c/EPA
              United States
              Environmental Protection
              Agency
              Office of Solid Waste
              and Emergency Response
              (OS-110)
EPA-500-B-92-006
October 1992
Ground-Water Modeling

Compendium
Model Fact Sheets, Descriptions, Applications
and Assessment Framework
                       OSWER Information Management
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         Purpose of This Compendium
  The Ground-Water Modeling Compendium increases the reader's
  awareness of ground-water models and modeling in general. The
  Compendium also provides a convenient source of information on
  overseeing modeling projects.

  The Compendium provides an Assessment Framework for planning
  and assessing modeling applications, summary descriptions of
  model applications that were used to test the Assessment Framework |
  and summary and detailed descriptions of four ground-water
  models.

  The use of this Compendium by technical support staff and remedial
  project managers will help to promote the appropriate use of models
  and therefore sound and defensible modeling within the hazardous
  waste/Superfund programs.
Who May Benefit From This Compendium
  This Compendium is intended for use by:
              • Technical Support Staff
              • Remedial Project Managers
  This Compendium may also help:
            • OSWER and Regional Management
            • EPA Contractors
            • Other Consultants
                             U.S. Environmental Protection Agency
                             ?5g,!°n 5, Library (PL-12J)
                             77 West Jackson Bpulevard, 12th
                             Chicago, IL 60604-3590

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                     Table of Contents
Section 1.0 • Introduction
       Introduction	1-1
Section 2.0 • Assessment Framework for Ground-Water Model
             Applications
       Introduction	2-1
       Assessment Criteria	2-2
       Footnotes	2-15
       Glossary of Technical Terms	2-17
       EPA Publications Related to Ground-Water Modeling	2-24
Section 3.0 - Model Applications
       Introduction	3-1
       Summary Description #1	3-3
       Summary Description #2	3-11
       Summary Description #3	3-25
       Summary Description #4	3-39
Section 4.0 • Model Descriptions
       Introduction	4-1
       Model Fact Sheets	4-3
       Detailed Model Descriptions	4a
             MOC	4a-l
             MODFLOW	4b-l
             PLASM	4c-l
             RANDOM WALK	4d-l

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1.0 • Introduction

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1.0

                             Introduction


Background

    This Ground-Water Modeling Compendium has been prepared as part of the
Models Management Initiative being conducted by EPA's Office of Solid Waste and
Emergency Response (OSWER). OSWER's Resource Management and Information
Staff (RMIS) is directing this effort in order to promote improved usage of
environmental models — initially focusing on hazardous waste/Superfund
programs, and in the future, supporting Agency-wide efforts.

Objective and Intended Use

      During FY 1991-92, OSWER has been conducting a pilot project on ground-
water modeling with the primary objective of providing useful information on
existing modeling practices and models to EPA staff, contractors, and the regulated
community.  OSWER recognizes that ground-water models are being used in a
variety of ways and under different circumstances and constraints. Models can be
used to guide and complement field investigations, thereby improving the
understanding of the consequences of site-specific hydrogeologic conditions.
However, models should not be used in lieu of field investigations and care must be
taken to ensure  that models are not misused. The intention of this Compendium is
to:

    O   promote the appropriate use of models by increasing users' awareness
         about  the strengths, weaknesses and inherent uncertainties associated
         with ground-water models and modeling in general; and

    O   support model users and decision-makers by providing a convenient
         source of information on how to oversee modeling projects, how certain
         models have been applied in the context of hazardous waste/Superfund
         programs, and the characteristics of four specific ground-water models.

      The contents of the Compendium have been reviewed extensively by ground-
water modeling  experts both within and external to EPA.  OSWER recommends this
document as a reference source for promoting sound and defensible modeling
methods and approaches.  This document does not, however, constitute official EPA
guidance, nor should it be construed as an endorsement of specific models.

Organization  and  Structure

    The Compendium is organized into four distinct sections designed to meet the
needs of various audiences, including project/site managers, technical reviewers,
and model users. The four sections of the Compendium are:
                                                                  Page 1-1

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Section 1s  Introduction
    O   1.0, this section, is the Introduction describing the Compendium's
         purpose and organization.

    G   2.0, Assessment Framework for Ground-Water Model Applications,
         provides a framework for planning and assessing model applications.  The
         framework is organized into eight categories (e.g., Project Management,
         Model Setup and Input Estimation).  Each category contains a series of
         criteria that can be used to assess a model application after the fact (i.e., by
         using existing documentation and the knowledge of  the participants to
         determine how actual modeling practices compare to the criteria), or to
         guide a team in an ongoing or future application (i.e., by conducting the
         project in the manner indicated by the criteria). This framework has been
         developed  by the pilot project team in conjunction with recognized
         modeling experts. Also included in Section 2.0 are footnotes for some of
         the criteria, a glossary of technical terms, and a list of potential sources of
         information on EPA modeling guidance.

    CJ   3.0, Model Applications, provides summary descriptions of the model
         applications used to test the assessment framework.  These tests were
         performed to gain insight into the effectiveness of the assessment
         framework in different modeling situations.  Each description discusses
         the decision objective, regulatory context, site characteristics (e.g., geology,
         ground-water contamination), modeling activities and results, interesting
         features of the application, and the names of EPA staff to contact for more
         details. This section is intended to help readers understand the variety of
         modeling applications used to test the assessment framework.

    O   4.0, Model Descriptions, provides summary and  detailed descriptions for
         the four selected models. The summary descriptions are contained on a
         series of Fact Sheets, each of which is a double-sided encapsulation of the
         important characteristics of the model and sources of additional
         information.  The detailed model information contained in the latter part
         of the section includes names of the developers, names and addresses of
         the custodian, technical features, and solution methods.  This  information
         has been extracted from a database of ground-water models developed and
         maintained by the International Ground Water Modeling Center
         (IGWMC).

Future Plans

    This Compendium  may be expanded as additional information is collected,
analyzed, and organized. This edition focuses on ground-water modeling, reflecting
the scope of the OSWER pilot project.  Later editions could be expanded or modified
in order to:

    CJ   enhance the  assessment framework;

    O   include case studies of model applications that illustrate both appropriate
         and less appropriate modeling methodologies;
Page 1-2

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Section 1:  Introduction
     G   include summary and detailed descriptions for additional models;

     G   address other modeling domains; and

     O   modify the format or contents to meet specific requests for information.

     If you have any comments about this edition or would like to identify sources
of additional information, please contact Mary Lou Melley at OSWER/RMIS (202-
260-6860).

Acknowledgements

     The OSWER Pilot Project has benefitted since its inception from input by a
team of ground-water modeling experts that includes Dr. Mary Anderson,
University of Wisconsin, Dr. Paul van der Heijde, International Ground Water
Modeling Center, and Dr. Luanne Vanderpool, EPA Region V. These individuals
were instrumental in developing the assessment framework provided in Section 2
of the Compendium, and their insights led to many improvements in the other
sections.

     Darcy Campbell and Jon Lutz, of Region Vm, contributed to the contents of the
"EPA Publications Related to Ground-Water Modeling" in Section 2.0.

     A committee, representing model users in the EPA Regional offices, in
OSWER, and other program offices, has been serving as a review group and
providing suggestions for the Compendium. Its members include:

               Office of Solid Waste and Emergency Response
              David Bartenfelder
              Randall Breeden
              Dorothy Canter
              Matthew Charskey
              Lynn Deering
           Subijoy Dutta
           Loren Henning
           Tony Jover
           Zubair Saleem
           Richard  Steimle
              Richard Willey
              Allison Barry
              Fred Luckey
              Nancy Cichowicz
              Mike Arnett
 Region I


 Region II



Region III


Region IV
Christos Tsiamis
                                                                   Page 1-3

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Section 1:  Introduction
                                 Region VI
              Shawn Ghose                Michael Hebert
                                Region VII
              Mary Bitney
                                Region VIII
              Darcy Campbell
                                 Region IX
              Richard Freitas
                                 Region X
              Glenn Bruck
                    Office of Research and Development
              Bob Ambrose                 Will LaVeille*
              David Burden                Ron Wilhelm
              Carl Enfield                  Darwin Wright*
              Amy  Mills*
                         Office of Air and Radiation
              Robert Dyer*                 Kung-Wei Yeh*
              Joe Tikvart*
                              Office of Water
              Marilyn Ginsberg*
                Office of Information Resources Management
              Dwight Clay*
    * Ex-Officio Members
Page 1-4

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Section 2.0 - Assessment Framework for
   Ground-Water Model Applications

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2.O

Assessment  Framework for Ground-Water  Model Applications


Introduction

    This section provides a framework for assessing ground-water model
applications. The framework contains a series of assessment criteria, grouped into
eight categories:

    CJ   Modeling Application Objectives

    G   Project Management
    O   Conceptual Model Development
    O   Model (code) Selection
    G   Model Setup and Input Estimation
    O   Simulation of Scenarios
    O   Post Simulation Analysis
    O   Overall Effectiveness.

    The objective of the assessment framework is to support the use of models as
took for aiding decision-making under conditions of uncertainty. A manager,
reviewer, or modeler can use these criteria to assess modeling work that has already
been performed, or they can use the criteria to guide a current or future effort.
These criteria cover a wide range of conceivable technical and management issues
that might be encountered in a variety of modeling applications.  For certain types of
problems, some of the criteria may not be applicable. For the more complex
modeling applications, some criteria may have to be modified or expanded.

    The criteria address the activities and  thought processes that should be part of a
modeling application and the subsequent documentation of that activity or process.
Consequently, some of the following criteria are preceded with an asterisk "*"
indicating that the analysis, the process, or the data referred to in the question
should be documented to assure the defensibility of the modeling application.

    Some of the criteria are followed  by footnotes referencing other sources of
information.  The criteria also contain numerous technical terms that may require
additional explanation. These terms are italicized the first time they appear. A
glossary that follows the criteria contains the definitions for these terms in the
context in which they are used  in the criteria.  In other contexts, alternative
definitions of these terms may be more appropriate.
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Section 2*  A*»0ssm*nt Frmmowork                        Assessment Criteria


Assessment Criteria

Modeling Application Objectives

1  n  *Management's decision objectives and the modeling objectives should be
       clearly specified up-front.

2  D  *Management's decision objectives should be based upon existing
       information about the physical characteristics of the site (e.g., hydrogeologic
       system) and the source and location of the contamination.

3  n  The function of the model (e.g., data organization, understanding the
       system, planning additional field characterization or  evaluation of
       remediation alternatives) should be defined  during the development of the
       modeling objectives.

4  n  The potential solutions to be evaluated (e.g., containment and remediation
       solutions) should be identified prior to the initiation of the modeling.

5  D  The level of analysis required (e.g., numerical model, analytical model or
       graphical techniques) should be determined  during the definition of the
       modeling objectives.

6  D  'Management, in consultation with a  professional  ground-water scientist,
       should specify the time period (e.g., one year, ten years or hundreds of years)
       for which model predictions are required.

7  D  The level of confidence (quantitative or qualitative) required of the
       modeling results should be specified.

8  D  Performance targets (e.g., allowable head error) for the model application
       should be specified up-front.

9  D  *An analysis should be performed of the incremental costs associated with
       expanding these study objectives (e.g., expanding the size of the study area,
       the number of remedial technologies modeled or the performance targets of
       the model) and the consequent incremental  improvement in supporting
       management's decision objectives.

10 D  Management's decision objectives should be reaffirmed throughout the
       modeling  process.

11 D  The modeling objectives should be reviewed,  after the development of the
       conceptual model and prior to the initiation  of the  modeling, to ensure that
       they support management's decision objectives.

12 D  The level of analysis required should be reviewed during the course of the
       project and if necessary modified.

13 D  The function of the model should be reviewed  during the course of the
       project and if necessary modified.
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Sect/on 2r Am*»»»m0nt Frmmowork                         Assessment Criteria

Project Management

14 D  The individuals who are actually performing the modeling, managing the
       modeling effort and performing the peer review should have the ground-
       water modeling experience required for the project. Specifically, for their
       role on the project, each should have the appropriate level of:
            •  Formal training in modeling and hydrogeology
            •  Work experience modeling physical systems
            •  Field experience characterizing site hydrogeology
            •  Modeling  project management experience.

15 D  These individuals should be organized as a cohesive modeling team with
       well defined  roles, responsibilities and level of participation.

16 D  The organization  of the team should be appropriate for the application.

17 D  *An independent  quality assurance (QA) process should be established at
       the beginning of the project.

18 D  This QA process should include ongoing peer review of the:
            •  Modeling  objectives development
            •  Conceptual model development
            •  Model code selection
            •  Model setup and calibration
            •  Simulation of scenarios
            •  Post simulation analysis.

19 D  This QA process should be implemented.

20 D  A procedure should be established up front for documenting the model
       application.

21 D  The documentation should include a discussion of the:
            •  General  setting of the site
            •  Physical systems of interest
            •  Potential solutions to be evaluated
            •  Modeling objectives and time frame for model predictions
            •  Quality assurance and peer review process
            •  Composition of the modeling team
           •  Data sources and data quality
           •  Conceptual  model
                 —  Hydrostratigraphy
                 -  Ground-water flow system
                 -  Hydrologic boundaries
                 —  Hydraulic properties
                 -  Sources and sinks
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Sect/on 2*  Assessment Framework                         Assessment Criteria

                 —  Contaminant source, loading and areal extent
                 —  Contaminant transport and transformation processes
            • Selection of the computer code
                 —  Description of the code
                 -  Reliability
                 -  Usability
                 —  Transportability
                 —  Performance
                 -  Public Domain vs. Proprietary Models
                 —  Limitations
                 —  Related  Applications
            • Ground-water model construction
                 -  Code modifications
                 -  Model grid
                 —  Hydraulic parameters
                 —  Boundary conditions
                 —  Simplifying Assumptions
            • Calibration, sensitivity analysis, and verification
            • Predictive simulations
                 -  Scenarios
                 —  Implementation of the scenarios
                 -  Discussion of the results of each run
            • Uncertainty analysis
            • Discussion of results related to management's information needs as
              formulated in the decision objectives
            • Executive summary (in terms of the decision objectives)
            • References
            • Input and output files.

        See Footnote 1.

22  D   The documentation should provide the information required for an
        independent reviewer  to complete a  post application assessment.
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Section 2t  A**0**m0nt Framework                         Assessment Criteria

Conceptual Model Development

23 D  An initial conceptual model of both the local and regional hydrogeological
       system should be developed prior to any computer modeling.

24 D  The conceptual model should be based upon a quantification of field data
       as well as other qualitative data  that includes information on the:
            •  Aquifer system (Distribution and configuration of aquifer and
              aquitard units)
                  —  Thickness and continuity of relevant units
                  —  Areal extent
                  -  Interconnections between units
            •  Hydrologic boundaries
                  —  Physical extent of  the aquifer system
                  —  Hydrologic features that impact or control the ground-water
                     system
                       -   Ground-water divides
                       -   Surface water bodies
            •  Hydraulic properties (Including, where relevant, homogeneous and
              isotropic characteristics)
                  —  Transmissivity
                  —  Porosity
                  —  Hydraulic conductivity
                  —  Storativity
                  —  Specific yield
            •  Sources and Sinks
                  -  Recharge to the aquifer (e.g., Infiltration)
                  —  Evapotranspiration
                  —  Drains
                  -  Ground-water discharges (e.g., flow to surface water bodies)
                  -  Wells  (e.g., water supply, injection or irrigation wells)
            •  Fluid Potential (i.e., the potentiometric  surface, the magnitude and
              direction of the hydraulic gradient within each model layer)
            •  Contaminant
                  —  Source
                  -  Loading
                  — Areal extent
                  — Physical properties
                  - Chemical interactions
                  — Biotransformations
            •  Soils.

       See Footnote 2.
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Section 2s  Assessment Framework                         Assessment Criteria


25 D  *The quantity, quality and completeness of the field data should be analyzed
       as part of the development of the conceptual model.

26 D  If there are data gaps (e.g., missing water level or hydraulic conductivity
       information), additional field work and other attempts to fill in these gaps
       should be documented.

27 D  *If there are data gaps, the tradeoff should be analyzed between the cost of
       acquiring additional data and the consequent improvement in meeting
       management's decision objectives.

28 D  The data sources should be documented.

29 D  The quality of the data should be examined and documented and the
       influence of their quality on the project's results should be assessed.

30 D  *Any and all potential interactions with other physical systems (e.g., surface
       water systems or agricultural systems) should be evaluated, prior to the
       beginning of the modeling, by means of a water budget, a chemical mass
       balance or other analytical techniques.

31 D  The manner in which existing and future engineering (e.g., wells or  slurry
       walls) must be represented in the numeric or analytic model should  be
       explicitly incorporated into the conceptual model.

32 D  Sufficient contaminant sources should be identified to account for the
       contaminant mass in  the plume.

33 D  *A clear statement of the location, type and state of the boundary conditions;
       justification of their formulation; and the source(s) of information on the
       boundary conditions should be included as part of the conceptual model.

34 D  *A11 conceptual model parameters and reasonable parameter ranges should
       be specified prior to beginning the calibration of the numerical model.
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Section 2t Assessment Framework                        Assessment Criteria

Model (code) Selection

35  D   The selected model (code) should be described with regard to its flow and
        transport processes, mathematics, hydrogeologic system representation,
        boundary conditions and input parameters.

36  D   The reliability of the model (code) should be assessed including a review of:
            • Peer reviews of the model's theory (e.g., a formal review process by
              an individual or organization acknowledged for their expertise in
              ground-water modeling or the publication of the theory in a peer-
              reviewed journal)
            • Peer reviews of the model's code (e.g., a formal review process by an
              individual or organization acknowledged for their expertise in
              assessing ground-water computer models)
            • Verification studies (e.g., evaluation of the model results against
              laboratory tests, analytical solutions or other well accepted models)
            • Relevant field tests (i.e., the application and evaluation of the model
              to site specific conditions for which extensive data sets are available)
            • The model's (code) acceptability in the user community as evidenced
              by the quantity and type of use.

37  D   The usability of the model (code) should be  assessed including the
        availability of:
            • The model binary code
            • The model source code
            • Pre and post processors
            • Existing data resources
            • Standardized data formats
            • Complete user instruction manuals
            • Sample problems
            • Necessary hardware
            • Transportability across platforms
            • User support.

38  D   The tradeoff should be analyzed between model (code) performance (e.g.,
        accuracy and processing speed) and the human and computer resources
        required to perform the modeling.

39  D   The model (code) should be in the public domain or at least readily
       accessible to all interested parties. If not, the  modelers should explain how
       the inaccessibility would not detract from the study objectives and the
       regulatory process.

40  D  The assumptions in the model (code) should be analyzed with regard to
       their impact upon the modeling objectives.
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Sectfon 2r  A*»09*mont Framaworfc                         Assessment Criteria


41   D *Any and all discrepancies between the modeling requirements (i.e., as
       indicated by the decision objectives, conceptual model and available data)
       and the capabilities of the selected model should be identified and justified.
       The modelers should explain why the modeling objectives and/or the
       conceptual model did or did not need to be modified. For example, the
       implications of the selected code supporting one, two or three dimensional
       modeling; providing steady versus unsteady state modeling; or requiring
       simplifications of the conceptual model should be discussed.
                                    *
42 D  *If the modeling objectives are modified due to  such discrepancies, those
       modifications should be documented.

43 n  *If the model source code is modified, the following tests should be
       performed and the testing methodology and results should be justified:
            • Reliability testing (See criteria #36)
            • Usability evaluation (See criteria #37)
            • Performance testing.

       See Footnote 3.
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Sect/on 2t  A*90**m0nt Framework                         Assessment Criteria

Model Setup And Input Estimation

44 n  The overall grid resolution (e.g., average spacing of 100 feet versus 1000
       feet) should be analyzed with respect to the dependent variable accuracy
       required to meet management's objectives.  For example, the grid should be
       fine enough to allow the hydraulic gradient to be accurately represented.

       See Footnote 7.

45 D  The finite element or finite difference grid design should be analyzed with
       respect to the modeling objectives such as the need to locate or model wells,
       existing and future engineering or contaminant sources and plumes.

       See Footnote 7.

46 D  The grid should be designed with respect to the physical system.  For
       example:
            • The main grid orientation should be aligned with the principal
             directions of hydraulic conductivity and/or transmissivity.
            • A finer grid should be used in areas where results are needed (e.g., in
             the area of highest pollution or drawdown) or areas having large:
                 — Changes in transmissivity
                 - Changes in hydraulic head
                 - Concentration gradients
            • A coarser grid should be used where data are scarce and for those
             parts of the study area that are not of particular interest.

       See Footnotes 4 and 7.

47 D  The grid spacing and time step size should be analyzed with respect to
       numerical accuracy. For example:
            • If a finite difference model with variable grid spacing was used the
             grid should be expanded towards distant boundaries by less than a
             factor of 2.
            • If a finite  element model was used the following should be analyzed
             with regard to their impact on the numerical accuracy of the model
             application:
                 - Length to width ratio of  each element
                 — Size difference between neighboring elements
                 - The Peclet number (Pe = v • AX/D).
           • The Courant number (Cr = v • At/AX) should be < 1
                   Where:
                      D = Dispersion Coefficient (!2/t)
                      At=Time Step
                      V = Velocity (1/t)
                      AX = Grid spacing (1).
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Sect/on 2s Assessment Framework                         Assessment Criteria

            • If Random Walk particle tracking was used the grid spacing and
              particle mass should be analyzed with respect to the contaminant
              resolution required.

        See Footnotes 5 and 7.

48 D   The mapping of the location of the boundary conditions on the grid should
        be evaluated.  For example:
            • The boundaries should be located far enough away from the areas of
              interest to dampen any instability in the model.
            • The manner in which  the boundaries are represented in the grid
              should ensure the fineness of the grid, the accuracy of the geometry
              and the accuracy of the boundary conditions.
            • For finite element grids, internal and external boundaries should
              coincide  with element boundaries.

        See Footnotes 6 and 7.

49 D   Well nodes should be located near the physical location of the wells.

50 D   *The data sources, the data collection procedures and the data uncertainty
        for the model input data should be evaluated and documented in the
        project report or file.

51 D   *A11 model inputs should be defined as to whether they are measurements,
        estimates or assumptions including:
            • The constitutive coefficients and parameters (i.e., parameters that are not
              generally observable but must be inferred from observations of other
              variables, for example the distribution of transmissivity and specific
              storage)
            • The forcing terms (e.g.,  sources and sinks of water and dissolved
              contaminants)
            • The boundary conditions
            • The initial conditions.

52 D   The input estimation process  whereby data are converted into model inputs
        (e.g.,  spatial and temporal interpolation and extrapolation or Kriging) should
        be described and the spatial location and the associated values of the data
        used  to perform the interpolation should be shown on a map or provided
        in a table.

        See Footnote  7.

53 D   The uncertainty  associated with the input estimation process should be
        specified, explained and documented.

54 D   The model should be calibrated.
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Section 2s  Assessment Framework	           Assessment Criteria
55 D  *If the model is not calibrated, the reasoning for not calibrating the model
       should be explained.

56 D  The criteria being used to terminate the calibration process (i.e., the
       definition of an adequate match between observed and modeled values)
       should be justified with regard to the modeling objectives.

       See Footnote 7.

57 D  "The calibration should be performed in a generally acceptable manner.
       Specifically:
            • A sensitivity analysis should be performed to determine the key
              parameters and boundary conditions to be investigated during
              calibration.
            • The calibration should include a calculation of residuals between
              simulated and measured values.
            • The calibration should include an evaluation of both spatial and
              temporal residuals.
            • The calibration should be performed in the context of the physical
              features (e.g., were residuals analyzed with respect to the pattern of
              ground-water contours including mounds or depressions or
              indications of surface water discharge or recharge).

       See Footnote 8.

58 D  If a water budget is developed, the results and their use in calibrating the
       model should be explained.

59 D  *A11 changes in initial model parameter values due to calibration should  be
       justified as to their reasonableness.

60 D  *Any discrepancies between the calibrated model parameters and the
       parameter ranges estimated in the conceptual model should be justified.

61 D  *If the conceptual model is modified as a result of the model calibration, all
       changes in the conceptual model should be justified.  Whenever feasible,
       the calibrated model  should be verified with an independent set  of field
       observations.
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Section 2r  Assessment Framework                         Assessment Criteria

Simulation Of Scenarios

62 D  *F°r each modeling scenario, the model inputs and the location of features
       in the model grid should be justified.  For example:

            •  If a pumping well was not located at a node, the allocation of well
              discharges among neighboring nodes should be justified.
            •  If a slurry wall is a remedial alternative, the representation in the
              model of the  wall's geometric and hydraulic properties should be
              justified.
            •  If cleanup times are calculated, all assumptions about the location,
              quantity and  state of the contaminants should be justified.
            •  When a remedial action, such as extraction wells, affects the flow,
              such effects should be determined, including the downgradient
              distance to the stagnation point and the lateral reach of each
              modeled extraction well.
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Section 2r  Assessment Framework                         Assessment Criteria

Post Simulation Analysis

63 D  The success of the model application in simulating the site scenarios
       should be assessed.

64 n  This assessment should include an analysis of:
            • Whether the modeling simulations were realistic
            • Whether the simulations accurately reflected the scenarios
            • Whether the hydrogeologic system was accurately simulated
            • Which aspects of the conceptual model were successfully modeled.

65 D  The sensitivity of the model  results to uncertainties in site specific
       parameters and the level of error in the model calibration should be
       examined and quantified. For example the modeling scenarios should be
       simulated for the range of possible values of the more sensitive
       hydrogeologic parameters.  Moreover, the range of error in the model
       calibration should be considered when drawing conclusions about the
       model results.

66 D  The post-processing should be analyzed to ensure that it accurately
       represents the modeling  results and interpolation and smoothing methods
       should be documented where appropriate.

67 D  The post-processing results should be analyzed to ensure that they support
       the modeling objectives.

68 D  The final presentation should effectively and accurately communicate the
       modeling results.

69 D  When feasible, a post audit of the model should be carried out or planned for
       in the future.

       See Footnote 9.
                                                                   Page 2-13

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Section 2r  Assessment Framework                        Assessment Criteria

Overall Effectiveness

70 D  *Any difficulties encountered in the model application should be
       documented.

71 D  The model application should provide the information being sought by
       management for decision making.

       See Footnote 10.

72 D  The model application results should be acceptable to all relevant parties.

73 D  The model application should support a timely and effective regulatory
       decision.

74 n  Those aspects of the modeling effort that in hindsight might have been
       done differently should be documented.
Page 2-14

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Section 2r  Assessment Frmmework                                  Footnotes
Footnotes

1.   For more information on documentation see the Draft ASTM Standard Section
    D-18.21.10, "Guide for Application of a Ground-Water Flow Model to a Site-
    Specific Problem" and "Standards For Mathematical Modeling of Ground
    Water Flow and Contaminant Transport at Hazardous Waste Sites," Chapter 4
    of Volume 2 of Scientific and Technical Standards For Hazardous Waste Sites -
    Draft. Department of Health Services, State of California.

2.   For more information on data requirements for conceptual model
    development see the Draft ASTM Standard Section D-18.21.10, "Guide for
    Application of a Ground-Water Flow Model to a Site-Specific Problem;"
    "Standards For Mathematical Modeling of Ground Water Flow and
    Contaminant Transport at Hazardous Waste Sites," Chapter 4 of Volume 2 of
    Scientific and Technical Standards For Hazardous Waste Sites - Draft.
    Department of Health Services, State of California, pg. 4; Ground  Water
    Models. Scientific and Regulatory Applications, Committee on Ground-Water
    Modeling Assessment, National Research Council, National Academy of
    Sciences, 1990, pgs. 221 - 230; and Applied Ground Water Modeling:  Simulation
    Of Flow And Advective Transport.  Anderson, M. and  Woessner, W. W.,
    Academic Press, 1992.

3.   For more information on the testing of model codes see Groundwater
    Modeling: An Overview and  Status  Report, van der Heijde, P. K., El-Kadi, A. I.
    and Williams, S. A., International Ground Water Modeling Center, Colorado
    School of Mines, Golden, Colorado, 1988, pgs. 27 - 33; and "Testing and
    Validation of Ground Water Models," van der Heijde, P. K., Huyakorn, P.S.
    and Mercer, J.W., Proceedings. NWWA/IGWMC Conference on Practical
    Applications of Groundwater Models. Columbus, Ohio, August 19-20, 1985,
    National Water Well Association, Dublin, Ohio.

4.   For more information on the design  of the grid  see Groundwater  Modeling: An
    Overview and Status Report, van der Heijde, P. K., El-Kadi, A. I. and Williams,
    S. A., International Ground Water Modeling Center, Colorado School of Mines,
    Golden, Colorado, 1988, pgs. 45-48 and Applied Ground Water Modeling:
    Simulation Of Flow And Advective Transport. Anderson,  M. and Woessner
    W. W., Academic Press, 1992.

5.   For information on  how grid design and  time step size  can affect  the numerical
    accuracy of a model see  Computational Methods in Subsurface Flow.
    Huyakorn, P. S. and Pinder, G. F., Academic Press, New York, New York, 1983,
    pgs. 206 and 392; Groundwater Modeling: An Overview and Status Report, van
    der Heijde, P. K.,  El-Kadi, A. I. and Williams, S. A., International Ground
    Water Modeling Center, Colorado School of Mines, Golden, Colorado, 1988,
    pgs. 45 - 48; and Applied Ground Water Modeling; Simulation Of  Flow And
    Advective Transport. Anderson, M.  and Woessner, W.  W., Academic Press,
    1992.
                                                                  Page 2-15

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Section 2t  Assessment Framework                                  Footnotes
6.   For information on properly locating and representing boundary conditions see
    Definition of Boundary and Initial Conditions in the Analysis of Saturated
    Ground-Water Flow Systems - An Introduction, Franke, O. L., T. E. Reilly and
    G. D. Bennett, Open-File Report 84-458, U. S. Geological Survey, Reston,
    Virginia, 1984; and Applied Ground Water Modeling; Simulation Of Flow And
    Advective Transport. Anderson, M. and Woessner, W. W., Academic Press,
    1992.

7.   For information on model setup, input estimation and criteria for the
    termination of the calibration process see: Applied Ground Water Modeling;
    Simulation Of Flow And Advective Transport. Anderson, M. and Woessner,
    W. W., Academic Press, 1992.

8.   For more information on the calibration of ground-water models see: Applied
    Ground Water Modeling; Simulation Of Flow And Advective Transport.
    Anderson, M. and Woessner, W. W., Academic Press, 1992; Groundwater
    Modeling: An Overview and Status Report, van der Heijde, P. K., El-Kadi, A. I.
    and  Williams, S. A., International Ground Water Modeling Center, Colorado
    School of Mines, Golden, Colorado, 1988; Draft ASTM Standard Section D-
    18.21.10, "Standard Guide for Comparing Ground-Water Flow Model
    Simulations  to Site-Specific Information;" Subpart 6.5;  and "Standards For
    Mathematical Modeling of Ground Water Flow and Contaminant Transport at
    Hazardous Waste Sites," Chapter 4 of Volume 2 of Scientific and Technical
    Standards For Hazardous Waste Sites - Draft. Department of Health Services,
    State of California, Section 3.3.2.4.

9.   For more information on post audits see; "The Role of the Postaudit in Model
    Validation",  Anderson, M. P. and Woessner, W. W., submitted to Advances in
    Water Resources. October, 1991

10.  For more information on decision making under conditions of uncertainty see:
    "Hydrogeological Decision Analysis: 1. A Framework," Freeze,  R. A.,
    Massmann, J., Smith, L., Sperling,T. and James, B., Ground Water 1990, 28(5),
    738 - 766.
Page 2-16

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Section 2*  Assessment Framework                 Glossary of Technical Terms

Glossary of Technical Terms

      This glossary provides definitions for some of the technical terms used in
Section 2.0, Assessment Framework, of the Compendium of Modeling Information.
Words appearing in italics are defined elsewhere in the glossary. Numbers in
parentheses following each definition correspond to the reference source for the
definition. A complete list of references is included on the last page of the glossary.

    Analytical model - mathematical expression used to study the behavior of
    physical processes such as ground-water flow and contaminant transport. This type
    of model is generally more economical and  simpler than a numerical model,
    but it requires many simplifying assumptions regarding the geologic setting
    and hydrologic conditions.  In comparison with a numerical model, however,
    an analytical model provides an exact solution of the governing partial
    differential equation instead of an approximate solution. (9, 14)
    Aquitard - a geologic unit with low values of hydraulic conductivity which
    allows some movement of water through it,  but at rates of flow  lower than
    those of adjacent aquifers. An aquitard can  transmit significant quantities of
    water when viewed over a large area and long time periods, but  its
    permeability is not sufficient to justify production wells being placed in it. It
    may serve as a storage unit, but it does not yield water readily. (1,11,12,15)
    Boundary conditions - mathematical expressions specifying the dependent
    variable (head) or the derivative of the dependent variable (flux) along the
    boundaries of the problem domain.  To solve the  ground-water flow equation,
    specification of boundary conditions, along with the initial conditions is
    required. Ideally, the boundary of the model should correspond  with a physical
    boundary of the  ground-water flow system, such as an impermeable body of
    rock or a large body of surface water. Many  model applications,  however,
    require  the use of non-physical boundaries, such as ground-water divides and
    aquifer  underflow.  The  effect of non-physical boundaries on the modeling
    results must be tested.  (3)

    Calibration - a procedure for finding a set of parameters, boundary conditions,
    and stresses that produces simulated heads and fluxes that match field-
    measured values within a pre-established range of error. (3)
    Capture Zone - steady state: the region surrounding the well that contributes
    flow to the well and which extends up gradient to the ground-water divide of
    the drainage basin; travel time related: the region  surrounding a well that
    contributes flow  to the well  within a  specified period of time. (14)
    Conceptual model - an interpretation or working description of  the
    characteristics and dynamics of a physical system. The purpose of building a
    conceptual model is to simplify the field problem and organize the field data so
    the system can be analyzed more readily. (3,9)

    Constitutive coefficients and parameters - type of model input  that is not
    directly observable,  but, rather, must be inferred from observations of other
    model variables;  for example the distribution of transmissivity, specific storage,
    porosity, recharge, and evapotraspiration.  They are difficult to estimate because
                                                                   Page 2-17

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Section 2*  Assessment Frmmowork                  Glossary of Technical Terms

    they vary and can not be observed, particularly when field measurements are
    limited. (13)

    Containment - action(s) undertaken, such as constructing slurry trenches,
    installing diversionary booms, earth moving, plugging damaged tank cars, and
    using chemicals to restrain the spread of the substance, that focus on
    controlling the source of a discharge or release and minimizing the spread of
    the hazardous substance or its effects. (18)

    Contaminant source, loading and area! extent - the physical location of the
    source contaminating the aquifer, the rate at which the contaminant is entering
    the ground-water system, and the surface area of the contaminant source,
    respectively.  In order to model fate and transport of a contaminant, the
    characteristics of the contaminant source must be known or assumed. (2)

    Contaminant transformation - chemical changes and reactions that change the
    chemical properties of the contaminant. (2)

    Contaminant transport - flow and dispersion of contaminants dissolved in
    ground water in the subsurface environment. (13)
    Evapotranspiration - a combined term for water lost as vapor from a soil or
    open water surfaces, such as lakes and streams (evaporation) and water lost
    through the intervention of plants, mainly via the stomata (transpiration).
    Term is used because, in practice, it is difficult to distinguish water vapor from
    these two sources in water balance and atmospheric studies. Also known as fly-
    off, total evaporation and water loss. Losses from evapotranspiration can occur
    at the water table. (1,2)

    Field characterization - a review of historical, on- and off-site, as well as surface
    and sub-surface data, and the collection of new data to meet project objectives.
    When possible, aerial photographs,  contaminant source investigations, soil
    and aquifer sampling, and the delineation of aquifer  head and contaminant
    concentrations should be reviewed.  Field characterization is a necessary
    prerequisite to the development of a conceptual model. (2)
    Finite difference model - a type of numerical model that uses a  mathematical
    technique called finite-difference to obtain an approximate solution to the
    partial differential ground-water flow equation.  Aquifer heterogeneity is
    handled by dividing the aquifer into homogeneous rectangular blocks.  An
    algebraic equation is written for each block, leading to a set of equations which
    can be input  into a matrix and solved numerically.  This type of model has
    difficulty  incorporating irregular and uneven boundaries. (2,6,9,10)

    Finite element model - a type of numerical model that uses the finite-element
    technique to  obtain an approximate  solution to the partial differential ground-
    water flow equation. To handle aquifer heterogeneity, the aquifer can be
    divided into  irregular homogeneous elements, usually triangles. This type of
    model can incorporate irregular and curved boundaries, sloping soil, and rock
    layers more easily  than a finite difference model for some problem types. This
    technique, like finite-difference, leads to a set of simultaneous  algebraic
    equations which is input into a matrix and solved numerically. (2,6,9,10)
Page 2-18

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Section 2t  Assessment Framework                  glossary of Technical Terns

    Fluid potential - mechanical energy per unit mass of fluid at any given point
    in space and time with regard to an arbitrary state and datum. (6,16)
    Forcing terms - type of model input included in most ground-water models to
    account for sources and sinks of water or dissolved contaminants. They may be
    measured directly (e.g., where and when contaminants are introduced into the
    subsurface environment), inferred from measurements of more accessible
    variables, or they may be postulated (e.g., effect of proposed cleanup strategy).
    (13)

    Ground-water divides - ridges in the water table or potentiometric surface from
    which ground water moves away  in both directions (14); an imaginary
    impermeable boundary at the crest or valley bottom of a ground-water flow
    system across which there is no flow. (6)

    Ground-Water flow system - movement of water through, and the collective
    hydrodynamical and geochemical processes at work in, the interconnected
    voids in the phreatic zone (the zone of saturation). (1,16)

    Hydraulic conductivity - the ability of a rock, sediment, or soil to permit water
    to flow through it. The scientific definition is the volume of water at  the
    existing kinematic viscosity of the medium that will move in unit time under
    a unit hydraulic gradient through  a unit area measured at right angles to the
    direction of flow. (14)

    Hydraulic properties - those properties of a rock, sediment, or soil that govern
    the entrance of and the capacity to yield and transmit water (e.g., porosity,
    effective porosity, specific yield, and hydraulic conductivity). (2,22)

    Hydrologic boundaries - boundary conditions which relate to the flow of water
    in an aquifer system. (2)

    Hydrostratigraphy - a sequence of geologic units delimited on the basis of
    hydraulic properties. (5)

    Infiltration - flow of water downward from the land surface into and  through
    the upper soil layers. (5)

    Kriging - an interpolation procedure for estimating regional distributions of
    ground-water model inputs from scattered observations. (13)
    Model grid - a system of connected nodal points superimposed over the aquifer
    to spatially discretize the aquifer into cells (finite  difference method) or elements
    (finite element method) for the purpose of mathematically modeling the aquifer
    (21,22)                                                     °      n

    Model representation - a conceptual, mathematical or physical depiction of a
    field or laboratory system. A conceptual model describes the present condition
    of the system. To make predictions of future behavior, it is necessary to
    develop a dynamic model, such as physical scale models, analog models, or
    mathematical models. Laboratory  sand tanks simulate ground-water flow
    directly. The flow of ground water can be implied by using an electrical analog
    model. Mathematical models, including analytical, analytic  element, finite
    difference, and finite element models are more widely used because they are
    easier to develop and manipulate.  (3,5).
                                                                   Page 2-19

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Section 2i  Assessment Framework                  Glossary of Technical Terms

    Modeling objectives - the purpose of the model application. The objectives
    should direct model selection and level of effort for the modeling study. (2,3)
    Numerical model - a mathematical model that allows the user to let the
    controlling parameters vary in space and time, enabling detailed replications of
    the complex geologic and hydrologic conditions existing in the field.
    Numerical models require fewer restrictive assumptions, and are potentially
    more realistic and adaptable than analytical models, but provide only
    approximate solutions for the governing differential equations. (2,10,13)
    Peer review - a process by which a panel or individual is charged  to review and
    compare the results of modeling efforts and to assess the importance and
    nature of any differences which are present. The review may examine, for
    example, the scientific validity of the model, the mathematical code,
    hydrogeological/chemical/biological conceptualization, adequacy of data, and
    the application of the model to a specific site. (2,13)
    Performance target - a measure of model accuracy. (2)
    Performance testing - determining for the range of expected uses, the efficiency
    of the model in terms of the accuracy obtained versus the human and
    computer resources required  by comparing model results with predetermined
    benchmarks. (20)
    Porosity - total volume of void space divided by the  total volume of porous
    material.  The term, "effective porosity," is related.  It is the total  volume of
    interconnected void space divided by the total volume of porous material.
    Effective porosity is used to compute average linear ground-water velocity. (2,5)
    Post audit - comparison of model predictions to the actual outcome measured
    in the field. Used to determine the success of a model application as well as the
    acceptability of the model itself. (13)
    Potentiometric surface - a surface that represents the level to which water will
    rise in tightly cased wells. The water table is a particular potentiometric surface
    for an unconfined aquifer. (5)
    Reliability - the probability that a model will satisfactorily perform  its intended
    function under given circumstances. It is the amount of credence placed in  a
    result. (15)
     Remediation - long-term action that stops or substantially reduces and prevents
     future migration  of a release or threat of hazardous substances that  are a
     serious but not an immediate threat to public health, welfare, or the
     environment. (17)
     Residuals - the differences between field measurements at calibration points
    and simulated values. (8)
     Sensitivity analysis - process to identify the model inputs that have the most
    influence on model predictions, at least over a specified range. (2,13)
    Sources and Sinks  - gain or loss of  water or contaminants from the system.  In
    a ground-water flow system, typical examples are pumping or injection wells.
    (2,13)
 Page 2-20

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Section 2r Assessment Framework                  Glossary of Technical Terms

    Specific yield - quantity of water that a unit volume of aquifer, after being
    saturated, will yield by gravity (expressed as a ratio or percentage of the volume
    of the aquifer).  (15)

    Storativity - volume of water given per unit horizontal area of an aquifer and
    per unit decline of the water table or potentiometric surface. Also known as
    storage coefficient. (1,6)

    Surface water bodies - all bodies of water on the surface of the earth. (15)
    Transmissivity - the rate at which ground-water of a prevailing density and
    viscosity is transmitted through a unit width of an aquifer or confining bed
    under a unit hydraulic gradient. It is a function of the properties of the liquid,
    porous media, and the thickness of the porous media.  Often expressed as the
    product of the hydraulic  conductivity and the full saturated thickness of the
    aquifer. (1,14)

    Uncertainty analysis -  the quantification of uncertainty in the spatially
    distributed values of input hydraulic properties within an  aquifer system. (7)

    Verification study - consists of the verification of governing equations
    through laboratory or field tests, the verification of model  code through
    comparison with other models  or analytical solutions, and the verification of
    the model  through tests independent of the model calibration data. (3,4,19)
                                                                     Page 2-21

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Section 2g Assessment Framework                 glossary of Technical Terms


Sources

Definitions are directly drawn from, and based upon the following sources:

1.   Allaby, Ailsa and Michael.  The Concise Oxford Dictionary of Earth Sciences.
    Oxford: Oxford University Press. 1990.

2.   Anderson, Mary P., based wholly or in part on written comments provided on
    the initial draft version of the glossary (May, 1992).

3.   Anderson, Mary P., and William W. Woessner.  Applied Groundwater Modeling -
    Simulation of Flow and Advective Transport. New York, Academic Press, Inc. 1992.

4.   Belgin, Milovan S. Testing, Verification, and Validation of Two-Dimensional Solute
    Transport Models,  International Ground Water Modeling Center, December,
    1987.

5.   Fetter, C.W.  Applied Hydrogeology - 2nd Edition  Columbus, Merrill Publishing
    Company, 1988.

6.   Freeze, R. Allen and John A. Cherry. Groundwater.  Englewood, New Jersey:
    Prentice-Hall. 1979.

7.   Freeze, Allen, Joel Massman, Leslie Smith, Tony Sperling, and Bruce James.
    Hydrogeological Decision Analysis, Ground Water, 1990, 28(5)

8.   Golden Software, Inc. Surfer Reference Manual  Golden Colorado.

9.   Istok, Jonathan. Groundwater Modeling by the Finite Element Method.
    Washington, D.C.: American Geophysical Union. 1989.

10. Javandel, Iraj, Christine Doughty, and Chin-Fu Tsang. Ground  Water Transport:
    Handbook of Mathematical Models. Washington, D.C.: American Geophysical
    Union. 1984.

11. Kruseman, G.P. and  N.A. de Ridder, Analysis and Evaluation of Pumping Test
    Data. The Netherlands,  International Institute for Land Reclamation and
    Improvement, 1990.

12. Lohman, S.W., Definitions of Selected Ground-Water Terms - Revisions and
    Conceptual Refinements, Geological Survey Water-Supply Paper 1988.  Washington,
    D.C.:  United States Government Printing Office, 1972.

13. National Research Council.  Ground Water Models, Scientific and Regulatory
    Applications.  Washington, D.C.:  National Academy Press.  1990.

14. The Ohio State University,  Department of Geological Sciences Capzone Users
    Manual, Columbus,  Ohio, September, 1991.
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Section 2r Assessment Framework                  Glossary of Technical Terms


15.   Parker, Sybil P. McGraw-Hill Dictionary of Scientific and Technical Terms, Fourth
     Edition.  New York:  McGraw-Hill Book Company. 1989.

16.   Subsurface-Water Glossary Working Group, Ground  Water Subcommittee,
     Interagency Advisory Committee on Water Data, Subsurface-Water and Solute
     Transport Federal Glossary of Selected Terms. August 1989.

17.   United States Environmental Protection Agency. Office of Public Affairs.
     Glossary of Environmental Terms and Acronym List. Washington, D.C.  August
     1988.

18.   United States Environmental Protection Agency. Technical Assistance Team
     (TAT) Contract Users Manual. Washington, D.C.  October 1981.

19.   van der Heijde, Paul, K.M. Quality Assurance and Quality Control in Groundwater
     Modeling. International Ground Water Modeling Center, November, 1989.

20.   van der Heijde, Paul, K.M.  Identification and  Compilation of Unsaturated/Vadose
     Zone Models Possibly Applicable  to Setting Soil Remediation Levels at Superfund Sites,
     Report to the EPA Kerr Lab, Ada, Oklahoma, Draft, July 1992.

21.   van der Heijde, Paul, K.M., Aly I. El-Kadi, and Stan A. Williams Groundwater
     Modeling: An Overview and Status Report   Indianapolis, Indiana, International
     Ground Water Modeling Center, December 1988.

22.   Wang, Herbert F. and Mary P.  Anderson. Introduction  to Groundwater Modeling,
     Finite Difference and Element Methods. San Francisco, California:  W.H. Freeman
     and Company.  1982.
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                                                    EPA Publications Related
Section 2t Assessment Framework                  to Ground-Water Modeling

EPA Publications Related to Ground-Water Modeling

                 CONTAMINANT FATE AND TRANSPORT

USEPA. Grove, D.B. and Rubin, J. 1976.  Transport and Reaction of Contaminants
    in Ground Water Systems, Proceedings of the National Conference on Disposal
    of Residues on Land. Office of Research and Development, pp. 174-178.

USEPA. 1989.  Determining Soil Response Action Levels Based on Potential
    Contaminant Migration to Ground Water: A Compendium of Examples.
    EPA/540/2-89/057.

USEPA. 1989.  Laboratory Investigations of Residual Liquid Organics from Spills,
    Leaks, and Disposal of Hazardous Wastes in Groundwater. EPA/600/6-90/004.

USEPA. Schmelling, Stephen, et al. 1989. Contaminant Transport in Fractured
    Media: Models for Decision Makers:  Superfund Ground Water Issue, Ada,
    Oklahoma.

USEPA. 1990.  Subsurface Contamination Reference Guide. EPA/540/2-90/Oil.

USEPA. 1990.  Groundwater, Volume I:  Ground Water and Contamination.
    EPA/625/6-90/016a.

                                 DNAPLs

USEPA. 1992.  OSWER Directive No. 9355.4-07. Estimating the Potential for
    Occurrence of DNAPL at Superfund  Sites.

USEPA. 1992.  OSWER Directive No. 9283.1-06.  Considerations in Ground Water
    Expediation at Superfund Sites and RCRA Facilities — Update.

USEPA. Dense Nonaqueous Phase Liquids - A Workshop Summary.

                     GROUND-WATER ISSUE PAPERS

USEPA. Puls, R.W., Barcelona, M.J. 1989. Ground Water Sampling for Metals
    Analysis. EPA/540/4-89/001.

USEPA. Lewis, T.Y.; Crockett, R.L.; Siegrist, R.L.; Zarrabi, K.  1991. Soil Sampling
    and Analysis for Volatile Organic Compounds.  EPA/450/4-91/001.

USEPA. Breckenridge, R.P.; Williams, J.R.; Keck, J.F. 1991. Characterizing Soils for
    Hazardous Waste Site Assessments. EPA/540/4-91 /003.

USEPA. Schmelling. S.G.; Ross, R.R.  1989.  Contaminant Transport in Fractured
    Media: Models for Decision Makers.  EPA/540/4-89/004.

USEPA. Huling, S.G. 1989. Facilitated Transport.  EPA/540/4-89/003.
 Page 2-24

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                                                    EPA Publications Related
Section 2t  A»*essment Framework                   to Ground-Water Modeling

USEPA. Piwoni, M.D.; Keeley, J.W. 1990. Basic Concepts of Contaminant Sorption
     at Hazardous Waste Sites.  EPA/540/4-90/053.

USEPA. Huling, S.G.; Weaver, J.W. 1991. Dense Nonaqueous Phase Liquids.
     EPA/540/4-91/002.

USEPA. Keely, JJF. 1989.  Performance Evaluations of Pump-and Treat
     Remediations.  EPA/540/4-89/005.

USEPA. Sims, J.L.; Suflita, J.M.; Russell, H.H. 1991.  Reductive Dehalogenation of
     Organic Contaminants in Soils and Ground Water.  EPA/540/4-90/054.

USEPA. RusseU, H.H.; Matthews, J.E.; Sewell, G.W.  1992. TCE Removal from
     Contaminated Soil and Ground Water. EPA/540/S-92/002.

USEPA. Palmer, C.D.; Fish, W. 1992.  Chemical Enhancements to Pump-and-Treat
     Remediation.  EPA/540/S-92/001.

USEPA. Sims, J.L.; Suflita, J.M.; Russell, H.H. 1992.  In-Situ Bioremediation of
     Contaminated  Ground Water. EPA/540/S-92/003.

USEPA. 1990. Colloidal-Facilitated Transport of Inorganic Contaminants in Ground
     Water: Part 1, Sampling.  EPA/600/M-90/023.

USEPA. Puls, R.W.; Powell, R.M.; Clark, D.A.; Paul, C.J.  1991. Facilitated Transport
     of Inorganic Contaminants in Ground Water:  Part  2, Colloidal Transport.
     EPA/600/M-91/040.

            GROUND-WATER MONITORING AND WELL DESIGN

USEPA. Denit, Jeffrey. 1990.  Appropriate Materials for Well Casing and Screens in
     RCRA Ground Water Monitoring Networks.

USEPA. Aller, L.; Bennett, T.W.; Hackett, G.; Denne, J.E.; Petty, R.J. 1990. Handbook
     of Suggested Practices for the Design and Installation of Ground Water
     Monitoring Wells. EPA/600/4-89/034.

USEPA. 1992.  Chapter Eleven of SW-846, Ground Water Monitoring. Office of
     Solid Wastes, Washington,  DC. Pre-Publication.

                             HYDROGEOLOGY

USEPA. 1985.  Issue Papers in Support of Groundwater Classification Guidelines.
     EPA/440/6-85/001.

USEPA. 1986.  Criteria for Identifying  Areas of Vulnerable Hydrogeology Under
    RCRA. Appendix D:  Development of Vulnerability Criteria Based  on Risk
    Assessments, Office of Solid Waste and Emergency  Response, Washington, DC.
                                                                 Page 2-25

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                                                    EPA Publications Related
Section 2r  Assessment Framework                   to Ground-Water Modeling

USEPA. 1990.  A New Approach and Methodologies for Characterizing the
    Hydrogeologic Properties of Aquifiers. EPA/600/2-90/002.

USEPA. Molz, F.J.; Oktay, G.; Melville, J.G. Auburn University. 1990.
    Measurement of Hydraulic Conductivity Distributions:  A Manual of Practice.

USEPA. 1990.  Ground Water, Volume H: Methodology. EPA/625/6-90/016b.

                                MODELING

USEPA. Pettyjohn, W.A., Kent, D.C., Prickett, T.A., LeGrand, H.E.  (No date.)
    Methods for the Prediction of Leachate Plume Migration and Mixing, Office of
    Research Laboratory, Cincinnati.

USEPA. Bond, R; Hwang, S.  1988. Selection Criteria for Mathematical Models Used
    in Exposure Assessments: Ground Water Models.  EPA/600/2-89/028.

USEPA. 1988.  OSWER Directive No. 9355.0-08. Modeling Remedial Actions at
    Uncontrolled Hazardous Waste Sites.

USEPA. Bear, J.; Geljin, M.; Ross, R. 1992.  Fundamentals of Ground Water
    Modeling for Decision Makers. EPA/540/S-92/005.

                                  RCRA

USEPA. 1984.  OSWER Directive No. 9504.01-84. Enforcing Groundwater
    Monitoring Requirements in RCRA Part B Permit Applications.

USEPA. 1984.  OSWER Directive No. 9481.06-84. Clarification of the Definition of
    Aquifer in 40 CFR 260.10.

USEPA. 1984.  OSWER Directive No. 9481.02-84. ACL Demonstrations, Risk Levels,
    and Subsurface Environment.

USEPA. 1985.  OSWER Directive No. 9481.02-85. Ground Water Monitoring Above
    the Uppermost  Aquifier.

USEPA. 1985.  OSWER Directive No. 9481.05-85. Indicator Parameters at Sanitary
    Landfills.

USEPA. 1985.  OSWER Directive No. 9931.1.  RCRA Ground Water Monitoring
    Compliance Order Guidance.

USEPA. 1985.  OSWER Directive No. 9476.02-85. RCRA Policies on Ground Water
    Quality at Closure.

USEPA. 1985.  OSWER Directive No. 99050.0.  Transmittal of the RCRA Ground
    Water Enforcement Strategy.
Page 2-26

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                                                    EPA Publications Related
 Sect/on 2»  Assessment Framework                  to Ground-Water Modeling

 USEPA. 1986. OSWER Directive No. 9950.2.  Final RCRA Comprehensive Ground
     Water Monitoring Evaluation (CME) and Guidance.

 USEPA. 1986. Leachate Plume Management. EPA/540/2-85/004.

 USEPA. 1987. OSWER Directive No. 9950.1.  RCRA Ground Water Monitoring
     Technical Enforcement Document.

 USEPA. 1987. OSWER Directive No. 9481.00-10.  Implementation Strategy for
     Alternate Concentration Levels.

 USEPA. 1988. OSWER Directive No. 9476.00-10.  Ground Water Monitoring at
     Clean Closing Surface Impoundment and Waste Pile Units.

 USEPA. 1988. OSWER Directive No. 9950.3. Operation and Maintenance
     Inspection Guide (RCRA) Ground Water Monitoring Systems.

                            RISK  ASSESSMENT

 USEPA. 1988. Bond, R; Hwang, S.  1988. Selection Criteria for Mathematical
     Models Used in Exposure Assessments: Ground Water Models. EPA/600/8-
     88/075.

 USEPA. 1988. Superfund Exposure Assessment Manual. EPA/540/I-88/001.

 USEPA. 1989. Risk Assessment Guidance for Superfund, Vol. I: Human Health
     Evaluation Manual. EPA/540/1-89/002.

 USEPA. 1989.  Risk Assessment Guidance for Superfund, Vol. II: Environmental
     Evaluation Manual. EPA/540/1-89/001.

                    SAMPLING AND DATA ANALYSIS

 Bauer, K.M.; Glauz, W.D.; Flora, J.D.  1984.  Methodologies  in Determining Trends
     in Water Quality Data.

 USEPA. 1986. NTIS No. PG-86-137-304.  Practical Guide for Ground Water
     Sampling.

 USEPA. 1987. OSWER Directive No. 9355.0-14. A Compendium of Superfund Field
     Operation Methods, Volumes 1 and 2.

USEPA. 1988.  Field Screening Methods Catalog: User's Guide.  EPA/540/2-88/005.

USEPA. 1989. Data Quality Objectives for Remedial Response Activities:
     Development Process.  EPA/540/G-87/003.

USEPA.  1991.  OSWER Directive No. 9355.4-04FS.  A Guide: Methods for
    Evaluating the Attainment of Clean-Up  Standards for Soils and Solid Media.
                                                                Page 2-27

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                                                    EPA Publications Related
Section 2s Assessment Framework                  to Ground-Water Modeling

USEPA. 1991.  OSWER Directive No. 9360.4-06.  Compendium of ERT Ground
    Water Sampling Procedures.

              REMEDIAL INVESTIGATION/FEASIBILITY STUDY

USEPA. 1988.  Guidance on Conducting Remediation Investigation and Feasibility
    Studies (RI/FS) Under CERCLA. EPA/540/G-89/004.

USEPA. 1988.  OSWER Directive No. 9283.1-02.  Guidance on Remedial Action for
    Contaminated Ground Water at Superfund Sites.

USEPA. 1989.  OSWER Directive No. 9355.4-03.  Considerations in Ground Water
    Remediation at Superfund Sites.

USEPA. 1989.  Example Scenario:  RI/FS Activities at a Site with Contaminated Soil
    and Ground Water.  EPA/540/G-87/004.

USEPA. 1989.  OSWER Directive No. 9835.8. Model Statement of Work for a
    Remedial Investigation and Feasibility Study Conducted by a Potentially
    Responsible Party.

USEPA. 1991.  Conducting Remedial Investigation/Feasibility Studies for CERCLA
    Municipal Landfill Sites.  Office of Emergency Remedial Response,
    Washington, DC.

USEPA. 1991.  OSWER Directive No. 9835.3-2a.  Model Administrative Order on
    Consent for Remedial Investigation/Feasibility Study.

USEPA. 1992.  Site Characterization for Subsurface Remediation. EPA/625/4-
    91/026.

                  REMEDIAL DESIGN/REMEDIAL ACTION

USEPA. 1986.  OSWER Directive 9355.0-4A. Superfund Remedial Design and
    Remedial Action Guidance.

USEPA. 1988.  OSWER Directive No. 9355.0-08.  Modeling Remedial Actions at
    Uncontrolled Hazardous Waste Sites.

USEPA. 1988.  OSWER Directive No. 9283.1-02.  Guidance on Remedial Action for
    Contaminated Ground Water at Superfund Sites.

USEPA. 1989.  OSWER Directive No. 9355.4-03.  Considerations in Ground Water
    Remediation at Superfund Sites

USEPA. 1990.  OSWER Directive No. 9355.0-27FS. A Guide to Selecting Superfund
    Remedial Actions.

USEPA. 1990.  Guidance on Expediting Remedial Design and Remedial Action.
    EPA/540/G-90/006.
Page 2-28

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                                                    EPA Publications Related
Section 2i Assessment Framework                  to Ground-Water Modeling

USEPA. 1990.  Guidance on EPA Oversight of Remedial Designs and Remedial
    Actions Performed by Potentially Responsible Parties. Interim Final.
    EPA/540/G-90/001.

USEPA. Ross, R. General Methods for Remedial Operations Performance
    Evaluations.

USEPA. 1990.  OSWER Directive No. 9355.4-01FS. Guide on Remedial Actions at
    Super-fund Sites with PCB Contamination.

USEPA. 1990.  OSWER Directive No. 9833.0-2b.  Model Unilateral Order for
    Remedial Design and Remedial Action.

USEPA. 1991.  OSWER Directive No. 9835.17. Model CERCLA RD/RA Consent
    Decree.

                           RECORD OF DECISION

USEPA. 1990.  OSWER Directive No. 9283.1-03. Suggested ROD Language for
    Various Ground Water Remediation Options.

USEPA. 1991.  OSWER Directive No. 9355.3-02FS-3. Guide to Developing
    Superfund No Action, Interim Action, and Contingency Remedy RODs.

USEPA. 1991.  OSWER Directive No. 9355.7-02.  Structure and Components of Five
    Year Reviews.

                         CLEAN-UP STANDARDS

USEPA. 1990.  OSWER Directive No. 9234.2-11FS. ARARs Q's and A's: State
    Ground Water Antidegradation Issues.

USEPA. 1990.  OSWER Directive No. 9234.2-09FS.  ARARs Q's and A's:  Compliance
    with Federal Water Quality Criteria.

USEPA. 1990.  OSWER Directive No. 9234.2-06FS. CERCLA Compliance with  Other
    Laws Manual: CERCLA Compliance with the Clean Water Act (CWA) and the
    Safe Drinking Water Act (SDWA).

USEPA. 1991.  OSWER Directive No. 9355.4-04FS. A Guide: Methods for
    Evaluating the Attainment of Cleanup Standards for Soil and Solid Media.

                    PUMP AND TREAT REMEDIATION

USEPA. 1989.  Evaluation of Ground Water Extraction Remedies, Volume I:
    Summary Report. EPA/540/2-89/054a.

USEPA. 1989.  Evaluation of Ground Water Extraction Remedies, Volume II:  Case
    Studies 1-19. EPA/540/2-89/054b.
                                                                 Page 2-29

-------
                                                    EPA Publications Related
Section 2r  Assessment Framework                  to ground-Water Modeling

USEPA. 1989.  Evaluation of Ground Water Extraction Remedies, Volume HI:
    General Site Data, Data Base Reports. EPA/540/289/054c.

USEPA. 1989,  OSWER Directive No. 9355.0-28.  Control of Air Emissions from
    Superfund Air Strippers at Superfund Ground Water Sites.

USEPA. Mercer, J.W.; Skipp, D.C; Giffin, D. 1990.  Basics of Pump and Treat
    Ground Water Remediation Technology.  EPA/600/8-90/003.

USEPA. 1990.  Saunders, G.L.  1990. Comparisons of Air Stripper Simulations and
    Field Performance Data.  EPA/450/1-90/002.

USEPA. 1989.  Forum on Innovative Hazardous Waste Treatment Technologies:
    Domestic and International. EPA/540/2-89/056.

USEPA. 1990.  OSWER Directive No. 9355.0-27FS.  A Guide to Selecting Superfund
    Remedial  Actions.

                          IN SITU REMEDIATION

Middleton, A.C.; Hiller, D.H. 1990.  In Situ Aeration of Ground Water:  A
    Technology Overview.

USEPA. 1990.  OSWER Directive No. 9355.0-27FS.  A Guide to Selecting Superfund
    Remedial  Actions.

USEPA. 1990.  Emerging Technologies:  Bio-Recovery Systems Removal and
    Recovery of Metal Ions from Ground Water. EPA/540/5-90/005a.

USEPA. 1989.  Forum on Innovative Hazardous Waste Treatment Technologies:
    Domestic and International. EPA/540/2-89/056.

                    LANDFILLS AND LAND DISPOSAL

USEPA. Kirkham, R.R., et al. 1986. Estimating Leachate Production from Closed
    Hazardous Waste Landfills. Project Summary, Cincinnati

USEPA. Mullen, H. and Taub, S.I.  1976. Tracing Leachate from Landfills, A
    Conceptual Approach, Proceedings of the National Conference on Disposal of
    Residues on Land.  Environmental Quality Symposium, Inc., pp. 121-126.

USEPA. 1990.  OSWER Directive No. 9481.00-11. Status of Contaminated Ground
    Water and Limitations on  Disposal and Reuse.

Federal Register, Part H, 40 CFR Parts 257 and 258, Wednesday, October 9, 1991.  Solid
    Waste Disposal Facility Criteria: Final Rule.

USEPA. 1989. NTISNo. PB91-921332/CCE.  Applicability of Land Disposal
    Restrictions to RCRA and  CERCLA Ground Water Treatment Reinjection,
    Superfund Management.


Page 2-30

-------
                                                    EPA Publications Related
 Section 2?  Assessment Framework                  to Ground-Water Modeling

 USEPA. 1991.  Conducting Remedial Investigation/Feasibility Studies for CERCLA
     Municipal Landfill Sites. Office of Emergency Remedial Response,
     Washington, DC.

            MISCELLANEOUS GROUND-WATER PUBLICATIONS

 USEPA. 1986.  Background Document Groundwater Screening Procedure. Office of
     Solid Waste.

 USEPA. 1990.  Continuous Release - Emergency Response Notification System and
     Priority Assessment Model:  Model Documentation, Office of Emergency and
     Remedial Response, Washington, DC.

 USEPA. 1991.  Protecting the Nation's Ground Water:  EPA's Strategy for the 1990s;
     The Final Report of the EPA Ground Water Quality Task Force. Office of the
     Administrator, Washington, DC.

 USEPA. 1990. ORD Ground Water Research Plan: Strategy for 1991 and  Beyond.
     EPA/9-90/042.

                        DRINKING WATER SUPPLY

 USEPA. 1988. Guidance on Providing Alternate Water Supplies. EPA/540/G-
     87/006.

                                CATALOGS

 USEPA. 1992. Catalog of Superfund Program Publications.  EPA/540/8-91/014.
To obtain these documents, contact the EPA Regional Libraries, the EPA Regional
Records Center, or the Center for Environmental Research Information
(513-569-7562)
                                                                Page 2-31

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Section 3.0 - Model Applications

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3.0

                      Model Applications


Introduction

      This section provides summary descriptions of the model applications
used to test the assessment framework.  These descriptions are presented to
help the reader understand the variety of model applications that the
framework was tested against. These descriptions are not intended to be
examples of the application of the framework but simply summaries of the
test cases.  Each description discusses the:

     O   Decision objective;

     O   Regulatory context;

     O   Site characteristics (e.g., geology, ground-water contamination);

     O   Modeling activities and results;

     G   Interesting features of the application; and

     G   Names of EPA staff to contact for more details about the test case.
                                                             Page 3-1

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Section 3t Model Applications                            Introduction
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Pago 3-2

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3.1 • Summary Description #1

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Section 3i  Model Applications                          Summary Description ft


3.1

                          Model  Applications

                      Summary Description #1


Decision Objective:

     This RCRA site was modeled to determine if the effects of a hydraulic barrier
and hydraulic head maintenance system would meet hydraulic gradient
performance standards set forth in a Consent Decree. This was an enforcement lead
site where contractors for the responsible party performed the modeling.  The
Region reviewed the modeling effort and results  to ensure that the site was
modeled as accurately as possible and that the model results indicated that the
proposed corrective action would meet the Consent Decree performance standards.

Background:

     The site is  located in an area of industrial, commercial and warehousing
operations on a peninsula in Baltimore Harbor. A significant portion of the
perimeter of the site abuts the harbor. Chromium ore was processed at the site from
1845 to 1985.  This was a waste intensive operation that generated large quantities of
process residuals containing soluble chromium. Historically, these process residuals
were used as fill material at the plant site and in  other areas around Baltimore
Harbor. (See Figure 3.1-1.)

     The contamination of soil and ground water with elevated levels of chromium
creates the potential for human and environmental exposure. The risk of such
exposure, although small, will potentially exist as long as  the site remains
uncontrolled. To  minimize  this risk of exposure, a combination of a low
permeability cap, a hydraulic barrier and ground-water extraction wells was
proposed as a containment strategy.

     Remedial investigation and subsequent ground-water modeling of this site
began in October 1985, with further site investigations occurring through 1989 as
potential remedial actions were evaluated and  the ground-water model was refined.
The ground-water modeling that is the focus of this case study began with the
refinement of the prior model  to increase modeling accuracy.  This work was
performed in 1989 and 1990.

Geologic Summary:

    The site is located within the Coastal Plain Physiographic Province, an area that
is characterized  by an unconsolidated  sediment wedge that thickens toward the
Atlantic coast. In  the vicinity of the site, coastal plain sediments are on the order of
70 ft thick. This site is underlain by artificial fills,  recent organic silty day deposited
in the harbor, Pleistocene sediments, lower Cretaceous sediments and bedrock.
                                                                    Page 3-3

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Section Si  Model Applications                          Summary Description *1


    The deepest geologic unit investigated consists of gneiss bedrock which is
composed of three distinct strata. The lowest stratum is weathered rock composed
of fine to medium grained gneiss that is often broken and fractured.  Overlaying this
lowest stratum is a second stratum with an average thickness of eighteen feet. This
stratum consists of fine to coarse sand within a white clay-silt matrix that includes a
high feldspar content and a fine to coarse sand containing trace to some silt with a
high biotite content. The upper bedrock stratum consists of clayey fine to coarse
sand and has an average thickness of ten feet.

    Overlaying the bedrock are Lower Cretaceous sediments which vary in
thickness from 12 to 40 feet. These sediments range from a silty white sand to white
sand and gravel to a white clayey silt. Blanketing the Lower Cretaceous sediments
are Pleistocene deposits composed of silty day, sand, gravel and cobbles which range
from 5 to 15 feet in thickness. Above the Pleistocene deposits black organic silty
clays and silty fine sand are found along the bulkhead margins of the site. The
organic silty clays have an average thickness of 20 feet and the silty fine sand varies
between 5 and 10 feet in thickness.

    The fill materials, which created the level surface on which the site facilities
were built, consist of silty sands, micaceous sandy silts and poorly to well graded
sands as well as construction debris, bricks and wood fragments. The fill material
occurs at every location across the site and can be as much as 30 feet thick.

Ground-Water Contamination Summary:

    The chromium contamination at the site was found to be present in two
ground-water yielding layers, one shallow, a water table aquifer, and one deep, a
regional aquifer system. The shallow ground water, which lies principally above the
low permeability silts near the site perimeter, flows radially off the site through the
bulkheads to the north, west and south.  The shallow ground-water contamination,
which occurs chiefly near major source areas was found to have chromium levels
from 0.01 mg/L to 14,500 mg/L.

    Deep ground-water contamination within the Cretaceous sands was also
highest near the source areas. Regionally, flow in the deep ground water originates
from the northwest of the site and flows towards the southeast.  Locally, the deep
ground water flows radially away from the central portion of the site, with localized
small  upward and downward flow gradients between the deep and shallow ground
water.

Modeling Summary:

    The U. S. Geological Survey's three dimensional flow code, MODFLOW, was
used to model this site in a steady state.  Six model layers, each of which was
constructed with variable thicknesses and bottom elevations, were used to simulate
the flow of ground water under the site. A 24 row by 24 column finite-difference
grid was constructed. (See Figure 3.1-2.) Grid cell dimensions varied between 75 and
150 feet with the smallest cells located directly over the study site. Boundary
conditions modeled included the flow directions and gradients of the water table
and regional aquifer systems, leakage from the harbor  and precipitation recharge.
Page 3-4

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Section 3i Model Applications                          Summary Description #1


Horizontal hydraulic conductivity was determined for each layer by averaging
hydraulic conductivities from field tests.  Vertical hydraulic conductivities were
initially assumed to equal the horizontal hydraulic conductivities and were adjusted
during calibration of the model.

     During the calibration of the model, water levels in the observation wells were
used as targets and compared to simulated water levels.  The hydraulic parameters
were adjusted to provide the best possible match between measured and calculated
heads at the calibration targets. Residual analysis was used to measure the
effectiveness of the calibration.  The residual sum of squares was equal to 32.6 ft2 and
the residual mean was 0.0053 ft.

     Additional field testing was performed to refine the calibration of the model.
Aquifer tests were used to improve hydraulic conductivity estimates.  Additional
piezometers were also installed to better understand hydraulic gradients.  The
model was then recalibrated with these new data.

     Three hydraulic barrier scenarios were evaluated through model simulations.
All scenarios assumed site closure with the emplacement of a low-permeability cap
over the entire site.  The first scenario simulated a "deep soil mixing" wall that
extended one foot into the uppermost stratum of the bedrock, a clayey fine to coarse
sand. This scenario was modeled in combination with ground-water extraction
wells and with perimeter trench drains placed at different depths.

     The second scenario simulated a shallow slurry wall that extended two feet into
the clayey silt stratum of the Lower Cretaceous sediments. This scenario was
modeled in combination with alternative configurations of ground-water extraction
wells and with perimeter trench drains placed at different depths.

     The third scenario simulated only ground-water extraction wells on the site.

Modeling Results Summary:

     Model simulations of the first scenario indicated that the use of a  deep
hydraulic barrier without pumping or trench drains would not meet the head
difference performance standards of the Consent Decree.  However, the use of 12
extraction wells pumping a total of 2100 gal/day in combination with the wall
would meet these performance standards. The model simulations also indicated
that perimeter drains in combination with the deep hydraulic barrier would meet
the performance standards. When drains were placed at -05 ft msl. and 0.0 ft msl.
the model simulations indicated that 13500 gal/day and 3500 gal/day of ground-
water extraction would occur respectively.

     Model simulations of the second scenario indicated that the shallow hydraulic
barrier without pumping or drains would not meet the head difference performance
standards  of the Consent Decree. Moreover, the modeling indicated that the use of
the shallow hydraulic barrier instead of the deep hydraulic barrier would require
significantly increased ground-water extraction. If twelve extraction wells were used
a total pumpage of 27500 gal/day would be needed.  If only eight wells were used,
the pumpage requirements would increase to 28,000 gal/day. If perimeter trench
                                                                    Page 3-5

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Section 3i  Model Applications                         Summary Description #1


drains were used in lieu of wells the ground-water extraction rate would vary
between 17,440 and 13,500 gal/day depending on the elevation of the drains.

    Model simulations of the third scenario indicated that the head difference
performance standards of the Consent Decree could be met by pumping alone with
no hydraulic barrier.  The total pumpage, however, required to meet the
performance standard would be 92,580 gal/day distributed over twelve extraction
wells.

    In summary, model simulations indicated that the Consent Decree hydraulic
head difference performance standards could be met by each of the three modeling
scenarios. The first scenario, a deep wall and pumping resulted in minimum
extraction rates. Pumping wells alone were able to meet the  performance standards;
however, in the absence of a hydraulic barrier, the amount of pumpage necessary to
maintain the performance standards was more than an order of magnitude greater
than that of the first scenario.

Strengths And Interesting Features Of This Application:

    In this case study, an existing model of a site was refined and recalibrated. The
refinement of the model reflected the need for increased simulation accuracy as the
regulatory process moved from site characterization, to technology screening, to the
design of a specific containment technology and management strategy.

    This modeling application was used to predict the performance of alternative
corrective actions and the impact of those alternatives upon the hydrogeologic
system.  It should be noted that the quantity and quality of site field data in this case
study are atypical of most sites. These data allowed the development of a model
with considerable hydrogeologic specificity.

    This application  provided the information necessary to justify the need for
both a slurry wall and ground-water pumping inside the wall. Originally the
responsible party had proposed just a slurry wall with no pumping. This study
demonstrated the problems with such an approach and the effectiveness of
combining the slurry wall with pumping. For example, this study dramatized that
required pumping rates varied by over an order of magnitude with and without the
slurry wall. Moreover, this study helped to determine the design capacity of a water
treatment system by determining the volume of ground-water extraction for each
scenario.

    This study demonstrated that the hydrogeologic system would be modified by
the proposed corrective action and provided a mechanism for predicting these
impacts.  The Region  noted  that they will monitor the effectiveness of the selected
corrective action and if necessary the corrective action and /or the model application
will be modified as additional information is gained. This type of review, often
called a post audit, is strongly encouraged by ground-water modeling experts.

    The calibration report provides an example of the use of residual analysis to
evaluate the model calibration.
    Areas that should be covered in model calibration documentation include:
Pag*

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Section 3s Model Applications                         Summary Description §1

      1.    Explicitly establishing and documenting a reasonable range of
           parameter values to be used in the calibration of the model;
      2.    Documenting the model residuals and the residual analysis;
      3.    Documenting the sensitivity of the model to variations in model
           parameters;
      4.    Documenting the impact of grid spacing and time step on the
           numerical accuracy of the model;
      5.    Documenting the criteria being used to terminate the calibration
           process; and
      6.    Documenting the evaluation of the spatial and temporal distribution
           of residuals.
Contacts:
    For further information about this ground-water study please contact:
      Joel Hennessy          Region 3          Tel. # (215) 597-7584
      Nancy Cichowicz       Regions          Tel.# (215)597-8118
Modeling Documents:
    Please contact the above people for specific modeling documents.
                                                                  Page 3-7

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Section 3*  Model Applications
Summary Description ft
                                   Figure 3.1-1



                                   Site Location
Page 3-3

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Section 3t Model Applications
                     Summary Description tl
          o
          CM
                                   Figure 3.1-2


                           Finite Difference Model Grid
                         \
                           J
                                 s
7
                                          \/
                                       Zi
                                     ^N
                 /\
                                                                a
                                                                  I



                                                                  I
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Section 3i Model Applications                       Summary Description
                 (THIS PAGE INTENTIONALLY LEFT BLANK.)
Page 3-10

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3.2 • Summary Description #2

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3.2

                            Model  Applications

                        Summary Description #2


Decision Objective:

     The United States Army's (Army) Aberdeen Proving Ground O-Field site was
modeled in the early phases of a site investigation to assist in screening corrective
actions for the site. Specifically, the objective of the modeling was to:

      1.    Provide a framework for the characterization of contaminant releases
            and plumes;
      2.    Determine if contamination was migrating to other aquifers or
            surrounding surface water bodies; and
      3.    Predict the probable hydrologic and chemical effects of relevant
            remedial actions.
     This modeling was performed as a requirement of a RCRA permit that EPA
issued to the U.S. Department of Army. In turn, the U.S. Army Environmental
Management Office of the Aberdeen Proving Ground contracted with the U. S.
Geological Survey (USGS) to conduct the modeling that is the focus of this case
study. The EPA Region reviewed the modeling results to ensure that the site was
modeled as accurately as possible and that the above decision objectives were met.

Background:

     O-Field site is a 259 acre area located within the 79,000 acre Aberdeen Proving
Ground Army installation and is surrounded by Army testing ranges.  O-Field lies
on a neck that extends into the Chesapeake Bay and is directly bordered on the west
by the Gunpowder River and on the north and east by a tributary of the Gunpowder
River, Watson Creek. (See Figures  3.2-1 and  3.2-2.) Watson Creek,  which is better
described as a pond, discharges into the Gunpowder River through a man-made
culvert that restricts tidal flushing and therefore causes high organic loading in the
creek. To the south of O-Field lie other Army testing ranges. The site topography is
relatively flat with the highest elevation being about 19 feet above sea  level.

     O-Field includes two sub areas, Old O-Field and New O-Field.  Old O-Field was
periodically used from the late 1930's into the 1950's for the disposal of munitions
and chemical-warfare agents.  Disposal at New O-Field began in 1950 and continued
for an unspecified period. Disposal materials at New O-Field included ordnance,
contaminated material, laboratory quantities  of chemical-warfare agents and dead
animals. The primary activity  in later years at New O-Field was the destruction of
material by burning.

     At both New and Old O-Field, containerized and uncontainerized material was
disposed in unlined and uncovered trenches, pits and directly on the ground.
Beginning in 1949, sporadic cleanup efforts were initiated with the goal of destroying
                                                                   Page 3-11

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Section 3i  Model Applications	Summary Description *2


some of the explosives.  Periodically during the cleanup operations, explosions
raptured container casings and directly exposed contaminants. Today, most of the
pits and trenches have been covered with soil.

     In 1976, the Army recommended an assessment of the Aberdeen Proving
Ground to determine the potential for off-post migration of chemical contaminants.
Observation wells installed at O-Field in 1978 showed the presence of arsenic and
chlorinated organic solvents in the ground water. Analysis of surface water and soil
samples indicated that the ground water was transporting arsenic into Watson
Creek.  A limited resampling of ground and surface water in 1984 confirmed these
findings.

     An observation well network was developed in 1985 when eleven existing
wells were supplemented with 21 additional wells installed at eight locations. All
well drilling was performed using a remote control drill, bombproof shelters and
other extraordinary safety and security procedures due to the possibility of
encountering buried ordnance or chemical-warfare agents.  An additional five wells
were installed in 1987 when quarterly sampling indicated the possibility that
contaminants might be present beyond the area covered by the original observation
well network.

Geologic Summary:

     O-Field is located on unconsolidated sand, clay and silt of the Atlantic Coastal
Plain. Beneath the Coastal Plain sediments lies a basement complex of Precambrian
to Paleozoic crystalline rocks and Mesozoic rift-basin sedimentary rocks.  The depth
to the pre-Cretaceous basement rocks at O-Field is approximately 650 feet.

     The site hydrogeology was investigated to only a 200 hundred foot depth
because of the difficulties associated with  remote drilling operations and the
improbability that contamination had extended to this depth. Four aquifers were
discovered but only the upper three were  investigated.  These three consisted of a
water table aquifer and two confined aquifers with the lowest confined aquifer
occurring at a depth of 70 to 90 feet. (See Figure 3.2-3.)

     The uppermost soils at O-Field are silt to silty lean clay and below this layer lies
a low permeability, tan to grey sand with some silt. Lenses of gray clay underlie the
sand followed by silty sand where the water table begins. Extensive excavation and
explosions have probably destroyed much of the natural strata of the site to a depth
of 10 to 12 feet.

     The water table aquifer lies 9 to 15 feet below ground surface with an average
saturated thickness of ten feet that varies seasonally by as much as three feet. This
aquifer is present across the site and is composed of brown to reddish-brown quartz
sand interbedded with discontinuous silt and clay layers. The sand  is medium
grained in the central areas of the site and becomes finer to the east and north and
coarser to the northeast. The water table aquifer is underlain by a confining layer
composed of highly plastic black to gray or greenish gray clay. The depth of this
confining layer is 11 to 30 feet below ground surface and ranges in thickness from 05
Page 3-12

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 Section 3i Model Applications                          Summary Description *2


 to 5 feet.  The presence of contamination below this layer indicates that the
 confining layer is either leaky or discontinuous.

     The upper confined aquifer is below this confining layer. This aquifer lies 20 to
 30 feet below the ground surface with a thickness that varies from 13 feet in the east
 and south to less than a foot as it nears the Gunpowder River to the west. The
 aquifer probably remains confined beneath the Watson Creek shoreline but loses its
 confining bed beneath the deeper parts of the creek. This aquifer is composed of
 dark grey to brown, medium to coarse-grained sand interbedded with gravel and
 discontinuous clay lenses. This aquifer is underlain by a confining layer composed
 of dense, black to dark grey clay.  The depth of this confining layer is 20 to 39 feet
 below ground surface and ranges in thickness from 43 to 60 feet. The extent,
 thickness and low permeability of this confining bed are probably adequate to
 prevent contaminant migration  or significant  water movement from the upper
 confined aquifer to the lower confined aquifer.

     The lower confined aquifer lies approximately 80 feet below ground surface and
 is 10 to 20 feet thick. There is little information on the extent and lithology of this
 aquifer.  Downhole gamma, spontaneous-potential  and resistance logs as well auger
 behavior during drilling suggests that it is composed of a highly permeable, gravel
 like material.

 Ground-Water Hydrology Summary:

    Water flow in the aquifers underlying this site is complex due to the surface-
 water interactions and lagging tidal cycles in Watson Creek. Ground water in the
 water-table and upper confined aquifer generally flows from south to
 north/northeast towards Watson Creek.  A ground-water divide that lies to the west
 of Old O-Field causes a portion of the ground water to bypass Old O-Field and flow
 into the Gunpowder River.  (See Figure 3.2-4.)  A gross estimate of the ground-water
 flow rate is 50 feet/year.

    The water-table aquifer derives most of its recharge from vertical infiltration of
 precipitation. Additional recharge occurs by lateral movement of ground water as
 discussed above and periodically by Watson Creek, which overflows its banks
 during periods of high tides. Discharge is primarily to Watson Creek and the
 Gunpowder River.

    Recharge to the upper confined aquifer is by downward leakage from the
 overlying water-table aquifer. Discharge is by slow upward leakage through the
 confining bed to the water table aquifer in down gradient areas and by leakage to
 surface water bodies where the confining bed has eroded.

    The  hydraulic gradient indicates that the ground water in the lower confined
aquifer flows toward the west-northwest, possibly discharging into the Gunpowder
River. The heads in this aquifer are typically higher than those in the upper
confined  aquifer.  Thus, in the unlikely event that there are pathways for downward
contaminant migration between  the upper and lower confined aquifers, the
hydraulic gradient would oppose all such flow except for the density driven
migration of free product.
                                                                   Page 3-13

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Section 3t  Model Applications                          Summary Description *2


Ground-Water And Surface Water Contamination Summary:

    The ground water in both the water table and the upper confined aquifer at O-
Field contains inorganic and organic contaminants.  Inorganic contaminants
include arsenic, iron, manganese, zinc, boron, antimony, cadmium and chloride.
For example, arsenic concentrations range from 1.96 parts per million (ppm) in the
water-table aquifer to 0.0016 ppm in the upper confined aquifer.  Dominant organic
contaminants are chlorinated aliphatic hydrocarbons, aromatic hydrocarbons and
chemical-warfare degradation products which contain sulfur and phosphorus.
Concentrations of thiodiglycol, a degradation product, ranged from 1000 ppm to 5
ppm in the water-table aquifer.  In general the highest contaminant concentrations
are measured in the water-table aquifer, although higher concentrations of boron
and 1,1,2,2-tetrachloroethane are present in the upper confined aquifer than in the
water-table aquifer. The arsenic and cadmium concentrations found exceed EPA
drinking water maximum contaminant levels.  The concentrations of chloride,
iron, manganese and zinc exceed 1987 EPA secondary maximum contaminant
levels.

    The distribution of individual dissolved contaminants varies areally in the
water table and upper confined aquifer.  For example, the concentrations of arsenic
and organic contaminants are  highest  along the northeastern side of Old O-Field.
However, iron is present as two distinct plumes, one along the eastern side and  one
along the northeastern side of Old O-Field. The areal distribution of contaminants
at New O-Field could not be evaluated because of the limited number of wells at the
site.

    Although low concentrations of organic contaminants have been detected in
water samples from the lower confined aquifer, hydraulic gradients and the
lithology and thickness of the  overlying bed  make it unlikely that O-Field
operations have contaminated the lower confined aquifer.

    A surface water quality study in 1985 of Watson and nearby creeks found
unusually high organic loading in Watson Creek and dissolved inorganic
constituents that exceed EPA chronic toxicity levels for freshwater and saltwater
aquatic life. The lateral migration of  ground-water  contaminants into Watson
Creek is thought to be partially responsible for the surface water contamination.
Ultimately, this surface water contamination may migrate into the Gunpowder
River.

Modeling  Summary:

    The U. S. Geological Survey's (USGS) three dimensional flow code,
MODFLOW, was used to model this site in a quasi three dimensional, steady state
mode. Two model layers were used, one layer simulating the water-table aquifer
and the second layer simulating the underlying confining layer and the upper
confined aquifer.  The lower boundary of the second layer coincides with the top of a
fifty foot thick layer of dense day below the upper confined aquifer.  The low
permeability and continuity of the clay was thought  to justify its use as a no-flow
boundary for this model application and thus eliminated the need to model the
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Section 3i Model Applications                          Summary Description #2


lower confined aquifer.  The model was found to be relatively insensitive to this
assumption as discussed below.

     A 66-row by 61-column finite-difference grid was constructed and aligned with
the principal direction of flow. The grid extends to the south and considerably
beyond O-Field to coincide with surface water bodies that could be modeled under
steady state conditions as constant head boundaries. Grid cell dimensions varied
between 20 and 2375 feet with the smallest cells located directly over the areas of
interest.  Changes in cell size were limited to no  more than 1.5 times the size of
adjacent cells.

     Boundary conditions modeled included surface water bodies, no-flow regions,
drains, and leakage between the layers. Vertical hydraulic conductivities were based
upon typical values for similar soil types, limited field data and model calibration.
The water-table aquifer was bounded at most locations by constant head boundaries
which represented the shoreline of surface water bodies. At the two areas where the
water-table aquifer extended beyond the modeled area the ground-water flow was
parallel to the  model boundaries and thus these areas were modeled as no-flow
boundaries.

     The lateral boundaries of the upper confined aquifer were specified as no-flow
boundaries. However, a relatively high vertical hydraulic conductivity was
specified for those portions of the overlying confining layer that lay beneath surface
water bodies and thus these areas of the modeled layer responded almost as if they
had been established as constant head boundaries. Consequently, as the modeled
portion of the upper confined aquifer is almost entirely surrounded by surface water
bodies this layer was effectively modeled with constant head boundaries with one
exception.  That exception was determined to be  far enough from O-Field that the
no-flow boundary had negligible effects on simulations within O-Field.

     Preliminary calibration of the steady-state model was achieved by setting
average annual recharge constant and adjusting model coefficients, primarily the
horizontal hydraulic conductivity of the water-table aquifer and the transmissivity
of the upper confined aquifer. These coefficients were adjusted within a range of
reasonable values based upon field measurements.  The calibration was  considered
acceptable if the simulated and observed average annual heads agreed within 0.5
feet. The model was then recalibrated against observed head data for a period of
elevated ground-water levels. During this second calibration the horizontal
hydraulic conductivity and transmissivity values obtained from the first calibration
were held constant and recharge was uniformly increased until the predicted heads
acceptably matched the observed heads  Horizontal hydraulic conductivity and
transmissivity  were then adjusted slightly to improve the match. These new values
were then used to once again calibrate the model against the average annual
observed heads.  This process was repeated until the model met the calibration
criteria under both hydrologic scenarios.

     Because of uncertainties about the actual recharge and hydraulic conductivities
at O-Field, several alternative solutions to the steady state model were then
generated by varying both recharge and hydraulic conductivity. Based upon
recharge estimates and field  measurements of horizontal hydraulic conductivity,
                                                                   Page 3-15

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Section 3s  Model Applications                          Summary Description *2


the recharge was varied between 9 and 16 inches per year and the hydraulic
conductivity was uniformly adjusted by the same percentage. The resulting head
configurations still closely matched the observed heads.  These alternative
hydrogeologic system representations were used to model the system responses to
the remedial alternatives evaluated  also.  Thus, the impact of hydrogeologic
uncertainty upon the results of the remedial alternatives modeled could be
quantified.

    A sensitivity analysis of the calibrated flow model was performed for a range of
recharge, hydraulic conductivity and transmissivity values.  This analysis indicated
that heads in  the water-table aquifer were relatively insensitive to variations in the
vertical hydraulic conductivity of the confining layer or transmissivity of the
confined aquifer.  Heads in the confined aquifer were somewhat more sensitive to
these variations.  The sensitivity analysis also indicated that simulated heads in
both aquifers  were very sensitive to changes in the horizontal hydraulic
conductivity and recharge of the water-table aquifer.

    The assumption that the lower confined aquifer did not need to be modeled
was also examined during the sensitivity analysis.  Simulations of a modified
version of the model that included the lower confined aquifer as a third layer
demonstrated that significant head variations in the lower confined aquifer had a
minimal impact on the head in the upper two aquifers. This confirmed that
simulation of  the ground-water system as a two layer system was adequate for the
purposes of this modeling effort.

    Five remedial actions and a sixth no-action scenario were evaluated.  These
remedial actions were evaluated on the basis of their ability to lower ground-water
levels within  the disposal areas and to limit lateral or vertical movement of water
through the disposal areas. The remedial actions evaluated included: installation of
an impermeable cap; installation of subsurface barriers; installation of a ground-
water drain; ground-water pumping to control water levels; ground-water pumping
to recover contaminants; and no action. All remedial actions were also simulated
with the alternative model configurations described above to quantify the impact of
hydrogeologic uncertainty upon each remedial alternative's predicted effectiveness.

    The impermeable cap remedial alternative was simulated by establishing areas
of no ground-water recharge. The subsurface hydraulic barriers were simulated by
reducing horizontal  hydraulic conductances in the model cells representing the
barriers. These conductances were calculated to represent a 5 foot thick barrier with
a horizontal hydraulic conductivity of 0.001 feet per day and accounted for the fact
that the barriers did not comprise the entire cell.  The ground-water drain was
simulated by  lowering the surface elevation of an existing natural drain to 15 feet
above sea level during the period of record.

    Ground-water pumping to control water levels was simulated with the
addition of three pumping wells upgradient from Old O-Field and two wells
upgradient from New O-Field.  Each of these wells were simulated at pumping rates
of 2,900,5,800,10,000 and 21,600 gallons per day (gal/d) but Old O-Field and New Old
Held wells were simulated separately.  The pumping was simulated with and
without impermeable covers.  Similarly, ground-water pumping to recover
Page 3-16

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Section 3i  Model Applications                          Summary Description #2


contaminants (pump-and-treat) was simulated with the addition of two wells
adjacent to the southeastern side of Old O-Field and two wells adjacent to the
northeastern side of New O-Field.  Again, each of these wells was pumped at rates of
2,900,5,800,10,000 and 21,600 gal/d; Old O-Field  and New O-Field wells were
simulated separately; and the pumping was simulated with and without
impermeable covers on the respective disposal areas.

Modeling Results Summary:

    The simulations indicated that covering Old O-Field with an impermeable cap
would lower water levels beneath the site by less than 1 foot. An impermeable cap
over New O-Field would be even less effective and reduce water levels by only 0.3
feet. Ground-water velocities appear to be sufficient to compensate for the loss of
recharge water intercepted by the caps. However, the reduction of precipitation
infiltration into the unsaturated zone at the fill could decrease the amount of
contaminant leaching.

    Subsurface hydraulic barriers upgradient from Old O-Field resulted in water
level declines below Old O-Field of about 1  foot but produced increases in water
levels at New O-Field.  Thus while potentially reducing contaminant leaching at
Old O-Field the barriers may also increase leaching at New O-Field. Complete
encapsulation of Old O-Field with hydraulic barriers and an impermeable cap was
also simulated and was shown to provide short term aquifer protection. However,
the concentrations of some contaminants would  likely increase in solution and
should the encapsulating walls fail at some future point, the concentrations of some
contaminants in the ground water would then increase.

    The simulation of subsurface barriers at the New Old-Field reduced water
levels at the disposal trenches by 25 feet but increased water levels by 2 feet on the
upgradient side.  These reductions increased to 35 to 4.5 feet with the addition of an
impermeable cap.

    The simulation of deepening an existing natural drain lowered water levels in
the water table aquifer beneath both Old and New O-Field.  In turn, a ground-water
divide developed between the drain and Old O-Field and  contaminant movement
from Old O-Field towards the drain probably would not occur. However, during
periods of low ground-water levels or high  surface water levels, brackish surface
water would enter the drain and recharge parts of the water-table aquifer with
brackish surface water.

    Pumping to manage water levels at Old O-Field indicated that the water-table
aquifer would be drawn down by 0.7 to 1.0 feet when the wells were pumped at 5800
gal/d per well. When an impermeable cap was added the drawdown increased by
0.5 feet. However, some simulations within the range of hydrogeologic uncertainty
demonstrated that a pumping rate of 5800 gal/d per well or more could induce
contaminants to migrate to previously uncontaminated areas.

    Pumping rates of 10,000 and 21,600 gal/d per well were required at New O-Field
to reduce ground-water levels by 1.0 and 2.3 to 3.5 feet respectively.  However, both
                                                                   Page 3-17

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Section 3:  Model Applications                         Summary Description #2


rates would produce hydraulic gradient reversals extending to the disposal trenches
and thus induce the movement of contaminants toward the wells.

    The simulations predicted that pump-and-treat at a rate of 2900 gal/d per well
in combination with an impermeable cap would intercept the bulk of ground-water
contamination at Old O-Field in the spring, summer and fall. This rate would have
to be increased to 5800 gal/d in the winter when ground-water levels are higher.
However, this higher rate could induce the movement of water from Watson Creek
into the aquifer if it is maintained throughout the year.  Pump-and-treat at New O-
Reld resulted in drawdowns of 1.1 to 1.8 feet for pumpage of 5800 gal/d and 2.2 to 35
feet for pumpage of 10,000 gal/d.  As little is known about the extent of
contamination under New O-Held, no conclusions could be drawn as to whether
this would  intercept the bulk of the contamination.  New O-Field simulations at
these rates did not show inducement of infiltration of creek water but the proximity
of the hydraulic grade reversal to the creek implies that infiltration would probably
be induced  if a 5800 gal/d per well pumping rate was maintained during dry
summer months.

    If no remedial actions are taken at O-Field, the simulations indicated that
mobilization and transport of  organic and inorganic contaminants will continue,
primarily because the seasonal and recharge induced water levels rise above the base
of the buried contamination. The ground water contaminants, in turn, will
continue to discharge to Watson Creek. If the contaminants in the creek attain
sufficient concentrations, then the depletion mechanisms in the creek may be
inadequate to prevent contaminant migration from the creek into the Gunpowder
River.

Strengths And Interesting Features Of This Study:

    In this case study, a model was applied in the early phases of a site investigation
to assist in  characterizing the contaminant releases and plumes, the future
migration of contaminants and to explore and screen potential remedial
alternatives. Because of the hazards associated with sampling at this site, only
limited hydrogeologic data was available  when the modeling began. Perturbations
in the ground-water system caused by tidal induced changes in the elevations of the
surrounding surface water bodies further complicated the modeling. Nevertheless,
data acquired after this  modeling was completed confirmed the general flow field
and the surface water and ground-water interactions predicted by the model.

    A major effort was made  to ensure that the model application would accurately
predict the system response during both the average and the extreme hydrogeologic
conditions found at the  site.  Specifically,  the model was calibrated against two
different sets of observed conditions; one representing average annual head
observations, the other  representing a .period of time when significantly higher than
average heads were observed. The calibration continued until the model
application accurately predicted system response under both sets of conditions.

    This modeling effort quantified the impact of the hydrogeologic uncertainty
upon the results of the  simulations. Alternative solutions to the steady state model
application were developed by increasing and decreasing recharge and horizontal
Page 3-18

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Section 3i Model Applications                          Summary Description #2


hydraulic conductivity within ranges defined by field measurements and
professional judgement  These alternative solutions closely matched the observed
heads, and therefore, were judged to bound the set of reasonable representations of
the ground-water system. In turn, these alternative representations of the system
were used to bracket the range of system responses to the remedial alternatives
evaluated.

    An analysis of the sensitivity of the calibrated model application to changes in
hydrogeologic parameters was also performed.  As a part of this analysis the
sensitivity of the model predictions to modeling the site as a two layer system was
investigated. The sensitivity analysis  indicated that the two-layer representation
was sufficient for the purposes of the study.

    The model application provided  the EPA  Region with the framework for
selecting the most appropriate remedial alternative. It provided guidance in
determining the goals and objectives of the remediation effort.  Based upon the
results of the modeling described in this case study, ground-water extraction was
selected as the preferred  remedial action. The model application was subsequently
used to  evaluate alternative extraction systems.

Contacts:

    For further information about this ground-water study please contact:

      Steven Hirsh            Regions          Tel.# (215)597-0549

      Nancy Cichowicz         Region 3          Tel. # (215) 597-8118

      Cindy Powels            Aberdeen         Tel.# (410)671-4429
                              Proving Ground

Modeling Documents:

    Please contact the above people for specific modeling documents.
                                                                   Pago 3-19

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Section 3f  Model Applications
Summary Descriotion #2
                                   Figure 3.2-1
                                  Site Location
                       PENNSYLVANIA
                                                                    76°15'
                         Washington
                        VIRGINIA
                                                 PROVING AGROUND
 39°20'
      Base from US. Geological Survey. 1:100.000.
    2 MILES
                                              0123 KILOMETERS
Page 3-20

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   Sect'on 3t  Model Applications
Summary Description 02
                                              Figure 3.2-2

                                        Detailed Site Location
                          EXPLANATION

             S   ObMrv«iion-w«M MineJna, Me and identification
                 number n O-FieW.
             •   ObMTvanon-wel duster sit* and identMcation
                 number n O-FMd.
                             r w*l in H-FMd.
              &' TeeeqraoMe comae Interval • 6 feet.
39'20' 30'
39'2tf IS'
   3920*
                                                                     o  100 «M  too ico
                                                                        f tit i *'
                                                                     9  M  110  HO 2«0
        USGS, 1991

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Section 3i  Model Application*
Summary Description #2
                                           Figure 3.2-3


                                Sample Hydrogeologic Sections
                     Sit* OF«                 SHe OF 17    Sit* Oral     SM* OF20

                   (AltHud* !• «.7 F**O   (Altitude is «.2 F**|)  (Altitude It «.a  (Altitude !• S.«
                                                         confined aquifer
                                                                0 70 4d (• M WT
                             Lower confined
                   HYOROGEOLOGIC SECTION A-A'
                                                            vertical £i*«o*r«iion x 4
                                                                       B*
                    FEET
                       30 —

                                          L-J^---.------'-----^---.-.^-.-.".
                                          <^$<<<<<<<<<<<$-z<:
                         HYOROGEOLOGIC SECTION B-8
                                                     , vertical EnaggereMon x 10
 Page 3.22

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Section 3t  Model Applications
Summary Description #2
                                   Figure 3.2-4
                            Site Water-Table Contours
                                                                    Page 3-23

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Section 3t Model Applications                       Summary Doscriotion #2
                 (THIS PAGE INTENTIONALLY LEFT BLANK.)
Page 3-24

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3.3 - Summary Description #3

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 3.3

                            Model Applications

                        Summary  Description #3


 Decision Objective:

     This fund-lead site was modeled during the Remedial Design (RD) to ensure an
 appropriate design while minimizing design costs.  Specifically, additional
 information on the ground-water flow and contaminant fate and transport was
 required to design a ground-water extraction and collection system that had been
 specified in the Record of Decision (ROD). The EPA contractor proposed additional
 field investigations including an extensive drilling program to obtain the needed
 design information. EPA suggested that much of the required information could be
 obtained through the use of ground-water modeling, thus significantly reducing
 design costs. The contractor agreed to the modeling effort and specific modeling
 objectives were established. These objectives were to:

      1.    Delineate the maximum possible extent of the contaminant plume in
            January 1993, when the pump and treat system is scheduled to begin
            operation;

      2.    Estimate  the mass of contamination per unit volume of the aquifer;
      3.    Conceptualize  extraction well alignment designs; and
      4.    Evaluate  the design alternatives.

     An EPA contractor working under an Alternative Remediation Contracting
 System  contract did the modeling that is the subject of this case study. The EPA
 project manager reviewed the modeling work.

 Background:

     This is a six acre site located in a 250 home residential area with homes within
 100 feet of the site. (See Figure 3.3-1.) Other land use in the area includes some
 commercial development along a state highway southeast of the site and
 agricultural activities southeast of the same highway. The site is an inactive
 manufacturing facility and is currently used for minor non-production activities,
 primarily warehousing. Located on the site are process, office and warehouse
 buildings. (See Figure 3.3-2.) A tank farm and a laboratory have been removed
 from the site. The site topography is  relatively flat but exhibits occasional low rises
 and gentle depressions. The average annual precipitation is approximately 35
 inches and the mean monthly temperatures range from 26° F to 72° F.

    This site was used to manufacture and repackage non-lubricating automotive
fluids from the early 1960s to 1978. During the facility's operation, a number of
releases and a major fire contributed to the site  contamination.  Undocumented
releases of chlorinated  hydrocarbons into  the vadose zone occurred south of the
process buildings. Documented releases of diethyl ether occurred in 1972 when an
underground pipeline was ruptured during excavation. Chlorinated organics,


                                                                   Page 3-25

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Section 3t  Model Applications                          Summary Description #3


benzene and other solvents were released during a two day fire in 1978.  During this
fire numerous tanks and drums ruptured and their contents were spread onto
unpaved areas by the water used to fight the fire. The unsaturated zone soil was
thought to be the primary remaining source of contamination at the site.

History of Investigation

    The owner of the site installed six on-site monitoring wells in 1972.
Contaminant levels detected in these wells and nearby residential wells indicated
that the contamination was moving off-site. Consequently, under an agreement
with the state agency responsible for environmental protection, the owner began
supplying bottled water to homes with contaminated wells in 1973.  After the 1978
fire, the owner began removing underground tanks. Then in 1980,15 more
monitoring wells were installed at 9 locations. In 1982, the state agency initiated
legal actions against the site owner to force site remediation.  The following year the
owner began operating a ground-water treatment system.

    The site was placed on the National Priorities list (NPL) in 1984 and at that time
EPA assumed the lead enforcement role. In 1985, the owner agreed to fund a
remedial investigation and feasibility study (RI/FS) under an Administrative Order
of Consent.  The completion of that study was funded by EPA when the owner filed
for bankruptcy in 1986. The state, in 1986, extended a public water supply to the
residents in the area near the site. In 1988, the ground-water treatment system was
closed down by the site owner due to financial problems.

    In 1988, the Record of Decision (ROD) was issued. The ROD specified soil and
ground-water remediation including a  contaminated soil flushing system, a  ground-
water extraction and collection system and a ground-water treatment (air stripping)
and discharge system. The ROD further specified that the aquifer within the 1.5
parts per billion contaminant concentration isopleth would have to be restored to
drinking water standards.

Geologic Summary:

    This site is located in an area dominated by glacial sediments deposited in a
northeast-southwest trending belt. The two major types of deposits are glacial
outwash with post glacial alluvium and ice-contact outwash deposits.  Both types of
deposits contain fine sand to coarse gravel with occasional large cobbles and are very
poorly sorted. Sixteen borings made in the vicinity of this site indicate that the
glacial sediments extend to an average depth of 117 feet below the surface.
Underlying the site are clay, silty sand,  sand and gravel fades which laterally
intergrade with one another and result in laterally discontinuous layers.

    The uppermost soils at the site consist of a 5 to 10 foot upper layer of fine sand
and a lower 115 to 125 foot sand layer. 
-------
 Section 3i Model Applications                          Summary Description #3


 just east of the site 50 feet below the ground surface.  This lense extends over 3000
 feet to the west and rises to thirty feet below the surface. It reaches a maximum
 thickness of 20 feet. Several small gravel beds where detected also in the lower parts
 of the lower sand layer.

 Ground-Water Hydrology Summary:

     The site hydrogeology is composed of three distinct hydrogeologic units. The
 uppermost unit is an unconfined aquifer that is encountered at approximately 30
 feet below the ground surface with a saturated thickness of 70 to 90 feet in the site
 area and increasing to a thickness of 135 feet just over a mile and a half to the west.
 This aquifer corresponds to the lower sand layer discussed previously. The second
 hydrologic unit, a confining layer of sandy day that varies between 7 and 22 feet in
 thickness near the site but thins to a two foot thickness a mile to the west, lies below
 the aquifer. The third hydrogeologic unit, a confined aquifer, whose confined head
 is approximately one and one half feet lower than the head of the upper aquifer lies
 below this confining layer. This lower  aquifer corresponds to the layer of sands and
 gravel with occasional minor clay lenses discussed above.  The thickness of this
 confined aquifer is unknown as none of the borings reached bedrock.

     The upper unconfined aquifer is no longer used  as a drinking water supply in
 the immediate site area because of contamination.  Two miles to the west of the site
 are three municipal wells which produce more than a million gallons per day from
 this aquifer. The cone of depression caused by the operation of these wells may
 eventually enhance the off-site movement of contaminated ground-water towards
 the west.  The direction of flow in this aquifer is generally west-southwest with a
 velocity of approximately 0.5 feet per day.  Both pump and slug test data were used
 to estimate the hydraulic properties of this aquifer. The pump test data indicated an
 average aquifer hydraulic conductivity and transmissivity of 0.0775 cm/sec, and
 148,000 gpd/ft, respectively, assuming an average aquifer thickness of 90 feet. The
 slug test data indicated an average aquifer hydraulic conductivity and transmissivity
 of 0.0489 cm/sec, and 98,000 gpd/ft, respectively.

    The lower confined aquifer was not extensively studied for the purposes of
 remediating this site because of: (1) the presence of the confining layer above the
 aquifer, (2) prior sampling which indicated no presence of contamination in the
 lower aquifer and (3) the relatively small difference in head between the two
 aquifers.

 Ground-Water Contamination Summary:

    Eighteen contaminants were found at the site, with ten being selected as
 indicator compounds.  These induded 1,1-DCE, 1,1-DCA, 1,1,1-TCA and Benzene.
The Remedial Investigation (RI) identified the unsaturated zone underlying two
areas of the site as the major sources of contamination. The RI also speculated that
there was potentially one other on-site  source and several additional off-site sources
of contamination based upon the location and discontinuity of the contaminant
plume. This plume begins beneath the site and extends west-southwest beyond the
site property boundaries. The plume may not be continuous within its boundaries
and the thickness of the plume diminishes as it extends off-site. The contaminated
                                                                   Page 3-27

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Section 3i  Model Applications                         Summary Description #3


zone reaches the bottom of the upper aquifer at the site and at a minimum extends
1500 feet downgradient.

    The on-site ground-water contamination was being partially contained by two
purge wells that operated from 1983 to the spring of 1988.  These wells had a
combined pumping rate of 200 gallons per minute which resulted in a maximum
drawdown  of about one foot. When these wells were operating they apparently
contained the plume within the western and northern site boundaries. Since they
ceased operation, significant additional contaminant  migration has occurred.

Modeling Summary:

    Analytic and analytic/numeric models and graphical techniques were used to
investigate  the site and to evaluate the effectiveness of ground-water extraction
alternatives. This approach was chosen after a review of project objectives, the
limited quantity and poor quality of the available field data, the modeling budget
and project time constraints.

    The modeling was divided into three phases.  The objective of the Phase One
modeling was to determine the maximum extent of contamination in the upper
aquifer. An analytical function driven variation of the fate and transport model
Random Walk and the analytic transport model PLUME were used in this phase.
The objective of the Phase Two modeling was to conceptualize remedial design
alternatives. Graphical Javandel type curve analysis procedures were used to
determine the minimum number of pumping wells, discharge rates and recovery
well locations under different pumping scenarios.  Then time related zones of
capture for  each alternative were determined using the the U.S. EPA Wellhead
Protection Area Model (WHPA). Finally, the aquifer drawdown resulting from each
alternative was simulated using the analytic ground-water flow model WELFLO.
The objective of the Phase Three modeling was to evaluate the most promising
remedial design alternatives. Again, Random Walk was used in this phase to: (1)
estimate the discharge rates, average concentration and mass of contaminants in the
extraction well discharge; (2) evaluate  and compare the remedial alternatives and (3)
identify areas of uncertainty in design features. This case study will focus on the use
of the Random Walk model in phases one and three.

    The analytical function driven variation of the Random Walk model was
chosen, based on the advice of an outside consultant, to verify the results of the
PLUME model. Random Walk was suggested because of the modeling objectives,
data limitations and the outside consultant's detailed familiarity with the model.
This version of the Random Walk model utilizes an analytic function based upon
the Theis equation to  generate the flow field. The numeric Random Walk model is
applied to simulate the fate and transport of the contaminants.

    The simplifying assumptions associated with the analytic flow component of
the Random Walk model required that the aquifer be treated as  homogeneous,
isotropic and infinite in areal extent. Thus, no site-specific boundary conditions or
spatial variability in aquifer characteristics could be modeled.  Moreover,
unidirectional, steady state ground-water flow had to be assumed.  The modeling
team established a uniform hydraulic conductivity, saturated thickness,
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 Section 3* Model Applications                          Summary Description *3


 transmissivity, hydraulic gradient and aquifer porosity for the modeled area based
 upon information obtained from the RI report and field data.

     For the Phase One modeling, three contaminants were originally selected: the
 most toxic (1,1-DCE), the most mobile (1,1-DCA) and the most pervasive (1,1,1-TCA).
 However, initial modeling efforts indicated that insufficient soil and ground-water
 data were available to develop or calibrate contaminant transport models for 1,1-
 DCE or 1,1-DCA. As 1,1,1-TCA had migrated and persisted farther downgradient
 than the other contaminants the modeling team felt that focusing solely on 1,1,1-
 TCA was valid and appropriately conservative.

     The site conceptual model developed by the modeling team hypothesized that
 the downgradient plume developed primarily through the dissolution of 1,1,1-TCA
 retained in aquifer pores at residual saturation.  This was in contrast to prior studies
 of the site which suggested that the major contaminant source lay in the
 unsaturated zone and was percolating into the saturated zone.  Initially, the
 modeling team had accepted this latter hypothesis and developed a batch flushing
 model to simulate the migration of the contaminant into the saturated zone.
 However, when the results of the batch flushing model were compared with
 observed phenomena, there were major discrepancies. For example, only 2 to 4
 percent of the contamination in the aquifer could be accounted  for under this
 hypothesis.

     After a careful review and some initial skepticism about the validity of the
 batch flushing model results, the modeling team hypothesized that the source term
 lay in the saturated zone.  They searched peer reviewed ground-water literature for
 examples of similar conceptual models and found three. Then, additional site
 sampling including a soil gas survey was initiated.  The results of this sampling
 indicated very limited soil contamination, thus further supporting the new
 hypothesis that the source term lay in the saturated zone.

    The particle tracking component of the Random Walk model was then used to
 model the 1,1,1-TCA dissolution from the 1,1,1-TCA mass stored at residual
 saturation in the saturated zone.  This included the rate of loading of 1,1,1-TCA
 from the unsaturated zone by percolation to the ground water, minus  the mass
 removal of 1,1,1-TCA from the ground-water system, during  the historic operation
 of the purge wells described previously. This approach resulted in a source term
 that varied as a function of time and dropped to zero during  the historical operation
 of the purge wells. The longitudinal and transverse dispersivities, background
 concentrations, and organic carbon partition coefficients utilized in the model were
 based upon field data and established EPA methods. All ground-water
 contamination was assumed to exist in the dissolved phase; and, consequently,
 dense, nonaqueous phase liquid  migration was not simulated. Biodegradation and
 volatilization was also ignored.

    The calibration of the Random Walk model was restricted  to the  contaminant
 fate and transport component. This version of Random Walk assumes a
unidirectional flow field which can not be directly calibrated against observed
piezometric heads. Field data from the RI report was used to  establish  the flow field
parameters.  Calibration of the contaminant transport model was achieved by
                                                                   Page 3-29

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Section 3t Model Applications                         Summary Description 93


adjusting the flow direction, flow velocity and dispersivity until predicted
concentration values matched observed concentrations. These modifications were
within reasonable parameter ranges and in the case of the flow direction were based
upon additional field data. The source release term was held constant during the
calibration process.
     The calibration of the model presented a number of challenges. First, the data
used to calibrate the model was obtained from prior studies conducted by the site
owner's contractors. A review of that data indicated numerous data quality
problems including transcription errors, false positive and false negative
indications, conflicting sampling dates and surface maps of conflicting scales.
Second, data from nested monitoring wells indicated the presence of a vertical
contaminant concentration gradient.  However, the direction and magnitude of this
gradient varied inconsistently from one monitoring location to another.
     The modeling team established a two-tier calibration target after analyzing
these constraints and the primary model objective, which was to predict the extent
of the contaminant plume at the beginning of operation of the extraction system.
For those wells where the field data indicated no contamination, the model would
have to  indicate no contamination. For those wells where field data indicated
contamination, the model concentrations would have to be within one half an
order of magnitude of the measured values at that location.  Furthermore, at nested
monitoring wells, the average of the measured values would be used for model
calibration.  The model was then calibrated against three different sampling events
spanning an 8 year period utilizing field data from up to 19 wells.

     Recognizing the limitations of the calibration data and in turn the calibration
process, the contractor initiated a new round of sampling at  23 monitoring wells
under stringent quality assurance procedures. This data was not available until the
calibration of the model had been completed.  The modeling team, however, was
able to use this data to verify the model calibration.  The success of this verification
surprised the modeling team.  With only one exception the model accurately
simulated all wells where no contamination was detected. At those wells where
field data indicated evidence of  contamination, the residuals between the simulated
and observed values were much closer than the one half order of magnitude
calibration target used. Moreover, at the downgradient monitoring well that lay
directly on the center line of the plume, the measured and simulated concentration
value varied by only one part per billion.

Modeling Results Summary:

     The Phase One modeling results indicated that the 1,1,1-TCA plume will have
migrated 625 meters downgradient and 225 meters laterally by 1993. This migration
has occurred in spite of the operation of two purge wells from 1983 to 1988.  The
modeling team was careful to note that they were more confident of the delineation
of the plume boundary than the predicted concentrations  within the plume because
of model and data limitations.

     Based upon these results, 15 extraction well alternatives were developed in
Phase Two using Javandel type curve analysis, the GPTRAC module of the U.S. EPA
Well Head Protection Area Model (WHPA), and the analytic model WELFLO.  This
 Page 3-3O

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 Section 3s Model Applications                          Summary Description #3


 analysis indicated that under ideal conditions only one extraction well discharging
 at 100 gallons per minute would be required.  However, recognizing the limitations
 associated with the Phase One modeling and the models used in this second phase,
 two additional alternatives utilizing three and five wells respectively were chosen
 for further consideration in the Phase Three modeling. The location of the  capture
 zone of one alternative is shown in Figure 3.3-5.

     The efficiency, flexibility and the mass of contaminants in the extraction well
 discharges for these three alternative were then evaluated in Phase Three using the
 Random Walk model. The efficiency of each alternative was defined as a function
 of the pumping rate, the volume of water requiring treatment and the time required
 to restore the ground water to clean-up goals. While the pumping rates for  the
 three alternatives were found to be very similar, the five well alternative was found
 to meet the cleanup goals in one quarter the time of the other two  alternatives.  The
 five well alternative, moreover, would significantly reduce the volume of water
 requiring treatment.

     The flexibility of each alternative was defined as the ability of the alternative to
 operate efficiently when the actual aquifer response to the pumping varied
 significantly from the response predicted by the modeling.  In particular, the
 modeling team was concerned about the possibility of unmodeled heterogeneity in
 aquifer properties and the distribution of contaminant concentrations within the
 plume. The five well alternative was again found to be the preferred alternative
 because it allowed the operation of each of the five extraction wells to be tailored to
 the specific characteristics of that part of the plume and aquifer within which the
 well was located.

     EPA has awarded a contract for the construction of the five well ground-water
 extraction system developed as part of this modeling effort. This system is expected
 to be in place in early 1993.  A ground-water monitoring program has been proposed
 which will allow the monitoring  of the remediation progress and the ongoing
 validation of this ground-water modeling application.

 Strengths And Interesting Features Of This Study:

     In this case study, a model was utilized as part of the remedial design process.
 The modeling was initiated at the suggestion of EPA in order to reduce the
 magnitude and cost associated with additional site sampling. The model chosen
 represented a compromise between the level of detail and accuracy desired by the
 designers, the available data and the modeling budget. In fact, during the
 development of the modeling objectives, the modeling team attempted  to use both
 a simple analytic and a finite difference contaminant transport model before
abandoning the former for its lack of specificity, and the latter because of the limited
site data available.
                                                                   Page 3-31

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Section 3i  Model Applications                          Summary Description #3


    One of the more interesting aspects of this case is that both EPA and the
contractor agreed that the modeling reduced the design costs by $450,000. Part of this
cost reduction was due to the use of the model to delineate the plume boundary in
lieu of locating the boundary by means of an extensive drilling program. The other
part of the cost reduction occurred as a result of the modeling process which led to
the identification of an error in the source characterization.

    Previously it had been hypothesized that the source lay in the unsaturated
zone.  Consequently, soil flushing had been specified as a remedial action in the
ROD. While trying  to develop the source term for the model, the modeling team
began to question this hypothesis.  Based upon the results of a batch flushing model,
a search of  peer-reviewed literature for similar cases, and additional field sampling,
the modeling team determined that the source term  most probably lay in the
saturated zone. Thus, the need for the design and implementation of the soil
flushing system specified in the ROD was eliminated. This resulted in considerable
design cost savings and will result in considerable additional construction and
operational cost savings.

    Another interesting aspect of this modeling  was that the Phase One modeling
was actually performed twice using two different models. First the site was modeled
using PLUME. Then at the suggestion of an outside consultant the site was
remodeled using Random Walk. There was a high degree of correlation between
the model results. However, such correlation is not necessarily evidence that a site
was modeled properly. Rather it demonstrates that  for this same conceptual model,
these two models produce very similar results.

    Both EPA and the contractor noted that this case is another example of how the
use of modeling early in the remedial investigation  process could have improved
the entire remediation effort. Specifically, it was  noted that a very simple analytic
model could have improved the sampling  plan and monitoring well locations in
prior site studies.  This in turn would have increased the possibility that a more
accurate numerical model could have been used during the design process, possibly
resulting in a more efficient design.

Contacts:

      For further information about this ground-water study please contact:

      Bob Whippo             Region  5         Tel. # (312) 886-4759

Modeling Documents:

      Please contact the above person for specific modeling documents.
Page 3-32

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Section 3t Model Applications
Summary Descrtotfon #3
                                  Figure 3.3-1
                      Site and Contaminant Plume Location
                                                                Page 3-33

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Section 3* Model Applications
                                           Summary Description #3
                                   Figure 3.3-2



                   Detailed Site Location and Monitoring Wells
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                                              §
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                                                    *rf  K



                                                     8
-------
Section 3t Modal Applications
                                                Summary Description #3
                               Figure 3.3-3

                        Sample Hydrogeologic Section
               IJ £ f i
ill
             9
             i:
               •.nil
                     \l
                                         A  «  *
                                                         M!
                               I

-------
Section 3i Modal Applications
Summary Description #3
                                   Figure 3.3-4



                    Location of Sample Hydrogeologic Section
 Page 3-J6

-------
Section 3*  Model Applications
Summary Description *3
                                           Figure 33-5

                                     Capture Zone Analysis
                                                                               4
                                                                               N
                                                                               *
                          YonK«r St.   Business Rout* 60
         NOTE; Capture ton* of only tho two downqradtant
             ««!• i* mown to niuctroto tho sy«twn«
             eesoelllty to eoptur* th« eantominatM plum*.
             Addltlonot w«H at ^t* (net mown)
             •ill winanc* piumo  capture.
                                                                                    Page 3-37

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Section 3i Model Applications                       Summary Descrfntfon 93
                 (THIS PAGE INTENTIONALLY LEFT BLANK.)
Page 3-38

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3.4 • Summary Description #4

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3.4

                         Model Applications

                      Summary Description #4


Decision Objective:

    This enforcement lead site was modeled by EPA during the remedial design
(RD) to ensure an appropriate RD and remedial action (RA). Specifically,
information on the ground-water flow and contaminant fate and transport was
required to support RD and RA negotiations. As this was an enforcement lead site,
the objective of EPA in conducting this modeling was to gather sufficient
information to be able to review the responsible party's characterization of the
nature and extent of contamination at the site and the remedial design.

    The modeling was deemed necessary because it was recognized in the Record of
Decision (ROD) that the design objectives and remedial action specified in the ROD
were based upon incomplete knowledge of both the sources and the actual extent of
the contamination and the contaminant plume. Consequently, EPA determined
that a limited modeling effort would assist in better understanding the site and the
effectiveness of the proposed  pump and treat remedial design.  In support of these
decision objectives  the following four modeling objectives were established:
    1.   Identify potential off-site contaminant migration;
    2.   Examine the proposed pump and treat extraction well alignment;
    3.   Improve (if necessary)  the extraction well alignment design; and
    4.   Determine the time required to clean the site.
    The modeling that is the subject of this case study was  performed by an EPA
contractor under a Technical  Enforcement Support at Hazardous Waste Sites
contract. The modeling work was reviewed by both the EPA project manager and an
EPA hydrogeologist.

Background:

    This site is comprised of 18  acres located in an industrial corridor adjacent to an
interstate in a major western  metropolitan area. The site abuts a major railroad line
and is surrounded by other small industries.  (See Figure 3.4-1.)  Located on the site
are abandoned and active tank farms and a filled and abandoned sump.  There is
also a capped evaporation pond, the contents of which are unknown. The site
topography is generally flat and low lying with a vacant swampy area to the south.
The nearest residential area is within a quarter mile of the site and the total
population within a one mile radius of the site is less than 5000.

    Operations at the site began in 1957 and included the production of herbicides
and pesticides; the production of sodium hypochlorite; refilling and distributing
chlorine and ammonia cylinders; and the packaging and distribution of acids,
caustics and organic solvents. Information related to the historical operations at the


                                                                   Page 3-39

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Section 3t Model Applications                          Summary Description #4


site indicates that the uncontrolled release of contaminates may have begun in the
very first year of operation and may have continued through 1989. These releases
are believed to have been the result of both disposal practices and spills.

    Examples of disposal practises that led to releases include: the use of unlined
settlement and evaporation ponds for process wastewater discharge; the discharge of
industrial and process waste materials to an on-site septic tank and drain field; and
the dumping of wastewater, pesticide and herbicide tank wash water on the ground.
Examples of spills included a 4000 to 8000 gallon spill of muriatic acid that occurred
during the unloading of a rail tanker and a hydrochloric acid spill due to a tank
rupture.  Sources of contamination include the former evaporation pond which was
filled with earthen materials and capped with concrete in 1980, a process drain
system and sump, settlement ponds (location unknown), a leach field, dioxin
removal wastes and contaminated soil.

History of Investigation

    Beginning in 1980, the site  was operated as a RCRA Interim Status Hazardous
Waste Storage Facility. Between 1983 and 1989, the owner/operator of the site was
cited for several violations by a state agency responsible for RCRA enforcement. In
1984, that agency advised the owner/operator of an alleged release from the property
to the environment and then initiated a Preliminary Assessment and a follow-up
Site Investigation. Additional field investigations were conducted by the state
agency between 1985 and 1987.

    In 1986, CERCLA enforcement activities were initiated.  This led to an
emergency action by EPA later that year to remove drums, cylinders and
contaminated material from the site. In 1987, EPA proposed that the site be placed
upon the National Priorities List. In 1988, the owner/operator agreed to undertake a
Remedial Investigation/Feasibility Study (RI/FS) which was completed in March
1990.  In  1989, the owner/operator notified the relevant agencies of its intent to close
its RCRA Part A Interim Status  Storage Facility.  In 1990, additional site sampling
was initiated under EPA's "Make Sites Safe" initiative.  This sampling found
evidence of high levels of dioxin on that part of the site where contaminated
materials had been removed as  part of EPA's 1986 emergency action. Consequently,
actions to stabilize  the contaminants on the site pending remediation were initiated.

    In March 1991, the Record  of Decision (ROD) was issued. In the ROD, EPA with
the concurrence of the state, specified soil and ground-water remediation measures
at the site but reserved the right to further modify the ground-water remedy because
the ground-water contamination had not been fully characterized. The ground-
water remedy specified consisted of a pump and treat system utilizing approximately
ten wells to capture and treat the contaminant plume. These wells were proposed to
be located along the northern and western boundaries of the site and to be operated
at an extraction rate of two gallons per minute.

Geologic Summary:

     This site is located in a valley  that was part of a Pleistocene great basin lake.
The surficial geology of the valley  is the result of successive expansions and
Page 3-40

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 Section 3t Model Applications                          Summary Description #4


 contractions of that great basin lake and glacial surges and retreats. The valley
 consists of alluvial  deposits which overlie and merge with deep, unconsolidated
 lacustrine sediments.  The alluvial deposits typically consist of silt and sand in the
 first several feet and mostly fine pebble gravel to a depth of 5 feet or more.  These
 deposits are of a deltaic type and are associated with the development of the valley
 drainage network.  The underlying lacustrine deposits consist of clay, silt, sand and
 gravel facies  that laterally intergrade with one another and result in laterally
 discontinuous layers.

     The uppermost soils at the site consist of a 2 to 6 foot layer of mixed fill
 material and  a 2 to 5 foot layer of clay to silty clay material beneath the fill material.
 Underlying the clay material is a sand to clayey to silty sand layer that extends to a
 depth of 15 to 18 feet and below this point a clayey layer begins.  Two borings to
 depths of 27 and 50 feet indicated that this clayey layer extends to at least a depth of
 50 feet and exhibits interfingering (clay, silt and sand) characteristic of the general
 geology of the valley.  A fluvial paleochannel consisting of fine to coarse grained
 sand appears to meander across the center of most of the site. The top of this
 channel lies 7 to 9 feet below the surface of the site and the channel is approximately
 6 to 8 feet deep.

 Ground-Water Hydrology Summary:

     There is some disagreement regarding the ground-water hydrology.  Prior
 studies by  the responsible party's consultants indicated that the site hydrogeology is
 consistent with the  regional hydrogeology and is composed of three distinct
 hydrogeologic units. These studies indicated that the uppermost unit is a shallow
 unconfined aquifer that begins 3 to 5 feet beneath the site and extends to a depth of
 15 to 18 feet.  This aquifer corresponds to the sand to clayey to silty sand layer
 discussed in the above paragraph.  Below this shallow aquifer lies the second
 hydrogeologic unit, a relatively impermeable confining layer which acts as a single
 confining bed that ranges from approximately 40 to 100 feet in thickness.  This unit
 corresponds to the clayey layer described in the above paragraph.  Below this
 confining unit lies a confined aquifer that consists of Quaternary deposits of day,
 silt, sand and gravel.  The maximum thickness of this aquifer is greater than 1000
 feet.

     The state agency responsible for environmental enforcement disagrees with the
 concept that there are two completely distinct aquifers underneath the site.  They
 take the position that the second hydrologic unit is not truly impermeable as there
 are interfingerings of sand and silt in the clay layer. Consequently, they believe that
 there is communication between the upper and lower hydrologic unit and all three
units should be  considered as  one aquifer with shallow and deep portions.  The
modeling team did not feel it was necessary to resolve this discrepancy in the
conceptual model given EPA's decision objectives and the fact that the modeling
focused solely on the upper 13.5 feet of the shallow aquifer.

     The shallow unconfined aquifer is not used as a drinking water supply because
of its poor  quality (e.g. high total dissolved solids, sulfide and chloride) and the low
yields to wells.  The direction of flow in this aquifer is generally to the west-
northwest,  which is consistent with the regional flow direction. In the late summer
there are several localized deviations in  the flow pattern as several ground-water

                                                                     Page 3-4*

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Section 3s  Model Applications                          Summary Description #4


mounds build and dissipate. The transmissivity of this aquifer is estimated to be 77
ft2 per day.  The recharge to this aquifer is primarily from upward flow through the
confining layer from the underlying confined aquifer and infiltration from
irrigation, precipitation and a nearby drainage ditch. This drainage ditch which runs
adjacent to  the site is hydraulically connected to the shallow unconfmed aquifer. In
the spring this ditch appears to recharge the aquifer while during the summer that
portion of the aquifer underlying the site appears to contribute 1.1 to 1.4 gallons per
minute to the flow in the ditch.

    The deep confined aquifer is a primary source of drinking water for the
surrounding metropolitan area.  Pumping tests from other studies indicate that the
transmissivity of this aquifer ranges from 4000 to 10,000 ft2. This aquifer was not
extensively studied for the purposes of managing this site because of the presence of
a thick confining layer above the aquifer and the upward movement of water from
this aquifer to the shallow aquifer.

Ground-Water  Contamination Summary:

    A wide variety of contaminants was found at the site including VOCs, SVOCs,
Pesticides, Herbicides, Dioxins and Furans. The major sources of contamination on
the site include a process drain system, a former evaporation pond, a yard drain
system and a septic system. The primary contaminants of concern in the ground
water are the indicator chemicals TCE, PGE, PCP and 2,4-D.  Ground-water samples
from monitoring wells indicated that these contaminants exceed maximum
contaminant levels (MCLS) as established under the Safe Drinking Water Act by up
to three orders of magnitude.  These contaminants are widely dispersed horizontally
and vertically in the shallow aquifer underlying the site. (See Figure 3.4-1.)
However, ground-water samples from monitoring  wells below the shallow aquifer
do not indicate that the contamination has extended into the  confining layer
separating the shallow aquifer from the deep confining aquifer.

    At the time the ROD was issued, the extent and origin of the contaminated
water found on the northern portion of the site had not been  fully characterized.
The ROD anticipated that further investigations and subsequent ground-water
remediation decisions would have to be made prior to the initiation of remedial
actions.

Modeling Summary:

    A series of analytic and analytic/numeric models were used to investigate the
site.  An analytic modeling approach was chosen as a function of EPA's decision
objectives and resource constraints. As this was an enforcement lead site, EPA's
responsibility was to review the responsible party's remediation plan and activities
to ensure they met regulatory and legal requirements.  Thus,  EPA's objective in
conducting this modeling was not to develop a definitive remedial design but to
gather sufficient information to be able to review the responsible party's
characterization of the site and the RD.

    New information, received since the issuance of the ROD, suggested the need
for the RD/RA to address ground-water contamination not previously thought to be
Page 3-42

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Section 3:  Model Applications                         Summary Description #4


connected with the site. Evidence suggested that the plume in the shallow aquifer
may have migrated off-site.  EPA desired to explore this possibility and to examine
its impact upon the proposed remedial design.  As these were review and not design
objectives, these decision objectives were not considered sufficient to warrant the
costs associated with a full fledged numerical modeling effort at this stage in the
remediation process.  Moreover, EPA and their contractor believed  that current data
on the site was not sufficient to support a numerical model.  Consequently, an
analytic modeling approach was chosen.

     The modeling was divided into two phases. The objective of the phase one
modeling was to determine the maximum extent of chloride and TCE
contamination in the  shallow aquifer.  An analytical function-driven variation of
the fate and transport model Random Walk was used in this phase. The objective
of the phase two modeling was to examine the effectiveness of proposed and
alternative extraction  well designs. Two models were used in this phase.  The
analytic flow model THWELLS was used to determine well field drawdown.  Then
the capture zones for the ground-water remedial alternatives were estimated using
the particle tracking module of the U.S. EPA Wellhead Protection Area (WHPA)
model called GFTRAC  This case study will focus on phase one of the modeling
which is the use of the Random Walk model to delineate the contaminate plume
and potential  sources.

     The analytical function-driven variation of the Random Walk model was
chosen for the phase one modeling because of its relative simplicity, prior contractor
experience and prior contractor verification of the model through a comparison of
its results with that of another well-respected model.  This version of the Random
Walk model utilizes an analytic function based upon the Theis equation to generate
the flow field. Then the numeric Random Walk model is applied to simulate the
fate and transport of the contaminants.

     The simplifying assumptions associated with the analytic flow component of
the Random Walk model required that the aquifer be treated as homogeneous,
isotropic and infinite in areal extent.  Thus, no site specific boundary conditions or
spatial variability in aquifer characteristics could be modeled. Moreover,
unidirectional, steady state ground-water flow had to be assumed. The modeling
team established a uniform hydraulic conductivity, saturated thickness,
transmissivity, hydraulic gradient and aquifer porosity for the modeled area based
upon information obtained from the RI report and the ROD. They assumed that
there was no precipitation recharge to the aquifer.

     Chloride was chosen as one of the two contaminants to be modeled because it is
mobile and non-retarded.  Thus, its plume would represent the outermost limits of
the plumes of the other contaminants of interest. Moreover, since chloride is a
conservative substance, it was hypothesized that the successful replication in the
model of the existing  chloride plume would be evidence that the simplifying
assumptions of the  analytic flow model did not unduly compromise the model
results given EPA's decision objectives. TCE was selected as the other contaminant
to be modeled because it is relatively toxic and ubiquitous to the site.
                                                                   Page 3-43

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Section 3r  Model Applications                          Summary Description #4


    The particle tracking component of the Random Walk model was used to
model the chloride releases as slugs that began in 1982 at four potential sources.  The
TCE releases were modeled as continuous releases that began in 1957 at eight
potential sources. The location of the sources and the timing of the releases were
inferred from soil and ground-water chemistry, information in the RI and the ROD
and model calibration.  The longitudinal and transverse dispersivities, background
concentrations and organic carbon partition coefficients were based upon field data
and established EPA methods. All ground-water contamination was assumed to
exist in the dissolved phase and consequently dense, nonaqueous phase liquid
migration was not simulated. Biodegradation and volatilization were also ignored.

    The calibration of the Random Walk model was restricted to the contaminant
fate and transport component. This version of Random Walk assumes a
unidirectional flow field which can not be directly calibrated against observed
piezometric heads. Reid data from the RI report was used to establish the flow field
parameters. Moreover, as was noted above, it was thought that the successful
calibration  of the chloride plume would serve as an indication of the
appropriateness of the assumed flow field.  Calibration of the contaminant transport
model was achieved by adjusting the number, location and release terms of the
sources until simulated concentrations matched field observations for twelve on-
site monitoring wells.  The calibration process was terminated when:
    •   The mean model error and standard deviation of errors were less than 10
         percent of the largest observed  field concentration;
    •   The regression analyses of field data versus model results yielded a
         correlation coefficient squared (r2) value greater than 0.90, (an r2 value of
         1.0 indicates perfect correlation  between the field data and the model data);
         and
    •   The shapes of the simulated plumes approximated the shapes of the
         plumes observed in the field.
    The calibration of the contaminant transport model required that the grid
nodes in the model be close to the physical location of the monitoring wells on the
site.  Considerable effort was made to do  this, but in order to determine the predicted
contamination concentrations at the monitoring wells, linear interpolation routines
ultimately had to be developed In retrospect, the modeling team realized that by
varying the location of the origin of the model grid, the grid nodes could have been
located precisely over the monitoring well  locations thus eliminating the need to
interpolate the contaminate concentrations and possibly improving  the calibration.
It was noted, however, by the modeling team that the shifting of the grid would
become very time consuming with a large number of wells.

    Difficulties were encountered calibrating the model. These difficulties caused
the modeling team to explore the possibility of the existence of undocumented on
and off-site sources. In an iterative fashion, sources were added to the model until
all calibration targets were met, the simulated plumes approximated the field
observable plumes and r2 values of 0.92 and 0.99 were obtained for the chloride and
TCE models respectively.  (See Figures 3.4-2 and 3.4-3.)  The reasonableness of the
location of these hypothetical contaminate sources was examined using site
information and aerial photographs of the site taken in the 1960's and 1980's.


Page  3-44

-------
Section 3;  Model Applications                          Summary Description #4


Interestingly, these photographs had not been available to the modeling team
during the calibration process, yet wherever a hypothetical source had been
introduced into the model in order to effect a better calibration, the aerial
photographs provided confirming evidence of the existence of a potential source at
that location.

     Because of budget limitations a sensitivity analysis was not performed to
determine the potential variations in the results as a function of changes in key
parameters or the removal of hypothetical sources.  In retrospect, the modeling
team felt additional resources should  have  been requested to perform a sensitivity
analysis.

Modeling Results Summary:

     The phase one modeling results indicated that the ground-water
contamination moved much further off-site than was estimated in the ROD.
Moreover, the model simulations suggested the possibility of off-site sources of
chloride and TCE contamination. (See Figure 3.4-4.)  Specifically, the model
indicated that the plume had migrated almost 450 feet north and a 150 feet west of
the site and covered a surface area over 1/3 larger than the contaminant plume
defined in the ROD.

     Four potential chloride sources and eight potential TCE sources were identified.
One of the chloride sources and three  of the TCE sources were located off-site. None
of these potential off-site sources had been identified in the ROD. Consequently,
EPA's concerns about the completeness of the field characterization were supported
by the modeling results.

     The phase one results were then used  to evaluate the proposed and alternative
pump and treat extraction well designs. This evaluation (not part of this case study)
determined that the proposed design of the pump and treat extraction wells would
not fully capture the contaminant plume because the plume had migrated so far off-
site. Moreover, it was determined that the proposed pumping rate would de-water
the aquifer.

     Based  upon the information developed in this modeling effort, EPA  directed
the Responsible Party to initiate further site characterization including a search for
additional off-site sources. The Agency also requested that the design of the
extraction wells be reviewed. However, the Agency and the modeling team were
careful to not assign certitude to the model  results. As was stated in the modeling
report, the simplifications associated with the use of analytic models and  the limited
field data available required that the results of this modeling effort be used with
great care.  Thus the Agency limited the use of the model results to:

     1.   Estimate the maximum dowrigradient and lateral extent of ground-water
         contamination;
     2.   Focus future field activities;
     3.   Provide insight into the location of additional potential sources; and
                                                                    Page 3-45

-------
Section 3s  Model Applications                          Summary Description #4


    4.   Provide preliminary ideas regarding the conceptual design of pump and
         treat alternatives.

Strengths And Interesting Features Of This Study:

    In this case study, a model was applied late in the remedial process to review
the completeness and accuracy of the site characterization and remedial  design
specified in the ROD. The decision and modeling objectives of this model
application were carefully limited so as not to exceed the limitations of the model
and available data.

    Perhaps the most striking aspect of this case was that the entire modeling effort
required only 180 hours. This was possible because the decision objectives of the
modeling effort were limited in such a way that relatively simple models and
simplifying assumptions could be used. Nonetheless, the information gained from
the modeling could be used to guide field characterization activities and to raise
significant concerns about the characterization of the site and the design of the
proposed extraction wells.  The ultimate consequences may be a considerable cost
savings through the implementation of a more  appropriate remedial design.

    Another interesting aspect of this study was the use of the model to identify the
location of previously undocumented potential sources of contamination and the
post modeling corroboration through the use  of aerial photographs.  This is  an
example of the power of relatively simple models when they are carefully used as
preliminary investigation tools.

    In retrospect, the Region noted that it might have been useful to conduct this
type of modeling during the RI/FS phase of the cleanup. The Region also noted that
additional modeling might be required later, once the additional site
characterization activities are completed. The Region suspected that should
additional modeling be performed, the level of certainty they would then require
would necessitate the use of a more sophisticated model and significantly more data.

Contacts:

    For further information about this ground-water study please contact:

    Bert Garcia              Region 8           Tel. # (303) 293-1526

Modeling Documents:

    Please contact the above person for specific modeling documents.
Page 3-46

-------
Section 3t Model Applications
                                                     Summary Description
                                   Figure 3.4-1

                            Chloride  Concentrations
                                                                   1
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                                                                    Page 3-47

-------
Section 3s Model Applications
Summary Description
                                   Figure 3.4-2


                     Location of Suspected Chloride Sources
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Page 3-4S

-------
Section 3t  Model Applications
Summary Description #4
                                Figure 3.4-3


                         Model Calibration - Chloride
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-------
Section 3:  Model Applications
Summary Description
                                   Figure 3.4-4



                   Estimated Maximum Extent of Contamination
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-------
4.0 - Model

-------
     4.0

                               Model  Descriptions

     Introduction

     This section provides summary and detailed descriptions for four ground-
water models that were selected as the initial set of models to be considered as part
of this pilot project. The four models are:

     O   MOC

     O   MODFLOW

     O   RANDOM  WALK

     O   PLASM

     While these models are generally well known and have been used often in
EPA programs, the inclusion of them in the Compendium does not represent an
endorsement of them by OSWER for any specific purpose.  In the future, OSWER
may develop guidelines for application of models under certain conditions or for
specified types of analyses, and add other models to the Compendium. At this time,
the descriptions are provided as general reference information only.

     Fact  Sheets

     The beginning of this section contains a two-sided Fact Sheet for each of the
models. These were developed based on comments received from EPA Regional
office staff, who identified a need to have quick access to some key model
descriptors. The Fact Sheets are designed to provide an "at a glance" overview of
the models' characteristics, scope, and applicability, as well as the name of a contact
for technical support and more information.

     Model Descriptions

     The latter part of this section contains  more detailed information on the same
set of four models. This information was extracted from a computerized database
maintained by the International Ground Water Modeling Center  (IGWMC) in
Golden, Colorado.  The information has been re-formatted, and in some cases, sub-
sections have been re-numbered and re-ordered, but the information itself has been
modified only  slightly.  IGWMC's database contains information  on many more
ground-water models. Using data that comes directly from the IGWMC database
will maintain the integrity of the information, if for example, OSWER wishes to
expand this portion of the Compendium in the future by taking larger extracts from
the IGWMC database.

-------
Section 4: Model Descriptions                                      Introduction


     Modeling Data Requirements

      There is often confusion about how modeling data requirements are
determined and the relationship between data requirements and the model (code).
It is  important to understand that the determination of a modeling application's
general data requirements should precede the selection of a model.  Furthermore,
the determination of the type, quantity, and accuracy of the data required for the
modeling application can be complex because it is dependent upon:

     1.   Management's reasons for performing the modeling and the subsequent accuracy
         and level of detail required of the modeling results. For example, a preliminary
         screening of alternative remedial technologies conducted as part of a
         remedial investigation and feasibility study can usually be modeled with
         less detail than a remedial design being modeled as part of the remedial
         design phase.

     2.   The physical processes and the characteristics of the site being modeled. For
         example, chemical fate and transport processes often require considerably
         more types of data than flow processes.  Moreover, the quantity and the
         accuracy required of the data are often a function of the types of chemicals
         being modeled or the  level of heterogeneity of the site.

     3.   The engineering objectives of the modeling. For example, the types and
         quantity  of data required to determine the effectiveness of a deep hydraulic
         barrier design  are often different from the data required to analyze a
         network  of ground-water extraction wells.

      Once the data requirements have been determined, a model can be selected
which will support these data requirements and provide management with the
information they need to make  informed decisions. Thus, the decision objectives,
process and site characteristics,  and engineering objectives are the factors which
primarily determine a model application's data requirements and, in turn, govern
the selection of a particular model.

      To determine if a model  will support an application's data requirements, the
reader is referred to the model descriptions that follow and the model
documentation that is usually available from the model's authors or the
International Ground Water Modeling Center.
Page 4-2

-------
    Model Fact Sheets
           For
          MOC
          MODFLOW
          PLASM
          RANDOM WALK
          SOURCE:
INTERNATIONAL GROUND WATER
      MODELING CENTER
          (IGWMC)

-------
Model Type:  Solute Transport
                                      MOC
                            (USGS-2D-TRANSPORT, KONBRED)
                                              Version 3.0
                            	Release Date: 11/89
                                                          Summary Updated  5/29/92
    MOC is a ground-water flow and mass transport model.  It provides capabilities for two dimensional simulation of
 non-conservative solute transport in heterogeneous, anisotropic aquifers. It computes changes in time in the spatial
 concentration distribution caused by convective transport, hydrodynamic dispersions, mixing or dilution from
 recharge, and chemical reactions. The chemical reactions include first-order sorption irreversible rate reaction (e.g.
 radioactive decay), equilibrium-controlled sorption with linear, Freundlich or Langmuir isotherms, and monovalent
 and/or divalent ion-exchange reactions. MOC solves the finite difference approximation of the ground-water flow
 equation using iterative ADI and SEP. It uses the method of characteristics followed by an explicit procedure to solve
 the transport equation. MOC uses a subgrid of the flow grid for simulation of containment transport.

 Note: A version of MOC called MOC Dense simulates two dimensional density dependent flow and transport in a
 crossectional plane. The specific characteristics of MOC Dense are not incorporated in this summary.
                                                Technical
                                                Assistance:


                           Dr. David S. Burden, Director
                           Center for Subsurface Modeling Support (CSMoS)
                           Robert S. Kerr Environmental Research Laboratory (RSKERL)
                           U.S. Environmental Protection Agency
                           P.O. Box 1198
                           Ada, OK 74820
                           (405) 332-8800
              Availability
         Usability
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          I
                    Reliability
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                                       I
                           Distributed By:
               International Ground Water Modeling Center
               Colorado School of Mines
               Golden, CO 80401, USA
               (303) 273-3103
               U.S. Geological Survey
               WRD WGS - Mail Stop 433
               National Center
               Reston, Virginia 22092
               Scientific Software Group
               P.O. Box 23041
               Washington D.C. 20026-3041
               (703) 620-9214
               Geraghty & Miller, Inc.
               Modeling Group
               1895 Preston Drive, Suite 301
               Reston, Virginia 22091
               (703) 476-0335
                                                  Scope
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                                                                                               Page 4-3

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Hardware Prime Preprocessors: PREMOC Postprocessors:
Platforms: DEC VAX MODELCAD
IBM PC/XT/AT
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Detailed information on this model, sources of distribution, and postprocessors and preprocessors
is available in The Ground-Water Modeling Compendium.



Page 4-4

-------
  Model Type: Saturated Flow
                                    MODFLOW
                                                           Summary Updated: 5/29/92
                                             Version 3.2
                                       Release Date: 10/89
    MODFLOW is a modular, block-centered finite difference model for the simulation of two dimensional and quasi-
  or fully-three-dimensional, transient ground-water flow in anisotropic, heterogeneous, layered aquifer systems. It
  calculates piezometric head distributions, flow rates and water balances. The model includes modules of flow
  towards wells, through riverbeds, and into drains. Other modules handle evapotranspiration and recharge. Various
  textual and graphic pre-and postprocessors are available.

  Note: Several particle tracking programs including ModPath utilize Modflow output to simulate contaminant
  transport. The specific characteristics of these particle tracking programs are not incorporated in this summary.


                                                Technical
                                                Assistance:

                           Dr. David S. Burden, Director
                           Center for Subsurface Modeling Support (CSMoS)
                           Robert S. Kerr Environmental Research Laboratory (RSKERL)
                           U.S. Environmental Protection Agency
                           P.O. Box 1198
                           Ada, OK 74820
                           (405) 332-8800
              Availability
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       Golden, CO 80401, USA
       (303) 273-3103
       U.S. Geological Survey
       WRD WGS - Mail Stop 433
       National Center
       Reston, Virginia 22092
       Scientific Publications Co.
       P.O. Box 23041
       Washington D.C. 20026-3041
       (703) 620-9214
       Geraghty & Miller, Inc.
       Modeling Group
       1895 Preston Drive, Suite 301
       Reston, Virginia 22091
       (703) 476-0335
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   Model Type: Saturated Flow
                                              PLASM
                                                                  Summary Updated: 5/29/92
                              Version - Illinois State Water Survey
                                          Release Date:  1985
      PLASM (Prickett Lonnquist Aquifer Simulation Model) is a finite difference model for simulation of transient,
   two-dimensional or quasi-three-dimensional flow in a single or multi-layered, heterogeneous, anistropic aquifer
   system. The original model of 1971 consisted of a series of separate programs for various combinations of
   simulation options. Later versions combined most of the options in a single code, including variable pumping
   rates, leaky confined aquifer conditions, induced infiltration from a shallow aquifer or a stream, storage coefficient
   conversion between confined and waterable conditions, and evapotranspiration as a function of depth to
   watertable.  The model uses the iterative alternating implicit method (IADI) to solve the matrix equation.
                                               Technical
                                               Assistance:


                           Dr. David S. Burden, Director
                           Center for Subsurface Modeling Support (CSMoS)
                           Robert S. Kerr Environmental Research Laboratory (RSKERL)
                           U.S. Environmental Protection Agency
                           P.O. Box 1198
                           Ada, OK 74820
                           (405) 332-8800
              Availability
         Usability
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                    Distributed By:
       International Ground Water Modeling Center
       Colorado School of Mines
       Golden, CO 80401, USA
       (303) 273-3103
       Thomas A. Prickett
       6 G.H. Baker Drive, Urbana IL 61801
       (217) 384-0615
       Illinois State Water Survey
       P.O. Box 232
       Urbana, Illinois 61801
       Ann Koch
       2921 Greenway Drive
       Ellicott City, Maryland 21043
       (301)461-6869
       Geraghty & Miller, Inc., Modeling Group
       1895 Preston Drive, Suite 301
       Reston, Virginia 22091
       (703)476-0335
                                                 Scope
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-------
  Model Type:  Solute Transport
                                       RANDOM WALK
                               Version - Illinois State Water Survey
                                           Release Date: 7/81
                                                          Summary Updated:  5/29/92
         RANDOM WALK/TRANS is a numerical model to simulate two-dimensional steady or transient flow and
      transport problems in heterogeneous aquifers under water table and/or confined or leaky confined conditions.
      The flow is solved using a finite difference approach and the iterative alternating direction implicit method. The
      advective transport is solved with a partide-in-cell method, while the dispersion is analyzed with the random
      walk method.

      Note: A number of other versions of Random Walk including analytical function driven versions are available.
      The specific characteristics of these other versions including output capababilities  vary considerably.
                                                Technical
                                                Assistance:

                             Dr. David S. Burden, Director
                             Center for Subsurface Modeling Support (CSMoS)
                             Robert S. Kerr Environmental Research Laboratory (RSKERL)
                             U.S. Environmental Protection Agency
                             P.O. Box 1198
                             Ada, OK 74820
                             (405) 332-8800
              Availability
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International Ground Water Modeling Center
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Golden, CO 80401, USA
(303) 273-3103

Thomas A. Prickett
6 G. H. Baker Drive
Urbana,IL 61801
(217) 384-0615

Bob Sinclair, Director of Computer Service
Illinois State Water Survey
Box 5050, Station A
Champaign, IL 61820
(217) 3334952

Geraghty & Miller, Inc., Modeling Group
1895 Preston Drive, Suite 301
Reston, Virginia 22091
(703) 476-0335
                                                  Scope
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(Neumann Condition)
Value Dependent Flux - A specified flux is given for a specified value. (Cauchy Condition)
Hardware Cyber 175 Preprocessors: PREWALK Postprocessors:
Platforms: VAX 11/780 MODFJLCAD
IBM PC/XT/AT








POSTWALK








Detailed information on this model, sources of distribution, and postprocessors and preprocessors
is available in The Ground-Water Modeling Compendium.
Page 4-10

-------
Detailed Model Descriptions
            For
          • MOC
          • MODFLOW
          • PLASM
          • RANDOM WALK
           SOURCE:
 INTERNATIONAL GROUND WATER
       MODELING CENTER
           (IGWMC)

-------
     Model Description For


             MOC
(USGS-2D- TRANSPORT/KONBRED)
           SOURCES
INTERNATIONAL GROUND WATER
       MODELING CENTER
           (IGWMC)

-------
                         Table of Contents

                                                                      PAGE

 1.   Model Identification	4a-1
      1.1.   Model Name(s)	4a-l
      1.2.   Date of First Release	4a-l
      1.3.   Current Version	4a-l
      1.4.   Current Release Date	4a-l
      1.5.   Author	4a-l

2.   Model Information..........	 4a-1
      2.1.   Model Category	4a-l
      2.2.   Model Developed For	4a-l
      2.3.   Units of Measurement Used	4a-l
      2.4.   Abstract	4a-l
      2.5.   Data Input Requirements	4a-2
      2.6.   Versions Exist For The Following Computer Systems	4a-2
      2.7.   System Requirements	4a-2
      2.8.   Graphics Requirements	4a-2
      2.9.   Program Information	4a-2

3.   General Model Capabilities.—..................	........	........ 4a-2
      3.1.   Parameter  Discretization	4a-2
      3.2.   Coupling	4a-2
      3.3.   Spatial Orientation	4a-3
      3.4.   Types of Possible Updates	4a-3
      3.5.   Geostatistics and Stochastic Approach	4a-3
      3.6.   Comments	4a-3

4.   Flow Characteristics[[[ 4a-3
      4.1.   Flow System Characterization	4a-3
      4.2.   Fluid Conditions	4a-4
      4.3.   Boundary Conditions	4a-4
      4.4.   Solution Methods for Flow	4a-4
      4.5.   Grid Design	4a-5
      4.6.   Row Output Characteristics	4a-5

5.   Mass Transport Characteristics...........................................4a-5
      5.1.   Water Quality Constituents	4a-5
      5.2.   Processes Included	4a-5
      5.3.   Boundary Conditions	4a-6
      5.4.   Solution Methods for Transport	4a-6
      5.5.   Output Characteristics for Transport	4a-6

6.   Evaluation[[[4a-6

-------
                                                                           PACE

7.   Documentation and Support........	4a-7
       7.1.   Documentation Includes	4a-7
       7.2.   Support Needs	4a-7
       7.3.   Level of Support	4a-7

8.   Availability...........................	4a-7
       8.1.   Terms	4a-7
       8.2.   Form	4a-7

9.   Pre and Post Processors.......	4a-8
       9.1.   Data Preprocessing	4a-8
       9.2.   Data Postprocessing	4a-8

10.  Institution of Model Development..................................	4a-8
       10.1.  Name	4a-8
       10.2.  Address	4a-8
       10.3.  Type of Institution	4a-8

11.  Remarks[[[ 4a-8


-------
                                   MOC

 1.    Model Identification

 1.1.   Model Name(s)
        •  USGS-2D-TRANSPORT
        •  MOC
        •  KONBRED

 1.2.   Date of First Release
        •  11/76

 1.3.   Current Version
        •  3.0

 1.4.   Current Release Date
        •  11/89

 1.5.   Author
        •  1. Konikow, L.F.
        •  2. Bredehoeft, J.D.

 2.    Model Information

 2.1.   Model Category
        •  ground-water  flow
        •  mass transport

 2.2.   Model Developed For
        •  general use (e.g. in field applications)

 2.3.   Units of Measurement Used
        •  SI system
        •  metric units
        •  US customary units
        •  any consistent system

2.4.  Abstract
      MOC is a two-dimensional model for the simulation of non-conservative
      solute transport in heterogeneous, anisotropic aquifers.  It computes changes
      in time in the spatial concentration distribution caused by convective
      transport, hydrodynamic dispersion, mixing or dilution from recharge, and
      chemical reactions.  The chemical reactions include first-order irreversible
      rate reaction (e.g. radioactive decay), equilibrium-controlled sorption with
      linear, Freundlich or Langmuir isotherms, and monovalent and/or divalent
      ion-exchange reactions.  MOC solves the finite difference approximation of
      the ground-water flow equation using iterative ADI and SIP.  It uses the
      method of characteristics followed by an explicit procedure to solve the
      transport equation.


                                                                   Pago 4m-1

-------
Section 4:  Model Descriptions	   Model Description for HOC

2.5.  Data Input Requirements:
      Data input requirements are provided in the model documentation and are
      discussed in the introduction to Section 4.0 of the Compendium.

2.6.  Versions Exist For The Following Computer Systems
        •  minicomputer
        •  workstations
        •  mainframe
        •  microcomputer

        •  Make/Model
          ~ Prime
          ~ DEC VAX
          -IBM PC/XT/AT
             - operating system
              MS DOS
          - IBM 80386/486
             - operating system
              MS DOS
              OS/2
              Unix
          ~ Apple Macintosh

2.7.  System Requirements
        •  core memory (RAM) for execution (bytes)
          - 640Kb (standard IBM PC version)
        •  mass storage (disk space in bytes)
          - at least 2Mb for data files
        •  numeric/math coprocessor
          — (for micro computers)
        •  compiler required
          — (for  mainframe)

2.8.  Graphics Requirements
        •  none

2.9.  Program Information
        •  programming language/level
          - Fortran 77
        •  number of program statements (total)
          - 2000

3.   General Model Capabilities

3.1.  Parameter Discretization
        •  distributed

3.2.  Coupling
        •  none
Page 4a-2

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Sect/on 4:  Model Descriptions                         Model Description for HOC

3.3.  Spatial Orientation
        •   saturated flow
        •   2D-horizontal
        •   2D-vertical

3.4.  Types of Possible Updates
        •   parameter values
        •   boundary conditions

3.5.  Geostatistics and Stochastic Approach
        •   none

3.6.  Comments
        •   This model has restart capability


4.   Flow Characteristics

4.1.  Flow  System Characterization
        •   Saturated Zone

        •   System
           —   single aquifer

        •   Aquifer Type(s)
           -   confined
           -   semi-confined (leaky-confined)

        •   Medium
           —   porous media

        •   Parameter Representation
           —   homogeneous
           -   heterogeneous
           —   isotropic
           —   anisotropic

        •   Flow Characteristics (Saturated Zone)
           —   laminar flow
           —   linear (Darcian flow)
           —   steady-state
           -   transient

        •   Flow Processes Included
           —   areal recharge
           —   induced recharge (from river)

        •   Changing aquifer conditions
              —  in space
              —  variable thickness

                                                                    Page

-------
Section 4i Model Descriptions                        Model Description for HOC

       •  Well Characteristics
          —  none

       •  Unsaturated Zone
          —  none

4.2.  Fluid Conditions
       •  Single Fluid Flow
          -  water

       •  Flow  of Multiple Fluids
          —  none

       •  Fluid Properties
          —  constant in time/space

4.3.  Boundary Conditions
       •  First Type - Dirichlet
          —  head/pressure

       •  Second type - Neumann (Prescribed Flux)
          —  injection/production wells
          —  no flow boundary
          —  areal boundary flux
          —  ground-water recharge

       •  Third Type - Cauchy
          —  head/pressure-dependent flux

4.4.  Solution Methods for Flow
       •  General Method
          —  Numerical

       •  Spatial Approximation
          —  finite difference method
          —  block-centered

       •  Time-Stepping Scheme
          -  Crank-Nicholson

       •  Matrix-Solving Technique
          -  SIP
          -  iterative ADIP
Page 4a-4

-------
 Section 4: Model Descriptions                        Model Description for MQC

 4.5.   Grid Design
        •  Cell/Element Characteristic
           -  constant cell size
           —  variable cell size

        •  Possible Cell Shapes
           —  2D-square
           -  2D-rectangular

        •  Maximum Number of Nodes
           -  2000

 4.6.   Flow Output Characteristics
        •  Simulation Results
           —  Head/Pressure/Potential
              -   ASCII file (areal values)
              -   ASCH file (hydrograph)

        • Water Budget Components
          -  ASCH file (global total area)


 5.    Mass Transport  Characteristics

5.1.   Water  Quality Constituents
          any component(s)
          single component
          total dissolved solids (TDS)
          inorganics
          organics
          radionuclides

5.2.  Processes Included
        • (Conservative) Transport
          —  advection
          —  dispersion (isotropic; anisotropic)
          —  diffusion

        • Phase Transfers
          -  Solid <-> Liquid
              -   sorption equilibrium isotherm
              -   linear
              -   Langmuir
              -   Freundlich

        • Fate
          -  first-order radioactive decay (single mother/daughter decay)
          -  first-order chemical decay
          —  first-order microbial decay

-------
Sect/on 4i  Model Descriptions                        Model Description for MOC

5.3.  Boundary Conditions
        •  First Type - Dirichlet
           -  Chemical processes embedded in transport equation
           -  concentration

        •  Second Type - Neumann (Prescribed Solute Flux)
           —  areal boundaries
           —  injection wells
           —  point sources
           —  line sources
           —  areal sources

5.4.  Solution Methods for Transport
        •  General Method
           —  numerical
           —  uncoupled flow and transport equation

        •  Spatial Approximation
           —  finite difference method
           —  block-centered
           —  particle-tracking

        •  Time-Stepping Scheme
           -  fully explicit

        •  Matrix-solving Technique
           -  method of characteristics

5.5.  Output Characteristics for Transport
        •  Simulation  Results
           —  Concentration in Aquifer/Soil
              -   ASCII file (areal values)
              -   ASCH file (time series)

        •  Mass Balance Components
           -  ASCH file (global total area)


6.   Evaluation

6.1.  Verification/Validation
           verification (analytic solutions)
           laboratory data sets
           field datasets (validation)
           synthetic datasets
           code  intercomparison

6.2.  Internal Code Documentation (Comment Statements)
        •  incidental
Page 4a-6

-------
Section 4: Model Descriptions                        Model Description for HOC

6.3.  Peer (Independent) Review
        •  concepts
        •  theory (math)
        •  coding
        •  accuracy
7.   Documentation and Support

7.1.  Documentation Includes
       •  model theory
       •  user's instructions
       •  example problems
       •  code listing

7.2.  Support Needs
       •  Can be used without support
       •  Support is available
          — from author
          — from third parties

7.3.  Level of Support
       •  limited
       •  support agreement available
8.   Availability

8.1.  Terms
       •  available
       •  public domain
       •  proprietary

8.2.  Form
       •  source code only (tape/disk)
       •  source and compiled code
       •  compiled code only
                                                                  Pago 4m-7

-------
Section 4:  Model Descriptions                       Model Description lor HOC

9.   Pre and Post Processors

9.1.  Data Preprocessing
        •   name:  PREMOC
           — separate (optional) program
           — generic (can be used for various models)
           - textual data entry/editing

        •   name:  MODELCAD
           — separate (optional) program
           — generic (can be used for various models)
           - textual data entry/editing
           - graphic data entry/modification  (e.g manual grid design, arrays)
           — data reformatting (e.g. for GIS)
           - error-checking
           — help screens

9.2.  Data Postprocessing
           •  name:  POSTMOC
           •  separate (optional) program
           •  reformatting (e.g. to standard formats)
10.  Institution of Model Development

10.1. Name
       •  U.S. Geological Survey

10.2. Address
       •  National Center
          Reston, Virginia

10.3. Type of Institution
       •  federal/national government
11.  Remarks

The MOC package distributed by the International Ground Water Modeling Center
includes a preprocessor (PREMOC) to prepare input files, a postprocessor
(POSTMOC) to reformat parts of the output file to allow the import the results in
graphic display programs, and two versions of the MOC simulation program,
MOCADI and MOCSIP. MOCADI and MOCSIP are identical apart from the methods
used to solve the finite difference flow equations.  The IGWMC distributes both
IBM-PC and mainframe versions.
Page 4a-8

-------
 Section 4:  Model Descriptions                        Model Description for MOC

 Contact the International Ground Water Modeling Center for latest information:

       IGWMC USA:    Inst. for Ground-Water Res. and Educ.,
                        Colorado School of Mines,
                        Golden, CO 80401, USA.

       IGWMC Europe:   TNO Institute of Applied Geoscience,
                        P.O. Box 6012, 2600JA Delft,
                        The Netherlands.

 IBM-PC, Macintosh and mainframe versions of the MOC code are also available
 from:

                         Scientific Software Group
                         P.O. Box 23041
                         Washington, D.C. 20026-3041
                         (703) 620-9214


 MOCGRAP is a program developed by TECSOFT, Inc. to provide graphics capability
 to MOC. It uses the output from MOC to contour heads and concentrations and to
 plot velocity vectors. It supports a  variety of graphic screen formats, printers and
 plotters. MOCGRAF requires TECSOFTs TRANSLATE program.  MOCGRAF is
 available from Scientific Software Group


 MACMOC is the implementation of the USGS Method of Characteristics
 Solute Transport Model  (MOC) for the Apple Macintosh. The data input
 editor, simulation code and output postprocessor are integrated in a single
 application. Graphic output includes head and concentration contouring,
 and velocity vector plotting.  It requires a Macintosh Plus with System 6.02
 and Finder 6.1 or higher and at least 2Mb RAM.  MACMOC is available
 from the Scientific Software Group.

 Notes on computer program updates have been published by the USGS, Reston,
 Virginia, on the following dates:

         1. May  16,1979            7. Jul. 26,1985            13. Oct. 20,1986
         2. Mar.  26,1980            8. Jul. 31,1985            14. Mar. 2,1987
         3. Dec.  4,1980             9. Aug. 2,1985           15. Mar. 5,1987
         4. Aug. 26,1981          10. Aug. 8,1985           16. Jan. 29,1988
         5. Oct. 12,1983           11. Aug. 12,1985           17. Nov. 21,1988
         6. Jun. 10,1985          12. Jul.  2,1986            18. Jul. 20,1989

A modification of this model to track representative water of tracer particles initially
loaded along specific lines has been developed by Garabedian  and Konikow (1983):

-------
Section 4s  Model Descriptions                        Model Description for MOC

   TRACK (see IGWMC key # 0741).


The code has been modified by Hutchinson to allow head-dependent flux as a
boundary condition:
        y

   Hutchinson, C.B. et al. 1981. Hydrogeology of Well-field Areas near Tampa,
      Florida. USGS Open-File Report  81-630.


A modification to allow linear  and non-linear  sorption isotherms and first-order
decay was introduced in 1982:

   Tracy, J.V.  1982. Users Guide and Documentation for Adsorption and Decay
      Modifications of  the USGS Solute Transport Model.  NUREG/CR-2502, Div.
      of Waste Management, Off. of Nuclear Material Safety and Safeguard, U.S.
      Nuclear Regulatory Comm., Washington, D.C.


MODELCAD is a graphical oriented, model-independent preprocessor to prepare
and edit input files for  two- and  three-dimensional ground-water models, including
aquifer properties, boundary conditions, and grid dimensions. The program
prepares input files for  MODFLOW, MOC, PLASM and RANDOM WALK, among
others.  File formatting  routines for other models are available upon request.
Contact:

                        Geraghty & Miller Modeling Group
                        1895 Preston  White  Drive
                        Suite 301, Reston, VA 22091
                        (703) 476-0335
   Strecker,E.W., W-S. Chu, and D. P. Lettenmaier. 1985. Evaluation of Data
      Requirements for Groundwater Contaminant Transport Modeling. Water
      Resources Series, Techn. Rept. 94, Univ. of Washington, Seattle, Wash.


In this study a parameter identification algorithm was used together with the USGS-
MOC code and applied to two synthetic aquifers, evaluating the effects of data
availability and uncertainty on ground-water contaminant transport prediction.
The parameter identification algorithm is based on constrained least-squares
minimization.

Also:

   Strecker, E.W., and W-s. Chu. 1986.  Parameter Identification of a Ground-Water
      Contaminant Transport Model. Ground Water, Vol. 24(1), pp. 56-62.
Page 4a-f 0

-------
Sect/on 4s  Model Descriptions                        Model Description for MOC

A modified version of the 1978 version of the USGS MOC model has been presented
by Kent et Al. (1983; see references). Modifications include water-table option for
flow and non-linear sorption.  The same authors developed a  menu-driven,
preprocessor  for their version of MOC. For more information contact Dr. Douglas C.
Kent, School  of Geol., Oklahoma State University,  Stillwater, Oklahoma.


A stochastics-based analysis of the performance of the MOC model in remedial
action simulations is discussed in:

   El-Kadi, A.I.  1988. Applying the USGS Mass-Transport Model (MOC) to
      Remedial Actions by Recovery Wells.  Ground Water, Vol.  26(3), pp. 281-288.


An IBM PC/386 extended memory version of this model is also available  from:

                         Geraghty & Miller, Inc.
                         Modeling Group
                         1895 Preston Drive, Suite 301
                         Reston, VA 22091
                         tel.: 703/476-0335
                         fax: 703/476-6372
                                                                    Page 4a-11

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Sect/on 4:  Model Descriptions                        Model Description for HOC

12.  References

   Finder, G.F. and H.H. Cooper. 1970. A Numerical Technique for Calculating the
      Transient Position of the Saltwater Front.  Water Resources Research, Vol.
      6(3), pp. 875-882.

   Bredehoeft, J.D., and G.F. Finder.  1973. Mass Transport in Flowing
      Groundwater.  Water Resources Research,  Vol. 9(1), pp. 194-210.

   Konikow, L.F., and J.D.  Bredehoeft.  1974. Modeling Flow and Chemical Quality
      Changes in an Irrigated Stream-Aquifer System.  Water Resources Research,
      Vol. 10(3), pp. 546-562.

   Konikow, L.F., and J.D. Bredehoeft.  1978. Computer Model of Two-Dimensional
      Transport and Dispersion in Ground Water. USGS Techniques of Water
      Resources Investigations, Book 7, Chapter  2, U.S. Geological Survey, Reston,
      Virginia.

   Kent, D.C., J. Alexander, L. LeMaster, and J. Wagner. 1983. Interactive
      Preprocessor Program  for the U.S.G.S. Konikow Solute Transport Model.
      Oklahoma State University, School of Geology, Stillwater, Oklahoma.

   Kent, D.C., M.M. Hoque, L. LeMaster, and J. Wagner.  1983. Modifications to the
      U.S.G.S. Solute Transport Model. School of Geology, Oklahoma State
      University, Stillwater,  Oklahoma.

   Goode, D.J., and L.F. Konikow. 1989. Modification of a Method-of-Characteristics
      Solute Transport Model to Incorporate Decay and Equilibrium-Controlled
      Sorption or Ion Exchange. USGS Water Resources Investigations Report 89-
      4030, U.S. Geological Survey, Reston,  Virginia.
Page 4a-12

-------
 Section 4; Model Descriptions                        Model Description for MOC

 13.  Users

    Spinazola, J.M., J.B. Gillespie, and RJ. Hart. Ground-Water Flow and Solute
      Transport in the Equus Beds Area, South Central Kansas, 1940-79. Water-
      Resources Investig. Rept. 85-4336, Lawrence, Kansas.

      The transport model was used to study the movement of chloride in the past
      and under the various proposed pumping development schemes. The
      sources of the chloride is oilfield brine moving towards the wellfields and the
      Arkansas river.

    Robertson, J.B.  1974. Digital Modeling of Radioactive and Chemical Waste
      Transport in the Snake River Plain Aquifer at the National Reactor Testing
      Station, Idaho.  USGS Open-File Report IDO-22054. U.S. Geological Survey,
      Boise, Idaho.

    Konikow, L.F. 1977. Modeling Chloride Movement in the Alluvial Aquifer at
      the Rocky Mountain Arsenal, Colorado. USGS Water Supply Paper 2044, U.S.
      Geological Survey, Denver, Colorado.

    Sohrabi, T. 1980.  Digital Transport Model Study of Potential Nitrate
      Contamination from Sceptic Tank Systems near Edmond, Oklahoma.  Rept.
      80-38, National Center for Ground Water Research, University of Oklahoma,
      Norman, Okla.

    Sophocleous, M.A.  1984.  Groundwater Flow Parameter Estimation and Quality
      Modeling of the Equus Beds Aquifer in Kansas, USA. Journ. of Hydrology,
      Vol. 69, pp. 197-222.

      In an accompanying Technical Completion Report of the Kansas Water
      Resources Research Institute at the University of Kansas, Lawrence,
      Sohocleous et al. compares the MOC code with Finder's ISOQUAD-4 code and
      Grove's finite difference solute transport code.

    Freeberg, K.M.  1985.  Ground Water Contaminant Modeling Applied to Plume
      Delineation and Aquifer Restoration at an Industrial Site. M.Sc. Thesis, Dept.
      of Env.  Sciences and Eng., Rice Univ., Houston, Texas.

    Groschen, G.E.  1985. Simulated Effects of Projected Pumping on the Availability
      of Fresh Water in the Evangeline Aquifer in an Area Southwest of Corpus
      Christi, Texas. USGS Water Resources Investigations Report 85-4182, Austin,
      Texas.

    Chapelle, F.H. 1986. A Solute Transport Simulation of Brackish Water Intrusion
      near Baltimore, Maryland.  Ground Water, Vol.  24(3), pp  304-311.

      The model was used to estimate the future movement of the brackish-water
      plume in the coarse sands and gravels of the Patuxent Formation based on
      alternative strategies of aquifer use.  (see also  Maryland Geological Survey
      Report of Investig. 43 (1986)).


""~"~~'~~1—"~~~"^                   Page 4»-13

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Sect/on 4:  Model Descriptions                         Model Description for MOC

   Davis, A.D.  1986.  Deterministic Modeling of Dispersion in Heterogeneous
      Permeable Media.  Ground Water, Vol. 24(5), pp. 609-615.

   Perez, R. 1986.  Potential for Updip Movement of Saline Water in the Edwards
      Aquifer, San Antonio, Texas. USGS Water Resources Investigations Report
      86-4032, U.S. Geological Survey, Austin, Texas.

   Bond, L.D., and J.D. Bredehoeft. 1987. Origins of Sea water Intrusion in a Coastal
      Aquifer—A Case Study of the Pajaro Valley, California.  Journ. of Hydrology,
      Vol. 92, pp.363-388.

   Mixon, P.O., A.S. Damle, R.S. Truesdale, and C.C. Allen. 1987. Effect of
      Capillarity and  Soil Structure on Flow in Low permability Saturated Soils at
      Disposal Facilities.  EPA/600/2-87/029, Hazardous Waste Eng. Research Lab.,
      U.S. Environmental Protection Agency, Cincinnati, Ohio.

   Patterson, C-V.  1987.  Risk Analysis of Annular Disposal of Oil and Gas Well
      Brines. M.Sc. Thesis, Dept. of Systems Eng., Case Western Reserve
      University, Cleveland,  Ohio.

   Al-Layla, R., H. Yazicigil, and R. de Jong.  1988. Numerical Modeling of Solute
      Transport Patterns in the Damman Aquifer. Water Resources Bulletin, Vol.
      24(1), pp. 77-85.

      Used to predict the extent of the saline intrusion in this carbonate rock aquifer
      in the Kingdom of Saudi Arabia and studying the effects of changes in the
      hydrologic regime on TDS concentration. The model was modified to
      include the effects  of salt gradients resulting from vertical leakage into the
      host aquifer.

   Satkin, R.L., and P.b. Bedient. 1988. Effectiveness of Various Aquifer Restoration
      Schemes under Variable Hydrogeologic Conditions. Ground Water, Vol.
      26(4), pp. 488-498.

   Yager, R.M. and M.P.  Bergeron. 1988. Nitrogen Transport  in a Shallow Outwash
      Aquifer at Olean, Cattaraugus County, New York. Water-Resources
      Investigations Report 87-4043, U.S. Geological Survey, Ithaca, New York.
Page 4a-14

-------
      Model Description For
         MODFLOW
           SOURCE:
INTERNATIONAL GROUND WATER
       MODELING CENTER
           (IGWMC)

-------
                      Table of Contents
                                                                    PAGE
 1.   Model Identification ......... .......................... . .......... ........ ..... 4b-1
       1.1.    Model Name(s) [[[ 4b-l
       1.2.    Date of First Release [[[ 4b-l
       1.3.    Current Version # [[[ 4b-l
       1.4.    Current Release Date [[[ 4b-l
       1.5.    Authors [[[ 4b-l

 2.   Model Information ..... .......... ....... .. ................ ...................... 4b-1
       2.1.    Model Category [[[ 4b-l
       2.2.    Model Developed For [[[ 4b-l
       2.3.    Units of Measurement Used [[[ 4b-l
       2.4.    Abstract [[[ 4b-l
       2.5.    Data Input Requirements [[[ 4b-l
       2.6.    Versions Exist for the Following Computer Systems ................ 4b-2
       2.7.    System Requirements [[[ 4b-2
       2.8.    Graphics Requirements [[[ 4b-2
       2.9.    Program Information [[[ 4b-2

 3.   General Model  Capabilities................................................ 4b*2
       3.1.    Parameter Discretization [[[ 4b-2
       3.2.    Coupling [[[ 4b-2
       3.3.    Spatial Orientation [[[ 4b-2
       3.4.    Types of Possible Updates [[[ 4b-3
       3.5.    Geostatistics and Stochastic Approach .......................................... 4b-3
       3.6.    Comments [[[ 4b-3

 4.   Flow Characteristics[[[ 4o-3
       4.1.    Row System Characterization [[[ 4b-3
       4.2.    Fluid  Conditions [[[ 4b-4

-------
                                                                       PAGE

8.   Pre and Post Processors	4b-6
       8.1.   Data Preprocessing	4b-6
       8.2.   Data Postprocessing	4b-7

9.   Institution  of Model  Development..	4b-7
       9.1    Name	4b-7
       9.2.   Address	4b-7
       9.3.   Type of Institution	4b-7

10.  Remarks	4b-7

11.  References................	 4b-1 1

12.  Users	 4b-12
Page 4b-ii

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                           MOD FLOW

 1.   Model Identification

 1.1.   Model Name(s)
        •  MODFLOW

 1.2.   Date of First Release
        •  6/83

 1.3.   Current Version #
        •  3.2

 1.4.   Current Release Date
        •  10/89

 1.5.   Authors
        •  1. McDonald, M.G.
        •  2. Harbaugh, A.W.


 2.    Model Information

 2.1.   Model Category
        •  ground-water flow

 2.2.   Model Developed For
        •  general use (e.g. in field applications)
        •  research (e.g. hypothesis/theory testing)
        •  demonstration/education

 2.3.   Units of Measurement Used
        •  SI system
        •  metric units
        •  any  consistent system

 2.4.   Abstract
      MODFLOW is a modular, block-centered finite difference model for the
      simulation of two-dimensional and quasi- or fully-three-dimensional,
      transient  ground-water flow in anisotropic, heterogeneous, layered
      aquifer systems.  It calculates piezometric head distributions, flow rates
      and water balances. The model includes modules for flow towards
      wells, through riverbeds, and into drains. Other modules handle
      evapotranspiration and recharge.  Various textual and graphic pre- and
      postprocessors are available.

2.5.  Data Input Requirements:
      Data input requirements are provided in the model documentation
      and are discussed in the introduction to  Section 4.0 of the Compendium.
                                                              Page 4b-1

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Section 4:  Model Descriptions            Model Description for MODFLOW

2.6.  Versions Exist for the Following Computer Systems
          supercomputer
          minicomputer
          workstations
          mainframe
          microcomputer

        •  Make/Model
          -  IBM-PC/XT/AT
             -  operating system
                DOS 2.1 or later
          -  DEC VAX 11/780
          -  PRIME 750
          -  Macintosh
          -  Intel 80386/80486 based computers

2.7.  System Requirements
        •  core memory (RAM) for execution (bytes)
          -  640Kb (standard IBM PC version)
        •  mass storage (disk space in bytes)
          -  at least 2Mb for data files
        •  numeric/math coprocessor
          —  (for micro computers)
        •  compiler require
          —  (for  mainframe)

2.8.  Graphics Requirements
        •  none

2.9.  Program Information
        •  programming language /level
          -  Fortran 77
        •  number of program statements (total)
          -  5000 lines
        •  size of runtime (compiled) version (bytes)
          -  580Kb (IBM-PC version)
3.   Genera/ Model Capabilities

3.1.  Parameter Discretization
        •  distributed

3.2.  Coupling
        •  N.A.

3.3.  Spatial Orientation
        •  saturated flow
        •  2D-horizontal
        •  2D-vertical
        •  3D-layered (quasi 3D)

Page 4b-2

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Section 4i  Model Descriptions             Model Description for iiODFLOW

3.4.  Types of Possible Updates
        •  parameter values
        •  boundary conditions

3.5.  Geostatistics and Stochastic Approach
        •  optional

3.6.  Comments
        •  This model has restart capability.


4.   Flow Characteristics

4.1.  How System Characterization
        •  Saturated Zone

        •  System:
          —  single aquifer
          —  single aquifer/aquitard system
          —  multiple aquifer/aquitard systems

        •  Aquifer Type(s)
          —  confined
          —  semi-confined (leaky-confined)
          -  unconfined (phreatic)

        •  Medium:
          —  porous media

        •  Parameter Representation
          —  homogeneous
          —  heterogeneous
          —  isotropic
          -  anisotropic

        •  Flow Characteristics (Saturated Zone)
          —  laminar flow
          —  linear (Darcian flow)
          —  steady-state
          —  transient

        •  Flow Processes Included
          —  areal recharge
          —  induced recharge  (from river)
          —  evapotranspiration

        •  Changing Aquifer Conditions
          —  in space
             -   variable thickness
             -   confined/unconfined
             -   pitching aquitard

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Sect/on 4s Model Descriptions             Model Description for MODFLOW

           —  in time
              -  desaturation(saturated/unsat.)
              -  confined/unconfined
              -  resaturation of dry cells

        •  Well Characteristics
           —  partial penetration

4.2.  Fluid Conditions
        •  Single Ruid Flow
           —  water

        •  Flow of Multiple Fluids
           -  N.A.

        •  Fluid Properties
           —  constant in time/space

4.3.  Boundary Conditions
        •  First Type - Dirichlet
           —  head/pressure

        •  Second Type - Neumann (Prescribed Flux)
           -  injection/production wells
           —  no flow boundary
           —  areal boundary flux
           —  ground-water recharge
           —  seepage face
           —  springs
           —  induced infiltration

        •  Third Type - Cauchy
           -  head/pressure-dependent flux
           —  free surface  (steady-state; movable)

4.4.  Solution Methods for  Flow
        •  General Method
           -  Numerical

        •  Spatial Approximation
           -  finite difference method
           —  block-centered

        •  Time-Stepping Scheme
           —  fully  implicit

        •  Matrix-Solving Technique
           -  Iterative
           -  SIP
           -  LSOR


Page 4b-4

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Section 4i Model Descriptions            Model Description lor iiODFLOW

4.5.  Grid Design
        •  Cell/Element Characteristic
           —  constant cell size
           —  variable cell size
           -  3D-hexahedral

        •  Possible Cell Shapes
           —  2D-square
           —  2D-rectangular
           -  3D-cubic

        •  Maximum Number of Nodes
           -  9999
4.6.  Row Output Characteristics
        • Simulation Results
          —  Head / Pressure /Potential
              -   binary file (areal values)
              -   ASCII file (areal values)
              -   binary file (hydrograph)
              -   ASCH file (hydrograph)
          —  Fluxes/Velocities
              -   binary file (areal values)
              -   ASCH file (areal values)
              -   binary file (temporal values)
              -   ASCII file (temporal values)
          —  Water Budget Components
              -   ASCn file (cell-by-cell values)
              -   ASCH file (global total area)
5.   Evaluation

5.1.  Verification/Validation
        •  verification (analytical solutions)
        •  synthetic datasets
        •  code intercomparison

5.2.  Internal Code Documentation (Comment Statements)
        •  sufficient

5.3.  Peer (Independent) Review
           concepts
           theory (math)
           coding
           accuracy
           documentation
           usability
                                                               Pag* 4b-3

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Section 4i Model Descriptions             Model Description lor MODFLOW

6.   Documentation and Support

6.1.  Documentation Includes
          model theory
          user's instructions
          example problems
          code listing
          program  structure and development
          verification/validation

6.2.  Support Needs
        •  Can be used without support
        •  Support is available
          —  from author
          —  from third parties

6.3.  Level of Support
        •  limited
        •  support agreement available


7.   Availability

7.1.  Terms
        •  available
        •  public domain
        •  proprietary

7.2.  Form
        •  source code only (tape/disk)
        •  source and compiled code
        •  compiled code only
        •  paper listing of source code


8.   Pro  and Post Processors

8.1.  Data Preprocessing
        •  name: MODELCAD
          -  separate (optional) program
          -  graphic data entry/modification (e.g manual grid design,
             arrays)
          -  (semi-) automatic grid generation
          -  data reformatting (e.g. for GIS)
          —  error-checking
          -  help screens

        •  name: PREMOD
          -  part of model package (dedicated)
          -  textual data entry/editing

Page 46-6

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Section 4i Model Descriptions            Model Description for MODFLOW

8.2.  Data Postprocessing
       •  name: POSTMOD
          -  part of model package (dedicated)
          -  textual data display on screen/printer
          -  reformatting (e.g. to standard formats)
9.   Institution of Model Development

9.1   Name
       U.S. Geological Survey

9.2.  Address
       Ground Water Branch
       WRD WGS - Mail Stop 433
       National Center
       Reston, Virginia 22092

9.3.  Type of Institution
       •  federal/national government


10.  Remarks

The code is available from the U.S.G.S. on tape ($40). Contact Arlen
Harbaugh (see contact address). The documentation (paper copy $69.95,
microfiche $3.50) is available from:

U.S. Geological Survey
Open-File Service Section
Branch of Distribution
Box 25425, Federal Center
Denver, CO 80225

Various MODFLOW implementations for IBM-PC and main frame systems
are also available from the International Ground Water Modeling Center (see
also MARS # 3983, 3984, 3985, and 3986), including MODFLOW PC for IBM
PC/XT/AT (640K), and MODFLOW PC/EXT for extended memory Intel
80386/80486 based computers (2Meg,4Meg) which includes a preconditioned
conjugate gradient solver and a stream-flow routing package.

           IGWMC USA:    Inst. for Ground-Water Res. and Educ.,
                             Colorado School of Mines,
                             Golden, CO 80401, USA.

           IGWMC Europe:  TNO Institute of Applied Geoscience,
                             P.O. Box 6012, 2600JA Delft,
                             The Netherlands.
                                                             Page 46-7

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 Section 4i  Model Descriptions	Model Description for MODFLOW

 Wagner, Heindel and Noyes Inc. has implemented MODFLOW on a Hewlett-
 Packard microcomputer (series 200).  Contact Jeffrey E. Noyes, Geologist:

 Wagner, Heindel and Noyes, Inc.
 285 North St.
 Burlington, Vermont 05401
 phone: (802) 658-0820.


 Various implementations of MODFLOW are available from:

 Scientific Publications Co.
 P.O. Box 23041
 Washington, DC 20026-3041
 phone: 703/620-9214
 fax: 703/620-6793.

 Versions included:

       MODFLOW/PC for IBM PC/XT/AT (640K)

       MODFLOW/EM for extended memory Intel 80386/80486 based
       computers (2Meg,4Meg) which includes a preconditioned conjugate
       gradient solver and a stream-flow routing package.

 MOCGRAF is a program developed by TECSOFT, Inc. to provide graphics
 capability to MODFLOW.  The menu-driven MODGRAF program uses the
 output from MODFLOW to automatically contour heads and drawdowns
 from each layer, stress period and time step and superpose velocity vectors on
 the head contour plots. The program requires TECSOFTs TRANSLATE
 program. A special 80386/486 version is available. Contact:

                       Scientific Software Group
                       P.O. Box 23041
                       Washington, D.C. 20026-3041
                       phone 703/620-9214.

 MODPATH: a particle-tracking program developed by the USGS for use with
 the MODFLOW model.  MODPATH  calculates the path a particle would take
 in a steady-state three-dimensional flow field in a given amount of time.  It
 operates as a post-processor for MODFLOW using heads, cell-by-cell flow
 terms and porosity to move each particle through the flow field.  The
 program handles both forward and backward particle tracking. (See also
 IGWMC Key 3984).

MODPATH-PLOT: a graphic display  program for use with MODPATH-PC It
uses the Graphical Kernal System (GKS) to produce graphical output on a
wide range of commonly used printers and plotters.  MODPATH-PLOT comes
with MODPATH.
Page 4b-8

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Section 4i  Model Descriptions             Model Description tor MODFLOW

MACMODFLOW: this is the Macintosh implementation of the MODFLOW
model.  It supports the standard Macintosh user-interface. The simulation
code is integrated with the input data editor and the graphic post-processor.
Extensive data-checking is employed and simulation stops are trapped with
control returning to the  program.  Graphic functions include contouring of
heads, drawdowns, hydraulic conductivity, transmissivity, and plots of the
finite difference grid. This version of MODFLOW is available from Scientific
Software Group.

PATH3D is a general particle tracking program for calculating ground-water
paths and travel times.   The program uses the head solution of the USGS
modular finite difference model MODFLOW. The program is available from:

S.S. Papadopulos and Assoc., Inc
12250 Rockville Pike
Suite 290
Rockville , Maryland 20852
MODELCAD is a graphical oriented, model-independent pre- processor to
prepare and edit input files for two- and three-dimensional ground-water
models, including aquifer properties, boundary conditions, and grid
dimensions. The program prepares input files for MODFLOW, MOC, PLASM
and RANDOM WALK, among others. File formatting routines for other
models are available upon request. Contact:

Geraghty & Miller Modeling Group
1895 Preston White Drive
Suite 301
Reston, VA 22091
Phone: (703) 476-0335.
A related program contains a preconditioned conjugate gradient method for
the solution of the finite difference approximating equations generated by
MODFLOW (Kuiper 1987; see references). Five preconditioning types may be
chosen: three  different types of incomplete Choleski, point Jacob! or block
Jacobi. Either a head change or residual error criteria may be used as an
indication of  solution accuracy and interation termination. A later version of
this solver is  included in the extended memory PC version from IGWMC,
Scientific Software and Geraghty & Miller Modeling Group.

A computer program to summarize the data input and output from
MODFLOW is described by Scott (1990; see references). This program, the
Modular Model Statistical Processor, provides capabilities to easily read data
input to and output from MODFLOW, calculate descriptive statistics, generate
histograms, perform logical tests using relational operators, calculate data
arrays using arithmic operators, and calculate flow vectors for use in a
graphical display program. The program  is written in Fortran 77 and tested on
a Prime 1/model 9955-11.

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Section 4i  Model Description*            Mode/ Description for MODFLOiy

A computer program for simulating aquifer-system compaction resulting
from ground-water storage changes in compressible beds has been published
by Leake and Prudic (1988; see references).  This program can be incorporated
in MODFLOW as the INTERBED-STORAGE-PACKAGE. (see also MARS
3985).

STR1 is a computer program written for use in MODFLOW to account for the
amount of flow in streams and to simulate stream-aquifer interaction. The
program is  known as the Streamflow Routing Package (Prudic 1989; see
references.) (see also MARS 3896).

PCG2 (Hill  1990; see references) is a numerical code to be used with the USGS
MODFLOW model. It uses the preconditioned conjugate-gradient method to
solve the equations produced by the MODFLOW model. Both linear and
nonlinear flow conditions may be simulated. PCG2 includes two
preconditioning options: modified Cholesky preconditioning and polynomial
preconditioning. Convergence of the solver is determined using both head-
change and residual criteria. Non linear problems are solved using Picard
iterations.  This solver is included in various extended memory PC versions.

An IBM PC/386 extended memory version of this model is also available
from:

Geraghty & Miller, Inc.
Modeling Group
1895 Preston Drive
Suite 301
Reston, VA 22091
tel.: 703/476-0335
fax: 703/476-6372
Page 4b-10

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Section 4s Model Descriptions             Model Description tor MOOFLOW

11.  References

   McDonald, M.G. and A.W. Harbaugh. 1983.  A Modular Three-
      Dimensional Finite-Difference Ground Water Model.  Open-File Report
      83-875, U.S.  Geological Survey, Reston, Virginia.

   Kuiper, L.K.  1987. Computer Program for Solving Ground-Water Flow
      Equations by the Preconditioned Conjugate Gradient Method. Water-
      Resources Investigations Report 87-4091, U.S. Geological Survey,
      Austin, Texas.

   Leake, S.A., and D.E. Prudic. 1988. Documentation of a Computer Program
      to Simulate  Aquifer-System Compaction using the Modular Finite-
      Difference Ground-Water How Model. Open-File Report 88-482, U.S.
      Geological Survey, Tuscon, Arizona.

   McDonald, M.G., and A.W. Harbaugh.  1988. A Modular Three-
      Dimensional Finite-Difference Ground-Water Flow Model.  Book 6,
      Modeling Techniques, Chapter Al, U.S. Geological Survey, Reston,
      Virginia.

   Prudic, D.E. 1989. Documentation of a Computer Program to Simulate
      Stream-Aquifer Relations using a Modular, Finite-Difference, Ground-
      Water Row  Model. Open-File Report 88-729, U.S. Geological Survey,
      Carson City, Nevada.

   Hill, M.C. 1990. Preconditioned Conjugate Gradient 2 (PCG2), A Computer
      Program for Solving Ground-Water Flow Equations.  Water Resources
      Investigations Report 90-4048, U.S. Geological Survey, Denver,
      Colorado.

   Scott, J.C. 1990. A Statistical Processor for Analyzing Simulations Made
      Using the Modular Finite-Difference Ground-Water Flow Model.
      Water-Resources Investigations Report 89-4159, U.S. Geological
      Survey, Oklahoma City, Oklahoma.
                                                           Pmge 4b-11

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Section 4i  Model Descriptions            Mod*l Description for liODFLOW

12.  Users

   Brahana, J.V., and T.O Mesko. Hydrogeology and Preliminary Assessment
      of Regional Flow in the Upper Cretaceous and Adjacent Aquifers in the
      Northern Mississippi Embayment.  Water-Resources Investig. Rept. 87-
      4000, U.S. Geolog. Survey, Nashville, Tennessee.

   McDonald, M.G., 1984.  Development of a Multi-Aquifer Well Option for a
      Modular Ground Water Flow Model. In: Proceedings Practical
      Applications of Ground Water Models, Columbus, Ohio, August 15-17,
      1984, pp.  786- 796. National Water Well Association, Dublin, Ohio.

   Bailey, Z.C., 1985. Hydrologic Effects of Ground and Surface Water
      Withdrawals in the Howe Area, LaGrange County, Indiana.  Water
      Resources Investig. Report 85-4163, U.S. Geological Survey,
      Indianapolis, Indiana.

   Grannemann, N.G. and F.R. Twenter, 1985. Geohydrology and Ground
      Water Flow at Verona Well Fields, Battle  Creek, Michigan. Water
      Resources Investig. Report 85-4056, U.S. Geological Survey, East
      Lansing, Michigan.

   Kuniansky, E.L., 1985. Complex Depositional Environment at Baton
      Rouge, Louisiana, Requires Innovative Model  Layering. In:
      Proceedings Practical Applications of Ground Water Models,
      Columbus, Ohio, pp. 122-143. National Water  Well Association,
      Dublin, Ohio.

   Lindgren, H.A., 1985. Hydrologic Effects of Ground and Surface Water
      Withdrawals in the Milford Area, Elkart and Kosciusko Counties,
      Indiana. Water Resources Investig. Report 85-4166, U.S. Geological
      Survey, Indianapolis, Indiana.

   Spinazola, J.M., J.B. Gillespie and R.J. Hart, 1985. Ground Water Flow and
      Solute Transport in the Equus Beds Area,  South-Central Kansas, 1940-
      79. Water Resources Investig. Report 85-4336,  U.S. Geological Survey,
      Lawrence, Kansas.

   Trudeau, D.A. and A. Buono,  1985. Projected Effects of Proposed Increased
      Pumpage on Water Levels and Salinity in the  Sparta Aquifer Near
      West Monroe, Louisiana.  Technical Report No. 39, Louisiana Dept. of
      Transportation and Development, Baton Rouge, Louisiana.

   Weatherington - Rice, J.P., 1985. A Three-Dimensional Ground Water
      Modeling Study for Development of the New  Well Field at London
      Correctional Institute in Madison County, Ohio. In: Proceedings
      Practical Applications of Ground Water Models, Columbus, Ohio, pp.
      197-211. Nat. Water Well Association, Dublin, Ohio.
Page 4b-12

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Sect/on 4: Model Descriptions             Model Description for MODFLOW

   Yager, R.M.  1985.  Simulation of Ground Water Flow Near the Nuclear
      Fuel Reprocessing Facility at the Western New York Nuclear Service
      Center, Cattaraugus County, New York. Water Resources Investig.
      Report 85-4308, U.S. Geological Survey, Albany, New York.

   Delin, G.N. 1986.  Hydrogeology of Confined-Drift Aquifers near the
      Pomme De Terre and Chippewa Rivers, Western Minnesota.  Water
      Resources Investig. Report 86-4098,  U.S. Geological Survey,
      Minneapolis, Minnesota.

   Mandle, R.J. and A.L. Kontis, 1986.  Directions and Rates of Ground Water
      Movement in the Vicinity of Kesterson Reservoir, San Joaquin Valley,
      California.  Water Resources Investig. Report 86-4196, U.S. Geological
      Survey, Sacramento, California.

   Martin, P. and C. Berenbrock, 1986. Ground Water Monito ring at Santa
      Barbara, California: Phase 3— Development of a Three-Dimensional
      Digital Ground Water Flow  Model for Storage Unit I of the Santa
      Barbara Ground- Water Basin. Water-Resources Investig. Report 86-
      4103, U.S.  Geological Survey, Sacramento, California.

   Tucci, P., 1986.  Ground Water Flow in  Melton Valley, Oak Ridge
      Reservation, Roane County, Tennessee - Preliminary Model  Analysis.
      Water Resources Investig. Report 85-4221,  U.S. Geological Survey,
      Nashville, Tenn.

   Zitta, V.L. and T.K. Pang, 1986.  Application of a Groundwater Model to
      Critical Areas in Northeast Mississippi.  Department of Civil
      Engineering, Water Resources Research Institute, Mississippi State
      University, Mississippi State, Mississippi.

   Bergeron, M.P.  1987.  Effect of Reduced Industrial Pumpage on the
      Migration  of Dissolved Nitrogen in  an Outwash Aquifer at Olean,
      Cattaraugus County, New York. Water-Resources Investig. Report 85-
      4082, U.S. Geological Survey, Ithaca, New York.

   Kernodle, J.M. R.S. Miller and W.B. Scott. 1987.  Three- Dimensional
      Model Simulation of Transient Ground Water Flow in the
      Albuquerque-Belen Basin, New Mexico. Water Resources Investig.
      Report 86-4194, U.S. Geological Survey, Albuquerque, New Mexico.

   Kidd, R.E., and W.S. Mooty.  1987. Simulation of the Flow System in the
      Shallow Aquifer, Dauphin Island, Alabama. In: E.J. Edwards  (ed.),
      Proceed. 17th Mississippi Water Resources Conference, Jackson,
      Mississippi, March 25-26, 1987, pp. 99-107.  Water Resources Research
      Inst, Mississippi State Univ., Mississippi State, Mississippi.

   Kyllonen, D.P., and K.D. Peter.  1987. Geohydrology and Water Quality of
      the Inyan Kara,  Minnelusa, and Madison Aquifers of the Northern
      Black-Hills, South Dakota and Wyoming, and Bear Lodge Mountains,
      Wyoming. Water-Resources Investigations Report 86-4158, U.S.
      Geological Survey, Rapid City, South Dakota.

                                                            Page 4b-13

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Section 4i  Model Descriptions             Model Description for MODFLOW

   Phillips, S.W. 1987. Hydrogeology, Degradation of Ground- Water Quality,
      and Simulation of Infiltration from the Delaware River into the
      Potomac  Aquifers, Northern Delaware. Water-Resources Investig.
      Rept. 87-4185, U.S. Geol. Survey, Towson, Maryland.

   Pool, D.R. 1987.  Hydrogeology of McMullen Valley, West- Central
      Arizona.  Water-Investigations Report 87-4140, U.S. Geological Survey,
      Tuscon, Arizona.

   Risser, D.W. 1987. Possible Changes in Ground-Water Flow to the Pecos
      River Caused by Santa Rosa Lake, Guadalupe County, New Mexico.
      Water-Resources Investigations Report 85-4291, U.S. Geological
      Survey, Albuquerque, New Mexico.

   Weiss, E.  1987.  Ground-Water Flow in the Navajo Sandstone in Parts of
      Emery, Grand, Carbon, Wayne, Garfield, and Kane Counties, Southeast
      Utah. Water-Resources  Investigations Report 86-4012, U.S. Geological
      Survey, Denver, Colorado.

   Zitta, V.L., and T-K. Pang.  1987. Application of a Layered Groundwater
      Model to Critical Areas in Northeast Mississippi.  In: E.J. Hawkins (ed.),
      Proceedings 17th Mississippi Water Resources Conference, Jackson,
      Mississippi, March 25-26,1987, pp, 89-94. Water Resources Research
      Inst., Mississippi State Univ., Mississippi State, Mississippi.

   Aucott,  W.R. 1988.  The Predevelopment Ground-Water Flow System and
      Hydrologic Characteristics of the Coastal Plain Aquifers of South
      Carolina. Water-Resources Investigations Report 86-4347, U.S.
      Geological Survey, Columbia, South Carolina.

   Bailey, Z.C.  1988. Preliminary Evaluation of Ground- Water  Flow in Bear
      Creek Valley, The Oak Ridge Reservation, Tennessee.  Water-
      Resources Investigations Report 88-4010, U.S. Geological Survey,
      Nashville, Tennessee.

   Brown,  J.G., and J.H. Eychaner. 1988.  Simulation of Five Ground-Water
      Withdrawal Projections for the Black Mesa Area, Navajo and Hopi
      Indian Reservations, Arizona. Water-Resources  Investigations Report
      88-4000,  U.G. Geological Survey, Tuscon, Arizona.

   Buckles, D.R., and K.R. Watts.  1988. Geohydrology, Water Quality, and
      Preliminary Simulations of Ground-Water Flow of the Alluvial
      Aquifer in the Upper Black Squirrel Creek Basin,  El Paso County,
      Colorado. Water-Resources Investigations Report 88-4017, U.S.
      Geological Survey, Denver, Colorado.

   Danskin, W.R.  1988. Preliminary Evaluation of the Hydrogeologic System
      in Owens Valley, California. Water- Resources Investigations Report
      88-4003,  U.S. Geological Survey, Sacramento, California.
 Page 4b-14

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Section 4: Model Descriptions             Model Description for MODFLOW

   Davies-Smith, A., E.L. Bolke, and C.A. Collins.  1988. Geohydrology and
      Digital Simulation of the Ground- Water Row System in the Umatilla
      Plateau and Horse Heaven Hills Area, Oregon and Washington.
      Water- Resources Investigations Report 87-4268, U.S. Geological
      Survey, Portland, Oregon.

   Emmons, P.J.  1988.  A Digital Simulation of the Glacial- Aquifer System in
      Sanborn and Parts of Beadle, Miner, Hanson, Davison, and Jerauld
      Counties, South Dakota. Water-Resources Investigations Report 87-
      4082, U.S. Geological Survey, Huron, South Dakota.

   Fenemor, A.D. 1988. A Three-Dimensional Model for Management of the
      Waimea Plains Aquifers, Nelson. Publication 18, Hydrology Centre,
      Dept. of Scientific and Industrial Research, Christchurch, New Zealand.

   Fretwell, J.D.  1988. Water Resources and Effects of Ground-Water
      Development in Pasco County, Florida.  Water-Resources
      Investigations Report 87-4188, U.S. Geological Survey, Tallahassee,
      Florida.

   Hamilton,F.A., and J.D. Larson. 1988.  Hydrogeology and Analysis of the
      Ground-Water Flow System in the Coastal Plain of Southeastern
      Virginia.  Water- Resources Investigations Report 87-4240, U.S.
      Geological Survey, Richmond, Virginia.

   Hansen, D.S.  1988. Appraisal of the Water  Resources of the Big Sioux
      Aquifer, Moody County, South Dakota.  Water-Resources
      Investigations Report 87-4057, U.S. Geological Survey, Huron, South
      Dakota.

   Johnson, M.J., C.J.  Londquist, J. Laudon, and H.T. Mitten. 1988.
      Geohydrology  and Mathematical Simulation of the Pajaro Valley
      Aquifer System, Santa Cruz and Monterey Counties, California.
      Water-Resources Investigations Report 87-4281, U.S. Geological
      Survey, Sacramento,  California.

   Laczniak, R.J., and A.A. Meng  HI.  1988.  Ground-Water Resources of the
      York-James Peninsula of Virginia. Water-Resources Investig. Rept. 88-
      4059, U.S. Geol. Survey, Richmond, Virginia.

   McAda, D.P., and  M. Wasiolek. 1988. Simulation of the Regional
      Geohydrology of the Tesque Aquifer System near Santa Fe, New
      Mexico.  Water-Resources Investigations Report 87-4056, U.S.
      Geological Survey, Albuquerque, New Mexico.

   Morgan, D.S.  1988. Geohydrology and Numerical Model Analysis of
      Ground-Water  Flow in the  Goose Lake Basin, Oregon and California.
      Water-Resources Investigations Report 87-4058, U.S. Geological
      Survey, Portland, Oregon.
                                                            Page 4b-15

-------
Section 4s  Model Descriptions             Model Description for MODFLOW

   Yates, E.B. and J.H. Wiese.  1988.  Hydrogeology and Water Resources of
      the Los Osos Valley Ground-Water Basin, San Luis Obispo County,
      California.  Water-Resources Investigations Report 88-4081, U.S.
      Geological Survey, Sacramento, California.

   Ackerman, D.J.  1989.  Hydrology of the Mississippi River Valley Alluvial
      Aquifer, South-Central  United States --A Preliminary Assessment of
      the Regional Flow System.  Water-Resources Investig. Rept. 88-4028,
      U.S. Geol. Survey, Little Rock, Arkansas.

   Coen HI, A.W. 1989. Ground-Water Resources of Williams County, Ohio,
      1984-86.  Water-Resources Investigations Report 89-4020, U.S.
      Geological Survey, Columbus, Ohio.

   Duwelius, R.F., and T.K. Greeman.  1989.  Geohydrology, Simulation of
      Ground-Water Flow, and Ground-Water Quality at Two Landfills,
      Marion County,  Indiana.  Water-Resources Investigations Report 89-
      4100, U.S. Geological Survey, Indianapolis, Indiana.

   Freckleton, J.R.  1989.  Geohydrology of the Foothill Ground-water Basin
      near  Santa Barbara,  California. Water-Resources Investig. Report 89-
      4017, U.S. Geological Survey, Sacramento, California.

   Imes, J.L. 1989. Analysis of the Effect of Pumping on Ground-Water Flow
      in the Springfiled Plateau and Ozark Aquifers near Springfield,
      Missouri.  Water-Resources Investigations Report 89-4079, U.S.
      Geological Survey, Rolla, Missouri.

      A model of 42 by 42 mile  area was calibrated under predevelopment
      and transient pumping conditions. The model then was used to
      quantify hydraulic properties of the aquifer and confining unit and the
      hydrologic budget.

   Lima, V. de,  and J.C. Olimpio.  1989. Hydrogeology and Simulation of
      Ground-Water Flow at  Superfund-Site Wells G and H, Woburn,
      Massachusetts. Water-Resources Investigations Report 89-4059,
      U.S.Geological Survey,  Boston, Massachusetts.

      (The  calibrated three-dimensional ground-water flow model of the
      stratified drift area was  designed as a tool for predicting the steady-state
      and transient effects of  pumpage in the vicinity of public supply wells.)

   Martin, Jr., A., and C.D. Whiteman, Jr.  1989.  Geohydrology and Regional
      Ground-Water Flow of  the Coastal Lowlands Aquifer System in Parts
      of Louisiana, Mississippi, Alabama, and Florida—A Preliminary
      Analysis. Water-Resources Investigations Report 88-4100, U.S.
      Geological Survey, Baton Rouge, Louisiana.
Page 4b-16

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Sect/on 4s Model Descriptions            Model Description for MODFLOW

   Summer, D.M., B.E. Wasson, and SJ. Kalkhoff.  1989. Geohydrology and
      Simulated Effects of Withdrawals on the Miocene Aquifer System in
      the Mississippi Gulf Coast. Water-Resources Investig. Rept. 87-4172,
      U.S. Geological Survey, Jackson,  Mississippi.

   Watson, L.R., R.J. Shedlock, K.J. Banaszak, L.D.  Arihood, and P.K. Doss.
      1989. Preliminary Analysis of the Shallow Ground-Water System in
      the Vicinity of the Grand Calumet River/Indiana Harbor Canal, North-
      western Indiana.  Open-File Report 88-492, U.S. Geological Survey,
      Indianapolis, Indiana.

   Yobbi, D.K. 1989. Simulation of Steady-State Ground Water and Spring
      Flow in the Upper Floridan Aquifer of Coastal Citrus and Hernando
      Counties, Florida. Water-Resources Investig. Rept., U.S. Geol. Survey,
      Tallahassee, Florida.

   Young, H.W., and G.D. Newton. 1989. Hydrology of the Oakley Fan Area,
      South Central Idaho. Water- Resources Investigations Rept. 88-4065,
      U.S. Geolog. Survey, Boise, Idaho.

   Bair, E.S., R.A. Sheets, and S.M. Eberts. 1990. Particle-Tracking Analysis of
      Flow Paths and Traveltimes  from Hypothetical Spill Sites within the
      Capture Area of a Wellfield.  Ground Water, Vol. 28 (6), pp. 884-892.

      Velocity fields computed from  simulated flows from a steadystate,
      three-dimensional numerical model of a glacial drift/carbonate-
      bedrock aquifer system were used in conjunction with a particle
      tracking program to delineate traveltimes related capture areas of a
      municipal wellfield and compute flow paths from a hypothetical spill
      site.

   Delin, G.N. 1990.  Geohydrology and Water Quality of Confined-Drift
      Aquifers in the Brooten-Belgrade Area, West-Central Minnesota.
      Water-Resources Investigations Report 88-4124, U.S. Geological
      Survey, St. Paul, Minnesota.

      (The quasi-three dimensional model was constructed to improve
      understanding of the movement of water in a complicated system of
      confined drift aquifers.)

   Dickerman, D.C., E.G. Todd Trench, and J.P. Russell. 1990.  Hydrogeology,
      Water Quality, and Ground-Water Development Alternatives in the
      Lower Wood River Ground-Water Reservoir, Rhode Island.  Water-
      Resources Investigations Report 89-4031, U.S. Geological Survey,
      Providence, Rhode Island.

  Eimers, J.L., W.L. Lyke, and A.R. Brockman. 1990. Simulation of Ground-
     Water Flow in Aquifers in Cretaceous Rocks in the Central Coastal
     Plain, North Carolina. Water-Resources Investigations Report 89-4153,
     U.S. Geological Survey, Raleigh,  North Carolina.
                                                            Page 4b-17

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Section 4s Model Descriptions	Model Description for UODFLOW

   Lum II, W.E., J.L. Smoot, and D.R. Ralston. 1990. Geohydrology and
      Numerical Model Analysis of Ground-Water Flow in the Pullman-
      Moscow Area, Washington and Idaho.  Water-Resources
      Investigations Report 89-4103, U.S. Geological Survey, Tacoma,
      Washington.

   Mahon, G.L. and A.H. Ludwig. 1990. Simulation of Ground- Water Flow
      in the Mississippi River Valley Alluvial Aquifer in Eastern Arkansas.
      Water-Resources Investigations Report  89-4145, U.S. Geological
      Survey, Little Rock, Arkansas.

   Ohland, G.L.  1990.  Appraisal of the Water Resources of the Skunk Creek
      Aquifer in Minnehaha County, South Dakota.  Water-Resources
      Investigations Report 87- 4156, U.S. Geological Survey, Huron, South
      Dakota.

   Tucci, P., D.W. Hanchar, and R.W. Lee. 1990. Hydrogeology of a
      Hazardous-Waste Disposal Site near Brentwood, Williamson County,
      Tennessee.  Water-Resources Investigations Report 89-4144, U.S.
      Geological Survey, Nashville, Tennessee.

   Zomorodi, K. 1990. Experiences in using MODFLOW on a PC. In: E.B.
      Janes and W.R.  Hotchkiss (eds.), Transferring Models to Users, Denver,
      Colorado, November 4-8, 1990, pp. 351-356. American Water Resources
      Assoc., Bethesda, Maryland.
 Page 4b-18

-------
     Model Description For
           PLASM
           SOURCE:
INTERNATIONAL GROUND WATER
      MODELING CENTER
           (IGWMC)

-------
                      Table of Contents
                                                                   PAGE

 1.   Mode/ Identification	4c-1
      1.1.   Model Name(s)	4c-l
      1.2.   Date of First Release	4c-l
      1.3.   Current Release  Date	4c-l
      1.4.   Authors	4c-l

 2.   Model Information	 4c-1
      2.1.   Model Category	4c-l
      2.2.   Model Developed For	4c-l
      2.3.   Units of Measurement Used	4c-l
      2.4.   Abstract	4c-l
      2.5.   Data Input Requirements	4c-2
      2.6.   Versions Exist for the Following Computer Systems	4c-2
      2.7.   System Requirements	4c-2
      2.8.   Graphics  Requirements	4c-2
      2.9.   Program Information	4c-2

 3.   General Model Capabilities...	................................... 4c-2
      3.1.   Parameter Discretization	4c-2
      3.2.   Spatial Orientation	4c-2
      3.3.   Types of Possible Updates	4c-2
      3.4.   Geostatistics and Stochastic Approach	4c-2
      3.5.   Comments	4c-3

 4.   Flow Characteristics........................	 4c-3
      4.1.   Row System Characterization	4c-3
      4.2.   Fluid Conditions	4c-4
      4.3.   Boundary Conditions	4c-4
      4.4.   Solution Methods for Flow	4c-4
      45.   Grid Design	4c-4
      4.6.   Flow Output Characteristics	4c-5

 5.   Evaluation[[[ 4c-5
      5.1.   Verification/Validation	4c-5
      5.2.   Internal Code Documentation (Comment Statements)	4c-5
      5.3.   Peer (Independent) Review	4c-5

 6.   Documentation and Support.............................................4c-5
      6.1.   Documentation Includes	4c-5
      6.2.   Support Needs	4c-5
      6.3.   Level of Support	4c-6

 7.   Availability.			.	4c-6
      7.1.   Terms	4c-6
      7.2.   Form	4c-6


-------
                                                                  PACE
9.   Institution of Model Development...	...4c-7
      9.1.   Name	4c-7
      9.2.   Address	4c-7
      9.3.   Type of Institution	4c-7
10.  Remarks	4c-7
11.  References...	 4c-9
12.  Users		4c-10
Page 4c-»

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                              PLASM

 1.   Model Identification

 1.1.  Model Name(s)
        •  PLASM

 1.2.  Date of First Release
        •  1971

 1.3.  Current Release Date
        •  1985

 1.4.  Authors
        •  1. Prickett, T.A.
        •  2. Lonnquist, C.G.


 2.   Model Information

 2.1.  Model Category
        •  ground-water flow

 2.2.  Model Developed For
        •  general use (e.g. in field applications)
        •  research (e.g. hypothesis/theory testing)
        •  demonstration/education

 2.3.  Units of Measurement Used
        •  SI system
        •  metric units
        •  US customary units
        •  any consistent system

2.4.  Abstract
      PLASM  (Prickett Lonnquist Aquifer Simulation Model) is a finite
      difference model for  simulation of transient,  two-dimensional or
      quasi-three-dimensional flow in a single or multi-layered,
      heterogeneous, anisotropic aquifer system.  The original model of 1971
      consisted of a series of separate programs for  various combinations of
      simulation options. Later versions combined most of the options in a
      single code, including variable pumping rates, leaky confined aquifer
      conditions, induced infiltration from a shallow aquifer or a stream,
      storage coefficient conversion between confined and watertable
      conditions, and evapotranspiration as a function of depth to water
      table. The model uses the iterative alternating implicit method (IADI)
      to solve  the matrix equation.
                                                              Pmg* 4c-1

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 Section 4s Model Descriptions	Model Description for PLASM

 2.5.   Data Input Requirements:
      Data input requirements are provided in the model documentation
      and are discussed in the introduction to Section 4.0 of the Compendium.

 2.6.   Versions Exist for the Following Computer Systems
        •  minicomputer
        •  workstations
        •  mainframe
        •  microcomputer

        •  make/model
           - IBM 360,370
           - DEC VAX
           - IBM PC/XT/AT

 2.7.   System Requirements
        • core memory (RAM) for execution (bytes)
          -  640K (for IBM PC version)
        • mass storage (disk space in bytes)
          -  1M
        • numeric/math coprocessor
          —  (for micro computers)
        • compiler required
          -  (for  mainframe)

 2.8.   Graphics Requirements
        • none

 2.9.   Program Information
        • programming language/level
          —  Fortran IV
3.   Genera/ Model Capabilities

3.1.  Parameter Discretization
        •  distributed

3.2.  Spatial Orientation
        •  saturated flow
        •  2D-horizontal
        •  3D-layered

3.3.  Types of Possible Updates
        •  parameter values
        •  boundary conditions

3.4.  Geostatistics and Stochastic Approach
        •  none
Page 4c-2

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Section 4i  Model Descriptions                Model Description for PLASM

3.5.  Comments
        •  This model has restart capability.
4.   Flow Characteristics

4.1.  Flow System Characterization
        •  Saturated Zone

        •  System
          —  single aquifer
          —  single aquifer/aquitard system
          —  multiple aquifer/aquitard systems

        •  Aquifer Type(s)
          —  confined
          —  semi-confined (leaky-confined)
          -  unconfined (phreatic)

        •  Medium
          —  porous media

        •  Parameter representation
          —  homogeneous
          —  heterogeneous
          —  isotropic
          —  anisotropic

        •  Flow characteristics (saturated zone)
          —  laminar flow
          —  linear (Darcian flow)
          -  steady-state
          -  transient

        •  Flow processes included
          —  areal recharge
          —  induced recharge (from river)
          —  evapotranspiration

        •  Changing aquifer conditions
          —  in space
             -   variable thickness
             -   confined/unconfmed

          -  in  time
             -   confined/unconfined

       •  Well characteristics
          —  none

                                                             Pag* 4c-3

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Sect/on 4:  Model Descriptions                Model Description tor PLASM

4.2.  Fluid Conditions
        •   Single Fluid Flow
           — water

        •   Flow of Multiple Fluids
           - N.A.

        •   Fluid Properties
           — constant in time/space

4.3.  Boundary Conditions
        •   First Type - Dirichlet
           — head/pressure

        •   Second Type - Neumann (Prescribed Rux)
           - injection/production wells
           — no flow boundary
           — areal boundary flux
           — ground-water recharge
           — induced infiltration

        •   Third Type - Cauchy
           — head/pressure-dependent flux

4.4.  Solution Methods for Row
        •   General Method
           — Numerical

        •   Spatial Approximation
           — finite difference method
           — node-centered

        •   Time-Stepping Scheme
           — fully implicit

        •   Matrix-Solving  Technique
           — Iterative
           - iterative ADIP
           - Direct
           — Gauss elimination

4.5.  Grid Design
        •   Cell/Element Characteristic
           - constant cell size
           — variable cell size

        •   Possible Cell Shapes
           — 2D-square
           — ID-rectangular
Page 4c-4

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Section 4:  Model Descriptions                Model Description for PLASM

        •   Maximum Number of Nodes
           - 5000

4.6.  Flow  Output Characteristics
        •   Simulation Results
           - head/pressure/potential
             -   ASCII file (areal values)
             -   ASCII file (hydrograph)
           — water budget components
             -   ASCH file (cell-by-cell values)
             -   ASCII file (global total area)
5.   Evaluation

5.1.  Verification/Validation
        •  verification (analytical solutions)
        •  field datasets (validation)
        •  synthetic datasets
        •  code intercomparison

5.2.  Internal Code Documentation (Comment Statements)
        •  incidental

5.3.  Peer (Independent) Review
          concepts
          theory (math)
          coding
          accuracy
          documentation
          usability
          efficiency
6.   Documentation and Support

6.1.  Documentation Includes
          model theory
          user's  instructions
          example problems
          code listing
          program structure and development
          verification/validation

6.2.  Support Needs
       •  Can be used without support
       •  Support is available
          —  from  author
          -  from third parties
                                                             Page 4c-5

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Sect/on 4: Model Descriptions               Model Description for PLASM

6.3.  Level of Support
       •  limited
7.   Availability

7.1.  Terms
          available
          public domain
          proprietary
          restricted public domain
          purchase
          license

     Form
          source code only (tape/disk)
          source and compiled code
          compiled code only
          paper listing of source code
          (depends on version)


8.   Pre and Post Processors

8.1.  Data Preprocessing
        •  name: PREPLASM
          —  part of model package (e.g. under a shell; dedicated)
          —  textual data entry/editing
          —  error-checking

        •  name: MODELCAD
          —  separate (optional) program
          -  graphic data entry/modification (e.g manual grid design,
             arrays)
          -  (semi-) automatic grid generation
          -  data reformatting (e.g. for GIS)
          -  error-checking
          —  help screens
Page 4c-6

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Section 4:  Model Descriptions               Model Description for PLASM

9.   Institution of Model Development

9.1.  Name
           Illinois State Water Survey
9.2.  Address
           P.O. Box 232
           Urbana, Illinois 61801

9.3.  Type  of Institution
           state/provincial government


fO.  Remarks

A modified version of PLASM to analyze hydrologic impacts of mining is
documented in in a report of the U.S. Office of Surface Mining (1981; see user
references).

An extended and updated single aquifer version of PLASM for the IBM-PC is
available from:

                             T.A. Prickett
                             6 G.H. Baker Drive
                             Urbana, IL 61801
                             phone: 217/384-0615.

This version is the same as published in Bulletin 55,  except for the multi-
layered option and the confined/unconfined storage conversion.
The IGWMC distributes a mainframe version of PLASM running on the
DEC/VAX 11 series. The Center distributes also an IBM-PC version. This
latter version comes as a program package including separate codes for
confined (CONPLASM) and watertable (UNCPLASM) conditions and a
textual preprocessor for input data preparation (PREPLASM).  Contact:

           IGWMC USA:    International Ground Water  Modeling
                             Center,
                             Colorado School of Mines, Golden, Colorado,
                             USA, or
                             TNO Inst. of Applied Geoscience, P.O. Box
                             6012, 2600JA
                             Delft, The Netherlands.

           IGWMC Europe:   TNO Institute of Applied Geoscience,
                             P.O. Box 6012, 2600JA Delft,
                             The Netherlands.

For earlier microcomputer versions of PLASM see IGWMC Key # 6010 and
6011 (MARS historic data base).

                                                             Pag* 4e-7

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Section 4:  Model Descriptions                Model Description for PLASM

MODELCAD is a graphical oriented, model-independent pre-processor to
prepare and edit input files for two- and three-dimensional ground-water
models, including aquifer properties, boundary conditions, and grid
dimensions. The program prepares input files for MODFLOW, MOC, PLASM
and RANDOM WALK, among others. File formatting routines for other
models are available upon request.  Contact:

                              Geraghty & Miller Modeling Group
                              1895 Preston White Drive
                              Suite 301
                              Reston, VA 22091
                              Phone: (703) 476-0335.
The IBM-PC version of this program is also available from:

                              National Water Well Association
                              Ground Water Bookstore
                              P.O. Box 182039
                              Dept. 017
                              Columbus, Ohio 43218
                              Tel. (614) 761-1711
The version available from the National Water Well Association runs on
IBM PC or compatible and has been prepared by Koch and Associates and
includes interactive data preparation.  The code is directly available from
Koch and  Associates.  Contact:

                              Ann Koch
                              2921 Greenway Drive
                              Ellicot City, Maryland 21043
                              tel. 301/461-6869.
 Page 4c-8

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Section 4: Model Descriptions                Model Description for PLASM

11.  References

   Prickett, T.A. and C.G. Lonnquist. 1971. Selected Digital Computer
      Techniques for Groundwater Resource Evaluation.  Bulletin 55.
      Illinois State Water Survey, Urbana, 111.

   Texas  Water Development Board, Systems Engineering Division.  1974.
      GWSIM  - Groundwater Simulation Program, Program Documentation
      and User's Manual. Texas Dept. of Water Resourc, Austin, Texas.

   Prickett, T.A. and C.G. Lonnquist. 1976. Methods de Ordenador para
      Evaluacion de Recursos Hidraulicos Subterraneas.  Boletin 41.
      (Spanish version of Bulletin 55, ISWS). Ministerio de Obras Publicas,
      Direction General de Obras Hidraulicos, Madrid, Spain.

   Texas  Dept. of Water Resources.  1979. Program Description of GWSIM.
      In:  Mathematical Simulation Capabilities in Water Resources Systems
      Analysis, Eng. and Environm. Systems Section, Report LP-16, revised
      November 1979.

   Institute Geologico Y Minero de Espana.  1981. Modelos Multicapa —
      Tomo II: Listados de Programas, Ministreio de Industria Y Energia,
      Madrid, Spain.

   Institute Geologico Y Minero de Espana.  1981. Modelos Multicapa —
      Tomo I: Manuales  de Utilization.  Ministerio de Industria Y Energia,
      Madrid, Spain.

   Institute Geologico Y Minero de Espana.  1982. Modelos Monocapa en
      Regimen Transitorio — Tomo II: Listados de Ordenador.  Ministerio de
      Industria Y Energia, Madrid, Spain.

   Institute Geologico Y Minero de Espana.  1982. Modelos Monocapa en
      Regimen Transitorio — Tomo  I: Manuales de Utilization.  Dirretion de
      Aguas Subterraneas y Geotecnia, Ministerio de Industria y Energia,
      Madrid, Spain.
                                                                  4c-9

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Sect/on 4s Model Descriptions                Model Description for PLASM

12.  Users

   T.R. Knowles developed two models based on PLASM for the Texas Dept.
      of Water Resources, Austin, Texas. See models GWS1M (IGWMC key
      # 0681) and GWSIM II (IGWMC key # 0680).

   Beltran, J.M.A., L.L. Garcia, and M.R.L. Madurga.  1973. Estudio de la
      Explotacion de los Aquiferos del Llano de Palma de Mallorca Mediante
      un Modelo Digital Simplificado. Boletin 38, Dirrecion General de
      Obras Hidraulicas, Ministerio de Obras Publicas, Madrid, Spain.

   Karanjac, J., M. Altunkaynak, and G. Ovul.  1976. Mathematical model of
      Elazig-Uluova Plain, Republic of Turkey.  Ministry of Energy and
      Natural Resources. Geotechnical Services and Groundwater Division,
      Ankara, Turkey.

   Naymik, T.G. 1979. The Application of Digital Model for Evaluating the
      Bedrock Water Resources of the Maumee River Basin, Northwestern
      Ohio.  Lawrence Livermore Laboratory. University of California.
      Livermore, California.

   U.S. Department of the Interior. 1981. Office of Surface Mining -
      Reclamation and Enforcement.  Ground Water Model Handbook  (H-
      D3004-021-81-1062D). Office of Surface Mining. Western Technical
      Service Center. Denver, Colorado.

   Yazicigil, H. and L.V.A. Sendlein.  1981. Management of Ground Water
      Contaminated by Aromatic Hydrocarbons in the Aquifer Supplying
      Ames, Iowa. Groundwater, Vol. 19(6), pp. 648-665.

   Grosser, P.W. 1984. Application of Ground Water Models to the
      Identification of Contaminant Sources.  In: Proceed. Conf. on Practical
      Applications of Ground Water Models, Columbus, Ohio, pp. 452-461.
      Nat. Water Well Assoc., Dublin, Ohio.

   Khaleel, R. and D.M. Peterson. 1984.  A Quasi Three- Dimensional
      Ground Water Flow Model for the Mesilla Bolson, New Mexico.  In:
      Proceed.  Conf. on Practical Applications of Ground Water Models,
      Columbus, Ohio, pp. 52-67. Nat. Water Well Assoc., Dublin, Ohio.

   Martin, P.L.  1984.  The Use of a Numerical Model in Predicting the
      Effectiveness of a Dewatering System. In: Proceed. Conf. on Practical
      Applications of Ground Water Models, Columbus, Ohio, pp. 759-777.
      Nat. Water Well Assoc., Dublin, Ohio.

   Osiensky, J.L., G.V. Winter, and R.E. Williams.  1984. Monitoring and
      Mathematical Modeling of Contaminated Ground Water Plumes in
      Fluvial Environments.  Ground Water, Vol. 22(3), pp. 298-306.
 Page 4c-10

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Section 4i  Model Descriptions                Model Description tor PLASM

   Potter, S.T. and W.J. Gburek. 1984. Seepage Face Simulation Using the
      Illinois State Water Survey Ground Water Model.  In: Proceed. Conf.
      on Practical Applications of Ground Water Models, Columbus, Ohio,
      pp. 674-700. Nat. Water Well Assoc., Dublin, Ohio.

   Ritchey, J.D.  1984.  Method for Including the Effects of River Stage and
      Precipitation on Ground Water Levels in an Aquifer Model.  In:
      Proceed. Practical Applications of Ground Water Models, Columbus,
      Ohio, pp. 649-673. Nat. Water Well Assoc., Dublin, Ohio.

   Sevi, E.A., T.M. Cosgrave, and F.L. Fox. 1984.  Sequential Horizontal and
      Vertical Cross-Sectional Modeling of a Small Site.  In: Proceed. Conf. on
      Practical Applications of Ground Water Models, Columbus, Ohio, pp.
      621-633.  Nat. Water Well Assoc., Dublin, Ohio.

   Singh, R., S.K.  Sondhi, J. Singh, and R. Kumar.  1984. A Ground Water
      Model for Simulating the Rise of Water Table under Irrigated
      Conditions. Journ. of Hydrol., Vol. 71, pp. 165-179.

   Kalinski, R.J.  1985.  Investigation and Computer Simulation of Stream-
      Aquifer Relationship at Elm Creek, Nebraska. In: Proceed.  Practical
      Applications of Ground Water Models, Columbus, Ohio, pp. 146-161.
      Nat. Water  Well  Assoc., Dublin, Ohio.

   Song, S.  and A.O. Akan.  1985.  Ground Water Management by Linear
      Programming with Sample Applications to the Eastern Shore of
      Virginia Aquifer. In: Proceed. Conf. on Practical Applications of
      Ground Water Models, Columbus, Ohio, pp. 90-107.  Nat. Water Well
      Assoc., Dublin, Ohio.

   Contractor, D.N., S.M.A. El-Didy, and A.S. Ansary. 1986. Numerical
      Modeling of Groundwater Flow and Water Quality at Underground
      Coal Gasification Sites.  DOE/LC/11053-2151. Office of Fossil Energy,
      U.S. Dept. of Energy, Laramie, Wyoming, (pp.7-50).
                                                                  4c-11

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Section 4s  Model Descriptions	Model Description for PLASM
             (THIS PAGE INTENTIONALLY LEFT BLANK)
 Page 4c-12

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     Model Description For
      RANDOM WALK
           SOURCE:
INTERNATIONAL GROUND WATER
      MODELING  CENTER
           (IGWMC)

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                      Table of Contents
                                                                   PAGE

 1.   Model Identification ........................... . ............................... 4d-1
      1.1.    Model Name(s) [[[ 4d-l
      1.2.    Date of first release [[[ 4d-l
      1.3.    Current Release date [[[ 4d-l
      1.4.    Authors [[[ 4d-l

2.   Model Information ........................... ........................ ...... ..... 4d-1
      2.1.    Model Category [[[ 4d-l
      2.2.    Model Developed For [[[ 4d-l
      2.3.    Units of Measurement Used [[[ 4d-l
      2.4.    Abstract [[[ 4d-l
      2.5.    Data Input Requirements [[[ 4d-l
      2.6.    Versions Exist for the Following Computer Systems ................ 4d-2
      2.7.    System Requirements [[[ 4d-2
      2.8.    Graphics Requirements [[[ 4d-2
      2.9.    Program Information [[[ 4d-2
3.   General Model Capabilities. .............................................
      3.1.   Parameter Discretization [[[ 4d-2
      3.2.   Coupling [[[ 4d-2
      3.3.   Spatial Orientation [[[ 4d-2
      3.4.   Geostatistics and Stochastic Approach .......................................... 4d-2

4,   Flow Characteristics[[[ 4d-2
      4.1.   Flow System Characterization [[[ 4d-2
      4.2.   Fluid Conditions [[[ 4d-3
      4.3.   Boundary Conditions [[[ 4d-4
      4.4   Solution Methods for Flow [[[ 4d-4

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                                                                  PACE

8.  Availability. ....................... - ................................. - ................ 4d-7
      8.1.   Terms [[[ 4<*-7
      8.2.   Form [[[ 4
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                      RANDOM  WALK
 1.   Model Identification

 1.1.  Model Name(s)
        •  RANDOM WALK

 1.2.  Date of first release
        •  7/81

 1.3.  Current Release date
        •  7/81

 1.4.  Authors
        •  Prickett, T.A.
        •  Naymik, T.G.
        •  Lonnquist, C.G.
2.   Model Information

2.1.  Model Category
        •   ground-water flow
        •   mass transport

2.2.  Model Developed For
        •   general use (e.g. in field applications)
        •   research (e.g. hypothesis/theory testing)
        •   demonstration/education

2.3.  Units of Measurement Used
        •   metric units
        •   US customary units
        •   any consistent system

2.4.  Abstract
       RANDOM WALK/TRANS is  a numerical model to simulate two-
       dimensional steady or transient flow and transport problems in
       heterogeneous aquifers under  water table and/or confined or leaky
       confined conditions. The flow is solved using a finite difference
       approach and the iterative alternating direction implicit method.
       The advective transport is  solved with a particle-in-a-cell method,
       while the dispersion is analyzed with the random walk method.

2.5.  Data Input Requirements
       Data input requirements are provided in the model documentation
       and are discussed in the introduction to Section 4.0 of the
       Compendium.
                                                             Page 4d-1

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Section 4; Model Descriptions          Model Description for Random Walk

2.6.  Versions Exist for the Following Computer Systems
       •  minicomputer
       •  workstations
       •  mainframe
       •  microcomputer

          —  make/model
             -   Cyber 175
             -   VAX 11/780
             -   IBM PC/XT/AT or compatible

2.7.  System Requirements
       •  core memory (RAM) for execution (bytes)
          -  640K (for IBM PC version)
       •  mass storage (disk space in bytes)
          -  at least 2Mb for data files
       •  numeric/math coprocessor
          —  (for micro computers)
       •  compiler required
          —  (for mainframe)

2.8.  Graphics Requirements
       •  none

2.9.  Program Information
       •  programming language/level
          —  Fortran rV
3.   General Model Capabilities

3.1.  Parameter Discretization
       •  distributed

3.2.  Coupling
       •  none

3.3.  Spatial Orientation
       •  saturated flow
       •  2D-horizontal

3.4.  Geostatistics and Stochastic Approach
       •  random walk
4.   Flow Characteristics

4.1.  Flow System Characterization
        •  Saturated Zone
Page 4d-2

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Section 4t  Model Descriptions	Model Description for Random Walk
        •  System
           —  single aquifer
           -  single aquifer/aquitard system

        •  Aquifer Type(s)
           —  confined
           -  semi-confined (leaky-confined)
           —  unconfined (phreatic)

        •  Medium
           —  porous media

        •  Parameter representation
           —  homogeneous
           —  heterogeneous
           —  isotropic
           —  anisotropic

        •  Flow characteristics (saturated zone)
           —  laminar flow
           —  linear (Darcian flow)
           —  steady-state
           —  transient

        •  Flow processes included
           —  areal recharge
           -  induced recharge (from river)
           —  evapotranspiration

        •  Changing aquifer conditions
           —  in space
              -  variable thickness
              -  confined/unconfined

           —  in time
              -  confined/unconfined

        •  Well characteristics
           —  none

4.2.  Fluid Conditions
        •  Single Fluid Flow
           —  water

        •  Flow of Multiple Fluids
           -  N.A.

        •  Fluid Properties
           -  constant in time/space

                                                              Page 4d-3

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Section 4:  Model Descriptions          Model Description for Random Walk

4.3.  Boundary Conditions
        •  First Type - Dirichlet
          —  head/pressure

        •  Second Type - Neumann (Prescribed Flux)
          —  injection/production wells
          —  no flow boundary
          —  areal boundary flux
          —  ground-water recharge
          —  springs
          -  induced infiltration

        •  Third Type - Cauchy
          —  head/pressure-dependent flux
4.4.  Solution Methods for Flow
        •  General Method
          — Numerical

        •  Spatial Approximation
          — finite difference method
          — node-centered

        •  Time-Stepping Scheme
          - fully implicit

        •  Matrix-Solving Technique
          — Iterative
          - iterative ADIP
          — Direct
          — Gauss elimination

4.5.  Grid Design
        •  Cell/Element Characteristic
          — constant cell size
          — variable cell size

        •  Possible Cell Shapes
          - 2D-square
          — ID-rectangular

        •  Maximum Number of Nodes
          - 5000
Page 4d-4

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 Section 4: Model Descriptions	Model Description for Random Walk
 4.6.   Flow Output Characteristics
        •  Simulation Results
           -  head/pressure/potential
              -   ASCn file (areal values)
              -   ASCII file (hydrograph)
           -  fluxes/velocities
              -   ASCII file (areal values)
           —  water budget components
              -   ASCn file (cell-by-cell values)
              -   ASCII file (global total area)
5.    Mass  Transport Characteristics

5.1.   Water Quality Constituents
           any component(s)
           single component
           total dissolved solids (TDS)
           inorganics
           organics
           radionuclides
5.2.  Processes Included
        •  (Conservative) Transport
           -  advection
           —  dispersion
           -  isotropic
           —  anisotropic
           —  diffusion

        •  Phase Transfers
           —  equilibrium
           —  isotherm

        •  Fate
           —  first-order radioactive decay (single mother/daughter decay)
           —  first-order chemical decay
5.3.  Boundary Conditions
        •  First Type - Dirichlet
          - Chemical processes embedded in transport equation
          — concentration
                                                              Pag* 4d-S

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Section 4: Model Descriptions          Model Description for Random Walk

        •  Second Type - Neumann (Prescribed Solute Flux)
           —  areal boundaries
           —  injection wells
           —  point sources
           —  line sources
           —  areal sources

5.4.  Solution Methods for Transport
        •  General Method
           —  numerical
           —  uncoupled flow and transport equation

        •  Spatial Approximation
           —  finite difference method
           —  node-centered
           —  particle-tracking

        •  Time-Stepping Scheme
           -  fully implicit

        •  Matrix-Solving Technique
           -  Random Walk
           —  direct
           —  Gauss elimination
5.5.  Output Characteristics for Transport
        •   Simulation Results
           —  concentration in aquifer/soil
              -  ASCE file (areal values)
              -  ASCII file (time series)
           -  concentration in well
              - ASCH file (time series)
           -  velocities (from given heads)
              -  ASOI file (areal values)
           —  mass balance components
              - ASCE file (cell-by-cell values)
              - ASCH file (global total area)
6.   Evaluation

6.1.  Verification/Validation
        •  verification (analytic solutions)
        •  code intercomparison

6.2.  Internal Code Documentation (Comment Statements)
        •  incidental
Page 4d-€

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 Section 4s  Model Descriptions	Model Description for Random Walk
6.3.  Peer (Independent) Review
        •  concepts
        •  theory (math)
 7.   Documentation and Support

 7.1.  Documentation Includes
          model theory
          user's  instructions
          example problems
          program structure and development
          code listing
          verification/validation

 7.2.  Support Needs
        •  Can be used without support
        •  Support is available
          —  from  author
          —  from third parties

 7.3.  Level of Support
        •  limited
8.   Availability

8.1.  Terms
        •  available
        •  public domain
        •  proprietary
        •  purchase

8.2.  Form
        •  source code only (tape/disk)
        •  source and compiled code
        •  compiled code only
        •  paper listing of source code
9.   Pr0 and Post Processors

9.1.  Data Preprocessing
       •  name:  PREWALK (IGWMC)
          -  separate (optional) program
          -  textual data entry/editing
          -  data reformatting
          —  error-checking
                                                            Page 4d-7

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Sect/on 4: Model Descriptions          Model Description for Random Walk

       •  name: MODELCAD
          —  separate (optional) program
          —  generic (can be used for various models)
          -  textual data entry/editing
          —  graphic data entry/modification (e.g manual grid design,
             arrays)
          —  data  reformatting (e.g. for GIS)
          —  error-checking
          —  help screens

9.2.  Data Postprocessing
       •  name:  POSTWALK (IGWMC)
          —  separate (optional) program
          —  textual data display on screen/printer
          —  reformatting (e.g. to standard formats)
1O.  Institution of Model Development

10.1. Name
          Illinois State Water Survey

10.2. Address
          P.O. Box 5050
          Sta.A
          Urbana, IL 61820

10.3. Type of Institution
        •  state/provincial government

11.  Remarks

Various microcomputer versions are available among others from the
International Ground Water Modeling Center:

            IGWMC USA:     Inst. for Ground-Water Res. and Educ.,
                              Colorado School of Mines,
                              Golden, CO 80401, USA.

            IGWMC Europe:   TNO Institute of Applied Geostience,
                              P.O. Box 6012
                              2600JA Delft
                              The Netherlands.
Page 4d-8

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Section 4:  Model Descriptions	Model Description for Random Walk
Code is available from:
Bob  Sinclair
Director of Computer Service
Illinois State Water Survey
Box 5050
Station  A
Champaign, IL 61820
telephone (217) 333-4952
at cost of magnetic tape, copying and postage.

Code is also available from:
Thomas A. Prickett
6 G.H. Baker Drive
Urbana, IL 61801
Phone 217/384-0615
A modified version of PLASM and RANDOM WALK to analyze hydrologic
impacts of mining is documented in U.S. Office of Surface Mining (1981; see
user references).  Program codes are available through Boeing Computer
Network.
MODELCAD is a graphical oriented, model-independent pre-processor to
prepare and edit input files for two- and three-dimensional ground-water
models, including aquifer properties, boundary conditions, and grid
dimensions. The program prepares input files for MODFLOW, MOC, PLASM
and RANDOM WALK, among others.  File formatting routines for other
models are available upon request.  Contact:

                        Geraghty & Miller Modeling Group
                        1895 Preston White Drive
                        Suite 301, Reston, VA 22091
                        (703) 476-0335
                                                             Page 4d-9

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Section 4:  Model Descriptions          Model Description for Random Walk

12.  References

   Prickett, T.A. and C.G. Lonnquist. 1971. Selected Digital Computer
      Techniques for Groundwater Resource Evaluation.  Bulletin 55, Illinois
      State Water Survey, Champaign, Illinois.

   Navmik, T.G. and M.J. Barcelona. 1981. Characterization of a
      Contaminant Plume in Groundwater, Meredesia, Illinois.  Ground
      Water, Vol. 19(5), pp. 517-526.

   Prickett, T.A., T.G. Naymik and C.G. Lonnquist.  1981. A Random-Walk
      Solute Transport Model for Selected Groundwater Quality Evaluations.
      Bulletin 65, Illinois State Water Survey, Champaign, Illinois.

   Naymik, T.G. and M.E. Sievers.  1983. Groundwater Tracer Experiment (II)
      at Sand  Ridge State Forest. Illinois State Water Survey Division,
      Illinois Dept. of Energy and Natural Resources, Report 334, Champaign,
      Illinois, pp. 1-105.
Page 4d-10

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Sect/on 4s  Model Descriptions	Model Description for Random Walk
13.  Users

   U.S. Office of Surface Mining.  1981.  Groundwater Model Handbook.
      Kept. H-D3004-021-81-1062D, U.S. Dept. of Interior, Western Technical
      Service Center, Denver, Colorado.

   Royce, B., M. Garrell, A. Kahn and E. Kaplan.  1983. A Methodology for
      Modeling the Migration of Eor Chemicals in Fresh Water Aquifers.
      Prepared for Bartlesville Energy Technology Center, Order No. DE-
      API 9-82BC99996, U.S. Dept. of Energy, West Virginia.

   Johnson, R. and S.A. Dendrou.  1984.  Evaluation of the Potential Water
      Supply Impacts Posed by the Transgulf Pipeline, Broward County,
      Florida.  In: Proceed. Practical Applications of Ground Water Models,
      Columbus, Ohio, August 15-17, 1984, pp. 584-601.  Nat. Water Well
      Assoc., Dublin, Ohio.

   Wright, S.J. 1984.  Modeling Contaminant Migration Under the Influence
      of a Series of Pumping Wells.  In: Proceed. Practical Applications of
      Ground Water Models, Columbus, Ohio, August 15-17, 1984, pp. 462-
      477. Nat. Water Well Assoc., Dublin, Ohio.

   Herweijer, J.C., G.A. Van Luijn and C.A.J. Appelo.  1985. Calibration of a
      Mass Transport Model Using Environmental Tritium. Journ. of
      Hydrology, Vol.  , pp.

   Naymik, T.G. and M.E. Sievers. 1985.  Characterization of Dyetracer
      Plumes: In Situ Field Experiments. Ground Water, Vol. 223(6), pp. 746-
      752.

   American Petroleum Institute.  1986.  Cost Model for Selected
      Technologies for Removal of Gasoline Components from
      Groundwater. API Publication No. 4422, American Petroleum
      Institute, Washington D.C.

   Anderson, M.P. and C.J. Bowser. 1986. The Role of Groundwater in
      Delaying Lake Acidification. Water Resources Research, Vol. 22(7), pp.
      1101-1108.

   Taylor, M.D., M.K. Leslie, and R.C. Johnson. 1989. Groundwater Modeling
     Key to Isolating Contamination.  Water and Waste Water
     International, February 1989.
                                                            Page 44-11

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