United States Office or Air Quality EPA - 454/R-99-042b
Environmental Protection Planning and Standards August 1999
Aeency Research Triangle Park. NC 27711
Air
&EPA
Integrated Iron and Steel Industry Final Rep
Manual Testing
Volume II of
LTV Steel Company Indiana Harbor Works
East Chicago, Illinois
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Integrated Iron and Steel Industry
Final Report
Volume II of III
Appendices
Contract No. 68-D7-0068
Work Assignment 2-13
LTV Steel Company
Indiana Harbor Works
East Chicago, Illinois
Prepared for:
Michael K. Ciolek
Emission Measurement Center
Emission, Monitoring, and Analysis Division
Office of Air Quality Planning and Standards
U.S. Environmental Protection Agency
Research Triangle Park, North Carolina 27711
August 1999 y.s. Environmental Protection Agency
Region 5, Library (PL- 12J)
77 West Jackson Boulevard, 12th Floor
Chic**), II 60604-3590
EASTERN RESEARCH GROUP, I N-C
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Table of Contents
Appendix A Method 23, Analysis Data for Dioxins/Furans
Appendix B Method 23 Analytical Data for PAHs
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Appendix A
Method 23
Analysis Data for Dioxins/Furans
cah/K \7997\03\07-RPT\APX-CVR WP6
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CASE NARRATIVE
Analysis of Samples for the Presence of
Polychlorinated Dibenzo-p-Dioxins and Dibenzofurans by
High-Resolution Chromatography / High-Resolution Mass Spectrometry
Method 23 (6/93)
Date:
Client ID:
P.O. Number:
TLI Project Number:
July 24, 1997
Eastern Research Group
42299A
This report should only be reproduced in full. Any partial reproduction of this report requires permission from
Triangle Laboratories, Inc.
Rev. 05/08/97
Triangle Laboratories, Inc.
801 Capitola Drive P.O. Box 13485
Durham, NC 27713-4411 Research Triangle Park, NC 27709-3485
919-544-5729 Fax #919-544-5491
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Triangle Laboratories. Inc. July 24, 1997
Case Narrative 42299A
Overview
Five M23 samples were received from Eastern Research Group at 4 °C in good condition
on July 01,1997 and were stored in a refrigerator at 4°C. The samples and any associated
QC samples were extracted and analyzed according to procedures described in the
Triangle Laboratories' Data User's Manual (Rev. 12/92-HK-2-AH-2/93). Any particular
difficulties encountered during the sample handling by Triangle Laboratories will be
discussed in the QC Remarks section below. Results reported relate only to the items
tested.
Quality Control Samples
A laboratory method blank, identified as the TLJ Blank, was prepared along with the
samples.
Quality Control Remarks
This release of this particular set of Eastern Research Group analytical data by Triangle
Laboratories was authorized by the Quality Control Chemist who has reviewed each
sample data package individually following a series of inspections/reviews. When
applicable, general deviations from acceptable QC requirements are identified below and
comments are made on the effect of these deviations upon the validity and reliability of the
results. Please consult Triangle Laboratories' Data User's Manual for further details.
Specific QC issues associated with this particular project are:
Sample Preparation Laboratory: Only four M23 samples were extracted and analyzed
under this project.
Mass Spectrometry: None
Data Review: None
Other Comments: Any analytes found in the TLJ Blank are detected at a level equal to or
less than the Target Detection Limit This level of contamination is acceptable as per TLJ
guidelines.
Sample Calculations:
Analvte Concentration
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Triangle Laboratories, Inc. July 24, 1997
Case Narrative 42299A
The amount of any analyte is calculated using the following expression.
A«*Qp
A mt , — __ _
f\mi (o) —
Ap*RRF(0) *W
Where:
Amt (a) is the amount of a given analyte,
A<, is the integrated current for the characteristic ions of the analyte,
Ap is the integrated current of the characteristic ions of the corresponding internal
standard,
Qp represents the amount of internal standard added to the sample before extraction,
RRF(a) is the mean analyte relative response factor from the initial calibration (ICal) and,
W is the sample weight or volume (W = 1 for M23)
The amount is expressed in nanograms (ng) or picograms (pg).
Detection Limits
The detection limit reported for a target analyte that is not detected or presents an analyte
response that is less than 2.5 times the background level is calculated by using the -
following expression. The area of the analyte is replaced by the noise level measured hi a
region of the chromatogram clear of genuine GC signals multiplied by an empirically
determined factor. The detection limits represent the maximum possible concentration of
a target analyte that could be present without being detected.
2 * 2.5 * (F * H) * Qp
DL<0) =
Ap*RRF(0) *W
Where:
DL«j) is the estimated detection limit for a target analyte,
2.5 is the minimum response required for a GC signal,
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Triangle Laboratories, Inc. July 24, 1997
Case Narrative 42299A
F is an empirical number that approximates the area to height ratio for a GC signal. This
number is 3.7 for both the DB-5 GC column and the DB-225 GC column,
H is the height of the noise
Ap is the integrated current of the characteristic ions of the corresponding internal
standard,
Qp represents the amount of internal standard added to the sample before extraction,
RRF(0) is the mean analyte relative response factor from the initial calibration (ICal) and,
W is the sample weight or volume
The detection limit is expressed in nanograms (ng) or picograms (pg).
Other sample calculations may be found in the Triangle Laboratories Data User's Manual.
Data Flags
In order to assist with data interpretation, data qualifier flags are used on the final reports,
as discussed in Triangle Laboratories' Method 23 Data User's Manual. Please note that all
data qualifier flags are subjective and are applied as consistently as possible. Each flag has
been reviewed by two independent Chemists and the impact of the data qualifier flag on
the quality of the data discussed above. The most commonly used flags are:
A 'B' flag is used to indicate that an analyte has been detected in the laboratory method
blank as well as in an associated field sample. The 'B' flag will be used only when the
concentration of analyte found in the sample is less than 20 times that found in the
associated blank. This flag denotes possible contribution of background laboratory
contamination to the concentration or amount of that analyte detected in the field sample.
Under Triangle Laboratories guidelines, a laboratory blank is acceptable if the tetra-
through hepta-CDD/CDF levels are all below the target detection limits (TDLS) or if the
contamination levels are less than 5% of the levels detected in the associated field samples.
If these conditions are satisfied or if the blank is unable to be reextracted, the
interpretation of the contamination levels relative to the samples should be as follows: 1)
analyte quantitations should be considered valid if the level of blank contamination is less
than five percent of the level detected in the field sample, 2) analyte quantitations should
be considered estimated if the analyte level in the sample is five to twenty times the level
of the analyte hi the blank, or 3) analytes whose level in a sample is the same as or less
than five times the level detected in the associated blank should be considered present
likely due to laboratory contamination and not native to the sample.
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Triangle Laboratories, Inc. July 24, 1997
Case Narrative 42299A
An '£' flag is used to indicate that an PCDF peak has eluted at the same time as the
associated diphenyl ether (DPE) and that the DPE peak intensity is ten percent or more of
the PCDF peak intensity. Total PCDF values are flagged 'E' if the total DPE contribution
to the total PCDF value is greater than ten percent. All PCDF peaks that are significantly
influenced by the presence of DPE peaks are quantitated with EMPC values, regardless of
the isotopic abundance ratio. These EMPC values are most likely overestimated due to
the DPE contribution to the peak area.
An T flag is used to indicate labeled standards have been interfered with on the GC
column by coeluting, interferent peaks. The interference may have caused the standard's
area to be overestimated. All quantitations relative to this standard, therefore, may be
underestimated.
A 'PR' flag is used to indicate that a GC peak is poorly resolved. This resolution problem
may be seen as two closely eluting peaks without a reasonable valley between the peak
tops, overly broad peaks, or peaks whose shapes vary greatly from a normal distribution.
The concentrations or amounts reported for such peaks are most likely overestimated.
A 'Q' flag is used to indicate the presence of QC ion instabilities caused by quantitative
interferences. Affected analytes may be overestimated or underestimated as a result of this
interference. A peak is flagged 'Q' only if it is affected by a QC ion deviation greater than
20% full scale as determined relative to the labeled standard against which it is
quantitated. Total PCDF/PCDF quantitations will be flagged 'Q' if the interferences affect
ten percent or more of the total PCDD/PCDF peak areas.
An 'RO' flag is used to indicate that a labeled standard has an ion abundance ratio that is
outside of the acceptable QC limits, most likely due to a coeluting interference. This may
have caused the percent recovery of the standard to be overestimated. All quantitations
versus this standard, therefore, may be underestimated.
A 'U' flag is used to indicate that a specific (2,3,7,8-substituted) isomer cannot be
resolved from a large, coeluting interferent GC peak. The specific isomer is reported as
not detected as a valid concentration/amount cannot be determined. The calculated
detection limit, therefore, should be considered an underestimated value.
A 'V flag is used to indicate that, although the percent recovery of a labeled standard may
be below a specific QC limit, the signal-to-noise ratio of the peak is greater than ten-to-
one. The standard is considered reliably quantifiable. All quantitations derived from the
standard are considered valid as well.
-------
Triangle Laboratories, Inc. July 24, 1997
Case Narrative 42299A
By our interpretation, the analytical data in this project are valid based on the guidelines
of EPA Method 23 (6/93) and Triangle Laboratories' Method 23 Data User's Manual.
Any specific QC concerns or problems have been discussed in the QC Remarks section of
this case narrative with emphasis on their effect on the data. Should Eastern Research
Group have any questions or comments regarding this data package, please feel free to
contact our Project Scientist, Amy Boehm, at 919/544-5729 ext. 268.
For Triangle Laboratories, Inc.,
Report Preparation Quality Control
VIJAYS.CHHABRA
Report Preparation Chemist Report Preparation Chemist
The total number of pages in the data package is :
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7 y r-/7J? \
TRIANGLE LABORATORIES, INC.
UST OF CSHTIRCATICNS AND ACCREDITATIONS
PNVmCNMENTAL
American Association for Laboratory Accreditation. Expires July 31, 1997. Certificate
Number 0226-01. Accmiitaticn for technical competence in Environmental TestingXIndudlng
Waste Water. Sol/Haz Waste. Pulp/Paper, and Air Matrices) Parameters are AGX/TQX
Vdatfles. Pesticides. PCS's. BNA's, and DioxtrvFuian. Method 1613 tor Drinking Water.
State of Alabama, Department of Environmental Management. Expires December 31,
1997. Laboratory I.D. * 40S50. Oloxin in drinking water.
State of Alaska, Department of Environmental Conservation. Expires December 21, 1997.
Certificate number OS-Q0397. Diox'n in drinking water.
State of Arizona, Department of Health Services. Expires May 26. 1997. Certificate
#AZD423. Drinking Water far Qicxin, Dfoxin in WW and SH Waste.
State of Arkansas, Department of Pollution Control and Ecology. Expires February 18,
1998. Pulp/paper, soil, water, and Hazardous Waste for Qfaxin/Ftaran; AOX/TOX.
Stats of California, Department of Health Services. Expires August 31. 1997. Certificate
#1922. Selected Metals in Waste Water; Vdatfles, Serra-vdaffles, and Otoxmmjian in WW and
Sci/Haz Waste. Dicxin in drinking water. -
State of Connecticut, Department of Health Services. Expires September 30, 1997.
Registration #PH-Q117. Oloxin in drinking water.
Delaware Health and Social Services. Expires December 31, 1997. Certificate *NC 14Q.
Dioxin in drinking water.
Rorida Department of Health and Rehacflhative Services. Expires June 30.1997.0taan in
DW. Drinking Water ID HRS» 37424. Metals. Fatraclabte Orgarbcs (GOMS), Pesflcaea/PCgs
(GC) and Vdatiles (GC'MS) in Environmentai Samples. Environmental water ID HHS*
Diatom, X 277734477 ItmwmJi THangb Pwrk, HC 277084485
-------
Hawaii Department of Hearth. Expires Marcn 1, 1398. Ofaxn in drinking water. 'Accepted"
for regulatory purposes.
Idaho Department of Heatt and Werfare. Expires November 30, 1997. Otadn in drinking
water.
State of Kansas, Decaneeat of Health and Environment. Expires January 31, 1998.
Environmental AnaiysesfNon potable Water and Sciid and Hazardous Waste. Method 1613
for drinking water. ID ¥s- Banking water and/or poflutton ccmrd - E-215. Sciki or Hazardous
Waste -E-t 209.
Conwncnweaitn of Ktettcky, Department for Environmentai Protection. EUpiioa
December 31 , 1997. 104900BL Qfaxtn in Oruikuiij water.
Maryland Department of Hsatih and Mental Hygiene. Expires September 30. 1997.
Cartficalicn #Z3S. Onrtdng voter by Metncd 1 613A.
State of Michigan, Devmaiiem of Puisiic Heattn. Expires March 31,1997. Qnnking water by
Metnod 1613.
Mississippi State CJepartaeat of Heattn. No expiration ctate.. Oioxin in drinking 'water.
Montana Department of Heafth and Environmentai Services. Expires Oecsmber 31,1997.
Oioxin in drinking water:
State of New Jersey, Dquiuiaii of Environraentai Protection and Energy. Extended by
state. Temporary uaiiliuBi oofl June 30, 1997 or sooner. ID #67351. BNAs and Voiatfies.
Oioxin in drinking water.
State of New Mexico, Dafcuument Department Expires July 31, 1997. OTcxin in drinking
water.
New York State Dey*i«tni of Heattn. Expires June 30, 1997. 10 H1Q2S. Environmentai
Analyses of non-pdabie Water; Sofid and Hazardous Waste. Method 1613 in OW.
State of North CarofinB» Department of Eiwuonment IiewUi and Naturai nesoivces
Expires December 31,1997. Canficate f 37751. Oioxin In diiiikiiig
State of North CJIUUBB* Okperttmnt of Eiiworuneiity ilejiiUi^ and Natural
Division of SnvironoeBal lengement. Expires Oecember 31,1997. Cartificate * 485.
Metais, pesticides & PGa^sni-woiaJBes and vdatfles; TCIP.
North Dakota Stato DBpameui of Health and Consolidated Lab
December 31,1997. Caelotef R-Q76. Elfedfve October 4,1993. Ofaan in drinking water.
8
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Oklahoma Department at £a»iiunjiieiiui Quality. Etpires Goober 31, 1997. Laboratory
#9612. Dioxin by 1613A, 82SO and 8280.
State of South Carolina, Department of Health and Environmental Control. Expires April
1, 1997. Carnficate number 399040001 (drinking water). Expires August 31, 1297. Certificate
number *99C4COQ2 (other paianeters). Oioxin/Furans, SNA, Vdatfes, and PCSs/pestiddes
under Cean Water Act 2.3.7,3-TCCC for Drinking Water, and Organic ex&aoables for Solid
and Hazardous Waste.
Stats of Tennessee. DeujiBaeut of Environment and Conservation. Expires February 5,
1 999. ID 402B32. Method 1 613 Drinking water only.
Department of Agriculture Soil Permit Expires September 30, 2002. Permit No. S-
4953. Under the authority of ffle Federal Plant Pest Act permission is granted to receive
foreign soil sampies for use in laboratory analysis.
U.S. Army Corps of Djqimeia. Expires November 30, 1997. Validated to perform methods
3280 & 3290 for Lackbcume LanQSl Ste Investigation, Defense Distribution Depot Projecs,
and assarted .orojecs far the USACc iHorth Pacific Division Laboratory.
U.S. SPA Region V. Expires Movember U, 1999. Dicotin in drinking water.
Region VB, for tte State of Wyoming. Expires Movember 13, 1997. Dioxin a
drinking water.
State of Utah, Derailment of Health. Expires December 31, 1997. Certificate Number E-
166. Camficanon for Hie fbtowig parameters: Semi-Vciatfes and Volafles under HCRA;
Votanies under dean Water Acs Dkam/furans by Method 3280; Drinking water tor Ofccon by
Method 161 3; Metals indudhg Mercury and VBcrowave Digestkax
Commonwealth of Virginia, DepdiUueut of General Services, Division of Consolidated
Laboratory Services. Expires June 30, 1997. ID * 00341. Dkadn in drinking water.
State of Washington, DqMiUiieiit of Ecology. Expires September 11, 1997. Lao
Accrwtftatian Number COST. Scope of Acueumiun apples to water anaryses far
Porychiorinated DtoenzD-^Hfioans and Poiycrdorinated Dibenzorurans, SNA Extr (Sernrvciaffle)
Organics and Purgeabte (Vdafc) Organics.
State of Washington, Di,u«emiit of Health. Expires April 30, 1998. Dkcdn in Uiinking water.
Lab I.0. 129
Stats of West Virginia, Oeuauueu of Hearth. Expires December 31, 1997. Cardficate No.
9923(0). Dioxin in drinking '
-------
State of Wisconsin, Oev+uucuL at Natural Resources. Expires June 30. 1997. Laboratory
10 Num&er 99983530. £*»*!** for me fcilcwmg categories of Orgarrics: PurgeaOe,
Base/Neutral. Add. PCSs, and Otaon. Expires November 14, 1999. Laboratory IO
999869530. Ctaon in
Drug enforcsma* Agency (DEAV Expires November 30, 1997. Registration number
RT01195835. Connoted stance registration for schedules 1 ,Z3,2N,4,5.
Oepiu uiieiit of HUBBB Atsources. Expires October 31, 1997. Registration number
NC-PT 0000 0031. No^CaB^teccpBctedsuiaiaiices ieyi&a^liuiL Appfication suomiited for
renewal.
Food & Drug AdminiatraBQB (FDA) Registration. Expires Juiy 1997. IO ^s 001500 1053481.
Annual retjiatration erf drug astafabtoaiL Annual registrancn of drug establisrtment
OTtiEH
Cinical Laboratory liapi-memeiit Amendments (CUA) Registtation. Expires May 30,1999.
ID # 3400705121 Departcnent of Health & Human Services, Hearth Care Financing
Administration.
OS. EPA Large QOEH% ftganftun Waste Generator. No expiration date. EPA ID
#NCC982156879. Pant'ofcaies ibattne laboratory ts a large generator of hazardous waste.
North Carolina BjJfaauhe Iterate License, Expires Apni 30 1998. License Na 032-
0954-1. License autfianzeste fcgnsge to receive, acquire, own, piygjfta, transrer, nrnpott and
sucn ituJiuat^n
North Carolina General 1 li i»11 far Radiation protection. No. expiration date. License No.
Q32-875-OG. The gencat fcanse apples arty to radioactive material contained in devices
which have been manufadBed and labeled in accordance witt specific requirements.
"IIF
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DOCUMENT
CONTROL
Triangle Laboratories, Inc.
801 Cap/to/a Drive P.O. Box 13485
Durham, NC 27713-4411 Research Triangle Park, NC 27709-3485
919-544-5729 Fax * 919-544-5491
11
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LTV STEEL COMPANY
CHAIN OF CUSTODY
RELINQUISHED BY « <^| <-Ji^ L ~ 6 <^J^
RELINQUISHED BY -
DATE- C?«^&-i / / \<\«n
DATE " ' 0
RECEIVE!
t—
HI
>BY: nliwTsST DATE: /(^£/
RECEIVE6 BY: ^ ' U U DATE:
SAMPLE ID
LTV-98
LTV-ea^
LTV-68-,
LTV-73<
LTV-78 -
LTV-83
LTV-64 "
LTV-69 ^
LTV-74
LTV-79
LTV-84
LTV-66 '
LTV-71 S
LTV-76 X
LTV-81 /
LTV-86
LTV-65 •'
LTV-70 -
LTV-75 ''
LTV-Brj"-
LTV-85
LTV-67 -
LTV-72 x
LTV-77 •'
LTV-BZ^'
LTV-87
FIELD ID
LTV- 062597- M23- OUTLET- MeCI2- PB
LTV- 062497- M23- OUTLET- PR- 1
LTV- 062697- M23- OUTLET- PR- 2
LTV- 062797- M23- OUTLET- PR- 3
LTV- 062697- M23- OUTLET- PR- FB1
LTV- 062497- M23- OUTLET- PR- RB1
LTV- 062497- M23- OUTLET- PRT/CRT- 1
LTV- 062697- M23- OUTLET- PRT/CRT- 2
LTV- 062797- M23- OUTLET- PRT/CRT- 3
LTV- 062697- M23- OUTLET- PRT/CRT- FBI
LTV- 062497- M23- OUTLET- PRT/CRT- RB1
LTV- 062497- M23- OUTLET- XAO- 1
LTV- 062697- M23- OUTLET- XAD- 2
LTV- 062797- M23- OUTLET- XAO- 3
LTV- 062697- M23- OUTLET- XAD- FB1
LTV- 062497- M23- OUTLET- XAD- RBI
LTV- 062497- M23- OUTLET- F- 1
LTV- 062697- M23- OUTLET- F- 2
LTV- 062797- M23- OUTLET- F- 3
LTV- 062697- M23- OUTLET- F- FB1
LTV- 062497- M23- OUTLET- F- RBI
LTV- 062497- M23- OUTLET- IMP- 1
LTV- 062697- M23- OUTLET- IMP- 2
LTV- 062797- M23- OUTLET- IMP- 3
LTV- 062697- M23- OUTLET- IMP- FB1
LTV- 062497- M23- OUTLET- IMP- RB1
SAMPLE TYPE
METHOD 23, INLET, PROOF BLANK
METHOD 23, OUTLET, RUN 1
METHOD 23, OUTLET, RUN 2
METHOD 23. OUTLET, RUN 3
METHOD 23, OUTLET, FB 1
METHOD 23, OUTLET, RB 1
METHOD 23, OUTLET, RUN 1
METHOD 23, OUTLET, RUN 2
METHOD 23, OUTLET. RUN 3
METHOD 23, OUTLET, FB 1
METHOD 23, OUTLET, RB 1
METHOD 23, OUTLET, RUN 1
METHOD 23, OUTLET, RUN 2
METHOD 23, OUTLET. RUN 3
METHOD 23, OUTLET, FB 1
METHOD 23, OUTLET, RB 1
METHOD 23. OUTLET. RUN 1
METHOD 23, OUTLET, RUN 2
METHOD 23, OUTLET. RUN 3
METHOD 23. OUTLET, FB 1
METHOD 23, OUTLET, RB 1
METHOD 23, OUTLET, RUN 1
METHOD 23, OUTLET, RUN 2
METHOD 23. OUTLET, RUN 3
METHOD 23, OUTLET, FB 1
METHOD 23, OUTLET, RB 1
j PRESERVATIVE
MeCI2 Rinse
MeCI2/Acetone Probe Rinse
MeCI2/Acetone Probe Rinse
MeCI2/Acetone Probe Rinse
MeCI2/Acetone Probe Rinse
MeCI2/Acetone Probe Rinse
, Toluene Probe Rinse
Toluene Probe Rinse
1 Toluene Probe Rinse
Toluene Probe Rinse
Toluene Probe Rinse
XAO Trap
XAD Trap
XAD TrarJ
XAD Trap
XAD Trap
Filter
Filter
Filter
Filter
Filter
Implngers and Rinses
Implngers and Rinses
Implngers and Rinses
Implngers and Rinses
Implngers and Rinses
COMMENTS
Vtott
ANALYSIS
«*iYtnert»AH
DIoxIns/PAH
Dioxins/PAH
Dioxins/PAH
DIoxIns/PAH
Dioxins/PAH
Dioxins/PAH
Dioxins/PAH
DIoxIns/PAH
Dioxins/PAH
Dioxins/PAH
Dtoxins/PAH
Dioxins/PAH
Dioxins/PAH
Dioxins/PAH
DIoxIns/PAH
Dloxln«/PAH
DIoxIns/PAH
DIoxIns/PAH
DioxInt/PAH
Dioxins/PAH
Dioxins/PAH
Dioxins/PAH
Dioxins/PAH
Dioxins/PAH
DIoxIns/PAH
Page 8
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Table 5-11
alytical Detection Limits For Dioxras/Furans
I
Analyte
Tetra TCDDs
Penta TCDDs
Hexa TCDDs
Hepta TCDDs
beta TCDDs
Tetra TCDFs
Penta TCDFs
Hexa TCDFs
Hepta TCDFs
Octa TCDFs
Total Detectable Amount, ng
5
25
25
25
50
5
25
25
25
50
NOTE: D/F analysis by High Resolution Mass Spectrometry assumes a 2 fjL injection of a
200 }j,L sample extract
5-44
13
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=TRIANGLE LABORATORIES. INC. -- LOG IN RECORD/CHAIN OF CUSTODY*
| Custody Seal : Absent Sample Seals: Absent
K Chain of Custody t Present Container. . . : Intact
H Sample Tags : Absent
|| Sample Tag Numbers: Not Listed on Chain of Custody
fl SMO Forms : N/A
TLI Pro;
Client i
Date Re<
|| Ice Chest ICE/ICE PACKS Temp 4.0 C Carrier
||TLI Number Client Sample ID Matrix
|jmR/H:CPM. Client COC ID * Location
I)
||173-61-1A LTV-65 FILTER
|| LTV-65 C01
||173-61-1B LTV-66 XAD
U LTV-66 C01
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||173-61-1C LTV-63 ACE/MECL2
H LTV-63 C01
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(173-61-1D LTV-67 IMP6RINSE
H LTV-67 C01
R173-61-1E LTV-64 TOLUENE
I) LTV-64 C01
11
R173-61-3A LTV-70 FILTER
H LTV-70 C01
H173-61-2B LTV-71 XAD
I) LTV-71 C01
((173-61-2C LTV-68 ACE/MECL2
fl LTV-68 C01
n .,
R173-61-2D LTV-72 IMP&RINSE
j • LTV-72 C01
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||173-61-2E LTV-69 ' TOLUENE
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1) -
J173-61-3B LTV-76 XAD
I) LTV-76 C01
I) ...
To LAB
Date/Init
J173-61-3C LTV-73 ACE/MECL2 1
D LTV-73 C01
n . -...
||173-61-3D LTV-77 IMP&RINSEj
|| LTV-77 C01 \
H Receiving Remarks: '
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1
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Date/Init j Date/Init
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and Number | JIM GAUGHEY *' I/ 61 ||
LAB
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Date/Init
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Date/Init
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1
To STORAGE
Date/Init
" 1
-
DISPOSED ||
Date/Init jj
II
II
II
II
-------
=TRIANQLE LABORATORIES, INC. -- LOO IN RECORD/CHAIN OF CUSTODY^
| Custody Seal : Absent Sample Seals : Absent
Chain of Custody : Present Container. . . t Intact
Sample Tags t Absent
Sample Tag Numbers t Not Listed on Chain of Custody
SMO Forms : N/A
-
Ice Chest ICE/ICE PACKS Temp 4
TLI Number Client Sample ID Matrix)
|mR/H:CPM. . ... Client COC ID . ..* Location
173-«1-3E LTV-74 TOLUENE)
| LTV-74 C01
|173-61-4A LTV-80 FILTERJ
j LTV-80 C01
II
1
|173-61-4B LTV-81 XAD)
| LTV-81 C01
|173-61-4C LTV-78 ACE/MECL2 |
| LTV-78 CO!
1
|173-61-4D LTV-82 IMP&RINSEJ
1 LTV-B2 C01
9,
||I73-61-4E LTV-79 TOLUENE)
I LTV-79 C01
I)
J173-61-5A LTV-8S FILTER
1 LTV-85 C01
(173-61-5B LTV-86 XAD
LTV- 86 C01
173-61-SC LTV-98 MECL2
LTV- 98 C01
173-61-5D LTV-84 TOLUENE
LTV- 84 C01
TLI Proi
Client!
ect number 42299 Book
ER002 - Eastern Research Group
/? 173
Date Received j 07/01/97 j By /^^^/^/^f^^ Pa9e
. 0 C Carrier
To LAB
Date/Init
•\fnhi
\
i i
i
..,,."
N
Receiving Remarks:
Archive Remarks :
TO STORAGE) TO LAB
Date/Init Date/Init
$7fc7 &
i(vi
•»/ 1 1
Vnlt)
J
\ ^
] %h] (Yl(^
u
I 7iV4
f'-fTI
I-*
To STORAGE) To
Date/Init Dat
i
UA
-------
TRIANGLE LABORATORIES, INC.
SAMPLE TRACKING AND PROJECT MANAGEMENT FORM
ADMINISTRATIVE INFORMATION
TLI Proj#: 42299-A Samples: 4 TurnAround.: 14 Day(s)
Prod Code: D23061 Matrix.: M23Train Hold Time..: 30 Day(s)
DetectLim: 0.05 ng Type...: A Start Date.: 07/15/97
Recvd..: 07/01/97 Ship By : 07/27/97
DWL Due Dt.: 07/22/97
Analyte List,: tetra-octa PCDDs/PCDFs
Method : Method 23 :Tetra-Octa (Tol Combined)
Client Proj..: Iron & Steel-Chicago
Client : Eastern Research Group (ERG02)
P.O. No : Collect Dt/Tm: 06/24/97
Contact : Jim McGaughey Phone : 919/461-1209
Proj. Mgr....: Amy J. Boehm Fax : 919/461-1579
Sample Origin: IL
SPECIAL INSTRUCTIONS / QA REQUIREMENTS
Joint With..: 42299{}> <^U^L^^" Prespike Standard: USF-C, USF-S
Prep Project: 03710 Wv ' Prespike Amount..: 4.0ng
Extraction Exp...: 07/24/97
-------------------------- REPORTING REQUIREMENTS
Reporting Format: Report Option II
See MILES for Instructions /Communications .
Completed by: _ _ DATE:
Reviewed by: fib _ DATE: "g^?. (PMGT0197)
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713 Printed: 08:58 07/15/97
Phone: (919) 544-5729 • Fax: (919) 544-5491
. - 16
-------
Triangle Laboratories, inc
TLI PROJECT* 03710
DATE 6/19/97 TLI BLANK
SPIKE 4.0ng usf-c & usf-s
spike lOOng pah-hrms
SPIKER ywi
PREPARER G.L. ERG02
/. "ft' -r ; :)'?71° ';'"nC
/—x - ;/U :-.. i^/.-r ~ ,-V--s
f , ) f ,\:--v- .fr-'^v '*'•:>£•::, fic-JJ"'-
V'y fe.3vr^vi9/; • -*r?i-:v^'
k^fe^! -.T-; "'iWi
^SS
\i\ \>C-/^ - -Ap*~
^»j • V^t/3 »>J/S-.-L
•VS^s:-
•*^./
cpRn?-Fastern Research Group
LTV-65
R r~ O j © C t : ^J- 2 2
1 73 — ©1 — 1A
ERG02-Eastern Research Group
LTV-66
-73— © 1 — 1
LTV-66
LTV- a(.-^M9"? -M23-OUTLET-XAD-1
? 9ple Type: METHOD 23, OUTLET, RUN 1
.tient: EPA
Location: CHICAGO, IL
Preservative: -XADTrap
Sampler JLSWIFT
Sample ID. LTV-7-!
FieWID- LTV- -M23-04ITLET.XAD-2
Sample Type- METHOD 23 '^
Client EPA
Location. CHICAGO-
Preser. jtive. XAO Trap
"SampieF JLSWIR
Date:
Comments
Tare V^-
rnal Wt
___ ERG02-Eastern Research Group
LTV- 71
1 T3— © 1 — 2B
Triangle. La'c..
TLI PROJECT-*
DATE 6/19/97
SPIKZMlOag
sniks lj
t* -- inc.
/ • irms
usf-s
ERG02-Eastern Research Group
LTV-70
r-ojeot: 4-2299
-I 73-© 1 -2A
17
-------
Client:
\_oeation'.
EPA
CHICAGO, «-
XAOTrap
Sampler
Date:
Comments
TareWt
. ~\
03710
/ Inc
usf-c & u<"
jsr Pah-hrms
ERG02
if 2-
'J
ERG02-Eastern Research Group
LTV-76
r-oj^c-ti^saas
1 73—e 1 —3B
4)
TLI PROJECT* •'fiiQ*** ". ~Inc'
D?:T,'S, . 5/19/97
SPIKE 4.0ng usf-c .£ us'f-s
-pi.;> :• lOOng pan-hrms
' PBFBAEL 5 L'.
ERG02-Eastern Research Group
LTV-81
1 73 — e 1 —
Group
Sample ID:
Field ID:
Sample Type:
Client
Location: • c;.
Preservative: XAO1
Sampler
Date:
Comments
Tare Wt:
Final Wt
18
-------
Date: 07/17/97
Time: 18:51
Sample
# crd TH_Number. . Customer.Sample. Id.
TRIANGLE LABORATORIES, INC.
Wet Lab MM5/PUF Observations
Projecti 42299-A
PRDPERC V3.19
Page: 1
F. XAD
No Color.
Filter
Color..
000 TLI Blank TLI M23 Blank
001 173-61-1ABCE M23-Outlet-Run 1
002 173-61-2ABCE M23-Outlet-Run 2
003 173-61-3ABCE M23-Outlet-Run 3
004 173-61-4ABCE M23-Outlet-RBI
005 TLI LCS TLI LCS
006 TLI LCSD TLI LCSD
*** End of Report ***
WHITE
1 YELLOW/WHI BROWN
1 YELLOW/WHI BROWN
1 YELLOW/WHI BROWN
1 WHITE WHITE
WHITE
WHITE
GlasB Wool PUF
Color Color
YELLOW
YELLOW
YELLOW
WHITE
Odor. . .
NONE
SMOKE
SMOKE
SMOKE
NONE
NONE
NONE
i Air
Q.No. Entered
03710 GO
03710 00
03710 GO
i 03710 GO
03710 GO
GO
: GO
By
Date.... Time..
07/17 18:51 F
07/17 18!51 F
^
I
07/17 18:51 F
07/17 18:51 F
07/17 18:51 F
07/17 18:51 F
07/17 18:51 F
. S
-------
Project: 42299A
TRIANGLE LABORATORIES, INC. PAGE 1 OF 1
Dicncin Sample Preparation Tracking & Management Form
Client: Eastern Research Group (ERGO2)
Solvent(3)/Acid(s) :
Lot Numbers: 9/ 1~)^ t I
IS Spike: 40 wl cone: 0.1000 ng//il
SS Spike: M! cone: . ng/jil
MS Spike: 0 jtl cone: 0.0000 ng/ul
LCS Spike: U M! cone: 0.0000 ng/Ml
OPR Spike: 20 fil cone: _0.01 ng/Ml
Method: Method 23 :Tetra-Octa (Tol Combined) Matrix:
Extraction Date: *2-/H_/3J.
I
;--"!MTz;-7""W&T^P"'
I JWJ I WStt \iy*<&U
i ^F'l i VSF-W iQf^-A
j* / i! /!/1 «•/ £ /if iji>
i
|Chemist I
I Spike # |
I • ID I
| TLI /
#.crd| SAMPLE / CLIENT
I I? / SAMPLE ID
| GROSS
| WEIGHT
| Before After
' / j^ 11 ^ / '^fj''? / ' — ' ' I * Expirj
* £Z / iZ. /I? I ±?/ 1? /i? I "T / J5. /2f/l _/_/_! " Date |
SAMPLE | 3 : / 6"ffa)(t
| 173-61-1ABCE |
01 | M23-Outlet-Run 1 |
' '
1 f 1
Lefti
*
| 173-61-2ABCE |
02 | M23-Outlet-Run 2 |
'
'
| 173-61-3ABCE |
03 | M23 -Outlet -Run 3 |
/ I
|«m,«ft|
iX
\ 173-S1-4ABCE |
04 I M23-Outlet-RBI I
!toy
'£
| TLI LCS
OS |
|
TLI LCS |
,
i f
| Any Left]
TLI LCSD
06
|
TLI LCSD |
[Any Left]
|Any Left]
| yes/no |
-|Any Left)
| yes/no |
1
|Any Left)
| yes /no |
Gross weight of sample container + sample tef ore/after aliquot removal.
.- Lc$ , La s}> used $<44/a> Xffl) fff
counts.-
14P4/C3
Initials
: F5-
Date:
,
Initials of both SPIKER AND OBSERVER must be entered.
XXXXX - Gross Weight not provided for WATER Samples. |
REV 05/27/97 (PSTMF 7)--+
20
-------
PAGE 1 OF 1
TRIANGLE LABORATORIES, INC.
DIOXIN SAMPLE EXTRACTION and CLEANUP TRACKING FORM
TLI Project No.: 42299 A
I I
i
I
I I
nter the procedure number below into the box at the top of each column to signify the step performed.
nitial and date each sample for each numbered procedure performed.
PROCEDURE DETAILS (circle)
iy EXTRACTION OH OFF Soxhlet / 'j4r / Sep Funnel / Steam Dist' / Cont LL / ASE / Waste Dilution |
2*)) SPIKE AFTER EXTRACTION
ADD TRIDECANE
4)/ ROTOVAP 40mL / (lOmL^ / Dryness
COMBINE. ~.<£- JjpL >rtaj$- * . • __ ____
rviDE / LIPID DETERMINATION 20*/80% £so%/50») 5mL/20mL Other
SOLVEJT EXCHANGE
8)) CLEANUP / DSP 225 / DSP 115 / DSP 215 / DSP 267 / Other
:& TRANSFER ^
0) ADDITIONAL CLEANUP Mod. DSP 260 / DSP 225 / DSP 115 / DSP 215 / DSP 267 / Other
1) FINAL TRANSFER
Comments:
«Rev 06/24/97 (PSTMF 4):
21
-------
PAGE 1 OF 1
TRIANGLE LABORATORIES, INC.
Transfer Chain- of -Custody Form
Project 42299-A
Transfer From: DWLH5 To: DMS5
Initials . . Date
Released by:
Accepted by!
Time . . .
MILES.ID.
42299-A
42299-A
42299-A
42299-A
42299-A
42299-A
42299-A
-000
-001
-002
-003
-004
-005
-006
TLI No.
Cust.Id.
TLI Blank
173-61-1ABCE
173-61-2ABCE
173-61-3ABCE
173-61-4ABCE
TLI LCS
TLI LCSD
TLI M23 Blank
M23-Outlet-Run 1
M23-Outlet-Run 2
M23-Outlet-Run 3
M23-Outlet-RBI
TLI LCS
TLI LCSD
Additional comments or instructions:
-XfrCOC (Rev 11/01/94)--+
22
-------
PAGE 1 OF 1
Method: Method 23:Tetra-Octa (Tol Combined)
Required Detection Limit: 0.05 ng
TRIANGLE LABORATORIES, INC.
HR GC/HRMS ANALYSIS
| PROJECT: 42299A
SAMPLE INFORMATION
1ST COLUMN
2ND COLUMN
RS Cone
20 /il 9 100.0 PG/fil
I TLI / | GC/MS FILENAME |CONFIRM |CONFIRM FILENAME |USF-RS |USF-RS (ANALYSIS
#.crd| SAMPLE ID / CLIENT | COLUMN: "Mpf | |COLUMN: ^§IT£~ |VOLUME (INIT. |COMMENTS
| / SAMPLE ID | || ISOLN ID IDATE |
I TLI Blank | | X |
00 | TLI M23 Blank
173-ol-lABCE
|
01
1
1
'
1 173-.HABCS
02 '
1 |
| 173-61-3ABCE
03 | M23-Outlet-Run 3 |i i
i i Q*. . ,- 3 3
| 173-61-4ABCE |
34 | M23-Outlet-RBl '
| TLI LCS
35
|
I
i
.a..!.
I i I
| TLI LCSD
36 |
TLI LCSD |
Counts:
"7
Type: A
Spike File: SPX23704
Amt of Extract: 50% |
REV
23
-------
Triangle Laboratories, inc.
Run Log
Instrument ID
Column Type
Column ID
Plot Name
In). Vol.
Acquisition
S/Q
Signature
Date
Filename
1
Date*
Time*
Project #
Sample*
No.
ll
Cllent Sample ID
Syr
Mlfl
332
Operator/Date
Comments*
V
S-o
ok
(l/t
0
*~-0
%?V1
K/
)^ «.-*-€« ^
IV If
c?
TM
D
v-i
*
*»
Transcribed from chromatographic data
Dated initials required
srvrl/qa/forms/hrruntog doc (02/05/97)
ConCal Due:
ConCal Due:
. 66
-------
Triangle Laboratories, Inc.
Run Log
ID
Instrument ID
Column Type
Column ID
Plot Name
Ini. Vol.
Acquisition
/
Signaturf
G/C
7
Date
Filename
Date*
Time*
Project #
Sample*
No.
Client Sample ID
Syr
332
Operator/Date
Comments
•-TCO-
US
LcS
lc?Q
I/
1^1
JrCl
Ay'
fl-M
^
-r LI u/s
i/
I/
Jb
i/
TM
v<
* Transcribed from chromatographic data
** Dated initials required
srvr1/qa/forms/hrrunlog doc (02/05/97)
ConCal Due:
ConCalDue:
Pace:
G7
-------
I Mil I l_l>H
Instrument ID Column Type Column ID Plot Name Inj. Vol. Acquisition
-fj H/ll JJ
^1 qc^oKJLO^s
1 I Signature
QIC
*to/4>
Date
CD
CM
Filename
Date*
Time*
Project #
Sample*
No.
Client Sample ID
Syr
332
Operalor/Date
Comments*
Hw/HA
m-il-HMct
i
I
±
Jt
J/
JL
* Transcribed from chromatographic data
** Dated initials required
srvr1/qa/forms/hrrunlog.doc (02/05/97)
ConCal Due:
ConCal Due:
68
Page:
-------
Triangle Laboratories, Inc.
Run Log
Instrument ID Column Type Column ID
Plot Name
Inl. Vol.
Acquisition
Signature
G/C
Date
Filename
Date* Time*
Project*
Sample*
No.
Client Sample ID
Syr
332
Operator/Date
Comments*
PVUI
\ -
V!
1/1
fat
l+1
2_
9
flU 3
* Transcribed from chromatographic data
** Dated initials required
srvr1/qa/forms/hmink>g doc (02/05/97)
ConCal Due:
ConCal Due:
-------
SAMPLE
DATA
Triangle Laboratories, Inc.
801 Cap/to/a Drive P.O. Box 13485
Durham, NC 277134411 Research Triangle Park, NC 277094485
919-544-5729 Fax * 919-544-5491
28
-------
TRIANGLE LABORATORIES. INC.
MATRIX SPIKE RECOVERY ANALYSIS AND COMPARISON
Project: 42299 - A
Matrix: XAO
Method: Modified 23
ner
3-TCOD
78-PeCDD
478-HxCOD
578-HxCDD
789-HxCDD
4678-HpCDD
a
8-TCDF
78-PeCDF
78-PeCDF
478-HxCDF
578-HxCDF
578-HxCDF
789-HxCDF
4678-HpCDF
4789-HpCDF
-
Not Detected
Not Applicable
]: EMPC Value
ent Recovery QC
W972829
ID: TLI M23 Blrnk
Sample
(ng)
ND
NO
ND
NO
NO
0.02
[0.04]
ND
ND
ND
[0.02]
ND
ND
NO
[0.04]
NO
0.08
Processed By:
Limits: 70 to 130
tive Percent Difference QC Limits:
W972825
ID: TLI LCS
With Spike
(ng)
0.39
1.8
2.0
1.9
1.5
1.9
4.0
0.36
1.9
1.7
2.1
2.0
2.1
2.2
1.9
1.6
3.6
\JcC/
percent.
+/- 20 percent.
Percent
Recovery
96.4
90.3
100
95.1
77.0
95.3
99.9
90.1
96.1
84.8
102
102
107
112
94.5
79.9
87.6
W972826
10: TLI LCSO
Spike Dup
(ng)
0.41
2.0
2.4
2.0
1.8
1.9
4.1
0.38
2.1
1.9
2.1
2.1
2.4
2.2
2.0
1.6
3.5
Date: 07/24/97
Percent
Recovery
103
100
119
101
90.8
93.1
101
95.8
103
96.5
103
105
118
112
97.3
78.9
84.6
Relative
Percent
Difference
6.62
10.2
17.4
6.02
16.4
2.34
1.10
6.13
6.93
12.9
0.98
2.90
9.78
0.0
2.92
1.26
3.48
MILES 4.15.00
GRY_PSUM vl.OO
.... . .
: Method 23 does not address spiked saaples. Triangle Labs
uses Method 8290 control Units as advisory guidelines.
nal Spike Levels (ng):
TCDD/TCDF..: 0.4 ng
PeCDD/PeCDF: 2.0 ng
HxCDO/HxCDF: 2.0 ng
HpCDD/HpCDF: 2.0 ng
OCDO/OCDF..: 4.0 ng
29
-------
TRIANGLE LABORATORIES, INC.
Sample Result Summary for Project 42299A
Method 8290X Full Screen Analyses (DB-5)
Page 1
07/24/97
Data File
Sample ID
Units
Extraction Date
Analysis Date
Instrument
Matrix
Extraction Type
Analytes
2378-TCDD
12378-PeCDD
123478-HxCDD
123678-HxCDD
123789-HxCDD
1234678-HpCDD
OCDD
2378-TCDF
12378-PeCDF
23478-PeCDF
123478-HxCDF
123678-HxCDF
234678-HxCDF
123789-HxCDF
1234678-HpCDF
1234789-HpCDF
OCDF
TOTAL TCDD
TOTAL PeCDD
TOTAL HxCDD
TOTAL HpCDD
TOTAL TCDF
TOTAL PeCDF
TOTAL HxCDF
TOTAL HpCDF
W972831
M23-Outlet-Run
1
ng
07/17/97
07/22/97
W
M23TRAIN
W972832
M23-Outlet-Run
2
ng
07/17/97
07/22/97
W
M2 3TRAIN
M23-Outlet-RBI,
ng v—"
07/17/97 "\j
07/22/97
W
M23TRAIN
0.08
0.21
0.04
0.94
0.48
1.1
0.83
3.9
0.59
0.56
0.67
0.25
0.23
{0.02}
0.37
0.05
0.16
0.93
1.3
8.2
2.5
31.1
6.2
2.8
0.42
B
B
0.08
0.21
{0.06}
0.89
0.42
1.1
0.71
5
54
56
69
0.27
0.24
0.03
0.38
{0.06}
{0.10} B
0.78
1.4
7.6
2.5
27.5
7.4
2.9
0.63
B
Other Standards Percent Recovery Summary (% Rec)
37C1-TCDD
13C12-PeCDF 234
13C12-HXCDF 478
13C12-HXCDD 478
13C12-HpCDF 789
98.1
98.6
109
69.3
94.7
V
97.2
96.7
104
68.8
95.4
V
-Otiier.- -^franria-rf^g
13012-HxCDF 789
13C12-HxCDF 234
90.4
94.6
StTrnma-ry (9c Raf \
92.9
95.4
Internal Standards Percent Recovery Summary (% Rec)
13C12-2378-TCDF 91.6 85.9
13C12-2378-TCDD 98.8 89.6
13C12-PeCDF 123 98.4 84.5
13C12-PeCDD 123 98.0 " 87.5 "" "
B
B
{0.03}
(0.03)
(0.03)
(0.02)
(0.02)
(0.04)
0.10
0.02
(0.02)
(0.02)
0.02
(0.01)
(0.02)
(0.02)
{0.03} B
(0.03)
{0.06} B
{0.03}
(0.03)
(0.02)
(0.04)
0.02
(0.02)
0.02
{0.03}
105 .
117
98.8
87.1
92.6
86.7
78.8
93.9
85.4
65.2
72.7
W972833
M23-Outlet-Run
3
ng
07/17/97
07/22/97
W
M23TRAIN
0.06
0.20
0.04
0.93
0.40
0.94
{0.70} B
2.9
0.42
0.46
0.54
0.22
0.17
(0.03)
0.36
{0.05}
20
B
0
0.81
1.7
7.6
2.2
24.0
5.6
2.3
0.58
99.4
98.6
101
76.4
98.1
B
97.8
97.1
92.9
94.8
94.3
95.8
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 16:00 07/24/97
30
-------
TRIANGLE LABORATORIES, INC.
Sample Result Summary for Project 42299A
Method 8290X Full Screen Analyses (DB-5)
Page 2
07/24/97
Data File
Sample ID
Units
Extraction Date
Analysis Date
Instrument
Matrix
Extraction Type
W972831
M23 -Outlet-Run
1
ng
07/17/97
07/22/97
W
M2 3 TRAIN
W972832
M23 -Outlet-Run
2
ng
07/17/97
07/22/97
W
M2 3 TRAIN
r ::============ ===
W972830
M23 -Outlet-RBI
ng
07/17/97
07/22/97
W
M2 3 TRAIN
W972833
M23-Outlet-Run
3
ng
07/17/97
07/22/97
W
M23TRAIN
Internal Standards Percent Recovery Summary (% Rec)
13C12-HXCDF 678 82.5
13C12-HxCDD 678 83.7
13C12-HpCDF 678 80.5
13C12-HpCDD 678 75.0
13C12-OCDD 39.9
87.0
89.9
74.9
68.2
38.3
71.9
89.7
75.0
75.1
62.4
94.0
88.9
81.7
76.1
50.2
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitals Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 16:00 07724/97
31
-------
TRIANGLE LABORATORIES, INC.
Sample Result Summary for Project 42299A
Method 8290X Full Screen Analyses (DB-5)
Page 3
07/24/97
Data File
Sample ID
W972829
TLI M23 Blank
Units
Extraction Date
Analysis Date
Instrument
Matrix
Extraction Type
ng
07/17/97
07/22/97
W
XAD
Analytes
2378-TCDD
12378-PeCDD
123478-HxCDD
123678-HxCDD
123789-HxCDD
1234678-HpCDD
OCDD
2378-TCDF
12378-PeCDF
23478-PeCDF
123478-HxCDF
123678-HxCDF
234678-HxCDF
123789-HxCDF
1234678-HpCDF
1234789-HpCDF
OCDF
TOTAL TCDD
TOTAL PeCDD
TOTAL HxCDD
TOTAL HpCDD
TOTAL TCDF
TOTAL PeCDF
TOTAL HxCDF
TOTAL HpCDF
(0.01)
(0.02)
(0.02)
(0.01)
(0.02)
0.02
{0.04}
(0.007)
(0.01)
(0.01)
{0.02}
(0.01)
(0.02)
(0.02)
{0.04}
(0.03)
0.08
(0.01)
(0.02)
(0.02)
0.02
(0.007)
(0.01)
{0.02}
{0.04}
Other Standards Percent Recovery Summary (% Rec)
37C1-TCDD 104 - ...
13C12-PeCDF 234 110
13C12-HXCDF 478 93.8
13C12-HXCDD 478 80.0
13C12-HpCDF 789 88.5
.Other, -qt-anrqai-^g Por-nonl- Pof rvu-QT-y grm»ir»a-ry_(^_ppr; ^
13C12-HXCDF 789 86.3
13C12-HxCDF 234 79.2
Internal Standards Percent Recovery Summary (% Rec)
13C12-2378-TCDF 97.1
13C12-2378-TCDD 87.5
13C12-PeCDF 123 84.1
13C12-PeCDD 123 "88.6
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 16:00 07/24/97
32
-------
TRIANGLE LABORATORIES, INC.
Sample Result Summary for Project 42299A
Method 8290X Full Screen Analyses (DB-5)
Page 4
07/24/97
Data File
Sample ID
Units
Extraction Date
Analysis Date
Instrument
Matrix
Extraction Type
W972829
TLI M23 Blank
ng
07/17/97
07/22/97
W
XAD
Internal Standards Percent Recovery Summary (% Rec)
13C12-HxCDF 678 71.8
13C12-HXCDD 678 102
13C12-HpCDF 678 74.6
13C12-HpCDD 678 82.2
13C12-OCDD 70.2
{Estimated Maximum Possible Concentration), (Detection Limit)
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 16:00 07/24/97
33
-------
STANDARD OPERATING PROCEDURES
Table of Contents
High Res Dioxin Analysis
BOOK: 38
ID Revision Title
6.0.01 2 PREVENTATIVE AND SCHEDULED MAINTENANCE OF LABORATORY EQUIPMENT
6.01.02 1 PIPETTE CALIBRATION
CMA103 2 CHANGING HEUUM CYLINDERS
CSS104 4.0 ANTI-VIRUS SOFTWARE INSTALLATION AND USE
DDR 104 8.0 DETERMINATION OF NOISE IN AN HRGC/HRMS SICP
DHRioi 3 CLEANING SYRINGES
DHR117 5 ADDITION OF RECOVERY STANDARD SOLUTION
DHR129 2 CHANGING A PFK SEPTUM
2 CHANGING THE GC INTERFACE PLATE AND WASHER
5 PCDDS AND PCDFS BY HRGC/HRMS-METHOD 8290
2 PCDDS AND PCDFS BY GC/MS - METHOD 8280
1 PCDDs AND PCDFs BY HRGC/HRMS- METHOD 1613A4B
1 THE PURIFICATION OF n-NONANE BY FLORISIL
DHR157
DHR182
DHR183
DHR184
DSP265
Page 1 of 1
712497
34
-------
TRIANGLE LABORATORIES, INC.
Sample Result Summary for Project 42299A
Method 23X (DB-225)
Page I
07/24/97
Data File
Sample ID
Units
Extraction Date
Analysis Date
Instrument
Matrix
Extraction Type
Analytes
2378-TCDF
P973370
M23-Outlet-Run
1
ng
07/17/97
07/23/97
P
M23TRAIN
P973371
M23-Outlet-Run
2
ng
07/17/97
07/23/97
P
M23TRAIN
P973372
M23-Outlet-Run
3
ng
07/17/97
07/23/97
P
M23TRAIN
P973373
M23-Outlet-RBI
ng
07/17/97
07/23/97
P
M23TRAIN
1.1
0.89
0.73
0.006
Internal Standards Percent Recovery Summary (% Rec)
13C12-2378-TCDF 103 92.2
92.6
80.9
Triangle Laboratories, Inc.® Analytical Services Division
801 Captola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 15:59 07/24/97
35
-------
,,t ^ , ,
•*& "• '"', ' \Xs '£•
*<<&* *""*&?$mfr<}.
TLI Project: 42299A
Client Sample: TLI M23 Blank
Method 23 PCDD/PCDF Analysis (a)
Analysis File: W972829
Client Project:
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
Iron & Steel-Chicago
XAD Date Received:
TLJ Blank Date Extracted:
Date Analyzed:
1.000
n/a
DB-5
Dilution Factor:
Blank File:
Analyst:
II
07/17/97
07/22/97
n/a
W972829
MM
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPX23704
WF54307
W972828
n/a
n/a
n/a
Anafytes
2,3,7,8-TCDD
U,3,7,8-PeCDD
1,2,3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
1,2,3,4,6,7,8-HpCDD
1,2,3,4,6,7,8,9-OCDD
2,3,7,8-TCDF
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
U,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
1,2,3,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
1,2,3,4,6,7,8,9-OCDF
Totals
Total TCDD
Total PcCDD
Total HxCDD
Total HpCDD
Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF
K&mSltf
ND
ND
ND
ND
ND
0.02
EMPC
ND
ND
ND
EMPC
ND
ND
ND
EMPC
ND
0.08
Amt (ng
ND
MTV
ND
0.02
ND
ND
EMPC
EMPC
^i^^i^^^^K^-.^' ^^ -**$&&& $R » \£bg/s
0.01
0.02
0.02
0.01
0.02
1.19 31:45
0.04
0.007
0.01
0.01
0.02
0.01
0.02
0.02
0.04
0.03
0.78 34:18
r Kureter DL EMPC Flags
0.01
fi CtTf
0.02
1
0.007
0.01
0.02 . . . _
0.04
Page 1 of 2
X237 JPSR vlOO. LARS 6.10.03
Triangle Laboratories, Inc.®
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 20:45 07/22/97
36
-------
^ / X
V v*^.
TLI Project:
Client Sample:
42299A
TLI M23 Blank
Method 23 PCDD/PCDF Analysis (a)
Analysis File: W972829
.-. inter ns& Standards '...'' 1 • .?v.v-:"' . ..!
13C,2-2,3,7,8-TCDF
13C,2-2,3,7,8-TCDD
13C,2-l,2,3,7,8-PeCDF
13Ci2-l,2,3,7,8-PeCDD
I3C,2-l,2,3,6,7,8-HxCDF
13C,2-l,2,3,6,7,8-HxCDD
13C,2-l,2,3,4,6,7,8-HpCDF
13C12-l,2,3,4,6,7,8-HpCDD
13Ci2- 1,2,3,4,6,7,8,9-OCDD
Surrogate Standards (type A)
37CL.-2,3,7,8-TCDD
13C,2-2,3,4,7,8-PeCDF
13Cp-l,2,3,4,7,8-HxCDF
13Cp-l,2,3,4,7,8-HxCDD
3C,2-l,2,3,4,7,8,9-HpCDF
#»wripate&^^
13C,2-l,2,3,7,8,9-HxCDF
13C,2-2,3,4,6,7,8-HxCDF
Recovery Standards
13C12-1,2,3,4-TCDD
13Cp-l,2,3,7,8,9-HxCDD
fArat:Cr*s}
3.9
3.5
3.4
3.5
2.9
4.1
3.0
3.3
5.6
AWL w
4.2
4.4
3.8
3.2
3.5
Amt fng}
3.5
3.2
"
%R*o»»fy
97.1
87.5
84.1
88.6
71.8
102
74.6
82.2
70.2
% Recovery
104
110
93.8
80.0
88.5
% Recover/
86.3
79.2
QC Limits
40%- 130%
40%-130%
40%-130%
40%-130%
40%-130%
40%-130%
25%- 130%
25%-130%
25%-130%
QC Limits
70%-14070
70%- 140%
70%- 140%
70%- 140%
70%- 140%
QC Limits
40%- 130%
40%- 130%
:^i®te-x
0.76
0.81
1.52
1.46
0.51
1.29
043
1.06
091
lafcifey*;-
1.48
051
1.17
0.43
Ratio
0.52
0.50
Ratio
0.83
123
^ttar.'
19:53
20:43
24:19
25:28
28:08
28:52
30-53
31:45
34-12
^Iffc
20:44
25:05
28-02
28:48
32:06
RT
29:23
28:40
RT
20:30
29-10
*>:»§».";
—
—
•'m*&::-
—
Ffegs
—
Flags
—
Data Reviewer
07/22/97
Page 2 of 2
X237.PSR viOO. LARS 6.10.03
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 20:45 07/22/97
37
-------
TLI Project: 42299A
Client Sample: TLI M23 Blank
Toxicity Equivalents Report
Analysis File: W972829
Client Project:
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
Iron & Steel-Chicago
XAD
TLI Blank
1.000
n/a
DB-5
Date Received:
Date Extracted:
Date Analyzed:
Dilution Factor:
Blank File:
Analyst:
/ /
07/17/97
07/22/97
n/a
W972829
MM
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPX23704
WF54307
W972828
n/a
n/a
n/a
Analytes
2,3,7,8-TCDD
1,2,3,7,8-PeCDD
1,2.3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDD
1,2.3,7,8,9-HxCDD
1.2.3.4,6,7,8-HpCDD
1,2.3,4.6,7,8,9-OCDD
TOTAL PCDD
2,3,7,8-TCDF
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
1.2,3,4,7,8-HxCDF
1,',3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
1,2.3,4.6,7.8-HpCDF
1,2,3.4,7,8,9-HpCDF
1,2,3,4,6,7,8,9-OCDF
TOTAL PCDF
AmL (ng)
(0.01)
(0.02)
(0.02)
(0.01)
(0.02)
0.02
[0.04]
(0.007)
(0.01)
(0.01)
[0.02]
(0.01)
(0.02)
(0.02)
[0.04]
(0.03)
0.08
Total
* v
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
EPA TEFs,
TEF <••'•. ;-
1
0.5
0.1
0.1
0.1
0.01
0.001
0.1
0.05 „
.0.5
0.1 . ; =
0.1
0.1
0.1
0.01
0.01
0.001
1989a: 0.0392 ng
Equivalent
0.01
0.01
0.002
0.001
0.002
0.0002
0.00004
0.0252
0.0007
0.0005
0.005
0.002
0.001
0.002
0.002
0.0004
0.0003
0.00008
0.014
[...] indicates that the value is that of an EMPC.
(...) indicates that the value is that of a Detection Limit.
Page 1 of 1
TEFPR vS.l I. LARS 6.10.II5<.
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 19:1909/18/97
Added Paae
-------
Data Review By:
. .Date..
Calculated Noise Area: 14.30
The Total Area for each peak with an ion abundance ratio outside
ratio limits has been recalculated according to method requirements.
Page No. 1
07/22/97
Compound/
M_Z.... QC.Log Omit Why
TCDF
304-306
D
304-306
13C12-TCDF
316-318
316-318
TCDD
320-322
320-322
37C1-TCDD
328
DC
DC
DC
D
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC .
DC
DC
NL
SN
SN
SN
SN
SN
0
NL
WL
WH
WH
4
NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
_SN
WH
WH
0
Listing
Matched
. . RT . OK
0;
17:
:00
54
18:15
19:
20:
20:
54
:18
: 42
0
RO
RO
RO
RO
RO
of W972829B.dbf
GC Peaks / Ratio / Ret. Time
Ratio Total. Area. .. Area. Peak. 1. . Area . Peak . 2 . . Rel.RT Compound. Name. . ID.. Flags.
.65-0.89
1
1
0
0
0
1
.06
.48
.92
.57
.80
.83
Peaks
0:
18:
19:
19:
20:
20:
21:
21:
00
38
22
53
23
44
22
50
0.
RO
RO
RO
11
13
19
35
17
17
0
.98
.77
.17
.65
.69
.58
.00
.65-0.89
0
0
0
0
0
0
0
0
Peaks
0:
17:
18:
18:
18:
19:
19:
20:
20:
20:
21:
21:
22:
22:
00
44
01
41
59
15
36
16
28
43
09
0.
RO
RO
RO
RO
RO
RO
RO
RO
RO
L5 RO
09
25
.44
.32
.52
.76 15
.94
.86
.82
.71
15
65-0.89
0
1
1
0
0
1
1
0
5
1
0
6
0
0
.74
.52
.33
.23
.53
.23
.46
.16
.68
.26
.69
.00.
.69
.84
Peaks
5
90
64
,631
192
29
20
49
.93
.60
.64 28.12
.51 6,744.74
.91 102.00
.84 13.76
.38
.64
0.819-1.109
0
0
0
1
1
1
.000
.900
.918
.001 2378-TCDF AN
.021
.041
0.950-1.050
0
0
53.91 0
8,886.77 1
108.99 1
16.08 1
1
1
.000
.937
.974
.000 13C12-2378-TCDF ISO
.025
.043
.075
.098
,918.90
4
13
2
6
9
11
7
1
4
16
8
.64
.86
.28
.69
.72
.15
.38
.82
.48
.00
.87
1.9-L
13
11
0
.90
.91
.00
0.849-1.064
0
0
0
0
0
0
0
0
0
.000
.856
.870
.902
.916
.929 _
.946
.978
.988
1.000 2378-TCDD AN
1.021
1^026
1.069
1.
.082
0.903-1.097
DC
DC
DC
DC
NL
SN
SN
SN
0:
19:
19:
19:
00
03
34
56
2
3
5
6
.31
.01
.90
.08
0.000
0.920
0.944
0.
.962
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 20:45 07/22/97
38
-------
Page No.
07/22/97
Listing of W972829B.dbf
Matched (X Peaks / Ratio / Ret. Tin
Compound/
M_2.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak. 1. . Area.Peak.2.. Rel.RT Compound.Name.. ID.
Flags.
328
13C12-TCDD
332-334
332-334
PeCDF
340-342
D
34Q-342_
13C12-PeCDF
352-354
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
D
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
SN
SN
SN
SN
3
NL
SN
SN
SN
SN
4
NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
WH
WH
0
NL
SN
20:03
20:22
20:44
21:06
21:28
21:39
21:48
Peaks
0
20
20
21
21
21
21
22
22
:00
:30
:43
:07
:17
:32
:37
:05
:15
0.
RO
RO
RO
RO
RO
RO
10
10
5.17
2.14
,611.30
33.02
10.80
6.85
12.54
,656.36
.65-0.39
2.
0.
0.
0.
1.
1.
0.
0.
2.
Peaks
0
22
22
22
23
23
23
24
24
24
25
25
25
25
26
26
26
26
:00
:07
:28
:34
:16
:31
:44
:16
:35
:42
:05
:14
:45
:54
:11
:17
:32
:40
1.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
82
83 11
81 10
96
75
54
57
38
96
22
32-1.78
1.
5.
0.
0.
35.
1.
0.
1.
0.
0.
1.
1.
1.
0.
3.
6.
0.
0.
04
74
53
22
38
39
52
12
37
99
74
41
17
31
66
65
11
92
Peaks
0
23
23
24
24
25
25
:00
-.21
:56
:19
:37
:05
:37
1.
RO
RO
RO
32-
0.
1.
1.
1.
1.
1.
0.
1.78
98
54
90
52 9
33
48 9
25
11.12
,418.54
,496.06
176.61
16.58
13.33
9.01
29.11
8.44
,120.32
4.98
2.32
17.46
3.16
0.61
8.74
6.15
27.41
7.75
10.04
18.61
14.04
18.34
3.32
13.11
1.84
1.46
4.24
0.00
3.72
46.27
50.54
,768.98
76.04
,931.60
5.64
0.
0.
10,611.30 1.
33 . 02 1 .
1.
1.
12 . 54 1 .
0.903-
0.
5,165.27 6,253.27 0.
4,697.46 5,798.60 1.
96.15 99.78 1.
1.
1.
1.
13.60 15.51 1.
1.
968
983
001 37C1-TCDD
019
036
045
052
1.097
000
990 13C12-1234-TCDD
000 13C12-2378-TCDD
019
027
039
043
066
074
SUR1
RSI
IS1
0.904-1.081
0.
0.
0.
0.
0.
0.
0.
0.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
0.835-
0.
28.06 18.21 0.
37.71 19.82 0.
5,888.37 3.880.61 1.
43.35 32.69 1.
5,931.99 3,999.51 1.
1.
000
910
924
928
957
967
976
998
Oil
016
032 23478-PeCDF
038
059
065
077
081
091
097
1.165
000
960
984
000 13C12-P«CDF 123
012
032 13C12-i>«cnF 234
053
AN
IS2
SOR2
Triangle Laboratories, Inc.® Analytical Services Division
801 Capftola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 20:45 07/22/97
39
-------
Page No.
07/22/97
Listing of W972829B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak. 1.. Area.Peak.2. . Rel.RT Compound.Name.. ID.. Flags.
352-354
PeCDD
356-358
356-358
13C12-PeCDD
368-370
368-370
HxCDF
374-376
M
374-376
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
6
NL
SN
SN
SN
SN
SN
SN
SN
SN
WH
0
NL
SN
SN
SN
SN
SN
SN
2
NL
WL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
WH
1
26:05
Peaks
0:00
23:23
23:27
23:34
23:47
24:17
24:45
25:06
25:29
26:11
Peaks
0:00
23:52
24:03
24:40
24:53
25:28
25:37
25:49
26:19
Peaks
0:00
26:51
26:59
27:13
27:27
27:36
27:41
27:46
27:48
28^02.
28:10
28:36
28:41
28:59
29:05
29:16
29:23
29:53
Peak
RO
1
RO
RO
RO
RO
RO
RO
RO
RO
1.
RO
RO
RO
RO
1
.87
36.80
19,910
.32-1.78
1
0
0
0
0
1
0
0
1
1
.04
.31
.69
.58
.81
.07
.20
.82
.72
.48
3
1
1
10
11
19
2
9
12
8
0
.23
iE* / p-
K 1 C V
.96
.15
.76
.55
.30
.69
.37
.46
.22
.20
.00
,32-1.78
0
1.
.98
.54
0.90
0.17
0.
1.
,36
.46
1.64
RO
RO
1.
RO
RO
RO
RO
RO
RO
RO
RO
RQ .
RO
RO
RO
RO
RO
0.
98
1.94
H WMVVM .
3
4
9
2
4
5,453
613
.11
.65
.15
.11
.10
.87
.99
18.33
12.75
6,067.86
B**^T\^ / Uu/
05-1.43
2.
1.
2.
0.
0.
1.
11.
2.
1.
71
35
64
68
34
49
56
74
46
-1-02.
1.
0.
1.
0.
0.
0.
0.
1.
06
78
42
70
45
99
94
17
J 1 IUIV
6.18
6.46
8.36
7.91
8.
8.
0.
4.
9.
18
89
76
79
39
45. 7Q .
22.
5.
27.
4.
3.
7.
9.
4.
45.
48
74
23
28
49
14
21
77
70
26.96 14.43 1
.073
0.918-1.027
0
0
0
0
0
0
0
0
1
1
.000
.918
.921
.925
.934
.954
.972
.986
.001 12378-PeCDD
.028
AN
0.843-1.157
0
0
0,
.000
.937
.944
0.969
0.
3,237.52 2,216.35 1.
381.77 232.22 1.
1.
1.
"*ni? P«1 1 SM»ie
.977
,000 13C12-PeCDD 123
.006
.014
033
I S3
0.956-1.053
0.
0.
0.
0.
0.
0.
0.
0.
0.
000
954
959
967
976
981
984
987
988
25 , 3n 24 7n 0 0°6 t2^478-H5fTTIF aM
1.001 123678-HXCDF
1.
1.
1.
1.
1.
1.
1.
017
020 234678-HxCDF
030
034
040
044 123789-HxCDF
062
AN
AN
AN
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 20:45 07/22/97
40
-------
Page No. 4
07/22/97
Compound/
M_Z. . . . QC.Log Omit
13C12-HXCDF
384-386 DC
DC
DC
DC
DC
DC
DC
384-386
why
NL
SN
SN
SN
SN
SN
SN
7
Listing
Hatched
. . RT . OK
0:
27:
27:
27:
27:
28:
28:
28:
28:
29:
29:
29:
29:
29:
00
02
10
32
48
02
08
40
56
09
23
42
44
51
0.
RO
RO
RO
RO
RO
RO
RO
of W972829B.dbf
GC Peaks / Ratio
Ratio Total. Area
43
0
0
0
0
0
0
0
0
0
0
0
0
0
0
-0.59
.62
.44
.53
.87
.54
.51
.51
.50
.26
.91
.52
.15
.70
.41
Peaks
13
44
57
9
7
7,758
9,064
8,057
42
14
7,542
15
22
19
32,567
/ Ret . Time
. .. Area. Peak. 1. . Ar ea . Peak . 2 . .
.44
.76 13.71
.81 19.93
.12
.04
.06 2,621.15
.98 3,076.28
.78 2,701.28
.22 14.26
.66
.37 2,574.92
.13
.11
.93
.98
0.
31.05
37.88
5.136.91
5,988.70
5,356.50
55.69
4,967.45
Rel . RT Compound . Name . .
358-1.142
0.000
0.961
0.966
0.979
0.988
0.996 13C12-HXCDF 478
1.000 13C12-HXCDF 678
1.019 13C12-HXCDF 234
1.028
1.036
1.044 13C12-HXCDF 789
1.056
1.057
1.061
ID. . Flags.
SUR3
1 34
ALT2
ALT1
HxCDD
390-392 DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
390-392
13C12-HXCDD
402-404 DC
DC
DC
402-404
HpCDF
408-410 DC
DC
M
NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
WH
WH
WH
0
NL
WL
SN
4
NL
WL
0:
27:
27:
27:
27:
28:
28:
28:
28:
28:
29:
29:
29:
29:
00
36
43
47
54
02
08
14
46
53
10
19
22
34
1.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
05-1.43
0
1
1
1
69
1
2
0
1
0
2
2
1
1
.53
.30
.04
.47
.67
.13
.58
.47
.44
.51
.18
.37
.52
.46
Peaks
0:
27:
28:
28:
28:
29:
29:
00
34
14
48
52
10-
30
1.
RO
RO
RO
3
13
7
4
0
20
5
5
9
10
12
3
13
7
0
.76
.73
.46
.79
.13
.11
.98
.53
.83
.91
.41
.90
.26
.53
.00
05-1.43
1
8
1
1
1
•^
2
Peaks
0:
30:
30:
00
41
54
0.
RO
RO
.61
.56
.31
.17
.29
..23
.46
*!>.-..«.
6
1
23
6,604
9,240
_8 ..428
32
24,307
88-1.20
1
0
1
.08
.32
.29
7
5
73
.18
.48
.23
.70 3,554.19
.62 5.211.90
.88 d fiSfi fifi
.91 36.09
.11
D / HpCDF Follows —~
.31
.55
.03 46.20
0.
0.
3,050.51
4,028.72
949-1.015
0.000
0.956
0.960
0.962
0.967
0.971
0.975
0.978
0.997
1.001 123678-HxCDD
1.010 123789-HxCDD
1.016
1.017
1.024
965-1.035
0.000
0.955
0.978
0.998 13C12-HXCDD 478
1.000 13C12 -HxCDD 678
1_7_7? Ti i mo nri-2-nvrnn 7S9
14.69
0.
35.80
1.022
996-1.045
0.000
0.994
1.001 1234678-HpCDF
AN
AN
SUR4
1 35
BS9
AN
Triangle Laboratories, Inc.® Analytical Services Division
801 Capftola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 20:45 07/22/97
41
-------
Page No. 5
07/22/97
Compound/
M_2.... QC.Log omit Why
Listing of W972829B.dbf
Matched GC Peaks / Ratio / Ret. Time
.RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. 10.. Flags.
408-410
13C12-HpCDF
418-420
DC
DC
DC
DC
DC
DC
DC
SN
SN
SN
SN
SN
WH
1
NL
31
31
31
:30
:34
:53
32:01
32:06
32:33
RO
RO
RO
RO
RO
RO
1
13
0
0
0
2
.29
.99
.34
.23
.56
.41
Peak
0:00
0
RO
30:53
DC
DC
DC
SN
SN
SN
31:13
RO
31:26
31:49
RO
32:06
418-420
HpCDD
424-426
M
424-426
13C12-HpCDD
436-438
436-438
OCDF
442-444
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
2
NL
SN
SN
WH
WH
1
NL
SN
2
NL
SN
SN
SN
DC SN
DC
DC
DC
DC
DC
DC
DC
DC
SN
SN
SN
SN
SN
SN
SN
SN
6
3
9
3
21
7
73
.12
.02
.51
.00
.64
.81
.03
.37-0.51
0
0
0
0
.73
.43
.25
.47
1.92
0.43
Peaks
0:
31:
31:
31:
32:
32:
00
01
09
45
05
11
0.
RO
RO
RO
RO
RO
.88-1.20
0.
.34
0.73
0.61
1.
19
3.32
3.54
Peak
0:
31:
32:
32:
00
45
05
11
0.
RO
RO
10
5,453
33
26
4
3,547
.08
.73 1,627.20
.19
.54
.48
.62 1,066.78
1.020
1.022
1.032
1.037
1.039 1234789-HpCDF
1.054
0.935-1.130
0.000
3,826.53 1.000 13C12-HpCDF 678
1.011
1.018
1.030
2,480.34 1.039 13C12-HpCDF 789
AN
IS6
SOR5
9,001.35
• HDCDF / HDCDD Follows
4
3
12
32
3
5
32
.55
.08
.18
.90 17.90
.98
.51
.90
88-1.20
0.
1.
0.
0.
34
06
99
30
Peaks
0:
30:
31:
31:
.31:
32:
33:
33:
33:
33:
33:
34:
34:
35:
00
52
11
31
43
38
02
08
21
28
45
18
26
15
0.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
17
4,986
25
13
5,012
uw/^m
.97
.20 2.564.19
.96 12.94
.14
.16
76-1.02
0.
0.
0.
2.
2.
2.
4.
0.
0.
2.
0.
0.
0.
1.
92
21
79
32
09
75
57
37
35
18
86
78
47
10
5
5
20
.26
.03
.72
3.50
11.02
3.18
3.38
8.69
4.
.08
5.63
9.74
80.86 35.53
16.01
8.05
0.976-1.006
0.000
0.977
0.981
15.00 1.000 1234678-HpCDD
1.010
1.014
0.968-1.032
0.000
2,422.01 1.000 13C12-HpCDD 678
13.02 1.010
1.014
0.883-1.117
0.000
0.903
0.912
0.922
0.927
0.954
0.966
0.969
0.975
0.979
0.987
45.33 1.003 OCDF
1.007
1.031
AN
IS7
AN
Triangle Laboratories, Inc.® Analytical Services Division
301 Caprtola Drive • Durham, North Carolina 27713
=>hone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 20:45 07/22/97
42
-------
Page No. 6 Listing of W972829B.dbf
07/22/97 Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Ar ea.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
DC SH 35:30 RO 1.43 3.57 1.038
DC SN 35:42 RO 3.24 1.57 1.044
DC SN 35:49 RO 0.65 3.20 1.047
DC SN 35:55 RO 0.26 1.21 1.050
442-444 1 Peak 80.86
OCDD 0.76-1.02 0.883-1.117
458-460 DC NL 0:00 RO 1.12 3.93 0.000
H 34:12 RO 0.63 31.22 14.70 23.30 1.000 OCDD AH
DC SN 34:38 0.82 5.40 1.013
458-460 1 Peak 31.22
13C12-OCDD 0.76-1.02 0.996-1.005
470-472 DC NL 0:00 0.92 4.38 0.000
34:12 0.91 5,676.46 2.700.01 2,976.45 1.000 13C12-OCDD IS8
470-472 1 Peak 5,676.46
Column Description 'tfcy' Code Description QC Log Desc.
M_Z -Nominal Ion Mass(es) WL-B*low Retention Tine Window A-Peak Added
..RT. -Retention Time (mm:ss) WH-Above Retention Time Window X-Peak Kept
Rat.l -Ratio of M/M+2 Ions SB-Below Signal to Noise Level D-Peak Deleted
OK -RO=Ratio Outside Limits
-------
TiletH972829 #1-758 Acqi22-JVL-1997 13:10:41 GC XI* Voltage SIX 70SX Boi*et3586 ~~~
303.9016 ri2 BSUB(256,30,-3.0) PKS(9,5,5,0 .10\,14344 .0,1.00\,T,T) XxptXPCUS2
TRIASGLS LABS TextiTLI M23 BLAST XLH42299A
100
80
60
40.
20.
0
305
TSIJ
10K
80.
60.
40.
20.
0
Tilt
315.
TSIA
1001
80:
eo:.
40:
20:
0
File
317.
TSIA
1001
80:
60:
40:
20:
o-
rile
30.
TSIA.
1003
so:
60:
40:
20:
o:
1
;
l^wvvml)
37X4 \^^Al.lSi
IwlW^^
[.0015
,
(i.
Al
111
MUlU)
Ca.ii4
•f5*5 A1.51E5 .
fc |j A1.81X5 ^ 49xs IJA1.15S5 1
'.6.5X4
.4.9X4
.3.3X4
.1.6X4
^ 1
17:00 18:00 15(00 20(00 21\00 ' ' ' '22:00 ' Time
HH972829 tl-798 Acqt22-JOL-1997 13:10:41 GC XI + Voltage SIR 70SX Soimei3387
8987 Tt2 BSUB(256,30,-3.0) PTD(9, 5,5,0. 10\,13548.0,1.00\,T,T) XzptXPCUS2
\HGLX LABS TextiTLI M23 BLAST TXJt42299A
C6.5X4
1 A7. 7$JS\
to. 34X4. I. I. I 111]
j&J
4AJIJW«
41.8725 -»|
^MjWIf
.74X6 A9.93X4 A1.07X5 ,
Hilllikli 1 lull 1
nil w Wii ullvU wMUl^ilWwi^i^
17/00 18(00 15(00 20(00 ' 21(00 22(00
KN972825 tl-798 Aoqi22-JVL-1997 13tlO:41 SC XI+ Voltage SIR 70SX Soiae:1290
9419 r>2 BSUB(256,30,-3.0) PTD(9, 5,5,0. 10\r5160. 0,1. 00\,T,T) Xlp:XPCUS2
\SGLX LABS TexttTLI M23 BLAST TLH42299A
A6.74X7
J
\-
17(00 10(00 15:00 20(00 ' ' ' 21(00' ' ' ' 22(00'
:H972629 tl-798 Aoqt22-JOL-1997 13 1 10 1 41 GC XI+ Voltage SIS 70SX Soiae:2932
9389 n2 BSUB(256,30,-3.0) PKD(9,5,S,0 .10\,11728.0,1.00\,T,T) XxpiXPCUS2
HGLX LABS TexttTLI M23 BLAST TLH42299A
AS 89X7
J
17(00 1«(00 15(00 20(00 21(00 22(00
(1072825 tl-798 Acqt22-JOL-1997 13:10:41 GC XH- Voltage SIR 70SX
9792 Pt2 XxpiXPCUS2
HGLX LABS TezttTLI M23 BLAST TLH42299A
16:41 17:26 19i31 J5/5f 20t46 33l°*^
lMrw^rT ^Aywy
•x^
^Y^V^Vv"
n't 00 18:00 19:00 20:00 ' 21(00 ' ' ' 22:00
ilettr972829 tl-798 Acqi22-JUL-1997 13:10:41 GC XH- Voltage SIR 70SX
75.8364 T:2 XxptXPCUS2
TRIASGLX LABS TerttTLI M23 BLASK TLH42299A
001 16 50
80.
60:
40:
o':.
16:33
j*M^
\J\AiAl^Jl\*JjkjWvKJinJi. ' * - *" -*-f
17*00 IBtOO
LJ(*AA*M^^
15(00 2
0(00 21(00 22(00
L5.2Z4
JL3.9X4
1.2.6X4
L1.3X4
Y 0.0X0
Time
-1.4X7
.1.1X7
.8.6X6
.5.7X6
.2.9X6
0.0X0
Time
-1.8X7
'-.1.5X7
.1.1X7
.7.3X6
.3.7X6
0.0X0
Time
.3.0X7
-.2.4X7
'-.1.8X7
.1.2X7
.5.9X6
.0.0X0
Time
.1.1X5
.8.7X4
.6.5X4
.4.4X4
.2.2X4
.0.0X0
Time
44
-------
rilatffS72B29 tl-798 Acqt22-JUL-1997 13tlOi41 GC EH- Voltage SIR 70SS Hoi.**1986
319.8965 rt2 BSUB(256,30, -3.0) TXJ><7,5,3,0.10\,3944.0,1.00\,r,T) XxpiXPCUS2
TXIANGLX LASS TfltsTLI M23 BLASX XUI42299A
1001 A1.44X5
18(00 15t00 20(00 21(00
file(M972825 tl-798 Acqi22-JVL-l»97 13*10t41 GC EI+ Voltage SIS 70SX Sodjmil333
321.8936 Ti2 BSUB(256,30,-3.0) rfD(7,5,3,0.10\,5332.0,1.00\,r,T) EzptXfCUS2
TXIABGLX LABS TaittTLI M23 BLAST XLZH2299A
100$
22100
18(00 15(00 20,00 21:00
tl-798 Acqt22-JVL-1997 13tlOi41 GC XI+ Voltage SIX 70S* Noiaat8841
331.9368 Tt2 BSV3(256,30,-3.0) TXD(7,5,3,0.10\r35364.0,1.00\,T,T) XxpiXfCUS2
TRIAHSZX LABS Text (XL J M23 BLAST ZLH42299A
100$ *5-*W.;
22:00
601
401
20:
.70X7
±
_I.J*7
.1.0X7
'•.7.6X6
'•.5.0X6
'-.2.5X6
0.0X0
18.00 15«00 20(00 21 i 00
MleiH972829 tl-798 Aoqt22-JtJL-1997 13tlOt41 GC EH- Voltay* SIX 70SX Xoi*»t3139
333.9338 ft2 BSUB(256,30,-3.0) TXD(7, 5,3, 0.10\, 12556 .0,1. 00\,T,T) XxptKPCDS2
LABS TertlZLX K23 BLAST XLIH2299A
.22(00
80:
60:
40:
20:
18(00 15(00 20(00 21(00
r±loitf972829 tl-798 Acqi22-JUL-1997 13tlOs41 GC XH- Voltage SIS 70SX Jfo±M»tll55
327.8847 Tt2 BSU3(256,30,-3.0) PXD(7,5,3,0.10\,4620.0,1.00\,r,T) XxptXPCUSa
XXIAHSZX LABS TmrtiTLI H23 BLAXK XLO42299A
1001 A1.06X8
22(00
1.5*7
1.217
9.1X6
6.1X6
3.0X6
.0.0X0
T±M«
ao:
60:
40:
20:
^2.4X7
18(00 15(00 20(00 21(00
F±l»tH972S29 tl-798 Acqt22-JUL-1997 13110141 GC H+ Waltmg* SIX 70SX
330.9792 Tt2 XzptEPCUS2
TKASGLX LABS T«xt(TLX H23 BLAST XLIt42299A
1005
80:
60:
40:
20:
o:
19t31
19156
20(45
22(00
21(27 31.4722(04
.1.5*7
.1.5*7
.9.7X6
.4.9X6
.0.0X9
XiMJ
.3.0X7
.2.4X7
.1.8X7
.1.2X7
.5.9X6
.0.0X0
18(00
15(00
20(00
21100
22(00
45
-------
rJJ.mttf972829 tl-798 Acq,22-JVL-1997 13tlOt41 SC XI+ Voltage SIX 70SX SoifetlSlS
339.8597 Ft2 BSVB(256,30,-3.0) PXD(7,5,3,0.10\,6052.0,1.00\,r,T) XxpiXTCUS2
TXIAHGLX LASS TexttTLI M23 BLANK TLH42299A
lOOSi
22s00 23100 24100 25:00
T±letH372829 #1-758 Actj:22-JUL-1997 13tlOi41 GC XZ+ Voltage SIX 70S* Soime:1448
341.8567 ri2 BSUB(256,30,-3.0) PXD(7,5,3,0.101,5792.0,1.00\,r,T) XrptXPCOS2
TXIAHGLX LABS TexttTLX H23 BLANK TLH42299A
1001
so:
60:
26 tOO
40:
20:
23100 24100 25100
ril«tW972a29 01-798 Acqt22-JOL-1997 13tlOi41 GC XI+ Voltaya SIX 70SX Boi*mtll31
351.9000 Tt2 BSOB(256,30,-3.0) PXD(7,5,3,0.10\,4524.0,1.00\,T,T) ErpiEPCUS2
TRIAHSLX LABS XarttXLI M23 BLAST XLH42399A
1001
80:
60:
40:
20:
oj
AS.93X7
22iOO 23i00 24:00 25,00
•11*1*972829 tl-798 Acqt22-JVL-1997 13tlOt41 GC KI+ Voltage SIX 70SX Ko±f»tll55
353.8970 f:2 BSOB(256,30,-3.0) PXD(7,5,3,0.10\,4620.0,1.00\,r,T) XxptXPCUS2
TXIABGLX LABS TmxttTLI H23 BLANK XLH42299A
26100
1001
80:
60:
40:
20:
0:
A4.00X7
22:00 23:00 24:00
ril»iH972829 tl-798 Acqt22-JVL-1997 13:10:41 GC XI +
30.9792 T:2 Xxp:EPCUS2
TXIARGLX LABS TmrtiTLI M23 BLANK TLI442299A
25:00
SIX 70SX
26100
ao
eo:
40:
20:
o:
22:00 23*00 24:00 25:00
11»:H972829 tl-798 Acqt22-JUL-1997 13:10:41 GC XI + Voltag* SIS 70S*
09.7974 Ti2 XxptXPCUS2
IANGLX LABS TuxttTLI M23 BLANK TLH42299A
00\
26100
22:06
80:
60:
40:
20:
ol
22 tOO
22:38
-J\*.~.A^*Jr*\
22:58
23:00
24100
.0.0X0
Tim
1.8X7
'•.1.5X7
'•.1.1X7
'.7.3X6
.3.6X6
-.0.0X0
Time
-1.2X7
'•.9.3X6
.7.0X6
.4.6X6
.2.3X6
0.0X0
Time
,.3.7X7
-.2.9X7
.2.2X7
.1.5X7
.7.3X6
0.0X0
25100
26:00
46
-------
TlJ.airi971o39 tl-7S8 AcqiJJ-JuL-lyyf J.J:J.O:4J. GC SZ-r vo.icag» SIR /USE
355.8546 T,2 3SUB(256,30r-3.0) PXB(7,5,3,0.10\,481f.O,1.00\,r,T) XrptXPCOS2
XRIANGLX LABS TextiTLJ H23 BLASX TLH42299A
100%
24100 25:00 26'tOO
ttlmtM972829 il-798 Acqt22-JUL-1997 13:10t41 GC XX* VOltMg* SIS 70S* XOi»»ill60
357.8516 ri2 BSUB(256,30,-3.0) PXI>(7,5,3,0.10\,464t.O,1.00\,r,T) KxptKPCUS2
TSIAWSLX LABS TezttXCX JOJ BLANK TLI442299A
100\ Al.f.2fS A1.S6X5
24100 25,00 26', 00
Tila,WS72S39 H-798 Acqt22-Jm,-1997 13,10,41 GC XT* VblCaga SIX 70S* St>im»,947
367.8949 Tt2 BSUB(256,30, -3.0) PXD(7,5,3,0.10\r3788.0,1.00\,r,T) Xxp,EPCUS2
TXIABGHS LASS TmrtiTLI M23 BLAKK TLH42299A
100% A3.24E7
80.
60.
40.
20:
.82E6
24100 25x00 36:00
Tilmtm72829 tl-798 Acqt22-JUL-1997 13:10:41 GC XT* Voltaga 513 70SX yoi*»i967
369.8919 r>2 BSV1>(2S6,30,-3.0) PXD(7,5,3,0.10\e386I.O,1.00\rT,T) SfptSPCUS2
XXIA1KLX LABS TmxtiTLI K23 BZAXX XLH43399A
100% A2*)2X7
801
601
¥0.
20:
o:
.32X6
34:00 35,00
'ilmitl972829 91-798 Aoyi23-JUL-1997 13tlOt41 GC XH- Vtiltmgm SIX 703X
330.9792 r,2 XxptXPCOSS
TXIAOSLX LABS TVftiTLX M23 BLAVX XLH42299A
100%
23,40 ^.nn 24,17 AfV 35.05. 35,31
26,00
60.
40.
20.
0.
-9.4X6
'.7.5X6
.5.6X6
.3. 8X6
.1.9X6
0.0X0
-6.3X6
.5.0X6
.3.8X6
-1.3X6
.0.0X0
Tim,
24100
-3.7X7
.2.9X7
.2.2X7
.1.5X7
.7.3X6
'.0.0X0
25,00
26:00
47
-------
Til»tW972829 U-422 Acq:22-JVL-1997 13:10,41 GC XH- Voltagu SIS 70S! Noit»,3739
373.8208 f,3 BSUB(256,30,-3.0) PXD(7,5,3,0.10\,14956.0,1.00\,T,T) XxptXPCOS2
TRIANGLE LABS TexttTLI M23 BLANK TLI»42299A
1004 A4.J.7X5
-9.1X4
27,00 27112 27124 27,36 27,48 28iOO 33,12 38,24 28,36 28:48 29,00 29,12 29,24 29,36 29,48
rll«,W972829 U-422 Acq:22-JOL-1997 13,10,41 GC XH- Voltayo SIS 70S* Bo±M»,1380
375.8178 r,3 B8UB(2S6,30, -3.0) PXD(7,S,3,0.10\,5520.0,1.00\,T,T) Xxp,XPCUS2
TRIANGLE LABS Taxt.,TLI H23 BLANK TLH42299A
1001 A2.84E5
aol
27,00 27,12 27,24 27:36 27,48 28,00 28,12 28,24 28,36 28,48 29,00 29,12 29,24 29,36 29,48
r±l»,tf972829 U-422 Aoqt22-JUL-1997 13,10,41 SC XH- Voltay* SIX 70SX Nol*»,2753
383.8639 fi3 BSUB(2S6, 30, -3.0) PKD(7,5,3, 0.101,11012.0,1.00\,f,T) XzptXPCUS2
TRIANGLE LABS TmxtlTLI M23 BLANK XLH42299A
100S
30.
«OJ
401
20.
OJ
A3.08X7
A2.70X7
A3.57X7
27,00 27,12 27i24 27,36 27,48 28,00 28,12 38,24 28,36 28:48 29:00 29,12 29:24 29,36 29,48
Tllm,*972829 U-422 Acq,22-JUL-1997 13,10,41 GC XH- Voltagm SIX 70SX XOim*i4449
85.8610 r,3 B3OB(256,30,-3.0) PXD(7,5,3,0.101,17796.0,1.00\,T,T) Kxp,EPCUS2
TRIANGLE LABS T*xt:TLI H23 BLANK TLH4229SA
1001
sol
60:.
40.
o
AS. 36X7
A4.97X7
/ V
27(00 27,12 27,24 27,36 27,48 28,00 28,12 28,24 28,36 28,48 29,00 29,12 29,24 29:36 29:48
r±le,tT972829 U-422 Acq:22-JUL-1997 13:10:41 GC XH- VoltMgu SIR 70SX
92.9760 f,3 XxptXPCOS2
•SIANGLE LABS TmrttTLX M23 BLANK TLII42299A
1004
SO.
SO:
40:
20:
0j
27,00 27,12 27:24 27,36 27,48 28:00 28,12 28,24 28:36 28,48 29:00 29,12 29,24 29,36 29,48
±1»,H972829 U-422 Acq,22-JUL-1997 13:10:41 CC XH- Volt*gm SIX 70SX
45.7555 T,3 Ixp,XPCUS2
TRIANGLE LABS TaxtiTLI M23 BLANK XLH42299A
00
^7.8X4
0.0X0
T±m»
-9.5X6
.7.6X6
.5.7X6
.3.8X6
-.1.9X6
.0.0X0
Time
1.9X7
'•.1.5X7
'-.1.1X7
'•.7.6X6
.3.8X6
0.0X0
Time
1.8X7
^.l74X7
.1.1X7
.7.1X6
.3.6X6 -
0.0X0
27,00 27:12 27,24 27,36 27,48 28:00 28,12 28,24 28,36 28:48 29:00 29Yl2 29V24 "29:36'
0.0X0
Tim*
43
-------
ri-Laiw97j82S tl-422 Acq,22-JuL-1997 13,10,41 SC Sir VolugiB SIX 70SE Noit*>1042
389.8156 n3 BSUB(256,30,-3.0) PKD(7,5,3,0.10\, 4168.0,1.00\,r,I) KzptSfCUS2
TXIANGLX LABS TartiZZJ M23 BLAST TLIt42299A
100* AS. 58X4
A4.18S4
A7.76X4*3'"*4
27:24 27,36 27t48 28,00 28,12 28', 24 28,36 28,48 29', 00 29',12
TJJ.atH972829 tl-422 Aoq,22~JUL-l997 13,10,41 CC X+ Valtmg* SIX 70S! Bo±M»,1962
391.8127 r>3 BSUB(256r30,-3.0) fTD(7,5,3,0.10\f7848.0,1.00\,e,I) Kxp,XPCOS2
OtlAOSLX LABS TfrttTLI M23 BLAST XLII42299A
10M A9.43X4
29124
0.0X0
29,36 T±mt>
27,24 27,36 27', 4 8 28', 00 28', 12 28,24 28>36 28,48 29', 00 29', 12
rU.*tM972829 11-422 Aaj,22-JUL-1997 13,10,41 CC XI+ Voltage SIX 70SX IK>ia»,2219
401.8558 Ti3 B3UB(256,30,-3.0) tXD(7,5r3,0.10\,8876.0,1.00\,rrT) XxptXfCU32
TmxtiTLI H23 BLAST XLH42299A
27,24
TXIAXKLX LABS
1001
80.
60.
40.
20:
AS. 21X7
A4.66X7
29,36 Time
r!.5X7
J..2X7
.9.0X6
.6.0X6
'.3.0X6
27 24 27,36 27,48 29,00 28,12 28,24 28,36 28,48 29,00 29^,12
Til»,M972829 tl-422 Ac?,22-JUL-1997 13,10,41 CC XH- Ifoltmgm SIX 70SX Boil*,1382
403.8529 T,3 BSUB(256,30, -3.0) fKD(7,5,3,0.1Q\rS528.0,l.QO\,T,T) XxptXfCU32
TSIAHGLX LABS TfXtiTU M23 BLAST TL1I42299A
0.0X0
29,24 29,36
1001
80.
60.
20:
o:
A4.03X7
A3.77X7
27 24 27,36 27,48 28,00 28,12 28,24 28,36 28,48 29,00
Tlle,N972829 tl-422 Acq,22-JVL-1997 13,10,41 CC XH- Vtilt*ym SIX 70SX
392.9760 Tt3 XxpiKPOTS2
TXIABCLX LABS TmxttTLI M23 BLAST TLH42299A
100S 27,33 28,46
27,42 27,52 28,03 _ 28,21 . 2St41
..1.2X7
'.9.7X6
'.7.3X6
'.4^.9X6'
'.2.4X6
.0.0X0
29,12 29,24 29,36 ££»•
lo. oro
27,24 27,36 27,48 28,00 28,12 28,24 29,36 28,48 ' '29,00 ' '29,12 ' 29,24 ' '29,36 Time
49
-------
T±le:M972829 #1-440 Acq:22-JOZ-1997 13:10:41 GC XH- Voltagm SIX 70SX yoimm:1894
407.7818 T:4 3803(256,30,-3.0) PXD(7,5,3,0.10\,7576.0,1.00\,T,T) Xrp:XPCUS2
TRIANGLE LASS TrnxHtTLI M23 BLANK XLZI42299A
A4.72X5
30:48 31:00 31:12 31:24 31:36 31:48 32:00 32:12
rJJ.»:M972829 41-440 Acq:22-JVL-1997 13:10:41 GC XH- Voltngm SIX 70SX Soil*, 1762
409.7789 f:4 3303(256,30,-3.0) PXD(7,5,3,0.10\,7048.0,1.00\,r,I) Xxp:XPCOS2
TRIANGLE LABS Taxt:TLI M23 BLANK TLI442299A
100\ A3.90X5
32:24
30:48 31:00 31:12 31:24 31:36 31:48 32:00 32:12
Fila:tfS72829 fl-440 Acqi22-JUL-1997 13:10:41 GC XH- Voltage 3H 70SX Xoiaas2544
417.8253 Ti4 3303(256,30,-3.0) PXD(7,5,3,0.10\,10176.0,1.00\,T,T) Xxp:XPCUS2
TRIANGLE LASS TexttZET M23 BLANK XLH42299A
10 0\ A1.63S7
32:24
80.
60:
40:
201
OJ
A1.07X7
30:48 31:00 31:12 31:24 31:36 31:48 32:00 32:12
f±J.»:M972829 91-440 Acq:22-JUL-1997 13:10:41 GC XH- Voltage SIB 703X X6ima:3502
'19.8220 Ti4 3303(256,30,-3.0) PXD(7,5,3,0.10\r1400a.O,1.00\,T,T) XzptXPCOS2
TSIASGLX LABS Tart:TLI M23 3LABX XLH42299A
1003, A3. $3X7
32:24
80:
60:
40:
201
A2.48X7
30:48 31:00 31:12 31:24 31:36 31:48 32:00
•±la:K972829 tl-440 Aaq:22-JOL-1997 13:10:41 GC XI + Volttgm SIX 703X
30.9729 T:4 Xxp:XPCOS2
IAKSLX LABS TtUCttZLJ M23 BLANK TLI942299A
.001
80:
60:
40:
20:
ol
30:51
31:17
31:29
31:42
31:54
32:12
32:13
32:24
32:24
30:48 31:00 31:12 31:24 31:36 31:48 32:00
±J.»:H972829 91-440 Aoq:22-JUL-1997 13:10:41 GC XX+ Voltmym SIX 708X
79.7165 t:4 Xxp:XPCUS2
'.IAHGLX LASS T«rt>ZLT H23 BLANK XLH42299A
00\ 30:50 31:21
32:12
32:24
32:36
32:36
0.0X0
Time
4.9X6
'•.3.9X6
'•.2.9X6
'•.1.9X6
'-9.7X5
32:36
-.0.0X0
Tim
1.2X7
.9.3X6
.7.0X6
.4.6X6
.2.3X6
32:36
.0.0X0
Time
.1.3X7
-.1.1X7
.8.0X6
.5.3X6
.2. 7X6
32:36
0.0X0
Time
30:48
31:00
31:12
31:24
31:36
31:48
32:00
32:12
32:24
32 36
50
-------
ri-LatH97JS29 tl-440 Acq> 3J-JuIi-lSH7 J.JU.UI4J. sc El-f v(7,5,3,0.10\,5516.0,1.00\,T,T) XxptXKOS2
TXIAHSLX LABS TmxtiTLI M23 3XJJOC TLH42299A
10 0\ A2.08X5
80.
-7.0X4
.5.6X4
.4.2X4
^3.8X4
.1.4X4
.0.0X0
32t06 32112
T±mu
so:
40.
A1.02X5
A4.45S4
A8.22X4
A6.91X4
-7.2X4
.5.8X4
.4.3X4
'.2.9X4
'-1.4X4
31:00 31:06 31:12 31:18 31>24 31:30 31:36 31>42 31:48 31:54 32:00 32:06
r±l»tt!972»29 tl-440 Acq:32-JUL-1997 13:10:41 GC XI+ Vbltag» SIX 70S* Bolm9:4S79
435.8169 n4 3SUB(256,30,-3.0) PXD(7,5,3,0.10\,18316.0,1.00\,f,T) XzpiXPCOS2
TRIAHGLX LA38 TmxtiXLI H23 BLAST TLH42299A
.0.0X0
32tl2
HM»
ion
so:
40.
201
OJ
A3. 56X7
31:00 31:06 31:12 31:18 31:24 31:30 31:36 31:42 31:48 31:54 32s00 32,06
rilf:H972829 tl-440 Aoq:22-JOL-1997 13:10:41 CC XI+ VoltMgm SIX 70SX Jk>if»t5464
437.8140 ft4 3SUB(256,30,-3.0) PXD(7,5,3,0.10\,21856.0,1.00\,T,T) Xxp:fPCUS2
TXIAHSLX LABS TmxttXZ.1 H23 BLAKZ TLIt42299A
100$ A2.42X7
ao:
eo:
40.
20:
32tl2
o:
r7. 7X6
.6.2X6
'.4.6X6
-3.1X6
'.1.5X6
.0.0X0
Urn*
-7.4X6
.5.9X6
.4.4X6
.1.5X6
0.0X0
ZtMJ
31:00 31:06 31:12 31:18 31:24 31:30 31:36 31:42 31:48 31:54 32tOO 32:06 32:12
r±l»:W973829 tl-440 Acq:22-JUL-1997 13:10t41 CC XH- VOlt*g» SIX 70sr
430.9729 f:4 Xxp*XPCO92
TSIAJKLX LA3S TmrtilLI K23 BLAST TLIt42299A
lOOi, ,,.„, J1.J7 31,29 _ 31t42 31tS4 . ^ 32,13^1.3X7
80.
60.
40.
20.
0.
31i07
31:00 31:06 31:12 31:18 '31:24 '31:30 3l':36 '31:42 '31:48 '31:54 '33\00 '32: 06 '32:12
.1.1X7
'.8.0X6
.5.3X6
.2. 7X6
0.0X0
Tim*
51
-------
rilm:rt7282$ M.-440 Acq:22-JUL-l997 13,16,41 GC EH- Voltage SIS 70SX
441.7428 T:4 BSUB(256,30,-3.0) PKD(7,5,3,0.10\,5036.0,1.00\,r,T) XxptXPCUS2
TRIANGLE LASS T*xt:XLI M23 BLANK XLH42299A
1001 A3.55X5
31', 00 32:00 33:00 34:00 35tOO
T±l«:m72829 tl-440 Aoq:22-JVL-1997 13tlOi41 GC XI+ Voltage SIX 70SX Boil*11371
443.7399 f:4 aSUB(2S6,30,-3.0) PB>(7,5,3,0.101,5484.0,1.00\,T,T) SrptXPCUS2
TXIASCLX LABS TtxttTLI M23 BLANK XLH42299A
10IA A4.53X5
31', 00 32:00 33:00 34:00
f±l«:H972829 tl-440 Aoq:22-JUL-1997 13:10:41 GC fl+ Volt»g» SIX 70S*
430.9729 T:4 XzptZPCDS2
XSIAHSLJS LABS Text»ITJ M23 BLANK XLH42299A
33:48 34,17
.. 33,1-S 32:57
30:51 31tl7
35:00
31:00 32:00 33:00 34:00
r±l»:H972829 tl-440 Aoq:22-JUL-1997 13:10:41 GC XI+ Volt*g* SIX 70S!
513.6775 T:4 XxptXPCOS2
TRIANSLX LABS TartfXCX H23 BLAKK TLH42299A
35:00
0.0X0
36 00 Time
36 00
36 00
31:00
32:00
33:00
34:00
35:00
0.0X0
36:00 T±M»
-------
457.7377 T,4 BSU3(256,30, -3.0) Pa>(7,5,3,0.10\,4640.0,1.00\,T,T) XxpigfCVS2
TXIASGLX LASS TmxtiXZI M23 BLANK XLI442299A
1001 A2.50X5
80.
SO.
40.
20.
AS. 79X4
A2.43X4
7.1X4
.5.7X4
.4.3X4
.2.8X4
.1.4X4
0.0X0
34t06 34112 34,18 34t24 34,30 34*36
ril»,tf972829 41-440 Acqt22-JVL-1997 13tlOt41 GC XH- Volt*gm SIX 70SX Boi**il»42
459.7348 Ti4 B3U3(256,30,-3.0) tX3>(7,5,3,0.10\,4168.0,1.00\,T,T) XxptXPOJSS
TXIAHGLX LAMS TmxtiTLI M33 SLAJOf TLIt42299A
100$ A3.73XS
80.
SO.
40.
20:
34,42
-8.9X4
.7.1X4
.5.3X4
.3.6X4
1.8X4
34t06 34tl3 34>18 34i24 34,30 34,36
rllfitr972829 fl-440 Aoqt22-JVZ-1997 13,10,41 SC XH- Volttg* SIX 703X Hoi*»tU51
469.7779 r,4 BSOB(256,30,-3.0) rXD(7,5,3r0.10\,4204.0,1.00\,r,X) XxptXPCUS2
TXIAIKLX LABS TfxttTLI M23 BLANK XLII42299A
1001 AS.',
34,06 34,12 34,18 34', 24 34', 30 34',36
r±J.»,H972829 41-440 Aoq:22-JVL-1997 13,10,41 GC XH- Voltage SIX 70SX *o±*9,1140
471.7750 Tt4 BSUS(256,30, -3.0) PXD(7,5,3,0.10\,4S60.0,1.00\,r,T) XxptXPOJS2
- LASS TmxtsTLI M23 BLANJC XX.H42299A - •-
ion
34,06 34,12 34,18 34',24 34', 30
ril*,H972829 41-440 Acqt22-JBL-1997 13,10,41 GC XH- Vbltag* SIX 70SX
430.9729 T,4 XxpiXfCUS2
TSIAWSLX LASS TmxtiTLI H33 3XJUOC XLI442399A
1001
80.
60.
40.
20:
0.
34,36
34,42
0.0X0
Urn
..5.9X6
.4.7X6
.3.5X6
.2.4X6
'.1.2X6
.0.0X0
34t42 Z±m»
-.6.5X6
.5.2X6
'.3.9X6
.1.3X6
0.0X0
34142
Urn.
34,06
34,12
34,18
34,24
-1.4X7
'.1.1X7
.8.5X6
.5.7X6
'.2.8X6
34,30
34,36
.0.0X0
34', 42 Time
53
-------
10
Peak Locate Examination:22-JUL-1997:13:09 File:W972829
Experiment:EPCUS2 Function:2 Reference:PFK
-------
File:W972829 #1-422 Acq:22-JUL-1997 13:10:41 GC EI+ Voltage SIR 70SE
373.8208 F:3 Exp:EPCUS2
Sample Text:TLI M23 BLANK TLI#42299A File Text:TRIANGLE LABORATORIES,
lOOi A2.53E5
80 j
60 j
40 J
20 j
OJ
in
kO
INC .
DB5 :
27:00 27:12 27:24 27:36 27:48 28:00 28:12 28:24 28:36 28:48 29
File:W972829 ttl-422 Acq:22-JUL-1997 13:10:41 GC EI+ Voltage SIR 70SE
375.8178 F:3 Exp:EPCUS2
Sample Text:TLI M23 BLANK TLI#42299A File Text:TRIANGLE LABORATORIES, INC.::
100% A2.47E5
80.
40_:
20.
OJ
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DBS: :
29:00 29:12
27:00 27:12 27:24 27:36 27:48 28:00 28:12 28:24 28:36 28:48
File:W972829 #1-422 Acq:22-JUL-1997 13:10:41 GC EH- Voltage SIR 70SE
383.8639 F:3 Exp:EPCUS2
Sample Text:TLI M23 BLANK TLI#42299A File Text:TRIANGLE LABORATORIES, INC.:: DBS::
100% 28:08 28:40
80J
601
40J
20
OJ
.1.0E5
.8.2E4
.6.1E4
.4.1E4
.2.0E4
.O.OEO
Time
.9.3E4
.7.5E4
.5.6E4
.3.7E4
.1.9E4
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27:00 27:12 27:24 27:36 27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12
.9.5E6
.7.6E6
.5.7E6
.3.8E6
.1.9E6
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Time
-------
CD
10
File:W972S29 #1-440 Acq:22-JUL-1997 13:10:41 GC EI+ Voltage SIR 70SE
423.7766 F:4 Exp:EPCUS2
Sample Text:TLI M23 BLANK TLI#42299A File Text:TRIANGLE LABORATORIES, INC.:: DBS::
100% A1.7^9E5
80
60J
40
20J
0
T—i—|—i—i—i—i—i—|—P—i—i—i—i—[~i—i—i—i—i—|—i—P—r—i—i—i—i—i—i—i—i—i—n—i—i—TT—i—i—i—i—i—i—i—i—i—i—i—i—i—r—i—i—i—i—i—i—i—i r |—i—n—i—i—I i i—i—i—r—i—i—i—r
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File:W972829 #1-440 Acq:22-JUL-1997 13:10:41 GC EI+ Voltage SIR 70SE
425.7737 F:4 Exp:EPCUS2
Sample Text:TLI M23 BLANK TLI#42299A File Text:TRIANGLE LABORATORIES, INC.:: DBS::
100% A1.50E5
80 j
60 j
401
201
OJ
.8.4E4
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.3.3E4
.1.7E4
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30:36 30:48 31:00 31:12 31:24 31:36 31:48 32:00 32:12 32:24 32:36 32:48 33:00 33:12
File:W972829 #1-440 Acq:22-JUL-1997 13:10:41 GC EI+ Voltage SIR 70SE
435.8169 F:4 Exp:EPCUS2
Sample Text:TLI M23 BLANK TLI#42299A File Text:TRIANGLE LABORATORIES, INC.:: DBS::
100% 31;45
80J
60J
40 j
20
OJ
30:36 30:48 31:00 31:12 31:24 31:36 31:48 32:00 32:12 32:24 32:36 32:48 33:00 33:12
O.OEO
Time
.7.7E6
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.1.5E6
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Time
-------
File:W972829 #1-440 Acq:22-JUL-1997 13:10:41 GC EI+ Voltage SIR 70SE
457.7377 F:4 Exp:EPCUS2
Sample TextrTLI M23 BLANK TLI#42299A File Text:TRIANGLE LABORATORIES, I
100% A1.47E5
80J
60J
40J
20J
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LO
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DBS : t
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33:24 33:36 33:48 34:00 34:12 34:24 34:36 34:48 35:00
File:W972829 #1-440 Acq:22-JUL-1997 13:10:41 GC EI+ Voltage SIR 70SE
459.7348 F:4 Exp:EPCUS2
Sample Text:TLI M23 BLANK TLI#42299A File Text:TRIANGLE LABORATORIES, I
_8.5E4
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L3.4E4
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35:12 35:24
Time
NC.:: DBS
100%
801
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T — i — i — i — i — r — i — i — i — i — i — r— i
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34:36 34:48 35:00
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14.1E4
L2.1E4
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35:12 35:24
Time
File:W972829 #1-440 Acq:22-JUL-1997 13:10:41 GC EI+ Voltage SIR 70SE
471.7750 F:4 Exp:EPCUS2
Sample Text:TLI M23 BLANK TLI#42299A File Text:TRIANGLE LABORATORIES, I
100% 34 ;.12
80J
60 j
40
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Time
-------
00
10
File:W972829 #1-440 Acq:22-JUL-1997 13:10:41 GC EI+ Voltage SIR 70SE
407.7818 F:4 Exp:ErCUS2
Sample Text:TLI M23 BLANK TLI#42299A File Text:TRIANGLE LABORATORIES,
100% A4.62E5
80J
60 j
40J
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SIC. : : DBS : :
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L1.2E5
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T—I I I—I 1—I—I—I—I—i—I—I—i—I—I—i—I—1—i—i—I—i—r—I—i—i—I—i—i—I—i—i—i—i—i—1—i—i—i—I—i—I—i—i—I—i—I—1—i—i—i—i—I—1—r—r—T-
30:24 30:36 30:48 31:00 31:12 31:24 31:36 31:48 32:00 32:12
File:W972829 #1-440 Acq:22-JUL-1997 13:10:41 GC EI+ Voltage SIR 70SE
409.7789 F:4 Exp:EPCUS2
Sample Text:TLI M23 BLANK TLI#42299A File Text:TRIANGLE LABORATORIES,
100* A3.58E5
801
60 J
40J
20 j
OJ
T — i — i — i — i
32:24
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File:W972829 #1-440 Acq:22-JUL-1997 13:10:41 GC EI+ Voltage SIR 70SE
417.8253 F:4 Exp:EPCUS2
Sample Text:TLI M23 BLANK TLI#42299A File Text:TRIANGLE LABORATORIES,
100% 30:53
32:24
32:36
INC.:: DBS::
80j
60 J
40 j
20J
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L2.9E6
L1.9E6
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Time
i — i— T
32:48
-------
TLI Project:
Client Sample:
42299A
M23-Outlet-Run
Method 23 PCDD/PCDF Analysis (a)
Analysis File: W972831
Client Project:
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
Iron & Steel-Chicago
M23TRAIN Date Received:
173-61-1ABCE Date Extracted:
Date Analyzed:
1.000
n/a
DB-5
Dilution Factor:
Blank File:
Analyst:
07/01797
07/17/97
07/22/97
n/a
W972829
MM
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPX23704
WF54307
W972828
n/a
n/a
n/a
Anafytes
2,3,7,8-TCDD
1,2,3,7,8-PeCDD
1,2,3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
1,2,3,4,6,7,8-HpCDD
1,2,3,4,6,7,8,9-OCDD
2,3,7,8-TCDF
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
1,2,3,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
1,2,3,4,6,7,8,9-OCDF
Totals
Total TCDD
1 Ouli rG\_,DD
Total HxCDD
Total HpCDD
Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF
. . x *mt &s> , JK . „; ;iBipa - . x; a~ i
0.08
0.21
0.04
0.94
0.48
1.1
0.83
3.9
0.59
0.56
0.67
0.25
0.23
EMPC 0.02
0.37
0.05
0.16
Amt (ng) Number Dt BrtPC
0.93 12 1.0
.3 T r.6
8.2 6 8.3
2.5 2
31.1 14
6.2 13 6.3
2.8 10 2.9 -
0.42 2 0.63
v;fc*fe „
0.87
1.56
1.37
1 22
A .4t4r
1.14
1 11
JL .X J.
1.02
0.77
1.54
1.64
127
125
1.34
1 15
A*U
1 15
A* JL.J
097
\j,y 1
icr
20:48
25:31
28:50
9^-55
29:13
-1-1. AQ
34:14
19:59
24:23
25:08
28:03
28:11
28:43
30-56
J\J*J\J
32-OX
J±*,\J{J
34-20
J*T.^-W
Rags
^^^^~
ftegs
^
—
—
^
SLr
Page 1 of 2
X237.PSR vlOO. LARS 6.10.03
Triangle Laboratories, lnc.»
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 20:48 07/22/97
59
-------
TLI Project: 42299A
Client Sample: M23-Outlet-Run
Method 23 PCDD/PCDF Analysis (a)
Analysis File: W972831
internal Standards -•
13C,2-2,3,7,8-TCDF
13Ci2-2,3,7,8-TCDD
13C,2-12,3,7,8-PeCDF
13C,2-l,2,3,7,8-PeCDD
I3Ci2-12,3,6,7,8-HxCDF
13C12-l,2,3,6,7,8-HxCDD
13C,2-l,2,3A6,7,8-HpCDF
13C12-l,2,3A6,7,8-HpCDD
13d2-l,2,3,4,6,7,8,9-OCDD
; Surrogate Standards {Type A)
37Cl4-2,3,7,8-TCDD
13C,2-2,3,4,7,8-PeCDF
I3Ci2-l,2,3,4,7,8-HxCDF
l3Cp-l,2,3,4,7,8-HxCDD
13C12-l,2,3,4,7,8,9-HpCDF
Alternate Standards
13C,2-l,2,3,7,8,9-HxCDF
I3Ci2-2,3,4,6,7,8-HxCDF
Recovery Standards
13Ci2-l,2,3,4-TCDD
13C,2-l,2,3,7,8,9-HxCDD
Amtc (noj
3.7
4.0
3.9
3.9
3.3
33
32
3.0
32
Amt (no.)
3.9
3.9
4.4
2.8
3.8
Amt (n§>
3.6
3.8
%R*wwHY
91.6
98.8
98.4
98.0
825
83.7
80.5
750
39.9
% Recovery
98.1
98.6
109
693
947
%8*x«$£
90.4
94.6
QC Limits
40%-130%
40%-130%
40%- 130%
40%-130%
40%-130%
40%-130%
25%-130%
25%-130%
25%-130%
QC Limits
70%-140%
70%- 140%
70%- 140%
70%- 140%
70%- 140%
ikQC^iftiite
40%- 130%
40%-130%
Ratio
0.76
0.79
1.49
1.43
053
1.24
0.44
107
087
Ratfo
1.51
0.50
1 24
042
Ratio
0.51
0.50
Ratio
0.81
1.23
4^fr^l|IH^L
19:57
20:47
24:23
25:30
28- 11
28:54
30:55
31-47
34-14
JHtt -'ff~& ''''¥*£ A£t&
20:48
25:08
28:04
2X-50 V <£L
32-Q7
UT " Fteg*-|
29:25
28:42
8T 7- Ffags
20:33
29:12
Data Reviewer
07/22/97
Page 2 of 2
X237.PS* TMO. LARS 6.10.0J
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 20:48 07/22/97
60
-------
TLI Project: 42299A
Client Sample: M23-Outlet-Run 1
Toxicity Equivalents Report
Analysis File: W972831
Client Project:
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
Iron & Steel-Chicago
M23TRAIN
173-61-1ABCE
1.000
n/a
DB-5
Date Received:
Date Extracted:
Date Analyzed:
Dilution Factor:
Blank File:
Analyst:
07/01/97
07/17/97
07/22/97
n/a
W972829
MM
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPX23704
WF54307
W972828
n/a
n/a
n/a
Analytes
2,3,7,8-TCDD
1,2,3,7,8-PeCDD
1,2,3,4,7.8-HxCDD
1,2,3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
1,2,3,4,6,7,8-HpCDD
1,2,3,4,6,7,8,9-OCDD
TOTAL PCDD
2,3,7,8-TCDF
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,7,8.9-HxCDF
1,2,3,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
1,2,3,4,6,7,8,9-OCDF
TOTAL PCDF
Amt(ng)
0.08
0.21
0.04
0.94
0.48
1.1
0.83
1.1
0.59
0.56
0.67
0.25
0.23
[0.02]
0.37
0.05
0.16
Total EPA
X
X
X
X
X
X
X
X
X »
X
X
X
X
X
X
X
X
TEFs,
TEF
1
0.5
0.1
0.1
0.1
0.01
0.001
0.1
0.05 r =
,0.5
o.i • =
0.1
0.1
0.1
0.01
0.01
0.001
1989a: 0.884 ng
Equivalent
0.08
0.105
0.004
0.094
0.048
0.011
0.00083
0.343
0.11
0.0295
0.28
0.067
0.025
0.023
0.002
0.0037
0.0005
0.00016
0.541
[...] indicates that the value is that of an EMPC.
Page 1 of 1
TEFPRv5.ll.LARS6.IO.IUc
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Added Paae
Printed: 19:2009/18/97
-------
Initial
...Date.
Daca Review By:
Calculated Noise Area: 10/00
The Total Area for each peak with an ion abundance ratio outside
ratio limits has been recalculated according to method requirements.
Page No.
07/22/97
Compound/
M_Z QC.
TCDF
304-306
304-306
13C12-TCDF
316-318
316-318
TCDD
320-322
M
1 Listing
Matched
.Log Omit Why . .RT. OK
0.
DC NL 0:00
17:01
17:13
17:43
17:54
18:23
18:42
19:06
19:29
19:45
19:59
20:27
20:41
20:58
21:55
14 Peaks
0.
DC NL 0:00 RO
DC WL 17:21 RO
DC WL 18:41
19:57
20:27
2 Peaks
0.
DC NL 0:00
17:50
DC SN 18:03 RO
18:17
18:35
DC SN 19:05 RO
19:27
19:52
20:10
20:31
20:41
20:48
20:58
21:10 RO
21:24
of W972831B.
GC Peaks / F
Ratio Total.
65-0.89
0.76
0.32 5
0.79 3
0.78 25
0.78 21
0.77 24
0.76 18
0.77 26
0.77 13
0.76 10
0.77 24
0.77 9
0.78 6
0.76
0.70
191
65-0.89
5.20
2.18
0.79
0.76 19
0.82
19
65-0.89
0.82
0.69
0.48
0.82
0.76
0.91
0.74
0.71
0.74
0.82
0.73
0.87
0.79
0.93
0.87
dbf
Latio /
Area. . .
95.14
,224.76
,760.90
,744.60
.448.21
,393.20
, 549 . 12
,907.30
,787.73
,134.95
,159.60
,729.21
,366.00
844.84
492.34
, 542 . 76
12.35
29.31
144.42
,038.71
266.13
,304.84
TCDF /
11.40
516.95
10.94
323.69
325.45
6.37
713.34
600.00
326.07
415.23
410.14
360.44
155.74
347.57
131.32
Ret. Time
Area. Peak. 1. .
2,348.26
1,663.41
11,262.00
9,403.91
10,580.40
7,998.02
11,677.80
6,003.77
4.378.11
10,481.70
4,233.06
2,792.83
363.89
202.67
8,215.71
119.57
TCDD Follows ~
210.66
145.41
140.60
303.02
249 . 00
138.87
187.27
172.54
168.17
68.68
182.26
61.14
Area. Peak. 2. . Rel.RT Compound . Name .. ID.. Flags.
0.819-1.109
0.000
2,876.50 0.853
2,097.49 0.863
14,482.60 0.888
12,044.30 0.897
13,812.80 0.921
10,551.10 0.937
15,229.50 0.957
7,783.96 0.977
5,756.84 0.990
13,677.90 1.002 2378-TCDF AN
5,496.15 1.025
3,573.17 1.037
480.95 1.051
289.67 1.099
0.950-1.050
0.000
0.870
0.937
10,823.00 1.000 13C12-2378-TCDF ISO
146.56 1.025
0.849-1.064
0.000
306.29 0.858
0.868
178.28 0.880
184.85 0.894
0.918
410.32 0.936
351.00 0.956
187.20 0.970
227.96 0.987
237.60 0.995
192.27 1.001 2378-TCDD AN
87.06 1.009
196.37 1.018
70.18 1.030
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 20:48 07/22/97
61
-------
Page No. 2
07/22/97
Compound/
M_Z... . QC.Log Omic Why
Listing of W972831B.dbf
Matched GC Peaks / Ratio / Ret. Time
.RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
320-322
37C1-TCDD
328
328
13C12-TCDD
332-334
332-334
PeCDF
340-342
A
A
M
340-342
DC SN 21:37
21:55
DC WH 22:12
13 Peaks
DC NL 0:00
DC WL 17:49
19:13
20:48
21:02
21:15
4 Peaks
DC NL 0:00
19:27
20:33
20:47
21:10
DC SN 21:58
DC SN 22:04
DC SN 22:09
4 Peaks
DC NL 0:00
22:15
DC SN 22:25
DC SN 22:35
DC SN 22:46
23:19
23:29
23:40
23:50
24:07
24:20
24:23
24:33
24:40
25:08
25:16
25:36
DC SN 25:48
DC SN 25:51
26:08
DC WH 26:28
14 Peaks
RO
RO
0.
RO
RO
RO
RO
RO
RO
2.34
0.81
1.40
65-0.89
2.20
0.42
0.81
0.79
0.93
0.63
1.07
4.06
13
163
7
4,789
4
5
24
14,591
34
420
15,070
16
30
14,733
15,297
232
20
16
8
.59
.14
.24
.08
.00
.08
.34
.10
.42
.09
.45
.05
.60
.50
.17
.05
.71
.87
.80
30,293.32
ftVtMVA . ivnn /
i.
RO
RO
RO
RO
RO
RO
32-1.78
1.73
1.44
0.26
1.65
1.02
1.64
1.49
1.54
1.52
1.51
1.45
1.54
1.53
1.51
1.64
1.52
2.39
0.26
2.89
1.64
3.30
9
984
9
14
13
768
10,177
624
621
698
825
2,471
1,568
2,378
.48
.28
.54
.90
.16
.98
.39
.83
.00
.27
.00
.00
.64
.81
72
24
14,591
34
420
13
6,599
6,736
121
.78
.84
.10
.42
.09
.31
.93
.81
.90
90
31
8,133
8,560
131
.36
0.
0.
.57
.57
.36
.10
1.
1.
1.
903-
0.
0.
0.
1.
1.
1.
040
055
068
1.097
000
857
925
001 37C1-TCDD SOR1
012
022
903-1.097
0.
0.
0.
1.
1.
1.
1.
1.
000
936
989 13C12-1234-TCDD RSI
000 13C12-2378-TCDD IS1
018
057
062
066
580
478
6,093
378
375
420
488
1,500
948
1,430
.26
.22
.07
.84
.00
.10
.00
.00
.39
.08
. 2.312-37 1.435.09
2.146
167
5
7
205
5
25,950
.09
.97
.61
.11
.38
.02
.01
1,295
157
127
.56
.54
.69
404
290
4.084
245
246
278
337
971
620
948
0.
.02
.76
.32
.99
.00
.17
.00
.00
.25
.73
904-
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
1.
1.
877. 2S L.
850
65
77
.53
.87
.69
1.
1.
1.
1.
1.
1.
1.081
000
913
919
926
934
956
963
971
977 ....... . _ _ .
989
998
000 12378-PeCDF AN
007
012
031, ,234-7^-peCDP , , AH
036
050
058
060
072
085
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 20:48 07/22/97
62
-------
Page No. 3 Listing
07/22/97 Matched
Compound/
M_Z.... QC.Log Omit Why . .RT. OK
13C12-PeCDF 1
352-354 DC NL 0:00
23:25
24:23
24:32
24:40
25:08
26:08
352-354 6 Peaks
PeCDD
356-358 DC NL 0:00
DC SN 23:26
23:39
DC SN 23:54
DC SN 24:13
24:23
24:32
24:42
24:52
24:59
25:12
A 25:18
25:31
25:40
26:00
DC WH 26:12
DC WH 26:23
356-358 11 Peaks
13C12-PeCDD
368-370 DC NL 0:00
DC SN 23:28
DC SN 24:11
24:32
DC SN 24:55
DC SN 25:15
25:30
25:38
368-370 3 Peaks
HxCDF
374-376 DC NL 0:00
27:05
27:13
27:22
27:31
27:42
RO
RO
RO
RO
1.
RO
RO
RO
RO
RO
RO
RO
RO
RO
1.
RO
RO
RO
RO
RO
1.
RO
of W972831B.dbf
GC Peaks / Ratio
Ratio Total. Area
.32-1.78
1
1
1
2
1
1
1
.10
.07
.49 14
.63
.98
.51 13
.40
28
4
33
.738
88
166
.450
40
.519
/ Ret. Time
... Area. Peak.
.74
.51
.92
.84
.90
.72
.23
.12
20
8,818
91
129
8.082
23
1. . Area. Peak.
.37
.59
.77
.54
.66
.46
18
5,920
34
65
5,368
16
2. .
0.
.97
.33
.84
.45
.06
.77
Rel.RT Compound. Name. . ID.. Flags.
835-1.165
0
0
1
1
1
1
1
.000
.960
.000 13C12-PeCDF 123 IS2
.006
.012
.031 13C12-PeCDF 234 SUR2
.072
BAS*nv l i>AS*nn v**l l *.,.,*,
,32-1.78
0
0
1
0
1
1
1
1
1
1
0
0,
1
1.
1.
2,
1,
.62
.70
.62
.32
.88
.56
.45
.47
.52
.95
.96
.64
.56
.50
.11
.25
.37
4,
3
.16
0.
11.29
439.31
7,
20,
.11
.58
988.59
618.
449.
266.
.16
.33
.13
355.19
58.
27.
,37
,80
556.64
231.
17
131.09
11.
12
271
601
366
267
160
271
35
16
339
138
79
.85
.68
.19
.48
.67
.60
.48
.90
.07
.79
.68
167
386
251
181
105
139
36,
26
217.
92.
71.
.96
.91
.97
.85
.46
.29
.80
.60
.57
.38
.71
5.63
122.
28
32-1.78
0.
2.
0.
1.
1.
0.
1.
1.
,88
,34
,22
,13
66
64
43 7,
58
8,
ft WMVM . V
3.
11.
2.
25.
14.
19.
781.
773.
581.
52
93
39
70
90
08
98
39
07
15.
4,573.
473.
.62
.49
.83
13.
3,208.
299 .
918-1.027
0
0
0
0
0
0
.000
.919
.927
.937
.950
.956
0.962
0,
0.
0.
0.
0.
1.
1.
1.
1.
1.
.969
.975
.980
.988
.992
,001 12378-PeCDD AN
007
020
027
035
0.843-1.157
82
49
56
0.
0.
0.
0.
0.
0.
1.
1.
000
920
948
962
977
990
000 13C12-P6CDD 123 IS3
005
i—j^r\r\ / tSud'vnY* w— 1 i _._._
05-1.43
0.
1.
1.
1.
1.
1.
80
32
22 2,
43
30
20
23.
549.
422.
177.
232.
355.
05
57
24
21
02
69
312.
1,332.
104.
131.
193.
88
69
20
17
71
236.
1,089.
73.
100.
161.
0.956-1.053
69
55
01
85
98
0.
0.
0.
0.
0.
0.
000
961
966
971
976
983
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 20:48 07/22/97
63
-------
Page No.
07 22/97
Listing of W972831B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_3.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound. Name. . ID.. Flags.
N 28:03
28:11
28:17
28:30
A 28:36
M 28:43
DC SN 28:53
AN 29:25
M 29:30
DC SN 29:37
374-376 13 Peaks
13C12-HXCDF
384-336 DC NL 0:00
27:04
27:11
DC SN 27:35
DC SN 27:48
28:04
28:11
28:20
28:42
28:53
DC SN 28:56
DC SN 29:02
DC SN 29:14
29:25
29:41
384-386 9 Peaks
HxCDD
390-392 DC NL 0:00
27:37
28:05
28:18
A 28:26
AN 28:50
M 28:55
29:13
DC WH 29:21
1.27
1.25
RO
0.
87
1.34
RO
RO
RO
RO
0.
RO
RO
RO
RO
RO
RO
RO
1.
RO
RO
RO
TV WH 79-17 RO
390-392 7 Peaks
13C12-HXCDD
402-404 DC NL 0:00
DC WL 27:26
DC WL 27:39
DC WL 27:44
DC SN 27:56
DC SN 28:04
1.
RO
RO
RO
RO
RO
RO
1.
1.
0.
1.
1.
0.
15
34
85
65
01
30
1,620.71
822.37
117
279
.62
.57
88.90
521,
.00
908.
457.
65.
159.
47.
293.
,12
27
,11
36
60
00
712.
365.
74.
119.
41.
223.
59
10
91
71
30
00
7.64
45.47
107.
.48
33.
59.
40
50
20.
59.
30
00
9.48
7,339.
.35
43-0.59
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
05-
0.
1.
1.
1.
1.
1.
1.
1.
1.
0.
14
59
70
90
50
50
53
87
50
97
48
27
57
51
70
1.43
93
21
19
21
52
37
22
14
79
61
11.
53.
41.
6.
7.
8,639.
8,707.
47.
8,045.
42.
30.
22.
17.
6,609.
36.
32,224.
• SJVf^nE
,29
,98
.74
.33
27
24
.32
,32
89
91
63
36
81
76
19
35
» t Uu
20.
19.
2,888.
3,010.
27.
2,685.
27.
2,231.
16.
07
32
43
68
23
69
59
25
34
33.
27.
5,750.
5,696.
31.
5,360.
23.
4,378.
23.
0.
91
64
81
64
34
20
42
51
97
0.
1.
1.
1.
1.
1.
1.
1.
1.
1.
995 123478-HxCDF AN
000 123678-HxCDF AN
004
Oil
015
019 234678-HxCDF AN
025
044 123789-HxCDF AN
047
051
858-1.142
0.
0.
0.
0.
0.
0.
1.
1.
1.
1.
1.
1.
1.
1.
1.
000
960
965
979
986
996 13C12-HXCDF 478 SUR3
000 13C12-HXCDF 678 IS4
005
018 13C12-HXCDF 234 ALT2
025
027
030
037
044 13C12-HXCDF 789 ALT1
053
i««« •Of*^ i ,».._».
16.
1,766.
292.
8,689.
100.
60.
1,680.
751.
15.
5
13,339.
17
05
74
50
13
10
00
23
57
17
75
966.
159.
4,762.
68.
34.
923.
400.
42
05
59
10
70
00
71
799.
133.
3,926.
44.
25.
757.
350.
0.949-
63
69
91
70
40
00
52
0.
0.
0.
0.
0.
0.
1.
1.
1.
1.015
000
956
972
979 _
984
998 123478-H3CTDD AN
001 123678-HXCDD AN
Oil 123789-HxCDD AN
016
,,., , 1.025
05-1.43
3.
0.
0.
0.
0.
0.
90
93
94
75
60
23
3.
6.
3.
8.
5.
2.
76
61
34
27
00
82
0.965-
0.
0.
0.
0.
0.
0.
1.035
000
949
957
960
967
971
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 20:48 07/22/97
64
-------
Page No. 5
07/22/97
Compound/
M_Z.... QC.Log Omit Why
Listing of W972831B.dbf
Matched GC Peaks / Ratio
/ Rat. Time
.RT. OK Ratio Total.Area... Area.Peak. 1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
402-404
HpCDF
408-410
M
M
408-410
13C12-HpCDF
418-420
418-420
28:17 1.41
DC SN 28:38 RO 1.67
28:50 1.24 3,
28:54 1.24 6,
29:12 1.23 7,
29:25 RO 1.82
DC SN 29:31 RO 3.27
DC SN 29:35 RO 4.37
5 Peaks 17,
— — — &Ho\n» - V
0.88-1.20
DC NL 0:00 RO 1.99
30:56 1.15
31:09 RO 1.31
31:16 RO 1.30
DC SN 31:33 RO 0.54
32:08 1.15
DC WH 32:34 RO 1.57
4 Peaks 1,
0.37-0.51
DC NL 0:00 RO 1.17
30:55 0.44 4,
DC SN 31:17 RO 0.65
32:07 0.42 3,
2 Peaks 8,
32.38 18.95
7.84
948.28 2,183.17
373.64 3,528.54
050.01 3.891.84
48.:>6 39.56
13.19
3.33
452.87
hrf nn / WnPTTP Pol 1 owe
ix\~uu 1 np\-L>c c oxbows ~
10.44
667.00 357.00
114.46 73.36
221.63 141.10
6.67
69.50 37.10
5.67
072.59
13.45
920.62 1,503.86
15.29
424.98 1,005.38
345.60
13.43 0.979
0.991
1,765.11 0.998 13C12-HXCDD 478
2,845.10 1.000 13C12-HXCDD 678
3,158.17 1.010 13C12-HXCDD 789
21.68 1.018
1.021
1.024
0.996-1.045
0.000
310.00 1.001 1234678-HpCDF
56.11 1.008
108.64 1.011
1.020
32.40 1.039 1234789-HpCDF
1.053
0.935-1.130
0.000
3,416.76 1.000 13C12-HpCDF 678
1.012
2,419.10 1.039 13C12-HpCDF 789
SCR4
IS5
RS2
AN
AN
IS6
SDR5
HpCDD
424-426
424-426
13C12-HpCDD
436-438
436-438
OCDF
442-444
0.88-1.20
DC NL 0:00 1.11
31:11 1.09 1,
31:48 1.11 1,
DC WH 32:10 RO 0.24
2 Peaks 2,
0.88-1.20
DC NL 0:00 RO 1.65
DC SN 31:03 RO 0.41
DC SN 31:09 RO 0.39
31-47 1 . 0"? -- , ?,
32:00 RO 1.37
DC SN 32:08 RO 0.72
DC SN 32:14 RO 0.68
2 Peaks 3,
&Vviva • U
0.76-1.02
DC NL 0:00 RO 1.70
4.31
437.84 748.46
066.54 561.19
2.32
504.38
6.51
3.38
7.12
^0° 24 ., ..,1,964.02
40.19 27.08
21.17
7.89
849.43
,
5.33
0.976-1.006
0.000
689.38 0.981
505.35 1.001 1234678-HpCDD
1.012
- --
0.968-1.032
0.000
0.977
0.980
„„ 1.84L.22 _,1,~OQO I3ci2-Hpcnn §7!)
19.70 1.007
1.011
1.014
0.883-1.117
0.000
AN
£S7
_. _
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 20:48 07/22/97
65
-------
Page No. 6 Listing of W972831B.dbf
07/22/97 Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
DC SN 30:57 RO 0.25 4.78 0.904
DC SN 31:13 RO 0.25 7.41 0.912
DC SN 32:16 RO 0.26 2.53 0.943
DC SN 32:23 RO 2.67 3.87 0.946
DC SN 32:30 RO 2.35 1.68 0.949
DC SN 32:38 RO 0.24 3.53 0.953
DC SN 33:24 RO 1.31 9.75 0.976
DC SN 33:35 RO 1.57 5.88 0.981
M 34:20 0.97 75.40 37.20 38.20 1.003 OCDP AN
DC SN 34:33 RO 1.99 6.62 1.009
DC SN 34:43 RO 5.03 3.80 1.014
DC SN 35:14 0.86 14.71 1.029
DC SN 35:21 RO 2.93 7.26 1.033
DC SN 35:39 0.85 12.33 1.041
DC SN 35:45 0.83 7.12 1.044
442-444 1 Peak 75.40
OCDD 0.76-1.02 0.883-1.117
458-460 DC NL 0:00 0.78 4.44 0.000
M 34:14 1.02 307.00 155.00 152.00 1.000 OCDD AN
458-460 1 Peak 307.00
13C12-OCDD 0.76-1.02 0.996-1.005
470-472 DC NL 0:00 RO 1.48 3.42 0.000
34:14 0.87 2,699.15 1,256.24 1,442.91 1.000 13C12-OCDD IS8
DC WH 34:43 RO 1.29 8.01 1.014
470-472 1 Peak 2,699.15
Column Description "Why" Code Description QC Log Desc.
M_Z -Nominal Ion Mass(es) WL-Below Retention Time Window A-Peak Added
..RT. -Retention Time (mouss) WH-Above Retention Time Window K-Peak Kept
Rat.l -Ratio of M/M+2 Ions SN-B«low Signal to Noise Level O-Peak Deleted
OK -RO=Ratio Outside Limits
-------
17:00
tt2a:lf972831 tl-798 Acqs22
315.9419 Ts2 BSUB(256,30,-
TRIASGLX LASS Text:M23-
100\
80:
so:
40J
20:
o:
T±1»:W972831 tl-798 Acq:22-JUL-1997 14:31:25 SC EH- Voltmgm SIX 70SX Xoi**t20577
303.9016 Ti2 BSUB(256,30,-3.0) PKD(9,5,5,0.10\,82308.0,1.00*,r,T) XxpiXPCUS2
TRIANGLE LASS Text :M23-OUTLET-RON 1 TLIt42299A
rll*,tl972831 tl-798 Acq:23-JUL-1997 14131:25 GC XH- Volt*g» Sit 70SX Soia*:26997
305.8987 T:2 BSUS(256,30,-\3.0) PXD(9,5,^,0.10\,107988.0,1.00\,f,T) Xzp:XPCUS2
TRIAHSLX LABS
1004
18'tOO 19'tOO 20
JUL-1997 14:31t25 GC XH- Volttgm SIS
'.0) PXD(9,S,S,0.10\,72576.0,1.00\,r
odfTLET-SUIT 1 TLIt42299A
A8.
17:00
T±latft972831 tl-798 Acq:22
317.9389 T:2 BSUB(2S6,30,-
TBIANGLE LABS Toit:M23-
1003
801
601
40:
20:
OOCCET-
i i i I i i i
17:00
Tile:H972831 #1-738 Acq:2.
330.9792 T:2 EipsSPCUS2
TRIANSLX LABS Taxt:M23-<
1004
17:00
r±le:H972a31 tl-798
375.8364 Ti2 Exp:EPCaS2
TRIANGLE LABS Text.:M23-OLET-RUN 1 TLIt42299A
100\
30:
40^
20.
0.
6.37 17:00 17:26
00 21100
70S! Soil*:18144
I) Erp:XPCUS2
T
-r
szt
IfliOO 15.00 20
JUL-1997 14:31:25 GC EH- Voltagm
0) PXD(9,5,5,0.10\,13956.0,1.00*,r
'-RUN 1 TLH42299A
Al.
00 21100
70S* Soia»:3489
T) Elp:EPCUS2
IS8
18:00 19:00 20
JUL-1997 14:31:25 GC XI + Voltag*
ST.'.
OUTLET-
TLHH2299A
25 18:S3 19:14
18:00 19tOO 20
-1997 14:31:25 GC EI+ Volt*g» ST.
17
00
70SE
'Sit 00
00
70SX
31t 00
22:00
22:00
'22:00
2X7
8X7
3X7
9X6
5X6
0X0
0X7
4X7
8X7
2X7
9X6
0X0
22:00
21136
J^jUiu^xIiJu^^
-1
17:00
10tOO
15.00
20100
21:00
22:00
,0X5
2X4
2X4
1X4
1X4
0X0
T±me\
67
-------
10*00 15*00 20*00 21*00
r±letH972831 41-798 Acq:22-JUL-1997 14:31:25 SC XH- Voltage SIS 70SX Hoi*ft 3125
321.8936 rt2 BSUB(256,30, -3.0) PJ3)(7,5,3,0.10\,12SOO .0,1.00\,F,T) XxptEPCUS2
TRIANGLE LASS Teit:H23-OUTLET-RUlf 1 TLI442299A
100S A4.J.OE6
FU.etff972831 41-798 Acq:22-JUL-1997 14:31:25 SC EH- Voltage SIR 70SX Noimet2573
319.8965 rt2 BSUB(256,30,-3.0) PXD(7,5,3,0.10\,10292.0,1.00\,r,T) KxptXPCUSS
TRIANGLE LABS Text :M23-OUTLET-ROOT 1 XLI442299A
1003k A3.Q3E6
801
50:
40:
20:
A3.06E6
A1.85E6 «.««"••»
A A JlA. /V
10*00 15*00 20*00 21*00
riletW972831 41-798 Acq:22-JUL-1997 14:31:25 SC XI+ Voltage SIR 70SX Bo±*ft9990
331.9368 T:2 BSUB(256,30,-3.0) PXZ(7,5,3,0.10*,39960.0,1.00\,r,T) XxptXPCUS2
TRIANGLE LABS Text :M23-OUTLET-SUIT 1 TLI442299A
1001
00:
50:
40:
20:
o:
10*00 15*00 20*00 21*00
r±l«iH972831 41-798 Acq:22-JUL-1997 14:31:25 SC XI+ Voltage SIS 70SX Sola ft 45 3 5
333.9338 T-.2 BSUS(256,30,-3.0) PXD(7,5,3r0.10\,18140.0,1.00\,r,T) XzptXPCUS2
TRIANGLE LABS Text :M23-OUTLET-SUIT 1 TLI442299A
1001
80:
50:
40:
20:
10*00 15:00 20:00 21*00
rile*K9720Jl #1-758 Acq:22-JUL-1997 14:31:25 SC EI+ Voltage SIR 70SX OO±Metl998
327.8847 Ti2 BSUB(256,30,-3.0) PXD(7,5,3,0.10\,7992.0,1.00\,r,T) ExptEPCUS2
TRIANGLE LABS Text :M23-OUTLET-SUIT 1 TLI442299A
100S A1.46E8
00:
50:
40:
20J
o:
22*00
22*00
22*00
22*00
10*00 15*00 20*00 21*00
r±lfttf972831 41-798 Acq:22-JUL-1997 14:31:25 SC H+ Voltmgm SIS 70SX
330.9792 rt2 ExptEPCUS2
TRIANGLE LABS Text :M23-OUTLET-SUIT 1 TLI442299A
1003,
22.00
J..IT6
.8.0X5
.5.4X5
'•.2.7X5
0.0X0
Time
-1.6X7
'.1.3X7
-.9.9X6
.6.6X6
.3.3X6
0.0X0
Time
2.0X7
.1.6X7
.1.2X7
.8.0X6
.4.0X6
0.0X0
TiMt
3.4X7
.2.7X7
.2.0X7
.1.3X7
'•.6.7X6
0.0X0
Hm»\
18 oo
IsiOO
20 tOO
21*00
22*00
68
-------
22,00 23:00 24:00 25:00
r±le:H972B31 fl-798 Ac
-------
24:00 25iOO 26tOO
rile .-WS 72831 tl-798 Acqt22-JUL-1997 14,31:25 GC XI* Vbltaga SIS 70S* So±aa:1068
367.8949 r-.2 BSUB(256r30,-3.0) PXD(7,5,3, 0.10\,4272.0,1. OQ\,T,T) Exp:KPCUS2
TSIANGLX LASS Tajct:M23-OUTLET-SUir 1 TLIM2299A
TilatifS72831tl-798 Acq:JJ-JUL-lyir7 14iJl:J5 SC Elf Voltage SIS 7Oaf ffoj.M»1958
355.8546 Fs2 BSUB(256,30,-3.0) PXD(7,5,3,0.10%,3832.0,1.00\,T,X) ExptEPCfJS2
TRIANGLE LASS Text :M23-OUTLET-BOX 1 TLIt42299A
100\ A6.f2X6
24100 25100 26100
rlla,H972831 tl-798 Acqi22-JVL-1997 14:31:25 SC XH- Voltag* SIX 70S* Kojj»tl545
357.8516 T-.2 BSUB(256,30,-3.0) PED(7,S,3,0.10\,61BO.0,1.00\,T,T) ExptEPCOS2
TSIASGZX LABS T&zt:M23-OUTLET-Sa* 1 TLH42299A
1004 A3.(
801
001
801
601
401
201
•
0'
A4.
J
5717
1
A4.74E6
WV
^1.4X7
-1.1X7
.8.5X6
.5.6X6
-2.8X6
'0.0X0
24:00 25i00
TilatV972831 #1-758 Acq:22-JVL-1997 14:31:25 SC XI* Yoltag* SIS 70SX No±tftl211
369.8919 T:2 BSUB(256,30,-3.0) PXD(7,5,3r0.10\,4844.0,1.00\,r,T) XipsXPCVS2
TXIASGLX LABS TBXt:M23-OUTLET-XUX 1 TLH42299A
24t00 25t00
TilaiV972831 01-798 Acqt22-JUL-1997 14:31:25 SC XH- Volt»gm SIX 70SX
330.9792 T:2 XxpiEPCVS2
XXIAHGLX LABS Taxt:M23-OVTLXT-SUr 1 TLHt42299A
36 1 00
1001
80.
60.
40.
20.
0
A3
)
1X7
A3. 00X6
V/V
-9.5X5
.7.6X6
.5.7X6
\-3.~8X6
-1.9X6
-0.0X0
24:00
25100
26:00
70
-------
File:H972831 tl-422 Acq:22-JUL-1997 14:31:25 GC EI+ Voltage SIR 70SX Holme:6381
373.8208 r:3 BSUB(2S6,30, -3.0) PXD(7,5,3,0.10\,25S24. 0,1. 00%,r,T) XxptXPCUS2
TRIANGLE LASS Text :M23-OUTLET-SUM 1 TLIt42299A
100\ A1.33E7
ao:
60:
40:
20:
OJ
A3.13EI
A
A9.08E6
14.57E6
A1.94X6
y\ A
A3. 42X6
A1.60X6
A
S* V
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-4.4X6
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la.7X5
27:00 27:12 27:24 27:36 27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48
rile,M72831 tl-422 Acq:22-JUL-1997 14:31:25 GC XI* Voltage SIR 70SX Noise:8020
375.8178 T:3 BSUB(256,30,-3.0) PXD(7,5,3,0.10\,32080.0,1.00\,rfT) Xxp:XPCUS2
TRIANGLE LASS Text :M23-OUTLET-RUM 1 TLH42299A
100\ A1.09E7
80:
0.0X0
Tim
60.
40:
20:
o:
A7.13E6
\3.65E6
A1.62E6
A1.01E6 A.
y\
A2.82X6
A8.52X5
27:00 27:12 27:24 27:36 27:48 28:00 28:12 28:24 28:36 28:48 29:00'29:12'29:34'29:36'29:48
TiletH972831 tl-422 Acqs22-JUL-1997 14:31:25 GC Eli- Voltage SIR 70SX Noime:4274
383.8639 T:3 BSUB(256,30, -3.0) PXD(7,5,3,0.10\,17096.0,1.00\,r,T) Xxp:XPCUS2
TRIANGLE LABS Text :M23-OUTLET-RUM 1 TLH42299A
-3.5X6
.2.8X6
•J.1X6
.1.4X6
•.7.1X5
-.0.0X0
Tim
1001
80:
60:
40:
20:
o:
A3-9E7
A2.23Z7
27:00 27:12 27:24 27:36 27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48
rile:H972831 tl-422 Acq:22-JUL-1997 14:31:25 GC XI+ Voltage SIR 70SX Noiae:3742
385.8610 F:3 BSUB(256,30,-3.0) PXD(7,5,3,0.10\,14968.0,1.00\,r,T) XxptXPCUS2
TRIANGLE LABS Text :M23-OUTLET-RUN 1 TLIt42299A
.8.3X6
.6.2X6
".4.1X6
'.2.1X6
0.0X0
Time
1003
80:
60:
40:
20:
o:
A5.75E7
«5.M7
A4.38E7
-2.0X7
.1.6X7
J..2X7
.8.0X6
.4.0X6
~T
-r
-r
T1
uu*
T
-r
T
27:00 27:12 27:24 27:36 27:48 28:00 28:12 28:24 28:36 28:48 29ibb'29:12'29:24 29:36'29:4a'
rile:ff972831 tl-422 Acq:22-JUL-1997 14:31:25 GC XI+ Voltage SIR 70SX
92.9760 T:3 Exp:EPCUS2
TRIANGLE LABS Text :M23 -OUTLET-RUM 1 TLIt42299A
00* 27:00 27:18 27:3a 27:49^fl.OI ,„.,„ 28:43
-.0.0X0
Time
27:00 27:12 27:24 27:36 27:48 28:00 28:12 28:24 28:36 28:48'29:00 29:12'29:24' 29:36 29:48
±le:M972831 tl-422 Acq:22-JUL-1997 14:31:25 GC XI+ Voltage SIR 70SX
45.7555 F:3 Xzp:EPCUS2
TRIANGLE LABS Text iM23-OUTLET-RUM 1 TLIt42299A
001
0.0X0
T±mm
27:00 27:12 27:24 27:36 27:48 28:09 28:12 28:24 28:36 28:48 29:00 29:12 29:24'29:36'29:48
0.0X0
Tim
71
-------
File
389.
TSIA
1001
801
601
401
201
0'
27
File
391.
TRIA
1001
801
601
40.
201
0
27
rile
401.
TRIA
100J
so:
601
401
201
0
27
rile
403.
TRIA
1001
801
601
401
20.
0.
27
rile
392.
TRIA
1001
80.
60.
40.
20.
0
27
8156 T:3 BSUB(256, 30, -3.0) PKD(7,5,3,0.10\,17900.0,1.00\,r,T) Xxp:XPCOS2
JtGLE LABS Tejct:M23-OUTLST-XUlT 1 TLH42299A
A4.76E7
A
A
A9.66E6 I I A9.83X6
A / v A **"*
/ \ ^-^ f Vr rV \ ~/\
:24 27:35 27:48 28:00 28:12 20:24 28»3S 28:40 29:00 29:12 29:24 29: :
:H972831 tl-422 Acq:22-JUL-1997 14:31:25 GC EH- Voltage SIX 70SX BOim»:4811
8127 F:3 BSU3(256,30,-3.0) PXD(7,5, 3,0 .10\, 19244 .0,1. 00\rF,T) Kxp:XPCUS2
NSLE LABS Tex t:M23 -OUTLET-SOS 1 TZIt42299A
A3. 93X7
f\
T _ /I 7T -/r
24 27.' 35 27:48 28:00 28il2 28:24 2siJ5 28:48 29:00 29^12 29': 24 29 :J
:H972831 tl-422 Acq:22-JUL-1997 14:31:25 GC EH- Voltage SIS 70SX Noise: 3277
8558 Ts3 BSUB(256,30,-3.0) PKD( 7,5, 3,0. 101,13108. 0,1.00\,r,T) Kxp:XPCUS2
NGLE LABS Text:M23-OUTLZT-Sim 1 TLIt42299A
A3. 53X7 A3. 89X7
A A
ft n
A
A
/ll 11
-1 . 4X7
.1.1*7
.8.2*$
.5.5*6
.2. 7X6
0.0X0
16 Time
-1.1X7
.9.1X6
.6.3X6
.4.6X6
.2.3X6
0.0X0
6 OM»
-1.2X7
.9.7X6
.7.3X6
.4.9X6
.2.4X6
.0.0*0
24 27.-J5 27:48 28:00 2si-Z2 28:24 28iJ5 2S:4S 2S:00 29:12 29:24 29:36 Time
:H972831 tl-422 Acq:23-JUL-1997 14:31:25 GC XH- Voltage SIX 70SX Boise: 840
8529 T:3 BSUB(256,30,-3.0) PKD(7,5,3,0.10*,3360.0,1.00\,r,T) Xxp:XPCDS2
NGLS LABS Tar-t:X23-OUTLKT-SVir 1 TLIt42299A
A2.85X7 A3. 16X7 -.9.6X6
ft n
A
III 11
24 27:J6 27:48 28:00 28:12 38:34 28136 38:48 29:00 29:12 39:24 39:3
•.V972831 tl-422 Acq:22-JUL-1997 14:31:25 GC XH- Voltage SIX 70SX
9760 r:3 ExpsEPCUS2
NGLE LABS rext.-M2J-OOTLTT-.Enjr 1 TLH42299A
v V / w
V
.7.7*6
.5.8*6
.3.9X6
-1.9X6
0.0X0
6 Time
-1.5X7
-1.3X7
-8.9X6
-5.9X6
-3.0X6
-0.0X0
24 27:J$ 27:48 28:00 38:13 38:34 28:36 28:48 29:00 39:12 29:34 29:36 Time
12
-------
Tile:H972831 tl-441 Acq: 22- JUL- 1997 14:31:25 SC XH- Voltage SIX
70SE No±Me:5107
407.7818 T:4 SSUS(256,30,-3.0) PXD<7,5,3,0.10\,2042».Or1.0Q\rT,T) Xzp:XPCUS2
TRIANGLE LASS Text:M23-OOTLET-RUjr 1 TLH42299A
100!
80.
60.
40.
20.
A3 .92ES
f\
j\
I \ A1.41E6
\ A7Ar5A
^ V AJ V^ „
30:48' ' ' 3l':0'o' ' 31:12 31:24 31:36 31\48
Tile:W972831 tl-441 Acq:22-JUL-1997 14:31:25 SC XI* Voltage SIX
AS 34X5
Jv^ ^
-1.1X6
.8.8X5
.6.6X5
'-.4.4X5
.2.2X5
32:00 32:12 32:24 32 36 Time
70SX *>i*e:2560
409.7789 T:4 SSUS(256, 30, -3.0) PXD(7,5,3,0.10\,10240.0,1.00\,T,T) Exp:XPCUS2
TRIANGLE LASS Text iM23 -OUTLET-SUIT 1 TLH42299A
iota
80.
60.
40.
20:
A3.20E6
K
A
1 \ Al. 09E6
1 \ AS. 61X5 l\
1 V. -/\IJ^
30:48 31:00 31:12 31:24 31:36 31:48
Tile:K972831 tl-441 Acq:22-JVL-1997 14:31:25 SC XH- Voltage SIX
«;•«
-9.8X5
.7.9X5
.5.9X5
.3.9X5
.2.0X5
32:00 32:12 32:24 32 36 Time
70SX Noi*e:5457
417.8253 T:4 SSUS(2S6, 30, -3. 0) PXD(7,5,3,0.10\,2182».0,1.00\,T,T) XxptXPCUS2
TRIANGLE LASS Text:M23-OUTLET-RUJT 1 TLIf42299A
1003
ao:
601
401
201
A1.50E7
h
/ \
y v
' 30:48 ' ' ' 31:00 ' ' 31:12 31:24 31:3f 31148
Tile:tf972831 tl-441 Acq:22-JVL-1997 14:31:25 SC XZ+ Voltage SIX
A1.01X7
\
A
\
/ V^
-5.1X6
'-.4.1X6
-.3.1X6
-.2.0X6
.1.0X6
0.0X0
32:00 32il2 32:24 32 36 Time
70SX Soiae:4668
419.8220 T:4 SSUS(2S6,30,-3 .0) PXJ>(7, 5, 3, 0.101,18672. 0,1. 00\,T,T) Xxp:XPCUS2
TRIANGLE LASS TextsM23-OUTLET-RUIT 1 TLH42299A
1003
ao-.
60:
40:
20:
A3.42E7
A
i \
\
/ \
y v
' jflU'fl ' ' 'JlfOO' ' ' 3 it 12 ' ' ' 31:24 ' ' 31:3f' 31148
Tile:tf972831 tl-441 Acq:22-JTJL-1997 14:31:25 SC XH- Voltage SIR
430.9729 T:4 Exp:EPCUS2
TRIANGLE LASS Text:M23-OUTLET-RUlT 1 TLH42299A
1001
80:
60:
40:
20:
ol
30:48 30:57 31t£*r~v2J^!L *'/12^sS^^ ^>~&^\~
A2 . 42X7
A
A
\
/ \_
-1.1X7
'.9.1X6
.6.8X6
.4.5X6
.2.3X6
0.0X0
' 32:00 32:12 32:24 32 36 Time
70SX
33:0032:06 __3v\5^v 3S^3
30:48' ' ' 31:00 ' ' '31:12' ' '31:24 31:36 31:48
Tile:H972831 tl-441 Acq:22-JUL-1997 14:31:25 SC XH- Voltage SIX
479.7165 T:4 Exp:EPCUS2
TRIANGLE LASS Text :M23 -OUTLET-RUN 1 TLH42299A
1001
80:
60:
40:
20:
ol
30:47
| 1
-1.2X7
-.9.3X6
.7.0X6
-4.7X6
.2.3X6
0.0X0
' 32:00 ' ' ' 32:12 ' ' 32:24 ' 32 36 Time
70SX
32:21 6.5X4
1 33ll7\ I
A L.,5 31:36 31,56 A A . 1 A 1 /
/ A 31: 09ft 1!15 A 31,47
1 i^/\ AA A A A \A A /\ M A \ A AAA A A
_j \*/v \j vVvAyvvv w / \J vy\^/v v\y\-j v/v\_/ w V/WL,,
30\4B JI.'OO 31*:12 3l':24 3l':36 3l':48
A \ v, h AA / A /
A IU V\/V\/v/l /Uu/
^/V^-JN VulU Vx
-------
423.7766 T:4 BSUB(256, 30, -3.0) PXD(7,S,3,0.10\,4S44.0,1.00\,T,T) XxpiXPCUS2
3BISWGZS LASS Taxt slf 23 -OUTLET-SUIT 1 TLH42299A
1001
80.
60.
40.
20.
3
Tilt
425.
TSUI
1001
80.
60.
40.
20.
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3
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435.
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1003
80.
60.
40.
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1003
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3
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430.
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100S
80.
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0
3
A7.48E6
1 \ AS. 61X6
/ A
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It 00 31\06 31s 12 '31s 18 'lit 24 '31: JO '31\36 '31:42 '31:48 '31t54 '32ii>6 32:06 '32:12
<:lf972831 il-441 Acqs22-JUL-1997 14t31s25 GC XH- Volt*g* SIX 70S! Voimmil021
7737 T:4 3SUB(256,3Q,-3.0) PKD(7,5 ,3,0. 10\, 4084. 0,1. 00\,T,T) XzptXPCtTS2
\NGLE LASS Text :M2 3 -OUTLET-SUIT 1 TLH42299A
A6.89E6
A
I 1 AS. 05X6
A
/\
y V, ;v_ .
1:00 3l'i06 31:12 '31:18 '31t24 '31:30 31s 36 31:42 3l':48 '31\S4 32>66 J2>0« '32\12
IW972831 tl-441 Ac00 '3l': OS 31\12 31 .-13 '31:24 31:30 31:36 31:42 '31i48 '31:54 32:00 '32:06 '32:12
:W972831 il-441 Acq:22-JUL-1997 14:31:25 GC EH- Volt*gm SIX 70SX
9729 T:4 Exp:EPCUS2
HSZS LABS Text:M23-OUTLET-XWr 1 TLH42299A
2^jy^r~^\!^^
1:00 '3l': 06 31:12 '31:18 31:24 '31:30 '31:36 '31:42 '31:48 31:54 '32:00 '32:06 '32:12
-2.3X6
.1.8X6
.1.4X6
.9.0X5
.4.5X5
Time
-2.2X6
J..7X6
_I.iI6
.8.7X5
.4.4X5
.0.0X0
Time
-6.4X6
.5.1X6
.3.8X6
^.6X6
.1.3X6
Time
.5.6X6
.4.5X6
.3.4X6
12.3X6
.1.1X6
.0.0X0
Time
.1.2X7
.9.3X6
.7.0X6
.4.7X6
.2.3X6
0.0X0
Time
74
-------
tile:H972831 fl-441 Acq:22-JUL-1997 14:31:25 GC Sir VoltAgf SIM TOSS nQlm»,240Q
441.7428 T:4 SSUS(256,30,-3.0) PXD(7,5,3,0.10\,9600.0,1.00\,T,X) Xrp,XPCUS2
TRIANGLE LASS Text :tf23-OUTLET-RUN 1 TLH42299A
0X0
31:00 32:00 33:00 34,00 35,00
rHa,tf972831 fl-441 Acq:22-JUL-1997 14:31:25 GC TH- Voltmgu SIX 70SX SO±M»tl409
443.7399 fs4 SSUS(256, 30,-3.0) PXD(7,5, 3, 0.10\, 5636.0,1.00\,T,T) XxpiXPCOSS
TRIANGLE LASS Text.:M23-OUTLET-RUN 1 TLH42299A
A4.6BZ5
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430.9729 T:4 Exp:EPCUS2
TRIANGLE LASS TextsM23-OUTLET-RON 1 TLIM2299A
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13.6775 T>4 Exp:EPCUS2
TRIANGLE LASS Text :M23-OUTLET-RUN 1 TLH42299A
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TRIANGLE LASS Text :M23-OUTLET-RON I TLH42299A
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TRIANGLE LABS Text :M23-OUTLET-RUN 1 TLH42299A
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TRIANGLE LABS Text:M23-OUTLET-RUN 1 TLIt42299A
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TRIANGLE LASS Tttxt:M23-OVTLET-RUIT 1 TLH42299A
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-------
Peak Locate Examination:22-JUL-1997:14:30 File:W972831
Experiment:EPCUS2 Function:2 Reference:PFK
-------
TLI#42299A File Text : TRIANGLE LABORATORIES
File:W972831 #1-798 Acq:22-JUL-l997 14:31:25 GC EI+ Voltage SIR 70SE
319.8965 F:2 Exp:EPCUS2
Sample Text :M23 -OUTLET-RUN 1
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File:W972831 #1-798 Acq:22-JUL-1997 14:31:25 GC EI+ Voltage SIR 70SE
321.8936 F:2 Exp:EPCUS2
Sample Text:M23-OUTLET-RUN 1 TLI#42299A File Text:TRIANGLE LABORATORIES
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File:W972831 #1-798 Acq: 22-JUL-1997 14:31:25 GC El-f Voltage SIR 70SE
331.9368 F:2 Exp:EPCUS2
Sample Text:M23-OUTLET-RUN 1 TLI#42299A File Text:TRIANGLE LABORATORIES
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File:W972831 #1-798 Acq:22-
339.8597 F:2 Exp:EPCUS2
Sample Text:M23-OUTLET-RUN
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File:W972831 #1-798 Acq:22
341.8567 F:2 Exp:EPCUS2
Sample Text:M23-OUTLET-RUN
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File:W972831 #1-798 Acq:22-JUL-1997 14:31:25 GC EI+ Voltage SIR 70SE
351.9000 F:2 Exp:EPCUS2
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File:W972831 #1-798 Acq:22
339.8597 F:2 Exp:EPCUS2
Sample Text:M23-OUTLET-RUN
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-JUL-1997 14:31:25 GC EI+ Voltage SIR 70SE
1 TLI#42299A File Text:TRIANGLE LABORATORIE
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File:W972831 #1-798 Acq:22
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1 TLI#42299A File Text:TRIANGLE LABORATORIES
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File:W972831 #1-798 Acq:22-JUL-1997 14:31:25 GC El-f Voltage SIR 70SE
339.8597 F:2 Exp:EPCUS2
Sample Text:M23-OUTLET-RUN 1 TLI#42299A File Text:TRIANGLE LABORATORIES
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File:W972831 #1-798 Acq:22-JUL-1997 14:31:25 GC EI+ Voltage SIR 70SE
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File:W972831 #1-798 Acq: 22-JUL-1997 14:31:25 GC El-f Voltage SIR 70SE
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File:W972831 #1-798 Acq:22-JUL-1997 14:31:25 GC EI+ Voltage SIR 70SE
355.8546 F:2 Exp : EPCUS2
Sample Text :M2 3 -OUTLET-RUN 1 TLI#42299A File Text :TRIANGLE LABORATORIES
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File:W972831 #1-798 Acq:22-JUL-1997 14:31:25 GC EI+ Voltage SIR 70SE
357.8516 F:2 Exp:EPCUS2
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File:W972831 #1-798 Acq:22-JUL-1997 14:31:25 GC EI+ Voltage SIR 70SE
369.8919 F:2 Exp:EPCUS2
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File:W972831 ttl-422 Acq:22-JUL-1997 14:31:25 GC EI+ Voltage SIR 70SE
373.8208 F:3 Exp : EPCUS2
Sample Text :M2 3 -OUTLET-RUN 1 TLI#42299A File Text : TRIANGLE LABORATORIES
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File:W972831 #1-422 Acq:22-JUL-1997 14:31:25 GC EI+ Voltage SIR 70SE
375.8178 F:3 Exp:EPCUS2
Sample Text :M2 3 -OUTLET -RUN 1 TLI#42299A File Text : TRIANGLE LABORATORIES
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383.8639 F:3 Exp:EPCUS2
Sample Text :M2 3 -OUTLET-RUN 1 TLI#42299A File Text : TRIANGLE LABORATORIES
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File:W972831 #1-422 Acq:22-JUL-1997 14:31:25 GC EI+ Voltage SIR 70SE
373.8208 F:3 Exp:EPCUS2
Sample Text:M23-OUTLET-RUN 1 TLI#42299A File Text:TRIANGLE LABORATORIES
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File:W972831 #1-422 Acq:22-JUL-1997 14:31:25 GC EH- Voltage SIR 70SE
375.8178 F:3 Exp:EPCUS2
Sample Text:M23-OUTLET-RUN 1 TLI#42299A File Text:TRIANGLE LABORATORIES
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File:W972831 #1-422 Acq:22-JUL-1997 14:31:25 GC EI+ Voltage SIR 70SE I
383.8639 F:3 Exp:EPCUS2
Sample Text :M23-OUTLET-RUN 1 TLI#42299A File Text:TRIANGLE LABORATORIES,
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-------
File:W972831 #1-422 Acq:22
373.8208 F:3 Exp:EPCUS2
Sample Text :M2 3 -OUTLET- RUN
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File:W972831 #1-422 Acq:22
375.8178 F:3 Exp:EPCUS2
Sample Text:M23-OUTLET-RUN
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1 TLI#42299A File Text : TRIANGLE LABORATORIES
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1 TLI#42299A File Text : TRIANGLE LABORATORIES
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383.8639 F:3 Exp:EPCUS2
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-JUL-1997 14:31:25 GC EI+ Voltage SIR 70SE
1 TLI#42299A File Text-.TRIANGLE LABORATORIES
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File:W972831 #1-422 Acq:22-JUL-1997 14:31:25 GC EI+ Voltage SIR 70SE
373.8208 F:3 Exp:EPCUS2
Sample Text:M23-OUTLET-RUN
100%
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File:W972831 #1-422 Acq:22
375.8178 F:3 Exp:EPCUS2
Sample Text:M23-OUTLET-RUN
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File:W972831 #1-422 Acq:22
383.8639 F:3 Exp:EPCUS2
Sample Text:M23-OUTLET-RUN
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File:W972831 #1-422 Acq:22-JUL-1997 14:31:25 GC EI+ Voltage SIR 70SE
389.8156 F:3 Exp:EPCUS2
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File:W972831 ttl-422 Acq: 22-JUL-1997 14:31:25 GC EI+ Voltage SIR 70SE
391.8127 F:3 Exp : EPCUS2
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401.8558 F:3 Exp:EPCUS2
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File:W972831 #1-422 Acq:22-JUL-1997 14:31:25 GC EI+ Voltage SIR 70SE
389.8156 F:3 Exp:EPCUS2
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391.8127 F:3 Exp:EPCUS2
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389.8156 F:3 Exp : EPCUS2
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File:W972831 #1-441 Acq:22-JUL-1997 14:31:25 GC EI+ Voltage SIR 70SE
407.7818 F:4 Exp : EPCUS2
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409.7789 F:4 Exp:EPCUS2
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417.8253 F:4 Exp:EPCUS2
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File:W972831 #1-441 Acq:22-JUL-1997 14:31:25 GC E1+ Voltage SIR 70SE
407.7818 F:4 Exp:EPCUS2
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409.7789 F:4 Exp:EPCUS2
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417.8253 F:4 Exp:EPCUS2
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File:W972831 #1-441 Acq:22-JUL-1997 14:31:25 GC EI+ Voltage
407.7818 F:4 Exp:EPCUS2
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409.7789 F:4 Exp:EPCUS2
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417.8253 F:4 Exp:EPCUS2
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File:W972831 #1-441 Acq:22-JUL-1997 14:31:25 GC EI+ Voltage SIR 70SE
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409.7789 F:4 Exp:EPCUS2
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Sample Text:M2 3-OUTLET-RUN
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File:W972831 #1-441 Acq:22-JUL-1997 14:31:25 GC EI+ Voltage SIR 70SE
441.7428 F:4 Exp:EPCUS2
Sample Text:M23-OUTLET-RUN 1 TLI#42299A File Text:TRIANGLE LABORATORIES, INC
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469.7779 F:4 Exp:EPCUS2
Sample Text:M23-OUTLET-RUN 1 TLI#42299A File Text:TRIANGLE LABORATORIES
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457.7377 F:4 Exp:EPCUS2
Sample Text:M23-OUTLET-RUN 1 TLI#42299A File Text:TRIANGLE LABORATORIES
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459.7348 F:4 Exp:EPCUS2
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File:W972831 #1-441 Acq:22-JUL-1997 14:31:25 GC EI+ Voltage SIR 70SE
469.7779 F:4 Exp:EPCUS2
Sample Text:M23-OUTLET-RUN 1 TLI#42299A File Text:TRIANGLE LABORATORIES, INC
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-------
TLI Project: 42299A Method 23 TCDD/TCDF Analysis (DB-225)
Client Sample: M23-Outlet-Run I Analysis File: P973370
Client Project: Iron & Steel-Chicago
Sample Matrix: M23TRAJN Date Received: 07/01/97
TLI ID: 173-61-1ABCE Date Extracted: 07/17/97
Date Analyzed: 07/23/97
Sample Size: 1.000
Dry Weight: n/a
GC Column: DB-225
Dilution Factor: n/a
Blank File: W972829
Analyst: BB
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPC2NF04
PF22206
P973363
n/a
n/a
n/a
Amiytes ' „- *»Mto£*'\ , Dfc.Vf i$aMP6^ -V^fe"118^^ ** * <**
2,3,7,8-TCDF 1.1 *
Internal Standard AmL (n
13Ci:-2,3,7,8-TCDF 4.1
Recovery Standard
13r,,-1.2.3.4-TCDD
/
g> % Recovery QCL&nrte
103 40%-130%
,
0.76
"Rafift St
0.75
, M* -
0.76
20:59
fiT Flags
20:59
BT l^q^T-
20:00
Data Reviewer.
07/24/97
Page 1 of 1
C2NF.PSR Y2.00. LARS 6.10.03
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 15:48 07/24/97
96
-------
Initial
..Data...
Data Review By:
Calculated Noise Area: n/a
The Total Area for each peak with an ion abundance ratio outside
ratio limits has been recalculated according to method requirements.
Page No. 1 Listing
07/24/97 Matched
Compound/
M_Z.... QC.Log Omit Why . .RT. OK
TCDF 0
304-306 DC NL 0:00
16
16
17
17
17
18
:42 RO
:50 RO
:48
:52
:58
:07
18:23
18:
:32
18:40
18:
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18:58 RO
19;
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19:21
DC SN 19:28 RO
19:
19:
20:
20:
20:
20:
20:
21:
21:
21:
22:
22:
43
57
09
20 RO
31
53
59
11
24
32
15
55 RO
of P973370B.dbf
GC Peaks / Ratio / Ret. Time
Ratio Total. Area. .. Area. Peak.
.65-0.89
0.78 0.73
6.20
4
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0.
0,
0,
0.
0.
0.
0.
0.
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.76
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,74
76
0.69
0.
304-306 25 Peaks
13C12-TCDF
316-318 DC NL 0:
DC WL 19:
DC WL 19:
20:
21:
21:
DC SN 21:
DC WH 22:
0.
00 RO
42 RO
57
59
23 RO
32
56 RO
56
64
15,
11.75
21
622
206
,179
683
562
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407
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273
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752
1
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699
863
62
581
480
523
425
451
768
404
37
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41
59
267
89
498
287
230
459
173
900
119
543
351
527
299
363.
34.
249.
201.
225.
177.
192.
330.
165.
16.
1. . Area. Peak.
.15
.14
.92
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.34
.97
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.21
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.01
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.41
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74
61
79
55
34
6
12
354
116
681
395
331
648
233
1,242
243
832
401
752.
400.
500,
35.
331.
279.
297.
247.
259.
437.
238.
25.
65-0.89
1.
1.
0.
0.
1.
0.
0.
0.
316-318 3 Peaks
32
44
83
75 1,
30
88
63
82
1,
— Above:
1.
.27
2.. Rel.RT Compound. Name. . ID.. Flags.
0.787-1.099
0.000
.64
.28
.98
.43
.59
.70
.81
.69
.87
.37
.99
.11
.82
.17
.29
.39
.29
,28
.04
87
52
12
46
55
48
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0.
0.
0,
0.
0.
1.
1.
1.
1.
1.
1.
.796
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.848
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.863
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.940
.951
.960
.969
.978
,995
,000 2378-TCDF AN
010
020
026
060
092
— , ._ .
0.952-1.048
4.50
10.86
908.
,62
5.77
20.86
821.
4.
9.
02
24
76
1,087.
3.
11.
60
26
10
1.63
18.
63
0.
0.
0.
1.
1.
1.
1.
1.
000
939
951
000 13C12-2378-TCDF ISO
019
026
045
093
935.25
TCDF / TCDD Rollout
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carofina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 15:49 07/24/97
97
-------
Page No.
07/24/97
Listing of P973370B.db£
Hatched OC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log oraic Why
13C12-TCDD
332-334
332-334
DC
.RT. OX Racio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
0,
NL. 0:00 RO
18:44
19:46
20:00
20:39
4 Peaks
.65-0.89
1.78
0.74
0.82
0.76
0.72
0.73
6.45
1,440.16
1,339.27
16.68
2.802.56
2.74
647.20
578.64
6.96
3.71
792.96
760.63
9.72
0.898-1.102
0.000
0.948
1.000 13C12-2378-TCDD IS1
1.012 13C12-1234-TCDD RSI
1.045
Column Description.
- Cod* Description QC Log Desc.
M_Z -Nominal Ion Mass(as)
..RT. -Retention Time (mm:ss)
Rat.l -Ratio of M/M+2 Ions
OK -RO=Ratio Outside Limits
Rel.RT-Relative Retention Time
End of Report
WL-Below Retention Tina Window
WH-Abov* letention Tia» window
SH-telow Signal to Kbise Level
-------
303.3016 3303(256, 30,-3.0) PKD(5, 3, 1,0. 101,640. 0,0.00\,r, T) XxptOS225
TSIAJKLX LASS T*xt:M23 -OUTLET-SDH 1 XLIt42299A
1001
80.
60.
40.
20.
A9.00X6
1 AS. 43X6
i! 1 AS 37t6
A4 . 60X0.] n *3 • f /eo
A4.98X6 1 ] I
ft fl ft A3'"ES
. , I M i A *»•«»
A A / m ft n"-A50M ^ A
1 A A A A^'^A **'66*6
w \n/y w\ I MvA/V A
/s^^ /iyUvywViilV;lx JvMyVAJv^/VV/vyVV. 7V ^
-2.1X6
.1.6X6
.1.2X6
.8.2X5
.4.1X5
0.0X0
17': 00 ' ' 18:00 19:00 20\o6 21:00 22:00 23:00 Urn*
fil»:P973370 tl-965 AOJ-.23-JUL-1997 21:08:04 XH- Voltage SIS 70P Hairnet 204
305.8987 3SU3(256,30,-3.0) PXJ>(S,3,l,0.10\,816.0,0.00\,r,r) XxptDB225
TRIAHGLX LABS T*rt:M23-OUTLXT-BUjr 1 TLH42299A
ion
80.
60.
40.
20.
Q '
A1.24X7
I
1 ^'l"6
'A A 1 AS. 00X6
lL 1 ^A3.31X6 «..*«
fli n A J ft (1 Mf-A^ft »-3»6
Iw AMU I v\y\/v A
/ I? u x / v V 1 I\JI\ \J Vyv/v/v yyxyV/Yx yV >^
-2.9X6
'.2.3X6
.1.7X6
.1.2X6
.5.8X5
0.0X0
'l7:00 18:00 19:00 20:00 21:00 22:00 23\00 Time
r±l»:P973370 tl-965 Acq:23-JUL-1997 21:08:04 XH- Voltage SIX 70P Boi*e:475
315.9419 3303(256, 30, -3.0) PXO(5,3,l,0.10\,1900.0,0.00\,r,r) XxptD3225
TXIANGLX LASS TtuctiM23 -OUTLET-SUN 1 TLIt42299A
loot
80.
60.
40.
20.
g.
AB.21E6
I
j \
2.2X6
'.1.8X6
'.1.3X6
.8.8X5
.4.4X5
0.0X0
17tOO ' ' 18:00 ' 19:00 ' ' ' 2o':00 2l'io6 ' ' 22:00 ' ' ' 23:00 Ttm»
ril»:P973370 tl-965 Acqt23-JVL-1997 21:08:04 XH- Voltage SIX 70P Hoife:360
317.9389 3303(256,30, -3.0) PXJ>(5,3,l,0.10\,1440.0rO.OO\,T,T) Xxp:DB225
TBIAHGLX LASS Text :M23 -OUTLET-SUN 1 TLH42299A
1001
80.
60.
40.
20:
0.
Al . 09X7
\
1 I
.3.0X6
.2.4X6
.1.8X6
.1.2X6
'.6.0XS
0.0X0
17<00 10100 19:00 20:00 21:00 22:00 23:00 Time
r±l»:P973370 tl-965 Aoqt23-JUL-1997 21:08:04 XH- Voltage SIX 70P
375.8364 XxfiO322S
TXIAOGLX LASS Text:M23-OUTLrT-SUlf 1 TLH42299A "" '
1001
80.
60.
40.
20.
0
16:43
I
II 17:07
1
A !..»
M fl 18:20 1 IStSl 20:30 21:22 Slifa
^(^\^I^Mi^ — *J^«^
-------
TH»,P973370 tl-965 AcqtJJ-JliA-lUl'S 21:08,04 EI+ Voltage SIS 70P Noj.ia,229
319.8965 BSVB(356,30,-3.0) PXD(5,3,1,0.10\,916.0,0.00\,T,T) Xzp,DB225
TXIASSLX LABS T3 00X5 R A2 05X5
ft "in *l
"•"» ft \\A2.64X5 h
1 A «-.?» /I Kjw5
ft A Uf L.^4 y ^^ A7.04X4
/I /I I /UuVinA JVfL A A A
— I \ f~. I ^ vw^ ••/ Ly\JvA-/\/\y II IV r VA * V r 1 NL /\ f\- r \ TV\*
^.7X4
.7.0X4
.5.0X4
.J.5X4
.1.5X4
10ioO 15»00 20:00 2l't 00 22,00 ' ' T±m»
r±la,P973370 tl-965 Acqt23-JVL-1997 21:08:04 XX* Voltage SIX 70P Bo±ae>,236
327.8847 BSUB(256,30,-3.0) PXD(S,3,l,0.10\,944.0,0.00\rT,r) XrptDB22S
TXIANGLX LABS Taxt.iK23-OUTLFT-EUR 1 TLIt42299A
1001
00.
60.
40.
20.
0.
JLL.42S7
n
4.2X5
.3.3X6
J.5X6
J..7X6
.8.3X5
0.0X0
' 18:00 ' ' 15»00' 20:00 21:00 22tOO ' ' Urn*
ril»tP973370 tl-965 Acg,23-JVL-1997 21:08,04 XH- Voltage SIX 70P Ho±»»t367
331.9368 BSVB(256,30,-3.0) PKD(5,3,l,0.10\,146».0,0.00\,r,T) XxpiDB225
XRIAJKZX LABS TmxtiH23-OOTLXT-XUIt 1 TUt42299A
1001
801
601
401
201
01
A6.47X6
jla5. 7515
f
lul
-1.9X6
.1.5X6
.1.1X6
.776X5
.3.8X5
0.0X0
18:00 19tOO 20tOO 21»00 22:00 Time
y±lttP973370 tl-965 Acqt23-JUL-1997 21,08:04 XH- Voltage SIX 70P So±Mft206
333.9338 BSV3(256,30,-3.0) PrO(5,3rl,0.10\,»24.0,0.00\,T,r) XxptDB225
TtlASSLX LABS T*rt,M23-OUTLXT-Zinr 1 TLIt42299A - •
1004
00.
601
401
201
a7.S3*ff
1
«a7.«zff
/I/ I
-2.4X6
-1.9X6
-1.5X6
-9.7X5
-4.9X5
' ' ' ' .1 . ' ' ' ' ' ..' ..' ' ' ' ' ..' . ' ' ' ' ' . 1 ' ' ' ' ' AM' ..' ' '
1st 00 19,00 20,00 21,00 22,00 dM0
100
-------
ril»tP973370 tl-965 Acq:23-JVL-1997 21:08:04 11+
303.9016 Xxp:DB225
TRIAHGLX LABS Tax t:H23 -OUTLET-BUN 1 TLIt42299A
100* 18f4t
Voltage SIS 70P
80:
20:
19il7
19:43
20109
21132
22115
A
,2.1X6
.1. 6X6
.1.2X6
.9.2X5
.4.1X5
17,00 18,00 19,00 20:00 21,00
r±10,P973370 tl-965 Aoqt23-JUL-1997 21:08:04 XI+ Voltag* SIX 70P
315.9419 XxptDB225
TXXABSLX LABS Text iM23-OUTLET-RUN 1 TLH42299A
22100
23100
.0.0X0
T±M
iota
80:
so:
40:
20:
20159
2.2X6
.1. 8X6
.1.3X6
.8.8X5
.4.4X5
0.0X0
17>38
18:06
17:00 18:00 19iOO 20tOO 21iOO
r±l»:P973370 tl-965 Aoq>23-JVZ-1997 21,08:04 KT+ Voltagw SIS 70P
319.8965 XxpiDB225
TSIMKLX LABS Text :M23-OUTLET-BUN 1 TLH42299A
100* 18,44
80:
60:
40:
20:
OJ
17>00 18:00 19:00 20:00 21:00
r±l»tP973370 tl-965 Aoq:23-JVL-1997 21:08:04 XI+ Voltmg* SIX 70P
331.9368 XxpiDB225
3XXAHGXZ LABS Text :M23-OUTLET-BUN 1 TLIt42299A
22:00
23 i 00
16:39
17tl8
1003
80:
60:
40:
20:
19s 46
1.9E6
.1.5X6
.1.1X6
.7.6X5
.3.8X5
17:00 18:00 19:00 20:00 21:00
TilmiP973370 tl-965 Acqi23-JTJL-1997 21:08:04 XH- VoltMgm SIX 70P
292.9825 XxptDB225
TRIAHSLX LABS Taxt.,M33-OUTLET-RUN 1 TLIt42299A
22100
23:00
0.0X0
T±mt
17,00 18,00 19,00 20,00 21:00 22,00
r±l»tP973370 tl-965 Acq:23-JUL-1997 21,08:04 XZ+ VoltMgm SIX 70P
330.9792 Xxp:DB225
TXIAHKLX LABS T+Xt:M23-OUTLET-XUN 1 XLIt42299A
23100
17:00
18:00
19:00
20:00
21:00
22:00
23100
101
-------
fl:P973378
tef, iass 232,9825 Peak top
Height ,58 wits Span 208 ppi
Systei file rate
Data file naie
Resolution
Group naber
lonlzatlon nxk
Switching __
Ref, usses 292,3825,
fl 292,9825
8 383,9616
C 385,8987
0 315,9419
E 317,333
F 319,8965
6 321,3336
H 327,8847
338,9792
J
K
L
II
1
El*
VOLTflGE
~388i376f
338.9792
331,9368
375,8384
Channel I 338,9792 Peak top
Height ,42 volts Span 268 ppi
102
-------
TLI Project: 42299A
Client Sample: M23-Outlet-Run 2
Method 23 PCDD/PCDF Analysis (a)
Analysis File: W972832
Client Project:
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
Iron & Steel-Chicago
M23TRAIN Date Received:
173-61-2ABCE Date Extracted:
Date Analyzed:
LOGO
n/a
DB-5
Dilution Factor:
Blank Hie:
Analyst*
07/01/97
07/17/97
07/22/97
n/a
W972829
MM
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPX23704
WF54307
W972828
n/a
n/a
n/a
Anaiytes
2,3,7,8-TCDD
1,2,3,7,8-PeCDD
1,2,3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
1,2,3,4,6,7,8-HpCDD
1,2,3,4,6,7,8,9-OCDD
2,3,7,8-TCDF
12,3,7,8-PeCDF
2,3,4,7,8-PeCDF
1,2,3,4,7,8-HxCDF
12,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
12,3,4,6,7,8-HpCDF
12,3,4,7,8,9-HpCDF
1,2,3,4,6,7,8,9-OCDF
totals
Total TCDD
lotal PeCLJL)
Total HxCDD
Total HpCDD
Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF
«#fc#*:fB£jfc :®*w ' "
0.08
021
EMPC 0.06
0.89
0.42
1.1
0.71
3.5
0.54
0.56
0.69
027
024
0.03
0.38
EMPC 0.06
EMPC 0.10
•A-WMfcl''' ^iibtM^-t* -^TOVfiftMkifeAM ^^A ISifc&tiW^' "v
•ttHiC i-n^Cv ^%9RCn»DnF i-fc ^yio»i**c— .
^ ^TWM%F %"^9ip i. ^^W!¥H*JI*I>^^» *^*» ^•M'FVK ^*^ ^
0.78 10 0.99
.*•• O 1 .0
7.6 7 7.7
2.5 2
27.5 15
7.4 14 7.4
2.9 11 3.0
0.63 3 0.69
Ratio
0.77
1.55
1.23
1.37
1.04
0.80
0.76
1.48
1.52
1.16
1.18
1.20
1.37
1.12
PIT
20:51
25:31
28:55
29:13
31:47
34:14
20:02
24:24
25:09
28:04
28:11
28:43
29:26
30:56
flag*
____
_®_
_
_^__
B_
_,_„_-
_
— —
— —
B_
.
B_
Flags
S-
—
&±
SR TiOa LARS 6.10.03
Triangle Laboratories, Inc.®
801 Capttola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 20:37 07/22/97
103
-------
TLI Project: 42299A
Client Sample: M23-Outlet-Run 2
Method 23 PCDD/PCDF Analysis (a)
Analysis File: W972832
• internal Standards •"> .' ..' -""Mili
13C,2-2,3,7,8-TCDF
I3C,2-2,3,7,8-TCDD
13d2-l,2,3J,8-PeCDF
13C,2-U,3,7,8-PeCDD
13C,2-l,2,3,6,7,8-HxCDF
13C,2-l,2,3,6,7,8-HxCDD
13C,2-l,2,3,4,6,7,8-HpCDF
13Cis-l,2,3,4,6,7,8-HpCDD
13C,2-1,2,3,4,6,7,8,9-OCDD
Surrogate Standards (type A) >
J7Cl4-2,3,7,8-TCDD
13C,2-2,3,4,7,8-PeCDF
13C,2-l,2,3,4,7,8-HxCDF
l3Cp-l,2,3,4J,8-HxCDD
13O-l,2,3,4,7,8,9-HpCDF
Altematft Standards (Typ»A> ,
13C,2-l,2,3,7,8,9-HxCDF
l3C,2-2,3,4,6,7,8-HxCDF
Recovery Standards
13C,2-1,2,3,4-TCDD
13C,2-l,2,3,7,8,9-HxCDD
*mt. (ng) *
3.4
3.6
3.4
3.5
3.5
3.6
3.0
17
3.1
tout (*$) ;
3.9
3.9
42
2.8
3.8
MLM^. ^ ^
3.7
3.8
vT '"
85.9
89.6
84.5
87.5
87.0
89.9
74.9
68.2
38.3
%Bee&«Biy
97.2
96.7
104
68.8
95.4
% Recovery
92.9
95.4
,., ,
QCUmrts -:;.
40%- 130%
40%-130%
40%-130%
40%-130%
40%-130%
40%-130%
25%-130%
25%-130%
25%-130%
QCLimrts
70%-140%
70%-140%
70%-140%
70%-140%
70%-140%
QC Limits
40%-130%
40%- 130%
% • " ;" ":"•" Vf>:'|
m®**-^
0.78
0.80
1.50
1.49
0.53
1.21
0.42
1.06
0.84
Ratfo
1.46
0.50
1.25
0.43
Ratio
0.52
0.51
1$%^
0.81
1.22
>.;Br-,.ik«^,-
20:00
20:48
24:23
25:31
28:11
28:55
30:56
31:47
34:14
Iff flags
20:50
25:08
28:04
28:51 V ©•
32:07
PIT Flags
29:26
28:42
^:J^;W£*L.
20:35
29:12
Data Reviewer.
Page 2 of2
07/22/97
X237.PSR vlOO. LARS 6.10 03
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 20:37 07/22/97
104
-------
TLI Project:
Client Sample:
42299A
M23-Outlet-Run 2
Toxicity Equivalents Report
Analysis File: W972832
Client Project:
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
Iron & Steel-Chicago
M23TRAIN
173-61-2ABCE
1.000
n/a
DB-5
Date Received:
Date Extracted:
Date Analyzed:
Dilution Factor:
Blank File:
Analyst:
07/01/97
07/17/97
07/22/97
n/a
W972829
MM
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPX23704
WF54307
W972828
n/a
n/a
n/a
A -— — I..*— —
Analytes
2,3.7,8-TCDD
1,2,3,7,8-PeCDD
1,2.3.4,7,8-HxCDD
1,2,3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
1,2,3,4,6,7,8-HpCDD
1,2,3,4,6,7,8,9-OCDD
TOTAL PCDD
2,3,7,8-TCDF
1,2.3,7,8-PeCDF
2,3,4,7,8-PeCDF
1,2,3,4.7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
1,2,3,4,6,7,8-HpCDF
1, 2,3.4.7, 8,9-HpCDF
1,2,3,4,6,7,8,9-OCDF
TOTAL PCDF
A *M* S»W\
Amt. (ng) -
0.08
0.21
[0.06]
0.89
0.42
1.1
0.71
0.89
0.54
0.56
0.69
0.27
0.24
0.03
0.38
[0.06]
fO 101
l\s. i vyj
Total
* - •>'
X
X
X
x
X
X
X
X
X >
X
X
x
x
X
x
x
x
EPA TEFs,
•I" Hi' t±' * '^ ?• " ; '- %"x?" *"- " "^ >"'
TEF .^, ;;r;v-i.,-..-^.i
1
0.5
0.1
0.1 =
0.1 =
0.01
0.001 =
0.1
0.05 r =
,0.5
0.1 ; =
0.1 =
0.1
0.1
0.01 =
0.01 =
0.001 =
1989a: 0.857 ng
Equivalent
0.08
0.105
0.006
0.089
0.042
0.011
0.00071
0.334
0.089
0.027
0.28
0.069
0.027
0.024
0.003
0.0038
0.0006
0.0001
0.524
[...] indicates that the value is that of an EMPC.
Page 1 of 1
TEFPR vS.I I. LARS 6.I0.05<.
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Added Paae7rr°9/18/97
-------
Initial
..Date..
Data Review By:
Calculated Noise Area:
00
The Total Area for each peak with an ion abundance ratio outside
ratio limits has been recalculated according to method requirements.
Page No. 1 Listing
07/22/97 Matched
Compound/
M_Z.... QC.Log Omit Why . .RT. OK
TCDF 0 .
304-306 DC NL 0:00 RO
A 16:
17:
17:
17:
17:
18:
18:
19:
19:
19:
20:
20:
20:
20:
21:
40
03
17
47
59
25
46
09
31
47
02
29
43
59
56
of W972832B.dbf
GC Peaks / Ratio
Ratio Total. Area
65-0.89
0.38 98
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.65
.78
.79
.78
.79
.77
.75
.76
.73
.77
.76
.75
.77
.77
.76
304-306 15 Peaks
13C12-TCDF
316-318 DC NL 0:
DC WL 16:
DC WL 17:
DC WL 18:
20:
20:
0.
00 RO
59 RO
34 RO
46 RO
00
28
/ Ret. Time
. .. Area. Peak. 1. . Area . Peak . 2 . .
0.
.04
221.10
5,016
3,333
18,508
17,089
20,293
15,887
23,051
11,077
8,883
19,910
8,101
5,930
752
461
158,518
.65
.90
.25
.02
.59
.38
.52
.36
.84
.67
.09
.66
.32
.02
.37
87
2,203
1,467
8,098
7,544
8,799
6,326
9,942
4,689
3,854
8,572
3,479
2,580
328
199
.10
.56
.85
.05
.71
.69
.40
.52
.87
.55
.07
.34
.89
.10
.48
134
2,813
1,866
10,410
9,544
11,493
9,060
13,109
6,387
5,029
11.338
4,621
3,349
424
261
65-0.89
5
7
5
1
0
0
.71
.77
.56
.12
.78
.72
316-318 2 Peaks
AU
TCDD
320-322 DC NL 0:
17:
M 18:
18'
19:
D D CO 19:
M 19:
20:
20:
20:
20:
20:
21:
0.
00 RO
54 RO
19 RO
3,7 RO
30
48 RO
55
13
32
42
51
58
12
5
21
17
115
17,793
250
13,043
.65-0.89
2
0
0
.81
.61
.64
12
421
181
.56
.79
.89
.79
.50
.04
.54
P /
r /
.05
.35
.37
7,779
104
.10
.48
10,014
145
.00
.09
.05
.20
.31
.90
.98
.00
.49
.29
.60
.75
.77
.22
.54
0.
.40
.56
Rel.RT Compound . Name .. ID.. Flags.
819-1.109
0.000
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
1.
1.
1.
1.
833
853
864
889
899
921
938
958
976
989
002 2378-TCDF AN
024
036
049
097
950-1.050
0.
0.
0.
0.
1.
1.
000
849
878
938
000 13C12-2378-TCDF ISO
023
183
78
.30
.90
0 •;<» tio so 139 i«
0
1
0
0
0
0
0
0
0
.30
.19
.75
.78
.84
.68
.77
.82
.84
598
305
566
288
406
366
339
.16
.63
.00
.87
.64
.13
.93
150.99
377
.27
266
242
126
185
147
148
67
172
.63
.00
.95
.30
.93
.09
.95
.10
298
123
0.
.24
.00
349-1.064
0.
0.
0.
000
861
881
235.92 Q S9S
331
324
161
221
218
191
83
205
.53
.00
.92
.34
.20
.84
.04
.17
0.
0.
0.
0.
0.
0.
1.
1.
1.
938
952
958
972
987
995
002 2378-TCDD AN
008
019
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 20:37 07/22/97
105
-------
Page No. 2
07/22/97
Compound/
M_2.... QC.Log Omit Why
Listing of W972832B.dbf
Matched GC Peaks / Ratio / Ret. Time
.RT. OK Ratio Total.Area... Area.Peak.1. . Area.Peak. 2. . Rel.RT Compound.Name.. ID.. Flags.
320-322
37C1-TCDD
328
328
13C12-TCDD
332-334
332-334
PeCDF
340-342
A
M
340-342
13C12-PeCDF
352-354
21:27
21:56
13 Peaks
DC NL 0:00
DC WL 17:56
19:13
20:40
20:50
21:18
21:41
5 Peaks
0
DC NL 0:00 RO
19:32
20:35
20:48
21:11
4 Peaks
1.
DC NL 0:00
DC WL 21:57 RO
22:17
DC SN 22:47 RO
23:20
23:29
23:41
23:56
24:08
24:20
24:24
24:34
24:41
25:09
25:18
25:30 RO
25:36
DCL SN _25i.50 RO^
DC SN 26:02 RO
26:09
15 Peaks
1.
DC NL 0:00 RO
23:26 RO
24:07 RO
24:23
0.80
0.70
.65-0.39
2.29
0.76
0.81
0.30
0.65
ay..
.32-1.78
1.37
0.50
1.46
1.04
1.49
1.53
1.49
1.61
1.52
1.54
1.48
1.51
1.50
1.52
1.56
1.88
1.72
1.86_
1.26
1.41
32-1.78
0.94
1.12
1.26
1.50
93.44
150.73
4,260.77
2.97
6.39
128.92
13.62
13,058.00
391.73
16.85
13,609.12
15.63
38.28
14,686.45
13,826.54
254.48
28,805.75
3VS i TCDD / Ps
8.37
120.95
2,452.32
12.73
1,604.19
9,492.16
831.88
626.28
649.97
811.00
1,927.00
1,372.68
2,083.45
1,983.09
2,048.47
50.52
171.71
a.49_
15.05
173.81
26,278.53
3.98
29.70
31.31
12,625.52
41.56
62.03
128.92
13.62
13,058.00
391.73
16.35
16.54
6,586.42
6,140.56
100.53
1,456.86
959.07
5,738.29
498.01
386.01
391.89
492.00
1,150.00
825.94
1,250.63
1,196.86
1,246.94
37.30
108.48
101.54
18.05
19.03
7,578.55
51.88 1.031
88.70 1.054
0.903-1.097
0.000
0.862
0.924
0.994
1.002 37C1-TCDD SUR1
1.024
1.042
0.903-1.097
0.000
21.74 0.939
8,100.03 0.990 13C12-1234-TCDD RSI
7,685.98 1.000 13C12-2378-TCDD IS1
153.95 1.018
0.904-1.081
0.000
0.900
995.46 0.914
0.934
645.12 0.957
3,753.87 0.963
333.87 0.971
240.27 0.982
258.08 0.990
319.00 0.998
777.00 1.001 12378-PeCDF AN
546.74 1.008 _ _. _ _
832.82 1.012
786.23 1.031 23478-PeCDF AN
801.53 1.038
19.81 1.046
63.23 1.050
L.059
1.068
72.27 1.072
0.835-1.165
0.000
16.09 0.961
15.06 0.989
5,046.97 1.000 13C12-PeCDF 123 IS2
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 20:37 07/22/97
106
-------
Page No. 3 Listing of W972832B.dbf
07/22/97 Matched GC Peaks / Ratio / Ret. Time
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2. . Rel.RT Conpound.Name.. ID.. Flags.
24:40 RO 2.01 119.67 94.40 46.93 1.012
DC SN 24:58 RO 1.31 30.17 1.024
25:08 1.46 11,306.18 6,702.08 4,604.10 1.031 13C12-PeCDF 234 SOR2
DC SN 26:08 1.53 29.93 1.072
352-354 5 Peaks 24,112.38
PeCDD
356-358 DC NL 0:
23:
DC SN 23:
DC SN 24:
24:
24:
24:
M 25:
25:
A 25:
25:
25:
26:
DC SN 26:
00
39
52
14
24
33
43
00
12
18
31
40
03
09
1.
RO
RO
RO
RO
RO
RO
32
1
1
0
1
1
1
1
1
1
0
1
1
1
2
-- AOOVB:
-1.78
.28
.47
.75
.28
.44
.52
.48
.85
.57
.54
.55
.42
.52
.74
356-358 10 Peaks
13C12-PeCDD
368-370 DC NL 0:
DC SN 23:
DC SN 24:
DC SN 24:
DC SN 24:
25:
25:
DC SN 25:
DC SN 26:
00
25
32
43
57
31
40
56
03
1.
RO
RO
RO
RO
RO
RO
RO
32
1
0
0
0
0
1
1
1
1
368-370 2 Peaks
HxCDF
374-376 DC NL 0:
27:
27:
27:
27:
27:
28:
28:
28:
28:
AN 28:
M 28:
00
05
14
23
32
42
04
11
17
31
40
43
1.
RO
RO
05
1
1
1
1
1
1
1
1
1
1
1
1
-1.78
.09
.32
.48
.46
.68
.49
.46
.88
.02
-1.43
.20
.31
.2S ._
.56
.19
.31
.16
.18
.52
.24
.39
.20
r»-ur
3.
490.
10.
15.
844.
585.
418.
571.
72.
28.
484.
187.
143.
6.
3,827.
4.
8.
6.
9.
5.
6,929.
735.
19.
16.
7,665.
/
93
96
83
17
22
53
99
20
97
79
59
33
28
58
86
29
21
94
34
92
82
38
28
71
20
I /
fecuu foix
292
498
353
250
415
44
17
294
109
36
4,144
436
.16
.43
.12
.17
.00
.61
.50
.45
.78
.48
.66
.30
198
345
0.
.30
.79
232.41
163
224
28
32
190
77
56
2,785
299
.32
.00
.36
.50
.14
.55
.80
0.
.16
.08
918-1.027
0.000
0.927
0.935
0.950
0.956
0.962
0.969
0.980
0.988
0.992
1.000 12378-PeCDD AN
1.006
1.021
1.025
843-1.157
0.000
0.918
0.961
0.969
0.978
1.000 13C12-P6CDD 123 IS3
1.006
1.016
1.021
21.
542.
1_992.,
116.
199.
261.
1,370.
710.
93.
223.
61.
449.
71
80
17
79
60
36
44
05
23
66
30
00
307
.77
_ r.117.47
81
108
147
734
383
63
123
35
245
.24
.53
.98
.62
.63
.17
.67
.60
.00
235
0.
.03
956-1.053
0.000
0.961
874J7Q- 0-966
52
91
113
635
326
41
99
25
204
.14
.07
.38
.32
.42
.62
.99
.70
.00
0.972
0.977
0.983
0.996 123478-HxCDF AN
1.000 123678-HxCDF AN
1.004
1.012
1.017 ~
1.019 234678-HXCDF AN
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 20:37 07/22/97
107
-------
Page No.
07/22/97
Compound/
Listing of W972832B.dbf
Matched GC Peaks / Ratio / Ret. Time
M_Z QC.Log Omit Why . .RT.
AN
M
374-376
13C12-HXCDF
384-386
384-336
HXCDD
390-392
A
AN
M
390-392
13C12-HXCDD
402-404
402-404
29:26
29:30
13 Peaks
DC NL 0:00
27:04
27:13
28:04
28:11
DC SN 28:22
28:42
DC SN 28:52
DC SN 28:57
DC SN 28:59
DC SN 29:10
29:26
DC SN 29:37
29:44
DC SN 29:53
7 Peaks
DC NL 0:00
27:37
DC SN 27:58
28:05
28:18
28:27
28:28
28:50
28:55
29:13
3 Peaks
DC NL 0:00
DC WL 27:26
DC WL 27:29
DC WL 27:34
DC WL 27:39
DC WL 27:49
DC SN 28:10
DC SN 28:18
28:51
28:55
29:12
DC SN 29:32
DC SN 29:36
3 Peaks
OK
0
RO
RO
RO
RO
RO
RO
RO
RO
RO
1.
RO
RO
1.
RO
RO
RO
RO
RO
RO
RO
RO
Ratio Total. Area
1.37
1.20
.43-0.59
0.40
0.42
0.93
0.50
0.53
0.57
0.51
0.46
1.07
0.84
0.69
0.52
0.77
1.14
0.35
. — — _ _ av\oi
05-1.43
1.40
1.25
0.63
1.28
1.24
1.21
1.09
1.56
1.23
1.37
05-1.43
0.83
0.83
1.03
2.72
1.23
0.56
0.58
0.74
1.25
1.21
1.22
2.82
1.27
51
112
6,183
18
39
22
6,808
7,160
32
6,328
36
6
13
25
5,297
22
25
25
25,681
18
1,387
7
246
6,490
116
111.
72.
1,343.
555,
10,322.
... Area. Peak. 1. . Area. Peak.
.20
.20
.30
.56
.26
.33
.72
.28
.50
.01
.94
.34
.02
.05
.37
.68
.04
.05
.51
G* / Hv
t 1 OX
.57
.69
.77
.08
.96
.30
.30
.35
.00
.04
.72
29
61
13
14
2,260
2,491
2,133
1,821.
18.
.60
.10
.26
.01
.92
.50
.38
.86
.84
21
51
31
15
4,547
4,668
4.194
3,475
16
2. .
.60
.10
0.
.34
.12
.80
.78
.63
.51
.58
Rel . RT Compound . Name . .
1.044 123789-HXCDF
1.047
858-1.142
0.000
0.960
0.966
0.996 13C12-HXCDF 478
1.000 13C12-HXCDF 678
1.007
1.018 13C12-HXCDF 234
1.024
1.027
1.028
1.035
1.044 13C12-HXCDF 789
1.051
1.055
1.060
ID. . Flags
AN
SUR3
IS4
ALT2
ALT1
C* FIT"! T7rtl 1 nua
770.
138.
3,589.
63.
58.
50.
740.
321.
21
27
18
77
00
40
00
08
617
107
2.901
52
53
32.
603,
233.
0.949-1.015
.48
.81
.78
.53
.30
.30
.00
.96
0.000
0.955
0.967
0.971
0.979
0.984
0.984
0.997 123478-HxCDD
1.000 123678-HxCDD
1.010 123789-HXCDD
AN
AN
AN
0.965-1.035
6.
7.
5.
4.
6.
4.
5.
16.
3,283.
5,337.
5,495.
8.
9.
14,116.
.27
.86
.78
70
62
48
56
51
74
38
46
74
62
58
1,821.
2,923.
3,018.
71
55
65
1,462.
2,413.
2,476.
03
83
81
0.000
0.949
0.950
0.953
0.956
0.962
0.974
0.979
0.998 13C12-HXCDD 478
1.000 13C12-HXCDD 678
1.010 13C12-HXCDD 789
1.021
1.024
SUR4
IS5
RS2
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 20:37 07/22/97
108
-------
Page No. 5
07/22/97
Compound/
M_2.... QC.Log Omit why
HpCDF
408-410
M
408-410
13C12-HpCDF
418-420
418-420
HpCDD
424-426
424-426
13C12-HpCDD
436-438
436-438
OCDF
442-444
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
SN
SN
SN
SN
WH
4
NL
SN
2
NL
SN
SN
SN
WH
2
NL
SN
2
NL
SN
SN
SN
SN
SN
SN
SN
Listing
Matched
. ,RT. OK
0:
30:
31:
31:
31:
31:
31:
32:
32:
32:
00
56
10
17
29
45
56
04
07
24
0.
RO
RO
RO
RO
RO
of W972832B.dbf
GC Peaks / Ratio
Ratio Total. Area.
38-1.20
1.
1.
0.
0.
1.
1.
0.
2.
1.
1.
30
12
93
99
92
10
78
26
41
19
Peaks
0:
30:
32:
32:
00
56
07
35
0.
RO
RO
12.
501.
102.
176.
13.
12.
11.
16.
60.
12.
840.
/ Ret. Time
. .. Area . Peak . 1 .. Area . Peak . 2 . . Rel.RT Compound. Name. .
.81
.00 265.00
,77 49.39
47 87.82
02
66
14
08
32 41.70
19
56
37-0.51
0.
0.
0.
1.
Peaks
0:
31:
31:
31:
31:
31:
32:
00
12
23
33
33
47
07
0.
RO
RO
RO
RO
77
42
43
06
11.
3,566.
2,501.
16.
6,067.
UM^nc
88-1.20
1.
1.
1.
0.
0.
1.
3.
20
01
79
80
52
04
94
Peaks
0:
31:
31:
32:
00
11
47
04
0.
RO
RO
7.
1,024.
8.
3.
6.
780.
8.
1,804.
68
79 1,061.60
02 750.86
46
31
* / Hn<"tnn Prt T 7 nw«
/ npv. uu c o x JL ows —
38
40 515.83
61
98
53
13 397.75
59
53
88-1.20
0.
0.
1.
1.
Peaks
0:
30:
31:
31:
32:
32:
32:
32:
00
37
38
54
06
11
24
35
0.
RO
RO
RO
RO
RO
RO
RO
88
82
06
44 - -
9.
19.
2,699.
29.
2,729.
HpCDD
30
69
69 1,389.78
42 20.73
11
Octa-CDD and CD
76-1.02
1.
0.
0.
0.
0.
3.
2.
1.
50
54
43
29
36
00
07
32
4.
7.
7.
1.
8.
4.
15.
7.
59
58
79
61
00
18
50
24
0.996-1.045
0.000
236.00 1.000 1234678-HpCDF
53.38 1.008
88.65 1.011
1.018
1.026
1.032
1.037
29.57 1.038 1234789-^>CDF
1.047
0.935-1.130
0.000
2,505.19 1.000 13C12-HpCDF 678
1,750.16 1.038 13C12-HpCDF 789
1.053
0.976-1.006
0.000
508.57 0.982
0.990
0.993
0.993
382.38 1.000 1234678-HpCDD
1.010
0.968-1.032
0.000
0.981
1,309.91 1.000 13C12-HpCDD 678
14.42 1.009
0.883-1.117
0.000
0.894
0.924
0.932
0.938
0.940
0.946
0.952
ID. . Flags.
AN
AN
IS6
SOTS
AN
IS7
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 20:37 07/22/97
109
-------
Page No. 6 Listing of W972832B.dbf
07/22/97 Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z. . . . QC.Log Omit 'ihy ..RT. OK Ratio Total .Area. .. Ar ea. Peak. 1. . Ar ea. Peak. 2. . Rel.RT Compound. Name. . ID.. Flags.
DC SN 33:34 RO 0.48 10.89 0.981
DC SN 33:47 RO 0.31 6.75 0.987
M 34:21 RO 0.64 37.80 17.80 28.00 1.003 OCDF AN
DC SN 34:28 RO 1.07 9.22 1.007
DC SN 34:39 RO 0.28 2.00 1.012
DC SN 34:44 RO 0.26 2.42 1.015
DC SN 35:03 RO 1.72 9.70 1.024
DC SN 35:20 0.97 20.30 1.032
DC SN 35:44 RO 0.73 6.86 1.044
DC SN 35:58 RO 1.14 9.28 1.051
442-444 1 Peak 37.80
OCDD 0.76-1.02 0.883-1.117
458-460 DC NL 0:00 0.97 5.23 0.000
M 34:14 0.80 197.60 87.60 110.00 1.000 OCDD AN
DC SN 34:43 RO 2.05 5.67 1.014
458-460 1 Peak 197.60
13C12-OCDD 0.76-1.02 0.996-1.005
470-472 DC NL 0:00 RO 1.30 3.86 0.000
34:14 0.84 2,018.47 920.56 1,097.91 1.000 13C12-OCDD IS8
DC WH 34:31 RO 0.69 29.48 1.008
DC WH 34:38 RO 0.54 12.64 1.012
DC WH 34:44 RO 1.30 10.00 1.015
470-472 1 Peak 2,018.47
Column Description "Why" Code Description QC Log Desc.
M_Z -Nominal Ion Mass(es) HL-Below Retention Time Window A-Peak Added
..RT. -Retention Time (mm:ss) WH-Above Retention Time Window K-Peak Kept
Rat.l -Ratio of M/M-t-2 Ions SN-Below Signal to Noise Level D-Peak Deleted
OK -RO=Ratio Outside Limits
-------
PileiH972832 #1-797 Acg:22-JUL-1997 15:12:08 OC EH- Voltage SIR 70SE Soite:21324
303.9016 F:2 BSUB (256, 30, -3.0) PXD(9,5,5, 0. 05%, 85296. 0, 1. 00\,X, T) Sxp:EPCUS2
TRIANGLE LABS Text :M2 3-OUTLET-RUN 2 TLI#42299A
100* A8.57X7
ao:
60:
40:
20:
o:
A4.69E7
A8.10B7
AS.80S7
A6.83E7
A2.20E7
.ass
17:00 18:00 19': 00 20:00 21:00
Pil»>tt972832 #1-797 Acg,22-
-------
Pile:H972832 91-797 Acq:22-JVL-1997 15:12:00 OC SI* Voltage SIR 70SB Noiae:9565
319.8965 P:2 BSUB(2S6,30,-3.0) PXD(7,5,3,0.05*,38260.0,1.00*,P,T)
TRIANGLE LABS Text:M23-OUTLST-RUB 2 TLI942299A
100
80
60
40.
20.
0
\ A2. 67B6
: 1
; II
': A1.83E6 A1.85E6
'• A A1.39E6 1 ,„ „,„, Al. 2 7B6 \
fl A6.73E5 /V 1 A2.06E6 A J\ .A
i. A - A. A Jv/v (\ /V\
18:00 15:00 20:00
Exp:EPCUS2
C9.1S5
A1.72E6
AK.80SS\\ A6.20E5
f\^J brs. A . .
.7.3ES
.5.5B5
.3. TBS
ii.ass
21:00 22:00 Time
Pile:tf972832 91-797 Acq:22-JUL-1997 15:12:00 OC £1* Voltage SIR 70SE Noise: 3403
321.8936 P:2 3303(256, 30, -3.0) PXD(7,S,3,0.05*,13612.0,1.00*,P,T)
TRIAmLS LABS TfXt:M2 3 -OUTLET-SIX 2 TLI942299A
1001
80.
60.
40.
20.
0
A3.32B6
A
A2.96E6 1
Ai A2.36E6 11 A1.62E6
\ A1.35E6 f\ lii 73S6 h ^
It 1 (1 I L ™A • / JZkO M r*
..ILA/l. . ./Wv A. /
10:00 15:00 20:00
, AI
v\
Sxp:EPCUS2
C9.8BS
A2.05B6
/I h
\ A8.87B5
fill A
.7.8B5
.5.9B5
.3.9B5
.2.0ES
21:00 22:00 Time
Pila:W972832 91-797 Acq:22-JUL-1997 15:12:00 OC EH- Voltage SIR 70SB Noise, 10094
331.9368 P:2 BSVB (256,30, -3. 0) PXD(7,5,3, 0.05%, 40376. 0,1. 00\,P,T)
TRIANGLE LABS Text:U23-OUTLET-RUN 2 TLI942299A
1005
80.
60.
40;
20;
0;
A6.
1
10:00 15:00 20:00
9E7
A6..
\l
Exp:SPCU32
r!.6E7
14E7
V
.1.3E7
.9.9E6
.6.6E6
.3.3E6
O.OSO
21:00 22:00 ' Time
Plle:W972832 91-797 Acq:22-JVL-1997 15:12:08 OC Elf Voltage SIR 70SS Boiaes4416
333.9338 P:2 BSUB(256,30,-3.0) PXD( 7,5, 3,0.05*, 17664. 0,1. 00%,F, T)
TRIANGLE LABS Text:M23-OUTLET-RUS 2 TLI942299A
100* A0.,
80;
60;
40;
20;
o'-
/
10:00 15:00 20:00
OE7
A7.t
j\
I /
Sxp:EPCUS2
2.0E7
-9E7
v
.1.6S7
.1.2B7
'.8.2E6
'.4.1E6
O.OSO
21:00 22:00 Time
Pile:tT972832 91-797 Acq:22-JVL-1997 15:12:00 OC SH- Voltage SIR 70SE Noise, 1487
327.8847 P:2 BSUB (256, 30, -3 . 0) PKD(7,5, 3,0.051,5948. 0,1. 00*,P,T) ExpsBKVS2
TRIANGLE LABS Text :H23-OOTLST-RJX 2 TLI942299A
1003
80;
60;
40;
20;
0;
18:00 15:00 20:00
Al.
/
1E8 3.0E7
-2.4B7
.1.8E7
.1.2E7
.6.1B6
o.oso
21:00 22:00 Time
Plle:W972832 91-797 Acq:22-JUL-1997 15:12:00 OC BI+ Voltage SIR 70SE
330.9792 P:2 Bxp>BPCUS2
TRIANGLE LABS Text:K23-OUTLST-RVN 2 TU942299A
ion
80;\
60;
40;
20;
o-
17:51 10:3* 18/£? 19tJJ 19:48 20:20
A* *_ A i^^.*/vJ^*\ .^^"t 1 9 • ^ y A. MSA A_
A n r\F^\ n f\f\ AJ*\ r
\ \ \ V i
I \M i u
M v V V
18:00 15:00 20:00
/»^u\
•N/V^V
20:55 21»28 21:5022:08 _2.8S7
A"N>vv*A* wt/A t**\ A X\ ^*l . •
\pV^ fMA/1 ff
v \l U
V
.2.2S7
.1.7B7
1.1B7
5.6B6
o.otto
21:00 22:00 ' Time
112
-------
Pile:tT972B32 #1-797 Acq: 22-JUL-1997 15:12:08 OC £Z> Voltage SIS 70SS Noiae:2421
339.8597 P:2 BSVS(256, 30,-3.0) PXD(7,5,3, 0.05*,9684.0,1. 00*,P,T) Sxp:EPCUS2
TRIANGLE LABS Text:K23-OUTLET-RUN 2 TLI»42299A
100* A5.7.4S7
ao:
22:00 23:00 24*00 25:00
Pile:!f972832 #1-797 Accj:22-JUL-1997 15:13:08 OC XL* Voltage SIR 70SS Noise: 1209
351.9000 P:2 BSUB(256,30, -3.0) PXD(7,5,3,0.05*,4836.0,1.00*,P,T) Exp:EPCUS2
TRIANGLE LABS Text:lt23-OUTLST-KUa 2 TLIt42299A
lOOSt A7.58S7
601
40:
20:
A1.46E7
A1.68S7
4.98S6
XV ^-
A1.25E7
AA
22:00 23:00 24:00 25:00
Plle:tf972832 #1-797 Acq:22-JUL-1997 15:12:08 OC ZT+ Voltage SIR 70SE Noise: 1765
341.8567 P;2 BSUB(256,30,-3.0) PXD(7,5,3,0.05*,7060.0,1.00*,P,T) Bxp:EPCUS2
TRIANGLE LABS Text :M23-OUTLET-BUR 2 TLI#42299A
100» A3.75S7
80:
26:00
60:
40:
20:
A9.95E6
A7.B6S6
26:00
eo:
60:
40:
20:
ol.
A6. 70B7
22:00 23:00 24:00 25:00
Pile:W972832 #1-797 Ac
-------
Fila:lf972832 91-797 Acq:u-tiUii-1997 15s 12108
-------
Pile:H972832 #1-423 Acq:22-JUL-1997 15:12:08 OC El* Voltage SIR 70SE Nolae:5922
373.8208 P:3 BSUB(2S6, 30,-3.0) PXD( 7,5,3, 0. 05%, 23 688. 0, 1.00*, P, T) Sxp:SPCUS2
TRIANGLE LABS Text :K2 3-OUTLET-RUB 2 TLI#42299A
27:00 27:12 27:24 27:36 27:48 28:00 28:12 28:24 28:35 28:48 25:00 25:12 25:24 25:35 25:48
Pile:W972832 #1-423 Acqt22-JUL-1997 15:12:08 OC EH- Voltage SIR 70SE Noiae:4936
375.8178 P:3 BSUB(256,30,-3.0) PKD(7,5,3, 0. 05*, 19744.0,1. 00*,P,T) Sxp:EPCUS2
TRIANGLE LABS Text:M2 3-OUTLET-RUB 2 TLI#42299A
100* A8.75B6
27:00 27:12 27:24 27:35 27:48 28:00 28:12 28:24 28:35 28:48 29:00 29:12 29,24 29:36 25:48
Plle,W972832 #1-423 Aeq:22-JUL-1997 15,12:08 OC EH- Voltage SIR 70SS Soiae,3134
383.8639 Pi3 BSUB1256,30, -3.0) PXD(7,5,3, 0.05*, 12536. 0,1. OO*,P,T) Exp:SPCUS2
TRIANGLE LABS Text :M2 3-OUTLET-RUB 2 TLI#42299A
100H A2.4527
... " '."" A1.82E7
80:
60:
40:
20:
o:
uug
ao:
60:
40:
20:
ol
JU..+JJS/
A7.35E6
J /A.
A3 . OSES \ f \ A
A / I Ml.4U€ / \A
/ YJ V^x /\ rv 1 v ^
A2.80E6
A1.24E6/\
so:
eo:
40:
20:
0:
A6.36SS
A2.35B
A
/V
A1.13SS
. A-
/V3.2525
AL
A2.4SE6
A1.00S6
6 f\
^ \-
i i i I i t l i i I l i i i i I i i i i i I i t i i i i i i 1 i i |*i i i 'i i I i ^ M I l i l l i I f i i i rl i l i i i [ i i i i i I i i i 11 I i i ' i i | i i i i i | i i i
27:00 27:12 27:24 27:35 27:48 28:00 28:12 28:24 28:35 28:48 25:00 25:12 25:24 25:35 25:48
Pile,W972B32 #1-423 Acqi22-JUL-1997 15:12:08 tX Eli- Voltage SIR 70SS Soiae:7751
385.8610 P,3 BSUB(256,30,-3.0) PXD(7,5,3, 0. OS*,31004. 0, 1. 00*,P, T) Bxp:BPCUS2
TRIANGLE LABS Text :M23-OUTLET-RUB 2 TLI#42299A
100H A4.5527 A4.19S7
80:
eo:
40:
20:
A3.48E7
^3.8S6
.3. OE6
2.3S6
1.5S6
7.SS5
O.OEO
Time
2.555
2.3E6
1.8E6
1.2E6
5.8E5
O.OEO
Time
7.7E6
5.255
L4.5E5
.3.1B5
'-1.5E6
O.OEO
Time
1.5E7
'.1.2E7
La.525
15. OS5
13.025
O.OEO
Tla*
' '27:00' 27:12 27:2"4 27:35 27:48 28:00 28:12 28:24 28:35 28:48 25:00 25:12 25:24 25:35 25:48
Plle:W972832 #1-423 Acq:22-JUL-1997 15,12:08 QC SI+ Voltage SIR 70SE
392.9760 Ps3 Sxp:EPCUS2
TRIASOLB LABS Text,M23-OUTLBT-RUB 2 TLI#42299A
27:17 27:49 M.Oi 28:13 „.„ 29,00 29sl9 29,38 25:51^1.427
40:
20:
26,59
27:00 27^12 27:24 27:35 27:48 28:00 28:12 28:24 28:35 28:48 25:00 25:12 29:24 25:35 25:48
-T
T
T
11.127
18.525
.5.725
.2.525
O.OXO
Tim
Plle,m72832 #1-423 Acq:22-JUL-1997 15:12:08 OC I
445.7555 F:3 Sxp:EPCUS2
TRIANGLE LABS Text :H23-OUTLET-RUN 2 TLI#42299A
25:55
Voltage SIR 7OSS
60:
40:
20:
o.
25:40
25:51
' 27: 00 '27:12 '27:24 '27:35' 27:48 '28100 '28:12 '28:24 '28:35' 28:48 '25:00 '25:12 ' 25:24 ' 25^35'25^48 '
,.5.824
.5.424
.4.124
.2.724
.1.424
O.OEO
TltM
115
-------
Pile:H973B33 »l-433 Xeq: 23- JUL- 1997 15:13:08 OC BSf Voltage SIR 70SS Hoiaei54ia
389.8156 P:3 B3UB(256,30, -3.0) PXO( 7, 5,3, 0. OS*,21672. 0,1. 00*,P,T) Srp:EPCUS2
TRIANBLS LABS Text :tt2 3 -OUTLET- RUN 2 TLI142299A
ion
80.
60.
40.
20.
A3.S9E7
A
a
A7.70S6 I \ A8
TT
lose
A _ /V A -*-
27-24 27:36 27:48 28:00 28:12 28:24 28:3* 28:48
1.US7
.3.5E6
.6.4E6
.4.3E6
'.2.1S6
' O.OEO
29:00 25:12 29:24 29*: 3 6 Time
PiletW972832 *l-423 Acq:22-JUL-1997 15:12:08 OC SI* Voltage SIS 70SE Noime:3864
391.8127 P:3 BSOB(256,30,-3.0) PXD< 7,5,3, 0. 05*,15456.0, 1.0O*,P,T)
TRIANGLE LABS Text ltt2 3 -OUTLET- RUN 2 TU142299A
100*
so;
601
401.
",
20.
A2.90E7
A
ft
A6.17E6 \ A6
Srp:EPCUS2
.•toss
A . /V A -«-
27-24 27\36 27:48 28:00 28:12 28:24 28:jV 28:48
8.6E6
.6.8E6
.5.1E6
.3.4E6
.1.7E6
O.OEO
29:00 25:12 25:24 29': 3 6 Time
Pile:W972832 #1-423 Acq:22-JUL-1997 15:12:08 OC Elf Voltage SIR 70SE Noise: 1733
401.8558 P:3 BSUB(2S6,30,-3.0) PXD(7,5,3,0.05*,6932.0,1.00*,P,T)
TRIANGLE LABS Text: tS2 3 -OUTLET '-RUN 2 TLI#42299A
loot
30.
eo:
40:
201
A2.
A
N
1
27 24 ' 27': 3 6 ' 27:48 28:00 28:12 28:24 28:36 28:48
Sxp:EPCUS2
92B7 A3 . 02E7
A |\
ft
I
V 7 v_
9 . 2E6
'.7.4E6
.S.SE6
•.3.7E6
.1.8E6
O.OEO
25:00 25:12 25:24 2s':36 Time
Plle:W972832 #1-423 Acq:22-JUL-1997 15:12:08 OC Elf Voltage SIR 70SE Noise: 2083
403.8529 P:3 BSUB(256,30,-3.0) PXD(7,5,3,0.05*,8332.0,1.00*,P,T)
TRIANGLE LABS Text:M23-OUTLET-RUN 2 TLI#42299A
1003
so:
so:
' 40.
20:
A2.
I
Bxp:EPCUS2
41E7 A2.48E7
I It
ft
r.a.ose
.6.4E6
.4.8E6
_3~2E6~
.1.6E6
27:24 27\36 27:48 28:00 28:12 28:24 2a':36 28:48 25:00 25:12 25:24 29\36 Time
Plle:IT972832 #1-423 AG(j:22-JUL-1997 15:12 : 08 OC Elf Voltage SIR 70SE
392.9760 P:3 Bxp:SPCUS2
TRIANGLE LABS Text :M2 3 -OUTLET-RUN 2 TLI042299A
1003
80.
so:
40:
20.
o:
... 27:36 A27A.<577Af7 28:07*1" 28:25 .
f^*^/>^s*\/^J*/^^^ 38j.
V
V
27 24 27': 3 6 27:48 28:00 28:12 28:24 2s':3f 28:48
29 s 00 29 f 19
54.^*. *ArS*^^*n—J\ A *A*. /—**«*/-
£X\A/* \ /VA/w '
V
-1.4E7
.1.1E7
.8.6E6
_5. 7B6
.2.9E6
O.OEO
25:00 25:12 25:24 25:J« Tim»
116
-------
PileiV972832 #1-441 Acq:22-JUL-1997 15:12:08 OC ST+ Volt«£T» SJJl 70SE Noise: 4087
407.7818 P:4 BSUB (256, 30, -3 . 0) PKD( 7, 5,3, 0. 05%, 16348. 0, 1. 00\,P, T) X*p:XPCUS2
TRIANGLE LABS Text :H2 3 -OUTLET-RUN 2 TLI942299A
100% A2.98E6
80.
60.
40.
20.
Pllt
409.
TRIA
ion
so:
601
40.
201
Pile
417.
TRIA
1003
80:
50:
40:
20:
o:
file
419.
TRIA
100%
80:
601
40:
20:
01
Pile
430.
TRIA
1003
80:
601
40:
20:
o:
Pil»
479.
TSXA
100%
80:
601
401
201
o-
I I
/ \ A8.78B5
I \ A4.94E5/\ A4.17E5
-~-' V_-y^~V\/ V ^- "-j!f£f_-_^/\~ ^
30:48 31:00 31:12 31:24 3li36 31:48 32:00 32:12 32:24 32
:M972832 #1-441 Acq: 22-JUL-1997 15:12:08 OC XX* Voltage SIS 70SS BolMei3139
7789 Pi4 BSUB(2S6,30,-3.0) PXD(7,S,3,0.05*,125S6.0, 1.00*,P,T) SxptXPCUS2
JfOLE LABS Text:ll23-OUTLET-Stni 2 TLH42299A
A2.49B6
A
\\
1 \ A8.86ES
30:48' ' ' 31:00 ' '31:12' ' 31:24 ' 31:3ff ' ' '31:48' ' ' 32:00 ' ' '32:12 ' ' 32s24 ' ' 32
IW972832 #1-441 Acq:22-JUL-1997 15:12:08 OC SX+ Voltage SIS 70SS Boi**t3117
8253 Pi4 BSUB(256,30,-3.0) PKD( 7,5,3,0. 05t,12468. 0,1. 00\,P,T) Bxp:BPCUS2
HOLE LABS Toxt:M23-OUTLET-RUN 2 TLH42299A
A1.06E7
h
I >
A
IV • IV
30:48 31:00 31:12 31:24 3l':36 31:48 32:00 32:12 32:24 32
:W972832 #1-441 Acq: 22-JUL-1997 15:12:08 OC EI+ Voltage SIS 70SS Noises 4055
8220 Ps4 BSVB(256,30,-3.0) PKD(7,5,3,O.OS*,16220.Q,1.0Ot,P,T) SxpsEPCUS2
NGLE LABS Text:X23-OUTLST-RUll 2 TLIt42299A
A2.51B7
1 \ A1.7SX7
A
\
i\ l\^
30:48 31:00 31:12 31:24 31:36 31:48 32:00 32:12 32:24 32
:W972B32 #1-441 Acq: 22- JUL- 1997 15:12:08 OC Sit- Voltage SIR 70SB
9729 P:4 Bxp:BPCUS2
SOLE LABS TextiM23-OUTLBT-RUir 2 TLI*42299A
^~/i^-^V^~>^^~^^*~vH
30^48' ' ' 31:00 '•' 31:12 ' ' 31:24 ' ' ' 31:3ff ' ' ' 31:4« ' ' ' 32:00 ' ' '32:12' ' '32124' ' ' 32
SW972832 #1-441 Acq: 22-JUL-1997 15(12:08 OC XT* Voltage SIS 70SS
7165 P:4 SxptSPCUSa
HOLE LABS Text:M23-OUTLST-RUll 2 TLI*42299A
I 32:25
3°l" 3is09 Jl I A
Jv^JjdV^lK^^^ AWL/l
30^48 31:00 Jl:12 31:24 31:3* ' 31^48 ' ' 32:00 ' '32:12' '32:24 ' 32
9.1S5
'•.7.3ES
Is.sss
-3.6B5
•.i.ass
36 Tlae
C8.7S5
.6.9B5
-5.2B5
.3.5X5
.1.7E5
36 Time
3.4E6
-2.8E6
'-.2.1X6
•-1.4S6
.6.9ES
-O.OBO
36 Time
,7.6X6
'.6.1E6
-4.6B6
-3.0E6
-1 . 5B6
,0.0X0
36 Time
-1.1S7
"-8.7E6
.6.5E6
-4.3B6
.2.2X6
O.OSO
36 Time
.9.1B4
.7.2X4
.5.4X4
.3.6X4
.1.8X4
0.0X0
36 Time
117
-------
Pil»:»972B32 #1-441 Acq:22-3UL-^S?7 ISriSTiW QC ETf
423.7766 P:4 BSUB(256, 30, -3. 0) PKD(7,5,3,0. 05X, 8036
TRIANGLE LABS Ttxe:M23-OUTLET-RUN 2 TLI042299A
100* A5.16E6
80.
SO.
40.
20.
3
Fill
425.
TRU
1003
80.
60.
40.
20J
0'
3
Pile
435.
TRIA
100J
801
601
401
20.
0
3
File
437.
TRIA
1003
801
60.
40.
201
01
3.
Pll»
430.
TRIAi
iooa
80.
601
401
201
0'
31
I \
\
1:00 ' '31:06 ' '31112 ' 31:18 ' '31t24 31:30 31:3*
SW972832 01-441 Acqi22-JUL-1997 15 t 12:08 OC SZ+
7737 P:4 BSOB(256,30,-3.0) PXD (7, 5, 3, 0.05*, 6720
\NOLS LASS TmxttiaS-OUTLST-RUN 2 TLH42299A
AS.09E6
A
/ 1
j v_
1:00 31 1 06 31:12 31:18 31:24 31. -30 3l':36
tW972832 tl-441 Ac
-------
Fil»:H97i83* #1-441 Acq:22-JVL-i997 15:12:08 OC gjy- Voltage SIS 70SE Sois»:i819
441.7428 Ps4 BSU3(256,30,-3.0) PXD(7,5,3, 0. 05*, 7276. 0,1. OOX,F,T) Bxp:SPCUS2
TRIANGLE LABS T«Xt .-M2J-OOTLST-HDN 2 TLI042299A
31-00 32x00 33>00 34x00 35x00
File:tl972832 #1-441 Acq:22-JUL-1997 15x12:08 OC Elf Voltage SIR 70SE Soime:1213
443.7399 F:4 BSTJ3(256, 30,-3.01 PED(7,5,3, 0. 05X, 4852. 0,1. 00\,F,T) SxplSPCUS2
TRIANGLE LABS Text :H2 3'OUTLET-ROM 2 TLI*42299A
100* A3 8SS
901
801
701
601
501
401
301
lOj
01
A8.20S4
A6.66S4
A8.S7S4
A1.63ES
A1.01ES
A8.50E4
32:00 32s24
31x00 32x00 33x00 34x00
Flle:W972832 #1-441 Acq:22-JUL-1997 15:12:08 OC SI+ Voltage SIR 70SE
430.9729 F:4 Exp:EPCUS2
TRIANGLE LABS TeJCt:M23-OUTL*T-Rmi 2 TLIX42239A
33:13 11.At 34x14
30x40
,.J
801
701
601
501
401
301
201
Ol
35:00
34:52
35:28
31:00 32:00 33x00 34x00
File:W972832 #1-441 Acqs22-JOL-1997 15:12:08 OC KT* Voltage SIR 70SE
513.6775 F:4 Sxp:EPCUS2
TRIANOLS LABS Text:M23-QTJTLST-RUS 2 TLX142299A
31 39 32:29
32:54
35:00
O.OSO
36s00 Time
-1.2S5
ll.ISS
19.SS4
'•.8.3E4
17.1S4
15.9S4
14.7X4
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2.4S4
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36:00 Vioe
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L8.0S6
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13. 4E6
L2.3B6
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36:00 Time
31:00
32:00
33:00
34x00
35x00
36:00 Time
119
-------
F110:W972832 91-441 Acq:22-iJuL-19y7 13:11:08 OC ST+ voltage SIR /OSS noise:!
457.7377 F:4 BSUB (256, 30, -3.0) PXD(7,5,3, 0.05^,5168. 0.1. 00\,F,T) Sxp:EPOJS2
TRIANGLE LASS T fxt:M2 3-OUTLET-BOB 2 TLI942299A
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34:06 34:12 34:18 34:24 34:30 34:36
File:tf972832 #1-441 Aag:22-JUL-li97 15:12:08 OC BH- Voltage SIR 70SB Soil*: 1326
459.7348 Pt4 BSUB (256, 30,-3.01 rXD(7,5,3,0.05\,5304.0.1.00\,F.T) SjcpiBPCUS2
TRIANGLE LABS Text :M23-OUTLET-XOX 2 TLIt42299A
100* A1.21S6
ao:
60:
40:
34:42
0. OEO
Time
20:
3.5ES
.2.8E5
.2.1X5
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A6.11E4
A7.53B4
34:06 34:12 34:18 34:24 34:30 34:36
Fil»s«972832 #1-441 Acq:22-JUL-1997 15:12:08 QC BH- Voltage SIR 70SE Noise:1329
469.7779 F:4 BSUB(2S6,30,-3.0} PXD(7, 5,3, 0. 05\,5316. 0,1. 00\,F, T) BxptEPCUS2
TRIANGLE LABS Tm3tt:M23-OUTLBT-R01l 2 TLI942299A
IQOit A9.31S6
so:
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40:
20'.
34:42
O.OEO
Time
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34:06 34:12 34:18 34:24 34:30 34:36
Fil»:W972832 il-441 Acqt22-JUL~1997 15:12:08 OC EH- Voltage SIR 70SE Noise:1021
471.7750 F:4 BSUB(256,30, -3.0) PXD(7,5,3,0.05»t,4084.0,1.00\,F,T) Exp:BFCUS2
TRIANGLE LABS Text:M23-OUTLET-SUB 2 TLH42299A
lOOii A1.J.OS7
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40.
201
34:42 Time
2.7B6
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34:06 34:12 34:18 34:24 34:30
Pile:W972832 #1-441 Aoq:22-JUL-1997 15:12:08 OC XT* Voltage SIR 70SB
430.9729 P:4 Bjrp:BPCUS2
TRIANGLE LABS Text: 1123-OUTLET-BUT 2 TLX#42299A
100!t 35*AC 34^21
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40.
20:
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34:36
34:36
34:42
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34:06
34:12
34:18
34:24
34:30
34:36
34:42
O.OEO
Time
120
-------
Peak Locate Examination:22-JUL-1997:15:10 File:W972832
Experiment:EPCUS2 Function:2 Reference:PFK '
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File:W972832 #1-797 Acq: 22-JUL-1997 15:12:08 GC EI+ Voltage SIR 70SE '
303.9016 F:2 Exp:EPCUS2
Sample Text :M2 3 -OUTLET-RUN 2 TLI#42299A File Text : TRIANGLE LABORATORIES, INC.:: DBS::
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319.8965 F:2 Exp:EPCUS2
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321.8936 F:2 Exp:EPCUS2
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331.9368 F:2 Exp:EPCUS2
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-------
File:W972832 #1-797 Acq:22-JUL-1997 15:12:08 GC EI+ Voltage SIR 70SE
319.8965 F:2 Exp:EPCUS2
Sample Text:M23-OUTLET-RUN 2 TLI#42299A File Text:TRIANGLE LABORATORIES, INC.:: DBS
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File:W972832 #1-797 Acq:22-JUL-1997 15:12:08 GC EI+ Voltage SIR 70SE
321.8936 F:2 Exp:EPCUS2
Sample Text:M23-OUTLET-RUN 2 TLI#42299A File Text:TRIANGLE LABORATORIES
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Sample Text:M23-OUTLET-RUN 2 TLI#42299A File Text:TRIANGLE LABORATORIES,
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File:W972832 #1-797 Acq:22-JUL-1997 15:12:08 GC EI+ Voltage SIR 70SE
319.8965 F:2 Exp:EPCUS2
Sample Text:M23-OUTLET-RUN 2 TLI#42299A File Text:TRIANGLE LABORATORIES,
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Sample Text:M23-OUTLET-RUN 2 TLI#42299A File Text:TRIANGLE LABORATORIES
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File:W972832 #1-797 Acq:22-JUL-1997 15:12:08 GC EI+ Voltage SIR 70SE
331.9368 F:2 Exp:EPCUS2
Sample Text:M23-OUTLET-RUN 2 TLI#42299A File Text:TRIANGLE LABORATORIES
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-------
File:W972832 #1-797 Acq:22-JUL-1997 15:12:08 GC fil+ Voltage SIR 70SE
339.8597 F:2 Exp:EPCUS2
Sample Text:M23-OUTLET-RUN 2 TLI#42299A File Text:TRIANGLE LABORATORIES,
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File:W972832 #1-797 Acq:22-JUL-1997 15:12:08 GC EI+ Voltage SIR 70SE
341.8567 F:2 Exp:EPCUS2
Sample Text:M23-OUTLET-RUN 2 TLI#42299A File Text:TRIANGLE LABORATORIES,
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File:W972832 #1-797 Acq:22-JUL-1997 15:12:08 GC EI+ Voltage SIR 70SE
351.9000 F:2 Exp:EPCUS2
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File:W972832 #1-797 Acq:22-JUL-1997 15:12:08 GC EI+ Voltage SIR 70SE
2 TLI#42299A File Text : TRIANGLE LABORATORIES, INC.
339.8597 F:2 Exp:EPCUS2
Sample Text:M23-OUTLET-RUN
100%
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File:W972832 #1-797 Acq:22
341.8567 F:2 Exp:EPCUS2
Sample Text:M23-OUTLET-RUN
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-JUL-1997 15:12:08 GC EI+ Voltage SIR 70SE
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23:48 24100
File:W972832 #1-797 Acq:22
351.9000 F:2 Exp : EPCUS2
Sample Text :M2 3 -OUTLET -RUN
100%
80 j
60 j
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0
1 1 1 1 1 1 1 1 I I 1 •• i
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-JUL-1997 15:12:08 GC EI+ Voltage SIR 70SE
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File:W972832 #1-797 Acq:22-JUL-1997 15:12:08 GC EI+ Voltage SIR 70SE
339.8597 F:2 Exp:EPCUS2
Sample Text:M23-OUTLET-RUN 2 TLI#42299A File Text:TRIANGLE LABORATORIES
100%, A1.15E7
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File:W972832 #1-797 Acq:22-JUL-1997 15:12:08 GC EI+ Voltage SIR 70SE
341.8567 F:2 Exp:EPCUS2 I
Sample Text:M23-OUTLET-RUN 2 TLI#42299A File Text:TRIANGLE LABORATORIES, INC.:: DBS:
100% A7.77E6
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File:W972832 #1-797 Acq:22-JUL-1997 15:12:08 GC EI+ Voltage SIR 70SE
351.9000 F:2 Exp:EPCUS2
Sample Text :M23-OUTLET-RUN 2 TLI#42299A File Text :TRIANGLE LABORATORIES', INC.
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-------
File:W972832 #1-797 Acq:22
355.8546 F:2 Exp:EPCUS2
Sample Text:M23-OUTLET-RUN
100%
-JUL-1997 15:12:08 GC EI+ Voltage SIR 70SE;
2 TLI#42299A File Text:TRIANGLE LABORATORIES, INC.:: DBS
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File:W972832 #1-797 Acq:22
357.8516 F:2 Exp:EPCUS2
Sample Text:M23-OUTLET-RUN
100%
80 j
601
40 J
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-JUL-1997 15:12:08 GC EI+ Voltage SIR 70SE
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File:W972832 #1-797 Acq:22-
367.8949 F:2 Exp:EPCUS2
Sample Text:M23-OUTLET-RUN
100%
80J
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-JUL-1997 15:12:08 GC EI+ Voltage SIR 70SE
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-------
FilerW972832~Tfl^797 Acq:22-JUL-1997 15:12:08 GC EI+ Voltage SIR 70SE
355.8546 F:2 Exp:EPCUS2
Sample Text:M23-OUTLET-RUN 2 TLI#42299A File Text:TRIANGLE LABORATORIES
100%
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File:W972832 #1-797 Acq:22-JUL-1997 15:12:08 GC EI+ Voltage SIR 70SE
357.8516 F:2 Exp:EPCUS2
Sample Text:M23-OUTLET-RUN 2 TLI#42299A File Text:TRIANGLE LABORATORIES
100%
80 J
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40 j
20 J
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367.8949 F:2 Exp:EPCUS2
Sample Text:M23-OUTLET-RUN 2 TLI#42299A File Text:TRIANGLE LABORATORIES
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373.8208 F:3 Exp:EPCUS2
Sample Text:M23-OUTLET-RUN 2 TLI#42299A File Text:TRIANGLE LABORATORIES
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File:W972832 #1-423 Acq:22-JUL-1997 15:12:08 GC EI+ Voltage SIR 70SE
375.8178 F:3 Exp:EPCUS2
Sample Text :M23-OUTLET-RUN 2 TLI#42299A File Text:TRIANGLE LABORATORIES,,
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383.8639 F:3 Exp:EPCUS2
Sample Text :M23-OUTLET-RUN 2 TLI#42299A File Text: TRIANGLE LABORATORIES^
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373.8208 F:3 Exp:EPCUS2
Sample Text:M23-OUTLET-RUN 2 TLI#42299A File Text:TRIANGLE LABORATORIES
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383.8639 F:3 Exp:EPCUS2
Sample Text:M23-OUTLET-RUN 2 TLI#42299A File Text:TRIANGLE LABORATORIES
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Sample Text:M23-OUTLET-RUN 2
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375.8178 F:3 Exp:EPCUS2
Sample Text:M23-OUTLET-RUN 2 TLI#42299A File Text:TRIANGLE LABORATORIES
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373.8208 F:3 Exp:EPCUS2
Sample Text:M23-OUTLET-RUN 2
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File:W972832 #1-423 Acq: 22-JUL-1997 15:12:08 GC EI+ Voltage SIR 70SE
389.8156 F:3 Exp : EPCUS2
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407.7818 F:4 Exp:EPCUS2
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Sample Text:M23-OUTLET-RUN 2 TLI#42299A File Text:TRIANGLE LABORATORIES, INC.:: DBS::
100% 34:14 i
60J
40j
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0
33!24 33:36 33 I 48 34!00 34!12 ' 34:24 34 I 36 34148 ' 35:00 ' 35:12 35:24 ' 35 I 36
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.2.2E6
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Time
-------
File:W972832 #1-441 Acq:22-JUL-1997 15:12:08 GC EI+ Voltage SIR. 70SE
457.7377 F:4 Exp:EPCUS2
Sample Text:M23-OUTLET-RUN 2 TLI#42299A File Text:TRIANGLE LABORATORIES
100% A8.76E5
CO
, INC.
DBS : :
33124 33i36 33i48 34iOO 34il2 34i24 ' 34:36 ' 34:48 ' 35:00 ' 35:13
File:W972832 #1-441 Acq:22-JUL-1997 15:12:08 GC EI+ Voltage SIR 70SE
459.7348 F:4 Exp:EPCUS2
Sample Text:M23-OUTLET-RUN 2 TLI#42299A File Text:TRIANGLE LABORATORIES
100% A1.10E6
60 j
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34112 34:24 34:36 34:48 35:00 35:13 35:24 35:36
i
33:24 33:36
File:W972832 #1-441 Acq:22-JUL-1997 15:12:08 GC EI+ Voltage SIR 70SE
469.7779 F:4 Exp:EPCUS2 i
Sample Text:M23-OUTLET-RUN 2 TLI#42299A File Text:TRIANGLE LABORATORIES, INC.:: DBS::
100% 34;14
80 J
60 J
40 J
20J
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.2.4E5
.1.9E5
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33:24 33:36 33:48 34:00 34:12 34:24 34:36 34:48 35:00 35:12 35:24 35:36
.2.2E6
.1.8E6
.1.3E6
.9.0E5
.4.5E5
.O.OEO
Time
-------
File:W972832 ttl-441 Acq:22-JUL-1997 15:12:08 GC EI+ Voltage
441.7428 F:4 Exp:EPCUS2
Sample Text:M23-OUTLET-RUN 2 TLI#42299A File Text:TRIANGLE
100% A1.78E5
80 J
60J
40 j
20J
0
File:W972832 ttl-441 Acq:22-JUL-1997 15:12:08 GC EH- Voltage SIR 70SE
443.7399 F:4 Exp:EPCUS2 I
Sample Text:M23-OUTLET-RUN 2 TLI#42299A File Text:TRIANGLE LABORATORIES, INC.:: DBS::
100%. A2.80E5
SIR 70SE
LABORATORIES
INC. : : DBS : :
-i—i—I—i—i—|—i—I—I—I—I—I—I—I—I—I—I—I—i—r—i—I—i—i—r—i—I—i—r—I—I—I—i—i—r~~i—i—i—i—i—r—I—i—i—r
33i24 33:36 33:48 34:00 34:12 34:24 34:36 34:48
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33:24 33:36 33148 34100 34112 34124 34136 34148 35iOO 35il2
File:W972832 #1-441 Acq:22-JUL-1997 15:12:08 GC EI+ Voltage SIR 70SE j
469.7779 F:4 Exp:EPCUS2 I
Sample Text:M23-OUTLET-RUN 2 TLI#42299A File Text:TRIANGLE LABORATORIES, INC.:
100% 34;14
80-
eol
40 J
20 j
35:36
DBS: :
OJ
33:24 33:36 33:48 34:00 34:12 34:24 34:36 34:48
35:00 35:12
35:24
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.2.2E6
.1.8E6
.1.3E6
.9.0E5
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Time
-------
TLI Project: 42299A Method 23 TCDD/TCDF Analysis (DB-225)
Client Sample: M23-Outlet-Run 2 Analysis File: P973371
Client Project: Iron & Steel-Chicago
Sample Matrix: M23TRAIN Date Received: 07/01/97
TLI ID: 173-61-2ABCE Date Extracted: 07/17/97
Date Analyzed: 07/23/97
Sample Size: 1.000 Dilution Factor: n/a
Dry Weight: n/a Blank File: W972829
GC Column: DB-225 Analyst BB
Spike File: SPC2NF04
ICal: PF22206
ConCal: P973363
% Moisture: n/a
% Lipid: n/a
% Solids: n/a
Anafytes ; ' ^^at^^^v^^: 3*$*"^ > ^IW**^^ ' ^S«
2,3,7,8-TCDF 0.89
; Intenial Standard ' ^f-Jtaa&' ^i*f$' ' %Reco«ser|f QC Limits
13C12-2,3,7,8-TCDF 3.7 92.2 40%-130%
Recovery Standard . : '
0.73 21:02
'•- •-•• tSu^CvK- "• CVf
j .. txBD» fi 1
0.73 21:00
i&^t&n- U^f
—
Flags
—
Flags
13C12-1,23,4-TCDD
0.79 20:02
Data Reviewer.
Page 1 of 1
07/24/97
ONF_PSR vZOtt LARS 6.10.03
Triangle Laboratories, Inc.®
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 15:49 07/24/97
145
-------
Initial
....Date...
Data Review By:
Calculated Noise Area: n/a
The Total Area for each peak with an ion abundance ratio outside
ratio limits has been recalculated according to method requirements.
Page No. 1 Listing
07/24/97 Matched
Compound/
M_Z .... QC . Log Omit Why . . RT . OK
TCDF 0
304-306 DC NL 0
17
17
17
18
18
18
18
18
18
19
19
19
19
20
20
20
20
21
21
21
21
DC SN 21
22
:00 RO
of P973371B.dbf
GC Peaks / Ratio
Ratio Total. Area
.65-0.89
0.56
:18 0.80
:47
:53
0
.76
0.75
:01 0.71 1
:11 0.71
:26
:34
:42
0.73
0.70 1
0.
.75
:51 0.73 2
:00 RO
1.26
:19 0.71 2
:44
:59
:10
:22 RO
:32
:54
:02
:12
:26
:34
:52 RO
:17
22:56
0.70 1
0.70
0.
0.
0.
0.
0.
0.
0.
0.
18.
0.
0.
304-306 23 Peaks
13C12-TCDF
316-318 DC NL 0
0.
:00 RO
DC WL 19:44
DC WL 19:58 RO
21:00
21:10
21:
:34 RO
DC WH 22:12 RO
DC WH 22:42 RO
DC WH 22:59
73
95
74
74
73
76
72
70
29
72
70
15,
0
5
868
450
,073
665
421
,015
381
/ Ret. Time
. . . Area. Peak.
.44
.42
.15
.80
.90
.89
.78
.69
.31
,013.00
227
.16
,140.14
,268.20
673.55
871.42
65.10
600.
513.
495.
441.
456.
713.
0.
443.
41.
,847.
.03
,29
.99
38
.76
35
60
91
71
93
2
374
193
444
275
177
418
163
848
161
889
520
278
367
34
254
219
209
191
190
294
185
17
1. . Area, Peak.
.41
.36
.45
.06
.74
.32
.99
.24
.40
.40
.37
.02
.22
.74
.34
.74
.00
.37
.08
.79
.82
.57
.16
3
493
257
629
390
244
596
213
1,164
128
1,250
748
395
503
36
345
294
286
250
265
418
258
24
65-0.89
1.
0.
0.
0.
0.
0.
0.
0.
0.
316-318 3 Peaks
~i3C12-TCDD
332-334 DC NL 0:
0.
00 RO
33
86
51
73 2,
83
95
60
51
74
2,
1.
9.
8.
,142.
8.
16.
1.
1.
21.
166.
iti/^r\w
22
12
05
33
07
07
98
52
29
47
> / nw>i
65-0.89
2.
03
0.
55
902.
.78
3.67
8.59
1,239
4
9
2.. Ral.RT Compound. Name. . ID.. Flags.
0.787-1.099
.01
.79
.35
.84
.15
.46
.70
.07
.60
.34
.77
.18
.33
.68
.78
.29
.29
.62
.30
.97
.53
.34
.55
0
0
0
0
0
0
0
.000
.324
.847
.852
.358
.866
.878
0.884
0,
0.
0
.390
.898
.905
0.920
0.940
0.952
0.
0.
0.
0.
1.
1.
1.
1.
1.
1.
1.
.960
.970
978
995
002 2378-TCDF AN
010
021
027
041
061
092
0.952-1.048
.55
.40
.08
0.
0.
0.
1.
1.
1.
1.
1.
1.
000
940
951
000 13C12-2378-TCDF ISO
008
027
057
081
094
0.898-1.102
0.
000
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 15:49 07/24/97
146
-------
Page No. 2 Listing of P973371B.dbf
07/24/97 Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
18:46 0.76 6.88 2.98 3.90 0.947
19:49 0.79 1,685.42 741.30 944.12 1.000 13C12-2378-TCDD IS1
20:02 0.79 1,674.96 739.45 935.51 1.011 13C12-1234-TCDD RSI
20:42 RO 0.96 17.40 9.43 9.33 1.045
332-334 4 Peaks 3,384.66
Column Description 'Why" Cod* Description QC Log Desc.
H_Z -Nominal Ion Mass(es) WL-Below intention Tia» Window A-Peak Added
..RT. -Retention Time (mm:ss) WH-Above Retention Time Window K-Peak Kept
Rat.l -Ratio of M/M+2 Ions SN-Below Signal to Hois* Level D-Peak Deleted
OK -ROsRatio Outside Limits
-------
303.9016 3303(256, 30, -3.0) ?B>(5,3,l,0.10\,376.0,0.00\,r,r) XxpiDS225
atlAOaX LASS T*xt:M23-ODTLXT-SUX 2 TLH42299A
1001
80.
60.
40.
20.
0
A8.48X6
I
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305.8987 3803(256,30, -3,0) rXD(S,3,l,0.10\,672.0,0.00\,T,T) XxpiD3225
TRIAHSLX LASS T*xtsM23-OOTLXT-MUX 2 TLH42299A
1003
00.
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20.
A3.. 16X7
A1.25X7
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n/v A/vU U /U\A A/I A
^ MYuVyvViTTXJv 7\J\/Vxv/V /Vv/vyVV yv -^
-3.0X6
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0.0X0
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Fll*tP973371 tl-965 Aoyi23-JOL-1997 21(55(20 JET* Voltagrv SIX 70P tfoi*»,458
315.9419 3303(256, 30, -3.0) PXD(5,3,1,0.10\,1832.0,0.00\,F,F) XxpiD3225
TXIABSLX LABS Xart:M23-OOTLXT-XaV 2 TLIt42299A
1003,
80.
60.
40.
20.
0
A9.03E6
!\
2.2X6
.1.7X6
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.8.7X5
.4.4X5
0.0X0
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T±latP973371 tl-965 Acqt23-JOL-1997 21(55(20 XH- Voltage SIR 70P Hoiae,344
317.9389 3803(256, 30, -3.0) rXD(5,3,l,0.10\r1376.0,0.00\,T,T) XxptD3225
TXIAHGLX LASS Taxt:M23-OOTLXT-XUtr 2 TLXt42299A
iota
80.
60.
'40.
20.
0.
A1.24X7
1
J v
.3.1X6
_2.5Z5
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.6.1X5
0.0X0
17(00 10(00 ' 15(00 20(00 ' 21(00 22(00 25(00 T±m»
r±lm,P973371 tl-965 Aoq,23-JUL-1997 21(55(20 XH- ValtMy* SIX 70P
375.8364 X*ptDS225
XXIAJKLX ZABS Tarts X23-OnTLXT-XUB 2 TLH42299A
100J
80.
60.
40.
201
•
o:
Itfi44
1
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1
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.1.6X4
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0.0X0
17(00 ' ' 10(00 15(00 ' 20(00 ' ' ' 21(00 ' ' ' 22(00 ' ' ' 25(00 T±*»
•
14S
-------
319.8965 3303(256,30,-3.0) PXD(5,3,l,0.10\,S44.0,0.00*,r,r) XxptDB225
TRIABGLX LABS TerttM23-OOTLXT-XOf 2 TLXt42299A
1001
18,00 19iOO 20,09 21t00
ril»tP973371 U-965 Acqt23-JOL-1997 21i53t20 XH- Voltage SIX 70P 9oimmi212
321.8936 3303(256,30,-3.0) fXD(S,3,l,0.10\,848.0,O.OO^T,T) XfpiD3225
TRXAIKUl LA3S Text jMSJ-OtTTLET-iOlf 2 TLIt42299A
100*
A4.05XS
A3-26X5
22100
IB, 00 19 tOO 20,00
r±l*,P973371 U-965 Aoji23-JVL-1997 21t 53*20 XXI- Valtmgm SIX 70P
327.8847 BSU3(256,30,-3.0) PXD(5,3,1,0.10\,904.0,0.00\,P,T) KxpiD3225
TXIABSLX LABS Text I M23 -OUTLET-SUN 2 TLH42299A
100* A1.65K7
00:
60.
40.
20:
21 1 00
22100
-f-
18,00 19100 20 tM 21s 00
riletP973371 tl-965 Aoq,23~JUL-1997 21t53>20 JT* Voltage SIX 70P Ooif»*317
331.9368 BSUB(256,30,-3.0) PXD(5,3,l,0.10\,1268.0,0.00\,r,T) XxptDB225
TRIA1KLX LABS Text :M33-OUTLET-BUB 2 TLIf42299A
22 tOO
80.
so:
-40:
20:
10100 19,00 20:00 21,00
f±l»iP973371 tl-965 Aoqt23-JUL-1997 21153120 XX+ Voltage SIX 70P Hoi»»il57
333.9338 BSOB(256,30,-3.0) PXD(S,3,l,0.10\,62a.O,Q.OO^PfT) XxptDB225
TtlABGLX LABS TextiMZS-OUTLXT-XUV 2 XLIM2299A
22100
100]
80.
60.
40.
20.
0.
.36X6
.1.1X5
.8.8X4
.6.6X4
.4.4X4
-2.2X4
0.0X0
TLm*
,4.8X6
3.8X6
2.9X6
•-1.9X6
9.6X5
0.0X0
SLme
.2.2X6
.1.7X6
.1.3X6
.8-.7XS—
4.4X5
0.0X0
T±mm
-2.8X6
.2.2X6
J..7X6
.1.1X6
-5.5X5
18,00
19100
20:00
21,00
22s 00
0.0X0
Time
-------
ril»iP973371 tl-965 Acq»23-JUL-1997 21,53,20 KI+ Voltage SIX 70P
303.9016 Xzp,DS225
TJLXAHSLX LASS Tmxt,M23-OnTLXT-XON 2 TLIt42299A
18,51
17i47
20,54
80:
50:
40:
201
OJ
20,10
21134
JUVlAAA
22,17
A
-2.2X6
.1.8X6
.1.3X6
.a.axs
.4.4X5
17,00 18,00 19,00
Fil»,P973371 tl-965 Aoq,23-JUL-1997 21,53,20 tt+
315.9419 Xxp,DS225
XRIA1KLX LASS TmrtsM23-OOTLXT-Xinr 2 TLH42299A
100\
SO:
60:
40:
20:
o:
20,00 2)\00
Volt*g» SIX 70P
21 1 00
22 tOO
23,00
0.0X0
Tim
-2.2X6
.1.7X6
.1.3X6
.8.7X5
.4.4X5
17,00 18,00 19,00 20,00
rJLL»,P973371 tl-965 Acq,23-JOL-1997 21,53,20 XH-
319.8965 Xxp, 03225
TflAHSLX LABS T*XtlM23-OUTLST-XOX 2 XLIM2299A
18t46 19,50
21,00
SIX 70P
22,00
23,00
0.0X0
Tim
17,00 18,00 19,00 20,00 21,00
rHa,P973371 tl-965 Acq,23-JUL-1997 21,53,20 XH- Voltage SIX 70P
331.9368 Kxp,DB225
AWeUS LASS Text, M23-OUTLXT-BOX 2 TLH42299A
1001 19,49
80.
60.
40:
20.
2.2X6
.1.7X6
.1.3X6
.8.7X5
.4.4X5
17100 18,00 19,00 20,00 21,00
Til*,P973371 tl-965 Acq,23-JUL-1997 21,53,20 XX+ Volt*g» SIX 70P
-•92.9835 Xxp,DS225
LASS T*Xt,M23-OOTLXT-Mtnr 2 TLIt42299A
17,24 19,1819,4330,08 20j52
17*09." * - - -
22,00
23,00
.0.0X0
Tim*
17,00 18,00 19', 00 20,00 21,00
ilm,P973371 tl-965 Acq,23-JVL-1997 21,53,20 XX+ Volt*g» SIX 70P
30.9792 Xxp,DB225
TXIAIKLX LASS Twttttt23-OUTLXT-XBX 2 TUt42299A
16,42 17!33 *°'.°* 30t41
22,00
23,00
17,00
18,00
19,00
20,00
21,00
150
-------
f) 292,9825
8 383,9616
C 385.8987
0 315.3419
E 317.3389
F 319,8965
6 321,8936
H 327.8847
I 338.9792
tef, lass 292,9825 Peak top
Height ,51 volts Span 286 ppa
Systel f de n*e
Data file me
Resolution
Group nmter
lonlzatlon Mde
fl:P973371
1
Q*
VOLIRGE
388,3/w
j 336.9792
K 331,333
L 333,3338
H £5.8364
Channel I 338.9792 Peak top
Height .46wlts Span 286ppi
151
-------
TLI Project: 42299A
Client Sample: M23-Outlet-Run 3
Method 23 PCDD/PCDF Analysis (a)
Analysis File: W972833
Client Project:
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
Iron & Steel-Chicago
M23TRAIN Date Received:
173-61-3ABCE Date Extracted:
Date Analyzed:
1.000
n/a
DB-5
Dilution Factor:
Blank File:
Analyst
07/01/97
07/17/97
07/22/97
n/a
W972829
BB
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPX23704
WF54307
W972828
n/a
n/a
n/a
Anatytes
2,3,7,8-TCDD
12,3,7,8-PeCDD
12,3,4,7,8-HxCDD
12,3,6,7,8-HxCDD
12,3,7,8,9-HxCDD
1,2,3,4,6,7,8-HpCDD
12,3,4,6,7,8,9-OCDD
2,3,7,8-TCDF
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
12,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
12,3,7,8,9-HxCDF
1,2,3,4,6,7,8-HpCDF
12,3,4,7,8,9-HpCDF
1,2,3,4,6,7,8,9-OCDF
Totals
Total TCDD
Total PeCDD
Total HxCDD
Total HpCDD
Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF
' ••' ^** && " -* < m> eipc
0.06
020
0.04
0.93
0.40
0.94
EMPC 0.70
2.9
0.42
0.46
0.54
022
0.17
ND 0.03
0.36
EMPC 0.05
0.20
*mt(ng) Number DL EMPC
0.81 10 0.89
17 10 1 7
7.6 7
22 2
24.0 14
5.6 14
2.3 10 2.4
0.58 3 0.63
— &*fc^
0.65
1.52
1.37
120
1.31
1.06
0.77
1.45
1.51
125
1.35
1.39
1.07
0.91
'
HT
20:46
25:30
28:48
28:54
29:12
31:47
19:58
24:22
25:07
28:03
28:10
28:41
30:55
34:20
''•'
Flags
B_
B_
B_
ftefs
—
£i
^
Page 1 of2
XOTJ'SR riOO. LARS 6.10.03
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 20:52 07/22/97
152
-------
TLI Project:
Client Sample :
42299A
M23-Outlet-Run 3
Method 23 PCDD/PCDF Analysis (a)
Analysis File: W972833
muHnaf. aianoafws
13C,:-2,3,7,8-TCDF
I3C,2-2,3,7,8-TCDD
13C,2-l,2,3,7,8-PeCDF
13C,rl,2,3,7,8-PeCDD
13C,2-l,2,3,6,7,8-HxCDF
13C,2-l,2,3,6,7,8-HxCDD
13C,:-l,2,3,4,6,7,8-HpCDF
I3d2-l,2,3,4,6,7,8-HpCDD
13Cp-l,2,3,4,6,7,8,9-OCDD
SuffogatoStanda»teCI^A^ >,
*a-23,7,8-TCDD
13C,2-2,3,4J,8-PeCDF
13C,2-l,2,3,4,7,8-HxCDF
13C,2-l,2,3A7,8-HxCDD
13C,2-l,2,3,4J,8,9-HpCDF
.: Alternate Standards (Typ* A)
"Cu-U^J.S^-HxCDF
13C,2-2,3,4,6,7,8-HxCDF
Recovery Standards
13C,2-U,3,4-TCDD
13Ci:-l,2,3,7,8,9-HxCDD
Amf t*tm
AIIU.. JIM
3.7
3.8
3.8
3.8
3.8
3.6
33
3.0
4.0
Amfc
» %w)wov»fy
92.9
94.8
94.3
95.8
94.0
88.9
81.7
76.1
50.2
$ % Recovery
99.4
98.6
101
76.4
98.1
| % Recovery
97.8
97.1
^ •- O o
f\f* f in»i*»
vivutnitis
40%-130%
40%-130%
40%-130%
40%-130%
40%-130%
40%-130%
25%-130%
25%-130%
25%-130%
QC Limits
70%- 140%
70%- 140%
70%-140%
70%- 140%
70%- 140%
QC Limits
40%-130%
40%-130%
^.
P— (t-.
HBuO -,
0.77
0.77
1J3
1.51
0.49
1.19
0.46
1.01
0.88
8alte.f:y
1.49
0.53
1.34
0.42
Ratio
0.49
0.51
Ratio
0.81
1.26
wr* • irt__ :
RT Flags : .
19:56
20:45
24:21
25:29
28:10
28:53
30:54
31:46
34:13
JltI|||p|aM
20:47
25:07
28:04
28:48 QL^
32:07
HI Flags
29:24
28:41
RT -^'/FlagS"':
20:32
29:11
Data Reviewer:
07/22/97
Page 2 of 2
X237.PSR rZOO. LARS 6.10 03
Triangle Laboratories, Inc.®
801 Captola Drive • Durham, North Carofina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 20:52 07/22/97
153
-------
t-^-^i
^ *§><
-------
Data Review By:
Initial
\l r
....Date...
Calculated Hoise Area: 19.98
The Total Area for each peak with an ion abundance ratio outside
ratio limits has been recalculated according to method requirements.
Page No. 1 Listing
07/22/97 Matched
Compound/
M_Z. . . . QC.Log Omit Why . .RT. OK
TCDF 0 .
304-306 DC NL 0:
16:
17:
17:
17:
18:
18:
19:
19:
19:
19:
20:
20:
20:
21:
00 RO
59
12
36
53
21
41
05
27
43
58
26
40
57
53
of W972833B.dbf
GC Peaks / Ratio
Ratio Total. Area
.65-0.39
3.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
304-306 14 Peaks
13C12-TCDF
316-318 DC NL 0:
DC ML 18:
19:
19:
20:
20:
DC WH 20:
0.
00 RO
40
26
56
12 RO
25 RO
57 RO
62
77 4
80 2
76 22
75 16
76 17
76 12
76 19
75 8
79 7
77 16
77 6
74 4
84
31
139
43
.702
,695
,191
,832
,305
,122
,013
,702
,105
,661
,676
,610
587
399
,607
/ Ret. Time
... Area. Peak. 1. . Area. Peak.
.72
.95
.84
.00
.17
.19
.66
.71
.45
.29
.36
.81
.37
.76
.73
.29
2.049.
1,194.
9,588.
7.193.
7.492.
5.236.
8.190.
3,736.
3,144.
7,262.
2.906.
1,965.
268.
179.
96
27
60
73
36
15
91
36
77
19
28
13
30
47
2.652
1,501
12,602
9.638
9,812
6,386
10,822
4,966
3,960
9,399
3,770
2,645
319
220
65-0.89
5.
0.
0.
0.
1.
0.
0.
316-313 4 Peaks
TCDD
320-322 DC NL 0:
17:
18:
18:
19:
M 19:
D D CO 19:
DC SN 19:
20:
20:
20:
20:
20:
0.
00 RO
48
14
34
26
36
43 RO
57 RO
09
28
39
46
57 RO
15
87
83
77 17
04
96
59
18
5
117
73
,952
27
213
27
,266
wnr
65-0.89
1.
0.
0.
0.
0.
0.
0.
2.
0.
0.
0.
0.
0.
14
80
67
78
76
77
58
45
78
76
70
65
94
11
381
243
280
579
543
271
8
248
.52
.08
.50
.08
.56
.62
.38
.76
Tf 1
r i
.08
.61
.60
.90
.12
.00
.71
.87
.86
326.51
298
235
127
.05
.46
.76
33.
7.836.
16.
115.
29
98
17
61
40
10,115
15
120
2. .
0.
.99
.57
.40
.44
.83
.51
.80
.09
.52
.17
.53
.24
.46
.26
0.
.21
.10
.57
.69
Rel.RT Compound. Name. . ID.. Flags.
819-1.109
0
0
0
0
0
0
0
0
0
0
1
1
1
1
1
950
0
0
0
1
1
1
1
.000
.852
.863
.883
.897
.921
.937
.957
.976
.989
.002 2378-TCDF AN
.025
.037
.051
.098
-1.050
.000
.936
.975
.000 13C12-2378-TCDF ISO
.013
.024
.051
169.
97.
123.
249.
236.
108.
141.
123.
92.
67.
75
95
11
50
00
91
47
15
33
55
211
145
157
329
307
139
185
174
143
72
0.
.86
.65
.79
.62
.00
.95
.04
.90
.13
.18
349-1.064
0
0
0
0
0
0
0
0
0
0
0
1
1
.000
.858
.879
.895
.937
.945
.950
.961
.971
.986
.995
. 001 2378-TCDD ~ ~" AN
.010
Triangle Laboratories, Inc.® Analytical Services Division
801 Capftola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 20:52 07/22/97
154
-------
Page No.
07/22/97
Listing of W972833B.dbf
Matched GC Peaks / Ratio /
Ret. Time
Confound/
M_Z.... QC.Log Omit Shy . .RT. OK Ratio Total. Area... Area.Peak.1.
Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
320-322
37C1-TCDD
328
328
13C12-TCDD
332-334
332-334
PeCDF
340-342
D
A
M
D
21:
21:
DC SN 21:
21:
09
22
35
53
RO
RO
RO
0.75
0.92
0.47
0.94
13 Peaks
DC NL 0:
19:
DC SN 19:
20:
DC SN 21:
21:
00
09
56
47
04
15
3 Peaks
DC NL 0:
DC WL 17:
DC WL 18:
DC SN 19:
20:
20:
20:
21:
21:
DC SN 21:
DC SN 21:
DC SN 21:
22:
22:
00
44
08
26
08
32
45
06
25
34
38
54
05
16
0.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
65-0.89
2.35
4.19
0.46
0.42
1.23
0.81
0.77
0.98
1.12
1.66
0.60
3.11
1.05
2.41
7 Peaks
*lu
DC NL 0:
22:
D SN 22:
DC SN 22:
DC SN 22:
23:
23:
23:
23:
24:
24:
24:
24:
24:
D SN 24:
25:
25:
00
13
22
28
49
18
27
38
53
05
18
22
32
39
58
07
15
1.
RO
RO
RO
RO
RO
32-1.78
0.61
1.41
1.13
0.50
1.93
1.43
1.47
1.34
1.38
1.55
1.51
1.45
1.54
1.55
0.61
1.51
1.46
304.71
78.32
7.93
126.27
3,774.17
2.06
73.38
10.58
13,207.90
8.10
296.12
13,577.40
12.41
12.46
15.86
24.89
28.11
13,711.55
13,667.03
191.18
38.59
20.25
14.37
11.77
22.66
28.35
27,687.97
131.
40.
66.
73.
13,207.
296.
19.
6,152.
5,946.
105.
24.
13.
39.
08
60
87
38
90
12
51
80
63
90
41
38
31
173.
44.
71.
15.
7,558.
7,720.
108.
21.
12.
16.
63
25
34
0.
0.
38
75
40
01
80
30
30
1
1
1
1
903
0
0
0
1
1
1
.019
.030
.040
.055
-1.097
.000
.923
.961
.002 37C1-TCDD SUR1
.015
.024
903-1.097
0
0
0
0
0
0
1
1
1
1
1
1
1
1
.000
.855
.874
.937
.970
.990 13C12-1234-TCDD RSI
.000 13C12-2378-TCDD IS1
.017
.032
.039
.043
.055
.064
.073
4.31
1,542.36
23.64
16.55
11.25
1,054.69
7,529.37
706.64
523.55
943.89
635.00
1 , 547 . 00
1,109.19
1,596.94
26.34
1,711.85
1,708.71
901.
620.
4,486.
405.
303.
574.
382.
916.
672.
970.
1,030.
1,015.
31
99
85
00
45
40
00
00
33
26
36
44
641.
433.
3,042.
301.
220.
369.
253.
631.
436.
626.
681.
693.
0.
05
70
52
64
10
49
00
00
86
68
49
27
904-1.081
0
0
0
0
0
0
0
0
0
0
0
1
1
1
1
1
1
.000
.912 _.
.919
.923
.937
.957
.963
.971
.981
.989
.998
.001 12378-PeCDF AN
.008
.012
.025
.031 23478-PeCDF AN
.037
Triangle Laboratories, Inc.® Analytical Services Division
301 Caprtola Drive • Durham, North Carofina 27713
3hone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 20:52 07/22/97
155
-------
Page No. 3
07/22/97
Congpound/
M_Z.... QC.Log Omit Why
Listing of W972833B.db£
Matched GC Peaks / Ratio / Ret. Time
.RT. OK Ratio Total.Area... Area.Peak.1. . Area.Peak.2. . Rel.RT Cornpound.Name. . ID.. Flags.
DC
340-342
13C12-PeCDF
352-354 DC
DC
DC
DC
DC
352-354
PeCDD
356-358 DC
D D
DC
M
A
DC
356-358
13C12-PeCDD
368-370 DC
DC
. -_ .. .. . DC
DC
DC
DC
DC
DC
DC
DC
SN
14
NL
SN
SN
SN
SN
6
NL
SN
SN
SN
11
NL
SN
_SN
SN
SN
SN
SN
SN
SN
SN
25:34
25:47 RO
26:08
Peaks
1.
0:00
22:07
23:26
23:45 RO
24:04 RO
24:21
24:31 RO
24:38 RO
25:07
25:24 RO
26:00 RO
Peaks
1.
0:00 RO
23:37
23:53 RO
24:11
24:22
24:31
24:41
24:52
24:58
25:10
25:18 RO
25:30
25:39
25:45 RO
26:00
Peaks
1.
0:00 RO
23:34 RO
23:58 RO
24:22 RO
24:41 RO
24:50 RO
25:03 RO
25:15
25:29
25:38 .
26:14 RO
26:22 RO
1.50
2.43
1.73
32-1.78
1.45
1.76
1.63
1.97
0.96
1.53
0.87
1.81
1.49
3.07
1.83
32-1.78
1.79
1.57
1.01
1.32
1.58
1.38
1.44
1.76
1.58
1.41
0.78
1.52
1.52
1.20
1.37
32-1.78
1.03
0.26
1.91
1.14
1.24
0.25
1.81
1.75
1.51
1.60
2.23
1.20
173.84
14.97
103.19
20,886.22
5.92
13.41
38.61
14.51
47.81
13,150.41
75.23
131.50
12.007.27
18.28
14.48
25,450.83
104
65
23
29
7,948
45
93
7,181
.30
.36
.95
.06
.72
.73
.28
.16
69.
37.
14.
30.
5.201.
52.
51.
4.326.
54 1.
83
0.
66
34
69
56
57
11
1.
1.
050
059
073
835-1.165
0.
0.
0.
0.
0.
1.
1.
1.
1.
1.
1.
000
908
962
975
988
000 13C12-PeCDF 123
007
012
031 13C12-P4COF 234
043
068
IS2
SOE2
•O«*y^T\T\ W«1 T A*-!*.
5.94
576.66
25.98
28.45
905.67
573.17
378.00
236.07
415.18
70.31
29.61
489.21
193.94
22.32
174.08
4,041.90
4.01
2.58
4.23
21.21
15.53
4.39
11.63
9.69
7,079.74
741 . 87
11.32
15.53
352
554
332
223
150
254
41
18
295
117
100
4,263
456
.26
.10
.78
.00
.40
.06
.15
.00
.41
.13
.77
.15
.27
224.
351.
240.
155.
85.
161.
29.
23.
193.
76.
73.
2.816.
285.
0.
40
57
39
00
67
12
16
10
80
81
31
0.
59
60
918-1.027
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
1.
1.
1.
843-
0.
0.
0^.
0.
0.
0.
0.
0.
1.
1.
1.
1.
000
927
937
949
956
962
969
976
980
988
993
001 12378-PeCDD
007
010
020
1.157
000
925
940
956
969
974
983
991
000 13C12-PeCDD 123
006
029
035
AN
IS3
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 20:52 07/22/97
156
-------
Page No.
07/22/97
Listing of W972832B.dbf
Matched GC Peaks . Ratio / Ret. Time
Compound/
M_Z QC.Log Omit '.toy . .RT. OK Ratio Total .Area... Area.Peak.l.. Area. Peak. 2. . Rel.RT Compound. Name.. ID.. Flags.
368-370
2 Peaks
7,821.51
HxCDF
374-376
A
M
DN
NM
374-376
13C12-HXCDF
384-386
384-386
HxCDD
^90- 39?
M
AN
M
390-392
DC NL 0
DC WL 26
27
27
27
27
27
28
28
28
28
28
28
D SN 29
29
DC SN 29
DC WH 29
1
:00 RO
:54 RO
:03
:12
:22
:30
:41
:03
:10
:17
:29 RO
:36 RO
:41
:24 RO
:28
:40 RO
-.57 RO
.05
0
0
1
1
1
1
1
1
1
1
1
1
1
0
1
0
0
12 Peaks
DC NL 0
27
27
DC SN 27
28
28
28
DC SN 28
23
DC SN 28
DC SN 29
29
0
:00 RO
:02 RO
:11 RO
:33 RO
:04
:10
:21 RO
:29 RO
:41
:57
:06 RO
:24
-- Above:
-1.43
.97
.34
.23
.20 1
.14
.16
.34
.25 1
.35
.25
.44
.59
.39
.68
.41
.48
.48
5
PeCDD /
19.15
6.47
491.92
. 857 . 47
129.03
188.55
303.45
,245.88
676.55
116.71
203.44
96.32
358.00
33.11
107.60
3.90
7.35
,774.92
HXCDF you
271
1,013
68
101
173
693
388
64
130
68
208
62
ows
.58
.78
.32
.08
.86
.05
.43
.88
.89
.30
.00
.90
220
843
60
87
129
552
288
51
90
43
150
44
.43-0.59
1
0
0
0
0
0
0
1
0
0
0
0
7 Peaks
DC NL 0
27
28
28
28
28
23
29
DC WH 29
1
iOO -
:36
:04
:17
:26
:48
:54
:12
:23 RO
.66
.61
.79
.88
.53 7
.49 8
.67
.40
.51 6
.47
.23
.49 5
28
H W*»*A .
7.31
58.01
37.18
16.01
,572.77
,216.76
39.05
7.10
,841.33
22.32
9.39
.924.24
.689.34
tlw/Tll? 1
.05-1.43
i
1
1
1
1
1
1
1
3
7 Peaks
17
.23 1
.27
.24 7
.16
.37
.20 1
.31
.13
10
19.93
,396.93
229.33
,014.61
91.30
52.00
,468.00
548.84
10.12
,801.01
23
19
2,627
2.686
17
2,306
1,958
.62
.57
.33
.20
.28
.76
.97
38
24
4.945
5,530
25
4,534
3,965
0.
.34
.69
.21
.47
.59
.83
.12
.83
.82
.00
.00
.70
0.
.42
.62
.44
.56
.86
.57
.27
956-1.053
0.000
0.955
0.960
0.966
0.972
0.976
0.983
0.996 123478-HXCDF
1.000 123678-HXCDF
1.004
1.011
1.015
1.018 234678-HxCDF
1.044 123789-HxCDF
1.046
1.053
1.063
858-1.142
0.000
0.960
0.965
0.978
0.996 13C12-HXCDF 478
1.000 13C12-HXCDF 678
1.007
1.011
1.018 13C12-HXCDF 234
1.028
1.033
1.044 13C12 -HxCDF 789
AN
AN
AN
AN
SUR3
IS4
ALT2
ALT1
770
128
3,878
49
30
801
311
.99
.20
.94
.00
.10
.00
.74
625
101
3,135
42
21
667
237
0.
.94
.13
.67
.30
.90
.00
.10
949-1.015
0.000
0.956
0.972
0.979
0.984
0.997 123478-HxCDD
1.001 123678-HxCDD
1.011 123789-HxCDD
1.017
AN
AN
AN
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 20:52 07/22/97
157
-------
Page No.
07/22/97
Listing of W972833B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_2.... QC.Log Omit Why . .RT. OK Ratio Total. Area..
Area.Peak.1.. Area.Peak.2. . Rel.RT Conpound. Name.. ID.. Flags.
13C12-HXCDD
402-404
DC NL 0
DC SN 28
DC SN 28
DC SN 28
DC SN 28
28
28
:00
:07
:16
:34
:39
:48
:53
1.
RO
RO
RO
RO
RO
.05-1.43
0
1
1
0
1
.85
.91
.69
.95
.95
1.34
29:11
29:26
DC SN 29:37
402-404
HpCDF
408-410
H
RO
RO
1
.19
1.26
0,
0,
4 Peaks
DC NL 0:00
0.
RO
30:55
31:09
408-410
13C12-HpCDF
418-420
418-420
HpCDD
424-426
424-426 -
13C12-HpCDD
436-438
436-438
31:
DC SN 31:
32:
DC WH 32:
DC WH 32:
15
43
07
19
34
.91
.67
3
9
21
8
7
3,831
5,607
5,839
24
22
15,303
88-1.20
2.
1.
1.
.01
,07
16
1.13
RO
RO
RO
2.
1.
1.
0.
95
45
13
66
4 Peaks
DC NL 0:
30:
DC SN 31:
DC SN 31:
32:
00
54
12
58
07
0.
RO
RO
RO
10
555
89
200
6
56
6
11
901
.51
.99
.21
.60
.03
.39 2,195.15
. 67 3 , 042 . 21
.93 3,257.14
.22 13.41
.49
.21
.69
.00 287.00
.08 47.76
.94 106.68
.59
.10 39.74
.63
.30
.12
37-0.51
0.
0.
1.
0.
0.
82
46
07
78
42
2 Peaks
DC NL 0:
31:
DC SN 31:
31:
00
ll'
27
47
0.
RO
RO
DC WH 31:58 RO
- 2 Pea1"
DC NL 0:
DC SN 31:
DC SN 31:
DC SN 31:
31:
00
18
24
33
46
0.
RO
RO
RO
RO
11
4,135
12
5
2.981
7,116
.35
.10 1,294.70
.05
.85
.46 884.88
.56
V 1 UnT'Ttn V~l 1 M.M
88-1.20
0.
1.
1.
1.
1.
88-
2.
1.
7.
0.
1.
50
01
49
06
26
1.20
21
64
62
26
01
1 Peak
3.47
1,109.
11.
802
.24 557.75
.71
.65 413.16
23.32
1 911 °°
5.
,61
6.28
1.51
3.26
3,198.47 1,608.05
0.965-1.035
0.000
0.973
0.979
0.989
0.992
1,636.24 0.997 13C12-HXCDD 478
2,565.46 1.000 13C12-HXCDD 678
2,582.79 1.010 13C12-HXCDD 789
SUR4
IS5
RS2
14.73 1.019
1.025
0.996-1.045
0.000
263.00 1.001 1234678-HpCDF
41.32 1.
94.26 1.
1.
27.50 1.
1.
1.
008
Oil
026
039 1234789-HpCDF
046
054
AN
AN
0.935-1.130
0.
2,840.40 1.
1.
1.
2,096.58 1.
000
000 13C12-HpCDF 678
010
035
039 13C12-HpCDF 789
IS6
SUR5
0.976-1.006 .. -, .
0.
551.49 0.
0.
389.49 1.
1.
0.968-
0.
0.
0.
0.
1,590.42 1.
000
982
990
001 1234678-HpCDD
006
1.032
000
985
988
993
000 13C12-HpCDD 678
AN
IS7
3,198.47
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 20:52 07/22/97
158
-------
Page No.
07/22/97
Listing of W972833B.dbf
Matched GC Peaks / Ratio
/ Ret. Time
Compound/
M_Z.... QC.Log Omit Why
.RT. OK Ratio Total. Area... Area. Peak. 1.. Area.Peak.2.. Rel.RT Compound. Name.. ID.. Flags.
OCDF
442-444
442-444
OCDD
458-460
458-460
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
1
NL
SN
SN
SN
1
0:
30:
30:
31:
32:
32:
32:
32:
33:
33:
33:
34:
35:
35:
35:
00
31
52
59
17
28
34
50
15
20
28
20
19
27
58
0
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
.76-1.02
0.
0.
1.
0.
0.
0.
1.
1.
0.
3.
0.
0.
1.
2.
1.
38
08
68
07
66
59
25
31
39
34
23
91
96
15
26
Peak
0:
34:
34:
34:
34:
00
05
14
25
42
0.
RO
RO
RO
RO
76-
0.
1.
0.
1.
0.
1.02
87
06
75
52
11
Peak
Above: HpCDD / Octa-CDD and CDF Follows
7.27
1.47
10.02
1.53
6.75
5.65
10.77
10.98
2.57
1.87
5.22
98.36
6.50
13.91
10.22
98.36
5.20
10.81
268.66
7.67
1.13
268.66
46.77
126.51
0.883-1.117
0.000
0.892
0.902
0.935
0.943
0.949
0.952
0.960
0.972
0.974
0.978
51.59 1.003 OCDF
1.032
1.036
1.051
0.883-1.117
0.000
0.996
169.07 1.000 OCDD
1.006
1.014
AN
13C12-OCDD 0.76-1.02
470-472 DC NL 0:00 0.96 4.87
DC WL 34:00 RO 1.39 10.40
34:13 0.88 2,816.33
470-472 1 Peak 2,816.33
1,320.85
0.996-1.005
0.000
0.994
1,495.48 1.000 13C12-OCDD
IS8
Column Description "Why" Code Description QC Log Desc.
M_Z -Nominal Ion Mass(as)
..RT. -Retention Time (mm:ss)
Rat.l -Ratio of M/M+2 Ions
OK -RO=Ratio Outside Limits
WL-Below Retention Time Window A-Peak Added
WH-Above Retention Time Window K-Peak Kept
SN-Below Signal to Noise Level D-Peak Deleted
-------
rile,H972833 #1-758 Acq,22-JUL-1997 15*52(50 GC EH- Voltage SIS 70SX Noimei44730
303.9016 Tt2 3SU3(256, 30, -3.0) PXD(9,5r5,0.10\,178920.0,1.00\,rrT) XxptXPCOS2
TSIASSLX LABS TextiM23 -OUTLET-SUIT 3 TLH42299A
100J
80:
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40:
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A 7. 26X7
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21(00 22(00 Time
THetH972833 #1-758 Acq:22-JUL-1997 15(52(50 SC EH- Voltage SIX 70SX Ab.lrail2.352
305.8987 T:2 3SUB(256,30,-3.0) PaO(9rS,S,0.10\,4940a.Or1.00\rr,T) XxpiXPCOS2
TSIASSLX LABS Text :M23 -OUTLET-SUN 3 TLH42299A
1001
SO:
50:
40:
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A9.{OX7
A1.26X8
A4.97X7
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315.9419 t
(2 BSU3(256,30,-3.0) PKD(9r5rS,0.10\,32132.0,1.00\,r,T) XrptXPCUS2
TSIASSLX LABS Text :M23 -OUTLET-SUN 3 TLH42299A
1001
SO:
40:
20:
A7.S4X7
17(00 ' ' ' 18(00 15(00
I \.
20 1 00
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LS.5Z5
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0.0X0
21(00 22(00 rl*e
r±letH972S33 #1-758 Aoqi22-JUL-1997 15tS2i50 GC EH- Voltage SIS 70SX No±metl562
317.9389 Tt2 BSUB(256r30,-3.0) PXD(9,5r5,0.1Q\,6248.0,1.00\,T,T) XxptXPCUS2
TSIASSLX LABS Text iM23 -OUTLET-SUN 3 TLH42299A
100S
80:
40:
20:
A1.01E8
17(00 ' ' ' 'l8(0
0 15(00
1 V
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330.9792 Tt2 XxptXPCUS2
TSIASSLX LABS TextiM23-OUTLXT-XUN 3 TLH42299A
lOOJj
80:
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16 27
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T±lettt972833 #1-758 Aoq,22-JUL-1997 15(52(50 GC XI+ Voltage SIS 70SX
375.8364 Ti2 XxptXPCUS2
TSIASSLX LABS Text iM23 -OUTLET-SUN 3 TLH42299A
lOOJj
80:
50:
40:
20:
0:
15
18(07
16t31 | . 17(511
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17(00' 18(0
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21 100 22(00 £!••
160
-------
ril»iX972833 #1-798 Acqi22-JVZ-1997 15i52i50 SC SI+ Voltage SIR 70SX Noim»t3574
319.3965 Tt2 BSUB(256, 30, -3.0) PXD(7,5, 3, 0.10\, 14296.0, 1.00\,T,T) XzptXPCUB2
TRIASSLX LASS T*ztiK23-OOTL£T-Rtnr 3 TLH42299A
100.
80.
60.
40.
30.
\ A3. 49X6
&1-70X6 A1.09X6 A1.31X6
A A1.23Z6 l\ . ,a_5 1 A1.23XS jl
/\ A9.79X5 A. / "•«» A » A A A6.69X5
A .A A .JWu. A A/Vrov^ A.
-7.3X5
'•.5.9X5
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.1.5X5
18.00 15*00 20*00 21*00 22*00' ' Time
rUm:M972833 #1-798 Aoqt22-JVZ-1997 15t52i50 SC XH- Voltmgm SIR 70S* No±M»t3132
321.8936 Tt2 BSOB(256, 30, -3.0) FKD(7, 5,3,0 .10\, 12528. 0,1. 00\,f,T) XxptXPCOS2
TXIANSLX LASS Text tN23 -OUTLET-RUN 3 TtI#43299A
1001
80.
60.
40.
30.
A3. 30X6
1
11
A2.12X6 1 A1.74X6
AA1.58S6 \\A2.02X6 M-.40X6 A1.43X6 i
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IB1, 00 15*00 20*00 ' 21:00 22*00 Time
Tile>M972833 #1-798 Aoyi22-JUL-1997 15*52*50 SC KI+ Voltaga SIX 70S! Hoimmt8218
331.9368 r»2 BSUB(256,30,-3.0) PO}(7,5, 3, 0.10%, 32872.0, 1.00\,T,T) Eip,EPCUS2
XRIAHSLX LABS Taxt:M23 -OUTLET-RUN 3 TLI942299A
1001
aol
so:
40:
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A6.15X7
h AS. 95X7
1 u
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ril»itf972833 H-798 Acqt22-JDZ-1997 15i52t50 SC KI+ Voltaya SIR 70SX K>lmui3504
333.9338 T>2 BSUB(2S6,30,-3.0) FXD( 7,5, 3,0 .10\, 14016 .0, 1.00\,T,T) SxptXPCOS2
TRIAOGLS LABS Taxt.!K23-OUTLET-SUlT 3 TLH42299A
100J
80:
so:
40:
201
0:
A7 56X7
A7.72X7
1 \J
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.1.5X7
.1.1X7
.7.6X6
.3.8X6
0.0X0
laiflO 15*00 20iOO ' ' 21tOO 22\00 ' Time
rH»ilt972833 tl-798 Aoqt22-JVI,-1997 15*52*50 SC XI + Voltay* SIR 70SX Xo±m*tl038
327.8847 Tt2 BSUB(256,30,-3.0) PXD(7,5,3,0.10\,4112.0,1.00\,r,T) XxptXPCtJS2
TRIASSLX LABS T*xt:lC33 -OUTLET-RUN 3 TLH42299A
10 0\
80.
*o:
40:
201
OJ
A1.32X8 -3.0X7
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330.9792 Ti2 XiptXfCaS2
TRIANGLX LABS Text iM23 -OUTLET-SUN 3 TLH42299A
10 0\
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161
-------
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339.8597 Tt2 3SU3(256,30,-3.0) rXD(7,5,3,0.10\,5236.0,1.00\,T,T) Xrp:XPCUS2
TRIAHGLX LABS T»ftiM23-OaTLXT-Xtnr 3 TLH42399A
1004 A4.49X7
801
601
33', 00 33100 24,00 25,00
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341.8567 Tt2 BSUB(256,30,-3.0) PXD(7,5,3,0.10\,S620.0,1.00\,r,T) XxptXPCOS2
TXIANGLX LABS Tvct,M23-OUTLXT-xm 3 TLH42299A
33', 00 23,00 34,00 25,00
Til»:H972833 tl-798 Acqt22-JVL-1997 15:53:50 GC XI+ Voltag» SIX 70S* «oi»«»1751
351.9000 r,3 BSUB(356,30,-3.0) PXD(7,5,3,0.10\,7004.0,1.00\,r,T) Xrp:XPCUS2
TXIANGLX LABS TextsMSS-OOTLET-XtOT 3 TLH42299A
1001 A7.95X7
401
2oi
A9.01X6
A
A1.33X7
A1.03X7
'Ptf A 1\
AA AA
1003
801
601
401
201
A3. 04X7
-/r
A9.06X6
AS.93X6
A/L
801
6oi
4oi
201
A7.18X7
23i00 24,00 25,00
f±latff973833 tl-798 Acq,33-JUL-1997 15,52,50 GC XH- Voltaya SIX 70S* Jtoiaatl211
353.8970 T,2 BSUB(356,30,-3.0) PXD(7,5,3,0.10\,4844.0,1.00\,T,T) Xzp:EPCUS2
TXIANGLX LABS Text:M33-OVTLXT-Xtnr 3 TLH42299A
10n AS.30X7
801
60i
401
301
A4.B3X7
22\00 ' ' ' ' ' 33\00 ' ' 24\00 ' ' 25,00
rilaiff972833 tl-798 Aotf,22-JVL-1997 15,52,50 GC XI+ Voltay* SIX 70S*
330.9792 r,2 XxptXPCUS2
TXIAOGLX LABS Tart:M33-OUTLXT-XUlT 3 TLIt43399A
1001
26tOO
36:00
26tOO
26*00
23,00 24,00 25,00
TilaiH972833 tl-798 Acqt22-JUL-1997 15,52,50 GC XH- Voltagm SIX 70S*
409.7974 T,2 XzptXPCOS2
TXIASGLX LABS T*xttM23-OUTLET-SUIT 3 TLIt42299A
2ftOO
33,00
3300
34iOO
35>00
26tOO
^.8X6
.7.8X6
J.9X6
.3.9X6
12.0X6
.0.0X0
T±mm
,6.5X6
.5.2X6
13.9X6
13.6X6
11.3X6
.0.0X0
T±mm
-2.8X7
J.3X7
.1.7*7
.1.1*7
J.5X6
.0.0X0
T±m»
-1.8X7
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Fi±a:if97iSJJ H-7S8 Acqi22-JUIt-1997 15*52*50 GC Sir- VOX tag* SIS /USE liOiafll
355.8546 Ti2 BSO3(2S6,30,-3.0) rXD(7,5,3rO.101,8352.0,1.00\,r,T) XxptXPCUS2
TSIANSLS LASS T*xtiM23-OUTLXT-SlOr 3 TLH42299A
100* AS. $4X6
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357.8516 T*2 3SUB(256,30,-3.0) PXO(7,5,3f0.10\r4668.0,1.00\,r,T) XxptXPCUS2
TXIANSLX LASS TfxtiH23-aaTLXT-tOf 3 TLH42299A
1001 A3.52X6
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367.8949 Ti2 aSUB(256,30,-3.0) PXB(7rSr3,0.10\,4872.0,1.00\rT,T) XxptXfCOS2
TSIANSUS LASS Tejct:M23-ODTLET-Stnr 3 TLH42299A
100* A4.26X7
80.
60.
40.
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24*00 25t00 26*00
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369.8919 f*2 S3US(256r30,-3.0) PXD(7,5,3r0.10\,4728.0,1.00\rTrT) Xxp*XPCU32
TRIASGLX LASS TfrttM23-OUTLXT-XOM 3 XLH42299A
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TXIAOGLX LABS TurtiM23-OUTLXT-Xmr 3 TLH42299A
100* 33l53 3tt23 24:38 24*50 25,02^
26*00
SIB 7052
-1.8X6
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0.0X0
-8.6X6
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~3TtX6~
.1.7X6
.0.0X0
Time
-2.5X7
'.2.0X7
.1.5X7
.9.9X6
.4.9X6
24100
25100
26100
0.0X0
Time
163
-------
'27\QO' 27il2' 27:24 27:36 27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48
Tile:N972833 tl-423 Acq:22~JUL-1997 15:52:50 GC EH- Voltage SIS 70SX Noife:4009
383.8639 T:3 3SOB(2S6,30,-3.0) PXD(7,5,3,0.10\,16036.0,1.00\,r,T) Xxp:XPCUS2
TSIANSLX LABS Text :M23-OUTLET-RUN 3 TLIt42299A
100(7,5,3,0.10\,21916.0,1.00\,T,T) XxptXPCOS2
TRIANGLE LASS Text:H23-OUTLET-ROlt 3 TLIt42299A
1001 A8.44E6
80:
60:
20:
AS. 53X6
A2.20E6
A
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60:
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27:00 27:12 27:24 27:36 27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48
rile:H972833 tl-423 Acq:22-JUL-1997 15:52:50 GC XH- Voltage SIS 70SX Noi*e:2419
385.8610 r:3 3303(256,30,-3.0) PKD(7,5,3,0.10\,9676.0,1.00*,r,T) Xxp:XPCDS2
TRIANGLE LABS Teit:ft23-OUTLET-SUTf 3 TLH42299A
100$ AS S 17
80:
60:
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A4.53X7
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27>27t227i24 27t36 27i48 28:00 28:12 2 a: 24 fl tf
29t 29112 29: 24 29:36 29:4a
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392.9760 T:3 Xlp:EPCU32
TRIANGLE LABS Text :H23-OUTLET-RUN 3 TLH42299A
lOOi
-3.2E6
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'-.1.8X6
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-1.7X7
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27s00 27t12 27:24 27:36 27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48
rile:tf972833 tl-423 Aoq:22-JUL-1997 15:52:50 GC XH- Voltage SIX 70SX
445.7555 T,3 XlptEPCUS2
TRIANGLE LABS Text :M23-OUTLET-RUN 3 TUt42299A
100J
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Tim,
40:
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27: 27:12 27:24 27: 36 27: 4 8 28: 00
164
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389.8156 T,3 SSOS(256,30f-3.0) PXO(7,5,3,0.10\,21540.0,1.00\,r,T) Xxp,XPCUS2
TRIANGLE LASS Text. ,1(33 -OUTLET -RUN 3 TLIt42299A
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Tile ,1197283 3 tl-423 Aoq,22-JUL-1997 15 1 52 1 50 GC XX* Voltage SIS 70SX No±ae,4604
391.8127 Tt3 BSUB(256,30,-3 .0) PXD(7t5,3,0.10\,18416.0,1.00\,T,T) Xxp,XPCUS2
TRIANGLE LASS Text,H23-OUTLXT-RUlt 3 TLH43299A
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f±leiH972833 tl-423 Aoq,22-JUL-1997 15i52t50 GC XI+ Voltage SIS 70SX N6iae,2353
401.8558 Ti3 SSUS(256,30,-3.0) PXD(7,5,3,0.10\,9412.0,1.00\,r,T) XxptXPCUS2
TRIANGLX LASS Text : M23 -OUTLET-RUN 3 TLIt42299A
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F±lettT972S33 tl-423 Aoq,22-JUL-1997 15,52,50 GC EH- Voltage SIS 70SE Nolaa,2770
403.8529 Ti3 SSUS(256,30,-3.0) PXD(7,5e3,0.10\,11080.0,1.00\fr,T) XxpiXPCUS2
TRIANGLX LASS Text :K23 -OUTLET-RUN 3 TLIt42299A
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rile,H972833 tl-423 Aoq,32-JUL-l997 15,53,50 GC XH- Voltage SIS 70SX
392.9760 T>3 XxftXPCUS2
TRIANGLX LASS Text:M23-OUTLXT-RUN 3 TLH42299A
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70SE O0i»ei5273
407.7818 r:4 3SU3(256, 30, -3.0) PXB(7, 5, 3,0. 101,21092. 0,1.00\,r,T) XxptXPCUS2
TSIASGLX LASS Text:M33-OUTLXT-SUlT 3 TLH42299A
1003
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A3. 97X5
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-6. 7X5
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32:00 32\12 32:34 32 36 Time
70SX S0i»e:2619
409.7789 r:4 3303(256, 30, -3.0) PXD(7,5,3,0.10\,10476.0,1.00*,r,T) Xxp:XPCUS2
TSIASGLX LABS Text :M23 -OUTLET-SUN 3 TLH42299A
1003
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sol
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A
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A2.75X5
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-y'4E5
-7.5X5
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32:00 33:13 32:24 32 36 Time
70SX Boife:32SO
417.8253 F:4 BSUB(256, 30, -3.0) PXD(7,5t3,0.10\,13000.0,1.00\,r,T) Xxp:XPCUS2
TSIASGLX LASS Text:M23-OUTLXT-SUlT 3 TLIt42299A
1003
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33*00 32:12 32:24 32 36 Time
70SX Soiaes3940
419.8220 T:4 3SUB(256,30,-3.0) PKD(7,5,3,0.10\,15760.0,1.00\,T,T) Xxp:XPCUS2
TRIANGLE LASS Text :H23 -OUTLET-SUIT 3 TLH4229SA
1003
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rile:H972833 tl-440 Acq:22-JUL-1997 15:52:50 GC XI+ Voltage SIS
430.9729 P:4 XxpiXPCUS2
TSIASGLX LABS T»xt:H23 -OUTLET-SUIT 3 TLH42299A
1003
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60:
40:
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A
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70SX
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479.7165 T:4 XxptXPCUS2
TSIASGLX LABS Text :M23 -OUTLET-SUN 3 TLIt42299A
1001
80:
sol
40:
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31 113 31:23 Al i 31i48 ,
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3.2.00 3 2': 12 32:24 32 36 Time
166
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TiJL»iH972833 tl-440 Aotft H-JUIi-mit / A3S3JS3U tic Sf-f ValcajW SIX /USE NOlm*t
423.7766 Tt4 BSUB(256e30,-3.0) PXO(7,5r3,0.10\,3S32.0e1.00\,r,T) XrptXPCUS2
TRIASGLX LABS Tmxt,K33-OUTLET-RUN 3 TLIt42299A
1001 AS.58X6
A4.13X6
-1.7X6
31:00 31', 06 31tl2 31:18 31i24 31,30 3li36 31:42 31:48 3l't54 32tOO
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425.7737 f ,4 BSUB(256,30,-3.0) PXD(7,5,3,0.10%,7104.0,1.00\,T,T) Xxp,XPCUS2
XRIAHGLX LABS TfXt:M23-OUTLXT-SUK 3 TLH42299A
100% AS.51X6
32:06 32t12
80.
60.
40.
20.
A3.89X6
31:0031:06 31:12 31tl8 31»24 31t30 31t36 31t42 31:48 31i54 32tOO 32i06 32il2
rJJ.a:H972833 tl-440 Acq:22-JUL-1997 15:52:50 GC XH- Voltage SIX 70SX Hola»:3042
435.8169 f:4 BSVB(256,30,-3.0) PKD(7,5,3,0.10\,12168.0,1.00*,T,T) Exp:EPCU32
TRIAHGLX LABS Tm3CttM23-OUXLXT-RUll 3 TLIt42299A
-.1.8X6
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31': 00 31:06 31:12 31:18 31:24 31:30 31:36 31t42 31:48 31:54 32,00 32,06 32,12
r±l»iff972833 tl-440 Acqi22-JVL-1997 15,52,50 GC XH- Voltagv SIR 70SX Jtoim»tl375
437.8140 T:4 BSUB(256,30,-3.0) PXD(7,5,3,0.10\,5500.0,1.00\,T,T) XxptXPCUS2
TRIASGLX LABS Text:M23-OUTLET-RU1T 3 TLIt42299A
.0.0X0
Time
100%
901
60.
40.
20.
A1.59X7
31to6 31\06 31il2 31:18 31t24 31s30 31i36 31t42 31t48 31:54 32t66 32i06 32112
rllaiN972833 tl-440 Aoqi22-JUL-1997 15:52,50 GC XH- VoltMgm SIX 70SX
430.9729 f>4 XxptXPCUS2
'IAHGLX LABS T*XttM23-OUTLET-RUB 3 TLIt42299A
100% , 31jl6 31,32 31i41 31i52 31,58 32t08
80.
60.
40.
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0.
-5.1X6
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31:00 31i06 31tl2 31tl8 31t24 31t30 31i36 3l':42 ' 31:48 ' '31t54 ' '32:66 ' '32:06 ' '32:12
0.0X0
Timu
167
-------
rllm:H972833 #1-446 Acq:22-JUL-1997 15:52:50 SC SI+ Voltage SIS 70S! Hoi**,1701
441.7428 r:4 3SO3(256,30,-3.0) PXD(7,5,3,0.10\r 6804.0,1.00\,f,T) Xxp:XPCOS2
TXIAfKLX LASS T*jctiM23-OUTLET-BUN 3 TLIt42299A
31:00 33,00 33,00 34,00 35,00
rilm:H972833 tl-440 Aoq:22-jm-1997 15,52,50 GC XII- Voltmgu SIX 70SX Soi*mtl936
443.7399 f:4 3SO3(256,30,-3.0) PKD(7,5,3,0.10%,7744.0,1.QO\rT,T) SzptXPCUS2
TXIANGIJS LASS TartiMSJ-OOTETT-JtCW 3 TLH42299A
.0X0
36 00 T±m»
30:47
32,24
31:00 32,00 33,00 34,00
rilattf972833 tl-440 Aoqi22-JUL-1997 15,52,50 SC XH- Voltagm SIX 70SX
430.9729 f,4 Sxp,EPCUS2
TBIANGLX LABS T*rt!M23~OUTLET-RUlf 3 TLH42299A
. 32t54 33,31
31,16 31:41
801
701
601
sol
401
301
101
01
34:23
35:00
35:06 35:27
31:00 32:00 33:00 34:00
Tila:W972B33 tl-440 Acqt22-JVI,-1997 15:52:50 GC XH- Voltage SIX 703E
513.6775 Ti4 Xxp:EPCUS2
TXIASSLX LASS T*JCt:M23-OUTLET-BUR 3 TLI142299A
1004
35,00
10.0X0
36 00 Tim*
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36 00 Time
901
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4ol
301
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tl-440
457.7377 F:4 BSUB(256,30, -3.0) PKD(7,5,3,0.10\,4840.0,1.00\,r,T) XxptEPCUS2
TRIASGLX LABS Text tM23-OUTLET-RON 3 TLH42299A
1001
80.
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A6.17X4
A4.21X4
341 OS 34113 34tl8 34t24 34i30 34i36
rllm:V972B33 11-440 Aoq:22-JUL-1997 15tS2t50 GC XH- Voltage SIX 70S* Xoimeil391
459.7348 T:4 BSUB(256,30,-3.0) PXD(7,5r3,0.10\,5564.0el.\,T,T) XrptXPCOS2
TRIASOLX LABS T*xt:M33-OUTLET-SOS 3 TLH42299A
10 0\ A1.J9E6
34:06 34tl2 34:18 34s24 34t30 34i36
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469.7779 Tt4 BSUB(256,30,-3.0) PXD(7rSr3,0.10\,4768.0t1.00\,TrT)
TRIANGLE LABS Text lK23-OUTLET-RUN 3 TLH42299A
1001 Al.
80.
34,06 34:12 34:18 34:24 34t30 34t36
rilB:ff972833 tl-440 Acqi22-JUL-1997 15:52:50 GC EH- Voltjg* SIS 70SX XolMUtl245
471.7750 Tt4 BSUB(256,30,-3.0) PXD(7,S,3,0.10\,4980.0,1.00*,rrT) Erp:EPCUS2
TRIANGLE LABS Text:H23-OUTLET-RUH 3 TLH42299A
1001 A1.50E7
0.
34'tOS 34,12 34 1 13 34:24 34:30
r±2» t*972833 tl-440 Aoqt22-JUL-1997 15:52:50 GC EH- Volt*9» SIS 70SE
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TXIANGLE LABS Text :M23 -OUTLET-SUIT 3 TLIt42299A
1001 34^11 _ 34j£3 34:33
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319.8965 F:2 Exp:EPCUS2
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373.8208 F:3 Exp:EPCUS2
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File:W972833 #1-423 Acq:22-JUL-1997 15:52:50 GC EI+ Voltage SIR 70SE
389.8156 F:3 Exp:EPCUS2
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389.8156 F:3 Exp:EPCUS2
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391.8127 F:3 Exp:EPCUS2
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File:W972833 #1-423 Acq:22-JUL-1997 15:52:50 GC EI+ Voltage SIR 70SE
389.8156 F:3 Exp:EPCUS2
Sample Text :M23-OUTLET-RUN 3 TLI#42299A File Text: TRIANGLE LABORATORIES'
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391.8127 F:3 Exp:EPCUS2
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401.8558 F:3 Exp:EPCUS2
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File:W972833 #1-440 Acq: 22-JUL-1997 15:52:50 GC EI+ Voltage SIR 70SE
407.7818 F:4 Exp
: EPCUS2
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File:W972833 #1-440 Acq:22-JUL-1997 15:52:50 GC EI+ Voltage SIR 70SE
409.7789 F:4 Exp
: EPCUS2
Sample Text :M2 3 -OUTLET -RUN 3 TLI#42299A File Text : TRIANGLE LABORATORIES', INC.:: DBS::
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File:W972833 #1-440 Acq: 22-JUL-1997 15:52:50 GC EI+ Voltage SIR 70SE
417.8253 F:4 Exp
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|File:W972833 #1-440 Acq:22-JUL-1997 15:52:50 GC EI+ Voltage SIR 70SE
407.7818 F:4 Exp:EPCUS2
Sample Text :M2 3 -OUTLET- RUN 3 TLI#42299A File Text : TRIANGLE LABORATORIES
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417.8253 F:4 Exp:EPCUS2
Sample Text:M23-OUTLET-RUN 3 TLI#42299A File Text:TRIANGLE LABORATORIES', INC.:: DBS::
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File:W972833 #1-440 Acq:22-JUL-1997 15:52:50 GC EI+ Voltage SIR 70SE
457.7377 F:4 Exp:EPCUS2
Sample Text:M23-OUTLET-RUN 3 TLI#42299A File Text:TRIANGLE LABORATORIES, INC
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File:W972833 #1-440 Acq:22-JUL-1997 15:52:50 GC EI+ Voltage SIR 70SE
459.7348 F:4 Exp:EPCUS2
Sample Text:M23-OUTLET-RUN 3 TLI#42299A File Text:TRIANGLE LABORATORIES, INC,
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File:W972833 #1-440 Acq:22-JUL-1997 15:52:50 GC EI+ Voltage SIR 70SE
471.7750 F:4 Exp:EPCUS2
Sample Text:M23-OUTLET-RUN 3 TLI#42299A File Text:TRIANGLE LABORATORIES, INC.:: DBS:
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-------
TLI Project: 42299A Method 23 TCDD/TCDF Analysis (DB-225)
Client Sample: M23-Outiet-Run 3 Analysis File: P973372
Client Project:
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
Iron & Steel-Chicago
M23TRAIN Date Received:
173-61-3ABCE Date Extracted:
Date Analyzed:
1.000 Dilution Factor:
n/a Blank File:
DB-225 Analyst:
07/01/97
07/17/97
07/23/97
n/a
W972829
BB
Spike File:
ICal:
ConCal:
% Moisture
% Lipid:
% SoUds:
SPC2NF04
PF22206
P973363
: n/a
n/a
n/a
*m&*& - * :: *&fc(*i& ^v ' »t: , a*W? * '^t 'mate'-;', *TT **»
2,3,7,8-TCDF
ifltemal Standard
13C,r2,3,7,8-TCDF
: Beco^ary Randan
13C12-1,2,3,4-TCDD
0.73
-'"•• ftmL CnaJ " - % Recovery QCLfenltei*'
•» ^* " * -- vA-ff-
3.7 92.6
i
40%-130%
0.73
Ratio
0.74
Ratio
0.81
20:59
fit
20:58
UT
19:59
—
Ftegs
—
^«^«i-
Data Reviewer
Nit/
07/24/97
Page 1 of 1
C2NFJ>SR ri.00. LARS 6.10.03
Triangle Laboratories, Inc.®
801 Capftola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 15:49 07/24/97
18S
-------
Initial
..Date.
Data Review By:
Calculated Noise Area: n/a
The Total Area for each peak with an ion abundance ratio outside
ratio limits has been recalculated according to method requirements.
Page No. 1 Listing
07/24/97 Matched
Compound/
M_Z.... QC-Log Omit Why . .RT. OK
TCDF 0 •
304-306 DC NL 0
16
DC SN 17
17
17
17
18
18
18
18
18
18
19
19
19
20
20
20
20
20
21
21
21
DC SN 21
22
22
DC WH 23
DC WH 23
:00 RO
:40 RO
:14 RO
:43
:48
-.55
:05
:21
:31
:38
:47
:56
:16
:42
:57
:08
:19
":29
:52
:59
:09
:24
:32
:47 RO
:14
:54
:03 RO
:05 RO
of P973372B.d£>£
QC Peaks / Ratio
Ratio Total. Area
65-0.89
1
14
1
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
8
0
0
1
1
.53
.32
.27
.71
.68
.69
.69
.70
.69
.72
.74
.69
.70
.72
.70
.71
.84
.74
.77
.73
.76
.74
.76
.10
.72
.75
.03
.08
304-306 23 Peaks
13C12-TCDF
316-318 DC NL 0
DC WL 19
DC WI. 19
20
21
21
21
DC WH 22
DC WH 22
0.
:00 RO
:41 RO
•55 RO
:58
:08 RO
:22
:30
:07
:55 RO
0
3
1
985
342
/ Ret. Time
Area. Peak. 1. . Area . Peak . 2 . . Rel.RT Compound . Name .. ID.. Flags.
0.787-1.099
.57
.13
.31
.17
.09
1,037.72
591
458
876
380
1,709
332
1,711
973
538
675
58
447
390
379
344
342
584
1
309
32
0
0
13,507
.89
.87
.13
.92
.26
.99
.76
.68
.84
.49
.38
.34
.52
.55
.16
.68
.94
.79
.59
.31
.65
.67
.41
25
409
138
422
241
188
356
159
725
136
706
406
220
281
26
190
170
160
148
146
252
129
13
.35
.38
.49
.34
.66
.92
.84
.40
.43
.03
.38
.89
.98
.06
.71
.23
.39
.50
.11
.28
.13
.26
.89
1.
575.
203.
615.
350.
269.
519.
221.
983,
196.
1,005,
566.
317,
394,
31.
257,
220,
219.
196
196
332
180
18
65-0.89
1
1
.22
.91
1-22
0
1
0
0
0
1
.74
.18
.70
.65
.65
.01
316-318 4 Peaks
1
3
.38
.49
,77
,79
.60
.38
.23
.95
.29
.52
.83
.96
.38
.79
.86
.43
.67
.11
.13
.05
.05
.40
.81
.33
.42
0.
8.73
1,987
4
6
17
2
15
2,015
.18
.46
.62
.34
.42
.40
.60
847
2
2
6
.52
.98
.72
.34
1,139
2
3
10
.66
.52
.90
.50
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
1
1
1
1
1
1
1
1
1
.000
.795
.822
.845
.849
.855
.862
.875
.383
.889
.896
.903
.919
.940
.952
.960
.969
.977
.995
.001 2378-TCDF AH
.009
.021
.027
.039
.060
.092
.099
.101 , „
952-1.048.
0
0
0
1
1
1
1
1
1
.000
.939
.950
.000 13C12-2378-TCDF ISO
.008
.019
.025
.055
.093
Triangle Laboratories, Inc.® Analytical Services Division
801 Capftola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 15:49 07/24/97
189
-------
Page No.
07/24/97
Listing of P973372B.dbf
Hatched GC Peaks / Ratio / Ret. Time
Compound/
H_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. 10.. Flags.
13C12-TCDD
332-334
332-334
DC
DC
NL 0
18
19
19
20
SN 21
:00
:42
:46
:59
:39
:13
0.
RO
RO
RO
RO
65-0.89
1.
0.
0.
0.
1.
1.
67
60
77
81
00
83
4 Peaks
Above: TCUF / TCDD Follows
0.80
5.54
1.524.01
1,546.45
15.79
1.49
3,091.79
2.41
662.50
690.56
8.93
0.898-1.102
0.000
4.05 0.946
861.51 1.000 13C12-2378-TCDD IS1
855.89 1.011 13C12-1234-TCDD RSI
3.92 1.045
1.073
Column Description "Why" Code Description QC Log Desc.
M_Z -Nominal Ion Mass(es)
..RT. -Retention Time (mm:ss)
Rat.l -Ratio of M/M+2 Ions
OK -RO=Ratio Outside Limits
Rel.RT-Relative Retention Time
End of Report *»*
WL-Below Retention Tim* Window
WH-Above Retention Time Window
SN-Below Signal to Noise Level
-------
303.9016 BSUS(256,30,-3.0) PXD(5,3,l,0.10\,980.0rO.OO\,r,T) Xxp,DS225
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r±lm,P973372 fl-964 Acq,23-JUL-1997 23,47,33 XI+ Voltage SIS 70P
Boiae,475
315.9419 SSUS(256,30,-3.0) PKD(5,3,1,0.10\,1900.0,0.00\,T,T) Xxp,DB225
TXUOISZX LASS Text:M23 -OUTLET-SON 3 XLit42299A
lOOi
80.
60.
40.
20.
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1
8X6
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'.2.0X6
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T±1*,P973372 fl-964 Acq,23-JUL-1997 23,47,33 XI+ Voltage SIX 70P
Boise t 390
317.9389 BSUS(256,30,-3.0) PXD(5,3,l,Q.10\,1560.0,0.00\,r,r) Xrp,DS225
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60.
20.
o:
Al.l
- -- - -
4X7
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375.8364 Xxp,DS225
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1001
80.
60.
40:
20.
0'
16 41
17,07
|
- - —
II j| 18,49
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191
-------
rU»tf97337S tl-964 Ac?,JJ-JVX.-J.ilSJ Mt47tJ3 B± Vfaitag* SIS 70f BoJ.a.,330
319.8965 3801(256,30, -3.0) PXD(5,3,1,0.10\,920.0,0.00\,T,T) XxpiBB22S
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TXIMKIX LASS T*xt i M23-OUTLET-SOX 3 TLU42299A
A3.03X5
22'tOO
A1.79X5 A2.47X5
A1.32XS
IBiOO 19tOO 20iOO 21tOO
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so:
SO.
40:
18100 19:00 20tOO 21>00
ril»tP973372 il-964 Aaqi23-JVL-1997 22t47t33 H+ Voltmg* SIX 70P Boi*»t373
31.9368 BSOB(256,30,-3.0) PXD(5,3,l,0.10\,1492.0,0.00\,r,r) XxptDB225
TXIAOSLX LABS T*XtiM23-OOTLET-BOir 3 XLH42299A
I I I I I
22100
80.
eo:
40.
20:
18tOO 19100 29'tOO 21'tOO
r±l»tP973372 #1-964 Acqt23-JVL-1997 22t47t33 XH- Voltmgf SIX 70P Bo±M*t223
33.9338 B8UB(256,30,-3.0) PXD(S,3,l,0.10\,892.0,0.90\fr,T) Xxp,DB225
tlAHBLX LABS T*rtiM23-OUTLXT-XO* 3 TLH42299A
00* A8.
80.
60.
40.
20.
0.
i i i i i
22 tOO
IBtOO
' 19iOo'
20tOO
21iOo'
22tOo'
-4.4X6
.3.5X6
.1.7X6
-8.7XS
.0.0X0
Tim,
-2.0X6
.1.6X6
.1.2X6
.4.1X5
'.0.0X0
Time
-2.6X6
'.2.1X6
.1.5X6
.1. 0X6
.5.1X5
0.0X0
192
-------
rllmiP973372 tl-964 Aoqt23-JTJL-1997 22:47:33 SI+ Voltage SIX TOP
303.9016 XxptDB225
TXIAHGLX LASS TmrttM23-OOTLXT-Xtar 3 TLH42299A
17iOO 18'tOO 19 tOO 20100 21:00
HJ.01P973372 tl-964 Aoqt23-JVL-1997 22:47:33 XH- Voltage SIX 70P
315.9419 XxptDS225
TXIABSLX LABS TuxttlQS-OVTLXT-Xinr 3 TLH42299A
1001 30; 58
SO.
SO:
401
20:.
22 tOO
23100
.0.0X0
Tim.
-2.5X6
'•.2.0X6
.1.5X6
.0X6
IS. 0X5
0.0X0
'l7\00 18100 19tOO 20100 21tOO
T±lmtP973372 tl-964 Aoqi23-JVL-1997 22:47:33 XI+ Voltage SZH 70P
319.8965 Xip:DB225
TRIAHSLX LASS r«xtsM2J-Ot7TLST-HCW 3 TLH42299A
100\ 18t43
17134
22100
23100
17:00 18:00 19:00 20:00 21:00
ril»tP973372 tl-964 Acqt23-JUZ-1997 22:47:33 XI+ Voltage SIX 70P
331.9368 Kxp:D3225
TXIAHGLX LASS T*XtiM23-OtrCLXT-Xtar 3 XLIt42299A
1001
80.
so:
40:
20:
19tS9
,.2.0X6
.1.6X6
.1.2X6
.8.2X5
1.4.1X5
17:00 18:00 19:00 20:00 21:00
m»iP973372 tl-964 Acqt23~JUL-1997 22:47:33 XH- Voltage SIX 70P
292.9825 XXftDS225
TXIAXGLX LASS Tmrt.:M23-OUTUST-RUK 3 TLIt42299A
17/15 19tl6 20.17 20i48 21il7
22,00
23 tOO
23:00
0.0X0
Tiff
22:57 -2.0X6
17 tOO 18:00 19:00 20:OO 31:00
T±l»tP973373 tl-964 Aoqi23-JOL-1997 22:47:33 XH- Voltage SIX 70P
330.9792 Xrp:DS225
XXIAHSLX LASS tmrttM23-OOTLXT-Xm 3 TLXt42299A
17:15 . 18:19 19_jl8 20:05 20:35 21:16
22100
23 tOO
Timm
17100
18:00
19100
20100
21:00
22:00
23100
193
-------
I
H
1
I
H
r« 9
S968'6J£ J
6886VIC 3
nwfiie Q
$68'9K 3
9186*888 8
utn^rtuo
dnojg
aieu
-------
TLI Project: 42299A
Client Sample: M23-Outlet-FBl
Method 23 PCDD/PCDF Analysis (a)
Analysis File: W972830
Client Project: Iron & Steel-Chicago
Sample Matrix: M23TRAIN Date Received: 07/01/97
TLI ID- 173-61-4ABCE Date Extracted: 07/17/97
Date Analyzed: 07/22/97
Sample Size: 1.000
Dry Weight: n/a
GC Column: DB-5
Analytes - s^V^*^8f|£^
Dilution Factor n/a
Blank File: W972829
Analyst MM
^^HP^'/--^011*^?''"' *
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
**$**?'<''***
SPX23704
WF54307
W972828
n/a
n/a
n/a
2,3,7,8-TCDD
1,2,3,7,8-PeCDD
1,2,3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDD
U,3,7,8,9-HxCDD
1,2,3,4,6,7,8-HpCDD
1,2,3,4,6,7,8,9-OCDD
2,3,7,8-TCDF
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
U,3,7,8,9-HxCDF
U,3,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
1,2,3,4,6,7,8,9-OCDF
f fdls ***'- •&
•• *•"«>* ^ s' %'\
Total TCDD
Total PeCDD
Total HxCDD
Total HpCDD
Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF
EMPC
ND
ND
ND
ND
ND
0.10
0.02
ND
ND
0.02
ND
ND
ND
EMPC
ND
EMPC
'^H'"aAmfc. &&$?>^
> " $$>;, -',\+. "&&!&
' ' •• •••.*'•'•. ',
—
—
—
^___
—
___
—
Page 1 of2
X237 J>SR TilXX LARS S.10.03
Triangle Laboratories, lnc.»
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 01:04 08/13/97
-------
TLI Project: 42299A
Client Sample: M23-Outlet-FBl
Method 23 PCDD/PCDF Analysis (a)
Analysis File: W972830
Internal Standards
I3C12-2,3,7,8-TCDF
l3C12-2,3,7,8-TCDD
13C12-l,2,3,7,8-PeCDF
13C,2-l,2,3,7,8-PeCDD
13C,2-l,2,3,6,7,8-HxCDF
I3C12-l,2,3,6,7,8-HxCDD
13C12-l,2,3,4,6,7,8-HpCDF
13C12-l,2,3,4,6,7,8-HpCDD
13C,2-1,2,3,4,6,7,8,9-OCDD
»a-23,7,8-TCDD
13C!2-2,3,4,7,8-PeCDF
13C12-l,2,3,4,7,8-HxCDF
13C12-l,2,3,4,7,8-HxCDD
13C12-l,2,3,4,7,8,9-HpCDF
AJtemate Standards (Type ft)
13C12-l,2,3,7,8,9-HxCDF
I3C12-2,3,4,6,7,8-HxCDF
13C12-1,2,3,4-TCDD
13Ci2-l,2,3,7,8,9-HxCDD
V~ '*&&&&
3.8
3.4
2.6
2.9
2.9
3.6
3.0
3.0
5.0
i^:JN&,C$&:
4.2
4.7
4.0
3.5
3.7
*rat"(ngte
3.5
32
••^-' **&
93.9
85.4
65.2
TLI
71.9
89.7
75.0
75.1
62.4
tjIfff^P^vaKSf
105
117
98.8
87.1
92.6
^^iecbveijf
86.7
78.8
^
r^OEttaftfr^
40%-130%
40%-130%
40%-130%
40%-130%
40%-130%
40%-130%
25%-130%
25%-130%
25%-130%
-^uiS;:'
70%-140%
70%-140%
70%-140%
70%-140%
70%-140%
' C«Lta«»^
40%-130%
40%-130%
•f •• S f .- /
Ratfo
0.78
0.83
1.49
1.47
0.51
1.21
0.44
1.06
0.91
Ratto
1.48
0.52
1.24
0.44
r Ratio
0.51
0.51
Ratio
0.83
.22
RT
19:50
20-41
24:17
25-27
28:07
28:51
30:53
31:44
34:12
irr
20-42
25:04
28:01
28:47
32:05
8T
29:22
28:39
«T
20-27
29:09
Fteg*
—
—
—
"~W*&
—
Ftegs
—
Ftegs
^^—
Data Reviewer
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Page 2 of 2
08/13/97
X237J>SR vZOO. LARS 6.10.03
Printed: 01:04 08/13/97
-------
TLI Project:
Client Sample:
42299A
M23-Outlet-FBl
Toxicity Equivalents Report
Analysis File: W972830
Client Project:
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
Iron & Steel-Chicago
M23TRAIN
173-61-4ABCE
1.000
n/a
DB-5
Date Received:
Date Extracted:
Date Analyzed:
Dilution Factor:
Blank File:
Analyst:
07/01/97
07/17/97
07/22/97
n/a
W972829
MM
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPX23704
WF54307
W972828
n/a
n/a
n/a
Analytes
2,3,7,8-TCDD
1,2,3,7,8-PeCDD
1,2,3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
1,2,3,4,6,7,8-HpCDD
1,2,3,4,6,7,8,9-OCDD
TOTAL PCDD
2,3,7,8-TCDF
1,2,3.7,8-PeCDF
2,3,4,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
1,2,3,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
1,2,3,4,6,7,8,9-OCDF
TOTAL PCDF
•"ft Amt.(ng)
[0.03]
(0.03)
(0.03)
(0.02)
(0.02)
(0.04)
0.10
0.006
(0.02)
(0.02)
0.02
(0.01)
(0.02)
(0.02>
[0.03]
(0.03)
[0.06]
Total
*- ^
X
X
X
X
X
X
X
X
X t
X
X
X
X
X
X
X
X
EPA TEFs,
TEF
1 —
0.5
0.1
0.1
0.1
0.01
0.001
0.1
0.05 r =
,0.5
b.'i • • =
0.1
0.1
0.1
0.01
0.01
0.001
1989a: 0.071 8 ng
f- Equivalent
0.03
0.015
0.003
0.002
0.002
0.0004
0.0001
0.0525
0.0006
0.001
0.01
0.002
0.001
0.002
0.002
0.0003
0.0003
0.00006
0.0193
[...] indicates that the value is that of an EM PC.
(...) indicates that the value is that of a Detection Limit.
Page 1 of 1
TEFPR v5.11. LARS 6. lO.OSc
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Added Pace
Printed: 19:21 09/18/97
-------
Data Review By:
Initial
\[ c
..Date.
Calculated Noise Area: 13.76
The Total Area for each peak with an ion abundance ratio outside
ratio limits has been recalculated according to method requirements.
Page No. 1
07/22/97
Compound/
M_Z QC.Log Omit Why
TCDF
304-306 DC
DC
DC
DC
304-306
13C12-TCDF
316-318 DC
DC
DC
316-318
TCDD
320-322 DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
...... ... .. . . . . DC
DC
DC
320-322
37C1-TCDD
328 DC
DC
DC
DC
NL
SN
SN
SN
1
NL
WL
WH
2
NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
_SN._
SN
WH
1
NL
WL
SN
SN
Listing
Matched
. .RT. OK
0:
16:
17:
18:
19:
00
53
04
55
52
0.
RO
RO
of W972830B.dbf
GC Peaks / Ratio
Ratio Total. Area
/ Ret. Time
... Area. Peak. 1.. Area . Peak . 2 . . Rel
65-0.89
1
1
0
0
0
.32
.25
.89
.76
.72
Peak
0:
18:
19:
20:
21:
00
37
50
21
47
0.
RO
RO
11
17
16
25
74
74
.81
.28
.12
.83
.65 31.34
.65
65-0.89
2
1
0
0
0
.08
.09
.78
.77
.69
Peaks
HVu
0:
17:
17:
18:
18:
18:
19:
19:
19:
19:
20:
20:
20:
20:
21:
21:
21:
22:
00
43
48
11
40
58
06
30
38
50
16
32
42
:58
07
43
43
:15
0.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
4
72
13,279
232
49
13,512
65-0.89
1
1
2
1
1
0
1
0
0
6
1
1
0
0
0
2
0
0
.01
.16
.32
.63
.46
.82
.03
.87
.92
.26
.65
.19
.53
.20
.40
.61
.38
.34
Peak
0:
17:
18:
19:
:00
38
:56
;05
4
14
4
9
5
8
10
7
5
6
3
10
80
4
7
3
5
5
80
2
7
4
10
.02
.94
.85 5,834.63
.18 100.70
.67
.03
.28
.53
.27
.01
.79
.95
.87
.16
.77
.53
.45
.96
.09 34.34
.23
.34
0.819-
0.
0.
0.
0.
43.31 1.
0.950-
0.
0.
7,445.22 1.
131.48 1.
1.
.RT Compound . Name .. ID.. Flags.
1.109
000
851
861
954
002 2378-TCDF AN
1.050
000
939
000 13C12-2378-TCDF ISO
026
098
0.849-1.064
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
65.83 1.
1.
1.
000
857
861
879
902
917
923
943
949
959
980
993
001 2378-TCDD AN
014
021
.33_. ....... 1.050
.24
.31
.09
.50
.18
.23
.53
1.
1.
0.903-
0.
0.
0.
0.
054
076
1.097
000
853
915
923
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 20:46 07/22/97
197
-------
Page No. 2
07/22/97
Compound/
M_Z.... QC.Log Omit Why
Listing of W972830B.dbf
Matched OC Peaks / Ratio
/ Set. Time
.RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Conpound.Name. . ID.. Flags.
328
13C12-TCDD
332-334
332-334
PeCDF
340-342
340-342
13C12-P6CDF
352-354
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
SN
SN
SN
SN
SN
SN
4
ML
WL
WL
WL
SN
SN
SN
SN
SN
SN
5
NL
SN
SN
SN
SN
SN
SN
SN
SN
-SN
SN
SN
SN
WH
0
NL
SN
19:37
20:42
21:01
21:10
21:21
21:29
21:44
21:55
21:59
22:07
Peaks
0
17
17
18
18
18
19
19
20
20
20
20
21
21
21
:00
:44
:57
:22
:42
:53
:06
:26
:01
:27
:41
:56
:03
:17
:36
0
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
9
9
15.28 15.28
,159.40 9,159.40
17.91 17.91
25.09 25.09
8.51
8.54
2.79
11.40
5.01
8.44
,217.68
.65-0.89
3.
1.
7.
2.
3.
2.
4.
2.
1.
0.
0.
0.
1.
1.
1.
Peaks
0
22
22
22
22
22
23
23
23
24.
24
25
26
26
:00
:00
:15
:22
:34
:52
:20
:48
:59
:17
:28
:45
:04
:21
1.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
45
33
02
68
45
42
11
18
14
33 10
33 9
56
31
19
53
19
ftlwim. .
.32-1.78
0.
2.
2.
0.
1.
0.
0.
0.
2.
0.
1.
0.
0.
1.
71
22
77
79
45
31
84
29
02
49
47
57
60
21
Peaks
0
23
:00
:19
1.
RO
32-
•0.
1.
1.78
82
47
7
15
6
17
6
7
9
5
27
,029
,005
33
140
19
14
.75
.31
.87
.10
.35
.36
.38
.82
.84 17.91
.60 4,545.51
.65 4,090.28
.77 14.69
.86 104.54
.72
.89
0.
1.
1.
1.
1.
1.
1.
1.
1.
1.
,948
,001 37C1-TCDD SOR1
,016
,023
,032
,039
,051
.060
063
069
0.903-1.097
0.
0.
0.
0.
0.
0.
0.
0.
15.73 0.
5,484.09 0.
4,915.37 1.
26.10 1.
79.58 1.
1.
1.
000
857
868
888
904
913
923
940
963
989 13C12-1234-TCDD RSI
000 13C12-2378-TCDD IS1
012
018
029
044
,237.72
3
10
10
5
6
5
18
2
13
.70
.51
.48
.97
.30
.43
.99
.30
.72
10.69 _ . . .
15
2
5
4
0
.50
.60
.38
.05
.00
0.904-1.081
0.
0.
0.
0.
0.
0.
0.
0.
0.
000
906
916
921
929
942
961
980
988
_ .__. 1. 000 12373-PaCDP AN
1.
1.
1.
1.
008
060
073
085
0.835-1.165
3
28
.72
.67
0.
0.
000
960
'riangle Laboratories, Inc.® Analytical Services Division
!01 Capitola Drive • Durham, North Carolina 27713
'hone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 20:46 07/22/97
198
-------
Page No. 3
07/22/97
Compound/
M_Z. . .. QC.Log Omit T.-fhy
Listing of W972830B.dbf
Hatched GC Peaks / Ratio / Rat. Tim*
.RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
DC
DC
352-354
PaCDD
356-358 DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
356-358
13C12-PeCDD
368-370 DC
DC
DC
DC
DC
DC
DC
368-370
HxCDF
374-376 DC
DC
D D
DC
DC
DC
DC
DC
SN
SN
3
NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
WH
HH
WH
0
NL
SN
SN
SN
SN
SN
SN
2
NL
SN
SN
SN
SN
SN
SN
SN
23:
24:
25:
26:
26:
55
17
04
00
25
RO
RO
1.
1.
1.
1.
2.
Peaks
0:
23:
23:
23:
24:
24:
24:
24:
25:
25:
25:
25:
25:
26:
26:
26:
00
22
35
46
03
17
30
46
20
29
37
44
53
10
14
26
1.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
12
49 6
48 7
45
35
13
32-1.78
1.
1.
1.
0.
1.
1.
0.
0.
0.
1.
0.
2.
2.
1.
3.
1.
03
22
46
51
53
96
35
27
18
02
85
25
55
60
52
02
Peaks
0:
23:
23:
24:
24:
25:
25:
26:
00
37
49
16
49
:27
36
:05
26:23
1.
RO
RO
RO
RO
RO
RO
RO
43
,649
.197
13
7
,890
.43 26.40
.47 3,975.31
.75 4,295.88
.16
.85
.65
23.59 0.
2,674.16 1.
2,901.87 1.
1.
1.
985
000 13C12-PeCDF 123
032 13C12-PeCDF 234
071
088
IS2
STJR2
3
4
24
2
12
16
4
2
5
13
8
4
8
9
6
10
0
.49
.35
.83
.52
.98
.12
.47
.29
.15
.23
.29
.41
.26
.39
.50
.28
.00
32-1.78
1.
2.
0.
2.
0.
1.
1.
3.
2.
Peaks
0:
27;
27:
27:
27:
27;
27:
28:
28:
:00
:03
:09
:22
:30
:47
:49
:02
:08
1.
RO
RO
RO
RO
RO
RO
.05-
1.
1.
0.
1.
0.
0.
0.
1.
2.
12
33
80
62
41
47 3
60
10
63
4
1.43
19
22
93
78
77
85
34
08
60
3
11
4
16
5
,931
427
12
14
.49
.76
.52
.47
.07
.12 2,340.68
.42 263.08
.95
.33
0.918-1.027
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
1.
1.
1.
1.
1.
1.
0.843-
0.
0.
0.
0.
0.
1,590.44 1.
164.34 1.
1.
1.
000
918
927
934
945
954
963
973
995
001 12378-PeCDD
007
Oil
017
028
031
039
1.157
000
928
936
954
975
000 13C12-PeCDD 123
006
025
037
AN
I S3
,358.54
8
12
23
7
8
1
2
40
12
.22
.52
.95
.95
.51
.59
.78
.11 20.78
.59
0.956-1.053
0.
0.
0.
0.
0.
0.
0.
19.33 0.
1.
000
962
966
973
978
988
989
997 123478-HxCDF
001 123678-HxCDF
AN
AN
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 20:46 07/22/97
1QQ
-------
Page No. 4
07/22/97
Compound/
M_Z.... QC.Log Omit Why
Listing of W972830B.dbf
Hatched OC Peaks / Ratio / Ret. Time
.RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Ral.RT Compound.Name.. ID.. Flags.
374-376
13C12-HXCDF
384-386
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
SN
SN
SN
SN
SN
SN
SN
SN
SN
WH
1
NL
SN
28
28
28
28
28
29
29
29
29
29
:18
:28
:40
:47
:53
:02
:02
:34
:36
:44
RO
RO
RO
RO
RO
RO
RO
RO
RO
0
1
0
1
2
1
0
0
0
1
.15
.58
.82
.79
.86
.30
.40
.45
.85
.97
Peak
0
27
27
28
28
28
:00
:00
:09
:01
:07
:20
28:23
0
RO
RO
RO
RO
RO
28:39
29:22
DC
SN
29:36
29:39
384-386
HxCDD
390-392
D
390-392
13C12-HXCDD
402-404
DC
DC
DC
DC
DC
DC
DC
DC
DC
D
DC
DC
DC
. .DC-
DC
DC
DC
DC
DC
SN
8
NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
-SN -
SN
SN
WH
WH
0
NL
WL
29:46
RO
RO
RO
1
4
19
7
2
1
3
4
4
2
40
.03
.37
.82
.39
.96
.40
.14
.15
.70
.17
.11
.43-0.59
0
0
0
0
0.
0,
.62
.68
.68
.52 6
.51 6
.89
0.37
0.51 6
0.
0.
1.
0.
Peaks
1.
0:00
27:23
27:32
27:36
27:46
27:
47
28:03
28:
28:
28:
28:
28:
28.:
29:
29:
29:
29:
08
16
29
47
52
57
00
12
21
36
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
.51 5
.28
.02
,60
25
JV WAI FA . 1
20
36
38
,217
,902
21
23
,095
,765
29
19
25
,095
LTwiTM
.04
.75
.32
.48
.09
.06
.12
.76
.17
.16
.34
.53
.97
7 / Uun
05-1.43
1.
1.
0.
0.
1.
0.
8.
2.
0.
6.
0.
1.
12
16
81
66
67
20
60
42
64
06
57
64
1-99 .
0.
0.
4.
3.
12
37
19
47
Peaks
0:
27:
00
27
1.
RO
05-
0.
1.
1.43
91
06
6.
4.
10.
4.
3.
2.
3.
5.
22.
1.
3.
13.
.59
.85
.33
.32
.70
.08
.67
02
20
16
50
89
. 2-17 ...
0.
6.
5.
6.
0.
7.
11.
72
16
39
83
00
17
25
1.007
1.012
1.020 234678-HxCDF
1.024
1.027
1.033
1.033
1.052
1.053
1.057
0.858-1.142
0.000
16.62 24.34 0.960
17.26 25.38 0.966
2,127.86 4,089.62 0.996 13C12-HXCDF 478
2,346.06 4,556.03 1.000 13C12-HXCDF 678
12.43 13.95 1.008
1.009
2,064.18 4,031.58 1.019 13C12-HXCDF 234
1,944.05 3,821.12 1.044 13C12-HXCDF 789
1.053
13.04 12.81 1.055
1.059
f"*nn "Pol 1 r»t»/e
0.949-1.015
0.000
0.949
0.954
0.957
0.962
0.963
0.972
0.975
0.980
0.987 .
0.998 123478-HxCDD
1.001 123678-HstCDD
- . . . 1.0Q3-
1.005
1.012
1.017
1.026
0.965-1.035
0.000
0.951
AN
SUR3
1 34
ALT2
ALT1
AN
AN
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 20:46 07/22/97
200
-------
Page No.
07/22/97
Listing of W972830B.dbf
Matched SC Peaks / Ratio / Rec. Time
Compound/
M_2.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.PT Compound.Name.. ID.
Flags.
402-404
HpCDF
408-410
M
408-410
13C12-HpCDF
418-420
418-420
HpCDD
424-426
D
D
424-426
13C12-HpCDD
436-438
436-438
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
D
D
DC
ML
WL
SN
SN
SN
SN
SN
SN
5
NL
SN
SN
SN
SN
SN
WH
1
NL
SN
2
NL
SN
SN
0
NL
2
27:36
27:46
27:54
28:00
28:02
28:15
28:31
28:36
28:47
28:51
29:09
29:26
29:33
Peaks
0:00
30:53
31:10
31:15
31:33
31:41
32:07
32:23
Peak
0:00
30:53
31:12
32:05
Peaks
0:00
31:10
31:45
Peaks
0:00
31:44
32:07
Peaks
RO
RO
RO
RO
RO
RO
RO
1
1
2
0
1
0
1
0
1
1
1
0
3
.21
.19
.51
.47
.51
.92
.38
.17
.24
.21
.22
.92
.09
5
8
3
3
3
22
3
2
4,840
6,213
6,410
76
20
.50
.67
.67
.00
.18
.71 12.57
.53
.69
.19 2,679.64
.30 3,406.77
.29 3,519.24
.72 42.47
.92
0.
0.
0.
0.
0.
13.72 0.
0.
0.
2,160.55 0.
2.806.53 1.
2,891.05 1.
46.12 1.
1.
957
962
967
971
972
979
988
991
998 13C12-HXCDD 478
000 13C12-HXCDD 678
010 13C12-HXCDD 789
020
024
SOR4
IS5
RS2
17,563.21
0.
RO
RO
RO
RO
RO
0.
RO
RO
0.
RO
0.
RO
88-1.20
1
1
0
1
1
1
0
2
.60
.34
.88
.17
.29
.10
.76
.91
6
44
9
13
6
9
12
7
44
.14
.47 29.20
.97
.93
.98
.22
.24
.04
.47
37-0.51
1
0
1
0
.88
1
0
0
.28
.44
.74
.44
-1.20
.46
.93
.91
8
4,166
7
2,834
.78
.43 1,263.06
.11
.48 871.92
0.996-1.045
0.
21.80 1.
1.
1.
1.
1.
1.
1.
000
000 1234678-HpCDF
009
012
022
026
040 1234789-HpCDF
049
AN
AN
0.935-1.130
0.
2,903.37 1.
1.
1,962.56 1.
000
000 13C12-HpCDF 678
010
039 13C12-HpCDF 789
IS6
SUR5
7,000.91
3
24
51
0
.61
.89
.10
.00
.88-1.20
0
1
0
.96
.06
.61
11
3,468
28
.88
.40 1,788.32
.62 14.59
3,497.02
Above: HnCDD / Octa-CDD and CDF
0.976-1.006
0.
0.
1.
000
982
001 1234678-HpCDD
AN
0.968-1.032
0.
1,680.08 1.
24.03 1.
Follows
000
000 13C12-HpCDD 678
012
IS7
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 20:46 07/22/97
-------
Page No.
07/22/97
Listing of W972830B.dbf
Matched OC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2. . Rel.RT Compound.Name.
ID.. Flags.
OCDF
442-444
AN
442-444
OCDD
458-460
458-460
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
SN
SH
SK
SN
SN
SH
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
1
NL
SN
SN
SN
1
0:
30:
31;
31:
31:
32:
32:
32:
32:
32:
33:
33:
33:
33:
34:
34:
35:
35:
35:
35:
:00
;58
:20
:45
;53
:02
:15
:32
:41
:52
:01
:16
38
:47
00
:18
:01
:07
:16
46
0,
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
.76-1.02
1.
1.
0.
1.
2.
0.
0.
1.
0.
1.
0.
0.
0.
0.
1.
1.
2.
0.
0.
1.
01
90
78
00
05
19
92
80
59
20
34
41
94
35
24
13
10
84
38
09
Peak
0:
34:
34:
34:
34:
00
03
12
35
45
0.
RO
RO
76-1.02
0.
0.
1.
0.
0.
97
15
00
77
65
Peak
5.57
4.88
14.06
9.02
7.35
1.47
13.77
3.57
9.64
9.94
16.29
5.50
6.81
9.53
10.66
38.37
8.07
11.23
5.03
5.99
38.37
4.25
1.89
50.50
8.69
5.18
50.50
22.90
25.30
0.883-1.117
0.000
0.905
0.916
0.928
0.932
0.937
0.943
0.951
0.956
0.961
0.965
0.973
0.983
0.988
0.994
20.30 1.003 OCDF
1.024
1.027
1.031
1.046
0.883-1.117
0.000
0.996
25.20 1.000 OCDD
1.011
1.016
AN
AN
13C12-OCDD 0.76-1.02
470-472 DC NL 0:00 0.88 4.35
34:12 0.91 3,842.12
470-472 1 Peak 3,842.12
1,831.31
0.996-1.005
0.000
2,010.81 1.000 13C12-OCDD
IS8
Column Description "Why" Code Description QC Log Desc.
M_Z -Nominal Ion Hass(es)
..RT. -Retention Time (mm:ss)
-Rat_0~-Ratio- of- H/M+2- Ions
OK -RO=Ratio Outside Limits
Rel.RT-Relative Retention Time
End of Report
WL-Below Retention Time Window A-Feak Added
WH-Above Retention Time Window K-Peak Kept
-SN-Belou-Signal to.Moise. Lave] D-Peak. Deleted
-------
Pil»:W972830 41-798 Aoqt22-JUL-1997 13:50:47 GC XI* Voltage SIX 70SX Boil*:4410
303.9016 Ti2 BSUB(256,30,-3.0) PXD(9,5,5,0.101,17640.0,1.00\,r,T) XXp:XPCUS2
TXIASGLX LABS Tmxt:H23-OPTLXT-XBl TLI»42299A
A3.21X5
A3.13X5
-4.0X4
17.00 IBtOO 19100 20:00 21:00
Til»tM972830 tl-798 Aoqt22-JOL-1997 13:50:47 GC XI + Voltage SIX 70SX Bol**i3336
305.8987 Pt2 BSOB(256,30, -3.0) PKD(9,5,S,0.10\,13344 .Or1.00\,T,T) Xxp:XPCUS2
TXIAHSLX LAM TuxtiM23-OOILXT-Xai TLH42299A
1003
80.
22*00
-.0.0X0
Time
7.4X4
.9X4
17(00 18(00 19(00 20:00 21100
rilt:tf972830 tl-798 Acq:22-JUL-1997 13:50:47 GC XI+ Voltage SIX 708X Boia»:2359
315.9419 P>2 BSUB(256,30,-3.0) PKD(9,5,S,0.10\,9436.0,1.00\,T,T) XxpiXPCUS2
TXIAHGLX LABS T»xt:M23-OUTLXT-SBl TLH42299A
1001
801
601
401
201
01
22100
O.
17i00 18iOO 19:00 20iOO 21:00
Pll*iW972830 fl-798 Aoqt22-JUL-1997 13:50:47 GC XH- Voltage SIS 70SX Soim»tll34
317.9389 Pt2 3SUB(2S6,30,-3.0) PXD(9,S,S,0.10\,4536.0,1.00\rP,T) Xxp>XPCUS2
TXIAHGLX LASS TtuctsM23-OUTLXT-X31 XLH42299A
1001
aol
601
40:
201
OJ
22*00
17:00 18:00 19:00 20:00
Pil»:ta72830 '1-798 Acq:22-Jm.-1997 13:50:47 GC XI + Voltage SIS 70SX
330.9792 P:2 XxpiXPCOS2
TXIAHSLX LABS T*It:M23-OOTLXT-BBl TLH42299A
1001
801
601
401
201
01
21100
22:00
0X0
Time
.2X7
.9X6
.4X6
.0X6
.5X6
0X0
Time
6X7
3X7
8X6
5X6
3X6
.0X0
Tiff
-.5.
4X6
0X0
17100 18:00 19:00 20:00
•il*:K972830 il-798 Acqt22-JUL-1997 13t50t47 GC XI + Voltage SIS 70SX
175.8364 Pi2 Xxp:XPCU82
TXIANGLX LASS TmrtiM23-OOTLXT-XBl TLIt42299A
21100
22:00
1001
801
601
401
201
01
16
40
18*05 21i25 '.6
klJL^J^JifiJ^
1X5
1X4
8X4
5X4
3X4
0X0
17 tOO
10(00
19(00
20100
21100
22:00
-------
r±lm,M972830 41-798 Aoq,22-Jm,-1997 13,50,47 GC XI+ Voltagm SIS 70SX Holme ,1223
319.8965 T,2 BSUB(256,30,-3.0) PXD(7,5,3,0 .10\,4892.0,1.00\,T,T) XxptXPCUS2
TXIAHGLX LABS Tmxt,H23-OUXLXI-XBl TUf42299A
100.
80.
60.
40.
20
w ^=--. iy^~7 fY-^ j, ^- ,' 3 • -}~ *<=•
v , "7 J * L- / "^ -^~"
\ ' r it " f ' j
\t *- '
. A1.05X5 A2.31X5
nil A 111 AtfT*4 ll 1 ^'l^/liL ^"f'finr 77**9\i
' 18,00 19\00 30\00'
A3. 4 8X5 9.3X4
-
.,. 1 , M..50X5 Ae. 32X4 [
L f\J Ji.fi ^'^'U
yj VV^AAMWI^JU^
.7.5X4
.5.6X4
.3.7X4
J Of A
' 21tOo' ' ' 22,00' ' Time
rUm>H972830 tl-798 Acqi22-JOZ-1997 13,50,47 GC XH- Voltage SIX 70SX Xo±me,1208
321.8936 r,2 BSVB(256,30,-3.0) PXO(7, 5,3,0. 10%,4832. 0,1. 00\,F,T) X*p,XPCVS2
SXIAHSLX LABS Taxt,M23-OOTLXT-RBl TLXt42299A
1001
80.
60.
40.
20.
0
A2.41X4 A1.33X5 A6.14X4 A6.11X4 .
1 II A5.09S4 1 . * j l.iiiA h A
JWjJ^Ju^Mu*^t\j>i^fjM^i(^^
' IStOO ' ' ' 19\00 ' ' 20',00'
A6.58X5 -1.7X5
[ A6.63X4
i 1 MP'^5W I AI.«1JB5
MX HWAyMjJL\--^JV/UAA«^^\
'.1.3X5
ll.OXS
-.6.7X4
•
-.3.4X4
'• o . oto
'21\00' ' ' '22iOo' Time
r±lm,H972830 #1-798 Acq : 22-JUL-1997 13,50,47 GC XI + Voltage SIX 70SX Ooimm>7557
331.9368 r,2 BSUB(256,30,-3.0) PXD(7,5,3,0.10\,30228.0,1.00\,T,T) Xxp,XPCOS2
XXIASSLX LABS TfXtiM23-OOXLXT-XBl TLH42299A
ion
aol
60-.
40:
20:
o:
A4.
i
'ifllofl 19'tOO 20,00'
5X7 .1.1X7
A4.09X7
u
\^_
.8.5X6
'.6.4X6
.4.2X6
.2.1X6
2l',00 22\00' ' Time
TilmiM972830 41-798 Aoy,22-JOL-1997 13,50,47 GC XI+ Voltage SIX 70SX BoLmm,2189
333.9338 P,2 BSVB(256,30,-3.0) PXB(7,5,3,0.10\,8756.0,1.00*,T,T) Xxp,XPCUS2
TSIANSLX LABS 3*rttM23-OOTLXT-XBl TLH42299A
1001
ao:
60:
40:
20:
0:
AS. 4
}
I
}
ia',00 19iOO 20\00
rll*,W972830 tl-798 Acq,22-JVL-1997 13,50,47 GC XI* Voltagm
(S7 -1.3X7
4.92X7
J
V
'-.1.0X7
.7.8X6
.5.2X6
.2.6X6
O.OXO
' 2l',00 22',00' ' Time
SIX 70SX Holme, 1248 •
327.8847 P,2 BSOB(256,30,-3.0) PXD(7,5, 3, 0.101,4992.0,1 .00\,f,T) XxptXPCDS2
TSIABGLX LABS TextHC23-OVTLfT-R31 XHII42299A
1003,
80:
60:
40:
20:
o:
A9.
i
18tOO 19tOO 20,00
rilei>r972a30 tl-798 Aoq,22-JVL-1997 13,50,47 GC XI + Voltagm
330.9792 r,2 Xxp,XPCOS2
XBIANGLX LABS TmxttM23-OnXLXT-XBl XLH42299A
1001
A/f ' '
BQ.
60:
40:
20:
o':.
-*&£r*^£L*^^
IsiflO 19(00 SOiOO
6X7 2.2X7
V
.1.7X7
.1.3X7
.8.7X6
.4.4X6
O.OXO
21\00 22,00 ' Time
SIX 70SX
0,3$i" 21,06 21,38 22,05 r
^\^v^-^^^^^Vy^^^A/V^*V**>-^»-^r<^^
.2.7X7
.2.2X7
.1.6X7
.1.1X7
.5.4X6
O.OfO
21 ', 00 221, 00 Time
2u4
-------
22,00 33,00 24tOO 35,00
r±l»tM972830 tl-798 Aoq,33-JUL-1997 13,50,47 GC XH- VoltMgm SIX 703X Bolm»tl579
341.8567 Tt2 3803(356,30,-3.0) PXD(7,5,3,0.101,6316.0,1.00\,f,T) XzpiXPCUS2
XXIA1KLX LABS T*xtiM33-OUTLST-XBl TLIt43399A
23,00 33100 34,00 25,00
Tllmttl972830 tl-798 Aaqt22-JUL-1997 13,50,47 GC XH- Voltmgm SIX 70SX Mo±M»tll28
351.9000 Pt2 3803(256,30,-3.0) PXD(7,5,3,0.10\,4512.0,1.00\,r,T) XzpiXPCOS2
XSIASOLX LABS TaxtlM33-OOTLXT-XBl TLH43399A
100* A3.98X7 '
50.
40.
30.
ril»iW973a30 f1-798 Acqi33-JUL-1997 13tSOi47 GC XH- Voltmgm SIX 70SX tfoia»:lJ.25
339.8597 Tt2 3803(256,30, -3.0) PXD(7,5,3,0.10%,4SOO.0,1.00*,r,T) XxpiXPCOSa
TXIASGLX LAM Ztatt/aj-ODZUT-XU TLH43399A
1001
80.
sol
40.
aol
A9.17X4
A1.14X5
A1.15X5
AS.08X4
A1.59X5
A1.09X5
13.43X,
Al.
.14X4
8X4
26100
36100
V
33,00 33i00 34i00 25iOO
Til»,VS73830 tl-798 Acqt23-JVL-1997 13t50t47 GC H+ Volttgu SIX 70SX Bo±Mmtl371
353.8970 Tt3 3803(356,30,-3.0) PXD(7,5,3,0.10\,5484.0,1.00\,T,T) XxpiXPCUS2
TXIANSLX LA3S TortiM23-OOXLXT-X31 XLI942299A
26't 00
1003
80.
60l
40:
30.
A2.67X7
A3.90X7
32,00 23,00 24*00 35,00
Til»iM972830 tl-798 Aoqt23-JUL-1997 13t50i47 GC XH- Voltage SIX 70SX
330.9792 Ti2 XlcptXPCOS2
TXIANGLX LABS TurtiM33-OOXLXT-X31 XLH43399A
"l48 35,10
33,36 ~~34t0734t24 "•Aft ~ ~ ./Vr-?*'**
—*s*~>*~s+ef**v~-~~f*->f
1003
80J.
60.
40.
aol
36100
32t27 32t47
33100 33100 34100 35,00
r±l»,K972830 #1-758 Acqt33-JUL-1997 13tSOt47 GC XH- Volt*?* SIX 70SX
409.7974 Ti2 XzptXPCUSa
TXIASGLX LABS Tmxtilt23-OOXLXT-X31 TLH43399A
100*
36100
23131
tffl
40J
20.
ol
33tOO
33,43
22121
23,051
23100
6,
Is.
':4.
'•.3.
:i.
£o.
8X4
5X4
1X4
7X4
4X4
0X0
3X7
6X6
3X6
8X6
4X6
0X0
34,40 25,33 36,08 ;
(^JM$^^
34,00
25100
26100
2X6
6X6
.9X6
.3X6
.6X6
.0X0
Time
.3X7
.6X7
.0X7
.3X7
.5X6
.0X0
Time
.3X5
.0X5
5X4
.0X4
.5X4
.0X0
Tim»
205
-------
j~-ju±,-±yy/ AJIDVUS I*G sir waxug* SIM 70SX
355.8546 Ti2 BStn(256,30,-3.0) pat(7,5,3r0.10\,4244.0,1.00\,r,T) KxptXPCUS2
OtZJOKLX LASS TuxtiM23-OOZZXT-Ul XLXf42299A
100* A1.47X5
0J I '
24'tOO 25*00 26'tOO
rilmtV972830 il-798 Aoqt22-JVL-1997 13t50t47 GC IT* Valtmg* SIX 70S* BoimmilOSO
357.8516 Tt2 BSU*(256,30,-3.0) PXD(7,5,3,0.10\,4120.0,1.00\,r,I)
LAM TaxttM23-OtnifT-MBl XLI«42299A
24100 25100 26100
r±J.m:H973830 fl-798 Act[t22-JVZ-1997 13i50i47 SC XH- fbltaga 5ZK 70S* Bolauil062
367.8949 T»2 SSV3(256,30,-3.0) PB>(7,5,3,0.10\,4248.0,1.00\rr,T) SxptXPCUS2
AflGUr LABS Toitttaj-OUTLXT-Ral XLII42299A
10 0\ A2.34X7
80.
60.
40.
20.
.63X6
24 1 00 25tOO
r±l»ttf972830 tl-798 Aaqt22-JUL-1997 13i50t47 GC XH- WUt*g» SIX 70S* Holm*t947
369.8919 fi2 BSOB(256,30,-3.0) PXD(7,3r3,0.10\,3788.0,l.OO\,T,T) XxptSPCUS2
TXUUKLX LASS Tart;JO3-OOZUT-Ul TLH42299A
100& A1.59X7
so:
60.
40.
20:
26tOO
.64X6
24 tOO 2StOO
il»iM972830 tl-798 Aoqt22-JVL-1997 13 1 50 1 47 GC XI+
30.9792 n2 XxptXPCOS2
TXIABSLX LASS TaxH,H23-OVTUSI-X31 TLH42299A
24 1 48
26100
SIX 70SX
00$
80.
60.
40.
20:
0.
6.9X6
'.5.5X6
'.4.2X6
.2.8X6
1.4X6
0.0X0
Tim,
4.7X6
3.8X6
2.8X6
-9.5X5
0.0X0
Tim*
23136
26 til
24'tOO
25(00
26tOO
-.3.3X7
'.2.6X7
.2.0X7
-1.3X7
-6.5X6
0.0X0
206
-------
r±l»,U972830 tl-422 Aog,22-JUL-1997 13,50,47 GC XH- Volt*g» SIX 70SX SaiMm,2235
373.8208 r,3 BSUB(256,30,-3.0) rXD(7,5,3,0.10\, 8940.0,1.OQ\,T,T) Xxp,XPCOS2
XXIABGLX LABS Tfrt,lO3-OVJXXT-XBl XLIt42299A
1001 A3. 8X5
27,00 27,12 27124 27)36 27,48 28,00 28,12 28,24 28,36 28,48 29,00 29,12 29,24 29,36 29,48
ril»,U972830 tl-422 Aoqi22-JUL-1997 13,50,47 SC XX* Voltmgm SIX 70SX Boifm,1873
375.8178 f,3 BSUB(256t30,-3.0) PKD(7,5,3,0.10\,7492.0,1.00*,r,T) Xxp,XPCOS2
XBIAJXLX LASS T»rt,M23-OOTLET-SSl XLH42299A
100* A1.93S5
27,00 27,12 27,24 27,36 27,48 28,00 28,12 28,24 28,36 28,48 29,00 29,12 29,24 29,36 29,48
rll9iM972830 tl-422 Aoqi22-JUL-1997 13,50,47 GC XH- Volttgm SIX 708X Soim»,4107
383.8639 T>3 B3Ut(256,30,-3.0) fXO(7,5,3,0.10^,16428.0,1.00\,r,T) Krp,XfCUS2
TXIA1KLX LASS Ttat,M2J-OUTLXT-X31 TLIt42299A
1001
aol
601
401
20l
A3.13X7
A3.06X7
A1.94X7
27,00 27,12 27124 27,36 27,48 28:00 28,12 28,24 28,36 28,48 29,00 29,12 29,24 29,36 29,48
Fil»,H972830 tl-422 Acqi22-JUL-1997 13,50,47 GC XI+ Volt«g» 5X1 70SX 9oi*»,6637
385.8610 f,3 S3UB(256,30,-3.0) TXD(7,5,3,0.10\,36548.0,1.00\,T,X) XxptKPCUSS
TSIASGLX LASS TmrttH33-OOTUST-XMl XLIt42299A
1001
sol
60'
401
O
A4.03X7
A3.82X7
} V
27:00 27,12 27,24 27,36 27,48 28:00 28,12 38,34 38,36 38,48 29,00 29,13-29,24 29,36 29,48
Til»iM972830 tl-422 Aoq,23-JUL-1997 13,50,47 GC XI + Voltmg* SIX 70SX
392.9760 f,3 XxptXPCUSS
TBIARSLX LABS Text :M23-OUTLET-SSI TLIt43299A
28,46 39,06
8X6
3X6
7X6
1X6
6X6
0X0
Time
.4X7
.2X7
.7X6
.8X6
.9X6
.0X0
TiMt
371,00' '27Vl3' 27',24' 27,36 27,48 28,00 28,12 28,24 28,36 28,48 29,00 29', 12 29',24 29,36 29,48
T±lm,H97283Q tl-422 Aoq,22-JVL-1997 13,50,47 GC XI+ Volt*gm SIX 70S!
445.7555 T,3 Xxp,XPCUS2
XXZAJteZX LASS Tmzt,M33-OUTUST-X31 XLH43299A
1003, 39 18
802
602
402
202
02
28,39
27,50
\d^jJ\.*Lj3&^^
29,09
' 27\00"27\'l2 "27\24 27:36 27,48 28:00 28,12 28,24 28,36 28,48 29,00 29112 29,24 29,36 29,48
.1X5
.6X4
.4X4
.3X4
.1X4
.0X0
TiMf
-------
27 24 37',36 27,48 28,00 28,12 28,24 2»i36 28i48 29*00 29il2
T±1»,H972830 tl-422 Aoq,22-JOZ-1997 13i50i47 GC XH- Yoltmgm SIX 70S* Soim»*1555
391.8127 Tt3 BStTB(256,30,-3.0) PXD(7,5,3,0.10\,6330.0,1.00\,r,T) XxptXPCOSS
TXIAVGUS LABS Tmrt,M23-OUTLXT-XBl TU 44 2299A
100\
Tlle,t(972B30 tl-422 Acq,.12->Juli-iyyf u,3Uti7 sc si-t- voiuge six toss aoiaeij.
389.8156 rt3 BSOB(256r30,-3.0) PKD(7,3,3r0.10\,6953.0,1.00\,r,T) Xxp,XPCVS2
THJOKLX LASS T*xtiM23-OOTL£T-ZBl TLH42299A
29,24 29,36
.0X0
T±m»
27 24 27,36 27,48 28,00 28,12 28,24 38,36 28,48 29,00 29,12 29,24 29,36
r±l»t*972830 tl-422 Acq,22-JVL-1997 13,50,47 GC XH- Voltmg* SIX 70SX Hoia»,1983
401.8558 f,3 BSUB(256,30,-3.0) PXD(7,5,3,0.10\,7932.0,1.00\,T,X) frp,XPCOS2
TXIAHSLX LABS T*rt,M23-OOTLXT-XBl XLIt42239A
A3.52X7 "1'
80.
60.
40.
20.
0X0
Time
2X7
5X6
2X6
8X6
4X6
0.0X0
27 24 27,36 27,48 28,00 28,12 28:24 28,36 28,48 29,00 29,12
rllt,H972830 tl-422 Aoq,22-JUL-1997 13,50,47 GC XH- Voltaga SIX 70SX !To±f*,2169
403.8529 f,3 BSUB(256,30,-3.0) PXD(7,5,3,0.10\,8676.0,1.00\,T,X) Xxp,XPCOS2
TXIAVGLX LABS Tart, H23-OUTLET-JUB1 XLH42299A
"•{it7 A3.89X7
. A
80.
so:
40.
20.
29,24 29,36
i i i i i I i i i i i I i i i i i I i i i i i t"T"^BT' i i i i ^-T-n^r^rT"!
27 24 27,36 27,48 28,00 28,12 38,24 28,36
•llo,K972830 tl-422 Aey,22-Jm-1997 13,50,47 GC XH-
'92.9760 T,3 Xxp,XPCOB3
TXIAHGLX LABS T*rt,M23-OUTLZT-RBl XLXt42399A
OOi, 27,33 „ .. 38t46
37,44 37,58 38,10
~. AJ»> ^ AS*
80.
60.
40.
20.
0.
-9.8X6
.7.8X6
.5.9X6
'.3.9X6
-.2.0X6
38,48 39,00
SIX 70SX
i i I i I^^^TT i i i i i i
29,12 29,34 29,36
0.0X0
TiMtA
28154
29,06
-1.6X7
'.1.3X7
.9.5X6
.6.3X6
.3.2X6
0.0X0
27 24 27,36 27,48 28,00 28,13 28,24 28,36 38,48 29,00 29,12 29,24 29:36 T±mm
208
-------
Til»*H972830 #1-441 Acqs22-JOL-1997 13i50t47 GC XX+ Voltagw 5X1 70S* Hoim»i2413
407.7818 ts4 BSV3(256,30, -3.0) PKD(7,5,5,0.10%,9652.0,1.00\,r,T) Xrp*XfCOS2
TXIABGLX LAMS Tmxt*M23-OOTLXT-XBl TLH42299A
10M A3. $1X5
30,48 31,00 31,13 3it24 31*36 31,48 32*00 32*12
T±l»iH972830 41-441 Aoj,22-JVL-1997 13i50i47 GC XH- Vblt«g» SIX 708* Ho±M**1507
409.7789 r*4 3803(256,30,-3.0) PKD(7,5,3,0.10\,6029.0,1.OQ\,r,T) Xxp*XrCU32
TXIAHGLX LA3S TurttM23-OOXtJCT-S31 XLH42299A
32t24
ion
so:
60:
40:
20.
A2.79X5
AS.31X4
A A6.4
A3.42X4 A4.40X4
,2.75X4
30:48 31,00 31,12 31,24 31,36 31,48 32iOO 32', 12
M2»iV972830 #1-441 Acq,22-JUL-1997 13,50,47 GC XI+ Vtilttgm SIX 70SX 3toim»i3913
417.8253 rs4 3SO3(256,30,-3.0) PXD(7,5,3,0.10\,15652.0,1.00\,T,T) XxptXfCU32
TRIANGLE LA3S TaxtlJOJ-OtTZCET-JUl TLIt42299A
1001 A1.26X7
32124
80:
60:
40:
20:
A8. 72X6
30,48 31,00 31,13 31,24 31i36 31,48 32,00 32,12
r±J.aiH972830 #1-441 Aoq,22-JUL-1997 13i50t47 GC XI + Voltfym SIX 703X Boia»,3050
419.8220 Tt4 3SUB(2S6,30,-3.0) PXD(7,5,3,0.10\,13200.0,1.00\,r,T) Xzp,fPCU32
TXIANCLX LASS TextjJOJ-OOTLTT-JLBl TLII42299A
1001 A2.90X7
A1.96X7
32124
30t48 31,00 31,12 31,24 31,36
ril»iK972830 #1-441 Aoq,22-JVL-1997 13,50,47 GC XI +
430.9729 F>4 XxptXPCUS2
XRIAHGLX LASS TuxttM23-OOTLXT-XBl XLH42299A
31Li4 31t34
" ' - — ~" -- " '" " f^/^^^t f^\ ^^-n^i^
aoj
so:
40:
20:
oj
31i48 32,00
SIX 70S*
32,13
32*24
30,48 JltOtf 31,12 31*24 31*36 31,48 32*00
r±l»iH972830 #1-441 Acqt22-JOL-1997 13*50*47 GC XH- Volt»ym SIX 70S*
479.7165 Tit Xxp,XPCUS2
TXIAHSLX LABS T*xttM23-OUTLXT-X31 TLH42299A
1001
32,12
32,24
30,48
31*00
31*12
31*24
31*36
31*48
32*00
32*12
32,24
32,36
32*36
-4.3X6
.3.4X6
.2.6X6
.1. 7X6
.8.5X5
32*36
0.0X0
T±m<
-9.2X6
-.7.4X6
.5.5X6
.3.7X6
.1.8X6
32 36
u.0.020
T±m,
•.9.2X6
.6.9X6
.4.6X6
.2.3X6
32 36
0.0X0
T±m»
32*36
209
-------
Til»,U972830 tl-441 Aoqtl2-Juli-J.yy/ IJiiUH/ BC JSI+ YOJ.cag» SIX /OSS JfoxfmiJ.
423.7766 Tt4 3803(256,30,-3.0) PKD(7,5,3,0.10\,5164.0,1.00\,r,T) XxpiXPCUS2
XXIABSLX LASS TmxtiM23-OOTLST-*31 TLH42299A
1004 A3.43X5
.8.0X4
31 1 Jff j Jlfl j.24 jO JliJtf 31 1 43 31:41 31t54 32: 00
ril»:N972830 H-441 Aaqi22-JOL-1997 13t50t47 GC XI+ Voltmgm SIX 70S* 9oif»i»84
425.7737 Tt4 3803(256, 30, -3.0) HO>(7,5,3,0.lO\,3536.0r1.00\,T,X) X*piXPCOS2
XSIAHSLX LABS TmxtiM23-OUTLST-RBl TLH43299A
100\ A3. 68X5
'32\06
^5.9X4
0.0X0
31', 00 31,06 31,12 31:18 31,34 31:30 31,36 31:42 31,4t 31,54 32tOO 32,06 32,12
Til»ttr972830 tl-441 Acqi22-JUL-1997 13,50:47 GC XH- Volt*g» SIX 70S* Soia*:2905
435.8169 Ti4 3SOB(256,30,-3.0) PXD(7,5,3,Q.10\,11620.0,1.00\,T,I) Xzp:XPCU33
TSIANSLX LABS ToxtiM23-OOXLXT-RBl TLIt42299A
100\ A1.79X7 _5.1S5
T±M»
80.
60.
40.
20.
.4.1X6
.3.1X6
U..OX6
0.0X0
Time
31,00 31:06 31:12 31:18 31:24 31:30 31:36 31:42 31,48 31,54 32*00 32,06 32>12
r±l*,H973B30 tl-441 Acqt22-jnZ-1997 13,50:47 GC XI + Voltag* SIX 70SX Bo±B*i3037
437.8140 Ti4 3303(256,30,-3.0) PKJ>(7,5,3,0.101,12148.0,1.00\,T,T) Xxp:XPCUS3
TXIANGLX LABS TerttM23-OOTLXT-RBl TLH42299A
1001 A1.68X7 ,.5.2X6
80.
601
40.
20:
31tOO 31t06 31tl2 31.118 31t24 31i30 31,36 31:42 31,48 31:54 32tOO 32,06 33112
r±l»>H972830 tl-441 Aoqt22-JUL-1997 13,50,47 GC XH- Volttgm SIX 70S!
30.9729 r,4 XxpiXPCO32
TXIASSLX LA38 TmXt,M23-OUTLET-SB 1 TLH42299A
001 31i14 31:24 31:44 31:53 32jJL
^^^^xy^-^^^\/^^/^^^->^x^^^^^\^^--~-^ ^N ^,
80.
60.
40.
20.
.4.2X6
.3.1X6
J..OX6
0.0X0
31tOO 31:06 31:12 31:18 31:24 31:30 31t36 31:42 31i4» 31:54 ' '32:66 ' 32:06 ' '32\12
-1.1X7
.9.0X6
.6.8X6
.4.5X6
-2.3X6
0.0X0
Xbral
210
-------
rU»>*97283d tl-441 Acq>l2-JVL-l997 13,56,47 GC XI+ Vbltag. SIX 700X Xo±M*tl4d6
441.7428 r>4 3303(256,30,-3.0) tXJ}(7,5,3,0.10\,5600.0,1.00\,T,I) XxptXPCUS2
TXIANSLX LASS Ttact:M23-OOTLXI-S31 TLI142299A
31'tOO 32100 33,00 34tOO 35', 00
m»tW972830 tl-441 Aoq,22-JVL-1997 13,50,47 GC XI + Voltag* SIX 708X Bo±m*tl387
443.7399 f>4 3SV3(2S6,30,-3.0) PKD(7,5,3,0.101,5548.0,1.00\,r,T) XxptSTCUS2
ZBXAHGXZ LASS T*xt,M23-OOTLET-aBl XLIt42299A
A3.27X5
36100 Time
31,00 32'tOO 33tOO 34,00
rilmiM972830 tl-441 Aoqi22-JVL-1997 13i50i47 GC SI+ Voltagre SIX 70SX
430.9729 r,4 XxpiEPCUS2
TB.IABGLX LABS Tart IM23-OUTLET-RBI TLH42299A
1004
35,00
0X0
36', 00 Urns
,^^vl^^^^
.9.0X6
17.7X6
16.4X6
15.2X6
-.3.9X6
-.2.6X6
LJ.3X6
0.0X0
31,00 32,00 33t00 34,00
r±l*iH972830 tl-441 Acqi22-JOL-1997 13,50,47 GC X1+ Volttgm 3IX 70SX
513.6775 r,4 XzptSPCUS2
TRIANGLX LABS T*rttM23-OOTL£T-tBl TLII42299A
100\
31156
35100
36,00 T±me
31,00
32,00
33100
34100
35100
36,00 Time
91 1
-------
34106 34tl2 34tl8 34t24 34i30 34\36
71101*972830 tl-441 Acqi22-JUL-1997 13:50:47 SC XX+ Voltage SIX 70S! BoiMe,1017
469.7779 Tt4 3SUB(256,30, -3.0) PXD(7,5,3,0.10\,4068.0,1.00\,T,T) Xxp,XPCUS2
TKUOKLX LASS TexttM23-OUTLET-RBI TLH42299A
100* A1.83X7
tU.e,tf9728JO tl-441 Acqt22-JVIi-ly97 UtSOl47 SC £1+ VOltfyf SIX 70Sf BOlme:104j
457.7377 Ti4 BSUB(256,30,-3.0) PKD<7,5,3,0.10\r4172.0,1.00\,T,T) Xxp,XPCUS2
TJUJOKLS LABS T*XtiH23-OOTLXT-XBl TX>Xt42299A
IOCS A3.95X5
.1.0X5
34',06 34tl2 34', 18 34,24 34,30 34,36
riluiV972830 tl-441 Aoqi22-JUL-1997 13:50:47 GC XH- Voltmgm SIX 70S* Moi***1078
459.7348 Ts4 BSVB<256,30,-3.0) fXS(7,5,3,0.10\,4312.0,1.00\,r,T) XxpiXTCUSS
TflAHGLX LASS TaxttH23-OOTLXT-RBl TLH42299A
1001 A3.13X5
80.
60.
40.
20.
A4.92X4
34,06 34:12 34:18 34,24 34,30 34,36
rile,H972830 tl-441 Acq,22-JUL-1997 13,50:47 CC XX+ Voltage SIX 70SX Soime:1160
471.7750 T:4 S8UB(256,30,-3.0) PXD(7,5r3,0.10\,4640.0,1.00\,r,T) XxptXPCUS2
TSOAJKLX LABS TextiM23-OOTLXT-XBl TLH42299A
*1X7
34,06 34,12 34:18 34,24 34:30
rilm,K972830 tl-441 Aoqi22-JUZ.-1997 13,50,47 QC XH- Voltagm SIX 70SX
430.9729 T:4 XzptXPCUS2
3XIAHGLX LABS Text :M23-OUTLET-RBI TLH42299A
100*
80.
601
40:
20:
34 i 36
o.oxo
34142 TiMe\
-6.2X4
.5.0X4
.3.7X4
.2.5X4
'-1.2X4
'.0.0X0
34142 Time
-4.3X6
.3.4X6
.2.6X6
.1.7X6
.8.6X5
.0.0X0
34142 Timi
-4.4E6
.o.oxo
34142 Time
-1.2X7
.9.9X6
.7.4X6
.5.0X6
.2.5X6
34106
34112
34:18
34,24
34130
34136
.0.0X0
34142 Time
212
-------
Peak Locate Examination:22-JUL-1997:13:49 File:W972830
Experiment:EPCUS2 Function:2 Reference:PFK ]
CO
T-l
CM
Volts
0.4160
330.94615
330.97925
331.01235
Volts
0.1085
416.93435
416.97604
417.01774
-------
rf
T-H
CM
File:W972830 #1-798 Acq:22-JUL-1997 13:50:47 GC EI+ Voltage SIR 70SE
319.8965 F:2 Exp:EPCUS2
Sample Text:M23-OUTLET-RBI TLI#42299A File Text:TRIANGLE LABORATORIES, ilNC .
100%
60 J
40J
20_
0
A3.39E5
: DBS
19:00 20:00 21:00 22:00 23:00
File:W972830 #1-798 Acq:22-JUL-1997 13:50:47 GC EI+ Voltage SIR 70SE
321.8936 F:2 Exp:EPCUS2
Sample Text:M23-OUTLET-RBI TLI#42299A File Text:TRIANGLE LABORATORIES, INC.:: DBS
100%
60J
40J
20j
OJ
19:00 20:00 21:00 22:00 j 23:00
File:W972830 #1-798 Acq:22-JUL-1997 13:50:47 OC EH- Voltage SIR 70SE
331.9368 F:2 Exp:EPCUS2
Sample Text:M23-OUTLET-RBI TLI#42299A File Text:TRIANGLE LABORATORIES, INC.:: DBS:
100% 20,27
80J
60J
40J
20J
0
19:00
20:00
21:00
22:00
.1.1E5
.8.7E4
.6.5E4
.4.3E4
.2.2E4
.O.OEO
Time
.1.8E5
.1.5E5
.1.1E5
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.O.OEO
Time
23:00
.1. 1E7
.8.5E6
.6.4E6
.4.3E6
.2 . 1E6
.O.OEO
Time
-------
File:W9728JU ftl-44l Acq;22-JUL-1997 13:50:47 GC EI+ Voltage SIR 70SE
407.7818 F:4 Exp:EPCUS2
Sample Text:M23-OUTLET-RBI TLI#42299A File Text:TRIANGLE LABORATORIES,
A2.92E5 i
in
T-H
CM
INC
DBS
60j
40J
20 J
Ol
31:00 32:00 33:00
File:W972830 #1-441 Acq:22-JUL-1997 13:50:47 GC EI+ Voltage SIR 70SE
409.7789 F:4 Exp:EPCUS2
Sample Text:M23-OUTLET-RBI TLI#42299A File Text:TRIANGLE LABORATORIES,
INC . : : DBS
30:53
31:00 32:00
File:W972830 #1-441 Acq:22-JUL-1997 13:50:47 GC EI+ Voltage SIR 70SE
417.8253 F:4 Exp:EPCUS2
Sample Text:M23-OUTLET-RBI TLI#42299A File Text:TRIANGLE LABORATORIES,
100% - - - -
eol
40 J
20l
0
|
33loO
32:05
31:00
INC . : : DBS
32:00
33:00
^7.3E4
L5.5E4
L3.7E4
L1.8E4
LO.OEO
Time
Time
4.3E6
L3.4E6
L2.6E6
L1.7E6
L8.5E5
.O.OEO
Time
-------
File:W972830 #1-441 Acq:22-JUL-1997 13:50:47 GC EI+ Voltage SIR 70SE
441.7428 F:4 Exp:EPCUS2
Sample Text:M23-OUTLET-RBI TLI#42299A File Text:TRIANGLE LABORATORIES,
CD
iH
CM
INC .
DBS : :
33112 33124 33i36 33148 34iOO 34ll2 34J24 34.:36 34148 35!66'35ll2 35124 35i36
File:W972830 #1-441 Acq:22-JUL-1997 13:50:47 GC EI+ Voltage SIR 70SE
443.7399 F:4 Exp:EPCUS2
Sample Text:M23-OUTLET-RBI TLI#42299A File Text:TRIANGLE LABORATORIES, INC.
100%, A2.03E5
801
60 j
40
20.:
0-
DBS::
sslii'ssl^'silie'silis'iiSoo'siSii'silii'iiSse'siUs'ssSoo'ssSii'is
File:W972830 #1-441 Acq:22-JUL-1997 13:50:47 GC EI+ Voltage SIR 70SE j
471.7750 F:4 Exp:EPCUS2 j
Sample Text:M23-OUTLET-RBI TLI#42299A File Text:TRIANGLE LABORATORIES, iINC .
100% 34jl2
sol
601
40
i r i -
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i i i i i i i i
35:36
Ol
i ' I | ' I I I ' | r I I i I | I I I I I" | I I I I I I I I I T i i i i i i i [iiTT'l ] i I i IT1 r T I" I I I I I I" ri I I 1 I I i I -i i i i i i i i
33:12 33:24 33:36 33:48 34:00 34:12 34:24 34:36 34:48 35:00 35:12 35:24 35:36
i
DBS::
O.OEO
Time
.7.7E4
.6.2E4
.4.6E4
.3 . 1E4
.1.5E4
.O.OEO
Time
.4.4E6
.3.5E6
.2.7E6
.1.8E6
.8.9E5
.O.OEO
Time
-------
File:W972830 #1-441 Acq:22-JUL-1997 13:50:47 GC EI+ Voltage SIR 70SE
457.7377 F:4 Exp:EPCUS2
Sample Text:M23-OUTLET-RBl TLI#42299A File Text:TRIANGLE LABORATORIES,
100% A2.53E5
80J
60J
40
20J
CM
INC
DBS
OJ
—i—i—I—r~t—i—r—i—r—i—i i i i—r—i—i—i—r~i—I—i i i—i i i i i—i i i—r—i—i—n—i—i—i i i—i—i—i i i—r~i—i—pi—i—n—r~|—i—n—I—r~]—I T r~T—i—]—i—r—n—i—[—T—r—r-
33:12 33:24 33:36 33:48 34:00 34:12 34:24 34:36 34:48 35:00 35:l£ 35:24 35:36
File:W972830 #1-441 Acq:22-JUL-1997 13:50:47 GC EI+ Voltage SIR 70SE
459.7348 F:4 Exp:EPCUS2
Sample Text:M23-OUTLET-RBl TLI#42299A File Text:TRIANGLE LABORATORIES,
100%
80 j
60J
40 j
20 j
OJ
A2.52E5
INC.:: DBS::
•i—i—i—i—r-1—i—i—i—i—i—i—i—i—i—n—r—i—i—i—i—i—i—r—i—i—i—i—i—i—i—n—i—|—i—i—i—i—i—I—i—n—i—i—i—i—i—i—n—I—i—i—n—r~i—i—i—i—i—r-i—i—i—i i i—I—i—i—i—i—i I i i—i—IT
33:12 33:24 33:36 33:48 34:00 34:12 34:24 34:36 34:48 35:00 35:12 35:24 35:36
.1.1E5
.9. 1E4
.6.8E4
.4.6E4
.2.3E4
.O.OEO
Time
.7 .6.E4
.6.1E4
.4.6E4
.3 . OE4
.1.5E4
.O.OEO
Time
File:W972830 #1-441 Acq:22-JUL-1997 13:50:47 GC EI+ Voltage SIR 70SE
471.7750 F:4 Exp:EPCUS2
Sample Text:M23-OUTLET-RBI TLI#42299A File Text:TRIANGLE LABORATORIES,
100%
80 J
60 J
40 J
20J
0.
34:12
INC.:: DBS::
i r T r r i i i i T T r iTiiiiiiiTiirririiirTTiiiiiiiiiiiii 111 iriii i i t > i • i i • > > i i | I
33:12 33:24 33:36 33:48 34:00 34:12 34:24 34:36 34:48 35:00 35:lS 35:24 35:36
I
.4.4E6
.3.5E6
.2.7E6
.1.8E6
.8.9E5
.O.OEO
Time
-------
CO
•rH
CM
File:W972830 #1-441 Acq:22-JUL-1997 13:50:47 GC EI+ Voltage SIR 70SE
423.7766 F:4 Exp:EPCUS2
Sample Text:M23-OUTLET-RBI TLI#42299A File Text:TRIANGLE LABORATORIES,
ENC. : : DBS
I—i—i—i—i—i—I—i—i—i—i—i—1—i—i—i—i—i—I—i—i—i—i—i—I—i—i—i—i—i—I—i—i—i—i—i—1—i—i—i—i—i—1—i—i—i—i—i—I—i—i—i—i—i—I—i—i i i i—I—i—i—i—i—i—I—i—i—r
30:36 30:48 31:00 31:12 31:24 31:36 31:48 32:00 32:12 32:24 32J36 32:48
File:W972830 #1-441 Acq:22-JUL-1997 13:50:47 GC EI+ Voltage SIR 70SE
425.7737 F:4 Exp:EPCUS2
Sample Text:M23-OUTLET-RBI TLI#42299A File Text:TRIANGLE LABORATORIES, INC.:: DBS:
100* TI . c?q 3U-45
T 1 1 1 f
33:00
,OEO
Time
I—T—T—1—I—I—1—I—I—I—I—I—I—P—I—I—1—I—I—l—I—l—I
30136 30148 3liOO 31:12 31:24 31:36 31:48 32:00 32:12 32:24 32536 32:48
File:W972830 #1-441 Acq:22-JUL-1997 13:50:47 GC EI+ Voltage SIR 70SE ;
435.8169 F:4 Exp:EPCUS2 !
Sample Text:M23-OUTLET-RBI TLI#42299A File Text:TRIANGLE LABORATORIES, INC.:: DBS
100% 31;44
80J
601
40J
20J
T—r—i—i—f~
33:00
0.
30136 30148 31:00 31:12 31:24 31:36 31:48 32iOO 32:12 32i24 32
_5
L4
13
12
Ll
Lo
36 32:48 33:00
,OEO
Time
1E6
1E6
1E6
1E6
OE6
OEO
Time
-------
TLI Project: 42299A
Client Sample: M23-Outlet-FBl
Method 23 TCDD/TCDF Analysis (DB-225)
Analysis File: P973373
Client Project: Iron & Steel-Chicago
Sample Matrix: M23TRAIN Date Received: 07/01/97
TLI ID: 173-61-4ABCE Date Extracted: 07/17/97
Date Analyzed: 07/23/97
Sample Size:
Dry Weight:
GC Column:
1.000
n/a
DB-225
Dilution Factor n/a
Blank File: W972829
Analyst BB
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPC2NF04
PF22206
P973363
n/a
n/a
n/a
Aitefct**, * — "-' '^A^W^^lll^ "'^&*g$
23,7,8-TCDF
>3C,2-2,3,7,8-TCDF
0.006
0.66
20:57 _
32
80.9
40%-130%
0.75
20:56
«C12-1,23,4-TCDD
0.81
19:56 _
Data Reviewer.
08/13/97
Page 1 of 1
ONF.PSR 12.00. LARS £.10.03
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: (M:17 08/13/97
-------
Data Review By:
Initial
sic.
..Date..
Calculated Noise Area: n/a
The Total Area for each peak with an ion abundance ratio outside
ratio limits has been recalculated according to method requirements.
Page No. 1
07/24/97
Compound/
M_2. . . . QC.Log Omit
TCDF
304-306 DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
MK
DC
DC
DC
DC
DC
DC
DC
304-306
13C12-TCDF
316-318 DC
DC
DC
DC
316-318
13C12-TCDD
332-334 DC
DC
Sfliy
NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
2
NL
WL
WL
WH
2
NL
WH
Listing
Matched
. .RT. OK
0:
17:
17:
17:
17:
17:
18:
18:
18:
18:
19:
19:
19:
20:
20:
20:
21:
21:
22:
22:
22:
22:
22:
00
20
28
36
44
50
15
26
43
51
13
19
39
04
28
57
07
45
12
37
39
50
54
0.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
of P973373B.OBt
GC Peaks / Ratio
Ratio Total. Area
/ Ret. Time
Area. Peak. 1. . Area . Peak . 2 . . Rel.RT Compound . Name .. ID.. Flags.
65-0.89
0
3
0
0
1
0
3
0
0
0
0
0
0
0
1
0
0
0
0
0
1
0
0
.95
.89
.25
.75
.04
.96
.25
.45
.41
.19
.40
.55
.58
.57
.39
.66
.86
.36
.26
.79
.08
.20
.61
Peaks
0:
19;
19:
20:
21:
22:
:00
:39
:53
:56
;27
49
0.
RO
0
0
0
1
0
1
0
0
1
0
1
0
3
0
0
3
0
0
0
0
0
0
0
6
.78
.16
.32
.03
.99
.35
.14
.87
.13
.14
.61
.25
.38 1.47
.57
.58
.51 1.40
.93
.21
.11
.43
.21
.39
.25
.89
65-0.89
0
0
0
0
0
0
Peaks
0:
18:
19:
19
20
22
:00
:38
:43
:56
:37
:16
0.
RO
.74
.52
.75
.75 2
.74
.77
2
Above:
.65-0.89
2
0
0
0
0
0
.04
.69
.80 1
.81 1
.82
.82
1
4
9
,139
20
21
,159
.69
.18
.59
.70 915.48
.29 8.60
.31
.99
TCDF / TCDD Follows
0
6
,666
,904
19
2
.83
.49 2.65
.25 742.25
.70 851.89
.00 ~ "" ~8.57
.73
0.787-1.099
0
0
0
0
0
0
0
0
0
0
0
0
2.54 0
0
0
2.11 1
1
1
1
1
1
1
1
.000
.828
.834
.841
.847
.852
.872
.881
.394
.900
.918
.923
.939
.959
.978
.001 2378-TCDF AN
.009
.039
.061
.080
.082
.091
.094
0.952-1.048
0
0
0
1,224.22 1
11.69 1
1
.000
.939
.950
.000 13C12-2378-TCDF ISO
.025
.090
0.898-1.102
0
3.34 0
924.00 1
1,052.81 1
10.43 I
1
.000
.945
.000 13C12-2378-TCDD IS1
.011 13C12-1234-TCDD RSI
.046 "
.129
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 15:50 07/24/97
220
-------
Page No. 2 Listing of P973373B.dbf
07/24/97 Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak. 1. . Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
332-334 4 Peaks 3,596.44
Column Description "Why" Code Description QC Log Desc.
M_Z -Nominal Ion Mass(es) HL-Below Retention Time Window A-Peak Added
..RT. -Retention Time (mm:ss) WH-Above Retention Time Window K-Peak Kept
Rat.l -Ratio of M/M+2 Ions SN-Below Signal to Noise Level D-Peak Deleted
OK -RO=Racio Outside Limits
-------
\TU»>?973373 tl-9H Acq:23-J13L-1997 23t4S>12 SH- Voltayt SIS 70P
303.9016 3003(256,30,-3.0) IXD(5,3,l,0.10\,832.0,0.00\,r,r) SxpiDB225
XXXA1KLX LABS T*x-ttM23-OUTLXT-XBl TLXI42299A
1001
17iOO 18100 19100 20iOO21t0622\00
T±l»tP973373 tl-964 Aoqi23-JOL-1997 23i49il2 XI+ Voltag* SIX 7OP Boitm,221
305.8987 Bsm(256,30,-3.0) tXD(5,3,l,0.10\,884.0,0.00\,r,r) SxptDB22S
TRI1OISLX XJLRS TmrttM23-OUTLXX-Xfl TLH42299A
1QO\ A2.54X4
90.
23100
17tOO 18tOO IS 100 20tOO 21tOO 22tOO
r±l»tP973373 tl-964 Acqt23-JUL-1997 23149:12 SI+ Voltage SIS 70S Bo±M*:35S
315.9419 BSUB(256,30,-3.0) rXD(5,3,l,0.10\,1432.0,0.00\,TrT) XxptDB225
XXIAHCLZ LABS Tezt.sM23-OUTLET-RSI TLIt42299A
100\ A9.15E6
80.
50.
40:
20:
o:
23100
-2.5X6
J.OX6
11.0X6
•.5.0X5
-.0.0X0
17:00 IS', 00 19'tOO 20'tOO 21',00 22»00
r±l»it973373 tl-964 Aoqt23-JUL-1997 33i49tl2 XI+ Voltagw SIS 70P Boiaet485
317.9389 BSUB(256,30,-3.0) tXD(5,3,1,0.10\,1940.0,0.00\,r,r) XxptDB225
XXZABSLX LABS Tmrtiia3-OUTLXI-tBl XLH42299A
23,00
10K
80.
60.
40.
20.
A1.22X7
-3.3X6
J.6X6
J.OX6
^3X6—
.6.5X5
0.0X0
17:00 18,00 19,00 20,00 21,00
Til»,P973373 tl-964 Acqi23-JOL-1997 23t49tl2 XX+ Voltmgm SIX 70P
375.8364 XxptDB225
XtlAHGLX LABS T»*tiM23-OOXLXT-MBl TLIt42299A
100\16,39
22100
23,00
18,48
^.4X4
JL.9X4
J..4X4
J9.6X3
17i33 IStOS
20i31 20t59 21i40 22il3
23,06
.4.8X3
17,00
18,00
19100
20100
21100
22,00
'.0.0X0
23',00 Time
222
-------
319.8965 3303(256, 30, -3.0) PXD(5,3,1,0.19\,492
TXIA1KLS lASS Tmrt!H33-OOTLXT-M31 TLH42299A
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-------
Til»,P973373 tl-964 Acq,23-JVL-1997 23, 49 : 12 XI* Voltage
303.9016 XxptDB225
SIS 70P
XSIAHCLX LABS T*xt,M23 -OUTLET-SSI XLH42299A
I .. ..
ao:
601
401
201
19
iy,j.j
17,08 17,36 18tl5 ISj."
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17,00 18,00 19,00
i .
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39
, Jirt
WWwu
20:00
f±le,P973373 tl-964 Acqi23-JVL-1997 23,49,12 XH- Voltage
315.9419 XrpiDB225
-7.6X3
20,57
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^^wwwu^^l^^
•
'-.6.1X3
.4.5X3
-.3.0X3
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21:00 22:00 2J:00 Time
SIS 70P
TBIAHGLX LABS Text.: M23 -OUTLET-RSI XLIt42299A
10K
aoj
60:
40:
201
17\00 ' 18,00 19\00
20:00
r±le,P973373 tl-964 Aoq,23-JTJL-1997 23,49,12 XI* Voltage
319.8965 XxpiDB225
20,56
i\
-2.5X6
.2.0X6
.1.5X6
.1.0X6
'•.5.0X5
0.0X0
21:00 22:00 23:00 Time
SIS 70P
TS1AJKLX LABS TextsM23-OOTLXT-SBl TLIt42299A
1001
80:
60:
40J
201
oj
19:44
1 1
^^I7:0<-^»18,0^^
17,00 ' ISiOO 19,00
-^rw- ,
i?0:00
r±leiP973373 tl-964 Aoq,23-JVL-1997 23,49,12 XI+ Voltage
331.9368 Xzp,DB225
*-**-^J"^ljL^JuLffA^JU*^^^
* *»^^/wr^-Wi
21:00 22:00 23:00
2.0X4
.1.6X4
-.1.2X4
'-.8.0X3
-.4 . 0X3
0.0X0
Time
5TX 70P
TSIAHGLX LABS Tert,M23-OUTLXT-XBl XLIf42299A
1001
so:
60:
401
20:
19 s 56
-2.425
19:43\
17:00 ' ' ' isioo is.-oo
ul
20l<30
rile,P973373 tl-964 Acq,23-JVL-1997 23,49:12 SI+ Voltage
292.9825 Xxp,DB225
-.1.9X6
'-.1.4X6
.9.6X5
.4.8X5
0.0X0
21:00 22:00 2J.-00 Time
SIS 70P
XXIANGLX LABS T*xtsM23-oaTLXT-XBl TLIt42299A
ion
80:
60:
40:
20:
0'
17,03 17,34 18,32
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20:00
r±le,P973373 tl-964 Acqt23-JUL-1997 23,49,12 XH- Voltage
330.9792 XxptDB225
20,42 21:15 21:54 32*54 ,
1 ii>iAj«-1flirt l"*!"*!"*! ^AxlW^^VAlW^^VVWWIiAVV
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SJ8 70P
TSIAJKLX LABS TfxttM23-OOTLXT-SBl XLIt42299A
80:
60:
40:
20:
OJ
16,4217,06 17t33 17,58 ^ji*j£*^.
-vr^-^-u^
17:00 ia»00 ' 15:00
19,26
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20:00
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21:00 ' ' ' 22:00 ' ' ' 2J:00 Ilji*
224
-------
Re?, tass 292,9825 Peak top
Height 5,39 wits Span 288 pp*
Systa file naie
Data file naie
Resolution
Groipnuiber
loniiatlon lode
Switching
292,9825
383,9616
315,9419
317,9389
319,8965
321,8936
327,8847
336,9792
fl:P973373
J
K
L
R
1
n*
VQLTBGE
389,9761
338,9792
331,9368
375,3384
Chamel I 338,9792 Peaktop
Height 5,16 volts S|)an 208 ppi
00=:
-------
CD
CJ
File:P973373 #1-964 Acq:23-JUL-1997 23:49:12 EH- Voltage SIR 70?
303.9016 Exp:DB225
Sample Text:M23-OUTLET-RBl TLI#42299A File Text:M23-OUTLET-RBl TLI#42299A
100% A1.40E4
80 j
60 J
40J
20J
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19:48 20:00 20:12 20:24 20:36 20:48 21:00 21:12 21:24 21:36 21:48 22:00 22:12
File:P973373 #1-964 Acq:23-JUL-1997 23:49:12 EI+ Voltage SIR 70P
305.8987 Exp:DB225
Sample Text:M23-OUTLET-RBI TLI#42299A File Text:M23-OUTLET-RBl TLI#42299A
100%
80 j
60 J
40 j
20J
OJ
T—i—i—i—r—i—i—r—i—r-i—i—i—i i i i i—i—i—i—i—r—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—|—i—i—r—i—i—i—i—i—i—i—i—r~i—i—i—i—i—|—i—i—i—i—i—I—i—r
19:48 20:00 20:12 20:24 20:36 20:48 21:00 21:12 21:24 21:36 21:48 22:00 22:12
File:P973373 #1-964 Acq:23-JUL-1997 23:49:12 EH- Voltage SIR 70P
315.9419 Exp:DB225
Sample Text:M23-OUTLET-RBI TLI#42299A File Text:M23-OUTLET-RBI TLI#42299A
100% 20;56
80 J
60J
40 J
201
0
19148 20:00 20:12 20:24 20:36 20J48 21:00 21:12 2l!24 21:36 21:48 22lOO 22 i12
.5.6E3
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Time
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Time
A
2.5E6
2.0E6
1.5E6
1.0E6
5.0E5
O.OEO
Time
-------
File:P973373 #1-964 Acq:23-JUL-1997 23:
303.9016 Exp:DB225
49:12 EI+ Voltage SIR 70P
CM
Sample Text :M2 3 -OUTLET -RBl TLI#42299A File Text :M2 3 -OUTLET- RBl TLI#42299A
100%
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40J
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A 20:04 on-PR 20
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: O.OEO
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48 21:00 21:12 21:24 21:36 21 48 22:00 22:12 Time
File:P973373 #1-964 Acq:23-JUL-1997 23:49:12 EI+ Voltage SIR 70P
305.8987 Exp:DB225
Sample Text :M2 3 -OUTLET-RBI TLI#42299A File Text :M2 3 -OUTLET- RBl TLI#42299A
100%
80 j
60 j
"
40 j
20 j
0:
19:53
1
20
VA /A^ 20-15 20:29 A 1
19:48 20:00 20:12 20124 20i36 20 i
20:57
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L6.4E3
L4.8E3
L3.2E3
I.1.6E3
: O.OEO
48 21:00 21:12 21:24 21:36 21:48 22:00 22:12 Time
File:P973373 #1-964 Acq:23-JUL-1997 23:49:12 EI+ Voltage SIR 70P
315.9419 Exp:DB225
Sample Text :M2 3 -OUTLET-RBI TLI#42299A File Text :M23 -OUTLET-RBI TLI#42299A
100%
80J
60J
40 J
20J
0:
19:48 20:00 20:12 20 24 20:36 20:
20:56 2.5E6
A
/ V
i
L2.0E6
L1.5E6
L1.0E6
L5.0E5
: O.OEO
1 i i — i — r — r • p r T r~ r T"| i — i — r~r — i — i i rT""l i — r~i — i — r~i — i — i — r — i — i — i — i — i — i — i — r — i — i — i — i — i — i — i *
48 21:00 21:12 21:24 21:36 21:48 22:00 22:12 Time
OJ
-------
TLl Project: 42299A
Client Sample: TLI LCS
Method 23 PCDD/PCDF Analysis (a)
Analysis File: W972825
Client Project:
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
Iron & Steel-Chicago
XAD Date Received:
TLI LCS Date Extracted:
Date Analyzed:
1.000
n/a
DB-5
Dilution Factor:
Blank File:
Analyst:
/ /
07/17/97
07/22/97
n/a
W972829
MM
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPX23704
WF54307
W972811
n/a
n/a
n/a
Analytes
2,3,7,8-TCDD
1,2,3,7,8-PeCDD
1,2,3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
1,2,3,4,6,7,8-HpCDD
1,2,3,4,6,7,8,9-OCDD
2,3,7,8-TCDF
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
1,2,3,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
1,2,3,4,6,7,8,9-OCDF
:: internal Slawdaixfei
>3C12-2,3,7,8-TCDF
13C,2-l,2,3,7,8-PeCDF
13C,2-l,2,3,7,8-PeCDD
13CP-l,2,3,6,7,8-HxCDF
13C12-l,2,3,6,7,8-HxCDD
13C,2-l,2,3,4,6,7,8-HpCDF
13C,2-l,2,3,4,6,7,8-HpCDD .
13C12-1,2,3,4,6,7,8,9-OCDD
'/ijwlrt; OWi
% ^ ff -mar
0.39
1.8
2.0
1.9
1.5
1.9
4.0
0.36
1.9
1.7
2.1
2.0
2.1
22
1.9
1.6
3.6
!" i
2.8
.. .... .97
2.5
2.5
2.4
3.8
2.5
2.4
3.5
-v Bt a«»e
•Jfe HodWWy *K* UKitiI»
69.2 40%-130%
-------
TLI Project: 42299A
Client Sample: TLI LCS
Method 23 PCDD/PCDF Analysis (a)
Analysis File: W972825
Alt«^« Standards (Type A}
QCUmits
13C12-l,2,3,7,8,9-HxCDF
13C12-2,3,4,6,7,8-HxCDF
3.0
2.7
74.1
68.0
40%-130%
40%-130%
0.54
0.51
29:22
28:38
Recovery Stawfafcfs
Flags
13Ci2-l,2,3,4-TCDD
13CI2-l,2,3,7,8,9-HxCDD
0.82
1.21
20:28
29:09
Data Reviewer
07/22/97
Page 2 of2
X237J>SR rZOO, LARS 6.10.03
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 20:34 07/22/97
229
-------
Initial
. .Date. .
Data Review By:
NJ Cxi frf
Calculated Noise Area: n/a
The Total Area for each peak with an ion abundance ratio outside
ratio limits has been recalculated according to method requirements.
Page No. 1
07/22/97
Compound/
M_Z. . . . QC.Log Omit Why
TCDF
304-306
304-306
13C12-TCDF
316-318
316-318
TCDD
320-322
320-322
13C12-TCDD
332-334
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
SN
SN
SN
1
NL
WL
WL
WL
SN
SN
NH
2
NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
1
NL
WL
WL
Listing
Matched
. . RT . OK
0
19
19
19
20
:00
:06
:23
:51
:36
0,
RO
RO
RO
RO
of W972825B.dbf
GC Peaks / Ratio / Ret. Time
Ratio Total. Area. .. Area . Peak . 1 .. Area . Peak . 2 . . Rel . RT Compound . Name .. ID.. Flags
.65-0.89
1
1
1
0
1
.12
.60
.11
.72
.08
Peak
0
16
16
18
19
19
20
20
21
:00
:50
:58
:37
-.20
:50
:20
:43
:49
0.
RO
RO
RO
20
19
43
1,442
38
1,442
.34
.28
.24
.00 603.61
.25
.00
65-0.89
0
1
0
0
1
0
0
0
0
.86
.90
.20
.76
.02
,75
.69
.76
.84
Peaks
ftW*
0
17
17
17
18
18
18
19
19
20
20
20
21
21
21
:00
:35
:42
:53
:22
:29
:44
:28
:52
:01
:12
:42
:34
:46
:55
0.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
65-0.89
0
2
0
0
1
0
1
0
1
3
3
0
0
0
0
.65
.57
.49
.99
.67
.38
.02
.39
.46
.54
.50
.79
.96
.28
.19
Peak
0
17
17
:00
:39
:54
0.
RO
RO
RO
18
7
12
85
52
12,375
209
12
49
.34
.27
.64
.01
.80
.98 5,317.11
.82 85.50
.18
.22
0.820-1.109
0.
,000
0.963
0.
.977
838.39 1.001 2378-TCDF AN
1.039
0.950-1.050
0.
0.
0.
0.
0.
7,058.87 1.
124.32 1.
1.
1.
000
849
855
939
975
000 13C12-2378-TCDF ISO
025
045
100
12,585.80
yvfe* TCDF / TCDD Follows ~
8
5
6
6
7
8
6
4
16
3
4
1,061
13
6
5
1,061
.31
.29
.53
.78
.33
.52
.44
.83
.62
.61
.99
.14 467.30
.17
.11
.26
.14
65-0.89
1
2
3
.87
.22
.52
20
11
6
.57
.75
.04
0.850-1.064
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
593.84 1.
1.
1.
1.
0.903-
0.
0.
0.
000
850
856
865
888
894
906
941
961
968 •
977
001 2378-TCDD AN
043
052
060
1.097
000
853
865
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 20:35 07/22/97
230
-------
Page No. 2
07/22/97
Compound/
M_2.... QC.Log Omit Why
Listing of W972825B.dbf
Hatched GC Peaks / Ratio / Ret. Time
.RT. OK Ratio Total.Area... Area.Peak.1. . Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
DC
DC
DC
DC
DC
332-334
PeCDF
340-342 DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
340-342
13C12-PeCDF
.352-354 DC
DC
DC
DC
DC
DC
DC
DC
DC
352-354
WL
WL
SN
SN
SN
2
NL
WL
WL
WL
WL
WL
WL
WL
WL
WL
WL
WL
SN
SN
SN
SN
SN
SN
SN
2
NL
SN
SN
SN
SN
SN
SN
SN
SN
2
18:
18:
20:
20:
21:
21:
21:
:02
:07
:28
41
04
43
:53
RO
RO
RO
RO
RO
3
1
0
0
0
1
1
.23
.82
.82
.82
.98
.72
.56
Peaks
RU.
0:
16:
17:
17:
17:
18:
18:
18:
19:
20:
20:
20:
22:
22:
23:
23:
24:
24:
25:
26:
26:
:00
ia
:15
:21
:32
:00
;10
:40
:10
:11
:18
45
:08
:18
:11
:23
;18
:38
:05
:05
28
1.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
32-1.78
0
0
1
0
0
0
3
1
1
1
4
0
0
0
1
2
1
1
1
0
1
.99
.44
.22
.71
.63
.13
.25
.97
.22
.36
.41
.63
.98
.35
.47
.32
.58
.31
.56
.78
.26
Peaks
0:
21:
21:
23:
23
23:
24:
24:
24
25:
26
:00
:03
:35
:18
:33
:55
:17
:37
:49
:03
:05
1.
RO
RO
RO
RO
RO
RO
RO
RO
32
0
1
3
0
0
1
1
3
3
1
2
-1.78
.93
.60
.82
.96
.76
.20
.49
.67
.33
.53
.15
Peaks
Ahni
8
12
12,691
8,853
140
19
24
.62
.23
.54 5,713.23
.98 3,995.08
.15
.42
.32
0
0
6,978.31 0
4,858.90 1
1
1
1
.872
.876
.990 13C12-1234-TCDD
.000 13C12-2378-TCDD
.019
.050
.058
RSI
I SI
21,545.52
8.92
9
6
5
8
1
9
9
11
10
4
9
16
7
13
23
4.434
71
3,890
16
18
8,325
.43
.71
.12
.92
.97
.97
.87
.34
.48
.82
.48
.17
.62
.76
.36
.90 2.718.37
.47
.41 2,371.73
.29
.11
.31
0.904-1.095
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
1,716.53 1
1
1,518.68 1
1
1
.000
.671
.710
.714
.722
.741
.748
.769
.789
.831
.836
.854
.911
.918
.955
.963
.001 12378-PeCDF
.014
.033 23478-PeCDF
.074
.090
AN
AN
0.835-1.165
5
16
4
20
5
51
8,182
30
22
92
20
8,274
i» • p«x-n
•00 __
.58
.18
.47
.39
.28
.01 4.895.00
.29
.90
.76 56.16
.35
.77
p / p«rnn p<*ii«u9 .-
0
0
0
0
0
0
3,287.01 1
1
1
36.60 1
1
.000
.867
.889
.960 '
.970
.985
.000 13C12-P6CDF 123
.014
.022
.032 13C12-P6CDF 234
.074
IS2
SUR2
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 20:35 07/22/97
231
-------
Page No. 3
07/22/97
Compound/
M_2. . . . QC.Log Omit
PeCDD
356-358 DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
356-358
13C12-PeCDD
368-370 DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
Why
NL
WL
WL
WL
WL
WL
WL
WL
WL
WL
WL
WL
WL
ML
WL
WL
WL
WL
WL
WL
WL
WL
WL
SN
SN
SN
SN
SN
SN
WH
WH
WH
1
NL
WL
WL
WL
WL
WL
WL
WL
WL
WL
WL
WL
WL
WL
SN
Listing
Matched
. . RT . OK
0:
16:
16:
17:
17:
18:
18:
19:
19:
19:
19:
19:
20:
20:
21:
21:
21:
21:
22:
22:
22:
22:
22:
24:
24:
00
12
23
15
52
06
58
03
18
30
42
49
29
43
03
25
33
45
03
21
31
48
58
04
16
24:28
24:
24:
25:
25:
26:
26:
26:
33
49
27
44
15
24
33
1.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
of W972825B.dbf
GC Peaks / Ratio
Ratio Total. Area
.32
0
2
1
2
3
0
2
1
3
0
3
1
0
1
2
1
1
2
1
0
0
0
5
2
1
2
0
0
1
1
1
0
1
-1.78
.99
.49
.11
.26
.62
.60
.98
.08
.43
.21
.20
.43
.95
.94
.02
.28
.45
.34
.22
.30
.88
.38
.81
.64
.32
.72
.67
.77
.70
.91
.19
.72
.36
Peak
0:
17:
17:
18:
18:
18:
19:
19:
19:
19:
20:
20:
20:
21:
21:
00
10
27
09
49
54.
11
21
51
59
06
19
28
11
57
1.
RO
RO
RO
RO
/ Ret. Time
. .. Area. Peak. 1. . Area. Peak. 2. . Rel.RT Compound . Name .. ID.. Flags
0.919-1.027
4
10
12
12
4
4
8
5
9
3
5
.56
.91
.67
.47
.82
.69
.39
.96
.56
.32
.41
16.79
6
4
9
6
7
7
8
5
10
6
5
16
27
6
10
12
2,660
14
9
6
4
2,660
.51
.49
.49
.58
.16
.37
.03
.20
.23
.12
.61
.70
.85
.89
.30
.90
.50 1,676.29
.97
.34
.51
.03
.50
32-1.78
1
0
1
1
4
.15
.37
.16
.50
.96
RO 2 . 67
RO
RO
RO
RO
RO
RO
RO
RO
3
1
1
0
3
1
2
0
5
.03
.31
.68
.20
.17
.01
.36
.52
.20
4
10
3
12
7
.43
.59
.75
.91
.29
4.59
9
3
21
4
3
10
9
3
2
.64
.57
.48
.57
.39
.46
.77
.90
.50
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
984.21 1.
1.
1.
1.
1.
0.843-
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
000
637
644
678
702
712
746
749
759
767
775
779
805
815
828
842
847
855
867
879
385
896
903
946
954
962
965
976
001 12378-PeCDD AN
012
032
038
044
1-157
000
675
686
714 '
740
743
754
761
780
786
790
799
805
833
863
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 20:35 07/22/97
232
-------
Page No. 4
07/22/97
Compound/
M_Z QC.Log Omit Why
Listing of W972825B.dbf
Hatched GC Peaks / Ratio / Ret. Time
.RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel. RT Compound.Name.. ID.. Flags.
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
368-370
HxCDF
374-376 DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
374-376
13C12-HXCDF
384-386 DC
DC
DC
DC
DC
DC
DC
DC
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
2
NL
SN
SN
SN
SN
SN
SN
SN
WH
WH
WH
WH
WH
WH
4
NL
SN
SN
SN
SN
SN
SN
SN
22
22
22
22
23
23
24
24
24
25
25
25
26
26
26
:17
:23
:38
:54
:28
:53
:02
:19
:32
:26
:35
:44
:19
:25
:35
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
2.
2.
0.
1.
2.
0.
2.
2.
0.
1.
1.
2.
1.
1.
0.
61
32
61
44
60
65
39
03
94
60
38
00
23
75
46
Peaks
0
27
27
27
28
28
28
28
28
29
29
29
29
29
29
29
30
30
:00
:00
:28
-.36
:01
:08
:39
:47
:59
:10
:22
:36
:43
:50
:53
:58
:05
:12
1.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
05-
2.
0.
1.
0.
1.
1.
1.
2.
2.
1.
1.
1.
0.
0.
0.
2.
1.
0.
1.43
07
65
12
76
29
27
25
74
13
55
28
41
73
85
55
05
18
17
Peaks
0
28
28
28
28
28
29
29
29
29
30
:00
:07
:24
:32
-.38
:46
:05
:22
:39
:53
:03
0.
RO
RO
RO
RO
RO
RO
RO
RO
8
9
10
6
10
5
8
20
8
4,327
442
22
11
11
5
4,770
.72
.72
.50
.78
.94
.05
.24
.04
.04
.94 2,660.46
.18 256.20
.80
.32
.17
.12
.12
0
0
0
0
0
0
0
0
0
1,667.48 1
185.98 1
1
1
1
1
.876
.880
.890
.900
.923
.939
.945
.956
.965
.000 13C12-PeCDD 123
.006
.012
.035
.039
.045
IS3
11
10
8
4
3,417
4,564
3,311
63
8
18
3,042
30
9
10
3
4
11
1
14,335
.13
.39
.50
.25
.21 1,925.35
.82 2,554.78
.62 1,841.71
.93
.96
.91
.28 1,707.82
.56
.90
.06
.92
.88
.91
.90
.93
43-0.59
0.
0.
1.
1.
0.
0.
1.
0.
0.
0.
0.
37
51
13
64
51
97
47
54
68
81
22
16
5,964
14
6
5,443
122
11
5,093
33
19
11
.55
.54 2,011.71
.44
.54
.30 1,850.22
.78
.58
.97 1,780.09
.07
.71
.64
0.955-1.053
0
0
0
0
1,491.86 0
2,010.04 1
1,469.91 1
1
1
1
1,334.46 1
1
1
1
1
1
1
1
.000
.960
.977
.982
.996 123478-HxCDF
.001 123678-HxCDF
.019 234678-HxCDF
.024
.031
.037
.044 123789-HXCDF
.053
.057
.061
.063
.066
.070
.074
AN
AN
AN
AN
0.858-1.142
0
3,952.83 1
1
1
• 3,593.08 1
1
1
3,313.88 1
1
1
1
.000
.000 13C12-HXCDF 678
.010
.015
.018 13C12-HXCDF 234
.023
.034
.044 13C12-HXCDF 789
.055
.063
.069
IS4
ALT2
ALT1
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 20:35 07/22/97
233
-------
Page No.
07/22/97
Listing of W972825B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_2.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak. 1. . Area.Peak. 2. . Rel.RT Compound.Name.. ID.. Flags.
384-386
HxCDD
390-392
390-392
13C12 -HxCDD
402-404
402-404
HpCDF
408-410
" "
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
SN
3
NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
WH
WH
WH
WH
WH
3
NL
WL
SN
SN
SN
SN
SN
SN
SN
SN
2
NL
WL
SN
SN
SN
WH
30:16
Peaks
0:00
27:24
27:56
28:03
28:09
28:15
28:20
28:28
28:31
28:39
28:48
28:52
29:10
29:22
29:31
29:36
29:56
30:09
Peaks
0:00
27:31
28:14
28:26
28:39
28:51
29:09
29:29
29:33
29:38
29:45
29:49
Peaks
0:00
30:38
30:53
31:07
31:33
31:53
32:05
32:25
RO
0
.21
3
.32
1
.076
16,501.81
KWAvn*.. t-**fS*r\v i uuf*T\n »*»1 1 *«.».
i
RO
RO
RO
RO
RO
.05-1.43
0,
0.
.68
.16
12.08
0.88
0.82
1.35
RO
RO
RO
RO
0.
1.
1.
2.
.93
.93
.66
,52
1.25
1.22
1.28
RO
0.95
1.33
RO
RO
RO
1.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
0.
RO
RO
RO
RO
7.
2.
5.
63
02
47
s . njv**ur i ivt\vW c W^AWMO
5
1
1
8
.22
.73
.34
.00
11.90
7.73
7
.14
2.71
3.63
7.64
3,031.23 1,682.63
3,666.73 2,018.35
2,584.71 1,448.98
42.18
13.
3.
7.
2.
9,282.
.55
.14
.95
.93
67
.05-1.43
1.
0.
0.
4.
1.
1.
1.
0.
1.
0.
0.
5.
57
58
64
28
02
20
21
60
90
30
98
61
8.
8.
20.
3.
16.
6,852.
6,630.
20.
22.
7.
16.
5.
13,482.
74
38
49
47
01
17 3,735.80
57 3,636.25
99
98
26
89
31
74
0.949
0
0
0
0
0
0
0
0
0
0
1,348.60 0
1,648.38 1
1,135.73 1
1
1
1
1
1
-1.015
.000
.950
.968
.972
.976
.979
.982
.987
.988
.993
.998 123478-HxCDD
.001 123678-HXCDD
.011 123789-HxCDD
.018
.023
.026
.038
.045
AN
AN
AN
0.965-1.035
0
0
0
0
0
3,116.37 1
2,994.32 1
1
1
1
1
1
.000
.954
.979
.986
.993
.000 13C12-HXCDD 678
.010 13C12-HXCDD 789
.022
.024
.027
.031
.034
.
IS5
RS2
• WvfT^n / Unf*T\tt T?rtl 1 s*t*re
88-1.20
0.
1.
1.
0.
0.
3.
1.
0.
78
00
11
88
14
21
07
67
12.
5.
2,557.
19.
3.
5.
1,528.
12.
97
93
93 1,347.44
94
90
67
10 790.53
36
0.995-1.045
0.000
0.992
1,210.49 1.001 1234678-HpCDF
AN
1.008
1.022
1.033
737.57 1.039 1234789-HpCDF
AN
1.050
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 20:35 07/22/97
234
-------
Page No. 6
07/22/97
Compound/
M_2.... QC.Log Cmit Why
Listing of W972825B.dbf
Matched GC Peaks / Ratio / Ret. Time
.RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak. 2.. Rel.RT Compound.Name.. ID.. Flags.
DC
DC
DC
DC
DC
DC
DC
408-410
13C12-HpCDF
418-420 DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
418-420
HpCDD
424-426 DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
424-426
13C12-HpCDD
436-438 DC
DC
.. - .
DC
WH
WH
WH
WH
WH
WH
WH
2
NL
SN
SN
SN
SN
SN
SN
SN
SN
WH
WH
WH
1
NL
SN
SN
WH
WH
WH
WH
WH
WH
WH
WH
WH
WH
WH
WH
WH
1
NL
SN
SN
32:
32:
33:
34:
34:
35:
35:
31
38
34
10
19
22
29
RO
RO
RO
RO
RO
2
0
0
0
1
0
0
.52
.43
.91
.87
.34
.90
.66
Peaks
0:
30:
31:
32:
32:
32:
33:
33:
34:
34:
35:
35:
35:
00
52
51
05
22
39
08
16
26
44
11
27
41
0
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
6.
12.
17.
26.
169.
16.
9.
4,086.
30
28
89
89
65
49
49
03
.37-0.51
1
0
1
0
1
0
0
1
1
0
1
0
1
.40
.42
.14
.48
.25
.76
.92
.49
.25
.33
.62
.97
.53
Peak
0:
31:
31:
31:
32:
32:
32:
33:
33:
33:
33:
34:
34:
34:
35:
35:
35:
00
18
32
44
17
22
53
06
22
33
45
12
40
49
17
51
54
0
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
4.
3,592.
9.
6.
5.
6.
6.
4.
2.
4.
5.
3.
9.
3,592.
19
83 1,054.55
09
43
10
03
47
39
49
32
04
84
39
83
: HpCDF / HpCDD Follows -
.88-1.20
0
0
0
0
3
0
0
1
0
6
0
1
0
3
0
0
0
.78
.65
.65
.98
.36
.38
.51
.51
.22
.48
.32
.35
.33
.57
.27
.49
.45
Peak
0:
31:
31:
32:
00
30
44
04
0
RO
RO
RO
5.
18.
4.
1,471.
6.
6.
6.
8.
4.
2.
4.
107.
4.
6.
3.
8.
2.
1,471.
08
07
83
09 727.67
36
89
39
12
02
65
59
18
20
02
20
06
24
09
.88-1.20
1
0
1
1
.36
.66
.00
.45
10.
8.
2,868.
9.
04
43
18 1,437.14
12
1.
053
1.057
1.
1.
1.
1.
1.
087
107
112
146
150
0.935-1.130
0.
2,538.28 1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
000
000 13C12-HpCDF 678
032
039 13C12-HpCDF 789
049
058
073
078
116
125
140
148
156
IS6
SOR5
0.976-1.006
0.
0.
0.
743.42 1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
000
936
994
000 1234678-HpCDD
017
020
036
043
051
057
064
078
092
097
112
130
131
AN
0.968-1.032
0.
0.
1,431.04 1.
1.
000
993
000 13C12 -HpCDD 678
Oil
IS7
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitals Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 20:35 07/22/97
235
-------
Page No. 7 Listing of W972825B.dbf
07/22/97 Matched GC Peaks / Ratio / Ret. Time
Compound/
M_2.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak. 2. . Rel.RT Compound.Name.. ID.. Flags.
436-438
OCDF
442-444
442-444
OCDD
458-460
458-460
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
SN
SN
WH
WH
WH
WH
WH
1
NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
1
NL
1
32
32
33
33
33
34
34
:09
:19
:33
:48
:55
:13
:31
RO
RO
RO
0.
0.
1.
2.
0.
1.
1.
93
90
13
51
27
02
28
Peak
0
30
31
31
31
31
31
32
32
32
32
32
33
33
33
33
34
34
34
34
35
35
35
:00
:56
:04
:18
:22
:45
:52
:00
:21
:35
:40
:52
:08
:13
:25
:41
:18
:33
:47
:59
:01
:33
:44
0
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
A K A1 »A
23
18
10
10
9
220
19
2,868
.71
.01
.76
.67
.02
.25
.28
.18
n /
.76-1.02
1.
0.
2.
2.
4.
0.
0.
1.
0.
1.
0.
0.
2.
1.
1.
0.
0.
0.
1.
0.
1.
1.
2.
64
30
62
69
39
67
25
16
74
41
36
36
10
10
04
43
93
50
02
77
50
55
48
Peak
0
34
:00
:12
0.
RO
76-
1.
0.
1.02
15
85
Peak
5
7
4
5
2
12
3
7
15
3
5
9
6
3
16
9
1,775
28
13
9
14
8
4
1,775
4
1,535
1,535
.08
.11
.73
.95
.72
.93
.89
.14
.86
.53
.34
.83
.26
.10
.29
.09
.29
.63
.12
.06
.12
.64
.63
.29
.23
.64
.64
13C12-OCDD 0.76-1.02
470-472
470-472
DC
DC
DC
NL
WH
WH
1
0
34
34
34
:00
:11
:29
:37
RO
RO
1.
0.
1.
1.
08
91
00
12
Peak
4
2,772
49
15
2,772
.76
.17
.62
.10
.17
1.
1.
1.
1.
1.
1.
1.
013
018
057
065
069
078
088
0.883-1.117
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
854.11 921.18 1.
1.
1.
1.
1.
1.
1.
0.883-
0.
707.06 828.58 1.
000
905
909
916
918
929
932
936
946
953
956
961
969
972
978
985
003 OCDF AN
Oil
018
023
024
040
045
1.117
000
000 OCDD AN
0.995-1.004
0.
1.319.21 1.452.96 1.
1.
1.
000
000 13C12-OCDD IS8
009
013
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713 Printed: 20:36 07/22/97
Phone: (919) 544-5729 • Fax: (919) 544-5491
-------
Page No. 8
07/22/97
Listing of W972823B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
H_Z QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak. 1.. Area.Peak.2. . Rel.BT Coopound.Kane.. ID.. Flags.
Column Description.
"Why" Code Description QC Log Desc.
M_Z -Nominal Ion Mass(as)
..RT. -Retention Time (om:ss)
Rat.l -Ratio of M/M+2 Ions
OK -RO=Ratio Outside Limits
Rel.RT-Relative Retention Time
*** End of Report ***
ML-Below Retention Time Window
WH-Above Retention Time Window
SN-Below Signal to Noise Level
-------
nj.aiH972825 #1-798 Acq:22-JUL-1997 09:53:55 GC XI+ Voltage SIX 70SX Boi*»:6460
303.9016 F:2
BSUB(256,30,-3.0) PKD(9,
5,5r0.10\,25B40.0,1.00\rr,T) XxptXfCOS2
TXIANGLE LASS XaxtsTLI LCS TU #42299 A
100
80
60.
40.
20.
0.
!
A6.04X6
I
C1.4X6
: A3. 71X5 1 \
17:00
18:00
HIM" i ii r~ i fM irr^ — nil
15:00
20:00
.1.1X6
.8.3X5
.5.5X5
-3.7X5
21:00 22:00 ' Hmm
*ile:W9 72825 #1-798 Acqs22-JUL-1997 09:53:55 GC XI+ Voltage SIX 70BX Boi*u:5745
305.8987 t:2
BSU3(256,30,-3.0) PXD(9,
5,5,0.10\,229SO.O,1.00\,T,T) XxptXTCUS2
XXIASGLX LABS T*xt:TLI LCS TLH42299A
1001
80.
60.
40.
20.
rila:H972a25
315.9419 T:2
17:00
•_ .
18:00
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15:00
A3. 38X6
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-1.5X6
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21:00 ' ' ' '22:00 ' T±ma
#1-798 Acq:22-JVL-1997 05:55:55 GC XI+ Voltage SIX 70SX SoiM»:4245
BSUB(256,30,-3.0) PKD(9,5,5,0 .10\,16980 . 0,1
TXIASGLS LABS Tajct:TLI
1003
aol
601
401
20:
ol
.00\,T,T) XxptXTCtrS2
LCS XLH42299A
AS. 32X7
n
17:00
rile :V9 72825
#1-798 Ac ^ r
30 t 00 ' ' '
-1.3X7
L5.5S5
L7.1W
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21:00 22:00 Xi*e
•.22-JUL-1997 09:53:55 GC XI+ Voltage 512 70SX Xoi*a:4924
317.9389 T:2 BSOB(256,30,-3.0) PKD(9, 5,5,0. 10\, 19696.0,1
TSIAHGLE LABS
1001
80:
60:
40:
20:
ol
Teit:TLI
17:00
Tila:W972825 #1-798 Acq
,oo\,r,T) sxptspcuss
LCS TLH42299A
18:00
15:00
1X7
.
20:00
-1.5*7
J..3X7
.9.2X6
.6.2X6
.3.1X6
O.OfO
21:00 ' ' ' 22: 00' ' Time
22-JVL-1997 09t53i55 GC XI+ Voltage SIX 70SX
330.9792 T:2 XxpiEPCUS2
TSIANSL£ LABS
1001
80:
60:
40:
20:
ol
16:38
TaftiTLI LCS TLI#42299A
17:07
17:50 18:3018:53 19s32i9j£* 20>33 20:52 31 1 33 31 143 33 1 04^^.6. 6X7
17,00
18:00
15:00
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O.OIO
31tOO — - 22 1 00 HM»
Jlle :W9 72825 #1-798 Acq:23-JOL-1997 09:53:55 GC XH- Voltage SIX 70S!
375.8364 P:2 XrptXPCUS2
TXIANGLX LABS
1001
80:
•
60:
40:
20:
oj.
16
1 15.-J5
^JUvyA^
TaftsTLI
LCS XLH42399A
55 17:34 15:10 19t40
^MJM
17:00
1 i Ifl
1 18:11
4wA(ALM"
18:00
1
... 18:57J
I 1
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15:00
20:2J
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20:00
-7.0X4
22:04
21:J5 I -
.5.6X4
.4.2X4
.2.8X4
J..4X4
a.oro
21:00 22:00 Time
-------
rila:tf972825 tl-798 Acq:22-JUL-1997 09 : 53 1 55 GC SI+ Volt*?*
SIX 70SX Koim*il639
319.3965 r:2 BSOB(256,30, -3.0) PKD(7,S,3,0.10\,6556.0,1.00\,T,T) Xzp*XPCUS2
TRIANGLE LABS TextsTLI LCS TLH42299A
1001
80.
60.
40.
20.
i
- ^^
18:00 ' 19:00 20:00
fll»:m72825 tl-798 Acq:22-JUL-1997 09:53*55 GC XI + Voltmym
\4 . 67X6
l\ ...
-1.1X6
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'21:00 3.2:00' ' zia*
SIX 70SX Boif 0*2515
321.8936 T:2 BSU3(256, 30, -3.0) PXD(7rS,3,0.10\r10060.0,1.00*,T,T) Xrp:XTCUS2
TRIANGLE LABS Tait:TLI LCS TLH42299A
1001
80.
60.
401
201
A3. 94X6
n
A
' 18:00 15:00 20:00
\
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-1.4X6
.1. 1X6
.8.3X5
.5.5X5
.2.8X5
2l'iOO 22:00' ' Hm»
rile:MS72825 41-798 Acq:22-JUZ-1997 09:53:55 GC XH- Voltigm SIX 708X XOif»:10863
331.9368 T:2 BSVB(256,30,-3.0) PKD(7, 5,3, 0.10\,43452. 0,1.00*
TRIANGLE LABS Taxt.-IXJ LCS TLH42299A
1001
801
601
401
201
01
AS '1
A
1 V
' ISiOo' ' 15:00 20:00
,r,T) Xxp:EPCUS2
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4.00X7
I
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-1.3X7
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'21:00 22:00' ' Xlm*
r±le:W972825 fl-798 Acq: 22-JUL-1997 09:53:55 GC KH- Voltagm SIX 70SX No±M9:5812
333.9338 T:2 BSOB(256,30,-3.0) PXV(7, 5,3,0. 101,23248. 0,1.00\,r,T) Xlp:SPCUS2
TRIANGLE LABS Taxt:TLI LCS TZIt42299A
1001
801
601
401
201
0:
A6 :0
A
/ V
'l8:00 15.- 00 20:00
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4.86X7
A
-
/ V
-1.7X7
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• 0.0 fO
' 31:00 ' ' • '22*00' ' XfM
r±le:tf972825 tl-798 Acq:22-JUL-1997 09*53*55 GC XI* Voltage SIX 70SX Noi**:1663
327.8847 1:2 BSUB(256,30,-3.0) PXD(7,5,3, 0.10%, 6652. 0,1. 00\,r,T) XxptXfCUS2
TRIANGLE LABS TsftfTLI LCS TLIt42299A
1001
801
601
401
201
A1.45E6
_ l^^^
'l8iOO 19\00' ' ' ' '20*00'
.3.6X5
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'-.2.2X5
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21*00 22*00 - ££*•
r±la:H972825 tl-798 Acq:22-JUL-1997 09:53*55 GC XH- Volt*y» SIX 70SX
330.9792 T:2 XxptZPCOS2
TRIANGLE LABS Tert:TLI LCS TLH42299A
1001
801
601
401
201
01
-J&£2-~*^-J&2!n~J^^
' 10:00' 15. -00 ' 30100'
20: 52 21*23 21*43 22*04^^,
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J..3I7
0.0X9
'21:00 22:00 ' UM
-------
riletU972825 #1-798 Acq:22-JUL-1997 05:53:55 GC XI+ Voltage SIX 70SX RoJLfe:2711
339.8597 7:2 BSOB(256,30,-3.0) PXD(7,S,3,0.10\rlQ844.0,1.00\,r,T) Xxp:XPCUS2
TRIANGLE LABS TextsTLI LCS TLI942299A
1001
80:
50:
40:
20:
OJ
A3. 73X7
A3. 37X7
' 17160' ' 'ia.-OO 15:00 20:00 21:00 22:00 23:00 24:00 25:00 25:00
Tiletlf972825 #1-798 Acq:22-JUL-1997 05:53:55 GC XH- Voltage SIX 70SX Soiaet2752
341.8567 F:2 BSUB(256,30,-3.0) PXD(7,5,3,0.10%, 11008.0,1.00\,f,T) XxptXPCOSS
TRIANGLE LABS Text:TLI LCS TLH42299A
1001
80:
so:
40:
20:
o:
A1.73X7
A1.52X7
17:00 18:00 15:00 20:00 21:00 22:00 23:00 24:00 25:00 25:00
r±le:H972825 #1-798 Acq:22-JUL-1997 05:53:55 GC XH- Voltage SIX 70SX Boise: 1520
351.9000 Ti2 BSUB(2S6,30,-3.0) PXD(7,5,3,0.101,6080.0,1.00\,T,T) Erp:KPCUS2
TRIANGLE LABS TextsTLI LCS TLI#42299A
1004 A4.90X7
60.
40:
20:
OJ,
17:00 18:00 15:00 20:00 21:00 22:00 23:00 24:00 25:00
r±J.e:ff972825 #1-798 Acq:22-JVL-1997 09:53:55 GC SI+ Voltage SIX 708X BoiMe:1628
353.8970 Ts2 BSVB(256,30f-3.0) PKD(7,5,3,0.10%,5512.0,1.QO\,r,T) XrptXPCUS2
TStlANGLE LABS Tart.-CTJ LCS TLH42299A
1004 A3.29X7
80:
so:
40:
20:
26tOO
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17:00 18:00 15:00 20:00 21:00 22:00 23:00
Mle:W572S25 #1-798 Acq:22-JVL-1997 05:53:55 GC XH- Voltage SIX 70SX
330.5752 Ti2 EzptEPCUS2
TRIANGLE LABS Text:TLI LCS TLI#42299A
1001
i^vw^IIi^Ed''7" ir-4 30s5a'
24:00
25>00
25>00
ao:
50:
40:
20:
24:45
^jfe^:
17:00 18:00 15:00 20:00 21:00 22:00 23:00
rile:M972825 #1-798 Acq:22-JUL-1997 05:53:55 GC fH- Voltage SIX 70SX
409.7974 r:2 XxptEPCUS2
TRIA1KLE LABS Text:TLI LCS TLH42299A
1004
24:00
25:00
2ff<00
SO:
50:
40:
o:
17:11
18:30
15:43 . 24:25 I I
KLl^jL^Sm^
17:00
18:00
15:00
20:00
21:00
22:0o
23>00
24:00
25»00
2fiOO
.8.4X6
.6.7X6
.5.0X6
13.4X6
'.1.7X6
-.0.0X0
Time\
-5.1X6
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0,0X0
Tim<
-1.4X7
'-.1.1X7
'-.8.5X6
'•.5.7X6
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-.0.0X0
Tim,
9.5X6
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0.0X0
Tim,
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'-.4.7X7
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0.0X0
Hme\
25139
kikka
-1.2X5
'-.9.4X4
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'•.2.3X4
10.0X0
Time\
240
-------
file
355.
TRIA
1001
80.
60.
40.
20.
0
16
rila
357.
TSIA
1001
80.
60.
40.
20.
0'
16
rile
357.
TSIA
1001
80.
60.
40.
20.
0
16
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369.
TSIA
1001
80.
60.
40.
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0
16
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330.
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1004
00:
so:
40:
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0"
15
:H972B25 #1-793 Acq: 22-JUL-1997 09:53:55 ec flf Voltage SIX 70SX SOH*lJ.JB5
8546 T:2 BSUB(256,30,-3.0) PXO(7,5,3,0.10\,5540.0,1.00\,r,I) XxptXPCOSS
IfSLE LABS TeJCtilXT LCS TLIt42299A
Al.
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:WS72025 tl-798 Acq: 22-JUL-1997 09:53,55 CC XH- Voltage SIX 70SX No±**:1397
8516 T:2 BSUB(256,30,-3 .0) PKD(7 ,5,3,0. 10\,55I9. 0,1. 00\,T,T) Xxp:XPCUS3
OGLE LABS T&it:TLI LCS TLH42299A
A9.
:00 17:00 18:00 19:00 20:00 21:00 22:00 23:00 24:00 25:00
:ff972825 tl-798 Acq:22-JVL-1997 09:53:55 SC XH- Voltage SIX 70SX NoLffil344
8949 T:2 BSU3(256,30r -3.0) PKD(7, 5, 3,0. 10%, 5375. 0,1.00\,r,I) Xxp:XPCUS2
NSLS LABS Text:TLI LCS TLIt42299A
A3.
:00 17:00 10:00 15:00 20:00 21:00 22:00 23:00 24<00 25 1 00
.-WS72025 tl-798 Acq:23-JUL-1997 09:53:55 SC XH- Voltage SIS 70SX JK>l«e:1170
0515 r.-2 BSUB(256,30,-3.0) PKD(7 ,5,3,0. 10\,4ftO. 0,1. 00\,r,T) XzptZPCUSS
TfSLX LABS Tsxt:TLI LCS TLIt42299A
Al.
027
25:00
14X6
26:00
6X7
(A
'25: 00'
7JT7
vv
-5.3X6
.4.3X6
.3.3X6
.2.1X6
.1.1X5
0.0X0
Umm
-3.0X6
J.4X6
.1.8X6
J..2X6
.6.1X5
0.0X0
8.2X6
.6.6X6
.4.9X6
.3.3X6
.1.6X6
0.0X0
.5.1X6
.4.1X6
.3.1X6
.1.0X6
.0.0X0
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:ff972825 tl-798 Acq:22-JUL-1997 09:53:55 CC JX+ Voltage SIX 708X
9792 1:2 Exp:EPCUS2
HSLX LABS Text: TLI LCS TLIt42299A —
24 t 46 7.8X7
J-6!38 17-5018-30 13'54 *°'53 aj'*3 33t43^*3? in^JV^"^v4£rtr2-
^^~~^W^^
.•00 17:00 10:00 15:00 20:00 21:00 ' *22:00 23:00* 24:00 ' '25:00 25:00
.6.3X7
.4.7X7
.3.1X7
.1.517
0.0X0
241
-------
rile:ft972B25 tl-422 Acq:22-JVL-1997 09:53:55 SC XX* VoJLtagia SIX 70S! Ho±m»i5154
373.8208 r:3 BSU3(2S6,30, -3.0) PXD(7,5,3,0.101,20616.0,1.00\,r,T) XxpiXTCtrsa
TRIANGLE LASS TfXtiTLI LCS TLIt42299A
100* A2.55E7
801
601
401
201
A1.84X7
Al. 71X7
27:00 28:00 29tOO
Mia: TO 72025 tl-422 Acq:22-JUL-1997 09:53t55 GC U+ Voltagn SIX 70SX Hoi*»:2486
375.8178 t:3 BSVB(256,30,-3.0) PXD(7,S,3,0.1Q\,9944.0,1.00\rr,X) XxpiXPCVSS
TRIASGLE LABS TaxtsTLI LCS TLH42299A
1004 A2.Q1S7
30100
00:
sol
40:
201
OJ
A1.47X7
A1.33S7
A1.8SX7
rr
AJL.78S7
27:00 28s00 29,00
rile:H972825 #1-422 Acqs22-JUZ-1997 09:53:55 GC ZT+ Voltag* SIX 708X Boim*t2794
383.8639 r-.3 BSOB(256,30, -3.0) PKD(7,S,3,0.10\,11176.0,1.0Q\,TeT) XzptXPCUS2
XBIAXGZE LABS Text:TLI LCS TLH42299A
1001
801
sol
401
201
01
30100
T
27:00 20:00 29:00
r±le:H972825 tl-422 Acq:22-JUL-1997 09:53:55 GC EH- Voltage, SIX 70S* Soitm17521
385.8610 T:3 BSUB(256,30,-3.0) PKD(7,5,3,0.10\r30084.0,1.00\,T,T) XzptSPCUSZ
TRIANGLE LABS Text .-HI LCS TLH42299A
100* A3.95E7 A3.59X7
JO 100
SOJ
601
401
201
A3.31S7
27:00 28:00 29:00 30:00
File-.0972825 tl-422 Acq:22-JVL-1997 09:53:55 GC JET* Voltagm SIS 70SX
392.9760 F:3 SxptEPCUS2
TSI ANGLE LABS Texts TLI LCS TLH42299A
100J
aoj
601
401
201
OJ
28:47
<^^
29i54
30:20
27:00 20:00 29:00
M.18.-W972025 «-422 Acq:22-JUL-1997 09:53:55 GC XH- Voltagw SIB 70S*
445.7555 F:3 ExptEPCUS2
TRIANGLE LABS Text:TLI LCS TLH42299A
1004
20:20
I 27:24 27:39
60J I I i I. , | | 20:00
401
201
01
30:00
27:00
28:00
8.7X6
'-.7.0X6
.5.2X6
'-.3.5X6
'-.1.7X6
0.0X0
-7.0X6
'-.5.6X6
'•.4.2X6
.2.8X6
.1.4X6
0.0X0
Tim*
-7.2X6
-.5.8X6
.4.3X6
-.2.9X6
'-.1.4X6
"-.o.oxo
-1.4X7
.1.1X7
.8.5X6
.5.6X6
J2.8X6
0.0X0
Tim*
-3.9X7
-.3.1X7
.2.3X7
J..6X7
.7.8X6
0.0X0
7.7X4
.6.1X4
-.4.6X4
.3.1X4
.1.5X4
29100
30100
0.0X0
Tim*
242
-------
PLLa:H973B25 91-422 Acq:22-3VL-l997 09t53:55 SC KH- Voltaym SO 70SI Soim»:1444
389.8156 F:3 BSOB(256,30,-3.0) PKD(7,5,3,0.10\,5776.0,1.00\,r,T) XxpiXPCOS2
TBIANSLS LABS Tart.-IXJ LCS TLIt42299A
100$ A2.02X7
80.
60.
40.
201
A1.45X7
28:00 29 > 00 30iOO
T±lastf972B25 41-422 Ac30S5
401.8558 1:3 BSU3(256,30, -3.0) PXD(7,5,3,0.10\,12220.0,1.00\,r,r) Kxp:fPCUS2
TRIANGLE LASS Tsurt.-TLJ LCS TLI442299A
1001
80.
60.
40.
20.
0.
A3. 74*7 A3.64X7
28s00 29:00 30:00
rile:W972825 fl-422 Acq:22-JDL-1997 09s53s5S GC SI+ Voltag* SIX 70SX Soim»tl951
403.8529 Ts3 BSUB(256,30,-3. 0) PKD(7,5,3,0.101,7804.0,1.00*,r,T) XxptXPCOSS
TRIANGLE LABS TextsTLI LCS TLH42299A -
2.001
80.
60.
40.
20.
0.
A3.12X7
28:00 29i00
Til*:tr97282S tl-422 Acq:22-JVL-1997 09:53:55 CC XH- Volt*g» SIX 70SX
392.9760 T:3 XiptXPCUS2
TSIANSLX LABS Tart .TEX LCS TLIf42299A
28,47
30100
1001
80.
60.
40.
20:
0.
27s 32
27:45 28:02 28:16
9sOO
-6.6X6
'.5.2X6
.3.9X6
.2.6X6
-1.3X6
0.0X0
-5.3X6
.4.3X6
.3.2X6
.2.1X6
-1.1X6
0.0X0
-1.2X7
'.1.0X7
.7.5X6
-5.0X6
.2.5X6
0.0X0
-1.1X7
.8.6X6
.6.4X6
-2.1X6
0.0X0
XI**
-3.9X7
.3.1X7
J.3X7
.1.6X7
-7.8X6
28:00
29100
30100
0.0X0
Tim*
A r\
-------
TiXa:»972a25 #1-440 Acqi22-JUL-1997 09*53:55 OC XI + Voltagm SIX 70S* Soim»t3306
407.7818 T:4 BSUB(2S6,30, -3. 0) PKD(7,5,3, 0.101,13224.0,1.00*,r,T) Xxp:XPCOS2
TRIANGLE LASS Imxt:TLI LCS TLIt42299A
1004 A1.35E7
80:
60:
40:
20:
0:
A7.91ES
31:00 32:00 33:00 34:00 35:00
T±le:tr97282S tl-440 Acqi22-JUL-1997 09:53:55 GC XH- Vbltmym SIX 70S* Xo±M»t4260
409.7789 T:4 BSUB(256,30,-3.0) PXD(7,5,3,0.101,17040.0,1.00*,r,I) Xxp:XPCUS2
TRIANGLE LASS Taxt:TLI LCS TLH42299A
100}
80.
sol
40:
20.
A1.21E7
A7.38E6
31:00 32:00 33:00 34:00 35:00
Tile:W972825 tl-440 Acq:22-JUL-1997 09:53:55 GC KI+ Voltage SIX 70SX Htiim»:2035
417.8253 F:4 BSUB(256r30, -3. 0) fKD(7,5,3,0.10\,»140.0,1.OQ\,T,T) Xxp:XfCUS2
TRIANGLE LABS T&ttsTLI LCS TLH42299A
1004 A1.05E7
aol
50:
40l
20:
31:00 32:00 33:00 34,00 35:00
r±la:W97282S tl-440 Acq:22-JUL-1997 09:53:55 GC XH- Voltagm SIX 70SX XOl»9tl456
419.8220 T:4 BSUB(256,30, -3.0) fXD(7,5,3,0.10\,5824.0,1.00\,T,T) Xxp:S?CUS2
TRIANGLE LABS Teit:TLI LCS TLH42299A
1004 A2.54E7
sol
60:
40:
20:
31:00 32:00 33:00
rile:W972a25 tl-440 Acq:22-JVL-1997 09:53:55 GC
430.9729 T:4 Xxp:£PCUS2
TRIANGLE LABS Taxt:TLI LCS TUt42299A
10°* _ 31,57 __32:27 _ 33*07 33:32
A_*v ^ ^.^^^^ A . _»* _i_»j'<>^\iA_»ii_AA .A.*..jt.A A^^JM.A^^J<^^^^
80j
50J
40J
30:
oj
34:00
Voltaye 5XX 70S!
34i03 34*25
35:00.
36:00
36:00
36100
36:00
31:00 32:00 33:00 34tOO
rila:H972825 tl-440 Acq:22-JUL-1997 09:53:55 GC XX+ Voltmgm SIX 70S*
79.7165 T:4 Exp:EPCOS2
TRIANGLE LABS TfXt.-TLI LCS TLIH2299A
so
35*00
34,55
36100
AjiJLjj^^
31:00
32: 00
33:00
34100
-4.4X6
.3.5X6
.2.6X6
.1.8X6
.8.8X5
0 0X0
-4.2X6
.3.4X6
.2.5X6
.1.7X6
.8.4X5
0.0X0
HM,
3.7X6
.3.0X6
J.2X6
JL.5X6
.7.5X5
0.0X0
T±m>
-8.8X6
.7.0X6
.5.3X6
.3.5X6
-1.8X6
0.0X0
Umi
-2.4X7
\-1.9X7
.1.4X7
J.5X6
.4.7X6
0.0X0
Hmu
-1.1*5
.8.5X4
.6.4X4
.4.3X4
-2.1X4
35:00
36:00
0.0X0
Time
244
-------
TiJLt
423
TSIJ
100.
80.
60.
40.
20.
0.
7766 F:4 BSUB(256,30,-3.0) SKD(7, 5,3,0
UfGLS LABS Tejct:TLI LCS TLH42299A
A7.28S6
)L
55 GC EI+ VOdtag* SIS 70S! VOif»,J.J96
.io*,5ia4. o,i.oo\,r,T) xxptxrcaas
A7.09X5
31:00 3.2:00 33iOO 34:00 ' 35,00 36', 00
rile,ti972825 H-440 Acqi22-JVL-1997 09,53,55 GC XX+ Voltmgm SIS 70SX Bairn* 1 1654
425.7737 r:4 BSU3(256, 30, -3. 0) PrD(7rS,3,0.10\,6616.0,l.OQ\,r,T) XxptXPCOBS
TRIANGLE LASS Teit:TLI LCS TLH42299A
1004 A7.43ES
80.
SO.
401
201
0'
31
rile
435.
TSIA
1003
80.
601
401
201
0'
31
rile
437.
TSIA
1001
801
60.
40.
201
0'
31
rile
430.
TSIA,
1001
80.
601
401
201
01
11
>w_
1-00 32:00 33:00 34:00 35,00 36,00
•.W972825 H-440 Acq:22-JVL-1997 09,53,55 GC XH- Voltage SIS 70SX SaiMe,3344
8169 T:4 BSUB(256r 30, -3.0) PKD(7,5,3,0.10\,13376.0,1.00\,r,T) Xxp,XTCUS2
NSLE LABS Text-.TLI LCS TLI942299A
A1.44E7
11
- /^ .
:00 32': 00 33 1 00 34:00 35,00 36,00
:ti972825 tl-440 Acq:22-JUL-1997 09,53,55 GC XI+ Voltage SIS 70SX Btii**,2460
8140 r:4 BSUS(256,30f-3.0) PKD( 7,5,3, 0 .10\,9B40.0r1.00\,T,T) XxptXfCUSS
NGLE LABS Texts HX LCS TLI#42299A - --
A1.43E7
1
:00 32:00 33:00
:«97282S tl-440 Acq:22-JUL-1997 09,53,5
9729 r:4 ElpsEPCOS2
UGLS LABS Tox-tiTLI LCS TLIf42299A
31:57 32:27 .JJ;°1
H'V>r*SJr#*t***~
-------
rile:W972825 tl-440 Acq:22-JUL-1997 09:53:55 GC XI+ Voltage SIX 70SX Boise t 219 8
441.7428 F:4 BSUS(256, 30, -3. 0) PK2(7 ,5,3,0 .10\,8792. 0,1. 00\,T,T) XxpiXPCOS2
TRIANGLE LABS TeJCt:TLI LCS TLI#42299A
1001 A8.54X6
90.
80.
70.
60.
50.
40.
30.
20.
10.
rile
443.
TRIA
1003
901
801
70.
601
sol
40.
301
201
101
0-
rile
430.
TRIA
1001
90.
80.
70.
60.
50.
40.
3ol
101
0-
Tile
513.
TRIAl
1001
901
801
701
601
SOI
401
301
201^
101
01.
'^,
31\00 32:00 33:00 34:00 35:00 36
:H97282S tl-440 Acq:22-JUL-1997 09:53:55 GC XH- Voltage SIX 70SX SoJLfe>1346
7399 F:4 BSUB(256,30, -3. 0) PKD(7,5, 3 ,0 .10\,5384 .0,1.00\,T,T) Kxp:XPCUS2
JfGLX LABS Text:TLI LCS TLIt42299A
A9.21X6
IL
3l':00 32:00 33:00 34tOO 35:00 36
•.W97282S tl-440 Acq:22-JUL-1997 09s53s55 GC XH- Voltage SIR 70SX
9729 ri4 Xxp:EPCUS2
NGLE LABS Text.-IXJ LCS TLIt42299A
I^Z^r**^^
31:00 32:00 33tOO 34\00 ' ' ' '3S\00 36
•.W972825 tl-440 Acq:22-JUL-1997 09:53:55 GC XI+ Voltage SIX 70SX
5775 Ts4 XxpiXfCUS2
VSLX LABS Text:TLI LCS TLIt42299A
31} 29 32t35 ,
33t02
34: 9
31>00 34tg3
lAJUuWJ|Ul^^
J1.-00 32:00 33:00 ' ' ' 34tOO ' ' ' 35:00 ' ' ' ' 36t
-2.4X6
.2.1X6
.1.9X6
11.7X6
.1.4X6
11.2X6
.9.5X5
.7.1X5
.4.7X5
.2.4X5
00 Time
-2.6X6
12.4X6
12.1X6
11.8X6
ll.6X6
11.3X6
[l.lX6
17.9X5
.5.3X5
12.6X5
0.0X0
00 Time
2.4X7
12.1X7
'.1.9X7
.1.7X7
.1.4X7
.1.2X7
19.5X6
''.7.1X6
.4.7X6
.2.4X6
0.0X0
00 Time
.1.1X5
.9.6X4
.8.5X4
.7.4X4
.6.4X4
.5.3X4
.4.2X4
.3.2X4
.2.1X4
.1.1X4
.0.0X0
00 Time
246
-------
34 00 34:06 34sl2 34,18 34,24 34t30
rilesW972S25 tl-440 Acq:22-JUL-1997 09:53:55 SC XH- Voltugm SIX 70S*
459.7348 f:4 BSOS(256,30,-3.0) PKD(7,5,3,0.10\, 4484 .Q,1.00\,T,T) XzptXPCOS2
TRIANGLE LASS TaxttTLI LCS TLH42299A
1001 A8.29E6
80.
so:
40:
.20:
ri.la:H972325 tl-440 Acq:22-JUL-J.997 09:53:55 SC SI+ Volt4g» SIR JOSS
457.7377 F:4 BSUS(256,30, -3.0) PKD(7,5,3,0.10\,5144.0,1.00\,T,X)
XSIAKSLS LASS Taxt.-HJ LCS TLH42299A
1001 A7.07E6
-1.8X6
J..4X6
J..1X6
.7.0X5
-3.5X5
0.0X0
34, 3f
0.
34 00 34:06 34:12 34',18 34>24 34',30
Tila:W972825 tl-440 Acq:22-JUL-1997 09:53:55 SC £1+ Voltaym SIX 70SX Xo±*»,13S3
469.7779 T:4 BSUS(25S,30, -3.0) PKD(7,5,3,0.10\r5412.0,1.QO\,TrT) XzptXPCOSS
TRIANGLE LASS Text:TLI LCS TLIf42299A
1004 A1.3.2E7
80J
eo:
-------
Peak Locate Examination:22-JUL-1997:09:11 File:W972824
Experiment:EPCUS2 Function:2 Reference:PFK j
-------
&'#'&'
fa.
,
TLI Project: 42299A
Client Sample: TLI LCSD
Method 23 PCDD/PCDF Analysis (a)
Analysis File: W972826
Client Project:
Sample Matrix:
TLIID:
Sample Size:
Dry Weight:
GC Column:
Iron & Steel-Chicago
XAD
TLI LCSD
1.000
n/a
DB-5
Date Received:
Date Extracted:
Date Analyzed:
Dilution Factor:
Blank File:
Analyst:
II
07/17/97
07/22/97
n/a
W972829
MM
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPX23704
WF54307
W972811
n/a
n/a
n/a
Anafytes
2,3,7,8-TCDD
12,3,7,8-PeCDD
1,2,3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
12,3,4,6,7,8-HpCDD
1,2,3,4,6,7,8,9-OCDD
2,3,7,8-TCDF
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
12,3,4,7,8-HxCDF
12,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
12,3,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
12,3,4,6,7,8,9-OCDF
Internal Standards
13Cl2-2,3,7,8-TCDF
v-i2-2,j,/,o-TU/D
'3C12-l,2,3,7,8-PeCDF
13C,2-l,2,3,7,8-PeCDD
13C12-l,2,3,6,7,8-HxCDF
13C12-l,2,3,6,7,8-HxCDD
13Cp-l,2,3,4,6,7,8-HpCDF
l3C12-l,2,3,4,6,7,8-HpCDD
13C,2-1,2,3,4,6,7,8,9-OCDD
'**w -no*: ^ "aptr-*:; $
0.41
2.0
2.4
2.0
1.8
1.9
4.1
0.38
2.1
1.9
2.1
2.1
2.4
22
2.0
1.6
3.5
*«t.(wt' ;c^^i**»^w^;ll^^»^^
3.7 91.6 40%-130%
3.4 JJ5.1 40%-130%
2.7 682 40%-130%
2.5 61.7 40%-130%
2.8 70.1 40%-130%
3.8 95.3 40%-130%
2.9 71 8 25%-130%
2.9 - 72.7 -25%-130%
4.1 51.5 25%-130%
r«w»
0.83
1.63
121
125
120
0.93
0.85
0.81
1.51
1.53
127
129
129
126
1.09
1.00
0.90
£***
0.76
" -0.79'--
1.49
1.52
0.52
1.24
n j.s
1.00
0.85
ITT
20:43
25:27
28:48
28:52
29:10
31:45
34:12
19:50
24:18
25:05
28:02
28:08
28:39
29:22
30:53
32:05
34:18
«T
19:50
— 20:41 —
24:17
25:27
28:07
28:51
-«__»
31:44
34:12
Flags
—
—
Flags
^__
Page 1 of 2
X237.PSR Y2.00. LARS 6.10.03
Triangle Laboratories, Inc.®
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 20:35 07/22/97
249
-------
TLI Project: 42299A
Client Sample: TLI LCSD
Method 23 PCDD/PCDF Analysis (a)
Analysis File: W972826
Alternate Star«tafftJ»(TypeA> Amt
HT.
13C,rl,23,7,8,9-HxCDF
13C12-2,3,4,6,7,8-HxCDF
3.5
3.4
86.4
84.2
40%-130%
40%-130%
0.52
0.49
29:22
28:38
Raeowny Standards
13d:-l,2,3,4-TCDD
13C,:-l,2,3,7,8,9-HxCDD
0.83
20:29 _
29:09 _
Data Reviewer
07/22/97
Page 2 of 2
X237 JSR rZOO, LARS 6.10.03
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 20:35 07/22/97
250
-------
Initial
..Date..
Daca Review By:
Calculated Noise Area: n/a
The Total Area for each peak with an ion abundance ratio outside
ratio limits has been recalculated according to method requirements.
Page No.
07/22/97
Listing of W972826B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. 10.. Flags.
TCDF
304-306
304-306
13C12-TCDF
316-313
316-318
TCDD
320-322
320-322
13C12-TCDD
332-334
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
SN
1
NL
WL
WL
SN
SN
SN
WH
1
NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
-SN
SN
1
NL
SN
SN
0:
18:
19:
00
34
50
0.
RO
RO
65-0.39
1.08
1.38
0.31
Peak
0:
18:
18:
19:
19:
20:
20:
21:
00
11
34
21
50
21
41
47
0.
RO
RO
RO
RO
RO
65-0.39
1.62
0.79
0.72
1.11
0.76
0.59
1.23
1.14
Peak
*w.
0:
17:
17:
18:
18:
18:
18:
18:
18:
19:
19:
19:
20:
20:
00
48
56
08
25
34
38
43
56
04
13
42
17
43
21; 02
21:11
0.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
65-0.89
0.94
0.42
6.03
2.43
0.80
1.97
0.65
2.25
0.21
1.98
1.81
1.35
2.21
0.83
1 . ?f> ,
1.89
Peak
0:
20:
20:
21:
21:
00
29
41
05
14
0.
RO
RO
65-0.89
1.41
0.33
0.79
0.73
2.17
0.820-1.109
20
34
1,631
1,631
.39
.80
.05
.05
0.
0.
727.82 903.23 1.
000
936
000 2378-TCDF
AN
0.950-1.050
10
24
70
53
13,164
163
32
55
13,164
.12
.76
.75
.79
.72
.60
.98
.83
.72
1? / »IV
0.
0.
0.
0.
5,671.13 7,493.59 1.
1.
1.
1.
000
917
936
976
000 13C12-2378-TCDF
026
043
098
ISO
0.850-1.064
6
4
3
5
6
4
2
1
1
5
5
11
1
1,164
7
9
1,164
.11
.34
.06
.45
.37
.66
.66
.98
.59
.17
.10
.27
.29
.53
Q1
.65
.53
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
527.50 637.03 1.
i
1.
000
861
867
377
890
898
901
905
915 .
922
929 .
952
981
002 2378-TCDD
m ft
024
AN
0.903-1.097
21
10,192
9,116
158
20
.10
.26
.75
.16
.23
0.
4,618.30 5,573.46 0.
4,030.41 5,086.34 1.
1.
1.
000
990 13C12-1234-TCDD
000 13C12-2378-TCDD
019
027
RSI
IS1
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 20:35 07/22/97
-------
Page No.
07/22/97
Listing of W972826B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_3.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
332-334
DC
DC
SN
SN
2
21:32
22
:19
RO
RO
1
0
.56
.32
Peaks
25
11
19,309
.06
.65
.01
1
1
.041
.079
xiuw-A . rnr*T\r\ i ~D-^S*TVO DA! 1 «t.t«.
PeCDF
340-342
340-342
13C12-PeCDF
.152-354
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
WL
WL
WL
WL
WL
WL
WL
WL
WL
WL
WL
WL
WL
WL
WL
WL
WL
WL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
2
NL .
WL
WL
WL
WL
WL
WL
WL
WL
WL
0:
16:
16:
16:
16:
17:
iOO
: 17
;23
:52
:55
10
17:20
17:31
17:48
18:
18:
18:
19:
20:
20:
21:
21:
21:
21:
22:
22:
23:
02
23
32
06
20
51
07
34
49
56
06
45
21
23:31
23:
24:
24:
24:
24:
25:
25:
25:
26:
59
18
36
47
55
05
27
41
05
1
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
.32-1.78
0.83
1.25
0.13
1
0.
.89
.46
0.98
0.33
0.37
0.93
7.
0.
2.
0.
1.
1.
1.
0.
0.
1.
0.
0.
0.
0.
1.
1.
1.
0.
0.
1.
1.
1.
1.
,45
,49
,02
,60
04
45
31
59
26
63
28
96
98
50
62
51
54
91
77
53
82
22
61
Peaks
0:
16:
17:
17:
17:
17:
18:
19:
20:
20:
00
15
03
28
47
59
16
50
03
10
1.
RO
RO
RO
RO
RO
RO
RO
RO
RO
'V « . ±\vL/LS I * l^rUf f WA J. W*V0
5
8
1
5
4
8
4
4
6
1
5
6
12
8
11
4
12
3
7
5
6
32
.92
.26
.83
.25
.59
.57
.56
.13
.43
.66
.87
.32
.27
.32
.67
.97
.26
.65
.60
.46
.20
.29
2.73
14
4,093
79
12,
9,
3,825,
.03
.55 2,464.17
.90
.47
.72
.57 2,313.11
18.05
16.
29.
.83
,48
0.904-1.095
0
0
0
0
0
0
0
0
0
.000
.671
.675
.695
.697
.707
.714
.721
.733
0.743
0.757
0.763
0.787
0.837
0,
.859
0.870
0.888
0.898
0.903
0.910
0.937
0.962
0.
0.
1,629.38 1.
1.
1.
1.
1,512.46 1.
1.
1.
1.
968
988
001 12378-PeCDF AN
013
021
026
033 23478-PeCDF AN
048
058
074
7,919.12
32-1.78
0.
2.
1.
0.
3.
0.
3.
0.
1.
1.
93
19
06
64
50
84
06
85
08
51
A.10 _
7.
12.
7.
10.
5.
12.
6.
5.
15.
17
29
45
17
28
32
30
74
00
0.835-1.165
o.aoo
0.
0.
0.
0.
0.
0.
0.
0.
0.
669
702
719
732
741
752
817
826 ~
830
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carofina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 20:35 07/22/97
or
-------
Page No. 3
07/22/97
Compound/
M_Z.... QC.Log Omit Why
Listing of W972826B.dbf
Matched OC Peaks / Ratio / Rat.
Time
.RT. OK Ratio Total.Area.. . Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
DC
DC
DC
DC
DC
DC
DC
DC
DC
352-354
PeCDD
356-358 DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
356-358
13C12-PeCDD
368-370 DC
DC
DC
DC
SN
SN
SN
SN
SN
SN
SN
SN
SN
3
NL
WL
WL
WL
WL
WL
WL
WL
WL
WL
WL
WL
WL
WL
WL
WL
ML
WL
WL
WL
WL
SN
SN
SN
SN
_SN
SN
1
NL
WL
WL
WL
21
22
23
23
23
24
24
24
25
26
26
26
:39
:40
:08
:20
:55
:17
:35
:47
:05
:04
:18
:37
RO
RO
RO
RO
RO
RO
RO
RO
RO
0.
0.
1.
2.
1.
1.
1.
0.
1.
0.
1.
2.
Peaks
0
16
16
16
17
17
18
18
19
19
19
19
20
20
20
21
22
22
22
22
23
23
23
23
24
24
24
25
:00
:24
:37
:48
:23
:43
:09
:27
:25
:29
:45
:54
:14
:28
:44
:49
:07
:17
:25
:38
:16
:38
:56
:59
:29
:42
:55
:27
1.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
32-
1.
1.
1.
2.
2.
0.
0.
8.
0.
0.
0.
0.
0.
0.
0.
0.
0.
2.
1.
1.
0.
1.
0.
1.
1.
2.
0.
1.
62
47
48
43
19
49
60
67
27
86
02
13
1.78
36
14
55
29
27
39
72
08
53
63
70
43
40
68
29
61
71
47
54
74
25
99
18
04
61
08
86
63
Peak
0
16
17
17
:00
:38
:08
:14
1.
RO
RO
RO
6
5
4
20
56
7,066
48
25
82
17
9
6
.99
.54
.32
.83
.02 34.05
.01 4,229.76
.39
.78
.42 50.10
.70
.03
.27
0.
0.
0.
0.
28.61 0.
2,836.25 1.
1.
1.
39.52 1.
1.
1.
1.
892
933
953
961
985
000 13C12-P6CDF 123 IS2
012
021
033 13C12-PeCDF 234 SCR2
073
083
096
7,204.45
4
11
10
4
5
4
7
2
7
5
12
7
5
9
3
7
6
3
11
12
2
5
1
7
23
9
12
2,315
2.315
.97
.85
.46
.77
.53
.34
.35
.42
.17
.59
.40
.91
.92
.48
.67
.88
.55
.87
.27
.97
.09
.53
.92
.07
.34
.64
.08
.76 1,435.76
.76
.32-1.78
1.
1.
0.
3.
09
52
45
42
4
10
2
8
.52
.41
.76
.47
0.919-
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
880.00 1.
1.027
000
644
653
660
683
696
713
725
763
766
776
782
795
804
815
857
869
876
881
889 . . _ . _ _ _
914
929
940
942
962
971
979
000 12378-PeCDD AN
0.843-1.157
0.
0.
0.
0.
000
654
673
677
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 20:35 07/22/97
253
-------
Page No.
07/22/97
Listing of W972826B.dbf
Matched GC Peaks / Ratio
/ Ret. Time
Compound/
M_2 QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak. 1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.,
Flags.
368-370
HxCDF
374-376
374-376
13C12-HXCDF
384-386
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
WL
WL
WL
WL
WL
WL
WL
WL
WL
WL
WL
WL
WL
WL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
2
NL
SN
SN
SN
SN
WH
WH
4
NL
SN
SN
SN
17
17
17
18
19
19
20
20
20
20
20
20
20
21
21
22
22
22
22
23
24
24
24
25
25
25
25
25
26
:24
:34
:40
:24
:13
:21
:00
:13
:23
:35
:42
:52
:59
:17
:30
:00
:10
:16
:38
:24
:11
:17
:41
:08
:14
:27
:35
:53
:08
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
1
1
1
0
2
0
2
0
1
4
5
0
1
0
0
2
0
2
2
0
1
1
4
0
4
1
1
0
1
Peaks
0
26
27
28
28
28
28
29
29
29
29
:00
:56
:49
:02
:08
:22
:39
:02
1.
RO
RO
RO
RO
.30
.96
.33
.58
.59
.72
.42
.27
.05
.35
.40
.42
.47
.18
.49
.36
.63
.15
.28
.58
.22
.63
.74
.49
.35
.52
.66
.23
.47
It W..VW.
,05-1.43
1
0
1
1
1
0
1
1
.83
.36
.93
.27
.29
.97
.29
.18
;22- 1 '*
:47
:53
RO
1.65
1
.10
Peaks
0
26
27
27
:00
:52
:10
:20
0.
RO
RO
RO
.43
0
0
0
1
-0.59
.74
.53
.29
.04
6
9
4
4
5
6
8
3
6
6
5
7
10
1
5
6
5
10
2
2
8
22
14
3
2
3,390
361
5
18
.38
.26
.31
.29
.92
.24
.80
.80
.02
.48
.74
.57
.91
.40
.54
.91
.15
.76
.50
.55
.55
.18
.08
.73
.27
.75 2,042.85
.32 225.58
.23
.39
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
1,347.90 1
135.74 1
1
1
.684
.690
.694
.723
.755
.760
.786
.794
.801
.809
.813
.820
.324
.836
.845
.864
.871
.875
.889
.919
.950
.954
.970
.988
.991
.000 13C12-PeCDD 123 IS3
.005
.017
.027
3,752.07
: PoCDu / iD^CuF Follows —————————————————————
16
2
4
3,294
4.466
15
3,470
9
-2,398
11
12
14,130
.60
.69
.68
.83 1,844.38
.25 2,516.57
.82
.68 1,958.30
.47
11 1 "flo_u,«~nir IM _
1
1
.059
.063
0.858-1.142
10
6
5
5
.59
.67
.68
.75
0
0
0
0
.000
.956
.966
.972
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 20:35 07/22/97
254
-------
Page No. 5
07/22/97
Compound/
M_Z.... QC.Log Omit Why
Listing of W972826B.dbf
Matched GC Peaks / Ratio
/ Ret. Time
.RT. OK Ratio Total.Area... Area.Peak.1. . Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
384-386
HXCDD
390-392
-3-90-i92_
13C12-HXCDD
402-404
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
3
NL
WL
WL
SN
SN
SN
SN
SN
SN
SN
SN
SN
WH
WH
WH
WH
WH
WH
^
NL
WL
WL
WL
WL
SN
SN
27:32
27:57
28:07
28:16
28:28
28:38
29:02
29:08
29:15
29:22
29:39
29:47
29:57
30:01
30:07
30:13
Peaks
0:00
27:17
27:22
27:32
27:37
27:38
27 : 47
27:57
28:21
28:24
28:31
28:38
28:48
28:52
29:10
29:37
29:49
29:54
30:00
30:15
30:19
Peaks
0:00
27:09
27:17
27:42
27:46
28:22
28:31
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
1.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
1
1
0
1
1
0
0
2
0
0
0
0
0
0
2
3
05
1
0
1
0
2
0
2
0
1
0
0
6
1
1
1
2
0
0
0
0
0
.43
.94
.52
.04
.41
.49
.23
.10
.53
.52
.10
.50
.40
.66
.41
.54
-1.43
.09
.67
.15
.99
.46
.51
.45
.36
.29
.34
.38
.70
.21
.25
.20
.21
.63
.81
.19
.85
.83
3
3
5,696
40
7
5,516
9
10
16
4,868
6
19
15
11
3
2
16,081
5
2
6
9
2
1
3
7
5
2
1
2
2,944
3,180
2,487
14
9
4
2
5
2
.49
.26
.14 1,938.72
.27
.14
.33 1,825.91
.42
.68
.66
.98 1,673.79
.37
.17
.10
.54
.44
.57
.45
o i Uyf*nn T7rtl 1 nw«
C I fOv^UU JrOXXQWS ~~
.33
.24
.03
.97
.35
.23
.45
.93
.10
.64
.63
.06
.67 1,614.86
.01 1,764.90
.86 1,354.83
.40
.75
.82
.04
.78
.26
0
0
3,757.42 1
1
1
3,690.42 1
1
1
1
3,195.19 1
1
1
1
1
1
1
.979
.994
.000 13C12-HXCDF 678
.005
.012
.018 13C12-HXCDF 234
.033
.036
.040
.044 13C12-HXCDF 789
.055
.059
.065
.068
.071
.075
IS4
ALT2
ALT1
0.949-1.015
0
0
0
0
0
0
0
0
0
0
0
0
1,329.81 0
1,415.11 1
1,133.03 1
1
1
1
1
1
1
.000
.946
.949
.954
.957
.958
.963
.969
.983
.984
.988
.992
.998 123478-HxCDD
.001 123678-HxCDD
.011 123789-HxCDD
. 027 _
.034
.036
.040 '
.049
.051
AN
AN
AN
_.
a si 2 SA
1.
RO
RO
RO
RO
RO
,05-1.43
2
1
2
1
1
1
2
.07
.71
.99
.25
.81
.27
.01
7
9
6
6
9
6
3
.53
.09
.38
.59
.72
.53
.96
0.965-1.035
0
0
0
0
0
0
0
.000
.941
.946
.960
.962
.983
.988
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 20:35 07/22/97
255
-------
Page No.
07/22/97
Listing of W972826B.dbf
Matched GC Peaks / Ratio /
Rat. Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.l.. Area.Peak.2.. Rel.RT Confound.Name.. ID..
Flags.
402-404
HpCDF
408-410
408-410
13C12-HpCDF
418-420
418-420
HpCDD
424-426
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
rv-
DC
DC
DC
DC
SN
SN
WH
WH
WH
2
NL
ML
SN
SN
SN
SN
SN
WH
WH
WH
WH
WH
WH
WH
WH
WH
WH
2
NL
SN
SN
SN
SN
SN
SN
-SN
SN
WH
WH
1
NL
28:
29:
29:
29:
29:
30:
30:
51
09
28
42
54
03
08
RO
RO
RO
RO
RO
1
1
0
0
6
2
0
Peaks
0:
30:
30:
31:
31:
31:
31:
31:
32:
32:
33:
33:
33:
33:
33:
34:
34:
35:
35:
00
41
53
18
34
40
45
54
05
36
07
12
35
52
59
05
18
14
40
0.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
.24 5
.21 5
.72
.67
.20
.28
.82
11
» l>,» « _
,590
,429
16
11
4
3
7
,019
Uu^n
88-1.20
0
1
1
1
1
1
0
0
1
4
1
1
0
0
0
3
1
2
1
Peaks
0:
30:
31:
32:
32:
33:
33:
33:
00
52
26
05
58
22
32
40
0.
RO
RO
RO
RO
RO
RO
RO
34 :-15- RO
34:39 RO
35:
35:
23
29
RO
RO
37
1
0
1
2
0
0
0
0
.70
.38
.09 2
.30
.26
.47
.85
.77
.00 1
.08
.30
.31
.85
.87
.62
.31
.23
.21
.54
3
-0.51
.04
.45 3
.17
.46
.75
.57
.76
.71
3 48
8.39
1
0
Peak
0:
00
0.
.07
.92
3
88-1.20
1
.04
12
3
,477
3
10
11
15
14
,420
2
7
9
9
30
15
10
142
5
16
,897
6
,382
11
7
10
15
8
11
.38 3,092.03
.50 2,978.12
.15
.63
.36
.58
.84
.88
.67
.77
.79 1,292.70
.34
.20
.55
.10
.12
.12 709.51
.16
.10
.22
.96
.62
.57
.08
.86
.10
.08
.91
.31
.04 1,049.69
.03
.47
.37
.12
.71
.38
^ on
1
3
5
.56
.50
.83
2,498.35 1
2,451.38 1
1
1
1
1
1
.000 13C12-HXCDD 678 IS5
.010 13C12-HXCDD 789 RS2
.021
.029
.036
.042
.044
0.995-1.045
0
0
1,185.09 1
1
1
1
1
1
710.61 1
1
1
1
1
1
1
1
1
1
1
0.935
0
2,332.35 1
1
1
1
1
1
1
.000
.994
.001 1234678-HpCDF AN
.014
.023
.026
.029
.033
.039 1234789-HpCDF AN
.056
.073
.076
.088
.097
.101
.104
.111
.141
.156
-1.130
.000
.000 13C12-HpCDF 678 IS6
.018 .
.039 13C12-HpCDF 789 SUES
.068
.081 .
.086
.091
..__._ L nn
1
1
1
.123
.146
.150
,382.04
7
.73
0.976-1.006
0
.000
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 20:35 07/22/97
25G
-------
Page No. 7 Listing of W972826B.dbf
07/22/97 Matched OC Peaks / Ratio / Ret. Time
Compound/
M_2.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak. 1. . Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
424-426
13C12-HpCDD
436-438 DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
436-438
OCDF
442-444 DC
DC
DC
DC
DC
DC
DC
DC
SN
WH
WH
WH
WH
WH
WH
WH
WH
WH
WH
WH
WH
WH
WH
WH
WH
WH
WH
WH
WH
1
NL
SN
SN
WH
WH
WH
WH
WH
WH
WH
WH
WH
WH
1
NL
SN
SN
SN
SN
SN
SN
SN
31:
31:
32:
32:
32:
32:
32:
33:
33:
33:
33:
33:
34:
34:
34:
34:
35:
35:
35:
35:
35:
35:
17
45
05
12
22
31
53
05
18
32
39
54
02
13
39
49
02
06
15
22
41
49
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
1.
0.
3.
3.
0.
1.
0.
0.
0.
3.
1.
0.
0.
1.
2.
1.
4.
7.
3.
1.
1.
1.
16
93
04
56
58
24
63
42
99
49
48
33
95
07
05
13
62
29
97
48
84
22
Peak
0:
31:
31:
32:
33:
33:
33:
33:
33:
34:
34:
34:
35:
35:
00
44
58
32
02
22
27
34
46
12
24
46
39
47
0.
RO
RO
RO
RO
RO
RO
RO
RO
RO
16.
1,424.
11.
5.
10.
9.
11.
10.
18.
8.
10.
5.
7.
146.
5.
13.
1.
0.
4.
5.
10.
13.
1,424.
67
27 686.83
26
94
18
75
18
55
71
57
02
37
94
91
73
37
73
86
73
81
98
83
27
.88-1.20
0.
1.
1.
0.
1.
0.
1.
3.
0.
1.
0.
2.
1.
4.
91
00
51
31
25
86
16
07
24
13
52
02
02
33
Peak
0:
30:
30:
31:
31:
31:
32:
32:
00
51
58
23
30
48
07
27
0.
RO
RO
RO
RO
RO
RO
- Above
12.
2,840.
25.
6.
14.
15.
28.
7.
7.
195.
23.
9.
7.
6.
2,840.
39
38 1,422.27
23
20
57
91
77
63
81
00
34
20
96
02
38
: HpCDD / Octa-CDD and CDF
,76-1.02
0.
0.
1.
1.
0.
1.
1.
0.
96
71
17
50
75
30
64
93
5.
7.
6.
11.
14.
18.
6.
18.
36
77
39
25
95
03
29
15
0.
737.44 1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
986
001 1234678-HpCDD AN
Oil
015
020
025
036
043
049
057
060
068
072
078
092
097
104
106
111
114
124
129
0.968-1.032
0.
1,418.11 1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
0.883-
0.
0.
0.
0.
0.
0.
0.
0.
000
000 13C12-HpCDD 678 IS7
007
025
041
051
054
058
064
078
084
096 . . .
123
128
1.117
000
902
905
918
921
930
939
949
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713 Printed: 20:35 07/22/97
Phone: (919) 544-5729 • Fax: (919) 544-5491
-------
Page No. 8 Listing of W972826B.dbf
07/22/97 Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
0.957
0.966
0.972
0.977
0.993
1.000
786.39 873.37 1.003 OCDF AN
1.011
1.015
1.032
1.042
1.049
442-444
OCDD 0.76-1.02 0.883-1.117
458-460 DC NL 0:00 RO 0.66 3.89 0.000
34:12 0.85 1,499.11 688.15 810.96 1.000 OCDD AN
DC SN 34:27 0.87 32.47 1.007
458-460 1 Peak 1,499.11
13C12-OCDD 0.76-1.02 0.995-1.004
470-472 DC NL 0:00 RO 1.10 4.59 0.000
34:12 0.85 2,683.79 1,229.42 1,454.37 1.000 13C12-OCDD IS8
470-472 1 Peak 2,683.79
Column Description "Why" Code Description QC Log Desc.
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
1
32:
33:
33:
33:
33:
34:
34:
34:
34:
35:
35:
35:
44
02
15
25
58
11
18
34
42
18
38
52
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
0
0
1
1.
0,
0.
0.
0.
2.
1.
0.
5.
.99
.68
.08
.32
.70
.65
.90
,46
.25
37
60
31
Peak
14.
18.
7.
3.
6.
17.
1,659.
12.
7.
7.
3.
4.
1,659.
86
39
98
63
60
69
76
87
71
86
18
06
76
M_Z -Nominal Ion Hass(es) WL-Below Retention Time Window A-Peak Added
..RT. -Retention Time (mm:ss) WH-Above Retention Time Window K-Peak Kept
Rat.l -Ratio of M/M+2 Ions SN-Below Signal to Noise Level D-Peak Deleted
OK -RO=Ratio Outside Limits
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1001
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0:
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17*00 18*00 15:00 20*00 ' 21*0o' '22*00 ' '23*00' ' '24*00
3X7 -.1.2X7
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L7.4X5
:4.5X5
12.5X5
0.0X0
25*00 '25*00 ' ' Time
file * W9 72825 #1-798 Ac?:22-JZ7Z-1557 10*35*44 GC XH- Voltage SIX 70SX Soiae:1345
353.8970 F:2 BSUB(256r30r-3.0) PKD(7,5,3,0.10\rS380.0,1.00\rT,T) XxptXPCUS2
TXIASSLX LABS TextiTLI LCSD TLIt42299A
ion
80:
50:
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0:
A2.I
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rll»:H972826 tl-798 Aoqt22-JUL-1997 10*35:44 GC XI+ Voltage SIX 70SX
330.9792 fi2 XxptXPCUS2
TXIAOSLX LABS TextiTLI LCSD TLIf42299A
ion
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'25*00' ' '26:00 ' ' Time
24:45 6.9X7
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T±leitl972826 tl-798 Aoqi22-JVL-1997 10*35:44 GC XT* Voltage SIX 70SX
409.7974 Ti2 Sxp:EPCUS2
TXIAOGLX LIOS TextiTLI LCSD TLIt42299A
1001
80:
50:
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15*53 j
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17*00 18*00 15*00 20*00 21*00 22*00 23*00 24*00
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0.0X0
35 1 00 26 1 00 Time
1.5X5
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11 ttSzS^
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11.2X5
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MKLE LASS TeztiTLI LCSD TLIt42299A
I Al.
fioo 17(00 18t00 19:00 20(00 21(00 22:00 23(00 24(00 25:00
HH972826 tl-798 Aoq,22-JOL-1997 10,36,44 GC XH- Voltage SIX 70S* Hairnet 105 3
8516 T,2 3SU3(256,30,-3.0) fXD(7,5 ,3,0 ,10\, 4212. 0,1. 00\,T,T) Xxp:KPCUS2
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ttfS72826 tl-798 Acq,22-JOL-1997 10,36,44 GC XI+ Voltaga SIX 70SK Naif e: 1376
8949 T,2 3SV3(256,30,-3.0) PXD(7,5,3,0.10\r5504.0,1.00\,T,X) Xxp,XPCUS2
JKILX LASS TextiXLI LCSD XLH42299A
A2.
477
2ff(00
0X6
26(00
1417
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8919 r,2 SSUS(256,30,-3.0) PXD(7, 5, 3,0.101,5056. 0,1. 00\,T,T) Xxp,XPCUS2
BGLX LASS Text.:XLI LCSD XLIt42299A
A1.35X7
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:V972836 tl-798 Acq:22-JUL-1997 10,36,44 GC XI + Voltage SIX 70SX
9792 r>2 Xxp,XPCVS2
9SLX LA3S Text:TLI LCSD XLXt42299A
24,46
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A
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r±lf:H973836 fl-423 Acq,22-JVL-H97 I0t36i44 SC XI* Voltaga SIS 70S* Noime,2601
383.8639 r,3 BSOB(256,30, -3.0) fXD(7,5,3,0.101,10404.0,1.00\,r,T) XxpiXfCUS3
TXIAHSLX LABS TtJCtiTLI LCSD TLH42299A
IOCS A1.94X7
A1.83X7
TLL»iW972S26 fl-433 Acq,33-JUL-1997 10:36:44 SC XX+ Voltage SIX 70SX Noia«:6791
373.8308 Tt3 BSUB(356,30,-3.0) fXD(7,5,3,0.10\,27164.0,1.00\,f,T) Xxp,XPCOS2
TXIAHGLX LABS T«xt»ZU LCSD TLH43399A
100\ A3.52X7
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Til»tH972826 tl-433 Aoqs33-JOL-1997 10136144 SC EI+ Volttyu SIX 70SX Boi*»t3704
375.8178 ri3 BSUB(356,30,-3.0) m(7,S,3,0.10\,14816.0,1.00\,r,T) XxpiXPCUS3
TXIAHOLX LABS TaxtiXLI LCSD TU*42299A
30:00
1003
80:
60:
40:
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0:
A1.95X7
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30,00
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401
301
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37:00 28,00 29:00
ttl»iW973836 tl-433 Acqs33-JVL-1997 10:36:44 SC XI+ Voltag* SIX 70SX Boi»ut3503
385.8610 Tt3 BSOB(356,30,-3.0) PXO(7,5,3,0.10\,14013.0,1.00\,r,T) XxptXPCUSS
TSIAtKLS LABS TaxttTLI LCSD XLIf42399A
30:00
1003
80J
601
401
30J.
A3.69E7
A3.30X7
37:00 28:00 29:00
r±l»t*973836 fl-433 Aoqt33-JUZ-1997 10:36:44 GC XH- Volta^v SIX 70SX
393.9760 r>3 XxptXPCUSS
TXIANGLX LABS T*xt:TLI LCSD TLH42299A
30 tOO
1001
so:
so:
40:
20:
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27iO« 37:33 A. _^.,
AA^ **-»v^~»-v-v^ ^^*^M-
28:47
37:00 38,00 39,00
T±l»ttr972826 tl-433 Acq,22-JOL-1997 10,36,44 GC XI + Voltagu SIX 70SX
445.7555 f,3 Kip,EPCU32
TXIAHGLX LABS TmrttTLI LCSD TLXt42399A
37>53 38,37 38,56
28,26
30,00
1001
80:
60:
40:
30:
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37,13
39,30
37,00
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13.7X6
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263
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399.8156 ri3 BSUB(256,30, -3.0) HD(7,S,3,0.10\,5564.0,1.00\,r,T) XxptXPCOSS
TRIAHSLX LASS TfXtsTLI LCSD TLH42299A
10 0\ A1.61X7
80.
60.
40.
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A1.35X7
28t00 29i00 30,00
f±l»ita72836 tl-423 Acqt22-JVL-1997 10*36,44 GC KI+ Voltagm SIS 7031 Xoi*»il273
391.8127 Tt3 BSUB(256,30, -3.0) fX»(7,5,3,0.10\,5092.0,1.00\,r,T) Xxp,XfCOS2
IAJKHJC LABS TmxtiXLI ZCSD TLX942299A
100\ A1.33E7
80.
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40.
20:
A1.13E7
I V.
28,00 29,00 30,00
rll*iM972836 tl-423 Acq,22-JUL-1997 10,36,44 GC XI+ Voltage SIX 70SX lto±m*,3485
401.8558 r,3 BSUB(256,30,-3.0) nO^7,5,3,0.10\,13940.0,1.00\,T,T) Xxp,XPCUS3
XXIAJfSLX LABS TmrtsTLX LCSD TLX942299A
lOOi, A3.09X7 *2.98X7
SO.
40.
20.
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28,00 29,00 30,00
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03.8529 T,3 BSU3(256,30,-3.0) tXft7,5,3,0.10%,6720.0,1.OQ\,T,T) Xxp,XPCUS2
XSIAOSZX LABS T^xtiXLZ LCSD XLX942299A
80.
60.
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20:
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A2.45X7
38,00 39i00
il*,M972826 tl-423 Aaq,23-JUL-1997 10,36,44 GC EH- Voltage SIX 70SX
92.9760 T,3 Xxp,XfCOS2
'IANSLX LABS TmzttXLI LCSD TLI942299A
00$ 28147
27,32
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264
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407.7818 r-.4 BSUS(256,30,-3.0) PXD( 7,5, 3,0.10\,12924 ,0,1.00\,T,T) XxpiXTCOS2
TXIAJKLX LABS Teit:TLI LCSD TLIt42299A
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80.
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A1.29X7
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Jl.-OO 32tOO 33:00 ' J4iOO J5»00 35*00 Time
riletM972826 tl-440 Acqi22-JUL-1997 10,36:44 GC XH- Voltage SIX 70SX Holtet4598
409.7789 T:4 BSU*(256, 30, -3. 0) PXD(7, 5, 3, 0.101,18392. 0,1.00*,r,T) XxpiXPCOS2
TXIAHGLX LABS TextlTLI LCSD TLIt43299A
1003
ao:
60-
40:
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A1.19X7
A7.11X6
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JlioO 32tOO ' 33tOO ' ' '34\00 ' ' 35tOO JfflflO Time
riletH972826 tl-440 Acqi22-JUL-1997 10:36:44 GC XX+ Voltage SIX 70SX Noiaet3383
417.8253 r:4 BSUS(256,30,-3.0) PlO}(7,5,3,0.10%,9132.0,1.00\,f,T) XxptXPCOS2
TXIAOGLX LABS Text. -JIT LCSD TLIt42299A
1001
80:
50:
40:
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Al . 05E7
1 W
3.8X6
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Jl.-OO 32tOO ' ' ' '33tOO JrfiflO 35»00 36:00 Time
rile>m72826 tl-440 Acq»22-JUL-1997 10,36:44 GC XI+ Voltage SIX 70SX Boi*e:2191
419.8220 T:4 BSVB(256,30,-3.0) PXD(7,5, 3,0.10\,8764 .0,1. 00\,T,T) Xxp:EPCUS3
TXIAHGZS LABS TeitiTLI LCSD TLH42299A
1001
80:
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40:
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A2.33X7
1 V
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0.0£0
31:00 33iOO 33tOO 34tOO J5ioO. ' 3ff»00 Time
riletM972826 tl-440 Aoq>22-JUL-1997 10:36,44 GC KI+ Voltage SIX 70SX
430.9729 r>4 XxptXPCUS2
TXIASGLX LABS TextlTLI LCSD XLIt42299A
100S
80:
60:
40:
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Tiletm72B26 tl-440 Acqt22-JVL-1997 10:36:44 GC XII- Volt«9* SIX 70SX
479.7165 Ti4 XzptXPCUS2
TXIAHGLX LABS TeltsTLI LCSD TLIt43299A
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31 • 01 _t2 J5 1
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31\00 32tOO ' 33tOO 34tOO 35»00 36tOO Time
265
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423.7766 r*4 »SU3(256,30,-3.0) PXa(7,3,3,0.10\,7900.0,1.00\,TfT)
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100
80
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m»iN972826 tl-440 Ac*J,22-JUL-1997 10*36*44 GC XH- Vbltag* SIS 70SX Xois**1889
425.7737 T*4 BSOB(256, 30, -3.0) PXD(7,5,3,0.10+,7S56.Q,1.00+,T,T)
XSIAOeZX LASS TmxtiTLI LCSD XLXt42299A
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435.8169 r*4 SSUB(256, 30, -3.0) PXD(7,5,3,0.10\,12300.0,1.00\,T,T)
XXIAHGLX LASS TfltiTLI LCSD TLIt42299A
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437.8140 r*4 asUS(256,30,-3.0) PKD(7,5r3r0.10*r13472.0,1.00\,TfT)
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30.9729 r*4 Xxp*XPCUS2
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430.9729 ft4 Xxp:EPCUS2
3XIAHGLX LABS ToxtlTLI LCSD
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801
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513.6775 Ti4 XlcptXPCUS2
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901
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601
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.7.1X4
.6.1X4
J.1X4
.4.1X4
.3.1X4
.2.0X4
.1.0X4
a. Of a
34*00 35*00 36*00 Tim«
267
-------
rU.a,if971826 tl-440 AdJi23-22-JUL-1997 10,36,44 GC XH- Volt*?* SXX 70SX Boim*,137B
459.7348 T,4 3SO3(2S6,30,-3.0) PXD(7,5r3,0.10\,5512.0,1.00\rr,T) XxptXPCUS2
XRIAHGZX LASS T«Xt»TLX LCSD TLIf42299A
AS.11X6
34,36
34', 06 34', 12 34,18 34,24 34,30
r±luim72826 tl-440 Acgs22-JUL-1997 10,36,44 CC JET* VoZtagw SIX TOSS Soiam,1336
469.7779 f>4 3SU3(256,30,-3.0) PKD(7,5r3,0.10\,5344.0,1.00\,r,T) Xip,EPCUS2
TXIABGLX LASS TfXttTLI LCSD XLIt42299A
34136
100*
so:
so:
A1.23S7
40:
20:
34 00 34,06 34,12 34,18 34,24 34,30
r±lm»K972826 tl-440 Acq*22-JUL-1997 10,36,44 GC XI+ Voltagm SXX 70SX Boim*tl217
471.7750 f,4 BSUS(256,30,-3.0) PXJJ(7,5r3,0.10\,486a.O,1.00\,T,X) XxptXPCUS2
TSIAOSLS LASS TurttTLI LCSD TLIt42399A
1004
34136
34 00 34',06 34,12 34,18 34,24 34',30
•±JLmiH972826 tl-440 Acqt22-JOL-1997 10,36,44 GC XH- Voltag* SIX 70SX
30.9729 T,4 XzpiXPCUS2
aiAOGLX LASS TmrtiTLI LCSD TLIt42399A
34_t20
80.
60.
40.
20.
0.
34136
-1 . 8X6
.1.5X6
.1.1X6
.7.3X5
-3.6TS
-2.3X6
.1 . 8X6
.1 . 4X6
.9.0X5
.4.5X5
.0.0X0
3.1X6
.2.5X6
.1.9X6
.1.3X6
.6.3X5
'.0.0X0
3.6X6
.2.9X6
2.2X6
.7.2X5
34 00
34,06
34112
34,18
34,24
34,30
34,36
.0.0X0
Tim*
.2.0X7
1.6X7
1.2X7
8.2X6
4.1X6
0.0X0
Time
263
-------
Peak Locate Examination:22-JUL-1997:10:34 File:W972826
Experiment:EPCUS2 Function:2 Reference:PFK !
CD
CM
-------
CALIBRATION
DATA
Triangle Laboratories, Inc.
801 Capitals Drive P.O. Box 13465
Durham, HC 277134411 Research Triangle Park, NC 277094485
919-544-5729 Fax* 919444*5491
270
-------
Initial Calibration Summary for WF54307
Instrument :
Analyses
Tocal MCDF
Tonal MCDD
Tocal DCDF
Total DCDD
Total TriCDF
Total TriCDD
2378-TCDF
TOTAL TCDF
2378-TCDD
TOTAL TCDD
12378-PeCDF
23478-PeCDF
TOTAL PeCDF
12378-PeCDD
TOTAL PeCDD
123478-HxCDF
123678-HxCDF
234678-HxCDF
123789-HxCOF
TOTAL HxCDF
123478-HxCDD
123 67 3 -HxCDD
123789 -HxCDD
TOTAL HxCDD
1234678-HpCDF
1234789-HpCDF
TOTAL HpCDF
1234678-HpCDD
TOTAL HpCDD
OCDF
OCDD
Other Standards
37C1-TCDD
13C12-PeCDF 234
13C12-HXCDF 473
13C12-HxCDF 234
13C12-HXCDF 789
13 C12 -HxCDD 478
13Cl2-HpCDF 789
Internal Standards
13C12-2378-TCDF
13C12-2378-TCDD
13C12-PeCDF 123
V ^ / ^ ** 1 •* ' ***• ****** «* *•••••* **«« W *
w
0
0
0
0
0
0
1
1
1
1
1
1
1
1
1
1
1
1
0
1
0
1
0
0
1
1
1
1
1
1
1
0
0
0
0
0
0
0
1
1
1
RF
.000
.000
.000
.000
.000
.000
.295
.295
.244
.244
.128
.122
.125
.358
.358
.116
.494
.037
.910
.139
.882
.123
.980
.995
.478
.066
.272
.060
.060
.427
.097
RF
.971
.927
.911
.805
.693
.892
.737
RF
.408
.051
.016
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
SD
.000
.000
.000
.000
.000
.000
.126
.126
.102
.102
.031
.047
.037
.124
.124
.051
.066
.065
.049
.056
.051
.080
.043
.049
.080
.058
.068
.114
.114
.097
.078
SD
.007
.020
.011
.024
.014
.008
.013
SD
.060
.019
.047
%RSD
100%
100%
100%
100%
100%
100%
10%
10%
8%
8%
3%
4%
3%
9%
9%
5%
4%
6%
5%
5%
6%
7%
4%
5%
5%
5%
5%
11%
11%
7%
7%
%RSD
1%
2%
1%
3%
2%
1%
2%
%RSD
4%
2%
5%
Page
RT
19:45
20:35
24:11
24:57
25:20
27:54
28:00
28:31
29:14
28:39
28:44
29:02
30:44
31:56
31:35
34:06
34:00
RT
20:35
24:57
27:54
28:31
29:14
28:38
31:55
RT
19:43
20:35
24:10
1
RT/LO
0:01
0:35
6:43
7:35
10:43
12:35
15:43
16:35
20:10
21:20
23:59
24:43
26:44
27:35
29:59
29:59
RT/LO
18:35
22:10
23:44
RT/LO
18:4J
18:35
20:10
RT/HI
13:43
14:35
14:43
15:35
17:43
18:35
23:43
24:35
28:10
29:20
31:59
32:43
34:44
35:35
37:59
37:59
RT/HI
22:35
26:10
34:44
RT/HI
20:43
22:35
28:10
Ratio 1
0
0
0
0
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
0
0
.784
.784
.825
.325
.561
.493
.524
.578
.578
.280
.265
.251
.254
.263
.237
.213
.229
.225
.026
.068
.043
.013
.013
.911
.837
Ratiol.
1
0
0
0
1
0
.493
.510
.503
.505
.221
.430
Ratiol
0
0
1
.750
.799
.472
Ratio2 N
0
0
0
0
0
0
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
Ratio2 N
5
5
5
5
5
5
5
Ratio2 N
5
5
5
f-z-t^^i-. I _l*__*A^jk,Mi !•**» 4* A**«ftlu+{«M^ CAM •£«»«* A ni*MA2«»_
801 Capitals Drive • Durham, North Caioina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 13:05 04/30/97
271
-------
TRIANGLE LABORATORIES, INC.
Initial Calibration Suasnary for WFS4307
13C12-PeCDD 123
13C12-HXCDF 678
13C12-HXCDD S78
13C12-HpCDF 678
13C12-HpCDD 678
13C12-OCDD
0
1
1
0
0
0
.539
.495
.079
.363
.719
.479
0
0
0
0
0
0
.032
.041
.021
.017
.020
.029
6%
3%
2%
2%
3%
6%
25:20
27:59
28:43
30:44
31:35
33:59
21
23
27
28
30
31
:20
:59
:43
:44
:35
:59
29:
31:
29:
34:
32:
35:
20
59
43
44
35
59
1
0
1
0
1
0
.482
.507
.221
.437
.023
.860
Daca: 04/30/97
5
S
5
5
5
5
Recovery Standards RF SD %RSD RT RT/LO RT/HI Ratiol Ratio2 N
13C12-1234-TCBD 1.000 0.000 0% 20:21 0.822 5
13C12-HXCDD 789 1.000 0.000 0% 29:01 1.217 5
*** End of Report *»*
Page 2
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Caroina 27713
Phone: (919) 544-5729 • Fax (919) 544-5491
Printed: 13:05 04/30/97
272
-------
TRIANGLE LABORATORIES OF RTF, INC.
Initial Calibration Sumnary for PF22206
Data: 02/20/96
Analysis Data.
Instrument
.: 02/20/96
.: P
Mtcaod : C2NF
GC Column...: DB-225
Analytes
2378-TO3F
TOTAL TCDF
2378-TCDD
TOTAL TCDO
Otnar Standards
37C1-TCDD
RF SD %RSD
1.040 0.109 10*
1.040 0.109 10%
0.992 0.101 10%
0.992 0.101 10%
RT RT/LO RT/HI Ratiol Ratio2 N
21:32 14:31 25:31 0.767
0.767
20:12 16:11 24:11 0.782
0.782
RF SO
1.014 0.048
%RSD
5%
RT RT/LO RT/HI
20:12 18:11 22:11
Ratiol Ratio2
Internal Standards RF SO %RSO
13O2-2378-TCDP 1.388 0.062 4%
13C12-2378-TCDD 1.067 0.036 3%
Recovery Standards RF SD %RSD
13C12-1234-TCDD 1.000 0.000 0%
•»* End of Report ***
RT RT/LO
21:31 20:31
20:11 18:11
RT/HI
22:31
22:11
Ratiol
0.758
0.786
Ratio2
10
10
10
10
N
10
N
10
10
RT RT/LO RT/HI Ratiol Ratio2 N
20:27 0.794 10
Page
Triangi* Laboratories, Inc.® Analytical Services Division
801 Captota Drive • Durham, North Carafina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 23:10 02/20/96
070
-------
Date: 07/22/97 TRIANGLE LABORATORIES, INC.
Continuing Calibration for W972828
Analysis Date : 07/22/97 Method : M237
Operator : MM
Init Calibration. ; WF54307
ICal Data
: 04/30/97
Analyte Sunmary
Mama RF
Ratio
1&2
Total MCDF
Total TCDD
Total DCDF
Total DCDD
Total TriCDF
Total TriCDD
2378-TCDF
TOTAL TCDF
2378-TCDD
TOTAL TCDD
123 7 8 -PeCDF
23478-PeCDF
TOTAL PeCDF
12378-PeCDD
TOTAL PeCDD
123478-HxCDF
123678-axOJF
234678-HxCDF
123789-HxCDF
TOTAITHxCDF
123478-HXCDD
123678-HxCDD
0.
.000
0.000
0.
0.
0.
0.
1.
1.
1.
1.
1.
1.
1.
1.
1.
000
000
000
000
318
318
159
159
109
154
131
291
291
1.071
1.
1.
0.
453
101
934
0
0
0
0
1
1
.76
.76
.76
.76
.51
.51
Tnaf^njita
mt. . : W
Std.Conc
.
ICal
RT RT Rel. RT RF
Lo/Hign
0:01
13:51
0:42
14:42
6:51
14:51
7:42
15:42
10:51
17:51
12:42
18:42
16:15 19:52 1.0008
22:01
17:35 20:43 1.0008
22:01
21:58 24:18 1.0000
26:16
25:04 1.0316
1.51
1.59
1
1
1
1
.59
.27
.28
.26
1.28
1.J.4U i.Zf
0.845 1.23
1.
047
1.24
23:22 25:27 1.0000
26:08
3
3
0
2
1
1
1
1
1
1
1
1
1
.314
.691
.341
.072
.753
.860
.294
.294
.244
.244
.128
.122
.125
1.361
1.361
26:52 28:02 0.9970
29:37
28:08 1.0006
28:39 1.0190
29:22 1.0445
27:24 28:48 0.9977
29:18
28:52 1.0000
1.117
1.495
1.037
0.911
0.884
1.126
50.00
Delta
RF
-3.
-3.
.814
,691
-0.341
-2.
072
-1.753
-1.
0.
0.
-0.
-0.
-0.
0.
0.
-0.
-0.
-0.
360
024
024
085
085
019
032
006
070
070
046
-0.042
0.
0.
a:
-0.
-0.
064
023
%D
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
1.9%
1.9%
-6.9%
-6.9%
-1.7%
2.9%
0.6%
-5.2*
-5.2%
-4.2%
-Z.8% — —
6.2%
2.5%"
000 OTO% ~ -
039 -4.4%
079
-7.0%
Page
rriangto Laboratories, Inc.® Analytical Services Division
301 Capitals Drive • Durham, North CarofnaiZ7713
3hone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 13fl6 07/22/97
0-74
-------
Dace: 07/22/97
TRIANGLE LABORATORIES. INC.
Continuing Calibration for W972811
film AJ ^^»^ **«»».» . •
Operator
• MC
Init Calibration.: WF54307
ICal Data :
Analyte Simmary
Name
Total ICDF 0
Total MO3D 0
Total DCDP 0
Total DCDD 0
Total
Total
TriCDP
TriCDD
2378-TCDF
TOTAL
TCDF
2378-TCDD
TOTAL
TCDD
12378-PeCDF
23478-PeCDP
TOTAL
PeODF
12378-PeOJD
TOTAL
PeCDD
123478-HJeCDF
123678-HXCDF
234678-HxCDP
123789-fficCDF
1 TOTAL HxCDP"
123478-fficCDD
123678-HxCDD
0
Q
1
1
1
1
1
1
1
04/30/97
RF
.000
.000
.000
.000
.000
.000
.116
.116
.143
.143
.036
.119
.078
1.261
1
0
" 1
1
0
1
0
0
.261
.903
.424
.049
.909
ton~
.675
.981
Ratio
1&2
0.
0.
0.
0.
1.
1.
76
76
78
78
51
50
Instrument. . : W
Std.Conc. :
ICal
RT RT Rel. RT RF
Lo/High
0:01 3.814
13:52
0:42 3.691
14:42
6:52 0.841
14:52
7:42 2.072
15:42
10:52
17:52
12:42
18:42
15:52 19:52 1.0000
23:52
16:42 20:44 1.0016
24:42
20:18 24:18 1.0000
28:18
25:05 1.0322
1.51
1.
1.
1.
55
55
27
'1.28
1.28
1.28
-t.
1.
1.
10
23
23
21:27 25:28 1.0007
29:27
24:08 28:02 0.9964
32:08
28:08 1.0000
28:39 1.0184
29:22 1.0438
24:52 28:48 0.9977
32:52
28:53 1.0006
Page 1
1.753
1.860
1.294
1.294
1.244
1.244
1.128
1.122
1.125
1.361
1.361
1.117
1.495
1.037
0.911
ir 140-
0.884
1.126
50.00
Delta
RF
-3.814
-3.691
-0.841
-2.072
-1
.753
-1.860
-0
-0
-0
-0
-0
.178
.178
.101
.101
.092
-0.003
-0
-0
-0
-0
.047
.100
.100
.214
-0.071
0
.012
%D
100
100
100
100
100
.0»~
.0%
.0%
.0%
.0%
100.0%
-13
-13
-8
-8
.8%
.3%
.1%"
.1%
-8.2%
-0
-4
.3%
- *•.
.2%
-7.3*°
-7.3%
-19
-4
.2%
.7%- -
1.1%
-0.002 -0.2% ' " ~~"
-0.209 -23.6%
-0
.145
-12
.9%'
.-,
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 00:13 07/22/97
-------
Date: 07/23/97 TRIANGLE LABORATORIES OF RTF, IBC.
Continuing Calibration for P973363
Analysis Date : 07/23/97 Method : C2HF
: WK
Operator
Init Calibration.: PP22206
ICal Date : 02/20/96
Analysis Tine : 15 :43
Instrument..: P
Std.Conc : 5.00
GC ColUBB...: DB-22S
Analyte Summary ICal Delta
Hame RF Ratio RT RT Rel. RT RF RF %D
142 Lo/High
2378-TCDF 0.961 0.73 16:27 20:55 1.0008 1.040 -0.079 -7.6%
22:58
1.040 -0.079 -7.6%
TOTAL TCDF
2378-TCDD
TOTAL TCDD
0.961 0.73
1.047 0.75
1.047 0.75
17:17 19:42 1.0008 0.992 0.055 5.6%
22:19
0.992 0.055 5.6%
Other Standard Summary
Hame RF Ratio
162
37C1-TCDD 0.934
ICal Delta
RT RT Rel. RT BF RF %D
Lo/High
17:41 19:42 1.0008 1.014 -0.080 -7.9%
21:41
Internal Standard summary
Hame RF Ratio
1S2
13C12-2378-TCDF 1.328 0.78
13C12-2378-TCDD 1.079 0.80
ICal Delta
RT RT Rel. RT RF RF %D
Lo/High
19:54 20:54 1.0000 1.388 -0.060 -4.4%
21:54
17:41 19:41 1.0000 1.067 0.012 1.1%
21:41
Recovery Standard Summary
Name RF Ratio
Ifi2
13C12-1234-TCDD 1.000 0.82.
ICal Delta
RT RT Rel. RT RF RF %D
Lo/High
19:56 1.0127...1.000 0.000 0.0%.
Page
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-6729 • Fax: (919) 544-5491
Printed: 18:02 07/23/97
276
-------
Appendix B
Method 23 Analytical Data for PAHs
cah/K \7997\03\07-RPT\APX-CVR WPS
-------
CASE NARRATIVE
Analysis of Samples for the Presence of
Semivolatile Analytes by
High-Resolution Gas Chromatography / Low-Resolution Mass Spectrometry
METHOD 8270A Rev. 1 (7/92)
Date:
August 29, 1997
Client ID :
Eastern Research Group
TLI Project Number : 42299Bn 1
This report should only be reproduced in full. Any partial reproduction of this report requires permission from
Triangle Laboratories, Inc.
Triangle Laboratories, Inc.
801 Capitola Drive P.O. Box 13485
Durham, NC 27713-4411 Research Triangle Park, NC 27709-3485
919-544-5729 Fax #919-544-5491
I-
-------
TRIANGLE LABORATORIES, INC. August 29,1997
CASE NARRATIVE 42299Bnl
Objective: Analysis of three MM5 train samples for polycyclic aromatic hydrocarbon
semivolatile compounds, using Method 8270A.
Method:
Five MM5 train samples and one proof blank were received by Triangle Laboratories, Inc. on ice
at 4°C and in good condition on July 1, 1997. The impinger rinse for rinse blank (M23-Outlet-
RB1) was listed on the chain of custody but did not arrive with the samples. Results for the field
blank and rinse blank are not included in this data package. The proof blank was placed on hold
and was not analyzed at this time as per the instructions from the client. The samples were stored
in a cooler at 4°C prior to extraction. The samples were extracted according to procedures
described in the Triangle Laboratories Data User's Manual "Modified Carb Method 429: High
Resolution Mass Spectrometry; Stack Emission Samples" (rev. 11/92-HK-4-AH-2/93). The
extracts were first analyzed using high resolution mass Spectrometry resulting in saturated levels
of several target analytes. The extracts were then analyzed according to the guidelines of Method
8270A Rev. 1 (7/92). The results reported relate only to the items tested.
The internal standards, naphthalene-dg, acenaphthene-dio, phenanthrene-dio, chrysene-di2, and
perylene-di2, were added to the extracts such that the final internal standard concentration was 40
ug/mL immediately prior to analysis by GC/MS.
The GC/MS analysis conditions are listed below:
GC Conditions:
Column: J&W DB5-625, 30m x .32mm x Iwm
Program: 35C, ramp at 12C/min to 285C, hold for 2 min.
ramp at 8.5C/min to 315 C, hold for 6.5 min.
Carrier Gas: Helium
MS Conditions:
Instrument: HP MSD, Chemsystem and Target data systems
Scan: 35-550 amu at 1.67 scan/sec
Interface: Capillary, Injector: 250C, Detector: 275C
Report:
Enclosed with the case narrative are the sample identification index, project summary sheets,
client and TLI chain of custody sheets, wet laboratory extraction information sheets, GC/MS
tracking forms, and analytical run logs. The sample identification index correlates the client
sample name, TLI sample number and the analytical file name for the each sample. The project
summary sheets list the amounts of analytes detected in gray and list the estimated detection limits
in parentheses for analytes which were not detected.
The data are reported as quantitation reports, chromatograms, interim reports, and spectra of
detected target analytes. The quantitation report header lists the TLI project number, analysis
-------
TRIANGLE LABORATORIES, INC. August 29,1997
CASE NARRATIVE 42299Bnl
method, instrument sample file name, and client sample name. The client project number, TLI
sample number, calibration file, dilution factor, and date received, extracted, and analyzed are also
listed in the quantitation report header. The response factors used for all calculations are from the
continuing calibration listed in the header. All initial and continuing calibration data are located in
the back of the data package. The amount reported for each target analyte detected in the
samples is reported in total ug. The retention time (RT) will be listed for all internal standards
and analytes which are detected. If a target analyte is not detected, it will be flagged with a "U"
and a detection limit will be listed. Estimated detection limits are calculated using an area of
10,000 for all analytes which were not found in the samples. The estimated detection limits
reported are the average detection limits achievable over time on an instrument type. The actual
detection limit for a given compound on a given day may vary from the estimate reported. The
quantitation limit for all analytes is half of the low point of the initial calibration adjusted for
dilution when appropriate. Below this point the calibration cannot be considered to be linear.
Any amounts reported at a level below the quantitation limit will be flagged with a "J" and should
be considered estimated. If a target analyte is found at a level exceeding the upper calibration
limit, it will be flagged with an "E" and should also be considered estimated. Any analytes flagged
with a "B" on the sample topsheets were detected in the associated laboratory blank. All target
analytes are quantitated against the internal standard preceding them on the target analyte list. If
an internal standard area is above or below the quality control limits as defined by the continuing
calibration, it will be flagged with "High" or "Low" in the flag column.
Immediately following the quantitation report are two pages which comprise the total ion chro-
matograms. Labeled internal and surrogate standards present in the sample have their identifica-
tions and retention time printed above their peak on the chromatogram. The chromatogram is
followed by the interim report. On the interim report a $ is indicative of a surrogate standard and
a * represents an internal standard. The interim report from the instrument is followed by the
target spectra of detected compounds. Four spectral plots are included for each compound: a raw
spectrum of the peak, a background subtracted version of the same spectrum, a library spectrum
of the compound, and a plot showing the percent difference between the library spectrum and the
background subtracted spectrum. Extracted ion current profiles are plotted on the right-hand side
of the page showing the quantitation mass and one or two other prominent ions known to be
present in target compound as they appear in the sample peak.
Results:
The samples were extracted outside the fourteen day sampling to extraction holding time and
analyzed within the extraction to analysis holding time.
The extracts were brought to a final volume of 0.2 milliliters (mL). Extracts prepared for analysis
by Method 8270A are normally brought to a final volume of 1.0 mL. The "concentration factor"
applicable to these samples is taken into account on the quantitation reports as a dilution factor of
0.2. Each of the extracts was also diluted immediately prior to the analyses to lessen
chromatographic interferences and to bring target analyte results within the calibration range. This
was also accounted for by the application of dilution factors. [For example, an extract
"concentration factor" of 0.2 and a twenty-fold dilution at the instrument results in a "dilution
factor" of four (0.2 x 20 = 4) for the sample.]
O
-------
TRIANGLE LABORATORIES, INC. August 29,1997
CASE NARRATIVE 42299Bnl
The samples were spiked prior to extraction with some labelled internal standards that were again
spiked into the extracts immediately prior to analysis by low resolution mass spectrometry. The
levels of labelled internal standards spiked for the high resolution mass spectrometry analysis were
insignificant relative to those levels spiked for the low resolution analysis. Only the internal
standards spiked just prior to analysis by low resolution mass spectrometry were accounted for in
the quantitations.
Please note that naphthalene was found at a level below the quantitation limit in the laboratory
blank. This analyte should not be considered truly present in the native samples unless detected at
a level at least five times the level in the blank. If the analyte level in the sample is twenty times
the level in the blank, the blank contribution can be considered statistically insignificant.
Naphthalene, 2-methylnaphthalene, and phenanthrene were found at levels above the upper
calibration limit in the field samples. These analytes are flagged with an "E" and the
concentrations reported should be considered estimated. These samples were further diluted in
order to bring these concentrations within the linear calibration range of the instrument. Both sets
of diluted analyses are reported. Only "E" flagged target analyte results should be taken from the
more highly diluted analyses, while all other results should be taken from the less diluted analyses.
All internal standard areas were within Method 8270 quality control criteria.
The samples were not spiked with the surrogate standards normally utilized for analyses by
Method 8270A, therefore, no indication of extraction efficiency is available for these samples.
Sample Calculations:
Response Factor, RF = Area analyte x Amt Is
Area IS x Amt analyte in the ccal
Amount ug = Area analyte x Amt IS x DF
Area IS x RF
Where:
Amt IS = amount of internal standard = 40 ug
Amt analyte in the ccal = amount of analyte in the continuing calibration = 50 ug
DF = dilution factor
-------
TRIANGLE LABORATORIES, INC. August 29, 1997
CASE NARRATIVE 42299Bnl
The data reported has been judged to be valid and in compliance with the guidelines of Method
8270A Rev. 1 (7/92) except as noted above. Should you have any questions about this project,
please feel free to contact our Project Scientist, Amy Boehm, at (919) 544-5729, ext. 268.
For Triangle Laboratories, Inc.,
Report Preparation: Quality Control:
(TA
Penny A. Brock Sarah A. Hubbard
Report Preparation Chemist Report Preparation Chemist
The total number of pages in this data package is
-------
Triangle Laboratories of RTF
Sample Identification Index for Project: 42299Bnl
Client I& ¥P1&
M23-OUTLET-RUN1 O-HO* 173-61-1A-D VG137
M23-OUTLET-RUN1 Sx 173-61-1A-D VG141
M23-OUTLET-RUN 2 O.'/O* 173-61-2A-D VG142
M23-OUTLET-RUN 2 4* 173-61-2A-D VG139
M23-OUTLET-RUN 3 O.^O* 173-61-3 A-D VG143
M23-OUTLET-RUN 3 4* 173-61-3A-D VG140
TLI BLANK 071797 TLI BLANK 071?'?!- VG136
Triangle Laboratories of RTF, Inc Proj_Sum v4.0
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
-------
Triangle Laboratories of RTP
Project Summary for Project 42299Bnl
Client ID:
Filename :
TLIId :
Matrix :
Units :
Naphthalene
2-Methylnaphthalene
2-Chloronaphthalene
Acenaphthylene
Acenaphthene
Fluorene
Phenanthrene
Anthracene
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Benzo(e)pyrene
Benzo(a)pyrene
Perylene
Indeno(l,2,3-cd)pyrene
Dibenz(a,h)anthracene
Benzo(g,h,i)perylene
M23-OUTLET M23-OUTLET
-RUN 1 -RUN 1
o.Hor. 8x
VG137 VG141
173-61-1A-D 173-61-1A-D
MM5 MM5
ug ug
220.50
imsa
(0.16)
"": 3£24 -
13.69 1
22.39 i
1&3.39 ;
7,30
33,01
. A-*' - 13.72 1
:•:<;•• ••• 2.30
6.29 ;
:'- ." &S» i
0,94 j
• •••*•; • 3.ffl
1.01
(0.18)
1.0ft
... . 0.45
. • -W»
322,91
124£2
(3.47)
38,85
15,56
24,91
188-98
7.69
31,41
14,47
(2.66)
6.$4
4.90
1.33
(3.66)
(3.33)
(3.90)
(3.03)
(3.87)
(3.57)
M23-OUTLET
-RUN 2
o.fo*
VG142
173-61-2A-D
MM5
ug
245,96
132.58
(0.16)
36.56
16.04
22,93
153.06
8.94
35.23
1482
2>62
5.S9
&.4S
1.02
3.50
116
0,30
1.09
0.40
1S5
M23-OUTLET
-RUN 2
M y
VG139
173-61-2A-D
MM5
ug
381,63
134.84
(1.84)
41,82
16.86
26.22
195-98
7.73
31.39
14.61
(1.39)
6.30
5.94
(1.66)
3.54
(1.75)
(2.06)
1,31
(2.04)
1,75
M23-OUTLET
-RUN 3
O.'iOX
VG143
1 73-61-3 A-D
MM5
"g
211,52
108.&5
(0.16)
25.14
13.38
18.12
130.25
7.97
25,86
1044
1.77
4,06
3.63
0.64 ;
2.47
0.80
0.26
0,91
0.39
1-27
M23-OUTLET
-RUN 3
VG140
173-61-3A-D
MM5
ug
293.68
108.86
(1.79)
27^4
13.84
20.27
188.87
7.87
2336
: 1040
(1.35)
4v27
3.67
OJ&4
: 2J6
(1.72)
(2.01)
(1.56)
(2.00)
(1.84)
TL1 BLANK
071797
VG136
TLI BLANK 07
XAD
0.89
(0.07)
(0.08)
(0.04)
(0.08)
(0.07)
(0.05)
(0.05)
(0.05)
(0.05)
(0.06)
(0.07)
(0.07)
(0.07)
(0.09)
(0.08)
(0.09)
(0.07)
(0.09)
(0.08)
l "
Triangle Laboratories of RTP, Inc.
801 Capitola Drive • Durham, North Carolina 27713
Phone: (9,19) 544-5729 • Fax: (919) 544-5491
( (-Estimated Detection Limit
Page 1
Savar v3.5
Printed: 14:43:21 08/29/97
-------
CO
LTV STEEL COMPANY
CHAIN OF CUSTODY
RELINQUISHED BY = (I\
RELINQUISHED BY =
L - 6
DATE'
DATE'
i,
RECEIVED BY:
RECEIVED BY:
DATE:.
DATE:
SAMPLE ID
LTV-98
LTv-ea-^
LTV-68--
LTV-73X'
LTV-78 ^
LTV-83
LTV-64 •"
LTV-69 S
LTV-74
LTV-79
LTV-84
LTV-66 ^
LTV-71 ""
LTV-76 ^
LTV-81 \/
LTV-86
LTV-65 •"
LTV-70 -"
LTV-75 '"
LTV-80L-
LTV-85
LTV-67 -
LTV-72 x
LTV-77 "•
LTV-82— -
LTV-87
FIELD ID
LTV- 062597- M23- OUTLET- MeCI2- PB
LTV- 062-197- M23- OUTLET- PR- 1
LTV- 062697- M23- OUTLET- PR- 2
LTV- 062797- M23- OUTLET- PR- 3
LTV- 062697- M23- OUTLET- PR- FBI
LTV- 062497- M23- OUTLET- PR- RB1
LTV- 062497- M23- OUTLET- PRT/CRT- 1
LTV- 062697- M23- OUTLET- PRT/CRT- 2
LTV- 062797- M23- OUTLET- PRT/CRT- 3
LTV- 062697- M23- OUTLET- PRT/CRT- FBI
LTV- 062497- . M23- OUTLET- PRT/CRT- RBI
LTV- 062497- M23- OUTLET- XAD- 1
LTV- 062697- M23- OUTLET- XAD- 2
LTV- 062797- M23- OUTLET- XAO- 3
LTV- 062697- M23- OUTLET- XAD- FBI
LTV- 062497- M23- OUTLET- XAD- RB1
LTV- 062497- M23- OUTLET- F- 1
LTV- 062697- M23- OUTLET- F- 2
LTV- 062797- M23- OUTLET- F- 3
LTV- 062697- M23- OUTLET- F- FBI
LTV- 062497- M23- OUTLET- F- RBI
LTV- 062497- M23- OUTLET- IMP- 1
LTV- 062697- M23- OUTLET- IMP- 2
LTV- 062797- M23- OUTLET- IMP- 3
LTV- 062697- M23- OUTLET- IMP- FB1
LTV- 062497- M23- OUTLET- IMP- RB1
SAM RLE TYPE
METHOD 23, INLET, PROOF BLANK
METHOD 23, OUTLET, RUN 1
METHOD 23, OUTLET, RUN 2
METHOD 23, OUTLET, RUN 3
METHOD 23, OUTLET, FB 1
METHOD 23, OUTLET, RB 1
METHOD 23, OUTLET, RUN 1
METHOD 23, OUTLET, RUN 2
METHOD 23, OUTLET, RUN 3
METHOD 23, OUTLET, FB 1
METHOD 23, OUTLET, RB 1
METHOD 23, OUTLET, RUN 1
METHOD 23, OUTLET, RUN 2
METHOD 23, OUTLET, RUN 3
METHOD 23, OUTLET. FB 1
METHOD 23, OUTLET, RB 1
METHOD 23, OUTLET, RUN 1
METHOD 23, OUTLET, RUN 2
METHOD 23, OUTLET, RUN 3
METHOD 23, OUTLET, FB 1
METHOD 23, OUTLET, RB 1
METHOD 23, OUTLET, RUN 1
METHOD 23, OUTLET, RUN 2
METHOD 23, OUTLET, RUN 3
METHOD 23, OUTLET, FB 1
METHOD 23, OUTLET, RB 1
PRESERVATIVE
MeCI2 Rinse
MeCI2/Acetone Probe Rinse
MeCI2/Acetone Probe Rinse
MeCI2/Acetone Probe Rinse
MeCI2/Acetone Probe Rinse
MeCI2/Acetone Probe Rinse
Toluene Probe Rinse
Toluene Probe Rinse
Toluene Probe Rinse
Toluene Probe Rinse
Toluene Probe Rinse
XAD Trap
XAD Trap
XAD Trap
XAD Trap
XAD Trap
Filter
Filler
Filter
Filter
Filter
Impingers and Rinses
Impingers and Rinses
Impingers and Rinses
Impingers and Rinses
Impingers and Rinses
COMMENTS
\V\i
ANALYSIS
•BiiHlim/PAM
DioxIns/PAH
Dioxins/PAH
Dioxins/PAH
DioxIns/PAH
Dioxins/PAH
Dioxins/PAH
Dioxins/PAH
Dioxins/PAH
Dioxins/PAH
Oioxins/PAH
Dioxins/PAH
Dioxins/PAH
Dioxins/PAH
Dioxins/PAH
Dioxins/PAH
Dioxins/PAH
Dioxins/PAH
Dioxins/PAH
Dioxins/PAH
Dioxins/PAH
Dioxins/PAH
Dioxins/PAH
Dioxins/PAH
Dioxins/PAH
Dioxins/PAH
Page 8
-------
II
n
n
D
n
1
Custody Seal
Chain of Custody
Sample Tags :
Sample Tag Numbers:
SMO Forms :
Ice Chest
Absent
Present
Absent
Not Listed
N/A
Sample Seals: Absent
Container...: Intact
on Chain of Custody
ICE/ICE PACKS Temp 4.0 C
TLI Project Number 42299
Client: ERG02 - Eastern Research Group
X>i -
Date Received
Carrier and Number
j 07/01/97 | By (j[W/ty^
| JIM QAUGHEY ^
Book 1
1
173
Page
61
HTH Number Client Sample ID Matrix] To LA]
IJmR/H'CPM Client COC ID • Location | Date/
HI
B TO STORAGE] TO LAB
Init 1 Date/Init j Date/Init
i
r^J~*
R173-61-1A LTV-65 FILTER) J-fcj-
J LTV-6S CO! jYl7//H
IJ173-61-1B LTV-66 XADJ
H LTV-66 C01 j
(173-61-1C LTV-63 ACE/MECL2|
jj LTV-63 C01 1
II 1
(173-61-1D LTV-67 IMPIR1NSB)
1) LTV-67 C01 |
n
|)173-61-1E LTV-64 TOLUENE)
I) LTV-64 C01 j
n i
|173-61-2A LTV-70 FILTER)
|| LTV-70 C01 |
|i . . .
fll73-6l-2B LTV-71 XAD)
(I -, LTV-71 C01 |
II ' 1
||173-61-2C LTV-68 ACE/MBCL2|
II LTV-6B C01 j
II 1
|)173-61-2D LTV-72 IHP&RINSB)
IJ • LTV-72 C01 j
II 1
(173-61-2E LTV-69 ' TOLUENE)
I) LTV-69 C01 |
I) ... .. j
||173-61-3A LTV-75 FILTER)
I LTV-75 C01 j
1 1
||173-61-3B LTV-76 XAD)
I) . LTV-76 C01 |
||173-61-3C LTV-73 ACE/MECL2 1
II LTV-73 C01 1
||173-61-3D LTV-77 IMPSJUNSE|
I) LTV-77 C01 |
•/
i/
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( n^ejy !
J
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1
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jt/7/^i 5|^lWj
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|| Receiving Remarks! »
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TO STORAGE]
Date/Init
>AAuA
UAW-*1
To LAB
Date/Init
I
TO STORAGE]
Date/Init
•
To LAB
Date/Init
— '
To STORAGE
Date/Init
DISPOSED
Date/Init
- — •
\
'Form Revised 05/27/1997 -- Page 1 OF 2-
-------
|| Custody Seal : Absent
|| Chain of Custody : Present
|| Sample Tags : Absent
|| Sample Tag Numbers: Not Listed on Chain of Custody
jj SMO Forms : N/A
=TRIANGL,E LABORATORIES, INC. -- LOG IN RECORD/CHAIN OF CUSTODY=
Sample Seals: Absent
Container...; Intact
TLI Project Number 42299
Client: ERQ02 - Eastern Research Group
Date Received
| 07/01/97 | By
H Ice Chest
ICE/ICE PACKS Temp 4.0 C
Carrier and Number | JIM OAUGHEY
||TLI Number Client Sample ID. Matrix
||mR/H:CPM. . .. Client COC ID. .* Location
II
||173-S1-3E 1.TV-74 TOLUF.NE
jj LTV- 74 C01
II
((173-61-4A LTV-80 FILTER
|| LTV-80 C01
(173-61-4B LTV-B1 XAD
jj LTV-81 C01
B173-61-4C LTV-78 ACE/MECL2
jj LTV-78 C01
jf- - - - -.-.......
||173-61-4D LTV-82 IMPSRINSE
I) LTV-82 C01
||173-61-4E LTV-79 TOLUENE
jj LTV-79 C01
||173-S1-SA LTV-85 FILTER
Jl LTV-85 C01
||173-61-5B LTV-86 XAD
jj LTV-86 C01
||173-61-5C LTV-98 MECL2
jj ' LTV-98 C01
| .......... . .
||173-61-SD LTV-84 ' TOLUENE
(I LTV-84 C01
II
n
1) . - . ... . --
II
II
II
II
II
II
To LAB
Date/Init
iM
Vl/97
.
N
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To STORAGE | To LAB
Date/Init Date/Init
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i 7
-------
PAGE 1 OF 1
Project: 42299B
TRIANGLE LABORATORIES, INC.
Sample Preparation Tracking & Management Form
Client: Eastern Research Group (ERG02)
Method:
Solvent/Acids ):
VkjJti
Sample Information
Extraction Date: ° 7 1 ±L/ 5l
Lot:
I
I TLI /
ample] SAMPLE ID / CLIENT
crd / SAMPLE ID
i I i
| Sample | Final |
|Wgt /
| g / ml | ml
i
\ « '-^7 |
/ _ / _ 1 _ / _ / _ 1 _ / _ / _ 1
TLI 31 rink
\
JO |
TLI Method Blank
\
| 173-ol-IA-D j I
11 | M23-Outlet-Run 1 | I M*
[ 173-61-2A-D
'2 I M23-Outlet-Run 2
| 173-61-3A-D
3 I M23-Outlet-Run 3
&
| 173-61-4A-D
M23-Outlet-RBl
1 / i "i
I6i
TLI LCS
TLI LCS
i
| TLI LCi'D
S \
I
TLI LCSD |
|o-a|
RJ-
ll
II
II
II
I
II
II
II
II
II
II
!
-REV 07/26/93 (PSTMF 7)--+
li
-------
OF :RTS>
SAMPLE EXTRACTION AND CLZANU? TRACKING FORM
ORGANIC WET EAB
TLI-RT? PRCJZCT NUMBER:.
Sansie No.
Step Number and Description
Inital Da-
ater Bath Temperature
atal Hours: "'
ounents:
-------
Date: 07/17/97
Time: 18:47
Sample
8 crd TLI_Number.. Customer.Sample.Id
000 TLI Blank TLI Method Blank
001 173-61-1A-D M23-Outlet-Run 1
002 173-61-2A-D M23-Outlet-Run 2
OOJ 173 61 1A I) M23-Outlet-Run 3
004 173-61-4A-D& M23-Outlet-RBl
005 TLI LCS TLI LCS
006 TLI LCSD TLI LCSD
*** End of Report ***
TRIANGLE LABORATORIES, INC
Wet Lab MM5/PUF Observations
Project: 42299-B
PRDPERC V3.19
Page: 1
0-5
F.
No
1
1
1
1
XAD
Color
WHITE
YELLOW/WHI
YELLOW/WHI
YELLOW/WHI
WHITE
WHITE
WHITE
Filter
Color. . .
BROWN
BROWN
BROWN
WHITE
Glass Wool PUF
. . Color. . . Color
YELLOW
YELLOW
YELLOW
WHITE
Odor
NONE
SMOKE
SMOKE
SMOKE
NONE
NONE
NONE
Air
Q.No.
03710
03710
03710
03710
03710
GU
GU
GU
GU
GU
GU
GU
Date.... Time..
07/17 18:43 F
07/17 18:43 F
07/17 18:43 F
07/17 18:43 F
07/17 18:43 F
07/17 18:46 F
07/17 18:46 F
. S
-------
Date: 07/22/97
Time: 13:10
Sample
0 crd TLI_Number.. Customer.Sample.Id.
000 TL1 Blank TLI Method Blank
001 173-61-1A-D M23-Outlet-Run 1
002 173-61-2A-D M23-Outlet-Run 2
003 173-61-3A-D M23-Outlet-Run 3
004 173-61-4A-D& M23-Outlet-RBl
TRIANGLE LABORATORIES, INC.
Wet Lab Extraction and Observations
Project: 42299-B
Init. NaOH Adj. H2S04 Adj.
pH... mL.. pH.l. mL... pH.2. Appearance. Color Odor... Vol. Entered.By.
7.00 n/a n/a n/a n/a
4.00 0.2 8.00 n/a n/a
4.00 0.1 9.00 n/a n/a
4.00 0.1 9.00 n/a n/a
2.00 0.2 8.00 n/a n/a
HPLC WATER COLORLESS NONE 600 SZULC
CLEAR COLORLESS NONE 500 SZULC
CLEAR COLORLESS NONE 540 SZULC
CLEAR COLORLESS NONE 500 SZULC
CLEAR COLORLESS NONE 200 SZULC
PRDPERC V3.19
Page: 1
Date.... Time.... S
07/22/97 13:08:12 F
07/22/97 13:08:12 F
07/22/97 13:08:12 F
07/22/97 13:08:12 F
07/22/97 13:08:12 F
*** End of Report ***
-------
Field ID'.
Client'.
vocation'.
v Date:
Comments
."*. TareWt:
J-
Final W
> r
03710
HR G. L .
ERG02
ERG02-Eastern Research Group
LTV-76
.„_
J^OJECT# '^37 10
4.0ng usf-c ,i usf-s
lOOng ?ah-hrrns
ERG02-Eastern Research Group
' LTV-81
ERG02-Eastern Research Group
LTV-80 P
Sample ID:
Field ID:
Sample Type:
Client: _/-o,tt-
Location:
Preservative:'
Sampler:
Date:
Comments
Tare Wt:
er
XA01
Final Wt:
15
-------
Triangle Laboratories, inc
TLI PROJECT* 03710
DATE 6/19/97 TLI BLAflK
SPIKE 4.0ng usf-c & usf-s
spike lOOng pah-hrms
SPIKER \M/1
ERG02
PREPARER G.L.
ERG02-Eastern Research Group
LTV-66
R r-o j ©dr. : -4-2299
-| 7 3—S 1 — 1 B
cpnn?-Fastern Research Group LTV-CB
LTV-6 5 „ LTV- CtcZ^W -M23-OUTLET-XAD-1
' »"~ O J © O "t = -4-229 9ple Type: METHOD 23. OUTLET, RUN 1
173 — ©1— 1*
Sample ID. LTV-71
f'dl(D' LTV, -M23-~,TLET-XAD-2
Sample Type- METHOD 23 • '••'
Client: gp^
Location. CHICAGO-
Preser.jflve. XAD Trap
Sampler JLSWIFT
Date:
Comments
~-'e We f
,iient:
Location:
Preserviive:
Sampler.
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CHICAGO, IL
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Triangle.
TLI.1 PROJECTS*
.DATE'6/19/97
Inc.
usf-s
ERG02-Eastern Research Group
LTV-70
»r-oj^o't. : 4-2299
1 73 — 61 —2A
16
-------
PAGE 1 OF 1
TRIANGLE LABORATORIES, INC.
Transfer Chain-of-Custody Form
Project 42299-B
Transfer From: OWLS5 To: DMS5
Initials. . Date Time,
Released by:
Accepted by:
MILES.ID,
42299-B
42299-B
42299-B
42299-B
42299-B
42299-B
42299-B
-000
-001
-002
-003
-004
-005
-006
TLI No,
Cust.Id.
TLI Blank
173-61-1A-D
173-61-2A-D
173-61-3A-D
173-61-4A-D&
TLI LCS
TLI LCSD
TLI Method Blank
M23-Outlet-Run 1
M23-Outlet-Run 2
M23-Outlet-Run 3
M23-Outlet-RBI
TLI LCS
TLI LCSD
Additional comments or instructions:
•XfrCOC (Rev 11/01/94)--+
-------
SEMIVOLATILE GC/MS TRACKING FORM
TL-RTP Project #:
MATRIX: MM§ PUF Water Soil Other
METHOD: (g27o) 625 CLP
ANALYTELIST: Table 2 TCLP 625 CLP CAA/PAP
ICALName: ICAL \JLp\ll _
Other
Time
TLFfTP O
Sample ipi-::!r
J- : File Name:
Ioi4
DFTPP
\0i\0
SSTD050
Hi i
Vtj
1451
Kg-OUTLET EM5
3QS6
v/6154
Hi
Dun r-
tnlu-Ud Zo<
iZDZ.
-OUTLET-
173 - IP( SA-D
175- Lcl
ZA-d>
ML
V
173 •
TRIANGLE LABORATORIES OF RTP, INC.
SOP No. OMS130
Revision 3.0
12 January 1994
page 9 of 10 10
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Run Log
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W jklii
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GO 4
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s"
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urrogate / Recovery
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42&2Z
tl-
ML- PBigidSL- V2, Wxau
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JBB.
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TRIANGLE LABORATORIES, INC.
LIST OF CERTIFICATIONS AND ACCREDITATIONS
ENVIRONMENTAL
American Association for Laboratory Accreditation. Expires July 31. 1997. Certificate
Number 0226-01. Accreditation for technical competence in Environmental Testing.(lncluding
Waste Water, Sol/Haz Waste, Pulp/Paper, and Air Matrices) Parameters are AOX/TOX,
Voiatiles, Pesticides, PCB's. BNA's, and Dioxin/Furan. Method 1613 for Drinking Water.
State of Alabama, Department of Environmental Management. Expires December 31,
1997. Laboratory I.D. # 40950. Dioxin in drinking water.
State of Alaska, Department of Environmental Conservation. Expires December 21, 1997.
Certificate number OS-00397. Dioxin in drinking water.
State of Arizona, Department of Health Services. Expires May 26. 1998. Certificate
#AZ0423. Drinking Water for Dioxin, Dioxin in WW and S/H Waste.
State of Arkansas, Department of Pollution Control and Ecology. Expires February 18,
1998. Pulp/paper, soil, water, and Hazardous Waste for Dioxin/Furan; AOX/TOX.
State of California, Department of Health Services. Expires August 31. 1997. Certificate
#1922. Selected Metals in Waste Water; Voiatiles, Semi-volatiles, and Dioxin/furan in WW and
Sol/Haz Waste. Dioxin in drinking water.
State of Connecticut, Department of Health Services. Expires September 30, 1997.
Registration # PH-0117. Dioxin in drinking water.
Delaware Health and Social Services. Expires December 31, 1997. Certificate #NC 140.
Dioxin in drinking water.
Rorida Department of Health and Rehabilitative Services. Expires June 30, 1997.Dioxin in
DW. Drinking Water ID HRS# 87424. Metals, Extractable Organics (GC/MS), Pesticides/PCB's
(GC) and Voiatiles (GC/MS) in Environmental Samples. Environmental water ID HRS#
E87411.
Triangle Laboratories, Inc.
801 Cap/fo/a Drive P.O. Box 13485
Durham, NC 27713-4411 Research Triangle Park, NC 27709-3485
919-544-5729 Fax # 919-544-5491
-------
Hawaii Department of Health. Expires March 1, 1998. Dioxin in drinking water. "Accepted"
status for regulatory purposes .
Idaho Department of Health and Welfare. Expires November 30, 1997. Dioxin in drinking
water.
State of Kansas, Department of Health and Environment. Expires January 31, 1998.
Environmental Anaiyses/Non potable Water and Solid and Hazardous Waste. Method 1613
for drinking water. ID #'s - Drinking water and/or pollution control - E-215. Solid or Hazardous
Waste-E-1209.
Commonwealth of Kentucky, Department for Environmental Protection. Expires
December 31. 1997. ID#90060. Dioxin in drinking water.
Maryland Department of Health and Mental Hygiene. Expires September 30, 1997.
Certification #235. Drinking water by Method 1613A.
State of Michigan, Department of Public Health. Expires March 31, 1997. Drinking water by
Method 1613.
Mississippi State Department of Health. No expiration date.. Dioxin in drinking water.
Montana Department of Health and Environmental Services. Expires December 31, 1997.
Dioxin in drinking water.
State of New Jersey, Department of Environmental Protection and Energy. Extended by
state. Temporary certificate until June 30, 1997 or sooner. ID #67851. BNAs and Volatiles.
Dioxin in drinking water.
State of New Mexico, Environment Department. Expires July 31, 1997. Dioxin in drinking
water.
New York State Department of Health. Expires June 30, 1997. ID #11026. Environmental
Analyses of non-potable Water, Solid and Hazardous Waste. Method 1613 in DW.
State of North Carolina, Department of Environment Health and Natural Resources
Expires December 31, 1997. Certificate # 37751. Dioxin in drinking water.
State of North Carolina, Department of Environment, Health, and Natural Resources,
Division of Environmental Management. Expires December 31, 1997. Certificate # 485.
Metals, pesticides & PCBs, semi-volatiles and volatiles; TCLP.
North Dakota State Department of Health and Consolidated Laboratories. Expires
December 31,1997. Certificate # R-076. Effective October 4, 1993. Dioxin in drinking water.
Revised 6/26/97 ;m
Printed W6/97
-------
Oklahoma Department of Environmental Quality. Expires October 31, 1997. Laboratory
#9612. Dioxin by 1613A. 8290 and 8280.
State of South Carolina, Department of Health and Environmental Control. Expires June
30. 1997. Certificate number #99040001 (drinking water). Expires August 31, 1997. Certificate
number #99040002 (other parameters). Dioxin/Furans, BNA, Volatiles, and PCBs/pesticides
under Clean Water Act, 2,3.7,8-TCDD for Drinking Water, and Organic extractables for Solid
and Hazardous Waste.
State of Tennessee. Department of Environment and Conservation. Expires February 5,
1999. ID #02992. Method 1613 Drinking water only.
U.S. Department of Agriculture Soil Permit. Expires September 30, 2002. Permit No. S-
4958. Under the authority of the Federal Plant Pest Act, permission is granted to receive
foreign soil samples for use in laboratory analysis.
U.S. Army Corps of Engineers. Expires November 30, 1997. Validated to perform methods
8280 & 8290 for Lockboume Landfill Site Investigation, Defense Distribution Depot Projects,
and assorted projects for the USAGE North Pacific Division Laboratory.
U.S. EPA Region V. Expires November 14, 1999. Dioxin in drinking water.
U.S. EPA Region VIII, for the State of Wyoming. Expires November 13, 1997. Dioxin in
drinking water.
State of Utah, Department of Health. Expires December 31, 1997. Certificate Number E-
166. Certification for the following parameters: Semi-Volatiles and Volatiles under RCRA;
Volatiles under Clean Water Act; Dioxin/furans by Method 8280; Drinking water for Dioxin by
Method 1613; Metals including Mercury and Microwave Digestion.
Commonwealth of Virginia, Department of General Services, Division of Consolidated
Laboratory Services. Expires June 30, 1998. ID # 00341. Dioxin in drinking water.
State of Washington, Department of Ecology. Expires September 11, 1997. Lab
Accreditation Number C067. Scope of Accreditation applies to water analyses for
Polychlorinated Dibenzo-p-dioxins and Polychlorinated Dibenzofurans, BNA Extr (Semivolatile)
Organics and Purgeable (Volatile) Organics.
State of Washington, Department of Health. Expires April 30, 1998. Dioxin in drinking water.
Lab I.D. 129
State of West Virginia, Department of Health. Expires December 31, 1997. Certificate No.
9923(C). Dioxin in drinking water.
Revised 6/26/97 |m
Printed STC6/97
?0
-------
State of Wisconsin, Department of Natural Resources. Expires June 30. 1997. Laboratory
ID Number 999869530. Certification for the following categories of Organics: Purgeable,
Base/Neutral. Acid. PCSs, and Dioxin. Expires November 14, 1999. Laboratory ID
999869530. Dioxin in drinking water.
PHARMACEUTICAL
Drug Enforcement Agency (DEA). Expires November 30, 1997. Registration number
RT01195835. Controlled substance registration for schedules 1,2.3,3N,4,5.
N.C. Department of Human Resources. Expires October 31, 1997. Registration number
NC-PT 0000 0031. North Carolina controlled substances registration. Application submitted for
renewal.
Food & Drug Administration (FDA) Registration. Expires July 1997. ID #'s 001500 1053481.
Annual registration of drug establishment. Annual registration of drug establishment.
OTHER
Clinical Laboratory Improvement Amendments (CL1A) Registration. Expires May 30, 1999.
ID # 34D0705123. Department of Health & Human Services, Health Care Financing
Administration.
U.S. EPA Large Quantity Hazardous Waste Generator. No expiration date. EPA ID
#NCD982156879. Permit indicates that the laboratory is a large generator of hazardous waste.
North Carolina Radioactive Materials License. Expires April 30 1998. License No. 032-
0954-1. License authorizes the licensee to receive, acquire, own, possess, transfer, import and
use such radioactive materials as designated.
North Carolina General License for Radiation Protection. No. expiration date. License No.
032-875-OG. The general license applies only to radioactive material contained in devices
which have been manufactured and labeled in accordance with specific requirements.
Revised 6/26/97 jm
Prin
-------
Eastern Research Group -
Project Number. 42299Bnl
Sample File: VG137
Client Project: Iron & Steel
TU ID: 173-6M A-D ;
Date Received:
Date Extracted:
07/01/97
ti//l7/97
Method 8270A MM5
Sample ID: M23-OUTLET-RUN 1
y : ; Jtespcoise File VG134
I 'ir- U- ^h:'-'!
Dilution Factor: 0.40
Analyte .. -. ;.'.-•••:. -&m
- : .1 '."•'••'• H
Naphthalene-d
Naphthalene
2-Viethylnaphthalene
Acenaphthene-d
2-Chloronaphthalene
Acenaphthylene
Acenaphthene
Fluorene
Phenanthrene-d
10
Phenanthrene
Anthracene
Fluoranthene
Chrysene-d __
Pyrene
Benzo(a)anthracene
Chrysene
Perylene-d ^
Benzo(b)fluoranchene
Benzo(k)fluoranthene
Benzo(e)pyrene
Benzo(a)pyrene
Perylene
Indeno(l ,2,3-cd)pyrene
Dibenz(a.h) anthracene
Benzo(g,h, i) perylene
Reviewed bv t3"O-J(A Date
NA- Not Applicable; Det
Qaittt. :;-FL&G-. .
tg:.\. :',;:.,::':;.. ;. :::.;.. "..
IS 2
220.50 BE
120.53 E
IS 3
U
35.24
13-69
22.39
IS 4
153.39 E
7.30
33-01
IS 5
13.72
2.30 J
6.29
IS 6
5.58
0.94 J
3.57 J
1.01 J
U
1.08 J
0.45 J
1.52 J
R/^/li
RT
10.94
11.01
12.41
14.50
14.21
14.56
15.62
17.54
17.62
17.69
20.00
22.91
20.44
22.89
22.94
26.08
25.09
25.15
25-77
25.91
28.68
28.74
29.25
£}£&. Limit Ottftft. timik
$& titj
. . ^* . ™
4
4
0.16 4
4
4
4
4
4
4
4
4
4
4
4
4
4
0.18 4
4
4
4
Limit Detection Limit; Quan. Limit: Quantitation Limit
IS: Internal Standard; U: Undetected; B: Present In Blank; J: Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
Triangle Laboratories of RTF, Inc.
801 Capitoia Drive • Durham, North Carolina 27713
Phone- (914) 544-5729 • Fax: (919) 344-5491
Savar v3.5
Printed: 14:26 08/29/1997
2T>
O
-------
Data File: /chem/V.i/08-22-97.b/VG137.d
Date • 22-flUG-97 09:32
Instrument : V.i
Sample ID : M23-OUTLET-RUN 1
Column phase : DB-5
Volume Injected (uL) : 1.0
Page 9
of RTP, Inc.
Column diameter : 0.32
/chem/V.i/08-22-97.b/VG137.d (Part 1 of 2)
0°
o:
O fl)
BB
QQ
10 11
Time (mln.)
r
12
T"
13
14 15
16
17
~T
18
-------
Data File: /chen/V.i/08-22-97.b/VG137.d
Date : 22-ftUG-97 09:32
Instrument : V.I
Sample ID : H23-OUTLET-RUN 1
Column phase : DB-5
Volume Injected (uL) : 1.0
of HTP, Inc.
Page 10
Column diameter : 0.32
—r~
20
/chem/V.i/08-22-97.b/VG137.d (Part 2 of 2>
18
19
21
22
23
24
1 ' i •
T
25 26
Time (min.)
27
T"
28
-i—I—i—i—i—r-
29
30
i '
31
' ' i
32
-1—
33
-------
Data File: /chem/V.i/08-22-97.b/VG137.d
Report Date: 22-Aug-1997 10:27
Page 1
Data file
Lab. Id.
Inj Date
Operator
Smp Info
Misc Info
Comment
Method
Meth Date
Cal Date
Als bottle
Oil Factor
Integrator
Sample Type
TRIANGLE LABORATORIES, INC.
SEMI-VOLATILE QUANTITATION REPORT
/chem/V.i/08-22-97.b/VG137.d
42299BN1
22-AUG-97 09:32
DD
M23-OUTLET-RUN 1
173-61-1A-D
Autotune Date:
Inst ID: V.i
03-Jul-97 12:11:2
/chem/V.i/08-22-97.b/cclist.m
22-Aug-1997 08:04 target
22-AUG-1997 07:09
3
2.000
HP RTE
: AIR
Cal File: VG134.d
Target Version: Target 2.20
Compound Sublist: pah.sub
CONCENTRATIONS
Compounds
* 1 1,4-Dichlorobenzene-d4
* 2 Naphthalene-dS
* 3 Acenaphthene-d10
* 4 Phenanthrene-d10
* 5 Chrysene-d12
* 6 Perylene-d12
$ 7 2-Fluorophenol
$ 8 Phenol-dS
$ 9 2-Chlorophenol-d4
$ 10 1,2-Dichlorobenzene-d4
$ 11 Nitrobenzene-d5
$ 12 1,3,5-Trichlorobenzene-d3
$ 13 1,4-Dibromobenzene-d4
$ 14 2-Fluorobiphenyl
$ 15 2,4,6-Tribromophenol
$ 16 Anthracene-d10
$ 17 Pyrene-d10
$ 18 Terphenyl-d14
42 Naphthalene
46 2-Methylnaphthalene
50 2-Chloronaphthalene
56 Acenaphthylene
58 Acenaphthene
65 Fluorene
73 Phenanthrene
74 Anthracene
77 Fluoranthene
78 Pyrene
83 Benzo(a)anthracene
84 Chrysene
86 Benzo(b)fluoranthene
QUANT SIG
MASS RT (REL RT)
152.00 8.456(1.000)
136.00 10.942(1.000)
164.00 14.499(1.000)
188.00 17.535(1.000)
240.00 22.907(1.000)
264.00 26.078(1.000)
112.00 6.098(0.721)
Compound Not Detected.
Compound Not Detected.
Compound Not Detected.
82.00 9.474(0.866)
Compound Not Detected.
Compound Not Detected.
172.00 13.071(0.902)
Compound Not Detected.
Compound Not Detected.
Compound Not Detected.
Compound Not Detected.
128.00 11.014(1.007)
142.00 12.406(1.134)
152.00 14.209(0.980)
154.00 14.564(1.004)
166.00 15.625(1.078)
178.00 17.616(1.005)
i-ra nn ll ( O 17 m,* nnc\
202.00 20.005(1.141)
202.00 20.438(0.892)
228.00 22.885(0.999)
228.00 22.944(1.002)
ON
RESPONSE
420022
1473124
1034994
1514784
1159163
1110668
23326
83306
23798
23001461
7645943
4000528
877773
1658498
14086412, .
1'itm',1> '
2987626
1464492
190980
468501
f f m 1 ftf */D^/'
-COLUMN
( ng)
40.00
40.00
40.00
40.00
40.00
40.00
1.73
6.44
0.79
551.47
301.25
88.10
34.23
55.98
383.35
394.74
82.56
34.31
5.75
15.73
^5.56
FINAL
( ug)
3.45(aR)
12.88(aR)
1.58(aR)
1102. 93(A)
602.50(A)
176.20
68.46
111.96
766.69(A)
789.48(A) |
165.13
68.62
11.51(a)
31.45
31.11 [*
t/xtfir
Data Review:
Date:
-------
Data File: /chem/V.i/08-22-97.b/VG137.d
Report Date: 22-Aug-1997 10:27
Page 2
CONCENTRATIONS
QUANT SIG
MASS
252.00 JZIS
252.00
252.00 ZS.1I
276
278
276
•
00
00
00
RT (REL RT)
25
28
28
29
.769(0.
.678(1.
.743(1.
.247(1.
988)
100)
102)
122)
RESPONSI
205579
75452
24339
89829
ON -COL
-. (
«s*ii
8
63tf?-8
2
1
3
UMN
ng)
.77
.92
.12
.71
.12
.80
FINAL
( ug)
33. 55^
17.84(a)
16.25(a)
5.
2.
7.
42(a)
23(a)
60(a)
Compounds
87 Benzo(k)fluoranthene
88 Benzo(e)pyrene
89 Benzo(a)pyrene
90 Perylene
91 Indeno(1,2,3-cd)pyrene
92 Oibenz(a,h)anthracene
93 Benzo(g,h,i)perylene
QC Flag Legend
a - Target compound detected but, quantitated amount
Below Limit Of Quantitation(BLOQ) .
A - Target compound detected but, quantitated amount
exceeded maximum amount.
R - Spike/Surrogate failed recovery limits.
-------
Data File: /chem/V.i/08-22-97.b/VG137.d
Date : 22-flUG-97 09:32
Instrument : V.i
Sample ID : M23-OUTLET-RUN 1
Column phase : DB-5
Volume Injected : 1.0
42 Naphthalene
Page 11
Column diameter : 0.32
Scan 1137 (11.014 min) of VG137.d
6.0-i
5.0-1
!
2 :
S 3.0-i
x :
:
1.0-j
0.0-
II
. ,. J ..L tllll ... . J
|ll j . 1 1 j 1 1 1 ( • • • J 1 • « [ « « • J 1 1 1 | < • ' ( I 1 « |
40 60 80 100 120 140 160 180 200 220
Mass/Charse
6.0-^
:
5.0-;
^4.0-;
£3.0-:
x :
1.0-;
0.0J
Scan 1137 (11.014 min) of
. 1 ,11 J 1
VG137.d (Subtracted)
I , . | . i ) | i i i | • i i [ • • i | i i i | i i i | < < i | i < • |
40 60 80 100 120 140 160 180 200 220
Mass/Charge
8.0-
34.0-
o.o:
42 Naphthalene (PBM F
|l .ill tin, , J. 1
leference Spectrum)
j i 1 • | i • 1 | • i i | > T I ( • • . | ... | i i i [ i t • j ... |
40 60 80 100 120 140 160 180 200 220
Mass/Charse
Scan 1137 (11.014 min) of VG137.d (2 DIFFERENCE)
100-q
75-
50-
25-j
Sj: o-i
»-25-
** :
-50-:
-75-!
- •-• • -- •-- — •• - -j1- -•- •- •
40 60 80 100 120 140 160 180 200 220
Mass/Charge
Mass 128.00
6.0-j
5.5-1
5.0-1
4.54
4.04
33.54
< :
S3.0^
-22.54
"• 2.0-=
1.5-5
1 0-=
A* V _
0.51
0.0^
,
A. J
— *v
O
*
3
^ !
10.60 10.80 11.00 11.20 11.40
Time (min.)
9.0-i
8.0-
7.0-
6.0-
S5.0-
o '•
2.0-
0 0-
Mass 129.00
I IT
•
uJ.
o
^'
>/V^xv\^_
10.60 10.80 11.00 11.20 11.40
Time (min.)
Mass 127.00
1.6-
•
1.4-
:
1.2-
~1.0J
f
S0.8-
2 '•
1
J
i
Lfl
8
»-*
»0.6-? 1
0.4-^
0.2-
0 0-
K
ji
\/ 1 /
v W^
A
\
\ jf^
W/XVu^
10.60 10.80 11.00 11.20 11.40
Time (min.)
-------
Data File: /chem/V.i/08-22-97.b/VG137.d
Date : 22-6UG-97 09:32
Instrument : V.i
Sample ID : M23-OUTLET-RUN 1
Column phase : DB-5
Volume Injected (uL> : 1.0
46 2-Methylnaphthalene
Page 12
Column diameter : 0.32
Scan 1330 (12.406 win) of VG137.d
2.8-f
2.4-j
2.0-j
-
31.6-:
x 1«'~
^0.8-i
0.4-.
, 1 1 i
40 60 80 100
! •! Ll
.in
i ' ' • i • • • i • • • i • • • i • •
120 140 160 180 200
Mass/Charee
Scan 1330 (12.406 min)
2.8-
2.4-
2ft—
.u
31.6-
x 1«£-
^0.8-
0.4^
40 60 80 100
of VG137.d (Subtracted)
t .
120 140 160 180 200
Mass/Charee
46 2-Methyl naphthalene (PBM Reference Spectrum)
8.0:
.
fO * "
o
"* 4.0-
XX
^2.0^
0.0J
il II 1 it, ii in i.l . i
| i 1 r | 1 f ,.,,,..
40 60 80 100
|_ fc
| 1 1 1 | 1 1 . | ... | ... | ..
120 140 160 180 200
Mass/Charee
Scan 1330 (12.406 min)
100 -q
75-
50-
25-
<4- I
"*-50-
-75-i
40 60 80 100
of VG137.d (Z DIFFERENCE)
120 140 160 180 200
Mass/Charee
Mass 142.00
2.3-
2.5-
2.2-
2.0-
^1.8-i
gl.5-
|l.2-
>_ 1.0J
0.8-
0.5-
0.2-j
0.0-
-«•
B
a
i
1
/
i/ Vi
, , T" , , ( , 1 , , , . | , . . , . i
12.00 12.20 12.40 12.60 12.80
Time (min.)
Mass 141.00
2.4-
2.2-
2.0-
1.8-i
1.6-
~ 1.4-
Sl.2-
rH
<21.0-
0.6-
0.4-j
Irs
n "i
II CM
II
,/ V]
12.00 12.20 12.40 12.60 12.80
Time (min.)
-------
Data File: /chem/V.i/08-22-97.b/VG137.d
Date ; 22-AUG-97 09:32
Instrument : V.i
Sample ID : M23-OUTLET-RUN 1
Column phase : DB-5
Volume Injected (uU : 1.0
56 flcenaphthylene
Page 14
Column diameter ; 0.32
Scan 1579 (14.209 Bin) of VG137.d
1.4-
1.2-
1.0-
J°0.8-
-S0.6-
0.2-
fill n
J 11 luJll. .IjJil llj.lil.1.. J,i,l,lii ^i,..l,L.lj ttu.. .. 1.., . 1
III. -,--
40 60 80 100 120 140 160 180 200 220
Mass/Charge
Scan 1579 (14.209 win) of VG137.d (Subtracted)
1.4-
1.2-
1.0-
?0.6-
9-0.4-
0.2-
0 0-
.ii
U.U ,,,,(,, ,,,.,,.,,,.,,.., | ,,,,-,-,,, ,-T T~-| -,
40 60 80 100 120 140 160 180 200 220
Mass/Charge
8.0-:
IV)
-S4.0-
>. :
2.0-
•
0 0-
56 flcenaphthylene (PBM Referenc
J
I ,ll
h J III .1 U.- . J .11
e Spectrum)
40 60 80 100 120 140 160 180 200 220
Mass/Char?e
Scan 1579 (14.209 min) of VG137.d (Z DIFFERENCE)
100-a
75-.
SO-.
25-.
fc 0-j
"-25-J
-50-=
-75-1
-100-
•- •— • v- -• • - ••• -- _......
40 60 80 100 120 140 160 180 200 220
Mass/Charge
Mass 152.00
1.4-
1.2-
1.0-
^0.8-
•20.6-
0.4-
0.2-
0.0-
15
3
/VSA J \ A
^•s/ ^ Vj^vi/ Vj -— / ^/*v
13.8 14.0 14.2 14.4 14.6
Time (min.)
Mass 151.00
3.2-
2.8-
2.4-
^.2.0-
<
X
0.8-
0.4:
•
A
i^J W
13.8 14.0 14.2 14.4 14.6
Time (min.)
Mass 153.00
3.6T
3.2-;
.8-
2.4-
;
in2-0"
^1.6-
*
0.8-i
0.4-
Jl
va j
^ 1 1
3
*
n
j
A
n/vi
\ \ A I '
\ / \ / \ /
13.8 14.0 14.2 14.4 14.6
Time (mm.)
-------
Data File: /chem/V.i/08-22-97.b/VG137.d
Date : 22-flUG-97 09:32
Instrument : V.i
Sample ID : M23-OUTLET-RUN 1
Column phase : DB-5
Volume Injected (uL) : 1.0
58 ficenaphthene
Page 15
ColuMi diameter
0.32
Scan 1628 (14.564 rain) of VG137.d
7.0-j
6.0-i
5.0-j
£4.0-1
1.0-1
0.0-
40
i '
60
i
80
i JllJIll,. ,|j,yn,...i.Jili.L.i|ij.iiililiH.M.. lii|i..|ll...i,i..4.'..i ..•...',.
' i " * f I ' • i r v M T % i i i ! \f i i i i
100 120 140
Mass/Charge
160
180 200
Scan 1628 (14.564 min) of VG137.d (Subtracted)
4.0-
3.0-
2.0-j
i.o-
0.0-
T
40
60
58 Acenaphthene
-------
Data File: /chem/V.i/08-22-97.b/VG137.d
Date : 22-AUG-97 09:32
Instrument : V.i
Sample ID : M23-OUTLET-RUN 1
Column phase : DB-5
Volume Injected : 1.0
65 Fluorene
Pace 16
Coluan diameter : 0.32
Scan 1774 (15.625 min) of VG137.d
1.0-;
0.6-
0.0
40
I
I. l.l.lilllll . l.l.lllll ll.lll.l.llll.l.l.|.l,l|lll.|.I.Nll III.I,. I
' ' I ' ' ' I • • ' I ' ' ' 1
80 100
120 140 160
Mass/Charge
180
200 220 240 260
Scan 1774 <15.625 rain) of VG137.d (Subtracted)
0.0
J
J
ll 1
ilk ,'i, , .Hi , ,"...ii
i . .1
, i
„ j. .
40 60 80 100 120 140 160 180 200 220 240 260
Mass/Charge
65 Fluorene (PBM Reference Spectrum)
8.0-
^6.0:
1 4.0-j
'2.0-
0.0-un
40
60 80 100 120 140 160 180 200 220 240 260
Mass/Charge
100-
75-i
50-j
25-I
o-i
-25-;
'-50^
-75-j
-100-^
Scan 1774 (15.625 min) of VG137.d (2 DIFFERENCE)
40
60 80 100 120 140 160 180 200 220 240 260
Hass/Charge
Mass 166.00
15.2 15.4 15.6 15.8 16.0
Time (min.)
Mass 165.00
15.2 15.4 15.6 15.8
_ Time
-------
Data File: /chem/V.i/08-22-97.b/VG137.d
Date : 22-flUG-97 09:32
Instrument : V.i
Sample IB : H23-OUTLET-RUN 1
Column phase : DB-5
Volume Injected
-------
Data File: /ch««^.i/'08-22-97.b/VG137.d
Date : 22-flUG-97 09:32
Instrument : V.i
Sample ID : M23-OUTLET-RUN 1
Column phase : DB-5
Volume Injected : 1.0
74 Anthracene
Page 10
Column diameter : 0.32
Scan 2057 (17.689 min) of VG137.d
3.2-
2.8-
2.4-
~2.0-
£l.6-
3 1.2-j
0.4-j
0.0-
J
i • •
40
2 A '•
.0-
1c •
.5-:
S1.2-:
o 1 ft-=
3 * =
-0.81
0.2-j
60
80
I
1
it
li.jlllllllilllllllllllllllllllllllllllillllillilill
100 120 140 160
Mass/Charge
[lljjilLl,llll!llll.Ll.ll,,l. :
2.0-
0 0-
40
rt
• i r | . .
60
,
80
tl
100 120 140 160
Hass/Charee
L
Jl
180 200 220 240 260
Scan 2057 (17.689 min) of VG137.d (2 DIFFERENCE)
100-q
75-j
50-!
25-;
£ o-i
3 -25-!
*4 '
-so-;
-75-!
-100-:
.n
1
40
~ — h
--i
60
— JU_
80
j
_.^.., *. ...L_jL. ji. __.
i . , 1 1 1 1 • i . . 1 1 .
100 120 140 160
Mass/Charee
180 200 220 240 260
Mass 178.00
4.0-
3.6-
3.2-
2.8-
32.4-
3 2*°~
^^ f '
1.2-i
0.8-i
0.4-:
i
1
1
j
I
i
«^
/ u. .
17.20 17.40 17.60 17.80 18.00
Time (win.)
Mass 176.00
8.0-:
7.0-i
6.0J
^5.0r
? !
X '.
^3.0-
2.0-i
1.0^
•
t—
. 0 -"-r T1 ' ' 1 ' ' ' 1 ' ' ' 1 ' ' ' 1 ' '
17.20 17.40 17.60 17.80 18.00
Time (min.)
Mass 179.00
7.0-i
6.0-
•
5.0-j
i
b :
^< ^ 0-
>- * :
2.0-i
•
"
l.o-i
0.0-
ri
1 j
/ lA A^\
^ -
' ( ' ' ' 1 ' ' ' 1 ' ' ' 1 ' ' * I ' T
17.20 17.40 17.60 17.80 18.00
Time (min.)
33
-------
Data File: /chem/V.i/08-22-97.b/VG137.d
Date : 22-flUG-97 09:32
Instrument : V.i
Sample ID : h23-OUTLET-RUN 1
Column phase : DB-5
Volume Injected (uL> : 1.0
77 Fluoranthene
Page 19
Column diameter : 0.32
1.4-g
1.2-j
i.o-i
o ' :
30.6-i
0.2-i
Scan 2373 (20.005 min) of
,11 .11 li.,,llihlLlL,,u,.,,, „ ^ , .1
VG137.d
50 75 100 125 150 175 200 225 250 275 300
Mass/Charge
1.4-
1.2-i
1.0-
gO.8-
s-0.4-
0.2-
Scan 2373 (20.005 min) of VG137,
J
d (Subtracted)
50 75 100 125 150 175 200 225 250 275 300
Mass/Charge
8.0:
^6.0-
ro
§4.0-
2.o:
0 0-
77 Fluoranthene (PBM Refere
. . .. „ .1 . ,. ,. J
nee Spectrum)
50 75 100 125 150 175 200 225 250 275 300
Mass/Charge
100 •:
75-i
504
25i
s-25-j
-75-i
Scan 2373 (20.005 min) of VG137.d (Z DIFFERENCE)
50 75 100 125 150 175 200 225 250 275 300
Mass/Charge __
30.8:
o
So.6:
o.4:
o.2:
Mass 202.00
|| S
i
— u L^_^_ i/
D
O
V
3
19.60 19.80 20.00 20.20 20.40
Time (min.)
2.4-
2.2-i
2.0-
1.8-
1.6-i
il*
>-0.8-
0.6-
0.4-
Mass 101.00
a
I
.0 i-| i i i | i i i | i i i | i i i | ••
19.60 19.80 20.00 20.20 20.40
Tine (min.)
1.8:
1.6-
1.4-i
1.2-i
"0.6:
0.4:
0.2:
0 0-
Mass 100.00
1 *
1 S
S
-------
Data File: /chem/V.i/08-22-97.b/VG137.d
Date : 22-AUG-97 09:32
Instrument : Y.i
Sample ID : M23-OUTLET-RUN 1
Col Limn phase : DB-5
Volume Injected (uL) : 1.0
78 Pyrene
Page 20
Column diameter : 0.32
Scan 2432 (20.438 »in) of VG137.d
6.0-
5.0-
£4'°~
S3.0-
x
>•
1.0-
i
II 1 1 1, i i
i Hi , 1
,1 J.ilLolil.l.iJ-,-1 - O.-..|L|L. ,
50 75 100 125 150 175 200 225 250 275 300 325
Mass/Charee
Scan 2432 (20.438 min) of VG137.d (Subtracted)
:
6.0-;
5.0-j
S4.0-E
< •
S 3.0—
X I
~2.0-^
>• * .
1.0-5
i
K
- - _ .. - A ,j 1 -- -Ii iflk .
50 75 100 125 150 175 200 225 250 275 300 325
Mass/Charee
8.0^
•
r6'0":
I4-0*:
~
2.0:
0 0-
78 Pyrene
-------
Data File: /chem/V.i/08-22-97.b/VG137.d
Date : 22-AUG-97 09:32
Instrument : V.i
Sample ID : M23-OUTLET-RUN 1
Column phase : DB-5
Volume Injected . :
2.0-
'.
o.o-l
83 Benzo (a)anthracene (PBM Re
i
i
, j j
"i i |'i i'i i 'f i i*n* i iH i | i i i i-j-n-VT-p-'i-n-^-r T rrf
ference Spectrum)
50 75 100 125 150 175 200 225 250 275 300 325 350 375
Mass/Charee
Scan 2764 (22.885 min) of VG137.d (Z DIFFERENCE)
100-q
75-
50-
251
£ 0-
s-25-i
**-so4
-75-
1 II 1
.11. .iL.ll.tO.t.M.^m^ll ..Jua.j._.« „!*.,. jJi .^li.lli ... i .... ...
50 75 100 125 150 175 200 225 250 275 300 325 350 375
Mass/Charee
Mass 228.00
1.6-
1.4-
1.2-:
1.0-
tn
oO.S-5
X
0.4-^
0.2-
n ^
a
J
n
cvj
lj
N
.
A
j\ . . A! \L.^
22.4 22.6 22.8 23.0 23.2
Time (min.)
Mass 229.00
3.6-
3.2-
2.8-
2^4-
y«»
T2.0-
Sl.6-
0.8-
0.4-
0 0-
i Ln
fl ^
« K
I
I ]
i
In
i_/\ u M. At IIJI_/V
^ WX>AvJJLJ^JV%vJw
22.4 22.6 22.8 23.0 23.2
Time (mm.)
Mass 226.00
4.8-
4.4-i
4.0-i
3.6-i
3.2-i
^2.8-i
^2.4-:
32.0-f
>-i.6-i
1.2-i
0.8-f
0.4^
0 0-
22.4 22.6 22.8 23.0 23.2
Time (min.)
42
-------
Data File: /chem/V.i/08-22-97.b/VG137.d
Date : 22-flUG-97 09:32
Instrument : V.i
Sample ID : M23-OUTLFJ-RUN 1
Column phase : DB-5
Volume Injected of VG137.d (Subtracted)
1.2-f
i.o-i
ID
30.6^
X
~o.4-q
0.2-i
0 0"N'i il'.'.t'H'"!'" n'l'iM fii'i'iyii'n|»iii'ir»iit|i
50 75 100 125 150 175 200 225 250 275 300 325 350 375
Mass/Charge
84 Chrysene (PBM Reference Spectrum)
8.0-
2.0-
0.0
41.
("'"1 "'"1'""P '" l" "I " "I ""I"" l" "I '
50 75 100 125 150 175 200 225 250 275 300 325 350 375
Hass/Charge ___ .
100-
75"!
504
25-j
i-254
Scan 2772 (22.944 Min) of VG137.d (2 DIFFERETCE)
-75-:
-100-
1 111 111 11 111 111 111 111111 i' l 111' l''' ' i'''' I' * • * i * * * * i • * * • i • * * * i • * *'[''
50 75 100 125 150 175 200 225 250 275 300 325 350 375
1.6
1.4-
1.2-
1.0
0.4-
0.2-j
;\
I_^v.
0.0 !.>••. T'-^-r
22.6 22.8 23.0
Time (min.)
23.2 23.4
22.6 22.8 23.0
Time (min.)
23.2 23.4
Mass 229.00
3.2-i
2.4-j
0.8-i
0.4r
0.0
22.6 22.8 23.0
Tjine (min.)
23.2 23.4
-------
Data File: /chem/V.i/08-22-97.b/VG137.d
Date : 22-AUG-97 09:32
Instrument : V.i
Sample ID : M23-OUTL£T-fiUN 1
Column phase : DB-5
Volume Injected (uL) : 1.0
86 Benzo(b)fluoranthene
Page 15
Column diameter : 0.32
Scan 3062 (25.090 min) of VG137.d
1.2-
1.0-
xx 0.8:
in
00.6,
X ;
>-<)'4~-
0.2^
0.0-
i
[
1 h
JllililiJiilJLjliuijiLu.ilL.LL.jtrf.,^., j
u»^ .
40 80 120 160 200 240 280 320 360 400
Mass/Charee
•
8-°:
S6*°~
S4.0-
X
"2.0-
0.0-
Scan 3062 (25.090 min) of VG137.d (Subtracted)
,
L
40 80120160200240280320360400
Mass/Charee
8.0-
xx 6.0-
0
"x4.0-
2rt_
.O-
0.0-
86 Benzo(b)fluoranthene (PBM Re<
1
• • • i • ' ' i • • < 1 ' ' ' I ' ii i ~
"erence Spectrum)
' i i l i i i r ' '" ' l ' ' ' i
40 80120160200240280320360400
Mass/Charee
100-
75-!
50-j
25-j
£ o-i
s-25-j
**-50-l
-75-1
-100-^
Scan 3062 (25.090 min) of VG137.d (2 DIFFERENCE)
_i .. .......... ,,-.__ . ^ .. _ ._ ..
40 80120160200240280320360400
Mass/Charee
Mass 252.00
1.1-
1.0-
0.9-
0.8-
0.7-
550.6-
o rt _
^0.4-j
0.3-f
0.2-f
o.i-i
- . , ^. \j ,.i^ ^/\^_^^
24.6 24.8 25.0 25.2 25.4
Time (min.)
Mass 253.00
2.4-=
2.2-^
2.0-i
1.8-i
1.6-i
•~1 4-
<*".*_ :
Si.o^
0.6-;
0.4.H
0»2~
0.0-:
IT*
fl»'
M
A
J\ J \ A A
vVVvi W^" — ' L/VV
^cxv -yw^ s^/r v Tv\/v,
24.6 24.8 25.0 25.2 25.4
Time (min.)
Mass 125.00
4.4-i
4.0-i
3.6H
3.2H
2.8-j
^2.4-1
^2.0-:
^1.6-i
1.2-j
0.8-i
0.4-J
0 0—
P.
LsjiAi 1 \
^\*hlA , ,
^^Wui,
v"rVyM^
24.6 24.8 25.0 25.2 25.4
Time (min.)
-------
Data File: /chem/V.i/08-22-97.b/VG137.d
Date : 22-AUG-97 09:32
Instrument : V.i
Sample ID : M23-OUTLET-RUN 1
Column phase : DB-5
Volume Injected (uL) : 1.0
87 Benzo- * :
0.2-i
0.0J
4
1
1 I
1
J 1 illjiiiH^V^ "rt-r H
80120 160 200 240 280 320 360 400
Mass/Charse
Scan 3070 (25.150 min) of VG137.d (Subtracted)
.
1 4-
**" .
1.2-i
1.0-i
xx ;
i£g]
:- 0.4-i
0.2-i
0.0-
4
i
0 80 120 160 200 240
1 Jt 1 --l-.lt ^r" .' f'r V"|- L"-f f
280 320 360 400
Hass/Charee
8.0-j
ro
|4.0-
***^
*~2.0-
87 Benzo(k)fluoranthene (PBM Ri
fference Spectrum)
,
J II
40 80120160200240280320360400
Mass/Chanre
Scan 3070 (25.150 min) of VG137.d (Z DIFFERENCE)
100-g
75-j
50-j
25^
5£ °-i
"3
-75-1
i
i .
L JuJ.LL. .^J^. LlllluJli.nUlli«UUJ.iAi^,ilfc-.4n^U.J .- 1. — .* .. .i..-Jk^... II
-100 ^ i i i | i i i | i i i | i ' ' | ' i ' i ' ' i i ' ' • i • • • i • • • i •
40 80120160200240280320360400
Hass/Charge
Mass 252.00
1.1-3
i.o4
0.9-1
0.8-!
0.7-j
SO.6-1
So.5^
X
O.JH
0.2-i
0.1-i
h
n
11
1
Is
1 Il5
f
1
1 1
I I
j ' \-i //\_~^-^-
24.6 24.8 25.0 25.2 25.4
Tine (min.)
.
2.2-i
2.0H
1.8^
1.6-1
-1.4-j
2 1.0-j
0.6^
0.4-i
0.2-i
Mass 253.00
jrg
II *
r
1 1
24.6 24.8 25.0 25.2 25.4
Time (min.)
Mass 125.00
4.4-=
4.0^
3.6-j
3 2J
-
2.8-;
j?2.4r
So 0-
x '*w ;
0.8-i
0.4-i
0 0-
P
n«
IK , I
JftMV. \
VI™ T X i i /I
\/^AK \ Lu A
T^r \MAt i
V^VvW^
^Y¥rv
• i
24.6 24.8 25.0 25.2 25.4
Time (nin.)
-------
Data File: /chem/V.i/08-22-97.b/VG137.d
Date : 22-flUG-97 09:32
Instrument : V.i
Sample ID : M23-OUTLET-RUN 1
Column phase : DB-5
Volume Injected (uL) : 1.0
88 Benzo(e)pyrene
Page 25
Column diameter : 0.32
o.8:
£0.6-
S -
x 0 4-
XX * .
""0.2:
Scan 3154 (25.769 »in) of
lilt
i , Mil.llJULuLL^L^^..
40 80 120 160 200 240
Mass/Charee
6.0-
5.0-i
4.0-;
53.0-!
x :
1.0-i
Scan 3154 (25.769 mm) of VG137.
I
! .11... 1 .J.I., ...... ., ... . . J
VG137.d
280 320 360 400
d (Subtracted)
I. L . .........
40 80 120 160 200 240 280 320 360 400
Mass/Charee
8.0:
fo * •
§4.0:
88 Benzo(e)pyrene (PBM Refer
.ll J
?nce Spectrum)
40 80 120 160 200 240 280 320 360 400
Mass/Charee
100-
75-1
50-j
254
£
-------
Data File: /chei«/V.i/08-22-97.b/VG137.d
Date : 22-AUG-97 09:32
Instrument : V.i
Sanple ID : H23-OUTLET-RUN 1
Colunn phase : DB-5
Volune Injected (uL) : 1.0
89 Benzoi 4.0-
'2.0-
0.0
-1-
40 80120160200240280320360400
Hass/Charge
100T
75-i
so-i
25-i
"• 0^
s-25-\
-754
-100Jr
Scan 3173 (25.909 nin> of VG137.d (2 DIFFERENCE)
Jl J(-
40 80120160200240280320360400
Hass/Charge
Has* 252.00
25.4 25.6 25.8 26.0 26.2
Time (min.)
Mass 253.00
25.4 25.6 25.8 26.0 26.2
Time (min.)
Hass 125.00
25.4 25.6 25.8 26.0 26.2
Tine (nin.)
47
-------
Data File: /chem/V.i/08-22-97.b/VG137.d
Date : 22-ftUG-97 09:32
Instrument : V.i
Sample ID : M23-OUTLET-RUN 1
Column phase : DB-5
Volume Injected of VG137.d
75 100 125 150 175 200 225 250 275 300 325 350
Mass/Charge
Scan 3551 (28.678 min> of VG137.d (Subtracted)
L Hi ,) . i.Jl il..i ..I, iLlDj. . , ..,.u nf..v,,.. .1 ..I. .. .1
i-iWi'i < K i .1 ii i ii1. \
50 75 100 125 150 175 200 225 250 275 300 325 350
Mass/Charee
91 Indeno(l,2,3-cd)pyrene (PBM Reference Spectrum)
50 75 100 125 150 175 200 225 250 275 300 325 350
Mass/Charee
Scan 3551 (28.678 min) of VG137.d (2 DIFFERENCE)
50 75 100 125 150 175 200 225 250 275 300 325 350
Mass/Charee
Mass 276.00
28.2 28.4 28.6 28.8 29.0
Time (min.)
28.2 28.4 28.6 28.8 29.0
Time (min.)
43
-------
Data File: /chem/V.i/08-22-97.b/VG137.d
Date : 22-flUG-97 09:32
Instrument : V.i
Sample ID : M23-OUTLET-RUN 1
Column phase : DB-5
Volume Injected (uL) : 1.0
92 Dibenz(a,h)anthracene
Page 29
Column diameter : 0.32
Scan 3560 (28.743 mm) of VG137.d
6.0-i
5.0-i
LOT
JH^^^^^^.,^.,.,..^!.,
50 75 100 125 150 175 200 225 250 275 300 325 350 375
Mass/Charee
Scan 3560 (28.743 min) of VG137.d (Subtracted)
8.0-j
6.0-1
.5.0-1
="2.0-1
1.0-j
0.0-
ii
JjUlMlyllUhdliL
50 75 100 125 150 175 200 225 250 275 300 325 350 375
Mass/Charee
92 Dibenz(a,h)anthracene (PBM Reference Spectrum)
8.0-
.6.0-j
J4.0-
'2.0-j
0.0
T
U
T
T
^
ii I" "I ""!' " • I "
50 75 100 125 150 175 200 225 250 275 300 325 350 375
Mass/Charee
100-
75-i
50-i
>-25-=
'-50-j
-75-=
Scan 3560 (28.743 win) of VG137.d (2 DIFFERENCE)
.1.1 .ji J.H.IUI, .iLiy ii .ijutfii Ji.,
.Hj-j^iJiuji.wJi^J ,11 .Jhw
h i
1 I ' ' ' ' I ' ' ' ' I ' ' ' ' I ' ' ' ' I ' ' ' ' I ! I ' ' I ' I ' > I ' ' I I | I I I I | I ' ' I | ' ' I I | I I I I | I I I I | IT
50 75 100 125 150 175 200 225 250 275 300 325 350 375
Hass/Charee
28.4 28.6 28.8 29.0 29.2
Time (min.)
Mass 139.00
28.4 28.6 28.8 29.0 29.2
Time (min.)
Mass 279.00
28.4 28.6 28.8 29.0 29.2
Time (min.)
43
-------
Data File: /chem/V.i/08-22-97.b/VG137.d
Date : 22-flUG-97 09:32
Instrument : V.i
Sample ID : N23-OUTLET-RUN 1
Column phase : DB-5
Volume Injected of VG137.d (Subtracted)
40 80 120 160 200 240 280 320 360
Mass/Charge
93 Benzo(g,h,i)perylene (PBH Reference Spectrum)
Scan 3629 (29.247 min) of VG137.d (Z DIFFERENCE)
U.J..L*..
-100 \ i i • i i
40 80
400
400
40 80 120 160 200 240 280 320 360 400
Mass/Charge
120 160 200 240 280 320 360 400
Mass/Charge
Mass 276.00
28.8 29.0 29.2 29.4
Time (min.)
29.6
Mass 138.00
29.0 29.2 29.4
Time (min.)
29.6
Mass 277.00
28.8 29.0 29.2 29.4 29.6
Time (min.)
50
-------
...?r,.' S Eastern R^chfflaap i / . .,'.
Project Number: 42299Bnl
Sample File: VG141
Client Project: Ixoa&'Stad
TIJ ID: 173-61-tA-D ?' v'.
?| Date Received: &7/I&/97
Method 8270A MM5
Sample ID: M23-OUTLET-RUN 1
Response File: YG134
;fc '^Bate€xtc*^& 87/17/97 .•''•.- : ---:: . ."
% ; ;. . Date Analyzed t.
Dilution Factor:
0S&2/97
8.00
Analyte •
: '•>.
Naphthalene-d
Naphthalene
2-Methylnaphthalene
Acenaphthene-d
2-Chloronaphthalene
Acenaphthylene
Acenaphthene
Fluorene
Phenanthrene-d
10
Phenanthrene
Anthracene
Fluoranthene
Chrvsene-d
' 12
Pyrene
Benzo(a)anthracene
Chrysene
Peryiene-d
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Benzo(e)pyrene
Benzo(a)pyrene
Peryiene
[ndeno(l .2,3-cd)pyrene
Dibenz(a.h) anthracene
3enzo(g,h.i)perylene
- Amouttf EP^Gf
tig .:; -^-:-v -\
IS 2
322.91 B
124.52
IS 3
U
38.85 J
15.56 J
24.91 J
IS 4
188.98
7.69 J
31.41 J
IS 5
14.47 J
U
6.54 J
IS 6
4.90 J
1.33 J
U
U
U
U
U
U
: RT
10.91
10.95
12.36
14.46
14.16
14.52
15.58
17.48
17.53
17.63
19.94
22.87
20.39
22.92
26.02
25-05
25.10
[ , .fp* jLteft i <2tt*i, Limit
••; :v:-'^:::«g..---' .;! »8
80
80
3.47 80
80
80
80
80
80
80
80
2.66 80
80
80
80
3.66 80
3.33 80
3-90 80
3.03 80
3.87 80
3-57 80
Reviewed by
Dace g / 2*7/?>
NA- Not Applicable; Det Limit Detection Limit; Quan. Limit Quantitation Limit
IS: Internal Standard; U: Undetected; B: Present In Blank; J: Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
Triangle Laboratories of RTF, Int
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Savar v3.5
Printed: 14:27 08/2<>/1997
51
-------
Y (xl~JO!-'IV3
I....1.iiiliinln.ilii.il
l,4-Dichlorobenzene-d4 (8.439)
flcenaphthene-dlO ^14.461)
Phenanthrene-dlO (17.482)
Data Review:
Date:
<. O If) •— <=> C3
o o a< 3 a> a>
*— ^- 3
C C TJ
IT c •• -n
• =
<~* GO
^
v 8-
« 3
\
(->•<:
3 56!
C
Q.
1
1
-o
0)
-------
Data File: /chem/V.i/08-22-97.b/VG141.d
Date : 22-OUG-97 13:34
Instrument : V.i
Sample ID : H23-OUTLET-RUN 1
Column phase : DB-5
Volume Injected H
1.2-1
1.0-i
0.9-i
0.8-i
0.7-
0.6-;
0.5J
0.4-^
0.3J
0.2^
Q.I1.
0.0
/chem/V.i/08-22-97.b/VG141.d (Part 2 of 2)
vo
oo
rf
«
CM
(X
I
18
19
20
21
22
23
24
25 26
Time (mln.)
27
~r~
28
29
30
31
~r~
32
~T-
33
-------
Data File: /chem/V. i/08-22-r37wJo/VG141.d
Report Date: 25-Aug-1997 06:42
Page 1
TRIANGLE LABORATORIES, INC.
SEMI-VOLATILE QUANTITATION REPORT
Data file
Lab. Id.
Inj Date
Operator
Smp Info
Misc Info
Comment
Method
Meth Date
Cal Date
Als bottle
Oil Factor
Integrator
/chem/V. i/08-22-97 .b/VG141.d
42299Bnl
22-AUG-97 13:34
DD
M2 3 -OUTLET -RUN 1
173-61-1A-D
Autotune Date: 03-Jul-97 12:
Inst ID: V.i
/chem/V. i/08-22-97. b/cclist.m
22-Aug-1997 08:04 target
22-AUG-1997 07:09
4
40.000
HP RTE
Sample Type: AIR
Compounds
QUANT SIG
MASS RT (REL RT)
* 1 1,4-Dichlorobenzene-d4 152.00 8.439(1.000)
* 2 Naphthalene-d8 136.00 10.912(1.000)
* 3 Acenaphthene-dIO 164.00 14.461(1.000)
* 4 Phenanthrene-d10 188.00 17.482(1.000)
* 5 Chrysene-d12 240.00 22.869(1.000)
* 6 Perylene-d12 264.00 26.022(1.000)
Cal File: VG134.d
Target Version: Target 2.20
Compound Sublist: pah. sub
CONCENTRATIONS
ON-COLUMN FINAL
RESPONSE ( ng) ( ug)
462361 40.00
1525510 40.00
934574 40.00
1536021 40.00
1051000 40.00
1052701 40.00
$ 7 2-Fluorophenol Compound Not Detected.
$ 8 Phenol -d5
Compound Not Detected.
$ 9 2-Chlorophenol-d4 Compound Not Detected.
$ 10 1,2-Dichlorobenzene-d4 Compound Not Detected.
$ 11 Nitrobenzene-d5 82.00 9.513(0.872)
1009 0.08 3.01(aR)
$ 12 1,3,5-Trichlorobenzene-d3 Compound Not Detected.
$ 13 1,4-0ibromobenzene-d4 Compound Not Detected.
$ 14 2-Fluorobiphenyl Compound Not Detected.
$ 15 2,4,6-Tribromophenol Compound Not Detected.
$ 16 Anthracene- d10 Compound Not Detected.
$ 17 Pyrene-d10
Compound Not Detected.
$ 18 Terphenyl-d14 Compound Not Detected.
42 Naphthalene
128.00 10.955(1.004)
46 2-Methylnaphthalene 142.00 12.358(1.133)
56 Acenaphthylene 152.00 14.159(0.979)
58 Acenaphthene
65 Fluorene
73 Phenanthrene
74 Anthracene
77 Fluoranthene
78 Pyrene
154.00 14.519(1.004)
166.00 15.577(1.077)
178.00 17.525(1.002)
202.00 19.942(1.141)
202.00 20.388(0.892)
84 Chrysene 228.00 22.919(1.002)
86 Benzo(b)f luoranthene 252.00 25.051(0.963)
1744135 40.38 1615.21
409015 15.56 622.47
199126 4.86 194.25(3)
45043 1.95 77.81(a)
83302 3.11 124.55(3)
879902 23.61 944.58
144131 3.93 157.12(3)
70024 1.81 72.37(3)
m7B1_ ft-** 1*. TTl-,1 O4> ftt/9 fr/i9
22071 0.82 32.68(3)
16842 0.61 24.49(a)
Data Review:
Date:
-------
Data File: /chem/V.i/08-22-97.b/VG141.d
Report Date: 25-Aug-1997 06:42
Page 2
CONCENTRATIONS
Compounds
87 Benzo(k)f luoranthene
88 Benzo(e)pyrene
89 Benzo(a)pyrene
90 Perylene
91 Indenod, 2, 3-cd)pyrene
92 0 ibenz( a, h) anthracene
93 Benzo(g,h, i)perylene
QC Flag Legend
QUANT SIG
MASS
252. 00 .2£ (0
252 nn
*>^">
on
_QD
RT
25 71
(REL
c/n
ag.taacij
01
RT)
10 \
1r
W
ON -COLUMN
RESPONSE
"1 rt 0 1 A /I
1003"7
/**&
Compound Not Detected.
Compound Not Detected.
a - Target compound detected but, quantitated amount
Below Limit Of Quantitation(BLOQ) .
R - Spike/ Surrogate failed recovery limits.
-------
Data File: /chem/V.i/08-22-97.b/VG141.d
Date : 22-flUG-97 13:34
Instrument : V.i
Sample ID : M23-OUTLET-RUN 1
Column phase : DB-5
Volume Injected : 1.0
42 Naphthalene
Page 11
Column diameter : 0.32
1.0-
0.8-
-0.6-
<&
<<*
^0.4-
s**
>-
0.2:
0 0
Scan 1152 (10.955 min) of VG141.d
.11 i 1. i,. .ill . i. mil ..... i 1
40 50 60 70 80 90 100 110 120 130 140 150 160
Mass/Charee
1.0-
°.8-i
~0.6:
VJ5
<
I0-4:
D"°-2:
Scan 1152 (10.955 min) of VG141.d (Subtr
..i ,, 1. ,. .,11 ,. in , . 1
acted)
1
40 50 60 70 80 90 100 110 120 130 140 150 160
Mass/Charee
8.0-
~6.0:
ro
<
o
^4.0-
s^
>- '.
2.0-
0 0
42 Naphthalene (PBM Reference Spect
.ill Mm i . 1
run)
40 50 60 70 80 90 100 110 120 130 140 150 160
Mass/Charee
100-
75-1
50 r
25-
fc -
0.4-^
0.2:
0 0-
Mass 127
-J\^. J
.00
-Mf)
If)
0
•*H
1
10.6 10.8 11.0 11.2 11.4
Time (min.)
56
-------
Data File: /chem/V.1/08-22-97.b/VG141.d
Date : 22-AUG-97 13:34
Instrument : V.i
Sample ID : M23-OUTLET-RUN 1
Column phase : DB-5
Volume Injected (uL) : 1.0
46 2-Methy1naphthalene
Page 12
Column diameter : 0.32
Scan 1348 (12.358 mm) of VG141.d
.
2.0-j
1.8-j
1.5-j
Sl*0-=
3 0.8-1
^0.5-i
0.2-1
0.0J
Ui
.1 .il... i| ,il.[ r.!|l i[.i..i...i.i.l I...I.L. ........... l. ....... 11
1
1.. ii
40 60 80 100 120 140 160 180
Mass/Charge
2.0-j
1.8-1
1.5-:
£^'21
ol. 0-1
-0.8-
^0.5-
0.2-j
0.0-
Scan 1348 (12.358 mm) of VG141.d (Subtrac
41 i 1 t . >
:ted)
. ii . .
1 I ' ' ' r^
40 60 80 100 120 140 160 180
Mass/Charee
8.0-
xxG.O-J
o -
^4.0-
""
0.0^
46 2-Methy 1 naphthalene (PBM Reference Sp«
il 1 ll , n i i. i.l .1
^ctrum)
40 60 80 100 120 140 160 180
Mass/Charee
Scan 1348 (12.358 min) of VG141.d (Z DIFFERENCE)
100-q
75-j
50-j
25-j
S-25-!
**
-50-j
-75-j
"' ' " 1 '
10U-1 | — i — i — ' — : — i — i — • — | — i • ' i • .- • ] • • • | • • • | • • • |
40 60 80 100 120 140 160 180
Mass/Char?e
Mass 142.00
i
2.0-i
1.8-:
1.6-j
1.4-j
S1.2-!
Sl.OH
X
*-* Q gj
0.6-:
0.4-i
0.2-j
-a
ro
CM
TH *-t
K
cvl
'
1
1
., 11
12.0 12.2 12.4 12.6 12.8
Time (min.)
Mass 141.00
.
'
1.6-j
1.4-:
1.2-
S l-'®~
0 . 0
3 ' :
0.4-
0.2^
J\ /\J~^—*_s~\1
-a
ro
CN ^-1
^ ffi
S
i
_i .-.
12.0 12.2 12.4 12.6 12.8
Time (min.)
*- •»
-------
Data File: /chem/V.i/OS-22-97.b/VG141.d
Date : 22-flUG-97 13:34
Instrument : V.i
Sample ID : M23-OUTLET-RUN 1
Column phase : DB-5
Volume Injected < . j > < > i ,
?d)
. j i . i | i
40 60 80 100 120 140 160 180
Mass/Charee
56 flcenaphthylene (PBM Reference Spectrum)
.
"
8.0:
-6.0-
ro
§4.0:
~ ;
2.0:
o.o:
,i iii , „ .1
i ' ' • i ' * ' i • • • i • ' • t * • • i '
i ! . . . i > <
40 60 80 100 120 140 160 180
Mass/Charge
Scan 1599 (14.159 mm) of VG141.d -°'4i
0.3-i
0.2-j
o.i-i
L ID
•^
ft T
A7V\A^
13.8 14.0 14.2 14.4 14.6
Time (mm.)
Mass 151.00
^
2.2-.
2.0-
1.8-
1*4-
~ * ;
J1.2-
31.0-
^0.8-
0 6-
v» t»
0.4-
0.2^
0 0-
A .I A
A/VUW
—
s
3
A
A
_Ww v\
13.8 14.0 14.2 14.4 14.6
Time (min.)
Mass 153.00
2.5-j
2.2-i
2.0-;
1.8-i
^i.s-i
Si 2-
X :
-i.o-:
>_
•
<*
S j
S
i t
ll.
o.aif JU M /III
1
°*5I I l\ \
H v VlALLw v\
0.0 ^ i i | i i i | i i i | i i i i'' i i i i
13.8 14.0 14.2 14.4 14.6
Time (mm.)
-------
Data File: /chem/V.i/08-22-97.b/VG141.d
Date : 22-AUG-97 13:34
Instrument : V.i
Sample ID : M23-OUTLET-RUN 1
Column phase : DB-5
Volume Injected '-
X i»^ -
•^f
>-0.8-i
•
0.4-;
0 0--1
1
Ill
40 60
~~i
80
i.J,
it
ihlllll,,,,,
100
lij . 1
.iilihi). . i,l,|llli|l,i.|, ,.^1,1.1 |,|J|
.iilHtill.ll... 1. ... . ,.,.., .
120 140 160 180 200
Mass/Charee
(14.519 min) of VG141.d (Subtracted)
'i1 i
100
i
ii , ,|l
120 140 160 180 200
Mass/Charee
58 flcenaphthene (PBM Reference Spectrum)
8.0^
xx 6.0-|
o
34.0-
>- :
2.0-
1
,1 ,1. li
40 60
80
!
100
i Ml
120 140 160 180 200
Mass/Charee
Scan 1649 (14.519 min) of VG141.d (2 DIFFERENCE)
"si
501
.
i of-
£ -25-
X '•
-75-;
- ,,' M' 'MM
T '"
40 60 80
i., .
11 i "~
100
' " "'[I1' "•
-i i i iii | i i • i ... i i i i — |— i
120 140 160 180 200
Mass/Charse
Mass 154.00
2.4-
2.2-
2.0-
1.8-
1.6-
xx 1.4-
< 1 O
3i.o-
>-0.8-
0.6-
0 4-
V * *T
0 0 "
LA WS. fj
— OJ
*
T-(
t f\
i\ A fl A
WAMA/VV^ ' •* mil V *V
14.2 14.4 14.6 14.8 15.0
Time (min.)
Mass 153.00
2.5":
2.2-i
2,0-i
i.s-i
xxi,5-i
Si 9 ^
X :
-1.0-:
0.8H
0.5-i
0.2'H
0 0-
— o^
So
i ^
;
II I
1 [11 i ft
K A! n
\j I / y v Vv y1
v 'W^^VL-^3
14.2 14.4 14.6 14.8 15.0
Time (min.)
Mass 152.00
i.o-i
0.9-i
°-8i
0.7-j
S 0.5-1
X ;
^0.4H
0.3-1
0.2-1
0.1-j
N^J
T-H
in
^
1
/ti
U.W . . . | , , . | , , , | , , , , , ..,
14.2 14.4 14.6 14.8 15.0
Time (min.)
5.1
-------
Data File: /chemA>.i/08-22-97.b/VG141.d
Date : 22-AUG-97 13:34
Instrument : V.i
Sample ID : M23-OUTLET-RUN 1
Column phase : DB-5
Volume Injected (uL) : 1.0
65 Fluorene
Page 16
Column diameter : 0.32
7.0-
6.0-
5.0-
= 4.0-
3.0-
1.0-3
0.0-
5.0-
4.0-1
1.0-;
0.0-
8.0-
.6.0-
)
2.0:
0.0
40
100 -
75-j
50-j
254
3-25-I
ft -
-50-;
-754
-100-V
40
Scan 1796 (15.577 min) of VGWl.d
4-
40 60 80 100 120 140 160 180 200 220
Hass/Charge
Scan 17% (15.577 min) of VG141.d (Subtracted)
40 60 80 100 120 140 160 180 200 220
_^ Hass/Charge
65 Fluorene (PBM Reference Spectrum)
60
80 100 120 140 160 180 200 220
Mass/Charge _
Scan 1796 (15.577 min) of VG141.d (2 DIFFERENCE)
„..., .il. ~al... .-Hi ,J_.._.llil ...Ju ^Ji... ......
60 80 100 120 140 160 180 200 220
Mass/Charge
Mass 166.00
15.20 15.40 15.60 15.80 16.00
Time (min.)
Mass 165.00
15.20
15.40 15.60
Tine (min.)
15.80 16.00
Mass 167,00
15.20 15.40 15.60 15.80 16.00
Time (minfj
-------
Data File: /chem/V.i/08-22-97.b/VG141.d
Date : 22-flUG-97 13:34
Instrument : V.i
Sample ID : M23-OUTLET-RUN 1
Column phase : DB-5
Volume Injected - I
1.0-
0.0-
1
,11 .. 1,1 , ...il.,.,..!!. , ... ..... . , 1 ,,!
T ' ' ' 1 ' ' ' I . I , i i . | i , i , i "i i , . . i , . . . , i i i | i i
40 60 80 100 120 140 160 180 200 220
Mass/Charee
Scan 2066 (17.525 min) of VG141.d (Subtracted)
-
4.0-^
-
3.0-:
£ :
S2'0":
*"l.O^
0.0-
j
i
,, ,. ,.l „ , ,1 ,.,ll ll. I .
1 ' ' < |"T I' 'I1 | l""l I 'T 1 l'"l |"l" 1 1 | 1 ""1 [III 1 1 1 | 1 1 , | . .
40 60 80 100 120 140 160 180 200 220
Mass/Charee
8.0:
-,6.0:
co
|4.0^
s-
2.0:
0.0:
73 Phenanthrene (PBM Reference Spectrt
1
itn)
. ,. „ ,1 .,ll . ll .III
40 60 80 100 120 140 160 180 200 220
Mass/Charee
Scan 2066 (17.525 min) of VG141.d (2 DIFFERENCE)
100-
75 "I
50 -i
25 -f
i °"i
S-25-;
**-50-i
-75 -j
-100 :
' — -- -
40 60 80 100 120 140 160 180 200 220
Mass/Charee
Mass 178.00
4.4-
4.0^
3.6-
3.2-i
2.8-i
£2.44
S 0 -
ti.6\
1.2-i
0.8^
0.4-i
'J
8
t*^
^
d/V
17.20 17.40 17.60 17.80 18.00
Time (dirt.)
Mass 179.00
7.0-
6.0-
5.0-
— .
J4.0-
-3.0-
2.0-j
i.a-j
0^
^.t^^^^^M
"S
*
A^v
(X^-uJ^^—v^-
.0 'i i i | i i i | i ' i i i i i | i '' 1
17.20 17.40 17.60 17.80 18.00
Tim* (nin.)
Mass 176.00
8.0-
7.0-
6.0-
^5.0-
j*" ~.
S4.0-
X ;
^3.0-
2.0-i
"
i.o-i
iJ
"S
^
l/V-^., , i
17.20 17.40 17.60 17.80 18.00
Time (min.)
61
-------
Data File: /chem/V.i/08-22-97.b/VG141.d
Date : 22-fKJC-97 13:34
Instrument : V.i
Sample ID : M23-OUTLET-RUN 1
ColuNi phase : DB-5
Volume Injected : 1.0
74 flnthracene
Page 10
Column diameter : 0.32
2.0-i
:
1.6-
pl.2J
o ;
3 0.8:
0.4-;
Scan 2080 (17.626 min) of VG141.d
1.
nil
till lib kllllll 1 i i 1 ii , ii i
40 60 80 100 120 140 160 180 200 220
Mass/Charse
1.2:
•
1.0-i
3°-8~i
00.6:
X
~0.4:
0.2:
0.0-
Scan 2080 (17.626 min) of VG141.d (Subtracted)
i
1
II flii L ,uB Ii . luiJ i. , LL . ,.. b LI. Nil, , 1 ..m.l
J. Ii, . ,. .,,
ii, f.v ,i. inp i)ii 1.1,111, ,.i| i, i,. , ij up., ., . |. ,,i ri,i ! T fi.1,11 ( ,,,,,,,!,,
40 60 80 100 120 140 160 180 200 220
Hass/Charee
8.0-J
g«-H
§4.0:
>. :
2.0:
74 finthracene (PBH Reference Spectrun
Ji
)
J Jill
40 60 80 100 120 140 160 180 200 220
Mass/Charee
Scan 2080 (17.626 min) of VG141.d (Z DIFFERENCE)
100-3
751
501
25-j
**-»•!
-75-1
1
t ,JI MuU...^.^ u , LL . *.j..bi. .4,^... .A.AJJJ. IL ii
40 60 80 100 120 140 160 180 200 220
Hass/Charee
4.4-=
4.0-:
3.6^
3.2-=
?2*4^
32-°i
.
1.2-:
0.8-^
0.4-E
0.0-
Mass 178.00
1
1
CM
1 5
l?
' ^i^1 r i
i i i | i i i | i 'i inj r i P|"i i i |
17.20 17.40 17.60 17.80 18.00
Time (win.)
8.0-i
7.0-i
:
6.0-i
~ 5.0:
0 ''
X
2.0-i
Mass 176.00
f— If)
O f^.
8 'H
I
. . d
.
L.
17.20 17.40 17.60 17.80 18.00
Time (min.)
Mass 179.00
7.0-i
6 A
.0:
*,
5.0:
?4.0-
o :
^< :
-3.0-|
2.0-:
1.0-i
0 0-
r§
1 "*
r\^rrrrrr-rr
1
LAjVv^,
17.20 17.40 17.60 17.80 18.00
Time (min.)
-------
Data File: /chem/V.1/08-22-97.b/VG141.d
Date : 22-ftUG-97 13:34
Instrument : V.i
Sample ID : M23-OUTLET-RUN 1
Column phase : DB-5
Volume Injected ~2.0-
* ~:
~rY--.r\-*— ^.-j)
19.6 19.8
s
8
8*
20.0 20.2 20.4
Time (min.)
Mass 101.00
1.1-!
1.0-1
0.9^
0.8-1
07 -
./-
— :
o E
0.3H
0.2^
0.1-:
0.0-3
i— % ^*
1 "r
1 °;
T-l
88
l\ ro
II •
8
1 i
1"
ii i i >
19.6 19.8 20.0 20.2 20.4
Time (min.)
Mass 100.00
8.0-i
7.0^
6.0-i
^5.0-j
ro '•
<
x :
^3.0-
2.Q-.
1.Q-.
0.0-^
?>
°"
11 ^^ ^^
I s
0
II CM
n [n n h
[ i
19.6 19.8 20.0 20.2 20.4
Time (min.)
63
-------
Data File: /chem/V.i/08-22-97.b/VG141.d
Date : 22-AUG-97 13:34
Instrument : V.i
Sample ID : M23-OUTLET-RUN 1
Column phase : DB-5
Volume Injected (uL) : 1.0
78 Pyrene
Page 20
Column diameter : 0.32
3.5^
3.0-j
2.5H
Q2.0-J
o :
X I*'3"
^l.O-j
0.5-j
"
:
3.2-:
2.8-:
2.4-1
52.0-j
<3 1 fi-
Si^-j
'"o.s-
0.4-j
8.0:
-.6.0-
ro
<
o -
'xM.O-
^^
*~2.0-^
0.0-
100-
754
50 -1
25 i
<=-25-j
~-50 -j
-75 -j
-100-
Scan 2463 (20.388 min) of VG141.d
| i
1 i 1 1 1 1 1 1 1
i , ,nl , , I ll ,J 1 ill III, II, 1,11 Illlll, ,llli M. , lilHI|Hli.i.i.|.l.l m.l i.l,l!..i 1 1 -IJy . , ill. ii... nil l,i i ,il
40 60 80 100 120 140 160 180 20
Mass/Charee
Scan 2463 (20.388 mm) of VGMl.d (Subtracted)
ll
, ,l 1 i i... ...nil. .ll.iiilli . . • • • . . .j. ... ....... . ..Li. .(.. H IL il
40 60 80 100 120 140 160 180 20
Mass/Charge
78 Pyrene (PBM Reference Spectrum)
j
40 60 80 100 120 140 160 180 20
Mass/Charge
Scan 2463 (20.388 min) of VGWl.d (2 DIFFERENCE)
u
*l i i i I i i ' l ' ' ' I ' • • i • • • i • • • i • • • i • • • i
40 60 80 100 120 140 160 180 20
Mass/Charge
ll ' ,' , >i'
0 220
ii i,
0 220
I
, .
1 ' • r
0 220
u u.
0 220
6.0-
5.0-
-, *-0"
<
Ss.o-
>•
2.0-
1 c\-
i.y
:
1.1~
1.0-1
0.9-i
0.8-j
07^
.1 .
o ;
jo.5-
0.3-j
0.2-i
y * v
8. Or
7.0-
6.0-
_5.0-i
tf> ".
<
x :
^3.0-
2.0-
1.0-
0 0-
V# V
Mass 202.00
—CM
5
^H
GO
"i
O
CM
1
_|
20.00 20.20 20.40 20.60 20.80
Time (min.)
Mass 101.00
1
'
|
1
,1 \ ML ft flU JU A
1 | ' ' ' 1 ' ' ' 1 ' ' ' 1 ' ' ' 1 '
20.00 20.20 20.40 20.60 20.80
Time (mm.)
Mass 100.00
IS
OO
ro
CM
i
1
1
A
II
1
Jl Jl J| | 1 ty
20.00 20.20 20.40 20.60 20.80
Time (min.)
64
-------
Data File: /chern/V. 1/08-22-97.b/VG141.d
Date : 22-SUG-97 13:34
Instrument : V.i
Samcle ID : M23-OUTLET-RUN 1
Column phase : DB-5
Volume Injected — 3
0.2-3
n n3'
II
1
, ll ill llliMliyilLiiUd.,iiiiii,,ik ,in HI HI „
j
1
40 60 80 100 120 140 160 180 200 220 240 260
Mass/Charee
Scan 2816 (22.919 min) of VG141.d (Subtracted)
6.0-3
5.0-2
? * 1
S3.0-3
•2 3
3.2.0-3
1.0-3
]
iii i i , , , .ii i .
0.0 '; i i '' i i i i i i i i i ' ' ' I ' ' ' i ' ' T~r ' • ' i ' ' ' i ' • • i
40 60 80 100 120 140 160 180 200 220 240 260
Mass/Charee
84 Chrysene (PBM Reference Spectrum)
i
8.0-j
.-,6.0-
ro * •
o -
34.0-
^~ 2.Q-
.
-
j
1
|.
il I i>
II III ... .1,1 J
i
0.0 '| i i' i | r | i i i | i i i | i i i | i i i | i i i | ••• T--T- •• • i • • •
40 60 80 100 120 140 160 180 200 220 240 260
Mass/Charee
Scan 2816 (22.919 min) of VG141.d (Z DIFFERENCE)
100 -3
75 -i
50-1
25-
u. 0-!
£-25-
~-50-
-75 -
n ''V L • ' • '- •' - -" ^ -"r
-100 T | i i i | i i i | i i i i i i i i i i i i i i i i i ' ' i ' ' ' i ' ' ' I ' ' ' i ' ' ' i
40 60 80 100 120 140 160 180 200 220 240 260
Mass/Charee
8.0^
7.0-
6.0-i
^5.07
<
X ' '•
^3.0-
2.0-
1.0-
\
Mass 228.00
Hi
n ^
fl
1
Jf
J
1
1
22.6 22.8 23.0 23.2 23.4
2.4-:
2.2-!
2.0-1
i
i.8-i||l
Lfil
Sl.4|
sl-2i
^O 8-
0.6^
0.4-i
Ol2-=
n r\ "'
]
22.
2.0-;
1 O
1.3-
1.6-
1.4-
_1.2-
^1.0-
3o,8-
"0.6-
0.4-
0.2-
O.Q 1| i i i
22.4 22
Time (min.)
Mass 226.00
6 22.8 23.0 23.2 23.4
Time (min.)
Mass 229.00
S'
* •
1 ~
l|g
I II L^
1 r
P
.6 22.8 23.0 23.2
Time (min.)
-------
Data File: /chem/V.i/08-22-97.b/VG141.d
Date : 22-flUG-?7 13:34
Instrument : V.i
Sample ID : M23-OUTLET-RUN 1
Column phase : DB-5
Volume Injected (uL) : 1.0
86 Benzo(b)fluoranthene
Page 23
Column diameter : 0.32
Scan 3114 (25.051 mm) of VGWl.d
8.0-j
7.0-i
6.0-i
£5.0-1
< :
S4.0-;
^o-i
l.O-i
0.0J
ll 1
1 1
_li L
i ' ' i ' •
i i, . i i , i i i , i , , ,
III llilill mil i Him lil ii ill in
i i i i i * , i i i , i i i i i i i i i i i i i i i | i
40 60 80 100 120 140 160 180 200 220 240
Mass/Charee
3r- -
.5-
3.0-1
2.54
^* i
o * :
31.5-:
9-1.0-j
0.54
Scan 3114 (25.051 mm) of VGWl.d (Subtracted)
i
iji i ii ii .11 i ii i.
.1 II
1. if ,111,11111 Hi 1. Ill), il
40 60 80 100 120 140 160 180 200 220 240
Mass/Charge
86 Benzo(b)fluoranthene (PBM Reference Spectrum)
8.0:
-
x.6.0-
ro
<
34.0-
~ ;
2.0:
• ll 1
. .„ ,11 II ..!,. Ill,
40 60 80 100 120 140 160 180 200 220 240
Mass/Charee
Scan 3114 (25.051 mm) of VGWl.d (Z DIFFERENCE)
lOOq
75-
50-
25-1
£ o4
« 25
~-50^
-75-
... ii . i
1 . „ ., II ,,,,,i,l kill, L Ilk ,i ... ^ .^
40 60 80 100 120 140 160 180 200 220 240
Mass/Charee
Mass 252.00
4.44
4.o4
3.e4
3.2-:
o 2.4-
S2.o4
>-1.6-
1.2--
o.a4
0.44
0 0~
i S'
1 ^
JJ
1
II
i
24.60 24.80 25.00 25.20 25.40
Time (min.)
Mass 253.00
i 1 1
* :
I.Q:
* :
0.8-
^0.7-j
^0.6-i
30.5-
0.3-
0.2-
0.1-
0 0-
1 0
in*
II (M
I
1
i
ii
24.60 24.80 25.00 25.20 25.40
Time (mm.)
Mass 125.00
2C '
*3 .
2.24
2.04
1 1
Ut i Hfr i.
i.84i\,|i|i||ii jij \m ii
-i.sjlvy I iflflM liriniWall h.
s^j ryilillrllUlil'iliyii
x :
o.s4
0.54
0.24
0 0-
i M ii r I'nn i
24.60 24.80 25.00 25.20 25.40
Time (min.)
66
-------
Data File: /chem/V.i/08-22-97.b/VG141.d
Date : 22-AUG-97 13:34
Instrument : V.i
Sample ID : H23-OUTLET-RUN 1
Column phase : DB-5
Volume Injected fluoranthene
Page
Column diameter : 0.32
1
8.0-J
_6.0-
ro
}-.
S4.0-
X
^2.0^
40
1.2-i
i.o-
S0.6-
w
X
~0.4-
^-
0 2-
v.t
• 0~l
I '' ' '
40
8.0-
P5
§4.0-
>—
2.0-
40
i
1
60
1 i '
60
60
Scan 3121 (25.101 min) of VG141.d
I
M t! 1 1 i 1 i i
jiU|llfiiil[U|| HI | 1
80 100 120 140 160 180 200
Hass/Charee
Scan 3121 (25.101 min) of VG141.d (Subtracted)
, i
1 In 1
i i
1
l
1
ni)i
Ijiiii i
P -|!i 1
80 100 120 140 160 180 200
Hass/Charee
220 240
220 240
87 Benzo(k)fluoranthene (PBH Reference Spectrum)
J
80 100 120 140 160 180 200
Hass/Charee
1
"P
220 240
Scan 3121 (25.101 min) of VG141.d (Z DIFFERENCE)
100 -g
75-f
50-j
25-j
£ 0-j-
-*M •
«-25-i
**-50-^
-754
-100 T| i i i
40
60
1 J ll 1 1 1 1
_ii. u i iJiiJii.i i i
i
80 100 120 140 160 180 200
Mass/Charge
• - J,
220 240
Hass 252.00
4.8-d
4.4-!
4.0-i
3.6-i
3.2-1
2 8-
r*> :
^2.4-
^lis-i
1.2-i
0.8-i
0.4-;
0 0-
ft
I
•^
.«
i m
F
1
I
24.60 24.80 25.00 25.20 25.40
Time (win.)
Hass 253.00
1.1-
1 0-
x.v .
0.9-
0.8-
0 7-
"• ' .
o *
30.5-
s-0.4-
0 3-
v«w
0.2-
0 0-
fi
II CSI
\\
1
1'
24.60 24.80 25.00 25.20 25.40
Time (min.)
Hass 125.00
2cJ
.0"
z.z-
2.0-
1 1 , ira
n 1 1 L Rli \*
1 1 Hi i IFIB i.
i.8-ifj|iiin it] inn ltu i
->1.5-f Mill Irllnhlll UllnlralWji ll 11.
§1.2-1
x * :
0 8-
v.a .
0.5-
0.2-
PlffF "'IW
24.60 24.80 25.00 25.20 25.40
Time (min.)
67
-------
V
Project Number 42299Bnl
Sample File: VG142
Client Project: Iron &SteeI
i|H T TT*V 'ifff^ /"•!•• f^ A" • T*fc
TLJ ID: x73"6T*ZnB*O'"
Analyte
Naphthalene-d
Naphthalene
2-Methylnaphthaiene
Acenaphthene-d
2-Chloronaphthalene
Acenaphthylene
Acenaphthene
Fluorene
Phenanthrene-d
10
Phenanthrene
Anthracene
Fluoranthene
Chrysene-d
Pyrene
Benzo(a)anthracene
Chrysene
Pervlene-d
' 12
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Benzo(e)pyrene
Benzo(a)pyrene
Perylene
Indeno(l ,2,3-cd)pyrene
D ibenz(a.h) an thracene
Benzo(g,h,i)perylene
..:. . •'•: '; -
• ; Eastetii Research G
Date Received: 0'
"!"%***•* TT.rift^M Atdk.if d ft*
f«*C JuX.lutCI.CU~v
Dilution Factor:
Aaaatttt FtAC
^S
IS 2
245-96 BE
132.58 E
IS 3
U
36.56
16.04
22.93
IS 4
153.06 E
8.94
35.23
IS 5
14.82
2.62 J
5-89
IS 6
5-45
1.02 J
3.50 J
1.16 J
0.30 J
1.09 J
0.40 J
1.55 J
roup
?01»
I8/221S
0.40
-RT;-
10.95
11.03
12.42
14.51
14.21
14.57
15.64
17.54
17.62
17.70
20.01
22.91
20.45
22.89
22.95
26.09
25-10
25.16
25.78
25.91
26.15
28.69
28.75
29.25
Method 8270A MM5
Sample ID: M23-OUTLET-RUN 2
;' . :': ' '.'; Res_pCHR^s(-JSSi!es:;:VCi:134
...
;.•;•'': ENsfc.tinsit:: ."..' : •'. -Quaii, Limit
.'. : ...••:•.....::;:: . ..:V '-?".-'' v :: .-
. -.: .y,:;,:,- ttg .--..,. . ... ttg
4
4
0.16 4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
Reviewed bv
Date S/2SL/!15L
NA- Not Applicable; Det. Limit: Detection Limit; Quan. Limit: Quantitation Limit
IS: Internal Standard; U: Undetected; B: Present In Blank;): Esrinuted- Below Quantitation Limit; E: Estimated- Above Calibration Range
Triangle Laboratories of RTF, Inc
SOI Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-3729 • Fax: (919) 544-5491
Savar v3.5
Printed: 14:26 08/29/1997
-------
Data File: /chen/V.i/08-22-97.b/'VG142,d
Date : 22-ftUG-1997 14:20
Instrument : V.i
Sample ID : H23-OUTLET-RUN 2
Column phase : DB-5
Volume Injected : 1.0
Triangle Laboratories
of RTF, Inc.
Column diameter : 0,32
Page 9
CO
'0.0
/chen/V.i/08-22-97.b/VG142.d (Part 1 of 2)
i • • • ' i
10 11
Time (min.)
18
-------
Data File: /'chem/V.i/08-22-97.b/VG142.d
Date : 22-fiUG-1997 14:20
Instrument : V.i
Sample ID : H23-OUTLET-RUN 2
Column phase : DB-5
Volume Injected (uL) : 1.0
Triangle Laboratories
of RTF, Inc.
Column diameter : 0.32
Paje 10
/chen/V.i/08-22-97.b/VG142.d {Part 2 of 2>
25 26
Time (min.)
-------
\Pil»:US7269S #1-1377 Acqt13-100-1997 03,07,33 OC BI+ VoTtag* JIB 70S Boi**tl7362
276.0939 P:4 BSOB(256,30,-3.0) PKD(15,13,11,0.50\, 69448.0,0.OO\,P,P) SxpsPASS
TSIASOLS LIBS TfJtt: TLI H8TBOD BLANK TLI942299B
100H
so:
40.
201
A2.
^>^^^
20 00
22 s 00
24100
26 tOO
28 tOO
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32iO
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SIX 70S Boll ft 16
288.1552 P:4 BSVB(256,30,-3.0) PXD (IS, 13,11, 0.50%, 65928.0,0. 00\,PfP) SxptPABS
TRIANOL8 LABS TfXtt TLI METHOD BLANK TLI142299B
A4.
80.
60.
40.
20.
8S6
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82
988
34:00
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20:00 22:00 24:00 26:00 28:00 30:00 32':0il
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278.1096 P:4 3SVB12S6, 30,-3.0) PKD(1S, 13, 11, 0. S0\, 101284. 0, 0. 00\,P,P) Exp:PXBS
TRIANQLS LABS Text: TLI METHOD BLANK VLI#42299B
IOCS
80.
60.
401
34:00
9S6
sa
20.
-Vv
20:00 22:00 24:00 25:00 28:00 30:00 32:00
Plla:U97269S #1-1377 Ac
-------
Peak Locate Examination:13-AUG-1997:02:06 File:U972695
Experiment:PAHS Function:3 Reference:PFK
Volts
0.3195
204.96319
204.98882
205.01444
218.95825
218.98563
219.01300
to
-------
File:U972695 #1-294 Acq:13-AUG-1997 02:07:32 GC EI+ Voltage SIR 70S Noise:1787451
128.0626 BSUB(256,30,-3.0) PKD(7,3,1,0.10%, 7149804.0, 0.00%,F,T) Exp:PAH5
Sample Text: TLI METHOD BLANK TLI#42299B File Text:TRIANGLE LABORATORIES , INC
lOOi _&2_95E9
90 J
801
70J
60J
50 J
40J
30J
20 J
10J
0
5:12 5:18 5:24 5:30 5:36
File:U972695 #1-294 Acq:13-AUG-1997 02:07:32 GC EI+ Voltage SIR 70S Noise:48452
136.1128 BSUB(256,30,-3.0) PKD(7,3,1,0.10%, 193808.0, 0.00%,F,T) Exp:PAH5
Sample Text: TLI METHOD BLANK TLI#42299B File Text:TRIANGLE LABORATORIES , INC
100% A6.21E8
90 J
80 J
70 J
60J
50 J
40J
30J
20J
10 J
5:42
Time
5:'l2
5:18
5:24
5:30
5:36
T?42
_4.2E8
_3.8E8
_3.4E8
_3.0E8
_2.5E8
_2.1E8
_1.7E8
-1.3E9
_8.5E7
_4.2E7
O.OEO
Time
CO
-------
File:U972695 #1-294 Acq:13-AUG-1997 02:07:32 GC EI+ Voltage SIR 70S Noise:84215
142.0782 BSUB(256,30,-3.0) PKD(7,3,1,0.10%,336860.0,0.00%,F,T) Exp:PAH5
ample Text: TLI METHOD BLANK TLI#42299B File Text:TRIANGLE LABORATORIES , INC
100% A1.40E8
90 j
80 J
70J
60J
50 J
40J
30J
20J
10 J
A8.01E7
6:24 6:26 6:28 6:30 6:32 6:34 6:36 6:38 6:40 6:42 6:44 6:46 6:48
File:U972695 #1-294 Acq:13-AUG-1997 02:07:32 GC EI+ Voltage SIR 70S Noise:17077
152.1410 BSUB(256,30,-3.0) PKD(7,3,1,0.10%, 68308.0, 0.00%, F,T) Exp:PAH5
Sample Text: TLI METHOD BLANK TLI#42299B File Text:TRIANGLE LABORATORIES , INC
100% A3_^4E8
90 j
80 j
70J
60J
50 J
40J
30J
20 j
10J
6:*24 ' 6:'26
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L6.4E7
L5.7E7
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L3.5E7
L2.8E7
L2.1E7
L1.4E7
L7.1E6
6:50
O.OEO
Time
6:28 6:30 6:32
6:34 ' 6:36
6:38 6:40
6:42 6:44 6:46 6 :48 6:50
1.8E8
L1.7E8
_1.5E8
_1.3E8
-1.1E8
-9.2E7
L7.3E7
L5.5E7
L3.7E7
^1.8E7
O.OEO
Time
-------
>ile:U972695 #1-535 Acq:13-AUG-1997 02:07:32 GC EI+ Voltage SIR 70S
L52.0626 F:2 Exp:PAH5
Sample Text: TLI METHOD BLANK TLI#42299B File Text : TRIANGLE LABORATORIES
100%
INC
B01
80J
70J
60J
50J
40J
30J
20J
10J
A1.04E7
8:20 8:22 8:24 8:26 8:28 8:30 8:32 8:34 8:36 8:38 8:40 8:42
Mle:U972695 #1-535 Acq:13-AUG-1997 02:07:32 GC EI+ Voltage SIR 70S Noise .-46020
.60.1128 F:2 BSUB(256,30,-3.0) PKD(7,3,1,0.10%, 184080.0,0.00%,F,T) Exp:PAH5
Sample Text: TLI METHOD BLANK TLI#42299B File Text:TRIANGLE LABORATORIES , INC
LOOi A7.78E8
8:44
_6.6E6
L5.9E6
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L4.6E6
L3.9E6
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L2.6E6
L2.0E6
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L6.6E5
LO.OEO
Time
8:20 8:22 8:24 8:26 8:28 8:30 8:32 8:34 8:36 8:38 8:40 8:42 8:44
Time
"35"
C/l
-------
File:0972695 #1-535 Acq: 13-AUG-1997 02:07:32 GC EH- Voltage SIR 70S
154.0782 F:2 Exp:PAH5
Sample Text: TLI METHOD BLANK TLI#42299B File Text : TRIANGLE LABORATORIES , INC
100& A2 . 18E7
90 J
80 J
70J
60 J
50J
40J
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164.
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100%
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80 J
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:U972695 #1-535 Acq: 13-AUG-1997 02:07:32 GC EI+ Voltage SIR 70S
1410 F:2 Exp:PAH5
le Text: TLI METHOD BLANK TLI#42299B File Text : TRIANGLE LABORATORIES , INC
8:47
A
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2.8E8
_2.5E8
-2.2E8
_1.9E8
L1.7E8
-1.4E8
_1.1E8
_8.3E7
-5.5E7
_2.8E7
O.OEO
Time
-------
File:U972695 ttl-294 Acq:13-AUG-1997 02:07:32 GC EI+ Voltage SIR 70S Noise:12612
169.0676 8308(256,30,-3.0) PKD(7,3,1,0.10%, 50448.0,0.00%,F,T) Exp:PAH5
Sample Text: TLI METHOD BLANK TLI#42299B File Text:TRIANGLE LABORATORIES , INC
100% A2.64E8
90J
80J
70J
60 J
50 J
40J
30J
20 J
10J
OJ
T
T
T
T
T
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7:22 7:24 7 :'26 7:28 7:'30 7 :'32 7:'34 7:'36 7:'38 7:40 7 :'42
File:U972695 #1-294 Acq:13-AUG-1997 02:07:32 GC EI+ Voltage SIR 70S Noise:7907
171.0648 BSUB(256,30,-3.0) PKD(7,3,1,0.10%, 31628.0,0.00%,F,T) Exp:PAH5
Sample Text: TLI METHOD BLANK TLI#42299B File Text:TRIANGLE LABORATORIES , INC
100% A8.Q2E7
90 J
80J
70J
60 J
50 J
40 j
30J
20J
10 J
OJ
7:22
7:24
7/26
_3
7:30 ' 7 :'32 ' 7:'34 ' 7:'36 ' 7:'38 ' 7:40 ' 7 :*42
1.2E8
1.1E8
9.7E7
8.5E7
.7.2E7
.6.0E7
4.8E7
.3.6E7
.2.4E7
.1.2E7
.O.OEO
Time
3.7E7
3.3E7
OE7
2.6E7
2.2E7
1.9E7
5E7
LIE?
7.4E6
3.7E6
O.OEO
Time
_1
-------
File:U972695 #1-294 Acq:13-AUG-1997 02:07:32 GC EI+ Voltage SIR 70S
162.0236 Exp:PAH5
Sample Text: TLI METHOD BLANK TLI#42299B File Text:TRIANGLE LABORATORIES
lOOi A4.16E5
90 J
80 j
70J
60 J
50 J
40 j
30J
20 J
10J
OJ
, INC
6:36 6:48 7:00 7:12 7:24 7:36
File:U972695 #1-294 Acq: 13-AUG-1997 02:07:32 GC EI+ Voltage SIR 70S
164.0207 Exp:PAH5
Sample Text: TLI METHOD BLANK TLI#42299B File Text : TRIANGLE LABORATORIES
100*
90 J
80 J
70J
60 J
50J
7:48
, INC
30
20J
10 J
0
A1.48E5
1 1 r-
6:36
6:48
7:00
7 :
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7:24
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7:'48
.2.4E5
.2.2E5
.1.9E5
.1.7E5
.1.4E5
.1.2E5
.9.6E4
.7.2E4
.4.8E4
.2.4E4
.O.OEO
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.3.0E5
.2.7E5
.2.4E5
.2.1E5
.1.8E5
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-1.2E5
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Time
CO
-------
File:U972695 #1-535 Acq:13-AUG-1997 02:07:32 GC EI+ Voltage SIR 70S
178.0782 F:2 Exp:PAH5
Sample Text: TLI METHOD BLANK TLI#42299B File Text:TRIANGLE LABORATORIES , INC
10
12:12 12:24 12:36 12:48 13:00 13:12 13:24 13:36 13:48
File:U972695 #1-535 Acq:13-AUG-1997 02:07:32 GC EI+ Voltage SIR 70S
188.1410 F:2 Exp:PAH5
Sample Text: TLI METHOD BLANK TLI#42299B File Text:TRIANGLE LABORATORIES , INC
12_
Bl
el
2l
12:12 12:24 12:36 12:48 13:00 13:12 13:24 13:36 13:48
1.4E7
.1.3E7
.1. 1E7
.9.0E6
.7.2E6
.5.4E6
.3.6E6
.1.8E6
.O.OEO
Time
4.4E7
3.9E7
3.3E7
2.8E7
2.2E7
-1.7E7
ll.lE7
5.5E6
O.OEO
Time
CO
-------
File:U972695 #1-703 Acq:13-AUG-1997 02:07:32 GC EI+ Voltage SIR 70S
228.0939 F:3 Exp:PAH5
Sample Text: TLI METHOD BLANK TLI#42299B File Text:TRIANGLE LABORATORIES , INC
100%
95 J
90 J
85J
70 J
65 J
60 J
55 J
50J
45J
40J
35J
30J
25 j
20J
15 J
10J
0
A3.04E6
1 IT 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1—I 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1
19:00 19:06 19:12 19:18 19:24 19:30 19:36 19:42 19:48
1.6E6
U.5E6
L1.4E6
_1.3E6
_1.3E6
-1.2E6
_1.0E6
_9.4E5
_8.6E5
.7.8E5
_7 . 1E5
_6.3E5
_5.5E5
_4.7E5
-3.9E5
_3.1E5
_2.4E5
_1.6E5
L7.8E4
.O.OEO
Time
U!
CD
-------
File:U972695 #1-1377 Acq:1J-AUG-1997 02:07:32 GC EI+ Voltage SIR 70S
276.0939 F:4 Exp:PAH5
Sample Text: TLI METHOD BLANK TLI#42299B File Text:TRIANGLE LABORATORIES , INC
A4.91E6
30:00 31iOO 32iOO
File:U972695 #1-1377 Acg:13-AUG-1997 02
288.1692 F:4 Exp:PAH5
Sample Text: TLI METHOD BLANK TLI#424
A4 .
90J
80J
70 j
60J
50 J
40 J
30J
20 j
10J
3ooO
31:00
32lOO
33:00 34:00
:07:32 GC EI+ Voltage SIR 70S
99B File Text:TRIANGLE LABORATO
18E8
35:00
WES , INC
A3.:ilE8
.3.1E5
.2.8E5
.2.5E5
.2.2E5
.1.8E5
.1.5E5
.1.2E5
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.6.2E4
.3.1E4
.O.OEO
33:00
1 - 1 - r
34:00
35:00
Time
2 . 1E7
1.9E7
1.7E7
1.5E7
.1.3E7
1.1E7
8.4E6
6.3E6
4.2E6
2.1E6
O.OEO
Time
cn
-------
File:U972695 #1-1377 Acg:13-AUG-1997 02:07:32 GC EI+ Voltage SIR 70S
278.1096 F:4 Exp:PAH5
Sample Text: TLI METHOD BLANK TLI#42299B File Text:TRIANGLE LABORATORIES
100$ 25:47
INC
'27|00 28:00 29iOO 30iOO 31iOO 32iOO 33100 34iOO
File:U972695 #1-1377 Acq:13-AUG-1997 02:07:32 GC EI+ Voltage SIR 70S
292.1974 F:4 Exp:PAH5
Sample Text: TLI METHOD BLANK TLI#42299B File Text:TRIANGLE LABORATORIES , INC
100% 32;32
90 j
80 j
70J
60J
50 J
40 J
30 J
20 J
10J
0
35:00 Time
26:00
27:00
28:00
29:00
30:00
31:00
32:00
33:00
34:00
35
-------
File:U972695 #1-1377 Acq:13-AUG-1997 02:07:32 GC E3> Voltage SIR 70S
278.1096 F:4 Exp:PAH5
Sample Text: TLI METHOD BLANK TLI#42299B File Text:TRIANGLE LABORATORIES ,
25:47
INC
I ' ' '
33:00
26:00 27:00 28:00 29100 30iOO 31iOO 32100
File:U972695 #1-1377 Acq:13-AUG-1997 02:07:32 GC EI+ Voltage SIR 70S
292.1974 F:4 Exp:PAH5
Sample Text: TLI METHOD BLANK TLI#42299B File Text:TRIANGLE LABORATORIES ,
100% A2.63E8
90 j
80 j
70J
60J
50 J
40J
30J
20J
10J
ol
34:00
INC
26:00 27:00
28:00
29:00
30:00
31:00
32:00
33:00
34:00
35
35
OT
-------
in
rile:U972695 #1-1377 Acq:13-AUG-l9~97 02:07:32 GC El+~WTtage SIR 70S
52.0939 F:4 Exp:PAH5
lample Text: TLI METHOD BLANK TLI#42299B File Text:TRIANGLE LABORATORIES , INC
100%. 23t26 i
23:00
'ile:U972695 #1-1377 Acq
:64.1692 F:4 Exp:PAH5
Jample Text: TLI METHOD
L00% 23
90 j
80l
70J
60^
50 J
30^
20J
10 j
0
24:00 25:00
-AUG-1997 02:07:32 GC EI+ Voltage SIR 70S
TLI#42299B File Text:TRIANGLE LABORATORIES , INC
24:54
25:19
24:36
23:00
24:00
25:00
26:00
1.2E8
L1.1E8
Ll.OES
L8.7E7
L7.5E7
L6.2E7
L5.0E7
L3.7E7
L2.5E7
L1.2E7
O.OEO
Time
-------
TLI Project:
Client Sample:
42299B
M23-Outiet-Run
PAHJ Analysis (a)
Analysis File: U972698
Client Project:
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
Iron & Steel-Chicago
MM5 Date Received:
173-61-1A-D Date Extracted:
Date Analyzed:
1.000
n/a
DB-5
Dilution Factor:
Blank File:
Analyst
07/01/97
07/17/97
08/13/97
n/a
U972695
HLM
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPPAHJ10
UPJ8127
U972690
n/a
n/a
n/a
^ra$fe* >'" MM
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
Perylene
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Benzo(a)pyrene
Benzo(e)pyrene
Benz
-------
Data Review By:
Initial
,.Date...
Calculated Noise Area: n/a
Page No.
08/21/97
Listing of O972698B.db£
Matched
-------
Page No.
08/21/97
Listing of O972698B.dbf
Matched <3C Peaks / Ratio / Ret. Tina
Compound/
H.Z.... QC.Log Oniit Why ..RT. OK Ratio Total.Area.. . Area.Peak.l.. Area. Peak. 3. . Rel.RT Confound. Name.. ID.. Flags.
M
MTN
252
dl2-B-b-Pluoran
264 DC
264
I-123-cd-Py
276 DC
DC
DC
DC
DC
DC
DC
DC
DC
M
H
276
21:06
21:22
21:34
23:27
23:35
24:48
25:05
25:32
8 Peaks
NL 0:00
21:59
22:08
23:21
23:28
23:57
24:39
24:57
25:23
8 Peaks
NL 0:00
ML 20:44
WL 21:46
WL 22:13
WL 22:33
WL 22:56
WL 23:19
WL 23:48
WL 24:27
24:44
25:02
25:28
25:53
26:14
26:54
27:32
28:06
30:02
30:36
31:08
31:52
32:38
33:16
33:46
34:04
34:53
17 Peaks
18,888.30
5,814.52
16,297.50
597,000.00
137,000.00
298,282.00
85,229.10
12,557.00
1,171,068.42
124.09
148.60
114. OS
7,327.96
7,604.57
128.73
2,763.93
4,303.72
4,596.09
26,987.66
• Above : B— b— FluO2rafi /
171.59
341.08
637.54
6,785.89
11,939.30
20,958.60
19,388.60
11,268.00
3,687.97
3,471.97
2,414.87
2,382.21
585.78
2,290.42
2,299.36
600.92
1,922.55
931.86
5,844.02
2,837.07
17,967.30
46,200.00
1,532.33
1,260.08
2,847.98
50,500.00
145,388.72
18,888.30
5,814.52
16,297.50
597,000.00
137,000.00
298,282.00
85,229.10
12,557.00
148.60
114.06
7,327.96
7,604.57
128.73
2,763.93
4,303.72
4,596.09
1-123— cd—Pv Follows — —
3,471.97
2,414.87
2,382.21
585.78
2,290.42
2,299.36
600.92
1,922.55
931.86
5,344.02
2,837.07
17,967.30
46,200.00
1,532.33
1,260.08
2,847.98
50,500.00
0.331
0.842
0.850
0.924 B-b-Pluoran AN PR
0.929 B-k-Pluoran AN PR
0.977 B-e-Pyrene AN
0.988 B-a-Pyren« AN
1.006 Perylene AN
0.606-1.394
0.000
0.366
0.872
0.920 d!2-B-b-Fluoran isll
0.924 d!2-B-k-Fluoran is!2
0.944
0.971 d!2-B-e-Pyrene RS3
0.983 d!2-B-a-Pyrene is!3
1.000 d!2-Perylene IS7
0.711-1.289
0.000
0.599
0.628
0.641
0.651
0.662
0.673
0.687
0.706
0.714
0.723
0.735
0.747
0.757
0.777
0.795
0.811
0.867
0.884
0.899
0.920
0.942 I-123-cd-Py AN PR
0.961
0.975
0.984
1.007 B-ghi-Pery AN
Triangle Laboratories, Inc.® Analytical Services Division
801 Cap'rtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 14:37 08/21/97
57
-------
Page No.
08/21/97
Listing of 09726988.dbC
Matched GC Peaks / Ratio / Ret. Tin*
Compound/
M_Z QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1. . Area.Peak.2.. Rel.RT Compound.Name.. ID..
Flags.
DiB-ah-Anth
278
278
d!2-I-123-cd-Py
288
M
288
d!4-DiB-ah-Anth
292
M
292
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
WL
WL
WL
WL
WL
WL
WL
WL
WL
WL
WL
WL
WL
WL
6
NL
2
NL
1
0:00
22:08
23:08
24:01
24:44
25:02
25:27
26:14
26:31
26:53
28:06
28:21
28:28
30:03
30:36
31:08
31:52
32:55
33:17
33:46
34:04
Peaks
0:00
32:26
34:38
Peaks
Abo
0:00
32:37
Peak
Above: I-123-cd-Py / DiB-ah-Anth Follows
281.05
477.19
4,048.72
127.60
3,798.37
2,329.31
2,882.42
5,376.33
171.38
4,834.95
2,799.81
255.10
223.62
338.24
4,227.18
1,646.11 1,646.11
9,933.79 9,933.79
16,100.00 16,100.00
2,810.55 2.810.55
3,805.04 3,805.04
9,266.10 9.266.10
43,561.59
Above: DiB-ah-Anth / d!2-I-123-cd-Py Follows
0.939-1.061
0.000
0.679
0.709
0.736
0.758
0.768
0.780
0.804
0.813
0.824
0.862
0.369
0.873
0.921
0.938
0.955
0.977
1.009 DiB-ah-Anth
281.34
1,980.00
1,595.84
3,575.84
1,980.00
1,595.84
Above: d!2-I-123-cd-Py / dl4-DiB-ah-Anth Follows
391.53
1,740.00
1,740.00
AN
.020
.035
1.044
0.711-1.289
0.000
0.936 d!2-I-123-cd-Py is!4 I
1.000 d!2-B-ghi-Pery IS8
1,740.00
0.939-1.306
0.000
1.000 d!4-DiB-ah-Anth IS9
Column Description.
"Why" Code Description QC Log Desc.
M_Z -Nominal Ion Mass(es)
..RT. -Retention Time (mm:ss)
Rat.l -Ratio of M/M+2 Ions
OK -RO=Ratio Outside Limits
Rel.RT-Relative Retention Time
*«* end of Report ***
WL-Below Retention Time Window
WH-Above Retention Time Window
SN-Below signal to Noise Level
-------
FlJ.»iUS72698 91-295 Aaqt 13-AOG-1997 Oftl4:22 ia»:529089
152.1410 BSUB(256,30,-3.0) PKD(3,1, 10, 0. S0\,2116356. 0, 0. 00*,F,F) Sxp:PABS
TRIANGLE LABS Taurt; H23-OUTLET-RUS-1 TLI#42299B
IOCS
I « i i i i I i i i i"i I i i i i i i i
7:12 7:24 7:36 7:48 8:00
5:'00 5:12 '5:24 ' '5:36 '5:48 ' '6:66 ' '(l:i^S:24 ' '6:36 ' '6:48 ' '7:00
'11»:U972698 #1-295 Actj: 13-AUQ-1997 06:14:22 OC BI+ Voltage SIR 70S
154.9920 Sxp:PAB5
TRIAM2LE LABS Tuct: H23-OUTLET-RUS-1 TLI#42299B
100* 6lS1
80.
60.
40.
20.
0.
7:12 7:24 7:36
7148 8:00
5:06
5:00 s7l2 '5:24 ' '5:36 ' 'Si48
6:24 ' ' 6t36 ' '6:48 ' 'JJ66
'7t24 ' 7J36
7:48 8:00
7S7
4S7
OB7
9S6
4S6
OSO
Tla»
53
-------
Pll*s0972S98 #1-534 Acq, 13-ADO-1997 OS:14:23 K HV Volt*?* SIR 703 Soim»t2940S429i
153.0636 P:2 BSVB(256.30,-3.0) PXO(3,3,9,0.01*,1176217316.0,0.00*,P,P) XxptPABS
TRIAHOLX LABS Tvttt M23-OUTLXT-RUB-1 m#42299B
„ 8 32 B 57 10*33. 13-l?9 ^3l32
9t27
, H I V
so;
601
401
201
0.
BlOO 9:00 10,00 11:00 12:00 13:00
P11»:U972698 #1-534 Aaqtl3-Aa<3-1397 06:14:22 OC XH- Volt*g» SIR 70S So±m»t3451B93
160.1128 Ps3 BSTJB(2S6,30,-3.0) PKO(3,3,9,0.01*,13807573.0,0.00*,P,P) XxptPABS
TRIABQLS LABS Text: K23-OUTLBT-RUB-1 TLI#42399B
loan Si 20
8:00 9:00 10:00 11:00 12:00 13:00
Fila:U972698 #1-534 Acq:13-AUO-1997 06:14:23 OC SIf Voltay• SIR 70S Noiso:45017747
154.0782 F:2 BSVB1256,30,-3.0) PKD(3,3,9, 0. 01*, 180070992. 0,0.00*,?,F) Bxp:PAB5
TRZAM3LS LABS Text: 1133-OUTLET-RUS-l TLI#42299B
100*. „ 8 57
11:04
11:31
13:20
1.1*9
.3.6X8
.6.4S8
.4.3S8
.2.1S8
0.0X0
14100 ttmu
,.3.3X7
801
601
401
201
0.
9:27
9:50
.10!37 10:51
11:16 lls.sl 12,13
12:44
8:00 9:00 10:00 11:00 12:00 13:00
Fll»:U972698 #1-534 Acqsl3-AU<3-1997 06:14:22 QC EH- Voltaga SIR 70S Kois»s521422
164.1410 Fi2 BSUB(256,30,-3.0) PKD(3,3,9, 0. 01*,2085688. 0, 0. 00*,P,P) Exp:PAS5
TRIANGLE LASS Tauct.- M23-OUTLET'-XUX-1 TLX#42299B
100* 8:53
0.0X0
14 00 Time
1.1S9
18.6B8
'.6.4X8
'.4.3E8
'.2.1S8
0.0X0
14 s 00 Time
^1.6X7
8:00 9:00 10:00 11:00 12:00
P11«:U97269B #1-534 Acq; 13-AUQ-1997 06:14:22 OC Xlf Volt ay • SIR 70S
168.9888 Ft2 XxptPABS
TRIANQLE LABS Text: O23-OVTLST-RUN-1 TLI#42299B
IOCS
so;
601
401
201
0.
13:00
0X0
14s 00 Tim*
ft/^^p^^
-6.1X7
8:00
9:00
lOtOO
11:00
12 tOO
13 tOO
'.4.9X7
.3.6X7
'.2.4X7
'.1.2X7
.0.0X0
14 00 Tim*
60
-------
\fil»:U973S9S 91-395 JLcqt13-Mo-1997 OS:14:33 X BX* Voltmgm SIR 70s 9oim»:157709
162.0236 BSUB(256r30,-3.0) PXD(3,2, 8,1.OO*, 630836.0, 0.00*,fff) XxptPlBS
TRIANGLE LABS T»xt: H23-OUTLBT-RUN-1 TLI942299B
100*
80.
eo:
40.
20.
7,42
SiOO 5s 12 5t24 St36 5t48 ft 00 6112 6t24 6t36 6t48 7:00 7tl2 7z24 7:36 7:48 8:00 Tia*
Pil»:U972698 #1-295 Acy:13-AUO-1997 06:14:22 OC SX+ Voltmgm SIR 703 Soim»:122507
164.0207 BSUB(2S6,30,-3.0) fXD(3,2, 8f 1.00*, 490028. 0, 0. 00*,P,P) Sxp:PAB5
TRIANGLE LABS Tozt: M23-OUTLET-RUN-1 TLI*42299B
100* 7:42 2.9B8
ao:
eo:
40:
20L
.2.3S8
.1.8B8
.1.2S8
.5.9S7
O.OSO
5:00 5:12 5:24 5:36 5:48 6:00 6:12 6:24 6:36 6:48 7:00 7:12 7:24 7:36 7:48 8:00
Pil»:U972698 #1-235 Acq: 13-AUO-1S97 06:14:22 OC BI+ Voltage SIR 70S Hoia»:216€33
169.0676 3SUS(256,30,-3.0) PKD(3,2, 8, 1.00*, 866532. 0, 0.00*,P,P) ffltp.-PAHS
TRIANGLE LASS T03CH: M23-OUTLET-RUN-1 TLI#42299B
100% 7t,?9 9.0E6
ao:
so:
40:
20:
o:
6:09
6:43
5:34
7:49
5:00 5:12 5:24 5:36 5:48 6s 00 6:12 6:24 6:36 6:48 7: 7:12 7:24
Pil«:U972698 #1-295 Acy: 13 -AUO- 199 7 06:14:22 GC SI* Voltage SIS 70S Nois»:14119B
171.0648 BSUB(256,30,-3.0) PXD(3,2,8, 1.00*,564792.0,0.00*,f,P) Bxp:PAB5
TRIANGLE LABS Text: K23 -OUTLET-RUN- 1 TLI#42299B
100* 5:34
'.7
"-5.
'.3.
11.
7:36 7:48 8:00
2B6
4S6
.6B6
.BS6
.OBO
Time
5:00 5:12 3,24 5:36 5:48 6:66 6:12 6:24 6:36 6:48 7:00 ' '7:12 ' '7:24
F±1»:U972698 #1-295 Acq: 13-AUG-1997 06:14:22 GC Elf Voltage SIR 70S
154.9920 Zip:PAHS
TRIANGLE LABS Text: M23-OUTLST-RUN-1 TLI#42299B
100H S:.51
80.
60.
40.
20.
0.
7:36 7:48 8:
5:06
5:00 5,12 524 st36 ' S.'rfV
'6i24 ' ~6t3f ' '6t48 ' 'H66
'ii24 ' 'it36 ' ~7i4»
1.
LI.
.1.
'.6,
.3.
0,
7X7
4X7
0X7
9X6
4X6
0X0
Tlawf
61
-------
flle:u972698 wl-534 Acq: 13-AUQ-1S97 06:14:32 OC SI* Voltage SIR 70S aoiMe:211J7897
166.0782 ?s2 BSUB (256, 30,-3.0) PXD(S.1,1. 0.50*. 84551592.0, 0.00*,f,f) XxptPABS
LABS Text: M23-OUTLET-RUS-1 TLI#42299B
100H A7_fJ9X9
Ai.aax^
80.
60.
40.
20.
0.
BtOO 9tOO 10:00 lit 00 12:00 13:00
Pll»tU972698 91-534 Acqsl3-AUO-1997 06:14:22 OC *I> Voltage SIR 70S Hoife:558645
176.1410 f:2 BSUB(2S6,30,-3.0) PXD(S, 1,1, 0.50*, 223 4580.0, 0.00*,f,F) SxpiPABS
TRIAIIOLX LABS TfXtt 1(23-OUTLET-ROB-1 TLHH2299B
loan
8:00 9:00 10:00 11:00 12:00 13:00
F11«:U972698 #1-534 Acqil3-AUQ-1997 06:14:22 OC BI+ Voltage SIR 70S Noiso:7555130
178.0782 P:2 BSU3(256,30, -3.0) PKD(S, 1,1, 0.50*, 30220520. 0, 0. 00*,?,F) SjcpiPABS
TRIANGLE LABS Tuxt: H23-OUTLET-RUN-1 TLI#42299B
A1.UE9
8.-00 9:00 10:00 11:00 12:00 13:00
Fil»:U972698 #1-534 Acqi 13-AUQ-1997 06:14:22 OC EI+ Voltago SIR 70S Ooig»:2084475
188.1410 ?:2 BSUB(256,30,-3.0) PSD(5,1,1, 0,50*, 8337900. 0, 0, 00*,?,?) EJfpsPABS
TRIANGLE LABS Text: M23-OUTLET-RUN-1 TLIK43299B
100*
80.
so:
40.
20.
0.
A5.07E7
A2.77E7
8:00 9:00 lOsOO 11<00 12:00
F11»:U972698 #1-534 Acq:13-AVO-1997 06:14:22 OC BI+ Voltage SIR 70S
168.9888 F:2 XxptPABS
TRIANGLE LABS Text: K23-OUTLET-RUN-1 TLH42299B
loot
eo:
eo:
40:
20:
OJ
13:00
-1.1S9
'.8.5X8
.6.4X8
.4.3X8
.2.1X8
0.0X0
14 00 Tim*
14 00 Time
0.0X0
14.00 Timo
9.6X7
".7.7X7
',5.8X7
'.3.9X7
'.1.9E7
14 00 Tim»
ft/^lpVT^^
-6.1X7
'.4.9X7
.3.6X7
".2.4X7
.1.2X7
8:00
'9:00
10s 00
ll'tOO
12:00
1 1 r"
13 {00
^ '.0.0X0
14 00 Tim*
62
-------
Plle:U972698 #1-703 AC~~~Kr~^^
14-00 15:00 ltfi-00
2.7B7
-
- •
Al . 7827
_ ^.-.. . M
1 i ' ' 1 1 1 1 1 1 1 1 r r-i — I I 1 1 1 1 T 1
17:00 18:00 19:00 30
-2.2B7
-1.6E7
1 127
~
.5.52*
00 Time
Pile:0972698 #1-703 Acq: 13-AUO-1997 06:14:22 OC 2T+ Voltage SIR 70S Koiae:262425
244.1974 F:3 BSUB (256, 30, -3 .0) PKD(S,3,
1, 0. 10%, 1049700. 0, 0. OOX,P,P) Exp:PABS
TRIAKOLE LABS Text: H2 3 -OUTLET- RUN- 1 TLI#42299B
100*
80:
60:
40:
20:
oj
i «i^j_ ^ »
14 00 15:00 itf:00
rl.S27
A3. 1527
Jl
17rOO 18:00 19:00 ' '30
.1 . 527
.1.127
.7.3X6
.3.6B6
_ 0 • 020
00 Time
PilesU972698 #1-703 Acq:13-AUO-1997 06:14:22 OC 2Z+ Voltage SIR 70S
242.9856 P:3 XxptPABS
TRIAHOLB LABS Text: X2 3 -OUTLET- RUN- 1 TLHf42299B
100*
an-
o u_
60:
40:
20:
ol.
1*,3» Iff: 03
14:49 *r« j, ^Af+****f
^xXV~W'-'Vw*»-*»-/^^^
f
14 00 15:00 16tOO
19:41 2 »S7
18:50 1lJ^fk_JwpW^A[
lff:47 I7l4i ^.^ to*Aktll**Vlt**fl*Jf*^*1^
^.. -AjL^L-L J*J\S*#\lllJl\jl~^^V^^^
•
-
17:00 18:00 19:00 ' '30
.2.2X7
.1.7X7
.1.1X7
.5,5X6
.0.0X0
00 Time
63
-------
File
252.
TRIA.
iooa
90.
ao:
70:
60:
so.
40.
30.
20.
10.
20
File
264.
TRIA.
1004
:U972698 91-1377 Ad
0939 Pi 4 3303(256,3
SOLS LABS Text: JO.
^'J?*^
J:13-AUO-1S97 06:14:22 OC 31* Voltage SIM 70S BOlme: 1O14695
1, -3.0) PXD(7,5,3,0.2O*.40587aO.O,0.00*,P,P) SxptPASS
3-ODTLBT-OTN-l TLI*42299B
1739
A3. 9 839
-
u
1
iJL
00 22;00 24:00 2ff»00 2«iob ' ' 30:00 32:00 34.-00 36
,0972693 #1-1377 Acq:13-AUO-1997 06:14:22 OC XX* Voltage SIR 70S Noise: 62044
1692 P:4 BSUB(256,30,-3.0) PKD(7, 5,3, 0.20*,248176.0, 0.00*,P,F) Bxp:PAB5
HOLS LABS Text i H23-OUTLBT-Rm-l TLI#42299B
A7.60S7
903
ao:
70:
60:
so:
40:
so:
20:
10:
,:
20
File
268.
TRIA
1001
A4 . 60E7
n
11
9.6*8
-.8.638
-.7.738
.6.738
.5.838
.4.838
.3.838
.2.988
.1.938
.9.637
00 Time
-1 . 537
Ll.4S7
11.2S7
I1.1S7
\9.2E6
\.7.7E6
-.6.136
-.4.636
'-.3.136
-.1.536
-.00 22:00 24:00 26': 00 28:00 30:00 32:00 ' 34:00 36': 00 Time
SU972698 #1-1377 Acy:13-AUa-1997 06:14:22 OC 31* Voltage SIR 70S
9824 P:4 Sxp:PABS
SOLS LABS Text: M23-OVTLST-RVN-1 TLI*42299B
23:10 24:52 .... 2.437
31 -S7 ijL ,1 .. .! 3*,^ 39S°S F
\ TiPfWiW L 3ii29 \2'2*7
ao\2 °$M* > ' ''"iifT HniiN^^ ik "i37 I*-**7
7oJj0V 1 ]||! lip" r^^T^^MP^MniJlfii^
jU 1 1 1 TIT ^ r
sol
401
30J
20J
10J
o:
20
-
:00 22>ob 24:00 26:00 28:00 30:00 32:00 34:00 36
'-.1.737
.1 . 437
.1.237
.9.636
.7.236
.4.836
.2.436
0.030
00 Tim*
-------
Pile:0972698 #1-1377 Aotf.l3-AUO-i997 06,14:22 X 31+ Voltage SIS 70S Boime:B5796
276.0939 P:4 BSUB(256,30,-3.0) PXD(15,13,11, 0.5O*,343184. 0,0. 00*,P,P) XxpiPASS
TRIANGLE LABS Text: M23-OUTLET-RUN-1 TLIH42299B
100* AS.76X8
ao:
eo:
40:
20;
A
•ft-
A4.84S8
Ai.aose
-4.6X7
.3.7X7
.2.8X7
.1.8X7
.9.2X6
20 00 22:00 24:00 26:00 28iOO 30:00 32:00
Pile:U972698 #1-1377 Acq: 13-AUG-1997 06:14:22 OC EH- Voltage SIX 703 Noime: 140671
288.1692 P:4 BSUB(256,30, -3.0) PKD(15, 13, 11, 0.50*,562684.0,0. 00*,P,F) XxpiPASS
TRIANGLE LABS Text: H23-OUTLST-RUN-1 TLI#42299B
100*
34:00
0.0X0
80:
eo:
40.
20J
0.
A2.30B7
A1.60E7
20 00 22:00 24:00 26:00 28:00 30:00 32:00 34:00
Pile:U972698 #1-1377 Acg: 13-AUO-1997 06:14:22 OC Xlf Voltage SIR 70S Noiae: 140526
278.1096 P:4 BSUB(256, 30, -3. 0) PKD11S, 13, 11, 0.50*,562104. 0,0. 00*,P,P) Sxp:PAB5
TRIANGLE LABS Text: M23-OUTLET-RUN-1 TLIX42299B
100* A1.56E8
20:00 22:00 24:00 26:00 28:00 30:00 32:00
Plle:U972698 #1-1377 Acq:13-AUO-1997 06:14:22 OC EH- Voltage SIR 70S Soise:195766
292.1974 P:4 BSUB(256,30,-3.0) PKD(15,13, 11, 0.50*, 783064. 0, 0. 00*,P,P) Xxp:PABS
TRIANGLE LABS Text: M23-OUTLET-RUN-1 TLIX42299B
100*
so:
so:
40:
20:
A1.2SB7
20:00 22:00 24:00 26:00 28:00 30:00
Plle:U97269a #1-1377 Acq: 13-AUO-1997 06:14:22 OC EH- Voltage SIR 70S
268.9824 P:4 Sxp:PAB5
TRIANGLE LABS Text: U23-OUTLST-RUN-1 TLI#42299B
100*
20:00
22:00
24:00
26:00
36 00 Time
-2.3X6
.1.8X6
.1.4X6
.9.2X5
.4.6X5
0.0X0
36 00 Time
1.3S7
3.6X6
'.2.9S6
'.2.1X6
".1.4B6
-7.1SS
= '.0.0X0
36 00 Tiam
.0X0
36 00 Time
64
-------
Peak Locate Examination:13-AUG-1997:06:13 File:U972698
Experiment:PAHS Function:3 Reference:PFK
Volts
0.2411
204.96319
204.98882
205.01444
218.95825
218.98563
219.01300
C'l
-------
File:U972698 #1-703 Acq:13-AUG-1997 06:14:22 GC EI+ Voltage SIR 70S
228.0939 F:3 Exp:PAH5
Sample Text: M23-OUTLET-RUN-1 TLI#42299B File Text:TRIANGLE LABORATORIES , INC
100% A3.QOE9
19:00 19!06 19!12 19!18 19!24 19!30 19^36 19:42
File:U972698 #1-703 Acq:13-AUG-1997 06:14:22 GC EI+ Voltage SIR 70S Noise:701250
240.1692 F:3 BSUB(256,30,-3.0) PKD(7, 3 , 1, 0.10%, 2805000.0,0.00%,F,T) Exp:PAH5
Sample Text: M23-OUTLET-RUN-1 TLI&42299B File Text:TRIANGLE LABORATORIES , INC
100% A2.29E7
90
80 J
70J
60J
50J
40 J
30J
20 J
10 J
OJ
A1.91E7
Time
19 lob
CD
Q)
19:18
19124
19130
-i—i—(—r-
19:36
19! 42
8.3E6
7.4E6
6.6E6
5.8E6
5.0E6
_4.1E6
F.3.3E6
2.5E6
1.7E6
8.3E5
O.OEO
Time
-------
File:U972698 #1-1377 Acg:13-AUG-1997 06:14:22 GC EI+ Voltage SIR 70S
252.0939 F:4 Exp:PAH5
Sample Text: M23-OUTLET-RUN-1 TLI#42299B File Text:TRIANGLE LABORATORIES , INC
lOOi A5.97E9
90 j
80 j
70J
60J
50J
40 j
30J
20J
10J
OJ
23:48 23:54
22:54 23:00 23:06 23:12 23:18 23:24 23:30 23136 23i42
File:U972698 #1-1377 Acq:13-AUG-1997 06:14:22 GC EI+ Voltage SIR 70S
264.1692 F:4 Exp:PAH5
Sample Text: M23-OUTLET-RUN-1 TLI#42299B File Text:TRIANGLE LABORATORIES , INC
lOOi ^ ^, 23;28
90J
80 J
70J
60 J
50J
40J
30 J
20 J
10 j
23:21
~i—I—i—I—I—i—I—i—r
22:54 23:00
T
23:06 23:12 23:18 23:24
—i—i—i—i—i—r
23:30
23:36 23:42 23:48 23:54
Time
1.6E7
-1.4E7
_1.2E7
_9.3E6
_7 . 8E6
_6.2E6
_3.1E6
_1.6E6
O.OEO
Time
CD
-------
File:U972698 #1-1377 Acq:13-AUG-1997 06:14:22 GC EI+ Voltage SIR 70S
252.0939 F:4 Exp:PAH5
Sample Text: M2 3 -OUTLET-RUN- 1 TLI#42299B File Text : TRIANGLE LABORATORIES ,
100%
INC
'23\3Q
23:42' ' 23:
22i54 23100 23i06 23il2 23 i 18 23i24 233Q 23:36
File:U972698 #1-1377 Acq:13-AUG-1997 06:14:22 GC EI+ Voltage SIR 70S
264.1692 F:4 Exp:PAH5
Sample Text: M2 3 -OUTLET-RUN- 1 TLI#42299B File Text : TRIANGLE LABORATORIES
100* „, „„ 23:28
1 ' I ' ' I ' I
48 23:54
INC
90J
80J
70J
60 J
50 J
40 J
30J
20 J
10 J
OJ
23:21
22:54 23:00 23:06
—^5 •
GO
1 ' i ' ' ' ' ' i ' ' ' ' ' i > ' ' •' ' i ' ' ' ' ' i ' ' ' ' i i ' ' i i i i i i i i i i i i
23:12 23:18 23:24 23:30 23:36 23:42 23:48 23:54
Time
_1.6E7
L1.4E7
L1.2E7
L1.1E7
-7.8E6
L.6.2E6
L4.7E6
L3.1E6
L1.6E6
_O.OEO
Time
-------
|File:U972698 #1-1377 Acg:13-AUG-1997 06:14:22 GC EI+ Voltage SIR 70S
276,0939 F:4 Exp:PAH5
Sample Text: M23-OUTLET-RUN-1 TLI#42299B File Text:TRIANGLE LABORATORIES ,
100%
90 J
80 J
70J
60 J
50 J
40J
30J
20 J
10J
A4.62E8
1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1
32:00 33:00 34:00
File:U972698 #1-1377 Acq:13-AUG-1997 06:14:22 GC EI+ Voltage SIR 70S
288.1692 F:4 Exp:PAH5
Sample Text: M23-OUTLET-RUN-1 TLI#42299B File Text:TRIANGLE LABORATORIES ,
lOOi A1.9.8E7
90 J
80 J
70J
60 J
50 J
40 J
30J
20J
10 J
-i 1 r
35:00
INC
OJ
32:00
-i 1 r-
33:00
34:00
35:00
_1
4.7E7
4.3E7
3 . 8E7
3.3E7
2.8E7
2.4E7
.1.9E7
.1.4E7
.9.5E6
4.7E6
O.OEO
Time
1.9E6
1.7E6
5E6
1.3E6
1.1E6
9.3E5
7.5E5
5.6E5
3.7E5
1.9E5
O.OEO
Time
05
CD
-------
File:U972698 #1-1377 Acq:13-AUG-1997 06:14:22 GC EI+ Voltage SIR 70S
278.1096 F:4 Exp:PAH5
Sample Text: M23-OUTLET-RUN-1 TLI#42299B File Text:TRIANGLE LABORATORIES , INC
lOOli A1..61E8
90 j
80J
70J
60J
50J
40 J
30J
20J
10J
OJ
32:00 33:00 34:00
File:U972698 #1-1377 Acq: 13-AUG-1997 06:14:22 GC EH- Voltage SIR 70S
292.1974 F:4 Exp:PAH5
Sample Text: M23-OUTLET-RUN-1 TLI#42299B File Text:TRIANGLE LABORATORIES , INC
100% 32:37
80J
70J
60J
50J
40 j
30J
20J
10J
3s!oo
_1.4E7
_1.2E7
-1.1E7
_9.6E6
_8.2E6
-6.8E6
_5.5E6
_4.1E6
_2.7E6
_1.4E6
O.OEO
Time
32JOO
33IOO
34!oO
3s!oo
1.4E6
Ll.3E6
_1.2E6
L8.7E5
.7.2E5
L5.8E5
L4.3E5
L2. 9E5
O.OEO
Time
-------
File:U972698 #1-1377 Acq:13-AUG-1997 06:14:22 GC EI+ Voltage SIR 70S
278.1096 F:4 Exp:PAH5
Sample Text: M23-OUTLET-RUN-1 TLI#42299B File Text:TRIANGLE LABORATORIES , INC
100% A1..61E8
90 j
80J
70J
60J
50J
40J
30J
20J
10J
OJ
32:00 33:00 34:00 35:00
File:U972698 #1-1377 Acq:13-AUG-1997 06:14:22 GC EI+ Voltage SIR 70S
292.1974 F:4 Exp:PAH5
Sample Text: M23-OUTLET-RUN-1 TLI#42299B File Text:TRIANGLE LABORATORIES , INC
100% A1.74E7
90 J
80 J
70J
60 J
50 J
40 J
30 J
20 j
10J
OJ
32100
33100
34:00
3s!oo
1.4E7
L1.2E7
L1.1E7
L9.6E6
L8.2E6
L6.8E6
L5.5E6
L4.1E6
L2.7E6
Ll.4E6
O.OEO
Time
1.4E6
L1.3E6
L1.2E6
L1.0E6
L8.7E5
L7.2E5
_5.8E5
.4.3E5
L2.9E5
-1.4E5
LO.OEO
Time
-------
TLI Project:
Client Sample:
42299B
M23-Outlet-Run 2
PAHJ Analysis (a)
Analysis File: U972697
Client Project:
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
Iron & Steel-Chicago
MM5
173-61-2A-D
.
1.000
n/a
DB-5
Date Received:
Date Extracted:
Date Analyzed:
Dilution Factor
Blank File:
Analyst:
07/01/97
07/17/97
08/13/97
n/a
U972695
KB
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPPAHJ10
UPJ8127
U972690
n/a
n/a
n/a
Analytes
Fluorantbene
Pyrene
Benzo(a)anthracene
Chrysene
Perylene
Benzo{b)fluoranthene
Benzo(k)fluoranthene
Benzo(a)pyrene
BenzoCe)pyrene
Benzo(g,h,i)perylene
Indeno( 1,2,3 -cd)pyrene
Dibenz(aji)anthracene
Internal Standards
d!2-Benzo(a)anthracene
dio-Fluoranthene
dI2-Chrysene
di2-Perylene
di2-Benzo(b)fluoranthene
di2-Benzo(k)fluoranthene
di2-Benzo(a)pyrene
di2-Benzo(g,h,i)perylene
di2-Indeno( 1 ,2,3-cd)pyrene
di4-Dibenz(a,h)anthracene
;:> Amt (*<^
11670
10830
4710
9270
616
11260
2850
2970
6350
4580
3790
1210
Amt (ng)
393
114
256
209
251
199
258
244
357
518
?^fti^A-^-a»C''^ c-
• ; % Re
-------
Data Review By:
initial
.Cat*..
\0 *2_,VjQ
Calculated Noise Area: n/a
Page No.
08/21/97
Listing of O972697B.dbf
Matched OC peaks / Ratio
/ Ret. Tine
Compound/
M_Z QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT compound.Name.. ID.. Flags.
Fluoran
202
202
dlO-Fluoran
212
M
212
B-a-Anth
228
M
M
228
d!2-B-a-Anth
240
M
M
240
DC NL 0:00
14:14
14:31
15:10
15:15
15:24
15:36
15:42
15:48
16:11
17:16
18:19
18:37
12 Peaks
DC ML 0:00
15:31
15:43
16:06
3 Peaks
DC NL 0:00
16:12
16:36
18:07
18:19
18:26
18:43
19:21
19:27
19:43
9 Peaks
DC NL 0:00
14:26
14:42
14:47
19:16
19:22
5 Peaks
19,417.66
15,209.30
284,733.00
18,693.40
10,182.20
8,423.01
541,673.00
12,694.30
24,161.40
515,818.00
13,888.10
27,216.70
34,874.50
1,507,566.91
465.58
3,209.01
800.95
3,580.00
7,589.96
776.36
12,978.70
2,924.06
4,563.30
6,171.55
2,467.66
43,718.90
191,000.00
291,000.00
8,828.14
563,652.31
1,032.35
2,885.30
368.15
190.78
2,930.00
2,350.00
8,724.23
15,209.30
284,733.00
18.693.40
10,182.20
8,423.01
541,673.00
12,694.30
24,161.40
515,818.00
13,388.10
27,216.70
34,374.50
3,209.01
800.95
3,580.00
12,978.70
2,924.06
4,563.30
6,171.55
2,467.66
43,718.90
191,000.00
291,000.00
8,828.14
2,885.30
368.15
190.78
2,930.00
2,350.00
0.354-1. 646
0.000
0.917
0.936
0.977
0.983
0.992
1.005 Fluoran AN S
1.012
1.013
1.043 Pyrene AN S
1.113
1.180
1.200
0.290-1.646
0.000
1.000 dlO-Fluoran IS5
1.013
1.038 dlO-Pyrene RS2
0.481-1.519
0.000
0.841
. 0.862 _ , .
0.940
0.951
0.957
0.971
1.004 B-a-Anth AN PR
1.010 cnrysene AN PR
1.023
0.481-1.519
0.000
0.749
0.763
0.767
1.000 d!2-B-a-Anth IS6
1.005 d!2-Chrysene islO
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 14:24 08/21/97
73
-------
Page Ho.
08/21/97
Listing of 0972697B.db_
Matched OC Peaks / Ratio / Ret. Time
Compound/
M_Z QC.Log Omit Why . .RT. OK Ratio Total. Area... Area. Peak. 1.. Area. Peak. 2.. Rel.RT Cotnpound.Hame.. ID.. Flags.
B-b-Fluoran
252 DC
M
MN
252
d!2 -B-b-Fluoran
264 DC
264
I-123-cd-Py
276 DC
DC
DC
DC
DC
DC
DC
DC
M
______ — -_-- xi
NL 0:00
21:05
21:21
21:33
23:26
23:55
24:47
25:04
25:30
8 Peaks
NL 0:00
23:19
23:27
24:38
24:55
25:21
5 Peaks
NL 0:00
WL 21:29
WL 22:13
WL 22:33
WL 22:54
WL 23:17
WL 23:47
WL 24:25
24:43
25:00
25:25
25:51
26:13
26:52
27:29
28:03
28:25
30:00
30:34
31:06
31:49
32:36
33:14
33:45
34:01
34:50
xvm: u-a-Ancn / a-i
2,215.66
18,855.00
6,449.55
16,464.70
630,000.00
162,000.00
326,564.00
122,009.00
21,266.40
1,303,608.65
106.32
8,993.04
8,686.07
3,031.74
5,625.48
5,996.19
32,332.52
231.45
668.37
5,800.82
9,813.66
18,790.80
16,558.70
10.287.30
3,279.95
3,232.53
3,083.98
2,690.59
713.22
2,612.35
2,439.87
602.41
2,130.28
659.21
1,292.05
6,471.58
3,457.94
22,094.30
56,400.00
1,700.08
2,210.78
3,571.34
66,270.30
18,355.00
6,449.55
16,464.70
630,000.00
162,000.00
326,564.00
122,009.00
21,266.40
8,993.04
8,686.07
3,031.74
5,625.48
5,996.19
.23~cd~py Fol lows ~~
3,232.53
3,083.98
2,690.59
713.22
2,612.35
2,439.87
602.41
2,130.28
659.21
1,292.05
6,471.58
3,457.94
22,094.30
56.400.00
1,700.08
2,210.78
3,571.34
66,270.30
0.606-1.394
0.000
0.832
0.842
0.850
0.924 B-b-Fluoran AN PR
0.943 B-k-Fluoran AN PR
0.978 B-e-Pyrene AN
0.989 B-a-Pyrene AN
1.006 Perylene AN
0.606-1.394
0.000
0.920 d!2-B-b-Fluoran isll
0.925 d!2-B-k-Fluoran is!2
0.972 dl2-B-«-Pyrene RS3
0.983 d!2-B-a-Pyrene is!3
1.000 d!2-Perylene IS7
0.711-1.289
0.000
0.621
0.642
0.652
0.662
0.673
0.687
. 0.706 - .
0.714
0.723
0.735
0.747
0.758
0.776
O.794
0.811
0.821
0.867
0.383
0.899
0.920
0.942 I-123-cd-Py AN PR
0.961
0.975
0.983
1.007 B-ghi-Pery AN
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 14:24 0^21/97
T4
-------
Page No.
08/21/97
Listing of 0972697B.dbf
Matched GC Pe*ka / Ratio / Ret. Tim*
Compound/
M_2 QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. 10.. Flags.
276
18 Peaks
181,632.81
DiB-ah-Anth
278
278
d!2-I-123-cd-Py
288
M
238
d!4-DiB-ah-Anth
292
M
292
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
WL
ML
WL
WL
WL
ML
WL
WL
WL
WL
WL
6
ML
2
NL
1
0:00
23:06
23:47
24:42
25:00
25:25
26:12
26:52
28:05
28:28
30:01
30:34
31:06
31:51
32:51
33:14
33:45
34:00
Peaks
0:00
32:25
34:36
Peaks
~ AVv»
0:00
32:36
Peak
Above: I-123-cd-Py / DiB-ah-Anth Follows
291.75
4,104.75
550.18
3,309.36
2,606.48
3,053.36
5,513.03
4,640.51
3,058.50
474.53
1,176.90
4,388.03
1,845.47 1,845.47
11,182.20 11,182.20
20,200.00 20,200.00
3,410.64 3,410.64
5,684.00 5,684.00
10,393.00 10,393.00
52,715.31
Above: DiB-ah-Anth / d!2-I-123-cd-Py Follows
0.939-1.061
0.000
0.709
0.730
0.758
0.767
0.780
0.804
0.824
0.361
0.873
0.921
0.938
0.954
0.977
1.008 DiB-ah-Anth
1.019
1.035
1.043
151.46
2,560.00
2,236.26
4,796.26
2,560.00
2,236.26
Above: d!2-I-123-cd-Py / d!4-DiB-ah-Anth Follows
91.21
2,130.00
2,130.00
AN
0.711-1.289
0.000
0.937 d!2-I-123-cd-Py is!4 I
1.000 d!2-B-ghi-Pery IS8
2,130.00
0.939-1.306
0.000
1.000 d!4-DiB-ah-Anth IS9
Column Description.
"Why" Code Description QC Log Desc.
M_Z -Nominal Ion Mass(es)
..RT. -Retention Time (um:ss)
Rat.l -Ratio of M/M+2 Ions
OK -RO=Ratio Outside Limits
Rel.RT-Relative Retention Time
•** End of Report ***
WL-Below Retention Tine Window
NH-Above Retention Time Window
SN-Below Signal to Noise Level
-------
\FiJ.es0973S97 tl-294 Acgtl3-AD8-lJJ'/ 04>4B*51 X g* Voltage 91* 70S aol*et359S72993
128.0626 BSUB(256,30,-3.0) PXD(3,1,10, 0.50*, 1038291968. 0, O.OO*,P,P) E*p:PASS
TRIANGLE LABS Texts It23-OUTLET-RUN-2 TLI1t42299B
10« SiiS S 36 S'10 fl3J 7fJ8
5:00 Si 00 7tOO
FllesU972S97 01-294 Acgsl3-AOG-1997 04:48:51 GC 2T+ Voltage SIR 70S Soitet1970298
136.1128 BSVB(256,30,-3.0) PKD(3,1,10, 0.50*, 7881192. 0, 0. 00*,F,P) SxpiPJLBS
TRIAHOLS IJLBS Texts 1123-OUTLET-RUN-2 TLH42299B
100*
0.0X0
Si 00 Tim*
ao:
so:
-------
f110t us72697 fl-535 Acyt 13-XuO-iSS/ O4t48lSl OC JU+ Voltage &LK /US Holm*1282439366
152.0626 f:2 BSUB(256,30,-3.0) PXD(3,3,9,0.01*,1139758308.0,0.00*,f,P) BxpsPAHS
TRIANGLE LABS Textt H23-OOTLBT-Rm-2 TLI*42299B
lOOSf 823 836 10f33 „ II^SS IStfl
1 Illl . . ._ 10»;
80.
60.
BiOO 9:00 10:00 11:00 12:00 13:00
FlletO-972697 #1-535 Acq:13-AUO-1997 04t48i51 OC SI* Volt*?* SIR 70S Nairn*t4513503
160.1128 Ps2 8SUB(256,3O,-3.0) PKD(3,3,9, 0. 01*, 18054013. 0, 0. 00*,P,P) SxptPASS
TRIANOLB LABS Text: K23-aOTLET-RUS-2 TLI#42299B
100*, 8-..19 9tl5
8:00 9:00 10:00 11:00 12:00 13:00
filatU972697 #1-535 Acq:13-AUG-1997 04:48:51 OC EI+ Voltspa SIS 70S Soie»s487S6000
154.0782 ?:2 SSUB(256,30,-3.0) PXV(3,3,9, 0.01*, 195024000. 0,0. 00*,F,P) Sxp:PAB5
TRIANOLS LABS T«urt: X23-OVTLET-RUII-2 TLI#42299B
40.
20:
0.
\llt03
11:31
13120
13:50
1.1X9
.8.6*8
.6.4X8
-4.3E8
-2.1B8
.0. 0X0
14 00 Tia»
12:14
11:57 A A 12:4513L04 13:28
80:
so:
40:
1:24
9:27
9:50
10:16
10:51
11:15
11:51
ll:39/t
12:12
O.OEO
14 00 Time
I. IBS
la. 620
'.6.4E8
'.4 . 3E8
-2.1E8
12:43
13:50.
8:00 9:00 10:00 11:00 12:00 13:00
Flla:V972697 #1-535 Acq: 13-AUO-1997 04:48:51 OC EH- Voltafff SIR 70S Noise:925520
164.1410 F:2 BSUB (256, 30, -3.0) PKD(3,3,9, 0. 01*, 3702 080.0, 0.00*,f,P) Bxp:PAB5
TRIANOLS LABS T»xt: M23-OUrLET-RUIl-2 TLHH2299B
100*,
ao:
eo:
14
.O.OEO
00 Tim*
8:00 9:00 10:00 lit 00 12:00
fi!0:U972697 #1-535 Acq: 13-AUO-1997 04:48:51 OC ST* VoltMfff SIR 70S
168.9888 P:2 SxpsPABS
TRIANOLE LABS Texts M23-OUTLET'-RUN-2 TLI#42299B
8:29
13tOO
'.1.6S7
-1.2B7
'.7.8E6
-3.9E6
'.O.OEO
14100 Time
'00 9:24 9:50 10,12
8:00
9100
10:00
11 tOO
12 tOO
13 tOO
O.OJSO
14 tOO TlJM
77
-------
Pll»,17972697 il-394 *cq: 13-1BO-1997 04,48,51 X g* Volktg* SIS 703 Bbl*»i129830
162.0236 BSUB(256,30,-3.0) PXD(3,2,8,1.00*,S19320.0,0.00*,P,P) SxptPASS
TRIANQLS LASS Ttatt M23-OUTLXT-ROS-3 TLH42299B
loan
80.
SO.
40.
20.
7*42
7:55
_8.4X8
.6.8X8
'.5.1X8
'.3.4S8
.1.7X8
A
5 tOO 6tOO 7:00
Pil0:U972697 #1-294 Acq:13-AOO-1997 04t48iSl OC XH- Voltag* SIS 70S Noim*:101S68
164.0207 BSUB(256,30,-3.0) PXD(3,2, 8,1.00*,407472. 0, 0.00*,P,P) SleptPABS
VRIABQLX LABS T»Xt: K23-OUTLET-KPN-2 TLI*42299B
100H
601
401
201
0.0X0
8 tOO Tim*
7:42
2.5X8
'.2.0X8
.1.5X8
.1.0X8
_5. 0X7
5:00 6s00 7:00
Fil«:U972697 #1-294 Acq:13-AUQ-1997 04:48:51 OC EI+ Voltage SIS 70S Boia*:199982
169.0676 BSUB(256,30,-3.0) PXD(3,2, 8, 1. 00*, 799928. 0, 0. 00*,P,P) Sxp:PAB5
TRIANGLE LABS Taxt: X23-OUTLET-RUN-2 TLIX42299B
100*
a 01
601
401
201
0.
'.0.0X0
7:40
5:35
8100 Tim*
9.7X6
-7.7S6
-5.SE6
-3.9E6
.1.9X6
5:00 6:00 7:00
Pil*:U972697 #1-294 Acq:13-AUQ-1997 04:48:51 QC XI* Voltag* SIS 70S SOia»i67808
171.0648 BSUB(256,30,-3.0) PKD(3,2, 8, 1.00*,271232. 0, 0.00*,P,F) Xxp:PAB5
TRIANGLE LABS Text: X23-OUTLET-RUN-2 TLI#42299B
10O>f A1.40X7
8:
0.0X0
00 Tim*
5tOO 6:00 7:00
Pil*:U972697 01-294 Acq: 13-AUQ-1997 04:48:51 OC BI+ Voltaa* SIR 70S
154.9920 SxptPABS
TRIANGLE LABS T*Xt: H23-OUTLBT-RUtl-2 TLIJ42299B
lOOSt f:.S2
801
601
40.
20.
0.
8:00
6,39
5:07
5:35
7:18
1.6X7
.1.3X7
.9.7X6
.6.5X6
-3.2X6
5:00
StOO
7iOO
.0.0X0
8:00 Tim*
78
-------
Pile:0972697 #1-535 laq:i3-lOO-l997 04:48:51 X ZX+ Volbag* 3TR 70S Maim*:14547105
166.0782 f:2 BSUS(256,30,-3.0) PXD(5,l,l,0.50*,58188420.0,0.00*,f,F) Exp:PAB5
TRIASOLS LABS TfXt: M23-OUTLET-SUB-2 TLI#42299B
100H
80.
8:00 9t'00 lO'iOO 11*00 12/00 13;00
Pile:U972697 #1-535 Aeq:13-Am-1997 04:48:51 OC XX* Voltage SIS 70S Noime:82S320
176.1410 f:2 BSUB (256, 30, -3.0) Pa3(5,l,l,0.50*,3301280.0,0.00*,P,P) BrpiPAHS
TRIANGLE LABS Text: 1123-OUTLET-RUN-2 TLI*42299B
100*
80.
60.
8:00 9:00 10:00 11:00 12:00 13:00
Pile:U972697 #1-535 Acq: 13-AUO-1997 04:48:51 OC ST+ Voltage SIR 70S ttolaf:6630001
178.0782 ?:2 BSVB1256, 30,-3 .0) PKD(5, 1, 1, 0. 50*,26520004. 0, 0. 00*,P,P} B3Cp:PABS
TRIANOLS LABS Tact: K23-OUTLST-XOII-2 TLI&42299B
100* A7.8J5JB?
so:
40.
20.
A1.95E7
A3.77E7
A2.23E7
A7.42E6
fl.-OO 9:00 10:00 11:00 12:00 13:00
File:U972697 #1-535 Acq:13-AUO-1997 04:48:51 OC BI+ Voltage SIR 70S tfoise:3508068
188.1410 P:2 BSUB (256, 30,-3.0) PKB(5, 1,1, 0.50*, 14032272.0, 0. 00*,P,P) Bxp-.PABS
TRIANGLE LABS Text: H23-OUTLET-RUN-2 TLI#42299B
iota
so:
so:
-------
Pile:U972697 #1-702 Acq:13-AUO-1997 04:48:51 OC KL+ Voltage SIR 70S Holme: 9708829
202.0782 F:3 BSUB (256, 30, -3.0) PXD(5,3,1,0.10*,38835316.0,0.00*,P,P) Sxp:PAB5
TRIANGLE LABS Text: M2 3 -OUTLET -RUN- 2 TLI#42299B
100)
801
601
401
20.
o'-
14
AS ^4 2X9 AS .16X9
A2.85X9
1
'
A1.52S^ A1'f(™8 1 nA 11 A3.. 39X8 "'A2** A
;00 15:00 ItfiOO 17:00 18tOO 15:00 20
I.lf9
'.3.6X8
.6.4X8
.4.3X8
.2.1X8
0.0X0
00 Time
Plle:U972697 #1-702 Acq: 13-AUO-1997 04:48:51 OC XXf Voltage SIS 70S Soiaet2327S9
212.1410 F:3 BSUB (256, 30, -3.0) PKD(5, 3, 1,0. 101,931156. 0,0. 00*,P,P) XxptPABS
TXIANOLS LABS Text: M23-OUTLST-RUH-2 TLI#42299B
100*
so:
60:
40:
20:
o-
14
A3. 21X7 A3. 31X7
1 i
L^^^v^^J^ li_A^ __^>
00 'lS tOO ItftOO ' 17:00 ' ' ' 'l8:00 ' ' ' 15:00 20
-1.3X7
'.9.6X6
.7.2X6
.4.8X6
.2.4X6
' 0 0X0
1 00 Time
PileiU972697 #1-702 Acq: 13-AUO-1997 04:48:51 OC Elf Voltage SIR 70S Soiae:388178
223.0939 F:3 BSUB (256, 30, -3 .0) PJO3(5, 3, 1, 0. 10%, 1552712. 0, 0. OOX,F,P) XxptPABS
TRIANGLE LABS Text: U2 3 -OUTLET- RUN- 2 TZI#42299B
100*
80:
60:
40:
20:
0:
A4. 4X9
/
A
ff
A4.37E8
A1.30E8 A /
/\ / V J ^ ^
9.0X8
'-.7.2X8
-.5.4X8
'.3.6X8
-1.8X8
'• a . oso
14:00 15:00 ltfi-00 17:00 18:00 15:00 20:00 Time
Pile:U972697 #1-7O2 Acq:13-AUCS-1997 04:48:51 OC SI+ Voltage SIR 70S Koiae:516174
240.1692 Fs3 BSUB (256, 30, -3 .0) PKD(5,3,1, 0.10^,2064696. 0, 0.00%, F,F) Xxp:PABS
TRIANGLE LABS Text: K2 3 -OUTLET -RUN- 2 TLI#42299B
100%
80:
60:
40:
20:
0-
14
A2.89B7 ~ • —
1 A2.66E7
n L
lu.«« A
v>^jUw»^ArL^vv-^ ^_ _ . Hi __
00 15:00 16\00 17:00 ' ' 18:00 ' "l5:00 ' 20
C2.0X7
-.1.6X7
^1.2X7
-7.9X6
.3.9X6
00 Time
Pil»:U972697 #1-702 Acq; 13-AUO-1997 04:48:51 OC XI+ Voltage SIR 70S Holae:180374
244.1974 F:3 BSUB(256, 30, -3 .0) PKD(5, 3, 1, 0. 1O%, 721496. 0, O. 00*,?, P) BxpsPABS
TRIANGLE LABS Text: X2 3 -OUTLET -RUN- 2 TLI#42299B
100%
soj
60:
40:
20:
o-
14
A2.33B7
L_- .. . i!
00 15:00 ItfrOO 17:00 ' ' ' 1S.-00 ' 15:00 20
.1.3X7
.1.1X7
.8.0X6
.5.3X6
.2.7X6
00 Time
File:U972697 #1-702 Acq: 13-AUO-1997 04:48:51 OC XI* Voltage SIR 703
242.9856 F:3 XxptPABS
TRIANGLE LABS Text: M23-OUTLST-RUN-2 TLI#42299B
1004
;
80:
"
60:
40:
20:
O-J
1. art
^ * '" J^.Jttu/**^*\^''V-*^^
17zOtf 17:37 .WVj»^s'*'^V**^'p*^pfc'^''
15*38 >i,-i$V^w««^nSA*«^V/>^^
_^-/--s^--'i^x^^
14'°° 15:00 1«:00 17:00 laioo ' ' ' 'iftOO ' ' ' ~20
~
.3.0X7
.2.3X7
.1.5X7
.7.6X6
0 . 0X0
00 Time
80
-------
KT!
252.
TRIA
loos
901
80-
70.
sol
50:
40:
30:
20:
10:
o:
20
File
264.
TRIA
IOCS
so:
so:
70:
50:
40:
30:
20:
10:
20
File
268.
TRIA
1003
so:
so:
70:
601
50:
40:
30:
20:
10:
20
,0972697 #1-1377 Aoq
0939 Ft 4 BSUB(2S6,30
JKtLS LABS Tart: M23
A7.
A A
ti3-AOo-i9S7 O4t4e»5i d£ K+ Volktgm SIR 70s itoif»ittd7828
,-3.0) PXD(7,5.3,0.20*,4431312.0,0.00*,r,r) XxptPABS
-OVTLST-RUN-2 TLI*42299B
12S9
A3. 27X3
|
.A Illl
..,
A
00 22:00 24:00 2ff':00 28:00 30:00 32:00 34:00 36
:U972697 #1-1377 Acqsl3-AUQ-1997 04:48:51 <3C BX+ Voltage SIR 70S Soi*ut 53160
1692 Ft4 BSUB(256r30,-3.0) PKD{7,5,3,0.20\,212640.0,0.00*,F,F) XxpsPASS
HOLS LABS Tart: M23-OUTLBT-RUK-2 TLI#42299B
A8.99E7
1
|
Jk6.
I
1
I. Ill
JOE7
00 22:00 241-00 ' 2*1-00 ' ' ' 2sl'00 ' ' ' 30:00 ' ' ' 32:00 ' ' ' 34:00 36
-.U972697 #1-1377 Acy:13-AUO-1997 04:48:51 OC BI+ Voltage SIR 70S
9824 Ft 4 XxpiPABS
HOLE LABS Tart: U23-OUTLE7-RVN-2 TLHt42299B
22s S3 24:23
/r
r
00 22:00 24:00
-1.0B9
'.9.4X8
.8.3X8
.7.3X8
-.6.2X8
•.5.2S6
'.4.2X8
.3.1X8
•-2.1B8
'.l.OEB
-.0.0X0
00 Time
1.BE7
-1.6E7
.1.4E7
.1.2E7
-1.1E7
.3.9E6
^.7.1X6
-5.3X6
-3.6E6
-1.8X6
-O.OBO
00 Tlaa
-3.0X7
\Wk)tAil( iki 37tS7 29-19 L2.7JB7
^^*^"W^
26\00 2B\00 30:00 32:00 34fOO ' ' 36
-1.8X7
-1.5X7
-1.2X7
-8.9X6
-6.0X6
-3.0X6
-0.0X0
00 Tlm»
81
-------
&iia:U972697 91-1377 ActJtl3-AuO-ly97 O4l48i51 OC BI+ Voltage SIR 70S HOiatt115723
276.0939 Pt4 BSUB (256, 30, -3.0) PKDflS, 13,11, 0.50*,462892.0,0.00*,F,F) Sxp:PAB5
TRIANGLE LABS Texts M23-OUTLET-RUS-2 TLI*42299B
A7.02S8
80.
60.
40.
20.
0.
A6.63S8
Al.S8E8
A6.47E7
. A
A2.21E8
A3.57S7
20*00 22:00 24tOO 26:00 28:00 30:00 32:00 34:00
ffilu:U972697 01-1377 Acy: 13-AUO-1997 04t48t51 OC SIf Voltaff* SIX 70S Noia»:75728
288.1692 F:4 BSUB(256,30,-3.0) PXO(1S,13,11,0.50*,302912.0,0.00*,F,F) SacptPABS
LABS I*«ct: K23-OUTLBT-RUIT-2 TLH42299B
A3.24S7
14.7*7
'.3.5S7
.2.4S7
-1.2S7
O.OSO
100?
80.
60.
40:
20:
0.
A2.24S7
~r
T
~r
36:00 Tla*
-2.3S6
'.1.8E6
'.1.4E6
'.9.2ES
'.4.6E5
'.O.OEO
20 00 22:00 24:00 26:00 28:00 30:00 32:00 34:00
F11»:V972697 #1-1377 Acq:13-AUO-1997 04:48:51 OC BI+ Voltagf SIR 70S Nois»:145874
278.1096 F:4 BSUB (256, 30, -3 . 0) PKD( 15, 13, 11, 0.50*, 583496. 0,0. 00*, F,F) Exp:PAB5
TRIANGLE LABS TfXt: M23-OOTLBT-RON-2 TLHt42299B
100% A1.79S8
36 00 Tim«
r.1.5E7
20:00 22:00 24:00 26:00 28:00 30:00 32:00 34:00
Pil«:0972697 #1-1377 Acy:13-AUO-1997 04:48:51 OC EH- Voltagf SIR 70S SoiB»:45605
292.1974 F:4 BSUB(256, 30,-3.0) PKD (15, 13, 11, 0. 50*, 182420. 0,0. 00*,P,F) Sjep-.PABS
TRIANGLE LABS Text: M23-OVTLST-ROTf-2 TLIK42299B
100* A1.92E7
80.
60.
36 00
40.
20.
^^^^j^
1. 8E6
.1.4E6
.1.1X6
_7.1BS
-3.5ES
20:00 22:00 ' 24:00 ' 2^-00 ' 28 i 0(7
'Il*:ff972697 tl-1377 Acg: 13-AOG-1997 04:48t51 OC EI+
268.9824 F:4 ExpiPABS
TRIANGLE LABS T»xt: M23-OUTLST-ROV-2 TLI#42299B
30tOO 32:00
SIR 70S
34'sOO
.O.OEO
1005
80.
60.
40,
20.
0.
22:53 24:23
25:19 26:33
36 00 Time
,.3. OE7
20 00
22:00
24100
26:00
28:00
30:00
32 tOO
34100
'.1 . 8S7
.1.2S7
'.6. OE6
.O.OSO
36 00 T±m»
-------
Peak Locate Examination:13-AUG-1997:04:47 File:U972697
Experiment:PAH5 Function:3 Reference:PFK
"CO"
-------
File:U972697 #1-702 Acq:13-AUG-1997 04:48:51 GC EI+ Voltage SIR 70S
202.0782 F:3 Exp:PAH5
Sample Text: M23-OUTLET-RUN-2 TLI#42299B File Text:TRIANGLE LABORATORIES ,
100% 16O17_
90 j
80 j
70J
60J
50J
40 j
30 J
20 j
INC
10
15:48
T
'leliV ' ' 16 1 2*4'
15:48 15:54 16:00 16:06
?ile:U972697 #1-702 Acq:13-AUG-1997 04:48:51 GC EH- Voltage SIR 70S
212.1410 F:3 Exp:PAH5
Sample Text: M23-OUTLET-RUN-2 TLI#42299B File Text:TRIANGLE LABORATORIES ,
100%, A3 .
INC
90J
80J
70 j
60J
50 J
40 j
30J
20 J
10 j
OJ
8E7
T
T
T
1548 1554 1600 1606 16 12 16 18
16:24
'l'6!4'2'
_1.1E9
_9.7E8
_8.6E8
_7.5E8
_6.4E8
_5.4E8
_4.3E8
_3.2E8
_2.1E8
O.OEO
Time
1.3E7
Ll.1E7
Ll.OE7
_8.9E6
L7.6E6
L6.3E6
L5.1E6
L3.8E6
L2.5E6
_1.3E6
^O.OEO
Time
00
-------
File:U972697 #1-702 Acq:13-AUG-1997 04:48:51 GC EI+ Voltage SIR 70S
228.0939 F:3 Exp:PAH5
Sample Text: M23-OUTLET-RUN-2 TLI#42299B File Text:TRIANGLE LABORATORIES
100%, A2.21E9
90 J
80 J
70J
60J
50J
401
30J
20J
10J
INC
A1.91E9
19:18 19:24 19:30 19:36
File:U972697 #1-702 Acq:13-AUG-1997 04:48:51 GC EI+ Voltage SIR 70S
240.1692 F:3 Exp:PAH5
Sample Text: M23-OUTLET-RUN-2 TLI#42299B File Text:TRIANGLE LABORATORIES , INC
100%.
90J
80 J
70J
60 J
50J
40J
30J
20 J
10J
19:22
19:32
19:18
19:24
19:30
19:36
9.1E8
L8.2E8
-7.3E8
-6.4E8
L5.5E8
L4.5E8
L3.6E8
L2.7E8
L1.8E8
L9.1E7
LO.OEO
Time
1.0E7
L9.3E6
L8.2E6
L7.2E6
L6.2E6
L5.1E6
L4.1E6
L3.1E6
L2.1E6
L1.0E6
.LO.OEO
Time
01
-------
File:U972697 #1-702 Acq:13-AUG-1997 04:48:51 GC EI+ Voltage SIR 70S
228.0939 F:3 Exp:PAH5
Sample Text: M23-OUTLET-RUN-2 TLI#42299B File Text:TRIANGLE LABORATORIES ,
19:04 19:06 19i08 19ilO 19ll2 19ll4 19il6 19ll8 19120 19I22 ' 19J24
File:U972697 #1-702 Acq:13-AUG-1997 04:48:51 GC EI+ Voltage SIR 70S
240.1692 F:3 Exp:PAH5
Sample Text: M23-OUTLET-RUN-2 TLI#42299B File Text:TRIANGLE LABORATORIES
100* A2.93E7
19
126 ' 19128
INC
19:04 19:06 19:08 19:10 19:12 19:14 19:16 19:18
00
Q)
-------
File:U972697 #1-1377 Acq:13-AUG-1997 04:48:51 GC EI+ Voltage SIR 70S
252.0939 F:4 Exp:PAH5
ample Text: M23-OUTLET-RUN-2 TLI#42299B File Text:TRIANGLE LABORATORIES
lOOi A6.3.0E9
90 J
80J
70J
60 J
50 j
40 j
30J
20 J
10J
0 ,
23:06 ' ' ' 23ll2 ' ' 23:18 23:24 23i30 23i36
File:U972697 #1-1377 Acq:13-AUG-1997 04:48:51 GC EI+ Voltage SIR 70S
264.1692 F:4 Exp:PAH5
Sample Text: M23-OUTLET-RUN-2 TLI#42299B File Text:TRIANGLE LABORATORIES
INC
23:42
INC
100%
90 J
80J
70 j
60J
50 J
40J
30 J
20 J
10J
23:19
23:27
23I06
23:12
23:18
23124
1 1 r—
23:30
23:36
_1
.1.8E7
.1.6E7
.1.4E7
.1.3E7
1E7
9.0E6
7.2E6
5. 4E6
3.6E6
1.8E6
O.OEO
Time
OO
-------
File:U972697 #1-1377 Acq:13-AUG-1997 04:48:51 GC EI+ Voltage SIR 70S
276.0939 F:4 Exp:PAH5
Sample Text: M2 3-OUTLET-RUN-2 TLI#42299B File Text .-TRIANGLE LABORATORIES , INC
A5.64E8
90J
80J
70J
60 j
50J
40J
30J
20J
10J
0
31:00 32:00 33:00
File:U972697 #1-1377 Acq:13-AUG-1997 04:48:51 GC EI+ Voltage SIR 70S
288.1692 F:4 Exp:PAH5
Sample Text: M23-OUTLET-RUN-2 TLI#42299B File Text:TRIANGLE LABORATORIES , INC
100% A2.56E7
90J
80J
70J
60J
50J
40 j
30J
20 J
10J
0
34100
3i!oo
32IOO
34:00
5.6E7
5.0E7
4.4E7
3.9E7
3.3E7
2. 8E7
2.2E7
1.7E7
1.1E7
.5.6E6
.O.OEO
Time
.2.3E6
.2.1E6
.1.8E6
.1.6E6
1.4E6
.1.2E6
.9.2E5
.6.9E5
.4.6E5
.2.3E5
.O.OEO
Time
OO
CO
-------
File:U972697 #1-1377 Acq:13-AUG-1997 04:48:51 GC EI+ Voltage SIR 70S
278.1096 F:4 Exp:PAH5
Sample Text: M23-OUTLET-RUN-2 TLI#42299B File Text:TRIANGLE LABORATORIES , INC
lOOi A2.Q2E8
90 J
80J
70 J
60 J
50 J
40J
30J
20 J
10J
OJ
T
T
T
29:00 30:00 31:00 32iOO 33100 34JOO
File:U972697 #1-1377 Acq:13-AUG-1997 04:48:51 GC EI+ Voltage SIR 70S
292.1974 F:4 Exp:PAH5
Sample Text: M23-OUTLET-RUN-2 TLI#42299B File Text:TRIANGLE LABORATORIES , INC
lOOi A2.13E7
90J
80 J
70J
60 J
50J
40J
30J
20J
10J
OJ
isloo
29-100
00
CD
30:00
ii!o6
32:00
33lo6
34:00
ssloo
.1.6E7
.1.4E7
.1.3E7
.1.1E7
.9.4E6
.7.8E6
.6.3E6
.4.7E6
.3 . 1E6
.1.6E6
.O.OEO
Time
.1.8E6
.1.6E6
.1.4E6
.1.2E6
.1.1E6
.8.8E5
.7 . 1E5
.5.3E5
.3.5E5
.1.8E5
-O.OEO
Time
-------
TLI Project: 42299B
Client Sample: M23-Outlet-Run 3
PAHJ Analysis (a)
Analysis File: U972699
Client Project: Iron & Steel-Chicago
Sample Matrix: MM5 Date Received: 07/01/97
TLI ID- 173-61-3A-D Date Extracted: 07/17/97
Date Analyzed: 08/13/97
Sample Size: 1.000
Dry Weight: n/a
GC Column: DB-5
AnaJytBS- ' \ '- '"
Fluoranthene
Pyretic
Benzo(a)anthracene
Chrysene
Perylene
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Benzo(a)pyrene
Benzo(e)pyrene
Benzo(g,h,i)perylene
Indeno( 1 ,2,3-cd)pyrene
Dibenz(a4i)anthracene
internal Standards
di2-Benzo(a)anthracene
dio-Fluorantliene
dn-Chrysene
di2-Perylene
di2-Benzo(b)fluoranthene
di2-Benzo(k)fluoranthene
di2-Benzo(a)pyrene
di2-Benzo(g,h,i)perylene
di2-Indeno(l ,2,3-cd)pyrene
di4-Dibenz(a,h)anthracene
Recovery Standards '"""" '-^ "
dio-Pyrene
di2-Benzo(e)pyrene
^*XL\
14140
12540
3600
6610
490
7270
2220
2030
4710
4070
2910
1010
Amt,
320
102
224
111
235
176
216
188
285
383
X
Dilution Factor: n/a
Blank File: U972695
Analyst: HLM
;r,rr^&r-: aipo
(K$ %Be«0y«y <3CUrnite
320 40%-130%
102 40%-130%
224 40%-130%
88.6 40%-130%
117 40%-130%
88.0 40%-130%
108 40%-130%
94.2 40%-130%
143 40%-130%
192 40%-130%
"'^W'^*"^ --
Spike FUe: SPPAHJ10
ICal: UPJ8127
ConCal: U972690
% Moisture: n/a
% Lipid: n/a
% Solids: n/a
'"- ?&tifr$s^ Ht
15:35
16:10
19:20
19:27
25:29
23:25
23:54
25:03
24:47
34:49
32:34
32:50
Ratio RT
19:16"
15:31
19:24
25:20
23:18
23:27
24:55
34:34
32:23
32:36
" V' *' /" < 8* *
16:06
24:38
flag*
s_
s_
PR-
PR-
—
PR-
PR-
—
—
PR_
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—
—
—
—
—
—
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I
- *kgs
— —
—
Data Reviewer.
Page 1 of 1
08/21/97
PAHLPSR rlOO, LARS 6.10.03
Triangle Laboratories, Inc.®
801 Caprtota Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 14:25 Ofi2J/97
-------
Data Review By:
Initial
..Date.,
Calculated Noise Area: n/a
Page No.
08/21/97
Listing of O972699B.dbC
Hatched <3C Peaks / Ratio / Ret. Time
Compound/
M_2.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak. 1. . Area.Peak.2. . Rel.RT Compound.Name.. ID.,
Flags.
Fluoran
202
202
dlO-Pluoran
212
M
212
B-a-Anth
228
M
M
228
d!2 -B-a-Anth
240
H
MTN
240
B-b-Fluoran
252
0.354-1.646
DC NL 0:
14:
14:
14:
15:
15:
15:
15:
16:
17:
18:
18:
00
14
18
31
10
35
42
48
10
15
19
37
11 Peaks
15
14
4
216
15
512
6
12
465
8
9
17
1,281
,202
,132
,005
,445
,033
,557
,140
,617
,920
,212
,465
.111
,640
.50
.40
.48
.00
.10
.00
.96
.70
.00
.48
.38
.10
.60
14
4
216
15
512
6
12
465
8
9
17
,132.
,005.
,445.
,033.
,557.
,140.
,617.
,920.
,212.
,465.
,111.
40
48
00
10
00
96
70
00
48
38
10
0
0
0
0
0
1
1
1
1
1
1
1
.000
.917
.922
.936
.977
.004 Fluoran AN S
.012
.018
.042 Pyrene AN S
.112
.180
.200
0.290-1.646
DC NL 0:
15:
16:
00
31
06
2 Peaks
1
2
3
,231
,504
,140
.76
.34
.00
5,644.34
DC NL 0:
14:
16:
16:
18:
18:
18:
18:
19:
19:
19:
00
05
12
36
07
18
26
43
20
27
42
10 Peaks
DC NL 0:
19:
19:
00
16
24
2 Peaks
DC NL 0:
00
1
9
2
2
3
1
27
104
159
4
317
1
2
1
3
1
656
,792
,815
,425
,505
,706
,664
,779
,000
,000
,471
,161
,959
,090
,300
,890
,422
.80
.69
.86
.76
.65
.21
.60
.80
.00
.00
.28
.85
.94
.00
.00
.00
u /
Q /
.71
2
3
,504.
,140.
34
00
0
1
1
.000
.000 dlO-Fluoran IS5
.038 dlO-Pyrene RS2
1
9
2
2
3
1
27
104
159
4
2
1
T> _w _T7l
O~D f±
,792.
,815.
,425.
,505.
,706.
,664.
,779.
,000.
,000.
,471.
,090.
,800.
uorsjo
69
86
76
65
21
60
80
00
00
28
00
00
0.481-1.519
0
0
0
0
0
0
0
0
1
1
1
0.481
0
1
1
.000
.731
.841
.862
.940
.950
.957
.971
.003 B-a-Anth AN PR
.010 Cbrysene AN PR
.02^
-1.519
.000
.000 d!2-B-a-Anth IS6
.007 d!2-chrysene islO
0.606-1.394
0
.000
Triangle Laboratories, Inc.® Analytical Services Division
801 Capftola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 14:25 08/21/97
n •«
-------
Page No. 2
08/21/97
Compound/
M_Z QC.Log Omit Why
Listing at O972699B.dbf
Matched OC Peaks / Ratio / Ret. Tim*
.RT. OK Ratio Total.Area... Area.Peak. 1.. Area.Peak.2. . Rel.RT Compound.Ham*.. ID.. Flags.
H
MN
252
d!2-B-b-Fluoran
264 DC
264
I-123-cd-Py
276 DC
DC
DC
DC
DC
DC
DC
DC
DC
M
276
20:54
21:04
21:20
21:32
23:25
23:54
24:47
25:03
25:29
9 Peaks
NL 0:00
23:18
23:27
24:38
24:55
25:20
5 Peaks
NL 0:00
WL 20:43
WL 22:12
WL 22:32
WL 22:53
WL 23:06
WL 23:16
WL 23:47
WL 24:24
24:42
25:00
25:24
26:11
26:51
27:27
28:04
28:24
30:00
30:33
31 : 04
31:48
32:34
33:13
33:42
34:00
34:49
17 Peaks
2,167.22
11,335.40
3,707.39
9,806.34
324,000.00
95,100.00
172,769.00
59,413.60
12,207.20
690,506.15
88.35
7,163.59
6,548.69
2,579.62
4,011.00
4,324.68
24,627.58
p Atoove : B— o— Fluoirau / I~]
192.54
214.79
3,457.18
4,516.40
7,649.54
3,831.66
8,866.47
5,879.43
1,729.79
2,265.31
1,760.06
2,021.89
1,730.89
1,584.51
363.18
1,007.29
361.22
6O6.40
3,470.23
1,511.38
13,312.30
29,500.00
1,206.04
1,390.95
2,599.05
38,678.90
103,369.60
2,167.22
11,335.40
3,707.39
9,306.34
324,000.00
95,100.00
172,769.00
59,413.60
12,207.20
7,163.59
6,548.69
2,579.62
4,011.00
4,324.68
2,265.31
1,760.06
2,021.89
1,730.89
1,584.51
363.18
1,007.29
361.22
606.40
3,470.23
1,511.38
13,312.30
29,500.00
1,206.04
1,390.95
2,599.05
38,678.90
0.825
0.832
0.842
0.850
0.924 B-b-Fluoran AN PR
0.943 B-k-Fluoran AN PR
0.978 B-e-Pyrena AN
0.989 B-a-Pyrene AN
1.006 Perylene AN
0.606-1.394
0.000
0.920 d!2-B-b-Fluoran isll
0.926 d!2-B-k-Fluoran is!2
0.972 d!2-B-e-Pyrene RS3
0.984 dl2-B-a-Pyrene isl3
1.000 d!2-Perylene IS7
0.711-1.289
0.000
0.599
0.642
0.652
0.662
0.668
0.673
0.683
0.706
0.715
. 0.723 . _
0.735 ~
0.757
0.777
0.794
0.812
0.822
0.868
0.884
0.899
0.920
0.942 I-123-cd-Py AN PR
0.961
0.975
0.984
1.007 B-ghi-Pery AN
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 14:25 08/21/97
92
-------
Page Mo.
08/21/97
Listing of O972699B.dbf
Matched GC Peaks / Ratio / Ret. Tim*
Compound/
M_Z QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Campound.Name.. ID.
Flags.
DiB-ah-Anth
278
278
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
WL
WL
WL
WL
WL
WL
WL
WL
WL
WL
WL
6
0:00
23:
23:
24:
24:
25:
25:
26:
26:
28:
30:
30:
31:
31:
32:
33:
33:
34:
06
48
22
42
00
25
11
51
03
00
33
07
48
50
15
42
00
Peaks
Above: I-123-cd-Py / DiB-ah-Anth Follows
229.03
2,613.25
360.36
246.22
2,349.57
1,620.37
1,862.95
3,120.61
2,802.45
1,542.25
587.53
2,559.13
1,131.00 1,131.00
6,170.37 6,170.37
10,600.00 10,600.00
2.024.72 2,024.72
3,334.03 3,334.03
6,580.24 6,580.24
29,840.36
Above: DiB-ah-Anth / d!2-I-123-cd-Py Follows
0.939-1.061
0.000
0.709
0.730
0.747
0.758
0.767
0.780
0.803
0.824
0.860
0.920
0.937
0.954
0.975
1.007 DiB-ah-Anth
1.020
1.034
1.043
AH
d!2-I-123-cd-Py
288 DC
M
288
NL
0:00
32:23
34:34
2 Peaks
137.50
1,740.00
1,469.54
3,209.54
1,740.00
1,469.54
0.711-1.289
0.000
0.937 d!2-I-123-cd-Py is!4 I
1.000 d!2-B-ghi-Pery IS8
Above: d!2-I-123-cd-Py / d!4-DiB-ah-Anth Follows
d!4-DiB-ah-Anth
292 DC
DC
M
292
NL
ML
0:00
20:24
32:36
1 Peak
79.86
181.98
1,340.00
1,340.00
1,340.00
0.939-1.306
0.000
0.626
1.000 dl4-DiB-ah-Anth IS9
Column Description.
•Why Code Description QC Log Desc.
M_Z -Nominal Ion Mass(es)
..RT. -Retention Time (nxn:ss)
Rat.l -Ratio of M/M+2 Ions
OK -RO=Ratio Outside Limits
Rel.RT-Relative Retention Time
End of Report ***
WL-Below Retention Time Window
WH-Above Retention Time Window
SM-Below Signal to Noise Level
-------
Sile:U972699 #1-294 Ac00 7,'00
'ile:U972699 #1-294 Acq: 13-AUO-1997 06155:28 OC Elf Voltage SIR 70S
154.9920 BxpiPABS
TRIANGLE LABS Text: X23-OUTLST-RUN-3 TLI#42299B
100* 6:51
ao:
eo:
8:00
0.020
Time
to:
20:
6:38
5:05
5s 34
5:48 6:00 6:14 6:27
7il6
1.5S7
.1.2S7
.9.2B6
-6.1E6
.3.1X6
ft 00
7:00
.'.O.OSO
8:00 Time
-------
flle:U972699 91-535 Acq:13-AUQ-199J O6l55t*B (K KJ.+ Voltage SIX 70S NOlme:1O1OO95Q3
152.0626 P:2 B3VB(256,30, -3.0) PXD(3,3,9, 0.01*,404038016. 0,0.00*,P,f) ExptPABS
TRIANGLE LABS Text: H23-OUTLST-ROIT-3 TLI142299B
100* 8 3J. jftjS .10{44 1 f.58
80.
50.
40.
20.
0.
8tOO 9iOO lOtOO lltOO 12:00 13:00
Plle:U972699 #1-535 Acq: 13-AUQ-1997 06:55:28 OC «Z> Volta.au SIR 70S Hoimet305€571
160.1128 Ps2 BSUB(256,30,-3.0) PXD(3,3,9,0.01*,12226284.0,0.00*,P,P) SxptPASS
TRIANGLE LABS Text: U2 3-OUTLET-SON-3 TLHH2299B
100*
.B.6S8
.6.4X8
_4.3EB
_2.1E8
O.OSO
14100 Tlm»
ao:
60:
40.
20:
3:32
9:14
12:4313:03 13:30
4.7S7
.3.7S7
.2.8S7
.1.9B7
-9.3B6
8:00 9:00 10:00 11:00 12:00 13:00
Pile:U972699 #1-535 Acg:13-AUO-1997 06:55:28 OC Elf Voltage SIR 70S Noise:40636810
154.0782 P:2 BSUB(2S6,30,-3.0) PKD(3, 3,9, 0.01*, 162547248.0,0. 00*,P,F) Exp:PAB5
TRIANGLE LABS Text: H2 3-OUTLET-RUN-3 TLI#42299B
100% 8 £6
SOJ
so:
O.OEO
14:00 Time
40:
20:
8:00 9:00 10:00 11:00 12:00 13:00
Pllo:U972699 #1-535 Acg:13-AUQ-1997 06:55:28
-------
\MlfiU972f~99 #1-394 Aoyil3-AJje-i997 OS:55,3B'X g* Volkmg* SIR 70S Bolf»,13051S
162.0236 aaOB(256,30,-3.0) PXO(3,2,8,1.00*,4820fO.O,O.OO*,F,F) XxpsPABS
TRIANOLS LABS T»Xt! H23-OUTLST-RUS-3 TLI#42299B
10 OH
80.
60.
40.
20.
7s.41
7s55 •
A
-7.1X8
15.7X0
.4.3SB
'.2.8S8
1.4SS
Si 00 ft 00 7100
FllasU972699 #1-294 Acqsl3-AVO-1997 06:55:38 OC K> Voltage SIR 703 Soif9:88094
164.0207 8303(256,30,-3.0) PXD(3,2, 8,1.00*,352376.0,0.00*,F,F) XxpsPABS
TRIANGLE LABS Tmxts H23-OUTLET-RUN-3 TLI#42299B
100*
80:
eo:
40:
20:
0.0X0
8:00 Timf
7 .41
-2.1S8
'.1. 7S8
'.1.2S8
.8.3B7
'.4.1S7
5:00 6:00 7s 00
Fila:U972699 #1-294 Acqi 13-AOO-1997 06:55:28 OC BI+ Voltage SIR 70S Soia»sl53274
169.0676 BSVB(3S6,30,-3.0) PXD(3,2,8,1.00\, 613096.0, 0.00*,F,F) ExpsPABS
TRIANGLE LABS T*xt: K23-OUTLET-RUN-3 TLI#42299B
100*
81
o.oso
00 Tia»
7:39
5:00 6s00 7s00
Pilt:U972699 #1-294 Acgs 13-AOG-1997 0€s55s28 GC EH- Voltagu SIR 70S Soia»s78134
171.0648 BSUB(256,30,-3.0) PKD(3,2, 8, 1.00*,312536. 0, 0.00*,P,P) E3cp:PAS5
TRIANGLE LABS TKCCs M23-OUTLET-RON-3 TLI#42299B
100* 5:34
flOj
60:
O.OEO
8:00 Tim*
40:
201
5." 00 6 tOO 7 iOO
'±l»sU972699 #1-294 Aays13-AUG-1997 06sS5s28 GC SX+ Voltage SIR 70S
54.9920 SxpsPABS
'RIASOLS LABS Text: H23-ODTLET-RUN-3 TLI042299B
6s 51
80.
60.
40.
20.
6,38
5x05
5s 34
SsJS ft 00 Stl4 ft27,
00
6:00
7:00
O.OSO
8s 00 Time
rl.SS7
.1.2X7
,.9.2X6
-6.1X6
'.3.1X6
0.0X0
8s 00
-------
Fll»lO973699 91-535 Aoqs13-AUO-1997 OStSSliO OC JU* Voltage SIS 70S BOlm*t13951646
166.0782 F:2 BSUB (256,30,-3.0) PXD(5,1,1, 0.50*,S5806S84.0, 0. 00*,F,F} SatptPABS
TRIAmLX LABS TUXt: M23-OUrLXT-ROJI-3 71,1*422993
100* A7+22B9
9:00 lOtOO 11:00 12:00 13*00
Fil»:U972699 01-535 Ac(S,1.1,0.50*.2108612.0,0.00*,F,F) XxptPABS
TRZANOLE LABS Tajft: 1123-OUTLET-SOS-3 TtiX*42299B
100* .
so:
8:00 9:00 10:00 11:00 12:00 13:00
Fil»:U972699 #1-535 Acg: 13-AUO-1997 06:55:28 OC EZ> Voltaff* SIR 70S KOia«:5232045
178.0782 P:2 BSUB (256, 30,-3.0) PXD(5, 1,1, 0.50*,20928180. 0, 0. 00*,F,F} SxpsPAHS
TRUWQLE LABS T«ctJ M23-OVTLST-RVN-3 TLI*42299B
401
201
A1.92B7
A8.J8S6
A3.14E6
A3.1787
A4.24S6I
8:00 9:00 10:00 11:00 12:00 13:00
Pil»:U972699 #1-535 Acq: 13-AUO-1997 06:55:28 OC ST* Voltage SIR 70S Hois«:1532856
188.1410 F:2 BSUB (256, 30, -3 .0) PKD(5, 1,1, 0.50*, 6131424. 0,0. 00*,F,F) BXp:PAB5
TRIANOLE LABS T«ct: H2 3 -OUTLET -RUN- 3 TLI#42299B
lOOSf
so:
eo:
401
201
0
A4.99E7
8:00 9tOO 10:00 11:00 12:00
Fil«:U972699 #1-535 Acq: 13-AUO-1997 06:55:28 OC BI+ Voltag* SIR 70S
168.9888 F:2 Bxp:PAB5
TRIANOLE LABS T»Xt: H2 3 -OUTLET -RUN- 3 TLI#42299B
1009
13:00
14 00
o.oso
Via*
14:
2.9E7
.2.4S7
-1.8B7
11.2E7
.5.9E6
.0. OEO
00 Tim*
14
.O.OEO
> 00 Tim*
-1.2E8
-7.0E7
.4.6E7
.2.3E7
O.OEO
14 00
801
601
401
201
13:38
8:38
- „
"
9:41
_5.5B7
.4.437
.3.3X7
.2.2X7
.1.1X7
8:00
9100
'lOrOO
•" 1 r"
lltOO
13; 00
.O.OSO
14 00 Ttm»
97
-------
Pilf:U972699 #1-703 Aaq:13-AOO-1997 06iS5t28 OC XT* Voltmg* SIS 703 Ooim»t76012Sl
202.0782 P:3 B3UB(256, 30, -3.0) PXD(5,3,1, 0.10*, 30405004. 0,0. 00*,P,P) SxptPABS
TSIASOLB LABS Texts H23-OUTLXT-Sna-3 TLI642299B
100* A5.13S9 A4.66E9
801
sol
401
201
01
A2.16S9
A1.41S8,
A1.SOB8
A8.21S7
A1.71B8
1.1X9
'-.8.6S8
.6.4B8
.4.3S8
-3.1S8
14tOO 15:00 16s00 17:00 18,00 19>00
P11»:U972699 91-703 JLaytl3-XOO-1997 06i55t28 OC SI* Voltag* SIX 703 Bo±m»t615878
212.1410 Ps3 BSUB(2S6,30,-3.0) PXD(S.3,1, 0.10*,2463512.0, 0.00*,P,P) SxptPABS
TRUUtOLS LJL33 Trnxt: H23-OUTLXT-RUN-3 TU*42299B
100H
O.OSO
20 00 Time
14 00 15:00 16:00 17:00 18:00
Pil»:U972699 #1-703 Ac
-------
Pil»tU972699 91-1377 Actjt 13-AUO-1997 OSi55t28 OC XI+ Voltmff* SIR 70S Hoit»l711355
252.0939 Pt4 B3OB(256,30,-3.0) PXD(7,5,3,O.2O*,2a45420.0,0.00*,P,r) XarptPABS
TRIAOOLX LABS T«UCtl JQ3-ODTL2T-JIOV-3 TLIt42299B -
1001
90:
so:
70:
60:
so:
40:
30:
20:
10:
20
A4.
A1.13ES
T.A«A J
0X9
A1.73X9
-
A
ft
A
U lUU
00 22:00 24:00 2«:00 20:00 30:00 32:00 34:00 36
5.4X8
'-.4.9X8
-.4.4X8
.3.8X8
-.3.3X8
-.2.7X8
-.2.2X8
.1.6X8
-.1.1X8
-.5. 4X7
00 Tim*
Pil»:U972699 #1-1377 AO3:13-AUO-1997 06:55:28 OC JBJ+ Voltag* SIR 70S Boigfs 44177
264.1692 P:4 BSUB (256, 30, -3 . 0) PKD(7,S,3,0.20*,176708.0,O.OOX,P,P) Xxp:PAB5
TRIANGLE LABS Tmxts M23 -OUTLET- RUN- 3 TLI#42299B
10(9
90:
80:
70:
60:
so:
40:
30:
20:
10:
20
A7.1
!
i . __J.
657
•
1 A4.32E7
... -
•00 22:00 24:00 ' 25:00 2fli-00 ' 30:00 32:-00 34:00 36
1.4X7
.1.2X7
.1.1S7
_9. 6X6
-.8.3X6
_6.9E6
.5.5X6
.4.1X6
_2 . 8X6
.1.4X6
_ 0 . O.EO
00 Tims
PilasU972699 #1-1377 Acq:13-AVO-1997 06:55:28 QC XI* Voltafff SIR 70S
268.9824 P:4 XxpsPABS
TRIANOLE LABS Text: M2 3 -OUTLET- RUN- 3 TLI#42299B
100* 23:09 2.2X7
H aois.L^W^ , "J" • M-^
kJftWnrf' r^iHi^ ««" r
•JMf" ^*Tf^^
60:
so.
40:
30.
20:
10.
o:
.
20:00 22'tOb 24:00 2ff»00 ' 28:00 ' 30:00 32:00 34:00 ' ' ' 3*
.1.3S7
_i.l*7
.a.sse
.6. 7X6
.4.5X6
.2.2X6
0.0X0
00 Tim*
99
-------
P11»:U973699 91-1377 Acqi lJ-AUO-1997 06:55:28 OC JSi+ Volttgu SIX 70S Hoi*»:96268
276.0939 P:4 BSUB(256,30, -3.0) PKD (15,13,11, 0.50*, 385072. 0,0.00*,P,P) Bxp:PAH5
TRXASOLB LABS Ttact: M23-OUrLXT-SOS-3 TLHH2299S
80.
60.
40.
20.
OJ
A7.65E7
A2.02X7
A3.4757
A3.87X8
JL1.33S8
A2.60S
XX/V
20 00 22iOO 24:00 26:00 28(00 30<00 32tOO 34,00
Pil»>1T972699 #1-1377 Acq: 13-AUO-1997 06:55:28 OC XI+ Voltaff* SIS 70S Se>im»t68752
288.1692 Ps4 BaUB(256,30,-3.0) PXD( 15,13,11, 0.50*,275008. 0,0. 00*,P,P) JBcp«PAH5
TJOJUSOLB LASS Twcti X23-OUTLET-RUN-3 TLH42299B
loon,
A2.22S7
r3.3JB7
.2.6B7
'.2.0X7
.1.3S7
'.6.6X6
-r^.O.OBO
36 00 Tia»
20:00 22:00 24:00 26': 00 28:00 30:00 32:00 34:00
Pil»:U972699 #1-1377 Acq: 13-AUQ-1997 06:55:28 GC BI+ Voltag» SIR 70S tloia»:114513
278.1096 P:4 BflTOB (256,30, -3. 0) PKD(1S, 13, 11,0.50*, 458052.0,0, 00*,F,P) Sxp:PAB5 .
TRIANGLE LASS TfJCti H23-OOTLBT-ROlf-3 TLIX42299B
A1.04E8
20:00 22:00 24:00 26:00 28:00 30:00 32:00- 34:00
'ila:U972699 #1-1377 Acq: 13-AUO-1997 06:55:28 OC Slf Voltagu SIR 70S Uoisf.39929
392.1974 P:4 BSUB (256,30, -3 .0) fXD(15, 13, 11, 0.50*, 159716. 0,0. 00*,P,P) Bxp.-PABS
TRIANOLS LABS TfJcC: K23-OUTLET-RUN-3 TLX#42299B
100%
80.
601
40.
20.
o:
Al. 21E7
rr
rr
~r
rr
20«00 22*00 24»00 2ff*00 28:00 30/00 32JOO
'±1«:U972699 #1-1377 Acq:13-AVO-1997 06:55:28 QC XX+ Volt*g» SIR 70S
68.9824 P:4 XxptPABS
TRXAHOLB LABS Tmxt: H23-OUTLXT-RUII-3 TLI042299B
34:00
36 00
O.OBO
Time
.O.OBO
36 00
p3.2B6
.2. 5B6
.1.9E6
-1.3E6
-6.3ES
'.O.OEO
36 00 Time
1 no
-------
File:U972699 #1-703 Acq:13-AUG-1997 06:55:28 GC EI+ Voltage SIR 70S
202.0782 F:3 Exp:PAH5
Sample Text: M23-OUTLET-RUN-3 TLI#42299B File Text:TRIANGLE LABORATORIES
100% 16,.
90 J
80J
70J
60 J
50J
40J
30J
20 J
10J
INC
15:54 16:00 16:06 16:12 16:18 16:24 16:30
16:36 16:42 16:48 16:54
File:U972699 #1-703 Acq:13-AUG-1997 06:55:28 GC EI+ Voltage SIR 70S
212.1410 F:3 Exp:PAH5
Sample Text: M23-OUTLET-RUN-3 TLI#42299B File Text:TRIANGLE LABORATORIES (
100% A3.14E7
90 J
80J
70 J
60J
50J
40 J
30J
20J
10 J
0
17:00 17:06
INC
i i I i i i i i i i i i i i I i i i i i I i i i i i I i i i i i I i i i i i I i i i i i I i i i i i I i i i i i I i i i i i I i i i i i I i i i i i l i i
15:54 16:00 16:06 16:12 16:18 16:24 16:30 16:36 16:42 16:48 16:54 17:00 17:06
.1.1E9
.9.7E8
.8.6E8
L7.5E8
6.4E8
5.4E8
4.3E8
3.2E8
2.1E8
1.1E8
O.OEO
Time
.1.4E7
.1.2E7
.1.1E7
.9.6E6
.8.2E6
.6.9E6
5.5E6
.4.1E6
2.7E6
1.4E6
.O.OEO
Time
-------
File:U972699 f1-703 Acq:13-AUG-1997 06:55:28 GC EI+ Voltage SIR 70S
228.0939 F:3 Exp:PAH5
Sample Text: M23-OUTLET-RUN-3 TLI#42299B File Text:TRIANGLE LABORATORIES , INC
100% A1.59E9
90J
80J
70J
60J
50 j
40 j
30J
20J
10 J
OJ
A1.04E9
19:42
19:06 19:12 19:18 19:24 19:30 19:36
File:U972699 #1-703 Acq: 13-AUG-1997 06:55:28 GC EI+ Voltage SIR 70S
240.1692 F:3 Exp:PAH5
Sample Text: M23-OUTLET-RUN-3 TLI#42299B File Text:TRIANGLE LABORATORIES , INC
100% A2.Q9E7
90J
80 j
70J
60 J
50 J
40J
30J
20J
10J
19:48
4.8E8
L4.3E8
L3.8E8
L3.3E8
L2.9E8
L2.4E8
L1.9E8
Ll.4E8
19.5E7
L4.8E7
LO.OEO
Time
19:06
19:12
19:18
19:24
19:30
19:36
19:42
19:48
J7.7E6
L7.0E6
L6.2E6
L5.4E6
L4.6E6
L3.9E6
L3.1E6
L2.3E6
L1.5E6
L7.7E5
LO.OEO
Time
O
10
-------
File:U972699 #1-1377 Acq:13-AUG-1997 06:55:28 GC EI+ Voltage SIR 70S
252.0939 F:4 Exp:PAH5
Sample Text: M23-OUTLET-RUN-3 TLI#42299B File Text:TRIANGLE LABORATORIES , INC
100% A3.24E9
23112 23118 23124 23i30 23i36 23i42 ' 23! 48
File:U972699 #1-1377 Acq:13-AUG-1997 06:55:28 GC EI+ Voltage SIR 70S
264.1692 F:4 Exp:PAH5
Sample Text: M23-OUTLET-RUN-3 TLI#42299B File Text:TRIANGLE LABORATORIES , INC
100% 23 U8
23:54
90J
80J
70J
60J
50J
40J
30J
20 j
10 j
OJ
23:27
23 112
23 ! 18
23:2 4
23: 30
23: 3 6
23:42
23 ! 48
23:54
.5.5E8
.4.9E8
.4.4E8
.3.8E8
.3.3E8
.2.7E8
.2.2E8
.1.6E8
.1.1E8
.5.5E7
.O.OEO
Time
.1.4E7
.1.3E7
.1.1E7
.9.7E6
.8.3E6
.7 . OE6
.5.6E6
.4.2E6
.2.8E6
-1.4E6
.O.OEO
Time
O
CO
-------
F±le:U972699 #1-1377 Acq:13-AUG-1997 06:55:28 GC EI+ Voltage SIR 70S
276.0939 F:4 Exp:PAH5
Sample Text: M23-OUTLET-RUN-3 TLI#42299B File Text:TRIANGLE LABORATORIES , INC
A2.95E8
90J
34:00
32:00 33:00
File:U972699 #1-1377 Acq:13-AUG-1997 06:55:28 GC EI+ Voltage SIR 70S
288.1692 F:4 Exp:PAH5
Sample Text: M23-OUTLET-RUN-3 TLI#42299B File Text:TRIANGLE LABORATORIES INC
A1.74E7
Time
-------
File:U972699 #1-1377 Acq:13-AUG-1997 06:55:28 GC EI+ Voltage SIR 70S
278.1096 F:4 Exp:PAH5
Sample Text: M23-OUTLET-RUN-3 TLI#42299B File Text:TRIANGLE LABORATORIES , INC
lOOi A1.06E8
90J
801
70J
60 j
50 J
40 J
30J
20 j
10J
OJ
32:00 33:00 34:00 35:00
File:U972699 #1-1377 Acq:13-AUG-1997 06:55:28 GC EI+ Voltage SIR 70S
292.1974 F:4 Exp:PAH5
Sample Text: M23-OUTLET-RUN-3 TLI#42299B File Text:TRIANGLE LABORATORIES , INC
100%, A1.34E7
_7
9.4E6
8.4E6
5E6
6.5E6
5.6E6
4.7E6
3.7E6
2.8E6
1.9E6
9.4E5
O.OEO
Time
-------
TLI Project: 42299B
Client Sample: M23-Outlet-FBl
PAHJ Analysis (a)
Analysis File: U972700
Client Project:
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
Iron & Steel-Chicago
MM5
173-61-4A-D
-
1.000
n/a
DB-5
Date Received:
Date Extracted:
Date Analyzed:
Dilution Factor:
Blank File:
Analyst:
07/01/97
07/17/97
08/13/97
n/a
U972695
HLM
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPPAHJ10
UPJ8127
U972690
n/a
n/a
n/a
Analytes !
Naphdialene
2-MediylnaphdiaJene
Acenaphdiene
2-Chloronaphthalene
Acenaphdiylene
Ruorene
Phenanthrene
Andiracene
Fluoranthene
Pyrene
3enzo(a)andiracene
Chrysene
3erylene
Benzo(b)tluoranthene
BenzodOfluorandiene
Benzo(a)pyrene
3enzo(e)pyrene
3enzo(g,h.i)perylene
Indeno( l,2.3-cd)pyrene
Dibenz( a,h )andoracene
•:-*x&fr& /H^*fc
651
70.0
4.9
0.16
2.0
9.5
56.0
3.6
37.2
21.6
8.6
11.2
2.5
16.8
5.1
6.7
12.1
11.7
12.6
2.8
^;'f=aiPO-.^- -1::>Fte«0 i •-..:: FFF
5:24
6:34
8:52
2.84 7:33
8:29
10:04
12:28
12:36
15:32
16:08
19:21
19:27
25-28
23:25
23:35
- - 25:03 . .
24:46
34:51
32:34
32:49
Flags
SQB
B_
B
QB_
B_
B_
B_
B_
B_
B_
PRB
PRQ
PR,
PR_
B
B_
Page 1 of 2
PAHI.PSR vlOO. LARS 6 10 03
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 11:26 0:
-------
TLI Project: 42299B
Client Sample: M23-Outlet-FBl
PAHJ Analysis (a)
Analysis File: U972700
Internal Standards
dg-Naphthalene
dio-2-Methylnaphthalene
d7-2-Chloronaphthalene
ds-Acenaphthylene
dio-Phenanthrene
di2-Benzo(a)anthracene
dio-Fluoranthene
dn-Chrysene
di:-Perylene
di:-Benzo(b)fluoranthene
di2-Benzc(k)fluoranthene
di:-Benzo(a)pyrene
di2-Benzo(g,h,i)perylene
di:-Indeno(l,2,3-cd)pyrene
di4-Dibenz(a.h)anthracene
Surrogate Standards {Type A}
dio-Fluorene
du-Terphenyl
Alternate Standard {Type A)
dio- Anthracene
Recovery Standards
dio-Acenaphthene
dio-Pyrene
di2-Benzo(e)pyrene
Anst; (off ^.
39.2
33.3
29.3
67.6
110
264
110
125
182
299
97.9
234
307
479
600
AmL (tig)
84.2
131
AmL (119)
22.6
% Recovery
39.2
33.3
29.3
67.6
110
264
110
125
91.2
150
48.9
117
154
240
300
% Recovery
84.2
131
: % Recovery
22.6
QC Limits
40%- 130%
40%- 130%
40%- 130%
40%- 130%
40%- 130%
40%- 130%
40%- 130%
40%-130%
40%- 130%
40%- 130%
40%- 130%
40%- 130%
40%- 130%
40%- 130%
40%- 130%
QC Limits
40%- 130%
40%- 130%
QC Limits
40%- 130%
'.. '*& \-\~tm :
5:21
6:30
3.34 7:31
8:26
12:24
19:17
15:29
19:22
25:21
23:19
23:27
24:55
34:34
32:23
32:34
RT
10:00
16.32
• -- RX---
12:33
RT
8:47
16:05
24:37
'Flags
V
V
VQ_
I
Flags
—
flags
v
Ffags
Data Reviewer
08/25/97
Page 2 of 2
PAHJ.PSR vioo. LARS « 10 03
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 11:26 08/25/97
-------
Initial
Data Review By:
. .Date.
Calculated Noise Area: n/a
Page No. 1
08/25/97
Compound/
M_2.... QC.Log Omi t Why
Listing of U972700B.dbf
Matched OC Peaks / Ratio / Ret. Time
.RT. OK Ratio Total.Area... Area.Peak. 1.. Area.Peak. 2. . Rel.RT Confound.Name. . ID.. Flags.
Naph
123
128
d8-Naph
136
136
2 -Me -Naph
142
N
142
dlO-2-Me-Naph
152
N
DC NL 0:00
5:03
5:09
5:24
5:40
6:15
6:44
6:52
7:09
7:17
7:20
DC WH 7:35
10 Peaks
DC NL 0:00
5:21
1 Peak
DC NL 0:00
6:12
6:17
6:29
6:34
6:46
7:20
7:42
7 Peaks
DC NL 0:00
DC NL 0: 00
6:30
6:41
3:29
8:44
8:52
10:29
10:57
11:17
11:22
11:25
11:31
3,580.78
212,470.00
16,611.50
270,706.00
12,948.90
4,034.15
1,905.38
7,968.22
2,164.66
20,793.10
16,833 .10
3,882.39
566,435.01
67.78
35,444.50
35,444.60
— Above : Naph /
141.57
267.49
55.70
110.39
15,897.30
8,538.06
296.03
634.63
25,799.60
25.20
1,281 .33
18,176.00
109.75
1,237.91
2,123.25
1,920.87
2,492.16
1.399.80
297.10
8,239 .68
4.284.79
3.775.38
212,470.00
16,611.50
270,706.00
12, 948.90
4,034.15
1,905.38
7,968.22
2,164.66
20,793.10
16,833.10
35,444.60
267.49
55.70
110.39
15, 897.30
8,538.06
296.03
634.63
18,176.00
109.75
1,237.91
2,123.25
1,920.87
2,492.16
1,399.80
297.10
8,239.68
4,284.79
3,775.38
0.628-1.372
0.000
0. 944
0.963
1.009 Naph
1.059
1.168
1.259
1.283
1.336
1.361
1.371
1.417
0.071-1.372
0.000
1 . 000 d8-Naph
0. 692-1. 308
0. 000
0.954
0. 967
0.997
1.010 2-Me-Naph
1 . 041
1. 128
1.135
0.002-1. 949
0.000
0.000
1.000 dlO-2-Me-Naph
0.792
1 . 006 Acenaph
1.036
1.051
1.243
1.298
1.338
1.348
1.354
1. 366
AN SQ
ISO
AN
I SI
AN
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: J1:26 08/25/97
08
-------
Page No. 2
08/25/97
Compound/
M_Z. . . . QC.Log Omit Why
Listing of O972700B.dbf
Matched GC Peaks / Ratio / Ret. Time
.RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Confound.Name.. ID.. Flags.
152
Acenaphthen
154 DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
19
11:
11:
11:
11
12:
12:
12:
13:
:34
:47
:52
: 55
:22
:29
:34
:15
Peaks
SK«.
7
4
2
5
955
651
,380
,685
,752
,877
511
650
.10
.72
.89
.33
.18
.65
.40
.02
955
651
7,380
4,635
2,752
5,377
511
650
67,521.53
NL
WH
WH
WH
WH
WH
WH
WH
WH
WH
WH
WH
WH
WH
WH
WH
WH
WH
WH
WH
WH
WH
WH
0;
3:
8:
3:
3:
9:
9:
9:
9:
9:
9:
9:
9:
9:
9:
10:
10:
10:
10:
10:
10:
11:
11:
11:
11:
11:
11:
11:
11:
12:
12:
12:
12:
12:
12:
12:
12:
12:
13:
: 00
09
:12
:52
56
01
05
14
21
23
31
41
44
47
55
14
13
29
34
51
57
22
25
30
34
47
52
55
.53
00
:02
04
12
:14
:22
:31
:33
36
:00
1
3
1
2
1
1
2
491,
300.
18.
,594.
81.
417.
,873.
168.
231.
136.
159.
476.
221.
152.
,104.
337.
62.
379.
32,
673.
434.
,696,
748,
,487.
881.
798,
,456.
23.
56,
63.
43.
49.
470
335,
,202.
152.
108.
37.
227,
.01
97
.92
.70
,85
,93
,56
.35
.19
89
.30
97
42
.24
22
.59
51
.30
.09
,43
,60
,67
,23
.68
66
.94
.53
,58
.42
.61
.48
47
66
,34
.57
,55
.02
,39
,55
300,
18,
1,594,
31 .
417,
3 ,373 ,
168.
231.
136.
159.
476.
221.
152.
1,104.
337
62.
.10
.72
.39
.38
.18
.65
.40
.02
.97
.92
.70
,85
, 93
.56
.35
,19
39
.30
97
42
.24
22
59
,61
1
1
1
1
1
1
1
1
.372
.397
.407
.413
.466
.430
.490
.571
0.764-1.236
0.
0
0
1
1.
1
1
1
1
1.
1 .
1
1 .
1.
1
1.
1 .
1.
1.
1
1 .
1,
1.
1.
1 .
1.
1 .
1 .
1.
1.
1.
1.
1.
1.
1.
1 .
1,
1.
1.
.000
.966
. 972
.051 Acenaphthen
.059
. 069
.077
.095
.109
.1-3
. 1-S
.148
, 154
, 160
1'6
.213
.ZZl
243
.253
237
298
,343
354
,364
372
,397
. 40~
,413
.419
423
,427
,431
,447
.451
466
.484
.488
.494
.542
AN
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 11:2608/25/97
109
-------
Page No 3
08/25/97
Compound/
M_Z... QC.Log Omit Why
Listing of U972700B.dbf
Matched GC Peaks / Ratio / Ret. Time
.RT. OK Ratio Total. Area. .. Area. Peak. 1.. Area.Peak.2.. Rel. RT Confound. Name. . ID.. Flags.
154
d8-Acenaph
160
ISO
2-Cl-Naph
162-164
M
162-164
dlO-Acenaphthen
164
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
WH
WH
WH
16
NL
WH
WH
WH
WH
WH
WH
WH
WH
WH
WH
WH
WH
WH
WH
WH
WH
WH
WH
WH
7
NL
WL
WL
2
NL
WH
WH
13:03
13:15
13:44
Peaks
0:00
8:21
8:26
3:47
9:09
9:22
9:45
10:01
10: 39
10:54
12-00
12:09
12:24
12:33
12:4S
12- 50
12:52
13- 00
13.08
13:14
13:17
13.20
13:26
13:33
13:34
13: 39
13:42
Peaks
0:00
5:04
5:23
7: 33
7:49
Peaks
0:00
8:47
12:43
13:05
440.01
351.49
327.32
9,338.71
147.96
459.07 459.07
52,175.50 52,175.50
31,665.90 31,665.60
64.37 64.87
668.77 668.77
106.19 106.19
67.05 67.05
148.78
168.42
179 .19
78.09
11,855.30
2,073.41
92.46
151.39
90.36
581.07
86.48
144.05
313.46
111.77
1,473.37
47.51
23.38
55.62
178.30
85,207.05
2.62-3 .54
RO 1.00 25.32
RO 0.49 15.23
RO 1.01 78.00
2.84 36.50 27.00 9
2.85 27.70 20.50 7
64.20
Above: 2-Cl-Naph / dlO-Acenaphthen Follows -
37.81
50,064.00 50,064.00
75.07
166.42
1.547
1.571
1.628
0.002-1.236
0.000
0.990
1 . 000 d8-Acenaph IS2
1.042
1.085
1.111
1.156
1.188
1.263
1.292
1.423
1.441
1.470
1. 438
1.514
1.522
1. 526
1.542
1.557
1. 569
1.575
1. 581
1. 593
1.607
1.609
1.619
1.625
0.735-1.265
0.000
0. 674
0.716
.50 1.004 2-Cl-Naph AN
.20 1.040
0.735-1.265
0.000
1.169 dlO-Acenaphthen RSI
1.692
1.741
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 11:26 08/25/97
110
-------
Page No.
08/25/97
Listing of U972700B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
164
Fluorene
166
166
DC WH 13
:55
1 Peak
DC NL 0:
8:
3:
9:
9:
Q .
10:
10:
10:
10:
10:
10:
10:
11:
11:
11:
11:
12:
12.
DC WH 12-
DC WH 12:
DC WH 13-
DC WH 13:
DC WH 13:
DC WH 13:
- rt±JW«S .
:00
:45
:56
ill
46
:58
04
:14
:22
28
:37
48
:57
.04
22
30
52
15
21
44
57
02
15
30
40
18 Peaks
37
.29
50,064.00
dlO— Acenaphthen /
340
1,081
376.
295
839.
248
4,117.
443.
659
1.363.
180
633 .
1,224.
554
24,274,
309.
14,411.
901.
1,249.
1.037.
194.
452.
335.
608.
489.
53,165.
.35
.78
.81
.70
.04
.38
.42
.74
.40
.35
.35
.34
.13
.41
,50
.92
10
.00
.97
.21
,15
34
,33
.05
.35
.34
d7-2-Cl-Naph
169-171
DC NL 0 :
2.62
00 RO 1
-3.54
.19 31.
.46
1.
351
1,081
376
295
839
248
4,117.
443
659
1,363
180
633
1,224.
554
24,274.
309
14,411.
901
1,249
.78
.81
.70
.04
.88
.42
.74
.40
.35
.35
.34
.13
.41
.50
.92
. 10
.00
.97
0.678-
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
1 .
1.
1.
1.
1 .
1.000
000
706
720
741
788
304
312 Fluorene
325
336
344
356
371
383
392
917
927
957
938
996
027
044
051
069
089
102
ti / •" A ~*— i ~JNelpn c O.L XOWS — "^
0.735-
0.
1.265
000
169-171
dlO-Fluorene
176
K
176
Phenan
173
7:31 3.34
1 Peak
16,623.76
16,623.76
12,792.10
IS3 Q
Above: d7-2-Cl-Naph / dlO-Fluorene Follows
DC NL
0:00
10:00
1 Peak
42.37
30,546.50
30,546.50
30,546.50
Above: dlO-Fluorene / Phenan Follows
DC NL
0:00
9:03
255.97
896.21
896.21
0.839-1.564
0.000
0.306 dlO-Fluorene
0.195-1.305
0.000
0.730
SUR1
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 11 .-2608/25/97
111
-------
Page No.
08/25/97
Listing of U972700B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak. 1.. Area.Peak.2.
Rel.RT Compound.Name.. ID.. Flags.
178
dlO-Phenan
138
133
Fluoran
202
M
202
dlO-Fluoran
212
9:11
9:45
10:15
10t26
10:31
10:40
10:57
11:03
11:07
11:17
11:22
11:27
11:30
11:41
11:52
12:06
12:28
12:36
12:42
12: 56
13:02
13 . 39
13:42
13: 54
25 Peaks
DC NL 0:00
12:24
12:33
2 Peaks
DC NL 0:00
14. 06
14:29
15:23
15:32
15:39
16:00
16:03
17:32
17:37
13:19
10 Peaks
DC NL 0:00
15:29
16:05
1,577.78
367.90
1,084.74
411.59
319.57
612.53
3,479.75
341.70
2,808.19
3,085.20
5,732.32
4,188.09
2,155.85
1,959.80
4,097.21
527.70
27,096.40
1,491.76
1,483.49
565.90
1.177.09
190.99
2,476.07
505.37
68,733 .70
47. 05
36,514.30
6,511.09
43,025.39
366.25
406.17
1,281.30
1,297.32
22,162.80
4,142.03
312.32
13,200.00
254.43
1,729.02
2,625.22
47,411.11
140.24
41,178.60
47,591.40
1,577.78
367.90
1,084.74
411.59
319.57
612.53
3,479.75
341.70
2,808.19
3,085.20
5,732.32
4,188.09
2,155.35
1,959.80
4,097.21
527.70
27,096.40
1,491 76
1,483 .49
565.90
1, 177.09
190.99
2,476.07
605. 37
36, 514.30
6, 511.09
406.17
1,281.30
1,297.32
22, 162.80
4, 142.03
312.32
13,200.00
254.43
1, 729.02
2,625.22
41, 178.60
47.591.40
0.741
0.786
0.827
0.341
0.348
0.360
0.383
0.891
0.897
0.910
0.917
0.923
0.927
0.942
0.957
0.976
1.005 Phenan
1.016 Anth
1.024
1. 043
1. 051
1.101
1. 105
1.121
0. 195-1.305
0. 000
1.000 dlO-Phenan
1.012 dlO-Anth
0.354-1.646
0.000
0.911
0. 935
0.994
1 . 003 Fluoran
1.011
1.033
1 . 042 Pyrene
1.132
1.138
1.133
0.290-1.646
0.000
1.000 dlO-Fluoran
1.039 dlO-Pyrene
AN
AN
IS4
ALTS
AN
AN
IS5
RS2
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 11:26 08/25/97
-------
Page No.
08/25/97
Listing of U972700B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound. Name. . ID.. Flags.
212
B-a-Anth
228 D 7C
223
d!2-B-a-Anth
240 DC
240
d!4-Terphenyl
244 DC
DC
244
B-b-Fluoran
252
M
MTN
M
M
MKTN
252
d!2 -B-b-Fluoran
264 DC
M
16.
19:
19:
32
:17
22
5 Peaks
3,
1,
1,
735.
890.
148.
33
32
71
95,544.86
NL 0:
15:
16:
16:
16:
16:
17:
13:
13:
19:
19:
19:
:00
30
11
32
35
59
20
19
43
21
24
27
11 Peaks
NL 0:
16:
17:
19:
19-
00
22
52
17
22
4 Peaks
NL 0:
IS:
WH 13:
00
32
05
1 Peak
1,
13,
3,
2
2,
24,
4,
26,
15,
45,
23,
104.
663.
536.
61.
138.
119.
101.
336.
253.
097.
552.
264.
625.
65.
082.
169.
111.
200.
564.
29.
741.
785.
23,741.
96
61
63
61
69
71
76
30
05
28
18
S3
45
12
32
92
50
30
54
1
57
70
02
70
/
3,735.
1,890.
1,148.
.33
.82
.71
1.
1.
1.
068
245
251
663.
1,536.
61.
138.
119.
101.
13,336.
253.
3.097.
2,552.
2,264.
4,082.
169.
26,111.
15,200.
.61
S3
.61
69
71
.76
30
05
28
18
63
.82
92
50
30
0.481-
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
1.
1.
0.481-
0.
0.
0.
1.
1.
1.519
000
304
339
357
360
381
399
950
971
003 B-a-Anth AN PR
006
009 Chrysene AN PRQ
1.519
000
357
927
000 d!2-B-a-Anth ISS
004 d!2-Chrysene islO
23,741.
20:
23:
23:
24:
25:
25:
:45
25
:35
:46
:03
:23
6 Peaks
1,
7,
3,
1,
16,
052.
820.
993.
940.
730.
536.
071.
04
00
00
00
00
00
04
1,052.
7,820.
993.
3,940,
1,730.
536.
.70
,04
,00
.00
.00
,00
,00
0. 354-
. 0.
1.
1.
0.606-
0.
0.
0.
0.
0.
1.
1.129
000
063 d!4-Terphenyl SUR2
153
1. 394
319
924 B-b-Fluoran AN PR
930 B-k-Fluoran AN PR
977 B-e-Pyrene AN
988 B-a-Pyrene AN
005 Perylene AN
0.606-1.394
NL 0:
23:
:00
:19
75,
30.
000.
05
00
75,000.
.00
0.
0.
000
920 d!2-B-b-Fluoran isll
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 11:26 08/25/97
11
-------
Page No 7
08/25/97
Compound/
M_Z ... QC-Log Omit Why
Listing of U972700B.dbf
Matched OC Peaks / Ratio / Ret. Time
.RT.
OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
M
264
I-123-cd-Py
276
M
276
DiB-ah-Anth
278
M
273
d!2-I-123-cd-Py
288
5
23:
24:
24:
25:
:27
:37
:55
:21
Peaks
29,900.
21,168.
35,596.
36,526.
00 29,900.00
10 21,168.10
30 35,596.80
90 36,526.90
0.
0.
0.
1.
925 d!2-B-k-Fluoran
971 d!2-B-e-Pyrene
983 d!2-B-a-Pyrene
000 d!2-Perylene
isl2
RS3
is!3
IS7
198,191.30
DC
DC
DC
DC
NL
WL
WL
WL
3
0
22:
22:
22
31
32 :
34
:00
:12
:28
: 53
46
:34
: 51
Peaks
100.
117.
102.
81.
186.
1,760.
1,488.
92
93
05
03
27 186.27
00 1,760.00
98 1,488.98
0.711-
0.
0.
0.
0.
0.
0.
1.
1.289
000
642
650
662
919
942 I-123-cd-Py
008 B-ghi-Pery
AN
AN
3 ,435.25
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
WL
WL
WL
WL
:VL
WL
WL
WL
WL
WL
WL
WL
WL
WL
WL
WL
WL
WL
WL
WL
2
NL
WL
WL
0:
20:
20
21:
21
21:
22:
22
22:
23 :
23
23
24
24
24
25
26
26
27.
29
29
31;
32:
:00
:23
:43
. T_ 1
32
37
:04
41
:48
:07
:20
:43
:02
:11
:39
•24
:10
:52
:07
•02
: 35
:46
:49
Peaks
0:
20:
21:
:00
:53
30
65.
1,655.
63
80
26.
75.
182.
38.
98.
123.
104.
85.
77.
16.
121.
97.
160.
197.
38.
78.
20.
235.
371.
606.
- Above: DiB-ah-Anth
40.
977.
853.
59
17
65
09
90
38
94
02
73
43
29
48
03
05
38
54
98
03
99
30
32
05 235.05
00 371.00
05
/ d!2-I-123-cd-Py Follows
75
91
97
0. 939-
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
0.711-
0.
0.
0.
1 061
000
623
636
650
661
664
678
697
700
710
716
723
738
743 *~
757
•780
303
325
333
392
908
975
008 DiB-ah-Anth
1.289
000
604
622
AN
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 11:26 08/25/97
114
-------
Page No.
08/25/97
Listing of U972700B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_2.... QC.Log Omi t Why
.RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
233
d!4-DiB-ah-Anth
292
292
DC
DC
DC
DC
WL 22:05
WL 22:30
23:48
31:48
32:23
33:59
34:34
5 Peaks
— - — Al
NL 0:00
WL 28:44
32:02
32:34
2 Peaks
232.78
531.25
268.72
458.05
24,000.00
206.32
19,676.80
44,609.39
268.72
458.05
24,000.00
206.32
19,676.80
Above: d!2-I-123-cd-Py / dl4-DiB-ah-Anth Follows
19.60
137.55
213.66 218.66
17,197.00 17,197.00
17,415.66
0.639
0.651
0.333
0.920
0.937 d!2-I-123-cd-Py is!4 I
0.983
1.000 dl2-B-ghi-Pery IS8
.939-1.306
0.000
0.382
0.984
1.000 d!4-DiB-ah-Anth IS9
Column Description "Why" Code Description QC Log Desc.
M_Z -Nominal Ion Mass(es)
.RT. -Retention Time (mm:ss)
Rat.1 -Ratio of M/M+2 Ions
OK -RG=Ratio Outside Limits
Rel.RT-Relative Retention Time
End of Report
WL-Below Retention Time Window
WH-Above Retention Time Window
SN-Selow Signal to Noise Level
-------
Filo:USV170O 91-294 Acq, 13-AUO-1997 07:41,26 (Jt dX*
128.0626 B3UB(256,30,-3.0) PXD(3,1,3,0.50*,7161564.
TRIANOLS LABS TfJCt: H23-OUTLST-RUH-RB1 TLH42299B
loos
80.
60.
40.
20.
0.
A2.7139
A A1.29B8
, VA _ . A
5:00 5,12 5,24 5,36 5,48 6:00 6,13 6,34
• voltage am 70S aoim»ti79O39i
0,0.00*,P,P) SxptPASS
A3. 08*8
XN yv\ ^
-1.1*9
.8.6*8
.6.4*8
.4.3*8
.2.1*8
6:36 6:48 7:00 7:12 7,24 7:36 7,48 ' 8,00 Tia»
Fll»,U973700 #1-294 Acy, 13-AUO-1997 07,41,26 OC BI+ Voltagm SIR 703 Hoii»:33B90
136.1128 BSUB(356,30,-3.0) PKD(3,1,2,0.50*,135560.0,0.00*,F,P) SxptPABS
TRIANGLE LABS TfJCts M33-OUTLBT-RUN-RB1 TLI»43399B
loot
80.
60.
40.
201
01
A3.S4B8
} \
5:00 5:12 5:24 5,36 5,48 6:00 6:12 6:24
Pila:U972700 #1-294 Acg: 13-AUG-1997 07:41:26 OC EH-
142.0782 BSUB(256,30,-3.0) PXD(3, 1, 2, 0.50*,283136. 0
TRIANGLE LABS Text: M23-OUTLET-RUN-RB1 TLI#42299B
100*
80.
60.
40.
20.
0.
2.6*8
'.2.1*8
'.1.6E8
'.1.1E8
'.S.3S7
' O. OEO
6:36 6:48 7:00 7:12 7:24 7:36 7:48 8:00 Time
Voltag* SIR 70S Nola»:70784
,0.00*,F,F) BxptPABS
A1.59E8
^
5:00 5:12 5:24 5:36 5:48 6,00 6:12 6:24
PilasU972700 #1-294 Acyt 13-AUQ-1997 07:41:26 OC SI-f
A8.54B7
I
l\l\ • ^
8.9E7
'.7.1E7
'.5.4E7
L3.6E7
"-1.8E7
' n . osn
6:36 6:48 7:00 7:12 7:24 7:36 7:48 8:00 Tdjae
Volt ago SIR 70S Boia», 12599
152.1410 BSUB(256,30,-3.0) PKD(3, 1, 2, 0.50*,50396. 0, 0. 00*,P,P) SxptPABS
TRIANGLE LABS Text: H2 3 -OUTLET -RUN- RBI TLI#42299B
100*
80.
601
401
201
01
Al.
J
5:00 5:12 5:24 5,36 5,48 6:00 6:12 6i24
F±1»,U972700 #1-294 Acgs 13-AUO-1997 07:41:36 OC BI+
154.9920 Bxp:PAB5
TRIASGLS LABS Tuxt: M23-OUTLET-RUN-RB1 TLX#42299B
ion
'.
80.
601
40.
201
•
01.
6,12
5:05 5,16 5'n>5 6*35 _ ... f *»57 n 'ft. A **?'
A k v r^VAM /s S'49T^J\ r\ A /~^\
/\|W 1/VVV/ \K \JV
V V
V
5*00 5*12 5*24 5,36 5»4« 6,00 6,12 6,24
I2E8
6:36 6:48 7,00 7:12 7,24 7,36 7,48 8,
.9.4E7
'.7.5E7
.5.7E7
.3.8E7
.1 . 9E7
.0. OEO
00 Tlmo
Voltage SIR 70S
r 6tf° 7,26 /wA J^y\AV\_
\N^\ 7AI^UA/A / \J
\ /\_ ^ * ^ /V / \ 1
V/N
V
6,36 6,48 7,00 7,12 7,24 7,36 7t48 8,
.5. 7E6
.4.6*6
.3.4*6
.2.3*6
.1.1*6
0 . 0*0
JO Time
116
-------
8:00 9:00 10.00 11(00 12:00 13:00
Pll»sU972700 #1-535 Aaqs13-AVO-1997 07:41:26 OC JET* Voltage SIX 703 BOia»:739B2
160.1128 P:2 BSUB<256,30,-3.0) PKD{3,3,1, 0.01X,295928.0, 0.00*,F,P} Sxp:PAB5
TRIANOLE LABS TfXt: K23-OUTLST-RnS-RBl TLX*42299B
Pila:U972700 #1-535 Acq: 13-AUQ-1997 07:41:26 QC SIf Voltagt SIS 70S Soia»:245503
154.0782 P:2 BSUB (256, 30, -3.0) PXD(3,3,1,0.01*,982012.0,0.00*,P,P) Exp:PAB5
TRIANGLE LABS Text: M23-aUTLET-RON-RBl TLI*42299B
.±»tUS727OQ 91-535 Acqt 13-AUB-1997 O7i41i26 OC XI* Voltagf SIR 70S NOimo:64O913
152.0626 Pi2 BSUB(256f30t-3.0) PXD(3,3,l,0.01\,2563652.0,O.OO*fP,P} BxpiPABS
TRIANOLE LABS T«Xt.- M23-OUTLBT-RUB-RB1 rLX*42299B
IOOH A8.24S7
14 00
ooa
80.
60.
40.
20.
0
8i
AS.
!2E8
A3.17E8
A1.19E8
1 L
OO' ' ' ' 9:00' ' ' 10:00 ' ' 'llioO ' ' ' 'l2:00 ' ' ' 'l3sOO ' 14
.2.1S8
_1.7E8
-1.3E8
.8.6E7
-4.3E7
O.OEO
00 Tin
IOCS
so:
eo:
401
20:
o:
A2.70E7
A3.87E7
A2.20S7
1.5E7
.1.2E7
.9.0E6
.6.0E6
.3.0E6
8:00 9:00 10:00 11:00 12:00 13:00
P11»:U972700 #1-535 Acq: 13-AUO-1997 07:41:26 OC SI* Voltage SIR 70S NOia»:18904
164.1410 P:2 BSUB(256,30,-3.0) PKD(3,3,1,0.01\,75616. 0,0.00*,P,P) ExpsPABS
TRIASOLB LABS Text : M23 - OUTLET-RUH-RBI TLI#42299B
100% AS. Q128
so:
601
401
201
S.OEO
14 00 Tiao
2.3E8
.1.8E8
.1. 4ES
.9.2E7
.4.6B7
8:00 9:00 10:00 11:00 12:00
P11«:U972700 #1-535 Acq: 13-AUQ-1997 07:41:26 OC BI+ Voltage SIR 70S
168.9888 P:2 SxplPAHS
TRIANOLE LABS TfXt: M23-OUTLET-SUN-RBI TLI#42299B
13:00
O.OEO
14 00 Time
10<*
9:28
8>00
117
-------
File:OS72700 91-294 Acq,13-WO-lSS7 07,41,3S X g* Voltage SIS 70S Boi*et6690
162.0336 BSVB(256,30,-3.0) PXD(3,2,1,1.00*,26760.0,0.00*,P,F) SxptPASS
TRIANGLE LABS Text, M23-OUTLST-KOJi-RBl TLIJ42299B
100k A3.93S5
5»00 5,12 ^,24 5,36 5,48 6,00 6,'l2 6i24 6,36 6,48 7,00 7,12 7,24
Flle,U972700 #1-294 Aaq,13-AOO-1997 07,41,26 OC BH- Voltage SIR 70S Koite:671B
164.0207 BSVB(256,30,-3.0) PKD(3,2, 1, 1.00*,26872.0, 0.00*,F,F) SxpsPASS
TRIANGLE LABS Text: K23-OVTLET-RU1I-RB1 TLI#42299B
100* A5.S6SS
A3.87E5
A2.63E5
0.0X0
7,36 7,48 8,00 Tim*
5.-00 5:12 5:24 5:36 5,48 6,00 6,12 6,24 6,36 6:48 7,00 7:12 7:24
Fila:U972700 #1-294 Acy.-13-AUQ-1997 07:41:26 OC EH- Voltage SIS 70S Soief.8534
169.0676 BSVB(256,30,-3.0) PKD(3,2, 1, 1.00*,34136.0,0. 00*,F,F) E3Cp:PAS5
TRIANGLE LABS TfXt: U23-OOTLST-Rmi-RBl TLZ#42299B
100* A1.28E8
80.
60.
401
20.
O.OEO
7:36 7,48 8:00 Tim*
5. 7E7
.4.6E7
.3.4E7
^2.3S7
.1.1E7
O.OEO
5:00 5:12 5:24 5:36 5:48 6:00 6,12 6:24 6,36 6:48 7:00 7:12 7:24 7:36 7:48 8:00 Tim*
Pile:U972700 #1-294 Acq:13-AUO-1997 07:41,26 OC BJ+ Voltage SIR 70S Kbia»:7195
171.0648 BSUB(256,30,-3.0) PKD(3,2, 1, 1. 00*, 28780. 0, 0. 00*,F,F) Sxp:PAS5
TRIANGLE LABS Text: K23-OVTLET-Rim-RBl TLI842299B
100* A3.83E7
BO:
60.
40i
20:
0.
1. 7E7
.1.4S7
.1.OE7
.6.9E6
.3.4E6
5:00 5:12 5:24 5:36 5,48 6,00 6,12 6,24 6:36 6,48 7:00
Fil»:O972700 #1-294 Acq,13-AUO-1997 07:41,26 OC EH- Voltage SIR 70S
154.9920 ExpsPABS
TRIANQLE LABS Text: M23-OUTLET-RUN-RB1 TLI#42299B
100JE
.O.OEO
7,12 7,24 7:36 7,48 8,00 Time
so:
eo:
40.
20:
0.
5*05 5, is
5,25
6,12
6,40
,.45
5. 7S6
'.4.6E6
.3.4X6
.2.3X6
.1.1X6
-r
5:00 5,12 5,24 5,36 5,48 6,00 6,12 6,24 6,36 6,48 7,00 7,12
•7737
i i I i i i i i I i i
7,36 7,48
.0.0*0
8,00 Time
118
-------
File
166.
TRIA
ion
801
60.
to:
20.
0
8:
Pile
176.
TRIA
1003
80.
60.
40.
20.
0
8:
Pile
178.
TRIA.
1003
so:
601
401
201
01
8:
Pile
188.
TRIA
ion
801
601
401
201
0
8:
Pile
168.
TRIA
1005
ao:
601
401
201
0
8:
t 0972700 91-535 Aatft 13-AUO-1997 07:41126 OC Jtl> Voj
0782 P:2 BSVB(256,30, -3.0) PXD(5, 1,1,0.50%, 680708.1
NOLX LABS Text: M23 -OVTLXT-RnN-RBl TLI942299B
A2.
A4.12X7
A A3..36X7*1.22*7 I
* - r n r/\ * M — -"rA^I
Ltage SIR 70S soime:17Ol77
},0.00*,P,F) SxptPAMS
3X8
A1.44X8
I
* * L -*\ A — «- - _ PL. _„ rt
00 WOO 10:00 ' 11:00 12»00 13:00 14
:U972700 #1-535 Acq:13-AUO-1997 07:41:26 *,. n A. l/\h
MNm>i^
V
00 Woo 10:00 11:00
W' yW-!TVirTr--v^u>yfT«TyW^^
-
12:00 13:00 14
.9.2X7
.6.1X7
.3.1X7
0.0X0
00 Time
110
-------
Flle:U972700 01-703 Acq: 13-AUO-1997 07:41:26 OC XI* Voltage SIX 703 Sol fei 433125
202.0782 F:3 BSUB (256, 30, -3.0) PKD(5, 3, 1, 0. 101, 1732500.0, 0.001,F,P) XXpiPASS
TRIANGLE LABS Text: M2 3 -OUTLET-RUN- RBI TLI*42299B
1003
80.
60.
40.
20.
14
A2.22X8
11.34S3
\\ i
'
^ A1.28X7 jJ\J^ J]^ ^^^ A1..73X7 J^j3*7 _
:00 ""* 15:00 16:00 17:00 ' ISiOO ' ' 'lf\00 ' ' 20
3.8X7
.7.0X7
.5.3X7
.3.5X7
.1.8X7
00 Time
File:U972700 01-703 Acq: 13- AUG- 1997 07:41:26 OC XH- Voltage SIX 703 So±*ei70121
212.1410 Fs3 BSUB(256,30,-3-.0) PKD(5, 3,1, 0.101, 280484.0, 0.00*,F,F) XxptPABS
TRIANGLE LABS Text: M23-OUTLET-RUK-RB1 TLI042299B
iota
80.
60.
40.
20:
o:
,^ •.•,.» 14.76X8 -1.9X8
A4 . 12X8 \
/ / A3.74S7
/ V / I JV —
14:00 15:00 16\00 ' 17:00 ' ' ' 18:00 ' ' ' 'l9:00 "30
•
'•.1.6X8
-.1.2X8
-.7.8X7
'.3.9X7
'
• o.oxo
: 00 Time
File:U972700 01-703 Acq: 13- AUG- 1997 07:41:26 OC XI* Voltage SIR 703 Noiae:52481
228.0939 F:3 BSUB (256, 30, -3 . 0} PXD(5,3,1, 0. 101,209924. 0, 0. 001,F,F) Xxp:PAHS
TRIANGLE LABS Text: H23-OUTLET-Rmr-RBl TLI042299B
100*
aol
sol
40^
202,
•
o"4
14
Al. 8E8
/
A1.54E7 \ I A*
A6.64E6 A / /VV\
-A J\ 1 ^ily
-4.5X7
.3.6X7
'.2.7E7
.1.8E7
.8.9E6
a. DEO
.•00 15:00 15:00 17:00 ' 18:00 15:00 20:00 Tim«
Pil»:U972700 #1-703 Aoq:13-AUO-1997 07:41:26 OC EH- Voltage SIR 70S Soiae:32561
240.1692 F:3 BSUB (256,30, -3 . 0) PKD(5, 3, 1,0. 101, 130244. 0,0. 001,P,F) SxpiPASS
TRIANGLE LABS Text: M23 -OUTLET-RUK-RB1 TLX042299B
100*
so:
60:
40:
•
20:
o-
14
A2.61E8
\
'k ~-
\
A4.08E7 f V
Jl /
00 15:00 16:00 17:00 18:00 19:00 20
-6.1B7
.4.9X7
_3 . 7B7
2.5S7
.1.2E7
0.0X0
00 Time
Fila:U972700 01-703 Acqsl3-AUG-1997 07:41:26 OC SI+ Voltage SIR 70S Koise:14787
244.1974 F:3 BSUB (256,30, -3 .0) PKD(5,3,1, 0. 101,59148. 0, 0. OO1,P,F) ExptPABS
TRIANGLE LABS Text: M23-OUTLET-RUN-RB1 TLI042299B
100*
ao:
60:
40:
20:
0:
A2.37E8
I
14:00 15:00 16:00 17:00 ' 'lS»00 ' ' ' 'l9:00 ' ' ' 20.
.9.5X7
.7.6X7
.5.7X7
.3 . 8E7
.1.9X7
.0. 0X0
00 Time
Flle:U972700 01-703 Acq: 13 -AUG- 1997 07:41:26 OC XX* Voltage SIR 70S
242.9856 F:3 XxptPABS
TRIANGLE LABS Text: X2 3 -OUTLET -RUN- RBI TLI042299B
1003s
80:
60:
40:
20:
o-
14
14s47 15:16 15:48,- Qg 16:50 17:29 17:52 18:25 18:54 19:30
i^ Mju..iA rtjt.. >y-ii i i ifv*i»*nr.. i aiVfr»iu •>m>itn>i i *<. L »-- ^ ^. . -i.. .
^^^^^y^f^jV^^^ ^/Y'H^^^^^f^W ^**A P***^*»*«
'" *ll
V
.
°° ISiOO 16:00 17',00 ' ' '18:00 ' ' ' 'l9\00 ' ' ' ' 20
.3.9X7
.3.1X7
.2.3X7
.1.6X7
.7. 8XS
.0.0X0
00 Time
120
-------
Fll»tU972700 #1-1377 Acq: 13-AOa-1997 07:41:16 OC SI* Voltage 3IR 70S Soimut105597
353.0939 P:4 BSUB(356,30,-3.0) Piaj(7,5,3,0.30*,432388.0,0.00*,P,P) BJtptPABS
TRIASOLS LABS Text: K23-OOTLBT-gUB-RBl TLH43399B
A8.39X7
30 00 33:00 34:00 26:00 28:00 30:00 33:00
Plle:U973700 #1-1377 Acq:13-AUO-1997 07:41:36 OC SI+ Voltage SIR 70S
264.1693 P:4 BSUB(356,30, -3.0) PXD(7,5,3,0.30X,60108.0,0.00*,P,P) Bxp:PAB5
TRIANOLB LABS Text: K23-OUTLBT-SOV-RB1 TLI#42299B
100* A7.58E8
901
701
601
501
401
301
201
101
34:00
A3.56E8
20:00 22:00 24:00 26:00 28:00 30:00 32:00
P11»:U972700 #1-1377 Acq:13-AOO-1997 07:41:36 OC BI+ Voltage SIR 70S
268.9824 P:4 SxpiPASS
TRIANGLE LABS Text: H23-OVTLBT-RVB-RB1 TLI*42299B
34:00
30 00
23:00
34:00
36:00
38:00
30:00
33:00
34:00
8.7S6
-7.8B6
•.6.9E6
-6.1S6
•.5.3S6
-4.3B6
'.3.5S6
-2.6E6
-1. 7B6
'-.8.7BS
.O.OEO
36 00 Tiiao
8.0B7
•-7.2E7
16.4E7
-5.6E7
'.4.8E7
-.4.0E7
.3.2E7
-2.4E7
i.1.627
•.8.0E6
_T_LO.OBO
36 00 Tim*
0.020
36 00 Tim*
121
-------
\Pile:0972700 01-1377 Acg,13-AOO-1997 07,41,36 OC JP> Vblt«g» SIS. 70S Boise,504SO
276.0939 P:4 BSUB(256,30,-3.0) PKDflS, 13,11, 0.501, 201840.0,0.001,P,P) Xxp:PAH5
TRIANGLE LABS Text: tt23-OUTLST-ROS-RBl TLI042299B
100* A1.40Z7
801
601
401
"f^£$th~^^
2.0X5
0.0X0
20,00 22,00 24,00 26,00 28,00 30,00 32,00
Fil»,a972700 01-1377 Aaqt13-ADO-1997 07,41,26 OC BI+ Voltage SIR 70S Noime:20377
288.1692 F,4 BST1B(256,3O,-3.O) PXD(15,13,11,0.501,81508.0,0.001,F,F) SxptPABS
TRIANGLE LABS Text, M23-OUTLST-RUS-RB1 TLI042299B
10(9
801
601
401
201
A2.
A9.78E6
A A .^
310 33,10 34,35
36
9.2E6
17.3E6
15.SE6
13.7E6
11.8E6
O.OEO
36 00 Time
2.0S7
V^NH^v^^-^7
11.2X7
20 00
22,00
24,00
26QO
2800
30:00
32-»00
3400
.0.0X0
3S:00 Time
122
-------
File:U972700 #1-294 Acq:13-AUG-1997 07:41:26 GC EI+ Voltage SIR 70S
162.0236 Exp:PAH5
Sample Text: M23-OUTLET-RUN-RBl TLI#42299B File Text:TRIANGLE LABORATORIES ,
00^ A2.70E5
90 J
80 J
70J
60J
50J
40J
30J
20 J
10 J
OJ
INC
T
T
T
T
T—i—i—i—r
6:54 7:00 7:06 7:12 7:18 7:24 7:30 7:36 7:42
File:U972700 #1-294 Acq:13-AUG-1997 07:41:26 GC EI+ Voltage SIR 70S
164.0207 Exp:PAH5
Sample Text: M23-OUTLET-RUN-RBl TLI#42299B File Text:TRIANGLE LABORATORIES ,
100%
90J
80J
70J
60J
50J
40 J
30J
20J
10J
ol
7:'48
INC
6:54
7:00
7:'06
>" i '
7:18
7:'24
7:30
1 i '
7:36
' i -' •
7:42
1 I ' ' '
7:48
1.7E5
L1.5E5
L1.4E5
L1.2E5
L1.0E5
L8.5E4
_6.8E4
_5.1E4
_3.4E4
_1.7E4
.O.OEO
Time
2. 8E5
L.2.5E5
_2.2E5
-2.0E5
-1.7E5
-1.4E5
1.1E5
_8.4E4
_5.6E4
_2.8E4
O.OEO
Time
ro
CO
-------
File:U972700 #1-703 Acq:13-AUG-1997 07:41:26 GC EI+ Voltage SIR 70S
202.0782 F:3 Exp:PAH5
Sample Text: M23-OUTLET-RUN-RBl TLI#42299B File Text:TRIANGLE LABORATORIES , INC
lOOi A1.32E8
90 J
80J
70 J
60 J
50 J
40 J
30J
20 J
10J
OJ
15:42 15148 15:54 16:66 16:06 16:12 16:18 16:24 16:30 16:36 16142 ieUs
File:U972700 #1-703 Acq:13-AUG-1997 07:41:26 GC EI+ Voltage SIR 70S
212.1410 F:3 Exp:PAH5
Sample Text: M23-OUTLET-RUN-RBl TLI#42299B File Text:TRIANGLE LABORATORIES , INC
_5.1E7
L4.6E7
L4.1E7
_3.6E7
_3.1E7
_2.6E7
_2.0E7
_1.5E7
_1.0E7
_5.1E6
_O.OEO
16:54 Time
100%
90J
80 J
70J
60J
50J
40 J
30J
20^
10J
O:
]
16:05
(1
1
1
1
1 1
1 1 *'
/ \ ! 16:32
L5:42 15148 15!54 ieloO 16!o6 16112 16 1 18 16124 ielio 16-136 16142 ieUs ielf
1.9E8
_1.7E8
_1.6E8
_1.4E8
_1.2E8
_9.7E7
_7.8E7
L5.8E7
L3.9E7
L1.9E7
_O.OEO
>4 Time
ro
-------
File:U972700 #1-1377 Acq:13-AUG-1997 07:41:26 GC EI+ Voltage SIR 70S
252.0939 F:4 Exp:PAH5
Sample Text: M23-OUTLET-RUN-RBl TLI#42299B File Text:TRIANGLE LABORATORIES , INC
lOOi A7.82E7
90 J
80 J
70 J
60J
50J
40 J
30J
20J
10J
OJ
22:36 22:48 23:00 23:12 23:24 23:36 23:48 24:00 24:12 24
File:U972700 #1-1377 Acq:13-AUG-1997 07:41:26 GC EI+ Voltage SIR 70S
264.1692 F:4 Exp:PAH5
Sample Text: M23-OUTLET-RUN-RBI TLI#42299B File Text:TRIANGLE LABORATORIES
100% 23;19
90J
80 J
70J
60 J
501
40J
30J
20J
10!
02
:24 24:36
, INC
24:37
22:36 22:48
I—I—i—r
23:00
23:12 23:24 23:36
i—i—i—i—i—i—i—i—i—i—r
23:48 24:00
T—i—r~i—i—i—i—i—r-
24:12 24
I ' ' ' ' ' I ' '
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_9.4E6
L8.4E6
L7.5E6
L6.6E6
L5.6E6
U.7E6
L3.7E6
L2.8E6
L1.9E6
L9.4E5
O.OEO
Time
8.0E7
L7.2E7
L6.4E7
L5.6E7
L4.8E7
L4.OE7
L3.2E7
L2.4E7
L1.6E7
L8.0E6
LO.OEO
Time
ro
01
-------
File:U972700 #1-1377 Acq:13-AUG-1997 07:41:26 GC EI+ Voltage SIR 70S
252.0939 F:4 Exp:PAH5
Sample Text: M23-OUTLET-RUN-RBl TLI#42299B File Text:TRIANGLE LABORATORIES
>4E7
INC
25:00 26:00 27:00
File:U972700 #1-1377 Acq:13-AUG-1997 07:41:26 GC EI+ Voltage SIR 70S
264.1692 F:4 Exp:PAH5
Sample Text: M23-OUTLET-RUN-RBl TLI#42299B File Text:TRIANGLE LABORATORIES
lOOi 24:55 25:21
90 J
80J
70J
60J
50J
40J
30J
20J
10J
INC
24:37
4.5E6
4.1E6
3.6E6
3.2E6
2.7E6
2.3E6
1.8E6
1.4E6
9.1E5
.4.5E5
.O.OEO
Time
3.6E7
3.2E7
2.8E7
2.5E7
2.1E7
1.8E7
1.4E7
25:00
26:00
27:00
7.1E6
3.6E6
O.OEO
Time
-------
File:U972700 #1-1377 Acq:13-AUG-1997 07:41:26 GC EI+ Voltage SIR 70S
252.0939 F:4 Exp:PAH5
Sample Text: M23-OUTLET-RUN-RBl TLI#42299B File Text:TRIANGLE LABORATORIES , INC
100% A1.73E7
25:00 26100 27iOO
File:U972700 #1-1377 Acq:13-AUG-1997 07:41:26 GC EI+ Voltage SIR 70S
264.1692 F:4 Exp:PAH5
Sample Text: M23-OUTLET-RUN-RBl TLI#42299B File Text:TRIANGLE LABORATORIES , INC
100^A 25:21
90 J
28:00 Time
3.6E7
L3.2E7
L2.8E7
L2.5E7
L2.1E7
Ll.8E7
L1.4E7
-1.1E7
-7.1E6
_3.6E6
O.OEO
25:00
26:00
27:00
28:00 Time
ro
-------
File:U972700 #1-1377 Acq:13-AUG-1997 07:41:26 GC EI+ Voltage SIR 70S
252.0939 F:4 Exp:PAH5
Sample Text: M23-OUTLET-RUN-RB1 TLI#42299B File Text:TRIANGLE LABORATORIES , INC
lOOi 23;25
90 J
80J
70 J
60 J
50J
40 J
30J
20J
10J
OJ
24:46
26:21
23:00 24:00 25:00 26:00
File:U972700 #1-1377 Acq:13-AUG-1997 07:41:26 GC EI+ Voltage SIR 70S
264.1692 F:4 Exp:PAH5
San4)le Text: M23-OUTLET-RUN-RBI TLI#42299B File Text:TRIANGLE LABORATORIES , INC
100% 23;19
25:21
9.4E6
8.4E6
7.5E6
6.6E6
5.6E6
4.7E6
3.7E6
2.8E6
9E6
9.4E5
O.OEO
_1
23:00
24:00
25:00
26:00
Time
8.0E7
7.2E7
_6.4E7
_5.6E7
_4.8E7
_4.0E7
_3.2E7
L2.4E7
L1.6E7
L8.0E6
O.OEO
Time
ro
CO
-------
File:U972700 #1-1377 Acq:13-AUG-1997 07:41:26 GC EI+ Voltage SIR 70S
264.1692 F:4 Exp:PAH5
Sample Text: M23-OUTLET-RUN-RBI TLI#42299B File Text:TRIANGLE LABORATORIES
100% A7.50E8
95 J
90J
85 J
80J
75-i
70 J
65 J
60J
55J
50 J
45 J
40J
35J
30J
25J
20 2
INC
5J
22:48
23:00 23:12
23:24
23:36
23:48
24:00
24:12
' i r—
24:24
8.0E7
7.6E7
7.2E7
.6.8E7
.6.4E7
6.0E7
5.6E7
5.2E7
.4. 8E7
4.4E7
4.0E7
3.6E7
.3.2E7
.2.8E7
2.4E7
2.0E7
1.6E7
1.2E7
8. OE6
4.0E6
O.OEO
Time
CD
-------
5j
0
23:00
A2.99E8
File:U972700 #1-1377 Acq: 13-AUG-1997 07:41:26 GC EI+ Voltage SIR 70S -
264.1692 F:4 Exp:PAH5
Sample Text: M23 -OUTLET-RUN-RBl TLI#42299B File Text : TRIANGLE LABORATORIES
100%
95J
90J
85J
80 j
75 j
70 j
65 j
60J
55J
50J
45J
40J
35J
30J
251
20J
151
INC
23! 12
23 :24
23:36
23148
~~I 1 1 1 1 1 1 1 1 1 1-
24:00 24:12
_8.0E7
L7.6E7
_7.2E7
_6.8E7
_6.4E7
_6.0E7
_5.6E7
_5.2E7
_4.8E7
_4.4E7
_4.0E7
^.3 . 6E7
L3.2E7
L2.8E7
i2.4E7
L2.OE7
L1.6E7
L1.2E7
i.8.0E6
L4.0E6
.O.OEO
24:24 Time
CO
o
-------
File:U972700 #1-1377 Acq: 13-AUG-1997 07:41:26 GC EI+ Voltage SIR 70S
264.1692 F:4 Exp:PAH5
Sample Text: M23-OUTLET-RUN-RB1 TLI#42299B File Text :TRIANGLE LABORATORIES
lOOi
INC
99E8
23:00
24o
25:00
26:00
27 00
28:00
r8.0E7
^.1.6E1
_7.2E7
_6.8E7
_6.4E7
_6.0E7
-5.6E7
-5.2E7
L4.8E7
L4.4E7
L4.0E7
L3.6E7
L3.2E7
.2.8E7
L2.4E7
L2.OE7
L1.6E7
L1.2E7
L8.0E6
L4.0E6
LO.OEO
Time
-------
File:U972700 #1-1377 Acq:13-AUG-1997 07:41:26 GC EI+ Voltage SIR 70S
276.0939 F:4 Exp:PAH5
Sample Text: M23-OUTLET-RUN-RBI TLI#42299B File Text:TRIANGLE LABORATORIES
100^ A1.76E7
90J
, INC
31:00 32:00 33:00 34iOO
File:U972700 #1-1377 Acq:13-AUG-1997 07:41:26 GC EI+ Voltage SIR 70S
288.1692 F:4 Exp:PAH5
Sample Text: M23-OUTLET-RUN-RBI TLI#42299B File Text:TRIANGLE LABORATORIES
32;23
90J
80 j
70J
60 j
50 j
40 j
30J
20 j
10J
OJ
35:00
INC
34:34
31:00
1.4E7
_1.3E7
-1.1E7
-9.8E6
_8.4E6
-7.0E6
-5.6E6
_4.2E6
_2.8E6
_1.4E6
O.OEO
33:00
34:00
35:00 Time
CO
ru
-------
File:U972700 #1-1377 Acq:13-AUG-1997 07:41:26 GC EI+ Voltage SIR 70S
278.1096 F:4 Exp:PAH5
Sample Text: M23-OUTLET-RUN-RBl TLI#42299B File Text:TRIANGLE LABORATORIES , INC
31:00 32:00 33:00 34100
File:U972700 #1-1377 Acq:13-AUG-1997 07:41:26 GC EI+ Voltage SIR 70S
292.1974 F:4 Exp:PAH5
Sanqple Text: M23-OUTLET-RUN-RBl TLI#42299B File Text:TRIANGLE LABORATORIES , INC
1004 32;34
31:00
32:00
33:00
34:00
9.2E6
-8.3E6
_7.4E6
_6.5E6
-5.5E6
_4.6E6
_3.7E6
-2.8E6
_1.8E6
_9.2E5
_O.OEO
Time
CO
-------
File;U9727UO »l-13'/7 Acq:13-AUG-1997 07:41:26 GC EH- Voltage SIR 70S
276.0939 F:4 Exp:PAH5
Sample Text: M23-OUTLET-RUN-RBl TLI#42299B File Text:TRIANGLE LABORATORIES , INC
32;34
90 32::
80 J
70J
60 J
50 J
40 J
30J
20 J
10J
OJ
33:43
31:00 32:00 33:00
File:U972700 #1-1377 Acq:13-AUG-1997 07:41:26 GC EI+ Voltage SIR 70S
288.1692 F:4 Exp:PAH5
Sample Text: M23-OUTLET-RUN-RBl TLI#42299B File Text:TRIANGLE LABORATORIES , INC
100^ A2.40E8
90 J
80 J
70J
60J
50J
40 J
30J
20J
10 J
OJ
-4-*.
CO
3i!oo
32TOO
_1.2E6
L1.1E6
L9.7E5
E.8.5E5
L7.3E5
L6.1E5
U.9E5
L3.6E5
L2.4E5
Ll.2E5
O.OEO
Time
33:00
1.4E7
L1.3E7
L1.1E7
L9.8E6
L8.4E6
L7.0E6
L5.6E6
L4.2R6
L2.8E6
L1.4E6
LO.OEO
Time
-------
TLI Project:
Client Sample:
42299B
TLILCS
PAHJ Analysis (a)
Analysis File: U972701
Client Project:
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
Iron & Steel-Chicago
XAD Date Received:
TLI LCS Date Extracted:
Date Analyzed:
1.000
n/a
DB-5
Dilution Factor:
Blank File:
Analyst:
II
07/17/97
08/13/97
n/a
U972695
MM
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPPAHJ10
UPJ8127
U972690
n/a
n/a
n/a
Analytes
Naphthalene
2-Methylnaphthalene
Acenaphthene
2-Chloronaphthalene
Acenaphthylene
Fluorene
Phenantlirene
Anthracene
Ruorantliene
Pyrene
Benzo(a)anthracene
Chrysene
Perylene
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Benzol a)pyrene
Benzo(e)pyrene
Benzol g,h.i)perylene
Indeno( 1.2,3-cd)pyrene
Dibenzi a.h)anthracene
-.:^..*mMRS*.: v-
4730
130
88.1
97.2
93.3
73.6
107
94.6
95.0
80.3
81.7
91.8
80.6
75.5
85.2
69.1
76.0
90.2
86.6
95.8
•^^^B^-'r-.l:'--:--^*^''1 •'-'• &
5:25
6:37
8:53
3.23 7:35
8:30
10:05
12:28
12:36
15:32
16:07
19:20
19:27
25:30
23:26
23:33
25:03
24:47 "
34:50
32:37
32:53
Flags
SB_
B_
B_
B_
B_
B_
B_
PR_
Page 1 of 2
PAHJ.PSR vlOO. LARS 6.10 03
Triangle Laboratories, Inc.®
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 11:2608/25/97
-------
'",''>:,'•'••- •• •
TLI Project:
Client Sample:
internal Standards
dg-Naphthalene
dio-2-Methylnaphthalene
d7-2-Chloronaphthalene
dg-Acenaphthylene
dio-Phenantorene
di;-Benzo(a)antfaracene
dio-Fluoranthene
di;-Clirysene
di;-Perylene
di;-Benzo(b)fluorantiiene
di:-Benzo(k)fluoranthene
di:-Benzo(a)pyrene
di:-Benzo(g,lu)perylene
di:-Indeno( l,2.3-cd)pyrene
du-Dibenz(a,li)anthracene
f, „ £*
42299B
TLILCS
/;'<---*afc&&^
25.6
26.7
24.7
73.7
103
153
112
99.0
135
216
120
191
188
344
400
Alternate Standard (Type A) AmL (ng)
dio- Anthracene
Recovery Standards
dio-Acenaphthene
dio-Pyrene
di:-Benzo(e)pyrene
104
, ' ^fc^^^AK^
E«feM»ifeKrgKghSit3Ky^»E si
'^^^^K f " ?v '^
v" \ ' .""
' '"**- iSil?^
'* '-' ^ { '^jff^V'
^ \ ', ^
•. ^-*S ^
PAHJ Analysis (a)
•.;;^%^«WWf
25.6
26.7
24.7
73.7
103
153
112
99.0
67.6
108
60.1
95.5
94.1
172
200
% Recovery
104
QC Limits
40%-130%
40%- 130%
40%- 130%
40%-130%
40%- 130%
40%-130%
40%- 130%
40%- 130%
40%- 130%
40%- 130%
40%- 130%
40%- 130%
40%- 130%
40%- 130%
40%- 130%
QC Limits
40%- 130%
Analysis File:
::;:.:- -RadSla-- :;.::;. '• RT
5:23
6:32
3.21 7:32
8:28
12:24
19:16
15:29
19:22
25:20
23:19
23:27
24:55
34:36
32:24
32:36
BT
12:33
RT
8:49
16:04
24:37
U972701
^.Ftegs
v
V
V
I
Flags
—
Flags
Data Reviewer:
08/25/97
Page 2 of 2
PAHJ.PSR »ioo. LARS 610 03
Triangle Laboratories, Inc.®
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 11:26 08/25/97
136
-------
Data Review By:
Initial
. .Date.
Calculated Noise Area: n/a
Page No. 1
08/25/97
Compound/
M_Z.... QC.Log Omit Why
Listing of O972701B.dbf
Matched GC Peaks / Ratio / Ret. Time
.RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
Naph
123
128
d8-Naph
136
136
2-Me-Naph
142
142
dlO-2-Me-Naph
152
DC NL 0:00
5:07
5:12
5:25
5:43
6:54
7:19
7:22
7 Peaks
DC NL 0:00
5:23
DC WH 7:26
1 Peak
DC NL 0:00
5:15
6:37
6:48
7:21
4 Peaks
DC NL 0:00
DC NL 0:00
6: 32
6-44
8: 12
8: 30
8:35
8:45
8:53
9:13
9:15
9:48
10:15
10:23
10:29
10:41
10:51
10:58
11:04
227.30
125,203.00
10,815.00
329,782.00
1,151.88
1,760.38
2,531.52
2,117.28
473,361.06
10.66
5,935.70
51.71
5,935.70
35.34
73.17
6,051.87
439.29
72.40
6,636.73
5.38
87.20
3,720.68
30.89
51.52
16,097.40
29.50
92.09
5,858.44
145.91
28.00
24.58
60.99
61.57
418.27
61.49
119.30
222.14
91.05
125,203.00
10,815.00
329,782.00
1,151.88
1,760.38
2,531.52
2,117.28
5,935.70
73.17
6,051.37
439.29
72.40
3,720.63
30.89
51.52
16,097.40
29.50
92.09
5,858.44
145.91
28.00
24.58
60.99
61. 57
418.27
61.49
119.30
222.14
91.05
0.623-1.372
0.000
0.950
0.966
1 . 006 Naph
1.062
1.282
1.359
1.368
0.071-1.372
0.000
1. 000 d8-Naph
1 381
0. 692-1. 308
0 000
0. 957
1.013 2-Me-Naph
1. 041
1.125
0.002-1.949
0.000
0.000
1.000 dlO-2-Me-Naph
0.795
0. 969
1.004 Acenaph
1..014
1 . 033
1.049
1.089
1.093
1.157
1.211
1.226
1.238
1.262
1.281
1.295
1.307
AN
ISO
AN
IS1
AN
Triangle Laboratories, inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 11:27 08/25/97
137
-------
Page No.
08/25/97
Listing of CJ97270lB.dbf
Matched GC Peaks / Ratio / ReC. Time
Compound/
M_Z .... QC . Log Qmi t Why
,RT. OK Ratio Total.Area... Area.Peak. 1. . Area.Peak.2. . Rel.RT Compound.Name.. ID.. Flags.
11:08
11:22
11:26
11:31
11:34
11:40
11:42
11:47
11:52
11:55
11:58
12:04
12:09
12:12
12:15
12:21
12:29
12:32
12:36
12:43
12:45
12:47
12:55
13:03
13 10
13:15
13:29
13:33
13:40
13:43
13:45
13:50
152 49 Peaks
Acenaphthen
154 DC NL 0:00
8:10
8:38
8: 53
8:57
9:02
9:06
9:55
10:15
DC WH 10:29
DC WH 10:43
DC WH 10:51
DC WH 10:58
DC WH 11:08
DC WH 11:11
263.80
588.50
439.00
664.21
180.76
59.50
109.07
169.72
651.64
333.60
51.39
35.84
66.11
79.56
183.16
362.35
3,629.31
30.26
2,371.31
337.15
264.63
298.50
107.28
159.03
96.50
134.97
359.32
261.75
60.29
100.60
23 .19
151.89
39,739.11
44.20
10.32
19.27
8,085.29
7.12
34.12
528.20
243 .49
86.47
65.35
31.29
86.35
72.68
21.05
36.01
263.30
588.50
439.00
664.21
180.76
59.50
109.07
169.72
651.64
333.60
51.39
35.34
66.11
79.56
183.16
362.85
3,629.31
30.26
2,371.31
337.15
264.63
298.50
107.28
159.03
96.60
134.97
359.32
261.75
60.29
100.60
23.19
151.89
Acenaphthen Follows —
10.82
19.27
8, 085.29
7 12
34.12
528.20
243.49
86.47
1.315
1.343
1.350
1.360
1.366
1.378
1.382
1.392
1.402
1.407
1.413
1.425
1.435
1.441
1.447
1.459
1 .474
1.480
1.488
1. 502
1.506
1. 510
1.526
1 541
1.555
1 565
1. 593
1 .600
1.614
1.620
1.624
1.634
0.764-1.236
0. 000
0.965
1.020
1 . 049 Acenaphthen
1.057
1.067
1 .075
1.171
1.211
1.233
1.266
1.281
1.295
1.315
1.321
AN
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 11:27 08/25/97
-------
Page No.
08/25/97
Listing of U972701B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Conpound.Name.. ID.. Flags.
154
d8-Acenaph
160
160
2-Cl-Naph
162-164
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
WH
WH
WH
WH
WH
WH
WH
WH
WH
WH
WH
WH
WH
WH
WH
WH
WH
WH
WH
WH
WH
WH
WH
3
NL
WH
WH
WH
WH
WH
WH
WH
WH
4
NL
11
11
11
11
11
11
12
12
12
12
12
12
12
12
13
13
13
13
13
13
13
13
13
:22
:25
:30
: 34
:47
:52
:12
-.14
:22
:28
:32
:41
:46
:54
:00
:04
:09
:15
-.29
: 33
:40
:44
: 55
Peaks
0
8
3
8
9
12
12
12
12
13
13
13
13
Pe
0
00
22
23
49
45
06
25
33
56
00
14
17
27
aks
:00
170.
89.
198.
121.
175.
151.
85.
79.
177.
15.
56.
70.
140.
75.
31.
93.
31.
23.
424.
396.
18.
61.
22.
9,014.
13 .
36.
14,563.
8,675.
52.
23.
3,303.
2,323.
31.
46.
20.
19 .
76.
23,327.
•~ ADOVS ; Ac ena.pri tiier!
2.62-3.54
RO 1.00 6.
36
42
16
47
29
62
79
74
09
09
04
29
69
36
02
74
58
18
91
34
72
21
29
73
73
52 36.52
40 14,563.40
39 8,675.39
28 52.28
93
18
37
61
69
35
00
51
59
57
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1
1.
1 .
I.
I.
0.002-
0.
0.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
0.735-
0.
343
348
358
366
392
402
441
445
461
472
480
498
508
524
535
543
553
565
593
600
614
622
544
1.236
000
988
000 d8-Acenaph
041
152
429
467
482
523
535
563
569
589
1.265
000
162-164
132
7:35 3.23
1 Peak
4,892.43
4,892.43
3,736.53
1,155.90 1.007 2-Cl-Naph
AN
dlO-Acenaphthen
164 DC NL
0:00
Above: 2-Cl-Naph / dlO-Acenaphthen Follows
5.01
0.735-1.265
0.000
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 11:2708/25/97
139
-------
Page No.
08/25/97
Listing of U972701B.dbf
Matched GC Peaks / Ratio / Ret.
Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
N
164
Fluorene
166
166
d7-2-Cl-Naph
169-171
169-171
Phenan
178
178
dlO-Phenan
188
138
Fluoran
202
8:49
12,814.60
1 Peak 12,814.60
DC NL 0:00
10:05
10:57
11:22
11:52
12:21
DC WH 13:30
5 Peaks
DC NL 0:00
7:32
1 Peak
DC NL 0:00
9:13
10:57
11:07
11:13
11:22
11:27
11:30
11:42
11:52
12:28
12:36
13:42
13:55
13 Peaks
DC NL 0:00
12:24
12:33
2 Peaks
DC NL 0:00
15:32
30.58
8,404.55
114.43
1,323.40
938.39
151.69
99.46
10,932.46
2.62-3.54
3.10 7.70
3.21 3,589.94
3,589.94
Above • d7 - 2 -Cl -Naph /
34.11
392 .86
274.46
857.96
143.19
344.61
274.22
114.39
265.39
245.74
13,730.80
10,242.70
353.92
143.35
27,394.59
4.59
9,639.42
3,424.01
18,063.43
132.63
16,217.40
12,814. 60
8,404.55
114.43
1,323.40
933.39
151.69
c37- 2-Cl -Naph Follows
2,737.70
392.36
274.46
857 96
143.19
344. SI
274.22
114.39
265.39
245.74
13,730.30
10,242.70
353.92
143.35
9,639.42
8,424.01
16,217.40
1 . 170 dlO-Acenaphthen
0.678-1.000
0.000
0.813 Fluorene
0.833
0.917
0.957
0.996
1.089
0.735-1.265
0. 000
852.24 1.000 d7-2-Cl-Naph
0.195-1.805
0. 000
0.743
0.383
0. 397
0.911
0.917
0.923
0.927
0.944
0.957 ~
1 . 005 Phenan
1.016 Anth
1.105
1.122
0.195-1.805
0. 000
1.000 dlO- Phenan
1.012 dlO-Anth
0.354-1.646
0.000
1.003 Fluoran
RSI
AN
IS3
AN
AN
IS4
ALTS
AN
Triangle Laboratories, Inc.® Analytical Services Division
801 Capttola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 11:2708/25/97
140
-------
Page No
08/25/97
Listing of U972701B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_2.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1. . Area.Peak.2.. Rel.RT Confound.Name.
ID.. Flags.
202
dlO-Fluoran
212 DC
212
B-a-Anth
228 DC
228
d!2-3-a-Anth
240 DC
240
B-b-Fluoran
252 DC
M
M
M
M
M
252
d!2 -B-b-Fluoran
264 DC
M
M
M
M
16:
19:
19:
:07
:20
: 27
4 Peaks
NL 0:
15:
16:
19:
19:
:00
:29
04
:16
:22
4 Peaks
14
30
11
13
,063.
221.
290.
,792.
18.
,800.
,368.
328.
331.
25,829.
20
76
41
77
07
90
30
94
48
62
/
NL 0:
15:
16:
16:
19:
19-
:00
:30
ill
53
20
27
5 Peaks
NL 0:
17:
19:
19:
00
52
15
22
3 Peaks
4
4
9
4
3
18.
143 .
261.
207.
,321.
,157.
,592.
9.
125.
,265.
,389.
7,780.
39
34
81
06
55
97
23
17
98
21
11
30
/
NL 0:
23:
23:
24:
24:
25:
25:
:00
:26
:33
:24
i47
:03
;30
6 Peaks
NL 0:
22
23
23:
23:
24:
24
24:
:00
:46
:01
:19
:27
:16
:37
:55
3
2
2
2
1
12
7
5
2
3
29.
,490.
,800.
40.
,770.
,010.
,720.
,330.
19.
249.
496.
,430.
,030.
107.
,900.
,990.
89
00
00
56
00
00
00
56
39
98
90
00
00
55
00
00
14,063.
221.
290.
11,800.
13,368.
328.
331.
20
76
41
90
30
94
48
1
1
1
0.290
0
1
1
1
1
.041
.249
.256
Pyrene
AN
-1.646
.000
.000
.038
.244
.251
dlO-Fluoran
dlO- Pyrene
IS5
RS2
143.
261.
207.
4,321.
4,157.
125.
4,265.
3,389.
B~ D~ F LUO1T3J1
3,490.
2,800.
40.
2,770.
2,010.
1,720.
249.
496.
7,430.
5,030.
107.
2,900.
3,990.
84
31
06
55
97
98
21
11
00
00
56
00
00
00
98
90
00
00
55
00
00
0.481
0
0
0
0
1
1
0.431
0
0
1
1
0.606
0
0
0
0
0
0
1
0. 606
0
0
0
0
0
0
0
0
-1. 519
.000
.304
.840
.381
.003
.010
3-a-Anth
chrysene
AN
AN
-1.519
.000
.927
. 000
.005
d!2-B-a-Anth
dl 2 -Chrysene
IS6
islO
-1.394
.000
.925
.930
.963
.978
.989
.007
B-b-Fluoran
B-k-Fluoran
B-e-Pyrene
B-a-Pyrene
Perylene
AN
AN
AN
AN
AN
-1.394
.000
.899
.909
.920
.926
.958
.972
.984
d!2 -B-b-Fluoran
d!2-B-k-Fluoran
d!2-B-e- Pyrene
d!2 -B-a-Pyrene
isll
is!2
RS3
is!3
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 11:27 08/25/97
141
-------
Page No.
08/25/97
Listing of U972701B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak. 1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
IS7
M
264
I-123-cd-Py
276
M
276
DiB-ah-Anth
278
M
273
d!2-I-123-cd-Py
288
3
25
:20
Peaks
3,710
.00
23,914.43
DC
NL
5
0
32
32
33
34
34
:00
:37
:54
:35
:09
:50
Peaks
16
1,190
340
23
67
963
.03
.00
.44
.26
.37
.39
2,584.46
nV*A*T« . T 1 n "i ~~-3 TV.. /
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
WL
WL
WL
WL
WL
WL
WL
WL
WL
WL
WL
WL
WL
WL
WL
WL
WL
WH
4
0
20
20
21
22
22
23
23
:00
:28
:50
:48
:20
: 56
:24
:33
24. 00
25:02
25'
1 1 T
25:29
25:
26.
27:
27:
2 ' :
29.
30-
32:
32:
32:
34:
51
06
23
35
51
11
36
16
22
53
52
Peaks
12
123
5
14
14
16
8
34
32
.33
.26
.39
.73
.93
.05
.55
.97
.37
3,710
.00
1
.000
dl2-Perylen<
11 *) 1 f*A th r V*\ 1 ^ rtue
1,190
340
23
67
963
.00
.44
.26
.37
.39
0.711
0
0
0
0
0
1
-1.289
.000
.943
.951
.971
.987
.007
I-123-cd-Py
B-ghi-Pery
0.939-1.061
0
0
0
0
0
0
.000
.628
.639
.669
.535
.703
0.713
17.73
21.32
20.39
9.46
15.30
17.58
18.
23.
2.
22.
99.
72.
1,180.
30.
13
36
29
61
17
49
00
45
1,374.27
DC
DC
NL
WL
0:
22:
25:
26:
30:
31:
31:
00
24
52
45
42
20
47
10.
47.
11.
15.
59.
31.
136.
73
45
01
53
55
29
54
22.
99.
72.
1,180.
61
17
49
00
0.
0.
.722
.736
0.768
0.776
0.782
0.793
0.
0.
0.
0.
0.
0.
0.
0.
1.
1.
301
340
346
354
395
939
990
993
009
070
DiB-ah-Anth
il2- I- 123-cd-Py Follows
11.
15.
59.
31.
136.
01
53
55
29
54
0.711-
0.
0.
0.
0.
0.
0.
0.
1.289
000
647
748
773
387
906
919
AN PR
AN
AN
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitoia Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 11:27 08/25/97
142
-------
Page No. 7
08/25/97
Compound/
M_Z.... QC.Log Omit Why
288
d!4-DiB-ah-Anth
292
292
DC
DC
DC
DC
DC
DC
31:55
32:24
33:24
33:52
34:36
10 Peaks
- — &i
NL 0:00
WL 24:35
WL 26:26
WL 26:53
WL 27:06
WL 23:49
31:08
31:35
32:01
32:36
34:45
35:17
6 Peaks
Listing of U972701B.dbf
Matched GC Peaks / Ratio / Ret. Time
.RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
0.922
0.936 d!2-I-123-cd-Py is!4 I
0.965
0.979
1.000 d!2-B-ghi-Pery IS8
38.29
2,360.43
40.67
205.06
1,651.66
4,550.03
38.29
2,360.43
40.67
205.06
1,651.66
Above: d!2-I-123-cd-Py / d!4-DiB-ah-Anth Follows
1
1
3
7
8
15.
19.
25.
1.
33.
126.
,570.
15.
7.
,755.
.52
.81
.17
.28
.45
.43
.55
.52
.98
.00
.22
93
.20
1
33
126.
1, 570
15
7.
.55
. 52
.98
.00
.22
.93
0.939
0
0
0
0
0
0
0
0
0
1
1
-1.306
.000
.754
.311
.325
.331
.384
.955
.969
.982
.000 d:
. 066
000 d!4-DiB-ah-Anth IS9
i.os:
Column Description.
"Why" Code Description QC Log Desc.
M_Z -Nominal Ion Massies)
..RT. -Retention Time (mm:ss)
Rat.l -Ratio of M/M+2 Ions
OK -RO=Ratio Outside Limits
Rel RT-Relative Retention Time
End of Report
WL-Below Retention Time Window
WH-Above Retention Time Window
SN-Below Signal to Noise Level
-------
Filf:0972701 #1-295 Acqii3-AVO-l997 08:30:40 X g* Voltage SIS. 703 Solme:113S4B
128.0626 BSUB(256,
30, -3.0) PXB(3,1, 2, 0.50*,454592. 0,0.00*,?,?) Bxp:PAB5
TRIASOLX LABS TfXtiTLI LCS TLIt42299B
100*
80.
SO.
40.
20.
0
A3. 3
A1.25B9
t
i
IL /
JOS9
-1.1X9
.8.6X8
.6.4S8
.4.3S8
.2.1X8
' 0.0X0
5:00 5:12 5:24 5:36 5:48 6iOO 6:12 6t24 6:36 6t48 7:00 7:12 7:24 7>36 7t48 8:00 Tloe
Plle:U972701 01-295 Acq:13-AVO-1997 08:30:40 OC «T+ Voltage SIR 703 Sod.me:5330
136.1128 BSUS1256,
30, -3.0) PXD (3, 1,2, 0.50*, 21320.0, 0. 00*,P,P) Sxp:PAH5
TRIANOLS LABS Text:TLI LCS TLIJ42299B
IOCS
so:
601
401
201
0"
A5.94S7
1 \
-2.7X7
'.2.1S7
'.1.6B7
.1.1X7
.5.3S6
O.OSO
Sidd ' '5:12 ' 'Ss24 ' '5:36 ' '5:48 ' ' 6iOO ' ' 6si2 ' 6:24 ' '6:36 ' '6:48 ' 7:66 ' '7:12 ' '7:24 ' '7:36 ' 7:48 ' '8:00 Tlma
Fil»:U972701 #1-295 Acq: 13-AUG-1997 08:30:40 OC EI+ Voltage SIR 70S SOis»:17671
142.0782 BSUB(256,
30, -3.0) PKD(3,1,2,0.50*,70684.0,0.00*,P,P) Exp:PAB5
TRIANGLE LASS Texf.TLI LCS TLI#42299B
100%
so:
601
401
201
01
A6.05E7 3.6S7
1
A4.39E6
MA • -
'.2.9B7
-2.US7
'.1.4S7
-7.1E6
" O.OSO
5s 00 5:12 5s 24 5:36 5:48 6:00 6:12 6:24 6:36 6:48 7:00 7:12 7:24 7:36 7:48 8:00 Tim»
FJ.l»iU972701 #1-295 Acq: 13 -AGO- 1997 08:30:40 OC SI+ Voltage SIR 70S Hoiau:2692
152.1410 BSUB(256,
30, -3.0) PKD(3,1,2,0.50*,10768.0,0.00*,P,P) Bxp:PAB5
TRIANGLE LASS T«xt:TLI LCS TLI#42299B
10 (A
so:
601
40:
201
0'
\
A3 . 72E7
'
l\
-2.4B7
.1.9S7
-1.4S7
-9.5E6
.4. 8S6
a.oso
5:00 5:12 5:24 5:36 5:48 6:00 6:12 6:24 6:36 6:48 7:00 7:12 7:24 7:36 7:48 8:00 Tim*
P±1»:O972701 #1-295 Acq: 13-AVO-1997 08:30:40 " 7:26 7'.<3t . .
S'P9 5:18 J\AAA,/VA /*\^\ N/^ A A X>^/Vv^AA *»W A. J\/\,,A/SA /-vJ\AMy\/vAAAA/^
AV^v
/ \J V
/
/
i • Y w -"VV--1 /w^/ \y n n / u v V * v
\N V U 1 / L V
\r V\JM
.
.2.5X6
-2.0S6
.1.5X6
.1.0X6
.5.0X5
a.oso
5:00 Ssl2 5:24 St36 5i48 giOO 6:12 6t24 6:36 ' '6:48 ' '7:00 ' 'ilia ' ~7:24 ' '7i36 ' '7:48 ' 'itOO Tlae
144
-------
PlJ.ftO'972701 #1-534 Aaqtl3-JUJO-1997 O8:JO:40 OC1 Jbl* voltage SJS 70S OOlf»t436O2
152.0626 Pi 2 BSUB(256,30,-3.0) PSD(3,3,l,0.01*,174408.0,0.00*,f,f) XXptPAHS
rSIABOLB LABS TmxttTLI LCS TLH42299B
ion
80.
60.
40.
20.
Al.
8:00
1X8
AS.
-
0«*7
A3.«3*7
..r r. -!U
-1.0*0
.0.0*7
.6 . 0*7
.4.0*7
.2.0*7
000
5:00 10:00 11:00 12:00 13:00 14 00 7iae
Pil»:U972701 #1-534 Aaqi 13 -ADO- 155 7 00:30:40 OC SH- Voltage SIX 70S Hoi* •: 6865
160.1128 Pt2 BSOB (256, 30, -3.0) PXD (3, 3, 1,0. 01*, 27460. 0,0. 00*, P. P) SxptPABS
TRIANGLE LABS T«zt:TLJ LCS TLI142399B
100*
00:
601
401
201
01
Al.
8:00'
6E8
AS.68E7
A3. 30*7
h
_5.3*7
_7.4*7
_5.S*7
_3 . 7*7
-1.5B7
0.0*0
5/00 10:00 11:00 12:00 13:00 14:00 Time
P±1»:O972701 #1-534 Ac^:13-AtrO-1557 08:30:40 OC *I* Voltage SIR 70S Hoi**t22100
154.0782 P:2 BSOB(256,30, -3. 0) PKD(3,3,1, 0. 01*,88400. 0, 0. 00*,P,P) ExpsPASS
TRIANGLE LABS Text.'TLJ LCS TLIX42299B
100*
SOI
601
401
201
0'
8:00
AB.
15*7
A * ^ » »NA- _
_4 . 5B7
_3 . 6*7
_2.7*7
_1.«7
15.0*6
"5.0*0
5;'oO 10:00 ' 11:00 ' ' ' 12:00 ' 13:00 14:00 Time
File: 17572701 #1-534 Acq: 13-AUO-1997 08:30:40 OC BI+ Voltage SIR 70S Hoi f»: 2505
164.1410 Ps2 BSOB (256, 30, -3.0} PKD(3, 3,1, 0.01*, 10020 .0,0. 00*,P,P) Exp:PASS
TRIAHOLE LABS Text.-TLX LCS TLIX42299B
100*
80.
601
401
20.
0.
8:00
Al.
asa
7.3S7
.5.5*7
.4.4*7
12.5*7
.1.5*7
0.0*0
9:00 10:00 11:00 12:00 13:00 14:00 Time
Pllut0972701 #1-534 Aaqt 13-AOO-1S97 00:30:40 OC ST+ Voltage SIR 70S
168.9888 P:2 Exp:PAB5
TRIASQLB LABS Tf3Ct:TLI LCS TLH42299B
100*
so:
40.
20:
0.
°M
8:00
0:42 9tii i(Jf24 «:59 la,34 la.54
Jul j(Ufl lUi. J.J-jJfl/^i . J. ,. i fi&WtjMlLj&&U... . 1 nrtflriil 11/VlhAnnfViJl^'J^I lAl
(I^'V
\f- Y^T^TT^ «^fw\iuu^ v pr ^ 'TfWnn' r T ffwn"V ^"w ^ ^ » r
-
6.2*7
.4.5*7
13.7*7
12.5*7
11.2*7
0.0*0
5:00 10:00 11:00 12:00 13:00 14:00 Time
14
-------
\Pil»:OS7270l 91-295 Acq, 13-100-1997 0*t30,iO X g* Volk*g» «B 70S Boi,»:1643
162.0236 BSUB(256,30, -3.0) PKD<3,2, 1, 1.00*,6572.0, 0. 00*,P,P) Xxp:PAS5
TRIABOLS LABS T«Xt:TLJ LCS TLI*42299B
100* A3. 7^4X7
so:
60^
40,
30_
0.:
5t
Pll»
164.
TRXA
100*
so;
so:
40:
20:
a:
5:
Fil«
i«.
TJMA
1005
80,
60,
40.
20.
0
5t
Flit
171.
TRIA
100*
so;
60^
40.
20.
0'
5i
Pile
154.
TRXA.
ion
BO.
60.
40.
20.
0
Si
II
-2.4T7
.1.9X7
'.1.4X7
.9.4X6
.4.7X6
0.0X0
66' 5«'ia" '5i24" 5:36 5,49 6166 6tl2 6t24 6^36 6t4B 7tOO 7il3 7,24 7t36 7t4B 8>00 Tim.
iUS72701 tl-295 Acqt 13-AUQ-1997 OBi30i40 OC XX* Voltay. SIR 703 Noll ft 1638
0207 B30S(25S,30, -3.0) PXD(3,2el,1.00*,6552.0,0.00*,P,P) SxpiPABS
HOLS LABS TmxttTLI LCS TLI042299B
A1.1SS7 7.3S6
\ r
'.5.9S6
.4.4E6
.2.936
.1.5S6
O.OSO
66 ' '5:12 ' '5s24 ' 'st36 5:48 6:00 6tl2 6t24 6i36 6:48 7:00 7:12 7:24 7:36 7:48 8:00 Tlm»
:U972701 #1-295 Acq: 13-AUO-1997 08:30:40 OC BX+ Voltage 3IR 703 Solf»:2909
0676 BSUB(256,30,-3.0) PKD(3,2, 1, 1. 00*, 11636. 0, 0. 00*,P,F) SxpsPASS
SOLS LABS Toxf.TLI LCS VLI#42299B
A2 4E7 1 . 6S7
\ -
66 ' '5:12 ' 'Ss24 ' ' 5:36 ' '5:48 ' 6:66 ' '6:12 ' '6:24 ' '6:36 ' '6:48 ' '7:66 ' '7:12 ' 7:24 7:36 7:48 8:
:U972701 #1-295 Acq: 13-AUO-1997 08:30:40 QC BI+ Voltafff SIR 70S Sois»:939
0648 BSUB(256,30,-3.0) PKD(3,2, 1, 1.00*, 3756. 0, 0.00*,P,F) Sxp:PAB5
HOLE LABS Tmxf.TLI LCS TLI#42299B
A8.52S6
'
11
00 5:12 5:24 5:36 5:48 6:66 6:12 6:24 6:36 6:48 7:00 7sl2 7:24 7:36 7:48 8:
:U972701 #1-295 AcqilS-AUO-1997 08:30:40 OC SZf Voltafff SIR 703
9920 SxpsPABS
HOLS LABS Toxt-.TLI LCS TLI042299B
. .„ 5:29 5t47 6:00 6'21 f>31 , ,, 7:09 7*17 7:26 7\43i . .
5s°9 5:18 /^>V^\A/^A.JV/A /\A /\ /^W^^ . 6>S9 A. *^AAn/N^rvJYVVvv'V^/^
I \ \l \N U L / L I v
J v vw \iM
1
00 5tl2 5:24 5i36 5:48 6tOO 6tl2 fi24 6:36 6:48 7tOO 7:13 7t24 7:36 7:48 8:
'.1.3S7
.9.7S6
.6.5S6
.3.2S6
O.OSO
00 T±ma
^5.1E6
-4.1B6
_3.1S6
_2.1S6
.1.0S6
O.OSO
00 Time
-2.SS6
.2.0X6
.1.5X6
.1.0X6
.5.0X5
.0.0X0
00 Time
146
-------
Fil*
166.
TRIA.
IOCS
80.
60.
40.
201
0
8:
Pil*
176.
TRIA
1003
801
601
401
201
0'
8:
178.
TRIA.
1005
801
60.
40.
201
0
8:
Pil*
188.
TRIA
1003
801
601
401
201
0
8:
Pil*
168.
TRIA
1003
801
601
401
201
0'
8:
IU9727O1 91-534 Acq: 13-Auv- 1S97 08:30:40 <*J JSJ.+ VOltMg* SIX 70S HO1B*:15388
0782 P:2 BSUB(25€,30,-3.0) PXDf5,l,l, 0.50*, 61132. 0,0. 00*,F,P) SxpiPABS
HOLE LABS TtxttTLI LCS TLI042299B
AS. 0X7
. . "'fT"'3™ . r .
_4.A*7
.3.8X7
.2.9X7
.1.9X7
.9.5X6
0. 0X0
00 WOO 10*00 11*00 12*00 13 1-00 14*00 Tim*
:O972701 #1-534 Aoq:13-AUO-1997 08:30:40 OC XH- Voltfg* SIX 703 Holm*: 2537
1410 P:2 BSUB(256,30,-3.0) PXD(5, 1,1, 0.50*, 10148. 0,0. 00*,P,F) X3tp:PAB5
HOLE LABS TmxtiTLI LCS TLI#42299B
— — M.p ^
f^htL^^^^
-5.2X4
-3.9E4
-2.6E4
.1.324
0.020
00 ' ' ' 9:00 10*00 11*00 ' 12*00 '- 13*00 ' 14 00 Tim*
SV972701 #1-534 Acq: 13-AUQ-1997 08:30:40 OC EI+ Voltag* SIR 70S Soia*:170S6
0782 P:2 BSUB(256,30, -3.0) PXD(5, 1,1,0.50*, 68224.0, 0.00*,P,P) ExptPABS
NQLE LABS T*xt:TLI LCS TLIS42299B
Al. 728 7.6E7
IS. 127
14.527
13.027
11.527
r a.OEO
00 9:00 10*00 11*00 12*00 13 .-00 14-00 Tim*
-.0972701 #1-534 Acq: 13-AUO-1997 08:30:40 OC 22> Voltag* SIR 70S SOis*:2296
1410 P-.2 BSUB(256,30,-3.0) PXD(S,1,1,O.SO*,9184.0,0.00*,P,P) Sxp:PAB5
SOLE LABS T*xt:TLI LCS TLI#42299B
A9. 427 5.427
1'
00 9:00 10*00 11*00 12*00 13*00 14
> 7972701 #1-534 Acqi 13-AUO-1997 08:30:40 OC BI+ Voltag* SIR 70S
9888 P:2 Xxp:PAB5
HOLE LABS T*xt:TLI LCS TLI#42299B
8M^^
00 9:00 10*00 11*00 ' 'l2«00 13*00 ' 14
.4.327
.3.227
.2.127
-1.127
0.020
00 Tim*
6.2X7
.4.9X7
.3.7X7
.2.5X7
.1.2X7
0.0X0
00 Tim*
147
-------
PiletU972701 #1-703 Acqt13-AUO-1997 08:30.40 OC XI* Voltage SIR 70S Soimet66314
202.0782 Ps3 BSVB(256,30,-3.0) PXD(S,3,1,0.10*,2S5256.0,0.00\,F,F) SxptPABS
TRIANGLE LABS TexttTLI LCS TLI*42299B
100* JU..62S8
80:
6ol
40:
20:
oj
A1.41S8
14»00 15:00 16:00 17:00 18:00 15:00
Pll»tU972701 #1-703 Ac^
14:00 15:00 ISiOO 17:00 18:00
Plle:U972701 #1-703 Acgtl3-AUO-1997 08:30:40 OC EH- Voltage SIR 70S
242.9856 P:3 SxptPABS
TRIANGLE LABS TexttVLI LCS TLI*42299B
1003
80:
60l
40:
20:
0:
15:00
.6.3X7
.4.7X7
.3.1X7
.1.6X7
O.OEO
20 00 Time
6.SS7
.5.2X7
.3.9X7
_2.6E7
11.3S7
Lo.oso
20.00
1.6B7
Ll.3^7
'-.9.8E6
'-.6.5E6
'-.3.3E6
n '-.o.oxo
20:00 Time
1.5E7
.1.2X7
.9.0X6
.6.0X6
_3. 0X6
L0.0BO
20 00 Time
.1.8ES
.9.0X4
.4.554
O.OEO
20 00 Time
5lll26 IStSl 16:47 17:34 18:28 18»52 10,5910.43 ,.*'
rf^t^i^^^^
IS*! 00
17:00
.3X7
.9.9X6
.6.6X6
.3.3X6
0.0X0
20 00 Time
148
-------
File
252.
TXXJL
lots
90.
80.
70;
60.
SO.
40.
30.
20.
10.
20
File
264.
TRIA
100*
50J
80J
70J
60:
50:
40;
30;
20:
10-
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20
File
268.
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100)
50_
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70.
60.
SO.
40.
30.
20.
10.
0
20
tU972701 * 1-1377 Act,
0939 Ft 4 BSUB(256,3t
HOLS LA83 TextiTLI
""
J: 13-AUO-1397 08s 30 1 40 QC XI* Voltuge SIS 70S Soiie: 14944
1,-3.0) PKD(7,5,3,0.20*,S977f.O,0.00*,r,r) XxpiPABS
LCS TLHf42299B
14X7
A3. 041
J
A
LA
S7
1.47B7
J{
00 22:00 24:00 26\OQ 28s 00 30:00 32:00 34 IT 00 36
:U972701 #1-1377 Acq: 13-AUO-1997 08:30:40 QC XI* Voltage SIR 703 Half e: 9697
1692 F:4 B3VS(2S6,30, -3.0) PXD(7,5,3,0.20*,3878S.O, 0.00*,F,P) SxpiPASS
SOLS LABS TaxtiTLI LCS TLI#42299B
A6.96E7
A3 . 69E7
1
LJ
A
6.1X6
.S.5S6
.4.9S6
.4.336
.3 . 7S6
.3.0X6
.2.4X6
'-1.3B6
.1.2X6
'.6.1S5
00 Time
.1.3X7
.1.1X7
.1.0B7
.8.9E6
-7.7E6
.6.4E6
.S.1E6
.3 . BE6
.2.6B6
'.1.3B6
• 0.020
:00 22\00 ' .24:00 26\00 28iOO 30sOO 32:00 34:00 3«sOO Tim*
:V972701 #1-1377 Acq: 13-AUO-1997 08:30:40 QC BI+ Voltage SIS 703
9824 F:4 SxptPABS
HOLS LABS TextlTLI LCS TLI1t42299B
ISLkjftjiS
M T WJR nf yir 1 1 T^
00 2.2/00 ' 24 1-00
p -' nri'-p • ify irT17iriWWTf|pl P^V
26\00 28tOO 30 tOO 32\00 34tOO 36
-.5.6X6
.4.9X6
.4.2X6
.3.5X6
.2.8X6
.2.1X6
.1.4X6
.7.0X5
0.0X0
00 rime
149
-------
\File:U972701 #1-1377 Acti:~13-A.!lO-lS97 OUiJOt40 X g* Voltage SIR 703 Boi*e,80l6
276.0939 P:4 BSUB(256, 30, -3.0) PKD(IS, 13,11, 0. SO*, 32064. 0, 0. 00*,F,P) Bxp:PAH5
TRIANQLB LABS TtXtsTLI LCS TLI#42299B
100ft AS. 34X6
ao.
60.
40-
20.
20:00 22:00 24:00 26:00 28:00 30'tOO 32} 00
Flle:U972701 #1-1377 Actjt 13-AUO-1997 08:30:40 IX BI+ Voltage SIS 70S Soite:S364
288.1692 Fs4 BSUB(2S6,30,-3.0) PXD(15,13,11,0.5O*,21456.0,0.00\,P,F) Sxp:PAH5
TRIANGLE LABS Text:TLI LCS TLI#42299B
10O
ao:
so:
20:
A2.36S7
A4. 74SS
A1.65S7
A1.37,
r1.7S6
Ll. 3S6
.9.9E5
•.6.6SS
.3.3E5
A2.0SS,
20 00 22:00 24:00 26:00 28:00 30sOO 32:00 34:00
fil»:U972701 #1-1377 Acq:13-AUO-1997 08:30:40 dC BI+ Voltage SIR 70S Kols«s6417
278.1096 P:4 BSUB(256, 30,-3.0} PKD(15,13,ll,0.50*,25668.a,0.00*,F,F) Exp:PAB5
TRIANGLE LABS T«XC:TLI LCS TLI#42299B
100* A8.86S6
80.
60.
.O.OEO
36 00 Tina
,-7.2SS
'.s. ass
40.
20.
20:00 22:00 24:00 26:00 28:00 30:00 32:00
Pil»:U972701 #1-1377 Acq: 13-AUG-1997 08:30:40 QC BI+ Voltage SIR 70S Noise: 1762
292.1974 P:4 BSUB(256,30, -3. 0) PXD(15, 13,11,0.50%, 7048. 0, 0.00*,P,P) Exp:PAH5
TRIANGLE LABS Taxt:TLI LCS TLI842299B
100* A1.32E7
ao:
eo:
40:
20:
0.
34:00
36 00
20:00 22:00 24:00 26:00 28:00 30:00
Pil*:U972701 #1-1377 Acq:13-AUO-1997 08:30:40 OC BI+ Voltage SIR 70S
268.9824 P:4 ExpsPASS
TRIASOLB LABS TfJCtiTLI LCS TLI#42299B
32} 00
34:00
.8.9BS
.6.7S5
-4.4S5
.2.2B5
O.OEO
36:00 Time
ion
ao:
eo:
40:
20:
o.
20:34 22:4023:37 25,26 36:57 28:38 30:37 „„ ,„ 33,40
-------
File;U972701 #1-1377 Acq:13-AUG-1997 08:30;40 GC EI+ Voltage SIR 70S Noise;14944
252.0939 F:4 BSUB(256,30,-3.0) PKD(7,3,1,0.10%, 59776.0, 0.00%, F,T) Exp:PAH5
Sample Text:TLI LCS TLI#42299B File Text:TRIANGLE LABORATORIES , INC
22112 22124 22:36 22:48 23:00 23:12 23:24 23:36 23:48 24:00 24:12
File:U972701 #1-1377 Acq:13-AUG-1997 08:30:40 GC EI+ Voltage SIR 70S Noise:9697
264.1692 F:4 BSUB(256,30,-3.0) PKD(7,3,1,0.10%, 38788.0, 0.00%,F,T) Exp:PAH5
Sample Text:TLI LCS TLI#42299B File Text:TRIANGLE LABORATORIES , INC
100%
90 j
80 J
70 J
60J
50 j
40J
30J
20 j
10J
oi
A7.43E7
22100 22:12 22:24 22:36 22:48 23:00 23:12 23:24 23:36 23:48 24:00 24:12
O.OEO
Time
1.3E7
1.1E7
1.0E7
8.9E6
7.7E6
6.4E6
5.1E6
8E6
2.6E6
1.3E6
O.OEO
Time
or
-------
Pile:U972701 #1-1377 Acq:13-AUG-1997 08:30:40 GC EI+ Voltage SIR 70S Noise:14944
252.0939 F:4 BSUB(256,30,-3.0) PKD(7,3,1,0.10%, 59776.0,0.00%,F,T) Exp:PAHS
Sample TextrTLI LCS TLI#42299B File Text:TRIANGLE LABORATORIES , INC
100%, A2.77E7
90J
80 J
70J
60J
50J
40 J
30J
20 J
10J
A2.01E7
A1.72E7
24:00 25:00 26:00
File:U972701 #1-1377 Acq:13-AUG-1997 08:30:40 GC EI+ Voltage SIR 70S Noise:9697
264.1692 F:4 BSUB(256,30,-3.0) PKD(7,3,1, 0.10%, 38788.0,0.00%,F,T) Exp:PAHS
Sample Text:TLI LCS TLI#42299B File Text:TRIANGLE LABORATORIES , INC
100%. A3.99E7 A3.71E7
A
90 J
80J
70J
60 J
50J
40J
30 J
20J
10J
OJ
A2.90E7
24:00
25:00
26:00
4.0E6
3.6E6
.3.2E6
.2.8E6
.2. 4E6
.2. OE6
.1.6E6
.1.2E6
.7.9E5
.4.0E5
.O.OEO
Time
_6.0E6
_5.4E6
_4.8E6
_4.2E6
_3.6E6
_3.0E6
_2.4E6
_1.8E6
L1.2E6
_6.0E5
O.OEO
Time
cn
r j>
-------
File:U972701 #1-1377 Acq:13-AUG-1997 08:30:40 GC EI+ Voltage SIR 70S
276.0939 F:4 Exp:PAH5
Sample Text:TLI LCS TLI#42299B File Text:TRIANGLE LABORATORIES , INC
lOOi A1.19E7
90 J
80 j
70J
60 J
50J
40J
30J
20J
10 J
0
22:00 24:00 26:00 28:00 30iOO 32100
File:U972701 #1-1377 Acq:13-AUG-1997 08:30:40 GC EI+ Voltage SIR 70S
288.1692 F:4 Exp:PAH5
Sample Text:TLI LCS TLI#42299B File Text:TRIANGLE LABORATORIES , INC
100% A2.58E7
90 j
80 j
70 J
60J
50J
40J
30J
20 j
10 j
OJ
34:00
22:00
24:00
26:00
28:00
30:00
~^—1—•"
32:00
34100
UJ
CO
-------
File;U972701 ttl-137'7 Acq; 13-AUG-1997 08:30:40 GC EI+ Voltage SIR 705
278.1096 F:4 Exp:PAH5
Sample Text:TLI LCS TLI#42299B File Text : TRIANGLE LABORATORIES , INC
100S
90 j
80J
70J
60J
50J
40J
30J
20J
10 j
0 :
Al.i
1
|
J\ ^^y^
22lob 24lob 26lob 28lob ' 30:00 ' ' ' 32lob '
File:U972701 #1-1377 Acq: 13-AUG-1997 08:30:40 GC EI+ Voltage SIR 70S
292.1974 F:4 Exp:PAH5
Sample Text:TLI LCS TLI#42299B File Text : TRIANGLE LABORATORIES , INC
100%
90J
80J
70 J
60J
50J
Af\ -
f»U_
^n :
ou_
20J
10 j
-8E7 ,_7.6E5
1
_6.8E5
_6.1E5
_5.3E5
_4.5E5
_3.8E5
_3.0E5
_2.3E5
_1.5E5
L7 . 6E4
. . . lfTTvrTT'>" • OEO
34:00 Time
A1.57E7 ^1.2E6
' ll
'
i I 1
' ^__~--r ^
22 lob 24 lob 26 lob 28lob 30:00 32lob '
-1.0E6
_9.2E5
_8.1E5
_6.9E5
-5.8E5
-4.6E5
.3.5E5
_2.3E5
_1.2E5
f\ /\TT»/\
TT^T-] ", "< v 1- »r u • ucu
34:00 Time
-------
TLI Project:
Client Sample:
42299B
TLI LCSD
PAHJ Analysis (a)
Analysis File: U972702
Client Project: Iron & Steel-Chicago
Sample Matrix: XAD Date Received: / /
TLI ID: TLI LCSD Date Extracted: 07/17/97
Date Analyzed: 08/13/97
Sample Size: 1.000
Dry Weight: n/a
GC Column: DB-5
Dilution Factor: n/a
Blank File: U972695
Analyst: MM
Spike File: SPPAHJ10
ICal: UPJ8127
ConCal: U972690
% Moisture: n/a
% Lipid: n/a
% Solids: n/a
i***®** ^ ^-^i^t^^^^i^^m^^ ''•"&$$*&&*¥• *rr V*«*WP
Naphthalene
2-Methylnaphthalene
Acenaphthene
2-Chloronaphthalene
Acenaphthylene
Fluorene
5henanthrene
Anthracene
Fluoranthene
Pyrene
Benzo(a)anthracene
2hrysene
3erylene
3enzo(b)fluoranthene
3enzo(k)fluoranthene
3enzo(a)pyrene
ienzo(e)pyrene
Jenzo(g,h,i)perylene
ndeno(l,2,3-cd)pyrene
)ibenz(aji)anthracene
1610
134
113
103
78.7
74.9
106
89.6
91.2
85.4
101
123
98.7
89.0
93.6
91.6
92.5
87.1
83.0
84.4
5:24
6-33
\J*~jJ
8-50
O. J\J
3.28 7:32
8-97
O.^» /
12:26
12-34
X Ar.»J*T
15-30
i^J ,^J\J
16-06
l\J,\s\J
19-19
A^. 1-7
19-25
*^. Ar^/
25-27
*>v> • A> /
23-30
-i«— '. J\_/
25-00
— . . , 4*tJ ,\J\J
24:44
34-46
«/^.^VJ
32:32
32:49
SQB
._.__
„„_
B
LJ
_
L
1
•^~~~
— —
•^ '
1
•^^~~
PR
* 1S-—
Page 1 of2
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
PAHJJ>SR TiOtt LARS «.10.03
Printed: 14:27 08/21/97
14:27 01
155
o
-------
TLI Project: 42299B
Client Sample: TLI LCSD
PAHJ Analysis (a)
Analysis File: U972702
m^'*m** ^ * AH* ti&^:m&*™#w" fcctfmit* r * X&S*C**r * ' ' **s*
ig-Naphthalene
dio-2-Methylnaphthalene
(17-2-Chloronapnthalene
dg-Acenaphthylene
dio-Phenanthrene
di2-Benzo(a)anthracene
dio-Fluoranthene
di2-Chrysene
di2-Perylene
di2-Benzo(b)fluoranthene
di2-Benzo(k)fluorantbene
di 2-Benzo(a)pyrene
di2-Benzo(g,h,i)perylene
di2-Indeno(l,2,3-cd)pyrene
di4-Dibenz(a,h)anthracene
Alternate Standard (Type A)
dio- Anthracene
i Recovery Standards
dw-Acenaphthene
dio-Pyrene
59.7
43.6
35.1
84.1
112
90.0
106
68.0
174
239
193
213
210
276
347
AmL (09)
98.8
59.7
43.6
35.1
84.1
112
90.0
106
68.0
86.8
119
96.3
106
105
138
173
% Recovery
98.8
:
40%-130%
40%-130%
40%-130% 3.34
40%-130%
40%-130%
40%-130%
40%-130%
40%-130%
40%-130%
40%-130%
40%-130%
40%-130%
40%-130%
40%- 130%
40%- 130%
QCLtmfts
40%-130%
5:21
6:30
7:30 V
8:25
12:22
19:14
15:27
19:20
25:18
23:15
23:25
24:52
34:30
32:19 I
32:32
BT Flags
12:31
Wf Fiags
8:46
16:03
24:35
Data Reviewer.
Page 2 of 2
08/21/97
PAHLPSRYiflfll LARS 6.10.03
Triangle Laboratories, Inc.®
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 14:27 08/21/97
156
-------
Data Review By:
Initial
Date...
Calculated Noise Area: n/a
Pag* No.
08/21/97
Listing of 09727028.dbf
Matched GC Peaks / Ratio
/ Ret. Tim*
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. 10.. Flags.
Naph
128
128
d8-Naph
136
136
2-Me-Naph
142
N
142
dlO-2-Me-Naph
152
DC NL 0:00
5 -.04
5:08
5:24
5:40
7:16
7:19
6 Peaks
DC NL 0:00
5:21
1 Peak
DC NL 0:00
6:11
6:33
6:45
7:19
4 Peaks
DC NL 0:00
DC NL 0:00
5:10
6:30
6:41
8:27
8:32
8:42
8:50
8:55
8:59
9:04
9:10
9:12
9:45
10:02
10:13
10:21
10:27
10:30
10:50
531.09
186,492.00
15,986.50
269,091.00
5,467.85
2,626.56
998.44
480,662.35
25.03
14,260.20
14,260.20
26.59
112.57
10,529.70
679.23
83.59
11,405.09
8.38
75.75
51.37
6, 272. 58
53.28
15,986.80
26.55
140.18
5,964.38
17.19
31.10
69.64
134.94
30.51
83.15
84.60
43.74
70.73
314.79
54.05
40.31
186,492.00
15,986.50
269,091.00
5,467.85
2,626.56
998.44
14,260.20
112.57
10.529.70
679.23
83.59
51.37
6,272.58
53.28
15,986.80
26.55
140.18
5,964.38
17.19
31.10
69.64
134.94
30.51
83.15
84.60
43.74
70.73
314.79
54.05
40.31
0.628-1.372
0.000
0.947
0.960
1.009 Napb
1.059
1.358
1.368
0.071-1.372
0.000
1.000 d8-Naph
0.692-1.308
0.000
0.951
1.008 2-Me-Naph
1.038
1.126
0.002-1.949
0.000
0.000
- 0.614 - .
1.000- dlO-2-Me-Naph
0.794
1 . 004 Acenaph
1.014
1.034
1.050
1.059
1.067
1.077
1.089
1.093
1.158
1.192
1.214
1.230
1.242
1.248
1.287
AN
ISO
AN
^. .
IS1
AN
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 14:27 08/21/97
157
-------
Page No. 2 Listing of O972702B.dbt
08/21/97 Matched OC Peaks / Ratio
Conpound/
/ Ret. Time
M_Z. . . . QC.Log Omit Why . .RT. OK Ratio Total. Area. . .
10:
11:
11:
11:
11:
11:
11:
56
01
05
16
20
24
29
11:31
11:
11:
11:
11:
11:
11:
12:
12:
12:
12:
12:
12:
12:
12:
12:
13:
13:
13:
13:
13:
13:
13:
13:
13:
38
40
46
50
53
56
10
13
20
27
31
35
41
43
46
00
04
13
24
27
32
38
41
54
152 51 Peaks
Acenaphthen
154 DC NL 0:
8:
8:
8:
9:
9:
10:
10:
DC WH 10:
DC WH 10:
DC WH 10:
DC WH 10:
DC WH 10:
DC WH 11:
DC WH 11:
210
68
191
53
470
332
474
145
31
58
90
577
255
26
16
160
286
3,739
21
2,413
121
144
163
71
13
149
16
127
55
134
104
19
.43
.76
.68
.25
.14
.53
.87
.61
.85
.42
.90
.27
.60
.10
.80
.47
.35
.03
.95
.65
.77
.65
.22
.17
.17
.97
.64
.97
.04
.27
.52
.77
40,217.71
Hl*,»»* . "') U-. ItTwiVi /
00
25
35
50
04
53
13
21
27
41
44
49
55
06
09
59
66
36
12,237
601
232
84
32
101
44
22
73
74
29
23
.19
.62
.23
.80
.41
.86
.05
.61
.70
.15
.73
.54
.02
.22
.24
Area. Peak. 1
210.
68.
191.
53.
470.
332.
474.
145.
31.
58.
90.
577.
255.
26.
16.
160.
286.
3,739.
21.
2,413.
121.
144.
163.
71.
13.
149.
16.
127.
55.
134.
104.
19.
Ac on sp xi triBp
66.
36.
12,237.
601.
232.
84.
32.
. . Area. Peak. 2. . Rel
43
76
68
25
14
53
87
61
85
42
90
27
60
10
80
47
35
03
95
65
77
65
22
17
17
97
64
97
04
27
52
77
62
23
80
41
86
05
61
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1,
1.
1.
1.
.BT Compound. Name. . ID.. Flags
299
309
317
339
347
354
364
368
382
386
398
406
412
418
446
451
465
479
487
495
507
511
517
545
552
570
592
598
608
620
626
651
- - -
0.764-1.236
0.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
000
0.00
020
050 Acenaphthen AN
077
174
214
230
242
269
275
285
297
319
325
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 14:27 08/21/97
158
-------
Page No.
08/21/97
Listing of U972702B.dbf
Matched OC P«aks / Ratio / Ret. Time
Compound/
M_Z QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak. 1.. Area.Peak.2.. Rel.RT conpound.Name.. ID.
Flags.
154
d8-Acenaph
160
160
2-Cl-Naph
162-164
162-164
OC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
HH
WH
WH
WH
HH
WH
WH
WH
WH
HH
WH
HH
WH
WH
WH
WH
WH
WH
WH
WH
WH
7
NL
WH
WH
WH
WH
WH
WH
WH
WH
WH
WH
WH
WH
4
11:20
11:
11:
11:
11:
11:
12:
12:
12:
12:
12:
12:
12:
12:
13:
13:
13:
13:
13:
13:
13:
23
28
32
46
50
10
12
16
20
22
26
30
57
13
18
27
32
38
42
53
Peaks
0:
3:
8:
8:
9:
11:
12:
12:
12:
12:
12:
12:
12:
12:
13:
13:
13:
00
19
25
46
43
59
04
22
31
44
48
51
53
58
12
16
24
Peaks
202
75
212
153
158
146
81
100
20
316
39
19
65
35
66
12
159
99
63
41
45
13,291
11
48
17,144
9,478
30
25
29
3,863
2,507
22
23
24
40
59
36
34
137
.76
.11
.87
.50
.83
.19
.08
.28
.33
.93
.61
.30
.30
.29
.14
.32
.82
.26
.18
.32
.32
.58
.18
.19 48.19
.30 17,144.30
.40 9,478.40
.81 30.81
.18
.91
.25
.22
.92
.45
.97
.44
.63
.76
.37
.66
i
i
i
i
i
i
i
i
i
i
i
i
i
i
i
i
i
i
i
i
i
0.002
0
0
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
.347
.352
.362
.370
.398
.406
.446
.450
.457
.465
.469
.477
.485
.539
.570
.580
.598
.608
.620
.628
.650
-1.236
.000
.988
. 000 d8-Acenaph
.042
.154
.424
.434
.469
.487
•513
.521
.527
.531
.541
.568
.576
.592
26,701.70
2.62-3.54
DC
NL
1
0:
7:
00
32
Peak
RO 1.78 5
3.28 7,581
7,581
IKoir™. 3_<-l-N«n
.01
.59 5,808.44
.59
Vi / H1 ft— lY*«n-»«rih^Vn»n Vr>
0.735-1.265
0
1,773.15 1
11 nun
.000
.004 2-Cl-Haph
IS2
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitals Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 14:27 08/21/97
159
-------
Page No.
08/21/97
Listing of O972702B.db«
Matched OC Peaks / Ratio
/ Ret. Tim*
Compound/
M_2.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Confound.Name.. ID.. Flags.
dl 0 - Acenaph then
0.735-1.265
164
164
Fluorene
166
166
d7-2-Cl-Naph
169-171
DC NL 0:00
8:46
DC HH 13:52
1 Peak
&1
DC NL 0:00
9:44
10:03
10:26
10:55
11:15
11:20
11:50
12:20
8 Peaks
DC NL 0:00
4.59
13,214.60
30.75
13,214.60
aovej dlO-Acenaphthen /
14.57
105.96
9,342.41
115.93
185.73
90.40
1,351.75
894.09
160.66
12,246.93
2.S2-3.54
RO 4.31 5.93
13,214.60
105.96
9,342.41
115.93
185.73
90.40
1,351.75
894.09
160.66
dT™2~Cl'~Nfl.ptl Pol lows ™ "
0.000
1.169 dlO-Acen
1.849
0.678-1.000
0.000
0.787
0.813 Fluorene
0.844
0.383
0.910
0.916
0.957
0.997
0.735-1.265
0.000
169-171
7:30 3.34
1 Peak
5,247.73
5,247.73
4,038.83
1,208.90 1.000 d7-2-Cl-Naph
I S3
Phenan
178
DC NL 0
9
10:
11
11
11.
11;
11:
11:
11:
12:
:00
:10
:55
:05
:15
:20
:25
:29
:40
:50
:26
12:34
178
dlO- Phenan
188
188
12:
13:
13:
40
40
:52
14 Peaks
!: O/-.6-' — L-nap
20
415
421
855
199
382
345
151
310
238
14,783
10,604
165
342
168
29,385
a t n
.92
.93
.45
.54
.45
.85
.65
.54
.10
.17
.40
.50
.55
.92
.80
.85
zenaci rojLj.ows
0.195-1.805
0.000
415
421
855
199
382
345
151
310
238
14,783
10,604
165
342
168
.93
.45
.54
.45
.85
.65
.54
.10
.17
.40
.50
.55
.92
.80
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
1.
1.
1.
1.
741
883
896
910
916
923
929
943
957
OO5 Phenan
016 Anth
024
105
121
AN
AN
0.195-1.805
DC NL 0:
12:
12:
00
22
31
2 Peaks
2
10,533
8.059
18.593
.59
.70
.94
.64
10,533
8,059
.70
.94
0.
1.
1.
000
000 dlO-Phenan
012 dlO-Anth
IS4
ALTS
Triangle Laboratories, Inc.® Analytical Services Division
801 Cap'rtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 14:27 08/21/97
160
-------
Page No.
08/21/97
Listing of U972702B.dbf
Hatched GC Peaks / Ratio
/ Rat. Tina
Compound/
M_2.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
Pluoran
202 DC
202
dlO- Fluor an
212 DC
212
B-a-Anth
228 DC
228
d!2 -B-a-Anth
240 DC
240
B-b-Fluoran
252 DC
252
d!2 -B-b-Fluoran
264 DC
NL 0:00
15:30
16:06
19:19
19:25
4 Peaks
ML 0:00
15:27
16:03
19:14
19:20
4 Peaks
NL 0:00
15:28
16:09
16:57
19:19
19:25
5 Peaks
NL 0:00
17:50
19:14
19:20
3 Peaks
NL 0:00
20:42
23:23
23:30
24:44
25:00
25:27
6 Peaks
NL 0:00
23:15
23:25
98.72
14,870.90
14,275.10
266.46
363.82
29,776.28
9.63
11,264.30
13,489.40
321.86
335.79
25,411.35
10.71
120.34
153.65
23.69
3,536.26
3 , 847 . 64
7,682.08
5.12
51.91
2,526.39
2,348.07
4,926.37
13.58
35.38
2,387.48
2,593.83
1,975.04
1,560.54
1,424.07
9,976.34
3.50
4,314.58
4,241.28
14,370.90
14,275.10
266.46
363 . 32
11,264.30
13,489.40
321.86
335.79
120.84
153.65
23.69
3,536.26
3,847.64
51.91
2,526.39
2,348.07
B~D—FiUOIT3Jl Follows "••"
35.38
2,387.48
2,593.83
1,975.04
1,560.54
1,424.07
4,314.58
4,241.28
0.354-1.646
0.000
1.003 Pluoran
1 . 042 Pyrene
1.250
1.257
0.290-1.646
0.000
1.000 dlO-Fluoran
1.039 dlO-Pyrene
1.245
1.251
0.481-1.519
0.000
0.804
0.840
0.381
1.004 B-a-Anth
1 . 010 Chrysene
0.481-1.519
0.000
0.927
1.000 d!2-B-a-Anth
1.005 dl2-Chry.sene
O.S06-1.394
o .'ooo
0.818
0.924 B-b-Fluoran
0.929 B-k-Fluoran
0.978 B-e-Pyrene
0.988 B-a-Pyrene
1 . 006 Perylene
0.606-1.394
0.000
0.919 d!2 -B-b-Fluoran
0.926 d!2-B-k-Fluoran
AN
AN
IS5
RS2
AN
AN
IS6
isio
AN
AN
AN
AN
AN
isll
is!2
Triangle Laboratories, Inc.® Analytical Services Division
801 Capftola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 14:27 08/21/97
161
-------
Page No.
08/21/97
Listing of O972702B.dbf
Hatched CC Peaks / Ratio / Rat. Tima
Compound/
H_Z.... QC.Log omit Why . .RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Conpound.Hane.. ID.. Flags.
264
I-123-cd-Py
276 DC
276
DiB-ah-Anth
278 DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
278
d!2-I-123-cd-Py
288 DC
DC
DC
DC
DC
23:52
24:35
24:52
25:18
6 Peaks
57
1,526
2,335
2,508
.42
.14
.30
.23
57
1,526
2,335
2,508
14,982.95
NL 0:00
26:30
26:57
29:18
29:42
31:30
32:32
32:48
34:04
34:46
9 Peaks
NL 0:00
WL 20:26
WL 21:43
WL 22:21
WL 22:32
WL 22:34
WL 24:01
WL 25:35
WL 26:01
WL 26:14
WL 26:54
31:20
31:46
32:21
32:49
33:58
WH 34:43
5 Peaks
NL 0:00
WL 20:51
WL 21:28
WL 21:51
WL 22:31
28:45
7
5
6
3
7
11
481
241
17
544
1,313
4
29
9
10
7
3
5
5
3
5
6
8
2
5
474
2
5
493
4
27
21
8
11
8
.27
.41
.14
.12
.73
.23
.64
.01
.19
.86
.33
. . / nJ T
.57
.73
.25
.17
.47
.47
.16
.15
.41
.03
.63
.06
.85
.58
.60
.80
.74
.89
Vi / A~\ f
n / QAJ
.69
.10
.69
.56
.01
.93
5
6
3
7
11
481
241
17
544
a_ =ih — 2n^
9~o£l~*mw.
8
2
5
474
2
> — T— 1 *) "i —
6 A A A J
8
.42
.14
.30
.23
Jf S O A A WWB»
.41
.14
.12
.73
.23
.64
.01
.19
.86
U S\J A A t/W5»
.06
.85
.58
.60
.30
.93
0
0
0
1
0.711
0
0
0
0
0
0
0
0
0
1
.943
.972 dl2-B-e-Pyrene
.983 dl2-B-a-Pyrene
.000 d!2-Perylene
-1.289
.000
.768
.781
.849
.861
.913
.943 I-123-cd-Py
.951
.987
.008 B-ghi-Pery
RS3
ial3
137
AN
AN
0.939-1.061
0
0
0
0
0
0
0
0
0
0
0
0
0
0
1
1
1
0.711
0
0
0
0
0
0
.000
.628
.668
.687
.693
.694
.738
.786
.800
.806
.827
.963
.976
.994
.009 DiB-ah-Anth
.044
.067
-1.289
.000
.604
.622
.633
.653
.333
AN
PR
Triangle Laboratories, Inc.® Analytical Services Division
801 Capftoia Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 14:27 08/21/97
16
2
-------
Page No.
08/21/97
Listing of U972702B.dbf
Matched OC Peaks / Ratio / Rat. Tim*
Compound/
M_Z QC.Log Omit Why ..RT. OK Ratio Total.Ar*a.
.. Area.Peak.1.. Area.Peak.2.. Rel.HT Compound.Name.. ID.. Flags.
288
30:32
31:43
32:19
33:48
34:30
6 Peaks
7.16
24.77
997.00
22.57
967.31
2.027.74
7.16
24.77
997.00
22.57
967.31
0.885
0.919
0.937 d!2-I-123-cd-Py is!4 I
0.980
1.000 d!2-B-ghi-Pery IS8
Above: d!2-I-123-cd-Py / dl4-DiB-ah-Anth Follows
dl4-DiB-ah-Anth
292 DC
DC
292
NL
WL
0:00
28:45
31:25
32:32
2 Peaks
2.26
7.34
4.42
716.65
721.07
4.42
716.65
.939-1.306
0.000
0.884
0.966
1.000 d!4-DiB-ah-Anth IS9
Column Description "Why" Code Description QC Log Desc.
M_Z -Nominal Ion Mass(es)
. .RT. -Retention Time (mm:ss)
Rat.l -Ratio of M/M+2 Ions
WL-Below Retention Time Window
WH-Above Retention Time Window
SN-Below Signal to Noise Level
OK
-RO=Ratio Outside Limits
-------
Pilt
128.
TRI1
1001
80.
60.
40.
20.
0
5:
Pilt
136.
TRIA
IOCS
80.
60.
40.
201
0'
5:
Pilt
142.
TRIA
1003
801
601
401
20.
0'
5s
File
152.
TRIA
1003
801
601
401
201
5:
File
154.
TRIA^
801
60.
40.
201
01
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-------
CALIBRATION
DATA
Triangle Laboratories, Inc.
801 Capitola Drive ' P.O. Box 13485
Durham, NC 27713-4411 Research Triangle Park, NC 27709-3485
919-544-5729 Fax #919-544-5491
o
172
-------
Date: 08/13/97
TRIANGLE LABORATORIES OF RTF, INC.
Continuing Calibration for U972690
Operator
Init Calibration.
ICal Data
Analyte Summary
Name
Naph
2-Me-Naph
Acenaph
Acenaphthen
2-Cl-Naph
Pluorene
Phenan
Anth
Pluoran
Pyrene
B-a-Anth
Chrysene
B-b-Fluoran
B-k-Fluoran
B-e-Pyrene
B-a-Pyrene
Perylene
I-123-cd-Py
B-ghi-Pery
DiB-ah-Anth
• BB
: CTPJ8127
• 08/12/97
RF Ratio
1&2
1.288
1.489
1.237
0.710
1.595 3.22
1.093
1.364
1.176
1.430
1.413
1.352
1.237
1.197
1.200
1.889
1.493
1. 193
1.052
1.191
1.119
Instrument.
Std.Cone
. : CT
ICal
RT
Lo/High
3:23
7:23
4:30
8:30
6:28
10:28
5:33
9:33
8:25
12:25
2:25
22:25
5:29
25:29
9:17
29:17
15:23
35:23
24:37
44:37
30:38
34:38
Page 1
RT
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16
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24
25
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26
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29
53
35
:06
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:37
:33
:08
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-.35
:49
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:31
:39
-.52
:54
Rel. RT
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R?
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1
1
1
1
1
1
1
1
1
1
1
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1
.174
.250
.185
.630
.402
.184
.326
.123
.447
.484
.383
.336
.244
.307
.828
.459
.151
.164
.294
.569
100.
Delta
RP
0.114
0.239
0.052
0.080
0.193
-0.091
0.038
0.053
-0.017
-0.071
-0.031
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0.061
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00
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-1.
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-7.
-3.
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3.
2.
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7%
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3%
4%
6%
6%
9%
7%
Triangle Laboratories, Inc.® AnalyticaJ Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed:
13/97
-------
DaCe: 08/13/97
TRIANGLE LABORATORIES OP RTF, INC.
Continuing Calibration Cor U972690
Other Standard Suaroary
Name RF Ratio RT RT
1&2 Lo/Hign
dlQ-Fluorane 0.983
ICal
Rel. RT RF
Delta
RF
dlO-Anth O.S40
d!4-Terphenyl 0.517
Internal Standard Summary
Name RF Ratio..
1&2
d8-Naph 2. Ill
dlO-2-Me-Naph 0.929
d8-Acanaph 1.768
d7-2-Cl-Naph 0.713 3.37
dlO-Phenan 0.737
dlO-Fluoran 0.306
d!2-B-a-Anth 0.224
d!2-Chrysene 0.308
d!2-B-b-Fluoran 2.132
d!2-B-k-Fluoran 3.046
d!2-B-a-Pyrene 1.383
dl2-Perylene 1.684
d!2-I-123-cd-Py 0.338
d!2-B-ghi-Pery 0.429
d!4-DiB-ah-Anth 0.246
Recovery Standard Summary
Name RF Ratio
142
dl0-Acenaphthen 0.000
dlO-Pyrene 0.000
d!2-B-e-Pyrene 0.000
10:25 10:02 0.3081
19:25
12:33 1.0107
5:29 16:32 1.0678
17:29
0.994 -0.011 -1.1%
0.605 0.035 5.7%
0.441 0.076 17.1%
ICal
RT RT Rel. RT RF
Lo/High
0:23 5:23 1.0000
7:23
0:01 6:30 1.0000
16:30
0:01 3:28 1.0000
10:28
5:33 7:33 1.0000
Delta
RF
%D
9:33
2:25 12:25 1.0000
22:25
4:29 15:29 1.0000
25:29
9:17 19:17 1.0000
29:17
19:23 1.0052
23:20 0.9192
23:28 0.9245
24:57 0.9829
15:23 25:23 1.0000
35:23
32:25 0.9364
24:37 34:37 1.0000
44:37
30:38 32:38 1.0000
42:38
1.807 0.304 16.8%
1.089 -0.160 -14.7%
1.542 0.226 14.7%
1.133 -0.415 -36.6%
0.698 0.039 5.6%
0.785 0.021 2.7%
0.208 0.016 7.6%
0.256 0.052 20.2%
2.368 -0.236 -10.0%
2.386 0.160 5.5%
1.440 -0.057 -4.0%
1.893 -0.209 -11.0%
0.473 -0.135 -28.6%
0.605 -0.176 -29.0%
0.271 -0.025 -9.0%
RT RT
Lo/High
5:33 8:48 1.1656
9:33
16:05 1.0388
ICal
Rel. RT RF
Delta
RF
%D
1.000 -1.000 100.0%
1.000 -1.000 100.0%
24:39 0.9711 1.000 -1.000 100.0%
Page
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 * Fax: (919) 544-5491
Printed: 00:18 08/13/97
174
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Date: 08/13/97 TRIANGLE LABORATORIES OF RTP, INC.
Continuing Calibration for U972690
Page
Triangle Laboratories, Inc.® Analytical Services Division
801 Capftoia Drive • Durham, North Carolina 27713 Printed: 00:18 08/13/97
Phone: (919) 544-5729 • Fax: (919) 544-5491
-------
TECHNICAL REPORT DATA
(Please read Instructions on reverse before completing)
1. REPORT NO. 2.
EPA- 454/R-99-042b
4. TITLE AND SUBTITLE
Integrated Iron and Steel Industry Final Report Manual Testing
Volume II of HI
LTV Steel Company Indiana Harbor Works East Chicago, Illinois
7. AUTHORS)
EMAD
9. PERFORMING ORGANIZATION NAME AND ADDRESS
U.S. Environmental Protection Agency
Office of Air Quality Planning and Standards
Research Triangle Park, NC 27711
12. SPONSORING AGENCY NAME AND ADDRESS
Director
Office of Air Quality Planning and Standards
Office of Air and Radiation
U.S. Environmental Protection Agency
Research Triangle Park, NC 27711
3. RECIPIENT'S ACCESSION NO.
5. REPORT DATE
August 1999
6. PERFORMING ORGANIZATION CODE
8. PERFORMING ORGANIZATION REPORT NO.
10. PROGRAM ELEMENT NO.
1 1 . CONTRACT/GRANT NO.
68-D7-0068
13. TYPE OF REPORT AND PERIOD COVERED
Final
14. SPONSORING AGENCY CODE
EPA/200/04
15. SUPPLEMENTARY NOTES
16. ABSTRACT Integrated iron and steel manufacturing is among the categories of major sources for
which national emission standards for hazardous air pollutants (NESHAPS) are to be issued by
November 2000 pursuant to Section 112 of the Clean Air Act. The integrated iron and steel
manufacturing category includes mills that produce steel from iron ore. Key processes and unit
operations include sinter production, iron production, steel making, continuous casting, and the
preparation of semi-finished and finished products. Source tests are required to quantify and
hazardous air pollutant (HAP) emissions, and the performance of a sintenng plant equipped with
characterize the paniculate matter (PM), a venruri scrubber.
17 KEY WORDS AND DOCUMENT ANALYSIS
a. DESCRIPTORS
Paniculate Matter, Dioxin/Furan, PAH, Metals
18. DISTRIBUTION STATEMENT
Release Unlimited
b. IDENTIFIERS/OPEN ENDED TERMS
19. SECURITY CLASS (Report)
Unclassified
20 SECURITY CLASS (Page)
Unclassified
c. COSATI Field/Group
21. NO. OF PAGES
636
22. PRICE
EPA Form 2220-1 (Rev. 4-77) PREVIOUS EDITION IS OBSOLETE
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TRIANGLE LABORATORIES 2F RTF, INC.
Initial Calibration Summary for OPJS127
Data: 08/13/97
Instrument •
Analytas
Naph
2 -Me -Naph
Acenaph
Acenaphthen
2-Cl-Naph
Pluorene
Phenan
Anth
Fluoran
Pyrene
B-a-Anth
Chrysene
B-b-Fluoran
B-k-Fluoran
B-e- Pyrene
B-a- Pyrene
Perylene
I-123-cd-Py
B-ghi-Pery
DiB-ah-Anth
Other Standards
dlO- Fluor ene
dlO-Anth
d!4-Terphenyl
Internal Standards
d8-Naph
dlO-2-Me-Naph
d8- Acenaph
d7-2-Cl-Naph
dlO- Phenan
dlO-Fluoran
d!2-B-a-Anth
dl 2 -Chrys ene
d!2-B-b-Fluoran
dl2-3->c-Fluoran
dl2-3-a-Pyrene
dl 2 -Perylene
d!2- 1-123 -cd-Py
d!2-B-ghi-Pery
d!4-DiB-ah-Anth
Recovery Standards
dl 0 -Acenaphthen
V 1
u
J f ±**
f *•
RF
1.174
1.250
1.
0
1.
1.
.185
.630
.402
.184
1.326
1.123
1.447
1.484
1.
1.
1.
1.
.383
,336
.244
307
1.828
1.
1.
1.
1.
1.
459
151
262
294
587
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
RF
0.
0.
0.
994
605
441
0
0
0
RF
1.
1.
1.
1.
0.
0.
0.
0.
2.
2.
1.
1.
0.
0.
0.
807
089
542
133
698
785
208
256
368
386
440
893
437
605
271
0
0.
0
3D
.078
.143
.050
.086
.135
.161
.108
.099
.057
.051
.112
.075
.083
.093
.151
.133
.090
.102
.069
.339
3D
.121
.052
.044
3D
.182
.114
.150
0.240
0.
.071
0.014
0.
0.
.022
.033
0.680
0.623
0.077
0.
0.
0.
0.
RF
1.
000
0.
233
115
168
080
3D
000
%RSD
7%
11%
4%
14%
10%
14%
3%
9%
4%
3%
3%
6%
7%
7%
3%
9%
3%
8%
5%
21%
%RSD
12%
9%
10%
%RSD
10%
10%
10%
21%
10%
2%
11%
13%
29%
22%
5%
15%
26%
23%
30%
%RSD
0%
Page
RT
5:25
6:35
3:28
8:47
7:34
10:04
12:27
12:35
15:31
16:07
19:20
19:26
23:24
23:32
24:45
25:02
25:23
32:34
34:48
32:51
RT
10:00
12:22
16:31
RT
5:22
6:32
8:27
7:31
12:23
15:28
19:15
19:21
23 : 17
23:26
24:54
25:20
32:21
34:33
32:34
RT
8:47
1
RT/LO
3:22
4:32
6:27
5:31
8:23
2:23
5:28
9:15
15:20
24:33
30:34
RT/LO
10:23
5:28
RT/LO
0:22
0:01
0:01
5:31
2:23
4:28
9:15
15:20
24:33
30:34
RT/LO
5:31
RT/HI
7:22
8:32
10:27
9:31
12:23
22:23
25:28
29:15
35:20
44:33
34:34
RT/HI
19:23
17:28
RT/HI
7:22
16:32
10:27
9:31
22:23
25:28
29 : 15
35:20
44:33
42:34
RT/HI
9:31
PAHJ
Ratiol Ratio2
3.173
Ratiol Ratio2
Ratiol Ratioa
3.162
N
5
5
5
5
S
5
5
5
5
5
5
5
5
5
5
S
S
5
5
5
N
5
5
5
Ratiol
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
Ratio2 N
5
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 00:16 08/13/97
176
-------
TRIANGLE LABORATORIES OF RTF, INC. Data: 08/13/97
Initial Calibration Summary for UPJ8127
dlO-Pyrene 1.000 0.000 0% 16:04 5
dl2-B-e-Pyrene 1.000 0.000 0% 24:36 5
*** End of Report **»
Page
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitoia Drive » Durham, North Carolina 27713 Printed: 00:16 08/13/97
Phone: (919) 544-5729 • Fax: (919) 544-5491 1 ^ -,
I !' I
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