4
Tunnel Run 4 Set 4
Number of
Containers
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
RlSmqttt9h9al>y: ./ // i s\ . ,
T^StrrfW Q flW
Relinquished by:
Analytical Request '
Date Time
ifafe 1070
Date Time
?/*ffo /&e?
-
Comments
Tenax/Charcoal
Tenax
Tenax/Charcoal
Tenax
Tenax/Charcoal
Tenax
Tenax/Charcoal
Tenax
Tenax/Charcoal
Tenax
Tenax/Charcoal
Tenax
Tenax/Charcoal
Tenax
Tenax/Charcoal
: I
Received by:
Received for Lab by:
£?*6S h/t-^te^-
Page 2 of 2
-------
l /<
O PACIFIC ENVIRONMENTAL SERVICES, INC.
Centra! Park West
5001 South Miami Boulevard, P.O. Box 12077
Research-Triangle Park, North Carolina 27709-2077
,-'(919) 941-0333 FAX: (919) 941-0234
O
vH
Sample Chain of Custody Record
PLANT: US EPA HOT MIX ASPHALT PLANT C
RECOVERY PERSON: Abemathy, Maret
PROJECT NO.: R012.001
SAM PLERS: Abernathy, Maret
.1
Sample .
Identification
S-V-2-1-A
S-V-2-1-B
S-V-2-2-A
S-V-2-2-B
S-V-2-3-A
S-V-2-3-B
S-V-2-4-A
S-V-2-4-B
T-V-2-1-A
T-V-2-1-B
T-V-2-2-A
T-V-2-2-B
T-V-2-3-A
T-V-2-3-B
T-V-2-4-A
T-V-2-4-B
T-V-FB-A
T-V-FB-B
S-V-3-1-A
S-V-3-1-B
S-V-3-2-A
S-V-3-2-B
S-V-3-3-A
S-V-3-3-B
S-V-3-4-A
S-V-3-4-B
S-V-3-5-A
S-V-3-5-B
S-V-3-6-A _j
S-V-3-6-B
T-V-3-1-A
Collection
Date
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
Time
Sample
Name
Silo 2 Run 2 Set 1
Silo 2 Run 2 Set 1
Silo 2 Run 2 Sot 2
Silo 2 Run 2 Set 2
Silo 2 Run 2 Set 3
Silo 2 Run 2 Set 3
Silo 2 Run 2 Set 4
Silo 2 Run 2 Set 4
Tunnel Run 2 Set 1
Tunnel Run 2 Set 1
Tunnel Run 2 Set 2
Tunnel Run 2 Set 2
Tunnel Run 2 Set 3
Tunnel Run 2 Set 3
Tunnel Run 2 Set 4
Tunnel Run 2 Set 4
Tunnel Field Blank
Tunnel Field Blank
Silo 2 Run 3 Set 1
Silo 2 Run 3 Set 1
Silo 2 Run 3 Set 2
Silo 2 Run 3 Set 2
Silo 2 Run 3 Set 3
Silo 2 Run 3 Set 3
Silo 2 Run 3 Set 4
Silo 2 Run 3 Set 4
Silo 2 Run 3 Set 5
Silo 2 Run 3 Set 5
Silo 2 Run 3 Set 6
Silo 2 Run 3 Set 6
Tunnel Run 3 Set 1
Number of
Containers
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
Analytical Rec
uest
Comments
Tenax
Tenax/Charcoal
Tenax
Tenax/Charcoal
Tenax
Tenax/Charcoal
Tenax
Tenax/Charcoal
Tenax
Tenax/Charcoal
Tenax
Tenax/Charcoal
Tenax
Tenax/Charcoal
Tenax
Tenax/Charcoal
Tenax I
Tenax/Charcoal
Tenax
Tenax/Charcpal
Tenax
Tenax/Charcoal
Tenax
Tenax/Charcoal
Tenax
Tenax/Charcoal
Tenax
Tenax/Charcoal
Tenax
Tenax/Charcoal
Tenax
SP-.
Page 1 of 2
-------
z; "1 .!¥:
DOCUMENT
CONTROL
THfengte Laboratories, Inc.
801 Capita** Drtvm P.O. Box 13485
OurtuuntNC27713-t411 ~ ~
919-S44-S729 FfX 1919-544-5491
-------
=TRIANGLE LABORATORIES, INC. -- LOG IN RECORD/CHAIN OF CUSTODY^
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Date Received j 07/29/9B j B> ' f?)/^fyyy/*{S
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Project Number 46323 /
nt: PES03 - Pacific Environmental Services
Date Received | 07/29/98 j Bv^^
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J214-27-8A T-V-2-4-A TENAX
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I214-27-8B T-V-2-4-B TNX/CHAR
| ! T-V-2-4-B R026
(214-27-9A T-V-FB-A TENAX
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(214-27-98 ' T-V-FB-B TNX/CHAR
| • i . T-V-FB-B R02S
|214-27-l6A S-V-3-1-A TENAX
| S-V-3-1-A R026
|2U-27-10B S-V-3-1-B TNX/CHAR
| ! S-V-3-1-B R026
JJ214-27-11A S-V-3-2-A TENAX
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(214-27-11B S-V-3-2-B TNX/CHAR
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(214-27-12A S-V-3-3-A TENAX
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| T-V-3-1-A R026
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'|, ' 1 . T-V-3-1-B R026
J214-27-17A T-V-3-2-A TENAX
| T-V-3-2-A R026
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| '' . T-V-3-3-A R026
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|214-J7-19A S-V-FB-A TGNAX
| S-V-FB-A R026
(214-27-198 S-V-FB-B TNX/CHAR
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s ^
i Archive Remarks: >
=Form Revised OS/27/1997w page 3 OF 4
-------
Custody Seal i Absent Sample Seals: Ahoenl
Chain of Custody : Present Container. . . : Intact
Sample Tags : Absent
Sample Tag Numbers: Not Listed on Chain of Custody
SMO Forms : N/A
TLI Project Number 46323 ; Book
Client: PES03 - Pacific Environmental Services ' .'
. • 2*4
Date Received j 07/29/98 | Bj^ / fasj^C^Z? Pa9e
i i Yr S7SS\r y^r j i
Ice Chest ICE PACKS Temp 6.0 C Carrier and Number j FedEx/ \S , 27
TLI Number Client Sample ID Matrix
mR/HiCPM Client COC ID . * Location
214-27-22A T-V-4-3-A TENAX
T-V-4-3-A R026
214-27-22B T-V-4-3-B TNX/CIIAR
T-V-4-3-B R02fi
214-27-23A T-V-4-4-A TENAX
T-V-4-4-A R026
1 1 '
214-27-23B ' T-V-4-4-B TNX/CIIAR
, , T-V-4-4-B R026
1
I
1
«
1
To I .An
Date/Init
To STORAGE
Date/Init
•-
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Date/Init
To STORAGE
Date/Init
To LAB
Date/Init
To STORAGE
Date/Init
To IAB
Date/Init
To STORAGE
Date/Init
'
\
-
DISPOSED
Date/Init
'
~
Receiving Remarks:
n
D Archive Remarks :
10
*.-H
i
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a
-------
Triangle Laboratories, Inc.
Run Log
Column Type
~D&2/
Column ff
3274^5 6
Analysis'
J*>
r-*
Other*
1
Standards
Internal / Surrogate / Recovery
¥f-
Internal / Surrogate / Recovery
Analyte
Extr§cL/-Sample volume
^9&^
Date
Clrde unit
L ml
3ate
*
&
I£2£
Time"
Projecl
Sample*
Client 10
nrc
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lo r/rc
Filename
#H/rtr
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Operator/Date
JJL
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nrc
f/f/f /
/o:5|
f /•//•//
y
T
' Volatile Data Only
SRVR4\\AP\MSRtMRRUNLOG DOC (10/16/97)
Transcribed Data
"* Dated Signature/Initials Required
-------
Triangle Laboratories, Inc.
Run Log
r-
••-1
Column Type
T>K?W
Column #
*?Z1 t/Gsc,
Analysis'
4^0
Acquisition
Method
\/o ft
GC Method'
14*3
Find DBs*
<^X<*c>*£
Other* .
?lt>6*
Standards
Internal / Surrogate / Recovery j Internal / Surrogate / Recovery
Analyte
Extract / Sample volu/ne
Clrde unit
>2 uL mL
Dale*
Time"
Project
Sample*
f/fcftK
Client ID
Filename
T/fc
u.
r/rc
A/
J
M
s-v-2- 4- a
niz
•K-ht
fe
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r/c
f
* Volatile Data Only " Transcribed Data
SRVR4\\AP\MSRL\LRRUNLOQ DOC (1(VI6»7)
Dated Signature/Initials Required
-------
Triangle Laboratories, Inc.
Run Log
CO
-H
Column Type
^>t>
Analysis"
£260
Acquisition
Method
l/e>/*
GC Method*
(yi/f3
Find DBs*
-------
SAMPLE
DATA
Triangle Laboratories, Inc.
801 Capitola Drtv* P.O. Box 13485
Durham, NC 277134411 Raaaarch TVimgte Part; WC 2771
919-5444723 Fax * 919 544 5491
-------
Pacific Environmental Services
Project Number 46323
Sample File: HW897
Client Project R012.0&1
IU ID: VOSTBUC090498
Dale Received:
Date Analyzed i
Method 8260 VOST
Sample ID: VOSTBLK 090498 T/TC
/ / Response File: ICALH904
: Q9/04/98 ; {;
Analyte
Pen cafluorobenzene
Chloromethane
Vinyl Chloride
Bromomethane
Chloroe thane
Trichlorofluoromethane
1,1-Dichloroethene
lodomethane
Carbon disulfide
Acetone
Allyl chloride
Methylene chloride
Acrylonitrile
trans- 1 ,2-Dichloroethene
1,1-Dichloroethane
Vinyl acetate
cis-1 ,2-Dichloroethene
2-Butanone
Chloroform
1,1,1 -Trichloroethane
1 ,4-Difluoro benzene
Carbon tetrachloride
Benzene
1 ,2-Dichloroe thane
Trichloroethene
1 ,2-Dichloropropane
• .;.,' Airt*^:-';;?^?'..:-.
t -' ag ; '?•" .•"•''•• ":'•
IS 1
0.025 J
U
0.022 J
U
U
U
0.002 J
U
0.005 J
U
0.004 J
U
U
U
U
U
0.003 J
0.001 J
U
IS 2
U
0.027 J
U
U
U
*::'y'$CE .. '•'••:.-.. Defcljattit Quan. timit
«g ng
5.04
0.96 0.05
0.001 0.05
1.46 0.05
0.001 0.05
0.001 0.05
0.001 0.05
2.56 0.05
0.001 0.05
2.64 0.05
0.001 0.0^
3.04 0 05
0.004 0.05
0.001 0.05
0.001 O.OS
0.001 0.05
0.001 0.05
4.50 0.05
4.75 0.05
0.001 0.05
5-77
0.001 0.05
5.24 0.05
0.001 0.05
0.001 0.05
0.001 0.05
NA- Not Applicable; Det Limit Detection Limit; Quan. Limit Quantitation Limit
IS: Internal Standard; U: Undetected; B: Present In Blank; ]: Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
Triangle Laboratories, Inc.
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Savar v3.7
Printed: 16:29 09/08/1998
-------
Project Number 46323
Sample File: HW897
Client Project R812.0&1 :•
TU ID: VQSTBUC090#&a
'•:•• '• ••- Pla.dlic-iEnvfed«imch.^
^'SfemieesS';--^-' ;- •'•>'..•••" 'r \j":.r
. ' ' • '••' -
Method 8260 VOST
Sample ID: VOSTBLK 090498 T/TC
; .-• :,: :; /: ;- ..'. Dale^tecerviaid:^/- / ;•'' •"".': ' •;;..'.;' Respcoise Filer ICALH9M
• •':,••;.!:,;.•••,;;.. -iDate-^halyziii
ifis&i&i- .
Analyte
Methyl methacrylate
Bromodichloromethane
cis-l,3-Dichloropropene
4-Methvl-2-pentanone
Toluene
trans- 1 ,3-Diehloropropene
1 ,1 ,2- Frichloroethane
Chlorobenzene-d
i
Tetrachloroethene
2-Hexanone
Dibromochloromethane
1 ,2-Dibromoethane
Chlorobenzene
Ethylbenzene
m-/p-Xylene
o-Xylene
Styrene
Bromoform
1 ,4-Dichlorobenzene-d
4
Cumene
1 ,1 ,2,2-Tetrachloroethane
Amo^rt >IAG
ag ' " '
U
U
U
U
0.004 J
U
U
IS 3
0.001 J
U
U
U
U
0.001 J
0.001 J
0.001 J
0.002 J
U
IS 4
0.001 J
U
RT ; i>et turtit
: US
0.001
0.001
0.001
0.001
7.74
0.001
0.001
9.94
8.55
0.001
0.001
0.001
0.001
10.29
10.53
11.24
11.28
0.001
15.05
12.01
0.001
Quan- limit
«g
0.05
O.OS
0.01
0.05
0.05
0.«5
O.tll
0.05
0.05
«.05
0.05
0.05
0.05
0.10
0.05
0.05
0.05
0.05
0.05
NA- Not Applicable; Det Limit Detection Limit; Quan. Limit: Quantitation Limit
IS: Internal Standard; U: Undetected; B: Present In Blank; J: Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
Triangle Laboratories, Inc.
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Savarv3.7
Printed; 16:29 09/08/1998
0 , 21
-------
Pacific Bnvtammental Services
Project Number: 46323 Method 8260 VOST
Sample File: HW897 Sample ID: VOSTBLK 090498 T/TC
Client Project: R012.001 Date Received: // Response File: ICALH904
TIJ ID: VOSTBUKU9049S
Date Analyzed: 05/04/98
Surrogate Summary : .
Dibromofluoromethane
Toluene-d
4-Bromofluorobenzene
'^^jiy
0.280
0.273
0.314
f 1'f B';f '^ •;'
4.91
7.64
12.22
••f^jC'
I
2
2
• : .%KEC
112
109
126
Reviewed by V^QA^ Dace C| / *K /
NA- Not Applicable; Det Limit: Detection Limit; Quan. Limit: Quantitation Limit
IS: Internal Standard; U: Undetected; B: Present In Blank;): Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
Triangle Laboratories, Inc. Savar v3.7
801 Capitola Drive • Durham, North Carolina 27713 Printed: \&29
Phone: (919) 544-5729 • Fax: (919) 544-5491
-------
Project Number: 46323 Method 8260 VOST
Sample File: HW897 Sample ID: VOSTBLK 090498 T/TC
Client Project: R012.0&1 Bate Received:
Date Analyzed
// ; Response «!OULH$84
^ ' flO/ft/t'/QO ]• ." • - •' ' '•,•---• \-~-~
* , U3r'V*W.3O" :' : ' : • •-.•.•',•'.••:":
Analyte
Pentafluorobenzene
1,3- Butadiene
Vinyl bromide
n-Hexane
1 ,2-Epoxybutane
Iso-Octane
1 ,4-Difluorobenzene
Ethyl acrylate
.. A*<*at .; 'JUte
••' : ag -.:•' •.'•". ;
ISl
U
U
0.001 J
U
U
IS 2
U
:".'RT.' .;['• Det.:tuftit ^-^
•j Ug
5.04
0.001
0.001
3.64
0.034
0.001
5.77
0.001
Q^.Umir;
:-«g . .- ••
0.25
0.25
0.25
0.25
0.25
0.25
Reviewed by
NA- Not Applicable; Det. Limit: Detection Limit; Quan. Limit: Quantitation Limit
IS: Internal Standard; U: Undetected; B: Present In Blank; J: Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
Triangl e Laboratories, Inc. Savar v3.7
801 Capitola Drive • Durham, North Carolina 27713 Printed: 1654 09/08/1998
Phone: (919) 544-5729 • Fax: (919) 544-5491 ^
-------
C-J
09-04-98 15:53
s: UOSTBLK T/TC
Triangle Laboratories, Inc. (919) 544-5729
Instrument H
HW897 „ ft
100
X.FS-
0
Min
5.84
4 31$
t
I
H t
5.
'I ,
55 7 .
/j|
JP
77
64
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94 12
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15
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4.0 6 = 0 8 = 8 18. 6 12.0 14.8 16.0 18.0 28.8
QD
-------
QUAN OB : HWS97
LAB-BASE QUAN
09-O4-93
It-; 45
No. MAT FOR REV Delta
Area P.hlags
RT
QM Name
1
2
3
4
5
6
7
S
9
10
11
12
13
14
15
16
17
18
1°
20
21
~> "•
23
24
•-> r
xu •— '
26
'-> j
23
29
30
31
32
33
34
35
36
37
38
39
41
42
43
44
45
46
47
48
49
50
100
100
100
100
100
100
100
0
98
0
100
0
0
0
92
73
79
0
100
0
0
0
0
0
0
71
70
0
0
0
0
100
0
0
0
0
0
0
0
j\ -T
'HO
89
0
0
0
77
0
0
0
0
0
85
96
95
79
97
90
89
0
74
0
91
0
O
O
70
40
41
0
77
u
i)
t )
O
O
o
49
46
O
Q
C)
0
09
0
0
0
0
0
0
0
62
0
0
0
58
0
0
0
0
0
99
98
96
98
Q9
97
93
0
82
0
96
0
0
O
84
7 '7
86
0
9O
0
0
0
0
n
0
& 3
e>7
O
0
0
0
'59
0
0
0
0
0
0
0
feo
88
0
0
O
68
0
0
0
0
0
_2
0
-1
0
1
0
0
o
0
0
0
0
0
0
2
,-j
i.)
0
n
0
O
0
o
0
o
1
1
0
0
0
0
i
0
0
0
0
0
0
0
,-\
o
1
0
0
0
0
0
0
0
0
0
3o70831
4037552
3878054
1386261
1823460
4689891
2576768
0
92252
0
105020
t")
0
0
1°67C
•'itV'ri
1.0200
o
18424
0
0
0
O
0
(.1
7204
38-14
0
0
o
0
495836
0
0
0
0
0
0
0
47340
0
0
0
3636
0
0
0
0
0
bv
bv
bv
bv
bv
bv
bv
bv
bv
bb
hh
A
bb
5.
5.
9.
15.
4.
7.
12.
0.
0.
0.
1.
0.
0.
0.
2.
-.
2.
O .
3 .
i )
0.
i).
0
0.
04
77
94
05
91
64
22
00
96
00
46
00
OO
'JO
56
C C^T
64
oo
U<4
OO
OO
oo
oo
OO
168
114
117
152
113
98
95
35
50
62
04
64
101
Q6
142
> 7,^
43
41
84
'~j~,
96
i1- "%
43
*7 T
0,. OO 9t>
bb
bv
4,
50
4 . 7 5
0 .
oo
0.00
0.00
--1 3
33
12:0
97
117
0.00 75
bv
5.24
0
0
oo
.00
0 . 00
0 . GO
0 . 00
O . 00
0 . 00
bb
bb
7
0
0
0
8
0
0
0
0
0
.74
.00
.00
.00
.55
.00
.00
.00
.00
.00
78
62
130
60
93
41
83
75
4" """ TT
o
92
75
97
69
164
76
43
129
107
112
Pentaf 1 uorobenzene
1 ., 4-Di f 1 uorobenzene
Ch Lorobenzene-d5
1 , 4-Dich Iorobenzene-di4
Dibromof 1 uorome thane
Toi uene-d8
4-Bromof 1 uorobenzene
0 ich iorodi f 1 uorome r:har»e
Chlorome thane
Vinyl Chloride
Bromomethane
Ch 1 or oe thane
T r L c h i o r o f i uorome t ha ne
1 , 1 -0 I '._ h i. o roe t he n,-
lodomech;.! ne
C>:i r be1 n '.J i s u 1 f i de
Ac a to* ie
A L 1 / 1 oh lor i 'V.-
Me t h y L e n e < ':. h i. o r i d e
Aery loni tr i J..-;
trans- I , >-OIcnloroeth.2
1 ., 1-0 i c h i o r <:<••> t .'id rir-
Viny^ ace cat a
.2 ., 2 ~ 0 L c h i o r o <.•> r > j p a ne
cis-1 , 2-lJiciiioroethene
2-8u tanone
C h 1 o r o f o r rn
8 r o rn > j c h 1 o r o m e t ha n e
1 , 1 , l - )~r ichloroethane
C a f b o ri t e t r a c h i o r L d e
1 , 1 -Oichloropropene
Benzene
1 , 2-Oicn io roe thane
T r i c h 1 o r oe t he ne
1 , 2-Dlchloropropane
D i b r omoma t ha ne
Methyl methacrylare
8 r omod i c h 1 o rorne t ha ne
n
cis-1 ,3-Oichloropropene
4 Me thy 1 -^-pentanone
Tol uene
trans-1 . 3-Dichloroprope
1,1, 2-Tr ich Loroethane
Ethyl methacrylate
Tetrachloroethene
1 , 3-~Dich loropropane
2-Hexanone
Dibromochlorome thane
1 , 2-Dibromoethane
Chlorobenzene
Data Review: YR
Date:
-------
No. MAT FOR REV Delta
Area P.Flags
RT
QM Name
51
52
53
54
c t;,
56
57
58
59
60
61
62
63
64
65
66
67
t> 8
6c>
70
71
72
73
74
75
76
77
78
79
0
43
72
62
69
0
74
0
65
0
79
15
84
79
56
72
85
74
0
92
0
0
68
81
0
96
62
96
88
0
21
55
55
64
0
62
0
33
0
66
10
67
68
•z, •".>
59
70
St.
0
70
0
0
c.(-->
63
0
91
23
88
y?
0
c, "*
66
55
64
0
62
r)
73
0
73
37
78
71
55
59
70
00
0
81
O
0
60
75
0
QO
90
91
87
0
2
2
4
5
0
3
0
1
0
3
-31
3
4
2
0
1
0
0
1
0
0
2
3
0
6
6
6
6
0
2740
11892
6024
23120
0
15420
0
13000
0
5764
1393252
10632
14408
18488
15250
4329ft,
24988
0
377815
vf
0
2971^
5 '31 7'->
0
55508
1401.6
1200^6
41363
bb
bv
A
A
bv
A
A
A
A
bv
bv
A
A
A
A
wai
A
bV
bb
A
bv
0.
10,
10.
11.
11.
0.
12.
0.
12.
0.
12.
12.
12.
13.
13 ,
14,
14.
1.4 .
0.
14.
i5.i3 G^-
fC\ c,
. OO
I1"-1 . 12
131
106
106
106
104
173
105
33
156
75
120
75
126
126
105
11.9
105
105
11 '-3
146
' 146
°1
•-'1
i (6
75
130
j. '-1 „ „! ^ X ? — '
19.
19
. 3 2
5 ^
128
180
1,1,1,2-Tetrachloroetha
Efchy [benzene
m-/p~Xy lene
o-Xy lene
Styrene
Bromof orm
Cumene
1, 1,2,2-retrachloroeth;
Bromobenzene
1 „ 2 , 3-Tr ich ioropropane
n-Propy 1 benzene
trans- 1,4-0 ich Loro-2-b
2-Chloroto i uene
4-C h 1 o r a to L ue ne
1 ,3,5-Trlmeth y L b e n z * n e
te r t -6 u t y i !>••: n z e ne
1,2., 4 - T r i met hy :. L-e n ze ne
.5 a c - 8 1 j t y !. b e n ~ e r i e
p-Cymene
L , .3 - 0 i c h 1 o t • o b e n ^ e ri -5
1 , 4-D ich Lorc'benrei'ie
Benzyl cnion^e
n - 6 1 J t y 1 1 e n z e n e
1,2- 0 i c i'l i o r < :• b e n .: e n e
1 , 2 - 0 i. b r o m o - 3 - c h 1 o r
1 ,2 , 4 -Tr ioh 1. ore-be n /
H e > a c n 1 o r o b u t a d i c? n e
Naphtha i.-jne
1 , 2 , 3- T r i c h 1 o robe nz
opr
ent
enc
•') r»
Jo
-------
QUAN DB : HW897
No. MAT FOR REV Delta
LAB-BASE QUAN
Area P.Flags
09-04-98
16:56
RT
QM Name
1 100 85 99 0 3670831 bv
2 100 96 98 1 4037552 bv
3 100 95 96 -2 3878054 bv
4 1OO 740 A
12 0 0 OO 0
13 0 0 0 0 O
14 0 0 0 0 0
5.04 168 Pentaf1uorobenzene
5.77 114 1,4-Oifiuorobenzene
9.c:>4 117 Chlorobenzene-dS
15.05 152 1,4-Dichlorobenzene-d^
4.91 113 0tbromofluoromethane
7.64 98 Toluene-d8
12.22 95 4-Bromof1uorobenzene
0.00 39 1,3-Butadiene
0,. 00 106 Vinyl bromide
0.00 73 MT3E
3.64 57 n-Hexane
0.00 42 1,2-Epoxybutane
O.OO 57 Iso-Octane
O.oo 55 Ethyl acrylate
Data Review: W
rv»*A. _. . '"V
Date:
0 . 27
-------
OvJ
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(896 -8) 96 iLbSMH
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Sample: UOSTBLK T/TC
Triangle Laboratories, Inc. (919) 544-5729
Instrument H
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09-04-98 15:53
Sanple: UOSTBLK T/TC
Triangle Laboratories, Inc. (919) 544-5729
Instrument H
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-------
IO
ro
09-04-98 15:53
Sample: UOSTBLK T/TC
Laboratories, Inc. (919) 544-5729
Instrunemt H
HW897 524 (5.241)
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250 300 350
-------
89-04-98 15:53
CO
0-5
Triable Laboratories, Iflc. (919) 544-5729
Sample: UOSTBLK I/TC Instrument H
HU897 774 (7.741)
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09-04-98 15:53
Sanple: UQSTBLK T/
Triangle Laboratories, hie. (919) 544-5729
Instrument H
HW897 1053 (10.531)
100
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o
09-04-98 15:53
Sanple: UOSTBLK T/TC
Triable Laboratories, Inc. (919) 544-5729
Instrument H
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09-84-98 15:53
Triangle Laboratories, Inc. (919) 544-5729
Instrument H
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•"':•'• = •' '":' •'•' .'' ' •<' ^lEjCif
Project Number: 46323
Sample File: HW903
Client Project: R0I2.001
I1JID:214~27-4A; /f :: ' ' "
•. •; :•:• .•:.:•:, • ••:•••:• '• •.•.•.•....•:/.•:;.•::. :'•'.*..
Date Received: 07/29/98
Date Analyzed 1 09/04/98
%.;.-. ;:,;.-Y;.>..;:.;,'': :: ?, . . ' •
Method
Sample ID:
8260 VOST
S-V-2-4-A T
Response File: ICALH904
Analyte : : ; Aa
Pen tafluorobenzene
Chioromethaiie
Vinyl Chloride
Bromomethane
Chloroe thane
TrichloroBuoromethane
1,1-Dichloroethene
lodomethane
Carbon disulfide
Acetone
Allyl chloride
Methylene chloride
Acrylonitrile
trans- 1 ,2-Dichloroethene
1,1-Dichloroethane
Vinyl acetate
cis-l,2-Dichloroethene
2-Butanone
Chloroform
1 ,1 ,1-Trichloroe thane
1 ,4-Difluoro benzene
Carbon tetrachloride
Benzene
1 ,2-Dichloroethane
Trichloroethene
1 ,2-Dichloropropane
- ' • •'•••• ••"*"'..' :.' ' -. . ' • . " - •
Etfr .- •
IS 1 5.05
0.390 B 0.96
U
0.086 B 1 .47
0.311 1-61
U
U
U
0.943 2.57
2.048 BE 2.67
U
U
U
U
U
U
U
1.402 BE 4.48
U
U
IS 2 5.78
U
0.711 B 5.24
U
U
U
Defctuait
0.001
0.001
0.001
0.001
0.001
0.001
0.006
0.001
0.001
0.001
0.001
0.001
0.001
•o.ooi
0.001
0.001
0.001
Quan. limit
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
NA- Not Applicable; Det Limit: Detection Limit; Quan. Limit: Quantitation Limit
IS: Internal Standard; U: Undetected; B: Present In Blank; J: Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
Triangle Laboratories, Inc.
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Savar v3.7
Printed: 17:09 09/08/1998
-------
• • .- .• •;. - •;.' •'•
Project Number 46323
Sample File: HW903
Client Project R012.0&1
TLI ID: 214-27-4A If
'• - /' »- '" •:.' -V • :i:> •• '•?:•' -•••'::''•}% '•':..; :•"' >
:' • . ".;..';;-:: ' . '• ' • • .' .!:':-:v-::-- • ;. - -
Date Received: 07/29/98
Date Analyzed : 09/04/^8
;.. !- ..-. '.•''- '.', ' ' / ..' *•'; • ;j -. : •... ;V" ' • •
Method
Sample ID:
Response File:
''•:.::- :' "
8260 VOST
S-V-2-4-A T
ff19**
Analyse :
Methyl methacrylate
Bromodichloromethane
cis- 1 ,3- Dichloropropene
4-Methyl-2-pencanone
Toluene
troiu-1 ,3- Dichloropropene
1.1 ,2-Trichloroethane
Chlorobenzene-d
Tecrachloroethene
2-Hexanone
Dibromochloromethane
1 ,2- Dibro moethane
Chlorobenzene
Ethylbenzene
m-/p-Xylene
o-Xylene
Sryrene
Bromoform
1 ,4-Dichlorobenzene-d
4
Cumene
1,1 ,2,2-Tetrachloroethane
^':^:%K.-:
u
u
u
u
0.820 B 7.74
U
U
IS 3 9.96
U
U
u
u
u
0.385 B 10.30
2.108 BE 10.54
0.784 B 11.25
0.145 B 11.29
U
IS 4 15.14
U
U
^:*f£"' -: .•;.'•
0.002
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
Quttfc Limit
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.10
0.05
0.05
0.05
0.05
0.05
NA- Not Applicable; Det Limit Detection Limit; Quan. Limit: Quantitation Limit
JS^nterna[Standard; U: Undetected; B: Present In Blank; J: Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
Triangle Laboratories, Inc.
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
I&O
Savar v3.7
Printed 17:09 09/OR/1998
(j '
-------
Pacific i&viHttuxtental Services
Proj ect Number. 46323 Method 8260 VOST
Sample File: HW903 Sample ID: S-V-2-4-A T
Client Project: R012.D&1
III IP: 214-27-4A
Date Received:
Date Analyzed
07/29/98
: 09/04/98
Response File: ICALH904
Surrogate Saraaaajy ; •
Dibromofluoromethane
Toluene-d
4-Bromofluorobenzene
;";il|pltllf
0.271
0.317
1.454
||^p
4.92
7.65
12.27
f:^k":H:?
i
2
2
I*!:/"*
108
12~
582
Reviewed by \S IXt^ Date_L/_A
NA- Not Applicable; Det Limit Detection Limit; Quan. Limit Quantitation Limit
IS: Internal Standard; U: Undetected; B: Present In Blank; J: Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
Triangle Laboratories, Inc. f Savar v3.y
801 Capitola Drive • Durham, North Carolina 27713 Printed: 17:09 09/08/199?
Phone: (919) 544-5729 • Fax: (919) 544-5491
-------
Paeiiie Eavii-onmental Services
Proj ect Number 46323 Method 8260 VOST
Sample File: HW903 Sample ID: S-V-2-4-A T
Client Project: R012.S01
ITJ ID: 214-27-4A
• ' ' '"'"'1 Date Received: 07/2S/9& \--.
i Date Analyzed: 09/(M/$$ i
Response File:
lOWUH^M
' • .'^?-..- ::
Analyte
Pentafluorobenzene
1,3-Butadiene
Vinyl bromide
n-Hexane
1 ,2-Epoxybutane
Iso-Ocune
1 ,4-Difluorobenzene
Ethyl acrylate
Amount* ••'"' $IA& " ' "'"RT .' : .,
•-•: t*g -'-;- . '"• . = •'• •' ' ••_.-• \
IS 1 5.05
U
U
1.423 BE 3.66
U
U
IS 2 5-78
U
Efetturtit l
ug
0.001
0.001
0.046
0.001
0.001
Quan. Limit
«8
0.25
0.25
0.25
0.25
0.25
0.25
OLAJG>
Reviewed by O (A\-> Date ^1 / O /'
NA- Not Applicable; Det Limit: Detection Limit; Quan. Limit: Quantitation Limit
IS: Internal Standard; U; Undetected; B: Present In Blank;): Estimated- Below QuantitaHon Limit; E: Estimated- Above Calibration Range
Triangle Laboratories, Inc. Savar v3T
801 Capitola Drive • Durham, North Carolina 27713 Printed: 16:55 09/08/1998
Phone: (919) 544-5729 • Fax: (919) 544-5491 t .1 *J
-------
cs
Data Review:
Date:
43
-------
QU'AN 08 : HW^03
No. MAT FOR REV Delta
LAB-BASE QUAN
Area P. Flags
RT
QM Name
1
^-
3
4
5
6
7
8
9
10
11
12
13
14
15
i<-j
17
18
19
? i.' i
21
T*' 'T*1
23
24
25
26
27
2.8
29
30
31
~- '".'
•.-' O
34
35
36
_, _r
38
40
41
42
43
44
45
46
47
~i ,'
48
49
50
08
75
58
53
0
70
37
0
0
0
100
as
0
o
0
77
98
0
0
0
0
0
o
'_^
0
100
0
0
o
0
0
LOO
o
0
0
0
o
0
100
0
f)
0
0
0
0
0
0
30
40
35
14
0
44
21
0
ij
0
82
3^
f)
0
i j
47
8O
r i
0
0
0
0
n
0
81
i )
O
O
1 1
o
9 1
1 )
0
'"'
0
o
0
80
0
0
0
O
0
0
0
0
78
TO
57
73
0
71
41
0
0
O
o<3
97
0
O
(3
82
88
0
i -|
0
ij
i )
•
0
9<4
0
0
0
1 ~l
0
00
0
o
0
0
o
0
07
0
0
0
0
0
0
0
0
-1
0
0
o
0
1
-r
O
0 |
0
0
o
0
0
0
1
T
0
0
o
0
o
I1')
'_,'
0
-2
0
0
o
0
0
0
0
0
0
0
o
0
-1
0
0
0
0
0
0
0
0
2725C'64 bv
2928352 bb
28OO662 bv
1303168 bb
1309212 A
3057952 bfc,
86505O4 A
• >
0^3^% <*>(£p'Pa~&
0
31093o bv
729776 bb
0
o
0
•"-'251134 bv
33O571.2 bb
(>
i-)
o
0
0
1 J
I)
2567383 vv
O
o
0
M
'"1
•3643147 vv
0
0
0
0 &0 fa.
rj
-TOOOOO',: /- <5io ecu
7236oo7 vv
0
0
0
0
0 <5&Ai
0
0
0
5
5
9
15
4
7
12
0
i^.
0
1
1
0
0
0
2
7
0
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7
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0
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0
0
0
. 05
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.96
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.65
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.OO
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, OO
. J ••'
. £, /
. or,
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.0"
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. OO
-, ' *J'J
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_ 48
. OO
. 00
. OO
. 00
. OO
. 24
. 00
. 00
. OO
.00
- OO
.. 00
. 74
.00
. 00
.00
.00
.00
..91-
.00
. 00
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lc,3
114
117
152
113
98
QS
85
1 h SO
62
0,;}
64
10 L
•"V-
14.:
76
43
41
c-
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128
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7 -
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62
130
6 j
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83
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6°
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129
107
112
Pentaf 1 uorobenzerie
1 , 4-Dif L uorobenzerie
Ch Iorobenzene-d5
1. , 4-Dichlorobenzene-d4
D ibromof 1 uorornethane
Tol uene-d8
4 - B r o rn o f 1 1 j o r ob e n z e ne
0 ichl orod 1 f 1 uoromethane
Chlorome thane
Vinyl Chloride
Sromome t hane
Ch loroe tharui
T r \ c h J. o ro f "' iJ'O r orne t ha ne
L , l ™D i '.: hi L o ro'-> t he i le
l*j> Joriier, hane
C.irbon d i :su 1 f ide
A i : a t o i "i e
Al i v L ch I. or '. dc;
hethiy i. ene oh i..jr ;. • ie
;nO T "'••'' i O1 1 1 i f i" L ', • :'
tr.ti-rr- L 2-D ich LOi-':iech..?rif-.
L , l-O i r- h ! o roe c h,-j ne
'•• LIV./I o.-.:eta t 2
^
.. , ,~U i.'- 1 1 Loropropo iV:-
r i i -1. , '.': -D i.ch Lomethene
."' -Sura none
C h Loro r" 'jrrn
8 rornoo hi j. o rome 1: ha ne
1 , L , 1 - T r i o h Lor o e t • i a n e
•2 a rbo n te t r a e i i J. o r I <.ie
1 , 1 - 0 i o 1 1 L o r op r ope ne
Benzene
i ., 2 -D i c. h I o r oe t ha ne
Trie h 1 o r o e t hi e r i e
1 , 2-0 ion loropropa ne
D Lbromometnane
M e t h y 1 m e t. h a c r y 1 a t: e
8 r omod ichl o r ome t ha ne
o is - 1 , 3-D ichloropropene
4 M e t h y 1 .j, p e n t a n o n e
Tol uene
trans- 1 „ 3-Dichioroprope i
1 , 1 , 2-T r i c h L o roet ha ne
Ethyl met hacry late
Te t r ac h 1 o roe t he ne
1 , 3-Dlch Loropropane
2-Hexanone
Dlbromochloromethane
1 , 2-D ibromoe thane
Chlorobenzene
Data Review.
Date:
-------
No. HAT FOR REV Delta
Area P,Flags
RT
QM Name
51
52
S3
54
55
56
57
58
59
60
61
62
63
o4
o3
ot>
o7
63
'-j'3
70
71
7 2
?- T
r1 J
74
75
76
77
78
70
0
81
88
78
0
0
0
0
0
u
0
0
0
0
0
0
84
57
76
0
0
22
71
0
0
0
0
0
0
o
48
59
51
0
0
0
0
0
0
0
0
0
t;
0
0
C 7
1?
4-oh lot-
vOrob^n :
ura^.i i^ne
1 , 2 , 5- Tr ion iorobenz
•-ne
opr
.3 ne
15 Me
-------
QUAN DB : HW9O3
LAB-BASE QUAN
09-04-98
20: 36
No. MAT FOR REV Delta
Area P.FLags
RT
QM Name
1
2
o
4
5
6
7
0
g
1O
11
1 ^
i a
67
76
57
53
0
68
38
0
.O.C
100
.41 .
30
49
35
14
0
44
21
0
' 1 \
95
78
72
57
73
0
71
41
-r -r
0
I- ,.)
^
. ~,
1
1
-1
9
0
2725964
2928352
28OO662
13031o8
1309212
-2 3957952
2
0
1 •"
-1
—
8650504
|
i 1 '"i J i*
0
-r tx 1 10
7119674
bv
bb
bv
bb
A
bb
A ^
Gr-r3! f
'. y. / QjO J
bv(Sp) ^
^ £^g) p
•*. i.-i "r i""i 11 '" ''7 f \ ' *" ' f" '"• ^^^^r i
5
5
Q
15
4
7
12
0
fCLP. ~
3
.05
.78
.96
. 14
,.92
.65
.. 27
Q
.00
C. 7
. 6 6
; -i
-, ^
168
114
117
152
113
98
95
39
106
73
57
C 7
55
Pentaf 1 uorobenzene
1 ., 4-Di f 1 uorobenirene
Chlorobenzene-d5
1 „ 4-D Ichioroben2ene-d4
Dibromof 1 uoromethane
Tol uene-d8
4-8romof L uorobenzeno?
1 ^ — R 1 1 1" 3. d i ^ n f
Vinyl bromide
MTBE
n-Hexane
F h h v 1 a c r v i a t: ^
51
-------
M-Sep-98 19138
Sample: S-U-2-4-A
Triangle laboratories, Inc.
T 214-27-4A TLIU46323
(919) 544-5729
Instrument H
HU903 96 (0.960)
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0-
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HASTER 9 (1.250) Chloronethane
100
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0
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5
44
, , 1,1.1
9
52
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50 100 150 200 250
216064
300 350
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Project Number 46323
Sample File: HW898
Client Project: RS12.001
Til ID: 214-27-4B X
r'-isf-*' ;:':-' lfS^;':^
iictjavramm ^ __ : .••ves;.
\D^^cerf|^m>
•,-'., 'i': '/:-.:^l : .' ;V~ -.''.'"'• *t •:•:-":::•-.'•. ' ''.'"
Dai^^eai(WM»»;!
Method 8260 VOST
Sample ID: S-V-2-4-B TC
>> .." RespMO ^,w ; •
IS 1 5.03
0.766 B 0.95
U
0.141 B 1.47
U
U
U
U
U
0.006 BJ 2.67
U
0.020 BJ 3.03
U
U
U
U
U
U
U
U
IS 2 5.77
U
0.006 BJ 5-23
U
U
U
Dettuttit ; Quaa. limit
• tig : eg
o.os
0.001 0.05
o.us
0.001 O.OS
0.001 0.05
o.ooi o.os
0.001 0.05
0.001 O.OS
0.05
0.001 0.05
O.os
0.005 0-05
0.001 O.OS
0.001 0.05
0.001 0.05
0.001 0.05
0.001 0.05
0.001 0.05
0.001 O.OS
0.001 0.05
0.05
0.001 0.05
0.001 0.05
0.001 0.05
Det Limit Detection Limit; Quan. Limit: Quantiution Limit
IS: Internal Standard; U: Undetected; B: Present In Blank; J: Estinuted- Below Quantiution Limit; E: Estimated- Above Calibration Range
Triangle Laboratories, Inc.
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Savar v3.7
Printed: 1629 09/08/1998
65
-------
"'•v: ••-:• ' ' -V:': Pacific Environmental Services .' .-•• ;v.: :^-:;A :'-.-:' :';. .
Project Number. 46323
Sample File: HW898
Client Project R&12.0&1
TU ID: 214-27-4B
Method 8260 VOST
Sample ID: S-V-2-4-B TC
Date Received: 07/29/98
Dale Analyzed : 09/04/98
Response File:
HCA1JH904
Analyte : ; .
Methyl methacrylate
Bromodichloromcchane
cis-1 .3-Dichloropropene
4-Mechyl-2-penranone
Toluene
trans- 1 ,3-Dichloropropene
1 ,1 ,2-Trichloroethane
Chlorobenzene-d
Tetrachloroethene
2-Hexanone
Dihromochloromethane
1 ,2-Dibromoethane
Chlorobenzene
Ethylbenzene
m-/p-Xylene
o-Xylene
Scyrene
Bromoform
1 ,4-Dichlorobenzene-d
Cumene
1,1 ,2,2-Tetrachloroethane
^•\--^AW^^%^\;%;RT; ,
'•'•? " tig -' ••-'!•=' -.- • '-":: '"'••. :-'- '
u
u
u
u
0.009 BJ 7.73
U
U
IS 3 9.94
U
U
u
u
u
0.001 BJ 10.29
0.001 BJ 10.53
U
0.001 BJ 11.29
U
IS 4 15.05
U
U
Sei.Ljbtti* ;. "-J':
• ttg" ;. -• ' -.'
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
^rf^t^Ht* • triit-Bffjf y
^M^
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.10
0.05
0.05
0.05
0.05
0.05
NA- Not Applicable; Det Limit: Detection Limit; Quan. Limit: Quantitation Limit
IS: Internal Standard; U: Undetected; B: Present In Blank; J: Estimated- Below QuantitaHon Limit; E: Estimated- Above Calibration Range
Triangle Laboratories, Inc.
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Savar v3
Printed: 16:29 09/08/19'
oo
b D
-------
Pacific Envtionmenfal Services
Project Number 46323 Method 8260 VOST
Sample File: HW898 Sample ID: S-V-2-4-B TC
Client Project: R&12.001
JU ID: 214-27-4B ; :
Date ^Received:
Date Analyzed
07/29/9E
: 09/04/98
Response File:
ICALH904
Surrogate Summary ;'•'.' • "• '.'. Amoiw^ j;^- i^ !:•'>. -.^^'o -KT •; r: ' ISRel. _\ .' . -::;';-%RiC" •>-.-
: - - " "' -'" ' ; ' fogjf "-:".r" '':$:;: .: : :'. ' /:'••.. l"": ' •" : :' '''•''"' -'•"•':•:'• '-?: :':S:Tf. ::- :':";
Dibromofluoromethane
Toluene-d
s
4-Bromofluorobenzene
0.284
0.283
0.324
4.90
7.64
12.22
i
2
2
114
113
130
Reviewed by -ffll Date /
NA- Not Applicable; Det Limit Detection Limit; Quan. Limit Quantitation Limit
_^S:jn^enialjUndard;jJ^Undetected; B: Present In Blank; J; Estimated- Below QuanHtation Limit; E: Estimated- Above Calibration Range
Triangle Laboratories, Inc. Savar v3 7
801 Capitola Drive • Durham, North Carolina 27713 Printed: 16:29 09/08/1998
Phone: (919) 544-5729 • Fax: (919) 544-5491
67
-------
Pacific Bnvtmnmental Services
Project Number: 46323
Sample File: HW898
Method 8260 VOST
Sample ID: S-V-2-4-B TC
Client Project: R012.001
TUID: 214-27-4B
Date Received: 07/29/98
Date Analyzed 1 09/04/9$
Response File: ICALH904
Analyte
Pentafluorobenzene
1 ,3- Butadiene
Vinvl bromide
n-Hexane
1 .2-Epoxybutane
Uo-Octane
1 ,4-Difluorobenzene
Ethyl acrvlate
- ; . Amount .••::.••; JF£A0.';.: .- :; :> vRT. -: '_]'•.
IS 1 5.03
U
U
0.002 BJ 3.64
U
0.001 J 5.40
IS 2 5.77
U
" -f : . '
• jj^fc L»£E&Sv
ti&* "
0.001
0.001
0.035
0.001
<2u«n. Limit
ag
0.25
0.25
0.25
0.25
0.25
0.25
Reviewed by
Date
/
NA- Not Applicable; Det Limit: Detection Limit; Quan. Limit: Quantitation Limit
IS: Internal Standard; U: Undetected; B: Present In Blank; J: Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
Triangle Laboratories, Inc.
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Savar v3.7
Printed: 16:54 09/08/1998
-------
s is
X
•w
I- s|w 3
«a 3~ 5u
-------
QUAN DB : HW898
No, MAT FOR REV Delta
LAB-BASE QUAN
Area P.. Flags
O9-04-9S
RT
QM Name
1 100
2 10O
3 100
4 100
5 100
6 100
7 100
8 0
9 100
10 0
11 100
12 0
13 0
14 0
15 0
16 0
1 7 foo
18 0
19 92
2O 0
21 0
22 0
23 0
24 0
25 0
27 0
28 0
29 0
30 0
31 0
32 100
33 0
34 0
35 0
36 0
37 0
38 0
39 0
41 1OO
42 0
43 0
44 0
46 0
47 1-9-
48 0
49 0
5O O
84
96
96
79
'"'5
91
89
0
93
0
92
0
0
0
0
0
Z2
0
63
o
0
0
o
(j
o
0
0
0
0
0
94
0
0
0
0
0
0
0
-^
76
0
0
0
0
0
0
0
99
98
96
98
99
97
93
0
98
0
9 9
0
0
0
0
0
S4
0
70
0
0
0
0
0
0
0
0
0
t)
0
97
0
0
O
0
0
0
0
94
0
0
0
0
0
0
0
-3
1
-1
0
1
0
0
0
0
0
1
0
0
0
o
0
4
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
o
3528238 bv
3984048 bv
3876915 bv
1989388 bv
1775368 bv
4809862 bv
2620116 bv
0
2767137 vv
0
662062 bv
0
0
0
0
0
12332 vv
0
35o08 bv
0
i.)
0
0
0
Q
- . - 1
0
0
0
o
0
112648 bv
0
0
0
0
0
0
0 *r--i' r £1'
10736O bv
0
0
— ° (&)
o 6?)
0
0
0
5.03
5. 77
9 . 94
15.05
4 . 90
7.64
12 . 22
0.00
0.95
0.00
1 .47
0 . 00
O . 00
0 . 00
0 . 00
O.Ou
2 - fc 7
O . OO
.3 . 0 3
0.00
0 . 00
0 .OO
0 . 00
0 . 00
0 . 00
o.oo
0 . 00
0 . >)0
0.00
0 . OO
5.23
0 . 00
0.00
0.00
0.00
0 , 00
0 . 00
0 . 00
P^Llfl -7 ' J.
7.73
0.00
0.00
Pa& o . oo
paG o . oo
T. 11
o.oo
0.00
o.oo
168 Pentaf 1 uorobenzane
114 1 , 4-Dif luorobenzene
117 Chloroben,:ene-d5
152 1 ,4-Dich Iorobenzsne-d4
113 Dibromof luorornethane
98 Tcluene-dS
95 4-Bromof 1 uorobenzene
85 Dichlarodif Luorometharx
50 C hi orome thane
62 Vinyl Chloride
94 B r o m o m e t h a n e
64 Chioroetharie
10 1 T r i c h 1 o r o f 1 uo r ome t ha ne
96 l , 1-0 ich Loroe then.?
1 4 2 I o d o rn e t h a i i e
7 6 C a r b on d i s u 1 r i ci =•:-
43 :'ic.--:-tone
41 ALiyl cnloride
84 he t hy 1 e ne c i 1 1 o r * de
53 Aery loni tri 1 e
''•> 6 t r a n s - 1 , .2-0 i. c h i o r u • ~ r; n a
63 1,1- 0 i c h 1 o r o e t n a n a
4 3 V i n y 1 a c a 1: a t • -:•
77 2 , 2-0 ich Lor opropaoe
1 v 6 c i s - 1 . 2 - D i c h L o r o e the n g
/j ~ "• — ["•,' i i i*" 7i n i"*! f i £2i
^1 %_,' v_ U.J L 1 L* ili 1 1 k_l 1 1 w
;j.:. uhlorof orm
128 3 r ornoc h L o rome t: na ne
97 1 , 1 , 1 - T f i o h L o r o>-:. t; ha ne
117 Carbon tecrachlor ide
75 1 „ 1 •- u i c h 1 o r o p r o p • ? n •:?
78 Benzene
62 1 ,2-DicrUoroethane
130 Trichloroethene
63 1 „ 2-O I e h 1 o r op r opa ne
43 A — Methvl — 2~pentanons
92 Toluene
75 trans~l,3-Dichioroproi
97 1,1,2-Trichloroethane
69 Ethyl methacrylate
76 1 ,3-Dichloropropane
43 2-Hexanone
129 Dlbromochloromethane
107 1,,2-Dibrornoethane
112 Chloroben^ene
Data Review:
Date:
-------
No. MAT FOR REV Delta
Area P.Flags
RT
Qh Name
£ 1
52
53
54
55
56
5*7
f
58
59
60
61
62
63
64
65
66
67
68
to 9
70
71
/ il.
73
74
75
76
77
78
79
0
39
TO
0
71
0
0
0
0
54
0
58
6O
0
74
6t.
73
0
78
0
0
45
63
0
77
65
73
70
0
21
56
0
64
0
0
0
0
39
0
38
42
o
59
57
51
0
55
0
0
31
3Q
0
70
33
59
60
0
45
65
0
64
0
0
0
0
5ft
f)
S'~>
62
0
59
,:.- 7'
6'5
i)
7i i
0
0
j. .
64
0
78
84
85
78
0
2
2
0
4
0
0
0
0
3
0
2
3
0
1
4
1
0
1
0
0
3
i
0
7
c.
8
"7
0
1316
12924
0
17552
0
0
0
0
2280
0
38 5o
7780
0
7876
28832
l^t/28
0
212OO
n
O
2182O
234O8
0
29336
11224
64549
23412
bb
A
A
fid t
A
bb
A
A
A
A
A
A
A
bv
bb
bv
bv
0
10
10
0
11
'«* °
0
0
0
12
0
12
13
0
14
14
14
i.)
14
o
0
16
16
0
19
1'^
19
1Q
.00
. 29
.53
.00
.29
.00
.00
.00
.00
.84
.00
. 8°
,. 1 5
. 00
.07
•.•£.'__
.72
. 00
.82
. 00
. 00
.87
.35
. OO
. 13
.. 33
.34
. 54
131
106
106
106
10 '4
173
1 (~\ c
1O ;>
83
156
75
120
75
L26
126
105
11Q
I'"1' 5
10--.
11°
I'-tO
1-4.':.
'"-> 1
'-31
l'4to
/ 3
18O
•>'" C.
128
180
1, 1,1,2-Tetrachloroethar
Ethylbenzene
m-/p-Xy lene
o-Xylene
otyrene
Bromof orm
Cumene
1, 1,2.2-Tetrachloroetha
Bromobenzene
1,2, 3-Tr ichloroproDane
n-propy 1 benzene
trans-1 ., 4--Dichioro-2-bu
2 -C h 1 oroto 1. ue ne
'•i-Chlorotol uene
1,3, 5- T r i roe r. h ••/ I be nza ne
tert-Buty 1 benzene
i . 2 ., '4 - T r i me t liy i be n <;: = ne
^ e c - 6 u t y i'oenz^ne
P -Cvmene
1 . 3-D i c h 1 o robe nae i K-;;
,t. . 4 - D i c hi i o r o b e n z e n a
Senzy ! oh Lor Lcie
n-8ufy lben.:ene
L , 2- 0 1 c h i o r obe n ze ne
t
1
1 , 2-Dibromc-3-ohioroprof
1 ., 2 , 4 - T r 1 c h 1 o r obe n z e ne
H e x a c h 1 o r o but a < j i e n e
Naohthalene
1 „ 2 , 3-Tr tch Lorobenzene
71
-------
QU'AN D8 : HW89S
No. MAT FOR REV Delta
LAB-BASE QUAN
Area P.Flags
O9-04-98
RT
QM Name
1
3
4
5
6
7
8
9
10
11
12
13
14
100
100
100
100
100
100
100
0
T^T
86
70
84
96
96
79
95
91
89
-y -^
0
"*n
69
,
49
99
98
96
98
99
97
93
0
36
-1 3528238 bv 5.03
2 3984048 bv 5.77
-2 3876915 bv 9.94
3 1989388 bv 15.05
1 1775368 bv 4.90
-1 4809862 bv 7.64
-1 2620116 b
0 0
_«• OOT"?,/, £,
-1 13336 A
1 O o-^
f x*C" ^ >• X. -iC. .•£..£*.
\ ) W-S r**M& ^ f\y
0 . 00
-------
CO
IN
89-84-98 16:34
Sample: S-U-2-4-B
Triangle Laboratories, Inc. (9ly) 544-5729
T/C
214-2V-4B TLI#46323
Instrunent H
HU898 95 (0,950)
1001 5
XFS
49
0
52
M/Z 50 108 150 2SS
HU898'95 (0.951) REFINE
5
XFS
49
0 '•• '•'
0
52
•«- n , •——-,
w/z 50 lee 150 200
8260B 9
1001 5
XFS
• 4i4i
(0.960) CMoromethane
0
52
*'2 50 IS® 150 2C*0
442368
258 300 350
485504
259 300 350
FIND
100
256 ' 300 350
-------
M
o
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09-04-98 16:34 Triangle Laboratories, Inc
Sanple: S-V-2-4-B T/C 214-27-4B TLI If 46323
(919) 544-5729
Instrument H
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SanplR: S-U-2-4-B T/C 214-27-4B TLU463Z3 Instrument H
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89-04-98 16:34 Triangle Laboratories, Inc
Sample: S-U-2-4-B T/C 214 27-4B TLIM6323
(919) 544-5729
Instrument H
HW898 540 (5.401)
57 1*7 1424
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-------
X t^ifieEBvtemne^Ssvices '. > •/..,
Project Number: 46323
Sample File: HW904
Client Prefect R012.001
T13 ID: 214-27-12A
Dale Received: 07/29/98
Date Analyzed : 09/04/93
Method 8260 VOST
Sample ID: S-V-3-3-A T
Response File ICALH904
Analyte
Pentafluorobenzene
Chloromethane
Vinyl Chloride
Bromomethane
Chloroethane
Trichlorofluoromethane
1,1-Dichloroethene
lodomethane
Carbon disulfide
Acetone
Ally! chloride
Methylene chloride
Acrylonitrile
trans- 1 ,2-Dichloroethene
1 ,1-Dichloroethane
Vinyl acetate
cis-1 ,2-Dichloroethene
2-Butanone
Chloroform
1,1,1- frichloroethane
1 ,4-Difluorobenzene
Carbon tetrachloride
Benzene
1 ,2-Dichloroethane
Trichloroethene
1 ,2-Dichloropropane
•; . . Amount ';'
0.001 0.05
0.001 0.05
0.001 0.05
0.001 0.05
0.05
0.001 0.05
0.001 0.05
0.001 0.05
0.05
0.001 0.05
0.001 0.05
0.001 0.05
NA- Not Applicable; Det Limit: Detection Limit; Quan. Limit: Quanritation Limit
IS: Internal Standard; U: Undetected; B: Present In Blank; J: Estimated- Below Quantitarion Limit; E: Estimated- Above Calibration Range
Triangle Laboratories, Inc.
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
2/1
Savar v3.7
Printed; 17:09 09/08/1998
34
-------
; ? Pacific Enviimimeiital Services
Project Number 46323
Sample File: HW904
Client: Project: R&12.0&1
TU ID: 214-27-t2A.
Dale Received: §7/29/98
Date Analyzed : 09/04/98
Method 8260 VOST
Sample ID: S-V-3-3-A T
Response File: ICALH904
Aualyte
Methyl methacrylate
Bromodichloromethane
cis- 1 ,3- Dichloropropene
4-Methyl-2-pentanone
Toluene
trans- 1 ,3- Dichloropropene
1 ,1 ,2-Tnchloroethane
Chlorobenzene-d,
Tetrachloroethene
2-Hexanone
Dibromochloromethane
1 ,2-Dibromoethane
Chlorobenzene
Ethylbenzene
m-/p-Xylene
o-Xylene
Styrene
Bromoform
1 ,4-Dichlorobenzene-d
4
Cumene
1 , 1 ,2,2-Tetrachloroethane
• / ^i;^;t;" RT' •' '•'
U
U
u
u
3.898 BE 7.79
U
U
IS 3 Low 9.99
U
U
U
u
u
2.716 BE 10.36
12.924 BE 10.62
3.540 BE 11.32
0.490 B 11.35
U
IS 4 Low 15.17
U
U
E>et Lintit Quan. limit
0.003 0.05
0.001 0.05
0.001 0.05
0.002 0.05
0.05
0.001 O.OS
0.001 0.05
0.001 0.05
0.003 0.05
0.001 0.05
0.002 0.05
0.001 0.05
0.05
0.10
0.05
0.05
0.002 0.05
0.001 0.05
0.003 0.05
NA- Not Applicable; Dirt. Limit Detection Limit; Quan. Limit Quantitation Limit
: Present In Blank; J: Estimated. Below Quantitation Limit; E: Estimated- Above Calibration Range
Triangle Laboratories, Inc.
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Savarv3.7
Printed: 17:09 09/08/1998
85
-------
Pacific Environmental Services
Project Number 46323 Method 8260 VOST
Sample File: HW904 Sample ID: S-V-3-3-A T
Client Project; R012.0&1
TU ID: 214-27-12 A
Dale Received: 07/29/98
Dale Analyzed s 09/04/98
Response File: ICALH9Q4
*«*.*«* ;.. ^ :, ;;
Dibromofluoromethane
Toluene-d
3
4-Bromofluorobenzene
Tf;?tr: -
0.292
0.401
1.737
RT
4.92
7.68
12.36
ISBel- { I;/'.;/ ;••;• %K£C ;
1 117
2 160
2 695
Reviewed by VJ (JU*b Date.
NA- Not Applicable; Det Limit: Detection Limit; Quan. Limit Quantitation Limit
IS: Internal Standard; U: Undetected; B: Present In Blank;): Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
Triangle Laboratories, Inc. Savar v3.7
801 Capitola Drive • Durham, North Carolina 27713 Printed: 17:09 09/08/1998
Phone: (919) 544-5729 • Fax: (919) 544-5491 . , -. O C
-------
Pacific Environmental Services
Project Number: 46323 Method 8260 VOST
Sample File: HW904 Sample ID: S-V-3-3-A T
Client Project: R&12.$01 Data Received: 07/29/98 Response B% IOLLH9M
TIJJD: 214-27-12A '. • -.\ '"'' Vf''' 7t:- ®fe ^
Date Analyzed 109/04/98 " '--'^l- •':•?.. £•', f--' ••.'•
fMlajyvC _ .- * ..:;'..'_..: -' .. ... :.:."
Pentafluorobenzene
1,3-Buudiene
Vinvl bromide
n-Hexane
1,2-Epoxybutane
Iso-Octane
1 ,4-Difluorobenzene
Ethyl acrylate
IS 1 5.05
U
U
5.008 BE 3.66
U
U
IS 2 579
U
0.001
0.001
0.055
0.001
0.001
0.25
0.25
0.25
0.25
" 0.25
0.25
Reviewed by.
NA- Not Applicable; Det Limit: Detection Limit; Quan. Limit: Quantitation Limit
IS: Internal Standard; U: Undetected; B: Present In Blank; J: Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
Triangle Laboratories, Inc. Savar v3.7
801 Capitola Drive • Durham, North Carolina 27713 Printed: 16:55 09/08/1998
Phone: (919) 544-5729 • Fax: (919) 544-5491
0:
-------
00
00
-04-98 20:21
: S-U-3-3-A
Tr- i a vtq 1 e La bora tor i es, I vie
T 214-27-12A TLIH4G323
HW904
108
HFS-
e
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1.06
5.02
4.23
3.87
1
4.0
6.0
18 64
9.25
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11,87
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33658048
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12.8
18.0
20.0
.
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-------
UAN DB
HW9Q4
LAB-8ASE QUAN
09-04-^S
2 r: L2
No. MAT FOR REV Delta
Area P. Flags
RT
QM Name
I
2
~r
4
5
to
7
3
9
10
11
12
13
14
15
1.-,
17
13
11 1 "i
-' J
21
->.—.
^1 .1"'
24
25
«.'. t
27
2Q
29
3O
31
52
33
34
35
•60
37
38
4O
^"t \J
41
42
43
44
45
46
47
48
49
50
35
0
32
to 3
0
40
0
0
i')
i,)
9 to
Q
o
0
0
82
100
r.i
O
M
O
0
0
0
100
0
0
0
0
0
100
0
0
0
0
4-4—
0
0
100
0
0
0
0
0
C 1
0
0
0
11
o
19
20
O
25
0
0
O
o
60
0
•')
l)
0
48
i". "*
0
o
J "l
1 '1
'J
o
1 '1
8 'I
O
O
0
0
0
V-. C
0
0
0
1 J
- 4.-_.
t j
0
80
0
0
0
0
(J
•""' z
0
0
0
45
0
33
32
0
40
0
0
0
0
Qp,
0
0
o
o
8 to
9L
0
1 1
O
o
o
o
0
'"'to
o
0
o
IJ
0
Q.--5
0
o
0
0
c •-
0
0
97
0
O
0
o
0
£ T
0
0
0
-1
0
1
4
O
1
0
0
0
0
-1
o
o
0
0
1
~ 1
0
o
o
ri
r
O
O
- o
0
0
0
0
0
0
0
0
0
0
—
0
0
3
0
0
0
0
0
c;
0
0
0
22801.36 bv
21862C'6 A
922468 bv
351408 A
1178340 A
3730528 bv
771609& A
n
^ftO^Z ** ® ?&-&
o
178016 bv
O
O
o
n
4638861 bv
4217O83 vb
O
''•; ($® f
u
1 )
r.i
1 )
o
4 4. 1.40. -.to VV
0
O
i j
O
0
.16474820 bv
0
0
0
I'")
.->1 C-, ,00 •_,(, §fi] f
0
0 -rt
V-,,-s-.. , ,> <^J
25665920 bv
0
0
0
0
0 /-svv
i /• T i t ••>.•'.•••. xy'rL/ I
0
0
0
5.05
5.79
o _ C.(
o . oo
0 . OO
0 . 00
0 . 00
o.oo
0 . 00
7.79
0.00
0 ,. 00
0.00
0.00
a * 0.00
0.00
0.00
0 . 00
168 Pentaf 1 uorobenzene
114 1 . 4-D i t 1 uorobenzene
117 Chlorobenzene-dS
152 1 , 4-D ich Iorobenzene-d4
1 1 3 D i b r o m o f i u o r o m e t h a n e
'"•'8 ToLuene~d8
95 4-8romof I uorobenzenc-
85 Dich lorod if I uciromethane
3b~:IJ !-h Lot-ome ttiane
to 2 Vinyl Chloride
9 4 3 r o m o m e 1 1 1 a n e
64 Chi o r . ~j e t h a n e
1O.L T r ichlurof ' noromethane
'36 1 .. i—O ioh Loi~oe !'. iiene
14.: 1 ooo m..-- than. •-:•
7.;. "arbon d i T.U L i: rJe
aC f-icetone
•:* L iil IV 1 Ch I'jr i'.dc:;
84 he thy 1 .-;• n - 1 , .".: - 0 i c i 1 1 o r oe t he ne
43 : -fruta none
83 C h 1 oru tor i'ii
1 ."8 8 r omoc h i. o rorne t ha ne
:~' 7 1,1, 1 -- T r i. o 'n L O' r oe t ha M«.
117 Car^'.in tetrach ior ; de
7 1. i ., 1 - D I c h 1 o r o p r o p •-- n e
78 r-3eriz.?ne
62 1 , 2-0 i c h 1 o roe t ha ru--:
1 3 O T i - i c h 1 o r o e t h e n e
6 3 1,2- D i c h 1 o r o p r o p a n c--?
93 D i b r o m o m e t h a n e
*^i 1 M '^* "i~ ki v./ 1 m o t~ f'i is r** p"* v / 1 j ^* ^**
*~T J. i i c/ L. i i y i. i M c. l i id ^ i y L ci L. w
8 3 8 r o rn o d i c h i o r o rn e t hi a n e
75 ci-:.-l , 3-D Ichloropropene
A-^J 4 Methyl „-- pentanone
92 Toluene
75 t rans-1 . 3-D Lchloroprope
97 1,1,2-Trichloroetha ne
69 Ethyl methacry late
164 Tetrachioroethene
76 1 ,3-Dichloropropane
43 2-Hexanone
129 Dibromochloromethane
107 1,2-Dibromoethane
112 Chlorobenzene
Data Review:
Date:
89
-------
No- MAT FOR REV Delta
Area P. Flags
RT
QM Name
51
52
53
54
55
56
57
58
59
60
ol
c.2
63
64
o 5
6 e>
c,7
63
69
7O
71
7'^
73
74
75
76
77
78
79
0
80
77
71
0
0
0
o
0
0
0
0
0
0
56
0
100
74
39
0
0
Z 5
0
0
0
0
0
0
0
0
54
57
51
L)
0
0
0
0
0
0
0
o
o
43
O
74
3'";
40
0
O
10
O
o
0
0
o
0
0
o
87
83
82
O
O
0
0
o
0
o
0
o
r)
SM'JI
0
98
8iro r° 1 'Jen--?
1 , T- . 5- Tr L me thy iber i :>viie
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-------
1UAN DB : HW9O4
No. MAT FOR REV Delta
LAB-BASE QUAN
Area P.Flaqs RT
09-04-98
QM Name
1
2
3
4
/
73
9
10
11
12
13
L4
35
0
32
62
0
37
O
11
0
19
20
0
25
0
45
0
33
82
0
40
0
0
0
0
1
0
5
7
0
4
0
228O136
2186296
922468
351408
139076
3730528
7716096
bv
A
bv
A
A
bv
A
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5
9
15
15
7
12
05
79
99
17
24
68
36
0
-H-
0
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0 . 0 O
100 97
-1
20964340
•" " •" r i"i ..i ,1
vv
•o-Octane
Ethyl acrylata
C
91
-------
!4-Sep-98 20:21
tawple: S-U-3-3-A
Triangle Laboratories, Inc
T 214-27-12A TLI»46323
(919) 544-5729
c\i
CO
Instrunent H
W904 96 (0.960)
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Sanple: 8-U-3-3-A T
Triangle L*boratorIes,
TL]fM6323
Inc
(919) 544-5729
214-27-120
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100
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6 847872
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58 108 150 ' 208 259 ' 300 350
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100
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78 127
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50 180 158 208 250 ' 300 350
(K
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-------
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CD
89-84-98 20:21 Triable Laboratories, Inc.
Sample: S-V-3-3-A T 214 27 12rt TUJt4b32:3
(919) 544-5729
HU904 263 (2.638)
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58
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100
150
298
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308
358
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188- 43
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58
59
100
156
58
FIND
100
380
350
-------
CO
CD
09-04-98 20:21 Triangle Laboratories, Inc. (919) 544-5729
Sanple: S-U-3-3-A T 214-27- 12A TL 1*46323 Instrument H
HU904 447 (4.470)
100
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13 536576
72
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58 188 159 208 258 388 358
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189
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72
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58 188 158 258 388 350
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180
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72
44 73
•' 57 J/
58 160 158 258 388 358
-------
09-04-98 20'21 Triangle Laboratories, Inc
Sanple: S-U-3-3-A T 214-27-12ft TL
(919) 544-5729
Instn.inent H
HW904 525 (5,251)
7
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8
79
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7
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52 ?4 '
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8
79
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100- 7
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2244608
300 358
2113536
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100
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•*"•-<
09-04-98 20:21 Triangle Laboratories, Inc
Sample: S-U-3-3-R T 214-27-12R TLI#46323
(919) 544-5729
histrunent H
HU9I
100
XFS
0_
H/Z
HU9E
108
XFS
0'
M/Z
826E
180
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M/Z
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. . f , i i i , . .
50
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9
39 51
50
1)
1 1753088
97 7~'~
108 150 260 250 300 356
1) REFINE
1 1474568
106
if?5J>B7
100 158 250 308 356
o-Xylene FIND
J 100
106
92 JlB?
J;
160 150 25Q 388 350
M
-------
!4-Sep-98 2BI21
lanple: S-U-3-3-A T
Triangle Laboratories, Inc
214-27-12A TL1846323
(919) 544-5729
Instrument H
W984 1134 (11.341)
L00
fl-
i
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55
n 6
JI......IIII 1 J.B
• ¥ | • >
50
91
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100 150 200 250 300 350
tt!9B4'1134 (11.341)
.001
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I/Z
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50
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104 149504
10
78
\ 102
,ll , 94
• 1 • • • • 1
100 150 200 250 300 350
1 ASTER 62 (12.248) Stymie FIND
nn _
.00
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01
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A
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50
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103
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78 1
14 100
105
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CM
-------
M-Sep-98 20:21
Janple: S-V-3-3-A
T
Tr iangle Laborator ies, Inc.
214-27-12A TLI»46323
(919) 544-5729
Instrument H
HU9E
100
XFS-
0
M/Z
HU9f
100
0
M/Z
NAS1
100
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5
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86
100 ' 150 ' 200 250 300 350
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7 2064384
86
"''' T1"' ' ' — «~i — i~-r ' ' i • • • • i ' • • • i • • • ' i • • • • i • • • • i • • • • i • • • • i • • • • i • • • • i • • • • i
50 100 150 200 250 300 350
R 2E
5
3
56
50
> (4.24B) rv-Hexane FIND
7 180
86
U-,— , \ t .... f .... t .... t .... t -i i i i | i i i— r ,...,,. j j i , i i T i | i i i r ,....,
100 150 200 250 300 350
-------
•:: . <•-•'<•••' " -" 'j::-4^ ' ' '. •- • "^ ^. • -\ " '.' '•'.:", .....
'.': :: f: ':' ':- Pacific Environmental Services '. .'-..•••. '-..::;•••. A"':-
Project Number: 46323
Sample File: HW899
Client Project R012.001
TU ID: 214-27-12B
Date Received: 07/29/98
Date Analyzed : 09/04/99
Method 8260 VOST
Sample ID: S-V-3-3-B TC
Response Bile ICALH904
: • • ••::.' '•'• : :
Aiwlyte .
Pentafluorobenzene
Chloromethane
Vinvl Chloride
Bromomethane
Chtoroethane
Trichlorofluoromethane
1,1-Diehloroethene
odomethane
Carbon disulfide
Acetone
Allyl chloride
Methylene chloride
Acrylonitrile
tranvl ,2-Dichloroethene
1,1-Dichloroethane
Vinyl acetate
cis-1 ,2-Dichloroethene
2-Butanone
Chloroform
1,1 ,1-Trichloroethane
1 ,4-Difluorobenzene
Carbon tetrachloride
Benzene
1 ,2-Dichloroethane
Trichloroethene
1 ,2-Dichloropropane
. ;. . ^j»o«d*'.-:/IlAG- •;_:'•' Kl ;- .
;': '- ag ;"" :'i';:; "' '":• •'• -"• : •
IS 1 5.04
0.353 B 0.96
U
0.071 B 1.48
U
U
U
U
U
0.075 B 2.65
U
U
U
U
U
U
U
0.050 B 4.49
U
U
IS 2 5.77
U
0.037 BJ 5-24
U
U
U
Det limit <|««n.lamit
ug ttg
0.05
0.001 0.0?
0.05
0.001 . 0.05
0.001 0.05
0.001 0.05
0.001 0.05
0.001 0.05
0.05
0.001 0.05
0.001 0.05
0.005 0.05
0.001 0.05
0.001 0.05
0.001 0.05
0.001 0.05
0.05
0.001 0.05
0.001 0.05
0.001 0.05
0.05
0.001 0.05
0.001 0.05
0.001 0.05
NA- Not Applicable; Det Limit: Detection Limit; Quan. Limit: Quantitation Limit
•IS: Internal Standard; U: Undetected; B: Present In Blank; J: Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
Triangle Laboratories, Inc.
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Sa«arv3.7
Printed: 1659 09/08/1998
10-
-------
1 PadficB.wtemaentalS.rvic.s
Project Number 46323
Sample File: HW899
Client Prof «cbR0:EL001
TLI ID: 214-27-12B : ;
Method 8260 VOST
Sample ID: S-V-3-3-B TC
Date'Received: 07/29/98
Date Analyzed ; 09/04/98
Response File:
ICALH9G4
Aiwlyte
Methyl methacrylate
Bromodichloromethane
cis-1 ,3-Dichloropropene
4-Metfiyl-2-pentanone
Toluene
trans- 1 ,3-Dichloropropene
1 ,1 ,2-Trichloroethane
Chlorobenzene-d.
Tetrachloroethene
2-Hexanone
Dibromochloromethane
1 ,2-Dibromoetrune
Chlorobenzene
Ethylbenzene
m-/p-Xylene
o-Xylene
Styrene
Bromoform
1 ,4-Dichlorobenzene-d
4
Cumene
1 ,1 ,2,2-Tetrachloroethane
^f^ypfc: :-:%'••:;;.
U
U
U
U
0.005 BJ 7.74
U
U
IS 3 9.94
U
U
U
U
U
U
U
U
U
U
IS 4 15.04
U
U
:•. ' •••••' ' •. •'••
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
Quan. Limit
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.10
0.05
0.05
0.05
0.05
0.05
NA- Not Applicable; Det Limit Detection Limit; Quan. Limit Quantitation Limit
d; B: Present In Blank; J: Estimated- Below Quantitation Limit; E- Estimated- Above Calibration Range
T.-iangle Laboratories, Inc.
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Savar v3.7
Printed: 16:29 09/08/1998
0
-------
Project Number 46323
Sample File: HW899
Method 8260 VOST
Sample ID: S-V-3-3-B TC
Client Proj€cfc R012.001
TU ID: " ' '
Surrogate Summary
Dibromofluoromethane
Foluene-d
a
4- Bromofluorobenzene
.. j fiaterift: ?'•••:•',:..,.'
' ' :"^(^::^N ••'••-'"
0.298
0.282
0.318
, m .;..,..;
4.91
7.64
12.22
r ' . .
•"•'•• ' : :• •
1
2
2
:.'•• ,.-%REC
119
113
127
Reviewed by.
Date
NA- Not Applicable; Det Limit Detection Limit; Quan. Limit Quantitation Limit
IS: Internal Standard; U: Undetected; B: Present In Blank; ): Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
Triangle Laboratories, Inc.
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Savar v3.7
Printed: 16:29 09/08/1998
08
-------
Project Number. 46323 Method 8260 VOST
Sample File: HW899 Sample ID: S-V-3-3-B TC
Client Project: R0123&1 Oate Received: 07/29/98
TU ID: 214-27-12B i ' • "•
: .:••"•. "' •-•• ; . •;' Date Analyzed 5 QS/04/98
Analyte
Pentafluorobenzene
1,3-Butadiene
Vinyl bromide
n-Hexane
1 ,2-Epoxybutane
Iso-Octane
1 ,4-Difluorobenzene
Ethyl acrylate
•"",^'r^f. .;:;w •['
IS 1 5.04
U
U
0.003 BJ 3.66
U
U
IS 2 5.77
U
Mute 1
0.001
0.001
0.036
0.001
0.001
Quan- Limit
0.25
0.25
0.25
0.25
0.25
0.25
Reviewed by &flJ& Date °\ I S
NA- Not Applicable; Det Limit: Detection Limit; Quan. Limit: Quantitation Limit
IS: Internal Standard; U: Undetected; B: Present In Blank; J: Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
Triangle Laboratories, Inc. Savar v3.7
801 Capitola Drive • Durham, North Carolina 27713 Printed: 16:54 09/08/1998
Phone: (919) 544-5729 • Fax: (919) 544-5491
, . 1 "> 7
-------
3 x r- as
"-• TI isa «:
3 51
-------
JAN DB
HW399
LAB-BASE QUAN
09--Q4-98
13:31
So. MAT FOR REV Delta
Area P .Flaqs
RT
QM Name
1
'*•
3
4
5
6
7
8
9
10
11
12
13
14
15
lo
17
18
19
T>
21
22
•"> T
24
25
26
27
23
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
" "
45
46
,•1*7
**t /
48
49
50
100
100
100
100
1OO
100
100
0
100
0
100
0
0
0
o
u
100
0
0
0
0
0
0
0
91
0
0
0
0
0
100
0
0
0
0
0
0
_>fr.
71
0
0
0
0
0
0
0
71
96
94
78
68
90
88
0
90
0
83
0
0
0
0
o
74
0
0
~,
0
0
0
0
0
''-' .--
0
0
0
0
0
95
0
0
0
0
o
0
"7
37
0
0
0
0
0
0
0
97
98
95
98
99
97
94
0
100
0
99
0
0
0
0
0
92
0
o
0
0
0
0
0
87
0
0
0
0
0
99
0
o
0
0
0
0
£ C
79
0
0
0
0
0
0
0
-2
0
-1
-1
1
0
0
0
0
0
2
0
0
0
0
0
1
o
0
-
0
0
0
0
0
o
0
0
0
0
o
1
o
0
0
0
— r
0
0
1
0
0
0
0
0
0
0
3509648 bv
3951552 bv
3804949 bv
1782907 bv
1854164 bv
4750834 vv
2557094 vv
0
1267996 vv
0
331 3t>4 bv
0
0
0
0
0
15 So 50 vv
0
Q
— ~ ,M. f^A flap.
0
o
0
0
o
117927 vb
0
0
0
0
0
683080 bv
0
0
0
.•"\
/^y*ft xv. ^
j_o-3- .-.-,-' A (rfi/ fZUZ
0
0 firf .,
_ _ _ ._ NjX? 1 ^^> Iff
56472 A
0
0 Gp PA^
0
0
0
0
0
5.
5.
9.
15.
4.
7 .
12.
0.
0.
0.
1.
0.
0.
0.
0.
0.
2 .
0.
O .
_
0
0.
0.
o .
o ,
4
0.
0,
0
0
0
5
0
0
04
77
94
04
91
64
22
00
96
00
48
00
00
00
00
00
C.' '.C'
00
00
00
oo
oo
'JO
oo
40
oo
00
00
oo
00
24
.00
. 00
0 . 00
0 . 00
0 . 00
0
7
0
0
0
0
0
0
0
.00
.74
.00
.00
.00
,.00
.00
.00
.00
168
114
117
152
113
98
95
85
50
62
94
64
1O.L
9^
142
76
43
41
84
t
96
6,"
43
/ i
9fc
43
83
128
97
1.17
~7 C
t — '
78
62
130
63
93
41
83
75
4~z
s_'
92
75
97
s (~,
6 V
164
76
43
129
107
112
Pentaf 1 uorobenzene
1 ,4-Di f 1 uorobenzene
Chlorobenzene-d5
1 , 4-Oiohlorobenzene-d4
Dibromot 1 uoromethane
Tol uene-d8
4-Bromof 1 uorobenzene
D ichlorodi f 1 uoromethane
Chloromethane
Vinyl Chlon.de
Sromome thane
Ch lo roe thane
T r i c h 1 ore f L uo rorne t ha ne
1 , 1 - Die h i. o r oe t he ne
lodometharie
0 a r b o n d i a u L f i d e
Ace 1:0 ne
A L Ly i ch ior tde
Met h y L e n e c h 1 o r I d e
H c r v i o n \ f.' r !. i to
trans-l, 2--D Lchlor :>echene
.1. . 1 -D i. oi'i ioro'ithane
Vv ny l ace tub*
2 , ~--'0 i c h Lor op r up a ne
cis~ L , 2-D Lchloroetnene
2-6 utu none
Chloroform
8 r omoc h i o rorne t hane
1,1, 1- Fr Lchloroethane
C a r b o n t & t r a c h i o r i d e
1 . l - D I c h 1 o r o p r o D e n e
Benzene
1 , 2-Oichioroethane
T r i c h i o r oe t he ne
1 „ 2-Dichloropropane
D ibrornome thane
Methyl methacrylate
Bromodi ch 1 orome thane
cis-1 „ 3-Dlchioropropene
si \X -t- 1 1 — *1~
<•« netnyi. t pentanone
Tol uene
trans-1 „ 3-D ichlorop roper
1,1, 2-Tr Ichloroethane
Ethyl methacrylate
Tetrachloroethene
1 .,3-Diehioropropane
2-Hexanone
Dibromochloromethane
1., 2-Dibromoethane
Chlorobenzene
Data Review:
Date:
1J3
-------
No. MAT FOR REV Delta
Area P.Flags
RT
QM Name
51
52
53
54
55
56
57
58
59
60
61
62
63
o4
65
66
67
63
69
7O
71
TO
,' „„
73
74
75
76
77
78
79
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
64
42
0
0
0
0
54
53
0
55
47
69
61
0
0
0
0
0
0
0
0
0
o
0
0
0
o
(I
0
36
13
t'.)
0
0
0
34
34
0
34
1O
4C'
41
0
0
0
0
0
0
0
0
0
0
0
0
o
0
0
0
69
51
0
0
0
o
59
50
0
72
80
33
76
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
1
1
0
0
0
0
2
4
0
i
7
7
7
0
0
0
0
0
0
0
U
0
0
0
0
0
0
0
0
40676 A
149-02 A
0
O
O
0
1&7SO A
14412 rt
0
3001o bv
6816 bb
9 20 43 bv
25052 bv
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
14
14
0
0
o
0
16
Lt<
0
10
19
1°
!•-">
.00
.00
.00
.00
.00
.00
.00
.00
.00
. oo
.00
.00
.00
. 00
.00
,. oo
.21
, / ,L
. 00
. 00
. 00
.00
.8.5
,. z^>
.00
. 12
,33
,32
.53
131
106
106
106
1O4
173
105
83
156
75
120
75
126
126
105
11°
105
105
119
146
146
C'L
cj[
146
T C
.' .— '
ISO
225
128
180
1, 1,1,2-Tetrachloroethc
Ethyl benzene \
m~/p-Xylene C ,„ ^
o-Xylene / ' '
Styrene
Bromof orm
Cumene
1, 1 , 2,2-Tetrachloroeth,
Bromobenzene
1,2, 3-TVich loropropane
n-Propy 1 benzene
trans -1 ., 4-Oic h loro-2-b
2-Chlorotol uene
4-Chloroto 1 1 iene
1 , 3 , 5- T r i me t ny 1 be nz? rie
t.e r t -6 1 1 1 v I be n ::e tit:
1,2. 4-Tr [me thy i benzene
•£. e c - 8 u t y 1 b e n ^ e n e
p-Cyrnene
1 „ .3-0 i c h L o fobe n ze ne
1 , 4 - O i c h J. o r o b e n .c e n a
8 e n :: y L c IT 1 o ride
n - 8 u t y 1 b e n z e. n e
1 , 2-0 ichlorobensene
1 „ 2-D ibromo-3~chloropr
1,2, 4 - T r i ' -. h I o rob e n ^ e n a
Hexach lorobutadi^ne
Naphtha Iene
1,2. 3- T r i c h 1 o r obe n ze ru-
10
-------
DB
HW899
LAB-BASE QUAN
09-04-98
No, MAT FOR REV Delta
Area P.Flags
RT
QM Name
1
2
3
4
5
6
7
8
9
10
11
12
13
14
100
100
100
100
100
100
100
6*4—
O
77
cc"1
5^
™
71
96
94
78
68
90
88
-TO
0
53
f. CJ
. T,4
- ~^i
97
98
95
98
99
97
94
"M —
0
70
pi
,i f.
0
1
-2
2
1
-1
-i
0
0
-. 0
.. -3r^ —
3509648
3951552
3804949
1782907
1854164
4750834
2557094
4f
„
r""r'"'O
0
18148
0 -I ..' •- /
bv
bv
bv
bv
bv
vv
VV xr-v
,. OA> <3c
^••' ^5f^ ^
A
w^, (Sf3 A-
v (9^>j jc%
, . ^S? ^
5.
5.
9.
15.
4.
7.
12.
0.
3.
5/"l yl
a^
u? T"
04
77
94
04
91
64
22
00
66
-~.ir .
*~" '"'
168
114
117
152
113
98
95
39
106
/ O
57
42
5 /
^c,
Pentaf 1 uorobenzene
1 , 4-Dif 1 uorobenzene
Chlorobenzene-d5
1, 4-Dlchlorobenzene-d<4
Dibromof 1 uorome thane
Toluene-d8
4-Bromof 1 uorabenzene
1, 3-Butadiene
Vinyl bromide
n 1 Be
n-Hexane
1 ,2-Epoxybutane
I so Od.ane
P t" h \i 1 a i— r~ \t 1 a t- e~.
111
-------
09-04-98 17:12
Sample: S-U-3-3-B
Tr i any 1e LaboratorIes, Inc
T/C 214-27-12B TLJ»4b323
(919) 544-5729
Instrument H
HU899 96 (0.960)
108
XFS-
»/I
5
43
0
52
J
58 180 158 208 ' 258
HU899'96 (0.961) REFINE
188-
XFS
8
826k
XFS
8
5
47
. i.i
8
52
58 ie0 158 ' 208 ' 258
IB 9
5
44
(0.960) Chloronethane
B
52
' --,...., . | - • | • • • 1 ... - | . : , ••, 4 r-. : ,-^ . , = , . .
58 160 150 2S0 258
217988
300 358
177152
388 358
FIND
188
388 358
-------
8££ 00£ 0SE &&Z 0SI 00
1 ... ± 1 ... 1 .. ..!.... 1 . . . 1 . . 1 , . . I . i ,| ... 1
88T I
QMIiI aueif^awowojg
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1 .... 1 ... ! .... 1 ....!.... 1 .... 1 . . ! . . . 1 . . i . . i
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8G£ 08£ 0fiE 8ST 881
i .... i .... l ....!. - I .... i ,..;... f ; j . i
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6
(T8fr'T) 8H,6f
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>8(1H
z/w
SJX
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i8HH
^.uaunJij.su i
3/1 a e-e-n-s r
(616) '311I
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(bib)
-------
10
•H
09-04-98 17:12 Triangle Laboratories, Inc. (919) 544-5729
Sample: S-M-3-3-B T/C 214-27- 12B TLI»46323 Instrument H
HW899 449 (4.490)
188
XFS-
8-
M/Z
I
M
3
56
i ,.!!
58
14080
72
,|1 8if 14? 196
100 158 200 250 388 358
HU899'449 (4.491) REFINE
188-
XFS-
8
M/Z
43
i
57
58
72 3312
73 117 186
188 156 200 250 388 358
826BB 26 (4.511) 2-Butaiione FIND
188
XFS
8-
M/Z
4
3
44
: 57
i . , . .
58
180
72
73
100 158 250 388 358
f
-------
CO
09-04-98 17:12 Triangle Laboratories, Inc
Sanple: S-U-3-3-B T/C 214-27-12B TLI#46323
(919) 544-5729
Instrument H
HU899 524 (5.241)
108
XFS
0
i
77
5/ J*
V. .Jilr.&.3 r:-i|,
8
79
i ..
50 108 150
HU899'524 (5.241) REFINE
100
0-
H/Z
7
3752 74
A . $ r-? , -y
8
79
50 100 150
8260B 32 (5.251) Benzene
100:
X.FS
j£
7
77
52
„«. .JU.3,,,,
3
79
58 100 158
94208
200 258 380 358
88064
268 258 300 350
FIND
108
' i ' J ' r - •" ••)-'•• i t J •• • ' -f ••' - ••• • "-•— i — •—.— '— — i
288 258 388 358
-------
89-84-98 17:12 Triable Laboratories, Inc
Sample: S-U-3-3-B T/C 214-27 12B TLI
(919) 544-5729
Instrument H
HU899 774 (7.741)
188
XFS
5
4154
.!: 1. . . (fit
M/Z 58
£
. ihilll
go 19712
-
91 108
q
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j 81
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108 150 250 388 350
HU899'7?4 (7.741) REFINE
100
XFS
39 _
01 3896
63 89
5b .-•
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H/Z 58
8260B 41
1001
•
X.FS
1
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39
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1 -••' • • — f —
H/Z 58
,
(*-!
f .
65
«i.i
I
92
H2
100 150 250 388 350
761) Toluene FIND
Q1 100
89
•
92
93
180 156 ! 258 ' 388 356
-------
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-------
•L^A^L
CALIBRATION
DATA
Triangle Laboratories, Inc.
801 Capttola Drive P.O. Box 13485
Durham, NC 27713-4411 Research Triangle Park, NC 27709-348Z
919-544-5729 Fax 9 919-544-5491
119
-------
Triangle Laboratories, Inc.
Initial Calibration Curve
ICAL File: ICALH904 Date of Analysis
RF0.10 HW887 RF0.25 HW888
RF0.75 HW890 RF1.00 HW891
:09/04/98 Analyte List: 8260
RF0.50 HW889
VOST Calibration.
Analyte ; •• . ,"•: . Flag
Pentafluorobenzene I
Chloromethane P
Vinyl Chloride C
Bromomethane
Chloroethane
Tnchlorofluoromethane
1,1-Dichloroethene C
lodomethane
Carbon disulfide
Acetone
Allyl chloride
Methylene chloride
Acrylonitrile
trans- 1 ,2- Dichloroethene
1,1-Dichloroethane P
Vinyl acetate
cis-l,2-Dichloroethene
2-Butanone
Chloroform C
1,1,1 -Trichloroethane
1,4-Difluorobenzene I
Carbon tetrachloride
Benzene
1 ,2 -Dichloroethane
Trichloroethene
1,2-Dichloropropane C
Methyl methacrylate
Bromodichloromethane
cis- 1 ,3-Dichloropropene
4-Methyl-2-pentanone
Toluene C
trans-1 ,3-Dichloropropene
1 ,1 ,2-Trichloroethane
Chlorobenzene-d5 I
Tetrachloroethene
2-Hexanone 1
Dibromochloromethane
1,2-Dibromoethane
KBX1Q RB&25 KBQ.S8 RF0.75 RFl^MEaB'. ' %jR$E»;;.:rq.- / .:."••;.;. .-.::;.:] '
0.236
0.303
0.305
0.199
0.599
0.301
0.633
0.903
0.043
0.338
0.302
0.029
0.324
0.651
0.090
0.339
0.050
0.714
0.630
0.688
1.281
0.357
0.469
0.406
0.082
0.575
0.507
0.115
0.738
0.337
0.255
0.418
0.060
0.407
0.318
0.271
0.367
0.354
0.213
0.643
0.324
0.633
0.921
0.186
0.349
0.312
0.028
0.350
0.675
0.214
0.360
0.234
0.767
0.702
0.601
1.138
0.368
0.414
0.419
0.082
0.573
0.561
0.155
0.770
0.404
0.248
0.411
0.198
0.385
0.298
0.220
0.338
0.312
0.207
0.644
0.330
0.674
0.957
0.177
0.377
0.322
0.031
0.363
0.691
0.231
0.378
0.201
0.817
0.683
0.554
1.235
0.363
0.422
0.413
0.090
0.589
0.579
0.149
0.770
0.428
0.255
0.427
0.180
0.414
0312
0.267
0.360
0.334
0.216
0.642
0.247
0.500
0.754
0.136
0.296
0.231
0.029
0.307
0.657
0.249
0.386
0.220
0.763
0.650
0.521
1.083
0.356
0.423
0.405
0.092
0.585
0.587
0.152
0.756
0.442
0.264
0.427
0.190
0.419
0.314
0.287
0.380
0.353
0.241
0.761
0.382
0.742
0.966
0.199
0.401
0.381
0.037
0.406
0.586
0.183
0.387
0.136
0.760
0.647
0.532
1.051
0.331
0.427
0.402
0.093
0.573
0.579
0.146
0.730
0.432
0.257
0.430
0.174
0.418
0.313
0.256
0.350
0.332
0.215
0.658
0.317
0.636
0.900
0.148
0.352
0.310
0.031
0.350
0.652
0.193
0.370
0.168
0.764
0.662
0.579
1.158
0.355
0.431
0.409
0.088
0.579
0.563
0.143
0.753
0.409
0.256
0.423
0.160
0.408
0.311
10.6
8.6
6.9
7.4
9.3
15.4
13.9
9.5
42.9
11.3
17.3
11.2
10.9
6.1
32.5
5.6
45.0
4.8
4.4
11.8
8.5
4.1
5.0
1.8
6.1
1.3
5.7
11.3
2.5
10.4
2.3
1.9
35.5
3.4
2.5
•-Fails QC Criteria for %RSD; « - RF less than minimum QC RF; » - RF greater than maximum QC RF
Triangle Laboratories, Inc.
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax- (919) 544-5491
Savarv3.7
120
-------
Triangle Laboratories, Inc.
Initial Calibration Curve
ICAL File: ICALH904
RF0.10 HW887
RF0.75 HW890
Date of Analysis :09/04/98
RF0.25 HW888
RF1.00 HW891
Analyte List: 8260
RF0.50 HW889
VOST Calibration.
Analyte •
Chlorobenzene
Ethylbenzene
m-/p-Xylene
o-Xylene
Styrene
Bromoform
l,4-Dichlorobenzene-d4
Cumene
1 ,1 ,2,2-Tetrach loroethane
Average %RSD
Surrogate
Dibromofluoromethane
Toluene-d8
4-Bromofluorobenzene
Flag
P
C
P
I
P
Flag
S
S
S
RF0.10
0.923
0.467
0.589
0.547
0.868
0.174
3.940
0.463
RF040
0.423
1.024
0.498
RFQ.2S R3KX50 RF6.75 SFUJft MEAN
0.954
0.496
0.608
0.569
0.929
0.203
3.920
0.618
RF0.25
0.489
1.072
0.524
0.987
0.502
0.613
0.569
0.946
0.233
4.136
0.674
Rmso
0.436
1.078
0.516
0.956
0.467
0.574
0.530
0.894
0.244
2.927
0.559
RF&75
0.438
1.087
0.502
0.954
0.468
0.567
0.543
0.907
0.251
2.740
0.504
RF1.0U
0.427
1.062
0.500
0.955
0.480
0.590
0.552
0.909
0.221
3.532
0.564
Mean
0.443
1.065
0.508
':%RSD.:',;; v " ' ../.:<"• ^ "•:
2.4
3.7
3.4
3.1
3.3
14.6
18.3
15.1
10.5
%RSD
6.0
2.3
2.3
Approved by:.
Date
-------
Triangle Laboratories, Inc.
Continuing Calibration Curve
CCAL File: HW894
ICAL File: ICALH904
Date of Analysis
:09/04/98
Analyte List: 8260
VOST Calibration.
Analyte • • • =• • >:C.,-,j^g.-- .:;-******^* ** .. , ;; ••.••'* •"••^.<: ••''••-.•/ •'••'' '•" •'•?•••"••.••••'•:''••'•[ •"•'•"" :\:;-:;-'--:-::':v- ;: • :'i*v . ;':-;
Pentafluorobenzene
Chloromethane
Vinyl Chloride
Bromomethane
Chloroethane
Tnchlorofluoromethane
1,1-Dichloroethene
lodo methane
Carbon disulfide
Acetone
Allyl chloride
Methylene chloride
Acrylonitrile
trans-l,2-Dichloroethene
1 ,1 -Dichloroethane
Vinyl acetate
cis-l,2-Dichloroethene
2-Butanone
Chloroform
1,1,1 -Trichloroethane
1 ,4-Difluorobenzene
Carbon tetrachloride
Benzene
1,2-Dichloroethane
Trichloroethene
1,2-Dichloropropane
Methyl methacrylate
Bromodichloromethane
cis-13-Dichloropropene
4-Methyl-2-pentanone
Toluene
trans-13-Dichloropropene
1 ,1 ,2-Trichloroethane
Chlorobenzene-d5
Tetrachloroethene
2-Hexanone
Dibromochloromethane
1,2-Dibromoethane
I
P 0.195
C 0.272
0.217
0.133
0.398
C 0.238
0.528
0.761
0.103
0.355
0.309
0.032
0.351
P 0.659
0.190
0.366
0.160
C 0.764
0.731
I
0.592
1.599
0.366
0.487
C 0.415
0.097
0.580
0.563
0.172
C 0.771
0.417
0.261
I
0.432
1 0.197
0.416
0.321
0.256
0.350
0.332
0.215
0.658
0.317
0.636
0.900
0.148
0.352
0.310
0.031
0.350
0.652
0.193
0.370
0.168
0.764
0.662
0.579
1.158
0.355
0.431
0.409
0.088
0.579
0.563
0.143
0.753
0.409
0.256
0.423
0.160
0.408
0.311
23.8
22.3
34.6
38.1
39.5
24.9
17.0
15.4
30.4
-0.9
0.3
-3.2
-0.3
-1.1
1.6
1.1
4.8
0.0
-10.4
-2.2
-38.1
-3.1
-13.0
-1.5
-10.2
-0.2
0.0
-20.3
-2.4
-2.0
-2.0
-2.1
-23.1
-2.0
-3.2
*- Fails QC Criteria for %D;« - Rf less than minimum QC RF;»- RF greater than maximum QC RF
Triangle Laboratories, Inc.
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Savar v3.7
-------
Triangle Laboratories, Inc.
Continuing Calibration Curve
CCAL File: HW894
ICAL File: ICALH904
Date of Analysis :09/04/98 Analyte List: 8260
VOST Calibration.
Analyte k :
Chlorobenzene
Ethylbenzene
m-/p-Xylene
o-Xvlene
Stvrene
Bromoform
1 ,4-Dichlorobenzene-d4
Cumene
1 ,1 ,2,2-Tetrachloroethane
Bag
P
C
P
I
P
KKJJS R
0.967
0.496
0.611
0.588
0.976
0.242
3.901
0.491
EMBAM.A;
0.955
0.480
0.590
0.552
0.909
0.221
3.532
0.564
;-.%^>;:;;,;.,^.--.V, ^--,-0::- -j^
-1.3
-3.3
-3.6
-6.5
-7.4
-9.5
-10.4
12.9
Surrogate
Mag RKL25 RFMEAN
Dibromofluoromethane S 0.492 0.443 -11.1
Toluene-d8 S 1.060 1.065 0.5
4-Bromofluorobenzene S 0.562 0.508 -10.6
Approved by:.
Date q / ^ 7^rT
*- Fails QC Criteria for %D;« - Rf leas than minimum QC RF; »- RF greater than maximum QC RF
Triangle Laboratories, Inc. Savar v3.7
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491 -J ) ,
-------
Triangle Laboratories, Inc.
Initial Calibration Curve
ICAL File: ICALH904 Date of Analysis :09/04/98 Analyte List: short
RF0.50 HW893
VOST Calibration.
Analyre ..; •...•••.••.-flag,.-••.JEUHLSO^MEAN %RS£>
Pentafluorobenzene I
U-Butadiene 0.455 0.455 0.0
Vinyl bromide 0.375 0.375 0.0
n-Hexane 0.459 0.459 0.0
U-Epoxybutane 0.004 0.004 0.0 «
Iso-Octane 1.767 1.767 0.0
1,4-Difluorobenzene I
Ethyl acrylate 0.194 0.194 0.0
Average %RSD 0.0
Approved by. Date
*• Fails QC Criteria for %RSD;« - RF less than minimum QC RF;» - RF greater than maximum QC RF
Triangle Laboratories, Inc. Savar v3.7
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax (919) 544-5491 . ^ .
-------
APPENDIX G.5
EPA METHOD 18 REPORT AND DATA
-------
Pacific Environmental Services, Inc.
5001 South Miami Blvd, Suite 300
Research Triangle Park, NC 27709
Analytical Report
(0798-19)
EPA Method 18 (Tubes)
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
SW-846 Method 8260
GC/MS Scan
Enthalpy Analytical, Inc.
3211 Bramer Drive
Raleigh, NC 27604
919/850-4392
-------
Sample Custody
'
ENTHALPYanalytical. inc
-------
PACIFIC ENVIRONMENTAL SERVICES, INC.
Central Park West
5001 South Miami Boulevard, P.O. Box 12077
Research Triangle Park, North Carolina 27709-2077
(919) 941-0333 FAX: (919) 941-0234
Sample Chain of Custody Record
PLANT: US EPA HOT MIX ASPHALT PLANT C
RECOVERY PERSON: B. Purser
PROJECT NO.: R012.001
SAMPLERS: B. Purser, T Abernathy
Sample
Identification
T-M18-1-Aa
T-M18-1-Ab
T-M18-1-Ba
T-M18-1-Bb
T-M18-2-Aa
T-M18-2-Ab
T-M18-2-Ba
T-M18-2-Bb
T-M18-FB-Aa
T-M18-FB-Ab
T-M18-FB-Ba
T-M18-FB-Bb
T-M18-3-Aa
T-M18-3.-Ab
T-M18-3-Ba
T-M18-3-Bb
T-M18-4-Aa
T-M18-4-Ab
T-M18-4-Ba
T-M18-4-Bb
S-M18-1-Aa
S-M18-1-Ab
S-M18-1-AKO
S-M18-1-Ba
S-M18-1-Bb
S-M18-1-BKO
S-M18-2-Aa
S-M18-2-Ab
S-M18-2-AKO
S-Mt8-2-Ba
S-Mt8-2-Bb
S-M18-2-BKO
S-M18-3-Aa
Collection
Date
7/24/98
7/24/98
7/24/98
7/24/98
7/25/98
7/25/98
7/25/98
» 7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/27/98
7/27/98
7/27/98
7/27/98
7/26/98
7/26/98
7/26/98
7/26/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/24/98
Time
Sample
Name
Leg A Tube a
Leg A Tube b
Leg B Tube a
Leg B Tube b
Leg A Tube a
Leg A Tube b
Leg B Tube a
Leg B Tube b
Leg A Tube a
Leg A Tube b
Leg B Tube a
Leg B Tube b
Leg A Tube a
Leg A Tube b
Leg B Tube a
Leg B Tube b
Leg A Tube a
Leg A Tube b
Leg B Tube a
Leg B Tube b
Leg A Tube a
Leg A Tube b
Leg A Knock-out Imp
Leg B Tube a
Leg B Tube b
Leg B Knock-out Imp
Leg A Tube a
Leg A Tube b
Leg A Knock-out Imp
Leg B Tube a
Leg B Tube b
Leg B Knock-out Imp
Leg A Tube a
Number of
Containers
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
Analytical Req
uest
_
Comments
Spike Tube
Spike Tube
Field Blank
Field Blank - Spike Tube
Field Blank
Field Blank
Spike Tube
Spike Tube
Spike Tube
Spike Tube
Page 1 of 2
-------
O PACIFIC ENVIRONMENTAL SERVICES, INC.
Central Park West
5001 South Miami Boulevard, P.O. Box 12077
Research Triangle Park, North Carolina 27709-2077
(919) 941-0333 FAX: (919) 941-0234
Sample Chain of Custody Record
PLANT: US EPA HOT MIX ASPHALT PLANT C
RECOVERY PERSON: B. Purser
PROJECT
SAMPLEF
NO.: R012.001
ES: B. Purser, T Abernathy
Sample
Identification
S-M18-3-Ab
S-M18-3-AKO
S-M18-3-Ba
S-M18-3-Bb
S-M18-3-BKO
S-M18-4-Aa
S-M18-4-Ab
S-M18-4-AKO
S-M18-4-Ba
S-M18-4-Bb
S-M18-4-BKO
- C-\
Relinqi^iptr'bY /
RelinqulsRed by:
— — ~"
Collection
Date
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
Time
«
a
Sample
Name
Leg A Tube b
Leg A Knock-out Imp
Leg B Tube a
Leg B Tube b
Leg B Knock-out Imp
Leg A Tube a
Leg A Tube b
Leg A Knock-out Imp
Leg B Tube a
Leg B Tube b
Leg B Knock out Imp
Number of
Containers
1
1
1
1
1
1
1
1
1
1
1
^i SJfl««JQ. )/4fer
„-
Analytical Req
Date. Time
Date Time
uest
Comments
Spike Tube
Spike Tube
Received by:
Received for Lab by. ^ • t i
r~) JUs— ^^^
Page 2 of 2
-------
Narrative Summary
ENTHALPYanalytical
, inc.
-------
Enthalpy Analytical Narrative Summary
Company:
Client #:
PO#
PES
R012.001
104980229
Enthalpy*:
Analyst:
* Parameters
0798-19
BGP
Organics
Custody Brian Purser of Enthalpy Analytical, Inc. received the samples on 07/29/98 after
being relinquished by Pacific Environmental Services, Inc. No apparent container
problems were noted upon receipt. Prior to and during analysis, the sample was kept
under lock with access only to authorized personnel of Enthalpy Analytical, Inc.
Analysis The samples were analyzed for organics using the analytical procedures in EPA
Method 18 (40 CFR, Part 60, Appendix A). All charcoal tubes were desorbed using
5.0 mL of a 2% DMF in carbon disulfide solution.
The analyzer was a Hewlett-Packard 5890 Series II Gas Chromatograph equipped
with a flame ionization detector using hydrogen as the carrier gas.
Separation The samples were separated using a J&W DB-5 30m x 0.53mm ID capillary column.
All calibration curve(s) and quality assurance point(s) are located in the "Curves"
section of the report and referenced hi the "Cal. Curve" section on the Results page.
The following table shows approximate retention tunes for each analyte.
Analyte Retention Time
Hexane 1.46
Benzene 5.40
Toluene 7.40
Ethylbenzene 9.19
p-Xylene 9.34
m-Xylene 9.49
Cumene 9.99
o-Xylene 10.40
Chromatographic
Conditions
Reporting Notes
Initial temperature:
Ramp:
Net Run Time
Pressure Constant:
Injector temperature:
Detector temperature:
45°C, hold for 2.00 minutes
7.5°C per minute to 125°C
12.67 minutes
2.1psiat45°C
195°C
225°C
The symbols MDL and LOQ represent the Minimum Detection Limit and the Limit
of Quantification. The values that are between the MDL and the LOQ are indicated
by a tilde (~).
Hub^.d
0798-19tubw.doc
ENTHALPYanalytical.
inc.
-------
Narrative Summary (Cont.)
Tunnel To demonstrate the train collection efficiency, spike and recoveries were operated
Spike & Recovery simultaneously for four test runs at the Tunnel test location. The adsorbents from the
two trains were analyzed using the same analytical procedure and instrumentation.
The fraction of spiked compound recovered (R ) is determined using the following
equations.
where Mv = mass per volume of spiked compound measured (ng/L).
Ms = total mass of compound measured on adsorbent with spiked train (jig).
Vs = volume of stack gas sampled with spiked train (L).
Mu = total mass of compound measured on adsorbent with unspiked train (ng).
Vu = volume of stack gas sampled with unspiked train (L).
where S = theoretical mass of compound spiked onto adsorbent in spiked train (jig).
Mv = Ms-Mu R = Mv*Vs
Vs ' Vu S
Reported Results = Measured Concentration (ppm)
R
Example The following is the spike and recovery example calculation for this test program.
Calculation Foj. ^ T_M1 g_j (^p^ _12 g ug> Hexane
For run T-M18-1 (spiked) 263 ug, Hexane
Mv- 263 - 12.8 R= 1.0726 * 233.2
233.2 231.9 204
Mv=1.0726ug/L R=122%
The unspiked sample trains were corrected for the collection efficiency determined
for each analyte.
6
0798-19tubes.doc
ENTHALPYanalytical, inc.
an*
-------
Enthalpy Analytical Narrative Summary
Company:
Cfleata
>•' . ••' *O#
PES
R012.001
104980229
0798-19
TAB
SW-846 8260
Custody
Analysis
Separation
Chromatographic
Conditions
Reporting Notes
Example Calculation
Brian Purser of Enthalpy Analytical, Inc. received the samples on 07/29/98 after
being relinquished by Pacific Environmental Services, Inc. No apparent container
problems were noted upon receipt. Prior to and during analysis, the sample was kept
under lock with access only to authorized personnel of Enthalpy Analytical, Inc.
The Silo charcoal tube samples were extracted and analyzed in the same fashion as
the tunnel samples. However, the large number of peaks made quantitation
impossible. There were literally hundreds of peaks. The flame ionization detector
was unable to differentiate the target peaks from the crowd. The chromatograms
from the FID analysis are included at the back of this report. Realize that there is a
significant possibility that the concentration presented on those chromatograms
includes extraneous peaks that have co-eluted with the target peaks.
At PES's request, the Silo charcoal tube extracts were qualitatively characterized
using the analytical procedures in SW-846 Method 8260. The Silo charcoal tubes
were desorbed using 5.0 mL of a 2% DMF in carbon disulfide solution.
The scope of the task was to identify as many compounds as possible and give the
best tentative identification (TICs) using the NBS 44,000 compound library. The
TICs were semi-quantitated using the internal standard 4 bromofluorobenzene and a
response factor of 1.00. Some compounds may appear more than once on the
summary sheets which indicates the presence of isomers. The thirty peaks with the
highest peak height are reported for each sample.
*The compound NN dimethyl formamide appears in all samples. This was added to
the samples to facilitate efficient desorption from the charcoal media.
1 uL of the sample was injected with 1 uL of an internal standard mixture. The
sample was injected directly into the gas chromatograph.
The analysis was performed using a HP 5890 Gas Chromatograph (GC) and a HP
5970 Mass Spectrometer (MS) detector.
The samples were separated using a Supelco DB-1 60m x 0.32mm capillary column.
Initial Temperature: 40°C, hold for 5.00 minutes
Initial Ramp: 8°C per minute to 210°C
Injector Temperature: 190°C
Separator Oven Temp: 300°C
MS Scan Range: 35- 350 AMU
The estimated concentration of the reported compounds has an estimated error of
+100% to-50%.
The concentrations calculated for all compounds were based on internal standard
4- bromofluorobenzene.
Where:
(Area of compound) x (Volume of Extract) x (Amt of Int. Std.)
ug/mL= —
(Area of Int. Std.)
U
0798-19ms.doc
ENTHALPYanalytical.
inc.
-------
Tunnel Results
ENTHALPY analytical, inc.
-------
Company:
Analyst:
Parameters:
# Samples:
PES
BGP
Organics
20 CT tubes
Client*:
Enthalpy*:
PO#:
Report Date:
R012.001
0798-19
104980229
09/23/98
Compound
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Sample ID/Catch weight (ug)
T-M18-1A
- 9.80
<4.39
- 15.2
32.9
~ 21.3
- 7.13
- 16.1
- 7.98
T-M18-2A
- 18.4
~ 5.13
~ 25.7
41.1
- 13.4
- 6.87
- 11.3
- 5.66
T-M18-3A
< 3.82
<4.39
~ 10.1
- 12.3
<4.35
<4.35
< 3.91
<4.76
T-M18-4A
< 3.82
< 4.39
-9.05
- 15.4
< 4.35
< 4.35
< 3.91
< 4.76
T-M18-FB-A
~ 11.3
<4.39
- 24.5
39.0
- 9.83
- 4.39
24.5
- 16.0
Reviewed by:
QA:
Steven J. Bpkard
Date:
Analyst: _
Brian G. Purser
Date:
ENTHALPYanalytical,
:e: 1
J:VOBS98V07\0798-19\0798-19A.WB2 10:09 AM 09/23
-------
MDL: 1 00 ppm
LOQ: 5.00 ppm
Curve range (7.34 - 388 ppm)
Compiaiyi
Amlysl:
Piraneim:
* Samples:
PES
BGP
Hexane
20 CT tubes
Cttwt*
Erfbalp,*:
K>*i
Report Dit«:
R012.001
0798-19
104980229
09/23/98
Identification
M. *1 4 lid. #2
Retention fbne(min.) ,
Ini. #1 I Inj.*2
Difference
Concentration
InJ. #1 | bd. #2
% Difference
of Mean
Average
Cone.
Cat.
Curve
Volume
(ml/)
Ratio
(aid
- HtM.
Catch Weight
T-M18-1A FH
T-M18-1A BH
009F0901 D
010F1001 D
009F0902.D
010F1001 D
1.462
NA
1.464
NA
0.14
, NA
- 1.76
< 1.00
- 3.37
< 1.00
> 5 %
0.00
- 2.57
< 1.00
0798-19.M
0798-1 9. M
5
5
1
1
- 12.8
< 5.00
- 12.8
% Rec 131
- 9.80 I
T-M18-2A FH
T-M18-2A BH
011F1101 D
012F1201.D
011F1102.D
012F1202D
1.461
1.477
1.477
1.476
1.10
0.07
- 4.69
< 0.72
' 4.96
< 0.70
2.79
1.68
- 4.82
< 0.71
0798-19.M
0798-19.M
5
5 •
1
t
- 24.1
< 5.00
- 24.1
% Rec 131
- 18.4 |
T-M18-3A FH
T-M18-3A BH
013F1301.D
014F1401.D
013F1302.D
014F1402.D
1.470
NA
1.476
NA
0.41
NA
< 1.00
< 1.00
< 1.00
< 1.00
0.00
0.00
< 1.00
< 1.00
0798-19.M
0798-19.M
5
5
I
1
T-M18-4A FH
T-M18-4A BH
01 SF1 501.0
016F1601.D
T-M18-FB-A FH
T-M18-FB-A BH
025F2701.D
026F2801 D
015F1502.D
016F1602 D
025F2702.D
026F2602 0
1.473
1.472
1.471
NA
1.476
1.474
1.469
NA
0.20
0.14
< 1.00
< 1.00
< 1.00
< 1.00
0.00
0.00
0.14
NA
- 2.55
< 1.00
- 3.37
< 1.00
> 5 %
0.00
< 1.00
< 1.00
0798-19.M
0798-19.M
- 2.96
< 1.00
0798-19.M
0798-19.M
5
5
5
5
1
1
1
1
< 5.00
< 5.00
< 5.00
< 5.00
< 5.00
< 5.00
' 14.8
< 5.00
- 14.8
% Rec 131
< 3.82 I
% Rec 131
< 3.82 I
% Rec 131
- 11.3 I
T-M18-1B FH
T-M18-1B BH
017F1701 D
018F1801.D
017F1702.D
018F1802.D
1.470
NA
1.469
NA
0.07
NA
52.6
< 1.00
52.5
< 1.00
0.11
0.00
52.5
< 1.00
0798-19.M
0798-1 9. M
5
5
1
1
T-M18-2B FH
T-M18-2B BH
019F2101.D
020F2201.D
019F2102D
020F2202.D
1.429
1.458
1.442
1.467
0.91
0.62
67.0
- 1.02
59.9
< 1.00
> 5 %
0.84
63.4
- 1.01
0798-19.M
0798-19.M
5
5
1
1
263
< 5.00
263
317
- 5
322
263 I
322 1
T-M18-3B FH
T-M18-3B BH
021F5501.D
022F2401.D
021F5502.D
022F2402.D
1.455
NA
1.460
NA
0.34
NA
51.7
< 1.00
50.6
< 1.00
1.06
0.00
51.2
< 1.00
0798-19D.
0798-I9.M
5
5
1
1
T-M18-4B FH
T-M18-4B BH
T-M18-FB-B FH
T-M18-FB-B BH
023F5601.D
024F2601.O
023FS602.0
024F2802D
1.463
NA
1.467
NA
0.27
NA
53.6
< 1.00
53.2
< 1.00
0.39
0.00
53.4
< 1.00
0798-I9D.
0798-19.M
5
5
1
1
027F1101.D
028F3001.D
027F1102D
028F3002 D
1.466
NA
1.466
NA
0.00
NA
37.9
< 1.00
37.7
< 1.00
0.28
0.00
37.8
< 1.00
0798-19D.
0798-19.M
5
5
1
1
256
< 5.00
256
267
< 5.00
267
189
< 5.00
189
256 1
267 |
189 I
ENTHALPYanalytical. inc.
imrm-iw WBJ 9 a AM mm
-------
MDL: 1.00 ppm
LOQ: 5.00 ppm
Curve range (7.85 - 416 ppm)
--v:-.',--iMk *"
:". a*** ., •--•
^sz
*^£r
PES
BOP
Benzene
20 CT tubes
EnUulpyl:
roii
Report Ihrtei
R012.001
0798-19
104980229
09/23/98
Retention Time (into.)
N/
5
.420
NA
NA
5.429
NA
NA
NA
NA
iA
NA
-------
MDL: 1.00 ppm
LOQ: 5.00 ppm
Curve range (7.77 - 41 1 ppm)
&Stt0le ' .." --T-rJi ••„ " . t*bID -
tdo.aflc.tlon '.-.-< r.ik,* I 1 M.fi
Rete«lonTtaK(mln.)
liA.fl 1 Inj.*2
Analjit:
fSampto:
res
BGP
Toluene
20 CT tubes
'. ClM«i
rot:
Report ftrt«
ROI2.001
0798-19
104980229
09/23/98
Difference
. Coocenira«on
M. »l I Inj.*2
or Mean
Average Ca
Cone. Cm
1, Vohune
rve (mL)
Rafio 5 %
0.00
- 2.47
- 1.10
0798-19.M
0798-19.M
5
5
1
1
T-M18-2A FH
T-M18-2A BH
011F1101.D
012F1201.D
011F1102.D
012F1202.D
7.413
7.418
7.416
7.413
0.04
0.07
- 4.62
' 1.36
- 4.74
' 1.31
1.23
1.81
- 468
- 1.34
0798-19.M
0798-1 9. M
5
5
1
1
T-M18-3A FH
T-M18-3A BH
013F1301.D
014F1401.D
T-M18-4A FH
T-M18-4A BH
015F1501.D
016F1601 0
013F1302.D
014F1402.D
7.411
7.408
7.410
7.406
0.01
0.03
- 1.26
- 1.08
- 1.32
- 1.04
2.41
2.34
- 1.29
- 1.06
0798-19.M
0798-19.M
5
5
1
I
01SF1502.D
016F1602 D
T-M18-FB-A FH
T-M18-FB-A BH
025F2701 D
026F2801 D
02SF2702.D
026F2802.0
7.407
7.402
7.404
7.403
0.04
0.01
- 1.02
- 1.10
- i.oo
' 1.11
0.94
0.61
7.404
7.403
7403
7404
0.01
0.01
- 4.35
' 1.31
' 4.51
' 1.30
1.79
0.46
- 1.01
- 1.1!
0798-19.M
0798-19.M
5
5
1
1
- 4.43
' 1.30
0798-19.M
0798-19.M
5
5
1
1
- 12.3
- 5.51
- 17.8
- 23.4
- 6.69
- 30.1
- 6.46
- 5.30
- 11.8
- 5.05
- 5.54
- 10.6
- 22.1
- 6.52
- 28.7
% Rec 1 17
- 15.2 I
%Rec 117
-25.7 |
% Rec 1 17
- 10.1 I
% Rec 117
- 9.05 I
%Rec 117
- 24.5 |
T-M18-1B FH
T-M18-1B BH
017F1701.D
018F1801 D
017F1702 D
018F1802 D
7.399
7.400
7.400
7.400
0.01
0.00
45.9
- 1.03
46.1
- 1.01
0.22
1.02
46.0
- 1.02
0798-19.M
0798-19.M
5
5
1
1
T-M18-2B FH
T-M18-2B BH
019F2101 D
020F2201.D
019F2102D
020F2202.D
7.298
7.377
7.347
7.393
0.67
0.22
61.7
- 2.30
57.1
- 2.22
3.82
1.64
59.4
- 2.26
0798-1 9. M
0798-19.M
5
5
1
1
T-M18-3B FH
T-M18-3B BH
021F5501.D
022F2401.D
021F5502.D
022F2402 D
7.361
7.406
7.378
7.406
0.23
0.00
52.7
- 1.13
51.5
- 1.13
1.15
0.22
52.1
- 1.13
0798-19D.
0798- 19.M
5
5
1
1
T-M18-4B FH
T-M18-4B BH
023F5601.D
024F2601.D
023F5602.D
024F2602 D
7.385
7.403
7.391
7.407
0.08
0.05
53.2
- 1.06
52.5
- 1.04
0.65
0.84
52.9
- 1.05
0798-19D.
0798-19.M
5
5
1
1
T-M18-FB-B FH
T-M18-FB-B BH
027F1101.D
028F3001.D
027F1102.D
028F3002.D
7.390
NA
7.390
NA
0.00
NA
33.2
< 1.00
32.9
< 1.00
0.54
0.00
33.1
< 1.00
0798-19D.
0798-19.M
5
5
1
1
230
- 5.12
235
297
- 11.3
308
260
- 5.64
266
264
- 5.26
270
165
< 5.00
165
235 1
308 1
266 I
270 I
165 I
ENTHALPYanalytical,
inc.
j yoBS«u9A WBZ s
-------
SO
-t
MDL: 1. 00 ppm
LOQ: 5.00 ppm
Curve range (7.73 - 409 ppm)
Sample , 1 UbID
Identtflcatloa I InJ.#l I Inj. *2
Retortion TJmednln.)
tol.fl 1 W.#2
Coi»p«j(
Aailyrt:
/Smpteii;
PES
BGP
Ethylbenzene
20 CT tubes
CBMt*
EMU*?*
roii
. Report DiU:
R012.001
0798-19
104980229
09/23/98
Percent >
DlfiCfQICC
Concentration
lai.il 1 Ini.fZ
% Difference
.. of. Mean
Average
Cone.
Cal.
Curve.
Volume
taL)
mutton C*teu Weight Total 1
Ratio (OR) Catch Weight; I
T-M16-1A FH
T-M18-1A BH
T-M18-2A FH
T-M18-2A BH
009F0801D
010F1001.D
011F1101 D
012F1201.D
009F0902.D
010F1001.D
9.177
9.200
011F1102.D
012F1202.D
9.203
9.205
9.193
9.200
0.17
0.00
5.41
- 2.76
9.205
9.201
T-M18-3A FH
T-M18-3A BH
T-M18-4A FH
T-M18-4A BH
T-M18-FB-A FH
T-M18-FB-A BH
013F1301.D
014F1401.D
015F1501.D
016F1801.D
013F1302.D
014F1402D
015F1502D
016F1602.D
025F2701.0
026F2801 O
025F2702 D
026F2B02 D
9.199
9.198
9.194
9.189
9.191
9.192
9.199
9.194
9.192
9.191
9.191
9.190
0.02
0.04
0.00
0.04
0.02
0.02
000
0.02
8.46
" 2.13
5.52
- 2.76
0.95
0.00
5.47
- 2.76
7.83
' 2.10
- 1.64
- 1.42
- 1.95
- 1.88
' 1.69
- 1.41
- 2.00
' 1.88
8.17
- 1.52
8.26
- 1.54
3.91
0.75
1.50
0.27
1.25
0.13
0.56
0.75
8.15
- 2.12
- 1.67
' 1.42
- 1.98
- 1.88
8.22
- 1.53
0798-19.M
0798-19.M
0798-19.M
0798-19.M
0798-I9.M
0798-19.M
0798-19.M
0798- 19.M
0798-19.M
0798-19.M
5
5
5
5
5
5
5
5
5
5
1
1
1
1
1
1
1
1
1
1
27.3
- 13.8
41.2
40.7
- 10.6
51.3
- 8.33
- 7.08
- 15.4
- 9.90
- 9.40
- 19.3
41.1
- 7.65
48.7
%Rec 125
32.9 |
%Rec 125
41.1 |
%Rec 125
- 12.3 I
%Rec 125
- 15.4 |
%Rec 125
39.0 I
T-M18-1B FH
T-M18-1B BH
01 7F1 701.0
018F1801 D
017F1702.D
018F1802 D
9.187
9.188
9.188
9.186
0.01
0.02
52.8
- 2.44
53.2
- 2.43
0.38
0.15
53.0
- 2.43
0798-I9.M
0798-19.M
5
5
1
1
265
- 12.2
277
277 |
T-M18-2B FH
T-M18-2B BH
019F2101 D
020F2201.D
019F2102.0
020F2202.D
9.088
9.167
9.136
9.181
• 0.53
0.15
68.9
- 3.08
61.0
- 2.98
> 5 %
1.69
65.0
' 3.03
0798-19.M
0798-19.M
5
5
1
1
T-M18-3B FH
T-M18-3B BH
021F5S01.D
022F2401D
021FSS02.D
022F2402D
9.149
9.192
9.167
9.193
0.20
0.01
57.5
- 1.49
562
- 1 47
1.16
0.73
56.9
- 1.48
0798-19D.
0798-19.M
T-M18-4B FH
T-M18-4B BH
023FS601 D
024F2601 D
023FS602 D
024F2602.D
9.173
9.191
9.179
9.192
0.07
0.01
56.6
- 2.21
55.8
- 223
T-M18-FB-B FH
T-M18-FB-B BH
027F1101D
028F3001.D
027F1102.D
028F3002D
9.177
NA
9.178
NA
0.01
NA
39.2
< 1.00
38.6
< 1.00
0.72
0.27
0.68
0.00
56.2
- 2.22
38.9
< 1.00
0798-19D.
0798-19.M
0798-19D.
0798-19.M
5
5
5
5
5
5
1
1
1
1
I
I
325
- 15.2
340
284
-7.41
292
281
- 11.1
292
195
< 5.00
195
340 |
292 |
292 |
195 |
1 \JOBS98\I07\0798-19\074S-19AWB2 1000AM 09/23
-------
MDL: 1.00 ppm
LOQ: 5.00 ppm
Curve range (7.79 - 412 ppm)
' f} *t' :>, Soiqiie . •'•„..•'.; ;1 TliWtf" ;• Retention Time (mto.) •
toVntiflcarJoa W. * 1 I InJ. * 2 W-'l 1 Inl.*2
PinunMtra
.y^picii
PES
BGP
p-Xylene
20 CT lubes
CBntl:
roii
R«l»ttDM«:
R012.001
0798-19
104980229
09/23/98
, Percent '
. Difference
Concentration
InJ. #1 1 In), if 2
%DlrTerence
of Mean
~ Average
Cone.
oa.,
Curve,
Volume
(mL)
iWntion Catch Weight Total
Ratio (UK) Catch Welzht
T-M18-1A FH
T-M18-1A BH
009F0901.D
010F1001.D
009F0902D
010F1001 D
9.334
9.358
9.347
9.358
0.14
0.00
' 3.00
- 1.89
- 3.04
- 1.89
0.66
0.00
- 3.02
- 1.89
0798-19.M
0798-1 9. M
5
5
1
1
' 15.1
- 9.43
- 24.5
% Rec 1 15
- 21.3 1
T-M18-2A FH
T-M18-2A BH
011F1101 D
012F1201.D
011F11020
012F1202 D
9.361
NA
9.363
NA
0.02
NA
- 3.09
< 1.00
- 3.07
< 1.00
0.28
0.00
- 3.08
< 1.00
0798-19.M
0798-19.M
5
5
1
1
T-M18-3A FH
T-M18-3A BH
T-M18-4A FH
T-M18-4A BH
T-M18-FB-A FH
T-M18-FB-A BH
013F1301.D
014F1401.D
013F1302.D
014F1402 0
NA
NA
NA
NA
015F1S01.D
016F1601.D
025F2701.D
026F2801 D
015F1502 D
016F1602 D
025F2702 D
026F2802 D
NA
NA
9.343
NA
NA
NA
9.343
NA
NA
NA
NA
NA
0.00
NA
< 1.00
< 1.00
< 1.00
< 1.00
- 2.26
< 1.00
< 1.00
< 1.00
0.00
0.00
< 1.00
< 1.00
- 2.26
< 1.00
0.00
0.00
0.07
0.00
< 1.00
< 1.00
< 1.00
< .1.00
- 2.26
< 1.00
0798-19.M
0798-19.M
0798-19.M
0798-19.M
0798-19.M
0798-19.M
5
5
5
5
5
5
1
1
1
1
1
1
- 15.4
< 5.00
- 15.4
< 5.00
< 5.00
< 5.00
< 5.00
< 5.00
< 5.00
- 11.3
< 5.00
- 11.3
%Rec 115
- 13.4 |
%Rec 115
< 4.35 I
96 Rec 115
< 4.35 I
% Rec 1 15
- 9.83 |
T-M18-1B FH
T-M18-1B BH
017F1701.D
018F1801.D
017F1702 0
018F1802.D
9.348
NA
9.349
NA
0.01
NA
46.3
< 1.00
46.7
< 1.00
0.35
0.00
46.5
< 1. 00
0798-19.M
0798-19.M
5
5
1
1
T-M18-2B FH
T-M18-2B BH
019F2101.D
020F2201.D
019F2102.D
020F2202D
9.250
9.328
9.297
9.343
0.51
0.16
58.9
- 1.11
52.2
- 1.07
> 5 %
2.16
55.5
- 1.09
0798-19.M
0798-19.M
5
5
1
1
232
< 5.00
232
278
- 5
283
232 I
283 1
T-M18-3B FH
T-M1B-3B BH
T-M18-4B FH
T-M18-4B BH
021FS501.0
022F2401 D
023FS601.D
024F2601.0
021F5S02.D
022F2402.D
9.311
NA
023F5602.D
024F2602.D
9.336
NA
9.330
NA
9.342
NA
0.20
NA
51.8
< 1.00
0.06
NA
52.3
< 1.00
50.7
< 1.00
51.6
< 1.00
1.04
0.00
51.3
< 1.00
0798-19D.
0798-19.M
5
5
1
1
0.64
0.00
52.0
< 1.00
0798-19D.
0798-19.M
5
5
1
1
T-M18-FB-B FH
T-M18-FB-B BH
027F1101.D
028F3001.D
027F1102D
028F3002 D
9.339
NA
9.340
NA
0.01
NA
32.6
< 1.00
32.1
< 1.00
0.76
0.00
32.3
< 1.00
0798-19D.
0798-19.M
5
5
1
1
256
< 5.00
256
260
< 5.00
260
162
< 5.00
162
256 1
260 I
162 I
r^
ENTHALPYanalytical. inc.
jyOBSWKr7WJ|.|
-------
• ' 'v-Stafde-,' ' . ,-j
, IdenHtkatlon tnf
MDL: 1.00 ppm
LOQ: 5.00 ppm
Curve range (7.74 - 409 ppm)
• Lab ID
1 1 W. f 2
Itetentlnitlme (min.)
Inl.ll 1 Inj. #2
fSmpha;
PES
BGP
m-Xylene
20 CT lubes
' CBml:
Enthalpy »:
POI:
R012.0D1
0798-19
104980229
09/23/98
Difference
Concentration
InJ. #1 I Inl. #2
% Difference
of Mean
Average
Cone.
Cat.
Curve
Vohnne
(mW
Dilution Catdt Weight Total
Ratfo (ng) Catch Weight
T-M18-1A FH
T-M18-1A BH
009F0901.D
010F1001.D
009F0902D
OlOFtOOl D
9.476
NA
9.492
NA
0.17
NA
- 1.62
< 1.00
- 1.66
< 1.00
0.99
0.00
- 1.64
< 1.00
0798-19.M
0798-19.M
5
5
1
1
- 8.20
< 5.00
- 8.20
%Rec 115
- 7.13 |
T-M18-2A FH
T-M18-2A BH
011F1101.0
012F1201.D
011F1102D
012F1202.D
9.502
NA
9.504
NA
0.02
NA
' 1.57
< 1.00
- 1.59
< 1.00
0.42
0.00
- 1.58
< 1.00
0798-19.M
0798-19.M
5
5
1
1
-7.91
< 5.00
- 7.91
% Rec 115
- 6.87 |
T-M18-3A FH
T-M18-3A BH
013F1301.D
OMF1401.D
013F1302D
014F1402.D
NA
NA
NA
NA
NA
NA
< 1.00
< 1.00
< 1.00
< 1.00
0.00
0.00
< 1.00
< 1.00
T-M18-4A FH
T-M18-4A BH
015F1501.D
018F1801.D
015F1502D
016F1602 D
T-M18-FB-A FH
T-M18-FB-A BH
025F2701.0
026F2801 D
025F2702 0
026F2802.D
NA
NA
9.492
NA
NA
NA
NA
NA
9.491
NA
0.01
NA
< 1.00
< 1.00
< 1.00
< 1,00
0.00
0.00
< 1.00
< 1.00
' 1.02
< 1.00
0.89
0.00
< 1.00
< 1.00
- 1.01
< 1.00
0798-19.M
0798-19.M
0798-19.M
0798-19.M
0798-19.M
0798-1 9.M
5
5
5
5
5
5
1
1
1
1
1
1
< 5.00
< 5.00
< 5.00
< 5.00
< 5.00
< 5.00
- 5.05
< 5.00
- 5.05
%Rcc 115
< 4.35 I
%Rec 115
< 4.35 I
% Rec 115
- 4.39 |
T-M18-1B FH
T-M18-1B BH
T-M18-2B FH
T-M18-2B BH
T-M18-3B FH
T-M18-3B BH
T-M18-4B FH
T-M18-4B BH
017F1701.D
018F1801.D
019F2101.D
020F2201.D
017F1702.D
018F1802 D
9.485
NA
019F2102.D
020F2202.D
9.386
NA
021F5501.D
022F2401.D
021F5502.D
022F2402 D
023F5601.D
024F2601.D
023FS602.D
024F2602 D
9.448
NA
9.486
NA
0.01
NA
44.9
< 1.00
9.435
NA
9.467
NA
9.472
NA
9.478
NA
0.52
NA
0.20
NA
57.4
< 1.00
45.2
< 1.00
0.34
0.00
50.8
< 1.00
51.3
< 1.00
50.0
< 1.00
0.06
NA
52.2
< 1.00
51.4
< 1.00
> 5%
0.00
1.23
0.00
0.81
0.00
45.1
< 1.00
54.1
< 1.00
50.6
< 1.00
51.8
< 1.00
0798-19.M
0798-19.M
0798-19.M
0798-19.M
0798-19D.
0798- 19.M
0798-19D.
0798-19.M
5
5
5
5
5
5
5
5
I
1
1
1
1
1
1
1
225
< 5.00
225
271
< 5.00
271
253
< 5.00
253
259
< 5.00
259
225 I
271 I
253 I
259 I
T-M18-FB-B FH
T-M18-FB-B BH
027F1101D
02BF3001 D
027F1102D
028F3002.D
9.476
NA
9.476
NA
0.00
NA
32.0
< 1.00
31.5
< 1.00
0.81
0.00
31.7
< 1.00
0798- 19D.
0798-19.M
5
5
1
1
159
< 5.00
159
159 |
J \JOBS9S\J07\0798-19\079M9A WB2 10 00 AM 09/23
-------
MDL: 1.00 ppm
LOQ: 5.00 ppm
Curve range (7.70 - 407 ppm)
Compuw
Anmlyrt:
PuwKten:
ISumXtK
PES
BGP
Cumenc
20 CT tubes
CUratf:
KaOutwt:
VOt:
Report Date
R012.001
0798-19
104980229
09/23/98
R
fi».*i Mm.**
Retention Time (
Inf.fl
Difference
Concentration
Inl.*l 1 Inl.#2
% Difference
Average
Cone.
Cat.
Volume
Ratio
Catch Wright
«*>
Catch Weight
T-M18-1A FH
T-M18-1A BH
T-M18-2A FH
T-M18-2A BH
T-M18-3A FH
T-M18-3A BH
T-M18-4A FH
T-M18-4A BH
009F0901.D
010F1001.D
009F0902D
010F1001 D
9.984
NA
9.998
NA
0.14
NA
5.58
< 1.00
- 2.68
< 1.00
> 5 %
0.00
- 4.13
< 1.00
0798-19.M
0798-19.M
5
5
011F1101.D
012F1201.D
011F1102.D
012F1202.D
10.008
NA
10.009
NA
0.01
NA
- 2.70
< 1.00
- 3.06
< 1.00
> 5 %
0.00
- 2.88
< 1.00
0798-19.M
0798-19.M
5
5
013F1301.D
014F1401.D
015F1501.D
016F1601.D
013F1302.D
014F1402.O
NA
NA
NA
NA
NA
NA
< 1.00
< 1.00
< 1.00
< 1.00
0.00
0.00
< 1.00
< 1.00
0798-19.M
0798-19.M
5
5
01SF15Q2.D
016F1602.D
NA
NA
NA
NA
NA
NA
< 1.00
< 1.00
< 1.00
< 1.00
0.00
0.00
< 1.00
< 1.00
0798-1 9. M
0798-19.M
5
5
T-M18-FB-A FH
T-M18-FB-A BH
025F2701.D
026F2801.D
025F2702.D
026F2802.0
9.997
NA
9.998
NA
0.01
NA
6.28
< 1.00
6.26
< 1.00
0.15
0.00
6.27
< 1.00
0798-19.M
0798-19.M
5
5
1 j
!
1
1
1
1
1
1
1
1
- 20.6
< 5.00
- 20.6
- 14.4
< 5.00
' 14.4
< 5.00
< 5.00
< 5.00
< 5.00
< 5.00
< 5.00
31.3
< 5.00
31.3
% Rec 128
"16.1 |
% Rec 128
- 11.3 I
% Rec 128
< 3.91 I
% Rec 128
< 3.91 I
% Rec 128
24.5 I
T-M18-1B FH
T-M18-1B BH
T-M18-2B FH
T-M18-2B BH
017F1701.D
018F1801.D
017F1702.D
018F1802.D
10.108
NA
10.110
NA
0.02
NA
51.7
< 1.00
53.3
< 1.00
1.53
0.00
52.5
< 1.00
0798-19.M
0798-1 9. M
5
5
1
1
01SF21Q1 D
020F2201 D
019F2102.D
020F2202.D
10.014
NA
10.060
NA
0.46
NA
65.8
< 1.00
56.9
< 1.00
> 5 %
0.00
61.3
< 1.00
0798-19.M
0798-19.M
5
5
1
1
262
< 5.00
262
307
< 5.00
307
262 |
307 I
T-M18-3B FH
T-M18-3B BH
021F5501D
022F24010
021F5S02.D
022F2402.D
10.072
NA
10.090
NA
0.18
NA
57.0
< 1.00
55.7
< 1.00
1.13
0.00
56.3
< 1.00
0798-19D.
0798-19.M
5
5
1
1
T-M18-4B FH
T-M18-4B BH
T-M18-FB-B FH
T-M18-FB-B BH
023FS601 D
024F2601 D
027F1101.D
028F3001.D
023F5602.D
024F2602.D
10.096
NA
10.102
NA
0.06
NA
56.3
< 1.00
55.5
< 1.00
0.76
0.00
55.9
< 1.00
0798-19D.
0798-19.M
5
5
1
1
027F1102.D
028F3002.D
10.099
NA
10.099
NA
0.00
NA
40.9
< 1.00
40.1
< 1.00
1.01
0.00
40.5
< 1.00
0798- 19D.
0798-1 9. M
5
5
1
1
282
< 5.00
282
279
< 5.00
279
203
< 5.00
203
282 I
279 |
203 |
ENTHALPYanalytical, inc.
Pip I
1 yOMW\W7Mm«-lwn»»-l»A
10-QO AM 09/M
-------
MDL: 1.00 ppm
LOQ: 5.00 ppm
Curve range (7.67 - 406 ppm)
Sample •- . ' , •', L»bn> '
JdentiflaiHon W.H 1 InJ./2
Retention Time (mid.)
Inl. /I 1. lai.tl
. *3&
PES
BOP
o-Xykne
20 CT lubes
• , Qtnti:
:. R«t>0«D»fK
R012 001
0798-19
104980229
09/23/98
Difference
Concentration
Inl.Jl 1 Iot.fl
* Difference
of Mean
Cone.
Cal.
Curve
Volume
(mL) ,
Motion CstchWel^bt Total
Ratio faf) Catch Weight
T-M18-1A FH
T-M18-1A BH
009F0901.D
010F1001.D
009F0902.D
010F1001 D
10.393
NA
10.407
NA
0.13
NA
- 2.35
< 1.00
< 1.00
< 1.00
> 5 %
0.00
' 1.68
< 1.00
0798-19.M
0798-1 9.M
5
5
1
I
T-M18-2A FH
T-M1&-2A BH
011F1101.D
012F1201.D
T-M18-3A FH
T-M18-3A BH
013F1301.D
014F1401.D
011F1102.D
012F1202 D
10.593
NA
10.424
NA
1.60
NA
- 1.38
< 1.00
< 1.00
< 1.00
> 5 %
0.00
- 1.19
< 1.00
0798-19.M
0798-19.M
5
5
013F1302.D
OMF1402.D
NA
NA
NA
NA
NA
NA
< 1.00
< 1.00
< 1.00
< 1.00
0.00
0.00
< 1.00
< 1.00
0798-19.M
0798-19.M
5
5
1
1
1
1
T-M18-4A FH
T-M18-4A BH
015F1501.D
016F1601.D
015F1502.D
016F1602.D
NA
NA
NA
NA
NA
NA
< 1.00
< 1.00
< 1.00
< ).00
0.00
0.00
< 1.00
< 1.00
0798-19.M
0798-19.M
5
5
1
1
T-M18-FB-A FH
T-M1»-FB-A BH
025F2701.D
026F2801.D
025F2702.D
026F2802.O
10.581
NA
10.576
NA
0.05
NA
- 3.32
< 1.00
- 3.41
< 1 00
1.37
0.00
- 3.37
< 1.00
0798-19.M
0798-1 9. M
5
5
1
1
- 8.38
< 5.00
- 8.38
- 5.95
< 5.00
- 5.95
< 5.00
< 5.00
< 5.00
< 5.00
< 5.00
< 5.00
- 16.8
< 5.00
- 16.8
% Rec 105
- 7.98 |
% Rec 105
- 5.66 I
% Rec 105
< 4.76 |
% Rec 105
< 4.76 1
% Rec 105
- 16.0 |
T-M18-1B FH
T-M18-1B BH
017F1701.D
018F1801.D
017F1T02.D
01BF1802.0
10.404
NA
10.405
NA
0.01
NA
38.9
< 1.00
41.3
< 1.00
3.02
0.00
40.1
< 1.00
0798-19.M
0798-19.M
5
5
1
1
T-M18-2B FH
T-M18-2B BH
019F2101 D
020F2201.D
019F2102.D
020F2202D
10.309
NA
10.355
NA
0.45
NA
53.0
< 1.00
44.2
< 1.00
> 5%
0.00
48.6
< 1.00
0798-19.M
0798-19.M
5
5
1
1
T-M18-3B FH
T-M18-3B BH
021F5501.D
022F2401 0
021F5502D
022F2402.D
10.368
NA
10.386
NA
0.17
NA
46.7
< 1.00
45.6
< 1.00
1.17
0.00
46.1
< 1.00
0798-19D.
0798-19.M
5
5
1
1
T-M18-4B FH
T-M18-4B BH
023F5601 D
024F2601.D
023F5602.D
024F2602.O
10.392
NA
10.398
NA
0.06
NA
47.8
< 1.00
47.0
< 1.00
0.75
0.00
47.4
< 1.00
0798-19D.
0798-19.M
5
5
1
1
200
< 5.00
200
243
< 5.00
243
231
< 5.00
231
237
< 5.00
237
200 I
243 1
231 1
237 I
T-M18-FB-B FH
T-M18-FB-B BH
027F1101.D
028F3001.0
027F1102.D
028F3002 D
10.395
NA
10.396
NA
0.01
NA
29.1
< 1.00
28.6
< 1.00
1.02
0.00
28.9
< 1.00
0798-19D.
0798-19.M
5
5
1
1
144
< 5.00
144
144 |
J \JOBS9S\I07\079S-19\079S-19AWB2 1000AM 09/23
-------
Tunnel
Spike & Recovery
18
ENTHALPYanalytical. inc.
-------
Spike and Recovery Calculations
Hexane
T-M18-1A
Spike Ami.
Catch (ug)
Simple Volume
Spiked Train
204
Un-spiked Train
Volume Adjusted Spike Catch
263
- 12.8
250
233.2
231.9
NA
122
T-M18-2A
Spite Ami.
Catch (ug)
Spiked Train I 204
Un-spiked Train
Volume Adjusted Spike Catch
322
- 24.1
298
229.7
230.3
NA
146
T-M18-3A
Spike Ami
Catch (ug)
Sample Volume
Recovery (%)
Spiked Train I 204
Un-spiked Train
Volume Adjusted Spike Catch
256
< 5.00
256
229.3
230.7
NA
125
T-M18-4A
Spike Ami.
Catch hit)
Sample Volume
Recovery (%)
Spiked Train
204
Un-spiked Train
Volume Adjusted Spike Catch
267
< 5.00
267
229.0
225.8
NA
131
Avg: 131
Benzene
T-M18-1A
Spike Ami
Catch (ut)
Sample Volume
Recovery (%)
Spiked Train
218
Un-spiked Train
Volume Adjusted Spike Catch
224
< 5.00
224
233.2
231.9
NA
103
T-M18-2A
Spike Ami.
CMch(ut)
Simple Volume
Recovery (%)
Spiked Train
218
Un-spiked Train
Volume Adjusted Spike Catch
274
- 5.85
268
229.7
230.3
NA
123
T-M18-3A
Spike Ami.
Catch (uj)
Simple Volume
Recovery (%)
Spiked Train
218
Un-spiked Train
Volume Adjusted Spike Catch
246
< 5.00
246
229.3
230.7
NA
113
T-M18-4A
Sinnlc Volume
Spiked Train
218
Un-spiked Train
Volume Adjusted Spike Catch
253
< 5.00
253
229.0
225.8
NA
116
Avg: 114
ENTHALPYanalytical,
19
|-\IOBS»t\J07W7M-19UI79>-19AWB2 1009AM 09/23
-------
Spike and Recovery Calculations
Toluene
Spike Ami,
Catch (ug)
Sample Volume
T-M18-1A
T-M18-2A
T-M18-3A
T-M18-4A
T-M18-1A
T-M18-2A
T-M18-3A
T-M18-4A
Spiked Train
216
Un-spiked Train
Volume Adjusted Spike Catch
235
- 17.8
217
233.2
231.9
NA
101
Spike Ami. Catch (UK) Sample Volume Recovery (K)
Spiked Train
216
Un-spiked Train
Volume Adjusted Spike Catch
308
- 30.1
278
229.7
230.3
NA
129
Spike Ami. Catch (HE) Sample Volume Recovery (%)
Spiked Train
Un-spiked Train
216
Volume Adjusted Spike Catch
Spiked Train
266
- 11.8
254
229.3
2307
NA
118
Spike Ami Catch (ue) Sample Volume Recovery (%)
216
Un-spiked Train
Volume Adjusted Spike Catch
Ethyl benzene
Spiked Train
270
- 10.6
259
229.0
225.8
NA
120
Spike Aim Catch (UE) Sample Volume Recovery («)
215
Un-spiked Train
Volume Adjusted Spike Catch
277
41.2
236
233.2
231.9
NA
110
Spike Aim Catch (ug) Sample Volume Recovery (%)
Spiked Train
215
Un-spiked Train
Volume Adjusted Spike Catch
Spiked Train
340
51.3
' 289
229.7
230.3
NA
134
Spike Ami Catch (u£) Sample Volume Recovery (%)
215
Un-spiked Train
Volume Adjusted Spike Catch
292
- 15.4
276
229.3
230.7
NA
129
Spike Aim. Catch (ue) Sample Volume Recovery^
Spiked Train
215
Un-spiked Train
Volume Adjusted Spike Catch
292
- 19.3
273
229.0
225.8
NA
127
Avg: 117
Avg: 125
ENTHALPY a na lyti ca I,
inc.
20
HM»AU ma
-------
Spike and Recovery Calculations
p-Xylene
Spite Ami
Catch (UE)
Sample Volume
T-M18-1A
T-M18-2A
T-M18-3A
T-M18-4A
T-M18-IA
T-M18-2A
T-M18-3A
T-M18-4A
Spited Train
216
Un-spiked Train
Volume Adjusted Spike Catch
232
- 24.5
208
233.2
231.9
NA
96.2
Spike Ami Catch (UE) Simple Volume Recovery (%)
Spiked Train
Un-spiked Train
216
Volume Adjusted Spike Catch
283
- 15.4
268
229.7
230.3
NA
124
Spike Aim. Catch (ug) Sample Volume Recovery (%)
Spiked Train
Un-spiked Train
216
Volume Adjusted Spike Catch
Spiked Train
256
< 5.00
256
229.3
230.7
NA
119
Spike Ami Catch (ue) Sample Volume Recovery (%>
216
Un-spiked Train
Volume Adjusted Spike Catch
m-Xylene
Spiked Train
Un-spiked Train
260
< 5.00
260
229.0
225.8
NA
120
Spike Ami Catch (UE) Sample Volume Recovery (*)
215
Volume Adiusted Spike Catch
Spiked Train
225
- 8.20
217
233.2
231.9
NA
101
Spike Ami. Catch (ug) Sample Volume Recovery (%)
215
Un-spiked Train
Volume Adiusted Spike Catch
271
- 7.91
263
229.7
230.3
NA
122
Spike Ami Catch (us) Sample Volume Recovery (%)
Spiked Train
Un-spiked Train
215
Volume Adiusted Spike Catch
253
< 5.00
253
229.3
230.7
NA
118
Spike Ami Catch (UE) Sample Volume Recovery (*)
Spiked Train
215
Un-spiked Train
Volume Adjusted Spike Catch
259
< 5.00
259
229.0
225.8
NA
121
Avg: 115
Avg: 115
ENTHALPY analytics I,
inc.
21
J:\IOB9M\l07\ir7M-imnM-19AWB2 1009AM DW23
-------
Spike and Recovery Calculations
Cumene
Spike Ami
Catch (UE)
Sample Volume
Recovery (%)
T-M18-1A
T-M18-2A
T-M18-3A
T-M18-1A
T-M18-2A
T-M18-3A
T-M18-4A
Spiked Train 214
Un-spiked Train
Volume Adjusted Spike Catch
262
- 20.6
242
233.2
231.9
NA
113
Spike Ami Catch (UE) Sample Volume Recovery (%)
Spiked Train 214
Un-spiked Train
Volume Adjusted Spike Catch
307
- 14.4
292
229.7
230.3
NA
137
Spike Ami. Calch (us) Sample Volume Recovery (%)
Spiked Train 214
Un-spiked Train
Volume Adjusted Spike Catch
282
< 5.00
282
229.3
230.7
NA
132
Spike Ami Catch (ue) Sample Volume Recovery («)
Spiked Train 214
Un-spiked Train
Volume Adjusted Spike Catch
279
< 5.00
279
229.0
225.8
NA
131
O-Xylene Spike Amt. Catch (UE) Sample Volume Recovery (%)
Spiked Train 213
Un-spiked Train
Volume Adjusted Spike Catch
200
' 8.38
192
233.2
231.9
NA
90.1
Spike Amt Catch (UE) Sample Volume Recovery (%)
Spiked Train 213
Un-spiked Train
Volume Adjusted Spike Catch
243
- 5.95
237
229.7
230.3
NA
111
Spike Amt Catch (ug) Sample Volume Recovery (*)
Spiked Train 213
Un-spiked Train
Volume Adjusted Spike Catch
231
< 5.00
231
229.3
230.7
NA
108
Spike Amt. Calch (ue) Sample Volume Recovery (%}
Spiked Train 213
Un-spiked Train
Volume Adjusted Spike Catch
237
< 5.00
237
229.0
225.8
NA
111
Avg: 128
Avg: 105
ENTHALPYanalytical,
inc.
22
j:\j06Stt\jm\o7M-iwnM-iMWB2
-------
Tunnel
Sample & Curve
Chromatograms
2'
£»«
ENTHALPYanalytical, inc.
-------
if a
fwr'T-Q-aw.
Injection.. Date'
Sample Name
Acq. Operator- - •
Sequence File
Acq. "Method
Last -changed
Analysis Method
Last 'changed'
;6:: 28: 50 ~.
T-M18-R1 'Aa+AbEH
Vial
- Ml 8 - Rl' "Aa+ AbFH
'9.-
9
1
- - . -..iir-, .. . Inj Volume
E rXHPG-HEM-\-TELLER^SEQUENGE-t0798 -T9AVS" • - --
E : \HPCHEM\TELLER\-METHODS\0798-19A:"M"
E:\HPCHEM\TELLER\METHODS"V07.9"8.-19:Jf
FID1A, (0798-19B\009F09Q1 .D)
counts
18000-j-
16000
. .. 10
.15
20.
mm
External Standard Report
Sorted By- • : Signal
Calib.. Data-.Modified i.- -.. -.-. B,/3/ 9 a.-1.1: Q.^tl.6. -AM
Multiplier.; •" r ...'; :"V:>-^-,.: .:::'r^do.(jo:/. .;...-.-•-7--^'..-:::•"?•
Dilution . . '.-.."-"".-;" .-"-.-' ."l.-O.QO'O" •
Signal• 1:-Pi-Dl.A.r "••--••-• ••-••' - . • • •-_-.-.--.- ••,- ••"--.
RetTime Type ^^f/ .;: .-Amt/Area Amount.... -Grp-_-. Name -.
. .jjmin] . ..- ." counts'*?'.," "'.'".:'~~_~'" ' "' "'""'"
1.462 VP
5.409
7.388 VB
9.177 BV
9/33-4 "w
9.476 VP
9.984 VB
.10.393 -BV
1916.04797 9.19566e-4
1.76193
2436,
6532,
35BT.
1943,
6238,
2.9DO-.
76343
23438
24121
70.435
51465
57733
8.30843e-4
8.289516-4
8.3'63-80e-4
8.35032e-4
8.93-8266-4
.'8-.1020uOe-.4
02457
41490
00030
1.62305
5.57615
2...3-5Q05
Hexane
Benzene
Toluene
Ethylbenzene
-p--xylene
.m-Xylene
Cumene
,. o-Xylene.
»lTer:3
-------
Data
Ltf£SH^B;^^M1:8--Ri - ;Aa *Ab.FH
Injection Date : 7/31/98 6:59:11 PM
Sample Name : T-M18-R1 Aa+AbFH
Acq. Operator : bgp
Seq. Line : 9
Vial : 9
Inj : 2
—r:-: 2
Analysis Methpd "::" E>\HPCH^\^^ ':'.
Last changed:":.r.-i~'''' '*" " " •-'-—-•"
"5- •'
. -10
• . "15'
20
External Standard Report
•*- ---*-*-- -—-^ --"— -- '"-'-- • "-. "- - •"'""
Sorted-By;- - .'
Ca-1-ibv..-Dat.a.. Modified,,.-<,-^--r-^ ^.8^aa:^^_.
Multiplier— "-" ,-.[- '[ ~.\\ •.T'-'-':r--lv?:p'Q0'p;i-"- "-"--••="- ';!''"/•;;•;.' ,./;-':
Dilution ;---•_,..- : -..,-,. .; -t-.-.'^-^l-vQ.Q'p-O;,--.,... .:-_. .';-.._• -~ .-.-.V,-.V;u! _—„-;?---
Signal l: FID-l A,-- - •- " "" • ' " """ " "
RetTime Type- "" Arjea" .:Amt"/Area Amount-"-" Grp" :"" Name
[min] counts*-s • - • [ug'/kg] - " "•-"
,. |._-__•____-,.,__-, |-
1.464 VP - 3669.848.11. 9.-
5.4'X)9.
Totals :
Results obtained..with, enhanced .integrator 1
2 Warnings' or-Errors : ......
Warning : Calibration-"warnings, (see calibration "table listing)
Warning : Calibrated compound(s) riot found
25
To! 1 or- fi XT /QP 1 1 • 1 0 • 07 AM bOO
Page 1 of 2
-------
AbBH
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
•7/31/98- 7; 29: 45'
T-M18-R1 AbBH .
:. S.eq. Line
Vial.
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19A.S
E:\HPCHEM\TELLER\METHODS\0798-19A.M
7/31/98 6:22:19 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19.M
8/3/98 11:06:31 AM by bgp
10
10
1
2 /xl
FID1A, (0798-1 9B\010F1 001. D)
counts j ?
"1 -r-
J (Si
18000 -j
1
16000^
t
t
i
' J f '
14000-1 I
1 |
; 12000 -^ i g
H
J
10000 -I
j
Q) i
S
at'a Mddi:'fied^
"Multiplier;-- .-
Dilution- - —-
Signal
AM
-i-.-oooo
bignaj. .
Ret Time
[min]
1.467
5.409
7.409
9.200
9.358
9.474
10.097
10.393
: i? ID1
Type
- _ _ i
1
BP
BV
VB
A', '• -"
Area
counts*s
1325.48633
3333.27417
2254.26270
Amt /Area
8.30843e-4
8.28951e-4
8.363806-4
...Amount..
[ug"/kg]
1.10127
2.76312
1.88542
Grp. Name
i
"1
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals Y
5/74981"
Results obtained with enhanced integrator!
2 Warnings or Errors :
Warning : Calibration warnings (see calibration table listing)
Warning : Calibrated compound(s) not found
26
slier 8/3/98
-AM "bgp -------
-Page 1 of 2
-------
Data File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19B\010F1002.D
T-M18-R1 AbBH
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
7/31/98 8:00:14 PM
T-M18-R1 AbBH
bgp
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19A.S
E:\HPCHEM\TELLER\METHODS\0798-19A. M
7/31/98 6:22:19 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19.M
8/3/98 11:06:31 AM by bgp
10
10
2
FID1 A, (0798-1 9B\010F1002.D)
I
counts H $ 5
1 5 3
18000-}
1600XH
i
14000^
^
12CKXH
lj
J
10000 H
8000 J
1
J
6000-^j 8
C
s
i •%
i • i
- ? s l-
lr W • h- 00 TJ
-------
ata File E:\HPCHEM\TELLER\QATA\1998\jyL98\079.8-19B.\011F1101 .D T-M18-R2 Aa+AbFH
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
7/31/98 8:30:47 PM
T-M18-R2 Aa+AbFH
bgp
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19A. S
E-: \HPCHEM\TELLER\METHODS\0798 - 19A. M
7/31/98 6:22:19 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19.M
8/3/98 11:06:31 AM by bgp
11
11
1
FID1A, (0798-19B\011F1101.D)
10
15
20
min
-External Standard Report- ..
Sorted By :
Calib. Data Modified :
Multiplier :
Dilution :
Signal 1: FID1 A,
RetTime Type Area
[min] counts*s
Signal
8/3/98 11:04:16 AM
1.0000
1.0000
Amt/Area
Amount
[ug/kg]
Grp
Name
1.461 VP
5.420 VP
5098.51855 9.19566e-4
1384.52429 8.40787e-4
"
4.68842
1.16409
Hexane
Benzene
9.-203-BV
9/502 VP
10.008 VB
10.593 W
Totals :
188S.59692 8 .'350326-4
3022.40161 8.93826e-4
1702.03247 8.10200e-4
-- 8,4643-2- ^--Ethyl-benzene--
~~3T(W13T":~'~~-* p^yl-ene"
1.57453 m-Xylene
Cumene
o-Xylene
2.70150
1.37899
27.68545
Results obtained with enhanced integrator!
1 Warnings or Errors :
Warning j--Calibration-warnings;, (-see- cai-ibration tabl~e- 1-is-fcing)
28
slier 8/3"/98 "11:1'0:43 AM."bgp""
Pa'ge 1 of 2
-------
Data File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19B\OliF1102.D~ T-M18-R2 Aa+AbFH
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
7/31/98 9:01:16 PM
T-M18-R2 Aa+AbFH
bgp
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19A.S
E": \HPCHEM\TELLER\METHODS\0798-19A.M
7/31/98 6:22:19 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19 .M-
8/3/98 11: 06-: 31 AM by-bgp
11
11
2
RD'f A,
counts J
1
18000 -4
-j
16000^
14000-j
(0798-1 9B\011Flf02.D) ' "_
81" ' " •'-"-'-'• "• ---•-•• j
T. t
14 a
i
t
i
r-.
22 ft! ,
-------
ita File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19B\012F1201.D.
T-M18-R2 AbFH
Injection Date
Sample _Name
aerator
-7/31/98 9:31:43 PM «,? "\^. . Seq. -Line :
v>\\+ -
-. ...cAv.VV-._- ...
Acqr M
-Lasi^-Gh^ri^erdt1-. ^
Analysis' -fM^rh'od-
T-M18-R2 AbPff .P?^. -. .^USVT - Yi§I_.:
^^I^v-;v""-3C'"--^'-^ ;-;r.^^^l^pJ—ii 1^'^^mii
t?^^^^:^^^--y ..^ v-.-•^-;""-.-;7/.:?^^"f-^In'^•3^635®^'"'
^^^("^MX-^frrrtj^^RnTT^^^n^^^
^33&xM^5;;'y:
12 -
1.2,
-i' --
~2"^
^
-.:-4
counts H
18000 -j
SI
.i4bda4--^--w
-j
•-" 3-
t - — .^..., --. . _ --C^ - - * - -
* •r~*;r^?-JX^i-^.-*-i«.-«»»~ I"?"" ^" -?• ~^'V'-tIl'-^'*i:-i'rr?r;&??^'';^-~* f '^ '''r-J^i t^'"~'rV~
4r--•*^^"--^i%^'^iSS^>i-^^'i-5»?.^U3^-,.«^ir?^.-=t
„,,,.,..,.-.-,--» ii,^^^.-^0i,«ii-a.g^rs-.r.;.---_-r.-rj-~!;-
;-;;i •--•--•-.;-.- ^.-^;i^7.;;';.-_iCrj'rr-i T-'.;i;'.$!iT_.:;r-;":r','--l];ttr.'-"c
-.--j.r^ ---v--
-------
Data-: File -EV-\H-;
-R2: AbFH
Injections-Bate -r 7-/J1V9-&-•10-:-0-2-r06 -PM -
Sample Name -~ : :T-M18-R2.
Acq. Operator : bgp;. :.--,..-.
.- -"-.".- : -. .-" -.-. . """".- ...Inj .Volume
Sequence-File - -:. -E-:--\JIPCHEM.\TELLER\-SEQUENCEVO"79A'-1.9A^S .-..- -
Acq. Method - : - E : \HP,CHEM\T.ELLER\METHODS~VO 7 9 8-19A:. M
-li'as£:;.~(
"Analyses";
.Las'-t"'_t'
----- 12-
: 12
: _. 2
:-.2 u.:
Multipl'-ier-" ." -
Dilution.
.*•-"£- '- -• -^3^aa,,,li-r04.: 1& -ftM-..> /- : :-
".." : ' :/ ^-0000 -..".-•" :. • " '. .. J_~
Signal 1- FIDl A, '"'-". :-'r" ' ;'; • ••"•" ••••"'--.-.•--..- --;
RetTime- .-Type . - {Area— ^-- \ --Amt-^Area -.". ."-^-AmQunt- "I'l-'-Grpr-' —Name--
[minj count S*SL . „ . Lug./kgJ -
-----
/:r...CZST ^Ei- -.':Z ^5S^S8^^"9^^5.6u6e^4;.^;9519JD.e^^sr^esa^ :J....
" ^ - - ~- • ' * - ' " -" "i. t '- ~' ™" - - "' , _. . • •.— --.".-" " .- -" - ' ' -- • ~->—^v A- . .-*r - - - -
-• "5" 409" ' •' ••"«•-• '•-'*%1"1""- -. -,,,.^-«. - , -- "_ _» • ,' . ^ r . , -. *Cl^^T^ ff CITTJli~~ - - - "
9.4-74 -"•.:-'-;••"-"- -•<-----.-,•-- -;' - ' "--
io.-o9y " '; ^^l^---""'"r"^': :-;
10.J93' ". ' -; ~:~-":~:- "- ^J" "."'" -^--------
Totals : - - - '
4.87910
j,__--Rj5juljyi(j^^ ^V^^X^" _
-Warning ":""'Caiibratipn":Tra"^'ings"";(s^^7:calibratip~n-rtaipl|l "ir?siring)
Warn±fig^zCa±i^r^ "" •""
,??2. ••_ . '. '^^--^:
31
i^ 1-1 •>,».—
-I t-r-r-r T—*»M —^TrtYS
pa'cre • r
-------
ita File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19B\013F1301.D T-M18-R3 Aa+AbFH
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
7/31/98 10:32:24 PM
T-M18-R3 Aa+AbFH
bgp
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19A.S
E:\HPCHEM\TELLER\METHODS\0798-19A.M
7/31/98 6:22:19 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19.M
8/3/98 11:06:31 AM by bgp
13
13
1
FID1A, (0798-1 9B\013F1 301. D)
counts J (
j f
18000H
1
j
16000-j
H
4
14000^
12000-
j
10000 J
I
8000 ^j |
6000 -^ T
H eoo
J OI>-
4000^ ^
! !
4 r
1
j
1
8
-=• £K
H uE.
M ^ t §g
i ^~ ^! <^ **7
CN CM CO
CM O) O o
to ion S
N: «o°. o)
fcl ^V-— i>'\^^/v^>—
•»5 / U-^"^
^ /Y ^^
•*i/ J^~^
m Is* oo as) i ~"A£*^
- — -
10
15
20
min
• Sor,ted.:By;-"--.. - .,. =_...---.1 :T.- -——- -Sigoial^;—^ -.-,..:...:-... ^i..--.--^;-.--,:,".--.>;-• ^.-.._...... - - ,
^ Cal-^j_4rj^a"Mp^^ ^l;.'.;-;:..""- '..
,,1-T.^ j - -- --'~-* ~ ^•^•'~^'''< c~-~-~r~~-••---~ - --•"- *
Ret-Time- ""-"Hype' "." ; vA'rea-r:"~-A-:::""-Am.t^/-Area^
[min] counts*s [ug/kg]
.- :'"T v4-7a::^B:' vviV^^^^l^r^ti'Cs^^^ .-:'-"•" .'--
""" " r ..... "' "
5.409
"" '
~" Benzene
•| V' ;• * -•* 5. ssi-r-v*sjE**ft: --t-- ^^-^v-^/^-'j^i^i^si^^Jisi^-A^^i'—---^^--^.*™ ""«=^W-^»»'V^-i-r •«>..-•*- ^^-;,;A*i^-->*». A:«a5^ift,«Wji*i-fe***.i6E.<*.'f^ is* '.r-r^J^t^r-^iA-v -- .-•- • "; .-*-
-------
Data File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19B\013F1302.D T-M18-R3 Aa+AbFH
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
7/31/98 11:02:42
T-M18-R3 Aa+AbFH
PM
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19A.S
E:\HPCHEM\TELLER\METHODS\0798-19A.M
7/31/98 6:22:19 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19.M
8/3/98 11:06:31 AM by bgp
12000-
1
10CKXH
-
8000 ^
6000 H
4CXXH
r-.
in
o
o co
5 CNJ
N- eb
13
13
2
FID1 A,
counts jj
1
18000 H
1
16000-1
1
14000^
(0798-19B\013F1302.D)
mi T
9 ;
f! :
i
i
+
10
20
mm
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FID1 A,
Signal
8/3/98 11:04:16 AM
1.0000
1.0000
RetTime
[min]
1.476
5.409
7.410
9.199
9.362
9.474
10.097
10.393
Type
BB
BP
BV
VB
Area
counts*s
741.12000
-
1592.62354
2039.45740
710.55457
-
Amt/Area
9.19566e-4
-
8.308436-4
8.289516-4
8.363806-4
-
Amount G
[ug/kg]
6.81509e-l
-
1.32322
1.69061
5.942936-1
-
rp Name
Hexaas
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals
4.28963
Results obtained with enhanced integrator!
2 Warnings or Errors :
Warning : Calibration warnings (see calibration table listing)
Warning : Calibrated compound(s) not found
Teller 8/3/98 11:11:40 AM bcro
Page 1 of 2
-------
ta File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19B\014F1401.D T-M18-R3 AbBH
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
7/31/98 11:33:00 PM
T-M18-R3 AbBH
bgp
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19A.S
E:\HPCHEM\TELLER\METHODS\0798 -19A. M
7/31/98 6:22:19 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19.M
8/3/98 11:06:31 AM by bgp
14
14
1
counts jj
FIDTA," (0798;t9B\014FT401-.D)—'
SI
T:
-"; j~ - -. ->?-. - ~ - --- ---'
^_ __g^^As^;"':^^;;-.rf-X^,-l-.-^r;^g
-• • -'--^-;:-V,«.1s;r|:^-rii-^-^..p^ - --••-: - ;
- :5,;. 40 9"-"~; ;:•;•-- - •_•'—.-** -.—-•'_- r?-"sjri v£v«-,-.?-Ar«s.''^"y«. •-. - i-r•i*i-;rv'.-. . "•:;; r.^Ci-^'N";^^"-^-'-.^^
91i98"PV 1713". 40027 "8 ."28"951e-4 1 .'42032 " " "Ethylbenzene
9".3"3'8 " - - - " p~XyIehe "
9 ..474 - - - - m-Xylene
10,097 .. -, .... .... - . ..... ... _=. , _. . ....," . Cumene., ,
Totals--: " •" --- -".,-'. ~-"--'-". 7V / - " -2-rS052i"-~""--'-"----"-.
Results, obta'ined with .-.enhanced integrator 1 . „•"."".:-.' "--. ,"-• -\.:. " "
^ ini iQ *^TT j T* ^-? 5 ^j IT * HI ~]^ JL^^J *^ s *' * ~ ' " ..*-.*- ..
T *s, • -^- ', ,-„ ._, ..' . -. i ff _ . »^ V9-* ." . -—- '•.v ."-*- *"»,• :*fi^fj. *^ 't .'.y-ja ,-^. i »,. >-, " -'. -~<~*-*-t- -" ' . r ,. r _ f, f-i »,-^kv-l» j.~"J -: •• T- r ','"..- *"- ^-»_'i - ',*-'* --'•" " . .-'
Warning : Calibration warnings (see calibration table-listing)
Warning : Calibrated compound(s) not found
Her 8/3/98 11:11:52 AM bgp Page 1 of 2
-------
Data File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19B\014F1402.D
T-M18-R3 AbBH
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
8/1/98 12:03:13 AM Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0 7 9 8-19A.S
E:\HPCHEM\TELLER\METHODS\0798-19A.M
7/31/98 6:22:19 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19.M
8/3/98 11:06:31 AM by bgp
14
14
2
FID1 A, (0798-1 9B\014F1402.D) |
counts J SI '
1 3 !
18000-
16000^
14000^
^
12000-1
1
10000H
8000 H
6000 J
4000- ~
•
i
I
0)
c
0)
N
1 1
3 >•
5 E
o)
? 5 i
"H r !
•> H- i
•? T^ 1
!
I
! |
i
\.~^_^^--~ , i
S\
0 5 10 15 20 mm
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FID1 A,
Signal
8/3/98 11:04:16 AM
1.0000
1.0000
RetTime
[min]
1.467
5.409
7.406
9.194
9.338
9.474
10.097
10.393
Type Area
count s*s
i __
1
-
BB 1245.97449
PV 1704.23376
-
-
-
-
Amt/Area
_
-
8.30843e-4
8.28951e-4
-
-
-
-
Amount G
[ug/kg]
_
-
1.03521
1.41273
-
-
-
-
rp Name
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals :
2.44794
Results obtained with enhanced integrator!
2 Warnings or Errors :
Warning .- Calibration warnings (see calibration table listing)
Warning .- Calibrated compound(s) not found
Teller 8/3/98 11:12:03 AM bgp
Page 1 of 2
-------
ata File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19B\015F1501.D T-M18-R4 Aa+AbFH
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
8/1/98 12:33:31 AM
T-M18-R4 Aa+AbFH
bgp
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19A.S
E:\HPCHEM\TELLER\METHODS\0798-19A.M
7/31/98 6:22:19 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19.M
8/3/98 11:06:31 AM by bgp
15
15
1
FID1 A, (0798-19B\015F1S01.D) i
i counts _j SI ?f
: 5i g
-i | [ j
1 6000 -
1 4000 -
12000^ i
10000-J
J
' 8000^ |
1 6000 - T
0)
N
: *O 5f
I- HO.
i . ii
1 - toco ! ; CO h* O ^W"
or*- ' to o ^- on
4000- ^ ; ^ * & l£
I
I
i
I
co
I n
\ t~- 00
S/^x1 - — • — ;
J^
0 5 10 15 20 mm
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FIDl A,
Signal
8/3/98 11:04:16 AM
1.0000
1.0000
RetTime
[min]
1.473
5.409
7 .407
9.194
9.354
9.474
10.097
10.393
Type
PB
PB
PV
VB
Area
count s*s
i
709.56940
-
1227.05225
2357.92407
869.63312
-
Amt/Area
_
9.19566e-4
-
8.30843e-4
8.289516-4
8.36380e-4
-
Amount G
[ug/kg]
6.524966-1
-
1.01949
1.95460
7.273436-1
-
rp Name
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals :
4.35393
Results obtained with enhanced integrator!
2 Warnings or Errors :
Warning : Calibration warnings (see calibration table listing)
Warning : Calibrated compound(s) not found
Mr
slier 8/3/98 11:12:15 AM bgp
Page 1 of 2
36
-------
Data File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19B\015F1502.D T-M18-R4 Aa+AbFH
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
8/1/98 1:03:42 AM
T-M18-R4 Aa+AbFH
bgp
Seq.
Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19A.S
E:\HPCHEM\TELLER\METHODS\0798-19A.M
7/31/98 6:22:19 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19.M
8/3/98 11:06:31 AM by bgp
15
15
2
; FID1 A, (0798-1 9B\015F1502.D)
'• counts jj
-------
ata File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19B\016F1601.D ' T-M18-R4 AbBH
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
8/1/98 1:34:00 AM
T-M18-R4 AbBH
bgp
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19A.S
E:\HPCHEM\TELLER\METHODS\0798-19A.M
7/31/98 6:22:19 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19.M
8/3/98 11:06:31 AM by bgp
16
16
1
FID1 A, (0798-1 9B\016F1 601. D)
counts j !
'
1 c
180CKH
. d .
• -1600
-------
Data File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19B\016F1602'.D T-M18-R4 AbBH
Injection Date : 8/1/98 2:04:14 AM
Sample ,.N_ame . : . T-M18-R4 AbBH
Acq. _6p.erat;or'"'_"".V.'. bgp '.-'; ~i.~
Seq. Line : 16
Vial : 16
Last1' chaiigjdo - : 7'^7;3J^9a7-6T2X^ >""~V"'"' : "-":"
^ .:' -,.y
j ,v^-:i::-:~-F}0i>a'^£p798^
' counts jj S
18000-4 ' -
J " 1
16000-1
1
14000-
i i
12000H
j !
10000-
• 8000 - c
(0
...i «.
6000 J
j TT^- i
4000-^ ^
3! ' ' • -
- - . • ' ... 7- • .'--". ...-._.:
I
i
§
1 1
4- -- , - J. . . ..If. - - -
* - -• ^~-- ^_ -- UQ^
U3 CO 00 "HD
LO N- oo cm
2 .----.. ' 1
'• - •- •-/•-... -
;
i
I
i
. -.--.^-^-^— -
Js
0 5 10 15 20 mini
External Standard. Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FIDl A,
Signal
8/3/98 11:04:16 AM
1.0000
1.0000
R.etTime
[min]
1.474
5.409
7.403
9.191
9.350
9.474
10.097
10".393
Type
BB
PB
PV
VB
Area
counts* s
i
728.30017
-
1341.05078
2270.17700
879.62396
- •
Amt/Area
9.195666-4
-
8.308436-4
8.289516-4
8.363806-4
Amount G
[ug/kg]
6.697206-1
-
1.11420
1.88187
7.356996-1
-
rp Name
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals
4.40149
Results obtained with enhanced integrator!
2 Warnings or Errors :
Warning : Calibration warnings (see calibration table listing)
Warning : Calibrated 'compound '(s) hot" "found ..... ~ ......... .'
Teller 8/3/98 11:12:49 AM bgp
O.Q
Page 1 of 2
-------
ata File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19B\017F1701.D T-M18-R1 Ba+BbFH
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
8/1/98 2:34:28 AM
T-M18-R1 Ba+BbFH
bgp
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19A.S
E:\HPCHEM\TELLER\METHODS\0798-19A.M
7/31/98 6:22:19 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19.M
8/3/98 11:06:31 AM by bgp
17
17
1
counts J
FID1 A, (0798-19B\017F1701.D)
v ml
18000-
min
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FID1 A,
External Standard Report
Signal
8/3/98 11:04:16 AM
I'.'OOOO
1.0000
Ret Time
[min]
1.470
5.417
7.399
9.187
9.348
9.485
10.108
10.404
Type
W
VB
VB
BV
W
VP
W
VB
Area
counts^s
5.88468e4
5.56530e4
-5-. 8469664-
6.78597e4
5.8844364
5.7249164
6.0716064
5.1070364
Amt/Area
i
8.937466-4
8.014506-4
7 ,.8 55726 --4.
7.781586-4
7.872416-4
7.846126-4
8.509226-4
7.610066-4
Amount Grj
[ug/kg]
i
52.59406
44.60306
. -45% 93208 • •
52.80560
46.32461
44.91835
51.66459
38.86480
D- Name
Hexane
Benzene
-Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cutnene
o-Xylene
Totals :
377.70714
Results obtained with enhanced integrator!
l Warnings or Errors :
Warning : Calibration warnings (see calibration table listing)
*1
Her 8/3/98 11:13:03 AM bgp
40
Page 1 of 2
-------
Data File E:\HPCHEM\YELLER\DATA\i998\JUL98^^ T-M18-R1 Ba+BbFH
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed-
Analysis Method
Last changed
8/1/98 3;04.:-35-AM
T-M18-R1 Ba+BbFH
Seq. -Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19A.S
E:\HPCHEM\TELLER\METHODS\0798-19A.M
7/31/98 6:2"2:.l? PM.-bylbgp . . .
E : \HPCHEM\TELLER\METHODS\0-798-19 .M
S/3/9& 11:06:31 AM by
17
17
2
20
min
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FIDl A,
Signal
8/3/98 11:04:16 AM
1.0000
1.0000
Ret Time
[min]
1.469
5.416
7.400
9.188
9.349
9.486
10.110
10.405
Type
W
VB
VB
BV
W
VP
W
W
Area
count s*s
5.87134e4
5. 6316364
5. 87247e4
6.83843e4
5. 92682e4
5.7645664
6. 2623664
5.4297464
Amt/Area
_ i
8.93755e-4
8.01356e-4
7.85534e-4
7.780966-4
7.871756-4
7.84545e-4
8.507066-4
7.603416-4
Amount
[ug/kg]
52.47540
45.12944
46.13026
53.20955
46.65442
45.22555
53.27430
41.28451
Grp Name
_ i _ _ _
1
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals :
383.38342
Results obtained with enhanced integrator!
1 Warnings or Errors :
Warning : Calibration warnings (see calibration table listing)
41
Teller 8/3/98 11:13:18 AM bgp
Page 1 of 2
-------
File • E : XHPCHEMVTELLERVDATAVl^gSXJUL98\Q.798-1_9B\01"8F1.8'01".-D
Injection "Date
Sample Name
Acq. Operator
Sequence FiTe~r"
Acq. Method
Last changed
Analysis Method
Last changed
T-M18-R1 BbBH
8:/l798 - 3 : 3-4^.4 0 AM
T-M18--Rl'BbBH
Vial
18
18
1
---.••_. .:-;f. •-. - .- • • ,-v-.•.---?:-,:In-jM-Volume
'lE7\"HPCHEM\"TELLER\7SEQUENGEV07F8~r9ATS
E: \HPCHEM\TELLER\METHODS\0.7-98-19A.M
7/3i/98 6:22:19 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19.M
8/3/98 11;06.-31 AM by bgp
- t- 2
FID1 A, (0798-19B\018F1801 .D)
counts J J5J
r
18000-!--=-— ..-
16000 -j
14000-j
12000-
10000^)
8000-]
i
6000 H
' - J *
- --) o S
4000 rj ^ |
6
V
1 »
i-,-.~,^-.^v--- _,.-., -.-.-- :- ,..-... '
j
' - '-
\
- 1'-
j - " 7 -«_,-—-=_ r. ; - , - '7 , - , -$- - r - ' -. , .._-
^. .... ._....
Area
count s*s
i _
1
1245\60'657
2939.87476
1138.29846
. ™- . . ' .
Amt/Area
._
8-308-43e--4
8.289'51e-4
8.36380e-4
... - -.-.. - -
Amount Grj
[ug/kg]
|__
" l"-OJ490 -
2.43701
9.52050e-l
. -_.- ---,..: -. • •- .
3 Name
Benzene
Toluene
Ethylberizene
p-Xylene
m-Xylene
Cumene
o-Xylese
Totals :
,2 Darnings. or^BLcrp^s,..:
4.42397
^d^integrat:oEl7::;'--7::-'~r.:
.Warning. : Ca'i-;i^.r%ti.pn^wa;in$;igs -{see , -c^libra.tiori; -tabl..e,'
Warning : Calibr"a""tred~rcompouhd { s) " not 'found' ": '-""-'•;• • '
;llerr
42
r-
-------
Data-File E:\HPCHEM\TELLER\DATA\19-98\JUL98\0798-19B\018F1802.D T-M18-R1 BbBH
Injection Date
Sample Name
Acq. Operator
S equencer~Fil:e
Acq. Method
Last changed
'Airalysls~Me"thod-
Last changed
8/1/98 4:04:48 AM
T-M18-R1 BbBH
bgp
Seq. Line
Vial
Inj
Inj Volume
~:-En:\HP.CHEM\TELLER\-SEQUENeE\ 07 9 8 -19 A. S-
E:\HPCHEM\TELLER\METHODS\0798-19A.M
. 7/31/98' 6:22:19 PM~ by'bgp. '..-.- :: " - -
8/3/98 11:06:31 AM by bgp
18
18
2-
F1D1 A, (0798-19B\018F1802.D)
counts J 5)l
18000H
-I
16000J,
14000^
12000^
1
10000-1
8000-^
6000-
m
o
4000H
V "
N- 00 09)
10
15
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FID1 A,
Signal
8/3/98 11:04:16 AM
1.0000
1.0000
RetTime
[min]
1.467
5.409
7.400
9.186
9.346
9.474
10.097
10.393
Type
PB
PV
VB
Area
count s*s
_
-
1220.44141
2931.23804
1124.07080
-
-
-
Amt/Area
_
-
8.308436-4
8.289516-4
8.363806-4
-
-
-
Amount G
[ug/kg]
_
-
1.01400
2.42985
9.40150e-l
-
-
-
rp Name
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals
4.38400
Results obtained with enhanced integrator!
2 Warnings or Errors :
Warning
Warning
Calibration warnings (see calibration table listing)
Calibrated compound(s) not found
Teller 8/3/98 11:13:42 AM bqp
43
Page 1 of 2
-------
Data File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19B\019F2101.D T-M18-R2 Ba+BbFH
Injection Date
Sample Name
Acq. Operator
Acq. Method
Last changed
Analysis Method
Last changed
8/2/98 10:24:30 AM
T-M18-R2 Ba+BbFH
bgp
FIDl A, (0798-19B\019F2101.D)
0
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\METKODS\0798-19A.M
7/31/98 6:22:19 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19.M
8/11/98 9:42:26 AM by bgp
21
19
1
IV V
40000 -
30000 -
20000 -
10000 -
0-
SOO (^ i
•t O'
i «
10
15
20
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FIDl A,
Signal
8/11/98 9:38:54 AM
1.0000
1.0000
RetTime
[min]
1.429
5.317
7.298
9.088
9.250
9.386
10.014
10.309
Type
W
VB
VB
BV
W
VP
W
W
Area
counts*s
7.50164e4
7. 26226e4
7.87055e4
8.88007e4
7.50438e4
7. 3356264
7. 7420964
6.99144e4
Amt/Area
8.92873e-4
7.99597e-4
7.83355e-4
7.762506-4
7.85246e-4
7.824736-4
8.493916-4
7.57989e-4
Amount
[ug/kg]
66.98010
58.06878
61.65435
68.93154
58.92786
57.39930
65.76061
52.99430
Grp Name
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals :
490.71684
Results obtained with enhanced integrator!
1 Warnings or Errors :
Warning : Calibration warnings (see calibration table listing)
'eller 8/26/98 10:02:17 AM dmb
========== 44
Page 1 of 1
-------
Data File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19B\019F2102.D T-M18-R2 Ba+BbFH
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
8/2/98 10:54:06 AM
T-M18-R2 Ba+BbFH
bgp
Seq.
FID1 A, (0798-19B\019F2102.D)
Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19A.S
E:\HPCHEM\TELLER\METHODS\0798-19A.M
7/31/98 6:22:19 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19.M
8/3/98 11:06:31 AM by bgp
21
19
2
counts 1
nnin
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal l: FIDi A,
Signal
8/3/98 11:04:16 AM
1.0000
1.0000
RetTime
[min]
1.442
5.365
7 .347
9.136
9.297
9.435
10.060
10.355
Type
W
VB
VB
BV
W
VP
VP
VB
Area
count s*s
6. 70176e4
6.4547764
7.2860164
7.8468364
6.6341164
6.4902664
6.6918264
5.8152564
Amt/Area
8.93252e-4
8.00357e-4
7.83869e-4
7.770646-4
7.86197e-4
7.834636-4
8.50265e-4
7.596436-4
Amount
[ug/kg]
59.86363
51,66123
57.11275
60.97490
52.15713
50.84880
56.89816
44.17512
Grp Name
__ 1
1
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals :
433.69173
Results obtained with enhanced integrator!
1 Warnings or Errors :
Warning : Calibration warnings (see calibration table listing)
nt
Teller 8/3/98 11:14:52 AM bgp
t 45
Page 1 of 2
-------
ita File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19B\020F2201.D T-M18-R2 BbBH
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
8/2/98 11:24:01
T-M18-R2 BbBH
bgp
AM
Seq.
Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19A. S
E:\HPCHEM\TELLER\METHODS\0798-19A.M
7/31/98 6:22:19 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19.M
8/3/98 11:06:31 AM by bgp
22
20
1
8000-
6000 -.
4000-
FID1 A, (0798-19B\020F2201.D)
counts _j $|
18000 -i
16000 -
14000-
12000 -
10000-
Hexane
I/) 00
cntn
3
01
§
CD
-v
T-
to
- is-
h~ i*tV»
N- CN rso
CO ^— **O
r^ co cv>
10
15
20
mm
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal
8/3/98 11:04:16 AM
1.0000
1.0000
Signal 1: FID1 A,
RetTime
[min]
1.458
5.409
7 .377
9.167
9.328
9.474
10.097
10.393
Type
PB
BB
BV
VB
Area
count s*s
1105.82886
-
2765.96143
3718.42993
1331.17395
-
Amt/Area
i
1
9.19566e-4
-
8.30843e-4
8.28951e-4
8.36380e-4
-
Amount
[ug/kg]
1.01688
-
2.29808
3.08240
1.11337
-
Grp Name
_ _ i
1
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals :
7.51073
Results obtained with enhanced integrator!
2 Warnings or Errors :
Warning
Warning
Calibration warnings (see calibration table listing)
Calibrated compound(s) not found
Her 8/3/98 11:15:04 AM bgp
46
Page 1 of 2
-------
Data File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19B\020F2202.D T-M18-R2 BbBH
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
8/2/98 11:54:02 AM
T-M18-R2 BbBH
bgp
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19A.S
E:\HPCHEM\TELLER\METHODS\0798-19A.M
7/31/98 6:22:19 PM by bgp
E:\HPCKEM\TELLER\METHODS\0798-19.M
8/3/98 11:06:31 AM by bgp
22
20
2
, FID1 A, (0798-1 9B\020F2202.D)
counts ' $>| '
^ *i !
18000- ; '
;
16000 J
14000^
12000-^
10000^ j, |
] 0) ' ! a. ™
8000- c ' j <= 35
] $ ] 33?
eooo^ x '; ^
- ^^-" fV 00 CO ^O
OCO tO O O) COT
4000- ^ 'r " :: ^2
_, T— •<— Ln n- oo con
0 5 10
External Standard ]
* !
1 i
!
j ;
i
i
I / i
1 5 20 mm
Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FID1 A,
Signal
8/3/98 11:04:16 AM
1.0000
1.0000
RetTime
[min]
1.467
5.409
7.393
9.181
9.343
9.474
10.097
10.393
Type
PB
BB
PV
VB
Area
count s*s
i
1
1047.90112
-
2676.80029
3594.99927
1274.94312
-
Amt/Area
9.19566e-4
-
8.30843e-4
8.28951e-4
8.36380e-4
-
Amount G
[ug/kg]
9.636146-1
-
2.22400
2.98008
1.06634
-
rp Name
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals :
7.23403
Results obtained with enhanced integrator!
2 Warnings or Errors :
Warning
Warning
Calibration warnings (see calibration table listing)
Calibrated compound(s) not found
47
Teller 8/3/98 11:15:17 AM bgp
Page 1 of 2
-------
ata File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19C\021F5501.D T-M18-R3 Ba+BbFH
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
8/6/98 12:31:42 PM
T-M18-R3 Ba+BbFH
bgp
FIDl A, (07y8-19C\021F5501.D)
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19D.S
E:\HPCHEM\TELLER\METHODS\0798-19A.M
8/3/98 3:07:34 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19D.M
8/10/98 4:33:19 PM by bgp
55
21
1
counts -
45000 -;
40000 -
35000 -_
30000 -
25000 -
20000 -
15000 -
10000 -
5000 -
0-_
0
10
15
20
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FIDl A,
Signal
8/10/98 4:32:29 PM
1.0000
1.0000
RetTime
[min]
1.455
5.378
7.361
9.149
9.311
9.448
10.072
10.368
Type
VP
VB
VB
BV
W
VP
VP
VB
Area
count s*s
6.09983e4
6.58453e4
7.08737e4
7.79383e4
6. 95989e4
6.9136664
7.0646564
6.5102364
Amt/Area
i i
1 1
8.479926-4
7.564506-4
7.434146-4
7.379456-4
7.442336-4
7.413616-4
8.065156-4
7.166576-4
Amount
[ug/kg]
51.72605
49.80868
52.68849
57.51419
51.79779
51.25520
56.97750
46.65597
Grp Name
__i _ _
1
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals :
418.42386
Results obtained with enhanced integrator!
1 Warnings or Errors :
Warning : Calibration warnings (see calibration table listing)
4:58:16 PM boo
UL- 48
Paqe 1 of 2
-------
Data File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19C\021F5502.D T-M18-R3 Ba+BbFH
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
S
8/6/98 1:01:37 PM
T-M18-R3 Ba+BbFH
bgp
F1D1 A, (0798-19C\021F5502.D)
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19D.S
E:\HPCHEM\TELLER\METHODS\0798-19A.M
8/3/98 3:'07:34 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19D.M
8/10/98 4:33:19 PM by bgp __
55
21
2
counts ;
45000 -
oo
m
40000 ^
35000 -
30000 - u
52
25000 -] |
20000 -_ 3
^
15000 -
10000 -
tOM
5000 - ^.1'
0 -
0
s
V
1 fl p-
C 3 "*V —i
w ^ ^*Ve CJO
1 £ X ' '
f2 -^6^
w^ m O%^ ^jC
CN p^ ' . — '
7' ; '1 '; '' _ !v
\Q \Q ^y* i ' f*« !**• i i SJS '1 1 1 ® ' 33^ 5\ ^*J S- i' **
5 • 10
15
20
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FID1 A,
Signal
8/10/98 4:32:29 PM
I.0000
1.0000
RetTime Type
[min]
1.460 VP
5.395 VB
7.378 VB
9.167 BV
9.330 W
9.467 VP
10.090 VP
10.386 VB
Area
count s*s
5.97375e4
6.43444e4
6. 92771e4
7.61632e4
6.81792e4
6.74720e4
6.90756e4
6. 36131e4
Amt/Area
8.477356-4
7.562516-4
7.432476-4
7.378156-4
7.44095e-4
7.411966-4
8.063606-4
7.164926-4
Amount Grj
[ug/kg]
i __
50.64158
48.66051
51.49000
56.19438
50.73180
50.00997
55.69978
45.57822
3 Name
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals
409.00625
Results obtained with enhanced integrator!
1 Warnings or Errors :
Warning : Calibration warnings (see calibration table listing)
49
S/o
Paae 1 of 2
-------
ata File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19B\022F2401.D ' T-M18-R3 BbBH
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
8/2/98 1:24:11
T-M18-R3 BbBH
bgp
PM
Seq.
Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19A.S
E:\HPCHEM\TELLER\METHODS\0798-19A.M
7/31/98 6:22:19 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19.M
8/3/98 11:06:31 AM by bgp
24
22
1
FID1 A, (0798-1 9B\022F2401.D)
counts J 5
18000-
!
16000-
i
: 14000 J j
12000-
10000-
-
8000-
*
5000-
in
o '
4000 - ^
I
[' :
i
i
,
4) CO
C > O*
0) CO
c ' ''" ^
C u J^
3 >• ; / ^ ^
t- UJ ! i ^ ^^
CD O O O) ! / ^^
in t~- co O) ^^
0 5 10 15 20 mm
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FID1 A,
Signal
8/3/98 11:04:16 AM
1.0000
1.0000
RetTime Type
[min]
i
1.467
5.409
7.406 BP
9.192 BV
9.338
9 .474
10.097
10.393
Area
count s*s
_
-
1354.67822
1800.91504
-
-
-
-
Amt/Area
_
-
8.30843e-4
8.28951e-4
-
-
-
-
Amount
[ug/kg]
_
-
1.12553
1.49287
-
-
-
-
Grp Name
__ i
1
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals :
2.61840
Results obtained with enhanced integrator!
2 Warnings or Errors :
Warning
Warning
2/1
jller 8/3/98 11:15:53 AM bgp
Calibration warnings (see calibration table listing)
Calibrated compound(s) not found
50
Page 1 of 2
-------
Data File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19B\022F2402.D
T-M18-R3 BbBH
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
8/2/98 1:54:11 PM
T-M18-R3 BbBH
Seq. Line
Vial
inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19A.S
E:\HPCHEM\TELLER\METHODS\0798~19A.M
7/31/98 6:22:19 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19.M
8/3/98 11:06:31 AM by bgp
24
22
2
FID1 A, (0798-1 9B\022F2402.D) !
counts j; N- CO O) ;
T I
i
1
(0 1
co
/^
0 5 10 15 20 mm
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FIDi A,
Signal
8/3/98 11:04:16 AM
1.0000
1.0000
Ret Time Type
[min]
i __
1.467
5.409
7.406 BP
9.193 PV
9.338
9.474
10.097
10.393
Area
counts* s
-
1360.76868
1774.91150
-
Amt/Area
-
8.30843e-4
8.289516-4
-
Amount Grj
[ug/kgj
I
1 --
-
1.13059
1.47131
"
3 Name
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals :
2.60190
Results obtained with enhanced integrator!
2 Warnings or Errors :
III
Warning
Warning
Calibration warnings (see calibration table listing)
Calibrated compound(s) not found
51
Teller 8/3/98 11:16:04 AM bgp
Page l of 2
-------
ata File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19C\023F5601.D T-M18-R4 Ba+BbFH
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
FIDl A, (0798-19C\023F5601.D»
8/6/98 1:31:32 PM Seq. Line
T-M18-R4 Ba+BbFH Vial
bgp Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19D.S
E:\HPCHEM\TELLER\METHODS\0798-19A.M
8/3/98 3:07:34 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19D.M
8/10/98 4:33:19 PM by bgp
56
23
1
counts
45000 -
40000 -
35000 -
30000
25000 -
20000 \
15000 -
10000 -
5000 -
0 -
0
Si
rs
r-
ao
10
15
20
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FIDl A,
Signal
8/10/98 4:32:29 PM
1.0000
1.0000
RetTime
[min]
1.463
5.400
7.385
9.173
9.336
9.472
10.096
10.392
Type
VP
BB
BB
BV
W
VP
BV
VB
Area
counts *s
6.31487e4
6. 7225964
7.15840e4
7.6761164
7.0279464
7.0453464
6.9833464
6. 6617464
Amt/Area
1
j
8.48407e-4
7.566256-4
7.434866-4
7.378606-4
7.44297e-4
7.414866-4
8.064366-4
7.168176-4
Amount G
[ug/kg]
53.57579
50.86477
53.22172
56.63891
52.30871
52.24024
56.31616
47.75247
rp Name
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals :
422.91876
Results obtained with enhanced integrator!
1 Warnings or Errors :
Warning : Calibration warnings (see calibration table listing)
52
3/3
PM
Paqe 1 of 2
-------
Data File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19C\023F5602.D T-M18-R4 Ba+BbFH
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
8/6/98 2:01:34 PM
T-M18-R4 Ba+BbFH
bgp
Seq
F1D1 A, (0798-19002:^561X2.01
Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19D.S
E:\HPCHEM\TELLER\METHODS\0798-19A.M
8/3/98 3:07:34 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19D.M
8/10/98 4:33:19 PM by bgp
56
23
2
40000 -j
35000 ^
30000 -j
25000 -
20000 -
15000
loooo - ;
t
5000 - fli
r-
CO
0
10
15
20
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FID1 A,
Signal
8/10/98 4:32:29 PM
1.0000
1.0000
RetTime
[min]
1.467
5.407
7.391
9.179
9.342
9.478
10.102
10.398
Type
VP
BB
BB
BV
W
VB
BV
VB
Area
count s*s
6.26610e4
6.65805e4
7.0672564
7. 5677564
6.9387364
6.9325564
6.8795464
6.5632364
Amt/Area
8.48315e-4
7.565446-4
7.433946-4
7.377796-4
7.442136-4
7.413796-4
8.063316-4
7.167146-4
Amount
[ug/kg]
_ _ __ __
53.15629
50.37111
52.53748
55.83328
51.63894
51.39647
55.47188
47.03956
Grp Name
1
1
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals :
417.44501
Results obtained with enhanced integrator!
1 Warnings or Errors :
Warning : Calibration warnings (see calibration table listing)
ft/I 0/98 4:58:55 PM bcrp
* 53
Page 1 of 2
-------
ata File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19B\024F2601.D
T-M18-R4 BbBH
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
8/2/98 3:24:19 PM
T-M18-R4 BbBH
bgp
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19A.S
E:\HPCHEM\TELLER\METHODS\0798-19A.M
7/31/98 6:22:19 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19.M
8/3/98 11:06:31 AM by bgp
26
24
1
i FID1 A, (0798-1 9B\024F2601 D)
counts J SI S
18000-^
16000-'
14000-
1 2000 -
10000-^
^i yv
i r
i
! &
8000 ^ , !||
1 • ~O 5)
6000 -J *7 ^
in i co r*- T-T-
O , i O O CCO
4QQQ *- | i ^r CN T«O
i
s
(O
1 ^
//~^_---^
J^
10
1 5
20
mini
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FID1 A,
Signal
8/3/98 11:04:16 AM
1.0000
1.0000
RetTime
[min]
1.467
5.409
7.403
9.191
9.351
9.474
10.097
10.393
Type
BB
PV
VB
Area
counts* s
1 --
1
-
1277.33398
2670.78638
1124.84509
-
Amt/Area
_
-
8.30843e-4
8.28951e-4
8.36380e-4
-
Amount G
[ug/kg]
_
-
1.06126
2.21395
9.407976-1
-
rp Name
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals
4.21601
Results obtained with enhanced integrator!
2 Warnings or Errors :
Warning
Warning
Calibration warnings (see calibration table listing)
Calibrated compound(s) not found
slier 8/3/98 11:1€:41 AM bgp
Page 1 of 2
54
-------
Data File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19B\024F2602.D
T-M18-R4 BbBH
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
8/2/98 3:54:19
T-M18-R4 BbBH
bgp
PM
Seq.
Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19A.S
E:\HPCHEM\TELLER\METHODS\0798-19A.M
7/31/98 6:22:19 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19.M
8/3/98 11:06:31 AM by bgp
26
24
2
i FID1 A, (0798-1 9BV024F2602.D)
j counts j £
I : f
; 18000-
] !
16000-
•
| 14000-1
12000-
| j
: 10000 -^
3000 -"
6000^
' 0
4000- ~
Q
I;
•>
T
i
1
!
i
j
i
§
r-~
x-^ — -- • ~~*
//
0 5 10 15 20 mirt
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FID1 A,
Signal
8/3/98 11:04:16 AM
1.0000
1.0000
RetTime
[min]
1.467
5.409
7.407
9.192
9.353
9.474
10.097
10.393
Type
BB
PV
VB
Area
counts* s
-
1256.14758
2685.15796
1185.61462
-
Amt/Area
-
8.30843e-4
8.289516-4
8.363806-4
-
Amount
[ug/kg]
-
1.04366
2.22586
9.916246-1
-
Grp Name
i
_ j
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals
4.26115
Results obtained with enhanced integrator!
2 Warnings or Errors :
Warning : Calibration warnings (see calibration table listing)
Warning : .Calibrated compound(s) not found
1,11,
Teller 8/3/98 11:16:53 AM bgp
55
Page 1 of 2
-------
ita File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19B\025F2701.D T-M18-FB Aa+AbFH
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
8/2/98 4:24:22 PM
T-M18-FB Aa+AbFH
bgp
Seq.
Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\07 9 8 -19A. S
E:\HPCHEM\TELLER\METHODS\0798-19A.M
7/31/98 6:22:19 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19.M
8/3/98 11:06:31 AM by bgp
27
25
1
; FID1 A, (0798-1 9BV025F2701.D) j
i counts 2. ffi! a
] fl " !
1 8000 -
1 6000 -_
1 4000 -
12000-
1 0000 -
8000 " c
; 6000 -^ T
4000 - *^°
0
i
0)
c
1 Mo °
I
|
I
^jjBJjl ® !
„, ^^^^^flT ^^ '
^^^^^P1" :
'^^P^ !
5 10 15 20 mm
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FID1 A,
Signal
8/3/98 11:04:16 AM
1.0000
1.0000
RetTime
[min]
1.471
5.409
7.404
9.191
9.343
9.492
9.997
10.581
Type
VP
VB
W
W
VP
W
W
Area
counts*s
2770.21680
-
5232.68848
9896.30664
2705 .70215
1177.06531
7023.66455
4097.05811
Amt/Area
_
9.19566e-4
-
8.308436-4
8.255526-4
8.36380e-4
8.350326-4
8.93826e-4
8.102006-4
Amount
[ug/kg]
2 .54740
-
4.34754
8 .16991
2.26299
9.82887e-l
6.27794
3.31943
Grp Name
_ i
1
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals :
27.90811
Results obtained with enhanced integrator!
2 Warnings or Errors :
Warning
Warning
Calibration warnings (see calibration table listing)
Calibrated compound(s) not found
56
Her 8/3/98 11:17:06 AM bgp
Page l of 2
-------
Data File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19B\025F2702.D T-M18-FB Aa+AbFH
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
8/2/98 4:54:30 PM
T-M18-FB Aa+AbFH
bgp
Seq.
Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19A.S
E:\HPCHEM\TELLER\METHODS\0798-19A.M
7/31/98 6:22:19 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19.M
8/3/98 11:06:31 AM by bgp
27
25
2
FID1 A, (0798-19BV025F2702.D)
counts j
18000-j
16000^
14000-
j
12000^
1
10000-
1
8000 -
6000 H
4000 M
on IN ,
TW a >
x™^ CH \
t*~ O con
cocoro
— too-
10
15
20
mm
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FID1 A,
Signal
8/3/98 11:04:16 AM
1.0000
1.0000
Ret Time
[min]
1.469
5.409
7.403
9.191
9.343
9.491
9.998
10.576
Type
W
VB
W
W
VP
VB
BV
Area
counts*s
3660.71289
-
5423 .03467
1.0016764
2701.98755
1219.19104
7002.34375
4210.58203
Amt/Area
j
9.19566e-4
-
8.308436-4
8.24885e-4
8.36380e-4
8.35032e-4
8.93826e-4
8.10200e-4
Amount
[ug/kg]
3.36627
-
4.50569
8.26260
2.25989
1.01806
6.25888
3.41141
Grp Name
i
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylsne
Totals :
29.08280
Results obtained with enhanced integrator!
2 Warnings or Errors :
Warning
Warning
Calibration warnings (see calibration table listing)
Calibrated compound(s) not found
?/&
Teller 8/3/98 11:17:20 AM bgp
Page 1 of 2
57
-------
ita File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19B\026F2801.D
T-M18-FB AbBH
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
8/2/98 5:24:36 PM
T-M18-FB AbBH
bgp
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19A.S
E:\HPCHEM\TELLER\METHODS\0798-19A.M
7/31/98 6:22:19 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19.M
8/3/98 11:06:31 AM by bgp
28
26
1
I FID1 A, (0798-1 9B\026F2801.D)
!
counts uji n i
~ -r- f« I
r f
18000- I
16000- I
14000-
1 2000 ^
1 0000 -
8000-^
6000 -
: 5
4000- ^
i
;
1
v a
a S.
1 £
1- LJJ
O O (7)
•
-------
Data File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19B\026F2802.D
T-M18-FB AbBH
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
8/2/98 5:54:41 PM
T-M18-FB AbBH
Seq. Line
Vial
inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19A.S
E:\HPCHEM\TELLER\METHODS\0798-19A.M
7/31/98 6:22:19 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19.M
8/3/98 11:06:31 AM by bgp
28
26
2
i FID1 A,
counts jj
i
]
18000-]'
: 16000H
14000H
12000-^
10000-3
-i
8000 J
]
6000 -j
•!
4000-^
0
(0798-1 9B\026F2802.D)
S| §
5i f>
1 i n
!
! |
|
i
' CO O) : ! / i
5 10 15 20 min
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FID1 A,
Signal
8/3/98 11:04:16 AM
1.0000
1.0000
RetTime Type
[min]
_ _ i
-- 1
1.467
5.409
7.404 PP
9.190 BV
9.338
9.474
10.097
10.393
Area
count s*s
_
-
1562.13708
1858.57507
-
Amt/Area
i
1
-
8.30843e-4
8.28951e-4
-
Amount Grj
[ug/kg]
_ |__
-
1.29789
1.54067
-
3 Name
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals :
2.83856
Results obtained with enhanced integrator!
2 Warnings or Errors :
Warning
Warning
Calibration warnings (see calibration table listing)
Calibrated compound(s) not found
Teller 8/3/98 11:17:43 AM bgp
59
Page 1 of 2
-------
ata File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19C\027F1101.D T-M18-FB Ba+BbFH
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
8/5/98 12:10:10 AM
T-M18-FB Ba+BbFH
bgp
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19D.S
E:\HPCHEM\TELLER\METHODS\0798-19A.M
8/3/98 3:07:34 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19D.M
8/10/98 4:33:19 PM by bgp
11
27
1
FID I A, (0798-19C\027F1101.D)
counts ;
45000 -
40000 -
._nun
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FID1 A,
Signal
8/10/98 4:32:29 PM
1.0000
1.0000
RetTime
[min]
1.466
5.407
7.390
9.177
9.339
9.476
10.099
10.395
Type
W
VB
VB
BV
W
VP
W
W
Area
counts *s
4. 49669e4
4.01662e4
4. 4970164
5.32726e4
4. 3977464
4. 3394364
5.0934064
4.09096e4
Amt/Area
_ 1
1
8.43649e-4
7.510066-4
7.392486-4
7.353716-4
7.403776-4
7.373996-4
8.038696-4
7.124896-4
Amount Grj
[ug/kg]
1 __
37.93631
30.16502
33 .24408
39.17516
32.55988
31.99887
40.94422
29.14760
3 Name
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals :
275.17115
Results obtained with enhanced integrator!
1 Warnings or Errors :
Warning : Calibration warnings (see calibration table listing)
321
60
Slier 8/10/98 4:39:44 PM bgp
Page 1 of 2
-------
Data File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19C\027F1102.D T-M18-FB Ba+BbFH
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
iffi
rs:
8/5/98 12:40:04 AM
T-M18-FB Ba+BbFH
HDl A, (U798-19C\027F1102.D)
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19D.S
E:\HPCHEM\TELLER\METHODS\0798-19A.M
8/3/98 3:07:34 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19D.M
8/10/98 4:33:19 PM by bgp
11
27
2
counts ;
45000 -:
40000 -
35000 -
30000 -
25000 -
20000 -
15000 -
10000 -
5000 -
«
-------
ata File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19B\028F3001.D
T-M18-FB BbBH
Injection Date
Sample Name
Acq. Operator
Acq. Method.
Last changed
Analysis Method
Last changed
8/2/98 7:24:59 PM
T-M18-FB BbBH
bgp
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\METHODS\0798-19A.M
7/31/98 6:22:19 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19.M
8/3/98 12:19:03 PM by bgp
(modified after loadina)
30
28
1
I F1D1 A, (0798-1 9B\028F3001.D)
I counts j S
| - ^"
17500 -j !
15000^
' 12500- !
10000^ i
J I
'. 7500 ~
5000 -
i
2500 - ]
$
1
!
i
j
8
0)
a
I 1
i t i
1- UJ j '
N CM O | /^
(v! 00 OJ ! i -^
: 0^
0 5 10 15 20 min
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FID1 A,
Signal
8/3/98 11:04:16 AM
1.0000
1.0000
RetTime Ty
[min]
1.467
5.409
7.402 BP
9.190 PB
9.338
9.474
10.097
10.393
pe Area
counts* s
_
_
1089.38684
1195.99377
-
-
-
-
Amt/Area
-
8 .30843e-4
8.289516-4
-
-
-
-
Amount
[ug/kg]
-
9.051106-1
9.91420e-l
-
-
-
-
Grp Name
i
-_ 1 __ _
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
tn-Xylene
Cumene
o-Xylene
Totals
1.89653
Results obtained with enhanced integrator!
2 Warnings or Errors :
Warning
Warning
32$
Her 8/3/98 12:19:04 PM bgp
Calibration warnings (see calibration table listing)
Calibrated compound (s) not found
Page
t 62
1 of 2
-------
Data File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19B\028F3002.D
T-M18-FB BbBH
Injection Date
Sample Name
Acq. Operator
Acq. Method
Last changed
Analysis Method
Last changed
8/2/98 7:55:00 PM
T-M18-FB BbBH
bgp
Seq,
Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\METHODS\0798-19A.M
7/31/98 6:22:19 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19.M
8/3/98 12:19:34 PM by bgp
(modified after loading)
30
28
2
FID1 A, (0798-19B\028F3002.D)
counts j Si
17500-
15000-^
f
8
12500-
10000-
7500 ~ | i
5000- ' i
: Si'
2500- - i '
o^
0
c
V
« s
1
K UJ
n Q o .
O O O) i
i^ oo o) 1
5 10
I
i X
__^ — -^'^
15 20 mm
External Standard Report
Sorted By :
Calib. Data Modified :
Multiplier :
Dilution :
Signal 1: FID1 A,
RetTime Type Area
[min] counts*s
Signal
8/3/98 11:04:16 AM
1.0000
1.0000
Amt/Area
Amount
tug/kg]
Grp
Name
1.467
5.409
7.403 BB
9.190 PB
9.338
9 .474
10.097
10.393
Totals :
1089.69263 8.30843e-4 9.053646-1
1190.57117 8.289516-4 9.86925e-l
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
1.89229
Results obtained with enhanced integrator!
2 Warnings or Errors :
Warning
Warning
Calibration warnings (see calibration table listing)
Calibrated compound(s) not found
63
Teller 8/3/98 12:19:35 PM bgp
Page l of 2
-------
Method: E:\HPCHEM\TELLER\METHODS\0798-19.M of 8/3/98 12:59:48 PM
Calibration Table
Calib. Data Modified
Calculate
Based on
Rel. Reference Window
Abs. Reference Window
Rel. Non-ref. Window
Abs. Non-ref. Window
Uncalibrated Peaks
Partial Calibration
Correct All Ret. Times
Curve Type
Origin
Weight
Recalibration Settings
Average Response
Average Retention Time
8/3/98 11:04:16 AM
External Standard
Peak Area
5.000 %
0.080 min
5.000 %
0.080 min
not reported
Yes, identified peaks are recalibrated
No, only for identified peaks
Linear
Connected
Linear -
Average all calibrations
Floating Average New 75%
Calibration Report Options :
Printout of recalibrations within a sequence:
Calibration Table after Recalibration
Normal Report after Recalibration
If the sequence is done with bracketing:
Results of first cycle (ending previous bracket)
Signal 1: FID1 A,
Ret Time Lvl Amount
[min] Sig [ug/kg]
1 1 __
1 1
1.467 1 1 7.34000
2 16.28000
3 40.60000
4 80.70000
5 198.90000
6 388.00000
5.409 1 1 7.85000
2 17.43000
3 43.40000
4 86.40000
5 213.00000
6 416.00000
7.390 1 1 7.77000
2 17.23000
3 42.90000
4 85.50000
5 210.60000
6 411.00000
9.176 1 1 7.73000
2 17.13000
Area
8639.78955
1.7369664
4 .34487e4
8.96983e4
2.23496e5
4.38292e5
1. 00166e4
2.06058e4
5 .24541e4
1. 0740165
2. 68902e5
5.25387e5
1.00433e4
2.0646764
5.30103e4
1.08566e5
2.7122665
5.3010365
1.0006964
2.0.6647e4
Amt/Area Ref G
__ ]
1
8 .495586-4
9.372706-4
9.34436e-4
8.99683e-4
8 .89948e-4
8.85255e-4
7.83699e-4
8.45876e-4
8.273916-4
8.044626-4
7.921116-4
7.917976-4
7.736496-4
8.34517e-4
8.092776-4
7.87536e-4
7.76475e-4
7.753216-4
7.724706-4
8.28948e-4
rp Name
Hexane
Benzene
Toluene
Ethylbenzene
Teller 8/11/98 9:10:34 AM bgp
64
Page 1 of 2
-------
Method: E:\HPCHEM\TELLER\METHODS\0798-19.Mof 8/3/98 12:59:48 PM
RetTime Lvl Amount Area Amt/Area Ref Grp Name
[min] Sig [ug/kg]
3 42.70000
4 85.00000
5 209.30000
6 409.00000
9.338 1 1 7.79000
2 17.27000
3 43.00000
4 85.70000
5 211.00000
6 412.00000
9.474 1 1 7.74000
2 17.15000
3 42.80000
4 85.10000
5 209.60000
6 409.00000
10.097 1 1 7.70000
2 17.07000
3 42.60000
4 84.70000
5 208.60000
6 407.00000
10.393 1 1 7.67000
2 17.02000
3 42.40000
4 84.40000
5 208.00000
6 406.00000
5.3191464
1. 09014e5
2.7127665
5. 3259965
9969.17383
2.0664264
5.3048764
1.0886365
2.7093165
5 .3073665
9986.18457
2.0583164
5.2702564
1. 0844065
2.6959965
5 .2987865
9340.51563
1. 8820764
4.8270864
9 .9190664
2.46706e5
4 .8435665
1.0155064
2 .1095864
5.4113964
1.1121165
2.76692e5
5.4306765
8.
7.
7.
7.
7.
8.
8.
7.
7.
7.
7.
8.
8.
7.
7.
7 .
8.
9.
8.
8.
8.
8.
7.
8.
7.
7.
7.
7.
I -
02762e-4
797146-4
71540e-4
67932e-4
81409e-4
35745e-4
10577e-4
87227e-4
78795e-4
76281e-4
750716-4
33207e-4
12106e-4
84768e-4
774506-4
718766-4
24366e-4
06980e-4
825206-4
539126-4
455416-4
40291e-4
55295e-4
067956-4
835336-4
589196-4
517376-4
47606e-4
— 1
p-Xylene
m-Xylene
Cumene
o-Xylene
3 Warnings or Errors :
Warning : Overlapping peak time windows at 9.176 min, signal 1
Warning : Overlapping peak time windows at 9.338 min, signal 1
Warning : Overlapping peak time windows at 10.097 min, signal 1
Peak Sum Table
***No Entries in table***
Teller 8/11/98 9:10:34 AM bgp
v 65
Page 2 of 2
-------
ata File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19B\001F0101.D gc-14 pg 53 #1
Injection Date
Sample Name
Acq. Operator
Sequence .File
Acq.- Method
Last"-'.chang~ed. 1 ".•"," •
Last changed'-;-;
7/31/98 1:16:52 PM
gc-14 pg 53 #1
Seq. Line
Vial
.... ... mj
Inj Volume
.E.:.\HPCHEM\TELLER\SEQUBNCE\Q798- 19A. S
1
2 /zl
? by'lgp--
,1 (0798r19a\D01J:010.i;D):
-counts
40000
',]
35000-3
30000 -n
20000 -^
A
- - a
15000 -q
-r
10000 -jj
.- -50QO-
-r -
0
$
X
8 J
r -A - ,
2
-
--
• - - ''-'a
§•" g-g "
0) -3?
P ^*
0 0
-CD *— - - . U4flfc . ( (
..'.,.-. J.-4 ..... ! ..§ . -1.-11
— — — — i--- ' t^_- - ^UV^Y — _. ^ „_ , -/v~ i® • *"- — iA/^\ iArA" -'" — - -
j. ... . _^_w _ --t^-^r-i-_ _'-_." - -_ -: /-/-.- ' ;-.r^;:.- -" -V--..- .„.-'---:•---"*"'' r- -'.->-"---- -
I . - j ' ' ' * ' ' ' !. i
- 4 .6 8 10 12 min
External Standard Report
Sorted By
Calib. Data Modified
Multiplier .. .
Dilution
Signal 1: FID1 A,
Signal
8/3/98 10:05:25 AM
1.. 00.00. ..
1.0000
RetTime
[min]
1.471
5.411
7.393
9'. 179
9.339
9.475-
..10-. 099
"10-.39-5-
Totals
Type
BP
VP
BP
BV
W •
VB
-BP- - -.
Area
counts* s
8623.16504
1.0003364
9968.09863
99SO'."8'0371
-9940.78320'
-9984.4990-2
- 9,14 6-^9 2:8,7-l-
: — :_.
Amt/Area
-_i
9.1-73456-4
8.376366-4
8.275126-4
8'.25248e-4
•8.326986-4 -
;8V3a7'21e-4----
-8":-<56lCFle-4: "'
'"-
Amount G
[ug/kg]
7.91041
8.3-7917
8.24872
8.21188
8. -27767
8 v 2943 3' :
"-•- 8:18685-.:
.65 ..£5820
rp Name .
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m--Xylene —
--Gum.ene,.^ — -- - -
_ .
Results obtained--with enhanced integrator! . -
1 Warnings.or. Error,? ;„.. _ _ •
Warning : Calibration warnings (see calibration table listing)
29- ;- - : " "-" - -- " ""
Her 8/3/98 10:23:26 AM bgp
w ^ 66
Page 1 of 2
-------
Data File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19B\001F0102.D
gc-14 pg 53 #1
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
7/31/98 1:34:08 PM
gc-14 pg 53 #1
bgp
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19A.S
E:\HPCHEM\TELLER\METHODS\0798-19B.M
7/31/98 1:13:37 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19.M
8/3/98 10:23:06 AM by bgp
1
1
2
| FID1
counts 1
1
1
40000 H
1
35000 -3
q
30000 -,
3
25000 -5
j
20000^
15000 J
^
10000 J
5000 ^
T
o "i
i 0
====.=%="=_=
A, (0798-1 9B\001F01 02. D)
c
§"' g c
if
m - K UJOt
S^'\1--,:- -.
Ca'liH ^^^ta^^Q^ff iff^i^^-t^^^^^f 6ff|:; 255^^^eit:U->^::i-
L^fci^^^^^^^l^^^^^
,--•-'-" 5" - -" -""•*•. ^^o-Ti - V.."---1- ^i-.-.----^-.-^'.-."' llrcr/?*-!^--*— : Ij^-c .-":.-.- .".'•-."„ _ .-< ".','^Z-'-e-^i-.' -.,."" *"--,"- ------ "*•-"
L^QH3.jL""-'J"!Ql"Z1'--"'E^I^il^-• A:J"-""*" "^""^-^jj**—"^--*;r?=j.-r- ™-~." _*vV'- -- "V' f-'—****^^:""*'*'4*-0*"'"--- -^T~*"V -— -{ -:--- "''"^
RetTime- "-Type; •. --': ''Area;-V ^->AmE/fAr'ea--;' "•"-".jSnoun£-.~"":-^rp.; --^Nathe-'-"""-.
[min]: ". "' " 'c6unts*s; • -"-"-•"--" •- - - . Tug/kg]- - : "
.-— ,i - - t .. . - . . _ i. -~~ -^ ^~ ^ ~ \- • ', ,:... - ~ ." " 7*" ~ j *
5.-412 -VB - - 1. Q0299e4 '-8 .3-7520e-4 ---8\ 4002-1- - Benzene'-'•
7 .392 "BP v-,-...,. ,,l-C^3g:8_5Je4i...8'-.,2§76te.-4" . ..a.3:-6559 .... ^rbluene
9 .,178; BV '• - ^l-T^Ogei^eil.;,. 8; 24:6.33e^4;;:. .^cS:429t8?52;:•: '^ "Ethylbeiizene,
~' " " ' " :8-; 32 if8-5; •'.-. :"p-^(yiene - :
:.----8-v2-969:S •'v-:-m^T?T6nfe;"'. '
",'".".. .-Cuineiie'"""'. :'
-__ ; p-Xylene
9.338 --VV
9.476 VP '
10 .'.69S.":BB'. •_;:: :'9.5V3:4-.-.:
10 .'393 BB" 1: 0153'8-e4 8'.
Totals :
66...2 83 82..
Results obtained with' enhanced integrator!
1 Warnings or Errors- :
Warning : Calibration warnings (see calibration table listing)
Teller 8/3/98 10:23:40 AM bgp
Page
67
1 of 2
-------
ita File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19B\002F0201?D gc-14 pg 53 #2
Injection Date
Sample Name
Acq. Operator
Sequence .File
Acq. Method
Last changed
Analysis- Method"
Last changed
7/31/98 1:51:15 PM
-gc-14 pg 53 #2
bgp
Seq.
- ]; . „ ~ _, -—.A -•- 3
Line
-Vial
. -M
2
2
1
E
. :
E:\HPCHEM\TELLER\METHODS\0798-19B.M
7-/31/-98 1:13:37 PM by bgp -. - .-. .
E": \HPCHEM\-TELLER\METHODS\0798-iaiM "
8/3/98 10:23:06 AM by bgp
- - ' FID1 A; (0798-1 9B\002F0201-.DF _"-"_-- " ' " ; ', ~:~'. ''.
counts 1 S • - - - •
1 ;
3
40000-
J
35000-
3
i
I
30000 -j ~ 1
25000 -
j
20000^ §
3 X
15000^ T
10000-j |
5000^ ° A
,
i
a) ^
2 2 Jlf S-l
| | §§"- |^
CD *— - , • '
. . .1 iS % | ?/5?._.-f.?- - i
1 .•» «A .A .«• ,/VY\ A.A i
o J '
0 2 4 6 8 10 12 mm
External Standard Report
Sorted By
Cal ibT "Dat'a
Multijplier
Dilution
Signal
" 10": 05 :-
1.0000
i";dob"o
Signal 1: FID1 A,
RetT-ime
[min]
1.469
5.411
7.391
9.177
9.338
9.474
.io.-o.aa:
10.393
•Type
BB
VB'
BP
BV
W
VB
-BV- ;.- .
VB
Area - -
count s*s
1. 7400864 -.
2.0653564
2.07118e4
2.0749164
2.0743364
2.' 062 5 7 64
^1-:8946S64..:
2.1210964
Amt/Area
9-, 0-3397e-4-
8:l4888e-4
8.012856-4
7.965306-4
8.042136-4
8.019.076-4
ra...6.6561e-4
7:767646-4
Amount Grp - Name
[ug/kg]
• 15.7198.0 ,
16.83"026"
16.59603
16.52731
16.68206
16. 53 988
- 1.6 v 4-1:8.6 8 -:-
16.47584
- --Hexane- -
""'Benzene
Toluene ~"
Ethylbenzene
p-Xylene_
m-Xylene
-..-Cumene- " — . . .
o-Xylene
Totals :
131.78985
Results obtained with enhanced integrator!
1 .Warnings or Errors. :
-------
Data File E:\HPCHEM\TELt,ER\DATA\1998\JUL98\0798-i9B\0'02F0202 .D gc-14 pg 53 #2
Injection Date
Sample* Name " -
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis --/Method;
Last-changed
Seq." Line
7/31/_?8 2:08:35 PM
"gc-14" pg- -53 • • #2'~ "•• "
bgp Inj
•". . . .. • ... : •-.---_-."- Inj. Volume
E: \HPCHEM\TELLER\SEQUENCE\0798-19A.-S
E: \HECHEM\TELLER\METHOpS\0798-I9B~.M
7/31/98. 1:13: 37..PJSfl ..by bgp". ~. - - -
: E • VHPCHEM-XTELLER-VMET^.ODS\o 798:-i9-<&V-,,.. :
lQ.;-23-': 06- AM-:by..-bgp'•-.
2_
"• 2 "
2
: All
, FID1 A; ;(0798r19B\Oi
counts, J '-.-{g
- JJ : '1
3
40000-3 ' " '
35000^
30000 -5
^
25000 ^
20000-3 §
15000 J x
-| *
10000^ |
sooo-^ r ;\
4
)2R3202;D)c,;..i.,.:- .-.;• ; - .-...--_.- -.._ . :..---.':, - -~.~.:~^r:...-: .~: . .,
-*---- - - ">>* . * -- ', - >-•..--*- - ,v*i -.-'—,-.-- r- --• - . > . t. .—
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. ':/,": S'^lvTSS.- -lOrdS-: 25 -.AM
- .--i:rOt).a6"^-:- :-- --"—--
Ret Time
[min]
1.469
5.410
7.390
9.175
9.336
9.473
10.096
10.392
Type
BB
VP
BP
BV
W
VB
BV
VB
Area
counts*s
1.7338464
2.05582e4
2.0581664
2.0580364
2.0585064
2.0540664
1.86945e4
2.0980764
Amt/Area
9.034466-4
8.14987e-4
8.01439e-4
7.96747e-4
8.044156-4
8.02019e-4
8.66868e-4
7.770606-4
Amount G
[ug/kg]
15.6&431
16.75467
16.49489
16.39734
16.55891
16.47392
16.20564
16.30329
rp Name
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals :
130.85297
Results obtained with enhanced integrator!
1 Warnings or Errors :
Warning : Calibration warnings (see calibration table listing)
>o
Teller 8/3/98 10:24:04 AM bgp
69
Page 1 of 2
-------
ita File .-E:\HPCHEM\TELLER\DATA\1998\JUL9.8'\07-98-i9BV003F0301-.D - gc-14 -.pg 53 #3
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis ""Method
Last changed
: 7/31/98 2:25:44 "PM
-gc-14 'pg 53' '#3
bgp
.'" . .'..S.eq. Line
-'• \Vlal-
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19A.S
E:\HPCHEM\TELLER\METHODS\0798-19B.M
7/31/-98 -l:-13r37 PM -by bgp.
E: \HPCHEM\TELLER\METHODS\079 8-" 19': M
8/3"/98 10:23":06- AM"by
3
— -3 -
1
2 fJLl
FID1 A, (0798-19B\003F0301.D)
counts
40000-
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35000 -? - • -
30000 -^
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15000^ ' y
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[min'] "~"~" ". counts*s"
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8/3/98 -10:05:25 AM
-1.0000 - -- -.
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""" " [.ug/kgj -
-1.469
5.411
7.-391-
9:177
9.339
9.474
10.099
10.393
.BB
VB
BB
BV
W
VP
BV
VP
4.. 344.5764......
"5 .2454164
•5 . '3 &tO'"3je3 : "- ±.
"5.3191464
5.3048764
5.2702564
4.8270864
5.4113964
--8.-..95182e--;4-
8.019336-4
'7-V8, 6i4 59"e .-4"'
"7'."-8b:396e^4
7.882506-4
7.85452e-4
8.527516-4
7.60376.6-4
•3--8--. &9#4.7 - '
4'2." 06467
- 4.±"V- 63-04"! - -"-
" 4-l!5.a9-99
41.81562
41.39529
41.16300
...4,1.14692
" /Hexane-..-
•Benzene
-- "T.Q'iyeiie- -
Ethyiberiz ene
p-Xylene
m-Xylene
Cumene
.o-Xylene
Totals :
329.68038
Results obtained with enhanced integrator!
1 Warnings or Errors :
Warning : Calibration warnings (see calibration table listing)
.'Her 8/3/98 10:24:17 AM bgp
79
Page 1 of 2
-------
Data File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19B\003F0302.D gc-14 pg' 53
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
7/31/98 2:42:56 PM
gc-14 pg 53 #3
bgp
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19A.S
E:\HPCHEM\TELLER\METHODS\0798-19B . M
7/31/98 1:13:37 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19.M
8/3/98 10:23:06 AM by bgp
3
3
2
2 ul
FID1 A, (0798-19B\Q03F0302.D)
External Standard -Report
Sorted .By.. . . :
Calib. Data Modified :
Multiplier :
Dilution .. ....:.
Signal 1: FIDl A, ' " •
Ret-Xime .Typ_e. ..- _ Are.a__
[min] counts*s
Signal
8/3/98 10:05:25 AM
1.0000
1..0000 .. _._
. Amt./Ar.e.a Amount Grp___Jt!ame_
[ug/kg.]
1.469 BP
5 ."413 VP
7.3'93-BB
9.1773V
9.339 W
9...47.5.VP
10.098 BV
10.394 VB
Totals. ..:. ., ... r
4.34285e4
•5T 2473464
5.32-15864
5,31714.64
4.8393464
5-. 4316564
-.: --:,.-• .- .-
' 1 -
8
' "8
7
~j
' "7
8
-. 7
..951846-4
.019306-4'
;86423e-4
;80369e-4
.88227e-4
,,85:3-966-4
.527286-4
.603376-4
,1
.r I --
38-..S-7648
. ' -4-2.08.000
-41-r&5QT3-' '- - -
:41V5904T ' '
4~1 ..9111.0 - .
41.26639
- - 41.298.83 .
3-3 Q. 48-920V .-•
Hexane
Benzene
•To'1-uene - -
. Ethylben'zene
-p-.Xyl.ene
m---Xy-lene
Cumene
o-Xylene
-
Results-- obtained--with"- •enhanced- integrator ,tr-
1 Warnings..or.Errors.:.. . .
Warning : Calibration warnings (see calibration table listing)
71
Teller 8/3/98 10:24:28 AM"bgp
Page 1 of 2
-------
ita
Inj
SampTe^Name
-Acq: Operator. -
Sequence-"File
Acq. Method
Last changed
Analysis Method
Last - changed
."--.:. :v±al
- Inj.
Inj -Volume
E-ft-HPCHEM-\TELLER\-SEQUENCE\:0798;-19A:\S-'- •
E:\HPCHEM\TELLER\METHODS\0798-19B.M
7/31/98" I.: 13-: 37 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19.M
8 Z3-./9&.10:^43:0.6-.AR
:,.:-.-4.
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45000 -3
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R_. '• -^-.,.
•f-3^--- ^:V""":^§^^-""-~J-:>:^'-T'-='"^ •^'^rr^j^'-" •- ^ - -"•-"••-'•
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1 • - ' -I.
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-- - -. — -=--.. TT-,--— — **,.-?-.*-_-,-- _--=r-^- -,'.TZ**'*-^^;*r—-*- -jaafrv. .-,Ti7A.— - TX •- ar-^-*;-*!.— ^i,. ^rr: :->.-.-.:-, .T7rT-^.-«c^-i^_- ^~ -r^«^;r^',Tw^;-^r.v -,- - ' ^--r
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Signal- 1: "FIDl'Ay- - " '
~'-.'VSignal..-:'." '.:•" "•".. ~"""'' " " "'- ~:~--•---•- -
3--10:-0-5:-25---"-;
1.0000
RetTime
[min]
5.410
7 .-391
9.177
9.338
9.474
10.097
10.393
Type
VB" "-'
VP
BB
BV
W
VB
BV
VF -
Area
count s*s
«.99227e4 -
1.07524e5
1.08752e5
1.0926765
1-.-0917865
1.0864365
"9.94"233e4 '
1"* "1**1* A.'Q £+."£* C ""
•• ^L^L^c O D C* J
Amt/Area
8.1.923466-4--
7.97624e-4
7". 8r586e-4'
7.75092e-4
7.829816-4-
7.800046-4
'8.."4'816"Oe-4"
Amount
[ug/kg]
-"--"'SO". 2 421-5
85.76399
' 84.99874
84.69234
" '"85.48429
84; 74167
' ' "8-473-2 "6"87
~8'4M-655T
Grp Name
i __ I
LI.
"•'-" Hexarie" "
Benzene
Toluene
Ethylbenzene
• --p-Xyl'ene
m--Xylene
Cumeiie" ""
' b-Xylene - - •
••
Results obtained' -vith-' enhanced integrator! ." . " .
1 Warnings or Errors : "
Warning.: -Calibration warnings (see calibration table. listing)
ller._8"./3/9'a
:._P.age._l of 2
-------
Data File Er\HPCHEM\TELCTR\.DATA\1998\JUL98\Q798-lr9B\004F0402 .D gc-14 -pg 53 #4
Injection Date
Sample Name
Acq-.- Operator .-
Sequence'File
Acq. Methqd_
Last changed
Analysis"
Last changed
;Seq.. Line
.7/31/98 -3 r 17: 32' PM
•gc-14"pg- 53 #4
bgpi.--..
- - ' ... - -. In j"". Volume
E:\HPCHEM\TELLER\SEQUENCEV.O-798-19A~ S~ . '-
E: \HPCHEM\TELLER\METHODS.\0798-19B .M
-7/31/98.-. 1:13 iJT.'PM by bgp " :
---ET\HPCHEM\TELLER\METHQDS\Q7?8-i9;M " "-•
8/3/98''10:23: 06 "AM" by bgp --•'•'•
4
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Dilution - .:-.'_'-'
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-Siohal
N 25i:-AM
_
-ivbooo-
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I thin]
1.469 BP
5. '410 VB
7.390 BB
9.176 BV
9.337 W
9.474 VP
10.097 BV . -
10';. 3 93 VP
T»«-fc-'^-l -,-,--—•_ ^- - ----- -•
Area. .
coun'ts'^s" '
8. 9473864
1.0727865
1.0838165
T.O §76165
1.0854865
1.0823765
_1..109;35e5.;.-
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8.92359e-4
7.976346-4
7.816026-4
7.751156-4
7.830106-4
7". 800246-4
8,481816-4
;7; 549656-4
- -__ :-—---
Amount. . G
-[.ugyHS-I
79.84274
85 ."56836
84.71110
84.30"238 "
84.99421
84.42718
83.93411....
"".::83.r7_52"-19-_"
-- . :.„„ — ^..\,
rp . Name
- - -- I.-: - -
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
-Cumene
--; cx^Xylene-
.. ;.. — .^ .-..-.. ....
"Results 'obtained^'witli""enhanced integrator! ---••- . -' - '-' -
1 Warnings or-Errors : _.- -- .......
Warning. : Calibration;warnings (see calibration--table listing)
8/3/98 10:24:51
73
Page 1 of 2
-------
.ta - File. E.:AHP-GHEM\rTELLE|L\LDATA\ 19.9^ \JUL9 &\Q333-3.9B\Q p5ExL i ne-
Vial
Inj
Inj- -Volume-
.E,:-\HPCHEM\T-ELLER\SEQUENGE-\a798-19A,-S ---
E:\HPCHEM\TELLER\METHODS\0798-19B.M
7/31/98.1:13:37 PM by- bgp '
E:\HPCHEM\TELLER\METHODS\0798-19.M
8/3/98 10:23:06 AM "by 5gp ' '
•5
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50000 -| "I
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Her
V"-'v.'-"-"-Xv...; w.::i-Pa9;e 1 of 2
-------
Data File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19B\005F0502.D gc-14 pg 53 #5
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
7/31/98 3:52:06
gc-14 pg 53 #5
bgp
PM Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19A.S
E:\HPCHEM\TELLER\METHODS\0798-19B.M
7/31/98 1:13:37 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19.M
8-/3/9S 10:23:06 AM by bgp
5
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50000-
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-------
ata File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19B\006F0601.D gc-14 pg 53 #6
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
7/31/98 4:09:19 PM
gc-14 pg 53 #6
bgp
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19A.S
E:\HPCHEM\TELLER\METHODS\0798-19B.M
7/31/98 1:13:37 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19.M
8/3/98 10:23:06 AM by bgp
6
6
1
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counts -| ™
1 00000 J 1
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Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FID1 A,
Signal
8/3/98 10:05:25 AM
1.0000
1.0000
RetTime
[min]
1.467
5.409-
7.391
9.176
9.339
9.475
10.098
10.394
Type
VB
VP
BB
BV
W
VB
BV
VP
Area
count s*s
4.37921e5
5. 2582865
5.3119865
5.3378665
5.3220465
5.3108765
4.8556865
5.4439865
Amt/Area
8.90239e-4
7.94359e-4
7.77901e-4
7.710956-4
7.790226-4
7.75922e-4
8.447156-4
7.508626-4
Amount
[ug/kg]
389.85419
417,69611
413 .21948
411 .-60028^
414.59880
412.08225
410.16667
408:76811
Grp . Name
_ i
-- 1
Hexane
- Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals :
3277.98588
Results obtained with enhanced integrator!
1 Warnings or Errors :
Warning : Calibration warnings (see calibration table listing)
76
slier 8/3/98 10:25:24 AM bgp
Page 1 of 2
-------
Data File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19B\006F0602.D gc-14 pg 53 #6
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
7/31/98 4:26:32 PM
gc-14 pg 53 #6
bgp
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19A.S
E:\HPCHEM\TELLER\METHODS\0798-19B.M
7/31/98 1:13:37 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19.M--
8/3/98 10:23:06 AM by bgp
6
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-------
ata File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19B\007F0701.D gc-14 pg 53 #7
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
7/31/98 4:43:39 PM
gc-14 pg 53 #7
bgp
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19A.S
E:\HPCHEM\TELLER\METHODS\0798-19B.M
7/31/98 1:13:37 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19.M
8/3/98 10:23:06 AM by bgp
7
7
1
FID1A, (0798-1 9B\007F0701.D)
counts -i 1
4 i
175000^ "
t
c
1 50000 -; ^
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-
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1 ^ *
i
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i
-------
Data File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19B\007F0702.D
gc-14 pg 53 #7
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
7/31/98 5:01:16 PM
gc-14 pg 53 #7
bgp
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19A.S
E:\HPCHEM\TELLER\METHODS\0798-19B.M
7/31/98 1:13:37 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19.M
8/3/98 10:23:06 AM by bgp
7
7
2
FID1 A, (0798-19B\007F0702.D)
: counts^ g fi g ggg g g
j j
1 '
1 75000 -j :
i t
J 5
150000^ ^
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-------
.ta File &i\lIP<3IEM\'i;^ ;Vv:i:eagent blank
Injection Date : 7/31/98 5:18:30 PM Seq. Line : 8
Sample Name : reagent blank Vial : 8
Acq. Operator : bgp Inj : 1
.-.•_.-- v- • --. .: In j.-Volume r -2 p.1-
Sequence File " :" E : \HPCHEM\TELLER\SEQUENCE\-0798 -"19A".S
Acq. Method : E:\HPCHEM\TELLER\METHODS\0798-19B.M
Last. changed,. .. : 7/3J./98 1:13 :.3.7...PM. by. bgp .. .. . r,
Last changed : 8/3/98 11:06:31 AM by bgp
FID1 A, (0798-19B\008F0801.D)
counts "I SI
~i
18000-j
-I
14000-f-
1 -
12000-". _.
"10000--3--: -•; .... _ _, .
.-.--::j- ^.-[4.-:-- ^-i-J&»~:~. .•"i.-jgSf-^.. --;',-/r
.8000^.,.^-..^, ,^-.^-^^^_,-,*-...--;,: ,_.
....;- ii-. _3fr- "^ '- -"-v . -.'..-, . -—r"i.'.' "' " ' ''"' '•
eooo-^ ' -- -
1
4000-i
--15 -
20 - ^nirt
Multiplier
- Diluton-- -.--
-- •"--.-—"- -1 PO-000-
"^
- ..--v. .•.--•>--,--•-,-..i£V-,-=TaltliBne
^ „._.„-. T. . _..!-_-..-?-,- — - *"v* •."-- i^xr i ,» : — T"^*." "--*-~ --*0*., r*^- T-T> ^^-* - -vw^zw,.- — r-7-'..^*3^* JMa:.^>?i3ii«:*)r-**iTtrT5
Totals,,::?-.. ..v::.:...:,,^;- -;._.-.•. :,:. .;;>":• '.... ,\-;:vf\,a:-OO^cr^:~">!
-Resul-ts obt-ained:.w£feh: enLhranced--.inte5ra'tor-!:
2 Warnings or Errors :
Warning' V "Caiibrati'dri • warnings x'(:see"'caiitfra'tibri' •tab'i'e'-- iistitig). \
Warning : Calibrated compound(s) not found
Her 8/3/98 11:09:25 AM bgp
80
Page 1 of 2
-------
Data -Fiii f E
'-' : -reagent bl ank
Injection Date
Sample Name
Acq. Operator
Sequence .-File
Acq. Method
Last ''changed'' -
Analysis _Method
. Las t';chaifge:d"'.
7/31/9;8:; 5.^35 i 4'0" ~PM~
reagent- blank
bgp
: " ..... " "Seq.-":Lihe
• Vial
Inj
Tnj '-Volume^
E : \HPCHEM\TELLERASEQUEN-CE\ .0 7 9 8-19A. S - -
E : \HPCHEM\TELLER\METHQDS\0798---19B . M :
--
-19-.M:,
8
8
2
:"• E-:
.12000=1 ••-• '•;-ji-1
'""
.....E2?.t_errral -Standard:,Report -- ,..,.
5 or ted-By,- - - - -. -• ----- -.-^:-^"^*~.
Calib,-Da£a-Modified-:t-V^':'^-/
" - -.-^ counts*^:-.r.-~~?-:-- '• •-:
r-.'-~- ~r;**;~~-K;:"t*'*-•"-.[^-^•"-ViD-^-.-iVt::
7..-39.0'' .
. 176 ••:'->'.
; Totals;.::-:.c;-r;/:%i;^^.;^;:;-tr;7-:;;7.^/:\:^r "-~\.^'.(^QfrO^^^ .",'."-/• "•"
--'-\Waj^inH^-:^£ali±>£at?^ :'-~,:- -J
•'3iri"-"-~ ''"•'""""'"?•"•• ''".'.:'Ix.i»-".-i:;y/.-.r",i"--.i ^* v'?: \^-JTr^>"?:V^-^-^'^--^'^;:±"^;rv^r^*i-"^'.^^.';"''-''" '" •
?^Z
^•^ o
/no i i . rva .-•3:Q-""aM-" Vkrrri" -"
'Paae "1. of 2
-------
ita File-Er\HPeHEM\TELLER\iDATA-Vl-998-VJUL.98\0-798-i9B\003-F190-l-7f> gc-14 pg 53 #3
Inj ection^Dabe..
Sample-".'Name
Acq. Operator
Sequence--Fi-le --
Acq. Method
Last changed
Analysis Method
Last changed
. bgp_ _ . . _ r Inj
'"""•• i£5 Volume
- -E-r\HPGHEM-\T-ELL-E-R-\SE^UENGE\079S~-19AvS --•
E:\HPCHEM\TELLER\METHODS\0798-19B.M
7/3T/98 1:13:37 PM'by bgp
E:\HPCHEM\TELLER\METHODS\0798-19.M
8/3/98 11:06:31 AM by bgp
3--
1.
FID1A, (0798-1 9BV003F1901.D)
counts j SI
.
18000-
16000-
14000-
K
Hexane
en
$
!
a
4) O
N I'-
ll)
§ 0)
&l
10000-
8000-
.6000-^
4000 -
CD
8
10
15
-20
mini
External Standard Report
Sorted--By
Calib...Data Modified
Multiplier
Dilution
Signal
-8/3_/98
l.'OOOO
1.0000-
.AM - :-
signal- .
RetTime
[min]
1.469
5.414
7.397'
9.185
9.346
9.483
10.107
10.403
L: -U'lDl-
Type
~
BP
VB
BB
BV
W
VB'
BV
-VB
A, -
Area
count s*s
4.4554064
5. 36396e4
5r45539e"4
5.4826964
5.4669064
5.4640464
4.9934964
5.5954264-
Amt/Area
1 _
1
8.950466-4
8.017486-4
7.861906-4
7.80082e-4
7.87946e-4
7.85077e-4"
8.524546-4
7.6002-96-4
Amount Grj
[ug/kg]
39.87785
43.00538
42.88974"
42.76950
43.07628
42.89690 •'
42.56717
42.52-682
3 Name
Hexane
Benzene
Toluene"
Ethylbenzene
p-Xylene
m-Xylehe
Cumene
"p-Xylene .
Totals :
339.60964
Results obtained .with enhanced integrator!
1 Warnings or Errors :
Warning : Calibration warnings (see calibration table listing)
1
Her 8/3/98 11:13:54 AM bgp
82
Page l of 2
-------
Data Fil-e-E^VHPG^M\-TBIrLER\DA^ —— gc-14- pg -53 #3
Injection-Date-
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last .changed -
Analysis Method
Last changed
8/1/98.. 4:.52:.02. AM-
gc-1-4 pg -53 #3
-. - Seq, Line
Vial
19
3
2
.'•_.....- .. -•• .- . - 1.-_:__-"•" •-' Inj-lrVolume
E:\HPCHEM\TELLER\SEQUENCE\0798-19A.S
E : \.HP.CHEM\TELLER\METHOD5VP79.8 -19B..M
7/31798. l:.llr.37 PM"..by_bgp ...'....'"
E:-\HPCHEM\TELLER\METHODS\0-79.a-19 .M: - "-
'8/379'8 11"; 06; 31" AM-by bgp
FID1 A, (0798-19B\003F1902.D)
counts j $
3 <
18000-1
]
16000H
t400o4 -5
" '
-i
12000^
10000 4
H
8000H
6000J
I S
4000^; ^,
S
]
r
4
-1
c 5
LS - - Si
| . ~' i=
4)
m • r*
9
in
i
j
i
I ^
i ' i
0 - 5.
i
I
i
|
i
5 i
- - - ii
"
~
i
. -.
" External.
- i
•:. j. --.-.-.
r"t?
i c
1
i
-
10 - 15 - 20 mm
, .V .- _ - .. - . __ ^..
Standard " Report
Sorted By "- • -
Calib-,. _ Cat a...Modified •.-,-'.
Dilution
Signal- 1:'. FIDl -A-, \y. •"••.'-.-:
RetTime Type Area
[min] counts*s
-Signal
' 1/00 00''
Amt/Area
Amount
[ug/kg]
Grp Name
1..467 ..
.,_ 40 ;.i
7.387 BB
9.173 -BV- '
9.335 W
9.471 VB
10.096 BV
10.392 VB
5.5114864
- - 5.543'78«4--
5.5347864
5.5143464
5.0519564
5.6602664
7.86096e-4
-7 '.7 95-7-16-4
7.878246-4
7.849846-4
8.52354e-4
7.599126-4
43.32552
-43.23-9-8,8-
43.60433
43.28669
43.06052
43.01301
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Jjumene
o-Xylene
Totals
343.10853
Results obtained with enhanced integrator!
1 Warnings or Errors :
Warning : Calibration warnings (see calibration table listing)
Q/-3/QS
AM hern
Page l of 2
-------
ata File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19B\004F2001.D gc-14 pg 53 #4
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
8/1/98 5:
gc-14 pg
bgp
09
53
-.05 AM
#4
Seq.
Line :
Vial :
Inj :
20
4
1
^ . . T
FID1 A, (0798-19B\004F2001.D)
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19A.S
E:\HPCHEM\TELLER\METHODS\0798-19B.M
7/31/98 1:13:37 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19.M
8/3/98 11:06:31 AM by bgp
: counts i !
~~i i
i i
18000-
16000- ^
14000-^
-
12000-^
I
10000^
8000-
i
"
6000 -_
_
1
4000 -
0
i SI 2
D i! a
I "M
: ! ' j
u
!•: 1
u
i
!
1
en ir>
^) ^1
•y iri
5
* 2
> i
j -i
• (
] l-
\ 1
i 1
i
1
i $
i t
3 f
i £
1
_ff
> 1
' J
3
1
i
CO
I =
i ) OJ
!r 1
1 : O
I ffl
I $
1- <3t>
V t
I
' '
!
i
10
! j
i
? '
<> ,
f
) !
3) <
\
|
K t
,
[
1 5 20 min
External Standard Report
Sorted By :
Calib. Data Modified :
Multiplier :
Dilution :
Signal 1: FID1 A,
RetTime Type Area
[min] counts*s
Signal
8/3/98 11:04:16 AM
1.0000
1.0000
Amt/Area
Amount Grp
[ug/kg]
Name
1.463
5.398
7.380
9.168
9.329
9.466
10.089
10.385
BB
VB
BP
BV
W
VB
BV
VB
9 .4151464
1. 12904e5
1.1542865
1.16960e5
1.1653165
1.1666265
1.06802e5
1.1952565
8.92227e-4
7.974296-4
7 .813186-4
7.747616-4
7.826666-4
7.796526-4
8.478616-4
7.545956-4
I -
84.00436
90.03271
90.18625
90.61615
91.20521
90.95574
90.55294
90.19261
~ 1
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cutnene
o-Xylene
Totals :
717.74597
Results obtained with enhanced integrator!
1 Warnings or Errors :
Warning : Calibration warnings (see calibration table listing)
*
iller 8/3/98 11:14:17 AM bgp
84
Page 1 of 2
-------
Data File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19B\004F2002.D
gc-14 pg 53
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
8/1/98 5:26:07 AM
gc-14 pg 53 #4
bgp
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798 -19A.S
E:\HPCHEM\TELLER\METHODS\0798-19B.M
7/31/98 1.-13.-37 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19.M
8/3/98 11:06:31 AM by bgp
20
4
2
FID1 A, (0798-1 9B\004F2002.D)
counts ~* i
i
- -
18000-
1 i
16000^ ^
1 4000 - !
12000-
" i
•" i
10000- :
8000 ~ \
6000 - i
§^l
^^ . I
B S
I •<
> o
;
S 1 i
s i
CD r
« r
i S S
Jj 1
1 i
1
i
i
i
i
j
o at ',
fc al
f a:
P T
1
0
I
i
1
i
"i
i
i
i
1 ! ;
i [
i ;
g i
TP
a^
!
1
i
i
•
!
0 5 10 15 20 mm
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FID1 A,
Signal
8/3/98 11:04:16 AM
1.0000
1.0000
RetTime
[min]
1.460
5.393
7.375
9.162
9.325
9.461
10.085
10.380
Type
BB
VB
BB
BV
W
VB
BV
VB
Area
counts* s
i __
1
9.4519764
1. 13242e5
1.1586165
1. 17556e5
1.1743865
1.1708165
1.0735365
1.2012865
Amt/Area
8.92217e-4
7.97417e-4
7.813026-4
7.747386-4
7.826306-4
7.796346-4
8.478406-4
7.545716-4
Amount G
[ug/kg]
84.33204
90.30146
90.52228
91.07513
91.91054
91.28052
91.01854
90.64509
rp Name
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals :
721.08560
Results obtained with enhanced integrator!
1 Warnings or Errors :
Warning : Calibration warnings (see calibration table listing)
OK
3
Teller 8/3/98' 11:14:28 AM bgp
Page 1 of 2
-------
ata File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19B\004F4401.D gc-14 pg 53 #4
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
8/3/98 8:46:21 PM
gc-14 pg 53 #4
bgp
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19A.S
E:\KPCHEM\TELLER\METHODS\07 9 8 -19B.M
8/3/98 3:08:36 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19.M
8/3/98 12:59:48 PM by bgp
44
4
1
FID1 A, (0798-1 98\004F4401.D)
counts j | 55! | c |
" x T"j N _2 i
17500- 7 .' " T 1
Si' 01 11
15000- ^ '! ^ $ j
: ! . ' T ' 3
12500- '< i | «t
: 'l i
10000- , : ! 1
: :! ; • i!
7500^ j i '
5000- i| - :l
- §! ' i; !' i ^
2500 - 51;;' ; - ; ' » ;
A) D
x: c
5. 1
• ?
: 1
; CD
1
1
1
i
|
i
__J 1
1
j
.Si
>K
t !
1 i
D .
j
,
1
10
1 5
20
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FID1 A,
Signal
8/3/98 11:04:16 AM
1.0000
1.0000
RetTime
[min]
1.458
5.389
7.371
9.157
9 .319
9 .457
10.081
10.376
Type
BB
BP
BB
BV
W
VP
BV
VB
Area
counts*s
9 .77024e4
1. 17667e5
1. 1872665
1. 1891665
1. 1845665
1.1853165
1.0806165
1.21298e5
Amt/Area
8.92135e-4
7.97271e-4
7.81197e-4
7.746846-4
7.825916-4
7.795766-4
8.478146-4
7.545256-4
Amount G
[ug/kg]
87.16372
93 .81246
92 .74812
92.12230
92 .70269
92.40364
91.61544
91.52250
rp Name
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals :
734.09086
Results obtained with enhanced integrator!
1 Warnings or Errors :
Warning : Calibration warnings (see calibration table listing)
Her 8/4/98 8:04:02 AM bgp
UL 88
Page 1 of 2
-------
Data File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19B\004F4402.D
gc-14 pg 53 #4
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
8/3/98 9:03:48 PM
gc-14 pg 53 #4
bgp
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0 7 9 8 -19A. S
E:\HPCHEM\TELLER\METHODS\0798-19B.M
8/3/98 3:08:36 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19.M
8/3/98 12:59:48 PM by bgp
44
4
2
FID1 A, (0798-1 9B\004F4402.D)
counts J £ ffl c I
_ CO t-i 0) 1
3C ' M "
i
s
1
i
I I
i
1 |
i
$
^j
"P
®
I :
I
\
I
i
i
•
1
10
1 5
20
mm
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FID1 A,
Signal
8/3/98 11:04:16 AM
1.0000
1.0000
RetTime
[min]
1.456
5.383
7.364
9.152
9.313
9.450
10.075
10.371
Type
BP
VB
BB
BV
W
VB
BV
VB
Area
counts*s
i
1
9.52l24e4
1. 13881e5
1.13914e5
1. 1383265
1.13460e5
1.1327365
1. 03323e5
1.15914e5
Amt/Area
8.92198e-4
7.97395e-4
7.8l376e-4
7.74890e-4
7.82793e-4
7.797956-4
8.479976-4
7.547446-4
Amount Grj
[ug/kg]
_ |
84.94831
90.80822
89.00937
88.20727
88.81540
88.32969
87.61785
87.48507
D Name
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals
705.22117
Results obtained with enhanced integrator!
1 Warnings or Errors :
Warning : Calibration warnings (see calibration table listing)
Teller 8/4/98 8:04:21 AM bgp
Page l of 2
-------
Data File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19B\003F3201.D gc-14 pg 53 #3
Injection Date
Sample Name
Acq. Operator
Acq. Method
Last changed
Analysis Method
Last changed
8/2/98 8:59:11 PM
gc-14 pg 53 #3
bgp
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\METHODS\0798-19B.M
7/31/98 1:13:37 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19.M
8/11/98 9:27:42 AM by bgp
(modified after loading)
F1D1 A, (0798-19B\003F3201.D)
32
3
1
counts :
40000 -]
35000 -
30000 -
25000 -
20000 -
15000 -
10000 -
5000 -
0-_
0
10
12 min
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FID1 A,
Signal
8/3/98 11:04:16 AM
1.0000
1.0000
RetTime
[min]
1.464
5.399
7.381
9.167
9.329
9.466
10.089
10.384
Type
BB
VB
BB
MF
MF
FM
MM
MM
Area
counts*s
4 .7454164
5.72762e4
5. 96777e4
6.00312e4
6.04495e4
5.89629e4
5.49102e4
6. 1197464
Amt/Area
8.94719e-4
8. 01225e-4
7.85397e-4
7.79214e-4
7.86995e-4
7.84329e-4
8.51672e-4
7.59154e-4
Amount
[ug/kg]
42 .45803
45.89113
46.87069
46 .77711
47.57348
46.24630
46.76548
46.45823
Grp Name
1 _ _
1
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals :
369.04045
Results obtained with enhanced integrator!
1 Warnings or Errors :
Warning : Calibration warnings (see calibration table listing)
neller 8/11/98 9:27:46 AM bgp
Page 1 oJ
-------
Data File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19B\003F3202.D gc-14 pg 53 #
Injection Date
Sample Name
Acq. Operator
Acq. Method
Last changed
Analysis Method
Last changed
8/2/98 9:16:07 PM
gc-14 pg 53 #3
bgp
Seq. Line
Vial
Inj
Inj Volume
E : \HPCHEM\TELLER\METHODS\079 8 -19B.M
7/31/98 1:13:37 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19.M
8/11/98 9:29:17 AM by bgp
(modified after loading)
FIDi A, (0798-19B\003F3202.D)
counts ;
40000 ^
35000 -
30000 -
25000 -_
20000 -:
15000 -_
10000 -_
5000 -
5 -
s x
O O
32
3
2
2 Ml
60540
i 3
0 -
0 2
10
12
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FIDI A,
Signal
8/3/98 11:04:16 AM
1.0000
1.0000
RetTime
[min]
1.464
5.395
7.376
9.163
9.324
9.460
10.085
10.381
Type
BP
VB
BB
MF
MF
FM
MM
MM
Area
count s*s
i
4.8038864
5. 7799464
5.98757e4
6 .0497964
6.0222364
5.9257864
5.4407264
6.0540064
Amt/Area
__
8.946576-4
8.01155e-4
7.853696-4
7.791436-4
7.870296-4
7.842826-4
8.517456-4
7.592556-4
Amount Grj:
[ug/kg]
42.97826
46.30627
47.02449
47 .13648
47.39669
46.47485
46.34106
45.96532
5 Name
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals :
369.62342
Results obtained with enhanced integrator!
1 Warnings or Errors :
Warning : Calibration warnings (see calibration table listing)
Teller 8/11/98 9:29:20 AM bgp
^ 89
Page 1 of 2
-------
Method: 'E:\HPCHEM\TELLER\METHODS\0798-19D.M of 8/10/98 4:33:19 PM
Calibration Table
Calib. Data Modified
Calculate
Based on
Rel. Reference Window
Abs. Reference Window
Rel. Non-ref. Window
Abs. Non-ref. Window
Uncalibrated Peaks
Partial Calibration
Correct All Ret. Times
Curve Type
Origin
Weight
Recalibration Settings
Average Response
Average Retention Time
8/10/98 4:32:29 PM
External Standard
Peak Area
5.000 %
0.080 min
5.000 %
0.080 min
not reported
Yes, identified peaks are recalibrated
No, only for identified peaks
Linear
Connected
Linear .
Average all calibrations
Floating Average New 75%
Calibration Report Options :
Printout of recalibrations within a sequence:
Calibration Table after Recalibration
Normal Report after Recalibration
If the sequence is done with bracketing:
Results of first cycle (ending previous bracket]
Signal 1: FID1 A,
RetTime Lvl Amount
[min] Sig [ug/kg]
1.463 1 1 7.34000
2 16.28000
3 40.60000
4 80.70000
5 198.90000
6 388.00000
5.391 1 1 7.85000
2 17.43000
3 43.40000
4 86.40000
5 213.00000
6 416.00000
7.373 1 1 7.77000
2 17.23000
3 42.90000
4 85.50000
5 210.60000
6 411.00000
9.161 1 1 7.73000
2 17.13000
Area
9673.23975
1.93840e4
4 .76743e4
9.41487e4
2.32427e5
4. 5265865
1.12912e4
2.29720e4
5. 7128264
1. 1345265
2.8008665
5. 4445665
1.1326564
2. 3057264
5.7432064
1. 14587e5
2. 82801e5
5.47336e5
1.1285164
2.3036364
Am t/ Are a Ref
7.58794e-4
8.39868e-4
8.51612e-4
8.571556-4
8.557546-4
8.571596-4
6.95232e-4
7.587516-4
7.59695e-4
7.61554e-4
7.60481e-4
7.640666-4
6. 86000e-4
7.472726-4
7.469716-4
7.461556-4
7.446926-4
7.509096-4
6.849736-4
7.436096-4
Grp Name
Hexane
Benzene
Toluene
Ethylbenzene
u 9
36" /
eller 8/11/98 8:27:32 AM bgp
Page 1 of 2
-------
Method: E:\HPCHEM\TELLER\METHODS\0798-19D.M of 8/10/98 4:33:19 PM
RetTime Lvl Amount
[min] Sig [ug/kg]
3 42.70000
4 85.00000
5 209.30000
6 409.00000
9.323 1 1 7.79000
2 17.27000
3 43.00000
4 85.70000
5 211.00000
6 412.00000
9.460 1 1 7.74000
2 17.15000
3 42.80000
4 85.10000
5 209.60000
6 409.00000
10 . 084 11 7 . 70000
2 17.07000
3 42.60000
4 84.70000
5 208.60000
6 407.00000
10.379 1 1 7.67000
2 17.02000
3 42.40000
4 84.40000
5 208.00000
6 406.00000
Area
5.74747e4
1. 1497865
2.84062e5
5.49455e5
1. 13100e4
2.3021064
5. 7296464
1. 14837e5
2. 83267e5
5.4845665
1.1248364
2.2971464
5.7353864
1.1450365
2.8292465
5.4591865
1.0373064
2 .1049064
5.2315964
1.0473765
2.5868365
5.0024065
1.1542064
2. 35537e4
5 .8660164
1.1742665
2.89885e5
5 .6047665
Amt/Area Ref
_ |
7.429366-4
7.392756-4
7.368106-4
7.443756-4
6.887736-4
7.501856-4
7.504846-4
7.462776-4
7.448806-4
7.512006-4
6.881056-4
7.465826-4
7.462466-4
7.432146-4
7.408346-4
7.491976-4
7.423146-4
8.10963e-4
8 .142856-4
8 .086946-4
8.063936-4
8.136106-4
6.645286-4
7.226046-4
7.228086-4
7.187526-4
7.175276-4
7.243846-4
Grp Name
p-Xylene
m-Xylene
Cumene
o-Xylene
3 Warnings or Errors :
Warning : Overlapping peak time windows at 9.161 min, signal 1
Warning : Overlapping peak time windows at 9.323 min, signal 1
Warning : Overlapping peak time windows at 10.084 min, signal 1
Peak Sum Table
***No Entries in table***
Teller 8/11/98 8:27:32 AM bgp
91
Page 2 of 2
-------
ata File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19C\001F0101.D gc-14 pg 53 #1
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
8/4/98 5:10:41 PM
gc-14 pg 53 #1
HD1A, (0798-iyC\001F0101.D)
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0 7 9 8 -19D.S
E:\HPCHEM\TELLER\METHODS\0798-19B.M
8/3/98 3:08:36 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19D.M
8/10/98 4:33:19 PM by bgp
1
1
1
2 /zl
S 5.
4000 -
3500 -
3000 -
rti
2500 -
2000 -
10
15
20
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FID1 A,
Signal
8/10/98 4:32:29 PM
1.0000
1.0000
RetTime
[min]
1.453
5.360
7.342
9.130
9.292
9.429
10.054
10.350
Type
BB
VB
BB
BV
W
VP
BV
VB
Area
count s*s
9766 .34668
1.13277e4
1.13748e4
1.13538e4
1.13914e4
1.13131e4
1.04436e4
1.16209e4
Amt/Area
7.84089e-4
7.15467e-4
7.05586e-4
7.05348e-4
7.10416e-4
7.072206-4
7.671006-4
6.842206-4
Amount Gri
[ug/kg]
__ 1 _
7.65769
8.10456
8.02590
8.00841
8.09261
8.00083
8.01131
7.95124
3 Name
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals :
63.85254
Results obtained with enhanced integrator!
1 Warnings or Errors :
Warning : Calibration warnings (see calibration table listing)
&
iller 8/10/98 4:35:35 PM bgp
92
Page 1 of 2
-------
Data File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19C\001F0102.D gc-14 pg 53'#]
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last chanaed
8/4/98 5:27:43 PM
gc-14 pg 53 #1
bgp
FID1 A, <079S-19C\001F0102.r>5
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19D.S
E:\HPCHEM\TELLER\METHODS\0798-19B.M
8/3/98 3:08:36 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19D.M
8/10/98 4:33:19 PM by bgp
1
1
2
counts
10
.15
20
nun
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FID1 A,
Signal
8/10/98 4:32:29 PM
1.0000
1.0000
RetTime
[min]
1.438
5.362
7.347
9.137
9.300
9.436
10.061
10.357
Type
BV
VP
BP
BV
W
VB
BV
VB
Area
counts*s
_
9580.13281
1. 1254864
1. 1278364
1.1216464
1.1228664
1. 11835e4
1.0302364
1.1463264
Amt/Area
i
7.826lOe-4
7.151466-4
7.05200e-4
7.048806-4
7.098306-4
7.067476-4
7.66465e-4
6.836776-4
Amount
[ug/kg]
7.49751
8.04879
7.95345
7.90621
7.97038
7.90391
7.89635
7.83710
Grp Name
__ i __
1
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals :
63.01371
Results obtained with enhanced integrator!
1 Warnings or Errors :
Warning : Calibration warnings (see calibration table listing)
f
93
R/10/98 4:35:48 PM bqp
Page 1 of 2
-------
ata File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19C\002F0201.D
gc-1'4 pg 53 #2
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
8/4/98 5:44:45 PM
gc-14 pg 53 #2
bgp
FID1 A, (0798-19C\002F020I.D)
§ S1
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19D.S
E:\HPCHEM\TELLER\METHODS\0798-19B.M
8/3/98 3:08:36 PM by bgp
E:\HPCHEM\TELLER\METHODS\0 7 9 8 -19D.M
8/10/98 4:33:19 PM by bgp
2
2
1
counts -
6000 -;
5500 -'
5000 -
4500 -_
4000 -_
3500 -_
3000 -
2500 :
2000 -
f-
no
,'A
0
10
15
20
-_nun
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FID1 A,
Signal
8/10/98
1.0000
1.0000
4:32:29 PM
RetTime
[min]
1.456
5.377
7.359
9.146
9.309
9.446
10.070
10.365
Type
BB
VB
BP
BV
W
VB
BV
VB
Area
count s*s
1. 94564e4
2. 3051464
2 .3137364
2.3120364
2.3077964
2. 30659e4
2. 11355e4
2.3629964
Amt/Area
8.219826-4
7.406426-4
7.28494e-4
7.247666-4
7.308926-4
7.28020e-4
7.904986-4
7.042876-4
Amount G
[ug/kg]
15.99285
17.07283
16 .85538
16.75680
16.86745
16 .79241
16.70755
16.64220
rp Name
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals :
133.68747
Results obtained with enhanced integrator!
1 Warnings or Errors :
Warning : Calibration warnings (see calibration table listing)
'
• ;
Teller 8/10/98 4:35:59 PM bgp
Page 1 of 2
-------
Data File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19C\002F0202.D ' gc-14 pg 53 #2
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
8/4/98 6:01:48 PM
gc-14 pg 53 #2
F1D1 A, (0798-19C\002F0202.D)
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19D.S
E:\HPCHEM\TELLER\METHODS\0798-19B.M
8/3/98 3:08:36 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19D.M
8/10/98 4:33:19 PM by bgp
2
2
2
counts
2000 -
10
15
20
mini
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FID1 A,
Signal
8/10/98 4:32:29 PM
1.0000
1.0000
RetTime
[min]
1.458
5.382
7.364
9.152
9.313
9.450
10.074
10.370
Type
BV
VB
BP
BV
W
VB
BV
VB
Area
count s*s
1. 93115e4
2. 2892564
2.2977164
2. 29523e4
2. 29641e4
2.2876964
2.0962664
2.34776e4
Amt/Area
8.21696e-4
7.404736-4
7.28339e-4
7.246296-4
7.30793e-4
7.278546-4
7.903096-4
7.041616-4
Amount
[ug/kg]
15.86821
16.95128
16.73513
16.63192
16.78200
16.65101
16.56693
16.53198
Grp Name
1
1
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals :
132.71846
Results obtained with enhanced integrator!
1 Warnings or Errors :
Warning : Calibration warnings (see calibration table listing)
95
Teller 8/10/98 4:36:11 PM bgp
Page 1 of 2
-------
ita File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19C\003F0301.D gc-14 pg 53 #3
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
ig
rl
8/4/98 6:19:01 PM
gc-14 pg 53 #3
bgp
FTOl A, (0798-19C\003F0301.D)
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19D.S
E:\HPCHEM\TELLER\METHODS\0798-19B.M
8/3/98 3:08:36 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19D.M
8/10/98 4:33:19 PM by bgp
3
3
1
counts
10000
8000 -
6000 -
4000 -
8
2000 -
10
15
20
_min
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FID1 A,
External Standard Report
Signal
8/10/98 4:32:29 PM
1.0000
1.0000
RetTime
[min]
1.460
5.385
7.368
9.156
9.318
9.454
10.078
10.374
Type
. __
BV
VB
BP
BV
W
VB
BV
VB
Area
counts* s
|
4. 7789164
5 .7194064
5. 7419364
5. 7409964
5.7261964
5.7304364
5.2260464
5.8613064
Amt/Area
8.44625e-4
7.55162e-4
7.41720e-4
7.35957e-4
7.42807e-4
7.39982e-4
8.04110e-4
7.158766-4
Amount Grj
[ug/kg]
40.36387
43 .19074
42.58905
42 .25125
42.53457
42.40416
42.02307
41.95963
3 Name
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals :
337.31634
Results obtained with enhanced integrator!
I Warnings or Errors :
Warning : Calibration warnings (see calibration table listing)
'eller 8/10/98 4:36:23 PM bgp
96
Page 1 of 2
-------
Data File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19C\003F0302.D gc-14 pg 53 #3
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
?5E
8/4/98 6:36:09 PM
gc-14 pg 53 #3
F1D1 A, (0798-19C\003F0302.D)
s $!
Seq. Line : 3
Vial : 3
Inj : 2
Inj Volume : 2 fj.1
E:\HPCHEM\TELLER\SEQUENCE\0798-19D.S
E:\HPCHEM\TELLER\METHODS\0798-19B.M
8/3/98 3:08:36 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19D.M
8/10/98 4:33:19 PM by bgp
FrPT7VT~T\\ " a*A
counts
I «'
10000 -
s
8000 -
6000
4000
2000 -
I
S
-o
10
15
20
min
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal
8/10/98 4:32:29 PM
1.0000
1.0000
Signal 1: FID1 A,
RetTime
[min]
1.460
5.388
7.370
9.157
9.319
9.456
10.080
10.376
Type
BV
VB
BB
BV
W
VB
BV
VB
Area
count s*s
4. 7559564
5. 70623e4
5.74446e4
5.7539464
5.73308e4
5.7403264
5.2371364
5.8707364
Amt/Area
8.44550e-4
7.55139e-4
7.417246-4
7.35974e-4
7.428176-4
7.399966-4
8.04129e-4
7.158896-4
Amount
[ug/kg]
40.16637
43.09000
42.60799
42.34755
42.58630
42.47814
42.11333
42.02791
Grp Name
__ 1
\ . .. -
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals :
337.41758
Results obtained with enhanced integrator!
1 Warnings or Errors :
Warning : Calibration warnings (see calibration table listing)
Teller 8/10/98 4:36:34 PM bgp
97
Page 1 of 2
-------
it a File E:\HPCHEM\TELLER\DATA\1998\JUL98\0-798-19C\004F0401.D
gc-14 pg 53 #4
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
FEDl A, (0798-19C\004F0401.D)
8/4/98 6:53:16 PM
gc-14 pg 53 #4
bgp
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19D.S
E:\HPCHEM\TELLER\METHODS\0798-19B.M
8/3/98 3:08:36 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19D.M
8/10/98 4:33:19 PM by bgp
4
4
1
2 /zl
counts _-
20000 -"
17500 -_
15000 -
12500 -j
10000 -;
7500 -
5000 -
o no-
2500 - - —: •
*
-c
—
30
10
15
20
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal
8/10/98 4:32:29 PM
1.0000
1. 0000
Signal ]
RetTime
[min]
_ _
1.461
5.389
7.372
9.159
9.321
9.458
10.083
10.378
L: FID1
Type
BV
VB
BB
BV
W
VB
BV
VP
A,
Area
count s*s
9.40295e4
1.13221e5
1. 1420165
1.14469e5
1.1431265
1. 14059e5
1. 04220e5
1.1683465
Amt/Area
8.52271e-4
7.60013e-4
7.46158e-4
7.39719e-4
7.46822e-4
7.439926-4
8.08718e-4
7.197776-4
Amount G
[ug/kg]
80.13861
86.04933
85.21218
84 .67486
85.37055
84.85930
84.28492
84.09424
rp Name
Kexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals :
674.68398
Results obtained with enhanced integrator!
1 Warnings or Errors :
Warning : Calibration warnings (see calibration table listing)
slier 8/10/98 4:36:46 PM bgp
98
Page 1 of 2
-------
Data File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19C\004F0402.D gc-14 pg 53
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
8/4/98 7:10:28 PM
gc-14 pg 53 #4
bgp
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19D.S
E:\HPCHEM\TELLER\METHODS\0798-19B.M
8/3/98 3:08:36 PM by bgp
E:\HPCHEM\TELLER\METHODS\0 7 9 8 -19D.M
8/10/98 4:33:19 PM by bgp
rpn'-fTTT rn * a*-*-
4
4
2
counts
20000
17500
15000
12500
FTOIA,
j £
SJ
x
D
_ •"•
: CK
I/TI
- "^
i
— i
-
-i
(0798-19C\004F04Q2.D)
r>' ,
2 s !
CM. 8 =
= :
& s-
cv P
S S
• rp
1
i S
; i
3
1
1
1
1
3
°H
ji
,
t 2*
I 53
Ai
^
E ^
i i
| |
i
i i
10000 -_
7500 -
5000 -
O reoi
2500 - - —',
*
'
s
ad
10
15
20
jmn
External Standard Reoort
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FID1 A,
Signal
8/10/98 4:32:29 PM
1.0000
1.0000
RetTime
[min]
1.459
5.389
7.372
9.159
9.322
9.459
10.082
10.378
Type
BV
VB
BP
BV
W
VB
BV
VB
Area
count s*s
1 __ _
1
9. 4267864
1. 13684e5
1.1497465
1.1548665
1.15362e5
1.1494665
1. 05253e5
1. 18018e5
Amt/Area
8.52291e-4
7.60033e-4
7.46188e-4
7.397526-4
7.468586-4
7.440236-4
8.087636-4
7.198176-4
Amount
[ug/kg]
80.34360
86.40335
85.79195
85.43102
86.15885
85.52248
85.12493
84.95119
Grp Name
__!__
1
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals :
679.72735
Results obtained with enhanced integrator!
1 Warnings or Errors :
Warning : Calibration warnings (see calibration table listing)
99
i oo
Page 1 of 2
-------
ata File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19C\005F0501.D
gc-14 pg 53 #5
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last chanqed
8/4/98 7:27:34 PM
gc-14 pg 53 #5
bgp
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19D.S
E:\HPCHEM\TELLER\METHODS\0798-19B.M
8/3/98 3:08:36 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19D.M
8/10/98 4:33:19 PM by bgp
5
5
1
FID1 A,
counts ~ 0
«
X
50000 - ~
' 3
40000 -
-
30000 -
20000 -
10000 -
(0798-19C\005F0501.D)
4J u ES \
- 1 2 8*? =
*T 1J gffl^ ^
IN p m T
! ! a3lli
i i|!
'IS1
i ' ! !'
s i i
; i i ;
i
i •
o -_
0
10
15
20
JBIH
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FID1 A,
Signal
8/10/98 4:32:29 PM
1.0000
1.0000
RetTime Type
[min]
_ _. _ i
1,462 BV
5.390 VB
7.373 BB
9.161 BV
9.323 W
9.460 VB
10.084 BV
10.380 VB
Area
count s*s
2.32817e5
2 .80396e5
2.82960e5
2. 84084e5
2.83107e5
2. 82990e5
2 .5869565
2.8990065
Amt/Area
8.56982e-4
7.62966e-4
7.48835e-4
7.419786-4
7.49224e-4
7.464096-4
8.114866-4
7.221226-4
Amount Grj
[ug/kg]
i __
199.51974
213 . 93234
211.89053
210.78420
212.11038
211.22596
209.92757
209.34334
3 Name
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals
1678.73407
Results obtained with enhanced integrator!
1 Warnings or Errors :
Warning : Calibration warnings (see calibration table listing)
'eller 8/10/98 4:37:09 PM bgp
100
Page 1 of 2
-------
Data File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19C\005F0502.D
gc-14 pg 53 #5
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
ig<
rs;
8/4/98 7:44:40 PM
gc-14 pg 53 #5
FIDi A, <079S-19C\005F0502.D)
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19D.S
E:\HPCHEM\TELLER\METHODS\0798-19B.M
8/3/98 3:08:36 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19D.M
8/10/98 4:33:19 PM by bgp
5
5
2
counts
soooo
"
5= u$
40000 :
30000 -
20000 -
10000 ~
~s
X
0-
10
15
20
mini
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FIDI A,
Signal
8/10/98 4:32:29 PM
1.0000
1.0000
RetTime
[min]
1.461
5.391
7.373
9.162
9.324
9.461
10.084
10.380
Type
_ _ _
BB
VB
BB
BV
W
VB
BV
VB
Area
count s*s
2.32037e5
2.79776e5
2.82642e5
2.84041e5
2.83427e5
2.82859e5
2.58670e5
2.89869e5
Am t/ Are a"
8.56971e-4
7.629616-4
7.48833e-4
7.41978e-4
7.49226e-4
7.46408e-4
8.11485e-4
7.22122e-4
Amount Grj
[ug/kgj
j__
198.84866
213.45857
211.65183
210.75197
212.35101
211.12820
209.90705
209.32068
5 Name
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals :
1677.41797
Results obtained with enhanced integrator!
1 Warnings or Errors :
Warning : Calibration warnings (see calibration table listing)
Paqe 1 of 2
-------
ata File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19C\006F0601.D gc-14 pg 53 #6
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
, hlDl A. (07y»-19C\006F0601.D)
8/4/98 8:01:47 PM
gc-14 pg 53 #6
bgp
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0 798-19D.S
E:\HPCHEM\TELLER\METHODS\0798-19B.M
8/3/98 3:08:36 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19D.M
8/10/98 4:33:19 PM by bgp
6
6
1
counts
100000
s
4>
M
i
Tol
80000 -
60000
40000
20000 -
S
'00
CM w-i
TI vn
10
15
20
.JHJDJ
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal
8/10/98 4:32:29 PM
1.0000
1.0000
Signal 1: FID1 A,
RetTime
[tnin]
1.463
5.392
7.373
9.161
9.324
9.460
10.084
10.379
Type
BV
VB
BB
BV
W
VB
BV
VB
Area
count s*s
4.51702e5
5. 4369465
5.46499e5
5.48540e5
5. 4729565
5.45232e5
4.9941765
5.5952665
Amt/Area
i
8.585286-4
7.639346-4
7.497086-4
7.427136-4
7.500096-4
7.471946-4
8.123866-4
7.228856-4
Amount G
[ug/kg]
387.79894
415.34663
409.71448
407.40779
410.47635
407.39376
405.71883
404.47246
rp Name
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals
3248.32924
Results obtained with enhanced integrator!
1 Warnings or Errors :
Warning : Calibration warnings (see calibration table listing)
102
>H<=r 8/10/98 4:37:32 PM b
-------
Data File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19C\006F0602.D gc-14 pg 53 #6
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
8/4/98 8:18:58 PM
gc-14 pg 53 #6
bgp
FID1 A. (U798-19C\0061-'0602.D);
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19D.S
E:\HPCHEM\TELLER\METHODS\0798-19B.M
8/3/98 3:08:36 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19D.M
8/10/98 4:33 :19 PM by bgp
6
6
2
counts
J
100000 -
80000 -
60000 -
40000 -
I
l
S
20000
o--
I
10
15
20
mm;
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal
8/10/98 4:32:29 PM
1.0000
1.0000
Signal 1: FID1 A,
RetTime
[min]
1.463
5.391
7.373
9.161
9.323
9.460
10.084
10.379
Type
BB
VB
BB
BV
W
VB
BV
VB
Area
count s*s
4. 53614e5
5. 45217e5
5.4817465
5. 50369e5
5.4961765
5.4660365
5.0106365
5.6142665
Amt/Area
8.585356-4
7.63937e-4
7.497116-4
7.427166-4
7.500136-4
7.471966-4
8.123896-4
7.228876-4
Amount G
[ug/kg]
389.44396
416.51158
410.97214
408.76803
412.21955
408.41984
407.05816
405.84804
rp Name
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals :
3259.24130
Results obtained with enhanced integrator!
1 Warnings or Errors :
Warning : Calibration warnings (see calibration table listing)
103
To! 1
«/in/Q«
PM bCTD
Page 1 of 2
-------
ata File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19C\007F0701.D gc-14 pg 53 #1
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
8/4/98 8:36:06 PM
gc-14 pg 53 #7
bgp
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0 7 9 8 -19D.S
E:\HPCHEM\TELLER\METHODS\0798-19B.M
8/3/98 3:08:36 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19D.M
8/10/98 4:33:19 PM by bgp
7
7
1
FIDi A, (0798-19C\007F0701.D)
counts -
n^nnn _
§
2
£
4)
3
i
a
|
£
3= M =
Is- &>•
M 04
150000
rj
S
125000 - ! | ! ^
100000 -
- I (I
75000 - ;
' f^1 '
50000 - N
25000 -_ g '
-------
Data File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19C\007F0702.D gc-14 pg 53 #7
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
igi
rs;
8/4/98 8:53:17 PM
gc-14 pg 53 #7
bgp
FTO1A, (0798-19C\007F07U2.D)
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19D . S
E:\HPCHEM\TELLER\METHODS\0798-19B.M
8/3/98 3:08:36 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19D.M
8/10/98 4:33:19 PM by bgp
•7
7
2
counts . u
200000 -j I
. ^2
175000 - T
• I
150000 - -
125000 -
100000 ^
75000 - !
r
T
50000 -: r
J
25000 - oo o
^ CO
0--
10
15
20
jmn
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FID1 A,
Signal
8/10/98 4:32:29 PM
1.0000
1.0000
RetTime
[min]
_
1.462
5.390
7.373
9.162
9.324
9.460
10.085
10.380
Type
W
VB
BB
BV
W
VB
BV
VB
Area
counts*s
_
8.67357e5
1.04386e6
1. 05233e6
1.0579066
1.0552366
1.0511066
9. 63790e5
1.0798066
Amt/Area
8.59317e-4
7.64428e-4
7.50159e-4
7.43094e-4
7.50414e-4
7.476016-4
8.12852e-4
7.232806-4
Amount Grj
[ug/kg]
| __
745.33410
797.95392
789.41583
786.11965
791.86273
785.80522
783.41833
780.99682
3 Name
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals :
6260.90659
Results obtained with enhanced integrator!
1 Warnings or Errors :
Warning : Calibration warnings (see calibration table listing)
~^ o/in/aa /i.-jQ.m PM hern
105
Page 1 of 2
-------
ata File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19C\008F0801.D
reagent blank
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
ig<
nr
8/4/98 9:10:18 PM
reagent blank
bgp
F1D1 A, (0798-19C\008F0801.D)
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19D.S
E:\HPCHEM\TELLER\METHODS\0798-19A.M
8/3/98 3:07:34 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19D.M
8/10/98 4:33:19 PM by bgp
8
8
1
counts
45000 -
40000 -
35000
30000 -
25000 -
20000 -
15000 -;
loooo -:
5000 -
0
10
15
20
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FID1 A,
Signal
8/10/98 4:32:29 PM
1.0000
1.0000
RetTime Type Area Amt/Area Amount Grp Name
[min] counts*s [ug/kg]
i __ 1 __
1 1
1.463
5.391
7.373
9.161
9.323
9.460
10.084
10.379
. Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals :
0.00000
Results obtained with enhanced integrator!
2 Warnings or Errors :
Warning
Warning
Calibration warnings (see calibration table listing)
Calibrated compound(s) not found 1 OB
eller 8/10/98 4:38:19 PM bgp
Page 1 of 2
-------
Data File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19C\008F0802.D
reagent blank
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
FID1A, (0798-19C\008F0802.D)
8/4/98 9:40:22 PM
reagent blank
bgp
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19D.S
E:\HPCHEM\TELLER\METHODS\0798-19A.M
8/3/98 3:07:34 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19D . M
8/10/98 4:33:19 PM by bgp
8
8
2
2 Ml
counts
45000
40000 -
35000
30000 -
25000 -
20000 -
15000 -
10000
5000 -
-------
lata File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19C\002F1201.D gc-14 pg 53 #2
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
rx;
8/5/98 1:10:00 AM
gc-14 pg 53 #2
bgp
HDl A, (0798-19C\002FI20C
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19D . S
E:\HPCHEM\TELLER\METHODS\0798-19A.M
8/3/98 3:07:34 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19D.M
8/10/98 4:33:19 PM by bgp
rmrrrTO —
12
2
1
2 fj.1
counts -
6000 -
5500 -
5000 -
4500 -
4000 -
3500 -_
3000 -;
2500 ^
2000 -
S 3
3 -..
* mi
e
so
o
10
20
.mm
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FID1 A,
Signal
8/10/98 4:32:29 PM
1.0000
1.0000
RetTime
[min]
1.465
5.406
7.389
9.176
9.338
9.475
10.099
10.393
Type
BV
VP
BP
BV
W
VB
BV
VB
Area
count s*s
1.92377e4
2. 27607e4
2 .2923764
2 .3005064
2.2996964
2.2960764
2.1042064
2.3548764
Amt/Area
8.215486-4
7.40331e-4
7.28287e-4
7.246726-4
7.308226-4
7.279286-4
7.903966-4
7.042206-4
Amount G
[ug/kg].
15.80466
16.85048
16.69503
16.67105
16.80664
16.71375
16.63152
16.58347
rp Name
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals :
132.75661
Results obtained with enhanced integrator!
1 Warnings or Errors :
Warning : Calibration warnings (see calibration table listing)
8/10/98 4:40:10 PM bgp
TQS
Page l of 2
-------
Data File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19C\002F1202.D gc-14 pg 53 #;
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last chanqed
8/5/98 1:40:02 AM
gc-14 pg 53 #2
bgp
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19D.S
E:\HPCHEM\TELLER\METHODS\0798-19A.M
8/3/98 3:07:34 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19D.M
8/10/98 4:33:19 PM by bgp
12
2
2
FID1 A, (0798-19C\002F1202.D)
counts - „ — ., ui „„
~ S 2
; I *'
u
1
=
-------
ata File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19C\003F1301.D gc-14 pg 53 #3
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
??
rsr
MU1 A, (U7y«-19C\003F1301.D)
8/5/98 2:09:53 AM Seq. Line
gc-14 pg 53 #3 Vial
bgp Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0 798-19D.S
E:\HPCHEM\TELLER\METHODS\0798-19A.M
8/3/98 3:07:34 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19D.M
8/10/98 4:33:19 PM by bgp
13
3
1
counts
12000
10000
8000 -
6000
4000
Tolu
.388
2000
10
15
20
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FID1 A,
Signal
8/10/98 4:32:29 PM
1.0000
1.0000
RetTime
[min]
1.465
5.406
7.388
9.176
9.338
9.474
10.098
10.393
Type
BB
VB
BB
BV
W
VB
BV
VB
Area
count s*s
4.73164e4
5.66121e4
5.73015e4
5.76857e4
5.75846e4
5. 74559e4
5.25911e4
5.88886e4
Am t/ Are a
8.444698-4
7.550616-4
7.417016-4
7.359936-4
7.428526-4
7.400036-4
8.041686-4
7.159136-4
Amount
[ug/kg]
39.95728
42 .74560
42.50061
42.45628
42.77683
42.51755
42.29204
42.15913
Grp Name
- 1
1 ~- ~- ~ -
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals :
337.40531
Results obtained with enhanced integrator!
1 Warnings or Errors :
Warning : Calibration warnings (see calibration table listing)
H
2ller 8/10/98 4:40:35 PM bqp
110
Page 1 of 2
-------
Data File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19C\003F1302.D
gc-14 pg 53 #;
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
25!
re;
8/5/98 2:39:49 AM
gc-14 pg 53 #3
bgp
FIDl A, (0798-19O003F1302.D)
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19D.S
E:\HPCHEM\TELLER\METHODS\0798-19A.M
8/3/98 3:07:34 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19D.M
8/10/98 4:33:19 PM by bgp
13
3
2
counts
10000
8000 -
6000 -
4000 -
2000 -_
00 ' O
c\ oo
*o • oo
10
15
20
jmn
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FIDl A,
Signal
8/10/98 4:32:29 PM
1.0000
1.0000
RetTime
[min]
1.465
5.405
7.388
9.174
9.336
9.473
10.097
10.392
Type
_ _
BV
VB
BB
BV
W
VB
BV
VB
Area
counts* s
4.69837e4
5. 61973e4
5.68241e4
5.7178464
5.7062264
5.6987464
5.2120164
5. 8397764
Amt/Area
8.44358e-4
7.54988e-4
7.41626e-4
7.35927e-4
7.42779e-4
7.39937e-4
8.04085e-4
7.15847e-4
Amount
[ug/kg]
_ _
39.67107
42.42826
42.14223
42.0*7912
42.38461
42.16712
41.90899
41.80383
Grp Name
_ I
1
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals :
334.58522
Results obtained with enhanced integrator!
I Warnings or Errors :
Warning : Calibration warnings (see calibration table listing)
ill
Paqe 1 of 2
-------
ata File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19C\001F2601.D gc-14 pg 53 #1
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
8/5/98 3:36:53 PM
gc-14 pg 53 #1
bgp
counts
3500 -
3000 -
HD1A, (0798-19C\001F2601.D)
s »• i
*"* CO
\
un '
Sea. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19D.S
E:\HPCHEM\TELLER\METHODS\0798-19B.M
8/3/98 3:08:36 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19D.M
8/10/98 4:33:19 PM by bgp
26
1
1
2500 -
- S i
2000 - -
10
15
20
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FID1 A,
Signal
8/10/98 4:32:29 PM
1.0000
1.0000
RetTime
[min]
1.465
5.388
7.371
9.158
9.321
9.457
10.081
10.377
Type
PP
VB
BB
BV
W
VB
BB
BB
Area
count s*s
1 _ __ __
1
9892.75000
1.17021e4
1. 17243e4
1.18427e4
1.17606e4
1. 17522e4
1.08340e4
1.2024764
Am t/ Are a
_ _
7.85061e-4
7.17051e-4
7.06929e-4
7.06923e-4
7.11686e-4
7.08745e-4
7.68766e-4
6.855466-4
Amount G
[ug/kg]
7.76642
8.39096
8.28823
8.37186
8.36987
8.32933
8.32882
8.24348
rp Name
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals :
66.08898
Results obtained with enhanced integrator!
1 Warnings or Errors :
Warning : Calibration warnings (see calibration table listing)
filler 8/10/98 4:46:22 PM bqp
Page 1 of 2
-------
Data File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19C\001F2602.D gc-14 pg 53 #1
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
8/5/98 3:53:57 PM
gc-14 pg 53 #1
bgp
FIDl A. (0798-19C\001F2602.D)
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19D . S
E:\HPCHEM\TELLER\METHODS\0 7 9 8 -19B.M
8/3/98 3:08:36 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19D.M
8/10/98 4:33:19 PM by bgp
r^ivnn T%^ ' ' "
26
1
2
counts
c
u
ca
3500 -
3000 -
2500 -
10
15
20
mm
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FIDl A,
Signal
8/10/98 4:32:29 PM
1.0000
1.0000
RetTime
[min]
-- --
1.462
5.389
7.371
9.157
9.320
9.457
10.081
10.376
Type
BP
VB
BB
BV
W
VB
BV
VB
Area
counts*s
1.01062e4
1.1945964
1. 19909e4
1. 2046164
1. 20123e4
1. 20167e4
1.1093464
1. 23312e4
Amt/Area
I
1
7.866486-4
7.180296-4
7.079016-4
7.075416-4
7.12506e-4
7.096106-4
7. 698096-4
6.864956-4
Amount
[ug/kg]
7.94999
8.57749
8.48834
8.52309
8.55882
8.52717
8.53981
8.46530
Grp Name
i _ _
~ ~ 1
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals
67.63002
Results obtained with enhanced integrator!
1 Warnings or Errors :
Warning : Calibration warnings (see calibration table listing)
113
t _ i 1 — —
f c\ a A . A C . ^ A TDM V^
-------
Data File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19C\002F2701.D gc-14 pg 53 #2
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
jgj
TK
counts ;
6000 -|
5500 -:
5000 -
4500 -
4000
3500 -
3000 -
2500 -
2000 -
0
FIDi A, (0798-19C\002F2701.D)
S
3
8/5/98 4:10:57 PM Seq. Line
gc-14 pg 53 #2 Vial
bgp Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19D.S
E:\HPCHEM\TELLER\METHODS\0 798-19B.M
8/3/98 3:08:36 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19D.M
8/10/98 4:33:19 PM by bgp
27
2
1
§
l
•p
o*
»n
90
10
15
20
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FIDI A,
Signal
8/10/98 4:32:29 PM
1.0000
1.0000
RetTime
[min]
1
5
7
9
9
9
10
10
.460
.387
.369
.156
.319
.455
.079
.375
Type Area
counts*s
I
BP
VB
BB
BV
W
VB
BV
VP
i
1
2
2
2
2
2
2
2
. 96048e4
.3405764
.3513064
.35986e4
.3614464
.3533364
.15492e4
.4130264
Amt/Area
1 ' '
8
7
7
7
7
7
7
7
.22271e-
.41010e-
.288486-
.251466-
.313456-
.284176-
.909376-
.04689e-
i
4
4
4
4
4
4
4
4
Amount Grp Name
[ug/kg]
._ _ i
15
17
17
17
17
17
17
17
.12050
.34382
.13742
.11246
.27028
.14207
.04408
.00432
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals :
136.17496
Results obtained with enhanced integrator!
1 Warnings or Errors :
Warning : Calibration warnings (see calibration table listing)
>
Teller 8/10/98 4:46:46 PM bgp
114
Page 1 of 2
-------
Data File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19C\002F2702.D gc-14 pg 53 #:
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
8/5/98 4:27:55
gc-14 pg 53 #2
bgp
PM
Seq. Line
Vial
Inj
Inj Volume
E:\HPCKEM\TELLER\SEQUENCE\0798-19D.S
E:\HPCHEM\TELLER\METHODS\0798-19B.M
8/3/98 3:08:36 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798 -19D.M
8/10/98 4:33:19 PM by bgp
27
2
2
FIDl A, (0798-19C\002F2702.D)
counts : S $ „ S j|
6000 - I £ 5 1 1
• c 3 a)
•? m f-> S
5500 ^ i , f
5000 T - | rf 1
4500 ~ \ ' i 3
4000 - ! ! j
: ! .1 >|
3500 -_ : i
i
3000 : S
w-i
7<(V) [- i Cv
-jw - o\ w-i
: o -
— 00
2000 - . , ,
:
|||
J Oo
l:\
\ .•
I ;
10
15
20
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FIDl A,
Signal
8/10/98 4:32:29 PM
1.0000
1.0000
RetTime
[min]
1.460
5.385
7.367
9.155
9.317
9.454
10.078
10.374
Type
BP
VB
BB
BV
W
VB
BV
VB
Area
counts*s
1
1.96589e4
2.35329e4
2. 37342e4
2. 38620e4
2.38921e4
2.3830864
2.1843164
2. 4433164
Am t/ Are a
8.223766-4
7.411396-4
7.290516-4
7.253486-4
7.315726-4
7.286626-4
7.912386-4
7.049256-4
Amount
[ug/kg]
16.16696
17.44118
17.30346
17.30825
17.47876
17.36458
17.28313
17.22352
Grp Name
__i
__ 1 _
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals :
137.56984
Results obtained with enhanced integrator!
1 Warnings or Errors :
Warning : Calibration warnings (see calibration table listing)
1 or- fl/in/QR 4-46-^8 PM bCTD
115
Page 1 of 2
-------
ata File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19C\003F2801.D ' gc-14 pg 53 #3
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
8/5/98 4:45:27 PM
gc-14 pg 53 #3
bgp
FID1 A, <0798-19C\003F2801.D)
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19D.S
E:\HPCHEM\TELLER\METHODS\0798-19B.M
8/3/98 3:08:36 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19D.M
8/10/98 4:33:19 PM by bgp
28
3
1
counts -
12000 -
10000 -
8000 -
6000 -
4000 -
s2
3
2000
10
15
20
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FID1 A,
Signal
8/10/98 4:32:29 PM
1.0000
1.0000
RetTime
[min]
1.461
5.385
7.366
9.155
9.317
9.453
10.077
10.373
Type
BP
VP
BB
BV
W
VB
BV
VB
Area
count s*s
4.9490964
5.94979e4
5.99434e4
6.01167e4
6.00323e4
5. 9907le4
5.4783164
6.1355364
Am t/ Are a
_ i
1
8.45159e-4
7.55542e-4
7.42095e-4
7.362976-4
7.431786-4
7.403326-4
8.045356-4
7.162266-4
Amount
[ug/kg]
41.82766
44.95313
44 .48376
44.26373
44 .61470
44.35114
44.07496
43 .94430
Grp Name
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals :
352.51337
Results obtained with enhanced integrator!
1 Warnings or Errors :
Warning : Calibration warnings (see calibration table listing)
slier 8/10/98 4:47:09 PM bqp
115
Page 1 of 2
-------
Data File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19C\003F2802.D gc-14 pg 53 #:
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
FIDl A. (0798-19C\003F7802
8/5/98 5:02:54 PM
gc-14 pg 53 #3
bgp
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19D.S
E:\HPCHEM\TELLER\METHODS\0798-19B.M
8/3/98 3:08:36 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19D.M
8/10/98 4:33:19 PM by bgp
u*yy?v5~i^ * ~ ~
28
3
2
counts -
12000 -
10000 -
8000 -
6000 -
3 s;
* is
4000 -
I
2000 -
10
15
20
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FID1 A,
Signal
8/10/98 4:32:29 PM
1.0000
1. 0000
RetTime
[min]
1.459
5.383
7.365
9.154
9.316
9.452
10.076
10.372
Type
BP
VB
BB
BV
W
VB
BV
VB
Area
count s*s
4.93526e4
5.94520e4
6.00325e4
6.02789e4
6.02093e4
6.00765e4
5.50062e4
6.16074e4
Am t/ Are a
8.45117e-4
7.55534e-4
7.421086-4
7.363166-4
7.432016-4
7.403546-4
8.045716-4
7.162576-4
Amount G
[ug/kg]
41.70870
44.91803
44.55063
44.38435
44.74761
44.47789
44.25640
44.12672
rp Name
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals :
353.17033
Results obtained with enhanced integrator!
1 Warnings or Errors :
Warning : Calibration warnings (see calibration table listing)
m_i T ^^.
n /QQ
DM T-irrn
Paqe
-------
>ata File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19C\004F2901.D gc-14 pg 53 #4
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
8/5/98 5:19:54
gc-14 pg 53 #4
bgp
FIDl A, (0798-19C\004F2901.D)
PM Seq. Line
Vial
Inj
Inj Volume
E : \HPCHEM\TELLER\SEQUENCE\0798-19D.S
E:\HPCHEM\TELLER\METHODS\0798-19B.M
8/3/98 3:08:36 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19D.M
8/10/98 4:33:19 PM by bgp
29
4
1
counts -
45000 ^
40000 ^
35000 - j
M
30000 \ 3
T
25000 -_
20000 -_
15000 -
10000 -_
5000 - 1
5 a
*? "6
S
fi
<~
10
15
20
J11U1'
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FIDl A,
Signal
8/10/98 4:32:29 PM
1.0000
1.0000
RetTime
[min]
1.458
5.384
7.366
9.153
9.316
9.452
10.076
10.372
Type
BP
VB
BB
BV
W
VB
BV
VB
Area
counts* s
1
1.00341e5
1. 20798e5
1.2205565
1. 2276365
1.22584e5
1.2218465
1. 11941e5
1.2536165
Amt/Area
1
1
8.527686-4
7.60324e-4
7.46447e-4
7.399746-4
7.47093e-4
7.442616-4
8.090386-4
7.200456-4
Amount
[ug/kg]
85.56799
91.84564
91.10732
90.84131
91.58164
90.93695
90.56470
90.26525
Grp Name
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals :
722.71081
Results obtained with enhanced integrator!
1 Warnings or Errors :
Warning : Calibration warnings (see calibration table listing)
eller 8/10/98 4:47:33 PM bop
118
Page 1 of 2
-------
Data File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19C\004F2902.D gc-14 pg 53 #
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
8/5/98 5:37:21 PM
gc-14 pg 53 #4
bgp
FID1A. (UW8-19C\004K9()2.U>)
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19D.S
E:\HPCHEM\TELLER\METHODS\0798-19B.M
8/3/98 3:08:36 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19D.M
8/10/98 4:33:19 PM by bgp
29
4
2
counts -
45000 -,
40000 -^
35000 ^
I
30000 -j
25000 :
20000 -_
15000 -
-
10000 -f
5000 -
J-
0 -
0_
g
«
X
u
"™"
Cv
w-i
^
— •
1 '
— ,
u g
jjjf "5L
u ss, &<
Sy T ' £
— fT^fi s i
u o , ^j^.,
c _io!, ****
cfl ' "So ^Cu-;
**" u-i — ^; r;—
' en ^^ ^ '
fM • i u O '
oo r- ] — .
n : V |
«n '
[J i
:; if I 1 i
§!: s '" •'•
"i * i :
5 .10
15
20
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FID1 A,
Signal
8/10/98 4:32:29 PM
1.0000
1.0000
RetTime
[min]
1.459
5.382
7.365
9.153
' 9.315
9.451
10.076
10.371
Type
BP
VB
BB
BV
W
VB
BV
VB
Area
count s*s
I
1
1.00275e5
1.2046465
1. 2139665
1.21982e5
1.2178365
1.2152365
1. 11223e5
1.2456165
Amt/Area
8.52763e-4
7.603116-4
7.464246-4
7.399526-4
7.470696-4
7.442416-4
8.090106-4
7.200216-4
Amount Grj
[ug/kg]
85.51103
91.58992
90.61259
90.26043
90.98017
90.44265
89.98031
89.68640
5 Name
Hexa-ne
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals :
719.06352
Results obtained with enhanced integrator!
1 Warnings or Errors :
Warning : Calibration warnings (see calibration table listing)
PM ban
119
Page 1 of 2
-------
Data File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19C\005F3001.D gc-14 pg 53 #5
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
8/5/98 5:54:26 PM
gc-14 pg 53 #5
bgp
FTO1A, (0798-19C\005F3001.D)
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19D.S
E:\HPCHEM\TELLER\METHODS\0798-19B.M
8/3/98 3:08:36 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19D.M
8/10/98 4:33:19 PM by bgp
30
5
1
2 il
counts _
50000 -
40000 -
30000 -
20000 -
7 s
»
p"l
Vv
3
1!
10000 -
10
15
20
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FID1 A,
Signal
8/10/98 4:32:29 PM
1.0000
1.0000
RetTime
[min]
1.457
5.382
7.364
9.152
9.315
9.452
10.075
10.371
Type
BP
VB
BB
BV
W
VB
BV
VB
Area
counts* s
2.40122e5
2.89426e5
2.92052e5
2.93213e5
2. 9246165
2.92304e5
2.67238e5
2.99443e5
Amt/Area
_ 1
8.570796-4
7.63028e-4
7.488916-4
7.420266-4
7.492766-4
7.464616-4
8.115456-4
7.221726-4
Amount G
[ug/kg]
205.80309
220.84041
218.71496
217.57124
219.13377
218.19350
216.87590
216.24938
rp Name
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals :
1733.38226
Results obtained with enhanced integrator!
1 Warnings or Errors :
Warning : Calibration warnings (see calibration table listing)
*1
Teller 8/10/98 4:47:57 PM bqp
t20
Page 1 of 2
-------
Data File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19C\005F3002.D
gc-14 pg 53 #!
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
??
FAT
8/5/98 6:11:30 PM
gc-14 pg 53 #5
bgp
counts -
FUJI A, (0798-19C\005F3002.D)
|
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19D.S
E:\HPCHEM\TELLER\METHODS\0798-19B.M
8/3/98 3:08:36 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19D.M
8/10/98 4:33:19 PM by bgp
30
5
2
2 /xl
50000 -
40000 -
30000
20000 -
10000 -
a.
va>
•
-------
Data File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19C\006F3101.D gc-14 pg 53 #6
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
8/5/98 6:28:36 PM
gc-14 pg 53 #6
bgp
FED1 A, (0798-19C\006F3101.U)
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19D.S
E:\HPCHEM\TELLER\METHODS\0798-19B.M
8/3/98 3:08:36 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19D.M
8/10/98 4:33:19 PM by bgp
31
6
1
counts
100000 -
80000 -
60000
40000 -
00
n
-------
Data File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19C\006F3102.D gc-14 pg 53 #
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
FID1A, (0798-19C\006F3102.D)
8/5/98 6:45:39 PM
gc-14 pg 53 #6
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19D.S
E:\HPCHEM\TELLER\METHODS\0798-19B.M
8/3/98 3:08:36 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19D.M
8/10/98 4:33:19 PM by bgp
31
6
2
counts
100000 -
80000
60000
40000 -
20000 -
o--
0
10
15
20
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FID1 A,
Signal
8/10/98 4:32:29 PM
1.0000
1.0000
Ret Time
[mini
1.459
5.383
7.367
9.154
9.317
9.454
10.078
10.373
Type
BB
VB
BB
BV
W
VB
BV
VB
Area
count s*s
4.80723e5
5. 77425e5
5.80793e5
5. 8318665
5.8134965
5.7974065
5.3079065
5.94669e5
Amt/Area
8.58628e-4
7.63995e-4
7.49764e-4
7.427606-4
7.500596-4
7.472446-4
8.124436-4
7.22933e-4
Amount Grj
[ug/kg]
412.76189
441.14983
435.45779
433.16706
436.04611
433.20733
431.23688
429.90611
3 Name
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals :
3452.93302
Results obtained with enhanced integrator!
1 Warnings or Errors :
Warning : Calibration warnings (see calibration table listing)
123
o /1 n / o o /i . /to. TO DM Virrn
Paqe 1 of 2
-------
Data File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19C\007F3201.D gc-14 pg 53 #7
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
FIDl A, (0798-19C\007F3201.D)
8/5/98 7:03:14 PM
gc-14 pg 53 #7
bgp
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19D.S
E:\HPCHEM\TELLER\METHODS\0798-19B.M
8/3/98 3:08:36 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19D.M
8/10/98 4:33:19 PM by bgp
32
7
1
2 [J.I
counts -
200000 -j
175000 -]
150000 -
125000 -_
100000 -_
75000 ^
50000 -
25000 -_
0--
0
§
1
U
CO
1
-
O' C
f^l. 3C
— - CV
10
15
20
_nun'
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FID1 A,
Signal
8/10/98 4:32:29 PM
1.0000
1.0000
RetTime
[minj
1.460
5.383
7.366
9.156
9.318
9.455
10.079
10.374
Type
VB
VB
BB
BV
W
VB
BV
VB
Area
counts*s
9.15150e5
1.10075e6
1.11061e6
1.11818e6
1.1152166
1. 1119466
1.0203166
1. 14142e6
Amt/Area
8.59361e-4
7.64456e-4
7.50185e-4
7.43116e-4
7.50438e-4
7.476256-4
8.128796-4
7.233036-4
Amount
[ug/kg]
786.44437
841.47744
833.16451
830.93727
836.89699
831.31312
829.38751
825.59503
Grp Name
- - 1
1
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals :
6615.21624
Results obtained with enhanced integrator!
1 Warnings or Errors :
Warning : Calibration warnings (see calibration table listing)
£•
'eller 8/10/98 4:48:44 PM bgp
124
Page 1 of 2
-------
Data File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19C\007F3202.D gc-14 pg 53
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
¥
8/5/98 7:20:16 PM
gc-14 pg 53 #7
bgp
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19D.S
E:\HPCHEM\TELLER\METHODS\0798-19B.M
8/3/98 3:08:36 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19D.M
8/10/98 4:33:19 PM by bgp
32
7
2
FID I
(0798-19C1007F32U2. D)
counts -
200000 -
175000 -
150000 :
125000 -I
100000 -"
75000 -_
50000 -:
25000 -;
0--
3
nn
r*
o, o
m oo
o
10
15
20
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FID1 A,
Signal
8/10/98 4:32:29 PM
1. 0000
1.0000
RetTime
[min]
_ _ __
1.458
5.383
7.366
9.157
9.319
9.456
10.078
10.374
Type
VB
VB
BB
BV
W
VB
BV
VB
Area
counts*s
9.16961e5
1. 10659e6
1. 12023e6
1. 13027e6
1.1287666
1.1224966
1.0320166
1.15395e6
Amt/Area
8.593636-4
7.644596-4
7.501886-4
7.431206-4
7.50443e-4
7.476296-4
8.128856-4
7.233076-4
Amount Grj
[ug/kg]
__ __ __ \ _ _
1
788.00214
845.94169
840.38516
839.92771
847.06971
839.20411
838.90201
834.65808
3 Name
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals :
6674.09060
Results obtained with enhanced integrator!
1 Warnings or Errors :
Warning : Calibration warnings (see calibration table listing)
« i— *•• TMl *
-------
Data File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19C\008F3301.D reagent blank
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
8/5/98 7:37:22 PM
reagent blank
bgp
FIDl A, (0798-19C\008t3301.D)
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19D.S
E:\HPCHEM\TELLER\METHODS\0798-19B.M
8/3/98 3:08:36 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19D.M
8/10/98 4:33:19 PM by bgp
33
8
1
counts .
2300 -
2200 -
2100
2000
1900 -
10
15
20
join
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FIDl A,
Signal
8/10/98 4:32:29 PM
1.0000
1.0000
RetTime Type Area Amty
[min] counts*s
1.463
5.391
7.373
9.161
9.323
9.460
10.084
10.379
Totals :
/Area Amount Grp Name
[ug/kg]
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
0.00000
Results obtained with enhanced integrator!
2 Warnings or Errors :
Warning : Calibration warnings (see calibration table listing)',?-
Warning : Calibrated compound(s) not found
Teller 8/10/98 4:49:08 PM
Page 1 of 2
-------
Data File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19C\008F3302.D
reagent blanl
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
8/5/98 7:54:51 PM
reagent blank
bgp
counts
2300 -
FID 17^, (079s-19C\008F3302JJ)
QO O
m m
Seq. Line
Vial
Inj
Inj Volume
E : \HPCHEM\TELLER\SEQUENCE\0798-19D.S
E:\HPCHEM\TELLER\METHODS\0798-19B.M
8/3/98 3:08:36 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19D.M
8/10/98 4:33:19 PM by bgp
33
8
2
2200 -
1800 -
10
15
20
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FID1 A,
Signal
8/10/98 4:32:29 PM
1.0000
1.0000
RetTime Type Area
[min] counts*s
1 _
1.463
5.391
7.373
9.161
9.323
9.460
10.084
10.379
Amt/Area Amount
[ug/kg]
_
-
-
-
-
Grp Name
_ I _
I
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals :
0.00000
Results obtained with enhanced integrator!
2 Warnings or Errors :
Warning : Calibration warnings (see calibration table listing)
Warning : Calibrated compound(s) not found
127
Paqe 1 of 2
-------
Data File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19C\002F4101.D gc-14 pg 53 #2
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
8/6/98 2:46:09 AM
gc-14 pg 53 #2
bgp
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19D.S
E:\HPCHEM\TELLER\METHODS\0798-19B.M
8/3/98 3:08:36 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19D.M
8/10/98 4:33:19 PM by bgp
41
2
1
HD1 A, (0798-19C\002F4101.D)
counts -. . g, g
6000 - 1 «; 3
3 u
5500 - x
wm o*
5000 - £
4500 - , j
4000 -j
3500 - ' l
3000 ^ 2!
2500 ^ - ' '
2000 ~ 1,1
:
0 5
2 <£
u i
3 S
? i
« i
" 1
: i
i!
1 1
o
06
\
I ||
r ^
E <->«!,
1 ^*^)
h!
i;!
i
10 15 20 min
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FID1 A,
Signal
8/10/98 4:32:29 PM
1.0000
1.0000
RetTime
[min]
1.458
5.379
7.361
9.149
9.311
9.448
10.072
10.367
Type
BP
VP
BB
BV
W
VB
BV
VB
Area
counts*s
i
1
1. 98031e4
2.36562e4
2. 3918464
2. 4100364
2. 4118264
2. 40242e4
2.2022664
2.4624864
Amt/Area
8.22651e-4
7 .41263e-4
7.292176-4
7.25528e-4
7.317536-4
7.288186-4
7.914186-4
7.050716-4
Amount G
[ug/kg]
16.29107
17.53549
17.44174
17.48546
17.64856
17.50927
17.42909
17.36227
rp Name
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals :
138.70295
Results obtained with enhanced integrator!
1 Warnings or Errors :
Warning : Calibration warnings (see calibration table listing^
eller 8/10/98 4:52:42 PM bgp
Page 1 of 2
-------
Data File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19C\002F4102.D gc-14 pg 53 #
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
g
A,
8/6/98 3 :02:56 AM
gc-14 pg 53 #2
bgp
counts ~
6000 -;
5500 -
5000 -
4500 -f
4000 -"
3500 -
3000 -;
2500 ~
2000 -
(0798-19C\002F4102. D)
CTV g
• u
fM • y
Seq. Line
Vial
Inj
Inj Volume
E : \HPCHEM\TELLER\SEQUENCE\0798-19D . S
E:\HPCHEM\TELLER\METHODS\0798-19B.M
8/3/98 3:08:36 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19D.M
8/10/98 4:33:19 PM by bgp
41
2
2
I
0
10
15
20
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FID1 A,
Signal
8/10/98 4:32:29 PM
1.0000
1.0000
RetTime
[min]
1.456
5.377
7.359
9.146
9.309
9.445
10.069
10.365
Type
BP
VP
BB
BV
W
VB
BV
VB
Area
counts*s
2.00435e4
2 .3946464
2. 41049e4
2.4257064
2. 42205e4
2.4213864
2.2175764
2.4795664
Amt/Area
I
8.231016-4
7.41551e-4
7.29383e-4
7.25644e-4
7.318346-4
7.289696-4
7.915706-4
7.052006-4
Amount
[ug/kg]
16.49779
17.75746
17.58170
17.60196
17.72541
17.65107
17.55365
17.48588
Grp Name
_ 1
1
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals :
139.85492
Results obtained with enhanced integrator!
1 Warnings or Errors :
Warning : Calibration warnings (see calibration table listing)
fl/in/oa
PM hern
129
Pacre 1 nf ?
-------
ata File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19C\003F4201.D gc-14 pg 53 #3
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
8/6/98 3:20:15 AM
gc-14 pg 53 #3
bgp
FIDl A. (0798-19C\003F420m>
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19D.S
E:\HPCHEM\TELLER\METHODS\0798-19B.M
8/3/98 3:08:36 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19D.M
8/10/98 4:33:19 PM by bgp
42
3
1
counts -
12000 -
10000 -
8000 -
6000 -
I 5
cd .
5 rMi
4000 -
2000 -_
10
15
20
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FIDl A,
Signal
8/10/98 4 :32 :29 PM
1.0000
1.0000
RetTime
[min]
1.454
5.373
7.355
9.142
9.305
9.442
10.065
10.361
Type
BP
VB
BB
BV
W
VB
BV
VB
Area
count s*s
5.0797464
6.11546e4
6.20564e4
6. 25570e4
6.24251e4
6.23966e4
5.7063464
6.39282e4
Amt/Area
_ 1
1
8.455456-4
7.55797e-4
7.42387e-4
7.36578e-4
7.434726-4
7.406406-4
8.048886-4
7.165276-4
Amount Grj
[ug/kg]
42.95150
46.22047
46.06985
46.07809
46.41135
46.21342
45.92965
45.80631
3 Name
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals :
365.68064
Results obtained with enhanced integrator!
1 Warnings or Errors :
Warning : Calibration warnings (see calibration table listing)
1 1 f*r fl/in/Qfi
PM boo
1 of
-------
Data File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19C\003F4202.D gc-14 pg 53
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
FTOi A, (0798-19C\003F4202.D)
8/6/98 3:37:03 AM
gc-14 pg 53 #3
bgp
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19D.S
E:\HPCHEM\TELLER\METHODS\0798-19B.M
8/3/98 3:08:36 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19D.M
8/10/98 4:33:19 PM by bgp _
42
3
2
counts
12000 -
10000 -
8000 -
6000
4000 -
«
3
2000
10
15
20
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FIDl A,
Signal
8/10/98 4:32:29 PM
1.0000
1.0000
RetTime
[min]
1
5
7
9
9
9
10
10
.454
.372
.354
.142
.304
.440
.065
.360
Type Area
counts *s
. _ . I _
BP
VB
BB
BV
W
VB
BV
VB
1
5
6
6
6
6
6
5
6
.09829e4
.1434264
.2412964
.2946064
.2985164
.2725164
.7505264
.43890e4
Amt/Area
1 - 1 -
1
8
7
7
7
7
7
8
7
.455996-
l
4
.558396-4
.424346-
.366216-
.435386-
.406786-
.049536-
.165796-
4
4
4
4
4
4
Amount Grp Name
[ug/kg]
43
46
46
46
46
46
46
46
l
.11106
.43431
.33747
.36732
.83184
.45915
.28893
.13977
1
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals :
367.96986
Results obtained with enhanced integrator!
1 Warnings or Errors :
Warning : Calibration warnings (see calibration table listing)
131
Pacr<= 1 of 2
-------
ita File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19C\005F4401.D gc-14 pg 53 #5
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
ig<
rs:
8/6/98 4:27:29 AM
gc-14 pg 53 #5
bgp
FIDl A, (0798-19C\005F4401.D)
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0 7 9 8 -19D . S
E:\HPCHEM\TELLER\METHODS\0798-19B.M
8/3/98 3:08:36 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19D.M
8/10/98 4:33:19 PM by bgp
44
5
1
counts
50000 -
40000 -
30000 -
20000 -
S
i
10000 -
0-
8
10
15
20
External Standard Reoort
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FIDl A,
Signal
8/10/98 4:32:29 PM
1.0000
1.0000
RetTime
[min]
1.453
5.370
7.351
9.140
9.302
9.439
10.063
10.358
Type
BP
VB
BB
BV
W
VB
BV
VB
Area
count s*s
2.50274e5
3 .0091365
3 .0491965
3.0731365
3.0689565
3.0587765
2.8024765
3.1406365
Amt/Area
i _ i
1 1
8.57204e-4
7.63102e-4
7.48965e-4
7.420936-4
7.49350e-4
7.46531e-4
8.116296-4
7.222446-4
Amount G
[ug/kg]
214.53571
229.62719
228.37346
228.05477
229.97146
228.34691
227.45668
226.82992
rp Name
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals :
1813.19610
Results obtained with enhanced integrator!
1 Warnings or Errors :
Warning : Calibration warnings (see calibration table listing)
3«
>.ller 8/10/98 4:53:53 PM bom
132
Paae 1 of 2
-------
Data File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19C\005F4402.D gc-14 pg 53 #5
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
8/6/98 4:44:17 AM
gc-14 pg 53 #5
bgp
FIDl A, (0798-19C\005F44tf2TD7
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19D.S
E:\HPCHEM\TELLER\METHODS\0798-19B.M
8/3/98 3:08:36 PM by bgp
E : \HPCHEM\TELLER\METHODS\0798-19D.M
8/10/98 4:33:19 PM by bgp
44
5
2
50000 -
40000 -
30000 -
20000 -
10000 -
(N
TT
ad
10
15
20
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FIDl A,
Signal
8/10/98 4:32:29 PM
1.0000
1.0000
RetTime
[min]
1.452
5.369
7.350
9.138
9.301
9.437
10.061
10.357
Type
BP
VB
BB
BV
W
VB
BV
VB
Area
count s*s
1
1
2.50300e5
3.01311e5
3. 05927e5
3.08694e5
3 .0800565
3.07228e5
2.8147965
3 .1544965
Amt/Area
8.57205e-4
7.631056-4
7.489716-4
7.421006-4
7.493556-4
7.465386-4
8.116376-4
7.222506-4
Amount Grj
[ug/kg]
1 __
214.55852
229.93167
229.13046
229.08185
230.80493
229.35758
228.45903
227.83289
3 Name
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals :
1819.15693
Results obtained with enhanced integrator!
1 Warnings or Errors :
Warning : Calibration warnings (see calibration table listing)
133
n / -n /•> / n O A . C A - r\ C
Paae 1 of 2
-------
ita File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19C\003F5301.D gc-14 pg 53 #3
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last.changed
Analysis Method
Last changed
ig<
rx;
8/6/98 11:23:44 AM
gc-14 pg 53 #3
bgp
F1D1 A, (07y«-19C\0031-'5301.D)
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19D.S
E:\HPCHEM\TELLER\METHODS\0798-19B.M
8/3/98 3:08:36 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19D.M
8/10/98 4:33:19 PM by bgp
53
3
1
counts '
12000 -
10000 -
8000 -
6000 -
4000 -
co
2000 -_
10
15
20
mini
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FID1 A,
Signal
8/10/98 4:32:29 PM
1.0000
1.0000
RetTime
[min]
1.462
5.381
7.364
9.153
9.315
9.452
10.075
10.371
Type
BP
VB
BB
BV
W
VB
BV
VP
Area
count s*s
4.99256e4
6. 01662e4
6.1571464
6.2326364
6.2333064
6.2125664
5.6959964
6.3733364
Amt/Area
8.45290e-4
7.55646e-4
7.42322e-4
7.36552e-4
7.43461e-4
7.40607e-4
8.04872e-4
7.16505e-4
Amount Grj
[ug/kg]
_ __ I
42.20164
45 .46440
45.70580
45.90661
46.34222
46.01065
45.84548
45.66527
3 Name
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals :
363.14206
Results obtained with enhanced integrator!
1 Warnings or Errors :
Warning : Calibration warnings (see calibration table listing)""
r- R/in/qfl 4-=;7-i?fl PM hem
t-34
Paae 1 of 2
-------
Data File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19C\003F5302.D gc-14 pg 53 #3
Injection Date
Sample Name
Acq. Operator
8/6/98 11:40:59 AM
gc-14 pg 53 #3
bgp
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19D.S
E:\HPCHEM\TELLER\METHODS\0798-19B.M
8/3/98 3:08:36 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19D.M
53
3
2
Sequence File
Acq. Method
Last changed
Analysis Method ~. \~~ —.— \ v ,
Last changed 8/10/98 4:33:19 PM by bgp
FIDl A, (0798-19C\003F5302.D)
counts :
12000 -
10000 -
8000
6000 -
4000 -
2000 -_
oa
(2
1
10
15
20
mm
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FIDl A,
Signal
8/10/98 4:32:29 PM
1.0000
1.0000
RetTime
[min]
1.458
5.381
7.362
9.150
9.313
9.450
10.073
10.369
Type
BP
VP
BB
BV
W
VB
BV
VB
Area
count s*s
5. 04413e4
6.07557e4
6.1953464
6. 25815e4
6. 25698e4
6.23963e4
5. 7143564
6.3964564
Amt/Area
8.454426-4
7.557376-4
7.423736-4
7.365816-4
7.434896-4
7.406406-4
8.04899e-4
7.16531e-4
Amount G
[ug/kg]
42.64523
45.91533
45.99251
46.09634
46.51998
46.21318
45.99478
45.83257
rp Name
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals
365.20993
Results obtained with enhanced integrator!
1 Warnings or Errors :
Warning : Calibration warnings (see calibration table listing)
135
Darrp> 1 of ?
-------
ita File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19C\004F5401.D gc-14 pg 53 #4
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
rs;
8/6/98 11:57:57 AM
gc-14 pg 53 #4
bgp
FIDl A, "f079£T9C\004F540i.D)
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19D.S
E:\HPCHEM\TELLER\METHODS\0798-19B.M
8/3/98 3:08:36 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19D.M
8/10/98 4:33:19 PM by bgp
54
4
1
counts -
45000 -_
40000 -_
35000 -:
30000 -
25000 -
20000 -;
15000 -_
10000 -
5000 -
S
a
I
«. a?
I 6
£2
10
15
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FIDl A,
Signal
8/10/98 4:32:29 PM
1.0000
1.0000
RetTime
[min]
1.456
5.379
7.361
9.149
9.311
9.448
10.072
10.368
Type
BP
VB
BB
BV
W
VB
BV
VB
Area
counts*s
|
1. 03187e5
1.24076e5
1. 27499e5
1.2965265
1.2977565
1.29420e5
1.1873465
1.3274965
Amt/Area
j __
8.529726-4
7.60447e-4
7.46626e-4
7.40162e-4
7.47302e-4
7.44472e-4
8.09284e-4
7.2024&e-4
Amount
[ug/kg]
88.01538
94.35345
95.19395
95.96347
96.98086
96.34962
96.08996
95.61250
Grp Name
- 1 --
__l _
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals :
758.55918
Results obtained with enhanced integrator!
1 Warnings or Errors :
Warning : Calibration warnings (see calibration table listing)
slier 8/10/98 4:57:52 PM boo
136
Pacre 1 of 2
-------
Data File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19C\004F5402.D gc-14 pg 53 #4
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
8/6/98 12:14:49 PM
gc-14 pg 53 #4
bgp
FTOIA, (OTO8-19C\004F5402.D)
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19D.S
E:\HPCHEM\TELLER\METHODS\0798-19B.M
8/3/98 3:08:36 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19D.M
8/10/98 4:33:19 PM by bgp
54
4
2
counts
45000
40000
35000
30000
25000
20000
15000
10000
5000
0
1 8
Si S
ouu uS1
l»r si
SFB §.
'-*L ^o
$. -!
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FID1 A,
Signal
8/10/98 4:32:29 PM
i.OOOO
1.0000
RetTime
[min]
1.456
5.378
7.360
9.149
9.311
9.448
10.072
10.368
Type
BP
VB
BB
BV
W
VB
BV
VB
Area
counts*s
1. 0339565
1. 2462765
1.2848165
1.3081965
1.30931e5
1.30497e5
1.1988365
1.3398965
Amt/Area
8.52987e-4
7.604676-4
7.466576-4
7.401926-4
7.473336-4
7.445026-4
8.093236-4
7.202806-4
Amount G
[ug/kg]
88.19448
94.77463
95.93112
96.83092
97.84923
97.15542
97.02372
96.50965
rp Name
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals
764.26917
Results obtained with enhanced integrator!
1 Warnings or Errors :
Warning : Calibration warnings (see calibration table listing)
o/ir>/oo /i . c O . n O DM Virrr\
Paae 1 of 2
-------
ata File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19C\001F5901.D gc-14 pg 53 #1
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
F1D1 A
counts :
3750 -"
3500 -j
3250 -
3000
2750 -:
2500 -
2250 j
2000 -
1750 -
0
(0798-19C\001F5901.D)"
8
u
a
a
8/6/98 5:00:57 PM Seq. Line
gc-14 pg 53 #1 Vial
bgp Inj
Inj Volume
E : \HPCHEM\TELLER\SEQUENCE\0798-19D.S
E:\HPCHEM\TELLER\METHODS\0798-19B.M
8/3/98 3:08:36 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19D.M
8/10/98 4:33:19 PM by bgp
59
1
1
10
15
20
mm
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FID1 A,
Signal
8/10/98 4:32:29 PM
1.0000
1.0000
RetTime
[min]
1.462
5.392
7.375
9.162
9.325
9.461
10.084
10.380
Type
BP
VP
BB
BV
W
VB
BB
BB
Area
counts*s
9538.49316
1. 11561e4
1. 11073e4
1. 12084e4
1.1231364
1. 11514e4
1.03224e4
1.14369e4
Amt/Area
7.82272e-4
7.14706e-4
7.04501e-4
7.04853e-4
7.098406-4
7.066286-4
7.66556e-4
6.83585e-4
Amount
[ug/kg]
7.46169
7.97335
7.82513
7.90025
7.97241
7.87989
7.91267
7.81809
Grp Name
-- 1 -
__l
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals :
62.74348
Results obtained with enhanced integrator!
1 Warnings or Errors :
Warning : Calibration warnings (see calibration table listing)
198
n /1 « /on * . c r\ . c c TIM
Paae 1 of 2
-------
Data File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19C\001F5902.D' gc-14 pg 53 #1
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
FAT
8/6/98 5:17:59 PM
gc-14 pg 53 #1
bgp
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19D. S
E:\HPCHEM\TELLER\METHODS\0798-19B.M
8/3/98 3:08:36 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19D.M
8/10/98 4:33:19 PM by bgp
59
1
2
FIDI
(0798-1 9C\001 F5902.D)
counts :
3750 -
3500 -
3250 -
3000 -
2750 -
2500 -
2250 -
2000
1750 -
0
3
1
I
r~
i
r-
w^
od
10
15
20
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FIDI A,
Signal
8/10/98 4:32:29 PM
1.0000
1.0000
RetTime
[min]
1.461
5.390
7.372
9.160
9.322
9.459
10.082
10.378
Type
BB
BB
BB
BV
W
VB
BV
VB
Area
count s*s
9555.06152
1.10191e4
1.11801e4
1.1235964
1.12540e4
1.1202764
1.0342764
1.1501464
Amt/Area
i
1
7.82407e-4
7.140816-4
7.048016-4
7.049476-4
7.099226-4
7.06818e-4
7.666486-4
6.838106-4
Amount
[ug/kg]
7.47595
7.86851
7.87977
7.92068
7.98944
7.91828
7.92919
7.86480
Grp Name
__! _
1
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals :
62.84663
Results obtained with enhanced integrator!
1 Warnings or Errors :
Warning : Calibration warnings (see calibration table listing)
139
Paae 1 of
-------
ata File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19C\002F6001.D gc-14 pg 53 #2
Injection Date
'Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
BE
8/6/98 5:34:58 PM
gc-14 pg 53 #2
bgp
FTO1A, (0798-19C\002F600r.D)
t 3'
i «•
i
i
3
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19D.S
E:\HPCHEM\TELLER\METHODS\0798-19B.M
8/3/98 3:08:36 PM by bgp
E:\HPCHEM\TELLER\METHODS\0 798-19D.M
8/10/98 4:33:19 PM by bgp
ezn/\i T\^ * :^*
60
2
1
counts
5500
5000
4500
4000
3500 -
3000 -_
2500 -_
2000 -
.2
0
10
15
20
_mm
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FID1 A,
Signal
8/10/98 4:32:29 PM
1.0000
1.0000
RetTime
[min]
1.461
5.388
7.370
9.158
9.321
9.457
10.081
10.376
Type
BP
VP
BB
BV
W
VB
BV
VB
c
1
1
1
2
2
2
2
2
2
2
Area
ount s * s
.8834964
.2394264
.2502264
.2611964
.2591864
.2558564
.0670064
.3115264
1
1
8
7
7
7
7
7
7
7
Am t/ Are a
__ i
.207226-4
.39928e-4
.27868e-4
.243456-4
.304636-4
.275696-4
.899836-4
.038546-4
Amount G
[ug/kg]
15.45822
16.57008
16.37863
16.37883
16.50250
16.41285
16.32896
16.26972
rp Name
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals :
130.29980
Results obtained with enhanced integrator!
1 Warnings or Errors :
Warning : Calibration warnings (see calibration table listing)
Q/TD/QP
PM hero
140
Page 1 of 2
-------
Data File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19C\002F6002.D gc-14 pg 53 #2
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
rSr
8/6/98 5:52:03 PM
gc-14 pg 53 #2
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19D . S
E:\HPCHEM\TELLER\METHODS\0798-19B.M
8/3/98 3:08:36 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19D.M
8/10/98 4:33:19 PM by bgp
60
2
2
FIDl
(0798-I9C\002F6002..D)
counts -
5500 -
5000
4500
4000
3500 -
3000 -
2500 -
2000 -
S S
a """.
5 (H<
=>
3
0
10
15
20
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FIDl A,
Signal
8/10/98 4:32:29 PM
1.0000
1.0000
RetTime
[min]
1.462
5.388
7.370
9.158
9.320
9.457
10.081
10.377
Totals
Type
1
1
BP
VB
BB
BV
W
VB
BV
VP
.
Area
counts*s
1. 88527e4
2.24067e4
2.25652e4
2.26749e4
2. 27059e4
2.26387e4
2.07404e4
2.31923e4
Amt/Area
1
1
8.20759e-4
7.399426-4
7.279326-4
7.243986-4
7.305656-4
7.276426-4
7.900626-4
7.039206-4
Amount Gr^
[ug/kg]
i__
15.47350
16.57969
16.42589
16.42564
16.58811
16.47285
16.38620
16.32554
130.67741
5 Name
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Results obtained with enhanced integrator!
1 Warnings or Errors :
Warning : Calibration warnings (see calibration table listing)
Paae 1 of 2
-------
ata File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19C\003F6101.D
gc-14 pg 53
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
rx
8/6/98 6:09:05 PM
gc-14 pg 53 #3
bgp
FIDl A, (0798:i9C\003F6101.D)
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19D.S
E:\HPCHEM\TELLER\METHODS\0798-19B.M
8/3/98 3:08:36 PM by bgp
E:\HPCHEM\TELLER\METHODS\0 798-19D.M
8/10/98 4:33:19 PM by bgp
61
3
1
counts _
10000 -
8000 -
6000 -
4000
8
a
T>
_
(2
2000 -
10
15
20
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FIDl A,
Signal
8/10/98 4:32:29 PM
1.0000
1.0000
RetTime
[min]
1.461
5.388
7.370
9.158
9.320
9.457
10.081
10.376
Type
BB
BP
BB
BV
W
VB
BV
VB
Area
count s*s
4.5783564
5.48417e4
5.55141e4
5.5818964
5. 5752964
5.5654464
5.0945264
5.7034664
Amt/Area
8.43943e-4
7.54742e-4
7.41413e-4
7.35742e-4
7.425896-4
7.397436-4
8. 03871e-4
7.156606-4
Amount G
[ug/kg]
38.63867
41.39128
41.15891
41.06835
41.40151
41.16995
40.95336
40.81739
rp Name
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals :
326.59941
Results obtained with enhanced integrator!
1 Warnings or Errors :
Warning : Calibration warnings (see calibration table listing)
-K- fl/in/QR
PM
142
Page 1 of 2
-------
Data File.-£AHPCHEM\TELLER\DATA\1998\JUL98\0798-19C\003F6102.D gc-14 pg 53 #3
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
rK
FID1 A, (U798-19C\003F6102.D)
counts _ j qjji
'• 3 Si
10000 -
8000 -
6000
8/6/98 6:26:06 PM Seq. Line
gc-14 pg 53 #3 Vial
bgp Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19D.S
E:\HPCHEM\TELLER\METHODS\0798-19B.M
8/3/98 3:08:36 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19D.M
8/10/98 4:33:19 PM by bgp
61
3
2
2 /xl
4000 -
2000 -
10
15
20
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FID1 A,
Signal
8/10/98 4:32:29 PM
1.0000
1.0000
RetTime
[min]
1.462
5.387
7.370
9.156
9.319
9.455
10.080
10.375
Type
BB
BP
BB
BV
W
VB
BV
VB
Area
counts*s
4.59909e4
5.51822e4
5.59330e4
5.62218e4
5.62132e4
5. 6098464
5. 13419e4
5. 7489364
Amt/Area
I
I
8 .44017e-4
7.54805e-4
7.414826-4
7.357986-4
7.426576-4
7.398096-4
8.039446-4
7.157236-4
Amount Grj
[ug/kg]
I __
1
38.81705
41.65178
41.47331
41.36789
41.74716
41.50206
41.27603
41.14646
3 Name
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals :
328.98172
Results obtained with enhanced integrator!
1 Warnings or Errors :
Warning : Calibration warnings (see calibration table listing)
143
Pacrp>. 1 of 2
-------
)ata File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19C\004F6201.D gc-14 pg 53 #4
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
8/6/98 6:43:12 PM
gc-14 pg 53 #4
bgp
Last changed
1 X. (0798-19C\004F620i;D)
TTOT
Seq. Line
Vial
Inj
Inj Volume
E : \HPCHEM\TELLER\SEQUENCE\0 7 9 8 -19D.S
E:\HPCHEM\TELLER\METHODS\0798-19B.M
8/3/98 3:08:36 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19D.M
8/10/98 4:33:19 PM by bgp
62
4
1
counts
45000
40000 -_
35000 -:
30000 -:
25000 :
20000 -;
15000 -
10000 -_
5000 -
=.
10
15
20
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FID1 A,
Signal
8/10/98 4:32:29 PM
1.0000
1.0000
RetTime
[min]
1.462
5.388
7.370
9.158
9.321
9.457
10.082
10.377
Type
BP
BB
BB
BV
W
VB
BV
VB
Area
counts*s
9. 66502e4
1.15994e5
1.17522e5
1.1832965
1. 1808865
1.1792565
1.0805865
1.2095165
Amt/Area
1
1
8.52485e-4
7.60132e-4
7.462856-4
7.39842e-4
7.46950e-4
7.441256-4
8.088836-4
7.199116-4
Amount G
[ug/kg]
82.39284
88.17057
87.70514
87.54510
88.20591
87.75083
87.40653
87.07407
rp Name
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals :
696.25100
Results obtained with enhanced integrator!
1 Warnings or Errors :
Warning : Calibration warnings (see calibration table listing).
144
raller 8/10/98 5:01:08 PM bcrp
Page 1 of 2
-------
Data File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19C\004F6202.D gc-14 pg 53
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
8/6/98 7:00:18 PM
gc-14 pg 53 #4
bgp
A, (U798-19C\004F6202.D)
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19D.S
E:\HPCHEM\TELLER\METHODS\0798-19B.M
8/3/98 3:08:36 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19D.M
8/10/98 4:33:19 PM by bgp _ _
62
4
2
counts
22500 -
20000 -
17500 -
15000 -
12500
10000
7500 -
5000 -
2500 -
« ft>
1 -: 8
™ 4>
£ *' s
•S u
1 ffl
\a i~
•* oo
— £ ^
i «l>
1
i . ' ''
=0
. I /
s i ii
i « P1
j" »S u<^
» •si A^
« *^ op;
"7 fjK Oo"
• wnjljl ""—
1 ^!' :
I
!:
{!
I
S
od
10
15
20
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FID1 A,
Signal
8/10/98 4:32:29 PM
1.0000
1.0000
RetTime
[min]
1.462
5.387
7.369
9.157
9.320
9.456
10.080
10.376
Type
BB
BB
BB
BV
W
VB
BV
VB
Area
counts*s
9. 66746e4
1. 15979e5
1.1748465
1.1825065
1.1799565
1. 1787965
1.0794465
1.2080465
Amt/Area
I
1
8.52487e-4
7.60131e-4
7.462836-4
7.39840e-4
7.469476-4
7.441236-4
8.088786-4
7.199066-4
Amount
[ug/kg]
82.41385
88.15916
87.67633
87.48569
88.13641
87.71669
87.31387
86.96794
Grp Name
_. I
1
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals :
695.86994
Results obtained with enhanced integrator!
1 Warnings or Errors :
Warning : Calibration warnings (see calibration table listing)
' 8/10/98 5:01:19 PM
145
Paqe 1 of 2
-------
Data File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19C\005F6301.D gc-14 pg 53 #E
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
l A,
8/6/98 7:17:15 PM
gc-14 pg 53 #5
bgp
counts
40000 -
30000 -
20000
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19D.S
E:\HPCHEM\TELLER\METHODS\0798-19B.M
8/3/98 3:08:36 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19D.M
8/10/98 4:33:19 PM by bgp
(0798-19C\005F6301 .D)
63
5
1
2 /xl
10000
•a
>n
cb
o -..
0
10
15
20
mini
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FID1 A,
Signal
8/10/98 4:32:29 PM
1.0000
1.0000
RetTime
[min]
1.461
5.387
7.369
9.158
9.321
9.457
10.081
10.377
Type
_
BP
BE
BB
BV
W
VB
BV
VB
Area
count s*s
2.3205165
2. 7887665
2.8134865
2.8279165
2.82024e5
2.8155465
2. 5783565
2.88700e5
Amt/Area
i
1
8.56971e-4
7.629556-4
7.488246-4
7.419716-4
7.492186-4
7.464016-4
8.114796-4
7.221156-4
Amount Grj
[ug/kg]
I
1 __
198.86109
212.77005
210.68045
209.82278
211.29742
210.15185
209.22810
208.47462
3 Name
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals :
1671.28635
Results obtained with enhanced integrator!
1 Warnings or Errors :
Warning : Calibration warnings (see calibration table listing)
w-
eller 8/10/98 5:01:31 PM bgp
146
Paqe 1 of 2
-------
Data File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19C\005F6302.D gc-14 pg 53 #
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
8/6/98 7:34:14 PM
gc-14 pg 53 #5
FID1A, (0798-19C\(X)5F6302:C7
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19D.S
E:\HPCHEM\TELLER\METHODS\0798-19B.M
8/3/98 3:08:36 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19D.M
8/10/98 4:33:19 PM by bgp
63
5
2
counts
50000 -
40000
=f
\o
oo
fl
30000
20000 -
10000 -
10
15
20
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FID1 A,
Signal
8/10/98 4:32:29 PM
1.0000
1.0000
RetTime
[min]
1.461
5.386
7.367
9.156
9.318
9.454
10.078
10.374
Type
BP
BB
BB
BV
W
VB
BV
VB
Area
count s*s
2.32557e5
2. 7993865
2.82953e5
2. 84730e5
2.84202e5
2.83418e5
2.60010e5
2.90922e5
Am t/ Are a
8.56978e-4
7.62963e-4
7.48835e-4
7.41982e-4
7.49230e-4
7.46411e-4
8.11495e-4
7.221286-4
Amount G
[ug/kg]
199.29587
213.58252
211.88528
211.26462
212.93271
211.54612
210.99654
210.08270
rp Name
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals :
1681.58635
Results obtained with enhanced integrator!
1 Warnings or Errors :
Warning : Calibration warnings (see calibration table listing)
147
-<~.-\ n «•«. o/in/QQ
DM Virrn
Pacre» 1 of
-------
Data File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19C\006F6401.D gc-14 pg 53 #6
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
8/6/98 7:51:15 PM
gc-14 pg 53 #6
bgp
counts -
100000 -
80000 -
60000 -
40000 -
FIDl A, (0798-19C\006F6401.D)
= 2
5 §
» a
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19D.S
E:\HPCHEM\TELLER\METHODS\0798-19B.M
8/3/98 3:08:36 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19D.M
8/10/98 4:33:19 PM by bgp
64
6
1
vO
•t
20000
o--
2 -
£ oo
10
15
20
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FIDl A,
Signal
8/10/98 4:32:29 PM
1.0000
1.0000
RetTime
[min]
1.461
5.384
7.367
9.156
9.318
9.454
10.078
10.375
Type
BP
BB
BB
BV
W
VB
BV
VB
Area
count s*s
1
4.50567e5
5.42683e5
5.49425e5
5.54107e5
5.53794e5
5.51352e5
5. 06372e5
5.66429e5
Amt/Area
1
8.58524e-4
7.63932e-4
7.49713e-4
7.42721e-4
7.500196-4
7.472036-4
8.123996-4
7.228956-4
Amount G
[ug/kg]
386.82304
414.57311
411. 91120
411.54739
415.35604
411.97205
411.37610
409.46851
rp Name
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals
3273.02743
Results obtained with enhanced integrator!
1 Warnings or Errors :
Warning : Calibration warnings (see calibration table listing)
eller 8/10/98 5:01:56 PM bgp
1.48
Paqe 1 of 2
-------
Data File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19C\006F6402.D gc-14 pg 53 #<
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
rsr
8/6/98 8:08:15 PM
gc-14 pg 53 #6
bgp
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19D.S
E:\HPCHEM\TELLER\METHODS\0798-19B.M
8/3/98 3:08:36 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19D.M
8/10/98 4:33:19 PM by bgp
64
6
2
counts .
100000 -
80000 -
60000 •
40000 -,
20000 -
FIDI A, (0798-19C\006F6402.D)
8 g
1 I
i a
o-
10
15
20
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FIDI A,
Signal
8/10/98 4:32:29 PM
1.0000
1.0000
RetTime
[min]
1.460
5.384
7.367
9.156
9.318
9.454
10.079
10.373
Type
BB
BB
BB
BV
W
VB
BV
VB
Area
counts*s
i _
4. 53507e5
5.45976e5
5.51595e5
5.55808e5
5.55121e5
5.53005e5
5.07604e5
5.67888e5
Amt/Area
i
1
8.58535e-4
7.63939e-4
7.49717e-4
7.42724e-4
7. 500216-4
7.472066-4
8.124016-4
7.22897e-4
Amount
[ug/kg]
389.35120
417.09219
413.53996
412.81144
416.35219
413.20832
412.37820
410.52417
Grp Name
__ i
1
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals :
3285.25766
Results obtained with enhanced integrator!
1 Warnings or Errors :
Warning : Calibration warnings (see calibration table listing)
tyo
Teller 8/10/98 5:02:08 PM bcro
149
Page 1 of 2
-------
Data File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19C\007F6501.D gc-14 pg 53 #7
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
$
8/6/98 8:25:11 PM
gc-14 pg 53 #7
bgp
counts :
175000 -
150000 -
125000 -_
100000 -_
75000 -'•
50000
25000 -
FID1 A, (0798-19C\007F6501.D)
S
iC
3
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19D.S
E:\HPCHEM\TELLER\METHODS\0798-19B.M
8/3/98 3:08:36 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19D.M
8/10/98 4:33:19 PM by bgp
65
7
1
Tolu
o
so
10
15
20
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FID1 A,
Signal
8/10/98 4:32:29 PM
1.0000
1.0000
RetTime
[min]
1.460
5.383
7.366
9.156
9.318
9.455
10.079
10.374
Type
VB
BB
BB
BV
W
VB
BV
VB
Area
count s*s
8. 51358e5
1.02519e6
1.0391666
1.0505066
1.0507166
1.0429066
9.61165e5
1.0737566
Amt/Area
8.59301e-4
7.64419e-4
7.50153e-4
7.430916-4
7.504136-4
7.475986-4
8.128506-4
7.232776-4
Amount Grj
[ug/kg]
| _
731.57272
783 .67731
779.53165
780.61967
788.46711
779.66834
781.28303
776.62184
3 Name
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals :
6201.44168
Results obtained with enhanced integrator!
1 Warnings or Errors :
Warning : Calibration warnings (see calibration table listing)
Jill 1~
'eller 8/10/98 5:02:20 PM bgp Page 1
-------
Data File E:\HPCHEM\TELLER\DATA\1998\.JUL98\0798-19C\007F6502.D gc-14 pg 53 #
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
8/6/98 8:42:08 PM
gc-14 pg 53 #7
bgp
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19D.S
E:\HPCHEM\TELLER\METHODS\0798-19B.M
8/3/98 3:08:36 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19D.M
8/10/98 4:33:19 PM by bgp
fcz'riw 'r^\ -
65
7
2
FTO1A, <0798-19C\007F6502.D)
counts - a
- G 0
'-- I i
175000 - 7 a
150000 - 3 S
125000 - !
100000 - ;
75000 -; ' '
50000 -_ •
U1 •=
t? &
ff !
, >c
:
GO
By
i^
i
H
1
t 1
', • m
^
10
15
20
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FID1 A,
Signal
8/10/98 4:32:29 PM
1.0000
1.0000
RetTime
[min]
1.460
5.383
7.365
9.156
9.319
9.455
10.079
10.374
Type
VB
BB
BB
BV
W
VB
BV
VB
Area
count s*s
8.5035465
1.02494e6
1.0393566
1.0513466
1.04964e6
1.0466266
9.62492e5
1.07506e6
Amt/Area
8.593006-4
7.64419e-4
7.50153e-4
7.430916-4
7.504126-4
7.476006-4
8.128516-4
7.232786-4
Amount Grj
[ug/kg]
i __
730.70922
783 .48636
779.67291
781.23920
787.66473
782.44937
782.36291
777.56691
) Name
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals :
6205.15160
Results obtained with enhanced integrator!
1 Warnings or Errors :
Warning : Calibration warnings (see calibration table listing)
Teller 8/10/98 5:02:32 PM bgp
152
Page 1 of 2
-------
Silo
GC/MS Results
153
ENTHALPYanalytical, inc.
-------
Tentative Identification of Detected Compounds
Client ID : PES
Sample ID: S-M18-1
Enthalpy Project ID : 0798-19
Volume of Sample (ml) = 5
Peak*
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
Ret
Time
6.934
10.436
10.552
10.908
11.523
13.198
13.553
13.772
13.821
14.492
14.964
15.567
15.929
16.155
17.274
17.582
17.981
18.187
18.928
19.148
19.561
19.953
20.496
20.888
22.120
22.457
23.664
24.126
25.650
15.176
Tentative Identification
Benzene
N,N-Dimethyl formamide *
Toluene
Trimethanolpentanol
Trimethylhexane
Trimethylcyclohexane
Ethylbenzene
Ethylhexane
m&p-Xylenes
o-Xylene
Nonane
Methylpentadiene
Dimethyloctane
Methyloctane
Trimethylbenzene
Decane
Trimethylbenzene
Dimethylnonane
Ethylmethylcyclopropane
Methylmethylenecyclohexane
Dipropylcyclopropene
Tetradecane
Decahydromethylnaphthalene
Octadecyne
Methylundecane
Dimethylundecane
Trimethyldecane
Tridecane
Trimethyldodecane
Internal Standard
4-Bromofluorobenzene
Total
Area
165,743
21,937,208
1,142,251
826,952
1,541,560
886,566
488,654
2,397,148
2,214,485
931,029
916,690
803,175
1,189,071
1,047,621
823,130
1,465,245
1,636,194
1,656,031
1,203,166
991,440
813,093
1,723,934
960,004
1,217,570
1,908,125
2,086,560
955,196
1,526,276
1,241,035
970,108
Catch
(ua)
42.7
5,653
294
213
397
228
126
618
571
240
236
207
306
270
212
378
'422
427
310
255
210
444
247
314
492
538
246
393
320
ug/ml
50
CAS
71-43-2
68-12-2
108-88-3
123-44-4
3522-94-9
3073-66-3
100-41^
619-99-8
1 08-38-3 & 106-42-3
95-47-6
111-84-2
1118-58-7
2051-30-1
2216-33-3
526-73-8
124-18-5
95-36-3
17302-28-2
53778-43-1
2808-75-5
10306-92-0
629-59-4
2958-76-1
35365-59-4
7045-71-8
17301-23-4
62108-25-2
629-50-5
3891-98-3
MW
78.1
73.0
92.1
130.0
128.2
126.1
106.2
114.1
106.2
106.2
128.2
82.1
142.2
128.2
120.1
142.2
120.1
156.2
84.1
110.1
124.1
198.2
152.2
250.3
170.2
184.2
184.2
184.2
212.2
Reviewed by:
QA:
Steven J. Ecksird
Date:
ENTHALPY a na lyti ca I.
inc.
154
-------
Tentative Identification of Detected Compounds
Client ID
Sample ID
Enthalpy Project ID
Ret
Peak# Time
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
10.474
11.512
13.786
15.940
16.159
16.652
17.578
17.989
18.181
18.353
18.483
18.936
19.156
19.348
19.718
19.952
20.350
20.494
20.886
21.367
21.752
22.117
22.949
23.666
24.045
24.128
24.535
25.652
26.005
15.19
PES
S-M18-2
0798-19
Volume of Sample (mL) =
Tentative Identification
N,N-Dimethyl formamide •*
Trimethylheptane
2-Heptyn-1-ol
2,4-Dimethylheptane
3-Ethyl-2-methylheptane
Tetramethylcyclohexane
2-methylnonane
Trimethylbenzene
2-Heptenal
1 -methyl-4-(1 -methylethylidene)-Cyclohexane
5-Methyl-3-undecene
5-Methyl-1-decene
Cyclodecene
Methylbicyclohexane-3-one
Dimethylnonadiene
Dimethyloctane
Tetradecyloxirane
Decahydro-2-methylnaphthalene
Decahydro-2-methylnaphthalene
Bromotridecane
Undecyne
Dodecane
Trimethylcyclohexane
Dimethylundecane
Dimethylcyclooctane
Tridecane
Cetylpyridinium chloride
Tetramethylheptadecane
Tetracecane
Internal Standard
4-Bromofluorobenzene
5
Total
Area
21,749,581
702,688
513,034
726,063
483,694
814,772
953,947
821,522
1,103,064
472,118
1,063,219
460,895
668,305
759,510
983,674
1,146,137
552,319
1,133,399
878,578
725,002
566,797
1 ,046,226
2,076,158
1,264,257
466,498
2,080,059
866,092
1 ,007,238
3,558,428
630,620
Catch
(Ufl)
8,622
279
203
288
192
323
378
326
437
187
421
183
265
301
390
454
219
449
348
287
225
415
823
501
185
825
343
399
1,411
ug/ml
50
CAS
68-12-2
14720-74-2
1002-36-4
2213-23-2
14676-29-0
6783-92-2
871-83-0
95-36-3
57266-86-1
1124-27-2
NA
54244-79-0
3618-12-0
1125-12-8
20054-25-5
1072-16-8
7320-37-8
2958-76-1
2958-76-1
765-09-3
2294-72-6
112-40-3
1678-97-3
17301-23-4
13151-98-9
629-50-5
6004-24-6
18344-37-1
629-59-4
MW
73.0
142.2
112.0
128.2
142.2
140.2
142.2
120.1
112.0
138.1
112.1
154.2
138.1
152.1
152.2
142.2
240.2
152.2
152.2
262.1
152.2
170.2
126.1
184.2
140.2
184.2
357.0
296.3
198.2
ENTHALPYanalytical.
inc.
155
-------
Tentative Identification of Detected Compounds
Client ID : PES
Sample ID: S-M18-3
Enthalpy Project ID : 0798-19
Volume of Sample (ml) = 5
Peak#
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
- 26
27
28
29
Ret
Time
10.201
10.359
11.513
13.775
14.952
15.938
16.157
16.651
16.884
17.577
17.989
18.18
18.352
18.928
19.148
19.306
19.711
19.944
20.885
22.453
23.437
23.658
24.126
24.27
25.654
26.005
27.224
27.905
30.164
15.185
Tentative Identification
N,N-Dimethyl formamide *
N,N-Dimethyl formamide t
Trimethylhexane
m&p-Xylenes
Nonane
Methylnonane
Dimethyloctane
Dimethyloctene
2-Ethylhexanal
Decane
Ethylmethylbenzene
Methylnonane
Hexadecyne
Undecene
Dodecenol
Pentenal
Methyloctyne
Decane
Decahydromethylnaphthalene
Dimethylundecane
Hexyldecanol
Dimethylheptadecane
Tridecane
Tetradecene
Trimethyldodecane
Tetradecane
Tetramethylheptadecane
Pentadecane
Hexadecane
Internal Standard
4-Bromofluorobenzene
Total
Area
2,565,563
11,277,526
503,869
903,615
1,074,316
711,888
1,203,289
915,416
531,066
1,218,396
1,876,924
1,124,655
2,427,532
807,099
516,327
792,549
818,242
1,530,864
998,790
519,648
1,392,597
850,090
1,284,708
571,984
634,272
1,629,986
953,903
5,126,790
1,699,568
618,049
Catch
(ug)
1038
4,562
204
366
435
288
487
370
215
493
759
455
982
326
209
321
331
619
404
210
563
344
520
231
257
659
386
2,074
687
ug/ml
50
CAS
68-12-2
68-12-2
3522-94-9
1 08-38-3 & 106-42-3
111-84-2
5911-04-6
2051-30-1
4057-42-5
645-62-5
124-18-5
611-14-3
5911-04-6
74685-28-2
764-97-6
20056-92-2
2100-17-6
62108-34-3
124-18-5
2958-76-1
17301-23-4
2425-77-6
54105-67-8
629-50-5
1120-36-1
3891-98-3
629-59-4
18344-37-1
629-62-9
544-76-3
MW
73
73
128.2
106.17
128.2
142.2
142.2
140.2
126
142.2
120.1
142.2
222.2
154.2
184.2
84.1
124.1
142.2
152.2
184.2
242.3
268.3
184.2
196.2
212.2
198.2
296.3
212.2
226.3
ENTHALPY
nc.
156
-------
Tentative Identification of Detected Compounds
Client ID : PES
Sample ID: S-M18-4
Enthalpy Project ID : 0798-19
Volume of Sample (ml) = 5
Peak*
1
2
Ret
Time
10.188
10.457
Tentative Identification
N,N-Dimethyl formamide *
N,N-Dimethyl formamide 4
Total
Area
100
100
Catch
(UQ)
0.0324
0.0324
CAS
68-12-2
68-12-2
MW
73.0
73.0
Internal Standard
ug/ml
15.186 4-Bromofluorobenzene 772,573
50
ENTHALPY analytical.
inc.
157
-------
Silo
GC/MS Data
1 ^
ENTHALPYanalytical. inc.
-------
File
Operator
Acquired
Instrument
Sample Name
Misc Info
Vial Number
D:\HPCHEM\1\DATA\079819\798198.D
TAB
27 Aug 98 9:44 am using AcqMethod 079819
5970
S-M18-1
2000000^
*5 U O W W V' ™,
- *-} r\ f\ f^ r* t
_ z u J \j u
TIC: 798198.D
. OOCOOC -
60QOOC-
400000-
200000-'
10.00
15.00
20.00
25.00
159
-------
File
Operator
Acquired
Instrument
Sample Name
Hisc Info
Vial Number
D:\HPCHEM\1\DATA\079819\7981910.D
TAB
27 Aug 98 12:10 pm using AcqMethod 079819
5970
S-M18-2
2000000 -:
•; o r\ A A r\ r\ i
-L C U u J U J -
1600COO-
. 2 0 0 0 0 C
TIC: 7981910.D
600000-,
400000 -
.£. U U U U U "I
Mm^mwr-r1
'11! '
tf»
10.00
.5.00
20.0;
25.00
-------
File
Operator
Acquired
Instrument
Sample Name
Misc Info
Vial Number
D:\HPCHEM\1\DATA\079819\7981911.D
TAB
27 Aug 98 12:46 pm using AcqMethod 079819
5970
S-M18-3
7
/ r\r\
.
-------
File
Operator
Acquired
Instrument
Sample Name
Misc Info
Vial Number
D:\HPCHEM\1\DATA\079819\7981912.D
TAB
27 Aug 96 1:46 pm using AcqMethod 079819
5970
S-M18-4
TIC: 7981912.D
40000C-
200000-'
10.00
15.00
20.00
25.00
3B2
-------
Information from Data File:
File
Operator
Acquired
Sample Name
'isc Info
\7ial Number
D:\HPCHEM\1\DATA\079819\798198.D
TAB
27 Aug 98 9:44 am using AcqMethod 079819
S-M18-1
Search Libraries:
C:\DATABASE\NBS75K.L
C: \DATABASE\EXTRA. L
C: \DATABASE\T014TAR.L
Minimum Quality: 10
Minimum Quality: 10
Unknown Spectrum: Apex
Integration Params: current RTEINT parameters
RT
Ref£
;AS#
Qual
10.44 35.47 C:\DATABASE\NBS75K.L
Formarr.ide, K,N-dimerhyl-
Formamide, N,N-dimethyl-
2-3uianamine, (.+/-.)-
10.55 2.00 C:\DATA3ASE\NBS75K.L
Pyrrolidine
Kydroxy1amine, 0-pen~y1-
Pyrrolidine
10.91 1.45 C:\DATA3ASE\N3S75K.L
1-Pentancl, 2,2,4-trimethyl-
Heptane, L,l'-oxybis-
Heptane, 2-methyl-
11.52 2.70 C:\DATA3ASE\N3S75K.L
Hexane, 2,2,5-trimethyl-
Kexane, 2,2,5,5-tetramerhyl-
Heptane, 2,2-dimethyl-
13.20 1.55 C:\DATA3ASE\N3S75K.1
Cyclohexane, 1,1,3-trimethyl-
Cyclohexane, 1,1,3-trimezhyl-
Cyclohexane, 1,1,3-trimerhyl-
13.77 4.20 C:\DATA3ASE\N3S75K.L
Hexane, 3-ethyl-
Hexane, 2,3,5-trimethyl-
Heptane, 2,3-dimethyl-
14.19 1.34 C:\DATA3ASE\N3S75K.L
1-Hexanol, 2-ethyl-
1-Hexanol, 2-ethyl-
Ether, heptyl hexyl
62525 000068-12-2 86
62526 000068-12-2 86
298 C33966-50-6 86
62469 000123-75-1 43
1838 005963-74-6 43
62470 000123-75-1 43
5514 000123-44-4 64
26421 000629-64-1 56
3092 000592-27-8 42
65126 003522-94-9 83
66226 001071-81-4 72
65135 001071-26-7 72
64941 003073-66-3 87
64942 003073-66-3 72
4647 003073-66-3 68
64222 000619-99-8 38
5161 001069-53-0 38
5152 003074-71-3 38
65293 000104-76-7 78
65291 000104-76-7 74
23013 007289-40-9 56
796198.D
Thu Aug 27 10:37:16 1998
Page 1
163
-------
Pk# RT
Area%
Library/ID
Ref#
CAS# Qual
8 14.64 1.32
C:\DATABASE\NBS75K.L
6-Oxabicyclo[3.1.0]hexane
3-Nonene, (E)-
4-Pentenal
575 000285-67-6 64
4664 020063-92-7 59
571 002100-17-6 53
14.96 1.61
C:\DATA3ASS\NBS75K.L
Nonane
Nonane
Nonane
65144 000111-84-2 91
65145 000111-84-2 83
65143 000111-84-2 78
.
U
15
C:\DATABAS E\N3S 7 5 K.L
Benzene, l-bromo-2-fiucro-
Benzene, l-brorno-3-f luorc-
Benzene, l-bromo-3-fluoro-
16035 001072-85-1 97
16C34 001073-06-9 93
68407 001073-06-9 91
C: \DATABASE\NBS'15K. L
1,3-Pentadiene, 2-methyi-
'-, 3-Pentaciens, 2-methyl-,
Bicyclo[4.1.0]heptane
482 001118-58-7 49
475 000926-54-5 47
63134 000286-08-8 43
14
.
94
C:\DATA3ASE\N3S75K.1
Octane, 2, 6-dimethyl-
Octane, 2, 6-dime-hyl-
Oxirane, pentyi-
C : \DATA3ASE\N3S7 5K . L
Undecane, 5, 6-dimethyl-
Oczane, 3-iriethyl-
Decane, 2, 5, 6-trimethyl-
44
2.
C:\DATABASE\N3S75K.L
Benzene, 1, 2, 3-trimethyl-
1,2, 4-Trimethylbenzene
Benzene, 1, 2, 3-trimethyl-
C:\DATA3ASE\N3S75K.L
Decane
Octane, 2, "-dimetr.yl-
Nonane, 2 -methyl -
C:\DATAEASE\NBS75K.L
3-Octyne, 6-methyl-
Cycloheptene, 1, 2-dimerhyl-
17-Pentatriacontene
66227 002051-30-1 53
66228 002051-30-1 53
3071 005063-65-0 53
19004 017615-91-7 50
515C 002216-35-3 50
19019 062108-23-0 47
3773 000526-73-8 89
3771 000095-36-3 67
64576 000526-73-8 64
66206 000124-16-5 64
8076 001072-16-6 53
8093 000871-83-0 52
4262 062108-34-3 43
425C 020053-89-6 36
58705 006971-40-0 35
17.98 2.67
C:\DATABASE\NBS75K.L
1,2, 4-Trimethylbenzene
Cyclohexane, l-methyl-4- (1-metr.yle
5-Methyl-5-hexen-3-yn-2-ol
3771 000095-36-3 49
^092 001124-27-2 45
2307 068017-33-4 43
98198.D
Thu Auc 27 10:38:24 1998
Page 2
164
-------
Pk# RT
Area%
Library/ID
Ref#
CAS# Qual
18 18.19 2.90 C:\DATABASE\NBS75K.L
Nonane, 2, 6-dimethyl-
Decane, 4-methyl-
Nonane, 4-methyl-5-propyl-
19 18.35 1.40 C:\DATABASE\N3S75K.L
Naphthalene, decahydro-2-methyl-
Cyclohexene, 3-methyl-6-(1-methyle
3,5-Dimethylcyclohexene
20
16.93 2.11 ^
C: \DATABASE\N3S7 5K. L
Cyclopropane, 1-ethyl-l-methyl-
5-Undecene, (E)-
1-Decene, 5-methyl-
19.15 1.74 C:\DATA3ASE\N3S75K.L
l-Methyl-2-methylenecyclohexane
Cyclohep-ene, methyl-
cis-7-Dodecen-l-ol
22 19.56 1.43 C:\DATA3ASE\NBS75K.L
1,2-Dipropylcyclopropene
1, 4-Hexadiene, 2, 3-dime~hvl-
(E)-1-Phenyl-l-butene
23 19.95 3.02 C:\DATA3ASE\N3S75K.L
Tetradecane
Nonadecane
Pentadecane
24 2C.50 1.66 C:\DATA3ASE\NBS75K.L
Naphthalene, decahydro-2-methyl-
Cyclohexanone, 2-methyl-5-(1-methy
Cyclohexanone, 2-methyl-5-(1-methy
25 20.69 2.14 C:\DATA3ASE\N3S75K.L
9-Octadecyne
Cyciohexanone, 2-methyl-5-(1-methy
1-Dodecyne
26 22.12 5.35 C:\DATA3ASE\N3S75K.L
Undecane, 2-methyl-
Decane
Decane, 2-methyl-
27 22.46 3.66 C:\DATABASE\NBS75K.L
Undecane, 2,6-dimethy1-
Heptane, 3-ethyl-2-methyl-
3-Undecene, 6-methyl-, (E)-
11598 017302-28-2 50
67324 002847-72-5 47
19021 062185-55-1 47
10436 002958-76-1 58
7099 005256-65-5 53
2315 000000-00-0 49
609 053778-43-1 64
67184 000764-97-6 64
11073 054244-79-0 58
2368 002808-75-5 70
63885 055308-20-8 60
18959 020056-92-2 59
4240 010306-92-0 38
2380 018669-52-8 36
5878 001005-64-7 35
69661 000629-59-4 64
37469 000629-92-5 64
26001 000629-62-9 64
67009 002958-76-1 93
10308 007764-50-3 93
66974 005948-04-9 87
34017 035365-59-4 68
10308 007764-50-3 60
68014 000765-03-7 53
15356 007045-71-8 64
66204 000124-18-5 59
67322 006975-98-0 59
19058 017301-23-4 59
8080 014676-29-0 43
14747 074630-52-7 43
798198.D
Thu Aug 27 10:40:07 1998
Page 3
165
-------
RT
Area%
Library/ID
Ref#
CAS# Qual
28 23.66 1.68 C:\DATABASE\NBS75K.L '
Decane, 2,6,7-trimethyl-
Nonane, 3-methyl-
Octane, 2,3,7-trimethyl-
29 24.13 2.68 C:\DATA3ASE\N3S75K.L
Tridecane
Dodecane
Tridecane
30 25.65 2.18 C:\DATABASE\N3S75K.L
Dodecane, 2,6,10-trimethyl-
Dodecane, 2,6,ll-trimethyl-
Dodecane, 2,6,11-trimethyl-
19027 062108-25-2 64
66201 005911-04-6 64
11603 062016-34-6 53
69019 000629-50-5 91
68254 000112-40-3 72
69020 000629-50-5 64
70269 003891-98-3 72
25998 031295-56-4 64
70271 031295-56-4 59
98198.D
Thu Aug 27 10:40:54 1998
Page 4
166
-------
S-M18-1
Peak#
1
2
3
4
5
6
7
8
Q
10
-1 *
-L -L
12
13
14
-L W1
16
- —;
18
19
20
/. —
22
23
24
25
-<=;
,
26
29
30
Ret Time
10.
10.
10.
11.
13.
13.
14.
14.
14.
15.
15.
15.
16.
17.
17 .
"' 1
17 .
18.
1 0 .
18.
1 9 .
19 .
19.
20.
20.
22.
22.
23.
24 .
25.
436
552
908
523
198
772
190
642
964
176
567
929
155
274
562
939
96 '
187
352
928
" L £
561
953
496
666
120
457
664
126
650
Type
rBV
rVB
rEV
rBV
rVB
rBV
rBV
rVB
rBV
rW
rV3
rW
rBV
rBV
rBV
rW
rVB
rBV
rBV
rBV
rBV
rVB
rBV
rBV
rVB
rVB
rVB
rBV
rVB
rVB
Width
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0 .
0.
0.
0.
J .
0.
\J .
0.
u .
0.
w .
u .
r-
0.
w .
0.
335
164
171
157
130
185
164
130
096
082
144
096
096
096
062
076
165
096
096
117
062
096
1 /
089
^- J. \^'
096
156
09"
' "" "7
124
Area
21937208
1142251
826952
1541560
886566
2397148
764616
753360
916690
970108
803175
1189071
1047621
823130
1465245
838366
1636194
1656031
79696'
1203166
991440
813093
1723934
960004
_ 2 _L / 3 7 0
1908125
2066560
955196
1526276
1241035
Start Time
10.
10.
10.
11.
13.
13.
14.
14.
14.
15.
1 5 .
15.
16.
17.
* —j
17 .
17 .
18.
16 .
18.
19 .
19.
19.
20.
20.
22 .
22
23.
24.
25.
176
518
853
448
150
704
094
581
909
121
512
882
100
225
534
878
960
132
297
853
107
513
904
454
840
086
409
622
064
609
End
10
10
11
11
13
13
14
14
15
15
15
15
16
17
17
17
18
18
16
18
19
19
20
20
20
22
22
23
24
25
Time
.511
.682
.024
.605
.280
.889
.259
.711
.005
.204
.656
.977
.196
.322
. 617
.953
. 125
.228
.393
.970
.189
.609
. 021
.544
.950
.182
. 566
.719
.202
.733
167
-------
UU 31 . U
,f£
4 ^--M
5
6
7
8
9
10
11
12
13
14
j. 0
16
- -j
18
19
20
13.821
.14.492
16.210
16.402
17.267
17.651
18.805
19.347
19.554
20.269
20.331
20.661
20.764
20.888
21.018
21 . 087
21.844
22.072
/ V UU 31 .
S-M18-1
Type
rBV
rBV
rBB
rBB
rBV
rBV
rVB
rBV
rBV
rVB
rVB
rBV
rVB
rVB
rBV
rBV
rBV
rBV
rBV
rVB
i u ; : /
Width
0.062
0.075
0.199
0.151
0.123
0.103
0.117
0.096
0.158
0.069
0.103
0.069
0.110
0.110
0.090
0.083
0.090
0.055
0.090
0.076
/ 30 130
Area
22889
28121
196585
67268
37806
16236
22235
12888
48615
10755
20233
12811
18169
12377
18842
15055
15493
17903
14088
Start Time
10.511
13.492
13.
14,
16,
16,
17
731
416
128
327
205
603
709
320
519
20.221
20.317
20.606
20.716
17
18
19
19
846
963
053
21.769
22.044
20,
20,
21,
End Time
10.573
13.567
13
14
16
16
17
17
18
19
19
20
20
20
20
20
21
21
21
22
930
567
251
430
322
699
867
389
623
289
427
716
805
929
053
108
879
120
168
-------
j. _L^ : / 20 1 »o . u
S-M18-1
i
Peak# Ret Time Type Width Area Start Time End Time
1 13.547 rm 0.082 488654 13.519 13.601
2 13.772 rm 0.165 2214485 13.718 13.882
3 14.450 rrn 0.103 931029 14.402 14.505
16"
-------
/ r o j. re . u
S-M18-1
?eak# Ret Time Type Width
1 6.934 rm 0.253
Area
165743
Start Time
6.832
End Time
7.085
170
-------
S-M18-1
Peak# Ret Time Type Width Area Start Time End Time
1 10.552 rm 0.082 1142548 10.518 10.600
171
HT.\ :
-------
xuo.uu iiuo./u LO IUD./UJ
S-M18-1
=eak#
1
2
3
4
5
6
Ret Time
13.834
14.498
17.267
17.988
20.998
23.098
Type
rBB
rBB
rBB
rBB
rBB
rBB
Width
0.171
0.117
0.089
0.089
0.090
0.090
Area
74588
25640
16737
13222
15042
11748
Start Time
13.745
14.430
17.212
17.932
20.963
23.043
End Time
13.916
14.546
17
18
21
301
022
053
23.133
1 7
JL I
-------
j-wii 3j..uu \»u./u to iU./U): /yb!98.D
S-M18-1
Peak# Ret Time Type Width Area Start Time End Time
1 13.821 rBB 0.199 196585 13.731 13.930
173
-------
Information from Data File:
File . D:\HPCHEM\1\DATA\079819\7981910.D
Operator TAB
Acquired 27 Aug 98
Sample Name S-M18-2
lisc Info
Vial Number
12:10 pm using AcqMethod 079819
Search Libraries:
C:\DATABASE\NBS75K.L
C: \DATABASE\EXTRA. L
C:\DATABASE\T014TAR.L
Ur.known Spect rurr.: Apex
Integration Params: current RTEINT parameters
Minimum Quality: 5
Minimum Quality: 5
R7
TV vr. _ g.
rs.j- — c. "6
ibrarv/ID
Ref#
CAS* Qual
10.47 43.26 C:\DATA3ASE\NBS75K.L
Fcrmamide, N,N-dime~hyl-
Formamide, N,N-dimethyl-
Formamide, N,N-dime~hyl-
11.51 1.40 C:\DATABASE\NBS75K.L
Heptane, 2,2,4-trimethyl-
Decane, 2,2,6-trimerhyl-
Kexane, 2,2,5-trimethyl-
13."3 1.C2 C:\DATA3ASE\N3S75K.I
2-Heptyn-l-ol
Furan, 2,3-dihydro-
1-Heprene, 4-methyl-
15.15 1.25 C:\DATA3ASE\N3S75K.L
Benzene, l-bromo-2-fluoro-
Benzene, l-bromo-3-flucrc-
p-Bromofluorobenzene
15.94 1.44 C:\DATA3ASE\N3S75K.L
Heptane, 2,4-dimerhyl-
Heptane, 2,4-dimethyl-
Heptane, 2,4-dimethyl-
16.16 0.96 C:\DATABASE\N3S75K.L
Heptane, 3-ethyl-2-methyl-
(Z)-3-Heprene
Cyclohexane, methyl-
16.65 1.62 C:\DATA3ASE\N3S75K.L
Cyclohexane, 1,1,2,5-tetramethyl-
Cyclohexane, I, 2, 3-triinethyl-, {'.
Cyclohexane, 1,2,3-trimethyl-, C
62525 000068-12-2 86
62526 000068-12-2 86
62527 000068-12-2 83
8105 014720-74-2 59
18995 062237-97-2 59
65126 003522-94-9 56
2590 001002-36-4 50
62438 001191-99-" 36
2675 013151-05-8 25
16035 001072-85-1 97
16034 001073-06-9 96
16036 000460-00-4 91
65121 002213-23-2 43
5145 002213-23-2 43
65120 002213-23-2 37
8080 014676-29-0 38
1368 007642-10-6 27
63236 000108-87-2 27
7580 006783-92-2 76
4680 001678-81-5 60
4622 001839-88-9 47
7981910.D
Fri Aug 28 14:57:36 1998
Page 1
174
-------
Pk# RT
Area%
Library/ID
Ref#
CAS# Qual
8 17.58 1.90 C:\DATA3ASE\NBS75K.L
Nonane, 2-methyl-
Kydroxylamine, 0-decyl-
Decane
9 17.99 1.63 C:\DATABASE\N3S75K.L
1,2,4-Trimethylbenzene
Benzene, 1,2,3-trimethyl-
Benzene, l-ethyl-2-methyl-
.0 18.18 2.19 C:\DATA3ASE\N3S75K.L
2-Heptenal, (Z)-
2-Heptenal, (E)-
Silane, trichloroeicosyl-
1 A
8093 000871-83-0 53
15973 029812-79-1 53
66206 000124-18-5 52
3771 000095-36-3 72
64576 000526-73-8 47
3765 000611-14-3 38
2610 057266-86-1 70
2632 018829-55-5 45
54853 018733-57-8 43
18.35 0.94 C:\DATABASE\N3S75K.L
Cyclohexane, l-methyi-4-(1-methyle 65946 001124-27-2 46
5-3romo-l-hexene 12764 004558-27-4 43
3icyclo[4.1.0]heptane, 3,7,7-trime 7090 018968-23-5 43
L s
IS.94
19
.72
17 19.95
11 C:\DATABASE\N3S 7 5 K.L
3-Undecene, 5-methyi-
3-Heptene, 3-methyi-
5-Methyl-3-heptene
92 C:\DATABAS E\NBS 7 5 K.L
1-Decene, 5-methyl-
6-Octenal, 3,7-dimethyl-
3-undecene, (E)-
33 C:\DATA3ASE\N3S 7 5K. L
Cyclodecene
1-Methy1-2-methylenecyclohexane
cis-7-Dodecen-l-oI
14689 000000-00-0 47
64039 007300-03-0 46
2641 000000-00-0 43
11073 054244-79-0 72
67174 000106-23-0 "C
11074 001002-68-2 64
65941 003618-12-0 76
2368 002808-75-5 60
18959 020056-92-2 59
1.51 C:\DATA3ASE\N3S75K.L
Bicyclo[3.i.O]hexan-3-one, 4-methy 10295 001125-12-8 60
Bicycle[4.1.0]heptane, 3-methyl- 2354 0419^7-47-3 49
Cyclodecene, 3-bromo- 26651 056325-56-5 47
1.96 C:\DATA3ASE\NBS75K.L
1,8-Nonadiene, 2,8-dimethyl-
trans-1, 3-Diethylcyclopentane
Cyclopentane, 1,2-dimethyl-3-(1-me
2.28 C:\DATABASE\NBS75K.L
Octane, 2,7-dimethyl-
Undecane
Heptane, 2,6-dimethyl-
10445 020054-25-5 60
4618 000000-00-0 47
7606 000489-20-3 47
66209 001072-16-8 64
6^317 001120-21-4 53
65137 001072-05-5 53
7981910.D
Fri Aug 28 14:56:54 1998
-------
RT
Area%
Library/ID
Ref#
CAS# Qual
18 20.35 1.10 C:\DATA3ASE\NBS75K.L
Oxirane, tetradecyl-
Silane, trichloroeicosyl-
1-Tetracosanol
19 20.49 2.25 C:\DATABASE\NBS75K.L
Naphthalene, decahydro-2-methyl-
7-Hexadecyne
Bicyclo[4.1.0]heptan-3-one, 4,7,7-
20 20.89 1.75 C:\DATABASE\NBS75K.L
Naphthalene, decahydro-2-methyl-
Naphthalene, decahydro-2-methyl-
Cyclohexanone, 2-methyl-5-(1-methy
21 21.37 1.44 C:\DATA3ASE\N3S75K.1
Tridecane, 1-bromo-
Hexadecane, i-bromc-
Oxirane, [(tetradecyloxy)methyl]-
22 21.75 1.13 C:\DATA3ASE\N3S75K.L
5-Undecyne
trans,cis-1,6-Dimethylspiro[4.5j de
3-Octvne, 5-methyl-
23 22.12 2.08 C:\DATA3ASE\N3S~5K.L
Dodecane
Doaecane
Dodecane
32056 007320-37-8 27
54853 018733-57-8 27
49775 000506-51-4 27
67009 002958-76-1 90
28265 074685-28-2 83
10380 004176-04-9 64
67009 002958-76-1 83
67008 002958-76-1 81
10308 007764-50-3 60
71786 000765-09-3 49
"'2567 000112-82-3 41
37802 038954-75-5 38
67011 002294-72-6 55
14144 000000-00-0 53
4258 062108-33-2 50
68250 000112-40-3 70
63249 OOC112-40-3 7C
66252 000112-40-3 70
23.67
26
:4 .13
4.13 C: \DATA3ASE\N3S75K. I
Cyclohexane, 1,2, 3-trimerhyl-
Cyclotridecane
Cyclopentane, l-pentyl-2-propyl-
2.51 C
: \DATA3ASE\N3S7 5K . L
1'ndecane, 2, 6-dimethyl-
Octane, 2, 3, "/-trinnetnyl-
Nonane, 4-methyl-5-propyl-
0.93 C : \DATABASE\N3S7 5K . L
Cycloocrane, 1, 4 -dimethyl-, trans
Cyclohexane, 1, 2, 3-trimetnyl-, (1
6-Tridecene, 7-merhyl-
4.14 C:\DATABASS\N3S75K.L
Tridecane
Tridecane
Tridecane
4646 001678-97-3 68
16483 000295-02-3 62
18495 062199-51-3 62
19058 0173C1-23-4 72
116C3 062016-34-6 72
19021 062185-55-1
59
7608 013151-98-9 70
4622 001839-86-9 45
69534 024949-42-6 43
69019 000629-50-5 92
18989 000629-50-5 "0
69020 000629-50-5 62
7981910.D
Fri Aug 28 15:00:33 1998
Pace .3
176
-------
Pk# RT
Area!
Library/ID
Reftt
CAS# Qual
28 24.53 1.72 C:\DATABASE\NBS75K.L
Cetylpyridinium Chloride
1-Dotriacontanol
Silane, trichloroeicosyl-
29 25.65 2.00 C:\DATABASE\N3S75K.L
Heptadecane, 2,6,10,14-tetramethyl
l-Iodo-2-methyiundecane
Dodecane, 2, 6,11-trirtiethyl-
30 26.00 ~.08 C:\DATA3ASE\N3S75K.L
Tetradecane
Tetradecane
Hydroxylamine, 0-decyl-
50020 006004-24-6 49
57795 006624-79-9 30
54853 018733-57-8 27
42200 018344-37-1 80
41997 073105-67-6 72
70271 031295-56-4 72
69661 000629-59-4 93
69658 000629-59-4 70
15973 029812-79-1 70
7981910.D
Fri Aug 28 15:01
15
1998
Page 4
-------
.U . U
S-M18-2
iak#
1
2
3
4
5
6
7
8
9
10
11
12
13
14
-L 0
16
17
18
1 9
20
21
22
23
24
25
~6
_7
28
29
30
Ret Time
10.474
11.512
13.786
15.194
15.940
16.159
16.652
17.578
17.989
18.181
18.353
18.483
18.936
19.156
19.348
19.718
19.952
20.350
20.494
20.886
21.367
21.752
22. 117
22.949
23 . 666
24.045
24.126
24.535
25.652
26.005
Type
rBV
rVB
rBV
rVB
rVB
rBV
rBV
rVB
rVB
rBV
rW
rW
rVB
rBV
rW
rW
rVB
rVB
rBV
rBV
rV3
rW
rV3
rVB
r3V
rW
rW
rVB
rBV
rVB
Width
0.636
0.225
0.219
0.164
0.212
0.336
0.288
0.261
0.165
0.192
0.089
0.309
0.151
0.172
0.24"'
0.302
0.330
0.137
0.275
0.413
0.234
0.303
0.117
0. 634
0. 393
0.062
0.421
0.290
0. 359
1.208
Area
21749581
702688
513034
630620
726063
483694
814772
953947
821522
1103064
472118
1063219
460695
666305
759510
983674
1146137
552319
1133399
878578
725002
566797
1046226
2076158
1264257
466498
2080059
866092
1007236
3558428
Start Time
10.221
11.451
13.704
15.153
15.892
16.111
16.556
17.537
17.962
18.126
16.318
18.408
18.874
19.108
19.279
19.608
19.9'' 0
20.316
20.453
20.845
21.340
21.724
22 . 052
22. 922
23. 625
24.017
24.080
24.507
25. 611
25.970
End Time
10.857
11.676
13.922
15.317
16.104
16.447
16.844
17.797
18.126
18.318
16.408
18.716
19.025
19.279
19.526
19.910
20.240
20.453
20. 726
21.257
21.573
22.027
22.199
23.556
24.017
24.080
24.500
24.797
25.970
27.178
J7S
-------
S-M18-3
Peak*
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
, -~
X ;
-» r
j- £
' 9
20
2 _L
22
23
24
25
">6
i__ ;
28
2 9
30
Ret Time
10.
10.
11.
13.
14.
15.
15.
16.
16.
16.
17.
17.
18.
18.
•; *">
J. D .
"' 9 .
19 .
19.
19.
20.
22 .
23.
23.
s~*, /
^4 .
24 .
25.
26.
2 / .
27 .
30.
201
359
513
775
952
185
938
157
651
884
577
989
180
352
928
148
306
711
944
885
453
437
658
*i c^. /-
L/. D
2~0
654
005
224
905
164
Type
rBV
rW
rBV
rBV
rBV
rVB
rV3
rBV
rVB
rBV
2T v .3
rBV
rW
v.T TT T
r v v
rW
rW
rVB
rBV
~ T TT -
r v \
rVB
v-T -~
_ \' ^
-w«"*" 7" — '
— V ^
rYV
rVB
ZT ^3 v
rBV
j_ \ ^
rVB
rVB
r\^v
Width
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
r<
J .
p.
/
B
075
602
273
219
274
274
192
364
267
158
268
329
165
5~7
240
171
330
288
412
392
509
482
392
124
282
234
324
653
239
384
Area
2565563
11277526
503869
903615
1074316
618049
711888
1203289
915416
531066
1218396
1876924
1124655
2427532
807099
516327
792549
818242
1530864
998790
519648
1392597
850090
1284708
571984
634272
1629986
953903
5126790
1699568
Start Time
10.160
10.236
11.425
13.686
14.890
15.164
15.896
16.088
16.575
16.843
17.529
17.797
18.125
18.290
16. 86"?
19.107
- r> -•*> -7 f»
j. i» . Z / ?
19.608
19. 910
20.851
22.405
23.066
23.616
24.084
24.208
25. 606
25.964
27.169
27.864
30.103
End Time
10.236
10.837
11.698
13.905
' 15.164
15.438
16.088
16.452
16.843
17.001
17.797
18.125
18.290
18.867
19.107
19.278
19.608
19.896
20 . 322
21.243
22.914
23.547
24.009
24.208
24 . 491
25.840
2 6 . 2 & 8
27.823
30.103
31.486
-------
Information from Data File:
File
Operator
Acquired
Sample Name
iisc Info
Vial Number
D:\HPCKEM\1\DATA\079819\7981911.D
TAB
27 Aug 98 12:46 pm using AcqMethod 079819
S-M18-3
Search Libraries:
C:\DATABASE\NBS75K.L
C: \DATABASE\EXTRA. L
C:\DATABASE\T014TAR.L
Minimum Quality: 5
Minimum Quality: 5
Unknown Spectrum: Apex
Integration Params: current RTEINT parameters
Library/ IB
1 10.20 5.45 C:\DATABASE\NBS75K.L
Fc rmami de, N, N- d ime t hy 1 -
Formamiae, N,N-dimethyl-
2-3utanamine, (.-/-.)-
2 1C.36 23.95 C:\DATA3ASE\NBS75K.L
Formamide, N,N-dimethyl-
Formamide, K,N-dimethyl-
2-3utanarr.ine, (.+/-.)-
3 11.51 1.0~ C: \DATA3ASE\N3S ~' 5K.L
Hexane, 2, 2, 3-trimethyl-
Per.zane, 3--ezhyl-2, 2-dimethyl-
Penrane, 3-ethyl-2,2-dimethyl-
C:\DATA3ASE\N3S7 5K.L
Cyclopropane, I,l-dimethyI-2-
"-Oxabicyclo[4.1.0]heptane, 3-
Hydroxylamine, 0-dec'yl-
14.95 2.2E C:\DATA3ASZ\N3S75K.L
Nonane
Nonane
Nonane
1.31 C:\DATABASE\NBS75K.L
Benzene, l-bromo-2-fluoro-
Benzene, l-Dromo-3-fIuoro-
p-Bromofluorobenzene
C:\DATA3ASE\N3S75K.L
OMrane, (3-methylbutyl)-
1-lJKdecene, 5-methyi-
l-Pen\anol, 2-methyl-
15.94
62526 00006S-12-2 90
62525 000068-12-2 90
293 033966-50-6 66
62526 000068-12-2 &6
62525 000068-12-2 B6
298 033966-50-6 86
5165 016747-25-4 59
65109 C16":4''-32-3 59
65110 016747-32-3 59
1-me 4264 074779-84-3 16
cxir 7391 OOC106-S7-6 10
15973 029812-79-1 10
5163 000111-84-2 78
65145 000111-84-2 78
65143 000111-84-2 78
16035 001072-85-1 97
16034 001073-06-9 96
16036 000460-00-4 91
3027 053229-41-7 47
14702 074630-40-3 36
1775 000105-30-6 38
7981911.D
Fri Aug 28 15:32:16 1996
Page 1
JSP
-------
Pk# RT
Area%
Library/ID
Ref#
CAS# Qual
16.16, 2.56 C:\DATABASE\NBS75K.L
Oxirane, [(dodecyloxy) methyl]-
O'v
3-Undkcene, 6-methyl-, (E)-
HeptaneX 3-ethyl-2-methyl-
9 16.65 1.94 C:\DATABASE\N3S75K.L
2-Octene, 2,6-dimethyl-
Cyclopentane, ethyl-
cis-3-Decene
10 16.86 1.13 C:\DATA3ASE\N3S75K.L
2-Hexenal, 2-erhyl-
2-Heptenal, (Z)-
2-Heptenal, (E)-
11 1T.59 2.59 C:\DATA3ASE\N3S75K.L
Octane, 2,7-dimethyl-
Decane
Nonane, 2-methyl-
12 1^.99 3.99 C:\DATA3ASE\N3S75K.L
4-?yridinol, acetate (ester;
Benzene, l-ethyl-2-merhyl-
Benzene, 1,2,3-trimethyl-
32383 002461-18-9 47
14747 074630-52-7 43
8080 014676-29-0 38
7538 004057-42-5 52
1350 001640-89-7 49
7589 019398-86-8 49
64925 000645-62-5 43
2610 057266-86-1 30
2632 018829-55-5 30
8078 001072-16-8 59
66204 000124-18-5 53
66220 000871-83-0 53
6735 014210-20-9 43
64559 000611-14-3 35
64576 000526-73-8 35
39 C
: \ DATABASE \K3S 7 5K . L
Ocrane, l,l'-oxybis-
Nonane, 2, 6-cimezhyl-
Nonane, 3-methyl-
71250 000629-82-3 53
11596 C173C2-26-2 43
66201 005911-04-6 43
5.16 C : \ DATABASE \N3S 7 5K . L
7-Hexaaecyne
3-Hexadecyne
Spiropentane, butyl-
1.71 C : \DATA3ASE\N3S7 5K . L
Cyclopropane, 1, 2-dimethyl-l-penty
5-Unaecene, (E;-
6-Octenal, 3, 7 -dimethyl -
1.10 C : \DATABASE\N3S7 5K . L
cis-7-Dodecen-l-ol
2-Decen-l-ol, (Z)-
1, 10-Undecadiene
19.31 1.66 C:\DATABASE\NBS75K.L
6-Oxabicyclo[3.1.0]hexane
4-?entenal
2,7-Octadiene, 4-methyl-
28265 074685-28-2 58
26271 061886-62-2 53
4219 006191-90-8 52
7541 062238-04-4 ^6
67164 000764-97-6 72
11019 000106-23-0 62
18959 020056-92-2 52
11570 004194-71-2 36
10429 013688-67-0 38
575 000285-67-6 25
5"! 002100-17-6 25
4209 000000-00-0 25
'961911.D
Fri AUQ 28 15:33:41 1996
Page 2
181
-------
Pk# RT Area%
18 19.71
Library/ID
Ref#
CAS# Qual
19 19.94
20 20.89
LL
:3.66
24.2'
25.65
26.01
1.74 C:\DATABASE\NBS75K.L
3-Octyne, 6-methyl-
Diphosphoric acid, diisooctyl este
4-Undecene, (E)-
3.25 C:\DATA3ASE\NBS75K.L
Decane
Tetradecane
Decane
2.12 C:\DATA3ASE\NBS75K.L
Naphthalene, decahydro-2-methyl-
7-Kexadecyne
3-Cyclohexene-l-carboxaldehyde, 1,
1.10 C:\DATA3ASE\N3S75K.L
Undecane, 2,6-dimethyl-
Undecane, 3,6-dime-hyl-
Eicosane
2.96 C:\DATABASZ\N3S75K.L
2-Kexyl-1-decanol
Ethanone, 1- (2, 2-dimerhylcycloper.r
1-Octadecanol
'..z+ C: \DATA3ASZ\1\~3S~5K.L
Heptadecane, 2,6-dimethyi-
Nonane, 3-iriethyl-
Octane, 2,3,7-rrimethyl-
2.^3 C : \ DAT ABAS Z \ N3 S ~' 5 K. L
Tridecane
Tridecane
Pentacosane
:\DATABAS Z\N3S75K.I
1-Terradecene
3-Terradecene, ;Z;-
3-Tetradecene, (E)-
1.35 C:\DATABASE\N3S7 5K.L
Heptadecane, 2,6,10,14-tetramethyl
Dodecane, 2, 6, iO-trimetiryl-
Dodecane, 2, 6,10-trimethyl-
3.46 C:\DATA3ASE\N3S75K.L
Tetradecane
Decane, 2-me~hyl-
Tetradecane
4262 062108-34-3 38
54052 072101-0*7-6 35
11061 000693-62-9 30
66206 000124-18-5 72
69661 000629-59-4 64
66205 000124-18-5 59
67008 002958-76-1 53
28265 074685-28-2 46
66952 040702-26-9 46
19058 017301-23-4 64
19000 017301-28-9 50
72326 000112-95-8 47
32422 000000-00-0 58
7482 003664-75-3 38
72028 000112-92-5 35
37466 054105-67-8 64
6075 005911-04-6 64
11603 062016-34-6 59
69019 000629-50-5 95
18989 000629-50-5 87
73718 000629-99-2 80
69532 001120-36-1 46
21966 041446-67-7 45
21967 041446-68-8 45
42200 018344-37-1 80
25995 003891-98-3 72
70269 003891-98-3 72
69658 000629-59-4 93
67320 006975-98-0 63
69657 000629-59-4 81
7981911.D
Fri Aug 28 15:35:30 1996
Page 3
182
-------
Pk# RT
Area%
Library/ID
Ref#
CAS# Qual
28 27.22 2.03 C:\DATABASE\NBS75K.L
Heptadecane, 2,6,10,14-tetramethyl
Tetradecane
Dodecane
29 27.91 10.89
30 3C.16 3.61
C:\DATABASE\N3S75K.L
Pentadecane
10-Methylnonadecane
Tridecane, 4,8-dimethyl-
C: \DATABASE \NBS7 5K. L
Hexadecane
Triacontane
Eicosane
42200 018344-37-1 90
69661 000629-59-4 80
68254 000112-40-3 80
70276 000629-62-9 90
39858 000000-00-0 86
26000 055030-62-1 80
70787 000544-76-3 96
55461 000638-68-6 86
72323 000112-95-8 83
7981911.D
Fri Aug 28 1
:36:09 1996
Page 4
183
-------
Information from Data File:
File
Operator
Acquired
Sample Name
'isc Info
Vial Number
D:\HPCKEM\1\DATA\079819\7981912.D
TAB
27 Aug 98 1:46 pm using AcqMethod 079819
S-M18-4
Search Libraries:
C:\DATABASE\NBS7 5K.L
C:\DATABASE\EXTRA.L
C:\DATA3ASE\T014TAR.L
Minimum Quality: 10
Minimum Quality: 10
Unknown Spectrum: Apex
Integration Params: current. ETEINT parameters
?kr R7
Area%
Library/ID
Reffr
CAS I?
Qual
10.19 42
-i n
— V '
36 46
1 c . -. y
:\DATABAS E\NBS 7 5 K.L
Formamide, N,N-dimethyl-
Formamide, N,N-dimethyl-
2-3u~anamine, (.-/-.)-
92 C:\DATA3ASE\N3S75K.L
Formamide, N,N-dimethyl-
Formamioe, N,N-dimethyl-
2-3uranamine, (.-f/-.)-
84 C:\DATA3ASE\N3S75K.L
2-Hydroxypyridine
1, z, 4 f 5-3enzer.ete"cracarboxylic anr.
2-Hydroxypyridine
71 C:\DATABAS E\N3S 7 5 K.L
Benzene, l-bromo-2-fluoro-
Benzene, l-bromo-3-fluoro-
Benzene, l-bromo-3-fluoro-
62526 000068-12-2 90
62525 000068-12-2 90
298 033966-50-6 86
62526 000068-12-2 86
62525 000066-12-2 86
298 033966-50-6 86
63081 D00142-08-5 12
2"?C7C OOOC89-32-7 12
63080 000142-08-5 10
16035 001072-85-1 96
16034 001073-06-9 96
68407 001073-06-9 90
981912.D
Thu Aug 27 14:17:14 1998
Page 1
184
-------
S-M18-4
Peak* Ret Time Type Width Area Start Time End Time
I 10.457 rm 0.492 24450783 10.154 10.646
2 •LS.IBS rm 0.253 772573 15.001 15.254
3 20.637 rm 0.659 219077 20.254 20.913
185
-------
- \U / ybiy.S
Comment:
Operator:
Data Path: d:\HPCHEM\l\DATA\079819\
Pre-Seq Cmd:
Post-Seq Cmd:
Method Sections To Run On A Barcode Mismatch
(X) Full Method (X) Inject Anyway
( ) Reprocessing Only ( ) Don't Inject
Line Type Vial DataFile Method Sample Name
1) Blank 1 798196 079819 blank & is
2} Blank 2 79&197 C79&19 rlanK & is
3) Sample 5 798198 079&19 S-M18-1
4) Sample 6 798199 C79819 S-K18-2
b) Sample 7 7981910 079819 S-M18-3
6] Sample S "981911 0'SEIS S-M18-4
7) Blank 2 79?«i912 079819 blank & is
,ast Modifiec: Thu Aug 27 06:12:36 1998 Page: 1
-------
TOPLEVEL PARAMETERS
Method Information For: C:\HPCHEM\1\METHODS\079819.M
Method Sections To Run:
( ) Save Copy of Method With Data
( ) Pre-Run Cmd/Macro =
(X) Data Acquisition
(X) Data Analysis
( } Post-Run Cmd/Macro =
Method Comments:
This is direct injection Volatile method.
END OF TOPLEVEL PARAMETERS
ACQUISITIOK PARAMETER;
rai -nrcrmaticn
?une File : ATUNE.U
Accuisition Moae : Scan
IS Information
olvent Delay : 6.00 min
,M Absolute : True
esulting Voltage : 1600.0
Scan Parameters]
ow Mass : 35
igh Mass : 350
nreshold : 500
ampling £ : 2 A/D Samples 4
2thod: 079819. M Thu Aug 27 14:32:27 1998 Page: 1
- Q«
-------
Time Window : 10 min
'.conize Real Time Display : False
>lot 1 type : Total ion
male minimum : 1
le maximum : 1500000
•j.ot 2 type : No plot
C Temperature Information
3C Zone Temperatures]
ij . A : 250 C Off
ij. 3 : 190 C
2t. A : 50 C Off
5t. B : 300 C
)ven Parameters!
-en Equic Time : 0.20 r
•en Max : 325 C
•en : On
vo : Off
itial Terno. : 40 C
/el Rate (C/rrdr.) Final Temp. (C) rinal Time (min)
I 6.00 210 1.00
2 0.00
•ct Run Time : 2~7.25 min
ector Information
ection Source : Manual
rge Infcrmaticnj
ge A/E :nit. Value On Time Off Time
7. f~\ ^ _;• r>oo r* r\ r^
/i U' — -L. v^ . ^ L, l^' . C v
B Off 0.50 0.00
JOG: 079819.M Tnu Aug 27 14:32:27 1998 Page: 2
188
-------
END OF ACQUISITION PARAMETERS
DATA ANALYSIS PARAMETERS
Method Name: C:\HPCHEM\1\METHODS\079819.M
Percent Report Settings
Sort By: Retention Time
Output Destination
Screen: Yes
Printer: No
File: No
Integration Events: Autelr.tegrate
Senerate Report During Run Method: No
Signal Correlation Window: O.C2G
qualitative Report Settings
3eak Location of Unknown: Apex
-ibrarv to Searcn Minimum Quality
:: \DATABASE\NBS75K.L 0
.eport Type: Summary
'utput Destination
Screen: No
Printer: Yes
File: No
enerate Report During Run Method: No
j itative Report Settings
sthod: 079819.M Thu Aug 27 14:32:27 1998 Page: s!89
-------
Report Type: Summary
Output Destination
Screen: No
Printer: Yes
File: No
Generate Report During Run Method: No
'.aliDration Last Updated:
eference Window: 10.00 Percent
on-Reference Window: 5.00 Percent
orrelation Window: 0.02 minutes
efault Multiplier: 1.00
sfault Sample Concentration: 0.00
Dmpound Information
rT tjnpty Quant it at ior. Dataoass
END OF DATA ANALYSIS PARAMETERS
nod: 079819.M Thu Aug 27 14:32:27 1998 Page: jQQ
-------
Silo
GC/FID Data
191
ENTHALPY analytical, inc.
-------
Company:
Analyst:
Parameters:
# Samples:
PES
BGP
Organics
11
Client 1h
Enthalpy #:
P0#:
Report Date:
R012.001
0798-19
104980229
09/23/98
Compound
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Sample ID/Catch weight (ug)
S-M18-1A
691
801
1,092
809
967
1.524
615
754
S-M18-2A
2,528
283
921
1,635
771
526
1,198
349
S-M18-3A
2,371
394
944
955
- 654
494
1,180
340
S-M18-FB
- 7.35
< 5.00
- 20.6
- 31.4
- 7.66
< 5.00
< 5.00
< 5.00
ENTHALPYanalytical. inc.page:
O
J:\JOBS98\J07\079S-19\0798-19B.WB2 10:40 AM 09/23
-------
MDL:
LOQ:
I 00
5.00
ppm
ppm
Curve range (7.34 - 388 ppm)
Company:
Andy*
Pimnden:
IStmfkr.
PES
BGP
llcxane
11
Cltanl 1;
KnUuUpy*:
POI:
Report Dole:
ROI2 001
0798 19
104980229
09/17/98
"-.'liBBP^'''
*£ ~-^li&W^,',:'
S'lnJ','"i-l?
^iaSi'tH"
. . Retention Time (mln.)
" "ini.M
InJ.#2
Percent
Difference
Concentration ,
Inj. 11
hl.fl
S-M18-1A VGA
S-M18-1A FH
S-M18-1A BH
047F3401.0
029F3301 O
030F3401 O
047F3402 D
028F3302D
030F3402D
NA
1.427
NA
NA
1 444
NA
NA
I 19
NA
< 1 00 < I 00
145 131
< 1 00 < 1 00
S-M18-2A VGA
S-M18-2A FH
S-M18-2A BH
049F3601.D
031F1501 D
032F3601.D
049F3802D
031F1S02 D
032F3602D
1.447
1.464
1 465
1.447
1 462
1.466
000
0 14
007
538
532
< 1.00
53.9
53.0
< 1 00
S-M18-3A VGA
S-M18-3A FH
S-M18-3A BH
051F3801 D
033F1601 O
034F3B01 O
05IF3802D
033F16O2 D
OMF3802 D
1 445
1.460
NA
1 445
1 460
NA
000
000
NA
493
598
< 1 00
495
593
< 1.00
S-MT8-FB FH
S-M18-FB BH
035F1701D
036F4001 D
03SF1702 D
036F4002 O
1 465
NA
1 465
NA
000
NA
- 1 46
< 1 00
- 1.48
< 1.00
% Difference
of Mean
Average
Cone.
Cal.
. Curve
1000
> 5 %
000
< 1.00
138
< 1 00
0798- 19D
0798 19. M
0798 19 M
Volume
(ml-)
Dilution
Ratio
:C»tch Weight
10
5
5
1
1
1
008
024
000
539
53 1
< 1 00
0798 I9D
0798- I9D.
0798-19 M
1018 1 494
041 59.5
000 |< 1 00
0798-19D
0798 -19D
0798-19 M
093
000
- 1 47
< 1 00
0798- I9D
0798- 19 M
42
5 ,
5
1
1
1
42
5
5
1
1
1
5
5
1
1
< 100
691
< 500
691
2.262
265
< 500
2,528
2,073
298
< 5.00
Total
Catch Weight
691
2,528
2,371 1 2,371
- 735
< 500
- 735
- 735
! ENTHALPY^nalyt.c^l. inc.
I MOBSVtMUA07V8 ltf\O7V* IW WB2 10 04 AM 09/13
-------
.fc
3
MDL.
LOQ:
1.00
500
ppm
ppm
Curve range (7.85 - 416 ppm)
Company!
Parameter*!
1 Sampled
PES
BGP
Ben/ciie
II
CUtolf,
Eothalpy 'f;
POli
Report Data:
ROI2 001
0798-19
104980229
09/17/98
m
fflHL'tf'$
S-M18-1A VOA
S-M18-1A FH
S-M18-1A BII
S-M18-2A VOA
S-M18-2A HI
S-M18-2A BII
S-M18-3A . VOA
S-M18-3A ' FH
S-M18-3A BII
S-M18-FB FH
S-M18-FB BII
ij^^fflBW?^' "•'
* fell.' fW
M7F3401 D
029F33O1.D
030F3401.D
049F3601.D
032F3601 D
051F3801.D
034F3801 D
035F1701 D
036F4001 0
* ia\:i>i
047F3402 D
029F3302 O
030F3402 O
CW9F3602D
032F3602 O
OS1F3802D
034F3802 D
03SF1702D
036F4002 D
' Retention Time (win.)
lai.il"
NA
5438
NA
NA
NA
NA
NA
NA
NA
rhj.*2
NA
5.507
NA
NA
NA
NA
NA
NA
NA
Percent
Difference
NA
1 27
NA
NA
NA
NA
NA
NA
Concentration
In]. » 1
< 1 00
169
< 1 00
< 1.00
< 1 00
< 1 00
77 6
< 1 00
< 1 00
In|. 12
< 1 00
,5,
< 1 00
< 100
- 5fi.7_.
< 100
< ; oo
80.1
< 1 00
< 1 00
NA 1 < 1 00 I < 1 00
% Difference
of Mean
Eooo
> 5 %
000
000
0.22
000
000
1 60
000
000
000
Cone.
< 1.00
160
< 1 00
Curve
0798- I9D
0798-19 M
0798 19 M
< 1 00 10798 I9D
566
< 1 00
< 1.00
78 8
< 1.00
< 1 00
< 1 00
0798- I9D
0798 19 M
0798 I9D
0798- I9D
0798 19 M
0798- I9D
0798- 19 M
Volume
10
5
5
42
5
5
42
5
5
5
.
Dilution
Ratio
1
1
1
1
1
1
1
Catch Weight
<
<
<
<
<
<
<
100
801
5 00
801
420
283
500
283
420
394
5 00
394
5 00
500
500
Total
801
283
394
< 500
ENTHALPY analytical, me
IWUTW itp w«z 10 as AM
-------
MDL: 1.00 ppm
I.OQ. 5.00 pp"1
Curve range (7.77 - 411 ppm)
Caw*")"
AMlyrt:
Parameters:
J Samples:
PES
BOP
Toluene
11
CUoot f I
RWluilr.yJ':
PO*
Report Date:
ROI2 001
0798 19
104980229
09/17/98
1 -vrS^SS^^-M
V^'idwilleMiln ' "^"\ '
v.« A • •"• •&!) rt> '* •
,,K,,1/,,»,,:
Retention Time (ruin.)
' feh i f
In). 12
Percent'
Difference
Concentration
InJ.*l
InJ.fi
S-M1B-1A VOA
S-M18-1A HI
S-M1B-1A Bll
047F3401 O
029F3301 D
030F3401.D
047F3402 O
029F3302 D
030F3402 D
7.261
7303
NA
7271
7.362
NA
0 14
081
NA
' 246
224
< I 00
-233
203
< 1 00
S-M18-2A VOA
S-M1B-2A FH
S-M18-2A Bll
048F3601 D
031F1S01.O
a»F38O1 D
049F3602.D
031F1S02D
O35F38O2D
NA
7.367
7.393
NA
7.391
NA
003
< 1 00
~- 1 21
< I 00
- 1 15
S-M18-3A VOA
S-M18-3A Fli
OS1F3801.D
033F1601 O
051F3802 D
033F1602 D
7.424
7382
7427
7.383
004
00!
< 1 00
188
- i •>*
< 1 00
187
- 1 7S
S-M18-FB Fll
I S-M18-FB BM
035F170I 0
|036F4001 O
035F1702 D
7.388
7.387
001
- 301
- i n«
- 3 03
- i in
% Difference
of Mean •
Average
Cone,'
C»l.
Cui-ve
Volume
5 %
000
- 240
214
< 1 00
0798-19D
0798-19.M
0798-19 M
10
5
5
1
1
1
0.00 |< 1 00 10798- I9D.
082 I 183 0798-19D
2 47 _| - 1 18 J0798-I9 M
42 1
5 1 1
"5 I " 1
1000
021
000
< 1 00 0798 19D
187 0798-19D.
- 1 25 0798 19 M
42 1
5 '
5 1
042
096
- 302
- 1 09
0798 I9D
0798-19 M
5
5
j
' 240
1,068
< 500
1,092
< 420
915
- 588
921
< 420
937
- 6.25
944
- 15 1
- 545
- 206
Total
Catch Weight
1,092
921
944
- 206
ENTHALPY analytical, inc
i uousvB\tU7\bvyi ,y\o7ys IVB wo? to us AM mm
-------
J. MDL- 1.00 ppm
LOQ: 5.00 ppm
Curve range (7 73 - 409 ppm)
'!$BSsPi5S|IBMf!$O ••, ; ;" ."£»fi*pK!s,"''.
>vifeidenfino»ti6n_..: <• inj, t"L .r.osi. vi •
Retention Time (mln.)
InJ.*l 1 M.t2
Camfny.
Amlyrt:
Parameter!:
1 Samples;
PES
BOP
Elhyllwiueitt
II
Cltoorl:
fOI:
Report Date:
ROI2 001
0798-19
104980229
09/17/98
Percent
Difference
Concentration ,
fnj.fl | InJ. 12
* Difference
of Met®
Ayernge
Cone,
Coll
Curve
Volume
(mL)
Dilution ;f"*^»tchWelglit , TStlJ V '
Ratio (UK) Catch Weight
S-M18-1A VGA
S-M18-1A FH
S-M18-1A Bll
S-M18-2A VGA
S-M18-2A FH
S-M18-2A Bll
S-M18-3A VOA
S-M18-3A FH
S-M18-3A nil
S-M18-FB FH
S-M18-FB BH
047F3401 D
029F33O1 D
030F340I O
(M9F3601 D
032F3601 D
051F380I D
033F1601 O
034F3801 O
035Ft701 D
036F4001.O
047F3402 D
029F3302 O
030F3402 0
049F3602D
032F3602 D
OS1F3802 O
033F1602 D
034F3802 D
035F1702 0
036F4002 D
8981
9236
NA
NA
9 179
9076
9048
9 174
9 176
9 179
8.991
9 157
NA
NA
9.180
9073
9.181
9 178
9 175
9 178
0 11
086
NA
NA
001
003
1 47
004
OOj
001
- 1 07
189
< 1 00
< 1 00
1 318
- 1 65
' 256
284
- 150
-473
- 1 54
' 1 09
130
< 1 00
I< 1.00
333
- 1 67
- 2.58
52
- 1 59
- 473
' 1 55
090
> 5 %
000
000
225
0.45
036
> 5 %
297
004
055
- 1 08
160
< 1 00
< 1.00
325
-1.66
- 257
168
- 1.55
- 473
- 1 55
0798- I9D
0798 19 M
0798 19 M
0798-19D
0798- I9D
0798 I9.M
0798- I9D
0798 19D
0798 19 M
0798 19D
0798- 19 M
10
5
5
42
5
5
42
5
5
5
5
1 i '
i
,
i
i
i
i
i
,
1
1
• 108
798
< 500
809
< 420
1.626
- 8.31
1,635
' 108
840
' 773
955
' 23 6
- 773
- 31 4
809 |
1,635 |
955 |
-31.4 |
ENTHALPY analytical, inc.
IVB WBI in 03 AM
-------
MDL:
I.OQ:
I 00
500
ppm
ppm
Curve range (7.79 - 412 ppm)
Company:
Parameter*!
1 S«mpkj;
PES
BGP
p-Xylenc
II
"Ctteitf:
IflUuUp,*
Report Date:
R012 001
0798-19
104980229
09/17/98
';iiiSS-<'-; "
py-."'^'ft^.... |
''a"-lTO.:»*- 1
Retention Time (min.)
L Inl.*l 1 InJ.12 1
Percent
Difference
Concentration
InJ, 11 1 Inj.la
% Difference
of Menu
Average
Cone.
Cul.
Curve
Volume
(ml)
Dilution
Ratio
' Catch VYelght
M
Total
Catch Weight
S-M18-1A VOA
S-M18-1A FH
S-M18-1A BI1
S-M18-2A VOA
S-M18-2A FH
S-M18-2A ' BH
S-M18-3A VOA
S-M1B-3A Fll
S-M18-3A BH
S-M18-FB Fll
S-M18-FB Bll
047F3401 O
029F3301.D
030F3401 D
049F3601 O
031F1501 O
032F3601 D
OS1F3801 O
033FI601 D
034F3801 D
035FI701 D
036F4001 O
047F3402 D
029F3302 0
030F3402D
049F3602D
031F1S02 0
032F3602 D
051F3802 D
033F1602 0
034F3802 O
03SF1702.D
036F4002 O
NA
9393
NA
NA
9322
9341
9284
9321
NA
9.338
9342
NA
9.294
NA
NA
9319
9340
9284
9.324
NA
9337
1 9 337
NA
1 05
NA
NA
003
001
000
003
NA
001
1 005
< 1.00
214
< 1 00
< 1.00
157
< 1.00
- 180
116
< 1 00
- 1 54
< 1 00
< 1 00
173
< LOO
< 1 00
151
< 1 00
- 183
115
< 1 00
- 1.53
< 1 00
000
> 5 %
000
000
201
000
085
046
000
033
000
< 1 00
193
< 1 00
< 1 00
154
< 1 00
- 1 81
116
< 1 00
- 1 53
< 1 00
0798 I9D
0798- 19 M
[0798 19 M
0798 I9D.
0798 -19D
0798 19 M
0798 I9D
0798- I9D
0798- 19 M
0798 191)
0798-19 M
10
5
5
42
5
5
42
5
5
5
5
1
1
1
1
1
1
1
1
1
1
1
< 100
967
< 500
967
< 42.0
771
< 500
771
- 76 1
578
< 500
654
- 766
< 500
" 7 66
967 |
1
771 |
654 |
-, CL 1
7 66 I
PY
I9B WB2 10 06 AM OWI3
^n^K/nr
-------
MDL: 1 00 ppm
LOQ: 5.00 ppm
Curve range (7.74 - 409 ppm)
!£-.$: ^;W,-W6V*V
- Retention time (mln.)
" InJ.Tf * I InJ.*2 '
1 Sampltai
PES
BGP
ni-Xyleiie
11
•' Report D«(«:
ROI200I
0798-19
104980229
09/17/98
Percent . .
Difference
Concentration ' ,
JnJ. Hi | InJ. 1 2 '•'
% &(Wertnc(!
, of Mean .
'Average
ConCi. _.
Cal.
_CuiVe
• Volume
(mL)
Ratio .:i > (aid Catch Weight
S-M18-1A VGA
S-M1B-1A FH
S-M1B-1A BII
S-M18-2A VOA
S-M18-2A FI1
S-M18-2A DH
S-M18-3A VOA
S-M18-3A FH
S-M18-3A BII
S-M18-FB • FI1
S-M18-FB BII
047F3401.D
029F3301 0
030F3401 D
049F3601 D
032F3601 D
051F3801 D
033F1601 O
034F3801 O
035F1701 0
038F4001 O
047F3402 D
029F3302O
030F3402 O
049F3602D
032F36O2 D
OS1F3602 D
033F1602 D
034F3802 O
03SF1702 D
036F4002D
9.538
9743
NA
NA
NA
NA
9475
NA
9474
NA
9.545
9449
NA
NA
NA
NA
9475
NA
9475
NA
0.07
>3 %
NA
NA
NA
NA
000
NA
001
NA -
- 1 47
412
< 1.00
< 1 00
< 1.00
< 1 00
97 33
< 1 00
< 1 00
< 1 00
1- 1 44
192
< 1 00
< 1 00
< 1 00
< 1 00
100
< 1 00
< 1 00
< 1 00
1.02
> 5%
000
000
1 07
000
000
1.54
000
000
000
- 1 46
302
< 1 00
< 1 00
105
< 1 00
< 1 00
989
< 1 00
< 1 00
< 1 00
10798 19D
0798 19 M
0798 19 M
0798- I9D
0798 19D.
0798 19 M
I0798-I9D
0798 I9D
0798 19 M
0798 19D.
0798 19 M
10
5
5
42
5
5
42
5
5
5
5
tl
,
- 1 -
1
_.....
1
1
1
1
1
" 14 6
1 509
< 500
1,524
< 420
526
< 500
526
< 42 0
494
< 5 00
494
< 5 00
< 500
< 5 00
1.524 |
526 |
494 |
< 500 |
ENTHALPYanalyncal.
inc.
I'\IOBS»IMOWJI IW>»| IWWBt ID IK AM OWJJ
-------
MDL:
LOQ:
1 00
5 00
ppm
ppm
Curve range (7.70 - 407 ppm)
ParamtMn:
ISimpfej:
PES
BGP
Cunicne
II
CUiolfi
BniMpyf!
POf:
Report Date:
R012 001
0798 19
104980229
09/17/98
-Jferfentlfa Time (rota.)
Inl.ll I InjTTT
Percent
Difference
Concentration
InJ.ll" ")• InJ. f 2
% Difference
of Mean
Average
Cone.
Cal.
Curve
Volume
(ml.)
Dilution
Ratio
Catch Weight
(ug)
Total
Caleb Weight
S-M18-1A VOA
S-M18-1A FH
S-M1S-1A BH
S-M18-2A VOA
S-M18-2A FH
S-M1B-2A BH
S-M1B-3A VOA
S-M1B-3A FH
S-M18-3A BH
S-M18-FB FH
S-M18-FB BH
047F3401 D
028F3301 D
030F3401D
OOF 3601 O
031FI501 O
032F3601 D
OS1F3801 D
033F1801 O
034F380I O
035F1701 O
036F4001 O
047F3402D
029F3302 0
030F3402 D
049F3802 D
031F1S02D
032F3602D
051F3802 D
033F1602D
OMF3802D
035F1702 D
036F4002 0
NA
10.169
NA
NA
9994
NA
9994
9988
NA
10.102
NA
NA
10223
NA
NA
9991
NA
9993
9990
NA
10 101
NA
NA
053
NA
NA
003
NA
001
002
NA
001
NA
< 1 00
129
< I 00
< 100
240
< 1 00
532
192
< 1 00
< 1 00
< 1 00
< 1 00
117
< 1 00
< 1.00
239
< 1 00
535
190
< 1 00
< 100
< 100
000
484
000
000
009
000
021
038
000
000
000
< 1 00
123
< 1 00
< 1 00
240
< 1 00
533
191
< 1 00
< 1 00
< 1 00
0798 190
0798- 19 M
0798-19 M
0798 I9D
0798 I9D
0798 19 M
0798- I9D
0798 I9R
0798 19 M
0798- 19D
0798-19 M
10
5
5
42
5
5
42
5
5
5
5
1
1
1
1
1
1
1
1
1
1
1
< 100
615
< 500
615
< 420
1,198
< 500
1.198
224
956
< 5 00
1,180
< 500
< 500
< 500
615 |
1.198 1
1,180 |
< 500 |
PMTHAUPY^rialvtical. inc
* iv&ne iva WBI 1007 AM 1*9/23
-------
MDL:
LOQ:
I 00
5 00
ppm
ppm
Curve range (7.67 - 406 ppm)
Cootpwy;
Anulyri:
P.raroe(«r»i
1 Suupleii
PES
BGP
o Xylene
11
pit*'*
EWknlpff:
•' ~m
Report D«U:
ROI2 001
0798 19
104980229
09/17/98
Retention Time (mln.)
Inl.
Inl. 12
Percent
Difference
Concentration
lnj;*f I
% Difference
of Mean ',
Average
Cone.
Cal.
Curve
Volume
(ml)
Dilution
Ratio
Catch Weight
(UK)
Total
Catch Weight
S-M18-1A VGA
S-M18-1A Fll
S-M18-1A BII
S-M18-2A VOA
S-M18-2A Fll
S-M18-2A BM
S-M18-3A VOA
S-M18-3A FH
S-M18-3A BII
S-M18-FB Fll
S-M18-FB BII
047F3401 D
029F3301 D
030F3401D
049F36Q1 O
031F1501 D
032F3601 D
OS1F3801 D
033F1601O
034F3801.0
035F1701 O
036F4001 O
M7F3402 O
029F3302 O
030F3402 O
049F3602 O
031F1S02 D
032F3602 O
OS1F3802 O
033F16020
034F3602 D
035F1702 D
036F4002D
10.656
10308
NA
NA
10386
NA
NA
10389
NA
NA
NA
10664
10364
NA
NA
10380
NA
NA
10389
NA
NA
NA
008
054
NA
NA
006
NA
NA
000
NA
NA
NA
- 156
155
L< 100
< 1 00
684
< 1 00
< 1 00
675
< 1 00
< 1.00
< 1.00
- 1 48 ~
140
< 1 00
< 100
71 2
< 1 00
< 1 00
686
< 100
< 1 00
< 1 00
280
> 5 %
000
000
200
000
000
083
000
000
000
- 1 52
148
< 1 00
< 1 00
698
< 1 00
< 1 00
68 1
< 1 00
< 1 00
< 1 00
0798- 19D.
0798 19 M
0798 19 M
0798- 19D
0798- 19D
0798 19 M
0798 19D
0798 I9D
0798 19 M
0798 19D.
0798 19 M
10
5
5
42
5
5
42
5
5
5
5
1
1
1
1
1
1
1
1
1
1
- 152
738
< 500
754
< 420
349
< 500
349
< 420
340
< 500
340
< 500
< 5.00
< 500
754 |
349 |
340 |
< 500 |
ENTHALPY analytical, inc.
-------
Data File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19C\047F3401.D
S-M18-R1 A VOt
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
FTOIA. (0798-
8/5/98 8:12:24 PM
S-M18-R1 A VOA
bgp
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19D.S
E:\HPCHEM\TELLER\METHODS\0798-19A.M
8/3/98 3:07:34 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19D.M
8/10/98 4:33:19 PM by bgp
34
47
1
counts
2000 -
10
15
20
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FID1 A,
Signal
8/10/98 4:32:29 PM
1.0000
1.0000
RetTime
[min]
1.463
5.391
7.261
8.981
9.323
9.538
10.084
10.656
Totals
Type
i
1
BB
PP
PB
PV
.
Area
counts*s
-
3496.70679
1523 .99316
2083.59888
2287.66577
Amt/Area
-
-
7.04194e-4
7.040476-4
7.059226-4
6.828546-4
Amount G
[ug/kg]
-
-
2.46236
1.07296
1.47086
1.56214
6.56832
rp Name
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Results obtained with enhanced integrator!
2 Warnings or Errors :
Warning : Calibration warnings (see calibration table listing)
Warning : Calibrated compound(s) not found
201
ft/in/Qfi 4;49:40 PM bOP
Page I of 2
-------
Data File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19C\047F3402.D S-M18-R1 A VGA
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
8/5/98 8:42:19 PM
S-M18-R1 A VOA
bgp
FIDl A. (0798-19C\047F34U2.D)
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\Q798-19D.S
E:\HPCHEM\TELLER\METHODS\0798-19A.M
8/3/98 3:07:34 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19D.M
8/10/98 4:33:19 PM by bgp
34
47
2
counts -
5500 -
5000 -
4500 -
4000
3500 -
3000 -
2500 -_
2000 -
0
10
15
20
External Standard Reoort
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FIDl A,
Signal
8/10/98 4:32:29 PM
1.0000
1.0000
RetTime
[min]
1
5
7
8
9
9
10
10
.463
.391
.271
.991
.323
.545
.084
.664
Type Area
counts*s
1 i
1
BB
PP
PB
PV
1
3314
1551
2041
2163
-
.64355
.56201
-
.66711
-
.11621
Amt/Area
I
7
7
7
6
_
-
.041946-
.04047e-
-
.059226-
-
l
4
4
4
.828546-4
Totals :
Amount
[ug/kg]
2
1
1
1
6
_
-
.33415
.09237
-
.44126
-
.47709
.34487
Grp Name
1 _
1
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Results obtained with enhanced integrator!
2 Warnings or Errors :
Warning : Calibration warnings (see calibration table listing)
Warning : Calibrated compound(s) not found
202
Teller 8/10/98 4:49:53 PM bgp
Page 1 of 2
-------
Data File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19B\029F3301.D S-M18-R1 Aa+AbFH
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
8/3/98 10:13:14 AM
S-M18-R1 Aa+AbFH
Seg.
Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19A.S
E:\HPCHEM\TELLER\METHODS\0 79 8 -19A.M
7/31/98 6:22:19 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19.M
8/3/98 12:59:48 PM by bgp
33
29
1
FID1 A, (0798-19B\029F3301.D)
counts J
10
15
20
mirt
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal
8/3/98 11:04:16 AM
1.0000
1.0000
Signal 1: FIDl A,
RetTime
[min]
Type
Area
counts*s
Amt/Area
Amount
[ug/kg]
Grp
Name
1.427 W
5.438 W
7.303 W
9.236 W
9.393 W
9.743 W
10.169 W
10.308 W
Totals :
1.6321465
2.1287965
2.8828165
2.44732e5
2.73796e5
5.3107765
1.52252e5
2.0632865
8.911556-4
7.955936-4
7.787006-4
7.723106-4
7.799866-4
7.75922e-4
8.46657e-4
7.52583e-4
145.44933
169.36479
224.48417
189.00882
213.55716
412.07445
128.90518
155.27882
1638.12271
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Results obtained with enhanced integrator!
1 Warnings or Errors :
Warning : Calibration warnings (see calibration table listing)
203
Teller 8/4/98 7:55:54 AM bgp
Page 1 of 2
-------
ata File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19B\029F3302.D S-M18-R1 Aa+AbFH
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
8/3/98 10:43:09 AM
S-M18-R1 Aa+AbFH
bgp
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19A.S
E:\HPCHEM\TELLER\METHODS\0798-19A.M
7/31/98 6:22:19 PM by bgp
S:\HPCHEM\TELLER\METHODS\0798-19.M
8/3/98 12:59:48 PM by bgp
33
29
2
FID1 A, (0798-19B\029F3302.D)
counts -
17500 -
15000-
12500 -
10000-
0-
10
15
20
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FID1 A,
Signal
8/3/98 11:04:16 AM
1.0000
1.0000
RetTime
[min]
1.444
5 .507
7 .362
9 .157
9.294
9.449
10.223
10.364
Type
W
W
W
W
W
W
W
W
Area
count s*s
1. 47009e5
1.8969165
2. 6023065
1.68426e5
2 .21887e5
2.46637e5
1.3813965
1.8607165
Amt/Area
i
8.913166-4
7.958476-4
7.788896-4
7.733276-4
7 .804516-4
7.771336-4
8.469466-4
7.528846-4
Amount
[ug/kg]
131.03177
150.96457
202 .69023
130.24839
173 .17158
191.66947
116.99614
140.08986
Grp Name
1
!
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals :
1236.86202
Results obtained with enhanced integrator!
1 Warnings or Errors :
Warning : Calibration warnings (see calibration table listing)
204
slier 8/4/98 7:56:15 AM bgp
Page 1 of 2
-------
Data File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19B\030F3401.D
S-M18-R1 AbFH
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
8/3/98 11:12:49 AM
S-M18-R1 AbFH
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19A.S
E:\HPCHEM\TELLER\METHODS\0798-19A.M
7/31/98 6:22:19 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19.M
8/3/98 12:59:48 PM by bgp
34
30
1
FID1 A, (0798-198\030F3401.D)
counts
17500 T
15000-
H
12500
10000-
7500-' i 1 j
•i ' i
5000 -? CN 8 ! 0 ^ !
2500 J L ,1 ' "" °? i-
04
0 5 10
CN ]
jjjg^ ;
15 20 mm
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FID1 A,
Signal
8/3/98 11:04:16 AM
1.0000
1.0000
RetTime
[man]
1.467
5.409
7.390
9.176
9.338
9.474
10 .097
10.393
Type Area Amt/Area Amount Grp Name
counts*s [ug/kg]
_
-
-
-
-
_
-
-
-
-
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals :
0.00000
Results obtained with enhanced integrator!
2 Warnings or Errors :
Warning
Warning
Calibration warnings (see calibration table listing)
Calibrated compound(s) not found
Teller 8/4/98 7:56:35 AM bgp
205
Page 1 of 2
-------
>ata File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19B\030F3402.D
S-M18-R1 AbFH
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
8/3/98 11:42:35 AM
S-M18-R1 AbFH
bgp
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19A.S
E:\HPCHEM\TELLER\METHODS\0798-19A.M
7/31/98 6:22:19 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19.M
8/3/98 12:59:48 PM by bgp
34
30
2
FID1 A, (07
counts j §
17500-
T j
15000^ ;
1 2500 ~
10000-^
7500 -J
5000 -^ EN 8
•i ^- CN
i 2500 ^ ,H
98-19B\030F3402.D)
JE
r
T"
I
§00 S2
TT 00
T r co '
i
>
•
CO
jjjlk '
0^
0 5 10 15 20 mm
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FID1 A,
Signal
8/3/98 11:04:16 AM
1.0000
1.0000
Ret Time Type Ai
[min] count
1.467
5.409
7.390
9.176
9.338
9.474
10.097
10.393
re a Amt/Area Amount G
:s*s [ug/kg]
1 - -
.
.
.
-
rp Name
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals :
0.00000
Results obtained with enhanced integrator!
2 Warnings or Errors :
Warning : Calibration warnings (see calibration table listing)
Warning : Calibrated compound(s) not found
Slier 8/4/98 7:57:01 AM bgp
206
Page 1 of 2
-------
Data File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19C\049F360l.D' S-M18-R2 A VOJ
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
rx
8/5/98 10:12:14
S-M18-R2 A VOA
bgp
PM
F1D1 A, (0798-19C\049F360i.D)
Seq. Line
Vial
Inj
Inj Volume
E : \HPCHEM\TELLER\SEQUENCE\0798-19D.S
E:\HPCHEM\TELLER\METHODS\0 7 9 8 -19A.M
8/3/98 3:07:34 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19D.M
8/10/98 4:33:19 PM by bgp
r«VTT\l~T\\ " *^" —
36
49
1
counts
14000 -
12000 -
10000
8000 -
6000 -
4000 -
2000 -_
I
10
15
20
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FID1 A,
Signal
8/10/98 4:32:29 PM
1.0000
1.0000
RetTime Ty
[min]
1.447 BB
5.391
7.373
9.161
9.323
9.460
10.084
10.379
pe Area
count s*s
6.34282e4
-
-
-
-
-
-
-
Amt/Area
8.48458e-4
-
-
-
-
-
-
-
Amount G
[ug/kg]
53 .81621
-
-
-
-
-
-
-
rp Name
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals
53.81621
Results obtained with enhanced integrator!
2 Warnings or Errors :
Warning : Calibration warnings (see calibration table listing)
Warning : Calibrated compound(s) not found
907
o/in/OO Jl.cn. 1-3 DM Herri
Paqe 1 of 2
-------
Data File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19C\049F3602.D S-M18-R2 A VGA
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
FIDl A, (0798-19C\049F3602.Dy
8/5/98 10:42:10 PM
S-M18-R2 A VOA
bgp
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19D.S
E:\HPCHEM\TELLER\METHODS\0798-19A.M
8/3/98 3:07:34 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19D.M
8/10/98 4:33:19 PM by bgp
36
49
2
counts -
14000 -
12000 -
10000 -
8000 -
6000 -
4000 -
2000 _
10
15
20
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FIDl A,
Signal
8/10/98 4:32:29 PM
1.0000
1.0000
RetTime Type
[min]
1.447 BP
5.391
7.373
9.161
9.323
9.460
10.084
10.379
Area
counts*s
6.35279e4
-
-
-
-
Amt/Area
8 .48477e-4
-
-
-
-
Amount G
tug/kg]
53 .90196
-
-
-
-
rp Name
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals :
53.90196
Results obtained with enhanced integrator!
2 Warnings or Errors :
Warning : Calibration warnings (see calibration table listing)
Warning : Calibrated compound(s) not found
••filler 8/10/98 4:50r46 PM ban
208
Paae 1 of 2
-------
Data File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19C\031F1501.D S-M18-R2 Aa+AbFH
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
ig«
ra:
HDl A. (0798-19C\031F1501.D)
8/5/98 4:09:11 AM Seq. Line
S-M18-R2 Aa+AbFH Vial
bgp Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19D.S
E:\HPCHEM\TELLER\METHODS\0798-19A.M
8/3/98 3:07:34 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19D.M
8/10/98 4:33:19 PM by bgp
15
31
1
counts
50000 -
40000
30000 -
20000 -
10000 -
a
8 tt&»i3g i-
Ji s^ililrii/ii
mini
External Standard Report
Sorted By
Calib, Data Modified
Multiplier
Dilution
Signal 1: FID1 A,
Signal
8/10/98 4:32:29 PM
1.0000
1.0000
RetTime
[min]
1.464
5.442
7.367
9.057
9.322
9.480
9.994
10.386
Type
W
w
W
w
w
w
w
w
Area
counts*s
6. 27407e4
7.45377e4
2.42525e5
4 .28229e5
2.10223e5
1. 39680e5
2.95555e5
9.52145e4
Amt/Area
i
8.483306-4
7.574436-4
7.485336-4
7.424916-4
7.486606-4
7.447356-4
8.117186-4
7.188866-4
Amount G
[ug/kg]
53.22483
56.45810
181.53760
317.95643
157.38589
104.02433
239.90748
68.44837
rp Name
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals
1178.94302
Results obtained with enhanced integrator!
1 Warnings or Errors :
Warning : Calibration warjiings (see calibration table listing)
209
Parro 1 nf •)_
-------
ata File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19C\031F1502.D S-M18-R2 Aa+AbFH
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
rs:
8/5/98 4 :39 : 04 AM
S-M18-R2 Aa+AbFH
bgp
FUJI A, (U7yS-I9C\03IFI50Z.D)
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19D.S
E:\HPCHEM\TELLER\METHODS\0798-19A.M
8/3/98 3:07:34 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19D.M
8/10/98 4:33:19 PM by bgp
15
31
2
counts _
50000 -
40000 -
S
30000 - -s
i
20000 -
10000 -
J= •!
4ii
, i ££
£ r$£«
-fcilTliW-
,1 vr»
' ^
10
15
20
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FID1 A,
Signal
8/10/98 4:32:29 PM
1.0000
1.0000
RetTime
[min]
1.462
5.436
7.363
9.053
9.319
9.479
9.991
10.380
Type
W
W
W
W
W
W
W
W
Area
count s*s
6.2449264
7.48563e4
2.46545e5
4. 4793565
2.01966e5
1.4268165
2.95025e5
9. 9083964
Amt/Area
8.48275e-4
7.574756-4
7.48567e-4
7.425366-4
7.485706-4
7.448046-4
8.117156-4
7.190746-4
Amount Grj
[ug/kg]
52.97408
56.70179
184.55565
332.60783
151.18565
106.26962
239.47638
71.24863
3 Name
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals :
1195.01963
Results obtained with enhanced integrator!
1 Warnings or Errors :
Warning : Calibration warnings (see calibration table listing)
^
»1 1 or- R/in/qp d-4.1-4.1 PM hem
210
Paqe 1 of 2
-------
Data File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19B\032F3601.D S-M18-R2 AbBH
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
8/3/98 1:12:14 PM
S-M18-R2 AbBH
bgp
Seq
Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\079 8 -19A . S
E:\HPCHEM\TELLER\METHODS\0798-19A.M
8/3/98 1:05:33 PM by bgp
(modified after loading)
E:\HPCHEM\TELLER\METHODS\0798-19.M
8/3/98 12:59:48 PM by bgp
36
32
1
FID1 A, (0798-19BVD32F3601.D)
counts _
0-
a
1 7500 -
15000-
12500-
10000-
7500-
5000-
2500-
1
C
ra cr
•< x c
S*^
^ 1
So
S?
i
o>
• s 1
! H «t
It ' i o)
< co po q^_ o)
o O) NT Is-
to -^ -m oi
r- co <%) »-
i
i
1
i
i
[go
"f
1 t*JT
V|ft
10
1 5
20
mm
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FIDl A,
Signal
8/3/98 11:04:16 AM
1.0000
1.0000
RetTime
[min]
1.465
5.409
7.393
9.179
9.341
9.474
10.097
10.393
Type
PB
BP
BV
VB
Area
counts* s
i _
1
781.63977
-
1450.75732
1994.65137
874.27551
-
Amt/Area
_
9.19566e-4
-
8.308436-4
8.289516-4
8.363806-4
-
Amount G
[ug/kg]
7.187696-1
-
1.20535
1.65347
7.312266-1
-
rp Name
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals
4.30882
Results obtained with enhanced integrator!
2 Warnings or Errors :
Warning : Calibration warnings (see calibration table listing) 2t1
Teller 8/4/98 7:58:06 AM bgp Page 1 of 2
-------
ata File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19B\032F3602.D
S-M18-R2 AbBH
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
8/3/98 1:42:06
S-M18-R2 AbBH
bgp
PM
Seq.
Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19A.S
E:\HPCHEM\TELLER\METHODS\0798-19A.M
8/3/98 1:35:21 PM by bgp
(modified after loading)
E:\HPCHEM\TELLER\METHODS\0798-19.M
8/3/98 12:59:48 PM by bgp
36
32
2
FID1 A, (0798-1 9B\032F3602.D)
counts J S-ll j
Q^\ P
17500^
I
1 5000 ^
1 2500 -;
- '-I
o-i
0 5 10
I
Si
? !
i
1 5 20 min
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FID1 A,
Signal
8/3/98 11:04:16 AM
1.0000
1.0000
RetTime
[min]
1.466
5 .409
7.391
9.180
9.340
9.474
10.097
10.393
Type
BB
BP
PV
VB
Area
counts*s
729 .49854
-
1380.82410
2012 .73389
868.76587
-
Amt/Area
9.19566e-4
-
8.30843e-4
8.28951e-4
8.363806-4
-
Amount G
[ug/kg]
6 .70822e-l
-
1.14725
1.66846
7.26618e-l
-
rp Name
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals
4.21315
Results obtained with enhanced integrator!
2 Warnings or Errors :
Warning. : Calibration warnings (see calibration table listing) 212
WL
Her 8/4/98 7:58:27 AM bgp Page 1 of 2
-------
Data File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19C\051F3801.D
S-M18-R3 A VOP
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
FTOl A, (0798-19C\051F3801.D)
8/6/98 12:12:00 AM
S-M18-R3 A VGA
bgp
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19D.S
E:\HPCHEM\TELLER\METHODS\0798-19A.M
8/3/98 3:07:34 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19D.M
8/10/98 4:33:19 PM by bgp
38
51
1
counts -
14000 -
12000 -
10000 -
8000 -'
6000 -
4000 -
2000 -_
0
10
15
20
__mui
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal l: FID1 A,
Signal
8/10/98 4:32:29 PM
1.0000
1.0000
RetTime
[min]
1.445
5.391
7.424
9.076
9.284
9.460
9.994
10.379
Type
BP
PB
W
VP
VB
Area
counts*s
\
1
5.81485e4
-
717.28729
3637.93311
2533 .23242
6955.11768
-
Am t/ Are a
8.47395e-4
-
7.04194e-4
7.04047e-4
7.089336-4
7.653406-4
-
Amount
[ug/kg]
49.27469
-
5.05109e-l
2.56128
1.79589
5.32303
-
Grp Name
_ _ 1 _ _
__l __
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals
59.46000
Results obtained with enhanced integrator!
2 Warnings or Errors :
Warning : Calibration warnings (see calibration table listing)
Warning : Calibrated compound(s) not found
o/in/an
213
Paqe 1 of 2
-------
Data File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19C\051F3802.D S-M18-R3 A VO'A
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
rsr
8/6/98 12:41:52 AM
S-M18-R3 A VOA
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19D.S
E:\HPCHEM\TELLER\METHODS\0798-19A.M
8/3/98 3:07:34 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19D.M
8/10/98 4:33:19 PM by bgp
38
51
2
counts -
14000 -
12000 -
10000 -
8000 -
6000 -
4000 -
HDl A, (079S-19C\051F3802.D)
1 i
2000
ii 1
wt c
VO
-------
Data File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19C\033F1601.D S-M18-R3 Aa+AbFH
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
8/5/98 5:08:49 AM
S-M18-R3 Aa+AbFH
bgp
counts -
40000 -
30000 - 5a
20000 -
10000 -
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19D.S
E:\HPCHEM\TELLER\METHODS\0 7 9 8 -19A. M
8/3/98 3:07:34 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19D.M
8/10/98 4:33:19 PM by bgp
16
33
1
10
15
20
External Standard Reoort
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FID1 A,
Signal
8/10/98 4:32:29 PM
1.0000
1.0000
RetTime
[min]
1.460
5.412
7.382
9.048
9.321
9.475
9.988
10.389
Type
W
W
W
W
W
W
W
W
Area
count s*s
7.03650e4
1.02148e5
2 .50915e5
3.82630e5
1. 55327e5
1.3073565
2.36540e5
9.38973e4
Amt/Area
8.49613e-4
7.59476e-4
7.48603e-4
7.42371e-4
7.47886e-4
7.445086-4
8.113116-4
7.188186-4
Amount G
[ug/kg]
59.78302
77.57935
187.83555
284.05329
116.16679
97.33338
191.90747
67.49510
rp Name
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals
1082.15396
Results obtained with enhanced integrator!
1 Warnings or Errors :
Warning : Calibration warnings (see calibration table listing)
215
Pace 1 of 2
-------
Data File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19C\033F1602.D S-M18-R3 Aa+AbFH
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
8/5/98 5:38:54 AM
S-M18-R3 Aa+AbFH
bgp
F1D1A, (0798-19C\033F1602.D)
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19D.S
E:\HPCHEM\TELLER\METHODS\0798-19A.M
8/3/98 3:07:34 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19D.M
8/10/98 4:33:19 PM by bgp
16
33
2
counts -
40000
30000
20000 -
10000 -
10
15
_mini
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FID1 A,
Signal
8/10/98 4:32:29 PM
1.0000
1.0000
RetTime
[min]
1.460
5.415
7.383
9.181
9.324
9.475
9.990
10.389
Type
W
w
W
w
w
w
w
w
Area
counts*s
6.97956e4
1. 05456e5
2. 4988965
7.03364e4
1. 53911e5
1.3479865
2.3474365
9.5459264
Amt/Area
1
8.49527e-4
7.596496-4
7.48595e-4
7.373446-4
7.478586-4
7.446156-4
8.112956-4
7.188986-4
Amount G
[ug/kg]
59.29322
80.10916
187.06587
51.86212
115.10395
100.37223
190.44548
68.62545
rp Name
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals
852.87748
Results obtained with enhanced integrator!
1 Warnings or Errors :
Warning : Calibration warnings (see calibration table listing)
216
'eller 8/10/98 4:42:08 PM bcro
Paqe 1 of 2
-------
Data File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19B\034F3801.D
S-M18-R3 AbBH
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
8/3/98 3:13:40 PM Seq. Line
S-M18-R3 AbBH Vial
bgp Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19A.S
E:\HPCHEM\TELLER\METHODS\0798-19A.M
8/3/98 3:07:34 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19.M
8/3/98 12:59:48 PM by bgp
38
34
1
FID1 A, (0798-19B\034F3801.D)
: counts J IB f
- CM f
17500-
• i
15000-^ |
12500^
- 0)
10000-^ ' jjj
i H c 1
7500- § •£. j
- "o *= i
- te ni H HI
CO O) ' !
5000 " 8 J, '
*- • • \ to r^- ^
i CN i 03 CO Is-
tl • J_
0^
0 5 10
External Standard F
I
|
^Pf^~ •
_§>"
15 20 min
leport
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FID1 A,
Signal
8/3/98 11:04:16 AM
1.0000
1.0000
Ret Time Type
[min]
i
1.467
5.409
7.386 BP
9.174 PB
9.338
9.474
10.097
10.393
Area
counts*s
_
-
1504.16638
1809.70996
-
Amt/Area
_
-
8.30843e-4
8.28951e-4
-
Amount G
[ug/kg]
-
-
1.24973
1.50016
-
rp Name
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals :
2 .74989
Results obtained with enhanced integrator!
2 Warnings or Errors :
Warning
Warning
Calibration warnings (see calibration table listing)
Calibrated compound(s) not found
Teller 8/4/98 7:59:30 AM bgp
217
Page 1 of 2
-------
ata File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19B\034F3802.D
S-M18-R3 AbBH
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
8/3/98 3:43:29 PM
S-M18-R3 AbBH
bgp
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19A.S
E:\HPCKEM\TELLER\METHODS\0798-19A.M
8/3/98 3:07:34 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19.M
8/3/98 12:59:48 PM by bgp
38
34
2
FID1 A, (0798-1 9B\034F3802.D)
counts -i 55! £
Tj f
-1 CM (>
" ' 1 *
', 17500 -ij i
; i
15000^ '
12500-J !
D
10000^ i
'-, : , 0) §
7500- ! I i,
- ft d':. i2 2
5000- *" 5 : •
*~ ri t o 01 to
: i N i i & oo r*
2500- ] | ! 1 2 S 5
°T
0 5 10
External Standard F
!
II
1>
T
L__^25^
i
1 5 20 mm
Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FID1 A,
Signal
8/3/98 11:04:16 AM
1.0000
1.0000
RetTime Ty
[min]
1.467
5.409
7.390 BP
9.178 BV
9.338
9.474
10 .097
10.393
pe Area
counts*s
_
-
1504.11279
1920.49646
-
-
-
-
Amt/Area
1
-
8 .30843e-4
8.28951e-4
-
-
-
-
Amount
[ug/kg]
_
-
1.24968
1.59200
-
-
-
-
Grp Name
I
--{--
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals :
2.84168
Results obtained with enhanced integrator!
2 Warnings or Errors :
Warning
Warning
Calibration warnings (see calibration table listing)
Calibrated compound(s) not found
Her 8/4/98 7:59:51 AM bgp
218
Page 1 of 2
-------
Data File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19C\035F1701.D S-M18-FB Aa+AbFt
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
FAT
8/5/98 6:08:57 AM
S-M18-FB Aa+AbFH
bgp
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19D.S
E:\HPCHEM\TELLER\METHODS\0798-19A.M
8/3/98 3:07:34 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19D.M
8/10/98 4:33:19 PM by bgp
17
35
1
FIDl A, (0798-19C\035F 1 "OLD)
counts ;
45000 -_
40000 ^
35000 -
30000 -
oj
(N
25000 -]
20000 '-
15000 -
10000 -
5000 -
0-
0
a
X
u
«U-|
u
N
1 |1
S i $ -
r* ad ^b\ — ( ^__^ — '
5 10 15 20
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FIDl A,
Signal
8/10/98 4:32:29 PM
1.0000
1.0000
RetTime
[min]
1.465
5.391
7.388
9.176
9.338
9.474
10.102
10.379
Type
PB
BP
BV
W
VP
BP
Area
count s*s
1864.04346
-
4273 .76465
6714.62695
2168.54346
770.28723
598.98212
-
Amt/Area
7.81099e-4
-
7.04194e-4
7.04047e-4
7.08933e-4
7.059226-4
7.653406-4
-
Amount Grj
[ug/kg]
_ 1 __
1.45600
-
3.00956
4.72741
1.53735
5.437636-1
4.58425e-l
-
3 Name
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals
11.73251
Results obtained with enhanced integrator!
2 Warnings or Errors :
Warning
Warning
Calibration warnings (see calibration table listing)
Calibrated compound(s) not found
219
TelTe-r R/in/9fl 4-4?r21 PM bOD
Page 1 of 2
-------
Data File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19C\035F1702.D S-M18-FB Aa+AbFH
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
rx;
8/5/98 6:38:46 AM
S-M18-FB Aa+AbFH
bgp
Seq.
F1D1 A, (0798-19C\035F1702.D)
Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-I9D.S
E:\HPCHEM\TELLER\METHODS\0798-19A.M
8/3/98 3:07:34 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19D.M
8/10/98 4:33:19 PM by bgp
17
35
2
counts
45000 -
40000 -
35000
30000 -
25000 -
20000 -
15000
10000
5000
tj
-
r: - * 2
10
15
20
__min
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FID1 A,
Signal
8/10/98 4:32:29 PM
1.0000
1.0000
RetTime
[min]
1.465
5.391
7.387
9.175
9.337
9.475
10.101
10.379
Type
BB
BP
BV
W
VP
BP
Area
count s*s
1899.01147
-
4309.81299
6719.50342
2154.44360
725.68115
604.85809
-
Amt/Area
7.81099e-4
-
7.04194e-4
7.04047e-4
7.08933e-4
7.059226-4
7.65340e-4
-
Amount G
[ug/kg]
1.48332
-
3 .03494
4.73084
1.52736
5.122746-1
4.629226-1
-
rp Name
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals :
11.75166
Results obtained with enhanced integrator!
2 Warnings or Errors :
Warning
Warning
Calibration warnings (see calibration table listing)
Calibrated compound(s) not found
1 AT R/in/Qft 4.-49-T4 PM ban
220
Pacre 1 of 2
-------
Data File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19B\036F4001.D
S-M18-FB AbBH
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
8/3/98 5:13:02 PM
S-M18-FB AbBH
bgp
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19A.S
E:\HPCHEM\TELLER\METHODS\0798-19A.M
8/3/98 3:07:34 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19.M
8/3/98 12:59:48 PM by bgp
40
36
1
FID1 A, (0798-1 9B\036F4001.D)
counts _;
T
17500-;
15000^
12500^
10000-^
7500^
5000-
; CM
2500 - -
rti
8
5
h- CO
C%,
10
1 5
20
min
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FID1 A,
Signal
8/3/98 11:04:16 AM
1.0000
1.0000
RetTime
[min]
1.467
5 .409
7.393
9.179
9.342
9.474
10.097
10.393
Type
BB
PV
VB
Area
counts*s
i ._ __
1
-
1299.58960
1854.63794
632.35193
-
Amt/Area
-
8.30843e-4
8.289516-4
8.363806-4
-
Amount
[ug/kg]
_
-
1.07976
1.53740
5 .28886e-l
-
Grp Name
_ 1 __
1 - ~
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
tn-Xylene
Cumene
o-Xylene
Totals
3.14605
Results obtained with enhanced integrator!
2 Warnings or Errors :
Warning : Calibration warnings (see calibration table listing)
Warning : Calibrated compound(s) not found
Teller 8/4/98 8:00:53 AM bqp
221
Page 1 of 2
-------
)ata File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19B\036F4002.D
S-M18-FB AbBH
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
8/3/98 5:42:58 PM
S-M18-FB AbBH
bgp
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19A.S
E:\HPCHEM\TELLER\METHODS\0798-19A.M
8/3/98 3:07:34 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19.M
8/3/98 12:59:48 PM by bgp
40
36
2
FID1 A, (0798-19B\036F4002.D)
counts
17500-
CNI
1 5000 -] !
12500-^ . i
D
10000^ i §
7500 -_ § %
5000- i ! .
CN ; CN O> S>-
; c i o> oo i>) !
*~ i co T~ Trn i
2500- ••- r-' co <%, ^
I
!
i
15
20
min
External Standard Report
Sorted By :
Calib. Data Modified :
Multiplier :
Dilution :
Signal 1: FID1 A,
RetTime Type Area
[min] counts*s
Signal
8/3/98 11:04:16 AM
1.0000
1.0000
Amt/Area
Amount
[ug/kg]
Grp Name
1.467
5.409
7.392 BP
9.178 PV
9.337 VB
9.474
10.097
10.393
Totals :
1324.87170 8.30843e-4 1.10076
1875.25574 8.28951e-4 1.55449
658.98865 8.36380e-4 5.51165e-l
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
3.20642
Results obtained with enhanced integrator!
2 Warnings or Errors :
Warning : Calibration warnings (see calibration table listing)
Warning : Calibrated compound(s) not found
222
Slier 8/4/98 8:01:14 AM bgp
Page l of 2
-------
Data File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19C\045F5101.D
LCS #1
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
rsr
8/6/98 10:07:31 AM
LCS #1
bgp
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19D.S
E:\HPCHEM\TELLER\METHODS\0798-19A.M
8/3/98 3:07:34 PM by bgp
E:\HPCHEM\TELLER\METHODS\0 798-19D.M
8/10/98 4:33:19 PM by bgp
51
45
1
F1D1 .
(U798-19C\045F5101. D)
counts :
45000 -
40000 -
35000
30000 -
25000 -
20000 -
15000 -
10000 -
5000 -;
0
10
15
20
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FID1 A,
Signal
8/10/98 4:32
1.0000
1.0000
29 PM
RetTime
[min]
1.459
5.395
7.378
9.166
9.328
9.465
10.089
10.385
Type
BB
BB
BB
BV
W
VB
BV
VB
Area
counts*s
i
1
5. 4492264
5.99673e4
6.2226464
6.5595164
6.2959764
6.3440964
6.1557864
6.1235364
Amt/Area
1 - 1
1 |
8.46537e-4
7.55615e-4
7.424096-4
7.36899e-4
7.43535e-4
7.40761e-4
8.05506e-4
7.162126-4
Amount
[ug/kg]
46.12968
45.31221
46.19746
48.33695
46.81276
46.99461
49.58516
43.85743
Grp Name
_ i
__l
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals :
373.22626
Results obtained with enhanced integrator!
1 Warnings or Errors :
Warning : Calibration warnings (see calibration table listing)
223'
--- n /i n I on
c/r.CO DM K/-TT-,
Pacre 1 of 2
-------
Data File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19C\045F5102.D
LCS #1
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
FIDl A, (0798-19C\045F51027DT
8/6/98 10:37:15 AM
LCS #1
bgp
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19D.S
E : \HPCHEM\TELLER\METHODS\0798-19A.M
8/3/98 3:07:34 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19D.M
8/10/98^ 4 :33 :19 PM by bgp
51
45
2
counts :
45000 -
40000
35000 -
30000 -
25000
20000
15000 -
10000 -j
5000 -
a
I
-------
Data File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19C\048F3501.D S-M18-R1 B VOt
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
FA;
HDl A, (0798-19C\048F3501.D)
8/5/98 9:12:21 PM Seq. Line
S-M18-R1 B VOA Vial
bgp Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19D.S
E:\HPCHEM\TELLER\METHODS\0798-19A.M
8/3/98 3:07:34 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19D.M
8/10/98 4:33:19 PM by bgp
35
48
1
counts
5500 -
5000 -_
4500 -
4000 -
3500 -_
3000 -_
2500 -j
2000 -
0
10
15
20
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FID1 A,
Signal
8/10/98 4:32:29 PM
1.0000
1.0000
RetTime
[min]
1.463
5.391
7.279
8.999
9.323
9.551
10.084
10.670
Totals
Type
VB
PP
PB
PB
Area
count s*s
1
I
-
2959.74780
1229.61743
1782.05444
1847.85669
Amt/Area
-
7.04194e-4
7.04047e-4
7.05922e-4
6.828546-4
Amount
[ug/kg]
_
-
2.08424
8.657086-1
1.25799
1.26182
5.46975
Grp Name
i
1
Hexane
. Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Results obtained with enhanced integrator!
2 Warnings or Errors :
Warning
Warning
Calibration warnings (see calibration table listing)
Calibrated compound (s) not found
i-l T1»* \-.f
225
Paqe 1 of 2
-------
Data File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19C\048F3502.D S-M18-R1 B VGA
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
~~ F1D1 A, (0798-19C\048F3502.'DV
8/5/98 9:42:17 PM
S-M18-R1 B VOA
bgp
Seq. Line
Vial
Inj
Inj Volume
E : \HPCHEM\TELLER\SEQUENCE\0798-19D.S
E:\HPCHEM\TELLER\METHODS\0798-19A.M
8/3/98 3:07:34 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19D.M
8/10/98 4 :33 : 19 PM by bgp
35
48
2
2000
10
15
20
min
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FID1 A,
Signal
8/10/98 4:32:29 PM
1.0000
1.0000
RetTime
[min]
1.463
5.391
7.281
8.998
9.323
9.554
10.084
10.672
Totals
Type
BB
PP
BB
PB
Area
count s*s
-
2952.48633
1248.16382
1796.79407
1873.41663
Am t/ Are a
__ __
-
7.04194e-4
7.04047e-4
7.05922e-4
6.82854e-4
Amount
[ug/kg]
_
-
2.07912
8.78766e-l
1.26840
1.27927
5.50555
Grp Name
i
1
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Results obtained with enhanced integrator!
2 Warnings or Errors :
Warning : Calibration warnings (see calibration table listing)
Warning : Calibrated compound(s) not found
R/in/98 4:50:20 PM bat)
Paqe 1 of 2
-------
Data File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19C\037F1801.D S-M18-R1 Ba+BbFH
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
rx;
8/5/98 7:08:33 AM
S-M18-R1 Ba+BbFH
bgp
FIDl A, (0798-19C\037F1801.D)
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19D.S
E:\HPCHEM\TELLER\METHODS\0798-19A.M
8/3/98 3:07:34 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19D.M
8/10/98 4:33:19 PM by bgp
18
37
1
ir* \ »w \tfvr- "i —;o-jy«:;
rfeujHfitefe^i.flgTniv
nun
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FIDl A,
Signal
8/10/98 4:32:29 PM
1.0000
1.0000
RetTime
[min]
1.462
5.409
7.388
9.178
9.332
9.476
10.090
10.392
Type
W
W
W
W
W
W
W
W
Area
counts*s
2.04053e5
2.60243e5
3.5043565
7.0154365
2.91187e5
3 .3064165
2.7301065
3.17976e5
Amt/Area
I _ - -- |
8.56532e-4
7.628116-4
7.491836-4
7.42886e-4
7.492696-4
7.466446-4
8.115836-4
7.222626-4
Amount
[ug/kg]
174.77828
198.51585
262.54019
521.16618
218.17726
246.87097
221.57052
229.66208
Grp Name
1
1
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals
2073.28132
Results obtained with enhanced integrator!
1 Warnings or Errors :
Warning : Calibration warnings (see calibration table listing)
w
Teller 8/10/98 4:42:46 PM bgp
227
Page 1 of 2
-------
Data File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19C\037F1802.D S-M18-R1 Ba+BbFH
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
FIDl A, (0798-19C\037F1802.D)
8/5/98 7:38:26 AM
S-M18-R1 Ba+BbFH
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19D.S
E:\HPCHEM\TELLER\METHODS\0798-19A.M
8/3/98 3:07:34 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19D.M
8/10/98 4:33:19 PM by bgp
18
37
2
50000 -
40000 - ^T
ft
i"
30000 - H
20000
10000 -
0-
10
15
20
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FIDl A,
Signal
8/10/98
1.0000
1.0000
4:32:29 PM
RetTime
[min]
1.461
5.406
7.386
9.177
9.331
9.475
10.089
10.391
Type
W
W
-TV
W
W
W
W
W
Area
count s*s
2.04814e5
2.62453e5
3. 53094e5
7.04914e5
2. 92837e5
3.34004e5
2. 7257365
3.2006865
Amt/Area
8.565456-4
7.62829e-4
7.491946-4
7.42889e-4
7.49278e-4
7.46658e-4
8.11581e-4
7.222716-4
Amount
[ug/kg]
175.43229
200.20657
264.53637
523.67263
219.41663
249.38698
221.21463
231.17595
Grp Name
_|__ _
1
Hexane
Benzene
Toluene
Ethyl benzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals :
2085.04205
Results obtained with enhanced integrator!
1 Warnings or Errors :
Warning : Calibration warnings (see calibration table listing)
Teller 8/10/98 4:43:00 PM bgp
228
Page 1 of 2
-------
Data File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19B\038F420l.D
S-M18-R1 BbBH
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
8/3/98 7
S-M18-R1
bgp
:12:39
BbBH
PM
Seq.
Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19A.S
E:\HPCHEM\TELLER\METHODS\0798-19A.M
8/3/98 3:07:34 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19.M
8/3/98 12:59:48 PM by bgp
42
38
1
FID1 A, (0798-1 9B\038F4201.D)
counts _;
17500-
f
1
15000-J
12500^
10000-
7500 -^
to £
: o" c
5000 - ^ o
- T i
2500 - *
o^"
0
i j
i 03
OD
1
5 10
I
^
\ljff^ '
15 20 mm
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FID1 A,
Signal
8/3/98 11:04:16 AM
1.0000
1.0000
RetTime Type
[min] cc
_ i
1 _
1.467
5.409
7.390
9.176
9.338
9.474
10.097
10.393
Area Amt/Area Amount G
3unts*s [ug/kg]
I
1
_ _ _
_
- - -
_
- - -
-
_
rp Name
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals :
0.00000
Results obtained with enhanced integrator!
2 Warnings or Errors :
Warning
Warning
Calibration warnings (see calibration table listing)
Calibrated compound(s) not found
Teller 8/4/98 8:02:20 AM bgp
229
Page 1 of 2
-------
ata File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19B\038F4202.D
S-M18-R1 BbBH
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
8/3/98 7:42:33
S-M18-R1 BbBH
bgp
PM
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19A.S
E:\HPCHEM\TELLER\METHODS\0798-19A.M
8/3/98 3:07:34 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19.M
8/3/98 12:59:48 PM by bgp
42
38
2
2 l
FID1 A, (0798-1 9B\038F4202.D)
counts - 55J {;
~ *- r>
1 7500 - i
: i • ]
15000-^ ! i
12500^ ; ,
10000-
7500 -
- ,,3 0)
'• " i ' ™
2500- 1 ' co '
0 5 10
External Standard 5
i
ii
>
•
0*4
J_i^^"
1 5 20 mm
.eport
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FID1 A,
Signal
8/3/98 11:04:16 AM
1.0000
1.0000
RetTime Type A:
[min] coun
1.467
5.409
7.390
9.176
9.338
9.474
10.097
10.393
rea Amt/Area Amount
:s*s [ug/kg]
I
i
- - -
- - -
-
-
-
-
-
Grp Name
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals
0.00000
Results obtained with enhanced integrator!
2 Warnings or Errors .-
Warning •. Calibration warnings (see calibration table listing)
Warning : Calibrated compound(s) not found 230
Page 1 of 2
Her 8/4/98 8:02:47 AM bgp
-------
Data File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19C\050F370l.D S-M18-R2 B VOJ
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
counts
FID1A, (0798PT9C\050F3701.D)
I
i
8/5/98 11:12:05 PM Seq. Line
S-M18-R2 B VOA Vial
bgp Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19D.S
E:\HPCHEM\TELLER\METHODS\0798-19A.M
8/3/98 3:07:34 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19D.M
8/10/98 4:33:19 PM by bgp
14000 -
12000 -
10000 -
37
50
1
8000 -
6000 -
4000 -
2000 -_
0
-
-------
Data File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19C\050F3702.D S-M18-R2 B VOA
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
8/5/98 11:42:02 PM
S-M18-R2 B VOA
bgp
FID1A, (0798-r9C\050F3702TD7
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19D.S
E:\HPCHEM\TELLER\METHODS\0798-19A.M
8/3/98 3:07:34 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19D.M
8/10/98 4j33 ;19 PM by bgp
37
50
2
counts
16000 -
14000
12000 -
10000 -
8000 - i
I
6000 - ;
4000 -
. 8
2000 - IL
0
10
15
20
mini
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FID1 A,
Signal
8/10/98 4:32:29 PM
1.0000
1.0000
RetTime Type
[min]
1.446 BV
5.391
7.373
9.161
9.323
9.460
10.084
10.379
Area Amt/Area
counts*s
j
6.41331e4 8.48587e-4
-
-
-
-
Amount Grp Name
[ug/kg]
__ i i
54.42251 Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals
54.42251
Results obtained with enhanced integrator!
2 Warnings or Errors :
Warning : Calibration warnings (see calibration table listing)
Warning : Calibrated compound(s) not found
Teller 8/10/98 4:51:12 PM bqp
232
Page 1 of 2
-------
Data File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19C\039F4801.D S-M18-R2 Ba+BbFH
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
FTOl A. (0798-iyC\03yF480i.D)
8/6/98 7:09:13 AM
S-M18-R2 Ba+BbFH
bgp
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19D . S
E:\HPCHEM\TELLER\METHODS\0798-19A.M
8/3/98 3:07:34 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19D.M
8/10/98 4:33:19 PM by bgp
r?jani r\\ *"* —•— - -
48
39
1
counts
50000 -
40000
30000 -
20000 - 2
10000 -
0-
10
15
20
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FID1 A,
Signal
8/10/98 4:32:29 PM
1.0000
1.0000
RetTime
[min]
1
5
7
9
9
9
10
10
.457
.391
.365
.159
.317
.459
.079
.378
Type Area
count s*s
i
W
W
W
W
W
W
W
W
1
1
1
3
5
2
2
2
2
.33993e5
.6411665
.3624665
.5082865
.4322665
.2746765
.2584165
.3110865
Amt/Area
I - i
I
8
7
7
7
7
7
8
7
.546286-
.615496-
.491226-
.427176-
.489576-
.460116-
.112146-
.217196-
l
4
4
4
4
4
4
4
4
Amount Grp Name
[ug/kg]
i
114
124
251
409
182
169
183
166
.51425
.98208
.88944
.10888
.16593
.69302
.20543
.79535
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals :
1602.35437
Results obtained with enhanced integrator!
1 Warnings or Errors :
Warning : Calibration warnings (see calibration table listing)
233
rp/^i n <=v Q/in/QO
PM V-irrn
Paqe 1 of 2
-------
ata File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19C\039F4802.D S-M18-R2 Ba+BbFH
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
8/6/98 7:39:04 AM
S-M18-R2 Ba+BbFH
bgp
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19D.S
E:\HPCHEM\TELLER\METHODS\0798-19A.M
8/3/98 3:07:34 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19D.M
8/10/98 4:33:19 PM by bgp
48
39
2
2 fj.1
counts
50000
40000
30000
20000
10000
frlUl A, (0798-19C\039F4802.D)
u O*'1! c
C fls}*^^. V
*4j ortfri^ ^
PC m .J;L.ao _
r, JL SS 8 vp.,720
TT S 5s •»« — * i~q^
S IS g>> - ^ '. nfc
• ." ? ^ !aa.!li
• *J 1 § J 0 -1 W
•— • ' N ja ^f f** • 1 ri • ' ^^i— : oo^ ;?; fr\
: 2z s £ r ff 'fcsefc ' «5 ','j
1^ ffl S^ '• 1 . $ "= ' ' -
: - ,; -' B '^. ip'l^'i ':;( ! ',
* *8 * .S.iiS •!-^'> ' :
— W 1 — (MK^X !,,1 W .'I'!1.
Hj ' . TSTHs,io I' '"" LpV J l';; ' : L ' ;
-^Oi — i • — : ' , ,c\ ; , v i , ; i • . '
ffieii "i ". — • i 'i' 1
^
it
' " • ' 'i 't(«k.
' ' i'i'^2.
; '• 'i!^
i ' ^P\S
jii ,' | ,' ! i *\fc -^*?*2feagw
i !• ' '', : ! . ^n> °S^°^r^ ^ "^
1 ' i i . ' ' i \ i- m OQOwSrtv^ ^ ^
!•: : ,•• • • • -**w&%& d r;
l| -^u_^3^JN £j
o-
0
10
15
20
-jrun
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FIDl A,
Signal
8/10/98 4:32:29 PM
1.0000
1.0000
RetTime
[min]
1.458
5.393
7.370
9.164
9.322
9.464
10.080
10.382
Type
W
W
W
W
W
W
W
W
Area
counts*s
1.31846e5
1. 6324065
3.35324e5
5. 5319265
2.4460765
2.2873065
2.2521965
2.33362e5
Amt/Area
1
8.545386-4
7.615316-4
7.491186-4
7.427206-4
7.489686-4
7.460226-4
8.112086-4
7.217396-4
Amount G
[ug/kg]
112.66767
124.31253
251.19720
410.86671
183 .20304
170.63781
182.69960
168.42663
rp Name
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals
1604.01120
Results obtained with enhanced integrator!
1 Warnings or Errors :
Warning : Calibration warnings (see calibration table listing)
234
slier 8/10/98 4:55:53 PM bqp
Page 1 of 2
-------
Data File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19B\040F4601.D S-M18-R2 BbBH
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
8/3/98 10:20:01 PM
S-M18-R2 BbBH
bgp
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19A.S
E:\HPCHEM\TELLER\METHODS\0798-19A.M
8/3/98 3:07:34 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19.M
8/3/98 12:59:48 PM by bgp
46
40
1
I FID1 A, (0798-1 9B\040F4601.D) ]
i counts _; §| $ !
17500-
15000-
12500-
10000-
7500-
-5000 -
i
2500 -
0-
',
0)
ra ^
X {— i
^m g
2 o
; i
I
1 1 i
01 ' !
N ]
jj j^jfe^—J
z J i ^ » i ^l^^^ :
3 5 10 15 20 min
======
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FID1 A,
Signal
8/3/98 11:04:16 AM
1.0000
1.0000
RetTime
[min]
1.460
5.409
7.378
9.166
9.327
9.474
10.097
10.393
Type
BE
BB
BV
VB
Area
count s*s
964.68384
-
2242.50830
3906.80664
1152.00232
-
Amt/Area
9.19566e-4
-
8.30843e-4
8.289516-4
8.363806-4
-
Amount G
[ug/kg]
8.870906-1
-
1.86317
3.23855
9.635116-1
-
rp Name
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals
6.95233
Results obtained with enhanced integrator!
2 Warnings or Errors :
Warning
Warning
Calibration warnings (see calibration table listing)
Calibrated compound(s) not found
Teller 8/4/98 8:05:24 AM bgp
235
Page 1 of 2
-------
'ata File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19B\040F4602.D S-M18-R2 BbBH
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
8/3/98 10:49:45
S-M18-R2 BbBH
bgp
PM
Seq.
Line
Vial
inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19A.S
E:\HPCHEM\TELLER\METHODS\0798-19A.M
8/3/98 3:07:34 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19.M
8/3/98 12:59:48 PM by bgp
46
40
2
FID1
counts j
-
17500-J
15000-;
12500-
10000-;
7500 -^
5000 - I
1
2500 -
°~:
0
A, (0798-1 9B\040F4602.D)
3 S
CNl f
i
j , [
! i
I
D
N
C
o> i C .cc
c <5 "3K
™ M • 3 .£>.
-« 8 ! £ 3r
Si SS °° '*J
5 10
External Standard I
>
(N
to
15 20 min
leport
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FID1 A,
Signal
8/3/98 11:04:16 AM
1.0000
1.0000
RetTime
[min]
1.461
5.409
7.380
9.167
9.327
9 .474
10.097
10.393
Type
BB
BB
BV
VB
Area
counts*s
i
1
961.89789
-
2234.69775
3934.68726
1196.38647
-
Amt/Area
9.19566e-4
-
8.308436-4
8.289516-4
8.363806-4
-
Amount
[ug/kg]
8.845286-1
-
1.85668
3 .26166
1.00063
-
Grp Name
i
__ j _ _
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals
7.00351
Results obtained with enhanced integrator!
2 Warnings or Errors :
Warning : Calibration warnings (see calibration table listing)
Warning : Calibrated compound (s) not found . 236)
Page 1 of 2
iller 8/4/98 8:05:45 AM bgp
-------
Data File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19C\052F3901.D S-M18-R3 B VOi
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
8/6/98 1:11:44 AM
S-M18-R3 B VOA
bgp
counts
FIDl A, (0798-19C\052F3901.D)
S
ea
«
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19D.S
E:\HPCHEM\TELLER\METHODS\0798-19A.M
8/3/98 3:07:34 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19D.M
8/10/98 4:33:19 PM by bgp
12000 -
10000 -
8000 -
6000 -
4000 -
2000
39
52
1
10
15
20
mm1
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FIDl A,
Signal
8/10/98 4:32:29 PM
1.0000
1.0000
=letTime
[min]
1.443
5.391
7.385
9.070
9.280
9.460
9.991
10.379
Type
BP
PB
W
VP
VB
Area
counts*s
5.14604e4
-
559.48907
3223.32056
2390.66724
6316.97852
-
Amt/Area
8.45734e-4
-
7.04194e-4
7.04047e-4
7.08933e-4
7.65340e-4
-
Amount
[ug/kg]
43.52177
-
3.93989e-l
2.26937
1.69482
4.83464
-
Grp Name
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals
52.71458
Results obtained with enhanced integrator!
2 Warnings or Errors :
Warning : Calibration warnings (see calibration table listing)
Warning : Calibrated compound(s) not found •
Teller 8/10/98 4:51:52 PM bqp
237
Page 1 of 2
-------
Data File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19C\052F3902.D S-M18-R3 B VO/-
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
igj
rt:
8/6/98 1:41:30 AM
S-M18-R3 B VOA
bgp
F1D1 A, (0798-19C\052F39027DJ
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19D.S
E:\HPCHEM\TELLER\METHODS\0798-19A.M
8/3/98 3:07:34 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19D.M
8/10/98 4:33:19 PM by bgp
39
52
2
counts
12000 -
10000 -
8000 -
6000 -
4000 -
2000 -_
3
s$
10
15
20
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FID1 A,
Signal
8/10/98
1.0000
1.0000
4:32:29 PM
RetTime
[min]
1.443
5.391
7.392
9.070
9.278
9.460
9.989
10.379
Type
BP
PB
W
VB
VB
Area
count s*s
5.23668e4
-
762.66333
3324.22925
2424.00928
6414.71875
-
Amt/Area
8.459846-4
-
7.041946-4
7.04047e-4
7.08933e-4
7.65340e-4
-
Amount G
[ug/kg]
44.30143
-
5.370636-1
2.34041
1.71846
4.90944
-
rp Name
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals
53.80680
Results obtained with enhanced integrator!
2 Warnings or Errors :
Warning : Calibration warnings (see calibration table listing) 238
Warning : Calibrated compound(s) not found
Teller 8/10/98 4:52:06 PM bgp
Page 1 of 2
-------
Data File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19C\041F490l.D S-M18-R3 Ba+BbFH
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
r3t
8/6/98 8:08:45 AM Seq. Line
S-M18-R3 Ba+BbFH Vial
bgp Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19D.S
E:\HPCHEM\TELLER\METHODS\0798-19A.M
8/3/98 3:07:34 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19D.M
8/10/98 4:33:19 PM by bgp
49
41
1
FUJI A, (07V8-19C\041F4S01.D)
counts -
40000 -
30000 -
20000 -
10000 -
3
*c
£
U
a
5
0
T *ior>
' ^ ::
»n
•O •»
oo '• .,
£
O'T ^
.SS
— m
155
i?
>0
ids:
1 L; ^frooen_<^> i . ^ I
1 t ^l^SS •!|2- _.
"' "'•"!« l^n' S|o,W
•!^r^"^
cc I
" .51
r- •« -iji j-sga'Sp,: '«a.:h,y
"' ''~ r „ '.n1 ''
-,..!,, 'lf*!
if'1:1.; ,•• <•
P !
I f 'I
>qt-l IT-*
C^ > '
«sR ,
0 -
0
10
15
20
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FID1 A,
Signal
8/10/98 4:32:29 PM
1.0000
1.0000
RetTime Type
[min]
1 -
1.458 W
5.395 W
7.374 W
9.166 W
9.324 W
9.465 W
10.080 W
10.383 W
Area
count s*s
i _
1.23852e5
2.52715e5
3 .2446465
4.43642e5
1.9962465
1.9301065
1.5784165
1.7913365
Amt/Area
8.54174e-4
7.62747e-4
7.49066e-4
7.425276-4
7.48544e-4
7.45648e-4
8.10292e-4
7.211436-4
Amount G
[ug/kg]
105.79078
192.75763
243.04486
329.41613
149.42733
143.91771
127.89743
129.18056
rp Name
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals :
1421.43242
Results obtained with enhanced integrator!
1 Warnings or Errors :
Warning : Calibration warnings (see calibration table listing)
1
Teller 8/10/98 4:56:06 PM bgp
239
Page 1 of 2
-------
ica File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19C\041F4902.D S-M18-R3 Ba+BbFH
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
8/6/98 8:38:24 AM
S-M18-R3 Ba+BbFH
FID1 A, (0798-19CW1F4902.D)
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19D.S
E:\HPCHEM\TELLER\METHODS\0798-19A.M
8/3/98 3:07:34 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19D.M
8/10/98 4:33:19 PM by bgp
49
41
2
40000
30000 -
20000 -
10000 -
0-
10
15
20
jnm
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FID1 A,
Signal
8/10/98 4:32:29 PM
1.0000
1.0000
RetTime
[min]
1.458
5.395
7.373
9.165
9.323
9.464
9.986
10.383
Type
W
W
W
W
W
W
W
W
Area
counts*s
1. 22404e5
1. 8507865
3 .23061e5
4.41326e5
2.00091e5
1.91902e5
3 .41276e5
1.7819465
Amt/Area
I _ _ __
8.54103e-4
7.61936e-4
7.49059e-4
7.42521e-4
7.485496-4
7.45634e-4
8.11937e-4
7.211306-4
Amount Grj
[ug/kg]
_i _
104.54529
141.01749
241.99175
327.69432
149.77806
143.08881
277.09443
128.50119
3 Name
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals :
1513.71134
Results obtained with enhanced integrator!
1 Warnings or Errors :
Warning : Calibration warnings (see calibration table listing)
240
slier 8/10/98 4:56:20 PM bgp
Page 1 of 2
-------
Data File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19B\042F480l.D
S-M18-R3 BbBJ
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
8/4/98 12:18:48 AM
S-M18-R3 BbBH
bgp
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19A.S
E:\HPCHEM\TELLER\METHODS\0798-19A.M
8/3/98 3:07:34 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19.M
8/3/98 12:59:48 PM by bgp
48
42
1
FID1 A, (0798-1 9B\042F4801.D)
counts _i 3-
1 (Nl
17500^ . ' :
1 2500 ~ j ' !
10000-^
7500 ^
: 5000 -j TJ. ' :
: ° 3 ' '
2500- 7 «? J
0
f
1
1
1
-------
ata File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19B\042F4802.D
S-M18-R3 BbBH
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
8/4/98 12:48:31 AM
S-M18-R3 BbBH
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19A.S
E:\HPCHEM\TELLER\METHODS\0798-19A.M
8/3/98 3:07:34 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19 .M
8/3/98 12:59:48 PM by bgp
48
42
2
FID1 A, (0798-1 9B\042F4802.D)
: counts j ?| ; i 2 i
CNI P?
17500^
15000^
12500^ j , ,
10000-f
7500 -J i ! :
5000 -_ - M i
2500 - f ™ ' . :
i
i
•
* i '
c !
-------
Data File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19B\043F4901.D S-M18-FB Ba+BbFI
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
8/4/98 1:18:08 AM
S-M18-FB Ba+BbFH
bgp
Seq.
FID1 A, (0798-19B\043F4901 D)
Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19A.S
E:\HPCHEM\TELLER\METHODS\0798-19A.M
8/3/98 3:07:34 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19.M
8/3/98 12:59:48 PM by bgp
49
43
1
counts J
1 7500 -; !
:
1 5000 - u !
; c
I x !
12500 -H £ |
10000-] £
,_ I
7500 -t j
5000 - ! !
3 1: i
2500 - - : j
0>
1>
§C V
1
g e *$
CD LO1' Is* i
1 7' I?
« 1 1 j
1 i - 1
/ A ? Jill Jll
i
!
i
v -
10
15
20
mm
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FID1 A,
Signal
8/3/98 11:04:16 AM
1.0000
1.0000
RetTime
[min]
1.458
5.394
7.377
9.165
9.327
9.463
10.087
10.383
Type
BB
BP
BB
BV
W
VB
BV
VB
Area
count s*s
2 .7471364
2 .5012164
2. 6440664
2 .9314864
2 .4989964
2 .4954764
2.7281464
2.0960164
Amt/Area
I i
I 1
8 .983746-4
8.111646-4
7.960136-4
7.887986-4
7.997596-4
7.972176-4
8.596166-4
7.770876-4
Amount G
[ug/kg]
24.67946
20.28893
21.04710
23.12342
19.98587
19.89431
23.45154
16.28778
rp Name
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals :
168.75840
Results obtained with enhanced integrator!
1 Warnings or Errors :
Warning : Calibration warnings (see calibration table listing)
243
Teller 8/4/98 8:07:30 AM bgp
Page 1 of 2
-------
ata File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19B\043F4902.D S-M18-FB Ba+BbFH
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
8/4/98 1:47:47 AM
S-M18-FB Ba+BbFH
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19A.S
E:\HPCHEM\TELLER\METHODS\0798-19A.M
8/3/98 3:07:34 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19.M
8/3/98 12:59:48 PM by bgp
49
43
2
2 ,ul
F1D1 A, (0798-1 9B\043F4902.D) I
counts j cnl tt
1 f
1 7500 - j
-
-
15000-; a
: |
12500-: |
- r*-
1 0000 - "J
j Z
-
7500-
: ,:
- yj
•* o ;:
2500 - - ;
n> :
rr I
QJ
OJ
li "
C 0) -^^ 3^.
si | a| c^-
S H ,* .4
CD , tf)'' ft '
• f^ ^S^ o^
O5 , rtw ^— _
" ^ fn' 2
f
,l u> ! '
' t i
;; ; - ;!L
,
.
,
i
CD / " " —
y'
__ -^^^ '•
10
15
20
mm
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1-. FID1 A,
Signal
8/3/98 11: 04 :16 AM
1.0000
1.0000
RetTime
[min]
1.457
5.394
7.377
9.165
9.326
9.463
10.087
10.383
Type
BB
BB
BP
BV
W
VB
BV
VP
Area
counts*s
2
2
2
2
2
2
2
2
.7451964
.5191064
.6762864
.9657064
.5271664
.5281964
.7594064
.1213564
Amt/Area
8.98380e-4
8.110396-4
7.957846-4
7.885826-4
7.995166-4
7.969286-4
8.594376-4
7.767616-4
Amount
[ug/kg]
24.66226
20 .43087
21.29739
23 .38699
20 .20509
20.14783
23.71534
16.47778
Grp Name
i
_ 1 _ _
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals :
170.32356
Results obtained with enhanced integrator!
l Warnings or Errors :
Warning : Calibration warnings (see calibration table listing)
214
jller 8/4/98 8:07:49 AM bgp
Page 1 of 2
-------
Data File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19B\044F5001.D
S-M18-FB BbBH
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
8/4/98 2:17:22 AM
S-M18-FB BbBH
bgp
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19A.S
E:\HPCHEM\TELLER\METHODS\0798-19A.M
8/3/98 3:07:34 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19.M
8/3/98 12:59:48 PM by bgp
50
44
1
F1D1 A, (0798-19B\044F5001 D)
counts i
17500-
15000-
12500 -_
10000-
toi
tni
'8
n
7500-^
-i
2500-
°~
0
c • ' a ^"
1:: it
aim tr Is- 3N , .^^ .
!
5 10 15 20 mm
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FID1 A,
Signal
8/3/98 11:04:16 AM
1.0000
1.0000
RetTime
[min]
1.458
5.409
7.376
9.165
9.325
9.474
10.097
10.393
Type
PB
BP
PV
VB
Area
count s*s
838.18164
-
1931.41174
2568.42358
938.82379
-
Amt/Area
9.19566e-4
-
8.30843e-4
8.289516-4
8.36380e-4
-
Amount Grj
[ug/kg]
7.707636-1
-
1.60470
2.12910
7.852136-1
-
3 Name
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals :
5.28977
Results obtained with enhanced integrator!
2 Warnings or Errors :
Warning
Warning
Calibration warnings (see calibration table listing)
Calibrated compound(s) not found
Teller 8/4/98 8:08:10 AM bgp
245
Page 1 of 2
-------
ata File E:\HPCHEM\TELLER\DATA\1998\JUL98\0798-19B\044F5002.D
S-M18-FB BbBH
Injection Date
Sample Name
Acq. Operator
Sequence File
Acq. Method
Last changed
Analysis Method
Last changed
8/4/98 2:47:05 AM
S-M18-FB BbBH
Seq. Line
Vial
Inj
Inj Volume
E:\HPCHEM\TELLER\SEQUENCE\0798-19A.S
E:\HPCHEM\TELLER\METHODS\0798-19A.M
8/3/98 3:07:34 PM by bgp
E:\HPCHEM\TELLER\METHODS\0798-19.M
8/3/98 12:59:48 PM by bgp
50
44
2
i FID1 A, (0798-1 9B\044F5002.D)
; counts j §| £* I
I -, '
; C
17500-^
15000^
12500-J
10000-
!
r
0) '
c
0)
H I1M
? « * L
__^ :
°i
0 5 10 15 20 mm
External Standard Report
Sorted By
Calib. Data Modified
Multiplier
Dilution
Signal 1: FID1 A,
Signal
8/3/98 11:04:16 AM
1.0000
1.0000
RetTime
[min]
1.459
5.409
7 .375
9.163
9.325
9 .474
10.097
10 .393
Type
BB
BB
PV
VB
Area
counts* s
813.76160
-
1924.91589
2517.97632
909.71381
-
-
-
Amt/Area
9.19566e-4
-
8.30843e-4
8 .2895le-4
8.36380e-4
-
-
-
Amount G
[ug/kg]
7 .48307e-l
-
1.59930
2.08728
7.60866e-l
-
-
-
rp Name
Hexane
Benzene
Toluene
Ethylbenzene
p-Xylene
m-Xylene
Cumene
o-Xylene
Totals
5.19576
Results obtained with enhanced integrator!
2 Warnings or Errors :
Warning
Warning
Calibration warnings (see calibration table listing)
Calibrated compound(s) not found
slier 8/4/98 8:08:30 AM bgp
Page 1 of 2
-------
Sensidyne Flow Cell
Calibration Certificate
ENTHALPYanalytical
. inc.
-------
| SENSIDYNE, INC,
1 CALIBRATION CERTIFICATE
! CELL S/N: 16299-S DATE: C5 -
| This is to certify that
•* O A f*f* f
, d - i SSc
the above referenced Giiicrator Ficw Ceil
| was calibrated using film flowmeter MCS-102-A, which ha
» calibrated by instruments directiy traceable
J of Standards and Tech
I Results:
I REFERENCE
* \i(~* '^ * n"1 A
• n/lv_--o- : wii-.**.
: cc;min
i 2009
! 2012
I 2011
I 2011
| 2012
! 2015
| 2013
j 2009
I 2016
! 2019
| MAX
IMEAN 2012.7
! CALIBRATED BY 7)6
nolcgy. NIS i Report
S/N
1S399-S
cc/min
2011
2012
2013
2013
2013
2015
2016
2009
2017
2021
2014
/
to the National
536160^1.
RELATIVE
^ if-—
uirr.
cc/'min
2
0
2
j
1
0
3
0
1
s
3
<^.>.
S-; DATE:
s been
institute
FERCEM~
CIFF.
0.1
0.0
0.1
0.1
0.05
0.0
0.15
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0.05
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0.15
05-18-1S98
' / / /
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i CODE 300
M
IS1
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-------
TECHNICAL REPORT DATA
Please read instructions on the reverse before completing
1. REPORT NO.
EPA-454/R-00-025H
4. TITLE AND SUBTITLE
Final Report
Hot Mix Asphalt Plants,
Truck Loading and Silo Filling,
Manual Methods Testing,
Asphalt Plant C,
Los Angeles, California
Volume 8 of 8
2.
<
7. AUTHOR(S)
Frank J. Phoenix
9. PERFORMING ORGANIZATION NAME AND ADDRESS
Pacific Environmental Services, Inc.
Post Office Box 12077
Research Triangle Park, North Carolina 27709-2077
12. SPONSORING AGENCY NAME AND ADDRESS
U.S. Environmental Protection Agency
Office of Air Quality Planning and Standards
Emissions, Monitoring and Analysis Division
Research Triangle Park, North Carolina 2771 1
3. RECIPIENT'S ACCESSION NO.
5. REPORT DATE
May 2000
6. PERFORMING ORGANIZATION CODE
8. PERFORMING ORGANIZATION REPORT NO.
10. PROGRAM ELEMENT NO.
11. CONTRACT/GRANT NO.
68-D-98004
1 3 . TYPE OF REPORT AND PERIOD COVERED
Final
14. SPONSORING AGENCY CODE
EPA/200/04
15. SUPPLEMENTARY NOTES
16. ABSTRACT
The United States Environmental Protection Agency (EPA) Office of Air Quality Planning and Standards (OAQPS) is investigating hot mix
asphalt plants to identify and quantify paniculate matter ( >M), methylene chloride extractable matter (MCEM), and organic hazardous air pollutant
(HAP) emissions during asphalt concrete loading operations. In support of this investigation, the OAQPS issued Pacific Environmental Services, Inc.
(PES) a series of work assignments to conduct emissions testing at a hot mix asphalt plant during load-out operations.
The primary objective of the emissions testing was to characterize the uncontrolled emissions of PM, MCEM, polynuclear aromatic hydrocarbons
(PAHs), semi-volatile organic hazardous air pollutants (SVOHAPS), and volatile organic hazardous air pollutants (VOHAPS) from a hox mix
production plant during loading operations. An asphalt plant south of Los Angeles, California was selected by EPA as the host facility. Testing
was performed over five consecutive days beginning on July 24, 1998. Testing was performed under two conditions. Under normal operations, testing
was performed to characterize load-out emissions from the tunnel exhaust and load-in emissions from the asphalt concrete storage silo. Under
background conditions, testing was performed to characterize emissions from the combustion of diesel fuel in transport trucks.
The entire report consists of eight volumes totaling 4,234 pages, Vol. 1 (388 pages), Vol. 2 (308 pages), Vol. 3 (573 pages), Vol. 4 (694 pages),
Vol. 5 (606 pages), Vol. 6 (564 pages), Vol. 7 (570 pages), and Vol. 8 (531 pages).
17.
a. DESCRIPTIONS
Hazardous Air Pollutants
Methylene Chloride Extractable
Matter
Paniculate Matter
Polynuclear Aromatic Hydrocarbons
Semi-volatile Organic Hazardous Air
Pollutants
Volatile Organic Hazardous Air
Pollutants
18. DISTRIBUTION STATEMENT
Unlimited
KEY WORDS AND DOCUMENT ANALYSIS
b. IDENTIFIERS/OPEN ENDED TERMS
19. SECURITY CLASS (This Report)
Unclassified
20. SECURITY Ct ASS (This page)
Unclassified
c. COASTI Field/Group
21. NO. OF PAGES
Vol. 8-531
22. PRICE ,-',.
EPA Form 2220-1 (Rev. 4-77) PREVIOUS EDITION IS OBSOLETE
F:\U\FMeadows\TRD.Frm\WP 6.1
------- | |