United States
Environmental Protection
Agency
Office of Air Quality
Planning and Standards
Research Triangle Park, NC 27711
EPA-454/R-00-013t/'
April 2000
AIR
   &EPA

   Final Report

   Manual Testing and Continuous
   Emissions Monitoring, Kiln No. 2
   Scrubber Inlet and Outlet and Kiln
   No. 3 Baghouse Inlet and Stack
   Austin White Lime Company
   Austin, Texas

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                       FINAL REPORT

MANUAL TESTING AND CONTINUOUS EMISSIONS MONITORING
         KILN NO. 2 SCRUBBER INLET & OUTLET AND
            KILN NO. 3 BAGHOUSE INLET & STACK

               AUSTIN WHITE LIME COMPANY
                       AUSTIN, TEXAS
                   EPA Contract No. 68-D98-004
                    Work Assignment No. 3-03


                          Prepared for:

                   Mr. Michael L. Toney (MD-19)
                    Work Assignment Manager
                      SCGA, EMC, OAQPS
                U.S. Environmental Protection Agency
                 Research Triangle Park, NC 27711

                           April 2000
                sp:\s523\fmrpts\texas\austwhte\report\aw-rpt.wpd


                          Submitted by

           PACIFIC ENVIRONMENTAL SERVICES, INC.
                   5001 S. Miami Blvd., Suite 300
                      Post Office Box 12077
               Research Triangle Park, NC 27709-2077
                        (919) 941-0333
                       FAX (919) 941-0234
                                              U.S. Environmental Protection Agency
                                              Region 5, Library (PL-12J)
                                              77 West Jackson Boulevard, 12th Floor
                                              Chicago. IL 60604-3590

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                                   DISCLAIMER

      This document was prepared by Pacific Environmental Services, Inc. (PES) under EPA
Contract No. 68-D98-004, Work Assignment No. 3-03. This document has been reviewed
following PES' internal quality assurance procedures and has been approved for distribution. The
contents of this document do not necessarily reflect the views and policies of the U.S.
Environmental Protection Agency (EPA). Mention of trade names does not constitute
endorsement by the EPA or PES.
                                         11

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                        TABLE OF CONTENTS


                                                             Paee

1.0   INTRODUCTION	  1-1

2.0   SUMMARY OF RESULTS	2-1

     2.1   KILN NO. 3	2-1
     2.2   KILN NO. 2	2-9

3.0   PROCESS DESCRIPTION	3-1

4.0   SAMPLING LOCATIONS 	4-1

     4.1   KILNNO. 3	4-1
     4.2   KILN NO. 2	4-5

5.0   SAMPLING AND ANALYSIS PROCEDURES	5-1

     5.1   LOCATION OF MEASUREMENT SITES AND
          SAMPLE/VELOCITY TRAVERSE POINTS 	5-1
     5.2   DETERMINATION OF EXHAUST GAS VOLUMETRIC
          FLOW RATE	5-1
     5.3   DETERMINATION OF EXHAUST GAS MOISTURE CONTENT	5-1
     5.4   DETERMINATION OF PCDDs/PCDFs 	5-4
     5.5   DETERMINATION OF HYDROGEN CHLORIDE 	5-4
     5.6   DETERMINATION OF CARBON DIOXIDE, OXYGEN, AND
          TOTAL HYDROCARBONS	5-6
     5.7   CEMs DATA ACQUISITION AND HANDLING	5-9

6.0   QUALITY ASSURANCE/QUALITY CONTROL PROCEDURES (QA/QC)
     AND RESULTS 	6-1

     6.1   CALIBRATION AND PREPARATION OF APPARATUS	6-1
     6.2   REAGENTS AND GLASSWARE PREPARATION	6-4
     6.3   ON-SITE SAMPLING	6-5
     6.4   LABORATORY ANALYSES	6-8
     6.5   QA COORDINATOR FIELD AUDIT	6-12
                                111

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                     TABLE OF CONTENTS (Concluded)
APPENDICES
     APPENDIX A  -RAWFIELDDATA	A-l
     APPENDIX B  -METHOD 23 LABORATORY ANALYTICAL DATA  	B-l
     APPENDDC C  - CALCULATIONS & COMPUTER SUMMARY 	C-l
     APPENDIX D  - EXAMPLE EQUATIONS	...>....	D-l
     APPENDDCE  -QA/QCDATA	E-l
     APPENDDCF  - PROCESS DATA	F-l
     APPENDIXG  - SAMPLING & ANALYSIS METHODS	G-1
     APPENDIX H  - PROJECT PARTICIPANTS  	H-l
                               IV

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                                 LIST OF TABLES
                                                                              Page

Table 2.1      Emissions Test Log, Austin White Lime Company - Austin, Texas	2-2
Table 2.2      Air Flow Rates & Exhaust Gas Parameters, Kiln No. 3 Baghouse Stacks,
             Austin White Lime Company - Austin, Texas	2-3
Table 2.3      PCDDs/PCDFs Sampling and Exhaust Gas Parameters, Kiln No. 3 Baghouse
             Inlet and Stack (North 3), Austin White Lime Company - Austin, Texas	2-4
Table 2.4      PCDDs/PCDFs Concentrations and Emission Rates, Kiln No. 3
             Baghouse Inlet and Outlet, Austin White Lime Company - Austin, Texas .... 2-6
Table 2.5      PCDDs/PCDFs Concentrations and 2378-TCDD Toxic Equivalent
             Concentrations Adjusted to 7 Percent Oxygen, Kiln No. 3 Baghouse Inlet
             and Stack (North 3), Austin White Lime Company - Austin, Texas	2-7
Table 2.6      HC1 and THC Concentrations and Emission Rates, Kiln No. 3 Baghouse
             Inlet and Stack, Austin White Lime Company - Austin, Texas	2-8
Table 2.7      PCDDs/PCDFs Sampling and Exhaust Gas Parameters, Kiln No. 2
             Scrubber Inlet and Outlet, Austin White Lime Company - Austin, Texas .... 2-10
Table 2.8      PCDDs/PCDFs Concentrations and Emission Rates, Kiln No. 2
             Scrubber Inlet and Outlet, Austin White Lime Company - Austin, Texas .... 2-11
Table 2.9      PCDDs/PCDFs Concentrations and 2378-TCDD Toxic Equivalent   .
             Concentrations Adjusted to 7 Percent Oxygen, Kiln No. 2,
             Scrubber Inlet and Outlet, Austin White Lime Company - Austin, Texas .... 2-13
Table . 10      HC1 and THC Concentrations and Emission Rates, Kiln No. 2,
             Scrubber Inlet and Outlet, Austin White Lime Company - Austin, Texas .... 2-14

Table 5.1      Summary of Sampling and Analysis Methods, Austin White Lime
             Company - Austin, Texas	5-2
Table 5.2      Summary of Sampling Locations, Test Parameters, Sampling Methods,
             and Number and Duration of Tests, Austin White Lime Company -
             Austin,  Texas	5-3

Table 6.1      Summary of Temperature Sensor Calibration Data	6-2
Table 6.2      Summary of Pitot Tube Dimensional Data 	6-4
Table 6.3      Summary of Dry Gas Meter and Orifice Calibration Data	6-4
Table 6.4      Summary of EPA Methods 23 Field Sampling QA/QC Data	6-7
Table 6.5      Summary of Calibration Gas Cylinders	6-7
Table 6.6      Summary of Method 322 HC1 In Situ Spiking Data	6-9
Table 6.7      Summary of EPA Method 23 Blanks and Sample Catches	6-10
Table 6.8      Summary of EPA Method 23 Standards Recovery Efficiencies	6-11

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                                 LIST OF FIGURES
                                                                                Page
                                                                i'.'f1 •'*'
Figure 1.1    Project Organization - US EPA Texas Lime Kiln Screening,
             Austin White Lime Company - Austin, Texas	 1-3

Figure 4.1    Kiln No. 3 Process Exhaust Gas Schematic, Austin White Lime Company -
             Austin, Texas	4-2
Figure 4.2    Kiln No. 2 Process Exhaust Gas Schematic, Austin White Lime
             Company - Austin, Texas	4-3
Figure 4.3    Kiln No. 3 Baghouse Inlet Sample Ports and Sample Point Locations,
             Austin White Lime Company - Austin, Texas	4-4
Figure 4.4    Kiln No. 3 Baghouse Typical Stack Sample Ports and Sample Point Locations
             For Isokinetic Testing, Austin White Lime Company - Austin, Texas  	4-6
Figure 4.5    Kiln No. 2 Scrubber Inlet Sample Ports and Sample Point Locations,
             Austin White Lime Company - Austin, Texas	4-7
Figure 4.6    Kiln No. 2 Scrubber Outlet Sample Ports and  Sample Point Locations,
             Austin White Lime Company - Austin, Texas	4-8

Figure 5.1    Sampling Train Schematic for EPA Method 23, Proposed Revisions  	5-5
Figure 5.2    Sampling Train Schematic for EPA Proposed  Method 322   	5-7
Figure 5.3    Sampling Train Schematic for EPA Methods 3A and 25A 	5-8
                                          VI

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                                1.0 INTRODUCTION
       The U.S. Environmental Protection Agency (EPA) Office of Air Quality Planning and
Standards (OAQPS) Emission Standards Division (ESD) is investigating the lime manufacturing
industry to identify and quantify hazardous air pollutants (HAPs) emitted from Line kilns. ESD
requested that EPA OAQPS Emissions, Monitoring and Analysis Division (EMAD) conduct the
required testing. EMAD issued a work assignment to Pacific Environmental Services, Inc. (PES)
to conduct a "screening" test to collect air emissions data as specified in the ESD test request.
Initial planning, pre-test site survey, and preparation activities were conducted under EPA
Contract No. 68-D7-0002, Work Assignment No. 0/005. Remaining preparation and field
mobilization were conducted under EPA Contract No. 68-D7-0002, Work Assignment
No. 1/007. The draft final report was completed under EPA Contract No. 68-D98-004, Work
Assignment No. 2-04. Generation of the Final Report, incorporating EPA's comments on the
Draft Final Report, was completed under EPA Contract No.  68-D98-004, Work
Assignment 3-03.

       The primary objective was to characterize the uncontrolled and controlled emissions of
selected HAPs from two rotary kilns located at Austin White Lime Company's Austin, Texas
facility.  The "screening" tests were conducted to quantify the air emissions of hydrogen chloride
(HC1), total hydrocarbons (THC), and polychlorinated dibenzo-p-dioxins and  polychlorinated
dibenzofurans (PCDDs/PCDFs). The basic test methods that were employed  were US EPA Test
Methods 1 (sample point  location), 2 (effluent gas velocity),  3 A (oxygen and carbon dioxide
content), 4 (moisture content), 23 (PCDDs/PCDFs content) with proposed revisions, 25A (THC
content), and Proposed Method 322 (HC1 content).

       Testing at Kiln No. 3 was conducted on June 30, 1998.  One 3-hour test, comprised of the
sampling methods mentioned previously, was conducted at the baghouse inlet and  two baghouse
outlet stacks - stack "North 3" for  the isokinetic PCDDs/PCDFs sampling and stack "South 2" for
the oxygen (O2), carbon dioxide (CO2), THC, and HC1 sampling; inlet and outlet sampling were
performed simultaneously. Volumetric air flow rate traverses were also made on the seven
baghouse stacks not tested isokinetically so that a total baghouse air flow rate determination
could be made for use in calculating estimated total controlled emission rates  at the baghouse
outlet.

       Kiln No. 2 was tested on July 1, 1998. The scrubber inlet and scrubber outlet were tested
simultaneously for one 3-hour run  using the same sampling methods noted above.

       PES used three subcontractors for this effort: Air Pollution Characterization and Control,
Ltd. (APCC), Paradigm Analytical Laboratories, Inc. (PAL), and Atlantic Technical Services, Inc.
                                         1-1

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(ATS). APCC provided field testing support for measurement of O2, CQ^, THC, and HC1
concentrations using Continuous Emission Monitors (CEMs); PAL prepared the XAD*-2 sorbent
resin traps and performed the analysis of the Method 23 sample fractions to determine catch
weights of PCDDs/PCDFs congeners; and ATS provided support during preparation of the
Quality Assurance Project Plan (QAPP), She Specific Test Plan (SSTP), field testing and field
data reduction, reduction of laboratory analytical data, and preparation of the Draft Final Report.

       The PES test crew consisted of Michael D. Maret (who served as the Task Manager and
Field Team Leader), Dennis P. Holzschuh (on site Quality Assurance Coordinator^ Troy
Abernathy, Gary Gay, Dennis D. Holzschuh, and Paul Siegel.  APCC was represented by Eric
Dithrich and Peter Day; ATS was represented by Emil Stewart. Also present during the testing
was Michael L. Toney, the EPA Work Assignment Manager, and Cybele M. Brockmann of
Research Triangle Institute  (RTI), an ESD contractor. Austin White Lime Company was
represented by Curt Shane.

       Figure 1.1 presents the project organization and major lines of communication.
Section 2.0 presents the results of the testing;  Section 3.0 is reserved for a process description
and operational data; Section 4.0 presents descriptions of the sampling locations; Section 5.0
presents descriptions of the sampling and analysis procedures; and Section 6.0 presents the
Quality Assurance/Quality Control procedures that were employed during the testing program,
and the results of calibrations and analytical QA data.  Copies of all field data generated during
the testing, the subcontracting laboratory analytical report, computer calculations and example
calculations, calibration data and compressed gas certifications of analysis, project participants,
and reprints of the EPA Test Methods are presented in the appendices to this document.
Appendix F is reserved for process and operational  data.
                                          1-2

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                                      Austin White Lime Company

                                             Curt Shane
                                           (512)255-0457
                                                  I
                                              EPA/EMC
                                        Work Assignment Manager
                                           Michael L. Toney
                                            (919)541-5247
                                                I
                                             EPA/ESD

                                          Joseph P. Wood
                                          (919)541-5446
                                                                           PES
                                                                     Program Manager
                                                                     John T. Chehaske
                                                                      (919)941-0333
                                                            PES
                                                   Corporate QA/QC Officer
                                                     Jeffrey L. Van Atten
                                                       (703)471-8383
                                                                          PES
                                                                     Project Manager
                                                                     Franklin Meadows
                                                                      (919)941-0333
                                                                          PES
                                                                      Task Manager
                                                                     Michael D. Maret
                                                                      (919)941-0333
                                                                   Research Triangle Institute
                                                                        BSD Contractor
                                                                     Cybele M. Brockmann
                                                                        (919)990-8654
   Pretest
 Site Survey

    FES
Quality Assurance
  Project Plan

      PES
Site Specific
 Test Plan

   PES
                           Subcontractor

                          Atlantic Technical
                           Services, Inc.
 Field
Testing

 PES
                             Subcontractor

                           Atlantic Technical
                             Services, Inc.
Sample
Analysis

  PES
                               Subcontractor

                         Air Pollution Characterization
                              and Control, Ltd
                                                                                      Subcontractor

                                                                                     Atlantic Technical
                                                                                      Services, Inc.
Draft Final
  Report

   PES
                              Subcontractor

                           Paradigm Analytical
                            Laboratoriet, Inc.
                         Subcontractor

                       Atlantic Technical
                         Services Bio.
Figure 1.1  Project Organization - US EPA Texas Lime Kiln Screening, Austin White Lime Company - Austin, Texas

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                            2.0 SUMMARY OF RESULTS
       This section summarizes the results of the testing that was conducted on two of the rotary
lime kilns at Austin White Lime Company's facility at Austin, Texas. Testing was conducted at
the inlet and outlet stacks of the baghouse used to control the paniculate emissions from Kiln
No 3. Kiln No. 2 was tested at the scrubber inlet and scrubber outlet locations. Table 2.1
presents the Emissions Test Log, which summarizes the sample run designators, test dates and
times, target pollutants, and downtimes for port changes and other stoppages. Kiln No. 3 flue gas
parameters, pollutant concentrations, and pollutant mass emission rates at the baghouse inlet and
outlet are summarized in Tables 2.2 through 2.6; Tables 2.7 through 2.10 summarize the results
of the testing at the Kiln No. 2 scrubber inlet and outlet locations.
2.1    KILN NO. 3

2.1.1   Baghouse Outlet Total Air Flow Rate Determination

       The baghouse controlling the particulate emissions from Kiln No. 3 consists of eight
separate baghouse modules, with each module having a separate exhaust stack.  PCDDs/PCDFs
testing was performed on the North 3 stack; CEMs testing was performed at the South 2 stack.
All eight stacks were traversed using Method 2 procedures to measure exhaust gas velocities and
subsequently determine the volumetric air flow rates at each of the eight stacks. The O2 and C02
concentrations as measured at the South 2 stack and the moisture concentration as measured at
the North 3 stack were used in the flow rate calculations for all the stacks. Table 2.2 presents the
air flow rates for each of the eight baghouse outlet stacks and the total baghouse outlet flow rate.

2.1.2   PCDDs/PCPFs Measurements

       Table 2.3 presents the Method 23  sampling parameters and parameters of the baghouse
inlet and outlet exhaust gases.  One Method 23 sampling run was performed at the baghouse inlet
location, and one Method 23 sampling run was performed at the outlet location. Both runs were
conducted simultaneously, and both sample runs were within the isokinetic sampling ratio
criterion of 100 ± 10 percent (%); the isokinetic sampling  ratio for the inlet run (M23-I-3) was
102.4% and the isokinetic sampling ratio for the outlet run (M23-O-3) was 101.9%. For
purposes of the calculation of the volumetric flow rates, 02 and CO2 data were determined from
the Method 3 A CEM data, and moisture content was determined by using the mass of condensate
collected in the impinger trains during the runs.
                                          2-1

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                               TABLE 2.1

                         EMISSIONS TEST LOG
           AUSTIN WHITE LIME COMPANY - AUSTIN, TEXAS
Run No.
Kiln No. 3 Baghouse Inlet
M23-I-3
M3A-I-3
M25A-I-3
M322-I-3
Date

06/30/98
06/30/98
06/30/98
06/30/98
Kiln No. 3 Baehouse Stack South 2

South 2
M3A-0-3
M25A-O-3
M322-O-3
06/30/98
06/30/98
06/30/98
06/30/98
Kiln No. 3 Baehouse Stack North 3

M23-O-3
06/30/98
Pollutant
Run Time

PCDDs/PCDFs
C02 / O2
THC
HC1
1248-1605
1418-1558
1418-1558
1418-1558
L. llMMliiiie,
vMwrtes'

17
40
40
40

Air Flow Rate
CO2 / 02
THC
HC1
0856
1248-1508
1248-1508
1248-1508
NA
80
80
80

PCDDs/PCDFs
1247-1612
25
Kiln No. 3 Baghouse Stacks
South 1, 3, & 4
North 1, 2, & 4
06/30/98
06/30/98
Air Flow Rates
Air Flow Rates
0850-0910
0920-1414
NA
NA
Kiln No. 2 Scrubber Inlet
M23-I-4
M3A-I-4
M25A-I-4
M322-I-4
07/1/98
07/1/98
07/1/98
07/1/98
PCDDs/PCDFs
CO2 / 02
THC
HC1
1415-1736
1445-1705
1445-1705
1445-1705
21
80
80
80
Kiln No. 2 Scrubber Outlet
M23-O-4
M3A-O-4
M25A-O-4
M322-O-4
07/1/98
07/1/98
07/1/98
07/1/98
PCDDs/PCDFs
C02/02
THC
HC1
1414-1734
1415-1635
1415-1635
1415-1635
20
80
80
80
The CEMs sample acquisition system operated on a time-shared basis, switching between the inlet and
outlet locations. This applies to Methods 3A, 25A, and Proposed Method 322.
                                   2-2

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                                                     TABLE 2.2

                               AIR FLOW RATES & EXHAUST GAS PARAMETERS
                                         KILN NO. 3 BAGHOUSE STACKS
                               AUSTIN WHITE LIME COMPANY - AUSTIN; TEXAS
Run No.
Date
Traverse Times
Average Exhaust Gas Temperature, °F
O2 Concentration, % by Volume
CO2 Concentration, % by Volume
Moisture, % by Volume
Exhaust Gas Volumetric Flow Rate:
acfinb
dscfin c
dscmmd
South 1
6/30/98
0850
366
a
a
a

8,390
4,760
135
South 2
6/30/98
0856
367
10.7
18.0
a

9,440
5,350
152
South 3
6/30/98
0904
371
a
a
a

10,170
5,730
162
South 4
6/30/98
0910
364
a
a
a

11,330
6,440
182
North 1
6/30/98
0920
384
a
a
a

12,560
6,980
198
North!
6/30/98
0925
378
a
a
a

10,010
5,590
158
North3
M23-O-3
6/30/98
1247-1612
401
a
a
10.1

13,230
7,200
204
North 4
6/30/98
1414
311
a
a
a

4,380
2,660
75
Baghouse
Total

na
na
na
na

79,500
44,700
1,270
* For calculation purposes, the O2 and CO2 values are from the CEMs testing at South 2 Stack while the moisture is from the PCDDs/PCDFs testing
 at the North 3 Stack (Run M23-O-3).
b Actual cubic feet per minute at exhaust gas conditions.
0 Dry standard cubic feet per minute at 68° F (20° C) and 1 atm.
d Dry standard cubic meters per minute at 68° F (20" C) and 1 atm.
                                                         2-3

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                            TABLE 2.3
   PCDDs/PCDFs SAMPLING AND EXHAUST GAS PARAMETERS
      KILN NO. 3 BAGHOUSE INLET AND STACK (NORTH 3)
        AUSTIN WHITE LBME COMPANY - AUSTIN, TEXAS
Run No.
Date
Time
Total Sampling Time, minutes
Average Sampling Rate, dscfin *
Sample Volume:
dscfb
dscm"
Average Exhaust Gas Temperature, °F
02 Concentration, % by Volume d
C02 Concentration, % by Volume d
Moisture, % by Volume
Exhaust Gas Volumetric Flow Rate, acfin ':
As Measured at Inlet & North 3 Stack
Baghouse Total, Sum of 8 Stacks f
Exhaust Gas Volumetric Flow Rate, dscfin ':
As Measured at Inlet & North 3 Stack
Baghouse Total, Sum of 8 Stacks f
Exhaust Gas Volumetric Flow Rate, dscmm B:
As Measured at Inlet & North 3 Stack
Baghouse Total, Sum of 8 Stacks f
Isokinetic Sampling Ratio, %
M23-I-3
6/30/98
1248-1605
180
0.602

108.393
3.069
430
9.5
19.2
10.9

78,200
-

38,800
-

1,100
-
102.4
M23-O-3
6/3tfM
1247~16I2
180
0.778

140.031
3.965
401
10.7
18.0
10.1

13,200
79,500

7,200
44,700

204
1,270
101.9
• Dry standard cubic feet per minute at 68' F (20' C) and 1 atm,
b Dry standard cubic feet at 68' F (20' C) and 1 atm.
 Dry standard cubic meters at 68' F (20' C) and 1 atm.
 O2 and CO2 values are from the CEMs sampling performed concurrently at the South 2 Stack.
 Actual cubic feet per minute at exhaust gas conditions.
 Air flow rate data presented for the outlet is the sum of the 8 stacks exhausting the baghouse.
 Dry standard cubic meters per minute at 68* F (20* C) and 1 atm.
                                 2-4

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      From time to time during the Method 23 analyses, a peak elutes at the position expected
for a particular congener, but the peak fails validation based on the theoretical split of chlorine
isotopes.  That is to say that the number of Cl35 isotopes and the number of Cl37 isotopes attached
to the PCDDs/PCDFs congeners should agree with the C135/C137 ratio found in nature. For each
congener, this ratio must agree within fifteen percent.  If the mass ratio of chlorine isotopes does
not agree with the natural chlorine isotope ratio then the peak is flagged as an Estimated
Maximum Possible Concentration, or "EMPC".

      In-stack concentrations and associated mass emission rates of the PCDDs/PCDFs
congeners are given in Table 2.4 for the inlet and North 3 stack sampling runs. Also shown are
the estimated total baghouse outlet PCDDs/PCDFs emission rates calculated using the North 3
stack PCDDs/PCDFs concentrations and the sum of the volumetric air flow rates measured at the
eight individual stacks as tabulated in Table 2.2. Because the testing was for screening purposes
only, the operating efficiencies and, therefore, the outlet concentrations of the eight baghouse
modules were assumed to be the same.  The actual total emission rates from the baghouse may be
higher or lower than the reported results, depending on the actual operating efficiency of each of
the eight baghouse modules.

      The values presented as "Total PCDDs" are the sum of the "12346789 OCDD"
polychlorinated dibenzo-p-dioxin and all of the dioxins labeled "Total"; "Total PCDFs" values are
the sum of the "12346789 OCDF" polychlorinated dibenzofuran and all of the furans labeled
"Total". "Total PCDDs + Total PCDFs" values are the sum of the "Total PCDDs" and "Total
PCDFs" values.  Values that have been qualified as being EMPC have been included in the sums.
Concentrations and emission rates that are based on or including EMPC values are denoted by
braces ({}). Concentrations and emission rates based on values that have been qualified as being
below the detection limit (Not Detected),  or ND, are denoted by parentheses ( ( )).

      Table 2.5 presents two PCDDs/PCDFs concentration-based measurements for both the
inlet  and the outlet sampling locations.  In the second and third columns of the table, the in-stack
concentrations of the 2378-PCDDs/PCDFs congeners as well as the homologues (i.e., PCDDs
and PCDFs groups that have the same degree of chlorination) are presented adjusted to 7% O2.
The fifth and sixth columns of the table present the 2378 tetra-chloro dibenzodioxin (TCDD)
toxic equivalent values for those congeners chlorinated at the 2, 3, 7, and 8 positions. These
columns represent the in-stack concentrations of the 2378 congeners after being adjusted for
toxicity relative to 2378-TCDDs. PCDDs/PCDFs congeners that are not chlorinated at the 2, 3, 7,
and 8 positions have a relative toxicity of zero and therefore the total homologues (e.g., Total
TCDD) are not presented in the Toxic Equivalency  columns.

2.1.3 CEM Measurements

      Measurements were conducted at the baghouse inlet and the outlet to determine the
concentrations of O2, C02, THC, and HC1. These measurements were conducted using CEMs.
The CEMs were housed in a trailer supplied by APCC. Table 2.6 presents the average THC and
HC1  concentrations and mass emission rates. Outlet emission rates were calculated using the
South 2 stack air flow rate and also using the sum of the flow rates from the eight stacks.
                                         2-5

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                                 TABLE 2.4

          PCDDs/PCDFs CONCENTRATIONS AND EMISSION RATES
                 KILN NO. 3 BAGHOUSE INLET AND OUTLET
              AUSTIN WHITE LIME COMPANY - AUSTIN, TEXAS

CONGENER
V> V/l^ VF J-Jl^ J^JLV

DIOXINS:
2378 TCDD
Total TCDD
12378 PeCDD
Total PeCDD
123478 HxCDD
123678 HxCDD
123789 HxCDD
Total HxCDD
1234678 HpCDD
Total HpCDD
12346789 OCDD
Total PCDDs
FURANS:
2378 TCDF
Total TCDF
12378 PeCDF
23478 PeCDF
Total PeCDF
123478 HxCDF
123678 HxCDF
234678 HxCDF
123789 HxCDF
Total HxCDF
1234678 HpCDF
1234789 HpCDF
Total HpCDF
12346789 OCDF
Total PCDFs
Total PCDDs + PCDFs
CONCENTRATION •
(ng/dscm, as measured)
M23-I-3
Inlet

{0.00101}
{0.00375}
0.000195
0.00117
(0.000261)
{0.000508}
{0.000964}
0.00287
{0.00262}
0.00195
0.00772
{0.0175}

{0.00239}
{0.0209}
0.000749
{0.000209}
{0.00358}
{0.00111}
{0.000443}
(0.000130)
(0.000130)
{0.00176}
0.00160
(0.000195)
0.00169
0.00117
{0.0291}
{0.0466}
M23-O-3
North 3

0.000378
0.00300
0.000151
0.00141
(0.000101)
0.000353
{0.000494}
0.00192
0.00113
0.00222
0.00421
0.0128

0.00136
0.0360
0.000958
{0.000605}
0.00787
0.000832
{0.000424}
{0.000293}
(0.000126)
0.00262
0.00159
{0.000282}
0.00192
0.00232
0.0507
0.0635
EMISSION RAH*
(ugM1'
M23-I-3
Inlet

{0.0663}
{0.247}
0.0129
0.0773
(0.0172)
{0.0335}
{0.0635}
0.189
{0.173}
0.129
0.509
{1.15}

{0.158}
{1.38}
0.0494
{0.0137}
{0.236}
{0.0730}
{0.0292}
(0.00859)
(0.00859)
{0.116}
0.105
(0.0129)
0.112
0.0773
{1.92}
{3.07}
M23-O-3
North3

0.00463
0.0367
0.00185
0.0173
(0.00123)
0.00432
{0.00605}
0.0234
0.0139
0.0271
0.0515
0.156

0.0167
0.441
0.0117
{0.00740}
0.0962
0.0102
{0.00518}
{0.00358}
(0.00154)
0.0321
0.0194
{0.00346}
0.0234
0.0284
0.621
0.777
Estimated
Total Outlet0

0.0287
0.228
0.0115
0.107
(0.00767)
0.0268
{0.0376}
0.146
0.0862
0.169
0.320
0.970

0.103
2.74
0.0728
{0.0460}
0.598
0.0632
{0.0322}
{0.0222}
(0.00958)
0.199
0.121
{0.0215}
0.146
0.176
3.86
4.83
 ' Nanogram per dry standard cubic meter at 20*C and 1 atm.
 b Micrograms per hour.
 0 Emission rates calculated using the sum of the eight air flow rates and the North 3 Stack concentrations.
()  Not Detected. Value shown is the detection limit and is included in totals.
{ } Estimated Maximum Possible Concentration. EMPC values are included in totals.
                                      2-6

-------
                                      TABLE 2.5
      PCDDs/PCDFs CONCENTRATIONS AND 2378-TCDD TOXIC EQUIVALENT
              CONCENTRATIONS ADJUSTED TO 7 PERCENT OXYGEN
               KILN NO. 3 BAGHOUSE INLET AND STACK (NORTH 3)
                 AUSTIN WHITE LIME COMPANY - AUSTIN, TEXAS

CONGENER

DIOXINS:
2378 TCDD
Total TCDD
12378 PeCDD
Total PeCDD
123478 HxCDD
123678 HxCDD
123789 HxCDD
Total HxCDD
1234678 HpCDD
Total HpCDD
12346789 OCDD
Total PCDDs
FURANS:
2378 TCDF
Total TCDF
12378 PeCDF
23478 PeCDF
Total PeCDF
123478 HxCDF
1 23678 HxCDF
234678 HxCDF
123789 HxCDF
Total HxCDF
1234678 HpCDF
1234789 HpCDF
Total HpCDF
12346789 OCDF
Total PCDFs
Total PCDDs + PCDFs
CONCENTRATION *
(ng/dscm, adjusted to 7 percent O,)
M23-I-3

{0.00123}
{0.00457}
0.000238
0.00143
(0.000318)
{0.000620}
{0.00118}
0.00350
{0.00319}
0.00238
0.00941
{0.0213}

{0.00292}
{0.0255}
0.000914
{0.000254}
{0.00437}
{0.00135}
{0.000540}
(0.000159)
(0.000159)
{0.00215}
0.00195
(0.000238)
0.00207
0.00143
{0.0355}
{0.0568}
M23-O-3

0.000516
0.00409
0.000206
0.00192
(0.000137)
0.000481
{0.000674}
0.00261
0.00155
0.00302
0.00574
0.0174

0.00186
0.0491
0.00131
{0.000825}
0.0107
0.00113
{0.000577}
{0.000399}
(0.000172)
0.00357
0.00217
{0.000385}
0.00261
0.00316
0.0691
0.0865
2378-TCDD k
Toxicity
Equivalency Factor

1.000

0.500

0.100
0.100
0.100

0.010

0.001
Total PCDDs TEQ

0.100

0.050
0.500

0.100
0.100
0.100
0.100

0.010
0.010

0.001
Total PCDFs TEQ
Total TEQ
2378 TOXIC EQUIVALENCIES
(ng/dscm, adjusted to 7 percent O2)
M23-I-3

{0.00123}

0.000119

(0.0000318)
{0.0000620}
{0.000118}

{0.0000319}

0.00000941
(0.00160)

{0.000292}

0.0000457
{0.000127}

{0.000135}
{0.0000540}
(0.0000159)
(0.0000159)

0.0000195
(0.00000238)

0.00000143
(0.000709)
(0.00231)
M23-O-3

0.000516

0.000103

(0.0000137)
0.0000481
{0.0000674}

0.0000155

0.00000574
(0.000769)

0.000186

0.0000653
{0.000412}

0.000113
{0.0000577}
{0.0000399}
(0.0000172)

0.0000217
{0.00000385}

0.00000316
(0.000920)
(0.00169)
  Nanogram per dry standard cubic meter at 20°C and 1 atm and corrected to 7 percent oxygen.
 b North Atlantic Treaty Organization, Committee on the Challenges of Modern Society. Pilot study on Information
  Exchange on Dioxins and Related Compounds: International Toxicity Equivalency Factor (I-TEF) Methods of Risk
  Assessment for Complex Mixtures of Dioxins and Related Compounds. Report No. 176, August 1988.
() Not Detected. Value shown is the detection limit and is included in totals.
{} Estimated Maximum Possible Concentration.  EMPC values are included in totals.
                                        2-7

-------
                          TABLE 2.6

    HCL AND THC CONCENTRATIONS AND EMISSION RATES
           KILN NO. 3 BAGHOUSE INLET AND STACK
       AUSTIN WHITE LIME COMPANY - AUSTIN, TEXAS
Run No.
Date
Time
Sampling Location
Total Sampling Time, minutes
O2 Concentration, % by Volume
CO2 Concentration, % by Volume
Moisture, % by Volume*
Volumetric Flow Rate, dscfm b
As Measured at Inlet & South 2 Stack
Sum of 8 Stacks
HC1:
Formula Weight, Ib/lb-mole
Concentration, ppmvw c
Concentration, ppmvd d
Concentration, ppmvd @ 7%O2 e
Emission Rate, Ib/hr f
As Measured
Using Sum of 8 Stacks Flow Rate
THCs (as propane):
Formula Weight, Ib/lb-mole
Concentration, ppmvw c
Concentration, ppmvd d
Concentration, ppmvd @ 7%02 c
Emission Rate, Ib/hr f
As Measured
Using Sum of 8 Stacks Flow Rate
M322-I-3
6/30/98
1418-1558
Inlet
60
9.5
19.2
10.9

38,800
-

36.47
1.5
1.68
2.05

0.371
-

44.11
10.3
11.6
14.1

3.08
-
M322-O-3
6/3
-------
       02 and C02 concentrations have been corrected for observed calibration and bias errors
 using Equation 6C-1, as required in Method 3 A, and HC1 concentrations have been corrected
 using Equation 1 in Proposed Method 322.  THC concentrations are presented uncorrected, as
 required in Method 25 A; the uncorrected Oj, CO2, and HC1 concentrations are given in Appendix
 A. 1.4. Refer to Appendix D for example equations.

       The CEMs collected data from the inlet and the outlet locations on a time-sharing basis.
 The system was switched from inlet to outlet and back again every thirty minutes. The first 10
 minutes of data from each 30-minute period were excluded from the calculation of average
 responses to allow for the time necessary to purge the CEMs system of the exhaust gases from
 the previous sampling location and for the responses to stabilize. Due to a pluggage in the inlet
 sampling system, the data from the first inlet 20-minute sampling period (1318-1338) was not
 reported; the last inlet sampling period was increased to 40 minutes (1518-1558).
 2.2    KILN NO. 2

 2.2.1  PCDDs/PCDFs Measurements

       Table 2.7 presents the Method 23 sampling parameters and parameters of the scrubber
 inlet and outlet exhaust gases.  One  Method 23 sampling run was performed at the scrubber inlet
 location, and one Method 23 sampling run was performed at the scrubber outlet location.  Both
 runs were conducted simultaneously, and both sample runs were within the isokinetic sampling
 ratio criterion of 100 ± 10%; the isokinetic sampling ratio for the inlet run (M23-I-4) was  103.3%
 and the isokinetic sampling ratio for the outlet run (M23-O-4) was 99.5%.  For purposes of the
 calculation of the volumetric flow rates, O2 and C02 data were determined from the Method 3 A
 CEM data, and moisture content was determined by using the mass of condensate collected in the
 impinger trains during  the runs.

       In-stack concentrations and associated mass emission rates of the PCDDs/PCDFs
 congeners are presented in Table 2.8 for the inlet and outlet sampling runs.  The table presents
 two inlet PCDDs/PCDFs emission rates based on two different inlet air flow rates - using the "as
 measured" flow rate and using the outlet air flow rate. The outlet flow rate was used to calculate
 total uncontrolled emission rates because approximately 50% of the kiln exhaust gases bypassed
.the inlet sampling location before entering the scrubber, thereby making the "as measured" inlet
 air flow rate non-representative of the total inlet air flow. The "...As Measured" emission rates
 were calculated using the "As Measured" air flow rate and concentrations of PCDDs/PCDFs as
 measured at the inlet.-  The "...From  Outlet" emission rates were calculated  by multiplying the
 "...As Measured" emission rate by the ratio of the outlet-to-inlet air flow rates.

       The values presented as "Total PCDDs" are the sum of the "12346789 OCDD"
 polychlorinated dibenzo-p-dioxin and all of the dioxins labeled "Total"; "Total PCDFs" values are
 the sum of the "12346789 OCDF" polychlorinated  dibenzofuran and all of the furans labeled
 "Total",  "Total PCDDs + Total PCDFs" values are the sum of the "Total PCDDs" and "Total
                                          2-9

-------
                           TABLE 2.7

   PCDDs/PCDFs SAMPLING AND EXHAUST GAS PARAMETERS
           KILN NO. 2 SCRUBBER INLET AND OUTLET
        AUSTIN WHITE LIME COMPANY - AUSTIN, TEXAS
Run No.
Date
Time
Total Sampling Time, minutes
Average Sampling Rate, dscfin '
Sample Volume:
dscfb
dscmc
Average Exhaust Gas Temperature, °F
O2 Concentration, % by Volume
CO2 Concentration, % by Volume
Moisture, % by Volume
Exhaust Gas Volumetric Flow Rates,
As Measured:
acfmd
dscfin'
dscmm e
Isokinetic Sampling Ratio, %
M23-I-4
7/1/98
1415-1736
180
0.595

107.021
3.031
347
10.5
16.2
12.8


20,200
11,200
318
103.3
M23-O-4
7/1^98
1414-1734
180
0.628

112.961
3.199
134
10.1
16.3
18.2


40,100
26,900
761
99.5
1 Dry standard cubic feet per minute at 68" F (20s C) and 1 atm.
b Dry standard cubic feet at 68° F (20° C) and 1 atm.
c Dry standard cubic meters at 68° F (20° C) and 1 atm.
d Actual cubic feet per minute at exhaust gas conditions.
e Dry standard cubic meters per minute at 68° F (20° C) and 1 atm.
                               2-10

-------
                                      TABLE 2.8

              PCDDs/PCDFs CONCENTRATIONS AND EMISSION RATES
                     KILN NO. 2 SCRUBBER INLET AND OUTLET
                 AUSTIN WHITE LIME COMPANY - AUSTIN, TEXAS

CONGENER



DIOXINS:
2378 TCDD
Total TCDD
12378 PeCDD
Total PeCDD
123478 HxCDD
123678 HxCDD
123789 HxCDD
Total HxCDD
1 234678 HpCDD
Total HpCDD
12346789 OCDD
Total PCDDs
FURANS:
2378 TCDF
Total TCDF
12378 PeCDF
23478 PeCDF
Total PeCDF
123478 HxCDF
1 23678 HxCDF
234678 HxCDF
123789 HxCDF
Total HxCDF
1 234678 HpCDF
1234789 HpCDF
Total HpCDF
1 2346789 OCDF
Total PCDFs
Total PCDDs + PCDFs
CONCENTRATION *
(ng/dscm, as measured)

M23-I-4


{0.000752}
0.00330
{0.000132}
{0.000792}
(0.000231)
{0.000251}
{0.000739}
0.00436
0.00224
0.00370
0.00634
{0.0185}

0.00766
0.0797
{0.00218}
{0.00235}
0.0144
{0.00135}
{0.000528}
{0.000251}
(0.000165)
0.00238
0.00155
(0.000297)
0.00158
{0.000818}
{0.0989}
{0.117}

M23-O-4


0.000406
0.00316
{0.000200}
0.000625
(0.000281)
{0.000413}
{0.000400}
0.00275
0.00250
0.00538
0.00682
0.0187

0.00941
0.0927
0.00241
0.00231
0.0185
0.00100
0.000500
{0.000275}
(0.000125)
0.00338
0.00175
(0.000219)
0.00175
0.00163
0.118
0.137
EMISSION RATE k
(pg/hr)
M23-I-4
(Air Flow Used
As Measured)

{0.0144}
0.0630
{0.00252}
{0.0151}
(0.00441)
{0.00479}
{0.0141}
0.0831
0.0428
0.0705
0.121
{0.353}

0.146
1.52
{0.0416}
{0.0448}
0.275
{0.0257}
{0.0101}
{0.00479}
(0.00315)
0.0453
0.0296
(0.00567)
0.0302
{0.0156}
{1.89}
{2.24}
M23-I-4
(Air Flow Used
From Outlet) '

{0.0343}
0.151
{0.00602}
{0.0361}
(0.0105)
{0.0114}
{0.0337}
0.199
0.102
0.169
0.289
{0.843}

0.349
3.64
{0.0994}
{0.107}
0.657
{0.0614}
{0.0241}
{0.0114}
(0.00753)
0.108
0.0708
(0.0136)
0.0723
{0.0374}
{4.51}
{5.36}

M23-0-4


0.0185
0.144
{0.00913}
0.0285
(0.0128)
{0.0188}
{0.0183}
0.126
0.114
0.245
0.311
0.855

0.429
4.23
0.110
0.106
0.845
0.0457
0.0228
{0.0126}
(0.00571)
0.154
0.0799
(0.00999)
0.0799
0.0742
5.38
6.24
   Nanogram per dry standard cubic meter at 20°C and 1 atm.
   Micrograms per hour.
 c  Inlet emission rate adjusted for the air flow bypassing the inlet location. Calculated by multiplying
   the inlet ug/hr by the ratio of the outlet flow rate to the inlet Sow rate.
()  Not Detected. Value shown is the detection limit and is included in totals.
{ } Estimated Maximum Possible Concentration. EMPC values we included in totals.
                                          2-11

-------
PCDFs" values. Values that have been qualified as being EMPC have been included in the sums.
Concentrations and emission rates based on or including EMPC values are denoted by braces
       Table 2.9 presents two PCDDs/PCDFs concentration-based measurements for both the
inlet and the outlet sampling locations.  In the second and third columns of the table, the in-stack
concentrations of the 2378-PCDDs/PCDFs congeners as well as the homologues (i.e., PCDDs
and PCDFs groups that have the same degree of chlorination) are presented adjusted to 7% O2.
The fifth and sixth columns of the table present the 2378 TCDD toxic equivalent ^ifcBS far those
congeners chlorinated at the 2, 3, 7, and 8 positions.  These columns represent the in-stack
concentrations of the 2378 congeners after being adjusted for toxicity relative to 2378-TCDDs.
PCDDs/PCDFs congeners that are not chlorinated at the 2, 3, 7, and 8 positions have a relative
toxicity of zero and therefore the total homologues (e.g., Total TCDD) are not presented in the
Toxic Equivalency columns.

2.2.2   CEM Measurements

       Measurements were conducted at the scrubber inlet and the outlet to determine the
concentrations of 02, CO2, THC, and HC1. These measurements were conducted using CEMs.
The CEMs were housed in a trailer supplied by APCC. Table 2. 10 presents the average THC and
HC1 concentrations and mass emission rates.  Inlet emission rates are presented twice - an
emission rate based on using the "as measured" inlet air flow rate and an emission rate based on
using the outlet flow rate to represent the total inlet air flow.

       O2 and  CO2 concentrations have been corrected for observed calibration and bias errors
using Equation 6C-1, as required in Method 3 A, and HC1 concentrations have been corrected
using Equation 1  in Proposed Method 322. THC concentrations are presented uncorrected,  as
required in Method 25A; the uncorrected O2 and CO2, and HC1 concentrations are given in
Appendix A. 2. 3.

       The CEMs collected data from the inlet and the outlet locations on a time-sharing basis.
The system was switched from inlet to outlet and back again every thirty minutes. The first 10
minutes of data from each 30-minute period were excluded from the calculation of average
responses to allow for  system response time and stabilization.
                                         2-12

-------
                                     TABLE 2.9
     PCDDs/PCDFs CONCENTRATIONS AND 2378-TCDD TOXIC EQUIVALENT
             CONCENTRATIONS ADJUSTED TO 7 PERCENT OXYGEN
                    KILN NO. 2 SCRUBBER INLET AND OUTLET
                AUSTIN WHITE LIME COMPANY - AUSTIN, TEXAS

CONGENER

DIOXINS:
2378 TCDD
Total TCDD
12378 PeCDD
Total PeCDD
123478 HxCDD
123678 HxCDD
123789 HxCDD
Total HxCDD
1 234678 HpCDD
Total HpCDD
12346789 OCDD
Total PCDDs
FURANS:
2378 TCDF
Total TCDF
12378 PeCDF
23478 PeCDF
Total PeCDF
123478 HxCDF
123678 HxCDF
234678 HxCDF
123789 HxCDF
Total HxCDF
1234678 HpCDF
1234789 HpCDF
Total HpCDF
12346789 OCDF
Total PCDFs
Total PCDDs + PCDFs
CONCENTRATION •
(ng/dscm, adjusted to 7 percent OJ
M23-I-4

{0.00101}
0.00441
{0.000176}
{0.00106}
(0.000309)
{0.000335}
{0.000988}
0.00582
0.00300
0.00494
0.00847
{0.0247}

0.0102
0.107
{0.00291}
{0.00314}
0.0192
{0.00180}
{0.000706}
{0.000335}
(0.000221)
0.00318
0.00207
(0.000397)
0.00212
{0.00109}
{0.132}
{0.157}
M23-O-4

0.000523
0.00406
{0.000258}
0.000805
(0.000362)
{0.000531}
{0.000515}
0.00354
0.00322
0.00692
0.00877
0.0241

0.01211
0.1193
0.00310
0.00298
0.0238
0.00129
0.000644
{0.000354}
(0.000161)
0.00435
0.00225
(0.000282)
0.00225
0.00209
0.152
0.176
2378-TCDD *
Toxicity
Equivalency Factor

1.000

0.500

0.100
0.100
0.100

0.010

0.001
Total PCDDs TEQ

0.100

0.050
0.500

0.100
0.100
0.100
0.100

0.010
0.010

0.001
Total PCDFs TEQ
Total TEQ
2378 TOXIC EQUIVALENCIES
(ng/dscm, adjusted to 7 percent O})
M23-I-4

{0.00101}

{0.0000882}

(0.0000309)
{0.0000335}
{0.0000988}

0.0000300

0.00000847
(0.00130)

0.00102

{0.000146}
{0.00157}

{0.000180}
{0.0000706}
{0.0000335}
(0.0000221)

0.0000207
(0.00000397)

{0.00000109}
(0.00307)
(0.00437)
M23-O-4

0.000523

{0.000129}

(0.0000362)
{0.0000531}
{0.0000515}

0.0000322

0.00000877
(0.000834)

0.00121

0.000155
0.00149

0.000129
0.0000644
{0.0000354}
(0.0000161)

0.0000225
(0.00000282)

0.00000209
(0.00313)
(0.00396)
•  Nanogram per dry standard cubic meter at 20"C and 1 atm and corrected to 7 percent oxygen.
"  North Atlantic Treaty Organization, Committee on the Challenges of Modern Society. Pilot study on Information
  Exchange on Dioxins and Related Compounds: International Toxicity Equivalency Factor (I-TEF) Methods of Risk
  Assessment for Complex Mixtures of Dioxins and Related Compounds. Report No. 176, August 1988.
() Not Detected. Value shown is the detection limit and is included in totals.
{  } Estimated Maximum Possible Concentration. EMPC values are included in totals.
                                       2-13

-------
                           TABLE 2.10

      HCL AND THC CONCENTRATIONS AND EMISSION RATES
             KILN NO. 2 SCRUBBER INLET AND STACK
         AUSTIN WHITE LIME COMPANY - AUSTIN, TEXAS
Run No.
Date
Sampling Location
Total Sampling Time, minutes
O2 Concentration, % by Volume
CO2 Concentration, % by Volume
Moisture, % by Volume
Volumetric Flow Rate, dscftn a
HC1:
Formula Weight, Ib/lb-mole
Concentration, ppmvw b
Concentration, ppmvd c
Concentration, ppmvd @ 7%O2 d
Emission Rate, Ib/hr '
As Measured
Using Outlet Air Flow Rate
THCs (as propane):
Formula Weight, Mb-mole
Concentration, ppmvw b
Concentration, ppmvd c
Concentration, ppmvd @ 7%O2 d
Emission Rate, Ib/hr e
As Measured
Using Outlet Air Flow Rate
M322-I-4
7/1/98
Inlet
60
10.5
16.2
12.8
11,200

36.47
3.0
3.44
4.60

0.219
0.525

44.11
0.0
0.0
0.0

0.0

M322-O-4
• -?/!/§•
Outlet
60
10.1
16.3
18.2
26,900

36.47
1.5
1.83
2.36

0.280
-

44.11
0.0
0.0
0.0

0.0
-
*   Dry standard cubic feet per minute at 68* F (20° C) and 1 atm.
b   Parts per million by volume wet.
"   Parts per million by volume dry.
d   Parts per million by volume dry basis corrected to 7% oxygen.
e   Pounds per hour.
                               2-14

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                            3.0 PROCESS DESCRIPTION
       The process description is considered confidential business information (CBI) and is not
discussed in this report.  During the testing, however, an BSD contractor, Research Triangle
Institute, monitored and recorded process operational data which will be supplied to EPA EMC
under a separate EPA contract.
                                         3-1

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                            4.0 SAMPLING LOCATIONS
       Source sampling was conducted to determine uncontrolled and controlled emissions of
HC1, PCDDs/PCDFs, and THCs from two rotary kilns located at Austin White Lime Company's
Austin, Texas facility. Testing was performed at the inlet of the baghouse and at two of the eight
stacks exhausting the eight modules used to control the particulate emissions from Kim No. 3; the
inlet and outlet of the scrubber used on Kiln No. 2 were also tested. Figures 4.1 and 4.2 present
simplified process air flow schematics depicting the sampling locations at Kiln No. 3 and Kim
No. 2, respectively. Descriptions of the sampling locations are presented in the following text;
additional figures showing details of the sampling locations are also presented.
4.1    KILN NO. 3

4.1.1   Baghouse Inlet Sampling Location

       The baghouse inlet was a rectangular duct 33.25 inches deep and 102 inches wide,
connecting the multiclones to the fan at the baghouse inlet.  As shown in Figure 4.3, six access
ports are located 475  inches downstream (9.5 diameters using an equivalent diameter of 50.2
inches as calculated using Method 1) from a bend and 123 inches upstream (2.5 equivalent
diameters) from the duct expansion leading to the fan.  Two of the ports were used for the CEMs
sample extractions and one port was seized shut. Attempts were made by plant personnel to
remove the port cap, but these attempts were halted because it was feared that the walls of the
duct would be torn. With approval from the WAM, PES used the remaining three available ports
for isokinetic testing.  Six traverse points on  each of the three axes were used, which was more
than the minimum number of points (12) required by Method 1. Figure 4.3 also shows the sample
points within the duct that were used for the isokinetic testing.

       A check for the presence of non-parallel or cyclonic flow, as outlined in Section 2.4 of
EPA Method 1, was performed prior to testing. The results of the cyclonic flow test indicated an
average yaw angle (a), of 10.8°. Since the average yaw angle was less than 20°, which is the
maximum allowed by Method 1, the location was considered suitable for isokinetic sampling and
required no adjustment to the alignment of the nozzle direction.

4.1.2   Baghouse Stacks Sampling Locations

       Sampling was conducted at two of the eight baghouse module exhaust stacks - North 3
and South 2. Isokinetic sampling was performed at the North 3 stack while the CEMs samples
were extracted from the South 2 stack. Additional velocity traverses were also performed on all
                                          4-1

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 PCDDs/PCDFs
 Stack Sampling
   Location
                     BAGHOUSE MODULES
                                              CEMs Sampling
                                                 Locations
                          Multiclones
                           Preheater
                          Rotary Kiln
                             No. 3
 PCDDs/PCDFs
 Inlet Sampling
   Location
Figure 4.1 Kiln No. 3 Process Exhaust Gas Schematic, Austin White Lime Company
        Austin, Texas
                              4-2

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                  Atmosphere
      Rotary Kiln
         No. 1
        System
  Scrubber Inlet
Sampling Location
      Rotary Kiln
         No. 2
                       t
                     Stack
                                   Fan
                                                Scrubber Outlet
                                               Sampling Location
                                Scrubber
                            Fan
Cyclone
                          Preheater
  Dust
Chamber
 Figure 4.2 Kiln No. 2 Process Exhaust Gas Schematic, Austin White Lime Company
         Austin, Texas
                              4-3

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          Traverse    Distance
            Point     From Inside
          Number    Wall (in.)
1
2
3
4
5
6
23/4
8 1/4
133/4
191/4
243/4
301/4
            Cross Sectional View


i
33.25"
\


k
r



102'








                      u   u
    CEMs
Sampling Ports
               Seized Closed
                                                            From
                                                         Multiclones
                                                        o o  o
                                                                     475"
                                                                      123"
PCDDs/PCDFs
Sampling Ports
                                                      To Fan
    Figure 4.3 Kiln No. 3 Baghouse Inlet Sample Ports and Sample Point Locations,
             Austin White Lime Company - Austin, Texas
                                    4-4

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but the North 3 stack to determine the volumetric air flow rate at each stack. Figure 4.4 shows
the general stack and access hole arrangements, along with the North 3 stack dimensional
information.

       The North 3 stack was a 37-inch inside diameter (ID) round stack exhausting directly to
the atmosphere from one of the eight baghouse modules. Except for the location of the access
holes, the eight stacks are essentially identical, including being slightly elliptical in shape. The
average stack diameter was 37 inches as shown in Figure 4.4. Two access holes were located 70
inches (1.9 equivalent duct diameters) downstream from the top of the baghouse and 27.5 inches
(0.75 equivalent duct diameters) upstream from the top of the stack exhausting to the atmosphere.
Twelve traverse points on each of the two axes were used, as required by Method 1. Figure 4.4
shows the sample points within the stack that were used for the isokinetic testing and for the
velocity traverses performed on the other seven stacks.

       A check for the presence of non-parallel or cyclonic flow, as outlined in Section 2.4 of
EPA Method 1, was performed prior to testing.  The results of the cyclonic flow test indicated an
average yaw angle (a), of 2.5°. Since the average yaw  angle was less than 20°, which is the
maximum allowed by Method 1, the location was considered suitable for isokinetic sampling and
required no adjustment to the alignment of the nozzle direction.
4.2    KILN NO. 2

4.2.1   Scrubber Inlet Sampling Location

       The scrubber inlet was a 35.75-inch ID round duct connecting the cyclone to the fan
before joining with the duct from the dust chamber and entering the scrubber. As shown in Figure
4.5, two access ports were located 400 inches (11.2 equivalent duct diameters) downstream from
a bend and 40.5 inches (1.1 equivalent duct diameters) upstream from the duct expansion leading
to the fan. Twelve traverse points on each of the two axes were used as specified by Method 1.
Two other ports at the same location were used for the CEMs sampling. Figure 4.5 also shows
the sample points within the duct that were used for the isokinetic testing.

       A check for the presence of non-parallel or cyclonic flow, as outlined in Section 2.4 of
EPA Method 1, was performed prior to testing.  The results of the cyclonic flow test indicated an
average yaw angle (a), of 11.6 *. Since the average yaw angle was less than 20°, which is the
maximum allowed by Method 1, the location was considered suitable for isokinetic sampling and
required no adjustment to the alignment of the nozzle direction.

4.2.2   Scrubber Outlet Sampling Location

       The scrubber outlet was a 53.25-inch ID round duct connecting the cyclone to the fan
before joining with the duct exhausting the Kiln No. 1 process. As shown in Figure 4.6, two
access ports were located 180 inches (3.4 equivalent duct diameters) downstream from a bend
and 198 inches (3.7 equivalent duct diameters) upstream from the duct expansion leading to the
                                          4-5

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Traverse  Distance From Inside Wall
  Point            (inches)
Number  West Port      South Port
                                              Cross Sectional View
1
2
3
4
5
6
7
8
9
10
11
12
3/4
23/8
41/4
63/8
9
127/8
23 1/4
271/8
297/8
32
33 7/8
35 1/2
3/4
21/2
41/2
65/8
93/8
13 3/8
24 1/4
28 1/4
31
33 1/4
351/4
37
  W
        PCDDs/PCDFs Stack
                  N
       CEMs Stack
                                                                      37.75'
                                                       36.25"
                                                                       27.5"
                                                                       70"
                                                    From Baghouse
                                                    Module North 3
        Note: There are eight separate baghouse modules and stacks. All are
              basically the same and have the same measurements.
Figure 4.4 Kiln No. 3 Baghouse Typical Stack Sample Ports and Sample Point Locations,
          Austin White Lime Company - Austin, Texas
                                     4-6

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  Traverse    Distance
    Point    From Inside
  Number   Wall (in.)
1
2
3
4
5
6
7
8
9
10
11
12
1
23/8
4 1/4
63/8
9
123/4
23
267/8
293/8
31 1/2
333/8
343/4
    Cross Sectional View
          35.75"
                                        400'
                                         40.5"
                                                    o     o
Figure 4.5 Kiln No. 2 Scrubber Inlet Sample Ports and Sample Point Locations,
         Austin White Lime Company - Austin, Texas
                               4-7

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   Traverse   Distance
     Point    From Inside
   Number   Wall (in.)
1
2
3
4
5
6
7
8
9
10
11
12
1 1/8
3 5/8
6 1/4
93/8
13 3/8
19
34 1/4
40
437/8
47
495/8
52 1/8
            Cross Sectional View
                   53.25"
                                                     To Fan

                                                                   180"
                                                                    198"
Figure 4.6  Kiln No. 2 Scrubber Outlet Sample Ports and Sample Point Locations,
          Austin White Lime Company - Austin, Texas
                                 4-8

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fan. Twelve traverse points on each of the two axes were used as required by Method 1. Two
other ports at the same location were used for the CEMs sampling. Figure 4.6 also shows the
sample points within the duct that were used for the isokinetic testing.

       A check for the presence of non-parallel or cyclonic flow, as outlined in Section 2.4 of
EPA Method 1, was performed prior to testing. The results of the cyclonic flow test indicated an
average yaw angle (a), of 12.2°.  Since the average yaw angle was less than 20", which is the
maximum allowed by Method 1, the location was considered suitable for isokinetic sampling and
required no adjustment to the alignment of the nozzle direction.
                                          4-9

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                  5.0 SAMPLING AND ANALYSIS PROCEDURES
       Source sampling was performed at the inlets and outlets to the baghouse on Kiln No. 3
and the scrubber on Kiln No. 2 to determine the concentrations and mass emission rates of
PCDDs/PCDFs, THC, and HC1. One test run was performed at each location, with each
PCDDs/PCDFs run having a net sampling time of 180 minutes and the THC and HC1 runs having
net sampling times of 60 minutes. The sampling and analytical methods that were used are
summarized in Table 5.1.  In Table 5.2, the parameters measured, the sampling method, the
number of tests performed, and the duration of each test are summarized. Brief descriptions of
the sampling and analysis procedures used are presented below. Copies of all the methods that
were used are presented in Appendix G.
5.1   LOCATION OF MEASUREMENT SITES AND SAMPLE/VELOCITY
      TRAVERSE POINTS

      EPA Method 1, "Sample and Velocity Traverses for Stationary Sources," was used to
establish velocity and sample traverse point locations. The process ductwork, and the locations of
measurement sites and traverse points, are discussed in Section 4.0 of this document.
5.2   DETERMINATION OF EXHAUST GAS VOLUMETRIC FLOW RATE

      EPA Method 2, "Determination of Stack Gas Velocity and Volumetric Flow Rate (Type S
Pilot Tube)," was used (in conjunction with EPA Method 23 at the isokinetic sampling locations)
to determine exhaust gas velocity.  A Type S Pitot tube, constructed according to Method 2
criteria and having an assigned coefficient of 0.84, was connected to an inclined-vertical
manometer. The pitot tube was inserted into the duct and the velocity pressure (Ap) was
recorded at each traverse point. The effluent gas temperature was also recorded at each traverse
point using a Type K thermocouple.  The average exhaust gas velocity was calculated from the
average square roots of the velocity pressure, average exhaust gas temperature, exhaust gas
molecular weight, and absolute stack pressure. The volumetric flow rate is the product of
velocity and the stack cross-sectional area of the duct at the sampling location.
5.3   DETERMINATION OF EXHAUST GAS MOISTURE CONTENT

      EPA Method 4, "Determination of Moisture Content in Stack Gases," was used to
determine the exhaust gas moisture content. EPA Method 4 was performed in conjunction with
                                        5-1

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                               TABLE 5.1

          SUMMARY OF SAMPLING AND ANALYSIS METHODS,
            AUSTIN WHITE LIME COMPANY - AUSTIN, TEXAS
    Sampling Method
   Parameter or Target
  Measurement Principle
EPA Methodl


EPA Method 2


EPA Method 3 A


EPA Method 4


EPA Method 23 (Proposed
Revisions)


EPA Method 25A


EPA Proposed Method 322
Traverse Point Locations
Velocity and Flow Rate
CO, and 0, Content
Moisture Content
PCDDs/PCDFs
THC
HC1
Linear Measv
Differential Pressure,
Thermocouple

Micro-Fuel Cell, FINOR


Gravimetric


Gas Chromatography / Mass
Spectrometry (GC/MS)


Flame lonization Detector

Gas Filter Correlation /
Infrared (GFC/IR)
                                   5-2

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                     TABLE 5.2
  SUMMARY OF SAMPLING LOCATIONS, TEST PARAMETERS,
SAMPLING METHODS, AND NUMBER AND DURATION OF TESTS,
     AUSTIN WHITE LIME COMPANY - AUSTIN, TEXAS
Sampling
Location
Kiln No. 3
Baghouse Inlet
&
Kiln No. 2
Scrubber Inlet &
Outlet


Kiln No. 3
Baghouse North 3
Stack

Kiln No. 3
Baghouse South 2
Stack

Kiln No. 3
Baghouse Stacks
South 1, 2, 3, & 4
& North 1,2, &4
Test Parameter
Exhaust Gas Flow
Rate
CO2 & 02 Content
Moisture Content
PCDDs/PCDFs
THC
HC1
Exhaust Gas Flow
Rate
Moisture Content
PCDDs/PCDFs
C02 & O2 Content
THC
HC1
Exhaust Gas Flow
Rate
Sampling Methods
EPA Method 2
EPA Method 3A
EPA Method 4
EPA Method 23
(Proposed Revisions)
EPA Method 25A
EPA Proposed Method
322
EPA Method 2
EPA Method 4
EPA Method 23
(Proposed Revisions)
EPA Method 3A
EPA Method 25A
EPA Proposed Method
322
EPA Method 2
Number
of Tests
1
1
1
1
1
1
1
1
1
1
1
1
1
Duration,
(minutes)
180
60
180
180
60
60
180
180
180
60
60
60
na
                        5-3

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each EPA Method 23 test run.  Integrated, multi-point, isokinetic sampling was performed.
Condensed moisture was determined by recording pre-test and post-test weights of the impingers,
XAD* sorbent module, and silica gel.
5.4    DETERMINATION OF PCDDs/PCDFs

       EPA Method 23, "Determination of Polychlorinated Dibenzo-P-Dioxins and
Polychlorinated Dibenzofurans from Stationary Sources," was used to collect dkaaai and furans
at each location. The proposed rules amending Method 23 as published in the Federal Register,
Volume 60, No. 104, May 31, 1995, correct existing errors in the method, eliminate the
methylene chloride rinse, and clarify the quality assurance requirements of the method.  A multi-
point integrated sample was extracted isokinetically from the traverse points shown hi Section
4.0. At the Kiln No. 3 baghouse inlet location, the 18 traverse points were each sampled for 10
minutes for a total run time of 180 minutes.  Sampling at each of the other three isokinetic
sampling locations (Kiln No. 3 baghouse stack, Kiln No. 2 scrubber inlet and outlet) was
performed for 7.5 minutes on each of 24 traverse points for total run times of 180 minutes per
test.

       The EPA Method 23 samples were extracted through a glass nozzle, a heated glass-lined
probe, a precleaned and heated glass fiber filter, a water-cooled condenser coil, and a sorbent trap
containing approximately 40 g of XAD*-2 sorbent resin. The EPA Method 23 sampling train is
shown in Figure 5.1.

       The samples were extracted and analyzed according to EPA Method 23 and the above
mentioned proposed rules amendment.  The sample components (filter, XAD®, and rinses) were
Soxblet extracted and combined.  The sample was then split with half being archived and the other
half analyzed. For the inlet sample analysis, an additional separate "loose" paniculate fraction
was also Soxhlet extracted and analyzed; the results of the two inlet analyses were added to get a
single inlet catch weight.  Refer to Appendix B for a tabulation of the inlet sample catches.
Analysis was performed on a high resolution Gas Chromatograph with a high resolution Mass
Spectrometer (GC/MS) detector.
5.5    DETERMINATION OF HYDROGEN CHLORIDE

       EPA Proposed Method 322, "Measurement of Hydrogen Chloride Emissions from
Portland Cement Kilns by GFC/IR," was used to monitor HC1 emissions at each location. Stack
gas samples were extracted from each duct or stack and transported through a heated sample
probe, sample conditioning system, heated sample line, and a heated sample pump into the
analyzer containing the gas filter correlation infrared spectrometer (GFC/IR). Sampling
components were maintained at a minimum temperature of 375 °F. A heated three-way valve was
attached to the probe assembly to allow for sampling of stack gas or for the introduction of HC1
calibration standards.
                                         5-4

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tn
                                    Temperature
                                       Sensor
                                                              Condenser
         Button Hook
           Nozzle
              Types
            Pitot Tube
        Gas
        Exit
                        Stack
                         Wall
                                                                                              Temperature
                                                                                                 Sensor
                                                                      Adsorbent Resin Trap
                                               11  --.---, -1

                                               (I1 Ice   Ml
                                               I  I \\f\5   I .
                                              ||llwater||l|

                                               I     ^

                                              [1'J
 Inclined
Manometer
                                        Temperature
                                          Sensors
                                     Empty 100 ml HPLC Water Empty  Silica Gel
                           Orifice
-L	L
                                                                          Vacuum
                                                                           Line
                    Inclined
                   Manometer
                                                               Vacuum
                                                                Pump
                            Figure 5.1 Sampling Train Schematic for EPA Method 23, Proposed Revisions.

-------
      HC1 in the sample cell attenuates an infrared light source. The intensity of the attenuated
beam is measured by a detector positioned at the end of the cell.  The amount of HC1 in the
sample gas stream is related to the amount of light attenuated. A schematic of this system is
presented in Figure 5.2.
5.6    DETERMINATION OF CARBON DIOXIDE, OXYGEN, AND
       TOTAL HYDROCARBONS
                                                                   >   •
                                                                        •i
       Continuous emission monitoring was performed at the Kiln No.3 baghouse onfct and stack
(South 2) and the Kiln No. 2 scrubber inlet and outlet. All CEM data were recorded using a
TracerAVestronics 3000 automatic digital data logger. The CEMs were housed in the APCC
Environmental Monitoring Laboratory positioned near the sampling locations. Stack gas was
drawn from the stack through a heated Teflon* sample line which is maintained at a temperature
of approximately 375°F. A portion of the extracted sample was conditioned to remove moisture
and directed to the O2 and CO2 analyzers to determine diluent concentrations on a dry basis.  The
remaining portion of the stack gas sample was directed to the THC analyzer.  Figure 5.3 shows a
schematic of the sampling system.

5.6.1   Carbon Dioxide and Oxygen

       EPA Method 3 A, "Determination of Oxygen and Carbon Dioxide Concentrations in
Emissions from Stationary Sources," was used to determine the O2 and  CO2 concentrations at the
inlet and outlet test locations.

       A Teledyne Analytical Instruments Model 326 O2 analyzer was  utilized to measure the
percentage concentration of O2 in the gas stream. The analyzer utilizes  a unique micro-fuel cell to
measure the concentration of O2. The output signal is linear over the specified ranges of analysis.

       A Westinghouse/Maihak FINOR CO2 analyzer was used to monitor CO2 concentrations.
The measurement principle for C02 is IR absorption. Radiation absorbed by CO2 in the sample
cell produces a capacitance change in the detector which is proportional to the CO2 concentration.

5.6.2   Total Hydrocarbons

       EPA Method 25 A, "Determination of Total Gaseous Organic Concentration Using a
Flame lonization Analyzer," was used to determine the THC concentrations at both test locations.
A VIG Industries THC analyzer (or equivalent), which utilizes a flame ionization detector (FID)
to measure THC, was calibrated with propane. Approximately 5.0 liters per minute (1pm) of
sample gas is drawn from the source through a heated Teflon* sample line. The sample gas is
drawn through a heated filter and valves by a heated pump. The sample gas is introduced into the
FID chamber and THCs in the sample are ionized by a hydrogen flame.  The flame is positioned
between two charged plates, and the associated electric field induces the migration of the ions
towards the charged plates. The ion migration results in the generation of a current, which is
directly proportional to the amount of THCs present in the sample.
                                         5-6

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Figure 5.2 Sampling Train Schematic for EPA Proposed Method 322.
                            5-7

-------
00
                                Stack
                                Wall
                                          Heated Filter
                                                                               Sample By-Pass
                                                                                   Vent
                                      Figure 5.3 Sampling Train Schematic for EPA Methods 3A and ISA.

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5.7    CEMs DATA ACQUISITION AND HANDLING

       Analyzer responses were recorded by a Tracor/Westronics 3000 digital data logger which
recorded the O2, CO2, HC1 and THC concentrations using its integral color printer.  Trends were
monitored using the strip chart mode with averages printed digitally at 20-minute intervals and at
the conclusion of the test period. Analyzer responses were recorded by the data logger at five
second intervals.
                                        5-9

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             6.0  QUALITY ASSURANCE/QUALITY CONTROL (QA/QQ
                           PROCEDURES AND RESULTS
      For any environmental measurement, a degree of uncertainty ^exists in the data generated
due to the inherent limitations of the measurement system employed.  The goals of a QA/QC
program are to ensure, to the highest degree possible, the accuracy of the data collected. This
section summarizes the QA/QC procedures that were employed by PES hi the performance of this
test program.  The procedures contained in the reference test methods and in the "Quality
Assurance Handbook for Air Pollution Measurement Systems, Volume III, Stationary Source
Specific Methods," EPA/600/R-94/038c, served as the basis for performance for all testing and
related work activities in this project.
6.1    CALIBRATION AND PREPARATION OF APPARATUS

       The preparation and calibration of source sampling equipment is essential in maintaining
data quality.  Brief descriptions of the calibration procedures used by PES are presented below.
The results of equipment and sensor calibrations may be found in Appendix E. Detailed
procedures as presented in the EPA test methods are presented in Appendix G.

6.1.1   Barometers

       PES used aneroid barometers which were calibrated against a barometric pressure value
reported by a nearby National Weather Service station.

6.1.2   Temperature Sensors

       Bimetallic dial thermometers and Type K thermocouples were calibrated using the
procedure described in Calibration Procedure 2e of EPA/600/R-94/038c.  Each temperature
sensor was calibrated over the expected range of use against an ASTM 3C or 3F thermometer.
Table 6.1 summarizes the type of calibrations performed, the acceptable levels of variance,  and
the results. Digital thermocouple displays were calibrated using a thermocouple simulator having
arangeofO-2400°F.

6.1.3   Pitot Tubes

       PES  used Type S pilot tubes constructed according to EPA Method 2 specifications.
Each pilot tube was inspected for conformance to the geometric specifications by the application
of Calibration Procedure 2 of EPA/600/R-94/038c. Pitot tubes that meet these requirements are
                                         6-1

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                   TABLE 6.1
SUMMARY OF TEMPERATURE SENSOR CALIBRATION DATA
Temp.
Sensor
I.D.
4A



4F



T5A



MB- 10






RMB-15






Usage
Stack Gas



Stack Gas



Stack Gas



Meter Box
Inlet


Outlet


Meter Box
Inlet


Outlet


Temperature, °R
Reference
534
503
664
792
536
498
664
801
532
504
664
860

493
536
666
492
536
666

493
534
668
493
534
668
Sensor
534
503
665
793
536
498
664
802
532
504
664
860

494
536
• 665
494
537
665

495
534
670
493
535
668
Temperature
Difference*.*
0.0%
0.0%
0.15%
0.13%
0.0%
0.0%
0.0%
0.12%
0.0%
0.0%
0.0%
0.0%

0.20%
0.0%
-0.15%
0.40%
0.19%
-0.15%

0.40%
0.0%
0.30%
0.00%
0.19%
0.00%
: Tolerance
<±1.5%
<±1.5%
<±1.5%
<±1.5%
<±1.5%
<±1.5%
<±1.5%
<±1.5%
<±1.5%
<±1.5%
<±1.5%
<±1.5%

<±1.5%
<±1.5%
<±1.5%
<±1.5%
<±1.5%
<±1.5%

<±1.5%
<±1.5%
<±1.5%
<±1.5%
<±1.5%

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assigned a pilot coefficient, Cp , of 0.84. The dimensional criteria and results for each pitot tube
used are presented in Table 6.2.

6.1.4  Differential Pressure Gauges

       PES used Dwyer inclined/vertical manometers to measure differential pressures. The
differential pressure measurements included velocity pressure, static pressure, and meter orifice
pressure. Manometers were selected with sufficient sensitivity to accurately measure pressures
over the entire range of expected values. Manometers are primary standards and require no
calibration.

6.1.5  EPA Method 23 Dry Gas Meters and Orifices

       The EPA Method 23 dry gas meters and orifices were calibrated in accordance with
Sections 5.3.1  and 5.3.2 of EPA Method 5. This procedure involves direct comparison of the
metered volume passed through the dry gas meter to a reference dry test meter. The reference
dry test meter is calibrated annually using a wet test meter. Before its initial use in the field and
annually thereafter, the metering system is calibrated over the entire range of operation as
specified in EPA Method 5.  Acceptable tolerances for the individual dry gas meter correction
factor (y) and  orifice calibration factor (AH@) during initial or annual calibrations are ± 0.02 and
± 0.20 from the average, respectively. After field use, a calibration  check of the metering system
was performed at  a single intermediate setting based on the previous field test. The post-test
calibration check of the dry gas meter correction factor must agree within 5% of the correction
factor generated during the initial  or annual calibration. The results for the gas meters and orifices
used in this test program are summarized in Table 6.3.
6.2    REAGENTS AND GLASSWARE PREPARATION

       Sample reagents consisted of pesticide (or better) grade acetone and toluene for glassware
preparation and sample recoveries, and pesticide (or better) grade hexane for glassware
preparation. Sample filters and the XAD*-2 sorbent resin traps were prepared by PAL according
to the procedures outlined in Method 23. Water used in the impinger trains was HPLC-grade
reagent water.

       After preparation of the XAD*-2 sorbent resin traps by PAL, each trap was spiked with a
mixture of PCDDs/PCDFs surrogates, and capped with glass balls and sockets until used in the
field.

       Prior to the field testing portion of the program, all sampling train components and sample
recovery apparatus were prepared according to the following procedure.

       1.      Wash in hot soapy water (Alconox*).
       2.      Rinse three times with tap water.
       3.      Rinse three times with distilled/deionized water.
                                           6-3

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                      TABLE 6.2
       SUMMARY OF PITOT TUBE DIMENSIONAL DATA

Measurement

*i
a2
P.
P2
T
6
A
z
w
D,
(A/2)/D,

Criteria

<10°
<10°
<5°
<5°
-
-
-
£ 0.125"
<: 0.0313"
0.1875" < Dt < 0.375"
1.05 < (A/2)/Dt < 1.50
Acceptable
Assigned Coefficient
Results
Pitot Tube Identification
4A
1.1
0.8
0.5
0.3
0.8
0.7
0.967
0.014
0.012
0.375
1.29
Yes
0.84
4F
1
0
1
0
I
0
.94
.017
0
0.375
1.25
Yes
0.84
• I-5A
1
0.7
1.5
0.6
2.5
2.5
0.981
0.0
0.024
0.375
1.31
Yes
0.84
                      TABLE 6.3




SUMMARY OF DRY GAS METER AND ORIFICE CALIBRATION DATA
Meter
No.
MB-10
RMB-15
Dry Gas Meter Correction Factor, y
Pre-test
1.021
1.000
Post-test
1.020
0.995
% Diff.
-0.2
-0.5
EPA Criteria
±5%
±5%
Orifice Coefficient, AH@
Average
1.92
1.90
Range
1.73-2.44
1.86 - 1.92
EPA Criteria
1.72-2.12
1.70-2.10
                         6-4

-------
      4.     Rinse with pesticide-grade acetone.
      5.     Rinse with pesticide-grade toluene.
      6.     Rinse with pesticide-grade hexane.
      7.     Allow to air dry.
      8.     Cap all openings with hexane-rinsed aluminum foil.
6.3    ON-SITE SAMPLING

       The on-site QA/QC activities included:

6.3.1   Measurement Sites

       Prior to sampling, the stack and inlet duct were checked dimensionally to determine
measurement site locations, location of velocity and sample test ports, inside stack/duct
dimensions, and sample traverse point locations. Inside stack/duct dimensions were checked
through both traverse axes to confirm uniformity of the stack/duct inside diameter.  The inside
stack/duct dimensions, wall thickness, and sample port depths were measured to the nearest 1/16
inch

6.3.2   Velocity Measurements

       All velocity measurement apparatus were assembled, leveled, zeroed, and leak-checked
prior to use and at the end of each determination. The static pressure was determined at a single
point near the center of the stack or duct cross-section.

6.3.3   Moisture

       The Method 23 trains were used to determine stack gas moisture.  During sampling, the
exit gas of the last impinger was maintained below 68°F to ensure adequate condensation of the
exhaust gas water vapor. The total moisture was determined on-site gravimetrically using an
electronic platform balance with 0 1 gram sensitivity.  The amount of moisture collected by the
XAD* trap was also measured.

6.3.4   EPA Method 23

       The field sampling QA/QC for EPA Method 23 began in the sample recovery area. The
sample trains were set up and leak-checked to verify sample train integrity before transport to the
sampling sites. At the sampling sites, the sample trains were leak checked a second time. Leaks
found in excess of 0.02 cubic feet per minute (cfin) were corrected prior to beginning the test
runs.  Leak checks were also conducted before and after any sample train component changes,
between sample ports, and upon completion  of the test runs.  Sampling was conducted within the
isokinetic sampling criteria of 100 ± 10%.  Table 6.4 summarizes the EPA Method 23 field
sampling QA/QC measurements and EPA's acceptability criteria.
                                           6-5

-------
       In addition to the inlet and outlet samples, a field blank sample was collected at the Kiln
No. 3 baghouse stack and at the Kiln No. 2 scrubber inlet. A Method 23 sampling train was
assembled and transported to the sampling location, and leak-checked twice.  The sample train
was then recovered using the same procedures employed during the recovery of the sample trains
used during actual sample runs. The collected fractions were transferred to labeled, pre-cleaned
sample bottles, transported to the subcontract laboratory, and analyzed in the same manner as the
collected samples.
                                                                   ;* " ' •    *i,"
       PES also collected samples of the reagents that were used during the program as blanks.
Samples were collected of the acetone and toluene; an unused filter and XAD*-2 scrbent nodule
were also collected.  These reagent blank samples were transported to the subcontract laboratory
and analyzed for PCDDs/PCDFs using the same procedures as during the analysis of the collected
samples.

6.3.5   Continuous Emission Monitors

       CEMs were used to quantify the in-stack concentrations of O2, CO2, THC, and HC1 using
EPA Methods 3 A, 25A and Proposed Method 322, respectively. QA/QC checks performed
included direct calibrations, bias checks, and drift checks; matrix spikes were also performed on
the Method 322 HC1 CEMs  sampling system.  Table 6.5 summarizes  the compressed gas
standards that were used during the test program.

6.3.5.1 EPA Method 3A

       Prior to the start of each day of testing, the O2 and CO2 analyzers were calibrated with a
zero gas standard and two upscale standards corresponding to approximately 55 and 85% of the
instrument measurement ranges.  The calibration error of the analyzers on direct calibration was
less than or equal to 2% of span. The  sampling line bias was then checked with the zero gas and
one upscale gas for each analyzer. The sampling line bias was less than or equal to 5% of the
response of the analyzer to the calibration standard when injected directly into the analyzer.  At
the conclusion of the sampling run, the sampling system was again checked by introducing the
zero and upscale standard into the system at the probe end.  The sampling system drift was less
than 3% of the instrument span for both the zero and upscale calibration gases. The true
concentration of the gases measured was then calculated from the average instrument response
and the results of the calibration responses using Equation 6C-1  as found in Method 6C, which is
the procedure specified in Method 3 A. The gases used for calibrations were certified by the
manufacturer, and prepared  according to the procedures in "EPA Traceability Protocol for Assay
and Certification of Gaseous Calibration Standards (September 1993)." Results of the above
mentioned QC checks are tabulated in Appendix E.

6.3.5.2 EPA Method  25A

        Prior to the start of each day of testing, the THC sampling system was calibrated with a
zero gas standard and three  upscale propane standards corresponding to approximately 25, 50,
                                           6-6

-------
                     TABLE 6.4
SUMMARY OF EPA METHOD 23 FIELD SAMPLING QA/QC DATA
Run No.
Site
Date
Pre-Test Leak Rate, acfin
Post-Test Leak Rate, acfin
EPA Criteria, acfin
Percent Isokinetic
EPA Criteria
M23-I-3
Kiln No. 3
Baghouse
Inlet
06/30/98
0.003 @ 15"
Hg
0.002 @ 15"
Hg
0.02
102.4
90-110%
M23-O-3
Kiln No. 3
Baghouse
Stack North 3
06/30/98
0.005 @ 15"
Hg
0.008 @ 12"
Hg
0.02
101.9
90-110%
M23-I-4
Kiln No. 2
Scrubber Inlet
07/01/98
0.001 @ 15"
Hg
0.003 @ 16"
Hg
0.02
103.3
90-110%
M23-O-4
Kiln No. 2
Scrubber
Outlet
07/01/98
0.004 @ 17"
Hg
0.004 @ 19"
Hg
0.02
99.5
90-110%
                     TABLE 6.5
       SUMMARY OF CALIBRATION GAS CYLINDERS
Cylinder Number
CC91137
1912728Y
CC91081
CC91047
AAL-13302
CC84329
CC84329
CC86922
CC86922
Contents
27. 1 ppm HC1 in nitrogen
48.8 ppm HC1 in nitrogen
8.09 ppm C3Hg in air
15.15 ppm C3Hginair
30.0 ppm C3Hg in air
11.03%C02inN2/O2/C02
11.04%O2inN2/O2/CO2
19.01%CO2inN2/O2/C02
19.17%02inN2/02/C02
Expiration Date
Certified on 6/1 2/98
Certified on 6/23/98
5/12/01
5/12/01
5/01/01
3/02/01
3/02/01
3/02/01
3/02/01
                        6-7

-------
and 85% of the instrument measurement range.  The calibration errors of the THC system were
less than 5% of the instrument operating range.  At the conclusion of the sampling run, the
sampling system was again checked by introducing the zero and one upscale standard into the
system at the probe.  The sampling system drift was less than 3% of the instrument span for both
the zero and upscale calibration gases. The THC results are reported as the average of the
instrument responses over the period of the sampling run.  The gases used for calibration were
certified by the manufacturer, and prepared according to the procedures in "EPA Traceability
Protocol for Assay and Certification of Gaseous Calibration Standards (September 1993)."
Results of the above mentioned QC checks are tabulated in Appendix E.   •'•'~  .
                                                                       *         i
6.3.5.3 Proposed Method 322

       Prior to the start of each day of testing, the HC1 analyzer was calibrated with a zero gas
standard and two upscale standards corresponding to approximately 25 and 85% of the
instrument measurement ranges.  The calibration error of the analyzers on direct calibration was
less than or equal to 5% of span or 1 ppm, whichever is greater.  The sampling line bias was then
checked with the zero gas and one upscale gas.  The sampling line bias was less than or equal to
7.5% (or 1.5 ppm, whichever was greater) of the response of the analyzer to the calibration
standard when injected directly into the analyzer.  Results of the above mentioned QC checks are
tabulated in Appendix E.

       Following the direct calibration and bias checks, a matrix spike for HC1 was conducted so
that the integrity of the sampling and analysis system for HC1 could be ascertained. The flue gas
was sampled to determine the baseline concentration of the HC1, and after the baseline
concentration was established, a known quantity of HC1 was injected into the sampling system.
The analyzer response must report the concentration of the HC1 in the effluent stream plus the
contribution of the HC1 from the matrix spike injection. The allowable tolerance for the matrix
spike is ± 30% from the predicted value. During the matrix spike procedures conducted on the
sampling system at Austin White Lime Company, the average matrix spikes were within the
± 30% tolerance; note that the post-test spike recovery on Kiln No. 2 was 136%. The results of
the matrix spikes are presented in Table 6.6 and Appendix E.
 6.4    LABORATORY ANALYSES

 6.4.1  Analysis of Blank Samples

       The EPA Method 23 blank samples were analyzed following the procedures of EPA
 Method 23. Field blanks and laboratory blanks were used to evaluate the effectiveness of the
 sample train clean-up procedures and to check for contamination of the reagent materials. In
 addition, the subcontract laboratory conducted the Laboratory Method Blank (LMB) to evaluate
 the presence of contamination of the samples during analysis.  The results of these blank analyses
 and the actual run sample catches are presented in Table 6.7.
                                           6-8

-------
6.4.2   Standards Recovery Efficiencies

       Prior to shipment of the XAD*-2 sorbent modules by PAL, each module was spiked with
a mixture of surrogate (sampling) standards.  The modules were then sent to Austin, Texas, via
Federal Express for use in the sampling program.  Upon analysis, the recoveries of the surrogate
standards provide a measure of the capture and holding efficiency of the XAD*-2 sorbent traps
for the sampled PCDDs/PCDFs. A low recovery efficiency may indicate the loss of
PCDDs/PCDEs congeners from the XAD*-2 sorbent module after its recovery from the sampling
train.  A special "cleanup" standard was added to the separate paniculate sample fraction of the
inlet Method 23 sample train sample (recovered separately due to the excessively large amount of
the paniculate).  The recovery efficiency of these  standards are presented in lieu of the non-
existent surrogate standard recoveries.  Table 6.8  presents the results of the surrogate and
"cleanup" standards recoveries.

       Upon receipt of the XAD®-2 sorbent modules by the laboratory after sampling, the
XAD®-2 sorbent resin modules are spiked with a mixture of internal (extraction) standards. The
purpose of these standards is to evaluate the efficiency of the extraction of the PCDDs/PCDFs
congeners from the sample fractions.  The results  of these recoveries are also presented in
Table 6.8.
                                     TABLE 6.6
             SUMMARY OF METHOD 322 HCL EV-SITU SPIKING DATA
Kiln
Rotary
Kiln No. 3


Rotary
Kiln No. 2

Test
Location
Baghouse
Inlet
Baghouse
Stack South
2
Scrubber
Inlet
Scrubber
Outlet
HC1 Spike Recovery Efficiencies, %
Pre-test
108
86

119
122
Post-test
124
100

105
136
Average
116
93

112
129
EPA
Criteria
70-130
70-130

70-130
70-130
                                         6-9

-------
                                                                    TABLE 6.7

                            SUMMARY OF EPA METHOD 23 BLANKS AND SAMPLE CATCHES


PAL Lab Report Page
Numbers in Appendix B.
Analyte
2378-TCDD
12378-PeCDD
123478-HxCDD
123678-HxCDD
123789-HxCDD
1234678-HpCDD
OCDD
2378-TCDF °
12378-PeCDF
23478-PeCDF
123478-HxCDF
123678-HxCDF
234678-HxCDF
123789-HxCDF
1234678-HpCDF
1234789-HpCDF
OCDF
Total TCDDs
Total PeCDDs
Total HxCDDs
Total HpCDDs
Total TCDFs
Total PeCDFs
Total HxCDFs
Total HpCDFs
Total PCDD/Fsd
Catch, ng Per Sample
PAL LMB
025


{0.00098}
(0.0004)
(0.0004)
(0.0003)
{0.00116}
0.0029
0.0141
0.0015
(0 0007)
(0.0007)
{0.00096}
0.0006
(0.0005)
(0.0006)
{0.00168}
(0.0010)
(0.0009)
{0.001}
(0.0004)
0.0012
0.0052
0.0016
(0.0007)
0.0008
{0.002}
0.0229
M23 RB-1 "
112"


0.0011
(0 0004)
(0.0006)
{0 00096}
0.0014
0.0031
0.0096
(0.0006)
(0.0004)
(0.0004)
0.0008
(0.0003)
(0 0003)
(0.0004)
00030
(0.0006)
0.0028
00011
(0.0004)
0.0024
0.0032
(0.0006)
(0.0004)
0.0008
0.0032
0.023
M23-FB-3
091


0.0010
{0 00072}
(0.0006)
0.0011
{0.00112}
0.0043
0.0136
0.0016
(0.0004)
(0.0004)
0.0013
{0.0008}
{0.00068}
(0.0004)
00061
(0,0008)
{0.00468}
0.0022
0.0012
0.0040
0.0084
0.0024
0.0024
0.0028
0.0060
0.0429
M23-I-3 + FHb
OOOa/ 003/003 A
/ 043/179

{0.00309}
0.0006
(0.0008)
{0.00156}
{0.00296}
{0.00804}
0.0237
{0.00734}
0.0023
{0.00064}
{0 00340}
{0.00136}
(0.0004)
(0 0004)
0.0049
(0 0006)
00036
{0.0115}
0.0036
0.0088
0.0060
{0.0642}
{0.0110}
{0.0054}
0.0052
{0.143} b
M23-O-3
003 / 0067


0.0015
0.0006
(0.0004)
0.0014
{0.00196}
0.0045
0.0167
0.0054
0.0038
{0.0024}
0.0033
{0.00168}
{0.00116}
(0.0005)
0.0063
{0.00112}
00092
0.0119
0.0056
0.0076
0.0088
0.1428
0.0312
0.0104
0.0076
0.2518

M23-FB-4
161


{0.00065}
{0.00044}
(0.0006)
{0 00072}
{0.0012}
{0.00268}
{0.0076}
(0.0007)
(0.0004)
(0.0004)
{0.0008}
(0.0002)
(0.0003)
(0.0003)
0.0026
(0.0007)
{0.00148}
{0.0006}
{0.0012}
{0.006}
{0.0064}
(0.0007)
(0.0004)
{0.0012}
0.0028
0.0028

M23-I-4 + FH*
OOOb/ 003/003 A
/ 109/199

{0.00228}
{0.0004}
(0.0007)
{0.00076}
{0.00224}
0.0068
0.0192
0.0232
{0.0066}
{0.00712}
{0.00408}
{0.00160}
{0.00076}
, (0.0005)
0.0047
(0.0009)
{0.00248}
0.0100
{0.0024}
0.0132
0.0112
0.2416
0.0436
0.0072
0.0048
{•4557} »

M23-O-4
003 / 136


0.0013
{0.00064}
(0.0009)
{0.00132}
{0.00128}
0.0080
0.0218
0.0301
0.0077
0.0074
0.0032
0.0016
{0.00088}
(0.0004)
0.0056
(0.0007)
0.0052
0.0101
0.0020
0.0088
0.0172
0.2964
0.0592
0.0108
0.0056
0.4371
* Sample RB-1 collected at a different lime kiln facility tested during the same mobilization. The pages are inserted at the end of Appendix B, resulting in the imp Mmben being out of sequence.
b Result obtained by summing the two inlet sample fractions analyzed; EMPC "Total" values were used in calculating the "Total PCDD/Fs" value.
c Result obtained from the DB-225 analysis.
d Total PCDD/Fs represent the sum of all polychlorinated dibenzo-p-dioxins & dibenzofiirans.
( ) Denotes a non-detect value using the detection limit.
{} Denotes an EMPC value
                                                                        6-10

-------
                                                                 TABLE 6.8

                        SUMMARY OF EPA METHOD 23 STANDARDS RECOVERY EFFICIENCIES



FULL SCREEN ANALYSIS
PAL Report Page Number
Internal (Extraction) Standards
2378-TCDD
12378-PeCDD
123678-HxCDD
1234678-HpCDD
OCDD
2378-TCDF
12378-PeCDF
123678-HxCDF
1234678-HpCDF
Surrogate (Sampling) Standards
2378-TCDD
23478-PeCDF
123478-HxCDD
123478-HxCDF
1234789-HpCDF
Percent Recovery
PAL
LMB

026

88.8
966
90.7
90.6
829
71.0
58.3
59.5
46.6

92.5
89.8
97.3
90.3
95.8
M23-
1-3 j

044

65.8
64.2
67.7
72.2
66.6
59.3
57.3
62.0
65.1

98.2
97.0
103.9
103.5
100.8
M23-
1-3 FH

180

89.5
87.9
83.4
89.4
83.2
70.3
73.9
75.7
75.0

86.2 b
78.9 b
95.2 b
83. 8 b
89.3 b
M23-
O-3

068

89.4
96.2
81.1
80.7
65.5
81.9
88.0
73.5
75.1

97.7
94.4
106.3
101.0
96.3
M23-
FB-3

092

83.2
91.4
82.3
89.1
77.6
80.9
74.9
86.7
69.3

92.7
93.4
106.2
84.9
77.3
M23-
1-4

110

86.7
83.3
84.2
90.0
84.3
82.1
73.1
82.7
79.8

99.2
99.7
105.9
96.3
95.1
M23-
1-4 FH

200

74.6
70.8
75.0
77.4
69.4
68.3
58.8
64.8
60.9

89.1 •
81.3 "
97.1a
87.4 a
98.7 •
M23-
0-4

137

79.1
78.5
81.0
87.5
81.9
73.5'
67.2
81.3
72.3

100.0
100.4
108.0
91.3
93.6
M23-
FB-4

162

79.9
81.8
85.9
91.4
87.5
72.4
64.8
84.4
66.4

96.0
104.5
99.0
80.5
84.8
M23-
RB-1'

113'

86.4
94.1
87.4
92.3
83.6
87.7
81.5
91.8
73.7

96.4
98.2
110.1
88.2
81.6

QC
TJmitc
U11111U



40-130%
40-130%
40-130%
40-130%
40-130%
40-130%
25-130%
25-130%
25-130%

70-130%
70-130%
70-130%
70-130%
70-130%
The "M23-RB-1" sample was collected at a different lime kiln facility tested during the same mobilization. The pages are inserted at the end of Appendix B, resulting in the page numbers being out of
sequence.
The "Surrogate" recoveries presented for Samples "M23-I-3 FH" and "M23-I-4 FH" are actually recoveries for the "cleanup" standards which were only added to the separate inlet particulate samples.
                                                                    6-11

-------
6.5   QA COORDINATOR FIELD AUDIT

      To meet the goals of the Quality Control Program as described in the QAPP, PES supplied an
on site QA Coordinator to observe the emission testing and to audit the personnel, equipment,
procedures, and record keeping.

      Auditing and observations were conducted at regular intervals during the testing which
provided opportunity for any immediate corrective actions.  Checks and audits of tbc ampting, data
acquisition, sample recovery, and chain of custody for the samples were performed; copies of the
completed forms used for recording the results of the audits and checks are included in Appendix E,
"QA/QC Data."
                                           6-12

-------
  APPENDDCA




RAW FIELD DATA

-------
 Appendix A. 1




Raw Field Data




  Kiln No. 3

-------
       Appendix A. 1.1




  Raw Field Data, Kiln No. 3




Baghouse Inlet - PCDDs/PCDFs

-------
      TRAVERSE POINT LOCATION FOR RECTANGULAR DU£ia.
Plant;  /9
Date:	
Sampling Location:.
Duct Width, inches:.
Inside of Far Wall to Outside of Nipple:.
Inside of Near Wall to Outside of Nipple (Nipple Length):
Duct Length, inches:.
Equivalent Diameter =
                     3 "3
                   2xLxW/(L + W)
Distance Downstream from Flow Disturbance (Distance B):
         *V"?S   inches/Equivalent Diameter = 9.V
Distance Upstream from Flow Diisturbance (Distance A):
                 . inches / Equivalent Diameter
             • ~-*fc.
Calculated By:
                                                 dd
                                                 dd
  Schematic of
Sampling Location
Traverse
Point
Number
i
A
*
^
£
fn





Fraction
of
Length











Length
(inches)
33V
^V
^•^
I3*th
33£"
^





Product of
Columns 2 & 3*
(To nearest 1/8")
S>%"
Vfr"
/3H
x4?-^
J*'^"
30 V





Nipple
Length
(inches)
/*"
/*"
/ V
/V
/ ^
i^ ''
/ -^





Traverse Point
Location
(Sum of Col. 4 & 5)
V£"
to"
IS*"
41"
^^^^C^t"
3.2 "





             If No Ports, Calculate Distances From Stack Walls For Port Locations
Number
of
Ports








Fraction
of
Width








Width
(inches)








Port Location
Product of Col. 2 & 3*
(To Nearest 1/8")








        * All points or ports should be an equal distance from each other (D) and 1/2 of
        that distance from the stack walls (D/2), where D = Width / * of points or ports

-------
        Js.
   Duct Diameters Upstream From Row Disturbance* (Distance A)
  0.5            1.0            1.5           ZO           2.5
50
40
30
20
10
         T
                         T
      T
             24
                           20
                 16
Velocity (Non-Particulate)
                            16
         1
                   I
                                L _ 12
I
I
      T
       I
                 12
I
                                                                7

                                                                  I
                                                                  4
                                                                  I
                                                                 3!
                                                                DMurbanoM
   23      456789     10
   Duct Diameters Downstream From Row Disturbance* (Distance B)
   * From Point of Any Typ« of Disturbance (Band, Exp«n»ton, Contraction. «te)
           LOCATION OF TRAVERSE POINTS IN CIRCULAR DUCTS
         (Fraction of Stack Diameter from Inside Wall to Traverse Point)
Traverse
Point
Number
on a
Diameter
1
2
3
4
5
6
7
8
9
10
11
12

Number of Traverse Points on a Diameter

4
0.067
0.250
0.750
0.933








6
0.044
0.146
0.296
0.704
0.854
0.956


'



8
0.032
0.105
0.194
0.323
0.677
0.806
0.895
0.968




10
0.026
0.082
0.146
0.226
0.342
0.658
0.774
0.854
0.918
0.974


12
0.021
0.067
0.118
0.177
0.250
0.356
0.644
0.750
0,823
0.882
0.933
0.979

-------
GAS VELOCITY .CYCLONIC, AND VOLUMETRIC FLOW RATE

Plant:
/^o%ti^ ijJW^Vt L.'y^e_
Sample Location:
Run No.:
Pbar, in. Hg:
Moist, %:
K.'Uv** ft^W^v* rjjun
PreU^'^,. Tr.uVr^j/V-.., A^V.

-n+~- 5^,
Stack Dimension, in. Dia. 1 :
Wet Bulb. °F:
*sa
Jal
/0D
, r~
2£>
.22
£1
31
*{ t4^.

Traverse
Point
Number
i&k I
J
3
y
S
t
J. i
j
3
^
S
&>
B> i
o
S
-V
s
r?
(• i
o
?
<,
5
^

Velocity
Head, in.
H20
rgS .

T .71 •
-j
^r , ti t
"»*•
' 1
_,
f \O
f f


. &>£,
• 65?
. &<7
, fcS
. (?l

& Cs '
-. g-^ •>
^
. te 3. '
f *\

* \j i>







Stack
Temp.. °F
^50
•^50
-V5V
^60
Ll(c\
tyCot
«V50
^50
^56
V&V
*f& (a
*/(o~?

^6C.
£SQf ^}
4/f f








33^ _ /o-i
_

Cyclonic
Flow Angle,
-8s-
^
-/j
._^
~ xo
- /s
- S"
t -5
- /£
- /£-
- /?
- / '
-/§>
_ / -^
- to
- 'S'
- "?
-g-
- /s
-/s
- s
-/s
-'6
- ^

sq.rt. dp Stack Temp Angle, °
Director!
of Angle
•f-
-f
—
—
• —
—
—
4
—
—
—
—


—
—
•—
_
—








Average) /o.g
                                    Date:
                                    Clock Time:
                                    Operators:
                                    Static Pressure, in. H,O:
                                    Pilot Tube. Cp:   	.
                                    Dia. 2:          	-
                                    Dry Bulb. "F:     	
                                                Md - (0.44 x %CX3j) -i- (0.32 x %O2) + (0.28 x %h^)
                                                        
  xao

%^o
  100
                                                               X 17.647 X-
                                                                                         100
                                                QHW-

-------
• Utfltr  /^IS&Tf-rt. £**)£» * "TCZ- £ /*** <
Sampling Location  K. y. /Jb. 3
Run Number: **°ViS3 < Date:	
Pretest Leak Rate:   i'*=>    clrn @.<£\ in. Hg.
Pretest Leak Check: Pilot: _k/Orsal:  ^| A
                                        FIELD DATA SHEET
                                                 1->-s   Operator:	
                    Sample Type:
                    Pbar:_J^S
                    CO2:    ^«
                                                  Ps:
                                                  O2:
                                   Probe Length/Type:
                                   Stack Diameter:
                                                  .S-S
                                                                                 Nozzle ID:     ^^Thermocouple #:
                                                                                 Assumed Bws:  /Q Filter #:
                                                                                 Meter Bon #: ,*a to Y: (,**•(
                                                                                 Post-Test Leak Rate: . eQa  elm @^_ in. Hg.
                                                                                 Post-Test Leak Check: Pilot:	Orsal:
Number
_fii
C   '
4_i
Swiping
 Time
 (mln)
       3/S"
*3J3
      «353
      I1C&
             OockTInM
              (244KMJT
               dock)
               JO
             JO
               y-s
              6,0
        J:S.
               90
               9-5
        /oo
       1££.
                       GMMator
                        Rwding
                        (Vmjft3
                         . 3 3D
^//3.730
                      vao.soc)
                  S.S3
                         . 5 iO
                                Velocity
                               HMd (Ap)
                                inH2O
                          OriRc« Pr«Mur« Ditter*nlial
                               (AH) In H20
Desired  I   Actual
                                                                   Stack
                                                                   Trnnp.
T«mperatuf«
   °F
                                                     Probe
                                  V//////sY///////////////////7777,
                  5A.
                                        5o
                                       CoO
                                        55
                                         SCo
                                               i.fo
                                                 /.I S
                                                !-»*!
                                               /./I
                                                        /.I
                                                        ;•
                                                         1-2*
                                                                  400
                                              ^37
                                                                             22
                                                    «?-s*

                                         bnpingM
                                         T«mp.
Dry Gas Meter Temp.
  Mel
(Tmln°F)
                             OuUei
                           (TmoulcF)
 Pump
Vacuum
f«n.HgJ
                                                                           v///y////y/////y////////,
                                                                                -J4/7
                                                                                         •5 1
                                                                                         57
                                                                                          55
                                                                                         33
                                                                                    51
                                                                                         53
                                                                                          tTl
                                                                                   SI
                                                                                                 lOO
                                                                                                9-7
                                                                                           (OCi
                                                                                           /o
                                                                                                /Ol
                                                                                                /ot
                                                                                                yo
                                                                                                 ItoL,
                                                                            to 7-
                                                                                                   is?
                                                                                                       /o
                                                                                     to i
                                                                                                         101
                                                                                                         /Of
                                                                                                        l&f
                                                                                                   /OJ
                                                                                                         /0-?
                                                                                                       /OS
                           10*.
                 AVm-
                                                 AH-
                                                                                                                /C.
                                                                                                               10
                                                                                                                 /•v
                                                                                                                /Or
                                                                1&L
                                                                                                                        •y?
                                                                                                   ^5
                                                                                                                                 ft

-------
Page
ot
Plant Name: /*w*t* uju:v^ L.-^.t cc,
Run Number: /w - x - 5.

Traverse
Point
Number

X

II

^

to
















Test Date:
0

Sampling 1 Clock Time
Time, / (24 -hour
(min.) / clock)
IS.30 ' t*4
I&J& ' 1MO
1*30 f t«*

i*
/SffO ' i(.£
l&tt ' ne?
/foC>(? ' 1 7«5
iuo^> ' /ic?
/
/
/
/
/
/
/
/
/
/
/
/
'
'
Gas Meier
Reading
(V.)ft)
^5^.760
^(.S'KS
*r«s. /FC>
4G,«.7G.^

-y7^.6^C>
V 7 7. 7oc>
^J Ox1^ ^ *^^t
f-J^P ? » T!^"^
VSo.aao














Velocity
Header,)
in. II2O
-U"7
. S5
.(^

- 50
-5V
.53
- SJ
-•S5
53














Orifice Pics. Differential
Desired
/ C^S
,.jg
| .kb
/ -W
y.a^
/. 32
1 -3\
i ."id
i-~bq
). 3^














Actual
).c*-S
i.J>%
/ -Cx.O
l.H^I
i.m
;-3a
v. av
l.-^o
1.^0
Aa?0














Stack
Temp.'F
-y-y-s
wy
V?>4
^B^\
'H H
HS^
«/^3
43|
VP 3,
^?A














perator:
Probe
Temp./ Tiller
Temp" F
k ^* jp / ^J j/ ^T
JL^5*~^ c^ 7 »*
•^ ^* ^J ' j^^I/^*S
0-5-s. r^*o
JSo'^so
^G.07 ->Co^
O6"S J?^~>
O* •"* ^*^ ^y**^
J S o ' Dfc>O
f
3*13 ' c?SG>
j^/ ^g^,
'
/
/
/
/
/
/
/
/
1
1
1
1
1
£,-30-«ff
^^fs.

Inipinger
f»n«M
ic nip.
•F
5S
5-p
•5 •?>
S3
5j
5-3
SO

/Ofc
|C)^
/0«\
/C>$
;o*
/o?
/0~)
;o-?














umici
/o5
/O^/
/O "5
/t>4
104
/0"7
* O "7
/c^^a
/OCo
/ OC»














Pump
Vacuum
In.llg
J <>
/S
/5
IU
IU
it*
IL,
; o.
/G>
/<„















y^\^_
51
s\
•So
5TO





-------
                        SAMPLE RECOVERY DATA
PLANT

DATE
                                               Run No.  /*23 'X. -3
SAMPLE LOCATION

TRAIN PREPARER
                        Sample Box No.   H-5    Job No.  /?£/2. QQ3

                            " Bflahousa^	  Filter No.
SAMPLE RECOVERY PERSON  7
COMMENTS

FKONT HALF
Acetone
Container No.

Filter
Container No.

Description of Filter
                             Level Marked
                                                Sealed
                                                Sealed
 Samples Stored and Locked

 RACK HALF/MOISTURE
 Container No.        _
 Liquid Level Marked
                                                 Sealed
    IMP. NO.
                CONTENTS
                            INITIAL VOL
                               (ml)
                                                   WEIGHT (grams)
                                          INITIAL
                                                       FINAL
                                                                    NET
                              ^50
            TOTAL
           «f Tr

-------
       Appendix A. 1.2




   Raw Field Data, Kiln No. 3




Baghouse Stack - PCDDs/PCDFs

-------
                                                                             j
        TRAVERSE POINT LOCATION FOR CIRCULAR DUCTS
Plant:.
Date:
         sT/    U> /^ if r   /T / <-
               .
Sampling Location: RAC- f-fo^s c
Inside of Far Wall to Outaid* of
                                  A»
>  < <
Inside of Near Wall to Outside of Nipple (Nippte Length):	0
Stack I.D.: 3k V<<   ">*>7 far    3 1 3/ ^  5 OuT/V
Distance Downstream from Fiow Disturbance (Distance B):
                   1 Q   inches / Stack I.D. =   1.  °\ dd
Distance Uostream from Flow Disturbance (Distance A):
                 ">-1.5    inches / Stack I.D. =  . 15 dd
Calculated By:	A
O
f
                                                                Schematic of
                                                              Sampling Locatxjn
                                                                                  4'/2
Traverse
Point
Numfcer

a
•^
4
T
C
J
^
9
10
li

Fraction
of
Length
nz./
H( ')
. /p
. 11

. ^j^
, (oli-
1 7^"f5
i^^ ^
i 7? J? i_
• ^33

Length
(inches)
u^ 5
y..tf











^,i<











Proaua of
Columns 2 & 3
(To nearest 1 /8")
<3^^ -7fcl
^ .4-

( «-
°l -Ob
\x°\
O.V3
IT. \

^l.«\^
^1> S>
^^
Nippie
Length
(inches)












Traverse Point
Location
(Sum of Col. 4 & 5)
.1*1 2_
2-5 >'
3k£=fe=#-f^

^n I B j
13/4,
74-3
^f ^ • "^
ZI.O

1>S. >
-iC^- 57,0

-------
     Dua Diameters Uostream From Row Disturbance* (Distance A)

    0.5           1.0            1.5            2.0            2.5
o

s*°
ui
5
  30

-------
                 GAS VELOCITY ,CYCLONIC, AND VOLUMETRIC FLOW RATE
s<
Plant:
ruvH-d u»l-h-r<. Date: fe->1 -V
Sample Location:
Run No.:
Pbar, in. Hg:
Moist, %:
KKv^i &ft^ Hf"^ eJw7'-' Clock Time:
Operators: £& p^
^^ i » *TD^
^i
Stack Dimension, in. Dia. 1 :
Wet Bulb. °F:
Traverse
Point
Number
1
a
i
4-
$
U
1
I
«?
(0
M
IV
1
7
b
q
f
\>
1
I
*
\0
M
^

Velocity
Head, in.
H,O
, ! i
,1 2_
, Ifc
• zi
, ^0
\ M
, itf
- U
, jjt,
1 /O
* G(o
* ov
. l-T

» > 6
> 3-S
,3 >
, "i 2
• ^0
• ?J
« ^0
» \ (?
, | ^
- \ k

Stack
Temp., °F
370
>7 /
1>74
37*
S#t>
3^3
3g>
It 1
3^c?
%'7C)
^fc<-
:>£;>-
3>7o.
^ / ff
%^^
"itf »•
^ O ^
^ ^
^>b /»
"^M
0 .^^
l/^l
3ft6
"5^
3(5)1

Static Pressure, in. H2O: .. t i^
Pilot Tube. Cp: • 14
V > Dia. 2:
Dry Bulb. °F:

Cyclonic
Flow Angle.
c?
3
4-
&
^
r

-------
       Plant:   ftuSI
                                  FIELD  DA IA SHEET
                                           *•"!?   Operator: '
       Sampling Location
       Run Number:
Pretest Leak Rate:
Pretest Leak Check:
         Date
           frn
                                    Sample Type
                                    Pbar
                                    CO2:
                                                         .P» .
                                                          O2:
                                             Nozzle ID:  < -* * '   Thermocouple
                                             Assumed Bvw: C\   Filter #:   *VQ
                                             Meter Box #: t»n.l5 Y: I.QQ  AH@
         : -^T> "S   cfrn
         ck: Pilot: 4
                                    \5 in. Hg.
                                 Orsat:  ^
Probe LengtiYType:
Stack Diameter:  "± 1
                               Pilot #:
                                                     As:
                       Post-Test Leak Rale: ^^ff elm @ _p. in. Hg.
                       Post Test Leak Check: Pilot: _j/_Qna\: »^_
   o*
(40 *•
      Tr

      Numbw
       1L
       10
SwnpKng
 Tim*
 (mln)
            15
             \>1.S
OockTlrm
 dock)
                     15
                        GasMalw
                         Reading
                          (Vm)»3
                               I 00 '0
                                JH.
                               \»  I
                   JJti.
                              JOLJ
                       . L.
                                   ^_Q_
                                •43-
 Velocity
Head (Ap)
 biH2O
      Ociic« PtaMur* Drttetanhal
           (AH) in H2O
        Oesirad
Actual
Stack
Tamp
 (Ts)
  Tampaiatura
     °F
Proba  |
Impingar
 Tamp.
  °F
                                        Dry Gas Meter T«mp.
  Into!
(Tn»in°F)
  Outtot
(Tmoul0F)

                                  JL^.
                                                          - 3
                                             7-
                                             JO.
                                                         Z t_
                                            JLi.
                                     ^JL
                                             IA.
                                                                  V°\
                                                 9
                                                                     9
                                                                   2.
                                                                   I. h
                                                                           ilt-
                                                                          ie.
                                                                    4-IR
                                                               405
                                                                                    ->$
                                                                        ^55"
                                                                                                    3"?
                                                                                       57
                                                                                                            9°
                                                                                                c|0
                                                                                         Hi
                                                                                                            17
                                                                                                 «=«/
 Pump
Vacuum
f«.Hfl)
                                                                                                                            7
                                                                                                                                       Tr-x:

-------
                        SAMPLE RECOVERY DATA
                              Ccw*r»
PLANT    osi/x    yjL  .r/voz~   cwp*r»i _ Run No.

DATE    if ~3>C> - Ifi    Sample Box No.  A/- /O    Job No.
SAMPLE LOCATION    C

TRAIN PREPARER   	'_
                                I
SAMPLE RECOVERY PERSON  7. AbeSrudkJ

COMMENTS        	
                                               Filter No.
FRONT HALF
Acetone
Container No.

Filter
Container No.

Description of Filter
Liquid
Level Marked
                                               Sealed
                                               Sealed
 Samples Stored and Locked

 BACK HALF/MOISTURE
 Container No.        	
                                   To I KfT^t-
                                               Sealed

IMP. NO.
1
2
3
4
5
6
CONTENTS
*»eH
tkfc
tf-zP
ftnpfv
5)|;c*<^l
^ftD-Trop
TOTAL
INITIAL VOL
(ml)
	 	
,00
/oo
— -
2.50
	

WEIGHT (grams)
INITIAL
*~/~12 *-t
10G.-L
ItfX
5*3b.e>
f??.^
3/6. i
•
FINAL
~n?k
t*7/fif
~7£>(p.6
5H/
142.6
S^f

NET
•






n_«nr4«4-lr»r> - J * 	 ' 	 /">n+«l»>

-------
                                                    FIELD DATA SHEET
Plant:
                                  •J
      Sampling Location £>i/-Tl£T «P
f £,'^> Run Number: Re
Sample Type:
Pbar:	
CO2:
                                                                    Operator:
                                                         Ps:
                                                         02:
                                                                                                   Thermocouple
                                                                                                   Filter*: A/A.
Pretest Leak Rate: 0,000  cfm d
Pretest Leak Check: Pilot:     Orsat:
                                      in. Hg.
                                         Probe Length/Type:
                                         Stack Diameter:
                           Pitot #:
                                                                       As:
Nozzle ID:	
Assumed Bws:
Meter Box #:
                 Y: /.DOO AH@:
Post-Test Leak Rate:	cfm @	in. Hg.
Post-Test Leak Check: Pitot:     Orsat:	
Trmww
POM
NUIIMMf



























Swnplng
Tim*
(mln)
0
|

























OockTJm*
(24-hour
dodc)
/^^
/t>47

























GaaMetor .
Reading
(Vmjft3
JS7. i.4/
jn. 78¥

























Velocity
Head (Ap)
inH20
OHioa Pressure Differential
(AH) in H2O
Desired
Actual
Stack
Temp.
(T«)
Temperature
°F
Probe
Fitter
Impinger
Temp.
°F
Dry Gas Meter Temp.
ftr.l^«
Pllwl
(Tmln0F)
Outlet
(Tmoot°F)
Pump
Vacuum
(in.Hg)
y//////////////////////////: v/ '//////////////////////////////.















































































1


























































































V




















































































                        AVm-
                                                         AH=

-------
                        SAMPLE RECOVERY DATA
PLANT  Aj5£o

DATE   '(* ~ ?£>-

SAMPLE LOCATION

TRAIN PREPARER
                                              Run No.  M7>3 - FR-3
                        Sample Box No.  lo*-l    Job No.   R&I2.

                              Qo4liV        Filter No.   f,
                      T.
SAMPLE RECOVERY PERSON  T
COMMENTS

FRONT HALF
Acetone
Container No.

Filter
Container No.

Description of Filter
Liquid
Level Marked
                                               Sealed
                                               sealed
Samples Stored and Locked

BACK HALF/MOISTURE
Container No.        	
Liquid Level Marked
                                               Sealed

IMP. NO.
1
2
3
4
5
6
CONTENTS
£«f>H
t^>
ri^°
BrAP*"7
6:1!^ M
XA-D-Tr*p
TOTAL
INfTIAL VOL
(ml)
	 	
/oo
loo
- — -
•zao
— -

WEIGHT (grams)
INITIAL
^HS.'Z
in-o
T25.I
k/63
13U
"b/7^

FINAL
^4^-2
-111,0
12S./
c//t -J*
-71'-2'
.3/75

NET
•






Description of Impmger Catch:

-------

-------
          Appendix A. 1.3




     Raw Field Data, Kiln No. 3




Baghouse Outlets - Velocity Traverses

-------
                  <*  \^ v
                  ^   S  "*





                  N   N  i
                                       '**
oo     3

^    4
       L.  W


       «  ^s.


       ?  ^
N
-^   -    f
 0



I



ro
 0

~Z
                           I
      a



                          sr
                t-l
           1    *

           \-    K
           a    K.
           O    o

                                                                                                                               A
                                                                                                                                       r


                                                                                                                                      X-

-------
Plant:
 GAS VELOCITY AND VOLUMETRIC FLOW RATE



- wH\-rg  	K\u^  Klo -3    Date:
Sampling Lot
Run #: -A^UO
ressure, in. 1-
fa: O^.T^ Static Pressure, in. hUO: •*•»!/
Molecular wt.. Drv: PitotTutWorr - ¥4.
sion, in. Diameter or Sid«
: DryE

Velocity
H«»d
In. H20
,r>5
• 6 f-
» t) "1
. Oi>
i o G
. 0 #
Stack
T«mp.
°F
"i^C
3X t
543
3^4
3 tq
"31 ^
.0 * 3 7i
D $ 375"
vO1?
.^^
•01
,0 T
,0k
. OG
. ti ^
. 0 CD
, 0^
1 6^»
a x>
. o<^
v 0^
, o^
\ 0^
-0 &

$p .
37J
i 74
37^-
^>& y
w *j W
«**! /* I
J ^Q 1
7) fol
T, -]^
^?C,
-^Jo
^JC\
"W fc ^^
V 
-------
GAS VELOCITY AND VOLUMETRIC FLOW RATE
Plant: A.
                              Date:
Sampling Lo
Run #: *4oa
Barometric F
Moisture, %:
Stack Dimen
Wet Bulb, °F
Travtrt*
Point
Number
y /
2
3
*/
g
6
7
8
q
JO
It
12.
g/g 1
2
3
tf
£
L>
1
B
9
ID
II
/*>


cation :^t?>As£,u2>{jL£>e. Ot^-rcef Clock Time*. & * .
rw -^ Ooerators: /Z,£Au J£5/s*z.vrr
ressure, in. \
Ha: O-^-J^ Static Pressure, in. I-UO: — OB
Molecular wt.. Drv: Pilot Tube. CD: • 9 4
sion, in. Diameter or Sid<
: Dry!

Velocity
H««d
In. H2O
. oS
, OS
I V
• \ 3
v\_r
. \£
Stack
T«mp.
°F
ii^
34^
i^j
3^ /
2>6«
^^^
,13 -37?-
1 1 1 ^ ^4-
, OG
4 0^"
%04
. O^
« \0
* V I
1 \ I
% | r
1 1 \
> \ \
\ ^
i\ V
i n
. 0<\
i 0°\
. Cfo

^KP-
0 73
3 7 >
3-70
3>k 1
^fc5
3G 4-
^4,3
^6^-
3> *7\
3"U
n,-)^,
^-11
^lb
'MC
-bit)
1>^0

T.-
31: Side 2:
3ulb.°F:
Md - (0.44 x %CQ2) + (0.32 x %O2) + (0.28 x%^)
Md « (0.44 X ) + (0.32 x ) + (0.28 x )
Md-
% H2O % H2O
100 100
Ms-
Ti- °F- °R(°F + 460)
13.8 13.8
Pt - in. Hg
= / Ts (°R)
v. = ab.4«xCpx^Px \l P8XM8
Vj-fl548x( )h( ) x Al 	 	 	 	
V»- ft/i
At- n2
Qi-VixAax60a/m
Qt- x xflO
Pt %K^O
•W ' T« 100

ttd 100

-------
              GAS VELOCITY AND VOLUMETRIC FLOW RATE
Plant:
Run
- L V
                                             Date:
Ln-^ZS-
ling Lo
*: "Sau
netric P
ure, %:
Dimen
Julb,°F
V«HM
olnt
mbar
/
^
3
V
^
£
7
£
5
A9
;/
/£
1
2
J2,
^
/f
u
7
8
9
/o
//
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cation: GVS^KUW^ Ou-ree-r Clock Time: <70 f
rirw ^ -»? Ooerators: £&/&<*
ressure, in. 1-
to: 3.^1 S 4^ Static Pressure, in. HoO: — i Qtf
Molecular wt.. Drv: Pitot Tuba. CD: . f*
sion, in. Diameter or Sid«
: DryE

Valocrty
Haad
In. HjO
, \0
, 1 b
D°l
, \ t>
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Stack
Tsmp.
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91: Side 2: .
3ulb.°F:
Md - (0.44 x XCOj) •)• (0.32 x %O2> -t- (0.28 X %Nfe)
Md - (0.44 x ) •)• (0.32 x ) •)• (0.26 x )
Md-
% HO % HO
Mti m MH v M - . , ,. 1 + 1 ft f ^
100 100
Ms-
pg _ pt, + °'"- - ( ) -,-
13.0 ' ' i3.e
Ps - in. Hg
— / Ts (°R)
Vs-ttb.AWxCpx^P x ^ p8xM8
Vs - fl5.48 x( }>i( )xAJ
V / V / y
Vs- ft/s
As- ft2
Qs - Vs x As x 80 s/m
Os » x xM
Qs * acfm
p, %H-0
Oi^j- O* x 17.647 x 	 x (1 • 	 *— )
•W T« 100

                                 QHtd-

-------
              GAS VELOCITY AND VOLUMETRIC FLOW RATE
Plant:
KJ» »J
Date:
<
1
1
\


\J
rt
Sampling Lo
Run #\ 'Zon
3arometric P
Moisture, %:
Stack Dimen
Wet Bulb, °F
Traverae
Point
Number
Ki, -
2.
!*>
4
5
0?
7
&
^
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//
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2
3
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^
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7
£
4
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11
12


cation: ft^6, uoo.i/5" OuTr^f Clock Time: *? /ft
,r-^ ^^ Ooerators: Cr£ / P_S
ressure, in. K
4a: ^L *|, -J" f- Static Pressure, in. H«O: "" , V&
Molecular wt.. Drv: Pitot Tube. CD: • K i
sion, in. Diameter or Sick
: DryE

Velocity
Head
In. H2O
, 0$
03
, 10
, 1 1
, \s
,7 Z.
Stack
Temp.
3 fl-
35-2,
3^
IS 5
3-6>
3£5?
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1-5"
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i 0J*3
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3J*y
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^14-
11S
%i.r
3"K
^•74
?>9^

•MM
Ta-
s1: Side 2:
3ulb.°F:
Md - (0.44 x %CO2> + (0.32 X KOj) + (0.28 X%Ntj)
Md - (0.44 x ) + (0.32 x ) + (0.28 x )
Md-
% H.O % HO
Mn w Mr) v M . ... . 1 + 1 ft f 1
M,-( )x(1-_^r)*18(-T35-)
Ta- °F- °R (°Fi-460)

-------
GAS VELOCITY AND VOLUMETRIC FLOW RATE
Plant: Akfm^- lv/Hm=-     K«-*
Date:
                                        4> -
Sampling Lo
Run#: Ni°'
Barometric F
Moisture, %:
Stack Dimen
Wet Bulb, °F
Travaraa
Point
Number
s (
2.
3
y
5-
^
7
ft
q
JO
j 1
/2
£ /
2
4
4
$-
t>
7
6
 \ \

$P-
3^jy
3 #3
3 tf £
3^3
3fe1
2>^ 3
T, g f
>* 7
^H
3Cj|
^13
3*}d
-^qj
^> *1 I
"S ^^
-S^D

T«-
B1: Side 2:
3ulb.°F:
Md - (0.44 x %COj) + (0.32 x %O2) + (0.28 x %N^)
Md - (0.44 x ) + (0.32 x ) •)• (0.28 X )
Md -
% H,0 % H,0
M* w UH v/1. 1 j. 1fl / )
1 00 1 00
100 100
Ti- °F= °R(°F*460)
pg r pb + S-P/, _ / ) +
13.8 ' ' 13.6
P« - in. Hg
^SP-
== J T. (°R)
V« = 85.49 xCpx V&P x Al 	 p Ma —
Vff-^B-ipr{ )>( }vJ
Ve- ft/t
AS. n2
Q» - V» x A» x 80 a/m
Qa- x xflO
Qa • acfrn
Pt **^°
Qa..- Qa x 17.847 x 	 x (1 • 	 *— )
atd T, 100
aid ' too
                              Uacnii

-------
GAS VELOCITY AND VOLUMETRIC FLOW RATE
Plant: AUST/AJ - Jd/rrs /?;&~2^-^
Sampling Location: 3A&#ot/6£ £)*t/
Barometric F
Moisture, %:
Stack Dimen
Wet Bulb, °F
Travaraa
Point
Numbar
s /
2
3
4
s
t>
7
£
q
/o
If
/Z
fivl i
2

i


1
8
q
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jl
It


ft>ffTH ^ Ooerators: £6 /A£
'ressure, in. \
<\
^g: <3-c!l 5 4- Static Pressure, in. HoO: "^ » / 0
Molecular wt.. Drv: Pilot Tube. CD: • £/
sion. in. Diameter or Side 1 : Side 2:
': Dry Bulb. °F:

Vatocrty
H«ad
in. H2O
.0°\
, o^i
, o«i
, lo
, \
v \\

^
. 10
i 0 9
, -Ofe
	 1 	
» 0$
v \ O
A \ 3

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, Oc\
^ 0 (rt
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Stack
Tamp.
"b **5
316
3 ?<.
1 7^
3t> 6
3 V-3
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3-7-7
374-
37 >
36 1

37_r
3^0
3?3
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^^^
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i«3
380
0,^1,
^>«6 \

T.-
Md - (0.44x%CO2) -i- (0.32 x%O2) + (0.28 x%Nfe)
Md •= (0.44 x ) + (0.32 x ) + (0.28 x )
Md-
% H2O % H2O
M..( jxd.-jgj-) +18(^35.)
Ms =
TJ. °F= °R(°F + 460)
e p
p, _ pt, + ,fr-. - / ) +
13.0 ' ' 13.C
Pa » in. Hg
— / Ta (*R)
Va = 85.48xCpx^Px ^ p8xMe
V« = R«i 40 v ( ) v ( ) » A /
Va- ft/a
Aa- n2
da - VaxAaxQOa/m
Qa- x x80
CM * ocfro
Pa %H,0
O« ..-Qtx 17.847 x 	 x(1- 	 *_)
•" Tt 100
**Mm x 17.047 X 	 X ( 1 	 )
ltd 100
                            daefm

-------
JiffS
                  GAS VELOCITY AND VOLUMETRIC FLOW RATE
Plant: ALL^TM^ - to at -re tOusj A»JO 3> Date: t-^?-^*
Sampling Lot
Run#: A/&
Barometric P
Moisture, %:
Stack Dimen
Wet Bulb, °F
Trav»r»a
Point
Numbar
55 /
2
3
Lf
5
I
7
&
q
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II
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2
3
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^
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7
8
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//
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sation: $A&MOUS& ®urLe-r Clock Time: l4-^o
v^r-A' **( ? Ooerators: <££? y^5
ressure, in. H
^a: ^^ ^^ Static Pressure, in. HoO: ~~ • ^ *?
Molecular wt.. Drv: Pitot Tuh&Cn: • 1 4
sion, in. Diameter or Side
: DryE

Valocity
H«ad
in. H20
. 15"
. U
. \ 1?
• T-O
. IL
< 30
Stack
Tamp.
°F
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3l>-
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f »
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-1
4> ^
4^G
4?-5
4> ^
41(0

Ta- ^iQ
M: . *1 Side 2:
3ulb.°F:
Md - (O.MxKCOj) -i- (0.32x%O2> + (0.28 X%Nfe)
Md « (0.44 x ) + (0.32 x ) + (0.28 x )
Md -
% H2O % H2O
Mil «• ( W M . 1 + 1 R ( ... ., \
MS-( )X(1 10Q ) + 1B( 1QO )
Ts= °F= °R (°F-t-460)
pB » Pb + s:p,;. - ( ) +
13.8 ' 13.6
Ps = in. Hg
JftP =
— | Ts (°R)
V«-«b.4MXLpX^P X ^ p8xM8
Vn-8«i4Bx( )h( 'x\f 	
Vs- ft/*
A.- ft2
Qs » Vs x As x 80 a/m

Qa- x x60
Qa - acfm
Pa %H,0
Oa^ .- Qa x 17.847X 	 x (1 - — -*— )
«W Ta 100


                                            cwcnit
                                                 A 1

-------
GAS VELOCITY AND VOLUMETRIC FLOW RATE
Plant:
- VJ
                 uo-g
K
IIM
                              Date:
Sampling Location: A/ae-rtj -^4f dA^Uouie' Q«T. Clock Time:
Run#: Afo«
Barometric F
Moisture, %:
Stack Dimen
Wet Bulb, °F
Travtra*
Point
Number
S i
2
3
4
5"
£>
"7
A
<9
/o
/I
/2
Vs/ /
2
3
y
.5-
L>
7
8
9
/O
//
/2


?T?/ ^V Ooerators: <££AV / ^2s>/-*xn_
ressure, in. h
Ha: 1 ^r. J"f Static Pressure, in. HoO: — , P /
Molecular wt.. Drv: Pitot Tube. CD: . « /
sion, in. Diameter or Sidi
': Dryl

Vtloctty
H«ad
In. H20
»0^
0 \
O3
c? 3
0 ~L
o T_
Stack
T«mp.
^OS
'bio
^!1_
^ 14.
3)4,
3 iJ
, D"L 1»4
O*L 'b \4-
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N 0 ~T—
, to "L
V s_
i oT-

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V 0 ^

\ Ci*^
v 0^-
ot
, o"L
, 0 \
» 0 \

£? -
3 1 "i
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3 1 I
3 0*1
3\O
3o^
3ofc
3o<
^DS
TjDg
3 n
3U
3 IT
2>\4_
^j-.
3lD

T«-
91: Side 2:
3ulb.°F:
Md - (0.44X%CO2) + (0.32X%O2> + (0.28 X*!^)
Md «= (0.44 x ) + (0.32 x ) -K (0.28 x )
Md -
% HO % HO
HA _ 11.1 wH *\_L4Q* * \
100 100
100 100
Ms-
T- OF- O_ ,0-
Ts - F = R ( F + 460)
P« - Pb t -S.'.P-- - ( ) +
13.8 v ' 13.6
P« - in. Hg
fir-
== I Ts (°R)
Vs = 85.4WxCpx^P x 1^ p8xM8
\/« = R1 4Q * ( ) ^ ( ) y A I , , .,
V*« ft/8
AS- n2
Qs - Vs x As x 80 s/m
Qs - x x80
Qs * acfm
Os ..- Qtx17.847x — x(1 • )
«" T« 100
Q»^j- X17.B47X 	 X(1- )
•td 100

-------
      Appendix A. 1.4




  Raw Field Data, Kiln No. 3




CEMs Summary & Strip Charts

-------
HCI Emission Measurements from Kiln No. 3
       Austin White Lime Company
             Austin, Texas
                6/30/98
Time
Date
Inlet/Outlet
HCI
ppm
THC
ppm
O2
%
CO2
%

12:48-13:08
13:48-14:08
14:48-15:08
6/30/98
Outlet
Average
0.9
1.0
1.5
1.1
7.9
8.4
8.6
8.3
11.2
11.0
11.0
11.1
18.6
18.4
17.4
18.1

14:18-14:38
15:18-15:38
15:38-15:58
6/30/98
Inlet
Average
1.1
1.3
1.1
1.2
9.9
10.7
10.4
10.3
10.2
9.8
9.8
9.9
18.8
18.9
19.3
19.0

-------
HCI Correction Worksheet
 Austin-White Lime Company
         Kiln #3
       30-June-98

         OUTLET
H Actual value
,'>x3BB$q**£, 11 0
* *lra Si
3 Point Cal
0.8
26.3
48.5
slope (m) 0.976
Y-lntercept (b) 0.51
Avgconc: 1.1
Actual Cone: 1.6
PreBias
0.8
48.5
0.977
0.80
Post Bias
1.2
49.7
0.994
1.20
          INLET

zero ;
mid \
' tagfc
Actual value
0.0
27.1
48.8
3 Point Cal
0.9
26.4
47.8
slope (m) 0.960
Y-lntercept (b) 0.74
Avg cone: 1 .2
Actual Cone: 1.5
Pre Bias
0.9

47.8
0.961
0.90


Post Bias
1.2

46.9
0.936
1.20



-------
-1R
-ID
                                       *«* RtSEl fWHtt 89 45.«  a 2 3   FW       THC (f«
                                         KSBI flVBMtt 89 45 83  22  V 3   PCT       COC flf
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                                            < PRINTER  OFF 20:17;24 JUN 2^98 •»•**
                                             PRINTER  ON 28:17:14 JlJN  28/98 *•"*

-------
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-------
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-------

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-------
 Appendix A.2




Raw Fidd Data




  Kiln No. 2

-------
      Appendix A.2.1




 Raw Field Data, Kiln No. 2




Scrubber Inlet - PCDDs/PCDFs

-------
        TRAVERSE POINT LOCATION FOR CIRCULAR DUCTS
Plant.
Data:
                          L'\
Sampling Location: n;v~
Inside of Far Wall to Outside of Nipple:.
Inside of Near Wall to Outside of Nipple (Nipple Lsngth):.
Stack I.D.:	
Dbtanca Downstream from Flow Disturbance (Distance B):
                         inches / Stack I.D. •  /£. J   dd
 Distance Upstream from Flow Disturbance (Distance A!):
                  4ct>   inches/StackI.D. - /• P   dd
 Calculated Bv:  >>.gA^;*>    k.   H
                                                            Sampling Location
Traverse
Point
Number
i
rO
^
V
s
Cc
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•8
1
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II
u
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Traverse Point
Location
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/r
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-------
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   Duct Diameters Downstream From Row Disturbance* (Distance B)
   • Fiom RoM of Any Typ« of Dteturbww* (B»nd, Expmton, ConfrMtfon, «te)
           LOCATION OF TRAVERSE POINTS IN CIRCULAR DUCTS
         (Fraction of Stack Diameter from Inside Wall to Traverse Point)
Traverse
Point
Number
on a
Diameter
1
2
3
4
5
6
7
8
9
10
11
12

Number of Traverse Points on a Diameter

4
0.067
0.250
0.750
0.933








6
0.044
0.146
0.296
0.704
0.854
0.956


'



8
0.032
0.105
0.194
0.323
0.677
0.806
0.895
0.968

t


10
0.026
0.082
0.146
0.226
0.342
0.658
0.774
0.854
0.918
0.974


12
0.021
0.067
0.118
0.177
0.250
0.356
0.644
0.750
0.823
0.882
0.933
0.979

-------
                      GAS VELOCITY AND VOUJMETRIC FLOW RATE
/s
S
/•s
 /5
  8
^0
 f fc
  ~-^

 O
  o
o
  Il<:
       Plant*,
       Sampling Location:.
                                                       Date:_£_
                                                       Clock Time:
       Barometric Pressure, in. Ho:
       Moisture, %:_!	Moiecularwt, Dry:.
       Stack Dimension, in. Diameter or Side 1:	
       Wet Bulb, OP	     Dry Buto,oF:.
                                              Operators:.
                                              Static Pressure, In. HUQ:  - "7.
                                             	Pitot Tube, Cp:
                                             	Side g   	
           Point
          Numtar
               \o
          8   1
                     .9V
                      51
                      fO
                    •95
                    50
                   53.
                    51
                     51
                              Stack
                              Twnp.
                               °F
                               550
350
                             Bso
                                           Md -
                                          TJ-
                                          V«-e&48xCpX
                                         v«-es.48x(
                                                      ?=  J  T.(°R)
                                                            PtxMs
                                                     tfe
                                                              xao
                                          Qi ..-O«X 17*47x	
                                            no          T.
                         p»
                         ^^^^H
                         T*
                                                               100
                                                                          100

-------
               GAS VELOCITY AND VOLUMETRIC FLOW RATE
Plant!
\_;,
            Co.
Sampling Location: u:\~^**.
Date:    ~7- i-
Clock Time:  MO<.
                      Trc^opc^g  i^>. pi  Operators:.
Barometric Pressure, ia Ha:    ^.ao     Static Pressure, ia HUO:  - "?•
Moisture, %:__jfi__ Molecular wt, Dry:	PKotTube, Cp:.^.
Stack Dimension, la Diameter or Side 1:	Side 2:   	
Wet Butty OR  *-*	        Dry Bulb.OF!    —-	
   TfWWM
    Point
   Numbw
        1
        L
        "7
    A-   i
       f*
              .53
              .4/3
 Stack
 Twnp.
 3-90
3V/
                       37^
                       3-71
             Md-(044X    )•

             Md-
                           TcT^^-iB-1
                                    TS-
                                    Pi-
                      'F-
                                                         ISA
                        ln.H0
            V«-65.48xCpX
                                    V«-65.40X(
                                    Aa-
                                    Qi-VtxAixOOa/lm
                                Ptxfcto
                                                         xeo
                                                •eftn

                                                  P»
                                                 —
                                               X17447 X'
                                                                    100

-------
                                                      FIELD DA.   SHEET
Plant _J_
Sampling Location &(\^
Run Number: .j njpsTy
Pretest Leak Rate:  j£"
Pretest Leak Check: Pttol:
         Date:  "7-1-SB
          cfm
                            Sample Type:
                            Pbar:
                            C02:
                                                                     Operator:
                                                                        --7.0
                                                                02:
                                     Zuwin. Hg.
                                  Orsat:  /Q/A
Probe Length/Type:,
Stack Diameter:
                                                  As:
                                                                                 Nozzle ID:    . .^Thermocouple #:
                                                                                 Assumed Bws: /Q  Filter #:
                                                                                 Meter Box #: Aift-tt Y: /.wi  A
                                                                                 Post-Test Leak Rate: '.%•* cfm
                                                                                                 .'In. Hg.
                                                                                Post-Test Leak Check: Pltot:  \xOrsat:
                                                                                                      ~~^
#3.78
Numbw
           to
           n
           /a
           *
           ID
           II
               Thiw
dock Tim*
 (24-hour
 dock)
if SO
                     I73C,
           Ftoadmg
                                 .5/7
         06.
                                              hHZO
                                                   (AH) in H2O
       D«5lr»d  I   Actual
                          Stack
                          Tamp.
                                                                           T«mparalur«
                                                                               °F
Prob« I  FMtar
               knpingcr
               Tamp.
                                                                                                        Dry Gas Malar Tamp.
                                                                                   (Tmln0F)
                                                                                                        OuM
                                                                                                       (Tmoot°F)
 Pump
Vacuum
(in. Hg)
                                               61
                                                        /. /s
                                                /.S7
                                                                 J.SO
                                                                1.
                                                        1.50
                                                    353
                                                                          S53
                                                    157
                                                                                       y//////////////////////////,
                                                            .350
                                                                        ^50
                                                                   2^L
                                                                                          £"7
                                                                            /bO
                                                                            5*1
                                                                            57
                                                                                                         no
                                                                                                         1(1
                                                                                                JIG
                                                                                                        / IO
                                                                                                 1 tO
                                                                                                        1 1 1
                                                                                                         1 1
                                                                                                        1 If
                                                                                                 l/i
                                                                                    MJ,
                                                                                                                too
                                                                                                                MO
                                                                                                        /Ofc
                                                                                                        tot*
                                                                                            10 lm
                                                                                                         Wr
                                                                        1C*
                                                                                                                      5*7
                                                                                                                     5D
                                                                       Ti.

-------
                       SAMPLE RECOVERY DATA
PLANT

DATE
Li
                                              Run No.
                       Sample Box No.  A/-5    Job No.
SAMPLE LOCATION   K:ln  *2

TRAIN PREPARER    1"'.
                                              Filter No.
SAMPLE RECOVERY PERSON
                             - A
COMMENTS

FRONT HALF
Acetone
Container No.

Filter
Container No.

Description of Filter
   Liquid
   Level Marked
        t-(
                                              Sealed
                                              Sealed
Samples Stored and Locked

BACK HALF/MOISTURE
Container No.        	r_
Liquid Level Marked
                                              Sealed
    IMP. NO.
               CONTENTS
  INITIAL VOL
     (ml)
                                                 WEIGHT (grams)
                                        INITIAL
                                                    FINAL
                                         NET
                            /CO
                                       •705. Z
                                      -3.5
                            / oo
                                      T2/.V
                                       5/5.7
                                                                3-J
                                                                3-7. -7
                     '•$-
                                                                   . »
          TOTAL
 Description of Impmger Catch:

-------
                             FIELD D/      SHEET
/N.   l^\(
Sampling Location tc:u
Run Number: £-
Pretest Leak Rate:
Pretest Leak Check: Pilot:
                     Sample Type:
                     Pbar:	-^
                     CO2:
                                             Operator:
                                           Ps:
                                           O2:
                                                — ~? O
      elm i
                  In. Hg
:  .o/v
            Orsat:
Probe Length/Type:
Stack Diameter:
                                                As:
:  Nl/A
 "»
Nozzle ID:     . P&Jhermocouple #:
Assumed Bws:  to Filter #:
Meter Box #:
Post-Test Leak Rate:
                         AH@:
                  . oaocftn
Post-Test Leak Check: Pilot:  /J | ftOrsat;
                                                                                               . Hg.
TrevwM
Point
Numbar



























Tkra
(mlr^
D
P

























CkxATkna
(244wur
dock)
OUOO
0*0^

























Gaa Mater
Raadmg
W6,."5o&
-VS-Gi . -7-95

























Velocity
Head(Ap)
InHZO
Orilce Pressure Differential
(AH) In H2O
Desired
Actual
Y/////Y///////////////.














































































Stack
Temp.
(T«)
Temperature
°F
Probe
////////////























•




























Fitter
Impkigar
Tamp.
°F
r / f J f * J f S f J




















































Dry Gas Malar Tamp.
(Tmln0F)
V////.























t


Outlet
(Tmout°F)
Pump
Vacuum
On. HO)
///////////




















































AVm-
                                                   Ti-

-------
                        SAMPLE RECOVERY DATA
PLANT
                                                Run No.
DATE     ~7~ t-Qff     Sample Box No.  U>1-\    Job No. _

SAMPLE LOCATION   ftlfi *?-	  Filter No. 	£
                                                              . OO3
TRAIN PREPARER
SAM PT F RECOVERY PERSON
COMMENTS

FRONT HALF
Acetone
Container No.

Filter
Container No.

Description of Filter
                             Liquid
                             Level Marked
                       Z3 "
                                                Sealed
                                                Sealed
Samples Stored and Locked
BACK HALF/MOISTURE
Container No.           ^2-3-
 Liquid Level Marked
                                                 Sealed
    IMP. NO.
                CONTENTS
                            INITIAL VOL
                               (ml)
                                                   WEIGHT (grams)
                                          INITIAL
                                                       FINAL
                                                                    NET
                                        7723
           TOTAL
 Description of Impinger Catch:

-------
       Appendix A. 2 2




  Raw Field Data, Kiln No. 2




Scrubber Outlet - PCDDs/PCDFs

-------
        TRAVERSE POINT LOCATION FOR CIRCULApJJUCTS &
Plant:
Date:
        ft
          b
Sampling Location:.
Inside of Far Wall to Outside of Nipple:	^	
Inside of Near Wall to Outside of Nipple (Nipple Length): __i_/?
StackI.D.:       5*3 . l^	
Distance Downstream from Fjo^Disturbance (Distance B):
                                           3, 1 dd
                       /*?*"
                 /4 V^—ifiches / Stack I.D.
Distance Upstream from Flow Disturbance (Distance A): ^
                  \ S  X-^fhches / Stack I.D. = J^?±   dd
Calculated By:	
                                                             \
                                                               Schematic of
                                                             Sampling Location
Traverse
Point
Number
f
3
3
f
J
t
0
if
1
'D
]/
'•L
Fraction
of
Length
. 6*;
. n^ 7
. / U
.I-71
. ?-J o
,3^6
.fe ff
.1 3" b
,^^3
,V?x
,.JX
C--2 ?
T-4>
\1,3 |
u . ci ->"
M^q
i^.^>
4-^.8 >
4^.^C,
^$











Traverse Point
Location
(Sum of Col. 4 & 5)
*.*4-
C-6T
9.40
O-JJ
»(,-f 3
5> 0 %
3 7 -4f
43. o C

-------
  50
      Duct Diameters Upstream From Row Disturbance* (Distance A)
    0.5            1.0            1.5            2.0            2.5
£
c
'6
Q.

-------
GAS VELOCITY .CYCLONIC, AND VOLUMETRIC FLOW RATE
Plant:
Ao^~r)«v l**>)Ji~iC Date: G>-3o-^X
Sample Location:
Run No.:
Pbar, in. Hg:
Moist, %:
ii 1 V>>Vv Ov^LA Clock Time: |^ ,'Co /TO
*• Operators: r r P5
^s <^ . -^ i- Static Pressure, in. H2O: ""~__^$. 0
Pilot Tube. Cp: i 9 4-
Stack Dimension, in. Dia. 1 :
Wet Bulb. °F:
Traverse
Point
Number
I
2
3
f
S
C
7
r
^
(0
I/
)1
1
7
}
f-
;
C
1
t '
4
In
t;
,T

Velocity
Head. in.
H,O
. 4-i-
. U
.4.4-
i 4 X
4 1
•2>*1
• 3 ^
.3 -7
. ^ C,
:b%
, ^x
"L^
. 4X
* 4- J-
4 0i
> 44
,43

i'S)
.4o
, ID
, -»,>
;i>
.'SO

Stack
Temp., °F
1 ^ "i>
ilf
153
\ ^3
1 3 3
( 3"i
I 3 "i
1 3> 4-
\ H
lif
^ >J
1 ^
U 3
1 i^
|33
n 3
1 31
) 3-j
)33
1 51
133
1 "SV
I 3>
\*iX

S'i. > ^ Dia. 2:


Cyclonic
Flow Angle,
9&1-
0
7-
^j.
J"
Jf
1 s
\~s
IS
3o "^
£,k
>X
1 L>
* i
-}
f
J
\

30
^>>

sq.rt dp Stack Temp Angle, °
Average |,l,\TSl\1>V 1 \ 1 SL.

Directon
of Angle
-tec^
——
ec i^
Ccu/
c-c u/
CC i^
Cc tw
C tb
CCc^
C C U^
CCt^
Cd^
ecus
CC UJ
C C ^
CCK/
Cc u

ZCvj
Cc i^
Ce u>
cc uy
CC vj


Dry Bulb. °F:
Md • (0 44 x %COn) + (0 32 x %On) 4- (0 28 X %N?)
Md - (0.44 x ) -*• (0.32 X ) + (0.26 X )
, Md-
% H2O % H2O
M.-Mdx(1- 10Q )*18( 1QO )
*-< '"^-Tob-^18'^^'
TZ- °F- °R(°F + 4«0)
° 13.6 13.6
P« « 2~? . ' ^ in. Hg
== / T9(°R)
vs-es.wx^x JSP * \l P9XM8
/
Vs • 65.49 x ( ) x ( ) x Al
V»- ft/a
Aa- n2
Qt - Vt x As x 60 i/m
Q»m X X60
Qt • •dm
Qt ...Qtx 17.647 X 	 x(1- ^ )
tn TJ 100
•H 100

-------
                 GAS VELOCITY AND VOLUMETRIC FLOW RATE
Plant:   A b ST
               /
7
Date:
A
Sampling Lo
Run#:
Barometric P
Moisture, %:
Stack Dimen
Wet Bulb, °F
Trav*nM
Point
Number
i
7
"i>
V
j
6
1
^
^
ih
! I
l^
\
7-
3
4-
5

5
Z- Ooerators: C»C/ f>S
ressure, in. H
ta: 2 ^. fc £> Static Pressure, in.- H»O: *" ?^-<5
Molecular wt. Drv: Pitot Tube" Co: «»^-
sion, in. Diameter or Side 1 : Side 2:
: Dry Bulb. °F:

Velocity
in. H20
A5
i-Z
,4;.
4-£
.4^
i f >
Stack
T«mp.
°F .
13^
5O
133
1 ^ J
134
1 3,T~
• U '^5
t 5"! | -5 j
•55
.^"5
, J(o
*$1o
,sy
A>
A-fc
'^
,4- 15
i4^
• Jb
-^^
,55
.«S"3
,5- ^
• Tp

^KF -•')o^
13J
I 3&
136
134
( 35
134
(3b
I3j>
1 ^4
1 "S ^
1 34
3^>
I -^(o
* *y v
134
IM

fJ- l"b^
Md - (0.44X%CO2) f (0.32 x^iOj) t- (0.28 X%N^)
Md - (0.44 x ) + (0.32 x ) * (0.28 x )
Md-
% HO % HO
Ma « hAH v H \ * 1ft / ^
M. — / \ y M . ^ t 1ft f 	 ^
Mi -I )X(1 1QO ) + 10t 10 ( ) x \ I ...
1 ;v j w
V«- ft/s
A.- n2
Qt - V« x As x 60 a/m
Qt- x XBO
Qs » acfm
p, %H_0
O> ..- Q» x 17.947 X — — x (1 • — — )
ltd T, 100

•n loo
                \ fi_s

-------
                                            FIELD DA\   JHEET
 Sampling Location  Vy
Run Number: (VS-O^-  Date:
Pretest Leak Rate: -064- elm @^fr x
Pretest Leak Check: PHot: tXorsaf
    Sample Type: J
    Pbar:  ^.(p
    CO2:
                                                ^3   Operator: GC/V>     Nozzle ID:
         Ps:
         O2:
                                                                                              Thermocouple #: 5"
                              ln. Hg.
    Probe Length/Type: 5'6-Ur>   Pitot #: J"/l
    Stack Diameter: y3 ^5   As:   IS > 4 6
                                                                         Assumed Bws: J5  Filter #:
                                                                         Meter Box #: g*o;5" Y: J,0O
                                                                         Post-Test Leak Rate: , ppf- cfm @|o in. Hg.
                                                                         Post-Test Leak Check: Pitot:     Orsat:
 Point
Number
       Tim*
       (mln)
       Clock Tim*
        (244xH
        dock)
                      Goa Meter
                       Reading
                       (Vm)n3
 Velocity
Head (Ap)
 inH2O
Orifice Pressure Ditterenbnl
    (AH) in H2O
 Desired
           Actual
Stack
Temp.
 (Ts)
Temperature
   °F
                                    Probe
                                            Filter
Impinger
 Temp.
  °F
                                                                                             Dry Gas Meter Temp.
                     Inlet
                   (Tmln0F)
  Outtoi
(Tmoul°F)
 Pump
Vacuum
(in.Hg)
        O
        M
             \Va-\
                                y///////////////^^^
                                          1.0
                                                        - 0
                                                                                                                        "1
       15
                                          1.
                                                       J^J.
                                                          iA4.
                                                                                                             Jo.
                                                                                       ss
                                                                                        (01
                                                                                                            j_a
      30
        \v\
                                                                         LL
                                                                                                       11
                                                                                               01
                                                                                                 1 Ob
                                                                                                                  fj

                                                                                                                 43
                                                                                                                 43
                                                                                                                 T3
                                                                                                                 f >
      fco .0
                       -3
                                                                                         105.
                                                                                                      10 7
                                                               li.
                                      . JkV
 to
                                                                                              joj.
                                                                                                  _CL
                           0
                                  43
                    14^
                   i>t
                                                                                              (0
                                                                                      S3
                                                  1
                                                              13A
                                                                 JA7_
                                                                                                       is
                                                                         337
                                                                                             104.
                                                                                                     t o  6
      zo
                                                                -14,
 5
A7.-S
                                                                                                     i^JL
                                                                                                       14
                                                                                     ££_
                                                                                       ioi
                                                                                                            it
                                                          3
                                                                                        105
                                                                                                                  n
      So
                           •O.
                                                                 153
                                                                                                    102.
                                                                                                     Io7
                                                                         17
     Sl.S
                                                           AL
                                                                                                             H
      G5
                               ,  3?
                                                ,1
                                                                                     rn
                                                                         n
M
 7*5
                                                                                         105
                                                                                                                 ti-
      ifo
                      MO
                                                                                                     1£L
                                                                                                       in.
                AVm
                                                                                     Tm>

-------
                        SAMPLE RECOVERY DATA
PLANT

DATE
                              Run No.
SAMPLE LOCATION
TRAIN PREPARER
        Sample Box No.  AJ-JQ    Job No. _

                              Filter No.
SAMPLE RECOVERY PERSON
           TfV
COMMENTS

FRONT HALF
Acetone
Container No.

Filter
Container No.

 Description of Filter
             Liquid
             Level Marked
                   Sealed
                               Sealed
 Samples Stored and Locked

 RAPK HALF/MQISTURE
 Container No.        	
 Liquid Level Marked
                                Sealed
     IMP. NO.
CONTENTS
INITIAL VOL
   (ml)
                                                   WEIGHT (grams)
                                         INITIAL
                                      FINAL
                                                                   NET
                               /ok
                            . 5
                                        767.7
                              20
                                                     33^-7
            TOTAL

-------
      Appendix A.2.3




  Raw Field Data, Kiln No. 2




CEMs Summary & Strip Charts

-------

-------
HCI Emission Measurements from Kiln No. 2
       Austin White Lime Company
             Austin, Texas
                7/1/98
Time

14:15-14:35
15:15-15:35
16:15-16:35
Date
Inlet/Outlet
HCI
ppm
THC
ppm
02
%

7/1/98


Outlet


Average
15 '-fit &"J*
14:45-^:05
15:45-16:05
16:45-17:05
7/1/98


Inlet


Average
1.5
1.3
1.3
1.4
0.0
0.2
0.0
0.1

2.6
2.5
2.4
2.5
0.0
0.0
0.0
0.0
10.3
10.4
10.3
10.3
CO2
%

16.2
15.9
16.1
16.1

10.7
10.7
9.7
10.4
15.5
15.5
16.4
15.8

-------
HCI Correction Worksheet
 Austin-White Lime Company
         Kiln #2
         1-July-98

         OUTLET
                                 -.*>
                                  s" •

^.fsife^j
Actual value
0
27.1
48.8
3 Point Cal
-0.6
26.4
47.8
slope (m) 0.992
Y-lntercept (b) -0.56
Avg cone: 1 .4
Actual Cone: 1.5
PreBias
-0.6
47.8
0.992
-0.60
Post Bias
-0.3
46.7
0.963
-0.30
          INLET
II Actual value
zero/. ^ 0.0
; Ufci&f , 27.1
.. >T' ' 48.8
3 Point Cal
0.0
25.6
47.4
slope (m) 0.970
Y-lntercept (b) -0.21
Avg cone: 2.5
Actual Cone: 3.0
Pre Bias
0.0
47.4
0.971
0.00
Post Bias
0.7
47.1
0.951
0.70

-------
- ID
                      5. o
                  ?e. &     ies. 0     i«ei. o      175. o      210. 0      245. e     280. e     315. 0      350. 0  PPM
                                                                                                                   98. 8      180. 8  PCT
                                                            :TS  flT  08 f 21: 49  ***  ENDS 'ftT |08 : 2(L :58 iJUC 61,96 ***
                                                                       JPT  MTll   UNITS  ST   !  LIGDO     IPT  MIT1   UNITS  5T , I   1CTM
                                                                       ;« ,8 i   PPIM     THC ,   !      '  W  J |    PPH,     1)0.
                                                              •   •
                                                        ! -    ' !        .    I
                                                        t!9:4|4  **t  ENDS I
                                                 ;***  STHRTS f)T  081
                                                                       i
                                                  UNITS  5T   I ~T»BD      I FT
                                          •** KS8T flVDWCE 88:18 M  24-11
                                                             23
                                          M* RBT RVEJWE 88:18:84  22 4
                                           »*• ttil (WRBGE «8:18.8B
      «*£
H*n  wrc ST   ,  IBM
.2  :   *       MX
                                                                       '  43.J©
           1      I           '               '         I                  L           I
01   i   ***  STRRTS  ftT  08'  16: 46 ***  ENDS IflT 188:16 : -46  JUL 61,98 ***i

                                                          ! ft  MTTJI  UNI ' '	L
                                                                            *X
                                                                                                                               39.
PT  MB;  IHITS  ST  .   :UCtO
                                                                                                                    6   PPM
82  .2    PCI
                 CP2
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-------
             APPENDIX B




METHOD 23 LABORATORY ANALYTICAL DATA

-------
                               LabData


               Summary of Method 23 Analytical Results
                     Air Emissions Screening Test
             Austin White Lime Company - Austin, Texas
               US EPA Test Method 23 - PCDDs / PCDFs
                Kiln # 3 Baghouse Inlet - Run M23-I-3
Congeners

DIOXINS:
2378 TCDD
Total TCDD
12378 PeCDD
Total PeCDD
123478 HxCDD
123678 HxCDD
123789 HxCDD
Total HxCDD
1234678 HpCDD
Total HpCDD
12346789 OCDD
OCDD+Totals PCDDs

Back Half

0.0021 '
0.0085
0.0006
0.0036
(0.0008)
{0.00156}
{0.00208}
0.0072
{0.00636}
0.0052
0.0186
0.0431
Catches, ng/sample
Front Half

{0.00099}
{0.003}
ND
ND
ND
ND
{0.00088}
0.0016
{0.00168}
0.0008
0.0051
{0.0105}
Total

{0.00309}
{0.0115}
0.0006
0.0036
(0.0008)
{0.00156}
{0.00296}
0.0088
{0.00804}
0.0060
0.0237
{0.0536}

FURANS:
2378 TCDF
Total TCDF
12378PeCDF
23478 PeCDF
Total PeCDF
123478 HxCDF
123678 HxCDF
234678 HxCDF
123789 HxCDF
Total HxCDF
1234678 HpCDF
1 234789 HpCDF
Total HpCDF
12346789 OCDF
OCDF+Totals PCDFs
Total of Totals
0.0061
0.0632
0.0023
ND
0.0100
0.0026
{0.00104}
(0.0004)
(0.0004)
0.0044
0.0043
(0.0006)
0.0044
0.0036
0.0856
0.1287
{0.00124}
{0.001}
ND
{0.00064}
{0.001}
{0.0008}
{0.00032}
ND
ND
{0.001}
0.0006
ND
0.0008
ND
{0.0038}
{0.0143}

{0.00734}
{0.0642}
0.0023
{0.00064}
{0.0110}
{0.00340}
{0.00136}
(0.0004)
(0.0004)
{0.0054}
0.0049
(0.0006)
0.0052
0.0036
{0.0894}
{0.1430}
ND Not Detected. When both fractions are ND, the greater detection limit is used
    and is enclosed in parentheses ( ); otherwise, ND's are zero in calculating totals.
{}  Estimated Maximum Possible Concentration. EMPC values are included in totals.

-------
                             LabData

             Summary of Method 23 Analytical Results
                   Air Emissions Screening Test
            Austin White Lime Company - Austin, Texas
             US EPA Test Method 23 - PCDDs / PCDFs
               Kiln # 2 Scrubber Inlet - Run M23-I-4
Congeners

DIOXINS:
2378 TCDD
Total TCDD
12378 PeCDD
Total PeCDD
1 23478 HxCDD
123678 HxCDD
123789 HxCDD
Total HxCDD
1234678 HpCDD
Total HpCDD
12346789 OCDD
OCDD+Totals PCDDs
Catches, ng/sample
Back Half

0.0012
0.0088
{0.0004}
0.0004
ND
{0.00076}
{0.00116}
0.0076
0.0050
0.0096
0.0146
0.0410
Front Half

{0.00108}
0.0012
ND
{0.002}
(0.0007)
ND
{0.00108}
0.0056
0.0018
0.0016
0.0046
{0.0150}
Total -
-
{0.00228}
0.0100
{0.0004}
{0.0024}
(0.0007)
{0.00076}
{0.00224}
0.0132
0.0068
0.0112
0.0192
{0.0560}

FURANS:
2378 TCDF
Total TCDF
12378 PeCDF
23478 PeCDF
Total PeCDF
123478 HxCDF
123678 HxCDF
234678 HxCDF
123789 HxCDF
Total HxCDF
1234678 HpCDF
1234789 HpCDF
Total HpCDF
12346789 OCDF
OCDF+Totals PCDFs
Total of Totals
0.0106
0.1468
0.0022
{0.00192}
0.0156
{0.00168}
{0.00076}
{0.00076}
(0.0005)
0.0032
0.0035
(0.0009)
0.0036
{0.00248}
{0.17168}
{0.21268}
0.0126
0.0948
{0.0044}
0.0052
0.028
0.0024
{0.00084}
ND
ND
0.004
0.0012
ND
0.0012
ND
0.1280
{0.1430}

0.0232
0.2416
{0.0066}
{0.00712}
0.0436
{0.00408}
{0.00160}
{0.00076}
(0.0005)
0.0072
0.0047
(0.0009)
0.0048
{0.00248}
{0.2997}
{0.3557}
ND Not Detected. When both fractions are ND, the greater detection limit is used
    and is enclosed in parentheses (); otherwise, ND's are zero in calculating totals.
{}  Estimated Maximum Possible Concentration. EMPC values are included in totals.
                                                                      oooL

-------
                  PARADIGM ANALYTICAL LABORATORIES, INC.
                              2627 Northchase Parkway S.E.
                           Wilmington, North Carolina  28405
                                      (910) 350-1903
                                   Fax (910) 350-1557
24 July 1998
Michael Maret
Pacific Environmental Services, Inc.
5001 S. Miami Blvd
Research Triangle Park, NC 27709-2077

Contract.          68D70002
Sub-Contract:       RO12-002
Work Assignment   1-007

Subject: Polychlorinated Dibenzo-p-Dioxins & Dibenzofurans Measurements (PAL Project No. L-1072)

Dear Mike;

        Enclosed are the final results for the flue gas samples under your Project RO 12.003 Texas Lime
Kiln.  The analytical procedures conformed or exceeded the ones described in Method 23 using isotope-
dilution high-resolution gas chromatography combined with high-resolution mass spectrometry. The Level
II reporting format is described on the next page. A general summary of the analytical results is presented
in Table 1.  Tables 2 and 3 from Project L-l070 cover letter summarize the results for the front-halve of
the four inlet samples, expressed in absolute amount "ng" per sample, and in relative concentrations "part-
per-trillion". Figures land 2 show the TEQs and total homologues corresponding to Table 1 data.

        No. of  Samples Received:         6
        No. of Samples Analyzed:         8
        No. of Lab. Method Blanks:       1

        Your Project Number:          R012.003 Texas Lime Kiln
        PAL Project No.:               L-1072

        Remarks:
                •    Data meet QA/QC requirements.
                •    The FH of samples M23-I-3 and M23-I-4 contained 12.86 g and 29.63 g of dust, respectively. Both
                    FHs were processed as separate samples. The results are reported in two ways (see Tables 2 & 3
                    from PAL L-1070):
                        a) Absolute amount in "ng" per sample,
                        b) Relative concentration in parts-per-trillion (ppt) based on the weight of dust.
                •    No analytical difficulties to be reported.
        We wanted to thank you for the opportunity to serve you. Please, feel free to contact us if you
 have questions or should you need additional technical support.

 Sincerely,


 fves Tondeur, Ph.D.
                                                                                                     001
                      North Carolina Wastewater Certification #481

-------
                             Level II Report

Section 1: Cover Letter, contains a brief description of the project, the client and
         PAL Project Numbers, the number and type of samples, the
         methodology used to process the samples, QC remarks where any
         analytical difficulties are discussed and the impact on the quality of the
         data presented, a summary table with the analyte concentnion,
         detection limits, the client sample identification numbers, units to report
         the concentrations, and a graphical representation of the TEQs and
         totals.

Section 2: Project Synopsis, contains the Sample Tracking & Management
         Forms, Communications Form, any correspondence, chain-of-custody
         and the last page is always a copy of the sample injection log(s). This
         section is designed to help the laboratory and the data reviewer with an
         overall view of the entire analytical procedure, the initials and dates of
         who did what when on which sample.  Spiking solution IDs are
         recorded along with the batch numbers of the supplies and reagents
         used.

Section 3: Analytical Results, contains the sample results topsheets (one set of
         two per sample), the raw data (i.e., the selected ion current profiles, the
         areas, heights, ion abundance ratios, signal-to-noise ratios, and
         retention times of the GC peaks).

Section 4: System Performance, contains  the documentation on the GC/MS
         system performance. In particular, the mass resolution checks, GC
         column performance checks, initial and continuing calibration summary
         tables and, when applicable, associated raw data for both column types.
                                                                         C<   OO2

-------
Table 1: Analyte Concentrations in "ng" per Sampling Train
                   [ of the inlet sample shown in Tables 2 and 3 fromPAL L-1070
1,2,3,7,8-PeCDD
1,2,3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
1,2,3,4,6,7,8-HpCDD
OCDD
2,3,7,8-TCDF'
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
1,2,3,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
OCDF
Total TCDDs
Total PeCDDs
Total HxCDDs
Total HpCDDs
Total TCDFs
Total PeCDFs
Total HxCDFs
Total HpCDFs
Total PCDD/Fsb
TEQ (ND=0)C
TEQ(ND=l/2)d
TEQ EMPC(ND=0)*
TEQ EMPC (ND= 1/2)
(0.0004)
(0.0004)
(0.0003)
[0.00116]
0.0029
0.0141
0.0015
(0.0007)
(0.0007)
[0.00096]
0.0006
(0.0005)
(0.0006)
[0.00168]
(0.0010)
(0.0009)
[0.001]
(0.0004)
0.0012
0.0052
0.0016
(0.0007)
0.0008
[0.002]
0.0229
0.0003
0.0009
0.0015
0.0018
0.0006
(0.0008)
[0.00156]
[0.00208]
[0.00636]
0.0186
0.0061
0.0023
(0.0005)
0.0026
[0.00104]
(0.0004)
(0.0004)
0.0043
(0.0006)
0.0036
0.0085
0.0036
0.0072
0.0052
0.0632
0.0100
0.0044
0.0044
0.1287
0.0034
0.0037
0.0040
0.0042
0.0006
(0.0004)
0.0014
[0.00196]
0.0045
0.0167
0.0054
0.0038
[0.0024]
0.0033
[0.00168]
[0.00116]
(0.0005)
0.0063
[0.00112]
0.0092
0.0119
0.0056
0.0076
0.0088
0.1428
0.0312
0.0104
0.0076
0.2518
0.0030
0.0030
0.0050
0.0050
[0.00072]
(0.0006)
0.0011
[0.00112]
0.0043
0.0136
0.0016
(0.0004)
(0.0004)
0.0013
[0.0008]
[0.00068]
(0.0004)
0.0061
(0.0008)
[0.00468]
0.0022
0.0012
0.0040
0.0084
0.0024
0.0024
0.0028
0.0060
0.0429
0.0010
0.0020
0.0020
0.0020
[0.0004]
{0.0006)
[0.00076]
[0.00116]
0.0050
0.0146
0.0106
0.0022
[0.00192]
[0.00168]
[0.00076]
[0.00076]
(0.0005)
0.0035
(0.0009)
[0.00248]
0.0088
0.0004
0.0076
0.0096
0.1468
0.0156
0.0032
0.0036
0.2102
0.0020
0.0030
0.0040
0.0040
[0.00064]
(0.0009)
[0.00132]
[0.00128]
0.0080
0.0218
0.0301
0.0077
0.0074
0.0032
0.0016
[0.00088]
(0.0004)
0.0056
(0.0007)
0.0052
0.0101
0.0020
0.0088
0.0172
0.2964
0.0592
0.0108
0.0056
0.4371
0.0091
0.0093
0.0097
0.0098
[0.00044]
(0.0006)
[0.00072]
[0.0012]
[0.00268]
[0.0076]
(0.0007)
(0.0004)
(0.0004)
[0.0008]
(0.0002)
(0.0003)
(0.0003)
0.0026
(0.0007)
[0.00148]
[0.0006]
[0.0012]
[0.006]
[0.0064]
(0.0007)
(0.0004)
[0.0012]
0.0028
0.0028
0.0000
0.0006
0.0012
0.0014
a) Result obtained from the DB-225 analysis.
b) Total PCDD/Fs represent the sum of all polychlorinated dibenzo-p-dioxins & dibenzofurans.
c) TEQ computed using ITEF and setting non detected analytes with a "Zero" concentration.
d) TEQ computed using ITEF and setting non detected analytes with a concentration half the
   calculated detection limit.
e) TEQ computed using ITEF and setting the concentration of EMPC analytes to the EMPC value.
NOTE:
        () = ND using DL value.
        [] = EMPC value.
                                      06 AUG 98 Revision

-------
Table 2: Analyte Concentrations in "ng" per Front-Half Sampling Train (Le., fiber and dust) for all runs.
gjjiliii^SBffiHJ^BB
,3,-7,8-TCDD
1,2,3,7,8-PeCDD
1,2,3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
1,2,3,4,6,7,8-HpCDD
OCDD
2,3,7,8-TCDF*
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
1,2,3,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
OCDF
Total TCDDs
Total PeCDDs
Total HxCDDs
Total HpCDDs
Total TCDFs
Total PeCDFs
Total HxCDFs
Total HpCDFs
Total PCDD/Fs"
TEQ (ND=0)e
TEQ (ND=l/2)d
TEQ EMPC(ND=0)e
TEQ EMPC (ND-1/2)
^•^•••KaiHliHM
^^^^^^^^^H^Uu^^^^H^D^U
^^^^^^^KE&^^^^^^B
[0.0025]
[0.0034]
0.0028
[0.00536]
0.0072
0.0208
0.0200
0.0184
0.0198
0.0240
0.0323
0.0132
0.0114
0.0031
0.0215
[0.00232]
[0.00308]
0.1092
0.0744
0.1384
0.0376
0.6276
0.3208
0.1076
0.0244
1.4600
0.0220
0.0230
0.0270
0.0270
1H
[0.001561
(0.0003)
(0.0007)
0.0010
0.0016
0.0028
0.0060
0.0180
0.0184
0.0124
0.0102
0.0066
[0.00376]
(0.0008)
0.0061
[0.00176]
(0.0008)
0.0348
0.0060
0.0024
0.0028
0.3548
0.1644
0.0348
0.0092
0.6152
0.0110
0.0110
0.0130
0.0130
^
[0.00099]
(0.0003)
(0.0005)
(0.0004)
[0.00088] -•
[0.00168]
0.0051
[0.00124]
(0.0004)
[0.00064]
[0.0008]
[0.00032]
(0.0003)
(0.0003)
0.0006
(0.0006)
(0.0006)
[0.003]
(0.0003)
0.0016
0.0008
[0.001]
[0.001]
[0.001]
0.0008
0.0083
0.0000
0.0010
0.0020
0.0020
[0.00108]
(0.0004)
(0.0007)
(0.0005)
-*--«M«ll
0.0011
0.0046
0.0126
[0.0044]
0.0052
0.0024
[0.00084]
(0.0004)
(0.0004)
0.0012
(0.0006)
(0.0008)
0.0012
[0.002]
0.0056
0.0016
0.0948
0.0280
0.0040
0.0012
0.1410
0.0040
0.0050
0.0060
0.0060
a) Result obtained from the DB-225 analysis.
b) Total PCDD/Fs represent the sum of all polychlorinated dibenzo-p-dioxins & dibenzofurans.
c) TEQ computed using ITEF and setting non detected analytes with a "Zero" concentration.
d) TEQ computed using ITEF and setting non detected analytes with a concentration half the
   calculated detection limit
e) TEQ computed using ITEF and setting the concentration of EMPC analytes to the EMPC value.
NOTE;
        () = ND using DL value.
            EMPC value.
                                        06 AUG 98 Revision

-------
 Table 3: Analyte Concentrations in "parts-per-trillion" for die Front-Half Sampling Trains (Le., filler and
                                            dust).
*>:££gg&gsHK«^^H
^ ^"?;^l^[g8B8BB8BagiEB^B
2,3,7,8-TCDD
1,2,3,7,8-PeCDD
1,2,3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
1,2,3,4,6,7,8-HpCDD
OCDD
2,3,7,8-TCDF*
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
1,2,3,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
OCDF
Total TCDDs
Total PeCDDs
Total HxCDDs
Total HpCDDs
Total TCDFs
Total PeCDFs
Total HxCDFs
Total HpCDFs
Total PCDD/Fsb
TEQ (ND=0)C
TEQ (ND=l/2)d
TEQ EMPC(ND=0)C
TEQ EMPC (ND=l/2)
^••HgggKSnBKflBjB
[0.16055]
[0.21809]
0.180
[0.34381]
0.464
1.332
1280
1.178
1.270
1.539
2.073
0.849
0.731
0.198
1.380
[0.14881]
[0.19756]
7.004
4.772
8.877
2.412
40.257
20.577
6.902
1.565
93.647
1.429
1.457
1.735
1.735
^^^^^^^^^B
[0.04808]
(0.009)
(0.021)
0.030
0.049
0.085
0.186
0.553
0.568
0.382
0.314
0.204
[0.11576]
(0.024)
0.187
[0.05419]
(0.026)
1.071
0.185
0.074
0.086
10.924
5.062
1.071
0.283
18.942
0.337
0.352
0.397
0.402
[0.07707]
(0.026)
(0.038)
(0.027)
[0.06843]
[0.13064]
0395
[0.09642]
(0.031)
[0.04977]
[0.06221]
[0.02488]
(0.021)
(0.025)
0.050
(0.049)
(0.045)
[0.249]
(0.026)
0.124
0.062
[0.093]
[0.062]
[0.093]
0.062
0.644
0.001
0.042
0.129
0.142
[0.03639]
(0.014)
(0.023)
(0.016)
[0.03645]
0.059
0.154
0.424
[0.1485]
0.176
0.080
[0.02835]
(0.013)
(0.015)
0.042
(0.020)
(0.025)
0.041
[0.054]
0.189
0.054
3.199
0.945
0.135
0.041
4.757
0.139
0.156
0.190
0.197
a) Result obtained from the DB-225 analysis.
b) Total PCDD/Fs represent the sum of all polychlorinated dibenzo-p-dioxins & dibenzofurans.
c) TEQ computed using ITEF and setting non detected analytes with a "Zero" concentration.
d) TEQ computed using ITEF and setting non detected analytes with a concentration half the
   calculated detection limit
e) TEQ computed using ITEF and setting the concentration of EMPC analytes to the EMPC value.
NOTE:
        () = ND using DL vahie.
        [ ] = EMPC value.
                                           06 AUG 98 Revision

-------
                                          TEQ
                                                              0.0098
00000
                                                                                 TEQ (ND=0)
                                                                                HTEQ (ND=1/2)
                                                                                HTEQ EMPC (ND=0)
                                                                                DTEQEMPC(ND=1/2)
          1MB      M23-I-3     M23-0-3   M23-FB-3    M24-M
                                Amount in "ng" per Train
M24-O-4    M24-FB-4
                         Figure 1: Graphical representation of the TEQs
                                                                                                   OO4

-------
                                            Total Homologues
      04500 -r
      0.4000 -
      03500 -
      0.3000
      0.2500 -
Sample
      0.2000 -
       01500 -
       0 1000
       0 0500 -
       00000
                  1MB         M23-I-3       M23-O-3      M23-FB-3       M24-I-4
                                                Amount in "rig" per Train
                                                                                M24-0-4
                                                                                            M24-FB-4
             Figure 2: Graphical representation of the totals (terra- through octachlorinated congeners)
                                                                                                                 OC5

-------
            PAL Project No.: L-1072
                                     ! Ro (Z - 002,
                Section 2
            Project Overview
                   &
Sample Tracking & Communication Forms

-------
     Projec  Jverview for the Analysis of Polychlo,  ^ated Dibenzo-/?-Dioxins & Dibenzofu
    No. of Field Samples:   _°
    No. of Billable Samples:  6_
                          PAL Project No.:   L-1072
o
 •v
O
                Probe Rinse
              Concentration
            SOPSP-N-02
        ES:   23
        SS:   23
        JS:   23
4ng(l-2)
4ng(l-l)
        Tridecane batch No.
        Thimbles batch No.:
        Toluene batch No.:
        Pre-Soxhlet:
        Oth«s:
                                     Date Received:   08 JUL 98
                                     Due Date:        29 JUL 98
                                     Client Project ID: R012.003 TX
                                     LIME KILN
                                                                           MethM23
                                                                                         XAD
                                                                         Sampling Modules Prep. Project No.: Z.~~
 Add M23-ES-rtw,-SOtrfn>
Vol.: 40 n L;  Cone.: 0.1 ng/ \i L
                                                                            SOPSP-S-01
                                                 Soxhlet 16 H Toluene
                                                      SOPSP-E-01
                         Concentration & Solvent Exchange]  SOPSP-N-OI
                                         I
                                                     Split Extract
                                                   SOPSP-D-01
                                            Hexane batch No.:
                                            CH,a, batch No.:

                                            Silica batch No.:
                                            Alumina batch No.:
                                            PCU-F batch No.:
                                            Na,SO4 batch No.:
                                SOPSP-D-01
      Special Instructions:
                                                                                                       SOPSP^U-03
                                                                                       Concentration I  SOPSP-N-OI
                                                                                            I
                                                               Add M23-JS-07/?*r~S0t- ///
                                                              Vol.: 20 n L;   Cone.: 0.1 ng/ n L
                                                                                                           SOPSP-S-Ol
                                                                     HRGC - HRMS

-------
 Project Overview for the Analysis of Polychlorinated Dibenzo-p-Dioxins & Dlbenzofurans
No. of Field Samples:   J?
No. of Billable Samples:
   Special Instructions:
PAL Project No.:   L-1072
    Date Received:   08 JUL 98
    Due Date:        29 JUL 98
    Client Project ID: R012.003TX
    LIME KILN
                                          '*  ^fethod 2B
                                             SOPSP-A-OI
                                          Sample Extract
                                          Fortified with JS
Reporting Level:
                                                ra
                                                                                           ra+
1
8A.M.
r
MS
^
	 w

GC
k.
	 PI

Calibration
w

8P.M.

B

laiiK ~ oampies ~ ixOm^ai

fc Tfl
~ 1VJ
                                                     SOPRP-G-01
                                          Data Package
                                            Assembly
                   SOPSH-A-01
                                        Instrument ID!
                                        HP-5MS batch No.:
                                        DB225 batch No.:
                                        ICal:      *»
                                  Archive Data
                  Ship Data
                                   SOPRP-A-01
                                                       SOPSH-D-01

-------
Sampk , racking for the Analysis of Polychloi. uted Dibenzo-/?-Dioxins & Dibenzofu.  *s
No. of Field Samples:  v
Page / of
                               PAL Project No.:  L-1072
Date Received:   08 JUL 98
Due Date:       29 JUL 98
Client Project ID: R012.003 TX
LIME KILN

-------
Communication Exchanges Form for the Analysis of PCDD/PCDFs
No. of Field Samples:
                   PAL Project No.: L-1072
Date Received:  08 JUL 98
Due Date:      29 JUL 98
Client Project ID: R012.003 TX
LIMEKILN
          ^

                                                                             ':!

-------
Contract No.:           68D70002
Subcontract No.:        R01 2-002
Work Assignment:      1-007

08 July 1998

Michael Maret
Pacific Environmental Services, Inc.
500 IS. Miami Blvd
P.O. Box 12077
Research Triangle Park, NC 27709-2077

Reference:  Project No. R012.003; Project Name: US EPA'Lime Kiln Screening, Texas Lime

Subject: Inlet Samples Heavy Particulate Load

Dear Mike:

        The thirteen Method 23 samples were received in good condition and no discrepancies were noted
between the sample labels and the chain-of-custody. As we discussed, we organized the samples into three
separate projects, each assigned a specific PAL Project No.  Table 1 summarizes the sample identification
and their associated PAL Project Nos.

        The object of this letter is to bring to your attention the following concerns. Following a
description of the issues, possible solutions are discussed for your consideration.

        The issue pertains to the "inlet" samples. Each of the four inlet samples shows relatively high
levels of dust (particulates). Depending on the sample, we estimated the amount of solids to range from
10 g to 35 g.

        The first concern is a practical one.  Indeed, the capacity of a normal Soxhlet extraction set up is
exceeded if we want to combine the front- and back-halves of the sampling train (FH & BH). Two separate
extractions  would be required for each of the inlet samples.  This leads to the following two options:

        1 .   Combine the two extracts and process the FH and BH as a single sample.
            >   The question remains as to where the Method 23 internal standards are added.

        2.   Treat the FH and BH as two separate samples.
            >   Each sample receives a normal dose of Method 23 internal standards before the extraction.
            >   This option resembles Method 0023A's and results in four additional samples.

        The second concern is related to generating "meaningful" results for your client's study.
Reporting PCDD/F results in "ng /dscm" in the flue gas in such circumstances — where participate levels
are so high — may be  of no value to your client. We recommend Option 2 above and propose to report the
analytical results for the inlet samples in two ways:  a) absolute amount (e.g., ng per FH) of the PCDD/Fs
and, b) relative concentrations of PCDD/Fs expressed in parts-per-trillion (ppt) or picogram per gram of
"dust" recovered in the inlet sample. Note that mis approach can only be achieved if Option 2 is selected,
which amounts to treating the inlet FH as a sok'd sample rather than as a flue gas sample.

        Please, let us know if you have questions and we are waiting for a decision on how you would like
us to handle these particular inlet samples. I  can be reached at 910-350-2839.

Sincerely,
                                              4o
[
  Vendeur,Ph.D.          A*u*

                                      &Sdcf   Jubt+~k*.Jr   it   +A  X»  ">**i   ?*
                                                                                                '     Old

-------
       Table 1: Project No. R012.003; Project Name: US EPA Lime Kiln Screening, Texas Lime;
                              Sample and Project Identification.
       PES SampleiID     	PAL Sample ID	PAL Project No.
M23-I-1
M23-O-1
M23-FB-1
M23-RB
1070-1
; 1070-2
1070-3
1070-4
j L-1070 i
i L-1070
L-1070
L-1070
M23-I-2                       1071-1                        L-1071
M23-O-2                _   _107W	L-1071
M23-FB-2"	        ~  1071-3  ~    "  "    "~         L-1071
M23-I-3                       1072-1                        L-1072
M23-O-3                       1072-2   "                 ~ ~ L-~1072
M23-FB-3                    '  1072-3        '               1^1072'
M23-I-4                       1072-4        _         ___    L-1072
M23-O-4                      1072-5     	
M23-FB-4                     1072-6                        L-1072
                                                                                             012

-------
PACIFIC ENVIRONMENTAL
INC.
                           Central Park West
     5001 South Miami Boulevard, P.O. Box 12077
Research Triangle Park, North Carolina 27709-2077
           (919) 941-0333 FAX: (919) 941-0234
                                                 Chain of Custody Record
R012.003 I US EPA Ume Kiln Screening - Texas Lime

Date
6/25/98
6/28/98
6/28/98
6/28/98
6/28/98
6/30/98
6/30/98
6/30/98
6/30/98
7/1/98
7/1/98
7/1/98
7/1/98
6/25/98
6/25/98
6/25/98
6/25/98
6/27/98
6/27/98
Abwnathy. Gay. Maret, D.D Holzschuh. Siegal. Stewart
Time
1518
1033
1033
1033
1033
1247
1247
1247
1247
1414
1414
1414
1414






Field Sample 10
M23-O-1-4
M23-O-2-1
M23-O-2-2
M23-O-2-3
M23-O-2-4
M23-O-3-1
M23-O-3-2
M23-O-3-3
M23-O-3-4
M23-O-4-1
M23-O-4-2
M23-O-4-3
M23-0-4-4
M23-FB-1-1
M23-FB-1-2
M23-FB-1-3
M23-FB-1-4
M23-FB-2-1
M23-FB-2-2
Sample Description
Container No. 4 - XAD Sorbent Resin
Container No. 1 - Filter
Container No. 2 - Train Acetone Rinse
Container No. 3 - Train Toluene Rinse
Container No. 4 - XAD Sorbent Resin
Container No. 1 - Filter
Container No. 2 - Train Acetone Rinse
Container No. 3 - Train Toluene Rinse
Container No. 4 - XAD Sorbent Resin
Container No. 1 - Filter
Container No. 2 - Train Acetone Rinse
Container No. 3 - Train Toluene Rinse
Container No. 4 - XAD Sorbent Resin
Container No. 1 - Filter
Container No. 2 - Train Acetone Rinse
Container No. 3 - Train Toluene Rinse
Container No. 4 - XAD Sorbent Resin
Container No. 1 - Filter
Container No. 2 - Train Acetone Rinse
Analysis Requested

•
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•
•
•
•
•
•
•
•
•
•
•
•
•
•
•
•

•
•
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*
*
* '
*
•
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•
*
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Remarks
/*¥&-£
i*?/~l
/'zi-1-
/aXi^*'
Irtt'^
loll- 1
I»>Z- 2.
/o*2-t
10^-1-
/+^2.~£~
/' *2-JT
/'*2-r~
/e?2-f
FIELD BLANK 1 JOK>^3
FIELD BLANK 1 /0% ~J
FIELD BLANK 1 y^b~^
FIELD BLANK 1 ff&o-l
FIELD BLANK 2 /*>/~_l
FIELD BLANK 2 /"?/-3
   7/7/98
                                                                                                              Page 2 of 3 Pages

-------
                                                                13
PACfFIC ENVIRONMENTAL SERVICES. INC.
                           Central Park West
     5001 South Miami Boulevard, P.O. Box 12077
Research Triangle Park, North Carolina 27709-2077
           (919) 941-0333 FAX: (919) 941-0234
Chain of Custody Record
R012.003 I US EPA Lime Kiln Screening -Texas Lime

Date
6/25/98
6/25/98
5/25/98
•8/25/08
i6/28/08
,6/28/98
16/28/98
16/28/98
6/30/98
6/3008
6/3Q08
6/3008
7/J08
7/J08
7/108
7/1/08
8/2808
i 80008
Abemathy. Gay, Marat, D.D Holrschuh, Slegal, Stewart
Time
1518
1518
1518
1518
1033
1033
1033
1033
1247
1247
1247
1247
1414
1414
1414
1414
1518
1518
• MI i^aini
Field Sample ID
M23-I-1-1
M23-I-1-2
M23-M-3
M23-I-1-4
M23-I-2-1
M23-I-2-2
M23-I-2-3
M23-I-2-4
M23-I-3-1
M23-I-3-2
M23-I-3-3
M23-I-3-4
M23-I-4-1
M23-I-4-2
M23-I-4-3
M23-I-4-4
M23-O-1-1
M23-O-1-2
M23-O-1-3
Sample Description
Container No. 1 - Filter
Container No. 2 - Train Acetone Rinse
Container No. 3 - Train Toluene Rinse
Container No. 4 - XAD Sorbent Resin
Container No. 1 - Filter
Container No. 2 - Train Acetone Rinse
Container No. 3 - Train Toluene Rinse
Container No. 4 - XAD Sorbent Resin
Container No. 1 - Filter
Container No. 2 - Train Acetone Rinse
Container No. 3 - Train Toluene Rinse
Container No. 4 - XAD Sorbent Resin
Container No. 1 - Filter
Container No. 2 - Train Acetone Rinse
Container No. 3 - Train Toluene Rinse
Container No. 4 - XAD Sorbent Resin
Container No. 1 - Filter
Container No. 2 - Train Acetone Rinse
Container No. 3 - Train Toluene Rinse
Analysis Requested

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•i




Remarks
L -/*>?& t*je>-l
/04o~l
/*•)•• f
//&0-I
c- ~(03"i /jy&/~-J
/0^/~t

/ffi&S'l
y —/ & ~"}"JL j0"&3. ~t
/0Z2-I
J0V2-J
J0$2*-I
tbtt'V
fo}2~*f
/*}£**?
/*>£-<*
/0^"0 •*" %-
/09O- -2-
/*«*?- 2-
                                                                                                              Page 1 of 3 Pages

-------
PACIFIC ENVIRONMENTAL SERVICES. INC.
                          Central Park West
     5001 South Miami Boulevard, P.O. Box 12077
Research Triangle Park, North Carolina 27709-2077
           (919) 941-0333 FAX: (919) 941-0234
                                                Chain of Custody Record
ict Num [Project Name
R012.003 |
US EPA Lime Kiln Screening - Texas Lime
piers: •
Abemathy, Gay. Marat. D.D Hobschuh. Stegal, Stewart
Date
3/27/98
5/27/98
6/30/98
6/30/98
6/30/98
6/30/98
7/1/98
7/1/98
7/1/98
7/1/98
7/7/98
7/7/98
7/7/98
7/7/98
Time














Field Sample ID
M23-FB-2-3
M23-FB-2-4
M23-FB-3-1
M23-FB-3-2
M23-FB-3-3
M23-FB-3-4
M23-FB-4-1
M23-FB-4-2
M23-FB-4-3
M23-FB-4-4
M23-RB-1
M23-RB-2
M23-RB-3
M23-RB-4
Inqutehed by: (Signature)
-^SLfJ/ftf fiWfer

Date/Time
Date/Time
ildfteP

Sample Description
Container No. 3 - Train Toluene Rinse
Container No. 4 - XAD Sorbent Resin
Container No. 1 - Filter
Container No. 2 - Train Acetone Rinse
Container No. 3 - Train Toluene Rinse
Container No. 4 - XAD Sorbent Resin
Container No. 1 - Filter
Container No. 2 - Train Acetone Rinse
Container No. 3 - Train Toluene Rinse
Container No. 4 - XAD Sorbent Resin
Container No. 1 - Filter
Container No. 2 - Train Acetone Rinse
Container No. 3 - Train Toluene Rinse
Container No. 4 - XAD Sorbent Resin
Received by: (Signature)
Received for lab by: (Signature)
J_^^^— «^a_^ —-*
^F^S^r^bt^f- "OB-IW.W
Analysis Requested

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•
•
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•
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•
•
•
•

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•
•
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•
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•
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«
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Relinquished by: (Signature)






























Date/Tim*
Remarks
FIELD BLANK 2 fo?/~3
FIELD BLANK 2 /03/~l
FIELD BLANK 3 /^92-_?
FIELD BLANK 3 /<^2-J
FIELD BLANK 3 /*^2~J
FIELD BLANK 3 /*}ZrJ
FIELD BLANK 4 /^7/-d"
FIELD BLANK 4 /0jj-/
REAGENT BLANK ^&~ ^
Received by: (Signature)
f '
REMARKS
   7/7/98
                                                                                                            Page 3 of 3 Pages

-------
               Preparation of the XAD-2 Resin for Method 23 Sampling Session
No. Sampling Modules:  15
No. Filters:             25
PAL Project No.:   L-1043
                                                 PES.
Order Received:  04 JUN 98
Due Date:       22 JUN 98
Client Project ID: TX Lime Kilns
P.O. No.:
Ph.:        (512J-693-5122
To ensure proper handling of the samples, please return this form with the field samples to:
                                       Paradigm Analytical Labs
                                       2627 Northchase Pkwy S.E.
                                        Wilmington, NC 28405
                 Thank you for your cooperation. Our phone number is 910-350-2839. (Fax: 910-350-1557)
                                                               __
                                                                ••




fling Address: Best western
Attn.: Mike Maret
1403 Hiway 281 N
Marble Falls, TX 78654-4505
Ph.:(512)693-5122
icial Instruction^;




                                                                      Filters
                                                                           No.:
                                                                      Size:

                                                                      Type:
                                           83 mm diameter
                                          ^
                                          JSlass FiberJ  Quartz
                                                                     XAD-2 Resin Modules
                                                                                     /A 3-7
  Note: An mwuni of resin equ»l to one module was fortified as
    described above, retained by the laboratory and kept at 4«C.
    Upon return of the field samples, this aliquot will be
    used to process the Laboratory Method I
           T sample.
                                Batch No.:
                                Type: Ball/Sock* (fS-Rlng Ball/Sociceh) Screw Cap

                                Add  M2-
                                Vol.: 40 M L ;  Cone.: 0.1 ng/ M L
                                Preparation Date:
                                [Two-week holding time]

                                Analyst:

-------
                               LabData

              Summary of Method 23 Analytical Results
                     Air Emissions Screening Test
             Austin White Lime Company - Austin, Texas
              US EPA Test Method 23 - PCDDs / PCDFs
                Kiln # 3 Baghouse Inlet - Run M23-I-3
Congeners

DIOXINS:
2378 TCDD
Total TCDD
12378 PeCDD
Total PeCDD
123478 HxCDD
123678 HxCDD
123789 HxCDD
Total HxCDD
1234678 HpCDD
Total HpCDD
12346789 OCDD
OCDD+Totals PCDDs

Back Half

0.0021
0.0085
0.0006
0.0036
(0.0008)
{0.00156}
{0.00208}
0.0072
{0.00636}
0.0052
0.0186
0.0431
Catches, ng/sample
Front Half

{0.00099}
{0.003}
ND
ND
ND
ND
{0.00088}
0.0016
{0.00168}
0.0008
0.0051
{0.0105}
Total

{0.00309}
{0.0115}
0.0006
0.0036
(0.0008)
{0.00156}
{0.00296}
0.0088
{0.00804}
0.0060
0.0237
{0.0536}

FURANS:
2378 TCDF
Total TCDF
12378 PeCDF
23478 PeCDF
Total PeCDF
1 23478 HxCDF
123678 HxCDF
234678 HxCDF
123789 HxCDF
Total HxCDF
1234678 HpCDF
1 234789 HpCDF
Total HpCDF
12346789 OCDF
OCDF+Totals PCDFs
Total of Totals
0.0061
0.0632
0.0023
ND
0.0100
0.0026
{0.00104}
(0.0004)
(0.0004)
0.0044
0.0043
(0.0006)
0.0044
0.0036
0.0856
0.1287
{0.00124}
{0.001}
ND
{0.00064}
{0.001}
{0.0008}
{0.00032}
ND
ND
{0.001}
0.0006
ND
0.0008
ND
{0.0038}
{0.0143}

{0.00734}
{0.0642}
0.0023
{0.00064}
{0.0110}
{0.00340}
{0.00136}
(0.0004)
(0.0004)
{0.0054}
0.0049
(0.0006)
0.0052
0.0036
{0.0894}
{0.1430}
ND Not Detected. When both fractions are ND, the greater detection limit is used
    and is enclosed in parentheses ( ); otherwise, ND's are zero in calculating totals.
{ }  Estimated Maximum Possible Concentration. EMPC values are included in totals.

-------
                             LabData
              Summary of Method 23 Analytical Results
                    Air Emissions Screening Test
            Austin White Lime Company - Austin, Texas
              US EPA Test Method 23 - PCDDs / PCDFs
                Kiln # 2 Scrubber Inlet - Run M23-I-4
Congeners

DIOXINS:
2378 TCDD
Total TCDD
12378 PeCDD
Total PeCDD
123478 HxCDD
123678 HxCDD
123789 HxCDD
Total HxCDD
1234678 HpCDD
Total HpCDD
12346789 OCDD
OCDD+Totals PCDDs
Catches, ng/sample
Back Half

0.0012
0.0088
{0.0004}
0.0004
ND
{0.00076}
{0.00116}
0.0076
0.0050
0.0096
0.0146
0.0410
Front Half

{0.00108}
0.0012
ND
{0.002}
(0.0007)
ND
{0.00108}
0.0056
0.0018
0.0016
0.0046
{0.0150}
Total

{0.00228}
0.0100
{0.0004}
{0.0024}
(0.0007)
{0.00076}
{0.00224}
0.0132
0.0068
0.0112
0.0192
{0.0560}

FURANS:
2378 TCDF
Total TCDF
12378 PeCDF
23478 PeCDF
Total PeCDF
123478 HxCDF
123678 HxCDF
234678 HxCDF
123789 HxCDF
Total HxCDF
1234678 HpCDF
1234789 HpCDF
Total HpCDF
12346789 OCDF
OCDF+Totals PCDFs
Total of Totals
0.0106
0.1468
0.0022
{0.00192}
0.0156
{0.00168}
{0.00076}
{0.00076}
(0.0005)
0.0032
0.0035
(0.0009)
0.0036
{0.00248}
{0.17168}
{0.21268}
0.0126
0.0948
{0.0044}
0.0052
0.028
0.0024
{0.00084}
ND
ND
0.004
0.0012
ND
0.0012
ND
0.1280
{0.1430}

0.0232
0.2416
{0.0066}
{0.00712}
0.0436
{0.00408}
{0.00160}
{0.00076}
(0.0005)
0.0072
0.0047
(0.0009)
0.0048
{0.00248}
{0.2997}
{0.3557}
ND Not Detected.  When both fractions are ND, the greater detection limit is used
    and is enclosed in parentheses (); otherwise, ND's are zero in calculating totals.
{ }  Estimated Maximum Possible Concentration. EMPC values are included in totals.
                                                                       oooL

-------
                  PARADIGM ANALYTICAL LABORATORIES, INC.
                              2627 Northchase Parkway S.E.
                           Wilmington, North Carolina  28405
                                      (910) 350-1903
                                   Fax (910)  350-1557
24 July 1998
Michael Maret
Pacific Environmental Services, Inc.
5001 S. Miami Blvd
Research Triangle Park, NC 27709-2077

Contract:          68D70002
Sub-Contract:       RO12-002
Work Assignment'   1-007

Subject: Polychlorinated Dibenzo-p-Dioxins & Dibenzofurans Measurements (PAL Project No. L-1072)

Dear Mike;

       Enclosed are the final results for the flue gas samples under your Project RO 12.003 Texas Lime
Kiln. The analytical procedures conformed or exceeded the ones described in Method 23 using isotope-
dilution high-resolution gas chromatography combined with high-resolution mass spectrometry. The Level
II reporting format is described on the next page. A general summary of the analytical results is presented
in Table 1. Tables 2 and 3 from Project L-1070 cover letter summarize the results for the front-halve of
the four inlet samples, expressed in absolute amount "ng" per sample, and in relative concentrations "part-
per-trillion". Figures land 2 show the TEQs and total homologues corresponding to Table 1 data.
        No. of Samples Received:         6
        No. of Samples Analyzed:         8
        No. of Lab. Method Blanks:       1

        Your Proj ect Number:          R012.003 Texas Lime Kiln
        PAL Project No.:               L-1072

        Remarks:
                •   Data meet QA/QC requirements.
                •   The FH of samples M23-1-3 and M23-I-4 contained 12.86 g and 29.63 g of dust, respectively. Both
                   FHs were processed as separate samples. The results are reported in two ways (see Tables 2 & 3
                   from PAL L-1070):
                        a) Absolute amount in "ng" per sample,
                        b) Relative concentration in parts-per-trillion (ppt) based on the weight of dust.
                •   No analytical difficulties to be reported.


        We wanted to thank you for the opportunity to serve you. Please, feel free to contact us if you
have questions or should you need additional technical support.

Sincerely,



 fves Tondeur, Ph.D.
                                                                                                    001
                      North Carolina Wastewater Certification #481

-------
                             Level II Report

Section 1: Cover Letter, contains a brief description of the project, the client and
         PAL Project Numbers, the number and type of samples, the
         methodology used to process the samples, QC  remarks where any
         analytical difficulties are discussed and the impact on the quality of the
         data presented, a summary table with the analyte concent
         detection limits, the client sample identification numbers, units to report
         the concentrations, and a graphical representation of the TEQs and
         totals.

Section 2: Project Synopsis, contains the Sample Tracking & Management
         Forms, Communications Form, any correspondence, chain-of-custody
         and the last page is always a copy of the sample injection log(s). This
         section is designed to help the laboratory and the data reviewer with an
         overall view of the entire analytical procedure, the initials and dates of
         who did what when on which sample. Spiking solution IDs are
         recorded along with the batch numbers of the supplies and reagents
         used.

Section 3: Analytical Results, contains the sample results  topsheets (one set of
         two per sample), the raw data (i.e., the selected ion current profiles, the
         areas, heights, ion abundance ratios, signal-to-noise ratios, and
         retention times of the GC peaks).

Section 4: System Performance, contains the documentation on the GC/MS
         system performance.  In particular, the mass resolution checks, GC
         column performance checks, initial and continuing calibration summary
         tables and, when applicable, associated raw data for both column types.
                                                                         C<   OO2

-------
Table 1: Analyte Concentrations in "ng" per Sampling Train
               (FH of the inlet sample shown in Tables 2 and 3 from PAL L-1070

2,3,7,8-TCDD
1,2,3,7,8-PeCDD
1,2,3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
1,2,3,4,6,7,8-HpCDD
OCDD
2,3,7,8-TCDF"
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
1,2,3,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
OCDF
Total TCDDs
Total PeCDDs
Total HxCDDs
Total HpCDDs
Total TCDFs
Total PeCDFs
Total HxCDFs
Total HpCDFs
Total PCDD/Fsb
TEQ (ND=0)C
TEQ (ND=l/2)d
TEQ EMPC(ND=0)e
TEQ EMPC (ND=l/2)
gSilJi^UgMiWBHnffi
KB^H^^
[0.00098]
(0.0004)
(0.0004)
(0.0003)
[0.00116]
0.0029
0.0141
0.0015
(0.0007)
(0.0007)
[0.00096]
0.0006
(0.0005)
(0.0006)
[0.00168]
(0.0010)
(0.0009)
[0.001]
(0.0004)
0.0012
0.0052
0.0016
(0.0007)
0.0008
[0.002]
0.0229
0.0003
0.0009
0.0015
0.0018
HH^B
nHsBBBIH
0.0021
0.0006
(0.0008)
[0.00156]
[0.00208]
[0.00636]
0.0186
0.0061
0.0023
(0.0005)
0.0026
[0.00104]
(0.0004)
(0.0004)
0.0043
(0.0006)
0.0036
0.0085
0.0036
0.0072
0.0052
0.0632
0.0100
0.0044
0.0044
0.1287
0.0034
0.0037
0.0040
0.0042
Bffln^B
•QIB^^^IIIXHI
m§&B&BmH$lSS&
0.0015
0.0006
(0.0004)
0.0014
[0.00196]
0.0045
0.0167
0.0054
0.0038
[0.0024]
0.0033
[0.00168]
[0.00116]
(0.0005)
0.0063
[0.00112]
0.0092
0.0119
0.0056
0.0076
0.0088
0.1428
0.0312
0.0104
0.0076
0.2518
0.0030
0.0030
0.0050
0.0050
BHHf
BJBBjjflSlBHoii
0.0010
[0.00072]
(0.0006)
0.0011
[0.00112]
0.0043
0.0136
0.0016
(0.0004)
(0.0004)
0.0013
[0.0008]
[0.00068]
(0.0004)
0.0061
(0.0008)
[0.00468]
0.0022
0.0012
0.0040
0.0084
0.0024
0.0024
0.0028
0.0060
0.0429
0.0010
0.0020
0.0020
0.0020
•
0.0012
[0.0004]
(0.0006)
[0.00076]
[0.00116]
0.0050
0.0146
0.0106
0.0022
[0.00192]
[0.00168]
[0.00076]
[0.00076]
(0.0005)
0.0035
(0.0009)
[0.00248]
0.0088
0.0004
0.0076
0.0096
0.1468
0.0156
0.0032
0.0036
0.2102
0.0020
0.0030
0.0040
0.0040
•
0.0013
[0.00064]
(0.0009)
[0.00132]
[0.00128]
0.0080
0.0218
0.0301
0.0077
0.0074
0.0032
0.0016
[0.00088]
(0.0004)
0.0056
(0.0007)
0.0052
0.0101
0.0020
0.0088
0.0172
0.2964
0.0592
0.0108
0.0056
0.4371
0.0091
0.0093
0.0097
0.0098
•
[0.00065] 1
[0.00044]
(0.0006)
[0.00072]
[0.0012]
[0.00268]
[0.0076]
(0.0007)
(0.0004)
(0.0004)
[0.0008]
(0.0002)
(0.0003)
(0.0003)
0.0026
(0.0007)
[0.00148]
[0.0006]
[0.0012]
[0.006]
[0.0064]
(0.0007)
(0.0004)
[0.0012]
0.0028
0.0028
0.0000
0.0006
0.0012
0.0014
a) Result obtained from the DB-225 analysis.
b) Total PCDD/Fs represent the sum of all polychlorinated dibenzo-p-dioxins & dibenzofurans.
c) TEQ computed using ITEF and setting non detected analytes with a "Zero" concentration.
d) TEQ computed using ITEF and setting non detected analytes with a concentration half the
   calculated detection limit.
e) TEQ computed using ITEF and setting the concentration of EMPC analytes to the EMPC value.
NOTE:
        () = ND using DL value.
        [ ] = EMPC value.
                                       06 AUG 98 Revision

-------
 Table 2: Analyte Concentrations in "ng" per Front-Half Sampling Train (i.e., filter and dust) for ajj runs.
^^^^s|ymjM|ffi
.^«.^__l
1,2,3,7,8-PeCDD
1,2,3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
1,2,3,4,6,7,8-HpCDD
OCDD
2,3,7,8-TCDF*
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
1,2,3,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
OCDF
Total TCDDs
Total PeCDDs
Total HxCDDs
Total HpCDDs
Total TCDFs
Total PeCDFs
Total HxCDFs
Total HpCDFs
Total PCDD/Fsb
TEQ (ND=0)C
TEQ (ND=l/2)d
TEQ EMPC(ND=0)e
TEQ EMPC (ND=l/2)
HR|3^^r|||!j^9BHJ||
[0.0025]
[0.0034]
0.0028
[0.00536]
0.0072
0.0208
0.0200
0.0184
0.0198
0.0240
0.0323
0.0132
0.0114
0.0031
0.0215
[0.00232]
[0.00308]
0.1092
0.0744
0.1384
0.0376
0.6276
0.3208
0.1076
0.0244
1.4600
0.0220
0.0230
0.0270
0.0270
^35BIMMEIBniHBBHB9BH^I
GoZS^H^^E^^BMcH^^H^HiH^^B
jsi^^^^^H^^^^HB^^H
iHJ^BHI
[0.00156]
(0.0003)
(0.0007)
0.0010
0.0016
0.0028
0.0060
0.0180
0.0184
0.0124
0.0102
0.0066
[0.00376]
(0.0008)
0.0061
[0.00176]
(0.0008)
0.0348
0.0060
0.0024
0.0028
0.3548
0.1644
0.0348
0.0092
0.6152
0.0110
0.0110
0.0130
0.0130
M
[0.00099]
(0.0003)
(0.0005)
(0.0004)
[0.00088]
[0.00168]
0.0051
[0.00124]
(0.0004)
[0.00064]
[0.0008]
[0.00032]
(0.0003)
(0.0003)
0.0006
(0.0006)
(0.0006)
[0.003]
(0.0003)
0.0016
0.0008
[0.001]
[0.001]
[0.001]
0.0008
0.0083
0.0000
0.0010
0.0020
0.0020
•Hi
JBmHHHIStiMiif
[0.00108]
(0.0004)
(0.0007)
(0.0005)
[0.00108]
0.0018
0.0046
0.0126
[0.0044]
0.0052
0.0024
[0.00084]
(0.0004)
(0.0004)
0.0012
(0.0006)
(0.0008)
0.0012
[0.002]
0.0056
0.0016
0.0948
0.0280
0.0040
0.0012
0.1410
0.0040
0.0050
0.0060
0.0060
a) Result obtained from the DB-225 analysis.
b) Total PCDD/Fs represent the sum of all polychlorinated dibenzo-p-dioxins & dibenzofurans.
c) TEQ computed using ITEF and setting non detected analytes with a "Zero" concentration.
d) TEQ computed using ITEF and setting non detected analytes with a concentration half the
   calculated detection limit
e) TEQ computed using ITEF and setting the concentration of EMPC analytes to the EMPC value.
NOTE;
        () = ND using DL value.
        [ ] - EMPC value.
                                       06 AUG 98 Revision

-------
Table 3: Analyte Concentrations in "parts-per-trillion" for the Front-Half Sampling Trains (i.e., filter and
                                           dust).
AnaJlte Jg
T -^2^^,, -^^nwlin
2,3,7,8-TCDD
1,2,3,7,8-PeCDD
1,2,3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
1,2,3,4,6,7,8-HpCDD
OCDD
2,3,7,8-TCDF*
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
1,2,3,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
OCDF
Total TCDDs
Total PeCDDs
Total HxCDDs
Total HpCDDs
Total TCDFs
Total PeCDFs
Total HxCDFs
Total HpCDFs
Total PCDD/Fsb
TEQ (ND=0)C
TEQ (ND=l/2)d
TEQ EMPC(ND=0)e
TEQ EMPC (ND=l/2)
MBBTO^^^aBMH
^HHHIMIIHSfl
[0.16055]
[0.21809]
0.180
[0.34381]
0.464
1.332
1.280
1.178
1.270
1.539
2.073
0.849
0.731
0.198
1.380
[0.14881]
[0.19756]
7.004
4.772
8.877
2.412
40.257
20.577
6.902
1.565
93.647
1.429
1.457
1.735
1.735
^^sS^^jj^Hf^HHI
[0.04808]
(0.009)
(0.021)
0.030
0.049
0.085
0.186
0.553
0.568
0.382
0.314
0.204
[0.11576]
(0.024)
0.187
[0.05419]
(0.026)
1.071
0.185
0.074
0.086
10.924
5.062
1.071
0.283
18.942
0.337
0.352
0.397
0.402
P£aLIL^£k^l>^^U'WU|A8UgjUni
BgHaHQBffiB
^HIH
[0.07707]
(0.026)
(0.038)
(0.027)
[0.06843]
[0.13064]
0.395
[0.09642]
(0.031)
[0.04977]
[0.06221]
[0.02488]
(0.021)
(0.025)
0.050
(0.049)
(0.045)
[0.249]
(0.026)
0.124
0.062
[0.093]
[0.062]
[0.093]
0.062
0.644
0.001
0.042
0.129
0.142
^^^^^^^^^^^^^^^HH[
^HHi
[0.03639]
(0.014)
(0.023)
(0.016)
[0.03645]
0.059
0.154
0.424
[0.1485]
0.176
0.080
[0.02835]
(0.013)
(0.015)
0.042
(0.020)
(0.025)
0.041
[0.054]
0.189
0.054
3.199
0.945
0.135
0.041
4.757
0.139
0.156
0.190
0.197
a) Result obtained from the DB-225 analysis.
b) Total PCDD/Fs represent the sum of all polychlorinated dibenzo-p-dioxins & dibenzofurans.
c) TEQ computed using ITEF and setting non detected analytes with a "Zero" concentration.
d) TEQ computed using ITEF and setting non detected analytes with a concentration half the
   calculated detection limit
e) TEQ computed using ITEF and setting the concentration of EMPC analytes to the EMPC value.
NOTE:
        () = ND using DL value.
        [ ] = EMPC value.
                                           06 AUG 98 Revision

-------
                                           TEQ
0.0100
00010 -
00000
                                                               0.0098
                                                                                   TEQ (ND=0)
                                                                                 STEQ (ND=1/2)
                                                                                 BTEQ EMPC (ND=0)
                                                                                 DTEQ EMPC (ND=1/2)
          1MB      M23-I-3    M23-0-3    M23-FB-3    M24-I-4
                                 Amount In "ng" per Train
M24-0-4    M24-FB-4
                          Figure 1: Graphical representation of the TEQs
                                                                                                     004

-------
                                            Total Homologues
      0 4500 -i
      0 4000 -
      0.3500 -
      0.3000 -
      0.2500 -
Sample
      0.2000 -
      01500 -
      0.1000 -
       0 0500 -
       00000
                  LMB        M23-I-3       M23-0-3      M23-FB-3      M24-I-4
                                                Amount in "ng" per Train
M24-O-4      M24-FB-4
            Figure 2: Graphical representation of the totals (tetra- through octachlorinated congeners)
                                                                                                                005

-------
            PAL Project No.: L-1072
— *
               Section 2
            Project Overview
                   &
Sample Tracking & Communication Forms

-------
              Overview for the Analysis of Polychlorinated Dibenzo-/?-Dioxins & Dibenzolurans
    No. of Field Samples:   _f
    No. of Billable Samples:  6_
              PAL Project No.:   L-1072
o
 -v
O
                                                                  Date Received:   08 JUL 98
                                                                  Due Date:        29 JUL 98
                                                                  Client Project ID: R012.003 TX
                                                                  LIME KILN
              | Concentration
SOPSP-N-02
             Spike Profile
        ES:   23
        SS:   23
        JS:   23
4ng(l-2)
4ng(l-l)
                                                                                          XAD
                                                                         Sampling Modules Prep. Project No.
                 Add M23-
                Vol.: 40 n L;   Cone.: 0.1 ng/ ^ L
                                                                             SOPSP-S-01
        Tridecane batch No.:  Xt***A*1
        Thimbles batch No.:
        Toluene batch No.:
        Pre-Soxhlet:
        Others:
                                Soxhlet 16 H Toluene
                                                                        SOPSP-E-01
                         Concentration & Solvent Exchange | SOPSP-N-OI
                                                     Split Extract   I SOPSP-D-OI
                                                            Hexane batch No.:
                                                            CH2C12 batch No.:

                                                            Silica batch No.:
                                                            Alumina batch No.:
                                                            PCU-F batch No.:
                                                            NajSO4 batch No.:
                                SOPSP-D-01
      Special Instructions:
                                                                                        Fractionation  SOPSP-U-OS
                                                                                             I
                                                                                       Concentration
                                                                         SOPSP-N-01
                                                   Add M23JS-07/?4r-S9t- '¥
                                                  Vol.; 20 n L;  Cone.; 0.1 ng/ n L
                                                                                                            SOPSP-S-01
                                                         HRGC - HRMS  I ^QP SP-A-01

-------
    Project Overview for the Analysis of Poly chlorinated Dibenzo-/i-Dioxins & Dibenzofurans
   No. of Field Samples:   j
   No. of Billable Samples:
O

00-
      Soecial Instructions:
PAL Project No.:  L-1072
Date Received:   08 JUL 98
Due Date:       29 JUL 98
Client Project ID: R012.003 TX
LIME KILN
                                                SOPSP-A-01
                                              Sample Extract
                                             Fortified with JS J
                                                                        Reporting I


         Report
                                                         SOPRP-G-01
                                              Data Package
                                                Assembly
                   SOPSH-A-01
                                     Archive Data
                   Ship Data
                                      SOPRP-A-01
                   SOPSH-D-01
                                       ,evel; I Hi)
             m n+  m+
8A.M.
i
r
MS
'
1

^
	 p


GC


k.
... p


Calibration


^
p

8P.M.

E
hlnxlr ,.._. k Cn»-i»1r>r k /^rm/^nl ^ IVlTC
»iaiiK ~ samples ^ i^oni^ai ~ ivis
•
i
^^
     Instrument ID:
     HP-5MS batch No.:
     DB225 batch No.:

     ConCal: ->

-------
Sam^.e Tracking for the Analysis of Polychlu, mated Dibenzo-/?-Dioxins & Dibenzoit.* ans
No. of Field Samples:  0
Page _/_ of
                               PAL Project No.:  L-1072
Date Received:   08 JUL 98
Due Date:       29 JUL 98
Client Project ID: R012.003 TX
LIME KILN

-------
Communication Exchanges Form for the Analysis of PCDD/PCDFs
No. of Field Samples:
Page / of /
      ° ^
PAL Project No.: L-1072
Date Received:  08 JUL 98
Due Date:      29 JUL 98
Client Project ID: R012.003 TX
LIME KILN
                              ':

-------
Contract No.:           68D70002
Subcontract No.:        R012-002
Work Assignment:      1-007

08 July 1998

Michael Maret
Pacific Environmental Services, Inc.
5001 S. Miami Blvd
P.O. Box 12077
Research Triangle Park, NC 27709-2077

Reference:  Project No. RO12.003; Project Name: US EPA "Lime Kiln Screening, Texas Lime

Subject: Inlet Samples Heavy Particulate Load

Dear Mike:

        The thirteen Method 23 samples were received in good condition and no discrepancies were noted
between the sample labels and the chain-of-custody. As we discussed, we organized the samples into three
separate projects, each assigned a specific PAL Project No.  Table 1 summarizes the sample identification
and their associated PAL Project Nos.

        The object of this letter is to bring to your attention the following concerns. Following a
description of the issues, possible solutions are discussed for your consideration.

        The issue pertains to the "inlet" samples. Each of the four inlet samples shows relatively high
levels of dust (particulates). Depending on the sample, we estimated the amount of solids to range from
10 g to 35 g.

        The first concern is a practical one.  Indeed, the capacity of a normal Soxhlet extraction set up is
exceeded if we want to combine the front- and back-halves of the sampling train (FH & BH).  Two separate
extractions  would be required for each of the inlet samples.  This leads to the following two options:

        1.   Combine the two extracts and process the FH and BH as a single sample.
            >   The question remains as to where the Method 23 internal standards are added.

        2.   Treat the FH and BH as two separate samples.
            >   Each sample receives a normal dose of Method 23 internal standards before the extraction.
            >   This option resembles Method 0023A's and results in four additional samples.

        The second concern is related to generating "meaningful" results for your client's study.
Reporting PCDD/F results in "ng /dscm" in the flue gas in such circumstances - where paniculate levels
are so high ~ may be of no value to your client. We recommend Option 2 above and propose to report the
analytical results for the inlet samples in two ways: a) absolute amount (e.g., ng per FH) of the PCDD/Fs
and, b) relative concentrations of PCDD/Fs expressed in parts-per-trillion (ppt) or picogram per gram of
"dust" recovered in the inlet sample. Note that this approach  can only be achieved if Option 2 is selected,
which amounts to treating the inlet FH as a solid sample rather than as a flue gas sample.

        Please, let us know if you have questions and we are waiting for a decision on how you would like
us to handle these particular inlet samples. I can be reached at 910-350-2839.

Sincerely,                  v  }                  .
                                              4*
  VesTondeur,Ph.D.
                                                                                                  I      -N
                                                                                                 *  <*•).

-------
Table 1: Project No. R012.003; Project Name: US EPA Lime Kiln Screening, Texas Lime;
                       Sample and Project Identification.
PES Sample ID
PAL SampleID_
PAL Project No.
M23-I-1
M23-O-1
M23-FB-1
M23-RB

M23-I-2
M23-O-2
M23-FB-2
M23-I-3
M23-O-3
M23-FB-3
M23-I-4
M23-O-4
M23-FB-4
1070-1
1070-2
1070-3
1070-4

1071-1
1071-2
1071-3
" 1072-1 	
1072-2
' 1072-3
' 1072-4
1072-5 	 """
' 1072-6
, I>1070
L-1070
L-1070
L-1070
....
L-1071
L-1071
L-1071
	 """L-1072
L-1072
	 L-1072 	
L-1072
"L-1072 ~
	 L-1072
' L-1072
                                                                                      012

-------
^PACIFIC ENVIRONMENTAL SERVICES. INC.
                           Central Park West
     5001 South Miami Boulevard, P.O. Box 12077
Research Triangle Park, North Carolina 27709-2077
           (919) 941-0333 FAX: (919) 941-0234

R012.003

Date
!
6/25/98
6/28/98
6/28/98
6/28/98
6/28/98
6/30/98
6/30/98
6/30/98
6/30/98
7/1/98
7/1/98
7/1/98
7/1/98
6/25/98
6/25/98
6/25/98
6/25/98
6/27/98
6/27/98
Chain of Custody Record
US EPA Lime Kiln Screening - Texas Lime
Abamathy. Gay, Maret, D.D Holzschuh, Stegal. Stewart
Time
1518
1033
1033
1033
1033
1247
1247
1247
1247
1414
1414
1414
1414






Field Sample ID
M23-O-1-4
M23-O-2-1
M23-O-2-2
M23-O-2-3
M23-O-2-4
M23-O-3-1
M23-O-3-2
M23-O-3-3
M23-O-3-4
M23-O-4-1
M23-O-4-2
M23-O-4-3
M23-O-4-4
M23-FB-1-1
M23-FB-1-2
M23-FB-1-3
M23-FB-1-4
M23-FB-2-1
M23-FB-2-2
Sample Description
Container No. 4 - XAD Sorbent Resin
Container No. 1 - Filter
Container No. 2 - Train Acetone Rinse
Container No. 3 - Train Toluene Rinse
Container No. 4 - XAD Sorbent Resin
Container No. 1 - Filter
Container No. 2 - Train Acetone Rinse
Container No. 3 - Train Toluene Rinse
Container No. 4 - XAD Sorbent Resin
Container No. 1 - Filter
Container No. 2 - Train Acetone Rinse
Container No. 3 - Train Toluene Rinse
Container No. 4 - XAD Sorbent Resin
Container No. 1 - Filter
Container No. 2 - Train Acetone Rinse
Container No. 3 - Train Toluene Rinse
Container No. 4 - XAD Sorbent Resin
Container No. 1 - Filter
Container No. 2 - Train Acetone Rinse
Analysis Requested

•
•
•
•
•
•
•
•
•
•
•
•
*
•
•
•
•
•
•

•
*
*
•
•
•
•
• -
•
•
•
•
•
•
•
•
•
•
•




































































































Remarks
/0T0-2-
I0?l-l
/'3t~ 2-
/<&1^-l.
/^*/-^
1031-1.
t '*>>2- 2.
/o*2-t
^o^^-^-'
/oiz-r
/**2~_r~
/*>2-r~
/*?z-r^
FIELD BLANK 1 JOtO^Z
FIELD BLANK 1 / ~ J
FIELD BLANK 1 {03n '%
FIELD BLANK 1 //)$<,- 3
FIELD BLANK 2 /
-------
                                                              1 3
PACiRC ENVIRONMENTAL SERVICES. INC.
L-
                                                                  _*><>> «=* )

                                                                 ,         '
                                                                 £ ar , a*,
                                                Chain of Custody Record
                          Central Park West
     5001 South Miami Boulevard, P.O. Box 12077

Research Triangle Park, North Carolina 27709-2077

           (919) 941-0333 FAX: (919) 941-0234
ect Num [Project Name
R012.003 I US EPA Lime Kiln Screening - Texas Lime
ipters:
Abematny, Gay, Maret. D.D Holzschuh, Siegal, Stewart
Date
6/25/98
6/25/98
6/25/98
6/25/98
6/28/98
6/28/98
6/28/98
6/28/98
6/30/98
6/30/98
6/30/88
6/30/18
. 7/108
7/1«8
7/1/98
7/1/98
6/25/98
! 6/25/98
I a/2M>8
Time
1518
1518
1518
1518
1033
1033
1033
1033
1247
1247
1247
1247
1414
1414
1414
1414
1518
1518
1518
Field Sample 10
M23-I-1-1
M23-M-2
M23-M-3
M23-I-1-4
M23-I-2-1
M23-I-2-2
M23-I-2-3
M23-I-2-4
M23-I-3-1
M23-I-3-2
M23-I-3-3
M23-I-3-4
M23-I-4-1
M23-I-4-2
M23-I-4-3
M23-l-4^4
M23-0-1-1
M23-O-1-2
M23-O-1-3
Sample Description
Container No. 1 - Filter
Container No. 2 - Train Acetone Rinse
Container No. 3 - Train Toluene Rinse
Container No. 4 - XAD Sorbent Resin
Container No. 1 - Filter
Container No. 2 - Train Acetone Rinse
Container No. 3 - Train Toluene Rinse
Container No. 4 - XAD Sorbent Resin
Container No. 1 - Filter
Container No. 2 - Train Acetone Rinse
Container No. 3 - Train Toluene Rinse
Container No. 4 - XAD Sorbent Resin
Container No. 1 - Filter
Container No. 2 - Train Acetone Rinse
Container No. 3 - Train Toluene Rinse
Container No. 4 - XAD Sorbent Resin
Container No. 1 - Filter
Container No. 2 - Train Acetone Rinse
Container No. 3 - Train Toluene Rinse
Analysis Requested

•
•
•
•
•
•
•
•
•
•
•
•
•
•
•
•
•
•
•

•
•
•
•
•
•
•
• •
•
•
•
•
•
•
•
•
•
•
•




































































































Remarks
^ -/&?& wjv-i
S03a~)
/0}*>l
/03o-l
£~ -/fj* / /z?9/ — /
(°~^('!
ttty'i
/ffi&o-f
Z-/^9^_ y^W^y
/^> >?/- /
10VZ-J
I012.~I
l€>?2-¥
/0*Z~}t-*1
/o-3-o - Z-
fc^O- 2~
/030-1-
   7/7/«8
                                                                                                           Pagel of 3 Pages

-------
PACIFIC ENVIRONMENTAL SERVICES, INC.
                          Central Park West
     5001 South Miami Boulevard, P.O. Box 12077
Research Triangle Park, North Carolina 27709-2077
           (919) 941-0333 FAX: (919) 941-0234
                                                Chain of Custody Record
'reject Num project Name
R012.003 |
US EPA Lime Kiln Screening - Texas Lime
Samplers:
Abemathy, Gay, Maret. D.D Holzschuh. Siegal, Stewart
Date
6/27/98
6/27/98
6/30/98
6/30/98
6/30/98
6/30/98
7/1/98
7/1/98
7/1/98
7/1/98
7/7/98
7/7/98
7/7/98
7/7/98
Time














Field Sample ID
M23-FB-2-3
M23-FB-2-4
M23-FB-3-1
M23-FB-3-2
M23-FB-3-3
M23-FB-3-4
M23-FB-4-1
M23-FB-4-2
M23-FB-4-3
M23-FB-4-4
M23-RB-1
M23-RB-2
M23-RB-3
M23-RB-4
Relinquished by: (Signature)
fwflfouislwtf by: ^nature)
^-^jA-^/fl/7 wbter

Date/Time
Date/Time
^IsffeS
Sample Description
Container No. 3 - Train Toluene Rinse
Container No. 4 - XAD Sorbent Resin
Container No. 1 - Filter
Container No. 2 - Train Acetone Rinse
Container No. 3 - Train Toluene Rinse
Container No. 4 - XAD Sorbent Resin
Container No. 1 - Filter
Container No. 2 - Train Acetone Rinse
Container No. 3 - Train Toluene Rinse
Container No. 4 - XAD Sorbent Resin
Container No. 1 - Filter
Container No. 2 - Train Acetone Rinse
Container No. 3 - Train Toluene Rinse
Container No. 4 - XAD Sorbent Resin
Received by: (Signature)
Received for lab by: (Signature)
M~~*lt dQ i
^3&5a$^^ ^
^^cTr^uMJ^ oelw.**
Analysis Requested

•
•
•
•
•
•
•
•
•
•
•
*
•
•

•
•
•
*
•
•
•
• •
•
*
•
•
•
•













































Relinquished by: (Signature)






























Date/Time
Remarks
FIELD BLANK 2 /09/-3
FIELD BLANK 2 /^
-/
REAGENT BLANK y^fr~y
Received by: (Signature)
REMARKS
                                                                                                                              XT
   7/7/98
                                                                                                            Page 3 of 3 Pages

-------
              Preparation of the XAD-2 Resin for Method 23 Sampling Session
No. Sampling Modules: 15
No. Filters:            25
PAL Project No.:   L-1043
                                             PES.
Order Received:  04 JUN 98
Due Date:       22 JUN 98
Client Project ID: TX Lime Kilns
P.O. No.:
Ph.:       (512)-693-5122
To ensure proper handling of the samples, please return this form with the field samples to:
                                     Paradigm Analytical Labs
                                    2627 Northchase Pkwy S.E.
                                      Wilmington, NC 28405
                Thank you for your cooperation. Our phone number is 910-350-2839. (Fax: 910-350-1557)

                                   ^Method 2$Sampling •


Mailing Address:
Special Instructions:
Best western
Attn.: Mike Maret
1403 Hiway 281 N
Marble Falls, TX 78654-4505
Ph.: (512)693-5122
Note: An amount of resin equal to one module was fortified as ^^_________
described above, retained by the laboratory and kept at 4°C. ^ — • 	 "
Upon return of the field samples, this aliquot will be^ 	
used to process the Laboratory Method Blanj^^- 	

	 	
                                                                 Filters
                                                                 Batch No.:    O*-^   	
                                                                 Size:        83 mm diameter
                                                                 Type:     Ccjass FibeJ)  Quartz
                                                                 XAD-2 Resin Modules
                                                                 Batch No.:	   /
                                                                 Type: Ball/Soclwt (6-Ring Ball/Socke^ Screw Cap

                                                                 Add M23-SS-ti,M%-SOz,- n
                                                                 Vol.: 40 n L ;  Cone.: 6.1 ng/ \a L
                                                                 Preparation Date:
                                                                 [Two-week holding time]
                                                                 Analyst:

-------
          Paradigm Analytical Labs

             Login Report (In01)
                Jul. 08, 1998
                  10:05 AM
   Login Number: L1072
Account:        1027

 Project:       R012.003
Pacific Environmental Services,
Texas Lime Kiln               Page:  1 of 2
Laboratory
Sample Number
L1 072-1
L1 072-2
L1 072-3
L1 072-4
L1 072-5
L1 072-6
Client
Sample Number
M23-I-3
M23-O-3
M23-FB-3
M23-I-4
M23-O-4
M23-FB-4
Collect
Date
30-JUN-98
30-JUN-98
30-JUN-98
30-JUN-98
30-JUN-98
30-JUN-98
Receive
Date
08-JUL-98
08-JUL-98
08-JUL-98
08-JUL-98
08-JUL-98
08-JUL-98
Due
PR Date Comments
29-JUL-98 jPoetf Cr^tft^kjii
29-JUL-98
29-JUL-98
29-JUL-98
29-JUL-98
29-JUL-98


H^-of^f T


                        Signature:

                            Date:
                                          017

-------
                                        Paradigm
                              Sample Receipt Checklist
                     1027
Client:
Client Project ID:  R012.003
Lab Project: L1072
No
1

2

3

5
7



8

9

Check
YE^
/YES)
<^E§,
YES
/(ug)
/ NO
J NO
/^o;
S~^-
tf^
£77
^~~^
v *"5
YES
YES

/YE*/
U^
YES
// NU
°c
// Nu
/ NO
/ NO

// j\in
	 v
//NO y
^ 	 "
Description
Shipped
Hand Delivered
COC Present on Receipt
Additional Transmittal Form
COC Tape on Shipping Container
samples Intact
Temperature
-«m™4L -0^1= 3-L.^LL-J

Ne— Rreservative Noted

-------
          Paradigm Analytical Labs
             Login Report (In01)
                Jul. 13, 1998
                   11:57AM
   Login Number: L1072
Account:         1027
 Project:       R012.003
Pacific Environmental Services, Ir
Texas Lime Kiln               Page:  1
of 2
Laboratory Client Collect
Sample Number Sample Number Date
L1 072-1
StackAir
StackAir
StackAir
L 1072-2
StackAir
StackAir
StackAir
L1 072-3
StackAir
StackAir
StackAir
L1 072-4
r '-Air
\ir
StackAir
L1 072-5
StackAir
StackAir
StackAir
L1 072-6
StackAir
StackAir
StackAir
M23-I-3
P 23-TO
C 8290-TO-FT
C 8290-TO-SL
M23-O-3
P 23-TO
C 8290-TO-FT
C 8290-TO-SL
M23-FB-3
P 23-TO
C 8290-TO-FT
C 8290-TO-SL
M23-I-4
P 23-TO
C 8290-TO-FT
C 8290-TO-SL
M23-O-4
P 23-TO
C 8290-TO-FT
C 8290-TO-SL
M23-FB-4
P 23-TO
C 8290-TO-FT
C 8290-TO-SL
30-JUN-98
Hold:
Hold: 07-JUL-98
Hold: 07-JUL-98
30-JUN-98
Hold:
Hold: 07-JUL-98
Hold: 07-JUL-98
30-JUN-98
Hold:
Hold: 07-JUL-98
Hold: 07-JUL-98
30-JUN-98
Hold:
Hold: 07-JUL-98
Hold: 07-JUL-98
30-JUN-98
Hold:
Hold: 07-JUL-98
Hold: 07-JUL-98
30-JUN-98
Hold:
Hold: 07-JUL-98
Hold: 07-JUL-98
Receive
Date
08-JUL-98

4 oz. Glass
4 oz. Glass
08-JUL-98

4 oz. Glass
4 oz. Glass
08-JUL-98

4 oz. Glass
4 oz. Glass
08-JUL-98

4 oz. Glass
4 oz. Glass
08-JUL-98

4 oz. Glass
4 oz. Glass
08-JUL-98

4 oz. Glass
4 oz. Glass
Due
PR Date Comments
29-JUL-98

1 Bottles
1 Bottles
29-JUL-98

1 Bottles
1 Bottles
29-JUL-98

1 Bottles
1 Bottles
29-JUL-98

1 Bottles
1 Bottles
29-JUL-98

1 Bottles
1 Bottles
29-JUL-98

1 Bottles
1 Bottles
                         Signature :
                             Date :   tt-
                                                                        019

-------
           Paradigm Analytical Labs

             Login Report (In01)
                 Jul. 13, 1998
                   11:57 AM
   Login Number: L1072
Account:         1027         Pacific Environmental Services, Ir
 Project:                                                   Page: 2 of  2
Laboratory
Sample Number
L1 072-7
Client
Sample Number

Collect
Date

Receive
Date
08-JUL-98
Due
PR Date

Comments

                          Signature : 6arl - \tfad	;	
                                     1       0                      _
                              Date :                                        vr"*v

-------
O. .n 20-JUL-1998
Paradigm Sample Log
Data File S
al7ju!98b 1
al7ju!98b 2
al7ju!98b 3
a!7ju!98b 4
a!7ju!98b 5
al7ju!98b 6
a!7ju!98b 7
a!7ju!98b 8
al7ju!98b 9
a!7ju!98b 10
a!7ju!98b 11
a!7ju!98b 12
a!7ju!98b 13
al7ju!98b 14
a!7ju!98b 15
Page 1
Sample ID
DB-5 Retchk
FE CS3
098-M23 xl/2
598-M23 xl/2
SB
1070-0 xl/2
1070-1 xl/2
1070-2 xl/2
1070-3 xl/2
1070-4 xl/2
1070-5 xl/2
BE CS3

Page 1 of 1
Acq. Date Time
17-JUL-98 16:45:56 I
17-JUL-98 17:31:00 "
17-JUL-98 18:16:05
17-JUL-98 19:01:10
17-JUL-98 19:46:16
17-JUL-98 20:31:20
17-JUL-98 21:16:26 -
17-JUL-98 22:01:31
17-JUL-98 22:46:36
17-JUL-98 23:31:42
18-JUL-98 00:16:48
18-JUL-98 01:01:55 ,
18-JUL-98 01:47:01 /
18-JUL-98 02:32:07 i /
18-JUL-98 03:17:11 	 • v

-------




















o
OPUSquan 21-JUL-1998
Paradigm Sample Log
Data File S
a20ju!98b 1
a20ju!98b 2
a20ju!98b 3
a20ju!98b 4
a20ju!98b 5
a20jul98b 6
a20ju!98b 7
a20ju!98b 8
a20ju!98b 9
a20ju!98b 10
a20ju!98b 11
a20ju!98b 12
a20ju!98b 13
a20jul98b 14
a20ju!98b 15 •
a20ju!98b 16
a20ju!98b 17

Page 1

Sample ID
DB-5 Retchk
FE CS3
1071-0 xl/2
^071698 xl/2
^MHMHRf
107™ xl/2
1071-2 xl/2
1071-3 xl/2
1071-4 xl/2





071698 xl/2
PR 1071 xl/2
BE CS3



Acq . Date
20-JUL-98
20-JUL-98
20-JUL-98
20-JUL-98
21-JUL-98
21-JUL-98
21-OUL-98
21-JUL-98
21-JUL-98
21-JUL-98
21-JUL-98
21-JUL-98
21-JUL-98
21-JUL-98
21-JUL-98
21-JUL-98
21-JUL-98


Page 1 of 1
Time
21:16:15 — • 	 *
22:01:21
22:46:27
23:31:32
00:16:40
01:01:45
01:46:49
02:32:32
03:17:49
04:02:53
04:47:59
05:33:04
06:18:11
07:03:15
07:48:43 ^
08:33:49 ^^
09:18:54 \S



-------



























Ol n 22-JUL-1998

Page 1

Paradigm Sample Log
Data File
A21JUL98A
A21JUL98B
A21JUL98C
A21JUL98C
A21JUL98C
A21JUL98D
A21JUL98E
A21JUL98F
A21JUL98F
A21JUL98F
A21JUL98F
A21JUL98F
A21JUL98F
A21JUL98F
A21JUL98F
A21JUL98F
A21JUL98F
A21JUL98F
A21JUL98F
A21JUL98F
A21JUL98F
A21JUL98F
A21JUL98F
A21JUL98F
S
1
1
1
2
3
1
1
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
Sample ID
Sand QC
B-225 Retchk
B-225 Retchk
CS3
sb
B-225 Retchk
B-225 Retchk
B-225 Retchk
CS3
sb
1070-1 xl/2
1070-2 xl/2
1070-5 xl/2
flHMMMHV
1068-1 xl/2
1069-1 xl/2
1069-2 xl/2
-1069-3 xl/2
^I^MMHIBB
1071-2 xl/2
^fft^ftiji
^^^^fff
^^ffiSSi
CS3
Acq. Date
21-JUL-98
21-JUL-98
21-JUL-98
21-JUL-98
21-JUL-98
21-JUL-98
21-JUL-98
21-JUL-98
21-JUL-98
21-JUL-98
21-JUL-98
21-JUL-98
21-JUL-98
21-JUL-98
22-JUL-98
22-JUL-98
22-JUL-98
22-JUL-98
22-JUL-98
22-JUL-98
22-JUL-98
22-JUL-98
22-JUL-98
22-JUL-98

Page 1 of 1
Time
11:08:47
16:44:01
17:52:30
18:29:30
19:06:30
19:59:35
20:01:06
20:06:58
20:43:56 -4^~~~
21:20:54
21:57:56
22:34:59
23:12:05
23:49:03
00:26:13
01:03:12
01:40:19
02:17:20
02:54:34
03:31:35
04:08:35
04:46:12 /
05:23:13 /
06:01:17 v^/^
o
to
CO

-------
                         Section 3
                    Analytical Results
                 Documentation for the Analysis
                              of
        Polychlorinated Dibenzo-/>-Dioxins & Dibenzofurans
N

-------
                                                                     Paradigm Analytical Labs
                              Analytical Data Summary Sheet
Analyte

2,3,7,8-TCDD
1,2,3,7,8-PeCDD
1,2,3,4,7,8-HxCDD
1,2,3,6,7,8-BxCDp . j
1,2,3,7,8,9-HxCDD
U,3,4,6,7,8-HpCDD
OCDD
2,3,7,8-TCDF
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1, 2,3,6,7, 8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
1,2,3,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
OCDF
Total TCDDs
Total PeCDDs
Total HxCDDs
Total HpCDDs
Total TCDFs
Total PeCDFs
Total HxCDFs
Total HpCDFs
TEQ (ND=0)
TEQ (ND=l/2)
Amount ;^
oigp7^
EMPC
M?.;.:r-.
ND

"^'EMPC
'Q4)Q2gal
0.0141
0.0015
ND
ND
EMPC
0.0006
ND
ND
EMPC
ND
ND
ND
ND
0.0012
0.0052
0.0016
ND
0.0008
ND
0.0003
0.0009
;;?/DL .
t ; A«S> ,
0.0005
$m* t
0.0004
IWttC*
0.0003
|^0*0006,;-
0.0011
0.0008
0.0007
0.0007
0.0005
0.0004
0.0005
0.0006
0.0009
0.0010
0.0009
0.0005
0.0004
0.0003
0.0006
0.0008
0.0007
0.0004
0.0009


EMPC
W
0.0010
,„ w

^V«?", "•'•"J ,-
"btooii
-V."," •:• '"**>-i




0.0010



0.0017


0.0010

0.0040



0.0020
0.0020
0.0015
0.0018
RT
(mtn.)
28:27
32:37
34:43
34:46
34:59
,37:10
40:02
27:28

32:25
34:10
34:15
34:37
35:08
36:22












Ratio

2.99
1.17
4.66
2.01
1.70
0.91
0.81
0.79

2.2
1.01
1.33
0.91
0.5
0.64












Qualifier


























ITEF
ITEF
Client Information
Project Name:
Sample ED:
Laborator Information
Project ID;
'•Sample DO:-,'fcr- -'
Texas Lime Kiln
LMB
                         L1072
                                                  Sample Information

                                                  Mattix:
                                                  Weight / Volume:
                                                  Moisture / Lipids:
'• f?"-£^v;-;;QriginalpH:
 '•• , :'*!^i.ffe». '..iX^v .
                                                Air
                                                 1
                                                0.0
                                                NA
                                                                                Grams
                                                                                %
Analysis Date:
                                                        1798
                                        1/2
                                                                                           025

-------
                                                                Paradigm Analytical Labs
                           Analytical Data Summary Sheet
Client Information
Project Name:
Sample ID:

Laboratory Information

Project ID:
Sample ID;
Collection Date:
Texas Lime Kiln
LMB
L1072
1072-0
Samle Information
Matrix;
Weight /Volume:
Moisture /Lipids:
Original pH :
Filename:
Rcicjlk;

Air
1
0:0
NA
a!7juI98b-7
al7jnI98b-l
al7iuI98b-2
                                                   Grams
                                                                          FSiJLft
                                                                                      026
                                      2/2

-------
Ol .n 20-JUL-1998
Filename al?jul98b
Sample 7
Acquired 17-JUL-98
Processed 20-JUL-98
Sample ID 1072-0 xl/2
Page 1


21:16:26
09:03:59









































Cal Table m8290-23-071798
Results Table M8290-23-071798B
Comments
Typ
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
ES/RT
ES
ES
ES
ES
ES/RT
ES
ES
ES
JS
JS
CS
CS
CS
CS
CS
SS
SS
SS
SS
SS
Name;
2,3,7,8-TCDD;
1, 2,3,7, 8-PeCDD;
1,2,3,4/7, 8-HxCDD;
1,2,3,6,7,8-HxCDD;
1,2,3,7,8,9-HxCDD;
1,2,3,4,6,7,8-HpCDD;
OCDD;
2,3,7,8-TCDF;
1, 2,3,7, 8-PeCDF;
2,3,4,7,8-PeCDF;
1,2,3,4,7,8-HxCDF;
1,2,3,6,7,8-HxCDF;
2,3,4,6,7, 8-HxCDF ;
1,2,3,7,8,9-HxCDF;
1,2,3,4,6,7,8-HpCDF;
1,2,3,4,7,8, 9-HpCDF;
OCDF ;
13C-2,3,7,8-TCDD;
13C-1, 2,3,7, 8-PeCDD;
13C-l,2,3,6,7,8-HxCDD;
13C-l,2,3,4,6,7,8-HpCDD;
13C-OCDD;
13C-2,3,7,8-TCDF;
13C-1, 2,3,7, 8-PeCDF ,-
13C-l,2,3,6,7,8-HxCDF;
13C-l,2,3,4,6,7,8-HpCDF;
13C-1,2,3,4-TCDD;
13C-l,2,3,7,8,9-HxCDD;
37Cl-2,3,7,8-TCDD;
13C-2, 3,4,7, 8-PeCDF;
13C-l,2,3,4,7,8-HxCDD;
13C-l,2,3,4,7,8-HxCDF;
13C-l,2,3,4,7,8,9-HpCDF;
37Cl-2,3,7,8-TCDD;
13C-2 , 3,4,7, 8-PeCDF;
130-1,2,3,4,7, 8-HxCDD;
13C-1.2. 3,4,7, 8-HxCDF;
13C-l,2,3,4,7,8,9-HpCDF;

Resp;
3.11e+05;
2.50e+04;
1.92e+04;
4.22e+04;
7.64e+04;
1.45e+05;
5.88e+05;
1.33e+05;
* .
6.64e+04;
4.72e+04;
3.796+04;
2.49e+04;
1.72e+04;
5.81e+04;
it .
* .
3.74e+08;
2.84e+08;
3.056+08;
2.26e+08;
3.32e+08;
3.76e+08;
2.686+08;
2.31e+08;
1.10e+08;
3.84e+08;
3.136+08;
3.57e+08;
4.04e+08;
2.20e+08;
2.73e+08;
1.776+08;
3.57e+08;
4.046+08;
2.20e+08;
2.73e+08;
1.77e+08;

Ion 1;
6.79e+04;
1.35e+04;
1.58e+04;
2.826+04;
4.81e+04;
6.93e+04;
2.63e+05;
5.87e+04;
* •
4.566+04;
2.38e+04;
2.17e+04;
1.196+04;
5.71e+03;
2.27e+04;
* .
* .
1.63e+08;
1.73e+08;
1.706+08;
1.156+08;
1.57e+08;
1.656+08;
1.636+08;
7.93e+07;
3 .38e+07;
1.69e+08;
1.746+08;
3.57e+08;
2.47e+08;
1.22e+08;
9.29e+07;
5.406+07;
3.57e+08;
2.476+08;
1.22e+08;
9.296+07;
5.40e+07;

Ion 2;
2.43e+05;
1.156+04;
3.38e+03;
1.40e+04;
2.83e+04;
7.62e+04;
3.246+05;
7.426+04;
+ .
2.07e+04;
2.356+04;
1.63e+04;
1.316+04;
1.156+04;
3.54e+04;
* .
* .
2.116+08;
1.10e+08;
1.34e+08;
l.lle+08;
1.75e+08;
2.116+08;
1.056+08;
1.51e+08;
7.61e+07;
2.156+08;
1.396+08;
_;
1.586+08;
9.846+07;
1. 80e+08;
1.23e+08;
-;
1.586+08;
9.846+07;
1.80e+08;
1.23e+08;

RA;?,
0.28,-n;
1.17,-n;
4.66;n;
2.01;n;
1.70;n;
0.91',-y;
0.81,-y;
0.79;y;
*;n;
2.20;n;
1.01;n;
1.33;y;
0.91;n;
0.50,-n;
0.64;n;
*;n;
* ; n ;
0.77;y;
1.57;y;
1.27,-y;
1.03;y;
0.90;y;
0.78,-y;
1.55;y;
0.52;y;
0.44;y;
0.79;y;
1.25;y;
- ; - ;
1.56;y;
1 .24;y;
0.52;y;
0.44;y;
- • — •
1.56;y;
1.24;y;
0.52;y;
0.44;y;

RT;
28:27;
32:37;
34:43;
34:46;
34:59;
37:10;
40:02;
27:28;
NotFnd;
32:25;
34:10;
34:15;
34 : 37 ;
35:08;
36:22;
NotFnd;
NotFnd;
28:26;
32:36;
34:45;
37:10;
40:01;
27:25;
31:56;
34:14;
36:21;
28:09;
34:58;
28:27;
32:24;
34:42;
34:10;
37:31;
28:27;
32:24;
34:42;
34:10;
37:31;

Cone ;
0.084;
0.008;
0.009;
0.016;
0.029;
0.072;
0.353;
0.037;
* .
0.027;
0.024;
0.015;
0.012;
0.009;
0.042;
it .
* .
88.823;
96.600;
90.667;
90.554;
165.755;
71.034;
58.309;
59.442;
46.573;
79.619;
78.953;
92.462;
89.799;
97.264;
90.246;
95.784;
104.155;
154.058;
107.137;
150.619;
205.740;

DL;
0.0121;
0.0091;
0.0107;
0.0084;
0.0084;
0.0153;
0.0274;
0.0201;
0.0176;
0.0170;
0.0131;
0.0103;
0.0120;
0.0139;
0.0212;
0.0257;
0.0217;
0.0430;
0.0377;
0.0374;
0.0464;
0.0201;
0.0262;
0.0172;
0.1990;
0.0725;

-;
0.0236;
0.0176;
0.0554;
0.2554;
0.0926;
0.0279;
0.0184;
0.0544;
0.4006;
0.2481;

S/N1;?;
8;y;
3,-n;
4;y;
^ / J I
5;v;
•* t j t
7;y;
' 1 J '
13;y;
25;y;
6;y;
*;n;
9;y;
5;y;
3;y;
2;n;
l;n;
5;y;
*;n;
*;n;
3506;y;
10407;y;
7285;y;
3100;y;
10891;y;
8078,-y;
26346;y;
772, -y;
961;y;
3797;y;
6658;y;
10882;y;
40540;y;
5387;y;
llll;y;
1335;y;
10882 ;y;
40540; ry;
5387,-y;
1111, -y;
1335;y;

S/N2;?
34, -y
4;y
2;n
3,-n
6;y
w / Jr
17 ;y
115, -y
4,-y
*,-n
3,-n
5;y
3,-y
3;n
2,-n
9;y
*;n
*,-n
12546;y
19938;y
9638;y
6326,-y
22022;y
mod?
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
8004 ,-y ; no
10656,-y ; no
1090,-y
2118,-y
13492;y
8851;y
_; -
16440,-y
6985 ;y
1557 ,-y
2962,-y
-; -
16440,-y
6985;y
1557,-y
2962;y
no
no
no
no
no
no
no
no
no
no
no
no
no
no
Page

-------
OPUSquan   20-JUL-1998
                   Page 1
                                                                    Page 1 of 8

 Ent: 39 Name: Total Tetra-Furans  F:l  Mass: 303.902 305.899 Mod? no   #Hom:l

 Run: 12 File: al7jul98b    S:7  Acq:17-JUL-98 21:16:26 Proc:20-JUL-98 09:03:59
 Tables: Run: a!7ju!98b  Analyte: m8290-23-»  Cal: m8290-23-»Results: M8290-23*
 Version: V3.5 17-APR-1997 11:14:34  Sample text: 1072-0 xl/2
   Amount: 0.04
     Cone: 0.04
   Tox #1: -

Name

2,3,7,8-TCDF
of which 0.04
of which 0.04
     Tox #2:  -

#     RT Respnse
named and *
named and *
      Tox #3: -
    RA
1  27:28 1.3e+05  0.79 y
         1.3e+05
          Cone

           0.04
   unnamed
   unnamed
   Area  Height    S/N  Mod?
                                                   5.9e+04 1.2e+04 5.8e+00 y  n
                                                   7.4e+04 1.3e+04 4.5e+00 y  n
                                                                    Page 2 of 8

 Ent: 40 Name: Total Tetra-Dioxins F:l  Mass: 319.897 321.894 Mod? no   #Hom:4

 Run: 12 File: a!7ju!98b    S:7  Acq:17-JUL-98 21:16:26 Proc:20-JUL-98 09:03:59
 Tables: Run: a!7ju!98b  Analyte: m8290-23-»  Cal: m8290-23-»Results: M8290-23»
 Version: V3.5 17-APR-1997 11:14:34  Sample text: 1072-0 xl/2
   Amount: 0.11
     Cone: 0.11
   Tox #1: -
Name
of which 0.08
of which 0.08
     Tox #2:  -

#     RT Respnse
named and 0.02
named and 0.02
      Tox tt3: -
                                        RA
2,3,7,8-TCDD
1  25:16 4.7e+04  1.42 n
         4.76+04

2  26:55 1.8e+04  2.80 n
         1.8e+04

3  28:21 1.8e+04  0.99 n
         1.8e+04

4  28:27 3.1e+05  0.28 n
         3.le+05
                                              Cone

                                               0.01

                                                   3
                                               0.01
                                                   1
                                                   6
                                               0.00
                                                   e
                                                   £
                                               0.08
   unnamed
   unnamed
                  Area  Height
                                                                      S/N  Mod?
               2.7e+04 5.6e+03 3.9e+00 y  n
               1.9e+04 6.4e+03 4.1e+00 y  n
              L
               1.4e+04 3.1e+03 2.2e+00 n  n
               4.9e+03 1.9e+03 1.2e+00 n  n

               8.8e+03 3.1e+03 2.1e+00 n  n
               8.9e+03 2.5e+03 1.6e+00 n  n

               6.8e+04 l.le+04 7.9e+00 y  n
               2.4e+05 5.3e+04 3.4e+01 y  n
                                                                    Page 3 of 8

 Ent: 41 Name: Total Penta-Furans  F:2  Mass: 339.860 341.857 Mod? no   fHom:3

 Run: 12 File: a!7ju!98b    S:7  Acq:17-JUL-98 21:16:26 Proc:20-JUL-98  09:03:59
 Tables: Run: a!7ju!98b  Analyte: m8290-23-»  Cal: m8290-23-»Results: M8290-23»
 Version: V3.5 17-APR-1997  11:14:34  Sample text: 1072-0 xl/2
   Amount:  0.06
      Cone:  0.06
   Tox  #1:  -
of which 0.03
of which 0.03
     Tox #2: -
named and 0.04
named and 0.04
      Tox #3: -
Name
 2,3,4,7,8-PeCDF
                         RT Respnse
                                        RA
                       31:23  6.8e+04   1.27 n
                             6.8e+04
2  32:25 6.6e+04  2.20 n
         6.6e+04

3  32:29 2.0e+04  1.85 n
         2.0e+04
          Cone

           0.03
               3
               3
           0.03
               4

           0.01
    unnamed
    unnamed
                                   Area  Height
                                                                       S/N  Mod?
 3.8e+04 9.1e+03 5.8e+00 y  n
 3.0e+04 8.5e+03 2.7e+00 n  n

 4.6e+04 1.5e+04 9.4e+00 y  n
 2.1e+04 8.9e+03 2.8e+00 n  n
L
 1.3e+04 4.9e+03 3.1e+00 y  n
 7.2e+03 2.8e+03 8.8e-01 n  n

-------
OPUSquan   20-JUL-1998
                   Page 2
                                                                    Page 4 of 8

 Ent: 42 Name: Total Penta-Dioxins F:2  Mass: 355.855 357.852 Mod? no   #Hom:3

 Run: 12 File: a!7ju!98b    S:7  Acg:17-JUL-98 21:16:26 Proc:20-JUL-98 09:03:59
 Tables: Run: al7ju!98b  Analyte: m8290-23-»  Cal:  m8290-23-»Results: M8290-23»
 Version: V3.5 17-APR-1997 11:14:34  Sample text: 1072-0 xl/2
   Amount: 0.03
     Cone: 0.03
   Tox #1: -
Name
1,2,3,7,8-PeCDD
of which 0.01
of which 0.01
     Tox #2:  -

#     RT Respnse
named and 0.02
named and 0.02
      Tox #3: -
                                        RA
1  31:29 2.3e+04  0.69 n
         2.3e+04

2  32:24 4.2e+04  5.56 n
         4.2e+04

3  32:37 2.5e+04  1.17 n
         2.5e+04
                                              Cone

                                               0.01
                                                   S
                                                   1
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unnamed
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                  Area  Height
                                                                      S/N  Mod?
               9.4e+03 4.0e+03 1.8e+00 n  n
               1.4e+04 3.8e+03 3.4e+00 y  n
              L
               3.5e+04 1.3e+04 5.8e+00 y  n
               6.3e+03 1.5e+03 1.4e+00 n  n
              L
               1.4e+04 5.7e+03 2.6e+00 n  n
               1.2e+04 4.7e+03 4.2e+00 y  n

-------










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-------
OPUSquan   20-JUL-1998
Page 4

4 34:


5 34:


1,2,3,4,7,8-HxCDD 6 34:


1,2,3,6,7,8-HxCDD 7 34:


1,2,3,7,8,9-HxCDD 8 34:


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1.15 y


1.17 y


4.66 n


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1.70 n


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                                                                    Page 7 of 8

 Ent:  45 Name: Total Hepta-Furans  F:4  Mass: 407.782 409.779 Mod? no   #Hom:l

 Run:  12 File: al7ju!98b     S:7  Acq:17-JUL-98 21:16:26 Proc:20-JUL-98 09:03:59
 Tables: Run: al7ju!98b  Analyte: m8290-23-»  Cal: m8290-23-»Results: M8290-23»
 Version: V3.5 17-APR-1997  11:14:34   Sample text: 1072-0 xl/2

   Amount:  0.04     of which 0.04     named and *       unnamed
      Cone:  0.04     of which 0.04     named and *       unnamed
   Tox #1:  -            Tox #2: -         Tox #3: -
Name
                          RT  Respnse
                                         RA
 1,2,3,4,6,7,8-HpCDFl   36:22  5.8e+04   0.64  n
                             5.8e+04
        Cone    Area  Height     S/N  Mod?

          0.04
             2.3e+04  8.3e+03  4.7e+00 y   n
             3.5e+04  1.Oe+04  9.le+00 y   n

-------
OPUSguan   20-JUL-1998
                  Page 5
                                                                   Page 8 of 8

 Ent: 46 Name: Total Hepta-Dioxins F:4   Mass:  423.777  425.774 Mod? no   #Hom:4

 Run: 12 File: a!7ju!98b    S:7  Acq:17-JUL-98 21:16:26  Proc:20-JUL-98 09:03:59
 Tables: Run: a!7ju!98b  Analyte: m8290-23-»  Cal: m8290-23-»Results: M8290-23*
 Version: V3.5 17-APR-1997 11:14:34  Sample text:  1072-0 xl/2
   Amount: 0.18
     Cone: 0.18
   Tox #1: -
Name
of which 0.07
of which 0.07
     Tox #2:  -

#     RT Respnse
named and 0.10
named and 0.10
      Tox #3:  -
                                        RA
                   1  36:21 3.2e+04  2.61 n
                            3.2e+04

                   2  36:35 1.3e+05  1.07 y
                            1.3e+05

l,2,3,4,6,7,8-HpCDD3  37:10 1.5e+05  0.91y
                            1.5e+05

                   4  37:31 4.9e+04  4.50 n
                            4.9e+04
          Cone

           0.02

               £
           0.06
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           0.07
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unnamed
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Area  Height    S/N  Mod?
                                2.3e+04 7.6e+03 5.2e+00 y  n
                                8.9e+03 2.6e+03 2.2e-^00 n  n
                                6.6e+04  2.0e+04  1.4e+01 y  n
                                6.2e+04  1.9e+04  1.6e+01 y  n
                               7
                                6.9e+04  1.9e+04  1.3e+01 y  n
                                7.6e+04  2.0e+04  1.7e+01 y  n
                               2
                                4.0e+04  l.le+04  7.4e+00 y  n
                                8.8e+03  2.7e+03  2.3e+00 n  n
                                                                                                         032

-------
File: A17JUL9HB Acq:
17-JUL-1998 21:16:26 Exp: EXP_M23_DB5_OVATION
Voltage SIR EI+ GC Autospec-UltimaE Paradigm
Sample #7 Text: 1072-0 xl/2 ALS #7
319.8965 S:7 SMO(1,3)
100%


50_
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24:00
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	 24 loo'
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BSUB(128,15,-3.0) PKD (3 , 3 , 3 , 0 . 10%, 1432 . 0 , 1 . 00%

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A1.93E4 Ag 38_3
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BSUB(128,15,-3.0) PKD (3 , 3 , 3 , 0 . 10%, 9328 . 0, 1 . 00%



25 loo' ' ' ' 26 100 	 27 loo'
BSUB(128,15,-3.0) PKD (3 , 3 , 3 , 0 . 10%, 3352 . 0, 1 . 00%


25:00 	 26 100 	 27loo'
BSUB(128,15,-3.0) PKD (3 , 3 , 3 , 0 . 10%, 6380 . 0 , 1 . 00%



25 loo 	 26 100 	 27 loo'
PKD (3, 3, 3, 100. 00%, 0.0,1. 00%, F,F)
:1324:34 25;38 26:05 26:4927:


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-------
File: A17JUL98B—Acq: 17-JUL-1998 21:16:26Exp: EXP_M23_DB5_OVATION Voltage SIR EI+GC Autospec-UltimaEParadigm
Sample #7  Text: 1072-0 xl/2  ALS #7
355.8546 S:7 F:2 SMO(1,3) BSUB(128,15,-3.0) PKD(3,3,3,0.10%,2224.0,1.00%,F,F)
100%                                                                           A3.52E4


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     30:12  30:24  30:36  30:48  31:00  31:12  31:24  31:36   31:48  32:00  32:12  32:24  32:36  32:48  33:00  33:12    Time
357.8517 S:7 F:2 SMO(1,3) BSUB(128,15,-3.0) PKD(3,3,3,0.10%,1116.0,1.00%,F,F)
100%,
                                                                                      A1.15E4
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367.8949 S:7 F:2 SMO(1,3) BSUB(128,15,-3.0) PKD(3,3,3,0.10%,5820.0,1.00%,F,F)
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                                                                                      A1.73E8
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                               '  3i!66 ' 3i!i2 ' 3l!24 ' 3l!36 ' SlUs ' 32!6d ' 32!i2 ' 32124 ' 32136   32148 ' 33166 ' 33!l2    Time
369.8919 S:7 F:2 SMO(1,3) BSUB(128,15,-3.0) PKD(3,3,3,0.10%,1936.0,1.00%,F,F)
100%                                                                                  A1.10E8
     3b!i2 ' 3bl24 ' 36I36 '
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                                                                                                                 _1.9E7
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366.9792 S:7 F:2 SMO(1,3) PKD(3 , 3 , 3 , 100 . 00%, 0 . 0, 1 . 00%, F, F)
lOOi          30:27  30^4030:50   31:06  31:1631:26  31:39    31:55
                                              3l!24 ' 3l!36 ' 3l!48 ' 32160 ' 32!l2 ' 32!24 ' 32i36 ' 32!48 ' 33!6o ' 33ll2    Time
 so:
                                                                            32^18
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-------
File: A17JUL98B Acq: 17-JUL-1998 21:16:26
Sample t7 Text: 1072-0 xl/2
ALS #7
389.8156 S:7 F:3 SMO(1,3) BSUB(128, 15, -3 . 0 )
100%
so:
-


Exp : EXP_M2 3 _DB 5_OVAT I ON

PKD( 3, 5, 2, 0.10%, 1576. 0,1
Voltage SIR EI+ GC Autospec-UltimaE Paradigm

.00%,F,F)
A6.33E4
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1002
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100%
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7E3
OEO
Time

OE7
5E7
OEO
Time

6E7
8E7
OEO
Time

7E8
6E7
OEO
Time
o
CO

-------
File: A17JUL98B Acq: 17-JUL-1998 21:16:26 Exp: EXP_M23 DB5_OVATION Voltage SIR EI+ GC Autospec-UltimaE Parad
Sample #7 Text: 1072-0 xl/2 ALS #7
423.7767 S:7 F:4 SMO(1,3) BSUB (128 , 15 , -3 . 0) PKD{3 , 3 , 3 , 0 . 10% , 1476 . 0 , 1 . 00%, F, F)
100% A6.63E4 A6.93E4
I /\ /\ A3.97E4
A2.33E4 / \ / \ A
- /V ZA^ /-L__ JL\^ A3 99E3
™*"T-i — i — i — | — i — i — i — i— i — r— i — i — i — i — i — |— i — r-i — i — i — i — i — i — r— i — r-r-i — r"r T r—i T i i i r | i i i r i [ i r
36:00 36:12 36:24 36:36 36:48 37:00 37:12 37:24
425.7737 S:7 F:4 SMO(1,3) BSUB (128, 15, -3 . 0) PKD(3 , 3 , 3 , 0 . 10%,
100% A6.22E4 A7 . 62E4
A A
: A8.93E3 / \ / V A8
o- 	 ~ 	 x-\ _2 	 \ — . 	 ^J. 	 :^-~~^_/
36100 36ll2 36124 36136 36l48 37:00 37:12 37:24
435.8169 S:7 F:4 SMO(1,3) BSUB (128, 15, -3 . 0) PKD(3 , 3 , 3 , 0 . 10%,
lOOi A1.15E8
/I
n " ^— -^ / 	 ,
" ' i i i i i i i i i i i i l i i i I l i i ri |"l 1 i l i "T— I-T i i r i i i 1 l l II l l 1 i II 1
36:00 36ll2 36124 36136 36:48 37:00 37:12 37:24
437.8140 S:7 F:4 SMO(1,3) BSUB (128, 15, -3 . 0) PKD(3 , 3 , 3 , 0 . 10%,
100% A1.11E8
-I /V
a^~^_ y ^^—
36100 36ll2 36124 36:36 36148 37:00 37:12 37:24
430.9728 S:7 F:4 SMO(1,3) PKD(3 , 3 , 3 , 100 .00%, 0 .0, 1 . 00%,F,F)
100% 36:04 36:23 36:41 36_:57 37:09 37:19
so:
i i i i 1 	 | i i i i i | i i i i i | i i i i i | i i i i i | i i i i i | 	 | i i
36:00 36:12 36:24 36:36 36:48 37:00 37:12 37:24
> i ' i i i i ' ' i 	 1 ' ' ' ' ' 1 	 | i i i i i i i i i i i | i i i i i
37:36 37:48 38:00 38:12 38:24 38:36 38:48 39
1196. 0,1. 00%, F,F)
.83E3
37136 37148 38166 38112 38124 38136 SsUs 39
9628. 0,1. 00%, F,F)
'37I36 37148 38166 38112 38124 3s!36 38148 39l
4540. 0,1. 00%, F,F)
igm
2.2E4
O.OEO
00 Time
2.2E4
O.OEO
00 Time
3 . OE7
L1.5E7
LO.OEO
00 Time
2 . 9E7
_1.4E7
_O.OEO
' 37136 37148 38166 38112 38l24 38136 SsUs 39:00 Time
37:34 37:48 38:07 38:21 38:32 38:48 1 . 1E8

_5.5E7
_O.OEO
' 37136 ' 37148 ' 38166 38li2 38124 38136 38:48 39loO Time
CJ

-------
Pile: A17JUL9BB Acq: 17-JUL-1998 21:16:26 Exp:
Sample #7 Text: 1072-0 xl/2 ALS #7
457.7377 S:7 F : 5 SMO(1,3) BSUB (128 , 15 , -3 . 0 ) PKD(3
100%
so:
0"
459.
iooa
50J
469.
100S
50J
0"
471.
1004
50J
0"
454.
1002
50J
0"

39:12 39:24 39:36 39:48
7348 S:7 F:5 SMO(1,3) BSUB (128 , 15, -3 . 0) PKD(3

39ll2 39124 39136 39S48
7780 S:7 F:5 SMO(1,3) BSUB (128, 15 , -3 . 0) PKD(3

39ll2 39124 39136 39\48
7750 S:7 F:5 SMO(1,3) BSUB (128, 15 , -3 . 0) PKD(3

39ll2 39124 39!36 39 Us
9728 S:7 F:5 SMO(1,3) PKD(3 , 3 , 3 , 100 . 00%, 0 . 0 , 1
39:10 39:21 39:28
/
1 1 1 1 | ' 1 ' I1 1 ' 1 | 	 | i . i . . | .
39:12 39:24 39:36 39:48
EXP_M23_DB5_OVATION Voltage SIR EI+ GC Autospec-UltimaE Parad
, 3, 3, 0.10%, 2700. 0,1. 00%, F,F)
A2.63E5
_ w 	
40:00 40:12 40:24 40:36 40:48 41
, 3, 3, 0.10%, 656. 0,1. 00%, F,F)
A3 . 24E5
J\_
40:00 40:12 40:24 40:36 40:48 41:
, 3, 3, 0.10%, 3164. 0,1. 00%, F,F)
Al . 57E8
J\_
40:00 40:12 40:24 40:36 40:48 41:
, 3, 3, 0.10%, 1760. 0,1. 00%, F,F)
Al . 75E8
J\_
igm
7.4E4
_3.7E4
O.OEO
00 Time
7.7E4
L3.8E4
' O.OEO
00 Time
3.4E7
_1.7E7
O.OEO
00 Time
3.9E7
.1.9E7
O.OEO
4o!ob 40:12 40:24 40:36 40:48 41:00 Time
.00%,F,F)
39:56 40;05 40il7 40:3040:36 40:45 40:51 1.2E8

40-00 40:12 40:24 40:36 40:48 41
_6.1E7
O.OEO
00 Time
O
CO

-------
File: A17JUL98BAcq: 17-JUL-1998 21:16:26  Exp: EXP_M23_DB5_OVATION Voltage SIR El4-  GC Autospec-UltimaE  Paradigm
Sample #7  Text: 1072-0 xl/2  ALS #7
303.9016 S:7 SMO(1,3) BSUB(128,15,-3.0) PKD(3,3,3,0.10%, 2092.0,1.00%,F,F)
100%                                                                 A5.87E4
                 24:00          25:00          26:00           27:00
305.8987 S:7 SMO(1,3) BSUB(128,15,-3.0} PKD(3,3,3,0.10%, 2872.0,1.00%,F,F)
100%                                                                A7.42E4
                             A1.93E4                   A1.91E4
 50
                                                                              28:00
                                                            29:00
30:00  Time

     1.4E4

    !_7. 1E3

     O.OEO
                 24:00          25:00          26:00           27:00           28:00          29:00           30:00  Time
315.9419 S:7 SMO(1,3) BSUB(128,15,-3.0) PKD(3 , 3, 3, 0.10%,4228.0,1.00%,F,F)
100%                                                                A1.6.5E8                                     ^3.4E7

24:00 25:00 26:00 27:00 28:00 29:00 30:C
.1.7E7
_O.OEO
)0 Til
317.9389 S:7 SMO(1,3) BSUB(128,15,-3.0) PKD(3,3,3,0.10%, 5460.0,1.00%,F,F)
100%                                                                A2.UE8
  O
                                                             -r
                 24 loo'          25TOO          26iOO          27iOO
375.8364 S:7 SMO(1,3) BSUB(128,15,-3.0) PKD(3,3,3,100.00%,424.0,1.00%,F,F)
100%
                                                                                                                 4. 4E7

                                                                                                                 .2.2E7

                                                                                                                 O.OEO
 50J
                                                                              28:00           29:00

                                                                                    28:26
             23:48
                                  25:07           26:09
                                               M/L
                                                         26:37
 ^ j ;
A

                                                 ~T-
                 24:00           25:00          26:00
316.9824 S:7 SMO(1,3) PKD(3,3,3,100.00%,0.0,1.00%,F,F)
100%  23:18  23:47  24:1324:34           25^38  26^05.
                                                                   27:18
                                                                                                                 O.OEO
                                                                                                             30:00   Time

                                                                                                          29:52!  7.2E7
' ' V
24:00 25:00 26:00 27:00 28:00 29:00 30:C
_3 . 6E7
_O.OEO
)0 Time

-------
      File: A17JUL98BAcq:  17-JUL-1998  21:16:26Exp:  EXP_M23_DB5_OVATION Voltage SIR EI+GC Autospec-UltimaEParadigm
      Sample #7  Text: 1072-0 xl/2  ALS  #7
      339.8597 S:7 F:2 SMO(1,3) BSUB(128,15,-3.0)  PKD(3 , 3,3,0.10%,1580.0,1.00%,F,F)
      100%,                                                                             A4.56E4                            1. 5E4
                                                   A3.78E4
       50J   -- .- —                                 r\                 A1.38E4
o
CJ
CO
           30:12  30:24  30:36  30:48  31:00   31:12  31:24  31:36  31:48  32:00  32:12  32:24  32:36  32:48  33:00  33:12
      341.8568 S:7 F:2 SMO(1,3) BSUB(128,15,-3.0 ) PKD(3,3,3,0.10%,3144.0,1.00%,F,F)
      100%,                                        A2.98E4                             A2.Q7E4
             ~T "I" i—'—i—i—|—i—i—i—i—i—I—i—r~i—i—i—[—i—i—r~-r~r—i—i—i—i—i—rnj—i—i—i—i—i—i—i—i—r "i i—i—i—i—i—i—r—i—i—i—i—i—i—i—r—i—i—r—i—i—i—i—i—i—r—r—i—i—i—i—i—r—i—i—i—i—i—i—i—i—i—i—f—i—i—r*i—IT i—r~r
           30:12  30:24  30:36  30:48   31:00  31:12  31:24  31:36  31i48  32:00  32:12  32:24   32:36   32:48   33:00   33:12    Time
      351.9000 S:7 F:2 SMO(1,3) BSUB(128,15,-3.0) PKD(3 , 3,3 , 0.10%,2132.0,1.00%, F, F)
      100%                                                                            A2.47E8
       50J
                                                                      A1.63E8
                                                                                                     8.7E7

                                                                                                    L4.3E7
                                                                                                                         O.OEO
           30:12  30:24  30:36  30:48  31:00  31:12  31:24  31:36  31:48  32:00  32:12  32:24  32:36  32:48   33:00   33:12     Time
      353.8970 S:7 F:2 SMO(1,3) BSUB(128,15,-3.0) PKD(3,3,3,0.10%,3400.0,1.00%,F,F)
      100%,                                                                           A1.58E8
       50J

        OJ
                                                                      A1.05E8
                                                                                                     5. 6E7

                                                                                                    _2.8E7

                                                                                                     O.OEO
           30:12   30:24  30:36  30:48  31:00  31:12  31:24  31:36  31:48  32:00  32:12   32:24   32:36 '  32U8 ' 33166 ' 33:12     Time
     409.7974  S:7  F:2 SMO(1,3) BSUB(128,15,-3.0) PKD(3,3,3,100.00%,3912.0,1.00%,F,F)
     100%
       50J

       OJ
                                                31:16
                                                                                        33:01
:24
                           30
 1.1E4

.5.4E3

 O.OEO
          ~r i i—i—r T n—i—i—i—i—i—i—i—»—i—i—i—i—i—j—i—i—T-T—r—i—i—i—r-r'-i i—r—i—i—i—i—i—i—i—i—i—r—i—i—i—i—i—r—i—i—i—1~i—r~i—i—i—r—i—r~T—i—i—i—i—r—i—i—i—i—i—i—r—i—i—i—i—i—i—i—i r'-r1 T I—i—i i i  r r r i
           30:12   30:24   30:36   30:48  31:00  31:12  31:24  31:36   31:48   32:00   32:12   32:24   32:36  32:48  33:00  33:12    Time
66.
009
50_
o:
9792 S:7 F:2 SMO(1,3) PKD(3,3,
30:27 30:4030:50


3, 100. 00%, 0.0, 1.00%
31:06 31:16 31:26

,F,F)
31:39 31:55 32:09 32:25 32:46 33:00 8 . OE7

_4 . OE7
O.OEO

-------
    File:  A17JUL98BAcq: 17-JUL-1998 21:16:26Exp: EXP_M23_DB5_OVATION Voltage  SIR  EI+GC Autospec-UltimaEParadigm
    Sample #7  Text: 1072-0 xl/2  ALS #7
    373.8207 S:7 F:3 SMO(1,3) BSUB(128,15,-3.0) PKD(3,5, 2, 0.10%, 1840.0,1.00%,F,F)
    1004          .. 	                 A2.3.8E4                                                                       1.0E4
                  A1.21E4
                                             A1.19E4
                                                   A6.89E3
                                                                       A5.50E3    A3.25E3
                                                                                   .XV
                                                                                                                     _5.1E3

                                                                                                                       O.OEO
         T—i—|~~T—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—r™|—i—i—i—i—i—]—i—i—i—i—i—1—i—i—i—i—i—I—i—i—i—i—i—1—i—i—i—i—i—]—i—i—i—i—r~—i—i—i—i—i—i—i—i—T~T—i—r~~r
         33:24    33:36    33:48   34:00    34:12    34:24   34:36   34:48    35:00    35:12    35:24   35:36    35:48  Time
    375.8178 S:7  F:3 SMO(1,3) BSUB(128,15,-3.0) PKD(3 , 5,2,0.10%,1544.0,1. 00%, F, F)
    1004                                  A2.35E4
                 A8.49E3
         33:24    33:36    33:48   34:00    34:12    34:24   34:36    34:48    35:00    35:12    35:24    35 36    35 48  Time
   383.8639  S:7  F:3  BSUB(128,15,-3.0) PKD{3,5,2,0.10%, 39736.0,1.00%,F,F)
   1004                                  A9.29E7
     50J

      ol
A5.24E6
                  4.4E7

                 L2.2E7

                 ^O.OEO
        I  I I  I I  T~l  i*"i ~T i  I—i—i—I—i—i—i—i—i—I—p—i—r-^i—r—f—i—i—i I  I I i  i i—I—i  |n I  i—i—i—i—i—i—i—i—i—r—i—i—i—i—i—i—r—i—p—i—i—i—i i  i—i—i—i  i i  i i  i—i—r
         33:24    33:36    33:48   34:00    34:12    34:24   34:36    34:48    35:00   35:12   35:24   35:36    35:48  Time
   385.8610  S:7  F:3 BSUB(128,15,-3.0) PKD(3,5,2,0.10%, 54872.0,1.00%,F,F)
   100%                                  A1.80E8                                                                      8.5E7
    50J

     OJ
A1.06E7
                 _4.3E7

                  O.OEO
        i—r—i—i—i T^T I'i n i—i—i—r—!—i—i—i—i—i—i—i—i—r-i—i—f—p—i—i  I I  I j—i i  i—ill—i—i—i—i—r—i—i—i—i—i—i—i—p—i—r-i—i—i i  i i—r—i—r—i—i—r—i—i—>  i i  i i
         33:24   33:36   33:48    34:00    34:12   34:24    34:36    34:48    35:00   35:12    35:24    35:36    35:48  Time
   445.7555 S:7 F:3 SMO(1,3)  BSUB{128,15,-3.0)  PKD(3,3,3,100.00%,2108.0,1.00%,F,F)
   1004                                                             34:46    34:58
                                   33:59 34:07  34:17
                             I '  ' '  ' ' I  '
                                                                                              I	1	1 ' J I 'f	1	1	1	1	1	1	1	T	1	1
         33:24   33:36    33:48    34:00    34:12    34:24    34:36    34:48    35:00    35:12    35:24    35:36    35:48  Time
   380.9760 S:7 F:3 SMO(1,3)  PKD(3,3,3,100.00%,0.0,1.00%,F,F)
   1004               33:42    33:53 34:0234:09   34:1934:27   34:3834:45
    50J

     OJ
                                                             34:59
-J5; 30 35:37^
                                                                                                                     .1.7E8
                                                                                                    _8.6E7
                                                                                                                      O.OEO
        1 r-i r—II  I I  i i  i i  i i i  i i  i i  i |  i i  i i iI i  r—i  i i—i  i—i—i—i—i—i—i—i—i—i—i—i—i—i—r—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—r—i—I—i—I—r—i—i—i—i—i—r
        33:24    33:36    33:48    34:00    34:12    34:24    34:36    34:48   35:00    35:12    35:24    35:36    35:48  Time
o
$

-------
File:  A17JUL98BAcq:  17-JUL-1998 21:16:26Exp:  EXP_M23_DB5_OVATION Voltage SIR EI+GC Autospec-UltimaEParadigm
Sample #7   Text:  1072-0 xl/2  ALS 17
407.7818 S:7  F:4  SMO(1,3)  BSUB(128,15,-3.0)  PKD(3,3,3,0.10%,1764.0,1.00%,F,F)
100%              A2.27E4                                                                                        _1.1E4
  50-

   OJ
                                                                                                             _5.4E3

                                                                                                              O.OEO
       36:00  36:12  36:24  36:36  36:48  37:00  37:12  37:24  37:36  37:48  38:00  38:12  38:24  38:36  38:48  39:00
409.7788  S:7  F:4  SMO(1,3)  BSUB(128,15,-3.0)  PKD(3,3,3,0.10%,1116.0,1.00%,F,F)
100*               A3.54E4
       I  I I i I I I  I I I I I I I  I r i I i I I  I I i I i I	I	| i i i i  i | i r*i i  i |	I I I I I I  I	I  I I I I I I	I I  I I I I I I  I I I I I
       36:00  36:12  36:24  36:36  36:48  37:00  37:12  37:24  37:36  37:48  38:00  38:12  38:24  38:36  38:48  39:00
417.8253  S:7 F:4  SMO(1,3)  BSUB(128,15,-3 . 0) PKD(3,3,3,0.10%,10320.0,1.00%,F,F)
100%,                                                      A5.40E7
                  A3.38E7
 50-
                                                                                                              1,

                                                                                                             .6.
       36)00  36)12  36.:24  36.:36  36.:48  37)00  37)12  37)24  37)36  37:48  38:00  38:12  38:24  38:36  38:48  39:00
419.8220 S:7 F:4 SMO(1,3)  BSUB(128,15,-3.0)  PKD(3,3,3,0.10%,10620.0,1.00%,F,F)
100%,                                                      A1.23E8                                                 ,.3
                  A7.61E7
 50J
  Oj
                                                                                                             .1.


i i i i  I i i i i i  i i i f i i  iT i i i i I  i i i i i i i i i  i i I i i i  i i I i i i i  i I iri i i i  i i i i i i  i i i i i i i  i i > i i I  i i i i i I i  i i i i i i  i i i i i i 'i i i i i   '
  36:00  36:12  36:24  36:36  36:48   37:00   37:12  37:24  37:36  37:48  38:00  38:12  38:24  38:36  38:48  39:00
 Time

,1E4

.4E3

.OEO
 Time

,4E7

 9E6

,OEO
 Time

 1E7

 6E7

 OEO
 Time
479.7165 S:7 F:4 SMO(1,3) BSUB(128,15,-3.0) PKD(3,3,3,100.00%,3500.0,1.00%,F,F)
100%,                          ,,.,„             37^10                            38:07
                                                                                                             r-8.
      r i i" -i t—r-r-i—i—i—i—i—i—i—i—i—i—i—i—r—i—i—i—i—i—i—r—i—rn—i—i—i—i—i—i—i—i—i—i—i—m—i—i—i—i—i—i—i—i—i—i—i—n—i—i—i—i—i—n—[—i—i—i—i—i—i—i—i—i—i—i—i—i—i—r~\—r-|—r~r-i—i—i—i—i—i—i—r~r~ T'
       36:00  36:12  36:24  36:36  36:48  37:00  37:12  37:24  37:36  37:48  38:00  38:12  38:24  38:36  38:48   39:00
430.9728 S:7 F:4  SMO(1,3)  PKD(3,3,3,100.00%,0.0,1.00%,F,F)
100%,	36j_04       36:23     36:41   36:57  37:09 37:19   37:34   37:48      38:07   38:21  38:32     38:48      _1
                                                                                                               .OEO
                                                                                                                 Time

                                                                                                               ,1E8

                                                                                                               ,5E7

                                                                                                               .OEO
                                                                                                                 Time
       36166 ' 36112 ' 36124 ' 36:36  36:48  37:00  37:12  37:24  37:36  37:48  38:00  38:12  38:24  38;36  38:48  39:00

-------
   File: A17JUL98B  Acq:  17-JUL-1998  21:16:26  Exp: EXP_M23_DB5_OVATION Voltage  SIR EI+GC Autospec-UltimaE—Paradigm	
   Sample #7  Text: 1072-0 xl/2  ALS  #7
   441.7427 S:7 F:5 SMO(1,3) BSUB(128,15,-3.0) PKD(3,3,3,0.10%,900.0,1.00%,F,F)
   100%,                                                           A7.83E3                                             4.2E3
    50J

     OJ
-i	1	1	1	1	r-
    39:24
                                     T.
                                                           "1
                                                    ~T - 1 i  i - 1 - 1 - 1 - 1 - r  ;•  i ....... i
                                                        40:36      40:48
                                                                                                ^2. 1E3

                                                                                                 O.OEO
                                                                                            1 - 1 - r
                                                                                             41:00  Tim
                                                                                                                    ..5.5E3
                                                                                                1.2.7E3
              39:12       39)24       39)36      39)48       40)00      40)12      40)24
   443.7398 S:7 F:5 SMO(1,3) BSUB(128,15,-3.0) PKD(3,3,3,0.10%,1924.0,1.00%,F,F)
   100%                                                             40:11
    50J

     OJ
                            39:28
                                                                      40:50 40:57
                                     T
                                                T
                                                           -i	1	1	1	1	1	1	1	1	1	1	1	1	1	1	r-
                                                           40:24       40:36       40:48
                                                                                                                     .O.OEO
             39:12       39124       39)36       39)48       40)00       40:12
   469.7780 S:7 F:5 SMO(1,3) BSUB(128,15,-3.0} PKD(3,3,3,0.10%,3164.0,1.00%,F,F)
   100ft                                                   A1.57E8
    50.:

     ol
                                                                              41:00  Time

                                                                                  3.4E7

                                                                                 .1.7E7
                                                                                                _O.OEO
             39:12      39:24       39:36       39:48      40:00       40:12       40:24
   471.7750 S:7 F:5 SMO(1,3) BSUB(128,15,-3.0} PKD(3,3,3,0.10%,1760.0,1.00%,F,F)
   100%                                                  A1.75E8
                                                                      40:36
                                                                   40:48
     O
                                                                                             41:00  Time

                                                                                               _3 . 9E7

                                                                                               .1 . 9E7
             39:12      39:24      39:36      39:48      40iOO       40)12       40)24
   513.6775  S:7  F:5 SMO(1,3)  BSUB(128,15,-3.0)  PKD(3,3,3,100.00%,468.0,1.00%,F,F)
   100%                                                    40:01
                                                                      40:36
                                                                   40:48
    50^

     oJ
39:20
                              39:53
                                                                           40:41
                                                                                                Q -
                                                                                            41:00  Time
                                                                                  7 . OE3

                                                                                 13 . 5E3
                                                                                    40:51
                                                                                                                    .O.OEO
             '  |  i  i  "  i  > |  i  i  i  i  i	1	1	1	1	1	'	1—i	1	1	1	1	1	1	1	1	1	1	1	1	1	1	1	1	1	1	1	1	1	1	1	1	1	1 *^ T ~j" ' l	11 I 'i	F—r
             39:12      39:24      39:36      39:48      40:00      40:12      40:24       40:36       40:48      41:00  Time
   54.9728  S:7  F:5  SMO(1,3)  PKD(3,3,3,100.00%,0.0,1.00%,F,F)
   00%,     39:10	39:21 39:28	39:56    40:0j	40.^17
    o
                                                                 40:3040:36   A0;45
             39ll2
    39124
39536
                                                                                                .1.2E8
                                                                                                                    _6.1E7
                                                                                                                     O.OEO
                         39148
4o!ob
4o!l2
40I24
                                                                                          40:36
                                                                   40:48
                                                                                            41:00  Time
O
fi

-------
                                                                        Paradigm Analytical Labs
Analytical Data Summary Sheet
Analyte
2,3,7,8-TCDD
l,23A.^ , , -_,;
1, 2,3A778-HxCDD
'. ' '.
1,2,3,7,8,9-HxCDD
l^A&T.&i&CtoD'^^'*^

OCDD
2,3,7,8-TCDF
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
1,2,3,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
OCDF
Total TCDDs
Total PeCDDs
Total HxCDDs
Total HpCDDs
Total TCDFs
Total PeCDFs
Total HxCDFs
Total HpCDFs
TEQ (ND=0)
TEQ (ND=l/2)
Concentration
0.0021
• ^C$MJ|$|^^!
"""ND" "**

EMPC
%•
0.0186
0,0061 "'"*'
0.0023
ND
0.0026
EMPC
ND
ND
0.0043
ND
0.0036
0.0085
0.0036
0.0072
0.0052
0.0632
0.0100
0.0044
0.0044
0.0034
0.0037
^vSaPI
0.0005

0.0008**

0.0006
#, r~ V'JT " ••< ' • , •
0.0008
'^OjQ006
0.0005
0.0005
0.0004
0.0003
0.0004
0.0004
0.0005
0.0006
0.0009
0.0005
0.0005
0.0006
0.0005
, 0.0006
0.0005
0.0003
0.0005


sSSFU

•T-.S ;-,a;;-T.,, „

#$jjflj$i~
00021






0.0010





0.0105
0.0056
0.0140
0.0128
0.0772
0.0128
0.0068

0.0040
0.0042
. .«£.;.-•:-.
28:29
32:38

J''-fij44;;|
34:58

40:02
27:28
31:58

34:11
34:15
34:38

36:22
37:32
40:11










Ratio
0.65
1.58

0.61
OQ1
\j*y A
0.88
0.73
1.58

1.22
0.97
0 70
w. / \J
0.94
0.57
0.95










Qualifier





•;, . •



















ITEF
ITEF
Client Information

Project Name:
Sample ID:

Laboratory Information
Texas Lime Kiln
M23-I-3
Project ID:
Sample ID:

Collection Date:
Receipt Date:
ExtracJien Date:
Analysis Date:
Sample Information

Matrix:
Weight/Volume:
Moisture / Lipids:

                                                 Air
                                                  1
                         WfialjCM:
                    a20jul98b-17
                     ra8290-23-071798
                                                                                              043
                                          1/2

-------
                                                                       Paradigm Analytical Labs
                              Analytical Data Summary Sheet
Labeled
Standard
Extraction Standards
13C12-2,3,7,8-TCDD
l3C«-l'A3>?8-I>eC;DD/ .
13Cirl,2,3,6,7,8-HxCDD
3 ''*''' f**'T •'*''*'-•.'** f\ ft J^jr I, ' ,, -i

^12 *^?* < £Tt ;> IT* .; *\T^'- ;
13C12-OCDD
13C,r2,3,7,8-TCDF
13C12-l,2,3,7,8-PeCDF
"Cu-lAS.ej.S-HxCDF
13C12-l,2,3,4,6,7,8-HpCDF
Sampling Standards
37Cl4-2,3,7,8-TCDD
13C12-2,3,4,7,8-PeCDF
13C,2-l,2,3,4,7,8-HxCDD
13C12-l,2,3,4,7,8-HxCDF

Injection Standards
13C12-1,2,3,4-TCDD
13C12-l,2,3,7,8,9-HxCDD
Expected
-***®M!;:3,

4
"f*** "
4
:.',', ^* ^1«:|l¥ ' V?'' ''*' "^

u- ', -^^^
8
$"*?•'
4
4
4

4
4
4
4
4

'~? , '- •-•'"

J|easured
l"'~?~(N& ••'

2.63

2.71
^^^^^^^^^ *£"'*

W^^^-"
5.33
2.37
2.29
2.48
2.60

3.93
3.88
4.16
4.14
4.03



^"ggj^mt:!


65.8

67.7
" ^ ~, • ^^^A''^ l< ^

>***,^*^; -"'-
66.6
59.3
57.3
62.0
65.1

98.2
97.0
103.9
103.5
100.8

' " f " ".

$^ciKi,J
(mlB.)

28:27
'
34:46
|iV^.^j— "",i ^i - •-

^4^%?^"^^^^ t
40:02
27:26
31:57
34:15
36:21

28:29
32:24
34:42
34:10
37:31

28:11
34:59
•^•Jfci&l, ,
'**"''-
ft ,-x
0.77

,
1.24
_ — ^

'"„>< ^- • -- -"
0.89
0,7,8
1.55
0.52
0.45


1.56
1.24
0.52
0.44

0.78
1.24
Qualifier






















Client Information
Project Name:
Sample ID:

Laboratory Information

Project ID:
Sample ID;       ;.;
Texas Lime Kiln
M23-I-3
L1072
1072-1
Sample Information

Matrix:
Weight/Volume:
Moisture / Lipids:
                                                  Air
                                                   1
                                                  0.0
                                                                         a20ju!98b-5
                                                                         a20ju!98b-l
                                                                         a20ju!98b-2
                                           2/2

-------
Of n 21-JUL-1998 Page
Filename a20ju!98b
Sample 5
Acquired 21-JUL-98 00:16:40
Processed 21-JUL-98 13:42:31
Sample ID 1072-1 xl/2
Cal Table m8290-23-071798
Results Table M8290-23-072098B
Comments
Typ Name; Resp;
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
ES/RT
ES
ES
ES
ES
ES/RT
ES
ES
ES
JS
JS
CS
CS
CS
CS
CS
SS
SS
SS
SS
SS
2,3,7,8-TCDD; 3.89e+05;
1,2, 3,7,8-PeCDD; 4.036+04;
1,2,3,4,7,8-HxCDD; *;
1,2,3,6,7,8-HxCDD; 1.02e+05;
1,2,3,7,8,9-HxCDD; 1.36e+05;
1,2,3,4,6,7,8-HpCDD; 3.38e+05;
OCDD; 8.22e+05;
2,3,7,8-TCDF; 1.15e+06;
1,2,3,7,8-PeCDF; 1.756+05;
2,3,4,7,8-PeCDF; *;
1,2,3,4,7,8-HxCDF; 1.77e+05;
1,2,3,6,7,8-HxCDF; 8.98e+04;
2,3,4, 6,7, 8-HxCDF; 4.17e+04;
1,2,3,7,8,9-HxCDF; *;
1,2,3,4,6,7,8-HpCDF; 2.77e+05;
1,2,3,4,7,8,9-HpCDF; 5.47e+04;
OCDF; 1.71e+05;
13C-2,3,7,8-TCDD; 3.64e+08;
13C-l,2,3,7,8-PeCDD; 2.48e+08;
13C-1 , 2,3,6,7, 8-HxCDD; 3 . Ole+08 ;
13C-1 , 2,3,4,6,7, 8-HpCDD; 2 . 37e+08 ;
13C-OCDD; 3.52e+08;
13C-2,3,7,8-TCDF; 4.12e+08;
13C-l,2,3,7,8-PeCDF; 3.47e+08;
13C-l,2,3,6,7,8-HxCDF; 3.17e+08;
13C-l,2,3,4,6,7,8-HpCDF; 2.036+08;
13C-1,2,3,4-TCDD; 5.05e+08;
13C-l,2,3,7,8,9-HxCDD; 4.136+08;
37Cl-2,3,7,8-TCDD; 3.28e+08;
13C-2,3,4,7,8-PeCDF; 3.29e+08;
13C-l,2,3,4,7,8-HxCDD; 2.066+08;
13C-1 , 2,3,4,7, 8-HxCDF; 2 . 58e+08 ;
13C-l,2,3,4,7,8,9-HpCDF; 1.60e+08;
37Cl-2,3,7,8-TCDD; 3.286+08;
13C-2,3,4,7,8-PeCDF; 3.29e+08;
13C-1 , 2,3,4 , 7, 8-HxCDD; 2 . 06e+08;
13C-l,2,3,4,7,8-HxCDF; 2.58e+08;
13C- 1,2,3,4,7,8, 9-HpCDF; 1 . 60e+08 ;










7
2

3
6
1
3
4
1

9
4
1

1
1
8
1
1
1
1
1
1
2
1
6
2
2
3
2
1
8
4
3
2
1
8
4
1








Ion 1;
.376+04;
.47e+04;
* .
.896+04;
.466+04;
.53e+05;
.86e+05;
.84e+05;
.07e+05;
*;
.72e+04;
.42e+04;
.72e+04;
* .
.34e+05;
.99e+04;
.296+04;
.59e+08;
.50e+08;
.67e+08;
.226+08;
.66e+08;
.816+08;
.lle+08;
.08e+08;
.25e+07;
.226+08;
.28e+08;
.286+08;
.OOe+08;
.14e+08;
.80e+07;
.85e+07;
.28e+08;
.OOe+08;
. 14e+08;
. 80e+07;
.85e+07;









Ion 2;
3.156+05;
1.566+04;
*;
6.346+04;
7.146+04;
1.86e+05;
4.36e+05;
6.636+05;
6.80e+04;
* .
S.OOe+04;
4.576+04;
2.456+04;
*;
1.426+05;
3.486+04;
8.766+04;
2.056+08;
9.756+07;
1.346+08;
1. 156+08 ;
1.866+08;
2.316+08;
1.36e+08;
2.096+08;
1.406+08;
2.836+08;
1.846+08;

1.286+08;
9.216+07;
1.706+08;
1. lle+08 ;

1.286+08;
9.216+07;
1.706+08;
1. lle+08;










0
1

0
0
0
0
0
1

1
0
0

0
0
0
0
1
1
1
0
0
1
0
0
0
1

1
1
0
0

1
1
0
0









RA;?; RT;
.23;n; 28:29;
.58;y; 32:38;
*;n;NotFnd;
.61;n; 34:46;
.91,-n; 34:58;
.82;n; 37:10;
.88;y; 40:02;
.73;y; 27:28;
.58;y; 31:58;
*;n;NotFnd;
.22;y; 34:11;
.97;n; 34:15;
.70;n; 34:38;
*;n;NotFnd;
.94,-y; 36:22;
.57;n; 37:32;
.95;y; 40:11;
.77;y; 28:27;
.54;y; 32:37;
.24;y; 34:46;
.06;y; 37:10;
.89;y; 40:02;
.78;y; 27:26;
.55;y; 31:57;
.52;y; 34:15;
.45;y; 36:21;
.78;y; 28:11;
.24;y; 34:59;
-,--; 28:29;
.56;y; 32:24;
.24;y; 34:42;
.52;y; 34:10;
.44;y; 37:31;
-;-; 28:29;
.56;y; 32:24;
.24;y; 34:42;
.52,-y; 34:10;
.44;y; 37:31;


>^

"^ y
s\ C»
Y^>


Conc;
0.108;
0.015;
* .
0.039;
0.052;
0.159;
0.465;
0.292;
0.058;
* .
0.066;
0.026;
0.014;
* .
0.108;
0.026;
0.091;
65.777;
64.221;
67.737;
72.158;
133.204;
59.254;
57.310;
61.944;
65.094;
104.604;
104.123;
64.544;
55.552;
70.308;
64.614;
65.611;
98.180;
96.966;
103.890;
103.496;
100.830;


<^
is3
•£• ^\***'




DL;
0.0117;
0.0120;
0.0190;
0.0137;
0.0139;
0.0129;
0.0187;
0.0137;
0.0120;
0.0116;
0.0103;
0.0080;
0.0093;
0.0107;
0.0129;
0.0156;
0.0225;
0.0328;
0.0252;
0.0248;
0.0103;
0.0132;
0.0177;
0.0090;
0.1276;
0.0517;
-;
- ;
0.0110;
0.0092;
0.0376;
0.1637;
0.0661;
0.0168;
0.0091;
0.0544;
0.2285;
0.1258;









S/N1;?;
ll;y;
4;y;
*;n;
7;y;
9;y;
28;y;
67;y;
68;y;
35;y;
*;n;
11 ;y;
5;y;
2;n;
*;n;
17 ;y;
2;n;
17, -y;
3614;y;
11290;y;
9760;y;
17927, -y;
19365;y;
10388;y;
70115;y;
1638;y;
2473 ;y;
5077;y;
12939; ;y;
17598;y;
69110;y;
8675;y;
1439;y;
1732;y;
17598;y;
69110;y;
8675;y;
1439;y;
1732, -y, •









S/N2;?
47, -y
4;y
*;n
6;y
7;y
62,-y
95 ;y
43, -y
7;y
*;n
26;y
16;y
9;y
*;n
53, -y
ll;y
11, -y
12047;y
20247, -y
7111,-y
13198;y
18762 ;y
9902, -y
18630;y
1684;y
3409;y
16771;y
9633, -y
-; -
18211;y
6469;y
1515;y
2427;y
_ - -
1821l!-y
6469, -y
1515;y
2427,-y
mod?
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
                                                                                                                                          Page 10
o
^
en

-------
OPUSquan   21-JUL-1998
                   Page 1
                                                                    Page 1 of 8

 Ent: 39 Name: Total Tetra-Furans  F:l  Mass: 303.902 305.899 Mod? no   #Hom:18

 Run: 10 File: a20ju!98b    S:5  Acq:21-JUL-98 00:16:40 Proc:21-JUL-98 13:42:31
 Tables: Run: a20ju!98b  Analyte: m8290-23-»  Cal: m8290-23-»Results: M8290-23*
 Version: V3.5 17-APR-1997 11:14:34  Sample text: 1072-1 xl/2
   Amount: 1.95
     Cone: 1.95
   Tox #1: -
Name
 2,3,7,8-TCDF
of which 0.29
of which 0.29
     Tox #2:  -

#     RT Respnse
named and 1.66
named and 1.66
      Tox #3: -
                                        RA
                    1  23:42 6.2e+05  0.73 y
                            6.26+05

                    2  24:15 3.1e+05  0.99 n
                            3.1e+05

                    3  24:34 5.86+05  0.82 y
                            5.8e+05

                    4  24:53 1.3e+06  0.86 y
                            1.36+06

                    5  25:45 6.6e+05  0.48 n
                            6.6e+05
                       25:54  9.16+03
                             9.1e+03
                                      1.06  n
7  26:01 2.06+05  0.80 y
         2.0e+05

8  26:10 4.36+05  0.73 y
         4.3e+05

9  26:27 5.9e+05  0.75 y
         5.9e+05

10 26:34 2.le+05  0.76 y
         2.1e+05

11 26:51 6.7e+05  0.76 y
         6.7e+05

12 27:11 2.06+05  0.70 y
         2.06+05

13 27:28 l.le+06  0.73 y
         l.le+06

 14 28:04 2.96+05  0.72 y
         2.9e+05

 15  28:10 3.0e+04  2.20 n
         3.0e+04

 16  28:21  1.4e+05   1.18 n
          1.4e+05

 17  28:34  6.0e+04   1.84  n
          6.0e+04

 18  29:49  2.2e+05   1.16  n
          2.2e+05
          Cone

           0.16

               T

           0.08
               1
               1
           0.15

               T

           0.33
               C

               (
           0.17
unnamed
unnamed
Area  Height
                                                                      S/N  Mod?
                                2.6e+05 5.8e+04
                                3.6e+05 7.9e+04 3.2e+01 y  n
                               3
                                1.5e+05 2.8e+04 2.5e+01 y  n
                                1.6e+05 3.3e+04 1.3e+01 y  n
                               5
                                2.6e+05 5.6e+04 4.9e+01 y  n
                                3.2e+05 7.5e+04 3.0e+01 y  n
                               3
                                5.9e+05 1.2e+05 l.Oe+02 y  n
                                6.8e+05 1.5e+05 5.9e+01 y  n
                                                0.00
                                                0.05
                                                0.11
               2.1e+05 4.3e+04 3.8e+01 y  n
               4.56+05 5.8e+04 2.4e+01 y  n

               4.7e+03 1.5e+03 1.4e+00 n  n
               4.4e+03 1.7e+03 6.9e-01 n  n

               8.8e+04 1.96+04 1.7e+01 y  n
               1.le+05 2.4e+04 9.5e+00 y  n
               I
               1.8e+05 3.7e+04 3.2e+01 y  n
               2.5e+05 4.8e+04 1.9e+01 y  n
                                                0.15
                                                0.05
                                                0.17
                2.5e+05  4.6e+04  4.1e+01  y  n
                3.4e+05  6.1e+04  2.5e+01  y  n

                9.2e+04  2.2e+04  1.9e+01  y  n
                1.2e+05  2.7e+04  l.le+01  y  n
               7
                2.9e+05  5.7e+04  5.0e+01  y  n
                3.8e+05  7.7e+04  3.1e+01  y  n
                                                0.05
                                                0.29
                                                0.07
                                                0.01
                                                0.04
                i.2e+04 1.7e+04 1.5e+01 y  n
                L.2e+05 2.2e+04 8.9e+00 y  n

                4.8e+05 7.7e+04 6.8e+01 y  n
                6.6e+05 1.le+05 4.3e+01 y  n

                ..2e+05 2.7e+04 2.3e+01 y  n
                L.7e+05 3.4e+04 1.4e+01 y  n

                2.1e+04 5.1e+03 4.5e+00 y  n
                9.3e+03 3.5e+03 1.4e+00 n  n

                '.6e+04 1.8e+04 1.6e+01 y  n
                i.4e+04 1.4e+04 5.8e+00 y  n
                                                0.02
                                                0.06
                3.9e+04 8.4e-i-03 7.4e+00 y  n
                2.1e+04 6.4e+03 2.6e+00 n  n
               5
                1.2e+05 2.2e+04 1.9e+01 y  n
                l.Oe+05 1.9e+04 7.8e+00 y  n

-------
OPUSquan   21-JUL-1998
                   Page 2
                                                                    Page  2 of 8

 Ent: 40 Name: Total Tetra-Dioxins F:l  Mass:  319.897  321.894 Mod? no   #Hom:13

 Run: 10 File: a20ju!98b    S:5  Acq:21-JUL-98 00:16:40 Proc:21-JUL-98  13:42:31
 Tables: Run: a20ju!98b  Analyte: m8290-23-»  Cal:  m8290-23-»Results: M8290-23»
 Version: V3.5 17-APR-1997 11:14:34  Sample text:  1072-1 xl/2
   Amount:  0.36
     Cone:  0.36
   Tox #1:  -
Name
2,3,7,8-TCDD
of which 0.11
of which 0.11
     Tox #2:  -
named and 0.25
named and 0.25
      Tox #3:  -
                   f
                         RT Respnse
                                        RA
1  25:16 3.3e+05  0.78 y
         3.3e+05

2  25:41 1.56+05  0.71 y
         1.5e+05

3  26:02 2.3e+04  0.49 n
         2.3e+04

4  26:04 2.5e+04  0.60 n
         2.5e+04

5  26:56 9.1e+04  0.53 n
         9.16+04

6  27:26 6.1e+04  1.96 n
         6.16+04

7  27:46 2.6e+04  1.10 n
         2.66+04

8  28:12 4.7e+04  0.61 n
         4.7e+04

9  28:20 9.0e+04  0.84 y
         9.0e+04

10 28:29 3.9e+05  0.23 11
         3.9e+05

11 28:41 4.2e+04  0.24 n
         4.26+04

12 29:15 1.4e+04  1.57 n
         1.4e+04

13 29:22 4.7e+03  1.13 n
         4.7e+03
          Cone

           0.09
               3
               ]
           0.04
               e
               E
           0.01
               7
               1
           0.01
               c
               3
           0.03

               c
           0.02
               4

           0.01
               1
               ]
           0.01
               ]

           0.03
               4
               4
           0.11
               •/
               3
           0.01
               £
               2
           0.00
               £
               C
           0.00
    unnamed
    unnamed
                                   Area   Height    S/N  Mod?
  .5e+05 3.le+04  2.1e+01  y  n
  .9e+05 4.2e+04  3.3e+01  y  n

 6.2e+04 1.2e+04  8.2e+00  y  n
 8.7e+04 1.9e+04  1.4e+01  y  n

 7.7e+03 2.2e+03  1.5e+00  n  n
 1.6e+04 5.5e+03  4.3e+00  y  n
1
 9.3e+03 2.6e+03  1.8e+00  n  n
 1.6e+04 5.5e+03  4.3e+00  y  n

 3.2e+04 8.9e+03  6.0e+00  y  n
 5.9e+04 1.2e+04  9.5e+00  y  n
2
 4.0e+04 8.8e+03  6.0e+00  y  n
 2.1e+04 4.6e+03  3.6e+00  y  n
L
 1.4e+04 2.7e+03  1.8e+00  n  n
 1.2e+04 3.5e+03  2.7e+00  n  n

  .8e+04 5.0e+03  3.4e+00  y  n
 2.9e+04 7.3e+03  5.7e+00  y  n
3
 4.1e+04 1.le+04  7.5e+00  y  n
 4.9e+04 1.le+04  8.3e+00  y  n

 7.46+04 1.6e+04  l.le+01  y  n
 3.2e+05 6.0e+04  4.7e+01  y  n

 i.le+03 2.3e+03  1.66+00  n  n
  .4e+04 6.4e+03  S.Oe+OO  y  n

 8.6e+03 2.4e+03  1.7e+00  n  n
 5.5e+03 2.1e+03  1.7e+00  n  n
                                                   2.5e+03 8.8e+02 6-Oe-Ol n  n
                                                   2.26+03 8.4e+02 6.56-01 n  n
                                                                    Page 3 of 8

 Ent: 41 Name: Total Penta-Furans  F:2  Mass: 339.860 341.857 Mod? no   #Hom:7

 Run: 10 File: a20ju!98b    S:5  Acg:21-JUL-98 00:16:40 Proc:21-JUL-98 13:42:31
 Tables: Run: a20ju!98b  Analyte: m8290-23-»  Cal: m8290-23-»Results: M8290-23»
 Version: V3.5 17-APR-1997 11:14:34  Sample text: 1072-1 xl/2
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NTame
of which 0.06
of which 0.06
     Tox #2: -

#     RT Respnse
named and 0.29
named and 0.29
      Tox #3: -
    unnamed
    unnamed
                                        RA
                   1  30:18 1.7e+05  1.93 n
                            1.7e+05
          Cone

           0.05
    Area  Height    S/N  Mod?


 l.le+05 1.8e+04 2.0e+01 y  n
                                                                                                          047

-------
OPUSquan   21-JUL-1998
                   Page 3
1,2,3,7,8-PeCDF
2  31:22 3.7e-t-05  1.61 y    0.12
         3.7e+05

3  31:46 1.3e+05  1.64 y    0.04
         1.3e+05

4  31:58 1.8e+05  1.58 y    0.06
         l.Se+05

5  32:04 5.1e+04  1.39 y    0.02
         S.le+04

6  32:09 9.9e+04  1.59 y    0.03
         9.96+04

7  32:30 7.2e+04  1.08 n    0.02
         7.2e+04
                                                   5.7e+04 1.2e+04 3.5e+00 y  n
 2.3e+05
 1.46+05
i
 8.0e+04
 4.9e+04
5
 l.le+05
 6.8e+04
I
 3.0e+04
 2.16+04
3
 6.1e+04
 3.8e+04
2
 3.7e+04
 3.46+04
6.9e+04 7.46+01 y  n
4.1e+04 1.3e+01 y  n

2.7e+04 2.9e+01 y  n
1.6e+04 4.9e+00 y  n

3.3e+04 3.5e+01 y  n
2.2e+04 6.8e+00 y  n

l.le+04 1.26+01 y  n
S.le+03 2.56+00 n  n

2.2e+04 2.46+01 y  n
1.4e+04 4.3e+00 y  n

1.3e+04 1.3e+01 y  n
1.2e+04 3.8e+00 y  n

-------
OPUSquan   21-JUL-1998
                   Page 4
                                                                   Page 4 of 8

 Ent: 42 Name: Total Penta-Dioxins F:2  Mass:  355.855 357.852  Mod? no   #Hom:8

 Run: 10 File: a20jul98b    S:5  Acq:21-JUL-98 00:16:40 Proc:21-JUL-98  13:42:31
 Tables: Run: a20ju!98b  Analyte: m8290-23-»  Cal:  m8290-23-»Results: M8290-23*
 Version: V3.5 17-APR-1997 11:14:34  Sample text:  1072-1 xl/2
   Amount: 0.18
     Cone: 0.18
   Tox #1: -
Name
of which 0.01
of which 0.01
     Tox #2:  -

#     RT Respnse
named and 0.17
named and 0.17
      Tox #3: -
                                        RA
                   1  31:30 1.5e+05  1.39 y
                            1.5e+05

                   2  31:50 3.6e+04  2.57 n
                            3.6e+04
                      32:00 9.2e+04
                            9.26+04

                      32:10 4.86+04
                            4.8e+04
                                     3.88 n
                  1.74 y
 1,2,3,7,8-PeCDD
5  32:24 5.56+04  1.50 y
         5.5e+04

6  32:38 4.0e+04  1.58 y
         4.0e+04
                      32:43 2.8e+04
                            2.8e+04

                      32:55 5.7e+04
                            5.7e+04
                                     2.37 n
                  1.18 n
          Cone

           0.05
               £
               e
           0.01

               I
           0.03

               :
           0.02

               ]
           0.02
               1

           0.01
               2
               1
           0.01

               e
           0.02
    unnamed
    unnamed
    Area  Height
                                                                      S/N  Mod?
 8.6e+04  2.9e+04  l.le+01 y  n
 6.2e+04  2.0e+04  1.6e+01 y  n

 2.6e+04  9.1e+03  3.4e+00 y  n
 l.Oe+04  4.2e+03  3.3e+00 y  n
3
 7.3e+04  1.7e+04  6.4e+00 y  n
 1.96+04  7.7e+03  6.1e+00 y  n

 3.1e+04  1.3e+04  4.86+00 y  n
 1.8e+04  6.0e+03  4.8e+00 y  n

 3.3e+04  l.le+04  4.2e+00 y  n
 2.2e+04  5.1e+03  4.0e+00 y  n
 2.56+04 9.5e+03 3.5e+00 y  n
 1.6e+04 5.7e+03 4.5e+00 y  n
L
 2.0e+04 5.7e+03 2-le+OO n  n
 8.4e+03 3.4e+03 2.7e+00 n  n
2
 3.1e+04 1.2e+04 4.5e+00 y  n
 2.66+04 8.7e+03 6.9e+00 y  n
  Ent:  43 Name: Total Hexa-Furans
                                                                    Page 5 of 8

                                   F:3  Mass: 373.821 375.818 Mod? no   #Hom:10
  Run:  10  File: a20ju!98b    S:5  Acq:21-JUL-98 00:16:40 Proc:21-JUL-98 13:42:31
  Tables:  Run: a20ju!98b  Analyte: m8290-23-»  Cal: m8290-23-»Results:  M8290-23»
  Version: V3.5 17-APR-1997 11:14:34  Sample text: 1072-1 xl/2
    Amount:  0.20
      Cone:  0.20
    Tox  #1:  -
 Name
of which 0.11
of which 0.11
     Tox #2: -

#     RT Respnse
 named  and  0.09
 named  and  0.09
       Tox  #3: -
                                        RA
                    1   33:32  S.Oe+04   0.82 n
                             8.0e+04

                    2   33:38  1.3e+05   1.20 y
                             1.3e+05

                    3   33:44  7.3e+03   0.34 n
                             7.3e+03

                    4   33:48  8.5e+03   0.63 n
                             8.5e+03

                    5   33:56  2.5e+04   0.92 n
                             2.5e+04

                    6   34:02  l.Oe+04   9.47 n
                             l.Oe+04
          Cone

            0.03
               i
               4
            0.04
               6
               c
            0.00
               1
               c
            0.00
               3
               c
            0.01
               1
               1
            0.00
    unnamed
    unnamed
                                                      Area  Height
                                  S/N  Mod?
                                3.6e+04 1.5e+04 5.0e+00 y  n
                                4.4e+04 1.66+04 1.7e+01 y  n
                                 6.9e+04 2.4e+04 8.0e+00 y  n
                                 5.8e+04 1.9e+04 2.1e+01 y  n
                                }
                                 1.9e+03 l.le+03 3.6e-01 n  n
                                 5.5e+03 2.1e+03 2.2e+00 n  n
                                3
                                 3.3e+03 1.4e+03 4.7e-01 n  n
                                 5.2e+03 1.6e+03 1.7e+00 n  n
                                1
                                 1.2e+04 4.5e+03 1.5e+00 n  n
                                 1.3e+04 5.3e+03 5.7e+00 y  n
                                                    9.5e+03  2.9e+03  9.7e-01  n  n
                                                                                                        049

-------
OPUSguan   21-JUL-1998
                   Page S
1,2,3,4,7,8-HxCDF  7  34:11 1.8e+05  1.22 y    0.07
                            1.8e+05

1,2,3,6,7,8-HxCDF  8  34:15 9.0e+04  0.97 n    0.03
                            9.0e+04

2,3,4,6,7,8-HxCDF  9  34:38 4.2e+04  0.70 n    0.01
                            4.2e+04

                   10 34:46 8.1e+03  0.46 n    0.00
                            8.1e+03
                               l.Oe+03 5.0e+02 5.4e-01 n  n
                               7
                               9.7e+04 3.4e+04 l.le+01 y  n
                               8.0e+04 2.4e+04 2.6e+01 y  n
                               3
                               4.4e+04 1.5e+04 5.0e+00 y  n
                               4.6e+04 1.5e+04 1.6e+01 y  n
                               L
                               1.7e+04 7.0e+03 2.3e+00 n  n
                               2.4e+04 8.46+03 9.0e+00 y  n
                               D
                               2.5e+03 l.le+03 3.7e-01 n  n
                               5.6e+03 l.le+03 1.2e+00 n  n
                                                                    Page 6 of 8

 Ent: 44 Name: Total Hexa-Dioxins  F:3  Mass: 389.816 391.813 Mod? no   #Hom:6

 Run: 10 File: a20jul98b    S:5  Acq:21-JUL-98 00:16:40 Proc:21-JUL-98 13:42:31
 Tables: Run: a20ju!98b  Analyte: m8290-23-»  Cal:  m8290-23-»Results: M8290-23*
 Version: V3.5 17-APR-1997 11:14:34  Sample text: 1072-1 xl/2
   Amount: 0.37
     Cone: 0.37
   Tox #1: -
Name
of which 0.09
of which 0.09
     Tox #2: -

#     RT Respnse
 1,2,3,6,7,8-HxCDD  5


 1,2,3,7,8,9-HxCDD  6
named and 0.27
named and 0.27
      Tox #3: -
                                        RA
                    1  33:53 2.6e+05  1.08 y
                            2.6e+05

                    2  34:11 2.0e+05  1.46 n
                            2.06+05

                    3  34:21 1.8e+05  1.26 y
                            1.8e+05

                    4  34:25 2.1e+04  1.05 n
                            2.1e+04
   34:46 l.Oe+05  0.61 n
         l.Oe+05

   34:58 1.4e+05  0.91 n
         1.46+05
          Cone

           0.11
               1
               3
           0.08
               3
               E
           0.07
               c

           0.01
               2
               3
           0.04
               i
               «
           0.05
   unnamed
   unnamed
    Area   Height     S/N  Mod?
 1.3e+05  4.9e+04  2.5e+01  y   n
 1.2e+05  4.6e+04  1.8e+01  y   n
3
 1.26+05  3.7e+04  1.9e+01  y   n
 8.1e+04  2.4e+04  9.3e+00  y   n
7
 9.96+04  3.16+04  1.66+01  y   n
 7.9e+04  2.7e+04  l.Oe+01  y   n
L
 l.le+04  2.36+03  1.2e+00  n   n
 l.Oe+04  2.5e+03  9.6e-01  n   n
1
 3.9e+04  1.4e+04  7.2e+00  y   n
 6.3e+04  1.4e+04  5.5e+00  y   n
                                                    6.5e+04  1.8e+04 9.3e+00 y  n
                                                    7.1e+04  1.7e+04 6.7e+00 y  n
                                                                                                        050

-------
OPUSquan   21-JUL-1998
                   Page 6
                                                                   Page  7 of  8

 Ent: 45 Name: Total Hepta-Furans  F:4  Mass:  407.782  409.779 Mod? no   #Hom:3

 Run: 10 File: a20ju!98b    S:5  Acq:21-JUL-98 00:16:40 Proc:21-JUL-98  13:42:31
 Tables: Run: a20ju!98b  Analyte: m8290-23-»  Cal:  m8290-23-»Results: M8290-23*
 Version: V3.5 17-APR-1997 11:14:34  Sample text:  1072-1 xl/2
   Amount: 0.16
     Cone: 0.16
   Tox #1: -
Name
of which 0.13
of which 0.13
     Tox #2:  -

#     RT Respnse
named and 0.02
named and 0.02
      Tox #3:  -
                                        RA
1,2,3,4,6,7,8-HpCDFl  36:22 2.8e+05  0.94 y
                            2.8e+05

                   2  36:41 4.9e+04  0.43 n
                            4.9e+04

l,2,3,4,7,8,9-HpCDF3  37:32 5.5e+04  0.57 n
                            5.5e+04
          Cone

           0.11
               1
               :
           0.02
               ]
               i
           0.03
unnamed
unnamed
Area  Height    S/N  Mod?
                                1.3e+05  4.1e+04  1.7e+01 y   n
                                1.4e+05  4.4e+04  5.3e+01 y   n

                                1.5e+04  6.0e+03  2.5e+00 n   n
                                3.4e+04  9.1e+03  l.le+01 y   n
                               3
                                2.0e+04  5.4e+03  2.2e+00 n   n
                                3.5e+04  9.2e+03  l.le+01 y   n
                                                                    Page 8 of 8

 Ent: 46 Name: Total Hepta-Dioxins F:4  Mass: 423.777 425.774 Mod? no   #Hom:4

 Run: 10 File: a20ju!98b    S:5  Acg:21-JUL-98 00:16:40 Proc:21-JUL-98 13:42:31
 Tables: Run: a20ju!98b  Analyte: m8290-23-»  Cal:  m8290-23-»Results: M8290-23»
 Version: V3.5 17-APR-1997 11:14:34  Sample text:  1072-1 xl/2
   Amount: 0.34
     Cone: 0.34
   Tox #1: -
Name
of which 0.16
of which 0.16
     Tox #2: -

#     RT Respnse
named and 0.18
named and 0.18
      Tox #3: -
                                        RA
                   1  36:21 6.6e+04  3.71 n
                            6.6e+04

                   2  36:36 2.7e+05  1.01 y
                            2.7e+05

 l,2,3,4,6,7,8-HpCDD3  37:10 3.4e+05  0.82 n
                            3.4e+05

                   4  37:31 5.3e+04  6.02 n
                            5.3e+04
          Cone

           0.03
               E
               :
           0.13
               3
               3
           0.16
               1
               1
           0.02
unnamed
unnamed
                                                      Area  Height
                                  S/N  Mod?
                                5.2e+04 1.7e+04 l.le+01 y  n
                                 .4e+04 4.7e+03 5.4e+00 y  n

                                1.4e+05 4.1e+04 2.6e+01 y  n
                                1.3e+05 4.3e+04 5.0e+01 y  n

                                1.5e+05 4.4e+04 2.8e+01 y  n
                                1.9e+05 5.4e+04 6.2e+01 y  n
                               2
                                4.5e+04 l.Oe+04 6.3e+00 y  n
                                7.5e+03 2.5e+03 2.9e+00 n  n
                                                                                                          051

-------
File: A20JUL98B Acq:
21-JUL-1998 00:16
:40 Exp: EXP_M23
_DB5_OVATION Voltage SIR EI+ GC Autospec-UltimaE Paradigm
Sample #5 Text: 1072-1 xl/2 ALS #6
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27 loo 28 1 00 29:00 3oSoO Time
3704. 0,1. 00%, F,F)
A3.28E8
A
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_6.5E7
_3.3E7
O.OEO
27:00 28:00 29;00 30:00 Time

25:35 26:04 26:33 26:57 27:20 27:56 28:42 29:10 29:49 ,_6.7E7



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27:00 28:00 29loO 3o!oO Time

-------





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File: A20JUL98B Acq: 21-JUL-1998 00:16:40 Exp: EXP_M23_DB5_OVATION Voltage SIR EI + GC Autospec-UltimaE Paradigm
Sample #5 Text: 1072-1 xl/2 ALS #6
355.8546 S:5 F:2 SMO(1,3) BSUB (128, 15, -3 . 0 ) PKD(3 , 3 , 3 , 0 . 10%, 2684 . 0 , 1 . 00%, F, F)
100% A8.57E4 ,_3.2E4
50J
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367.
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100%
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36112 30
8517 S:5 F

30:12 30
8949 S:5 F

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30:12 30
8919 S:5 F

30:12 30
9792 S:5 F
__3JU16_

30:12 30
l\ A7/A3E4 A3'29E4
A2.57E4/\ A A A2.47E4 ™ 'ft™
	 _^- 	 	 	 ^^^V^L_L_^/-W W/\^^X_/VV^/A^LME3_
124 36136 bbUs 3ll66 3ill2 3il24 31 lie 31 Us 32166 32ll2 32124 32136 32148 33166 33ll2
:2 SMO(1,3) BSUB(128,15,-3.0) PKD(3 , 3 , 3 , 0 . 10%, 1268 . 0, 1 . 00%, F, F)
A6.17E4
I \ A1.89E4 A2.62E4
/ \ A1.00E4 A A1.77E4 A1.56E4 A
124 36136 36148 3ll66 31:12 31:24 31:36 3ll48 32166 32ll2 32l24 32136 32148 33-00 33:12
:2 SMO(1,3) BSUB (128, 15, -3.0) PKD(3 , 3 , 3 , 0 . 10% , 4748 . 0, 1 . 00%, F, F)
A1.50E8
j[
•24 30:36 30:48 31:00 31:12 31:24 31:36 31:48 32:00 32:12 32:24 32:36 32:48 33:00 33:12
:2 SMO(1,3) BSUB(128,15,-3.0) PKD(3 , 3 , 3 , 0 . 10%, 1724 . 0, 1 . 00%, F, F)
A9.75E7
A
A
124 30:36 3ol48 31:00 31:12 31:24 3ll36 3lUs 32loO 32:12 32:24 32:36 32:48 33:00 33:12
:2 SMO(1,3) PKD(3,3,3,100.00%,0.0,1.00%,F,F)
30:2830:38 30:50 31^04 31_Ll5 31:37 31:50 39. -.Q4 32--14 32:3032:40 33jJ)3

124 30136 30148 3llOQ 31:12 31:24 31:36 31:48 32100 32:12 32:24 32:36 32:48 33:00 33:12
L1.6E4
.0 . OEO
Time
2.2E4
L1.1E4
•_0 . OEO
Time
5.4E7
_2 . 7E7
O.OEO
Time
3 . 5E7
11.7E7
' O.OEO
Time
6.4E7
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O.OEO
Time


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;: A20JUL98B Acq: 21-JUL-1998 00:16:40 Exp: EXP M23 DBS OVATION Voltage SIR EI+ GC Autospec-UltimaE Parad
>le #5 Text: 1072-1 xl/2 ALS #6
8156 S:5 F:3 SMO(1,3) BSUB (128, 15 , -3 . 0) PKD(3 , 5, 2 , 0 . 10%, 1964 . 0 , 1 . 00%, F, F)
i A1.34E5
A
/\ A1.18E5
/ \ A A9.88E4
/ \ / Vx A A3 89E4 A6-46E4
33:24 33:36 33:48 34:00 34:12 34:24 34:36 34548 3s!oO 35.!12 3s!24 3s!36 35
8127 S:5 F:3 SMO(1,3) BSUB (128 , 15 , -3 . 0) PKD(3 , 5, 2 , 0 . 10%, 2596 . 0 , 1 . 00%, F, F)
A1.24E5
/\
M A7.86E4
/ \ A A A6-34E4 A7A4E4
\ / V / U. 03 4 ~S\ / \
33:24 33:36 33:48 34:00 34:12 34:24 34:36 34:48 35:00 35:12 35!24 35:36 35
8559 S:5 F:3 BSUB(128 , 15, -3 . 0) PKD(3 , 5 , 2 , 0 . 10%, 6512 . 0, 1 . 00%, F, F)
A2.28E8
A1.67E8 fl
rt / 1
M /v
33524 33536 33548 34!oO 34!l2 34!24 34136 34!48 3s!oO 3s!l2 35J24 35!36 35
8530 S:5 F:3 BSUB(128, 15, -3 .0) PKD(3 , 5, 2 , 0 . 10%, 7048 . 0, 1 . 00%, F, F)
Al . 84E8
A1.34E8 /I
n 1 1

33!24 33!36 33548 34:00 34:12 34:24 34:36 34:48 35:00 35:12 35:24 35:36 35
9760 S:5 F:3 SMO(1,3) PKD(3 , 3 , 3 , 100 . 00%, 0 . 0, 1 . 00%, F, F)
33:39 33:56 34jlO 34:20 34:3334:40 34:48 34:56 35:06 35:20 35:29 35:39
/

33?24 33:36 33!48 34!oO 34!l2 34!24 34!36 34Us 3s!oO 3s!l2 3s!24 3s!36 3s!
igm
5.1E4
_2 . 6E4
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4 . 8E4
.2 . 4E4
48 Time
8.4E7

.4.2E7
-O.OEO
48 Time
_6 . 8E7

_3.4E7
' O.OEO
48 Time
.1.4E8

.7.0E7
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-------
Fil«
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i: A20JUL9BB Acq: 21-JUL-1998
>le #5 Text: 1072-1 xl/2 ALS
7767 S:5 F:4 SMO(1,3) BSUB(128
A1.36E5
.
36:00 36:12 36:24 36:36
7737 S:5 F:4 SMO(1,3) BSUB(128
A1.35E5
r-
36166 36ll2 36124 36136
8169 S:5 F:4 SMO(1,3) BSUB (128

36166 36112 36124 36136
8140 S:5 F:4 SMO(1,3) BSUB(128

00:16:40 Exp: EXP M23 DBS OVATION Voltage SIR EH- GC Autospec-UltimaE Paradigm
#6
,15, -3.0) PKD (3, 3, 3, 0.10%, 1588. 0,1. 00%, F,F)
A1.53E5 4.6E4
I \ A4 . 54E4
36 Us' 37l6o 37112 37124 37136 37148 38166 ' 38l 12 ' 38-124 ' 38 lie ' 38 Us ' 39
,15, -3.0) PKD (3, 3, 3, 0.10%, 872. 0,1. 00%, F,F)
Al . 86E5
	 j[ „,_„.. 	
36:48 37:00 37:12 37:24 37:36 37:48 38:00 38:12 38:24 38136 38148 39
,15, -3.0) PKD (3, 3, 3, 0.10%, 1824. 0,1. 00%, F,F)
A1.22E8
/V
36148 37166 37112 37124 37136 37148 38166 38ll2 38124 38136 SsUs 39
,15, -3.0) PKD(3,3,3,0.10%,2356.0,1.00%,F,F)
A1.15E8
/I
36166 36112 36.-24 36136 36 Ua 37166 37112 37124 37136 37148 38166 38112 38124 38l36 38l48 39:
9728 S:5 F:4 SMO(1,3) PKD(3 , 3, 3 , 100 . 00%, 0 . 0 , 1 . 00%, F, F)
36:03 36:21 _ 36:34. 36:56 37:26 37:53 38:18 38:3338:43
1
36:00 36:12 36:24 36:36

36:48 37:00 37:12 37:24 37136 37148 38:00 38:12 38:24 38136 38148 39l
.2.3E4
_O.OEO
00 Time
5.4E4
.2.7E4
_O.OEO
00 Time
3.3E7
_1.6E7
.0 . OEO
00 Time
3 . 1E7
_1 . 6E7
_O.OEO
00 Time
9.5E7
_4.8E7
O.OEO
00 Time

-------
File: A20JUL98B
Sample #5 Text:
457.7377 S:5 F:5
100S
50-




39ll2
459.7348 S:5 F:5
100%

so:
o:
/^ \
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1 i- 1 1 | i
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469.7780 S:5 F:5
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471.7750 S:5 F:5
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100%. 19-OR T9?1

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39:12
Acq: 21-JUL-1998 00:16:40 Exp: EXP_M23_DB5_OVATION Voltage SIR EI+ GC Autospec -UltimaE Paradigm
1072-1 xl/2 ALS #6
SMO(1,3) BSUB(128,15,-3.0) PKD(3 , 3 , 3 , 0 . 10%, 1424 . 0 , 1 . 00%, F, F)
A3 . 86E5
A
J V^29E4
9.7E4
_4.9E4
O.OEO
39:24 39:36 39:48 40:00 40:12 40:24 40:36 40:48 41:00 Time
SMO(1,3) BSUB(128,15,-3.0) PKD(3 , 3 , 3 , 0 . 10%, 1128 . 0 , 1 . 00%, F, F)
•*~ H> of\ y*4 -/V / A4-36E5 ,_1.1E5
l/fr**^l_^W- 	 ^ v l\
^^j-^fttc }f l°°Jj. / \
L- ' K/ J 	 	

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0 OEO
39:24 39:36 ' 39:48 / 40:00 40 12 40:24 40:36 4o!48 41:00 Time
SMO(1,3) BSUB(128,15,-3.0) PKD(3 , 3 , 3 , 0 . 10%, 1996 . 0, 1 . 00%, F, F)
Al . 66E8
A
y v 	
3.9E7
_1.9E7
O.OEO
39:24 39:36 39:48 40:00 40 12 40:24 40:36 40:48 41:00 Time
SMO(1,3) BSUB(128,15,-3.0) PKD{3 , 3 , 3 , 0 . 10%, 2300 . 0 , 1 . 00%, F, F)
Al . 86E8
A
J V 	
4.3E7
.2.2E7
O.OEO
39:24 39:36 39:48 40:00 40 12 40:24 40:36 ,. 40:48 41:00 Time
SMO(1,3) PKD(3,3,3,100.00%,0.0,1.00%,F,F)
4 39:23 39:31 39^43 40:0440:09 40:16 40:44 40:53 1 . OE8




_5.0E7
O.OEO
39:24 39:36 39:48 40:00 40 12 40:24 40:36 40:48 41:00 Time

-------
File: A20JUL5BB Acq: 21-JUL-1998 00:16
Sample #5 Text: 1072-1 xl/2 ALS #6
303.9016 S:5 SMO(1,3) BSUB (128 , 15 , -3 . 0)
100% A5.92E5
50J A2.63E5 A2.62E5/
: A A1.54E5A /
A y\ l\ 1 U/~
24loO 25100
305.8987 S:5 SMO(1,3) BSUB (128, 15, -3 . 0)
100% A6.85E5
50 : A3.61E5 A3.21E5/1
: A A1.55E5A \ ^
n: , , , A A l\ I\^S-
24100 25100
315.9419 S:5 SMO(1,3) BSUB(128, 15, -3 . 0)
100%
50.
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24 100 25 100
317.9389 S:5 SMO(1,3) BSUB (128, 15, -3 . 0)
100%
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24100 25100
375.8364 S:5 SMO{1,3) BSUB(128, 15 , -3 . 0)
100%
5°~: 23:ffe 23:54 24:24 24:49
24100 25100
316.9824 S:5 SMO(1,3) PKD(3,3, 3, 100.00%,
100% 24:06 24i3124_L52
50J
0.: 	 	
24:00 25:00
:40 Exp: EXP_M23_DB5_OVATION Voltage SIR EI + GC Autospec-UltimaE Paradigm
PKD(3,3,3,0.10%,1132.0,1.00%,F,F)
r!.2E5
A4.84E5 :
A2.14E5 A2.89E5 A _6.0E4
26 00
PKD(3,3,3,0.10%
A4.50E5
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26100
PKD(3,3,3,0.10%
2eloo
PKD(3,3,3,0.10%
' ' ' I 	 -i 	 1 	 1 	 1 	 1 	 1 — i i r i 	 1 	 1 	 1 	 r- "i- — i • i '- -*-" • "•Ul"
27:00 28:00 29:00 30 00 Time
,2476.0,1.00%,F,F)
1.5E5
A6.63E5
A3-"E5 A _7.7E4
/\ / \ 3V 1 1*7T?C/ \ Al .69E5 ^ + r\ A ~-r-
/ \ I \ **•*• • J- ' co/ \ r\ -*fj 1 i "EM Al 04E5
y Y\ / v w y v /v_ ^.nE4 >^ :n nT?n
27:00 28:00 29:00 30 00 Time
,3520. 0,1. 00%, F,F)
A1.81E8 3.7E7
/I _1.8E7
27 loo 28:00 29:00 	 30:00 Time
,4660. 0,1. 00%, F,F)
A2.31E8 4.6E7
11 .2.3E7
y V n mrn
26:00 27:00 2sloO 	 29loO 	 30:00 Time
PKD(3,3,3,100.00%,1372.0,1.00%,F,F)
28:11 9.6E3
27:25 21:57 \ A 29-43 -4 . 8E3
25:30 25:58 26:51 J\ M A \ /\28:44 29:31)!
26:00
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25j.35 26:04

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27:00 28:00 29:00 30:00 Time
26^33 26:57 27:20 27:56 28i42 29:10 29:49 6.7E7
V / _3.4E7
27:00 28:00 29:00 	 30:00 Time
o
c^

-------
File: A20JUL98B Acq:
Sample #5
339.8597
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21-JUL-1998 00:16:40
Exp : EXP_
M23_DB5_OVATION Voltage SIR E1+ GC Autospec-UltimaE Paracligm
: 1072-1 xl/2 ALS #6
2 SMO(1



24 30:
2 SMO(1


,3)



36
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BSUB(128,15,



30:48 31:00
BSUB(128,15,


-3.0)



PKD (3,3,3
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A
A
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31:12 31:24
-3.0)


PKD (3,3,3
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, 0.10%, 940. 0,1. 00%, F,F)

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, 0.10%, 3288. 0,1. 00%, F,F)

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30:50 31i04 31


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, 0.10%, 1048. 0,1. 00%, F,F)
A2.11E8 A2.00E8
A A
A A
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7
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0
31136 31:48 32l6o 32ll2 32124 32136 32148 33:00 33:12
, 0.10%, 2560. 0,1. 00%, F,F)
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A A
A A
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31136 31148 32166 32ll2 32124 32:36 32:48 33lOO 33:12
,100. 00%, 3440. 0,1. 00%, F,F)
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Time

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-------
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5: A20JUL9«B Acq: 21-JUL-1998 00:16:40 Exp: EXP M23
>le #5 Text: 1072-1 xl/2 ALS #6
8207 S:5 F:3 SMO(1,3) BSUB(128, 15, -3 . 0) PKD(3,5,2,0.
i A9.72E4
A6 . 94E4 A
A3 . 58E4f\ / \
J\L\ _ _ A1^E4 7 V^53E3
33J24 33J36 33Us 34loO 34ll2 34?24
8178 S:5 F:3 SMO(1,3) BSUB(128, 15, -3 . 0) PKD(3,5,2,0.
A8.00E4
A5.78E4 A
A /\7\ Al 32E4 / V\
33!24 33136 33-148 34loO 34J12 34124'
8639 5:5 F:3 BSUB(128, 15, -3 . 0) PKD(3 , 5, 2 , 0 . 10%, 28072
A1.08E8
33:24 33:36 ' '33148 ' '34loo' 34ll'2' ' 3'4l2'4'
8610 S:5 F:3 BSUB(128, 15, -3 . 0) PKD(3 , 5, 2 , 0 . 10%, 52192
A2.09E8
M
_DB5_OVATION Voltage SIR EI+ GC Autospec-UltimaE Parad
10%, 2984. 0,1. 00%, F,F)
A1.72E4
34:36 34:48 35:00 35:12 35:24 35:36 35
10%, 932. 0,1. 00%, F,F)
A2V^5E4 A1.90E4
^_/ \A5.58E3 	 vn^^V—^ A6^89E3 ^ 	
34136 34148 3s!oO 3s!l2 35J24 35J36 35
.0,1.00%,F,F)
34:36 34:48 35:00 35:12 35:24 35:36 35
.0,1.00%,F,F)
i
33124 33136 33!48 34!oO 34ll2 34124 34i36 34Us 35!oO 3s!l2 35124 35I36 35:
7555 S:5 F:3 SMO{1,3) BSUB(128, 15, -3 . 0) PKD(3 , 3 , 3 , 100 . 00%, 1212 . 0, 1 . 00% , F, F)
34:59
34:46 A
^1^^^*^^
igm
3.5E4
Ll.8E4
48 Time
2 . 5E4
L1.2E4
48 Time
4 . 6E7
_2.3E7
O.OEO
48 Time
8.8E7
L4.4E7
LO.OEO
48 Time
_1 . 1E4
L5.6E3
-O.OEO
33:24 33:36 33:48 34:00 34:12 34:24 34:36 34:48 35:00 35:12 35:24 35:36 35-48 Time
9760 S:5 F:3 SMO(1,3) PKD(3 , 3 , 3 , 100 . 00%, 0 . 0, 1 . 00%, F, F)
33:39 33:56 34jlO 34:20 34:3334:40 34:48 34:56 35:06 35:20 35:29 35:39 1.4RR
/
33:24 33136 33U8 34:00 34ll2 34\24

_7.0E7
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i i i . i i i i i i i i i i i i i i i i 1 i i i i i 1 i i i i i I i i i i i I
34:36 34:48 35:00 35:12 35:24 35:36 35:48 Time

-------
File: A20JUL98B
Sample #5 Text:
407.7818 S:5 F:4
1002
50 j
o"



36166 36
409.7788 S:5 F:4
iooa
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36166 36
417.8253 S:5 F:4
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o:
f


ijeloo ' 36
Acq: 21-JUL-199U 00:16:40
1072-1 xl/2 ALS #6
SMO(1,3) BSUB(128,15,-3.0)
Al . 34E5
A
/ \ A1.48E4
•12 ' 36124 ' 36136 ' 36\48 37
SMO(1,3) BSUB(128,15,-3.0)
A1.42E5
A
A
/ \ A3.44E4
/ V ^~^^V
Il2 361241 36\36 36:48 37
SMO{1,3) BSUB(128,15,-3.0)
A6.25E7
A
A
/ v
i i i r i i i n i i i i i i i-T'i1 r i i i i i
Il2 36:24 36136 36:48 37
SMO(1,3) BSUB(128,15,-3.0)
A1.40E8
A
A
y v
•12 36124 36136 36:48 37
SMO(1,3) BSUB(128,15,-3.0)
:12
\ ,fi .iq
1 . 36:29 •ib/Ta
1 A A~ Ay\/ VA
vw \-^v ^\y ^ v ^ '
Il2 ' 36124 ' 36136 ' 36\48 37
SMO(1,3) PKD(3,3,3,100.00%,
Exp: EXP_M23_DB5_OVATION

PKD(3,3,3,0.10%,2444.0,1


A1.99E4
r ~i 'ii'iiiTrin i 11 1111 11 i i
:00 37:12 37:24 37:36
PKD( 3, 3, 3 ,0.10%, 828. 0,1.


A3.48E4
^/~\^_^
166 ' 37l 12 ' 37! 24 ' 37! 36
PKD(3,3,3,0.10%,7504.0,1

A4.85E7
yV

100 37ll2 37:24 37:36
PKD(3, 3, 3, 0.10%, 12280.0,

A1.11E8
A
/ V
166 37112 37124 37136
PKD(3,3,3,100.00%,4560.0
37:09
Voltage SIR EI+ GC Autospec-UltimaE Paradigm

.00%,F,F)



4 . 5E4
L2.2E4
• 0 . OF.O
37:48 38:00 38:12 38:24 38:36 38:48 39:00 Time
00%,F,F)




_4 . 5E4
_2.2E4

_O.OEO
37148 ' 38:00 ' 38Sl2 ' 38S24 ' 38:36 ' 38S48 39loO Time
.00%,F,F)
rl . 9E7




.9.3E6
O.OEO
37:48 38:00 38:12 38:24 38:36 38:48 39:00 Time
1.00%,F,F)
4.2E7




.2 . 1E7
.O.OEO
37148 38166 38ll2 38124 38l36 ijsUs 39:00 Time
,1.00%,F,F)
1.1E4
/\ 37:40 ,„ „. TR-1^ A

\/ ^Y^XW vy
166 37 1 12 37124 37136
0.0,1.00%,F,F)
36-21 36:34 36:56 37:26



1 i i i i i 1 i i I i 'T-r i r I I I | i i I i i
Il2 36:24 36:36 36:48 37



166 ' 37li2 37124 37136
A /v /V^^ /V\ / \ r^\r^^r' — /vw_ r^ ^


-5.4E3
O.OEO
37148 38166 38:12 38124 38:36 38l48 39 00 Time

37:53 38:14 38:3338:43 9 . 5E7




_4 . 8E7
_O.OEO
37148 38166 38:12 38124 38136 38:48 39:00 Time

-------
File: A20JUL98B
Sample #5 Text:
441.7427 S:5 F:5
100%
50 j
;
n- 	
39ll2
443.7398 S:5 F:5
100%
50J
0: 	 * 	 	
39ll2
469.7780 S:5 F:5
100%
50J
0:
" \ — I — r— i — i — i — i —
39:12
471.7750 S:5 F:5
100S
50-
o-
*M — i — i — i — i — i — i —
39:12
513.6775 S:5 F:5
100%
50J
: 39:
o • -^— -•— -*s~^^f
39!l2
454.9728 S:5 F:5
100ft 39:05 39:1

50J
0:
' 39:12
Acq: 21-JUL-1998 00:16:40 Exp: EXP
1072-1 xl/2 ALS #6
SMO(1,3) BSUB(128,15,-3.0) PKD(3,3,3



______ 	 ,, „_-- 	 	 	 _— — — • 	 x 	
39:24 39:36 39:48
SMO(1,3) BSUB(128,15,-3.0) PKD(3,3,3


3T9?24 39136 3V:48
SMO(1,3) BSUB(128,15,-3.0) PKD(3,3,3



1—1 	 1 	 1 	 1 	 1 	 1 	 1 	 1— 1 	 1"1 "T I 1 1 1 I 1 1 1
39:24 39:36 39:48
SMO(1,3) BSUB(128,15,-3.0) PKD(3,3,3



39:24 39:36 39:48
SMO(1,3) BSUB(128,15,-3.0) PKD(3,3,3

39:42
15 39-25 39-32 /V AX
"^^ ^\_^\- — • — ~^_- 	 / \y ^ — .*-
39:24 39:36 39:48
SMO(1,3) PKD( 3, 3, 3, 100. 00%, 0.0, 1.00%
4 39:23 39:31 39:43



' 	 •' 	 '""-' I ' ' ' ' ' i 	 i • • •
39:24 39:36 39:48
M23_DB5_OVATION Voltage SIR EI+ GC Autospec-UltimaE Paradigm

, 0.10%, 1116. 0,1. 00%, F,F)
A8 • 29E4 2 . 1E4
/ \ L1.0E4
A2.40E3 / \A5.04E3 :
^ 	 	 ^. 	 ^ 	 . ^~r^ \ 	 ^ — -^— ^— ^^- — -^ ~~— ^ ' 0 OEO
4o!ob 40 12 4o!24 4ol36 4'oUs 4l!oO Time
, 0.10%, 2164. 0,1. 00%, F,F)
A8.76E4 2.7E4
/ \ _1.3E4
4o!ob 4o!l2 4o!24 4ol36 4o!48 4l!oO Time
, 0.10%, 1996. 0,1. 00%, F,F)
Al . 66E8 3 . 9E7
/ \ .1.9E7
J V 	 0 OEO
40:00 40 12 40:24 40:36 40:48 41 00 Time
, 0.10%, 2300. 0,1. 00%, F,F)
Al . 8 6E8 4 . 3E7
/ \ L2.2E7
J ^ 	 • O.OEO
4o!ob ' ' ' 4o!l2 ' 4o!24 4o!36 4ol48 4lloO Time
, 100. 00%, 848. 0,1. 00%, F,F)
40:02 9.1E3
/ \ _4.6E3
/ V^^ 40:14 40:28 40:46 40:55
~y ^ 	 ^^^ — ^ 	 ^/^ — — xl^-^L^-v^V. 	 — ~/~\ 	 -— O.OEO
4o!ob ' ' 40 12 4o!24 4o!36 4ol48 4l!oO Time
,F,F)
40:0440:09 40:16 40:44 40:53 1 . OE8

I.5.0E7
: O.OEO
40:00 40:12 40:24 40:36 40:48 41:00 Time

-------
OPUSquan   22-JUL-1998
                                      Page 1
                                                                                                                                              Page  17
         Filename
           Sample
         Acquired
        Processed
        Sample ID
        Cal Table
    Results Table
         Comments
 Typ
 Unk
 ES/RT
a21ju!98f
12
22-JUL-98  02:54:34
22-JUL-98  08:34:07
1072-1 xl/2
07feb-m23conf
M8290-23-072198F
 Total
 DPE
 LMC
              Name;     Resp;
      2,3,7,8-TCDF;        *;
  13C-2,3,7,8-TCDF; 5.29e+08;
      Tetra Furans; 5.59e-i-06,-
            HxCDPE;        *;
QC CHK ION (Tetra);        *;
   Ion 1;
       * ;
2.32e+08;
3.05e+05;
                                   Ion 2;
                                       *;
                                2.97e+08;
                                3.85e+05;
  RA;?;    RT;
   *;n;NotFnd;
0.78;y; 27:55;
0.79,-y; 18:13;
      ;NotFnd;
      ,-NotFnd;
   Cone ;
      * .
129.679;
  1.111;
    DL
0.0387

0.0387
S/N1;?;
   *;n;
1358;y;
  17 ;y;
   *;n
DivO;n
S/N2;?
   *;n
1223;y
  21 ;y
mod?
  no
  no
  no
  no
  no
                                                                 -;-;NotFnd
                                                                 -;-;NotFnd
                                                                                                                  -; -;   no

-------
OPUSguan   22-JUL-1998
                                      Page 1
 Ent: 3  Name:  Tetra Furans
                                                 Page  1  of  1

                F:l  Mass:  303.902  305.899 Mod? no   #Hom:17
 Run: 17 File: a21ju!98f    S:12 Acg:22-JUL-98  02:54:34  Proc:22-JUL-98  08:34:07
 Tables: Run: a21ju!98b  Analyte: m23_conf   Cal:  07feb-m23»Results: M8290-23*
 Version: V3.5 17-APR-1997 11:14:34  Sample text:  1072-1 xl/2
   Amount: 1.11
     Cone: 1.11
   Tox #1: -
Name
of which *
of which *
     Tox #2:  -

#     RT Respnse
named and 1.11
named and 1.11
      Tox #3:  -
                                        RA
                   1  18:13 6.96+05  0.79 y
                            6.9e+05

                   2  19:26 3.96+04  0.23 n
                            3.9e+04

                   3  19:53 l.Oe+06  0.88 y
                            l.Oe+06

                   4  20:23 l.le+05  2.68 n
                            l.le+05

                   5  20:43 l.Oe+05  1.61 n
                            l.Oe+05

                   6  21:13 1.9e+05  0.57 n
                            1.9e+05

                   7  21:34 1.66+05  0.34 n
                            1.6e+05

                   8  21:35 1.7e+05  0.43 n
                            1.7e+05

                   9  22:11 6.4e+05  0.67 y
                            6.4e+05

                   10 22:36 5.56+05  0.39 n
                            5.5e+05

                   11 22:38 5.2e+05  0.31 n
                            5.2e+05

                   12 23:18 3.4e+05  0.91 n
                            3.4e+05

                   13 24:21 8.6e+05  0.79 y
                            8.6e+05

                   14 25:30 6.6e+04  1.55 n
                            6.6e+04

                   15 25:32 5.5e+04  1.80 n
                            5.5e+04

                   16 26:31 1.2e+04  0.31 n
                            1.2e+04

                   17 26:35 7.2e+04  0.62 n
                            7.2e+04
          Cone

           0.14
               T
               T
           0.01
               1

           0.20
               4
               e
           0.02
               1
               2
           0.02
               e
               T
           0.04
               e
               ]
           0.03
               4
               1
           0.03
               C
               3
           0.13


           0.11
               3
               <
           0.10
               1
               f,
           0.07
               1
               1
           0.17

               4
           0.01
               4

           0.01
               •3
               3
           0.00
               2
               S
           0.01
unnamed
unnamed
                                                      Area  Height
                                  S/N  Mod?
                                3.0e+05  6.2e+04  1.7e+01  y  n
                                3.96+05  7.9e+04  2.16+01  y  n
                               I
                                7.46+03  4.4e+03  1.2e+00  n  n
                                3.26+04  1.26+04  3.1e+00  y  n
                               D
                                4.86+05  9.26+04  2.5e+01  y  n
                                5.46+05  1.2e+05  3-le+Ol  y  n
                               2
                                7.76+04  2.2e+04  6.0e+00  y  n
                                2.8e+04  1.3e+04  3.4e+00  y  n
                               2
                                6.36+04  1.6e+04  4.46+00  y  n
                                3.9e+04  9.9e+03  2.7e+00  n  n
                               i
                                6.8e+04  1.7e+04  4.6e+00  y  n
                                1.2e+05  2.4e+04  6.36+00  y  n

                                4.1e+04  1.6e+04  4.4e+00  y  n
                                1.26+05  2.2e+04  5.8e+00  y  n
                                5.2e+04 l.Se+04 5.1e+00 y  n
                                1.26+05 2.2e+04 5.86+00 y  n
                               3
                                2.56+05 4.9e+04 1.3e+01 y  n
                                3.8e+05 6.4e+04 1.7e+01 y  n

                                 .Se+05 4.7e+04 1.36+01 y  n
                                 .06+05 6.6e+04 1.8e+01 y  n

                                1.26+05 4.6e+04 1.3e+01 y  n
                                4.06+05 6.6e+04 1.8e+01 y  n
                                1.6e+05 2.3e+04 6.2e+00 y
                                1.86+05 3.0e+04 7.9e+00 y
                                3.8e+05 5.46+04 1.5e+01 y  n
                                4.86+05 7.0e+04 1.96+01 y  n

                                4.0e+04 l.le+04 3.0e+00 y  n
                                2.66+04 l.le+04 2.96+00 n  n
                               L
                                3.56+04 1.2e+04 3.36+00 y  n
                                1.96+04 9.9e+03 2.6e+00 n  n
                               3
                                2.96+03 2.6e+03 7.1e-01 n  n
                                9.56+03 S.Oe+03 2.1e+00 n  n
                               1
                                2.86+04 7.7e+03 2.1e+00 n  n
                                4.56+04 1.2e+04 3.3e+00 y  n
                                                                                                        063

-------
File: A21JUL98F Acq: 22-JUL-1998 02:
54:34 Exp: M23_DB225 Voltage
SIR EI+ GC Autospec-UltimaE Paradigm

Sample #12 Text: 1072-1 xl/2 ALS #12
303.9016 S:12
100%,
50 j
'
OJ



lelob
305.8987 S:12
100%,
;
50J
n-



16:00
315.9419 S:12
100%
50 J
o:



' 16:00
317.9389 S:12
100%
50 1
o"



"-1 — i — i — I — i — r
16:00
375.8364 S:12
100%
50J



15:32
16:00
316.9824 S:12
100%15:30
sol
o:


"-1 — i — i — i — i — i-
16:00
SMO ( 1 ,
3)
BSUB(128
,15, -3
-0)
PKD(3
,3, 3,0. 10%, 3628. 0,1.
A4-77E5
A3


18
SMO(1,
.05E5 fi
I

1
loo
3)
^1

' ' ' 20!
BSUB(128
A6.
jl f\^-
00
,15, -3
A2.54E5
A »,
84E4
A^,
F
J II
22 loo
.0)
PKD(3
A3.81E5
1 . 59E5 M
AA / \ $P • 52E4
KV^\..JL1_VJ5.J\^.>__^
HI y^i*! r"i^i T^"!*?1
24:00 26:00
,3, 3, 0.10%, 3744. 0,1.
A5.40E5
A3


18
SMO ( 1 ,



18
SMO{1,



18
SMO ( 1 ,



18
SMO(1,
17 :4


18
•85E5 |

l\
loo
3)



00
3)



00
3)



00
3)
2


lob


1 ' '20!
BSUB(128



20:
BSUB(128



-i — i — i — i — |-
20:
BSUB(128
19:36
n
/
1 • '20!
Al
1 ^
00
,15, -3



00
,15, -3



00
,15, -3


20:!
00
PKD(3,3,3,100.
	 19j_


' ' '20!
56 21


00
19E5

A "A

22lob
.0)



22
.0)



22
.0)


57
22
00%,
:J.l -


22
PKD(3



lob'
PKD(3



lob'
PKD(3



lob
0.0,1
22:17


lob'
E5 A4.80E5

,^\JLjflA^l^
24:00 ' 26:00
,3, 3, 0.10%, 19380. 0,1



24lob 26:00
,3, 3, 0.10%, 27708. 0,1



24loO 26lob
,3, 3, 100. 00%, 9632.0,


00%,F,F)
r9

A A3 . 1 5E4 .
^-v^^^^^vA^^-^*^^^^*^*^ /^ -AV^—rrt— „— ,.
_4

o
28lob 3o!ob 32:00 34lob
00%,F,F)
rl

A2.46E5
C^^JiLjlSt^^^^ 'J&?3 ^r .

_6
0
28:00 30:00 32:00 34:00
.00%,F,F)
A2.32E8
A
1
l\
2
Ll
0
28:00 30:00 32:00 34:00
.00%,F,F)
A2.97E8
A
I
l\
3
Li
:o
28:00 30:00 32:00 34:00
1.00%,F,F)


23:17 24:24 26:11 27:54 29:19 30:32 32:34 34:09
24lob 26lob
.00%,F,F)
.23; 23 , 	 __ . 25; 51..


24lob 26100
2
_1
0
2slob 3o!ob 32lob 34loo

27:38 28:5629:56 32^02 33:19 34:37 4


_2
0
2slob s'olob 32lob 34lob

.2E4
. 6E4

Time

.2E5

.OE4
.OEO
Time

.6E7
.3E7
.OEO
Time

.4E7
.7E7
.OEO
Time

.5E5
.3E5
.OEO
Time

.8E7
.4E7
.OEO
Time

-------
               -ian    24-JUL-1998
                                                Page  1
                   Filename
                     Sample
                   Acquired
                  Processed
                  Sample  ID
                  Cal Table
             Results Table
                   Comments
          Typ
          Unk
          ES/RT
        a21ju!98f
        12
        22-JUL-98  02:54:34
        22-JUL-98  08:34:07
        1072-1 xl/2
        07feb-m23conf
        m8290-23-072198£
          Total
          DPE
          LMC
              Name;     Resp;
      2,3,7,8-TCDF; 7.70e+05;
  130-2,3,7,8-TCDF; 5.29e+08;
      Tetra Furans; 6.36e+06;
            HxCDPE;        *;
QC CHK ION  (Tetra);        *;
   Ion 1;
3.38e+05;
2.32e+08;
3.05e+05;
   Ion 2;
4.32e+05;
2.97e+08;
3.85e+05;
  RA;?;
0.78,-y;
0.78,-y;
0.79;y;
   RT;
27:57;
27:55;
18:13;
   Cone;       DL;
  0.153;   0.0387;
129.679;
  1.264;   0.0387;
                          ;NotFnd;
                          ;NotFnd;
S/N1;?;
  ll;y;
1358;y;
  17 ;y;
   *;n
DivO;n
S/N2;?
  13,-y
1223;y
  21;y
mod?
 yes
  no
 ye
  no
  no
                                                                               27:57
                                                                               27:57
                                                                                                                                  yes
05
                                                                                                                                                       Page  12

-------
   File: A21JUL98F  Acq: 22-JUL-1998J 02:b4:J4  Exp: M^_DB22b Voltage SIR EH-  GC Autospec-UltimaE  Parac
   Sample #12  Text: 1072-1 xl/2  ALS #12
   303.9016 S:12 SMO(1,3) BSUB(128,15,-3.0) PKD(3,3,3,0.10%,3628.0,1.00%,F,F)
                              A4. 7E5
          16:00      18iOO      2  :00      22iOO      24100      26:00      28:00
   305.8987 S:12 SMO{1,3) BSUB(128,15,-3.0) PKD(3,3 , 3,0.10%,3744.0,1.00%,F,F)
                                                                           30:00
                                                                           32:00
                                                                                                           34:00
   100%

    90J

    80 j

    70J

    60 j

    50.:

    40 J

    30j

    20J

    10 j
                              A5.
           A3.85E5
                        OE5
                                            A4.80E5
                                   A3.97E5
                           A1.19E5
                                                               A4.32E5
                                                    .57E4
                                                        A1.42E4
                                                                                                         ILO.OEO
                                                                                                              Time
                                                                                                                    .O.OEO
                                                                                                                        Time
16:00
18:00
                                20:00
                                22:00
                                                     24:00
                                                      26:00
                                                                           28:00
                                                                 30:00
                                                                                      32:00
                                                                                      34:00
I

-------
                                                                    Paradigm Analytical Labs
                             Analytical Data Summary Sheet
Analyte
2,3,7,8-TCDD
1,2,3,4,7,8-HxCDD
1,2,3,7,8,9-HxCDD
f^3P^r^8-ti^fai> ' '
OCDD
l,2,3T7,8-PeCbF
2,3,4,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
1,2,3,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
OCDF
Total TCDDs
Total PeCDDs
Total HxCDDs
Total HpCDDs
Total TCDFs
Total PeCDFs
Total HxCDFs
Total HpCDFs
TEQ (ND=0)
TEQ (ND=l/2)
Concentration
0.0015
'EMPC
o.ociSSIf*]
0.0167
0.0038
BMPC '':'
0.0033
EMPC
EMPC
ND
0.0063
EMPC
0.0092
0.0119
0.0056
0.0076
0.0088
0.143
0.0312
0.0104
0.0076
0.0031
0.0033

0.0006
0.0004
0.0003
isMsipSjr -j
0.0011
0.0003
0.0005
0.0004
0.0005
0.0005
0.0005
0.0006
0.0011
0.0006
0.0003
0.0003
0.0006
0.0005
0.0003
0.0004
0.0005


'^
0.0020
-'v^Cw;
6.0024
0.0017
0.0012
0.0011
0.0146
0.0096
0.0164
0.153
0.0408
0.0132
0.0096
0.0048
0.0048

28:28
^H&^Slt'^
* - u ~-,-^WV, -s
34:43
':
35:00
fA
40:03
"shsiT"'3
32:24
34:11
34:15
34:38
35:08
36:23
37:32
40:11



^«Bifc,
0.75
1.85
4,41
1.65
v 'l^l-''.
0.94
1.51
1,31
1.30
1.49
1.46
0.17
1.15
1 24
0.9



Qualifier





*


ITEF
ITEF
Client Information
Project Name:
Sample ID:

Laboratory Information
Project SB;
Texas Lime Kiln
M23-O-3
LI072
Sample Information

Matrix:
Weight /VoHaae:
Moisture / LipioV
Analysis
                                               Air
                                                1
                                               0,0    %
                                                                     al7ju!98b-8
                                                                           '8b-l
                                                                                          067
                                        1/2

-------
                                                                      Paradigm Analytical Labs
                              Analytical Data Summary Sheet
Labeled
Standard
Extraction Standards
13C12-2,3,7,8-TCDD
15 i '• " - •,
13C12-l,2,3,6,7,8-HxCDD
"^y^&^S-HjiCDD'V '-
13C12-OCDD
"/"* 1 1 *7 C TY**TYI? ~v. - ~
*-'i2-4»'3»/*8~1*-JL't <-(£&£ *•• "•'.
13C12-l,2,3,7,8-PeCDF
13Cirl,2,3,6,7,8-HxCDF
"0,2-1,2,3,4,6,7,8-HpCDF
Sampling Standards
37CL4-23,7,8-TCDD
"0,2-2,3,4,7,8-PeCDF
13CI2-l,2,3,4,7,8-HxCDD
13C12-l,2,3,4,7,8-HxCDF
13Cl2-l,2,3,4,7,8,9-HpCDF
Injection Standards
13Ct2-l,2,3,4-TCDD
"0,2-1,2,3,7,8,9-HxCDD
AiNMf *
Amount
•^K— J

4
'^IS&jfc ^ll
4
- 0..>l*^fe , ^
8
4 „ J
4
4 -_- ,,i
4

4
4
4
4
4 , 1:
«*--
IVf easured <
,*^ "'>fiw) '';

3.58
3.25
*
^F^^ss^r
5.24
-
IWB^W^
3.52
£^ ::2.94, ' '
3.00

3.91
3.77
4.25
4.04
i 3.85

^J^Mt^-
*'•*• ifttf*-' ''-'

89.4
lissifel: ;.v'
81.1

65.5
'S%Rv
88.0
*- 73.5 .-
75.1

97.7
94.4
106.3
101.0
96,3

-."KT- -^
- '"•-'\'::r,,',-!:,'i*r|
{mia.) 5
.-.
28:27
,";
34:46
!^^^t7t J0^~^
40:02
*l*7.*l^C - / <
•|7:ie •;
31:57
34:15
36:22

28:28
32:24
34:43
34:11
37:32
: -28:10
34:59
«^-Jftim*ai-,v
^^^jfe&T'S?
^z*'" 1
—
0.78
;-vays
1 27

0.89
•'"'".-llMS" '-
1.56
0.52
0.45

1.57
1.24
0.52
0.45
0.79
1.25
Qualifier





\*"






Client Information
Project Name:
Sample ID:

Laboratory Information

Project ID:
Sample ID:

Collection Date:
Receipt Date:   *S**
                          Texas Lime Kiln
                          L1072
Sample Information

Matrix:
Weight/ Volume:
Moisture / Lipids:
                                                                           Air
                                                                            t
                                                                           O.Q
                                                                       al7jul98b-8
                                                                       al7ju!98b-l
                                                                       a!7ju!98b-2
                                                                       al7jul98b-15
                                                                       '488190-23471798
                                                                       r,,,-^
                                                                                       •       068
                                          2/2

-------
OP, n 20-JUL-1998
Filename al7ju!98b
Sample 8
Acquired 17-JUL-98
Processed 20-JUL-98
Sample ID 1072-2 xl/2
Page 1


22:01:31
09:04:44





















Cal Table m8290-23-071798




i:F-




s-
i\^^













Results Table M8290-23-071798B
Comments
Typ
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
ES/RT
ES
ES
ES
ES
ES/RT
ES
ES
ES
JS
JS
CS
CS
CS
CS
CS
SS
SS
SS
SS
SS
Name;
2,3,7,8-TCDD;
1, 2,3,7, 8-PeCDD;
1,2,3,4,7,8-HxCDD;
1,2,3,6,7,8-HxCDD;
1,2,3,7,8,9-HxCDD;
1,2,3,4,6,7, 8-HpCDD;
OCDD;
2,3,7,8-TCDF;
1, 2,3,7, 8-PeCDF;
2,3,4,7,8-PeCDF;
1,2,3,4,7,8-HxCDF;
1,2,3, 6,7,8-HxCDF;
2,3,4,6,7,8-HxCDF;
1,2,3,7,8,9-HxCDF;
1,2,3,4,6,7,8-HpCDF;
1,2,3,4,7,8, 9 -HpCDF ;
OCDF;
13C-2,3,7,8-TCDD;
13C-1 , 2,3,7, 8-PeCDD;
13C-l,2,3,6,7,8-HxCDD;
13C-l,2,3,4,6,7,8-HpCDD;
13C-OCDD;
13C-2,3,7,8-TCDF;
13C-1 , 2,3,7, 8-PeCDF;
13C-1 ,2,3,6,7, 8-HxCDF ;
13C-l,2,3,4,6,7,8-HpCDF;
13C-1,2,3,4-TCDD;
13C-l,2,3,7,8,9-HxCDD;
37Cl-2,3,7,8-TCDD;
13C-2, 3,4,7, 8-PeCDF;
13C-l,2,3,4,7,8-HxCDD;
13C-l,2,3,4,7,8-HxCDF;
13C-l,2,3,4,7,8,9-HpCDF;
37Cl-2,3,7,8-TCDD;
13C-2, 3,4,7, 8-PeCDF;
13C-l,2,3,4,7,8-HxCDD;
13C-1.2, 3,4,7,8-HxCDF;
13C-1.2, 3,4,7,8,9-HpCDF;


Resp;
3.856+05;
5.28e+04;
3.786+04;
1.086+05;
1.51e+05;
2.66e+05;
7.216+05;
2.05e+06;
3.76e+05;
2.48e+05;
2.67e+05;
1.69e+05;
l.Ole+05;
5.676+04;
4.606+05;
6.79e+04;
4.23e+05;
4.24e+08;
3.18e+08;
3.57e+08;
2.63e+08;
3.44e+08;
4.88e+08;
4.56e+08;
3.73e+08;
2.32e+08;
4.32e+08;
4.10e+08;
3.80e+08;
4.21e+08;
2.56e+08;
2.96e+08;
1.756+08;
3.806+08;
4.216+08;
2.56e+08;
2.96e+08;
1.75e+08;

Ion 1;
6.476+04;
3.216+04;
2.45e+04;
6.29e+04;
9.406+04;
1.34e+05;
3.50e+05;
8.836+05;
2.26e+05;
1.40e+05;
1.51e+05;
l.Ole+05;
6.006+04;
8.186+03;
2.46e+05;
3.77e+04;
2.006+05;
1.86e+08;
1.946+08;
2.00e+08;
1.34e+08;
1.62e+08;
2.156+08;
2.78e+08;
1.28e+08;
7.16e+07;
1.91e+08;
2.28e+08;
3.80e+08;
2.57e+08;
1.42e+08;
l.Ole+08;
5.406+07;
3.80e+08;
2.57e+08;
1.42e+08;
l.Ole+08;
5.406+07;

Ion 2;
3.21e+05;
2.076+04;
1.336+04;
4.476+04;
5.696+04;
1.336+05;
3.726+05;
1.17e+06;
1. 50e+05 ;
1. 08e+05;
1.16e+05;
6.78e+04;
4.11e+04;
4.856+04;
2.146+05;
3.03e+04;
2.236+05;
2.386+08;
1.246+08;
1.57e+08;
1.29e+08;
1.82e+08;
2.73e+08;
1.78e+08;
2.46e+08;
1.60e+08;
2.42e+08;
1.82e+08;
_;
1.64e+08;
1.14e+08;
1.95e+08;
1.216+08;
-;
1.646+08;
1.14e+08;
1.95e+08;
1.21e+08;

RA;?;
0.20;n;
1.55;y;
1.85;n;
1.41,-y;
1.65;n;
1.01;y;
0.94;y;
0.76;y;
1.51;y;
1.31;n;
1.30;y;
1.49;n;
1.46;n;
0.17;n;
1.15,-y;
1.24;n;
0.90,-y;
0.78;y;
1.57,-y;
1.27;y;
1.04;y;
0.89;y;
0.79;y;
1.56;y;
0.52;y;
0.45;y;
0.79;y;
1.25;y;

1.57;y;
1.24;y;
0.52;y;
0.45;y;
- ; _ ;
1.57,-y;
1.24,-y;
0.52;y;
0.45;y;

RT;
28:28;
32:38;
34:43;
34:47;
35:00;
37:11;
40:03;
27:29;
31:58;
32:24;
34:11;
34:15;
34:38;
35:08;
36:23;
37:32;
40:11;
28:27;
32:37;
34:46;
37:10;
40:02;
27:26;
31:57;
34:15;
36:22;
28:10;
34:59;
28:28;
32:24;
34:43;
34:11;
37:32;
28:28;
32:24;
34:43;
34:11;
37:32;

Cone;
0.092;
0.015;
0.016;
0.035;
0.049;
0.113;
0.418;
0.441;
0.095;
0.060;
0.083;
0.042;
0.029;
0.019;
0.157;
0.028;
0.230;
89.403;
96.147;
81.135;
80.694;
131.075;
81.920;
87.974;
73.475;
75.095;
89.652;
103.418;
87.282;
82.966;
86.321;
74.764;
72.298;
97.682;
94.340;
106.253;
100.947;
96.313;

DL;
0.0142;
0.0082;
0.0103;
0.0082;
0.0081;
0.0156;
0.0276;
0.0136;
0.0085;
0.0082;
0.0129;
0.0102;
0.0119;
0.0136;
0.0121;
0.0147;
0.0264;
0.0497;
0.0231;
0.0320;
0.0231;
0.0112;
0.0251;
0.0117;
0.1425;
0.0919;
- ;
- ,*
0.0192;
0.0120;
0.0474;
0.1828;
0.1174;
0.0217;
0.0080;
0.0557;
0.2224;
0.2084;

S/N1;?;
6;y;
5;y;
5;y;
13;y;
15;y;
22;y;
32;y;
66;y;
34;y;
26;y;
13;y;
9;y;
5;y;
l;n;
28;y;
4;y;
34;y;
3261;y;
19694;y;
6638;y;
4533;y;
23231;y;
11236;y;
43508 ;y;
1208;y;
1850;y;
3370;y;
7197;y;
13317;y;
42671;y;
4991;y;
992;y;
1225;y;
13317;y;
42671;y;
4991;y;
992 ;y;
1225;y;

S/N2;?
39;y
7;y
3;n
8;y
9;y
31,-y
97, -y
89 ;y
20 ;y
17 ;y
13 ;y
10 ;y
5;y
3;n
66, -y
8;y
25;y
10618;y
23668;y
10711;y
13757 ;y
17641;y
8870;y
32601;y
2199;y
1840;y
10955;y
11875;y
" 1 ~"
31817;y
7919 ;y
1801;y
1213;y
-; -
31817;y
7919;y
1801 ;y
1213;y
mod?
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
Page 13

-------
OPUSquan   20-JUL-1998
                                      Page 1
                                                                    Page  1  of  8

 Ent: 39 Name: Total Tetra-Furans  F:l  Mass:  303.902  305.899  Mod?  no   #Hom:20

 Run: 13 File: al7jul98b    S:8  Acq:17-JUL-98 22:01:31  Proc:20-JUL-98  09:04:44
 Tables: Run: al7ju!98b  Analyte: m8290-23-»  Cal:  m8290-23-»Results: M8290-23*
 Version: V3.5 17-APR-1997 11:14:34  Sample text:  1072-2 xl/2
   Amount: 3.85
     Cone: 3.85
   Tox #1: -
Name
 2,3,7,8-TCDF
of which 0.44
of which 0.44
     Tox #2:  -

#     RT Respnse
named and 3.41
named and 3.41
      Tox #3:  -
                                        RA
1  23:40 1.3e+06  0.75  y
         1.3e+06

2  24:15 5.66+05  0.69  y
         5.6e+05

3  24:34 l.Oe+06  0.76  y
         l.Oe+06

4  24:52 3.2e+06  0.78  y
         3.2e+06

5  25:02 3.3e+05  0.65  n
         3.3e+05

6  25:11 6.6e+05  0.58  n
         6.6e+05

7  25:16 l.le+06  0.88  y
         l.le+06

8  25:45 1.7e+06  0.75  y
         1.7e+06

9  26:01 5.1e+05  0.67  y
         S.le+05

10 26:09 l.le+06  0.71  y
         l.le+06

11 26:27 1.3e+06  0.73  y
         1.3e+06

12 26:34 5.0e+05  0.81  y
         5.0e+05

13 26:52 1.3e+06  0.75  y
         1.3e+06

14 27:11 3.1e+05  0.66  y
         3.1e+05

15 27:29 2.0e+06  0.76 y
         2.0e+06

16 28:04 5.6e+05  0.75 y
         5.6e+05

17 28:21 2.5e+05  0.75 y
         2.5e+05

18 28:35 5.7e+04  0.43 n
         5.7e+04

19 28:42 8.0e+03  0.24 n
         S.Oe+03
                                              Cone

                                               0.27
                                                   C
                                                   1
                                               0.12


                                               0.22
                                                   4
                                                   C
                                               0.68
                                                   1
                                                   1
                                               0.07
                                                   ]

                                               0.14

                                                   4
                                               0.23
                                                   C
                                                   C
                                               0.36
unnamed
unnamed
                  Area  Height    S/N  Mod? .
               5.4e+05 l.le+05 5.1e+01 y  n
               7.3e+05 1.5e+05 7.0e+01 y  n
              2
               2.3e+05 5.1e+04 2.4e+01 y  n
               3.3e+05 7.0e+04 3.3e+01 y  n

                .4e+05 9.4e+04 4.3e+01 y  n
               5.8e+05 1.2e+05 5.7e+01 y  n
              3
               1.4e+06 2.7e+05 1.3e+02 y  n
               1.8e+06 3.3e+05 1.6e+02 y  n

                .3e+05 2.6e+04 1.2e+01 y  n
               2.0e+05 3.8e+04 1.8e+01 y  n
              I
               2.4e+05 5.5e+04 2.6e+01 y  n
               4.2e+05 8.0e+04 3.8e+01 y  n

               5.1e+05 6.7e+04 3.1e+01 y  n
               5.8e+05 7.8e+04 3.7e+01 y  n
                                               0.11
                                               0.25
                                               0.27
                                               0.11
                                               0.27
               7.1e+05 8.7e+04 4.0e+01 y  n
               9.5e+05 1.2e+05 5.8e+01 y  n
              1
               2.0e+05 4.8e+04 2.2e+01 y  n
               3.0e+05 6.2e+04 2.9e+01 y  n

               4.7e+05 9.6e+04 4.4e+01 y  n
               6.7e+05 1.36+05 6.36+01 y  n
              7
               5.4e+05 9.7e+04 4.5e+01 y  n
               7.3e+05 1.3e+05 6.0e+01 y  n
              1
               2.3e+05 5.0e+04 2.3e+01 y  n
               2.8e+05 5.8e+04 2.8e+01 y  n
                                               0.07
                                                   5.46+05 l.le+05 5.0e+01 y
                                                   7.26+05 1.5e+05 7.2e+01 y
                                               0.44
                                               0.12
                                                0.05
                                                0.01
                                                0.00
                1.2e+05 2.8e+04 1.3e+01 y  n
                1.9e+05 4.0e+04 1.9e+01 y  n
               4
                8.8e+05 1.4e+05 6.6e+01 y  n
                1.2e+06 1.9e+05 8.9e+01 y  n
               2
                2.4e+05 5.3e+04 2.4e+01 y  n
                3.26+05 6.3e+04 3.0e+01 y  n

                l.le+05 2.0e+04 9.2e+00 y  n
                1.4e+05 3.1e+04 1.5e+01 y  n
               L
                1.76+04 6.0e+03 2.8e+00 n  n
                4.0e+04 8.4e+03 4.0e+00 y  n
                                                    1.5e+03  5.5e+02 2.6e-01 n  n
                                                    6.5e+03  1.4e+03 6.5e-01 n  n
                                                                                                           070

-------
OPUSquan   20-JUL-1998
                   Page 2
                   20 29:48 2.5e+05  1.43 n
                            2.5e+05
                                               0.05
                                                   1.5e+05 2.7e+04  1.3e+01 y  n
                                                   l.Oe+05 1.9e+04  9.0e+00 y  n
                                                                    Page 2 of 8

 Ent: 40 Name: Total Tetra-Dioxins F:l  Mass: 319.897 321.894 Mod? no   #Hom:7

 Run: 13 File: al7ju!98b    S:8  Acq:17-JUL-98 22:01:31 Proc:20-JUL-98 09:04:44
 Tables: Run: al7jul98b  Analyte: m8290-23-»  Cal: m8290-23-»Results: M8290-23»
 Version: V3.5 17-APR-1997 11:14:34  Sample text: 1072-2 xl/2
   Amount: 0.44
     Cone: Q.44
   Tox #1: -
Name
 2,3,7,8-TCDD
of which 0.09
of which 0.09
     Tox #2:  -
                   #
named and 0.35
named and 0.35
      Tox #3:  -
                         RT Respnse
                                        RA
1  25:16 7.4e+05  0.77 y
         7.4e+05

2  25:42 3.2e+05  0.82 y
         3.2e+05

3  26:05 4.6e+04  0.39 n
         4.6e+04

4  26:55 2.1e+05  0.62 n
         2.1e+05

5  28:11 7.7e+04  0.53 n
         7.7e+04

6  28:20 8.0e+04  0.90 n
         8.0e+04

7  28:28 3.9e+05  0.20 n
         3.9e+05
          Cone

           0.18
               3
               4
           0.08
               3
               ]
           0.01
               ]

           0.05
               1
               ]
           0.02

               c
           0.02
               3
               4
           0.09
   unnamed
   unnamed
                                   Area  Height
                                                                      S/N  Mod?
                                                   3.2e+05 6.5e+04 2.9e+01 y  n
                                                   4.2e+05 9.0e+04 5.2e+01 y  n

                                                   1.4e+05 3.1e+04 1.4e+01 y  n
                                                   1.8e+05 3.5e+04 2.0e+01 y  n

                                                   1.3e+04 4.36+03 1.9e+00 n  n
                                                   3.3e+04 7.26+03 4.2e+00 y  n
                                                  5
                                                   7.9e+04 1.6e+04 7.2e+00 y  n
                                                   1.36+05 2.16+04 1.2e+01 y  n

                                                   2.7e+04 6.2e+03 2.8e+00 n  n
                                                   5.0e+04 l.le+04 6.4e+00 y  n
3.8e+04 8.0e+03 3.6e+00 y  n
4.26+04 9.0e+03 5.2e+00 y  n

6.56+04 1.46+04 6.4e+00 y  n
3.2e+05 6.76+04 3.9e+01 y  n
                                                                                                  r
                                                                                      071

-------
OPUSquan   20-JUL-1998
                   Page  3
                                                                    Page 3 of 8

 Ent: 41 Name: Total Penta-Furans  F:2  Mass:  339.860 341.857 Mod? no   #Hom:12

 Run: 13 File: a!7ju!98b    S:8  Acq:17-JUL-98 22:01:31 Proc:20-JUL-98 09:04:44
 Tables: Run: al7ju!98b  Analyte: m8290-23-»  Cal:  m8290-23-»Results: M8290-23*
 Version: V3.5 17-APR-1997 11:14:34  Sample text: 1072-2 xl/2
   Amount: 1.05
     Cone: 1.05
   Tox #1: -
Name
of which 0.15
of which 0.15
     Tox #2:  -

#     RT Respnse
                 named and 0.89
                 named and 0.89
                       Tox #3:  -
                                        RA
1,2,3,7,8-PeCDF
1  30:17 3.0e+05  1.26 n
         3.0e+05

2  31:17 1.4e+05  1.46 y
         1.46+05

3  31:22 2.1e+06  1.57 y
         2.1e+06

4  31:28 1.6e+05  1.75 y
         1.6e+05

5  31:36 6.26+04  2.32 n
         6.2e+04

6  31:46 3.36+05  1.65 y
         3.36+05

7  31:58 3.8e+05  1.51 y
         3.8e+05

8  32:04 1.2e+05  1.61 y
         1.2e+05

9  32:09 1.9e+05  1.29 n
         1.9e+05
         Cone

          0.0-7
              1
              1
          0.03
              £
              c
          0.51
              1
              8
          0.04
              1
              C
          0.02
              4
              ]
          0.08
              2
              1
          0.09

              2
          0.03
                 unnamed
                 unnamed
                                   Area  Height    S/N  Mod? $'
                                                   1.7e+05 3.5e+04 1.8e+01 y  n
                                                   1.3e+05 2.7e+04 1.3e+01 y  n
                                                  3
                                                   8.1e+04 2.9e+04 1.6e+01 y  n
                                                   5.6e+04 2.0e+04 9.9e+00 y  n
                                                  L
                                                   1.36+06 4.06+05 2.1e+02 y  n
                                                   8.0e+05 2.5e+05 1.3e+02 y  n
                                                  1
                                                   l.Oe+05 2.3e+04 1.2e+01 y  n
                                                   5.7e+04 1.4e+04 7.0e+00 y  n

                                                    .4e+04 l.Oe+04 5.4e+00 y  n
                                                    .96+04 5.66+03 2.86+00 n  n
                                2.1e+05 6.7e+04 3.5e+01 y  n
                                1.2e+05 3.4e+04 1.7e+01 y  n
                               5
                                2.36+05 6.4e+04 3.4e+01 y  n
                                1.56+05 4.1e+04 2.0e+01 y  n
 2,3,4,7,8-PeCDF
10 32:24 2.5e+05
         2.5e+05
                                      1.31 n
                    11  32:30  2.0e+05   1.09 n
                             2.0e+05

                    12  32:58  4.8e+04   0.82 n
                             4.8e+04
                                               0.05
                                               0.06
                                                0.05
               7.6e+04  2.56+04  1.3e+01  y  n
               4.7e+04  1.8e+04  8.7e+00  y  n

               l.le+05  4.1e+04  2.1e+01  y  n
               8.3e+04  2.9e+04  1.5e+01  y  n

               1.4e+05  4.8e+04  2.6e+01  y  n
               l.le+05  3.4e+04  1.7e+01  y  n

               l.le+05  3.7e+04  1.9e+01  y  n
               9.76+04  3.46+04  1.7e+01  y  n
                            0.01
                                                    2.2e+04  7.2e+03  3.8e+00  y  n
                                                    2.6e+04  8.6e+03  4.3e+00  y  n
                                                                     Page 4  of 8

  Ent:  42 Name:  Total Penta-Dioxins F:2   Mass:  355.855  357.852  Mod?  no   §Hom:ll

  Run:  13 File:  al7ju!98b    S:8  Acq:17-JUL-98 22:01:31  Proc:20-JUL-98  09:04:44
  Tables: Run:  a!7ju!98b  Analyte: m8290-23-»  Cal:  m8290-23-»Results: M8290-23*
  Version: V3.5 17-APR-1997 11:14:34  Sample text:  1072-2 xl/2
    Amount:  0.25
      Cone:  0.25
    Tox #1:  -
 Name
 of which  0.01
 of which  0.01
      Tox  #2: -

 #      RT  Respnse
named and 0.23
named and 0.23
      Tox #3: -
                                         RA
                    1  31:30 2.7e+05  1.44 y
                             2.76+05

                    2  31:40 5.1e+03  1.24 n
                             5.1e+03
          Cone

           0.08
               3
               ]
           0.00
                                    unnamed
                                    unnamed
                                                       Area  Height
                                  S/N  Mod?
                                 1.6e+05  5.3e+04  2.4e+01  y  n
                                 l.le+05  3.4e+04  3.1e+01  y  n
                                3
                                 2.8e+03  1.6e+03  7.0e-01  n  n

-------
OPUSquan   20-JUL-1998
                                      Page 4
                                                  2.3e+03  7.5e+02 6.9e-01 n  n
                   3  31:44 7.7e+03   1.68  y    0.00
                            7.7e+03

                   4  31:49 6.56+04   1.70  y    0.02
                            6.56+04

                   5  32:00 1.8e+05   1.91  n    0.05
                            1.8e+05

                   6  32:05 4.4e+04   1.58  y    0.01
                            4.4e+04

                   7  32:10 8.1e+04   1.91  n    0.02
                            8.le+04

                   8  32:20 6.6e+04   1.46  y    0.02
                            6.66+04

                   9  32:24 9.3e+04   3.08  n    0.03
                            9.3e+04

1,2,3,7,8-PeCDD    10 32:38 5.3e+04   1.55  y    0.01
                            5.3e+04

                   11 32:44 1.3e+04   3.02  n    0.00
                            1.3e+04
 9e+03 1.9e+03 8.3e-01 n  n
 9e+03 9.8e+02 8.9e-01 n  n

,le+04 1.3e+04 5.9e+00 y  n
,4e+04 8.4e+03 7.7e+00 y  n

,2e+05 2.56+04 l.le+01 y  n
 le+04 2.0e+04 1.8e+01 y  n

,7e+04 l.Oe+04 4.6e+00 y  n
,7e+04 5.7e+03 5.2e+00 y  n

 3e+04 1.96+04 8.4e+00 y  n
,8e+04 9.9e+03 9.1e+00 y  n

,9e+04 9.2e+03 4.1e+00 y  n
, 7e+04 7.8e+03 7.1e+00 y  n

. Oe+04 1.8e+04 7.9e+00 y  n
 3e+04 5.2e+03 4.7e+00 y  n

,2e+04 1.le+04 4.9e+00 y  n
,le+04 7.4e+03 6.8e+00 y  n

,0e+04 4.2e+03 1.9e+00 n  n
,3e+03 1.3e+03 1.2e+00 n  n
                                                                                                   r
                                                      073

-------
OPUSguan   20-OUL-1998
                   Page 5
 Ent: 43 Name: Total Hexa-Furans
                                                Page 5  of  8

                F:3  Mass:  373.821 375.818 Mod? no    #Hom:ll
 Run: 13 File: al7ju!98b    S:8  Acq:17-JUL-98 22:01:31 Proc:20-JOL-98 09:04:44
 Tables: Run: al7ju!98b  Analyte: m8290-23-»  Cal: m8290-23-»Results:  M8290-23*
 Version: V3.5 17-APR-1997 11:14:34  Sample text: 1072-2 xl/2
   Amount: 0.39
     Cone: 0.39
   Tox #1: -
 vlame
of which 0.17
of which 0.17
     Tox #2:  -

#     RT Respnse
named and 0.22
named and 0.22
      Tox #3: -
                                        RA
                   1  33:32 2.9e+05  1.24 y
                            2.9e+05

                   2  33:38 2.8e+05  1.30 y
                            2.8e+05

                   3  33:43 2.2e+04  1.77 n
                            2.2e+04

                   4  33:49 3.2e+04  0.71 n
                            3.2e-i-04

                   5  33:56 6.6e+04  1.30 y
                            6.6e+04

                   6  34:02 3.2e+03  2.35 n
                            3.2e+03

 1,2,3,4,7,8-HxCDF  7  34:11 2.7e+05  1.30y
                            2.7e+05
 1,2,3,6,7,8-HxCDF  8   34:15  1.76+05
                             1.7e+05
                                      1.49  n
 2,3,4,6,7,8-HxCDF  9
   34:38 l.Oe+05  1.46 n
         l.Oe+05
 1,2,3,7,8,9-HxCDF  10 35:08  5.7e+04   0.17  n
                             5.76+04
                    11 35:12 6.5e+04
                             6.5e+04
                                      0.34 n
          Cone

           0.08
               1
               3
           0.08
               1
               1
           0.01
               1
               7
           0.01
               3
               1
           0.02


           0.00

               c
           0.08
               1
               1
           0.04
               3
                <
           0.03
                e
               .3
           0.02
                £
                <
           0.02
   unnamed
   unnamed
   Area  Height
                                                                      S/N  Mod?
                                1.6e+05 6.1e+04 1.8e+01 y  n
                                1.3e+05 4.9e+04 1.9e+01 y  n
                               3
                                1.6e+05 5.7e+04 1.7e+01 y  n
                                1.2e+05 4.76+04 1.8e+01 y  n
                               I
                                1.4e+04 5.4e+03 1.6e+00 n  n
                                7.8e+03 3.3e+03 1.3e+00 n  n
                               I
                                1.36+04 4.6e+03 1.3e+00 n  n
                                1.9e+04 6.3e+03 2.4e+00 n  n

                                3.7e+04 1.36+04 3.7e+00 y  n
                                2.9e+04 l.le+04 4.2e+00 y  n
 2.2e+03  l.Oe+03  3.0e-01 n  n
 9.56+02  7.2e+02  2.8e-01 n  n
3
 1.5e+05  4.4e+04  1.3e+01 y  n
 1.26+05  3.5e+04  1.3e+01 y  n

 l.Oe+05  3.3e+04  9.4e+00 y  n
 6.8e+04  2.7e+04  l.Oe+01 y  n

 6.06+04  1.6e+04  4.7e+00 y  n
 4.1e+04  1.46+04  5.3e+00 y  n

  .2e+03  3.9e+03  l.le+00 n  n
  .86+04  7.3e+03  2.8e+00 n  n
                                 1.76+04  4.9e+03  1.4e+00  n  n
                                 4.8e+04  7.3e+03  2.8e+00  n  n
                                                                     Page 6 of 8

  Ent: 44 Name: Total Hexa-Dioxins  F:3  Mass:  389.816 391.813 Mod? no   #Hom:14

  Run: 13 File: a!7ju!98b    S:8  Acg:17-JUL-98 22:01:31 Proc:20-JUL-98 09:04:44
  Tables: Run: a!7ju!98b  Analyte: m8290-23-»  Cal: m8290-23-»Results: M8290-23»
  Version: V3.5 17-APR-1997 11:14:34  San«3le text: 1072-2 xl/2
    Amount: 0.44
      Cone: 0.44
    Tox #1: -
 Name
 of which 0.10
 of which 0.10
      Tox #2:  -

 #     RT Respnse
 named and 0.34
 named and 0.34
       Tox #3: -
    unnamed
    unnamed
                                         RA
                    1  33:53 4.2e+05  1.39 y
                             4.26+05

                    2  34:00 1.4e+04  4.53 n
                             1.4e+04

                    3  34:11 2.4e+05  1.61 n
                             2.4e+05
           Cone    Area  Height

            0.15
                                                                       S/N  Mod?
                             0.01
                             0.08
                2.5e+05 8.4e+04 5.2e+01 y  n
                1.8e+05 6.0e+04 3.3e+01 y  n
               L
                1.2e+04 3.9e+03 2.5e+00 n  n
                2.6e+03 1.4e+03 7.5e-01 n  n
               3
                1.5e+05 4.8e+04 3.0e+01 y  n

-------
OPUSquan 20-JUL-1998

4 34:20 2
2

1,2, 3,4,7, 8-HxCDD 5 34:43 3
3

1,2,3,6,7,8-HxCDD 6 34:47 1
1

1,2,3,7,8,9-HxCDD 7 35:00 1
1

8 35:09 4
4

9 35:13 3
3

Page 6

5e+05 1.55 n
5e+05

8e+04 1.85 n
8e+04

le+05 1.41 y
le+05

5e+05 1.65 n
5e+05

4e+03 1.20 y
4e+03

7e+03 1.53 n
7e+03


9
0.09
1
9
0.02
2
1
0.04
6
4
0.05
9
5
0.00
2
2
0.00
2
1

.le+04

-5e+05
.9e+04

.4e+04
.3e+04

.3e+04
.5e+04

.4e+04
.7e+04

.4e+03
.Oe+03

.2e+03
.5e+03

2.

4.
3.

8.
5.

2.
1.

2.
1.

9.
1.

8.
6.

8e+04

Oe+04
le+04

4e+03
2e+03

le+04
5e+04

4e+04
6e+04

7e+02
Oe+03

le+02
2e+02

1

2
1

5
2

1
8

1
8

6
5

5
3

.5e+01

.5e+01
.7e+01

.3e+00
.9e+00

.3e+01
.3e+00

.5e+01
.9e+00

.le-01
.7e-01

.Oe-01
.4e-01

y

y
y

y
n

y
y

y
y

n
n

n
n

n

n
n

n
n

n
n

n
n

n
n

n
n
10 35:17 9.9e+03  0.29 n    0.00
         9.9e+03

11 35:25 8.9e+03  2.44 n    0.00
         8.9e+03

12 35:30 1.Oe+04  2.70 n    0.00
         1.Oe+04

13 35:37 2.6e+03  6.37 n    0.00
         2.6e+03
                                2.
                                7.
                               D
                                6.
                                2.
                               D
                                7.
                                2
                               0
                                2
                                3
14 35:43 3.2e+03  1.29 y    0.00
         3.2e+03                1
                                1
,2e+03  1.3e+03  8.2e-01  n  n
.7e+03  1.7e+03  9.le-01  n  n

. 3e+03  1.7e+03  l.le+00  n  n
.6e+03  1.3e+03  7.le-01  n  n

.5e+03  1.7e+03  l.Oe+00  n  n
.8e+03  1.3e+03  7.3e-01  n  n

.3e+03  8.7e+02  5.4e-01  n  n
.6e+02  1.8e+02  1.Oe-01  n  n

.8e+03  5. le+02  3.2e-01  n  n
,4e+03  7.le+02  3.9e-01  n  n

-------
OPUSquan   20-JUL-1998
                   Page 7
                                                                    Page 7 of 8

 Ent: 45 Name: Total Hepta-Furans  F:4  Mass: 407.782 409.779 Mod? no   #Hom:4

 Run: 13 File: al7ju!98b    S:8  Acq: 17-JUL-98 22:01:31 Proc:20-JUL-98 09:04:44
 Tables: Run: a!7ju!98b  Analyte: m8290-23-»  Cal: m8290-23-»Results: M8290-23»
 Version: V3.5 17-APR-1997 11:14:34  Sample text: 1072-2 xl/2
   Amount: 0.24
     Cone: 0.24
   Tox #1: -
Name
of which 0.19
of which 0.19
     Tox #2:  -

#     RT Respnse
named and 0.05
named and 0.05
      Tox #3:  -
                                        RA
1,2,3,4,6,7,8-HpCDFl   36:23 4.6e+05  1.15 y
                            4.6e+05

                    2   36:34 4.7e+04  1.30 n
                            4.7e+04

                    3   36:41 8.6e+04  1.09 y
                            8.6e+04

l,2,3,4,7,8,9-HpCDF4   37:32 6.8e+04  1.24n
                            6.8e+04
          Cone

           0.16


           0.02


           0.03
               <
               t,
           0.03
  unnamed
  unnamed
  Area  Height    S/N  Mod?
                                2.56+05 7.1e+04 2.8e+01 y  n
                                2.1e+05 6.76+04 6.6e+01 y  n
                               2
                                2.7e+04 8.7e+03 3.5e+00 y  n
                                2.1e+04 7.8e+03 7.7e+00 y  n

                                4.5e+04 1.3e+04 5.4e+00 y  n
                                4.1e+04 1.4e+04 1.4e+01 y  n
                               3
                                3.8e+04 9.9e+03 4.0e+00 y  n
                                3.0e+04 8.2e+03 8.1e+00 y  n
                                                                    Page  8  of  8

  Ent:  46 Name:  Total  Hepta-Dioxins F:4  Mass: 423.777 425.774 Mod? no   #Hom:4

  Run:  13 File:  al7ju!98b    S:8  Acq:17-JUL-98 22:01:31  Proc:20-JUL-98  09:04:44
  Tables: Run:  a!7ju!98b  Analyte: m8290-23-»  Cal: m8290-23-»Results: M8290-23»
  Version:  V3.5  17-APR-1997  11:14:34   Sample text:  1072-2 xl/2
    Amount:  0.27
      Cone:  0.27
    Tox #1:  -
 Name
of which 0.11
of which 0.11
     Tox #2: -

#     RT Respnse

1  36:22 6.9e+04
         6.9e+04
named and 0.16
named and 0.16
      Tox #3: -
                                         RA

                                      J.52  n
                    2  36:36 2.5e+05   1.06  y
                             2.5e+05

 1,2,3,4,6,7,8-HpCDD3  37:112.7e+05   l.Oly
                             2.7e+05

                    4  37:32 4.9e+04   6.98  n
                             4.9e+04
          Cone

           0.03
               (

           0.11
               ]
               ]
           0.11
               ]
               :
           0.02
   unnamed
   unnamed
                                                       Area  Height    S/N  Mod?
6.2e+04 1.9e+04 l.le+01 y  n
7.2e+03 2.8e+03 2.1e+00 n  n

 .3e+05 3.8e+04 2.1e+01 y  n
 .2e+05 3.7e+04 2.86+01 y  n

 .3e+05 4.0e+04 2.2e+01 y  n
 .3e+05 4.1e+04 3.1e+01 y  n

4.3e+04 1.2e+04 6.9e+00 y  n
6.16+03 2.2e+03 1.7e+00 n  n

-------
File: A17JUL58B Acq: 17-JUL-1998 22:01
Sample #8 Text: 1072-2 xl/2 ALS #8
319.8965 S:8 SMO(1,3) BSUB(128, 15, -3 . 0)
100% A3. 2
/
0: 	 , . /
24:00 25:00
321.8936 S:8 SMO(1,3) BSUB(128, 15, -3 . 0)
100% A4.2
1
n" -i- . . - '
24:00 25:00
331.9368 S:8 SMO(1,3) BSUB(128, 15, -3 .0)
100%
50J
o:
333.9339 S:8 SMO(1,3) BSUB(128 , 15, -3 .0)
100%
50 j
0:
24:00 25:00
327.8847 S:8 SMO(1,3) BSUB(128, 15, -3 .0)
1003
50 j
°: , ,
24:00 25:00
316.9824 S:8 SMO(1,3) PKD(3, 3 , 3 , 100 . 00%,
100% 23:18 23:59 24^5025:10
50 j
o: 	 	 ,
24:00 25:00
:31 Exp: EXP_M23_DB5_OVATION
PKD( 3, 3, 3, 0.10%, 223 6. 0,1. 00%
4E5
A1.43E5
A A7.91E4
\ \ A1.28E4 /\
V * \~. -^^ / \
26loO 27100
PKD( 3, 3, 3, 0.10%, 172 0.0, 1.00%,
;IE5
A1.75E5
J\ A3.J28E4 /Y
2e!oo 27loo
PKD(3, 3, 3, 0.10%, 11464. 0,1. 00%
2eloo 27loo
PKD (3, 3, 3, 0.10%, 4484. 0,1. 00%,
26:00 27loO
PKD (3, 3, 3, 0.10% ,5640. 0,1. 00%,
2e!oo 27loo
0.0,1.00%,F,F)
25i51 26:13 26:39 27:02

26:00 27:00
Voltage SIR EI+ GC Autospec-UltimaE Paradigm
F,F)
6.6E4
.3.3E4
A6.47E4
—A 	 ^Zv/^_ A9.26E3
28:00 29:00 30 00 Time
F,F)
A3.21E5 F
A _4 . 6E4
~ - ,~t A5^4^ I A1.20E4 ;0 nirn
28:00 29:00 30 00 Time
,F,F)
A1.91E8 3.9E7
/ 1 / \ "1 ' 9E7
28 !00 29! 00 	 3o!oO Time
F,F)
A2.42E8 4.9E7
A A
/ V J V 0 ORO
28 loo 	 29 100 	 30 100 Time
F,F)
A3.80E8 7.5E7
/ 1 .3 . 8E7
28 100 29 I 00 	 30 100 Time
27:29 28:13 28-50 29:13 29J6 7.0E7
i_3 . 5E7
0 . ORO
28 100 29:00 ' ' 30:00 Time

-------
File: A17JUL98B Acq: 17-JUL-1998 22:01:31 Exp: EXP_M23_DB5_OVATION
Sample #8 Text: 1072-2 xl/2 ALS #8
355.8546 S:8 F:2 SMO(1,3) BSUB( 128 , 15, -3 . 0) PKD(3 , 3 , 3 , 0 . 10%, 2240 . 0 , 1
100%
50"

0
A1.57E5
A
/ I A1'
/ \ A4.07E4/
\ f\ 1
: 	 -*» 	 — - —- . 	 _. 	 , 	 . 	 • 	 , 	 	 - 	 — 	 i— 	 ^ 	 — — 1 	 rV,^"^ 	 *^ 	
30ll2 30124 30136 30148 31:00 31:12 31:24 31:36 31:48 32
357.8517 S:8 F:2 SMO(1,3) BSUB (128, 15, -3 . 0) PKD(3 , 3 , 3 , 0 . 10%, 1096 . 0 , 1
100%
.
so:
•
0"
A1.09E5
A
\ A6-
/ /
/ \ A2.39E4 /
/ \ /\ /

30:12 30124 30136 30:48 31:00 31:12 31:24 31:36 31:48 32
367.8949 S:8 F:2 SMO(1,3) BSUB(128, 15, -3 . 0) PKD(3 , 3, 3 , 0 .10%, 3388 . 0, 1
100!
so:
0"



" '1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 | 1 1 1 1 1 1 1 1 1 I-'T I 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 | 1 1 1 l l | l l l ' l
3oll2 30124 30136 30148 31:00 31:12 31:24 31:36 31:48 32
369.8919 S:8 F:2 SMO(1,3) BSUB(128, 15, -3 . 0) PKD(3 , 3 , 3 , 0 . 10%, 1784 . 0 , 1
100*
50_




•J' 'l i I l i i i i i i i i i i I i i i T— r— r i i i i i i i i i i i l i i i i i l r i i i i | 	 | 	
30ll2 30:24 30l36 30l48 31:00 31:12 31:24 31:36 31:48 32
Voltage SIR EI + GC Autospec-UltimaE Paradigm

.00%,F,F)

16E5
<\ A5.35E4 A7.02E4
\ l\ f\ rk
v\/ V ^r V_ /N:^OE4 ^-^
5.5E4
_2.7E4

O.OEO
166 321: 12 32124 32136 32148 33166 33112 Time
.00%,F,F)

05E4
\
\ A2.80E4 A2.07E4
V/\/ V ^-'V-/^-^ -'\«ar^. ^^
3.5E4

_1.8E4

O.OEO
166 32li2' 32124 32136 32148 33lo6 33ll2 Time
.00%,F,F)
Al . 94E8
A
I \^
6.7E7
13.3E7
LO.OEO
166 32112 32124 32136 32148 33166 33112 Time
.00%,F,F)
A1.24E8
A

4.2E7
.2.1E7
.O.OEO
100 32:12 32:24 32:36 32:48 33:00 33:12 Time
366.9792 S:8 F:2 SMO(1,3) PKD(3, 3,3 , 100 . 00%, 0 .0, 1 . 00%,F,F)
!0oi ™-'« ™--** 31:12 31:29 31:4731:56 32:29 32:42 32:54 33.06 r7.8E7
-
so:
0"
" \/


" 'i l l l 	 1 l l i i i 1 i-i— i—r-r-r i i i I I I 	 | 	 | ' ' ' ' ' | ' ' ' • • | • ' ' ' '
30ll2 30124 30136 30:48 31:00 31:12 31:24 31:36 31:48 32




13 . 9E7
'O.OEO
166 32:12 321 24 32136 32:48 33166 33:12 Time

-------
File: A17JUL98B Acq: 17-JUL-1998 22:01:31 Exp : EXP_M23_DB5_OVATION Voltage SIR EI + GC Autospec-Ul timaE Paradigm
Sample #8 Text: 1072-2 xl/2 ALS #8
389.8156 S:8 F:3 SMO(1,3) BSUB(128 , 15, -3 . 0) PKD(3 , 5 , 2 , 0 . 10%, 1600 . 0 , 1 . 00%, F, F)
1003

50_

•
0
A2.47E5
A
/\
/ \ A1.47E5
/ A ^
/ i / V\ / A A6.29E4 A9.40E4
/ V / rv V_ ^y\ /V
1 ^~ — . / 1 r x — •-— . ^ — r \ J ^-^^
8.5E4

.4.2E4


.O.OEO
33:24 33:36 33:48 34loO 34:12 34I24 34:36 34:48 3s!oO 35:12 35:24 35:36 35:48 Time
391.8127 S:8 F:3 SMO(1,3) BSUB (128 , 15, -3 . 0) PKD(3 , 5 , 2 , 0 . 10% , 1832 . 0 , 1 . 00%, F, F)
1002
so:
-
0"
Al . 77E5
/ \ A9.89E4
/I ^ A
I A A A4A7E4 A/\E4
/ v_ / vy v_ /vv ^L\^
6.2E4
13.1E4

O.OEO
33:24 33:36 33:48 34:00 34:12 34:24 34:36 34:48 35:00 35:12 35:24 35:36 35:48 Time
401.8559 S:8 F:3 BSUB{128, 15, -3 . 0) PKD(3 , 5 , 2 , 0 . 10%, 12424 . 0, 1 . 00%, F, F)
100%
so:
0:
A2.00E8 A2.28E8
M A
/"V. /V-
8 . 9E7
_4 . 5E7
.O.OEO
33J24 33:36 33:48 34:00 34ll2 34^24 34:36 34:48 35:00 35:12 35:24 35:36 35:48 Time
403.8530 S:8 F:3 BSUB(128, 15, -3 . 0) PKD(3 , 5 , 2 , 0 . 10%, 6120 . 0 , 1 . 00%,F,F)
100%
so:
0"
A1.57E8 A1-?2E8
A A
A\ /I

7.3E7
13 . 6E7
LO.OEO
33:24 33:36 33:48 34:00 34:12 34:24 34:36 34:48 35:00 35:12 35:24 35:36 35 48 Time
380.9760 S:8 F:3 SMO(1,3) PKD(3 , 3 , 3 , 100 . 00%, 0 . 0 , 1 . 00%, F, F)
lOOi
so:
0"
33:28 33:37 34:02 34:15 34:31 34:44 34_L56 35:17 35^29 35:37
^

-1.8E8
_8.8E7
_O.OEO
33:24' ' '33:36' ' 33:48 34:00 34:12 34:24 34:36 '34:48 35:00 35:12 35:24 35:36' 35:48 Time

-------
Fil«
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5: A17JUL98B Acq: 17-JUL-1998 22:01:
sle #8 Text: 1072-2 xl/2 ALS #8
7767 S:8 F:4 SMO(1,3) BSUB (128 , 15, -3
i A1.28E5
A
A6.17E4 / \
... AlL~
36:00 36:12 36:24 36:36 36:48
7737 S:8 F:4 SMO(1,3) BSUB (128 , 15, -3
A1.20E5
A
A
A7>24E3 / V^_
36166 36112 36124 36136 36:48
8169 S:8 F:4 SMO(1,3) BSUB ( 128 , 15, -3

36166 36112 36124 36:36 36148
8140 S:8 F:4 SMO(1,3) BSUB (128, 15, -3

31 Exp: EXP_M23_DB5_OVATION Voltage SIR EI+ GC Autospec-UltimaE Paradigm
.0) PKD(3,3,3,0.10%,1788.0,1.00%,F,F)
A1.34E5 4.2E4
/ I A4.28E4
\ A A1.84E4
/ v — - / V__ /— -^ 	 ^
37:00 37:12 37:24 37:36 37:48 38:00 38:12 38124 38136 38148 39
.0) PKD(3,3,3,0.10%,1332.0,1.00%,F,F)
A1.33E5
A
A
/ V A6.14E3
' ^^y i.-^ S~~*-
37I66 37!i2 37124 inlie' 3^48 38166 38112 38:24 38136 38:48 39:
.0) PKD(3,3,3,0.10%,7536.0,1.00%,F,F)
Al . 34E8
/^
37166 37112 37124 37136 37148 38166 38li2 38124 38136 SsUs 39.'
.0) PKD(3,3,3,0.10%,2384.0,1.00%,F,F)
Al . 2 9E8

36:00 36:12 36:24 36:36 36:48 37:00 37:12 37:24 37:36 37:48 38:00 38:12 38:24 38:36 38:48 39:
9728 S:8 F:4 SMO(1,3) PKD(3 , 3 , 3 , 100 . 00%, 0 . 0 , 1 . 00%, F, F)
36:08 36x2336:32 36:55 37:25 37:49 38:1938:29 38:53

36166 36112 36124 36136 36\4B

37:00 37:12 37:24 37:36 37:48 38:00 38:12 38:24 38:36 38:48 39l
-2.1E4
LO.OEO
00 Time
4 . 3E4
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3.4E7
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_3.3E7
1.6E7
O.OEO
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1.1E8
_5.7E7
O.OEO
50 Time

-------
File: A1VJUL98B Acq: 17-JUL-1998 22:01:31 Exp: EXP_M23_DB5_OVATION Voltage SIR EI + GC Autospec-UltimaE Parad
Sample #8 Text: 1072-2 xl/2 ALS tt8
457.7377 S:8 F:5 SMO(1,3) BSUB ( 128 , 15, -3 . 0) PKD(3 , 3 , 3 , 0 . 10%, 2616 . 0 , 1 . 00%, F, F)
lOOi A3 . 50E5
50_
OJ
459.
loos
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469.
100%
so:
o:
471.
1008
so:
o:
454.
100%
so:
IV
39:12 39:24 39:36 39:48 40:00 40:12 40:24 40:36 40:48 41:
7348 S:8 F:5 SMO{1,3) BSUB (128, 15, -3 . 0) PKD(3 , 3 , 3 , 0 . 10%, 932 . 0 , 1 . 00%,F,F)
A3 -72E5
J\_
39:12 39:24 39:36 39:48 40:00 40:12 40:24 40:36 40:48 41:
7780 S:8 F:5 SMO{1,3) BSUB(128, 15 , -3 . 0) PKD(3 , 3 , 3 , 0 . 10%, 1556 . 0 , 1 . 00%, F, F)
Al . 62E8
J\_
' — i — i — i — r— i — r— i — i — i — I — i — i — i — i — i — r ' -i — i i i i i | i i i i *i | i IIP I ] ^"1 1 1 1 | > • • i • | 	 | • • ' • '
39:12 39:24 39:36 39:48 40:00 40:12 40:24 40:36 40:48 41:
7750 S:8 F:5 SMO(1,3) BSUB(128 , 15 , -3 . 0) PKD(3 , 3 , 3 , 0 . 10% , 2308 . 0, 1 . 00%, F, F)
Al .82 E 8
f\_
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39:12 39:24 39:36 39:48 40:00 40:12 40:24 40:36 40:48 41:
9728 S:8 F:5 SMO(1,3) PKD(3 , 3 , 3 , 100 . 00%, 0 . 0, 1 . 00%, F, F)
39:12 39JL54 40:07 40:18 40:34 40^47
r
39:12 39:24 39:36 39:48 40:00 40:12 40:24 40:36 40:48 41:
igm
8.8E4
.4.4E4
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9.2E4
.4 . 6E4
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3.6E7
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4 . 1E7
12 . OE7
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1.2E8
_6.0E7
O.OEO
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O
00

-------
File: A17JUL98B Acq: 17-JUL-1998 22:01
Sample #8 Text: 1072-2 xl/2 ALS #8
303.9016 S:8 SMO(1,3) BSUB (128, 15, -3 . 0)
1008
50_
0
A1.38E6
A
A5.41E5 A4.44E5
A A2A1E5A /Lrr
24 loo"1 ^S^OO"
305.8987 S:8 SMO(1,3) BSUB(128, 15, -3 . 0)
1001
50J
0;
A1.77E6
A
A7'26E5 A5.80E5 A ^
A "A3E5A /bf
24100 25100
315.9419 S:8 SMO(1,3) BSUB(128, 15, -3 . 0)
IOCS
50:
oj



	 24 loo' ' ' ' 25 100
317.9389 S:8 SMO(1,3) BSUB(128, 15, -3 . 0)
1004
50,
o:



24100 25100
375.8364 S:8 SMO(1,3) BSUB(128, 15, -3 .0)
1004
-
5°1

24:32,,.. ,._
23:13 23:45 h A £4:52 25:
\/T\A,_nA\ r-^ A / Ar^A. /VWN

24:00 25:00
316.9824 S:8 SMO(1,3) PKD(3, 3, 3, 100 .00%,
100% 23:18 23:59 24:5025:10
sol
1 o:


—• i i i i i i i i i i i i i i
24:00 25:00
:31 Exp: EXP_M23_DB5_OVATION Voltage SIR EI+ GC Autospec-UltimaE Paradigm

PKD(3,3,3,0.10%


,2160.0,1.00%,F,F)
2.7E5
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c A9.46E5
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26 loo'
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26 loo'
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A2.15E8
A
A
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4.3E7
12.2E7
O.OEO
27 loo ' 28 100 ' 29 100 	 30:00 Time
,6232.0,1.00%,F,F)
A2.73E8
A
A
A
5.5E7
_2 . 8E7
_O.OEO
27 100 28 100 29 1 00 30 I 00 Time
PKD(3,3,3,100.00%,1892.0,1.00%,F,F)


28:27 ^S.SES
27. -57 A /
25-50 26n:47 27-37 A. / \ |\ 29:16 29 = 46
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26:00

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27:00 28:00 29:00 30:00 Time

26:3927:02 27:29 28:13 28:5029:1329:36 7 OF.7



.3 . 5E7
-O.OEO
27:00 28:00 29:00 30:00 Time

-------
  File:  A17JUL98BAcq:  17-JUL-1998 22:01:31Exp:  EXP_M23_DB5_OVATION Voltage  SIR EI+GC  Autospec-UltimaE  Paradigm
  Sample #8   Text:  1072-2 xl/2  ALS #8
  339.8597 S:8  F:2  SMO(1,3)  BSUB(128,15,-3.0)  PKD(3,3,3,0.10%,1892.0,1.00%,F,F)
  100%.                                       A1.26E6
   50J
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               T
                                    T
                                          T
                                                                                                                  4.0E5

                                                                                                                 _2.0E5
                                                           A2J06E5
                                                                       A1.07E5  A1.40E5
                                                       T
                                                             T
       30:12  30:24  30:36  30i48  3llOO  3l!l2  3ll24  3l!36  3lUs  32:00  32!i2 ' 32124  32!36 ' 32:48 ' 33l6d ' 33112    Time
 341.8568  S:8 F:2 SMO(1,3) BSUB(128,15,-3.0) PKD(3,3,3,0.10%,2008.0,1.00%,F,F)
 100%                                        A8.QOE5                                                               2.6E5
A
A1.31E5 / AC 70F4 A1.50E5 A1.08E5
— -*'*^"'-"^. ^f 	 / /^J^M-Ti** y-^^ ^*-S~\^ ^ 	 *^^/~\^ J/*\_y/*sS.
T n • 1 O o n • *j ^ o n . ? £ "3n.^o o 1 . A n oi.ii -s 1 . -i .* ** t . t /? -» 1 >i r» -» ^ « /\ -i »•* i *•» -» ^ ^ * -t*^1-*^- -* ^ ' . « —-*'«« — — , ' - —
L1.3E5

10.0EO
                                  31:00  31:12  31:24  31:36  31:48  32:00   32:12  32:24  32:36  32:48  33:00  33:12     Time
 351.9000 S:8 F:2 SMO(1,3) BSUB(128,15,-3.0) PKD(3,3,3,0.10%,2216.0,1.00%,F,F)
 100%                                                            A2.78E8        A2.57E8                            9.6E7
 50J

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        T
               T
                      T
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                                  T
                                                                                                                  _4 . 8E7
                     ,       ,       ,       | i i i I I |	I i i  i i i I i i 1 I  I I I I I I I  I i I i I ri I  i TI I I i	i i i  i i i i	iii
     30:12  30:24  30:36  30:48  31:00  31:12  31:24  31:36   31:48  32lOO  32:12  32:24  32:36  32:48   33:00  33:12    Time
353.8970 S:8 F:2 SMO(1,3) BSUB(128,15,-3.0) PKD(3,3,3,0.10%,1892.0,1.00%,F,F)
100%.                                                            A1.78E8        A1.64E8                            6.2E7
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                     ,       .       i i i i i i i  i i i i i i i i  i i i i i i i  i i i i i r i i  ir i i i i i  i i i i 1 i i  r*i i i i i i  i i i i i i i  i i i i i i i  i i i i
     30:12  30:24  30:36  30:48  31:00  31:12  31:24   31:36   31:48  32:00  32^12  32:24  32:36   32i48   33:00  33:12    Time
 09.7974 S:8 F:2 SMO(1,3) BSUB(128,15,-3.0) PKD(3,3,3,100.00%,3968.0,1.00%,F,F)
100%.                                                       31; 48                                                 2.0E4


                                                                                                                 Ll.OE4
             30124  30!36 ' SoUs' ' 3l!66 ' 3i!l2 ' 3i!24 ' 3l!36 ' 3i!48 ' 32!6d ' 32112 ' 32124 ' 32136 ' 32U8  33:66 ' 33ll2    Time
  66.9792 S:8 F:2 SMO{1,3) PKD(3,3,3,100.00%, 0.0,1.00%,F, F)
  00%.         30:26           30:54 31:05	    3U29^   31;4731;56	32:29   32:42  32:54  33:06    7. 8E7
  50J
                                                                                                                  L3.9E7
        I	| ' ' i  ' i i i ' ' '  ' i ' ' i ' i  i ' i ' i ' i i  i ' ' ' i i i i  i i i t i i i i  i i i i i i i  i i i i i i i  i i i i i i i  i i i i i i i  i i i i i i i  i i i i i i i  •! |i " • UEU
      30:12  30:24   30:36  30:48  31:00  31:12  31:24   31:36  31:48  32100  32:12  32:24   32:36   32:48  33:00  33:12    Time
O
09
CO

-------
File: A17JUL98B Acq: 17-JUL-1998
Sample #8 Text: 1072-2 xl/2 ALS
373.8207 S:8 F:3 SMO(1,3) BSUB (128
100%, Al.glES
-
50 "
-
.
OJ
A A
/ \ /\
MM ,, 7ip
/ W M.38E4 A3v71E
/ *y xLZ-'--^ ^~~^^_ _/ \^
33:24 33136 33Us 34:
375.8178 S:8 F:3 SMO(1,3) BSUB (128
100%, A1.JOE5
•
50j
-
I




'/~^
- — - ^/~N^ / \^
33124 33136 33Us 34!
383.8639 S:8 F:3 BSUB(128, 15, -3 . 0)
100%
50 j
o"



33J24 33136 33Us 34!
385.8610 S:8 F:3 BSUB(128, 15, -3 .0)
100%
50 j
o:



" ' i i — 1 — i — i i i i 1 — i i i — i — i — | — P — i — i — i — i — r
33:24 33:36 33:48 34:
445.7555 S:8 F:3 SMO{1,3) BSUB(128
100%
50 1
Q


_/\ r^^P^l^^ 3/^
33:24 33:36 33:48 34:
22:01:31 Exp: EXP M23 DBS
#8
,15, -3.0) PKD(3,5,2,0.10%,

A1.51E5
f\
4 / V\ A6


00 34! 12 34! 24 34
,15, -3.0) PKD(3,5,2,0.10%,

A1.16E5
A A
/ \ A A4
/ V \ s~
J 1 \ — ^.^^ 	 "• — jr
00 34:12 34:24 34:
PKD (3, 5, 2, 0.10%, 46092. 0,1
A1.28E8
A A
/ V V_
00 34!l2 34!24 34l
PKD (3, 5 ,2, 0.10%, 49356. 0,1
A2.46E8
A A
/ V V
00 34:12 34:24 34:
_OVATION Voltage SIR EI+ GC Autospec-UltimaE Paradigm

3452. 0,1. 00%, F,F)
,_6.5E4


.OOE4
/~\ A1.65E4

:
i.3.3E4



36 34!48 35!oO 35:12 35:24 35:36 35:48 Time
2604. 0,1. 00%, F,F)
,_5.3E4


. 11E4
X\ A4.85E4

:
L2.7E4



36 34:48 35:00 35:12 35:24 35:36 35:48 Time
.00%,F,F)



5 . 6E7
.2.8E7
O.OEO
36 34!48 35:00 35:12 35:24 3s!36 35:48 Time
.00%,F,F)



1.1E8
L5.4E7
O.OEO
36 34:48 35:00 35:12 35:24 35:36 35 48 Time
,15, -3.0) PKD(3,3,3,100.00%,1500.0,1.00%,F,F)

34:13
^-~^-^A^-^-\l^^-^^~
— i i i i i | i ^ i i i | i i i i i p
00 34:12 34:24 34:
34:46 35:00
A A

X/ V_^ VXX__^A — , — ; •'-jj^B-llli0 /
_1.3E4
_6.3E3
O.OEO
36' 34!48 35!00 3s!l2 35:24 35I36 35:48 Time
380.9760 S:8 F:3 SMO(1,3) PKD(3, 3,3, 100.00%, 0.0, 1 .00%, F,F)
100% 33:28 33:37 34:02 34:15 34:31
50 1
0'
^

"-1— i — i — | — i — i — i — i — i — | — i — i — i — i — i — | — i — i — i — i — i — |-
>> 33 24 33 36 33:48 34:


00 34:12 34:24 34:
34:44 34^56 35:17 35j-29 35:37 1.8E8


_8.8E7
O.OEO
36' ' '34 Us' '35!oO 35!l2 3s!24 35!36 3s!48 Time
O
£

-------
 File: A17JUL98BAcq:  17-JUL-1998  22:01:31Exp: EXP_M23_DB5_OVATION Voltage SIR EI+GC Autospec-UltimaEParadigm
 Sample  #8  Text: 1072-2  xl/2  ALS  #8
 407.7818 S:8  F:4 SMO(1,3)  BSUB(128,15,-3.0) PKD(3,3,3,0.10%,2492.0,1.00%,F,F)
 100%               A2.46E5
   50J

    OJ
                                                                                                                 7.3E4

                                                                                                                 13.7E4
                              A4.48E4
                                                          A3.77E4
                                                                                                                LO.OEO
        36:00  36:12  36:24  36:36  36:48  37:00  37:12  37:24  37:36  37:48   38:00  38:12
  409.7788  S:8  F:4  SMO(1,3)  BSUB(128,15,-3.0) PKD(3,3,3,0.10%,1016.0,1.00%,F,F)
  100%               A2.14E5
   50J
    OJ
                                                                                         38:24  38:36  38:48  39:00  Time

                                                                                                                  6.8E4

                                                                                                                 L3.4E4
                               A4.10E4
                                                           A3.03E4
                                                                                                                  O.OEO
       36:00  36:12  36:24   36:36  36:48  37:00  37:12  37:24  37:36  37:48  38:00  38:12
417.8253 S:8 F:4 SMO(1,3) BSUB(128,15,-3.0)  PKD(3,3,3,0.10%,11428.0,1.00%, F, F)
100%              A7.16E7
                                                          A5.40E7
    OJ
        36lOO  36ll2  36124  3e!36  36:48  37:00  37:12  37:24  37:36  37:48   38:00  38:12
 419.8220 S:8 F:4 SMO(1,3) BSUB(128,15,-3.0) PKD(3,3,3,0.10%,25996.0,1.00%,F,F)
 100%               A1.60E8
                                                                                          38:24  38:36  38:48  39:00  Time
                                                                                                                 2 . 1E7

                                                                                                                 Ll.lE?

                                                                                                                 LO.OEO
   50J
    OJ
                                                           A1.21E8
                                                                                         38:24  38:36  38:48  39:00  Time
                                                                                                                 4. 8E7

                                                                                                                 L2.4E7
        36!6d ' 36112  36124 ' 36!36 ' 36:48 ' 37166 ' 37:12  37:24  37:36  37148   38:QO  38:12
 479.7165 S:8 F:4 SMO(1,3)  BSUB(128,15,-3.0) PKD(3,3,3,100.00%,4524.0,1.00%,F,F)
 100%                                            37;11
       35:58       36:19
   50J
                                                                                         38124 ' 38:36 ' 38:48 '  39:00  Time
                         1.4E4

                        _6.9E3

                          .OEO
38i24  38136  38148   39:00  Time

19J8:29          38^53   1.1E8

                        _5.7E7
        36:00  36:12  36:24  36:36  36:48  37:00  37:12  37:24  37:36  37:48   38:00  38:12
430.9728 S:8 F:4 SMO(1,3) PKD(3, 3 , 3, 100 . 00%, 0 . 0, 1 . 00%,F,F)
100%. _ 36:08    36^2336^22 _ 36:55 _ 37:32
  50^
   OJ
                                                                      37:49
                                                                                      38
        i i i  i i i i i i	i	i i i i  i i i i i i i i  i	i  i i i i i i i i  i i i i	i	i i i i i i  i i i
        36:00  36:12  36:24  36:36   36:48  37:00  37:12  37:24   37:36   37148  38:00  38:12
                                                                                         38:24 ' 38136 ' 38:48 ' 39:00  Time
o
00

-------
File: A17JUL98B Acq: 17-JUL-1998 22:01:31 Exp:
Sample #8 Text: 1072-2 xl/2 ALS #8
441.7427 S:8 F:5 SMO(1,3) BSUB(128 , 15, -3 . 0) PKD(3
100%
50J
n' i T-
39ll2 ' ' ' 39!24 ' ' ' 39136 ' ' ' 39148
443.7398 S:8 F:5 SMO(1,3) BSUB(128 , 15, -3 . 0) PKD(3
100%
50_
39:12 39:24 39:36 39:48
469.7780 S:8 F:5 SMO(1,3) BSUB(128 , 15, -3 . 0) PKD(3
100%
50:
o:
EXP_M23_DB5_OVATION Voltage SIR EI+ GC Autospec-ultimaE Parad
, 3, 3, 0.10%, 1532. 0,1. 00%, F,F)
A2.00E5
40:00 4o!l2 40:24 40:36 40:48 41
, 3, 3, 0.10%, 2080. 0,1. 00%, F,F)
A2.23E5
40:00 40:12 40:24 40:36 40:48 41:
, 3, 3, 0.10%, 1556. 0,1. 00%, F,F)
Al . 62E8
39ll2 39124 39i36 39U8 4o!ob 4o!l2 40:24 40:36 4ol48 4l!
471.7750 S:8 F:5 SMO(1,3) BSUB (128, 15, -3 . 0) PKD(3 , 3 , 3 , 0 . 10%, 2308 . 0 , 1 . 00%, F,F)
100% A1.82E8
A.
o- J ^ —
39!l2 39124 39136 39U8
513.6775 S:8 F:5 SMO(1,3) BSUB (128, 15, -3 . 0) PKD(3,
100%
50:
39-2839:34 39
39:11 39:19 _^Af /^N, 3 9 : 4 0 39^
40:00 40:12 40:24 40:36 4oUs 41
3, 3, 100. 00%, 72. 0,1. 00%, F,F)
40:02
igm
5.4E4
L2.7E4
' 0 . OEO
00 Time
5.4E4
.2 . 7E4
00 Time
3 . 6E7
_1.8E7
.O.OEO
00 Time
4.1E7
.2 . OE7
.O.OEO
00 Time
_6.3E3
_3.2E3
o. ORO
39:12 39:24 39:36 39:48 40:00 40:12 40:24 40:36 40:48 41 00 Time
454.9728 S:8 F:5 SMO(1,3) PKD(3 , 3 , 3 , 100 . 00%, 0 . 0, 1 . 00%,F,F)
100% 39:12 39i54 40:07 40:22 40:34 40:47 1 5RB
50:
^ 39ll2 39l24 39l36 ' s'gUs

.6.0E7
O.OEO
40:00 40:12 40:24 40:36 40:48 41:00 Time

-------
       Ol
              n    22-JUL-1998
                                              Page  1
                Filename
                  Sample
                Acquired
               Processed
               Sample  ID
               Cal Table
           Results Table
                Comments
        Typ
        Unk
        ES/RT
        Total
        DPE
        LMC
                                                                                                                                                     Page 12
        a21jul98f
        7
        21-JUL-98   23:49:03
        22-JUL-98   08:32:46
        1072-2 xl/2
        07feb-m23conf
        M8290-23-072198F
              Name;
      2,3,7,8-TCDF;
  13C-2,3,7,8-TCDF;
      Tetra Furans;
            HxCDPE;
QC CHK ION (Tetra) ,-
   Resp;
.02e+06;
. 90e+08;
,12e+07;
   Ion 1;
2.48e+05;
3.47e+08;
8.41e+05;
   Ion 2;
7.67e+05;
4.43e+08;
1.10e+06;
           RT;
        27:57;
0.78,-y; 27:55;
        18:13;
      ;NotFnd;
      ;NotFnd;
  RA; ?;
 . 32,- n;
0.77,-y;
   Cone;       DL;
  0.135;   0.0310;
193.556;
  2.825;   0.0310;
S/N1;?,-
  17; y ;
1687;y;
  42,-y,•
   *;n
DivO;n
S/N2;?
  21;y
1352,-y
  47,-y
mod?
  no
  no
  no
  no
  no
                                                                             27:57
                                                                             27:57
                                                                                                                         -; -;   no
O
09

-------
OPUSquan   22-JUL-1998
                   Page  1
 Ent: 3  Name: Tetra Furans
                                                                    Page 1 of 1

                                   F:l  Mass:  303.902  305.899 Mod? no   #Hom:29
 Run: 12 File: a21ju!98f    S:7  Acq:21-JUL-98 23:49:03 Proc:22-JUL-98 08:32:46
 Tables: Run: a21ju!98b  Analyte: m23_conf    Cal:  07feb-m23»Results:  M8290-23*
 Version: V3.5 17-APR-1997 11:14:34  Sample text:  1072-2 xl/2
   Amount: 2.82
     Cone: 2.82
   Tox #1: -
Name
of which 0.14
of which 0.14
     Tox #2:  -

#     RT Respnse
named and 2.69
named and 2.69
      Tox #3:  -
                                        RA
                   1  18:13 1.9e+06  0.77 y
                            1.9e+06

                   2  19:05 1.4e+04  2.59 n
                            1.4e+04

                   3  19:53 2.9e+06  0.87 y
                            2.96+06

                   4  20:23 7.8e+05  1.08 n
                            7.86+05

                   5  20:40 4.0e+05  0.26 n
                            4.0e+05

                   6  20:42 5.3e+05  0.66 y
                            5.36+05

                   7  21:14 7.1e+05  0.78 y
                            7.1e+05

                   8  21:33 5.5e+05  1.86 n
                            5.5e+05
                       21:50  4.26+04
                             4.26+04
                                      1.15 n
                    10  21:53  3.06+04   0.50 n
                             3.06+04

                    11  22:00  2.36+05   0.40 n
                             2.36+05
                    12  22:01  2.46+05
                             2.4e+05
                                      0.44  n
                    13  22:12  1.8e+06  0.80  y
                             1.8e+06

                    14  22:37  1.5e+06  0.81  y
                             1.5e+06

                    15  23:19  1.2e+06  0.48  n
                             1.26+06

                    16  23:30  7.0e+05  0.27  n
                             7.0e+05

                    17  24:21  1.9e+06  0.73  y
                             1.9e+06

                    18  25:03  1.8e+06  0.79  y
                             l.Se+06

                    19  26:36  4.9e+05  1.03  n
                             4.9e+05
          Cone

           0.26
               E
               ]
           0.00
               9
               3
           0.39
               1
               3
           0.10
               t,

           0.05
               £
               •3
           0.07


           0.10
               i
               4
           0.07
unnamed
unnamed
Area  Height    S/N  Mod?
                                8.4e+05 1.6e+05 4.2e+01 y  n
                                l.le+06 2.1e+05 4.7e+01 y  n

                                9.8e+03 5.6e+03 1.5e+00 n  n
                                3.8e+03 3.0e+03 6.6e-01 n  n
                               J
                                1.4e+06 2.56+05 6.5e+01 y  n
                                1.6e+06 2.9e+05 6.2e+01 y  n
                               3
                                4.0e+05 8.5e+04 2.2e+01 y  n
                                3.8e+05 9.16+04 2.0e+01 y  n

                                8.4e+04 5.26+04 1.36+01 y  n
                                3.2e+05 6.6e+04 1.4e+01 y  n
                               7
                                2.1e+05 5.5e+04 1.4e+01 y  n
                                3.2e+05 6.6e+04 1.4e+01 y  n
                                3.1e+05 5.5e+04 1.4e+01 y  n
                                4.06+05 6.7e+04 1.56+01 y  n
                                               0.01
                                               0.00
                            0.03
                                                0.03
               3.6e+05 5.5e+04 1.4e+01 y  n
               1.9e+05 6.0e+04 1.3e+01 y  n
               L
               2.36+04 1.2e+04 3.2e+00 y  n
               2.0e+04 l.Oe+04 2.3e+00 n  n
               D
               9.9e+03 7.9e+03 2.0e+00 n  n
               2.0e+04 l.Oe+04 2.3e+00 n  n
               3
               6.6e+04 2.6e+04 6.8e+00 y  n
               1.76+05 4.26+04 9.26+00 y  n
                                                0.25
                            0.20
                7.3e+04  2.8e+04  7.4e+00 y   n
                1.7e+05  4.2e+04  9.2e+00 y   n

                8.26+05  1.36+05  3.3e+01 y   n
                l.Oe+06  1.6e+05  3.4e+01 y   n
               D
                6.6e+05  l.Oe+05  2.7e+01 y   n
                8.1e+05  1.3e+05  2.7e+01 y   n
                             0.16
                             0.09
                             0.26
                             0.24
                             0.06
                3.9e+05  6.8e+04  1.8e+01 y  n
                8.1e+05  l.le+05  2.5e+01 y  n
               3
                1.5e+05  3.1e+04  8.0e+00 y  n
                5.5e+05  7.8e+04  1.7e+01 y  n
               5
                8.1e+05  1.2e+05  3.0e+01 y  n
                l.le+06  1.5e+05  3.3e+01 y  n
               4
                7.8e+05  9.9e+04  2.6e+01 y  n
                9.9e+05  1.2e+05  2.7e+01 y  n
               6
                2.5e+05  3.1e+04  8.0e+00 y  n
                2.4e+05  3.5e+04  7.6e+00 y  n

-------
OPUSguan   22-JUL-1998
                                      Page 2
                                                   5.
                                                   8.
                                                  4
                                                   2.
                                                   7.
                   20 27:36 6.2e+04  5.93 n    0.01
                            6.26+04

2,3,7,8-TCDF       21 27:57 l.Oe+06  0.32 n    0.14
                            l.Oe+06

                   22 27:59 l.le+06  0.42 n    0.15
                            l.le+06

                   23 28:34 2.4e+05  0.27 n    0.03
                            2.4e+05

                   24 29:39 5.2e+05  0.56 n    0.07
                            5.2e+05

                   25 29:42 3.1e+05  0.82 y    0.04
                            3.1e+05
                   26 31:27 2.7e+04  1.23 n    0.00
                            2.7e+04

                   27 31:49 3.4e+04  2.13 n    0.00
                            3.4e+04

                   28 31:53 5.3e+04  2.16 n    0.01
                            5.3e+04

                   29 31:56 5.4e+04  0.99 n    0.01
                            5.4e+04
 3e+04 2.0e+04 5.2e+00 y  n
 9e+03 7.2e+03 1.6e+00 n  n

 5e+05 6.7e+04 1.7e+01 y  n
.7e+05 9.7e+04 2.1e+01 y  n

,2e+05 7.2e+04 l,9e+01 y  n
.7e+05 9.7e+04 2.1e+01 y  n

,2e+04 1.4e+04 3.7e+00 y  n
.9e+05 2.9e+04 6.4e+00 y  n

.96+05 3.7e+04 9.56+00 y  n
.4e+05 5.26+04 l.le+01 y  n

.4e+05 3.3e+04 8.7e+00 y  n
.7e+05 4.4e+04 9.76+00 y  n

.5e+04 9.06+03 2.3e+00 n  n
.2e+04 4.7e+03 l.Oe+00 n  n

.3e+04 1.2e+04 3.0e+00 n  n
.le+04 7.7e+03 1.7e+00 n  n

.6e+04 1.4e+04 3.6e+00 y  n
.7e+04 1.le+04 2.46+00 n  n

.7e+04 1.26+04 3.26+00 y  n
.7e+04 1.2e+04 2.6e+00 n  n

-------
File: A21JUL98F Acq: 21-JUL-1998 23:49:03 Exp: M23_DB225 Voltage SI
Sample #7 Text: 1072-2 xl/2 ALS #7
303.9016 S:7 SMO(1,3) BSUB(128, 15, -3 . 0) PKD(3 , 3 , 3 , 0 . 10%, 3852 . 0 , 1 . 00%,
100% A1.36E6
; A8.41E5 fl
50j II A7.87E5 A8.13E5
16:00 18:00 20:00 22:00 24:00 26:00
305.8987 S:7 SMO(1,3) BSUB(128 , 15, -3 . 0) PKD(3 , 3 , 3 , 0 . 10%, 4576 . 0, 1 . 00%,
100%, A1.56E6
A1.10E6 |
5Q: ft A1.02E6 A1.11E6
" . A4.00E5 A AA5*53E5/1 Wk.26E5
n: II ^xJl (1 A J\J\ jj\ A J\ IL fl A r A
ielob ' 18:00 ' ' 2olob 22lob 24:00 26:00
315.9419 S:7 SMO{1,3) BSUB(128 , 15, -3 . 0) PKD(3 , 3 , 3 , 0 . 10%, 22304 . 0 , 1 . 00%
100%
50 1
16:00 18:00 20:00 22:00 24:00 26:00
317.9389 S:7 SMO(1,3) BSUB(128, 15, -3 .0) PKD(3 , 3 , 3 , 0 . 10%, 35548 . 0, 1 . 00%
100%
50J
16:00 ISIOO 20:00 22:00 24 00 26:00
375.8364 S:7 SMO{1,3) BSUB(128, 15, -3 . 0) PKD(3 , 3 , 3 , 100 . 00%, 10348 . 0 , 1 . 0
100%, 19:27
A
15:37 17:39 JT \ 20:57 22:46 24:0124:58 26:11
16lOO 18:00 20:00 22:00 24:00 26:00
316.9824 S:7 SMO(1,3) PKD(3, 3 , 3 , 100 . 00%, 0 .0, 1 . 00%,F,F)
100% 16:41 181.21 19jJS. 2UM2ii58 ..2.3: 12 24:58 26; 2.2
50 j
o •
ielob ' ' ' islob ' ' ' 2o!ob ' ' 22lob 24 ob 2'elob
R EI+ GC Autospec-UltimaE Paradigm
F,F)
5 Ajj^ ^AE5 A3J^E4
28 00 30:00 ' 32lob 34lob
F,F)
A7 . 67E5
A A3.36E5 Ag
28-00 3olob 32lob 34lob
,F,F)
A3.47E8
1
28-00 30:00 32:00 34:00
,F,F)
A4.43E8
28 00 30:00 32:00 34:00
0%,F,F)
27:35 28:48 JiPj.34 32:2933:28 34:38
28 00 3o!ob 32:00 34lob
28:09 ._29:2430:2131:18 32i2033jl8

' 28 00 ' 3olob 32lob 34lob
2.5E5
.1.2E5
.O.OEO
Time
Ll.4E5
.O.OEO
Time
3.8E7
.1 . 9E7
-O.OEO
Time
4 . 8E7
.2 . 4E7
_0 . OEO
Time
_3.0E5
_1 . 5E5
O.OEO
Time
_6.3E7
_3.2E7
-O.OEO
Time

-------
                                                                 Paradigm Analytical Labs
Analytical Data Summary Sheet
•• •-"*S55l>'!^|J's^te^-c'""" ' '• ••*
- ;'^#:?i®^^:'; '"Matrix: '• •-
Weight/ Votame:
, Moisture / Lipids:
'0- ••'/v'BJesa*^:^' . ;•
EndConCal:
Initial Cal: :JL
Air
4 .. - •
a!7j|ijBJH>-9
Ai^TJt^lflOlk 't
~ ^ft-' I jf TttEr •OD*' i
: M-JyOSgb-li
' ^m8290-23-C
                                                                              r
                                                                                    091
                                      1/2

-------
                                                                         Paradigm Analytical Labs
Extraction Standards
 C12-2,3,7,8-TCDD
*Ci2-l,2,3,6,7,S-n\CDD
3C12-U,3,4,6,7,8-HpCDD
 3C12-OCDD
 'C,r2,3,7,8-TCDF
 JC12-l,2,3,7,8-PeCDF
 JCi2-l,2,3,6,7,8-HxCDF
 3C12-l,2,3,4,6,7,8-HpCDF
Sampling Standards
 13C12-2,3,4,7,8-PeCDF
 °C,rlA3,4,7,8-aBCDD
 13C12-l,2,3,4,7,8-HxCDF
 13Cl2-l,2,3,4,7,8,9-HpCDF
 Injection Standards
 13C12-1,2,3,4-TCDD
 13C12-l,2,3,7,8,9-HxCDD
                               Analytical Data Summary Sheet
                                                       83.2
                                                       82.3
                                                       77.6
                                                       80.9
                                                       74.9
                                                       86.7
                                                       69.3
                                                       B?'
                                                       93.4
                                                       106.2
                                                       84.9
                                                       77.3
                                                                28:26
                                                                 34:45
                                                                 37:09
                                                                 40:01
                                                                 31:56
                                                                 34:14
                                                                 36:21
                                                              t  28:27
                                                                 32:24
                                                              ? 34^1,
                                                                 34:10
                                                                 37:31

                                                                 28:09
                                                                 34:58
0.78

1.26
^•^flji-
*»ii!5»
0.88
1.54
0.52
0.44
 1.56
 1.26
 0.51
 0.44

 0.79
 1.25
Client Information

Project Name:
Sample ID:

Laboratory Information

Project 0>:
 Collection Date:
 Receipt Date ,
 Extraction E>a4:
 Reviewed bvi  7. »•
                            Texas Lime Kiln
                            M23-FBr3
                                                    .Sample Information

                                                    Matqx;
                                                    W«^fVb1ame:
                                                    Moistajre/Lipids:
                                                                              Air
                                                                               1
                                                                          al7ju!98b-15
                                                                           m8290-23-071798
                                                                           "^r~ -*-"»-.
                                                                     Date
                                                                                              09Z
                                            2/2

-------
o
C£
CO
OPUSc,- ... 20-JUL-1998 Page
Filename al7ju!98b
Sample 9
Acquired 17-JUL-98 22:46:36
Processed 20-JUL-98 09:05:29
Sample ID 1072-3 xl/2
Cal Table m8290-23-071798
Results Table M8290-23-071798B
Comments
Typ Name; Resp;
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
ES/RT
ES
ES
ES
ES
ES/RT
ES
ES
ES
JS
JS
CS
CS
CS
CS
CS
ss
ss
ss
ss
ss
2,3,7,8-TCDD; 2.79e+05;
1,2,3,7,8-PeCDD; 5.59e+04;
1,2,3,4,7,8-HxCDD; 3.92e+04;
1,2,3, 6,7, 8-HxCDD; 6.61e+04;
1,2,3,7,8,9-HxCDD; 6.76e+04;
1,2,3,4,6,7,8-HpCDD; 2.15e+05;
OCDD; 5.35e+05;
2,3,7,8-TCDF; 1.70e+05;
1,2,3,7,8-PeCDF; *;
2,3,4,7,8-PeCDF; * ;
1,2,3,4,7,8-HxCDF; 9.48e+04;
1,2,3,6,7,8-HxCDF; 7.29e+04;
2,3,4,6,7,8-HxCDF; 5.53e+04;
1,2,3,7,8,9-HxCDF; * ;
1,2,3,4,6,7,8-HpCDF; 3.15e+05;
1,2,3,4,7,8,9-HpCDF; *;
OCDF; 1.96e+05;
13C-2,3,7,8-TCDD; 3.67e+08;
13C-l,2,3,7,8-PeCDD; 2.81e+08;
13C-l,2,3,6,7,8-HxCDD; 2.79e+08;
13C-l,2,3,4,6,7,8-HpCDD; 2.24e+08;
13C-OCDD; 3.14e+08;
13C-2,3,7,8-TCDF; 4.48e+08;
13C-l,2,3,7,8-PeCDF; 3.61e+08;
13C-l,2,3,6,7,8-HxCDF; 3.40e+08;
13C-l,2,3,4,6,7,8-HpCDF; 1.65e+08;
13C-1,2,3,4-TCDD; 4.02e+08;
130-1,2,3,7,8, 9-HxCDD; 3.16e+08;
37C1 -2,3,7,8-TCDD; 3.12e+08;
13C-2,3,4,7,8-PeCDF; 3.30e+08;
13C-1,2, 3,4,7,8-HxCDD; 2 .OOe+08;
13C-l,2,3,4,7,8-HxCDF; 2.27e+08;
13C-l,2,3,4,7,8,9-HpCDF; 9.99e+07;
37Cl-2,3,7,8-TCDD; 3.12e+08;
13C-2,3,4,7,8-PeCDF; 3.30e+08;
13C-1 , 2,3,4,7, 8-HxCDD; 2 . OOe+08 ;
13C-1 , 2,3,4,7, 8-HxCDF ; 2 . 27e+08 ;
13C-l,2,3,4,7,8,9-HpCDF; 9.99e+07;









4
3
1
3
3
1
2
7


5
4
3

1

8
1
1
1
1
1
1
2
1
5
1
1
3
2
1
7
3
3
2
1
7
3
1








Ion 1;
.OOe+04;
.706+04;
.986+04;
.41e+04;
.07e+04;
.03e+05;
.50e+05;
.31e+04;
* .
* .
.42e+04;
.69e+04;
.43e+04;
* .
.68e+05;
* -
. 16e+04;
. 60e+08;
.72e+08;
.56e+08;
. 14e+08;
.47e+08;
.97e+08;
. 19e+08;
. 17e+08;
. 06e+07;
. 78e+08;
. 76e+08;
. 12e+08;
. Ole+08;
.lle+08-
. 70e+07;
. 07e+07;
. 12e+08;
.Ole+08;
.lle+08;
.70e+07;
07e+07;









Ion 2 ;
2.396+05;
1.896+04;
1.94e+04;
3.20e+04;
3.696+04;
1.136+05;
2.866+05;
9.65e+04;
* .
* .
4.06e+04;
2.61e+04;
2.10e+04;
* ,
1.47e+05;
* .
1.15e+05;
2.07e+08;
1.09e+08;
1.23e+08;
l.lOe+08;
1.67e+08;
2.51e+08;
1.42e+08;
2.23e+08;
1.15e+08;
2.24e+08;
1.41e+08;

1.29e+08;
8.87e+07;
l.SOe+08;
6.92e+07;

1.296+08;
8.876+07;
1.50e+08;
6.926+07;










0
1
1
1
0
0
0
0


1
1
1

1

0
0
1
1
1
0
0
1
0
0
0
1

1
1
0
0

1
1
0
0









RA;?; RT;
.17;n; 28:27;
.96;n; 32:37;
.02;n; 34:42;
.07;y; 34:46;
.83;n; 34:58;
.91;y; 37:11;
.87;y; 40:02;
.76;y; 27:27;
*;n;NotFnd;
*;n;NotFnd;
.34;y; 34:10;
.80;n; 34:15;
.64;n; 34:37;
*;n;NotFnd;
.14;y; 36:22;
*;n;NotFnd;
.71;n; 40:10;
.78;y; 28:26;
.57;y; 32:37;
.26;y; 34:45;
.04,-y; 37:09;
.88;y; 40:01;
.79,-y; 27:25;
.54,-y; 31:56;
.52;y; 34:14;
.44;y; 36:21;
. 79 ;y; 28:09;
.25;y; 34:58;
-;-; 28:27;
. 56 ;y; 32:24;
?fi-y; 34:41;
. 51 ;y; 34:10;
. 44 ;y; 37:31;
-;-; 28:27;
. 56, -y; 32:24;
.26;y; 34:41;
.51;y; 34:10;
.44;y; 37:31;









Cone;
0.077;
0.018;
0.021;
0.028;
0.028;
0.107;
0.339;
0.040;
* .
* .
0.032;
0.020;
0.017;
* .
0.152;
* .
0.117;
83.138;
91.341;
82.304;
89.111;
155.238;
80.927;
74.916;
86.706;
69.318;
83.396;
79.761;
77.000;
69.960;
87.481;
74.154;
53.571;
92.670;
93.416;
106.152;
84.845;
77.312;









DL;
0.0140;
0.0099;
0.0159;
0.0126;
0.0125;
0.0120;
0.0384;
0.0152;
0.0108;
0.0104;
0.0093;
0.0074;
0.0086;
0.0099;
0.0170;
0.0205;
0.0218;
0.0410;
0.0294;
0.0330;
0.0279;
0.0097;
0.0229;
0.0228;
0.1600;
0.0527;
-;
-;
0.0173;
0.0233;
0.0489;
0.2053;
0.0674;
0.0206;
0.0178;
0.0517;
0.1971;
0.1216;









S/N1;?;
5;y;
4;y;
3;n;
4;y;
4;y;
27;y;
18;y;
7;y;
*;n;
*;n;
7;y;
5;y;
4;y;
*;n;
21;y;
*;n;
15;y;
4326;y;
16378;y;
7397;y;
5114;y;
26944; ;y;
8999, -y;
29712 ;y;
1677;y;
6700;y;
4773;y;
7294;y;
13431;y;
28255,-y;
5495;y;
1185, -y;
3566,-y;
13431 ;y;
28255;y;
5495;y;
1185 ;y;
3566 ; y;









S/N2;?
27, -y
6;y
3;y
5;y
6;y
27 ;y
59 ;y
7;y
*;n
*;n
8;y
6;y
5;y
*,-n
39;y
*;n
20;y
9103;y
16763;y
10813, -y
9817 ;y
30058,-y
12536;y
10475;y
2117;y
2552;y
9759;y
10671;y
"" / ~
9764;y
7970;y
1479, -y
1378;y
-; -
9764;y
7970;y
1479, -y
1378;y
mod?
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
                                                                                                                                         Page 14

-------
OPUSquan   20-JUL-1998
                                      Page  1
                                                                    Page  1  of  8

 Ent: 39 Name: Total Tetra-Furans  F:l  Mass:  303.902  305.899  Mod?  no   #Hom:8

 Run: 14 File: a!7ju!98b    S:9  Acg:17-JUL-98 22:46:36  Proc:20-JUL-98  09:05:29
 Tables: Run: a!7ju!98b  Analyte: m8290-23-»  Cal:  m8290-23-»Results: M8290-23*
 Version: V3.5 17-APR-1997 11:14:34  Sample text:  1072-3 xl/2
   Amount: 0.16
     Cone: 0.16
   Tox #1: -
Name
of which 0.04
of which 0.04
     Tox #2:  -

#     RT Respnse
named and 0.12
named and 0.12
      Tox #3: -
                                        RA
2,3,7,8-TCDF
1  23:38 S.le+04  0.46 n
         S.le+04

2  24:33 l.Oe+05  0.64 n
         l.Oe+05

3  24:51 8.2e+04  0.76 y
         8.2e+04

4  26:08 9.2e+04  1.03 n
         9.2e+04

5  26:26 6.3e+04  0.48 n
         6.3e+04

6  26:33 6.9e+04  0.48 n
         6.96+04

7  26:50 4.2e+04  0.71 y
         4.26+04

8  27:27 1.7e+05  0.76 y
         1.7e+05
          Cone

           0.01
               1

           0.02
               4
               (
           0.02
               •3
               4
           0.02
               4
               i.
           0.01

               t
           0.02

               t
           0.01
               1

           0.04
   unnamed
   unnamed
                                                      Area  Height
                                  S/N  Mod?
                                                   1.6e+04 4.1e+03  2.0e+00 n  n
                                                   3.5e+04 8.3e+03  3.5e+00 y  n

                                                    .0e+04 8.4e+03  4.2e+00 y  n
                                                    .3e+04 1.7e+04  7.0e+00 y  n

                                                   3.5e+04 8.7e+03  4.3e+00 y  n
                                                   4.7e+04 8.6e+03  3.6e+00 y  n

                                                    .7e+04 l.le+04  5.7e+00 y  n
                                                   4.5e+04 1.2e+04  5.1e+00 y  n
                                                  1
                                                   2.1e+04 4.4e+03  2.2e+00 n  n
                                                   4.3e+04 l.Oe+04  4.3e+00 y  n
                                                  I
                                                   2.2e+04 6.86+03  3.4e+00 y  n
                                                   4.7e+04 9.4e+03  3.9e+00 y  n
 1.7e+04  4.7e+03  2.4e+00 n  n
 2.5e+04  6.9e+03  2.9e+00 n  n
1
 7.3e+04  1.36+04  6.7e+00 y  n
 9.7e+04  1.6e+04  6.6e+00 y  n
                                                                    Page 2 of 8

  Ent:  40 Name: Total Tetra-Dioxins F:l  Mass: 319.897 321.894 Mod? no   #Hom:3

  Run:  14 File: al7ju!98b    S:9  Acq:17-JUL-98 22:46:36 Proc:20-JUL-98 09:05:29
  Tables: Run: a!7ju!98b  Analyte: m8290-23-»  Cal: m8290-23-»Results: M8290-23*
  Version: V3.5 17-APR-1997  11:14:34  Sample text: 1072-3 xl/2
    Amount:  0.12
      Cone:  0.12
    Tox #1:  -
 Name
 of which 0.08
 of which 0.08
     Tox #2: -

 #     RT Respnse
 named  and  0.04
 named  and  0.04
       Tox  #3: -
                                        RA
 2,3,7,8-TCDD
 1   25:15  l.le+05  0.79 y
          l.le+05

 2   25:40  4.8e+04  0.59 n
          4.8e+04

 3   28:27  2.8e+05  0.17 n
          2.8e+05
           Cone

            0.03
               L.
               (
            0.01
               1
               2
            0.08
    unnamed
    unnamed
                                                      Area  Height
                                                                      S/N  Mod?
 4.8e+04 1.3e+04 7.8e+00 y  n
 6.16+04 1.5e+04 8.4e+00 y  n
I
 1.8e+04 4.7e+03 2.9e+00 n  n
 3.0e+04 7.5e+03 4.1e+00 y  n
3
 4.0e+04 8.2e+03 S.le+00 y  n
 2.46+05 S.Oe+04 2.7e+01 y  n
                                                                     Page  3  of  8

  Ent:  41 Name:  Total Penta-Furans  F:2   Mass:  339.860  341.857  Mod?  no   #Hom:4

  Run:  14 File:  a!7ju!98b    S:9  Acg:17-JUL-98 22:46:36  Proc:20-JUL-98  09:05:29
  Tables: Run:  al7ju!98b  Analyte: m8290-23-»  Cal:  m8290-23-»Results: M8290-23»
                                                                                                  C'   094

-------
I
 OPUSquan   20-JUL-1998
                   Page 2
  Version: V3.5 17-APR-1997 11:14:34  Sample text:  1072-3 xl/2
    Amount: 0.11
      Cone: 0.11
    Tox #1: -
 Name
of which *
of which *
     Tox #2: -

#     RT Respnse
named and 0.11
named and 0.11
      Tox #3: -
                                         RA
                    1  30:16 1.2e+05  1.74 y
                             1.2e+05

                    2  31:21 1.36+05  1.81 n
                             1.3e+05

                    3  31:45 6.4e+04  1.74 y
                             6.4e+04

                    4  32:30 4.8e+04  1.31 n
                             4.8e+04
          Cone

           0.04
               1
               4
           0.04
               £
               4
           0.02
               <

           0.01
   unnamed
   unnamed
                                                       Area  Height
                                  S/N  Mod?
                                7.4e+04 1.8e+04 1.6e+01 y  n
                                4.2e+04 l.Oe+04 3.6e+00 y  n

                                8.1e+04 2.4e+04 2-le+Ol y  n
                                4.5e+04 l.le+04 4.0e+00 y  n

                                4.0e+04 l.le+04 9.5e+00 y  n
                                2.36+04 8.56+03 3.0e+00 y  n
                               1
                                2.7e+04 9.26+03 8.0e+00 y  n
                                2.16+04 7.7e+03 2.7e+00 n  n
                                                                     Page 4 of 8

   Ent:  42  Name: Total  Penta-Dioxins F:2  Mass: 355.855 357.852 Mod? no   tHom:4

   Run:  14  File: al7ju!98b     S:9  Acq:17-JUL-98 22:46:36 Proc:20-JUL-98 09:05:29
   Tables:  Run:  al7ju!98b  Analyte: m8290-23-»  Cal: m8290-23-»Results: M8290-23*
   Version:  V3.5 17-APR-1997  11:14:34   Sample text: 1072-3 xl/2
     Amount:  0.07
       Cone:  0.07
     Tox #1:  -
  Name
  1,2,3,7,8-PeCDD
of which 0.02
of which 0.02
     Tox #2: -
named and 0.05
named and 0.05
      Tox #3: -
                           RT  Respnse
                                          RA
                        31:29  l.le+05   1.63 y
                              l.le+05

                        32:24  4.2e+04   5.02 n
                              4.2e+04
                     3  32:30 9.8e+03
                              9.86+03
                   1.67 y
    32:37  5.6e+04   1.96  n
          5.6e+04
          Cone

            0.03
               6
               4
            0.01
               i
               e
            o.oo
               e
               2
            0.02
   unnamed
   unnamed
                                                       Area  Height
                                                                       S/N  Mod?
 6.7e+04  2.1e+04  8.3e+00 y  n
 4.1e+04  1.4e+04  l.le+01 y  n

 3.5e+04  l.le+04  4.6e+00 y  n
 6.9e+03  1.9e+03  1.6e+00 n  n
3
 6.16+03  2.4e+03  9.5e-01 n  n
 3.7e+03  1.4e+03  l.le+00 n  n
I
 3.7e+04  l.le+04  4.5e+00 y  n
 1.9e+04  7.4e+03  6.0e+00 y  n
                                                                                                 r '
                                                                                    095

-------
OPUSquan   20-JUL-1998
                                      Page 3
 Ent: 43 Name: Total Hexa-Furans
                                                 Page 5 of 8

                F:3  Mass:  373.821 375.818 Mod? no   #Hom:10
 Run: 14 File: al7ju!98b    S:9  Acq:17-JUL-98 22:46:36 Proc:20-JUL-98 09:05:29
 Tables: Run: al7ju!98b  Analyte: m8290-23->  Cal: m8290-23->Results: M8290-23»
 Version: V3.5 17-APR-1997 11:14:34  Sample text: 1072-3 xl/2
   Amount: 0.14
     Cone: 0.14
   Tox #1: -
Name
of which 0.07
of which 0.07
     Tox #2: -

#     RT Respnse
named and 0.07
named and 0.07
      Tox #3: -
                                        RA
                   1  33:31 3.9e+04  0.96 n
                            3.9e+04

                   2  33:37 1.2e+05  1.31 y
                            1.2e+05

                   3  33:43 3.8e+03  0.20 n
                            3.8e+03

                   4  33:55 3.4e+04  1.36 y
                            3.4e+04

1,2,3,4,7,8-HxCDF  5  34:10 9.5e+04  1.34 y
                            9.5e+04
1,2,3,6,7,8-HxCDF  6


2,3,4,6,7,8-HxCDF  7
   34:15 7.3e+04  1.80 n
         7.36+04

   34:37 5.5e+04  1.64 n
         5.56+04
8  34:43 5.2e+03
         5.2e+03
                                     5.85 n
                   9  34:46 9.9e+03  2.34 n
                            9.9e+03

                   10 34:52 9.76+03  0.80 n
                            9.76+03
          Cone

           0.01
               1

           0.04
               e
               c
           0.00
               e
               •3
           0.01

               1
           0.03
               c
               4
           0.02
               4

           0.02
               i

           0.00
               4

           0.00
               e
               3
           0.00
    unnamed
    unnamed
                                                      Area  Height    S/N  Mod?
  .9e+04 8.5e+03 3.4e+00 y  n
 2.0e+04 7.5e+03 4.8e+00 y  n
1
 6.6e+04 2.5e+04 l.Oe+01 y  n
 5.1e+04 1.7e+04 l.le+01 y  n
3
 6.4e+02 4.3e+02 1.7e-01 n  n
 3.1e+03 1.2e+03 7.6e-01 n  n
1
 2.0e+04 4.5e+03 1.8e+00 n  n
 1.46+04 5.3e+03 3.4e+00 y  n
3
 5.4e+04 1.8e+04 7.2e+00 y  n
  .16+04 1.3e+04 8.2e+00 y  n

  .76+04 1.4e+04 5.5e+00 y  n
 2.6e+04 8.8e+03 5.6e+00 y  n
2
 3.4e+04 l.Oe+04 4.0e+00 y  n
 2.1e+04 8.3e+03 5.36+00 y  n

 4.46+03 1.8e+03 7.36-01 n  n
 7.6e+02 2.8e+02 1.8e-01 n  n
3
 6.9e+03 2.1e+03 8.4e-01 n  n
 3.0e+03 1.4e+03 8.8e-01 n  n
D
 4.3e+03 1.9e+03 7.8e-01 n  n
 5.4e+03 2.0e+03 1.3e+00 n  n
                                                                    Page 6 of 8

 Ent: 44 Name: Total Hexa-Dioxins  F:3  Mass: 389.816 391.813 Mod? no   #Hom:19

 Run: 14 File: al7ju!98b    S:9  Acq:17-JUL-98 22:46:36 Proc:20-JUL-98 09:05:29
 Tables: Run: a!7ju!98b  Analyte: m8290-23-»  Cal: m8290-23-»Results: M8290-23»
 Version: V3.5 17-APR-1997 11:14:34  Sample text: 1072-3 xl/2
   Amount: 0.32
     Cone: 0.32
   Tox #1: -
Name
of which 0.08
of which 0.08
     Tox #2: -

#     RT Respnse
named and 0.24
named and 0.24
      Tox #3: -
                                        RA
                   1  33:52 1.6e+05  1.03 n
                            1.6e+05

                   2  34:03 9.8e+03  2.71 n
                            9.8e+03

                   3  34:04 7.2e+03  1.71 n
                            7.2e+03

                   4  34:10 1.4e+05  1.52 n
                            1.4e+05
                           Cone

                            0.07
                                E
                                •/
                            0.00
                                1
                                2
                            0.00
                                4

                            0.06
    unnamed
    unnamed
                                                      Area  Height
                                  S/N  Mod?
               8.1e+04 3.1e+04 1.2e+01 y  n
                .9e+04 2.6e+04 1.5e+01 y  n

               7.2e+03 1.8e+03 7.4e-01 n  n
               2.6e+03 1.2e+03 6.6e-01 n  n

               4.5e+03 2.3e+03 9.3e-01 n  n
               2.6e+03 1.2e+03 6.6e-01 n  n
              5
               8.6e+04 2.9e+04 1.2e+01 y  n

-------
OPUSquan 20-JUL-1998

5 34:


6 34:


7 34:


1,2,3,4,7,8-HxCDD 8 34:


1,2,3,6,7,8-HxCDD 9 34:


1,2,3,7,8,9-HxCDD 10 34:


11 35:


12 35:


13 35:


14 35:


15 35


16 35


17 35


19


32


37


42


46


58


07


10


18


20


25


30


35


1.
1.

6.
6.

6.
6.

3.
3.

6.
6.

6.
6.

8.
8.

7.
1 .

5.
5.

7
7

7
7

6
6

5


5e+05
5e+05

5e+03
5e+03

6e+03
6e+03

9e+04
9e+04

6e+04
6e+04

8e+04
8e+04

5e+03
5e+03

7e+03
7e+03

6e+03
6e+03

4e+03
4e+03

9e+03
9e+03

2e+03
2e+03

4e+03
Page 4

1.36 y


1.15 y


1.50 n


1.02 n


1.07 y


0.83 n


2.13 n


0.86 n


0.72 n


0.90 n


0.54 n


0.


0.


0.


0.


0.


0.


0


0


0


0


0

5.
07
8.
6.
00
3.
3.
00
4.
2.
02
2.
1.
03
3.
3.
03
3.
3.
00
5.
2.
00
3
4
00
2
3
00
3
3
00

7e+04

6e+04
3e+04

5e+03
Oe+03

Oe+03
6e+03

Oe+04
9e+04

4e+04
2e+04

le+04
7e+04

8e+03
7e+03

6e+03
2e+03

3e+03
3e+03

5e+03
9e+03

2.8e+03

1.67 n


0.98 n

0


0
5.4e+03

18 35


19 35



42


47



6
6

4
4


4e+03
4e+03

. 6e+03
. 6e+03


1.00 n


0.35 n



0


0


5
00
3
2
.00
2
2
.00
3
3
.00
1
3
2e+03

9e+03
3e+03

.7e+03
. 7e+03

.2e-t-03
.2e+03

. 2e+03
. 4e+03

1.3e+04

2.4e+04
2.0e+04

1. Oe+03
1.4e+03

1.5e+03
1.3e+03

7.2e+03
6.2e+03

1. Oe+04
9.9e+03

9.4e+03
1.2e+04

1.8e+03
l.le+03

1.4e+03
1.5e+03

8.6e+02
1.76+03

1.4e+03
1.6e+03

1.2e+03
1.3e+03

1.5e+03
9.96+02

9.3e+02
9.06+02

1. Oe+03
1.66+03

7.5e+02
1.6e+03

7.2e+00

9.7e+00
l.le+01

4-le-Ol
7.6e-01

6-Oe-Ol
7.1e-01

2.96+00
3.46+00

4.2e+00
5.4e+00

3.8e+00
6.46+00

7.3e-01
5.96-01

5. 76-01
S.Oe-01

3.5e-01
9.2e-01

5.86-01
8.5e-01

4.96-01
7.1e-01

6.06-01
5.4e-01

3.7e-01
S.Oe-01

4.0e-01
8.6e-01

3.0e-01
8.6e-01

y

y
y

n
n

n
n

n
y

y
y

y
y

n
n

n
n

n
n

n
n

n
n

n
n

n
n

n
n

n
n

n

n
n

n
n

n
n

n
n

n
n

n
n

n
n

n
n

n
n

n
n

n
n

n
n

n
n

n
n

n
n

-------
OPUSquan   20-JUL-1998
                   Page 5
                                                                    Page 7 of 8

 Ent: 45 Name: Total Hepta-Furans  F:4  Mass: 407.782 409.779 Mod? no   #Hom:3

 Run: 14 File: al7ju!98b    S:9  Acq:17-JUL-98 22:46:36 Proc:20-JUL-98 09:05:29
 Tables: Run: a!7ju!98b  Analyte: m8290-23-»  Cal: m8290-23-»Results: M8290-23»
 Version: V3.5 17-APR-1997 11:14:34  Sample text: 1072-3 xl/2
   Amount: 0.19
     Cone: 0.19
   Tox #1: -
Name
of which 0.15
of which 0.15
     Tox #2:  -

#     RT Respnse
named and 0.03
named and 0.03
      Tox #3: -
                                        RA
1,2,3,4,6,7,8-HpCDFl  36:22 3.2e+05  1.14 y
                            3.2e+05

                   2  36:33 2.7e+04  1.03 y
                            2.7e+04

                   3  36:41 3.76+04  0.69 n
                            3.7e+04
          Cone

           0.15
               1
               1
           0.01
               1
               ]
           0.02
unnamed
unnamed
Area  Height    S/N  Mod?
                                1.7e+05 4.9e+04 2.1e+01 y  n
                                l.Se+05 4.6e+04 3.9e+01 y  n
                               L
                                1.4e+04 4.36+03 1.8e+00 n  n
                                1.3e+04 4.9e+03 4.2e+00 y  n

                                1.5e+04 5.66+03 2.4e+00 n  n
                                2.2e+04 6.0e+03 5.1e+00 y  n
                                                                    Page  8  of  8

  Ent:  46  Name:  Total  Hepta-Dioxins  F:4   Mass:  423.777  425.774 Mod? no   #Hom:5

  Run:  14  File:  al7ju!98b    S:9   Acq:17-JUL-98 22:46:36  Proc:20-JUL-98  09:05:29
  Tables:  Run:  a!7ju!98b  Analyte: m8290-23-»   Cal:  m8290-23-»Results: M8290-23»
  Version:  V3.5  17-APR-1997  11:14:34  Sample text:  1072-3 xl/2
    Amount:  0.25
      Cone:  0.25
    Tox #1:  -
 Name
of which 0.11
of which 0.11
     Tox #2: -

#     RT Respnse
named and  0.14
named and  0.14
      Tox  #3: -
                                         RA
                    1  36:21 4.6e+04  2.52 n
                             4.6e+04

                    2  36:35 2.0e+05  1.15 y
                             2.0e+05

                    3  36:40 1.4e+04  0.72 n
                             1.4e+04

 l,2,3,4,6,7,8-HpCDD4  37:112.2e+05  0.91y
                             2.2e+05

                    5  37:31 2.9e+04  4.90 n
                             2.9e+04
           Cone

            0.02
                T
                1
            0.10
                1
                s
            0.01
                c
                £
            0.11
                1
                ]
            0.01
 unnamed
 unnamed
                                                       Area  Height
                                   S/N  Mod?
                                 3.3e+04  1.2e+04  1.2e+01 y  n
                                 1.3e+04  3.7e+03  3.2e+00 y  n
                                D
                                 l.le+05  3.3e+04  3.4e+01 y  n
                                 9.3e+04  2.8e+04  2.4e+01 y  n
                                L
                                 5.96+03  2.16+03  2.2e+00 n  n
                                 8.2e+03  2.16+03  1.8e+00 n  n
                                L
                                 l.Oe+05  2.6e+04  2.7e+01 y  n
                                 l.le+05  3.1e+04  2.7e+01 y  n
                                 2.4e+04 7.16+03 7.4e+00 y  n
                                 4.9e+03 1.7e+03 1.5e+00 n  n

-------
File: A17JUL98B Acq: 17-JUL-1998 22:46:36 Exp: EXP M23 DB5
Sample #9 Text: 1072-3 xl/2 ALS #9
319.8965 S:9 SMO(1,3) BSUB (128 , 15, -3 . 0) PKD(3 , 3 , 3 , 0 . 10% , 1608
100% A4.83E4
50J \ A1.78E4
0 " ~-'~-~-'V~y^<'V~ — ^A/Vv^-^^VW-i^y^^^yVv'^^-^^-^^'^SVvVN/^_^~v--^A,
24100
321.8936 S:9 SMO(1,3)
100%
501
"",,,,,
24 100
331.9368 S:9 SMO(1,3)
100%
sol
0:
	 24 loo'
333.9339 S:9 SMO(1,3)
lOOi
50_
24:00
327.8847 S:9 SMO(1,3)
100%
50J
24:00
316.9824 S:9 SMO(1,3)
100% 23:31 23:56
50 j
o:
24 loo'
25 loo 	 26 100
BSUB (128, 15, -3.0) PKD(3 , 3 , 3 , 0 . 10%, 1816
A6.11E4
A A3.02E4
-' ' ' 25 100 	 26 loo'
BSUB (128, 15, -3.0) PKD(3 , 3 , 3 , 0 . 10%, 7536
25 100 	 26 loo'
BSUB (128, 15, -3.0) PKD(3 , 3 , 3 , 0 . 10%, 4632
25:00 26:00
BSUB (128, 15, -3.0) PKD(3 , 3 , 3 , 0 . 10%, 4700
25:00 26:00
PKD(3,3,3,100.00%,0.0,1.00%,F,F)
24:2624:4925:1125:3425:58 26:28

25 100 	 26 loo'
_OVATION Voltage SIR EI+ GC Autospec-UltimaE Paradigm
.0,1.00%,F,F)
A6.07E4 1.5E4
|\ A4 . OOE4 '
/ \ &1 Ar\T?A.I\ _7 . 5Ej
_n r~ /• T-C^ f\ rt-L . *d VJ.Cj'x / \
A2 . 56E3 / \ A / \ -
^v/^A~>~rVV^-— ^-A^-->~r^v^AW>--XA^v^
-------
Samj
355
1003
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357.
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so:
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366.
100%,
so:
01

J: A17JUL98B Acq: 17-JUL-1998 22:46:36 Exp: EXP_M23 DB5 OVATION Voltage SIR EI + GC Autospec-UltimaE Parad
>le #9 Text: 1072-3 xl/2 ALS #9
8546 S:9 F:2 SMO(1,3) BSUB (128, 15 , -3 . 0) PKD(3 , 3 , 3 , 0 . 10% , 2468 . 0, 1 . 00%, F, F)
A6.74E4
A A6.46E4
/ A A3.48E4
\ A A
/ A\3 96E3 /\ /^VfX^J V, / V
3bli2 30124 30136 sbUs SlloO 3ill2 31124 33.136 31.148 32166 32 1 12 ' 32 124 ' 32 136 ' 32 148 ' 33 1 66 ' 33 1 12
8517 S:9 F:2 SMO(1,3) BSUB (128 , 15, -3 . 0) PKD(3 , 3 , 3 , 0 . 10%, 1232 . 0 , 1 . 00%, F, F)
A4.13E4
/ \ A2 . 68E4 A1 • 89E4
,wO\Ai 61E3 A J \ /-\/\^f\6 ' 93^Lj \ A7;^E3
3b!i2 30124 3ol36 sbUs 31166 3ili2 3ll24 31-.36 31.148 32166 32112 32 124 ' 32 136 ' 32 Us ' 33 1 66 ' 33 Il2
8949 S:9 F:2 SMO(1,3) BSUB (128, 15, -3 . 0 ) PKD(3 , 3 , 3 , 0 . 10%, 3756 . 0 , 1 . 00%, F, F)
A1.72E8
f(
30:12 30:24 30:36 30:48 31:00 31:12 31:24 31:36 31:48 32:00 32:12 32:24 32136 32148 33loO 33ll2
8919 S:9 F:2 SMO(1,3) BSUB (128, 15, -3 . 0) PKD(3 , 3 , 3 , 0 . 10%, 2332 . 0, 1 . 00%, F, F)
A1.09E8
j[
30:12 30124 30136 3ol48 31:00 31:12 31:24 31:36 3ll48 32166 32ll2 32:24 32:36 32J48 33:66 33:12
9792 S:9 F:2 SMO(1,3) PKD(3 , 3 , 3 , 100 . 00%, 0 . 0, 1 . 00%, F, F)
30:29 30:53 31:19 31:41 32:09 32:34 32^ 32:5R 33-10

30:12 30:24 3Q\36 3ol48 3ll66 3lli2 31124 31136 SlUs 32166' 32112 32 :24 ' 32 136 ' 32:48 ' 33 Sod ' 33 :12
igm
2.2E4
_1 . 1E4
0 OEO
Time
1.5E4
_7 . 6E3
0 OEO
Time
6.2E7
13.1E7
O.OEO
Time
r3 . 9E7
_2 . OE7
O.OEO
Time
_7 . 6E7
.3.8E7
O.OEO
Time

-------
Fil«
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389
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380.
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5: A17JULy«B Acq: 17-JUL-1998 22:46:36 Exp: EXP M23 DB5 OVATION Voltage SIR EI+ GC Autospec-UltimaE Parad
3le #9 Text: 1072-3 xl/2 ALS #9
8156 S:9 F:3 SMO(1,3) BSUB(128, 15 , -3 . 0) PKD(3 , 5, 2 , 0 . 10% , 2488 . 0, 1 . 00%, F, F)
S. A8.11E4
A A A8.60E4
\ 1 y\ \ A3.41E4 A3.07E4
^^__^-— 	 ____/— -X 3i^^ 1 V V__ __/TV __ylV^5.79E3 A3.86E3
33!24 33!36 33! 48 34!oO 34!l2 34?24 34!36 34:48' ' 's'slo'o' ' 's'sllV ' ' 35:24' ' 'a'slaV ' '35
8127 S:9 F:3 SMO(1,3) BSUB (128 , 15 , -3 . 0) PKD(3 , 5, 2 , 0 . 10% , 1824 . 0 , 1 . 00%, F, F)
A7.86E4
\ A6.32E4
/ 1 A5.68E4 A »o fiqp4
/ \ A / \ A3.20E4 AJ ' ^>
. 	 ^^y-A^i^3/ \/ ^i?^i_ ^^/W^/ V 	 A3.28E3
33:24 33:36 33:48 34:00 34:12 34!24 34!36 34!48 3s!oO 3s!l2 35?24 35:36 35
8559 S:9 F:3 BSUB(128, 15, -3 . 0) PKD(3, 5, 2, 0 . 10%, 9072 .0, 1 . 00%,F,F)
A1.56E8 A1.76E8
A A
M A
nv. /V_
33!24 33!36 33!48 34!oO 34!l2 34.!24 34!36 34!48 3s!oO 3s!l2 3s!24 3s!36 35
8530 S:9 F:3 BSUB(128, 15, -3 .0) PKD(3 , 5 , 2 , 0 . 10%, 4956 . 0, 1 . 00%, F, F)
A1.23E8 A1.41E8
A A
M A
/i L / v_
1 • I ' ' • • ' | 	 | 	 | i . i i i | i i i i i i i i i i i i i r 	 i i 1 I i i i i i I i i i i i i I"-T™ i — i — i — i i i i — i i i — r— i — r
33:24 33:36 33:48 34:00 34:12 34:24 34:36 34:48 35:00 3s!l2 3s!24 35!36 35?
9760 S:9 F:3 SMO(1,3) PKD(3 , 3 , 3 , 100 . 00%, 0 . 0 , 1 . 00%, F, F)
33:30 33:53 34:06 _34j32 35iJ39 35-42


33!24 33:36 33Us 34:00 34!l2 34:24 34!36 '34: 48' 3s!o'o 3s!l2 '35: 24' 35!36 35:
igm

3.4E4

L1.7E4

48 Time

2 . 8E4

1 4E4

o OEO
48 Time

6.7E7
.3.4E7
OEO
48 Time

_5.4E7
12 . 7E7
'0 OEO
48 Time

1.6E8
_7.9E7
O.OEO
48 Time

-------
Pile
Saim;
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;: A17JUL98B Acq: 17-JUL-1998 22:46:36
>le #9 Text: 1072-3 xl/2 ALS #9
7767 S:9 F:4 SMO(1,3) BSUB (128, 15, -3 . 0)
A1.07E5
A3.28E4 / 1
__ AJ_L 	
36l6o 36112 36124 36136 beUs 37:
7737 S:9 F:4 SMO(1,3) BSUB{128, 15, -3 . 0)
A9.27E4
A1.30E4 / \
/"^ 7 V-v_
36:00 36I12 36!24 36S36 36148 37!
8169 S:9 F:4 SMO(1,3) BSUB(128, 15, -3 . 0)
36:00 36:12 36:24 36:36 36:48 37:
8140 S:9 F:4 SMO{1,3) BSUB (128, 15, -3 . 0)
36:00 36:12 36:24 36:36 36:48 37:
9728 S:9 F:4 SMO(1,3) PKD(3 , 3 , 3 , 100 .00%,
36:01 36:14 36:24 36:3536:4436:54
r
36:00 36112 36!24 36136 36:48 3v!
Exp: EXP_M23_DB5_OVATION Voltage SIR EH- GC Autospec-UltimaE Parad
PKD(3,3,3,0.10%,960.0,1.00%,F,F)
A1.03E5
/ \ A2.38E4
y v__ ^ 	 	
00 37!i2 37!24 37136 37I48 38166 38ll2 38124 38136 38I48 39
PKD(3,3,3,0.10%,1156.0,1.00%,F,F)
A1.13E5
J V^_ A4185E3
66 37!i2 37S24 37136 37148 3s!66 38!l2 38:24 38136 SsUs 39:
PKD(3,3,3,0.10%,5864.0,1.00%,F,F)
Al . 14E8
00 37:12 37:24 37:36 37:48 38:00 38:12 38:24 38:36 38:48 39
PKD(3,3,3,0.10%,2944.0,1.00%,F,F)
Al . 10E8
igm
3.4E4
.1.7E4
.O.OEO
00 Time
3.2E4
_1.6E4
00 Time
3.0E7
.1.5E7
O.OEO
00 Time
_2 . 9E7
_1.4E7
O.OEO
00 37:12 37:24 37:36 37:48 38:00 38:12 38:24 38:36 38:48 39:00 Time
0.0,1.00%,F,F) ^
37:15 37:35 37:46 38:13 3b:33 1 . OEfl

_5.2E7
-O.OEO
66 37!i2 37I24 37136 37I48 38166 38!i2 38\24 38:36 38!48 39:00 Time

-------
File: A1/JUL98B Acq: 17-JUL-1998 22:46:36 Exp: EXP M23 DBS OVATION Voltage SIR EI+ GC Autospec-UltimaE Paradigm
Sample #9 Text: 1072-3 xl/2 ALS #9
457.7377 S:9 F:5 SMO(1,3) BSUB (128, 15, -3 . 0 ) PKD(3 , 3 , 3 , 0 . 10% , 3336 . 0 , 1 . 00%, F, F)
100S
50-
n
A2 . 50E5
J\^
6.6E4
_3.3E4
n m?n
T~ ( 1 1 •'! 1 -I— r 	 1 	 1 	 [ 	 1 	 1 	 1 	 T " 1 	 1 	 T "1 	 T 	 T 	 1 	 r 	 1 	 1 	 1 	 1 	 1 	 1 	 1 	 1 	 1 	 1 	 1 	 1 	 1 	 1 	 1 	 1 	 1 	 1 	 1 	 1 	 1 	 1 	 1 	 r 	 1 	 1 	 1 	 ! 	 ( 	 1 	 | 	 1 	 1 	 1 	 1 	 J— w . ««w
39:12 39:24 39:36 39:48 40:00 40:12 40:24 40:36 40:48 41 00 Time
459.7348 S:9 F:5 SMO(1,3) BSUB(128, 15, -3 . 0) PKD(3 , 3 , 3 , 0 . 10%, 1188 . 0, 1 . 00%, F, F)
lOOi
50_
0
A2 . 86E5
A
/ v_ 	 	
7 . 2E4
.3 . 6E4

39!l2 39^24 39!T6 39.-48 4o!ob 40^12 4ol24 4o[36 4o!48 4l!oO Time
469.7780 S:9 F:5 SMO(1,3) BSUB (128, 15 , -3 . 0) PKD(3 , 3 , 3 , 0 . 10%, 1232 . 0 , 1 . 00%,F,F)
100%
so:
o:
Al . 47E8
A
/ v_
3.3E7
_1.7E7
.O.OEO
39-ll2 39-124 39:36 39548 4o!ob 4o!l2 4o!24 40-136 40:48 41:00 Time
471.7750 S:9 F:5 SMO(1,3) BSUB (128, 15, -3 . 0) PKD(3 , 3 , 3 , 0 . 10% , 1240 . 0 , 1 . 00%, F, F)
100S
50J
OJ
Al . 67E8
/Y_

3.7E7
_1.9E7
O.OEO
39!l2 39!24 39!36 39!48 4o!ob 4o!l2 4o!24 4o!36 4o!48 41 00 Time
454.9728 S:9 F:5 SMO(1,3) PKD(3 , 3 , 3 , 100 . 00%, 0 . 0 , 1 . 00%, F, F)
100%
50J
o:
39:07 39:15 39:29 39:41 39:56 40:04 40:11 40:17 40:43 40:52 1.1E8


_5.7E7
' O.OEO
39:12 39!24 39:36 39!48 4o!ob 4o!l2 4o!24 40:36 4o!48 41:00 Time
O
p *

-------
File: A17JUL98B  Acq:  17-JUL-1998 22:46:36  Exp: EXP_M23_DB5_OVATION Voltage SIR EI +—GC Autospec-liltimaE
Sample #9  Text:  1072-3 xl/2  ALS #9
303.9016 S:9 SMO(1,3)  BSUB(128,15,-3.0)  PKD(3,3,3,0.10%,2008.0,1.00%,F,F)
100%                                                              A7.31E4
                                              A4.66E4
                                                     MA2.25E4
                                                      -  A   A       / \      A7.68E3
                                                           J^.^J~\^^r^^^
                                                           f^ i ^"i i«^ i I ^^i  i  • 
-------
  File: A17JUL98BAcq:  17-JUL-1998 22:46:36Exp:  EXP_M23_DB5_OVATION Voltage SIR EI+GC Autospec-UltimaE—Paradigm
  Sample  #9   Text:  1072-3 xl/2  ALS #9
  339.8597 S:9  F:2  SMO(1,3)  BSUB(128,15,-3.0)  PKD(3,3,3,0.10%,1156.0,1.00%,F,F)
  100%,                                        A8.J5E4
         A7.38E4
                                                                   A4.18E4
    50J

    OJ
              .09E3
A
A4.75E4


      AAA8.81E3
     J \  ^"^
                                                                                                                   2 . 5E4

                                                                                                                  .1.3E4
                                                                                                                     .O.OEO
      11 i ..... i ' r ' '  ' ' i ..... | i i i T i  |i"i T~rT| i  i i i i I ..... i T~T*I ii I i i i i  i i~i iii  ["TTTT^ i 'i i i' i i r i^i i i i i' i in T*r^~~i i TT> r rr^r
      30:12  30:24   30:36  30:48  31:00  31:12  31:24   31:36   31:48  32:00  32:12  32:24  32:36  32:48  33:00  33:12
341.8568 S:9 F:2  SMO(1,3)  BSUB(128, 15, -3 . 0)  PKD(3 , 3 , 3 , 0 . 10%, 2832 . 0 , 1 . 00%, F, F)
       A4.23E4                              A4 .
                                                          A2.32E4                  A2.07E4
                                                                                                                        Time
                                                                                                                    17.1E3
                                                                                                                      .OEO
       30il2  30124  3036  Sos  31:00  31:12  3124  Slse  31148 ' 32I66 ' 32112 ' 32124 ' 32!36 ' 32I48  33166 ' 33!i2     Time
  351.9000 S:9 F:2 SMO(1,3) BSUB(128,15,-3.0) PKD(3,3,3,0.10%,2600.0,1.00%,F,F)
                                                                  A2.19E8         A2.01E8                            7.7E7
   50J

    ol
         T
                             T
                                    T
                                                                   U • * •* J-J >-»        f\fl • \J J. i
                                                                                                                  .3 . 9E7

                                                                                                                   O.OEO
                                          I i i rTT I i i i i i  I i i i . i  i i i "i i i I  \ i i i i I i  i i i*i I i ~r I I I I i i  i i i i i i i  i i i i i i  i i i i .
     30:12  30:24  30:36  30:48  31:00  31:12  31:24  31:36  31:48  32:00  32:12  32:24  32:36   32:48   33:00   33:12     Time
353.8970 S:9 F:2 SMO(1,3) BSUB(128,15,-3.0) PKD(3,3,3,0.10%,4808.0,1.00%,F,F)
                                                                A1.42E8         A1.29E8

1 ' ' 1 ' ' ' ' ' | 1 ' ' • ' | ' ' ' ' ' | • ' ' ' • | ' ' ' 1 ' | 1 1 ri r 1 	 1 1 ' 1 1 1 I 1 1 * 1 1 pi 1 1 1 1 | 1 1 1 'I 1 It 1 1 1 1 I I f T -T'-TT ' ' ' 1 1 1 1 1 1 1 1 1 1*
L2 . 5E7
' O.OEO

       30:12  30:24  30:36  30:48  31:00  31:12  31:24  31:36  31:48  32:00  32:12  32:24  32:36  32:48  33:00  33:12    Time
   09.7974 S:9 F:2 SMO(1,3) BSUB(128,15,-3.0) PKD(3,3,3,100.00%,3776.0,1.00%,F,F)
                                                                                         32;36
                                                                                                        33:01
     30.:12  30124  30!36 ' 30:48 '  3l!6d ' 3i!l2 ' 3i!24 ' 3~Tl36
                                                                     32166  32112  32l24  32I36  32l48  33!66 ' 33!l2    Time
366.9792 S:
1003^
50_
o:


36!i2
9 F:2 SMO(1,3)
30:29


30124 30:36
PKD(3
30:


3b!48
,3,3
53


3l!
, 100. 00%, 0.0,1. 00%, F
31:19


66 31:12 31:24 3l!
,F)
31:41 32:09


i i i i i | i i i i i | T i r i i | i i
36 31:48 32:00 32:12

32:34


32:24 32:36

32^46


t-r T | i i
32:48

32:5R


T"l 1 | 1 1
33:00

JiiHL,-? . 6E7


.3.8E7
n nun
i i i i i r' " ' """
33:12 Time
O
CA

-------
Pile: Al
7JUL98B
Sample #9 Text:
373.8207
100%.
I
50J



S:9


Al.
F:3
A6

91E
Acq: 17-JUL-1998 22:4b:
36
Exp: EXP_M23_DB5
_OVATION
Voltage SIR EI+ GC Autospec-UltimaE Paradigm
1072-3 xl/2 ALS #9
SMO (1,3)
.64E4
A
/
BSUB(128,15,-3




A5

.0)

PKD(3, 5,2,0.10%,

2504.0,1

.00%,F,F)
2.7E4
.42E4
A
Z\/ V .. Ab^!i_ J }
'33!
375.8178
100%

50 j
0 '



'33!
383.8639
100%
50J
o:



'33!
385.8610
100%
50J
o"



'33!
445.7555
100%
"
50J
o:

24
S:9


Al.
/
24
8:9



24
S:9



i i r
24
S:9


33:26
r\

w!
380.9760
100%
50 J
0"
y

M!
\/^
24
S:9
33:


24
33
F:3
A5

99E'
/\
'V
33
F:3



33
F:3



33
F:3


33
/
v /
33
F:3
30


— , 	 1 —
33
:36 33
SMO (1,3)
.Q5E4

A
A\3.14E3
	 \ f — a 	
TsY ' '33
BSUB(128



r ' ' ' ' '
:36 33
BSUB(128



•36 33
SMO(1,3)


:36
•~k

TsT ' '33
SMO (1,3)



T — i — r— i — i — i —
:36 33
148
34:00
BSUB(128,15, -3


Al.4

Us'
,15, -3



1 ' i ' i
:48
,15, -3



1 i | ' |
•48

A4
4E4
vj 	 J.
34\QQ' '^
.0) PKD(3


y
— i — | — l — i — r-'r
34:00
. 0 ) PKD ( 3


J
34:00
BSUB(128,15,-3


33:51
\^V_
I481 '
PKD(3
33:53


U's'


34
S
-^^ 	 '
34500
,3,3,100.
34!
.0)

A A3-
J \ A1.20E4 /
V ^^. s~~^ /
12' 34:24 34:
PKD(3,5,2,0.10%,

43E4

V^^e^ES AU^i_ _-__ 	 -
36 34
1564.0,1


_1.4E4

:48 35:00 35:12 35:24 35:36 35-48 Time
.00%,F,F)
_1.8E4
. 06E4
A
i \
34!
,5,
Al
A
'.1
34!
,5,
A2
A
l\
34!
.0)


08
X_
34!
00%
A
11 	 i
— i — i — i— i— r-j-T i i i i |
12 34:24 34:
2, 0.10%, 30900. 0,1
.17E8
A,
A
' v
12 34524 34!
2, 0.10%, 47760. 0,1
.23E8
A.
A
' V.
12 ' 34:24 34 5
10E4
A

\ A5.38E3 .^ ^
V ^-^, 	 ^ _ — ^ — ^ \ ^-^ 	 . 	 ^**~^
36 34
.00%,F,F



36 34
.00%,F,F



36 34
PKD (3, 3, 3 ,100. 00%, 1816.0



.9.0E3
O.OEO
548 35500 355l2 35524 3s!36 35 48 Time
)



5.2E7
_2 . 6E7
O.OEO
548 35500 355l2 35:24 35:36 35 48 Time
)



1.0E8
L5.1E7
•O.OEO
548 35500 355l2 3s!24 35536 35-48 Time
,1.00%,F,F)
34:45 34A,58
34:4A
34 • 33 f^ \
t A 1 £ J •* » J J / \
3i^6 34:26 A / \
^ \^N 	 >\^-' ^
12 34?24 345
, 0.0,1. 00%, F,F)
^J
36 34

34:06


34! oo


34!


12 34524 345


36 34
\
/ V ^ ^ 35:26 35:38
^— _ / \ 	 . 35:16 /\ .. /w.
^^^ ^-^-^x— ~---^__/ V_Xv^y ^^
8.6E3

.4.3E3
O.OEO
548 35500 35:12 35:24 35:36 35:48 Time

34:52 35iD9 . 35:42 1 . fiEfl


_7 . 9E7
O.OEO
548 35500 355l2 35524 35?36 35548 Time

-------
 File:  A17JUL98B  Acq:  17-JUL-1998  22:46:36—Exp:  EXP_M23_DB5_OVATION Voltage SIR EI+—GC Autospec-UltimaE—Paradigm
 Sample #9   Text:  1072-3 xl/2  ALS  #9
 407.7818 S:9  F:4  SMO(1,3)  BSUB(128,15,-3.0)  PKD(3,3,3,0.10%,2364.0,1.00%,F,F)
 1004              A1.68E5

  50J
       36:00  36:12  36:24  36:36  36:48  37:00  37:12  37:24  37:36  37:48  38:00
409.7788 S:9  F:4  SMO(1,3)  BSUB(128,15,-3.0) PKD(3,3,3,0.10%,1176.0,1.00%, F, F)
100%               A1.47E5
   O
                                                                                               , .    ,  ,	 -0 • OEO
                                                                                  38il2  38:24  38:36   38:48   39:00  Time
                                                                                                                 4.7E4

                                                                                                                 J2.4E4
                             A2.19E4
                                                           A6.13E3
                                                                                                                 O.OEO
       36:00  36:12  36:24  36:36  36:48  37:00  37:12  37:24  37:36  37:48  38:00
417.8253 S:9 F:4  SMO(1,3) BSUB(128,15,-3.0) PKD(3,3,3,0.10%,2276.0,1.00%,F,F)
1004              A5.06E7
  50J
   O
                                                          A3.07E7
                                                                                  38:12  38:24  38:36  38:48   39iOO  Time
                                                                                                                 1.5E7

                                                                                                                 L7.6E6

                                                                                                                 LO.OEO
       36:00  36:12  36:24  36:36  36:48  37:00  37:12  37:24   37:36  37:48  38:00
419.8220 S:9 F:4 SMO(1,3) BSUB(128,15,-3.0) PKD(3,3,3,0.10%,13480.0,1.00%,F,F)
1004,              A1.15E8
                     A
                                                         A6.92E7
  OJ
                                                                                  38:12  38:24  38:36  38:48  39:00 Time
                                                                                                                  3.4E7

                                                                                                                 _1.7E7
                                                                                                                 O.OEO
       36:00  36:12  36:24  36:36  36:48  37:00  37:12  37:24  37:36  37:48  38:00
479.7165 S:9 F:4 SMO(1,3) BSUB(128,15,-3.0) PKD(3,3,3,100.00%,3768.0,1.00%,F,F)
1004                                           „ ,„                       37;57
 50,
       36:00  36:12  36:24  36:36   36:48  37:00  37:12  37:24  37:36   37:48  38iOO
430.9728 S:9 F:4 SMO(1,3) PKD{3,3,3,100.00%,0.0,1.00%, F, F)
1004,    36:01   36;14 36:24 36:3536:44 36:54	37:15	37:35 37:46	
 50J
  OJ
                                                                                  38:12  38:24  38:36   38:48  39:00  Time
                                                                                                                 1.0E4
                                                                                                                .5.0E3
                                                                                                                  O.OEO
                                                                                                             39:00  Time

                                                                                                                  ..OE8
 38:12   38:24  38:3

. 38:13	38;33
       i i I i  i i i i i i  i i i i i i i  i i i I i i i i  i I i i i i i I  i i i i i I i  i i i i I i—i  i i i I i i i i  i I	iii
       36:00  36:12  36:24   36:36  36:48  37:00  37:12  37:24   37:36  37:48  38:00
                                                                                                                .5.2E7

                                                                                  i i i i i  i—i i | i i i  i i i i i i i  i i i i i i  i
                                                                                  38:12   38:24   38:36  38:48  39:00  Time

-------
File: A17JUL98B
Sample #9 Text:
441.7427 S:9 F:5
100%
50 J


39:12
443.7398 S:9 F:5
100%
50J




39:12
469.7780 S:9 F:5
100%
50J
o •



"-1 — i — i — i — i — i — i —
39:12
471.7750 S:9 F:5
100%
50J
o •



39:12
513.6775 S:9 F:5
100%
sol
0 '


39:11
U-J — i — i — i — i — i — i —
39:12
454.9728 S:9 F:5
100% 19rf>7 39:

50^
•». o:
/


T "-1 — i — i — i — i — i — i —
->v 39:12
Acq: 17-JUL-1998 22:46:36
1072-3 xl/2 ALS 19
SMO(1,3) BSUB(128,15,-3.0)


39:24 39:36
SMO(1,3) BSUB(128,15,-3.0)


A7.71E3
39:24 39:36
SMO(1,3) BSUB(128,15,-3.0)



39:24 39:36
SMO(1,3) BSUB(128,15,-3.0)



39:24 39:36
SMO(1,3) BSUB(128,15,-3.0)

39:24 39:33 39:40
_^^/*^_^-^s\_y~^"$-
i 	 1 	 1 	 r — r i i r i i | i i i i
39:24 39:36
SMO(1,3) PKD(3,3,3,100.00%
15 39:29 39:41



T 	 1 	 1 	 1 	 1 	 1 	 1 	 r 	 i i i i . . .
39:24 39:36
Exp: EXP_M23_DB5_OVATION Voltage SIR EI+ GC Autospec-UltimaE Paradigm

PKD(3,3,3,0.10%,1256.0,1.00%,F,F)
A8 . 16E4
__^/A^
2.1E4
_1.0E4
0 .OEO
39:48 40:00 40:12 40:24 40:36 40:48 41:00 Time
PKD(3,3,3,0.10%,1476.0,1.00%,F,F)
A1.15E5
\ \
J Nq^46E3 	 	 A3.10E3
3.2E4
_1.6E4
O.OEO
39148 4o!ob 4o!l2 4o!24 4o!36 4ol48 41 00 Time
PKD(3,3,3,0.10%,1232.0,1.00%,F,F)
Al . 47E8
/\
J ^^-~~—
3.3E7
L1.7E7
.O.OEO
39Us 4o!ob 40:12 40^24 40:36 40:48 41:00 Time
PKD(3,3,3,0.10%,1240.0,1.00%,F,F)
Al . 67E8
/\
J v__
3.7E7
L1.9E7
.O.OEO
39148 4o!ob 4o!l2 40^24 40:36 4ol48 4lloO Time
PKD(3,3,3,100.00%,1132.0,1.00%,F,F)
40:01
39 54X X 40:13 4°--20_* 40-38 40-y49 40.56
^/^-^—^ vy-vXX__X\/V45-l±°-^^^_r'^^-v'" ^ \ 	 /\ 	
6.4E3
_3.2E3
O.OEO
39:48 40:00 40:12 40:24 40:36 40:48 41:00 Time
,0.0,1.00%,F,F)
39:56 40:04 40:1140:17 40:43 40:52 l.lRfl




_5.7E7
_O.OEO
39l48 40:00 40:12 40:24 40.36 40:48 41:00 Time

-------
                                                                     Paradigm Analytical Labs
                             Analytical Data Summary Sheet
Analyte

2,3,7,8-TCDD
1,2,3,4,7,8-HxCDD

1,2,3,7,8,9-HxCDD
l&',4$J;$3jffil!g?''*'
OCDD
2,3,7,8-TCDF
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
1,2,3,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
OCDF
Total TCDDs
Total PeCDDs
Total HxCDDs
Total HpCDDs
Total TCDFs
Total PeCDFs
Total HxCDFs
Total HpCDFs
TEQ(ND=0)
TEQ (ND=l/2)
Concentration
WB
0.0012
: JMPC , •"
ND

EMPC

0.0146
-0&06
0.0022
EMPC
EMPC
EMPC
EMPC
ND
0.0035
ND
EMPC
0.0088
0.0004
0.0076
0.0096
0.147
0.0156
0.0032
0.0036
0.0024
0.0028
• • ':".!&* • "•:
•*"$•- -•
0.0005
0.0006

0.0004

0.0005
*"j4CdJ8S^:
0.0004
TM9804
0.0005
0.0004
0.0004
0.0005
0.0007
0.0009
0.0008
0.0005
0.0004
0.0004
0.0004
0.0005
0.0004
0.0004
0.0007


EMPC
~r :j*WI'! :


Kg!* j|iK|t ', y
0.0012
IgJ't,^,.', ';,;„

• : •.*' • '•:!'

0.00i9
0.0017
0.0008
0.0008


0.0025
..
0.0048
0.0120
0.0116
0.160
0.0216
0.0072

0.0041
0.0042
RT
(mm.) i
28:26
-, '- 'IT!*^.-^
, ' .«/A»*/Q
• -l^l^
34:58
£^?
40:01
,27:26
31:56
32:24
34:10
34:15
34:37

36:21
40:10










Ratio
_-,_ . - •
0.76
1.84
-f^ tM :
2.41
. tis^-.r;.1
0.89
0.73
1.57
1.2
1.04
0.96
0.93

0.91
0.73










Qualifier























ITEF
ITEF
Client Information
Project Name:
Sample ID:

Laboratory Information

Project Hfc
Sample H>:
Texas Lime Kfln
M24-I-4
L1072
1072-4'*
Sample Information

Mafrix:
Weight/ Volume:
Moistare / Lipids:
Analysis 1
                                                Air
                                                 1
                                                0.0    %
                         Initial 0al:
                             -071798

                                                                                           109
                                         1/2

-------
                                            Paradigm Analytical Labs
    Analytical Data Summary Sheet
Labeled
Standard
Extraction Standards
13C12-2,3,7,8-TCDD
& -, * ^'VSiSsHijLi^njft*"'1 y
VrjJ" * >**|f^^^P*'^i~**'**'"*^"
13C12-l,2,3,6,7,8-HxCDD

13C12-OCDD
13Cir2,3,7,8-TCDF 1
13C12-l,2,3,7,8-PeCDF
13Cirl^,3,6J7,8-HxO>F
l3C12-l,2,3,4,6,7,8-HpCDF
Sampling Standards
37Cl4-2,3)7,8-TCDD
13C12-2,3,4,7,8-PeCDF
l3C,2-l,2,3,4,7,8-HxCDD
13C12- 1 ,2,3 ,4,7,8-HxCDF
13C,2-l,2,3,4,7,8,9-HpCDF
Injection Standards
^C,rlA3,4-TCDD
13C12-l,2,3,7,8,9-HxCDD
Expected
Anin$$H;-- |

4
" * **S80S3i* **"*£
* ^^^^^^^^^"^
4

8
4 ' ~
4
4
4

4
4
4
4
4



Measured
*^1

3.47
"'^^^^^^^B
^^^CTJ^^^P
3.37
%
6.74
3.29
2.93
•''3^i •'
3.19

3.97
3.99
4.23
' 3.85
3.80

--' -:

?i^tapccjBt -^
l^eryi

86.7
-M&^&Kt&lit vA,' >i' -;^j*;

84.2

84.3
~ -^£->S/
73.1
:;;«82.7
79.8

99.2
99.7
105.9
96.3
95.1

]-b

RT
OniB.)

28:26
*'-y&i&iZ~*'^'
^^^f^M»PP^' ; ^
34:44

40:00
'"2lt24, •: '
31:56
34:14
36:20

28:26
32:24
34:41
34:09
37:30

28:09
34:58
^sqp^- •?;


0.78
F' 1 jf f
!-. _l;So
1. 25

0.89
6:78
1.56
0.52
0.44


1.55
1. 24
0.5 1
0.44

0.79
1. 24
Qualifier





















Client Information

Project Name:
Sample ID:

Laboratory Information

Project ID:
Sample ED:

Collection Date:
Receipt Date:
Extraction Date:  ^%
Analysis Date:
  v  t-« >'
"  f
Texas Lime Kiln
M24-I-4
L1072
1072-4::
Ol-Jul-98
                      Sample Information

                      Matrix:
                      We^ht/Volume:
                      Moisture / Lipids:
                         Filename:
                         Retchk:
                                                 Ak
                                                  1
                                                 0.0
a20jul98b-lO
a20ju!98b-l
a20ju!98l>2
                                                                  110
                212

-------
O. aan 21-JUL-1998
Filename a20ju!98b
Sample 10
Acquired 21-JUL-98 04
Processed 21-JUL-98 13
Sample ID 1072-4 xl/2
Page 1


:02:53
:46:03






















£&


& ~ \ ^.
dL^'1'

•j
V

<*









Cal Table m8290-23-071798 qjt* ' (J
Results Table M8290-23-072098B
Comments
Typ
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
ES/RT
ES
ES
ES
ES
ES/RT
ES
ES
ES
JS
JS
CS
CS
CS
CS
CS
SS
ss
ss
ss
ss
Name ;
2,3,7,8-TCDD; 3
1,2,3,7,8-PeCDD; 2
1,2,3,4,7,8-HxCDD;
1,2,3, 6,7, 8-HxCDD; 4
1,2,3,7,8,9-HxCDD; 7
1,2,3,4,6,7,8-HpCDD; 2
OCDD; 6
2,3,7,8-TCDF; 2
1,2,3,7,8-PeCDF; 1
2,3,4,7,8-PeCDF; 1
1,2,3,4,7,8-HxCDF; 1
1,2,3,6,7,8-HxCDF; 6
2,3,4,6,7,8-HxCDF; 5
1 , 2 , 3 , 7 , 8 , 9-HxCDF;
1,2,3,4,6,7,8-HpCDF; 2
1,2,3,4,7,8,9-HpCDF;
OCDF; 1
13C-2,3,7,8-TCDD; 3
13C-l,2,3,7,8-PeCDD; 2
13C-l,2,3,6,7,8-HxCDD; 2
13C-1,2,3,4, 6,7,8-HpCDD; 2
13C-OCDD; 3
13C-2,3,7,8-TCDF; 4
13C-l,2,3,7,8-PeCDF; 3
13C-l,2,3,6,7,8-HxCDF; 3
13C-l,2,3,4,6,7,8-HpCDF; 1
13C-1,2,3,4-TCDD; 3
13C-l,2,3,7,8,9-HxCDD; 3
37Cl-2,3,7,8-TCDD; 3
13C-2,3,4,7,8-PeCDF; 3
13C-l,2,3,4,7,8-HxCDD; 2
13C-l,2,3,4,7,8-HxCDF; 2
13C-l,2,3,4,7,8,9-HpCDF; 1
37Cl-2,3,7,8-TCDD; 3
13C-2,3,4,7,8-PeCDF; 3
13C-l,2,3,4,7,8-HxCDD; 2
13C-l,2,3,4,7,8-HxCDF; 2
13C-l,2,3,4,7,8,9-HpCDF; 1


Resp;
.15e+05;
.70e+04;
* .
.87e+04;
.28e+04;
.55e+05;
.286+05;
.15e+06;
.64e+05;
.48e+05;
.17e+05;
.76e+04;
.66e+04;
* .
.09e+05;
* .
.13e+05;
.72e+08;
.49e+08;
.88e+08;
. 27e+08;
.43e+08;
.42e+08;
.43e+08;
.25e+08;
.91e+08;
. 91e+08;
.17e+08;
.38e+08;
.34e+08;
.Ole+08;
.46e+08;
.42e+08;
.38e+08;
. 34e+08;
.Ole+08;
.46e+08;
.42e+08;

Ion 1;
4.62e+04;
1.75e+04;
* .
3.14e+04;
5.156+04;
1.30e+05;
2.95e+05;
9.09e+05;
9.996+04;
8.096+04;
5.986+04;
3.32e+04;
2.73e+04;
* .
9.99e+04;
* .
4.776+04;
1.63e+08;
1.52e+08;
1.60e+08;
1.16e+08;
1.62e+08;
1.94e+08;
2.09e+08;
1.12e+08;
5.83e+07;
1.72e+08;
1.75e+08;
3.38e+08;
2.03e+08;
l.lle+08;
8.32e+07;
4.33e+07;
3.38e+08;
2.03e+08;
l.lle+08;
8.32e+07;
4.33e+07;

Ion 2;
2.696+05;
9.50e+03;
* .
1.736+04;
2.13e+04;
1.25e+05;
3.33e+05;
1.24e+06;
6.38e+04;
6.726+04;
5.75e+04;
3.44e+04;
2.94e+04;
* .
1.096+05;
* .
6.50e+04;
2.09e+08;
9.71e+07;
1.28e+08;
l.lle+08;
1.81e+08;
2.48e+08;
1.34e+08;
2.14e+08;
1.32e+08;
2.19e+08;
1.42e+08;

1.31e+08;
8.96e+07;
1.63e+08;
9.86e+07;
_;
1.316+08;
8.96e+07;
1.63e+08;
9.86e+07;


0
1

1
2
1
0
0
1
1
1
0
0

0

0
0
1
1
1
0
0
1
0
0
0
1

1
1
0
0

1
1
0
0

RA;?; RT;
.17;n; 28:26;
.84;n; 32:36;
*;n;NotFnd;
.82;n; 34:46;
.41;n; 34:58;
.03;y; 37:09;
.89;y; 40:01;
.73;y; 27:26;
.57,-y; 31:56;
.20;n; 32:24;
.04;n; 34:10;
.96;n; 34:15;
.93,-n; 34:37;
*;n;NotFnd;
.91;y; 36:21;
*;n;NotPnd;
.73;n; 40:10;
.78;y; 28:26;
.56;y; 32:36;
.25;y; 34:44;
.05;y; 37:09;
.89;y; 40:00;
.78;y; 27:24;
.56;y; 31:56;
.52,-y; 34:14;
.44;y; 36:20;
. 79 ;y; 28:09;
.24;y; 34:58;
-;-; 28:26;
.55;y; 32:24;
.24;y; 34:41;
.51;y; 34:09;
.44;y; 37:30;
-;-; 28:26;
. 55; y; 32:24;
.24;y; 34:41;
.51;y; 34:09;
.44;y; 37:30;

Cone ;
0.086;
0.010;
* .
0.019;
0.029;
0.125;
0.365;
0.510;
0.055;
0.048;
0.042;
0.019;
0.019;
* .
0.087;
* .
0.062;
86.715;
83.332;
84.139;
90.025;
168.526;
82.136;
73.125;
82.701;
79.763;
81.036;
80.047;
85.941;
72.861;
88.971;
80.230;
75.802;
99.162;
99.673;
105.840;
96.256;
95.067;

DL;
0.0113;
0.0090;
0.0144;
0.0104;
0.0106;
0.0095;
0.0128;
0.0117;
0.0097;
0.0094;
0.0117;
0.0091;
0.0106;
0.0122;
0.0179;
0.0217;
0.0202;
0.0396;
0.0241;
0.0375;
0.0183;
0.0187;
0.0225;
0.0093;
0.1868;
0.1361;
„.
-;
0.0141;
0.0095;
0.0569;
0.2396;
0.1740;
0.0168;
0.0080;
0.0617;
0.2398;
0.2526;

S/N1;?;
8;y;
3;y;
*;n;
5;y;
8;y;
37 ;y;
81;y;
81;y;
36,-y;
32 ;y;
7;y;
4;y;
3;y;
*;n;

*;n;
15,-y;
3981;y;
17660;y;
6479;y;
9696;y;
14504;y;
9726;y;
47570;y;
1452 ;y;
1137;y;
4322;y;
6649;y;
17907;y;
50467;y;
5807;y;
1122,-y;
737;y;
17907;y;
50467;y;
5807,-y;
1122 ;y;
737 ;y;

S/N2;?
39;y
4;y
*;n
4;y
4;y
45, -y
102, -y
108 ;y
7;y
10, -y
10 ;y
7;y
5;y
*;n
25, -y
*;n
9;y
12119;y
16048;y
8821;y
13667,-y
20450;y
12080;y
29562;y
1670, -y
1783;y
13094;y
8704 ;y
_ • _
31056;y
7623, -y
1389;y
1166;y
-; -
31056;y
7623, -y
1389;y
1166, -y
mod?
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
Page l!

-------
OPUSguan   21-JUL-1998
                                      Page 1
                                                                    Page 1  of  8

 Ent: 39 Name: Total Tetra-Furans  P:l  Mass:  303.902 305.899 Mod?  no    tHom:20

 Run: 15 File: a20ju!98b    S:10 Acq:21-JUL-98 04:02:53 Proc:21-JUL-98  13:46:03
 Tables: Run: a20ju!98b  Analyte: m8290-23-»  Cal:  m8290-23-»Results: M8290-23»
 Version: V3.5 17-APR-1997 11:14:34  Sample text:  1072-4 xl/2
   Amount: 4.01
     Cone: 4.01
   Tox #1: -
Name
 2,3,7,8-TCDF
of which 0.51
of which 0.51
     Tox #2:  -

#     RT Respnse
named and 3.50
named and 3.50
      Tox #3: -
                                        RA
1  23:39 7.6e+05   0.75  y
         7.6e+05

2  24:13 4.2e+05   0.71  y
         4.2e+05

3  24:32 7.0e+05   0.74  y
         7.0e+05

4  24:51 l.Se+06   0.74  y
         l.Se+06

5  24:58 1.7e+05   0.74  y
         1.7e+05

6  25:00 2.2e+05   0.78  y
         2.2e+05

7  25:17 1.46+06   0.49  n
         1.4e+06

8  25:44 3.1e+06   0.76  y
         3.1e+06

9  26:01 2.6e+05   0.87  y
         2.6e+05

10 26:08 5.8e+05   0.78  y
         5.86+05

11 26:25 7.16+05   0.73  y
         7.1e+05

12 26:32 5.5e+05   0.71  y
         5.5e+05

13 26:50 1.5e+06   0.77  y
         1.5e+06

14 26:59 2.0e+04   0.45  n
         2.0e+04

15 27:10 1.2e+06  0.76 y
         1.2e+06

16 27:26 2.1e+06  0.73  y
         2.1e+06

17 28:02 l.le+06  0.74 y
         l.le+06

18 28:19 5.0e+05  0.67 y
         5.0e+05

19 28:32 2.7e+04  0.48 n
         2.7e+04
                                              Cone

                                               0.18
                                                   3
                                                   4
                                               0.10
                                                   ]

                                               0.17

                                                   4
                                               0.35
                                                   e
                                                   £
                                               0.04

                                                   c
                                               0.05
                                                   S
                                                   ]
                                               0.32
                                                   4
                                                   c
                                               0.73
   unnamed
   unnamed
                  Area  Height    S/N  Mod?
               3.3e+05 6.9e+04 4.0e+01 y  n
               4.3e+05 9.5e+04 5.5e+01 y  n

                .7e+05 3.7e+04 2.2e+01 y  n
               2.4e+05 5.2e+04 3.0e+01 y  n
              7
               3.0e+05 6.6e+04 3.9e+01 y  n
                .0e+05 8.2e+04 4.8e+01 y  n

               6.3e+05 1.2e+05 7.2e+01 y  n
               8.5e+05 1.7e+05 l.Oe+02 y  n
              I
               7.3e+04 2.5e+04 1.5e+01 y  n
               9.9e+04 3.1e+04 1.8e+01 y  n
               9.7e+04 2.4e+04 1.4e+01 y  n
               1.2e+05 3.3e+04 1.9e+01 y  n

                .56+05 6.4e+04 3.8e+01 y  n
               9.16+05 8.6e+04 5.0e+01 y  n
                                               0.06
                                               0.14
                                               0.17
                                               0.13
                                               0.34
                                               0.00
               1.36+06 2.4e+05 1.4e+02 y  n
               1.7e+06 3.2e+05 1.9e+02 y  n

               1.26+05 2.6e+04 1.5e+01 y  n
               1.4e+05 3.3e+04 1.9e+01 y  n
               i
               2.56+05 4.9e+04 2.9e+01 y  n
               3.2e+05 6.9e+04 4.06+01 y  n
               7
               3.0e+05 6.1e+04 3.6e+01 y  n
               4.1e+05 7.56+04 4.4e+01 y  n
               3
               2.36+05 4.1e+04 2.4e+01 y  n
               3.2e+05 5.76+04 3.4e+01 y  n
               i
               6.36+05 1.3e+05 7.6e+01 y  n
               8.26+05 1.76+05 9.9e+01 y  n
                                               0.28
            0.51
                                               0.26
                                               0.12
                                               0.01
 6.2e+03  2.4e+03  1.4e+00  n  n
 1.46+04  4.3e+03  2.5e+00  n  n
3
 5.1e+05  l.Oe+05  6.1e+01  y  n
 6.8e+05  1.4e+05  8.1e+01  y  n
L
 9.1e+05  1.4e+05  8.1e+01  y  n
 1.2e+06  1.9e+05  l.le+02  y  n
5
 4.7e+05  9.7e+04  5.7e+01  y  n
 6.4e+05  1.3e+05  7.8e+01  y  n
2
 2.0e+05  3.66+04  2.1e+01  y  n
 3.0e+05  5.26+04  3.0e+01  y  n
I
 8.8e+03  3.4e+03  2.0e+00  n  n
 1.86+04  4.2e+03  2.4e+00  n  n
                                                                                                      112

-------
OPUSguan  21-JUL-1998               Page  2
                  20 29:48 1.7e+05  0.84 y    0.04
                          1.7e+05               8.0e+04  1.5e+04 8.6e+00 y n
                                                9.4e+04  1.7e+04 l.Oe+01 y n
                                                                                                  113

-------
OPUSquan   21-JUL-1998
                   Page 3
                                                                    Page  2  of  8

 Ent: 40 Name: Total Tetra-Dioxins F:l  Mass:  319.897  321.894  Mod? no   #Hom:10

 Run: 15 File: a20ju!98b    S:10 Acq:21-JUL-98 04:02:53  Proc:21-JUL-98  13:46:03
 Tables: Run: a20ju!98b  Analyte: m8290-23-»  Cal:  m8290-23-»Results: M8290-23»
 Version: V3.5 17-APR-1997 11:14:34  Sample text:  1072-4 xl/2
   Amount: 0.34
     Cone: 0.34
   Tox #1: -
Name
of which 0.09
of which 0.09
     Tox #2: -

#     RT Respnse
named and 0.25
named and 0.25
      Tox #3:  -
                                        RA
                   1  25:15 3.9e+05  0.80 y
                            3.9e+05

                   2  25:40 1.8e+05  0.67 y
                            1.8e+05

                   3  26:02 4.2e+04  0.82 y
                            4.2e+04

                   4  26:52 1.2e+05  0.66 y
                            1.2e+05
                      27:14 l.Se+04
                            1.5e+04
                                     0.40 n
                      27:23 8.36+04  5.96 n
                            8.36+04
                      27:45 2.46+04
                            2.4e+04
                                     0.94 n
2,3,7,8-TCDD
8  28:09 5.3e+04  0.45 n
         5.3e+04

9  28:26 3.1e+05  0.17 n
         3.1e+05
          Cone

           0.11
               ]

           0.05
               'i
               ]
           0.01
               ]

           0.03
               4

           0.00
               4
               ]
           0.02

               ]
           0.01
               ]
               3
           0.01
               1

           0.09
unnamed
unnamed
                                                      Area  Height    S/N  Mod?
                                 .7e+05  3.7e+04  2.6e+01  y  n
                                2.1e+05  4.3e+04  3.2e+01  y  n

                                 .3e+04  1.6e+04  l.le+01  y  n
                                 .le+05  2.3e+04  1.7e+01  y  n

                                 .9e+04  3.9e+03  2.7e+00  n  n
                                2.36+04  4.2e+03  3.1e+00  y  n
                               3
                                4.7e+04  9.2e+03  6.4e+00  y  n
                                7.16+04  1.26+04  9.16+00  y  n
                               0
                                4.36+03  1.7e+03  1.2e+00  n  n
                                l.le+04  3.4e+03  2.5e+00  n  n

                                7.1e+04  1.7e+04  1.2e+01  y  n
                                1.26+04  3.26+03  2.3e+00  n  n

                                1.2e+04  3.0e+03  2-le+OO  n  n
                                1.2e+04  2.8e+03  2.0e+00  n  n
                                                   1.7e+04 4.3e+03 3.0e+00 n  n
                                                   3.7e+04 8.3e+03 6.1e+00 y  n
                   10 28:39 1.3e+04
                            1.3e+04
                                     1.15 n
                                               0.00
                                4.6e+04 l.le+04 7.7e+00 y  n
                                2.7e+05 5.36+04 3.9e+01 y  n
                               3
                                6.7e+03 l.le+03 8.0e-01 n  n
                                5.9e+03 2.1e+03 1.5e+00 n  n
                                                                    Page 3 of 8

 Ent: 41 Name: Total Penta-Furans  F:2  Mass: 339.860 341.857 Mod? no   #Hom:10

 Run: 15 File: a20ju!98b    S:10 Acq:21-JUL-98 04:02:53 Proc:21-JUL-98 13:46:03
 Tables: Run: a20ju!98b  Analyte: m8290-23-»  Cal: m8290-23-»Results: M8290-23*
 Version: V3.5 17-APR-1997 11:14:34  Sample text: 1072-4 xl/2
    Amount:  0.55
      Cone:  0.55
    TOX #1:  -
of which 0.10
of which 0.10
     Tox #2: -
named and 0.45
named and 0.45
      Tox #3: -
 Name
                         RT Respnse

                       30:15 2.0e+05
                            2.0e+05
                     RA

                  2.14 n
                    2   31:21  6.4e+05   1.66 y
                             6.4e+05

                    3   31:29  9.96+04   1.54 y
                             9.9e+04
                       31:45  1.2e+05
                             1.2e+05
                                      1.85 n
          Cone

           0.06
               1
               6
           0.21
               4

           0.03
               (

           0.04
 unnamed
 unnamed
 Area   Height     S/N  Mod?
                                1.3e+05 2.9e+04 3.4e+01 y  n
                                6.3e+04 1.3e+04 5.5e+00 y  n
                               1
                                4.0e+05 l.le+05 1.3e+02 y  n
                                2.4e+05 6.4e+04 2.6e+01 y  n

                                6.0e+04 1.6e+04 1.9e+01 y  n
                                3.96+04 1.26+04 4.86+00 y  n
                               1
                                7.96+04 2.1e+04 2.56+01 y  n
                                                                                                       114

-------
OPUSquan   21-JUL-1998
                                      Page 4
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
5  31:56 1.6e+05  1.57  y    0.05
         1.66+05

6  32:03 8.4e+04  1.70  y    0.03
         8.4e+04

7  32:08 l.le+05  1.39  y    0.04
         l.le+05

8  32:24 1.5e+05  1.20  n    0.05
         1.5e+05

9  32:29 9.9e+04  1.36  y    0.03
         9.9e+04

10 32:37 9.6e+03  2.24  n    0.00
         9.6e+03
                                                  4.3e+04 l.le+04 4.7e+00 y  n
l.Oe+05 3.0e+04 3.6e+01 y  n
6.4e+04 1.8e+04 7.2e+00 y  n

5.3e+04 1.9e+04 2.2e+01 y  n
3.1e+04 1.2e+04 4.8e+00 y  n

6.4e+04 2.2e+04 2.6e+01 y  n
4.6e+04 1.5e+04 6.0e+00 y  n

8.1e+04 2.7e+04 3.2e+01 y  n
6.7e+04 2.36+04 9.6e+00 y  n

5.7e+04 2.06+04 2.4e+01 y  n
4.26+04 1.6e+04 6.3e+00 y  n

6.6e+03 1.8e+03 2.1e+00 n  n
2.96+03 1.4e+03 5.8e-01 n  n
                                                                                                    115

-------
OPUSquan   21-JUL-1998
                   Page  5
                                                                    Page 4  of  8

 Ent: 42 Name: Total Penta-Dioxins F:2  Mass:  355.855 357.852 Mod? no   tHom:9

 Run: 15 File: a20ju!98b    S:10 Acq:21-JUL-98 04:02:53 Proc:21-JUL-98  13:46:03
 Tables: Run: a20ju!98b  Analyte: m8290-23-»  Cal:  m8290-23-»Results: M8290-23*
 Version: V3.5 17-APR-1997 11:14:34  Sample text:  1072-4 xl/2
   Amount: 0.14
     Cone: 0.14
   Tox #1: -
Name
of which 0.01
of which 0.01
     Tox #2:  -

#     RT Respnse
named and 0.13
named and 0.13
      Tox #3:  -
                                        RA
                   1  31:29 1.66+05  1.32 n
                            1.6e+05

                   2  31:48 4.1e+04  1,. 42 y
                            4.1e+04
                      31:56 6.4e+04
                            6.4e+04
                                     3.13 n
1,2,3,7,8-PeCDD
4  32:04 l.le+04  1.33 y
         l.le+04

5  32:24 5.56+04  3.49 n
         5.56+04

6  32:30 7.6e+03  2.42 n
         7.6e+03

7  32:36 2.7e+04  1.84 n
         2.7e+04

8  33:05 1.2e+04  1.54 y
         1.2e+04
          Cone

           0.06
               6
               e
           0.01

               1
           0.02
               4
               ]
           0.00
               e
               4
           0.02
               4
               ]
           0.00
               R
               2
           0.01
               1
               s
           0.00
    unnamed
    unnamed
                                                      Area  Height    S/N  Mod?
 8.8e+04 2.7e+04  1.5e+01  y  n
 6.7e+04 2.0e+04  2.1e+01  y  n
L
 2.4e+04 9.2e+03  4.9e+00  y  n
 1.7e+04 5.9e+03  6.1e+00  y  n

  .9e+04 1.2e+04  6.2e+00  y  n
  .6e+04 5.9e+03  6.0e+00  y  n

 6.3e+03 2.4e+03  1.3e+00  n  n
 4.7e+03 1.7e+03  1.8e+00  n  n

  .3e+04 1.5e+04  8.2e+00  y  n
  .2e+04 3.1e+03  3.2e+00  y  n
 5.4e+03 2.3e+03 1.2e+00 n  n
 2.2e+03 8.6e+02 8.9e-01 n  n
L
 1.8e+04 6.0e+03 3.2e+00 y  n
 9.5e+03 4.06+03 4.1e+00 y  n
                      33:07 6.26+03
                            6.2e+03
                                     2.02 n
                            0.00
               7.46+03 2.7e+03 1.4e+00 n  n
               4.8e+03 1.6e+03 1.6e+00 n  n
              3
               4.1e+03 1.8e+03 9.5e-01 n  n
               2.06+03 7.5e+02 7.7e-01 n  n
 Ent: 43 Name: Total Hexa-Furans
                                                 Page 5 of 8

                F:3  Mass:  373.821 375.818 Mod? no   #Hom:ll
 Run: 15 File: a20ju!98b    S:10 Acq:21-JUL-98 04:02:53 Proc:21-JUL-98 13:46:03
 Tables: Run: a20ju!98b  Analyte: m8290-23-»  Cal: m8290-23-»Results:  M8290-23»
 Version: V3.5 17-APR-1997 11:14:34  Sample text: 1072-4 xl/2
   Amount:  0.20
     Cone:  0.20
   Tox  #1:  -
 Name
of which 0.08
of which 0.08
     Tox #2: -

#     RT Respnse
named and 0.12
named and 0.12
      Tox #3: -
                                        RA
                    1   33:31 5.66+04  0.92 n
                            5.6e+04

                    2   33:37 1.4e+05  1.25 y
                            1.4e+05

                    3   33:43 l.Oe+04  1.02 n
                            l.Oe+04

                    4   33:48 1.2e+04  1.08 y
                            1.26+04

                    5   33:55 9.0e+04  1.12 y
                            9.0e+04
          Cone

           0.02


           0.05
               1
               e
           0.00
               c
               c
           0.00
               e
               «
           0.03
    unnamed
    unnamed
                                                      Area  Height
                                  S/N  Mod?
                                2.7e+04 l.Oe+04 3.6e+00 y  n
                                2.9e+04 l.Oe+04 6.0e+00 y  n

                                7.7e+04 2.7e+04 9.4e+00 y  n
                                6.2e+04 2.3e+04 1.3e+01 y  n
                               D
                                5.0e+03 1.9e+03 6.6e-01 n  n
                                5.0e+03 1.8e+03 l.le+00 n  n
                               3
                                6.5e+03 2.5e+03 8.5e-01 n  n
                                6.0e+03 2.4e+03 1.4e+00 n  n

                                4.8e+04 1.6e+04 5.4e+00 y  n
                                                                                                 r(    116

-------
OPUSquan   21-JUL-1998
Page 6
                   6  34:01 9.4e+03   2.18  n     0.00
                            9.4e+03

1,2,3,4,7,8-HxCDF  7  34:10 1.2e+05   1.04  n     0.04
                            1.2e+05

1,2,3,6,7,8-HxCDF  8  34:15 6.8e+04   0.96  n     0.02
                            6.8e+04

                   9  34:19 l.Oe+04   0.80  n     0.00
                            l.Oe+04

                   10 34:27 2.3e+04   0.90  n     0.01
                            2.3e+04

2,3,4,6,7,8-HxCDF  11 34:37 5.7e+04   0.93  n     0.02
                            5.7e+04
                                                  4.2e+04 1.6e+04 9.16+00 y  n
             6.4e+03
             2.9e+03
            i
             6.0e+04
             5.8e+04
            2
             3.3e+04
             3.4e+04
            D
             4.6e+03
             5.8e+03
            L
             l.le+04
             1.2e+04
            2
             2.7e+04
             2.9e+04
1.9e+03
9.66+02

2.Oe+04
1.7e+04

1.2e+04
1.2e+04

2.1e+03
2.46+03

3.16+03
2.76+03

9.56+03
7.9e+03
6.5e-01 n  n
5.6e-01 n  n

6.8e+00 y  n
l.Oe+01 y  n

4.3e+00 y  n
6.7e+00 y  n

7.2e-01 n  n
1.4e+00 n  n

l.le+00 n  n
1.6e+00 n  n

3.3e+00 y  n
4.6e+00 y  n
                                                                                              C     117

-------
OPUSquan   21-JUL-1998
                   Page 7
                                                                    Page 6 of 8

 Ent: 44 Name: Total Hexa-Dioxins  F:3  Mass: 389.816 391.813 Mod? no   fHozn:14

 Run: 15 File: a20ju!98b    S:10 Acq:21-JUL-98 04:02:53 Proc:21-JUL-98  13:46:03
 Tables: Run: a20ju!98b  Analyte: m8290-23-»  Cal:  m8290-23-»Results: M8290-23*
 Version: V3.5 17-APR-1997 11:14:34  Sample text:  1072-4 xl/2
   Amount: 0.35
     Cone: 0.35
   Tox #1: -
of which 0.05
of which 0.05
     Tox #2:  -
named and 0.31
named and 0.31
      Tox #3: -
Name
                   #
                         RT Respnse
                                        RA
                   1  33:52 2.7e+05  1.19 y
                            2.7e+05
                   2  34:04 7.6e+03
                            7.6e+03
                  3.33 n
                   3  34:10 1.36+05  1.77 n
                            1.3e+05

                   4  34:14 7.56+04  4.89 n
                            7.5e+04

                   5  34:19 l.Se+05  1.20 y
                            1.5e+05

                   6  34:25 2.1e+04  1.97 n
                            2.1e+04

                   7  34:32 9.7e+03  2.46 n
                            9.7e+03

                   8  34:34 5.1e+03  0.82 n
                            S.le+03
1,2,3,6,7,8-HxCDD  9
   34:46 4.9e+04  1.82 n
         4.96+04
1,2,3,7,8,9-HxCDD  10 34:58 7.36+04  2.41 n
                            7.3e+04

                   11 35:07 l.Oe+04  0.30 n
                            l.Oe+04
          Cone

           0.12
               1
               1
           0.00
               c
               1
           0.06
               8
               4
           0.03
               €
               1
           0.07
               £
               e
           0.01
               1
               1
           0.00
               (.

           0.00


           0.02

               ]
           0.03
    unnamed
    unnamed
                                   Area  Height     S/N  Mod?
 1.5e+05  4.7e+04  2.7e+01 y  n
 1.2e+05  4.1e+04  2.4e+01 y  n
D
 5.8e+03  2.3e+03  1.3e+00 n  n
 1.8e+03  7.8e+02  4.6e-01 n  n
5
 8.1e+04  2.8e+04  1.6e+01 y  n
 4.6e+04  1.6e+04  9.2e+00 y  n
3
 6.2e+04  1.8e+04  l.le+01 y  n
 1.3e+04  4.3e+03  2.5e+00 n  n
7
 8.2e+04  2.76+04  1.6e+01 y  n
 6.9e+04  2.1e+04  1.3e+01 y  n
L
 1.4e+04  3.4e+03  2.0e+00 n  n
 7.2e+03  2.7e+03  1.6e+00 n  n

 6.9e+03  2.8e+03  1.6e+00 n  n
 2.8e+03  7.46+02  4.46-01 n  n
0
 2.36+03  l.le+03  6.1e-01 n  n
 2.86+03  7.46+02  4.4e-01 n  n
2
 3.16+04  9.16+03  5.2e+00 y  n
  .7e+04  6.1e+03  3.6e+00 y  n
                    12  35:16 l.le+04
                            l.le+04
                                     3.21 n
                    13  35:33  6.1e+03  0.84 n
                             6.1e+03

                    14  35:37  6.66+03  4.46 n
                             6.66+03
                            0.00
                                               0.00
                                               0.00
               5.1e+04 1.4e+04 8.0e+00 y  n
               2.16+04 7.36+03 4.3e+00 y  n
               3
               2.36+03 9.6e+02 5.6e-01 n  n
               7.7e+03 1.7e+03 9.96-01 n  n
               D
               8.3e+03 2.0e+03 1.2e+00 n  n
               2.6e+03 9.06+02 5.3e-01 n  n
               D
               2.8e+03 1.26+03 6.9e-01 n  n
               3.3e+03 l.Oe+03 6.0e-01 n  n
                            0.00
                                                   5.4e+03 1.6e+03 9.5e-01 n  n
                                                   1.2e+03 6.0e+02 3.5e-01 n  n
                                                                    Page 7 of  8

  Ent:  45 Name:  Total  Hepta-Furans  F:4  Mass: 407.782  409.779 Mod? no   #Hom:2

  Run:  15 File:  a20ju!98b    S:10 Acg:21-JUL-98  04:02:53 Proc:21-JUL-98  13:46:03
  Tables: Run:  a20ju!98b Analyte: m8290-23-»  Cal: m8290-23-»Results: M8290-23»
  Version:  V3.5 17-APR-1997  11:14:34   Sample text: 1072-4 xl/2
    Amount:  0.11
      Cone:  0.11
    Tox #1:  -
 Name
of which 0.09
of which 0.09
     Tox #2: -

f     RT Respnse
 named and  0.02    unnamed
 named and  0.02    unnamed
       Tox  #3: -
                                         RA
                                              Cone    Area  Height     S/N  Mod?
                                                                                                       118

-------
OPUSquan   21-JUL-1998
                   Page 8
1,2,3,4,6,7,8-HpCDFl  36:21 2.1e+05  0.91  y    0.09
                            2.1e+05

                   2  36:39 4.4e+04  0.50  n .   0.02
                            4.4e+04
                                l.Oe+05  3.2e+04 l.le+01 y  n
                                l.le+05  3.6e+04 2.5e+01 y  n
                               2
                                1.5e+04  6.6e+03 2.2e+00 n  n
                                2.9e+04  7.9e+03 5.4e+00 y  n
                                                                   Page 8 of 8

 Ent: 46 Name:  Total Hepta-Dioxins F:4  Mass:  423.777  425.774 Mod? no   #Hom:4

 Run: 15 File:  a20ju!98b    S:10 Acq:21-JUL-98 04:02:53  Proc:21-JUL-98 13:46:03
 Tables: Run:  a20ju!98b  Analyte:  m8290-23-»   Cal: m8290-23-»Results: M8290-23»
 Version: V3.5  17-APR-1997 11:14:34  Sample text:  1072-4 xl/2
   Amount:  0.29
     Cone:  0.29
   Tox #1:  -
Name
of which 0.13
of which 0.13
     Tox #2:  -

#     RT Respnse
named and 0.16
named and 0.16
      Tox #3:  -
                                        RA
                   1  36:20 6.8e+04  3.82  n
                            6.8e+04

                   2  36:35 2.2e+05  1.04  y
                            2.2e+05

l,2,3,4,6,7,8-HpCDD3  37:09 2.6e+05  1.03  y
                            2.6e+05

                   4  37:30 4.1e+04  2.41  n
                            4.1e+04
          Cone

           0.03
               C
               1
           0.11
               1
               ]
           0.13
               ]
               ]
           0.02
unnamed
unnamed
                                                     Area  Height
                                  S/N  Mod?
                                5.4e+04  1.8e+04  1.9e+01 y  n
                                1.4e+04  5.3e+03  6.5e+00 y  n
                               1
                                l.le+05  3.7e+04  3.8e+01 y  n
                                l.le+05  3.6e+04  4.5e+01 y  n

                                 .3e+05  3.5e+04  3.7e+01 y  n
                                 .3e+05  3.6e+04  4.5e+01 y  n

                                2.9e+04  9.6e+03  l.Oe+01 y  n
                                1.2e+04  3.6e+03  4.5e+00 y  n
                                                                                                       119

-------
File: A20JUL98B Acq:
21-JUL-1998 04:
02:53 Exp: EXP_M23_
DB5_OVATION Voltage SIR EI + GC Autospec-UltimaE Paradigm
Sample #10 Text: 1072-4 xl/2 ALS #11
319.8965 S:10 SMO(1,3)
iooa
50 1
o-


-— . .--»—
24100
321.8936 S:10 SMO(1,3)
100%.

50 j
0:



	 24 loo'
331.9368 S:10 SMO(1,3)
100%
50 1
Q-



	 24 loo'
333.9339 S:10 SMO(1,3)
100%
50J
o:



24:00
327.8847 S:10 SMO(1,3)
100%
50J
•
0 "




	 24 loo'
316.9824 S:10 SMO(1,3)
BSUB(128,15,-3.0) PKD(3 , 3 , 3 , 0 . 10%,
Al

•—^ -^-^-^
25:00
BSUB(128,15,-3

A2


25 100
BSUB(128,15,-3



25 100
BSUB(128,15,-3



25:00
BSUB(128,15,-3




— i 	 1 	 1 	 1 	 1 	 1
25:00
PKD(3,3,3,100.
100%, 23:30 24:05 24:3424:54
50J
OJ





25:00
.71E5
A
M A7.29E4
/ \ A A1.88E4
z__l_^_/__^^_/\ —
26 loo'
.0) PKD(3,3,3,0.10%,

.15E5
A1.09E5
A A2.30E4
•* *- S — \
26 loo'
.0) PKD(3,3,3,0.10%,



26 loo'
.0) PKD(3,3,3,0.10%,



26:00
.0) PKD(3,3,3,0.10%,




26:00
00%, 0.0,1. 00%, F,F)
25^36 26:01 26:


26 loo'
1436. 0,1. 00%, F,F)

A7.10E4 ,. ,0_.
A4.67E4 A .. A4|-62E4
/\ l\ A1.66E4A
jsJL^^/^s-^cy^f \ >rv r rJ^^— — A_\ 	 ^ ^^ ff^^^^vl/^j~^
3.9E4
_2.0E4
O.OEO
27 loo' ' ' ' 28 loo 	 29 100 	 3oloO Time
1368. 0,1. 00%, F,F)
A2.69E5 _5.5E4
A

A7.12E4 flo fifiTr4/
/\ _A3..1^9E4 ^ ^'A^ V_ A6.79E3
;
_2.7E4

27100 28loO 29100 3oloO Time
8324. 0,1. 00%, F,F)
A1.72E8
A A
y v / V
3.6E7
L1.8E7
: O.OEO
27 100 	 28 loo' ' 29 1 00 	 30:00 Time
3480. 0,1. 00%, F,F)
A2.19E8
A A
y V / V
4.6E7
L2.3E7
1 O.OEO
27 100 28 100 29 I 00 30:00 Time
3860. 0,1. 00%, F,F)
A3.38E8
A
A
/ \
J v
_6 . 9E7
_3 . 5E7

O.OEO
27 1 00 28 1 00 29iOO 30:00 Time

28 26:59 27:30 28:0928:30 29:04 29:32 5.2E7


_2 . 6E7
O.OEO
27 1 00 	 28 100 29:00 ' 30:00 Time

-------
File
Samp
355.
1008
so:
0"
357.
iooa
50:
0'
367.
100%
so:
0"
369.
1001
so:
0"
: A20JUL98B Acq: 21-JUL-1998 04:02:53 Exp: EXP M23 DB5 OVATION Voltage SIR EI + GC
le #10 Text: 1072-4 xl/2 ALS #11
8546 S:10 F:2 SMO(1,3) BSUB(128, 15, -3 . 0) PKD(3 , 3 , 3 , 0 . 10%, 1876 . 0 , 1 . 00%, F, F)
A8.83E4
A
A4.87E4 A4'27E4
______^___ 	 ^J\^^^^
36112 36124 36136 36148 siloO 3ill2 3il24 3l\36 31 Us ' 32 1 66 ' 32 Il2 ' 32 124 ' 32
8517 S:10 F:2 SMO(1,3) BSUB(128, 15, -3 . 0) PKD(3 , 3 , 3 , 0 . 10%, 972 . 0 , 1 . 00%, F, F)
A6.71E4
/ I A1.55E4
/ \ A A A7'59E3
30:12 30:24 30:36 30:48 31:00 31:12 31:24 31:36 31:48 32100 32ll2 32124 32
8949 S:10 F:2 SMO(1,3) BSUB(128, 15, -3 . 0) PKD(3 , 3 , 3 , 0 . 10%, 2932 . 0 , 1 . 00%, F, F)
Al.
1
361l2 30124 3Q\36 36148 31:00 31112 31124 3ll36 SlUs 32166 32112 32124 32
8919 S:10 F:2 SMO(1,3) BSUB(128, 15 , -3 . 0) PKD(3 , 3 , 3 , 0 . 10%, 2068 . 0 , 1 . 00%, F, F)
A9.
1
3oll2 30124 30136 30148 31:00 31:12 31:24 31:36 31:48 32:00 32:12 32:24 32
366.9792 S:10 F:2 SMO(1,3) PKD(3, 3 , 3 , 100 . 00%, 0 . 0, 1 . 00%, F, F)
lOOi 10-1? 30-30 30:54 31:11 31:33 31:47 32:00 32:12 32:28
so:
. 0"

30:12 30124 30:36 30:48 31:00 31:12 31:24 31:36 31:48 32:00 32:12 32:24 32
Autospec-UltimaE Parad
75E4
136 321481 ' 33166 33ll2
.50E3
/\_ A3.94E3
:36 32:48 33:00 33:12
52E8
136 32148 33166 33112
71E7
igm
2.9E4
_1.5E4
Time
2.2E4
0 OEO
Time
5.2E7
_2 . 6E7
_O.OEO
Time
3.3E7
.1.7E7
_O.OEO
:36 32148 33:00 33:12 Time
32:58 5.0E7

_2 . 5E7
O.OEO
:36 32:48 33:00 33:12 Time

-------
file: A20JUL98B—Acq: 21-JUL-1998 04:02:53Exp: EXP_M23_DB5_OVATION Voltage SIR EI +GC Autospec-UltimaEParadigm
Sample #10  Text: 1072-4 xl/2  ALS #11
389.8156 S:10 F:3 SMO{1,3) BSUB(128,15,-3.0) PKD{3,5,2,0.10%,1732.0,1.00%,F,F)
100%                     A1..45E5                                                                                 ^4.9E4
 50J
          A5.40E3
                                      A8.11E4
                             A5.84
                                                   .42E4
                                                                A3.14E4
                                                                        A5.15E4
                                                                                                                 _2.5E4
                                                                                                                  O.OEO
      33:24    33:36    33:48    34:00    34:12    34:24    34:36    34:48    35:00
391.8127 S:10 F:3 SMO(1,3) BSUB(128,15,-3.0) PKD(3,5,2,0.10%,1704.0,1.00%,F,F)
100%                    A1.22E5
                                                                               35:12    35:24    35:36
 50J
  0.
                                      A4 .57E4
                                             A6.85E4
                               .4.29E3
                                                  7.22E3
                                                               A1.73E4  A2.13E4
                                                                                        A1.61E4
                                                                                                              35:48  Time

                                                                                                                  4.2E4


                                                                                                                 _2.1E4
                                                                                                                  O.OEO
     TT~-i  i
      33:24
                 i
                  i— i — r — i — i — i — i — i — I — i — r
                   33:48    34:00
                                              T
                                                               T
                                                                           35:00
              33i36    33J48    34iOO    34il2    34:24    34:36    34:48
401.8559 S:10 F:3 BSUB(128,15,-3.0) PKD(3,5,2,0.10%,9508.0,1.00%,F,F)
100%                                                          A1.60E8  A1.75E8
 50J
                                                    35:12    35:24    35:36
  o:
35:48  Time

    6.3E7


   L3.2E7
                                                                                                                  O.OEO
     i—i—i—i—i—i—i i  i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i i i—i—i—i—i  i '  ii  ir
      33:24   33:36    33:48    34:00   34:12    34:24    34:36   34:48    35:00
403.8530 S:10 F:3 BSUB(128,15,-3.0)  PKD(3,5,2,0.10%,5756.0,1.00%,F,F)
100%                                                           A1.28E8   A1..42E8
 so:
                                                                                    35!12'   '35:24* ' '35:36
  OJ
                                                                                                         35:48  Time

                                                                                                             5. 1E7


                                                                                                             L2.5E7
                                                                                       .	,	• O.OEO
                                                                                        35:24    35:36    35:48  Time
                                        34! 12'  ' '34:24  '  '34! 36' ' ' 34148'
     1—l—i—i—I—l—i l  l—l  l l l—l—I—l l  l—r—l—|—i—i
      33:24   33:36    33:48    34:00
380.9760 S:10 F:3 SMO(1,3) PKD(3,3,3,100.00%,0.0,1.00%,F,F)
100%   33:25     33:39      33j£3	34:21    34:33   3J^43
 so:
                                                                                35:08 35:16  35:25 35:33
                                                                                                             1.0E8
                                                                                                                 L5.2E7
                                                                                                                  0 . OEO
T — i — ] — i — i
 33:24
             i — l — I — i — I — I — l — i — | — I — I
              33:36    33:48

34:00   34:12    34:24    34:36
                                                                           35 -o    35: 12    35: 24    35: 36    35:48  Time

-------
 File:  A20JUL98BAcq:  21-JUL-1998  04:02:53   Exp:  EXP_M23_DB5_OVATION Voltage SIR EI+—GC Autospec-UltimaE—Paradigm	
 Sample #10   Text:  1072-4 xl/2  ALS #11
 423.7767  S:10  F:4  SMO(1,3)  BSUB(128,15,-3.0)  PKD(3,3,3,0.10%,952.0,1.00%,F,F)
 10°*.                     A1.13E5             A1.30E5                                                             3.8E4
  so:
   oi
                  A5.39E4
                                  A6.04E3
                                                          A2.91E4
                                                                             A5.28E3
                                                                                                                 .1.9E4
                                                                                                                  O.OEO
                                                                                                                  10  Time
       36:00  36:12  36:24  36:36  36148  37!6o  37!l2  37124  37 ! leTT? ! 48 ' iTslod   381:123^l24^ 138^36
425.7737 S:10 F:4 SMO(1,3) BSUB(128,15 ,-3.0) PKD(3,3,3,0.10%,812.0,1.00%,F,F)
100%,                      A1.08E5            A1.25E5
 50_
                  A1.41E4
                                                                                                                 ^3.7E4
                                                                                                                 i_1.9E4
                                                         A1.21E4
                                                                                    .-prTVi'i i i r i i  ifrrr .  i i	i1 O.OEO
                                                                                   38:12  38:24  38:36  38:48  39:00  Time
       36!6d  36112  36124  36136  36:48  37166  37!l2 ' 37I24 ' 37I36 '  37I48 '  3s!
435.8169 S:10 F:4 SMO(1,3) BSUB(128,15,-3.0) PKD(3,3,3,0.10%,3280.0,1. 00%, F, F)
100*                                         A1.16E8
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       36:00  36:12  36:24   36:36  36:48  37:00  37:12  37:24  37:36   37:48   38:00  38:12  38:24  38:36  38:48  39:00  Time
437.8140 S:10 F:4 SMO(1,3)  BSUB(128,15,-3.0) PKD(3,3,3,0.10%,2216.0,1.00%,F,F)
100%,                                         A1.J.1E8                                                              3.0E7
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       36:00   36:12   36:24   36:36  36:48  37:00  37:12  37:24   37:36   37:48  38:00  38:12  38:24  38:36  38:48  39:00  Time
 30.9728 S:10 F:4 SMO(1,3)  PKD(3,3,3,100.00%,0.0,1.00%,F,F)
 00%,	36^23 36:35 36:46    37^01  37:12	      37^:46  37:58	33x1^ 38:28  38;39       	_7 . OE7
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       36:00   36:12  36:24  36:36  36:48  37:00  37:12   37:24  37:36  37:48  38:00  38:12  38:24  38:36  38:48  39:00  Time

-------
file
Samp
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: A20JUL98B Acq: 21-JUL-1998 04:02:53 Exp: EXP_M23_DB5_OVATION Voltage SIR EH- GC Autospec-UltimaE Parad
le #10 Text: 1072-4 xl/2 ALS #11
7377 S:10 F:5 SMO{1,3) BSUB (128, 15, -3 . 0) PKD(3 , 3 , 3 , 0 . 10%, 836 . 0 , 1 . 00%, F, F)
A2 . 95E5
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39:12 39:24 39:36 39:48 40:00 40:12 40:24 40:36 40:48 41
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A3 . 33E5
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39:12 39:24 39:36 39:48 40:00 40:12 40:24 40:36 40:48 41:
7780 S:10 F:5 SMO(1,3) BSUB(128, 15, -3 . 0) PKD(3 , 3 , 3 , 0 . 10%, 2504 . 0, 1 . 00%, F, F)
A1.62E8
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39:12 ' ' 39:24 39:36 39:48 40:00 40:12 40:24 40:36 40:48 41:
7750 S:10 F:5 SMO(1,3) BSUB(128, 15, -3 . 0} PKD(3 , 3 , 3 , 0 . 10%, 2012 . 0, 1 . 00%, F, F)
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)le #10 Text: 1072-4 xl/2 ALS #11
9016 S:10 SMO(1,3) BSUB(128, 15, -3 . 0) PKD (3 , 3 , 3 , 0 . 10%, 1700 . 0 , 1 . 00%, F, F)
A1.33E6
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A6.30E5 \ A6.32E5 A9.09E5
A3.27E5 A2.99E5A A4.46E5 / A3.00E5 A A A
A ^\ A y VwY\ / \ xx/\ /v\ yv yv y v
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8987 S:10 SMO(1,3) BSUB(128, 15, -3 . 0) PKD(3 , 3 , 3 , 0 . 10%, 1716 . 0, 1 . 00%, F, F)
A1.75E6
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A8.54E5 M A8.21E5 A1.24E6 A
A4.33E5 A4.03E5/\ A9.11E5 \ A4.09E5 A A A
A /\ A ywA / \ ^A /v\ yv yv y\
24:00 	 25:00 	 26:00 27! 00 	 2
9419 S:10 SMO(1,3) BSUB(128 , 15, -3 . 0) PKD(3 , 3 , 3 , 0 . 10%, 4144 . 0 , 1 . 00%, F,F)
A1.94E8
24:00 25:00 26:00 27loO 2
9389 S:10 SMO(1,3) BSUB (128, 15, -3 . 0) PKD(3 , 3 , 3 , 0 . 10%, 4268 . 0 , 1 . 00%, F, F)
A2.48E8
24:00 25:00 26:00 27:00 2
8364 S:10 SMO{1,3) BSUB(128, 15, -3 . 0) PKD(3 , 3 , 3 , 100 . 00%, 68 . 0 , 1 . 00%, F,F)
27
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24:00 25:00 26:00 27:00 2
9824 S:10 SMO(1,3) PKD(3 , 3 , 3 , 100 .00%, 0 . 0, 1 . 00%,F,F)
23:30 24:05 24:3424;54 25i36 26L01 26:28 2^_:59 27:30
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10

-------
Pile: A20JUL98B  Acq:  21-JUL-1998 04:02:53   Exp:  EXP_M23_DB5_OVATION Voltage SIR EI+  GC Autospec-UltimaE—Paradigm	
Sample  #10  Text:  1072-4  xl/2  ALS #11
339.8597  S:10  F:2  SMO(1,3)  BSUB(128,15,-3.0)  PKD(3,3,3,0.10%,832.0,1.00%,F,F)
100%,                                        A3.97E5                                                                1.1E5
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      30:12  30:24  30:36  30:48  31:00  31:12  31:24  31:36  31:48  32:00  32:12  32:24   32:36   32:48  33:00  33:12     Time
341.8568 S:10 F:2  SMO(1,3)  BSUB(128,15,-3.0)  PKD(3,3,3,0.10%,2444.0,1.00%,F,F)
100%                                       A2.i9E5                                                                 6.6E4
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                                               31:24   31:36  31:48  32:00  32:12  32:24  32:36   32:48  33:00   33:12     Time
            30:24  30:36  30:48  31:00
351.9000 S:10 F:2 SMO(1,3)  BSUB(128,15,-3.0) PKD(3,3,3,0.10%,1484.0,1.00%,F,F)
100%                                                            A2.09E8        A2.Q3E8

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     30:12  30:24  30:36  30:48  31:00   31:12  31:24  31:36  31:48  32:00   32:12   32:24  32:36  32:48  33:00  33:12    Time
353.8970 S:10 F:2 SMO(1,3) BSUB(128,15,-3.0) PKD(3,3,3,0.10%,1544.0,1.00%,F,F)
100%.                                                           A1.34E8         A1.31E8
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100%                                                                   32j07
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32:00  32:12  32:24   32:36  32:48 ' 33:66 ' 33!l2    Time
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     30:12  30:24  30:36  30:48  31:00  31:12  31:24  31:36  31:4
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100% 30:12      30:30   	30:54     31:11	31:33   31:47   32:00  32:12    32^28
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-------
File: A20JUL98B Acq: 21-JUL-1998 04:02:53 Exp: EXP_M23_DB5_OVATION
Sample #10 Text: 1072-4 xl/2 ALS #11
373.8207 S:10 F:3 SMO(1,3) BSUB(128, 15, -3 . 0) PKD(3,
100% A7.71E4

50 j
A A5.98E4
/\ A4.77E4 A
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33:24 33:36 33:48 34:00 34:12 34
375.8178 S:10 F:3 SMO(1,3) BSUB(128 , 15 , -3 . 0) PKD(3,
100% A6.J.8E4
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383.8639 S:10 F:3 BSUB (128, 15, -3 . 0) PKD(3 , 5, 2 , 0 . 10%
100%
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33:24 33:36 33:48 34:00 34:12 34
385.8610 S:10 F:3 BSUB(128 , 15, -3 . 0) PKD(3 , 5, 2 , 0 . 10%
100%
50 j
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445.7555 S:10 F:3 SMO(1,3) BSUB (128, 15, -3 . 0) PKD(3,
100%
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33:24 33:36 33:48 34:00 34:12 34
380.9760 S:10 F:3 SMO(1,3) PKD(3 , 3 , 3, 100 . 00%, 0 .0, 1 .

5, 2, 0.10%, 2908.0,


A2.73E4
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v-<— 1 	 1 	 1 	 1 	 1 	 1 | | 	 1 	 1 	 1 1 1 	 1 	 1 	 1 	 1 	 T-'T— 1 1 1 1 1 1 1 | 1 1 1 1 1
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124' ' ' 34:36' ' '34
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34i52 35:08 35:16 35:25 35:33 1 . OE8


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-------
 File:  A20JtJL98B—Acq:  21-JUL-1998 04:02:53Exp: EXP_M23_DB5_OVATION Voltage SIR EI+GC  Autospec-UltimaEParadigm
 Sample #10   Text:  1072-4  xl/2  ALS #11
 407.7818  S:10  F:4  SMO(1,3)  BSUB(128,15,-3.0)  PKD(3,3,3,0.10%,2964.0,1.00%,F,F)
 100%              A9.99E4
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        36:00  36:12  36:24  36:36  36:48   37:00  37:12  37:24  37:36  37:48   38:00
409.7788  S:10 F:4  SMO(1,3)  BSUB(128,15,-3.0) PKD(3,3,3,0.10%,1452.0,1.00%,F,F)
100%               A1.Q9E5
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417.8253 S:10 F:4  SMO(1,3) BSUB(128,15,-3.0) PKD(3,3,3,0.10%,15784.0,1.00%,F,F)
100%              A5.83E7
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                                                                                  38:12  38:24  38:36  38:48  39100  Time
                                                                                                                  1.8E7

                                                                                                                 L9.0E6
                                                                                                                 LO.OEO
       36166 ' 36112 ' 36124 ' 36I36 '  36:48  37:00  37:12  37:24  37:36   37:48  38:00
419.8220 S:10 F:4 SMO(1,3) BSUB(128,15,-3.0} PKD(3,3,3,0.10%,22956.0,1.00%,F,F)
100%              A1.3.2E8
                                                         A9.86E7
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                                                                                  38:12  38:24  38:36  38:48  39:00  Time
                                                                                                                  4.1E7

                                                                                                                 12.0E7
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       36:66 ' 36ll2 ' 36124 ' 36I36 ' 36:48  37:00  37:12  37:24  37:36  37:48  38:00
479.7165 S:10 F:4 SMO{1,3) BSUB(128,15,-3.0) PKD(3,3,3,100.00%,4076.0,1.00%,F,F)
100* 35;57                                    37.09
                                                                  37:43
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                                                                                                                ..9.4E3
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       36:00  36:12  36:24  36:36  36:48  37:00  37:12  37:24  37:36   37:48  38:00
430.9728 S:10 F:4 SMO(1,3) PKD(3,3,3,100.00%,0.0,1.00%,F,F)
100%, 	36:23  36:35 36:46    37jJ31 37:12	
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       36:00  36:12  36:24  36:36  36:48  37:00  37:12  37:24   37:36  37:48  38:00
                                                                                  38:12  38:24  38:36   38:48  39:00  Time

-------
File: A20JUL98B
Sample #10 Text:
441.7427 S:10 F:5
100%^
50J

39:12
443.7398 S:10 F:5
100%
50 J
o •


39! 12
469.7780 S:10 F:5
100%
50J
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39:12
471.7750 S:10 F:5
100%
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39:12
513.6775 S:10 F:5
100%
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39:11
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	 1 	 1 	 1 	 1 	 r' — r — r
39:12
454.9728 S:10 F:5
Acq: 21-JUL-1998 04:02
:53 Exp: EXP_M23_DB5_OVATION Voltage SIR EI+ GC Autospec-UltimaE Paradigm
1072-4 xl/2 ALS #11
SMO (1,3)


39:24
SMO (1,3)

_^ 	 — ~—
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SMO (1,3)



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39:24
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100% 39:07 39:18

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39:36
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27
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39:48
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.1.8E7
: O.OEO
lob 4oll2 40:24 40:36 40:48 41:00 Time
10%, 2012. 0,1. 00%, F,F)
81E8
V

4 . 1E7
.2 . 1E7
.O.OEO
lob 40:12 40124 40:36 40:48 41:00 Time
3, 3, 100. 00%, 1204. 0,1. 00%, F,F)
4C
/
/

40
00%, F,




40
hOl
\^^_J^^^

6.5E3
.3.2E3
.O.OEO
lob 4oll2 40124 4ol36 4ol48 41 00 Time
F)
40:15 40:27 40:34 7 . 6E7




.3.8E7
.O.OEO
lob 4oll2 40124 40136 40:48 41 00 Time

-------
i
        OPUSquan   22-JUL-1998
                          Page 1
                                                                                                                                                      Page 1
                 Filename
                   Sample
                 Acquired
                Processed
                Sample ID
                Cal Table
            Results Table
                 Comments
         Typ
         Unk
         ES/RT
        a21ju!98f
        14
        22-JUL-98  04:08:35
        22-JUL-98  08:34:39
        1072-4 xl/2
        07feb-m23conf
        M8290-23-072198F
         Total
         DPE
         LMC
              Name;     Resp;
      2,3,7,8-TCDF; 9.09e+05;
  13C-2,3,7,8-TCDF; 4.99e+08;
      Tetra Furans; 1.56e+07;
            HxCDPE;        * ;
QC CHK ION (Tetra);        *;
   Ion 1;
2.55e+05;
2.18e+08;
3.19e+05;
   Ion 2
6.55e+05
2.81e+08
4.50e+05
          0.71;y;
                ;NotFnd;
                ;NotFnd;
   Cone;      DL;
  0.192;  0.0354;
122.217;
  3.296;  0.0354;
S/N1;?;
  22;y;
1188;y;
  22,-y;
   *;n
DivO;n
S/N2;?
  25;y
 916;y
  28;y
mod?
  no
  no
  no
  no
  no
                                                                        -;-; 27:55
                                                                        -;-; 27:55
                                                                                                                         -; -;   no

-------
OPUSguan   22-JUL-1998
                                      Page 1
 Ent: 3  Name:  Tetra Furans
                                                 Page  1  of  1

                F:l  Mass:  303.902 305.899  Mod?  no   #Hom:26
 Run: 19 File:  a21ju!98f    S:14 Acq:22-JtJL-98 04:08:35  Proc:22-JUL-98  08:34:39
 Tables: Run:  a21ju!98b  Analyte: m23_conf    Cal:  07feb-m23»Results: M8290-23*
 Version: V3.5 17-APR-1997 11:14:34  Sample text:  1072-4 xl/2
   Amount: 3.30
     Cone: 3.30
   Tox #1: -
Name
of which 0.19
of which 0.19
     Tox #2:  -

#     RT Respnse
named and 3.10
named and 3.10
      Tox #3: -
                                        RA
                   1  18:11 7.7e+05  0.71 y
                            7.7e+05

                   2  19:31 4.0e+04  0.66 y
                            4.0e+04

                   3  19:33 5.36+04  0.70 y
                            5.3e+04

                   4  19:36 4.4e+04  0.24 n
                            4.4e+04

                   5  19:52 5.66+05  0.87 y
                            5.66+05

                   6  20:22 1.9e+05  1.42 n
                            1.9e+05

                   7  20:39 l.le+05  0.42 n
                            l.le+05

                   8  20:41 1.7e+05  1.19 n
                            1.7e+05

                   9  21:13 5.2e+05  0.77 y
                            5.2e+05

                   10 21:33 6.46+05  0.75 y
                            6.4e+05

                   11 22:11 2.0e+06  0.76 y
                            2.0e+06

                   12 22:36 7.06+05  0.78 y
                            7.0e+05

                   13 23:17 1.86+06  0.72 y
                            1.8e+06
                   14 23:25 9.8e+04
                            9.8e+04
                  0.44 n
                   15 23:28 1.5e+05  1.14 n
                            1.56+05

                   16 24:19 1.6e+06  0.76 y
                            1.6e+06

                   17 25:01 S.Oe+05  0.98 n
                            5.0e+05

                   18 25:26 l.le+06  0.26 n
                            l.le+06

                   19 25:29 1.4e+06  0.55 n
                            1.4e+06
          Cone

           0.16
               3
               4
           0.01
               1

           0.01
               2
               2
           0.01
               E
               •3
           0.12


           0.04
               1
               6
           0.02
               T
               1
           0.04
               S

           0.11


           0.13


           0.42
               E
               1
           0.15
               T
               1
           0.39

               ]
           0.02
               3
               e
           0.03
               e
               -
           0.34
               e
               c
           0.10


           0.24

               S
           0.29
   unnamed
   unnamed
                                                      Area  Height
                                  S/N  Mod?
                                3.2e+05 6.5e+04  2.2e+01  y  n
                                4.5e+05 9.1e+04  2.8e+01  y  n

                                1.6e+04 9.26+03  3.2e+00  y  n
                                2.4e+04 l.Oe+04  3.2e+00  y  n
                               1
                                2.2e+04 l.le+04  3.9e+00  y  n
                                3.1e+04 2.0e+04  6.0e+00  y  n
                               L
                                8.6e+03 6.36+03  2.2e+00  n  n
                                3.6e+04 1.9e+04  5.7e+00  y  n
                               2
                                2.6e+05 5.9e+04  2.0e+01  y  n
                                3.0e+05 7.0e+04  2.1e+01  y  n
                               4
                                l.le+05 3.1e+04  l.le+01  y  n
                                8.0e+04 3.1e+04  9.4e+00  y  n
                               I
                                3.3e+04 2.4e+04  8.3e+00  y  n
                                7.8e+04 1.8e+04  5.6e+00  y  n
 9.2e+04  2.4e+04  8.3e+00 y  n
 7.86+04  l.Se+04  5.6e+00 y  n
L
 2.3e+05  3.6e+04  1.2e+01 y  n
 2.9e+05  5.0e+04  1.5e+01 y  n
3
 2.76+05  4.3e+04  1.5e+01 y  n
 3.7e+05  5.2e+04  1.6e+01 y  n
2
 8.7e+05  1.4e+05  4.7e+01 y  n
 l.le+06  1.8e+05  5.5e+01 y  n

 3.1e+05  5.5e+04  1.9e+01 y  n
 3.9e+05  6.56+04  2.06+01 y  n
3
 7.7e+05  l.le+05  3.8e+01 y  n
 l.le+06  1.5e+05  4.4e+01 y  n
2
 3.0e+04  1.9e+04  6.4e+00 y  n
 6.8e+04  3.1e+04  9.3e+00 y  n
3
 S.Oe+04  2.46+04  8.2e+00 y  n
 7.0e+04  2.8e+04  8.5e+00 y  n
1
 6.9e+05  9.7e+04  3.3e+01 y  n
 9.1e+05  1.3e+05  4.0e+01 y  n
                                2.5e+05 3.3e+04 l.le+01 y  n
                                2.5e+05 3.96+04 1.2e+01 y  n
                               1
                                2.4e+05 7.3e+04 2.5e+01 y  n
                                9.0e+05 l.le+05 3.3e+01 y  n
                               3
                                S.Oe+05 8.6e+04 2.96+01 y  n
                                9.0e+05 l.le+05 3.3e+01 y  n
                                                                                                  r f
                                                                                      131

-------
OPUSquan   22-JUL-1998
                   Page 2
2,3,7,8-TCDF
20 25:39 1.8e+04  0.17 n
         1.8e+04

21 26:34 4.9e+04  0.12 n
         4.9e+04

22 27:32 2.4e+04  2.59 n
         2.4e+04

23 27:55 9.1e+05  0.39 n
         9.1e+05

24 27:57 8.9e+05  0.36 n
         8.9e+05

25 28:33 2.6e+05  1.99 n
         2.6e+05

26 29:38 9.4e+05  1.19 n
         9.4e+05
                                               0.00
                                                   2.5e+03 2.8e+03  9.6e-01 n
                                                   1.5e+04 6.1e+03  1.8e+00 n
                                               0.01
                                               0.01
                                                   5.2e+03 4.56+03 1.5e+00 n  n
                                                   4.4e+04 1.4e+04 4.3e+00 y  n
                                                   l.Ve+04 8.3e+03  2.8e+00 n
                                                   6.8e+03 3.3e+03  9.9e-01 n
0.19
                                               0.19
                                               0.05
                                               0.20
    2.5e+05 6.4e+04 2.2e+01 y  n
    6.5e+05 8.46+04 2.5e+01 y  n ,,
   9                             ,.'
    2.4e+05 6.0e+04 2.0e+01 y  n
    6.5e+05 8.4e+04 2.5e+01 y  n

    1.7e+05 2.76+04 9.3e+00 y  n
    8.7e+04 2.66+04 7.9e+00 y  n
                                                   5.1e+05 5.8e+04 2.0e+01 y  n
                                                   4.3e+05 7.5e+04 2.3e+01 y  n

-------
File: A21JUL98F Acq: 22-JUL-1998 04:08:3b Exp: M23_
Sample t!4 Text: 1072-4 xl/2 ALS #14
303.9016 S:14 SMO (1,3) BSUB(128 , 15 , -3 . 0) PKD(3,3,3,0.
10°3j A8-|6EA7.71E5
50J A3.19E5 A2.61E5 ft
! A IJA3L.27E4 A A I
n- 11 ^—"-Ml A l\^JA/A &ALl\ _J-Jx_
16:00 18:00 20:00 22:00 24:
305.8987 S:14 SMO(1,3) BSUB(128, 15, -3 . 0) PKD(3,3,3,0.
10°^ A1-f4EA1.08E6
50J A4j°E5 A3.01E5 A
ielob IS^OO 20100 22:00 24:
315.9419 S:14 SMO(1,3) BSUB(128, 15, -3 . 0) PKD(3,3,3,0.
100%
50 j
0:
ielob islob 2olob 22lob 24!
317.9389 S:14 SMO(1,3) BSUB(128, 15, -3 . 0) PKD(3,3,3,0.
100%
50 j
16:00 18:00 20:00 22:00 24:
375.8364 S:14 SMO(1,3) BSUB(128, 15 , -3 . 0) PKD(3,3,3,10
100% 19:33
A
: / \
n: 16:22 / \ 23:03
16:00 18:00 20:00 22:00 24:
316.9824 S:14 SMO(1,3) PKD(3, 3, 3, 100.00%, 0 .0, 1.00%,F,
100%^ 16:35 18j44 2 0_;_5_2-, 22: 09 2 3 1 1 4
50 J
"-<— -T— • r— r— i i i i i-- T— i 	 T— r"1"!1 • -r 	 T ••• i r r . . i i i c , , ,
16:00 ISIOO 20:00 22:00 24:
.DB225 Voltage SIR EI+ GC
10%, 2908. 0,1. 00%, F,F)
. A4.95E5
fl I A2.55E5
A 1\ A5.17E3 /I .
Ll. A y|\ . _y\_^. ^ilL A
00 26:00 28:00
10%, 3288. 0,1. 00%, F,F)
« A8.98E5
fl /l A6.55E5
IV A A A3 '14E4 ~l[ /K
ob 2e!ob 2'slob
10%, 20412. 0,1. 00%, F,F)
A2.18E8
00 26:00 28:00
10%, 33856. 0,1. 00%, F,F)
A2.81E8
,
ob 2'elob 2s!oo
0.00%,7576.0,1.00%,F,F)
25:08 26:44 27:54
00 26:00 28:00
F)
_.2J:45 26; 05. 27;2128.;18.

ill ii 1 1 T ! 1 1 1 i i
00 26:00 28:00
Autospec-UltimaE Paradigm
1.4E5
A5.09E5 .7.0E4
wxoLi — ^\ , ^-,, .m.,..^%..r.rr,^r n.nrcn
30:00 32:00 34:00 Time
1.8E5
A4.26E5 .9.0E4
A A1.15E4
-~*J (^ ... , ,,-«— s\ ^^_ -~- —11^,^1.-,. n fiT?n
30:00 32:00 34:00 Time
2.4E7
.1.2E7
O.OEO
30:00 32:00 34:00 Time
3.1E7
.1.6E7
, , 	 ,,,,,,, °-OEO
30:00 32:00 34:00 Time
3.1E5
.1.5E5
.^^3^11^ r._ ( i r ., n n^n
3olob 32lob 34lob Time
29:50 31:45 32:58 34:20 4.4E7
L2.2E7
O.OEO
30:00 32-00 34iOO Time

-------
OPUSquan   24-JUL-1998
                                      Page 1
                                                                                                                                              Page
                    a21ju!98f
                    14
                    22-JUL-98  04:08:35
                    22-JUL-98  08:34:39
                    1072-4 xl/2
                    07feb-m23conf
                    m8290-23-072198f
        Filename
          Sample
        Acquired
       Processed
       Sample ID
       Cal Table
   Results Table
        Comments
Typ  ;                   Name;     Resp;
Unk  ;           2,3,7,8-TCDF; 1.26e+06;
ES/RT;       13C-2,3,7,8-TCDF; 4.99e+08;
Total;           Tetra Furans; 1.51e+07;
DPE  ;                 HxCDPE;        *;
LMC  ;     QC CHK ION (Tetra);        *;
                                             Ion 1;
                                          5.59e+05;
                                          2.18e+08;
                                          3.19e+05;
   Ion 2;
7.03e+05;
2.81e+08;
4.50e+05;
  RA;?;
0.79;y;
0.78;y;
0.71,-y;
   RT;
27:55;
27:53;
18:11;
   Cone;       DL;
  0.266;   0.0354;
122.217;
  3.184;   0.0354;
                                                                    ;NotFnd;
                                                                    ;NotFnd;
S/N1;?;
  24 ;y;
1188;y;
  22 ;y;
   *;n
DivO;n
S/N2;?
  26;y
 916;y
  28;y
         mod?
                                                                     yes
                                                                      no
                                                                      no
                                                                -;-; 27:55
                                                                -;-; 27:55
                                                                                                                        yes

-------
   File:  A21JUL98F—Acq: 22-JUL-1998 04:08:35Exp:  M23_DB225  Voltage SIR EI+GC Autospec-UltimaEParadigm
   Sample #14  Text: 1072-4 xl/2  ALS #14
   303.9016 S:14 SMO(1,3)  BSUB(128,15,-3.0)  PKD(3,3,3,0.10%,2908.0,1.00%,F,F)
        i  i  i  r i  i
          16:00
   305.8987  S:14  SMO(1,3)  BSUB(128,15,-3.0)  PKD(3,3,3,0.10%,3288.0,1.00%,F,F)
                                                      32:00      34:00
                                                               lO.OEO
                                                                   Time
ie;oo      18:00
                               20:00
22:00
24:00
26:00
                                                                          28:00
                                           30:00
                                           32:00      34:00
                                                    _O.OEO
                                                        Time
CO
C/T

-------
                                            Paradigm Analytical Labs
    Analytical Data Summary Sheet
Analyte . ->
2,3,7,8-TCDD
1,2,3,7,8-PeCDD
1,2,3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
1,2,3,4,6,7,8-HpCDD
OCDD
2,3,7,8-TCDF
1,2,3,7,8-PeCDF
2,3,4,7,8:PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
1,2,3,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
OCDF
Total TCDDs
Total PeCDDs
Total HxCDDs
Total HpCDDs
Total TCDFs
Total PeCDFs
Total HxCDFs
Total HpCDFs
TEQ(ND=0)
TEQ (ND=l/2)
' -••• IMS* "^
0.0013
EMPG - -
ND
EMPC ?:
EMPC
0.0080
0.0218
0.0301
0.0077
 QJOQ04
0.0006
0.000?
0.0009
0.0006^
0.0003
0.0006
0.0005
0.0004
0.0005
0.0003
0.0006




"j^@^:j
O^K>i3
0.0013




U.-i --•• , -. >'
-V-f,v,
0.0009




0.0056
0.0148

0.310
0.0752
0.0124
0.0068
0.0097
0.0098
«f-.
::'«Wp.>.-"i
28:27
32^J<"
34^f5 '*
34:58
37:09
40:01
27:26
31:56
;32:24
34:10
_34:15
34:37
36:21
37:30
40:09










Ratio
0.82
:.*'-p* "
r.'-3sy, '
0.93
1.04
0.93
0.76
1.40
i-51
1.14
1.18
1.52
0.95
1.04
1










Qualifier






















ITEF
ITEF
Client Information

Project Name:
Sample ID:

Laboratory Information

Project ID:
Sample ID:

Collection Date:
Texas Lime KiJn
M24-O-4
L1072
1072-5
Sample Information

Matrix:
Weight/ Volume:
Moisture / Lipids:
                                                 Air
                                                  1
                                                 0.0
                                             a20jul98b-ll
                                             a20jul98b-l
                                             a20ju!98b-2
                                             a20jul9«b-17
                                                                   136
                1/2

-------
                                                                Paradigm Analytical Labs
                           Analytical Data Summary Sheet
Labeled "::-l

Standard x ^
Extraction Standards
13C,2-2,3,7,8-TCDD
I3C12-l,2,3,7,8-PeCDD
13C12-l,2,3,6,7,8-HxCDD
l3C12-l,2,3,4,6,7,8-HpCDD
13C12-OCDD
13Ci2-2,3,7,8-TCDF
13C,rU,3,7,8-PeCDF
uC!2-U,3,6,7,8-HxCDF
13C12- 1 ,2,3,4,6,7,8-HpCDF
Sampling Standards
37Cl4-2,3,7,8-TCDD
13C12-2,3,4,7,8-PeCDF
13C12-l,2,3,4,7,8-HxCDD

I3C,2-l,2,3,4,7,8,9-HpCDF
Injection Standards
13C12-1,2,3,4-TCDD
13C12-l,2,3,7,8,9-HxCDD
'""JSanjiJSBK '• -i



4
4
4
4
8
4 / •
4
/:4%%5 ^
4

4
4
4
4
4



''•M*asiB*if'!;



3.16
3.14
3.24
3,50
6.55
2.94
2.69
3.25
2.89

4.00
4.01
4.32
3.65
3.74



yj£Feetifc /'



79.1
78.5
81.0
87.5
81.9
73.5
67.2
V- 81,3
72.3

100.0
100.4
108.0
91.3
93.6



'- - RT

Cmiir.)

28:26
32:36
34:44
37:09
40:00
27:24
31:56
34:14
36:20

28:27
32:24
34:41
34:09
37:30

28:09
34:57
Ratio
• **S*^'-


0.78
1.57
1.25
1.04
0.89
0.78
1.56
0,52
0.44


1.58
1.25
0.52
0.43

0.79
1.25
Qualifier
^^1* fUIUU




















Client Information
Project Name:
Sample ID:

Laboratory Information

Project ID:
Sample ID:

Collection Date:
Receipt Date:
Extraction Date:
Analysis Date:
ReviewedJbfy: M 77.
Texas Lime Kiln
M24-O4



L1072
1072-5

Ol-Jul-98
08-M-98
15-M-98
21-Jol-98
^:^.-.;. ''^^iy;-- -,-;.• ,\
Sample Information

Matrix:
f/^*igbt7 Volume:
Mokture / Lipids:


Filename:
Retook:
Begin ConCal:
EndConCal:
Initial Cal:
,':-:C,^ ;^\!-' ' " Date


Air
1
0.0 %


a20jul98b-ll
a20ju!98b-l
a20jul98b-2
a20ju!98b-17
m8290-23-071798
Reviewed: ^vX
                                                                                   137
                                     2/2

-------
CJ
00
OPUSquan 21-JUL-1998 Page 1
Filename a20ju!98b
Sample 11
Acquired 21-JUL-98 04:47:59
Processed 21-JUL-98 13:46:46
Sample ID 1072-5 xl/2
Cal Table m8290-23-071798
Results Table M8290-23-072098B
Comments
Typ
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
ES/RT
ES
ES
ES
ES
ES/RT
ES
ES
ES
JS
JS
CS
CS
CS
CS
CS
SS
SS
SS
SS
SS
Name; Resp; Ion 1; Ion 2; RA;?; RT;
2,3,7,8-TCDD; 2.79e+05; 4.52e+04; 2.34e+05; 0.19;n; 28:27;
1,2,3,7,8-PeCDD; 3.87e+04; 2.01e+04; 1.86e+04; 1.08;n; 32:37;
1,2,3,4,7,8-HxCDD; *; *; *; *;n;NotFnd;
1,2,3,6,7,8-HxCDD; 7.27e+04; 5.19e+04; 2.08e+04; 2.50;n; 34:45;
1,2,3,7,8,9-HxCDD; 6.89e+04; 3.32e+04; 3.57e+04; 0.93;n; 34:58;
1,2,3,4,6,7,8-HpCDD; 3.56e+05; 1.82e+05; 1.74e+05; 1.04;y; 37:09;
OCDD; 8.25e+05; 3.98e+05; 4.27e+05; 0.93;y; 40:01;
2,3,7,8-TCDF; 4.18e+06; 1.81e+06; 2.37e+06; 0.76;y; 27:26;
1,2,3,7,8-PeCDF; 4.93e+05; 2.88e+05; 2.06e+05; 1.40,-y; 31:56;
2,3,4,7,8-PeCDF; 4.93e+05; 2.96e+05; 1.97e+05; 1.51;y; 32:24;
1,2,3,4,7,8-HxCDF; 1.98e+05; 1.05e+05; 9.23e+04; 1.14;y; 34:10;
1,2,3,6,7,8-HxCDF; 1.28e+05; 6.91e+04; 5.85e-i-04; 1.18;y; 34:15;
2,3,4,6,7,8-HxCDF; 6.02e+04; 3.63e+04; 2.39e+04; 1.52;n; 34:37;
1,2,3,7,8,9-HxCDF; *; *; *; * ;n,-NotFnd;
1,2,3,4,6,7,8-HpCDF; 2.78e+05; 1.36e+05; 1.43e+05; 0.95;y; 36:21;
1,2,3,4,7,8,9-HpCDF; 1.84e+04; 9.38e+03? 9.05e+03? 1.04;y; 37:30;
OCDF; 2.08e+05; 1.04e+05; 1.04e+05; 1.00;y; 40:09;
13C-2,3,7,8-TCDD; 3.16e+08; 1.38e+08; 1.78e+08; 0.78;y,- 28:26;
13C-l,2,3,7,8-PeCDD; 2.19e+08; 1.34e+08; 8.50e+07; 1.57;y; 32:36;
13C-l,2,3,6,7,8-HxCDD; 2.51e+08; 1.39e+08; l.lle+08; 1.25;y; 34:44;
13C-l,2,3,4,6,7,8-HpCDD; 2.00e+08; 1.02e+08; 9.78e+07; 1.04;y; 37:09;
13C-OCDD; 3.01e+08; 1.42e+08; 1.59e+08; 0.89;y; 40:00;
13C-2,3,7,8-TCDF; 3.69e+08; 1.62e+08; 2.07e+08; 0.78;y; 27:24;
13C-l,2,3,7,8-PeCDF; 2.94e+08; 1.79e+08; 1.15e+08; 1.56;y; 31:56;
13C-l,2,3,6,7,8-HxCDF; 2.89e+08; 9.89e+07; 1.91e+08; 0.52;y; 34:14;
13C-l,2,3,4,6,7,8-HpCDF; 1.57e+08; 4.79e+07; 1.09e+08; 0.44;y; 36:20;
13C-1,2,3,4-TCDD; 3.64e+08; 1.61e+08; 2.03e+08; 0.79;y; 28:09;
13C-l,2,3,7,8,9-HxCDD; 2.87e+08; 1.60e+08; 1.28e+08; 1.25;y; 34:57;
37Cl-2,3,7,8-TCDD; 2.90e+08; 2.90e+08; -; -;-; 28:27;
13C-2,3,4,7,8-PeCDF; 2.88e+08; 1.76e+08; 1.12e+08; 1.58;y; 32:24;
13C-l,2,3,4,7,8-HxCDD; 1.78e+08; 9.90e+07; 7.95e+07; 1.25;y; 34:41;
13C-l,2,3,4,7,8-HxCDF; 2.07e+08; 7.07e+07; 1.37e+08; 0.52;y; 34:09;
13C-l,2,3,4,7,8,9-HpCDF; 1.15e+08; 3.46e+07; 8.00e+07; 0.43;y; 37:30;
37Cl-2,3,7,8-TCDD; 2.90e+08; 2.90e+08; -; -;-; 28:27;
13C-2,3,4,7,8-PeCDF; 2.88e+08; 1.76e+08; 1.12e+08; 1.58,-y; 32:24;
13C-l,2,3,4,7,8-HxCDD; 1.78e+08; 9.90e+07; 7.95e+07; 1.25,-y; 34:41;
13C-l,2,3,4,7,8-HxCDF; 2.07e+08; 7.07e+07; 1.37e+08; 0 52;y 34-09-
13C-1,2,3,4, 7, 8,9-HpCDF; 1.15e+08; 3.46e+07; 8 OOe+07; 0 43;y 37-30-





ff -
L.'


Cone;
0.090;
0.016;
* .
0.033;
0.032;
0.199;
0.546;
1.189;
0.193;
0.186;
0 . 080 ;
0.040;
0.022;
* .
0.141;
0.011;
0.129;
79.064;
78.491;
81.028;
87.466;
163.774;
73.481;
67.215;
81.268;
72.298;
75.533;
72.447;
79.045;
67.421;
87.444;
74.739;
67.655;
100.032;
100.341;
108. 018;
91.248;
93.612;



«1^
, *'



DL;
0.0137;
0.0086;
0.0213;
0.0153;
0.0157;
0,0120;
0.0143;
0.0105;
0.0126;
0.0122;
0.0103;
0.0080;
0.0094;
0.0108;
0.0145;
0.0176;
0.0214;
0.0387;
0.0181;
0.0370;
0.0255;
0.0181;
0.0221;
0.0087;
0.1814;
0.0424;
-;
— ;
0.0161;
0.0089;
0.0561;
0.2327;
0.0542;
0.0213;
0.0083;
0. 0672;
0.2394;
0.0896;








S/N1;?;
7;y;
6;y;
*;n;
6;y;
5;y;
56 1 ;y;
135 ;y;
272, -y;
63 ;y;
72;y;
13 ;y;
8;y;
4;y;
*;n;
25 ;y;
2;n;
24 ;y;
4038,-y;
19854;y;
5426;y;
5551;y;
13208;y;
8804 , -y;
66289;y;
1665;y;
4799;y;
4919;y;
6063;y;
14121;y;
71159;y;
5061;y;
1187 ;yi
3101;y;
14121;y;
71159;y;
5061;y;
1187 ;y;
3101;y;








S/N2;?
36;y
4;y
*;n
5;y
6;y
46, -y
109 ;y
263 ;y
28 ;y
29,-y
20, -y
ftVfJ
12 ;y
**• , J
4;y
*;n
41;y
3;n
15 ;y
8999;y
22959;y
9642 ;y
12153 ;y
23009;y
10352 ;y
21818;y
1555;y
4096;y
10816 ;y
'^10638,-y
-; -
32862;y
8601, -y
"1161;y
2623 ;y
_ • —
22862 ;y
8601;y
1 1 Ki .v
j. AO j. , y
2623, -y
mod?
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
T1O
tHJ
no
no
                                                                                                                                      Page 16

-------
OPUSguan   21-JUL-1998
                   Page  1
                                                                    Page  1 of  8

 Ent: 39 Name: Total Tetra-Furans  F:l  Mass:  303.902  305.899 Mod? no   #Hom:25

 Run: 16 File: a20ju!98b    S:ll Acq:21-JUL-98 04:47:59  Proc:21-JUL-98  13:46:46
 Tables: Run: a20ju!98b  Analyte: m8290-23-»  Cal: m8290-23-»Results: M8290-23*
 Version: V3.5 17-APR-1997 11:14:34  Sample text:  1072-5 xl/2
   Amount: 7.79
     Cone: 7.79
   Tox #1: -
Name
2,3,7,8-TCDF
of which 1.19
of which 1.19
     Tox #2:  -

#     RT Respnse
named and 6.60
named and 6.60
      Tox §3:  -
                                        RA
1  23:38 6.46+05  0.80  y
         6.4e+05

2  24:14 5.0e+05  0.84  y
         5.0e+05

3  24:33 6.8e+05  0.75  y
         6.8e+05

4  24:51 2.1e+06  0.77  y
         2.1e+06

5  24:59 5.2e+05  0.74  y
         5.2e+05

6  25:11 5.4e+05  0.91  n
         5.46+05

7  25:17 1.5e+06  0.74  y
         1.5e+06

8  25:26 9.2e+03  1.49  n
         9.2e+03

9  25:44 4.9e+06  0.77  y
         4.9e+06

10 26:00 4.1e+05  0.91  n
         4.1e+05

11 26:08 9.6e+05  0.81  y
         9.6e+05

12 26:25 1.3e+06  0.71  y
         1.36+06

13 26:32 5.96+05  0.84  y
         5.9e+05

14 26:50 2.6e+06  0.75  y
         2.6e+06

15 26:59 1.7e+04  0.36  n
         1.7e+04

16 27:02 2.7e+04  1.24  n
         2.7e+04

17 27:10 1.9e+06  0.75  y
         1.9e+06

18 27:26 4.2e+06  0.76  y
         4.2e+06

19 27:40 l.le+04  0.49  n
         l.le+04
          Cone

           0.18

               3
           0.14


           0.19

               i
           0.60
               c
               ]
           0.15


           0.15


           0.43
               £
               £
           0.00
               c

           1.40


           0.12
               3

           0.27
               t,
               C
           0.37
               c

           0.17


           0.75
               :
               ]
           0.00
               <
               ]
           0.01
               ]
               ]
           0.53

               ]
           1.19
               3

           0.00
   unnamed
   unnamed
                                                      Area   Height
                                  S/N  Mod?
                                                   2.9e+05  6.1e+04  5.7e+01 y  n
                                                   3.6e+05  7.6e+04  5.2e+01 y  n
                                                  I
                                                   2.3e+05  4.7e+04  4.4e+01 y  n
                                                   2.76+05  6.0e+04  4.1e+01 y  n
                                                  3
                                                   2.9e+05  6.4e+04  6.0e+01 y  n
                                                   3.9e+05  8.2e+04  5.6e+01 y  n
                                                  3
                                                   9.2e+05  l.Se+05  1.7e+02 y  n
                                                   1.2e+06  2.2e+05  1.5e+02 y  n

                                                   2.2e+05  3.6e+04  3.3e+01 y  n
                                                   3.0e+05  4.9e+04  3.3e+01 y  n

                                                   2.66+05  5.3e+04  5.0e+01 y  n
                                                   2.8e+05  7.06+04  4.8e+01 y  n
                                                   6.4e+05 9.0e+04 8.4e+01 y  n
                                                   8.7e+05 1.2e+05 8.0e+01 y  n
                                                  3
                                                   5.56+03 2.5e+03 2.3e+00 n  n
                                                   3.7e+03 1.2e+03 S.le-01 n  n
                                                  D
                                                   2.1e+06 3.9e+05 3.7e+02 y  n
                                                   2.8e+06 5.3e+05 3.6e+02 y  n
                                                  2
                                                   1.96+05 4.3e+04 4.0e+01 y  n
                                                   2.2e+05 4.9e+04 3.4e+01 y  n
                                                  7
                                                   4.3e+05 9.0e+04 8.4e+01 y  n
                                                   5.3e+05 l.le+05 7.5e+01 y  n
                                                  7
                                                   5.5e+05 l.Oe+05 9.46+01 y  n
                                                   7.76+05 1.4e+05 9.86+01 y  n
                                                  7
                                                   2.7e+05 5.5e+04 5.1e+01 y  n
                                                   3.2e+05 6.7e+04 4.6e+01 y  n

                                                    .le+06 2.36+05 2.2e+02 y  n
                                                    .Se+06 2.9e+05 2.0e+02 y  n
  .4e+03  2.2e+03  2.06+00 n  n
  .2e+04  5.2e+03  3.6e+00 y  n

  .5e+04  5.0e+03  4.7e+00 y  n
  .2e+04  5.2e+03  3.6e+00 y  n

 7.9e+05  1.7e+05  1.6e+02 y  n
 l.le+06  2.2e+05  1.5e+02 y  n
9
 1.8e+06  2.9e+05  2.7e+02 y  n
 2.4e+06  3.8e+05  2.6e+02 y  n
3
 3.6e+03  1.4e+03  1.3e+00 n  n
 7.4e+03  2.3e+03  1.6e+00 n  n
                                                                                                 r
                                                                                                        139

-------
OPUSquan   21-JUL-1998
Page 2
                   20 28:02 2.7e+06  0.80 y    0.77
                            2.7e+06

                   21 28:19 9.5e+05  0.75 y    0.27
                            9.5e+05

                   22 28:27 1.5e+04  1.29 n    0.00
                            l.Se+04
             1.2e+06
             l.Se+06
            7
             4.1e+05
             5.4e+05
            a
             8.76+03
             6.76+03
                   23 28:32 3.2e+04  0.93 n    0.01
                            3.2e+04

                   24 29:48 1.4e+05  0.99 n    0.04
                            1.4e+05

                   25 29:53 l.Oe+05  0.46 n    0.03
                            l.Oe+05
             1.56+04
             1.76+04
            1
             7.16+04
             7.16+04
            3
             3.3e+04
             7.1e+04
2.5e+05 2.
3.16+05 2.

8.26+04 7.
9.7e+04 6.

2.4e+03 2.
3.16+03 2.

3.3e+03 3.
5.26+03 3.

1.4e+04 1.
1.4e+04 9.

7.9e+03 7,
1.6e+04 1.
4e+02 y  n
le+02 y  n

7e+01 y  n
7e+01 y  n

3e+00 n  n
le+00 n  n

le+00 y  n
6e+00 y  n

3e+01 y  n
7e+00 y  n

4e+00 y  n
,le+01 y  n
                                                                                                      r

-------
OPUSquan   21-JUL-1998
                   Page 3
                                                                    Page 2 of 8

 Ent: 40 Name: Total Tetra-Dioxins F:l  Mass: 319.897 321.894 Mod? no   #Hom:9

 Run: 16 File: a20ju!98b    S:ll Acq:21-JUL-98 04:47:59 Proc:21-JUL-98 13:46:46
 Tables: Run: a20ju!98b  Analyte: m8290-23-»  Cal: m8290-23-»Results: M8290-23*
 Version: V3.5 17-APR-1997 11:14:34  Sample text: 1072-5 xl/2
   Amount: 0.34
     Cone: 0.34
   Tox #1: -
Name
of which 0.09
of which 0.09
     Tox #2:  -

#     RT Respnse
named and 0.25
named and 0.25
      Tox #3: -
                                        RA
2,3,7,8-TCDD
1  25:15 3.4e+05  0.79 y
         3.4e+05

2  25:40 1.5e+05  0.77 y
         1.5e+05

3  26:03 2.8e+04  0.89 n
         2.8e+04

4  26:53 1.2e+05  0.72 y
         1.2e+05

5  27:44 3.3e+04  0.80 y
         3.3e+04

6  28:11 4.3e+04  0.54 n
         4.3e+04

7  28:19 4.9e+04  0.69 y
         4.9e+04

8  28:27 2.8e+05  0.19 n
         2.8e+05

9  28:56 1.6e+04  0.73 y
         1.6e+04
          Cone

           0.11
               1
               ]
           0.05
               C
               £
           0.01
               1
               1
           0.04
               4
               e
           o.oi
               i
               i
           0.01
               ]

           0.02


           0.09
               4

           0.01
    unnamed
    unnamed
    Area  Height
                                                                      S/N  Mod?
 1.5e+05 2.9e+04  2.0e+01  y  n
 1.96+05 4.2e+04  3.0e+01  y  n

 6.6e+04 1.4e+04  9.6e+00  y  n
 8.5e+04 2.0e+04  1.4e+01  y  n
1
 1.3e+04 3.3e+03  2.2e+00  n  n
 1.5e+04 3.6e+03  2.6e+00  n  n

 4.9e+04 8.3e+03  5.6e+00  y  n
 6.9e+04 1.4e+04  l.Oe+01  y  n
L
 1.5e+04 3.8e+03  2.6e+00  n  n
 1.9e+04 4.5e+03  3.2e+00  y  n

 1.5e+04 4.2e+03  2.8e+00  n  n
 2.8e+04 5.9e+03  4.2e+00  y  n
2
 2.0e+04 4.9e+03  3.3e+00  y  n
 2.9e+04 6.0e+03  4.3e+00  y  n
3
 4.5e+04 l.Oe+04  6.9e+00  y  n
 2.3e+05 5.1e+04  3.6e+01  y  n
                                                   6.9e+03 2.4e+03 1.6e+00 n  n
                                                   9.4e+03 2.7e+03 1.9e+00 n  n
                                                                    Page 3 of 8

  Ent:  41 Name: Total  Penta-Furans  F:2  Mass:  339.860  341.857 Mod? no   #Hom:12

  Run:  16 File: a20ju!98b    S:ll Acq:21-JUL-98 04:47:59  Proc:21-JUL-98  13:46:46
  Tables: Run:  a20ju!98b  Analyte: m8290-23-»   Cal: m8290-23-»Results: M8290-23»
  Version: V3.5 17-APR-1997  11:14:34  Sample text:  1072-5 xl/2
    Amount:  1.88
      Cone:  1.88
    Tox #1:  -
 Name
of which 0.38
of which 0.38
     Tox #2: -

#     RT Respnse
named and 1.50
named and 1.50
       Tox #3: -
                                         RA
                    1   30:14  3.2e+05   1.57  y
                             3.2e+05

                    2   31:14  7.8e+04   1.50  y
                             7.8e+04

                    3   31:21  2.1e+06   1.45  y
                             2.1e+06

                    4   31:28  2.5e+05   1.14  n
                             2.5e+05

                    5   31:38  9.3e+04   1.65  y
                             9.3e+04
           Cone

            0.12
                ]
                ]
            0.03
                4

            0.80
                1
                t
            0.10
                I
                1
            0.04
    unnamed
    unnamed
                                                       Area   Height     S/N  Mod?
                                  .9e+05  4.0e+04  2.9e+01 y  n
                                  .26+05  2.7e+04  1.2e+01 y  n

                                 4.6e+04  1.7e+04  1.2e+01 y  n
                                 3.16+04  l.le+04  4.8e+00 y  n
                                3
                                 1.26+06  3.46+05  2.46+02 y  n
                                 8.5e+05  2.3e+05  l.Oe+02 y  n
                                )
                                 1.3e+05  4.56+04  3.2e+01 y  n
                                 1.2e+05  3.5e+04  1.5e+01 y  n
                                1
                                 5.8e+04  1.7e+04  1.2e+01 y  n

-------
OPUSquan  ' 21-JUL-1998
                   Page 4
                                                  3.5e+04 8.3e+03 3.7e+00 y  n
1,2,3,7,8-PeCDF
6  31:44 2.5e+05  1.31 n    0.10
         2.5e+05

7  31:56 4.9e+05  1.40 y    0.19
         4.9e+05

8  32:03 2.9e+05  1.15 n    0.11
         2.9e+05

9  32:08 2.4e+05  1.29 n    0.09
         2.4e+05
2,3,4,7,8-PeCDF
                               1.
                               1.
                               9
                               2.
                               2,
                               1
                               1.
                               1.
                               J
                               1.
                               1.
10 32:17 7.5e+03   0.57 n    0.00
         7.5e+03

11 32:24 4.96+05   1.51 y    0.19
         4.9e+05

12 32:29 2.7e+05   1.42 y    0.11
         2.7e+05
4e+05 4.
le+05 3.

9e+05 8.
le+05 6.

66+05 5.
4e+05 5.

4e+05 4.
le+05 3.

7e+03 1,
8e+03 2,

.Oe+05 1
.Oe+05 6

.6e+05 5
.le+05 4
 3e+04
 3e+04

 8e+04
 2e+04

 5e+04
 Oe+04

 7e+04
 2e+04

.Oe+03
.2e+03

.Oe+05
.5e+04

.8e+04
.Oe+04
3.0e+01 y  n
1.5e+01 y  n

6.3e+01 y  n
2.8e+01 y  n

3.9e+01 y  n
2.2e+01 y  n

3.4e+01 y  n
1.4e+01 y  n

7.5e-01 n  n
l.Oe+00 n  n

7.2e+01 y  n
2.9e+01 y  n

4.2e+01 y  n
1.8e+01 y  n
                                                                                                        142

-------
OPUSquan   21-JUL-1998
                   Page 5
                                                                    Page 4  of  8

 Ent: 42 Name:  Total Penta-Dioxins F:2  Mass:  355.855  357.852 Mod?  no    #Hom:7

 Run: 16 File:  a20ju!98b    S:ll Acq:21-JUL-98 04:47:59  Proc:21-JUL-98  13:46:46
 Tables: Run: a20ju!98b  Analyte: m8290-23-»  Cal: m8290-23-»Results: M8290-23*
 Version: V3.5 17-APR-1997 11:14:34  Sample text:  1072-5 xl/2
   Amount: 0.16
     Cone: 0.16
   Tox #1: -
Name
of which 0.02
of which 0.02
     Tox #2: -

#     RT Respnse
named and 0.15
named and 0.15
      Tox #3:  -
                                        RA
 1,2,3,7,8-PeCDD
1  31:29 1.3e+05  1.54 y
         1.3e+05

2  31:48 3.2e+04  1.17 n
         3.2e+04

3  31:59 8.3e+04  2.33 n
         8.3e+04

4  32:09 3.8e+04  1.25 n
         3.8e+04

5  32:19 3.66+04  0.76 n
         3.6e+04

6  32:24 4.2e+04  3.16 n
         4.2e+04

7  32:37 3.9e+04  1.08 n
         3.9e+04
          Cone

           0.05
               E
               C
           0.01
               ]
               3
           0.03
               c

           0.02

               3
           0.01
               ]

           0.02

               ]
           0.02
   unnamed
   unnamed
   Area  Height
                                                                      S/N  Mod?
                                                   8.0e+04 2.6e+04 1.9e+01 y  n
                                                   5.2e+04 1.6e+04 1.5e+01 y  n

                                                   1.7e+04 6.2e+03 4.7e+00 y  n
                                                   1.5e+04 5.2e+03 4.8e+00 y  n
                                                  3
                                                   5.8e+04 1.4e+04 l.le+01 y  n
                                                   2.5e+04 9.0e+03 8.3e+00 y  n
                                                  2
                                                   2.1e+04 8.4e+03 6.3e+00 y  n
                                                   1.7e+04 6.0e+03 5.5e+00 y  n

                                                   1.5e+04 4.8e+03 3.6e+00 y  n
                                                   2.0e+04 5.76+03 5.36+00 y  n
3.2e+04 9.9e+03 7.5e+00 y  n
l.Oe+04 2.8e+03 2.6e+00 n  n

2.0e+04 7.7e+03 5.8e+00 y  n
1.9e+04 4.8e+03 4.5e+00 y  n
  Ent:  43 Name: Total Hexa-Furans
                                                                    Page 5 of 8

                                   F:3  Mass: 373.821 375.818 Mod? no   #Hom:9
  Run:  16  File: a20jul98b     S:ll Acq:21-JUL-98 04:47:59 Proc:21-JUL-98 13:46:46
  Tables:  Run: a20ju!98b  Analyte: n\8290-23-»  Cal: m8290-23-»Results: M8290-23»
  Version: V3.5 17-APR-1997  11:14:34   Sample text: 1072-5 xl/2
    Amount:  0.33
      Cone:  0.33
    Tox #1:  -
 Name
 of which  0.14
 of which  0.14
      Tox  #2: -

 #      RT  Respnse
 named and 0.18
 named and 0.18
      Tox #3: -
                                        RA
                    1   33:31  l.Ze+05   1.16 y
                             1.2e+05

                    2   33:37  2.6e+05   1.27 y
                             2.66+05

                    3   33:42  2.0e+04   1.18 y
                             2.0e+04

                    4   33:55  6.6e+04   0.76 n
                             6.6e+04

 1,2,3,4,7,8-HxCDF  5   34:10  2.0e+05   1.14 y
                             2.0e+05

 1,2,3,6,7,8-HxCDF  6   34:15  1.3e+05   1.18 y
                             1.3e+05

                    7   34:27  2.1e+04   0.78 n
                             2.1e+04
          Cone

            0.05
               £
               C
            0.10
               ]
               ]
            0.01
               1
               s
            0.02

               i
            0.08
               1
               9
            0.04
               e
               c
            0.01
   unnamed
   unnamed
   Area  Height
                                                                       S/N  Mod?
                                6.6e+04 2.5e+04  l.le+01 y  n
                                5.7e+04 2.1e+04  1.6e+01 y  n

                                  .4e+05 5.2e+04  2.2e+01 y  n
                                  .le+05 3.9e+04  2.9e+01 y  n

                                l.le+04 3.5e+03  1.5e+00 n  n
                                9.1e+03 3.2e+03  2.3e+00 n  n
                                I
                                2.9e+04 l.Oe+04  4.4e+00 y  n
                                3.8e+04 1.2e+04  8.6e+00 y  n
                                 l.le+05  3.0e+04  1.3e+01 y  n
                                 9.2e+04  2.7e+04  2.Oe+01 y  n
                                1
                                 6.9e+04  1.8e+04  7.8e+00 y  n
                                 5.9e+04  1.7e+04  1.2e+01 y  n
                                L
                                 9.2e+03  3.3e+03  1.4e+00 n  n
                                                                                                         143

-------
OPUSquan   21-JUL-1998               Page 6
                                                  1.2e+04 3.8e+03 2.8e+00 n  n
2,3,4,6,7,8-HxCDF  8  34:37  6.0e+04  1.52 n    0.02
                            6.0e+04                3.6e+04 9.2e+03 4.0e+00 y  n
                                                  2.4e+04 6.1e+03 4.5e+00 y  n
                   9  34:46  8.2e+03  1.72 n    0.00
                            8.2e+03                5.2e+03 1.9e+03 8.1e-01 n  n
                                                  3.0e+03 1.2e+03 8.6e-01 n  n
                                                                                                       144

-------
OPUSquan   21-JUL-1998
                   Page  7
                                                                    Page  6  of  8

 Ent: 44 Name: Total Hexa-Dioxins  F:3  Mass:  389.816 391.813  Mod?  no   #Hom:9

 Rum: 16 File: a20ju!98b    S:ll Acq:21-JUL-98 04:47:59  Proc:21-JUL-98  13:46:46
 Tables: Run: a20ju!98b  Analyte: m8290-23-»  Cal:  m8290-23-»Results: M8290-23»
 Version: V3.5 17-APR-1997 11:14:34  Sample text:  1072-5 xl/2
   Amount:  0.41
     Cone:  0.41
   Tox #1:  -
Name
of which 0.06
of which 0.06
     Tox #2:  -

#     RT Respnse
named and 0.34
named and 0.34
      Tox #3:  -
                                        RA
                   1  33:51 2.2e+05  1.10 y
                            2.2e+05

                   2  34:00 4.1e+03  0.60 n
                            4.1e+03
                      34:10 1.86+05
                            1.8e+05
                                     1.47 n
                   4  34:19 2.2e+05  1.35 y
                            2.2e+05

                   5  34:24 2.96+04  2.77 n
                            2.9e+04
1,2,3,6,7,8-HxCDD  6
   34:45 7.3e+04  2.50 n
         7.3e+04
1,2,3,7,8,9-HxCDD  7  34:58 6.9e+04  0.93 n
                            6.96+04

                   8  35:05 4.0e+03  0.29 n
                            4.06+03
                      35:14 8.2e+03
                            8.2e+03
                                     2.22 n
          Cone

           0.11
               ]
               ]
           0.00
               1
               2
           0.09
               1
               1
           0.11
               1
               c
           0.01


           0.03
               C

           0.03


           0.00
               c

           0.00
    unnamed
    unnamed
    Area  Height
                                                                      S/N  Mod?
  .2e+05  4.4e+04  1.7e+01 y  n
  .le+05  3.7e+04  2.2e+01 y  n

 l.Se+03  7.8e+02  3-Oe-Ol n  n
 2.6e+03  8.76+02  5.2e-01 n  n
}
 l.le+05  3.6e+04  1.4e+01 y  n
 7.5e+04  2.2e+04  1.3e+01 y  n
L
 1.36+05  4.0e+04  1.5e+01 y  n
 9.6e+04  3.26+04  1.9e+01 y  n
L
 2.1e+04  5.7e+03  2.2e+00 n  n
 7.66+03  2.5e+03  l.Se+00 n  n
3
 5.2e+04  1.6e+04  6.36+00 y  n
 2.16+04  8.1e+03  4.8e+00 y  n
3
 3.36+04  1.26+04  4.7e+00 y  n
 3.6e+04  l.Oe+04  6.1e+00 y  n
3
 9.0e+02  5.8e+02  2.2e-01 n  n
 3.1e+03  6.06+02  3.6e-01 n  n
                                                   5.7e+03 1.9e+03 7.2e-01 n  n
                                                   2.66+03 l.le+03 6.3e-01 n  n
                                                                    Page 7 of 8

 Ent: 45 Name: Total Hepta-Furans  F:4  Mass: 407.782 409.779 Mod? no   #Hom:3

 Run: 16 File: a20ju!98b    S:ll Acq:21-JUL-98 04:47:59 Proc:21-JUL-98 13:46:46
 Tables: Run: a20ju!98b  Analyte: m8290-23-»  Cal: m8290-23-»Results: M8290-23»
 Version: V3.5 17-APR-1997 11:14:34  Sample text: 1072-5 xl/2
   Amount:  0.18
      Cone:  0.18
   Tox  #1:  -
Name
of which 0.15
of which 0.15
     Tox #2: -

tt     RT Respnse
named and 0.03
named and 0.03
      Tox #3: -
                                        RA
 1,2,3,4,6,7,8-HpCDFl   36:21 2.8e+05  0.95 y
                            2.8e+05

                    2   36:39 4.8e+04  0.68 n
                            4.8e+04

 l,2,3,4,7,8,9-HpCDF3   37:30 l.Se+04  1.04y
                            l.Se+04
                           Cone

                            0.14
                                3
                                ]
                            0.03
                                ]

                            0.01
    unnamed
    unnamed
                                                      Area  Height
                                  S/N  Mod?
                 .46+05 4.46+04 2.5e+01 y  n
                 .4e+05 4.6e+04 4.1e+01 y  n

                1.9e+04 7.0e+03 3.9e+00 y  n
                2.9e+04 l.Oe+04 9.le+00 y  n
               L
                9.4e+03 2.9e+03 1.6e+00 n  n
                9.1e+03 3.1e+03 2.7e+00 n  n
                                                                    Page 8 of 8

  Ent:  46 Name:  Total  Hepta-Dioxins F:4  Mass: 423.777 425.774 Mod? no   #Hom:3
                                                                                                         145

-------
OPUSquan   21-JUL-1998                Page  8
 Run: 16 File: a20ju!98b    S:ll Acq:21-JUL-98  04:47:59  Proc:21-JUL-98 13:46:46
 Tables: Run: a20ju!98b  Analyte:  m8290-23-»  Cal: m8290-23-»Results: M8290-23*
 Version: V3.5 17-APR-1997 11:14:34  Sample text:  1072-5 xl/2

   Amount: 0.46    of which 0.20    named and 0.26    unnamed
     Cone: 0.46    of which 0.20    named and 0.26    unnamed
   Tox #1: -            Tox #2:  -         Tox #3:  -

Name               #     RT Respnse     RA   Cone    Area  Height    S/N  Mod?

                   1  36:20 4.6e+04  4.97 n    0.03
                            4.6e+04                3.8e+04 1.2e+04  1.4e+01 y  n
                                                   7.6e+03 2.6e+03  2.5e+00 n  n
                   2  36:35 4.2e+05  1.11 y    0.23
                            4.2e+05                2.2e+05 6.5e+04  7.4e+01 y  n
                                                   2.0e+05 5.9e+04  5.7e+01 y  n
l,2,3,4,6,7,8-HpCDD3  37:09 3.6e+05  1.04 y    0.20
                            3.6e-*-05                1.8e+05 5.0e+04  5.6e+01 y  n
                                                   1.7e+05 4.8e+04  4.6e+01 y  n
                                                                                                          146

-------
File: A20JUL98B Acq:
21-JUL-1998 04:47:
Sample #11 Text: 1072-5 xl/2 ALS #12
319.8965 S:ll SMO(1,3)
1003
50_
0



24JOO
321.8936 S:ll SMO(1,3)
1002
50J
-
oj




24 TOO
331.9368 S:ll SMO(1,3)
100%

50J
o:



24:00
333.9339 S:ll SMO(1,3)
100%
50J
o:



	 24 loo'
327.8847 S:ll SMO(1,3)
100%
50J
o:



24 loo'
316.9824 S:ll SMO(1,3)
BSUB(128,15,-3.0)
59 Exp: EXP_M23_DB5_OVATION Voltage SIR EH- GC Autospec-UltimaE Paradigm

PKD(3,3,3,0.10%,1476.0,1.00%,F,F)
A1.49E5
A
A
v-v— 	 	 v_^^^- 	 >— X
25100
BSUB(128,15,-3.0)
A6.55E4
A A4.94E4 A .. A4.52E4
/\ A1.30E4 AA2.p7f^ . A1 V^9FA A6.86E3 ^

3.1E4
Ll . 6E4
n npn
26:00 27:00 28:00 29:00 30 00 Time
PKD(3,3,3,0.10%,1392.0,1.00%,F,F)
A1.89E5 A2'/?4E5
An



25100
BSUB(128,15,-3.0)




25:00
BSUB(128,15,-3.0)



25 loo'
BSUB(128,15,-3.0)



25 loo'
PKD(3,3,3,100.00%,
1004 23:16 23:56 24:21 24:55
50 j
ol


24:00


25 loo'
A8.54E4 ,,. .,„_. /I
A A6.87E4 / \
\ A1.46E4 A A2.79E4/ \ A9.35E3
L \ _^c±_ / \ - _y-— — ^^^^ ^x-v ^'V^V \ ••^^•^-"" 	 ^ _^^_
5.2E4
12 . 6E4


26 loo' ' ' ' 27 loo' ' ' ' 28 100 	 29! 00 ' 30:00 Time
PKD(3,3,3,0.10%,6936.0,1.00%,F,F)
A1.61E8 3.4E7
A A1.38E8
/ 1 A
A A


L1.7E7
O.OEO
26:00 27:00 28:00 29:00 30loO Time
PKD(3,3,3,0.10%,4004.0,1.00%,F,F)
A2')?\¥78E8
A A
A/I
4.3E7
.2.2E7
O.OEO
26 100 27 loo 28:00 29loO 30:00 Time
PKD(3,3,3,0.10%,4176.0,1.00%,F,F)
A2.90E8
A
A
/v
_5.9E7
_3 . OE7
O.OEO
26 100 27 100 28 loo' 29! 00 ' ' ' 30:00 Time
0.0,1.00%,F,F)
25:3926:03 26:3326:55 27:2527:4628:10 28:36 29tl3 29:37 5 . OE7


_2 . 5E7
O.OEO
26:00 27:00 28:00 29:00 30:00 Time

-------
File
Samj
355
100S

50_
0_

357.
1008

50_
0'

367.
lOOS
so:
0'

369.
100%
so:
0'

366.
1004
so:
n:

5: A20JUL98B Acq: 21-JUL-1998 04:47:59 Exp : EXP M23 DBS OVATION Voltage SIR EI+ GC Autospec-UltimaE earac-
he #11 Text: 1072-5 xl/2 ALS #12
8546 S:ll F:2 SMO{1,3) BSUB(128, 15, -3 . 0) PKD(3 , 3 , 3 , 0 . 10%, 1328 . 0, 1 . 00%, F, F)
A8.02E4
l\ A5.84E4
/ Al 72E4/A A2'11E4 ^ A3E4
	 ^^_________^_^JA_^_^AJL1/V^^
••• 1 '•••• I '" ' ' I | I I I I I | I i i i I | i i I i i | i I I I i | i i i l i | i i i i l | l i i i r i • r-i-r-T i i 	 i i i i !•, i i i i li"!*1 »* 1 111 I l'TV7\ "pi *7
30:12 30:24 30:36 30:48 31:00 31:12 31:24 31:36 31:48 32:00 32:12 32:24 32:36 32:48 33:00 33:12
8517 S:ll F:2 SMO(1,3) BSUB(128, 15, -3 . 0) PKD(3 , 3 , 3 , 0 . 10%, 1080 . 0, 1 . 00%, F, F)
A5 . 2 OE4
\
A2.50E4
\ A1.47E4 A A1.69E4 A1.86E4
L \ /V 1 \ A/V_A \^\E4 /V^
l i | i 1 f r-T i | i i i i t f I-T-T I'll T-T-r-r-i i i i i i i i i i i i i i i i i i i T"i i i i i i i i i i i 	 i 	 i i i i i i i i i i i i TT'i irT^T r~!mft~^!~i^l
30:12 30:24 30:36 30:48 31:00 31:12 31:24 31:36 31:48 32:00 32:12 32:24 32:36 32:48 33:00 33Tl2
8949 S:ll F:2 SMO(1,3) BSUB(128, 15, -3 . 0) PKD(3 , 3 , 3 , 0 . 10%, 2296 . 0, 1 . 00%, F, F)
Al . 34E8
A
/ \_
1 • • | 	 | 	 | i i i i i | l i i i i | i i i i i | i i i i i l i i i i i i i i i i i i i i i i l i i i i i i i i i i i i i i i i i 'i i i i""Pi i -r^ i i i i i i i i i i i i 1 1
30:12 30:24 30:36 30:48 31:00 31:12 31:24 31:36 31:48 32:00 32:12 32:24 32:36 32:48 33:00 33:12
8919 S:ll F:2 SMO(1,3) BSUB(128, 15, -3 . 0) PKD(3 , 3 , 3 , 0 . 10%, 1280 . 0 , 1 . 00%, F, F)
A8 . 50E7
A
y v^
30:12 30I24 3ol36 3b!48 3l!66 3i!l2 3i!24 31:36 3i!48 32166 32ll2 32:24 32136 32:48 33166 33112
9792 S:ll F:2 SMO(1,3) PKD(3 , 3, 3 , 100 . 00%, 0 . 0, 1 . 00%,F,F)
30:14 30:25 30:43 31:09 31:25 31:38 31:52 32:08 32:30 32:53 33:08


30112 30124 30136 30 148 3lS66 3i!l2 3ll24 31 1 36 ' 31 Us 32166 32112 32124' 32 136 ' 32 Us ' 33 166 ' 33 1 12
igm


2.7E4

.1.4E4

Time

1.7E4

_8.7E3

Time

4 . 6E7
_2.3E7
O.OEO
Time

_2 . 9E7
_1.5E7
O.OEO
Time

_4 . 8E7
.2.4E7
O.OEO
Time
i

-------
File
Samp
389.
1003
50_
0"
391.
iooa
50:
o:
401.
100%
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o:
403.
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0"
380.
lOOi
so:
0'
;: A20JUL98B Acq: 21-JUL-1998 04:47:59 Exp: EXP_M23_DB5_OVATION Voltage
)le #11 Text: 1072-5 xl/2 ALS #12
8156 S:ll F:3 SMO(1,3) BSUB(128, 15 , -3 . 0 ) PKD(3 , 5, 2 , 0 . 10% , 2604 . 0 , 1 . 00%, F,
A1 17F5
A A1.29E5
/ \ / \ / \ A5.19E4 A3-3
SIR EI+ GC Autospec-UltimaE Parad
F)
2E4
\ A5.67E3 	 _^___^_
33:24 33:36 33:48 34:00 34:12 34:24 34:36 34:48 35:00 35:12 35:24 35:36 35:
8127 S:ll F:3 SMO(1,3) BSUB (128 , 15, -3 . 0) PKD(3 , 5, 2 , 0 . 10%, 1664 . 0 , 1 . 00%, F, F)
L A1.07E5
\ A7.49E4 /\
/ \ A / V A2.08E4 A3.57E4
____^HE3 / V. / W AV£3=3 . _^\ - /V J
33J24 33136 33J48 34loO 34J12 34124 34136 34Us 35^00 3s!l2 35J24 3s!36 3s!
8559 S:ll F:3 BSUB(128, 15, -3 .0) PKD(3 , 5 , 2 , 0 . 10%, 9520 . 0 , 1 . 00% , F, F)
A1.39E8 A1.60E8
33.!24 33136 33\48 34!oO 34ll2 34.!24 34136 34i48 31
8530 S:ll F:3 BSUB(128, 15, -3 . 0) PKD(3 , 5, 2 , 0 . 10%, 4440 . 0, 1 . 00%, F, F)
A1.11E8 A1'?>{
5:00 35:12 35:24 35:36 35:
3E8
igm
4.6E4
_2.3E4
.O.OEO
48 Time
3.7E4
.1.9E4
LO.OEO
48 Time
5.8E7
.2.9E7
-O.OEO
48 Time
4.7E7
.2.4E7
.O.OEO
1 1 1 1 1 1 1 1 	 II 1 	 1 1 1 1 I 	 1 1 I T— T—T- 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 I r 1 1 ' 1 1 1 1 1 1 'l 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 I 1 1 | I I 1 ' i
33:24 33:36 33:48 34:00 34:12 34:24 34:36 34:48 35:00 35:12 35:24 35:36 35 48 Time
9760 S:ll F:3 SMO(1,3) PKD(3 , 3 , 3 , 100 . 00%, 0 . 0, 1 . 00%, F, F)
33:31 33:48 34:13 34:26 34:35 34:43 34:59 35:07 35:21 35:43 _9.7E7
7

14 . 9E7
.O.OEO
v— '—I — l—l — 1 — I — l — I — I — 1 — I — r — i — I — I — i — r r r "i i I i i i i i | i i i i i | i i i i i | ' i i i i | i ' i i ' | 	 | ' ' > ' i | ' i ' i i I 	
33:24 33:36 33:48 34:00 34:12 34:24 34136 34:48 35:00 35:12 35:24 35:36 35 48 Time

-------
File: A20JULJ8B Acq: 21-JUL-19W 04 :47 :59
Sample #11 Text: 1072-5 xl/2 ALS #12
423.7767 S:ll F:4 SMO(1,3) BSUB(128, 15, -3 . 0)
100% A2.21E5
t\
A3.80E4 / \
/\ / V
36:00 36:12 36:24 36:36 36:48 37:
425.7737 S:ll F:4 SMO(1,3) BSUB(128, 15, -3 . 0)
100% A1.99E5
50. / \
_ A7.65E3 / V
36166 36112 36124 36:36 SeUs 31?!
435.8169 S:ll F:4 SMO(1,3) BSUB{128, 15, -3 . 0)
100%
so:
36:66 36112 36124 36136 36^8 37 1
437.8140 S:ll F:4 SMO(1,3) BSUB(128, 15, -3 . 0)
IOCS
so:
36166 belid 36124 36\36 36^8 37!
430.9728 S:ll F:4 SMO(1,3) PKD(3 , 3 , 3 , 100 . 00%
100% 36:0336:13 36:34 36:51
so:
36166 36112 36124 36136 36148 37l(
Exp: EXP_M23_DB5
PKD(3,3,3,0.10%
A1.82E5
/v.
66 37l 12 37124
PKD(3,3,3,0.10%
A1.74E5
1, 	
66 37! 12 37. -24
PKD(3,3,3,0.10%
A1.62E8
66 37l 12 37 124
PKD(3,3,3,0.10%
A9 . 78E7
66 37l 12 37 1^
,0.0,1.00%,F,F)
37:09 37:24

30 37! 12 37! 24
_OVATION Voltage SIR EI+ GC Autospec-UltimaE Paradigm
,888.0,1.00%,F,F)
6.6E4
L3.3E4
38E4
/x
\ n riTrn
37:36 37:48 38:00 38:12 38:24 38136 38148 39-00 Time
,1044. 0,1. 00%, F,F)
6.0E4
_3.0E4
37136 37148 38166 38112 38124 38136 38\48 39 00 Time
,4940. 0,1. 00%, F,F)
2.7E7
11.4E7
0 OP.O
1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 I I I T "T-T 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 | | | | | *— " • *"=»"
37:36 37:48 38:00 38:12 38:24 38136 38148 39 00 Time
,2168. 0,1. 00%, F,F)
2 . 6E7
_1.3E7
n.nRn
37136 37U81 38166 38112 38124 38136 bsUs 39 00 Time
37:40 37:5238:02 38:1538:25 3R:43 KKv.1
_3 . 3E7
37:36 37:48 38:00 38:12 38:24 38136 38148 39loO Time
 9
* *.

-------
File
Samj
457
lOOi
50.
0.
459.
1002
50_
o-
469.
100S
50_
o:
471.
100S
so:
o:
454.
100%
so:
o:
>
5: A20JUL98B Acq: 21-JUL-1998 04:47:59 Exp: EXP M23 DBS OVATION Voltage SIR EI + GC Autospec-UltimaE Parad
3le til Text: 1072-5 xl/2 ALS #12
7377 S:ll F:5 SMO(1,3) BSUB (128 , 15, -3 . 0 ) PKD(3 , 3 , 3 , 0 . 10%, 688 . 0 , 1 . 00% , F, F)
A3.98E5
/Y_
39:12 39124 39136 39U8 4o!ob 4o!l2 4ol24 4ol36 4o!48 41
7348 S:ll F:5 SMO(1,3) BSUB(128, 15, -3 . 0) PKD(3 , 3 , 3 , 0 . 10%, 972 . 0, 1 . 00%, F, F)
A4.27E5
f\^
39!l2 39124 39136 39148 4o!ob 4o!l2 4ol24 4ol36 4o!48 41
7780 S:ll F:5 SMO(1,3) BSUB(128, 15, -3 . 0 ) PKD(3 , 3 , 3 , 0 , 10%, 2468 . 0, 1 . 00%, F, F)
A1.42E8
J\_
39:12 39:24 39:36 39:48 40:00 40:12 40:24 40:36 40:48 41:
7750 S:ll F:5 SMO(1,3) BSUB(128, 15, -3 . 0) PKD(3 , 3 , 3 , 0 . 10%, 1592 . 0, 1 . 00%, F, F)
A1.59E8
J\_
39ll2 39124 39136 39148 4o!ob 4o!l2 4ol24 4ol36 40:48 41 !
9728 S:ll F:5 SMO(1,3) PKD{3 , 3 , 3 , 100 . 00%, 0 . 0, 1 . 00%, F, F)
39jlO 39:20 39:30 39:37 ' 40iOO 40ilO 40:22 40:41 40^50
'
39:12 39:24 39:36 39:48 40:00 40:12 40:24 40:36 40:48 41.
igm
9.4E4
L4.7E4
.O.OEO
00 Time
1.1E5
_5.4E4
-O.OEO
00 Time
3.3E7
.1.6E7
.O.OEO
00 Time
3.7E7
.1 . 8E7
O.OEO
00 Time
_7.2E7
_3 . 6E7
O.OEO
00 Time
en

-------
File: A20JUL98B Acq:
21-JUL-1998 04:47:59 Exp: EXP_M23_DB5_OVATION Voltage SIR EI+ GC Autospec-UltimaE Paradigm
Sample #11 Text: 1072-5 xl/2 ALS #12
303.9016 S:ll SMO{1,3)
100*,

50.
0_


A2.86E5
24 :00'
305.8987 S:ll SMO(1,3)
100%,
"
50 j
o;


A3.58E5
	 24 loo'
315.9419 S:ll SMO(1,3)
iooa
50J
o:



T i i i T | r
24:00
317.9389 S:ll SMO(1,3)
100%
50 j
o:



24:00
375.8364 S:ll SMO(1,3)
100%
50J
OJ


BSUB(128,15,-3.0) PKD(3
A2.1
/
A9.19E5 /
A2.94E5A A6^2E5 /
^ /v J W/T\ /
25 100
BSUB(128,15,-3.0) PKD(3
A2.7
A
A1.20E6 /
A3.91E5A A8.68E5 /
^ yx J \-^Y\ /
25 loo'
BSUB(128,15,-3.0) PKD(3




25:00
BSUB(128,15,-3.0) PKD(3



25:00
BSUB(128,15,-3.0) PKD(3

oc.no

,3, 3, 0.10%, 1072
5E6
1

1 A5.47E5
\ xxA /V
26loO
,3, 3, 0.10%, 1460
7E6

1
1 A7 . 68E5
26loo'
,3, 3, 0.10%, 3792



i | ( I i r
26:00
,3, 3, 0.10%, 4076



26:00
,3, 3, 100. 00%, 76


n23/e° 23:5624,j17 25:09/r 25-55 26:
^-^/U_/V^_fVvyV. 	 ./W\_ ^A_^\~/V-S^ ^DX°A 	 ^ J
24 loo'
316.9824 S:ll SMO(1,3)
25:00
PKD(3, 3, 3,100. 00%, 0.0,1
26:00
00%,F,F)

.0,1.00%,F,F)
_3.9E5
.12E6 A1'f1E6 A1.20E6
AA7.92E5/\ A
A / \ / \A4.09E5
. / V i V J v y\
-
L2.0E5
• O.OKO
27:00 28:00 29:00 30 00 Time
.0,1.00%,F,F)
,_5.3E5
A2 .37E6
.50E6 A A1.51E6
A/\ A
. A/V /V5^E5

.2.7E5
O.OEO
27loO 28IOO 29100 3oloO Time
.0,1.00%,F,F)
A1.62E8
A
A
A
3.3E7
_1.7E7
O.OEO

27 100 28 100 29 100 3oloO Time
.0,1.00%,F,F)
A2 . 07E8
A
f[

4.2E7
.2 . 1E7
O.OEO
27:00 28:00 29:00 30:00 Time
0,1.00%,F,F)
27:55 ^1.2E4
A
2T5 A 28:26 29K33
^IA*- A/V J VAv, A **A**29& A /K
-6.1E3
O.OEO
27:00 28:00 29:00 30:00 Time

100*23:16 23:56 24:21 24:55 25:3926:03 26:3326:55 27:2527:4628:10 28:36 29:13 29:37 5.0R7
;
50J
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> 24 I 00



25100



2eloo




.2 . 5E7
O.OEO
27:00 28:00 29:00 30:00 Time

-------
File: A20JUL98B Acq: 21-JUL-1998 04:47:59
Sample #11 Text>
339.8597 S:ll F:2
1001
50'

0:



A1.95E5
30:12 30:24
341.8568 S:ll F:2
100%
50 j
-
0:



A1.24E5
30:12 36124
351.9000 S:ll F:2
100%,
50 j
o:

30:12 36124
353.8970 S:ll F:2
100%
50J
o:



30:12 30:24
409.7974 S:ll F:2
100%
-
50J
,
0"

30:19
V Ax^vs/^
^\/ \s v-\y
i i i | i i i i i | i i
30:12 30:24
366.9792 S:ll F:2
100% 30:14 30:25
50J
o:


30:12 30:24
Exp: EXP_M23_DB5_OVATION Voltage SIR EI+ GC Autospec-UltimaE Paradigm
1072-5 xl/2 ALS #12
SMO ( 1 ,
3) BSUB(128,15,-3.0)
PKD (3, 3, 3,
0.10%, 1400. 0,1. 00%, F,F)

A1.23E6



' sols'e
SMO ( 1 ,




36:36
SMO ( 1 ,


36136
SMO ( 1 ,



i i i 1 i i
30:36
SMO ( 1 ,





30:48 31:00 31:12
3) BSUB(128, 15, -3 .0)

/ \
/ A1.35E5
J v_/-\
3il24 31
PKD ( 3 . 3 . 1 .
A8.52E5



30:48 31:00 31:12
3) BSUB(128,15,-3.0)


30:48 3l!6d 3lSi2
3) BSUB(128,15,-3.0)



30:48 31:00 31:12
3) BSUB(128,15,-3.0)

30 : 59
f\

/ \ 10 c
/ A1.18E5
31:24 31
PKD(3,3,3,


31124 31
PKD (3,3,3,



31:24 31
PKD(3,3,3,


A2 .88E5

:36 31:48 32:66 32!i2
0.10%,2248.0,1.00%,F,F)


A2.06E5

:36 31:48 32:66 32!l2'
0.10%,912.0,1.00%,F,F)
A1.79E8
A
!36 3l!48 32166 32!i2
0.10%,1792.0,1.00%,F,F)
A1.15E8


•36 31:48 32:00 32:12

A2.96E5
/Vx
3.4E5
.1.7E5

.O.OEO
32124 32I36 32!48 33166 33:12 Time



A1.97E5
/Vx
2.4E5
Ll.2E5

.O.OEO
32124 32I361 32148 33l6o 33!i2 Time

A1.76E8 _6.5E7
/\
L3.2E7
:O.OEO
32124 32!36 32148 33166 33:12 Time

A1.12E8
A
f[

4 . 1E7
12 . 1E7
.O.OEO
' 32124 32136 32148 33166 33ll2 Time
100. 00% ,2548. 0,1. 00%, F,F)
31:46
31-38 A ,i.«
3VB 30:51 /\ ,1:1, /S A /\ A7T.

^s V S^
30:36
SMO(1,
_A U v^v,
^^^ \^J ^\/^ N/
i i i i i ' i i > i i i i i i i i i
30:48 31:00 31:12
3) PKD(3,3,3,100.00%
30:43 31:09


i i i 1 i i
30:36


30:48 31:00 31:12
y\/ V~v
^r V v^
31:24 31
,0.0,1.00%,
M / vv v \J\ /V
Vy v L/ v
•36 31:48 32:00 32:12
F,F)
31:25 31:38 31:52 32:08


31:24 31


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33:01 _8.9E3
32-22 32U37 A
A /\ / \ 33:12
/y v^v^y \ /\j)2:48 / \ Ax
v ^-A^^y XV v
•
14.5E3
-
-O.OEO
' 32124 32136 32148 33166 33112 Time

32:30 32:53 33:08 4.8E7


_2.4E7
O.OEO
32:24 32:36 32:48 33:00 33:12 Time
tn

-------
File: A20JUL98B
Sample #11
373.8207 S:
100%
50 j


Text
11 F:
Al
Acq: 21-JUL-199U 04:4
7759 — ExpT
EXP_M2 3_DB5_OVATION
: 1072-5 xl/2 ALS #12
3 SMO(1,3)
.43E5
A
A6.63E4 \

' 33 ! 24
375.8178 S:
100%
;
-
50J
f\l
33
11 F:
Al
\
136 33i
3 SMO(1,3)
.13E5
BSUB(128,15

,-3.0) PKD(3,5,2,0.


10%, 2316

.0,

Voltage SIR EI+ GC Autospec-UltimaE Paradigi

1.00%,F,F)
C

A1.05E5
r\
A2 . 87E4
48 34:00
BSUB(128,15

/YY
34 1 12

34-124
,-3.0) PKD(3,5,2,0.


A3.63E4
34136
10%, 1364


34
.0,


	 J
_2
0
:48 35IOO 35ll2 35124 3s!36 35:48
1.00%,F,F)

/\ A9.23E4
A5.70E4 \ A

33:24
383.8639 S:
100%
50^
n •


01 i i 1 i
33:24
385.8610 S:
100%

50.
0-



< i i i i
33:24
445.7555 S:
10 OS
\
50-
Q •
A;
33
11 F:



i i i i
33
11 F:



i i i — r
33
11 F:
\A9.0
•36 33:
A3.77E4
7E3/\^
48 34:00
/v\
34ll2
3 BSUB(128,15,-3.0) PKD(3,5,2,0.



| i i ' i ' 1
•36 33:



48 34 loO
A9.89E7
A A
j V V 	
34:12
3 BSUB(128,15,-3.0) PKD(3,5,2,0.
A1.91E8
A



1 1 1 1 1 1 1
!36 33:
3 SMO(1,3)



48 34.!00
BSUB(128,15


,
34ll2
A1.18E4
34124
10%, 26004



34-24
10%, 52804



34124
A2.39E4
34136
.0,1.00%



34-136
.0,1.00%



34:36

34
,F,



34
,F,



34
,-3.0) PKD(3,3,3,100.00%,1076.
A9.33E3
4

•_2
:0
Us 35:00 35ll2 35:24 35:36 35:48
F)



4
.2
0
Us 35:00 35:12 35:24 35:36 35:48
F)



8
.4

0
Us 35100 35ll2 35:24 35:36 35:48
0,1.00%,F,F)
^4r5R _7
34:44 A
r-\ / \


A r\
'33 1 24
380-9760 S
100%
4> w UX
50J
0-
1


r. ' i i i i
33:24

33:31

T 	 1 	 1 	 T-
33
11 F:
33 L31



T" T" 1 	 T-
33

33:43
^— ^_s-^~\s~^
1 i i i ' ' 1
136 33:
3 SMO(1,3)
	 _33_i



1 i i i i i 1
•36 33:

33:58 H
^^X^-vA-^^V
48 34:00

:06
-\
^- ~v^ — — ^, . — . *r—
34 1 12
PKD(3,3,3,100.00%,0.0
.48 	 34j_13 _



48 ' ' 34 !00



34l 12

34:2334:.

34^24
A
/
3J^V
J
34136
34:26 '34:35 34:



34124



34136
/\
V

34
43



34
/ \ 35:25
N^^Z V_^ 	 !3^i^ V^-^r/vZ_X^/


.3

0
Us 35100 35:12 35:24 35136 35:48
34:59 35:07 35:21 35:43 9



_4

0
Us 35100 35ll2 35:24 35:36 35:48



. E
.7E4
.OEO
Time

.OE4

.OE4
.OEO
Time
"i r*i*7
.3E7
.2E7
.OEO
Time
.2E7
.1E7

.OEO
Time
.7E3

.9E3

.OEO
Time
.7E7
.9E7

.OEO
Time

-------
   File: A20JUL98BAcq:  21-JUL-1998  04:47:59   Exp:  EXP_M23_DB5_OVATION Voltage SIR EI+GC Autospec-UltimaEParadigm
   Sample #11  Text:  1072-5  xl/2   ALS #12
   407.7818 S:ll F:4  SMO(1,3)  BSUB(128,15,-3.0)  PKD(3,3,3,0.10%,1804.0,1.00%,F,F)
   100%.               A1.36E5
       36:00  36:12  36:24  36:36  36:48   3
409.7788 S:ll F:4 SMO(1,3) BSUB(128,15,-3.0)  PKD(3 , 3,3 , 0.10%,1124.0,1.00%,F,F)
100%,              A1.43E5
                                                                                                    3836
 50.:

  OJ
                             A2 .87E4
                           ,—V\
                                                                                                                   4.7E4

                                                                                                                  _2.4E4
                                                                                                                  .O.OEO
                                                                                                               39:00  Time
                                                                                                                      4. 8E4

                                                                                                                     _2.4E4
                                                             A9.05E3
                                                                                                                      O.OEO
            T
                =T=r f i i i i i  i i i i i i i i  i i p i i  i i i i i i~ii^T~r-i i r~r*i i i i i i i "Pi n i i i  i i i i i i  i i \ i i .  i i . i i i  i i r~i . i i  i~i i i i i  i i i .
       36iOO  36:12  36:24  36:36   36:48   37:00  37:12  37:24  37:36  37:48  38:00  38:12  38:24  38136   38148   39100  Time
   417.8253 S:ll F:4 SMO(1,3) BSUB(128,15,-3.0) PKD(3,3,3,0.10%,3040.0,1.00%, F, F)
   100%
    50J
     o
                                                             A3.46E7
                                                                                                                      l . 5E7
                                                                                                                  L7.3E6
                                                                                                                   O.OEO
                     36:24  36:36  36:48  37:00  37:12  37:24
       36:00  36::
419.8220 S:ll F:4 SMO(1,3) BSUB(128,15,-3.0)  PKD(3,3,3,0.10%,8164.0,1.00%,F,F)
100*              A1.09E8
                                                                        37148  38166  38112  38124  38li6
    50J

     OJ
       i  i i i i i i  i
                                                            A8.00E7
39:00  Time

    3.3E7

   _1.7E7

   .O.OEO
            I I I 1 I I'T-TT^TT'I \f I  I I I rT"l"t"T'l 1 ! I I II—I T T I T ' I" I  I 'T""l" T""r T T T FT *l ^"f 'I I I I I I  I I—I I T I I 'I I 1 ' T' 'I I—I I I' I I 1  I I I I I I  I III I I  I I1 I1" I
          36:00   36:12  36:24   36:36  36:48  37:00  37:12  37:24  37:36  37:48  38:00   38:12   38:24   38:36   38:48   39:00  Time
   479.7165 S:ll F:4 SMO(1,3) BSUB(128,15,-3.0) PKD(3,3,3,100.00%,3440.0,1.00%,F,F)
   100*35.56                     36;40

    50j

     ol

                                                                                                                  1.1E4

                                                                                                                  L5.7E3

                                                                                                                  O.OEO
       36:00   36:12   36:24  36:36  36:48  37:00  37:12  37:24  37:36  37:48  38:00  38:12   38:24   38:36
30.9728  S:ll  F:4 SMO(1,3)  PKD(3,3,3,100.00%,0.0,1.00%,F, F)
004      36j03 36:13	36:34     36:51      37:09    37:24    37:40  37:5238:02  38:1538:25  38:37
                                                                                                                  39oO  Time
    50J

     ol
                                                                                                                     6 . 6E7
                                                                                                                  _3.3E7

                                                                                                                  O.OEO
         36:00 ' 36:12  36:24  36:36  36:48  37:00  37:12  37:24  37:36  37:48  38:00  38:12   38:24   38:36 '  38148 ' 39:00  Time
W

-------
File: A20JUt98B Acq :~2 1 - JUL- r59¥~fl4~FT
Sample #11 Text: 1072-5 xl/2 ALS #12
441.7427 S:ll F:5 SMO(1,3) BSUB(128,15
100!
50.
0.



39ll2 39!24 39!36
443.7398 S:ll F:5 SMO(1,3) BSUB(128,15
1008
50_
o"



39ll2 39.!24 39736
469.7780 S:ll F:5 SMO(1,3) BSUB(128,15
100S
50 1
OJ



39!l2 39!24 39:'36
471.7750 S:ll F:5 SMO(1,3) BSUB(128,15,
100%
50J
OJ



39:12 39124 39136
513.6775 S:ll F:5 SMO(1,3) BSUB(128,15,
100%
"
50.:
, :
0-

39:28
39-14 I~~\
Y\^, / \

39:12 39:24 39:36
7:59 Exp: EXP_M23_DB5_OVATION Voltage SIR EI + Gt Autospec-OltimaE Paradigm
,-3.0) PKD (3, 3, 3, 0.10%, 908. 0,1. 00%, F,F)
A1.Q4E5 2.3E4
/\
/ Y___
Ll.lE4

39:48 40:00 40:12 40:24 40:36 40:48 41 00 Time
,-3.0) PKD (3, 3, 3, 0.10%, 1728. 0,1. 00%, F,F)
Al - 04E5
/\
y \_^ _
2.7E4
L1.4E4

39:48 40:00 40:12 40:24 40:36 40:48 41 00 Time
-3.0) PKD(3,3,3,0.10%,2468.0,1.00%,F,F)
Al . 42E8
f\
J \^__
3.3E7
L1.6E7
• n nwn
i i i | i i i < i | i i i i (' | T— r— T — i — r— i — i — i — i — i — i — i — i — i — i — i — i — i — i — i — i — i — i — .-w . .,— «
39:48 40:00 40:12 40:24 40:36 40:48 41 00 Time
-3.0) PKD (3, 3, 3, 0.10%, 1592. 0,1. 00%, F,F)
A1.59E8
l\
J ^. 	
3.7E7
Ll.8E7
- O.OEO
39:48 4o!ob 4o!l2 40:24 40:36 ' ' 40:48 ' ' ' 4l!oO Time
-3.0) PKD (3, 3, 3, 100. 00%, 172. 0,1. 00%, F,F)
40:00 6.8E3
l\
1 \
39:51 / V 40:27 40:44
__f3J-Cy^~\/^\ _-/ ^ V>— - -~^~\_-— — / \^~^-^ ^-/"'^V 	 \^ /~^\—S'

.3.4E3

n. ORn
39:48 40:00 40:12 40:24 40:36 -.- 40:48 41 00 Time
454.9728 S:ll F:5 SMO(1,3) PKD (3 , 3 , 3 , 100 . 00%, 0 . 0 , 1 . 00%, F, F)
00ft 39:10 39:20 39:30 39:37
:
50J
ol
r


! 39ll2 39!24 39!36
40:00 40:10 40:22 40i41 40:50 7 . 2R7




.3 . 6E7
n nv.n
1 i ' | i i i i i | i ' i i i | i i ' i i 1 	 i i T 1-1 	 1 	 1 	 1 	 1 r i 	 1 	 1* 	 • - — -
39:48 40:00 40:12 40:24 40:36 40:48 41:00 Time

-------
o.
      in   22-JUL-1998
                                      Page 1
         Filename
           Sample
         Acquired
        Processed
        Sample ID
        Cal Table
    Results Table
         Comments
 Typ
 Unk
 ES/RT
        a21ju!98f
        15
        22-JUL-98  04:46:12
        22-JUL-98  08:34:55
        1072-5 xl/2
        07feb-m23conf
        M8290-23-072198F
 Total
 DPE
 LMC
              Name;     Resp;
      2,3,7,8-TCDF; 3.10e+06;
  13C-2,3,7,8-TCDF; 4.34e+08;
      Tetra Furans; 2.88e+07;
            HxCDPE;        *;
QC CHK ION (Tetra);        *;
   Ion 1;
1.356+06;
1.90e+08;
3.17e+05;
   Ion 2;
1.756+06;
2.43e+08;
3.79e+05;
  RA;?;
0.77;y;
0.78,-y;
0.84,-y;
                                                                                                                                              Page 2
   RT;
27:54;
27:53;
18:12;
   Cone ;
  0.753;
106.314;
  6.986;
    DL;
0.0442;

0.0442;
                          ;NotFnd;
                          ;NotFnd;
S/N1;?;
  48;y;
 980;y;
  20 ;y;
   *;n
DivO;n
S/N2;?
  56 ;y
 713 ;y
  21;y
mod?
  no
  no
  no
  no
  no
                                                                     27:54
                                                                -;-; 27:54

-------
OPUSquan   22-JUL-1998
                   Page  1
 Ent: 3  Name: Tetra Furans
                                                Page 1 of 1

                F:l   Mass:  303.902  305.899 Mod? no   #Hom:34
 Run: 20 File: a21ju!98f    S:15 Acg:22-JUL-98 04:46:12 Proc:22-JUL-98 08:34:55
 Tables: Run: a21ju!98b  Analyte: m23_conf    Cal: 07feb-m23»Results:  M8290-23»
 Version: V3.5 17-APR-1997 11:14:34  Sample text: 1072-5 xl/2
   Amount: 6.99
   •  Cone: 6.99
   Tox #1: -
Name
of which 0.75
of which 0.75
     Tox #2:  -

#     RT Respnse
named and 6.23
named and 6.23
      Tox #3: -
                                        RA
                   1  18:12 7.0e+05  0.84 y
                            7.0e+05

                   2  19:39 2.2e+04  3.06 n
                            2.2e+04

                   3  19:51 1.2e+06  0.89 n
                            1.2e+06

                   4  19:59 2.6e+04  4.97 n
                            2.6e+04

                   5  20:01 3.4e+04  6.68 n
                            3.4e+04

                   6  20:05 3.1e+05  1.79 n
                            3.1e+05

                   7  20:22 6.8e+05  1.24 n
                            6.8e+05

                   8  20:40 3.8e+05  1.18 n
                            3.8e+05

                   9  21:12 7.6e+05  0.73 y
                            7.6e+05

                   10 21:33 8.8e+05  0.85 y
                            8.8e+05

                   11 21:49 6.0e+04  1.57 n
                            6.0e+04

                   12 21:51 3.3e+04  0.59 n
                            3.3e+04

                   13 21:57 8.7e+04  0.80 y
                            8.76+04

                   14 22:10 3.3e+06  0.75 y
                            3.36+06

                   15 22:35 6.0e+05  0.88 y
                            6.06+05

                   16 23:17 2.9e+06  0.76 y
                            2.96+06

                   17 23:27 4.3e+05  0.89 n
                            4.3e+05

                   18 24:19 3.0e+06  0.76 y
                            3.0e+06

                   19 25:01 l.le+06  0.71 y
                            l.le+06
          Cone

           0.17


           0.01
               1
               c
           0.29
               c
               «
           0.01

               4
           0.01
               2
               4
           0.08

               ]
           0.16
               i

           0.09

               1
           0.18

               4
           0.21
unnamed
unnamed
                                                      Area  Height    S/N  Mod?
                                3.2e+05  6.3e+04  2.0e+01 y  n
                                3.8e+05  7.96+04  2.1e+01 y  n
                               L
                                1.6e+04  7.1e+03  2.3e+00 n  n
                                5.4e+03  3.9e+03  l.le+00 n  n
                               9
                                5.6e+05  l.le+05  3.4e+01 y  n
                                 .3e+05  l.le+05  3.1e+01 y  n

                                2.2e+04  1.46+04  4.4e+00 y  n
                                4.4e+03  4.9e+03  1.3e+00 n  n

                                2.9e+04  1.3e+04  4.26+00 y  n
                                4.4e+03  4.9e+03  1.3e+00 n  n
                               3
                                2.0e+05  3.7e+04  1.2e+01 y  n
                                l.le+05  2.9e+04  7.86+00 y  n
                               5
                                3.86+05  7.26+04  2.3e+01 y  n
                                3.0e+05  6.7e+04  1.8e+01 y  n
                                2.16+05 3.6e+04 1.2e+01 y  n
                                1.76+05 4.26+04 l.le+01 y  n
                               3
                                3.2e+05 5.96+04 1.96+01 y  n
                                 .46+05 7.46+04 2.0e+01 y  n
                            0.01
                            0.01
                            .0.02
                            0.79
                            0.14
               4.1e+05 6.0e+04 1.96+01 y  n
               4.8e+05 7.0e+04 1.9e+01 y  n
               L
               3.7e+04 1.5e+04 4.7e+00 y  n
               2.36+04 1.3e+04 3.56+00 y  n
               L
               1.2e+04 7.26+03 2.3e+00 n  n
               2.1e+04 9.86+03 2.7e+00 n  n
               2
               3.96+04 l.le+04 3.56+00 y  n
               4.86+04 1.5e+04 4.0e+00 y  n
               }
               1.46+06 2.36+05 7.46+01 y  n
               1.9e+06 2.96+05 7.76+01 y  n
               1
               2.8e+05 4.6e+04 1.5e+01 y  n
               3.2e+05 5.3e+04 1.4e+01 y  n
                            0.70
                            0.10
                            0.72
                            0.27
                1.2e+06  1.7e+05  5.3e+01 y  n
                1.6e+06  2.2e+05  5.9e+01 y  n
               3
                2.0e+05  3.6e+04  l.le+01 y  n
                2.3e+05  4.16+04  l.le+01 y  n
               2
                1.3e+06  1.8e+05  5.8e+01 y  n
                1.7e+06  2.4e+05  6.6e+01 y  n
               7
                4.6e+05  6.1e+04  2.0e+01 y  n
                6.4e+05  8.7e+04  2.4e+01 y  n
                                                                                                    r
                                                                                                          1S8

-------
OPUSguan 22-JUL-1998
20 25:11 9
9

21 25:28 2
2

22 26:33 4
4

23 27:34 1
1

2,3,7,8-TCDF 24 27:54 3
3

25 28:31 4
4

26 28:33 4
4

27 29:00 3
3

28 29:02 3
3

Page 2
.6e+03 0.67 y
.6e+03

.4e+06 0.72 y
.4e+06

.5e+05 0.71 y
.5e+05

.le+05 0.14 n
.le+05

.le+06 0.77 y
.le+06

.3e+05 0.37 n
.3e+05

.6e+05 0.47 n
.6e+05

.3e+04 0.24 n
.3e+04

.3e+04 0.24 n
.3e+04


0.00
3
5
0.58
1
\
0.11
1
2
0.03
1
9
0.75
1
1
0.10
1
3
0.11
1
3
0.01
6
2
0.01
6
2


.8e+03
.8e+03

.Oe+06
.4e+06

.9e+05
.6e+05

.3e+04
.5e+04

.4e+06
.76+06

.2e+05
.le+05

.5e+05
.le+05

.2e+03
.6e+04

.4e+03
.6e+04


2
4

1
1

2
3

5
2

1
2

3
4

3
4

4
8

4
8


.7e+03
.le+03

.3e+05
.7e+05

. 9e+04
. 8e+04

.6e+03
.3e+04

.5e+05
.le+05

.5e+04
. 8e+04

.6e+04
.8e+04

.2e+03
.8e+03

.7e+03
.8e+03


8
1

4
4

9
1

1
6

4
5

1
1

1
1

1
2

1
2


.7e-01
.le+00

.3e+01
.7e+01

. le+00
. Oe+01

. 8e+00
.3e+00

.8e+01
.6e+01

.le+01
.3e+01

.2e+01
.3e+01

.4e+00
.4e+00

.5e+00
.4e+00


n
n

y
y

y
y

n
y

y
y

y
y

y
y

n
n

n
n


n
n

n
n

n
n

n
n

n
n

n
n

n
n

n
n

n
n
29 29:04 4.0e+04   0.51  n    0.01
         4.0e+04

30 29:36 2.46+06   0.36  n    0.57
         2.4e+06

31 29:38 2.5e+06   0.41  n    0.59
         2.5e+06

32 31:32 1.3e+04   1.34  n    0.00
         1.3e+04

33 31:47 1.2e+05   0.62  n    0.03
         1.2e+05

34 31:49 3.8e+05   0.75  y    0.09
         3.8e+05
3e+04 6.7e+03  2.le+00 n  n
6e+04 8.8e+03  2.4e+00 n  n

3e+05 1.4e+05  4.4e+01 y  n
7e+06 1.9e+05  5.Oe+01 y  n

2e+05 1.4e+05  4.3e+01 y  n
7e+06 1.9e+05  5.Oe+01 y  n

2e+03 3.7e+03  1.2e+00 n  n
4e+03 4.5e+03  1.2e+00 n  n

5e+04 1.9e+04  6.le+00 y  n
2e+04 2.3e+04  6.26+00 y  n

6e+05 3.0e+04  9.6e+00 y  n
2e+05 3.5e+04  9.6e+00 y  n
                                                                                    159

-------
  file: A21JUL98F  Acq:  22-JUL-1998  04:46:12  Exp: M23_DB225 Voltage SIR EI+  GC Autospec-UltimaE  Paradigm
  Sample #15  Text: 1072-5 xl/2   ALS #15
  303.9016 S:15 SMO{1,3) BSUB(128,15,-3.0)  PKD(3,3,3,0.10% , 3132.0,1.00%,F,F)
  100%

   50J

    OJ
                      A1.43E6
         A5.60E5
A3.17E5     A  . A3.29E5
           T
   A
                                 A1.29E6
                                       A1.01E6
                                                                      A1.35E6  A6.27E5
                                                         A
                                                                                                2.3E5

                                                                                                .1.2E5
                                                               A1.86E5
                                                                          Al.64E5
                                                                                                O.OEO
                                                                                                   Time
       16100      ISiOO      20iOO      22:00      24 I o!T' ~ "^eloo^  ' '^sloQ1 ' 'loloo' '  HbTolT'" '  "' 34lob ' ~'
305.8987 S:15 SMO(1,3) BSUB(128,15,-3.0) PKD(3,3,3,0.10%,3700.0,1.00%,F,F)
                                       A1.85E6    A1.69E6

                                                         A1.39E6
                           A6.28E5
                                          II     II     II     II            .
                                                               A2.63E5   M   .     /\       A2.19E5
   50J
    O
           T
A3.79E5

- 1--
                                                                        A1.75E6   A1.73E6
                                       A
                                                                                                2.9E5

                                                                                               :1.4E5
                                             T
                                                                 A
O.OEO
   Time
                                                        T
         16:00      18:00      20iOO      22iOO      24iOO      26iOO      28iOO
  315.9419 S:15 SMO(1,3) BSUB(128,15,-3.0} PKD(3,3,3,0.10%,21812.0,1.00%,F,F)
  100%                                                                  A1.90E8
                                                                 30:00
T^| "t~
 32:00
                                                                                                     i  i  ~ i i  i
                                                                                                        34:00
    OJ
                                                                                                                    2.1E7

                                                                                                                   L1.1E7
O.OEO
   Time
         16:00      18:00      20:00      22:00      24:00      26:00      28:00
  317.9389 S:15 SMO(1,3) BSUB(128,15,-3.0) PKD(3 , 3,3,0.10%,38496.0,1.00%, F, F)
  100%
                                                                 30:00
                                                                                             32:00
                                                                                       34:00
«.,

ie!ob ' ' 18:00 20.'ob 22:00 24-ob 26-ob 28
S)E8

!00 30:00 32:00 34:00
_2 . 8E7
_1.4E7
0 . OEO
Time
    OJ

  375.8364 S:15 SMO(1,3) BSUB(128,15,-3.0) PKD{3,3,3,100.00%,10156.0,1.00%,F,F)
100%
50J
•
o"


16:37
•
ttfw~iMMfyJW***i*j*^
ielob ' ' ' islob
316.9824 S:15 SMO(1,3)
100% 15:4816:45 18:1
50J
, o"


S v— *••-•! 	 1 	 [ 	 1 	 1 T f 1 	 1 	 1—
16:00 18:00
19:51
i
iffl
11 2°:
^AA^. ffl /*
20:00
PKD(3,3,3,100
3 19;51 21


' 2olob '




53 22:45 23:52 25:00 26:17
MAAAWW*/
22lob
.00%, 0.0,
:04 22


22 lob
\FW»AJW^JwWW^^
24:00 26:00
1.00%,F,F)
:4023:41 25:05 26:22


24 : 00 26 : 00


28:31
*»\/Vv^wAvw/vV»«tf
28:00

2.7.;28.28;.29.


-i i i i I I r
28:00


29:38 30:
vWvA/W'M^
solob

29:44 31


' 30:00


51 32:29 ,

7 . 8E4
13 . 9E4

•O.OEO
33:00 34:00 Time

;. 03 .,3,2:1733:15 34;36 4.2E7


.2.1E7
O.OEO
32 lob ' ' 34 lob ' Time
8

-------
                                                                    Paradigm Analytical Labs
                             Analytical Data Summary Sheet
Analyte

2,3,7,8-TCDD
1,2,3,4,7,8-HxCDD
l,2,3,7,8,9^HxCDD
OCDD
2,3,7,8-TCDF
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
1,2,3,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
OCDF
Total TCDDs
Total PeCDDs
Total HxCDDs
Total HpCDDs
Total TCDEs_
Total PeCDFs
Total HxCDFs
Total HpCDFs
TEQ (ND=0)
TEQ (ND=l/2)
Concentration

EMPC
ND
EMPC
EMPC" *'
- - ND 3
ND
ND
EMPC
ND
ND
ND
0.0026
ND
EMPC
ND
ND
ND
ND
._...ND--~-
ND
ND
0.0028
0.0000
0.0006
,r;vr3|J*"5£S'"i3
*m&&&s&k&fb&
0.0005
0.0006
0.0004
6.0006
4. -4$$^S1
0.0004
0.0004
0.0003
O.OOQ2
0.0003
0.0003
0.0006
0.0007
0.0007
0.0005
0.0003
0.0004
0.0004
—0.0007
0.0004
0.0002
0.0006

8^tEIiflH£ "

0.0007
0.0012
0.0076



0.0008




0.0015
0.0006
0.0012
0.0060
0.0064
. .._ 	

0.0012

0.0012
0.0014
•lUT ' '-•
SI^NM
28:27
'*" 34.41"'
34:59
40:01
" ^27:26 :


34:11
34:15

35:08
36:21
40:09









Ratio

1.16
2.06
0.92
0 91
0.75*"
1.31


1.76
0.92

3.66
0.99
1.2




	




Qiiafifipr



1 ./

















ITEF
ITEF
Client Information

Project Name:
Sample ID:

Laboratory Information

Project ID:
Texas Lime Kiln
M24-FB-4
Sample Information

Matrix:
Weight/Volume:
                                               Air
                                                1
                                               0.0   %
Collection Date:
                            21-M-98
                        Initial Cal:
                                                                                          161
                                        1/2

-------
                                                                         Paradigm Analytical Labs
                               Analytical Data Summary Sheet
         Labeled
         Standard
                                                                 JBT.
                                                                                    Qualifier
Extraction Standards
Cir2,3,7,8-TCDD

Cirl,2,3,6,7,8-HxCDD
3C12-OCDD
3C12-l,2,3,6,7,8-HxCr)F
3C12-l,2,3,4,6,7,8-HpCDF
Sampling Standards
37
Cl,-2,3,7,8-TCDD
3Ci2-2,3,4,7,8-PeCDF
13
  Ci2-l,2,3,4,7,8-HxCDF
I3Cu-l,2,3,4,7,8,9-HpCDF
Injection Standards
13CU-1,2,3,4-TCDD
13C12-l,2,3,7,8,9-HxCDD
                                 8
                                 J"
                                 4
                                 4
                                 4
                                 4
                                 4
                                 4
                                 4
                                             3.20
                                                       79.9
                                                                 28:26
                                                                  34:45
                                            7.00
                                            2.59
                                            3.37
                                            2.66
                                                       87.5
                                                      WigX'.'/
                                                        'A.
                                                       64.8
                                                       84.4
                                                       66.4
                                             4.18
                                            3.22
                                            !3.39
                                                       104.5
                                                       99.0
                                                       80.5
40:01
27:24
31:56
34:14
36:20
28:27
32:24
34:41
34:10
37:30


28:09
34:58
0.78

1.26

0.89
1.55
0.52
0.44
 1.54
 1.24
 0.51
 0.44

 0.78
 1.25
Client Information
Project Name:
Sample ID:

Laboratory Information

Project ID:
Sample ID:

Collection Date:
Receipt Date:
                           Texas Lime Kiln
                           M24-FB-4
                            L1Q72-
                            10'
                                                     Sample Information

                                                     Matrix:
                                                     Weight /Volume:
                                                     Moisture / Lipids:
 Reviewed by:
                                                                              Air
                                                                               1
                                                                              0.0
                                                                           a20jul98b-12
                                                                           a20ju!98b-l
                                                                           a20jul98b-2
                                                                                         ( •
                                                                                                162
                                            2/2

-------
C an 21-JUL-1998
Filename a20ju!98b
Sample 12
Acquired 21-JUL-98 05
Processed 21-JUL-98 13
Sample ID 1072-6 xl/2
Page 1


:33:04
:47:29









































Cal Table m8290-23-071798
Results Table M8290-23-072098B
Comments
Typ
Unk
Onk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
ES/RT
ES
ES
ES
ES
ES/RT
ES
ES
ES
JS
JS
CS
CS
CS
CS
CS
SS
SS
SS
SS
SS
Name;
2,3,7,8-TCDD; 2
1,2,3,7,8-PeCDD; 2
1,2,3,4,7,8-HxCDD; 2
1,2,3,6,7,8-HxCDD; 4
1,2,3,7,8,9-HxCDD; 7
1,2,3,4,6,7,8-HpCDD; 1
OCDD; 3
2,3,7,8-TCDF; 5
1, 2,3,7, 8-PeCDF;
2,3,4,7,8-PeCDF;
1,2,3,4,7,8-HxCDF; 5
1,2,3,6,7,8-HxCDF; 3
2,3,4,6,7,8-HxCDF;
1,2,3,7,8,9-HxCDF; 1
1,2,3,4,6,7,8-HpCDF; 1
1,2,3,4,7,8,9-HpCDF;
OCDF; 6
13C-2,3,7,8-TCDD; 3
13C-l,2,3,7,8-PeCDD; 2
13C-l,2,3,6,7,8-HxCDD; 2
13C-1,2,3,4, 6,7,8-HpCDD; 2
13C-OCDD; 3
13C-2,3,7,8-TCDF; 3
13C-l,2,3,7,8-PeCDF; 2
13C-l,2,3,6,7,8-HxCDF; 3
13C-l,2,3,4,6,7,8-HpCDF; 1
13C-1,2,3,4-TCDD; 3
13C-l,2,3,7,8,9-HxCDD; 3
37Cl-2,3,7,8-TCDD; 2
13C-2,3,4,7,8-PeCDF; 3
13C-l,2,3,4,7,8-HxCDD; 1
13C-l,2,3,4,7,8-HxCDF; 1
13C-l,2,3,4,7,8,9-HpCDF; 9
37Cl-2,3,7,8-TCDD; 2
13C-2,3,4,7,8-PeCDF; 3
13C-l,2,3,4,7,8-HxCDD; 1
13C-l,2,3,4,7,8-HxCDF; 1
13C-l,2,3,4,7,8,9-HpCDF; 9

Resp;
.32e+05;
.96e+04;
.39e+04;
.34e+04;
.22e+04;
.31e+05;
.22e+05;
.43e+04;
* .
* .
.32e+04;
.64e+04;
* .
.05e+04;
.26e+05;
* .
.69e+04;
.31e+08;
.36e+08;
.78e+08;
. 19e+08;
. 37e+08;
.76e+08;
. 93e+08;
.14e+08;
.50e+08;
.77e+08;
.OOe+08;
.91e+08;
.OOe+08;
.816+08;
. 99e+08;
. 97e+07;
.91e+08;
.OOe+08;
.81e+08;
. 99e+08;
.97e+07;

Ion 1;
2.836+04;
1.99e+04;
1. 15e+04 ;
2.12e+04;
3.44e+04;
7.476+04;
1.38e+05;
3.08e+04;
* .
* .
3.396+04;
1.74e+04;
* .
8.266+03;
6.246+04;
* ,
3.656+04;
1.45e+08;
1.44e+08;
1.55e+08;
1.126+08;
1.586+08;
1.656+08;
1.78e+08;
1.07e+08;
4.61e+07;
1.65e+08;
1.67e+08;
2.916+08;
1.826+08;
1. OOe+08 ;
6.746+07;
3.046+07;
2.916+08;
1.82e+08;
1. OOe+08 ;
6.74e+07;
3.04e+07;

Ion 2;
2.04e+05;
9.666+03;
1.24e+04;
2.22e+04;
3.78e+04;
5.67e+04;
1.84e+05;
2.356+04;
* ,
* .
1.93e+04;
1.896+04;
* .
2.26e+03;
6.32e+04;
* .
3.046+04;
1.866+08;
9.226+07;
1.23e+08;
1.07e+08;
1.786+08;
2.12e+08;
1.15e+08;
2.07e+08;
1.04e+08;
2.12e+08;
1.33e+08;
_;
1.18e+08;
8.09e+07;
1.316+08;
6.93e+07;

1.186+08;
8.09e+07;
1.316+08;
6.93e+07;


0
2
0
0
0
1
0
1


1
0

3
0

1
0
1
1
1
0
0
1
0
0
0
1

1
1
0
0

1
1
0
0

RA;?; RT;
.14,-n; 28:27;
.06;n; 32:37;
.92;n; 34:41;
.95;n; 34:46;
.91;n; 34:59;
.32;n; 37:10;
.75;n; 40:01;
.31;n; 27:26;
*;n;NotFnd;
*;n;NotFnd;
-76;n; 34:11;
.92;n; 34:15;
*;n;NotFnd;
.66;n; 35:08;
.99;y; 36:21;
*;n;NotFnd;
.20,-n; 40:09;
.78;y; 28:26;
.56;y; 32:37;
.26;y; 34:45;
.04;y; 37:09;
.89;y; 40:01;
.78;y; 27:24;
.55;y; 31:56;
. 52 ;y; 34:14;
. 44 ;y; 36:20;
-78;y; 28:09;
.25;y; 34:58;
-;-; 28:27;
. 54 ;y; 32:24;
.24;y; 34:41;
.51;y; 34:10;
.44;y; 37:30;
-,--; 28:27;
.54;y; 32:24;
.24;y; 34:41;
.51;y; 34:10;
.44;y; 37:30;

Cone ;
0.071;
0.011;
0.014;
0.018;
0.030;
0.067;
0.190;
0.015;
* .
* .
0.020;
0.011;
* .
0.004;
0.066;
* .
0.037;
79.865;
81.785;
85.861;
91.430;
175.052;
72.388;
64.830;
84.340;
66.373;
78.247;
75.772;
76.626;
67.704;
84.952;
68.456;
56.284;
95.998;
104.469;
99.033;
80.533;
84.829;

DL;
0.0121;
0.0081;
0.0143;
0.0103;
0.0105;
0.0093;
0.0149;
0.0168;
0.0111;
0.0107;
0.0077;
0.0060;
0.0070;
0.0080;
0.0138;
0.0168;
0.0173;
0.0365;
0.0205;
0.0418;
0.0152;
0.2122;
0.0201;
0.0073;
0.1654;
0.0607;
— ;
-;
0.0146;
0.0075;
0.0633;
0.2122;
0.0776;
0.0189;
0.0070;
0.0726;
0.2192;
0.1532;

S/N1;?;
6;y;
4;y;
2;n;
4,-y;
4;y;
20;y;
32 ;y;
4;y;
*;n;
*;n;
6;y;
3;n;
*;n;
l;n;
11 ;y;
*;n;
12,-y;
4074;y;
21980;y;
6182 ;y;
12523 ;y;
712,-y;
7096;y;
231009;y;
1387;y;
1282;y;
4826;y;
6569;y;
14883;y;
248086;y;
5143;y;
966;y;
771;y;
14883 ;y;
248086;y;
5143;y;
966;y;
771 ;y;

S/N2 ; ?
28;y
3;y
3;y
5;y
6;y
28;y
52 ;y
2;n
*;n
*;n
5;y
6;y
*;n
l;n
25;y
*;n
6;y
11193;y
17765;y
6399,-y
13469;y
23793;y
16958;y
19472 ;y
2011;y
4310;y
13171;y
680 6, -y
-; -
21262;y
5501, -y
1412 ;y
2602;y
_ . _
21262;y
5501 ;y
1412;y
2602;y
mod?
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
                                                                                                                                           Page 1
CO

-------
OPUSquan   21-JUL-1998
                   Page  1
                                                                    Page 1  of 8

 Ent: 39 Name: Total Tetra-Furans  F:l  Mass: 303.902 305.899 Mod? no   #Hom:2

 Run: 17 File: a20ju!98b    S:12 Acq:21-JUL-98 05:33:04 Proc:21-JUL-98 13:47:29
 Tables: Run: a20ju!98b  Analyte: m8290-23-»  Cal: m8290-23-»Results: M8290-23*
 Version: V3.5 17-APR-1997 11:14:34  Sample text: 1072-6 xl/2
   Amount: 0.03
     Cone: 0.03
   Tox #1: -
Name
2,3,7,8-TCDF
of which 0.02
of which 0.02
     Tox #2:  -

#     RT Respnse
named and 0.01
named and 0.01
      Tox #3: -
                                        RA
1  24:32 3.9e+04  0.79 y
         3.9e+04

2  27:26 5.4e+04  1.31 n
         5.46+04
          Cone

           0.01
               1
               2
           0.02
   unnamed
   unnamed
                                                      Area  Height    S/N  Mod?
 1.7e+04  4.9e+03  3.6e+00 y  n
 2.2e+04  7.1e+03  2.6e+00 n  n
I
 3.1e+04  5.4e+03  3.9e+00 y  n
 2.3e+04  4.9e+03  1.8e+00 n  n
                                                                    Page 2 of 8

 Ent:  40 Name: Total Tetra-Dioxins F:l  Mass: 319.897 321.894 Mod? no   ttHom:5

 Run:  17 File: a20ju!98b    S:12 Acq:21-JUL-98 05:33:04 Proc:21-JUL-98 13:47:29
 Tables: Run:  a20ju!98b  Analyte: m8290-23-»  Cal: m8290-23-»Results:  M8290-23»
 Version: V3.5 17-APR-1997  11:14:34  Sample text: 1072-6 xl/2
   Amount:  0.11
     Cone:  0.11
   Tox #1:  -
of which 0.07
of which 0.07
     Tox #2: -
named and 0.04
named and 0.04
      Tox #3: -
Name
                         RT Respnse
                                        RA
                       25:14  3.7e+04   1.28 n
                             3.7e+04
 2,3,7,8-TCDD
2  27:10 l.Se+04  9.46 n
         l.Se+04

3  27:24 5.9e+04  3.26 n
         5.9e+04

4  28:27 2.3e+05  0.14 n
         2.3e+05

5  29:52 1.5e+04  0.50 n
         1.5e+04
          Cone

            0.01

               ]
            0.00
               3
               ]
            0.02
               t,
               3
            0.07


            0.00
    unnamed
    unnamed
                                                      Area  Height
                                                   S/N  Mod?
 2.1e+04 5.2e+03 4.6e+00 y  n
 1.6e+04 5.5e+03 3.6e+00 y  n

 1.3e+04 3.16+03 2.8e+00 n  n
 1.4e+03 6.06+02 3.9e-01 n  n

 4.5e+04 9.6e+03 8.5e+00 y  n
 1.4e+04 3.3e+03 2.1e+00 n  n
7
 2.86+04 6.5e+03 5.8e+00 y  n
 2.06+05 4.2e+04 2.8e+01 y  n
                                                    4.9e+03 1.8e+03  1.6e+00  n  n
                                                    9.8e+03 3.4e+03  2.2e+00  n  n
                                                                     Page 3 of 8

  Ent: 41 Name: Total Penta-Furans  F:2  Mass:  339.860 341.857 Mod? no   #Hom:2

  Run: 17 File: a20ju!98b    S:12 Acq:21-JtJL-98 05:33:04 Proc:21-JUL-98 13:47:29
  Tables: Run: a20ju!98b  Analyte: m8290-23-»  Cal: m8290-23-»Results: M8290-23*
  Version: V3.5 17-APR-1997 11:14:34  Sample text: 1072-6 xl/2
    Amount: 0.02
      Cone: 0.02
    Tox #1: -
 Name
 of which *
 of which *
      Tox #2:  -

 #     RT Respnse
 named and 0.02
 named and 0.02
       Tox #3: -
                                         RA
                    1  30:15 3.8e+04  4.97 n
                             3.8e+04

                    2  32:29 1.3e+04  1.88 n
           Cone

            0.01
                3
                6
            0.00
    unnamed
    unnamed
                                                       Area  Height
                                   S/N  Mod?
                                 3.1e+04 8.7e+03 6.8e+00 y  n
                                 6.3e+03 2.3e+03 l.le+00 n  n
                                                                                                           164

-------
OPUSquan   21-JUL-1998
                   Page 2
                            1.36+04
                                8.2e+03 2.6e+03 2.0e+00 n  n
                                4.4e+03 1.96+03 9.2e-01 n  n
                                                                   Page 4 of  8

 Ent: 42 Name: Total Penta-Dioxins F:2  Mass:  355.855 357.852 Mod? no   tHom:5

 Run: 17 File: a20ju!98b    S:12 Acq:21-JUL-98 05:33:04 Proc:21-JUL-98  13:47:29
 Tables: Run: a20ju!98b  Analyte: m8290-23-»  Cal:  m8290-23-»Results: M8290-23*
 Version: V3.5 17-APR-1997 11:14:34  Sample text:  1072-6 xl/2
   Amount: 0.06
     Cone: 0.06
   Tox #1: -
Name
1,2,3,7,8-PeCDD
of which 0.01
of which 0.01
     Tox #2:  -
named and 0.05
named and 0.05
      Tox #3: -
                         RT Respnse
                                        RA
   31:29 4.8e+04  2.57 n
         4.8e+04

   32:24 5.8e+04  4.56 n
         5.8e+04

   32:31 7.2e+03  2.21 n
         7.2e+03

   32:37 3.0e+04  2.06 n
         3.0e+04

   32:43 7.4e+03  0.60 n
         7.46+03
          Cone

           0.02

               ]
           0.02
               4
               ]
           0.00
               c

           0.01

               c
           0.00
   unnamed
   unnamed
                                                      Area  Height
                                                                      S/N  Mod?
 3.4e+04  l.le+04 7.4e+00 y  n
 1.3e+04  4.4e+03 4.2e+00 y  n

  .7e+04  1.3e+04 8.7e+00 y  n
  .Oe+04  2.9e+03 2.8e+00 n  n

 5.0e+03  1.9e+03 1.3e+00 n  n
 2.2e+03  7.3e+02 6.9e-01 n  n
1
 2.0e+04  6.0e+03 4.1e+00 y  n
 9.76+03  3.5e+03 3.3e+00 y  n
0
 2.86+03  1.26+03 8.2e-01 n  n
 4.6e+03  2.1e+03 2.0e+00 n  n
                                                                                                         165

-------
OPUSquan   21-JUL-1998
                   Page 3
 Ent: 43 Name: Total Hexa-Furans
                                                 Page  5  of  8

                F:3  Mass:  373.821  375.818 Mod? no   #Hom:10
 Run: 17 File: a20ju!98b    S:12 Acq:21-JUL-98 05:33:04 Proc:21-JUL-98  13:47:29
 Tables: Run: a20ju!98b  Analyte: m8290-23-»  Cal:  m8290-23-»Results: M8290-23*
 Version: V3.5 17-APR-1997 11:14:34  Sample text:  1072-6 xl/2
   Amount: 0.07
     Cone: 0.07
   Tox #1: -
Name
of which 0.03
of which 0.03
     Tox #2:  -

#     RT Respnse
named and 0.04
named and 0.04
      Tox #3:  -
                                        RA
                   1  33:31 1.6e+04  2.30 n
                            1.6e+04

                   2  33:38 4.2e+04  0.89 n
                            4.2e+04

                   3  33:47 6.6e+03  0.86 n
                            6.6e+03

                   4  33:55 1.6e+04  1.80 n
                            1.66+04

                   5  33:59 l.le+04  0.78 n
                            l.le+04
1,2,3,4,7,8-HxCDF  6
   34:11 5.3e+04  1.76 n
         5.3e+04
1,2,3,6,7,8-HxCDF  7  34:15 3.6e+04  0.92 n
                            3.66+04

                   8  34:59 1.2e+04  1.38 y
                            1.2e+04

1,2,3,7,8,9-HxCDF  9  35:08 l.le+04  3.66 n
                            l.le+04

                   10 35:14 3.1e+03  0.57 n
                            3.1e+03
          Cone

           0.01
               3
               4
           0.01
               2
               2
           0.00
               3
               3
           0.01
               a
               c
           0.00
               t,
               «
           0.02

               ]
           0.01
               1
               1
           0.00
               6
               C
           0.00
               £
               2
           0.00
    unnamed
    unnamed
                                                      Area  Height    S/N  Mod?
 l.le+04 4.2e+03  2.2e+00  n  n
 4.7e+03 1.9e+03  1.7e+00  n  n

 2.0e+04 6.8e+03  3.5e+00  y  n
 2.2e+04 7.6e+03  7.1e+00  y  n
3
 3.0e+03 9.0e+02  4.7e-01  n  n
 3.56+03 1.4e+03  1.3e+00  n  n
L
 l.Oe+04 3.4e+03  1.8e+00  n  n
 5.6e+03 1.6e+03  1.5e+00  n  n
D
 4.7e+03 1.36+03  6.96-01  n  n
 6.0e+03 l.le+03  l.le+00  n  n

 3.4e+04 l.le+04  5.7e+00  y  n
 L.96+04 5.8e+03  5.4e+00  y  n

 1.7e+04 5.4e+03  2.8e+00  n  n
 1.9e+04 6.5e+03  6.0e+00  y  n
D
 6.86+03 3.0e+03  1.5e+00  n  n
 5.0e+03 1.6e+03  1.4e+00  n  n
                                8.3e+03 2.16+03 l.le+00 n  n
                                2.3e+03 l.le+03 l.le+00 n  n
                               D
                                l.le+03 4.7e+02 2.4e-01 n  n
                                2.0e+03 l.le+03 l.Oe+00 n  n
                                                                    Page 6 of 8

 Ent: 44 Name: Total Hexa-Dioxins  F:3  Mass: 389.816 391.813 Mod? no   #Hom:18

 Run: 17 File: a20jul98b    S:12 Acq:21-JUL-98 05:33:04 Proc:21-JUL-98 13:47:29
 Tables: Run: a20ju!98b  Analyte: m8290-23-»  Cal: m8290-23-»Results: M8290-23»
 Version: V3.5 17-APR-1997 11:14:34  Sample text: 1072-6 xl/2
   Amount: 0.22
     Cone: 0.22
   Tox  #1: -
Name
of which 0.06
of which 0.06
     Tox #2: -

#     RT Respnse
named and 0.16
named and 0.16
      Tox #3: -
                                        RA
                    1  33:52 8.7e+04  1.84 n
                            8.7e+04

                    2  34:10 5.8e+04  1.67 n
                            5.86+04

                    3  34:14 6.6e+04  3.68 n
                            6.6e+04

                    4  34:19 7.2e+04  1.03 n
                            7.2e+04
          Cone

           0.04
               c
               1
           0.03
               3

           0.03
               c
               ]
           0.03
    unnamed
    unnamed
                                                      Area  Height
                                  S/N  Mod?
                                5.7e+04 1.8e+04 9.3e+00 y  n
                                3.1e+04 1.2e+04 8.9e+00 y  n
                               3
                                3.6e+04 1.5e+04 7.7e+00 y  n
                                2.2e+04 7.4e+03 5.4e+00 y  n
                               3
                                5.2e+04 1.7e+04 9-Oe+OO y  n
                                1.4e+04 3.6e+03 2.7e+00 n  n

                                3.6e+04 1.2e+04 6.4e+00 y  n
                                                                                                          166

-------
OPUSquan 21-JUL-1998

5 34:26


6 34:36


1,2,3,4,7,8-HxCDD 7 34:41


1,2,3,6,7,8-HxCDD 8 34:46


1,2,3,7,8,9-HxCDD 9 34:59


10 35:12


11 35:16


12 35:22


13 35:25


14 35:29


15 35:33


16 35:38


17 35:43


18 35:47




7
7

6
6

2
2

4
4

7
7

6
6

3
3

8
8

3
3

6
6

9
9

9
9

2
2

2
2

Page 4

.9e+03 0.38 n
. 9e+03

.7e+03 0.79 n
.7e+03

.4e+04 0.92 n
. 4e+04

.3e+04 0.95 n
.3e+04

.2e+04 0.91 n
.2e+04

.Oe+03 0.21 n
.Oe+03

.8e+03 4.99 n
. 8e+03

.2e+03 1.95 n
.2e+03

.7e+03 0.36 n
.7e+03

.le+03 0.89 n
.le+03

.4e+03 0.74 n
.4e+03

.2e+03 0.89 n
.2e+03

.4e+03 0.63 n
.4e+03

.9e+03 4.96 n
.9e+03


3
0.00
2
5
0.00
3
3
0.01
1
1
0.02
2
2
0.03
3
3
0.00
1
4
0.00
3
6
0.00
5
2
0.00
9
2
0.00
2
3
0.00
4
5
0.00
4
4
0.00
9
1
0.00
2
4

.5e+04

.2e+03
.7e+03

.Oe+03
.8e+03

.le+04
.2e+04

.le+04
.2e+04

.4e+04
. 8e+04

.Oe+03
. 9e+03

.2e+03
-3e+02

.4e+03
.8e+03

.8e+02
.8e+03

.9e+03
.2e+03

.Oe+03
.4e+03

.3e+03
.9e+03

.2e+02
.5e+03

.4e+03
.9e+02

1

9
1

1
1

4
4

7
6

7
8

4
1

1
3

1
1

8
1

1
1

1
2

1
1

5
8

9
2

. Oe+04

. 2e+02
. 8e+03

.3e+03
.3e+03

.2e+03
. 5e+03

.2e+03
. 9e+03

.6e+03
.5e+03

.8e+02
.Oe+03

.Oe+03
.5e+02

.6e+03
.le+03

.7e+02
.le+03

.2e+03
.4e+03

.4e+03
.3e+03

.4e+03
.8e+03

.2e+02
.5e+02

.6e+02
.9e+02

7

4
1

6
9

2
3

3
5

3
6

2
7

5
2

8
8

4
8

6
1

7
1

7
1

2
6

5
2

.4e+00

. 8e-01
.4e+00

.6e-01
.7e-01

.2e+00
.3e+00

.7e+00
.le+00

.9e+00
.3e+00

.5e-01
.5e-01

.4e-01
.6e-01

.Oe-01
.3e-01

.5e-01
.3e-01

.2e-01
.Oe+00

.5e-01
.7e+00

.4e-01
.3e+00

.7e-01
.3e-01

.Oe-01
.le-01

y

n
n

n
n

n
y

y
y

y
y

n
n

n
n

n
n

n
n

n
n

n
n

n
n

n
n

n
n

n

n
n

n
n

n
n

n
n

n
n

n
n

n
n

n
n

n
n

n
n

n
n

n
n

n
n

n
n
167

-------
OPUSquan   21-JUL-1998
                  Page 5
                                                                    Page 7  of  8

 Ent: 45 Name: Total Hepta-Furans  F:4  Mass:  407.782  409.779  Mod?  no   #Hom:l

 Run: 17 File: a20ju!98b    S:12 Acq:21-JUL-98 05:33:04 Proc:21-JUL-98  13:47:29
 Tables: Run: a20ju!98b  Analyte: m8290-23-»  Cal:  m8290-23-»Results: M8290-23*
 Version: V3.5 17-APR-1997 11:14:34  Sample text:  1072-6 xl/2
   Amount: 0.07
     Cone: 0.07
   Tox #1: -
Name
of which 0.07
of which 0.07
     Tox #2:  -

#     RT Respnse
named and *
named and *
      Tox #3:  -
                                        RA
1,2,3,4,6,7,8-HpCDFl  36:21 1.3e+05  0.99 y
                            1.36+05
          Cone

           0.07
unnamed
unnamed
Area  Height    S/N  Mod?
                                6.2e+04  2.0e+04  l.le+01 y n
                                6.3e+04  2.0e+04  2.5e+01 y n
                                                                    Page 8 of 8

 Ent: 46 Name: Total Hepta-Dioxins F:4  Mass: 423.777 425.774 Mod? no   #Hom:4

 Run: 17 File: a20ju!98b    S:12 Acq:21-JUL-98 05:33:04 Proc:21-JUL-98 13:47:29
 Tables: Run: a20ju!98b  Analyte: m8290-23-»  Cal: m8290-23-»Results: M8290-23*
 Version: V3.5 17-APR-1997  11:14:34  Sample text: 1072-6 xl/2
    Amount:  0.16
      Cone:  0.16
    Tox #1:  -
 Name
of which 0.07
of which 0.07
     Tox #2: -

#     RT Respnse
named and 0.09
named and 0.09
      Tox #3: -
                                        RA
                    1   36:20  4.9e+04   3.43 n
                             4.9e+04

                    2   36:35  9.4e+04   0.87 n
                             9.4e+04

 l,2,3,4,6,7,8-HpCDD3   37:10  1.3e+05   1.32 n
                             1.3e+05

                    4   37:30  3.0e+04   2.41 n
                             3.0e+04
          Cone

           0.02

               ]
           0.05
               4
               c
           0.07
               1
               C
           0.02
unnamed
unnamed
                                                      Area  Height
                                  S/N  Mod?
                                3.8e+04 1.2e+04 l.le+01 y  n
                                l.le+04 3.5e+03 5.8e+00 y  n

                                4.3e+04 1.4e+04 1.3e+01 y  n
                                5.0e+04 1.5e+04 2.6e+01 y  n
                               7
                                7.5e+04 2.2e+04 2.0e+01 y  n
                                5.7e+04 1.6e+04 2.8e+01 y  n
                                2.1e+04 7.4e+03 6.8e+00 y  n
                                8.8e+03 2.0e+03 3.4e+00 y  n
                                                                                                        168

-------
File: A20JUL98B Acq:
21-JUL-1998 05:33:04 Exp: EXP_M23_DB5_OVATION Voltage SIR EI+ GC Autospec-UltimaE Paradigm
Sample #12 Text: 1072-6 xl/2 ALS #13
319.8965 S:12 SMO(1,3)
100%,

50_

0_



'-X^v-v/Vv^-^vrA^v^S — ST~S\
24 :00'
321.8936 S:12 SMO(1,3)
1002
50J
I
o-



	 	 ^-^_
24 loo'
331.9368 S:12 SMO(1,3)
100S
50 j
o:



	 24 loo'
333.9339 S:12 SMO(1,3)
1008
50J
o:



24 :00'
327.8847 S:12 SMO(1,3)
100%
50J
ol



24 loo'
316.9824 S:12 SMO(1,3)
100% 23:23 23:57
50 j
OJ


i i F r i | F
24:00
BSUB(128,15,-3.0) PKD(3 , 3 , 3 , 0 . 10%, 1132 . 0, 1 . 00%, F, F)
X,_1.1E4
A2.83E4
A
A1.41E4/\
-^ /J— ^^A^-yVv^p>^\_r^^A^^v^.^^>X»X

_5.5E3

O.OEO
25:00 26:00 27loO 	 28:00 	 29:00 30 I 00 Time
BSUB(128,15,-3.0) PKD(3 , 3 , 3 , 0 . 10% , 1536 . 0, 1 . 00%, F, F)
A2.04E5
A
A
A1.64E4 A1.39E4 / \
	 	 	 __^£^^ —w~^ 	 - — — *^_^_^-^^-«_ -T"^ ^^._ \ S\
4.4E4
L2.2E4

rt m?n
25:00 26:00 27 1 00 28 1 Oo' '' 29:00 	 30:00 Time
BSUB(128,15,-3.0) PKD(3 , 3 , 3 , 0 . 10%, 7244 . 0, 1 . 00%, F, F)
A1<^^S.845E8
y
A/V
3.5E7
Ll.7E7
"O.OEO
25:00 26:00 	 27loO 	 2sloO ' ' '29:0o' ' ' ' 3oloO Time
BSUB(128,15,-3.0) PKD(3 , 3 , 3 , 0 . 10%, 3384 . 0, 1 . 00%, F, F)
I 1 "A
A A
A/V
4 . 5E7
.2.2E7
O.OEO
25:00 26IOO 27loO 28:00 29loO 30:00 Time
BSUB(128,15,-3.0) PKD(3 , 3 , 3 , 0 . 10%, 3896 . 0 , 1 . 00%, F, F)
A2.91E8
A
/ V
_5.8E7
_2 . 9E7
O.OEO
25IOO 26!oO 27loO 2sloO 29loO 	 3o!oO Time
PKD(3,3,3,100.00%,0.0,1.00%,F,F)
24:31 24j53 25:44 26:1826i38 27i01 27:34 27_L59 28 :21 28:43 29:15 29:50 4. 7E7


_2.4E7
O.OEO
i 1 1 ( | i I I i i J • i i i i i i r i i i | i l I I i i i i i i i i
25:00 26:00 27:00 28:00 29:00 30:00 Time
O)

-------
File: A20JUL9«B "Acq: 21-JUL-199S U5:JJ:04 Exp: EXP_M2^_DBb_OVATION Voltage SI!
Sample #12
355.8546 S
100%^
-
so:
;





30:12
357.8517 S
100%


50-
n ~



A ^
u [i i n 1 1
30:12
367.8949 S
100%
-
so:
-




' 3bli2
369.8919 S
100$
•
50_
•




' 30:12
366.9792 S
100%

b°1
n ~
^ "™ '


0 '• i i 1 i i
30:12
I EI+ GC Autospec-UltimaE Paradigm
Text: 1072-6 xl/2 ALS #13
•12 F-2 SMO(1,3) BSUB(128,15,-3.0) PKD(3 , 3 , 3 , 0 . 10%, 1472 . 0 , 1 . 00%, F, F)
A3.44E4 A4^4E4
A A2-A1E4
/ /v
^-Azx_^-A\A-^\

'30124" 36136" 36148' 3ll6o 3lll2 3ll24 3ll36 3lUs 32:00 32ll2
•12 F-2 SMO(1,3) BSUB(128,15,-3.0) PKD(3 , 3 , 3 , 0 . 10%, 1048 . 0, 1 . 00%, F, F)
Al -34E4
1 1
\ A7.72E3
/ \ J\ A3.65E3.
^S^^^^^^^^-v^^^^
' SO1^ ' 36136 36148 31166 3lll2 31124 31136 31:48 32:00 32:12
:12 F:2 SMO(1,3) BSUB( 128, 15, -3 . 0) PKD(3 , 3 , 3 , 0 . 10%, 2320 . 0 , 1 . 00% , F, F)




' 36124 ' 30-36 ' 30148 3ll66 3lll2 3ll24 31:36 siUs 32:66 32:12
:12 F:2 SMO(1,3) BSUB (128, 15, -3 . 0) PKD(3 , 3 , 3 , 0 . 10%, 1828 . 0, 1 . 00%, F, F)




' 36124 ' 36136" 30148 3ll6o 3lll2 3ll24 3ll36 3ll48 32:00 32:12
• 19 P-2 SMOd 3) PKD(3 .3, 3, 100. 00%, 0.0,1. 00%, F,F)
30-32 30:52 31:1231:22 3 ]jll__lU5J_____32jLl3_.



' 30124 ' 36136 30l48 3ll66 3lll2 31124 31136 31:48 32:66 32:12

A1.99E4
A.
/\A8.45E3
k/V/ \S^Y\^~ rS\
_1.3E4

_6.6E3

.O.OEO
32l24 32:36 32148 33:66 33:12 Time

A9.66E3
A A
\l\ A A A
\-L^cvJ VVW W /, p^
5.8E3
.
12 . 9E3

' 0 . OEO
32124 32136 32148 33:66 33:12 Time
A1.44E8 _5.1E7
A


/ I

.2.5E7

10. OEO
32124 32136 32148 33:66 33:12 Time
A9.22E7 ^3.2X1
A


/v
:
11 . 6E7

10. OEO
32124 32136 32J48 33:00 33:12 Time
32:28 32:39 "" 32:57 p4 . 6E7



12.3E7

_O.OEO
32124 32136 32:48 33:66 33:12 Time

-------
File: A20JUL98B Acq: 21-JUL-1998 05:33:04 Exp: EXP M23_DB5_OVATION Voltage SIR EI+ GC Autospec-UltimaE Paradigm
Sample #12 Text: 1072-6 xl/2 ALS #13
389.8156 S:12 F:3 SMO(1,3) BSUB(128 , 15, -3 . 0) PKD (3 , 5 , 2 , 0 . 10%, 1932 . 0 , 1 . 00%, F, F)
1002
-
50J
0"

A5.67E4 A5.16E4
A A /\3.64E4
/ \ /VIA A2.12E4 A3.44E4
/ \ / i \ / \ f\ /"A
/ V ^-_^/~-L-L-Mii!H__^^ /V \-^ J \^ A5.39E3 A4.33E3
2 . OE4

.9.9E3
n ORO
'33! 24' ' '33:3V ' '33 Us' ' '34lo'o' ' '34!l2' ' ' 3412V ' '34! 36' ' '34! 48 35.!00 3s!l2 35I24 35136 35 48 Time
391.8127 S:12 F:3 SMO{1,3) BSUB (128 , 15, -3 . 0) PKD(3 , 5, 2 , 0 . 10%, 1356 . 0 , 1 . 00%, F, F)
100S



50.

n

A3.08E4
A A3.54E4
/\ n A3.78E4
/ \ A2.15E4 /\ A2.22E4 A
/\ A /\ A A
/ \ / PV V-x A3.76E/V L 45 J V A5 . 44E3
—A ^ 	 -, > 	 v __—J 	 la-v ^^-J 1 1 IT\ 	 ^-^/ 1 ^ '^^ ^-^ -^ 	 /> x^V f\ /^^ 	
' — i — i — i — i — i— i — r— i — i — i — i—i — i — i — I — r— i — r— i — r~ i — i — i — i — i — i — i — i — i — i — r — i — I — i — i — i — i — i — i — i — i — T-T-I i i i i r i i i i i i i i i i i i T" | i i1 1 T '-r--V i T i i i
33124 33:36 33:48 34:00 34:12 34:24 34:36 34:48 35:00 35:12 35:24 35:36 35
1.3E4



_6.6E3

0 OEO
48 Time
401.8559 S:12 F:3 BSUB (128, 15, -3 . 0) PKD(3 , 5, 2 , 0 . 10%, 9888 . 0, 1 . 00%, F, F)
10 OS
so:
OJ

A1.55E8 A1.67E8
A A
M A
/ r L / v_
6.5E7
.3.2E7
O.OEO
33J24 33136 33I48 34loO 34^12 34124 34136 34J48 35:00 35:12 35:24 35:36 35 48 Time
403.8530 S:12 F:3 BSUB(128, 15, -3 .0) PKD(3, 5, 2, 0 .10%, 7484 . 0, 1 . 00%, F, F)
10 OS
so:
OJ

A1.23E8 A1.33E8
, A A
M A
/[ L / v_
5.1E7
L2 . 5E7
' O.OEO
33!24 33!36 33148 34loO 34!l2 34124 34^36 34148 35:00 35:12 35:24 35:36 35 48 Time
380.9760 S:12 F:3 SMO(1,3) PKD(3 , 3 , 3 , 100 . 00%, 0 . 0, 1 . 00%, F, F)
100*

so:
0"
33:32 33:56 34:27 34:45 34:55 35:15 35:23 35:35
r


9.4E7

.4.7E7
O.OEO
'33:24 ' 's'shV ' 's'sUV ' '34 -OO 34!l2 34l24 34136 34Us 35^00 35:12 35124 35^36 35:48 Time

-------
file: A20JUL98B Acq: 21-JUL-1998 05:33:04
Sample #12 Text: 1072-6 xl/2 ALS #13
423.7767 S:12 F:4 SMO(1,3) BSUB (128, 15, -3 . 0)
100%
50.
0
425.
1001
50_
0"
435.
100%
50J
0"
437.
100%
50.
0"
430.
100%
50J
0"
Exp: EXP_M23_DB5_OVATION Voltage SIR EI+ GC Autospec-ultimaE Paradigm
PKD(3,3,3,0.10%,1088.0,1.00%,F,F)
A7.47E4 2.3E4
A4.34E4 /\
A3.78E4 /s H
_ LA-.JV
36!6d 36!l2 36I24 36I36 SeUs 37.!
7737 S:12 F:4 SMO(1,3) BSUB(128, 15, -3 . 0)
A5.02E4
A

A1.10E4
	 t 	 _£^_
36:00 36:12 36:24
8169 S:12 F:4 SMO(1,3)

36:00 36:12 36:24
8140 S:12 F:4 SMO(1,3)


A_ .
36:36 36:48 37:
BSUB (128, 15, -3.0)

36:36 36:48 37:
BSUB(128,15,-3.0)

00 37:12
PKD (3,3,3
A5 . 67E4
A
IV
00 37:12
PKD(3,3,3
A1.12E8
/^
00 37:12
PKD(3,3,3
A1.07E8
/^
A2.14E4
37:24 37:36 37:48 38:00 38:12 38:24 38:36 38:48 39
, 0.10%, 596. 0,1. 00%, F,F)

A8.85E3
37:24 37:36 37:48 38:00 38:12 38:24 38:36 38:48 39
,0.10%,2480.0,1.00%,F,F)

37:24 37:36 37:48 38:00 38:12 38:24 38:36 38:48 39
,0.10%,2204.0,1.00%,F,F)

L1.1E4
10.0EO
00 Time
1.7E4
_8.6E3
_O.OEO
00 Time
3.1E7
.1 . 6E7
O.OEO
00 Time
_3 . OE7
11 . 5E7
36:00 36:12 36:24 36:36 36:48 37:00 37:12 37:24 37:36 37:48 38:00 38:12 38:24 38:36 38:48 39 00 Time
9728 S:12 F:4 SMO(1,3) PKD(3 , 3 , 3 , 100 . 00%, 0 . 0, 1 . 00%, F, F)
36:08 36:32 36j_57 37:11 37:24 37:50 38:04 3&OS * 38:50 6.3E7
;
36:00 36:12 36124


36:36 36:48 37:00 37:12

37:24 37:36 37:48 38:00 38:12 38:24 38:36 38:48 39:
.3.2E7
O.OEO
30 Time

-------
File
Samj
457
100S
50.
0.
459.
100S
so:
0"
469.
100%
so:
0
471.
100%
so:
454.
100%
so:
0'
•
;: A20JUL98B Acq: 21-JUL-1998 05:33:04 Exp: EXP M23 DBS OVATION Voltage SIR EI + GC Autospec-UltimaE Parad
3le #12 Text: 1072-6 xl/2 ALS #13
7377 S:12 F:5 SMO(1,3) BSUB (128, 15, -3 . 0) PKD(3 , 3 , 3 , 0 . 10% , 1084 . 0 , 1 . 00%, F, F)
A1.38E5
j\
39:12 . 39:24 39:36 39:48 40:00 40:12 40:24 40:36 40:48 41
7348 S:12 F:5 SMO(1,3) BSUB(128 , 15, -3 . 0) PKD(3 , 3 , 3 , 0 . 10%, 824 . 0 , 1 . 00%, F, F)
A1.84E5
J\M
39:12 39:24 39:36 39:48 40:00 40:12 40:24 40:36 40:48 41
7780 S:12 F:5 SMO(1,3) BSUB(128, 15, -3 . 0) PKD(3 , 3 , 3 , 0 . 10%, 50768 . 0, 1 . 00%, F,F)
A1.58E8
J\_
39:12 39:24 39:36 39:48 40:00 40:12 40:24 40:36 40:48 41
7750 S:12 F:5 SMO(1,3) BSUB( 128, 15, -3 . 0) PKD(3 , 3 , 3 , 0 . 10%, 1700 . 0 , 1 . 00%, F, F)
A1.78E8
f\_
39:12 39:24 39:36 39:48 40:00 40:12 40:24 40:36 40:48 41:
9728 S:12 F:5 SMO(1,3) PKD(3 , 3 , 3 , 100 . 00%, 0 . 0, 1 . 00%, F, F)
39:11 39^36 39:48 40:00 40^09 40:4040:46 40:53

39:12 39:24 39:36 39:48 40:00 40:12 40:24 40:36 40:48 41
igm
3 . 5E4
L1.8E4
00 Time
4.3E4
_2.2E4
00 Time
3 . 6E7
11.8E7
_O.OEO
00 Time
_4.0E7
_2 . OE7
O.OEO
00 Time
_6.9E7
.3.4E7
.O.OEO
00 Time

-------
File: A20JUL98B  Acq:  21-JUL-1998 05:33:04   Exp:  EXP_M23_DB5_OVATION Voltage SIR EI+  Gc Autospec-UltimaE—Paradigm	
Sample  #12  Text:  1072-6  xl/2   ALS #13
303.9016 S:12  SMO(1,3)  BSUB(128,15,-3.0)  PKD(3,3,3,0.10%, 1376.0,1.00%,F,F)
                        A1.74E4                                      A3.08E4  *                                   _7.7E3
                                                               10E4     ft       A1.04E4
                                                                                                                 .3.8E3

                                                                                                                  O.OEO
                 24:00           25:00           26:00           27:00
305.8987 S:12 SMO(1,3)  BSUB(128,15,-3.0)  PKD(3,3,3 , 0.10%, 2764.0,1.00%,F,F)
100%                    A2.20E4
                                                                     A2.35E4
                           I i
 50 A

  OJ
                                               28:00
                                                                                              29:00
                                  T
                                                                 T
                                                                                                              30:00  Time

                                                                                                                   1. 1E4

                                                                                                                  .5.7E3

                                                                                                                   O.OEO
                 24:00          25:00           26:00           27:00
315.9419 S:12 SMO(1,3) BSUB(128,15,-3.0) PKD(3,3,3,0.10%,4764.0,1.00%,F,F)
100%                                                                A1.65E8
 50J

  OJ
                                                                               28:00
                                                              29 loo'
                                                                                                              30:00  Time

                                                                                                                  3.4E7

                                                                                                                 .1.7E7

                                                                                                             1	rJLo.OEO
                                                                                                              30:00  Time

                                                                                                                  4.4E7

                                                                                                                 .2.2E7
                 24:00          25:00           26:00           27:00
317.9389 S:12 SMO(1,3) BSUB(128,15,-3.0) PKD(3,3,3,0.10%,2580.0,1.00%,F,F)
100%                                                                A2.12E8
 50:

  OJ
                                                                                  O.OEO
                 24:00          25:00           26:00           27:00          28:00
375.8364 S:12 SMO(1,3) BSUB(128,15,-3.0) PKD(3,3,3,100.00%,740.0,1.00%,F,F)
100%                                                                                 28;26
                                                              29:00
  0 "
                        24:28
                                                    26:19
       23:24
                   24:10
                                   25:10
                                               25:57
                           ft6:44 27:05
                          VILA _/\  /Vj->__
                                                               27:00
                                                                                                             30:00   Time

                                                                                                                  7.8E3

                                                                                                                 13.9E3
                                                                       29:36
                                              28:00
                29:00
                                                                                 10.0EO
                                                                                                             30:00   Time
                 24:00          25:00          26:00
316.9824 S:12 SMO(1,3) PKD(3,3,3,100.00%,0.0,1.00%, F, F)
100%   23:23    23:57    24:31 24^53	25:44	26:18j6:38 2710J,   27:34  27:59 28:21 28843    29:15    29:50  4. 7E7

 50

  0

_2.4E7
-O.OEO
                24:00
25:00
                                               26:00
                                                               27:00
28:00
29:00
30:00  Time

-------
    :  A20JUL98B  Acq: 21-JUL-1998 05:33:04  Exp: EXP_M23_DB5_OVATION Voltage SIR EI +—GC Autospec-UltimaE—Paradigm
Sample #12  Text: 1072-6 xl/2  ALS #13
339.8597 S : 12 F:2 SMO(1,3) BSUB(128,15,-3.0) PKD(3,3,3,0.10%,1288.0,1.00%,F,F)
                                            A2.58E4                                                              -1'°E4
                                                                               Al.88E4
                                                                      A1.11E4
              A1.36E3                        '   '            -     	'\^A4.65E3
  50J

   OJ
      i ' I ' i  ' i i I i ' i  i i I i i i i  i I	I  i i i i i i i i  i i i I i i i  i i i i i i i  i i i i i i i  I i i i i i I i  i i i i I i  i i i i I i i  i i i I i i  i i i I i i i  i i I i i
      30:12   30:24   30:36  30:48  31:00  31:12   31:24   31:36  31:48  32:00  32:12  32:24  32:36   32:48   33:00   33:12
 341.8568 S:12  F:2 SMO(1,3)  BSUB(128,15,-3.0)  PKD(3,3,3,0.10%,2032.0,1.00%,F,F)
 10°*   A6.33E3
                                                                                                           L5.0E3

                                                                                                            O.OEO
  50J
                      i — i — i — i — i — i — i — i — i — i — i — i — i — i — i — i — i — F— i — i — i — i — i — i — i — i — i — i — i — i — | — i — r — i — i — r~i — i — i — i — i — i — i — i — i — r— i — i — i — i — i — i — i — i — i — r— i — i — i — i — i — i — i — i i i — t i* f -r -i — r"fT-"T"i — i — i — r-
      30:12  30:24  30:36  30:48  31:00  31:12   31:24  31:36  31:48  32:00  32:12  32:24   32:36   32:48  33:00  33:12
351.9000 S:12  F:2  SMO(1,3) BSUB (128, 15, -3 . 0) PKD(3 , 3 , 3 , 0 . 10%, 272 . 0, 1 . 00%, F, F)
100%                                                            A1.78E8         A1.82E8                          _6
  OJ
 .OEO
  Time

 .8E7

I.4E7

I. OEO
  Time

 .4E7

 .2E7

 .OEO
  Time

 .1E3

 .5E3

 .OEO
  Time

 .6E7

 .3E7

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  Time
     30:12  30:24  30:36  30:48  31:00  31:12  31:24  31:36  31:48  32:00  32:12  32:24  32:36  32:48   33:00  33:12
353.8970 S:12 F:2 SMO(1,3)  BSUB(128,15,-3.0)  PKD(3,3,3,0.10%,2064.0,1.00%,F,F)
100%                                                            A1.15E8        A1.18E8

 50J

  OJ
        I i i i i i  I i i i i i I  i i i i i I i  i i i i I i i  i i i I i i r~rr i i i i i i  i i i i i i i  i i 'i i i i" i  i i i i i i i  i 1*1 i IT i  i i i i i i  i i i i i i  i i i i i i i i  i i i
     30:12  30:24  30:36  30:48  31:00   31:12  31:24  31:36  31:48  32:00  32:12   32:24  32:36   32:48   33:00  33:12
409.7974 S:12 F:2 SMO(1,3) BSUB(128,15,-3.0) PKD(3,3,3,100.00%,2452.0,1.00%,F,F)
100!

 50 j

  OJ
30:14
             30:38
                                                                32:06
                                                                                 32:37
                                                                                                      33:01
                                                                                                     33:12
                                                                                                           _3
     30:12  30:24  30:36  30:48  31:00   31:12  31:24  31:36  31:48  32:00  32:12   32:24  32:36  32:48  33:00  33:12
366.9792 S:12 F:2 SMO(1,3) PKD(3,3,3,100.00%,0.0,1.00%,F,F)
100%,             30:32      30:52       31:1231:22    31:37
 50J
                                                        31:53
                                                                          32:13    32:28  32:39
32:57
     30:12  30:24  30:36  30:48  31:00  31:12  31:24  31:36  31:48  32:00  32:12  32:24  32:36  32:48  33:00  33:12

-------
File: A20JUL98B
Sample #12
373.8207
100%,
-
50 "
j
S:

Text:
12 F: 3

Acq: 21-JUL-1998 Ob: 33: 04 Exp: EXP_M23_
1072-6 xl/2
SMO (1,3)

ALS #13
BSUB(128,15,-3.0) PKD(3,5,2,0.

A3.39E4
DB5_OVATION Voltage SIR EI+ GC Autospec-UltimaE Paradigin

10%, 1932. 0,1. 00%, F,F)

A1.99E4 /\


° '33!
375.8178
100%
50-
-





^-51
383.8639
100%
50J
0 "



'33!
385.8610
100%
50J
o •



'Ml
445.7555
100%

50 :
~

•


A
r
'33!
380.9760
100%

50 J
- 0 '
/


33!
A
^.
24
S:




24
S:



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24
S:



24
S:


24

^
24
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1 '33!
12 F: 3
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12 F:3



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33:
12 F:3



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12 F:3
33:32



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34:00 34:12 34:24
BSUB(128,15,-3.0) PKD(3,5,2,0.


S\^-
C3
48
BSUB(128,15



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36 33:
SMO (1,3)



33 :
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SMO (1,3)




36' ' '33!



48
A1.89E4



34:00 34:12 34:24
,-3.0) PKD(3,5,2,0.10%,33956
A1.07E8
A
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T — i — i — | — i — i — r-n — r-1] i — rill I I I
34:00 34:12 34:24
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A2.07E8
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34100 34:12 34124

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34136 34148 3s!oO 3s!l2 3s!24 35J36 35 48
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34:36 34:48 35:00 3s!l2 35:24 35:36 35:48
BSUB(128,15,-3.0) PKD(3 , 3 , 3 , 100 . 00%, 1116 . 0 , 1 . 00%, F, F)



48
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34\00 34:12 34^24
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33:56 34:27



48



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34:00 34:12 34:24
34:58 _7 .
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34:45 34:55 35:15 35:23 35:35 9.




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0.
34136 34148 3s!oO 3s!l2 35124 3s!36 35I48



3E4

3E3
OEO
Time

2E3
1E3

OEO
Time

7E7
4E7
OEO
Time

1E7
5E7
OEO
Time

9E3

9E3

OEO
Time

4E7

7E7
OEO
Time

-------
File: A20JtJL98B
Acq: 21-JUL-1998 05:33:04
Exp: EXP_M23_DB5
_OVATION Voltage SIR EI+ GC Autospec-UltimaE Paradigm
Sample #12 Text: 1072-6 xl/2 ALS #13
407.7818 S:12
1003
50.

0
t

F


4 SMO(1,3)
A6.24E4
A
A
BSUB(128,15,-:


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/ V - A7.34E3
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417.8253 S:12
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36:00
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36:66
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36:36 36:48

37
BSUB(128,15,-3.0)


A6.05E3

' 36:36 ' 36:48
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36:36 36:48
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36:36 36:48
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36:36 36:48
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66 37! 12
PKD(3,3,3





00 37:12
PKD (3,3,3




66 37:12
PKD(3,3,3
37:09

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11 36:32 36:57 37:11



i i i > i I ' i
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i i ' I ' ' ' ' ' 1 ' ' '
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37:36
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37136
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37:48 38:00 38:12 38:24 38:36 38:48 39 00
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37:50 38:04 38^18 38:50 6.



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_3.
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37:48 38:00 38:12 38:24 38:36 38148 39100

2E4
1E4

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Time

1E4
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3E7

7E6
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Time

1E7

5E7
OEO
Time

3E3
2E3
OEO

Time

3E7

2E7
OEO
Time

-------
File: A20JUL98B
Sample #12 Text
441.7427 S:12 F:
100%
50 1




39:12
443.7398 S:12 F:
100%
50 j
0 '


^ _
39 1 12
469.7780 S:12 F:
100%
50J
0 '



u l . . i i 1 i
39:12
471.7750 S:12 F:
100%
50J
:


°-1-i — i — i — i — | — i—
39:12
513.6775 S:12 F:
100%
•
50.:
-
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39:09 3

39:12
454.9728 S:12 F:
100% T Q • 1 1
50J
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"-1— 1 — 1 — 1 — 1 — 1 — I—
39:12
Acq: 21-JUL-199« Ob:JJ:0
4 Exp: EXP_M23.
_DB5_OVATION Voltage
SIR EI+ GC Autospec-UltimaE Paradigm
: 1072-6 xl/2 ALS #13
5 SMO (1,3)



39124
5 SMO (1,3)


— — ~— ^- 	 •
T 	 1 	 1 	 1 	 1 	 r
39:24
5 SMO (1,3)



39:24
5 SMO(1,3)



39:24
5 SMO(1,3)



9:17
^\_ 39:
39124
5 SMO (1,3)


T 	 1 	 1 	 1 	 T 	 • 1
39:24
BSUB(128,15,-3



—i 	 1 	 1 	 1 	 1 	 r 	 1 	 r
39:36
BSUB(128,15,-3


/ ^ — ^-- — \^
— i 	 r — i — T- iiii
39:36
BSUB(128,15,-3



39:36
BSUB(128,15,-3



39136
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39:33
26 rV-^
39136
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39:36


39136
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— i — i — | — i — i — i — i — r-
39:48 40
.0) PKD(3,3,3,0


-— -—v^^x 	 -^
3 9 Us 40
.0) PKD(3,3,3,0
Al
/
/
39:48 40
.0) PKD(3,3,3,0
Al
/
/
39148 40
.10%, 844. 0,1. 00%, F,F)
A3 -.65E4
A
^ y v. .
lob 4oll2
.10%, 1516. 0,1. 00%, F,
A3 . 04E4
/ v>
^—^- — -CL-^~_
lob 4oll2
.10%, 50768. 0,1. 00%, F
.58E8
V

lob 4o!i2
.10%, 1700. 0,1. 00%, F,
.78E8

V
lob 4o!i2
.0) PKD (3, 3, 3, 100. 00%, 144. 0,1. 00% ,F
4
/
/
39:49 J

39:48 40
1:01
\
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00%, 0.0,1. 00%, F,F)
39:48 40:00 40:09


39. -48 40


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A1.74E3 /^X____
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— • 	 -s 	 	 	 '~jr~\^/~\~-S— 	 ^S^ 	 -~ 	 \
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F)



4 . OE7
_2 . OE7
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40:24 40:36 40:48 41:00 Time
,F)


40:24

_jJ V-^^X (/"V^r-^Si? *
5.8E3
' 2 9E3


LO.OEO
40:24 40136 4ol48 41:00 Time
40:4040:46 40:53 6 . 9E7


_3.4E7
O.OEO
40124 40:36 40:48 41:00 Time

-------
                                                                      Paradigm Analytical Labs
                              Analytical Data Summary Sheet
:-'.::&;*•*&* -T^
2,3,7,8-TCDD
1 ^,3,?^eOCSD '. , -;?: j!^::^
1,2,3,4,7,8-HxCDD
1,2,3,6,7,8-ifaCDD
1,2,3,7,8,9-HxCDD
U^ j| j£ T Q ^T-Tft f**l ' VT\ "
js*j_\j' f -ff™ jrTp*i_i*iji*il-'*
OCDD
2,3,7,8-TCDF
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
U,3,7,8,9-HxCDF
1,2,3,4,6,7,8-HpCDF
U,3,4,7,8,9-I^)CDF
OCDF
Total TCDDs
Total PeCDDs
Total HxCDDs
Total HpCDDs
Total TCDFs
Total PeCDFs
Total HxCDFs
Total HpCDFs
TEQ (ND=0)
TEQ (ND=l/2)

EMPC

ND

EMPC
' ijj^c-1''"'^
0.0051
EMPC
ND
EMPC
EMPC
EMPC
ND
ND
0.0006
ND' "• ~*'
ND
ND
ND
0.0016
0.0008
ND
ND
ND
0.0008
0.0000
0.0005

0.0004

0.0005

0.0004
;';'^0HK*'^
0.0004
0.0006
0.0004
0.0004
0.0003
0,0002
0.0003
0.0003
0.0005
0.0006
0.0006
0.0004 :i
0.0003
0.0004
0.0003
0.0006
0.0004
0.0002
0.0005



0.0010


SIS5^
0.0009
'f"'^QOi7

0.0012

0.0006
0.0008
0.0003





**Q£Q3
-------
                                                                         Paradigm Analytical Labs
                               Analytical Data Summary Sheet
                                                                            Ratio
                                                                                   Quatifier
Extraction Standards
13C12-2,3,7,8-TCDD
13Cirl)2>3>6,7,8-HxCDD
 3CI2-OCDD
 drl^.T.S-
 C12-l,2,3,7,8-PeCDF
 Qrl^ej.S-HxCDF
 C12-l,2,3,4,6,7,8-HpCDF
Cleanup Standards
3?yti  ** -*i •-
 1C12-2,3,4)7)8-PeCDF
uCirl,2,3A7,8-HxCDD
 'C12-l,2,3,4,7,8-HxCDF
13C12-U,3,4,7,8,9-HpCDF
Injection Standards
 3Ci2-l,2,3,4-TCDD
 3C12-l,2,3,7,8,9-HxCDD
                                 8
                                 4
                                 4
                                 4
                                 4
                                 4
                                 4
                                             3.58
                                            3.34
6.66
2.81
2.96
3.03
3.00
                                            3.16
3.35
3.57
           89.5
          S8P
           83.4
          $#»:
           83.2
                                                        73.9
                                                        75J
                                                        75.0
           96.2
           78.9
           83.8
           89.3
                                                                 28:25
34:45
37:09
40:00
27:24
31:56
34:13
36:20
                                                                  28:27
                                                                  32:23
                                                                  34:41
                                                                  34:09
                                                                  37:30

                                                                  28:08
                                                                  34:58
                                0.77
1.25
1.04
0.89
0.78
1.56
0.52
0.44
1.57
1.23
0.52
0.44

0.79
1.25
Client Information
Project Name:
Sample ID:
Laborator Information
Collection Date:
Receipt Date:
Extraction Date:
Analysis Date:

Reviewed by:
                           Texas Lime Kiln
                           M23-I-3FH
        Sample Information

        Matrix:
        Weight/ Volume:
                                                                             Air
                                                                              1
                                                                             0.0
                                                                             NA
                                                                          a20j
                                                                                     Grams
                                                                     DateReviewecl:
                                           2/2

-------
                                                                       Paradigm Analytical Labs
Analytical Data Summary Sheet
Analyte ~ -.—
•Ms^t*-.«#u»~~*. A ^ x
2,3,7,8-TCDD
t *» a:*f-.'4}*'»j^/-irvr» » ",""-'';.'!;•" '-'~*9t'
I,2,l,^^riSCJJ13 *••-_. • *>,
1,2,3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDiD
1,2,3,7,8,9-HxCDD
1,2,3,4,6,7,8-HpCDD
OCDD
2,3,7,8-TCDF
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
1,2,3,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
OCDF
Total TCDDs
Total PeCDDs
Total HxCDDs
Total HpCDDs
Total TCDFs
Total PeCDFs
Total HxCDFs
Total HpCDFs
TEQ (ND=0)
TEQ (ND=l/2)

gaga r. •; r; » a»fetea» ggggj ;; v j uuHE
EMPC
''••^llPfiP^,, .";
" \ ""•,'**'/; Vl> '>,'•«<%'•', — ^*'''«
ND
ND
EMPC
EJiitfC
0.40
EMPC
ND
EMPC
EMPC
EMPC
ND
ND- =• ;-
0.050
ND
ND
ND
ND
0.12
0.062
ND
ND
ND
0.062
0.0009
0.042
0.030

0.038
Q.Q2?
0.027
0.024
0.035
0.043
0.031
0.030
0.024
0.018
0.021
•MM££.-
0.041
/'O.dif :•:•:
0.045
O.B30
0.026
0.027
0.024
0.043
0.030
0.018
0.041


0.077
ifert^Si . . -, •


0.068
043

0.10

0.050
0.062
0.025

--,-


*
0.25

0.37
0.37
0.09
0.062
0.09

0.13
0.14
i^W'-^i

28:27
^3^fH
34:46
34j4§
34:58
5¥^S
40:01
27:26

32:24
34:09
34:13


36:21

40:10










Igapo-

1.16
0.95
0.80
0.8
1.51
0*1
w»*?-**- \ --.
0.85
0.98

1.16
2.45
2.53


1.03

0.35










Qualifier
•~£fe*._ 	

























ITEF
ITEF
Client; Information
Project Name:
Sample ID:

Laboratory Information

Project ID:
Sample ID;

Collection Date:
Receipt Date:
Extraction Date:
Texas Lime Kiln
M23-I-3FH
L1072
1072-7

   30-Jnn-98
   08-M-9S
   15-M-98
   21-Jul-98
Sample Information
Original pH:

Filename:
Retchb
Begin ConCal:
End ConCal:
Initial Cal:
   12.86
    0.0
   NA
                                                       Grams
                                                       %
a20ju!98b-13
a20ju!98b-l
                                         1/2
                                                                                              181

-------
                                                                          Paradigm Analytical Labs
                               Analytical Data Summary Sheet
3C12-2,3,7,8-TCDD
 C12-l,2,3,6,7,8-HxCDD
nCl2-l,2,3,4,6,7,8-HpCDD
 'C12-OCDD
I3C12-2,3,7,8-TCDF
 lCirl,2,3,7,8-PeCDF
 3C12-l,2,3,6,7,8-HxCDF
 1C,2-U,3,4,6.7,8-HpCX>F
Cleanup Standards
13C12-2,3,4,7,8-PeCDF
 3CI2-l,2,3A7,8-HxCDD
 3C12-l,2,3,4,7,8-HxCDF
13CirU,3,4,7,8,9-HpCDF
Injection Standards
13C12-1,2,3,4-TCDD
'3C,2-l,2,3,7,8,9-HxCDD
      4
      4
      4
      4
      4
      4
                                  4
                                  4
                                  4
                                  4
                                  4
 3.58
&&.
 3.34
  3*St'
 , »lf|;
 6.66
 2.81
 2.96
 3,03
 3.00
                        !§••
                  3.16
                  3.81
                  3.35
                  3.57
                                                        89.5
                                                        83.4
                                                        83.2
                                                        70.3
                                                        73.9
                                                        ,75.7
                                                        75.0
28:25
            78.9
            83.8
            89.3
34:45
40:00
27:24
31:56
34:13
36:20
32:23
34:41
34:09
37:30

28:08
34:58
0.77
1.54
1.25
XJ*
0.89
0.78
1.56
0.52
0.44
 1.57
 1.23
 0.52
 0.44

 0.79
 1.25
Client Information
Project Name:
Sample ED:

Laboratory Information
, v-;.;.'-
Prqje
Sample 10:

Collection Date:
Receipt Bate:
Extraction Date:
Analysis Date:

 Reviewed by:
Texas Lime Kiln
M23-I-3FH
         Sample Information
                                                   Air
                                                  12.86
                                                   fcO
                                               a20ju!98b-13
                                               a20ju!98b-l
                                               a20jul98b-2
                                               a20ju!98b-17
                                                                                            i&z:
                                            2/2

-------
00
CO
OPUt. .. 21-JUL-1998
Filename a20ju!98b
Sample 13
Acquired 21-JUL-98
Processed 21-JUL-98
Sample ID 1072-7 xl/2
Page 1


06:18:11
13:48:11











Wt^ll




ft
























Cal Table m8290-23-071798
Results Table M8290-23-072098B
Comments
Typ
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
ES/RT
ES
ES
ES
ES
ES/RT
ES
ES
ES
JS
JS
CS
CS
CS
CS
CS
SS
SS
SS
SS
SS
Name;
2,3,7,8-TCDD;
1, 2,3,7, 8-PeCDD;
1,2,3,4,7,8-HxCDD;
1,2,3,6,7, 8-HxCDD;
1,2,3,7,8,9-HxCDD;
1,2,3,4,6,7, 8-HpCDD;
OCDD;
2,3,7,8-TCDF;
1, 2,3,7, 8-PeCDF;
2,3,4,7,8-PeCDF;
1,2,3,4,7,8-HxCDF;
1,2,3, 6,7,8-HxCDF;
2,3,4,6,7,8-HxCDF;
1,2,3,7,8,9-HxCDF;
1,2,3,4,6,7,8-HpCDF;
1,2,3,4,7,8, 9-HpCDF;
OCDF;
13C-2,3,7,8-TCDD;
13C-1 , 2,3,7, 8-PeCDD;
13C-l,2,3,6,7,8-HxCDD;
13C-l,2,3,4,6,7,8-HpCDD;
13C-OCDD;
13C-2,3,7,8-TCDF;
13C-1, 2,3,7, 8-PeCDF;
13C-1 , 2 , 3 , 6 , 7 , 8-HxCDF;
13C-l,2,3,4,6,7,8-HpCDF;
13C-1,2,3,4-TCDD;
13C-l,2,3,7,8,9-HxCDD;
37Cl-2,3,7,8-TCDD;
13C-2, 3,4,7, 8-PeCDF;
13C-l,2,3,4,7,8-HxCDD;
13C-l,2,3,4,7,8-HxCDF;
13C-l,2,3,4,7,8,9-HpCDF;
37Cl-2,3,7,8-TCDD;
13C-2, 3,4,7, 8-PeCDF;
13C- 1,2, 3,4,7, 8-HxCDD;
13C- 1,2, 3,4,7, 8-HxCDF;
13C-1 , 2 , 3 , 4 , 7 , 8 , 9-HpCDF;


Resp;
2.846+05;
1.476+04;
2.226+04;
2.226+04;
5.266+04;
8.13e+04;
2.06e+05;
1.066+05;
* .
4.636+04;
4.77e+04;
2.44e+04;
*;
* .
3.406+04;
* .
1.82e+04;
3.60e+08;
2.466+08;
2.726+08;
2.156+08;
3.22e+08;
3.556+08;
3.246+08;
2.846+08;
1.716+08;
3.66e+08;
3.026+08;
3.186+08;
3.396+08;
2.056+08;
2.456+08;
1.59e+08;
3.18e+08;
3.39e+08;
2.056+08;
2.456+08;
1.59e+08;

Ion 1;
4.726+04;
7.08e+03;
9.84e+03;
9.846+03;
3.16e+04;
3.65e+04;
9.446+04;
5.25e+04;
*;
2.48e+04;
3.396+04;
1.756+04;
* .
*;
1.736+04;
* .
4.69e+03;
1.57e+08;
1.496+08;
1.516+08;
l.lOe+08;
1.52e+08;
1.56e+08;
1.97e+08;
9.71e+07;
5.26e+07;
1.61e+08;
1.68e+08;
3.186+08;
2.07e+08;
1.13e+08;
8.36e+07;
4.846+07;
3.186+08;
2.07e+08;
1.136+08;
8.366+07;
4.84e+07;

Ion 2;
2.37e+05;
7.586+03;
1.236+04;
1.23e+04;
2.10e+04;
4.49e+04;
1.12e+05;
5.34e+04;
* .
2.15e+04;
1.386+04;
6.916+03;
* .
* .
1.67e+04;
* .
1.35e+04;
2.03e+08;
9.69e+07;
1.216+08;
1. 056+08;
1.71e+08;
1.99e+08;
1.276+08;
1.876+08;
1. 18e+08;
2.05e+08;
1.34e+08;
-;
1.32e+08;
9.16e+07;
1.616+08;
l.lle+08;
-;
1.326+08;
9.16e+07;
1.61e+08;
l.lle+08;

RA;?; RT;
0.20;n; 28:27;
0.93;n; 32:36;
0.80;n; 34:46;
0.80;n; 34:46;
1.51;n; 34:58;
0.81;n; 37:09;
0.85;y; 40:01;
0.98,-n; 27:26;
*;n;NotFnd;
1.16;n; 32:24;
2.45;n; 34:09;
2.53;n; 34:13;
*;n;NotFnd;
*;n;NotFnd;
1.03;y; 36:21;
*;n;NotFnd;
0.35;n; 40:10;
0.77;y; 28:25;
1.54;y; 32:36;
1.25;y; 34:45;
1.04;y; 37:09;
0.89;y; 40:00;
0.78;y; 27:24;
1.56;y; 31:56;
0.52;y; 34:13;
0.44;y; 36:20;
0.79;y; 28:08;
1.25;y; 34:58;
-;-; 28:27;
1.57;y; 32:23;
1.23;y; 34:41;
0.52;y; 34:09;
0.44;y; 37:30;
-;-; 28:27;
1.57;y; 32:23;
1.23;y; 34:41;
0.52;y; 34:09;
0.44;y; 37:30;


0
0
0
0
0
0
0
0

0
0
0


0

0
89
87
83
89
166
70
73
75
74
75
76
86
78
95
83
89

Cone ;
.080;
.005;
.013;
.009;
.022;
.042;
.127;
.031;
* .
.016;
.020;
.008;
*;
*;
.016;
* .
.011;
.487;
.855;
.382;
.386;
.451;
.287;
.881;
.675;
.953;
.931;
.275;
.234;
.898;
.227;
.759;
.313;
96.418;
106.827;
114
109
119
310;
818;
200;

DL;
0.0097;
0.0083;
0.0121;
0.0087;
0.0088;
0.0078;
0.0111;
0.0139;
0.0099;
0.0095;
0.0076;
0.0059;
0.0069;
0.0079;
0.0131;
0.0159;
0.0145;
0.0345;
0.0200;
0.0401;
0.0140;
0.0115;
0.0171;
0.0076;
0.1194;
0.0774;

-;
0.0070;
0.0078;
0.0609;
0.1533;
0.0988;
0.0080;
0.0062;
0.0668;
0.1822;
0.1785;

S/N1;?;
8;y;
2;n;
3;n;
3;n;
5;y;
13-v
•*••> i y i
40 ;y;
7;y;
*;n;
9;y;
5;y;
3;y;
*;n;
*;n;
3;y;
*;n;
2;n;
4614;y;
20628,-y;
6817, -y;
14489; ry;
23781;y;
7860;y;
114096, -y;
2314;y;
3493;y;
4869;y;
6948;y;
35757 ;y;
122596;y;
4870,-y;
2191;y;
2775,-y;
35757 ;y;
122596;y;
4870;y;
2191;y;
2775;y;

S/N2;?
52, -y
2;n
2;n
2;n
4;y
27-v
^ • / jr
35;y
5;y
*;n
4,-y
5;y
3;y
*;n
*;n
5;y
*;n
2;n
15046;y
26056;y
6803;y
12216;y
25493 ;y
20412 ;y
26180;y
2008;y
1835;y
15585;y
6922, -y
-; -
28315;y
493 6, -y
1844, -y
1496;y
~; -
28315;y
4936;y
1844 ;y
1496;y
mod?
no
no
no
no
no
HO
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
                                                                                                                                                 Page If

-------
OPUSquan   21-JUL-1998
                   Page  1
                                                                    Page 1  of  8

 Ent: 39 Name: Total Tetra-Furans  F:l  Mass:  303.902 305.899  Mod?  no    #Hom:4

 Run: 18 File: a20ju!98b    S:13 Acq:21-JUL-98 06:18:11 Proc:21-JUL-98  13:48:11
 Tables: Run: a20ju!98b  Analyte: m8290-23-»  Cal:  m8290-23-»Results: M8290-23»
 Version: V3.5 17-APR-1997 11:14:34  Sample text:  1072-7 xl/2
   Amount: 0.06
     Cone: 0.06
   Tox #1: -
Name
of which 0.03
of which 0.03
     Tox #2: -

#     RT Respnse
named and 0.03
named and 0.03
      Tox #3:  -
2,3,7,8-TCDF
1  24:52 3.8e+04  0.81 y
         3.8e+04

2  26:50 5.0e+04  0.61 n
         5.0e+04

3  27:26 l.le+05  0.98 n
         l.le+05

4  28:01 2.5e+04  1.75 n
         2.5e+04
          Cone

           0.01
               1

           0.01
               3

           0.03
               c
               E
           0.01
    unnamed
    unnamed
    Area  Height
                                                                      S/N  Mod?
 1.7e+04  3.5e+03  2.8e+00  n  n
 2.1e+04  5.8e+03  2.9e+00  n  n

 1.9e+04  4.7e+03  3.8e+00  y  n
 3.1e+04  6.9e+03  3.5e+00  y  n
3
 5.2e+04  9.2e+03  7.4e+00  y  n
 5.3e+04  9.5e+03  4.9e+00  y  n
L
 1.6e+04  3.8e+03  3.0e+00  y  n
 9.3e+03  3.5e+03  1.8e+00  n  n
                                                                    Page 2 of 8

 Ent: 40 Name: Total Tetra-Dioxins F:l  Mass: 319.897 321.894 Mod? no   #Hom:2

 Run: 18 File: a20ju!98b    S:13 Acq:21-JUL-98 06:18:11 Proc:21-JUL-98 13:48:11
 Tables: Run: a20ju!98b  Analyte: m8290-23-»  Cal: m8290-23-»Results: M8290-23*
 Version: V3.5 17-APR-1997 11:14:34  Sample text: 1072-7 xl/2
   Amount:  0.09
     Cone:  0.09
   Tox  #1:  -
 Name
 2,3,7,8-TCDD
of which 0.08
of which 0.08
     Tox #2: -

#     RT Respnse
named and 0.01
named and 0.01
      Tox #3: -
                                        RA
1  27:24 4.3e+04  9.81 n
         4.3e+04

2  28:27 2.8e+05  0.20 n
         2.8e+05
                                              Cone

                                               0.01

                                                   4
                                               0.08
    unnamed
    unnamed
                  Area  Height
                                                                      S/N  Mod?
               3.9e+04 9.5e+03 7.2e+00 y  n
               4.0e+03 1.5e+03 1.5e+00 n  n
               3
               4.7e+04 9.9e+03 7.5e+00 y  n
               2.4e+05 5.3e+04 5.2e+01 y  n
                                                                    Page  3 of  8

  Ent:  41 Name:  Total Penta-Furans   F:2  Mass:  339.860  341.857 Mod? no   #Hom:5

  Run:  18 File:  a20ju!98b    S:13 Acq:21-JUL-98 06:18:11  Proc:21-JUL-98  13:48:11
  Tables: Run:  a20ju!98b  Analyte:  m8290-23-»   Cal: m8290-23-»Results: M8290-23»
  Version: V3.5 17-APR-1997 11:14:34  Sample text:  1072-7 xl/2
    Amount:  0.05
      Cone:  0.05
    Tox #1:  -
 Name
 2,3,4,7,8-PeCDF
 of  which 0.02
 of  which 0.02
      Tox #2: -

 #     RT Respnse
 named and 0.03
 named and 0.03
       Tox #3: -
                                         RA
 1  31:21  3.3e+04   3.27  n
          3.3e+04

 2  32:24  4.6e+04   1.16  n
          4.66+04

 3  32:29  3.4e+04   0.58  n
           Cone

            0.01
                2
                7
            0.02


            0.01
    unnamed
    unnamed
    Area  Height
                                                                       S/N  Mod?
  2.6e+04  6.8e+03  6.2e+00 y  n
  7.8e+03  2.9e+03  1.3e+00 n  n
 2
  2.5e+04  9.5e+03  8.7e+00 y  n
  2.1e+04  8.4e+03  3.8e+00 y  n
                                                                                                          184

-------
OPUSguan   21-JUL-1998
                   Page 2
                            3.4e+04

                   4  32:57 1.4e+04  0.53 n    0.00
                            1.4e+04

                   5  33:05 7.2e+03  0.97 n    0.00
                            7.2e+03
                                1.2e+04  3.5e+03  3.2e+00  y  n
                                2.2e+04  5.1e+03  2.3e+0.0  n  n
                               3
                                4.7e+03  1.8e+03  1.7e+00  n  n
                                8.9e+03  2.8e+03  1.3e+00  n  n
                               3
                                3.5e+03  9.8e+02  8.9e-01  n  n
                                3.6e+03  l.le+03  5.2e-01  n  n
                                                                    Page 4 of 8

 Ent: 42 Name: Total Penta-Dioxins F:2  Mass: 355.855 357.852 Mod? no   #Hom:3

 Run: 18 File: a20ju!98b    S:13 Acq:21-JUL-98 06:18:11 Proc:21-JUL-98 13:48:11
 Tables: Run: a20ju!98b  Analyte: m8290-23-»  Cal: m8290-23-»Results: M8290-23*
 Version: V3.5 17-APR-1997 11:14:34  Sample text: 1072-7 xl/2
   Amount: 0.04
     Cone: 0.04
   Tox #1: -
Name
 1,2,3,7,8-PeCDD
of which 0.01
of which 0.01
     Tox #2:  -
named and 0.03
named and 0.03
      Tox #3: -
                         RT Respnse
                                        RA
                      31:56 4.6e+04  7.27 n
                            4.6e+04
2  32:23 4.3e+04  4.60 n
         4.3e+04

3  32:36 1.5e+04  0.93 n
         1.5e+04
          Cone

           0.02
               ^
               C
           0.02
               3
               1
           0.01
    unnamed
    unnamed
                                   Area  Height
                                                                      S/N  Mod?
 4.1e+04  1.3e+04  8.3e+00  y  n
 5.6e+03  2.5e+03  2.2e+00  n  n

 3.5e+04  1.4e+04  8.6e+00  y  n
 7.7e+03  2.0e+03  1.8e+00  n  n
L
 7.1e+03  2.4e+03  1.5e+00  n  n
 7.6e+03  2.3e+03  2.0e+00  n  n

-------
OPUSquan   21-JUL-1998
                   Page 3
 Ent: 43 Name: Total Hexa-Furans
                                                 Page 5  of  8

                F:3  Mass:  373.821  375.818  Mod?  no    fHorn:9
 Run: 18 File: a20ju!98b    S:13 Acq:21-JUL-98 06:18:11 Proc:21-JUL-98 13:48:11
 Tables: Run: a20ju!98b  Analyte: m8290-23-»  Cal: m8290-23-»Results: M8290-23»
 Version: V3.5 17-APR-1997 11:14:34  Sample text: 1072-7 xl/2
   Amount: 0.04
     Cone: 0.04
   Tox #1: -
Name
of which 0.03
of which 0.03
     Tox #2:  -

#     RT Respnse
named and 0.02
named and 0.02
      Tox #3: -
                                        RA
                   1  33:37 1.46+04  1.08 y
                            1.4e+04

                   2  33:43 3.5e+03  1.51 n
                            3.5e+03

                   3  33:47 4.4e+03  0.54 n
                            4.46+03

                   4  33:50 5.8e+03  1.06 y
                            5.8e+03

                   5  33:56 3.8e+03  6.24 n
                            3.8e+03

                   6  33:57 7.3e+03  0.76 n
                            7.36+03

1,2,3,4,7,8-HxCDF  7  34:09 4.8e+04  2.45 n
                            4.8e+04

1,2,3,6,7,8-HxCDF  8  34:13 2.4e+04  2.53 n
                            2.4e+04

                   9  34:20 4.3e+03  0.99 n
                            4.3e+03
          Cone

           0.01
               1
               6
           0.00
               2
               ]
           0.00
               ]

           0.00
               3
               2
           0.00
               2
               c
           0.00
               T
               4
           0.02

               ]
           0.01
               1
               e
           0.00
unnamed
unnamed
                                                      Area  Height
                S/N  Mod?
                                7.0e+03 3.2e+03 1.8e+00 n  n
                                6.56+03 2.7e+03 2.8e+00 n  n
                               3
                                2.1e+03 l.le+03 6-le-Ol n  n
                                1.4e+03 5.2e+02 5.4e-01 n  n

                                1.56+03 7.2e+02 4.16-01 n  n
                                2.8e+03 7.36+02 7.5e-01 n  n
                                3.0e+03 1.2e+03 6.7e-01 n  n
                                2.8e+03 7.3e+02 7.5e-01 n  n
                               D
                                3.2e+03 1.2e+03 6.6e-01 n  n
                                5.26+02 2.76+02 2.86-01 n  n
                               3
                                3.26+03 1.6e+03 9.36-01 n  n
                                4.26+03 1.5e+03 1.6e+00 n  n

                                3.4e+04 9.2e+03 5.2e+00 y  n
                                1.4e+04 4.9e+03 5.0e+00 y  n

                                1.8e+04 6.2e+03 3.5e+00 y  n
                                6.9e+03 3.1e+03 3.2e+00 y  n
                                                   2.2e+03  8.0e+02 4.5e-01 n  n
                                                   2.26+03  S.Oe+02 5.26-01 n  n
                                                                     Page  6  of  8

 Ent:  44 Name:  Total  Hexa-Dioxins  F:3  Mass:  389.816  391.813 Mod? no   #Hom:10

 Run:  18 File:  a20ju!98b    S:13 Acq:21-JUL-98 06:18:11  Proc:21-JUL-98  13:48:11
 Tables: Run:  a20ju!98b  Analyte: m8290-23-»   Cal: m8290-23-»Results: M8290-23*
 Version: V3.5  17-APR-1997  11:14:34   Sample text:  1072-7 xl/2
   Amount:  0.15
      Cone:  0.15
   Tox #1:  -
 Name
of which 0.03
of which 0.03
     Tox #2: -

#     RT Respnse
named and  0.12
named and  0.12
      Tox  #3: -
                                         RA
                    1  33:52  9.06+04   1.20  y
                             9.06+04

                    2  33:58  2.6e+03   1.58  n
                             2.66+03

                    3  34:01  3.16+03   0.32  n
                             3.16+03

                    4  34:09  9.4e+04   1.79  n
                             9.4e+04

                    5  34:19  3.7e+04   1.62  n
                             3.7e+04
          Cone

            0.04
               4
               4
            0.00
               1
               ]
            0.00
               1

            0.04
               6
               3
            0.02
 unnamed
 unnamed
                                                       Area  Height
                                   S/N  Mod?
                                4.9e+04 1.7e+04 l.le+01 y  n
                                4.1e+04 1.6e+04 l.le+01 y  n
                                3
                                1.6e+03 6.86+02 4.3e-01 n  n
                                l.Oe+03 5.9e+02 3.9e-01 n  n

                                7.6e+02 3.56+02 2.2e-01 n  n
                                2.4e+03 8.4e+02 5.5e-01 n  n
                                I
                                6.0e+04 2.0e+04 1.3e+01 y  n
                                3.4e+04 6.96+03 4.6e+00 y  n
                                I
                                2.3e+04 6.7e+03 4.2e+00 y  n

-------
OPUSquan   21-JUL-1998
                   Page 4
                   6  34:25 1.5e+04  1.01 n    0.01
                            1.5e+04

                   7  34:34 8.7e+03  1.21 y    0.00
                            8.7e+03

1,2,3,6,7,8-HxCDD  8  34:46 2.2e+04  0.80 n    0.01
                            2.2e+04

                   9  34:52 8.6e+03  0.93 n    0.00
                            8.66+03

1,2,3,7,8,9-HxCDD  10 34:58 5.3e+04  1.51 n    0.02
                            5.3e+04
                                1.4e+04 S.le+03  3.4e+00 y  n
                               L
                                7.3e+03 2.8e+03  1.8e+00 n  n
                                7.3e+03 1.5e+03  l.Oe+00 n  n
                               0
                                4.8e+03 1.4e+03  9.0e-01 n  n
                                3.9e+03 l.le+03  7.4e-01 n  n
                               1
                                9.86+03 4.0e+03  2.56+00 n  n
                                1.2e+04 3.2e+03  2.1e+00 n  n
                               D
                                4.1e+03 1.7e+03  l.le+00 n  n
                                4.46+03 1.7e+03  l.le+00 n  n
                               2
                                3.2e+04 8.6e+03  5.4e+00 y  n
                                2.1e+04 5.6e+03  3.7e+00 y  n
                                                                    Page 7 of 8

 Ent: 45 Name: Total Hepta-Furans  F:4  Mass: 407.782 409.779 Mod? no   #Hom:l

 Run: 18 File: a20ju!98b    S:13 Acq:21-JUL-98 06:18:11 Proc:21-JUL-98 13:48:11
 Tables: Run: a20ju!98b  Analyte: m8290-23-»  Cal: m8290-23-»Results: M8290-23»
 Version: V3.5 17-APR-1997 11:14:34  San^jle text: 1072-7 xl/2
   Amount: 0.02
     Cone: 0.02
   Tox #1: -
Name
of which 0.02
of which 0.02
     Tox #2:  -

#     RT Respnse
named and *
named and *
      Tox #3: -
unnamed
unnamed
                                        RA
                                              Cone    Area  Height    S/N  Mod?
1,2,3,4,6,7,8-HpCDFl  36:21 3.4e+04  1.03y    0.02
                            3.4e+04
                                                   1.7e+04 5.3e+03 3.2e+00 y  n
                                                   1.7e+04 6.2e+03 5.2e+00 y  n
                                                                                                        187

-------
OPUSquan   21-JUL-1998
                   Page 5
                                                                    Page 8 of 8

 Ent: 46 Name: Total Hepta-Dioxins F:4  Mass: 423.777 425.774 Mod? no   #Hom:4

 Run: 18 File: a20ju!98b    S:13 Acq:21-JUL-98 06:18:11 Proc:21-JOL-98 13:48:11
 Tables: Run: a20ju!98b  Analyte: m8290-23-»  Cal: m8290-23-»Results: M8290-23*
 Version: V3.5 17-APR-1997 11:14:34  Sample text: 1072-7 xl/2
   Amount: 0.11
     Cone: 0.11
   Tox #1: -
Name
of which 0.04
of which 0.04
     Tox #2: -

#     RT Respnse
named and 0.07
named and 0.07
      Tox #3: -
                                        RA
                   1  36:20 5.1e+04  3.04 n
                            5.1e+04

                   2  36:34 3.2e+04  1.18 y
                            3.2e+04

l,2,3,4,6,7,8-HpCDD3  37:09 8.1e+04  O.Sln
                            8.1e+04

                   4  37:30 5.1e+04  2.85 n
                            5.1e+04
          Cone

           0.03
               3
               1
           0.02
               1
               ]
           0.04
               3
               4
           0.03
unnamed
unnamed
Area  Height    S/N  Mod?
                                3.8e+04 9.7e+03 l.le+01 y  n
                                1.3e+04 3.3e+03 6.6e+00 y  n

                                 .7e+04 5.5e+03 6.1e+00 y  n
                                 .4e+04 4.3e+03 8.4e+00 y  n

                                3.6e+04 l.le+04 1.3e+01 y  n
                                4.5e+04 1.4e+04 2.7e+01 y  n

                                3.8e+04 l.le+04 1.2e+01 y  n
                                1.3e+04 3.5e+03 7.0e+00 y  n

-------
File: A20JUL98B Acq: 21-JUL-1998 06:18:11 Exp: EXP_M23_DB5_OVATION Voltage SIR EI + GC Autospec-UltimaE Paradigm
Sample #13 Text: 1072-7 xl/2 ALS #14
319.8965 S:13 SMO(1,3) BSUB(128, 15, -3 . 0) PKD(3 , 3 , 3 , 0 . 10%, 1312 . 0 , 1 . 00%, F, F)
100% A3.90E4 A4.72E4 1 . 1E4
50J
OJ
321.
100%
50J
ol
331.
100%
50 j
OJ
333.
100%
sol
327.
100%
50J
OJ
316.
100%
50J
OJ

^—i 	 > ' < ' r '
24:00
8936 S:13 SMO(1,3)

24:00
9368 S:13 SMO(1,3)

	 24 loo'
9339 S:13 SMO(1,3)

	 p 	 1 	 1 	 1 	 1 	 1 	 r
24:00
8847 S:13 SMO(1,3)

' 	 1 	 P 	 1 	 1 	 1 	 1 	 r
24:00
9824 S:13 SMO(1,3)
23;31 23:52

	 24 loo'
^v^^vVv_A^^
_5.7E3
_O.OEO
25^00 26:00 27:00 28:00 29:00 30:00 Time
BSUB(128,15,-3.0) PKD(3 , 3 , 3 , 0 . 10%, 1020 . 0 , 1 . 00%, F, F)
A2.37E5 _5.3E4
A
UJ\
25:00 26:00 27:00 28:00 29:00 30:{
BSUB(128,15,-3.0) PKD(3 , 3 , 3 , 0 . 10%, 6944 . 0 , 1 . 00%, F, F)
A1.61E8
A A
AA
' ' ' 25^00 26loO 27IOO 28100 29IOO 30:(
BSUB(128,15,-3.0) PKD(3 , 3 , 3 , 0 . 10%, 2764 . 0 , 1 . 00%, F, F)
A2.Q5E8
A A
AA
' ' ' 25!00' 26^00 27100 28loO 29!oO 30:1
BSUB(128,15,-3.0) PKD(3, 3 , 3, 0 . 10%, 1804 . 0, 1 . 00%,F,F)
A3.18E8
A
_2.7E4
"O.OEO
)0 Time
3.4E7
_1.7E7
O.OEO
50 Time
4.3E7
L2.2E7
: O.OEO
30 Time
6.5E7
L3.2E7
_O.OEO
' ' ' 25!oo' ' ' 26100 27IOO 28IOO 29100 30lOO Time
PKD(3,3,3,100.00%,0.0,1.00%,F,F)
24-30 24:55 25:17 25; 38 26i08 26:33 26:57 27:26 27^5J. 28U8 2Sil5 29:42^ _p4.5E7

.2.2E7
_O.OEO
25:00 26:00 27:00 28:00 29:00 30:00 Time
00

-------
Pile:  A20JUL98B  Acq: 21-JUL-1998 06:18:11—Exp: EXP_M23_DB5_6VATION Voltage SIR EI+—GC Autospec-UltimaE—Paradigm	
Sample #13   Text: 1072-7 xl/2  ALS #14
355.8546  S:13  F:2 SMO(1,3) BSUB(128,15,-3.0) PKD(3,3,3,0.10%, 1576.0 ,1.00%,F,F)
100%                                                             A4.07E4        A3.55E4                          r_1.5E4
  so:
                                                                                                             u7. 6E3
     ~i—i—I—i—i—i—T i i—i—r—i—i—r—i—i—i—i—i—i—i—i—i—i—i i i—r—i—i—i—i—r-i—i—i—i—i—i—i—i—i—i—i—i—rn—r—i—i—i—r~i—i—i—i—i—i—i—i—i—i—i—r—r~i—i—i—i—i—r—i—i—i—r-i—i  i i n *i~ i—i—r—i—r-i—i—i—r—i—r~r
      30:12  30:24   30:36   30:48   31:00   31:12  31:24  31:36  31:48  32:00  32:12   32:24   32:36   32:48   33:00   33:12     Tiro
357.8517  S:13  F:2  SMO(1,3)  BSUB(128,15,-3.0) PKD(3,3,3,0.10%,1144.0,1.00%,F,F)
100%                                                             A5.I
 50_
                                                                                                 OE3
                                                                                                             11.7E3
                                                                                                                   .O.OEO
      30:12  30:24  30:36   30:48   31:00  31:12  31:24  31:36  31:48  32:00  32:12  32:24  32:36   32:48  33:00  33:12    Time
367.8949 S:13 F:2  SMO{1,3)  BSUB(128,15,-3 . 0) PKD(3,3,3,0.10%,2588.0,1. 00%, F, F)
100%
 so:
                                                                                  A1.49E8
                                                                                                                 ..5.3E7
                                                                                                             _2.7E7
                                                                                                                   O.OEO
      36!i2 '  36{24 ' 36!36 ' 30 Us  31-00  31:12  31:24  31:36  31:48  32:00  32:12   32:24  32:36  32U8  33i0033[l2    Time
369.8919 S:13 F:2 SMO(1,3)  BSUB(128,15,-3.0)  PKD(3,3,3,0.10%,1328.0,1.00%,F,F)
100%
 50J
                                                                                  A9.69E7
i i i i  i i i i i i  i i i i i i  i i i i i i  i i i i i i i  i i i i i i i i  i i i i i i i  i i i i i i  i i i i i i i  i i i i i i  i i i i i i i  i i i ' i i i  ii i i i i i  i i i i i i  i i i i
30:12  30:24  30:36  30:48  31:00   31:12  31:24  31:36  31:48  32:00  32:12  32:24  32:36  32j48   33:00   33:12
                                                                                                                 _3.5E7
                                                                                                             _1.7E7
                                                                                                                      Time
66.9792 S:13 F:2 SMO(1,3)  PKD(3 , 3, 3 , 100 . 00%, 0 . 0, 1 . 00%, F,F)
    30:11    30:26          30:50      31:09     31:26          31:52
 50J
                                                                   32:09   32j23
                                                                                             32:44
                                                                                                            ,_2.2E7
     T—i—i—i—i—T—i—i—r~r~T—i—i—r~i—i—r'T i "i—i—i—i—i—i—i—r—i—i—i—i—i—r—i—i—i—i—r~i—i—i—i—i—i—i—i—i—n—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—n—i—i—i—r~r-i—i—r-r—i—i -i ••r™-| i—i—i—r T ~\ • i—r i i i—i i• -
     30:12  30:24  30:36  30:48  31:00  31:12  31:24   31:36   31:48  32:00  32:12  32:24  32:36  32:48  33:00  33:12     Time

-------




Ui
File: A20JUL98B Acq: 21-JUL-1998 06:18:11 Exp: EXP_M2J_DBb
Sample #13 Text: 1072-7 xl/2 ALS #14
389.8156 S:13 F:3 SMO(1,3) BSUB(128 , 15 , -3 . 0) PKD(3 , 5, 2 , 0 . 10%
100* A4.89E4 A6 ' 21E4
o;
391.
100*
so:
401.
100&
so:
o:
403.
looa
so:
o:
380.
100%
so:
o:
VL«
\ / Y/V.34E3
^_^ J AJ^.62E3 J Y \/^\ 	
33:24 33:36 33:48 34:00 34ll2 34:24 34
8127 S:13 F:3 SMO(1,3) BSUB(128, 15, -3 . 0 ) PKD(3 , 5 , 2 , 0 . 10%
A4.08E4
/ 1 A3.35E4
33:24 33:36 33:48 34:00 34:12 34:24 34
8559 S:13 F:3 BSUB(128, 15, -3 . 0) PKD(3, 5, 2, 0 . 10%, 9896.0, 1

33:24 33:36 33:48 34:00 34:12 34:24 34
8530 S:13 F:3 BSUB(128, 15, -3 . 0) PKD(3 , 5, 2, 0 . 10%, 7896 . 0, 1

1 — i i i — i — i i i — i — i — i i i — i — i— t — i — i — i — i — i — i— r i i i i I i i I i i | i i i i i
33:24 33:36 33:48 34:00 34:12 34:24 34
9760 S:13 F:3 SMO(1,3) PKD(3 , 3 , 3 , 100 . 00%, 0 . 0., 1 . 00%, F, F)
•n;?9 TT:45 34:0234:09 34:22
r~
*•• r • i 	 r "V r— 'f-i — i— T-T'""r "i ' i — i — I — i '"» 't • i i I i i i ' ' i ' • ' ' ' | • ' ' ' '
33124 33:36 33:48 34:00 34:12 34:24 34
_OVATION Voltage SIR EI+ GC Autospec-UltimaE Par ad:
,1576.0,1.00%,F,F)
A3.16E4
A9.84E3 f\
•36 34:48 35:00 35:12 35:24 35:36 35:
,1512.0,1.00%,F,F)
A2.10E4
A1.23E4 /\
S36 '34148 35IOO 3s!l2 35J24 35I36 35
.00%,F,F)
A1.51E8 A1.68E8
/I A
/A 11
!36 34-148 35loO 35ll2 35124 35b6 35:
.00%,F,F)
A1.21E8 A1.34E8
A A
M A
be 34148 35:00 35ll2 35:24 35:36 35
	 3J:43 34^5435:02 35_:15 35:29 35:43

tgm
_2.0E4
_1.0E4
_O.OEO
48 Time
_1.8E4
_8.9E3
_O.OEO
48 Time
6.9E7
.3.4E7
O.OEO
48 Time
5.5E7
_2 . 7E7
O.OEO
48 Time
8.9E7
L4.4E7
LO.OEO
!36 34148 35loO 35:12 35:24 35:36 35:48 Time
CD
p.

-------
file
Samp
423.
1001
425.
100S
50J
OJ
435.
100%
50J
437.
100%
50J
0"
430.
100%
so:
;: A20JUL986 Acq: 21-JUL-1998 06:18:11
>le #13 Text: 1072-7 xl/2 ALS #14
7767 S:13 F:4 SMO(1,3) BSUB(128 , 15, -3 . 0)
A3.81E4
	 J\^
36:00 ' 36112 ' 36.'24
7737 S:13 F:4 SMO(1,3)
Al . 91E3 /\
111 iii i i n i i i i i i i i i i
36:00 36:12 36:24
8169 S:13 F:4 SMO(1,3)

1 i i i i 1 i i i i i I i i i i i I i i
36:00 36:12 36i24
8140 S:13 F:4 SMO(1,3)

I I I I I i I i i i -i—r T-I— i— n i i r
36:00 36:12 36:24
9728 S:13 F:4 SMO{1,3)
36:05
'
36166 36!i2 36124
^ 	
36.!36 36U8 3?!
BSUB(128,15,-3.0)
A1.44E4
1 1 T 1 1 1 1 1 1 I i i i i ) |
36:36 36:48 37:
BSUB(128,15,-3.0)

36:36 36:48 37:
BSUB(128,15,-3.0)

Exp: EXP_M23_DB5_OVATION Voltage SIR EI + GC Autospec-UltimaE Parad
PKD(3,3,3,0.10%,904.0,1.00%,F,F)
A3.65E4 A3.77E4
A A
A.
66 37! 12
PKD(3,3,3
A4.49E4
™'T I 1 I ' 1 T^^1^^
00 37:12
PKD (3,3,3
A1.10E8
A

00 37:12
PKD(3,3,3
A1.05E8
A
/I
J\^__^^__
37:24 37:36 37:48 38:00 38:12 38:24 38:36 38:48 39
, 0.10%, 508. 0,1. 00%, F,F)
A1.33E4
37124 37136 37|48 38166 38!i2 38124 38.'36 38.'48 39
, 0.10%, 2132. 0,1. 00%, F,F)

37:24 37:36 37:48 38:00 38:12 38:24 38:36 38:48 39
,0.10%,2444.0,1.00%,F,F)

36:36 36:48 37:00 37:12 37:24 37:36 37:48 38:00 38:12 38:24 38:36 38:48 39
PKD(3/3,3,100.00%,0.0,1.00%,F,F)
36;57 37:09 37:23 37:35 37i53 38:08 38:21 38:50

36:36 36:48 37-!

66 ' 37! 12 '

igm
1.2E4
.6.1E3
O.OEO
00 Time
1.4E4
_7 . OE3
O.OEO
00 Time
3 . 1E7
.1 . 5E7
O.OEO
00 Time
_3.0E7
_1 . 5E7
O.OEO
00 Time
5.9E7
.3.0E7
.O.OEO
37!24 37136 37148 38!66 38:12 38:24 38I36 bsUs' 39:00 Time

-------
Fil€
Samj
457.
lOOi
50.
0
459.
1002
so:
OJ
469.
100%
so:
0"
471.
100%^
so:
rr
454.
100%
so:
, IV

;: A20JUL98B Acq: 21-JUL-1998 06:18:11 Exp: EXP M23
)le #13 Text: 1072-7 xl/2 ALS #14
7377 S:13 F:5 SMO(1,3) BSUB( 128 , 15, -3 . 0) PKD(3,3,3,0
A9

J
39:12 39:24 39:36 39:48 40
7348 S:13 F:5 SMO(1,3) BSUB( 128, 15 , -3 . 0) PKD(3,3,3,0
Al.
/
	 . 	 L
39ll2 39124 39':36 39148 ' 40
7780 S:13 F:5 SMO(1,3) BSUB( 128, 15 , -3 . 0) PKD(3,3,3,0
Al.
/
/
39ll2 39124 39136 39148 40
7750 S:13 F:5 SMO(1,3) BSUB( 128, 15 , -3 . 0) PKD(3,3,3,0
Al.
/
/
39ll2 39124 39136 39148 40
9728 S:13 F:5 SMO{1,3) PKD(3 , 3 , 3 , 100 . 00%, 0 . 0, 1 . 00%, F,
39:09 39:36 39:44 40^
7
39:12 39:24 39:36 39:48 40
_DB5_OVATION Voltage SIR EI+ GC Autospec-UltimaE Parad
.10%, 588. 0,1. 00%, F,F)
.44E4
\
^___\__^___ A2.81E3
:00 40:12 40:24 40:36 40:48 41:
.10%, 792. 0,1. 00%, F,F)
K
\
A3.41E3
:00 40:12 40:24 40:36 40:48 41
.10%, 1488. 0,1. 00%, F,F)
52E8
V
:00 40:12 40:24 40:36 40:48 41:
10%, 1540. 0,1. 00%, F,F)
71E8
V
lob 4oll2 40124 40136 40:48 41:
F)
J)0 40:21 40^:28 40:39 40:52

:00 40:12 40:24 40:36 40148 4ll
igm
2.5E4
_1.2E4

00 Time
2.8E4
_1.4E4

00 Time
3 . 5E7
L1.8E7
.O.OEO
00 Time
3.9E7
.2 . OE7
_O.OEO
00 Time
_6.4E7
L3.2E7
O.OEO
DO Time
CO

-------
Pile: A20JUL98B — Acq: 21-JUL-1998  06:18:11  Exp: EXP_M23_DB5_OVATION Voltage SIR EI+  GC Autospec-UltimaE   Paradigm
Sample #13  Text: 1072-7 xl/2  ALS #14
303.9016 S:13 SMO(1,3) BSUB(128, 15 , -3 . 0) PKD(3 , 3 , 3 , 0 . 10%, 1240 . 0 , 1 . 00%, F, F)
100^                                                                 A5.25E4                                      9.7E3
                                                           A "I OT&A      I \
                                                                                                                 _4.9E3

                                                                                                                  O.OEO
                                                                                                             30:00   Time

                                                                                                                  1.2E4

                                                                                                                 L6.2E3

                                                                                                                 Lo.OEO
                 24!00          25iOO           26iOO           27iOO
305,8987 S:13 SMO(1,3) BSUB(128,15,-3.0) PKD(3,3,3,0.10%,1960.0,1.00%,F,F)
100$                                                                A5.34E4
                                                           A3.09E4
                                                                    28:00
                 24iOO          25:00           26:00           27:00
315.9419 S:13 SMO(1,3) BSUB(128,15,-3.0) PKD(3,3,3 , 0.10%,4040.0,1.00%,F,F)
100%                                                                A1.56E8
                                                                              28:00

       —i	1   i   i	1	1	1	1	1	1	1	1	1  i	r——i	1	1	1	1	1	r  i	r-
                 24:00          25:00          26:00           27:00
317.9389 S:13 SMO(1,3) BSUB(128,15,-3.0) PKD(3 , 3,3,0.10%,1996.0,1.00%,F,F)
lOOi                                                                A1.99E8
 50J
                                                                              Isloo'
                                                                                              29:00
                                                                                   29:00
                                                                                              29 loo'
                                                                                                              30:00

                                                                                                                  3

                                                                                                                 11

                                                                                                                 .0
                                                                                                   30:00

                                                                                                       4

                                                                                                      -2
                       Time

                      ,2E7

                      .6E7

                      ,OEO
                       Time

                      ,1E7

                      ,OE7
  OJ
                                                                                              '29:00
                                                                                                             30:00

                                                                                                                  7
-i	1	1	1   i   i	1	1	1	1	1	r
      24:00          25:00
                                                 T
                                                26:00           27:00
375.8364 S:13 SMO(1,3) BSUB(128,15,-3.0) PKD(3,3,3 ,100.00%, 56 . 0,1.00%,F,F)
lOOi
                                                                                     28:25


23:11


23=39 24:32 25/j01
r^/wA—nn A An_A — (W^n/r

26:0
25:49f1
vAVvAlJl
27:
3 1
26:51 f
- /\ /wA -WV '
28:08 A
21 A /
/ / 28
L 27:49 / /I
\. JUV V,/ WAJ

:58 on ,n
jt 29:49
\ 29:31 A
A ^\ f\ J^V^
                                                               27:00
                                                                    28:00
                 24:00          25:00           26:00
316.9824 S:13 SMO(1,3) PKD{3,3,3,100.00%,0.0,1.00%,F,F)
100&     23j3123:52     24:30  24;5525;1725:38   26i08.26^33 26i57 _27j26  27;5J.  28:18
29:00
                                                                                                             30:00
 50J

  OJ
                                                                                                 29:15  29:42
                                25! 00
                                               26 loo'
                                                                   28 !00
                                                                                              29 loo'
               30 !00
  Time

 2E3

.6E3

. OEO
  Time

.5E7

.2E7

.OEO
  Time
      24:00

-------
 File: A20JtJL98B—Acq:  21-JUL-1998 06:18:11Exp:  EXP_M23_DB5_OVATION Voltage SIR EI+GC Autospec-UltimaEParadigm
 Sample  #13  Text:  1072-7 xl/2  ALS #14
 339.8597 S:13  F:2  SMO(1,3)  BSUB(128,15,-3.0)  PKD(3,3,3,0.10%,1096.0,1.00%,F,F)
 100%,                                                             A2.64E4         A2.48E4                           r_1.0E4
                                             A2.55E4
                                                                     ; \       i\        i \
                                                                                                                   _5.1E3

                                                                                                                    O.OEO
     3oli2 ' 36124 ' 36136 ' 36148 ' 3ll66 ' 31112 '  31124  31:36  31:48  32:00  32-.I2  32-24,  32:36  32i48  33iOO   33il2
341.8568 S:13 F:2 SMO(1,3) BSUB(128,15,-3.0) PKD(3,3,3,0.10%,2208.0,1.00%,F,F)
100%                                                                            A2.15E4
                                                                                                                    9
       36112 '  36124 '  36136 '  30148 ' 3ll66 ' 3ill2 ' 31124 ' iilie '  3ll48   32166  32ll2  32l24  32136  32i48  33100  33il2
 351.9000 S:13 F:2 SMO(1,3) BSUB(128,15,-3.0)  PKD(3,3,3,0.10%,616.0,1. 00%, F, F)
 100%                                                            A1.97E8         A2.Q7E8                           _7

  50J                                                               MM                              P
   OJ
      ' 3oli2 '  36124 '  36136 '  36148 ' 3ll66 ' 3lli2 ' 3il24 ' iilie' '  SlUs  32:00  32:12  32:24  32136  32^8  33:00  33il2
 353.8970 S:13 F:2 SMO(1,3)  BSUB(128,15,-3.0)  PKDf3,3,3,0.10%,1724.0,1.00%,F,F)
 100%                                                            A1.27E8         A1.32E8

  50J
   OJ
                                                                                                                   4.

                                                                                                                  ':2.
      ' 36!i2 '  36124 '  36136 ' 30148 ' 31166 ' 3lli2 ' 31124 ' 31136 '  SlUs ' 32166 ' 32ll2 ' 32124 ' 32136 ' 32148 ' 33166 ' 33ll2
 409.7974 S:13 F:2 SMO(1,3)  BSUB(128,15,-3.0)  PKD(3,3,3,100.00%,3216.0,1.00%,F,F)
                                          31:13                                 ,„.„„     32A36         33:00
              Time

            . OE3

            .5E3

            .OEO
              Time

            .6E7

            .8E7

            .OEO
              Time

             9E7

            .4E7

            .OEO
              Time
  50,
                 30:29
    30:1030j20
                 /I  y^\     ju;jj.   / \  .j   ^    A       f \  I \ r\  I \fJ

    ' 36112' ' 36124 ' '30:36 ' SO.Us ' 31166  ' 3ill2 ' 31124 ' 3ll36 ' 3ll48 ' 32166 ' 32112 ' 32124  32i36  32i48  33:00  33il2
 366.9792 S:13 F:2 SMO(1,3)  PKD(3,3,3,100.00%, 0.0,1.00%,F, F)
 100% 30:11    30:26      30:43    	31:09     31:26	
  50
                                                                31:55   32:09    32:23    32:38
Jlii£4_
     T,, ,.-..,.,,.,.,..,,.- r.T ,., | i | ,...,..., , .. , | ill j.'i |
       30ll2  30:24   30:36   30:48  31:00
                                              3il24 ' 3ilie ' 31148 ' 32166 ' 32112 ' 32124 ' 32136 ' 32:48 '  33166 ' 33ll2
                                                                                                                  _2

                                                                                                                   0
 Time

4E7

2E7

OEO
 Time
H*
CO
cn

-------
 (File: A20JUL98B  Acq:  21-JUL-1998 06:18:11  Exp:  EXP_M23_DB5_OVATION Voltage SIR EI-i-—GC Autospec-UltimaE—Paradigm
 Sample  #13   Text:  1072-7 xl/2  ALS #14
 373.8207  S:13  F:3  SMO(1,3)  BSUB(128,15,-3.0)  PKD(3,5,2,0.10%,1772.0,1.00%,F,F)
 100%.                                   A3 .39E4
                  1	1	1	1	1	1	1	1	1	1	1	1	1	F	1	1	1	1	1	1	1	1	1	1	1	1	1	1	1	1	1	1	1	1	1	1	1	1	1	1	1	1	1	1	1	1	1	1	1	1	1	1	1	1	1	1	1	1	1	1	1	1	1	1	P	1	t
       33:24    33:36    33:48    34:00    34:12    34:24   34:36    34:48    35:00    35:12    35:24    35:36    35:48 Time
 375.8178 S:13 F:3  SMO(1,3)  BSUB(128,15,-3.0)  PKD(3,5,2,0.10%,972.0,1.00%,F,F)
 100%                                  A1.38E4
                                                          A7.00E3
                                             A2.18E3  A3.09E3A  A8.74E3   A4.02E3
                                                                                                                  LO.OEO
       33:24    33:36    33:48    34:00    34:12    34:24    34:36    34:48    35:00    35!l2    35:24    35:36    35:48 Time
 383.8639 S:13 F:3 BSUB(128,15,-3.0)  PKD(3 , 5,2,0.10%,18720.0,1.00%,F,F)
 100%                                     A9.71E7                                                                  4.3E7
  50J
   OJ
       -i—I—i—i  I i  i I i—i—i—i—i  I i—i—i—i—i—I—i i  i 'i  i—\—i—i~i I i  I i  i i—i i I  i i—i—i  i I  i—i—i—i—i—I—i—i—i—i—i—1—i—i—i—i i I—i—i—i i  i I  i i  i i  i f " • "BO
       33:24    33:36   33:48    34:00    34:12   34:24    34:36    34:48    35:00   35:12    35:24    35:36    35:48 Time
                                                                                                            L2.2E7
 385.8610 S:13 F:3 BSUB{128,15,-3.0)  PKD(3,5,2,0.10%,42224.0,1.00%,F,F)
 100%                                     A1.87E8
  50J

   OJ
      i  i I  i—i  i i—i  i i  i i—i—i—r—i—i
       33:24    33:36   33:48
                                           I  I i I  I i  I i—i—i—i—i—r—i—r—i—t
                                   34112    34:24   34:36    34:48
                                                                                                             8.5E7

                                                                                                            L4.2E7

                                                                                                            LO.OEO
                                  T
                                34:00
445.7555 S:13 F:3 SMO(1,3) BSUB(128,15,-3.0) PKD(3,3,3,100.00%,1440.0,1.00%,F,F)
100%                                                             34:45     34:58
  50J
—i—i—i—i—i—i—i—|-~i—i  i i—i  i i—r—i—i—i  I i  i i  i—r—]
35:00    35:12    35:24   35:36    35:48  Time
   OJ
     33:22
                                                                                                           35:42
                                                                                                             8.7E3

                                                                                                            L4.4E3

                                                                                                             O.OEO
33:24    33:36    33:48    34:00    34:12    34:24    34:36    34:48    35:00   35:12    35T2V
                                                                                                               35:48  Time
80.9760
.00%
:
50J
o:
/


•33!
S:13 F:3
33:29



24



33!
SMO(1,3) PKD(3,3,3,100.00%,0.
33:45 34:0234:09



36 33!



48 34100



34! 12
0,1.00%,F,F)
34:22



34^24' ' '34:36
34:43 34:5435:02



34:48 35:00
35:15 35:29 35:43 8 . 9E7




.4.4E7
•O.OEO
35:12 35:24 35:36 35:48 Time
CO

-------
File: A20JUL98B  Acq:  21-JUL-1998  06:18:11  Exp:  EXP_M23_DB5_OVATION Voltage  SIR  EI+—GC Autospec-UltimaE—Paradigm
Sample  #13   Text:  1072-7 xl/2   ALS #14
407.7818  S:13  F:4 SMO(1,3)  BSUB(128,15,-3.0) PKD(3,3,3,0.10%,1644.0,1.00%,F,F)
100%               A1.73E4
        36166   36ll2  36J24  3e!36  36J48  37166   37112  37l24  3v!36  37148  38166  38Sl2   38124 '  38136 '
409.7788 S:13  F:4  SMO(1,3)  BSUB(128,15,-3.0) PKD(3,3,3,0.10%,1192.0,1.00%,F,F)
100%               A1.67E4

 50_
  O
                                                                                                            ^T-O.OEO
                                                                                                             39:00  Timi
                                                                                                                 7.7E3

                                                                                                                L3.8E3
                                                                                                                  O.OEO










       36:00  36il2  36i24  36i36  36148  37iOO  37il2  37i24  37i36  37i48  38iOO
417.8253 S:13 F:4 SMO(1,3) BSUB(128,15,-3.0)  PKD(3,3,3,0.10%,4536.0,1.00%,F,F)
100%              A5.26E7
                                                         A4.84E7
  O
                                                                                  38!l2
                                                                                         38I24 ' 38':36 '
         rr
                                                                                                                00  Time

                                                                                                                .1.6E7

                                                                                                                 7.9E6
                                                                                                                  O.OEO
                      T
                             T
       36!00  36.:12  36124  36136  SeUs ' 37166 ' 37112 ' 37124 ' 37136 ' 37148 ' 38166 '  38112 ' 38124 ' 38136 ' 38\48 ' 39\00  Time
419.8220 S:13 F:4 SMO(1,3) BSUB(128,15,-3.0) PKD(3,3,3,0.10%,19456.0,1.00%,F,F)
100%              A1.18E8                                Ai_iiE8                                                 ^3.6E7
50J
  0-
         T
               T
                                                           A
                                                                                                                .1.8E7
                                                                                                                  O.OEO
                      T
                             T
                                    T
      36100  36112  36:24  36136  36:48  37166 ' 37112 ' 37124 ' 37:36 ' 37148 ' 38166 '  38112 ' 38:24 ' 38:36 ' 38:48 ' 39:00  Time
79.7165 S:13 F:4 SMO(1,3) BSUB(128,15,-3.0) PKD(3,3,3,100.00%,4328.0,1.00%,F,F)
                                             37A09   37-21                  O0.nn                    „,.„„         ..6.6E3
         36:04            36:35     36:53
      35:5
 50J

  OJ
                                                                              nn
                                                                             :00
                                                                                                    ,a  ,,,
                                                                                                    38:42
                                                                                                               L3.3E3
                                                                                                                ^O.OEO
       36100  36112  36i24  36136  36148  37lOO  37ll2  37l24  37l36  37l48  38166  38 !l2 ' 38124 ' 38!36 ' 38!48 ' 39^00 Time
 30.9728 S:13 F:4 SMO(1,3) PKD(3,3,3,100.00%, 0.0,1.00%,F,F)
 00%	36:05	36:57  37:09   37:23  37:35
50J
"« OJ
;
36lOO 36ll2 36I24 36J36 36i48 37lo6 37112 37124 37136 37148 38!66 38112 38 124 ' 38 136 ' 38 :48 ' 39!
L3.0E7
• 0 OEO
00 Time

-------
File: A20JUL98BAcq:  21-JUL-1998 06:18:11Exp:  EXP_M23_DB5_OVATION Voltage SIR El-fGC Autospec-UltimaE—Paradigm	
Sample  #13   Text:  1072-7  xl/2   ALS #14
441.7427  S:13  F:5  SMO(1,3)  BSUB(128,15,-3.0)  PKD(3,3,3,0.10%,740.0,1.00%,F,F)
                                                               A4.69E3                                            3.1E3
           39:12      39i24      39i36      39i48      40iOO      40il2      40124
443.7398 S:13 F:5 SMO(1,3)  BSUB(128,15,-3.0)  PKD(3,3,3,0.10%,1188.0,1.00%,F,F)
100%.                                                         A1.35E4
40:36
                         40:48
    O.OEO
41100  Time

    4. OE3

   L2.0E3
           39:12      39.:24      39:36      39.:48      40iOO      40il2      40i24
469.7780 S:13 F:5 SMO(1,3) BSUB(128,15,-3.0)  PKD(3,3,3,0.10%,1488.0,1.00%,F,F)
100%                                                  A1.52E8

 50:

  ol
40:36
                        	
                         40:48      41:00  Time
           39:12      39:24      39:36      39:48      40iOO      40il2      40i24
471.7750 S:13 F:5 SMO(1,3) BSUB(128,15,-3.0) PKD(3,3,3,0.10%,1540.0,1.00%,F,F)
100%                                                  A1.71E8



_3 . 5E7
_1 . 8E7
O.OEO
40:36
                         40:48
41:00  Time
           39:12      39:24      39:36      39:48      40:00      40:12      40:24
513.6775 S:13 F:5 SMO(1,3) BSUB(128,15,-3.0) PKD(3,3,3,100.00%,668.0,1.00%,F,F)
lOOi                                                   40:00
                      41:00  Time
                                                                     40:16   40:25
                                                                                    40:3240:38   40:47
           39:12      39J24      39:36      39i48       40100
454.9728 S:13 F:5 SMO(1,3) PKD(3,3,3,100.00%,0.0,1.00%,F,F)
100*    39:09	39:36  39:44	40jJlfl
  4024      4036

40:21 40:28
                         10.0EO
                      41:00  Time

               4Q;S2      fi . 4E7
'
39:12 39124 39\36 39! 48 4o!ob 4o!l2 4o!24 4o!36 40:48 4l!
L3.2E7
LO.OEO
00 Time

-------
                                                                        Paradigm Analytical Labs
Analytical Data Summary Sheet
- Analyte - •••&
• > • iWVs'" •- - " • "- '"" - - •--• i"*"^
- ., „•• i\"',' "v •> , * .,, .-k^..
2,3,7,8-TCDD
1,2,3,7,8-PeCDD
1,2,3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
1,2,3,4,6,7,8-HpCDD
OCDD
2,3,7,8-TCDF
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
1,2,3,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
OCDF
Total TCDDs
Total PeCDDs
Total HxCDDs
Total HpCDDs
Total TCDFs
Total PeCDFs
Total HxCDFs
Total HpCDFs
TEQ(ND=0)
TEQ (ND=l/2)
Amount
(ng) .. s$j
EMPC
' ND -,v^
ND
ND
EMPC
0.0018
0.0046
0.0126
EMPC
0.0052
0.0024
EMPQ.,^
ND
m
0.0012
ND
ND
0.0012
ND
0.0056
0.0016
0.0948
0.0280
0.0040
0.0012
0,0041
0.0046


0.0005
0.0007
0.0005
0.0005
0.0004
0.0009
moeos
0.0005
0.0005
0.0004
,;:0.0003
0.0004
";:liil84;
0.0005
0.0006
0.0008
0.0005
0.0004
0.0005
0.0004
0.0005
0.0005
0.0003
0.0005


»AJB*MR!o8£li

0.0011
':'" ••' • • _f:

0.0011

0.0044

0.0008




0.0070
0.0020
0.0080
0.0050
0.119
0.0380
0.0050

0.0056
0.0058
X TMJ-iW* ^^
28:27
32:37 a
34:45
34:45
34:58
37:10
40:01
27:26
31:56
32:24
34:10
-34fl£
34:36
• •;:;,"?
36:21 "

40:11










^^^3^^^^^^^^^v»
1.13
"'Kit '
2.45
2-45 i
1.48
' i;l
0.91
0.79
1.83
1.63
1.07
0.77
0.59
ir-' •, ,
1.01

0.4










-Qualifier



















ITEF
ITEF
Client Information

Project Name:
Sample ID:

Laboratory Information

Project ID:
Sample ID:

Collection Date:
Receipt Date:
Extraction Date:
Analysis Date:
Texas Lime Kiln
L1072
1072-8
Sample Information

Matrix:
Weight/Volume:
Moisture / Lipids:
Original pH:

Filename:
                                                  Air
                                                   1
                                                  0.0
                                                  NA
                                                         Grams
   Ol-Jul-98
   OS-Jul-98
   15-M-98
Begin ConGal:
EndConCal:
Initial Cal:
                                              a20ju!98b-14
                                              a20ju!98b-l
                                              a20ju!98b-2
                                              a20ju!98b-17
                                               ra8296-23-071798
                                                                                                199
                                          1/2

-------
                                                                          Paradigm Analytical Labs
          . ^Xjnliv •. i   .,>'•'• y^-AAt/.*„'»--.
         Standard -  '• f %•< *'"•:••*-
Extraction Standards
 C12-2,3,7,8-TCDD
 3Ci2-l,2,3,7,8-PeCDD
13C,2-l,2,3,6,7,8-HxCDD
 3Ci2-U,3,4,6,7,8-IlpCDD
 3C,2-OCDD
 3Ci2-2,3,7,8-TCDF
 3C12-l,2,3,7,8-PeCDF
 3C12-l,2,3,4,6,7,8-HpCDF
Cleanup Standards
37,
 'CV2,3,7,8-TCDD '
 3C12-2,3,4,7,8-PeCDF
 3C12-l)2,3,4)7)8-HxCDD
 3C12-l,2,3,4,7,8-HxCDF
 3C12-l)2,3,4,7,8)9-HpCDF
Injection Standards
13/-
 JC12-1,2,3,4-TCDD
 'C^-l^.SJ.S^-HxCDD
                                Analytical Data Summary Sheet
4
4
4
4
8
4
4
4
4
      4
      4
      4
      4
                                             2.98
                  3.00
                  3.09
                  5.55
                  2.73
                  2.35
                  2-fl
                  2.44
                                             3.25
                                             3.88
                                             3.50
                                             3.95
                             74.6
                                                        75.0
                                                        77.4
                                                        69.4
58.8

60.9
                       81.3
                       97.1
                       87.4
                       98.7
28:26
32:36
34:44
37:08
40:00
27:24
31:56
34:14
36:20
          28:27
          32:24
          34:41
          34:09
          37:30

          28:09
          34:57
0.77
1.55
1.26
1.05
 0.9
0.79
1.57
0.52
0.44
            1.55
            1.25
            0.52
            0.45

            0.78
            1.25
Client Information
Project Name:
Sample ID:

Laboratory Information

Project ID:
Sample ID:

Collection Date:
Receipt Date:
Extraction Date:
Analysis Date:

Reviewed by:   H  -T-
Texas Lime Kiln
M23-I-4FH
1072-8
   Ol-Jfll-98
   08-Jul-98
   15-M-98
   21-Jul-98
                                                     Samle Information
                                                     Moi
                                                     •., "•. v   >.
                                                    • Original

                                                     Filename:
                                                     initial Cal;
                                                   Air
                                                  '  1
                                                   NA
                                                    Grams
                                                        %
                                         a20ju!98b-14
                                         a20ju!98b-l
                                          m8290-23-071798
                                           Date Reviewed:
                                                                                           ff  '  200
                                           2/2

-------
                                                                     Paradigm Analytical Labs
                              Analytical Data Summary Sheet
Analyte

2,3,7,8-TCDD
li2A7,8-P^5D
iJ2,3,4J,8-HxCbD"
1 ^ ^ '!%' j*'jttjyi^jpT\T'| ~!"
^^^^^itilfjirs^* \ ,f^ 5
1^ ^ T O Q tJr»/T\T"\
l£W.7,8-HpCDJ> *
OCDD
2,3,7,8-TCDF
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
1,2,3,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
OCDF
Total TCDDs
Total PeCDDs
Total HxCDDs
Total HpCDDs
Total TCDFs
Total PeCDFs
Total HxCDFs
Total HpCDFs
TEQ (ND=0)
TEQ (ND=l/2)
AmoHtfl^
"iPPv ."' *~
EMPC
'': NI> ".'"
ND
' ^^jjjJT\y^ -„ "
''~\'^&~£$i!i^~&^ - "' -t.
EMPC

0.154
0.424
EMPC
0.176
0.0797
EMPC
ND
ND
0.0419
ND
ND
0.0405
ND
0.189
0.0540
3.20
0.945
0.135
0.0405
0.139
0.156
;^;» I.
'- -; - - |{ft|tt£ f>^-*
0.0163
'••;dSl|3['vi
d.'0228 "
r'f\ AJiJff'""'- '
A*" >. ^"*^^^^*h *i,'t
0 0167

0.0305'**
0.0158 "
0.0171
0.0166
0.0144
0.0112
0.0131
0,0150
0.0165
0.0198
0.0254
0.0163- ,
0.0143
0.0165
0.0123
0.0158
0.0166
0.0112
0.0165


•^pwc:j
'N" ^Hpw"'
0.0364
I^??ti5

:^^Hij$?^'3J^l^t.

0.0365


;,>-?' •
0.149


0.0284





-0.229
0.0540
0.283
0.175
4.02
1.28
0.162

0.190
0.197
.-jar., :
tSPPs!' ". - ' >
28:27
4£3^7" .
" "34:45"
•• ' '• "%'jSs»"^fe "'""• ''
i*v -»^ *£ * .is^ ^
34:58

40:01
2?:24'.- ':
31:56
32:24
34:10
34:14
34:36

36:21

40:11










, Ratio

1.13
2.12
2.45
- \ "~, fiL *J^* s s
. " •**^**^"-V": -
1*48""""""
?#•-, ' ? ^^i^^i^1** ""
0.91
0.79
1.83
1.63
1.07
0.77
0.59

1.01

0.4










Qualifier







,;,w



















ITEF
ITEF
Client Information

Project Name:
Sample ID:

Laboratory Information

Project H>:
Sample ID:        ;: ;
Texas Lime Kiln
M23-I-4FH
Sample Information

Matrix:

Moisture/Lipids: ,
Extraction Date:
Analysis Date:
 Air
29.63
                                                NA
                                                      Grams
                                             m8290-23-071798
                                                                                      r     201
                                         1/2

-------
                                                                          Paradigm Analytical Labs
                                Analytical Data Summary Sheet
         Standard
                                                                  (D1IB.)
                                                                             Ratio
                                                                                      Qualifier
Extraction Standards
 C12-2,3,7,8-TCDD
 C12-OCDD
13C12-2,3,7,8-TCDF
 3C12-l,2,3,7,8-PeCDF
Cleanup Standards
37
 Cl4-2,3,7,8-TCDD
  C12-l,2,3,4,7,8-HxCDF
  C,2-l,2,3,4,7,8,9-HpCDF
Injection Standards
13
  C12-1,2,3,4-TCDD
 3Ci2-l,2,3,7,8,9-HxCDD
4
4
8
4
4
4
4
                                  4
                                  4
                                  4
                                  4
                                  4
                                             2.98

                                             3.00
5.55
2.73
2.35
2.59
2.44
            3.56
            3.25
            3:88
            3.50
            3.95
 74.6
ill!
 75.0
                                                         69.4
                                                         58.8
                                                         64.8
                                                         60.9
           89.1
           81.3

           87.4
           98.7
                                 28:26
           28:27
           32:24
           34:41
           34:09
           37:30


           28:09
           34:57
                                 0.77
                                                                              1.26
                       0.9
                      0.79
                       1.57
                      0,52
                      0.44
1.55
1.25
0.52
0.45


0.78
1.25
Client Information
Project Name:
Sample ID:

Laboratory Information

Project ID:
Sample ID:
"'••&:••**
Collection Date:
Receipt Date:
Extraction Date:
Analysis Date:

Reviewed by:   Y^
                            Texas Lime Kiln
                            M23-I-4FH
                            L1072"
                    Sample Information

                    Matrix:
                    Weight/Volume:
                    Moisture/ Lipids:
                    Original pH:
                                  Air
                                 29.63    Grams
                                  0.0         %
                                  NA

                              a20ju!98b-14
                                                                            m8290-23-071798
                                                                             v •."-,, 5.*;,&"' -  ,"
                                     Date
                                                                                      jft
                                                                                            r
                                            2/2

-------
OPUS^ 21-JUL-1998 Page 1
Filename a20ju!98b
Sample 14
Acquired 21-JUL-98 07:03:15
Processed 21-JUL-98 13:48:53
Sample ID 1072-8 xl/2
Cal Table m8290-23-071798
Results Table M8290-23-072098B
Comments
Typ
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
ES/RT
ES
ES
ES
ES
ES/RT
ES
ES
ES
JS
JS
CS
CS
CS
CS
CS
SS
SS
SS
SS
SS
Name ; Resp ;
2,3,7,8-TCDD; 2.916+05;
1,2,3,7,8-PeCDD; 1.22e+04;
1,2,3,4,7,8-HxCDD; 3.18e+04;
1,2,3,6,7,8-HxCDD; 3.18e+04;
1,2,3,7,8,9-HxCDD; 5.43e+04;
1,2,3,4,6,7,8-HpCDD; 7.10e+04;
OCDD; 1.486+05;
2,3,7,8-TCDF; 1.80e+06;
1,2,3,7,8-PeCDF; 2.54e+05;
2,3,4,7,8-PeCDF; 3.11e+05;
1,2,3,4,7,8-HxCDF; 1.18e+05;
1,2,3,6,7,8-HxCDF; 5.42e+04;
2,3,4,6,7,8-HxCDF; 3.40e+04;
1,2,3,7,8,9-HxCDF; *;
1,2,3,4,6,7,8-HpCDF; 5.31e+04;
1,2,3,4,7,8,9-HpCDF; *;
OCDF; 2.25e+04;
13C-2,3,7,8-TCDD; 3.09e+08;
13C-l,2,3,7,8-PeCDD; 2.046+08;
13C-l,2,3,6,7,8-HxCDD; 2.366+08;
13C-l,2,3,4,6,7,8-HpCDD; 1.806+08;
13C-OCDD; 2.596+08;
13C-2,3,7,8-TCDF; 3.556+08;
13C-l,2,3,7,8-PeCDF; 2.66e+08;
13C-1 , 2,3,6,7, 8-HxCDF ; 2 . 34e+08 ;
13C-l,2,3,4,6,7,8-HpCDF; 1.346+08;
13C-1,2,3,4-TCDD; 3.77e+08;
13C-l,2,3,7,8,9-HxCDD; 2.916+08;
37Cl-2,3,7,8-TCDD; 3.38e+08;
13C-2,3,4,7,8-PeCDF; 3.60e+08;
13C-l,2,3,4,7,8-HxCDD; 2.01e+08;
13C-1, 2 ,3,4,7, 8-HxCDF; 2 . 46e+08;
13C-l,2,3,4,7,8,9-HpCDF; i.70e+08;
37Cl-2,3,7,8-TCDD; 3.386+08;
13C-2,3,4,7,8-PeCDF; 3.60e+08;
13C-1, 2 ,3,4,7, 8-HxCDD; 2 . Ole+08 ;
13C-l,2,3,4,7,8-HxCDF; 2.46e+08;
13C-l,2,3,4,7,8,9-HpCDF; 1.70e+08;








Ion 1;
4.33e+04;
8.266+03;
2.266+04;
2.26e+04;
3.23e+04;
3.71e+04;
7.04e+04;
7.97e+05;
1.64e+05;
1.936+05;
6.106+04;
2.37e+04;
1.27e+04;
* .
2.676+04;
* .
6.46e+03;
1.356+08;
1.246+08;
1.32e+08;
9.18e+07;
1.23e+08;
1.566+08;
1.626+08;
8.056+07;
4.116+07;
1.65e+08;
1.626+08;
3.386+08;
2.19e+08;
1.12e+08;
8.41e+07;
5.24e+07;
3.38e+08;
2.196+08;
1.126+08;
8.41e+07;
5.24e+07;








Ion 2;
2.47e+05;
3.906+03;
9.21e+03;
9.21e+03;
2.196+04;
3.38e+04;
7.776+04;
l.Ole+06;
8.97e+04;
1.18e+05;
5.70e+04;
3.066+04;
2.136+04;
* .
2.64e+04;
* .
1.60e+04;
1.74e+08;
8.02e+07;
1.04e+08;
8.786+07;
1.36e+08;
1.99e+08;
1.04e+08;
1.546+08;
9.28e+07;
2.126+08;
1.306+08;
_ .
1.41e+08;
8.96e+07;
1.626+08;
1.176+08;
_ .
1.416+08;
8.966+07;
1.626+08;
1.176+08;









0
2
2
2
1
1
0
0
1
1
1
0
0

1

0
0
1
1
1
0
0
1
0
0
0
1

1
1
0
0

1
1
0
0








RA;?;
.18;n;
.12;n;
-45,-n;
.45;n;
.48;n;
.10;y;
.91,-y;
•79;y;
.83;n;
.63;y;
.07;y;
.77;n;
.59;n;
*;n;
• 01,-y;
*;n;
.40;n;
.77;y;
-55;y;
• 26,-y;
. 05, -y;
. 90;y;
•79;y;
.57;y;
-52;y;
. 44;y;
-78;y;
.25,-y;

. 55;y;
• 25,-y;
-52;y;
.45;y;
_ . _ .
55-y;
25;y;
52 ;y;
45;y;
Wtzi







RT;
28:27;
32:37;
34:45;
34:45;
34:58;
37:10;
40:01;
27:26;
31:56;
32:24;
34:10;
34:14;
34:36;
NotFnd;
36:21;
NotFnd;
40:11;
28:26;
32:36;
34:44;
37:08;
40:00;
27:24;
31:56;
34:14;
36:20;
28:09;
34:57;
28:27;
32:24;
34:41;
34:09;
37:30;
28:27;
32:24;
34:41;
34:09;
37:30;
a-63

.--
V.




Cone ;
0.096;
0.005;
0.021;
0.015;
0.027;
0.044;
0.114;
0.533;
0.110;
0.130;
0.059;
0.021;
0.015;
*;
0.031;
* .
0.016;
74.606;
70.828;
75.030;
77.353;
138.736;
68.296;
58.800;
64.825;
60.925;
78.245;
73.563;
89.047;
81.270;
97.061;
87.415;
98.726;
119.423;
138.263;
129.482;
133.795;
162.102;

_yjl
•z, * '





DL;
0.0121;
0.0106;
0.0169;
0.0122;
0.0124;
0.0091;
0.0226;
0.0117;
0.0127;
0.0123;
0.0107;
0.0083;
0.0097;
0.0111;
0.0122;
0.0147;
0.0188;
0.0308;
0.0182;
0.0336;
0.0204;
0.0151;
0.0180;
0.0077;
0.1221;
0.1053;
-;
— ;
0.0097;
0.0079;
0.0509;
0.1567;
0.1346;
0.0135;
0.0082;
0.0647;
0.2139;
0.2691;








S/N1;?;
8;y;
2;n;
3;y;
,3;y;
5;y;
15;y;
ll;y;
122;y;
49;y;
70;y;
ll;y;
4;y;
3;n;
*;n;
8;y;
*;n;
2,-n;
4221,-y;
15359;y;
6601;y;
6015;y;
13855;y;
8767;y;
87979;y;
1360;y;
1164 ; y;
5366;y;
7727;y;
27185;y;
129276;y;
7336;y;
1577;y;
1329;y;
27185 ;y;
129276;y;
7336;y;
1577, -y;
1329, -y;








S/N2;?
41 ;y
2;n
3;n
3;n
5;y
15;y
34 ;y
97 ;y
11 * V
•*• •*• ' Jr
17 ;y
19 ;y
10,-y
7;y
*,-n
9;y
*;n
3;y
14348;y
32377;y
7639,-y
14244 ;y
21217 ;y
14263;y
19850;y
2138;y
1585;y
18158;y
9092 ;y
-; -
28951;y
8348;y
2527;y
1788;y
-; -
28951;y
8348;y
2527;y
1788;y
mod?
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
                                                                                                                                             Page 19
10
o
Co

-------
OPUSquan   21-JUL-1998
                   Page  1
                                                                    Page 1 of 8

 Ent: 39 Name: Total Tetra-Furans  F:l  Mass:  303.902 305.899 Mod? no   #Hom:19

 Run: 19 File: a20ju!98b    S:14 Acq:21-JUL-98 07:03:15 Proc:21-JUL-98 13:48:53
 Tables: Run: a20ju!98b  Analyte: m8290-23-»  Cal:  m8290-23-»Results: M8290-23»
 Version: V3.5 17-APR-1997 11:14:34  Sample text: 1072-8 xl/2
   Amount: 2.98
     Cone: 2.98
   Tox #1: -
 2,3,7,8-TCDF
of which 0.53
of which 0.53
     Tox #2:  -
named and 2.45
named and 2.45
      Tox #3: -
                         RT Respnse
                                        RA
                      23:38 2.26+05  0.92 n
                            2.2e+05
2  24:13 1.2e+05  0.94 n
         1.2e+05

3  24:33 2.5e+05  0.70 y
         2.5e+05

4  24:51 6.1e+05  0.65 n
         6.1e+05

5  25:00 1.3e+05  0.75 y
         1.3e+05

6  25:09 1.6e+05  0.67 y
         1.6e+05

7  25:15 2.9e-r05  0.46 n
         2.9e+05

8  25:17 2.7e+05  0.35 n
         2.7e+05

9  25:44 1.4e+06  0.75 y
         1.4e+06

10 26:00 l.le+05  0.94 n
         l.le+05

 11 26:08 2.5e+05  0.81 y
         2.5e+05

 12 26:25 4.8e+05  0.90 n
         4.8e+05

 13 26:33  1.2e+05  0.71 y
          1.26+05

 14 26:50  l.le+06   0.80  y
          l.le+06

 15 27:10  7.26+05   0.77  y
          7.2e+05

 16 27:26 1.86+06   0.79 y
          l.Se+06

 17 28:02 1.4e+06  0.78 y
          1.4e+06

 18 28:18 5.7e+05  0.68 y
          5.7e+05

 19 29:47 1.9e+05  0.75 y
          1.96+05
          Cone

           0.06
               3
               ]
           0.03
               C
               c
           0.07
               ]
               :
           0.18


           0.04
    unnamed
    unnamed
                                                      Area  Height    S/N  Mod?
 l.Oe+05 2.3e+04 2.2e+01 y  n
 l.le+05 2.4e+04 1.4e+01 y  n
3
 5.6e+04 1.2e+04 1.2e+01 y  n
 5.96+04 l.Se+04 8.9e+00 y  n

 l.Oe+05 2.0e+04 2.0e+01 y  n
 1.4e+05 3.16+04 1.8e+01 y  n
3
 2.4e+05 4.6e+04 4.5e+01 y  n
 3.76+05 7.06+04 4.16+01 y  n
                                                0.05
                                                0.09
               5.6e+04  8.2e+03  8.0e+00 y  n
               7.46+04  1.4e+04  8.56+00 y  n

               6.2e+04  1.7e+04  1.6e+01 y  n
               9.3e+04  2.2e+04  1.3e+01 y  n
               J
               9.1e+04  2.1e+04  2.0e+01 y  n
               2.0e+05  2.7e+04  1.6e+01 y  n
                                                0.08
                                                0.40
                                                0.03
                6.96+04  1.96+04  1.9e+01 y  n
                2.0e+05  2.7e+04  1.66+01 y  n
               3
                5.8e+05  l.le+05  l.le+02 y  n
                7.86+05  1.5e+05  8.8e+01 y  n
               i
                5.2e+04  l.Oe+04  9.8e+00 y  n
                5.5e+04  l.le+04  6.7e+00 y  n
                                                0.07
                                                0.14
                                                0.04
                l.le+05 2.3e+04 2.3e+01 y  n
                1.46+05 2.76+04 1.6e+01 y  n
               1
                2.3e+05 4.3e+04 4.2e+01 y  n
                2.5e+05 5.2e+04 3.1e+01 y  n
               1
                5.0e+04 1.2e+04 l.le+01 y  n
                7.26+04 1.7e+04 l.Oe+01 y  n
                                                0.32
                                                0.21
                4.8e+05 l.Oe+05 9.9e+01 y  n
                6.1e+05 1.3e+05 7.6e+01 y  n
                I
                3.1e+05 6.5e+04 6.4e+01 y  n
                4.0e+05 8.7e+04 5.2e+01 y  n
                                                0.53
                                                0.41
                                                 0.17
                                                 0.06
                8.0e+05 1.3e+05 1.26+02 y  n
                l.Oe+06 1.6e+05 9.7e+01 y  n
                L
                6.1e+05 1.3e+05 1.2e+02 y  n
                7.7e+05 1.66+05 9.7e+01 y  n
                7
                2.36+05 4.9e+04 4.8e+01 y  n
                3.4e+05 6.5e+04 3.9e+01 y  n
                5
                8.1e+04 1.3e+04 1.3e+01 y  n
                l.le+05 1.9e+04 1.2e+01 y  n

-------
OPUSguan   21-JUL-1998
                   Page 2
                                                                   Page 2 of 8

 Ent: 40 Name: Total Tetra-Dioxins F:l  Mass:  319.897  321.894 Mod? no   #Hom:8

 Run: 19 File: a20ju!98b    S:14 Acq:21-JUL-98 07:03:15 Proc:21-JUL-98  13:48:53
 Tables: Run: a20ju!98b  Analyte:  m8290-23-»  Cal:  m8290-23-»Results: M8290-23*
 Version: V3.5 17-APR-1997 11:14:34  Sample text:  1072-8 xl/2
   Amount: 0.23
     Cone: 0.23
   Tox #1: -
Name
2,3,7,8-TCDD
of which 0.10
of which 0.10
     Tox #2:  -
named and 0.13
named and 0.13
      Tox #3: -
                         RT Respnse
                                        RA
                      25:15 1.3e+05  0.94 n
                            1.3e+05
2  25:40 8.4e+04  0.79 y
         8.4e+04

3  26:52 3.7e+04  0.22 n
         3.7e+04

4  26:54 4.4e+04  0.44 n
         4.4e+04

5  27:24 4.9e+04  3.40 n
         4.9e+04

6  28:09 2.4e+04  0.85 y
         2.4e+04

7  28:16 2.3e+04  2.SO n
         2.3e+04

8  28:27 2.9e+05  0.18 n
         2.9e+05
          Cone

           0.04
               C
               t
           0.03
               T
               4
           0.01
               (

           0.01
               ]

           0.02

               ]
           0.01
               ]
               ]
           0.01
               1
               «
           0.10
   unnamed
   unnamed
                                   Area  Height
                                                                      S/N  Mod?
 6.4e+04  1.6e+04 1.4e+01 y  n
 6.8e+04  1.4e+04 l.le+01 y  n

 3.7e+04  7.5e+03 6.4e+00 y  n
 4.7e+04  9.9e+03 7.6e+00 y  n

 6.8e+03  3.0e+03 2.6e+00 n  n
 3.1e+04  6.1e+03 4.7e+00 y  n

 1.3e+04  4.0e+03 3.5e+00 y  n
 3.1e+04  6.1e+03 4.7e+00 y  n
2
 3.7e+04  9.1e+03 7.8e+00 y  n
 l.le+04  2.4e+03 1.8e+00 n  n

 l.le+04  2.3e+03 2.0e+00 n  n
 1.3e+04  4.7e+03 3.6e+00 y  n
  .7e+04 3.7e+03  3.2e+00  y   n
  .0e+03 2.16+03  1.6e+00  n   n

 4.3e+04 8.96+03  7.7e+00  y   n
 2.5e+05 5.4e+04  4.1e+01  y   n
                                                                                                         205

-------
OPUSquan   21-JUL-1998
                   Page 3,
                                                                    Page 3 of 8

 Ent: 41 Name: Total Penta-Furans  F:2  Mass:  339.860 341.857 Mod? no   #Horn:10

 Run: 19 File: a20ju!98b    S:14 Acq:21-JUL-98 07:03:15 Proc:21-JUL-98 13:48:53
 Tables: Run: a20ju!98b  Analyte: m8290-23-»  Cal:  m8290-23-»Results: M8290-23*
 Version: V3.5 17-APR-1997 11:14:34  Sample text: 1072-8 xl/2
   Amount: 1.00
     Cone: 1.00
   Tox #1: -
Name
of which 0.24
of which 0.24
     Tox #2:  -

#     RT Respnse
named and 0.76
named and 0.76
      Tox #3: -
                                        RA
 1,2,3,7,8-PeCDF
 2,3,4,7,8-PeCDF
1  30:15 7.1e+04  1.50 y
         7.1e+04

2  31:21 S.le+05  1.70 y
         8.1e+05

3  31:28 1.4e+05  2.08 n
         1.4e+05

4  31:38 4.36+04  2.75 n
         4.3e+04

5  31:44 l.Se+05  1.54 y
         1.5e+05

6  31:56 2.5e+05  1.83 n
         2.56+05

7  32:03 1.8e+05  2.01 n
         1.8e+05

8  32:08 1.7e+05  1.63 y
         1.7e+05

9  32:24 3.1e+05  1.63 y
         3.1e+05

10 32:29 2.26+05  1.58 y
         2.2e+05
          Cone

           0.03
               4

           0.35
               C

           0.06
               9
               4
           0.02
               T
               ]
           0.06
               e
               c
           0.11
               1
               9
           0.08
               ]
               (.
           0.07
                1
                £
           0.13
                ]
                ]
           0.09
  unnamed
  unnamed
  Area  Height
                                                                      S/N  Mod?
                                                   4.3e+04 8.9e+03 9.1e+00 y  n
                                                   2.9e+04 6.6e+03 2.8e+00 n  n

                                                   5.1e+05 1.4e+05 1.5e+02 y  n
                                                   3.0e+05 8.56+04 3.5e+01 y  n
                                                  S
                                                   9.6e+04 2.8e+04 2.8e+01 y  n
                                                   4.6e+04 1.6e+04 6.5e+00 y  n
                                                  I
                                                   3.1e+04 9.1e+03 9.3e+00 y  n
                                                   l.le+04 4.2e+03 1.8e+00 n  n
                                                   8.8e+04 2.5e+04 2.6e+01 y  n
                                                   5.7e+04 1.8e+04 7.6e+00 y  n
1.66+05 4.8e+04 4.96+01 y  n
9.0e+04 2.6e+04 l.le+01 y  n

 .26+05 4.5e+04 4.6e+01 y  n
 .1e+04 2.2e+04 9.4e+00 y  n

l.Oe+05 3.6e+04 3.7e+01 y  n
6.46+04 2.2e+04 9.1e+00 y  n

 .96+05 6.96+04 7.06+01 y  n
 .2e+05 4.16+04 1.76+01 y  n
                                                    1.36+05  S.Oe+04  S.le+01  y  n
                                                    8.56+04  3.16+04  1.36+01  y  n
                                                                     Page 4  of  8

  Ent:  42 Name:  Total Penta-Dioxins F:2  Mass:  355.855  357.852  Mod?  no    #Hom:5

  Run:  19 File:  a20ju!98b    S:14 Acq:21-JUL-98 07:03:15 Proc:21-JUL-98 13:48:53
  Tables: Run:  a20ju!98b  Analyte: m8290-23-»  Cal:  m8290-23-»Results:  M8290-23*
  Version: V3.5 17-APR-1997 11:14:34  Sample text:  1072-8 xl/2
    Amount:  0.08
      Cone:  0.08
    Tox #1:  -
 of which 0.01
 of which 0.01
      Tox #2:  -
 named and 0.07
 named and 0.07
       Tox #3: -
 Name
                    #
                          RT Respnse
                    1  31:28 8.36+04
                             8.3e+04
                      RA

                   1.83 n
                       31:48 1.96+04  2.50 n
                             1.96+04

                       31:56 3.76+04  9.51 n
                             3.7e+04

                       32:24 3.1e+04  7.72 n
                             3.1e+04
           Cone

            0.04
                c

            0.01
                ]
                c
            0.02
                ^

            o.oi
   unnamed
   unnamed
   Area  Height
                                                                       S/N  Mod?
                                 5.4e+04 1.8e+04 9.0e+00 y  n
                                 2.9e+04 7.0e+03 8.6e+00 y  n

                                 1.4e+04 4.2e+03 2.1e+00 n  n
                                 5.4e+03 1.9e+03 2.3e+00 n  n
                                2
                                 3.4e+04 l.Oe+04 5.2e+00 y  n
                                 3.5e+03 1.6e+03 2.0e+00 n  n
                                I
                                 2.8e+04 l.Oe+04 5.1e+00 y  n
                                                                                                      r

-------
OPUSquan   21-JUL-1998
                   Page 4
1,2,3,7,8-PeCDD
   32:37 1.26+04  2.12 n
         1.26+04
                                               0.01
               3.6e+03  l.Se+03  1.8e+00  n  n
              1
               8.3e+03  3.6e+03  1.8e+00  n  n
               3.96+03  1.36+03  1.6e+00  n  n
 Ent: 43 Name: Total Hexa-Furans
                                                 Page  5  of  8

                F:3  Mass:  373.821 375.818  Mod?  no   #Horn:9
 Run: 19 File: a20ju!98b    S:14 Acq:21-JUL-98 07:03:15  Proc:21-JUL-98  13:48:53
 Tables: Run: a20ju!98b  Analyte: m8290-23-»  Cal:  m8290-23-»Results: M8290-23»
 Version: V3.5 17-APR-1997 11:14:34  Sample text:  1072-8 xl/2
   Amount: 0.17
     Cone: 0.17
   Tox #1: -
Name
of which 0.10
of which 0.10
     Tox #2: -

t     RT Respnse
named and 0.07
named and 0.07
      Tox #3:  -
                                        RA
                   1  33:31 2.2e+04  2.73 n
                            2.2e+04

                   2  33:37 9.le+04  1.15 y
                            9.1e+04

                   3  33:43 l.Oe+04  0.88 n
                            l.Oe+04

                   4  33:48 7.7e+03  0.92 n
                            7.7e+03

1,2,3,4,7,8-HxCDF  5  34:10 1.2e+05  1.07 y
                            1.2e+05

1,2,3,6,7,8-HxCDF  6  34:14 5.4e+04  0.77 n
                            5.4e+04

                   7  34:26 2.le+04  1.09 y
                            2.le+04

2,3,4,6,7,8-HxCDF  8  34:36 3.4e+04  0.59 n
                            3.4e+04

                   9  34:51 3.3e+03  12.79n
                            3.36+03
          Cone

           0.01
               3
               C
           0.04
               4
               4
           0.00
               4
               c
           0.00
               1
               4
           0.06
               «
               c
           0.02

               i
           0.01
               1
               1
           0.02
               1

           0.00
unnamed
unnamed
                                                      Area   Height
                                  S/N  Mod?
                                1.6e+04  6.4e+03  3.2e+00 y  n
                                5.8e+03  2.2e+03  2.4e+00 n  n

                                 .9e+04  1.7e+04  8.3e+00 y  n
                                 .3e+04  1.5e+04  1.7e+01 y  n

                                4.9e+03  1.9e+03  9.4e-01 n  n
                                5.5e+03  1.8e+03  2.0e+00 n  n
                               3
                                3.7e+03  1.5e+03  7.6e-01 n  n
                                4.0e+03  1.3e+03  1.46+00 n  n

                                6.le+04  2.le+04  l.le+01 y  n
                                5.7e+04  1.7e+04  1.9e+01 y  n
                               2
                                2.46+04  7.86+03  3.8e+00 y  n
                                3.16+04  9.26+03  l.Oe+01 y  n
                               L
                                1.le+04  2.6e+03  1.3e+00 n  n
                                l.Oe+04  2.3e+03  2.5e+00 n  n
                               2
                                1.3e+04  5.3e+03  2.6e+00 n  n
                                2.16+04  6.76+03  7.36+00 y  n
                               3
                                3.1e+03  1.2e+03  6-Oe-Ol n  n
                                2.4e+02  1.4e+02  1.5e-01 n  n
                                                                                                 r
                                                                                     207

-------
OPUSquan   21-JUL-1998
                   Page  5
                                                                    Page 6 of 8

 Ent: 44 Name: Total Hexa-Dioxins  F:3  Mass:  389.816 391.813 Mod? no   tHorn:8

 Run: 19 File: a20ju!98b    S:14 Acq:21-JUL-98 07:03:15 Proc:21-JUL-98 13:48:53
 Tables: Run: a20ju!98b  Analyte: m8290-23-»  Cal: m8290-23-»Results: M8290-23*
 Version: V3.5 17-APR-1997 11:14:34  Sample text: 1072-8 xl/2
   Amount: 0.28
     Cone: 0.28
   Tox #1: -
Name
of which 0.04
of which 0.04
     Tox #2: -

#     RT Respnse
named and 0.23
named and 0.23
      Tox #3:  -
                                        RA
                   1  33:52 2.7e+05  1.18 y
                            2.7e+05

                   2  33:59 9.1e+03  1.11 y
                            9.1e+03

                   3  34:10 8.2e+04  2.26 n
                            8.2e+04

                   4  34:14 4.5e+04  7.29 n
                            4.5e+04

                   5  34:19 3.0e+04  0.59 n
                            3.0e+04
 1,2,3,6,7,8-HxCDD  6
 1,2,3,7,8,9-HxCDD  8
   34:45 3.2e+04  2.45 n
         3.26+04
          Cone

           0.14
               3
               ]
           0.00
               4
               4
           0.04
               C

           0.02
               i
               c
           0.02
               ]
               ]
           0.02
unnamed
unnamed
Area  Height    S/N  Mod?
                                1.5e+05 5.1e+04 2.6e+01 y  n
                                1.2e+05 4.4e+04 3.5e+01 y  n

                                4.8e+03 1.4e+03 7.1e-01 n  n
                                4.3e+03 1.7e+03 1.4e+00 n  n

                                5.7e+04 2.0e+04 l.Oe+01 y  n
                                2.5e+04 8.5e+03 6.6e+00 y  n
                               2
                                3.96+04 1.3e+04 6.8e+00 y  n
                                5.4e+03 2.26+03 1.7e+00 n  n

                                l.le+04 3.8e+03 1.9e+00 n  n
                                1.96+04 5.2e+03 4-le+OO y  n
   34:52 5.0e+03
         5.0e+03

   34:58 5.4e+04
         5.46+04
                                      1.54  n
                                      1.48  n
                                                0.00
                                                0.03
               2.3e+04 6.3e+03 3.1e+00 y  n
               9.2e+03 3.5e+03 2.7e+00 n  n
               D
               3.0e+03 9.7e+02 4.96-01 n  n
               2.0e+03 9.9e+02 7.7e-01 n  n
               3
               3.2e+04 9.0e+03 4.5e+00 y  n
               2.2e+04 6.0e+03 4.7e+00 y  n
                                                                     Page 7 of 8

  Ent:  45 Name:  Total Hepta-Furans  F:4  Mass:  407.782 409.779 Mod? no   #Hom:l

  Run:  19 File:  a20ju!98b    S:14 Acq:21-JUL-98 07:03:15 Proc:21-JUL-98 13:48:53
  Tables: Run: a20ju!98b  Analyte: m8290-23-»  Cal:  m8290-23-»Results: M8290-23»
  Version: V3.5 17-APR-1997 11:14:34  Sample text:  1072-8 xl/2
    Amount: 0.03
      Cone: 0.03
    Tox #1: -
 Name
 of which 0.03
 of which 0.03
      Tox #2:  -

 #     RT Respnse
 named and *
 named and *
       Tox #3:  -
 unnamed
 unnamed
                                         RA
 1,2,3,4,6,7,8-HpCDFl  36:21 5.3e+04  l.Oly
                             5.36+04
           Cone    Area  Height    S/N  Mod?

            0.03
                2.7e+04 l.Oe+04 8.1e+00 y  n
                2.6e+04 7.1e+03 8.6e+00 y  n
                                                                     Page 8 of 8

  Ent: 46 Name: Total Hepta-Dioxins F:4  Mass: 423.777 425.774 Mod? no   #Hom:5

  Run: 19 File: a20ju!98b    S:14 Acq:21-JUL-98 07:03:15 Proc:21-JUL-98  13:48:53
  Tables: Run: a20ju!98b  Analyte: m8290-23-»  Cal: m8290-23-»Results: M8290-23*
  Version: V3.5 17-APR-1997  11:14:34  Sample text: 1072-8 xl/2
    Amount: 0.13
      Cone: 0.13
    Tox  #1: -
 of which 0.04
 of which 0.04
      Tox #2: -
 named and 0.09    unnamed
 named and 0.09    unnamed
       Tox #3: -

-------
OPUSquan   21-JUL-1998
                                     Page 6
Name
                         RT Respnse
                                       RA
                   1  36:20 4.3e+04   5.03 n
                            4.3e+04

                   2  36:35 2.7e+04   0.78 n
                            2.7e+04

                   3  36:39 4.2e+03   3.44 n
                            4.2e+03

l,2,3,4,6,7,8-HpCDD4  37:10 7.1e+04   1.10 y
                            7.1e+04

                   5  37:30 6.5e+04   3.74 n
                            6.5e+04
Cone

 0.03


 0.02
     ]
     ]
 0.00

     c
 0.04


 0.04
    Area  Height
                                                                     S/N  Mod?
 3.6e+04  l.le+04  1.7e+01 y  n
 7.2e+03  2.7e+03  4.0e+00 y  n

  .2e+04  4.5e+03  7.0e+00 y  n
  .5e+04  4.4e+03  6.4e+00 y  n

 3.3e+03  8.2e+02  1.3e+00 n  n
 9.5e+02  3.8e+02  5.6e-01 n  n
4
 3.7e+04  9.5e+03  1.5e+01 y  n
 3.4e+04  9.9e+03  1.5e+01 y  n
I
 5.1e+04  1.6e+04  2.4e+01 y  n
 1.4e+04  3.6e+03  5.3e+00 y  n
                                                                                                      209

-------
File: A20JUL98BAcq: 21-JUL-1998  07:03:15Exp: EXP_M23_DB5_OVATlON Voltage SIR EI +GC AutOspec-UltimaE	Paradigm
C=mT^1 o *1 A  rn^-,,t- . ir\Tl_O ,,1 /O   ATC *1 C
Sample  #14   Text:  1072-8  xl/2  ALS #15
319.8965  S:14  SMO(1,3)  BSUB(128,15,-3.0)  PKD(3,3,3 , 0.10%,1160.0,1.00%,F,F)
100%                               A6.44E4
                                                                    A3.75E4
                                                             A1.35E4
                                                       ^	^X
 50
                                         A3.71E4
                                  T
                                                 ~T
                                                                                     A4.33E4
                                                                 T
                 24:00          25:00          26:00           27:00
321.8936 S:14 SMO(1,3) BSUB(128,15,-3.0) PKD(3,3,3,0.10%,1304.0,1.00%,F,F)
100%

                                                                                                                  1.7E4

                                                                                                                  R .„
                                                                                                                 -8'4E3
                                                                                        i' r \ *•* T
 so
                  T
                                   A6.83E4
                                     A
                                                            A3.06E4
                                  T1
                                                 ~T
                                                                 T
                                                                              28:00           29:00

                                                                                    A2.47E5
                                                                                A1.30E
                                                                                  -cs ^
                                                                                                              30 00  Time

                                                                                                                   5.5E4

                                                                                                                  _2.8E4
                 24:00           25:00           26^00          27iOO
331.9368 S:14 SMO(1,3)  BSUB(128,15,-3.0)  PKD(3 , 3,3,0.10%,6444.0,1.00%,F,F)
100%
 so
  o:
                                                                              28:00

                                                                               A1.65E8
                                                                                    A1.35E8
                                                                                              i n*| ni "  i
                                                                                              29:00
                                              rr^-rT
                                               30:00   Time
                                                                                                                 _3.5E7
                                                                                                                 F
                 24:00          25:00           26:00           27:00
333.9339 S:14 SMO(1,3) BSUB(128,15,-3.0) PKD(3,3,3,0.10%,2440.0,1.00%,F,F)
100%
 50J
                                                                              28 oo
                                                                               A2.12E8
                                                                                   A1.74E8
                                                                                              29 oo
                                  T
                                                 T
                                                                T
                                                                     T	1	T~
                 24:00          25:00           26:00           27:00
327.8847 S:14 SMO(1,3) BSUB(128,15,-3.0) PKD(3,3,3 , 0.10%, 2564.0,1.00%,F,F)
100%
 so
                                                                              28:00
                                                                                                             3ooO   Time

                                                                                                                 _4.4E7
                                                                                             ~*	1	r
                                                                                              29:00
                                                                                    A3.38E8
                                           "^	'	T
                                               30:00  Time
                                                                                                                  7.0E7
                                                              27 00
                                                                              28 oo
                24:00           25:00          26:00
 16.9824  S:14  SMO(1,3)  PKD(3,3,3,100.00%,0.0,1.00%,F,F)
 00% 23U4   23:42  24:08   24:36  25:01 25:24  _ _26;M_26;23,   26:53,27:14  27:4228^03     28:^B
                                                                                              29:00          30:00   Time

                                                                                              	29:27 29:53. 4 . 2E7
                24 loo'
                                25 loo'
                                               26 loo'
27 I 00
28 loo'
                                                                                               rrr—'—'—'—rn
                                                                                                                 _2.1E7
                                                                                                                 .O.OEO
                                                                                             29loO
                                                                                                             30oO   Time

-------
File: A20JUL98BAcq:  21-JUL-1998  07:03:15Exp:  EXP_M23_DB5_OVATION Voltage SIR EI+  GC Autospec-UltimaEParadigm
Sample #14  Text: 1072-8  xl/2   ALS #15
355.8546 S:14 F:2 SMO(1,3)  BSUB(128,15,-3.0)  PKD(3,3,3,0.10%,1976.0,1.00%,F,F)
                                                A5.38E4                                                           _2.0E4
                                                                                                                  L9.8E3
 50J
       -i—i—IT—i—r—i—i—i—i—i—i—i—i—i—i—i—i—]—i—i—i—i—i—i—r—i—i—i—i—i—i—i—i—i—r—i—r—i—i—i—i—r~i—r r i—r—i—r—r'i—i—r—i—i—i—i—i—i—r~\—r—i—i—i—r—T—i—r—T—i—i—i—i—1—1—i—i—i—m—i—r*T*"i—i—i—i—r~\—r*-r— *
     30:12  30:24  30:36  30:48  31:00   31:12   31:24  31:36  31:48  32:00  32:12  32:24  32:36   32:48   33:00   33:12     Time
357.8517 S:14 F:2 SMO(1,3) BSUB(128,15,-3.0) PKD(3,3,3,0.10%,812.0,1.00%, F, F)
lOOi                                            A2.95E4


 50J
                                                                                                                  _7.4E3
     30:12  30:24  30:36  30:48  31:00  31:12   31:24  31:36  31i48  32100  32:12  32:24  32:36  32:48  33:00  33:12
367.8949 S:14 F:2 SMO{1,3)  BSUB(128,15,-3.0)  PKD(3,3,3,0.10%,2800.0,1.00%,F,F)
100%
 50J
                                                                                      A1.24E8
  n -1                                                       	/   v	                    I Q . QEQ
  u '• i i  I i i i i i I  i i i i i i  i i i i i i  i i i i i i i  i i i i i i i i  i i i i i i i  i i i i i i i  i i i i i i  I i i i i ' I  ' i i ' ' I  ' ' ' i ' | '' * [l I '  ll11 I ll1'1 I ''
     30:12  30:24  30:36  30:48  31:00  31:12   31:24  31:36  31:48  32:00  32:12  32:24  32:36  32:48  33:00  33:12    Time
                                                                                                                  _4.3E7
                                                                                                                  _2.2E7
369.8919 S:14 F:2 SMO(1,3) BSUB(128,15,-3.0)  PKD(3,3,3,0.10%,864.0,1.00%,F,F)
lOOi
 50J
                                                                                      A8.02E7
                                                                                                                  _2. 8E7
                                                                                                                  _1.4E7
  n-\                                                      	1   ^~		LO.OEO
  "'' I I  I I I I I I I  I I I I I I  I I I I I I  	 I I I  I I I I I I I  I I I I I I I  I I I I I I I  I I I I I I I  I I I I I I  I I I I I I I  I I I I I I  I I I I I I  I '•» I I ••'• I '•
     30:12  30:24  30136  30:48  31:00   31:12   31:24  31:36  31:48  32:00  32:12  32:24  32:36  32:48  33:00   33:12    Time
366.9792 S:14 F:2 SMO(1,3)  PKD(3,3,3,100.00%, 0.0,1.00%, F, F)
100*  30:14              30:46           31:15	31^35
 so:
  °4-r
                                                                     32:03
                                                                                32^23   32:36
32:53 33:04     ^.1E7
                                                                                                                  _2.OE7
                                              _ _	, ,  , , , , ,-, ,  , , , ..... ,  , ,	,,,,,,,,,.,, ,-, ,	    ,- ° •OEO
                                              "31:24 ' 31136 ' 31148 ' 32166 ' 32ll2 ' 32124 ' 32136 ' 32148 '  33166 '  33112     Time
       r r r i i i "r T i i i i I i  i i i i I i  i i 'i i I ''
     30:12  30124  30:36  30:48  31:00

-------
Pile
Samj
389
100§
50_
391.
1008
50_
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401.
100%
50_
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100%
so:
0"
;: A20JUL98B Acq: 21-JUL-1998 07:03:15 Exp: EXP M23_DB5 OVATION Voltage SIR EI+ GC Autospec-Ultimafi Parad
3le #14 Text: 1072-8 xl/2 ALS #15
8156 S:14 F:3 SMO(1,3) BSUB(128, 15, -3 . 0) PKD(3 , 5, 2 , 0 . 10% , 1988 . 0 , 1 . 00%, F, F)
A1.45E5
/ \ A5.65E4
} y /\^1^10E4 A2^26E4 A3^23E4
33124 33136 33148 34loO 34J12 34124 34J36 34148 3s!oO 3s!l2 35J24 3s{36 35!
8127 S:14 F:3 SMO(1,3) BSUB(128, 15, -3 . 0) PKD(3 , 5, 2 , 0 . 10% , 1280 . 0, 1 . 00%, F, F)
A1.23E5
/ V A/^!l^^ _A9^21E3 A2>19E4
i I1 ^ i i i i i ' i i i i" i i i P i r i i i T i i i i i i i i
8559 S:14 F:3 BSUB(128, 15, -3 . 0) PKD(3,5,2,0.
33:24 33\36 33\48 34loO 34ll2
8530 S:14 F:3 BSUB(128, 15, -3 . 0) PKD(3,5,2,0.
1 I i I I r"i I |—7 I I • i -r—i— r T-T r r- j r i r1 i i T i i i-
33:24 33:36 33:48 34:00 34:12
380.9760 S:14 F:3 SMO(1,3) PKD(3 , 3 , 3 , 100 . 00%, 0 . 0
100% 33:26 33:37 33:56 34:09
so:
0"
r' '
'33:24 33136' ' 33: 48' 34lo'o' ' ' 34.M.2
34:24 34:36 34:48 35:00 35:12 35I24 35I36 35!
10%, 7644. 0,1. 00%, F,F)
Al . 12E8 Al . 62E8
34!24 34136 34148 3s!oO 35ll2 35:24 35:36 35:
10%, 5332. 0,1. 00%, F,F)
A8.96E7 A1.30E8
igm
5.3E4
L2.7E4
48 Time
4 . 6E4
_2.3E4
_O.OEO
48 Time
5.9E7
_3 . OE7
_O.OEO
48 Time
_4 . 8E7
L2.4E7
' n.ORO
34:24 34:36 34:48 35:00 35:12 35:24 35:36 35:48 Time
,1.00%,F,F)
34:24 34:37 34^573^:05 ^ , 35:36 R.1R7

.4 . 1E7
.O.OEO
34:24 34:36 34:48 35:00 35:12 35:24 35:36 35:48 Time

-------
File: A20JUL98B Acq: 21-JUL-1998 07:03:lb
Sample #14 Text: 1072-8 xl/2 ALS #15
423.7767 S:14 F:4 SMO(1,3) BSUB(128 , 15 , -3 . 0)
100%
A3 . 62E4
so: A
0 ~-~_--v-^_ ' V J-—^ — —>_
36:00 36:12 36:24 36:36 36:48 37:
425.7737 S:14 F:4 SMO(1,3) BSUB(128 , 15, -3 . 0)
100%
50J A1.49E4
; A7.20E3 A
o "--^ — />•> — ^v^-^_ — A-X 	 / — \ — ._- — . — ~^-^-
36166 36li2 36124 36136 36\48 37\
435.8169 S:14 F:4 SMO(1,3) BSUB(128, 15, -3 . 0)
100%
50J
36:00 36:12 36:24 36:36 36:48 37:
437.8140 S:14 F:4 SMO(1,3) BSUB(128, 15, -3 . 0)
100%
50J
36:00 36:12 36:24 36136 36:48 37:
430.9728 S:14 F:4 SMO(1,3) PKD(3 , 3 , 3 , 100 . 00%
100% 35:58 36:23 36:4& 36:56
50.
o-
Exp: EXP_M23_DB5_OVATION Voltage SIR EI+ GC Autospec-UltimaE Paradigm
PKD(3,3,3,0.10%,648.0,1.00%,F,F)
A5.14E4 1.6E4
A3.71E4 \ '•
A /
/ \ / V A5.06E3 A2.47E3
00 ' 37} 12 ' 37l 24 ' 37 136
PKD(3, 3,3, 0.10%, 680.0,
A3.38E4
/ \ A1.37E4
,li_A^
I T 1 1 1 1 1 1 1 1 1 1 1 I 1 1 1 1 1 1
00 37:12 37:24 37:36
PKD(3,3, 3, 0.10%, 4136.0
A9 . 18E7
00 37:12 37:24 37:36
PKD(3,3,3,0.10%,1696.0
A8 . 78E7
00 37:12 37:24 37:36
,0.0,1. 00%, F,F)
37_tl5 37jJ6

I1 l"l 1 1— T—i—i-r III 1*1" 1 '! r'r r 1 I "1 1 1 i i ] i i i i r— r T--I-T -T— I T -i- r-rr i i r i i r i r-r T-
> 36:00 36:12 36:24 36i36 36:48 37iOO 37:12 37-24 37136
i i i i i i i i i i i ' i i ' i i i i i i i i i i i i i i i »i iT i T i T i i i i i ' " • """
37:48 38:00 38:12 38:24 38:36 38:48 39 00 Time
1.00%,F,F)
1.1E4
37:48 38166 38112 38124 38136 SsUs 39loO Time
,1.00%,F,F)
2 . 5E7
.1.2E7
O.OEO
37:48 38:00 38:12 38:24 38:36 38148 39100 Time
,1.00%,F,F)
2.4E7
.1.2E7
0 .OEO
37:48 38:00 38:12 38:24 38:36 38:48 39:00 Time
37:59 38:1438:24 38:36 38:55 5 . SE7
12 . 8E7
37:48 38:00 38-12 38124 38:36 38:48 39:00 Time

-------
File: A20JUL98B Acq: 21-JUL-1998 07:03:15 Exp: EXP M23 DB5 OVATION Voltage SIR EI-t- GC Autospec-UltimaE Parad
Sample #14 Text: 1072-8 xl/2 ALS #15
457.7377 S:14 F:5 SMO(1,3) BSUB (128, 15, -3 . 0) PKD(3 , 3 , 3 , 0 . 10%, 1668 . 0, 1 . 00%, F, F)
100% A7.04E4
so: / \
39ll2 ' 39124 ' 39136 39!48 40
459.7348 S:14 F:5 SMO(1,3) BSUB (128, 15, -3 . 0) PKD(3,3,3,0
100% A7
i . /
39ll2 39124 39136 s'gUs 40
469.7780 S:14 F:5 SMO(1,3) BSUB(128, 15, -3. 0) PKD(3,3,3,0.
100% Al.
/
o- J
39!l2 39124 39136 39!48 40
471.7750 S:14 F:5 SMO(1,3) BSUB(128, 15, -3 . 0) PKD(3,3,3,0.
100% Al.'
"- /
n- J
39ll2 39124 39136 39!48 40
454.9728 S:14 F:5 SMO(1,3) PKD(3,3 , 3 , 100 .00%, 0 .0, 1 . 00%, F,
100% 39:07 39:18 39:25 39:37 39:46 39:52
so:
39:12 39:24 39:36 39:48 40:
-| i 	 1 	 1 	 1 	 1 	 1 	 1 	 1 	 1 	 1 	 r 	 1 	 1 	 1 	 1 	 1 	 1 	 ] 	 1 	 1 	 1 	 , 	 1 	 1 	 1 	 1 	 1 	 1 	 , 	 1
:00 40:12 40:24 40:36 40:48 41
10%, 564. 0,1. 00%, F,F)
.77E4
\A1.92E3
	 ^ ^ r"~^ — 	 	 , 	 • — - 	 ——^^
lob 4o!l2 ' ' ' 40!24 ' ' ' 4o!36 ' ' ' 4ol48 4l!
10%,2012.0,1.00%,F,F)
23E8
!o6 4o!l2 4o!24 4o!36 ' ' 4o!48 41:
10%, 1468. 0,1. 00%, F,F)
J6E8
igm
0 OPO
00 Time
2 . OE4
.1 . OE4
.O.OEO
00 Time
2 . 8E7
.1.4E7
10.0EO
00 Time
_1 . 6E7
O.OEO
00 40:12 4ol24 4ol36 40:48 41-00 Time
F)
40:03 40:17 40:27 4Qs3q 40:45 40:54 6.2K7

.3.1E7
00 4o!l2 ' ' ' 4ol24 ' 40:36 ' ' ' 4ol48 ' ' 41:00 Time

-------
File: A20JUL98B Acq: 21-JUL-1998 07:03:
Sample #14 Text: 1072-8 xl/2 ALS #15
303.9016 S:14 SMO(1,3) BSUB (128, 15, -3 . 0)
50-. A2.38E5
: A1.04E5 A1.01E5A A9.ll!
n-. y\ s^ /\ J V — -lyYTV
15 Exp: EXP_M23_DB5_OVATION Voltage SIR EI+ GC Autospec-UltimaE Parad
PKD(3,3,3,0.10%,1028.0,1.00%,F,F)
AC Q/tc-c: A7.97E5 A6.06E5
A5-84E5 A485E5 X V
/ A2.28E5 A Al\ T2^1E5
:4 ; I !^A1E5A, 1 V A A / V A A8^E4
	 24 loo 	 25 loo 	 26 loo' ' ' ' 27loO 	 28loO 	 29loO 	 30 1
305.8987 S.-14 SMO(1,3) BSUB(128, 15, -3 . 0) PKD(3 , 3 , 3 , 0 . 10%, 1676 . 0, 1 . 00%, F, F)
100% A7 79E5 A1.01E6 A7.74E5
1 'A A6TE5 A A
50- A3.68E5 / A252E5 \\'f\\ A3.37E5
: A1.13E5 A1.44E5A Al^9E5 \ Al . 37E5 A \ \ \ \ A A1.08E5
n • y\ y~v y\ J v-^yi'v / V s~*S\ 1 v\ / V y v / V i \ 1 \ /^
	 24 100 	 25 loo
315.9419 S:14 SMO(1,3) BSUB (128, 15, -3 . 0)
lOOi
50J
n:
	 24 100 	 25 loo'
317.9389 S:14 SMO(1,3) BSUB(128, 15, -3 .0)
100%
50 j
0:
24:00 	 25:00'
375.8364 S:14 SMO(1,3) BSUB (128, 15, -3 . 0)
100%
50J
O^n2^3 n_n^3A55 ^4A2nn ^nn
24:00 25100
316.9824 S:14 SMO(1,3) PKD(3 , 3, 3 , 100 . 00%,
100*23:14 23:42 24:08 24:36 25:0125:
50J
oi
^- 24100 25:00
26:00 27:00 28:00 29:00 30:(
PKD(3,3,3,0.10%,3680.0,1.00%,F,F)
A1.56E8
26 loo' ' ' ' 27 loo' ' 28 loo' ' ' ' 29! 00 	 30 !(
PKD(3,3,3,0.10%,2856.0,1.00%,F,F)
A1.99E8
26:00 27 !00 28 [oO 29loO 30 !(
PKD(3,3,3,100.00%,92.0,1.00%,F,F)
28:26
25:44 26:12 26.40 27.0 " 1? 27:5/1 l\ ^'^
igm
1.3E5
1.6.4E4
DO Time
1.6E5
_8.2E4
O.OEO
30 Time
3.2E7
:l . 6E7
-O.OEO
)0 Time
4.1E7
1.2 . OE7
LO.OEO
)0 Time
r5.7E3
26:00 27 loo 28:00 ' 29! 00 	 30:00 Time
0.0,1.00%,F,F)
24 26:00 2.6:23 26:5327:14 27:4228:03 28:38 29i27 29:53 4. 2E7

_2 . 1E7
O.OEO
26 loo ' 27 !00 	 28 !00 	 29loO 	 30:00 Time
20

-------
File: A20JUL98BAcq: 21-JUL-1998  07:03:15Exp: EXP_M23_DB5_OVATION Voltage SIR EI+GC Autospec-UltimaEParadigm
Sample #14  Text: 1072-8 xl/2  ALS #15
339.8597 S:14 F:2 SMO{1,3) BSUB(128,15,-3.0) PKD(3,3,3,0.10%,976.0,1.00%,F,F)
100%                                        A5-14E5                                                               _1.5E5
 50j
  OJ
      A4.27E4
                                       A2.77
                                                               A1.64E5
                                             A1.93E5
                                               M
                                                                                                                 _7.3E4

                                                                                                                  O.OEO
            30:24 ' 3ol36 ' SoUs ' 31:00   31:12  31:24  31:36  31:48  32:00  32:12  32:24  32136 ' 32148 '  33166 '  33ll2     Time
341.8568 S:14 F:2 SMO(1,3) BSUB(128,15,-3.0) PKD(3,3,3,0.10%,2388.0,1.00%,F, 1
100%                                        A3.01E5
 50J
  o
      A2.86E4
                                                               A8.97E4
                                                                               A1.18E5
                                                                                 M
                                                                                8. 8E4

                                                                               .4.4E4

                                                                                O.OEO
     3bll2 ' 36I24
                                  .:00  31:12  31:24  31:36
                                 32:00  32:12  32:24  32:36  32Us  33loO   33:12     Time
351.9000 S:14 F:2 SMO(1,3) BSUB(128,15,-3.0) PKD(3,3,3,0.10%,628.0,1.00%,F,F)
100%.                                                                           A2.19E8
                                                               Al.62E8
 50J
  0
                                                                                                                 -8.1E7

                                                                                                                 L4.1E7
                                                                                                                 10.OEO
                                   :00  31:12  31:24  31:36  31:48  32:00  32:12  32:24  32:36  32:48   33:00  33:12    Time
     30:12  30:24
353.8970 S:14 F:2 SMO(1,3) BSUB(128,15,-3.0) PKD(3,3,3,0.10%,1796.0,1.00%,F,
100%
                                                               A1.04E8
  o
                                                                               A1.41E8
                                                                               -5.2E7

                                                                               _2.6E7

                                                                                O.OEO
     30:12  30:24  30:36  30:48  31:00  31:12  31:24  31:36  31:48  32:00  32:12  32:24  32:36  32:48  33:00  33:12    Time
409.7974 S:14 F:2 SMO(1,3) BSUB{128,15,-3.0) PKD(3,3,3,100.00%,1568.0,1.00%,F,F)
100%.                                                                                                 33; 01       _9.8E3
                                          31:18
     30:12  30:24  30:36  30:48
366.9792 S:14 F:2 SMO(1,3) PKD(3,3,3,100.00%,0.0,1.00%,F,F)
100%  30:14             30:46         31:10	31:35
 50J
  o
                                                                    32:03
                                                                               32^23  32:36
                                                               32:53 33 .-04
.4. 1E7
                                                                                                                _2. OE7
     30:12  30:24   30:36  30:48
.:00  31:12  31:24  31:36  31:48  32:00  32:12  32:24  32:36  32:48  33:00  33-.12
                                                                                                                    Time
tt

-------
File: A20JUL98B
Sample #14
373.8207
100%,

50.


^IJ]
375.8178
lOOi
50 j
0:


S:


Text:
14 F:3

A4.
Acq: 21-JUL-1999 07:03:
1072-8 xl/2
ALS #15
15 Exp: EXP_M23_DB5_OVATION

SMO(1,3) BSUB(128,15,-3.0)

87E4
A6

.10E4
l\
A1.58E/\ / \~
/\J A4^88E3____ ^^— X-
24
S:


' '33!
14 F:3
A4.

A5 . 81E/3
'33!
383.8639
100$
50J
Oi



'33!
385.8610
100%
50J
o:



'33!
445.7555
100%
50J
o:


33
s —
'33!
380.9760
100% 33
50 j
o;
'

^ '33!
1 1
24
S:



— i — i
24
S:



i i
24
S:


:25
•v
24
33!
14 F:3



' '33!
14 F:3



' '33!
14 F:3

33:
33:32f
J-^—l
' '33!
S:14 F:3
:26 33


24


— i — i — i — p
36 ' ""33 Us'
34:00
34:12
SMO(1,3) BSUB(128,15,-3.0)
26E4
\
V A4
V-^N^^. — . 	 .
36 33 [48
BSUB (128, 15



"1 — i — i — r-T'-r i i
36 33:48
BSUB(128,15



~i i — i — i — i — i — i — i—
36 33:48
A5
/
92E3 /
x~> -/
34:00
.70E4
V

PKD ( 3 ,



5, 2, 0.10%, 2024.0,


Voltage SIR EI+ GC Autospec-UltimaE Paradigm

1.00%,F,F)
r2'

VA1.27E4
A1.10E4 /"V7.80E3
•s. — • 	 - — ^ 	 il^^-^—^ ^ — ^ ^^^
34
PKD ( 3 ,


•24 34:36 34
5,2, 0.10%, 912. 0,1

A2.13E4
V \ A1.00E4 /\ A8.50
34 ! 12
,-3.0) PKD(3,5,2
AS.
1
y
34:00
41E7
f\ A
ft A

i 'i i
34:12
,-3.0) PKD(3,5,2
Al.
j
y
34:00
62E8
h
I\A

34 : 12
SMO(1,3) BSUB(128,15,-3.0)

33:42
36 r\
V \J!M°
36 33:48


33:59
'34:00'
SMO(1,3) PKD(3,3,3,100

34 • 12
y^
' i '
34:12
34
,0.10%


^ 	
34
,0.10%


\_
34
PKD ( 3 ,

/
^J
34
.00%, 0.0,1.
:37 33:56 34j_D9


-I—T— T— r--l • -| 	 i r
36 33:48


34:00


34 ! 12
34


34
124 34136 34
,24396. 0,1. 00%, F,



124 34 [36 34
,29972. 0,1. 00%, F,



124' ' '34! 36 34
3, 3, 100. 00%, 932.0
34:41
, 34:36/ \

S24' ' 34T36 34
00%,F,F)
:24 34:37


124 ' '34536' 34

.1.
0
148 35!00 35ll2 3s!24 3s!36 35 48
.00%,F,F)


E3 	 ^^^ ^L^53 Al . 6 6E3
1.
.8.
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F)



3.
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:o.
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,1.00%,F,F)
34:57
/\ / \ 35:24
J\ V 35:11 P\ 35:33 35:42
v-^' v-— __^~\^-v 	 r \~ 	 /\. 	 r-\ 	
7.
.3.
:o.
Us 35100 35!l2 35:24 35136 35Us

34:57 35:05 35:25 35t36 8.


_4.
0.
Us 35IOO 35ll2 35-124 35I36 35:48



4E4

2E4
OEO
Time

7E4
7E3
OEO
Time

8E7
9E7
OEO
Time

6E7
8E7
OEO
Time

2E3
6E3
OEO
Time

3E7
1E7
OEO
Time
{0

-------
   File:  A20JUL98B  Acq:  21-JUL-1998 07:03:15Exp:  EXP_M23_DB5_OVATION Voltage SIR EI +—GC Autospec-UltimaE—Paradigm
   Sample #14  Text: 1072-8 xl/2  ALS #15
   407.7818 S:14 P:4 SMO(1,3)  BSUB(128,15,-3.0)  PKD(3,3,3,0.10%,1248.0,1.00%,F,F)
   100%,              A2.67E4
          36iOO   36)12  36J24  36l36  36:48  31:00  37:12  37:24  37:36  37.'48  38166  38112  38:24  38136 '  38\48 ' 39.:00  Time
   409.7788  S:14  F:4  SMO(1,3)  BSUB(128,15,-3.0)  PKD(3,3,3,0.10%,828.0,1.00%,F,F)
   100%              A2.64E4
       36iOO  36!l2  36:24  36\36  36-148  37l6d  37112  37-I24  37136  37148  38166  38112 ' 38124 ' 38I36 ' 38148 ' 39:00  Time
417.8253 S:14 F:4 SMO(1,3) BSUB(128,15,-3.0) PKD(3,3,3,0.10%,10664.0,1.00%,F,F)
100%,              *„  11M                                 A5.24E7                                                 r_1.4E7
    50J

     OJ
                    A4.11E7
                                                                                                                 _7.1E6

                                                                                                                  O.OEO
        i i  i r i i i i i  i i i*i i i  i"1 I I i i i  i i i i i i i  i i i i i i i i i  i i i i i r i  i f i i i i i  i i i i i i i  i i i i i i i  i i i i i i i  i i i i i i  i i i i i i i  i i i i i i i  i
         36:00  36:12  36:24  36:36  36:48  37:00  37:12  37:24  37:36  37:48  38:00   38:12   38:24   38:36  38:48  39:00  Time
  419.8220 S:14 F:4  SMO(1,3)  BSUB(128,15,-3.0)  PKD(3 , 3,3,0.10%,17848.0,1.00%,F,F)
  100%

   50J
    Oj
                 A9.28E7
                                                         A1.17E8
         36:00 ' 36:12 ' 36:24 ' 36:36  36:48  37:00  37:12  37:24  37:36  37:48  38:00  38:12  38-24 ' 38:36
  479.7165 S:14 F:4 SMO(1,3) BSUB(128,15,-3.0) PKD(3 , 3, 3 ,100.00%,2052.0,1.00%,F,F)
  100%, or c,                                     37:09
       35 :56 -ic .Q^
 3.2E7

_1.6E7
                                                                                                                  O.OEO
         36:00  36:12  36:24  36:36  36:48   37:00  37:12  37:24  37:36  37:48  38:00  38:12  38t24  38536 ' 38.;48 ' 39loO  Time
  430.9728 S:14 F:4 SMO(1,3) PKD(3,3,3,100.00%,0.0,1.00%,F,P)
  100% _35L58	36:23	36:46 36:56      37:15	37:36
   50J

    OJ
                                                                          _3.7;59	38:14M;24  38:36   38:48
 i.6E7
                                                                                                                 _2.8E7

                                                                                                                 O.OEO
         i r |  i i i i i | i  i i i i i i i  i i i i i i  i i i i i i i i  i i	i i  i i i i i i i  i i i i i i i  i i i i i i i  i i i i i i i  i i i i i i  i	i  l i i i i i i  i i i i i
         36:00  36:12  36:24   36:36   36:48  37:00  37:12  37:24   37:36   37:48  38:00  38:12  38:24  38:36  38:48  39:00  Time
IS
on

-------
File: A20JUL98B—Acg: 21-JUL-1998 07:03:15Exp: EXP_M23_DB5_OVATION Voltage  SIR EH-GC Autospec-UltimaE
Sample #14  Text: 1072-8 xl/2  ALS #15
441.7427 S:14 F:5 SMO(1,3) BSUB(128,15,-3.0) PKD(3,3,3,0.10%,828.0,1.00%,F,F)
100%                                                            A6.46E3

 50 j
                                                                                                              Paradigm
     OJ
                                                                                        4ol36
                                                                                                                    3.2E3

                                                                                                                    i_1.6E3
                                                                                                                    .O.OEO
               1
                       1 - 1 - 1 - r—
                        39:24
                                     T"
                                                           T
                                                                      T
                                                                                 T
           39:12       39:24       39:36       39:48       40:00       40:12      40:24
443.7398 S:14 F:5 SMO(1,3) BSUB(128,15,-3.0) PKD(3,3,3,0.10%,1148.0,1.00%,F,F)
100%                                                           A1.60E4
    50
     OJ
                                                                                                                      .OEO


                                     T

                                                           T"
           39il2       39i24       39i36       39i48       40100       40:12      40:24
469.7780 S:14 F:5 SMO(1,3) BSUB(128,15,-3.0) PKD(3,3,3,0.10%,2012.0,1.00%,F,F)
100%                                                 A1.23E8

 50J

  OJ
                                                                                          40:36
                                                                                                   40:48
                                                                                         41:00  Time

                                                                                            2. 8E7

                                                                                            .1.4E7
                                                                                                                     I.OEO
                                                                      T
                                                                               T
           39ll2  ' '  '  39124      39136      39148      40lOO      40ll2      40i24
471.7750 S:14 F:5 SMO(1,3) BSUB(128,15,-3.0) PKD(3,3,3,0.10%,1468.0,1.00%,F,F)
100%                                                 Al.;

 50J
                                                            6E8
                                                                                                              41:00  Time

                                                                                                                  3. 1E7

                                                                                                                 Ll.6E7
                                                                                                                     I.OEO

                                                                      T
                                                                               T
           39ll2  ' '  '  39124 '  ' '  39136      39148      40IOO      40112      40:24
513.6775 S:14 F:5 SMO(1,3) BSUB(128,15,-3.0) PKD(3,3,3,100.00%,172.0,1.00%,F,F)
100%                                                   40iOO
                                                                                        40:36
                                                                                                      40:48
   50
                    39:19
                            39:31   39:40
                                             39:47
                                                                40:08
                                                                               40:27
                                                                                            40:40
                                                                                         41:00 Time

                                                                                            4.3E3

                                                                                            :2.2E3
                                                                                                                     O.OEO
             i  I  'i	1	1	r=*T—|	1—
             39:12      39:24
                                  T

                                 39:36       39:48       40:00
454.9728 S:14 F:5 SMO(1,3) PKD(3,3,3,100.00%,0.0,1.00%, F, F)
100%  39:07     39:18 39:25	39:37    39:46 39:52	40:03
                                                                  4o!l2
                                                                                        40:36
   50
     OJ
                                                                         40:17    40:27
                                                                              40:48       41:00 Time

                                                                    4Q:3R  40:45   40:54     6. 2E7
                                                                             40I24
                                                                                                                    .3.1E7
                                                                                                                     O.OEO
             i — i — i —
             39:12
39124
39136
39548
                                                                  4ol2
41:00  Time
CD

-------
OPUSquan   22-JUL-1998
                          Page 1
                                                                                                                                             Page 21
         Filename
           Sample
         Acquired
        Processed
        Sample ID
        Cal Table
    Results Table
         Comments
 Typ
 Unk
 ES/RT
        a21jul98f
        16
        22-JUL-98  05:23:13
        22-JUL-98  08:35:13
        1072-8 xl/2
        07feb-m23conf
        M8290-23-072198F
 Total
 DPE
 LMC
              Name;     Resp;
      2,3,7,8-TCDP; 1.17e+06;
  13C-2,3,7,8-TCDF; 3.94e+08;
      Tetra Furans; 8.04e+06;
            HxCDPE;        *;
QC CHK ION (Tetra);        *;
  Ion 1;
. 07e+05;
. 73e+08;
. 31e+04;
   Ion 2;
6.67e+05;
2.21e+08;
3.79e+04;
  RA;?;
0.76;y;
0.79,-y;
0.61;n;
   RT;
27:56;
27:53;
18:11;
  Cone;       DL;
 0.314;   0.0480;
96.480;
 2.149;   0.0480;
                         ;NotFnd;
                         ;NotFnd;
S/N1;?;
  18;y;
 773;y;
   4;y;
   *;n
DivO;n
S/N2;?
  25;y
 539,-y
   6;y
mod?
  no
  no
  no
  no
  no
                                                                -;-; 27:56
                                                                 ;-;  27:56

-------
OPUSquan   22-JUL-1998
                                      Page 1
 Ent: 3  Name: Tetra Furans
                                                 Page 1 of 1

                F:l  Mass:  303.902 305.899 Hod?  no   #Hom:24
 Run: 21 File: a21ju!98f    S:16 Acq:22-JUL-98 05:23:13 Proc:22-JUL-98 08:35:13
 Tables: Run: a21ju!98b  Analyte: m23_conf    Cal: 07feb-m23»Results:  M8290-23*
 Version: V3.5 17-APR-1997 11:14:34  Sample text:  1072-8 xl/2
   Amount: 2.15
     Cone: 2.15
   Tox #1: -
Name
 2,3,7,8-TCDF
of which 0.31
of which 0.31
     Tox #2:  -

f     RT Respnse
named and 1.84
named and 1.84
      Tox #3: -
                                        RA
1  18:11 6.1e+04  0.61 n
         6.16+04

2  18:13 l.Oe+05  0.88 y
         l.Oe+05

3  18:25 6.5e+03  0.27 n
         6.58+03

4  19:51 2.36+05  1.26 n
         2.36+05

5  20:41 5.1e+04  2.20 n
         5.1e+04

6  21:12 1.36+05  0.31 n
         1.36+05

7  22:10 6.46+05  0.73 y
         6.4e+05

8  22:34 1.3e+05  0.95 n
         1.3e+05

9  23:16 3.6e+05  0.68 y
         3.6e+05

10 23:18 4.36+05  0.69 y
         4.3e+05

11 24:18 7.8e+05  0.32 n
         7.8e+05

12 24:20 8.06+05  0.37 n
         S.Oe+05

13 24:59 6.5e+04  0.15 n
         6.56+04

14 25:01 l.le+05  0.38 n
         l.le+05

15 25:26 5.46+05  0.25 n
         5.4e+05

16 25:28 6.2e+05  0.41 n
         6.2e+05

17 26:29 2.5e+04  0.39 n
         2.56+04

18 27:56 1.2e+06  0.76 y
         1.26+06

19 28:31 1.6e+05  0.21 n
         1.6e+05
          Cone

           0.02


           0.03
               4
               c
           0.00
               1
               c
           0.06
               1
               1
           0.01

               ]
           0.04

               3
           0.17

               i
           0.04
               «
               e
           o.io
               :

           0.12
               ]

           0.21
               ]
               c
           0.21

               C
           0.02
               e
               c
           0.03

               £
           0.15
                :
               4
           0.16
                ]
                4
           0.01
                e
                1
           0.31
                c
                e
           0.04
   unnamed
   unnamed
                                                      Area  Height
                                  S/N  Mod?
                                                   2.3e+04 1.3e+04 3.6e+00 y  n
                                                   3.8e+04 2.0e+04 6.1e+00 y  n

                                                    .8e+04 1.6e+04 4.4e+00 y  n
                                                   5.5e+04 1.9e+04 5.8e+00 y  n
                                                  D
                                                   1.4e+03 7.56+02 2.16-01 n  n
                                                   5.1e+03 2.6e+03 8.1e-01 n  n

                                                   1.3e+05 2.8e+04 7.7e+00 y  n
                                                   l.Oe+05 3.0e+04 9.3e+00 y  n
                                                   3.5e+04 l.Oe+04 2.7e+00 n  n
                                                   1.6e+04 8.1e+03 2.5e+00 n  n

                                                   3.2e+04 9.86+03 2.7e+00 n  n
                                                   l.Oe+05 1.9e+04 5.9e+00 y  n
                                                  7
                                                   2.7e+05 4.6e+04 1.3e+01 y  n
                                                   3.76+05 6.5e+04 2.0e+01 y  n

                                                   6.4e+04 1.3e+04 3.6e+00 y  n
                                                   6.86+04 1.8e+04 5.7e+00 y  n

                                                   l.Se+05 4.7e+04 1.3e+01 y  n
                                                   2.1e+05 6.7e+04 2.1e+01 y  n
                                                   1.8e+05 5.56+04 1.5e+01 y  n
                                                   2.66+05 6.5e+04 2.0e+01 y  n

                                                     .96+05 6.0e+04 1.6e+01 y  n
                                                   5.9e+05 8.4e+04 2.6e+01 y  n
                                                   1
                                                   2.2e+05 5.56+04 l.Se+01 y  n
                                                   5.96+05 8.4e+04 2.6e+01 y  n
                                                   2
                                                   8.4e+03 6.0e+03 1.7e+00 n  n
                                                   5.7e+04 1.9e+04 5.9e+00 y  n
 3.16+04  1.2e+04  3.4e+00 y  n
 8.36+04  2.3e+04  7.1e+00 y  n

 l.le+05  4.2e+04  1.2e+01 y  n
 4.4e+05  5.7e+04  1.8e+01 y  n

  .8e+05  4.2e+04  1.2e+01 y  n
  .4e+05  5.7e+04  1.8e+01 y  n

 6.9e+03  3.5e+03  9.8e-01 n  n
 1.8e+04  9.9e+03  3.1e+00 y  n
L
 5.1e+05  6.5e+04  1.8e+01 y  n
 6.7e+05  8.1e+04  2.5e+01 y  n
4
 2.7e+04  1.2e+04  3.4e+00 y  n
 1.3e+05  2.2e+04  6.9e+00 y  n

-------
OPUSquan   22-JUL-1998
Page 2
                   20  28:32  1.6e+05  0.24 n    0.04
                            1.6e+05

                   21  28:37  3.76+04  0.89 n    0.01
                            3.7e+04
             3.0e+04  1.2e+04 3.4e+00 y  n
             1.3e+05  2.2e+04 6.9e+00 y  n

             1.7e+04  6.1e+03 1.7e+00 n  n
             1.9e+04  1.26+04 3.7e+00 y  n
                   22 29:35  6.1e+05  0.46 n    0.16
                            6.1e+05

                   23 29:39  7.8e+05  0.83 y    0.21
                            7.8e+05

                   24 31:46  2.7e+04  2.81 n    0.01
                            2.7e+04
             1.9e+05 5.7e+04  1.6e+01 y  n
             4.2e+05 8.8e+04  2.7e+01 y  n

             3.5e+05 6.9e+04  1.9e+01 y  n
             4.36+05 9.2e+04  2.8e+01 y  n

             2.0e+04 l.Se+04  4.0e+00 y  n
             7.0e+03 4.46+03  1.4e+00 n  n
                                                                                                        222

-------
































-.
file: A21JUL98F Acq: 22-JUL-1998 Ob: 23: 13 Exp
: M23_
DB225 Voltage SIR EI+ GC Autospec-UltimaE Paradigm
Sample #16 Text: 1072-8 xl/2 ALS #16
303.9016 S:16
100%
•
50J
o •


U-^zy 	 f- .— 7--J-
16:00
305.8987 S:16
100%

".
50J
-
rj -





16:00
315.9419 S:16
100S
50 1
0 '


"-1 — i — i — i — i — r
16:00
317.
100%
50;
0-
9389 S:16


J — r — i — i — i — r
16:00
375.8364 S:16
100%
50 j



16:05
ielob
316.9824 S:16
100% 15:44

-


' ielob
JO
CO
SMO ( 1 ,


A4
18
SMO ( 1 ,






18
SMO ( 1 ,



— i — i — r—
18
SMO ( 1 ,


18
SMO { 1 ,


17:
18
SMO(1,
17 -22


18


3)


BSUB(128,15,-3.0) PKD(3,


3,3,0.
Al
J
S3S4 "f E5«.ie« II 1
Jl^^^^Vl n /LJVA/^ f^r\A "**-'. ^V~
20:00 22:00
BSUB(128,15,-3.0) PKD(3,



-i — i — I — r— I — i — i — i — i — i — | — i — i
20:00 22:00
BSUB(128,15,-3.0) PKD(3,


20:00 22:00
BSUB(128,15,-3.0) PKD(3,
19:14
RJi
A
/ \ 21:28
*£—, — i — r^-i — i — i l^r^T~iMfyy~r~'
20:00 22:00
PKD(3,3,3,100.00%,0.0,1.
19:35 20:58 22^1121


20:00 22:00


241
3,3,0.
A5
. 12E5
" |
I

flv
24:
3,3,0.



'24S
3,3,0.


'24S
10%, 3624. 0,1. 00%, F,F)
. 89E5 A5.
| A1.08E5
IjutjUifLJ
00 26:00 2?
07E5 A3.53E5
A H
\ A6.30E4
1^^^A/L^_^J\ . ^^r^^-
r>

.3
0
ilob 30100 32:00 34:00
10%, 3220. 0,1. 00%, F,F)
.86E5 A6.
t
ft A4.36E5
A
1 1 1 1 A4 . 47E4
jU_^JL^.~--j'L_~-~A-j
67E5 A4.27E5
i 1
A 1

1 111 "•" • T^
\ A * / \ ^ A
-A^LL^VVlXJ^~v--~«v-»y1^v/ \^**^ „ 	 ,/\ir-T 	 "-
9


^4

:o
00 26:00 28:00 30:00 32:00 34:00
10%, 25636. 0,1. 00%, F,
Al.
J
/
F)
73E8
1

I
2
.9
0
00 26lob 28!ob 30:00 32:00 34:00
10%, 46840. 0,1. 00%, F,
A2.

j
F)
21E8

\
2
Ll
:0
00 26lob 28100 30!00 32:00 34:00
3, 3, 100. 00%, 8736. 0,1. 00%, F,F)


24:
'24!


02 26:23 27:


4128:38 30:41 32:03 33:50
f
Li
:o
00 26100 28:00 30:00 32:00 34:00
00%,F,F)
1:09 24:1825:15 26:2627:24 28:5529.:52. 3lLQ73^2:rQ5 .. 33:3.6 . .__,_4


'24l






.2
:0
00 26lob 28:00 3o!oO 32:00 34:00


1


. 7E4

.9E4
.OEO
Time

. 5E4


.7E4

.OEO
Time

. OE7
.9E6
.OEO
Time
.5E7
.3E7
.OEO
Time
nw;
. V/CiZJ
.OE5
.OEO
Time
.OE7
.OE7
.OEO
Time



-------
                  Section 4
               Svstem Perfor
-------
                   Peak Locate Examination:17-JUL-1998:16:42  File:Al7JUL98B
                  Experiment:EXP_M23_DB5_OVATION Function:! Reference:PFK317
PPM
200
 Volts
2.3390
292.95315  292.98245  293.01175
PPM
200
 Volts
1.1178
       304.95195  304.98245  305.01295
 Volts
0.7482
                                316.95075  316.98245  317.01415
                                                         Volts
                                                        2.6891
                                                                Volts
                                                               1.3903
                                                               354.94375  354.97925  355.01475
~
X

-------
                   Peak Locate Examination:18-JUL-1998:04:00 File:Al7JUL98B
                  Experiment:EXP_M23_DB5_OVATION Function:! Reference:PFK317
                                                         Volts
                                                        0.8423
 Volts
1.8374
292.95315  292.98245  293.01175
       304.95195  304.98245 305.01295
                         Volts
                        0.5709
316.95075  316.98245  317.01415
                         Volts
                         2.3195
330.94615  330.97925 331.01235
                         Volts
                        0.6985
366.94255  366.97925 367.01595
'                        '     ~
                                Volts
                               1.9680
       342.94495  342.97925 343.01355
                                Volts
                               1.6313
       380.93795  380.97604  381.01414
                         Volts
                        1.0102
354.94375  354.97925  355.01475

-------
                   Peak Locate Examination:20-JUL-1998:21:14 File:A20JUL98B
                  Experiment:EXP_M23_DB5_OVATION Function:! Reference:PFK317
292.95315  292.98245 293.01175
                                PPM
                                200
                                 Volts
                                1.2464
        304.95195  304.98245  305.01295
                                 Volts
                                0.8353
        316.95075  316.98245  317.01415
                         Volts
                        3.4259
330.94615  330.97925  331.01235
                                Volts
                                3.1531
        342.94495  342.97925  343.01355
                                 Volts
                                1.6484
        354.94375  354.97925  355.01475
PPM
200
 Volts
1.1537
    94255 366.97925  367.01595
 Volts
2.7169
       380.93795  380.97604 381.01414
to

-------
                   Peak Locate Examination:21-JUL-1998:10:02 File:A20JUL98B
                  Experiment:EXP_M23_DB5_OVATION Function:! Reference:PFK317
292.95315  292.98245  293.01175
                                PPM
                                200
                         Volts
                        0.5587
                                                    \
304.95195  304.98245  305.01295
316.95075  316.98245 317.0r415
                         Volts
                         1.4691
330.94615  330.97925 331.01235
                         Volts
                        1.3513
342.94495 342.97925  343.01355
PPM
200
 Volts
1.2970
354.94375  354.97925  355.01475
                         Volts
                        0.5196
                         Volts
                        1.2009
3'ffi. 94255  366.97925  367.015951 1380.93795 380.97604  381.01414

-------
                   Peak Locate Examination:21-JUL-1998:20:06 File:A21JUL98F
                       Experiment:M23_DB225  Function:1 Reference:PFK317
                         Volts
                        4.2302
292.95315  292.98245 293.01175
                                Volts
                                1.8577
       304.95195  304.98245  305.01295
                                 Volts
                                1.1518
        316.95075  316.98245  317.01'415
PPM
200
 Volts
5.6745
330.94615  330.97925  331.01235
 Volts
4.8040
       342.94495  342.97925  343.01355
PPM
200
 Volts
2.4566
        354.94375  354.97925  355.01475
                         Volts
                        1.5610
3E6194255  366.97925  367.01595
       PPM
       200
 Volts
4.6436
       380.93795  380.97604 381.01414

-------
                   Peak Locate Examination:22-JUL-1998:08:11 File:A2lJUL98S
                       Experiment:M23_DB225  Function:! Reference:PFK317
                         Volts
                        0.8568
292.95315  292.98245  293.01175
                         Volts
                        0.4258
304.95195 304.98245  305.01295
                         Volts
                        0.2889
316.95075  316.98245  317.01415
                         Volts
                        1.0522
                         Volts
                        0.9891
                         Volts
                        0.6053
330.94615  330.97925  331.01235
342.94495 342.97925  343.01355
354.94375  354.97925  355.01475
                         Volts
                        0.3802
                         Volts
                        0.9007
366^94255  366.97925  367.01595
380.93795 380.97604  381.01414

-------
                   Section 4
                System Perfor<
                   Section 4-2

Gas Chromatographv Performance Check
    Isomer Specificity & Retention Time Windows

          Documentation for the Analysis
                      of
 Polychlorinated Dibenzo-/*-Dioxins & Dibenzofurans

-------
File: A17JUL98B—Acq; 17-JUL-1998 16:45:bfeExp: EXP_M23_DB5_OVATION Voltage SIR EI+GC Autospec-UltimaEParadigm
Sample #1  Text: DB-5 Retchk  ALS #1
303.9016,319.8965                        ,_
100%                                  "  /""                          27j27                                 l_
 80
 60:
 40J
 20 J
                                                                                                          29:
     -l	1	1-1—1^1  l	1	1	r-
                 24:00
F:2 339.8597,355.8546
100%
 80 J
 60J   30:14
 40J
 20J
                                25:00
                                               26:00
                                                               27:00
                                                                              28 loo'
                                              29 100
                                                                                                             30:00   Time
     i i l i i 11 i l  i i i i i l  i i
     30ll2  30:24  30:36
F:3 373.8207,389.8156
100%       33;32
 80 J
 60J
 40J
 20J
                                 3l!66 ' 31-112 ' 31124 ' 31\36 ' 3l!48 ' 3~2!66 '  32!i2
                                        32:36   32:48  33:00  33:12    Time
                               f
                               L.
                                                                                    35:12
                     i  i i  I r i  i—ii1 l  i i—i  i i "I i  i i i  i |  i '
                       33148    34:00   34:12    34:24
                                                                                   '35\TL2  ' '35124    35136    35l48  Time
F:4 407.7818,423.7767
100%                36;22
 80 J
 60 J
 40 J
 20J
                                                        L.
                                                            37:32
     i i i  i i i i l i i i  i i i 'i l l  r-T^^^T I I  I
       36100  36:12  36:24  36:36
319.8965,331.9368
100%
 80 J
 60J
 40 J
 20 J
                                          37166 '37112 '37l24  37\3^' 37-48  38166 ' 38ll2 ' 38134 ' 38:36 ' 38!« '39.-00  Time
                                    25
                                       14
                                         28:39
                                                                                                            29:53
         i " • i   i   i  r" T  i  "r~
                 24100
                                25:00
26 loo'
                                                               27 loo'
                                                                              28 100
29:00
30:00  Time

-------
                                                              mrWJl' i*!o6_liiiLJlii!
CJ

-------
  File: A20JUL98B  Acq: 20-JUL-1998 21:16:15  Exp: EXP_M23_DB5_OVATION Voltage SIR EH-—6C Autospec-UltimaEl—Paradigm
  Sample #1  Text: DB-5 Retchk  ALS #1
  303.9016,319.8965                      •£
                                                                       27;24
   80 J
   60 J
   401
   20J
    OJ
           23:36
                 24:00
P:2 339.8597,355.8546
1001
 80 j
 60J  30:13
 40 j
 20J
  ol
                                  25:00
                                                2 6 loo'
28:00
                                                                                                29:00
                                                                                                             30:00   Time
                T
                                                                               L
                   '1 I  1 I I I I I I  I I l I I I I l  I I I I	• | 'I I I I I I	Ill IT*1 I I I I I  I I I I I I I I  I I I I I I I  I I I I I l' i  f i T |*l I I  I I I I I
      30:12  30:24   30:36  30:48  31:00   31:12  31:24  31:36  31:48  32:00  32:12  32:24  32:36  32i48   33:00   33:12
F:3 373.8207,389.8156
lOOi      33;31
 80J
 60J
 40J
 20 J
  0
                                                                                                                      Time
                                                                                     35:11
       33i24    33136    33:48    34iOO    34il2    34i24    34i36    34i48    35iOO    35:12    35i24    35:36    35~U8  Time
  F:4 407.7818,423.7767
  100%               36;2£    . T                    [^
   80
   60J
   40 j
   20 j
                                                          37:30
       l l l l i	| i r -i i l i i l I 'l I I 111 I I  I l l l l l I  l i I i i I i i  i T I I I 'l I  l I |Pl I I  I I I l l I l  I I l l i i | i  i i i l | l I
         36:00  36:12   36:24   36:36  36:48  37:00  37:12  37:24   37:36  37:48  38:00  38:12  38:24.  38:36  38:48   39:00  Time
  319.8965,331.9368
00%
so:
0'
!
25
J
24IOO 25100
13 28
1 Ml
26:00 27:00 28:00
38
A
I /i
29loO 30:1
-5.1E7
.2.5E7
O.OEO
DO Time
CJ

-------
Pile: A20JUL98BAcq: 20-JUL-1998 21:16:15Exp: EXP_M23_DB5_OVATION Voltage SIR EI+—GC Autospec-UltimaE
Sample #1  Text: DB-5 Retchk  ALS #1
319.8965
                                                                   28:38
                                                                                                               Paradigm
     27748"  27754 "28:60  ' 2s! 06  2s! 12' '  28 S 18  ' '28124
                                                                    28: 36 ' 28! 42 ' 28 ! 48 '  28154 ' 29:00 '  29S06
                                                                                                                     5.0E7

                                                                                                                    .4.8E7

                                                                                                                    .4.5E7

                                                                                                                    .4.3E7

                                                                                                                    .4.0E7

                                                                                                                    .3.8E7

                                                                                                                    .3.5E7

                                                                                                                    L3.3E7

                                                                                                                    _3.0E7

                                                                                                                    :2. 8E7

                                                                                                                    .2.5E7

                                                                                                                    .2.3E7

                                                                                                                    .2.OE7

                                                                                                                    ll.8E7

                                                                                                                    Ll.5E7

                                                                                                                    L1.3E7

                                                                                                                    Ll.OE7

                                                                                                                    :7.5E6

                                                                                                                    :5.0E6

                                                                                                                    .2.5E6
    .O.OEO
29:12   Time
ca

-------
Pile: A21JUL98E1—Acq: 21-JUL-1998  20:06:58   Exp:  M23_DB225 Voltage SIR EI+  GC Autospec-UltimaE  Paradigm
Sample #1  Text: DB-225 Retchk  ALS #1
303.9016
100%                               	              27;
 90-

 80 j

 70J

 60 j

 50 j

 40J

 30J

 20 j

 10J
  OJ
                                  27:32
                                                                                   28:36 ' '  ' isUs
                                                                             1.2E8

                                                                            .1.1E8

                                                                            .9.9E7

                                                                            .8.6E7

                                                                            _7.4E7

                                                                            .6.2E7

                                                                            L4.9E7

                                                                            _3.7E7

                                                                            .2.5E7

                                                                            .1.2E7
                                                                                                                   .O.OEO
      i  i I  i  i—r—i—i—I—i i  i T—i—;—i—
       27:00     27:12      27:24
27! 36
315.9419
100%,
 90j

 80 j

 70J

 60 j

 50 j

 40 j

 30J

 20J

 10J
                     2812
                                                                                             29:00  Time

                                                                                                  2 . 6E7

                                                                                                 _2 . 4E7

                                                                                                 _2 . 1E7

                                                                                                 _1.8E7

                                                                                                 L1.6E7

                                                                                                 L1.3E7
                                                                            _7.9E6

                                                                            _5.3E6

                                                                            _2 . 6E6
                                                                                                                   O.OEO
2'7!ob'  '
27J12'  ' '27!2.4
27548
                               ,    , • ,      • ,-   ,  , • ,  ,    ,
                               28\12 ' '  '28S24'  ' ' 28\36
                                                                                                              29OO   Time

-------
                              Section 4
                          System Perfor^ianc
                             Section 4-3
                      Initial Calibrations
                       (HP-5MS & DB-225 Columns)

                   Documentation for the Analysis
                                of
         Polychlorinated Dibenzo-/;-Dioxins & Dibenzofurans
JO
CO

-------
 (h

OPUSquan 20-JUL-1998












Page 1
(/ S
list
Page 1 of 1 ^f /
Run: 0716crv Analyte: m8290-23-» Cal: m8290-23-» Results: Version: V3 . 5 17-APR-1997 11:14:34
17jul98a S3 17jul98a S4 17jul98a S5 17jul98a S6 17jul98a S7
Name Mean RRF
2,3,7,8-TCDD
1,2,3,7,8-PeCDD
1,2,3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
1,2,3,4,6,7,8-HpCDD
OCDD
2,3,7,8-TCDF
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
1,2,3,4,6,7, 8 -HpCDF
1,2,3,4,7,8,9-HpCDF
OCDF
13C-2,3,7,8-TCDD
13C-l,2,3,7,8-PeCDD
13C-l,2,3,6,7,8-HxCDD
13C-l,2,3,4,6,7,8-HpCDD
13C-OCDD
13C-2,3,7,8-TCDF
13C-1 , 2,3,7, 8-PeCDF
13C-1, 2 ,3,6,7, 8-HxCDF
13C-1 , 2,3,4,6,7, 8-HpCDF
13C-1,2,3,4-TCDD
13C-1, 2, 3 , 7 , 8, 9-HxCDD
37Cl-2,3,7,8-TCDD
13C~2,3.4,7,8-PeCDF
13C-l,2,3,4,7,8-HxCDD
13C-l,2,3,4,7,8-HxCDF
13C-l,2,3,4,7,8,9-HpCDF
37Cl-2,3,7,8-TCDD
/ 13C-2,3,4,7,8-PeCDF
/ 13C-l,2,3,4,7,8-HxCDD
13C-l,2,3,4,7,8-HxCDF
"A 13C-l,2,3,4,7,8,9-HpCDF
Total Tetra-Furans
Total Tetra-Dioxins
Total Penta-Furans
0.9843
1.1157
0.6718
0.8518
0.8597
0.8965
1.0033
0.9531
0.8711
0.9020
0.8611
1.0877
0.9347
0.8123
1.2600
1.0402
1.0684
1.0970
0.7648
1.0729
0.7951
0.6399
1.3772
1.1987
1.2388
0.7529
_
-
1.0062
1.1724 •*
0.7230
0.9654
0.5892
0.9166
0.9777 »
0.6747
0.7855
0.7823
0.9531
0.9843
0.8866
S. D.
0.011
0.016
0.023
0.119
0.115
0.011
0.004
0.008
0.009
0.023
0.047
0.183
0.129
0.082
0.040
0.103
0.040
0.024
0.056
0.161
0.020
0.032
0.039
0.086
0.206
0.010
-
-
0,058
"0.095
0.114
0.104
0.084
0.035
0.025
0.056
0.054
0.109
0.008
0.011
0.012
%RSD RRF#1 SD
1.
1.
3.
13.
13.
1.
0.
0.
1.
2.
5.
16.
13.
10.
3.
9.
3.
2.
7.
14.
2.
5.
2.
7.
16.
1.


5.
8.
15.
10.
14.
3.
2.
8.
6.
13.
0.
1.
1.
14 %
46 %
35 %
96 % — -
32 % —
21 %
40 %
86 %
04 %
50 %
49 %
79 %-"
85 %/
14 % '
15 %
89 %
72 %
18 %
28 % y
99 %r
49 %
03 %
82 %
14 % /
62 % /
36 %
- %
- %
74 %
13 %
80 %
79 %
34 %
84 %
55 %
32 %
85 %
97 %
86 %
14 %
31 %
1.00 1.1
1.14 1.2
0.67 -0.1
0.96 0.9
0.95 0.8
0.89 -0.1
1.00 0.1
0.96 1.4
0.87 -0.3
0.88 -0.9
0.87 0.1
1.25 0.9
1.03 0.7
0.87 0.8
1.23 -0.9
0.93 -1.1
1.03 -0.8
1.07 -1.2
0.71 -1.0
0.95 -0.8
0.78 -0.6
0.63 -0.4
1.36 -0.5
1.13 -0.8
1.08 -0.8
0.76 0.6
-
- -
0.92 -1.5
1.13 -0.4
0.64 -0.7
0.90 -0.6
0.53 -0.8
0.86 -1.7
1.01 1.2
0.67 0.0
0.83 0.8
0.69 -0.8
0.96 1.4
1.00 1.1
0.87 -1.0
RRF#2
0.97
1.11
0.68
0.94
0.95
0.88
1.00
0.95
0.87
0.87
0.89
1.20
1.04
0.88
1.22
0.96
1.02
1.08
0.73
0.95
0.78
0.61
1.34
1.14
1.07
0.74
-
-
0.99
1.08
0.58
0.84
0.49
0.91
0.95
0.62
0.79
0.66
0.95
0.97
0.87
SD
-1.2
-0.2
0.3
0.7
0.8
-1.6
-1.0
-0.9
0.3
-1.2
0.6
0.6
0.8
0.8
-1.0
-0.7
-1.2
-0.6
-0.6
-0.8
-0.9
-0.9
-1.1
-0.6
-0.8
-1.0
-
-
-0.3
-0.9
-1.2
-1.2
-1.1
-0.2
-1.3
-1.1
0.0
-1.1
-0.9
-1.2
-1.0
RRF#3
0.97
1.13
0.70
0.91
0.93
0.90
1.00
0.95
0.88
0.91
0.92
1.20
1.02
0.86
1.25
1.01
1.08
1.09
0.74
0.98
0.78
0.61
1.36
1.14
1.11
0.75
-
-
1.01
1.10
0.73
0.95
0.58
0.93
0.96
0.75
0.85
0.77
0.95
0.97
0.90
SD
-0.9
0.6
1.4
0.5
0.6
0.2
-1.0
-0.5
1.1
0.3
1.2
0.6
0.7
0.6
-0.2
-0.3
0.2
-0.4
-0.5
-0.6
-0.6
-0.8
-0.6
-0.7
-0.6
-0.4
-
-
0.1
-0.8
0.1
-0.2
-0.1
0.4
-0.7
1.4
1.2
-0.1
-0.5
-0.9
0.7
RRF#4
0.99
1.11
0.64
0.71
0.72
0.90
1.01
0.96
0.87
0.93
0.83
0.90
0.80
0.73
1.28
1.12
1.10
1.12
0.81
1.27
0.82
0.68
1.42
1.26
1.45
0.77
-
-
1.06
1.26
0.80
1.06
0.67
0.94
1.00
0.63
0.73
0.87
0.96
0.99
0.90
SD
0.6
-0.2
-1.4
-1.2
-1.2
0.7
1.0
0.7
0.4
1.0
-0.8
-1.0
-1.0
-1.0
0.6
0.8
0.8
0.9
0.9
1.2
1.0
1.2
1.1
0.8
1.0
1.4
-
—
0.8
0.9
0.6
0.9
1.0
0.7
0.7
-0.8
-1.0
0.8
0.7
0.6
1.2
RRF#5
0.99
1.09
0.67
0.74
0.75
0.91
1.01
0.95
0.86
0.92
0.80
0.88
0.78
0.72
1.32
1.17
1.11
1.12
0.83
1.23
0.82
0.67
1.42
1.32
1.48
0.75
-
—
1.06
1.29
0.86
1.09
0,68
0.94
0.98
0.70
0.73
0.91
0.95
0.99
0.89
SD
0.3
-1.4
-0.2
-1.0
-1.0
0.9
0.9
-0.7
-1.5
0.8
-1.2
-1.2
-1.2
-1.1
1.4
1.3
1.1
1.2
1.3
1.0
1.2
1.0
1.1
1.4
1.2
-0.7
-
—
0.9
1.2
1.2
1.2
1.1
0.7
0.1
0.5
-1.0
1.2
-0.7
0.3
0.2
N

-------
        ll-FEB-1998
                                   Page 1
Run: 07FEB98
                Analyte: M23_CONF   Cal: 225-07feb  Results:
                                                                   Page 1 of 1

                                  Version:  V3.5 17-APR-1997 11:14:34
                     Name Mean RRF

             2,3,7.8-TCDF   0.9472
         13C-2,3,7,8-TCDF
                   HxCDPE
       QC CHK ION  (Tetra)
S.  D.

0.033
                                                       07feb98d S4 07feb98d S5 07feb98d S6 07feb98d S7 07feb98d S8
                                                %RSD    RRF#1   SD  RRF#2   SD  RRF#3   SD  RRF#4   SD  RRF#5   SD
        3.49 %
                   1.00  1.5   0.91 -1.3   0.94 -0.4   0.95  0.0   0.95  0.1

-------
                     Section 4
                 System Perfon
                    Section 4-4
          Documentation for the Analysis
                       of
Polychlorinated Dibenzo-/i-Dioxms & Dibenzofurans

-------
       OPUSquan    20-JUL-1998
Page 1
                                                                                                                   Page 1 of 2
          Run  #6    Filename  a!7ju!98b        S:  2    I:  1  Acquired: 17-JUL-98 17:31:00 Processed: 20-JUL-98 08:49:43
          Run:  al7ju!98b  Analyte:  m8290-23-» Cal: m8290-23-* Results: m8290-23-»   Quan  : V3.5 17-APR-1997 11:14:34
          Sample  text:  FE CS3                     Comments:  U^nn^l              OPUS  : A3.6/8X 18-MAR-1998 16:12:42
10
               Typ
                                         Name
                                                         Resp
                                                                   RA
                                                                              RT
                                                                                       Cone
                                                                                               Dev'n
                                                                                                                   Mod?
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
ES/RT
ES
ES
ES
ES
ES/RT
ES
ES
ES
JS
JS
CS
CS
cs
cs
cs

ss
ss
ss
ss
ss
DPE
DPE
2,3,7,8-TCDD
1,2,3,7,8-PeCDD
1,2,3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
1,2,3,4,6,7,8-HpCDD
OCDD
2,3,7,8-TCDF
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
1,2,3,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
OCDF
130-2,3,7,8-1000
130-1,2,3,7,8-PeCDD
130-1,2,3,6,7,8-HxCDD
130-1 , 2 , 3 , 4 , 6 , 7 , 8-HpCDD
13C-OCDD
13C-2,3,7,8-TCDF
13C-l,2,3,7,8-PeCDF
130-1,2,3,6,7,8-HxCDF
130-1,2,3.4,6,7,8-HpCDF
130-1,2,3,4-TCDD
13C-l,2,3,7,8,9-HxCDD
37C1 -2,3,7,8-TCDD
13C-2,3,4,7,8-PeCDF
130-1,2,3,4,7,8-HxCDD
130-1,2,3,4,7,8-HxCDF
130-1,2,3,4,7,8,9-HpCDF

3701-2,3, 7, 8-TCDD
13C-2,3,4,7,8-PeCDF
13C-1,2,3,4,7, 8-HxCDD
130-1,2, 3,4,7,8-HxCDF
130-1,2,3,4,7,8,9-HpCDF
HxCDPE
HpCDPE
2
8
5
7
7
5
1
2
1
1
8
1
9
8
7
6
1
4
3
3
2
3
6
4
3
2
4
3
2
1
5
7
4

2
1
5
7
4


.4e+07
.6e+07
.9e+07
.3e+07
.7e+07
.8e+07
.Oe+08
.9e+07
.le+08
.le+08
.2e+07
.2e+08
.6e+07
.le+07
.7e+07
.2e+07
.le+08
. 8e+08
.Oe+08
-3e+08
.6e+08
. 9e+08
.Oe+08
.8e+08
.8e+08
.5e+08
.5e+08
.4e+08
.2e+07
.le+08
.le+07
.2e+07
. 8e+07

.2e+07
.le+08
.le+07
. 2e+07
. 8e+07
*
*
0.
1.
1.
1.
1.
I.
0.
0.
1.
1.
1.
1.
1.
1.
1.
1.
0.
0.
1.
1.
1.
0.
0.
1.
0.
0.
0.
1.
1.
1.
0.
0.

1.
1.
0.
0.




77
54
26
24
23
06
90
77
52
52
38
14
23
24
01
02
90
77
54
26
04
89
78
57
52
44
79
26
57
24
52
45

57
24
52
45




y
y
y
y
y
y
y
y
y
y
y
y
y
y
y
y
y
y
y
y
y
y
y
y
y
y
y
y
y
y
y
y

y
y
y
y




28:27
32:37
34:42
34:46
34:59
37:11
40:02
27:26
31:57
32:24
34:11
34:15
34:37
35:08
36:22
37:32
40:10
28:26
32:36
34:45
37:10
40:01
27:25
31:56
34:14
36:21
28:09
34:58
28:27
32:24
34:42
34:10
37:31

28:27
32:24
34:42
34:10
37:31
NotFnd
NotFnd
5.00
25.5
26.0
25.6
26.6
25.0
51.2
5.07
25.8
24.8
24.7
27.6
26.8
26.1
24.6
24.1
51.5
98.2
88.9
92.7
96.3
182
97.6
89.1
92.0
98.1
92.6
84.9
4.91
21.8
20.8
22.0
24.3

5.01
24.5
22.5
23.7
24.8
*
*
0
2
4
2
6
-0
2
1
3
-0
-1
10
7
4
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-3
3
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-11
-7
-3
-9
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-1
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n
n
n
n
n
n
n

-------
File: A17JUL98B  Acq: 17-JUL-1998  17:31:00—Bxp: EXP_M23_DB5_OVATION Voltage
Sample #2  Text: FE CS3  ALS  #2
319.8965 S:2 SMOU.3) BSUB(128 ,15 ,-3 . 0)  PKD(3 , 3 , 3 , 0 .10%, 1564 . 0 , 1. 00%, F, F)
100*
     50J

      OJ
                                                                                 SIR EI+  GC Autospec-UltimaE  Paradigm
                                                                                        A1.03E7
                                                                                                                  2.0E6

                                                                                                                 Ll.OE6
         ~t	1	r-
                      T
                         i   i  i	1	r-
                                                 T
                                                                    T
                 24100          25100           26:00           27:00
321.8936 S:2 SMO(1,3) BSUB(128,15,-3.0)  PKD(3 , 3 , 3,0.10%,1824.0,1.00%,F,F)
100%
     50
                                                                                                                  .O.OEO
                                                                                  28:00
      o
                                                                                        A1.33E7
                                                                                               -j—i—i—P—i—i—r
                                                                                              29:00          30:00  Time
                                                                                                                  2.7E6

                                                                                                                 L1.3E6
                                          i	1  i
                                                     T
                                                                    T
                 24:00          25:00           26:00           27:00
331.9368 S:2 SMO(1,3) BSUB{128,15,-3.0)  PKD(3,3,3,0.10%,11164.0,1.00%,F.F)
100%
    50
                                                                                 ""	1	'
                                                                                  28:00
                                                                                           1	1	1	r
                                                                                              29:00
                                                                                                         i  i	1   i
                                                                                                                  O.OEO
     OJ
                                                                                        A2.10E8
                                                                                                              30:00  Time

                                                                                                                  4.1E7

                                                                                                                 _2.1E7
                                                                                                                  O.OEO
                 24:00          25:00           26:00           27:00
333.9339 S:2 SMO(1,3) BSUB(128,15,-3.0) PKD(3,3,3,0.10%,3908.0,1.00%,F,F)
100%
    50
                                                                                  28 oo
                                                                                              29 00
  OJ
                                                                                       A2.71E8
               i  i   i
                                                                    T
                    —i—i	1	1	1	1	1	1	1	1	1   i  i	1	1	1—
                 24:00          25:00          26:00           27:00
327.8847 S:2 SMO(1,3) BSUB(128,15,-3.0) PKD(3,3,3, 0.10%, 7592.0,1.00%,F,F)
100%.
    50:
                                                                                                              30:00   Time

                                                                                                                  5.3E7

                                                                                                                 .2.7E7
                                                                                  28.:00          29:00

                                                                                        A2.21E7
                                                                                                                     O.OEO
                                                                                                              30:00   Time

                                                                                                                  4.4E6

                                                                                                                 _2.2E6
                                     T
                                                 T"
                                                                 T
                                                                  27:00
      i   i  i	1  i   i   r  I   i	1—
                24:00          25iOO           26)00
316.9824 S:2 SMO(1,3) PKD(3,3,3,100.00%,0.0,1.00%,F,F)
100%_2iL30	24:17   24:4625:08    25:43 26:07      26:48   27:19
    50
  Oj
                                                                              28:00'

                                                                               28:02
                                                                                                                     O.OEO
                                                                                              29:00           30:00   Time

                                                                                          28:44  29:1029:32       7.8E7
         -i—i  i
                   T	1	1	r-
                    24:00
                             -i	1	1	r
                                25:00
                                               1	1	r
                                               26:00
                                                              T	1	1	1	1	r-
                                                               27:00
T	1	r
 28:00
29:00'
                                                                                                                 _3 . 9E7
                                                                                                                     O.OEO
loloo   Time
N
M

-------
File
Samp
355.
100%
50:
o:
357.
1004
50J
o;
367.
100%
so:
0'
369.
100%
so:
0
366.
10 OS
so:
0
: A17JUL98B Acq: 17-JUL-1998 1
le #2 Text: FE CS3 ALS #2
8546 S:2 F:2 SMO(1,3) BSUB(128,

30:12 30:24 30:36 30:48 31:
8517 S:2 F:2 SMO(1,3) BSUB(128,

30:12 30:24 36136 36148 3ll
8949 S:2 F:2 SMO(1,3) BSUB(128,

' 3bli2 ' 36124 ' 36136 ' SoUs 3ll
8919 S:2 F:2 SMO(1,3) BSUB(128,

[i i i 1 i i i i i 1 i i i i i i i i i i T— r r-i1 i T i 1
30:12 30:24 30136 30:48 31:
9792 S:2 F:2 SMO(1,3) PKD(3,3,3
30:14 30:47

30:12 30:24 30:36 30:48 31:
7:31:00 Exp: EXP_M23_DB5_OVATION Voltage SIR EI+ GC Autospec-UltimaE Parad
15, -3.0) PKD(3,3,3,0.10%,2136.0,1.00%,F,F)
A5.24E7
1^
00 31:12 31:24 31:36 31:48 32:00 32:12 32:24 32:36 32:48 33:00 33:12
15, -3.0) PKD(3,3,3,0.10%,692.0,1.00%,F,F)
A3.41E7
IV
66 3ill2 3ll24 3il36 isiUs 32166 32112 32124 32136 32:48 33166 33li2
15, -3.0) PKD (3, 3, 3, 0.10%, 4016. 0, 1 . 00%,F,F)
A1.84E8
ru
66 ' 3lli2 ' 31124 ' 31136 ' isiUs ' 32166 ' 32112 ' 321241 32136 32\48 33166 33li2
15, -3.0) PKD (3, 3, 3, 0.10%, 2840. 0,1. 00%, F,F)
A1.20E8
IL
00 3lll2 3ll24 31:36 3ll48 32100 32:12 32:24 32:36 32:48 33:00 33:12
, 100. 00%, 0.0,1. 00%, F,F)
31:05 31:22 31:39 31:57 32:11 32:36 32:59

66 ' 31:12 ' 3ll24 3ll36 31 1 48 ' 32 166 32112 32124 32:36 32148 33:66 33li2
igm
r!.8E7
1 O.OEO
Time
1.1E7
-5.7E6
0 . OEO
Time
6.5E7
_3.3E7
O.OEO
Time
4.3E7
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O.OEO
Time
8.7E7
.4.3E7
O.OEO
Time
to

-------
Pile
Samp
389.
100%
so:
o:
391.
100%
so:
OJ
401.
100%
50J
OJ
403.
1004
so:
0_
380.
100%
so:
0'
: A17JUL98B Acq:' 17-JUL-1998 17:31:00 Exp: EXP_M23_DB5_OVATION Voltage SIR El -t- GC Autospec-ttltimaE Parad
le #2 Text: FE CS3 ALS #2
8156 S:2 F:3 SMO(1,3) BSUB(128, 15, -3 .0) PKD(3, 5, 2, 0 . 10%, 1860 . 0, 1 .00%,F,F)
A4-95E7 A4.24E7
r, A A

33:24 33:36 33
8127 S:2 F:3 SMO(1,3)

33:24 33:36 33
8559 S:2 F:3 BSUB(128

' i i 1 i i i i i 1 	
33:24 33:36 33
8530 S:2 F:3 BSUB(128

33:24 33:36 33
9760 S:2 F:3 SMO{1,3)
33:42
/

1 i i — r— i — i — i — i — i — i — i — < — i — i — i —
33:24 33:36 33
/
•48 34:00 34:12 34:24 34:36
BSUB(128,15,-3.0) PKD(3 , 5, 2 , 0 . 10%, 2388 . 0
A3
t\
1}
•48 34:00 34:12 34:24 34:36
,15, -3.0) PKD(3,5,2,0.10%,11648.0,1.00%,F
Al.

1 1 1 1 1 1 1 1 1 1 1 -T— ]""l T-l-l !"| 1 1 I'l 1 | 1 'i I1 1
•48 34:00 34:12 34:24 34:36
,15, -3.0) PKD( 3, 5, 2, 0.10%, 10004. 0,1. 00%, F
Al.

IU\.
34.U8 35!oO 35!l2 3sl24 3S.-36 35-
,1.00%,F,F)
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34U'8 35100 35ll2 35:24 35b6 35:
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34U'8 35IOO 35ll2 35124 35i36 35.
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|8E8 A1.49E8
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1.2E7
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O.OEO
48 Time
9.8E6
L4.9E6
.O.OEO
48 Time
6 . 8E7
_3.4E7
O.OEO
48 Time
5.5E7
12.7E7
.O.OEO
UV ' '34:0'o' ' '34:12 '34:24 34:36 34148 35^00 35!l2 35s24 35:36 35 48 Time
PKD(3,3,3,100.00%,0.0,1.00%,F,F)
33:56 34:08 34:18 34:31 34:43 34:53 35:14 35:43 l.flES


•48 34:00 34:12 34:24 34:36



.9.1E7
_O.OEO
34.U8 35IOO 35J12 3s!24 35:36 35 48 Time

-------
Pile: A17JUL986 AdqT 1V-JUL-1998 17:31:00
Sample #2 Text: FE CS3 ALS #2
423.7767 S:2 F:4 SMO(1,3) BSUB (128, 15, -3 . 0)
100%
so:
I i i i | i I I i I i i i i i I i i i i i f~~pl I i i i i i i r i i
36:00 36!l2 3e!24 36:36 36i48 37
425.7737 S:2 F:4 SMO(1,3) BSUB (128 , 15, -3 . 0)
10 OS
so:
o- —
3e!66 36!i2 se!^' seiie seUs' 37
435.8169 S:2 F:4 SMO(1,3) BSUB(128, 15, -3 . 0)
100%
so:
o •
36! 66 36! 12 36! 24 36:36 36! 48 37
437.8140 S:2 F:4 SMO(1,3) BSUB(128, 15, -3 . 0)
100%
so:
o:
36:66 36!i2 36J24 36!36 36U8 37
430.9728 S:2 F:4 SMO(1,3) PKD(3 , 3 , 3, 100 .00%
100% 35i59 36:10 36:22 36:33 36:47
50_
36j6d 35-12 36S24 ' 36i36 36:48 37
Exp: EXP_M23_DB5_OVATION Voltage SIR EI + GC Autospec-UltimaE Paradigm
PKD (3, 3, 3, 0.10%, 1392. 0,1. 00%, F,F)
A2.96E7 7.1E6
j[_
:00 37:12 37:24 37:36 37:48 38:00 38:12 38:24 38:36 38!48 39
PKD (3, 3, 3, 0.10%, 3 648. 0,1. 00%, F,F)
A2 . 81E7
/v
:00 37:12 37:24 37:36 37:48 38:66 38!l2 38!24 38!36 38:48 39!
PKD(3,3,3,0.10%,2028.0,1.00%,F,F)
A1.31E8
;V
• OO -^*7"1'5 "%*7 • 1 A "^ *7 • *5 C *5*7"^Q ^Q»fift TQ»1O *5Q»O^ Q Q * ^ C ^ O • /I O *)Q«
i U U -j 1 • j-^t j / Z £** J / I J O -5 / • ^ O -3 O I U L* JO*J-4 
-------
Pile
Samp
457.
100%
50J
0.1
459.
100%
so:
o:
469.
100%
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o:
471.
100%
so:
o:
454.
100%
so:
0'
: A17JUL98B Acq: 17-JUL-1998 17:31:00
le #2 Text: FE CS3 ALS #2
7377 S:2 F:5 SMO(1,3) BSUB(128, 15 , -3 . 0)

39!l2 39524 39536
7348 S:2 F:5 SMO(1,3) BSUB(128, 15, -3 . 0 )

39-!l2 39524 39536
7780 S:2 F:5 SMO(1,3) BSUB(128, 15, -3 .0)

39!l2 39524 39:36
7750 S:2 F:5 SMO(1,3) BSUB(128, 15, -3 . 0)

39ll2 39124 39536
9728 S:2 F:5 SMO(1,3) PKD(3,3, 3, 100.00%
39:11 39:2939:35

39:12 39:24 39:36
Exp: EXP_M23_DB5_OVATION Voltage SIR EI+ GC Autospec-UltimaE Paradigm
PKD(3,3,3,0.10%,2336.0,1.00%,F,F)
A4.77E7 9.9E6
J\__
39:48 40:00 40:12 40:24 40:36 40:48 41:
PKD(3,3,3,0.10%,332.0,1.00%,F,F)
A5.30E7
J\_
39:48 40:00 40:12 40:24 40:36 40:48 41:
PKD(3,3,3,0.10%,3976.0,1.00%,F,F)
A1.84E8
y\_
39:48 40:00 40:12 40:24 40:36 40:48 41:
PKD(3,3,3,0.10%,1228.0,1.00%,F,F)
A2 . Q8E8
J\_
_4.9E6
' O.OEO
00 Time
1.1E7
_5.6E6
O.OEO
00 Time
3 . 9E7
L1.9E7
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00 Time
4.3E7
.2.2E7
_O.OEO
39148 40.'ob 40.-12 4ol24 40l36^ 40:48 41-00 Time
,0.0,1.00%,F,F)
39:49 40:01 40:08 40:24 40:34 40:54 1.4Efi

39:48 40:00 40:12 40:24 40:36 40:48 41
16.8E7
' O.OEO
00 Time

-------
File: A17JUL98B Acq: 17-JUL-1998 17:31:00 Exp : EXP_M23_DB5_OVATION Voltage SIR EI + GC Autospec-UltimaE Paradigm
Sample #2 Text: FE CS3 ALS #2
303.9016 S:2 SMO(1,3) BSUB (128, 15, -3 . 0) PKD(3 , 3 , 3 , 0 . 10%, 1660 . 0 ,
100%
50J
0:
24100 25100 26loO
305.8987 S:2 SMO(1,3) BSUB(128, 15, -3 . 0) PKD(3 , 3 , 3 , 0 . 10%, 3140 . 0 ,
100%
50J
o: _,
24:00 25:00 2eloO
315.9419 S:2 SMO(1,3) BSUB(128, 15, -3 . 0) PKD(3 , 3 , 3 , 0 . 10%, 4980 . 0,
100%
50J
o:
	 24 SOO 	 25 100 ' 26 100
317.9389 S:2 SMO(1,3) BSUB(128, 15, -3 . 0) PKD(3 , 3 , 3 , 0 . 10%, 5448 . 0,
100%
50 j
o:
24100 25100 26100
375.8364 S:2 SMO(1,3) BSUB(128, 15, -3 . 0) PKD(3 , 3 , 3 , 100 . 00%, 76 . 0 ,

1.00%,F,F)
A1.26E7
A
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_2.5E6
_1.2E6
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27 loo 	 28 loo' ' ' ' 29 loo' ' ' ' ^3oloO Time
1.00%,F,F)
A1.64E7
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3.3E6
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_O.OEO
27100 28100 29100 3oloO Time
1.00%,F,F)
A2.64E8
A
A
/ V
5.3E7
L2.6E7
.O.OEO
27100 28100 29100 3oloO Time
1.00%,F,F)
A3.37E8
A
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6.7E7
.3.4E7
.O.OEO
27100 28100 29100 30:00 Time
1.00%,F,F)
100% 26:50 ,_8.7E3
;
50- 23:36 24:12 „ , 25-55
' A fl A h 24:51 /A
24:00 25:00 26:00
316.9824 S:2 SMO(1,3) PKD(3, 3 , 3 , 100 . 00%, 0 . 0, 1 . 00%, F, F)
100% 23j30 24:17 24:4625:08 25i43 26j_Q7 26j
50 J
0:
24:00 25:00 26:00
28:26
/\ o 29:34
J U2_8A47^ ^A Ar p^_

^4.4E3
27loO 28100 29:00 30:00 Time

48 27:19 28:02 28:44 29:1029:32 7 . 8E7


L3.9E7
LO.OEO
27 loo 28 loo ' 29 loo' ' ' 30:00 Time
_ T

-------
Pile: A17JUL98B
Sample #2 Text:
339.8597 S:2 F:2
100S
50J
ol



3o[l2T 36124
341.8568 S:2 F:2
100%
sol
o-



30:12 30:24
351.9000 S:2 F:2
100%
50J
•
o:




u Li i i 1 i i i i i 1 i i
30:12 30:24
353.8970 S:2 F:2
100%
50.

Q-




"-V-i-r-pr-r-n -r j-i r
30ll2 30:24
409.7974 S:2 F:2
100%
50J
o"
Acq: 17-JUL-1998 17:31:00
FE CS3
SMO (1,3)



36136
SMO (1,3)



i i i 1 i i i
30:36
SMO (1,3)




-r 1-i-j-i-r r
30136
SMO (1,3)




1 1 1 1 1 1 T
30:36
SMO (1,3)

ALS #2
BSUB(128,15,-3.0)



36:48 31:66 3lll2
BSUB(128,15,-3.0)



i i i i i i T-T r i -i i i i | i
30148 31:00 31:12
BSUB(128,15,-3.0)




i i i i i i i i T i- i r i i | I
30!48 3llOQ 31:12
BSUB(128,15,-3.0)




30l48 31:00 31:12
BSUB(128,15,-3.0)

30-18 3°A3° 30:46 31A°3
r^s 8 .. A 30 09A A_/\ A
jrr\j \T^
30:12 30:24
366.9792 S:2 F:2
100% 30:14
50J
0'


30:12 30:24
^/
' 30:36 '
SMO (1,3)



30.:36
^~x~^ V^J \j
30:48 31:00 31:12
Exp: EXP_M23_DB5_OVATION Voltage SIR EI+ GC Autospec-UltimaE Paradigm

PKD(3,3,3,0.10%,1524.0
A6

]
31124 3il36 3il48
PKD(3,3,3,0.10%,2624.0
A4


31:24 31:36 31:48
PKD (3, 3, 3, 0.10%, 60. 0,1
A2.
1
1

1 1 1 1 ! 1 1 1 1 | 1 1 1 1 1 | 1 1 1
3ll24 31:36 31:48
PKD(3,3,3,0.10%,1568.0
Al.
1
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31:24 31:36 31:48
PKD(3,3,3,100.00%,3856

31:21 31:37
/A A AA J -L
1 ^ ^^ \j s^y \^ — ^
3il24 31:36 SlUs

,1.00%,F,F)
.48E7 A6.44E7
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32l6o 32:12 32124 32136 32:48 33166 33112 Time
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32:00 32:12 32:24 32:36 32:48 33:00 33:12 Time
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9 . 6E7
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32:00 32:12 32124 32l36 32 Us 33166 33112 Time
,1.00%,F,F)
86E8
A
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6.2E7
13.1E7
•
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32l6o 32:12 32124 32136 32l48'33l6o 33ll2 Time
.0,1.00%,F,F)
32:36 ,_1.1E4
A
32*18 / \ -an c.c
:56 32:08 A p/ \J\ A A -A.
^\J\^J ^X/V \S*^ \J \jJ \A~
.5.7E3
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32166 32! 12 32 .-24 32 .-36 32:48 33:66 33:12 Time
PKD(3,3,3,100.00%,0.0,1.00%,F,F)
30:55 31:05


30:48 31:00 31:12
31:22 31:39 3:


31124 ' 3ll36 3il48
.:57 32:11 32:36 32-S9 ft.7R7


_4.3E7
.O.OEO
32:00 32:12 32:24 32:36 32:48 33:00 33:12 Time
I

-------
   File: A17JUL98BAcg:  17-JUL-1998 17:31:00Exp: EXP_M23_DB5_OVATION Voltage SIR EI+—GC Autospec-UltimaE—Paradigm
   Sample  #2  Text:  FE CS3  ALS #2
   373.8207 S:2 F:3  SMO(1,3)  BSUB(128,15,-3.0)  PKD(3,5,2,0.10%,4032.0,1.00%,F,F)
   100%,                                      A6.13E7
                                                             A5.31E7
     0
           T
                   T
                         T
                                                                                    A4 . 52E7
                                  T
                                           T
                                                               ~T
T
                                                                                                                   1.8E7

                                                                                                                   L9.2E6
                                                                                 T
         33:24    33i36    33i48    34iOO    34il2    34i24   34^36    34J48    35iOO
   375.8178 S:2 F:3  SMO(1,3)  BSUB(128,15,-3.0)  PKD(3,5,2,0.10%,1852.0,1.00%,F,F)
   100%,                                      A5.40E7
                                                             A4.30E7
                                                                                    '  ' I  ' '
                                                                                     35:12
                                                                                                                      O.OEO
                                                                                    A3.63E7
Fill—I I  I—i—1—i—i—|—i—i—r
 35:24    35:36    35:48  Time
                                                                                                                  _1.5E7

                                                                                                                  L.7.5E6
                   T~i—'—'—'—'—|—'—'—'—'—'—i—'—'—r~^—'—(~i—'—r- r i i1 i  i i  i ft—i—i 1  r i  i i  i i—i—i—i—i—rS—i—i—i ~i i  i i  i i—i—i—i—i—i—i—i—i—i—i—i—J-O.OEO
         33:24    33:36   33:48    34:00    34:12    34:24   34!36    34:48    35:00    3s!l2    3S-.24   35:36    35:48  Time
   383.8639 S:2 F:3 BSUB(128,15,-3.0)  PKD(3,5,2,0.10%,36440.0,1.00%,F,F)
   100%,                                     A1.32E8
 50_

  OJ
                                                                                                                     ^4.9E7

                                                                                                                     .2.5E7
                                                                                   A2 . 51E7
                                                                                                                      O.OEO
        —'—[""I—i—i—I—i  | I  i i—I i  I—i—i—i—i—i—I—I—i—r—f—r-*i—r—i—i i  I I I  I I  i I  i I  i i  i—r—i—i—i—i—i—i—i—i—r"T—i  I I  I I  I I  i—i—i—i—i—i i  i—p-1—r—i—r
        33:24    33:36    33:48    34:00    34:12    34:24    34:36    34:48    35:00    35:12    35:24   35:36    35l48  Time
   385.8610 S:2 F:3 BSUB(128,15,-3.0)  PKD(3,5,2,0.10%,79816.0 ,1.00%,F,F)
   100%,                                     A2.52E8                                                                   9. 6E7
 50J

  OJ
                                                                                   A4 . 80E7
                                             .4.8E7

                                              O.OEO
        i—I—I—i—i—i  i i  I i  i—i—i—I—r~i—i i  i—i—I—i—i—r—•?—r-*i—i—i—i  i I  I I  i i  i—i—i i  i—i—i—i—i—i—i—i—i—i—i—i—i—T—i  i I  I i  I i i—i—i—i—i—i i  i i—r—i—i i  i
         33:24    33:36    33:48    34:00    34:12    34:24    34:36    34:48    35:00    35:12    35:24   35:36    35:48  Time
   445.7555 S:2 F:3 SMO(1,3) BSUB(128,15,-3.0)  PKD(3,3,3,100.00%,1548.0,1.00%,F,F)
   100%.                                                             34:45     34:58
                                                                                                                   1.0E4

                                                                                                                  L5.2E3

                                                                                                                  LO.OEO
                 T—I—I—I—I—I—I—I—I—I—I—I—I—I—I—I—I—I—I—I—I—i—i—l—I—I—i—i—I—l—I—i—i—I—I—I—I—P—I—I—I—I—I—I—l—I—l—i—I—i—I—I—i—i—T-^T—i—i—i—i—i—i—i—j—i—i—r
      33:24    33:36    33:48    34:00    34:12   34:24    34:36    34:48    35:00    35!l2    35:24    35136    35!48  Time
380.9760 S:2 F:3 SMO(1,3)  PKD(3,3,3,100.00%,0.0,1.00%, F,F)
100%,              33:42	33^56    34:08	34:23  34:31   34:43   34:53
    50
     O
                                                                                         35:14
                                                                                                               35:43  , l.RES
        i—i—|—r—l—i—l—i—|—i—r-T—i—l—f—i—I—l—i—i—|—i—l—r—T—i—|—i—r
        33:24    33:36    33:48    34:00    34:12
                                                                                                                     _9.1E7
                                                                     	 O.OEO
                                                                   34:48    35:00    35:12     35:24    35!36    35:48  Time
10
CD

-------
    : A17JUL98B—Acq: 17-JUL-1998  17:31:00Exp: EXP_M23_DB5_OVATI6N Voltage SIR"EI+GC Autospec-UltimaEParadigm
Sample #2  Text: FE CS3  ALS #2
407.7818 S:2 F:4 SMO(1,3) BSUB(128,15,-3.0) PKD(3,3,3,0.10%,9768.0,1.00%,F,F)
100$               A3.£8E7                                                                                        _1.1E7
                                                          A3.14E7
                                                                                                                 L5.5E6
  o
                                              LO.OEO
       36:00 ' 36:12 ' 36:24 ' 36536 ' 36148 ' 37:00  37:12  37:24  37:36  37:48   38:00  38:12 ' 38124 ' 38!36 ' 38:48 ' 39lOO  Time
409.7788 S:2 F:4 SMO(1,3) BSUB(128,15,-3 .0) PKD(3,3,3,0.10%,7452 . 0,1. 00%, F, F)
100%               A3.83E7
 50^

  OJ
                                                          A3.08E7
       36:00  36:12  36:24  36:36  36:48   37:00  37:12  37:24  37:36  37:48   38:00  38:12  38:24  38:36
417.8253 S:2 F:4 SMO(1,3) BSUB(128,15,-3.0) PKD(3,3,3,0.10%,14644.0,1.00%,F,F)
100%              A7.60E7
                                               1. 1E7

                                              L5.4E6

                                              LO.OEO
  O
                                                          Al.50E7
                                           39:00  Time

                                               2. 1E7

                                              Ll.OE7

                                             JLO.OEO
     I i i i [  i i i i i I  i i 1 i i I i  i f I I I i l  l l I I l i i l  i l i l l l l I  l i 'I I I I I 'T l I PI' I I  I I I | I I l I  l I I I I I I  1 l I I l I I  l l l l l [ i  l l l I I l  l l i l [
       36:00  36:12  36:24  36:36   36:48  37:00  37:12  37:24  37:36   37:48  38:00  38:12  38:24  38:36  38:48  39:00  Time
419.8220 S:2 F:4 SMO(1,3) BSUB(128,15,-3.0) PKD(3,3,3,0.10%,10404 . 0,1. 00%, F, F)
100%              A1.73E8
 50J
                                                          A3.32E7
                                               4.7E7

                                              _2.4E7

                                               O.OEO
     i i i i i  i i i i i i i  i 1 i i l i i  i i i I i i  i i i I i i i i  i I	i  i i i i i i       ,,,,,,,.
       36IOO  36:12  36:24   36:36   36:48  37:00  37:12  37:24  37:36  37:48  38:00  38:12  38:24  38:36  38:48  39:00  Time
479.7165 S:2 F:4 SMO(1,3)  BSUB(128,15,-3.0) PKD(3 , 3 , 3 ,100.00%,2976.0,1.00%,F, F)
100%                                           37jlO
      35:58
 50 J
       I I I  I I I I I I I  I I I I I I I  I I I I I I  I I I I I I I I  I I I I I I I I  I I I I < I I T  I I I I I I  I I I I I I I I  I I
       36:00  36:12  36:24   36:36   36:48  37:00  37:12  37:24   37:36   37:48  38:00  38:12  38:24  38:36  38:48  39:00 Time
430.9728 S:2 F:4 SMO(1,3) PKD(3,3,3,100.00%,0.0,1.00%,F,F)
100%   35:5936:10   36^22  36i33   36:47	37:11 37^21
 50J
  OJ
37:45
38;10
38; 45
.1.2E8
                                                                                                                 L6.1E7
                                                                                                                 .O.OEO
       i i l  i i i i i i i  i i i i l i i  i i t i [ i i  i i i i i i i i  i i i i i i i i  i i i i i 	 | i i i  i i i i i i i i  [ i i i i i |  i i i i i | i  i i i i | i 'i i i i | i i  i i
       36:00  36:12  36:24   36:36   36:48  37:00  37:12  37:24  37:36   37:48  38:00  38:12  38:24  38:36  38:48   39:00  Time

-------































-s
^


File: A17JUL98B Acq: 17-JUL-1998 17:31:00
Sample #2 Text: FE CS3 ALS #2
441.7427 S:2 F:5 SMO(1,3) BSUB(128, 15, -3 . 0)
1002
50_
ol



39!l2 ' ' ' 39124 ' ' ' 39136
443.7398 S:2 F:5 SMO(1,3) BSUB(128, 15, -3 . 0)
100%
50 j
o-



39ll2 39124 39136
469.7780 S:2 F:5 SMOfl.3) BSUB(128 . 15 . -3 . 0)
100%
50J
0:



39!l2 39:24 39.;36
471.7750 S:2 F:5 SMO(1,3) BSUB(128, 15, -3 .0)
100%
50 j
oj



39ll2 39:24 39:36
513.6775 S:2 F:5 SMO(1,3) BSUB(128, 15, -3 .0)
100%
50 j

_


39:10 ,A 39 = 31 39A40
/— s. S*~ '\^/-*^ / \ > 	 S. / \ y 	 s. / \ v-

39!l2 39124 39136
454.9728 S:2 F:5 SMO(1,3) PKD(3, 3, 3 , 100 .00%
100% 39:11 39^2939:35 39:
50J
-
o-
7



39:12 39:24 39:36
(0
en
Exp: EXP_M23_DB5_OVATION Voltage SIR EI+ GC Autospec-UltimaE Paradigm

PKD(3,3,3,0.10%,772.0,1.00%,F,F)
A5 . 10E7
l\
J ^^_
1.1E7
L5.3E6
• O.OEO
39.-48 40:00 40:12 40:24 40:36 40:48 41 00 Time
PKD(3,3,3,0.10%,1372.0,1.00%,F,F)
A5 . 69E7
/\
J ^-_^
1.2E7
L6.0E6
LO.OEO
39l48 4o!ob 40:12 40:24 40:36 40:48 41:00 Time
PKD(3,3,3,0.10%,3976.0,1.00%,F,F)
A1.84E8
/\
J ^ 	
3.9E7
L1.9E7
LO.OEO
39:48 40.-00 4o!l2 40:24 4ol36 4oU8 41.-00 Time
PKD(3,3,3,0.10%,1228.0,1.00%,F,F)
A2.Q8E8
/\
J ^- — ^
4.3E7
L2.2E7
.O.OEO
39:48 4olob 4o!l2 40:24 4o!36 40S48 41:00 Time
PKD(3,3,3,100.00%,1228.0,1.00%,F,F)
40:02
r\
39^52 / \_^ 	 ^^ 40:27 40:39 40:53

8.2E3
14 . 1E3

_O.OEO
39!48 4o!ob 4o!l2 4ol24 4o!36 4o!48 4l!oO Time
,0.0,1.00%,F,F)
44 40:01 40:08 40:24 40:34 40:54 1.4E8



_6 . 8E7

O.OEO

39:48 40:00 40:12 40:24 40:36 40-48 41:00 Time



-------
OPUSguan 20-JUL-1998 Page
1





Run #7 Filename al7ju!98b S: 15 I: 1 Acquired: 18-JUL-98 03:17.
Run: 0716crv Analvte: m8290-23-» Cal: m8290-23-» Results:
Sample text
Typ
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
ES/RT
ES
ES
ES
ES
ES/RT
ES
ES
ES
JS
JS
CS
CS
CS
CS
CS

ss
ss
ss
ss
ss
DPE
DPE
.- BE CS3
Name
2,3,7, 8-TCDD
1,2,3,7, 8-PeCDD
1.2,3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
1,2,3,4,6,7,8-HpCDD
OCDD
2,3,7,8-TCDF
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
1,2,3,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
OCDF
13C~2,3,7,8-TCDD
13C-1 , 2,3,7, 8-PeCDD
13C-l,2,3,6,7,8-HxCDD
13C-l,2,3,4,6,7,8-HpCDD
13C-OCDD
13C-2,3,7,8-TCDF
13C-1 , 2,3,7, 8-PeCDF
13C-l,2,3,6,7,8-HxCDF
13C-l,2,3,4,6,7,8-HpCDF
13C-1,2,3,4-TCDD
13C-l,2,3,7,8,9-HxCDD
37Cl-2,3,7,8-TCDD
13C-2,3,4,7,8-PeCDF
13C-l,2,3,4,7,8-HxCDD
13C-1 ,2,3,4,7, 8-HxCDF
13C-l,2,3,4,7,8,9-HpCDF

37Cl-2,3,7,8-TCDD
13C-2,3,4,7,8-PeCDF
13C-l,2,3,4,7,8-HxCDD
13C-l,2,3,4,7,8-HxCDF
13C-l,2,3,4,7,8,9-HpCDF
HxCDPE
HpCDPE
Comments: £}£~~ll
Resp
3
1
7
1
1
8
1
4
1
1
1
1
1
1
1
9
1
6
4
4
3
5
8
6
5
3
6
4
3
1
8
1
7

3
1
8
1
7


.2e+07
.2e+08
.8e+07
.le+08
.le+08
.4e+07
.5e+08
.Oe+07
.5e+08
.5e+08
.2e+08
.5e+08
.3e+08
.2e+08
.le+08
.5e+07
.6e+08
.5e+08
. 4e+08
.6e+08
.8e+08
.8e+08
.3e+08
.8e+08
.2e+08
.6e+08
.2e+08
.7e+08
.le+07
.6e+08
.3e+07
.le+08
.4e+07

.le+07
.6e+08
.3e+07
.le+08
.4e+07
t
*
0
1
1
1
1
1
0
0
1
1
1
1
1
1
1
1
0
0
1
1
1
0
0
1
0
0
0
1
1
1
0
0

1
1
0
0




1^
RA
.78
.55
.22
.27
.25
.01
.88
.78
.53
.53
.21
.23
.21
.22
.02
.03
.89
.78
.56
.26
.04
.89
.79
.56
.52
.45
.79
.26
.56
.23
.52
.45

.56
.23
.52
.45




\s^ ^T
y
y
y
y
y
y
y
y
y
y
y
y
y
y
y
y
y
y
y
y
y
y
y
y
y
y
y
y
y
y
y
y

y
y
y
y




28:27
32:37
34:42
34:46
34:59
37:10
40:02
27:26
31:57
32:24
34:11
34:15
34:37
35:08
36:22
37:31
40:10
28:26
32:36
34:45
37:09
40:01
27:25
31:56
34:14
36:21
28:09
34:58
28:27
32:24
34:41
34:10
37:31

28:27
32:24
34:41
34:10
37:31
NotFnd
NotFnd



11 Processed: 20-JUL-98
Quan : V3.5 17-APR-1997
OPUS : A3
Cone
5.04
24.6
25.0
28.2
26.6
24.9
50.3
5.03
26.0
25.1
25.7
27.2
25.8
27.4
25.1
25.3
51.7
96.9
94.4
92.1
101
194
97.9
91.6
89.1
102
128
119
5.01
22.5
24.3
24.3
26.5

5.18
24.6
26.3
27.0
25.9
*
*
.6/8X
Dev
0
-1
0
12
6
-0
0
0
4
0
2
8
3
9
0
1
3
-3
-5
-7
0
-2
-2
-8
-10
2


0
-10
-2
-3
6

3
-1
5
8
3



Page 2 of 2
08:49:48
11:14:34
18-MAR71998 16:12:42
'n Mod?
.7
.6
.1
.8
.4
.3
.6
.6
.0
.5
.9
.7
.2
.7
.4
.2
.5
.1
.6
.9
.7
.9
.1
.4
.9
.5
-
~
.3
.1
.9
.0
.2

.5
.8
.3
.0
.6
_

n A/
n / (JL^^J
n' /r s
n /
n /
n
n
n
n
n
n
n
n
n
n
n
n
n
n
n
n
n
n
n
n
n
n
n
n
n'
n
n
n

n
n
n
n
n
n
n

-------
JO
CA
CO
File: A17JUL98B Acq: 18-JUL-1998 03:17:11 Exp: EXP_M23_DB5 OVATION Voltage SIR EH- GC Autospec-UltimaE Paradigm
Sample #15 Text: BE CS3 ALS #2
319.8965 S.-15 SMO(1,3) BSUB(128, 15, -3 . 0) PKD(3 , 3 , 3 , 0 . 10%, 1568 . 0, 1 . 00%, F, F)
100% A1.42E7 2.9E6
: A
50 j
o:
321.
1002
50J
o:
331.
100%
50^
o:
333.
100%
50J
o:
327.
100%
50J
o:
316.
100%
50J
o:

24100
8936 S:15 SMO(1,3)

24:00
9368 S:15 SMO(1,3)

	 24 loo'
9339 S:15 SMO(1,3)

24100
8847 S:15 SMO(1,3)


25100 26loO
BSUB(128,15,-3.0) PKD(3,3,3,0.

25:00 26:00
BSUB(128,15,-3.0) PKD(3,3,3,0.

25 loo' ' ' ' 26 loo'
BSUB(128,15,-3.0) PKD(3,3,3,0.

25100 26:00
BSUB(128,15,-3.0) PKD(3,3,3,0.

A
27:00 28:00 29:00 3ol(
10%, 1024. 0,1. 00%, F,F)
Al . 82E7
A

27:00 28:00 29:00 30:C
10%, 8452. 0,1. 00%, F,F)
A2.72E8
l\l\
27100 28100 29100 30:(
10%, 3540. 0,1. 00%, F,F)
A3.69E8
A A
A
27:00 28100 29loO 30-lc
10%, 5376. 0,1. 00%, F,F)
A3.11E7
A
A
24 loo' ' ' ' 25 loo' ' ' ' 26. -OO' ' ' ' 27loo' ' ' ' 28. -Oo' ' ' ' 29. -00 	 30 !•(
9824 S:15 SMO(1,3) PKD{3, 3, 3 , 100 .00%, 0 . 0, 1 .00%, F,F)
23:48 24:16 24:48 25:14 25:4526:07 26:32 26:59 27:26 28 L! 4 28:58 29:38

24100

25 loo 	 26 loo'

27 loo' ' ' ' 28 loo 	 29 100 	 30 Ic
_1.4E6
.O.OEO
)0 Time
3.7E6
L1.9E6
O.OEO
)0 Time
5.7E7
.2 . 8E7
0 . OEO
)0 Time
7.3E7
:3.7E7
O.OEO
)0 Time
_6.4E6
_3.2E6
O.OEO
10 Time
5.5E7
_2 . 8E7
O.OEO
0 Time

-------
Pile
Samp
355.
100%
so:
(T
357.
100%
50J
o:
367.
100%
50 J
0'
369.
100%
50J
(T
366.
100%
50J
0"

: A17JUL98B Acq: 18-JUL-1998 03. -IV .-11 Exp: EXP_M23_DB5_OVATION Voltage SIR EH- GC Autospec-UltimaE Parad
le #15 Text: BE CS3 ALS #2
8546 S:15 F:2 SMO(1,3) BSUB(128, 15 , -3 . 0) PKD(3 , 3 , 3 , 0 . 10% , 1636 . 0 , 1 . 00%, F, F)
A7.42E7
A

30:12 30:24 30:36 30:48 31:00 31:12 31:24 31:36 31:48 32:00 32:12 32:24 32:36 32:48 33:00 33:12
8517 S:15 F:2 SMO(1,3) BSUB (128, 15, -3 . 0) PKD(3 , 3 , 3 , 0 . 10%, 1152 . 0 , 1 . 00%, P, F)
A4.78E7
A

30:12 30:24 30:36 30:48 31:00 31:12 31:24 31:36 31:48 32:00 32:12 32:24 32:36 32:48 33:00 33:12
8949 S:15 F.-2 SMO(1,3) BSUB (128, 15, -3 . 0) PKD(3 , 3 , 3 , 0 . 10%, 3688 . 0, 1 . 00%, F, F)
A2 . 7 1E8
/L
3b!l2 30:24 3ol36 30:48 31166 3ill2 3ll24 33.136 SlUs 32166 32112 32124 32!36 32148 33166 33!i2
8919 S:15 F:2 SMO(1,3) BSUB(128, 15, -3 . 0) PKD(3 , 3 , 3 , 0 . 10%, 2720 . 0 , 1 . 00%, F, F)
A1.74E8
A
ll
3o!i2 36S24 36136 36:48 3ll66 31112 3il24 31136 31-4B 32166 32:12 32124 32136 32J48 33166 33112
9792 S:15 F:2 SMO(1,3) PKD(3 , 3, 3, 100. 00%, 0. 0, 1 . 00%, F,F)
30:26 30:4230:52 31:0831:18 31:4331:53 32:08 32:20 32:37 33^00 33:12

30:12 36124 36136 36:48 31:66 3lli2 31:24 3ll36 31:48 32166 32112 32124 32:36 32148 33:66 33112
igm
2.7E7
L1.3E7
" O.OEO
Time
1.7E7
L8.4E6
" O.OEO
Time
1.0E8
L5.0E7
LO.OEO
Time
6.4E7
_3.2E7
LO.OEO
Time
p6.2E7
13.1E7
LO.OEO
Time

-------
File
Samp
389.
100%
50:
o:
391.
100*
so:
o:
401.
100%
so:
o:
403.
100%
so:
o:
380.
100%
so:
0"
: A17JUL98B Acq: 18-JUL-1998 03:17:11 Exp: EXP_M23_DB5_OVATION Voltage SIR EI + GC Autospec-UltimaE Parad
le #15 Text: BE CS3 ALS #2
8156 S:15 F:3 SMO(1,3) BSUB(128, 15, -3 . 0) PKD(3 , 5, 2, 0 . 10%, 1552 . 0, 1 . 00%, F, F)
A6.24E7 A5.90E7
A A A

33J24 33136 33148 34loO 34ll2 34
8127 S:15 F:3 SMO(1,3) BSUB (128 , 15, -3 . 0) PKD(3,

33!24 33!36 33:48 34^00 34J12 . 34
8559 S:15 F:3 BSUB(128, 15, -3 . 0) PKD(3 , 5, 2, 0 . 10%

— i — i — i — i i i i — i — i — i — i — i— i — i — I — P — i — r-r- i -r- i -t i i i i i i I I i
33:24 33:36 33:48 34:00 34:12 34
8530 S:15 F:3 BSUB(128, 15, -3 . 0) PKD(3 , 5, 2, 0 . 10%

1 I I i — i i i — r— i — i — i — i — I — i — i— i— T — r i - 1 i i i i i i i | i i I I i
33:24 33:36 33:48 34:00 34:12 34
9760 S:15 F:3 SMO(1,3) PKD(3, 3, 3, 100 . 00%, 0 .0, 1 .
33:22 33:30 34:15

'33:2'4' ' '33:3'6' ' ' 33:48' '34:0o' 34!l2 34
/R IV
124 34136 34l48 3s!oO 3s!l2 3s!24 3s!36 35:
5, 2, 0.10%, 2248. 0,1. 00%, F,F)
A4.93E7 A4.73E7
/R /V
•24 34:36 34:48 35:00 35:12 35:24 35:36 35
,12588. 0,1. 00%, F,F)
13 A2 . 62E8
A
/I
i . . .......... i "i i i i I i i i i i I i i i i i i i i i i i i i i i i i
•24 34:36 34:48 35:00 35:12 35:24 35:36 35
,10808. 0,1. 00%, F,F)
18 A2 . 08E8
A
A
igm
r!.8E7
.9.2E6
L O.OEO
48 Time
_1.5E7
_7.3E6
' 0 . OEO
48 Time
1.1E8
.5.5E7
O.OEO
48 Time
8.7E7
.4.4E7
.O.OEO
[24 34:F36 34l48 3s!oO 3s!l2 3sl24 35J36 35 48 Time
00%,F,F)
34:47 34:58 35_i08 35:20 35:32 r!.3E8

_6.4E7
.O.OEO
124 34136 34':48 35loO 3s!l2 35:24 35I36 35 48 Time
V\

-------
File
Samp
423.
1008
so:
0'
425.
1002
50J
435.
100%
so:
o:
437.
1004.
50.
0
430.
1002
so:
^ 0"
s: A17JUL98B AcqV 18-JUL-1998 03:17:11 Exp: EXP_M23_DB5_OVATlON Voltage SIR EI+ GC Autospec-UltimaE Paradigm
>le #15 Text: BE CS3 ALS #2
7767 S:15 F:4 SMO(1,3) BSUB(128, 15 , -3 . 0) PKD(3 , 3 , 3 , 0 . 10%, 1484 . 0 , 1 . 00%, F, F)
A4.24E7 1.2E7
/V
36566 36512 36524' 36536 36548 37566 37512 37524' 37536 37548 38 5 00 ' 38 5 12 ' 38 524 ' 38 536 ' 38 548 ' 39
7737 S:15 F:4 SMO(1,3) BSUB( 128 , 15 , -3 . 0) PKD(3 , 3 , 3 , 0 . 10%, 884 . 0, 1 . 00%, F, F)
A4.17E7
A
A
36566 36512 36:24 36536 36548 37566 37512 37524 37536 37548 38566 38512 38524 38536 38548 39
8169 S:15 F:4 SMO(1,3) BSUB (128, 15 , -3 . 0) PKD(3 , 3 , 3 , 0 . 10%, 6540 . 0 , 1 . 00% , F, F)
Al . 92E8
/V
36:66 36:12 36:24 36:36 36548 37566 37512 37524 37536 37548 38566 385l2 38:24 38:36 38:48 39:
8140 S:15 F:4 SMO(1,3) BSUB(128, 15, -3 .0) PKD(3, 3 , 3, 0 . 10%, 3636 . 0, 1 . 00%, F,F)
Al . 84E8
/v
36{00 365l2 36524 36:36 36:48 37:00 37:12 37:24 37:36 37:48 38:00 38:12 38:24 38536 38!48 39}
9728 S:15 F:4 SMO(1,3) PKD(3 ,3,3, 100.00%, 0.0, 1 .00%, F,F)
36:09 36:36 36:53 37:07 37:18 37:41 38:06 38:17 38:33 3fl;45

36:66 36:12 36!24 36{36 36548 37566 37512 37524 37536 37548 38566 38512 38:24 38536 38548 395
15.8E6
LO.OEO
00 Time
1 . 1E7
L5.7E6
LO.OEO
00 Time
5.1E7
L2 . 5E7
O.OEO
00 Time
4.9E7
_2.4E7
O.OEO
00 Time
8.5E7
_4.2E7
O.OEO
00 Time

-------
File
Samp
457.
100%
so:
! 0"
459.
lOOi
50-
0'
469.
100%
so:
0'
471.
100%
50J
0"
454.
100%
so:
0'

: A17JUL98B Acq: 18-JUL-1998 03:17:11 Exp: EXP_M23_DB5_OVATION Voltage SIR EH- GC AutOSpec-UltimaE Parad
le #15 Text: BE CS3 ALS #2
7377 S:15 F:5 SMO(1,3) BSUB(128, 15 , -3 . 0) PKD(3 , 3 , 3 , 0 . 10%, 1824 . 0 , 1 . 00%, F, F)
A6 . 91E7
J\_
39.-12 39124 39136 39148 4o!ob 40.-12 40.-24 4ol36 40.-48 41
7348 S:15 F:5 SMO(1,3) BSUB(128, 15, -3 . 0) PKD(3 , 3 , 3 , 0 . 10% , 756 . 0 , 1 . 00%, F, F)
A7 -84 E7
J\_
39:12 39:24 39:36 39:48 40:00 40:12 40:24 40:36 40:48 41
7780 S:15 F:5 SMO(1,3) BSUB(128, 15, -3 . 0) PKD(3 , 3 , 3 , 0 . 10%, 2176 . 0, 1 . 00%, F, F)
A2 . 76E8
/\_
39:12 39.-24 39.-36 39148 4o!ob 4o!l2 4o!24 4ol36 4ol48 41
7750 S:15 F:5 SMO(1,3) BSUB (128, 15 , -3 . 0) PKD(3 , 3 , 3 , 0 . 10%, 1480 . 0 , 1 . 00%, F, F)
A3 . 08E8
yV
1 I i i — i— i — i — i — i — i — i — | — i — i — P — i — i — p~i — i — i — i — i — 1 — r — i — i 	 T*^T — i — r -r11 i ~i i 1 ' i 1 1 1 1 I I i i i I I i i i i i i i i i I i
39:12 39:24 39:36 39:48 40:00 40:12 40:24 40:36 40:48 41
9728 S.-15 F:5 SMO(1,3) PKD(3 , 3 , 3 , 100 . 00%, 0 . 0, 1 . 00%, F, F)
39:0739:12 39:18 39:25 39:36 39:49 39:58 40:08 40:14 40:22 40:32 40:44 40:52
/
39:12 39:24 39:36 39:48 40:00 40:12 40:24 40:36 40:48 41
igm
1.6E7
_8.0E6
_O.OEO
00 Time
1.8E7
_9.0E6
_O.OEO
00 Time
6.4E7
.3.2E7
_0 . OEO
00 Time
7.1E7
_3 . 6E7
_O.OEO
00 Time
9.4E7
.4.7E7
.O.OEO
00 Time

-------
File: A17JUL98B Acq: 18-JUL-1998 03:17:11 Exp: EXP_M23_DB5_OVATION Voltage SIR EI+ GC Autospec-UltimaE Paradigm
Sample #15 Text: BE CS3 ALS #2
303.9016 S:15 SMO(1,3) BSUB(128, 15, -3 . 0) PKD(3 , 3 , 3 , 0 . 10%, 1572 . 0 , 1 .00%, F, F)
100% A1.75E7 - 3.6E6
: A F
sol
o:
305.
100%
50J
o:
315.
100%
50 1
o:
317.
100%
50 1
o~-
375.
100%
50 1
o:
316.
100%
50J

24100
8987 S:15 SMO(1,3)

24100
9419 S:15 SMO(1,3)

24:00
9389 S:15 SMO(1,3)

24 :00'
8364 S:15 SMO{1,3)
23:12
A 23:44
/VW f^ AA /V

i • i i 1 i i i i i I i i < i T i i r i i i i ! , . , i i 	 1 	 1 	 1 	 i 	 1 	 1—
25:00 26:00 27:00 28:00 29:00 30:(
BSUB(128,15,-3.0) PKD(3 , 3 , 3 , 0 . 10% , 2200 . 0 , 1 . 00%, F, F)
A2.23E7
j[
i . . i 1 . i i . i i i . . , 1 i , i , , , 1 i i i i i i i~ r- • T 	 r- — i i
25:00 26:00 27:00 28:00 29:00 30:(
BSUB(128,15,-3.0) PKD(3 , 3 , 3, 0 . 10%, 4528 .0, 1 . 00%,F,F)
A3 . 66E8
A

25:00 26:00 27:00 28:00 29:00 30:(
BSUB{128,15,-3.0) PKD(3 , 3 , 3 , 0 . 10%, 5308 . 0 , 1 . 00%, F, F)
A4.64E8
A
25:00 26. -00 27loO 28:00 29:00 30 :C
BSUB(128,15,-3.0) PKD(3,3, 3, 100 . 00%, 48 . 0, 1 . 00%,F,F)
28:26
A A
A
2&2_!_ ,25^02 25^24^^ 25^58 26^22 ^ ^ ^ ^7^34 27^5|8 \J {^^^^00 _
24:00 25:00 26:00 27:00 28:00 29:00 30:C
9824 S:15 SMO(1,3) PKD(3, 3 , 3 , 100 . 00%, 0.0, 1 .00%, F,F)
23iAS 24:16 24:48 25:14 25:4526jJ)7 26;32 26:59 27:26 2BU4 28:58 29:38

24:00

25! 00 	 26!00 	 27!oo' ' ' ' 28 loo 	 29:00 	 30 !o
.1.8E6
O.OEO
30 Time
4.7E6
L2.3E6
O.OEO
30 Time
7 . 6E7
_3.8E7
O.OEO
)0 Time
9 . 6E7
.4.8E7
O.OEO
)0 Time
_9.3E3
_4.7E3
O.OEO
0 Time
5.5E7
_2 . 8E7
O.OEO
0 Time

-------
File: Al
7JUL98B Acq: 18-JUL-1998 03:17:11
Exp: EXP_M23_DB5_OVATION Voltage SIR EI+ GC Autospec-UltimaE Paradigm
Sample #15 Text: BE CS3 ALS #2
339.8597
iooa
50_
ol



• '36!
341.8568
100%
501
o:



i i i |
30:
351.9000
100%
50 J
-
o"




'36!
353.8970
100%
50J
-
ol





409.7974
100%
50 J
0'
S:15 F:2 SMO{1,3) BSUB (128, 15, -3 .



12 3bl24' 30136 30:48 3ll6d 3ll
S:15 F:2 SMO(1,3) BSUB (128, 15, -3 .




12 30:24 30:36 30:48 31:00 31:
S:15 F:2 SMO(1,3) BSUB (128, 15, -3 .




12 30124 3bl36 sbUs Sllod 31 !
S:15 F:2 SMO(1,3) BSUB(128 , 15 , -3 .




12 30:24 3oS36 sbUs 31:00 31:
S:15 F:2 SMO(1,3) BSUB(128 , 15, -3 .

0)



12
0)




12
0)




12
0)




12
0)

A 3..1. T ^O^-V^
V
"-1! 1 1 |
30:
366.9792
100%
50J
i 0"


1 -1! 1 1 I
30i
yN/X— — ' Xx~^ ^~S ^ \J \f >
12 30:24 30:36 30:48 31:00 31:
y
12
S:15 F:2 SMO(1,3) PKD(3 , 3 , 3 , 100 . 00%
30:26 30:4230:52 31:04



12 30:24 30:36 30:48 31:00 31:
31



12
PKD(3,3,3,



31124 31
PKD (3,3,3,




31:24 31
PKD(3,3,3,




3l!24 31
PKD(3,3,3,




' 31124 ' 31
PKD(3,3,3,

15 31:26
^ — "\y — ~^ ^
^^ ^^_X"
31:24 31
,0.0,1.00%,
: 18



31:24 31
0.10%, 984. 0,1. 00%,
A9.27E7

,
136 31 Us 32loO
0.10%, 2800. 0,1. 00%
A6.04E7



136 31:48 32:00
0.10%, 608. 0,1. 00%,
A4.12E8
A
A
/ \
y v
136 31:48 32ldd
0.10%, 1788. 0,1. 00%
A2.64E8
A
A
/ \
y v^
lie siUs 32lod
F,F)
A9.26E7
A
A
/ 1
r3.4E7
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O.OEO
32l 12 32! 24 32 136 32! 48 33l6d 33:12 Time
,F,F)
A6.06E7
A
y v_
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Ll.lE7
LO.OEO

32:12 32:24 32:36 32:48 33loO 33:12 Time
F,F)


A9.90E7
/\
1.4E8
_7.2E7

_O.OEO
32l 12 32124 32 lie 32148 33l6d 33! 12 Time
,F,F)


A6.33E7
/\
_9.3E7
.4 . 6E7

.O.OEO
32li2 32:24 32136 32:48 33:00 33:12 Time
100. 00%, 3904. 0,1. 00%, F,F)

31:45 31:56
_ f\ r\ . ,^/^~^~ ^
^~/\y vv/ >-/
i ' i < ' i i 	 i ' ' '
:36 31:48 32:00
F,F)
31:43 31:53 32


1 i i i i i 1 i i i i > 1 i i i
:36 31:48 32:00
32:36
32:12 32:2^\ 33:07
^-^/ \/ \s~^^~~~^, — ^\J v ^*\_y
1 . 5E4
.7.7E3
LO.OEO
32ll2 32:24 32136 32:48 33:00 33:12 Time

:08 32:20 32:37 33:00 33:12 6.2E7


.3.1E7
.O.OEO

32:12 32:24 32:36 32:48 33:00 33:12 Time
C/T

-------
File: Al
7JUL98B
Sample #15
373.8207
100%

-
50J
0"




^
375.8178
100%
-
50 J
o:



MS
383.8639
100%
SOI
-
0'




•33!
385.8610
100%
sol

0




'33!
445.7555
100%
SOl

0:


33:
^^^
— ' — i — r— r
33!
380.9760
S:





— i— i
24
S:




i i
24
S:




24
S:




i i
24
S:


24
-^v
— i — r
24
S:
Text:
15 F:3





i — p-i — r— r
33!
15 F:3




33!
15 F:3




' '33!
15 F:3




' '33!
15 F:3


33:33
/-\
s—r\^-
— i — i — i— r
33!
15 F:3
Acq: 18-JUL-1998 03:1
BE CS3
SMO (1,3)





36 ' ' '33:
SMO (1,3)




36 ' ' '33!
ALS #2
BSUB(128,15

*



48 ' '34 loo'
BSUB(128,15




— i — i — i — i — i — i — i — i —
48 34:00
7:11 Exp: EXP_M23_DB5_OVATION Voltage SIR EI+ GC Autospec-UltimaE Paradigm

,-3.0) PKD(3,
S7




34:12 34
,-3.0) PKD(3,
"A
A A
N\
J i V_
34! 12 34
BSUB(128,15,-3.0) PKD(3 , 5, 2 , 0 . 10%




36 33:




48 34:00
A1.77E8
/\
A
,/ 1
/V v_
34:12 34
BSUB(128,15,-3.0) PKD(3, 5, 2, 0. 10%




i i i i i I
36 33:
SMO (1,3)


33:43
> 	 s~\^
T t — i~~i — i — r
36 33:
SMO (1,3)




48 34:00
BSUB(128,15


33:52
-^^-^. 	 •-

48 34:00
A3.42E8
A
A
/\ \
/v v_
34:12 34
,-3.0) PKD(3,

34:11
A^L-_
^J \~~^ — ^

34:12 34
PKD(3,3,3,100.00%,0.0,1.
100%33:22 33:30
50J
v ol
34:15

5, 2, 0.10%, 53560. 0,1. 00%, F,F)
2
A6. 85E7
AA6.35E7
A
/ V


.1.
0.
! i i — i i f 1 — i i i ' 1 i i i i i i i I i i" i i i i i I i i i i i i i i i i— i r— i i i
!24 34:36 34:48 35:00 35:12 35:24 35:36 35 48
5, 2, 0.10%, 42572. 0,1. 00% ,F,F)
A5.67E7 T2'
AA5.22E7
A
> V

.1.
0.
!24 34!36 34 l48 35!oO 35:12 3s!24 3s!36 35.48
,40516. 0,1. 00%, F,F)


A3.69E7
S\^
7.
1.3.

• o.
!24 '34:f36' 34J48 3s!oO 35:12 3s!24 3s!36 35 48
,49724. 0,1. 00%, F,F)


A6.78E7
yv
1.
L7.

• o .
!24 34!36 34!48 3s!oO 3s!l2 3s!24 35:36 35 48
3, 3, 100. 00%, 1832. 0,1. 00%, F,F)
34:45 34:58

/ \^J VJX8 35:16 V 35:32 35:43
_^- — — ^/ — ^~y ^"^ ^-^ ^—^ V_^^ — v-x> — ^, — ^_^y ^ 	 -^_s/ ^--^
1.
i.6.

0.

•24 34!36 34:48 35:00 35:12 35«24 35:36 35:48
00%,F,F)
34:42 34:58 3S;08 35.20 35:32 1.

- '33!
24
33!
36 33:
48 34:00
34:12 34
-6.
-o.
:24 34:36 34:48 35:00 35:12 35:24 35:36 35:48


7E7


3E7
OEO
Time

2E7

1E7
OEO
Time

9E7
9E7

OEO
Time

5E8
7E7

OEO
Time

4E4
9E3

OEO

Time

3E8
4E7
OEO
Time
If

-------
File: A17JUL98B
Acq: 18-JUL-1998 03:17:11
Sample #15 Text: BE CS3
407.7818 S-.15 F:
100%,

50.;
o-



36166 36
409.7788 S.-15 F:
100%,

50 j
0;



36166 36
417.8253 S:15 F:
100%
50J
-
OJ




36166 36
419.8220 S:15 F:
100%
50J
:
o:




36166 36
479.7165 S:15 F:
100%
:
50 1
o:
4 SMO (1,3)
A5.79E7
A
A
/ v^
:12 36:24
4 SMO (1,3)
A5.68E7
A
/\
/ V
Il2 36124
4 SMO (1,3)
A1.13E8
A
A
/ \
y V-T
i i n i i 1 i I
:12 36:24
4 SMO (1,3)
A2.50E8
A
A
/ \
/ v^
•12 36l24
4 SMO (1,3)
ALS #2
BSUB (128, 15, -3.0)




36136 36.'48 37 1
BSUB (128, 15, -3.0)




36l36 36148 3?!
BSUB (128, 15, -3.0)




1 ' ' | 	 | i < i ' ' |
36:36 36:48 37:
BSUB(128,15,-3.0)




36:36 36148 37:
BSUB (128, 15, -3.0)
Exp:

EXP_M23_

PKD ( 3 ,




00




37!
PKD ( 3 ,




00




37!
PKD ( 3 ,




00




37!
PKD ( 3 ,




00




37!
PKD ( 3 ,

3,3,0.




12 37
3,3,0.




12 37
3,3,0.




12 37
3,3,0.




12 37
.DB5

10%

A4

j
124
10%

A4

/
124
10%


A2
_s
124
10%


A5
_S
124
_OVATION Voltage SIR EI+ GC Autospec-UltimaE Paradigm

,2896.0

.83E7
A
/ V
37136
,4068.0

.71E7
A
' V
371-36
,6436.0


28E7
/~\^
37:36
,14988.


08E7
^^
37136
3, 3, 100. 00%, 2332
37 A09

J\ 3/i
' I — y^J

36:00 36
430.9728 S:15 F:
36:19
11 n
\ I WA
v~w ^ V,
1 1 1 1 1 1 1 1 1
:12 36:24
4 SMO (1,3)
100% 36:09
50 1
o-
'

LT — | — | — | — i — | — | — | — i — | —
^ 36:00 36


1 i i i i i 1 i i
•12 36:24
36:58 /\
A
36:40 36:5lA
-S\A /\ 1 \
V'X^/vVv-^/VJ v

36:36 36:48 37:
PKD(3,3,3,100.00%
36:36 36:53


T i T r~i i i i i | i I~T n r
36:36 36:48 37:
/ V/\37:22
^J

00
,0.0
37


00


37:
,1.
07


37!
\-f \

12 37
00%, F,
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-------
10

-------
OPUSquan   20-JUL-1998
                   Page 1
                                                                    Page 1 of 8

 Ent: 39 Name: Total Tetra-Furans  F:l  Mass: 303.902 305.899 Mod? no   tHom:2

 Run: 10 File: al7ju!98b    S:5  Acq:17-JUL-98 19:46:16 Proc:20-JUL-98 09:02:31
 Tables: Run: al7jul98b  Analyte: m8290-23-»  Cal: m8290-23-»Results: M8290-23*
 Version: V3.5 17-APR-1997 11:14:34  Sample text: SB
   Amount: 27.92
     Cone: 27.92
   Tox #1: -
Name
2,3,7,8-TCDF
of which 23.96
of which 23.96
     Tox #2: -

#     RT Respnse
named and 3.96
named and 3.96
      Tox *3: -
                                        RA
1  23:40 1.9e+04  1.06 n
         1.9e+04

2  27:28 l.le+05  0.91 n
         l.le+05
                                              Cone

                                               3.96
                                                   9
                                                   9
                                              23.96
unnamed
unnamed
                  Area  Height    S/N  Mod?
               9.5e+03 3.3e+03 2.7e+00 n  n
               9.0e-t-03 3.6e-t-03 1.4e+00 n  n
              5
               5.3e+04 l.le+04 8.7e+00 y  n
               5.9e+04 l.le+04 4.3e+00 y  n
                                                                    Page 2 of 8

 Ent: 40 Name: Total Tetra-Dioxins F:l  Mass: 319.897 321.894 Mod? no   #Hom:l

 Run: 10 File: al7ju!98b    S:5  Acg:17-JUL-98 19:46:16 Proc:20-JUL-98 09:02:31
 Tables: Run: a!7ju!98b  Analyte: m8290-23-»  Cal: m8290-23-»Results: M8290-23*
 Version: V3.5 17-APR-1997 11:14:34  Sample text: SB
   Amount: 15.45
     Cone: 15.45
   Tox #1: -

Name

2,3,7,8-TCDD
of which 15.45
of which 15.45
     Tox #2: -

#     RT Respnse
named and *
named and *
      Tox #3: -
    RA
1  28:27 8.3e+04  0.98 n
         8.3e+04
          Cone

          15.45
unnamed
unnamed
Area  Height
                                  S/N  Mod?
                                                   4.1e+04  7.8e+03  3.8e+00 y   n
                                                   4.2e+04  8.2e+03  6.4e+00 y   n
                                                                     Page  3  of  8

  Ent:  41 Name: Total  Penta-Furans  F:2  Mass: 339.860  341.857 Mod? no   #Hom:l

  Run:  10 File: a!7ju!98b     S:5  Acq:17-JUL-98  19:46:16  Proc:20-JUL-98  09:02:31
  Tables: Run: a!7ju!98b  Analyte: m8290-23-»  Cal: m8290-23-»Results: M8290-23»
  Version: V3.5 17-APR-1997  11:14:34   Sample text:  SB
   Amount:  45.39
      Cone:  45.39
   Tox #1:  -

 Name

 1,2,3,7,8-PeCDF
of which 45.39
of which 45.39
     Tox #2: -

#     RT Respnse
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      Tox  #3:  -
    RA
 1   31:57  1.4e+05   1.79 n
          1.4e+05
           Cone

           45.39
 unnamed
 unnamed
 Area  Height    S/N  Mod?
                                                    8.8e+04  2.9e+04 3.0e+01 y  n
                                                    4.9e+04  1.7e+04 6.6e+00 y  n
                                                                     Page 4 of 8

  Ent:  42 Name:  Total Penta-Dioxins F:2   Mass:  355.855 357.852 Mod? no   #Hom:2

  Run:  10 File:  a!7ju!98b    S:5  Acq:17-JUL-98 19:46:16 Proc:20-JUL-98 09:02:31
  Tables: Run:  al7ju!98b  Analyte: m8290-23-»  Cal:  m8290-23-»Results: M8290-23»
  Version:  V3.5  17-APR-1997 11:14:34  Sample text:  SB
    Amount:  34.66
      Cone:  34.66
    Tox #1:  -
 of  which 32.20
 of  which 32.20
      Tox #2:  -
 named and 2.47     unnamed
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       Tox #3:  -

-------
' OPUSquan   20-JUL-1998                Page 2
 i>Jame               #     RT Respnse     RA   Cone    Area  Height    S/N  Mod?

 1,2,3,7,8-PeCDD    1   32:37 1.3e+05  1.49  y  32.20
                            1.3e+05               7.6e+04 3.0e+04 1.2e+01 y  n
                                                  5.1e+04 1.8e+04 2.0e+01 y  n
                    2   32:46 9.7e+03  3.22  n   2.47
                            9.7e+03               7.4e+03 3.0e+03 l.le+00 n  n
                                                  2.3e+03 9.4e+02 l.Oe^OO n  n
                                                                                            £'' 265

-------
OPUSquan   20-JUL-1998
                                      Page 3
 Ent: 43 Name: Total Hexa-Furans
                                                                    Page 5 of 8

                                   F:3  Mass: 373.821 375.818 Mod? no   #Hom:16
 Run: 10 File: a!7ju!98b    S:5  Acq:17-JUL-98 19:46:16 Proc:20-JUL-98 09:02:31
 Tables: R\in: a!7ju!98b  Analyte: m8290-23~»  Cal: m8290-23-»Results: M8290-23*
 Version: V3.5 17-APR-1997 11:14:34  Sample text: SB
   Amount: 162.28  of which 116.66  named and 45.62
     Cone: 162.28  of which 116.66  named and 45.62
                        Tox #2: -         Tox #3: -
   Tox #1: -

Name
                         RT Respnse
                                        RA
                   1  33:31 1.4e+04  4.13 n
                            1.4e+04

                   2  33:38 1.3e+04  1.61 n
                            1.36+04

                   3  33:43 6.8e+03  6.22 n
                            6.8e+03

                   4  33:47 1.7e+04  2.87 n
                            1.7e+04

                   5  33:49 8.8e+03  1.00 n
                            8.8e+03

                   6  33:56 7.5e+03  0.25 n
                            7.5e+03
1,2,3,4,7,8-HxCDF  7
                      34:11 5.5e+04  2.32 n
                            5.5e+04
1,2,3,6,7,8-HXCDF  8  34:15 7.6e+04  1.07 y
                            7.6e+04
                   9  34:29 6.4e+03  0.15 n
                            6.4e+03

                   10 34:37 6.3e+04  1.43 n
                            6.3e+04
2,3,4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF  11 35:08 8.3e+04  1.35 y
                            8.3e+04

                   12 35:18 l.Oe+04  0.47 n
                            l.Oe+04

                   13 35:22 8.9e+03  4.38 n
                            8.9e+03

                   14 35:31 l.le+04  1.91 n
                            l.le+04

                   15 35:36 3.5e+03  0.30 n
                            3.5e+03

                   16 35:37 3.5e+03  0.30 n
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                                                      Area  Height    S/N  Mod?
 l.le+04 4.2e+03 2.6e+00 n  n
 2.6e+03 1.2e+03 l.le+00 n  n
5
 7.8e+03 3.0e+03 1.9e+00 n  n
 4.8e+03 1.7e+03 1.6e+00 n  n

 5.9e+03 2.3e+03 1.4e+00 n  n
 9.5e+02 4.4e+02 4.0e-01 n  n

 1.3e+04 4.4e+03 2.8e+00 n  n
 4.4e+03 1.4e+03 1.36+00 n  n

 4.4e+03 l.le+03 6.7e-01 n  n
 4.4e+03 1.4e+03 1.3e+00 n  n
2
 1.5e+03 6.2e+02 4.0e-01 n  n
 6.0e+03 1.8e+03 1.7e+00 n  n
3
 3.8e+04 1.26+04 7.86+00 y  n
 L.6e+04 7.0e+03 6.4e+00 y  n

 3.9e+04 1.4e+04 8.9e+00 y  n
 3.7e+04 1.26+04 l.le+01 y  n

 8.5e+02 3.6e+02 2.3e-01 n  n
 5.56+03 1.3e+03 1.2e+00 n  n
1
 3.7e+04 1.26+04 7.66+00 y  n
 2.6e+04 9.16+03 8.3e+00 y  n
7
 4.8e+04 1.2e+04 7.5e+00 y  n
 3.5e+04 8.3e+03 7.6e+00 y  n
3
 3.3e+03 1.3e+03 8.0e-01 n  n
 7.1e+03 2.46+03 2.26+00 n  n
0
 7.2e+03 2.16+03 1.3e+00 n  n
 1.6e+03 6.46+02 5.96-01 n  n

 7.0e+03 1.9e+03 1.2e+00 n  n
 3.7e+03 1.5e+03 1.3e+00 n  n

 8.1e+02 3.5e+02 2.2e-01 n  n
 2.7e+03 l.Oe+03 9.16-01 n  n
5
 8.2e+02 4.86+02 3.0e-01 n  n
 2.7e+03 l.Oe+03 9.16-01 n  n
                                                                    Page 6 of 8

 Ent: 44 Name: Total Hexa-Dioxins  F:3  Mass:  389.816 391.813 Mod? no   #Hom:10

 Rxm: 10 File: a!7ju!98b    S:5  Acq:17-JUL-98 19:46:16 Proc:20-JUL-98 09:02:31
 Tables: Run:  a!7ju!98b  Analyte: m8290-23-»  Cal: m8290-23-»Results: M8290-23»
 Version: V3.5 17-APR-1997 11:14:34  Sample text: SB
                                                                                                r

-------
OPUSguan   20-JUL-1998
 Page 4



Amount: 149.52
Cone: 149.52
Tox #1: -
Name
1


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of

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RT
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.2e+04 9.

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8e+03



S/N Mod?

4.9e+OP y n
4.2e+00 y n
1,2,3,6,7,8-HxCDD  2  34:46 8.2e+04
                            8.2e+04

                   3  34:52 8.8e+03
                            8.8e+03

1,2,3,7,8,9-HxCDD  4  34:59 l.Oe+05
                            l.Oe+05

                   5  35:04 6.0e+03
                            6.0e+03

                   6  35:08 5.3e+03
                            5.3e+03

                   7  35:13 5.2e+03
                            5.2e+03

                   8  35:18 4.0e+03
                            4.0e+03

                   9  35:24 9.9e+03
                            9.9e+03

                   10 35:26 8.2e+03
                            8.2e+03
                                     0.58 n   37.08
1.31 y    4.24
1.34 y   46.45
              5
              3

              6.
2.84 n    2.90
2.37 n    2.55
1.20 y    2.54
3.89 n    1.94
.Oe+04 l.le+04  7.1e+00 y   n
.2e+04 9.8e+03  4.2e+00 y   n

,0e+03 1.8e+03  1.2e+00 n   n
,8e+03 1.5e+03  6.6e-01 n   n

 Oe+04 1.5e+04  9.6e+00 y   n
 4e+04 1.2e+04  5.3e+00 y   n

 4e+03 1.6e+03  l.Oe+00 n   n
 6e+03 7.2e+02  3.1e-01 n   n
                7e+03  1.4e+03  8.7e-01 n
                6e+03  7.2e+02  3.1e-01 n
               ,9e+03  l.le+03  7.0e-01 n  n
               ,4e+03  1.5e+03  6.6e-01 n  n

               ,2e+03  l.le+03  7.2e-01 n  n
               ,2e+02  5.8e+02  2.5e-01 n  n
1.58 n    4.78
0.72 n    3.95
              3
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               .le+03 1.4e+03  8.8e-01  n
               .8e+03 1.3e+03  5.7e-01  n
               .4e+03 1.5e+03  9.8e-01  n  n
               .7e+03 l.le+03  4.6e-01  n  n
                                                                                                    267

-------
OPUSquan   20-JUL-1998
                   Page 5
                                                                    Page 7  of  8

 Ent: 45 Name: Total Hepta-Furans  F:4  Mass:  407.782  409.779  Mod?  no    #Ho»:2

 Run: 10 File: al7ju!98b    S:5  Acq:17-JUL-98 19:46:16 Proc:20-JUL-98  09:02:31
 Tables: Run: al7ju!98b  Analyte: m8290-23-»  Cal:  m8290-23-»Results: M8290-23»
 Version: V3.5 17-APR-1997 11:14:34  Sample text:  SB
   Amount: 137.39  of which 137.39  named and *
     Cone: 137.39  of which 137.39  named and *
   Tox #1: -            Tox #2: -         Tox #3:  -
Name
                         RT Respnse
                                        RA
1,2,3,4,6,7,8-HpCDFl  36:22 7.Oe+04  1.01 y
                            7.0e+04

l,2,3,4,7,8,9-HpCDF2  37:32 3.Oe+04  0.61n
                            3.0e+04
                           Cone

                           90.72

                               1

                           46.67
                                  unnamed
                                  unnamed
                  Area  Height    S/N  Mod?
               3.5e+04 9.4e+03  6.2e+00 y  n
               3.5e+04 9.7e+03  8.7e+00 y  n
              7
               l.le+04 4.3e+03  2.8e+00 n  n
               1.9e+04 5.8e+03  5.2e+00 y  n
                                                                    Page 8 of 8

 Ent: 46 Name: Total Hepta-Dioxins F:4  Mass: 423.777 425.774 Mod? no   #Hom:2

 Run: 10 File: a!7ju!98b    S:5  Acq:17-JUL-98 19:46:16 Proc:20-JUL-98 09:02:31
 Tables: Run: a!7ju!98b  Analyte: m8290-23-»  Cal: m8290-23-»Results: M8290-23*
 Version: V3.5 17-APR-1997 11:14:34  Sample text:  SB
   Amount: 58.27
     Cone: 58.27
   Tox #1: -
of which 40.38
of which 40.38
     Tox #2:  -
named and 17.89
named and 17.89
      Tox #3:  -
Name
                         RT Respnse
                                        RA
                      36:35 2.1e+04  0.74 n
                            2.1e+04
 1,2,3,4,6,7,8-HpCDD2  37:10 4.7e+04  1.64 n
                            4.7e+04
                           Cone

                           17.89
                                £
                                ]
                           40.38
unnamed
unnamed
                  Area  Height
                                                                      S/N  Mod?
               8.8e+03 3.1e+03 3.8e+00 y  n
                .2e+04 3.3e+03 4.0e+00 y  n

               2.9e+04 8.56+03 l.le+01 y  n
               1.8e+04 5.3e+03 6.4e+00 y  n
                                                                                                r f
                                                                                    288

-------
File: A17JUL98B  Acq: 17-JUL-1998  19:46:16  Exp:  EXP_M23JDB5_OVATION  Voltage SIR EI+  GC Autospec-UltimaE  Paradigm
Sample #5  Text: SB  ALS  #3
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       =—r*—r*—i^ i  " T	1	i*^ i ^—i	1	1—~T—~T	r	1	1	f—P	1	1	1   I	(  i   i  r
                24:00          25:00           26:00          27:00
327.8847 S:5 SMO(1,3) BSUB(128,15,-3.0) PKD(3,3,3,0.10%,7132.0,1.00%,F,F)
100%
                                                                               28:00          29:00

                                                                                     A3.39E5
                                                               27:00
                                                                               28:00
29:00
                 24iOO          25:00           26:00
316.9824 S:5 SMO(1,3) PKD(3,3,3,100.00%,0.0,1.00%,F,F)
1004.,	23^55  24:22 24:45  25:12    25:44	26:38    27:1127:3427^55  28:2128;42  29:09  29:36
                                                                              30:00  Time

                                                                                   8.3E4

                                                                                  _4.2E4

                                                                                  .O.OEO
                                                                              30:00  Time
 50j

  OJ
              I " I  " I  ' '!
                24:00
'25:00'
                                                26:00'
                                                                                                                  .7.5E7
                                                                                                                  _3.7E7
                                                                                                                   O.OEO
                                                                                                              30:00  Time
29:00

-------
Pile: A17JUL98B  Acq:  17-JUL-1998 19:46:16  Exp: EXP_M23_DBE>_6VATION Voltage SIR EI +GC Autospec-UltimaE—Paradigm
Sample  #5  Text:  SB  ALS #3
355.8546 S:5  F:2  SMO(1,3) BSUB(128,15,-3.0) PKD(3,3,3,0.10%,2576.0,1.00%, F, F)
100%
 50J
                                         _3.2E4
                                         _1.6E4
                                                                                                                    O.OEO
     i  i i T i i i  i i i i i i  i i i i i  i i i i i i  i i i i i i i  i i i i i i i  i i i i i i  i	i i i i i i i  i i i i i i  i i i i i i  i i i i i i  i i i i i i  i i i i i i  i n i r i  i i i
     30:12  30:24  30:36   30:48   31:00  31:12  31:24  31:36  31:48  32:00  32:12  32:24  32:36  32:48  33:00  33:12    Time
357.8517 S:5 F:2  SMO(1,3)  BSUB(128,15,-3.0) PKD(3,3,3,0.10%,900.0,1.00%,F,F)
1004
 50.
              A5.Q8E4
         _1.8E4
                                                                                                  A1.49E4
                                                                                                 30I5A
     30:12  30:24  30136  30:48   31:00  31:12  31:24  31:36  31:48  32:00  32:12  32:24  32:36  32:48  33:00  33:12
367.8949 S:5 F:2  SMO(1,3)  BSUB(128,15,-3.0) PKD(3,3,3,0.10%,4304.0,1.00%,F,F)
100%
 50J
              A2.13E5
         ^7.5E4
                                         _3.7E4
                                                                                               1.13E4
                                                                                                                    O.OEO
    i T"f i "r r in f r i t i i—i—r~~i—rr—n—i T* i—i—i—i i i i—i—i—i—i—i—i—i—i—r-i—i—r—i—i -T • i—T*T—i—i—r~i—i i i i i i—i—i—i—i—i—i—i—i n—i—r—r-r™i—i—I~*T—i—i—i—r-r"i—r i "I~T i -r i  i i ' I I i  i i
     30:12   30:24  30:36  30:48  31:00  31:12  31:24  31:36  31:48  32:00  32:12  32:24  32:36  32:48  33:00  33:12    Time
369.8919 S:5 F:2 SMO(1,3)  BSUB(128,15,-3.0) PKD(3 , 3,3,0.10%,2288.0,1.00% , F, F)
100%                                                                                    A1.3.9E5                    ..4.7E4
 50J
366.9792 S:5 F:2 SMO(1,3)  PKD(3,3,3,100.00%,0.0,1.00% , F, F)
100%.      30:2030:30              31:00  31:11	31:44
32:11   32:25
                                                                                                           A7.10E3
33:05
                                         _2.3E4
                                                                                                                    O.OEO
          .8. 4E7
 50J
                                         .4.2E7
     r T'-I—i i • r* n—r-T~r~i—i—r-i—i—t~t"T"i—i—i—i—i—i—i—r—i—r—i i i—i—i—r—i—r—1—1—i—i—i—i—r—|—i—i—i—i—r~i—i—i—i—i—i—r-1—t—i—i—i—i—i—i—r—i—i—r—i—n—i—r-i—n—i—r~i—i r  i i 'i1 i" r i—i T1 i t -r-7-y
     30:12  30:24  30:36  30:48  31:00  31:12  31:24  31:36  31:48  32:00  32:12  32:24  32:36  32:48  33:00  33:12    Time

-------
iFile: A17JUL98B  Acq:  17-JUL-1998  19:46:16   Exp:  EXP_M23_DB5_OVATION Voltage SIR EH-—GC Autospec-UltimaE—Paradigm
Sample #5  Text: SB  ALS  #3
389.8156 S:5 F:3 SMO(1,3)  BSUB(128,15,-3.0)  PKD(3,5,2,0.10%,1560.0,1.00%,F,F)
100^                                                                      A5.96E4
                                                                 A3.03E4
 50:
                         A7.82E3
                         ~T
                                          T
                                         1.6E4


                                        17.8E3


                                         O.OEO
                                                            ~T
      33:24    33:36    33i48    34.:00    34.:12    34.:24    34i36    34148
391.8127 S:5 F:3 SMO(1,3)  BSUB(128,15,-3.0)  PKD(3,5,2,0.10%,2312.0,1.00%,F,F)
100$                                                                     A4.4.4E4
                                                                A5.19E4
 50_
      33^24    33i36    33148    34lOO    34!l2    34124    34!36'    34148
401.8559 S:5 F:3 BSUB(128,15,-3.0)  PKD(3,5,2,0.10%,9452.0,1.00%, F,F)
    1—i—I—I—I—I—I—I—l—l—I—I—I—I—li I I—I—i—I—i—i—i—r
  35:00    35:12    35:24   35:36    35:48  Time
                                                                                    A2.38E3   A4.75E3
                                         1.4E4


                                        16.8E3


                                         O.OEO
    ~I—i—'—i—'—>—I—>—i  i i—i—l—i—l—i—i—i—i—i—i—i—i—i—r
  35:00    35:12    35:24   35:36    35:48  Time
      33i24    33i36    33:48    34:00    34:12    34:24    34:36    34:48    35:00    35:12    35T24    35:36^35:48  Time
403.8530 S:5 F:3 BSUB(128,15,-3.0)  PKD(3,5,2,0.10%,5444.0,1.00%,F,F)
1004                                                            A1.13E5  A1.37E5
 50J
                                        r_4.7E4
                                        _2.4E4
                                                                                                                   O.OEO
      33:24    33:36    33:48    34:00    34:12    34:24    34:36    34:48   35:00    35:12
380.9760 S:5 F:3 SMO(1,3) PKD(3,3,3,100.00%,0.0,1.00%,F,F)
100*33:22   33:33                   34:07       34:22 34:30   34:40
 50J
34:5735:04  35:13  35:23
:36   35:48  Time

35:40     1.7E8
                                        18.7E7
                                                                                                                   O.OEO
     '33; 2V '  '33:36' ' '33 UV  ' 's^lo'o' '  '34! 12' '  '3'4!2'4' '"^34! 36'   '34 148'   VsloV '  's'sll^' ' ' 35124' ' ' 35 ! 36    3 5 i 4 8  Time

-------
File: A17JUL98BAcq:  17-JUL-1998 19:46:16Exp: EXP_M23_DB5_OVATION Voltage SIR EI+GC Autospec-UltimaEParadigm
Sample  #5  Text: SB  ALS  #3
423.7767 S:5  F:4 SMO(1,3)  BSUB(128,15,-3.0)  PKD(3,3,3,0.10%,804.0,1.00%,F,F)
100%.                                          A2.9,OE4                                                             9.0E3
  so:
                           A8.76E3
     A3.40E3
                                     A9.52E3
                                                   9.46E3
                                         14.5E3
          I i i i i i  I i T i i i I  i i i l i I i  i i i i | i i i  ii I i i i i i  I i i i i i i i  i i i i i i  i i i i I i i i  i i i i i i i  i i i i i i i  i	I''' i~TT i i i i i [
       36:00  36:12  36:24  36:36  36:48   37:00  37:12  37:24  37:36  37:48   38:00  38:12  38:24  38:36  38:48  39:00  Time
425.7737 S:5 F:4 SMO(1,3) BSUB(128,15,-3.0) PKD(3 , 3 , 3,0.10%,820.0,1.00%, F, F)
100%                                          A1.77E4
 50J
                          A1.19E4
                                        _6.3E3
                                        _3.2E3
                                                                                                                  O.OEO
       36:00  36:12  36:24  36:36  36:48  37:00  37:12  37:24  37:36  37:48   38:00  38:12  38:24  38:36  38:48  39:00  Time
435.8169 S:5 F:4 SMO(1,3) BSUB(128,15,-3.0) PKD(3 , 3 , 3,0.10%,6036.0,1.00%, F, F)
100%                                         A6.52E4
 50J
  OJ
                                        _2.6E4
                                        11.3E4
                                        LO.OEO
       36166 ' 36!i2 ' 36I24 ' 36T36  36:48  37:00  37:12  37:24  37:36  37:48  38:00  38:12  38:24  38:36  38:48  39:00  Time
437.8140 S:5 F:4 SMO(1,3) BSUB(128,15,-3.0) PKD(3,3,3,0.10%,1868.0,1.00%,F,F)
100&                                          A6.38E4
 50J


  0
                                         2. 6E4


                                        _1.3E4


                                         O.OEO
       36:00  36:12  36:24  36:36  36:48  37:00  37112  37:24  37:36   37:48  38:00  38:12  38:24 '.-38:36  38:48  39:00  Time
430.9728 S:5 F:4 SMO(1,3) PKD(3,3,3,100.00%,0.0,1.00%,F,F)
100%         36jll	36:36	37:04     37:20  37:32
 50J
37:55    3R:12 38:22
38:45
.1.1E8
                                        _5.7E7
                                                                                                                 O.OEO
       36:00  36:12  36:24  36:36  36:48  37:00  37:12  37:24   37:36  37:48  38:00  38:12  38I24 ' 38:36  38:48 '  39:00  Time

-------
File: A17JUL98B  Acq:  1V-JUL-1998  19:46:16Exp: EXP_M23_DB5_OVATION Voltage SIR EI +—GC Autospec-UltimaE—Paradigm	
Sample #5  Text: SB  ALS  #3
457.7377 S:5 F:5 SMO(1,3)  BSUB(128,15,-3.0) PKD(3,3,3,0.10%,3556.0,1.00%,F,F)
100%,                                                     40;03                                                    9.1E3
 50:
                                                                                                                  14.5E3
           39:12       39124      39i36      39i48      40iOO      40il2      40'24
459.7348 S:5 F:5 SMO(1,3)  BSUB(128,15,-3.0) PKD(3 , 3,3,0.10%,692.0,1.00%,F,F)
1004                                                    A2.36E4
 50J
                                                                                                             O.OEO
                                                                                                         41:00  Time
                                               A2.92E3
                                                                3.98E3
            T
                                                                                                                  .3.3E3
                                                                                                                 LO.OEO
                                                        T"
          39:12       39:24      39:36      39:48      40:00      40il2      40:24
469.7780 S:5 F:5 SMO(1,3)  BSUB(128,15,-3.0) PKD(3,3,3,0.10%,2744.0,1.00%,F,F)
100%,                                                    A4.98E4
 50.
                                                                                        - T— | - 1
                                                                                        40:36
                                                                                             I - 1 - 1 I ' I  1^~ I - 1 - 1
                                                                                              40:48       41:00  Time
                                             T"
                                                        T"
           39:12       39:24      39:36      39U8      40iOO      40il2      40124
471.7750 S:5 F:5 SMO(1,3)  BSUB(128,15,-3.0) PKD(3,3,3,0.10%,1468.0,1.00%,F,F)
100%                                                   A7.Q8E4
 50J
                                                                                                            _8.9E3
                                                                                                                  O.OEO
                                                                                                   40:48
                                                                                                         41:00  Time

                                                                                                             2. OE4


                                                                                                            .9.9E3
                                                                                                                  O.OEO
          39:12       39:24      39:36      39:48      40:00      40:12
454.9728 S:5 F:5 SMO(1,3)  PKD(3,3,3,100.00%,0.0,1.00%,F,F)
1004     39:10	39:23	 39:32     39:42	39:5440:00 40:06 40:13
                                                                             40:24
                                                                                   40:36
                                                                                                   40:48
                                                                   41:00  Time
 50:
  OJ
                                                                             40:24    40:34
                                                                                            40;46
i  i  i  i i—r-
     39:12
                    I	T- I ' -f ~
                      39:24
                                    T' " I* '!'• 't
-r~r—r—i—r
39:48
                                                      —i—p~r~
                                                       40:00
—T—I—-1	1—T-
 40:12
T—|	r~
 40:24
                                                                                                                  .1.3E8
                                                                                                             6.3E7
                                                                                                             O.OEO
39:36
40:36
                                                                                                   40:48
41:00  Time

-------
File: A17JUL98BAcq: 17-JUL-1998 19:46:16Exp: EXP_M23_DB5_OVATION Voltage SIR EI +GC Autospec-UltimaEParadigm
Sample #5  Text: SB  ALS #3
303.9016 S:5 SMO(1,3) BSUB(128,15,-3.0) PKD(3,3,3,0.10%,1244.0,1.00%,F,F)
100%                                                                 A5.3.5E4                                      1.2E4

                                                                                                                 L6.2E3

                                                                                                                  O.OEO
                                                                                                             30100  Time

                                                                                                                  1.4E4

                                                                                                                 _7.2E3

                                                                                                                  O.OEO
           i	1	1	1   r  T ••" i	r -i
                24:00          25iOO          26100           27iOO
305.8987 S:5 SMO(1,3) BSUB(128,15,-3.0) PKD(3,3,3,0.10%,2664.0,1.00%,F,F)
100%                                                                 A5.87E4


 50 j
                                                                              28:00
                                                                                              29:00
                 24:00'          25iOO          26iOO           21-00
315.9419 S:5 SMO(1,3) BSUB(128,15,-3.0) PKD(3,3,3,0.10%,3632.0,1.00%,F,F)
100%                                                                A2.36E5

 50 j


      	24:00	25! 00	26 !00           27iOO
317.9389 S:5 SMO(1,3) BSUB(128,15,-3.0) PKD(3,3,3,0.10%,5228.0,1.00%,F,F)
100%                                                                A2.56E5
                                                                              28:00
                                                                                              29:00
                                                                                                       A9.28E3
                                                                                                             30:00

                                                                                                                  4

                                                                                                                 .2

                                                                                                                  0
                                                                              28:00
                                                                                             29:00
                 24!00          25:00          26:00           27iOO
375.8364 S:5 SMO(1,3) BSUBU28,15,-3 . 0) PKD(3,3,3,100.00%,56.0,1.00%,F,F)
100%              24:07            25:12                      26.57
                                                                              28:00
                                                                                             29:00


                                                                                                29:09
                                                                                                             30:00

                                                                                                                 ^6

                                                                                                                 _3

                                                                                                                  0
                                                                                                             30:00

                                                                                                                 _2
        Time

      .9E4

      .4E4

      .OEO
        Time

      .1E4

      .1E4

      .OEO
        Time

      .6E3

      .3E3
                                                               27:00
                                                                              28:00
                                                                                             29:00
                 24:00          25:00          26:00
316.9824 S:5 SMO(1,3) PKD{3,3,3,100.00%,0.0,1.00%,F,F)
100%	23:55  24:22 24:45  25:12    25;44	26:38    27^1127:3427:55 28:2128:42  29:09  29:36
30:00
 50J
                24 loo'
                                       1 - 1 - 1 - 1
                                25:00
                                               26:00
                                                               27 loo'
                                                                                                                .3
30:00
.5E7

.7E7

. OEO
 Time

-------
file: A17JUL98B  Acq: 17-JUL-1998  19:46:16  Exp: EXP_M23_DB5_OVATION Voltage SIR EI +—GC Autospec-ultimaE—Paradigm
Sample #5  Text: SB  ALS #3
339.8597 5:5 F:2 SMO(1,3) BSUB(128,15,-3.0) PKD(3,3,3,0.10%,988.0,1.00%,F,F)
100%                                                            A8.77E4
                                                                               A6.41E4
                                                                                                  A1.41E4
                                                                                                     /\
 3.0E4

Ll.5E4

LO.OEO
     30:12  30:24  30:36  30:48  31:00  31:12  31:24  31:36  31:48  32:00  32:12  32:24  32:36  32:48  33:00  33:12    Time
341.8568 S:5 F:2 SMO(1,3) BSUB(128,15,-3.0) PKD(3,3,3,0.10%,2608.0,1.00%,F,F)
100%                                                            A4.90E4                                          _2.1E4
                                                                                                                 L1.0E4

                                                                                                                 LO.OEO
     30:12  30:24  30:36  30:48  31:00  31:12  31:24  31:36  31:48  32:00  32:12  32:24  32:36  32:48  33 00  33  12
351.9000 S:5 F:2 SMO{1,3) BSUB(128,15,-3.0) PKD(3,3,3,0.10%,800.0,1.00%,F,F)

                                                                A2.07E5

 50J

                                           A1.80E4
  O
 8.0E4

.4.OE4

 O.OEO
     30-12  30{24 ' 30:36 ' 30:48  31:00  31:12  31:24  31:36  31:48  32:00  32:12  32:24  32:36  32:48  33:00  33:12    Time
353.8970 S:5 F:2 SMO(1,3) BSUB(128,15,-3.0) PKD(3,3,3,0.10%,1424.0,1.00%,F,F)
100%.                                                           A1.3.9E5         A1.47E5
  O
 O.OEO
     30112 ' 30:24 ' 30:36 ' 30:48 '  31:66 ' 31:12  31:24 ' 31:36 ' 31:48 '  32:66  32112 ' 32124 ' 32:36 ' 32S48 ' 33:66 ' 33112    Time
409.7974 S:5 F:2 SMO(1,3) BSUB(128,15,-3.0) PKD(3,3,3,100.00%,4112.0,1.00%,F,F)
100i,                         30:54         31.19                 31.58
     I  I\j»         "^ f\ *» M        I \
 50.
                                                                                                                    OEO
     30.:12  30:24 ' 3C)!36 ' 3o!48 '  31166 ' 3l!l2  31:24  31i36  31:48  32:00  32:12  32:24  32:36  32:48  33:00  33:12    Time
366.
100%
50 1
o:
9792 S:5
, 30:
F:
20
2 SMO(1,3)
30:30
PKD(3,3,3
31:
,100.
00 31
00%,
:11
0.0,1.00%,F,F)
31:44 32:11 32:25 32:44 33:05 ft

i.4
0
.4E7
.2E7
.OEO

-------
File: A17JUL98B  Acq: 17-JUL-1998  19:46:16  Exp: EXP_M23_DB5_OVATION Voltage SIR El-t-  GC Autospec-UltimaE  Paradigin
Sample #5  Text: SB  ALS  #3
373.8207 S:5 F:3 SMO(1,3) BSUB{128,15,-3.0) PKD(3,5,2,0.10%,1576.0,1.00%,F,F)
100*

 50 j

  ol
                                          A3.94E4
          A1.09E4    A1.26E4
                                                          A3.72E4
                                                                  A4.76E4
                                                 J34.79
                                                                                                             1.5E4

                                                                                                            L7.4E3
                                                                                           A7.22E3
                                                                                       JV816.23,
                                                                                                                  .O.OEO
      T '[—r—'i—i—FT—i—i—i—i—i—i—|—i—i—r—i—i—[—i—i—i—T—r—i—i—i—i—i—i—I—i—i—i—i—i—I—i—i—i—i—i—I—i—r3^—r—i—I—r—i—i—i—i—i—i—i—i—i—i—i—i—i—T—r—i—i—i—i—r—i—r
      33:24    33:36    33:48    34:00    34:12    34:24    34:36    34:48    35:00    35:12    35:24    35:36   35:48  Time
375.8178 S:5 F:3 SMO(1,3) BSUB(128,15,-3.0) PKD(3,5,2,0.10%,1096.0,1.00%,F,F)
                                                          A2.60E4


                                                   A5.51E3 /  \   A4.36E3
      33:24    33 36    33:48    34:00    34112    34:24    34:36    34:48    35:00    35:12    35:24    35:36   35:48  Time
383.8639 S:5 F:3 BSUB(128,15,-3.0) PKD(3,5,2,0.10%,7684.0,1.00%,F,F)
100*                                     A1.19E5.
 50^

  ol
                                                                                                   A5.77E3
     r—i—r—T—i—i—i—i—r—i—i—i—1—1—i i  i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—I—i—i—i—i—i I  i—i—m—i—r—i—r
      33:24   33:36    33:48    34:00    34:12    34:24    34J36    34:48
385.8610 S:5 F:3 BSUB(128,15,-3.0)  PKD(3,5,2,0.10%, 4980.0,1.00%,F,F)
100%                                  A1.52E5
                                                                           35:00
                                                                                      T"
                                                                                T

                                                                                                    5.9E4


                                                                                                    .3.0E4


                                                                                                    O.OEO
                                                                      35:12    35:24   35:36    35:48  Time

                                                                                                    7.3E4

                                                                                                   L3.7E4
              33 36    33:48    34:00   34:12    34:24    34:36    34:48    35:00    35:12    35:24    35:36    35:48  Time
                                                  34:25
445.7555 S:5 F:3 SMO(1,3) BSUB(128,15,-3.0) PKD{3,3,3,100.00%,1192.0,1.00%,F,F)
100*                                    34,-11
   :              33:41
 50J        33:^33
   : /**-~^*S
  OJ
                                                                35:04
                                                                                           35:22  35:31
                                                                                                        35:40
      33:24    33:36    33:48    34:00    34:12    34:24    34:36    34:48    35:00    35:12    35»24
                                                                                                             O.OEO
                                                                                                             ,8  Tin

                                                                                                            _4.1E3
                                                                                                               i
                                                                                                            J2. 1E3

                                                                                                             O.OEO
                                                                                                     35:36    35:48  Time
380.9760 S:5 F:3 SMO(1,3) PKD(3, 3, 3 , 100. 00%, 0. 0, 1 . 00%,F,F)
100*33:22   33:33            _ 34:03  34:13  34:22 34:30
 50j

  ol
                                                                  34:47   34:5735:04  35:13 _ .15:23
                                                                                          35:40
33:24
33:36    33:48
                                34:00
'34!12    34:24
                                                                                                            .1.7E8
                                                                                                                  .8.7E7


                                                                                                                  O.OEO
                                                          34:36
34:48    35:00    35:12    35:24    35:36    35:48  Time

-------
 File:  A17JUL98BAcq: 17-JUL-1998 19:46:16Exp: EXP_M23_DB5_OVATION Voltage  SIR EI+—GC Autospec-UltimaE—Paradigm	
 Sample #5   Text: SB  ALS #3
 407.7818 S:5 F:4 SMO(1,3) BSUB(128,15,-3.0) PKD(3,3,3,0.10%,1500.0,1.00%,F,F)
 100%.               A3.52E4                                                                                          1.1E4
                                I i i i i  i I i i i i i  I i i i i i I  i i i i i I i  i i i—i I i  i i i i I i  i i i i I i i  i i i [ i i  i i i I i i  i i i I	i
         36:00   36:12   36:24   36:36  36:48  37:00  37:12  37124  37:36  37^8  3s!oO   38:12   38:24   38:36  38:48  39:00
 409.7788  S:5  F:4 SMO(1,3)  BSUB(128,15,-3.0)  PKD(3,3,3,0.10%,1120.0,1.00%,F,F)
 100*               A3.50E4                                                                                          1
   50_

   OJ
A4.66E3
A1.85E4

      ..85E3
                                                                                                                     0.
        I  I I I I I I  I I I I I I  I I I I I I  I I I I	1 I I  I I I T I I I  I I I I I |  I I I I I I I  I I I I I	I I I  I I I I I I  I I I I I I  I I I | I I  I I I I	I I I I  I I I
        36:00  36:12  36:24  36:36  36:48  37:00  37:12  37:24  37:36  37:48   38:00   38:12   38:24   38:36  38:48   39:00
 417.8253  S:5 F:4 SMO(1,3)  BSUB(128,15,-3 . 0)  PKD(3,3,3,0.10%,2240.0,1.00%, F, F)
 100%,                                                       A2.58E4                                                _1


                                                                                                                   _6
        36:00  36:12  36:24  36:36  36:48  37:00  37:12  37:24  37:36  37:48  38:00  38:12  38:24  38^3 638:4839100
 419.8220 S:5  F:4  SMO{1,3)  BSUB(128,15,-3.0) PKD(3,3,3,0.10%,1624.0,1.00%,F,F)
 100%                                                       A6.17E4
  50j

   0.
                   A3.54E4
                                                                                    2.
                                                                                   Li.
                                                                                   Lo,
        i i  I i I I i IT i i i i  i I i i i i i  I i i i r i  [ i i i i i i  i i i r i I i  i i i i I i i  i i i I i i  i i i I i i  i i i I	i i i i  i i i i T r i i i i i i  i i i i i i  i i r
        36:00  36:12  36:24  36:36  36:48  37:00  37:12  37:24   37:36   37:48   38:00  38:12   38:24   38:36   38:48   39:00
 479.7165 S:5 F:4  SMO(1,3)  BSUB{128,15,-3.0)  PKD(3,3,3,100.00%,3984.0,1.00%, F,F)
 100%                                                     37;25
  50J

   OJ
        36:00
                                                                                                            38:52
                                                                                    1.
        36:00  36:12  36:24  36:36  36:48  37:00  37:12  37:24  37:36  37:48  38:00   38:12   38:24   38:36   38:48   39:00
 430.9728 S:5 F:4 SMO(1,3)  PKD(3,3,3,100.00%,0.0,1.00%,F,F)
 100*.  	25ill	36:36	37:04     37:20  37:32
  5»r*ir"T'VaT"T"l ~\
        36:00  36:12  36:24  36:36  36:48  37:00  37:12  37124   37-36   37:48   38:00  38:12   38:24   38:36   38:48   39:00
  Time

 1E4

 4E3

 OEO
  Time

.2E4

.OE3

.OEO
  Time

.1E4

.1E4

.OEO
  Time

.1E4

.4E3

.OEO
  Time

.1E8

.7E7

.OEO
  Time
10

-------
File: Al7jtFt98BAcq:  17-JUL-1998  19:46:16Exp: EXP_M23_DB5_OVATION Voltage  SIR  EI +GC Autospec-UltimaE—Paradigm	
Sample #5  Text: SB  ALS  #3
441.7427 S:5 F:5 SMO(1,3) BSUB(128,15,-3.0) PKD(3,3,3,0.10%,868.0 ,1.00%,F,F)
100$                                                           A1.38E4                                           _6.1E3
           39:12       39:24      39:36      39:48      40:00      40:12      40:24
443.7398 S:5 F:5 SMO(1,3)  BSUB(128,15,-3.0) PKD(3,3,3,0.10%,1944.0,1.00%,F,F)
100$                                                            40;10
                             39:32
                                                                                   40:36
                                                                                                     —r—i—ri-" i
                                                                                                   40:48
 50J
39:06
                                                                                                                  O.OEO
          39:12       39:24      39:36      39:48       40:00       40:12      40:24
469.7780 S:5 F:5 SMO(1,3)  BSUB(128,15,-3.0) PKD(3,3,3,0.10%,2744.0,1.00%,F,F)
100%                                                    A4.^8E4
 50J
                                                                                   40:36
                                                                                                   40:48
  OJ
                                                                   41:00 Time

                                                                      1.8E4

                                                                      .8.9E3
                                                                  62E3
                                                                                                             O.OEO
           39:12       39:24      39:36      39:48       40:00       40:12      40:24      40:36      40:48
471.7750 S:5 F:5 SMO(1,3)  BSUB(128,15,-3.0) PKD(3,3 , 3 , 0.10%, 1468.0,1.00%,F,F)
100%                                                   A7.08E4

 50 J

  OJ
                                                                .44E3
          39112       39124       39:36      39148       40100       40:12       40124      40:36      40:48
513.6775 S:5 F:5 SMO(1,3) BSUB{128,15,-3.0) PKD(3,3,3,100.00%,112.0,1.00%,F,F)
100$                                      39;47
    39:05
                                                          40:03
                                                                                                         41:00  Time

                                                                                                             2. OE4

                                                                                                            19.9E3

                                                                                                            .O.OEO
                                                                                                         41:00  Time
                                                                                                                 _2.2E3
                                                                  40:12
       T—i  ii—i—r—i—i	1—i—i™—i—i—i—i—i—i—i—i—i	1—I—i—i—i—r
          39:12       39:24       39:36       39:48       40100
454.9728 S:5 F:5 SMO(1,3) PKD(3,3,3,100.00%,0.0,1.00%, F,F)
100$ _   39:10	39:23    39:32     39.-42       39:5440:00 40:06  40:13
 SO-
                                                                        40:24      40i36

                                                                        40:24    40:34
                                                                                                   40:48

                                                                                                 40:45
                                                                      .O.OEO
                                                                   41:00  Time
                                                                                                                 .1.3E8
                                                                                                            .6.3E7
                                                                                                                  O.OEO
          39:12
                39:24
                                 39:36
39:48
                                                       40:00
40:12
40:24
40:36
40:48
41:00  Time

-------
OPUSqu
           21-JUL-1998
                                      Page 1
                                                                                                            Page 1 of 2
   Run #6   Filename a20ju!98b        S: 2   I:  1  Acquired:  20-JUL-98 22:01:21 Processed:  21-JUL-98 13:34:23
   Run: 0716crv    Analyte: m8290-23-» Cal:  m8290-23-» Results:               Quan :  V3.5 17-APR-1997 11:14:34
   Sample text: FE CS3                     Comments:                 /        OPUS :  A3.6/8X 18-MAR-1998 16:12:42
        Typ
                                  Name
Resp
                                                            RA
                                                                       RT
                                                                                Cone
                                                                                        Dev'
                                                          Mod?





I

































"V
-•s
(v)
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
ES/RT
ES
ES
ES
ES
ES/RT
ES
ES
ES
JS
JS
CS
CS
CS
CS
CS

SS
SS
SS
SS
SS
DPE
DPE

2,3,7,8-TCDD
1,2,3,7,8-PeCDD
1,2,3,4,7,8-rixCDD
1,2,3, 6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
1,2,3,4,6,7,8-HpCDD
OCDD
2,3,7,8-TCDF
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
1,2,3,4,6,7,8-HpCDF
1,2,3,4,7,8, 9-HpCDF
OCDF
13C-2,3,7,8-TCDD
13C-l,2,3,7,8-PeCDD
13C-l,2,3,6,7,8-HxCDD
13C-l,2,3,4,6,7,8-HpCDD
13C-OCDD
13C-2,3,7,8-TCDF
13C-l,2,3,7,8-PeCDF
13C-l,2,3,6,7,8-HxCDF
13C-l,2,3,4,6,7,8-HpCDF
13C-1,2,3,4-TCDD
13C-l,2,3,7,8,9-HxCDD
37Cl-2,3,7,8-TCDD
13C-2,3,4,7,8-PeCDF
13C-1 , 2,3,4,7, 8-HxCDD
13C-l,2,3,4,7,8-HxCDF
13C-l,2,3,4,7,8,9-HpCDF

37Cl-2,3,7,8-TCDD
13C-2,3,4,7,8-PeCDF
13C-l,2,3,4,7,8-HxCDD
13C-l,2,3,4,7,8-HxCDF
13C-1 , 2,3,4,7,8, 9-HpCDF
HxCDPE
HpCDPE

2.2e+07
7.2e+07
5. Oe+07
7.6e+07
7.2e+07
5.9e+07
1. Oe+08
2.5e+07
8.9e+07
9.2e+07
7.9e+07
1. Oe+08
8.7e+07
7.7e+07
7.6e+07
6.5e+07
1. le+08
4.4e+08
2.7e+08
3.2e+08
2.6e+08
4.1e+08
5.4e+08
4.16+08
3.56+08
2.5e+08
4.0e+08
3.2e+08
2.1e+07
9.96+07
5.26+07
7.0e+07
5. Oe+07

2.1e+07
9.9e+07
5.2e+07
7.0e+07
5. Oe+07
*
*

0
1
1
1
1
1
0
0
1
1
1
1
1
1
I
1
0
0
1
1
1
0
0
1
0
0
0
1
1
1
0
0

1
1
0
0





.78
.54
.21
.25
.25
.03
.90
.77
.52
.53
.38
.13
.24
.26
.03
.01
.89
.78
.54
.25
.03
.90
.78
.55
.52
.44
.79
.24
.56
.24
.52
.46

.56
.24
.52
.46





y
y
y
y
y
y
y
y
y
y
y
y
y
y
y
y
y
y
y
y
y
y
y
y
y
y
y
y
y
y
y
y

y
y
y
y





28:27
32:37
34:42
34:46
34:59
37:10
40:01
27:26
31:57
32:24
34:10
34:14
34:37
35:08
36:21
37:31
40:09
28:25
32:36
34:45
37:09
40:00
27:24
31:56
34:14
36:21
28:08
34:58
28:26
32:23
34:42
34:10
37:30

28:26
32:23
34:42
34 : 10
37:30
NotFnd
NotFnd

4.93
24.3
24.7
27.2
26.4
24.9
49.5
4.87
24.9
25.1
26.7
26.4
26.7
26.9
24.6
25.3
49.4
100
86.3
92.0
104
202
97.4
84.4
88.1
102
83.6
80.6
5.12
20.9
23.0
22.8
26.6

5.11
24.8
25.0
25.7
26.0
*
*

-1
-2
_i
8
5
-0
-0
-2
-0
0
6
5
6
7
-1
1
-1
0
-13
-8
3
0
-2
-15
-11
2


2
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-8
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.5
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-
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.1
.9
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n
n
f n
_ n
/I n
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n
n
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n
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n
n
n
n
n
n
n
n
n
n
n

n
n
n
n
n
n
n


-------
File: A20JUL98B Acq: 20-JUL-1998
Sample #2 Text: FE CS3 ALS #2
319.8965 S:2 SMO(1,
100%
50:
o-



24
321.8936 S:2 SMO(1,
100%
50:
OJ



24
331.9368 S:2 SMO(1,
100%
50:
o:



24
333.9339 S:2 SMO(1,
100%
50:
o:



24
327.8847 S:2 SMO(1,
100%
50:
o"



24
316.9824 S:2 SMO(1,
100% 23:28
50:
0



24
3) BSUB(128,15,



100 25
3) BSUB(128,15,



100 25
3) BSUB(128,15,



100 25
3) BSUB(128,15,



T 	 1 	 1 	 1 	 1 	 1 	
100 25
3) BSUB(128,15,



loo' ' ' ' 25
22:01:21 Exp: EXP_M23_DB5
-3.0) PKD(3,3,3,



100 26 1
-3.0) PKD(3,3,3,



loo 2e!
-3.0) PKD(3,3,3,



loo 2e!
-3.0) PKD(3,3,3,



loo' ' ' 26 1
-3.0) PKD(3,3,3,



100 	 26!
0.10%, 1616



00
0.10%, 1368



00
0.10%, 7396



00
0.10%, 3996



00
0.10%, 5588



00
_OVATION
.0,1.00%



27100
.0,1.00%



27IOO
.0,1.00%



27100
.0,1.00%



i r— | r
27:00
.0,1.00%



27 loo'
Voltage SIR EI+ GC Autospec-UltimaE Paradigm
,F,F)
A9.46E6
A
A
i\
1.
_9.
• n
	 1 	 1 	 1 	 1 	 1 	 1 	 f 	 r1"— i 	 1 	 1 	 1 	 1 	 1 	 , 	 1 	 ,-*-« •
28:00 29:00 30:00
,F,F)
A1.21E7 2.
A
i\
Li.
• n
	 1 	 1 	 1 	 1 	 1 	 r—f 	 H*-T 	 1 	 r — i 	 1 	 1 	 1 	 1 	 r--- •
28:00 29:00 30.-00
,F,F)
A1.94E8
A A
A
. / V
3.
.1.
• o.
28:00 29:00 30:00
,F,F)
A2.50E8
A A
A
i\
5.
2"
0.
...... ~-i ..,,111111
28:00 29:00 30:00
,F,F)
A2.08E7
A
i \.
4.
.2.
0.
28 loo' ' 29 1 00 	 30 I 00


8E6
2E5
OFO
\J Ct\J
Time

4E6
2E6
OEO
Time

9E7
9E7
OEO
Time

OE7
5E7
OEO
Time

1E6
1E6
OEO
Time
3) PKD(3,3,3,100.00%,0.0,1.00%,F,F)
24:23 24:45


I 	 1 	 1 	 1 	 1 	 1
:00 25
25:26 26


T 	 1 	 1 i i i r
100 26l
i03 26:24



00
26:50


i i i r
27:00
27:2227:442fl:0728:3.| 29:0529:26 29:51 fl.


14.
•o

28:00 29:00 30:00
1E7
1E7
OEO
Time
00
o

-------
File
SamE
355.
1003
50.
357.
100S
50J
0"
367.
100%
so:
0'
369.
100%
so:
366.
100%
so:
""> OJ
**•.
V)
yt
(J
A
s: A20JUL98B Acq: 20-JUL-1998 22:01:21 Exp: EXP M23 DB5 OVATION Voltage SIR EI+ GC Autospec-UltimaE Parad
>le #2 Text: FE CS3 ALS #2
8546 S:2 F:2 SMO(1,3) BSUB(128, 15, -3 . 0) PKD(3 , 3 , 3 , 0 . 10%, 2496 . 0, 1 . 00%, F, F)
A4 . 3 8E7
/\
30:12 30:24 30:36 30:48 31:00 31:12 31:24 31:36 31:48 32^00 32:12 32:24 32:36 32:48 33:00 33:12
8517 S:2 F:2 SMO ( 1 , 3 ) BSUB(128, 15, -3 . 0) PKD(3 , 3 , 3 , 0 . 10%, 1052 . 0 , 1 . 00%, F, F)
A2.85E7
A

30:12 30:24 30:36 30:48 31:00 31:12 31:24 31:36 31:48 32:00 32:12 32:24 32136 32:48 33:00 33:12
8949 S:2 F:2 SMO(1,3) BSUB(128, 15, -3 . 0) PKD(3,3, 3 , 0 . 10%,3124 . 0, 1 . 00%,F,F)
A1.61E8
/I
30:12 30:24 30:36 30:48 31:00 31:12 31:24 31:36 31:48 32iOO 32:12 32:24 32:36 32:48 33:00 33:12
8919 S:2 F:2 SMO(1,3) BSUB{128, 15, -3 . 0) PKD(3 , 3 , 3 , 0 . 10%, 1536 . 0 , 1 . 00% , F, F)
A1.05E8
A
H
3b!i2 30:24 36136 SoUs 3i!66 31:12 3ll24: 31\36 3ll^8 32J66 32!i2 32124 32136 32148 33:66 33!i2
9792 S:2 F:2 SMO(1,3) PKD(3 , 3, 3 , 100 . 00%, 0 . 0, 1 . 00%, F, F)
30:25 30:38 30:57 31:09 31:21 31:3631:4631:56 32:12 32:24 32:37 32:50 33:04

30:12 30:24 30:36 30:48 31:00 31:12 31:24 31:36 31:48 32:00 32:12 32:24 32:36 32:48 33:00 33:12


igm
1.5E7
_7.7E6
o . OEO
Time
9.9E6
.4.9E6
o .OEO
Time
5.8E7
.2 . 9E7
_O.OEO
Time
_3.8E7
_O.OEO
Time
_7.9E7
_3.9E7
O.OEO
Time



-------
File
Samp
389.
100%,
50J
0"
391.
100%
50J
0'
401.
100%
so:
(V
403.
100%
so:
0'
380.
100*
50 1
0"
: A20JOL98B Acq: 20-JUL-1998 22:01:21 Exp: EXP_M23_DB5_6VAT
le #2 Text: FE CS3 ALS #2
8156 S:2 F:3 SMO(1,3) BSUB(128, 15, -3 .0) PKD(3, 5, 2, 0 . 10%, 2132 .
A4
l\
33J24 33:36 33Us 34^00 34ll2 34124 34136
8127 S:2 F:3 SMO(1,3) BSUB (128, 15, -3 . 0) PKD(3 , 5, 2 , 0 . 10%, 3224 . (
A3
l\
ION Voltage SIR EI+ GC Autospec-UltimaE Parad
D,1.00%,F,F)
.22E7 A4.01E7
34-148 35100 35!l2 3sl24 3s!36 35
D,1.00%,F,F)
•?7E7 A3.22E7
lU
33:24 33:36 33J48 34!oO 34ll2 34124 34136 34148 3s!oO 3s!l2 35I24 3s!36 35
8559 S:2 F:3 BSUB(128, 15, -3 . 0) PKD(3 , 5, 2 , 0 . 10% , 12000 . 0 , 1 . 00%, F, F)
A1.76E8 A1-77E8
33:24 33:36 33:48 34:00 34ll2 34124 34-136 34U's 3s!oO 35[l2 3sl24 35136 35:
8530 S:2 F:3 BSUB(128, 15, -3 .0) PKD(3 , 5, 2, 0 .10%, 7596 .0, 1 . 00%,F,F)
Al'flE8 A1.43E8
33:24 33:36 33!48 34:00 34!l2 34:24 34!36
9760 S:2 F:3 SMO(1,3) PKD(3 , 3 , 3, 100 . 00%, 0. 0, 1 . 00%,F,F)
33:22 33:4833:55 34:14

> 33:24 33:36 33:48 34:00 34:12 34:24 34:36
igm
1.2E7
L6.0E6
LO.OEO
48 Time
9.6E6
L4.8E6
O.OEO
48 Time
7.1E7
13 . 6E7
_O.OEO
48 Time
_5.7E7
.2 . 8E7
.O.OEO
34:48 35:00 35:12 35l24 35:36 35:48 Time
34:54 35:12 35:36 1 fiRft

L8.2E7
10.0EO
34:48 35:00 35:12 35:24 35:36 35:48 Time
s

-------
File
Samp
423.
100%
50J
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425.
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so:
0"
435.
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50J
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437.
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430.
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->*t
: A20JUL98B Acq: 20-JUL-1998 22:01:
le #2 Text: FE CS3 ALS #2
7767 S:2 F:4 SMO(1,3) BSUB(128, 15, -3

36:66 36!l2 36524 belie 36! 48
7737 S:2 F:4 SMO(1,3) BSUB (128, 15 , -3

36566 365l2 36524 36:36 36Us
8169 S:2 F:4 SMO(1,3) BSUB (128, 15, -3

I i i i 1 i i i i i i i i i i i 1 i i i I 'T 1 i i i i r -pi i-
36:00 36:12 36:24 36:36 36:48
8140 S:2 F:4 SMO(1,3) BSUB(128, 15, -3

36:66 36512 36524 36536 36548
9728 S:2 F:4 SMO(1,3) PKD(3 , 3, 3 , 100 .
36_i24 36:33 36:49
/"
36566 36:12 36524 36:36 36548
21 Exp: EXP_M23_DB5_OVATION Voltage SIR EI+ GC Autospec-UltimaE Paradigm
.0) PKD(3,3,3,0.10%,2004.0,1.00%,F,F)
A2.99E7 ^7.9E6
A F
/v
3?!66 37!l2 37!24 37!36 37! 48 3s!66 38! 12 3s!24 38!36 38!48 39
.0) PKD (3 , 3,3,0.10%, 1444 . 0 , 1 . 00% , F, F)
A2.91E7
A
/I
37I66 37!i2 37!24 37136 37!48 38!66 38ll2 38!24 38!36 38!48 39?
.0) PKD{3, 3, 3, 0.10%, 9024. 0,1.00%,F,F)
A1.34E8
A

37:00 37:12 37:24 37:36 37:48 38:00 38:12 38:24 38:36 38:48 39
.0) PKD(3,3,3,0.10%,2268.0,1.00%,F,F)
A1.30E8
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_4.0E6
O.OEO
00 Time
7.7E6
L3.9E6
' O.OEO
00 Time
3.5E7
.1.8E7
O.OEO
00 Time
3.4E7
L1.7E7
.O.OEO
37!66 37!i2 37524 37!36 37548 38566 38!l2 38!24 38536 38548 39 00 Time
00%, 0.0,1. 00%, F,F)
37:01 37:18 37:29 37=42 38:07 38:23 38:52 1 . 1E8

15.6E7
.O.OEO
37566 37!l2 37!24 37536 37548 3s!6o 38:12 38524 38!36 38U8 39 00 Time
00

-------
File
Samp
457.
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50J
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459.
100%
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469.
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471.
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so:
: A20JUL98B Acq: 20-JUL-199« 22:01:21 Exp: EXP_M23_DB5_OVATION Voltage SlR EH- <5C Autospec-UltimaE Parad
le #2 Text: FE CS3 ALS #2
7377 S:2 F:5 SMO(1,3) BSUB (128, 15, -3 . 0) PKD(3, 3 , 3 , 0 . 10%, 1584 . 0, 1 . 00%, F, F)
A4.85E7
j\_
39:12 39:24 39:36 39:48 40:00 40:12 40:24 40:36 40:48 41:
7348 S:2 F:5 SMO(1,3) BSUB(128, 15, -3 . 0) PKD(3 , 3 , 3 , 0 . 10% , 1020 . 0, 1 . 00%, F, F)
A5 . 41E7
f\_
39:12 39:24 39:36 39:48 40:00 40:12 40:24 40:36 40:48 41:
7780 S:2 F:5 SMO(1,3) BSUB (128, 15, -3 . 0) PKD(3, 3 , 3 , 0 . 10%, 1864 . 0, 1 . 00%, F, F)
Al . 95E8
J\_
39:12 39:24 39:36 39:48 40:00 40:12 40:24 40:36 40:48 41:
7750 S:2 F:5 SMO(1.3) BSUB(128, 15, -3 . 0) PKD(3, 3 , 3 , 0 . 10%, 1716 . 0, 1 .00%,F,F)
A2 . 18E8
J\_
39:12 39:24 39:36 39:48 40:00 40:12 40:24 40:36 40:48 41:
9728 S:2 F:5 SMO(1,3) PKD(3, 3, 3, 100. 00%, 0. 0, 1 . 00%, F, F)
39:10 39:26 39:41 39:55 40:03 40:16 40:2640:31 40.42 40:49

igm
1.1E7
L5.3E6
O.OEO
00 Time
1.2E7
.6.0E6
-O.OEO
00 Time
4.3E7
.2 . 1E7
.O.OEO
00 Time
4 . 8E7
L2 . 4E7
10 . OEO
00 Time
1.2E8
16.iE7
' O.OEO
-s 39:12 39:24 39:36 39:48 40:00 40:12 40:24 40:36 40:48 41:00 Time

-------
File: A20JUL98B Acq:
20-JUL-1998 22:01:21 Exp: EXP_M23_DB5_OVATION Voltage SIR EI + GC Autospec-UltimaE Paradigm
Sample #2 Text: FE CS3 ALS #2
303.9016 S:2 SMO(1,3)
1001
50 1
o-



24 loo
305.8987 S:2 SMO(1,3)
100S
50J
oj



24100
315.9419 S:2 SMO(1,3)
lOOi
50J
o:




24:00
317.9389 S:2 SMO(1,3)
100%
50 j
oj



24 100
375.8364 S:2 SMO(1,3)
100%
•
50 j
o:

23:28 23:51
_. N llrt M I\ »» nJ^
V\A/W uwK/ Y/^X/
24 100
316.9824 S:2 SMO(1,3)
100* 23:28
50J
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11 24:00
BSUB (128, 15, -3.0) PKD (3 , 3 , 3 , 0 . 10%, 1532 . 0 , 1 . 00%, F, F)
A1.09E7
A
y V
2.2E6
L1.1E6
O.OEO
25:00 26:00 27:00 28:00 29:00 30:00 Time
BSUB (128, 15, -3.0) PKD (3 , 3 , 3 , 0 . 10% , 2712 . 0, 1 . 00% , F, F)
A1.41E7
A
/ \^
2.9E6
_1.4E6
n riEn
25:00 26:00 27:00 28:00 29:00 30:00 Time
BSUB (128, 15, -3.0) PKD (3 , 3 , 3 , 0 . 10%, 3564 . 0, 1 . 00%, F, F)
A2.37E8
A
f[


4.9E7
.2 . 5E7
O.OEO
25:00 26:00 27:00 28:00 29100 30:00 Time
BSUB (128, 15, -3.0) PKD(3, 3, 3, 0.10%, 5324 . 0, 1 . 00%, F,F)
A3.03E8
A
A
/\
6.3E7
.3.2E7
O.OEO
25:00 26:00 27loO 28100 29:00 30:00 Time
BSUB (128, 15, -3.0) PKD (3 , 3 , 3 , 100 . 00%, 1404 . 0, 1 . 00%, F,F)
_o n(28:25 _9.7E3
28:08 A
26:43 A 11
M£WMA01-nm 25A!5 ».»aJl nn27(i^27A44 /l/L Juv^yxV


L4.9E3
_O.OEO
25100 26loO 27100 2sloO 29:00 30:00 Time
PKD (3, 3, 3, 100. 00%, 0.0,1. 00%, F.F)
24:2324:45 25:26 26:0326:24 26:50 27i22 27 : 44 28 : 07 28 :31 29:0529:26 29:51 8 . 1E7


L4.1E7
O.OEO

25:00 26:00 27:00 28:00 29:00 30:00 Time
00

-------
Pile: A20JUL98B Acq: 20-JUL-1998 22:01:21 Exp:
Sample #2
339.8597 S:
100%
50J
OJ



3b!i2
341.8568 S:
100%
50J
ol



30:12
351.9000 S:
100%
50J
-
o:




u 'i i i 1 i i
30ll2
353.8970 S:
100%
sol
-
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" 'l 1 1 1 1 1
30ll2
409.7974 S:
100%
-
SO-
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30:13
s\
^^/^-v
30:12
366.9792 S:
100%
50J
o"


"-iiijii
^ 30:12
EXP_M23_DB5_OVATION Voltage SIR EI+ GC Autospec-UltimaE Paradigm
Text: FE CS3 ALS #2
2 F:



301
2 F:



3o!
2 F:




'bb!
2 F:




i i' i |
30:
2 F:


30
s\
^W
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301
2 F:
30


r i i I
30:
2 SMO{1,3)



24 3ol36
2 SMO(1,3)



24 bblie
2 SMO(1,3)




i i i i i i i i i
24 30:36
2 SMO(1,3)




i i i i i i i i i
24 30:36
2 SMO(1,3)

30:31
:2sA /A^1
/\2/sl_/\ / \


_6.
0.
32:24 32:36 '32:48 33:66 33ll2

32:24 32:37 32:50 33:04 7.


.3.
0.
' 32:24 ' 32136 32:48 33166 33112

OE7
9E6
OEO
Time

3E7
5E6
OEO
Time

5E7
2E7

OEO
Time

5E7
7E7

OEO
Time

2E4

1E3
OEO
Time

9E7
9E7
OEO
Time
00

-------
  ?lle:  A20JUL98B  Acq: 20-JUL-1998  22:01:21   Exp:  EXP_M23_DB5_6VATl6N Voltage SIR EH-—GC Autospec-UltimaE—Paradigm	
  Sample #2  Text: FE CS3  ALS  #2
  373.8207 S:2 F:3 SMO(1,3) BSUB(128,15,-3.0)  PKD(3,5,2,0.10%,6016.0,1.00%,F,F)
  1004                                      A5.36E7          »„ 0>lt:,-,                                                  1.7E7
-
50 1
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33T24 33
375.8178 S:2 F:3



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SMO ( 1 ,



33 1 48 '


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34:00
3) BSUB(128,15,-3
AA
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34:12 34:24
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A4

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34:48
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7—1 	 TT 	 1 	 1 	 1 1 1 1 1 1 1 1 1 1 1 	 1 	 1— 1 	 1 	 1 	 1 	 1 	 H 	 • 	
:00 35:12 35:24 35:36 35:48 Time

100*

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                                           A4.73E7
                                                            A3.90E7
                                                                                   A3.39E7
      33:24    33:36    33:48   34:00    34il2    34i24    34i36
383.8639 S:2 F:3 BSUB(128,15,-3.0)  PKD(3,5,2,0.10%,28556.0,1.00%,F,
100%                                     A1.19E8
                                                                              35100    35-!l2    35124   35:36
                                                        1.4E7

                                                       _7.0E6

                                                        0.
                                                                                                                       .OEO
                                                          Time

                                                      „*.. 9E7
A
/\ \ A2.31E7
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33:24 33:36 33:48 34:00 34:12 34:24 34:36 34:48 35:00 35:12 35:24 35:36 35:
_2 . 4E7

O.OEO

48 Time
 385.8610  S:2  F:3  BSUB(128,15,-3.0) PKD(3,5,2,0.10%,52228.0,1.00%,F,1
 lOOi                                     A2.30E8
 50J

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                                                       .4.8E7
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       33:24    33:36    33:48    34:00   34:12    34:24    34:36    34:48    35:00   '35:12' '  '35:2'4' '  '35:36' '  '35:48  Time
 445.7555 S:2  F:3  SMO(1,3)  BSUB{128,15,-3.0) PKD(3,3,3,100.00%,1204.0,1.00%,F,F)
 100%,                                                              34^45    34:58                                   ,.9.1E3
  50-

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       33:24    33:36    33:48    34:
                                        '34 112'  ' '34124'
                                                                                                                   .4.8E3

                                                                                                                    O.OEO
 380.9760 S:2 F:3  SMO(1,3)  PKD(3,3,3,100.00%, 0.0,1.00%,F, F)
 100S. 33i22	33;4833;55	34:14	
~i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i i  i—i—i—i—i—i—i—f
1.-36    34:48    35:00    35:12    35:24    35136    35148 Time
  50
                                                                   ^4:49
                        _15_il2_
.15:36
      '33:2'4'  ' '3313V  ' 's'sUV '  '34:00'
                                          iSlV '  '34!2'4' '  '34\36' '  '34UV '  's'slo'o' ' VsllV  ' '35S24'  ' VslsV
.1.6E8
                                                                                                                    .8.2E7
                                                                                                                     O.OEO
                                                                                                                 35:48  Time
to
00

-------
Pile: A20JUL98B
Sample #2 Text:
407.7818 S:2 F:4
100%
-
50J
o:




36:00 36:
409.7788 S:2 F:4
100%
;
50J
o:



36:00 36:
417.8253 S:2 F:4
lOOi
50J
-
0 "




36:66 36l
419.8220 S:2 F:4
100%
50:

0-




36:00 36:
479.7165 S:2 F:4
100%
:
50J
0:
36-04
V AxV^V3
v~y V/ V^Vj
36166 36l
430.9728 S:2 F:4
100%

^ °-:
/

36loO 36:
Acq: 20-JOL-1998 22:01:
FE CS3 ALS #2
SMO(1,3) BSUB(128,15,-3
A3 . 88E7
A
/\
/ v_

12 36:24 36:36 36:48
SMO(1,3) BSUB{128,15,-3
A3.75E7
A
/\
/ V
12 36:24 36:36 36:48
SMO(1,3) BSUB(128,15,-3
A7 . 54E7
A
A
/ \
/ v_
12 36:24 36136 36148
SMO(1,3) BSUB{128,15,-3
A1.70E8
A
A
/ \
/ v_
12 36124 36136 36148
SMO(1,3) BSUB(128,15,-3

36:21 36:33 36:5

r\j \J V NT\/
12 36124 36136 36148
21

.0)





37
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37
.0)




37
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37
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1
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37
Exp: EXP_M23_DB5_OVATION Voltage SlR EH- GC Autospec-UltimaE Paradigm 	

PKD(3,3,3,0.10%,4488.0,

A3.24E7
7V_


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PKD (3,3,3,0. 10% , 11028 . 0

A3.22E7
A
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:00 37:12 37:24 37:36
PKD (3, 3, 3, 0.10%, 28536.0


Al . 57E7
y\^
166 37l 12 37! 24 37:36
PKD(3, 3, 3, 0.10%, 10456.0


A3.44E7
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166 37112 37124 37:36
PKD(3,3,3,100.00%,3600.
37:09


1.00%,F,F)
^1.1E7



•
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O.OEO

37:48 38:00 38:12 38:24 38:36 38:48 39 00 Time
,1.00%,F,F)
^1.1E7




L5.3E6
_O.OEO
37:48 38:00 38:12 38:24 38:36 3sl48 39loO Time
,1.00%,F,F)




2.2E7
.1.1E7

.O.OEO
'37148 38166 ' 38:12 38:24 ' 38:36 ' 38:48 ' 39:00 Time
,1.00%,F,F)




5 . OE7
_2 . 5E7

.O.OEO
37l 48 38166 38:12 38:24 38:36 38l48 39loO Time
0,1.00%,F,F)
9.3E3
37:51 38:14 38;38 /
/ \ 37:27 37:42 A _ ^ 38.29 n 38:53/
-A / v /~\ 1 \ r*\ -/ \ A- O o J U /^/ \ yvVS / \ / \__ x-v/"*\ /
~^\} ^-t V"W \r^\jT
166 37ll2 37124 37136
\s*s \j \_s ~\f v x_y^ \s ^ ^ * —

.4.7E3
LO.OEO
37 148 38166 38ll2 38:24 38:36 38:48 39:00 Time
SMO(1.3) PKD(3,3,3,100.00%.0.0,1.00%,F,F)
36:24 36:33 36:44 36i


12 36124 36136 36148
54


37
37:18 37:29 37


166 37l 12 37124 37136
.-42 38:07 }8.. 23 38:52 ] . IRfl


L5.6E7
.O.OEO
37148 38166 38ll2 38124 38136 38:48 39loO Time

-------
File: A20JUL98B
Sample #2 Text:
441.7427 S:2 F:5
100%
50 j
o:
443.
100S
501
o-
469.
100%
50J
o:
471.
1004
50 1
o:
513.
100%
sol
o:
454.
100%
50 1

39ll2
7398 S:2 F:5

39!l2
7780 S:2 F:5

39:12
7750 S:2 F:5

39!l2
6775 S:2 F:5
39:12
39:05 S\
	 — • 	 	 -S ^ — — '
39!l2
9728 S:2 F:5
39:10

^ 39! 12
Acq: 20-JUL-1998 22:01:21 Exp : EXP M23 DB5 OVATION Voltage SIR EI+ GC Autospec-UltimaE Paradigm
FE CS3 ALS #2
SMO(1,3) BSUB(128,15,-3.0y PKD(3 , 3 , 3 , 0 . 10%, 1012 . 0, 1 . 00%, F, F)
A5 -14E7 1 . 1E7
/Y_
• • ' i | i i i i i | i i i i i | i i i i i i i i *i i i i i i i i I i r • i T— r T — r— i — i— i — i — i — i — i — i — i — r—i 	
39:24 39:36 39:48 40:00 40:12 40:24 40:36 40:48 41
SMO(1,3) BSUB(128,15,-3.0) PKD(3 , 3 , 3 , 0 . 10%, 1964 . 0 , 1 . 00%, F, F)
«
i i i i | i i i i i 1 ' i i i i i i i i i i i i i "" i i i i i i i 1 1 i i i T" r — i i i i i — i — i — i — i — i — i i i i
39:24 39:36 39:48 40:00 40:12 40:24 40:36 40:48 41:
SMO(1,3) BSUB(128,15,-3.0) PKD(3 , 3 , 3 , 0 . 10%, 1864 . 0, 1 . 00%, F, F)
Al . 95E8
J\_
1 I 1 I I ' i ' I I | 	 | i i i fi p r -r- I-T T- | -r-l— I — I — I — i — i 	 1 — i — i — i — i 	 1 — i — i — i — i — i — i — i — i — , — , — J
39:24 39:36 39:48 40:00 40:12 40:24 40:36 40:48 41:
SMO(1,3) BSUB(128,15,-3.0) PKD(3 , 3 , 3 , 0 . 10%, 1716 .0, 1 . 00%, F, F)
A2 . 18E8
J\____
,..„ , 	 , _, — ^ 	 ,_,., — T — , — , 	 .. — , — r — r..1 	 r — | 	 , 	 , 	 1 < , 	 1 	 1 	 r— , 	 1 	 1 	 1 | | | i i i 	 1 	 1 	 1 	 1 	 1 	 1 	 1 	 1 	 1 	 1 	 1 	 .— , 	 , 	 , 	 , 	 , 	 J
39:24 39:36 39:48 40:00 40:12 40:24 40:36 40:48 41:
SMO(1,3) BSUB(128,15,-3.0) PKD{3 , 3 , 3 , 100 . 00%, 952 . 0 , 1 . 00%, F, F)
40:00
39:29 / \ 40-43
39:24 39:36 39:48 40:00 ' ' 40:12 40:24 40:36 ' 40:48 ' ' 41:
SMO(1,3) PKD(3,3,3,100.00%,0.0,1.00%,F,F)
39:26 39:41 39:55 40:03 40:16 40:2640:31 40:42 40:49

39124 39136 39148 4o!ob 4o!l2 ' ' 4o!24 ' ' ' 4o!36 ' ' ' 4'oUs 4lS
i.5.6E6
00 Time
1.3E7
_6.3E6
00 Time
4.3E7
L2.1E7
_O.OEO
00 Time
4 . 8E7
L2.4E7
LO.OEO
00 Time
1.1E4
L5.4E3
00 Time
1.2E8
_6.1E7
O.OEO
00 Time
05

-------
OPUSquan   21-JUL-1998
Page 1
                                                                                                            Page 2 of 2
   Run #7   Filename a20ju!98b        S: 17  I: 1  Acquired: 21-JUL-98 09:18:54 Processed: 21-JUL-98 13:34:28
   Run: 0716crv    Analyte: m8290-23-» Cal: m8290-23-» Results:              Quan :  V3.5 17-APR-1997 11:14:34
   Sample text: BE CS3                     Comments:                         OPUS :  A3.6/8X 18-MAR-1998 16:12:42
        Typ
                                  Name
            Resp
                                                            RA
                                                                       RT
                                                                                Cone
                                                                                        Dev'
Mod?
Unk
Unk
Unk
Unk
Unk
Unk '
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
ES/RT
ES
ES
ES
ES
ES/RT
ES
ES
ES
JS
JS
CS
CS
CS
CS
CS

SS
SS
SS
SS
SS
DPE
DPE
2,3,7,8-TCDD
1,2,3,7,8-PeCDD
1,2,3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
1,2,3,4,6,7,8-HpCDD
OCDD
2,3,7,8-TCDF
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
1,2,3,4,6,7, 8-HpCDF
1,2,3,4,7,8,9-HpCDF
OCDF
130-2,3, 7, 8-TCDD
13C-l,2,3,7,8-PeCDD
13C-l,2,3,6,7,8-HxCDD
13C-l,2,3,4,6,7,8-HpCDD
13C-OCDD
13C-2,3,7,8-TCDF
13C-l,2,3,7,8-PeCDF
13C-l,2,3,6,7,8-HxCDF
13C-l,2,3,4,6,7,8-HpCDF
13C-1,2,3,4-TCDD
13C-l,2,3,7,8,9-HxCDD
37Cl-2,3,7,8-TCDD
13C-2,3,4,7,8-PeCDF
13C-l,2,3,4,7,8-HxCDD
13C-l,2,3,4,7,8-HxCDF
13C-l,2,3,4,7,8,9-HpCDF

37Cl-2,3,7,8-TCDD
13C-2,3,4,7,8-PeCDF
13C-l,2,3,4,7,8-HxCDD
13C-l,2,3,4,7,8-HxCDF
13C-l,2,3,4,7,8,9-HpCDF
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8e+07
5e+07
6e+07
6e+07
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le+08
4e+08
7e+08
le+08
7e+08
le+08
2e+08
le+08
4e+08
5e+08
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le+08
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77
56
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55
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78
24
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23
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y
y
y
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28:27
32:37
34:42
34:46
34:59
37:10
40:01
27:26
31:57
32:24
34:11
34:15
34:37
35:08
36:21
37:31
40:10
28:26
32:37
34:45
37:09
40:01
27:24
31:56
34:14
36:21
28:09
34:58
28:27
32:24
34:41
34:10
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28:27
32:24
34:41
34:10
37:30
NotFnd
NotFnd
4.74
24.1
26.8
25.8
25.7
24.6
49.0
4.80
25.1
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27.1
26.8
27.1
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49.0
101
89.5
91.6
107
202
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86.0
103
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8
7
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-------
File: A20JUL98B Acq: 21-JUL-1998 09:18:54 Exp: EXP_M23_DB5_OVATION Voltage SIR EI+ GC Autospec-UltimaE Paradigm
Sample #17 Text: BE CS3 ALS #2
319.8965 S.-17 SMO{1,3) BSUB(128, 15, -3 . 0) PKD{3, 3, 3, 0 . 10%, 1196. 0, 1 . 00%, F,F)
100% A8.93E6 ,_1.8E6
l\
50 J
0:
24100 25:00 26loO
321.8936 S:17 SMO(1,3) BSUB(128, 15, -3 . 0) PKD(3,3,3,0.
lOOi
50 j
o- r
24 100 	 25 100 	 26 loo'
331.9368 S:17 SMO(1,3) BSUB{128, 15, -3 . 0) PKD(3,3,3,0.
100%
50^
n;
24 loo' ' ' ' 25-001 ' ' 26:00
333.9339 S:17 SMO(1,3) BSUB(128, 15, -3 .0) PKD(3,3,3,0.
100%
50J
0
24100 25100 26100
327.8847 S:17 SMO{1,3) BSUB(128, 15, -3 .0) PKD(3,3,3,0.
100%
50 j
0:
24100 25100 26100
316.9824 S:17 SMO(1,3) PKD(3, 3 , 3 , 100 .00%, 0 . 0, 1 . 00%, F,
100% 23:36 24jQ9 24:43 25:07 25:31 26:01
50J
24100 25:00 26:00
A
:9.1E5
LO.OEO
27loO 28100 29100 3oloO Time
10%, 1208. 0,1. 00%, F,F)
A1.16E7 2.4E6
l\
21:00 28-00 29loO 3ol(
10%, 6572. 0,1. 00%, F,F)
A1.92E8
A A
A
_1.2E6
O.OEO
)0 Time
4.0E7
.2 . OE7
.O.OEO
27 100 28 100 29 .-DO 30:00 Time
10%, 2444. 0,1. 00%, F,F)
A2.48E8 _5.1E7
A A
A
27:00 28100 29loO 3ol(
10%, 3272. 0,1. 00%, F.F)
A2.04E7
A
L2.6E7
•O.OEO
)0 Time
4.1E6
L2.1E6
LO.OEO
27 100 28 100 29 100 3oloO Time
F)
26:36 27:05 27:28 27L56 28:26 28:51 29^41 3.7E7

27:00 28:00 29:00 30:C
L1.9E7
; 0 . OEO
)0 Time

-------
File
Samp
355.
1003
so:
OJ
357.
100%
so:
0"
367.
100%
so:
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369.
100%
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366.
100%
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: A20JUL98B Acq: 21-JUL-1998 09:18:54 Exp: EXP_M23_DB5_OVATION Voltage SIR EI+ GC Autospec-UltimaE Parad
le #17 Text: BE CS3 ALS #2
8546 S:17 F:2 SMO{1,3) BSUB(128, 15 , -3 . 0) PKD(3 , 3 , 3 , 0 . 10%, 1484 . 0 , 1 . 00%, F, F)
A4.44E7
A
A
36112 36124 36136 boUs 31166 31:12 31:24 31136 31:48 32.'66 32112 32124 32136 32! 48 33166 33li2
8517 S:17 F:2 SMO{1,3) BSUB(128, 15, -3 . 0) PKD(3, 3, 3 , 0 . 10%, 836 . 0, 1 . 00%, F, F)
A2.88E7
f[
30:12 30:24 30136 30148 31:00 31:12 31:24 31:36 31:48 32:00 32:12 32:24 32:36 32:48 33:00 33:12
8949 S:17 F:2 SMO(1,3) BSUB(128, 15, -3 . 0) PKD(3 , 3 , 3 , 0 . 10%, 2752 . 0 , 1 . 00%, F, F)
A1.66E8
/L
30:12 30:24 30:36 30148 3ll66 31:12 31:24 31136 31 Us 32166 32112 32124 32136 32148 33166 33:12
8919 S:17 F:2 SMO(1,3) BSUB(128, 15, -3 . 0) PKD(3 , 3 , 3 , 0 . 10%, 812 .0 , 1 . 00%,F,F)
A1.07E8
/L
30:12 30:24' 36:36 36:48 31:66 31:12 31: 24 31136 31:48 32166 32:12 32124 32136 32:48 33:66 33:12
9792 S:17 F:2 SMO(1,3) PKD(3, 3,3, 100 .00%, 0 .0, 1 . 00%,F,F)
,30:12 30:32 30:45 31:07 31:22 31:38 31:50 32:02 32_j_13 	 32:33 32:59

boli^ 36124 36136 SOUS 3ll66 31:12 31124 3il36 31:48 32166 32112 32124 32136 32148 33166 33112
igm
1.6E7
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6.2E7
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_O.OEO
Time
3 . 9E7
L2.0E7
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Time
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-1.8E7
10.0EO
Time

-------
File
Samp
389.
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401.
100%
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380.
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: A20JUL98B Acq: 21-JUL-1998 09:18:54 Exp: EXP_M23_DB5_OVATION Voltage SIR EH- GC Autospec-UltimaE Parad
le #17 Text: BE CS3 ALS #2
8156 S:17 F:3 SMO(1.3) BSUB(128, 15, -3 . 0) PKD(3 , 5, 2, 0 . 10% , 1632 . 0 , 1 . 00%, F, F)
A3.96E7 A3.82E7
AM A
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33:24 33:36 33:48 34:00 34:12 34:24 34:36
8127 S:17 F:3 SMO(1,3) BSUBU28, 15, -3 . 0) PKD(3 , 5, 2 , 0 . 10%, 1536
A3
A
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34:48 35:00 35:12 35124 35136 35:
.0,1.00%,F,F)
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33:24 33:36 33:48 34:00 34:12 34:24 34:36 34:48 35:00 35:12 35:24 35:36 35:
8559 S:17 F:3 BSUB{128, 15, -3 . 0) PKD{3, 5, 2 , 0 .10%, 11444 . 0, 1 . 00%, F, F)
:5 A1.74E8
A

'I /I
33:24 33:36 33:48 34:00 34:12 34:24 34:36 34:48 35:00 35:12 35:24 35:36 35
8530 S:17 F:3 BSUB(128, 15, -3 .0) PKD(3, 5, 2, 0 . 10%, 4560 . 0, 1 . 00%,F,F)
A1.38E8 A1.40E8
A A

\ 11
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7.2E7
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48 Time
5.7E7
_2 . 8E7
O.OEO
33:24 33:36 33:48 34:00 34:12 34:24 34:36 34:48 35:00 35:12 35:24 35:36 35 48 Time
9760 S:17 F:3 SMO{1,3) PKD(3, 3, 3 , 100 .00%, 0 . 0, 1 . 00%, F, F)
33:36 33:46 33:54 34:04 34:21 34:33 34:45 35:0035:0735:14 35:25 35:37 7.2E7
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-------
Pile
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437.
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501
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430.
100%
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: A20JUL98& Acq: 21-JUL-1998 09:l8:b4
le #17 Text: BE CS3 ALS #2
7767 S:17 F:4 SMO(1,3) BSUB(128, 15, -3 . 0)

36:66 36!i2 36I24
7737 S:17 F:4 SMO(1,3)

36:00 36:12 36:24
8169- S:17 F:4 SMO(1,3)

' i » i i 1 	 1 	 | i '
36:00 36:12 36:24
8140 S:17 F:4 SMO(1,3)

1 i i i i I i i i i i 1 	 iii
36:00 36:12 36:24
9728 S:17 F:4 SMO(1,3)
36:21
/
I i i f i i i I i i I i i i"i— r |— r-i
36:00 36:12 36:24

36:36 36:48 37!
BSUB(128,15,-3.0)

36:36 36:48 37:
BSUB(128,15,-3.0)

36:36 36:48 37:
BSUB(128,15,-3.0)

1 t*T"T'T I— I 1 1 1 1 1 1 1 1 I
36:36 36:48 37:
PKD(3,3,3,100.00%
36.L49

T 1 f ' )• 1 1 1 1 1 | 1 1 1 1 1 |
36:36 36:48 37:
Exp: EXP_M23_t)B5_6VATION
PKD(3,3,3,0.10%,1308.0,
A2.99E7
A
k, .
00 37:12 37:24 37:36
PKD( 3, 3, 3, 0.10%, 908. 0,1
A2.93E7
A
1., .
00 37:12 37:24 37:36
PKD(3,3,3,0.10%,3120.0,
A1.37E8
A

00 37:12 37:24 37:36
PKD(3,3, 3, 0.10%, 3380.0,
A1.31E8
A
L ,
66 37! 12 37! 24 37136
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37:10 37:32

66 37!l2 37:24 37136
Voltage SIR EI+ GC Autospec-UltimaE Parad
1.00%,F,F)

37 Us 38166 38112 38124 38!36 38!48 39!
.00%,F,F)

37!48 38566 38!l2 38:24 38I36 38:48 39
1.00%,F,F)

37 Us 38:66 38!l2 38:24 38:36 38:48 39
1.00%,F,F)

Lgm
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37!48 38:66 38!l2 38I24 38!36 38!48 39 00 Time
37:53 38:09 38:2638:36 38:51 5.0E7

12 . 5E7
10. OEO
37U8 38!66 38:12 3s!24 38!36 38:48 39 00 Time
ro

-------
File: A20JUL98B Acq: 21-JUL-1998 09:18:54 Exp: EXP_M23_DB5_OVATION Voltage SIR EI+ GC Autospec-UltimaE Parad]
Sample #17 Text: BE CS3 ALS #2
457.7377 S:17 F:5 SMO(1,3) BSUB (128, 15, -3 . 0) PKD(3 , 3 , 3 , 0 . 10%, 1172 . 0, 1 . 00%, F, F)
100% A4.70E7
50J
0"
459.
100%
50J
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469.
100%
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471.
100%
so;
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454.
loot
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0

39ll2 39124 39136 39U8 4o!ob 4o!l2 4ol24 4o!36 4oUs 4l!
7348 S:17 F:5 SMO(1,3) BSUB(128, 15, -3 . 0) PKD(3 , 3 , 3 , 0 . 10% , 732 . 0 , 1 . 00% , F, F)
A5.31E7
yV
39:12 39:24 39:36 39:48 4o!ob 40:12 40:24 40:36 40:48 41:
7780 S-.17 F:5 SMO(1,3) BSUB ( 128, 15 , -3 . 0) PKD(3 , 3 , 3 , 0 . 10% , 1400 . 0 , 1 . 00%, F, F)
A1.93E8
f\_
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39:12 39:24 39:36 39:48 40:00 40:12 40:24 40:36 40:48 41.
7750 S:17 F:5 SMO(1,3) BSUB(128, 15, -3 . 0) PKD(3 , 3 , 3 , 0 . 10% , 1800 . 0 , 1 . 00%, F, F)
A2 -15E8
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1 — i — i — i — i — i — i 	 1 — i — i — i — r — i — i — i — i — i — i — i — i — i — i 	 1 — | — i — r — r -r~ r — r r— r -r i i 1 1 1 I i I | i i i i I | i i i i i | i i i i i
39:12 39:24 39:36 39:48 40:00 40:12 40:24 40:36 40:48 41:
9728 S:17 F:5 SMO(1,3) PKD(3 , 3 , 3 , 100 . 00%, 0 . 0 , 1 . 00%, F, F)
39:07 39:16 39:23 39:32 39:42 39:50 40:01 40:08 40:16 40:29 40:35 40:43 40:50 40:57
'
39:12 39:24 39:36 39:48 40:00 40:12 40:24 40:36 40:48 41
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5.0E7
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O.OEO
00 Time
10
CD
fH

-------
File: A20JUL98B Acq: 21-JUL-1998 09:
18:54 Exp: EXP_M23_DB5_OVATION
Voltage SIR EH- GC Autospec-UltimaE Paradigm

Sample #17 Text: BE CS3 ALS #2
303.9016 S:17 SMO(1
100%
50 j
oj



' ' ' ' T24l
305.8987 S:17 SMO(1
1001
50J
o:
,3) BSUB(128,15,-3



OO' ' 25 !00
,3) BSUB(128,15,-3
.0) PKD(3,3,3



26 1
.0) PKD(3,3,3
,0



00
,0
.10%, 1000. 0,1. 00%
,F,F)
Al . 04E7
A


27 loo'
.10%, 1884. 0,1. 00%

A
2.
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r i . i [ . , i • — i — i 	 1 	 1 	 1 	 1 	 1 	 r1-- •
28:00 29:00 30:00
,F,F)
A1.36E7 2.


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315.9419 S:17 SMO(1
100%
50J
0.



' ' ' ' 24!
317.9389 S:17 SMO(1
100%
50J
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375.8364 S:17 SMO(1
100%
50 :
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I ,JU3923A
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316.9824 S:17 SMO(1


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3E3
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Time

-------
File: A20JUL98B Acq: 21-JUL-1998 09:18:54 —
Sample #17 Text: BE CS3 ALS #2
339.8597 S
1003
50_
°~



30:12
341.8568 S:
100%
50 j
o:



30112
351.9000 S:
100%
50J

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3bll2
353.8970 S:
100%
50 j
I
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3bTl2
409.7974 S:
100%
50J
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30:10
> /\ ,^^
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3b!l2
366.9792 S:
100% 30:
50 j
•> o:


30:ri2
17 F: 2 SMO(1,



3b!24 3ol36
17 F:2 SMO(1,



3b!24 3b!36
17 F:2 SMO(1,




30:24 30:36
17 F:2 SMO(1,




i ' i i C i i i i i i i i
30:24 30:36
17 F:2 SMO(1,

30:32
V 	 ^'-y^-'\^-x/rXj
30:24 30136
17 F:2 SMO(1,
3) BSUB(128,15,-3.0)



sbUs sildd 3i!i2
3) BSUB(128,15,-3.0)



isbUs 31:00 3l!i2
3) BSUB(128,15,-3.0)




30:48 31:00 31:12
3) BSUB(128,15,-3.0)




30:48 31:00 31:12
3) BSUB(128,15,-3.0)

30:51
r\ AA 31:07,
/ V* -r** \ r— ' "*"\ r\ s**
1 \r \_r^ V v/^
30 5 48 31 1-00 3ill2
Exp: EXP_M23_DB5_OVATION Voltage SIR EH- GC Autospec-UltimaE Paradigm
PKD{3,3,3,0.10%/724.0,1.00%,F,F)
A5.38E7 A5.53E7
A A
A
/ V
31124 3ll36 31 Us 32loO 32112 32124
PKD (3, 3, 3, 0.10%, 1708. 0,1. 00%, F,F)
A3.49E7 A3.65E7
A A
A
i v-
3il24 3i!36 31148 32loO 32112 32124
PKD(3,3/3,0.10%,28.0,1.00%,F,F)
A2.47E8
A
A
/ \ A6.12E7
J V^ J\
31:24 31:36 31:48 32:00 32:12 32:24
PKD(3,3,3,0.10%,3096.0,1.00%,F,F)
A1.59E8
A
A
/ \ A3.90E7
J V_ /V
31:24 31:36 31:48 32:00 32:12 32:24
PKD(3,3,3,100.00%,2172.0,1.00%,F,F)

fAf\ 31:36 31:48 32:07 32:22
\ ,^ ^J~\ ^- ^A^ *S^S\ J\ ^^ f~. S*^ S
j \j^s~i W\X^^^^v/ \s ^^^-/^-^j
1 ! ' I ! ' ' ' ' | ' ' ' ' ' 1 ' ' ' ' ' 1 ' ' ' ' ' 1 ' ' ' ' ' 1 ' ' '
31:24 31:36 31:48 32:00 32:12 32:24




i i i i i i i i 1 i i i i i 1 i i i i i I i i
32:36 32:48 33:00 33:12
2 . OE7
_1.0E7
Time




1.3E7
.6.7E6
n . np.n
i i i i i i i i i i i i i i i i i i i i i i r ~ • - —
32:36 32:48 33:00 33:12 Time





8.8E7
.4.4E7

n.OEO
i i i i i i i i i i i i i i i i i i i i i i i' ~ • 	
32:36 32:48 33:00 33? 12 Time





5.7E7
.2 . 8E7

O.ORO
iitiiiiiiiiiiiiiii\ii\r~ • 	
32:36 32:48 33:00 33:12 Time

32:37 ,_9.1E3
A
jj \J\ 33:08
^x^^V_/ — \/ ^^"^
.4 . 6E3
O.OEO
T — I — I — I — 1 — i — i — i — [ — I — i i^i i — f — i Y i — i — i — i — i — r 	 	
32:36 32:48 33:00 33:12 Time
3) PKD(3,3,3,100.00%,0.0,1.00%,F,F)
18 30:32 30:45 31:07


30:24 "30:36


30:48 31:00 31:12
31:22 31:38 31:50 32:02 32jl3 32:25


31:24 31:36 31:48 32:00 32:12 32:24
32:40 32:59 3 . 6E7


:l.8E7
O.OEO
32136 32:48 33:00 33:12 Time

-------
File: A20JUL98B  Acq:  21-JUL-1998 09:18:54Exp: EXP_M23_DB5_dVATl6N Voltage SIR EI+—GC Autospec-UltimaE—Paradigm
Sample  #17   Text: BE CS3  ALS #2
373.8207  S:17  F:3 SMO(1,3)  BSUB(128,15,-3.0)  PKD(3,5, 2 , 0.10%,1600.0,1.00%,F,F)
100%.                                      A5.47E7         A4.74E7
                                                                                A4.22E7
  o-
      33:24    33136
                                                                                                                   1.8E7
                                                                                                                  :
                                                                                                                  L8.8E6
                                                                                                                  LO.OEO
                                34:00    34:12    34:24    34:36    34:48   35iOO    35ll2    35J24    35^36
375.8178 S:17 F:3 SMO(1,3) BSUB(128,15,-3.0) PKD(3,5,2,0.10%,17484.0,1.00%,F,F)
100&                                     A4.34E7
                                                                                                               35:48  Time

                                                                                                                  _1.4E7
— A 	 AJ.OUO/
AA A A3.36E7
/Yl A A.
33:24 33:36 33:48 34:00 34:12 34:24 34:36 34:48 35100 35:12 35:24 35:36 35:
f
L7.0E6
•O.OEO
48 Time
383.8639 S:17 F:3 BSUB(128,15,-3.0)  PKD(3,5,2,0.10%,10824.0,1.00%,F,F)
                                         A1.15E8.
                                                                                                                   5.3E7

                                                                                                                  L2.7E7
                                                                               A2.35E7
                                                                                                                  .O.OEO
      i  I i  i i  i l  I I  l I  l l  i i  l l—i—i—I—i—i—r"1—r""i—i—i i" I i  I i i  i i—i—I—i—i—i—i—i—I—i—i—i—i—i—1—i—r^i—i ~1  I i i  i—i  i I—r—i—i—r—i—I—i—i—r—i—r
      33:24    33:36    33:48    34:00   34:12    34:24    34:36    34:48   35:00    35:12    35:24    35:36   35:48  Time
385.8610 S:17 F:3 BSUB(128,15,-3.0)  PKD(3,5,2,0.10%, 6784.0,1.00%,F,F)
100%.                                     A2.20E8                                                                   1.0E8
 50

  n=
              33136^  33148'" '34:o'o'  ' '34:12    34:24    34:36
                                                                    T
                                                                               A4.37E7
                                                                              I i  i-i  1^1 |ii . i  i |
                                                                                                                  _5.2E7
                                                                                                                   O.OEO
      3324    3336    33:48    34:00    34:12    34:24    3436    3448    3soO    3sl2    3524    356   35  48  Time
445.7555 S:17 F:3 SMO(1,3) BSUB(128, 15, -3 . 0) PKD(3, 3 , 3, 100 . 00%, 916 .0, 1 .00%,F,F)
100%                                                             3445    34:58                                   8 . 6E3
          4    33:36    33:48    34:00    34:12    3
380.9760 S:17 F:3 SMO(1,3) PKD(3,3,3,100.00%,0.0,1.00%,F, F)
100%.          33:36   33:46 33:54   34:04	34:21    34:33    34:45
 50J
                                                                           35:0035:0735:14   35:25    35=37
                                                                                                                  7
                                                                                                                  3 . 6E7
                                                                                                                  O.OEO
    -i—i—i—r—i—i—i—i—I—i—i—i—i—i—i—i—i—i—i—P—|—i—i—>—i—>—i—i—i—i—i—i—l—i—>—i—>—i—I—i—i—i—'—'—l—i—i—i—i—l—i—i—i—i—i—i—i—i—i—i" r i—i—i—i—i—i—i—i—i—i—i—i—i—ri-u • "CiU
     33:24    33:36    33:48    34:00   34:12    34:24    34:36   34:48    35:00    35:12    35:24    35:36    35:48  Time

-------
  File:  A20JUL98B  Acq:  21-JUL-1998 09:18:54  Exp:  EXP_M23_DB5_OVATION Voltage SIR EH-—GC Autospec-UltimaE—Paradigm	
  Sample #17  Text: BE CS3  ALS #2
  407.7818 S:17 F:4 SMO(1,3) BSUB(128,15,-3.0)  PKD(3,3,3,0.10%,5688.0,1.00%,F,F)
  1003k              A3.87E7                                                                                        ..1.2E7
A A3.26E7
/v /v
36:00 36:12 36:24 36:36 36:48 37:00 37:12 37:24 37:36 37:48 38:00 38:12 38:24 38:36 38148 39!

_5.8E6
O.OEO
00 Til
409.7788 S:17 F:4 SMO(1,3)  BSUB(128,15,-3.0)  PKD(3,3,3,0.10%,1108.0,1.00%,F,F)
100%              A3.78E7
                                                          A3.15E7
                     i \
 50 J

  OJ.
                                                                                                                    1.
         I I I I I I I  I I I I T I  i I l~"l I I I  I I I I I I I  I I I I I I I I  I I I I I I I  I I I I 'I I I—I I I I I I  I I I I I I I  I I I I I I I  I I I I I I  I I I I I I I  I I I I I I  I I I I I
         36:00  36:12  36:24  36:36  36:48  37:00   37:12   37:24  37:36  37:48  38:00  38:12  38:24  38:36  38:48  39:00
 417.8253  S:17 F:4  SMO(1,3)  BSUB(128,15,-3.0)  PKD(3,3,3,0.10%,7384.0,1.00%,F,F)
 100*               A7.58E7                                                                                        _2
 2E7

. 8E6

.OEO
 Time

,3E7

,2E7

,OEO
 Time

,1E7

,6E7

, OEO
 Time

,2E3

.6E3

 OEO
 Time

,OE7

.5E7

,OEO
 Time
 50J

  0.
                                                           A1.57E7
                                                                                                                   .1
        36:00  36:12  36:24  36:36
                                          37100  37:12  37124  37:36  37:48  38:00  38:12  38:24  38:36  38:48   39:00
419.8220 S:17 F:4 SMO(1,3) BSUB(128,15,-3.0) PKD(3,3,3,0.10%,7212.0,1.00%,F,F)
100%              A1.69E8
  50
                                                                                                                    5
                                                           A3.49E7
        36166 ' 36:12 ' 36:24 ' 36:36 ' 36l48  37:00  37:12   37:24  37:36  37:48  38:00  38:12  38:24  38:36  38:48  39:00
479.7165 S:17 F:4 SMO(1,3) BSUB(128,15,-3.0) PKD(3,3,3,100.00%,1896.0,1.00%,F,F)
100%.                                    36:57  37^09
                                                                            38:00
  50^

   OJ
             36:07
                                                                                        38:18
                                                                                                                    7
       i i  i i i i i i i  i i i i i i I  i i i i i i i  i—i i i i i i  i i i i i i i  i i i i i i i  i i i i i i  i i i i i i i  i i i i i i i  i i i i i i i  i i i i i i  i i i i i i  i i i i i i i  i i i i'
        36.;00  36ll2  36:24  36:36  36.:48   37:00   37:12  37:24  37:36  37:48  38:00  38:12  38:24  38:36  38:48   39:00
 430.9728  S:17 F:4  SMO(1,3)  PKD(3,3,3,100.00%, 0.0,1.00%,F, F)
 100%	36:21	     36:49	3JLLLO	3JZJJ32	37:53    38:09     38:2638:36    38:51   _5
  50
   Oj
                                                                                                                  _2

                                                                                                                  0
        ill	i  i i i i i i  T r i i i I	i i i  i i i i i i i  i i I i i i i  i i i i i i  i i i i i i i i  i l i i i I  i i i i i I <  i i r i I i  i i i i i i  i i i i i i i  i i i i'
        36loO  36ll2  36124  36136  36:48   37:00   37:12  37:24  37:36  37:48  38:00  38:12  38:24  38:36  38148   39100
(£>

-------
File: A20JUL98B
Sample #17 Text:
441.7427 S:17 F:5
100%
50:
o:
443.
100%
50 j
o.:
469.
100%
50J
ol
471.
1003
50 1
ol
513.
100%
sol
ol
454.
100%
sol

39.1 12
7398 S:17 F:5

39ll2
7780 S:17 F:5

39:12
7750 S:17 F:5

39:12
6775 S:17 F:5
39:06 39
39:12
9728 S:17 F:5
39:07 39-

i — i i i | i i
39:12
Acq: 21-JUL-1998 09:18:54 Exp: EXP_M23_DB5_OVATION Voltage SIR EI+ GC Autospec-UltimaE Paradigm
BE CS3 ALS #2
SMO(1,3) BSUB(128,15,-3.0) PKD(3 , 3 , 3 , 0. 10%, 560. 0, 1 . 00%, F, F)
A5JD3E7 1.2E7

39:24
SMO(1,3)

39124
SMO(1,3)

39:24
SMO(1,3)

39:24
SMO (1,3)

39136 39148
BSUB(128,15,-3.0) PKD(3

39136 39U8
BSUB(128,15,-3.0) PKD(3

39:36 39.U8
BSUB(128,15,-3.0) PKD(3

39136 39:48
BSUB(128,15,-3.0) PKD(3
^6 39:26 3/^V^ 3/-\9
39:24
SMO(1,3)
16 39:23

1 1 ! | 1
39:24
39:36 39:48
PKD(3,3,3,100.00%,0.0,1
39:32 39:42 39

39:36 39:48

40:00 40:12 40
, 3, 3, 0.10%, 1172. 0,1. 00%, F,F)
A5.63E7

40:00 ' ' 40:12 40
,3,3,0.10%, 1400 .0,1. 00% , F, F)
Al .93 E 8
/V_
40:00 40:12 40
, 3, 3, 0.10%, 1800. 0,1. 00%, P,F)
j\^
40:00 40:12 40
, 3, 3, 100. 00%, 160. 0,1. 00%, F,F)
40:01
/ V 40:10
y ^ — • — • — r~\
40:00 40:12 40
.00%,F,F)
i53 40:01 40:08 40:16

40:00 40:12 40

L5.8E6
-O.OEO
:24 4o!36 40.-48 41.-00 Time
1.3E7

L6.6E6
LO.OEO
:24 40136 4oUs 41:00 Time
4 . 5E7

12 . 2E7
.O.OEO
124 40136 40.'48 41-00 Time
5.0E7

.2 . 5E7
.O.OEO
•24 40:36 40l48 41:00 Time
7.8E3
40:27 40:37 '• ^.^ 40:54
_3.9E3
_O.OEO
!24 40:36 ' 4ol48 41 00 Time
40:2940:35 40:43 40:50 40:57 5. 4E7

.2.7E7
_O.OEO
:24 40:36 40:48 41 00 Time
CO
•O

-------
       OPUSquo..    22-JUL-1998
                  Page 1
                                                                                                                   Page 2 of 2
          Run #7   Filename a21ju!98f
          Run: a07feb98f  Analyte:
          Sample  text: CS3
                  S: 2   I:  1  Acquired:  21-JUL-98 20:43:56 Processed:  22-JUL-98 08:22:02
                   Cal:  07feb-m23» Results:               Quan :  V3.5 17-APR-1997 11:14:34
                       Comments:                          OPUS :  V3.5X 17-APR-1997 11:31:23
               Typ

               Onk
               ES/RT
               Total
               DPE
               LMC
                                         Name
      2.3,7,8-TCDF
  13C-2,3,7,8-TCDF
      Tetra Furans
            HxCDPE
QC CHK ION (Tetra)
   Resp

4.0e+07
8.4e+08
4.7e+07
  RA
      V
0.77  y
0.78  y
1.74  n
/    RT

  27:53
  27:51
  19:51
 NotFnd
 NotFnd
Cone

5.04
 205
5.96
Dev'n

  0.8

  0.8
Mod?

n
n
n
n
n
CO
o

-------
File: A21JUL98BAcq: 21-JUL-1998  16:44:01Exp: M23_DB225 Voltage SIR EI+ GC Autospec-UltimaEParadigm
Sample #1  Text: DB-225 Retchk  ALS  #1
TIC  (+RP)
100%                                                      28;51
 90

 85J

 80 1

 75 j

 70J

 65J

 60J

 55J

 50J

 45 J

 40 j

 35J

 30J

 25J

 20 j

 15J

 10 j
  O
                            28:27
28:02 28:07
 4.7E8

L4.5E8

L4.3E8

L4.0E8

L3.8E8

L3.5E8

:3.3E8

L3.1E8

L2.8E8

.2.6E8

':2. 4E8

L2.1E8

:1.9E8

:1.7E8

L1.4E8

:1.2E8

L9.5E7

L7.1E7

L4.7E7

:2.4E7
 O.OEO
    Time
   28:00 28:06  28:12 28:18  28:24 28:30  28:36 28:42  28:48  28:54  29:00  29:06  29:12  29:18  29:24  29:30
                                                                                                     29:36

-------
         OPUSquo
22-JUL-1998
                           Page 1
                  Filename
                    Sample
                  Acquired
                 Processed
                 Sample ID
                 Cal Table
             Results Table
                  Comments
         Typ
         Unk
         ES/RT
         Total
         DPE
         LMC
                                                                                                                                                       Page 8
         a21ju!98£
         3
         21-JUL-98  21:20:
         22-JUL-98  08:31:
         sb
         07feb-m23conf
         M8290-23-072198F
              54
              41
       2,3,7
   1302,3,7
       Tetra
                    QC CHK ION
   Name;
,8-TCDF;
,8-TCDF;
 Furans;
 HxCDPE;
(Tetra);
    Resp ;
2.23e+05;
   Ion 1;
1.10e+05;
   Ion 2;
1.12e+05;
                     2.67e+06;  2.62e+05;  6.62e+04;
  RA,-?
0.98;n
   *;n
3.95;n
     RT;
  27:53;
 NotFnd;
  17:56;
;NotFnd;
;NotFnd;
                                                                       Conc
                                                                                  DL
S/N1;?;
   6;y;
   *;n;
  14; y;
   *;n
DivO;n
S/N2;?
   9;y
   *;n
mod?
  no
  no
  no
  no
  no
                                                                         -;-; 27:53
                                                                         -;-; 27:53
CO
o
CO

-------
OPUSquan   22-JUL-1998
                   Page  I
 Ent: 3  Name:  Tetra Furans
                                                Page 1 of  1

                F:l  Mass:  303.902  305.899 Hod? no   *Hom:8
 Run: 8  File:  a21ju!98f    S:3  Acq:21-JUL-98  21:20:54  Proc:22-JUL-98 08:31:41
 Tables: Run: a21ju!98b  Analyte: m23_conf    Cal:  07£eb-m23»Results: M8290-23*
 Version: V3.5 17-APR-1997 11:14:34  Sample text: sb
   Amount:  *
     Cone:  *
   Tox #1:  -
Name
2,3,7,8-TCDF
of which *
of which *
     Tox #2:  -
named and *
named and *
      Tox #3:  -
                         RT Respnse
                                        RA
                                              Cone
unnamed
unnamed
                                   Area   Height    S/N  Mod?
                      17:56 3.3e+05  3.95 n
                            3.3e+05

                      18:01 5.96+05  1.63 n
                            5.96+05
                      18:02 7.1e+05
                            7.1e+05
                                     2.16 n
4  27:32 2.0e+05  0.76 y
         2.0e+05

5  27:35 2.4e+05  1.08 n
         2.4e+05

6  27:53 2.2e+05  0.98 n
         2.2e+05

7  27:55 2.7e+05  0.47 n
         2.7e+05

8  28:13 l.le+05  2.12 n
         l.le+05
               2.66+05 6.3e+04  1.4e+01  y  n
               6.6e+04 2.8e+04  6.6e+00  y  n
              *
               3.6e+05 8.0e+04  1.8e+01  y  n
               2.2e+05 5.5e+04  1.3e+01  y  n
              *
               4.8e+05 7.3e+04  1.7e+01  y  n
               2.2e+05 5.5e+04  1.3e+01  y  n
              *
               8.7e+04 2.5e+04  5.7e+00  y  n
               l.le+05 3.3e+04  7.8e+00  y  n
              *
               1.2e+05 2.7e+04  6.2e+00  y  n
               l.le+05 2.8e+04  6.6e+00  y  n
              *
               l.le+05 2.86+04  6.4e+00  y  n
               l.le+05 3.86+04  9.16+00  y  n
              *
               8.7e+04 2.7e+04  6.1e+00  y  n
               1.8e+05 4.3e+04  l.Oe+01  y  n
              *
               7.86+04 1.66+04  3.7e+00  y  n
               3.7e+04 1.5e+04  3.5e+00  y  n
                                                                                                    304

-------
  File:  A21JUL98F  Acq: 21-JUL-1998 21:20:54  Exp:  M23_DB225 Voltage SIR EI+  GC Autospec-UltimaE — Paradigm
  Sample #3  Text:  sb  ALS #3
  303.9016 S:3  SMO(1,3) BSUB(128, 15, -3 . 0)  PKD(3 , 3 , 3 , 0 . 10% , 4352 . 0, 1 . 00% , F, F)
  100%             A3.65E5                                                                                          9
 50j

  OJ
                     T

                                                     ~T
                                                                T
                                                                        A8.75E4
                                                                        A
        16:00      18:00      20:00      22:00      24:00     26:00
 305.8987  S:3  SMO(1,3)  BSUB(128,15,-3.0)  PKD(3,3,3,0.10%,4188.0,1. 00%, F, F)
 1004             A2.24E5
                                                                        28:00
                               •' 1^ i—i—
                                 30:00
                                          AS.93E3
                                         ^p^H^H
                                                                                                T"".^,
                                                                                              32:00
T "'""I	1	p	1 ^ -T"'
    34:00
                                                                                                                   _4
 .3E4

 .7E4

I. OEO
  Time
       16:00      18:00      20:00     22iOO      24iOO      26iOO      28iOO
315.9419 S:3 SMO(1,3) BSUB(128,15,-3.0) PKD(3,3,3,0.10%,19804.0,1.00%,F,F)
1004              ,,.«                                                 27;53
                                                       24 v
 50 A
                                 30:00
                                                                                              32:00
                                                                                                          34:00
                                                                                                                    6

                                                                                                                   13.

                                                                                                                    0,
       16:00      ISiOO      20iOO     22iOO      24iOO      26:00      28^00
317.9389 S:3 SMO(1,3) BSUB(128,15,-3.0) PKD(3,3,3,0.10%,23456.0,1.00%,F,F)
1004              17:58
                                                                                    30:00
                                                                                              32:00
                                                       34:00
               .OEO
                Time

               ,4E4

               2E4

               .OEO
                Time
        16:00      18:00      20:00      22:00      24:00      26:00      28:00
 375.8364 S:3 SMO(1,3) BSUB(128,15,-3.0) PKD(3,3,3,100.00%,8900.0,1.00%,F,F)
 1004                                                   24:56
  50j

   OJ
                                                                                   30:00
                                                              26:00
                      28:00
                                                                                   30:00
                                                                                              32:00
   34:00
       16:00      18:00      20:00      22:00      24:00
316.9824 S:3 SMO(1,3) PKD(3,3,3,100.00%,0.0,1.00%,F,F)
1004_	19:22  20:42  21:57  23:1524:1525:1626:^427:14 28:28    30:0131:00  32:18   33;3734;34_8
  50,

   OJ
        ielob
                 18:00      20:00
i  I  ' i  i  i—r~i—i—i  i  P—i—r—I—i—i—i—i—i—r—i—i i  i  i  i  i  i • i—i—i—i—i—i-
24:00      26:00      28:00      30:00       32:00       34:00
                                                                                                                 _4
.2E5

. 6E5

.OEO
  Time

.5E7

.2E7

.OEO
  Time
CO
o
C/I

-------
OPUSquan   22-JUL-1998
                  Page 1
                                                                                                            Page 3 of 3
   Run #8   Filename a21ju!98f
   Run: a07feb98f  Analyte:
   Sample text: CS3
                  S: 17  I: 1  Acquired:  22-JUL-98 06:01:17 Processed:  22-JUL-98 08:24:11
                   Cal: 07feb-m23» Results:               Quan :  V3.5 17-APR-1997 11:14:34
                       Comments:                         OPUS :  V3.5X 17-APR-1997 11:31:23
        Typ

        Unk
        ES/RT
        Total
        DPE
        LMC
                                  Name
      2,3,7,8-TCDF
  13C-2,3,7,8-TCDF
      Tetra Furans
            HxCDPE
QC CHK ION (Tetra)
   Resp

3.0e+07
6.6e+08
3.5e+07
  RA

0.78
0.78
1.11
/   RT

 27:53
 27:51
 17:59
NotFnd
NotFnd
Cone

4.85
 161
5.55
Dev' n

 -3.0

 -3.0
Mod?

n
n
n
n
n

-------
File: A21JUL98F Acq: ;
Sample #17 Text: CS3
303.9016 S:17 SMO(1,3)
100%
50_
0
305.
1008
50 j
315.
100%
50 j
o:
317.
1003
50J
o:
375.
1003
50J
o:
316.
100%
50J
o:


ieSob
8987 S:17


ielob
9419 S:17

ielob
9389 S:17

16:00
8364 S:17



islob
SMO (1,3)


1 1 1 1 1
18:00
SMO(1,3)

islob
SMO(1,3)

SMO (1,3)

16:3117:30
' 16:00 '
9824 S:17
16;20

i i | i i
16:00
islob
SMO(1,3)
18;

i i i 1 i
18:00
J2-JUL-1998 06:01:17 Exp : M23 DB225 Voltage SIR EI+ GC Autospec-UltimaE Paradigm
ALS #2
BSUB(128,15,-3.0) PKD(3 , 3 , 3 , 0 . 10%, 3076 . 0 , 1 . 00%, F, F)
A1.32E7

A A7.JJ3E5
20:00 22:00 24:00 26:00 28:00 30:00 32:00 34:00
BSUB(128,15,-3.0) PKD(3, 3 , 3 , 0 . 10%, 3112 . 0, 1 . 00%, F, F)
A1.69E7

A A9 'J12E5
20:00 22:00 24:00 26:00 28:00 30:00 32:00 34:00
BSUB(128,15,-3.0) PKD(3 , 3 , 3 , 0 . 10% , 21212 . 0 , 1 . 00%, F, F)
A2.87E8
A

.,,.,,,
20100 22:00 24:00 26:00 28:00 30:00 32loO 34loO
BSUB(128,15,-3.0) PKD(3 , 3 , 3 , 0 . 10%, 33252 .0, 1 . 00%, F, F)
A3.68E8
A

	 , , ,
20100 22:00 24:00 26:00 28:00 30:00 32:00 34:00
BSUB(128,15,-3.0) PKD(3,3,3,100.00%,6884.0,1.00%,F,F)
19:08
/I
/ \ 21:48 23:22 24:45 26:18 21=.52 30:54 33:00 34:23
PKD(3,3,3,100.00%,0.0,1.00%,F,F)
21 21iD2 22_L09^3jll 24;57 26i3827j34 28j57 30:01 31:08 32:22 33:32

20:00 22:00 24:00 26:00 28:00 30:00 32:00 34:00
1.5E6
_7.5E5
O.OEO
Time
1.9E6
_9.4E5
O.OEO
Time
3.3E7
L1.7E7
: O.OEO
Time
4.2E7
L2.1E7
O.OEO
Time
1.9E5
L9.4E4
O.OEO
Time
_3 . 8E7
11.9E7
r O.OEO
Time

-------
Pile: A21JUL98F Acq: 21-JUL-1998 20:43:56 Exp: M23_DB225 Volt
age SIR EI+ GC
Autospec-UltimaE Paradigm
Sample #2 Text: CS3 ALS #2
303.9016 S:2
100%
50 j
•
0:




UJ — i — i — i — i —
16:00
305.8987 S:2
100%
50J
;



0 1— I — , | -T
16 : 00
315.9419 S:2
1001
50J
0-



ielob
317.9389 S:2
100%
50 1
0 '



WJ — 1 — 1 1 1
16:00
375.8364 S:2
100%.
50J
o-
SMO(1,3) BSUB(128,15,-3.0) PKD(3 , 3 , 3 , 0 . 10%, 3488 . 0 ,




1 	 1 	 1 i i ' l 	 r— i 	 1 	 r* -1 	 1 1 I 	 1 	 1 — •
ISIOO 20100 22




:00 24100 26
SMO(1,3) BSUB(128,15,-3.0) PKD(3 , 3, 3 , 0 .10%, 5344 . 0,



i — i i i — i — i — i i i — r"-i — i — i — i — i — i •
18 100 20:00 22



00 24100 26
SMO(1,3) BSUB(128,15,-3.0) PKD(3 , 3 , 3 , 0 . 10%, 18656 . 0



i—i — i — P — i — i — i — i — i — i — i — i — i — i — i — i —
18:00 20:00 22



.00 24lob 26
SMO{1,3) BSUB(128,15,-3.0) PKD(3 , 3 , 3 , 0 . 10%, 22144 . 0



i — i — r— T — i — i i i — i — i — I — i — i — r— i — i —
18:00 20:00 22



00 24:00 26
SMO(1,3) BSUB(128,15,-3.0) PKD(3 , 3, 3, 100 . 00%, 11180
21
16:53 19:57 21:03
ililiL AI/dM 1 -l-il A •luiA,. .iliLJlliJlil.iL Jji.<
WpW
' 16:00
316.
100%
50J
o •
9824 S:2
16:12



" ' 1 1 | 1
16:00
^wffPW
i 	 1 	 1 	 1 — I — i 	 1 	 1 	 1 	 1 	 1 	 1 	 r-1-! 	 1 	 1 	
18:00 20:00 22
SMO(1,3) PKD(3,3,3,100.00%,0
17:4818:47 20^6_ 	 22



islob 2olob 22
:59
„ 22i582(T9 ?5:°9
iJU M JL i it Mill 4 1 iM ti JL 1 A i
^m^^^W
00 24^00 26
1.00%,F,F)
A1.74E7
A
1

~l \
lob 2'slob
1.00%,F,F)
A2.26E7
A
1
JL
lob 2'alob
,1.00%,F,F)
A3 . 67E8
A
|
A
loo 2sSoo
,1.00%,F,F)
A4 . 68E8
A
|
/
:00 28:00
.0,1.00%,F,F)
27:51
26:34 j
1 (1
uJbMu .j^fc LilLJ
(IWTri^ifwv
lob 28lob
0,1.00%,F,F)
^0623:0324^01 25:34 27:51 25



00 24lob 26



lob 2'slob



A1.49E6
,.,.,.,.,. — i — i — r , s~f* i — i — i — H
2.0E6
_1.0E6
0/\i-*r\
. OEO
30:00 32:00 34:00 Time



, , i i — i — i — i — i — i — i — i — i—i — i ^V | i i — r
2.5E6
.1.3E6
O.OEO
30:00 32:00 34:00 Time




4 . 1E7
L2.1E7
O.OEO
30:00 32:00 34:00 Time




5 . 2E7
_2.6E7
O.OEO
30:00 32:00 34:00 Time

2 . 9E4
29:19 30s20 31:2932:30 34:16 f
TI ^| y in ill '» Tn™ir " IF 1 T '|j- Q OEO
30:00 3T2:00 34 1 00 Time
:0029;57 3^9 , 32;1033 :09 34:13



_9.4E7
_4.7E7
O.OEO
30 1 00 32:00 34:00 Time

-------
       Reagent blank sample M23-RB-1 analytical results are
      taken from PAL Project No. L1070 (PAL pages 112-128).
    This project report details analytical results from another kiln
   tested during the same mobilization.  One reagent blank sample
was collected for all the facilities tested during the single mobilization.

-------
                                                                       Paradigm Analytical Labs
                              Analytical Data Summary Sheet
        'Analyte
       i:\'«.-~f •.'•••rt.* '•• ;•'
                          Conttmrat
                                                «»«*
                                                                                  Qualifier
2,3,7,8-TCpp

l523,4(7i8-HxCpp

1,2,3,7,8,9-HxCDD
                              0.0011
                                          0.0005
 28:28
^f*
 34:43
                                                 0.78
OCDD
2,3,7,8-TCDF
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
1,2,3,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
OCDF
                              0.0096
                                           .0014
                                                                35:00
                                      40:03
                               ND
                              0.0008
                               MT
                               ND
                                          0.0004
                                          &0004,
                                          0.0004
                              0.0030
                             •?M)>.'
                              0.0028
                 0.0003
                 0-0004
                 0.0005
                                           0.008
                                      34:11
                                     "v 34:15:
 36:23

 40:10
0.93



1.15



1.00

0.91
Total TCDDsr
Total PeCDDs
Total HxCDDs
Total HpCDDs
      ND
   .0.0024
     0.0032
                                           0.0004
                                           0.0005
                                           0.0005
                                                     0.0048
Total TCDFs
Total PeCDFs
Total HxCDFs
Total HpCDFs
                               ND
                               ND
                              0.0008
                              0.0032
                 0r0006
                 0.0004
                 0.0003
                 0.0005
TEQ (ND=0)
TEQ (ND=l/2)
                              0.0014
                              0.0018
                            0.0015
                            0.0018
                                                                                     ITEF
                                                                                     ITEF
Client Information
Project Name:
 Texas Lime Rfln
••M2Hffl-i:-v^S
                                                    Cample Information
Laboratory Information

Project IP;": 'J .•.;_"'".'.,;,":-"
Sample JD:;  *: ;  " ,

Collection Date:
Receipt Date:
Extraction Date:
Analysis Date:
.-Ti/rtX
:L1070 •
                                                    w/:yoto«
                                        .,0^:?^
                                        *v^^^V^^-t¥??:^:cf1,< .v~-.''^
                                         -^-'-'   •-'
                              10-Jul-98
                              18-Jul-98
                                                                  ,
                                           };|^
                                                  ""   '"
                          Initial Gal:
                                                                         m8290-23-071798
                                          1/2

-------
                                                                       Paradigm Analytical Labs
                              Analytical Data Summary Sheet
^Ij^tffeek* 7 ' ,xfc
Extraction Standards
^J.S^DD^
13CU-1 ?V6V8-HxCDD
"Cu-U.SAe/Z.S-HpCDD
13C12-OCDD
13C12-2,3,7,8-TCDF
l3C12-l,2,3,7,8-PeCDF
13C,r,lA3,6,7,8-HxeDF
I3CirlA3,4,6,7,8-HpCDF
Sampling Standards
37CV2,3,7,8-TCDD
13C12-2)3,4,7,8-PeCDF
i3C,2-i,?,3,4,7,8flxCDD
13C12-l,2)3,4)7>8-HxCDF
13CI2-l,2)3,4,7,8,9-HpCDF
Injection Standards
!3C,rlA3,4-TCDD
''Cn-U.S.W-HxCDD
- Eip^ted^

4
4
4 - :,.
8
4
4
4
4

4
4
. >-.:_-4;.^;\ r
4
4:- :"



^B

3.45
3.50
3-69 ,
6.69
3.51
3.26
3.67 .
2.95

3.86.
3.93
4*0 "
3.53
3.27





86.4
87.4

83.6
= 87.7 V
81.5
91,8 V
73.7

•:^#3£
98.2
^iiiiry
88.2
81.6





28:27
34:46

40:02
27:26
31:57
34:15
36:22

$28:28
32:24
y -34^2-^f
34:11
: 37:32

28:10
34:59
PH

0.78
1.26
\$6
0.88
0.78
1.56
0,52
0.44


1.57
{y;i;23., -
0.52
0.44

0.79
1.25
Qualifier












, .',.:: . .





Client Information
Project Name:
Sample ID:

Laboratory Information

Project ID:
Sample ID:        \. v

Collection Date:
Receipt Date: 7
Extraction Date:
Analysis Date:       ,

Reviewed by: ^ .T
                          Texas Lime Kiln
                          M23-RB-1
                          ,Lid7o
                             08-M-98
Sample Information

Matrix:   ,
                                                  :",~~> ' ~ ^:?->.,'^'v;"
                                                   Filename:
                                                                           Air
                                                                            1. :-
                                                                          , 60
               7•-;-  al7jiil98b-13
                     al7jul98b-l
                     al7jul98b-2
                     al7ju!98b-15
               -.;,.   ,018290.23-071798

                Date Reviewed:  23QL>^
                                         212
                                                                                       or'  113

-------
OPUSquan 20-JUL-1998
Page 1
Filename al7ju!98b
Sample 13
Acquired 18-JUL-98 01:47:01
Processed 20-JUL-98 09:08:26
Sample ID 1070-4 xl/2
Cal Table m8290-23-071798
Results Table M8290-23-071798B

Typ
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Unk
Comments
Name;
2,3,7,8-TCDD;
1, 2,3,7, 8-PeCDD;
1,2,3,4,7,8-HxCDD;
1,2,3,6,7,8-HxCDD;
1,2,3,7,8,9-HxCDD;
1,2,3,4,6,7, 8-HpCDD;
OCDD;
2,3,7,8-TCDF;
1, 2,3,7, 8-PeCDF;
2,3,4,7,8-PeCDF;
1,2,3,4,7,8-HxCDF;
1,2,3,6,7,8-HxCDF;
2,3,4,6.7,8-HxCDF;
1,2,3,7,8,9-HxCDF;
1,2,3,4,6,7,8-HpCDF;
1,2,3,4,7,8,9-HpCDF;
OCDF;
ES/RT 13C-2,3,7,8-TCDD;
ES
ES
ES
ES
ES/RT
ES
ES
ES
JS
JS
cs
cs
cs
cs
cs
ss
ss
ss
ss
ss
13C-1, 2,3,7, 8-PeCDD;
13C-l,2,3,6,7,8-HxCDD;
13C-l,2,3.4,6,7,8-HpCDD;
13C-OCDD;
13C-2,3,7,8-TCDF;
13C-1, 2.3,7, 8-PeCDF;
13C-l,2,3,6,7,8-HxCDF;
13C-1.2,3,4,6,7,8-HpCDF;
13C-1,2,3,4-TCDD;
13C-l,2,3,7,8,9-HxCDD;
37Cl-2,3,7,8-TCDD;
13C-2, 3,4,7, 8-PeCDF;
13C-l,2,3,4,7,8-HxCDD;
13C-l,2,3,4,7,8-HxCDF;
13C-l,2,3,4,7,8,9-HpCDF;
37Cl-2,3,7,8-TCDD;
13C-2, 3,4,7, 8-PeCDF;
13C-1,2,3,4,7, 8-HxCDD;
13C-l,2,3,4,7,8-HxCDF;
13C-l,2,3,4,7,8,9-HpCDF;

Resp;
2.836+05;
1.92e+04;
2.77e+04;
5.81e+04;
8.43e+04;
1.53e+05;
3.906+05;
6.346+04;
* .
* .
6.126+04;
3.756+04;
*;
it .
1.616+05;
* .
1.206+05;
3.446+08;
2.61e+08;
2.83e+08;
2.22e+08;
3.236+08;
4.386+08;
3.546+08;
3.436+08;
1.676+08;
3.636+08;
3.02e+08;
3.046+08;
3.406+08;
2.106+08;
2.386+08;
1.07e+08;
3.04e+08;
3.40e+08;
2.10e+08;
2.38e+08;
1.07e+08;

Ion 1;
4.15e+04;
1.12e+04;
2.13e+04;
3.62e+04;
4.44e+04;
7.85e+04;
1.87e+05;
3.30e+04;
*;
* .
3.27e+04;
2.14e+04;
* .
* .
8.01e+04;
* .
5.69e+04;
1.51e+08;
1.59e+08;
1.58e+08;
1.14e+08;
1.51e+08;
1.92e+08;
2.16e+08;
1. 18e+08;
5.13e+07;
1. 60e+08;
1.68e+08;
3.04e+08;
2.08e+08;
1.16e+08;
8.10e+07;
3.26e+07;
3.04e+08;
2.08e+08;
1.16e+08;
8.10e+07;
3.26e+07;

Ion 2;
2.416+05;
7.97e+03;
6.486+03;
2.196+04;
3.996+04;
7.44e+04;
2.026+05;
3.046+04;
* .
* .
2.856+04;
1.616+04;
*;
* .
8.056+04;
* .
6.286+04;
1.936+08;
1.026+08;
1.25e+08;
1.086+08;
1.726+08;
2.466+08;
1.386+08;
2.256+08;
1.16e+08;
2.03e+08;
1.346+08;

1.336+08;
9.416+07;
1.576+08;
7.436+07;

1.336+08;
9.416+07;
1.57e+08;
7.43e+07;

RA;?;
0.17;n;
1.41;y,
3.28;n;
1.65;n;
l.ll;y;
1-05,-y;
0.93;y;
1.08;n;

RT;
28:28;
32:38;
34:43;
34:47;
35:00;
37:11;
40:03;
27:27;
*;n;NotFnd;
*;n;
1.15;y;
1.32;y;
*;n;
*;n;
1.00;y;
*;n;
0.91;y;
0.78;y;
1.56;y;
1.26;y;
1-06,-y;
0.88;y;
o;78.y.
1.56;y;
0.52;y;
0.44;y;
0.79;y;
1.25;y;

1.57;y;
1.23;y;
0.52;y;
0.44;y;
_ . _.
1.57;y;
1.23;y;
0.52;y;
0.44;y;
NotFnd;
34:11;
34:15;
NotFnd;
NotFnd;
36:23;
NotFnd;
40:10;
28:27;
32:37;
34:46;
37:10;
40:02;
27:26;
31:57;
34:15;
36:22;
28:10;
34:59;
28:28;
32:24;
34:42;
34:11;
37:32;
28:28;
32:24;
34:42;
34:11;
37:32;

Cone;
0.084;
0.007;
0.015;
0.024;
0.035;
0.077;
0.241;
0.015;
* .
*;
0.021;
0.010;
* .
* .
,
0.076;
* .
0.069;
86.342;
94.107;
87.419;
92.327;
167.134;
87 . 672 ;
81.511;
91.739;
73.664;
75.191;
76.109;
83.199;
79.976;
96.382;
81.509;
60.110;
96.414;
98.151;
110.111;
88.145;
81.631;

DL;
0.0114;
0.0105;
0.0156;
0.0123;
0.0122;
0.0112;
0.0351;
0.0152;
0.0091;
0.0088;
0 . 0089 ;
0.0070;
0.0082;
0.0094;
0.0126;
0.0152;
0.0190;
0.0487;
0.0273;
0.0430;
0.0276;
0.0208;
0.0241;
0.0144;
0.1787;
0.0977;
-;
-;
0.0202;
0.0148;
0.0639;
0.2293;
0.1249;
0.0238;
0.0105;
0.0670;
0.2151;
0.2158;

S/N1;?;
6;y;
2;n;
3;n;
5;y;
5;y;
19. • y;
14;y;
5;y;
*;n;
*;n;
4;y;
4;y;
*;n;
*;n;
15;y;
*;n;
15;y;
3589 ;y;
17216; ry;
6066;y;
5293;y;
13121,-y;
8853, -y;
43021, -y;
1389;y;
3242;y;
3900;y;
5940,-y;
12478 ;yi
42528,-yj
4471;y;
1039, -yi
1790;y;
12478;yi
42528;y;
4471,-y;
1039;y;
1790;y;

S/N2;? ;
34;y ;
3;n ;
2;n ;
4;y ;
6;y ;
28, -y ;
46, -y ;
3;n ;
*;n ;
*;n ;
7;y ;
3;n ,-
*;n ;
*;n ;
27 ;y ;
*;n ;
10 ;y j
8202;y ;
19494, -y ;
7523 jy ;
10514 ;y ;
15246;y ;
13263 ;y ;
19577;y ;
2083;y ;
1476,-y ;
8653 ;y ;
7373 ;y ;
_. _;
I9472;y ;
5760;y ;
1526;y ;
827;y ;
-; -;
19472 ;y ;
5760;y ;
1526;y ;
827,-y ;

mod?
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
no
Page 18 c

-------
OPUSquan   20-JUL-1998
                   Page 1
                                                                    Page 1  of  8

 Ent: 39 Name: Total Tetra-Furans  F:l  Mass:  303.902 305.899  Mod?  no    #Hom:1

 Run: 18 File: al7ju!98b    S:13 Acq:18-JUL-98 01:47:01 Proc:20-JUL-98 09:08:26
 Tables: Run: a!7ju!98b  Analyte: m8290-23-»  Cal:  m8290-23-»Results:  M8290-23*
 Version: V3.5 17-APR-1997 11:14:34  Sample text:  1070-4 xl/2
   Amount: 0.02
     Cone: 0.02
   Tox fl: -

Name

2,3,7,8-TCDF
of which 0.02
of which 0.02
     Tox #2:  -

#     RT Respnse
named and *
named and *
      Tox #3: -
    RA
1  27:27 6.3e+04  1.08 n
         6.36+04
          Cone

           0.02
   unnamed
   unnamed
   Area  Height    S/N  Mod?
                                                   3.3e+04 7.7e+03 4.7e+00 y  n
                                                   3.0e+04 7.7e+03 2.9e+00 n  n
                                                                    Page 2 of 8

 Ent: 40 Name: Total Tetra-Dioxins F:l  Mass: 319.897 321.894 Mod? no   #Hom:2

 Run: 18 File: a!7ju!98b    S:13 Acq:18-JUL-98 01:47:01 Proc:20-JUL-98 09:08:26
 Tables: Run: a!7ju!98b  Analyte: m8290-23-»  Cal: m8290-23-»Results: M8290-23»
 Version: V3.5 17-APR-1997 11:14:34  Sample text: 1070-4 xl/2
   Amount: 0.09
     Cone: 0.09
   Tox  #1: -
Name
 2,3,7,8-TCDD
of which 0.08
of which 0.08
     Tox §2: -

#     RT Respnse
named and 0.01
named and 0.01
      Tox #3: -
                                        RA
1  25:16 2.46+04  1.67 n
         2.4e+04

2  28:28 2.8e+05  0.17 n
         2.8e+05
          Cone

           0.01
               3
               £
           0.08
   unnamed
   unnamed
    Area  Height
                                                                      S/N  Mod?
 1.5e+04  3.3e+03 2.6e+00  n   n
 8.8e+03  2.7e+03 2.Oe+00  n   n
3
 4.1e+04  6.9e+03 5.6e+00  y   n
 2.4e+05  4.5e+04 3.4e+01  y   n
                                                                    Page 3 of 8

  Ent:  41  Name:  Total  Penta-Furans  F:2  Mass: 339.860 341.857 Mod? no   #Hom:4

  Run:  18  File:  a!7ju!98b    S:13 Acq:18-JUL-98  01:47:01 Proc:20-JUL-98 09:08:26
  Tables:  Run: al7jul98b Analyte: m8290-23-»  Cal: m8290-23-»Results: M8290-23*
  Version:  V3.5  17-APR-1997  11:14:34   Sample text:  1070-4 xl/2
    Amount:  0.02
      Cone:  0.02
    Tox #1:  -
 Name
 of which *
 of which *
     Tox #2: -

 #     RT Respnse
named  and 0.02
named  and 0.02
       Tox #3:  -
                                         RA
                    1  31:23  2.2e+04   1.35 y
                             2.2e+04

                    2  32:31  1.7e+04   1.13 n
                             1.7e+04

                    3  32:57  1.3e+04   0.27 n
                             1.3e+04

                    4  33:01  1.3e+04   0.28 n
                             1.36+04
           Cone

            0.01
                3
                c
            0.01
                c

            0.00

                3
            0.00
    unnamed
    unnamed
                                                      Area  Height
                                  S/N  Mod?
                                 1.3e+04 3.6e+03 3.7e+00 y  n
                                 9.46+03 2.86+03 1.2e+00 n  n
                                1
                                 9.06+03 2.9e+03 3.Oe+00 n  n
                                 7.96+03 2.0e+03 8.56-01 n  n
                                3
                                 2.8e+03 1.2e+03 1.2e+00 n  n
                                 l.Oe+04 4.36+03 1.9e+00 n  n
                                3
                                 2.9e+03 l.le+03 l.le+00 n  n
                                 l.Oe+04 4.3e+03 1.9e+00 n  n
                                                                     Page  4  of  8
                                                                                                  CK ' 115

-------
OPUSquan   20-JUL-1998
                   Page 2
 Ent: 42 Name: Total Penta-Dioxins F:2  Mass: 355.855 357.852 Mod? no   #Hom:3

 Run: 18 File: al7ju!98b    S:13 Acq:18-JDL-98 01:47:01 Proc:20-JUL-98 09:08:26
 Tables: Run: al7jul98b  Analyte: m8290-23-»  Cal: m8290-23-»Results: M8290-23»
 Version: V3.5 17-APR-1997 11:14:34  Sample text: 1070-4 xl/2
   Amount: 0.03
     Cone: 0.03
   Tox #1: -
Name
of which 0.01
of which 0.01
     Tox #2:  -

#     RT Respnse
named and 0.03
named and 0.03
      Tox #3: -
                                        RA
1,2,3,7,8-PeCDD
1  31:57 3.8e+04  3.76 n
         3.8e+04

2  32:24 4.1e+04  7.00 n
         4.16+04

3  32:38 1.9e+04  1.41 y
         1.96+04
          Cone

           0.01
               3
               6
           0.01
               2
               e
           0.01
    unnamed
    unnamed
    Area  Height
                                                                      S/N  Mod?
 3.0e+04  9.3e+03  4.0e+00 y  n
 8.1e+03  3.5e+03  2.7e+00 n  n
L
 3.6e+04  1.2e+04  5.3e+00 y  n
 5.1e+03  2.0e+03  1.5e+00 n  n
L
 l.le+04  3.7e+03  1.6e+00 n  n
 8.0e+03  3.8e+03  2.9e+00 n  n
 Ent: 43 Name: Total Hexa-Furans
                                                 Page 5 of  8

                F:3  Mass:  373.821 375.818  Mod?  no   #Hom:3
 Run: 18 File: a!7ju!98b    S:13 Acq:18-JUL-98 01:47:01 Proc:20-JUL-98 09:08:26
 Tables: Run: a!7ju!98b  Analyte: m8290-23-»  Cal: m8290-23-»Results: M8290-23»
 Version: V3.5 17-APR-1997 11:14:34  Sample text: 1070-4 xl/2
   Amount: 0.04
     Cone: 0.04
   Tox #1: -
Name
of which 0.03
of which 0.03
     Tox #2:  -

#     RT Respnse
named and 0.01
named and 0.01
      Tox #3: -
                                        RA
                   1  33:38 2.0e+04  1.23 y
                            2.0e+04

1,2,3,4,7,8-HxCDF  2  34:11 6.1e+04  1.15 y
                            6.1e+04

1,2,3,6,7,8-HxCDF  3  34:15 3.8e+04  1.32 y
                            3.86+04
          Cone

           0.01
               ]
               S
           0.02


           0.01
    unnamed
    unnamed
    Area  Height
                                                                      S/N  Mod?
                                l.le+04 4.3e+03 1.8e+00 n  n
                                9.1e+03 4.0e+03 2.6e+00 n  n
                               2
                                3.3e+04 l.Oe+04 4.5e+00 y  n
                                2.8e+04 l.Oe+04 6.6e+00 y  n
                               L
                                2.1e+04 8.36+03 3.66+00 y  n
                                1.66+04 4.46+03 2.8e+00 n  n
                                                                                                 C<

-------
OPUSquan   20-JUL-1998
                   Page  3
                                                                    Page 6 of 8

 Ent: 44 Name: Total Hexa-Dioxins  F:3  Mass:  389.816 391.813 Mod? no   #Hom:12

 Run: 18 File: al7ju!98b    S:13 Acq:18-JUL-98 01:47:01 Proc:20-JOL-98 09:08:26
 Tables: Run: a!7ju!98b  Analyte: m8290-23-»  Cal:  m8290-23-»Results: M8290-23*
 Version: V3.5 17-APR-1997 11:14:34  Sample text:  1070-4 xl/2
   Amount: 0.21
     Cone: 0.21
   Tox #1: -
of which 0.07
of which 0.07
     Tox #2: -
named and 0.14
named and 0.14
      Tox #3: -
Name
      RT Respnse     RA

                  0.90 n
                   1  33:53 3.6e+04
                            3.6e+04
                   2  33:59 2.1e+03  0.40 n
                            2.1e+03

                   3  34:06 6.1e+03  4.17 n
                            6.1e+03

                   4  34:11 9.4e+04  2.47 n
                            9.4e+04

                   5  34:15 6.8e+04  5.10 n
                            6.8e+04

                   6  34:20 7.0e+04  1.35 y
                            7.0e+04
          Cone

           0.02
               1
               ]
           0.00
               6
               1
           0.00
               c
               1
           0.04
               6
               2
           0.03
               c
               ]
           0.03
unnamed
unnamed
                                                      Area  Height    S/N  Mod?
                                1.7e+04 6.6e+03 2.9e+00 n  n
                                1.9e+04 7.3e+03 4.0e+00 y  n

                                6.1e+02 3.6e+02 1.6e-01 n  n
                                1.5e+03 6.2e+02 3.4e-01 n  n
                               3
                                5.0e+03 1.2e+03 5.1e-01 n  n
                                1.2e+03 7.2e+02 3.9e-01 n  n

                                6.7e+04 2.3e+04 9.8e+00 y  n
                                2.7e+04 9.1e+03 5.0e+00 y  n
                               3
                                5.7e+04 1.9e+04 8.4e+00 y  n
                                l.le+04 4.0e+03 2.2e+00 n  n
                       34:24  9.1e+03
                             9.16+03

                       34:28  l.le+04
                             l.le+04
                                      0.81 n
                  1.03 n
                                               0.00
                            0.00
               4.0e+04 1.2e+04 5.4e+00 y  n
               3.0e+04 8.9e+03 4.9e+00 y  n
               D
               4.1e+03 1.8e+03 8.0e-01 n  n
               5.0e+03 1.6e+03 8.7e-01 n  n
               3
               5.3e+03 2.0e+03 8.7e-01 n  n
               5.2e+03 1.7e+03 9.6e-01 n  n
                    9   34:31  l.le+04   1.07 y
                             l.le+04

 1,2,3,4,7,8-HxCDD  10 34:43  2.8e+04   3.28 n
                             2.8e+04

 1,2,3,6,7,8-HxCDD  11 34:47  5.8e+04   1.65 n
                             5.8e+04

 1,2,3,7,8,9-HxCDD  12 35:00  8.4e+04   1.11 y
                             8.4e+04
                                                0.00
                            0.01
                            0.02
                            0.03
                5.6e+03  1.9e+03  8.4e-01 n  n
                5.2e+03  1.7e+03  9.6e-01 n  n
               1
                2.1e+04  5.8e+03  2.5e+00 n  n
                6.5e+03  3.1e+03  1.7e+00 n  n
               2
                3.6e+04  l.le+04  4.7e+00 y  n
                2.2e+04  7.0e+03  3.9e+00 y  n
               3
                4.4e+04  l.le+04  4.7e+00 y  n
                4.0e+04  l.le+04  5.8e+00 y  n
                                                                     Page 7  of 8

  Ent:  45 Name:  Total Hepta-Furans  F:4  Mass:  407.782 409.779 Mod? no   #Hom:l

  Run:  18 File:  a!7ju!98b    S:13 Acq:18-JUL-98 01:47:01 Proc:20-JUL-98 09:08:26
  Tables: Run: a!7ju!98b  Analyte: m8290-23-»  Cal:  m8290-23-»Results: M8290-23»
  Version: V3.5 17-APR-1997 11:14:34  Sample text:  1070-4 xl/2
    Amount:  0.08
      Cone:  0.08
    Tox #1:  -
 Name
 of which 0.08
 of which 0.08
      Tox #2:  -

 #     RT Respnse
 named and *
 named and *
       Tox #3:  -
                                         RA
 1,2,3,4,6,7,8-HpCDFl  36:23 1.6e+05  1.00 y
                             1.6e+05
           Cone

            0.08
 unnamed
 unnamed
 Area  Height
                                                                       S/N  Mod?
                                 8.0e+04 2.6e+04 l.Se+01 y  n
                                 8.0e+04 2.6e+04 2.7e+01 y  n
                                                                                                        117

-------
OPUSquan   20-JUL-1998
                   Page  4
                                                                   Page  8 of 8

 Ent: 46 Name: Total Hepta-Dioxins F:4  Mass:  423.777 425.774 Mod? no   *Horn:5

 Run: 18 File: al7ju!98b    S:13 Acq:18-JUL-98 01:47:01 Proc:20-JUL-98  09:08:26
 Tables: Run: al7ju!98b  Analyte: m8290-23-»  Cal:  m8290-23-»Results: M8290-23*
 Version: V3.5 17-APR-1997 11:14:34  Sample text:  1070-4 xl/2
   Amount: 0.15
     Cone: 0.15
   Tox #1: -
Name
of which 0.08
of which 0.08
     Tox #2: -

#     RT Respnse
named and 0.07
named and 0.07
      Tox t3:  -
                                        RA
                   1  36:22 3.4e+04  6.09 n
                            3.4e+04

                   2  36:35 7.7e+04  1.21 n
                            7.7e+04

                   3  36:42 8.1e+03  0.74 n
                            8.1e+03

l,2,3,4,6,7,8-HpCDD4  37:11 1.5e+05  1.05 y
                            1.5e+05

                   5  37:32 3.0e+04  4.70 n
                            3.0e+04
          Cone

           0.02

               4
           0.04
               4

           0.00
               3
               4
           0.08
               7
               1
           0.02
unnamed
unnamed
Area  Height    S/N  Mod?
                                2.9e+04 9.1e+03 7.7e+00 y  n
                                4.8e+03 1.8e+03 2.3e+00 n  n
                               I
                                4.2e+04 1.2e+04 l.Oe+01 y  n
                                3.5e+04 l.Oe+04 1.3e+01 y  n
                                3.4e+03 1.3e+03  l.le+00 n  n
                                4.7e+03 1.3e+03  1.6e+00 n  n
                               3
                                7.9e+04 2.3e+04  1.9e+01 y  n
                                 .4e+04 2.2e+04  2.8e+01 y  n

                                2.5e+04 6.1e+03  S.le+00 y  n
                                5.2e+03 2.1e+03  2.6e+00 n  n
                                                                                                         118

-------
J.-V
File: A17JUL98B Acq: 18-JUL-1998 01:47:01 Exp: EXP M23 DBS OVATION Voltage SIR EI+ Gc Autospec-UltimaE Paradigm
Sample #13 Text: 1070-4 xl/2 ALS #13
319.8965 S:13 SMO(1,3) BSUB(128 , 15, -3 . 0) PKD(3 , 3 , 3 , 0 . 10%, 1248 . 0 , 1 . 00%, F, F)
100% A6.60E4 1.5E4
50_
0
321.
100S
50:
o;
331.
100%
o-
333.
100!
50:
o"
327.
100%
50:
o:
316.
lOOi
50:
o:

i i i i I i
24:00
8936 S:13 SMO(1,3)


24 loo'
9368 S:13 SMO(1,3)

	 24 :00'
9339 S:13 SMO(1,3)

1 ™i— r i -i — i — "i r
24:00
8847 S:13 SMO(1,3)

24:00'
9824 S:13 SMO{1,3)
23:26 23:55
/ 	 	 	
	 24 :00'
A1.47E4
25:00 26:00
BSUB{128,15,-3.0) PKD(3,3,3,0.

A8.80E3
25 100 	 26^00
BSUB(128,15,-3.0) PKD(3,3,3,0.

•25 loo' ' 26 loo'
BSUB(128,15,-3.0) PKD(3,3,3,0.

25 !00 26:00
BSUB(128,15,-3.0) PKD(3,3,3,0.

25100 26100
PKD{3,3,3,100.00%,0.0,1.00%,F,
24:37 24:5925:20 25:43

	 1 	 V "T 	 ' ' 1 	 1
25:00 26:00
/ 1 A4 . 15E4
L7.7E3
LO.OEO
27 100 28 100 	 29 loO 	 3oSoO Time
10%,1328.0,1.00%,F,F)
A2.41E5 ,_4.6E4
A F
A
	 _A_ 	 _,_
27 loo' ' 28 loo' 29 loo' ' 30 !(
10%, 8376. 0,1. 00%, F,F)
A1.60E8
A A
HA
.2 . 3E4
O.OEO
)0 Time
3.3E7
.1.6E7 "
.O.OEO
27 100 28 100 29 100 30:00 Time
10%, 4732. 0,1. 00%, F,F)
A2.03E8 _4.1E7
A A F

.2 . 1E7
.O.OEO
27:00 ' 28 100 29:00 30:00 Time
10%,4996.0,1.00%,F,F)
A3.04E8 _6.2E7
A
A
L3.1E7
-O.OEO
27100 28100 29:00 30:00 Time
F)
26:3626:56 27:27 27:51 28:2728:47 29:11 29:39 6.1E7

_3.0E7
.O.OEO
27 loO ' 28 loO 29 loO ' 30:00 Time

-------
 Pile:  A17JUL98B  Acq:  18-JUL-1998 01:47:01Exp;  EXP_M23_DB5_OVATIOU Voltage SIR EI+  GC Autospec-UlbimaE  Paradigm
 Sample #13  Text: 1070-4 xl/2  ALS #13
 355.8546 S:13 F:2 SMO(1,3)  BSUB(128,15,-3.0)  PKD(3,3,3,0.10%,2324.0,1.00%,F,F)
 100%                                                                           A3.55E4                           1.5E4
                                                                A3.04E4
                                                                                   / I                             I
                                                                                                                 .7.4E3
                             I i i i i i  I i i i i i I	I i i i i  i I i i i i i  I i i i i i I i  i i i i I	i i i i i  i i i i i i i  i 'i i i i i i  i i i i i i
      30:12  30:24  30:36  30:48  31:00  31:12  31:24  31:36  31:48  32:00  32:12  32:24  32:36  32i48  33:00  33:12    Tim.
357.8517 S:13 F:2 SMO(1,3) BSUB(128,15,-3.0) PKD(3,3,3,0.10%,1280.0,1.00%,F,F)
100%
                                                                 A1.38E4

 so:
  OJ
                                                                                       A7.97E3
                          _6.0E3
                                                                                                                 _3. OE3
                           .O.OEO
      30:12  30:24  30:36  30:48  31:00  31:12  31:24  31:36  31:48  32iOO  32:12  32:24  32:36 ' 32:48 ' 33166 ' 33:12
                              Time
367.8949 S:13 F:2 SMO(1,3)  BSUB(128,15,-3.0)  PKD(3,3,3,0.10%,3272.0,1.00%,F,F)
100%
 so:
A1.59E8
                                                                                                                 ..5.6E7
                          _2.8E7
                                                                                                                  0. OEO
     30:12  30:24  30:36  30:48  31:00  31:12  31:24  31:26  3ll48  32166  32112  32:24  32l36  32l48  33166  33:12    Time
369.8919 S:13 F:2 SMO(1,3) BSUB(128,15,-3.0) PKD(3,3,3,0.10%,1856.0,1.00%,F,F)
100%                                                                                   A1.P2E8                   _3.6E7
 50_
                          .1.8E7
                                                                                                                  O.OEO
     30:12  30:24  30:36  30:48  31:00  31:12  31:24  31J36  31i48   32iOO  32-12  32:24  32-36 ' 32:48 ' 33166 ' 33:12     Time
366.9792 S:13 F:2 SMO(1,3) PKD(3,3,3,100.00%,0.0,1.00%,F,F)
100%      30:20	30:42      31:00      31 jlg__3j,:32   31:47_   32:04
 50_
         32^51   ,31:06
                                                                                                                 .6.6E7
                          _3.3E7
                                                                                                                  O.OEO
     30:12  30:24  30:36  30:48  31:00  31:12  31:24  31:36 ' 3J.148 ' 32166 ' 32:12 ' 32:24  32136 '  32:48 ' 33:66 ' 33:12    Time

-------



























10
Pile: A17JUL98B Acq:
18-JUL-1998 01:47:01 — Exp: EXP_M23_DB5_OVATlON Voltage SIR EH- GC Autospec-UltimaE Paradigm
Sample #13 Text: 1070-4 xl/2 ALS #13
389.8156 S:13 F:3 SMO(1,3) BSUB (128, 15, -3 . 0)
100%,
50J
-




,-v ^ 	 ^
33:24 33:36
A6.70E4
A A

A / 1
— ' \ _ 	 / 1
33:48 34:00 34:12
391.8127 S:13 F:3 SMO(1,3) BSUBU28, 15, -3 . 0)
100%

so:
-




-- — -^^^~^s^\^s~^~\.
01 . 1 1 	 	
33:24 33:36

A2.71E4
A1.89E4 A
A A,
\ / v

33:48 34:00 34:12
401.8559 S:13 F:3 BSUB(128, 15, -3 . 0) PKD(3,5,2
100%
so:




33:24 33:36
403.
100%
so:




33:48 34:00 34:12
8530 S:13 F:3 BSUB(128, 15, -3 . 0) PKD(3,5,2


33:24 33:36
380.
100%
so:
0 '


33:48 34:00 34:12
9760 S:13 F:3 SMO(1,3) PKD(3, 3, 3, 100 .00%,
33:23 33:47
/


. ' 1 1 I 1 1 1 1 1 1 1 1 1
' 33:24 33:36



'saSaV ' 34IOO 34!l2
PKD( 3, 5, 2 ,0.10%, 2304. 0,1. 00%

k4.02E4 A3.62E4
\J\ ~/\
I V£^^^/ | A2^
34:24 34:36 34:48
PKD (3,5,2,0.10%, 1824 .0,1.00%

A2.19E4
A l\
A /A
W \A5 . 20E3 A-LA
J VS^\_ sS^J 	 ^-c:
34J24 34^36 34:48
, 0.10%, 10884. 0,1. 00%, F,F)
Al . 58E8
A
M
n\-
34124 34136 34Us
, 0.10%, 6960. 0,1. 00%, F,F)
A1.25E8
A
M
/1V_
34! 24 34! 36 34 1 48
0.0,1.00%,F,F)
34:19 34:38 34:47



34124 34:36 34:48
,F,F) ^ ^t

A4.44E4
A
7 V A1.03E4 A5.67E3
Lr ^~-^S~^~/"^~^~^r~^ —s~^s~^~^s | i-"^
— *
_1.2E4
_
•O.OEO
35IOO 35!l2 35:24 35:36 35.48 Time
,F,F)
A3.99E4 ,_1.1E4
A
\\

.JI^Nw^^NX^N^~x./ v-/ *> 	 ' ^~^-^.

.5.7E3

O.OEO
35:00 35:12 35:24 35:36 35:48 Time

A1.68E8
A
A
/ V_
b.bE/
.3.3E7
' 0 . OEO
35 !00 35:12 35I24 35136 35:48 Time
A1.34E8
A
A
/ V
5.2E7
.2 . 6E7
' O.OEO
35!00 35:12 35:24 35:36 35:48 Time
35:03 35:16 35:32
I/


1.4E8
L7.2E7
•O.OEO
35:00 35:12 35:24 35:36 35:48 Time

-------
I
Pile
Samj
423.
100§
50.
0
425.
1001
so:
OJ
435.
100%
so:
0'
437.
100%
so:
430.
100%
so:
0'
;: A17JUL986 Acq: 18-JUL-1998 01:47:01
>le #13 Text: 1070-4 xl/2 ALS #13
7767 S:13 F:4 SMO(1,3) BSUB(128, 15, -3 .0)
A4.21E4
JL_A 	
36:00 36:12 36124 36136 36:48 37:
7737 S:13 F:4 SMO(1,3) BSUB < 128 , 15, -3 . 0)
A3.47E4
A4.77E3 /A^65E3
36:66 36ll2 36124 36136 36l48 37 1
8169 S:13 F:4 SMO(1,3) BSUB (128, 15, -3 . 0)

36166 36ll2 36124 3el36 SeUs 37 1
8140 S:13 F:4 SMO(1,3) BSUB(128, 15, -3 . 0)

36:66 36112 36124 36:36 36l48 37 1
9728 S:13 F:4 SMO(1,3) PKD(3, 3, 3, 100 . 00%
35:56 36:0936:19 36:31 36:4636:55
/-
fixp: EXP_M23_DB5
PKD(3,3,3,0.10%
A7 . 85E4
_iL^
00 37:12 37:24
PKD(3,3,3,0.10%
A7.44E4
A
A
. /i -
66 37li2 37124
PKD(3,3,3,0.10%
Al . 14E8
R.
66 37li2 37124
PKD{3,3,3,0.10%
Al . 08E8
/^
66 37l 12 37l 24
,0.0,1.00%,F,F)
37:11 37^

" -r-r T -!-¥• i— r i T i i'T"i r i i | i i i i i i i i i i i 1 i i i i i i i i i i i 1 i i i i i i i i
36100 36:12 36124 36:36 36:48 37:00 37:12 37:24
_OVATI6N Voltage Sift E1+ 6C Autospec-ttttimaE Paradigm
,1184.0,1.00%,F,F)
2.4E4
.46E4
^7-36 37:48 38166 38112 38124 38136 38148 391
,796.0,1.00%,F,F)

.24E3
3711637148 38166 3s!l2 38124 38136 SsUs 39l
,5712.0,1.00%,F,F)

37136 37148 38166 38ll2 38124 38136 38l48 39:
,2768.0,1.00%,F,F)

_1.2E4
_O.OEO
00 Time
2.3E4
.1.1E4
.0 . OEO
00 Time
3 . OE7
_1 . 5E7
O.OEO
00 Time
2 . 9E7
_1 . 5E7
10. OEO
37136 37148 38166 38112 38:24 38:36 SsUs 39:00 Time
29 37:40 37:50 38:02 38:13 3Bt2« 38:47 9 . 4E7

.4.7E7
.0 . OEO
' 37136 ' 37148 ' 38lo6 38:12 38:24 ' 38:36 ' 38:48 39100 Time

-------
File: A17JUL98B Acq: 18-JUL-1998 01:4
Sample #13 Text: 1070-4 xl/2 ALS #13
457.7377 S:13 F:5 SMO(1,3) BSUB(128,15
100%
50.
0
459.
1003
50J
0"
469.
100%
so:
0'
471.
100%
so:
0'
454.
100!
so:
o:

39ll2 39124 39136
7348 S:13 F:5 SMO{1,3) BSUB(128,15


39ll2 39124 39136
7780 S:13 F:5 SMO(1,3) BSUB(128,15

39ll2 39124 39136
7750 S:13 F:5 SMO(1,3) BSUB(128,15

7:01 Exp: fiXP_M23_DB5_OvAf ION Voltage SIR EI+ <5C Autospec-UltimaE Paradigm
,-3.0) PKD(3,3,3,0.10%,3224.0,1.00%,F,F)
Al . 87E5 5 . OE4
______J\^ 	
39:48 4olob 40:12 40:24 40:36 40:48 41:
,-3.0) PKD(3,3,3,0.10%,1048.0,1.00%,F,F)
A2 . 02E5
A
J \ 	 A5 .J9E3
39:48 4olob 4oll2 4ol24 4ol36 40:48 41:
,-3.0) PKD(3,3,3,0.10%,2608.0,1.00%,F,F)
Al . 51E8
j\_
39148 40 lob 4oll2 4ol24 40.-36 4ol48 41:
,-3.0) PKD(3,3,3,0.10%,2528.0,1.00%,F,F)
Al . 72E8
/v
_2 . 5E4
O.OEO
00 Time
4.9E4
.2.4E4
00 Time
3.4E7
.1.7E7
O.OEO
00 Time
3.9E7
_1 . 9E7
_O.OEO
39ll2 39124 39136 39148 4olob 4oll2 4ol24 40J36 40J48 4lloO Time
9728 S:13 F:5 SMO(1,3) PKD(3 , 3 , 3 , 100 . 00%, 0 . 0, 1 . 00%, F, F)
39:09 39:18 39:24 39:33 39:44 40:0540-10 40:25 40.-3-540:41 40.-49 40:56 1 . OE8

39ll2 3V:24 39136

_5.2E7
_O.OEO
39 148 40 lob 40:12 4ol24 40J36 40:48 41:00 Time
H.
to

-------
IS'
     Pile: A17JUL98B  Acq: 18-.TOL-1998 01:47:01  Exp: EXP_M23_DB5_OVATI6N Voltage SIR EI+  GC Autospec-UltimaE  Paradigm
     Sample #13  Text: 1070-4 xl/2  ALS #13
     303.9016 S:13 SMO(1,3) BSUB(128,15,-3.0) PKD(3,3,3,0.10%, 1628.0,1.00%, P,F)
     100%                                                                A3.30E4
                      24:00           25100          26iOO          27iOO
     305.8987 S:13 SMO(1,3)  BSUB(128,15,-3.0) PKD(3,3,3,0.10%,2644.0,1.00%,F,F)
     100&                                                                A3.04E4
                                              28:00
                     24JOO           25100          26:00          27iOO
     315.9419 S:13 SMO(1,3)  BSUB(128,15,-3.0)  PKD(3,3,3,0.10%,4384.0,1.00%,F,F)
     100ft                                                                A1.92E8
                                                             29:00
       O
                                                     30:00   Tim<

                                                          1.1E4

                                                         _5.6E3

                                                          O.OEO
                                                     30:00   Tim<

                                                          3. 9E7

                                                         .1.9E7

                                                         LO.OEO
                     24:00           25:00           26:00          27:00
     317.9389 S:13  SMO(1,3)  BSUB(128,15,-3.0)  PKD(3,3, 3 , 0.10%,3748.0,1.00%,F,F)
     100ft                                                               A2.46E8
                                              28:00
                                     29:00

24 loo'

25100 26100 27:00 28:00 29:00 30:0
     375.8364  S:13  SMO(1,3)  BSUB(128,15,-3.0)  PKD(3,3,3,100.00%,44.0,1.00%,F,F)
     100ft
      50.
       OJ
                                                     28;27
                                                28:10
           23:23
                     ,,  co
                     23 : 58
25:00

   /v, A
                                   -0^
                                                   25:55
26:35       27:20  27:47
        .5^ AA  ,
                     24:00          25:00           26:00
     16.9824 S:13 SMO(1,3)  PKD(3,3,3,100.00%,0.0,1.00%,F,F)
                               24:37 24:5925:20  25:43
                              27:00
                                                                                                  29:03
           29:43
                30:00  Time

                   r5.0E7

                   .2.5E7

                    O.OEO
    -7.4E3

    _3.7E3

     0 . OEO
                      28:00
29iOO
30 00  Time

     6.1E7

24:00 25:00 26:00 27:00 28:00 29:00 30:C
L3 . OE7
10 . OEO
10 Time

-------
    File: A17JUL98B—Acq: 18-JuL-1998 01:47:01—Exp: EXP_M23_DB5_OVATlON Voltage SIR EI+  GC Autospec-UltimaE  Paradigm
    Sample #13  Text: 1070-4 xl/2  ALS #13
    339.8597 S:13 F:2 SMO(1,3) BSUB(128,15,-3.0) PKD(3,3,3,0.10%,976.0,1.00%,F,F)
                                                                                    A2.20E4                          ^_9.6E3
1004

 50 j
      0.
                                                A1.26E4
                                                                 A1.10E4
                                                                                                      A2.80E3
^4 . 8E3

10.0EO
         I I  I | I I I I I  I I I I I I  I I I I I I I I  I I I |X I I  I I I I I I I I  I I I I f I I	I I  I I I I I I I  I I I I I l'T""f I I              ,      ,       .
         30ll2  30124  30!36  30148   3l!oO   3l!l2  31:24  31:36  31:48  32:00   32:12   32:24  32:36  32:48  33:00  33:12
    341.8568 S:13 F:2 SMO(1,3) BSUB(128,15,-3.0) PKD(3,3,3,0.10%,2320.0,1.00%,F,F)
    100*
                                                A9.39E3
     50J
                                                                                                    A1.03E4
                36124 ' 36!36 ' 30:48 ' 3l!6o '  3lll2  3ll24  3ll36  3i:48  32lOO  32ll2  32i24  32136  32i48  33iOO  33il2
    351.9000 S:13 F:2 SMO(1,3) BSUB(128,15,-3.0) PKD(3,3,3,0.10%,1768.0,1.00%,F,F)
    100%                                                            A2.16E8         A2.08E8                          _7
     50
                                                                                             T
                                                                                                                  _3

                                                                                                                  0
    Time

  .6E3

  ,8E3

  . OEO
    Time

  .6E7

  .8E7

  .OEO
    Time

  .9E7

  .4E7

  .OEO
    Time


    'i i i  i i i i i i i  i i i i i i  i i i i i i i  i i i i i i i  i i i i i i i i' i i ii    .       .       .       ,       ,
     30:12  30:24  30:36  30:48  31:00   31:12  31:24  31:36  31:48  32:00  32:12  32:24   32:36
353.8970 S:13 F:2 SMO(1,3) BSUB(128,15,-3.0) PKD(3,3,3,0.10%,2480.0,1.00%,F,F)
                                                                A1.38E8         A1.33E8
                                                                                                         33     33l2
     50
      OJ

                                                                                                         33IOO ' 33l2
                                                                                                                  4,

                                                                                                                  L2,

                                                                                                                  Lo.

            36!24 ' 36136 ' 30U8  3lloO  3l!l2  3ll24  31:36  31:48  32!00  32 = 12  32i24   32i36
409.7974 S:13 F:2 SMO(1,3) BSUB(128,15,-3.0) PKD(3,3,3,100.00%,3692.0,1.00%,F,F)
100%                                                                                      32'40

                                        31-13 31:23    31:40           32:07       32:28
    L/VS^JO^-V V.   30:59   31.13
      U~\...f .......,,.—i—i •! i r j—p-,
                30:24  30:36
    366.9792 S:13 F:2 SMO(1,3) PKD(3,3,3,100.00%,0.0,1.00%,F,F)
    100%      30:20	_30j42	31^00	31:19   31:32   31:47     32^04.
     50J
                                                                                               J3i5l ...33;Q6.
  .6E7

  .3E7

  .OEO
    Time
     50J
      OJ
                                                                                                                     13
         36!i2 ' 36J24 ' 36J36 ' 30148 ' 3J!o6 ' 3lSl2 ' 3J.'24 ' 3JI36 ' 3J!48 ' 32J66 ' 321J2 ' 32J24 ' 32J36 ' 32I48 ' 33!66 ' 33T12
f.T

-------
Pile; A17JUL98B Acq: 18-JUL-199t) 01:47:01 Exp: EXP_M23_DBb_OVATiON
Sample #13 Text: 1070-4 xl/2 ALS #13
373.8207 S:13 F:3 SMO(1,3) BSUB (128 , 15, -3 . 0) PKD(3 , 5, 2 , 0 . 10%, 2336 . 0,
100% A3.27E4
^ /CS1 U 35E3 VlV
'33124' ' '33!36' ' 's'sUV ' '34loO 34J12 34124 34136 34
375.8178 S:13 F:3 SMO{1,3) BSUB(128, 15, -3 .0) PKD{3 , 5,2, 0 .10%, 1532 .0,
100% A2.85E4
SOl A9.13E3 A
; A / V \ A6.01E3 A2 g
n:^\-^^A__~^ 	 ^^< 1 V-^ 	 	 ^Vx-^A^S
u— 1— i — i— i — i — ii i — i — i — i — i — i — i — i — i — r — l — I — I — i — 1 — I — l — > — I — i — 1 r— I I I i | l i i P I | 1 I ' i r-
33:24 33:36 33i48 34:00 34:12 34:24 34:36 34
383.8639 S:13 F:3 BSUB(128, 15, -3 . 0) PKD(3, 5, 2, 0. 10%, 37376 .0, 1 . 00%, F,
100% A1.18E8
"1 M
' 33:24' ' '33-36 ' YsU's 34!oO 34ll2 34?24 34^36 34
385.8610 S-.13 F-.3 BSUB(128, 15, -3 .0) PKD(3 , 5,2, 0 .10%, 48152 .0, 1 . 00%, F,
100% A2.25E8
"1 A/I
Voltage SIR Ei+ GC Autospec-UltimaE Parad.
1.00%,F,F)
^^-^^^/~~- 	 v^ — ^^ 	 *. — 	 	 ^~^/\^~ 	 ^_
Us 35:00 35:12 35:24 35:36 35:
1.00%,F,F)
OE3 A2 'J|^ ^i^?3 A2JL5E3 ^^
148 35:00 35!l2 35!24 35:36 35:
F)
Us 35!00 35ll2 35:24 35:36 35:
F)
Vs^V ' 133\36 ' ' 33:48' ' '34:00 ' ' '34!l2' ' 34124' 34136 34:48 35IOO 35ll2 35:24 35:36 35:
445.7555 S:13 F:3 SMO{1,3) BSUB(128, 15, -3 .0) PKD(3, 3,3, 100 . 00%, 1852 .0, 1.00%, F,F)
100% 33:37 34:46 34:59
: l\ r\J\ \ 35:32
5°- - 33:3^ \ 33.51 34:01 34:11 34^22 3^3i^J \^^J \^y\^^J\y\J\f^
'33:2'4' ' -'33:36' ' I33:4I81 34loO 34!l2 34J24 34136 34
380.9760 S:13 F:3 SMO(1,3) PKD(3,3, 3, 100. 00%, 0.0,1. 00%, F,F)
100% T?-7^ 33:47 34:19 34:38 34_I
50J
' 33:24' ' '33:36' ' 33U8 34loO 34ll2 34124 34136 34
igm
1.3E4
.6.3E3
LO . OEO
48 Time
1.1E4
15 . 6E3
LO.OEO
48 Time
5.2E7
.2 . 6E7
_O.OEO
48 Time
1 . OE8
.5 . OE7
_O.OEO
48 Time
8 . 1E3
i.4 . 1E3
I.O.OEO
T48 35:00 35:12 35:24 35:36 35:48 Time
47 35:03 35.16 35:32 1 . 4E8
U
.7.2E7
_O.OEO
J48 35100 35ll2 35:24 35:36 35:48 Time

-------
File: A17JUL98B  Acq:  18-JOL-1998  01:47:01—Exp: EXP_M23_DB5_OVATION Voltage SIR EI+  GC Autospec-UitimaE
Sample  #13  Text:  1070-4  xl/2  ALS #13
407.7818 S:13 F:4  SMO(1,3)  BSUB(128,15,-3.0) PKD(3,3,3,0.10%,1688.0,1.00%,F,F)
100%,               A8.Q1E4
       36:00  36:12  36:24  36:36  36:48  37:00  37:12  37:24  37:36  37:48  38:00  38:12  38:24  38:36  38:
409.7788 S:13 F:4 SMO(1,3)  BSUB(128,15,-3.0) PKD(3,3,3,0.10%,980.0,1.00%,F,F)
100%               A8.05E4
 50J

  ol
A6.05E3
417.8253 S:13 F:4 SMO(1,3) BSUB(128,15,-3.0) PKD(3,3,3,0.10%,4796.0,1.00%,F,F)
100%              A5.13E7

                                                          A3.26E7
Paradigm
2 . 8E4

— ,-~~
1 1 1 1 1 I
48 39:


	 **"•*.
I ™ 1 III
48 39:


48 ' 39!


48 39:

Vx^
48 39!
47

48 39:
:l.4E4
_O.OEO
00 Time
2.7E4
.1 . 4E4
_O.OEO
00 Time
1.6E7
17.8E6
O.OEO
00 Time
3 . 5E7
Ll.7E7
: O.OEO
00 Time
7.7E3
_3 . 9E3
O.OEO
00 Time
..9.4E7
_4.7E7
O.OEO
00 Time
       36:6d ' 36:12 ' 36:24  36:36 '  36:48  37:00  37:12  37:24  37:36  37:48  38:00  38:12  38:24  38:36  38:48  39:00  Time
419.8220 S:13 F:4 SMO(1,3) BSUB(128,15,-3 . 0) PKD(3,3,3,0.10%,23640.0,1.00%,F,F)
100%              A1.16E8
 50_

  0
                                                          A7.43E7
       36:00  36:12  36:24  36:36  36:48  37:00  37:12  37:24  37:36  37:48  38:00  38:12  38:24  38:36  38:48  39:00  Time
479.7165 S:13 F:4 SMO(1,3) BSUB(128,15,-3.0) PKD(3,3,3,100.00%,2348.0,1.00%,F,F)
100%                                           37^10 37-21
                        36:30           36:58
                                                                                         38:25
                                                                                                    38:43
       36!66 ' 36!l2  36:24  36:36  36:48  37:00  37:12  37:24  37:36   37:48  38:00  38:12  38:24  38:36  38:48  39:00  Time
430.9728 S:13 F:4 SMO(1,3) PKD{3,3,3,100.00%,0.0,1.00%,F,F)
100% 35:56  36:09 36;19  36:3136:41    36:55    37:11   	37:34     37:50   38:02  38:13	ia^2fi	•
 50J
  Oj
       36:00 ' 36:12 '"36:24 '  36:36  36:48  37:00  37:12  37:24   37:36  37:48  38:00  38:12  38:24  38:36  38i48   39:00  Time

-------
File: A17JUL98B
Sample #13 Text:
441.7427 S:13 F:5
100%
50_
0-
443.
1003
50 j
0:
469.
100%
50j
o:
471.
100%
50 j
0:
513.
1003
50J
o.:
454.
100%
50 j
OJ
A2 . 09E3
^*l 1 ""'I I ™~| '~1 i'
39:12
7398 S:13 F:5
-> 	 -- — »»__^
39ll2
7780 S:13 F:5

39:12
7750 S:13 F:5

39Sl2
6775 S:13 F:5
Acq: 18-JUL-1998 01:47:01 Exp: EXP M23 DBS OVATION Voltage SIR EH- GC Autospec-UltimaE Paradigm
1070-4 xl/2 ALS #13
SMO(1,3) BSUB(128,15,-3.0) PKD(3 , 3 , 3 , 0 . 10%, 800 . 0 , 1 . 00%, F, F)
A5.69E4 1.3E4
• 	 • — *. — — *• 	 . 	 • 	 	 	
SMO(1,3) BSUB(128,15,-3
— > 	 	 	 • — 	 	 	 	 	 — . 	
i i i 1 1 1 1 1 < i i i i
39:24 39:36
SMO(1,3) BSUB(128,15,-3

39124 39136
SMO(1,3) BSUB(128,15,-3

39124 39136
SMO(1.3) BSUB(128,15,-3
39U;9 39:25 39:33 39:
v^ A_/x r\ ^
39:12
9728 S:13 F:5
39:09 19
/
39ll2
/ ^V aJ729 79 A2.86E3
39 Us 40|00 40-!l2 4ol24 4o!36 40148 41
.0) PKD(3,3,3,0.10%/1660.0,1.00%,F,F)
A6.28E4
_____J\_^ 	 ^____
L6.7E3
00 Time
1.9E4
19.5E3
• o.OEO
igUtT 4oTob 4o!l2 4o!24 4oT36 4ol48 4^1 -00 Time
.0) PKD(3,3,3,0.10%,2608.0,1.00%,F,F)
Al . 51E8 3 . 4E7
y\_
Ll.7E7
L.O.OEO
39148 4o!ob 4o!l2 4o!24 4o!36 40:48 41 00 Time
.0) PKD(3,3,3,0.10%,2528.0,1.00%,F,F)
Al . 72E8 3 . 9E7
/v_
Ll . 9E7
_O.OEO
39Us 4o!ob 40ll2 40:24 40J36 40 1-48 41:00 Time
.0) PKD(3,3,3,100.00%,88.0,1.00%,F/F)
40:02 5.5E3
39-53 / \ 4°:2° 40:36
39:24 39:36 39:48 4o!ob 40:12 40:24 40:36 4o!48 4l!
SMO(1,3) PKD(3,3,3,100.00%,0.0,1.00%,F,F)
:18 39:24 39:33 39:44 40:0540-10 40:25 40:3540:41 40-49 40:56

39:24 39:36

39:48 40:00 40:12 40:24 40:36 40:48 41:
12 . 8E3
•O.OEO
00 Time
1.0E8
.5.2E7
O.OEO
00 Time

-------
           APPENDIX C




CALCULATIONS & COMPUTER SUMMARIES

-------
          Appendix C.I




Calculations & Computer Summaries




           Kiln No. 3

-------
Summary of Stack Gas Parameters and Test Results
Air Emissions Screening Test
Austin White Lime Company - Austin, Texas
US EPA Test Method 2 - Volumetric Air Flow Rates
Kiln No. 3 Baghouse Stacks
Page 1 of 1




Pstatic
Pbar
C-
Dp1*
T,
CO2
02
N2

Dia

PS
Bws
1-Bws
Md
Ms
V8
A
Qa
Qs
Qs
8 Tabulated
STACK ID
RUN DATE
RUN TIME
MEASURED DATA
Stack Static Pressure, inches H2O
Barometric Pressure, inches Hg
Pitot Tube Coefficient
Average Square Root Dp, (in. H2O)1/2
Average Stack Temperature, °F
Carbon Dioxide content, % by volume b
Oxygen content, % by volume b
Nitrogen content, % by volume
Moisture, % b
Stack Diameter, inches:
CALCULATED DATA
Stack Pressure, inches Hg
Moisture, % by volume
Dry Mole Fraction
Molecular Weight (d.b.), Ib/lb-mole
Molecular Weight (w.b.), lb/lb«mole
Stack Gas Velocity, ft/s
Stack Area, ft2
Stack Gas Volumetric flow, acfm
Stack Gas Volumetric flow, dscfm
Stack Gas Volumetric flow, dscmm
results are for Run M23-O-3.
" O2 and C02 values are from the OEMs testing at South 2
South 1
6/30/98
0850

-0.11
29.54
0.84
0.2700
365.5
18.0
10.7
71.3
10.06
37.00

29.53
10.06
0.899
31.31
29.97
18.7
7.47
8,389
4,761
135

Stack while
South 2
6/30/98
0856

-0.08
29.54
0.84
0.3037
366.5
18.0
10.7
71.3
10.06
37.00

29.53
10.06
0.899
31.31
29.97
21.1
7.47
9,442
5,353
152

the moisture
South 3
6/30/98
0904

-0.08
29.54
0.84
0.3262
371.4
18.0
10.7
71.3
10.06
37.00

29.53
10.06
0.899
31.31
29.97
22.7
7.47
10,171
5,732
162

is from the
South 4
6/30/98
0910

-0.08
29.54
0.84
0.3649
364.5
18.0
10.7
71.3
10.06
37.00

29.53
10.06
0.899
31.31
29.97
25.3
7.47
11,330
6,439
182


North 1
6/30/98
0920

-0.16
29.54
0.84
0.3999
383.6
18.0
10.7
71.3
10.06
37.00

29.53
10.06
0.899
31.31
29.97
28.0
7.47
12,562
6,976
198


North 2
6/30/98
0925

-0.10
29.54
0.84
0.3197
378.4
18.0
10.7
71.3
10.06
37.00

29.53
10.06
0.899
31.31
29.97
22.3
7.47
10,010
5,595
158


PCDDs/PCDFs testing at North 3 Stack (Run M23-0-3).
North 3 *
6/30/98
1247-1612

-0.22
29.54
0.84
0.4169
400.6
18.0
10.7
71.3
10.06
37.00

29.52
10.06
0.899
31.31
29.97
29.5
7.47
13,228
7,200
204

North 4
6/30/98
1414

-0.01
29.54
0.84
0.1459
311.1
18.0
10.7
71.3
10.06
37.00

29.54
10.06
0.899
31.31
29.97
9.8
7.47
4,381
2,663
75
Fotal ACFM
Total DSCFM
Total DSCMM
8-Stacks
Total/
Average

-0.11
29.54
0.84
0.3184
368
18.0
10.7
71.3
10.06
37.00

29.53
10.06
0.899
31.31
29.97
22.2
7.47
9,939
5,590
158
79,512
44,718
1,266

-------
Summary of Stack Gas Parameters and Test Results
            Air Emissions Screening Test
    Austin White Lime Company - Austin, Texas
      US EPA Test Method 23 - PCDDs / PCDFs
                Kiln # 3 Baghouse Inlet
                      Page 1  of 6
          RUN NUMBER
          RUN DATE
          RUN TIME
 M23-I-3
 6/30/98
1248-1605
          MEASURED DATA
   y      Meter Box Correction Factor                 1.021
  AH      Avg Meter Orifice Pressure, in. H2O           1.382
  Pbar     Barometric Pressure, inches Hg              29.54
  Vm      Sample Volume, ft3                      114.293
  Tm      Average Meter Temperature, °F             102.92
 Pstatic     Stack Static Pressure, inches H2O           -20.00
  Ts      Average Stack Temperature, °F              429.9
  V|C      Condensate Collected, ml                   280.6
  CO2     Carbon Dioxide content, % by volume          19.2
  02      Oxygen content, % by volume                  9.5
  N2      Nitrogen content, % by volume                71.3
  Cp      Pitot Tube Coefficient                       0.84
 Ap1/2     Average Square Root Ap, (in. H2O)1/2         0.7493
   0      Sample Run Duration, minutes                 180
  Dn      Nozzle Diameter, inches                    0.256

          CALCULATED DATA
  Ap      Nozzle Area, ft2                         0.00036
 Vm(std)     Standard Meter Volume, dscf              108.393
Vm(std)m3    Standard Meter Volume, dscm               3.069
   Ps      Stack Pressure, inches Hg                  28.07
  Bws     Moisture, % by volume                     10.86
  Vwstd     Standard Water Vapor Volume, ft3           13.208
 1-Bw,     Dry Mole Fraction                        0.8914
  Md      Molecular Weight (d.b.), lb/lb«mole            31.45
  M,      Molecular Weight (w.b.), Ib/lb-mole           29.99
  V,      Stack Gas Velocity, ft/s                     55.32
   A      Stack Area, ft2                           23.552
  Qa      Stack Gas Volumetric flow, acfm            78,176
  Q,      Stack Gas Volumetric flow, dscfm           38,773
 Q«cmm)    Stack Gas Volumetric flow, dscmm            1,098
   I      Isokinetic Sampling Ratio, %                 102.4

-------
   Summary of Stack Gas Parameters and Test Results
       Austin White Lime Company - Austin, Texas
         US EPA Test Method 23 - PCDDs / PCDFs
                  Kiln # 3 Baghouse Inlet
                         Page 2 of 6
             RUN NUMBER
             RUN DATE
             RUN TIME
 M23-I-3
 6/30/98
1248-1605
             EMISSIONS DATA

             DIOXINS:

             2378 TCDD
     ng      Catch, ng                             {0.00309}
   ng/dscm   Concentration, ng/dscm, as measured      {0.00101}
    ug/hr     Emission Rate, ug/hr                     {0.0663}

             Total TCDD
     ng      Catch, ng                              {0.0115}
   ng/dscm   Concentration, ng/dscm, as measured      {0.00375}
    ug/hr     Emission Rate, ug/hr                      {0.247}

             12378 PeCDD
     ng      Catch, ng                               0.0006
   ng/dscm   Concentration, ng/dscm, as measured      0.000195
    ug/hr     Emission Rate, ug/hr                      0.0129

             Total  PeCDD
     ng      Catch, ng                               0.0036
   ng/dscm   Concentration, ng/dscm, as measured       0.00117
    ug/hr     Emission Rate, ug/hr                      0.0773

             123478 HxCDD
     ng      Catch, ng                              (0.0008)
   ng/dscm   Concentration, ng/dscm, as measured      (0.000261)
    ug/hr     Emission Rate, ug/hr                    (0.0172)

             123678 HxCDD
     ng      Catch, ng                             {0.00156}
   ng/dscm   Concentration, ng/dscm, as measured      {0.000508}
    ug/hr     Emission Rate, ug/hr                    {0.0335}
()  Not Detected. Value shown is the detection limit and is included in totals.
{}  Estimated Maximym Possible Concentration. EMPC values are included in totals.

-------
   Summary of Stack Gas Parameters and Test Results
       Austin White Lime Company - Austin, Texas
         US EPA Test Method 23 - PCDDs / PCDFs
                  Kiln # 3 Baghouse Inlet
                         Page 3 of 6
             RUN NUMBER
             RUN DATE
             RUN TIME
 M23-I-3
 6/30/98
1248-1605
             EMISSIONS DATA -Continued

             DIOXINS - Continued

             123789 HxCDD
     ng      Catch, ng                             {0.00296}
   ng/dscm   Concentration, ng/dscm, as measured     {0.000964}
    ug/hr     Emission Rate, ug/hr                    {0.0635}

             Total HxCDD
     ng      Catch, ng                               0.0088
   ng/dscm   Concentration, ng/dscm, as measured       0.00287
    ug/hr     Emission Rate, ug/hr                      0.189

             1234678 HpCDD
     ng      Catch, ng                             {0.00804}
   ng/dscm   Concentration, ng/dscm, as measured      {0.00262}
    ug/hr     Emission Rate, ug/hr                     {0.173}

             Total HpCDD
     ng      Catch, ng                               0.0060
   ng/dscm   Concentration, ng/dscm, as measured       0.00195
    ug/hr     Emission Rate, ug/hr                      0.129

             QCDJ2
     ng      Catch, ng                               0.0237
   ng/dscm   Concentration, ng/dscm, as measured       0.00772
    ug/hr      Emission Rate, ug/hr                      0.509

             Total PCDD
     ng      Catch, ng                              {0.0536}
   ng/dscm   Concentration, ng/dscm, as measured       {0.0175}
    ug/hr      Emission Rate, pg/hr       	{1.15}
()  Not Detected. Value shown is the detection limit and is included in totals.
{}  Estimated Maximum Possible Concentration. EMPC values are included in totals.

-------
   Summary of Stack Gas Parameters and Test Results
        Austin White Lime Company - Austin, Texas
         US EPA Test Method 23 - PCDDs / PCDFs
                   Kiln # 3 Baghouse Inlet
                         Page 4 of 6
              RUN NUMBER
              RUN DATE
              RUN TIME
 M23-I-3
 6/30/98
1248-1605
              EMISSIONS DATA - Continued

              FURANS

              2378 TCDF
      ng       Catch, ng                             {0.00734}
   ng/dscm    Concentration, ng/dscm, as measured      {0.00239}
     ug/hr     Emission Rate, ug/hr                     {0.158}

              Total TCDF
      ng       Catch, ng                              {0.0642}
   ng/dscm    Concentration, ng/dscm, as measured       {0.0209}
     ug/hr     Emission Rate, ug/hr                      {1.38}

              12378 PeCDF
      ng       Catch, ng                               0.0023
   ng/dscm    Concentration, ng/dscm, as measured      0.000749
     ug/hr     Emission Rate, ug/hr                     0.0494

              23478 PeCDF
      ng       Catch, ng                             {0.00064}
   ng/dscm    Concentration, ng/dscm, as measured     {0.000209}
     ug/hr     Emission Rate, ug/hr                    {0.0137}

              Total PeCDF
      ng       Catch, ng                             {0.0110}
   ng/dscm    Concentration, ng/dscm, as measured      {0.00358}
     ug/hr     Emission Rate, ug/hr                     {0.236}

              123478 HxCDF
      ng       Catch, ng                            {0.00340}
   ng/dscm    Concentration, ng/dscm, as measured      {0.00111}
     ug/hr     Emission Rate, ug/hr	{0.0730}
()  Not Detected. Value shown is the detection limit and is included in totals.
{}  Estimated Maximum Possible Concentration. EMPC values are included in totals.

-------
   Summary of Stack Gas Parameters and Test Results
       Austin White Lime Company - Austin, Texas
         US EPA Test Method 23 - PCDDs / PCDFs
                   Kiln # 3 Baghouse Inlet
                         Page 5 of 6
              RUN NUMBER
              RUN DATE
              RUN TIME
 M23-I-3
 6/30/98
1248-1605
              EMISSIONS DATA - Continued

              Furans - Continued

              123678 HxCDF
     ng       Catch, ng                             {0.00136}
   ng/dscm    Concentration, ng/dscm, as measured     {0.000443}
    ug/hr      Emission Rate, pg/hr                     {0.0292}

              234678 HxCDF
     ng       Catch, ng                              (0.0004)
   ng/dscm    Concentration, ng/dscm, as measured     (0.000130)
    ug/hr      Emission Rate, ug/hr                    (0.00859)

              123789 HxCDF
     ng       Catch, ng                              (0.0004)
   ng/dscm    Concentration, ng/dscm, as measured     (0.000130)
    ug/hr      Emission Rate, ug/hr                    (0.00859)

              Total HxCDF
     ng       Catch, ng                              {0.0054}
   ng/dscm    Concentration, ng/dscm, as measured      {0.00176}
    ug/hr      Emission Rate, ug/hr                      {0.116}

              1234678 HpCDF
     ng       Catch, ng                               0.0049
   ng/dscm    Concentration, ng/dscm, as measured       0.00160
    ug/hr      Emission Rate, ug/hr                        0.105

              1234789 HpCDF
     ng       Catch, ng                              (0.0006)
   ng/dscm    Concentration, ng/dscm, as measured     (0.000195)
    ug/hr      Emission Rate, ug/hr	(0.0129)
() Not Detected. Value shown is the detection limit and is included In totals.
{} Estimated Maximum Possible Concentration. EMPC values am included in taUfe.

-------
    Summary of Stack Gas Parameters and Test Results
        Austin White Lime Company -Austin, Texas
         US EPA Test Method 23 - PCDDs / PCDFs
                   Kiln # 3 Baghouse Inlet
                         Page 6 of 6
              RUN NUMBER
              RUN DATE
              RUN TIME
 M23-I-3
 6/30/98
1248-1605
              EMISSIONS DATA - Continued

              Furans - Continued

              Total HpCDF
      ng       Catch, ng                               0.0052
   ng/dscm    Concentration, ng/dscm, as measured       0.00169
     ug/hr     Emission Rate, ug/hr                       0.112

              OCDF
      ng       Catch, ng                               0.0036
   ng/dscm    Concentration, ng/dscm, as measured       0.00117
     Mg/hr     Emission Rate, ug/hr                      0.0773

              Total PCDF
      ng       Catch, ng                              {0.0894}
   ng/dscm    Concentration, ng/dscm, as measured       {0.0291}
     pg/hr     Emission Rate, ug/hr                       {1.92}

              Total PCDD + PCDF
      ng       Catch, ng                              {0.1430}
   ng/dscm    Concentration, ng/dscm, as measured       {0.0466}
     |jg/rir     Emission Rate, pg/hr                       {3.07}
()  Not Detected. Value shown is the detection limit and is included in totals.
{}  Estimated Maximum Possible Concentration.  EMPC values are included in totals.

-------
 Summary of Stack Gas Parameters and Test Results
             Air Emissions Screening Test
     Austin White Lime Company - Austin, Texas
       US EPA Test Method 23 - PCDDs / PCDFs
           Kiln # 3 Baghouse Stack North 3
                      Page 1 of 6
  Y
  AH
  Pbar
  vm
  Tm
 Pstatic
  Ts

  C02
  02
  N2
 Ap
  0
   P
   1/2
  An
V
 m(std)m3
  PS
  Bw,
 1-Bws
  Md
  Ms
  V8
  A
  Qa
  Qs
 Q§(cmm)
   I
          RUN NUMBER
          RUN DATE
          RUN TIME
                                   M23-O-3
                                    6/30/98
                                   1247-1612
* v.
MEASURED DATA
Meter Box Correction Factor                 1.000
Avg Meter Orifice Pressure, in. H20            2.30
Barometric Pressure, inches Hg               29.54
Sample Volume, ft3                       148.130
Average Meter Temperature, °F                94.4
Stack Static Pressure, inches H2O             -0.22
Average Stack Temperature, "F                 401
Condensate Collected, ml                   332.9
Carbon Dioxide content, % by volume          18.0
Oxygen content, % by volume                10.7
Nitrogen content, % by volume                71.3
Pilot Tube Coefficient                       0.84
Average Square Root Ap, (in. H20)1/2        0.41691
Sample Run Duration, minutes                180.0
Nozzle Diameter, inches                     0.381

CALCULATED DATA
Nozzle Area, ft2                         0.00079
Standard Meter Volume, dscf              140.031
Standard Meter Volume, dscm                3.965
Stack Pressure, inches Hg                   29.52
Moisture, % by volume                       10.1
Standard Water Vapor Volume, ft3            15.670
Dry Mole Fraction                         0.8994
Molecular Weight (d.b.),  Ib/lb-mole            31.31
Molecular Weight (w.b.). Ib/lb-mole            29.97
Stack Gas Velocity, ft/s                       29.5
Stack Area, ft2                              7.47
Stack Gas Volumetric flow, acfm             13,228
Stack Gas Volumetric flow, dscfm             7,200
Stack Gas Volumetric flow, dscmm             204
Isokinetic Sampling Ratio, %                 101.9

-------
     Summary of Stack Gas Parameters and Test Results
         Austin White Lime Company - Austin, Texas
          US EPA Test Method 23 - PCDDs / PCDFs
               Kiln # 3 Baghouse Stack North 3
                          Page 2 of 6
              RUN NUMBER
              RUN DATE
              RUN TIME
 M23-O-3
 6/30/98
1247-1612
              EMISSIONS DATA

              DIOXINS:

              2378 TCDD
      ng       Catch, ng                                0.0015
   ng/dscm    Concentration, ng/dscm, as measured       0.000378
     ug/hr     Emission Rate, ug/hr                     0.00463

              Total TCDD
      ng       Catch, ng                                0.0119
   ng/dscm    Concentration, ng/dscm, as measured        0.00300
     ug/hr     Emission Rate, ug/hr                      0.0367

              12378PeCDD
      ng       Catch, ng                                0.0006
   ng/dscm    Concentration, ng/dscm, as measured       0.000151
     ug/hr     Emission Rate, ug/hr                     0.00185

              Total PeCDD
      ng       Catch, ng                                0.0056
   ng/dscm    Concentration, ng/dscm, as measured        0.00141
     ug/hr     Emission Rate, ug/hr                      0.0173

              123478 HxCDD
      ng       Catch, ng                               (0.0004)
   ng/dscm    Concentration, ng/dscm, as measured      (0.000101)
     ug/hr     Emission Rate, ug/hr                    (0.00123)

              123678 HxCDD
      ng       Catch, ng                                0.0014
   ng/dscm    'Concentration, ng/dscm, as measured       0.000353
     ug/hr     Emission Rate, ug/hr    	0.00432
()  Not Detected. Value shown is the detection limit and is included in totals.
{}  Estimated Maximum Possible Concentration. EMPC values are included in totals.

-------
    Summary of Stack Gas Parameters and Test Results
        Austin White Lime Company - Austin, Texas
          US EPA Test Method 23 - PCDDs / PCDFs
               Kiln # 3 Baghouse Stack North 3
                          Page 3 of 6
             RUN NUMBER
             RUN DATE
             RUN TIME
 M23-0-3
 6/30/98
1247-1612
             EMISSIONS DATA -Continued

             DIOXINS - Continued

             123789 HxCDD
     ng      Catch, ng                             {0.00196}
   ng/dscm   Concentration, ng/dscm, as measured     {0.000494}
    ug/hr     Emission Rate, ug/hr                    {0.00605}

             Total HxCDD
     ng      Catch, ng                               0.0076
   ng/dscm   Concentration, ng/dscm, as measured       0.00192
    ug/hr     Emission Rate, ug/hr                      0.0234

             1234678 HpCDD
     ng      Catch, ng                               0.0045
   ng/dscm   Concentration, ng/dscm, as measured       0.00113
    ug/hr     Emission Rate, ug/hr                      0.0139

             Total HpCDD
     ng      Catch, ng                               0.0088
   ng/dscm   Concentration, ng/dscm, as measured       0.00222
    ug/hr     Emission Rate, ug/hr                      0.0271

             QQDD.
     ng      Catch, ng                               0.0167
   ng/dscm   Concentration, ng/dscm, as measured       0.00421
    ug/hr     Emission Rate, ug/hr                      0.0515

             Total PCDD
     ng      Catch, ng                               0.0506
   ng/dscm   Concentration, ng/dscm, as measured        0.0128
    ug/hr     Emission Rate, ug/hr	0.156
()  Not Detected. Value shown is the detection limit and is included in totals.
{}  Estimated Maximum Possible Concentration. EMPC values are inducted fa

-------
    Summary of Stack Gas Parameters and Test Results
         Austin White Lime Company - Austin, Texas
          US EPA Test Method 23 - PCDDs / PCDFs
               Kiln # 3 Baghouse Stack North 3
                          Page 4 of 6
              RUN NUMBER
              RUN DATE
              RUN TIME
 M23-O-3
 6/30/98
1247-1612
              EMISSIONS DATA - Continued

              FURANS

              2378 TCDF
      ng       Catch, ng                                0.0054
   ng/dscm    Concentration, ng/dscm, as measured        0.00136
     ug/hr     Emission Rate, ug/hr                      0.0167

              Total TCDF
      ng       Catch, ng                                0.1428
   ng/dscm    Concentration, ng/dscm, as measured         0.0360
     ug/hr     Emission Rate, ug/hr                       0.441

              12378PeCDF
      ng       Catch, ng                                0.0038
   ng/dscm    Concentration, ng/dscm, as measured       0.000958
     ug/hr     Emission Rate, ug/hr                      0.0117

              23478 PeCDF
      ng       Catch, ng                               {0.0024}
   ng/dscm    Concentration, ng/dscm, as measured      {0.000605}
     ug/hr     Emission Rate, ug/hr                    {0.00740}

              Total PeCDF
      ng       Catch, ng                                0.0312
   ng/dscm    Concentration, ng/dscm, as measured        0.00787
     ug/hr     Emission Rate, ug/hr                      0.0962

              123478 HxCDF
      ng       Catch, ng                                0.0033
   ng/dscm    Concentration, ng/dscm, as measured       0.000832
     ug/hr     Emission Rate, ug/hr	0.0102
()  Not Detected. Value shown is the detection limit and is inducted in totals.
{}  Estimated Maximum Possible Concentration. EMPC values are included in totals.

-------
    Summary of Stack Gas Parameters and Test Results
        Austin White Lime Company - Austin, Texas
          US EPA Test Method 23 - PCDDs / PCDFs
               Kiln # 3 Baghouse Stack North 3
                          Page 5 of 6
             RUN NUMBER
             RUN DATE
             RUN TIME
 M23-O-3
 6/30/98
1247-1612
             EMISSIONS DATA - Continued

             Furans - Continued

             123678 HxCDF
     ng      Catch, ng                             {0.00168}
   ng/dscm    Concentration, ng/dscm, as measured     {0.000424}
    ug/hr     Emission Rate, ug/hr                    {0.00518}

             234678 HxCDF
     ng      Catch, ng                             {0.00116}
   ng/dscm    Concentration, ng/dscm, as measured     {0.000293}
    pg/hr     Emission Rate, ug/hr                    {0.00358}

             123789 HxCDF
     ng      Catch, ng                               (0.0005)
   ng/dscm    Concentration, ng/dscm, as measured     (0.000126)
    ug/hr     Emission Rate, ug/hr                    (0.00154)

             Total HxCDF
     ng      Catch, ng                                0.0104
   ng/dscm    Concentration, ng/dscm, as measured        0.00262
    ug/hr     Emission Rate, ug/hr                       0.0321

              1234678 HpCDF
     ng      Catch, ng                                0.0063
   ng/dscm   Concentration, ng/dscm, as measured        0.00159
    ug/hr      Emission Rate, ug/hr                       0.0194

              1234789 HpCDF
     ng       Catch, ng                              {0.00112}
   ng/dscm    Concentration, ng/dscm, as measured      {0.000282}
    ug/hr      Emission Rate, ug/hr	{0.00346}
()  Not Detected. Value shown is the detection limit and is included in totals.
{}  Estimated Maximum Possible Concentration. EMPC values ai

-------
    Summary of Stack Gas Parameters and Test Results
         Austin White Lime Company - Austin, Texas
          US EPA Test Method 23 - PCDDs / PCDFs
               Kiln # 3 Baghouse Stack North 3
                          Page 6 of 6
             RUN NUMBER
             RUN DATE
             RUN TIME
 M23-O-3
 6/30/98
1247-1612
             EMISSIONS DATA - Continued

             Furans - Continued

             Total HpCDF
     ng      Catch, ng                               0.0076
   ng/dscm   Concentration, ng/dscm, as measured       0.00192
    ug/hr     Emission Rate, ug/hr                      0.0234

             OCDF
     ng      Catch, ng                               0.0092
   ng/dscm   Concentration, ng/dscm, as measured       0.00232
    ug/hr     Emission Rate, ug/hr                      0.0284

             Total PCDF
     ng      Catch, ng                               0.2012
   ng/dscm   Concentration, ng/dscm, as measured        0.0507
    ug/hr     Emission Rate, ug/hr                       0.621

             Total PCDD + PCDF
     ng      Catch, ng                               0.2518
   ng/dscm   Concentration, ng/dscm, as measured        0.0635
    pg/hr     Emission Rate, ug/hr                       0.777
()  Not Detected. Value shown is the detection limit and is included in totals.
{}  Estimated Maximum Possible Concentration.  EMPC values are included in totals.

-------
         Appendix C.2




Calculations & Computer Summaries




           Kiln No. 2

-------
Summary of Stack Gas Parameters and Test Results
            Air Emissions Screening Test
    Austin White Lime Company - Austin, Texas
      US EPA Test Method 23 - PCDDs / PCDFs
                Kiln # 2 Scrubber Inlet
                      Page 1  of 6
   Y
  AH
  Pbar
  vm
  Tm
 Pstatic
  Ts
  V,c
  C02
  02
  N2
 Ap
  0
   1"
  An
 »m(std)
 Vm(std)
  PS
  Bws
 VWs,d
 1-BW8
  Md
  M.
  V,
  A
  Qa
  Q,
 Q-s(cmm)
   I
          RUN NUMBER
          RUN DATE
          RUN TIME
                                    M23-I-4
                                     7/1/98
                                   1415-1736
MEASURED DATA
Meter Box Correction Factor                 1.021
Avg Meter Orifice Pressure, in. H2O            1.39
Barometric Pressure, inches Hg               29.60
Sample Volume, ft3                      113.653
Average Meter Temperature, °F               108.1
Stack Static Pressure, inches H20             -7.00
Average Stack Temperature, °F                 347
Condensate Collected, ml                   333.0
Carbon Dioxide content, % by volume          16.2
Oxygen content, % by volume                 10.5
Nitrogen content, % by volume                73.3
Pitot Tube Coefficient                       0.84
Average Square Root Ap, (in. H20)1/2         0.6934
Sample Run Duration, minutes                 180
Nozzle Diameter, inches                    0.256

CALCULATED DATA
Nozzle Area, ft2                          0.00036
Standard Meter Volume, dscf              107.021
Standard Meter Volume, dscm               3.031
Stack Pressure, inches Hg                  29.09
Moisture, % by volume                      12.8
Standard Water Vapor Volume, ft3           15.674
Dry Mole Fraction                         0.872
Molecular Weight (d.b.), Ib/lbvnole            31.01
Molecular Weight (w.b.), Ib/Ib-mole           29.35
Stack Gas Velocity, ft/s                      48.4
Stack Area, ft2                             6.97
Stack Gas Volumetric flow, acfm             20,246
Stack Gas Volumetric flow, dscfm           11,232
Stack Gas Volumetric flow, dscmm             318
Isokinetic Sampling Ratio, %	103.3

-------
   Summary of Stack Gas Parameters and Test Results
        Austin White Lime Company - Austin, Texas
         US EPA Test Method 23 - PCDDs / PCDFs
                   Kiln # 2 Scrubber Inlet
                         Page 2 of 6
              RUN NUMBER
              RUN DATE
              RUN TIME
 M23-I-4
  7/1/98
1415-1736
              EMISSIONS DATA

              DIOXINS:

              2378 TCDD
     ng       Catch, ng                             {0.00228}
   ng/dscm    Concentration, ng/dscm, as measured     {0.000752}
    ug/hr      Emission Rate, ug/hr                     {0.0144}

              Total TCDD
     ng       Catch, ng                                0.0100
   ng/dscm    Concentration, ng/dscm, as measured       0.00330
    ug/hr      Emission Rate, ug/hr                       0.0630

              12378PeCDD
     ng       Catch, ng                              {0.0004}
   ng/dscm    Concentration, ng/dscm, as measured     {0.000132}
    ug/hr      Emission Rate, ug/hr                    {0.00252}

              Total  PeCDD
     ng       Catch, ng                              {0.0024}
   ng/dscm    Concentration, ng/dscm, as measured     {0.000792}
    pg/hr      Emission Rate, ug/hr                     {0.0151}

              123478 HxCDD
     ng       Catch, ng                               (0.0007)
   ng/dscm    Concentration, ng/dscm, as measured      (0.000231)
    ug/hr      Emission Rate, ug/hr                    (0.00441)

              123678 HxCDD
     ng       Catch, ng                              {0.00076}
   ng/dscm    Concentration, ng/dscm, as measured      {0.000251}
    ug/hr      Emission Rate, pg/hr	{0.00479}
()  Not Detected. Value shown is the detection limit and is included in totals.
{}  Estimated Maximum Possible Concentration. EMPC values are included to

-------
    Summary of Stack Gas Parameters and Test Results
        Austin White Lime Company - Austin, Texas
          US EPA Test Method 23 - PCDDs / PCDFs
                    Kiln # 2 Scrubber Inlet
                          Page 3 of 6
              RUN NUMBER
              RUN DATE
              RUN TIME
 M23-M
  7/1/98
1415-1736
              EMISSIONS DATA -Continued

              DIOXINS - Continued

              123789 HxCDD
      ng      Catch, ng                             {0.00224}
   ng/dscm    Concentration, ng/dscm, as measured     {0.000739}
     ug/hr     Emission Rate, ug/hr                     {0.0141}

              Total HxCDD
      ng      Catch, ng                               0.0132
   ng/dscm    Concentration, ng/dscm, as measured       0.00436
     ug/hr     Emission Rate, ug/hr                      0.0831

              1234678 HpCDD
      ng      Catch, ng                               0.0068
   ng/dscm    Concentration, ng/dscm, as measured       0.00224
     ug/hr     Emission Rate, ug/hr                      0.0428

              Total HpCDD
      ng      Catch, ng                               0.0112
   ng/dscm    Concentration, ng/dscm, as measured       0.00370
     ug/hr     Emission Rate, ug/hr                      0.0705

              QCJ2D
      ng      Catch, ng                               0.0192
   ng/dscm    Concentration, ng/dscm, as measured       0.00634
     ug/hr     Emission Rate, ug/hr                       0.121

              Total PCDD
      ng      Catch, ng                              {0.0560}
   ng/dscm    Concentration, ng/dscm, as measured       {0.0185}
     ug/hr     Emission Rate, ug/hr	{0.353}
() Not Detected. Value shown is the detection limit and is included in totals.
{} Estimated Maximum Possible Concentration. EMPC values are included hi totals.

-------
   Summary of Stack Gas Parameters and Test Results
        Austin White Lime Company - Austin, Texas
         US EPA Test Method 23 - PCDDs / PCDFs
                   Kiln #2 Scrubber Inlet
                         Page 4 of 6
              RUN NUMBER
              RUN DATE
              RUN TIME
 M23-I-4
  7/1/98
1415-1736
              EMISSIONS DATA- Continued

              FURANS

              2378 TCDF
     ng       Catch, ng                               0.0232
   ng/dscm    Concentration, ng/dscm, as measured       0.00766
    ug/hr     Emission Rate, ug/hr                        0.146

              Total TCDF
     ng       Catch, ng                               0.2416
   ng/dscm    Concentration, ng/dscm, as measured        0.0797
    ug/hr     Emission Rate, ug/hr                         1.52

              12378 PeCDF
     ng       Catch, ng                              {0.0066}
   ng/dscm    Concentration, ng/dscm, as measured      {0.00218}
    ug/hr     Emission Rate, ug/hr                     {0.0416}

              23478 PeCDF
     ng       Catch, ng                             {0.00712}
   ng/dscm    Concentration, ng/dscm, as measured      {0.00235}
    ug/hr     Emission Rate, ug/hr                     {0.0448}

              Total PeCDF
     ng       Catch, ng                                0.0436
   ng/dscm    Concentration, ng/dscm, as measured         0.0144
    ug/hr     Emission Rate, ug/hr                        0.275

              123478 HxCDF
     ng       Catch, ng                              {0.00408}
   ng/dscm    Concentration, ng/dscm, as measured       {0.00135}
    ug/hr     Emission Rate, ug/hr            	{0.0257}
()  Not Detected. Value shown is the detection limit and is included in totals.
{}  Estimated Maximum Possible Concentration. EMPC values are induda* fct

-------
   Summary of Stack Gas Parameters and Test Results
        Austin White Lime Company - Austin, Texas
         US EPA Test Method 23 - PCDDs / PCDFs
                   Kiln # 2 Scrubber Inlet
                         Page 5 of 6
              RUN NUMBER
              RUN DATE
              RUN TIME
 M23-W
  7/1/98
1415-1736
              EMISSIONS DATA - Continued

              Furans - Continued

              123678 HxCDF
     ng       Catch, ng                              {0.00160}
   ng/dscm    Concentration, ng/dscm, as measured      {0.000528}
    ug/hr     Emission Rate, ug/hr                     {0.0101}

              234678 HxCDF
     ng       Catch, ng                              {0.00076}
   ng/dscm    Concentration, ng/dscm, as measured      {0.000251}
    ug/hr     Emission Rate, ug/hr                    {0.00479}

              123789 HxCDF
     ng       Catch, ng                               (0.0005)
   ng/dscm    Concentration, ng/dscm, as measured      (0.000165)
    ug/hr     Emission Rate, ug/hr                    (0.00315)

              Total HxCDF
     ng       Catch, ng                                0.0072
   ng/dscm    Concentration, ng/dscm, as measured        0.00238
    ug/hr     Emission Rate, ug/hr                      0.0453

              1234678 HpCDF
     ng       Catch, ng                               0.0047
   ng/dscm    Concentration, ng/dscm, as measured        0.00155
    ug/hr     Emission Rate, ug/hr                      0.0296

              1234789 HpCDF
     ng       Catch, ng                              (0.0009)
   ng/dscm    Concentration, ng/dscm, as measured      (0.000297)
    ug/hr     Emission Rate, ug/hr	(0.00567)
()  Not Detected. Value shown is the detection limit and is included in totals.
{}  Estimated Maximum Possible Concentration. EMPC values are included in totals.

-------
   Summary of Stack Gas Parameters and Test Results
        Austin White Lime Company - Austin, Texas
         US EPA Test Method 23 - PCDDs / PCDFs
                   Kiln # 2 Scrubber Inlet
                         Page 6 of 6
              RUN NUMBER
              RUN DATE
              RUN TIME
                                    M23-I-4
                                    7/1/98
                                  1415-1736
  ng
ng/dscm
 pg/hr
  ng
ng/dscm
 ug/hr
  ng
ng/dscm
 ug/hr
   ng
ng/dscm
  ug/hr
EMISSIONS DATA - Continued

Furans - Continued

Total HpCDF
Catch, ng
Concentration, ng/dscm, as measured
Emission Rate,
OCDF
Catch, ng
Concentration, ng/dscm, as measured
Emission Rate, ug/hr

Total PCDF
Catch, ng
Concentration, ng/dscm, as measured
Emission Rate, ug/hr

Total PCDD + PCDF
Catch, ng
Concentration, ng/dscm, as measured
Emission Rate, ug/hr
                                                    0.0048
                                                   0.00158
                                                    0.0302
                                                  {0.00248}
                                                 {0.000818}
                                                   {0.0156}
                                                  {0.29968}
                                                   {0.0989}
                                                     {1 .89}
                                                  {0.35568}
                                                    {0.117}
                                                     {2.24}
()  Not Detected.  Value shown is the detection limit and is included in totals.
{}  Estimated Maximum Possible Concentration.  EMPC values are included in totals.

-------
Summary of Stack Gas Parameters and Test Results
             Air Emissions Screening Test
     Austin White Lime Company - Austin, Texas
      US EPA Test Method 23 - PCDDs / PCDFs
                Kiln # 2 Scrubber Outlet
                       Page 1 of 6
          RUN NUMBER
          RUN DATE
          RUN TIME
                                              M23-0-4
                                               7/1/98
                                             1414-1734
  Y
 AH
 Pbar
 vm
 Tm
Pstatic
 Ts
 Vie
 CO2
 02
 N2
 C,
Ap
 0
 Dn
   'P
   1/2
  m(std)
  PS
  BWS
Bws(sat)
 Vwstd
 1-Bw,
  Md
  M.
  V,
  A
  Qa
  Q.
Q»(ctiim)
   I
MEASURED DATA
Meter Box Correction Factor                  1.000
Avg Meter Orifice Pressure, in. H2O             1.53
Barometric Pressure, inches Hg               29.60
Sample Volume, ft3                       121.715
Average Meter Temperature, °F               104.8
Stack Static Pressure, inches H2O            -28.00
Average Stack Temperature, °F                 134
Condensate Collected, ml                    602.9
Carbon Dioxide content, % by volume           16.3
Oxygen content, % by volume                  10.1
Nitrogen content, % by volume                 73.6
Pilot Tube Coefficient                        0.84
Average Square Root Ap, (in. H2O)1/2          0.6943
Sample Run Duration, minutes                180.0
Nozzle Diameter, inches                     0.258

CALCULATED DATA
Nozzle Area, ft2                          0.00036
Standard Meter Volume, dscf               112.961
Standard Meter Volume, dscm                3.199
Stack Pressure, inches Hg                   27.54
Moisture, % by volume                       20.1
Moisture (at saturation), % by volume           18.2  (used)
Standard Water Vapor Volume, ft3            28.379
Dry Mole Fraction                          0.818
Molecular Weight (d.b.), Ib/lb-mole             31.01
Molecular Weight (w.b.), Ib/lb-mole             28.64
Stack Gas Velocity, ft/s                       43.3
Stack Area, ft2                             15.47
Stack Gas Volumetric flow, acfm             40,143
Stack Gas Volumetric flow, dscfm            26,863
Stack Gas Volumetric flow, dscmm               761
Isokinetic Sampling Ratio, %                   99.5

-------
    Summary of Stack Gas Parameters and Test Results
        Austin White Lime Company - Austin, Texas
          US EPA Test Method 23 - PCDDs / PCDFs
                   Kiln # 2 Scrubber Outlet
                          Page 2 of 6
              RUN NUMBER
              RUN DATE
              RUN TIME
 M23-O-4
  7/1/98
1414-1734
              EMISSIONS DATA

              DIOXINS:

              2378 TCDD
     ng       Catch, ng                                0.0013
   ng/dscm    Concentration, ng/dscm, as measured       0.000406
    ug/hr      Emission Rate, ug/hr                      0.0185

              Total TCDD
     ng       Catch, ng                                0.0101
   ng/dscm    Concentration, ng/dscm, as measured        0.00316
    ug/hr      Emission Rate, ug/hr                       0.144

              12378 PeCDD
     ng       Catch, ng                              {0.00064}
   ng/dscm    Concentration, ng/dscm, as measured      {0.000200}
    ug/hr      Emission Rate, ug/hr                    {0.00913}

              Total PeCDD
     ng       Catch, ng                                0.0020
   ng/dscm    Concentration, ng/dscm, as measured       0.000625
    ug/hr      Emission Rate, ug/hr                      0.0285

              123478 HxCDD
     ng       Catch, ng                               (0.0009)
   ng/dscm    Concentration, ng/dscm, as measured      (0.000281)
    ug/hr      Emission Rate, ug/hr                     (0.0128)

              123678 HxCDD
     ng       Catch, ng                              {0.00132}
   ng/dscm    Concentration, ng/dscm, as measured      {0.000413}
    ug/hr      Emission Rate, ug/hr	{0.0188}
() Not Detected. Value shown is the detection limit and is included in totals.
{} Estimated Maximum Possible Concentration. EMPC values are included in totals.

-------
     Summary of Stack Gas Parameters and Test Results
         Austin White Lime Company - Austin, Texas
          US EPA Test Method 23 - PCDDs / PCDFs
                    Kiln # 2 Scrubber Outlet
                           Page 3 of 6
              RUN NUMBER
              RUN DATE
              RUN TIME
 M23-O-4
  7/1/98
1414-1734
              EMISSIONS DATA -Continued

              DIOXINS - Continued

              123789 HxCDD
      ng       Catch, ng                              {0.00128}
   ng/dscm    Concentration, ng/dscm, as measured      {0.000400}
     pg/hr     Emission Rate, pg/hr                     {0.0183}

              Total HxCDD
      ng       Catch, ng                                0.0088
   ng/dscm    Concentration, ng/dscm, as measured        0.00275
     ug/hr     Emission Rate, ug/hr                        0.126

              1234678 HpCDD
      ng       Catch, ng                                0.0080
   ng/dscm    Concentration, ng/dscm, as measured        0.00250
     ug/hr     Emission Rate, ug/hr                        0.114

              Total HpCDD
      ng       Catch, ng                                0.0172
   ng/dscm    Concentration, ng/dscm, as measured        0.00538
     ug/hr     Emission Rate, pg/hr                        0.245

              OCDD
      ng       Catch, ng                                0.0218
   ng/dscm    Concentration, ng/dscm, as measured        0.00682
     pg/hr     Emission Rate, pg/hr    _                    0.311

              Total PCDD
      ng       Catch, ng                                0.0599
   ng/dscm    Concentration, ng/dscm, as measured         0.0187
     pg/hr	Emission Rate, pg/hr                        0.855
()  Not Detected. Value shown is the detection limit and is included in totals.
{}  Estimated Maximum Possible Concentration. EMPC values are included in totals.

-------
    Summary of Stack Gas Parameters and Test Results
         Austin White Lime Company - Austin, Texas
          US EPA Test Method 23 - PCDDs / PCDFs
                   Kiln # 2 Scrubber Outlet
                          Page 4 of 6
              RUN NUMBER
              RUN DATE
              RUN TIME
 M23-O-4
  7/1/98
1414-1734
              EMISSIONS DATA - Continued

              FURANS

              2378 TCDF
      ng       Catch, ng                                0.0301
   ng/dscm    Concentration, ng/dscm, as measured        0.00941
    ug/hr     Emission Rate, ug/hr                       0.429

              Total TCDF
      ng       Catch, ng                                0.2964
   ng/dscm    Concentration, ng/dscm, as measured         0.0927
    ug/hr     Emission Rate, ug/hr                        4.23

              12378 PeCDF
      ng       Catch, ng                                0.0077
   ng/dscm    Concentration, ng/dscm, as measured        0.00241
    ug/hr     Emission Rate, ug/hr                       0.110

              23478 PeCDF
      ng       Catch, ng                                0.0074
   ng/dscm    Concentration, ng/dscm, as measured        0.00231
    pg/hr     Emission Rate, ug/hr                       0.106

              Total PeCDF
      ng       Catch, ng                               0.0592
   ng/dscm    Concentration, ng/dscm, as measured         0.0185
    ug/hr     Emission Rate, ug/hr                       0.845

              123478 HxCDF
      ng       Catch, ng                               0.0032
   ng/dscm    Concentration, ng/dscm, as measured        0.00100
    ug/hr     Emission Rate, ug/hr	0.0457
()  Not Detected. Value shown is the detection limit and is included in totals.
{}  Estimated Maximum Possible Concentration. EMPC values are included In totals.

-------
    Summary of Stack Gas Parameters and Test Results
         Austin White Lime Company - Austin, Texas
          US EPA Test Method 23 - PCDDs / PCDFs
                    Kiln # 2 Scrubber Outlet
                          Page 5 of 6
              RUN NUMBER
              RUN DATE
              RUN TIME
 M23-O-4
  7/1/98
1414-1734
              EMISSIONS DATA - Continued

              Furans - Continued

              123678 HxCDF
      ng       Catch, ng                                0.0016
   ng/dscm    Concentration, ng/dscm, as measured       0.000500
     ug/hr     Emission Rate, ug/hr                      0.0228

              234678 HxCDF
      ng       Catch, ng                              {0.00088}
   ng/dscm    Concentration, ng/dscm, as measured      {0.000275}
     |jg/hr     Emission Rate, ug/hr                     {0.0126}

              123789 HxCDF
      ng       Catch, ng                               (0.0004)
   ng/dscm    Concentration, ng/dscm, as measured      (0.000125)
     ug/hr     Emission Rate, ug/hr                    (0.00571)

              Total HxCDF
      ng       Catch, ng                                0.0108
   ng/dscm    Concentration, ng/dscm, as measured        0.00338
     ug/hr     Emission Rate, ug/hr                        0.154

              1234678 HpCDF
      ng       Catch, ng                                0.0056
   ng/dscm    Concentration, ng/dscm, as measured        0.00175
     ug/hr     Emission Rate, ug/hr                      0.0799

              1234789 HpCDF
      ng       Catch, ng                               (0.0007)
   ng/dscm    Concentration, ng/dscm, as measured      (0.000219)
     ug/hr     Emission Rate, ug/hr	     (0.00999)
()  Not Detected. Value shown is the detection limit and is included in totals.
{}  Estimated Maximum Possible Concentration. EMPC values are included in totals.

-------
     Summary of Stack Gas Parameters and Test Results
         Austin White Lime Company - Austin, Texas
          US EPA Test Method 23 - PCDDs / PCDFs
                   Kiln #2 Scrubber Outlet
                          Page 6 of 6
              RUN NUMBER
              RUN DATE
              RUN TIME
 M23-O-4
  7/1/98
1414-1734
              EMISSIONS DATA - Continued

              Furans - Continued

              Total HpCDF
      ng       Catch, ng                               0.0056
   ng/dscm    Concentration, ng/dscm, as measured       0.00175
     pg/hr     Emission Rate, pg/hr                      0.0799

              OCDF
      ng       Catch, ng                               0.0052
   ng/dscm    Concentration, ng/dscm, as measured       0.00163
     pg/hr     Emission Rate, ug/hr                      0.0742

              Total PCDF
      ng       Catch, ng                               0.3772
   ng/dscm    Concentration, ng/dscm, as measured         0.118
     pg/hr     Emission Rate, pg/hr                        5.38

              Total PCDD + PCDF
      ng       Catch, ng                               0.4371
   ng/dscm    Concentration, ng/dscm, as measured         0.137
     pg/hr     Emission Rate, pg/hr                        6.24
()  Not Detected. Value shown is the detection limit and is included in totals.
{}  Estimated Maximum Possible Concentration. EMPC values are Included in totals.

-------
    APPENDIX D




EXAMPLE EQUATIONS

-------
                       Nomenclature
      Y
     AH
     Pbar
     vm
      t»
     "static
      ts
     Vic
     CO2
      02
     N2
      CP
     Api/2

      0
      Dn
      An
     *m(std)
    ' m(std)m3
      PS
     Bws
     Vw(std)
     1-Bws
      Ma
      Ms
      vs
      A
      Qa
     Qs(std)
     Qs(cmm)
       I
    ng/dscm
ng/dscm@7%O2
     ug/hr
     Ib/hr
Meter Box Correction Factor
Avg Meter Orifice Pressure, in. H2O
Barometric Pressure, inches Hg
Sample Volume, ft3
Average Meter Temperature, °F
Stack Static Pressure, inches H2O
Average Stack Temperature, °F
Condensate Collected, ml
Carbon Dioxide content, % by volume
Oxygen content, % by volume
Nitrogen content, % by volume
Pilot Tube Coefficient
Average Square Root Ap, (in. H2O)1/2
Sample Run Duration,  minutes
Nozzle Diameter, inches
Nozzle Area,  ft2
Standard Meter Volume, dscf
Standard Meter Volume, dscm
Stack Pressure, inches Hg
Moisture, % by volume
Standard Water Vapor Volume, ft3
Dry Mole Fraction
Molecular Weight, dry, lb/lb«mole
Molecular Weight, wet, lb/lb*mole
Stack Gas Velocity,  ft/s
Stack Area, ft2
Stack Gas Volumetric flow,  acfrn
Stack Gas Volumetric flow,  dscfm
Stack Gas Volumetric flow,  dscmm
Isokinetic Sampling  Ratio, %
Concentration, ng/dscm
Concentration, ng/dscm adjusted to  7% oxygen
Emission Rate, ug/hr
Concentration, parts per million, dry
Concentration, parts per million, wet
Emission Rate, pounds per hour

-------
                               Example Calculations
                     Austin White Lime Company - Austin, Texas
                          US EPA Method 23-PCDD/PCDF
                           (Using Data from Run M23-I-3)

Note:  Discrepancies may exist between the computer generated reported results, which use
       more significant figures, and the values manually calculated from the displayed values.

1.      Volume of dry gas sampled corrected to standard conditions of 68 °F, 2932 in. Hg, ft3.
                         Vm(std) =  17.64VmY
                                                   AH
                                                   13.6
                                              460 + t
                                                     m
                  Vm(std) = (17.64)(114.293)(1.021)
                                                 29.54 +
                            1.382
                             13.6
                                                  460 -t-  102.92
                               Vm(std)  -  108.393 dscf
2.     Volume of dry gas sampled corrected to standard conditions of 68°F, 29.92 in. Hg, m3.

                                     = Vm(std)(0.028317)
                                   = (108.393)(0.028317)
                               Vm(std)m3 = 3.069 dscm
 3.     Volume of water vapor at standard conditions, ft3.
                                       =  0.04707V
                                                  1C
vwstd = (0.04707) (280.6)
                               w(std)
                                       = 13.208 scf

-------
4.     Moisture content in stack gas.



                                      V

                                 (*m(std)  + ^w(std)l



                                      13.208
                                                 (100)
                           K   = 	i±±^	(100)
                            w   108.393+ 13.208



                                   B... =  10.86
5.     Dry molecular weight of stack gas, Ib/lb-mol.


                Md - 0.44 (%CO2) + 0.32 (%O2) + 0.28 (%N2 + %CO)


                    Md  - 0.44(19.2) + 0.32(9.5) + 0.28(71.3+0)


                               Md  =  31.45  Ib/lb-mol





6.     Molecular weight of stack gas, Ib/lb-mol.



                        Ms  = Md(l-Bws/100)  +  18(BWS/100)



                     Ms - 31.45(1-10.86/100) + 18(10.86/100)



                         Ms = 31.45(0.8914)  +  18(0.1086)



                              M. = 28.026 + 1.9548
                                s
                               Ms  =  29.99 Ib/lb-mol

-------
7.      Absolute stack gas pressure, in. Hg.
                                              p   .
                                  p  _ p       static
                                   s "  bar    U6~
                                   = 29.54
                                                13.6
                                P. = 28.07 inches Hg
8.      Stack velocity at stack conditions, fps.
   vs  = 85.49 Cp
                       avg
                                                    ts+460
                                                    M., P.,
                      v,  =  (85.49) (0.84) (0.7493)
                          (429.9 +  460)
                          (29.99) (28.07)
                                    vs  - 55.32 fps
9.      Isokinetic Variation.
                           I =
                                                  (17.32)
                                (vs)(Dn2)(0)(Ps)(l-Bws/100)
                   I =
       (108.393) (429.9+460) (17.32)
(55.32) (0.256)2 (180) (28.07) (1-10.86/100)
                                      I =  102.4

-------
10.    Stack gas volumetric flow rate at stack conditions, acfin.


                                  Qa = (60) (A) (vs)


                              Qa  = (60) (23.552) (55.32)


                                  Qa = 78,176 acfin



1 1 .    Dry stack gas volumetric flow rate at standard conditions, dscfrn.
                                             198 07   ^
                                          4299/460 J  (1-10-86/100)
                                Qs(std)  =  38,773 dscfm
12.     Dry stack gas volumetric flow rate at standard conditions, dscmm.



                              Qs(cmm)  = Qs(std) 0-028317


                                    =  (38,773)  (0.028317)



                                 s(cmm)  =

-------
13.    Pollutant (2378 TCDD) concentration, ng/dscm.
                                ng/dscm = -——

                                            m(std)m
                                 ..        [ 0.00309 ]
                               ng/dscm =	-
                                            3.069
                             ng/dscm = [ 0.001007 ] ng/dscm



14.    Pollutant (2378 TCDD) concentration, ng/dscm adjusted to 7 percent oxygen.



                     ng/dscm@7%0,  = (ng/dscm)   (20'9 "  7)
                      *           2             (20.9 - %O2)




                    ng/dscm@7%O2 = ([ 0.001007 ])
                                                  (20.9 - 9.9)



                    ng/dscm@7%O2 =  [0.00127] ng/dscm@7%O2
1 5 .     Pollutant (2378 TCDD) emission rate,
                                   =  (60) (ng) (Qs(std))

                                             (vm(std))
                               _ (60) ([0.00309]) (38,773)

                                      (103) (108.393)
                              Aig/hr =  [0.0663] //g/hr

-------
16.    CEM Pollutant (HC1) Concentration, ppm,,

                            ppmd = ppn^ / (1 -BJ100)

                            ppmd = 1.5  /(I -10.86/1 00)

                                ppmd = 1.68 ppmd
1 7.    CEM Pollutant (HC1) Emission Rate, Ib/hr.

                          Ib/hr -
                                       (106) (385.3)

                        Ib/hr-  (60) (1-68) (36.47) (38,773)
                                       (106) (385.3)

                                Ib/hr  =  0.371  Ib/hr

18.    Method 3 A Calibration Error, %. Values are for the oxygen, mid range.

      Cal Err % =(100) (Instrument Response -Calibration Gas Concentration) /Span
                        Cal Err  %  = (100) (11.3 - 11.0) / 25

                                Cal Err  %  =  1.2 %


19.    Method 3 A System Bias Check, %. Values are for the oxygen, final upscale check.

         Sys  Bias % = (100) (Instr. ResponseCAL ERR - Instr. ResponseSYS CAL ) / Span

                       Sys Bias % = (100) (11.3 - 11.4) / 25

                               Sys Bias %  =  -0.4 %

-------
20.    Method 3A Drift, %. Values are for the oxygen, upscale check.
Drift % =(100) (Instr.
                                              -Instr. Response^ SYSCAL )/Span
                          Drift % = (100) (11.4 - 11.5) / 25

                                 Drift %  =  -0.4 %
21.    Method 3 A Zero & Upscale Sampling System Check Adjustment. Values are for
       oxygen, %.
                                                C_
                                                  ma
                            C   =(9.9-0.05)     1L°	
                              gas  V          11.45-0.05
                                    Cgas  = 9.5 %
       Where:       Cgas   = Adjusted gas concentration, ppm or %
                    Cavg   = Average unadjusted gas concentration from analyzer
                    C0    = Average of zero gas initial & final system cal. bias check
                    Cma   = Actual concentration of the upscale calibration gas
                    Cm    = Average of upscale initial & final system cal. bias check

-------
22.    Method 322 Zero & Upscale System Bias Checks Adjustment To Analyzer HCI
       Average.
                                          (C   -b)
                                (mi+mf)[V  avg
                          C
                           gas
                          (0.961 +0.936) [(L2  °'74)] +(0.90 + 1.20)
                                        l   0.960
                                    Cas  = 1.5  ppm
                                     gas
       Where:       bc     = Y-intercept of the calibration least-squares line.
                     bf     = Y-intercept of the final bias check 2-point line.
                     b;     = Y-intercept of the initial bias check 2-point line.
                     C^   = Effluent gas concentration, as measured, ppm.
                     Cavg   = Average gas concentration indicated by gas analyzer, as
                              measured, ppm.
                     mc    = Slope of the calibration least-squares line.
                    . mf    = Slope of the final bias check 2-point line.
                     m,    = Slope of the initial bias check 2-point line.

-------
23.    Method 322 HCI Matrix Spike Recovery, Pretest

      In Situ HCI Expected (Predicted^) Spike Concentration, ppm.

                      CE = (Cg) (Qs/Qtot)  + (W-W./QJ)

                   CE = (303)  (1.5/15.25)  + (4.8)(1 -(1.5/15.25))

                                  CE = 34.1 ppm
       Where:       CE    = Recovery efficiency of spiked HCI, %
                    Cs    = Concentration of HCI in spike gas, ppm
                    Qs    = Spike gas (dilution) flow rate, 1pm
                    Qt    = Sample gas (unspiked) flow rate, 1pm
                    Qtot    = (Qs+Qt) Sum of the spike gas and the sample flow rates, 1pm
                    Su    = Concentration of unspiked (native) sample gas
       In Situ HCI Spike Recovery Efficiency. %.

                                %R = (SM/CE)(100)

                               %R = (37.0/34.1)(100)

                                  %R =  108.5 %
       Where:       %R   =  Efficiency of recovery of spiked HCI, %
                    SM    =  Observed concentration of spiked + sample gas, ppm
                    CE    =  Expected or predicted concentration of HCI in spike gas, ppm

-------
APPENDIX E




QA/QC DATA

-------

-------
                                                                                                        1of2
                                     SERVICES. INC.
                                                                                 Central Park West
                                                          5001 South Miami Boulevard, P.O. Box 12077
                                                     Research Triangle Park, North CaroHna 27709-2077
                                                                 (919) 941-0333 FAX: (919)941-0234
    Date:
    Pt«ninHg'
9/1/97
30.16
Calibrator   Tom McDonald
Meter Box No.:   MB-10
                             Reference Meter Correction Factor    1.0049   (8/28/96)
AH= 0.5
Trial
1
2
3
Trial
Duration
(min)
19
19
19
Dry Gas Meter MB-10
Gas Volume
Initial
(ft3)
994.409
1001.982
1009.513
Final
(ft3)
1001.982
1009.513
1017.050
Net
(ft3)
7.573
7.531
7.537
Meter Temperatures
Initial, Inlet
(°F)
74
77
80
Final, Inlet
CF)
78
80
81
Avg. Inlet
CF)
76
78.5
80.5
Initial, Outlet
CF)
73
75
77
inal, Outte
<°F)
75
77
78
Avg. Outlet
(°F)
74
76
77.5

Trial
1
2
3
Reference Meter
Gas Volume
Initial
(ft3)
600.523
608.185
615.801
Final
(ft3)
608.185
615.801
623.430
Net
(ft3)
7.662
7.616
7.629
Meter Temperature
Initial
CF)
72
74
76
Final
CF)
74
76
77
Avg.
CF)
73
75
76.5
Meter Box
Correction
Factor
Y
1.019
1.019
1.021
Reference
Orifice Press
AH0
(in. H20)
1.71
1.74
1.74
AH = 0.75
Trial
1
2
3
Trial
Duration
(min)
15
15
15
Dry Gas Meter MB-10
Gas Volume
Initial
(ft3)
17.220
24.350
31.563
Final
(ft3)
24.350
31.563
38.780
Net
(ft3)
7.130
7.213
7.217
Meter Temperatures
Initial, Inlet
CF)
80
82
82
Final, Inlet
(°F)
82
83
83
Avg. Inlet
CF)
81
82.5
82.5
Initial, Outlet
CF)
78
79
79
inal, Outle
CF)
79
79
81
Avg. Outlet
CF)
78.5
79
80

Trial
1
2
3
Reference Meter
Gas Volume
Initial
(ft3)
623.622
630.833
638.141
Final
(ft3)
630.833
638.141
645.425
Net
(ft3)
7.211
7.308
7.284
Meter Temperature
Initial
CF)
77
78
78
Final
CF)
77
78
78.5
Avg.
CF)
77
78
78.25
Meter Box
Correction
Factor
r
1.020
1.021
1.018
Reference
Orifice Press
AH0
(in. H2O)
1.82
1.77
1.79
AH = 1.0
Trial
1
2
3
Trial
Duration
(min)
10
10
10
Dry Gas Meter MB-10
Gas Volume
Initial
(ft3)
38.946
44.490
50.050
Final
(ft3)
44.490
50.050
55.585
Net
(ft3)
5.544
5.560
5.535
Meter Temperatures
Initial. Inlet
CF)
81
83
84
Final. Inlet
CF)
83
84
84
Avg. Inlet
CF)
82
83.5
84
Initial, Outlet
CF)
80
80
80
inal, Outle
CF)
80
80
80
Avg. Outlet
CF)
80
80
80

Trial
1
2
3
Reference Meter
Gas Volume
Initial
(ft3)
645.614
651.220
656.829
Final
(ft3)
651.22
656.829
662.435
Net
(ft3)
5.606
5.609
5.606
Meter Temperature
Initial
CF)
78
78
78
Final
CF)
78
78
78
Avg.
CF)
78
78
78
Meter Box
Correction
Factor
T
1.019
1.018
1.023
Reference
Orifice Press
AH0
(in. H20)
1.79
1.78
1.78
10 09017.xls
                                                                                  Printed: 6/10/98

-------
                                                                                                     2 of 2
       PACIFIC  ENVIRONMENTAL SERVICES. INC.
                           Central Park West
     5001 South Miami Boulevard, P.O. Box 12077
Research Triangle Park, North Carolina 27709-2077
           (919)941-0333 FAX: (919) 941-0234
AH = 2.0
Trial
1
2
3
Trial
Duration
(min)
10
10
10
Dry Gas Meter MB-10
Gas Volume
Initial
^
55.868
63.519
71.182
Final
ft
63.519
71.182
78.845
Net
ft
7.651
7.663
7.663
Meter Temperatures
Initial, Intel
CF)
84
86
86
Rnal. inlet
CF)
86
86
87
Avg. Inlet
CF)
85
86
86.5
Initial, Outlet
CF)
81
81
81
inal, Oufle
CF)
81
61
81
Ayg. Outlet
CF)
81
81
81

Trial
1
2
3
Reference Meter
Gas Volume
Initial
(ft3)
662.729
670.472
678.244
Final
(ft3)
670.472
678.244
686.010
Net
(ft3)
7.743
7.772
7.766
Meter Temperature
Initial
CF)
78
78
78
Final
CF)
78
78
78
Avg.
CF)
78
78
78
Meter Box
Correction
Factor
T
1.021
1.025
1.024
Reference
Orifice Press
AHtt
(in. HzO)
1.87
1.86
1.86
AH = 4.0
Trial
1
2
3
Trial
Duration
(min)
8
8
8
Dry Gas Meter MB-10
Gas Volume
Initial
ft
79.058
86.620
94.185
Final
(ft8)
86.620
94.185
101.754
Net
(ft3)
7.562
7.565
7.569
Meter Temperatures
Initial, Inlet
CF)
85
87
89
Final, Inlet
CF)
88 •
89
89
Avg. Inlet
CF)
86.5
88
89
Initial, Outlet
CF)
81
82
82
inal, Outle
CF)
82
82
82
Avg. Outlet
CF)
81.5
82
82

Trial
1
2
3
Reference Meter
Gas Volume
Initial
(ft3)
686.208
693.895
701.558
Final
(ft3)
693.895
701.558
709.244
Net
(ft3)
7.687
7.663
7.686
Meter Temperature
Initial
CF)
78
78
78
Final
CF)
78
78
78
Avg.
CF)
78
78
78
Meter Box
Correction
Factor
T
1.023
1.021
1.025
Reference
Orifice Press
AH0
(in. H20)
2.44
2.45
2.43
    Calibration Results
AH I
0.50
0.75
1.0
2.0
4.0
' I
1.020
1.020
1.020
1.023
1.023
AHe
1.73
1.79
1.78
1.86
2.44
                                                 Dry Gas Meter MB-10 on 09/01/97
                                                 Meter Box Calibration Factor
                                                 Meter Box Reference Orifice Pressure
                            1.021
                             1.92
10 09017.xls

-------
    PACIFIC ENVIRONMENTAL SERVICES,  INC.

                            Posttest Dry Gas Meter Calibration Form (English Units)
                                                               Central Park West
                                         5001 South Miami Boulevard, P.O. Box 12077
                                    Research Triangle Park, North Carolina 27709-2077
                                                (919) 941-0333 FAX: (919) 941-0234
 Pretest Calibration Factor
 System Vacuum Setting, (in Hg)
 Reference Meter Correction Factor
 Date:         7/9/98   P^, in Hg
  1.021
    17
 1.0077
29.95   Calibrator:
D. Holzschuh
Meter Box No.
MB-10
AH= 1.53
Trial
1
2
3
Duration
(min)
10
11
10
Dry Gas Meter
Initial
(ft3)
611.3
618.025
625.403
Final
(ft3)
618.025
625.403
632.111
Net
(ft3)
6.725
7.378
6.708
Initial, Inlet
(°F)
79
77
77
Final, Inle
(°F)
77
77
77
Avg. Inlet
(°F)
78
77
77
Initial, Outlet
(°F)
79
78
77
Final, Outlet
(°F)
78
77
77
Avg. Outlet
(°F)
78.5
77.5
77

Trial
1
2
3
Reference Meter
Gas Volume
Initial
(ft3)
432.055
438.894
446.392
Final
(ft3)
438.894
446.392
453.2
Net
(ft3)
6.839
7.498
6.808
Meter Temperature
Initial
(°F)
77
79
77
Final
CF)
79
77
77
Avg.
(°F)
78
78
77
Meter Box
Correction
Factor
Y
1,021
1.019
1.019
Reference
Orifice Press
AH0
(in. H2O)
1.85
1.87
1.87
1009017.XLS
                    PostTest07-09-98
                                                                   7/10/98

-------
                                                                                                   1of2
       PACIFIC ENVIRONMENTAL SERVICES. INC.
                                                                             Cental Park West
                                                       5001 South Miami Boulevard, P.O. Box 12077
                                                   Research Triangle Park, North Carolina 27709-2077
                                                              <919)941-0333 FAX: (919) 941-0234
   Date:
   Pban in Hg'
10/13/97
29.86
Calibrator.  MMD
Meter Box No.:   RMB-15
                            Reference Meter Correction Factor    1.0077    (10/5/97)
AH = 0.5
Trial
1
2
3
Trial
Duration
(min)
15
13
12
Dry Gas Meter RMB-15
Gas Volume
Initial
(ft3)
48.833
54.722
59.821
Final
(ft3)
54.722
59.821
64.544
Net
(ft3)
5.889
5.099
4.723
Meter Temperatures
Initial, Inlet
CF)
73
78
80
Final, Inlet
CF)
77
80
83
Avg. Inlet
CF)
75
79
81.5
ln*t*.QulM
TO
72
74
76
inal, Outte
ro
75
75
77
Avg. Outlet
CF)
73.5
74.5
76.5

Trial
1
2
3
Reference Meter
Gas Volume
Initial
(ft3)
34.044
39.829
44.843
Final
(ft3)
39.829
44.843
49.463
Net
(ft3)
5.785
5.014
4.620
Meter Temperature
Initial
CF)
70
71
71
Final
CF)
70
70
71
Avg.
CF)
70
70.5
71
Meter Box
Correction
Factor
Y
0.997
1.001
0.999
Reference
Orifice Press
AHe
(in. H20)
1.86
1.86
1.86
AH = 0.75
Trial
1
2
3
Trial
Duration
(min)
6
21
13
Dry Gas Meter RMB-15
Gas Volume
Initial
(ft3)
69.524
73.327
83.322
Final
(ft3)
73.327
83.322
89.571
Net
(ft3)
3.803
9.995
6.249
Meter Temperatures
Initial, Inlet
CF)
74
77
78
Final, Inlet
CF)
74
83
82
Avg. Inlet
CF)
74
80
80
Initial, Outlet
CF)
77
76
78
inal, Outle
CF)
75
77
74
Avg. Outle'
CF)
76
76.5
76

Trial
1
2
3
Reference Meter
Gas Volume
Initial
(ft3)
54.365
58.108
67.912
Final
(ft3)
58.108
67.912
74.036
Net
(ft3)
3.743
9.804
6.124
Meter Temperature
Initial
CF)
72
72
73
Final
CF)
72
73
73
Avg.
CF)
72
72.5
73
Meter Box
Correction
Factor
Y
0.996
0.997
0.995
Reference
Orifice Press
AH0
(in. H2O)
1.91
1.91
1.88
AH= 1.0
Trial
1
2
3
Trial
Duration
(min)
19
8
16
Dry Gas Meter RMB-15
Gas Volume
Initial
(ft3)
89.777
100.214
104.614
Final
(ft3)
100.214
104.614
113.404
Net
(ft3)
10.437
4.400
8.790
Meter Temperatures
Initial, Inlet
CF)
82
85
85
Final, Inlet
CF)
86
87
88
Avg. Inlet
CF)
84
86
86.5
Initial, Outlet
CF)
79
81
82
inal, Outle
CF)
80
81
83
Avg. Outlet
CF)
79.5
81
82.5

Trial
1
2
3
Reference Meter
Gas Volume
Initial
(ft3)
74.254
84.440
88.743
Final
(ft3)
84.44
88.743
97.302
Net
(ft3)
10.186
4.303
8.559
Meter Temperature
Initial
CF)
73
73
73
Rnal
CF)
73
73
73
Avg.
CF)
73
73
73
Meter Box
Correction
Factor
Y
0.997
1.002
1.000
Reference
Orifice Press
AH0
(in. H2O)
1.92
1.91
1.92
15_10137.xls

-------
                                                                                                      2 of 2
              J ENVIRONMENTAL SERVICES. INC.
                           Central Park West
     5001 South Miami Boulevard. P.O. Box 12077
Research Triangle Park, North Carolina 27709-2077
 	(919) 941-0333 FAX: (919) 941-0234
AH = 2.0
Trial
1
2
3
Trial
Duration
(min)
9
7
7
DryGasMeterRMB-15
Gas Volume
Initial
(tt3)
13.863
20.884
26.372
Final
(ft3)
20.884
26.372
31.871
Net
(^
7.021
5.488
5.499
Meter Temperatures
Initial, Inlet
CF)
87
90
90
Final, Inlet
CF)
91
92
93
Avg. Inlet
CF)
89
91
91.5
Initial. Outlet
CF)
83
84
84
inal, Outie
CF)
83
84
84
Avg. Outlet
CF)
83
84
84

Trial
1
2
3
Reference Meter
Gas Volume
Initial
(ft3)
97.749
104.591
109.929
Final
(ft3)
104.591
109.929
115.281
Net
(ft3)
6.842
5.338
5.352
Meter Temperature
Initial
CF)
73
73
73
Final
CF)
73
73
74
Avg.
CF)
73
73
73.5
Meter Box
Correction
Factor
y
1.001
1.002
1.002
Reference
Orifice Press
AH0
(in. H20)
1.90
1.89
1.88
AH - 4.0
Trial
1
2
Trial
Duration
(min)
6.5
15.5
Dry Gas Meter RMB-15
Gas Volume
Initial
(ft3)
32.371
39.484
Final
(ft3)
39.484
56.484
Net
(ft3)
7.113
17.000
Meter Temperatures
Initial, Inlet
CF)
92
93
Final, Inlet
CF)
94
97
Avg. Inlet
CF)
93
95
Initial, Outlet
CF)
85
87
inal, Outle
CF)
85
87
Avg. Outlet
CF)
85
87

Trial
1
2
Reference Meter
Gas Volume
Initial
(ft3)
15.775
22.732
Final
(ft3)
22,732
39.287
Net
(ft3)
6.957
16.555
Meter Temperature
Initial
CF)
73
73
Final
CF)
74
73
Avg.
CF)
73.5
73
Meter Box
Correction
Factor
Y
1.004
1.005
Reference
Orifice Press
AH0
(in. H20)
1.92
1.92
    Calibration Results
AH
0.50
0.75
1.0
2.0
4.0
Y
0.999
0.996
1.000
1.002
1.004
AH0 |
1.86
1.90
1.92
1.89
1.92 <
                                                  Dry Gas Meter RMB-15 on 10/13/97
                                                  Meter Box Calibration Factor
                                                  Meter Box Reference Orifice Pressure
                                            • Two Trial Average
                             1.000
                              1.90
15 10137.xls
                             Printed: 6/10/98

-------
     $  i
    PACIFIC ENVIRONMENTAL SERVICES, INC.

                           Posttest Dry Gas Meter Calibration Form (English Units)
                                                              Central Park West
                                        5001 South Miami Boulevard, P.O. Box 12077
                                   Research Triangle Park. North Carolina 27709-2077
                                              (919) 941-0333 FAX: (919) 941-0234
Pretest Calibration Factor
System Vacuum Setting, (in Hg)
Reference Meter Correction Factor
Date:           7/9/98 Pb», in Hg
 1.000
   16
1.0077
 29.95 Calibrator.
DOH
Meter Box No.
RMB-15
AH= 1.39
Trial
1
2
3
Duration
(min)
10
10
10
Dry Gas Meter
Initial
(ft3)
356.55
362.922
369.302
Final
(ft3)
362.922
369.302
375.662
Net
(ft3)
6.372
6.380
6.360
Initial, Inlet
TF)
77
77
77
Final, Inle
(°F)
77
77
77
Avg. Inlet
(°F)
77
77
77
Initial, Outlet
(*F)
77
77
77
Final, Outlet
(°F)
77
77
77
Avg. Outlet
(*F)
77
77
77

Trial
1
2
3
Reference Meter
Gas Volume
Initial
(ft3)
455.45
461.749
468.028
Final
(ft3)
461.749
468.028
474.295
Net
(ft3)
6.299
6.279
6.267
Meter Temperature
Initial
<°F)
75
74
74
Final
<°F)
74
74
74
Avg.
m
74.5
74
74
Meter Box
Correction
Factor
r
0.997
0.994
0.995
Reference
Orifice Press
AH0
(in. H2O)
1.96
1.97
1.98
15 ior
                                                                                 8/18/98

-------
      Barometric Pressure    29.73
      Meter Yw             1.00000
      K ( deg R/inches Hg)   17.64

 _.                    Ory Gas Meter (DGM)
 Tine  Pressure   Meter Readings
(•in)  (in. H20)  Initial
 6.00      -6.60  374.451
24.00      -6.60  381.901
 >.00      -6.60  411.424
10.00      -4.00  421.233  430.675
35.00      -4.00  430.675  464.147
16.50      -4.00  464.147  479.992
12.50      -2.80  479.992  489.698
14.00      -2.80  489.698  500.594
58.50      -2.80  500.594  546.063
16.50      -1.60  574.496  583.672
42.00      -1.60  590.619  614.123
66.50      -1.60  614.123  651.520
15.00      -1.00  651.520  657.572
13.50      -1.30  657.572  663.065
35.30      -1.30  663.365  677.274
Signature
                                                        REFERENCE METER CALIBRATION
                                                        ENGLISH REFERENCE METER UNITS

                                                                           6841495
Date
M) Temperature
ilume Initial Final
29*523 74*0 76!fl
9.809 76.0 76.0

9.442
33.472
15.845


9.706
10.896
45.469

9.176
23.504
37.397

S.052
5.493
14.209

76.0
77.0
77.0


78.0
78.0
78.0

79.0
80.0
80.0

81.0
82.0
32.0

77.0
77.0
78.0


78.0
78.0
79.0

79.0
80.0
31.0

32.0
82.0
32.0
8/28/96 R«viEdT ^^"•EXCALIWAT\CAL-'«'W-OSK\0«a.REF.
Wet Test Meter (UTM) DGM Coefficient Finn
ffi f88^?98, , £lir Ta* a*"™-*** vESS* Jiu
%6 In sSlk Ca*fVl«) ^'n *"? « , ^"<*vg.Yds) (CW?
• ' 303. yB7 7.415 77.0 1 007 -n nnt 1 5nT
503.987 533.471 29.484 77.0 Oil 0000 MM
533.471 543.279 9.808 77.0 1.015 l\™ H2?

543.279
552.761
585.965


601.625
611.270
622.061

695.390
711.429
734.785

771 .901
777.994
T83.400

552.
585.
601.


611.
622.

761
965
625


270
061
667.125

704.
734.
771.

777.
783.
797.

530
785
901

994
400
515
Max Yds - Nin
Average
15*660
Max Yds - Min
Average
9 645
10*791
45*064
Mix Yds - Min
Average
37J16
Max Yds - Min
Average
6.393
5*'06
14*115
Yds «0.007489914 Must
Yds *1. 011058546 Must
77!o
Yds »0
Yds -1
77 a
77*0
77*.0
Yds «
Yds *1
77*0
77.0
1.013
1.002
0.999
'.014197179 Must
.004786738 Must
1
n'aao
1*001
0.00338145 Must
.000808891 Must
1.*003
1.003
Yds *0.000835063 Must
Yds >1. 003302205 Must
78 0
7n'n
rs'o

1 OQ?
1*003
be no greater than
be between 0.95 to
-o!o03
-0.006
be no great
be between

0.002
olooo 	 .
0.926
0.926
0.927

0.95 to

0.754
0.753
n 7^3
be no greater than
be between 0.95 to
0.000
0.000
0.000
0.541
0.543
0 S«
be no greater than
be between 0.95 to

0.011
-1*001

0.396
0.390
n- we
0.030

0 030
1.05



0.030
1.05

0.030
1.35



                                                                                                                * •«ww^         *J«UUI      U' _5VS
                                                                                       Max 
-------
                                                         REFERENCE METER CALIBRATION
                                                         ENGLISH REFERENCE METER UNITS
       Bsroawtric Pre«curt    29.82
       Meter YH             1.00000
       K (  deg R/inche« Hg)    17.64
                                                 OGH Serfat
                                                 Datt
                                                          6841495
                                                         10/5/97
                                                                    Filename:   F:\DATAFILE\CALIBRAT\CAL NENU.DSKNDGM REF.
                                                                    Revised:    06/08/95
 TiM
(•in)
20.50
 5.00
13.00
 8.50
27.50
26.50
 U.OO
 15.50
 12.50
23.50
17.50
15.00
32.00
SS.C'y
15.00
Pressure
(in. H20)
   -8.000
   -8.000
   -8.000
      Dry Gas Meter (DGM)
 Meter Readings       Volume     Initial
 Initial   Final   (cubic feet)  (deg F)
 742.719  768.193       25.474     78.0
 768.193
 774.402
774.402
790.575
   -5.400  790.575  798.821
   -3.400  798.821  825.423
   -5.400  825.423  850.983
   -3.800  850.983  861.899
   -3.800  861.899  873.960
   -3.800  953.219  962.970
   -2.400  962.970  976.611
   -2.400  976.611  986.740
   -2.400  986.740  995.413
   •1.600  995.413 1008.596
   •1.600 1008.596 1022.986
   -1.600 1022.986 1029.158
 6.209
16.173
                    TenBerature
                               Final
                              (deg F)
                                 79.0
79.0
79.0
79.0
79.0
             Wet Teat Meter (UTM)
Meter Readings      Volute
Initial   Final  (cubic feet)
671.890
697.180
703.325
697.180
703.325
719.309
25.290
 6.145
15.984
             OGM
 Tenp    Coefficient
(deg F)      Yds
    77.0       1.016
    77.0       1.013
    77.0       1.012
Coefficient
 Variation
Yds-(Avg.Yds)
       0.002
       0.000
      •0.002
 Flow
 Rate
(CFM)
  1.208
  1.204
  1.204
                                                                      Max Yds • Mln Yds •0.003626886 Must  be no greater  than 0.030
                                                                            Average Yds •1.013636253 Must  be between 0.95  to 1.05

                                                                        8.176       77.0       1.009         0.001     0.942
                                                                       26.324       77.0       1.008         0.000     0.938
                                                                       25.216       77.0       1.006        -0.001     0.932
                                                                      Max Yds - Min Yds -0.002262496 Must  be no greater  than 0.030
                                                                            Average Yds •1.007525980 Must  be between 0.95  to 1.05

                                                                       10.795       77.0       1.006         0.001     0.755
                                                                       11.920       77.0       1.006         0.001     0.753
                                                                        9.554       78.0       1.004        -0.001     0.747
                                                                      Max Yds - Mn Yds •0.002245979 Must  be no greater  than 0.030
                                                                            Average Yds •1.00516(785 Must  be between 0.95  to 1.05

                                                                       13.394       78.0       1.003        -0.001     0.557
                                                                        9.946       78.0       1.004         0.000     0.556
                                                                        8.524       78.0       1.006         0.002     0.556
                                                                      Max Yds - Mln Yds •0.002785363 Must  be no greater  than 0.030
                                                                            Average Yds -1.004591811 Must  be between 0.95  to 1.05

                                                                       12.956       78.0       1.006        -0.002     0.396
                                                                       14.150       78.0       1.007         0.000     0.395
                                                                        6.080       78.0       1.010         0.002     0.396
                                                                      Max Yds - Ntn Yds -0.004205886 Must  be no greater  than 0.030
                                                                            Average Yds -1.007822494 Mutt  be between 0.95  to 1.05

                                                                    Overall  Average Yds -1.007748265

I certify that the above Dry  Gas Meter HBS calibrated in accordance  with E.P.A. Method 5  , paragraph 7.1 rCFR 40 Part  60,
using the Precision Wet Test Meter f 11AE6, which in turn was calibrated using the  Aaerican Bell Prover f 3785.
certificate * F107, wtyi
-------
              TEMPERATURE SENSOR CALIBRATION FORM
Temperature Sensor No.

Ambient Temp. °F,
                             Sensor Type
                                   Barometric Pn
 Length

re,"Hg
Reference Temp. Sensor:
Date
*-is>«r
«•
"















Ref.
Point
No.
1
2
3
1
2
3
1
2
3
1
2
3
1
2
3
1
2
3
Temp.
Source
(it?
tart.
Mt.3
,














Temp. °F
Ref.
Sensor
*«i
1C,
z^c.















Test
Sensor
34-
It
^5-



.
•










Temp.
Diff. %

o

•














Within
Limns
Y/N


















Calibrated
By












'





Temp. Diff
   v
             (Ref' T&ap + 40)  " ( Teat
                                                   460)
                           (Ref. Temp. * 460)
                                                        x 100 S 1.5 V

-------
              TEMPERATURE SENSOR CALIBRATION FORM
Temperature Sensor No.
Ambient Temp. °F
                              Sensor Type
                                    Barometric Pr
Reference Temp. Sensor:
Date
VZ0-TY
*t
tf















Ref.
Point
No.
1
2
3
1
2
3
1
2
3
1
2
3
1
2
3
1
2
3
Temp.
Source
T-
1<* .
*u><-















Test
Sensor
3^
17
7^>^




•










Temp.
Diff. %
."foC.
J^c.
./£*















Within
TJlllllB
T/N
•
y
y
X















Calibrated
By
\U^
ri^
A^>^















V Temp  Diff »
  * ^"'f • **•**—
Temp * 460)  - ( Test Tenp. *  460)
     utsr.
                                                         x 10Q

-------
                     TEMPERATURE SENSOR CAUBRATION FORM
Temperature Sensor No.
Ambient Temp. °F	
                              M - s
       Reference Temp. Senson
                                Sensor Type K'-TC    Length
                               	  Barometric Pressure, "Eg
Date
'^^\f
u
fcf















Ref.
Point
No.
1
2
3
1
2
3
1
2
3
1
2
3
1
2
3
1
2
3
Temp.
Source
\C«a
M£*
?££'















Temp. °F
Ref.
Sensor
33
7*t
zc-v















Test
Sensor
^ O
^7 ^^
-2,1 0















Temp.
Diff. %
.40^
o
.fn















Within
Y/N
N
V
X















Calibrated
By
(U^>
ijUS
\l&















v *
% Temp. Diff »  (J?ef ' TeznP + 4f°> - ( Teat
                                                           460>
                                        Temp. * 460)
                                                                x 100 s  1  5 V

-------
              TEMPERATURE SENSOR CALIBRATION FORM
Temperatnre Sensor No.

       Temp. °F        "
Sensor Type _tiIE_ * Length
Reference Temp. Senson
       w *  ^^^^^^^>^^^^—^^

      Bdromctric ArcssurCy
Date
k*»M»
/.
.<















Ref.
Point
No.
1
2
3
1
2
3
1
2
3
1
2
3
1
2
3
1
2
3
Temp.
Source
ICC.
Hz=>
£**
^o%

•













Temp. °F
Ref.
Sensor
i**
So
7-f .
-LO%















Test
Sensor
3.3
-7.*"
Z-GTf




•










Temp.
Wff. %
o
.1*7
o
-••














Wtthin
UN
Y
Y
Y
- -














Calibrated
By
(\lft>
(b^
^k *
^f 1 j^j
^














          0±ff « (Ref • Teap * 4g0)  " ( reSt Teag* **•  460) x 100 s 1.5 %
        *                   (J2ef. Teznp. •*• 46oi

-------
09/14/98   10:08    O513 398 3342
     PES CINCINNATI   ->-»•» UUKttAM
                     PACIFIC ENVIRONMENTAL SERVICES.INC.
                                 4700 Duke Drive,
                                      Suite 150
                                    Maeon, Ohto
                             Phone: (513) 398-2556
                                Fax: (513) 3983342
                                   www.pos.com
                   TEMPERATURE SENSOR CALIBRATION DATA
                          FOR STACK THERMOCOUPLES
  THERMOCOUPLE NUMBER:
 4A
 DATE:
                                                                    12/23/97
  BAROMETRIC PRES.(ln.Hg):
  AMBIENT TEMP. °F:
29.52
 74
 REFERENCE:
'Mereury-in-glas*:

 Other:

'CALIBRATOR:
                                                                   ASTM-3F
                                                                     G.Gay
Reference
point
number
1
2
3
4
Source*
(Specify)
Ambient Air
Cold Bath
Hot Bath
Hot Oil
Reference
Thermometer
Temperatur*,BF
74
43
204
332
Thermocouple
Potentiometer
Temperature,0F
74
43
205
333
Temperature
Difference,"
%
0.00
0.00
0.15
0.13
   Type of calibration used.

   bfref temp CF+46QWtest thermometer temp CF+46(K  X100
              reftemp.aF+460
   Comments:
                             100<1.S%
                         STACK THERMOCOUPLE CALIBRATION FORM      1998 Yearly Calibration

-------
                   PACIRC ENVIRONMENTAL SERV1CES.INC.
                                4700 Duke Drive,
                                      Suite 160
                                    Mason. Ohio
                            Phone: (513) 398-2SS6
                               Fax:(513)3983342
                                  www.pes.eoni
                 TEMPERATURE SENSOR CAUBRATION DATA
                        FOR STACK THERMOCOUPLES
THERMOCOUPLE NUMBER:
 4F
DATE:
12/23/07
BAROMETRIC PRES.(ln.Hg):
AMBIENT TEMP. °F:
29.52
 76
 REFERENCE:
'Mercury-in-glass:

 Other.

'CALIBRATOR:
                                                                ASTM-3F
                                                                  J.C.
Reference
point
number
1
2
3
4
Source"
(Specify)
Ambient Air
Cold Bath
Hot Bath
Hot Oil
Reference
Thermometer
Temperature,°F
76
38
204
341
Thermocouple
Potentiometer
Temperature.'F
76
38
204
342
Temperature
Difference,'
%
0.00
0.00
0.00
0.12
'Type of calibration used.

bfref temn aF+d6QWtest thermometer temo.flF+46m
      X100
           reftemp,°Fi-460
 Comments:
                 100<1.5%
                       STACK THERMOCOUPLE CALIBRATION FORM

-------OCR error (C:\Conversion\JobRoot\000004ID\tiff\2000EVBC.tif): Unspecified error

-------
4A
PACIFIC ENVIRONMENTAL SERVICES, INC.
    4700 Duke Drive.
          Suite 150
  Mason. Ohio 45040
Phone: (513) 398-2556
  Fax (S13) 398-3342
       www.pes.com
Pitot Tube Number: 4A Dale:
Effective Length: 49' Calibrated By:
Pilot Tube Openings Damaged? YES 1 NO 1
Pitot Tube Assembly Level? 1 YES | NO
a , = l.l '« 10°) a 2 -
0, - 0.5 °«S°) P2 -
Y= 0.8 8 » 0.7 A =
z - A sin Y "• O-O*4 cm (in.) 0.32 cm ( < 1/8 in.)
w = A sin 9 — 0.012 cm (in.) 0.08 cm ( < 1/32 in.)
PA - 0.484 cm (in.)
12/23197
S. Simon
0.8
0.3
0.967

                                                                                                 10°)
                                             0.483
                                          cm (in.)
                                             0.375
                                          cm (in.)
                               c    f
          -^		---	---^--^--
                                                                (0)
           rrw typ»s or tace-openino mSBlgnmwrn *nownaeovawll not amct tne oaaelne vakiaof Qp(«) to
           1003 ae a,and«:le iBBBtrBnoreausno 10'. a, and a. teles* than oraqiaiite Sf.z'a lass than or
           equal to Q.32 on (1/8 in.), andw b toss than or equal to O.OB cm(ia2 in.) (raferoncol 1.O In
                                     Pitot Tube Calibration Form
                                                             1998 Yearly Calibration

-------
05/04/98    12:56     tt513 398 3342
                            FES
                                               -»-»•» vuivnaa
 4F
PACIFIC ENVIRONMENTAL SERVICES, INC.
                         4700 Duke Dri»»,
                                Suite ISO
                        Mason, Ohio 45040
                      Phone: (513)398-2556
                        Ftt (513) 398-3342
                             www.pes.com
 Phot Tube Number

 Effective Length:
   4F
   49'
         Date:

Calibrated By:
  Pint Tube Openings Damaged?


  Phot Tube Assembly Level?
               YES
a , - i °(< 10")
P, - 1 °(<5*)
-Y- I 9 -
i - A sin V = 0.017
w « A sin 6 « 0.
0
cm (in.) 0.32 cm
cm (in.) 0.08 cm
                                                                     3 =
                                                 0.47                cm (in.)
                                                 0.47
                                                0.375
                                            cm (in.)
                                            cm (in.)
                                                                                    12/23/97
                                                           S. Simon
                                                                                      0.94
              Tn« ITP«« of »«e«-«p«nlng mUiMenncnt ih*wn ceox •!« net «H«tl in* •••••n* ••Hi* *>C»(i) SB
              loot *• «i *na ^ I* Mil inin »r •<«•) to 10*. I, ma I, l« i»»» o>«n *r *qu>l M S*. t li Mi* ioi«i or
              • qual to 0.31 em (1/« In.). *n« • is lit* w«n or iquaita 0.08 em(ir32 hi.) (fif«f«ne«lt.O In
              ««ction 1«.Q).	       	
                                                                                                '(< 10*)
                                        Pilot Tube Calibration Form
                                                               1998 Yearly Caiankn

-------
I-5A
PACIFIC ENVIRONMENTAL SERVICES, INC.
                                             4700 Duke Drive.
                                                    Suite 150
                                            Mason, Ohio 45040
                                         Phone: (513) 399-2556
                                            Fax (513) 398-3342
                                                www.pes.com
Pitot Tube Number:

Effective Length:
   I-5A
   60"
 Pitot Tube Openings Damaged?

 Pitot Tube Assembly Level?
       P,
                            2.4
   0-5
                            0.5
             '(< 10°)
                                          9 =
                             1.7
                                         NO
                                      12/22/97
                                      S. Simon
                                        3.4
                                        1.2
                                       0.963
10")
      z = A sin y =

     w = A sin 8 SB
       0.0084
        0.029
                             Flow
                          CO)
                           t>
cm (in.)   0.32 cm ( < 1/8 in.)

cm (in.)   0.08 cm ( < 1/32 in.)

0.482                cm (in.)
                                                0.482
                                                0.375
                                            cm (in.)
                                            cm (in.)
             Tna typo* at foco-op»nino m»olignm«ni mownacovawll nci «T*a m«ba*»ln« value of Cp(«) «o
             tono •= a, andOji* i«as than or •aunt 10 1O«.a,«no ft, tel^stran or«qualto S". z B less thai er
             •qua) to O.32 cm (1/8 m.). »ndw i* !••» than or «qu«l IOO.O* em(1O2 In.) (r»f«rcancBl 1.O In
                                       Pitot Tube Calibration Form
                                                                                         199& Yearly

-------
c
NOZZLE CALIBRATION SHEET
              DATE-
                 CAUBRATION

Nozzle
identification
Number

D 1 , in.

D2,in.

D3,in.

AD, in.

Davg

              Where:
                 D1 2 3 = nozzle diameter measured on a different diameter, in.
                        Tolerance - measure within 0.001 in.

                 AD = maximum difference in any two measurements, in.
                        Tolerance = 0.004 in.
                 Davg~ average of D1§ D2, D3.

-------
c
            NOZZLE CALIBRATION SHEET
DATE:.
                                          CAUBRATION
Nozzle
Identification
Number
G-ttvssSSt
D-pln.
c^s^s
D2,in.
0,7/5"*
Dg,in.
6 ,7,5"^
AD, in.
o
avg
0,7,-sir
              Where:
                 DI 2 3 = nozzle diameter measured on a different diameter, in.
                        Tolerance = measure within 0.001 in.

                 AD = maximum difference in any two measurements, in.
                        Tolerance = 0.004 in.
                 Davgr avera9e

-------
c
            NOZZLE CALIBRATION SHEET
DATE:
                                          CALIBRATION

Nozzle
Identification
Number
CUVSS TT"
Dvin.

02,n.

D3,in.

AD, in.

avg

              Where:
   D1 a 3 "* nozzle
                                     measured on a different diameter, in.
                        Tolerance = measure within 0.001 in.
                AD = maximum difference in any two measurements, in.
                        Tolerance » 0.004 in.
                Davg= average of D.,, D2, Dg.

-------
~ 	 ^a^aa ft*«t ffrf"^*M
^^^f^f rOSH" Pa*
*<&n i <
CoJDept

• . . • •.
itoto •. -..-.ttfi ^"^v^r^^lp^w*' ' .•• •^^"^''"^''HiE?3R!nilB?H3S
1 &&JA4T fnm -feAA\I MpC£. i8M^«M(!M
Ca / ' Cheawt. CTCWO
"*"** . Mfc «OS)»Sc
SScD^^^C^iB^ '^farO^^-f^T**

Certificate of
Red*

Analysis: t.H.A. HfOtdCOl Gas Mixture
4149
Cylinder No: CC&4329 Purchase Order f 139680
Cylinder Pressure: 2000 Expiration Date: 3/2/01
Certification Date (3/2/98 Laboratory: Cheshire, CT
Reference. Standard
Tfflf Ct
GMIS Cc
V0M15 WJ
Instrumentation;
InBtrurnept/ModfiV!
Rosemourrt/NGA20l
S*rvoniex/244/7D1/
Analytical Methodol
certified concentrat



Analytical Results:
Iff Cor^poner|^
UtAnalyrisMt: __
S i^46
z .. a!88
2nd Cotpponefth
1«Amlyd«OttK
R. 173.830 ""
S »lJl6
Certification performed in .
procedures listed. •,

mcrmation;

lulKPJj^iii 9k!uiVRJRSf QpiHiBtipatior^
rton Dioxide CC34977 14.08%
cy^jen CC10914 20.98 %
iefial NOi • Anafvtical Principle
0^ad*» . NDIR
88 • • Parmagnetic
>gy does not require correction for analytical interferences.
ans:

^S*™tm^m^^3i^9»»*«gi^^?rjM'iff M'iaaiS^iBilitftn'lto^^ ^

2T1&W
"3 t«t2 Z 0.306 Cone 11j033 %
Z 0250 R 4.35T cone 1lIwT%
R 32de s z^*T cone II^ST"%
AVtt 11.034 %
aom
1 «1.130 Z 1.480 Cone 1U067 %
Z i.4dtt R f73J1o" cone ifM?*
R 173.630 S 91.1S6 Cone 11j5Tf%
AV6: """"iTM^
\coordance with 'EPA Tnceabillty Pmte/eol (JarLl3$8£using the assay
Do not use cylinder below 150 prig.
Approve^ for Release

-------
Airgas
                                                                                Airqas Specialty Case
                                                                                325 UcCausM Court
                                                                                ChesNnj.CT064tO
                                                                                Phone: (203) 2SM827
                                                                                FAX. (203)2Sft«42
          Certificate of Analysis: E.P.A. Protocol Gas Mixture
         Rec*
         Cylinder No:
         Cylinder Pressure:
         Certification Date
          4150
       CC86922
          2000
         3/2/98
         Reference Standard Information:
               Tvoe          Component
               GMIS
               GMIS
      Carbon Dioxide
      Oxygen
               Purchase Order*
               Expiration Date:
               Laboratory:
                            13980
                            3/2/01
                         Cheshire. CT
                         Cvl. Number
                         CC34977
                         CC19914
                                          14.08 %
                                          20.98%
         Instrumentation:
               Instrument/Model/Serial No.
               Rosemount/NGA2000/Rack#1
               Servomex/244/701/488
                                   Analytical Principle
                                   NDIR
                                   Parmagnetic
               Analytical Methodology does not require correction for analytical interferences.
         Certified Concentrations:
                               ^
         Analytical Results:
               1st Component;
               2nd Component:
               1st Analysis CM*
               R       173.830
               S
               2   ~
156.970
  1.890
S
z
R
                   156.880
 1.420
173.630
Z
R
S
                     1.460
173.8*0
157.030
                                                                           Cone
                                                                           Cone
                                                                           Cone
                                                                           AVG:
Cone
Cone
Cone
AVG:
                                                              19.065%
                                                              19.006 %
                                                              18.964%
                                                              19.012 %
                                                    19.175 %
                                                              19.165 %
                                                              19.158 %
                                                                                    19.166 %
         Certification performed in accordance with 'EPA Traceabttity Protocol (Jan. 1998)" using the assay
         procedures listed.
         Do not use cylinder below 150 psig.
                                   Approved for Release

-------
 55
SPECTRA GASES
277 Coit St. • Irvington, NJ 07111 USA  Tel: (973) 372-2060 • (800) 932-0624 • Fax: (973) 372-8551
Shipped From: 80 Industrial Drive • Alpha, N.J. 08865
     CERTIFICATE OF ANALYSIS
                                   EPA PROTOCOL MIXTURE
                                   PROCEDURE #:  G1
     CUSTOMER:
     SGI ORDER #:
     ITEM*:
     P.OJ:
         Pacific Environmental Services, Inc.
         133140
         2
         104-98-0181
CYLINDER*:    CC91081
CYLINDER PRES: 2000 PSIG
CGA OUTLET:   590
     CERTIFICATION DATE: 5/12/98
     EXPIRATION DATE:    5/12/2001

     CERTIFICATION HISTORY
COMPONENT
Propane



DATE OF
ASSAY
5/12/98



MEAN
CONCENTRATION
8.09 ppm



CERTIFIED
CONCENTRATION
8.09 ppm



ANALYTICAL
ACCURACY
+/-!%



     BALANCE                Air
     PREVIOUS CERTIFICATION DATES: None

     REFERENCE STANDARDS
COMPONENT
Propane



SRM/NTRM*
SRM-1666B



CYLINDER*
CAL011954



CONCENTRATION
9.73 ppm



     INSTRUMENTATION
COMPONENT
Propane



MAKE/MODEL
H. Packard 6890



SERIAL #
US00001434



DETECTOR
GC - FID



CALIBRATION
DATE(S)
5/12/98



     THIS STANDARD WAS CERTIFIED ACCORDINQ TO THE EPA PROTOCOL PROCEDURES.
     DO NOT USE THIS STANDARD IF THE CYLINDER PRESSURE IS LESS THAN 160 PSIG.
      ANALYST:
                                                           DATE:
                    TED NEEME
                                                      5/12/98
.

-------
•35
SPECTRA GASES
277 Coil St. • Irvington, NJ 07111 USA Tel.: (973) 372-2060 • (800) 932-0624 • Fax: (973) 372-8551
Shipped From: 80 Industrial Drive • Alpha, N.J. 08865
   CERTIFICATE OF ANALYSIS
                                   EPA PROTOCOL MIXTURE
                                   PROCEDURE#:  G1
   CUSTOMER:
   SGI ORDER #:
   ITEM*:
   P.O.*:
         Pacific Environmental Services, Inc.
         133140
         3
         104-98-0181
CYLINDER #:    CC91047
CYLINDER PRES: 2000 PSIG
CGA OUTLET:   590
    CERTIFICATION DATE: 5/12/98
    EXPIRATION DATE:    5/12/2001

    CERTIFICATION HISTORY
COMPONENT
Propane



DATE OF
ASSAY
5/12/98



MEAN
CONCENTRATION
15.15 ppm



CERTIFIED
CONCENTRATION
15.15 ppm



ANALYTICAL
ACCURACY
+/-!%



    BALANCE                Air
    PREVIOUS CERTIFICATION DATES: None

    REFERENCE STANDARDS
COMPONENT
Propane



SRM/NTRM#
SRM-1666B



CYLINDER*
CAL011954



CONCENTRATION
9.73 ppm



    INSTRUMENTATION
COMPONENT
Propane



MAKE/MODEL
H. Packard 6890



SERIAL*
US00001434



DETECTOR
GC - FID



CALIBRATION
DATE(S)
5/12/98



    THIS STANDARD WAS CERTIFIED ACCORDING TO THE EPA PROTOCOL PROCEDURES.
    DO NOT USE THIS STANDARD IF THE CYLINDER PRESSURE IS LESS THAN 180 PSIG.
    ANALYST:
                                             DATE:
                  TED NEEME
                   5/12/98

-------
     Scott Specialty Gases
    pped
 From:
1750 EAST CLUB BLVD
DURHAM
Phone: 919-220-0803
NC  27704
                                               Fax:  919-220-0808

             CERTIFICATE   OF   ANALYSIS
 PACIFIC ENVIRONMENTAL SER

 5001 SOUTH MIAMI
 3RD FLOOR, SUITE #300
 RESEARCH TRIANGLE PA
               NC  27709-2077
                                    PROJECT #: 12-28662-001
                                    PO#: 104-98-0178
                                    ITEM #: 12023411   CAL
                                    DATE:  5/01/98
   CYLINDER #: AAL13302
   FILL PRESSURE:  1400  PSIG
                       ANALYTICAL ACCURACY: +-1%
                       PRODUCT EXPIRATION:   5/01/2001
   BLEND TYPE :  RECERTIFICATION OF CYLINDER
                                   REQUESTED GAS
COMPONENT                            CONC MOLES
                                           ANALYSIS
                                              (MOLES)
PROPANE
AIR
                         30.
           PPM
           BALANCE
30.0
PPM
BALANCE
  ANALYST:
            B.M. BECTON

-------
               Scott Specialty  Gases
              1750 EAST CLUB BOULEVARD, DURHAM, NC 27704
                                                      {919)2200803  FAX<91S)22&OBCB
              CERTIFICATE OF ANALYSIS:  EPA PROTOCOL GAS
              Customer
              Pacific Environmental Services
              Attn: Mr. Frank Meadows
              P.O. Box 12077 "   -;-•       f
              Research Triangle Park, NC 27709
                     'V.'.;-,

                    .YT1CAL INFORMATION
                                    Assay Laboratory
                                    Scott Specialty Gases, Inc.
                                    1750 East Club Boulevard
                                    Durham, NG 2770* ^
                                                                  Purchase Order 104-95-0121
                                                                  Scott Project*   12-11271 ,
      to exceed the minimum specifications of EPA Protocol Procedure #G1, issued September, 1993.   --
ylflder Number    AAL-13302          Cerdficatfon Date         04-18,95    Expiration Date
                                                           None
 Pressure   2000  PSIG


ZED CYLINDER
                                                   Previous Certification
                                                                ntration
                                                                        AnafrtkalUncertamtV
                                                                        •W-1% NIST Directly Traceable
                                                                        Balance
                          ty • bchnve of anal bom eaat manxa wkidi at bait BcM« rafenooe
                    IENCE STANDARD
                    #1668
              Expiration Date
              06-%
                               Cylinder Number
                               ALM-032005
                                                   Last Date Calibrated
                                                   03-23-95
Concentratfoo
95.5 PPM Balance in Air
                                                                        Analytical Principle
                    .YZER READINGS  (Z-ZtroG«i  R-RefcmiccGr»
                  iponents    First Triad Analysis
                                          Second Triad Analysis
                                                                  Calibration Curve
                             Drta 04-1(43
                             STO-1397317  SPL-43«9-139«73  Sn>1393703
                                           STD~
                                           SPL-
                                                 SPL-
                                                 SPL-
                                                 STT>-
                                                                            03-2345
Dtfe:
STD™
SPL-
STT>-
RMpomeUmH:
SPL-
SPL-
STD-




Dtt»:
STD"
SPL-
STD-
RopoMelMr.
SPL-
SPL-
sn>.
DMW
STD-
SPL-
srr^
BapMeUite:
8PL-
SPL-
SID-




tMK
sn>
SPL-
8TO-
B-r»
SPL-
SPL-
sn>- .
••Una:


-.''
                                                                                 •  --^
!?*;T"""' ."•'/' W?" "•"""'* ""'- ''•' >- -T'-'-'- .-V*-?  -*B --. •*•*?: !-••-"'-*• -"	~,w.,,,.. -,c^,^. ...
;.*... _jt. ...HJ V - ••'.(•  -  •  ••.^'"'   -' ! '   'v   '••-,'  .*••' .-  ..-•;,•>'..• . -\.      ,.:..v., .

-------
              SPECTRfl BUSES
                                                                               71998
        ^J 277 Coit Street • Irvington. NJ 07111 USA   Tel: (973) 372-2060 • (800) 929-2427 • Fax: (973) 372-8551

SHIPPED FROM: 80 INDUSTRIAL DRIVE ALPHA, NJ. 08865 TEL (908) 454-7455
SHIPPED TO:
APCCLTD
80 Industrial Park Road West
Tolland, CT 06084
                                     CERTIFICATE
                                          OF
                                      ANALYSIS
SOI ORDER*:        133817
ITEM*:              2
CERTIFICATION DATE:  8/12/88
P.O.*:               3428
BLEND TYPE:         CERTIFIED
                                     CYLINDER *:CC91137
                                  CYLINDER PRES: 2000 psig
                                 CYLINDER VALVE: CGA 330
                                              ANALYTICAL ACCURACY: + / - 6%
    COMPONENT
Hydrogen Chloride


Nitrogen
                 REQUESTED GAS
                      CONC
                     25.0 ppm
                      Balance
                                                                       ANALYSIS
27.1 ppm

 ANALYST:
                                                               DATE:
                                                      6/12/98
                 TedNeeme
                           USA • United Kingdom • Germany <
                                     iso  a o o a

-------
              277 Coit Street • Irvington. NJ 07111 USA     Tel: (201) 372-2060 • (800) 932-0624 • Fax: (201) 372-8551
SHIPPED FROM: 80 INDUSTRIAL DRIVE ALPHA. NJ. 08865 TEL (908) 454-7455
SHIPPED TO:
APCC LTD - Eric Dtthrich
C/O Redlands Stone Products Company
179101H10 Wtst
San Antonio, TX 76257
                                       CERTIFICATE
                                             OF
                                              .YSIS
SGI ORDER*:         134121
ITEM*:               1
CERTIFICATION DATE:  0/23/98
P.OJP:               3454
BLEND TYPE:         CERTIFIED
                                       CYLINDER *:iai2728Y
                                   CYLINDER PRE8: 2000 ptig
                                   CYLINDER VALVE: CQA330
                                                 ANALYTICAL ACCURACY: + / •
    COMPONENT
                  REQUESTED GAS
                       CONC
                                                                           ANALYSIS
Hydrogen Chloride


Nitrogen
                      46.0 ppm
48.6 ppm
                                                        Balance
ANALYST:
                  Ted Neeme
                                             DATE:
                           USA — California • United Kingdom • Germany
                                     iso  o a o a

-------
                TABLE C-3.6
Redland Stone Products Company Calibration Tabte
                  Kiln No. 3
                 30-June-98
                   INLET
Austin, TX
THC
ZERO GAS
LOW RANGE
MID RANGE
IHIGH RANGE
||02
CALIBRATION ERROR TEST

Range 0 - SOppm
ACTUAL CONG RESPONSE
0.0 0.0
8.09 9.3
15.15 16.2
30.0 30.1
Range 0 - 25%


PREDICTED
8.1
15.2
30.1



%CALERR
•
14.6%
6.6%
0.0%

ZERO GAS
MID RANGE
HIGH RANGE
C02
ZERO GAS
MID RANGE
HIGH RANGE
HCI
ZERO GAS
MID RANGE
IHIGH RANGE
ACTUAL CONG
0.0
11.04
19.2
Range 0 - 20%
ACTUAL CONC
0.0
11.03
19.0
Range 0 - SOppm
ACTUAL CONC
0.0
27.1
48.8
RESPONSE
0.1
11.3
19.2

RESPONSE
0.3
11.4
19.1

RESPONSE
0.9
26.4
47.8
DIFFERENCE
0.1
0.3
0.0

DIFFERENCE
0.3
0.4
0.1

DIFFERENCE
0.9
-0.7
-1.0
% SPAN
0.4%
1.0%
0.0%

% SPAN
1.5%
1.9%
0.5%

% SPAN
1.8%
•1.4%
-2.0%

-------
Project Number
Firm Name
Site Location
Tost Number
Source
Date
                                          Continuous Emissions Monitoring Data Sheet
                                                        EPA Methods 3A, 2SA, and 322
                         98042
   PES
            Testers
Austin-While  Ambient Temp
            Time
    1
Inlet Kiln #3
  6/30/98
                                100
                             14:18-15:58
      Analyzer
Hydrogen Chloride
Total Hydrocarbons
Oxygen
Carbon Dioxide
 Range
 0-50 ppm
 0-50ppm
                         0-25%
                         0-20%
                                  zero
                                  upscale
                                  zero
                                  upscale
                                  zero
                                  upscale
                                  upscale
                                                      0.9
                                                      47.8
                                                      nfe
                                                      n/a
                                                       0.4
                                                      11.3
                                0.5
                                11.4
                                           Pre Test
                                          Sys. Cal.
                                                                   0.9
                                                                   47.8
                                                                   0.0
                                                                   16.2
                                                                   0.1
                                                                   11.5
                                             0.3
                                             11.1
 Cal. Bias
% of Span
                                                                                0.0%
                                                                                0.0%
                                                                                n/a
                                                                                n/a
                                                                               -1.2%
                                                                                0.8%
   -1.0%
   -1.5%
   ±5%
Post Test
Sys. Cal.
                                                                                             1.2
                                                                                             46.9
                                                                                             0.0
                                                                                             15.1
                                                                                             0.0
                                                                                             11.4
   0.2
   10.9
 Cal. Bias
% of Span
                                                                                                          0.6%
                                                                                                         -1.8%
                                                                                                          n/a
                                                                                                          n/a
                                                                                                         -1.6%
                                                                                                          0.4%
   -1.5%
   -2.5%
   ±5%
   Drift
% of Span
                                                                                                                      -0.6%
                                                                                                                       1.8%
                                                                                                                       0.0%
                                                                                                                       2.2%
                                                                                                                       0.4%
                                                                                                                       0.4%
   0.5%
   1.0%
   ±3%
Avg. Analyzer
Response
1.2
Actual Gas
Cone.
n/a

-------
         INLET
HCI In-Situ Matrix Spike
 Recovery Efficiencies
Plant Austin White Austin, TX
Date 30-Jun-98
Project No. 98042
Test 1 Su-Native Concentration (ppm)
Initial Qt-Analyzer Flow (Ipm)
Qs-Dilution Rate
(Ipm)
Sm-Observed Concentration (ppm)
Ce-Expected Concentration (ppm)
Spike Recovery
%)
Su-Native Concentration (ppm)
Final Qt-Analyzer Flow (Ipm)
Qs-Dilution Rate
(Ipm)
Sm-Observed Concentration (ppm)
Ce-Expected Concentration (ppm)
Spike Recovery

Cs-Spike Gas Cone, (ppm) 303
4.8
13.75
1.5
37
34.1
108%
1.8
12.50
1.5
42.1
34.1
124%

-------
      TABLE C-3.5
Austin-White Lime Company
        Kiln No. 3
       30-June-98
        OUTLET
AustinJX

THC

ZERO GAS
LOW RANGE
MID RANGE
HIGH RANGE
O2

ZERO GAS
MID RANGE
HIGH RANGE
CO2

ZERO GAS
MID RANGE
HIGH RANGE
HCI

ZERO GAS
MID RANGE
HIGH RANGE
CALIBRATION ERROR TEST

Range 0 - SOppm
ACTUAL CONC
0.0
8.09
15.15
30.0
Range 0 - 25%
ACTUAL CONC
0.0
11.04
19.2
Range 0 - 20%
ACTUAL CONC
0.0
11.03
19.0
Range 0 - SOppm
ACTUAL CONC
0.0
27.1
48.8


RESPONSE
0.0
9.3
16.1
29.8

RESPONSE
0.1
11.3
19.2

RESPONSE
0.3
11.4
19.1

RESPONSE
0.8
26.3
48.5


PREDICTED
-
8.0
15.0
29.8

DIFFERENCE
0.1
0.3
0.0

DIFFERENCE
0.3
0.4
0.1

DIFFERENCE
0.8
-0.8
-0.3


% CAL ERR
-
15.6%
6.9%
0.0%

% SPAN
0.4%
1.0%
0.0%

% SPAN
1.5%
1.9%
0.5%

% SPAN
1.6%
-1.6%
-0.6%

-------
Project Numbar
Firm Nam*
Site Location
Test Number
Source
Data
                                          Continuous Emissions Monitoring Data Sheet
                                                        EPA Methods 3A, 2SA, and 322
   98042
    PES
            _ Tester*
Austin-White  Ambient Temp
     1       Time
Outlet Kiln »3
  6/30/98
   100
12:48-15:08
      Analyzer
Hydrogen Chloride
Total Hydrocarbon*
Oxygen
Carbon Dioxide
  Range
  0-50ppm
  0-SOppm
                        0-25%
                        0-20%
            zero
                                  upscale
Rack Cat.
                                  zero
                                  upscale
                                  zero
                                  upscale
                                  zero
                                  upscale
                                                      48.5
                                                      n/a
                                                      n/a
                                                      0.4
                                                      11.3
                                 o.s
                                11.4
Pre Test
Sys. Cal.
                                                                   0.8
                                                                   48.5
                                                                   0.0
                                                                   16.1
                                                                   0.1
                                                                   11.5
                0.3
                11.5
 Cat. Bias
% of Span
                                                                               0.0%
                                                                               0.0%
                                                                                n/a
                                                                                n/a
                                                                               •1.2%
                                                                               0.8%
               -1.0%
               0.5%
               ±5%
Post Test
Sys. Cal.
                                                                                             1.2
                                                                                            49.7
                                                                                             2.4
                                                                                             15.2
                                                                                             0.1
                                                                                             11.4
                 0.3
                10.9
 Cal. Bias
% of Span
                                                                                                         0.8%
                                                                                                         2.4%
                                                                                                          n/a
                                                                                                          n/a
                                                                                                         -1.2%
                                                                                                         0.4%
               •1.0%
               •2.5%
                ±5%
   Drift
% of Span
                                                                                                                      -2.4%
                                                                                                                      -4.8%
                                                                                                                      1.8%
                                                                                                                      0.0%
                                                                                                                      0.4%
                0.0%
                3.0%
                ±3%
Avg. Analyzer
Response
1.1
Actual Oas
Cone.
n/a

-------
                                 Outlet
                       HCI In-Situ Matrix Spike
                        Recovery Efficiencies
Plant          Austin White Austin, TX
Date          30-Jun-98
Project No.     98042	
                              Cs-Spike Gas Cone, (ppm)      303
TesM
Initial
Final
Su-Native Concentration (ppm)
Qt-Analyzer Flow (Ipm)
Qs-Dilution Rate (Ipm)
Sm-Observed Concentration (ppm)
Ce-Expected Concentration (ppm)
Spike Recovery
Su-Native Concentration (ppm)
Qt-Analyzer Flow (Ipm)
Qs-Dilution Rate (Ipm)
Sm-Observed Concentration (ppm)
Ce-Expected Concentration (ppm)
Spike Recovery (%)
 2.3
17.5
 1.5
22.4
26.0
86%

 1.1
17.5
 1.5
24.9
24.9
100%

-------
              TABLE C-3.8
Austin-White Lime Company Calibration Table
                Kiln No. 2
                1-July-98
                 INLET
Austin, TX

THC

ZERO GAS
LOW RANGE
MID RANGE
HIGH RANGE
02

ZERO GAS
MID RANGE
HIGH RANGE
CO2

ZERO GAS
MID RANGE
HIGH RANGE
HCI

ZERO GAS
MID RANGE
HIGH RANGE
CALIBRATION ERROR TEST

Range 0 - SOppm
ACTUAL CONG
0.0
8.09
15.15
30.0
Range 0 - 25%
ACTUAL CONG
0.0
11.04
19.2
Range 0 - 20%
ACTUAL CONG
0.0
11.03
19.0
Range 0 - SOppm
ACTUAL CONC
0.0
27.1
48.8


RESPONSE
1.6
9.3
16.4
29.4

RESPONSE
0.2
11.3
19.3

RESPONSE
0.2
11.2
19.1

RESPONSE
0
25.6
47.4


PREDICTED
-
9.1
15.6
29.4

DIFFERENCE
0.2
0.3
0.1

DIFFERENCE
0.2
0.2
0.1

DIFFERENCE
0.0
-1.5
-1.4


% CAL ERR
-
2.5%
5.0%
0.0%

% SPAN
0.8%
1.0%
0.4%

% SPAN
1.0%
0.9%
0.5%

% SPAN
0.0%
-3.0%
-2.8%

-------
 Project Number
 Firm Name
 Site Location
 Test Number
 Source
 Date
                                           Continuous Emissions Monitoring Data Sheet
                                                        EPA Methods 3A, 2SA, and 322
   96042
    PES
	Testers
 Austin-While  Ambient Temp
             Time
     1
 Inlet Kiln #2
   7/1/98
   100
                              14:45-17:05
      Analyzer
Hydrogen Chloride
Total Hydrocarbons
Oxygen
Carbon Dioxide
   Range
  o-50ppm
  0-50ppm
                         0-25%
                         0-20%
                                   zero
                                   upscale
Rack Cal.
             zero
                                   upscale
             zero
             upscale
             zero
             upscale
                                                      0.0
                                                      47.4
                                                      n/a
                                                      n/a
   0.2
   11.3
   0.2
   11.2
PreTest
Sys. Cal.
                                                                   o.o
                                                                   47.4
                                                                   1.6
                                                                   9.3
   0.4
   10.9
   0.2
   10.9
 Cal. Bias
% of Span
                                                                                0.0%
                                                                                0.0%
                                                                                n/a
                                                                                n/a
   0.8%
   -1.6%
   0.0%
   -1.5%
   ±5%
Post Test
Sys. Cal.
                                                                                             0.7
                                                                                             47.1
                                                                                             0.0
                                                                                             -8.9
   0.2
   10.9
   0.3
   10.8
 Cal. Bias
% of Span
                                                                                                          1.4%
                                                                                                         -0.6%
                                                                                                          n/a
                                                                                                          n/a
   0.0%
   -1.6%
   0.5%
   •2.0%
   ±5%
   Drift
% of Span
                                                                                                                      -1.4%
                                                                                                                       0.6%
                                                                                                                       3.2%
                                                                                                                      36.4%
   0.8%
   0.0%
   -0.6%
   0.5%
   ±3%
Avg. Analyzer
Response
2.5
Actual Gas
Cone.
n/a

-------
         INLET   -
HCI In-Situ Matrix Spike
 Recovery Efficiencies
Plant Austin White Austin, TX
Date 1-Jul-98
Project No. 98042
Test 1 Su-Native Concentration (ppm)
Initial Qt-Analyzer Flow (Ipm)
Qs-Dilution Rate (Ipm)
Sm-Observed Concentration (ppm)
Ce-Expected Concentration (ppm)
Spike Recovery (%)
Su-Native Concentration (ppm)
Final Qt-Analyzer Flow (Ipm)
Qs-Dilution Rate (Ipm)
Cs-Spike Gas Cone, (ppm) 303
2.4
12.0
1.5
42.7
35.8
119%
2.6
12.8
1.5
Sm-Observed Concentration (ppm) 35.9
Ce-Expected Concentration (ppm)
Spike Recovery (%)
34.0
105%

-------
              TABLE C-3.7
Austin-White Lime Company Calibration Table
                Kiln No. 2
                1-July-98
                OUTLET
Austin,TX
THC

ZERO GAS
LOW RANGE
MID RANGE
HIGH RANGE
02

ZERO GAS
MID RANGE
HIGH RANGE
CO2

ZERO GAS
MID RANGE
HIGH RANGE
HCI

ZERO GAS
MID RANGE
HIGH RANGE
CALIBRATION ERROR TEST
Range 0 - SOppm
ACTUAL CONC
0.0
8.09
15.15
30.0
Range 0 - 25%
ACTUAL CONC
0.0
11.04
19.2
Range 0 - 20%
ACTUAL CONC
0.0
11.03
19.0
Range 0 - SOppm
ACTUAL CONC
0.0
27.1
48.8

RESPONSE
0.0
9.3
16.1
29.8

RESPONSE
0.2
11.3
19.3

RESPONSE
0.2
11.2
19.1

RESPONSE
-0.6
26.4
47.8

PREDICTED
-
8.0
15.0
29.8

DIFFERENCE
0.2
0.3
0.1

DIFFERENCE
0.2
0.2
0.1

DIFFERENCE
-0.6
-0.7
-1.0

% CAL ERR
-
15.6%
6.9%
0.0%

% SPAN
0.8%
1.0%
0.4%

% SPAN
1.0%
0.9%
0.5%

% SPAN
-1.2%
-1.4%
-2.0%

-------
Project Number
Firm Name
Site Location
Test Number
Source
Date
   98042
    PES
                                           Continuous Emissions Monitoring Data Sheet
                                                        EPA Methods 3A, 2SA, and 322
Austin-White
     1
Outlet Kiln *2
   7/1/98
_ Testers
_ Ambient Temp
"Time
                                 100
                  14:45-17:05
      Analyzer
Hydrogen Chloride
Total Hydrocarbons
Oxygen
Carbon Dioxide
  Range
  O-SOppm
  o-50ppm
                         0-25%
                         0-20%
                                   zero
                                   upscale
                  Rack Cal.
                                   zero
                                  upscale
            zero
            upscale
            zero
            upscale
                                                       -0.6
                                                      47.8
                                                       rVa
                                                       n/a
                     0.4
                     11.3
                     0.5
                     11.4
Pre Test
Sys. Cal.
                                                                   -0.6
                                                                   47.8
                                                                    0.4
                                                                    9.7
   0.1
   11.5
   0.3
   11.5
 Cal. Bias
% of Span
                                                                                0.0%
                                                                                0.0%
                                                                                 n/a
                                                                                n/a
   -1.2%
   0.8%
   -1.0%
   0.5%
   ±5%
Post Test
Sys. Cal.
                                                                                             -0.3
                                                                                             46.7
                                                                                              0.7
                                                                                              9.8
   0.4
   11.0
   0.5
   10.6
 Cal. Bias
% of Span
                                                                                                          0.6%
                                                                                                          -2.2%
                                                                                                           n/a
                                                                                                           n/a
   0.0%
   •1.2%
   0.0%
   -4.0%
   ±5%
   Drift
% of Span
                                                                                                 -0.6%
                                                                                                                       2.2%
                                                                                                 -0.6%
                                                                                                                       -0.2%
   -1.2%
   2.0%
   •1.0%
   4.5%
   ±3%
Avg. Analyzer
Response
1.4
Actual Gas
Cone.
n/a

-------
                                 Outlet
                       HCI In-Situ Matrix Spike
                        Recovery Efficiencies
Plant          Austin White Austin, TX
Date          1-Jul-98
Project No.     98042	___
                              Cs-Spike Gas Cone, (ppm)     303
Testl
 nrtial
Final
Su-Native Concentration (ppm)
Qt-Analyzer Flow (Ipm)
Qs-Dilution Rate (Ipm)
Sm-Observed Concentration (ppm)
Ce-Expected Concentration (ppm)
Spike Recovery (%)

Su-Native Concentration (ppm)
Qt-Analyzer Flow (Ipm)
Qs-Dilution Rate (Ipm)
Sm-Observed Concentration (ppm)
Ce-Expected Concentration (ppm)
Spike Recovery
 3.8
 15.0
 1.5
 37.7
 31.0
122%

 2.1
 12.5
 1.5
 46.8
 34.3
136%

-------
                                                          J
   3 o
Austin-White Lime Company
14001 McNeil Road
Austin, Texas  73728
Page
                                                                      1 of 5
I. Test Run Observations Date
R • Recommended
M » Mandatory
1. Train set up " filter ID
filter weight
filter checked for holes
filter centered
nozzle clean
nozz le undamaged
nozzle diameter (in;)
probe liner clean
probe markings correct
probe heated along
entire length
impingers- charged 	
	 impingers- iced 	
	 meter- box leveled- • ...
pitot manometer' zeroed 	
	 orifice- manometer- zeroed 	
	 filter- box- or- holder- at- temp.
all ball joints lightly
' greased 	 • • •
all openings capped 	
2. Train leak check LC
at nozzle: initial (R) VAC

«OP2 cfm (§ 15 p^ j- f/iai LC •
in. Hg initial, intermediate^^) VAC
Intermediate and LC
final at highest intermediate (R) VAC
Vacuum during LC
test run.) intermediate (R) VAC
final (M) LC
VAC
3. Pitot lines leak initial positive line (R)
check; negative line (R)-
^HtbTd 3ii?p H20)
final positive line- (M)
on manometer for
(15 sec.) 	 negative- line- (R)
	 pxtot- tube- undamaged
M-3 bag initial leak check (M)
Tedlar bag: Should hold 2 to 4 in. 1^0
/ pressure for • 10' minutes - or 	
A// A zero flow meter reading on
'In continuous evacuation- or-
/ Completely fill bag and let
stand overnight — no deflation.
/WeJ"
0£p£&
Test
Run
M-21
V/A
AJ/A
^
^
i/
^
QSL
i/
>/
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. • ^s--
• ^
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Test
Run
4









































-------
Austin-White Lime Company
14001 McNeil Road
Austin, Texas  78728
Page
      2  of  5
Date
R » Recommended
M » Mandatory

4. M-3 sampling train check:
initial (M; 	 	
f/A (should hold
I/ M 10 in. vacuum final \M;
// for 1/2 mm.) 	
Purge sample train with- stack gas 	
Constant rate sampling 	 1- pm •
5. Time- test" started
• Time test ended 	
6. Dry gas ( ^^)' port initial
meter final 	
volume: (^ )• port' initial 	
	 final 	
I (* ) port initial 	
• - final 	
( • ) • port initial 	
	 final 	
7. Train operation Nozzle changed
during run during run -
	 NOT' ALLOWED 	

pitch' and' yaw of- probe- o.k". 	
nozzle- not scraped- on- nipple 	
effective- seal- around- probe 	
probe moved- af proper- time 	
probe .heated' •
\i calculator constants or nomograph
/ i3D£
f 1*4,1 1>]
/uo


t> *r
' ' 'A fc~
• • • v^^
WfrJ
CKO
T ftr t f


t'vy
/ 0 '
jv'

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(VV '^ I
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Tes
Run
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JVR


-------
        Austin-White Lime  Company
        14001 McNeil Road
        Austin,  Texas  78728
Page  3 of 5
Date
R = Recommended
M « Mandatory
Check on filter holder loosening of
clamping device holder
was silica gel changed
during run?
was any particulate lost?
Accurate £p
reading of: AH
meter temperature •
stack temperature 	
meter vacuum 	
time- per- point 	
impinger temperature 	
filter- box temperature 	
Minimum sample time of • '<£?•*>> ' min met
Minimum sample volume of 	 dscf collected


8. Post test: - All- openings* sealed 	
- recovery area- clean* sheltered 	
- filter handled- with gloves', " fo-fcepiSS
- petri dish sealed, labeled
- any sample lost
UcLi ro.S Srad cyl.
(yjjfljJt weighed
water measured raL gms
- silica gel weighed, net ems'
- condition - color 	

- - *- spent 	
- probe cooled sufficiently 	
- nozzle removed- and- brushed 	
- probe brushed 6 times • 	
- nozzle brushes- clean 	
^ m$2 ~ wash bottles clean 	
(j - acetone clean 	
/ - M-8 15" minute purge x 	
,y - water/solution clean ••/- -/Wi«-e*LA_;- '
'j~tfdjni*A •" blank taken: acetone,' water-, other
Probe brush and extension clean, •
Sample container: Clean
Capped
Labeled
Sealed 	
Liquid- level- marked

l<t
Test
Run
t
>l/0
' *rn
S.
^ •
iS,
• S
if
' ' 'c/ ' '
• • •v!L^


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Test
Run
n~d-Is
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' V-)
^rc . •
i/
i/
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Cs
(S
' ' ^/:
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• 'i/' ' '
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W>Q '
••a-
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•A^La'
' fyt1* '
' r^f* '
' ^V
M//}
'SlJ&A
«#*-^'
o^ • •
'•c^fcd'

-------
Austin-White Li,me Company
14001 McNeil Road
Austin, Texas  78728
                                                                 Pai«  4 of 5
Date
R * Recommended
M * Mandatory
4. Post test Orsat Analysis of Initial (M)
rtl integrated bag sample Orsat
fuf"^ analyzer - Analyzer leak check
U* (levels should not fall below Final (M)
cap. tubing and not more than
0.2 mL in burrette for 2 roin.)
Orsat- samples: Each bag analyzed 3' times
«, / i Z CO? agrees within 0.2%
A 1 1 M *' 67 agrees- within 0.2Z 	
/ V / / 1 Z CO agrees within- 0.2% 	
Analysis at end of test. Orsat analyzer
checked against air" (20; 9 ± 0; 3) 	
Orsat Analysis:
CO ")!•_
o?% 	
coz 	
/ Fo • 20.9 -X 0?
iA ] / /) ' % COo 	
I\J n Fuel 	
/ F,, range for fuel
Orsat analysis valid
Orsat solutions changed
when calculated Fo
exceeds fuel type range
10. All samples locked up
All sampling components clean- and sealed
7 All data sheets submitted to- observer 'T'/vJ
< - Orsat 	
- Run- isokenetic Team/Observer 	
- Particuiate recovery 	
- Process- data 	
- Charts 	 • 	
• -• Calibration sheets 	
Test
Run

/,
/ I



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Run
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-------
 Austin-White Lime Company
 14001 McNeil Road                                     ,   <~
 Austin, Texas  78723                                  fC  >          ,  f ,
                                                       r* s     Page 5 of 5

J.    NOTES:  Care  should be taken,  when sampling  for organic compounds,  to
     follow stringent quality control guidelines  to avoid contamination  of  the
     sample and sampling train.   Take note of any occurences which could bias
     the sample in any manner.

     Include: (1)  General comments; (2) Changes to pretest agreement with
     justification; (3) Identify (manufacturer) and describe condition of
     sampling equipment; (4) any abnormal occurrences during test program.
     (Additional page(s) attached:   Yes  ^/, No     .)
  Signature of Observer            Affiliation of Observer          Date

-------
                                 Page    / - 2.
Quality Control Check
Prior to Start of Tests
Keep all cleaned glassware sealed until train assembly
Assemble trains in dust free environment
Visually inspect each train for proper assembly
Level and zero manometer
Calculate proper sampling nozzle size
Visually inspect sampling nozzle for chips
Visually inspect Type S Phot tube
Leak check each leg of Type S Phot tube
Leak check entire sampling train
During Testing
Read temperatures and differential pressures at each
traverse point
Sample data and calculations recorded on preformatted
datasheets
Unusual occurrences noted in test log
Properly maintain the roll and pitch of axis of Type S
Pilots and sampling nozzle
Leak check train before and after any component
changes during test
Maintain the probe and fitter temperature
Maintain ice in ice water bath and maintain impinger
exit temperature
Calibration forms reviewed for completeness and
accuracy
Data sheets reviewed by PM daily during testing
Observation

Cffrvoi.
QLt»v\_e_
O*-*arvoj_
ouiv^e
ol(rw_? ( /*j/eT. 3.T6J
civv^e^
OLXrvt^_
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t
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17
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-"^G^
Xt-4jL£y
/^J^dO
Xt^Q^
                 \J
A

-------
Date
Page
- 2
Quality Control Check
After Testing
Visually inspect sampling nozzle
Visually inspect Type S Pilot tube
Leak check each leg of the Type S Pitot tube
Leak check the entire sampling train
Record observations if any
Field Log
Project name/ID and location
Sampling personnel (names/position)
Geological observations including map
Sample run times and dates
Sample descriptions
Description of QC samples
Deviations from QAPP
Difficulties in sampling or unusual conditions
Sample Labels
Sample ID
Date and time of collection
Lab technician initials
Analytical parameter
Preservative required
Observation

^-\IJtJ
J
J
^i€^
U
-t^JLA-J
0
u
" A ^* '
/"» Ll_4 L>Ow^.
£*JHI/ JTetoQv^T /*J/(?/
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» \ CL v v ^ v* r& / kO
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/ 1 £ T n 6 CI •* J v ^-^ C^TTx^t^ / 'jCiA&Wj
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           r

-------
/SCO/

                                         Date  J<^
                                         Page   /_
Quality Control Check
Prior to Stan of Tests
Keep all cleaned glassware sealed until train assembly
Assemble trains in dust free environment
Visually inspect each train for proper assembly
Level and zero manometer
Calculate proper sampling nozzle size
Visually inspect sampling nozzle for chips
Visually inspect Type S Phot tube
Leak check each leg of Type S Pitot tube
Leak check entire sampling train
During Testing
Read temperatures and differential pressures at each
traverse point
Sample data and calculations recorded on preformatted
datasheets
Unusual occurrences noted in test log
Properly maintain the roll and pitch of axis of Type S
Pilots and sampling nozzle
Leak check train before and after any component
changes during test
Maintain the probe and filter temperature
Maintain ice in ice water bath and maintain impinger
exit temperature
Calibration forms reviewed for completeness and
accuracy
Data sheets reviewed by PM daily during testing
Observation

Cx-w*-H
OUn/^-e
\
oLuvs^e,
oL«rv^
nL^ . ( 
U
~^^~A
u
-^-05
0
x
-------
Date
Page
- 2
Quality Control Check
After Testing
Visually inspect sampling nozzle
Visually inspect Type S Pitot tube
Leak check each leg of the Type S Pitot tube
Leak check the entire sampling train
Record observations if any
Field Log
Project name/ID and location
Sampling personnel (names/position)
Geological observations including map
Sample run times and dates
Sample descriptions
Description of QC samples
Deviations from QAPP
Difficulties in sampling or unusual conditions
Sample Labels
Sample ID
Date and time of collection
Lab technician initials

Analytical parameter
Preservative required
Observation

•M^a ,
J
•ts\ p^ ,
a
"•Mje-^j
d
-/4>C4
u
-"}JU» -
(T
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Ksujp -Ac^^tAA.IuJ) UudcJ AnuJLid^

-------
                          BAGHOUSE INLET KILN  #3

       The baghouse inlet is a rectangular duct measuring approximately 33.25 in. By 102 in.
From the pre-survey information it was reported in the site- test plan a 24- point traverse matrix
at six ports would be used.  Two ports were supposed to be installed for FTIR, HCL, CO2, and
O2 Continuous Emission Monitors (CEM) access, plant personnel told us this would be done only
if plant went down for main$nce. This did not happen and work could not be done so access was
made for the two CEM,s FTIR and HCL. There two probes occupied two of the existing ports
and one of the ports could not be opened. Method 23 sampling took place in port C, D, and E
using a- 18 point traverse matrix consisting of 6- traverse points of 3 traverse lines. Using this
matrix, we did run Iso-Kinetic at 102%.

       Negative pressure at this location was -20 in. Hq, a running start approach was used at
 this location.

-------
Austin-White Lime Company
14001 McNeil Road
Austin, Texas  78728
Page
      1 of 5
I. Test Run Observations Date
R - Recommended
M - Mandatory
1. Train set up ' filter ID
filter weight
filter checked for holes
filter centered
nozzle clean
nozz le • undamaged
nozzle diameter (in;}
probe liner clean
probe markings correct
probe heated along
entire- length 	
	 impingers- charged 	
	 impingers- iced 	
	 meter- box leveled- • • •
	 pitot manometer' zeroed 	
	 orifice- manometer- zeroed 	
	 filter- box- or- holder- ar temp-.
all ball joints lightly
	 greased 	 • • •
	 • all openings- capped 	
2. Train leak check LC 	
at nozzle: initial (R-)' • VAC 	
«Q02 efm /
O-Tk
j/'
^
•• ^
L^
l^-""
1^
i^^-*"**
• • t^-~~
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-------
Austin-White Lime Company
14001 McNeil Road
Austin, Texas  78728
Page
                                                                      2 of 5
Date
R « Recommended
M • Mandatory

4. M-3 sampling train check:
/ initial \n/ 	
/ A (should hold
// iu in. vacuum tinai \n) 	
for- 1/2' min. ) 	
Purge sample train with- stack' gas 	
Constant rate sampling 	 1- pm 	
5. Time- test' started' * 	
* Time test ended
6. Dry gas ( * )* port initial 	
meter 	 final 	
volume: (• )• port initial 	
	 final 	
( ) port initial 	
' * - final 	
( )* port initial 	
	 final 	
7. Train operation Nozzle changed
during run during run -
NOT ALLOWED 	

pitcn ana yaw ot* probe* o«k« 	
nozzle* not scraped* on- nipple 	
effective- seal' around- probe 	
probe moved- at' proper- time 	
probe .heated* 	
calculator constants or nomograph
changed when TS and /or TM
changes- significantly
average time to set
isokenetics after probe

Average values:
impinger temperature
should be < 70*F 	
Post filter gas streamer or
Filter box temperajCure— ^
<^550"F +~2|p<3200Fl
F' circle one 	 • • •
stack temperature' • X^-i^i^t*;^ ' '
barometric- P taken- and- value '
was probe ever disconnected
from filter holder while in
stack?
was filter changed during run?
Mf
Test
Run
/••/ 2^3*

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u

-------
Austin-White Lime Company
14001 McNeil Road
Austin, Texas  78728
Page  3 of 5
Date
R * Recommended
M - Mandatory

Check on filter holder loosening of
clamping device holder
was silica gel changed
during run?
was any particulate lost?
Accurate &P
reading of: AH
meter temperature 	
stack temperature 	
meter vacuum 	
time- per' point 	
impinger- temperature 	
filter- box temperature 	
Minimum sample time of ' •<•?/>• min met
Minimum sample volume of 	 dscf collected

8. Post test: -• All- openings- sealed 	
- recovery area- clean- sheltered 	
-• filter handled- with1 gloves', • #brcre^r>'
- petri dish sealed, labeled'
- any sample lost 	
grad cyl.
water measured • mL hffigfts tftx^tfej"
- silica gel weighed-, nef gms 	
- condition - color 	
	 Z- spent 	
- probe- cooled sufficiently 	
- nozzle removed- and' brushed 	
- probe brushed 6- times 	
» . - nozzle brushes- clean 	
jt/v«tu» M 95 ~ wash bottles clean 	
U - acetone clean 	
- M-8 15- minute* purge 	
- water/solution clean 	
/^fr-tL^Mi, - blank taken: acetone, water", other-
' Probe brush" and extension clean, -
Sample container:- Clean
Capped
Labeled
Sealed 	
Liquid- level- marked' •
l*let
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Run
*
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AJO
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-------
Austin-White Li)iae Company
14001 McNeil Road
Austin, Texas   78728
                                                                  Pa8«  4 of 5

Date
R * Recommended
M * Mandatory

9. Post test Orsat Analysis of Initial (M)
integrated bag sample Orsat
ill analyzer - Analyzer leak check
jrl (levels should not fall below Final (M)
cap. tubing and not more than
0.2 mL in burrette for 2 min.) 	
Orsat samples: Each bag analyzed 3 times
, . Z CO? agrees within 0-.2Z •
/]/ / 11 Z-0? agrees- within 0-.2Z 	
' / f' Z CO- agrees- within- 0-.2X 	
Analysis at end of test. Orsat analyzer
checked against air (20; 9 ±- 0;3) 	
Orsat Analysis:

o?z 	
cox 	
) . Fo - 20; 9 --Z 0->
/) ; / 4 z co' 	
f\J ft Fuel 	
Frtrange for fuel
Orsat analysis valid
Orsat solutions changed
when calculated Fo
exceeds fuel type range
10. All samples locked up
All sampling components- clean- and- sealed
All data- sheets submitted to- observer' • •" 7*7^
- Orsat 	
- Run- isokenetic • • • Teara/Observer 	
- Particuiate recovery 	
- Process- data 	
-• Charts 	
• -• Calibration sheets 	
Uf-
Test
Run

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-------
 Austin-White Liae Company
 14001 McNeil Road
 Austin, Texas  78728
                                                                  Page 5 of 5
J.   NOTES:  Care should be taken,  when sampling  for organic compounds,  to
     follow stringent quality control guidelines  to avoid contamination  of  the
     sample and sampling train.   Take note of any occurences which could bias
     the sample in any manner.

     Include: (1) General comments; (2) Changes to pretest agreement with
     justification; (3) Identify (manufacturer) and describe condition of
     sampling equipment; (4) any abnormal occurrences during test  program.
     (Additional page(s) attached:   Yes •££_,  No
                                                                 .  .->
  Signature of Observer            Affiliation of Observer          Date

-------
Austin-White Lime Company
14001 McNeil Road
Austin, Texas  78728
Date
Page
                                                                      »  1998
Quality Control Check
Prior to Start of Tests
fCeco all cleaned glassware sealed until train assembly

Assemble trains in dust free environment
Visually inspect each tram for proper assembly
Level and zero manometer
ffllciitflte muDu sampling, nozzle size

Visually inspect sampling nozzle for chips
Visually inspect Type S Pilot tube
Leak check each leg of Type S Phot tube
•
Leak check enure sampling train
During Testing

traverse point
Sample data and calculations recorded on prefonnatted
datasheets
Unusual occurrences noted in test log
Properly ip^frtatn the roll and pitch of axis of Type S
Pitots and sampling nozzle
Leak check train before and after any component
changes during test
Maintain the probe and filter temperature
Maintain ice in ice water bath and maintain wnpineer

exit temperature
Calibration forms reviewed for completeness and
accuracy
Data sheets reviewed by^fcCdaily during testing

Observation

J tM
J^.
d«^
CjL(n
-------
Austin-White Lime Company
14001 McNeil Road
Austin, Texas  73728
                                                       «
                                                       Date   Jva&J, 1998
                                                        Page  2r2
Quality Control Check
After Testing
Vicuallv invnect wnnlififf nozzle

Visually inspect Type S Pitot tube
Leak check each leg of the Type S Pitot tube
IAnir /»h«cir tfi^ entire 
-------
Austin-White Lime Company
14001 McNeil Road
Austin, Texas  78728
                                                        Page
Quality Control Check
Prior to Start of Tests
Keep all cleaned glassware sealed until train assembly
Assemble trains in dust free environment
Visually inspect each train for proper assembly
Level and zero manometer



Visually inspect sampling nozzle for chips

Visually inspect Type S Pitot tube
Leak check each leg of Type S Pitot tube
Leak check entire sampling tram
During Testing

traverse point

Sample data ana calculations recoraea on preiormatua
datasheets
Unusual occurrences noted in test log
Properly T)*™**™ the roll and pitch of axis of Type S
Pftots and sampling nozzle
Leak check train before and after any component
changes during test
Maintain the probe and filter temperature
Maintain ic? **i ice water taith and nmhttani tmninnr


Calibration forms reviewed for completeness and
accuracy
Data sheets reviewed by^M dairy during testing
Observation

OL«rvs_&_
OLUVLJL
oLtr^Ji
£MrK_e,
vL^ (t^J^J- .OTA }
te^
CL»rv^_Ji_
C^-*J-Uv~D
cLru^sL .bb3(S> /J~"//v
/
cLen^jL
cLtr^jz_ •
r-^C-O
-^s-^
^«-^J2-0
^*^
Sft*A
^^
-^4*-*
                     y -

-------
Austin-White Lime Company
14001 McNeil Road
Austin, Texas-  73728
                                                 ,r
Date
Page
                                                              •Ju'
                                                                uy
                                                               2^2
1SL98
Quality Control Check
After Testing

Visually inspect sampling nozzle
Visually inspect Type SPftot tube
Leak check each leg of the Type S Phot tube


Record observations if any
Field Log
Project name/ID and location
Sampling personnel (names/position)

Geological observations including map
Sample run tones and ^*tfy*

Sample descriptions
Description of QC samples
Deviations from QAPP
Difficulties in sampling or unusual conditions
Sample Labels
Sample ED
Date and time of collection
Lab tcchnir'*1* initials

Analytical parameter
Preservative required
Observation

J^
&hrif \
-TA
Pc.bQ*/i°co£s . THC . HCL,
-°?
Kv~\t> AJk**i+JcJ Li^L. ' Xrt^JL,', ^MuJakL
u ' y i

-------
                APPENDIX F

               PROCESS DATA
    Process data to be supplied to EPA EMC by
Research Triangle Institute under a separate contract.

-------
                   APPENDIX G




         SAMPLING & ANALYSIS METHODS




(EPA Methods 1, 2, 3A, 23 and proposed amendments, 25A, 322)

-------
      Appendix G. 1




Sampling & Analysis Methods




      EPA Method 1

-------
        EMISSION MEASUREMENT TECHNICAL INFORMATION CENT
                        NSPS TEST METHOD
 Method 1 - Sample and Velocity Traverses for Stationary Sources
1.  PRINCIPLE AND APPLICABILITY

1.1   Principle.   To  aid in  the representative measurement of
pollutant  emissions and/or  total  volumetric  flow  rate  from a
stationary source,  a measurement  site where the effluent stream is
flowing in a known direction  is selected, and the cross-section of
the stack  is divided into a  number of equal areas.   A traverse
point is then located within each of  these equal areas.
      •
1.2   Applicability.   This method  is applicable to  flowing gas
streams  in ducts,  stacks, and flues.   The method cannot be used
when:  (1)  flow is cyclonic or swirling (see Section 2.4),  (2) a
stack is smaller than about 0.30 meter (12  in.)  in diameter, or
0.071 m2 (113 in.2) in cross-sectional area, or  (3) the measurement
site is  less than two stack  or duct  diameters downstream or less
than a half  diameter upstream  from  a flow disturbance.

The  requirements   of  this  method  must  be  considered  before
construction of  a  new  facility  from which  emissions  will be
measured;  failure to do so may require subsequent alterations to
the  stack or  deviation  from  the  standard  procedure.    Cases
involving  variants are subject to approval by the Administrator,
U.S. Environmental Protection Agency.

2.  PROCEDURE

2.1    Selection   of Measurement  Site.   Sampling or velocity
measurement  is performed at a site located at least  eight stack or
duct diameters downstream and two diameters upstream from any flow
disturbance  such as a bend, expansion, or contraction in the stack,
or from  a visible flame.   If  necessary,  an alternative location may
be  selected, at a position  at least two stack or duct  diameters
downstream and a half diameter upstream from any flow disturbance.
For a rectangular  cross section,  an equivalent diameter  (D.)  shall
be  calculated  from the  following  equation,  to  determine  the
upstream and downstream distances:
 Prepared by Emission Measurement Branch              EMTIC TM-001
 Technical Support Division,  OAQPS, EPA

-------
        EMISSION MEASUREMENT TECHNICAL INFORMATION CENT
                        NSPS TEST METHOD
                                 2LW
                               (L +W)
                                                       Eq. 1-1
     Where
                    Length and W - width.
An  alternative  procedure   is   available  for  determining  the
acceptability of a measurement  location not meeting the criteria
above.  This procedure,
determination  of gas  flow  angles at  the  sampling points and
comparing the results with acceptability criteria, is described  in
Section 2.5.

2.2  Determining the Number of Traverse Points.

2.2.1   ^articulate Traverses.   When  the eight- and two-diameter
criterion can be met,  the minimum  number of  traverse points shall
be:  (1) twelve, for circular or rectangular  stacks with diameters
 (or  equivalent diameters)  greater than  0.61 meter (24 in.);  (2)
eight,  for  circular stacks with diameters  between 0.30 and 0.61
meter  (12 and 24 in.); and  (3)  nine,  for rectangular stacks with
equivalent  diameters between 0.30  and 0.61 meter (12 and 24 in.).

When the eight-  and  two-diameter criterion cannot be met,  the
minimum number of traverse points is determined from Figure 1-1.
Before referring to the figure, however, determine the distances
from the chosen measurement  site to  the  nearest  upstream  and
downstream  disturbances, and divide  each distance  by the stack
diameter or equivalent diameter, to determine the distance in terms
of the number of  duct  diameters.  Then,  determine  from Figure 1-1
the  minimum number of  traverse points that corresponds:  (1)  to the
number of  duct  diameters  upstream;  and  (2)  to the  number  of
diameters downstream.  Select the higher of the two minimum numbers
of traverse points, or a greater value,  so that for circular stacks
 the  number is  a multiple of 4, and  for rectangular  stacks,  the
number is one of those shown in Table 1-1.
 Prepared by Emission Measurement Branch
 Technical Support Division, OAQPS, EPA.
BMTIC TM-001

-------
EMTIC TM-001          EMTZC NSPS TEST METHOD               Page 3


2.2.2   Velocity  (Non-Particulate)  Traverses.   When  velocity or
volumetric  flow rate  is to be determined  (but  not  particulate
matter), the same procedure as  that used for particulate traverses
 (Section 2.2.1)  is  followed, except that Figure  1-2 may be used
instead of Figure 1-1.

2.3  Cross-Sectional Layout and Location of.Traverse Points.

2.3.1    Circular Stacks.    Locate  the traverse  points  on  two
perpendicular  diameters according  to  Table 1-2  and  the example
shown  in Figure  1-3.  Any  equation (for examples,  see Citations 2
and 3  in the Bibliography) that gives the same values as those in
Table  1-2 may  be used in lieu  of  Table  1-2.

For particulate  traverses,  one of the diameters  must be in  a plane
containing  the  greatest expected concentration variation, e.g.,
after  bends, one diameter shall be in the plane  of the bend.  This
requirement  becomes   less critical  as  the distance  from  the
disturbance  increases;  therefore, other diameter  locations may be
used,  subject  to the  approval  of the Administrator.

 In addition,  for stacks having diameters greater  than 0.61 m  (24
 in.),  no traverse points shall  be within 2.5  centimeters (1.00 in.)
 of the stack walls; and for stack diameters equal to  or  less than
 0.61 m (24 in.), no traverse points shall be located within 1.3 cm
 (0.50  in.) of  the stack walls.   To meet  these criteria, observe the
 procedures  given below.
 2.3.1.1 Stacks  With Diameters Greater Than 0.61 m  (24 in.).  When
 any of the traverse points as  located in Section 2.3.1 fall within
 2.5 cm (1.00 in.)  of  the
 stack walls,  relocate  them away  from  the  stack walls to:  (1)  a
 distance of
 2.5 cm (1.00  in.); or (2)  a distance equal to the nozzle inside
 diameter, whichever is  larger.   These relocated traverse points (on
 each end of a diameter) shall be the  "adjusted*  traverse  points.
 Whenever two  successive traverse points are  combined to form  a
 single adjusted traverse  point,  treat the  adjusted point  as  two
 separate traverse  points,  both in  the  sampling  (or  velocity
 measurement)  procedure, and in recording the data.

 2.3.1.2  Stacks With Diameters Equal To or Less  Than 0.61  m (24
 in.).   Follow the  procedure in Section 2.3.1.1,  noting  only that
 any "adjusted" points  should be relocated away from the stack walls
 to: (1)  a distance  of  1.3 cm (0.50 in.); or (2)  a  distance equal to
 the nozzle inside diameter, whichever is larger.

 2.3.2  Rectangular  Stacks.  Determine the number of traverse points
 as explained in Sections 2.1 and  2.2 of this method. From Table 1-

-------
EMTIC TM-001         EMTIC NSPS TEST METHOD                Page 4


1,  determine the grid  configuration.    Divide the  stack cross-
section into as many equal rectangular elemental areas as traverse
points, and  then locate a traverse  point at  the centroid of each
equal area according to the example in Figure 1-4.
If  the tester  desires  to use  more than  the minimum  number of
traverse points, expand the "minimum number  of traverse points*
matrix  (see  Table 1-1)  by adding  the  extra traverse points along
one or the other or both legs of the matrix; the final matrix need
not  be balanced.   For  example,  if a 4  x 3  "minimum  number of
points* matrix were expanded to 36 points, the final matrix could
be  9 x 4  or 12 x 3, and would not  necessarily have to be 6 x 6.
After constructing  the final matrix, divide the stack cross-section
into as many equal rectangular, elemental areas as traverse points,
and locate a traverse point at the centroid of each equal area. The
situation.of traverse points being too close to the stack walls is
not expected to arise with rectangular  stacks.   If this problem
should ever arise,  the  Administrator  must  be  contacted for
resolution of  the matter.

2.4 Verification of Absence of Cyclonic Flow.  In most  stationary
sources, the direction of stack gas  flow is essentially parallel to
the stack walls.  However,  cyclonic flow may  exist (1)  after such
devices  as  cyclones  and  inertial demisters  following venturi
scrubbers, or  (2) in stacks having tangential inlets or other duct
configurations which tend to induce swirling; in these  instances,
the presence or absence of  cyclonic flow at the sampling location
must be determined.  The following techniques  are acceptable for
this determination. Level and zero the  manometer.  Connect  a Type
S pitot tube to the manometer.  Position the  Type S pitot tube at
each traverse  point, in succession, so that the planes of the face
openings of the pitot tube are perpendicular to  the stack  cross-
 sectional plane; when the Type 8 pitot tube is in this position,  it
 is at "0° reference."  Note the differential pressure (Ap)  reading
 at each traverse point.  If a null (zero) pitot reading is obtained
 at  0°  reference  at a  given traverse  point, an  acceptable flow
 condition exists at that point.  If the pitot reading is not zero
 at  0°  reference,  rotate the pitot tube (up to  ±90° yaw angle),
 until a null reading is obtained.  Carefully determine and record
 the value of the rotation angle  (a) to the nearest degree.   After
 the null technique
 has been applied at each traverse point, calculate the average of
 the absolute values of  o; assign a values of 0° to those points for
 which no rotation  was  required,  and  include  these in the overall
 average.    If  the  average value of  o  is greater  than 20°,  the
 overall  flow condition  in  the  stack  is  unacceptable,  and
 alternative  methodology,   subject  to  the  approval  of  the
 Administrator, must be  used to perform accurate sample and velocity
 traverses.  The alternative procedure described in Section 2.5 may
 be used to  determine the rotation  angles in  lieu of the procedure

-------
EMTIC TM-001          EMTIC NSPS TEST METHOD               Page 5


described above.
2.5   Alternative Measurement Site Selection  Procedure.   This
alternative applies to sources where measurement locations  are less
than 2 equivalent or duct diameters downstream or less than one-
half  duct  diameter  upstream from a  flow disturbance.    The
alternative  should be  limited to  ducts larger  than 24  in.  in
diameter  where   blockage  and  wall  effects  are  minimal.    A
directional  flow-sensing probe is used  to  measure  pitch and yaw'
angles of the gas flow at 40 or more traverse points; the resultant:
angle is calculated and compared with acceptable criteria  for mean
and standard deviation.

NOTE:   Both the pitch and yaw angles are  measured  from a line
passing through  the traverse point and  parallel  to the stack axis.
The pitch angle is the angle of the gas flow component  in the plane
that INCLUDES the traverse line and is  parallel  to the stack axis.
The yaw angle is the angle of the gas  flow  component  in the plane
PERPENDICULAR to the traverse line at the  traverse point and  is
measured  from  the line  passing  through the  traverse point and
parallel to  the stack axis.

2.5.1  Apparatus.

2.5.1.1  Directional  Probe.  Any directional probe,  such as United
Sensor Type DA Three-Dimensional Directional  Probe, capable  of
measuring both the pitch and yaw angles of gas flows is acceptable.
 (NOTSt    Mention  of trade  name  or  specific products  does not
constitute   endorsement  by  the  U.S.  Environmental Protection
Agency.)  Assign an identification number to the directional probe*
and permanently mark or engrave the  number on  the  body of the
probe.  The pressure holes of directional probes are susceptible to
plugging when used in particulate-laden gas streams.  Therefore,  a
system for  cleaning the pressure  holes by "back-purging"  with
pressurized air is required.

2.5.1.2  Differential Pressure Gauges.  Inclined manometers, U-tube
manometers,  or other  differential  pressure gauges  (e.g., magnehelic
gauges) that meet the specifications described in  Method 2, Section
2.2.

NOTE:   If the differential pressure gauge  produces both negative
and positive readings,  then both negative  and positive  pressure
readings  shall  be  calibrated  at  a  minimum of  three points  as
 specified in Method 2, Section 2.2.

 2.5.2   Traverse  Points.  Use a minimum  of  40 traverse points for
 circular ducts  and 42 points for rectangular ducts for the gas flow
 angle  determinations.  Follow Section  2.3 and Table 1-1 or 1-2 for

-------
EMTIC TM-001         EHTIC NSPS TEST METHOD                Page 6


the location and layout of the traverse points.   If the measurement
location is determined to be acceptable
according to  the criteria in this alternative procedure, use  the
same traverse point number and locations for sampling and velocity
measurements.

2.5.3  Measurement Procedure.

2.5.3.1  Prepare the directional  probe and differential pressure
gauges as  recommended by the manufacturer.   Capillary  tubing or
surge tanks may be used to  dampen pressure  fluctuations.  It ia
recommended,  but  not  required,  that a  pretest leak  check be
conducted.  To perform a leak check, pressurize or use suction on
the  impact  opening until a reading of  at  least 7.6 cm (3 in.)  H20
registers on the differential pressure  gauge,  then plug the  impact
opening.  The pressure of a leak-free system will remain stable  for
at least 15 seconds.

2.5.3.2  Level and zero the manometers. Since the manometer level
and  zero may  drift because of vibrations  and  temperature changes,
periodically check the  level and  zero  during  the  traverse.

2.5.3.3  Position the probe at the appropriate locations  in the gas
stream, and rotate until  zero deflection  is  indicated for the  yaw
angle pressure gauge.  Determine and record the yaw angle.  Record
the  pressure  gauge  readings  for the pitch angle, and determine  the
pitch angle from the calibration curve.  Repeat this procedure  for
each traverse point.  Complete a "back-purge" of the pressure lines
and  the impact  openings  prior to measurements of  each traverse
point.

A post-test check as described in  Section 2.5.3.1 is required.   If
the  criteria  for  a leak-free system are  not  met, repair  the
equipment,  and repeat the flow angle measurements.

2.5.4   Calculate the resultant angle  at  each traverse point,  the
average resultant  angle,  and  the standard  deviation  using  the
 following  equations.  Complete the calculations retaining at least
 one extra  significant  figure beyond  that  of the acquired data.
 Round the values after the  final  calculations.

 2.5.4.1  Calculate the resultant  angle at each traverse point:

                Ri « arc cosine [(cosineYi) (cosinePi) J


                                                         Eq. 1-2

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EMTIC TM-001          EMTZC NSPS TEST METHOD               Page 7
Where:
          Ri   *    resultant angle at traverse point i, degree.
          Yi   -    yaw angle at traverse point i, degree.
          Pt   -    pitch angle at traverse point i, degree.

2.5.4.2  Calculate the average resultant for the measurements:
                                                            Hj. 1-3
Where:
          RM,   -    average resultant  angle, degree.
          n    «    total number of traverse points.

2.5.4.3   Calculate the standard deviations:
                                     -B\2
                                  (n-1)

                                                             HZ. 1-4
Where:
           Sd    -    standard deviation,  degree.

2.5.5  The measurement location is acceptable if R.^ * 20° and Sd
* 10°.

2.5.6  Calibration.   Use a flow system as described  in  Sections
4.1.2.1 and  4.1.2.2  of Method 2.   In addition, the  flow system
shall have the  capacity  to  generate  two test-section  velocities:
one between  365 and  730 m/min  (1200 and 2400  ft/min)   and  one
between 730 and 1100 m/min  (2400 and 3600 ft/min) .

2.5.6.1 Cut  two entry ports in the test  section.  The axes through
the entry  ports shall be  perpendicular to each other and intersect
in the  centroid of the test section.  The ports should be elongated
slots parallel  to the  axis  of  the  test  section  and of sufficient
length to  allow measurement of pitch angles while maintaining the
pitot head position at the  test-section centroid.   To facilitate
alignment  of  the  directional probe during calibration,  the test
section  should  be  constructed  of  plexiglass  or  some  other
transparent material.   All calibration measurements should be made
at the same point in the test section, preferably at the centroid
of the test section.

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EMTIC TM-001         EMTIC NSPS TEST METHOD                Page 8


2.5.6.2  To  ensure that the gas flow is parallel  to the central
axis of the test section, follow the procedure in Section 2.4 for
cyclonic flow determination to measure the gas flow-angles at the
centroid of the test section from two test ports located 90° apart.
The  gas flow  angle measured  in each  port must  be  ±2°  of 0°.
Straightening vanes should be installed, if necessary,  to meet this
.criterion.

2.5.6.3  Pitch Angle Calibration.  Perform a calibration traverse
according  to  the manufacturer's  recommended  protocol  in   5°
increments for angles from -60° to +60° at one velocity in each  of
the two ranges specified above.  Average the pressure  ratio values
obtained  for  each angle  in the  two  flow ranges,  and  plot  a
calibration curve with the average values of the pressure ratio (or
other   suitable   measurement  factor  as  recommended  by  the
manufacturer) versus the pitch angle.  Draw a smooth  line through
the  data points.   Plot also the  data values  for each traverse
point.  Determine  the  differences between the measured datavalues
and  the angle  from the  calibration  curve at  the same pressure
ratio.   The difference  at  each  comparison must be within 2° for
angles between 0°  and 40° and within 3° for angles  between 40° and
60*.

2.5.6.4   Yaw Angle Calibration.  Mark the  three-dimensional  probe
to allow  the determination of the yaw position of the probe.  This
is usually a line extending  the  length of the probe and  aligned
with the impact opening.  To determine the accuracy of measurements
of the yaw angle,  only the zero or null position need be calibrated
as .follows:   Place the directional  probe in the test section, and
rotate  the  probe  until the  zero position  is  found.   With a
protractor or  other  angle measuring device,  measure the  angle
 indicated by  the yaw angle  indicator  on the  three-dimensional
probe.   This should be  within 2° of  0°.  Repeat this measurement
 for any other points along the length of the pitot where yaw angle
 measurements could be read in order to  account  for  variations  in
 the pitot markings used to indicate pitot head positions.

 BIBLIOGRAPHY

 1.   Determining  Dust  Concentration   in  a   Gas  Stream,   ASMS
      Performance Test Code No.  27.   New York.   1957.

 2.   DeVorkin,  Howard, et al.  Air Pollution Source Testing Manual.
      Air Pollution Control District.   Los Angeles,  CA.  November
      1963.

 3.   Methods for  Determining of Velocity, Volume,  Dust  and Mist
      Content of  Gases.   Western  Precipitation Division  of   Joy

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rlMTIC TM-001         EMTIC NSPS TEST METHOD                Page 9


     Manufacturing Co.  Los Angeles, CA.  Bulletin WP-50.  1968.

4.   Standard Method for  Sampling  Stacks for Particulate Matter.
     In: 1971 Book of ASTM Standards, Part 23.  ASTM Designation D
     2928-71.  Philadelphia, PA.  1971.

5.   Hanson,  H.A.,  et al.   Particulate Sampling Strategies for
     Large  Power Plants  Including Nonunifonn Flow.   USEPA, ORD,
     ESRL,  Research Triangle Park, NC.  EPA-600/2-76-170.   June
     1976.

6.   Entropy Environmentalists,  Inc. Determination of the Optimum
     Number of Sampling Points: An Analysis of Method 1 Criteria.
     Environmental Protection Agency.   Research Triangle Park, NC.
     EPA Contract No.  68-01-3172, Task  7.

7.   Hanson,  H.A.,  R.J.  Davini,  JlK.   Morgan, and A.A. Iversen.
     Particulate Sampling   Strategies   for  Large Power   Plants
     Including Nonuniform Plow.  USEPA,  Research Triangle Park, NC.
     Publication No. EPA-600/2-76-170.   June 1976.  350 p.

 8.   Brooks,  E.F.,  and R.L.  Williams.   Flow  and  Gas Sampling
     Manual.    U.S. Environmental  Protection Agency.  Research
     Triangle Park, NC.   Publication No. EPA-600/2-76-203.   July
     1976.   93  p.

 9.   Entropy Environmentalists,  Inc.    Traverse  Point Study.   EPA
     Contract No.  68-02-3172.   June 1977.   19 p.

 10. Brown, J.  and K.  Yu.   Test Report:  Particulate Sampling
      Strategy in  Circular Ducts.   Emission Measurement  Branch.
     Emission   Standards   and   Engineering  Division.      U.S.
      Environmental Protection Agency,   Research  Triangle Park,  NC
      27711.  July 31,  1980.  12 p.

 11.  Hawks ley,  P.G.W., S. Badzioch, and J.H. Blackett.  Measurement
      of Solids  in  Flue Gases.  Leatherhead, England, The  British
      Coal Utilisation Research Association.  1961.  p. 129-133.

 12.  Knapp,  K.T.   The  Number  of Sampling  Points Needed  for
      Representative Source Sampling.  In: Proceedings  of the Fourth
      National Conference on Energy and Environment.   Theodore, L.
      et al. (ed).   Dayton, Dayton Section of the  American Institute
      of Chemical Engineers.  October 3-7,  1976.   p.  563-568.

 13.  Smith, W.S.  and D.J.  Grove.   A  Proposed  Extension  of EPA.
      Method  1  Criteria.    Pollution  Engineering.  XV (8):36-37.

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EMTIC TM-001          EMTIC NSPS TEST METHOD               Page 10


     August 1983.

14.  Gerhart,  P.M.  and M.J. Dorsey.   Investigation of Field  Test
     Procedures for Large Fans.  University of Akron.  Akron, OH.
      (EPRI Contract CS-1651).  Final  Report  (RP-1649-5).   December
     1980.

15.  Smith, W.S. and D.J. Grove.  A New Look at Isokinetic Sampling
     -  Theory and  Applications.    Source  Evaluation Society
     Newsletter.  VIII(3):19-24.  August 1983.

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EMTIC TM-001
EMTIC NSPS TEST METHOD
Page 11
               Table 1-1.  CROSS-SECTION LAYOUT FOR
                        RECTANGULAR STACKS
                                 traverse points
                          9
                         12
                         16
                         20
                         25
                         30
                         36
                         42
                         49
                          3x3
                          4x3
                          4X4
                          5x4
                          5x5
                          6x5
                          6x6
                          7x6
                          7x7

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EMTIC TM-001
EMTIC NSPS TEST METHOD
Page 12
                            TABLE 1-2
         LOCATION OF TRAVERSE POINTS IN CIRCULAR STACKS
             (Percent of stack diameter from inside
                     wall to traverse point)
Traverse
Point
Number on a
Diameter
1 	

2 	

3 	

4 	

5 	

6 	

7 	

8 	

9 	

10 ....
11 ....
12 ....
13 ....
14 ....
Number of traverse points on a diameter
2
14
.6
85
.4












4
6.
7
25
.0
75
.0
93
.3










6
4.
4
14
.6
29
.6
70
.4
85
.4
95
.6








8
3.
2
10
.5
19
.4
32
.3
67
.7
80
.6
89
.5
96
.8






10
2.6
8.2
14.
6
22.
6
34.
2
65.
8
77.
4
85.
4
91.
8
97.
4




12
2.1
6.7
11.
8
17.
7
25.
0
35.
6
64.
4
75.
0
82.
3
88.
2
93.
3
97.
9


14
1.8
5.7
9.9
14.
6
20.
1
26.
9
36.
6
63.
4
73.
1
79.
9
85.
4
90.
1
94.
3
98.
2
16
1.6
4.9
8.5
12.
5
16.
9
22.
0
28.
3
37.
5
62.
5
71.
7
78.
0
83.
1
87.
5
91.
5
18
1.
4
4.
4
7.
5
10
.9
14
.6
18
.8
23
.6
29
.6
38
.2
61
.8
70
.4
76
.4
81
.2
85
.4
20
1.
3
3.
9 I
6.
7
9.
7
11
2.
9
16
.5
20
.4
25
.0
30
.6
38
.8
61
.2
69
.4
75
.0
79
.6
22
1.1
3.5
6.0
8.7
11.
6
14.
6
18.
0
21.
8
26.
2
31.
5
39.
3
60.
7
68.
5
73.
8
24
1.1
3.2
5.5
7.9
10.
5
13.
2
16.
1
19.
4
23.
0
27.
2
32.
3
39.
8
60.
2
67.
7

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EMTIC TM-001
EMTIC NSPS TEST METHOD
Page 13
15 ....
16 ....
17 ....
18 ....
19 ....
20 ....
21 ....
MM • • • •
w<3 • • • •
24 ....






































































95.
1
98.
4








89
.1
92
.5
95
.6
98
.6




•

83
.5
87
.1
90
.3
93
.3
96
.1
98
.7




78.
2
82.
0
85.
4
88.
4
91.
3
94.
0
96.
5
98.
9


72.
8
77.
0
80.
6
83.
9
86.
8
89.
5
92.
1
94.
5
96.
8
98.
9

-------
EMTIC  TM-001
EMTIC N8PS TEST METHOD
Page 14
                      DM DtMMton UprtMB torn Plow DMoftwne** (DMMH A)

                          1J	1J	M
              10
                     I
                          li tor
                    Mwl
                   i
                                L
                      9     4     I    •     7     •

                      Dud Dlrackn Dawmtaam tarn Pirn DMnb«»c** (DMMM •)
          Figure  1-1. Minimum number of  traverse  points  for
          particulate traverses.

-------
EMTIC TM-001
      EMTIC NSPS TEST METHOD
                                     Page  15
           so
           40
           M
           20
           10
                     Duet Dtamotera Uprinam from Flew DMuitaanca* (DManoa A)
                           141            1JI            24
                     1
       1
1
1
                   R*cta
                            lorDwk
                             10
                   DMurtwue* (BMd. Ex^tmlMt. CenkadN. «fe)

                     1       1      1      1
1
                                                       ia
                                                             • «•
                           •lack DtofMtor • 0 JO to 0 J1 • (1144 ax)
                           I	I	I	
34567      •
 Duet Dtamaten Dowiulnam from Flew Disturbance* (OMane* •)
                                                                    10
     Figure  1-2.  Minimum number of  traverse  points  for velocity
      (nonparticulate) traverses.

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EMTIC TM-001
EMTIC NSPS TEST METHOD
Page 16
               MI
               MJ
               TU
     Figure 1-3. Example showing circular stack  cross section
     divided into 12  equal areas,  with location of  traverse
     points indicated.

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EMTIC TM-001
EMTIC NSPS TEST METHOD
Page 17
1
0

o
	
o

o
k— — 4
o
......
o

o
_____(
o
.....
o

o

o

0
   Figure 1-4. Example  showing  rectangular stack cross section
   divided into 12 equal areas, with a traverse point at centroid
   of each area.

-------

-------
       Appendix G.2




Sampling & Analysis Methods




      EPA Method 2

-------

-------
              EMISSION MEASUREMENT TECHNICAL INFORMATION
                               NSPS TEST METHOD
        Method 2 - Determination of Stack 9as Velocity and Volumetric
                        Flow Rate  (Type 8 Pitot Tube)
1.  PRINCIPLE AMD APPLICABILITY

1.1  Principle.  The average gas velocity in a stack is determined from the gas
density  and from  measurement of  the average  velocity head with  a Type 8
(StausBcheibe or reverse type) pitot tube.

1.2  Applicability.  This method is applicable  for measurement of the average
velocity of a gas stream and for quantifying gas flow.

This procedure ia not applicable at measurement site* that  fail  to meet  the
criteria of Method 1, Section 2.1.  Also, the method cannot be used for direct
measurement in cyclonic or swirling gas streams} Section 2.4 of Method 1 shows
how  to  determine  cyclonic  or  swirling flow conditions.    When unacceptable
conditions exist,  alternative procedures,  subject  to the  approval  of   the
Administrator, U.S.  Environmental  Protection Agency,  must be employed to make
accurate flow rate determinations;  examples of such alternative procedures are:
 (1) to install straightening vanes;  (2) to calculate the total volumetric flow
rate stoichiometrically,  or  (3)  to move to another measurement site at which  the
flow is  acceptable.

2.  APPARATUS

Specifications for the apparatus are given below.   Any other apparatus that  has
been  demonstrated (subject  to approval of the Administrator) to be  capable of
meeting  the specifications will be  considered acceptable.
        j*
2.1  Type  a Pitot Tube.   Pitot tube  made of metal tubing (e.g., stainless steel)
as  shown  in Figure  2-1.  It  is recommended that the external tubing diameter
 (dimension DC. Figure 2-2b)  be between 0.48 and 0.95 cm (3/16 and  3/8  inch).
There  shall be an equal distance from the base of each leg of the pitot  tube to
its  face-opening plane  (dimensions P* and %,  Figure 2-2b);  it  is recommended
that this  distance be between 1.05 and 1.50 times the  external tubing diameter.
The face openings of the pitot tube  shall, preferably, be aligned as shown in
Figure 2-2;  hovever, slight misalignments of the openings are permissible  (see
Figure 2-3).

The Type S pitot tube shall have a known coefficient,  determined as outlined in
Section 4. An identification number shall be assigned to the pitot tube;  this


Prepared by Emission Measurement Branch                            EMTIC M-002
Technical Support Division, OAQPS,  EPA

-------
              EMISSION HS&SURSMHZTT TECHNICAL INFORMATION CKHT1H
                               NSPS TX8T II
number shall  be permanently narked or  engraved on the body of the  tube.  A
standard pi tot tube nay be used instead of a Type B, provided that it meets the
specifications of Sections 2.7 and 4.2; note, however, that the static and impact
pressure  holes  of  standard pitot tubes  are susceptible to  plugging  in
particulate-laden gas streams.  Therefore, whenever a standard pitot tube is used
to perform a traverse, adequate proof must be furnished that the openings of the
pitot tube have not plugged up during the traverse period; this can be  done  by
taking a velocity head (Ap)  reading at the final traverse point* cleaning out the
impact  and static  holes of  the  standard pitot  tube by •back-purging"  with
pressurized air,  and then taking  another  Ap reading.   If the Ap readings made
before  and after  the air  purge  are  the same  (±5 percent), the traverse  is
acceptable.   Otherwise,  reject- the run.  Note that if Ap  at  the final traverse
point is unsuitably low, another point  may be selected.  If  "back-purging"  at
regular  intervals is part of  the procedure, then comparative Ap readings  shall
be  taken,  as  above,  for the last  two  back purges at which suitably  high  Ap
readings are  observed.

2.2 Differential Pressure Gauge.  An inclined  manometer  or equivalent device.
Most sampling trains  are equipped with a 10-in.  (water column) inclined-vertical
nanometer, having 0.01-in.  HgO divisions on the  0-  to  1-in. inclined scale, and
0.1-in.  H,0 divisions on the 1- to 10-in. vertical scale.   This type of manometer
 (or other gauge of equivalent sensitivity)  is satisfactory for  the measurement
of  Ap values  as low as 1.3 mm (0.05 in.) H»0.  However,  a differential pressure
gauge of  greater sensitivity shall be used (subject to the approval of the
Administrator),  if any of the following is found to be true: (1)  the arithmetic
average of all Ap readings at the traverse  points in the stack  is  less than
1.3 mm  (O.O5 in.)  H,0;  (2)  for traverses of 12 or more points,  more  than 10
percent of the individual Ap readings are below 1.3 mm (0.05 in.) H,0; (3) for
 traverses of fewer than 12 points, more than  one Ap reading is  below 1.3 mm
 (0.05  in.) HjO.  Citation 18 in the Bibliography describes• commercially available
 instrumentation for  the measurement of  low-range gas velocities.

 As an alternative to criteria (1) through (3) above,  the following calculation
 may  be  performed  to  determine  the  necessity  of  using  a  more  sensitive
 differential pressure gauge:
 Prepared by Kmisiion Measurement Branch                            BMXXC M-002
 Technical Support Division,  OAQPS, BPA

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EMTIC TM-002                     NSPS TBST METHOD               .        Page 3
                               +K
                         n

                         I
Where:

        Apt  •     Individual velocity head reading at a traverse point, mm (in.)
                   H,0.

        n   •     Total number of traverse points.

        K   •     0.13 mm H,0 when metric unit* are used and 0.005 in. HjO when
                   English units are used.

 If T is greater than  1.05, the velocity head data are unacceptable and a more
 sensitive differential pressure gauge must be used.

 XlOTlt  If differential pressure gauges other than inclined manometers are used
 (e.g.,  magnehelic gauges),  their calibration must be checked after each test
 series.  To check the calibration of a differential pressure gauge,- compare Ap
 readings  of the gauge  with those  of a gauge-oil manometer at a minimum of three
 points, approximately representing the range of Ap values in the stack. If, at
 each point, the  values of Ap  as read by the differential pressure gauge and
 gauge-oil manometer agree to within 5 percent, the differential pressure gauge
 shall be  considered to be in proper calibration.   Otherwise, the test series
 shall either be voided,  or procedures to adjust the measured Ap values and final
 results shall be used, subject to the approval of the Administrator.

 2.3    Temperature Gauge.   A thermocouple,  liquid-filled bulb  thermometer,
 bimetallic thermometer, mercury-in-glass thermometer, or other gauge capable of
 measuring  temperature to  within 1.5  percent of the minimum  absolute stack
 temperature. The temperature gauge shall be  attached to the pi tot tube such that
 the sensor tip does not touch any metal; the gauge shall be in an interference-
 free arrangement  with  respect to the pi tot  tube face openings (see Figure 2-1 and
 also Figure 2-7 in Section 4).   Alternative positions may be used if the pitot
 tube-temperature gauge system is calibrated according to the procedure of Section
 4.  Provided that a difference of not more  than 1 percent din the average velocity
 measurement is introduced,  the temperature gauge need  not be attached to the
 pitot  tube; this  alternative is  subject to  the approval of the Administrator.

 2.4  Pressure  Probe and Gauge.   A piezometer tube and mercury- or water-filled
 U-tube manometer capable of measuring stack  pressure to within 2.5 mm (0.1 in.)
 Big.  The  static tap of a standard type pitot tube or  one leg of a Type  8 pitot
 tube with the  face opening planes positioned parallel to the gas flow may also
 be used as the pressure probe.

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EMTIC TM-002                     HSP8 TB8T METHOD                       page 4


2.3   Barometer.  A mercury, aneroid, or other barometer capable of measuring
atmospheric  pressure to within  2.5 mm  (0.1 in.)  Eg.   See HOTS in Method 5,
Section 2.1.9.

2.6   Gas  Density Determination Equipment.  Method 3 equipment,  if needed (see
Section 3.6),  to determine the  stack gas dry molecular weight, and Reference
Method 4 or Method 5 equipment  for moisture content determination; other methods
may be used  subject  to approval  of  the Administrator.

2.7   Calibration Pitot  Tube.    When calibration of the Type  8 pitot  tuba is
necessary  (see Section 4), a standard pitot tube for a reference. The  standard
pitot tube shall, preferably,  have a known  coefficient,  obtained either  (1)
directly from the National Bureau of Standards, Route 70 S, Quince Orchard Road,
Gaithersburg, Maryland,  or (2) by calibration against another standard pitot tube
with  an NBS-traceable coefficient.  Alternatively, a standard pitot tube designed
according to  the criteria given in Sections 2.7.1 through  2.7.5 below  and
illustrated  in Figure 2-4  (see also Citations 7, 8,  and 17 in the Bibliography)
may be used.  Pitot tubes designed according to these  specification* will have
baseline  coefficients of about 0/99 ±  0.01.

2.7.1 Hemispherical (shown in Figure  2-4)  ellipsoidal, or conical tip.

2.7.2  A minimum of six diameters straight  run (based upon D, the  external
diameter of the tube) between the tip and the static pressure holes.

2.7.3  A  minimum of eight diameters straight run' between the static pressure
holes and the center line of the external tube, following the 90-degree bend.

2.7.4 Static pressure holes of equal size (approximately 0.1 D), equally spaced
in a piezometer ring configuration.

2.7.5  Ninety-degree bend, with curved or mitered junction.

2.8  Differential Pressure Gauge for Type 8 Pitot Tube  Calibration.  An inclined
manometer or equivalent.   If  the single-velocity  calibration technique is
 employed  (see Section 4.1.2.3), the calibration differential pressure gauge shall
be  readable to the nearest  0.13 mm   (0.005  in.)  RaO.   For multivelocity
 calibrations,  the gauge shall be readable to the nearest 0.13 on (0.005 in.) HjO
 for  &p values between 1.3 and 25 mm (0.05  and 1.0 in.)  HaO, and to the nearest
 1.3 mm (0.05 in.) H,0 for &p values above 25  mm (1.0 in.)  HaO.   A special, more
 sensitive gauge will be  required to read Ap  values below 1.3  mm (0.05 in.) H»0
 (see Citation 18 in the Bibliography).


 3.   PROCKDORK

 3.1   Set up the apparatus as shown in  Figure 2-1.  Capillary  tubing or surge
 tanks installed between the manometer and pitot tube may be used  to  dampen Ap
 fluctuations.  It is recommended, but not required, that a pretest leak-check be
 conducted as follows:  (!)• blow through the pitot impact opening until at least

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EMTIC TM-002                     NSPS TEST METHOD                        Pag* 5


7.6 cm (3 in.) HjO velocity pressure registers on the manometer; then, close off
the impact opening.   The pressure shall  remain stable for at  least 15 seconds;
(2) do the same for the static pressure side, except using suction to "H-yjhn the
minimum of  7.6 cm (3 in.) H,0.   Other  leak-check  procedures, subject  to the
approval of the Administrator, may be used.

3.2  Level  and zero  the manometer.  Because the manometer level  and zero may
drift due to vibrations and temperature changes, make periodic check* ^rlnj the
traverse.   Record all  necessary data  as  shown in  the example data sheet
(Figure 2-5).

3.3  Measure the velocity head and temperature at the traverse points specified
by Method 1.   Ensure  that  the proper differential pressure gauge is being used
for the range of Ap values  encountered  (see Section 2.2).  If it is necessary to
change to a more sensitive gauge, do so, and  remeasure the Ap and temperature
readings at each traverse point.   Conduct a post-test leak-check  (mandatory), as
described in  Section  3.1 above, to validate  the traverse  run.

3.4  Measure the static pressure in the stack.   One reading is usually adequate.

3.5  Determine the atmospheric pressure.

3.6  Determine the stack gas dry molecular weight.  For combustion processes or
processes that emit essentially CO,, 03,  CO,  and Na, use Method 3.   For processes
emitting essentially  air, an analysis need not be conducted; use  a  dry molecular
weight of 29.0.  For  other processes,  other methods, subject to the approval of
the Administrator, must be used.

3.7  Obtain the moisture content from Reference Method 4 (or equivalent)  or from
Method 5.

3.8   Determine the cross-sectional area of the stack or duct at the sampling
location.  Whenever possible,  physically measure the stack dimensions rather than
using blueprints.

4. CALIBRATION

4.1   Type  8 Pi tot Tube.  Before its initial use,  carefully examine the Type S
pi tot tube  in top, side, and end  views  to verify that the face openings of the
tube are aligned within the specifications illustrated in Figure 2-2 or 2-3. The
pitot tube shall not  be used if it fails  to meet these alignment  specifications.

After verifying the  face  opening alignment, measure and record the following
dimensions  of the pitot tube:  (a)  the external tubing diameter (dimension D,,
Figure 2-2b);  and  (b) the base-to-opening plane distances  (dimensions PA and P»,
Figure 2-2b).  If DC  is between 0.48 and 0.95 cm (3/16 and 3/8  in.), and if %
and P, are  equal  and  between 1.05 and 1.50 D<, there are two possible options:
 (1)  the pitot tube may be calibrated according to the procedure outlined in
Sections 4.1.2 through 4.1.5 below, or (2) a baseline (isolated tube)  coefficient
value of 0.84 may be assigned to the  pitot tube.   Note, however, that if the

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EMTIC TM-002                     NSP8 TB8T METHOD                       Page 6


pitot tube  ia part of an assembly, calibration may still be required, despite
knowledge of  the baseline coefficient value  (see Section 4.1.1).

If  De,  H,  and f  are  outside the specified  limits,  the pitot  tube must  be
calibrated  as outlined in Sections 4.1.2  through 4.1.5 below.

4.1.1  Type 8 Pitot Tube Assemblies.  During sample and velocity traverses,  the
isolated Type S pitot tube is not always used;  in many  inntaTires, the pitot tuba
is  used in combination with other source-sampling components  (thermocouple,
sampling probe, nozzle) as part of  an "assembly." The presence of other sampling
components  can sometimes  affect the baseline value of  the Type S  pitot tube
coefficient (Citation 9 in the Bibliography); therefore an assigned (or otherwise
known) baseline coefficient value may or may not be valid for a given assembly.
The baseline  and  assembly coefficient values  will be identical only when the
relative placement of the components in  the assembly  is such that aerodynamic
 interference  effects are  eliminated.    Figures  2-6 through 2-8  illustrate
 interference-free  component arrangements for Type 8 pitot tubes having external
 tubing diameters between. 0.48 and  0.95 cm (3/16 and 3/8 in.).  Type 8 pitot tube
 assemblies that fail to meet any or all of the specifications of Figures 2-6
 through 2-8 shall  be calibrated according to the procedure outlined  in Sections
 4.1.2  through 4.1.5 below,  and prior to  calibration,  the values of  the
 intercomponent spacings  (pi tot-nozzle, pitot-thermocouple, pi tot-probe sheath)
 shall be measured and recorded.

' NOTBi  Do not use any Type S pitot tube assembly which is constructed such that
 the impact pressure opening plane of  the pitot tube is below the entry plane  of
 the nozzle (see Figure 2-6B).
                                      •
 4.1.2  Calibration Setup.  If the Type S pitot tube is to be calibrated, one  leg
 of the tube  shall be permanently marked A,  and the other, B.  Calibration shall
 be done in a flow system having the  following essential design features:

 4.1.2.1 The flowing gas stream must be confined to  a  duct of definite  cross-
 sectional area, either circular or rectangular. For circular cross sections,  the
 minimum duct diameter shall be 30.5 cm  (12  in.); for rectangular cross sections,
 the width  (shorter side)  shall be at least 25.4 cm (10  in.).

 4.1.2.2  The cross-sectional area of the calibration duct must be  constant  over
 a  distance of 10  or more duct diameters.  For a rectangular cross section,  use
 an equivalent diameter, calculated from the following  equation, to determine the
 number of  duct diameters:

                                          2LW
                                   D  « 	
                                   *    (L + W)


                                                                 «q. 2-1

  Where:

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EMTIC TM-002                     HSPS TEST MBTHOD                       Page 7


        D.   •    Equivalent diameter.
        L    •    Length.
        W    -    Width.

To  ensure  the  presence of  stable,  fully developed flow  patterns  at  the
calibration site,  or "test section," the site moat  be located at least  eight
diameters downstream and two diameters upstream from the nearest disturbances. .

NOTE i  The eight- and two-diameter criteria are not absolute; other test section
locations nay be used (subject to approval of the Administrator), provided that
the flow at the test site is stable  and demonstrably parallel  to the duct  axis.

4.1.2.3   The flow  system  shall have the capacity to  generate a  teat-section
velocity around 915 m/min  (3,000 f t/min).  This velocity must be constant with
time  to guarantee  steady flow during calibration.  Note that  Type  8 pitot tube
coefficients obtained by single-velocity  calibration at 915 m/min (3,000 f t/min)
will generally be valid to ±3 percent for the measurement of velocities above 305
m/min (1,000 f t/min) and to ±5 to 6 percent for the  measurement of velocities
between 180 and 305 m/min (600 and 1,000  f t/min).   If a more precise correlation
between Cp  and  velocity is  desired,- the  flow system  shall  have the capacity to
generate at least four distinct, time-invariant test-section velocities covering
the velocity range from 180  to 1,525 m/min (600 to  5,000 f t/min), and calibration
data  shall  be taken at regular velocity intervals over  this range (see Citation*
9 and 14  in the Bibliography for details).

4.1.2.4  Two entry ports, one each for the standard and  Type 8  pitot tubes,  shall
be cut in  the test section;  the standard pitot  entry port  shall be located
slightly downstream of the Type S port,  so that  the  standard and Type 8 impact
openings will  lie  in the  same  cross-sectional plane  during  calibration.   To
facilitate  alignment of  the pitot tubes during calibration,  it is advisable that
the test  section be constructed of plexiglas or some  other transparent material.

4.1.3 Calibration Procedure.  Note  that this procedure  is a general one and must
not be used without first  referring to the special considerations presented in
Section 4.1.5.  Note also  that this procedure applies only to single-velocity
calibration.   To obtain calibration data  for the A and B  sides of  the Type 8
pitot tube, proceed as follows:

4.1.3.1 Make sure that the manometer is properly filled and that the oil is free
 from contamination and is  of the proper density.   Inspect and leak-check all
pitot lines; repair or replace if necessary.

4.1.3.2  Level and zero the manometer.  Turn on the fan, and allow the flow to
 stabilize.  Seal the Type 8 entry port.

 4.1.3.3  Ensure that the manometer is level and zeroed.  Position the standard
pitot tube at the  calibration point  (determined as outlined in Section 4.1.5.1),
 and align the tube so that  its tip is pointed directly  into the flow.  Particular
 care should be taken in aligning the tube to avoid yaw and pitch angles.  Make
 sure that the entry port surrounding the tube is properly sealed.

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EMTIC TM-002                     NSPS TEST METHOD                        Page 8


4.1.3.4  Read Ap^, and record its value in a data table similar to the one shown
in Figure 2-9.  Remove the standard pitot tube  from the duct, and disconnect it
from the manometer.  Seal the standard entry port.

4.1.3.5  Connect the Type 8 pitot tube to the manometer.  Open  the Type 8 entry
port.  Check the manometer level and zero.  Insert and align  the Type 8 pitot
tube so that its A side impact opening is at the sane point  as  was the standard
pitot tube and is pointed directly into the flow.  Make sure that the entry port
surrounding the  tube is properly sealed.

4.1.3.6   Read Ap.,  and enter ita value in the data table.   Remove the Type 8
pitot tube  from the duct,  and disconnect it from the manometer.

4.1.3.7   Repeat  Steps  4.1.3.3 through  4.1.3.6 above  until three pairs of Ap
readings have been obtained.

4.1.3.8   Repeat Steps 4.1.3.3 through 4.1.3.7 above for the B side of the Type
8 pitot  tube.

 4.1.3.9   Perform calculations, as described in Section 4.1.4 below.

 4.1.4'  Calculatic
 4.1.4.1  For each of the six pairs of Ap readings  (i.e., three from side A and
 three from side B) obtained in Section 4.1.3 above, calculate the value of
 the Type 8 pitot tube coefficient as follows:
                              cp(«)
                                                                          •I. 2-2
         Where:

         Cp,.,       »    Type 8 pitot tube coefficient.

         CpiMd,      -    Standard  pitot  tube  coefficient;   use  0.99  if  the
                         coefficient is unknown and the tube is designed according
                         to  the criteria  of Sections  2.7.1 to  2.7.5  of this
                         method.

          Ap.t4      »    Velocity head measured by the standard  pitot tube, em
                         (in.) H,0.

          Ap.       •    Velocity head measured by the Type 8  pitot tube,  em (in.)
                         8,0.

  4.1.4.2  Calculate C,  (side A), the mean A-side coefficient,  and C, (side B), the

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EMTIC TM-002                     NSPS TEST METHOD                       Page 9


mean B-side coefficient; calculate  the  difference between these  two average
values.

4.1.4.3  Calculate the deviation of each of the three A-aide values of
CjU>  from Cp  (side A), and the deviation of each B-side values of Cpto)  from
Cp (side B).  Use the following equation:


                        Deviation = C    ~Cp(A or B)
                                                                 •Bq.  2-3

4.1.4.4  Calculate a, the average deviation from the mean, for both the A and B
sides of the pitot tube.  Use the following equation:

                                      3         	
                                     ElCp,.,  -Cp(AorB)|
                  o(side A or B) « 	
                                                                  Bq. 2-4

 4.1.4.5  Use the Type S pitot tube only if the values of a (side A)  and a (side
 B)  are less than or equal to 0.01 and if the  absolute  value of the difference
 between Cp  (A) and Cp (B)  is 0.01 or less.

 4.1.5   Special  Considerations.
     »
 4.1.5.1 Selection of  Calibration Point.
 2.3
 4.1.5.1.1  When an isolated Type S pitot tube is calibrated, select a calibration
 point  at or near the center of  the duct,  and follow the procedures  outlined in
 Sections 4.1.3 and 4.1.4  above.   The Type S pitot coefficients so  obtained,
 i.e.,  Cp (side A) and Q   (side B), will  be valid,  so long as  either:  (1)  the
 isolated pitot tube is used; or (2) the pitot tube is used with other components
 ^nozzle, thermocouple,  sample probe)  in  an  arrangement  that is free  from
 aerodynamic interference effects (see Figures 2-6  through 2-8).
 4.
 4.1.5.1.2   For Type  8  pitot tube-thermocouple  combinations  (without sample
 probe),  select a calibration point at or near the center of the duct, and follow
 the procedures outlined in Sections 4.1.3  and 4.1.4 above.  The coefficients so
 obtained will be valid so long as the pitot tube-thermocouple combinatioa is used
 by itself or with other components in an interference-free arrangement  (Figure*
 2-6 and 2-8).

 4.1.5.1.3   For assemblies with sample probes,  the  calibration point should bee

-------
EMTIC TM-002                     HSP8 TB8T XBTBOD                      Page 10


located at or near the center of the duct; however, insertion of a probe sheath
into a snail duct may cause significant cross-sectional area  blockage and yield
incorrect coefficient values (Citation 9 in the Bibliography).  Therefore* to
minimize the blockage effect, the  calibration point may be a few inches off-
center  if  necessary.  The actual blockage  effect will be negligible when the
theoretical  blockage, as  determined by a  projected-area model of  the probe
sheath,  is 2 percent or less of the duct cross-sectional area for assemblies
without external sheaths (Figure 2-10a), and 3 percent or less for assemblies
with external sheaths (Figure 2-10b).

4.1.5.2 For those probe assemblies in which pitot tube-nozzle  interference  is
a factor (i.e., those in which the pitot-nozzle separation distance fails to meet
the specification illustrated in Figure 2-6A), the value of CpU) depends upon the
amount  of free-space between the tube and nozzle, and therefore is a function of
nozzle  size.   In these instances, separate calibrations shall be performed with
each of the  commonly used nozzle sizes in place.   Note  that the single-velocity
calibration technique is  acceptable for this purpose, even though  the larger
nozzle sizes (>0.63S cm or 1/4 in.) are  not ordinarily used for  isokinetic
sampling at  velocities around 915 m/min (3,000 ft/min), which is the calibration
velocity;  note also that it  is not necessary to draw an isokinetic sample during
calibration  (see Citation 19 in the Bibliography).

4.1.5.3 For a probe  assembly constructed such that its pitot tube is always used
 in the same orientation, only one side of the pitot tube need be calibrated (the
 side which will face the  flow) .  The pitot tube must  still meet the alignment
 specifications of Figure 2-2 or 2-3, however, and must  have an average deviation
 (o)  value of 0.01 or less  (see Section 4.1.4.4.)

 4.1.6  Fi«ld Use and Rccalibration.

 4.1.6.1  Field  Use.

 4.1.6.1.1  When a Type S pitot tube (isolated or in an assembly) is used in the
 field,  the  appropriate coefficient  value (whether  assigned or  obtained  by
 calibration) shall be used to perform velocity calculations.  For calibrated Type
 8 pitot tubes,  the A side coefficient shall be used when the A side of  the tube
 faces  the flow, and the B side coefficient shall  be used when the B side  faces
 the flow; alternatively, the arithmetic average  of the A and B side  coefficient
 values may  be used,  irrespective of which side  faces  the flow.

 4.1.6.1..2  When a probe assembly is used to sample a small duct, 30.5 to 91.4 cm
  (12 to 36 in.)  in diameter, the probe sheath sometimes blocks a significant part
 of the duct cross-section, causing a reduction in the effective value of C,(st.
 Consult Citation 9 in the Bibliography for details.  Conventional pitot-sampling
 probe assemblies are not recommended for  use in ducts  having inside diameters
 smaller than 30.5 cm (12 in.) (see Citation 16  in the Bibliography).

 4.1.6.2  Kecalibration.

 4.1.6.2.1  Isolated Pitot Tubes.   After each field use, the pitot tube shall be

-------
EMTIC TM-002                     HSPS TEST MBTBOD                      Page 11


carefully reexamined in top, side, and end views.  If the pitot face openings are
still aligned within the  specifications illustrated in Figure 2-2 or 2-3,  it can
be assumed that the baseline coefficient of the pitot tube has not changed.  If,
however,  the  tube has been damaged to the extent that  it no longer meets the
specifications of the Figure 2-2  or 2-3, the damage shall either be repaired to
restore proper alignment of the face openings, or the tube shall be discarded.

4.1.6.2.2  Pitot Tube Assemblies.  After each field use, check the face opening
alignment of the pitot  tube, as in Section  4.1.6.2.1; also, remeasure the
intercomponent spacings of the assembly.   If the intercomponent spacings have not
changed and the face opening alignment is acceptable, it can be assumed that the
coefficient of the assembly has not changed.  If the face opening alignment: is
no  longer within  the  specifications  of  Figure 2-2 or  2-3,  either repair the
damage or replace the pitot tube  (calibrating the new assembly, if necessary).
If  the intercomponent spacings have changed, restore the original spacings, or
recalibrate the  assembly.

4.2  Standard Pitot Tube (if applicable) .   If a standard pitot tube is used for
the velocity  traverse, the tube  shall be constructed according to the criteria
of  Section 2.7 and shall be assigned  a baseline coefficient value of 0.99.  Zf
the standard  pitot tube is used as part  of  an assembly,  the tube shall be in an
interference-free arrangement (subject to  the  approval  of the Administrator) .

4.3  Temperature  Gauges.  After each field use, calibrate  dial thermometers,
liquid-filled bulb thermometers,  thermocouple-potentiometer systems,  and other
gauges at  a temperature  within 10 percent  of  the  average  absolute stack
temperature.  For temperatures up to 405"C  (76l"F), use an ASTM  mercury-in-glass
reference thermometer, or  equivalent, aa a reference;  alternatively,  either
a reference thermocouple and  potentiometer (calibrated by NBS)  or thermometric
 fixed points,  e.g.,  ice  bath  and boiling  water  (corrected  for barometric
pressure) may be  used.    For temperatures  above 405*C  (761*F), use an DBS-
 calibrated  reference thermocouple-potentiometer  system  or  an  alternative
 reference,  subject to the  approval  of the  Administrator.

 If, during calibration,  the absolute  temperature measured with the gauge being
 calibrated and the reference gauge agree within 1.5 percent,  the  temperature data
 taken in the  field shall be considered valid.   Qtherwise, the pollutant emission
 test shall either be considered invalid or adjustment* (if appropriate) of the
 test results shall be made,  subject to  the approval of the Administrator.

 4.4  Barometer.  Calibrate the barometer used against a mercury barometer.

 5•  CALCULATIONS

 Carry out calculations,  retaining at least one extra decimal figure beyond that
 of the acquired data.  Round off figures after final calculation.

 5.1  Nomenclature.

           A    •    Cross-sectional area of stack, wf (ft*).

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EWTIC TM-002                     NSPS TEST KBTBOD                      Page 12


               «    Water vapor  in the  gas  stream (from Method 5 or Reference
                    Method 4),   proportion by volt
          Cp    •    Pi tot tube coefficient, dimenaionless.

          Kp    •    Pitot tube constant,

                     34  97   m [ (g/g-iaole) (mmHg) |x/a
                            sec I    (°K)  (mmn^O)    I


 for the metric system.


                    85  19 ft  flb/lb-mole)  (in.Hg)11/2
                          sec I      (°R)  (in.HjO)     I


 for the  English system.

           Ma    -    Molecular weight of stack gas, dry basis (see Section 3.6),
                     g/g-mole  (Ib/lb-mole) .

           M.    -    Molecular weight of stack gaa, wet basis,  g/g-mole (Ib/lb-
                     mole).

                            = Md(l-Bws) + 18.OB^


                                                                 Bq.  2-5

           p^  •    Barometric pressure at measurement site, mm Hg (in. Hg).

           pf    «    Stack static pressure, mm Hg  (in. Hg).

           p,    m    Absolute stack pressure, mm Hg  (in. Hg),
                                     P    +  P
                                     rb«r    r
                                                                  Bq. 2-6
                     Standard absolute pressure,  760 mm Bg (29.52  in. Hg) .

                     Dry  volumetric stack  gas flow rate  corrected to  standard
                     conditions, dsm'/hr (dscf/hr) .

                     Stack temperature, *C (*P) .

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EMTIC TM-002
             NSPS TEST METHOD
Page 13
          T.
for metric.
Absolute stack temperature, *K (*&) .
                                  » 273  + t.
                                                                  Eg. 2-7
                                  - 460 + t.
for English.
           3,600-
                                                                  Bq. 2-8
Standard absolute temperature, 293"K  (528*11).



Average stack gas velocity, m/sec  (ft/sec).



Velocity head of stack gas, mm HaO (in. H,0) .



Conversion factor, sec/hr.
           18.0 »    Molecular weight of water, g/g-mole (Ib/lb-mole).



 5.2   Average Stack Oas Velocity.
                               KpCp
                                               T
                                               A
                                                                  Bq. 2-9
 5.3   Average Stack Gas Dry Volumetric Flow Rate.
                    Q8d = 3,600(1-BW.)V8A
                                                                  Bq. 2-10
 BIBLIOGRAPHT
 1.    Mark,  I».8.  Mechanical Engineers' Handbook.  New York.  McGraw-Hill Book

      Co.,  Inc.   1951.



 2.    Perry.  J.R.  Chemical  Engineers'  Handbook.   Mew  York.  McGraw-Hill Book

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EMTIC TM-002                     NSPS TEST METHOD                      Page 14


     Co., Inc.  1960.

3.   Shigehara, R.T.,  H.F.  Todd, and W.8.  Smith.   Significance of  Error* in
     Stack  Sampling  Measurements.    U.S.  Environmental  Protection  Agency,
     Research Triangle Park, N.C.  (Presented at the Annual Meeting of the Air
     Pollution Control Association,  St. Louis, MO., June 14-19, 1970).

4.   Standard Method for Sampling Stacks for Particulate Matter.  Ins 1971 Book
     of ASTM Standards,  Part 23.  Philadelphia, PA.   1971.   ASTM Designation
     D 2928-71.

5.   Vennard, J.K.  Elementary Fluid Mechanics.  New York.   John Wiley and Sons,
     Inc.   1947.

6.   Fluid  Meters  -  Their  Theory  and  Application.   American Society of
     Mechanical Engineers, New York, N.Y.   1959.

7.  ' ASHRAB Handbook of  Fundamentals.  1972.  p. 208.

8.   Annual Book of ASTM Standards, Part  26.  1974.  p. 648.

9.   Vollaro, R.F.  Guidelines  for Type  S  Pitot Tube Calibration.  U.S.
     Environmental Protection Agency, Research  Triangle Park,  N.C.   (Presented
     at  1st   Annual  Meeting,  Source   Evaluation   Society,   Dayton,   OB,
     September 18, 1975.)

10. Vollaro, R.F.  A Type S Pitot Tube Calibration Study.  U.S. Environmental
     Protection Agency,  Emission Measurement Branch,  Research Triangle Park,
     N.C.  JUly 1974..

11. Vollaro, R.F.  The Effects of  Impact Opening  Misalignment on the Value of
      the Type S Pitot Tube Coefficient.   U.S. Environmental Protection Agency,
      Emission Measurement Branch, Research Triangle Park,  NC.  October 1976.

 12.  Vollaro, R.F.  Establishment of a Baseline Coefficient Value for Properly
      Constructed  Type  S Pitot Tubes.  U.S.  Environmental Protection Agency,
      Emission Measurement Branch, Research Triangle Park,  NC.  November 1976.

 13.  Vollaro, R.F.  An Evaluation of Single-Velocity Calibration Technique: as a
      Means  of Determining Type  S Pitot Tube Coefficients.  U.S.  Environmental
      Protection Agency,  Emission Measurement Branch, Research Triangle Park, NC.
      August 1975.

 14.  Vollaro, R.F.   The Use of Type S Pitot Tubes for the Measurement of Low
      Velocities.   U.S.  Environmental Protection  Agency,  Emission Measurement
      Branch, Research Triangle  Park, NC.  November 1976.

 15.  Smith, Marvin L.  Velocity Calibration  of EPA Type Source Sampling Probe.
      United Technologies Corporation, Pratt and Whitney Aircraft Division, Bast
      Hartford, CT.   1975.

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EMTIC TM-002                     KSPS TKST METHOD                      Page 15


16.  Vollaro, R.P.  Recommended Procedure for Sample Traverses in Ducts Smaller
     than 12 Inches in Diameter.  U.S. Environmental Protection Agency, Emission
     Measurement Branch, Research Triangle Park, NC.  November 1976.

17.  Over, B. and R.C. Pankhurst.  The Measurement of Air Flow,  4th Ed. Ifondqn,
     Pergamon Press.   1966.

18.  Vollaro, R.F.  A Survey of Commercially Available Instrumentation for the
     Measurement  of Low-Range Gas Velocities.   U.S.  Environmental Protection
     Agency,  Emission  Measurement  Branch,  Research   Triangle  Park,  MC.
     November 1976.  (Unpublished Paper).

19.  Gnyp, A.W.,  C.C. St. Pierre, D.S. Smith, D.  Mozzon,  and J. Steiner. An
     Experimental Investigation of the Effect of  Pitot  Tube-Sampling Probe
     Configurations on the Magnitude of  the S Type Pitot Tube Coefficient for
     Commercially Available Source Sampling Probes.  Prepared by the University
     of  Windsor   for  the Ministry of   the  Environment,  Toronto,  Canada.
     February 1975.

-------
EMTIC TM-002
NSPS TEST MBTHOD
                                                                  Page 16
  1JO-U4M*
   ]_CT
 Figure 2-1.  Type S pitot tube manometer assembly.

-------
EMTIC TM-002
HSPS TSST METHOD
Page 17
             Tub* A*
                                   M
                                                   ~  v
                                   M
                                                              iJMDi

 Figure 2-2.  Properly constructed Type  S pi tot tube.

-------
EMTIC TM-002
NSPS TEST METHOD
Page 18
                        -ft
 Figure 2-3.  Types of  face-opening misalignment  that can result from field use
 or  improper construction  of  Type 8 pitot  tubes.   These  will  not affect the
 baseline value of Cp(s) so long as a1 and a* $10", &1 and 0*  s5*. *  *0.32  cm (1/8
 in.) and w  iO.08 cm  (1/32  in.)  (citation  11 in Bibliography).

-------
EMTIC IN-002
NSFS TEST METHOD
Page 19
    Figure 2-4.   Standard pitot tube design specifications.

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EMTIC TM-002                    NSVS TEST UttTUQD                       Page 20

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EMTIC TM-002
                               NSP8 TEST METHOD
                                                           Page 21
PLANT
DATE _
DIMENSIONS,
 (in. Eg) 	
OPERATORS _
             RUN NO.
             (in.)  __
TO  (in.) 	   BAROMETRIC PRESS.,
 .CROSS SECTIONAL AREA, V?  (ft*)	
.STACK DIA. OR
        mm Eg
PITOT TUBE I.D. NO.
  AVO. COEFFICIENT,
                  Cp .
LAST DATE CALIBRATED _
                                 SCHEMATIC OF STACK
                                  CROSS SECTION
Traverse
Pt. No.













Vel. Hd., Ap
ma (in.) H,O













Stack Temperature
*.,
•C CF)













Average
T.,
'K (°R)














»i
BEH Hg
(in. Kg)










•



Up)1*














                      Figure 2-5.  Velocity traverse data.

-------
EMTIC TM-002
NSPS TEST METHOD
Pag* 22
                       IB,  m»»n*-H*    ^
                mzr"
                (1_ J
                      flow Mmmlmt *rpn«cMnt t» Mate. Iw InpMl
  Figure  2-6.  Proper pitot tube-sampling nozzle configuration to prevent
  aerodynamic interference: button-hook  type nozzle:  centers of nozzle and
  pitot opening aligned: Dt between 0.48  and 0.95 cm (3/16 and 3/8 1n.).

-------
EMTIC TM-002
NSPS TBST HBTHOD
Page 23
^ K i*.»«-w C !"

I -Ml
i
i
                                                K
                   ==T	,+.
   Figure  2-7.   Proper thermocouple placement to prevent  Interference:
   between 0.48 and 0.95 on (3/16 and 3/8 1n.).

-------
EMTIC TM-002
N8P8 TEST METHOD
Page 24
   Figure 2-8.    Minimum pilot-sample  probe separation  needed to prevent
   interference:  Dt between 0.48 and 0.95 on (3/16 and 3/8 1n.).

-------
EMTIC TM-002
NSFS TKST METHOD
         Page 25
PITOT TUBE IDENTIFICATION NUMBER:
         DATE:
.CALIBRATED BY: _

RUN NO.
1
2
3
•A" SIDE CALIBRATION
APtd
cm H2O
(in H20)




*»U1
cm H,O
(in H,0)



Cp.«n
(SIDE A)
Cp,.,





Deviation
Cp,., - Cp(A)





RUN NO.
1
2
3
•B" SIDE CALIBRATION
A*.t4
cm H2O
(in H,O)




AP(.»
cm H,O
(in H,0)



^p.«»f
(SIDE B)
Cpc.)





Deviation
Cp«.) - Cp(B)




   Average Deviat ion = a
                          (AorB)
                                         — c
                                          '-
                                           p(AorB)
                     --MustBeiO.Ol
                   Cp(SideA) -Cp(SideB) -MustBesO.Ol

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EMTIC TM-002                  NSPS TEST METHOD                   Page 26
             Figure  2-9.   Pitot tube  calibration data.

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EMTIC TM-002
NSPS TEST METHOD
                                                                       Page 27
   Figure 2-10.  Projected-area models for typical pitot tube assemblies.

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       Appendix G.3




Sampling & Analysis Methods




     EPA Method 3 A

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                  EMISSION MEASUREMENT TECHNICAL INFORMATION CENTER
                                  NSPS TEST METHOD
        Method 3A - Determination of Oxygen and Carbon Dioxide Concentrations
                        1n Emissions fron Stationary Sources
                          (Instrumental  Analyzer Procedure)
1.  APPLICABILITY AND PRINCIPLE

1.1  Applicability.  This method 1s applicable to the determination of oxygen (0,)  and
carbon dioxide  (C02)  concentrations  1n emissions from  stationary sources only when
specified within the regulations.

1.2   Principle.   A  sample 1s continuously  extracted  from the  effluent stream:  a
portion  of  the  sample  stream  Is   conveyed to  an  Instrumental  analyzer(s)  for
determination of Oj and CQ concentratlon(s).   Performance specifications and test
procedures are provided to  ensure reliable data.


2.  RANGE AND SENSITIVITY

Same  as  1n Method 6C. Sections  2.1  and 2.2. except that the  span of the monitoring
system shall be selected such that the average Oj or  C02 concentration 1s not less than
20 percent of the span.

3.  DEFINITIONS

3.1   Measurement System.  The total equipment required for the  determination of the Oj
or CO* concentration.   The measurement system consists of the same major subsystems as
defined  1n Method 6C.  Sections 3.1.1. 3.1.2.  and 3.1.3.

3.2  Span. Calibration Gas.  Analyzer Calibration Error. Sampling System Bias.  Zero
Drift. Calibration Drift.  Response T1ne.  and  Calibration Curve.  Same as 1n Method 6C.
Sections 3.2 through  3.8. and  3.10.

3.3   Interference  Response.   The output  response of the measurement system to  a
component  1n the sample gas.  other than the  gas component being measured.

4.   MEASUREMENT SYSTEM PERFORMANCE SPECIFICATIONS

Same as  1n Method 6C.  Sections 4.1 through 4.4.
 Prepared by Emission Measurement Branch                                EMTIC TH-003A
 Technical Support Division. OAQPS. EPA                                   May 6.  1989

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EMTIC TM-003A                  NSPS TEST METHOD                                Page 2
5.  APPARATUS AND REAGENTS

5.1    Measurement  Systei.   Any measurement system for  Ox or  CQ  that  meets the
specifications  of  this  method.   A schematic of an acceptable measurement system  1s
shown  1n Figure 6C-1 of Method 6C.  The essential components of the measurement system
are described below:

5.1.1   Sample Probe.  A leak-free probe of  sufficient length to traverse  the sample
points.

5.1.2  Sample Line.  Tubing to transport the  sample gas  from the probe to the moisture
removal  system.  A heated sample line 1s not required for systems that measure the Oj
or C02 concentration on a dry basis,  or transport dry gases.

5.1.3  Sample  Transport  Line.  Calibration Valve Assembly. Moisture Removal Systei.
Paniculate Filter. Sample Pump. Sample Flow Rate Control. Sample  Gas Manifold, and
Data Recorder.  Same as In Method 6C. Sections 5.1.3 through 5.1.9.  and 5.1.11. except
that the requirements to use stainless  steel. Teflon, and nonreactive glass filters do
 not apply.

 5.1.4  Gas Analyzer.  An analyzer to determine continuously the Oj or CQt concentration
 1n  the  sample gas  stream.    The  analyzer must meet  the  applicable  performance
 specifications of Section 4.   A means  of controlling the analyzer flow  rate and  a
 device for determining proper  sample  flow rate (e.g.. precision rotameter.  pressure
 gauge downstream  of all flow controls, etc.) shall be provided at the analyzer.  The
 requirements for measuring and  controlling the  analyzer for measuring and  controlling
 the analyzer flow rate are not applicable 1f data are presented that demonstrate the
 analyzer 1s Insensitive to flow variations over the range encountered during  the test.

 5.2   Calibration  Gases.  The calibration gases for C0| analyzers shall be  CQ, 1n N* or
 COj 1n air. Alternatively.  COz/SOj.  (ySQz.  or (ycOz/SQz gas mixtures 1n N2 may be used.
 Three calibration gases, as  specified 1n Sections 5.3.1 through 5.3.4 of Method  6C.
 shall be  used.   For Oj monitors  that cannot  analyze  zero gas.  a calibration  gas
 concentration  equivalent to less than  10  percent of the span may be used  1n place of
 zero  gas.

 6.   MEASUREMENT SYSTEM PERFORMANCE TEST PROCEDURES

  Perform the following procedures before measurement of emissions (Section 7).

  6.1  Calibration  Concentration Verification.  Follow Section 6.1 of Method 6C. except
  1f calibration  gas analysis  1s  required,  use Method  3 and change  the acceptance
  criteria for agreement among Method 3 results to 5 percent (or 0.2 percent by volune.
  whichever 1s greater).

  6.2   Interference Response.   Conduct an  Interference response test of the analyzer
  prior to Its Initial use 1n the field.  Thereafter, recheck the measurement system 1f

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EMTIC TM-003A                  NSPS TEST METHOD                               Page 3


changes are  made 1n the Instrumentation that  could alter the Interference response
(e.g.. changes 1n the type of gas  detector).   Conduct the Interference response 1n
accordance with Section 5.4 of Method 20.

6.3   Measurement System Preparation.  Analyzer Calibration Error. Response T1»e. and
Sampling System Bias Check.  Follow Sections 6.2 through 6.4 of Method 6C.

7.  EMISSION TEST PROCEDURE

7.1   Selection of Sampling Site and Sampling Points.  Select a measurement site and
sampling points  using  the  same criteria that are applicable to tests  performed  using
Method 3.

7.2   Sample Collection.  Position the sampling probe at the  first measurement point.
and  begin sampling  at the same  rate as  that used during the  response time  test.
Maintain  constant  rate sampling (I.e..  ±10 percent)  during  the entire  run.   The
sampling  time per run shall be the same as for tests conducted using Method 3 plus
twice the average system  response  time.  For each  run.  use only those  measurements
obtained  after  twice  the  response time  of the measurement system  has elapsed  to
determine the average  effluent concentration.

7.3   Zero and Calibration Drift Test.   Follow  Section 7.4 of Method 6C.

8.  QUALITY CONTROL PROCEDURES

The  following quality control  procedures  are reconnended  when the  results  of this
method are used for an emission rate correction factor, or excess air determination.
The  tester  should select  one  of  the  following options for  validating measurement
 results:

 8.1    If  both Oj and  CQ  are measured  using Method 3A.  the procedures  described  1n
 Section 4.4 of Method 3  should  be followed to validate the Oj and CQ  measurement
 results.

 8.2    If  only Oj 1s measured using Method 3A.  measurements  of the sample stream2CO
 concentration should  be obtained at the sample  by-pass vent discharge using an Orsat
 or Fyrlte analyzer, or equivalent.  Duplicate samples should be obtained concurrent
 with at  least one run.  Average the duplicate Orsat  or Fyrlte analysis results for
 each  run.   Use the  average C02 values for comparison  with tne20  measurements 1n
 accordance with the procedures described 1n Section 4.4 of Method 3.

 8.3   If  only C02 1s measured  using Method 3A. concurrent measurements of the sample
 stream C02  concentration should be  obtained using an Orsat or Fyrlte analyzer as
 described 1n Section 8.2.  For each run. differences greater than 0.5 percent between
 the  Method 3A  results and the  average of the duplicate Fyrlte  analysis should be
 Investigated.

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EMTIC TM-003A                  NSPS TEST METHOD                                Page 4


9.  EMISSION CALCULATION

9.1  For all C02 analyzers, and for 02 analyzers that can be calibrated with zero gas.
follow Section 8  of Method 6C. except express all concentrations as  percent,  rather
than ppn.

9.2   For Oz analyzers  that use a low-level calibration gas 1n place of a zero gas.
calculate the effluent gas concentration using Equation 3A-1.

                        CM " CM
                C,,, -  	  (U - C.) + C.,                   Eq.  3A-1
                         C.-C.

Where:
                                                                                    *
       C,,,  - Effluent gas  concentration, dry basis, percent.

        C.  - Actual  concentration of the upscale calibration gas. percent.

        CQ,  - Actual  concentration of the low-level calibration gas. percent.

         C.  - Average of Initial and final system calibration bias check
      responses  for the upscale calibration  gas. percent.

         C,  - Average of Initial and final system calibration bias check
       responses for the low level  gas.  percent.

          C  - Average gas concentration Indicated by the gas analyzer, dry basis.
         percent.


 10.  BIBLIOGRAPHY

 Same as 1n Bibliography of Method 6C.

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       Appendix G.4




Sampling & Analysis Methods




     EPA Method 23

-------

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6560-50
                 ENVIRONMENTAL PROTECTION AGENCY
                          40  CFR Part  60

                          [AD-PRL-    ]
       STANDARDS OF PERFORMANCE FOR NEW STATIONARY SOURCES
                   Appendix A , Test Method 23

     AGENCY:   Environmental Protection Agency  (EPA) .

     ACTION:   Proposed Rule.

     SUMMARY:  This rule  amends Method 23, entitled

"Determination of Polychlorinated Dibenzo-p-Dioxins and

Polychlorinated Dibenzofurans from Stationary Sources," to

correct existing errors in the method, to eliminate the methylene

chloride rinse of the  sampling  train,  and to clarify the quality

assurance  requirements of the method.

     DATES:  Comments.  Comments must  be  received on or before

	 (90 days after publication in the  FEDERAL

REGISTER].

     Public  Hearing.   If  anyone contacts EPA requesting  to  speak

at a public  hearing by 	 (two  weeks after

publication  in the  FEDERAL  REGISTER) , a  public hearing will be

held on 	 (four weeks after publication  in  the

FEDERAL REGISTER),  beginning at 10:00 a.m.   Persons interested in

attending the hearing should call Ms. Lala Cheek at

 (919)  541-5545 to verify that a hearing will be held.

     Request: bo Speak at Hearing.  Persons wishing to present

-------
oral testimony must contact EPA by 	 (two weeks




after publication in the FEDERAL REGISTER) .




ADDRESSES: Comments.  Comments should be submitted (in duplicate




if possible) to Public Docket No. A-94-2  at the following




address: U. S. Environmental Protection Agency , Air and




Radiation Docket and Information Center, Mail Code: 6102, 401 M




Street, SW, Washington, DC 20460.  The Agency requests that a




separate copy also be sent to the -contact person listed below.




The docket  is located at the above address in Room M-1500




Waterside Mall  (ground  floor),  and may be inspected from




8:30  a.m. to Noon and  1:00 to 3:00 PM, Monday through  Friday.




The proposed regulatory text  and other materials related to this




rulemaking are available for  review  in  the docket  or copies may




be mailed on request from the Air Docket by  calling 2Q2-26Q-7548.




A reasonable fee may be charged for  copying  docket materials.




      Public Hearing.  If anyone contacts EPA requesting a public




 hearing, it will be held at EPA's Emission Measurement




 Laboratory, Research Triangle Park,  North Carolina.   Persons




 interested in attending the hearing or wishing to present oral




 testimony should notify Ms. La la Cheek  (MD-19), U.S.




 Environmental Protection Agency,  Research Triangle Park, North




 Carolina 27711, telephone number  (919)  541-5545.

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     Docket;   A Docket,  A-94-22,  containing materials relevant to




this rulemaking, is available for public inspection and copying




between 8:30 a.m. and Noon and 1:00 and 3:00 p.m.,  Monday through




Friday, in at EPA's Air Docket•Section (LE-131),  Room M-1500




Waterside Mall  (ground floor) 401 M Street, S.W., Washington,




D.C. 20460.  A reasonable fee may be charged for copying.




     FOR FURTHER INFORMATION CONTACT:  Gary McAlister, Emission




Measurement Branch  (MD-19), Emissions, Monitoring,  and Analysis




Division, U.S. Environmental Protection Agency,  Research Triangle




Park, North Carolina 27711, telephone  (919) 541-1062.




     SUPPLEMENTARY  INFORMATION:




     The proposed regulatory text of the proposed rule is not




included in this Federal  Register notice, but is available in




Docket No. A-94-22  or by  written or telephone request from the




Air Docket  (see ADDRESSES) .  If necessary,  a limited number  of




copies of the Regulatory  Text are available from the EPA contact




persons designated  earlier  in this notice.  This Notice  with the




proposed regulatory language is also  available on the Technology




Transfer Network (TTN), one of EPA's  electronic  bulletin boards.




TTN provides  information  and technology exchange in various  areas




of air pollution control.  The service is  free except for the




cost of  the phone call.   Dial  (919)  541-5742  for up to  a 14400

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bps modem.  If more information on TTN is needed,  call the HELP




line at  (919) 541-5384.




I. • SUMMARY




     Method 23 was promulgated along with the New Source




Performance Standard for municipal waste combustors  (Subpart Ea).




As promulgated, the method contained some errors.  This action




would correct those errors and would clarify some of the existing




quality  assurance requirements.  In addition, the current




procedure requires rinsing of the  sampling train with.two




separate solvents which must be analyzed separately.  Based on




data the Agency has collected  since promulgation of  Method 23,  we




believe  that one  of these rinse steps  and the resulting sample




 fraction can be eliminated.  This could save as much as $2000 per




 test run in analytical costs.




 II.   THE RULEMAKING




        This rulemaking does  not impose emission  measurement




 requirements beyond those specified in the  current regulations




 nor does  it change any emission standard.  Rather, the rulemaking




 would simply amend an existing test method associated with




 emission measurement requirements in the current regulations that




 would apply irrespective of this  rulemaking.




 III.  ADMINISTRATIVE REQUIREMENTS

-------
          bearin
     A public hearing will be held,  if requested,  to discuss the




proposed amendment in accordance with section 307 (d) (5) of the




Clean Air Act.  Persons wishing to make oral presentations should




contact EPA at the address given in the ADDRESSES  section . of this




preamble.  Oral presentations will be limited to 15 minutes each.




Any member of the public may file a written statement with EPA




before, during, or within 30 days after the hearing.  Written




statements should be addressed to the Air Docket Section address




given in the ADDRESSES section of this preamble.




     A verbatim transcript of the hearing and written statements




will be available for public inspection and copying during normal




working hours at EPA's Air Docket Section in Washington, DC  (see




ADDRESSES section of this preamble) .




p. Docket




     The docket is an organized and complete file of all the




information considered by EPA in the  development of this




rulemaking.  The docket is a dynamic  file, since material is




added throughout the rulemaking development.  The docketing




system is intended to allow members of the public and industries




involved to identify and locate documents readily so that they




may effectively participate in the  rulemaking process.  Along




                                5

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with the statement of basis and purpose of the proposed and




promulgated test method revisions and EPA responses to




significant comments, the contents of the docket, except for




interagency review materials, will serve as the record in case of




judicial review [Section 307(d)(7)(A)].




C. Executive Order 12291 Review




     Under Executive Order 12291, EPA is required to judge




whether a regulation is a "major rule" and, therefore, subject to




the requirements of a regulatory impact analysis.  This




rulemaking does not impose emission measurement requirements




beyond those specified in the  current regulations, nor does it




change any emission standard.  The Agency has  determined that




this regulation would result in none  of the adverse economic




effects set forth  in Section 1 of the Order as grounds for




finding the regulation to be a "major rule."   The Agency has,




therefore, concluded that this regulation  is not a  "major rule"




under Executive Order 12291.




P.  Regulatory  Flexibility Act




     The  Regulatory  Flexibility Act  (RFA)  of  1980  requires the




 identification of  potentially  adverse impacts of Federal




 regulations upon small  business entities.   The RFA specifically




 requires  the completion of an analysis in those instances where




                                 6

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small business impacts are possible.  This rulemaking does not




impose emission measurement requirements beyond those specified




in the current regulations, nor does it change any emission




standard.  Because this rulemaking imposes no adverse economic




impacts, an analysis has not been conducted.




     Pursuant to the provision of 5 U.S.C. 605(b), I hereby




certify that the promulgated rule will not have an impact on




small entities because no additional costs will be incurred.




E. Paperwork Reduction Aet




       This rule does not change any information collection




requirements subject to Office of Management and Budget review




under the Paperwork Reduction Act of 1980, 44 U.S.C. 3501 et sag.




F.  Statutory Authority




     The statutory authority for this proposal is provided by




sections 111 and 301(a) of the Clean Air Act, as amended: 42




U.S.C., 7411 and 7601(a).








LIST OF SUBJECTS




     Air pollution control, municipal waste  combustors,




polychorinated dibenzo-p-dioxins, sources.

-------
Date                               The Administrator




     It is proposed that 40 CFR Part 60 be amended as follows:




     1.  The authority citation for Part 60 continues to read as




follows:  Authority:  Clean Air Act (42 U.S.C.  7401 [et seq.], as




amended by Pub. L 101-549).




     2.  Replace test Method 23 of Appendix A,  with the




following:








 Method 23 - Determination of Polychlorinated Dibenzo-p-dioxlns




and Polychlorinated Dibenzofurana from Municipal Waste Combust or •




1.  APPLICABILITY AMD PRINCIPLE




  1.1  Applicability.  This method is  applicable to the




determination  of emissions of polychlorinated dibenzo-p-dioxins




 (PCDD's)  and polychlorinated dibenzofurans  (PCDF's) from




municipal waste combustors.  Calibration  standards are  selected




for regulated  emission  levels for municipal waste combustors.




  1.2   Principle.   A sample is  withdrawn  isokinetically from the




gas  stream and collected in the sample probe, on a glass fiber




 filter,  and on a packed column  of adsorbent material.   The sample




 cannot be separated into a particle and vapor  fraction.   The




 PCDD's and PCDF's  are  extracted from the  sample,  separated by




 high resolution gas chromatography (HRGC),  and measured by high




                                 8

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resolution mass spectrometry (HRMS) .




2.  APPARATUS




  2.1  Sampling.  A schematic of the sampling train is shown in




Figure 23-1.  Sealing greases shall not be used in assembling the




train.  The train is identical to that described in Section 2.1




of Method 5 of this appendix with the following additions:

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Figure 23.1 Sampling Train
              10

-------
  2.1.1  Nozzle.  The nozzle shall be made of nickel,  nickel-




plated stainless steel, quartz,  or borosilicate glass.




  2.1.2  Sample Transfer Lines.   The sample transfer lines,  if




needed, shall be heat traced, heavy walled TFE (1/2 in.  OD with




1/8 in. wall) with connecting fittings that are capable  of




forming leak-free, vacuum-tight connections without using sealing




greases.  The line shall be as short as possible and must be




maintained at 2-12 0°C.




  2.1.1  Filter Support.  Teflon or Teflon-coated wire.




  2.1.2  Condenser.  Glass, coil type with compatible fittings.




A schematic diagram  is shown in Figure 23-2.




  2.1.3  Water Bath.  Thermostatically controlled to maintain the




gas temperature exiting the condenser at s.204C (68°F) .




  2.1.4  Adsorbent Module.  Glass container  to hold up to 40




grams  of resin  adsorbent.  A schematic diagram is shown in Figure




23-2.  Other physical  configurations of the  water-jacketed resin




trap/condenser  assembly are acceptable.  The connecting fittings




shall  form  leak-free,  vacuum tight  seals.  A coarse glass frit  is




included to retain the adsorbent  in the water-jacketed sorbent




module.




   2.1.5  Probe  Liner.  The probe  liner shall be  made  of glass and




a  Teflon ferrule  or  Teflon coated O-ring  shall be  used to. make




the  seal at the nozzle end of the probe.





                                12

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  2.2  Sample Recovery.




  2.2.1  Fitting Caps.  Ground glass,  Teflon tape,  or aluminum




foil (Section 2.2.6) to cap off the sample exposed sections of




the train and sorbent module.




  2.2.2  Wash Bottles.  Teflon, 500-rnL.
                                 13

-------
  Flue
  Gas
  Flow
                                      Sorbent Trap
                                           §20/15
                                           GtaM Sintered Dfek
                                           XAO-2
                                              Water Jactet
                                         GtoM Wool Plug
Condenser
                                            CooBng Col
                                              Water Jickct
                                             * 20/15
Figure 23.2 Condenser and Adsorbent Trap
                                14

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15

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  2.2.3  Probe Liner,  Probe Nozzle, and Filter Holder Brushes.




Inert bristle brushes  with precleaned stainless steel or  Teflon




handles.  The probe brush shall have  extensions of  stainless




steel or Teflon, at least as  long as  the  probe.   The brushes




shall be properly sized and shaped to brush out the nozzle,  probe




liner, and transfer line, if  used.




  2.2.4  Filter Storage Container.  Sealed filter holder, wide-




mouth amber glass jar with Teflon-lined cap, glass  petri  dish, or




Teflon baggie.




  2.2.5  Balance.  Triple beam.




  2.2.6  Aluminum Foil.  Heavy duty,  hexane-rinsed  (Do not use to




wrap or ship  filter samples,  because it may react with




particulate matter).




  2.2.7 Metal  Storage Container.  Air tight container to store




silica gel.




  2.2.8 Graduated  Cylinder.  Glass, 250-mL with 2-mL




graduations.




  2.2.9 Glass  Sample Storage  Containers.  Amber glass bottles




 for sample glassware  washes, 500- or 1000-mL, with leak  free




 Teflon-lined caps.




  2.3  Analysis.




  2.3.1  Sample Containers.  125- and 250-mL flint glass bottles




 with Teflon-lined caps.





                                16

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  2.3.2   Test Tubes.   Glass.




  2.3.3   Soxhlet Extraction Apparatus.   Capable of  holding 43 x




123 mm extraction thimbles.




  2.3.4  Extraction Thimble.   Glass,  precleaned cellulosic, or




glass fiber.




  2.3.5  Pasteur Pipettes.  For preparing liquid chromatographic
                           •



columns.




  2.3.6  Reacti-vials.  Amber glass,  2-mL.




  2.3.7  Rotary Evaporator.  Buchi/Brinkman RF-121 or equivalent.




  2.3.8  Kuderna-Danish Concentrator Apparatus.




  2.3.9  Nitrogen Evaporative Concentrator.  N-Evap Analytical




Evaporator Model III or equivalent.




  2.3.10  Separatory Funnels.  Glass, 2-liter.




  2.3.11  Gas Chromatograph.  Consisting of the following




  components:




  2.3.11.1  Oven.  Capable of maintaining the  separation column




at  the proper operating temperature ±10°C and performing




programmed  increases  in temperature at  rates of at least




40°C/min.




  2.3.11.2   Temperature Gauges.  To monitor column oven,




detector, and exhaust  temperatures ±1°C.




  2.3.11.3   Flow Systems.  Gas metering system to  measure  sample*




fuel, combustion gas,  and carrier gas flows.





                                17

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  2.3.11.4  Capillary Columns.   A fused silica column,

60 x 0.25 mm inside diameter (ID),  coated with DB-5  and a fused

silica column, 30 m x 0.25 mm ID coated with DB-225.   Other

column systems may be substituted provided  that  the  user is able

to demonstrate, using calibration and performance checks, that

the column system is able to meet the specifications of Section

6.1.2.2.

  2.3.12  Mass Spectrometer.  Capable of routine operation at a

resolution of 1:10000 with a stability of ±5 ppra.

  2.3.13  Data System.  Compatible with the mass spectrometer and
                                                     •
capable of monitoring at least five groups  of  25 ions.

  2.3.14  Analytical Balance.  To measure within 0.1 mg.

3.  REAGENTS

  3.1  Sampling.

  3.1.1  Filters.  Glass fiber filters, without organic binder,

exhibiting at least 99.95 percent efficiency (<0.05 percent

penetration) on 0.3-micron dioctyl phthalate smoke particles.

The filter efficiency test shall be conducted in accordance with

ASTM Standard Method D 2986-71  (Reapproved 1978)  (incorporated by

reference - see §60.17).

  3.1.1.1  Precleaning.  All filters shall be cleaned before

their initial use.  Place a glass extraction thimble and 1 g  of

silica gel and a plug of glass wool into a Soxhlet apparatus,


                                18

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charge the apparatus with toluene, and reflux for a minimum of 3




hours.  Remove the toluene and discard it,  but retain the silica




gel.  Place no more than 50 filters in the thimble onto the




silica gel bed and top with the cleaned glass wool.  Charge the




Soxhlet with toluene and reflux for 16 hours.  After extraction,




allow the Soxhlet to cool, remove the filters, and dry them under




a clean nitrogen  (N2)  stream.   Store the filters in a glass petri




dishes and seal with Teflon tape.




  3.1.2  Adsorbent Resin.  Amberlite XAD-2 resin.  Thoroughly




cleaned before initial use.  Do not reuse resin.   If precleaned




XAD-2 resin  is purchased  from  the manufacturer,  the cleaning




procedure described in  Section 3.1.2.1  is not  required.




  3.1.2.1  Cleaning.  Procedure may be  carried out in a  giant




Soxhlet  extractor.   An  all-glass  filter thimble containing an




extra-coarse frit is used for  extraction of  XAD-2.  The  frit  is




recessed 10-15  mm above a crenelated ring  at the bottom  of the




thimble  to  facilitate drainage.   The resin must be carefully




retained in the extractor cup  with a glass wool plug and a




 stainless steel ring because it  floats on methylene chloride.




 This process involves sequential extraction in the following




 order.




      Solvent             Procedure




      Water               Initial Rinse: Place resin in a beaker,





                                19

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                        rinse once with HPLC water, and discard
                        water.  Refill beaker with water, let
                        stand overnight, and discard water.
     Water              Extract with HPLC water for 8 hours.
     Methanol            Extract with methanol for 22 hours.
     Methylene  Chloride Extract with methylene chloride for  22
                        hours.
     Methylene  Chloride Extract with methylene chloride for  22
        v                hours.
  3.1.2.2   Drying.
  3.1;2.2.1 Drying Column.   Pyrex pipe,  10.2 cm  ID by  0.6 m
long, with suitable retainers.
  3.1.2.2.2 Procedure.  The adsorbent  must  be  dried with  clean
inert gas.  Liquid nitrogen from a standard  commercial  liquid
 *
nitrogen cylinder has proven to be a reliable  source for large
volumes of gas free from organic contaminants.   Connect the
liquid nitrogen cylinder to the column by a  length of  cleaned
copper tubing,  0.95 cm ID, coiled to pass through a heat source.
A convenient heat source is a water-bath heated from a steam
line.  The final nitrogen temperature should only be warm to the
touch and not over 40°C.  Continue flowing nitrogen through the
adsorbent until all the residual solvent is removed.   The flow
rate should be sufficient to gently agitate the particles, but

                                20

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not so excessive as to cause the particles to fracture.




  3.1.2.3  Quality Control Check.  The adsorbent must be checked




for residual methylene chloride  (MeCl,)  as well as PCDDs and




PCDFs prior to use. The analyst may opt to omit this check for




precleaned XAD-2.




  3.1.2.3.1  MeCl, Residue Extraction.  Weigh a 1.0 g sample of




dried resin into a small vial, add 3 mL of toluene, cap the vial,




and shake it well.




  3.1.2.3.2  MeClj Residue Analysis.  Inject a 2 /tl sample of the




extract  into a gas chromatograph operated under the following




conditions:




  Column:  6 ft x 1/8  in  stainless  steel  containing 10 percent




  OV-1011" on 100/120 Supelcoport.




  Carrier Gas:  Helium at a rate of 30  mL/min.




  Detector:  Flame ionization detector  operated at a  sensitivity




  of 4 x 10-11 A/mV.




  Injection Port Temperature:   250°C.




  Detector Temperature:   305°C.




  Oven Temperature:  30°C for 4  min;  programmed to rise at




  40°C/min until it reaches 250°C;  return to  30°C after 17




  minutes.




  Compare the results  of  the analysis to the results  from the




 reference solution.  Prepare the reference solution by injecting





                                 21

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4.0 fil of methylene chloride into 100  mL of  toluene.   This




corresponds to 100 jig of methylene chloride  per g of  adsorbent.




The maximum acceptable concentration is 1000 pg/g of  adsorbent.




If the adsorbent exceeds this level,  drying  must be continued




until the excess methylene chloride is removed.




  3.1.2.3.3  PCDD and PCDF Check.  Extract the adsorbent sample




as described in Section 5.1.  Analyze the extract as  described in




Section 5.3.  If any of the PCDDs or PCDFs (tetra through hexa)




are present at concentrations above the target detection limits




 (TDLs), the adsorbent must be recleaned by repeating the last




step of the cleaning procedure.  The TDLs for the various




PCDD/PCDF congeners are listed in Table 1.




   3.1.2.4  Storage.  After cleaning, the adsorbent may be stored




in a wide mouth amber glass container with a Teflon-lined cap  or




placed in glass adsorbent modules tightly sealed with glass




stoppers.  It must be used within 4 weeks of cleaning.  If




precleaned adsorbent is purchased in  sealed containers, it must




be used within 4 weeks after the seal is broken.




   3.1.3  Glass Wool.  Cleaned by sequential  immersion in  three




 aliquots of methylene chloride,  dried in a  110°C oven, and stored




 in a  methylene chloride-washed glass  container with  a Teflon-




 lined screw cap.




   3.1.4  Water.  Deionized distilled  and stored in a methylene





                                22

-------
chloride-rinsed glass container with a Teflon-lined screw cap.




  3.1.5  Silica Gel.  Indicating type, 6 to 16 mesh.  If




previously used, dry at 175° C (350°F)  for two hours.  New silica




gel may be used as received.  Alternatively, other types of




desiccants (equivalent or better) may be used, subject to the




approval of the Administrator.




  3.1.6  Chromic Acid Cleaning Solution.  Dissolve 20 g of sodium




dichromate in 15 mL of water, and then carefully add 400 mL of




concentrated sulfuric acid.




  3.1.7  EPLC Water.




  3.2  Sample Recovery.




  3.2.1  Acetone.  Pesticide quality.




  3.2.2  Toluene. Pesticide quality.




  3.3  Analysis.




  3.3.1  Potassium Hydroxide.  ACS grade, 2-percent




 (weight/volume) in water.




  3.3.2  Sodium Sulfate.  Granulated, reagent grade.  Purify




prior to use by rinsing with methylene chloride and oven drying.




Store the cleaned material  in a  glass container with a Teflon-




lined screw cap.




  3.3.3  Sulfuric Acid.  Reagent grade.




  3.3.4  Sodium Hydroxide.  l.O N.  Weigh  40 g of sodium hydroxide




into a 1-liter  volumetric flask.  Dilute  to 1 liter with water.





                                23

-------
  3.3.5  Eexane.   Pesticide grade.




  3.3.6  Methylene Chloride.  Pesticide grade.




  3.3.7  Benzene.   Pesticide grade.




  3.3.8  Ethyl Acetate.




  3.3.9  Methanol.  Pesticide grade.




  3.3.10  Toluene.  Pesticide grade.




  3.3.11  Nonane.   Pesticide grade.




  3.3.12  Cyclohexane.   Pesticide Grade.




  3.3.13  Basic Alumina.  Activity grade  1,  100-200 mesh.   Prior




to use, activate the alumina by heating for 16 hours at 130°C.




Store in a desiccator.   Pre-activated alumina may be purchased




from a supplier and may be used as received.




  3.3.14  Silica Gel.  Bio-Sil A, 100-200 mesh.  Prior to use,




activate the silica gel by heating for at least 30 minutes at




180°C.  After cooling,  rinse the silica gel sequentially with




methanol and methylene chloride.  Heat the rinsed silica gel at




50°C for 10 minutes, then increase the temperature gradually to




180°C over 25 minutes and maintain it at  this temperature for




90 minutes.  Cool at room temperature and store in a glass




container with a Teflon-lined screw cap.




  3.3.15  Silica Gel Impregnated with Sulfuric Acid.   Combine 100




g of  silica gel with 44 g of concentrated sulfuric acid in a




screw capped glass bottle and agitate thoroughly.  Disperse the





                                24

-------
solids with a stirring rod until a uniform mixture  is obtained.




Store the mixture in a glass container with a Teflon-lined screw




cap.




  3.3.16  Silica Gel Impregnated with Sodium Hydroxide.   Combine




39 g of 1 N sodium hydroxide with 100 g of silica gel in a screw




capped glass bottle and agitate thoroughly.  Disperse solids with




a stirring rod until a uniform mixture is obtained.  Store the




mixture in glass container with a Teflon-lined screw cap.




  3.3.17  Carbon/Celite.  Combine 10.7 g of AX-21 carbon with 124




g of Celite 545 in a 250-mL glass bottle with a Teflon-lined




screw cap.  Agitate the mixture thoroughly until a uniform




mixture is obtained.  Store in the glass container.




  3.3.18  Nitrogen.  Ultra high purity.




  3.3.19  Hydrogen.  Ultra high purity.




  3.3.20  Internal Standard Solution.  Prepare a stock standard




solution containing the isotopically labelled PCDD's and PCDP's




at  the concentrations shown in Table 2 under the heading




"Internal Standards" in 10 mL of  nonane.




  3.3.21  Surrogate Standard Solution.   Prepare a  stock  standard




solution containing the isotopically labelled PCDD's and PCDF's




at  the^concentrations shown in Table 2 under the heading




"Surrogate Standards" in  10 mL of nonane.




  3.3.22  Recovery Standard Solution. Prepare a stock standard





                                25

-------
solution containing the isotopically labelled  PCDD's and PCDF's




at the concentrations shown in Table 2  under the heading




"Recovery Standards" in 10 raL of nonane.




4.  PROCEDURE




  4.1  Sampling.  The complexity of this  method is such that,  in




order to obtain reliable results, testers and  analysts should be




trained and experienced with the procedures.




  4.1.1  Pretest Preparation.




  4.1.1.1  Cleaning Glassware.  All glass components of the train




upstream of and including the adsorbent module, shall be  cleaned




as described in Section 3A of the "Manual of Analytical Methods




for the Analysis of Pesticides in Human and Environmental




Samples."  Special care shall be devoted to the removal of




residual silicone grease sealants on ground glass connections  of




used  glassware.  Any residue shall be removed by soaking the




glassware for several  hours in a chromic acid cleaning solution




prior to cleaning as described above.




   4.1.1.2  Adsorbent Trap.  The  traps  shall be  loaded in a clean




 area  to avoid contamination.  They may not  be loaded  in the




 field.  Fill a  trap with 20  to  40  g of XAD-2.  Follow the XAD-2




 with  glass wool and tightly cap both ends of  the trap.  Add  40 pi




 of the surrogate standard solution (Section 3.3.21)  to each  trap




 for a sample that  will be split prior  to analysis or 20 fA. of the





                                26

-------
surrogate standard solution (Section 3.3.21)  to each trap for




samples that will not be split for analysis (Section 5.1).   After




addition of the surrogate standard solution,  the trap must be




used within 14 days.  Keep the spiked sorbent under refrigeration




until use.




  4.1.1.3  Sampling Train.  It is suggested that all components




be maintained according to the procedure described in APTD-0576.




  4.1.1.4  Silica Gel.  Weigh several 200 to 300 g portions of




silica gel in air tight containers to the nearest 0.5 g.  Record




the total weight of the silica gel plus container, on each




container.  As an alternative, the silica gel may be weighed




directly  in the fifth impinger just prior to sampling.




  4.1.1.5  Filter.  Check each filter against light for




irregularities and  flaws or pinhole leaks.  Pack the filters flat




in a clean glass container or Teflon baggie.  Do not mark filter




with ink  or any other contaminating substance.




  4.1.2   Preliminary Determinations.  Same as Section 4.1.2




Method 5.




  4.1.3   Preparation of Sampling Train.




  4.1.3.1 During preparation and assembly of the  sampling  train,




keep all  train openings where contamination can enter,  sealed




until sampling is about to begin.  Wrap sorbent module  with




aluminum  foil to shield from radiant heat  of sun  light.   (NOTE:





                                27

-------
Do not use sealant grease in assembling the train.)




  4.1.3.2  Place approximately 100 mL of water in the second and




third impingers, leave the first and fourth impingers empty, and




transfer approximately 200 to 300 g of preweighed silica gel from




its container to the fifth impinger.




  4.1.3.3  Place the silica gel container in a clean place for




later use in the sample recovery.  Alternatively, the weight of




the silica gel plus the fifth impinger may be determined to the




nearest 0.5 g and recorded.




  4.1.3.4  Assemble the sampling train as shown in Figure 23-1.




  4.1.3.5  Turn on the adsorbent module and condenser coil




 recirculating pump and begin monitoring the adsorbent module gas




 entry temperature.  Ensure proper sorbent gas entry  temperature




 before proceeding and before sampling is initiated.  It is




 extremely important that the XAD-2 adsorbent resin temperature




 never exceed 50°C because thermal  decomposition and  breakthrough




 of surrogate standards will occur.  During testing,  the XAD-2




 temperature must not  exceed 20°C for efficient capture of the




 PCDD's and PCDF's.




   4.1.4  Leak-Check Procedure.  Same as Method 5, Section 4.1.4.




   4.1.5  Sampling Train Operation.  Same as Method 5,




 Section 4.1.5.




   4.2  Sample Recovery.   Proper cleanup procedure begins as soon





                                 28

-------
as the probe is removed from the stack at the end of the sampling




period.  Seal the nozzle end of the sampling probe with Teflon




tape or aluminum foil.




  When the probe can be safely handled, wipe off all external




particulate matter near the tip of the probe.  Remove the probe




from the train and close off both ends with aluminum foil.  Seal




off the inlet to the train with Teflon tape, a ground glass cap,




or aluminum foil.




  Transfer the probe and impinger assembly to the cleanup area.




This area shall be clean and enclosed so that the chances of




losing or contaminating the sample are minimized.  Smoking, which




could contaminate the sample, shall not be allowed in the -cleanup




area. Cleanup personnel shall wash their hands prior to sample




recovery.




  Inspect the train prior to and during disassembly and note any




abnormal conditions, e.g., broken filters, colored impinger




liquid, etc.  Treat the samples as follows:




  4.2.1  Container No. 1.  Either seal the filter holder or




carefully remove the filter from the  filter  holder and place it




in its identified container.  Do not  place the  filter in aluminum




foil.  Use a pair of cleaned tweezers to handle the filter.  If




it is  necessary to fold the filter, do so such  that the




particulate cake is inside the  fold.   Carefully transfer to the





                                29

-------
container any particulate matter and  filter fibers which adhere




to the filter holder gasket,  by using a dry inert bristle brush




and a sharp-edged blade.  Seal.the container  with Teflon tape.




  4.2.2  Adsorbent Module.   Remove the module from the train,




tightly cap both ends,  label it, and store it on ice for




transport to the laboratory.




  4.2.3  Container No.  2.   Quantitatively recover material




deposited in the nozzle,  probe 'transfer lines, the  front half of




the filter holder, and the cyclone, if used,  first,  by brushing




while rinsing three times with acetone and then, by rinsing the




probe three times with toluene.  Collect all the rinses in




Container No. 2.




  Rinse  the back half of the filter holder three times with




acetone.  Rinse the  connecting line between the filter and the




condenser .three times with acetone.   Soak the connecting*line




with  three  separate  portions of toluene for 5 minutes each.   If




using a  separate  condenser and adsorbent trap,  rinse the




 condenser in the  same manner as the  connecting  line.  Collect all




 the rinses in Container No. 2  and mark the level of the liquid on




 the container.




   4.2.4   Impinger Water.   Measure the liquid in the first four




 impingers to within 1  mL by using a graduated cylinder or by




 weighing it to within 0.5 g by using a balance. Record the





                                 30

-------
volume or weight of liquid present.  This information is required


to calculate the moisture content of the effluent gas.  Discard


the liquid after measuring and recording the volume or weight.


  4.2.5  Silica Gel.  Note the color of the indicating silica gel


to determine if it has been completely spent and make a mention


of its condition.  Transfer the silica gel from the fifth


impinger to its original container and seal.


5.  ANALYSIS


  All glassware shall be cleaned as described in Section 3A of


the  "Manual of Analytical Methods  for the Analysis of Pesticides


 in Human and Environmental  Samples."  All samples must  be


 extracted within 30  days  of collection  and  analyzed  within 45


 days of extraction.


   5.1  Sample  Extraction.   The analyst  may  choose  to split the


 sample extract after the completion of  sample  extraction


 procedures.   One half of the sample can then be archived.  Sample


 preparation procedures are given for using  the entire sample and


 for splitting the sample.


   5.1.1  Extraction System.  Place an extraction thimble  (Section


 2.3.4), 1 g of silica gel, and a plug of glass wool into the
                                             *

 Soxhlet apparatus, charge the apparatus with toluene, and reflux


 for a minimum of 3 hours.  Remove the toluene and discard it, but


 retain the silica gel.  Remove the extraction thimble from the



                                 31

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extraction system and place it in a glass beaker to catch the

solvent rinses.

  5.1.2  Container No. 1 (Filter).  Transfer the contents

directly to the glass thimble of the extraction system and

extract them simultaneously with the XAD-2 resin.

  5.1.3  Adsorbent Cartridge.   Suspend the adsorbent module

directly over the extraction thimble in the beaker (See Section

5.1.1).  The glass frit of the module should be in the up

position.  Using a Teflon squeeze bottle containing toluene,

flush  the XAD-2 into the thimble onto the bed of cleaned silica

gel.   Thoroughly rinse the glass module catching the rinsings in

the beaker containing the thimble.  If the resin is wet,

effective extraction can be  accomplished by loosely packing  the

resin  in the thimble.  Add the XAD-2 glass wool plug to the

thimble.

   5.1.4  Container No. 2  (Acetone and Toluene).  Concentrate the

sample to a volume of about  1-2  mL using a Kuderna-Danish

concentrator apparatus, followed by N2 blow down at a temperature

of less  than 37°C.  Rinse the sample container  three times with

small  portions of methylene  chloride and add these to  the

concentrated solution and concentrate  further to near  dryness.
                                                        *
This residue contains particulate matter removed in the rinse  of

the sampling train probe  and nozzle.   Add the concentrate to the


                                 32

-------
filter and  the XAD-2 resin in the Soxhlet apparatus described  in




Section  5.1.1.




   5.1.5   Extraction.  For samples that are to be split prior to




analysis add 40  /xl of the internal  standard solution




 (Section 3.3.20)  to the  extraction  thimble containing the




.contents of the  adsorbent cartridge,  the contents  of




Container No. 1,  and the concentrate  from Section  5.1.4.




Alternatively,  20 ;il of  the  internal  standard solution




 (Section 3.3.20)  for samples that are not to  be split prior to




 analysis.  Cover the contents of the extraction thimble with the




 cleaned glass wool plug to prevent the XAD-2  resin from floating




 into the solvent reservoir of the extractor.   Place the thimble




 in the extractor, and add the toluene contained in the beaker to




 the solvent  reservoir.  Add additional toluene to fill the




 reservoir  approximately 2/3 full.  Add Teflon boiling chips and




 assemble the apparatus.  Adjust the heat source to cause the




 extractor  to cycle three times per hour.  Extract the sample  for




 16 hours.   After extraction, allow the  Soxhlet to cool.  Transfer




 the toluene extract and three 10-mL  rinses to the rotary




 evaporator.  Concentrate the extract to approximately 10 raL.   If




 decided to split the sample, store one  half  for future use/ and




 analyze the other half  according to  the procedures in Sections




 5.2 and 5.3. In either case, use  a  nitrogen evaporative





                                 33

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concentrator to reduce the volume of the sample being analyzed to




near dryness.  Dissolve the residue in 5 mL of hexane.




     5.2  Sample Cleanup and Fractionation.




  The following sample cleanup and fractionation procedures are




recommended.  Alternative procedures may be utilized providing




acceptable identification criteria (Section 5.3.2.5) and




quantification criteria (Section 5.3.2.6) are met.




  5.2.1  Silica Gel Column.  Pack one end of a glass column,




20 mm x 230 mm, with glass wool.  Add in sequence, 1 g silica




gel, 2 g of sodium hydroxide impregnated silica gel, 1 g silica •




gel, 4 g of acid-modified silica gel, and 1 g of silica gel.




Wash the column with 30 mL of hexane and discard.  Add the  sample




extract, dissolved in  5 mL of hexane to the column with two




additional 5-mL rinses.  Elute the column with an additional 90




mL of hexane  and retain the entire eluate.  Concentrate this




solution to a volume of about 1 mL using the nitrogen evaporative




concentrator  (Section  2.3.9).




  5.2.2  Basic Alumina Column.  Shorten a  25-tnL  disposable




Pasteur pipette to about  16 mL.   Pack  the  lower  section with




glass wool  and 12 g of basic  alumina.   Transfer  the concentrated




extract from the silica gel  column to  the  top of the basic




alumina column and elute  the  column sequentially with 120 mL of




 0.5  percent methylene  chloride  in hexane followed by 120  mL of 35





                                34

-------
percent methylene chloride in hexane.  Discard the first 120 mL




of eluate.  Collect the second 120 raL of eluate and concentrate




it to about 0.5 mL using the nitrogen evaporative concentrator.




Transfer this extract with hexane to "13 mL tubes".




  5.2.3  AX-21 Carbon/Celite 545 Column.  Remove the bottom 0.5




in. from the tip of a 2-mL disposable Pasteur pipette.  Insert a




glass fiber filter disk or glass wool plug in the top of the




pipette 2.5 cm from the constriction.  Add sufficient




carbon/Celite" mixture to form a 2 cm column  (the 0.6 mL mark




column.  Top with a glass wool plug.  In some cases AX-21 carbon




fines may  wash through the glass wool plug and enter the sample.




This may be prevented by adding a  celite plug to  the exit end  of




the column. Pre-elute the column with  5 mL toluene, followed by 1




mL of  a 50:50 methylene  chloride/cyclohexane mixture,  followed by




5 mL of hexane.  Load in sequence,  the  sample extract  in 1  mL




hexane, 2x0.5 mL rinses  in hexane,  2 mL of 50 percent  methylene




chloride  in hexane  and  2 mL  of  50  percent benzene in  ethyl




acetate  and  discard the eluates.  Invert the  column and elute  in




the  reverse  direction with 13 mL of toluene.   Collect this




 eluate.  Concentrate the eluate in a nitrogen evaporator at 45°C




 to about  1 mL.   Transfer the concentrate to a Reacti-vial using a




 toluene rinses and concentrate to near dryness (less  than 20 /zl)




 using a stream of N2.  Store extracts  at room temperature,





                                35

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shielded from light, until the analysis is performed.




  5.3  Analysis.  Analyze the sample with a gas chromatograph




coupled to a mass spectrometer (GC/MS)  using the instrumental




parameters in Sections 5.3.1 and 5.3.2.  Immediately prior to




analysis, add a 20 pi aliquot of the recovery standard solution




from Table 2 to each sample.  A 2 /*! aliquot of the extract is




injected into the GC.  Sample extracts are first analyzed using




the DB-5 capillary column to determine the concentration of each




isomer of PCDD's and PCDF's  (tetra-through octa-).  If 2,3,7,8-




TCDF is detected in this analysis, then analyze another aliquot




of the sample in a  separate run, using the DB-225 column to




measure the  2,3,7,8 tetra-chloro dibenzofuran  isomer.  Other




column systems  may  be used, provided that  it can be demonstrated




using calibration and performance checks that  the column system




is able to meet the specifications  of  Section  6.1.2.




  5.3.1   Gas Chromatograph Operating Conditions.  The  recommended




conditions  are  shown  in Table 4.




  5.3.2   High  Resolution Mass Spectrometer.




  5.3.2.1  Resolution.   10,000 resolving power or 100  ppm




mass/mass.




  5.3.2.2  lonization Mode.  Electron impact.




  5.3.2.3  Source Temperature 250°C.




  5.3.2.4  Monitoring Mode.  Selected ion monitoring.   A list of





                                36

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the various ions to be monitored is presented in Table 5.




  5.3.2.5  Identification Criteria.  The following identification




criteria shall be used for the characterization of




polychlorinated dibenzodioxins and dibenzofurans.




  1.  The integrated ion-abundance ratio  (M/M+2 or M+2/M+4) shall




be within 15 percent of the theoretical value.  The acceptable




ion-abundance ratio ranges  (±15%) for the identification of




chlorine-containing compounds are given in Table 6;  If the ion-




abundance ratio ranges are  the outside those in Table 6, the




source has the option of using the results if the concentration




is determined using procedures in Section 9.3 or redoing the




analysis to  eliminate the unacceptable  ion-abundance ratio.




   2.  The  retention time for  the analytes must be within 3




seconds of the  corresponding  13C-labeled internal standard  or




surrogate  standard.




   3.  The  monitored ions, shown  in Table  5  for a given  analyte,




shall reach  their maximum within 2  seconds  of each other.




   4.  The  identification of specific isomers that  do  not have




corresponding 13C-labeled standards is done by comparison of the




relative  retention time (RRT) of the analyte to the nearest




 internal  standard retention time with reference (i.e.,  within




 0.005 RRT units)  to the comparable RRT's found in the continuing




 calibration.





                                 37

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  5.  The signal to noise ratio for all monitored ions must be




greater than 2.5.




  6.  The confirmation of 2, 3, 7,  8-TCDF shall satisfy all of




the above identification criteria.




  7.  Any PCDF coeluting (±2 s) with a peak in the corresponding




PCDPE channel, of intensity 10% or greater compared to the




analyte peak is evidence of a positive interference, the source




may opt keep the value to calculate CDD/CDP concentration or




conduct a complete reanalysis in an effort to remove or shift the




interference.  If a reanalysis is conducted, all values from the




reanalyzed sample will be used for CDD/CDF concentration




calculations.




  8.  Set the mass spectrometer lock channels as specified in




Table 5.  Monitor the quality control check channels specified in




Table 5 to verify instrument stability during the analysis. • If




the signal varies by more than 25 percent from the  average




response, results for all isomers at corresponding  residence time




shall be invalid.  The source has the options of conducting




additional cleanup procedures on the other portion  of  the  sample




for split samples or diluting  the original  sample or  following




other procedures recommended by the Administrator.  When a




complete reanalysis is conducted, all  concentration calculations




shall be based on the reanalyzed sample.





                                38

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  5.3.2.6  Quantification.  The peak areas for the two ions




monitored for each analyte are summed to yield the total response




for each analyte.  Each internal standard is used to quantify the




indigenous PCDD's or PCDF's in its homologous series.  For




example, the 13C12-2,3,7,8-tetra chlorinated dibenzodioxin is  used




to calculate the concentrations of all other tetra chlorinated




isomers.  Recoveries of the tetra- and penta- internal standards




are calculated using the 13C12-lf2,3,4-TCDD.   Recoveries of the




hexa- through octa- internal standards are calculated using  *3CU-




1,2,3,7,8,9-HxCDD.  Recoveries of the surrogate standards are




calculated using the corresponding homolog  from the  internal




standard.  When no peak is detected, the noise level,  as measured




by the  intensity of the noise  in a clear zone of  the




chromatogram, is used  to  calculate the detection  limit.   Tables




7, 8, and  9  summarize  the quantification relationships for the




unlabeled  analytes, internal  standards and surrogate standards,




respectively.




6.   CALIBRATION




   Same  as  Method 5 with the  following additions.




   6.1  GC/MS System.




   6.1.1  Initial Calibration.   Calibrate the GC/MS system using




the  set of five  standards shown in Table 3.  The relative




standard deviation for the  mean response factor from each of the





                                39

-------
unlabeled analytes (Table 3)  and of the internal  and surrogate


standards shall be less than or equal to the values in Table 6.


The signal to noise ratio for the GC signal present in every


selected ion current profile shall be greater  than or equal to


10.  The ion abundance ratios shall be within  the control limits


in Table 5.


  6.1.2  Daily Performance Check.


  6.1.2.1  Calibration Check.  Inject 2 /il of  solution Number 3


from Table 3.  Calculate the relative response factor  (RRF) for


each compound and compare each RRF to the corresponding mean RRF


obtained during the initial calibration.  The analyzer


performance is acceptable if the measured RRF's for the labeled


and unlabeled compounds for the daily run are within the limits


of the mean values shown in Table 10.  In addition, the ion-


abundance  ratios shall be within the allowable control limits


shown in Table 6.


   6.1.2.2  Column Separation Check.  Inject 2 /*! of a  solution of


a mixture  of PCDD's and PCDF's that documents resolution between


2,3,7,8-TCDD and other TCDD isomers.  Resolution is defined as a

                                                         k
valley between peaks  that is less  than 25  percent  of  the lower of


the  two peaks.  Identify and record the  retention  time windows
  %
for  each homologous series.  Perform a similar resolution  check


on the confirmation column to  document the resolution between


                                40

-------
2,3,7,8 TCDF and other TCDF isomers.




  6.2  Lock Channels.  Set mass spectrometer lock channels as




specified in Table 5.  Monitor the quality control check channels




specified in Table 5 to verify instrument stability during the




analysis.




7.  QUALITY CONTROL




  7.1  Sampling Train Collection Efficiency Check.  Add 40 /tl of




the surrogate standards in Table 2 for samples split for analysis




or 20 fj.1 of the surrogate standards for sample not split for




analysis to the adsorbent cartridge of each train before




collecting the field samples.




  7.2  Internal Standard Percent Recoveries.  A group of nine




carbon-labeled PCDDs and PCDFs representing the tetra- through




octachlorinated homologues, is added to every sample prior to




extraction.  The role of the internal standards is to quantify




the native PCDD's and PCDF's present in the sample as well as to




determine the overall method efficiency.  Recoveries of the




internal standards shall be between 40 to 130 percent for the




tetra- through hexachlorinated compounds while the range is  25  to




130 percent  for the  hepta- and octachlorinated homologues.




  7.3  Surrogate Standard Recoveries.  The  five  surrogate




compounds in Table 3 are added to  the resin in the adsorbent




sampling cartridge before the sample is collected.  The surrogate





                                41

-------
recoveries are measured relative to the  internal standards and




are a measure of the sampling train collection efficiency.  They




are not used to measure the native PCDD's and PCDF's.  All




surrogate standard recoveries shall be between 70 and




130 percent.  Poor recoveries for all the surrogates may be an




indication of breakthrough in the sampling train.  If the




recovery of all standards is below 70 percent, the sampling runs




must be repeated.  As an alternative, the sampling runs do not




have to be repeated if the final results are divided by the




fraction of surrogate recovery  (on a homolog group basis).  Poor




recoveries of  isolated surrogate compounds should not be  grounds




for rejecting  an entire set  of  samples.




   7.4  Toluene QA Rinse.   Report the results  of  the  toluene QA




rinse  separately from  the  total sample  catch.  Do not add it  to




the total sample.




   7.5  Detection Limits.   Calculate  the detection limits  using




 the equation in Section 9.8.  If the detection limits meet the




 Target Detection Limits (TDLs)  in Table 1, then they are




 considered acceptable.  If the TDLs are not  met, the impact of




 the detection limits shall be calculated using the  procedures in




 Section 9.9.  If the maximum potential  value of the sum of the




 summed detection limits is less then 50 percent of  the emission




 standard, the detection limits are acceptable.  If  the value is





                                 42

-------
greater than 50 percent of the emission standard,  then the

analysis and/or sampling and analysis must be repeated until

acceptable detection limits are obtained.

8.  QUALITY ASSURANCE

  8.1  Applicability.  When the method is used to analyze samples

to demonstrate compliance with a source emission regulation, an

audit  sample must be analyzed, subject to availability.

  8.2  Audit Procedure.  Analyze an  audit sample with each set of

compliance  samples.  The audit sample contains tetra through octa

isomers  of  PCDD  and PCDF.   Concurrently  analyze the audit sample

and  a  set of compliance samples  in the same manner to evaluate

the  technique  of the analyst and the standards preparation.  The

same analyst,  analytical reagents, and analytical system shall  be

used both for  the compliance samples and the EPA audit  sample.



   8.3  Audit Sample Availability. Audit samples will be supplied

 only to enforcement agencies for compliance tests.   Audit samples

 may be obtained by writing:
      Source Test Audit Coordinator  (MD-77B)
      Quality Assurance Division
      Atmospheric Research and Exposure Assessment Laboratory
      U.S. Environmental Protection Agency
      Research Triangle Park, NC 27711
 or by calling the Source Test Audit Coordinator  (STAC) at  (919)


                                 43

-------
541-7834.   The audit sample request must be made at least 30 days




prior to the scheduled compliance sample analysis.




  8.4  Audit Results.  Calculate the audit sample concentration




according to the calculation procedure provided in the audit




instructions included with the audit sample.  Fill in the audit




sample concentration and the analyst's name on the audit response




form included with the audit instructions.  Send one copy to the




EPA Regional Office or the appropriate enforcement agency and a




second copy to the STAC.  The EPA Regional office or the




appropriate enforcement agency will report the results of the




audit to the laboratory being audited.  Include this response




with the results of  the compliance samples in relevant reports to




the EPA Regional Office or the appropriate enforcement agency.




9.  CALCULATIONS




  Same as Method 5,  Section 6 with the  following additions.




  9.1  Nomenc la tur e.




    »   Integrated ion current of the noise at the retention time




        of the analyte.




    »   Integrated ion current of the two ions characteristic of




        compound i in the jth calibration standard.




A*elj »   Integrated ion current of the two ions characteristic of




        the internal standard i in the jth calibration standard.




    »   Integrated ion current of the two ions characteristic of





                                44

-------
       surrogate compound i in the calibration standard.




 A!  -   Integrated ion current of the two ions characteristic of




       compound i in the sample.




 A*t -   Integrated ion. current of the two ions characteristic of




       internal standard i in the sample.




       Integrated ion current of the two ions characteristic of




       the recovery standard.




        Integrated ion current of the two ions characteristic of




        surrogate compound i in the sample.




  Ci «  Concentration of PCDD or PCDF i in the sample, pg/M3.




  Cp »  Total concentration of PCDD's or PCDF's in the sample,




        pg/M3.




   DL «   Detection limit, pg/sample.




      «   Detection limit for each homologous series, pg/sample.




DL.ua  «   Sum of all isomers times the corresponding  detection




          limit, ng/m3.




  Hai =  Summed heights of the noise at the retention  time of the




        analyte in the two analyte channels.




  mci =  Mass of compound i in the calibration standard injected




        into the analyzer, pg.




 m*cl m  Mass of labeled compound i in the calibration standard




        injected- into the analyzer, pg.




  m*i -  Mass of internal standard i added to  the  sample, pg.





                                45

-------
     =  Mass of recovery standard in the calibration  standard




        injected into the analyzer, pg.




   m, •  Mass of surrogate compound in the sample to be analyzed,




        pg.




  m,! -  Mass of surrogate compound i in the calibration standard,




        pg-



 RRFi -  Relative response factor for compound i.




RRFr, »  Recovery standard response factor.




 RRF. •  Surrogate  compound response factor.




vm<«td>*     Metered  volume of  sample run, dscm.




 1000 -   pg per ng.




   9*2   Average Relative Response Factor.







             RRF   = i£ cij Cci                          Eq. 23-1

                i   aft *•  M
                         clj  cl
   9.3   Concentration of the PCDD's and PCDF's.
               C  =	—	                           Eq.  23-2


                    A,* RRF. V.
                         *  JB.»j*
   9.4  Recovery Standard Response Factor.
                                 46

-------
              RRFeg =  ci  "                             Eq.  23-3

                      Ar. "ci
  9.5  Recovery of  Internal Standards (R*)

                Ar.
                          xlOO%                         Eq. 23-4
  9.6   Surrogate Compound Response Factor,
                         »
                 RRF9 =   c*  **                           Eq. 23-5

                       Ac.i fflci
9.7  Recovery of Surrogate Compounds  (R.) .
                   A . ffl^
            Rt = 	^—	xlQO%                         Eq. 23-6
                 A  RRF m
  9.8  Detection Limit  (DL).  The detection limit can be


calculated based on either  the height  of  the noise or the area of


                                47

-------
the noise using one of the two equations.


Detection limit using height for the DB-225 column.  Three and


one half times the height has been empirically determined to give


area.
                2.5 (3.5 x H .) m/
           DL =	                        Eg. 23-7
Detection  limit using height for the DB-5 column.   Five times  the


height has been empirically determined to give  area.
                 2.5 (5 x H .) a/
             DL = - - - -                         Eq.  23-8
                     Ac\ RRF,
 Detection limit using area of the noise.
                    2 .5 A . ml
               DL =	—-                            Eq. 23-9
                     A,.*, RRFt
 9.9  Summed Detection Limits.  Calculate the maximum potential


 value of the summed detection limits.  If the isomer  (group of


 unresolved isomers) was not detected, use the value calculated


 for the detection limit in Section 9.8 above.  If the isomer


 (group of unresolved isomers} was detected, use the value  (target


                                 48

-------
detection limit) from Table 1.
        = (13 DLKDD + 16 DLtCDf + 12
        14 M^«r* 7 M«» * 12
         * 2 DL     + 4
                    / 1000
Note:  The number of isomers used to calculate the summed

detection limit represent the total number of isomers typically

separated and not the actual number of isomers for each series.

  9.10  Total Concentration of PCDD's and PCDP's in the Saxnpl*.
Any  PCDDs  or PCDPs that  are  reported as  not detected  (below the

DL)  shall  be counted as  zero for the purpose of calculating the

total  concentration of PCDDs and PCDPs in the sample.

10.  BIBLIOGRAPHY

   1.   American Society of Mechanical Engineers.  Sampling for the

Determination of Chlorinated Organic Compounds in  Stack

Emissions.  Prepared for U.S. Department of Energy and U.S.

Environmental Protection Agency. Washington DC.  December 1984.

25 p.

   2.   American Society of Mechanical Engineers.  Analytical

                                 49

-------
Procedures to Assay Stack Effluent Samples and Residual




Combustion Products for Polychlorinated Dibenzo-p-Dioxins (PCDD)




and Polychlorinated Dibenzofurans (PCDF) .   Prepared for the U.S.




Department of Energy and U.S. Environmental Protection Agency.




Washington, DC.  December 1984.  23 p.




  3.  Thompson, J. R.  (ed.).  Analysis of Pesticide Residues in




Human and Environmental Samples.  U.S. Environmental Protection




Agency.  Research Triangle Park, NC.  1974.




  4.  Triangle Laboratories.  Case Study:  Analysis of Samples




for the Presence of Tetra Through Octachloro-p-Dibenzodioxins and




Dibenzofurans. Research Triangle Park, NC.  1988.  26 p.




  5.  U.S. Environmental Protection Agency.  Method 8290 - The




Analysis of  Polychlorinated  Dibenzo-p-dioxin and Polychlorinated




Dibenzofurans by High-Resolution Gas  Chromatography/




High-Resolution Mass Spectrometry.  In:   Test  Methods  for




Evaluating Solid Waste.  Washington,  DC.   SW-846.




  6.   Personnel communications with R. L.  Harless  of U.S.  EPA and




Triangle Laboratory staff.
                                50

-------
           TABLE 23-1. TARGET DETECTION LIMITS  (TDLs)
ANALYTE
TCDD/TCDF
PeCDD/PeCDF
HxCDD/HxCDF
HpCDD/HpCDF
OCDD/OCDF
TDL (pg/Sample Train)
50
250
250
250
500
TABLE 23-2.  COMPOSITION OF THE SAMPLE FORTIFICATION AND RECOVERY
                       STANDARDS SOLUTIONS*
ANALYTE
CONCENTRATION (pg//iL)
Internal Standards
"C12-2,3,7,8-TCDD
"Cu-l^S^e-PeCDD
13C12-1 , 2 , 3 , 6 , 7 , 8 -HxCDD
13C12-1 , 2 , 3 , 4 , 6 , 7 , 8-HpCDD
13C12-OCDD
i3C12-2,3,7,8-TCDF
13C12-l,2,3,7,8-PeCDF
«C12-1 , 2,3,6,7, 8 -HxCDF
13C12-1 , 2 , 3 , 4 , 6 , 7 , 8-HpCDF
Surrogate
37Cl4-2,3,7,8-TCDD
13C12-1, 2, 3 , 4, 7, 8-HxCDD
13C12-2,3,4,7,8-PeCDF
13C12-1,2,3,4,7,8-HXCDF
13Cl2-l,2,3,4,7,8,9-HpCDF
100
100
100
100
100
100
100
100
100
Standards
100
100
100
100
100
Recovery Standards
                                51

-------
"Cja-i^s^-TCDD
13C12-1 , 2 , 3 , 7 , 8 , 9 -HxCDD
100
100
 Calibration levels are  specific  for  samples  at
the MWC compliance standard level.
                       52

-------
TABLE 23-3.  COMPOSITION OF THE INITIAL CALIBRATION SOLUTIONS
COMPOUND
SOLUTION NO.
CONCENTRATIONS (pg/J*D
1
2
3
UNLABELED ANALYTES
2,3,7,8-TCDD
2,3,7,8-TCDF
1,2,3,7,8-PeCDD
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
1,2,3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDD
1,2,3, 7,8, 9-HxCDD
1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
2,3,4,6,7,8-HxCDD
1,2,3,4,6,7,8-HpCDD
1,2,3,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
OCDD
OCDF
0.5
0.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
5
5
1
1
5
5
5
5
5
5
5
5
5
5
5
5
5
10
10
5
5
25
25
25
25
25
25
25
25
25
25
25
25
25
50
50
4
5

50
50
250
250
250
250
250
250'
250
250
250
250
250
250
250
500
500
INTERNAL STANDARDS
13C12- 2,3,7,8-TCDD
"Cia-l,2,3,7,8-PeCDD
"Cia-l , 2 , 3 , 6 , 7 , 8 -HxCDD
13CU-1 , 2,3,4,6,7, 8-HpCDD
13C12-OCDD
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
500
500
500
500
500
500
500
500
500
500
500
500
500
1000


100
100
100
100
100
                               53

-------
13Cia-2,3,7,8-TCDF
"C12-l,2,3,7,8-PeCDF
"Cia-l , 2 , 3 , 6 , 7 , 8-HxCDF
13C12-1 , 2 , 3 , 4 , 6 , 7 , 8-HpCDF
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
TABLE 23-3.   (Continued)
COMPOUND
SOLUTION NO.
CONCENTRATION (pg//iD
1
2
SURROGATE STANDARDS
"Cl4-2,3,7,8-TCDD
"C12- 2 , 3 , 4 , 7 , 8 -PeCDF
"Cu-1 , 2 , 3 , 4 , 7 , 8 -HxCDD
"Cu-1, 2 , 3 , 4 , 7 , 8-HxCDF
13Cia-l , 2 , 3 , 4 , 7 , 8 , 9-HpCDF
60
60
60
60
60
80
80
80
80
80
3

100
100
100
100
100
4

120
120
120
120
120

5


140
140
140
140
RECOVERY STANDARDS
l3Cia-l,2,3,4-TCDD
"Cu-1, 2 , 3 , 7, 8 , 9-HxCDD
100
100
100
100
100
100
100
100
100
100 1
                                 54

-------
        TABLE 23-4.  RECOMMENDED GC OPERATING CONDITIONS
Column Type
DB-5
DB-225
Length (ra)
i.d. (mm)
Film Thickness (fan)
Carrier Gas
Carrier Gas Flow (mL/min)
Injection Mode
Valve Time (rain)
Initial Temperature (o c)
Initial Time (min)
Rate 1 (deg. C/min)
Temperature 2 (deg. C)
Rate 2 (deg. C/min)
Final Temperature (deg. C)
60
0.25
0.25
Helium
1-2
<--
2.5
150
0.5
60
170
3
300
30
0.25
0.25
Helium
1-2
splitless — >
2.5
130
2.5
50
170
4
250
                                55

-------
   TABLE 23-5.  ELEMENTAL COMPOSITIONS AND EXACT MASSES OF THE IONS
MONITORED BY HIGH RESOLUTION MASS  SPECTROMETRY FOR PCDD'S AND PCDF'S
1 DESCRIPTOR
NUMBER
2










3
ACCURATE
MASS
ION
TYPE
292.9825 | LOCK
303.9016
305.8987
315.9419
317.9389
319.8965
321.8936
327.8847
330.9792
331.9368
333.9339
339.8597
341.8567
351.9000
353.8970
355.8546
357.8516
367.8949
369.8919
375.8364
409.7974
373.8208
375.8178
383.8639
385.8610
389.8157
391.8127
392.9760
M
M+2
M
M+2
M
M+2
M
QC
M
M+2
M+2
M+4
M+2
M+4
M+2
M+4
M+2
M+4
M+2
M+2
M+2
M+4
M
M+2
M+2
M+4
LOCK
ELEMENTAL COMPOSITION
C,FIX
C^H^C^O
C12H435C13C1370
13C12H43SC140
"CuH^CV'ClO
C12H«35C1402
C12H43SC1337C102
C12H437C1402
C7FU
13C12H435C1402
13C12H435C137C102
C12H33SC1437C10
C12H335C1337C120
13C12H335C14"C10
13C12H335C1337C120
C12H33SC1337C102
C12H335C1337C1202
13C12H335C14"C102
13C12H335C1337C1202
CuH^Cls^ClO
C12H335C1S37C10
C12H335C1537C10
C12H23SC1437C120
13C12H235C160
»C12H235C1537C10
C12H23SC1537C102
C12H235Cl437ClaOa
C,F15
ANALYTE 1
PFK
TCDF
TCDF
TCDF(S)
TCDF(S)
TCDD
TCDD
TCDD(S)
PFK
TCDD(S) 1
TCDD(S)
PeCDF
PeCDF
PeCDF (S)
PeCDF (S)
PeCDD 1
PeCDD
PeCDD (S)
PeCDD (S)
HxCDPE
HpCPDE
HxCDF
HxCDF
HxCDF (S)
HxCDF (S)
HxCDD
HxCDD 1
PFK |

-------
I
401.8559
403.8529
445.7555
430.9729
M+2
M+4
M+4
QC
"CiaHa^Cls^ClOa
13C12Ha35Cl437ClaO
C12H235Cl6"ClaO
C,Pi,
HxCDD (S)
HxCDD(S)
OCDPE
PFK
TABLE 23-5.
(Continued)
DESCRIPTOR
NUMBER




ACCURATE
MASS
407.7818
409.7789
417.8253
389.8157
391.8127
392.9760
401.8559
403.8529
445.7555
430.9729
407.7818
409.7789
417.8253
419.8220
423.7766
425.7737
435.8169
437.8140
479.7165
430.9729
441.7428
443.7399
457.7377
459.7348
469.7779
ION
TYPE
M+2
M+4
M
M+2
M+4
LOCK
M+2
M+4
M+4
QC
M+2
M+4
M
M+2
M+2
M+4
M+2
M+4
M+4
LOCK
M+2
M+4
M+2
M+4
M+2
ELEMENTAL DESCRIPTION
C12H35C1637C1O
C12H35C1537C12O
13C12H35C17O
C12H23SCl537ClOa
C12H235Cl437ClaOa
C,FU
13C12Ha"Cl537ClOa
13C12Ha35Cl437ClaO
Ci2H235Cl637ClaO
C,F17
C12H3SC1S37C1O
C12H35Cl5"ClaO
13C12H35C17O
13C12H35C1637C10
C12H35C1637C1O2
C12H3SC1537C12O2
13C12H35Cls37ClOa
"C12H35Cl537ClaOa
C12H35C1737C12O
C,Pi,
C123SC1737C10
Cia35Cls37ClaO
Cia35Cl,37ClOa
Cia35Cl«37ClaOa
13Cia35Cl737C10a
ANALYTE
HpCDP
HpCDF
HpCDP (S)
HxCDD
HxCDD
PFK
HxCDD (S)
HxCDD (S)
OCDPE
PFK
HpCDP
HpCDF
HpCDF (S)
HpCDF (S)
-HpCDD
HpCDD
HpCDD (S)
HpCDD (S)
NCPDB
PFK
OCDP
OCDF
OCDD
OCDD
OCDD(S)
                                   57

-------

471.7750
513.6775
442.9728
M+4
M+4
QC
"C^CV'ClaOa
CVCV'ClaOa
Cio^i?
OCDD(S)
DCDPE
PFK
                   35C1 m 34.968853
The following nuclidic masses were used:
H - 1.007825      0 - 15.994914    C - 12.000000
13C - 13.003355   "Cl  -  36.965903    P - 18.9984
S « Labeled Standard
QC * Ion selected for monitoring instrument stability during the
GC/MS analysis.
58

-------
TABLE 23-6.  ACCEPTABLE RANGES FOR ION-ABUNDANCE RATIOS OP PCDD'B AND
                                PCDF'S
Number of
Chlorine
Atoms
4
5
6
6*
7b
7
8
Ion Type
M/M+2
M+2/M+4
M+2/M+4
M/M+2
M7M+2
M+2/M+4
M+2/M+4
Theoretical
Ratio
0.77
1.55
1.24
0.51
0.44
1.04
0.89
Control Limits
Lower
0.65
1.32
1.05
0.43
0.37
0.88
0.76
Upper
0.89
1.78
1.43
0.59
0.51
1.20
1.02
                                   59

-------
TABLE 23-7. T3NLABELED ANALYTES QUANTIFICATION RELATIONSHIPS
IANALYTE
2,3,7,8-TCDD






Other TCDD's

1,2,3,7,8-PeCDD
Other PeCDD's

1,2,3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDD







1,2,3,7,8,9-HxCDD
Other HxCDD's

1,2,3,4,6,7,8-HpCDD
Other HpCDD's
INTERNAL STANDARD USED 1
"Cia- 2,3,7,8-TCDD 1
"Cja- 2,3,7,8-TCDD 1

"Ca-l^.S.T.B-PeCDD
"Cu- 1 ,2,3,7, 8 -PeCDD

"0x3-1,2,3,6,7,8-11x0)0
l3Cia-l ,2,3,6,7, 8-HxCDD
"Cxa- 1 ,2,3,6,7,8 -HxCDD
"Cij-l , 2 , 3 , 6 , 7 , 8-HxCDD

"da-l , 2 , 3 , 4 , 6 , 7 , 8-HpCDD
"Cxa-1 , 2 , 3 , 4 , 6 , 7 , 8-HpCDD

OCDD
"CXS-OCDD

2,3,7,8-TCDF
Other TCDF's
"Cxa- 2,3,7,8-TCDF
"Cxa- 2,3,7,8-TCDF

1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
Other PeCDF's
•
1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDP
1,2,3,7,8,9-HxCDF
2,3,4,6,7,8-HxCDF
Other HxCDF's
13C12-l,2,3,7,8-PeCDF
«Cia-l,2,3,7,8-PeCDF
«CM-lf2.3.7,8-PeCDF

"Cu-l , 2 , 3 , 6 , 7 , 8-HxCDP
"Cu-l , 2 , 3 , 6 , 7 , 8-HxCDP
"Cja-l , 2 , 3 , 6 , 7 , 8 -HxCDP
"da-l , 2 , 3 , 6 , 7 , 8-HxCDF
"Cu-l , 2 , 3 , 6 , 7 , 8-HxCDP
.
















       1,2,3,4,6,7,8-HpCDF   "Cia-l,2,3,4,6,7,8-HpCDF
                               60

-------
1,2,3,4,7,8,9-HpCDF   "C^-1,2,3,4, 6, 1, 8-HpCDF
OCDF                  uC12-l,2,3,4,6,7,8THpCDF
                         61

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 TABLE 23-8.   INTERNAL STANDARDS QUANTIFICATION RELATIONSHIPS
INTERNAL STANDARD
13C12-2,3,7,8-TCDD
"C^-l^S^e-PeCDD
"Cu-l, 2,3,6,7, 8-HxCDD
13Cia-l , 2 , 3 , 4 , 6, 7, 8-HpCDD
13Cia-OCDD

13C12-2,3,7,8-TCDF
l3Cia-l,2,3,7,8-PeCDF
"Cu-l, 2, 3 , 6, 7, 8-HxCDF
l3C12-l,2,3,4,6,7,8-HpCDF
STANDARD USED DURING PERCENT
RECOVERY DETERMINATION
uCu-l,2f3*4-TCDD
"C^-l^S^-TCDD
"Cfu-1,2, 3,7, 8, 9-HxCDD
13Cia-l,2,3,7,8,9-HxCDD
"Cu-l , 2 , 3 , 7 , 8 , 9 -HxCDD

"^-1,2,3,4-1(3)0
"Cia-l,2,3,4-TCDD
"Cu-1 , 2 , 3 , 7 , 8 , 9 -HxCDD
13Cia-l , 2 , 3 , 7 , 8 , 9 -HxCDD
TABLE 23-9. SURROGATE STANDARDS QUANTIFICATION RELATIONSHIPS
SURROGATE STANDARD
37Cl4-2,3,7,8-TCDD
13C12-2 , 3,4,7, 8-PeCDF
13Cia-l , 2 , 3 , 4 , 7 , 8 -HxCDD
13Cia-l,2,3,4,7,8-HxCDF
13C12-1 , 2,3,4,7,8, 9-HpCDF
STANDARD USED DURING PERCENT
RECOVERY DETERMINATION
13Cia-2,3,7,8-TCDD
13C12-1, 2 ,3,7, 8-PeCDF
"Cu-1 ,2,3,6,7,8 -HxCDD
13Cia-l , 2 , 3 , 6 , 7 , 8 -HxCDF
13Cia-l , 2,3,4,6,7,8 -HpCDF

-------
TABLE 23-10.  MINIMUM REQUIREMENTS FOR INITIAL AND DAILY CALIBRATION
                                  RESPONSE FACTORS
COMPOUND

RELATIVE RESPONSE FACTORS
INITIAL
CALIBRATION
(RSD)
DAILY
CALIBRATION
(% DIFFERENCE)
UNLABELED ANALYTES
2,3,7,8-TCDD
2,3,7,8-TCDF
1,2,3,7,8-PeCDD
1,2,3,7,8-PeCDF
1,2,4,5,7,8-HxCDD
1,2,3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,4,6,7,8-HpCDD
11,2,3,4,6,7,8-HpCDF
OCDD
OCDF
25
25
25
25
25
25
25
25
25
25
25
25
25
25
30
25
25
25
25
25
25
25
25
25
25
25
25
25
25
30
SURROGATE STANDARDS
37Cl4-2,3,7,8-TCDD
13C12-2,3,4,7,8-PeCDF
"C12-l , 2 , 3 , 4 , 7 , 8-HxCDD
13C12-1 , 2 , 3 , 4 , 7 , 8-HxCDF
I3Cu-l , 2 , 3 , 4 , 7 , 8 , 9-HpCDF
25




25


1



                                   63

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-------
       Appendix G.5




Sampling & Analysis Methods




     EPA Method 25A

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              EMISSION MEASUREMENT TECHNICAL INFORMATION
                               NBP8 TEST METHOD
               METHOD 25A-DBTERMINATION OF TOTAL GASEOUS ORGANIC
                CONCENTRATION USING A FLAME lONIZATZON ANALYZER

1.    Applicability and Principle

1.1   Applicability.  This method applies to the measurement of total gaseous
organic concentration of vapors consisting primarily of alk«Ties,  alkenes, and/or
arenea  (aromatic hydrocarbons).    The concentration is expressed  in terms of
propane  (or other appropriate organic calibration gas) or in terms of carbon.

1.2   Principle.   A gas sample is  extracted from the source through a heated
sample line, if necessary,  and glass fiber filter to a flame ionization analyzer
(FIA).    Results  are reported  as  volume  concentration  equivalents  of the
calibration gas or as carbon equivalents.

2.    Definitions

2.1   Measurement  Systems.   The  total equipment required for the determination
of the gas concentration.  The system consists of the following major subsystems:

2.1.1 Sample Interface.  That portion of the system that is used for one or more
of   the  following:     sample  acquisition,   sample  transportation,   sample
conditioning,   or  protection of  the analyzer  from the effects  of the  stack
effluent.

2.1.2 Organic Analyzer.    That  portion  of the  system  that  senses  organic
concentration and generates an output proportional to the  gas concentration.

2.2    Span Value.  The upper limit of a gas concentration measurement-range that
is  specified  for affected  source  categories  in the applicable  part of  the
regulations.   The  span value is established in the applicable regulation and is
usually 1.5 to 2.5  times  the applicable emission limit.   If no span value is
provided, use  a  span value equivalent  to  1.5  to  2.5   times the  expected
concentration.  For  convenience, the span value should correspond to 100 percent
of  the recorder scale.

2.3   Calibration Gas.  A known concentration of a gas in an appropriate diluent
gas.

2.4   Zero Drift.  The difference  in the measurement system response to a zero
level calibration gas before and after a stated period of operation during which
no unscheduled maintenance, repair, or adjustment took place.
 Prepared by Emission Measurement Branch                           KMTIC TM-25A
 Technical Support Division, OAQPS, EPA                           June 23, 1993

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EMTIC TM-25A               EMTIC NSPS TEST METHOD                      Page 2


2.5   Calibration drift.  The difference in the measurement system response to
a midlevel calibration gas before and after a stated period of operation during
which no unscheduled maintenance,  repair or adjustment took place.

2.6   Response  Tine.   The  time  interval  from  a step  change  in pollutant
concentration at  the inlet to the emission measurement system to the time at
which 95 percent of the corresponding final value is reached as  displayed on the
recorder.

2.7   Calibration Error.  The difference between the gas concentration indicated
by the measurement  system and the known- concentration of the calibration gas.

3.    Apparatus.

      A schematic of an acceptable measurement system is shown  in  Figure 25A-1.
The  essential components  of  the measurement system are described  below t

3.1   Organic Concentration Analyzer.  A flame ion! sat ion analyzer (FIA) capable
of meeting or exceeding the  specifications in this method.

3.2   Sample Probe.   Stainless steel,  or equivalent,  three-hole rake  type.
Sample holes shall be 4 mm in diameter  or smaller and located at  16.7, 50, and
 83.3 percent of the equivalent stack diameter.  Alternatively,  a single opening
probe may be used so that a gas sample  is collected from the centrally located
 10 percent area of the stack cross-section.

 3.3   Sample Line.  Stainless steel or  Teflon * tubing to transport the sample
 gas  to the analyzer.  The sample line should be heated, if necessary, to prevent
 condensation in the line.

 3.4   Calibration Valve Assembly.  A three way valve assembly to direct the zero
 and calibration gases to the analyzers  is recommended.  Other methods, such as
 quick-connect lines, to route calibration gas to the analyzers are applicable.

 3.5   ^articulate Filter. An in-stack or an*out-of-stack glass fiber filter is
 recommended if  exhaust gas particulate loading is significant.  An out-of-stack
 filter should be heated  to prevent any condensation.

       *  Mention  of trade  names  or specific products  does not constitute
 endorsement by the Environmental Protection Agency.

 3.5   Recorder.  A strip-chart recorder, analog computer, or digital recorder for
 recording  measurement data.   The minimum  data recording  requirement  is one
 measurement value per minute, Note:   This  method is  often applied in highly
 explosive areas.  Caution and care should be exercised in choice of equipment and
 installation.

 4.    Calibration and Other Oases.

       Gases used for calibrations, fuel, and combustion air  (if required) are

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EMTIC TM-25A                EMTIC KSPS TEST METHOD                       Page 3


contained in compressed gas cylinders.  Preparation of calibration gases shall
be done according to the procedure in Protocol No.  1,  listed in Citation 2 of
Bibliography.  Additionally, the manufacturer of the cylinder should provide a
recommended  shelf  life   for  each  calibration  gas  cylinder  over which the
concentration does not change more than ±2 percent from the certified value,  for
calibration gas values not generally available (i.e., organics between 1 and 10
percent by volume), alternative methods for preparing calibration gas mixtures,
such as dilution systems, may be used with prior approval of the Administrator.

      Calibration gases  usually consist of propane  in air or nitrogen and are
determined in terms of the span value.  Organic compounds other than propane can
be used following the above guidelines  and making the appropriate corrections for
response factor.

4.1   Fuel.  A 40 percent Ha/60 percent II, gas mixture is recommended to avoid
an  oxygen synergism effect  that reportedly occurs when oxygen concentration
varies significantly from a mean value.


4.2   Zero Gas.  High purity air with less than 0.1 parts per  million by volume
 (ppmv)  of organic  material  (propane or carbon  equivalent)  or  less  than  0.1
percent of the span value, whichever is greater.

4.3   Low-level Calibration Gas. An organic  calibration gas with a concentration
equivalent to  25  to 35 percent of  the applicable span  value.

4.4   Mid-level Calibration Oas. An organic  calibration gas with a concentration
equivalent to  45  to 55 percent of  the applicable span  value.

4.5   High-level   Calibration   Oas.     An  organic  calibration  gas   with  a
concentration  equivalent  to 80 to  90 percent of the applicable span value.

5.    Measurement System Performance Specifications

5.1   Zero Drift.   Less  than ±3 percent of the span value.

5.2   Calibration Drift.  Less than ±3 percent of span value.

5.3   Calibration Error.  Less than ±5 percent of the  calibration gas  value.

6.    Pretest  Preparations

6.1   Selection of Sampling Site.  The location of the  sampling site is generally
specified by the applicable regulation or purpose  of  the test;  i.e.,  exhaust
stack, inlet line, etc.   The sample port shall be located at least 1.5 meters or
2 equivalent diameters upstream of the gas discharge  to the atmosphere.

6.2   Location of Sample  Probe.  Install the  sample probe so that the probe is
centrally located in the  stack, pipe, or duct and is sealed tightly at the stack
port connection.

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EMTIC TM-25A                EMTIC NSPS  TEST METHOD                      Page 4


6.3   Measurement System Preparation.   Prior to the emission test, assemble the
measurement system following the manufacturer's written instruction* in preparing
the sample interface and the organic analyzer.  Make the system operable.

      FIA equipment can be calibrated for  almost any range of total organic*
concentrations.  For high concentrations  of organic*  <>1.0 percent by volume a*
propane) modifications to most commonly available  analyzers are  necessary.   One
accepted method of equipment modification is to decrease the size of the sample
to the analyzer through the use of  a smaller diameter sample capillary.  Direct
and continuous measurement of organic concentration la a necessary consideration
when determining  any modification  design.

6.4   Calibration Error Test.   Immediately prior  to the test  series, (within 2
hours of the start of the test) introduce zero gas  and high-level calibration gas
at the calibration valve assembly.  Adjust the analyzer output to the appropriate
levels,  if necessary.   Calculate the predicted response for  the  low-level and
mid-level gases based on a  linear response line between the zero and high-level
responses.  Then introduce low-level and mid-level  calibration gases successively
to the measurement system.  Record the analyzer response* for low-level and mid-
level calibration gases and determine the  difference*  between the measurement
syatem responses and the predicted responsea.  These  differences must be less
than S percent of the respective calibration gas value.  If not, the  measurement
system is not acceptable and must be replaced or repaired prior to testing.  No
adjustments to the measurement system shall be conducted after the  calibration
and before the drift check (Section 7.3) .  If adjustments are necessary before
the completion of the test series,  perform the drift checks prior to  the  required
adjustments and repeat the calibration following the adjustments.   If multiple
electronic ranges are to be used,  each additional range must be checked with a
mid-level calibration gas  to verify the multiplication factor.

 6.5   Response Tim* Test.   Introduce Zero gas into the measurement system at the
 calibration  valve assembly.   When the  system  output has  stabilized, switch
 quickly  to  the  high-level  calibration  gas.    Record  the  time from the
 concentration change to the measurement system response equivalent to 95 percent
 of the step  change.  Repeat the test three times and average the results.

 7.    Emission Measurement Test Procedure

 7.1   Organic Measurement.  Begin sampling at the start of the test period,
 recording  time  and  any  required  process  information  as  appropriate.    In
 particular, note on the recording chart periods of process interruption or cyclic
 operation.

 7.2   Drift  Determination.  Immediately  following  the completion  of  the test
 period  and hourly during  the  test period, reintroduce the zero and mid-level
 calibration  gases, one at a time,  to the measurement  system  at the calibration
 valve assembly.   (Make no adjustments to the measurement system until after both
 the zero and calibration drift check* are made.)  Record  the  analyzer  response.
 If  the  drift values exceed the specified limits,  invalidate  the  teat result*
 preceding the check and repeat the test following correction* to the measurement

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EMTIC TM-25A                EMTIC NSPS TEST METHOD                      Page 5


system.  Alternatively, recalibrate the test measurement system as in Section 6.4
and report the results using both sets of calibration data (i.e.,  data determined
prior to the test period and data determined following the test period) .

8.    Organic Concentration calculations

      Determine the average organic concentration in terms of ppmv as propane or
other calibration gas.  The average shall be determined by the integration of the
output recording over the period specified in  the applicable regulation.   If
results are required in terms of ppmv as carbon, adjust measured concentrations
using Equation 25A-1.
  Where t
      C,    •     Organic  concentration as carbon, ppmv.
                   Organic concentration as measured, ppmv.

      K     •      Carbon equivalent correction factor.

      K     »      2 for ethane.

      K     •      3 for propane.

      K     *      4 for butane.

      K     •      Appropriate response  factor for  other organic  calibration
                   gases.

 9.    Bibliography

      1.     Measurement of Volatile Organic Compounds-Guideline Series.  U.S.
             Environmental  Protection Agency.    Research Triangle  Park,  NC.
             Publication No. EPA-450/2-78-041.  June 1978.  p.  46-54.


      2.     Traceability Protocol for Establishing True Concentrations of Gases
             Used  for  Calibration and Audits  of  Continuous Source   Emission
             Monitors (Protocol No.  1).   U.S. Environmental Protection Agency,

             Environmental Monitoring and Support Laboratory.   Research Triangle
             Park,  NC.  June 1978.

      3.     Gasoline  Vapor  Emission  Laboratory  Evaluation-Part  2.    U.S.
             Environmental Protection Agency, Office of Air Quality Planning and
             Standards.  Research Triangle Park, NC.   EMB Report No. 75-GAS-6.
             August 1975.

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EMTIC TM-25A
EMTIC NSPS TEST METHOD
Page 6
         Prate
                                                                  Orgwto
                                                                  Ana*ar
                                                                    •nd
                                                                  RttcHhr
                          Caferaflw
                            Valra
           Stack
    Figure 25A-1.   Organic Concentration Measurement System.

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       Appendix G.6




Sampling & Analysis Methods




 EPA Proposed Method 322

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(PROPOSED) TEST METHOD 322 - MEASUREMENT OF HYDROGEN CHLORIDE
EMISSIONS FROM PORTLAND CEMENT KILNS BY GFCU
1.0  Applicability and Principle
     1.1  Applicability.  This method is applicable to the
determination of hydrogen chloride  (HC1) concentrations in
emissions from portland cement kilns.  This is an instrumental
method for the measurement of HCl using an extractive sampling
system and an infrared  (IR) gas-filter correlation (GFC)
analyzer.  This method is intended to provide the cement industry
with a direct interface instrumental method.  A procedure for
analyte spiking is included for quality assurance.  This method
is considered to be self-validating provided that the
requirements in section 9 of this method are followed.
     1.2  Principle.  A gas sample is continuously extracted from
a stack or duct over the test period using either a source-level
hot/wet extractive subsystem or a dilution extractive subsystem.
A nondispersive infrared gas filter correlation  (NDIR-GFC)
analyzer is specified for the measurement of HCl in the sample.
The total measurement system is comprised of the extractive
subsystem, the analyzer, and the data acquisition subsystem.
Test system performance specifications  are included in this
method to provide for the collection of accurate, reproducible
data.


     1.3  Test System Operating Range.  The measurement range
 (span) of the test system  shall include the anticipated HCl
concentrations of the effluent and  spiked  samples.  The range
should be selected so that  the average  of  the  effluent
measurements is between 25  and 15 percent  of span.  If at any
time during a test run, the effluent concentration exceeds the
span value of the test  system, the  run  shall be  considered
invalid.
2.0  Summary of Method
     2.1  Sampling and  Analysis.  Kiln  gas is  continuously
extracted from the stack or duct using  either  a  source  level,
hot/wet  extractive system,  or an in-situ  dilution probe or heated
out-of-stack dilution  system.  The  sample  is  then directed by  a
heated  sample line maintained above 350°F  to a GFC analyzer
having  a range appropriate to the  type  of  sampling system.   The
 gas  filter correlation analyzer  incorporates  a gas cell filled
with HCl.  This  gas  cell  is periodically moved into the path of
 an infrared measurement beam of  the instrument to filter  out
 essentially all  of  the HCl absorption wavelengths.   Spectral
 filtering provides  a reference  from which the HCl concentration
 of the  sample can be determined.   Interferences are minimized in
 the  analyzer by  choosing a spectral band over which compounds
 such as C02 and H2O either do not absorb significantly or do not
match  the spectral  pattern of the  HCl infrared absorption.

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     2.2  Operator Requirements.   The analyst must be familiar
with the specifications and test  procedures of this method and
follow them in order to obtain reproducible and accurate data.
3.0  Definitions
     3.1  Measurement System.  The total equipment required for
the determination of gas concentration.  The measurement system
consists of the following major subsystems:
     3.1.1  Sample Interface.  That portion of a system used for
one or more of the following:  sample acquisition, sample
transport, sample conditioning, or protection of the analyzers
from the effects of the stack gas.
     3.1.2  Gas Analyzer.  That portion of the system that senses
the gas to be measured and generates an output proportional to
its concentration.
     3.1.3  Data Recorder.  A strip chart recorder, analog
computer, or digital recorder for recording measurement data  from
the analyzer output.
     3.2  Span.  The upper limit of the gas concentration
measurement range displayed on the data recorder.
     3.3  Calibration  Gas.  A known concentration of a gas  in an
appropriate diluent gas  (i.e., N2) .
     3.4  Analyzer Calibration Error.  The difference between the
gas concentration exhibited  by the gas analyzer and  the known
concentration  of  the calibration  gas when  the calibration gas is
introduced  directly  to the analyzer.
      3.5   Sampling  System Bias.   The  sampling system bias is  the
difference  between  the gas concentrations  exhibited  by  the
measurement system when a known  concentration gas is introduced
at the outlet  of  the sampling probe  and  the  known value of  the
calibration gas.
      3.6   Response Time.   The amount of  time required for  the
measurement system to display 95 percent of  a step change  in  gas
 concentration on the data recorder.
      3.7   Calibration Curve.  A  graph or other systematic method
 of establishing the relationship between the analyzer response
 and the actual gas concentration introduced to the analyzer.
      3.8  Linearity.  The linear response of the analyzer or  test
 system to known calibration inputs covering the concentration
 range of the system.
      3.9  Interference Rejection.  The ability of the system to
 reject the effect of interferences in the analytical measurement
 processes of the test system.
 4.0  Interferences
      4.1  Sampling System Interferences.  An important
 consideration in measuring HC1 using an extractive measurement
 system is to ensure that a representative kiln gas sample is
 delivered to the gas  analyzer.  A sampling system interferant is
 a factor that inhibits an analyte from reaching the analytical
 instrumentation.  Condensed water vapor is a strong sampling
 system interferant for HC1  and other water soluble compounds.

-------
"Cold spots" in the sampling system can allow water vapor in the
sample to condense resulting in removal of HC1 from the sample
stream.  The extent of HC1 sampling system bias depends on
concentrations of potential interferants,  moisture content of the
gas stream, temperature of the gas stream, temperature of
sampling system components, sample flow rate, and reactivity of
HC1 with other species in the gas stream.   For measuring HC1 in a
wet gas stream, the temperatures of the gas stream and sampling
system components and the sample flow rate are of primary
importance.  In order to prevent problems  with condensation in
the sampling system, these parameters must be closely monitored.
     4.1.1  System Calibration Checks.  Performing these
calibration checks where HC1 calibration gas is injected through
the entire system both before and after each test run
demonstrates the integrity of the sampling system and capability
of the analyzer for measuring this water soluble and otherwise
unstable compound under ideal conditions  (i.e., HC1 in N2) .
     4.1.2  Analyte Spiking Checks.  For analyte spiking checks,
HC1 calibration gas is quantitatively added to the sample stream
at a point upstream of the particulate filter and all other
sample handling components both before and after each test run.
The volume of HC1 spike gas should not exceed 10 percent of the
total sample volume so that the sample matrix is relatively
unaffected.  Successfully performing these checks demonstrates
the integrity of the sampling system for measuring this water
soluble and reactive compound under actual sample matrix
conditions.  Successfully performing these checks also
demonstrates the adequacy of the interference rejection
capability of the analyzer.   (See section 9.3 of this method.)
     4.2  Analytical Interferences.  Analytical interferences are
reduced by the GFC spectroscopic technique required by the
method.  The accuracy of HC1 measurements provided by some GFC
analyzers is known to be sensitive to the moisture content of the
sample.  This must be taken into account  in  order to acquire
accurate results.  These analyzers must be calibrated for the
specific moisture content of the samples.
5.0  Safety
     This method may involve sampling at  locations having high
positive or negative pressures, or high concentrations of
hazardous or toxic pollutants,  and cannot address all safety
problems encountered under these diverse  sampling conditions.   It
is the responsibility of the tester(s) to ensure proper  safety
and health practices, and  to determine the applicability of
regulatory limitations before performing  this  test method.
Because HC1 is a respiratory irritant, it is advisable to limit
exposure to this compound.
6.0  Equipment and Supplies
     Note:  Mention of company  or product names does not
constitute endorsement by  the U. S.  Environmental  Protection
Agency.

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     6.1  Measurement System.  Use  any GFC measurement system for
HC1 that meets the specifications of this  method.   All sampling
system components must be maintained above the kiln gas
temperature, when possible,  or at least 350°F.  The length of
sample transport line should be  minimized  and sampling rate
should be as high as possible to minimize  adsorption of HC1.  The
essential components of the measurement system are described in
sections 6.1.1 through 6.1.12.
     6.1.1  Sample Probe.  Glass,  stainless  steel, Hastalloy**, or
equivalent, of sufficient length to traverse the sample points.
The sampling probe shall be heated to a minimum of 350°F to
prevent condensation.  Dilution  extractive systems must use a
dilution ratio such that the average diluted concentrations are
between 25 to 75 percent of the  selected measurement range of the
analyzer.
     6.1.2  Calibration Valve Assembly.  Use a heated, three-way
valve assembly, or equivalent, for selecting either sample gas or
introducing calibration gases to the measurement system or
introducing analyte spikes into the measurement system at the
outlet of the sampling probe before the primary particulate
filter.
     6.1.3  Particulate Filter.   A coarse filter or other device
may be placed at the inlet of the probe for removal of large
particulate  (10 microns or greater).  A heated (Balston® or
equivalent) filter rated  at 1 micron  is necessary  for primary
particulate removal, and  shall be placed  immediately after the
heated probe.  The filter/filter holder shall be maintained at
350°F or a  higher temperature.   Additional filters at the inlet
of the gas  analyzer may be used to prevent accumulation of
particulate material in the measurement system and extend the
useful life of components.  All filters shall be  fabricated of
materials  that are nonreactive with HC1.  Some types  of glass
filters  are known to react with HC1.
     6.1.4  Sample Transport  Lines.   Stainless steel  or
polytetrafluoroethylene  (PTFE) tubing shall be heated to a
minimum  temperature  of 350°F  (sufficient  to prevent condensation
and  to prevent HC1  and NH3 from combining into ammonium chloride
in the  sampling  system)  to  transport  the  sample gas to the  gas
analyzer.
     6.1.5  Sample  Pump.   Use a leak-free pump to pull the  sample
gas  through the  system at a flow rate sufficient  to minimize the
 response time of the measurement system.  The pump components
 that contact  the sample  must be heated to a temperature  greater
 than 350°F and must  be constructed of a material  that is
nonreactive to HC1.
      6.1.6  Sample  Flow Rate Control.  A  sample  flow rate control
 valve  and rotameter,  or equivalent,  must  be used to maintain a
 constant sampling rate within ±10  percent.   These components must
 be heated to a temperature greater than 350°F.   (Note:   The
 tester may elect to install a back-pressure regulator to maintain

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 the  sample gas manifold at a  constant pressure in order to
 protect  the analyzer(s) from  over-pressurization, and to minimize
 the  need for flow rate adjustments.)
      6.1.7  Sample Gas Manifold.  A sample gas manifold, heated
 to a minimum of  350°F, is used to divert a portion of the sample
 gas  stream to the analyzer and the  remainder to the by-pass
 discharge vent.   The  sample gas manifold should also include
 provisions for introducing calibration gases directly to the
 analyzer.  The manifold must  be constructed of material that  is
 nonreactive to the gas being  sampled.
      6.1.8  Gas  Analyzer.  Use a nondispersive infrared analyzer
.utilizing the gas filter correlation technique to determine HC1
 concentrations.   The  analyzer shall meet the applicable
 performance specifications of section 8.0 of this method.   (Note:
 Housing  the analyzer  in a clean, thermally-stable, vibration  free
 environment will minimize drift in  the analyzer calibration.)
 The  analyzer (system) shall be designed so that the response  of a
 known calibration input shall not deviate by more than ±3 percent
 from the expected value.  The analyzer or measurement system
 manufacturer may provide documentation that the instrument meets
 this design requirement.  Alternatively, a known concentration
 gas  standard and calibration  dilution system meeting the
 requirements of  Method 205 of appendix M to part 51 of this
 chapter,  "Verification of Gas Dilution Systems for Field
 Calibrations" (or equivalent  procedure), may be used to develop a
 multi-point calibration curve over  the measurement range of the
 analyzer.
      6.1.9  Gas  Regulators.   Single stage regulator with  cross
 purge assembly that is used to purge the CGA fitting and
 regulator before and  after use.   (This purge is necessary to
 clear the calibration gas delivery  system of ambient water vapor
 after the initial connection  is made, or after cylinder
 changeover,  and  will  extend the life of the regulator.)  Wetted
 parts are 316 stainless steel to handle corrosive gases.
      6.1.10  Data Recorder.   A strip chart recorder, analog
 computer, or digital  recorder, for  recording measurement data.
 The  data recorder resolution  (i.e., readability) shall be 0.5
 percent  of span.   Alternatively, a  digital or analog meter having
 a resolution of  0.5 percent of span may be used to obtain the
 analyzer responses and the readings may be recorded manually.  If
 this alternative is used, the readings shall be obtained at
 equally-spaced intervals over the duration of the sampling run.
 For  sampling run durations of less  than 1 hour, measurements  at
 1-minute intervals or a minimum of  30 measurements, whichever is
 less restrictive,  shall be obtained. For sampling run durations
 greater  than 1 hour,  measurements at 2-minute intervals or a
 minimum  of 96 measurements, whichever is less restrictive, shall
 be obtained.•
      6.1.11  Mass Flow Meters/Controllers.  A mass flow meter
 having the appropriate calibrated range and a stated accuracy of

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±2 percent of the measurement  range  is  used  to measure  the HC1
spike flow rate*.  This device  must be calibrated with the major
component of the calibration spike gas  (e.g., nitrogen)  using an
NIST traceable bubble meter or equivalent.   When spiking HC1, the
mass flow meter/controller should be thoroughly  purged  before and
after introduction of the gas  to prevent corrosion of the
interior parts.
     6.1.12  System Flow Measurement.   A measurement device or
procedure to determine the total flow  rate of sample gas within
the measurement system.  A rotameter,  or mass flow meter
calibrated relative to a laboratory  standard to  within  ±2 percent
of the measurement value at the actual operating temperature,
moisture content, and sample composition (molecular weight) is
acceptable.  A system which ensures  that the total sample flow
rate is constant within ±2 percent  and which relies on  an
intermittent measurement of the actual flow  rate
 (e.g., calibrated gas meter) is also acceptable.
     6.2  HC1 Calibration Gases.  The calibration gases for the
gas analyzer shall be HC1 in N2.  Use at least three calibration
gases as specified below:
     6.2.1  High-Range Gas.  Concentration equivalent to  80 to
100 percent of  the span.
     6.2.2  Mid-Range Gas.  Concentration equivalent to 40 to 60
percent of the  span.
     6.2.3  Zero Gas.  Concentration of  less than 0.25 percent  of
the  span.  Purified  ambient air may be used for  the  zero  gas  by
passing air through  a  charcoal filter or through one or more
impingers containing a solution of 3 percent H2O2.
     6.2.4 Spike Gas.  A calibration gas of known concentration
 (typically 100  to 200  ppm)  used for analyte spikes  in  accordance
with the  requirements  of section 9.3 of  this method.
 7.0  Reagents  and Standards
     7.1  Hydrogen Chloride.   Hydrogen  Chloride  is  a reactive gas
 and  is available in  steel cylinders from various commercial  gas
 vendors.  The  stability  is such that it is  not  possible  to
 purchase  a  cylinder  mixture whose HC1  concentration can  be
 certified at better  than ±5 percent.   The stability of the
 cylinder  may be monitored over time by periodically analyzing
 cylinder  samples. The cylinder gas concentration must be
 verified within 1 month prior to the  use of the calibration gas.
 Due to the relatively high uncertainty of HC1 calibration gas
 values,  difficulties may develop in meeting the performance
 specifications if the mid-range and high-range  calibration gases
 are not  consistent with each  other.  Where  problems are
 encountered, the consistency  of the test gas standards may be
 determined:   (1) by comparing analyzer responses for the test
 gases with the responses to additional certified calibration gas
 standards,  (2) by reanalysis  of the calibration gases  in
 accordance with sections 7.2.1 or  7.2.2 of  this method, or  (3) by
 other procedures subject to the approval of EPA.

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     7.2  Calibration Gas Concentration Verification.  There  are
two alternatives for establishing the concentrations of
calibration gases.  Alternative No. 1 is preferred.
     7.2.1  Alternative No. 1.  The value of the calibration
gases may be obtained from the vendor's certified analysis within
1 month prior to the test.  Obtain a certification from the gas
manufacturer that identifies the analytical procedures and date
of certification.
     7.2.2  Alternative No. 2.  Perform triplicate analyses of
the gases using Method 26 of appendix A to part 60 of this
chapter.  Obtain gas mixtures with a manufacturer's tolerance not
to exceed ±5 percent of the tag value.  Within 1 month of the
field test, analyze each of the calibration gases in triplicate
using Method 26 of appendix A to part 60 of this chapter.  The
tester must follow all of the procedures in Method 26 (e.g., use
midget impingers, heated Pallflex TX40H175 filter  (TFE-glass
mat)/ etc. if this analysis is performed.  Citation 3 in section
13 of this method describes procedures and techniques that may be
used for this analysis.  Record the results on a data sheet.
Each of the individual HC1 analytical results for each
calibration gas shall be within 5 percent  (or 5 ppm, whichever is
greater) of the triplicate set average; otherwise, discard the
entire set and repeat the triplicate analyses.  If the average of
the triplicate analyses is within 5 percent of the calibration
gas manufacturer's cylinder tag value, use the tag value;
otherwise, conduct at least three additional analyses until the
results of six consecutive runs agree within 5 percent  (or 5 ppm,
whichever is greater) of the  average.  Then use this average for
the cylinder value.
     7.3  Calibration Gas Dilution Systems.  Sample  flow rates of
approximately 15  L/min are typical for extractive  HC1 measurement
systems.  These flow rates coupled with response times of 15 to
30 minutes will result in consumption of large quantities of
calibration gases.  The number of cylinders and amount of
calibration gas can be reduced by the use  of a calibration gas
dilution system in accordance with Method  205 of appendix M to
part 51 of this chapter,  "Verification of  Gas Dilution Systems
for Field Instrument Calibrations."   If this option  is used, the
tester  shall also introduce an undiluted calibration gas
approximating the effluent HC1 concentration during  the  initial
calibration error test of  the measurement  system as  a quality
assurance check.
8.0  Test System  Performance  Specifications
     8.1  Analyzer Calibration Error.  This error  shall  be  less
than ±5 percent of the emission  standard concentration or ±1
ppm,(whichever is greater) for zero,  mid-, and high-range gases.
     8.2  Sampling System Bias.  This bias shall be  less than
±7.5 percent of the emission  standard concentration  or ±1.5 ppm
 (whichever is greater) for zero  and  mid-range gases.
     8.3  Analyte Spike Recovery.  This  recovery  shall be between

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70 to 130 percent of the expected concentration of spiked samples
calculated with the average of the before and after run spikes.
9.0  Sample Collection,  Preservation,  and Storage
     9.1  Pretest.  Perform the procedures of sections 9.1.1
through 9.1.3.3 of this method before measurement of emissions
(procedures in section 9.2 of this method).  It is important to
note that after a regulator is placed on an HC1 gas cylinder
valve, the regulator should be purged with dry N2 or dry
compressed air for approximately 10 minutes before initiating any
HC1 gas flow through the system.  This purge is necessary to
remove any ambient water vapor from within the regulator and
calibration gas transport lines; the HC1 in the calibration gas
may react with this water vapor and increase system response
time.  A purge of the system should also be performed at the
conclusion of a test day prior to removing the regulator from the
gas cylinder.  Although the regulator wetted parts are corrosion
resistant, this will reduce the possibility of corrosion
developing within the regulator and extend the life of the
equipment.
      9.1.1  Measurement System Preparation.  Assemble the
measurement system by following the manufacturer's written
instructions for  preparing and preconditioning the gas analyzer
and,  as applicable,  the other system components.  Introduce the
calibration gases in any  sequence, and make all  necessary
adjustments to  calibrate  the analyzer and the data  recorder.   If
necessary, adjust the instrument  for the  specific moisture
content of the  samples.   Adjust system components to  achieve
correct sampling  rates.
      9.1.2  Analyzer Calibration  Error.   Conduct the  analyzer
calibration error check in the  field by  introducing calibration
gases to  the measurement  system at any point upstream of the gas
analyzer  in accordance  with sections  9.1.2.1 and 9.1.2.2 of this
method.
      9.1.2.1   After the measurement  system has been prepared for
use,  introduce the  zero,  mid-range,  and  high-range  gases to the
analyzer.   During this  check,  make no adjustments to the system
except those  necessary to achieve the correct  calibration  gas
 flow rate at  the analyzer.  Record the  analyzer  responses  to each
 calibration gas.   HojLfi:  A calibration  curve established prior to
 the analyzer  calibration error check may be used to convert the
 analyzer response to the equivalent  gas concentration introduced
 to the analyzer.  However, the same  correction procedure  shall be
 used for all effluent and calibration measurements obtained
 during the test.
      9.1.2.2  The analyzer calibration  error check shall be
 considered invalid if the difference in gas concentration
 displayed by the analyzer and the concentration of the
 calibration gas exceeds ±5 percent of the emission standard
 concentration or ±1 ppm,  (whichever is  greater)  for the zero,
 mid-, or high-range calibration gases.   If an invalid calibration

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is exhibited, cross-check or recertify the calibration gases,
take corrective action, and repeat the analyzer calibration error
check until acceptable performance is achieved.
     9.1.3  Sampling System Bias Check.  For nondilution
extractive systems, perform the sampling system bias check by
introducing calibration gases either at the probe inlet or at a
calibration valve installed at the outlet of the sampling probe.
For dilution systems, calibration gases for both the analyzer
calibration error check and the sampling system bias check must
be introduced prior to the point of sample dilution.  For
dilution and nondilution systems, a zero gas and either a mid-
range or high-range gas  (whichever more closely approximates the
effluent concentration) shall be used for the sampling system
bias check.
     9.1.3.1  Introduce the upscale calibration gas, and record
the gas concentration displayed by the analyzer.  Then introduce
zero gas, and record the gas concentration displayed by the
analyzer.  During the sampling system bias check, operate the
system at the normal sampling rate, and make no adjustments to
the measurement system other than those necessary to achieve
proper calibration gas flow rates at the analyzer.  Alternately
introduce the zero and upscale gases until a stable response is
achieved.  The tester  shall determine the measurement system
response time by observing the times required to achieve a stable
response for both  the  zero and upscale gases.  Mote the longer of
the two times and  note the time  required  for the measurement
system to reach 95 percent of the step change in the effluent
concentration as the response time.
     9.1.3.2  For  nondilution systems, where the analyzer
calibration  error  test is performed by introducing gases directly
to the analyzer, the sampling system bias check shall be
considered invalid if  the difference between the gas
concentrations displayed by the  measurement  system for the
sampling system bias check and the known  gas concentration
standard exceeds ±7.5  percent of the emission  standard or ±1.5
ppm,  (whichever is greater) for  either the  zero or the upscale
calibration  gases.   If an invalid calibration  is exhibited,  take
corrective action, and repeat the sampling  system bias check
until acceptable performance is  achieved.   If  adjustment to  the
analyzer is  required,  first repeat the analyzer calibration  error
check, then  repeat the sampling  system bias  check.
      9.1.3.3  For  dilution  systems  (and  nondilution systems  where
all calibration gases  are introduced at  the probe), the
comparison of  the  analyzer  calibration error results  and sampling
system bias  check  results is not meaningful.   For  these systems,
the  sampling system  bias check  shall  be  considered  invalid if  the
difference between the gas  concentrations displayed by the
analyzer  and the actual  gas concentrations  exceed  ±7.5 percent of
the  emission standard  or ±1.5 ppm,  (whichever  is greater)  for
either the zero or the upscale  calibration gases.   If an invalid

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calibration is exhibited,  take corrective action,  and repeat the
sampling system bias check until acceptable performance is
achieved.  If adjustment to the analyzer is required, first
repeat the analyzer calibration error check.
     9.2  Emission Test Procedures
     9.2.1  Selection of Sampling Site and Sampling Points.
Select a measurement site and sampling points using the same
criteria that are applicable to Method 26 of appendix A to part
60 of this chapter.

     9.2.2  Sample Collection.  Position the sampling probe at
the first measurement point, and begin sampling at the same rate
as used during the sampling system bias check.  Maintain constant
rate sampling  (i.e., ±10 percent) during the entire run.  Field
test experience has shown that conditioning of the sample system
is necessary for approximately 1-hour prior to conducting the
first sample run.  This conditioning period should be repeated
after particulate filters are replaced and at the beginning of
each new day or following any period when the sampling system is
inoperative.   Experience has also shown that prior to adequate
conditioning of the system, the  response to analyte  spikes and/or
the change from an upscale  calibration gas to a representative
effluent measurement may be delayed by more than twice the normal
measurement system response time.  It is recommended that the
analyte  spikes (see section 9.3  of this method) be performed to
determine  if  the  system is  adequately conditioned.   The sampling
system is  ready for use when  the time required for the
measurement system to  equilibrate after a  change from a
representative effluent measurement to a representative spiked
sample measurement approximates  the calibration gas  response time
observed in section 9.1.3.1 of  this method.
      9.2.3 Sample  Duration.  After completing the sampling
system bias checks  and analyte  spikes prior  to a test  run,
constant rate sampling of  the effluent  should begin.   For each
run,  use only those measurements obtained  after all  residual
response to calibration standards or  spikes  are eliminated and
representative effluent measurements  are displayed to  determine
the average  effluent  concentration.   At  a  minimum, this  requires
that the response time of the measurement  system has elapsed
before  data  are recorded for  calculation of the average  effluent
 concentration.  Sampling should be  continuous for  the duration  of
 the test run.  The length of data collection should  be at least
 as long as required for sample.collection by Method  26 of part  60
 of this chapter.   One hour sampling runs using this  method have
 provided reliable data for cement kilns.
      9.2.4  Validation of Runs.  Before and after each run, or  if
 adjustments are necessary for the measurement system during the
 run, repeat the sampling system bias check procedure described in
 section 9.1.3 of this method.   (Make no adjustments  to the
 measurement system until after the drift checks are completed.)

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Record the analyzer's responses.
     9.2.4.1  If the post-run sampling system bias for either the
zero or upscale calibration gas exceeds the sampling system bias
specification, then the run is considered invalid.  Take
corrective action, and repeat both the analyzer calibration error
check procedure  (section 9.1.2 of this method) and the sampling
system bias check procedure (section 9.1.3 of this method) before
repeating the run.                                            ,
     9.2.4.2  If the post-run sampling system bias for both the
zero and upscale calibration gas are within the sampling system
bias specification, then construct two 2-point straight lines,
one using the pre-run zero and upscale check values and the other
using the post-run zero and upscale check values.  Use the slopes
and y-intercepts of the two lines to calculate the gas
concentration for the run in accordance with equation 1 of this
method.
     9.3  Analyte Spiking—Self-Validating Procedure.  Use analyte
spiking to verify the effectiveness of the sampling system for
the target compounds in the actual kiln gas matrix.  Quality
assurance  (QA) spiking should be performed before and after each
sample run.  The spikes may be performed following the sampling
system bias checks  (zero and mid-range system calibrations)
before each run in a series and also after the last run.  The HC1
spike recovery should be within ±30 percent as calculated using
equations  1 and 2 of this method.  Two general approaches are
applicable for the use of analyte spiking to validate a GFC HC1
measurement system:   (1) two independent measurement systems can
be operated concurrently with analyte spikes introduced to one of
the systems, or  (2) a single measurement system can be used to
analyze consecutively, spiked and unspiked samples in an
alternating fashion.  The two-system approach is  similar to
Method 301 of this appendix and the measurement bias is
determined from the difference in the paired concurrent
measurements relative to the amount of HC1 spike  added to the
spiked system.  The two-system approach must employ identical
sampling systems and analyzers and both measurement systems
should be  calibrated using the same mid- and high-range
calibration standards.  The two-system approach should be largely
unaffected by temporal variations in the effluent concentrations
if both measurement systems achieve the same  calibration
responses  and both systems have the same response times.   (See
Method 301 of this appendix for appropriate calculation
procedures.)  The single measurement system approach is
applicable when the concentration of HC1 in the source does not
vary substantially during the period of the test.  Since the
approach depends on the comparison of consecutive spiked and
unspiked samples, temporal variations in the  effluent HC1
concentrations will introduce errors in determining the expected
concentration of the spiked samples.  If the  effluent HC1
concentrations vary by more than ±10 percent  (or  ±5 ppm.

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whichever is greater)  during the time required to obtain and
equilibrate a new sample (system response time),  it may be
necessary to:  (1)  use a dual sampling system approach,
(2) postpone testing until stable emission concentrations are
achieved,  (3) switch to the two-system approach [if possible] or,
(4) rely on alternative QA/QC procedures.  The dual-sampling
system alternative uses two sampling lines to convey sample to
the gas distribution manifold.  One of the sample lines is used
to continuously extract unspiked kiln gas from the source.  The
other sample line serves as the analyte spike line.  One GFC
analyzer can be used to alternately measure the HC1 concentration
from the two sampling systems with the need to purge only the
components between the common manifold and the analyzer.  This
minimizes the time required to acquire an equilibrated sample of
spiked or unspiked kiln gas.  If the source varies by more than
±10 percent or ±5 ppm,  (whichever is greater) during the time it
takes to switch from the unspiked sample line to the spiked
sample line, then the dual-sampling system alternative approach
is not applicable.  As a last option,  (where no other
alternatives can be used) a humidified nitrogen stream may be
generated  in the field which approximates the moisture content of
the kiln gas.  Analyte  spiking  into this humidified stream can be
employed to  assure that the sampling system  is adequate  for
transporting the HC1 to the GFC analyzer and that  the  analyzer's
water interference rejection  is adequate.
     9.3.1  Spike Gas Concentration  and  Spike Ratio.   The volume
of HC1 spike gas should not exceed 10  percent of the total  sample
volume  (i.e.,  spike to  total  sample  ratio of 1:10)  to  ensure that
the sample matrix is  relatively unaffected.  An  ideal  spike
concentration  should  approximate  the native  effluent
concentration,  thus the spiked  sample  concentrations would
represent  approximately twice the native effluent  concentrations.
The ideal  spike concentration may not  be achieved  because the
native HC1 concentration  cannot be accurately predicted prior to
the field  test,  and limited calibration  gas  standards  will  be
available  during the  field test.   Some flexibility is  available
by varying the spike  ratio over the  range from 1:10 to 1:20.
 Practical  constraints must be applied to allow the tester to
 spike  at an anticipated concentration.  Thus,  the  tester may use
 a 100  ppm calibration gas and a spike ratio  of 1:10 as default
 values where information regarding the expected HC1 effluent
 concentration is not  available prior to the  tests.
 Alternatively, the tester may select another calibration gas
 standard and/or lower spike ratio (e.g., 1:20)  to more closely
 approximate the effluent HC1 concentration.
      9.3.2  Spike Procedure.  Introduce the  HC1 spike gas mixture
 at a constant flow rate (±2 percent) at less than 10 percent of
 the total sample flow rate.  (For example, introduce the HC1
 spike gas at 1 L/min (±20 cc/min) into a total sample flow  rate
 of 10 L/min).  The spike gas must be preheated before

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   introduction into the sample matrix to prevent  a  localized
   condensation of the gas stream at the spike introduction point.
   A heated sample transport line(s)  containing multiple transport
   tubes within the heated bundle may be used to spike gas up
   through the sampling system to the spike introduction point.   Use
   a calibrated flow device (e.g., mass flow meter/controller)  to
   monitor the spike flow rate.  Use a calibrated  flow device (e.g.,
   rotameter,  mass flow meter,  orifice meter,  or other method)  to
   monitor the total sample flow rate.  Calculate  the spike ratio
   from the measurements of spike flow and total flow.   (See
   equation 2  and 3 in section 10.2 of this method.)
        9.3.3   Analyte Spiking.  Determine the approximate effluent
   HC1 concentrations by examination of preliminary  samples.   For
   single-system approaches,  determine whether the HC1 concentration
   varies significantly with time by comparing consecutive samples
   for the period of time corresponding to at least  twice the system
   response time.  (For analyzers without sample averaging,  estimate
   average values for two to five minute periods by  observing the
   instrument  display or data recorder output.) If the concentration
   of the individual samples varies by more than ±10 percent
   relative to the mean value or ±5 ppm, (whichever  is greater),  an
   alternate approach may be needed.
        9.3.3.1  Adjust the spike flow rate to the appropriate level
   relative to the total flow by metering spike gas  through a
   calibrated  mass flow meter or controller.  Allow  spike flow to
   equilibrate within the sampling system for at least the
   measurement system response time and a steady response to the
   spike gas is observed before recording response to the spiked  gas
   sample.  Next, terminate the spike gas flow and allow the
   measurement system to sample only the effluent.   After the
   measurement system response time has elapsed and  representative
   effluent measurements are obtained,  record the  effluent unspiked
   concentration.  Immediately calculate the spike recovery.
        9.3.3.2  If the spike recovery is not within acceptable
   limits and  a change in the effluent concentration is suspected as
   the cause for exceeding the recovery limit,  repeat the analyte
   spike procedure without making any adjustments  to the analyzer or
   sampling system.  If the second spike recovery  falls within the
   recovery limits, disregard the first attempt and  record the
   results of  the second spike.
        9.3.3.3  Analyte spikes must  be performed  before and after
   each test run.  Sampling system bias checks must  also be
   performed before and after each test run.  Depending on the
   particular  sampling strategy and other constraints,  it may be
   necessary to compare effluent data either immediately before or
   immediately after the spike sample to determine the spike
   recovery.   Either method is  acceptable provided a consistent
   approach is used for the test program.  The average spike
    ecovery for the pre- and post-run spikes shall be used to
\   etermine if spike recovery is between 70 and 130 percent.

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10.0  Data Analysis and Emission Calculations
     The average gas effluent concentration is determined from
the average gas concentration displayed by the gas analyzer and
is adjusted for the zero and upscale sampling system bias checks,
as determined in accordance with section 9.2.3 of this method.
The average gas concentration displayed by the analyzer may be
determined by integration of the area under the curve for chart
recorders, or by averaging all of the effluent measurements.
Alternatively, the average may be calculated from measurements
recorded at equally spaced intervals over the entire duration of
the run.  For sampling run durations of less than 1-hour, average
measurements at 2 -minute intervals or less, shall be used.  For
sampling run durations greater than 1-hour, measurements at 2-
minute intervals or a minimum of 96 measurements, whichever is
less restrictive, shall be used.  Calculate the effluent gas
concentration using equation 1.
     C  = _ l   ^"    J -      where:
      •"                2                        bc    -  Y-
                                                     intercept of
                                                     the
                                                     calibration
                                                     least-
                                                     squares
                                                     line.
      bf    »  Y-intercept of the final bias check 2-point    line.
      bj    «  Y-intercept of the initial bias  check 2-point
              line.
      CgM   *»  Effluent gas concentration,  as measured,  ppm.
      Cavg   **  Average gas concentration indicated by gas
           analyzer,  as measured, ppm.
      m,,    «  Slope of the calibration least-squares line.
      mf    *=  Slope of the final bias  check 2-point  line.
      1%    _  Slope of the initial bias check  2-point line.

 The following equations are used to determine the percent
 recovery  (%R) for analyte spiking:
                  %R =  (SM/CE)  X 100                   (Eq.  2)
 where :
      SM •»  Mean concentration of duplicate analyte spiked
            samples (observed) .
      CB -  Expected concentration of analyte  spiked samples
            (theoretical) .
            CB  - CS(QS/QT)  + S0(1-QS/QT)                 (Eq.  3)
 where:
      Cs -  Concentration of HC1 spike gas (cylinder tag
            value) .
      Qs »  Spike gas flow rate.

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     QT  «   Total sample flow  rate  (effluent  sample flow plus
           spike flow).
     S0  =   Native concentration  of  HC1  in  unspiked effluent
           samples.
Acceptable recoveries  for analyte spiking are ±30 percent.
11.0  Pollution Prevention
     Gas extracted from the source and analyzed or vented from
the system manifold shall be either scrubbed, exhausted back into
the stack, or discharged into the atmosphere where suitable
dilution can occur to prevent harm to personnel health and
welfare or plant or personal property.
12.0  Waste Management
     Gas standards of HC1 are handled as according to the
instructions enclosed with the materials safety data sheets.
13.0  References
     1.   Peeler, J.W., Summary Letter Report to Ann Dougherty,
Portland Cement Association,  June 20, 1996.
     2.   Test Protocol, Determination of Hydrogen Chloride
Emissions from Cement Kilns  (Instrumental Analyzer Procedure)
Revision 4; June 20, 1996.
     3.   Westlin, Peter R. and John W.  Brown.  Methods for •
Collecting and Analyzing Gas Cylinder Samples.  Source Evaluation
Society Newsletter.  1(3):5-15.   September 1978.

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     APPENDIX H




PROJECT PARTICIPANTS

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                           PROJECT PARTICIPANTS
Affiliation
Name
Responsibility
USEPA
Joe Wood, BSD

Michael L. Toney, EMC
Environmental Engineer

Work Assignment Manager
Pacific Environmental Services,
Inc.
Franklin Meadows

Michael D. Maret

Dennis P. Holzschuh

Dennis D. Holzschuh

Gary Gay

Paul Siegel

Troy Abernathy
Project Manager

Task Manager

QA Coordinator

Site Leader/Console Operator

Site Leader/Console Operator

Sampling Technician

Sample Recovery
Atlantic Technical Services
(PES Subcontractor)
Emil Stewart
                             Alan F. Lowe
                             Marshall M. Cannon
Sampling Technician/Data
Reduction

Technical Support

Technical Support
APCC, Ltd.
(PES Subcontractor)
John Powell
                             Eric Dithrich
                             Peter Day
President
                        CEM Team Leader
                        CEM Sampling Technician
Research Triangle Institute
(EPA/ESD Contractor)
Cybele M. Brockmann
Process Coordinator

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TECHNICAL REPORT DATA
Please read instructions on the reverse before completing
1. REPORT NO.
EPA-454/R-00-013
2.
4. TITLE AND SUBTITLE
Final Report
Manual Testing and Continuous Emissions Monitoring
Kiln No. 2 Scrubber Inlet and Outlet and
Kiln No. 3 Baghouse Inlet and Stack
Austin White Lime Company
Austin, Texas

7. AUTHOR(S)
Franklin Meadows
Emil W. Stewart
9. PERFORMING ORGANIZATION NAME AND ADDRESS
Pacific Environmental Services, Inc.
Post Office Box 12077
Research Triangle Park, North Carolina 27709-2077
12. SPONSORING AGENCY NAME AND ADDRESS
U.S. Environmental Protection Agency
Office of Air Quality Planning and Standards
Emissions, Monitoring and Analysis Division
Research Triangle Park, North Carolina 2771 1
3. RECIPIENT'S ACCESSION NO.
5. REPORT DATE
April 2000
6. PERFORMING ORGANIZATION CODE
8. PERFORMING ORGANIZATION REPORT NO.
10. PROGRAM ELEMENT NO.
11. CONTRACT/GRANT NO.
68-D-98004
13. TYPE OF REPORT AND PERIOD COVERED
Final
14. SPONSORING AGENCY CODE
EPA/200/04
15. SUPPLEMENTARY NOTES
16. ABSTRACT
The United States Environmental Protection Agency (EPA) Emission Standards Division (BSD) is investigating the lime manufacturing industry to
identify and quantify hazardous air pollutants (HAPs) emitted from lime kilns. ESD requested that EPA's Emissions, Monitoring and Analysis Division
(EMAD) conduct the required testing. EMAD issued a work assignment to Pacific Environmental Services, Inc. (PES) to conduct a "screening" test to
collect air emissions data as specified in the ESD test request. The primary objective of the testing program was to characterize HAP emissions from
two rotary kilns at the Austin White Lime Company's facility located in San Antonio, Texas. Based on the pollutant concentrations and emission rates
calculated from the results of the "screening" tests, the kilns may be selected by EPA for further testing.
The tests were conducted to quantify the uncontrolled and controlled air emissions of hydrogen chloride (Hcl), total hydrocarbons (THC), and
polychlorinated dibenzo-p-dioxins and polyclorinated dibenzofurans (PCDDs/PCDFs). Emissions from the Kiln No. 2 were controlled by a scrubber.
Emissions from Kiln No. 3 were controlled by a baghouse. On Kiln No. 2, one 3-hour run was conducted. The scrubber inlet and lotlet were tested
simultaneously. On Kiln No. 3, one 3-hour run was conducted. The baghouse inlet and two baghouse outlet stacks were tejted. One of the baghouse
outlet stacks was sampled using manual methods and the other was sampled using continuous monitors. The baghouse inlet and two baghouse outlet
stacks were tested simultaneously.
During the testing program another EPA contractor monitored and recorded process and emission control system operating parameters. These data
were treated as Condidential Business Information and are not included in this report.
17.
a, DESCRIPTIONS
Baghouse
Dioxins/Furans
Hazardous Air Pollutants
Hydrogen Chloride
Scrubber
Total Hydrocarbons
18. DISTRIBUTION STATEMENT
Unlimited '
KEY WORDS AND DOCUMENT ANALYSIS
b. IDENTIFIERS/OPEN ENDED TERMS

19. SECURITY CLASS (This Report)
Unclassified
20. SECURITY CLASS (This page)
Unclassified
c. COASTI Field/Group

21. NO. OF PAGES
, 766 , ' "•
22. PRICE

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