United States Office of Air Quality
Environmental Protection Planning and Standards
Agency Research Triangle Park, NC 27711
EPA - 454/R-00-023b
April 2000
Air
&EPA
Hot Mix Asphalt Plants
Kiln Dryer Stack
Manual Methods Testing
Asphalt Plant B
Gary, North Carolina
Volume 2 of 2
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-------
FINAL REPORT
EMISSIONS TEST AT AN ASPHALT CONCRETE PRODUCTION PLANT:
ASPHALT PLANT "B" - CARY, NORTH CAROLINA
VOLUME II OF II
APPENDIX C
APPENDIX D
APPENDIX E
APPENDIX F
EPA Contract No. 68D70069
Work Assignment No. 2-09
Prepared for:
Mr. Michael L. Toney (MD-19)
Work Assignment Manager
SCGA, EMC, OAQPS
U.S. Environmental Protection Agency
Research Triangle Park, NC 27711
September 1999
p:\i529\finrpt\"B"\mm08119A.wpd
Submitted by
PACIFIC ENVIRONMENTAL SERVICES, INC.
5001 S. Miami Blvd., Suite 300
Post Office Box 12077
Research Triangle Park, NC 27709-2077
(919)941-0333
FAX (919) 941-0234 y s CnvhwimerrtH Protection Agency
-------
DISCLAIMER
This document was prepared by Pacific Environmental Services, Inc. (PES) under EPA
Contract No. 68D70069, Work Assignment No. 2-09. This document has been reviewed
following PES' internal quality assurance procedures and has been approved for distribution.
The contents of this document do not necessarily reflect the views and policies of the U.S. EPA.
Mention of trade names does not constitute endorsement by the EPA or PES.
11
-------
TABLE OF CONTENTS
VOLUME I Page
1.0 INTRODUCTION 1-1
2.0 SUMMARY OF RESULTS 2-1
2.1 OXYGEN AND CARBON DIOXIDE MEASUREMENTS 2-1
2.2 PCDDs/PCDFs MEASUREMENTS 2-1
2.2.1 Baghouse Inlet - Asphalt Production with RAP 2-5
2.2.2 Baghouse Outlet- Asphalt Production with RAP 2-9
2.2.3 Baghouse Inlet - Asphalt Production without RAP 2-13
2.2.4 Baghouse Outlet - Asphalt Production without RAP 2-17
2.3 PARTICULATE MATTER AND METALS MEASUREMENTS 2-17
2.3.1 Baghouse Inlet - Asphalt Production with RAP -. 2-17
2.3.2 Baghouse Outlet- Asphalt Production with RAP 2-25
2.3.3 Baghouse Inlet - Asphalt Production without RAP 2-25
2.3.4 Baghouse Outlet - Asphalt Production without RAP 2-34
2.4 DETERMINATION OF VISIBLE EMISSIONS 2-34
3.0 PROCESS DESCRIPTION 3-1
4.0 SAMPLING LOCATIONS 4-1
4.1 BAGHOUSE INLET SAMPLING LOCATION 4-1
4.2 BAGHOUSE OUTLET SAMPLING LOCATION 4-1
5.0 SAMPLING AND ANALYSIS PROCEDURES 5-1
5.1 LOCATION OF MEASUREMENT SITES AND
SAMPLE/VELOCITY TRAVERSE POINTS 5-1
5.2 DETERMINATION OF STACK GAS VOLUMETRIC
FLOW RATE 5-1
5.3 DETERMINATION OF DRY MOLECULAR WEIGHT
AND EMISSION CORRECTION FACTORS 5-1
5.4 DETERMINATION STACK GAS MOISTURE CONTENT 5-2
111
-------
TABLE OF CONTENTS (Continued)
VOLUME I Page
5.5 DETERMINATION OF POLYCHLORINATED DIBENZO-P-DIOXINS
AND POLYCHLORINATED DIBENZOFURANS 5-2
5.6 DETERMINATION OF PARTICULATE MATTER AND METALS 5-4
5.7 DETERMINATION OF PLUME OPACITY 5-8
6.0 QUALITY ASSURANCE/QUALITY CONTROL PROCEDURES
AND RESULTS 6-1
6.1 CALIBRATION OF APPARATUS 6-1
6.1.1 Barometers 6-1
6.1.2 Temperature Sensors 6-1
6.1.3 Pilot Tubes 6-1
6.1.4 Differential Pressure Gauges 6-2
6.1.5 Dry Gas Meter and Orifice 6-2
6.2 ON-SITE MEASUREMENTS 6-3
6.2.1 Measurement Sites 6-3
6.2.2 Velocity Measurements 6-5
6.2.3 Flue Gas Sampling 6-5
6.2.4 Moisture 6-5
6.2.5 Method 23/Method 29 6-6
6.3 ANALYSES 6-6
6.3.1 Method 23 Analyses 6-6
6.3.2 Method 29 Analyses 6-9
APPENDIX A PROCESS DATA
APPENDIX B RAW FIELD DATA
Appendix B.I Raw Field Data Baghouse Inlet
Appendix B.2 Raw Field Data Baghouse Outlet
IV
-------
TABLE OF CONTENTS (Concluded)
VOLUME II
APPENDIX C ANALYTICAL DATA
Appendix C.I Analytical Data Method 5 Particulate Matter
Appendix C.2 Analytical Data Method 23 PCDDs/PCDFs
Appendix C.3 Analytical Data Method 29 Multiple Metals
APPENDIX D COMPUTER SUMMARIES
Appendix D.I Computer Summaries Baghouse Inlet Method 23 & 29
Appendix D.2 Computer Summaries Baghouse Outlet Method 9, 23 & 29
APPENDIX E QA/QC DATA AND CERTIFICATIONS
APPENDIX F FIELD TESTING PARTICIPANTS
-------
LIST OF TABLES
VOLUME I Page
TABLE 2.1 EMISSIONS SAMPLING TEST LOG
ASPHALT PLANT "B" - GARY, NC 2-3
TABLE 2.2 PCDDs/PCDFs EMISSIONS SAMPLING AND EXHAUST GAS
PARAMETERS
ROTARY DRUM DRYER - BAGHOUSE INLET
ASPHALT PRODUCTION WITH RAP
ASPHALT PLANT "B" - CARY, NC 2-6
TABLE 2.3 PCDDs/PCDFs CONCENTRATIONS AND EMISSION RATES
ROTARY DRUM DRYER - BAGHOUSE INLET
ASPHALT PRODUCTION WITH RAP
ASPHALT PLANT "B" - CARY, NC 2-7
TABLE 2.4 PCDDs/PCDFs CONCENTRATIONS AND 2378 TOXIC EQUIVALENT
CONCENTRATIONS ADJUSTED TO 7 PERCENT OXYGEN
ROTARY DRUM DRYER - BAGHOUSE INLET
ASPHALT PRODUCTION WITH RAP
ASPHALT PLANT "B" - CARY, NC 2-8
TABLE 2.5 PCDDs/PCDFs EMISSIONS SAMPLING AND STACK GAS
PARAMETERS
ROTARY DRUM DRYER - BAGHOUSE OUTLET
ASPHALT PRODUCTION WITH RAP
ASPHALT PLANT "B" - CARY, NC 2-10
TABLE 2.6 PCDDs/PCDFs CONCENTRATIONS AND EMISSION RATES
ROTARY DRUM DRYER - BAGHOUSE OUTLET
ASPHALT PRODUCTION WITH RAP
ASPHALT PLANT "B" - CARY, NC 2-11
VI
-------
LIST OF TABLES (Continued)
VOLUME I Page
TABLE 2.7 PCDDs/PCDFs STACK GAS CONCENTRATIONS AND 2378 TOXIC
EQUIVALENT STACK
GAS CONCENTRATIONS ADJUSTED TO 7 PERCENT OXYGEN
ROTARY DRUM DRYER - BAGHOUSE OUTLET
ASPHALT PRODUCTION WITH RAP
ASPHALT PLANT "B" - GARY, NC 2-12
TABLE 2.8 PCDDs/PCDFs EMISSIONS SAMPLING AND STACK GAS
PARAMETERS
ROTARY DRUM DRYER - BAGHOUSE INLET
ASPHALT PRODUCTION WITHOUT RAP
ASPHALT PLANT "B" - GARY, NC 2-14
TABLE 2.9 PCDDs/PCDFs CONCENTRATIONS AND EMISSION RATES
ROTARY DRUM DRYER - BAGHOUSE INLET
ASPHALT PRODUCTION WITHOUT RAP
ASPHALT PLANT "B" - GARY, NC 2-15
TABLE 2.10 PCDDs/PCDFs CONCENTRATIONS AND 2378 TOXIC EQUIVALENT
STACK
GAS CONCENTRATIONS ADJUSTED TO 7 PERCENT OXYGEN
ROTARY DRUM DRYER - BAGHOUSE INLET
ASPHALT CONCRETE PRODUCTION WITHOUT RAP
ASPHALT PLANT "B" - GARY, NC 2-16
TABLE 2.11 PCDDs/PCDFs EMISSIONS SAMPLING AND STACK GAS
PARAMETERS
ROTARY DRUM DRYER - BAGHOUSE OUTLET
ASPHALT PRODUCTION WITHOUT RAP
ASPHALT PLANT "B" - GARY, NC 2-18
TABLE 2.12 PCDDs/PCDFs CONCENTRATIONS AND EMISSION RATES
ROTARY DRUM DRYER - BAGHOUSE OUTLET
ASPHALT PRODUCTION WITHOUT RAP
ASPHALT PLANT "B" - GARY, NC 2-19
VII
-------
LIST OF TABLES (Continued)
VOLUME I Page
TABLE 2.13 PCDDs/PCDFs CONCENTRATIONS AND 2378 TOXIC EQUIVALENT
CONCENTRATIONS ADJUSTED TO 7 PERCENT OXYGEN
ROTARY DRUM DRYER - BAGHOUSE OUTLET
ASPHALT CONCRETE PRODUCTION WITHOUT RAP
ASPHALT PLANT "B" - CARY, NC 2-20
TABLE 2.14 PARTICULATE/METALS EMISSIONS SAMPLING
AND INLET GAS PARAMETERS
ROTARY DRUM DRYER - BAGHOUSE INLET
ASPHALT PRODUCTION WITH RAP
ASPHALT PLANT "B" - CARY, NC 2-21
TABLE 2.15 PARTICULATE MATTER CONCENTRATIONS AND
EMISSION RATES
ROTARY DRUM DRYER - BAGHOUSE INLET
ASPHALT PRODUCTION WITH RAP
ASPHALT PLANT "B" - CARY, NC 2-22
TABLE 2.16 METALS CONCENTRATIONS AND EMISSION RATES
ROTARY DRUM DRYER - BAGHOUSE INLET
ASPHALT PRODUCTION WITH RAP
ASPHALT PLANT "B" - CARY, NC 2-23
TABLE 2.17 PARTICULATE/METALS EMISSIONS SAMPLING AND
STACK GAS PARAMETERS
ROTARY DRUM DRYER - BAGHOUSE OUTLET
ASPHALT PRODUCTION WITH RAP
ASPHALT PLANT "B" - CARY, NC 2-26
TABLE 2.18 PARTICULATE MATTER CONCENTRATIONS AND
EMISSION RATES
ROTARY DRUM DRYER - BAGHOUSE OUTLET
ASPHALT PRODUCTION WITH RAP
ASPHALT PLANT "B" - CARY, NC 2-27
TABLE 2.19 METALS CONCENTRATIONS AND EMISSION RATES
ROTARY DRUM DRYER - BAGHOUSE OUTLET
ASPHALT PRODUCTION WITH RAP
ASPHALT PLANT "B" - CARY, NC 2-28
viii
-------
LIST OF TABLES (Continued)
VOLUME I
TABLE 2.20 PARTICULATE/METALS EMISSIONS SAMPLING AND
STACK GAS PARAMETERS
ROTARY DRUM DRYER - BAGHOUSE INLET
ASPHALT PRODUCTION WITHOUT RAP
ASPHALT PLANT "B" - GARY, NC
Page
2-30
TABLE 2.21
PARTICULATE MATTER CONCENTRATIONS AND
EMISSION RATES
ROTARY DRUM DRYER - BAGHOUSE INLET
ASPHALT PRODUCTION WITHOUT RAP
ASPHALT PLANT "B" - GARY, NC
2-31
TABLE 2.22 METALS CONCENTRATIONS AND EMISSION RATES
ROTARY DRUM DRYER-BAGHOUSE INLET
ASPHALT PRODUCTION WITHOUT RAP
ASPHALT PLANT "B" - GARY, NC
2-32
TABLE 2.23
PARTICULATE/METALS EMISSIONS SAMPLING
AND STACK GAS PARAMETERS
ROTARY DRUM DRYER - BAGHOUSE OUTLET
ASPHALT PRODUCTION WITHOUT RAP
ASPHALT PLANT "B" - GARY, NC
2-35
TABLE 2.24 PARTICULATE MATTER CONCENTRATIONS AND
EMISSION RATES
ROTARY DRUM DRYER - BAGHOUSE OUTLET
ASPHALT PRODUCTION WITHOUT RAP
ASPHALT PLANT "B" - GARY, NC
2-36
TABLE 2.25
METALS CONCENTRATIONS AND EMISSION RATES
ROTARY DRUM DRYER-BAGHOUSE OUTLET
ASPHALT PRODUCTION WITHOUT RAP
ASPHALT PLANT "B" - GARY, NC
2-37
IX
-------
LIST OF TABLES (Continued)
VOLUME I Page
TABLE 3.1 PLANT OPERATING CONDITIONS
ASPHALT PLANT "B" - GARY, NC 3-3
TABLE 3.2 ASPHALT MIX SPECIFICATIONS
ASPHALT PLANT "B" - CARY, NC 3-5
TABLE 3.3 FUEL SPECIFICATIONS
ASPHALT PLANT "B" - CARY, NC 3-5
TABLE 3.4 SPECIFICS OF PLANT OPERATION
ASPHALT PLANT "B" - CARY, NC 3-6
TABLE 5.1 SAMPLING LOCATIONS, TEST PARAMETERS, AND
TEST METHODS SUMMARY
ASPHALT PLANT "B"-CARY, NC 5-2
TABLE 6.1 SUMMARY OF TEMPERATURE SENSOR CALIBRATION DATA
ASPHALT PLANT "B" - CARY, NC 6-2
TABLE 6.2 SUMMARY OF PITOT TUBE DIMENSIONAL DATA
ASPHALT PLANT "B" - CARY, NC 6-4
TABLE 6.3 SUMMARY OF DRY GAS METER AND ORIFICE
CALIBRATION DATA
ASPHALT PLANT "B" - CARY, NC 6-5
TABLE 6.4 SUMMARY OF METHOD 237 METHOD 29 FIELD SAMPLING
QA/QC DATA
ASPHALT PLANT "B" - CARY, NC 6-7
TABLE 6.5 SUMMARY OF METHOD 23 STANDARDS RECOVERY
EFFICIENCIES
ASPHALT PLANT "B" - CARY, NC 6-8
TABLE 6.6 SUMMARY OF METHOD 29 ANALYSIS QC DATA
LAB CONTROL SPIKES
ASPHALT PLANT "B" - CARY, NC 6-11
-------
LIST OF TABLES (Continued)
VOLUME I Page
TABLE 6.7 SUMMARY OF METHOD 29 ANALYSIS QC DATA
POST DIGESTION MATRIX SPIKES RUN NO. R-O-M29-1
ASPHALT PLANT "B" - GARY, NC 6-12
TABLE 6.8 METHOD 29 SERIAL DILUTION ANALYSIS QC DATA
RUNNOR-0-M29-1
ASPHALT PLANT "B" - GARY, NC 6-13
TABLE 6.9 METHOD 29 DUPLICATE ANALYSIS QC DATA
RUN NO. R-O-M29-2
ASPHALT PLANT "B" - GARY, NC 6-14
TABLE 6.10 METHOD 29 METHOD BLANK ANALYSIS QC DATA
ASPHALT PLANT "B" - GARY, NC 6-15
TABLE 6.11 METHOD 29 FIELD AND REAGENT BLANK ANALYSIS
QC DATA
ASPHALT PLANT "B" - GARY, NC 6-16
TABLE 6.12 METHOD 29 MERCURY SPIKE ANALYSIS QC DATA
ASPHALT PLANT "B" - GARY, NC 6-17
TABLE 6.13 METHOD 29 MERCURY FIELD BLANK ANALYSIS QC DATA
ASPHALT PLANT "B" - GARY, NC 6-18
XI
-------
LIST OF FIGURES
VOLUME I Page
Figure 1.1 Key Personnel and Responsibility for Testing - Asphalt Plant "B", Gary, NC . 1-3
Figure 1.2 Sampling Locations - Asphalt Plant "B", Gary, NC 1-4
Figure 4.1 Baghouse Inlet Sampling Location - Asphalt Plant "B", Gary, NC 4-2
Figure 4.2 Baghouse Inlet Point Locations - Asphalt Plant "B", Gary, NC 4-3
Figure 4.3 Baghouse Outlet Sampling Location - Asphalt Plant "B", Gary, NC 4-4
Figure 4.4 Baghouse Outlet Point Locations - Asphalt Plant "B", Gary, NC 4-5
Figure 5.1 Method 23 Sample Train Schematic - Asphalt Plant "B" Gary, NC 5-3
Figure 5.2 Method 29 Sample Train Schematic - Asphalt Plant "B", Gary, NC 5-5
Figure 5.3 Method 29 Sample Recovery Scheme (Sample Fractions 1-4)
Asphalt Plant "B", Gary, NC 5-6
Figure 5.4 Method 29 Sample Recovery Scheme (Sample Fraction 5)
Asphalt Plant "B", Gary, NC 5-7
XII
-------
APPENDIX C
ANALYTICAL DATA
-------
Appendix C.I
Analytical Data
Method 5 Particulate Matter
-------
-- /1. .1 *- ••-*
( 7 PACIFIC ENVIRONMENTAL SERVICES, INC.
3708 Mayfair Street. Suite 202
Durham. North Carolina 27707
(919)493-3538
Fax: (919) 493-7779
SAMPLE ANALYTICAL DATA FORM
Plant
^ fortifier
"8"
Run number 1-7$-Q-i
Sample location
Relative humidity ;
Density of acetone (pa)
O,
gf\6AQmSe-
g/ml
Sample
type
Acetone rinse
filter (s)
Sample
identifiable
tlh'Tt
vw-6\3 . m -23
Liquid level marked
and/or container sealed
Acetone rinse container number
Acetone rinse volume (V_,_)
7G7-9
ml
Acetone blank residue concentration (C )
Wa = CaVawPa= <<>
Date and time of wt
Date and time of wt
CLOOOO
Gross wt
Gross wt
O. &OOO
nig
Average gross wt
Tare wt
Less acetone blank wt (W_)
a
Weight of particulate in acetone rinse (m )
Filter (s) container number ggcW VJQ VV-fS
Date and time of wt Q^o5" Gross wt
Date and time of wt Qf?*?^? Iffi^ Gross wt
Average gross wt
IbLrtW t^ fr-~*Z $ F.\W fl^ -fivl Tare wt
Weight of particulate on filter(s) (m~)
Weight of particulate in acetone rinse
Total weight of particulate (m )
Note; In no case should a blank residue >0.01 mg/g or 0.001% of
the weight of acetone used be subtracted from the sample weight.
Remarks
Signature of analyst
Signature of reviewer
r
WASHINGTON. OC. • RESEARCH THIANSLE PARK. NC • LOS ANGELES. CA • CINCINNATI. OH
-------
1 PACIFIC ENVIRONMENTAL SERVICES, INC.
3708 Maytalr Street. Suite 202
Durham, North Carolina 27707
(919) 493-3536
Fax:(919)493-7779
SAMPLE ANALYTICAL DATA FORM
Plant
Sample location
Relative humidity ;
Density of acetone (pa)
Run number
0
Sample
type
Acetone rinse
filter(s)
Sample
identifiable
flu -74
W*ft- V\A -3
Acetone rinse volume (V___) l44T-f
Acetone blank residue concentration (C_)
a a aw a ~^~~
Date and time of wt ^/^/^ To"1? Gross wt
Date and time of wt "l/?6r?3- £)^3T Gross wt
Average gross wt
Tare wt
Less acetone blank wt (W )
a —
Weight of particulate in acetone rinse (in )
r— ~"
Filter(s) container number V^t-ldt (WA">-0\9
Date and time of wt ^/?4f^ IQ&>~ Gross wt
Date and time of wt ^T^*? tfa T Gross wt
Average gross wt
Tare wt
Weight of particulate on filter(s) (mf)
Weight of particulate in acetone rinse
Total weight of particulate (m_)
ml
Ci - O CoO ofa/g
Ci . OOCC pg
WLfc^KF 4i
VO^S^oo V9
\0\.0l9^ Big
Q .Cxyt) mg
6-0246 ^a
C . STZ-A-I- jrfg
0.^43 i*g
0 . 4-S$9 m'a
n.0134 X«
0.01 mg/g or 0.001% of
the weight of acetone used be subtracted from the sample weight.
Remarks
Signature of analyst
Signature of reviewer
WASHINGTON. DC. • RESEARCH TRIANGLE PMW. NC • LOS ANQELES. CA • CMOWMTI. OH
-------
i ,' PACIFIC ENVIRONMENTAL SERVICES, INC.
3708 Maytair Street. Suite 202
Durham, North Carolina 27707
(919) 493-3536
Fax:(919)4837779
SAMPLE ANALYTICAL DATA FORM
Plant
Run number
Sample location
Relative humidity
Density of acetone (p_)
g/ml
Sample
type
Acetone rinse
filter (s)
Sample
identifiable
\d~\c
KV-O?V W-il
Liquid level marked
and/or container sealed
Acetone rinse container number
\A) - IQ
Acetone rinse volume (V )
c|W - - —•—
Acetone blank residue concentration (Ca)
£1
ml
QjQOQO
Wa =
Ca Vaw
Date and time of wt
Date and time of wt
Gross wt
Gross wt
Ufc.fldll
Average gross wt
Tare wt
Less acetone blank wt (Wa)
GL
Weight of particulate in acetone rinse (m,)
T^ | v A
Filter(s) container number
Date and time of wt _
Date and time of wt
103.
ma
. poop
Gross wt
Gross wt
Average gross wt
tVU-UJT F.lW l*-<™ Tare wt
Weight of particulate on filter(s) (m-)
Weight of particulate in acetone rinse
Total weight of particulate (m )
(63.
(65.
/fig
Note; In no case should a blank residue >0.01 mg/g or 0.001% of
the weight of acetone used be subtracted from the sample weight.
Remarks
Signature of analyst
Signature of reviewer
VIA
WASHINGTON. DC • RESEARCH TRIANGLE PARK. NC • LOS ANGELES. CA • CINCINNATI. OH
-------
\
PACIFIC ENVIRONMENTAL SERVICES, INC.
3708 Mayfair Street. Suite 202
Durham, North CareUna 27707
(919)493-3536
Fax:(919)493-7779
SAMPLE ANALYTICAL DATA FORM
r
Plant
Sample location
Relative humidity
Density of acetone (pa)
a,
Run number
- X- JL
a.
Sample
type
Acetone rinse
filter(s)
Sample
identifiable
'Ealfr WM1-
j&g
Note; In no case should a blank residue >0.01 mg/g or 0.001% of
the weight of acetone used be subtracted from the sample weight.
Remarks
•W
AM?,
^cJi IftA
Signature of analyst
Signature of reviewer
WASHINGTON. QC. • RESEARCH TRIANQLE PARK. NC • LOS ANQELES. CA « CMCMNATI. OH
-------
17 PACIFIC ENVIRONMENTAL SERVICES, INC.
3708 Mayfalr Street. Suite 202
Durham. North Carolina 27707
(919)493-3536
Fax:(919)493-7779
SAMPLE ANALYTICAL DATA FORM
Plant
niarr ''£• "
Run number Tl-'^'T-'Z,
Sample location
Relative humidity -
Density of acetone (p )
\(\Ji
tT
Q .
g/ml
Sample
type
Acetone rinse
filter(s)
Sample
identifiable
^_U VYM1
|ftH, \OG*, ^tW N
Liquid level marked
and/or container sealed
-n-
Acetone rinse container number
Acetone rinse volume (V.,,.)
clW ~~ ~~ —
Acetone blank residue concentration (C.
ml
W = C V D = ( fc
* A A £tX*7 ~ SI *
A C* An C&
Date and time of wt
Date and time of wt
) ( 64*0 ) (
o.oooo
Gross wt
Gross wt
Average gross wt
Tare wt
Less acetone blank wt (W )
Weight of particulate in acetone rinse (m )
d
too.
fig
**
6.0QOO
Filter(s) container number
Date and time of wt °i\n.
Date and time of wt
V\M1-
Gross wt
Gross wt
Average gross wt
Weight of particulate on filter(s) (mf)
Weight of particulate in acetone rinse
Total weight of particulate (m )
Note: In no case should a blank residue >0.01 mg/g or 0.001%'of
the weight of acetone used be subtracted from the sample weight.
Remarks
Signature of analyst
Signature of reviewer
VWSHINGION. D.C « RESEARCH TRIANGLE PARK. NC • LOS ANGELES. CA • CINCINNATI. OH
-------
( J PACIFIC ENVIRONMENTAL SERVICES, INC.
3708 Maytair Street, Suite 202
Durham, North Carolina 27707
(919) 493-3536
Fax:(919)493-7779
C
SAMPLE ANALYTICAL DATA FORM
Plant
Sample location
Relative humidity
Density of acetone d
"E"
Run number V, -7^1 -"1 -3
g/»l
Sample
type
Acetone rinse
filter(s)
Sample
identifiable
^0.01 mg/g or 0.001% of
the weight of acetone used be subtracted from the sample weight.
Remarks
\xu
of
Signature of analyst
Signature of reviewer
NWkSMINGtON. O.C • RESEARCH TRIANGLE PARK. NC • LOS ANGELES. C* • CMCINNXn. OH
-------
\
17 PACIFIC ENVIRONMENTAL SERVICES, INC.
3708 Maytair Street. Suite 202
Durham. North Carolina 27707
(919) 493-3536
Fax (919) 493-7779
SAMPLE ANALYTICAL DATA FORM
Plant
Sample location
Relative humidity
Density of acetone (p_)
cl
"B" Run number fl- -7A - ^
g/ml
Sample
type
Acetone rinse
filter(s)
Sample
identifiable
VJ-CL
vu^-cv^
Liquid level marked
and/or container sealed
Acetone rinse container number
Acetone rinse volume (VM_)
ow ~" —~r- L~~—"' ~
Acetone blank residue concentration (C )
cl
|)Jo
*Jl
O-O006
Date and time of wt
Date and time of wt
(63T
Gross wt
Gross wt
(6S.ZICO
e .OQ6Q
o.ccol
7
*g
0.4W
Average gross wt
Tare wt
Less acetone blank wt (W )
a
Weight of particulate in acetone rinse (m )
Filter(s) container number F> \W No tyAQ"3
Date and time of wt ^/7.4nT- t^S^" Gross wt
Date and time of wt flfer ^ 6^0.01 mg/g or 0.001% of
the weight of acetone used be subtracted from the sample weight.
6. COOL
Remarks
Signature of analyst _
Signature of reviewer
WASHINGTON. OR. • RESEARCH TRIANGLE PARK. NC • LOS ANOELE& CA • CINCINNATI. OH
-------
m
>
w
$
METHOD 5
TARE HEIGHT
Project Numbers
Item Weiahedi
Dat
R.H. (%)
•MIMHM
Temi
(•F)
Std. Ht,
Analyst
ID Number
j(VL£
3
•AMkMHM^^H
V^W
Field Sample
Number
1st
2nd
a/.sfl
!6U9tS
ifiS
^
flj.6016
VMBMlMXMMMBMB^
Q7-30^3
3rd
4th
5th
Final
Ht. (g)
Tare
Ht. (g)
'V J-,
SI
t5§3^
X
1ST.
Difference
?i
-------
f- J
METHOD 5
TARE WEIGHT
8
m
C»
m
s
>>
Project Humbert
Item Weiahedi
Date
R.H. (%)
Temp. (*F)
Std. Wt.
Analyst
ID Number
- COT
-004-
^a
on-
^7A
si
Field Sample
Number
(?dv T-
t-
0 •
1st
6.363T-
.36(2,
0-
twj
2nd
0.30(0
Q 44Q-?
^
0
ZM
3rd
4th
5th
Final
Wt. (g)
0-3608
6 .
. 36?^
6
A.3Bl.(
6
Tare
Difference
(ng)
^
fl«l
en
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-------
1
5
I
1
1
f»
!
>roject Numl
Date
R.H. (%)
Temp. (*F)
Std. Wt.
Analyst
ID Number
VfPtTt-&i$
>er« ^4G-O64
Field Sample
Number
$1
~^4-^
0 *&&
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1st
644*1?
6448<<
6.4441
o
6.<
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4
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(nig)
'
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1
-------
W
a:
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-1
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i
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in
D Number
0^4-
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-------
II
O
m
m
^
M
METHOD 5
FINAL WEIOIT
Project Number:
Item Weighed:
F.lU
Date
R.H.
Std. Wt,
Analyst
ID Number
m-s
Field Sample
Number
1st
lo-'T
2nd
l£O. OOOO
3rd
4th
')•
5th
Final
Wt. (g)
Tare
Ht. (q)
Difference
(mg)
JMt-
tffe
<-\6.'X>°4
l(6.^<30fr
^b&
661?
\off. tcffa
U/T
.Lt
0.5144-
6. 4468
ca^ VA^W^. Uctf-<;L-^
iU,>s T
^n:
-------
Appendix C.2
Analytical Data
Method 23 PCDDs/PCDFs
-------
CASE NARRATIVE
Analysis of Samples for the Presence of
Polychlorinated Dibenzo-p-Dioxins and Dibenzofurans by
High-Resolution Chromatography / High-Resolution Mass Spectrometry
Method 23 (6/93)
Date:
Client ID:
P.O. Number:
TLI Project Number:
September 18, 1997
Pacific Environmental Services
104-98-0019- & -0020
43085
This report should only be reproduced in full. Any partial reproduction of this report requires permission from
Triangle Laboratories, Inc.
Rev. 05/08/97
Triangle Laboratories, Inc.
801 Capitola Drive P.O. Box 13485 \
Durham, NC 27713-4411 Research Triangle Park, fie 27709-3485
919-544-5729 Fax # 919-544-5491
1
-------
Triangle Laboratories, Inc. September 18, 1997
Case Narrative 43085
Overview
Eight M23 samples were received from Pacific Environmental Services in good condition
on September 03, 1997 at 6.0 °C. The samples were stored in a refrigerator at 4°C. The
samples and any associated QC samples were extracted and analyzed according to
procedures described in the Triangle Laboratories' Data User's Manual (Rev. 12/92-HK-
2-AH-2/93). Any particular difficulties encountered during the samples' handling by
Triangle Laboratories will be discussed in the QC Remarks section below. Results
reported relate only to the items tested.
Quality Control Samples
A laboratory method blank, identified as the TLIM23 Blank, was prepared along with the
samples.
Laboratory control spike (LCS) and laboratory control spike duplicate (LCSD) samples
were extracted and analyzed along with the samples. A report summarizing the analyte
recoveries and relative percent differences for these samples is included in the data
package.
Quality Control Remarks
This release of this particular set of Pacific Environmental Services analytical data by
Triangle Laboratories was authorized by the Quality Control Chemist who has reviewed
each sample data package individually following a series of inspections/reviews. When
applicable, general deviations from acceptable QC requirements are identified below and
comments are made on the effect of these deviations upon the validity and reliability of the
results. Please consult Triangle Laboratories' Data User's Manual for further details.
Specific QC issues associated with this particular project are:
Sample Preparation Laboratory: As per client request, the impinger samples are to be
archived and not analyzed.
Samples O-M23-1, O-M23-2, I-M23-1, I-M23-2, and I-M23-3 had larger than
normal XAD traps, requiring several Soxhlet apparatus.
Mass Spectrometry: None
Data Review: Most of the samples exhibit severe matrix-related problems. There are
shifts in the retention times and severe quantitative interferences. As a result, several
samples have elevated detection limits, out-of-ratio labeled standards, and labeled
-------
Triangle Laboratories, Inc. September 18, 1997
Case Narrative 43085
standards that are below the QC criteria of 10:1 signal-to-noise. The final reports have
been flagged accordingly. Please refer to the data flags for further details and possible
effects on data quality.
Other Comments:. Any analytes found in the TLIM23 Blank are detected at a level equal
to or less than the Target Detection Limit. This level of contamination is acceptable as per
TLI guidelines.
Sample Calculations:
Analyte Concentration
The amount of any analyte is calculated using the following expression.
Ao * Qp
Amt{0)=
Ap*RRF(0)*W
Where:
Amt (o) is the amount of a given analyte,
AC is the integrated current for the characteristic ions of the analyte,
Ap is the integrated current of the characteristic ions of the corresponding internal
standard,
Qp represents the amount of internal standard added to the sample before extraction,
RRF(o) is the mean analyte relative response factor from the initial calibration (ICal) and,
W is the sample weight or volume (W = 1 for M23)
The amount is expressed in nanograms (ng) or picograms (pg).
Detection Limits
The detection limit reported for a target analyte that is not detected or presents an analyte
response that is less than 2.5 times the background level is calculated by using the
following expression. The area of the analyte is replaced by the noise level measured in a
region of the chromatogram clear of genuine GC signals multiplied by an empirically
determined factor. The detection limits represent the maximum possible concentration of
a target analyte that could be present without being detected.
-------
Triangle Laboratories, Inc. September 18, 1997
Case Narrative 43085
2 * 2.5 * (F * H) * QP
DL(a)=
Ap*RRF(a) *W
Where:
DL(a) is the estimated detection limit for a target analyte,
2.5 is the minimum response required for a GC signal,
F is an empirical number that approximates the area to height ratio for a GC signal. This
number is 3.7 for both the DB-5 GC column and the DB-225 GC column,
H is the height of the noise
Ap is the integrated current of the characteristic ions of the corresponding internal
standard,
Qp represents the amount of internal standard added to the sample before extraction,
RRF(0) is the mean analyte relative response factor from the initial calibration (ICal) and,
W is the sample weight or volume
The detection limit is expressed in nanograms (ng) or picograms (pg).
Other sample calculations may be found in the Triangle Laboratories Data User's Manual.
Data Flags
In order to assist with data interpretation, data qualifier flags are used on the final reports,
as discussed in Triangle Laboratories' Method 23 Data User's Manual. Please note that all
data qualifier flags are subjective and are applied as consistently as possible. Each flag has
been reviewed by two independent Chemists and the impact of the data qualifier flag on
the quality of the data discussed above. The most commonly used flags are:
A 'B' flag is used to indicate that an analyte has been detected in the laboratory method
blank as well as in an associated field sample. The 'B' flag will be used only when the
concentration of analyte found in the sample is less than 20 times that found in the
associated blank. This flag denotes possible contribution of background laboratory
contamination to the concentration or amount of that analyte detected in the field sample.
Under Triangle Laboratories guidelines, a laboratory blank is acceptable if the tetra-
-------
Triangle Laboratories, Inc. September 18,1997
Case Narrative 43085
through hepta-CDD/CDF levels are all below the target detection limits (TDLS) or if the
contamination levels are less than 5% of the levels detected in the associated field samples.
If these conditions are satisfied or if the blank is unable to be reextracted, the
interpretation of the contamination levels relative to the samples should be as follows: 1)
analyte quantitations should be considered valid if the level of blank contamination is less
than five percent of the level detected in the field sample, 2) analyte quantitations should
be considered estimated if the analyte level in the sample is five to twenty times the level
of the analyte in the blank, or 3) analytes whose level in a sample is the same as or less
than five times the level detected in the associated blank should be considered present
likely due to laboratory contamination and not native to the sample.
An 'E' flag is used to indicate that an PCDF peak has eluted at the same time as the
associated diphenyl ether (DPE) and that the DPE peak intensity is ten percent or more of
the PCDF peak intensity. Total PCDF values are flagged 'E' if the total DPE contribution
to the total PCDF value is greater than ten percent. All PCDF peaks that are significantly
influenced by the presence of DPE peaks are quantitated with EMPC values, regardless of
the isotopic abundance ratio. These EMPC values are most likely overestimated due to
the DPE contribution to the peak area.
An 'I' flag is used to indicate labeled standards have been interfered with on the GC
column by coeluting, interferent peaks. The interference may have caused the standard's
area to be overestimated. All quantitations relative to this standard, therefore, may be
underestimated.
A 'PR' flag is used to indicate that a GC peak is poorly resolved. This resolution problem
may be seen as two closely eluting peaks without a reasonable valley between the peak
tops, overly broad peaks, or peaks whose shapes vary greatly from a normal distribution.
The concentrations or amounts reported for such peaks are most likely overestimated.
A 'Q' flag is used to indicate the presence of QC ion instabilities caused by quantitative
interferences. Affected analytes may be overestimated or underestimated as a result of this
interference. A peak is flagged 'Q' only if it is affected by a QC ion deviation greater than
20% full scale as determined relative to the labeled standard against which it is
quantitated. Total PCDF/PCDF quantitations will be flagged 'Q' if the interferences affect
ten percent or more of the total PCDD/PCDF peak areas.
An 'RO' flag is used to indicate that a labeled standard has an ion abundance ratio that is
outside of the acceptable QC limits, most likely due to a coeluting interference. This may
have caused the percent recovery of the standard to be overestimated. All quantitations
versus this standard, therefore, may be underestimated.
A 'U' flag is used to indicate that a specific (2,3,7,8-substituted) isomer cannot be
resolved from a large, coeluting interferent GC peak. The specific isomer is reported as
-------
Triangle Laboratories, Inc. September 18,1997
Case Narrative 43085
not detected as a valid concentration/amount cannot be determined. The calculated
detection limit, therefore, should be considered an underestimated value.
A 'V flag is used to indicate that, although the percent recovery of a labeled standard may
be below a specific QC limit, the signal-to-noise ratio of the peak is greater than ten-to-
one. The standard is considered reliably quantifiable. All quantitations derived from the
standard are considered valid as well.
By our interpretation, the analytical data in this project are valid based on the guidelines
of EPA Method 23 (6/93) and Triangle Laboratories' Method 23 Data User's Manual.
Any specific QC concerns or problems have been discussed in the QC Remarks section of
this case narrative with emphasis on their effect on the data. Should Pacific
Environmental Services have any questions or comments regarding this data package,
please feel free to contact our Project Scientist, Amy Boehm, at (919) 544-5729, ext.
268.
For Triangle Laboratories, Inc.,
Report Preparation Quality Control
Sheila A. Lee-Lewis 1
Report Preparation Chemist Report Preparation Chemist
The total number of pages in the data package is :
-------
TRIANGLE LABORATORIES, INC.
LIST OF CERTIFICATIONS AND ACCREDITATIONS
ENVIRONMENTAL
American Association for Laboratory Accreditation. Certification pending. Certificate
Number 0226-01. Accreditation for technical competence in Environmental Testing.(Including
Waste Water, Sol/Haz Waste, Pulp/Paper, and Air Matrices) Parameters are AOX/TOX,
Volatiles, Pesticides, PCB's. BNA's, and Dioxin/Furan. Method 1613 for Drinking Water.
State of Alabama, Department of Environmental Management Expires December 31, 1997.
Laboratory I.D. #40950. Dioxin in drinking water.
State of Alaska, Department of Environmental Conservation. Expires December 21, 1997.
Certificate number OS-00397. Dioxin in drinking water.
State of Arizona, Department of Health Services. Expires May 26, 1998. Certificate
#AZ0423. Drinking Water for Dioxin, Dioxin in WW and S/H Waste.
State of Arkansas, Department of Pollution Control and Ecology. Expires February 18,
1998. Pulp/paper, soil, water, and Hazardous Waste for Dioxin/Furan; AOX/TOX.
State of California, Department of Health Services. Expires August 31, 1999. Certificate
#1922. Selected Metals in Waste Water; Volatiles, Semi-volatiles, and Dioxin/furan in WW and
Sol/Haz Waste. Dioxin in drinking water.
State of Connecticut, Department of Health Services. Expires September 30, 1997.
Registration # PH-0117. Dioxin in drinking water.
Delaware Health and Social Services. Expires December 31, 1997. Certificate #NC 140.
Dioxin in drinking water.
Florida Department of Health and Rehabilitative Services. Expires June 30, 1998.Dioxin in
DW. Drinking Water ID HRS# 87424. Metals, Extractable Organics (GC/MS), Pesticides/PCB's
(GC) and Volatiles (GC/MS) in Environmental Samples. Environmental water ID HRS#
E87411.
Hawaii Department of Health. Expires March 1, 1998. Dioxin in drinking water. "Accepted"
status for regulatory purposes .
Revised 9/18/97 RM
Printed 9/18/97
-------
Idaho Department of Health and Welfare. Expires November 30, 1997. Dioxin in drinking
water.
State of Kansas, Department of Health and Environment Expires January 31, 1998.
Environmental Analyses/Non potable Water and Solid and Hazardous Waste. Method 1613
for drinking water. ID #'s - Drinking water and/or pollution control - E-215. Solid or Hazardous
Waste-E-1209.
Commonwealth of Kentucky, Department for Environmental Protection. Expires December
31, 1997. ID#90060. Dioxin in drinking water.
Maryland Department of Health and Mental Hygiene. Expires September 30, 1997.
Certification #235. Drinking water by Method 1613A.
State of Michigan, Department of Public Health. Expires March 31, 1998. Drinking water by
Method 1613.
Mississippi State Department of Health. No expiration date.. Dioxin in drinking water.
Montana Department of Health and Environmental Services. Expires December 31, 1997.
Dioxin in drinking water.
State of New Jersey, Department of Environmental Protection and Energy. Extended by
state. Temporary certificate until December 31,1997. ID #67851. BNAs and Volatiles. Dioxin in
drinking water.
State of New Mexico, Environment Department. Certification pending. Dioxin in drinking
water.
New York State Department of Health. Expires June 30, 1997. ID #11026. Environmental
Analyses of non-potable Water, Solid and Hazardous Waste. Method 1613 in DW.
State of North Carolina, Department of Environment Health and Natural Resources
Expires August 31, 1999. Certificate # 37751. Dioxin in drinking water.
State of North Carolina, Department of Env onment, Health, and Natural Resources,
Division of Environmental Management Expires December 31, 1997. Certificate # 485.
Metals, pesticides & PCBs, semi-volatiles and volatiles; TCLP.
North Dakota State Department of Health and Consolidated Laboratories. Expires
December 31, 1997. Certificate # R-076. Effective October 4, 1993. Dioxin in drinking water.
Revised 9/18/97 RM
Printed 9/18/97 5
-------
Oklahoma Department of Environmental Quality. Expires October 31, 1997. Laboratory
#9612. Dioxin by 1613A, 8290 and 8280.
State of South Carolina, Department of Health and Environmental Control. Expires June
30, 1997. Certificate number #99040001 (drinking water). Expires August 31, 1999. Certificate
number #99040002 (other parameters). Dioxin/Furans, BNA, Volatiles, and PCBs/pesticides
under Clean Water Act, 2,3,7,8-TCDD for Drinking Water, and Organic extractables for Solid
and Hazardous Waste.
State of Tennessee. Department of Environment and Conservation. Expires February 5,
1999. ID #02992. Method 1613 Drinking water only.
U.S. Department of Agriculture Soil Permit Expires September 30, 2001. Permit No. S-
3790. Under the authority of the Federal Plant Pest Act, permission is granted to receive
foreign soil samples for use in laboratory analysis.
U.S. Army Corps of Engineers. Expires November 30, 1997. Validated to perform methods
8280 & 8290 for Lockbourne Landfill Site Investigation, Defense Distribution Depot Projects,
and assorted projects for the USAGE North Pacific Division Laboratory.
U.S. EPA Region V. Expires November 14, 1999. Dioxin in drinking water.
U.S. EPA Region VIII, for the State of Wyoming. Expires November 13, 1997. Dioxin in
drinking water.
State of Utah, Department of Health. Expires December 31, 1997. Certificate Number E-166.
Certification for the following parameters: Semi-Volatiles and Volatiles under RCRA; Volatiles
under Clean Water Act; Dioxin/furans by Method 8280; Drinking water for Dioxin by Method
1613; Metals including Mercury and Microwave Digestion.
Commonwealth of Virginia, Department of General Services, Division of Consolidated
Laboratory Services. Expires June 30, 1998. ID # 00341. Dioxin in drinking water.
State of Washington, Department of Ecology. Expires September 1998. Lab Accreditation
Number C067. Scope of Accreditation applies to water analyses for Polychlonnated Dibenzo-
p-dioxins and Polychlonnated Dibenzofurans, BNA Extr (Semivolatile) Organics and Purgeable
(Volatile) Organics.
State of Washington, Department of Health. Expires April 30, 1998. Dioxin in drinking water.
Labl.D. 129
State of West Virginia, Department of Health. Expires December 31, 1997. Certificate No.
9923(C). Dioxin in drinking water.
Revised 9/18/97 RM
Printed 9/18/97
-------
State of Wisconsin, Department of Natural Resources. Expires August 31, 1998.
Laboratory ID Number 999869530. Certification for the following categories of Organics:
Purgeable, Base/Neutral, Acid, PCBs, and Dioxin. Expires November 14, 1999. Laboratory ID
999869530. Dioxin in drinking water.
PHARMACEUTICAL
Drug Enforcement Agency (DEA). Expires November 30, 1997. Registration number
RT01195835. Controlled substance registration for schedules 1,2,3,3N,4,5.
N.C. Department of Human Resources. Expires October 31, 1997. Registration number NC-
PT 0000 0031. North Carolina controlled substances registration. Application submitted for
renewal.
Food & Drug Administration (FDA) Registration. Expires June 1998. ID #'s 001500
1053481. Annual registration of drug establishment. Annual registration of drug establishment.
OTHER
Clinical Laboratory Improvement Amendments (CLIA) Registration. Expires May 30, 1999.
ID # 34D0705123. Department of Health & Human Services, Health Care Financing
Administration.
U.S. EPA Large Quantity Hazardous Waste Generator. No expiration date. EPA ID
#NCD982156879. Permit indicates that the laboratory is a large generator of hazardous waste.
North Carolina Radioactive Materials License. Expires April 30 1998. License No. 032-
0954-1. License authorizes the licensee to receive, acquire, own, possess, transfer, import and
use such radioactive materials as designated.
North Carolina General License for Radiation Protection. No. expiration date. License No.
032-875-OG. The general license applies only to radioactive material contained in devices
which have been manufactured and labeled in accordance with specific requirements.
Revised 9/18/97 RM
Printed 9/18/97
10
-------
DOCUMENT
CONTROL
Triangle Laboratories, Inc.
801 Capitola Drive P.O. Box 13485
Durham, NC 27713-4411 Research Triangle Park, NC 27709-3485
919-544-5729 Fax * 919-544-5491
11
-------
PACIRC ENVIRONMENTAL SERVICES. INC.
Central Park WeSTJ
5001 South Miami Boulevard, P.O. Box 12077
Research Triangle Park, North Carolina 27709-2077
(919)941-0333 FAX: (919) 941-0234
Chain of Custody Record
Project Num
s4 13-004
Project Name
US EPA EMC Asphalt Cement, ^t/. Asphalt Vt^ur "g
Samplers:
Dickerson, McDonald. Thompson, Hamiliton
Date
8/27/97
8/27/97
8/27/97
8/27/97
8/27/97
8/27/97
8/27/97
8/27/97
8/27/97
8/28/97
8/28/97
8/28/97
8/28/97
8/28/97
8/28/97
8/28/97
8/28/97
8/28/97
Time
0945
0945
0945
0945
0945
0945
0945
0945
0945
0845
0845
0845
0845
0745
0745
0745
0745
0745
Field Sample ID
l-M23-1-AceATol
I-M23-1 -Filter
I-M23-1-XAD
l-M23-1-lmp
O-M23-1-Ace/Tol
O-M23-1 -Filter
O-M23-1-XAD
O-M23-1-lmp(1/2)
O-M23-1-lmp(2/2)
l-M23-2-Ace/Tol
l-M23-2-Filter
I-M23-2-XAD
l-M23-2-lmp
O-M23-2-Ace/Tol
O-M23-2-Filter
O-M23-2-XAD
O-M23-2-lmp (1/2)
O-M23-2-lmp (2/2)
Relinquished by: (Signature)
Relinquished by: (Signature)
Relinquished by: (Signature)
<
Dateffime
AT-/1
Datemme
Date/Time
Sample Description
Acetone / Toluene Rinse
Filter
XAD Trap
BH Impinger Contents
Acetone/ Toluene Rinse
Filter
XAD Trap
BH Impinger Contents
BH Impinger Contents
Acetone / Toluene Rinse
Filter
XAD Trap
BH Impinger Contents
Acetone/ Toluene Rinse
Filter
XAD Trap
BH Impinger Contents
BH Impinger Contents
Received by: (Signature)
Received by: (Signature)
Received for lab by: (Signature)
Analysis Requested
PCDD
-
•
•
.
•
•
.
•
*
•
•
.
PCDF
•
-
•
•
-
•
-
•
*
*
•
•
Relinquished by: (Signature)
Relinquished by: (Signature)
Date/Time
Datemme
REMARKS
Remarks
ARCHIVE
ARCHIVE
ARCHIVE
ARCHIVE
ARCHIVE
ARCHIVE
Received by: (Signature)
Received by: (Signature)
|Page: of
-------
PACIFIC ENVIRONMENTAL SERVICES. INC.I
Central Park West
5001 South Miami Boulevard. P.O. Box 12077
Research Triangle Park, North Carolina 27709-2077
(919) 941-0333 FAX: (919) 941-0234
Chain of Custody Record
Project Num
8413-004
Project Name
US EPA EMC Asphalt Cement, . Asphalt TiAMg
Samplers:
Dickerson, McDonald, Thompson, Hamilton
Date
8/29/97
8/29/97
8/29/97
8/29/97
8/29/97
8/29/97
8/29/97
8/29/97
8/29/97
8/29/97
8/29/97
8/29/97
8/29/97
8/29/97
8/29/97
8/29/97
8/29/97
8/29/97
Time
0745
0745
0745
0745
0745
0745
0745
0745
0745
0745
0745
0745
0745
0745
0745
0745
0745
0745
Field Sample ID
-M23-3-Ace/Tol
l-M23-3-Filter
-M23-3-XAD
l-M23-3-lmp
O-M23-3-Acem>l
O-M23-3-Filter
O-M23-3-XAD
O-M23-3-lmp (1/2)
O-M23-3-lmp (2/2)
O-M23-FB-Ace/Tol
O-M23-FB-Filter
O-M23-FB-XAD
O-M23-FB-lmp
M23-RB - Acetone
M23-RB - Filters
M23-RB-XAD
M23-RB-Toluene
M23-RB - Water
Relinquished by: (Signature)
7£/&>^^
-------
Custody Seal : Present/Intact Sample Seals: Present
Chain of Custody : Present Container...: Intact
Sample Tags : Absent
Sample Tag Numbers: Not Listed on Chain of Custody
SMO Forms : N/A '
Ice Chest ICE PACKS Temp 6.0 C
TLI Project Number 43085 ,
Client: PES03 - Pacific Environmental Servic
Date Reoelved 09/03/97 1 By /&l)
\ i ITfi //*
I f ff ^/ ~
Carrier and Number | TIM MCDONALD
1 Book I
1 1
1 "I 1
CLI Number Client Sample ID Matrix) To LJ
nR/H:CPM. Client COC ID • Location j Date/
|
\B To STORAGE) To LAB
'Init Date/Init Date/Init
i
181-55-1A 0-M23-1 -FILTER FILTERJ L,$( \
0-M23-X-FILTER C02 j ^^ \1|CI?P»
LB1-5S-1B 0-M23-1-XAD XAD|
0-M23-1-XAD C02 |
181-55-1C 0-M23-1-IMP IMP)
O-H23-1-IMP C02 j
1
it I -55 -ID 0-M23-1-IMP IMP)
0-M23-1-IMP C02 j
j
1
181-5S-1E O-M23-1-ACB/TOL ACE/TOL|
- 0-M23-1-ACB/TOL C02 j I
1
I • ' { ' 1
1 1
L11-5S-2A O-M23-2-FILTER FILTER) \
^ O-M23-2-FILTER C02 j I
I 1
1
1*1-55-28 0-M23-2-XAD XAD|
~~ O-M23-2-XAD C02 j
j
L81-5S-2C 0-M23-2-IMP FH/RINSE)
O-M23-2-IMP C02 j
j
1
[81-5S-2D O-M23-2-IMP BH/RINSE)
O-M23-2-IMP C02 j
p81-S5-2E O-M23-2-ACE/TOL IMPINGERJ
•» 0-M23-2-ACE/TOL C02 j
L81-S5-3A O-M23-3-FILTER FILTER)
' O-M23 -3 -FILTER C02 |
1
1
.81-55-3B 0-M23-3-XAD XAD)
f- O-M23-3-XAD C02 j
j
L81-5S-3C 0-M23-3-IMP FH/RINSEJ (
0-M23-3-IMP C02 j I
I \
L81-55-3D 0-M23-3-IMP BH/RINSE) \j
O-M23-3-IMP C02 j
1
/
\
/l^-
i
1
\
h&D
/
•
y^&j'
i
\ s~^
/
i
J
To STORAGE
Date/Init
| To LAB
Date/Init
'
'
To STORAGE
Date/Init
t
| To LAB
Date/Init
To STORAGE
Date/Init
| DISPOSED
Date/Init
Receiving Remarks:
Archive Remarks:
=Form Revised 05/27/1997 -- Page 1 OF 3=
-------
Custody Seal i Present/Intact Sample Seals: Pr
Chain of Custody : Present Container. . . : In
Sample Taga i Absent
Sample Tag Numbers: Not Listed on Chain of Custody
SMO Forma : N/A '
LB LABORATORIES, IKC. -- LOO IN RECORD/CHAIN OF
esent TLI
tact Cli
U *
Project Number 43085 , | Book
ent": PES03 - Pacific Environmental Service* j
| 181
i
Date Received | 09/03/97 *Ytf /~liSl*~ £ \V*3*
i i fa &f7r4s&2s& \
Ice Chest ICE PACKS Temp 6.0 C Carrier and Number j TIM MCDONALD ^ j 55
i i i
TLI Number Client Sample ID 4 Matrix
nR/H-CPM Client COC ID * Location
181-5S-3B 0-M23-3-ACE/TOL IMPINGER
s. O-M23-3-ACE/TOL C02
181-SS-4A O-M23-FB-FILTER FILTER
) O-M23-FB-FILTER C02
181-55-4B 0-M23-FB-XAD XAD
> 0-M23-FB-XAD C02
181-S5-4C O-M23-FB-IMP FH/RINSE
0-M23-FB-IMP C02
181-S5-4D 0-M23-FB-ACE/TOL BH/RINSE
1 O-M23-FB-ACE/TOL C02
1S1-55-SA 1-M23-1-FILTER FILTER
> 1-M23-1-FILTER C02
181-SS-SB 1-M23-1-XAD XAD
/ 1-M23-1-XAD C02
181-55-5C 1-M23-1-IMP FH/RINSE
1-M23-1-IMP C02
181-5S-5D 1-M23-1-ACE/TOL BH/RINSE
' 1-M23-1-ACE/TOL C02
181-5S-6A 1-M23-2-FILTER FILTER
1-M23-2-FILTER C02
181-55-6B 1-M23-2-XAD XAD
1-M23-2-XAD C02
181-55-6C 1-M23-2-IMP FH/RINSE
1-M23-2-IMP C02
181-55-6D 1-M23-2-ACB/TOL BH/RINSE
" lrM23-2-ACE/TOL C02
181-55-7A 1-M23-3-FILTER FILTER]
1-M23-3-FILTER C02 |
| To LAB
Date/Init
L/
1/V/
I
I
* I
I
/
To STORAGE | To LAB
Date/Init j Date/Init
j
f* >^>
SuSfD
/t
1
1
1
j
>&\>
* 1
\hs?D
^\}JiV
( i
i
i
i
i 1
\i
\
|>0^)
1
1
1
j
^icf^v
\i A ^
\
To STORAGE
Date/Init
1
....
1 1
| To LAB
Date/Init
1
1 1
To STORAGE
Date/Init
t
1
1
| To LAB
Date/Init
1 1
| 1
To STORAGE
Date/Init
•
....
| 1
DISPOSED
Date/Init
, - — I
I 1
1 1
1
Receiving Remarks:
Archive Remarks:
=Form Revised OS/27/1997 -- Page 2 OF 3=
-------
•TRIANGLE LABORATORIES, INC. -- IAAS in Km_umj/I.IUMII vr
Custody Seal : Present/Intact Sample Seals: Present
Chain of Custody : Present Container...: Intact
Sample Tags : Absent
Sample Tag Numbers: Not Listed on Chain of Custody
SMO Forms : N/A '
TLI Project Number 43085 ,
Client: PES03 - Pacific Environmental Services
1 1 SI /
Date Received | 09/03/97 1 &{///? /^ss&Z***.
i i iS*\ 1 J^r *^
1 Book
1
| 181
^
^ 1 P«9«
i // wi • i
Ice Chest ICE PACKS Temp 6.0 C Carrier and Number | TIM MCDONALD " V 1 55
PL! Number Client Sample ID t Matrix
nR/H:CPM. Client COC ID. .. * Location
L81-SS-7B 1-M23-3-XAD XAD
1-M23-3-XAD C02
181-5S-7C 1-M23-3-IMP FH/RINSE
1-M23-3-IMP C02
L81-5S-7D 1-M23-3-ACE/TOL BH/RINSE
1-M23-3-ACE/TOL C02
L81-55-8A . M23-RB-FILTER FILTER
M23-RB-FILTER C02
LB1-5S-8B M23-RB-XAD XAD
M23-RB-XAD C02
181-5S-8C M23-RB -ACETONE FH/RINSE
M2 3 -RB- ACETONE C02
L81-SS-8D M23-RB-HATER BH/RINSE
M23-RB-HATER C02
L81-55-8B M23-RB-TOLUENE IMPINGER
> M2 3 -RB- TOLUENE C02
1 To LAB To STORAGE
Date/Init Date/Init
I
LD tf
M/
\
\
J
/
V
| To LAB
Date/Init
£D
,
w&
To STORAGE
Date/Init
| To LAB
Date/Init
To STORAGE
Date/Init
I
•»
| To LAB
Date/Init
To STORAGE
Date/Init
| DISPOSED
Date/Init
Receiving Remarks:
Archive Remarks:
=Form Revised 05/27/1997 -- Page 3 OF 3=
-------
TRIANGLE LABORATORIES, INC.
SAMPLE TRACKING AND PROJECT MANAGEMENT FORM
ADMINISTRATIVE INFORMATION
TLI Proj#: 43085- Samples: 8 TurnAround.: 14 Day(s)
Prod Code: D23061 Matrix.: M23Train Hold Time..: 30 Day(s)
DetectLim: 0.05 ng Type...: A Start Date.: 09/03/97
Recvd..: 09/03/97 Ship By....: 09/15/97
DWL Due Dt.: 09/10/97
Analyte List.: tetra-octa PCDDs/PCDFs
Method : Method 23:Tetra-Octa (Tol Combined)
Client Proj..: S413-004
Client : Pacific Environmental Services (PES03)
P.O. No : 104-98-0019 & -0020 Collect Dt/Tm: SeeCOC
Contact : Frank Meadows Phone : 919-941-0333
Proj . Mgr. . . . : Amy J. Boehm Fax : 919-941-0234
Sample Origin: NC
SPECIAL INSTRUCTIONS / QA REQUIREMENTS
Prep Project: 03803 Prespike Standard: USF-CS
Prespike Amount..: 4.Ong
Extraction Exp...: 09/26/97
-------------------------- REPORTING REQUIREMENTS
Reporting Format: Report Option II
See MILES for Instructions/Communications.
Completed by: _ _ _ DATE:
Reviewed by: _ ^£2 _ DATE: T/T^/er (PMGT0197
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713 Printed:417:21 09/02/WE
Phone: (919) 544-5729 • Fax: (919) 544-5491 IY
-------
Date: 09/04/97
rime: 20:29
Sample
• crd TLI_Number.. Customer.Sample.Id
000 TLI Blank TLI M23 Blank
001 181-55-1ABE 0-M23-1
002 1B1-S5-2ABE 0-M23-2
003 181-55-3ABE 0-M23-3
004 181-55-4ABD O-M23-FB
005 181-55-5ABD I-M23-1
006 181-55-6ABD I-M23-2
007 181-55-7ABD I-M23-3
008 181-55-8ABDE M23-RB
009 TLI LCS TLI LCS
010 TLI LCSD TLI LCSD
••• End of Report •**
TRIANGLE LABORATORIES, INC.
Wet Lab MM5/PUF Observations
Project: 43085
Page: 1
F.
No
0
1
1
1
1
4
4
4
1
0
0
XAD
Color
WHITE
WHITE
WHITE
WHITE
WHITE
WHITE
WHITE
WHITE
WHITE
WHITE
WHITE
Filter Glass Wool PUF
. . Color. . Color Color. . .
WHITE/BRWN WHITE/YELL
WHITE/BRWN WHITE/YELL
WHITE/BRWN WHITE/YELL
WHITE WHITE
WHITE/BRWN WHITE
WHITE/BRWN WHITE
WHITE/BRWN WHITE
WHITE WHITE
. . Odor . . .
NONE
OIL
OIL
OIL
NONE
OIL
OIL
OIL
NONE
NONE
NONE
Air
. . Q . No . Entered . By
03803 ADKINS
03803 ADKINS
03083 ADKINS
03803 ADKINS
03803 ADKINS
03803 ADKINS
03803 ADKINS
03803 ADKINS
03804 ADKINS
ADKINS
ADKINS
Date.... Time..
09/04 20:29 F
09/04 20:29 F
09/04 20:29 F
09/04 20:29 F
09/04 20:29 F
09/04 20:29 F
09/04 20:29 F
09/04 20:29 F
09/04 20:29 F
09/04 20:29 F
09/04 20:29 f
. S
-------
TRIANGLh LJ\bUtlAiUriiC£> ur n i r, UNO.
PROJECT COMMUNICATION TRACKIN'G FORM
TL1 Project Number:
page _ of .
Use this form to record all exchanges of information between production units as well as personnel
handling -this project. Decisions, corrective actions and recommendations must also appear on this
tracking document
ate
Name
-
Comment / Decision /
Resolution / Action / Observation
? \tfdZ5-
ffl iL | ^T ^y
n t< i< *•
*^\. *V— *^ < * f •* \l ^^
^ • •
' PESOS-Pacific Environmental Services .
0-M23-1-FTLTER
R r-o j ©o-t. : -4- 3 O © 5
1 a 1 — 55 — 1 A
PES03-Pacific Environmental Services
O-M23-1-ACE/TOL
1 Q I —55— 1 E
PESOS-Pacitic Environmental Services
O-M23-1-XAD
1 © 1 — 5 5— 1 B
/
"PES03-P"acif"ic tnvironmentai services
O-M23-2-XAD
F» r~o j e»c-t. : -4-3OS5
1 ©1 — 5 5 —2B
c tnvironmental Services
0-M23-2-ACE/TOL
J^o-t. : 4-3OQ5
e1 —55 —2E
c hnvironmentai services
O-M23-2-FILTER
Rt-ojoo-t. : -4-3OQ5
1©1—55—2A
-------
PROJECT COMMUNICATION TRACKING FORM
page .Z. of
TL1 Project Number:
. —- • -^•~~-^——
Use this form to record all exchanges of information between production units as well as personnel
' handling -this project. Decisions, corrective actions and recommendations must also appear on this
tracking document
Date
Name
Comment / Decision / Resolution / Action / Observation
=================================== ~ ~
PES03-Pacific Environmental Services
0-M23-3-ACE/TOL
P r- o j & G ^ : -4- 3 O © 5
1 © 1 —55—SEE
PtSQ3-Pacific Environmental Services
0-M23-3-FILTER . '
R r-o j ©G-fc. : -4-3 O © 5
1 ©1 — 5 5 — 3 A
PES03-Pacitic Environmental Services
0-M23-3-XAD
Rr-oJ^Gt : 4-3O©5
1 ©1 —55 —SB
PES03-Pacific Environmental Services
0-M23-FB-XAD
\
1 e 1 — 55 — -4-B
"PES03-Pacific Environmental Services
0-M23-FB-FIITER
Pr-ojj^o-t. : -4-3OQ5
1 e 1 — 55 — ^-A
PES03-Pacitic Environmental Services
O-M23-FB-ACE/TOL
Rr-ojoo-t : -4-3OQ5
1 e 1 — 55 — 4-D
Environmental Services
1-M23-1-FILTER
R r~ o j o o t : A- 3 O Q 5
1e1—55—5A
PESOS^-Pacific Environmental SeTvToes
1-M23-1-ACE/TOL
Pr-oj^ot : -4-3OQ5
1 ©1 —55— 5D
PES03-Pacific Environmental Services
1-M23-1-XAD
Pr-oj^G-t : -4-3OQ5
1 ©1 —55 —SB
20
-------
TRIANGLE LABORATORIES OF RTP, INC.
PROJECT COMMUNICATION TRACKING FORM
page _£__ of v3
TL1 Project Number:
Use this form to record all exchanges of information between production units as well as personnel
handling -this project. Decisions, corrective actions and recommendations must also appear on this
tracking document
ate
Name
Comment / Decision / Resolution / Action / Observation
i r ic. mv 1 1 onmenta i services
1-M23-2-FILTER
©c-t- : -4-3O85
1 — 55 — ©A
c bnvironmentai Services
1-M23-2-XAD
eo-t : -£ 3 O Q 5
1 e 1 — 55— ©B
PES03-Pacific Environmental Services
1-M23-2-ACE/TOL
F1 t-oj eot : -4-3O Q 5
1 e 1 — 5 5— ©D
F» r-o
PESO3-Pacific Environmental Services ,
1-M23-3-XAD 1
1 — 5S— 7
Bwlr
PES03-Pacific Env"ironmentaT~Serv1ces
1-M23-3-FILTER
Rr-ojeso-t : -4-3OQ5
1 e 1 —55— 7A
>
M
( 4>
PESOS-Pacific Environmental Sec vices" »
M23-RB-XAD L
1 e 1 — 55 — 8B
PES03-Pacific Environmental
M23-RB-FILTER
1 e 1 —55— ©A
"PES03-Pacif1c Environmental Services
M23-RB-ACETONE
oo-t. = 4-3OQ5
1 — 55 — 8C
-------
TRIANGLE LABORATORIES, INC. PAGE 1 OF 2
Dioxin Sample Preparation Tracking & Management Form
Project: 43085 Client: Pacific Environmental Services (PES03)
Solvent (s) /Acid(s) : /0/U^TO
IS Spike: 40 jil oonc: 0.1000 ng/ul •"
SS Spike: ul cone: . nq/ul
MS Spike: 0 ul cone: 0.0000 ng/ul
LCS Spike: 0 pi cone: 0.0000 ng/ul
OPR Spike: 20 ul cone: _0.01 ng/ul
| | TLI / | GROSS | SAMPLE
|Stt.crd| SAMPLE / CLIENT | HEIGHT | SIZE
| | ID / SAMPLE ID | Before After | g / ml
| I TLI Blank | | I
|000 | TLI M23 Blank ] | | f
| | 181-55-1ABE | | |
|001 | 0-M23-1 | | | J
^ , /*-" , TO- ;
525V I 1 S'Z.VSS | *\£3(\-h i
u<>F x. i use #* i JJSF-/4 i
7. / oZ/^| ij. / ij_ i3$\ $_ / £. 1^1 1
°l /cri ft~l | 3_ /oV /£7 1 £. / ^. /f£7 1
ii = 2s i d_ = lL i JL = L5_ i
•O'/ ng/ul 1 0.6( nq/Mi | fl./ nq/Bi |
VO ul 1 tO ul 1 40 ul 1
1 Chemis
1 Spike
" ID
_ / _ /_ " Exp
/ / " Dat
: " Tim
nq/j»l * Con
ul " Vol
4^. ( . | | /\JJi/ 1 t'yes/Y
/ yfrs^ ^-t^
^ I i * i
| | 181-55-2ABE | | | | , I 1 - x*~N "' 1
1002 | 0-M23-2 | | | I |iXL , , . | 1 /Sj4jX 1
1 _y \/rrr —
| | 181-5S-3ABE | | I 1 / /? 1 1 x-~N 1
|003 1 0-M23-3 | | | | | /_ / .1, , 1 1 fr\ LJJ^ 1
| | 181-55-4ABD | | I 1 X , ^ 1 \ * -"~\ 1
|004 | 0-M23-FB | | III O^-" ~~ ' 1 1 r\l-L£__ \
+ . .....L_+ +. ../OJrrrr...
|Any Le
| ye i/r
|Any L€
[.Y.y.
|AnyJL.
1 yea/i
|Any |L
1 yes/
| | 181-55-5ABD
|005 |
I-M23-1
|AnyL
| | 181-S5-6ABD
|006 |
I-M23-2
|Any'tL
I ye^/
181-55-7ABD
|007
I
I-M23-3 |
|Any|l
| | 181-55-8ABDE
1008 |
|
M23-RB |
|Any
| TLI LCS
|009
|
TLI LCS |
s.C
,
|Any\I
Gross weight of sample container + sample before/after aliquot removal.
Comments:
-
r
(jof
Initials :
Date:
7,
I Initials of both SPIKER AND OBSERVER must be entered.
XXXXX - Gross Height not provided for HATER Sampl
REV 05/27/97 (PSTMF
-------
Project: 43085
Solvent (a)/Acid(s)
Lot Numbers:
IS Spike: 40 Ml
SS Spike: Ml
MS Spike: 0 Ml
LCS Spike: 0 ul
OPR Spike: 20 M!
| TLI
;#.crd| SAMPLE /
] ID /
| TLI LCSD
no |
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
TRIANGLE LABORATORIES, INC. PAGE 2 OF 2 )
Dioxin Sample Preparation Tracking & Management Form \
Client: Pacific Environmental Service* (PESO 3) 1
: "Talut^vA- / / Method: Method 23:Tetra-Octa (Tol Combined) Matrix: fffl^ J
^7^1 )B 1 1 Extraction Date: 7 1 ^ I^H \
\
cone: . ng/ul 1 Ln 1 LT\ | 6-A 1 (Chemist 1
cone: 0.0000 na/ul 1 $2^1 1 52.3^3 | 52.35'5 1 1 Spike * t
cone: 0.0000 na/nl 1 OS P J. | UST A\X 1 USF'A 1 1 " ID 1
cone: _0.01_ ng/Ml I _Z / °2/3& 'J: / Z7/JL3! H. 1 £ /$ \ _ / _ /_ 1 ' Expiri
.. . . «. + + 9 /^V/^71 ^ 1 OV I<1'^ Q 1 (a 1^1 \ 1 1 \ 'Date 1
/ | GROSS | SAMPLE | _ll = ^ I {!_ = H 1 JL'i5L 1 = 1 ' Tin« (
CLIENT 1 WEIGHT 1 SIZE I O- ) ng/(il I O-Olnq/ul | 0-i na/ul 1 ng/ul 1 * Conc.l
SAMPLE ID | Before After | a / ml | ^O ul 1 ^Cj ul 1 'fo ul 1 tfl 1 " Vol. 1
1 i 1 1 , ., 1 ^ /-'- 1 ^-X 1 lAnyLeft*
TLI LCSD | | | [ | X. . C_ . L^ ' ^ ' | /SlW^ | |fl%)no |
+ nr. + ^Urrr^- + .. >^.- «.
III! 1 1 1 lAnyLeft)
I 1 1 I 1 1 1 1 yes/no j
1 1 1 1 1 1 1 lAnyLeftj
1 ! 1 1 1 1 1 1 yes/no |
1 1 ! 1 1 1 1 |AnyLeft|
1 1 1 1 1 1 1 1 yes/no 1
1 I 1 1 1 1 1 |AnyLeft|
1 1 I 1 ! 1 1 1 y~/no 1
1 1 1 1 1 I I |Any Leftj
1 1 1 1 1 1 1 1 yes/no |
1 1 1 I 1 1 I |AnyLeft|
1 1 1 1 1 1 1 1 y*s/no 1
1 1 1 1 1 1 1 |Any Left)
lilt 1 1 I 1 yes/no i
1 1 1 1 1 1 1 (Any Left
1 1 1 1 1 1 1 1 yes/no
till | | | |Any Left
1 1 1 1 1 1 1 1 yes/no
Gross weight of sample container + sample before/after aliquot removal.
Comments:
Initials:
Initials of both SPIKER AND OBSERVER must be entered.
XXXXX » Gross Height not provided for HATER Samples.
-.l-.-REV OS/27/97 (PSTOF 7)--
23
-------
PAGE 1 OF 2
TRIANGLE LABORATORIES, INC.
DIOXIN SAMPLE EXTRACTION and CLEANUP TRACKING FORM
TLI Project No.: 43085
Ext Stt.crd
TLI Number
Enter the procedure number below into the box at the top of each column to signify the step performed.
Initial and date each sample for each numbered procedure performed.
%'jfa'l
tt PROCEDURE DETAJ£S (circle)
^JX EXTRACT I ON ON OFF <£oxhla& / Jar / Sep Funnel / Steam Dist / Cont LL / ASE / Waste Dilut:
•(JP SPIKE AFTER EXTRACTION '*''"
£^U)ADD TRIDECANE /'
f ^\f ROTOVAP 4 OtnL
5) COMBINE _._
ffP DIVIDE / LIPID DETERMINATION 20%/80V (SOV/SOVJ) 5mL/20mL Other_
SOLVENT EXCHANGE—"— Q
i CLEANUP// ,4^>^X6c/1a^-vvw^SP~TGT^ / DSP 225 / DSP 115 / DSP 215 / DSP 267 / Other
> TRANSFER
10) ADDITIONAL CLEANUP
11) FINAL TRANSFER
Mod. DSP 260 / DSP 225 / DSP 115 / DSP 215 / DSP 267 / Other
Comments:
-Rev 06/24/97 (PSTMF 4
-------
PAGE 2 OF 2
TRIANGLE LABORATORIES, INC.
DIOXIN SAMPLE EXTRACTION and CLEANUP TRACKING FORM
TLI Project No.: 43085
Ext S#.crd and
TLI Number
i
Enter the procedure number below into the box at the top of each column to signify the step performed.
Initial and date each sample for each numbered procedure performed.
i PROCEDURE DETAILS (circle)
EXTRACTION ONJ^OFF_ / DSP 225 / DSP 115 / DSP 215 / DSP 267 / Other
/fp TRANSFER
10) ADDITIONAL CLEANUP
11) FINAL TRANSFER
5mL/20mL Other
Mod. DSP 260 / DSP 225 / DSP 115 / DSP 215 / DSP 267 / Other
Comments:
«Rev 06/24/97 (PSTM? 41 •
25
-------
PAGE 1 OF
TRIANGLE LABORATORIES, INC.
Transfer Chain-of-Custody Form
Project 43085
Transfer From: DWLH5 To: DMS5
Initials. . Date Time. . .
Released by: JL& __2./JL/_£Z /? ; C>~0
Accepted by: / / :
1
MILES. ID
43085-
43085-
43085-
43085-
43085-
43085-
43085-
43085-
43085-
43085-
43085-
-000
-001
-002
-003
-004
-005
-006
-007
-008
-009
-010
TLI
TLI
181
181
181
181
181
181
181
181
TLI
TLI
No
Blank
-55-1ABE
-55-2ABE
-55-3ABE
-55-4ABD
-55-5ABD
-55-6ABD
-55-7ABD
-55-8ABDE
LCS
LCSD
Gust .Id
TLI M23 Blank
O-M23-1
O-M23-2
O-M23-3
O-M23-FB
I-M23-1
I-M23-2
I-M23-3
M23-RB
TLI LCS
TLI LCSD
+ - XfrCOC (Rev 11/01/94)
Additional comments or instructions:
26
-------
PAGE 1 OP 1
TRIANGLE LABORATORIES, INC.
Transfer Chain-of -Custody Form
Project 43085
Transfer From: DWLH5
To: DMS5
Initials..
Date
Time...
Released by:
Accepted by:
MILES.ID,
43085-
43085-
43085-
43085-
43085-
43085-
43085-
43085-
43085-
43085-
43085-
-000
-001
-002
-003
-004
-005
-006
-007
-008
-009
-010
TLI NO Cust. Id,
TLI
181-
181-
181-
181-
181-
181
181
181
TLI
TLI
Blank
-55-1ABE
-55-2ABE
-55-3ABE
-55-4ABD
-55-5ABD
-55-6ABD
-55-7ABD
-55-8ABDE
LCS
LCSD
TLI M23 Blank
0-M23-1
O-M23-2
0-M23-3
0-M23-FB
I-M23-1
I-M23-2
I-M23-3
M23-RB
TLI LCS
TLI LCSD
Additional comments or instructions:
-XfrCOC (Rev 11/01/94) —
27
-------
PAGE 1 OF 1
I
| Method: Method 23:Tetra-Octa (Tol Combined)
| Required Detection Limit: 0.05 ng
TRIANGLE LABORATORIES. INC.
HR GC/HRMS ANALYSIS
(PROJECT: 4308S
I
SAMPLE INFORMATION
1ST COLUMN
2ND COLUMN
RS Cone
20 ill 9 100.0
I I TLI / | GC/MS FILENAME (CONFIRM (CONFIRM El LENAME^ I USF-RS (USF-RS (ANALYSIS
|S#.crd| SAMPLE ID / CLIENT (.COLUMN: 0^)5 | I COLUMN: {/D dloO (VOLUME (INIT. (COMMENTS
| / SAMPLE ID | | | ISOLN ID (DATE |
Spike File: SPX23704
Amt cf Extract: ««0%
--REV 03/07/95 (PSTMF
-------
Kim uuy
Instrument ID
Column Type
Column ID
Plot Name
Ini. Vol.
Acquisition
Signature
G/C
Date
Filename
Date
Time
Project #
Sample*
No.
Client Sample ID
Syr
332
"rr
Operalor/Oala
Comments'
7V/
V
/73'i
V
727
m
TI-.
TM
D
ILL
tLLL
tA-lAC
Z
b 4
\/
J
\
L
\v
r/W(/rms/hrrunlog doc (02/05/97)
CO
ConCal Due:
ConCalDue:
94
Page:
-------
•*
r J i"j \ | ' '' •
Transcribed from chromatographic data
Dated initials required
MvMAjafloons'hrrunlog.doc (02/05/97)
/••*
\^0^-
ConCal Due: _ / •"
ConCal Due:
Pane*
-------
Run Log
Instrument ID Column Type Column ID
Plot Name Ini. Vol. Acquisition
T&JL 2-£/ ff>U/$-L.
?^z-??z^
Signature
G/C
?>/?Xf^
Date
* Transcribed from chromatographic data
** Dated initials required
sfvr1/qa/forms/hrrunlog doc (02/05/97)
CO
ConCal Due:
ConCal Due:
It'.*2-
9G
Page:
-------
Triangle Laboratories, Inc.
Run Log
Instrument ID Column Type Column ID Plot Name
Inj. Vol. Acquisition
cJhjLxQ EPMS 2.
/(ail. /^Kx^^-H^t
' Signature f^~
Q/C
'*///,-
'Date
* Transcribed from chromatographic data
•* Dated initials required
•rvr1/qa/forms/hrrunk)fl doc (02/05/97)
CO .
ConCalDue:
ConCalDue:
5'-c/z.
97
-------
•ftgfe Laboratories, inc.
Run Log
Instalment ID
Column Type
Column ID
Plot Name
Ini. Vol.
O.o ^
Acquisition
Signature
G/C
Date
* Transcribed from chromatographic data
** Dated initials required
srvrl/qg/dyms/hrruntog doc (02/05/97)
ConCalDue:
ConCalDue:
Dano*
99
-------
Triangle Laboratories, Inc.
Run Log
Instrument ID Column Tvpe Column ID Plot Name
^»0 p DPI tW G££0*ni Tt-f
Ini. Vol. Acquisition QIC
u^ l/aft*
Signature Date
Transcribed from chromatographic data
Dated initials required
(02/05/97)
ConCal Due:
ConCal Due:
-------
Run Log
Instrument ID Column Type Column ID
"•? 0 ? ^ & 7 1 *" £} k- £ 4 1 "!>
Plot Name !' Inj. Vol. Acquisition
' — ^s
1 M'vA L< — .
1 Signature
G/C
\)&T. L \"
W,,/i-v
Date
Filename
Dale'
Time*
Project #
Sample*
No.
Client Sample ID
Syr
332
Operator/Date
Comments*
t s'
3AiM.
i.i
ft*
ML
Kl
1.
I
T,
1,
_iL
\ 3
s
i
I
^
/
yn^ Vu '!>
* Transcribed from chromatographic data
** Dated initials required
srvr1/qa/forms/hrrunlog doc (02/05/97)
CO
Ul
ConCal Due:
ConCal Due:
Page:
81
-------
SAMPLE
DATA
Triangle Laboratories, Inc.
801 Capitola Drive P.O. Box 13485
Durham, NC 27713-4411 Research Triangle Park, NC
919-544-5729 Fax * 919-544-5491
-------
TRIANGLE LABORATORIES OF RTP, INC. Page 1
Sample Result Summary for Project 43085 09/18/97
Method 8290X Full Screen Analyses (DB-5)
Data File S975815 S975866 S975867 S975868
Sample ID TLI M23 Blank O-M23-1 0-M23-2 0-M23-3
Units ng ng ng ng
Extraction Date 09/04/97 09/04/97 09/04/97 09/04/97
Analysis Date 09/11/97 09/13/97 09/13/97 09/13/97
Instrument S S S S
Matrix XAD M23Train M23Train M23Train
Extraction Type Soxhlet Soxhlet Soxhlet Soxhlet
Analytes
2378-TCDD (0.005) (0.09) (0.07) (0.01)
12378-PeCDD (0.006) (0.1) (0.09) (0.01)
123478-HxCDD (0.006) (0.1) (0.1) (0.02)
123678-HxCDD (0.005) (0.1) (0.1) (0.02)
123789-HxCDD (0.005.) (0.1) (0.1) (0.02)
1234678-HpCDD 0.02 (0.2) (0.2) (0.03)
OCDD 0.05 (0.5) (0.6) (0.10)
2378-TCDF 0.006 (0.08) (0.05) (0.006)
12378-PeCDF (0.004) (0.09) {0.24} E (0.01)
23478-PeCDF (0.004) (0.09) (0.07) (0.01)
123478-HxCDF (0.005) (0.09) (0.09) (0.01)
123678-HxCDF (0.003) (0.07) (0.07) (0.01)
234678-HxCDF (0.004) (0.09) (0.08) (0.01)
123789-HxCDF (0.005) (0.1) {0.24} Q,E (0.01)
1234678-HpCDF 0.02 (0.1) (0.2) (0.02)
1234789-HpCDF (0.007) (0.2) (0.2) (0.03)
OCDF 0.03 (0.4) (0.4) (0.07)
TOTAL TCDD (0.005) (0.09) (0.07) (0.01)
TOTAL PeCDD (0.006) {0.53} {1.0} (0.01)
TOTAL HxCDD (0.006) (0.1) 0.44 (0.02)
TOTAL HpCDD 0.02 (0.2) {1.0} (0.03)
TOTAL TCDF 0.006 0.15 (0.05) (0.006)
TOTAL PeCDF (0.004) (0.09) {0.41} E {0.02}
TOTAL HxCDF (0.004) (0.09) {0.46}E (0.01)
TOTAL HpCDF 0.02 (0.2) {0.36} (0.02)
Other Standards Percent Recovery Summary (% Rec)
37C1-TCDD 94.6 79.3 100 101
13C12-PeCDF 234 101 Q 71.8 93.1 93.4
13C12-HXCDF 478 87.3 73.8 94.3 Q 85.0
13C12-HXCDD 478 81.6 64.4 V 85.6 Q 83.2
13C12-HpCDF 789 78.6 78.7 116 Q 86.7
Other Standards Percent Recovery Summary (% Rec)
13C12-HxCDF 789 69.4 74.3 Q 58.2 Q 84.8
13C12-HxCDF 234 73.3 92.3 73.7 Q 94.6
Internal Standards Percent Recovery Summary (% Rec)
13C12-2378-TCDF 105 Q 137 88.1 114
13C12-2378-TCDD 74.6 145 90.2 95.4
13C12-PeCDF 123 94.4 Q 160 RO 82.1 Q,RO 91.9
13C12-PeCDD 123 101 Q 177 102 100
13C12-HxCDF 678 73.5 124 81.0 Q 103
13C12-HxCDD 678 83.2 122 77.6 Q 92 2
13C12-HpCDF 678 64.0 91.2 47.2 Q 64 7
13C12-HpCDD 678 71.5 88.5 53.2 Q 63.8
13C12-OCDD 73.1 60.5 29.8 Q 31.6
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713 Printed-16-26 09/1
Phone: (919) 544-5729 • Fax: (919) 544-5491
-------
TRIANGLE LABORATORIES OF RTF, INC.
Sample Result Summary for Project 43085
Method 8290X Full Screen Analyses (DB-5)
Page 2
09/18/97
Data File
Sample ID
Units
Extraction Date
Analysis Date
Instrument
Matrix
Extraction Type
Analytes
2378-TCDD
12378-PeCDD
123478-HxCDD
123678-HxCDD
123789-HxCDD
1234678-HpCDD
OCDD
2378-TCDF
12378-PeCDF
23478-PeCDF
123478-HxCDF
123678-HxCDF
234678-HxCDF
123789-HxCDF
1234678-HpCDF
1234789-HpCDF
OCDF
TOTAL TCDD
TOTAL PeCDD
TOTAL HxCDD
TOTAL HpCDD
TOTAL TCDF
TOTAL PeCDF
TOTAL HxCDF
TOTAL HpCDF
S975833
0-M23-FB
ng
09/04/97
09/11/97
S
M23Train
Soxhlet
S975834
I-M23-1
ng
09/04/97
09/11/97
S
M23Train
Soxhlet
S975835
I-M23-2
ng
09/04/97
09/11/97
S
M23Train
Soxhlet
S975843
I-M23-3
ng
09/04/97
09/11/97
S
M23Train
Soxhlet
B
B
B
{0.009}
0.04
0.02 Q
0.03
0.03
0.03
0.09
0.02
0.04
0.04
O.Q3
0.03
0.03
0.03
{0.03} B
0.02
0.03
{0.009}
0 .04
0.09
0.04
0.02
0.08
0.11
0.02
B
(0.06)
(0.2)
(0.2)
(0.2)
(0.2)
(0.3)
9.7
(0.05)
(0.09)
(0.09)
(0.1)
(0.1)
(0.1)
(0.2)
(0.2)
(0.2)
(0.3)
(0.06)
(0.2)
(0.2)
{0.35}
{0.18}
0.47
(0.1)
(0.2)
Other Standards Percent Recovery Summary (% Rec)
37C1-TCDD 95.6 102
13C12-PeCDF 234 89.4
13C12-HXCDF 478 83.1
13C12-HxCDD 478 72.6 Q
13C12-HpCDF 789 67.8 V
102
92.1
117
89.9
110
Q
Q
Q
Other Standards Percent Recovery Summary (% Rec)
13C12-HXCDF 789 69.7 80.6 Q
13012-HxCDF 234 81.5 76.4 Q
Internal Standards Percent Recovery Summary (% Rec)
13C12-2378-TCDF 75.7
13C12-2378-TCDD 71.5
13012-PeCDF 123 75.4
13C12-PeCDD 123 86.9
13C12-HxCDF 678 81.3
13C12-HXCDD 678 76.5
13C12-HpCDF 678 75.9
13C12-HpCDD 678 87.9
13C12-OCDD 87.6
72.8
.3
.6
73.
50
45.4
65.4
70.9
56.0
59.6
55.8
Q
Q
Q
Q
Q
Q
(0.03)
(0.06)
(0.1)
(0.09)
(0.09)
(0.2)
8.2
(0.02)
(0.04)
(0.04)
(0.06)
(0.05)
(0.06)
(0.07)
(0.1)
(0.1)
(0.4)
(0.03)
(0.06)
(0.10)
(0.2)
0.17
0.33
(0.06)
{0.26}
102
87.4
100
90.2
84.3
49.8
53.8
45.4
50.6
36.1
35.5
56.9
49.5
32.2
30.0
17.5
V,Q
V,Q
N
B
B
(0.005)
(0.009)
(0.01)
(0.01)
(0.01)
0.14
16.2
0.01
(0.005)
(0.005)
0.02
(0.006)
{0.006}
(0.008)
0.04 B
(0.02)
(0.05)
(0.005)
(0.009)
0.02
0.34
0.01
{0.01}
0.03
0.04
103
93.4
112
99.8
75.7
54.2
73.5
63.3
58.5
56.9
57.2
64.5
58.0
35.3
29.8
16.0
V
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 16:26
-------
TRIANGLE LABORATORIES OF RTF, INC. Page 3
Sample Result Summary for Project 43085 09/18/97
Data File
Sample ID
Units
Extraction Date
Analysis Dace
Instrument
Matrix
Extraction Type
Analytes
2378-TCDD
12378-PeCDD
123478-HxCDD
123678-HxCDD
123789-HxCDD
1234678-HpCDD
OCDD
2378-TCDF
12378-PeCDF
23478-PeCDF
123478-HxCDF
123678-HxCDF
234678-HxCDF
123789-HxCDF
1234678-HpCDF
1234789-HpCDF
OCDF
TOTAL TCDD
TOTAL PeCDD
TOTAL HxCDD
TOTAL HpCDD
TOTAL TCDF
TOTAL PeCDF
TOTAL HxCDF
TOTAL HpCDF
Method 82 9 OX
S975844
M23-RB
ng
09/04/97
09/11/97
S
M2 3 Train
Soxhlet
(0.004)
(0.005)
(0.005)
0.006
0.007
0.03 B
0.05 B
(0.003)
(0.004)
{0.005}
0.03
0.01
0.01
(0.003)
0.05 B
{0.008}
0.05 B
{0.007}
{0.01}
0.01
0.04
(0.003)
0.007
0.07
0.07
Full Screen Analyses (DB-5)
S975831
TLI LCS
ng
09/04/97
09/11/97
S
XAD
Soxhlet
0.36
1.8
1.8
1.8
1.8
1.7
3.4
0.36
2.0
1.8
1.7
1.7
1.6
1.5
2.1
1.5
2.7
S975832
TLI LCSD
ng
09/04/97
09/11/97
S
XAD
Soxhlet
0.36
1.9
1.7
1.8
1.9
1.8
3.6
0.37
1.9
1.9
1.7
1.8
1.7
1.8
1.8
1.6
2.8
Other Standards Percent Recovery Summary (% Rec)
37C1-TCDD 105
13C12-PeCDF 234 95.0
13C12-HxCDF 478 89.0
13C12-HxCDD 478 87.7
13C12-HpCDF 789 97.8
Other Standards Percent Recovery Summary (% Rec)
13C12-HxCDF 789 75.8 72.3 75.4
13C12-HxCDF 234 79.3 76.2 77.5
Internal Standards Percent Recovery Summary (% Rec)
13C12-2378-TCDF 68.5
13C12-2378-TCDD 61.5
13C12-PeCDF 123 67.5
13C12-PeCDD 123 69.2
13C12-HxCDF 678 75.6
13C12-HXCDD 678 . 69.2
13C12-HpCDF 678 60.9
13C12-HpCDD 678 66.8
13C12-OCDD 60.2
{Estimated Maximum Possible Concentration}, (Detection Limit)
64.9
62.6
65.3
69.4
72.8
73.1
58.4
64.5
56.7
65.4
60.9
64.9
66.7
72.8
70.3
62.5
67.1
60.2
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 16:26
-------
TRIANGLE LABORATORIES OF RTP, INC.
Sample Result Summary for Project 43085
Method 23X (DB-225)
Page 1
09/18/97
Data File
Sample ID
Units
Extraction Date
Analysis Date
Instrument
Matrix
Extraction Type
Analytes
2378-TCDF
P973852
TLI M23 Blank
P973854
I-M23-3
P973861
0-M23-FB
ng
09/04/97
09/12/97
P
XAD
Soxhlet
ng
09/04/97
09/12/97
P
M23Train
Soxhlet
ng
09/04/97
09/13/97
P
M23Train
Soxhlet
(0.03)
(0.03)
Internal Standards Percent Recovery Summary (% Rec)
13C12-2378-TCDF 67.4 53.9
(0.05)
70.9
(Detection Limit).
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 16:14 09/1 j
-------
TRIANGLE LABORATORIES. INC.
LAB CONTROL SPIKE RECOVERY ANALYSIS AND COMPARISON
Project: 43085
Matrix: XAD
Method: Modified 23
ID:
I some r
!378-TCOD
2378-PeCDD
123478-HxCDO
123678-HxCDD
123789-HxCOO
1234678-HpCDO 0
5CDD 0
2378-TCDF 0
12378-PeCOF
23478-PeCDF
123478-HxCDF
23678-HxCDF
234678-HxCDF
123789-HxCOF
1234678-HpCDF 0
1234789-HpCOF
DCDF 0
SO: Not Detected
4A: Not Applicable
[..]: EMPC Value
S975815
TLI M23 Blank
Samp le
(ng)
ND
NO
NO
ND
ND
.02
.05
.006
NO
ND
ND
ND
NO
ND
.02
ND
.03
Processed By:
S975831
ID: TLI LCS
With Spike
(ng)
0.36
1.8
1.8
1 .8
1.8
1.7
3.4
0.36
2.0
1 .8
1 .7
1.7
1.6
1 .5
2.1
1 .5
2.7
.3L-/«.,
S975832
Percent
Recovery
89.5
91.7
87.5
89.1
89.4
84.5
84.9
88.6
101
91.1
85.3
84.2
80.0
76.7
102
77.2
68.0
•tj
ID: TLI
Spike
(ng)
0.36
1.9
1.7
1.8
1.9
1.8
3.6
0.37
1.9
1.9
1 .7
1.8
1.7
1.8
1 .8
1.6
2.8
Date:
LCSD
Dup Percent
Recovery
89.1
93.6
87.4
. 90.4
94.9
87.7
88.7
89.9
94.7
95.0
86.3
87.8
83.5
90.4
90.6
80.6
70.2
09/18/97
Relative
Percent
Difference
0.45
2.05
0.11
1.45
5.97
3.72
4.38
1.46
6.44
4.19
1.74
4.19
4.28
16.4
11 .8
4.31
3.18
MILES 4.15.00
GRY_PSUM v1 .01
ercent Recovery QC Limits: 70 to 130 percent.
elative Percent Difference QC Limits: +/- 20 percent.
ote: Method 23 does not address spiked samples. Triangle Labs
uses Method 8290 control limits as advisory guidelines.
ominal Spike Levels (ng):
TCDD/TCDF..: 0.4 ng
PeCDD/PeCOF: 2.0 ng
HxCDO/HxCDF: 2.0 ng
HpCDD/HpCOF: 2.0 ng
OCDD/OCDF..: 4.0 ng
41
-------
TLI Project: 43085
Client Sample: TLI M23 Blank
Method 23 PCDD/PCDF Analysis (a)
Analysis File: S975815
Client Project:
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
S413-004
XAD
TLI Blank
1.000
n/a
DB-5
Date Received:
Date Extracted:
Date Analyzed:
Dilution Factor:
Blank File:
Analyst:
II
09/04/97
09/11/97
n/a
S975815
HLM
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPX23704
SF56117
S975814
n/a
n/a
n/a
to&ytes^ ,-^m^
2,3,7,8-TCDD
1,2,3,7,8-PeCDD
1,2,3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
1,2,3,4,6,7,8-HpCDD
1,2,3,4,6,7,8,9-OCDD
2,3,7,8-TCDF
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
1,2,3,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
1,2,3,4,6,7,8,9-OCDF
S*^ ">*'-•
Total TCDD
Total PeCDD
Total HxCDD
Total HpCDD
Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF
%*$fttat (ng>
ND
ND
ND
ND
ND
0.02
0.05
0.006
ND
ND
ND
ND
ND
ND
0.02
ND
0.03
Amt (ng)
ND
ND
ND
0.02
0.006
ND
ND
0.02
DL EMPC
0.005
0.006
0.006
0.005
0.005
0.004
0.004
0.005
0.003
0.004
0.005
0.007
Number DL EMPC
0.005
0.006
0.006
1
1
0.004
0.004
1
fiaifo fit £tegs
1.07 32:01 ~~
0.84 34:33
0.85 20:25
1.18 31:11
0.76 34:39
Flags
—
Page 1 of 2
X237 J>SR V2.00. LARS «.U
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed 13:58
0942
-------
TLI Project: 43085
Client Sample: TLI M23 Blank
Method 23 PCDD/PCDF Analysis (a)
Analysis File: S975815
trtternarstandards
13C12-2,3,7,8-TCDF
13C.2-2,3,7,8-TCDD
13C,2-l,2,3,7,8-PeCDF
13C,2-l,2,3,7,8-PeCDD
13C12-l,2,3,6,7,8-HxCDF
13C,2-l,2,3,6,7,8-HxCDD
13C,2-l,2,3,4,6,7,8-HpCDF
13C,2-l,2,3,4,6,7,8-HpCDD
13CP-1,2,3,4,6,7,8,9-OCDD
Surrogate Standards (Type A)
37CL,-2,3,7,8-TCDD
13C,2-2,3,4,7,8-PeCDF
13C,2-l,2,3,4,7,8-HxCDF
13Ci2-l,2,3,4J.8-HxCDD
13Ci2-l,2,3,4,7,8,9-HpCDF
Alternate Standards (Type A)
13C,2-l,2,3,7,8,9-HxCDF
13C12-2,3,4,6,7,8-HxCDF
Recovery Standards
13C12-1,2,3,4-TCDD
13C12-l,2,3,7,8,9-HxCDD
Amt (ng)
4.2
3.0
3.8
4.1
29
3.3
2.6
2.9
5 8
AmL (ng)
3.8
4.0
3.5
3 3
3 i
Amt (ng) :;
2.8
2.9
% Recovery
105
74.6
94.4
101
73 5
83.2
64.0
71.5
77 i
% Recovery;
94.6
101
87.3
91 f.
78 f\
|J:pi Recovery
69.4
73.3
QC Limits
40%- 130%
40%- 130%
40%- 130%
40%-130%
/inoji.i^n^
40%- 130%
25%- 130%
25%- 130%
QC Limits
70%- 140%
70%- 140%
70%-1407o
~IC\OJ. \Af\C!..
~I(\O!- 1 /tnor.
; QC Limits
40%- 130%
40%- 130%
Ratio
0.76
0.80
1.70
1.41
0 J.Q
1.18
0.43
0.95
078
. /o
Ratio
1.51
0.51
11 C
.13
OA1
.**3
: Ratio ?
0.48
0.50
Ratio
0.81
i m
RT
20:23
21:13
24:42
25:50
29:11
31:11
32:02
RT
21:13
25:28
28:22
oL.2.5
^.•:.RT::.:.,
29:41
28:59
RT
21:00
Flags
Q_
OH
Q_
—
«*8ts.
oil
~
Ffafs
—
Flags !
—~~.
Data Reviewer
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
09/17/97
Page 2 of 2
X237 J>SR vZOO. LARS 6 1O.O4
Printed: 13:58 09/1
-------
Data Review By:
Initial ....Date...
*tf\~/ 5_/J3L/2i: Calculated Noise Area:
1.55
The Total Area for each peak with an ion abundance ratio outside
ratio limits has been recalculated according to method requirements.
Page No.
09/17/97
Listing of S975815B.dbf
Hatched GC Peaks / Ratio / Ret. Time
Compound/
M_2.... QC.Log Omit Why
TCDF
304-306
D
M
304-306
13C12-TCDF
316-318
.RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
316-318
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
SN
SN
SN
SN
SN
SN
1
NL
WL
4
0:
17:
19:
19:
20:
20:
20:
22:
00
38
40
57
14
25
58
;17
0.
RO
RO
RO
RO
RO
RO
65-0.89
0.
0.
2.
0.
0.
0.
1.
0.
10
93
17
56
76
35
39
35
Peak
0
19
19
19
20
20
:00
:11
:32
:54
-.23
:51
0.
RO
RO
RO
RO
0.
1.
1.
6.
1.
8.
2.
4.
8.
18
61
93
21
94
52
62
07
52
65-0.89
0
0
0
0
0
1
.55
.69
.57
.59
.76
.23
Peaks
1.
49
6
25
4,593
19
4,645
.56
.17
.64
.77
.60
.88
.89
0.820-1.101
0.
0.
0.
0.
0.
3.91 4.61 1.
1.
1.
000
865
965
979
993
002 2378-TCDF AN
029
093
0.951-1.049
0
0
2.89 5.03 0
11.21 18.88 0
1,979.96 2,613.64 1
13.84 11.23 1
.000
.941
.958
.976
.000 13C12-2378-TCDF ISO
.023
Above: TCDF / TCDD Follows
TCDD
320-322
320-322
0.65-0.89
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
WH
0
0:
18:
18:
20:
00
15
42
:01
20:23
20
20
20
21
21
21
21
22
22
22
:37
:38
:58
:13
:28
:40
:42
:01
:15
:37
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
5.
4.
3.
0.
4.
1.
6.
2.
0.
0
1
0
4
0
5
13
53
00
44
40
43
69
.84
.30
.29
.86
.18
.69
.94
.70
Peaks
0.14
0.30
0.30
1.52
1.20
0.25
0.28
0.78
2.09
0.87
0.25
0.16
0.62
1.38
0.41
0.00
0.853-1.059
0.000
0.860
.381
.943
0.
0.
0.961
0.972
0.973
0.988
1.000 2378-TCDD
1.012
1.021
1.023
1.038
1.049
1.066
AN
37C1-TCDD
328
DC
DC
NL
0:00
0:00
19:40
0.08
0.00
13.92
13.92
0.906-1.094
0.000
0.000
0.927
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 1359 09/17/9'
44
-------
Page No. 2
09/17/97
Compound/
M_Z.... QC.Log Omit Why
Listing of S975815B.dbf
Hatched GC Peaks / Ratio / R«t. Time
.RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
AM
328
13C12-TCDD
332-334
332-334
PeCDF
340-342
340-342
13C12-PeCDF
352-354
352-354
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
SN :
5
NL
WL
SN
SN
SN
4
NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
WH
0
NL
7
21:13
21:29
21:38
21:42
22:01
Peaks
O.i
0:00 RO :
19:05 RO
19:29 RO
19:54 RO
20:36
21:00
21:13
21:34 RO
22:00 RO
Peaks
1.
0:00 RO
22:56 RO
23:04 RO
23:31 RO
23:50 RO
24:10 RO
24:27 RO
24:35 RO
24:45 RO
25-. 16 RO
25:48 RO
26:28 RO
26:36 RO
26:43 RO
Peaks
1
0:00 RO
23:49
24:20
24:42
25:00
25:28
25:50 RO
26:27 RO
Peaks
2,:
2,:
55-0.89
20.25
0.91
1.16
1.05
0.84
0.81 3,
0.80 2,
1.08
0.35
6,
32-1.78
0.09
0.09
0.52
0.30
0.61
0.27
2.73
2.15
0.79
0.50
1.13
0.23
0.31
0.78
.32-1.78
1.00
1.62
1.60
1.70 3
1.58
1.51 3
1.93
1.23
7
L10.00 2,110.00
2.91 2.91
2.91 2.91
2.17 2.17
1.01
131.91
0.14
2.46
1.31
16.35 9.69
3.83
329.10 1.490.55
645.89 1,177.55
41.54 25.41
1.54
032.88
TVT\n / DttfTMT V rtl 1 *-\ue
l\~UU f few IJJT rOll OWS - " '
0.12
0.10
0.54
0.59
2.88
1.07
4.74
0.84
2.68
2.02
0.15
0.81
0.64
2.20
0.00
0.15
56.50 34.94
20.27 12.47
,558.95 2,241.95
33.92 20.75
,479.61 2,092.50
6.17 4.68
10.18 6.19
,165.60
1.000 37C1-TCDD :
1.013
1.020
1.023
1.038
0.906-1.094
0.000
0.899
0.918
9.24 0.938
0.971
1,838.55 0.990 13C12-1234-TCDD
1,468.34 1.000 13C12-2378-TCDD
23.47 1.016
1.037
0.907-1.078
0.000
0.928
0.934
0.952
0.965
0.978
0.990
0.995
1.002 12378-PeCDF
1.023
1.045
1.072
1.077
1.082
•0.838-1.162
0.000
21.56 0.964
7.80 0.985
1,317.00 1.000 13C12-PeCDF 123
13.17 1.012
1,387.11 1.031 13C12-P6CDF 234
2.42 1.046
5.04 1.071
SOR1
RSI
IS1
AN
IS2
SUR2
Above: PeCDF / PeCDD Follows
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 13:59 09/17/
ft
-------
Page No.
09/17/97
Listing of S975815B.dbf
Hatched GC Peaks / Ratio / Ret.
Tin
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT CoBpound.Name.. ID.. Flags.
PeCDD
356-358
D
356-358
13C12-PeCDD
368-370
368-370
HXCDF
374-376
D
D
D
374-376
13C12-HXCDF
384-386
1.32-1.78
DC NL 0: 00 RO 12.71
DC SN 23:59 1.63
DC SN 24:43 RO 7.49
DC SN 25:00 RO 0.53
DC SN 25:51 RO 1.18
DC SN 26:19 RO 0.77
DC SN 26:30 RO 4.30
0 Peaks
1.32-1.78
DC NL 0:00 RO 1.00
DC SN 24:01 RO 0.86
DC SN 24:42 1.71
DC SN 24:52 RO 3.69
DC SN 25:34 RO 1.27
25:50 1.41
25:59 1.52
DC SN 26:34 RO 1.89
2 Peaks
1.05-1.43
DC NL 0:00 RO 1.91
DC SN 27:35 1.20
DC SN 28:17 RO 3.04
DC SN 28:23 1.05
DC SN 28:28 RO 0. 56
DC SN 28:43 RO 0.85
DC SN 28:53 RO 0.50
DC SN 28:59 RO 0.96
DC SN 29:06 RO 1.84
DC SN 29:22 RO 0.13
DC SN 29:37 1.19
0 Peaks
0.43-0.59
DC NL 0:00 RO 0. 91
27:21 RO 0.41
27:29 0.53
28:22 0.51
28:28 0.49
28:37 RO 0.62
28:59 0.50
29:08 0.46
DC SN 29:22 0.59
DC SN 29:27 RO 0.31
DC SN 29:33 RO 0.72
29:41 0.48
DC SN 29:55 RO 0.97
DC SN 30:11 RO 0.34
0.18
2.18
1.05
1.14
4.16
0.76
0.94
0.00
0.13
1.32
3.60
1.71
2.76
2,144.29 1,255.11
196.92 118.64
2.40
2,341.21
2.46
2.13
2.44
10.30
1.61
1.48
1.16
6.94
1.28
0.11
8.15
0.00
2.97
8.50 2.87
23.70 8.20
2.397.48 812.87
2,862.76 938.49
10.45 4.29
2,646.33 878.42
8.99 2.82
1.99
2.10
1.48
2,176.54 708.64
2.94
1.39
0.921-1.026
0.000
0.928
0.957
0.968
1.001 12378-PeCDD AN
1.019
1.026
0.845-1.155
0.000
0.930
0.956
0.963
0.990
889.18 1.000 13C12-PeCDD 123 IS3 Q
78.28 1.006
1.028
0.955-1.052
0.000
0.969
0.994
0.997 123478-HxCDF AN
1.000 123678-HXCDF AN
1.009
1.015
1.018 234678-HxCDF AN
1.022
1.032
1.040
0.859-1.141
0.000
7.04 0.961
15.50 0.965
1,584.61 0.996 13C12-HXCDF 478 SUR3
1,924.27 1.000 13C12-HXCDF 678 IS4
6.92 1.005
1,767.91 1.018 13C12-HXCDF 234 ALT2
6.17 1.023
1.032
1.035
1.038
1,467.90 1.043 13C12-HXCDF 789 ALT1
1.051
1.060
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed 13:59 09/1^*
-------
Page No.
09/17/97
Listing of S975815B.dbf
Matched GC Peaks / Ratio
/ Ret. Time
Confound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.P»ak.l. . Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
384-386
8 Peaks
10,134.75
HxCDD
390-392
D
390-392
13C12-HXCDD
402-404
402-404
HpCDF
408-410
MKT
D
408-410
13C12-HpCDF
418-420
418-420
HpCDD
424-426
1.05-1.43
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
SN
SN
SN
SN
SN
SN
SN
WH
0
NL
SN
SN
5
NL
SN
SN
SN
WH
WH
1
NL
SN
2
NL
SN
SN
0:00
28:21
28:28
28:54
29:12
29:19
29:24
29:28
29:48
Peaks
0:00
28:35
29:06
29:11
29:29
29:40
29:45
29:49
Peaks
0:00
31:11
31:33
32:10
32:24
32:39
32:53
Peak
0:00
31:11
31:26
32:23
Peaks
RO
RO .
RO
RO
RO
RO
RO
RO
1.
RO
RO
RO
RO
0.
3.
1.
2.
1.
0.
1.
2.
1.
80
97
49
55
95
41
33
91
56
1.
0.
2.
0.
1.
1.
5.
0.
0.
0.
75
72
SO
65
84
16
20
72
56
00
05-1.43
1.
0.
1.
1.
1.
1.
0.
1.
40
99
15
18
19
00
.73
.45
1.
25
12.77 7.07
2,128.76 1.138.54
2,679.88 1.451.98
3,236.46 1,760.90
6.79 3.76
1.70
2.22
0.950-1.015
0.
0.
0.
0.
1.
1.
1.
1.
1.
000
971
975
990
001 123678-HXCDD
005
007
010 123789-HxCDD
021
AN
AN
0.966-1.034
0.
7.15 0.
990.22 0.
1,227.90 1.
1,475.56 1.
3.75 1.
1.
000
979
997 13C12-HXCDD 478
000 13C12-HXCDD 678
010 13C12-HXCDD 789
017
019
SUR4
IS5
RS2
1.022
8,064.66
0.
RO
RO
RO
RO
RO
0
RO
RO
88-1.20
1
1
1
0
0
0
2
.37
1
0
1
0
-S3
.18
.09
.26
.87
.29
.24
-0.51
.34
.43
.87
.43
• Uv(—r^n / Urs/^TM? C"/N! 1 rtwe
nxuuLf / npcur follows —
0
14
3
0
5
0
1
14
.94
.68 7.95
.15
.45
.98
.31
.90
.68
0.995-1.044
0
6.73 1
1
1
1
1
1
.000
.000 1234678-HpCDF
.012
.032
.039 1234789-HpCDF
.047
.055
AN
AN
0.936-1.128
1
1,836
1
1,113
.18
.69 550.23
.90
.47 333.82
0
1,286.46 1
1
779.65 1
.000
.000 13C12-HpCDF 678
.008
.038 13C12-HpCDF 789
IS6
SUR5
2,950.16
0
0:00 RO
31:17 RO
31:28 RO
.88
7
1
3
-1.20
.14
.37
.09
tr i npv,uu TUJ.J.OWS --
0.14
1.20
1.41
0.976-1.006
0
0
.000
.977
0.982
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham. North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 13:59 09/
-------
Page No.
09/17/97
Listing of S975815B.db«
Macchod QC Peaks / Ratio / Ret. Tim*
Compound/
M_Z.... QC.Log omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
DC SN 31:39 RO 2.30
MT 32:01 1.07
424-426 1 Peak
0.94
7.73
7.73
4.00
3.73
0.988
0.999 1234678-HpCDD
AN
13C12-HpCDD 0.88-1.20
436-438 DC NL 0:00 1.11 3.77
31:26 RO . 1.25 7.08
32:02 0.95 1,887.05
436-438 2 Peaks 1,894.13
4.33
918.59
0.969-1.031
0.000
3.47 0.981
968.46 1.000 13C12-HpCDD 678 IS7
OCDF
442-444
442-444
0.76-1.02
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
1
0:00
30:
31:
31:
31:
32:
32:
32;
33;
33;
33
34
34
35
35
35
55
21
41
58
19
32
41
09
:15
:33
:24
:39
:18
:40
:54
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
0.
1.
1.
0.
0.
1.
2.
0.
2.
0.
0
0
0
1
0
0
89
16
14
04
08
00
93
.68
,28
.36
.67
.34
.76
.94
.15
.64
Peak
Above: HpCDD / Octa-CDD and CDF Follows
0.68
1.61
0.40
0.13
0.13
0.66
0.57
1.06
0.55
0.51
0.76
1.32
13.25
0.93
0.49
0.64
13.25
5.71
0.884-1.116
0.000
0.895
.908
7.54
0.
0.917
0.926
0.936
0.942
0.946
0.960
0.963
0.972
0.996
1.003 OCDF
1.022
1.033
1.040
AN
OCDD
458-460
458-460
0.76-1.02
DC NL 0:00 1.00
34:33 0.84
DC SN 34:46 RO 3.00
1 Peak
0.14
17.46
0.30
17.46
7.98
0.884-1.116
0.000
9.48 1.000 OCDD
1.007
AN
13C12-OCDD 0.76-1.02
470-472 DC NL 0:00 1.00 0.14
34:32 0.78 2,454.20
470-472 1 Peak 2,454.20
1,074.52
0.995-1.005
0.000
1,379.68 1.000 13C12-OCDD
1S8
Column Description.
"Why" Code Description QC Log Desc.
M_Z -Nominal Ion Mass(es)
. .RT. -Retention Time (mm:ss)
Rat.l -Ratio of M/M+2 Ions
OK
-RO=Ratio outside Limits
Rel.RT-Relative Retention Time
End of Report
WL-Below Retention Time Window A-Peak Added
WH-Above Retention Time Window
SN-Below Signal to Noise Level
-------
rile>SS75815 #1-848 Acq:ll-SEP-1997 03:08,30 SI+ Voltage SIX 70S Noiu»t3B
303.9016 Tt2 BSUB<256,30,-3.0) PKD(9,5,5,0.05\,152.0,1.00\,r,T) Exp:ETCUS
TRIANGLE LABS Text:Til M23 BLANK TLIH308S IJKT. TIME - 03t09
A5.07E4
17:00 18:00 19:00 20:00 21:00
r±le:S975815 #1-848 Acq:ll-SEP-1997 03:08:30 EH- Voltage SIS 70S O6ime:384
305.8987 Ts2 BSUB(256,30,-3.0) PKD(9,5,5,0.05\,1536.0,1.00%,T,T) ExpiEfCOS
TRIANGLE LABS Text!ITJ M23 BLANK TLH43085 1ST. TIME - 03:09
1003
aol
22 tOO
17:00 18:00 15.-00 20': 00 21:00
file:S975815 #1-848 Acqsll-SEP-1997 03:08:30 EI+ Voltage SIR 70S Noiae:342
315.9419 T:2 BSU3(256,30r -3.0) PKD(9,5,5, 0. 051,1368. 0,1. 00\,r,T) Exp:EPCUS
TRIANGLE LABS Text:TLI M23 BLANK TLI#43085 ISJ. TIME ' 03:09
22:00
1003
80.
601
40,
201
OJ
A1.98E7
-4.7E6
.3. 8E6
.2.8E6
.1. 9E6
.9. 4E5
T
"T
-I7.-00 18:00 1P.-00 20:00
rile:S975815 #1-848 Acq:ll-SEP-1997 03:08:30 EI+ Voltage SIR 70S Noiae:613
317.9389 F:2 BSUB(256,30, -3 .0} PKD(9, 5,5, 0. 05\,2452.0,1 . 00\,F,T) Exp:EPCUS
TRIANGLE LABS Text:TLI M23 BLANK TLI443085 IKJ. TIME - 03:09
1003
aol
40.
201
ol
"" 1 ""
22: 00
O.OEO
Time
~T
T
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.5. OE6
.3.8E6
.2.5E6
'•.1.3X6
21': 00
17:00 18:00 19:00 20:00
F±le:S975815 #1-848 Acq:ll-SEP-1997 03:08:30 Eli- Voltage SIR 70S
330.9792 T:2 ExpiEPCUS
TRIANGLE LABS Text:TLI M23 BLANK TLH43085 1X7. TIME -
22:00
O.OEO
Tine
03:09
21:00
17:00 18:00 19': 00 20:00
File:S975815 #1-848 Acq:ll-SEP-1997 03:08:30 EH- Voltage SIR 70S
375.8364 r:2 ExptEPCUS
TRIANGLE LABS TextiTLI M23 BLANK TLI#43085 UKT. TIME - 03:09
1001
22:00
48
-------
rile:S975815 #1-848 Acq: ll-SXP-1997 03:08:30 EH- Voltage SIX 70S Noim«:206
319.8965 r:2 BSUB(256, 30, -3 .0) PXD(7,5
,3, 0.05%, 82*.
TRIANGLE LABS Text:TLI M33 BLANK TLH43085
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60:
40:
20.
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A1.30E4
..JiJIljCiUui^L
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0,1.00\,F,T) XxptXPCOS
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7.1X3
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2.4X3
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321.8936 F:2 BSUB(256, 30, -3.0) PKD(7 , 5,3,0 .05\, 160
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40:
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0,1.00*,f,rj Exp:EPCUS V v £11-*'
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331.9368 T:2 BSOB(256, 30, -3 .0) PKD( 7,5, 3, 0. 05\, 3244. 0,1 . 00\,F, T) Exp:EPCUS
TRIANGLE LABS Text:TLI M23 BLANK TLI#4308S
1001
80:
60:
40:
20:
0:
' 20:00 '
INJ. TIME - 03:09
A1.49E7 3.8X6
\A1.18X7
ft
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333.9338 T:2 BSUB(256, 30, -3. 0) PKD(7,
5, J, 0.05%, 15ff.O,1.00%,J', T) Exp:EPCUS
TRIANGLE LABS Text:TLI M23 BLANK TLH43085
1001
80:
60-
40:
20.
0
19:00 '
20:00
INJ. TIME - OJ.-09
A1.84E7 4.6X6
f\A1.47E7
1 II
ft
; V; V
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Ll . 8E6
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rile:S975815 tl-848 Acq:ll-SEP-1997 03:08:30 Eli- Voltage SIR 70S Noise: J 8
327.8847 T:2 BSUB( 256,30, -3 . 0) PKD(7,
5,3,0.05\,152.0,1.00%,T,T) Exp:EPCUS
TRIANGLE LABS Text : IX J M23 BLANK TLI#43085
1001
80.
60.
40.
20.
0.
19:00'
'20:00
INJ. TIME - OJ.-09
A2.11E7 5.5X6
I
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21:00 22:00 Time
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330.9792 T:2 ElpiEPCUS
TRIANGLE LABS Text. -HI M23 BLANK TLI#43085
100
80
60
40
20
0
i
m ^_JLAJ^WW*^*'*V^'
' 19',00
20:10
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21 : 00 22: 00 Time
49
-------
HetS975815 11-848 Acq:ll-SXP-1997 03i08i30 SI+ Voltage SIX 70S Hairnet33
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OOi,
A5.08X4
so:
26s 00
23i00 24,00 25:00
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41.8567 T:2 BSO3(256, 30, -3. 0) PKD( 7,5, 3, 0 .OS\,1636.0,1.00\,T, T) XxpiEPCUS
TRIANGLE LABS Text:TLI H23 SLANT TLH4308S IJKT. TIKE - 03:09
A2.40E4
26:00
23i00 24:00 25:00
rile:S975815 #1-848 Acq:ll-SEP-1997 03:08:30 EH- Voltage SIR 70S Noise-.44
351.9000 T:2 BSUB(256,30,-3.0) PKD(7,5,3,0.OS\,176.0,1.00\,T,T) Exp:EPCUS
TRIANGLE LABS Text:TLI M23 BLANK TLIt43085 IIKT. TIKE - 03:09
100* A2.24E7 A2.09E7
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40:
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0:
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rile:S975815 #1-848 Acqsll-SEP-1997 03:08:30 EH- Voltage SIR 70S Noiae:46
353.8970 F:2 BSUB(256,30,-3.0) PKD(7,5,3,0.05\,184.0,1.00\,r,T) ExpsEPCUS
TRIANGLE LABS Text:TLI M23 BLANK TLI#43085 INJ. TIMS - 03:09
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40:
20:
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330.9792 T:2 Exp:EPCUS
TRIANGLE LABS Text:TLI M23 BLANK TLI#43085 INJ. TIMS -
24:23
26:00
0.0X0
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23:00 24:00 25:00
rile:S975815 #1-848 Acq:ll-SEP-1997 03:08:30 EI+ Voltage SIS 70S
409.7974 f:2 Exp:XPCUS
TRIANGLE LABS Text:TLI H23 BLANK TLI#43085 INJ. TIMX
1001
SO:
26:00
03:09
231 00
24:00
25iOO
26 i 00
-------
'Ue,3975B15 #1-848 Acqtll-sXf-1997 03:08:30 EI+ Volt*ye SXt 70S Ooifm:44S
55.8546 r:2 BSUB(256,30,-3.0) PKD(7t5r3,0.05\,17»4.0tL.OO\rr,T) ExptXPCUS
TRIAHGLX LABS TextiXLJ M23 BLANK TLIt43085 I JUT. TIME • 03:09
00\
24100 25100 26'tOO
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57.8516 Ts2 BSOB(256,30,-3.0) PKD(7,5,3, 0. 05%, 144.0,1. 00\,r,T) Xxp:XPCOS
TRIANGLE LABS Text:ITT M23 BLANK TLI#43085 IJKT. TIME - 03:09
OOi A1.31X4
Al. 61E4
'A2.15E4
A7.32E3
24:00 25:00 26:00
r±le:S975815 #1-848 Acq:ll-SEP-1997 03:08:30 EI+ Voltage SIR 70S Wbiae.OP
67.8949 F:2 BSUB(256, 30,-3 . 0) PKD( 7, 5, 3, 0. 05\, 156. 0, 1. 00\,T, T) Exp:EPCOS
TRIANGLE LABS Text-.TLI M23 BLANK TLI#43085 JJCJ. TIME • 03>09
100* A1.26E7
80.
60.
40:
20:
1.19E6
24:00 25:00 26:00
rilesS975815 #1-848 Acqsll-SEP-1997 03:08:30 EI+ Voltage SIR 70S Noiae:11
369.8919 T:2 BSUB(256,30,-3.0) PKD(7,5,3,0.05\, 164.0,1.00\,T,T) Exp:EPCVS
TRIANGLE LABS Text:Til H23 BLANK TLI#43085 INJ. TIME - 03:09
1001 A8 $9E6
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40.
20:
0.
7.83E5
24:00 25:00 26:00
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330.9792 r:2 XxptXPCUS
TRIANGLE LABS Text:TLJ M23 BLANK TLH43085 IKT. TIME - 03:09
25:00 25:12 25:25 25:38 ^i*3 26:08
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TRIANGLE LABS TexttTLI M23 BLANK TLIt4308S 1X7. TIMX " 03:09
10 OS, A3.31X4
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375.8178 Ti3 BSO3(256,30,-3.0) PKD(7,S,3,0.05\,2200,0,1.00\,T,T) ExptEPCUS
TXIANGLE LABS TextsTLI M23 BLANK TLIf43085 JJTJ. TIMX - 03:09
10°* AS.Q2X4 ,2.1X4
0X0
Tiae
27:12 27,24 27:36 27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:0030:12
file:S975815 #1-405 Acqtll-SEP-1997 03:08:30 XI+ Voltage SIR 70S Noiae:899
383.8639 F:3 BSUB(256,30,-3.0) PKD(7,5,3,0.05\,3596.0,1.00\,F,T) Ezp-.XPCUS
TRIANGLE LABS Tezt:TLI M23 BLANK TLJ#43085 INJ. TIKE - 03:09
I0°* A9.38Z5 jfl.T/lr* .3.4X6
80:
60:
40:
20:
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27:12 27:24 27:36 27:48 281-66 28:12 281-.24 281-36 28:48 29: 00 ' 29:12' 291-24' 29.-36' 29\ 48 30.' 00 ' 30.-1 f
File:S97S815 #1-405 Acq:ll-SEP-1997 03:08:30 EI+ Voltage SIR 70S Noise:985
385.8610 F:3 BSUB( 256, 30,-3 . 0 ) PKD( 7, 5,3, 0 . 05*, 3940 . 0,1. 00%,r, T) Ezp:EPCUS
TRIANGLE LABS Text.-ZXX M23 BLANK TLH43085 INJ. TIME - 03:09
I00^ Al 92E7 A1.77E7
80: |1 I A1.47E7
401
20:
°J A V A
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Tlae
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271-12 271-24 27^36 27:48 28': 00 ' 2B',12 "28-24 ' 28:35 ' 28:48 29i 00 29^12' 29^24 ' 29i36' 29-48 ' 30io6' 30:12
File:S975815 #1-405 Acq:ll-SEP-1997 03:08:30 EH- Voltage SIR 70S
392.9760 T:3 Xxp:XPCUS
TRIANGLE LABS Text:TLI M23 BLANK TLI#43085 IWJ. TIME - 03:09
I0°* 27:2127:3127:42 2S:-02 2B!-22 28->36. - ...29s.00 29:13 29:23 29:34
80:
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Tile:S975815 #1-405 Ac^:ll-srP-1997 03:08:30 EI+ Voltage SIX 70S
445.7555 F:3 Exp:EPCUS
TRIANGLE LABS Text:TLI M23 BLANK TLH43085 JWJ. TIME - 03:09
1004
0X6
7X6
3X6
OEO
9S6
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0X6
0X6
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28^48 29-00 29:12 29:24 29:36'29:48 30:Op'30ti2
0X0
Time
52
-------
.J.*lSS75815 #1-405 Acqtll-SEP-1997 OJtOBlJO EI+ VoltMgf SIM 70S NOl»mi48O
89.8156 Ti3 SSUB(256,30,-3.0) PKD(7,5,3,0.05\,1944.0,1.00\,r,T) Xlp:IPCUS
TRIANGLE LABS TexttTLI K23 BLANK TLH43085 ZIW. TIMS - 03:09
001
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60.
40.
20.
27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24
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91.8127 f:3 BSOB(256,30,-3.0) PKD(7,5,3,0.05\,2424.0,1.00\,r,T) ExptEPCOS
TRIANGLE LABS Telt-.TLI H23 BLANK TLH43085 INJ. TIME - 03109
00* A3.61E4
27:48 20:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36
rile:S97S815 #1-405 Ac
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ilo:S975815 11-430 Acq:ll-SEP-1997 03,08,30 MI+ Voltage SIS 70S Noisei376
07.7818 r:4 BSUB(2S6,30,-3.0) PKD(7,5,3,0.05\,1504.0,1.00\,r,T) KxpiIPCUS
TSIANSLX LABS Text,TLI M23 BLANK TLH43085 IKT. TIHX - 03,09
001
31:12 31:24 31,36 31,48 32:00 32:12 32:24
File:S97S815 #1-430 Acqsll-SEP-1997 03,08,30 EI+ Voltage SIS 70S Noise,230
09.7789 T:4 BSOB(256,30, -3.0) PKD(7,5,3, 0.05\,920.0,1.00\,r,T) Xxp:SPCOS
TRIANGLE LABS TextsTLI M23 BLANK TLIf43085 INJ. TIME - 03:09
1001 A8.48Z4
80:
32,36
32:48
so
40:
20:
Al. 51X4
A3.51E4
A8.42E3
^XX^^V.
31:12 31,24 31,36 31:48 32:00 32:12 32,24 32:36
File:S97S815 #1-430 Acqsll-SEP-1997 03,08,30 EH- Voltage SIS 70S Jfc.iae.-548
417.8253 T:4 BSUB(256, 30, -3. 0) PKD(7,5,3,0 .OS\,2192.0,1.00\,r,T) Exp-.EPCUS
TRIANGLE LABS Tert:TLI M23 BLANK TLI#43085 INJ. TIME - 03:09
1001 A5.50E6
32:48
2.3E4
1.9X4
1.4X4
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Time
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601
40:
201
0:
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1.9E6
1.5E6
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31:12 31:24 31:36 31:48 32:00 32:12 32:24
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419.8220 T:4 BSOB(256, 30,-3.0 ) PKD( 7, 5, 3, 0. 05\, 1648. 0,1. 00%, T, T) Exp:EPCUS
TRIANGLE LABS TextsTLI M23 BLANK TLI#43085 INJ. TIME - 03:09
10 OS, A1.29E7
32:36
32:48
so:
60:
40:
20:
o.
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4.4S6
3.6E6
2.7E6
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31:12 31:24 31:36 31:48 32:00 32,12 32,24 32:36 32,48
File:S975815 #1-430 Acqsll-SEP-1997 03:08:30 EI+ Voltage SIS 70S
430.9729 F,4 ExpsEPCUS
TRIANGLE LABS Text-.TLI M23 BLANK TLI#43085 INJ. TIME - 03:09
1003
80:
40:
201
0.
32,41
31 s 20
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31:12 31:24 31:36 31:48 32:00 32':12
file:S975815 #1-430 Acq:ll-SEP-1997 03:08,30 EH- Voltage SIS 70S
479.7165 F,4 Exp:EPCUS
TRIANGLE LABS TextsTLI M23 BLANK TLH43085 1KT. TIKE
1001
32:24
32:36
32:48
.O.OEO
Tim
03:09
31:12
31124
31,36
31:48
32:00
54
-------
rilmtS975B15 tl-430 Acqill-SEP-1997 03:08:30 Kit Voltage SIX 70S Nolle:248
423.7766 T:4 BSUB(256, 30, -3.0) PKD(7,5,3,0.05\,992.0,1.00\,T,T) Elp:XPCUS
TRIANGLE LABS TmxtiTLI M23 BLANK TLH430B5 1X7. TIME - 03:09
1001
80.
eo:
40:
20:
31': 18 31': 24 31:30 31:36 31:42 31:48 31:54 32:00 32:06 32:12 32:18 32:24 32:30
rile:S975815 tl-430 Acqtll-SEP-1997 03:08:30 EH- Voltage SIS 70S Hoi**-.36
425.7737 T:4 BSUB(256,30, -3. 0) PKD(7,5,3,0.05\,144.0,1.00\,T,T) Elp:EPCUS
TRIANGLE LABS Text:TLI M23 BLANK TLH43085 JK7. TIME - 03:09
1001
O.OEO
Time
_9.«3
31:18 31.-24 31:30 31:36 31:42 311-48 31:54 32iOO 32:05 32:12 32:18 32.-24 32:30
rile:S975S15 #1-430 Acq:ll-SEP-1997 03:08:30 EI+ Voltage SIS 70S Noiae:991
435.8169 T:4 BSUB(256,30,-3.0) PKD(7,5,3, 0. 05%, 39S4. 0,1. 00\,T, T) Exp:EPCUS
TRIANGLE LABS Text:TLI M23 BLANK TLIt4308S INJ. TIME - 03:09
100J
80J
so:
40.
20.
31:18 31:24 31:30 31:36 31:42 31:48 31:54 32:00 32:06 32:12 32:18 32:24 32:30
Tile:S975815 tl-430 Acq:ll-SEP-1997 03:08:30 Eli- Voltage SIS 70S Noiaei896
437.8140 T:4 BSUB(256,30,-3.0) PKD(7,5,3,0.05\,3584.0,1.00\,F,T) Exp:EPCUS
TRIANGLE LABS Text.-IXJ M23 BLANK TLI#430S5 INJ. TIME - 03:09
A9.19E6
-r
I I I I I I I I I I I
31:24 31:30
~T
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Time
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Time
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60:
40:
20:
A9.68E6
3. 2E6
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31:18 3li24 31i30 31i35 31i42 31.-48 3ll-54 32iOO 32iOS 32:12 32:18 32i24 32:30
File:S975815 tl-430 Acqtll-SEP-1997 03:08:30 £1* Voltage SIR 70S
430.9729 F:4 ExptEPCUS
TRIANGLE LABS Text:TLI M23 BLANK TLIt43085 X1KT. TIME - 03:09
.O.OEO
Time
80.
60.
40.
4.2E6
3.3E6
2.5E6
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20.
01
31:18 ' 31\24 ' 31: JO ' '3l':36 ' 31\42 ' 3l':48 31\54 32\66 ' 32:05 32\12 32:18 32\24 32:30
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lo . oro
Time
-------
31:00 32:00 33:00 34:00 35:00
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43.7399 r.-4 BSUB(256,30, -3. 0) PKD(7,5,3, 0.05%, 712. 0,1. 00*,r, T) EipsEPCUS
TRIANGLE LABS Taxt:TLI M23 BLANK TLIt43085 IKJ. TIME - 03:09
001 Al. 4ES
,,3975615 41-436 Acq.ll-SEP-1997 63,66,36 EI+ Volt+
-------
file:SS758l5 H-430 Acq,ll-SSP-1997 03,08,30 H* Voltagm Sit 70S BoiM.,36
457.7377 Ti4 BSUB(356,30,-3.0) PKD(7, 5,3, 0.05\, 144.0,1.00\,r,T) XxpiXPCUS
TRIANGLE LASS TeJcttTLI H23 BLANK TLH43085 TJW. TIMS - 03t09
100* A9.42E4
34:24 34130 34': 36 34>42 34:48 34:54
FiletS975815 il-430 Acqtll-SEP-1997 03:08,30 EI+ Volt*ye SIX 70S Noime:35
459.7348 Fi4 BSUB(256,30,-3.0) PKD(7,5,3,0.05\,140.0,1. 00\,T,T) ExptEPCUS
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TLI Project: 43085 Method 23 TCDD/TCDF Analysis (DB-225)
Client Sample: TLI M23 Blank Analysis File: P973852
Client Project:
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
S413-004
XAD
TLI Blank
1.000
n/a
DB-225
Date Received:
Date Extracted:
Date Analyzed:
Dilution Factor:
Blank File:
Analyst:
/ /
09/04/97
09/12/97
n/a
P973852
ML
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPC2NF04
PF22206
P973843
n/a
n/a
n/a
Analytes
Amt. (ng)
Bt
EMPC
Ralfo *
(T Flags
2,3,7,8-TCDF
ND
0.03
Internal Standard
Amt.; '(ng>'. ';'-;:;:'vJ4^:;:%:RecoVery';" QC Limits ;; .. • :Ratfo::;'-!f f :h
l3Ci:-2,3,7,8-TCDF
2.7
67.4
40%-130%
0.78
20:39
Recovery Standard
Ratio
Slags
13Cirl,2,3,4-TCDD
0.79
19:41
Data Reviewer
Of I
VK.L; - L^ i .
Page 1 of 1
09/18/97
CWF_PSR viOO. LARS 6.10.M
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 15:52
-------
Data Review By:
Initial Date...
J *" ( / Kill Calculated Noise Area:
1.53
The Total Area for each peak with an ion abundance ratio outside
ratio limits has been recalculated according to method requirements.
Page No.
09/12/97
Listing of P973852B.db£
Hatched GC Peaks / Ratio / Ret. Time
Compound/
M_Z QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Confound.Name.. ID.. Flags.
TCDF
304-306
304-306
0.65-0.89
DC NL 0:00 0.87
DC SN 22:12 RO 1.00
DC SN 22:16 0.65
0 Peaks
1.96
0.58
0.91
0.00
0.786-1.096
0.000
1.075
1.078
13C12-TCDF
316-318
316-318
13C12-TCDD
332-334
0.65-0.89
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
WL
WL
WL
WL
SN
WH
1
NL
SN
0:00
19:12
19:21
19:31
19:36
20:39
21:31
22:30
Peak
0:00
18:23
RO
RO
RO
RO
RO
RO
0.
RO
RO
0.
3.
0.
4.
0.
0.
4.
0.
94
77
34
38
86
78
45
93
65-0. 8S
1
1
.39
.33
2.25
0.23
0.92
0.42
6.26
516.62 225.80
0.19
4.96
516.62
Above: TCDF / TCDD Follows -
332-334
2.11
1.49
19:27 0.79 431.45 191.02
19:41 0.79 552.23 242.97
20:21 RO 0.91 5.26 2.71
3 Peaks 988.94
0.952-1.048
0.000
0.930
0.937
0.945
0.949
290.82 1.000 13C12-2378-TCDF ISO
1.042
1.090
0.897-1.103
0.000
0.945
240.43 1.000 13C12-2378-TCDD IS1
309.26 1.012 13C12-1234-TCDD RSI
2.97 1.046
Column Description "Why" Code Description QC Log Desc.
M_Z -Nominal Ion Mass (88)
..RT. -Retention Time (mm:ss)
Rat.l -Ratio of M/M+2 Ions
OK -RO=Ratio Outside Limits
WL-Bclow Retention Time Window
WH-Above Retention Time Window
SN-Below Signal to Noise Level
A-Peak Added
K-Peak Kept
D-Peak Deleted
-------
! K B B 8 8 fi
00
-------
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TXIANGLX LABS TexttTLI H23 BLANK TLH430B5
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221 00
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TXIANGLX LABS TextiXCX M23 BLANK TLH43085
004 A5.63E3
18.00 19:00 20.00 21:00
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80.
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22100
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F±le:P973852 #1-755 Aoj:12-SEP-1997 18:20:31 EH- Voltage SIX 70P Noiee:826
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333.9338 BSUB(2S6,30,-3.0) PKD(S, 3,1, 0.101,2376. 0, 0.00\,T,f) Eip:DB225
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-------
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303.9016 XxpiDB235
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315.9419 Exp:DB225
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1004
aol
60l
40:
ao:
'aa'too
17:00 18:00 19:00 20:00 21:00 22:00
rile>P973853 #1-755 Acqtl3-SEP-1997 18>30>31 EI+ Voltage SIR 70P
319.8965 Exp:DB325
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17:00 ISl-OO 1S:00 20l-00 21:00
r±leiP973852 #1-755 Acqil3-SEP-1997 18t20i31 EI+ Voltage SIR 70P
331.9368 Exp:DB235
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1001 19141
22:00
80:
60.
40:
20:
19,27
17:00 18:00 19:00 20.-00 21:00 22:00
J-ile:P973852 #1-755 Acqtl2-SEP-1997 18:20:31 EI+ Voltage SIR TOP
292.9825 Eip:DB225
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18:26
-~~****r~*~~~^jf^--^tt-^*~rv
80:
60:
40:
20:
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17:00
F±le:P973852 #1-755
33 0.9 792 Exp:DB225
18:00
AC9.-12-SEP-1997
19:00
20:00 21:00 22
0.0£0
1 00 Time
18: 20! 31 EH- Voltage SIR TOP
TRIANGLE LABS TexttTLI M23 BLANK TLH43085
1001
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40:
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0.
^~**iii£L17'10
L*J 1 I'^IMA^^
17:00
18:24
\*+^*m~*\**r~ ' "*-> '•
18:00
19,13
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19:00
19:38 20:09 21:15
•~~w>«/*v
-------
Ref, uss 232,9825 Peak top
Helpjt 1,86 volts Spai 286 ppi
file naie
Data fllenaie
Resolution
Group nuiber
lonlzatlon wde
Sultchlng
Ref, lasses 292,9825,
fl 292,9825
6 383,9816
C4AC 0001
OW.WO/
D 315.9419
E 317,9389
F 319,8965
G 321,8936
H 327,8847
I 338,9792
J
K
L
H
1
El*
VIM
388.9761
336,9792
331,9368
333,9338
375,8364
Chamd. I 338,9792 Peak top
Hel^t 1,85 volts Span 208 ppi
72
-------
TLI Project: 43085
Client Sample: O-M23-1
Method 23 PCDD/PCDF Analysis (a)
Analysis File: S975866
Client Project:
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
S413-004
M23Train
181-55-1ABE
1.000
n/a
DB-5
Date Received:
Date Extracted:
Date Analyzed:
Dilution Factor:
Blank File:
Analyst:
09/03/97
09/04/97
09/13/97
n/a
S975815
ML
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPX23704
SF56117
S975861
n/a
n/a
n/a
Artalytes
2,3,7,8-TCDD
1,2,3,7,8-PeCDD
1,2,3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
1,2,3,4,6,7,8-HpCDD
1,2,3,4,6,7,8,9-OCDD
2,3,7,8-TCDF
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
1,2,3,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
1,2,3,4,6,7,8,9-OCDF
;^otatev..kv.,.^^|'^-:
Total TCDD
Total PeCDD
Total HxCDD
Total HpCDD
Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF
Amt* (ng)
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
^•^.Arot-.CngT
ND
EMPC
ND
ND
0.15
ND
ND
ND
DL EMPC
0.09
0.1
0.1
0.1
0.1
0.2
0.5
0.08
0.09
0.09
0.09
0.07
0.09
0.1
0.1
0.2
0.4
^.;»«infa«fc;;l»,^:iMPC
0.09
0.53
0.1
0.2
1
0.09
0.09
0.2
Raffo HT Ffegs
—
—
Flags
—
.
Page 1 of 2
X237.PSR vlOO. LARS 6.10.C
Triangle Laboratories, Inc.®
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 15:16 09/17/9
-------
lental Services
TLI Project: 43085
Client Sample: O-M23-1
Method 23 PCDD/PCDF Analysis (a)
Analysis File: S975866
internal Standards
13C12-2,3,7,8-TCDF
13C12-2,3,7,8-TCDD
13C12-l,2,3,7,8-PeCDF
13C12-l,2,3,7,8-PeCDD
13C12-l,2,3,6,7,8-HxCDF
13C12-l,2,3,6,7,8-HxCDD
13C12-l,2,3,4,6,7,8-HpCDF
I3C12-1,2,3,4,6,7,8-HPCDD
13C,2-U,3,4,6,7,8,9-OCDD
Surrogate Standards (Type A)
37CL,-2,3,7,8-TCDD
'3C,2-2,3,4,7,8-PeCDF
13Ci2-l,2,3,4,7,8-HxCDF
l3Ci2-l,2.3,4,7,8-HxCDD
l3C,2-l,2,3,4,7,8,9-HpCDF
Alternate Standards (Type A)
l3Cu-l,2,3,7,8,9-HxCDF
l3C,2-2,3A6,7,8-HxCDF
Recovery Standards; ..:
13C,2-1(2,3,4-TCDD
13Ci2-l,2,3,7,8,9-HxCDD
Ami (ng)
5.5
5.8
6.4
7.1
4.9
4.9
3.6
3.5
4.8
Anrrt. (ng)
3.2
2.9
3.0
2.6
3.1
Amt (ng) ;?
3.0
3.7
% Recovery "
137
145
160
111
124
122
91.2
88.5
60.5
-:'!' ^Recovery
79.3
71.8
73.8
64.4
78.7
&$$***&£:.
74.3
92.3
QC Limits
40%-130%
40%-130%
40%-130%
40%- 130%
40%- 130%
40%- 130%
25%-130%
25%-130%
25%-130%
QC Limits
70%- 140%
70%- 140%
70%- 140%
70%- 140%
70%- 140%
QC Limits
40%- 130%
40%-130%
Ratio
0.80
0.78
1.23
1.46
0.51
1.19
0.43
1.02
1.00
Ratio ?;.P
1.41
0.52
1.21
0.44
; Ratfo %
0.52
0.50
. Ratio
0 84
1.23
RT
23:17
23:47
26:29
27-24
29:38
30-16
32-06
35:22
;?*rr,fj!
23-48
27-06
29:33
30-12
33:14
:,m • ,-.
30:45
30:05
RT
30:32
Flags
—
RO
"•""•
~"^^~"
^~—~
— —
—
f Flags'H
• • •• • \
— •
v
Ffegs
Q
Flags
"-
Data Reviewer
Page 2 of2
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
09/17/97
X237_PSRY2.00,U«S 6.10.04
Printed: 15:1609/1*
-------
Daca Review By:
Initial ....Date...
y._ I / I-**/ / T" calculated Noise Area:
1.69
The Total Area for each peak with an ion abundance ratio outside
ratio limits has been recalculated according to method requirements.
Page No.
09/17/97
Listing of S975866B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.,
TCDP
304-306
D
D
D
304-306
0.65-0.89
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
WL
WL
WL
SK
SN
SN
SN
SN
SN
1
0:
18:
19:
19:
19:
19:
20;
21
21
22
22
00
34
02
19
:33
49
:02
:24
:52
:05
:26
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
0.
1.
0.
3.
4.
a.
2.
1.
0.
0.
0,
94
47
51
29
89
59
73
11
92
,78
.94
Peak
0.
1.
1.
0.
3.
1.
4.
3.
5,
8
5
8
28
66
36
60
17
95
.94
,72
.15
.27
.06
.27
3.62
Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
0.838-1.092
0.000
0.805
0.826
0.838
0.848
0.860
0.869
0.928
0.949
4.65 0.958
0.973
13C12-TCDF
316-318
MKT
316-318
0.65-0.89
DC NL 0:00 RO 1.86 0.39
DC WL 18:57 RO 0. 50 1.56
DC SN 22:25 RO 1.91 2.67
DC SN 22:46 RO 10.08 0.71
23:17 0.80 176.80
1 Peak 176.80
78.80
0.954-1.046
0.000
0.822
0.973
0.988
98.00 1.000 13C12-2378-TCDF ISO
Above: TCDF / TCDD Follows
TCDD
320-322
320-322
0.65-0.89
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
WL
WL
WL
WL
WL
WL
SN
SN
SN
SN
SN
SN
SN
SN
SN
0
0:
19:
20:
20:
20:
20:
20
21
21
21
21
22
22
22
22
23
00
54
01
17
: 30
:33
:47
:07
:20
:26
:46
:23
:47
-.54
:59
:39
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
1.
1.
0.
4.
3
1
0
0
0
0
1
1
0
2
2
3
09
43
97
.88
.70
.27
.45
.58
.52
.92
.60
.57
.44
.65
.88
.30
Peaks
0.62
0.90
1.89
0.42
0.35
0.46
0.83
2.00
0.80
85
66
0.50
1.01
0.55
0.92
0.65
0.00
0.875-1.055
0.000
0.837
0.842
0.853
0.862
0.864
0.874
0.888
0.897
0.901
0.915
0.
0.
0.
0.
.941
.958
.963
.966
0.994
Triangle Laboratories, Inc.® Analytical Services Division
801 Capftola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
15:16
-------
Page No.
09/17/97
Listing of S975866B.dbf
Matched GC Peaks / Ratio
/ Rat. Tina
Compound/
M_2.... QC.Log omit Why ..RT. OK Ratio Total.Area,.. Area.Peak.1.. Area.Peak.2. . Ral.RT Compound.Name.. ID.. Flags.
37C1-TCDD
328
0.910-1.090
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
WL
ML
WL
WL
WL
WL
WL
WL
WL
WL
WL
WL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
0:
19:
19:
19:
20:
20:
20:
20:
20:
20:
20:
21:
21:
21:
21:
21:
21:
22:
22:
22:
00
30
45
57
10
10
25
30
41
53
55
15
29
40
43
43
59
19
28
37
0.
11
0.43
6.06
22:47
22:53
23:07
23;
23:
;29
:39
0.
0.
1.
0.
1.
0.
2.
1.
1.
1.
1.
0.
0.
0.
0.
0.
0.
51
35
06
38
04
96
42
16
13
10
01
38
40
41
78
59
72
0.74
0.67
1.03
0.11
7.13 7.13
23:48
328
13C12-TCDD
332-334
332-334
PeCDF
340-342
2
Peaks
101.18 101.18
0.000
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
820
830
839
848
848
858
862
870
878
879
893
903
911
913
913
924
938
945
951
958
962
0.972
0.987
0.994
1
.001 37C1-TCDD SUR1
108.31
0.65-0.89
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
WL
WL
WL
WL
WL
WL
SN
SN
SN
SN
2
0
20
20
20
21
21
21
22
22
22
23
23
23
:00
:08
:24
:58
:03
:11
:29
:07
:30
:37
:28
:37
:47
0.
RO 1.
RO 1.
RO 0.
RO 0
RO 1
RO 3
RO 3
0
RO 2
RO 1
0
0
Peaks
82
.98
,45
.28
.12
.48
.37
.95
.88
.22
.21
.84
.78
1.32-1.78
DC
DC
DC
DC
NL
WL
WL
WL
0:00
23
23
:40
:54
24:05
RO 0
RO 0
RO 0
RO 0
.92
.28
.53
.63
0.31
1
1
0
0
0
0
0
1
0
3
98
151
.04
.45
.64
.18
.44
.87
.37
.09
.32
.40
.04 44.64
.41 66.29
0.910-1.090
0.000
0. 347
0
0
0
0
0
0
0
0
0
53.40 0
85.12 1
.858
.882
.385
.391
.903
.930
.946
.951
.987
.993 13C12-1234-TCDD RSI
.000 13C12-2378-TCDD IS1
249.45
0
4
.20
.49
0.53
1
.35
0.915-1.074
0
0
.000
.865
0.873
0.880
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 15:16
-------
Page No.
09/17/97
Listing of S975866B.dbf
Hatched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why
.RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
340-342
13C12-P6CDF
352-354
NM
N
N
352-354
PeCDD
356-358
356-358
13C12-PeCDD
368-370
N
N
368-370
HxCDF
374-376
374-376
DC WL 24:24 RO 0.57
DC WL 24:54 RO 2.04
DC SN 25:22 RO 2.12
DC SN 25:48 RO 7.75
DC SN 26:32 RO 0.24
DC SN 26:47 1.38
DC SN 27:16 RO . 0.59
DC SN 27:27 RO 2.23
0 Peaks
1.32-1.78
DC NL 0:00 RO 1.09
DC SN 23:32 RO 1.29
23:40 RO 0.72
DC SN 24:09 RO 0.77
DC SN 24:33 RO 2.38
DC SN 25:27 RO 0.63
DC SN 25:46 1.68
DC SN 26:01 RO 0.55
26:29 RO 1.23
27:06 1.41
DC SN 27:22 RO 0.79
3 Peaks
1.32-1.78
DC NL 0:00 RO 1.20
DC WL 24:59 RO 0.81
DC SN 25:41 RO 4.11
DC SN 26:21 1.55
26:32 RO 2.90
1 Peak
1.32-1.78
DC NL 0:00 1.56
DC SN 25:53 RO 0.74
26:32 RO 0.70
27:24 1.46
2'V':"30 RO 1.03
3 Peaks
1.05-1.43
DC NL 0:00 RO 0.96
DC WL 28:42 RO 1.57
DC WL 28:49 RO 2.33
DC SN 30:16 RO 1.55
DC SN 30:41 1.17
0 Peaks
0.99
7.75
0.87
0.82
7.55
1.12
0.87
1.22
0.00
0.20
0.72
7.44 4.52
0.66
0.66
0.90
2.98
1.04
177.68 108.00
123.73 72.49
2.65
308.85
0.20
1.30
1.66
2.40
18.28 20.78
18.28
0.23
2.35
12.91 7.85
110.12 65.30
11.68 7.10
134.71
3.96
2.26
5.42
1.93
2.95
0.00
0.892
0.910
0.927
0.943
0.970
0.979
0.996
1.003
0.844-1.156
0.000
0.860
6.26 0.865
0.882
0.897
0.930
0.942
0.951
37.70 0.968 13C12-PeCDF 123 IS2
51.24 0.990 13C12-P6CDF 234 SUR2
1.000
0.926-1.024
0.000
0.908
0.934
0.958
7.17 0.965
0.850-1.150
0.000
0.941
11.26 0.965
44.82 0.996 13C12-PeCDD 123 IS3
6.86 1.000
0.959-1.050
0.000
0.954
0.958
1.006
1.020
Triangle Laboratories, Inc.® Analytical Services Division
801 Capftola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Flirted: 15:16
-------
Page No.
09/17/97
Listing of S975866B.db£
Hatched GC Peaks / Ratio / Ret. Tina
Compound/
M_Z QC.Log omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Confound.Name.. ID.
Flags.
13C12-HXCDF
384-386
N
N
N
N
N
384-386
HxCDD
390-392
390-392
13C12-HXCDD
402-404
N
N
N
402-404
HpCDF
408-410
408-410
13C12-HpCDF
418-420
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
SN
SN
SN
SN
SN
5
NL
WL
SN
SN
SN
0
NL
WL
WL
WL
WL
WL
SN
SN
SN
4
NL
0
NL
SN
SN
0:00
28:33
28:40
28:50
29:33
29:38
29:50
29:53
29:58
30:05
30:45
Peaks
0:00
28:48
29:55
30:01
30:44
Peaks
0:00
28:49
29:04
29:16
29:21
29:27
29:41
29:49
29:53
30:12
30:16
30:32
30:45
Peaks
0:00
Peaks
0:00
32:06
32:24
32:50
32:54
0.
RO
RO
RO
RO
RO
RO
43-0.59
0.
2.
0.
0.
0.
0.
0.
3.
1.
89
57
46
69
52
51
77
57
00
0.50
1.
RO
RO
RO
RO
1.
RO
RO
RO
RO
RO
RO
RO
0,
0
RO
RO
RO
0.
52
3.
0.
2.
8.
104.
147.
0.
0.
1.
102.
71.
434.
Uvrr\t
05-1.43
1.
1,
.04
.16
0.46
0.29
1
.02
3.
3.
1.
0.
4
0
88
82
40
02 3.67
54 35.91
69 49.82
59
32
66
23 33.98
53 24.50
01
.63
.88
.97
.94
.10
.00
05-1.43
1
1
2
4
1
0
3
0
1
1
1
1
1
.12
.64
.93
.32
.35
.51
.41
.93
.49
.21
.19
.23
.34
3
13
1
1
2
1
1
1
3
75
120
99
10
306
u+rS*r\
.88-1.20
0
.37
1
0
1
0
0
.99
-0.51
.19
.43
.25
.45
.65
3
0
.39
.66
.93
.12
.77
.93
.81
.37
.02
.64 41.38
.70 65.47
.30 54.81
.71 6.14
.35
.54
.00
0.863-1.137
0.
0.
0.
5.31 0.
68.63 0.
97.87 0.
0.
0.
0.
68.25 1.
47.03 1.
000
949
953
958
982 13C12-HXCDF
985 13C12-HXCDF
992
993
996
000 13C12-HXCDF
022 13C12-HXCDF
478 SUR3
678 IS4
234 ALT2
789 ALT1
0.953-1.014
0.
0.
0.
0.
1.
000
943
980
983
007
0.967-1.033
0.
0.
0.
0.
0.
0.
0.
0.
0
34.26 0.
55.23 0
44.49 1
4 . 57 1
000
.944
.952
.959
.961
.965
.972
.977
.979
.989 13C12-HXCDD
.991 13C12-HXCDD
.000 13C12-HXCDD
.007
478 SUR4
678 IS5
789 RS2
0.995-1.042
0
.000
0.937-1,125
2
80
6
2
2
.39
.36 24.04
.29 5.48
.49
.10
0
56.32 1
4.37 1
1
1
.000
.000 13C12-HpCDF
.009
.023
.025
678 IS6
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 15:16
97
-------
Page No.
09/17/97
Listing of S975866B.dbf
Matched GC Peaks / Ratio / Ret. Tim*
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
N
418-420
HpCDD
424-426
424-426
13C12-HpCDD
436-438
436-438
OCDF
442-444
442-444
OCDD
458-460
458-460
13C12-OCDD
470-472
470-472
DC
DC
DC
DC
DC
DC
33:14
SN 33:32 RO
3 Peaks
0.44
2.95
kl»A..A .
0.88-1.20
NL 0:00 1.09
SN 32:12 RO 1.47
SN 32:19 RO 0.72
SN 32:24 RO 0.78
WH 33:11 RO 0.51
0 Peaks
48.74 14.81
1.90
135.39
Ur\/"*TM7 / Ut^*^r> l?i-*l 1 /M*fA
2.24
2.41
1.53
5.16
1.71
0.00
0.88-1.20
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
SN
SN
1
NL
SN
SN
SN
SN
SN
SN
SN
SN
1
NL
SN
SN
SN
SN
0
NL
WH
WH
1
0:
00 RO
32:24 RO
32:
33:
52
05 RO
2.
0.
1.
0.
68
60
02
77
Peak
0:
31:
31:
32:
32:
33:
33:
33:
34:
35:
00
31
43
02
22
19
31
54
26
:26
0.
RO
RO
RO
RO
RO
RO
RO
76-
0.
0.
1.
0.
0.
0.
0.
0.
5,
0
- Above:
1.02
74
93
12
57
48
97
53
,70
.03
.89
Peak
0
35
35
35
35
-.00
:06
:14
:26
:44
0.
RO
RO
RO
RO
.76'
0
0
3
4
0
-1.02
.63
.49
.09
.57
.98
Peaks
0
35
35
35
:00
:22
:36
:47
0
RO
RO
RO
.76
0
1
-1.02
.28
.00
0.24
1
.22
Peak
0.90
4.30
71.64 36.09
0.96
71.
HpCDD
1.
0.
1.
1.
5.
2.
2.
4.
0.
2.
5.
64
/ Octa-CDD and CDF
72
89
38
30
59 2.63
21
70
99
59
80
,59
33.93 1.035 13C12-HpCDF 789 SUR5
1.045
0.977-1.005
0.000
0.980
0.983
0.986
1.010
0.969-1.031
0.
0.
35.55 1.
1.
0.387-
0.
0.
0.
0.
5.49 0.
0.
0.
000
936
000 13C12-HpCDD 678 IS7
007
1.113
000
891
897
906
915
942
948
0.959
0,
1
.974
.002
0.887-1.113
0.96
0
0
1
1
0
.96
.21
.02
.80
.00
0
0
0
1
1
.000
.992
.996
.002 OCDD AN
.010
0.996-1.005
0
62
0
0
62
.23
.34 31.22
.91
.85
.34
0
31.12 1
1
1
.000
.000 13C12-OCDD ISS
.007
.012
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed 15:16
-------
Page No. 6 Listing of S975866B.dbf
09/17/97 Hatched OC Peaks / Ratio / Ret. Tine
Compound/
M_Z QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
Column Description "Why" Code Description QC Log Desc.
H_Z -Nominal Ion Hass(es) WL-Below Retention Time Window A-Peak Added
..RT. -Retention Time (mn:ss) WH-Above Retention Time Window K-Peak Kept
Rat.l -Ratio of M/M+2 Ions SN-Below Signal to Noise Level D-Peak, Deleted
OK -RO=Racio Outside Limits
-------
rile:S975S66 tl-905 Acq>13-SXP-1997 Oli33i37 EI+ Voltage SIX 703 Boime:75
303.9016 Tt2 BSUB(256,30, -3.0) PXD<9,S,5, 0.05%,300.0,1.00\,T, T) ExpiEPCDS
TSIANGLX LABS TexttO-M23-l TLHH30B5 1X7. TIMS " 01:36
19:00 20:00 21:00 22:00
r±le:S975866 tl-905 Aoq:13-SEP-1997 01:33:37 SI+ Voltage SIS 70S Noise:82
305.8987 T:2 BSUB(256,30,-3.0) PKD(9,5t5,0.05%,328.0,1.00\,F,T) fxptSPCOS
TRIANGLE LABS Tejct:0-M23-l TLIt43085 UKT. TIMS -
100J
80:
231 00
Olt36
19:00 20:00 21:00 22:00 23:00
File:S975866 tl-905 Acq:13-SEP-1997 01:33:37 EI+ Voltage SIR 70S Noiae:203
315.9419 T:2 BSUB(256,30,-3.0) PKD(9,5,5,0.05\,812.0,1.00\,r,T) Eip:EPCUS
TRIANGLE LABS Text:O-M23-l TLIt43085 XK7. TIME - 01:36
1004 A7.90E5
40:
20:
1 , r—i f 1 'i I i' I i 1 1 1 1—. r—T 1« -i • f • i •""< -T- |" i
ISiOO 20:00 21:00 22:00 23:00
File:S975866 tl-905 Acg:13-SEP-1997 01:33:37 EI+ Voltage SIR 70S Noiae:112
317.9389 F:2 BSUB(256, 30,-3.0 ) PKD(9, 5,5, 0. 05%, 446. 0,1. 00\,r, T) Exp:EPCUS
TRIANGLE LABS Text:O-M23-l TLIt43085 IK7. TIME - 01:36
1001
80:
60:
40:
20.
.2.7X5
.2.2ES
.1. 6E5
.1.115
.5. 4X4
-r
rr
.o.oro
Time
3.4E5
.2.7E5
.2.0E5
.1.4E5
.6.8E4
19:00 20:00 21:00 22:00 23:00
F±le:S975866 tl-905 Acq:13-SEP-1997 01:33:37 Ell- Voltage SIX 70S
330.9792 T:2 Eip:EPCUS
TRIANGLE LABS Text:O-M23-l TLI143085 ISJ. TIHE - 01:36
.o.oro
Time
20s00 21:00 22:00
rile:S975866 tl-905 Acq:13-SEP-1997 01:33:37 EI+ Voltage SIR 70S
375.8364 T:2 Exp:EPCUS
TRIANGLE LABS Text:0-M23-l TLIt43085 IXJ. TIMS - 01:36
231 00
.O.OEO
Time
-------
±10,3975866 fl-905 Acqtl3-SXP-1997 01,33,37 XX+ Volt*f» SIX 70S Half*t192
19.8965 Ti2 BSU*(256,30f-3.0) PKS(7, 5,3, 0.05\,768.0,1.00\,r,T) XxpiMTCUS
TSIANGLX LABS T«xt»O-K3J-l TUI43085 OKT. TIM* • Oil36
OC
20tOO 21', 00 22100 23,00
ile:S97S866 il-905 Acqtl3-SXP-1997 01,33,37 XI* Volt*?* SIM 70S Hoi**t175
21.8936 n2 BSUB(256,30,-3.0) PXD(7,5,3,0.05\,700.0,1.00\,r,T) XxpiEfCUS
TSIANGLE LABS TextiO-M23-l TLI»43085 ISJ. TIME - Oil36
003
sol
60:
40.
20:
0:
A1.07E4
Al.
A9.65X3
1X4
A4.82X3
IA9.35X3
A9.37E3
Al. 01X4
A1.95X3
51:00 22:00
F±leiS97S866 fl-905 Acqsl3-SEP-1997 Ols33i37 JTJ+ Volttya SIX 70S Koi*«,69
31.9368 T,2 BSUS(256,30,-3.0) PKD(7,5,3,0.05\,276.0,1.00\,r,T) XxpsEPCOS
TRIANGLE LABS Text:O-M23-l TLH43085 ISJ. TIME »
1001
80:
60:
401
20:
0.
23,00
01,36
20,00 21:00 22:00
File,S975866 tl-905 Acq:13-SEP-1997 01:33:37 EI+ Voltage SIS 70S JK>isei84
333.9338 T:2 BSUB(256,30,-3.0) PKD(7,5,3,0.051,336.0,1.00\,T,T) Exp:EPCUS
TKIANSLE LABS Text:0-M23-l TLH43085 XWT. TIME -
1001
80:
60:
40:
20:
o:
23:00
01:36
20:00 21:00 22:00
rile:S975866 fl-905 Acq:13-SEP-1997 01:33:37 EH- Voltage SIS 70S Noiae:55
327.8847 F:2 BSUB(256,30,-3.0) PKS(7,5,3,0.05\,220.0,1.00\,T,T) ExpiEPCUS
TKIAffSLE LABS T&ft:O-M23-l TLI#4308S HKT. TIMS -
1003
aol
60:
40:
20:
o.
23:00
01,36
20:00 21:00 22:00
Tile:S975866 tl-905 Acqsl3-SEP-1997 01:33:37 EH- Voltage SIS 70S
330.9792 F:2 Exp:EPCUS
TRIANGLE LABS Text,O-M23-l TLH4308S XK7. TIME
100\
80:
60:
40:
20:
o:
22,27
20100
23:00
01136
23:03
20:00
21100
22:00
23100
.H
A4.46C.
A5.34X.
.9.4X3
17.5X3
-5.6X3
.3. 8X3
.1. 9X3
.0. 0X0
Time
-2.9X5
.2.3X5
.1. 8X5
.1.2X5
.5.8X4
0.0X0
Tim.
-3.8X5
~-3. 0X5
-2.3X5
.1.5X5
.7.6X4
0.0X0
Tim
_4.3E5
.3.4X5
'-2.6X5
.1. 7X5
.8.5X4
0.0X0
23,44
-1. 7X6
.1.4X6
Ll. OE6
.7.0X5
.3.5X5
0.0X0
Tim
82
-------
rlleiS975866 #1-905 Acqil3-SEP-1997 Oli33i37 XI+ Voltage SIX 70S Hoimet5$
339.8597 7:2 BSDB(256, 30, -3. 0) PKD(7 ,5,3,0 .05\, 333.
TRIANGLE LABS TextiO-M23-l TLII43085
1004 A6.20E4
"'
60. |
:
40.
20. A3. 73X4 A9.01X3 M
o,i.oo\,r,T> XXPIXPCUS
ixr. TIMX - oii36
-3.3X4
1 > '•
! :
1
A3. 48X4 A4'.59X4 \ A1.07X4 '•
J\ ,^.«^jAJ *7'*S*\S.26X3\ It'-
o ^ /^V^ AJV JLAjl/yAA^A-, ^, f lA yVv^AA-fv 7V.A/ MAVviAJk— AJVYIA (V VA/l.AA. AlWAjta A /L A JITu A~A/<»'
24 > 00 25 : 00
2.6X4
2.0X4
.1 . 3X4
.6.6X3
0.0X0
26\00 \ 27 t 00 Time
FileiS975866 #1-905 Acgi 1J-MT-1997 Olt33t37 EI+ Voltage SIX 70S Hoim:63
341.8567 Ti2 BSUB(256, 30, -3.0) PXD(7,5, 3, 0. 05%, 252.
raXAMEV LABS Text:O-M23-l TLH43085
1001
eo:
60:
'• A9.70X4
«>-. A
20 \\
' I \A5.96X3 A1.06E4 j^4" A Al
rt ' jf V A -A. >^\jduA-» A A^. An~A - • mi «^ ^V- i^O'"*- * n n
24100 ' ' 25:00 '
0,1.00\,F,T) SxpiEPCUS \
IXT. TIMX - Oil 36
A1.89X5 ! -5.1X4
/
.46*4 , .V . *f.00*3 ,
^"^^*r**n ^* ^***L^ "^ A_*J \^^« A* * ™ ' A^A jiA _A^ AAA^ «j^
.4.1X4
.3.1X4
.2.1X4
.1 . 0X4
a .oso
2tf:00 27:00 Ti*e
rileiS975866 #1-905 Acqil3-SEP-1997 Olt33t37 EI+ Voltage SIX 70S Soiaet59
351.9000 T:2 BSUB(256, 30, -3.0) PKD(7 ,5,3,0. 05\, 236.
TRIANGLE LABS Text:O-M23-l TLI»43085
1001
80:
60:
40:
20:
0 - -T- i •
24:00 25:00
0,1.00\,F,T) ExptEPCUS
JJW. TTME " 01:36
A1.10X6 -4.815
|
A7.25E5
A
J l / \
.3 . 8E5
.2.9X5
.1 . 9X5
.9.6X4
a. oso
2ff>00 27:00 Tlae
rile:S975866 #1-905 Ac?»l 3-SEP-1997 01:33:37 EI+ Voltage SIX 70S NbiaetSS
353.8970 Tt2 BSVB(256, 30, -3. 0) PKD( 7,5, 3, 0. 05%,220
TRIANGLE LABS TextsO-M23-l TLHf43085
lOOi
sol
60:
40:
20:
o- ^ . . ^
24 1 00 25:00 '
.o,i.oo%,r,r; EXPIEPCUS
XKT. n>ffi - 01:Jff
A8.95E5 3.6X5
AS. 12X5
A
I
J V / \ n
.2.9X5
.2.2X5
.1.4X5
.7.2X4
O.OEO
'26:00 27ioO MJIC
File,S975866 #1-905 Acq:13-SEP-1997 01:33:37 XI+ Voltage SIX 70S
330.9792 T:2 Exp-.EPCVS
TRIANGLE LABS TexttO-M23-l TLH43085
1004.
•
80:
go: i ~ — 'X3iJ!>~
00 25:00
JKT. TIMS - 01:35
27jlS—*-2X6
26:03 jUjJU—0^'/^ 7i* nT;iT^J\ J
-2^52SS^^^ r
f^
•J . 4X6
.2.5X6
.1 . 7X6
.8.4X5
O.OEO
26:00 27:00 Time
rile:S975866 #1-905 Acq:13-SEP-1997 01:33:37 XI+ Voltage SIX 70S
409.7974 F:2 XxpiXPCUS
TRIANGLE LABS TexttO-M23-l TLH43085
1003
HKT. TIME - 01:3ff
1 . 7Z4
801 25,35
60: 23:39
^ 1
• R 25:lff 1
0: fy*^J\A^t\~rfU\J&^^^
24 i 00 25:00
27:36
25.52 ^jM a5,jl- 27J21I 1
LA-jLuv^_Uj__Wl\^^^
-.1.3X4
.1 . 0X4
.6.7X3
.3.3X3
-'• o.oxo
26:00 27:00 Time
83
-------
355. J
TSIM
1001
80.
60.
40.
20.
S97TB6G 91-905 Ac2 faVB(256,30,-3.0) PXD(7,S,3,0.05\r232.0,1.00\rr,T) XxptXTCUS
tSLX LABS Text:0-K23-l TLH430S5 . IJW. TIM* • Oli36
A2.08X5 6.3X4
1
j\
A7.94E3 34 A3. 67X4 A1.06X4 *1-46s4j\ ^'l3" A1.88X4
~^J^fl^ *^f^S.^f. f^A. ^J^^J^^^-^f^JV \ VMyiJWLfA^lA. ,-~r~. ^^.^AAAA
24:48 25:00 25:12 25:24 25:36 25:48 26:00 26:12 26:24 26:36 26:48 27:00 27:12 27:24 27:36
.5 . 0X4
.3 . 8X4
.2.5X4
.1.3X4
.o.oxo
Time
rile; 3975866 tl-905 Acqtl3-SXP-1997 01:33:37 EI+ Voltage SIS 70S SoimetS2
357.8516 Fi2 BSUB(256,30,-3 .0) PKD(7,5,3,0.05\r209.0,1.00\^r,T) ExpiEPCUS
TKIASSLX LABS T*xt:O-M23-l TLH43085 \ UKT. TIKE - Oil 36
1001
80.
60.
40.
20.
0'
2
Al 22E4 *2-laX4
4:48 25:00 25:12 25:24 25:36 25:48 26:00 26:12 26:24 26:36 26:48 27:00 27:12 27:24 27:36
.2.4X4
.1.9X4
.1.4X4
.9.SE3
'.4.8X3
'0.0X0
Time
Tile:S975866 tl-905 Acqil3-SEP-1997 01:33:37 EH- Voltage SIS 70S Soime:68
367.8949 F:2 BSVB(256,30,-3.0) PKD(7,5,3, 0. 05\,272. 0,1. 00%, T, T) ExptEPCUS
TRIANGLE LABS Tejtt : O-M23-1 TLI#43085 INJ. TIKE - 01:36
1001
so:
50:
40:
20:
0
A6.53E5
A7.85X4 I A,
r - r- i r - - -! i" TV - A - r . /\^ -, , - -r f - -, ^ V/^T
!4 : 48 ' 25:00 ' 25:12 25:24' 25:36' 25:48 26:00 ' 26:12 26:24 26:36' 26:48 27:0o' 27:12' 27:24 27: 36
.2.8X5
.2.2X5
.1 . 7X5
_1 . 1E5
.5.5E4
0 . OEO
Time
F±le:S975866 tl-905 Acq:13-SXP-1997 01:33:37 EH- Voltagre SIS 70S Koiae:47
369.8919 F:2 BSUB(256,30, -3.0) PKD(7,5,3, 0. 05%,188. 0,1. 00%,r, T) EipsEPCUS
TRIANGLE LABS Tert:O-J«23-l TLH43085 UKT. TIKE - 01:36
1003
80.
60.
40.
20.
0
A4 . 8X5
A1.13X5
A1.16X4 _A
1 /\ A2.19E4 1 A
^-Wrf - r ^ T -f. ^^.,-A^A. ^^ A ^ VA ^r -t ri'S rt" ' ^VA
24:48 25:00 25:12 25:24 25:36 25:48 26:00 26:12 26:24 26:36 26:48 27:00 27;12 27:24 27:36
-1 . 6E5
11.3E5
.9.7X4
.6.5E4
.3.2X4
.0.0X0
Time
F±le:S975866 tl-905 Acqil3-SEP-1997 01:33:37 XI+ Voltage SIS 70S
330.9792 T>2 XxptXPCUS
TRIANGLE LABS TejcttO-H23-l TLIt43085 IKT. TIME - 01:36
100.
80.
60
40
20.
0
5
M ..„ /C, nn^/^V^^
25:01 25 ilS A?* lj\\ /** ^^ V
VVAA' ^
V
4.2X6
\'-
.3.4X6
.2.5X6
LI . 7X6
.8.4X5
0.0X0
24:48 25:00 25:12 25:24 25:36 25:48 26:00 26:12 26:24 26:36 26:48 27:00 27:12 27:24 27:36 Time
84
-------
rile: 5975866 tl-346 Aoq»13-SXP-1997 01:33:37 EH- Voltage SIX 703 Hoi*e:1094
373.8208 F:3 BSUB(256,30,-3 .0) HO>(7,5,3, 0.05\,4376 .0,1.00\,r,T) XxpiXTCUS
TRIANGLE LABS TmxttO-M23-l TLH43085 J1K7. TIMX " 01:36
1004
80:
60:
40:
20.
0:
rile
375.
TRIA
1001
801
601
40J
20.
A5i£?" J7.JU0" A2-52W
^^A>j\^^^_^_xMA(WVW^AJv^^^%^v^AvAA~^^
28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12 30:24 30:36 30:48 31:1
-.3975866 tl-346 Acqtl3-SXP-1997 01:33:37 XI* Voltage SIX 70S «oi»e:1144
8178 r:3 BSUB(256,30,-3.0) PKD(7 ,5,3 ,0 .OS\, 4576 .0,1 .00\,T,T) XxpiXPOJS
NGLE LABS TmxttO-M23-l TLH430B5 IJKT. TIMX - 01:36
42.42*4
-6.2*4
.4.924
-3.7X4
.2.5X4
.1.2X4
.0.0X0
10 Time
..1.915
11.5*5
.1.115
.7.4*4
L J . 7*4
28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12 30:24 30:36
Tile:S97S866 tl-346 Acq:13-SEP-1997 01:33:37 El* Voltage SIB 70S JR>i*e:1149
383.8639 T:3 BSUB(256,30,-3.0) PKD(7,5,3,0.05\,4596.0,1.00\,T,T) ElptEPCUS
TRIANGLE LABS Text:O-M23-l TLIt43085 ISJ. TIME - 01:36
1004 A4.98E5
4.0.0*0
: 00 Time
80.;
60:
40:
20:
A3.67E4
A3.40*5
A2.45E5
.2.2*5
Ll. 7*5
-1. 3*5
.8.7*4
.4. 3*4
0.0*0
28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12 30:24 30:36 30:48 31:00 rifle
rile.-SS75865 #1-345 Acq:13-SEP-1997 01:33:37 EI+ Voltage SIR 70S Soiaetl283
385.8610 T:3 BSUB(256,30, -3. 0) PKD(7,5,3, 0. 05%, 5132. 0,1. 00%,r, T) Exp:EPCUS
TRIANGLE LABS Text:0-M23-l TLH43085 IWJ. TIME - 01:36
1004 A9.79E5 _4.1*5
80:
60:
40:
20:
A65
A4.70*5
L3.3*5
12.4*5
:i. 5*5
18.2*4
0 . OEO
28:12 28<24 28>J5 28:48 29:00 29:12 29:24 29:36 29:48 3ooO 30:12 30:24 30:35 30:48 31:00 Time
rile:S975866 tl-346 Acq:13-SEP-1997 01:33:37 EH- Voltage SZJZ 70S
392.9760 T:3 ExptEPCOS
TRIANGLE LABS Text:O-M23-l TLIt43085 J7W. TIME -
100J
80:
60:
40:
20:
01:35
30:36 30:50
.4.1X6
-3.2X6
1.2.4X6
.1.5*6
.8.1*5
0.0*0
28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12 30:24 30:36 30:48 31:00
rile.-S975866 4*1-346 Acq:13-SEP-1997 01:33:37 *!+• Voltage SIR 70S
445.7555 Tt3 ExptEPCUS
TRIANGLE LABS TexttO-M23-l TLH43085 INJ. TIME - 01:36
Time
1003
80:
40:
20:
OJ
28i37
.... .~ 30:46
a8>48 29,06 30,20 i
A^fci^LJl^J
2.2*4
.1. 8*4
.1.3*4
.8.8*3
14.4*3
•o.oxo
28: 12 28i24 28: 36 28:48 29: 00 29tl2 29: 24 29: 36 29: 4 8 3o:o 3012 3034 30:36 3o:48 3l:00 T±*»
85
-------
'Um:S975B6S il-346 Acq,13-3XP-1997 01,33,37 gH- Veltaga SIS 70S Hoi,.,1006
89.8156 Ti3 BSUB(256,30, -3. 0) na>(7,5,3,0.05\,4024.0,1.00\,r,T) ExptfPCUS
TRIAHSLX LASS T*xtiO-M23-l TLH43085 IXT. TIMS * 01>36
001 A2.08E4
28', 36 28:48 29s 00 29,12 29,24 29,36 29,48 30,00 30:12 30:24 30>35
ile:S975866 tl-346 Acqtl3-SEP-1997 01,33t37 EH- Voltagre SIX 70S Soim*t964
91.8127 Ts3 BSUB(256,30,-3.0) PXD(7,5,3,O.OS\,3856.0,1.00\,T,T) ExptEPCUS
TRIANGLE LABS Text:0-K23-l TLH4308S IK7. TIME * 01:36
001
28:36 28,48 29:00 29:12 29,24 29,36 29,48 30,00 30,12 30,24 30,36
rile:S975866 tl-346 Acq:13-SEP-1997 01:33,37 EH- Voltage SIX 70S No±ae:896
01.8558 T,3 BSOB(256,30,-3.0) PKD(7,5,3,0.05\,3584.0,1.00\,r,T) EipiEPCUS
TRIANGLE LABS T&xt:O-M23-l TLH43085 IK7. TIME - 01,36
004 A6.55E5
80.
60.
401
201
Al.70X4
Al.79E4
A1.14E4
Al.52E4
1.2E4
.1. OE4
.7.5E3
.5. OE3
.2.5E3
80.
60.
40:
20:
A9.98E4
A2.52E4
. A ^
A5.48E5
O.OEO
Tim,
2.7E5
2.2E5
.1. 6E5
.1. 1E5
.S.5E4
28:36 28,48 29:00 29:12 29:24 29:36 29:48 30,00 30:12 30:24
•ile,S975866 tl-346 Acq:13-SEP-1997 01,33:37 EI+ Voltage SIS 70S Hoite:799
403.8529 F:3 BSUB(256,30,-3 .0) PKD(7,5,3, 0. 051,3196. 0,1. 00%,T, T) Exp,EPCOS
TRIANGLE LABS Text:0-H23-l TLI#4308S HKT. TIME - 01:36
1004 AS. 52E5
ao:
so:
401
20:
30:36
A4.45E5
O.OEO
Tim
A6.10E4
-2.3E5
'.1.9E5
-1.4E5
-9.3E4
.4. 6E4
28,36 28,48 29,00 29:12 29,24 29:36 29,48 30:00 30,12 30,24
r±le,S975866 tl-346 Acq,13-SEP-1997 01:33:37 EI+ Voltage SIR 70S
392.9760 T:3 ExptEPCUS
TRIANGLE LABS TexttO-M23-l TLI#43085 IXJ. TIME - 01,36
30:14 30:24
80.
60.
40.
20'.
0.
30,36
30:36
O.OEO
Tin
28:38
28:52
39:33 29:31 29,41 3*I49. 39,51
-3.7E6
.3.0E6
.2.2E6
L1.5Z5
.7.5X5
28:36 28:48 29:00 29:12 29,24 29,36 29,48 30:00 30:12 30,24 30,36
O.OEO
Tim
-------
File,3975866 tl-390 Aoq:13-SEP-1997 01:33:37 Eli- Voltage SIX 70S Soiu»:»»0
407.7818 F:4 BSUB(356,30,-3.0) PKD(7,5,3,0.05\,353Q.O,1.00\,T,T) XxpiEtCUS
TRIANGLE LABS Tmxt:0-H33-l TLIt43085 1X7. TIME - 01:36
Al.76E4
31:48 32'tOO 32', 12 32i24 33i36 32,48 33,00 33,12
F1101S975866 tl-390 Acq:13-SEP-1997 01:33:37 XI+ Voltage SIX 70S Holm*,889
409.7789 Ts4 BSU3(256,30, -3.0) PJO>(7,5,3, 0.05%,3556.0,1.00\,T,T) ExptEPCVS
TRIANGLE LABS T*xt:O-M33-l TLIt43085 IKT. TIME - 01:36
1004
33134
31',48 32-00 32:12 32:24 32:36 32:48 33:00 33:12
r±le,S975866 tl-390 Acq:13-SEP-1997 01:33:37 EI+ Voltage SIX 70S Noise-.992
417.8253 F:4 BSUB(256,30,-3.0) PKD(7,5,3,0.05\,3968.0,1.00\,T,T) ExptEPCUS
TRIANGLE LABS T*xt:O-H23-l TLIt43085 INJ. TIKE - 01:36
1001 A2.40E5
33:24
80:
601
40:
20:
31:48 32,00 32:12 32:24 32:36 32:48 33:00 33:12
rile:S975866 tl-390 Actj:13-SEP-1997 01:33:37 EI+ Voltage SIX 70S Noise1829
419.8220 F:4 BSUB(256,30, -3. 0) PKD(7,5,3,0. 05%,3316.0,1. 00\,T,T) Exp:EPCVS
TRIANGLE LABS Text:O-M23-l TLIt43085 HKT. TIME - 01:36
A1.48E5
A5.48E4
A2.03E4
2.07E4
33:24
1003
ao:
60:
40:
20:
T
33:00
31li48' ' 32:00 32:12 32:24 32:36 32:48
F±le:S975866 tl-390 Acq:13-SEP-1997 01:33:37 EH- Voltage SIR 70S
430.9729 F,4 Eip-.EPCDS
TRIANGLE LABS Tsxt:O-M23-l TLIt43085 rVJ. TIME »
AS. 63E5
A3.39E5
-f
33,12
33:24
01:36
1003
sol
60:
40:
20!
33:00
31:48 32:00 32:12 32:24 33:36 32:48
r±le:S975866 tl-390 Acq:13-SEP-1997 01:33:37 EH- Voltage SIR 70S
479.7165 F:4 EipiEPCUS
TRIANGLE LABS Text:0-M33-l TLIt43085 ISJ. TIME - 01:35
31:5231:58^32:06
32:13 32:21 32:28
33:12
33:24
1. OE5
8.3E4
6.2E4
.4.1E4
.2.1E4
.O.OEO
Tiae
.2.4ES
.1.9E5
.1.4E5
9.4E4
4.7E4
O.OEO
Time
3.4E6
.2.7E6
.2.1E6
.1.4E6
.6.8E5
.O.OEO
rifle
87
-------
'ile:SS75BSS tl-390 Aotj:13-stt-19S7 01:33:37 K+ Voltage 3H 703 Boi»«.5fl7
23.7766 ri4 SSVS(3S6,30, -3.0) PXD(7,5,3,0.05\,2348.0,1.00\, f,T) XxptXTCOS
TXIAHGLX LASS Tejft,O-M23-l TUH3085 OKT. TIM* - Oil 36
00\ A3. f 3X4
33', 00 33', 06 32:12 32:18 32',24 32:30 32',36 32:42 32:48 32:54
±le:S975866 91-390 Acq:13-SEP-1997 01:33:37 XI* Voltage SIX 70S Nairn*-.533
25.7737 T:4 BSUB(256,30,-3.0) PXD(7,5,3,0.05\,2132.0,1.00\,r,T) XxptEPCUS
TRIANGLE LASS Text:0-M23-l TLH430BS IKT. TIKE - 01:36
001 A3.38E4
33\00 ' '33',06
33:12
32:00 32:06 32:12 32-.18 32:24 32:30 32:36 32:42 32:48 32:54 33:00 33:06
FileiS975866 H-390 Acq:13-SEP-1997 01:33:37 EH- Voltage SIX 70S Noiae:590
35.8169 T:4 BSV3(256, 30, -3. 0) PKD(7, 5,3 ,0 .OS\,2360 .0,1,00\,T,T) Exp:EPCUS
TRIANGLE LASS TfXt:O-H23-l TLH43085 IKJ. TIKE " 01:36
1004 A3.61ES
SOJ
so:
40:
20J
0.0EO
33:12 Time
1.5ES
'.1.2E5
.9. 2E4
.6.1S4
.3.1E4
.O.OEO
32:00 32:06 32:12 32:18 32:24 32':30 32:36 32:42 32:48 32:54 33:00 33:06 33:12 Time
rile:S975866 #1-390 Acq:13-SEP-1997 01:33:37 EI+ Voltage SIX 70S Ooiae:220
437.8140 F:4 SSU3(256,30,-3.0) PKD(7,5,3,0.OS\, 880.0,1.00\,F,T) Exp:EPCUS
TRIANGLE LASS Text:O-M23-l TLKM3085 JK7. TIKE - 01:36
1004 A3.56E5
so:
60.
40.
202
A3.68E4
-1.4ES
.LIES
.8.2E4
-5.5E4
-2.7E4
.O.OEO
32:00 32:06 32,12 32:18 32:24 32:30 32:36 32:42 32:48 32:54 33:00 33:06 33:12
Time
rile:S975866 tl-390 Acq:13-SEP-1997 01:33:37 EI+ Voltage SIX 70S
430.9729 F:4 ExpiEPCUS
TRIANGLE LASS TeJCt:O-M23-l TLH43085 JJK7. TIME -
01,36
1001
80.
60.
40.
20.
0.
32:06
32:13
32:21
32:28
^3.4X6
'.2.7X6
12.0X6
1.1.4X6
.6.8X5
.0.0X0
32:00 32:06 32:12 32:18 32:24 32:JO 32:36 32:42 32:48 32:54 33:00 33:06 33:12
Time
-------
-------
'H0.3S7SBSS 11-390 Aog:13-SXP-19!>7 01,33,37 fH- Voitag* SIS 70S Hoi*.,335
57.7377 T,4 BSWS(256,30,-3.0) PKD(7,5,3,0.05\,900.0,1.00\,r,T) XzptfPCOS
TRIANGLE LABS T*JCt,O-M23-l TLH43085 IJKT. TIM* - Oli36
35,42
35,12 35,18 35,24 35,30 35:36
ila:S975866 tl-390 Acq,13-SEP-1997 01,33,37 XI* Voltagw 9IX 70S Nairn*,359
59.7348 r,4 BSUB(256, 30, -3. 0) PXD(7,5,3, 0. 05\,1436. 0,1. 00\,r,T) ExptEPCOS
TRIANGLE LABS Text:O-M23-l TLIt43085 IHJ. TIME - 01,36
004
801
50.
401
201
35:12 35:18 35:24 35:30 35:36 35:42
.FileiS975856 #1-390 Ac
-------
-------
CM-
>ile:S975866 ttl-905 Acq: 13-SEP-1997 01:33:37 EI+ Voltage SIR 70S
115.9419 F:2 Exp.-EPCUS
>ample Text:0-M23-l TLI#43085 INJ . TIME = 01:36 File Text:O-M23-l TLI#4»
L00% A7.88E5 r2.7E5
90J
80J
70J
60 j
50 j
40J
30J
20 J
10J
0;
L2.4E5
L2.2E5
L1.9E5
L1.6E5
L1.4E5
L1.1E5
18.1E4
_5.4E4
_2.7E4
O.OEO
Time
22:12 22:24 22:36 22:48 23:00 23:12 23:24 23:36 23:48 24:00 24:12 24:24 24:36
ile:S975866 #1-905 Acq:13-SEP-1997 01:33:37 EI+ Voltage SIR 70S
17.9389 F:2 Exp:EPCUS
ample Text:O-M23-l TLI#43085 INJ. TIME = 01:36 File Text:0-M23-l TLI#4»
A9.80E5 _3.4E5
. uvu
90 J
80 j
70 J
60j
50 J
40J
30J
20J
10 J
o:
n^ . WV/.1-J— *
|
22:12 22:24 22:36 22:48 23:00 23:12 23:24 23:36 23:48 24:00 24:12 24:24 24:36
L3.1E5
L2.7E5
L2.4E5
L2.0E5
L1.7E5
L1.4E5
_1.0E5
_6.8E4
_3.4E4
O.OEO
Time
-------
'ile:S975866 #1-905 Acq:l3-SEP-1997 01:33:37 EI+ Voltage SIR 70S
119.8965 F:2 Exp:EPCUS
Jample Text:O-M23-l TLI#43085 INJ. TIME = 01:36 File Text:O-M23-l TLI#4>
24:21
1.4E4
L1.1E4
25:00
Time
20:00 21:00 22:00 23:00 24:00
'ile:S975866 #1-905 Acq:13-SEP-1997 01:33:37 EI+ Voltage SIR 70S
21.8936 F:2 Exp:EPCUS
Jample Text:O-M23-l TLI#43085 INJ. TIME = 01:36 File Text :0-M23-J. TLI#4»
L003^
24:5
i—'—'—'—'—•—!
25:00
£).OEO
Time
20 lOO 2l! 00 22iOO 23.:00 24:00
'ile:S975866 #1-905 Acq:13-SEP-1997 01:33:37 EI+ Voltage SIR 70S
31.9368 F:2 Exp:EPCUS
lample Text:O-M23-l TLI#43085 INJ. TIME = 01:36 File Text:0-M23-l TLI#4»
23,-47 2.9E5
L2.3E5
.1.8E5
_1.2E5
_5.9E4
O.OEO
20:00 21100 22:00 23:00 24iOO 25:00 Time
.l/UI
80j
60 j
40 j
0 :
1
1
1
n, ,.fWy ~^r |nnri-|^r)ft.p-j- ^ '|'"i rT 1 n»^ti|« /Spnn[n.yifi|rt r"") i lrvi"r 1
^f /
-------
'ile:S975866 #1-905 Acq: 13-SEP-1997 01:33:37 EH- Voltage SIR 70S
51.9000 F:2 ExprEPCUS
lample Text:0-M23-l TLI#43085 INJ. TIME = 01:36 File Text:0-M23-l TLI#4»
.00%
90 J
80J
70J
60J
50 J
40 J
30J
20 J
10 J
0 :
(£T. 08E6 )
I
1 1 N
A
y I J I _^_
4.8E5
L4.3E5
L3.8E5
L3.4E5
L2.9E5
L2.4E5
L1.9E5
L1.4E5
L9.6E4
14.8E4
O.OEO
' ' ' ^25!48' ' '26!6o' ' 26! 12 ' 26S24 ' 26.O6 26148 27!6o 27ll2 27.!24 27136 27148 Time
lle:S975866 #1-905 Acq:13-SEP-1997 01:33:37 EI+ Voltage SIR 70S
53.8970 F:2 Exp:EPCUS
iample Text:O-M23-l TLI#43085
INJ. TIME = 01:36 File Text:O-M23-l TLI#4»
^3.6E5
.UUl
90 J
80 J
70J
60 J
50J
40 J
30J
20 J
10 J
0 -
( f\O . 1 1 CjJ '
1 i**1
1 1 A
A
V /
A ^ -— ^V \ -r— ^ V— ~^_ - ^^, ^^^. r-T—
i^i i ^T1 i •"? "fW i T | Ii~r~r-f7~- 1 i i~~r i" i i — 1 r i — i — i — i TT~^r~r^ i i i*! — r~r-i^i r=] r— r i i < ]^~^' ' r~^ ( ' ' ' ' ' I T ' ^ ' 1 ' •
25:48 26:00 26:12 26:24 26:36 26:48 27:00 27:12 27:24 27:36 27:48
L3.2E5
L2.9E5
L2.5E5
L2.2E5
L1.8E5
Ll.4E5
11.1E5
_7.2E4
_3.6E4
O.OEO
Time
-------
ile:S975866 fl-390 Acq:13-SEP-1997 01:33:37 EI+ Voltage SIR 70S
23.7766 F:4 Exp.-EPCUS
ample Text:O-M23-l TLI#43085 INJ. TIME =
00* 32:24
32:49
ftft
03
60 J
40J
20J
01:36 File Text:O-M23-l TLI#4>
34:31 ..8.3E3
33:58
31:16
31:39
L6.6E3
L5.0E3
L3.3E3
L1.7E3
LO.OEO
32:00 33:00
ile:S975866 #1-390 Acq:13-SEP-1997 01:33:37 EI+ Voltage SIR 70S
25.7737 F:4 Exp:EPCUS
ample Text:O-M23-l TLI#43085 INJ. TIME =
00* 32;24
801
60J
40J
20 J
34:00
Time
01:36 File Text:O-M23-l TLI#4»
33:54
I I 1 1 1 1 1 1 1 1 1 1 1 1 1 r-
32:00 33:00
ile:S975866 #1-390 Acq:13-SEP-1997 01:33:37 EI+ Voltage SIR 70S
35.8169 F:4 Exp:EPCUS
ample Text:O-M23-l TLI#43085 INJ. TIME =
00* 32;52
801
60.
40 j
34!00
1.2E4
L9.5E3
_7.1E3
_4.7E3
_2.4E3
O.OEO
Time
31:22
32:00
01:36 File Text:0-M23-l TLI#4»
1.5E5
L1.2E5
L9.2E4
L6.1E4
L3.1E4
33:00
34:00
.O.OEO
Time
-------
TLI Project: 43085
Client Sample: O-M23-2
Method 23 PCDD/PCDF Analysis (a)
Analysis File: S975867
Client Project:
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
S413-004
M23Train
181-55-2ABE
1.000
n/a
DB-5
Date Received:
Date Extracted:
Date Analyzed:
Dilution Factor:
Blank File:
Analyst:
09/03/97
09/04/97
09/13/97
n/a
S975815
ML
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPX23704
SF56117
S975861
n/a
n/a
n/a
Analytes • '•".• "">... i-\J'. •.'>':
2,3,7,8-TCDD
1,2,3.7,8-PeCDD
1,2,3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
1,2,3,4.6,7,8-HpCDD
1,2,3,4,6,7,8,9-OCDD
2,3,7,8-TCDF
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
: -2,3,7,8,9-HxCDF
1,2,3,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
1,2,3,4,6,7,8,9-OCDF
Totals
Total TCDD
Total PeCDD
Total HxCDD
Total HpCDD
Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF
:••" :; Amt: (ng)
ND
ND
ND
i~i-/
ND
ND
ND
ND
ND
EMPC
ND
ND
ND
ND
FMPC
LJlVti V_^
ND
ND
ND
Amt (ng)
ND
EMPC
0.44
EMPC
ND
EMPC
EMPC
EMPC
Dt EMPP.:':!^^
0.07
0.09
n i
U.I
0.1
0.1
0.2
0.6
0.05
0.24 E
0.07
0.09
0.07
0.08
n 94. /"\c
0.2 " ~
0.2
0.4 ~
:' Numbef;:' DL : -EMPC'' '••'^^:T<^-^''-r^^:f^;^'^-'f^.j^g^/;:
0.07
1.0 SR vZOO. LMS6.10M
Triangle Laboratories, Inc.®
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 12:07 09/1
-------
TLI Project: 43085
Client Sample: O-M23-2
Method 23 PCDD/PCDF Analysis (a)
Analysis File: S975867
Internal Standards
13C,2-2,3,7,8-TCDF
13Cn.-2,3,7,8-TCDD
13C12-l,2,3,7,8-PeCDF
13C,:-l,2,3,7,8-PeCDD
13C,:-l,2,3,6,7,8-HxCDF
13C,2-l,2,3,6,7,8-HxCDD
13Cp-l,2,3,4,6,7,8-HpCDF
I3C,rl,2,3,4,6,7,8-HpCDD
13C12-1,2,3,4,6,7,8,9-OCDD
Surrogate Standards (Type A)
37CL-2,3,7,8-TCDD
13C,:-2.3,4,7,8-PeCDF
13Cp-l,2.3.4,7,8-HxCDF
13Cp-l,2,3,4,7,8-HxCDD
IJC,:-l,2,3,4,7,8,9-HpCDF
Alternate Standards (Type A}
13Cp-l,2,3,7,8,9-HxCDF
13C,2-2,3,4,6,7,8-HxCDF
Recovery Standards :-:£: ^1^
13C12-1,2,3,4-TCDD
13C,2-l,2,3,7,8,9-HxCDD
Arrrt. {ng)
3.5
3.6
3.3
4.1
3.2
3.1
1.9
2.1
2.4
AmL (ng)
4.0
3.7
3.8
3.4
4.6
Amt. (ng) :
2.3
2.9
••'?•"'?' ••••:/:';::-:-.y:-.: •''••/-:
% Recovery
88.1
90.2
82.1
102
81.0
77.6
47.2
53.2
29.8
; " ^ Recovery
100
93.1
943
85.6
116
' '• '•• -•• :-:"%' Recovery
58.2
73.7
^™^V|:S-?»V
QC Limits
40%- 1 30%
40%- 130%
40%- 130%
40%- 130%
40%- 1 30%
40%- 130%
25%-130%
25%- 130%
25%- 130%
QC Limits
70%- 140%
70%- 140%
70%- 140%
70%- 140%
70%- 140%
QC Limits
40%- 130%
40%- 130%
•^f^^/;::
Ratio
0.77
0.83
1.11
1.44
0.52
1.36
047
1.11
1.00
Ratio
1.33
056
1 31
0.42
•!•••••• Ratia--^"
055
0.47
^t^Raiio-SI
0.84
1.20
RT
23:16
23:47
26:29
27:23
29:37
30:15
32-05
32:52
35:22
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27:06
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Data Reviewer.
Page 2 of 2
09/18/97
X237.PSR vZOO. UkRSfcK
Triangle Laboratories, Inc.®
801 CapHola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Panted: 12:07 09/18/2
, I S
-------
...Date...
Data Review By:
Calculated Noise Area:
The Total Area for each peak with an ion abundance ratio outside
ratio limits has been recalculated according to method requirements.
1.02
Page No.
09/18/97
Listing o£ S975867B.db£
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2. . Rel.RT Compound.Name.. ID.. Flags.
TCDF
304-306
304-306
13C12-TCDF
316-313
316-313
TCDD
320-322
0.65-0.89
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
ML
WL
SN
SN
SN
SN
SN
SN
SN
SN
0
NL
WL
WL
WL
WL
SN
1
NL
WL
WL
WL
WL
WL
WL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
0:
18:
19:
19:
20:
21:
22:
22:
22:
22:
22:
00
27
27
43
41
20
00
14
25
37
50
RO
RO
RO
RO
RO
RO
RO
1.
1.
2.
3.
4.
1.
0.
0.
0.
2.
0.
27
03
47
15
86
15
73
69
si
14
37
Peaks
0:
18:
00
27
19:26
20:
03
20:15
22:
23
:21
:16
0.
RO
RO
RO
RO
RO
RO
0.
0.
2.
2.
0.
3.
5.
1.
3.
1.
2.
0.
19
57
37
76
39
59
04
49
90
13
21
00
65-0.89
1.
0.
1.
0.
24
24
46
33
1.16
2.84
0.
Peak
0
19
19
20
20
20
20
21
21
21
21
21
22
22
22
22
23
:00
:23
:43
:10
:22
:29
:38
:07
:13
:25
:46
:54
:03
:15
:34
:43
:29
0.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
.77
65-0.89
0
2
0
0
0
0
1
1
0
0
1
1
0
1
0
2
1
.75
.27
.61
.48
.65
.27
.35
.84
.54
.94
.22
.49
.56
.53
.84
.00
.38
0.
0.
0.
0.
1.
0.
154,
37
37
96
32
22
.65
.49 67.28
0.838-
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.092
000
793
836
347
889
917
946
956
963
972
981
0.954-1.046
0.
0.
0.
0.
0.
0.
87.21 1.
000
793
335
362
870
.961
.000 13C12-2378-TCDF ISO
154.49
0
0
1
0
1
0
0
0
1
1
0
0
0
0
0
0
.35
.39
.24
.87
.17
.48
.87
.34
.03
.72
.41
.83
.85
.27
.57
.51
0.65
0.875-1.055
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.000
.819
.829
.348
.856
.861
.868
.888
.892
.900
.915
.921
.927
.936
.949
.955
.987
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 12:01 09/18/97-
98
-------
Page No.
09/18/97
Listing of S975867B.dbf
Matched (X Peaks / Ratio / Ret. Time
Compound/
M_2.... QC.Los Omit Why ..RT. OK Ratio Total.Area... Ar.a.P.ak.1.. Ar.a.Peak.2.. Rel.RT Compound.Name.. ID.. Fla,s.
DC
320-322
37C1-TCDD
328 DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
328
13C12-TCDD
332-334 DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
332-334
SN
0
NL
WL
ML
WL
WL
WL
WL
WL
WL
WL
WL
WL
WL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
2
NL
WL
WL
WL
WL
WL
SN
SN
SN
SN
SN
SN
SN
SN
2
23:40
Peaks
0:00
19:42
19:57
20:00
20:09
20:09
20:24
20:27
20:36
20:54
21:02
21:18
21:29
21:43
21:53
22:01
22:16
22:27
22: 34
22:41
22:52
23:05
23:19
23:27
23:39
23:47
Peaks
0
19
20
20
20
21
21
21
22
22
22
22
23
23:
:00
:39
:06
:18
:35
:09
:40
:52
:00
:12
:21
:50
:12
:25
RO
0.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
23:36
23:47
Peaks
1
65-
3
1,
1,
11.
2
1.
4.
1
4
1
5.
0
0,
1,
0,
0,
.92
-0.89
.54
.87
.35
.75
.04
.50
,19
.44
.26
.42
.47
.46
.55
.41
.84
.83
1
0
0
9
0
0
0
0
0
0
0
0
0
0
0
1
0
0
1
1
0
0
0
0
0
0
12
108
120
0
6
0
0
0
0
0
0
0
0
0
1
1
2
132
127
260
.40
.00
.16
.29
.33
.10
.17
.20
.21
.30
.66
.64
.15
.47
.88
.09
.51
.31
.04
.15
.26
.71
.49
.51
.13
.49
.85
.07
.92
.23
.48
.35
.14
.87
.25
.64
.96
.67
.64
.27
.52
.08
.21
.99
.81
.80
0.995
0.910-1.090
0.000
0.828
0.839
0.841
0.847
0.347
0.858
0.860
0.866
0.879
0.884
0.896
0.903
0. 913
0.920
0.926
0.936
0.944
0. 949
0.954
0.961
0.971
0. 980
0.986
12.85 0.994
108 -07 1.000 37C1-TCDD SUR1
0.910-1.090
o. ooo
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
SO. 76 72.23 0.
57.91 69.90 1.
826
845
854
865
389
911
919
.925
933
940
960
975
.985
992 13C12-1234-TCDD RSI
000 13C12-2378-TCDD IS1
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed 12:01 09/18/9'
Q<
-------
Page No.
09/18/97
Listing of S975867B.dbf
Matched GC Peaks / Ratio / Ret. Tin
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
PeCDF
340-342
E
E
340-342
13C12-PeCDF
352-354
N
N
352-354
PeCDD
356-353
356-358
13C12-PeCDD
368-370
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
WL
WL
WL
(§y
SN
SN
SN
SN
\E..
SN
SN
SN
2
NL
SN
SN
SN
SN
SN
3
NL
WL
WL
WL
SN
SN
SN
SN
SN
1
NL
SN
SN
SN
SN
0:
23:
23:
24:
24:
25:
25:
26:
26:
26:
27:
27:
27:
00
29
40
30
53
20
55
08
1.32-1.78
RO 1.00
RO 0.89
RO
RO .
RO
RO
RO
RO
21 RO
32@
02 RO
27
45
RO
RO
0.
0.
1.
0.
0.
2.
9.
0.
0.
3.
4.
23
61
40
18
78
72
48
17
70
78
40
Peaks
0:
23:
24:
25:
26:
00
39
58
26
04
1.
RO
RO
RO
RO
RO
26:12
26:29(RO;
26:57
27:
:06
TULfU
0.
0.
8.
0.
5.
0.
1.
1.
0.
8.
0.
1.
3.
14.
16
66
01
44
86 3.56
53
09
63
79
29 5.04
94
02
09
15
32-1.78
1.
0.
7 .
0.
1.
20
68
83
48
21
1.70
1.11
1.37
1.
Peaks
0
24
25
25
25
25
26
26
26
27
:00
:48
:09
:27
:39
:50
:14
:30
:47
:36
1.
RO
RO
RO
RO
RO
RO
RO
RO
RO
.33
32-1.78
1
2
1
1
1
0
2
3
0
0
.09
.13
.26
.09
.51
.72
.07
. 05
.78
.33
Peak
0
25
25
26
26
26
:00
:12
:23
:10
:30
:59
1
RO
RO
RO
RO
RO
0.
9.
0.
20
92 6.03
61
0.44
1.
.63
2.13
123.77 75.23
5.93
111
245
PeCDl
0
0
0
0
1
0
1
27
0
0
27
.72 63.86
.41
.20
.20
.72
.41
.43
.46
.05
.95 33.38
.69
.58
.95
.32-1.78
0
0
1
0
0
0
.92
.40
. 57
.38
.44
.62
0
0
0
0
14
.18
.56
.95
.58
.99 9.11
0.64
0.915-1.074
0.000
0.867
0.
0.
2.54 0.
0.
0.
0.
0.
29.97 0.
0.
1.
1.
0.844-
0.
8.92 0.
0.
0.
0.
0.
67.88 0.
0.
47.86 1.
873
904
918
935
956
964
972
979 12378-PeCDF AN (Q ^
998
013
024
1.156
000
873
921
938
962
967
977 13C12-PeCDF 123 IS2 p
994 **-•"
000 13C12-PeCDF 234 SUR2
0.926-1.024
0.
0.
0
0
0
0
0
10.96 0
0
1
.000
. 902_
.915
.925
.933
.939
.954
.964 (Q]
.974
.004
0.850-1.150
0
0
0
0
20.64 0
0
.000
.916
.923
.952
.964
.981
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 12:01 09/18/97
»100
-------
Page No.
09/18/97
Listing of S975867B.«Jbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area...
Area.Peak.l.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
N
N
368-370
HxCDF
374-376
EK
374-376
isc12-HXCDF
384-386
N
N
N
N
N
384-386
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
SN
SN
3
NL
WL
WL
\§'
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
en
0
SN
2
NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
27:08
27:23
27:30
27:41
Peaks
0:
28:
28:
28:
29:
29:
29:
29:
29:
29:
29:
29:
29:
30:
30:
30:
30:
30:
30:
30:
00
33
41
49
03
09
21
32
35
45
49
53
58
06
11
24
33
37
44
57
RO
RO
1.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
£0)
RO
1,
1
1
0.
.00
.44
.56
.52
,05-1.43
1,
1,
0,
1,
0,
2.
0.
1,
0.
0.
1.
3.
1
1.
0,
0.
0.
0.
0.
0,
.02
.35
.25
.40
,57
.03
,49
,80
.39
.62
.79
.50
.20
, 15
.56
,37
.45
,75
.89
.05
Peaks
0:
28:
28:
28:
28:
28:
23:
28:
29:
29:
29:
29:
30:
30:
30:
00
18
25
29
35
49
54
58
13
16
33
37
04
11
33
0.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
30:44
DC
SN
5
30:
55
RO
43-0.59
0.
0.
3,
0.
0
0
0.
0
1.
4,
0
0.
0.
0
1
0,
1
.94
.70
.46
.19
.39
.79
.54
.36
.13
.36
. 56
.52
.47
.82
.68
.55
.56
Peaks
0.67
86.32
10.69
0.23
112.00
1.81
1.48
0.13
6.97
0.47
0.65
0.45
1.10
0.45
1.28
0.94
1.03
1.23
3.09
1.63
0.70
1.32
1.32
6.63
0.20
13.60
1.01
0.69
0.20
0.50
0.80
9.44
1.05
0.63
0.47
0.17
89.18
98.61
83.08
1.10
1.45
57.08
0.83
337.39
50.92
6.52
Follows
0.987
35.40 0.996 13C12-PeCDD 123 IS3
4.17 1.000
1.007
4.35
3.67
AN
AN
AN
AN
4.91
32.02
33.78
26.72
20.26
0.959-1.050
0.000
0.950
0.954
3.11 0.958
0.966
0.970
0.976
0.982
0.984
0. 989
0.992
0. 994
0.997 123478-HxCDF
1.001 123678-HxCDF
1.004
1.011
1.016
1.018 234678-HxCDF
4.12 1.022 123789-HxCDF
1.029
0.863-1.137
0.000
0.941
0.945
0.947
0.951
6.25 0.958
0.961
0.963
0.972
0.973
57.16 0.983 13C12-HXCDF 478 SUR3<
64.83 0.985 13C12-HxCDF 678 IS4
56.36 1.000 13C12-HXCDF 234 ALT2 <
1.004
1.016
36.82 1.022 13C12-HXCDF 789 ALT1|
1.028
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 12J>1 09/18/S
101
-------
Page No.
09/18/97
Listing of S975867B.dbf
Matched GC Peaks / Ratio / Rat. Time
Compound/
M_Z QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
HxCDD
390-392
K
D
390-392
13C12-HXCDD
402-404
N
N
N
402-404
HpCDF
408-410
408-410
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
WL
WL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
WH
1
NL
WL
WL
WL
WL
WL
SN
4
NL
SN
SN
1
0:
28:
28:
28:
29:
29:
29:
29:
29:
29:
29:
29:
29:
30:
30:
30:
30:
30:
30:
00
39
48
54
09
16
20
29
34
36
44
47
53
02
10
12
18
36
45
1.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
ADOVe: HXCDF
05-1.43
0.
0.
1.
0.
1.
1.
0.
0.
0.
0.
1.
1.
1.
2.
0,
0,
1,
0.
1
83
35
34
86
14
23
53
23
25
63
,07
32
.23
.87
,59
.14
.88
.75
. 19
Peak
0:
28:
28:
29:
29:
29:
29:
30:
30:
30:
30:
00
40
49
11
15
20
32
11
15
31
43
1.
RO
RO
RO
RO
RO
RO
RO
RO
0.
0.
9.
1.
1.
1.
0.
0.
0.
0.
0.
0.
0.
0.
1.
0.
0.
1.
10.
9.
/ HXCDD Follows
99
13
02 5.17
19
50
05
89
33
14
47
91
95
78
69
05
20
58
28
16
02
05-1.43
0
2
2
0
2
5
2
1
1
1
1
Peaks
0:
32:
32:
33:
00
23
40
05
0,
RO
RO
RO
.87
.93
.23
.33
.25
.43
.78
.31
.36
.20
.85
,88-1.20
1
1
1
1
. 67
.79
.13
.77
Peak
1.
1.
16.
1.
0.
0.
0.
65.
78.
101.
18.
39
03
89
03
63
52
20
09 36.92
12 45.06
17 55.23
91 15.60
0.953-
0.
0.
3.85 0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
1.
0.967-
0.
0.
0.
0.
0.
0.
0.
28.17 0.
33.06 0.
45.94 1.
8.44 1.
1.014
000
939
944
947
955
959
961
966
969
970
974
976
979
984
989
990
993
003
008
1.033
000
939
944
956
958
961
968
989 13C12-HXCDD 478 SUR
991 13C12-HXCDD 678 IS5
000 13C12-HXCDD 789 RS2
007
263.29
1.
5.
0.
2.
5.
.98
22 4.59
96
.18
.22
0.995-1.042
0.
2.56 1.
1.
1 .
000
009
018
031
13C12-HPCDF 0.37-0.51
418-420 DC NL 0:00 RO 1.24
DC SN 31:58 RO 2.80
32:05 0.47
32:23 RO 1.43
1.48
0.66
42.38
8.57
13.48
8.53
0.937-1.125
0.000
0.996
28.90 1.000 13C12-HpCDF 678 IS6
5.95 1.009
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 12:01 0!
-------
Page No.
09/13/97
Listing of S975867B.dbf
Matched GC Peaks / Ratio / R«t. Tin
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Conpound.Nam*. . ID.,
Flags.
418-420
HpCDD
424-426
424-426
13C12-HpCDD
436-438
436-438
OCDF
442-444
442-444
OCDD
458-460
458-460
13C12-OCDD
470-472
470-472
DC
DC
DC
SN
SN
SN
3
32:41 RO
32:52 RO
33:13
33:31 RO
Peaks
0.63
0.65
0.42
0.57
0.88-1.20
DC
NL
0:00
32:22 RO
DC
WH
1
33:08 RO
0.95
0.64
0.45
Peak
0.88-1.20
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
SN
SN
SN
SN
1
NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
0:
32:
32:
32:
32:
33:
00
02
11
22
52
14
RO
RO
RO
RO
RO
2.38
0.24
1.75
1.38
1.11
3.10
Peak
0:
;00
32:02
32
32
33
33
33
34
35
35
35
35
:22
:56
:09
:14
:53
:44
:03
:09
:26
:32
0.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
76-1.02
0.65
0.61
0.41
2.19
0.21
1.67
0.38
1.67
0.43
0.89
0.42
2.19
2 Peaks
0.76-1.02
DC NL 0:00 RO 1.38
0 Peaks
0.76-1.02
DC NL 0:00 0.93
35:22 1.00
1 Peak
0.66
2.43
37.78
1.27
88.73
1.21
11.35
1.53
11.85
0.59
0.31
1.45
2.98
43.39
1.06
43.39
11.15
Follows
6.04
1.019
1.024
26.63 1.035 13C12-HpCDF 789 SUR5 Q
1.045
23.07
0.977-1.005
0.000
9.37 0.985
1.008
0.969-1.031
0.000
0.975
0.979
0.985
20.82 1.000 13C12-HpCDD 678 IS7
1.011
HpCDD / Octa-CDD and CDF Follows
1.40
1.17
11.70
0.51
0.42
0.68
3.22
0.93
1.36
1.78
4.38
2.25
19.92
0.15
0.00
0.27
31.27
31.27
5.51
3.87
15.60
0.887-1.113
0.000
0.906
13.44 0.915
0.931
0.937
0.940
10.30 0.958
0.982
0.991
0.994
1.002
1.005 OCDF
0.887-1.113
0.000
0.996-1.005
0.000
15.67 1.000 13C12-OCDD
AN
IS3 Q
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 12:01 09/18/J
103
-------
Page No.
09/18/97
Listing of S975867B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
Column Description "Why" Code Description QC Log Desc.
M_Z -Nominal Ion Mass(es)
. .RT. -Retention Time (mtn:ss)
Rat.l -Ratio of M/M+2 Ions
OK -RO=Ratio Outside Limits
Rel.RT-Relative Retention Time
End o f Report
WL-Below Retention Time Window
WH-Above Retention Time Window
Sit-Below Signal to Noise Level
-------
il»>S975867 tl-905 Aajtl3-SXP-1997 02tl2i56 XI+ Voltage SIS 70S HOimoift
03.9016 T:3 BSOB(256,30,-3.0) PKD(9,5,S,O.OS\,272.0,1.00\,T,T) KxptXPCUS
TRIANGLE LAIS T*xt:0-N23-2 TLH43085 XK7. TIMX - 02:15
19:00 20,00 21,00 22,00
ile,S975867 tl-905 Acq,13-SXP-1997 02,12:56 XI+ Voltaye SIX 70S Noif»,54
05.8987 F:2 BSU»(256,30,-3.0) PKD(9,S,S,0.05\,216.0f1.00\,f,T) XxpiXPCOS
TRIANGLE LABS Tejct:O-M23-2 TLH430B5 IKT. TIMX - 02:15
001
19:00 20:00 21:00 22,00
File,S975867 tl-905 Acq:13-SXP-1997 02,12,56 EH- Voltage SIX 70S Noiae:128
15.9419 F,2 BSUB(256,30,-3,Q) PKD(9,5,5,0.05\r512.0,1.00\,T, T) ElpsEPCUS
TRIANGLE LABS Text:O-M23-2 TLI#43085 ItU. TIME - 02:15
001
sol
50:
40J
A2.33E4
Al. 74X4
A2.13E4
A1.28X4
23:00
23:00
A6. 73E5
19,00 20,00 31:00 22:00
File:S9758S7 tl-905 Acq,13-SEP-1997 02,12:56 EI+ Voltage SIX 70S NOiae,103
317.9389 Fi2 BSUB(256,30, -3 . 0) PKD(9,5,5, 0. 05\,412. 0,1. 00\,r, T) ExpiEPCUS
TSIANGLE LABS Text:O-H23-2 TLHH3085 JTWJ-. TIKE - 02:15
1003
80:
so:
40:
20:
01 • - - - i (k__
23:00
A8.72E5
19:00 20:00 21:00 22:00 23:00
rile:S975867 #1-905 Acq:13-SEP-1997 02,12,56 Eli- Voltage SIX 70S
330.9792 T:3 EzpiEPCVS
TRIANGLE LABS Text:0-M23-2 TLIt43085 INJT. TIKX - 02,15
1001
.O.O.EO
Time
-2.4X5
-.1. 9E5
Ll.4E5
1.9.4X4
.4.7X4
O.OEO
Tia
.3.2X5
.2. 5E5
.1. 9E5
.1.3X5
.6.3X4
O.OEO
Tim
19:00 20,00 21:00 22:00
File,S975867 tl-905 Acq:13-SXP-1997 02:12:56 EH- Voltage SIX 70S
375.8364 T:3 Xxp:XPCUS
TXIANGLX LABS Text:O-M23-3 TLIt43085 XK7. TIME -
J004
23:00
02:15
19:00
20:00
21:00
22:00
23,00
105
-------
ilo,S975867 tl-905 Acqtl3-SXP-1997 02:12:56 XI+ Voltage SIX 70S Noise:76
19.8965 T:2 BSU3(256,30,-3.0) PKD(7, 5,3, 0.05\,304.0,1.00\,f,T) XxpiXTCUS
TRIANGLE LABS Text:O-M23-2 TU#43085 TJC7. TIMX " 02:15
Al.0814
20:00 21:00 22:00 23:00
ile:S975867 tl-905 Acqtl3-SXP-1997 02:12:55 EI+ Voltage SIS 70S N6imei98
21.8936 T:2 BSOB(256,30,-3.0) PXD(7,5,3, 0.05\,392. 0,1. 00\,r,T) EzptSTCOS
TRIANGLE LABS Text:O-M23-2 TLIt43085 ISJ. TIMS - 02:15
00>
.0614
20:00 21:00 22:00 23:00
File:S975867 tl-905 Acqsl3-SEP-1997 02:12:56 EH- Voltage SIR 70S Noise:231
331.9368 F:2 BSUB(256,30, -3. 0) PKD(7,5,3,0.051,924.0, 1.00\,F,T) Exp:£PCUS
TRIANGLE LABS TexttO-M23-2 TLH43085 INJ. TIME - 02:15
1003
80:
50:
40:
20:
80:
50:
40:
20:
0.
A7.00X3
A8.50E3
\3.81C3
A4.55E3
A3.63X3
AM/
15.3*3
L4.0r3
.2.7X3
.1.3X3
lo.oxo
Time
20:00 21:00 22:00 23:00
rile:S975867 tl-905 Acq:13-SXP-1997 02:12:56 EI+ Voltage SIR 70S Noiae:64
333.9338 T:2 SSUB(256,30,-3.0) PKD(7, 5,3,0.05\,256.0,1.00\,f,T) Elp:EPCDS
TRIANGLE LABS Text:O-M23-2 TLIt43085 JWJ. TIME - 02:15
100]
80:
50:
40:
20:
o:
20:00 21:00 22:00 23:00
rile:S975867 tl-905 Ac00
.2.4E5
-.1.9X5
.1.4X5
.9.6E4
14. 8X4
O.OEO
Tim-
4.1E5
.3.2X5
12.4X5
Ll. 5Z5
.8.1X4
LO.0X0
Tim
23:42
-1.6E6
-1.3X6
.9.4X5
.6.3X5
.3.1X5
O.OEO
106
-------
rile:S975B67 #1-905 Acqil3-3XP-1997 02tl2i56 EI+ VoltMym SIX 70S Nairn*>53
339.8597 Til BSVt(256, 30,-3.0) PKD(7, 5,3, 0.05\,208.0,1.00\,r,T) ExpiETCOS
TMIAHSZJC LABS Tttxt.O-M2.3-2 TLH43085 XX7. TXMZ - 02*15
100* A5\04X4
34.00 35.00
riles S975867 #1-905 Acq,13-SEP-1997 02:12tSS
25.00
Volt*9* SIX 70S Hoif*
341.8567 f,2 BSOB(256,30,-3.0) PKD(7, 5,3, 0.05\,208.0,1.00\,f,T) ExpiEXCOS
TXIAWSZE LABS
1004
T*xt:O-H23-2 TLIf43085
80:
50:
40:
20:
o.
IKT. TIKE
A3.
27 tOO
s52
02/15
A2.12E5
A2.54E4 A1.76E4
A2.30E4
A6.39E5
24.00 25.00 25.00 , 37-00
rile,S975867 #1-905 Acq,13-SEP-1997 02,12,56 EH- Voltage SIX 70S Noiaas60
351.9000 T:2 BSOB(256,30,-3.0) PKD(7,5,3,0.05\,240.0,1.00\,r,T) ExptEBCUS
TRIANGLE LABS Text .-O-M3J-3 TLI #43085 JNJ. TIKE- 02,15
100* A7.52E5
80:
50:
40:
20:
: A6.03E4
24:00 25,00 26,00 27,00
rlle:S975867 #1-905 Acq,13-SEP-1997 02,12,56 EH- Voltage SIX 70S NOima,52
353.8970 r,2 BSUB(256, 30,-3 .0) PXD(7, 5, 3, 0. OS\,208. 0,1. 00\,T, T) ExptEPCOS
TSIANSLE LABS Text,0-M23-2 TLH43085 IXJ. TIME - 02.15
1004 A6.79E5
80:
50:
40:
20.
AB.92E4
.79E5
24,00 25,00 26,00 27,00
rilesS975867 #1-905 Acq,13-SEP-1997 02,12,56 EH- Voltage SIX 70S
330.9792 r,2 ExpsEPCOS
TXIANGLE LABS Teit,O-M23-2 TLH430B5 IXJ. TIME - 02,15
1003)
25.21
_1.OE5
•.8-.2E4
.6.2X4
'.4.1E4
•-2.1E4
O.OKO
,.2.9E5
'.2.4ES
-1. 8E5
.1.2S5
.5.9E4
O.OEO
Tim
.2.7E5
12.1Z5
'.1.6ES
ll.lES
.5.4E4
O.OEO
Tim
80:
50:
40.
20:
36,42
27,38
25,59
23,53 34i10.
^3 . 8E6
_J . OIT5
-_2.3
-------
F3.J.e:S97Sa67 tl-905 Acqtl3-SXP-1997 Oitlit56 XI* Voltage SIX JOS Holme: 00
355.8546 Ti2 BSUB(256, 30, -3.0) PKD(7, 5,3, 0.05\,240. 0,1.00\,r,T) XxpiXPCUS
TKIAHGLX LASS Text,O-H23-2 TLI44308S 1X7. TZMX - 02,15
lOOt:
80.
60.
40.
20.
0.
A3. 34X5
h
/ - L *
24\48 25\bb 25*112 25T:24 25\36 '25\48 26\bo 26\12 26\24 26':36 26^48 27\'oO 27\'l2 27\24 27\36
.9.1X4
.7.3X4
.5.5X4
.3 . 7X4
.1 . 8X4
0.0X0
Time
rile ,3975867 #1-905 Acq,13-SXf-1997 02,12,56 EH- Voltage SIS 70S Koimei54
357.8516 F:2 BSUB(256, 30, -3.0) PKD( 7,5, 3, 0. 05\,216 . 0,1.00\,r,T) XxpiXPCUS
TRIANGLE LABS TmjctiO-M23-2 TLI#43085 IX J. TIME * 02:15
1004
80.
60.
40:
20:
o:
Al. 0X5
\
,
A It
I *\A8.90E3 1
AJ.4«tb A3.90E3 A/ V A A1.19X4
24:48 25:00 25:12 25:24 25:36 25:48 26:00 26:12 26:24 26:36 26:48 27:00 27:12 27:24 27:36
.3.3X4
.2.7X4
.2.0X4
.1.3X4
.6.6X3
0.0X0
Time
FileiS975867 #1-905 Acq:13-SEP-1997 02:12:56 Eli- Voltage SIS 70S N6iae,S6
367.8949 r,2 BSUB( 256, 30, -3 . 0) PKD(7, 5, 3, 0 . 05\,224. 0, 1 . 00\,f, T) ExpiEPCUS
TRIANGLE LABS Text:O-M23-2 TLI#43085 JKT. TIHX ' 02,15
ion.
so:
60:
40:
20:
0.
AS . 09X5
A9.11E4 I \
24,48 25,00 25,12 25:24 25,36 25:48 26:00 26,12 26:24 26,36 26,48 27:00 27:12 27:24 27,36
.2.3X5
'.1 . 8X5
.1 . 4X5
.9.2X4
'.4.6E4
' 0 . OEO
Time
rile:S975867 #1-905 Acq:13-SEP-1997 02:12:56 EI+ Voltage SIS 70S Unite, 58
369.8919 T:2 BSUB(256, 30, -3.0) PKD(7, 5,3,0 .05\,232. 0,1. 00\,r,T) Exp:EPCVS
TRIANGLE LABS TeJct:0-M23-2 TLH430SS INJ. TIME - 02,15
1003
80.
60.
40.
20.
0.
A3. 54X5
1
A2.06E5
A l\
24:48 25:00 25tl2 25:24 25:36 25:48 26:00 26:12 26,24 26:36 26:48 27:00 27:12 27:24 27:36
rl . 6E5
.1.3X5
.9.6X4
.6.4X4
.3.2X4
Tims
r±le>S975867 #1-905 Acq:13-SXP-1997 02:12:56 XI+ Voltage SIR 70S
330.9792 F:2 XxpiEPCUS
TRIANGLE LABS T*Xt,O-M23-2 TLI#43085 IKT. TIME - 02:15
lOOi
80.
60.
40.
20.
0.
\ 27i26
26:42 jf-c-, 27:05 A. /»./%. A.
26,21 26:36A 36>*3 "i" 27:16 \f^\ /\
25:59 /> /S^V\ J\ f\l\~f\J\ / * V
25:41 y/Vv/?f*l/ \f\ 1 \ 1 \f >/
25:00 ^^5,23 J\ f ^V^ V \ \l V
\s
r3.8X6
'.3.0X6
.2.3X6
.1.5X6
.7.6X5
24':48 25',00 25\12 25':24 2S\36 2S':48 26l,bb 26\12' 26\24' 26\ 36 ' jtfiifl' i?ioO ' 27\12 27',24 ' 27\ 36 Time
-------
ila:3975867 H-346 Acq:13-SEP-1997 02,12,56 EI+ Voltage SIR 70S Noif*:498
73.8308 T:3 BSUB(256r30,-3.0) PKD(7,5,3,0.05\,1992.0,1.00\,r,T) XxptXTCOS
TRIANGLE LABS T*xttO-M23-3 TLH43085 IHJ. TIMX - 02:15
OOJ
80:
50:
40:
20: A4.35X4
28:12 28,24 28,36 28:48 29:00 29,13 29,24 29:36 29,48 30:00 30\12 30\24
He-.8975867 #1-346 Acq:13-SEP-1997 02:12:56 EI+ Voltage SIR 70S Noift»491
75.8178 F:3 BSUB(256,30,-3.0) PKD(7,5,3,0.05\,1964.0,1.00\,r,T) Xxp,EPCDS
TRIANGLE LABS T*xt:O-H23-3 TLH43085 IJKT. TIMX - 02,15
00]
80:
50:
40:
20:
A3.11JE4
28,12 28,24 28,36 28:48 29,00 29:12 29:24 29:36 29:48 30:00 30:12 30:24 30:36 30:48
rile:S975867 #1-346 Acq,13-SEP-1997 02,12:56 EI+ Voltage SIS 70S NOia*:316
83.8639 F:3 BSUB(256,30, -3. 0) PKS(7, 5,3, 0. 05\f1264. 0,1. 00\,r, T) Exp:EPCUS
TRIANGLE LABS T*xt:O-M23-2 TLH43085 IKJ. TIME - 02:15
1004
AS.48X3
,» A _rfL_,
AS. 83X3
Al .61X4
. 05X3
A3.67Xf
.8.4X4
.6.7X4
.5. t*4
.3.3X4
.1. 7X4
.0.0X0
0i4« 31i«« ZlM
.1.4X5
Lt.AM
,7.0X4
.3.3X4
A4.12S4
-Pi
.a. oxo
ao:
so:
4o:
20:
o:
A3.38E5
A4.91E4
A2.67E5
A2.03X5
31:00 Tim*
-2.0ES
l.fXS
^1.2*5
.7.9X4
.4.0X4
28:12 28:24 28:36 38:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12 30:24
rile:S975867 tl-346 Acq:13-SEP-1997 02:12:56 EI+ Voltage SIR 70S »oiae:337
385.8610 Ts3 BSUB(256,30r-3.0) PKD(7,5,3,0.05\,134S.0,1.00\,r,T) ExpsEPCVS
TRIANGLE LABS Text:O-M23-2 TLI«43085 INJ. TIME - 02:15
A6.48E5
A5.64E5
30:36 30:48
.O.OEO
31': 00 Tim*
1003
80:
50:
40:
20:
0.
A6.25S4
A3.68X5
-2.6S5
\.2.1E5
.1. 6E5
.1. OE5
.5.2E4
-tH
28,12 38,24 28:36 28,48 29,00 29:12 29,24 29:36 29:48 30:00 30:13 30:34
r±le:S975867 #1-346 Acq:13-SEP-1997 02,12:56 EI+ Voltage SIR 70S
392.9760 F:3 Xxp:EPCUS
TRIANGLE LABS T*xt:O-M23-2 TLHH3085 IJKT. TIME - 02:15
1003,
30:20
29:20
30:36 30:48
.O.OEO
31>00 Tim
80:
50:
40:
20:
o:
30:34
30:47
28:08
28:21 28:36
.3.8E6
.3.0X6
'.3.3E6
1.1.5E6
.7.6X5
38:13 38:34 28:36 28:48 29:00 29:13 39:34 39:36 39:48 30:00 30:13 30:34
File:S975867 #1-346 Acgsl3-SEP-1997 03:12:56 EI+ Voltage SIR 70S
445.7555 Ts3 Sxp:EPCUS
TRIANGLE LABS T*xt:O-M23-2 TLI#43085 INJ. TIME ' 02:15
1001 28 47
80:
60:
40:
30:
0:
30:36 30:48
O.OEO
31': 00 Timm
30:44
.2.8X4
13.3X4
'•.1.7X4
a. 1x4
.5.6X3
JO.55
.0.0X0
28': 12 38:34 28:36 38:48 29s00 29\ 13 39',24 29',36 29',48 30',00 30:12 30:24 30:36 30:48 31:00 X*»
-------
'i±e,S9758S7 11-346 Aoj:13-SXP-1997 02,12,56 XH- Voltage SIS 70S *oiie,-J7t>
89.8156 r,3 BSUB(256,30,-3.0) PKD(7,5,3,0.05\,1104.0,1.00\,f,T) XrptXPCDS
TRIANGLE LABS Te*t:O-M23-2 TLI443085 OtJ. TIME - 02,15
AS.17X4
28:36 28',48 29', 00 29', 12 29,24 29', 36 29', 48 30tOO 30', 12 30',24 30,36 Time
iletS975867 tl-346 Aoqil3-SXP-1997 02,12,56 EH- Voltage 3IS 70S Hoi*e,331
91.8127 r,3 BSOB(256,30,-3.0) PKD(7,5,3,0.05%,1324.0,1.00\,r,T) XxptXPCOS
TRIANGLE LABS Text:O-M23-2 TLH43085 IKT. TIME - 0.3(15
00$
A3.85X4
28': 36 28': 4 8 29': 00 29': 12 29': 24 29': 36 29': 4 8 30':00 30:12 30:24
rile-.S975867 tl-346 Acg:13-SEP-1997 02:12:56 EH- Voltage SIR 70S Soiaes387
01.8558 r-.3 BSVB(2S6,30,-3.0) PKD(7,5,3, 0. 05 \,1548. 0,1.00%,T, T) ExptEPCVS
TRIANGLE LABS Teit:O-M23-2 TLH43085 HtJ. TIME - 02:15
1001 A5.
80J
so;
40:
20.
30:36
2E5
A4.51E5
Al.68X5
A
Time
2.3X5
1.9X5
LI. 4X5
.9.3X4
.4.7X4
28:36 28:48 29,00 29:12 29:24 29:36 29,48 30,00 30:12 30:24
rile:S975867 tl-346 Acq:13-SXP-1997 02,12,56 XI+ Voltage SIR 70S Noiees443
403.8529 Ts3 BSUB(256,30,-3.0) PKD(7,5,3, 0.05*, 1772.0,1.00\,r,T) ExptEPCUS
TRIANGLE LABS Text:O-M23-2 TLIt43085 INJ. TIME - 02:15
1001 A4.
; A3.31E5
ao:
so;
40.
20:
30:36
9X5
.0.0X0
Time
A7.S4X4
. /
1. 7X5
1.4X5
1. 0X5
6.9X4
'.3.4X4
28:36 28,48 29:00 29:12 29:24 29:36 29:48 30:00
rileiS975867 tl-346 Acq:13-SEP-1997 02sl2:56 EI+ Voltage SIX 70S
392.9760 n3 Kxp-.XPCUS
TRIANGLE LABS Tsxt:O-M23-2 TLH43085 INJ. TIME - 02:15
* 30;
29,20
28: 29'13
28-.362B.1.44- —
30:12 30:24 30:36
.0. OEO
Time
28:36 28:48
291 00
29> 12 29:24
29136
29,48
30,00
-------
rlle,S975867 41-390 Acq:13-SEP-1997 02tl2tS6 EX+ Voltage SIS 70S Hoiie,811
407.7818 P:4 BSVt(256,30,-3.0) PKD(7,5,3, 0.051,3244.0,1.00\,f,T) XrptXPCOS
TRIANGLE LABS Text,O-H23-2 TU443085 IK7. TIME - 02il5
1003k A4.59E4
OMO
31,48 32,00 32:12 32,24 32,36 32,48 33,00
rile:S975867 41-390 Acq,13-SEP-1997 02,12i56 EH- Voltage Sit 70S Koiae,487
409.7789 fi4 BSUB(256, 30,-3.0 ) PKD(7, 5,3, 0.05\,1948.0,1.00\,F,T) SxpiSPCUS
TRIANGLE LABS Text:0-M23-2 TU943085 1WJ. TIME " 02,15
A3.
OOE4
33112
33124
31:48 32': 00 32,12 32:24 32:36 32:48 33,00 33,12
Tilt,:3975867 41-390 Acq:l3-SEP-1997 02,12,56 EH- Voltage SIX 70S Noise,639
417.8253 f,4 BSUB( 256,30, -3. 0) PKD( 7,5,3, 0. 05\,2S56. 0,1. 00\,r, T) SxpsEPCUS
TRIANGLE LABS Tejct,0-H23-2 TLI443085 IJKT. TIME - 02:15
100* A1.35E5
33124
80:
60:
40:
20:
A1.12E5
A8.53E4
A1.29E4J
A9.19E3
A1.38E4
A1.10E4
31:48 32,00 32,12 32,24 32,36 32:48 33,00 33,12
rileiS975867 41-390 Acq,13-SEP-1997 02:12:56 EH- Voltage SIR 70S B6iae:513
419.8220 P:4 BSUB(256,30,-3.0) PKD(7,5,3,0.OS\,2052.0,1.00\,r,T) ExptEPCUS
TRIANGLE LABS Text,O-H23-2 TLI443085 IK7. TIME - 02:15
1001 A2.B9ES
33,24
80:
60:
40:
20:
A2.66E5
AS.95E4
_/ v—
Al. 69E4
Al.64E4
33,00
32:19
31:48 32,00 32,12 32,24 32,36 32,48
File,S975867 41-390 Acq,13-SEP-1997 02,12:56 EI+ Voltage SIR 70S
430.9729 F,4 ExpiEPCUS
TRIANGLE LABS Text,O-M23-2 TLI443085 JJTJ. TIME -
100* ,,.,a 32,33 32,47
32:08
^A^v~v\y^
fiOJ
40:
20:
o.
33,12
33,24
02,15
33,27
31,48 32,00 32,12 32:24 32:36 32:48 33,00 33:12 33,24
rile:S975867 41-390 Ac
-------
1J.0IS37SS67 U-J90 AcqIU-SfP-J.997 OillilSt EI+ Voltage SIX 70S
23.7766 T:4 BSUf(256,30,-3.0) PKD(7,5,3,0.05\,1172.0,1.00\,T,T) Exp:EPCDS
TXIANSLX LASS Tejct:O-M23-2 TLH43085 1X7. TIKE -
1001 A6.04E4
32:00 32t06 32:12 32ilB 32:24 32t30 32i36 32:42 32:48 32:54 33:00
rile:S975867 tl-390 Acq:13-SEP-1997 02:12:56 Eli- Voltage 3IX 70S Noite:309
425.7737 Tit BSUB(256,30,-3.0) PKD(7,5,3,0.05\,1236.0,1.00\,r,T) ExpiEPCUS
TRIANGLE LABS Text:0-M23-2 TLZt43085 IKT. TIME - 02:15
1003, A9.37E4
80J
so:
40:
20.
A1.55S4
Al.65X4
A7.80S3
Al.06E4
A3.54X3
37X3
.1.9X4
-1.5X4
.1.1X4
.7.7X3
.3.8X3
0.0X0
Timm
32:00 32:06 32:12 32:18 32:24 32:30 32:36 32:42 32:48 32': 54 33:00
rile:S975867 tl-390 Acg:13-SEP-1997 02:12:56 EI+ Voltage SIX 70S Noiae:346
435.8169 F:4 BSUB(256, 30, -3 .0 ) PKD(7,5, 3, 0. 05\,1384. 0,1 . 00\, T, T) ExpsEPCUS
TRIANGLE LABS Text:O-M23-2 TLH43085 JUT. TIME - 02:15
33:06 33:12
100$
so:
so:
40:
20:
A2.31E5
A2.75E4
A7.06E3
T
r5.1E4
.7.3E4
IS. 5E4
-3.7E4
'.1. 8E4
A1.58E4
/
32:00 32:06 32:12 32:18 32:24 32:30 32:36 32:42 32:48 32:54 33:00
Tile:S975867 tl-390 Acqtl3-SEP-1997 02tl2i56 EI+ Voltage SIX 70S Noise, 14 5
437.8140 f:4 BSUB( 256 , 30, -3 .0 ) PKD( 7, 5, 3, 0 . 05%, 580. 0, 1 . 00\,F, T) Exp:EPCUS
TSIANSLE LABS Text:O-M23-2 TLI#430BS IJTJ: TIME - 02:15
33:06 33:12
.O.OEO
Time
1003
80.
60.
40.
20.
0_
A2.QSE5
A7.07E3
A1.46E4
32:00 32:06 32:12 32:18 32:24 32:30 32:36 32:42 32:48 32:54 33:00
f±le:S97S867 tl-390 Acqs13-SEP-1997 02:12:56 EI+ Voltage SIX 70S
430.9729 T:4 Exp:EPCDS
TRIANGLE LABS TextsO-M23-2 TLIf43085 HKT. TIME - 02:15
.O.OEO
33:06 33:12 Time
.8.1E4
-6.4E4
-4.8E4
-3.2E4
_1. 6E4
1004
32;<33
32:00 32:06 32:12 32:18 32:24 32:30 32:36 32:42 32:48 32:54
I i i i i i I
33:06 33:12
O.OEO
Tim
112
-------
ril»:S975867 #1-390 Aoqtl3-SXP-1997 02:12,56 XI+ VoltMgm SIX 70S Holtft 332
441.7428 Tt4 BSOB(256,30,-3.0) PKD(7, 5,3,0.05\,1328.0,1.00\,r,T) XxpiXPCDS
TRIANGLE LASS T*xt,O-H23-2 TLH43085 1X7. TXHX - 02tl5
10 0\
AS.51X4
A3.87X4
AS.22X3
A2.30X4
t^jful^
.2.8X4
.2.5X4
J.3X4
.1. 7X4
.1.4X4
.1.1X4
.1.3X3
6X3
8X3
0.0X0
33,00
33,00
34,00
35,00
rile,S975867 tl-390 Acqil3-SXP-1997 02,12,56 EI+ Voltage SIS 70S Koimei512
443.7399 P,4 BSUB(256,30,-3.0) PKD(7,S,3,0,05\,2048.0,1.00\,T,T) Exp:EPCUS
TRIANGLE LABS TextsO-H23-2 TLIt43085 HKT. TIMX ' 02:15
100\ A1.34E5
32i00 33:00 34:00
rile:S975867 41-390 Acq:13-SEP-1997 02:12:56 EH- Voltage SIR 70S
430.9729 r,4 ExptEPCUS
TRIANGLE LABS Text:O-M23-2 TLH4308S INJ. TIME
32,33 33,03
32: IS
35:00
Time
32:00 33:00 34:00
File:S975867 91-390 Acq:13-SEP-1997 02:12:56 XI+ Voltage SIR 70S
513.6775 F:4 ExpiEPCUS
TSIASSLX LABS Text:0-H23-2 TLH4308S IWJ. TIME
-------
'iJ.»:S97S867 #1-39O AoqiJ.J-SSP-J.997 OJHJ:56 El* VOJ\tMg» SIM 70S MOlM»:54
57.7377 Ti4 BSUB(256,30,-3.0) PXD<7,5,3,0.05\,216.0,1.00\,T,T) ElpifPCUS
TRIANGLE LABS T+rttO-M23-2 TLH43085 OUT. TOtf - 02il5
00$
.55X4
35il2 35,18 35:24 35t30 35:36
rile:S975867 #1-390 Aoqtl3-SEP-1997 02:12i56 EI+ Voltag» SIX 70S Nairn*t40
S9.734B T:4 BSUB(256,30,-3.0) PKD(7,5,3,0.05\, 160.0,1.00\,T,T) XxpttPCUS
TXIANGLK LABS TmxttO-M23-2 TLH43085 IJKT. TIMX - 02115
100\
so:
"^ ' ' A5.00E3
I \ I \ /\
401
20.
35:42
Al.78E3
35i12 35:13 35i24 35:30 35:36
rile:S975867 #1-390 Acq:13-SEP-1997 02:12:56 EH- Voltage SIR 70S Noiae:63
469.7779 T:4 BSU3(256,30,-3.0) PKD(7,5,3, 0. OS\,252. 0,1. 00%,r,T) EzpsEPCtJS
TRIANGLE LABS Text:O-M23-2 TLI#43085 JKT. TIME - 02:15
1001 A1.56E5
80.
60.
401
20.
35:42
35:12 35:18 35:24 35:30 35:36
File-.3975867 #1-390 Acqtl3-SEP-1997 02:12:56 EH- Voltage SIS 70S Jtoiae:70
471.7750 T:4 BSU3(256,30,-3. 0) PKD(7,5,3,0.051,280.0,1.00\,r,T) EiptEPCVS
TRIANGLE LABS Text:O-M23-2 TLI#43085 INJ. TIKE - 02:15
1004 A1.57E5
80J
eo:
401
35:42
20:
A1.10E4
35:12 35:18 35:24 35:30 35:36
r±le:S975867 #1-390 Acqil3-SEP-1997 02:12:56 EI+ Voltage SIR 70S
430.9729 r:4 ExptSPCUS
TRIANGLE LABS Taxt:O-M23-2 TLI#43085 ISJ. TIME -
35:42
1003
80.
60.
40.
20.
0.
02:15
35:13
35:22
35:37
35:44
35tl2
35:18
35:24
351:30
35:36
"•—I '
35:42
5.1E3
4.1E3
3.1X3
.2.1E3
.1. OE3
.O.OEO
Time
-5.6E4
-4.5E4
-3. 4E4
.2.3E4
-1.1E4
.O.OEO
Tim
_3.6E6
-2.8E6
-2.1S6
.1.4X6
'.7.1X5
.0.0X0
Tim
114
-------
Channel I 338,9792 Peak top
Height 2,32 volts Span 288 ppi
Systei file naie EPCUS2
Data file naie R'9913971
Resolution 18888
Groupnmber 2
lonlzatlon iode Eh
Switching VOLTflGE
Ref, lasses 292,9825, 416,9768
J 331 S 368
K 332 1 378
L 334 U 376
H 348 V 418
H 342
0 352
P 354
0 356
R 358
&as! 416,9768 Peak top
heloht ,£ volts Spar 286 ppi
115
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51.
amp
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9000 F:2 ExprEPCUS
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f\
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L2.7E5
L2.4E5
L2.1E5
L1.8E5
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_1.2E5
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_5.9E4
_3.0E4
O.OEO
Time
ile:S975867 #1-905 Acq:13-SEP-1997 02:12:56 EI+ Voltage SIR 70S
53.8970 F:2 Exp.-EPCUS
ample Text:0-M23-2 TLI#43085 ... INJ. TIME =
02:15 File Text:0-M23-2 TLI#4»
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90 J
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25I24 ' 25136 ' 25l48 ' 26!6o 26!l2 26^24 26536 26148" 27166 27.'l2 27124 27:36 27:48 Time
-------
•'His 15975867 #1-346 Acq:13-SEP-19g7 02:12:56 EI+ Voltage SIR 70S
173.8208 P:3 Exp:EPCUS
Sample Text:0-M23-2 TLI#43085
LOO* 28 49
80J
60J
40J
201
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INJ. TIME =
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29:00 30:00
'116:3975867 #1-346 Acq:13-SEP-1997 02:12:56 EI+ Voltage SIR 70S
175.8178 F:3 Exp:EPCUS
Jample Text .-O-M23-2 TLI#43085
100% 28:48
INJ. TIME =
O.OEO
Time
02:15 File Text:O-M23-2 TLI#4»
30:44
30:34
29:00 30:00
'ile:S975867 #1-346 Acq: 13-SEP-1997 02:12:56 EI+ Voltage SIR 70S
183.8639 F:3 Exp:EPCUS
lample Text:0-M23-2 TLI#43085 INJ. TIME =
L00% 29:37
80j
60J
40j
20j
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28:49
29:00
30:04
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Time
02:15 File Text:O-M23-2 TLI#4»
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30:44
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L8.3E4
L5.5E4
L2.8E4
30:00
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Time
-------
.le:S975867 #1-390 Acq: 13-SEP-1997 02:12:56 EI+ Voltage SIR 70S ~~~~~
.7.8253 F:4 Exp:EPCUS
unple Text:0-M23-2 TLI#43085 INJ. TIME = 02:15 File Text:O-M23
32:05
2 TLI#4>:
6.2E4
0
35:00
32iOO 33iOO 34:00
.le:S975867 #1-390 Acq:13-SEP-1997 02:12:56 EI+ Voltage SIR 70S
.9.8220 F:4 Exp:EPCUS
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33:12
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32:40
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L1.0E5
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L7.9E4
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L5.7E4
L4.5E4
L3.4E4
L2.3E4
L1.1E4
LO.OEO
Time
-------
Lle:S975867 #1-346 Acq:13-SEP-1997 02:12:56 EI+ Voltage SIR 70S
73.8208 F:3 Exp:EPCUS
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02:15 File Text:O-M23-2 TLI#4»
1.7E4
29:00 30:00
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75.8178 F:3 Exp:EPCUS
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00* 28;48
801
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28:13
29:00 30:00
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45.7555 F:3 Exp:EPCUS
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3.8208 F:3 ExprEPCUS
.mple Text:0-M23-2 TLI#43085
INJ. TIME =
02
10 j
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28:58
29:18
29:0929:14
28:5(
29:04
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28:24 28:30 28:36 28:42 28:48 28:54 29:00 29:06 29:12 29:18
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'5.8178 F:3 Exp:EPCUS
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)0% 28;48
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11.0E4
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29?24 '29!3'6 '29:36
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15 File Text:0-M23-2 TLI#4»
1.4E4
L1.1E4
L8.6E3
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28:24 28:30 28:36 28:42 28:48 28:54 29:00 29:06 29:12 29:18 29:24 29:30 29:36
Lle:S975867 #1-346 Acq:13-SEP-1997 02:12:56 EI+ Voltage SIR 70S
15.7555 F:3 Exp:EPCUS
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28;47
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301
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2.8E4
L2.2E4
L1.7E4
28:22
29:37
15.6E3
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O
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-------
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'3.8208 F:3 Exp:EPCUS
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30%
sol
10J
201
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30:36 30:42
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-i 1 1 r
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30:24 30:30
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'5.8178 F:3 Exp:EPCUS
imple Text:O-M23-2 TLI#43085 INJ. TIME = 02:15 File Text:O-M23-2 TLI#4»
30:44
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30:24' 30:30 30:36 30:42 30:48 30:54 Time
.le:S975867 #1-346 Acq:13-SEP-1997 02:12:56 EI+ Voltage SIR 70S
15.7555 F:3 Exp:EPCUS
imple Text:O-M23-2 TLI#43085 INJ. TIME = 02:15 File Text:O-M23-2 TLI#4»
)0% 30;44
30:24
30:30
30:36
30:42
30:48
30:54
Time
-------
TLI Project: 43085
Client Sample: O-M23-3
Method 23 PCDD/PCDF Analysis (a)
Analysis File: S975868
Client Project:
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
S413-004
M23Train
181-55-3ABE
1.000
n/a
DB-5
Date Received:
Date Extracted:
Date Analyzed:
Dilution Factor:
Blank File:
Analyst:
09/03/97
09/04/97
09/13/97
n/a
S975815
ML
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPX23704
SF56117
S975861
n/a
n/a
n/a
Analytes • •:•".".'.• ••^•'•••- '"•
2,3,7,8-TCDD
1,2,3,7,8-PeCDD
1,2,3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
1,2,3,4,6,7,8-HpCDD
1,2,3,4,6,7,8,9-OCDD
2,3,7,8-TCDF
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
1,2,3,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
1,2,3,4,6,7,8.9-OCDF
Totals '•• ."/' :Jr ..V'.
Total TCDD
Total PeCDD
Total HxCDD
Total HpCDD
Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF
•;-;--;::7:.'Amt.-ing)
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
: :; : Amt (n§)
ND
ND
ND
ND
ND
EMPC
ND
ND
Dt EMPC fta*k» at Flag*
0.01
0.01
0.02
0.02
0.02
0.03
0.10
0.006
0.01
0.01
0.01
0.01
0.01
0.01
0.02
0.03
0.07
: Number Dt EMPC Ftegs
0.01
0.01
0.02
0.03
0.006
0.02
0.01
0.02
Page 1 of 2
X237 J-SR »100. LARS tlO.04
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Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 13:19 09/18/97
122
-------
TLI Project: 43085
Client Sample: O-M23-3
Method 23 PCDD/PCDF Analysis (a)
Analysis File: S975868
i Internal Standards
13C,:-2,3,7,8-TCDF
13C,2-2,3,7,8-TCDD
13C,2-l,2,3,7,8-PeCDF
13C,2-l,2,3,7,8-PeCDD
1JC,2-l,2,3,6,7,8-HxCDF
3CP-l,2,3,6,7,8-HxCDD
13C,2-l,2,3,4,6,7,8-HpCDF
13C,2-l,2,3,4,6,7,8-HpCDD
13Cir 1,2,3 A6,7,8,9-OCDD
Surrogate Standards (Type A)
37CL,-2,3,7,8-TCDD
13C,2-2,3,4,7,8-PeCDF
13Cp-l,2,3,4,7,8-HxCDF
13d2-l,2,3,4,7,8-HxCDD
13C,2-l,2,3,4,7,8,9-HpCDF
Alternate Standards (Type A)
13C,2-l,2,3,7,8,9-HxCDF
13C,2-2,3,4,6,7,8-HxCDF
Amt. (ng)
4.5
3.8
3.7
4.0
4.1
3.7
2.6
2.6
2.5
AmL (ng)
4.0
3.7
3.4
3.3
3.5
Amt (ng)
3.4
3.8
% Recovery
114
95.4
91.9
100
103
92.2
64.7
63.8
31.6
:-\.--:-~&£*Mmw
101
93.4
85.0
83.2
86.7
•<& Recovery
....•-:•. •:.^*.-??-rVove'y
84.8
94.6
QC Limits
40%- 130%
40%- 130%
40%- 130%
40%-130%
40%- 130%
40%- 130%
25%- 130%
25%- 130%
25%- 1 30%
QC Limits
70%-140%
70%- 140%
70%- 140%
70%- 140%
70%- 140%
: QC Limits
40%- 130%
40%- 130%
Ratio
0.74
0.77
1.36
1.50
0.50
1.22
0.43
1.04
0.91
'-. Ralte: ^j.
1.49
0.50
1.27
0.44
'•••• -Ratio- ,'.;;.••
0.52
0.51
«T^
21:37
22:22
25:41
26:44
29:17
29:58
31:56
32:46
35:20
'*•*&:?•*
22:23
26:23
29:11
29:54
33:08
; RT
30:29
29:46
*''**>
,;^flags,.
i
Flags
—
Recovery Standards ;?t ; "•••• -• •"•-.!•. -• ="- :• " -::': :^^^JV./-:.:?: ••'••••;v •••/. v ;•; ;.-.' . . ..-.' • -.•' RatfoV-^ifl.V-ilf. •• ;v;rkv;Fiags.
13Ci2-l,2,3,4-TCDD
13C12-l,2,3,7,8,9-HxCDD
0.83
1.22
22:10
30:16
—
Data Reviewer
Page 2 of 2
09/18/97
X237.PSR vlOO. LAW 6.K
Triangle Laboratories, Inc.®
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 13:19 09/tW
123
-------
Initial
... Date...
Data Review By:
~&- °\ I I%/)T Calculated Hois* Area: 0.93
The Total Area for each peak with an ion abundance ratio outside
ratio limits has been recalculated according to method requirements.
Page No.
09/18/97
Listing of S975868B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log omit Why
.RT. OK .Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Re1.RT Compound.Name.. ID.. Flags.
TCDF
304-306
304-306
DC
DC
DC
DC
DC
DC
DC
DC
NL
SN
SN
SN
SN
SN
SN
SN
0
0:00
18:24
19:30
20:14
20:35
20:51
21:12
21:37
Peaks
0.
RO
RO
RO
RO
RO
65-
0.
1.
0.
0.
0.
0.
0
0
•0.89
85
24
,71
.41
.50
.74
.90
.63
0.
0.
2.
2,
2
1
3
5
0
24
.89
.04
.05
.46
.97
.27
.03
.00
0.838-1.092
0.000
0.851
0.902
0.936
0.952
0.965
0.981
1.000 2378-TCDF
AN
13C12-TCDF 0.65-0.89
316-318 DC NL 0:00 RO 0.93 0.27
21:10 RO 1.06 5.52
21:37 0.74 1,205.98
316-318 2 Peaks 1,211.50
3.30
514.33
0.954-1.046
0.000
3.12 0.979
691.65 1.000 13C12-2378-TCDF ISO
TCDD
320-322
320-322
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
WH
0
0:
19:
20:
20:
20:
21:
21:
21:
22:
22:
22
22
22
23
23
23
Pe,
00
57
04
16
52
01
14
;36
:05
:23
:37
:46
:52
:07
:27
:47
aks
o.<
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
55-
0.
0.
2.
0.
1.
1.
1.
1,
3,
0
0
0
0
2
2
0
0.89
79
44
93
17
55
09
.47
,45
.75
.52
.68
.68
.59
.82
.08
.50
Above: TCDF / TCDD Follows
0.25
0.57
0.50
0.16
0.35
1.03
0.60
0.71
0.57
1.70
0.52
0.69
0.62
0.39
1.29
0.97
0.00
.875-1.055
0.000
0.392
0.897
0.906
0.933
0.940
0.949
0.966
0.987
1.001 2378-TCDD
1.011
1.018
1.022
1.034
1.048
1.063
37C1-TCDD
328
DC NL 0:00
DC WL 19:47
DC WL 19:57
DC SN 20:41
DC SN 20:58
0.38
0.74
0.32
1.56
0.97
.910-1.090
0.000
0.885
0.892
0.925
0.937
Triangle Laboratories, Inc.® Analytical Services Division
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Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 13:20 09/18/97
124
-------
Page Ho. 2
09/18/97
Compound/
M_Z QC.Log Omit Why
Listing of S975868B.db£
Matched GC Peaks / Ratio
/ Ret. Tine
..HP. OK Ratio Total.Area... Area.P.aJc.l.. Ar.a.Peak.2.. R.1.RT Compound.Name.. ID.. Flag,.
328
13C12-TCDD
332-334
332-334
PeCDF
340-342
340-342
13C12-P6CDF
352-354
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
SN
SN
SN
SN
SN
SN
SN
SN
1
NL
WL
WL
SN
SN
SN
3
NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
1
NL
SN
SN
SN
SN
SN
SN
SN
21:38
21:42
21:59
22:09
22:23
22:53
23:14
23:29
23:42
Peak
0:
19:
20:
22:
22:
22:
22:
22:
00
;52
17
10
:22
32
42
56
23:00
Peaks
0:
23:
23:
24:
24:
25:
25:
25;
26:
26;
26:
27:
27:
:00
41
:56
49
:59
14
:23
:59
:17
:27
:43
:01
:17
27:34
Peak
0;
23
24
24
25
25
25
25
26
:00
:40
:13
:18
:09
:21
:57
:05
0.
RO
RO
RO
RO
RO
RO
RO
1.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
1.
RO
RO
RO
RO
RO
RO
65
2
2
2
0
0
1
1
1
0
32
1
0
0
2
2
0
1
0
0
1
0
0
0
8
32
0
0
3
0
1
3
1
1
1
-0.89
.90
.25
.20
.83
.77
.81
.13
.07
.55
1,
-1.78
.14
.66
.65
.05
.00
.81
.74
.95
.30
.74
.42
.44
.95
.25
-1.78
.92
.44
.94
.79
.76
.34
.36
.01
.51
0
1
0
1
695
1
0
0
0
695
0
1
0
805
818
1
13
0
1
,636
Ten
i "w U
0
4
0
2
0
0
0
1
1
2
0
0
1
0
4
0
0
0
0
1
3
838
4
1
.79
.22
.84
.28
•96 695.96
.03
.72
.92
.76
.96
.51
.13
.80
•02 364.99
•51 356.56
.22
•42 3.54
.53
.01
.95
.26
•59 2.79
.71
.09
.54
.43
.96
.66
.02
.22
.41
.74
.37
.41
.59
.20
.56
.41
.25
.35
.11
•49 482.87
.06
.18
0.
0.
0.
0.
1.
1.
1.
1.
1.
,967
970
983
990
001 37C1-TCDD SUR1
023
039
050
060
0.910-1.090
0.000
0.
0.
440.03 0.
461.95 1.
1.
7.58 1.
1.
1.
0.915-
0.
4.24 0.
0.
0.
0.
0.
0.
1.
1.
1.
1.
1.
1.
1.
0.844-
0.
0.
0.
0.
0.
0.
355.62 1.
1.
1.
388
907
991 13C12-1234-TCDD RSI
000 13C12-2378-TCDD IS1
007
015
025
028
1.074
000
922
932
966
973
982
988
012
023
030 23478-PeCDF AN
040
052
062
073
1.156
000
921
943
946
979
987
000 13C12-PeCDF 123 IS2
010
016
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 13:20
-------
Page No. 3
09/18/97
Compound/
M_Z.... QC.Log Omit Why
Listing of S975868B.dbf
Matched GC Peaks / Ratio / Ret. Time
.RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
N
352-354
PeCDD
356-358
356-358
13C12 -PeCDD
368-370
368-370
HxCDF
374-376
374-376
13C12-HXCDF
384-386
DC
DC
26:23
SN 27:12
SN 27:32 RO
2 Peaks
1.49
1.45
0.67
1
* W A..A _
1.32-
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
WL
SN
SN
SN
SN
SN
SN
WH
0
NL
SN
SN
SN
SN
SN
2
NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
WH
WH
0
NL
SN
SN
0:
24:
25:
25:
26:
26:
26:
27:
27:
00
44
04
22
09
18
28
13
27
RO
RO
RO
RO
RO
RO
RO
RO
RO
1.
4.
4.
9.
0.
6.
3.
3.
0.
- jujwvw ;
1.78
18
27
33
89
70
89
08
80
15
Peaks
0:
24:
25:
26:
26:
26:
26:
27:
00
42
20
02
17
44
54
27
1.
RO
RO
RO
RO
RO
759.27 454.30
1.15
0.92
,597.76
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
21
28
54
23
82
92
66
38
15
00
32-1.78
1.
3.
0.
1.
0.
1.
1.
00
11
67
75
18
50
.48
0.51
Peaks
0
28
28
28
28
29
29
29
29
30
30
30
30
:00
:13
:22
:40
:49
:11
-.16
:23
:36
:22
:30
:48
:55
1.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
0.
0.
0.
0.
20
48
51
55
0.44
513.
40.
20 307.56
.92 24.43
0.81
554
W-./TM
05-1.43
1
1
1
0
1
1
1
1
1
0
0
1
0
.40
.57
.02
.84
.60
.25
.86
.37
.51
.99
.76
.78
.94
Peaks
0
28
28
:00
:21
:35
0
RO
RO
1
1
3
0
1
2
2
1
1
1
1
1
1
0
.12
.56
.41
.00
.69
.46
.36
.02
.23
.41
.39
.61
.01
.10
.00
.43-0.59
0
0
0
.65
.42
.54
1
1
1
.37
.07
.20
304.97 1.027 13C12-PeCDF 234 SUR2
1.059
1.072
0.926-1.024
0.
0.
0.
0.
0.
0.
0.
1.
1.
000
925
938
949
978
984
990
018
027
0.850-1.150
0.
0.
0.
0.
0.
205.64 1.
000
924
948
974
983
000 13C12-PeCDD 123 IS3
16.49 1.006
1.027
0.959-1.050
0
0
0
0
0
0
0
1
1
1
1
1
1
0.863
0
0
0
.000
.964
.969
.979
.984
.997 123478-HxCDF AN
.999
.003
.011
.037
.042 123789-HXCDF AN
.052
.056
-1.137
.000
.968
.976
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 13:
97
-------
Page No.
09/18/97
Listing of S975868B.dbf
Matched GC Peaks / Ratio /
Rat. Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Ar.a.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name. . ID.. Flag,.
384-386
HXCDD
390-392
390-392
13C12-HXCDD
402-404
402-404
HpCDF
408-410
408-410
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
SN
SN
SN
SN
SN
4
NL
SN
SN
SN
SN
SN
SN
SN
SN
WH
WH
0
NL
WL
WL
SN
SN
SN
SN
SN
3
NL
WL
SN
SN
SN
SN
SN
0
29:01
29:11
29:17
29:34
29:46
30:03
30:16
30:29
30:37
Peaks
0:00
29:18
29:24
29:33
29:53
29:59
30:07
30:15
30:22
30:38
30:41
Peaks
0:00
28:36
28:41
29:00
29:23
29:54
29:58
30:06
30:16
30:27
30:41
Peaks
0:00
31:45
31:52
32:11
32:24
33:08
33:15
Peaks
RO
RO
RO
RO
RO
1.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
1.
RO
RO
RO
RO
RO
RO
RO
0,
RO
RO
RO
RO
RO
RO
0.
0.
0.
0.
0.
0.
0.
0.
0.
91
50
50
19
51
16
23
52
81
05-1.43
0.
3.
1.
0.
2.
2.
1.
0.
0.
0.
0.
05-
1.
0.
2.
1.
1.
1.
1.
0.
1.
0.
0.
54
87
03
71
23
41
42
27
47
35
44
1.43
51
60
17
73
30
27
22
95
22
62
91
0.
529.
649.
0.
551.
0.
0.
429.
1.
51
99 176.72
92 217.16
41
11 184.95
36
86
21 146.08
34
0.
353.27 0.
432.76 1.
1.
366.16 1.
1.
1.
283.13 1.
1.
2,160.23
0.
0.
0.
0.
0.
0.
1.
0.
0.
0.
1.
0.
1.
0.
0.
1.
2.
388.
479.
1.
522.
0.
1.
1,390.
.88-1.20
1.
2.
7.
0.
2.
0.
3.
83
50
12
61
23
88
02
1.
0.
2.
2.
1.
2.
2.
0.
85
34
60
81
29
65
60
25
98
67
46
00
32
87
94
01
51
14 216.84
40 263.42
41
49 286.75
70
63
03
94
73
18
30
06
.07
,06
00
0.953-
0.
0.
0.
0.
0.
1.
1.
1.
1.
1.
1.
0.967-
0.
0.
0.
0.
0.
171.30 0.
215.98 1.
1.
235.74 1.
1.
1 .
0.995-
0.
0.
0.
1.
1.
1.
1 .
991
997 13C12-HXCDF 478
000 13C12-HXCDF 678
010
017 13C12-HXCDF 234
026
034
041 13C12-HXCDF 789
046
1.014
000
978
981
986
997 123478-HxCDD
001 123678-HxCDD
005
009 123789-HxCDD
013
022
024
1 . 033
000
954
957
968
981
998 13C12-HXCDD 478
000 13C12-HXCDD 678
004
010 13C12-HXCDD 789
016
024
1.042
000
994
998
008
015
038 1234789-HpCDF
041
SOR3
IS4
ALT2
ALT1
AN
AN
AN
SUR4
IS5
RS2
AN
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 1320 09/18/$
127
-------
Page No. 5
09/18/97
Compound/
M_Z .... QC . Log
13C12-HpCDF
418-420
418-420
HpCDD
424-426
424-426
13C12-HpCDD
436-438
436-438
OCDF
442-444
442-444
OCDD
458-460
458-460
13C12-OCDD
470-472
Omit
DC
DC
Listing of S
Matched GC I
Why . .RT. OK Rati
0.37-(
NL 0: 00 RO O.I
31:56 0.'
SK 32:47 0.:
33:08 0.'
2 Peaks
0.88-
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
WL
SN
SN
0
NL
SN
SN
1
NL
WL
SN
SN
SN
SN
SN
SN
SN
SN
SN
0
NL
SN
SN
0
NL
WL
0:00
31:58
32:09
32:46
Peaks
0:00
32:46
33:03
33: 16
Peak
0:00
31:17
31:55
32:32
33:00
33:23
33:58
34:38
34:51
35:13
35:28
Peaks
0:00
35:19
35:46
Peaks
RO
RO
RO
RO
0.
RO
RO
RO
0.
RO
RO
RO
RO
RO
RO
RO
RO
RO
0
RO
RO
0
0:00 RO
35:04 RO
35:20
470-472
1.
2.
2.
0.
88-
2.
1.
2.
0.
I975868B.
>eaks / R
Lo Total.
).51
53
13
37
14
- Above :
1.20
86
09
53
26
1.20
11
04
44
80
• - Above :
dbf
atio /
Area. .
2.:
299. f
1.1
200.:
500.:
HpCDF
1 Ret. Time
. Area. Peak. 1. . Area . Peak . 2 . . Re l.RT Compound. Name. . ID..
0.937-1.125
28 0.000
S9 90.77 209.12 1.000 13C12-HpCDF 678 IS6
SO 1.027
37 61.08 139.29 1.038 13C12-HpCDF 789 SUR5
26
0.88
1.
0.
1.
0.
0.
271.
1.
1.
271.
31
61
08
00
94
50 138.72
65
33
50
HpCDD / Octa-CDD and CDF
76-1.02
1.
3.
0.
2
0
3
0
0
2
0
0
.76
2
0
9
,07
.65
.81
.26
.66
.00
.68
.47
.75
.40
.78
-1.02
.59
. 83
.43
1.
0,
1.
0
2.
0
1
2
1
0
3
0
0
4
0
0
34
.81
.86
.95
.29
.68
.55
.31
.59
.96
.52
.00
.42
.47
.13
.00
.76-1.02
3
.44
2.49
0.91
1 Peak
0
2
171
171
.17
.00
.61 81.81
.61
0.977-
0.
0.
0.
1.
0.969-
0.
132.78 1.
1.
1.
1.005
000
976
981
000 1234678-HpCDD AN
1. 031
000
000 13C12-HpCDD 678 IS7
009
015
0.887-1.113
0.000
0.885
0.
0
0
0
0
0
0
0
1
0.887
0
1
1
.903
.921
.934
.945
.961
.980
.986
.997
. 004 OCDF AN
-1.113
.000
.000
.012
0.996-1.005
0
.000
0.992
89.80 1
.000 13C12-OCDD IS8
Flags.
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 13:20 09/18/97
128
-------
Page No.
09/18/97
Listing of S975868B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
Column Description "Why" Code Description QC Log Desc.
M_Z -Nominal Ion Mass(es)
..RT. -Retention Time (mm:ss)
Rat.l -Ratio of M/M+2 Ions
OK -RO=Ratio Outside Limits
Rel.RT-Relative Retention Time
*** End of Report
WL-Below Retention Time Window
WH-Above Retention Time Window
SN-Below Signal to Noise Level
-------
ile:S975868 #1-905 Acqtl3-SXP-1997 02i52i21 XI* Voltage SIX 70S Hoift 157
03.9016 Ti2 BSUB(256,30,-3.0) PKD(9,5,5,0.05\,228.0,1.00\,r,T) XxptXTCUS
TRIANGLE LABS TeJCt:O-M23-3 TZH43085 IJKT. TIMX - 0.2«55
001
19.00 20-00 21.00 22:00
lie:5975858 #1-905 Acq:13-SEP-1997 02:52:21 XI+ Voltage SIX 70S Noi*e:67
05.8987 f:2 BSUB(256, 30,-3.0) PKD(9,5,5, 0. 05\,268. 0,1.00\,T,T) ExpiEPCUS
TRIANGLE LABS Text:O-M23-3 TLH43085 IKT. TIME - 02:55
23100
.0.0X0
Time
19:00 20:00 21:00 22:00 23:00
File:S9758S8 #1-905 Acq:13-SEP-1997 02:52:21 XI* Voltage SIR 70S Noise:69
15.9419 r-.2 BSVS(256,30,-3.0) PKD(9,5,5, 0. 05\,276. 0,1. 00\,T, T) Exp:SPCUS
TRIANGLE LABS Text:O-M23-3 TLH43085 INJT. TIME - 02:55
1004
80J
40:.
20.
0.
A5.}.
4E6
19:00 20:00 21:00 22:00
File:S97586S #1-905 Acq:13-SEP-1997 02:52:21 EI+ Voltage SIR 70S Noi»e:76
317.9389 T:2 BSUB(256r 30, -3. 0) PKD(9, 5,5, 0. 05\,304. 0,1. 00*,JT, T) Exp:EPCUS
TRJANGLE LABS Teit:O-M23-3 Ttl#43085 JMT. TIME - 02:55
1001 A6.92E6
sol
50J
401
20.
0:
23:00
1.5X6
1.2X6
9. OE5
6.0E5
3. 0X5
O.OEO
Tim
.2.0E6
.1.6E6
.1.2X6
.8.1E5
.4.1ES
19:00 20:00 21:00 22:00
File:S975868 #1-905 Acq:13-SEP-1997 02:52:21 EI+ Voltage SIR 70S
330.9792 T:2 Exp:EPCUS
TRIANGLE LABS Text:O-M23-3 TLIt43085 INJ. TIME -
23:00
.O.OEO
Tim.
02:55
19:00 20:00 21:00
rile:S975868 #1-905 Acq:13-SEP-1997 02:52:21 SI+ Voltage SIR 70S
375.8364 T:2 Exp:EPCOS
TRIANGLE LABS Text:O-M23-3 TLH43085
100J
22:00
IKJ. TIME
23:00
02:55
401
201
0.
23 29
18:16
19:59
j\—L
19100
20100
.O.OEO
Tim
.1.1X4
.8.8X3
i6.6E3
.4.4X3
.2.2X3
21100
22100
23100
.0.0X0
Tim
130
-------
\rll»:S975868 tl-905 Aoqtl3-SSP-1997 03i53t31 Eli- Voltage SIX 70S Nolle:56
319.6965 F:2 BSUB(256, 30, -3.0) PKD( 7,5, 3, 0.05\,234.0,1.00\,r,T) ExptEPCUS
TXIAKGLX LABS TuxttO-K33-3 TLH4308S HKT. TIM* - 03i55
100*
0.9*9
20:00 21:00 23:00 23:00
riletS975a68 tl-905 Acqtl3-SEP-1997 02:52:31 EI+ Voltage SIS 70S Holm* t 72
321.8936 f>2 BSUB(256, 30, -3.0) PKD(7, 5,3, 0 .OS\, 288.0, 1.00\,r,T) ExptEPCOS
TX1ANSLE LABS T*xttO-M33-3 TLH43085 IXT. TIME - 03*55
100J
so:
60:
A5.
40.
20:
20:00 21:00 22:00 23:00
rile:S975868 tl-905 Acq:13-SEP-1997 03:53:31 EI+ Voltage SIX 70S No±me:422
331.9368 T:2 BSUB(356,30,-3.0) PKD(7,5,3, 0.05\,1688.0,1.00\,r,T) ExpsEPCUS
TRIANGLE LABS Text:0-M23-3 TLIt43085 HKT. TIME - 02:55
A3.65E6
..A3.57E6
60:
40:
20:
-r
T
rr
20s00 21:00 22:00 23:00
rile:S975868 tl-905 Aojsl3-SEP-1997 02:52:21 EH- Voltage SIX 70S No±ae:144
333.9338 T:2 BSUB(356,30,-3.0) PKD(7, 5,3,0.05\,576.0,1.00\,r,T) ExpsEPCUS
TRIANGLE LABS Text:O-M23-3 TLIt43085 UKT. TIME " 02:55
1001
80:
60:
40:
20:
II,,
/ V
20:00 21:00 22:00 23:00
rlle:S975868 tl-905 Aoqs13-SEP-1997 02:52:21 EH- Voltage SIX 70S Noise:188
327.8847 F:2 BSUB( 256, 30, -3 . 0) PJO)( 7, 5, 3, 0. 05%, 752. 0, 1. 00\,T, T) Exp:EPCUS
TRIANGLE LABS TextsO-M23-3 TLH43085 IXJ. TIME - 02:55
1004 A6.96E6
80:
60:
40:
20.
20:00 21:00 22>00 23:00
rile:S975868 tl-905 Acq:13-SEP-1997 02:52:21 EI+ Voltage SIX 70S
330.9792 P:3 ExptEPCUS
TXIANGLE LABS Text:O-M23-3 TLIt43085 IKT. TIME - 02:55
20:4821:03 ->T .« 2ii-54 22i17 — - '- •22-5fi
30 > 00
21:00
22:00
331 00
.1.1E6
-9.1E5
16.8E5
L4.6E5
O.OEO
Time
.1. 3E6
.1. 1E6
.8.115
.5.4E5
.2.7E5
.O.OEO
Time
2. ore
.1. 6E6
.1.2E6
'-.7.9E5
.4.0ES
.O.OEO
Time
13
-------
lle,S975868 tl-905 Aoq,13-SEP-1997 02:52,21 11+ Voltage SIX 70S Hoiae:80
39.8597 T:2 BSOB(256,30, -3.0) PXD(7,5,3, 0.05%, 330.0,1.00\,r,T) Xxp,XPCUS
TXIAHSLX LABS TexttO-M23-3 TLH43085 OU. TIM* - 02»55
24iOO 25iOO 20iOO
FllesS975868 tl-905 Acq,13-SEP-1997 02:52:21 EI+ Voltage SIX 70S Hoifet68
41.8567 T:2 BSUB(256,30,-3.0) PKD(7,S,3,0.05\,373.0,1.00\rF,T) Exp:EPCUS
TXIAXCUS LASS TexttO-M23-3 TLH43085 ISJ. TIMX - 03:55
A4.24X4
27tOO
24:00 25:00 26:00
rile:S97586B #1-905 Acq:13-SEP-1997 02:52:21 EI+ Voltage SIX 70S Koiae:61
351.9000 Fi2 BSUB(256,30,-3.0) PKS(7,5,3,0.05\,244.0,1.00\,F,T) Xip:EPCUS
TRIANGLE LABS Text:O-M23-3 TLIt43085 JK7. TIME - 02:55
100* A4.S4E6
A4.83E6
so:
60:
40:
20:
o\ . L
27-00
~r
~r
24:00 25:00 26:00
Flle:S975868 tl-905 Acq:13-SEP-1997 02:52:21 EI+ Voltage SIX 70S Hoiae:63
353.8970 F:2 BSUB(256, 30, -3. 0) PKD( 7, 5, 3, 0. 05\,252. 0,1. 00%, T, T) ExpsEPCUS
TXIAKGLE LABS Text:O-M23-3 TLI#43085 ISJ-. TIME - 02:55
2700
1003
SO:
60:
40:
20:
0.
A3.
56E6
A3 . 05E6
24:00 25:00 26:00
rile:S975868 tl-905 Acq:13-SEP-1997 02:52:21 EI+ Voltage SIS 70S
330.9792 F:2 ExpiEPCUS
TRIANGLE LABS Text:O-M23-3 TLIt43085 HTJ. TIME -
10<>3i 24:01 24:49 25:17 25:34 26:22
. ^^ /^«-\
ao3
eol
40:
20:
o:
27 00
02:55
27:09
T
rr
-r
24:00 25:00 26:00
File:S975868 tl-905 Acq:13-SEP-1997 02:52:21 SI+ Voltage SIX 70S
409.7974 F:2 Exp:EPCUS
TRIANGLE LABS Text,O-M33-3 TLH43085 IKT. TIMX -
1001
27«00
02i55
80:
60:
40:
20:
0.
23:50
24:10
24:38
3Stii
25:52
JLJL
24:00
25:00
26:19
^»^>A__A.
27:09
26\00
27iOO
1.4E6
1. 0X6
.6.9X5
.3.4X5
.0.0X0
1.3X6
9.3X5
7.0X5
4.7X5
2.3X5
.0.0X0
Tim
27:38
8.3X6
6.6X6
5.0X6
3.3X6
.1. 7X6
O.OEO
.1.5X4
-1.2X4
-8.8X3
.5.9X3
.2.9X3
0.0X0
132
-------
r±J.e,SS75868 H-905 AcqilJ-sSP-1997 OliSiill XI+ Volttym SIM 70S Ho±tet65
355.8546 Tt2 BSC3(256,30,-3.0) PKD(7,5,3,0.05\,260.0,1.00\,r,T) XxptXPCUS
TRIANGLE LABS TmxtiO-M23-3 TLH43085 XK7. JTMT - 02t55
24,48 25:00 25,12 25,24 25,36 25,48 26,00 26,12 26134 26,36 26,48 27:00 27,12 27,24 27,36
r±le:S975868 «1-905 Aoqtl3-SXf-1997 02,52,21 XI* Voltmge SIS 70S Ho±me:54
357.8516 T>2 BSUB(256,30,-3.0) PXD(7,5,3,0.05\,216.0,1.00\rr,T) ExpiXPCUS
TRIANGLE LABS Tejct,O-M23-3 TLH4308S OUT. TIME - 02tSS
100*
A3.39E3
80j
A7.64E3
A6.13E3
-8.1X3
.6.5X3
'-4.9X3
.3.3X3
'.1. 6X3
0.0X0
24:48 25:00 25:12 25,24 25:36 25:48 26:00 26:12 26:24 26:36 26:48 27:00 27:12 27:24 27:36
rile:S97S868 il-905 Acq,13-SEP-1997 02,52:21 EH- Voltage SIX 70S No±ae:62
367.8949 Tt2 BSUB(256,30,-3.0) PKD(7,5,3, 0. 05\,248. 0,1. 00\,T, T) XxptEPCUS
TRIANGLE LABS Text:O-M23-3 TLI#43085 JWJ. TIME - 02:55
1001 A3.Q8E6
so:
tfo:
40:
Time
20:
\2.44E5
A
'.9.1X5
L6.9E5
.4.6E5
-2.3E5
.O.OEO
24:48 25,00 25,12 25:24 25:36 25:48 26:00 26:12 26:24 26,36 26:48 27:00 27:12 27:24 27:36
T±le:S975B68 fl-905 Aoq:13-SEP-1997 02:52:21 EI+ Voltage SIX 70S Noiae:59
369.8919 T:2 BSUB(256, 30, -3 . 0) PKD(7,5,3, 0.05\,236. 0,1. 00\,T, T) ExptEPCUS
TXIAKGLE LABS Text:0-M23-3 TLI#43085 JKT. TIME - 02,55
Tine
100*
80.
60:
401
20:
A2.
.-7.8E5
.6.2X5
.4.7X5
'.3. 1X5
11. 6X5
SI. 65E5
A
.O.OEO
24,48 25:00 25,12 25,24 25:36 25:48 26:00 26:12 26:24 26:36 26,48 27:00 27:12 27:24 27:36
rile:S975868 41-905 Acqtl3-SEP-1997 02:52:21 EI+ Voltage SIX 70S
330.9792 T:2 XxptXPCOS
TXIANGLE LABS Text:O-M23-3 TLIt43085 XKJ. TIME - 03:55
Time
1003
BO.
60.
40.
20.
25:17
25:34 25:50
8.3X6
'.6.6X6
.5.0X6
.3.3X6
.1. 7X6
.O.OEO
24:4825:25i2 25s24 2S36
26 1 48 27:00 27:12 27:24 27:36
Tim^
13
-------
rilatS975868 tl-346 Aoq,13-SXP-1997 02,52,21 XI + Voltaym SIX 70S Holm*, 454
373.8208 f,3 BSUB(256,30, -3.0) PKD(7,5,3,0
TRIANGLE LABS T«xt:O-At23-3 2X1*43085
100]
80:
50:
40:
20.
05%, I8is.o,i.oo%,r, r; xxptxpcos
A1.66E4 A1.04X4 A1.59E4 Al.
J**^- - rt~i A ~\-***
IHJ-. TIME - 02:55
_7.4Jf4
8714 A7.75X3 . , ,
8'X4 j A6.13XJ
.5.5X4
.4.4X4
.3.0X4
.1.5X4
.0.0X0
28:12 28:24 28:35 28:48 25.66 25:12 25:24 25:35 25:48 30:66 30:12 30:24 30:35 30:48 31:00 TlM*
rile:S975868 tl-346 Acq,13-SEP-1997 02,52,21 EH- Voltage SIX 70S Noil* i 327
375.8178 r,3 BSUB(256,30, -3. 0) PXD(7, 5,3,0
TRIANGLE LABS Teit:0-M23-3 TLIt43085
100]
80:
so:
40J
20:
o:
.05\,1308.0,1.00\,r,T) Elp:XPCUS
IKJ-. TIME - 02,55
-1 . 8X5
.1.4X5
.1.1X5
.7.1X4
.3.6X4
O.OEO
28:12 28:24 28:35 28:48 25:66 25:12 25:24 25:35 25:48 30:66 30:12 30:24 30:35 30:48 31:00 Time
Tile:S975868 tl-346 Acq:13-SEP-1997 02:52:21 EI+ Voltage SIR 70S Noisa,295
383.8639 f:3 BSOB(256,30, -3 .0) PKD(7,5,3,0
TRIANGLE LABS Text:O-M23-3 TLIt43085
100]
80:
;
so:
40:
20J
0:.
A2
A
1
i y \
.05\,1180.0,1.00\,r,T) ElpiEPCUS
I7*6 Al.
i \ y
IITJ-. TIME - 02:55
8SE6
1
A1.46E6
A
i y i
-8.1E5
'_6.5ES
-4.9E5
.3.2X5
-.1 . 6E5
0 . OEO
28:12 28:24 28:35 28:48 25:66 25:12 25:24 25:35 25:48 30.'66 30:12 30:24 36:35 ' 30:48 ' 31: 00 Tiae
Tile:S975868 tl-346 Acq:13-SEP-1997 02:52:21 EI+ Voltage SIR 70S Noiae:455
385.8610 F:3 BSUB(256,30,-3 .0) PKD(7,5,3,0 .OS\,1820 .0,1.00\,r,T) Exp:EPCUS
TRIANGLE LABS Text:0-M23-3 TLIf430S5
1003
80:
so:
40:
20:
o:
A4.33E6
J
28:12 28:24 28:35 28:48 25:66 25:
rile:S975868 tl-346 Acq:13-SEP-1997 02:52
392.9760 T:3 Exp:EPCVS
TRIANGLE LABS Tejct,O-H23-3 TX.H43085
1004
80:
so:
40J
20:
o:
A3
J l y
IJCJ. TIME * 02:55
,_! . 7E6
66E6
\ A2.83E6
A
A
I y i
:l . 4E6
.1 . OE6
.6.9E5
.3 . 4E5
O.OfO
12 25:24 25:35 25:48 30:00 30:12 30:24 30:35 30:48 31:00 Time
21 EI+ Voltage SIR 70S
^^^nY^/YN^n^^nVvvXpAV^
^^V\r v\yv» '
UTjr. TIME - 02:55
29:56 30:11 ,0.2B 30:47 _4.3SS
'Wyx^/v\/v>^/\ /^^JYVvflTV
\jf
.3.4E6
.2.6E6
.1 . 7X6
.8.6B5
O.OEO
28:12 28:24 28:35 28:48 25166 25:12 25:24 25:35 25:48 30:66 30:12 30:24 ' 30:35 ' 30:48 ' 31:00 Time
rile:S975868 tl-346 Acq:13-SEP-1997 02:52:21 EI+ Voltage SIR 70S
445.7555 T:3 Exp:EPCUS
TRIANGLE LABS Te*t:0-M23-3 TLJ*43085
100]
80J
60:
40:
20:
o:
28:58
1
I
21" aa&"i4l M.,a9{°
U* — ^JvV^^^^_^O\^^-^AA^AA^^;vVA
-------
nio:SS75B68 #1-346 AcqilJ-SXP-1997 02:52:11 SI+ Voltmg* SIM 70S Hoif9t235
389.8156 Ts3 BSUB(256,30,-3.0) PKD(7,5,3,0.05\,940.0,1.00\,P,T) XxpifPCUS
TXIANGLX LASS T»Xt:O-M23-3 TLIH3085 I1KT. TIM* - 03.55
1001 A4. 5X3
38:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12 30:24 30:36
rile:S975868 #1-346 Acq:13-SEP-1997 02:52:21 EI+ Voltage SIX 70S Hoif»:434
391.8127 T:3 BSUB(256,30, -3. 0) PKD(7,5,3, 0. 05\,1736.0,1.00\,T, T) ExpiEPCUS
TRIANGLE LABS Teit:O-M23-3 TLH43085 IKJ. TIME - 02:55
1001
.9.3X3
28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12
rile:S975868 #1-346 Acq:13-SEP-1997 02:52:21 EI+ Voltage SIS 70S Hoi.ee-.444
401.8558 F:3 BSUB(256,30, -3. 0) PKD(7,5,3, 0. 05\,1776. 0,1. 00\,T, T) Exp:EPCUS
TRIANGLE LABS Text:0-M23-3 TLI#43085 INJ. TIME - 02:55
1001 A2.07E6
A2.63E6
ao:
60:
40.
so:
30:24
30:36
O.OEO
Time
.1.1E6
.9.0ES
6.7E5
4.5E5
2.2E5
O.OEO
28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12 30:24 30:36
rile:S975868 #1-346 Acq:13-SEP-1997 02:52:21 EH- Voltage SIR 70S N6iae:293
403.8529 T:3 BSDB(256,30, -3. 0) PKD(7,5,3, 0. 05\,1172. 0,1. 00\,T,T) Exp:EPCUS
TRIANGLE LABS Text:O-M23-3 TLI#43085 IJKT. TIME - 02:55
10 OS,
00J
so:
40.
20:
A2.16E6
A2.,
9.2E5
7.3E5
.5.5E5
.3. 7E5
.1. 8E5
O.OEO
28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00
File:S975868 #1-346 Acq:13-SEP-1997 02:52:21 EH- Voltage SIS 70S
392.9760 T:3 Ezp:EPCOS
TRIANGLE LABS Text:0-M23-3 TLI#43085 IKT. TIME -
30:12
30:24
30:36
02:55
1001
80.
60.
40.
20.
28:SO.i 39101
29,16
47
29:56
30:11
30:2t
.4.3E6
.3.4E6
.2.6E6
11.7E6
.8.6X5
28:36
28:48
29:00
29:12
29:24
29:36 29:48
30:00
30:12
30:24
30:36
O.OEO
T±mi
-------
'ilm,S975868 tl-390 Acq,13-SEP-1997 03tS2t2i £1+ Voltage SIX 70S Holme,869
407.7818 T>4 BSU*(256,30,-3.0) tKD(7,5,3,0.05\,3476.0,l.OO\,T,T) KxptXPCUS
TSIAXGLX LAM Text,O-M23-3 TUH3085 IHJ. TIM* - 02tS5
1004 A7 62X4
31,48 32:00 32', 12 32', 24 32', 36 32:48 33', 00
rile,S97S868 tl-390 Aoqil3-SEP-1997 02,52,21 XI+ Voltage SIS 70S HOime:477
409.7789 f:4 BSUB(256, 30, -3. 0) PKD( 7,5, 3, 0.05\, 1908.0,1.00\,f,T) ElptEPCUS
TSIANGLX LABS TeittO-M23-3 TLIt43085 1X7. TIME - 02:55
1004 A1.91E4
31:46 32,00 32', 12 32:24 32:36 32:48
rile,S975868 tl-390 Acq,13-SEP-1997 02:52,21 EI+ Voltage SIS 70S
417.8253 f,4 BSUB(256, 30, -3. 0) PKD( 7,5, 3, 0.05\,1988. 0,1 . 00\,T, T)
TSIANGLE LABS Text:O-M23-3 TLH43085 JWT.
33,12
33124
1003
80:
60:
40:
20:
0.
A9.Q8E5
33:00 33,12
Soiae,497
Exp:EPCUS
TIME - 02:55
A6.11ES
33:24
~r
-r
31:48 32:00 32:12 32:24 32:36 32:48
rile:S97S868 tl-390 Aoj,13-SEP-1997 02,52:21 EI+ Voltage SIR 70S
419.8220 F,4 BSUB(256,30,-3.0) PKD(7,5,3,0.OS\,3164.0,1.00\,T,T)
TRIANGLE LABS Text:O-M23-3 TLIt43085 XK7.
10OS A2.09E6
80:
60:
40:
20:
o:
-r
33:00
HOi*e>791
Exp:EPCUS
TIME - 02s55
A1.39E6
i* I i i i 1 i I^P i 'i i" i
33:12 33:24
~r
rr
31:48 32:00 32:12 32:24 32:36 32':48
rile:S975868 tl-390 Acq:13-SEP-1997 02:52:21 XI+ Voltage SIS 70S
430.9729 T:4 ExpsEPCUS
TRIANGLE LABS T&rt,O-M23-3 TLIt43085 TJCJ.
31:49 31,
80:
60:
40:
20:
o:
33:00
3312
i i i i r i i
33:24
.3. 8X5
.3. 0X5
.2.3X5
.1.5X5
.7.6X4
.0.0X0
Time
.8.3X5
.6.6X5
.5.0X5
.3.3X5
.1. 7X5
TIME - 02:55
3258 33:06
.'Vfl' ' ' 32\00' ' ' 32\12' ' ' 32\24 ' ' ' 32\36 ' ' '32:48' '
r±le:S97586S tl-390 Acq:13-SEP-1997 02:52:21 EI+ Voltage SIS 70S
479.7165 F:4 XzptEPCUS
TRIANGLE LABS Teit:0-M23-3 TLIt43085 UTJ.
i I i i i i i I i i i—i—r
33:12 33:24
0.0X0
Time
.3 . OE6
.2.4E6
.1 . 8X6
.1.2X6
.6.0E5
.0.0X0
Tim
TIME - 02: 55
33,00 33:12 33:24
31:48
32:00
32:12
32:24
32,36
32:48
Time
131
-------
23.7766 Tt4 BSUB(256,30,-3.0) PKD(7,5,3,0.OS\,1592.0,1.00\,T,T) Exp:EPCUS
TRIANGLE LABS TvftiO-M23-3 TLH43085 IKT. TIM* - 03i53
0*9
32:00 32i06 32>12 32tl8 32,24 32t30 32:36 32:42 32:48 32:54 33:00
ile:S975868 fl-390 Acqtl3-SEP-1997 02:52:21 EH- Voltag* SIX 703 Noil*: 213
25.7737 T:4 BSUB(256, 30, -3.0) PKD( 7,5, 3, 0. 05\, 852.0, 1.00\,T,T) Exp:EPCOS
IASSLE LABS Tmit:0-M23-3 TLH43085 HKT. TIMS - 02:55
33:06 33:12
O.OEO
32:00 32:06 32:12 32:18 32:24 32:30 32:36 32:42 32:48 32:54 33:00
r±la:S975868 tl-390 Acq:13-SEP-1997 02:52:21 EH- Voltage SIX 70S Koiae:484
35.8169 r:4 BSOB(256,30, -3.0) PKD(7,5,3,0.05\,1936.0,1.00\,T,T) Exp:EPCUS
TXIANGLE LABS T*xt:O-M23-3 TLI»43085 TJW. TIME - 02:55
100^ A1.39E6
eo:
40:
20.
33:06 33:12
Time
32:00 32:06 32:12 32:18 32:24 32:30 32:36 32:42 32:48 32:54 33:00
r±lesS975868 H-390 Aoq:13-SEP-1997 02:52:21 EH- Voltage SIX 70S Hoiae:230
437.8140 F:4 BSUB(256,30,-3.0) PKD( 7,5,3, 0. 05%, 920. 0,1.00\,f, T) ExpsEPCUS
TRIANGLE LABS Text:O-M23-3 TLI*43085 INJ. TIME - 02:55
1001 A1.33E6
so:
so:
-------
ile:S975B68 tl-390 Aoqil3-SXP-1997 02:52:31 11+ Voltfym SIX 70S Noilfi382
41.7428 rt4 BSU*(256,30,-3.0) PKD(7,5,3,0.05\,1528.0,1.00\,F,T) XxptXPCUS
TXIANGLX LABS T*xt:O-M23-3 TLH430B5 IXT. TIM* - 02>55
on
SOI
801
701
sol
50.
40.
30.
32>00 33i00 34:00
Til*tS975868 tl-390 Acq:13-SEP-1997 02iS2>21 EH- Voltage SIX 70S Koit»,354
43.7399 Ti4 BSUB(256,30, -3. 0) PKD(7,S,3, 0. 05\, 1416. 0,1.00\,T, I) Xxp:XPCUS
TRIANGLE LABS
1001
A1.57S4
A2.03S4
A1.54E4
35:00
.3.8X4
.2.5X4
.2.2X4
.2.0X4
ll. 7X4
11.4X4
.1.1X4
.8.4X3
.5.6X3
.2.8X3
-.0.0X0
T±me
Text:0-M23-3 TLIt43085
INJ-. TIME - 02:55
32:00 33:00 34:00
rile:S975868 tl-390 Acq:13-SXP-1997 02:52:21 EI+ Voltage SIX 70S
430.9729 T:4 ExpiEPCUS
TRIANGLE LABS T*xt:O-H23-3 TLIt43085 IJW. TIME
35:00
1003
sol
701
601
sol
40.
30.
20.
10.
0.
31139
32:16
35:51
32:00 33:00 34:00 35:00
rile:S975868 tl-390 Acq:13-SEP-1997 02:52:21 EI+ Voltage SIX 70S
513.6775 T:4 ExptEPCUS
TRIANGLE LABS TejcttO-M23-3 TLH43085 JWJ. TIMX " 02i55
32 55
.3.0X6
.2. 7X6
L2.4E6
12.1X6
.1. 8X6
.1.5X6
.1.2X6
.9. 1X5
.6.1X5
13. 0X5
0.0X0
Tim
32tOO
33:00
34:00
35,00
138
-------
'±le:S975BS8 U-390 Acqtl3-SgP-1997 02:S2t2i xH- Voltmgt SIS 703 Holme,2B6
57.7377 Tt4 BSUB(256,30,-3.0) PKD(7,5,3,0.05%,1144.0,1.00%,r,T) XxpiEPCOS
TRIANGLE LASS Text,O-M23-3 TLIH3085 IJKT. TIM* - 03.55
00\
35tl2 35', 18 35', 24 35', 30 35', 36
ileiS975868 #1-390 Acqil3-SEP-1997 02:52,21 II* Volttgm SIM 70S Noimetlll
59.7348 Ts4 BSUB(256,30,-3.0) PKD(7,5,3,0.05\,444.0,1.00\,T,T) ExpiEPCUS
TRIANGLE LABS Text,O-M23-3 TLI#43085 UKT. TIMS - 02»55
00* A2.44E4
35143
35sl2 35:18 35:24 35:30 35i36
•±le:S975868 tl-390 Acg:13-SEP-1997 02:52:21 EI+ Voltage SIX 70S lK>iae:153
69.7779 T:4 BSUS(256,30,-3.0) PXD(7,5,3,0.05\,612.0,1.00\,T,T) ExpsEPCOS
TRIANGLE LABS Text:O-M23-3 TLH43085 IKJ. TIME - 02i55
003, A8.J
80.
60.
401
20.
35:42
-r
T
35.-1.2 351-18 35:24 35:30 35i36
riletS975868 #1-390 Acq»13-SEP-1997 02iS2i21 SI+ Voltage SIR 70S Noiae>44
471.7750 T:4 BSUB(256,30f-3.0) PXD(7,5,3,0.05\,176.0,1.00\,T,T) ExptEPCUS
TRIANGLE LABS Text.-O-M2.3-J TLI043085 INJ. TIME - 02:55
1001 A8.?BE5
80.
60.
40:
20.
35:42
35:12 35il8 35:24 35:30 35s36
rile:S975868 11-390 Acqil3-SEP-1997 02:52:21 EI+ Voltage SIR 70S
430.9729 T:4 ExpsEPCUS
TRIANGLE LABS Text:O-M23-3 TLH43085 UKT. TIME -
100* 35,23 35:35
00J
60.
40.
20.
35:42
02:55
35,12
35>ia
.O.OEO
Time
2.8E5
2.3E5
.1. 7E5
.1.1E5
.5. 7E4
.O.OEO
T±m
3.715
2.9E5
.2.2E5
.1. 5E5
.7.4E4
35,24
35:36
35:42
.O.OEO
Tim
3.0E6
2.4X6
1. 8E6
.1.2X6
.5.9X5
.0.0X0
Tim
-------
'ile:S975868 #1-346 Acq:13-SEP-1997 02:52:21 EI+ Voltage SIR 70S
73.8208 F:3 Exp:EPCUS
lample Text:O-M23-3 TLI#43085 INJ. TIME =
LOOi
02:55 File Text:O-M23-3 TLI#4»
30 22 _1.0E4
29:00 30:00
ile:S975868 #1-346 Acq:13-SEP-1997 02:52:21 EI+ Voltage SIR 70S
75.8178 F:3 Exp:EPCUS
ample Text:O-M23-3 TLI#43085
.00%
INJ. TIME =
O.OEO
Time
02:55 File Text:0-M23-3 TLI#4»
_7.0E3
30:45
L5.6E3
29:00 30:00
ile:S975868 #1-346 Acq:13-SEP-1997 02:52:21 EI+ Voltage SIR 70S
83.8639 F:3 Exp:EPCUS
ample Text:0-M23-3 TLI#43085 INJ. TIME =
oo ??X17 29:46
Time
02:55 File Text:0-M23-3 TLI#4»
80 1
60 j
40 1
20J
o"
f'J • •LJ-/\ A
(1 "A
u A /
29
V
29:00 30:00
L6.5E5
L4.9E5
13.2E5
L1.6E5
: O.OEO
Time
-------
TLI Project: 43085
Client Sample: O-M23-FB
Method 23 PCDD/PCDF Analysis (a)
Analysis File: S975833
Client Project:
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
S413-004
M23Train
181-55-4ABD
1.000
n/a
DB-5
Date Received:
Date Extracted:
Date Analyzed:
Dilution Factor:
Blank File:
Analyst:
09/03/97
09/04/97
09/11/97
n/a
S975815
BJG
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPX23704
SF56117
S975814
n/a
n/a
n/a
Amlytesw:-:
2,3,7,8-TCDD
1,2,3,7,8-PeCDD
1,2,3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
1,2,3,4.6,7,8-HpCDD
1,2,3,4,6,7,8,9-OCDD
2,3,7,8-TCDF
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
1,2,3,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
1,2,3,4,6,7,8,9-OCDF
totals v:;:.'";;: •'• :'^.,X
Total TCDD
Total PeCDD
Total HxCDD
Total HpCDD
Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF
Amt. (ng) Dt EMPC
EMPC 0.009
0.04
0.02
0.03
0.03
0.03
0.09
0.02
0.04
0.04
0.03
0.03
0.03
0.03
EMPC 0.03
0.02
0.03
'•^f^cJ^Anit'tng) Number Dt EMPQ
EMPC 0.009
0.04 1
0.09 3
0.04 2
0.02 1 0.02
0.08 2 0.09
0.11 4
0.02 1 0.05
Ratio
1.67
1.39
1.22
1.23
0.94
0.94
0.70
1.66
1.36
1.43
1.14
1.17
1.08
1.03
0.88
*T
25:51
29:08
29:13
29:30
32:04
34:38
20:23
24:43
25:29
28:22
28:29
29:00
29:42
32:25
34:44
**Bi*i-' '
o
v<—
B_
B_
B_
B_
B_
Flags
—
Page 1 of 2
X237.PSR vlOO. LARS 6.10.0.
Triangle Laboratories, Inc.®
801 Capitals Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 14:06 09/1 i
-------
TLI Project: 43085
Client Sample: O-M23-FB
Method 23 PCDD/PCDF Analysis (a)
Analysis File: S975833
Internal Standards
13C,2-2,3,7,8-TCDF
13C12-2,3,7,8-TCDD
13C,:-l,2,3,7,8-PeCDF
13C,2-l,2,3,7,8-PeCDD
13Ci2-l,2,3,6,7,8-HxCDF
13Ci2-l,2,3,6,7,8-HxCDD
13Ci2-l,2,3,4,6,7,8-HpCDF
13C,2-l,2,3,4,6,7,8-HpCDD
13Cr-l,2,3,4,6,7,8,9-OCDD
Surrogate Standards (Type A)
37CL,-2,3,7,8-TCDD
13C12-2,3,4,7,8-PeCDF
13Ci2-l,2,3,4,7,8-HxCDF
13C,2-l,2,3,4,7,8-HxCDD
13Ci2-l,2,3,4,7,8,9-HpCDF
•Alternate Standards (Type A)
13C,2-l,2,3,7,8,9-HxCDF
'3Cp-2,3,4,6,7,8-HxCDF
Recovery Standards
13C,2-1,2,3,4-TCDD
13C12-l,2,3,7,8,9-HxCDD
AmL (ng)
3.0
2.9
3.0
3.5
3.3
3.1
3.0
3.5
7.0
%trlN}
3.8
3.6
33
2.9
2.7
Amt (n§)
2.8
33
%R«*very
75.7
71.5
75.4
86.9
81 3
76.5
75.9
87.9
876
% Recovery
95.6
89.4
83 1
72.6
67.8
% Recover^
69.7
81 5
V
QC Limits
40%- 130%
40%-130%
40%- 130%
40%- 130%
40%-130%
40%- 130%
25%-130%
25%-130%
25%- 130%
:VQC Limits^ :';.-::"
70%- 140%
70%- 140%
70%- 140%
70%- 140%
70%- 140%
FQOtiRiltS:'^:
40%- 130%
40%- 130%
: :f\ .,;.
Ratio
0.77
0.80
1.55
1.49
050
1.21
0.42
0.99
086
^•Rallo?:^.
1.59
051
1.23
0.42
t:-R»*
0.49
0 50
^•Ratio:-:^
0.81
1.21
RT
20:22
21:12
24:42
25:51
28-28
29:12
31-11
32:04
34-37
Strr-,,
21:13
25:28
28-21
29:07
32:25
:£ffnr:-V
29:41
-!«?r-
20:59
29:29
Flags
—
—
—
Flags
—
oIL
v
:.?-Ffci>gs";;-:'
*J$*i&:::
—
Data Reviewer.
2LJ.
Page 2 of 2
09/18/97
X237.PSR vlOO. LARS 6.10.04
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham. North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 14:06 09/18/97
142
-------
Data Review By:
Initial ....Date...
£L/.!!/3:
Calculated Noise Area: n/a
The Total Area for each peak with an ion abundance ratio outside
ratio limits has been recalculated according to method requirements.
Page No.
09/18/97
Listing of S975833B.dbf
Hatched GC Peaks / Ratio / Ret. Time
Compound/
H_Z ---- QC.Log Omit Why . .RT. OK Ratio Total .Area. .. Area . Peak . 1 .. Area. Peak. 2. . Rel.RT Compound. Name. . ID.. Flags.
TCDF
304-306
304-306
D
D
DC
DC
DC
DC
DC
DC
DC
DC
NL
SN
SN
SN
SN
SN
SN
SN
2
0:
17:
18:
18:
19:
19:
19:
20:
20:
22:
00
36
12
29
09
28
54
23
54
15
0.
RO
RO
RO
RO
RO
RO
RO
65-
1.
0.
0.
0.
0.
1.
1.
0.
0.
0.
0.89
14
58
21
31
44
14
22
70
81
69
Peaks
0.12
2.64
1.08
1.52
2.34
3.08
10.04
31.84
5.81
7.40
41.38
6.90
13.16
0.820-1.101
0.000
0.364
0.894
0.908
0.940
0.956
5.67 0.977
18.68 1.001 2378-TCDF
1.026
1.092
AN
13C12-TCDF
316-318
316-318
DC
DC
NL 0:
WL 19:
19:
19:
20:
20
20
00
11
:31
:53
:22
:52
:59
0.
RO
RO
RO
65-
1.
0.
0.
0.
0.
0.
1.
0.89
69
73
75
80
77
61
18
5 Peaks
0.
141.
15.
48
6,305
22
6
6,398
87
,93
.12
.40
.72
.14
.92
.30
6.
21,
2,733,
9
4
.48
,58
.69
.63
.63
8.
26
3,572
15
3
O.i
,64
.82
.03
.74
.91
0.951-1.049
0.000
0.942
0.958
0.976
1.000 13C12-2378-TCDF ISO
1 .025
1.030
Above: TCDF / TCDD Follows
TCDD
320-322
320-322
0.65-0.89
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
WH
1
0:
18:
18:
18:
20:
20:
20:
20:
21
21
21
22
22
00
06
13
52
04
23
43
:56
:12
:31
:52
:22
:40
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
a.
0.
1.
0.
1.
2,
0,
0
0
0
0
0
1
14
81
22
57
,09
,28
.58
.83
.56
.40
.21
.30
.18
Peak
0.
0.
1.
1.
0.
2.
0,
0,
12
0
0
0
1
12
12
67
66
17
41
,16
.60
.42
.60
.39
.78
.41
.38
.60
5.48
0.853-1.059
0.000
0.854
0.859
0.390
0.947
0.961
0.977
0.987
9.82 1.000 2378-TCDD
1.015
1.031
1.055
1.069
AN
37C1-TCDD
328
DC NL
0:00
19:39
0.06
130.92
130.92
0.906-1.094
0.000
0.927
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 14:07 Ott1 W
-------
Page No.
09/18/97
Listing of S975833B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
328
13C12-TCDD
332-334
332-334
PeCDF
340-342
21:13
2 Peaks
3,
4,
881.
012.
17 3,881.17
09
0.65-0.89
DC NL 0:
19:
20:
21:
21:
22:
00
52
59
12
34
41
RO
RO
1.
0.
0.
0.
0.
0.
5 Peaks
DC NL 0:
DC SN 22:
DC SN 22:
DC SN 23:
23:
DC SN 24:
DC SN 24:
24:
DC SN 25:
00
34
56
39
49
14
23
43
00
1 .
RO
RO
RO
RO
RO
RO
25:29
DC SN 25:46
DC SN 25:57
DC WH 26:44
340-342
13C12-PeCDF
352-354
352-354
PeCDD
356-358
DC WH 27;
:00
RO
RO
RO
32-
0.
1.
0.
0.
0.
0.
1.
1.
3.
1.
1.
0.
4.
67
79
81 6,
80 4,
78
59
11,
1.78
18
67
72
45
87
82
44
66
05
36
,69
,67
.47
1.29
3 Peaks
DC NL 0
23
24
24
25
25
DC SN 25
26
:00
:48
:20
:42
:00
:28
:45
:28
1.
RO
RO
2.
29.
317.
816.
78.
5.
247.
Tf*nr
i wUL
0.
5.
1.
1.
7.
71
49 13.01
39 2.820.24
30 2,138.52
21 34.15
82 2.53
21
15
48
41
60
57 4.60
0.76
2.90
63.
1,
58
,12 39.40
.50
.09 33.43
1.21
0
0
2
128
.81
.87
.06
.78
32-1.78
0
1
1
1
1
1
2
1
6 Peaks
DC NL 0
DC SN 23
DC SN 24
DC SN 25
DC SN 25
25
DC SN 25
:00
:54
:12
:29
:39
:51
:59
1
RO
RO
RO
RO
RO
RO
.32
0
0
0
5
1
1
0
. 38
.51
.66
.55 5
.55
.59 4
.36
.47
10
-1.78
.86
.06
.23
.78
.96
.67
.46
0
211
28
,398
41
,680
5
16
.12
.92 127.42
.69 17.89
.40 3,280.01
.06 24.96
.89 2,870.11
.92
.36 9.74
1.
001 37C1-TCDD
SUR1
0.906-1.094
0.
16.48 0.
3,497.15 0.
2,677.78 1.
44.06 1.
4.29 1.
0.907-
0.
0.
0.
0.
5.26 0.
0.
0.
23.72 1.
1.
24.66 1.
1.
1.
1.
000
937
990 13C12-1234-TCDD
000 13C12-2378-TCDD
017
070
1.078
000
914
928
957
964
981
987
001 12378-PeCDF
012
032 23478-PeCDF
043
051
082
RSI
I SI
AN
AN
1.093
0.838-1.162
0,
84.50 0,
10.80 0
2,118.39 1
16.10 1
1,810.78 1
1
6.62 1
.000
.964
.985
.000 13C12-PeCDF 123
.012
.031 13C12-P6CDF 234
.043
.072
IS2
SUR2
,377.32
PeCDF / PeCDD Follows —
0
1
2
1
0
38
1
.10
.48
.06
.28
.64
.74 24.22
.00
0.921
0
0
0
0
0
14.52 1
1
-1.026
.000
.925
.936
.986
.992
.000 12378-PeCDD
.005
AN
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 14:07 09/18/97
144
-------
Page No.
09/18/97
Listing of S975833B.dbf
Hatched GC Peaks / Ratio / Ret. Tine
Compound/
M_2.... QC.Log Omit Why . .RT. OK Ratio Total .Area. .. Area. Peak. 1. . Area. Peak. 2. . Rel.RT Confound. Name.. ID.. Fl*««.
356-358
13C12-PeCDD
368-370
368-370
HxCDF
374-376
D
374-376
13C12-HXCDF
384-386
384-386
HxCDD
390-392
DC SN 26:31 RO 0.53
DC WH 26:54 RO 3.33
1 Peak
1.32-1.78
DC NL 0:00 RO 1.00
DC SN 24:42 RO . 2.75
DC SN 24:53 RO 2.05
25:51 1.49
25:59 1.63
2 Peaks
1.05-1.43
DC NL 0:00 1.20
DC SN 27:23 RO 1.48
DC SN 27:30 1.40
DC SN 27:43 RO 5.48
DC SN 27:49 RO 0.46
DC SN 28:00 RO 1. 98
DC SN 28:04 1.35
28:22 1.43
28:29 1.14
DC SN 28:41 1.15
29:00 1.17
DC SN 29:34 RO 6.00
29:42 1.08
4 Peaks
0.43-0.59
DC NL 0:00 0.54
27:21 0.50
27:30 0.50
28:21 0.51
28:28 0.50
DC SN 28:47 RO 0.23
28:59 0.50
29:13 RO 0.74
DC SN 29:29 RO 0.29
29:41 0.49
DC SN 29:53 RO 0.27
7 Peaks
— lV^rtT7
1.05-1.43
DC NL 0:00 1.22
DC SN 28:23 RO 1.67
DC SN 28:29 RO 2.54
DC SN 28:36 RO 0.36
DC SN 28:41 RO 1.76
1.45
0.77
38.74
0.12
5.81
6.30
3,485.93 2,084.63
335.10 207.75
3,821.03
P»f T"in / HvTTlP Fnl 1 nurs — — -
. r&\~ULs I nx\rLfc f OA .L ows — — •
3.25
3.02
6.12
0.60
1.38
2.35
1.62
42.35 24.95
48.34 25.72
1.89
37.58 20.23
0.63
38.79 20.11
167.06
4.98
26.79 8.96
69.75 23.40
3,668.30 1,230.99
4,602.27 1,532.26
1.48
4,273.95 1,421.97
7.90 3.86
2.22
3,176.71 1,044.27
5.60
15,825.67
o • Hvf*rn7 i Uvonn Tr^l 1 nuc
6 ; nxi. Uf i rtxiw uu e o ± i ows
3.13
4.66
3.16
0.96
0.85
1.026
1.041
0.845-1.155
0.000
0.956
0.963
1,401.30 1.000 13C12-PeCDD 123
127.35 1.005
0.955-1.052
0.000
0.962
0.966
0.974
0.977
0.984
0.986
17.40 0.996 123478-HXCDF
22.62 1.001 123678-HxCDF
1.008
17.35 1.019 234678-HxCDF
1.039
18.68 1.043 123789-HxCDF
0.859-1.141
0.000
17.83 0.961
46.35 0.966
2,437.31 0.996 13C12-HXCDF 478
3.070.01 1.000 13C12-HXCDF 678
1.011
2,851.98 1.018 13C12-HXCDF 234
5.23 1.026
1.036
2.132.44 1.043 13C12-HXCDF 789
1 .050
0.950-1.015
0.000
0.972
0.975
0.979
0.982
I S3
AN
AN
AN
AN
SUR3
IS4
ALT 2
ALT1
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitals Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed 14:07
-------
Page No. 4
09/18/97
Compound/
M_Z.... QC.Log Omit Why
Listing of S975833B.dbf
Matched GC Peaks / Ratio / Ret. Tin
.RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Confound.Name.. ID.. Flags.
390-392
13C12-HXCDD
402-404
402-404
HpCDF
408-410
408-410
13C12-HpCDF
413-420
N
413-420
HpCDD
424-426
424-426
13C12-HpCDD
436-438
436-438
DC SN 28:55 RO
DC SN 29:00 RO
29:08
29:13
29:30
3 Peaks
l.<
DC NL 0:00 RO
28:35
29:07
29:12
29:29
4 Peaks
0.
DC NL 0:00 RO
DC WL 31:00 RO
31:12 RO
DC SN 32:06 RO
32:25
2 Peaks
0.
DC NL 0:00 RO
31:11
DC SN 31:29 RO
32:25
DC SN 32:39 RO
2 Peaks
0.
DC NL 0:00 RO
31:26
DC SN 31:45
32:04
DC WH 32:18 RO
DC WH 32:22 RO
2 Peaks
0
DC NL 0:00 RO
31:27
32:04
2 Peaks
3.35
2.13
1.39
1.22
1.23
35-1.43
0.99
1.29
1.23
1.21
1.21
1
88-1.20
2.11
2.71
1.26
3.91
1.03
37-0.51
1.28
0.42
0.78
0.42
0.78
.88-1.20
1.79
1.12
0.91
0.94
3.13
1.84
.88-1.20
0.70
1.00
0.99
0.38
2.15
20.26 11.78
29.32 16.09
32.56 17.95
82.14
4.12
22.18 12.51
2,527.73 1,393.53
3,578.12 1,960.48
4,703.04 2,577.69
.0,831.07
HvOnf^ / UrifTVfi* I?*-il 1 ^Mife
nxt-UJJ / fipCLJr r onows ---
1.55
0.92
37.27 23.11
0.47
20.34 10.56
58.11
1.48
3.165.84 939.83
2.33
1,653.99 489.01
2.82
4,819.83
: HpCDF / HpCDD Follows —
0.80
5.82 3.07
0.90
28.45 13.79
0.31
2.84
34.27
3.02
24.31 12.16
3,368.32 1,672.82
3,392.63
». Ursr-nn / rw-i-a-r^nn smA rm
0.990
0.993
8.48 0.998 123478-HXCDD AN Q
13.23 1.001 123678-HxCDD AN
14.61 1.010 123789-HXCDD AN
0.966-1.034
0.000
9.67 0.979
1,134.20 0.997 13C12-HXCDD 478 SUR4 Q
1,617.64 1.000 13C12-HXCDD 678 IS5
2,125.35 1.010 13C12-HXCDD 789 RS2
0.995-1.044
0.000
0.994
18.27 1.001 1234678-HpCDF AN
1.029
10.28 1.040 1234789-HpCDF AN
0.936-1.128
0.000
2,226.01 1.000 13C12-HpCDF 678 IS6
1.010
1,164.98 1.040 13C12-HpCDF 789 SUR5
1.047
0.976-1.006
0.000
2.75 0.980
0.990
14.66 1.000 1234678-HpCDD AN
1.007
1.009
0.969-1.031
0.000
12.15 0.981
1,695.50 1.000 13C12-HpCDD 678 IS7
Triangle Laboratories, inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 14:07
-------
Page No.
09/18/97
Listing of S975833B.dbf
Hatched GC Peaks / Ratio / Ret.
Tin
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1. . Area.Peak.2. . Rel.RT Compound.Name.. ID.. Flags.
OCDF
442-444
442-444
0.76-1.02
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
1
0:
30:
31:
31:
32:
32:
32:
33:
33:
33:
33:
33:
34:
34:
34:
34:
35
35
35
00
55
32
51
13
35
55
04
21
38
46
59
08
18
:24
:44
:26
:34
:56
RO
RO
RO
RO
RO
RO .
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
0.
0.
2.
1.
7.
0.
1.
1,
1
0,
2
0
0
1
0
0
1
0
1
12
43
15
73
00
,67
.15
.18
.34
.58
.96
.22
.46
.61
.56
.88
.91
.47
.20
Peak
0.
1.
0.
1.
0.
1.
1.
1.
1.
1.
1.
0.
0.
0.
0.
27.
1,
1,
3
27
13
08
49
25
11
53
51
49
17
85
02
23
87
53
96
,70
.55
.55
.29
.70
0.884-1.116
0.000
0.893
0.911
0.920
0.931
0.941
.951
.955
13.00
14.70
0.
0.
0.963
0.972
0.975
0.982
0.986
0.991
0.994
1.003 OCDF
1.024
1.027
1.038
OCDD
458-460
458-460
0.76-1.02
DC ML 0:00 0.86
34:38 0.94
1 Peak
0.13
55.85
55.85
27.09
0.884-1.116
0.000
28.76 1.000 OCDD
13C12-OCDD 0.76-1.02
470-472 DC NL 0:00 RO 2.34 0.72
34:37 0.86 4,277.10
DC WH 34:59 RO 1.61 3.21
470-472 1 Peak 4,277.10
1,971.86
0.995-1.005
0.000
2,305.24 1.000 13C12-OCDD
1.011
IS8
Column Description.
"Why" Code Description QC Log Desc.
M_Z -Nominal Ion Mass(es)
..RT. -Retention Time (mm:ss)
Rat.l -Ratio of M/M+2 Ions
OK -RO=Ratio Outside Limits
Rel.RT-Relative Retention Time
End of Report
WL-Below Retention Time Window A-Peak Added
WH-Above Retention Time Window
SN-Below Signal to Noise Level
-------
rile:5975833 #1-048 Aogill-S£P-1997 12:18:52 21+ Voltage SIX
70S Mbid«i39
303.9016 F:2 BSU*(2S6, 30, -3. 0) PXD(9,5,5, 0.05\,156 .0,1.00\,F,T) XxptETCOS
TRIANGLE LABS T*Xt:0-H23-FB TLH43085 1X7. TIME - 12:21
1001
80J
60:
40:
20:
Al
A6.90X4
i
Jll "Ff A1.99E4 111
... i. ^ JL..A.. -A-,. ,ju M,. JL. K.iA.l\lt *
17:00 18:00 19:00 20:00
225
\
A2.fOX4
\ |L A3. 02X4
.2.9X4
.2.4X4
.1.824
.1.224
.5.9JE3
21(00 22s 00 XisA
rile !S9 75833 #1-840 Acg:ll-SrP-1997 12:18:52 EH- Voltage SIX 70S Noi*»:33
305.8987 F:2 BSUB(256, 30, -3.0) ta>(9,5,S,0.05\rL32.0r1.00\,F,T) Exp:EPCUS
TRIANGLE LABS T«xt:O-K23-FB TLH43085
1001
80:
60.
40:
20:
0'
Al
AS. 67X4
A1.99X4 A1.21E4 lf[
17:00 18:00 19:00 20:00
UOr. TIKE - 12<21
7*5 -4.1X4
\
\
\ rk/\ A9.82E3 ~fj^\ 1
.J.224
.2.424
.1 . 524
.8.123
O.OEO
21:00' 22:00' Tijie
File:S975833 #1-848 Acq:ll-SEP-1997 12:18:52 EI+ Voltage SIR 70S Noiae:415
315.9419 F:2 BSUB(256,30,-3 .0) PKD(9,5,5, 0. 05\,1660. 0,1 . 00%,
TRIANGLE LABS Taxt:O-M23-FB TLI#43085
1003
80:
60:
40:
20:
o:
A2
171-00 18:00 191-00 ' '20:00
r, T) Exp : EPCUS
IIU. TIME - 12:21
• 73JT7 6.5E6
1 {
_5.225
Lj . 925
.2.525
.1.326
O.OEO
'21:00 ' 22.- 00 ' ' Mj»e
rile:S975833 #1-848 Acq:ll-SEP-1997 12:18:52 EI+ Voltage SIR 70S Jfci»e:247
317.9389 r:2 BSOB(256, 30, -3 . 0) PKD(9, 5,5, 0 .05\,988.0, 1.00\,F,T) Exp:EPCUS
TRIANGLE LABS Text:O-M23-FB 111*43085
lOOi
80J
60.
40.
20.
0.
A3
17:00 18:00 19:00 20:00
IttJ. TIME ' 12:21
JE7 8.6X6
.6.9X6
.5.1X6
.3 . 4X6
.1 . 7X6
' 0 . OEO
21\00 ' ' ' '22.- 00 ' Tine
F±le:S975833 #1-848 Ac'<
|l7:10i7.a0 I / AL 1. 19:1* 15»45i j
• ULAJU_M_OAAJ^JL/ A*uuJO_A_A-_AAAAAA^*M_JjuA_»JL L
17:00 18:00 19:00 ' 20:00
IKJ. TIME ' 12 i 21
C1.5X4
21:53
i
» 20,45 21.37 »f«
i.Jftfcj\AAA\A LA^^A^ AA/^/l VX^^L^^uA^
.1.2X4
.9.2X3
.6.2S3
.3.1X3
f a. oxo
21:00 22:00 Tijie
148
-------
FlletS975833 #1-848 Aoqill-SXP-1997 12:18:52 EI+ Voltage SIM 708
319.8965 Fi2 BSV*(256,30,-3.0) rKD(7,5,3,0.05\,1144.0,1.00\rr,T)
TRIANGLX LABS Text:O-M23-FB TLH43085 XX7.
1001 AS. 4
80J
001 A2.78X4
40J A 1
1 jl I A3. 53X3 I
4 ll « na u \ 1 1 1 1
"1 rl~ /^flA -J^JU .. .. A A AiAv/^/lAj*/»M/W\A^wv^»A\-AwwAAvJVwVAA'>'V\™-_A/V/' u.n.ii«Ax JUMJT i
19:00 20:00 21:00
Noi*et286 1
XxptXrCUS
TIM* - 12:21
8X4
\ -
\ A5.04X3
1
1 A5.51« 1 1 -
\*i.69*3 flln , i *J. i, ft -
I^»A !.«.. /LJurUUK/MIU^/JiL Iku
V^AftAHArtyv*/**!!*! WL/»IV lui^ABf»iV»A^'''"-j •
1.5X4
1.0X4
7.7*3
5.1*3
2.6X3
0.0X0
22 i 00 Time
Jile :SS 75833 91-848 Acqill-SXP-1997 12:18:52 XJ+ Vbltag* SIM 70S Noifet35
321.8936 Fs2 BSVB(256,30,-3.0) PKD(7,5,3,0.05\,140.0,1.00\,F,T)
TRIANGLX LABS Text:O-M23-FB TLH43085 IKT.
1001
80:
60l
40:
20:
A9.
Al . 11X4 1
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XxpiKPCUS
TIME - 12s 21
82X4
\ Al . 60X4
V^Aj*. AAj'VA..A^r>jAJlVAA^'W
2.5X4
2.0X4
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0.0X0
22:00 Time
File:S975833 #1-848 Acq:ll-SEP-1997 12:18:52 EI+ Voltage SIR 70S Noiae:1280
331.9368 F:2 BSDB(256, 30, -3. 0) PKD(7, 5, 3,0 .051,5120.0,1. 00\,F,T) ExpsEPCUS
TRIANGLE LABS Text:0-M23-FB TLH4308S INJ
100J
80J
soj
40:
20.
A2 B2E7
A2.
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19:00 20:00 21:00
TIME - 12:21
14X7
\
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.5.9X5
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•.2.7E6
_1 . 4X5
0.0X0
22:00 Time
File:S975833 #1-848 Acqill-SEP-1997 12:18:52 EI+ Voltage SIR 70S Noiae:767
333.9338 F:2 BSOS(256, 30, -3 .0) PKD(7,5, 3, 0. 05\, 3068. 0,1 . 00\,F,T) Eip-.EPCUS
TRIANGLE LABS Text:O-M23-FB TLI#4308S IJTJ. TIME - 12:21
1003
80:
60:
40:
201
AJ.sor?
U2.6flr7
/ \>
19:00 20:00 21:00
V
.8.5X5
16.5X5
1.5.2X5
1J.4X5
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0 . 0X0
22:00 Time
File:S975833 fl-848 Acqsll-SEP-1997 12:18:52 EI+ Voltage SIR 70S Noiae:31
327.8847 F:2 BSOB( 256, 30, -3 . 0) PKD(7, 5, 3, 0. 051,124 . 0,1. 00%, F, T) Exp:EPCUS
TRIANGLE LABS Text:O-M23-FB TLI#43085 IWJ". TIME ' 12:21
1001
80.
60.
40.
20.
0
A3
19:00 20:00 21:00
{E7
1 . 0X7
L8.1X6
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.4.0X6
.2.0X6
O.OEO
22:00 Time
File:S975833 fl-848 Acq:ll-SEP-1997 12:18:52 EI+ Voltage SIR 70S
330.9792 Fs2 ExpiEPCUS
TRIANGLE LABS TexttO-M23-FB TLI*43085 I«J. TIHX - 12:21
100
80
60
40
20
0
t 18-51 19*31 I54?2w?i^S 21-0
':
2 /^4^^v£5ios 22:20 -^
-5.7X6
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15:00 20:00 21:00 22:00 Tim*
14
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rile: 3975833 #1-848 Aoqtll-SXT-1997 12:18:52 XI+ Voltage SIM 70S Hoia»:43
339.8597 n2 BSU*(256, 30, -3.0) PKS(7,5,3
TMIANGLE LABS Text:0-M23-TB TLI#43085
1003
80:
50:
40.
20.
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o:
A3.43E4 A4.60X4
23:00 2ife:253
341.8567 Ts2 BSUB(256, 30, -3.0) PKD(7,5.3, 0 .05\r 1012.0,1 .00\,F. T) XzptXPCUS
TRIANGLE LABS TextiO-H23-FB TLI#43085
1003
80:
50:
40.
20:
o:
A5.26E4
IHJ. TIME - 12:21
A2.37X5 A2.47X5 7.5X4
I
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A1.19E4 M A1.11E4 1 \ AJ--f*8 I A1.03X4 A1.12X4.
•^s***~* ~~**Y***-As*i\m AJJMTVW f~*1~. 1 1^— / — w: — ?TV^A Xi1 "rt — A A1 r. — R — / — \~r~n — m*.n '~nrz — rr — V; IT n — • ' -"' •• — n n • — *-r* •.- .A.
.6.0X4
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23*00 24:00 25iflO 2Sl-00 ' ' ' life
Tile:S975833 #1-848 Acq:ll-SEP-1997 12:18:52 EH- Voltage SIX 70S KOiae:36
351.9000 Ti2 BSUB(256,30,-3.0) PKD( 7, 5, 3, 0. 05\,144.0,1. 00\,T, T) XxptEPCUS
TRIANGLE LABS Text:O-M23-FB TLH43085
100}
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so:
50:
40!
20:
0:
^^^^^
TWT. TIME - 12:21
A3. 28X7 ,.1.1X7
k A2.87X7
ft A
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.8.6X6
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• n nrn
23:00 24\00 25:00 25:00 Time
File:S97S833 #1-848 Acq:ll-SEP-1997 12:18:52 XI+ Voltage SIX 70S KOiae:39
353.8970 T:2 SSUB(256,30, -3 .0) PKD(7,5,3, 0. 054,155. 0,1. 00%, T, T) Exp:EPCUS
TXIANGLE LABS Text:O-M23-FB TLI#43085
1003
80:
50:
40:
20:
o:
INJ. TIME - 12:21
A2.
•2E7 6.9X6
Al . 81X7
1
V 1 i.
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.4. 1X6
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ll . 4X6
23:00 24:00 25:00 26:00 Time
Tile:S975833 #1-848 Acq:ll-SEP-1997 12:18:52 Eli- Voltage SIX 70S
330.9792 F:2 ExptEPCOS
TRIANGLE LABS Text : O -M2 3 -TB TLI#43085
1001
80:
50J
40J
20J
OJ
23 • 12 23 * 32 24 t 0
_r^v.j^^^vN^^^^^-^^-A\x^vV-'
-tyvr/g"^^^^
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JWJ. TIME - 12:21
i 24:19 24*49 25*23 ST'^l o*c IT *• .——
s-s*rv**s**f---*--^r-*~*t ~-~\ x-^w^vs. /V-^^A. />^i^ *£?J^ 26:35
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^-^^^
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23:00 24:00 25:00 26\00 ' ' ' Time
rile:S975833 #1-848 Acqtll-SEP-1997 12:18:52 EI+ Voltage SIX 70S
409.7974 F:2 ExptXPCOS
TRIANGLE LABS Text:O-M23-n TLI#43085
100]
80J
50J
.
401
201
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1NJ. TIME - 12:21
1 24:05 C8.8X3
II
22.-U2
1 ill 22s 53
11 1
fill 1 ft. 1 23:40
26, 3
Aii^A/
.7.0X3
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33l°° 24:00 25:00 ' 26\00 M»c
150
-------
Tll*iSy/5»33 tl-»4U Acq:ll-SEF-1997 11118:52 XI* Voltage SIX 70S Nolf*:JJ
355.8546 T:2 BSUB(256,30, -3 .0) PKD(7 ,5,3,0 .05\, 128. 0,1. 00\,T,T) XxptXPCUS
TXIANGLX LABS Text:O-M23-n TLIt4308S IXT. TXHX - 12:21
10M
SO.
50.
40.
20.
A2.42X5
1
^
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A1.25X4 A1,35C4 A7.50X3 A1.02X4 * '* * 1 \ AI'f5rf '
24:00 ' 25<00 26*00
0.2X4
6.514
t.»X4
3.3*4
1.6X4
9.0*0
Time
r±l»:S975833 #1-048 Acqi ll-SEP-1997 12:18:52 XI+ Voltage SIX 70S Holme : 37
357.8516 t:2 BSUB(256, 30, -3.0) PKV( 7,5, 3,0. 05\,148 .0,1.00\,r, T) XxpiXPCUS
TRIANGLE LABS TfJCt:0-K23-FB TLH43085 IVJ. TIME - 12:21
1003
80.
•
60:
40.
20.
OJ
A1.46E5
A A1.45Z5
I A5.43E4
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24:00 25:00 26:00
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O.OEO
Time
r±le:S975833 #1-848 Acij:ll-SEP-1997 12:18:52 EI+ Voltage SIR 70S Koine -.36
367.8949 1:2 BSUB( 256, 30, -3 . 0) PXD(7, 5,3,0. 05\, 144 .0, 1.00\,F,T) Exp:EPCUS
TRIANGLE LABS Text:O-M23-FB TLH43085 IHJ. TIKE - 12:21
100*
80J
60.
40:
20:
0
A2.
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08£7
1
42.08Z6
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24:00 25:00 2ffiflO
.6.7X6
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0 . OEO
Time
rlle:S975833 #1-848 Acq: ll-SEP-1997 12:18:52 EH- Voltage SIR 70S Ko±ae:35
369.8919 T:2 BSUB(256,30, -3.0) PKD(7,5, 3, 0.05\,140. 0,1. 00\,T, T) Exp:EPCUS
TRIANGLE LABS Text:O-H23-FB TLH43085 IWJ. TIME - 12:21
100J
80.
60.
40.
20
0
k Al.
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40£7
\
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24:00 25:00 26:00
4 . 6E6
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0 . OEO
Time
rile:S975833 #1-848 Acq: ll-SEP-1997 12:18:52 EI+ Voltage SIR 70S
330.9792 F:2 ElptEPCUS
TRIANGLE LABS TexttO-M23-FB TLI#43085 IKJ. TIKE - 12:21
100
80
60
40
20
C
3t 24:01 24:19 24:3824:49 25:04 25:23 25,36 25:53 26:17 ., ,,
• 'VVy-^V\/-A^~'>^AA-s/V^/s./^^Vl — •f-^i~*f — ~~^\ y—^vV/^'VX. /~*\_^-
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rile,S975B33 #1-406 Aaq,ll-SXP-1997 12,18,52 XI* Voltage SIS 70S Nolle: BBS
373.8208 F:3 BSUB(256,30,-3.0) PJO>(7,5,3,0
TSIANGLX LABS Text:O-M23-FB TLI#43085
1003
80:
60:
40:
20:
27
.05\,3540.0r1.00\,r,T) XxpiXPCOS
A2.50X5
H *
1
1
A2.00X4 A2.08X4 ) \
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11
1
' VAii^ff.^J
OUT. TIM* - 12:21
,.9.2X4
02X5
t A3. 01X5
rt A
I ai.. J \
',12 27:24 27\36 27:48 2B\00 28', 12 28 24 28\36 2B\48 29:00 29\12 29:24 29, 36 ' iiliff' 's'oVoo' JolL
.7.4X4
.5.5X4
.3.7X4
.1 . 8X4
I Time
Flle,S975833 #1-406 Acq: ll-SEP-1997 12,18,52 XI+ Voltage SIX 70S Nolme,742
375.8178 F:3 BSUB(256,30e -3.0) PXD(7,5,3,0
TRIANGLE LABS Text:O-M23-FB TLI#43085
1003
ao:
60:
40:
20:
.05%, 2958. 0,1. 00%
r!5
1«.
,,„„
,F,T) ElpiEPCUS
HKT. TIMX - 12:21
-8.2X4
I415 A1.87X5
h ft
I
1 / X6.8BX3
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* ft nrft
27:12 27:24 27:36 27:48 2B\00 2B\ 12 28:24 28\36 28:48 29:00 29:12 29:24 29:36 29:48 ' 30: 00 ' 30^12 M.»
ril«:S975833 #1-405 Acsr.-ll-SW-.Z9P7 12:18:
383.8639 F:3 BSUB(256,30, -3 . 0) PJO>(7,5,3,0
TRIANGLE LABS Text:O-M23-FB TLI#43085
1003
80:
60:
40:
20:
o:
Al
r
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27:12 27,24 27:36 27\4a 28\00 28:12 28^
52 EH- Voltage SIS 70S Nbiae,875
.05\,3500.0,1.00\
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{ J
,F,T) Exp:EPCUS
INJ-. TIME - 12:21
flE? 5.4E6
Al . 04E7
A
V / V
.4.3E6
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.1 . 1X6
24 28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00 30-12 T-,'.»
file :S9 75833 #1-406 Acq:ll-SEP-1997 12:18:52 Eli- Voltage SIS 70S Noiae:1617
385.8610 F,3 BSUB(256,30, -3. 0) PKD(7,S,3,0
TRIANGLE LABS Text:O-M23-FB TLI#43085
loot
sol
601
401
201
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A3
A
/ \
.05%, 6468. 0,1. 00\,F, T) Exp:EPCDS
.07E7 A2.
' V /
JKJ. TIME - 12:21
95*7 1.1E7
\ A2.13E7
!\
V / V
27:12 27:24 27:36 27:48 28': 00 28.-12 28:24 28:36 28:48 29:00 29:12 29:24 29: 36 ' 29: 48 30 '• 00 ' jb'-l
File:S975833 #1-406 Acq:ll-SEP-1997 12:18:52 EI+ Voltage SIS 70S
392.9760 F:3 Exp:EPCUS
TS I ANGLE LABS Text:O-M23-FB TLI#4308S
1003
ao:
60.
40.
20.
0.
27-19
J*-*^-Sf*^&j(4 27-4937:5jL».vvJv5vf;L,A
-8.5E6
.6.4X6
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.O.OEO
1 Time
TNJ-. TIME - 12:31
vv4^A/Sv%J5-" 29l24 29,45 29:56^30^09^2.8X6
^VV ^V^V^^A^V^^^^^^^
W
'-.2.2E6
.1 . 7E6
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27:12 27:24 27:36 27:48 28',00 28:12 28:24 28:36 28.-48 29.-00 29.-12 29:24 ' 29:36 29':48' 30: 66' 30:12 Tiae
File:S975833 #1-406 Acq:ll-SEP-1997 12:18:52 Eli- Voltage SIS 70S
445.7555 F:3 Xxp:XPCVS
TRIANGLE LABS Text:O-M23-FB TLI#43085
1003
80:
60:
401
201
ol
27 22
28:10
|
37 '4i 27,56 |
^AJK lJ(juJ(A*lJ\M~j^KL/Mk
•
38 !30 1 . 28.- 5J
MA^JUVLA.
27:12 27,24 27:36 27t48 28:00 28',12 2B\24 28,36 28',4a"2
IKJ. TIME - 12:21
18.8X3
6.6X3
'
o'oro
9iOO 29:12 29:24 29:35 29:48 30iOO 30il2 Time
152
-------
riJ.*lSy/5BJ3 #1-406 AOJlJ.l-SKf-1997 12iL9>52 XI+ VoJtag* SI* 70S Hoi»»taSB
389.8156 ri3 BSUB(256, 30, -3.0) PXD(7, 5,3, 0 .051,3432.0,1. 00\,r,T) XxpttPCOS
TXIAHSLK LASS T*XtlO-M23-fB TLII43085 J1K7. TIM* - 12(21
1001 AI.79X5
80.
60.
40.
20.
27(40 20(00 20(12 20(24 28:36 20(40 29(00
rile:3975833 41-406 Act}:ll-SEP-1997 12(10(52 XX+ Voltage 31X1703 Naif*:704
391.8127 T:3 BSUB(256,30,-3.0) PKD(7,5,3,0.051,2816.0,1.00\,r,T) ExpiEPCUS
TRIANGLE LABS TtattO-M23-FB TLH43Q85 INJ. TIME - 12(21
1001 JU.32X5 A1.46E5
80.
60.
Al. 51*5
A3.5SE4
o:^£=
2936 294»
40.
20.
A1.49E4
A7.39E3
27i48 28(00 28(12 28:24 28
-------
\ril»,S975633 tl-430 Aoqtll-SXP-1997 13:18,52 11+ Volt*?* SIX 70S Moif0,802
407.7818 Ts4 B9OB(256,30,-3.0) PXD(7, 5,3,0.05\,3308.0,1.00\,T,T) XzpiXTCUS
TRIANGLE LABS T9fttO-H33-FB TLH43085 OKT. TlttX " 13t21
1001
80:
60:
40.
20:
A3.31X5
Al.06X5
A3.02X4
Al.64X4
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-4.7S4
L3.6X4
12.4X4
.1.2X4
31:12 31:24 31,36 3l't48 32', 00 32,13 32,24 32:36
rileiS975S33 tl-430 Acqill-SXP-1997 13,18,52 XI* Voltage SIX 70S Nolle,382
409.7789 r,4 BSUB(256,30,-3.0) PXB(7,5,3r0.05\,1538.0,1.00\,r,T) XxptXPCOS
TXIASGLX LABS TexttO-H33-FB 11.1*43085 JKT. TIMX - 13t31
32,48
.0.0X0
Time
1001
ao:
60:
40:
20:
3X5
Al.03X5
A1.96E4
A7.17E3
A4.30X3
Al.39E4
->\^^—-^v__A^—
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-.4.4X4
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31:12 31:24 31,36 31,48 33:00 33:13 33:34 33:36
rile,S975833 tl-430 Aojsll-SEP-1997 13,18:53 EH- Voltage SIR 70S Stoife,658
417.8253 T:4 BSUB(256,30,-3.0) PKD(7,5,3,0.05\,2632.0,1.00\,r,T) ExpiEPCOS
TRIANGLE LABS Tejct:O-M23-FB TLIt4308S JKT. TIME - 12,21
A9.40X6
A4.89E6
32,48
O.OEO
Tim,
80:
60:
40:
20:
..2.9E6
'-.2.3X6
-1.7X6
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31,12 31,24 31,36 31,48 32:00 32:12 32,24 32,36
rile,S975S33 #1-430 Acq,ll-SEP-1997 13,18:53 EH- Voltage SIR 70S Boiae:513
419.8220 F:4 BSUB(256,30,-3.0) PKD(7,5,3,0.05\,2052.0,1.00\,F,T) Exp:EPCUS
TRIANGLE LABS Text,O-M23-TB TLH43085 ISJ. TIKE - 12,21
1004 A2.23E7
80:
60:
40:
20:
oj
32:48
O.OEO
Tim
31,12 31:24 31:36 31,48 32,00 32:12
Tile,S975833 tl-430 Acq:ll-SEP-1997 12,18,52 EI+ Voltage SIX 70S
430.9729 r,4 Eip-.EPCUS
TRIANGLE LABS Tsjct,O-H23-rB TLI#430BS Z1KT. TIMS -
31,51 ,„.„„ 32,14
A1.16E7
.5.4X6
.4.1X6
.2.7X6
.1.4X6
32,24
32:36
32:48
0.0X0
Tim
lOOi
80.
60:
40:
20.
o:
31:29
^32:02
12:21
32:32
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.2.0X6
'.1.5X6
-.1. OE6
.5.0E5
31,12 31,34 31:36 31,48 33,00 32:12 32:34
rile,S975833 tl-430 Acq:ll-SEP-1997 13:18:53 Eli- Voltage SIR 70S
479.7165 T:4 EipiEPCUS
TRIANGLE LABS Text:0-M33-fB TLH43085 JW7. TIME - 13,31
1001
33:36
33:48
.0. OEO
Tim
31:13
31:34
31,36
31,48
33,00
32:12
33:34
33:36
33,48
154'
-------
F1J.»:SS758JJ H-4JO Aoqtll-SEP-lS97 12:18:52 XI+ VOltMye SIX 70S HO1M»:348
423.7766 T:4 BSUB(256, 30, -3 .0 ) PKD( 7,5, 3,0 .05\, 1392.0,1 .00\,r,T) IxptXTCUS
TRIANGLE LABS T*xt:O-M23-FB TLH4308S IK7. TIMS - 12t21
1001
80.
60.
40.
20.
A
A2.56E4
lAr^/Vx^rr_ ^
iltlS 31; .2 4 31:30 31i3S '31\42 31\48 31»5< 32'i66 32\06 '32\12 32:18 32\24 35 .30
4.7X4
3.8X4
2.8X4
a.*»
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.0.0X0
Time
File:S975833 #1-430 Acqtll-SXP-1997 12:18,52 XH- Voltage SIR 70S Noise: 197
425.7737 T>4 BSUB(256, 30, -3.0) PKD(7, 5,3, 0 .05\, 788.0, 1.00\,F,T) ExpiXPCOS
TRIANGLE LABS TeitiO-H23-TB TLH43085 IK7. TIME - 12i21
100]
80J
60.
40:
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20.
A'-
Al . 39E4
^^J\^_^^^
31:18 '31:24 31:30 31:3ff 31\42 31:48 31:54 32:00 32:05 32\12 32:18 32:24 32i30
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Time
rile:S975833 11-430 Acq: ll-SEP-1997 12:18:52 EI+ Voltage SIR 70S Noiae:770
435.8169 T:4 BSOB(256, 30, -3 .0) PKD( 7,5,3, 0. 05\,3080. 0,1 . 00\,F, I) Exp:EPCDS
TRIANGLE LABS Teit:O-H23-FB TLI«430B5 TK7. TIME - 12:21
100J
so:
so:
40:
20.
0
A1.67E7
A
/ \
/ \
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31:18 31:24 31:30 31:35 31:42 31\48 3l':54 32:00 32:05 32:12 32:18 32:24 32i30
-4.3E6
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11 . 7E6
L8.7E5
0 . OEO
Time
r±le:S975833 «1-430 Acq: ll-SEP-1997 12:18:52 EI+ Voltage SIR 70S Ko±ae:1101
437.8140 T:4 BSUB(256, 30, -3. 0) PKD( 7,5,3, 0.05\,4404. 0,1. 00%, f,T) Exp:EPCUS
TRIANGLE LABS TextiO-M23-FB TLI#43085 I1KT. TIME - 12:21
1001
80.
60.
40.
20.
0
A1.70E7
A
/ \
/ \
J \
31:18 311-24 31:30 31:35 31:42 31:48 31:54 32:00 32:05 32:12 32:18 32:24 32:30
-4.3E6
.3.416
.2.6E6
.1 . 7E6
.8.6E5
.O.OEO
Time
Tiles S975833 fl-430 Acq: ll-SEP-1997 12:18:52 EI+ Voltage SIR 70S
430.9729 T:4 EzpsEPCUS
TRIANGLE LABS Text:O-H23-FB TLI (43085 ISJ. TIME - 12:21
100
80
60
40
20
0
^ 31:22 31s29 31:36 31:42 3{t** 3a.oa J^v5~- fV*J\ y^^
- ^ X/V^^v/ ^-A^^V-^^^^^-^
•^
-
31:18 311-24 jit30 31:36 31:42 31:48 31:54 '32:00 32:05 32:12 3224 32>30
-2.SE6
.2.0E6
.1.5X6
.1 . 0X6
.5.0X5
. .o.oxa
Xlmm
------- OCR error (C:\Conversion\JobRoot\000004IN\tiff\2000EY2Z.tif): Saving image to "C:\Conversion\JobRoot\000004IN\tiff\2000EY2Z.T$F.T$F" failed.
-------
*,sy/3ejj fi-«ju AcqtJ.i-ssf-j.ay/ utioisa EI+ vojicag* si* /us noim»,jy
57.7377 Ti4 BSUB(256,30,-3.0) PKD(7,5,3,0.05\,116.0,1.00\,r,T) XipiXTCOS
IANGLX LABS T*XttO-M23-r* TLXH3085 XX7. TIM* - 12131
001 A3.;
80.
60.
40.
20.
04-
34t24 34130 34:36 34,42 34,46 34,54
iletS975833 H-430 Acqill-SEP-1997 12,18,52 11+ Volt*ye SIS 70S ttoimms33
59.7348 T,4 BSOB(256,30,-3.0) PKD(7,5,3,0.05\,132.0,1.00\,T,T) SxptEPCOS
TRIANGLE LABS T«Xt:O-M3J-fB TLH430S5 INJ. TIME - 12,21
001
80.
60J
40.
20.
34:24 34:30 34:36 34:42 34:48 34:54
rile:S975833 #1-430 Acqsll-SEP-1997 12:18:52 EI+ Voltagre SIS 70S N6ise:446
69.7779 r,4 BSUB(256r30,-3.0) PU>(7,5,3,0.05\,1784.0,1.00\,T,T) ExpiEPCOS
TRIANGLE LABS T»lt:O-H23-rB TLH43085 IKT. TIME - 12:21
1001 A1.97E7
34,24 34,30 34:36 34:42 34:48 34:54
rile:S97S833 #1-430 Aoqtll-SEP-1997 12:18:52 EH- Voltage SIS 70S JK>iae:192
471.7750 T:4 BSOB(256,30,-3.0) PKD(7,5,3, 0.05%,768.0,1.00\,r,T) Eip:EPCUS
TRIANGLE LABS Text:0-M23-FB TLH43085 UKT. TIME » 12:21
100*
so:
34:24 34:30 34:36 34:42 34:48
F±le:S975833 #1-430 Acqsll-SEP-1997 12:18:52 EI+ Voltage SIX 70S
430.9729 r:4 ExpiEPCUS
TRIANGLE LABS T*rt:0-H23-FB TLH43085 INJ. TIME -
34:54
12:21
1003
80.
60.
40.
20.
0.
34:52
35,00
35:00
O.OKO
Time
-2.2E6
'.1. 8E6
-1.3E6
.8.9E5
.4.4E5
35:00
O.OSO
TJJ*
2.6X6
.2.1X6
-1.SE6
'.1. OE6
'.5.2E5
35:00
.0.0X0
Tim
34:24
-2.3S6
11 . 8E6
-9.1XS
.4.6X5
34,30
34s 36
34142
34:48
34,54
.0.0X0
J5JOO Time
-------
Channel I 338,3792 Peak top
Height 3,25 udts Span 288 pp«
Systei file na*EPOJS2
Data fdenaie fl=$911971
Resolution 18868
Group matter 2
lonlzklon aode El*
Switching VOLTflGE
Ref, masses 232,3825, 416.3788
ft 293 J 331 3 368
B 384 K 332 T 378
L 334 U 376
H 348 V 418
N 342
0 352
P 354
9 356
R 358
Ref, lass 416.3768 Peak top
Height ,72 volts Span 288 ppi
15
-------
'ile:S975833 #1-848 Acq:ll-SfiP-1997 12:18:52 EI+ Voltage SIR 70s
19.8965 F:2 Exp:EPCUS
'ample Text:O-M23-FB TLI#43085
.00%
90E4 >
INJ. TIME = 12:21 File Text:O-M23-FB TLI
r_1.3E4
20:00 21:00 22:00
ile:S975833 #1-848 Acq:ll-SEP-1997 12:18:52 EI+ Voltage SIR 70S
21.8936 F:2 Exp:EPCUS
ample Text:O-M23-FB TLI#43085
.00%
O.OEO
Time
80J
601
40 j
20_i
OJ
INJ. TIME = 12:21 File Text :O-M23-FB TLI»
r_2.5E4
20:00 21:00 22:00
ile:S975833 #1-848 Acq:ll-SEP-1997 12:18:52 EI+ Voltage SIR 70S
31.9368 F:2 Exp:EPCUS
O.OEO
Time
amp
00%
80J
60.;
40J
20J
0:
le Text:O-M23-FB TLI#43085 INJ. TIME = 12:21 File Text:O-M23-
20:59
A
l\ 21:12
1 1 r\
A
l\l\
w — i — i i 1 1 1 1 1 i 1 1 1 1 1— — ~r T - i i i —
20:00 21:00 22:00
FB TLI»
6.9E6
L5.5E6
L4.1E6
L2.7E6
L1.4E6
" O.OEO
Time
-------
ile:S975833 #1-430 Acq:ll-SEP-1997 12:18:52 EI+ Voltage SIR 70S
07.7818 F:4 Exp:EPCUS
ample Text :0-M23-FB TLI#43085^ INJ. TIME =
.00%
12:21 File Text:O-M23-FB TLI»
_5.9E4
30:48 31:00 31:12 31:24 31:36 31:48
lle:S975833 #1-430 Acq: ll-SEP-1997 12:18:52 EI+ Voltage SIR 70S
09.7789 F:4 Exp:EPCUS
32:00
32:12
Time
.'ample Text :O-M23-FB TLI#43085
.00%
INJ. TIME = 12:21 File Text .-O-M23-FB TLI»
30:48 31:00 31:12 31i24 31:36 31:48 32:00 32:12
•ile:S975833 #1-430 Acq:ll-SEP-1997 12:18:52 EI+ Voltage SIR 70S
17.8253 F:4 Exp.-EPCUS
iample Text:O-M23-FB TLI#43085 INJ. TIME = 12:21 File Text:O-M23-FB TLI»
.00% 31A11 .-2.9E6
80J A L2.3E6
60- I \ L1.7E6
40J / \ L1.2E6
20J / \ L5.8E5
i — I — i — i
30:48
i — i — I — i — i
31:00
31:12
i — i — i — | — i — i — i — i — i — I — i — i — i — i — i — | — i — i — i — i — i — I — i — i — i — i — i — | — i — i — r-
31:24 31:36 31:48 32:00 32:12
O.OEO
Time
-------
>ile:S975833 '11-430 Acq:ll-SfeP-19'97 12:18:52 EI+ Voltage SIR 70S
141.7428 F:4 Exp:EPCUS
.'ample Text :O-M23-FB TLI#43085 INJ. TIME = 1.2,:21 File Text :O-M23-FB TLI>
L00% f^Al. OE5)
31:00 32:00 33:00 34:00
'ile:S975833 #1-430 Acq:ll-SEP-1997 12:18:52 EI+ Voltage SIR 70S
:43.7399 F:4 Exp:EPCUS
lample Text :O-M23-FB TLI#43085 INJ. TIME = J^L:21_J?ile Text:O-M23
O.OEO
Time
FB TLI»
2.2E4
35:00
31:00 32:00 33lOO 34:00
'ile:S975833 #1-430 Acq:ll-SEP-1997 12:18:52 EI+ Voltage SIR 70S
69. 7779 F:4 Exp:EPCUS
iample Text:O-M23-FB TLI#43085 INJ. TIME = 12:21 File Text:O-M23
.00% 34;37
80 j
60J
40 j
20J
31:00
1 I 1 1-
32:00
-i 1 1 1 r
33:00
-i 1 1 r
34:00
.O.OEO
Time
FB TLI»
2.2E6
L1.8E6
L1.3E6
_8.9E5
4.4E5
35:00
O.OEO
Time
-------
TLI Project: 43085
Client Sample: O-M23-FB
Method 23 TCDD/TCDF Analysis (DB-225)
Analysis File: P973861
Client Project:
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
S413-004
M23Train
181-55-4ABD
1.000
n/a
DB-225
Date Received:
Date Extracted:
Date Analyzed:
Dilution Factor:
Blank File:
Analyst:
09/03/97
09/04/97
09/13/97
n/a
P973852
JM
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPC2NF04
PF22206
P973859
n/a
n/a
n/a
Analytes
Amt. (ng) PL
f-MPC Ratio
8T
Flags
2,3,7,8-TCDF
ND
0.05
Internal Standard
Ratio
"C,2-2,3,7,8-TCDF
2.8
70.9
40%- 130%
0.77 20:38
Recovery Standard
Ratio
RT
13C12-1,2,3,4-TCDD
0.82
19:40
Data Reviewer
O/l / ,
- ^r _?_ * ' r^-' i - '>
Page 1 of 1
09/18/97
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 15:53 09/1
-------
Initial
Date...
Data Review By:
J~ ^ / (*£/ I-T Calculated Noise Area: 1.26
The Total Area for each peak with an ion abundance ratio outside
ratio limits has been recalculated according to method requirements.
Page No.
09/13/97
Listing of P973861B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
TCDF
304-306
304-306
0.6S-O.S9
DC NL 0:00 0.81
DC SN 20:39 RO 0.46
0 Peaks
2.01
1.17
0.00
0.786-1.095
0.000
1.001 2378-TCDF
AH
13C12-TCDF
316-318
DC
DC
0.65-0.89
0:00 RO 0.96
2.63
NL
WL 19:21 RO
19:38 RO 2.07
20:38
0.77
316-318
DC WH 22:11 RO 3.45
2 Peaks
2.64
1.29
2.96
249.60
0.55
252.56
3.45
108.39
0.952-1.048
0.000
0.938
1.67 0.952
141.21 1.000 13C12-2378-TCDF ISO
1.075
Above: TCDF / TCDD Follows
13C12-TCDD 0.65-0.89
332-334 DC NL 0:00 RO 2.30 1.43
19:26 0.79 204.62
19:40 0.82 253.67
DC SN 20:19 RO 0.93 2.41
332-334 2 Peaks 458.29
90.32
114.52
0.897-1.103
0.000
114.30 1.000 13C12-2378-TCDD IS1
139.15 1.012 13C12-1234-TCDD RSI
1.045
Column Description "Why" Code Description QC Log Desc.
M_Z -Nominal Ion Mass(es)
. .RT. -Retention Time (mm:ss)
Rat.l -Ratio of M/M+2 Ions
OK -RO=Ratio Outside Limits
A-Peak Added
K-Peak Kept
D-Peak Deleted
WL-Below Retention Time Window
WH-Above Retention Time Window
SN-Below Signal to Noise Level
-------
Voltmg* 3IS 7 OP
'11*,P973B61 tl-755 Aoy,13-SxP-1997 11,57,55
03.9016 SjcptDB225
TANGLE LABS Tmxt:O-M33-n TLIt43085
21:00 21:12 21:24 21:36 21:48 22:00 22:12
r±le:P973861 fl-755 Atxj:13-SEP-1997 11:57:55 EH- Voltagre SIS 70P
319.8965 ExpsDB225
TRIANGLE LABS Text:0-M23-FB TLH43085
100$ 21:30
22:24
22:36
f O.OEO
22:48
21:58
22:06
22:29
22:40 22:55
22:49
45:
40.
35.
30l
25.
20.
15J
10.
23:00 Time
8.5E3
8.1E3
7.6E3
7.2X3
6.8E3
6.4E3
.5.9E3
.5. 5E3
.5.1E3
.4.7E3
.4.2E3
-.3. 8E3
.3. 4E3
.3.0E3
.2.5E3
.2.1S3
:1. 7X3
.1.3X3
.8.5X2
.4.2X2
31 00
31113
21:24
21:36
31:48
22100
22113
32134
23136
22:48
r^_-.0.0X0
23 00 T±M
164
-------
•1J.»:P973B6± tl-733 AoqtJ.J-SXP-1997 Ui57l55 EI+ Volt*g» SIM70P Hoim»l450
03.9016 BS03(25«,30r-3.0) PKD(5,3,1,0.10\,1800.0,0.00\,r,r) Xzp:DB225
TXIANGLE LABS T»*t.tO-K23-TB TLIt43085
00\
17100 IB'tOO 19,00 20100 21:00
ile:P973861 tl-755 Aoq:13-SXP-1997 11>57>55 EI+ Voltage SIS 7OP No±fm,554
05.8987 BSOB(2S6,30,-3.0) PKD(5,3,1,0.10\,3216.0,0.00\,T,r) Xxp:DB225
TXIAHGLX LABS T»JCt:O-M23-rB TLH4308S
00\ A1.12K4
22tOO
17:00 IS', 00 19': 00 20:00 21iOO
F±le:P973B61 tl-755 Acqtl3-SEP-1997 ll:S7i55 EH- Voltaga SIX 70P HO±aet714
15.9419 BSUB(25S,30,-3.0) PKD(5,3,1,0.10\,2856.0,0.00\,F,r) SxptDB225
TRIANGLE LABS TexttO-H23-TB TLH430B5
1001 A1.Q8E6
80.
60.
40:
201
22iOO
17:00 10:00 25:00 20:00 21:00
rileiP973861 tl-755 Acqil3-SEP-1997 11:57:55 EI+ Voltage SIX 70P Hoiaet747
317.9389 BSOB(356r30,-3.0) PKD(5,3,1,0.10\,2988.0, 0.QO\,T,T) ExpsDB225
TRIANGLE LABS T&Xt:O-M23-FB TLHH3035
22:00
1003
801
SO.
40.
301
A1.41E6
17 \ 00 18,00 19:00 20,00 21:00
rlleiP973861 tl-755 Ac?>13-SEP-1997 11:57:55 11+ Voltuga SIX 70P
375.8364 Exp:DB225
TRIANGLE LABS T*xt:O-M33-rB TLH43085
1003k
22:00
17,00
18:00
19:00
20100
21100
22100
3. OE5
.2.4X5
.1. 8E5
.1.2X5
.6.1X4
.0.0X0
T±m
3. 8X5
,3.1X5
.2.3X5
.1. 5X5
.7.7X4
.0.0X0
T±m
19t54 21:22
20:21 20:44
165.
-------
ISiOO 19!00 SOiOO 31.00
Flle,P973861 #1-755 Aoq:13-SXP-1997 Ili57i55 XI+ Voltage SIX 70P Halfft518
31.8936 BSUB(256r30,-3.0) PXD(5,3,1, 0.10\,2073.0fO.OO\,F,F) Kxp:DB225
TRIANGLE LABS Text:O-K23-FB TLH43085
10(71
80.
'Ile:py73861 91-755 AoqiJ.J-SKP-J.SS7 ll:S7lSS XI + Voltage SIM 70P HOim»:SlJ
19.8965 B3UB(256,30,-3.0) PKD(5,3,1,0.10\,3048.0, 0.00\,r,r) Xxp:DB325
tlAHSLX LABS TexttO-M33-FB TLH43085
00\
AS.12X3
A6.55X3
^4.4X3
A4.40X3
.88X31
32,00
T±mt
18,00 19:00 20:00 21:00
r±le:P973B61 #1-755 Acq:l3-SEP-1997 11:57:55 SI+ Voltage SIX TOP M&iae.-515
327.8847 BSUB(256,30,-3.0) PKD(5,3,1,0.10\,2064.0, 0.00\,r,T) ExptDB235
JAWCir LABS Text>O-M23-rB TLH43085
1003, A1.S2E6
so:
so:
40:
30.
18:00 19:00 20:00 31:00
Til*:P973861 #1-755 Acg:13-SEP-1997 11:57:55 EI+ Voltage SIX 70P Mai«et928
331.9368 BSUB(2S6,30,-3.0) PKD(5,3,1,0.10\,3712.0,0.00\,r,r) Exp:DB225
TRIANGLE LABS Tfat:O-M23-FB TLIt43085
1001 A1.J.5E6
80J
601
401
20L
o:
A9.03E5
18*00 ISsOO 20:00 21:00
F±le:P973861 #1-755 Acq:13-SXP-1997 11:57:55 XI+ Voltage SIS 70P Hoiae:403
333.9338 BSOB(356,30,-3.0) PKD(5,3,l,0.10\,1612.0,0.00\rF,F) Xlp:DB225
TRIANGLE LABS Text:O-M33-FB TLI*43085
A1.39X6
A1.14E6
80J
60.
40.
30.
0.
18:00
22: 00
22:00
22:00
.4.3ES
'.3.4X5
-2.6X5
.1. 7X5
.8.6X4
0.0X0
Tim
-3.1X5
.2.5X5
.1. 9X5
.1.3X5
.6.3X4
.0.0X0
Tim
19:00
20100
31:00
22:00
.3.8X5
.3.0X5
.2.3X5
'.1.5X5
.7.6X4
0.0X0
Xlm)
166
-------
ni*i
303. i
TXXJU
1004
^
40:
sol
0.
Tile
315..
TXIAi
100J
80J
50J
40:
sol
File
319.
XRIA
1001
Bol
60l
401
SO.
0.
rile
331.
TRIA
1001
aol
6ol
401
aol
o-
r±ie
293.
TXIt
1003
80.
60.
40.
20.
0.
rilt
330
TXI1
100!
80.
60.
40.
20.
0
P973861 41-755 Aoqil3-SXT-1997 Ili57i55 XI + Voltage SIM 70P
1016 Exp:DB225
KLX IMS TmxttO-H23-FB TLH43085
H^^^
17(00 18(00 19(00 20(06 21<00 ' 22(00
IP973861 #1-755 Acq,13-3i:P-1997 11(57(55 II* Voltage SIX 70P
9419 EiptD3225
ttSLE LABS TtxtiO-M23-FB TLH43085
20t38
1
17(06 18(00 19(00 20(00 21(00 22(06
(P973851 *l-755 Acqtl3-SEP-1997 11(57(55 EH- Volt»ge SIX 70P
8965 Exp -.03225
NC£JT LABS T*xt:O-M23-TB TLI»43085
I 17(50 20 t 19 21 (JO
17(06 18(00 IPl'OO 20(00 21(00 22(06
IP973861 #1-755 Acqtl3-SEP-1997 11(57(55 JEI+ Voltage SIX 70P
9368 EipsDB225
NSLE LABS TeJCt:O-M23-FB TLH43085
19 -.40
"il
III
17(06 18.'o6 15(06 20(00 21(00 22(00
(P973851 #1-755 Acq:13-SEP-1997 11:57:55 EI+ Voltage SIS 70P
9825 ExptDB225
\XSLE LABS Text:0-M23-fB TLI*43085
1.^^15^55^17(21 17(54 18:20 18(5019(15 19(4tf 20(47 21(47 22(45
17(06 ' 18:00 ' ' 19(00 20(00 ' 21(06 22(06
»(P9738ffl #1-755 Ac9:13-srP-1997 11(57(55 EH- Voltage SIX 70P
9792 ExptDB225
UIGLS LABS TextiO-M23-rB TLI4430B5
^J£«2917(0<> i7. 53 18(47 19(49 20.-J9 21:24 22-01 32,42
• T^^f^ I " *— V*w>V-''V-~vw ^v*~ w»^**> -~" •'» f\j^jr~***s*-. T>^^Asr^-i^yV- ,«,,.,^.. . .. .^..-^^.-.^^--u.v
j V
.a. 4X3
.7.5K3
.5.7X3
.3.9X3
.1.9X3
0.0X0
Am
.3.1X5
.2.5X5
.1 . 8X5
.1.2X5
.6.2X4
0 . 0X0
Time
.9.4X3
-7.5E3
.5.7X3
.3 . 8X3
.1 . 9X3
.0.0X0
Time
3.2E5
.2. 6X5
.1.9X5
.1.3E5
.6.4X4
• Q OEO
rue
-9.5E5
:7.7E6
.5.8X6
.3 . 8X6
.1.9X6
.0.0X0
Time
..1.217
9.6X6
7.3X6
4.8ft
.2.4X6
•o.oxo
17(00 18(06 19(06 20(00 21(06 ' ' ' 22(06 ' Tim*
-------
fef. tass 292,9825 Peak top
Height 1.61 volts Span 288 ppi
Systa file naie
]ka file naie
Resolution
Group ruter
lonlzatlon Mde
Switching
Ref, lasses 292.9825,
fi:P973861
292.9825
383.9816
385.8987
315.9419
317.9389
319.8965
321,8936
327,8847
338,9792
J
K
L
I
1
El*
VQLTRGE
388.9761
338.9792
331.9368
333,9338
3^,8364
Channel I 336.9792 Peak top
Height 1,83 volts Span 266 pet
168
-------
TLI Project: 43085
Client Sample: I-M23-1
Method 23 PCDD/PCDF Analysis (a)
Analysis File: S975834
Client Project:
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
S413-004
M23Train
181-55-5ABD
1.000
n/a
DB-5
Date Received:
Date Extracted:
Date Analyzed:
Dilution Factor:
Blank File:
Analyst:
09/03/97
09/04/97
09/11/97
n/a
S975815
BJG
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPX23704
SF56117
S975814
n/a
n/a
n/a
: • ; ••••;•;--.--_•: ; ;. r :.• -f ;.;.; .
Analytes .--• •••••;?:v:-': •
2,3,7,8-TCDD
1,2,3,7,8-PeCDD
1,2,3,4.7,8-HxCDD
1,2,3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
1,2,3,4,6,7.8-HpCDD
1,2,3,4,6,7,8,9-OCDD
2,3,7,8-TCDF
1,2,3,7.8-PeCDF
2,3,4,7,8-PeCDF
1,2,3,4.7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
1,2,3,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
1,2,3,4,6,7,8,9-OCDF
$0W*;* ;,,.,> ;^=v:
Total TCDD
Total PeCDD
Total HxCDD
Total HpCDD
Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF
-;•• :::-;v.r::-^int^ (ng)
ND
ND
ND
ND
ND
ND
9.7
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
^.4;f.l:.:VAnBt(tng)
ND
ND
ND
EMPC
EMPC
0.47
ND
ND
01. EMPC?-
0.06
0.2
0.2
0.2
0.2
0.3
0.05
0.09
0.09
0.1
0.1
0.1
0.2
0.2
0.2
0.3
Number DL EMPC
0.06
0.2
0.2
0.35
0.18
1
0.1
0.2
j^ * .Afe^fe •"* ^mm
R«tK> 8T t^fcgs
0.93 34:43
- .-\ ^ flags
—
_.
Pagel of 2
X237.PSR rlOO. LARS 6.1904
Triangle Laboratories, Inc.®
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 14:07
-------
Project: 43085
iient Sample: I-M23-1
Method 23 PCDD/PCDF Analysis (a)
Analysis File: S975834
Internal Standards
3C,2-2,3,7,8-TCDF
!Ci:-2,3,7,8-TCDD
'CiZ-l,2,3,7,8-PeCDF
3C,2-l,2,3,7,8-PeCDD
3Cp-l,2,3,6,7,8-HxCDF
'C,:-l,2,3,6,7,8-HxCDD
'Cr.-UJA^S-HpCDF
3C,:-l,2,3,4,6,7,8-HpCDD
3Cp-l,2,3,4,6,7,8,9-OCDD
Surrogate Standards {Type A)
7CL-2,3,7,8-TCDD
3C,2-2,3,4,7,8-PeCDF
3Ci2-l,2,3,4,7,8-HxCDF
3C,;-l,2,3,4,7,8-HxCDD
3Cr-l,2,3,4,7,8,9-HpCDF
Alternate Standards (Type A)
JC,2-l,2,3,7,8,9-HxCDF
3C,2-2,3,4,6,7,8-HxCDF
Recovery Standards i : iy;
3C!2-1,2,3,4-TCDD
3CI2-l,2,3,7,8,9-HxCDD
Ami (ng)
2.9
2.9
2.0
1.8
26
2.8
2.2
2.4
4.5
Arift. (ng)
4.1
3.7
47
3.6
44
Arat: (ng) ;;:
3.2
3.1
'•:•; i.;: ;;--: • ="•• ;' /K..
%R»covwy
72.8
73.3
50.6
45.4
654
70.9
56.0
59.6
558
^;;'^1R*coverr
102
92.1
117
89.9
f^v.%;^coyery
80.6
76.4
V;" ..;.|::.::.;.;'::d|;;|'.- . ;>.,.
QC Limits
40%-130%
40%- 130%
40%-130%
40%- 130%
40%- 130%
40%- 130%
25%- 130%
25%- 130%
25%- 130%
: OgUmits
70%- 140%
70%- 140%
70%- 140%
70%- 140%
70%- 140%
; : QG: Limits
40%-130%
40%- 130%
Ratio
0.74
0.87
1.56
1.56
051
1.24
0.43
1.04
0.79
Ratio
1.49
054
1.22
045
Ratio
0.51
0.52
Ratio
0.86
1.17
, wr
21:09
21:51
25:08
26:12
28-42
29:23
31:21
32:10
34-45
RT
21:52
25:52
28-36
29:18
32-31
8T"i'f
29:53
29:12
HT
21:37
29:40
Fiags
Q_
n
Q_
Q_
Q
O
Flags
Q
Q_
o
V
•;:Ftegs;k
Q_
Q
FNjs^I
Q
Data Reviewer
't -K-L<-i-'O
Page 2 of 2
09/18/97
X237.PSR V2.00. LARS 6.10.04
Triangle Laboratories, Inc.®
301 Capitola Drive • Durham, North Carolina 27713
3hone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 14:07 09/18/97
170
-------
Initial
. .Date. .
Data Review By:
Calculated Noise Area:
1.48
The Total Area for each peak with an ion abundance ratio outside
ratio limits has been recalculated according to method requirements.
Page No.
09/18/97
Listing of S975834B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK .Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. FLmg*.
TCDF
304-306
304-306
13C12-TCDF
316-318
316-318
TCDD
320-322
320-322
0.65-0.89
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
SN
SN
SN
SN
SN
1
NL
WL
SN
WH
1
NL
WL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
0:
18:
18:
18:
19:
19:
20:
00
16
35
55
17
35
03
RO
RO
RO
RO
RO
RO
0.
0.
0.
1.
0.
0.
0.
29
97
59
30
68
95
52
Peak
0:
19:
20:
21:
22:
00
54
43
09
17
0.
RO
RO
RO
RO
65-0.89
1.
0.
0.
0.
3.
14
32
31
74
12
Peak
0:
18
18
19
19
19
19
20
21
21
21
21
21
22
22
:00
:09
:53
:08
:47
:55
:59
:33
:OS
:21
:33
:45
:50
:30
:42
0.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
22:46 RO
65-0.89
1
0
0
0
3
0
0
1
2
1
8
0
0
4
1
1
.00
.64
.69
.40
.33
.94
. 94
.36
.00
.04
.17
.73
.43
.86
.74
.67
0 Peaks
0.46
2.76
13.49
1.43
6.72
14.07
7.40
14.07
0.12
0.76
1.40
257.05
1.19
257.05
0.820-1.101
0.000
0.864
.879
.894
.912
7.55
7.95
926
0.948
109.18
Above: TCDF / TCDD Follows
0.12
0.53
1.00
1.29
0.42
0.35
0.30
0.99
1.13
0.44
0.
.11
,02
.24
0.50
.20
.13
0.951-1.049
0.000
0.941
0.980
147.87 1.000 13C12-2378-TCDF ISO
1.054
.853-1.059
0.000
0.831
0.864
0.876
0.905
0.912
0.915
0.941
0.965
0.977
0.986
0.995
0.999 2378-TCDD
1.030
1.039
1.042
AN
0.00
37C1-TCDD
328
DC NL 0:00
DC WL 18:06
DC WL 18:09
DC WL 18:28
0.06
1.64
0.50
1.24
0.906-1.094
0.000
0.828
0.831
0.845
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed; 14:08 08/1&97
111
-------
Page No.
09/18/97
Listing of S975834B.db£
Matched oc PeaXs / Ratio / Ret. Tin
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area..
Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
328
13C12-TCDD
332-334 DC
DC
DC
DC
DC
DC
DC
DC
DC
332-334
PeCDF
340-342 DC
DC
DC
DC
WL
WL
WL
WL
WL
WL
WL
WL
WL
WL
WL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
3
NL
WL
WL
WL
WL
SN
SN
SN
SN
3
NL
WL
WL
SN
18:35
18:42
18:46
18:59
19:03
19:14
19:20
19:23
19:26
19:38
19:45
19:59
20:10
20:24
20:31
20:42
20:59
21:09
21:15
21:20
21:27
21:38
21:52
22:13
22:23
22:30
22:37
Peaks
0
18
18
19
19
21
21
21
22
22
22
22
Pe
0
22
22
23
24
:00
:36
:58
:09
:42
:20
.37
:51
:08
:23
:33
:37
aks
:00
:26
:45
:12
:19
0.
RO
RO
RO
RO
RO
RO
RO
RO
RO
1.
RO
RO
RO
65-0.89
38.33
0
3
12
17
0
0
0
1
1
0
2
32
1
0
0
1
1
.31
.03
.56
.00
.68
.86
.87
.76
.99
.91
.95
-1.78
.17
.62
.90
.52
.66
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
5.
0.
0.
0.
0.
0.
0.
0.
0.
0.
180.
9.
0.
1.
0.
195.
0.
1.
1.
0.
0.
2.
268.
209.
6.
1.
1.
25
40
09
45
59
,50
,38
16
38
SO
22
77
65 5.65
32
15
70
35
55
53
26
94
55
26 180.26
74 9.74
95
38
22
65
.11
,06
,19
,57
30
89
06 124.01
.33 97.44
02 5.97
,24
,65
0.97
483.41
TCDD / PeCDF Follows
0.12
0,
1
20
7
.63
.02
.10 12.11
.23
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
1
1
1
1
1
0.906
0
0
0
0
0
0
144.05 0
111.89 1
3.40 1
1
1
1
0.907
0
0
0
7.99 0
0
.850
.856
.859
.869
.872
.880
.885
.887
.889
.899
.904
.915
.923
.934
.939
.947
.960
.968
.973
.976
.982
.990
.001 37C1-TCDD SUR1
.017
.024
.030
. 035
-1.094
.000
.851
.368
.376
.902
.976
.989 13C12-1234-TCDD RSI
.000 13C12-2378-TCDD IS1
.013
.024
.032
.035
-1.078
.000
. 882
.894
.912
.956
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 14:0809/18/97
172
-------
Page No.
09/13/9-7
Listing oC S975834B.db«
Hatched GC Peaks / Ratio / Ret. Time
Conpound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1. . Area.Peak.2. . Rel.RT Compound.Name. . ID.. Flag*.
340-342
13C12-PeCDF
352-354
N
N
N
352-354
PeCDD
356-358
356-358
13C12-PeCDD
368-370
N
N
368-370
HxCDF
374-376
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
SN :
SN ;
SN
SN
SN
SN
1
ML
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
2
NL
ML
SN
SN
SN
0
NL
SN
SN
SN
SN
SN
SN
NL
WL
24:29
24:39 RO
24:51 RO
25:05 RO
26:36 RO
26:54 RO
Peak
1.3
0:00 RO
22:37 RO
22:43 RO
23:24 RO
23:34
24:03 RO
24:08 RO
24:20 RO
25:08
25:26 RO
25:52
26:20 RO
26:30
26:38 RO
Peaks
1.
0:00 RO
24:04 RO
25:57 RO
26:12 RO
26:33 RO
Peaks
1 .
0:00 RO
24:19 RO
24:26 RO
24:49 RO
25:10 RO
25:31
25:48 RO
26:12
26:20
> Peaks
1
0:00 RO
27:48 RO
1.42
1.14
1.18
0.95
0.34
0.10
12-1.78
1.00
0.46
0.84
1.17
1.37
0.46
0.54
0.99
1.56
2.21
1.49
3.21
1.55
0.77
32-1.78
1.00
9.18
0.62
3.43
0.20
32-1.78
1.00
4.42
0.82
3.28
4.29
1.72
3.93
1.56
1.66
.05-1.43
0.99
1.77
2.18
1.65
3.08
1.04
0.95
0.56
20.10
0.13
0.87
0.89
1.37
0.83
0.41
0.41
2.16
153.70 93.72
1.35
137.24 82.16
O.'M
1.94
2.14
290.94
0.10
0.28
0.53
0.94
0.33
0.00
0.10
0.31
0.77
0.46
0.97
0.68
0.36
77.33 47.13
10.17 6.34
87.50
1.88
3.96
0.963
0.969
0.977
0.986
1.046
1.058
0.838-1.162
0.000
0.389
0.893
0.920
0.927
0.946
0.949
0.957
59.98 0.988 13C12-PeCDF 123 IS2
1.000
55.08 1.017 13C12-PeCDF 234 SUR2
1.035
1.042
1.047
0.921-1.026
0.000
0.914
0.985
0.995
1.008
0.845-1.155
0.000
0.923
0.928
0.942
0.956
0.969
0.980
30.20 0.995 13C12-PeCDD 123 IS3
3.83 1.000
0.955-1.052
0.000
0.952
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 14:06
-------
Page No. 4
09/18/97
Compound/
M_Z.... QC.Log Omit Why
Listing of S975834B.dbf
Matched GC Peaks / Ratio / Ret. Time
.-OT. OK Ratio Total.Area... Area.P«ak.l.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
374-376
13C12-HXCDF
384-386
N
N
N
N
384-386
HxCDD
390-392
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
0
NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
4
NL
WL
SN
SN
SN
SN
SN
27:
28:
28:
28:
28:
28:
28:
28:
29:
29:
29:
29:
29:
29:
29:
30:
30:
:56
14
;35
40
;43
:48
:52
:57
:01
:13
:20
:20
:30
36
42
:06
13
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
0
1
2
0
6
1
0
1
1
2
1
0
0
1
0
1
4
.67
.37
.90
.90
.08
.10
.74
.34
.02
.74
.19
.98
.14
.01
.93
.95
.89
Peaks
0:
27:
27:
27:
27:
27:
28:
28:
28;
00
28
34
46
49
54
04
07
:13
28t21
28:
28:
28:
29:
29:
29:
29:
29:
29:
30:
:36
42
;53
:12
:20
:25
:33
:38
.53
14
0.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
43
0
4
0
2
2
0
0
0
0
1
0
0
0
0
0
1
7
0
0
0
Peaks
0
28
28
28
28
28
29:
:00
:06
:29
:43
:48
•50
:01
1.
RO
RO
RO
RO
05
1
1
5
0
1
1
0
-0.59
.40
.06
.14
.70
.54
.15
.75
.34
.58
.94
.54
.51
.60
.52
.40
.06
.40
.66
.51
.76
-- Above:
-1.43
.41
.14
.10
.11
.07
.02
.53
0.
3.
0.
1.
0,
0,
0.
0.
1.
1.
1.
0.
0.
3.
0.
2.
0.
0.
1.
0.
0.
0.
0.
0.
1.
0.
1.
0,
100.
89.
1
96,
0.
0.
0.
1.
88.
1
374
65
08
47
.26
.54
,88
.63
,89
.99
95
,53
74
78
09
90
89
63
00
66
27
30
.41
.20
.53
09
,47
.15
,72
.38
,20
.34
.55
.92
.71
.23
.28
.59
.37
.72
HxCDF /
1
0
0
0
0
0
1
.47
.60
.22
.16
.85
.81
.19
0.957
0.967
0.979
0.982
0.983
0.986
0.989
0.991
0.994
1.001 123678-HXCDF
1.005
1.005
1.010
1.014
1.017 234678-HxCDF
1.031
1.035
AN
AN
0.859-1.141
0.000
0.941
0.944
.951
.953
.955
.961
.963
.966
35.23
30.12
33.07
29.97
HXCDD Follows
0.
0.
0.
0.
0.
o.
0.971
65.15 0.979 13C12-HXCDF 478 SOR3 Q
59.08 0.983 13C12-HxCDF 678 IS4 Q
0.989
63.48 1.000 13C12-HXCDF 234 ALT2 Q
1.005
1.007
1.012
•1.015
58.62 1.023 13C12-HXCDF 789 ALT1 Q
1.035
0.950-1.015
0.000
0.947
0.960
0.968
0.971
0.972
0.978
Triangle Laboratories, Inc.® Analytical Services Division
801 CapKola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 14:08 09/
-------
Page No.
09/18/97
Listing of S975834B.db£
Matched GC Peaks / Ratio / Rat. Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel. RT Compound.Name.. ID.. Flags.
390-392
13C12-HXCDD
402-404
402-404
HpCDF
408-410
408-410
13C12-HpCDF
418-420
N
N
N
418-420
HpCDD
424-426
424-426
13C12-HpCDD
436-438
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
SN 29:08 1.38
SN 29:14 RO 2.97
SN 29:24 RO 0.37
SN 29:29 RO 0.75
SN 29:34 RO 0.08
SN 29:44 RO 0.25
SN 29:50 RO . 0.77
SN 29:54 RO 0.14
0 Peaks
1.05-1.43
NL 0:00 RO 0.93
WL 27:50 RO 2.14
WL 27:58 RO 1.65
WL 28:19 RO 0.56
WL 28:21 1.35
WL 28:29 RO 0.33
SN 29:00 1.20
SN 29:00 RO 1.48
SN 29:09 RO 0.61
29:18 1.22
29:23 1.24
29:40 1.17
SN 29:50 RO 0.95
SN 29:55 RO 2.02
3 Peaks
0.88-1.20
NL 0:00 RO 1.71
0 Peaks
0.37-0.51
NL 0:00 RO 0.99
31:21 0.43
SN 31:34 RO 0.98
32:31 0.45
SN 32:41 0.49
SN 32:51 RO 0.23
2 Peaks
0.88-1.20
NL 0:00 RO 1.66
SN 31:26 RO 0.39
31:36 RO 0.86
1 Peak
0.88-1.20
NL 0:00 RO 9.63
1.14
0.67
0.56
1.32
0.27
0.31
0.96
0.23
0.00
1.14
0.47
1.46
0.83
1.29
0.34
0.44
0.65
1.45
69.92 38.42
79.95 44.32
113.35 61.18
1.63
1.01
263.22
Uvf T\r\ 1 Ur-vPm? Fril ~\ I-M^C
4.22
0.00
2.02
56.35 17.02
1.50
47.69 14.86
2.00
2.65
104.04
1.63
0.57
5.10 2.60
5.10
0.16
0.982
0.985
0.991
0.994
0.997 123478-HxCDD
1.002 123678-HxCDD
1.006
1.008
0.966-1.034
0.000
0.938
0.943
0.954
0.956
0.960
0.978
0.978
0.983
31.50 0.988 13C12-HXCDD 478
35.63 0.990 13C12-HXCDD 678
52.17 1.000 13C12-HXCDD 789
1.006
1 .008
0.995-1.044
0.000
0.936-1.128
0.000
39.33 0.993 13C12-HpCDF 678
1.000
32.83 1.030 13C12-HpCDF 789
1.035
1.041
0.976-1.006
0.000
0.977
3.01 0.982
0.969-1.031
0.000
W
AN
SUR4 Q
IS5 Q
RS2 Q
IS6 Q
SDR5 Q
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 14:08
175
-------
Page No.
09/18/97
Listing of S97S834B.db£
Hatched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
436*438
DC SN 31:35 1.10
DC SN 31:40 RO 0.42
DC SN 31:59 RO 2.49
32:10 1.04
1 Peak
1.70
0.35
0.88
55.10
55.10
28.13
0.982
0.984
0.994
26.97 1.000 13C12-HpCDD 678 IS7
OCDF
442-444
442-444
. ^uj,
0.76-1.02
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
0
0:
30:
31;
31:
32:
32:
32:
32:
33:
33
33
34
35
35
00
56
30
40
04
:16
:30
:52
:10
:35
:56
:16
:29
:59
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
1.
0.
1.
2.
0,
0,
0
0
2
2
0
0
0
0
00
,47
.11
.86
.13
.85
.80
.08
.32
.96
.52
.86
.45
.58
Peaks
Above: HpCDD / Octa-CDD and CDF Follows
0.12
0.70
0.34
0.42
0.32
1.33
1.76
0.38
1.89
0.43
1.91
1.06
1.68
1.70
0.00
.884-1.116
0.000
0.890
0.906
0.911
0.923
.929
.935
.946
. 954
0.966
0.976
0. 986
1.021
1.035
OCDD 0.76-1.02
458-460 DC NL 0:00 RO 1.17 0.11
34:43 0.93 38.40
453-460 1 Peak 88.40
13C12-OCDD 0.76-1.02
470-472 DC NL 0:00 RO 0.09 0.11
DC WL 34:33 RO 2.02 0.93
34:45 0.79 65.71
470-472 1 Peak 65.71
42.55
28.91
0.384-1.116
0.000
45.85 0.999 OCDD AN
0.995-1.005
0.000
0.994
36.80 1.000 13C12-OCDD 138 Q
Column Description "Why" Code Description QC Log Desc.
M_Z -Nominal Ion Mass(es)
..RT. -Retention Time (mm:ss)
Rat.l -Ratio of M/M+2 Ions
OK -RO=Ratio Outside Limits
Rel.RT-Relative Retention Time
End of Report ***
WL-Below Retention Time Window
WH-Above Retention Time Window
SN-Below Signal to Noise Level
-------
Tilei3975834 tl-848 Acqtll-SEP-1997 12:58:11 XI+ Voltage SIX 70S Hoifmi35
319.8965 ri2 BSOB(256,30, -3.0) PKD(7, 5,3, 0.05\, 140.0,1.00\,r,T) IxptXPCUS
TRIANGLE LABS TextsI-M23-1 TLI#43085 IKT. TIMX - 13:00
1001
.8.0X3
^*"^B&_«^n.^_f^_^&dk_«^i^_U^^_^B^.^^|^UM<^^_^M«L^^«*A^MBK«fli^^^^H^^^i^^Hp_A^4_«&d_
19:00 20:00 21:00 22:00
rlle:S975834 tl-848 Acqtll-SEP-1997 12:58:11 EI+ Voltage SIX 70S Hoime:35
321.8936 rt2 BSUB(256,30,-3.0) PXD(7,5,3, 0. 05\,140.0,1.00\,T,T) XxptXPCDS
TRIANGLE LABS T*xt:I-M23-l TLIf43085 IKT. TIME - 13:00
IOU\ A1.44X4
80:
60:
40:
A7.97X3
AS.62X3
19:00 20:00 21:00 22:00
rile:S975834 tl-848 Acqsll-SEP-1997 12:58:11 EI+ Voltage SIX 70S NoiaesllSO
331.9368 T:2 BSOB(256,30, -3. 0) PXD(7,5,3, 0. 05\,4600.0,1. 00\,F,T) Exp:EPCUS
TRIANGLE LABS Text:I-M23-l TLIt430S5 IKT. TIME - 13:00
1001 A1.24X6
80:
60:
40:
A9.74E5
19100 20:00 21:00 22:00
FileiS975834 tl-848 Acq:ll-SEP-1997 12:58:11 EH- Voltage SIR 70S Noiae:30
333.9338 Tt2 BSUB(256,30, -3. 0) PXD(7,5,3, 0. 05\,120. 0,1. 00\,T, T) Xxp:XPCVS
TRIANGLE LABS ToXt:I-M23-l TLIt43085 IKT. TIME - 13:00
1001
40:
20:
0.
A1.44E6
A1.12E6
19:00 20:00 21:00 22:00
rile:S975834 tl-848 Acqsll-SEP-1997 12:58:11 EI+ Voltage SIR 70S NOi*e:29
327.8847 T:2 BSUB(256,30,-3.0) PKD(7,5,3, 0. 05\,116.0,1. 00\,T, T) ExpsEPCUS
TRIANGLE LABS Text:I-M23-l TLI*4308S IKT. TIME - 13:00
1001 A1.80E6
80:
60:
40:
20:
o< _ .-..-.-.,.. -— - --- - -
A9.74E4
19:00 20:00 21:00 22:00
rile:S975834 tl-848 Acqtll-SEP-1997 12:58:11 EI+ Voltage SIR 70S
330.9792 T:2 Exp:EPCOS
TRIANGLE LABS Text:I-M23-l TLH43085 IKT. TIME - 1J.-00
1001
19:18 _20:06
80J
2.4X5
1. 9E5
.1. 4E5
.9.6X4
.4.8X4
0.0X0
Tim
2.9E5
2.3E5
1. 7E5
1.1E5
5.7X4
0.0X0
Tim
.3.2X5
.2.6X5
ll.9E5
.1.3X5
.6.5E4
0.0X0
rim
19tOO
2000
21:00
22 00
-------
rile, 3975834 tl-848 Aoqtll-SXP-1997 12:58:11 XI+ Voltage SIX 70S Hoite:36
339.8597 ti2 BSUX(256, 30, -3 .0 ) PXD( 7,5,3,0. 05%,144. 0,1. 00\,r,T) X*p:XPCU8
TRIANGLE LABS Text:I-M23-l 311*43085
1001
so:
60:
40:
20:
0
A1.21E5
\
n
J 1 A4.51E4
I \ tal. 28*4
hVAJi. »jw trv w A. .. . -.. A.. K Ajn LJY.A
23io0 24i00
IHJ. TIMX - 1J.00
A6.28E3
*j'\nf}A JLA rV\jylAArJA/r
25.00
A3. 4 424
j^Ai .11 Ju ,
WwInAy'y\N\AA/''lJ\lA /
.3.0X4
.2.4X4
.1 . 8X4
.1.2X4
.6.0X3
0.0X0
26.00 Ti*e
rile i S5 75834 tl-848 Acq:ll-SEP-1997 12,58,11 XI+ Voltage SIX 70S Noime:30
341.8567 T:2 BSUB(256,30, -3 .0) PKD(7,S,3,0.05\,120.0,1.00\,T,T) Exp:EPCUS
TRIANGLX LABS Text:I-M23-l TLH43085
1001
80:
60.
40.
20.
A7.99E4
1
A1.52E4 II A2.72E4
[ A2.43X3J\ A6 25X3 J\A9-05S3
\^.fj \A_ftj_f-v**JLsjLj%«* v^*-»A* A/W\^I A A rA f^ \AA-A/vA^.
23:00 24 : 00
IHJ. TIMX - 13.00
Al . 58X4 Al . 11E4
i ii BO at
n!\ A A A A A ft lull A
A vVWv A AJ\ jjpvyWUWuvV
25\00
A3. 37X4 il
lAA^Av^ ^V\l \A jA^/w \ .
.2.8X4
.2.2X4
.1 . 7X4
.1.1X4
.5.5X3
0.0X0
26:00 Tiae
rile:S975834 tl-848 Acq:ll-SEP-1997 12:58:11 EI+ Voltage SIR 70S «oiae:41
351.9000 T:2 BSUB(256,30r-3 .0) PKD(7,5,3, 0.05%,164. 0,1. 00\,T,T) Exp:XPCUS
TRIANGLE LABS Text:I-M23-l TLH43085
1001
80:
eo:
40:
20:
o:
'23:00 24.-00 '
INJ. TIME - 13:00
A9.37ES
A8.
. . J 1 . . ., '
25:00
2.8E5
2£5
1
L^ T T— T -^ [^
.2.2ES
Ll . 7JE5
Ll . 125
L5.6E4
• o . oro
26:00 Tine
JTile:S575834 #1-848 Acq:ll-SEP-1997 12:58:11 EI+ Voltage SIX 70S «oiae:42
353.8970 T:2 BSUB(256, 30, -3 . 0) PKS(7, 5,3, 0. 05\,168.
TRIANGLE LABS Text: I-M23-1 TLIt43085
1001,
80'.
60.
40.
20.
0
Al . 50E4
' 23:00 24:00 '
0,1.00\,T,T) Exp:EPCOS
I1KT. TIME - 13:00
A6.00E5
_1 . 7£5
A A5 . 51£5
ft
J \ \
_*_/ V . . . - - r ^
' 25:00
Al . 68X4
\^. _f ^ ^ .>....
.1.4X5
.1 . 0X5
.6.8E4
.3.4E4
O.OEO
26:00 Time
rile:S975834 tl-848 Acq:ll-SEP-1997 12:58:11 EH- Voltage SIR 70S
330.9792 T:2 Xxp:EPCUS
TRIANGLE LABS TextsI-M23-l TLH43085
1003,
80.
60.
40.
20.
0
24:
_, ./v
/^ 33- 41 11.01 23:21 23:47 24:08 s^
/^\ * ^ ? * JL +j * uj ^t .. /V^y\A r
'23:00 24.-00 '
XK7. TIME - 13:00
26.40 ,2.2X6
"3&* 3 a A.
f «i/5 f^'4125;57, rv^Al'/^^^
X/^vA\j/v~vV X V^v"
\*vr v V V* v^
' 25:00 '
^vvv \/
v \J
.1 . 8E6
:l . 3X6
-8.8E5
-4.4E5
'• o . oxo
26:00 ' ' ' Time
rile:S975B34 tl-848 Acqtll-SEP-1997 12.58:11 XI+ Voltage SIR 70S
409.7974 T:2 Exp:EPCUS
TRIANGLE LABS Text : I-H23-1 TLIt43085
100
80
60
40
20
0
1 24
\ 1
: | 22,53 23-153{39 34'01 34'3°
'•\,j\N(ti}( AX /AAJWA ~AA/ ^lA^^AAjsA AA-A^
23.00 24.00
TWT. TJMT » 13.00
37
25.33
JlL^M_JV\JwlMAJW _
-------
riletS975834 tl-84f Acqtll-SXf-1997 J.i:i8:ll fir Voltay* SIX 70S MOJ.**lJa
355.8546 ft2 BSOB(256, 30,-3.0) PXD(7,5,3,0.05\,112.0,1.00\,T,T) fzptXPCOS
TRIANGLE LABS T*xt:I-N23-l TLH430S5 1X7. TIN* - 13iOO
100* Al.48X4
9.3X3
241 00 25'tOO 36100
file»S975834 #1-840 Acqtll-SEP-1997 12t58:ll 11+ Voltay* SIX 70S J*>i«««3i
357.8516 Ts3 BSUB(256,30, -3.0) PKD(7,5,3, 0.05%, 124. 0,1.00\,F,T) XrptXPCOS
TRIANGLE LABS T*xttI-M23-l TLI143085 HKT. TIME * 13tOO
100*
24': 00 25:00 26:00
r±le:S975834 H-B48 Acqill-SEP-1997 12i58tll EI+ Voltage SIS 70S Hoime:29
367.8949 Tt2 BSOB(256,30,-3.0) PKD(7,5,3,0.05\,116.0,1.00\rf,T) XxpsXPCOS
TRIANGLE LABS TeittI-M23-l TLIH30B5 INJ. TIME - 13:00
100\ A4.71E5
80J
50.
40.
20:
6.34E4
0.0X0
T±mi
1. 6E5
.1.3E5
.9. 5E4
.6.4S4
.3.2X4
24i00 25:00 26>00
riletS975834 #1-848 Acq:ll-SEP-1997 12>58tll XI+ Voltage SIS 70S KoiaetSl
369.8919 T:2 BSUB(256,30,-3.0) PXD(7,5,3,0.05\,124.0,1.00\,F,T) ExpsXPCVS
TRIANGLE LABS Tort:I-M23-1 TLH4308S IXJ. TIKE - 13»00
100* A3.02E5
BO:
eo:
40.
20:
.0.0X0
Tim>
.83E4
9.2X4
.7.3X4
.5.5X4
'.3. 7X4
'.1. 8X4
• i " - 'i" i ••• I " i" i •' ' "i- " "i* -^ - -i ' ' - -i i |
34:00 25:00 36:00
rile.-5975834 #1-848 Acq,ll-SEP-19S7 13t58:ll EI+ Voltage SIS 70S
330.9793 F:2 XxpsXPCOS
TRIANGLE LABS TeztsX-«23-l TLI#43085 JWJ. TIME - 13:00
1001
.o.oro
Time
26:40
34:00
25:00
26:00
-------
ile.S975834 tl-406 Aoqill-SXP-1997 12:58:11 XI+ Voltag* SI* 70S Half•:521
73.8208 T>3 BSUt(256,30,-3.0) PKD(7, 5,3,0.05\,2084.0,1,00\,r,T) XxpiXTCUS
TRIANGLE LABS T*xt:I-M23-l 1X1*43085 INJ. TIMX - 13:00
A3.14E4 *a-}"4
27.24 27:36 27:48 28:00 28«12 28*24 28.36 28:48 25:00 29:12 29:24 29:36 29:48 JO.00 J0:12
110:5975834 tl-406 Acq:ll-SEP-1997 12(58:11 EI+ Voltage SIX 70S No±m»:524
75.8178 Fi3 BSUB(256,30,-3.0) PKD(7,5,3,0.05\,2096.0,1,00\,T,T) ExptEPCOS
TRIANGLE LABS T*ztiI-M33-l TLH43085 IW7. TIME - 13:00
001
A1.52E4
Al.64X4
A2.51X4
Time
27:12 27:24 27:36 27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12
Tile:S975834 tl-406 Acqsll-SEP-1997 12:58:11 EI+ Voltage SIR 70S Haifa: 280
'83.8639 r-.3 BSUB(256,30,-3 .0) PXD(7 ,5,3,0 .05\,1120 .0,1. 00\,r,T) ExptEPCUS
TRIANGLE LABS Text:X-M2J-l TLH43085 IKT. TIME- 13:00
Timi
1003
80:
so:
40:
A3.52E5
A3 . 31E5
A3.00E5
_1 . 415
Ll.115
.8.3E4
.5 . 6E4
.2.8E4
A9.27E3
tf"
O.OEO
27:12 27:24 27:36 27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12
rile:S975834 #1-406 Acq:ll-SEP-1997 12:58:11 EI+ Voltage SIS 70S No±ae:697
385.8610 F:3 BSUB(256,30,-3.0) PKD(7, 5,3, 0.051,2788. 0,1. 00\,r,T) Exp:EPCUS
TRIANGLE LABS Text:I-M23-1 TLIf430S5 INJ'. TIME - 13:00
1001
80:
60:
40:
20:
o:
A6.S1E5
A6.3SE5
AS.B6E5
27:12 27:24 27:36 27:48 28:00 28.12 28:24
rile:S975834 #1-406 Acg:ll-S£P-1997 12:58:11
392.9760 F:3 Elp:EPCUS
TRIANGLE LABS Tart:J-M23-l TLIt43085
28:36 28:48 29:00 29:12 29:24 29:36 29:48
EH- Voltage SIS 70S
Time
.3E5
.9E5
.4E5
.3E4
.7E4
.OEO
Tia,
27:12 27':24' 27': 36 27:48' 28 i 00 ' 28:12* 281-24
file:S975834 #1-406 Acq:ll-SEP-1997 12:58:11
445.7555 T:3 ExptEPCUS
TRIANGLE LABS Text:I-M23-l TLIt43085
1001
I i ' i i i i i i i i i i i i i i i i i i i i i i i i i i i i i
28:36 26-48 29:00 29:12 29:24 29:36 29:48
EI+ Voltage SIX 70S
INJ. TIME - 13:00
I i i i i i I
30:00 30:12
.OEO
Tia
27:12 27:24
27:48 28:00
_->UAWWVl/UUAA*uUl
i i i i i » i ri1 r'r"i"| 'r11!11 T'T'T^TT'I i i'i i i
28i24 28:36 28:48 29:00 29:12 29:24
29«48 30:bb'30:12
0£0
Tim
180
-------
\Til.,S975B34 il-401 Aogi 11-09-1997 12,58,11 KH- Voltage Sl» 70S
389.8156 Ti3 BSUB(256,30, -3.0) PKD(7,5,3,0.05\, 1716.0,1.00\,T,T) XxptXPCaS
TXIA1KLX LABS TeJct:I-M23-l TLH43085 IXT. TIMX - 13iOO
100* A1.J.OX4
8.3X3
27\48 ' '28\00 ' '28\12 ' '28\24 ' ' 26\36 ' ' 28\48 ' 29\00 29:12 29i24 29',36\ 29:48
r±le,S975834 tl-406 Acqtll-SXP-1997 12i58ill XI+ Voltage SIS 70S Koif9,306
391.8127 r,3 BSUB(256,30r-3.0) PXD(7,5,3,0.05\,1224.0,1.00\,r,T) XxptXPCOS
TSIASGLX LABS Text:I-M23-l TLIf43085 I1W. TIMX - 13:00
1001
27,48 28,00 28,12 28i24 28,36 28:48 29:00 29,12 29:24 29,36 29:48
rile:S975834 tl-406 Acqsll-SEP-1997 12,58,11 EI+ Voltage SIS 70S «oite,316
401.8SS8 T,3 BSUB(256,30,-3.0) PKD(7,5,3,0.05\,1264.0,1.00\,T,T) XxptSPCVS
TXIANGLE LABS Taxt,I-M23-l TLH43085 XWJ- TIME - JJ.-OO
100J
so:
60.
40.
201
A6.12E5
A4.43E5
A1.21E4
'
2.1X5
.1. 7X5
.1. 3X5
.8.5E4
.4.3E4
"i i t i i1 lO |" i1 f i-il i1 , , ,
27,48 28,00 28,12 28:24 28:36 28:48 29:00
Tile,S975834 tl-406 Aoqill-SXP-1997 12:58:11 XI+ Voltage SIS 70S Soiae,342
403.8529 r,3 BSUB(256,30f-3 .0) PKD(7,5,3, 0. 05\, 1368. 0,1. 00\,r,T) Xip:EPCUS
TRIANGLE LABS Text:I-M23-1 TL.H430BS IKJ. TIMX - 13:00
100* AS. 22X5
29i48
.0.0X0
Time
ao:
60.
40.
20.
A3.15X5
T"r
27:48
T
A
J
1. 8X5
.1.4X5
.1.1X5
.7.1X4
.3. 6X4
28:00 28:12 28:24 28:36 28:48 29,00 29tl2 29,24 29:36
Tile,S975834 tl-406 Acqill-SEP-1997 12:58:11 EH- Voltage SIS 70S
392.9760 T,3 Xxp:EPCUS
TRIANGLE LABS Text:I-M23-l TLIt43085 J*J- TIMX - 13:00
29,48
.0.020
Time
1001
so:
60.
40.
20.
27:52
28:21
28:34
28,52"'°°
29:26
29:33
_.! . 8X6
.1.4X6
.1.1X6
'.7.2X5
.3.6X5
" t 1 1 1 1 1
27,48
'28160 ' ~28i
12 28\24
28:36
26,48
29 1 00 29 1
12 29:24 29
i 36 29\48
.0.0X0
fH
18
-------
ile:S975834 tl-430 Aoqill-SXP-1997 13i58tll II* Voltage SIM 70S Nolle:1774
07.7818 Ti4 BSUB(256,30,-3.0) PXD(7,5,3,0.05\,7096.0,1.00\,r,T) XxpiXPCOS
TXIANCLS LABS Text:I-M23-l TLH43085 IKT. TIM* - 13iOO
001
31:36 31i48 33.00 32s 12 32i24
ile:S975834 #1-430 Acqill-SEP-1997 12:58:11 EH- Voltage SIX 70S Koi»e:1037
09.7789 T:4 BSUS(256,30,-3.0) PKD(7,5,3, 0.05*, 4148.0,1.00\,F,T) XxptEPCUS
TRIANGLE LABS Text:I-H23-1 TLH43085 INJT. TIME - 13:00
100*
80J ' A2.06E4
sol
40:
20:.
0:
32136
32:48
31:12 31:24 31:36 31:48 32:00 32:12 32:24
Tile:S975834 tl-430 Acg_:ll-SEP-1997 12:58:11 EH- Voltage SIS 70S Noime:690
17.8253 F:4 BSUB(256, 30, -3. 0) PKD(7,5,3,0.05\,2760.0,1.00\,F,T) XxptXPCOS
TRIANGLE LABS Text:I-M23-l TLH43085 I1KT. TIME - 13tOO
1001 A1.70E5
32:36
32:48
40
20:
0:
A1.49E5
Al.02E4
Al.19X4
A^-^^V J^^^^\.^N-i
9.6X3
7.7X3
.5.8X3
3. 8X3
,1.9X3
,0.0X0
Time
.4.7X4
.3. 8X4
.2.8X4
.1.9X4
.9. 5X3
31il2 31:24 31:36 31:48 32:00 32:12 32:24
F±le:S975834 il-430 Acq:ll-SEP-1997 12:58:11 EH- Voltage SIX 70S Jtoi«e:701
419.8220 T:4 BSUB(256, 30, -3. 0) PXD( 7,5,3, 0. 05\,2804. 0,1. 00\,T, T) XxpsXPCUS
TRIANGLE LABS Text; I-M23-1 TLH43085 JK7. TIME - IJtOO
32:36
32:48
1003
60:
40:
20:
0:
A3.93E5
A3.28X5
A1.34E4
^-^|__-^v_".jfc^ ^*r~*.^
31:12 31:24 31:36 31:48 32tOO 32:12
rile:S975834 fl-430 Acqtll-SXP-1997 12:58:11 EI+ Voltage SIX 70S
430.9729 Ts4 ExpsEPCUS
TRIANGLE LABS TexttI-M23-l TLIt43085 HTJT. TIME
32:24
32136
32:48
O.OEO
Tim.
1.0X5
8.4X4
6.3X4
4.2X4
2.1X4
0.0X0
Time
13:00
1003
80:
60:
40:
20:
o:
31:15
31:58 32:05
32:3732:43
-r
-r
T
32:24
31:12 31:24 31:36 31:48 32:00 32:12
File:S975834 fl-430 Acq:ll-SEP-1997 12:58:11 EI+ Voltage SIX 70S
479.7165 T:4 EiptEPCUS
TXIANGLE LABS Text:I-M23-l TLIH43085 IHJ. TIME - 13s00
31; 57
32:36
32\4B
1. 8X6
.1.5X6
.1.1X6
'-7.4X5
.3. 7X5
0.0X0
Tim
31.1.2
31124
31136
31:48
32:00
32 > 12
32:48
0.0X0
Tim
182
-------
17:00 18:00 19:00 20»00 21:00
ile:S975834 91-848 Acqsll-SXP-1997 12>5Bill EI+ Voltage SIX 70S Jfciae.347
05.8987 Ts2 BSUB(256,30,-3.0) PKD(9, 5,5,0.05\, 1388.0,1.QO\,T,T) ExptEPCUS
TRIANGLE LABS Text:I-M23-1 TLH43085 IKT. TIME - 13:00
17:00 18:00 19:00 20:00 51:00
Tile:S975B34 #1-848 Acq:ll-SEP-1997 12:58:11 Eli- Voltage SIS 70S Noif»:39
15.9419 T:2 BSUB(256,30, -3. 0) PKD(9,5,5, 0. 05\,156. 0,1.00\,T, T) ExptEPCUS
TRIANGLE LABS Tert:I-M23-1 TLH43085 INJ. TIHX - 13:00
004 Al. 09E6
sol
so:
40:
20.
ilei5975834 #1-848 Acqtll-SXP-1997 12:58:11 XI+ Voltage SIX 70S Koime:99
03.9016 f:2 JSSU*(256,3Q,-3.0) PKD(9 , 5 ,5,0 .05\,396 .0 ,1.00\,T,T) XxpiXTCUS
lANSLf LABS Text:I-M23-1 TLH43085 IJKT. TIHX - 13:00
001 s^y A7.55X4
«*•
32100
221 00
ore
Time
2.1X5
,1. 6E5
1.2X5
.8.2S4
.4.1X4
17:00 18:00 19:00 20:00 21:00
•ile:S975834 #1-848 Acq:ll-SEP-1997 12:58:11 EI+ Voltage SIX 70S Noiae:34
17.9389 T:2 BSOB(256,30,-3.0) PKD(9,5,5r0.05\,136.0,1.00\,reT) Exp:£PCUS
TRIANGLE LABS TextsI-M23-1 TLH43085 I1W. TIHX - 13:00
22:00
O.OEO
Tine
100J
80:
50J
40:
20:
0.
A1.4BE6
17:00 18:00 19:00 20:00 21:00
file:S975834 #1-848 Acg:ll-SEJ>-1997 12:58:11 EH- Voltage SIS 70S
330.9792 T:2 ExpsEPCUS
TRIANGLE LABS T*xtsI-H23-l TLH43085 INJ. TIHE - 13:00
17:11
80:
50:
40:
20J
0.
22:00
P--1-
_1.
Li.
.6,
.3
17:00 18:00 19:00 20:00 21:00
Tile:S97S834 #1-848 Acgr:ll-Si;j'-1997 12:58:11 EH- Voltage SIS 70S
375.8364 T:2 Exp:XPCUS
TSIANGLE LABS TejctsI-H23-l 311 #43085 OU. TIHX - 13:00
17:53
22:00
80:
60l
40:
20:
17:10
17.35I
18:28
""
-••" »« •
2E5
.6X5
,1X5
.4X4
.0X0
Tim
.7E6
4E6
OE6
8X5
4X5
J.OEO
Time
1.1E4
3.5X3
S.4X3
t.3X3
17100
18:00
19:00
20:00
31100
22100
i.oro
TlMJ
is:
-------
\H1»:S975B34 U-430 Xoq:ll-SSP-lS97 12,5V< 11 XH- Voltage 311 70S Hbi«««6*7
423.7766 r:4 3SVS(256,30,-3.0) PKD(7,5,3,0.05\,2668.0,1.00\,r,T) XxpiXPCOS
TXIJUKLX LASS Tmxt:I-M23-l TLH43085 IHJ. TIMS - 13iOO
10(A A3.56X4
80.
60.
40.
20.
A2.05X3
T
T
-r
T
'32\06 ' '32', 12 ' '32', 18
3lil« 31', 24 31', 30 31', 36 31:42 31:48 31,54 32,00
Tlle:S975834 tl-430 Acqill-SEP-1997 12,58,11 XI+ VoltMgm SIX 70S Koimti401
425.7737 Ti4 BSOB(256,30,-3.0) PXD(7,5,3,0.05\,1604.0,1.00\,T,T) XxpiXPCOS
TRIASGLX LABS T*xtil-l423-l TLH430B5 IJKT. TIKE - 13100
IOCS A4.P7E4
80.
'32',24 ' 32', 30
.9.2X3
.7.3X3
'.5.5X3
.3.7X3
.1. 8X3
0.0X0
31:18 31:24 31:30 31:36 31:42 31:48 31:54 32:00 ' 32:05 32:12 32:18
T±le:S975834 tl-430 Ac
-------
file:5975834 tl-430 Aoqill-SEP-1997 12:58:11 EI+ Voltag* SIM 70S tfoif«t3l
441.7428 T>4 BSU*(25f,30,-3.0) PtX>(7, 5,3,0,05\, 124.0,1.00\efrT) XxptXTCOS
TRIANGLE LASS T*xttI-K23-l ZU 443065 XK7. TJMT - 13iOO
1003
31': 00 32,00 33iOO 34tOO
rile:S975834 tl-430 Acqtll-SEP-1997 12s58-.11 EI+ Voltage SIX 70S J*oi*e:28
443.7399 T:4 3SUS(256,30,-3.Q) PKD(7,5,3, 0. 05%, 112. 0,1. 00\,r,T) XxptXPCOS
35:00
Tim*
TXIANGLE LABS
1003.
Tezt:X-M2J-l TLH43085
XKT. TIKX - 13:00
31': 00 32:00 33': 00 34:00 35:00
rile>S975634 tl-430 Ac'a* "!4B
33:20
XWJ. TIME - 13:00
34:14 34(3B
34:02 ,
35:12
35:48 r
31:00 32:00 33:00 34:00 35:00
file.-5975834 41-430 Acq:ll-SEP-1997 12:58:11 EI+ Voltage SIS 70S
513.6775 Tt4 Exp:EPCUS
TRIANGLE LASS Tart.-I-W23-1 TLI#43085 INJ. TIME - 13:00
1.9E6
1.6E6
1.4X6
1.2E6
1. OE6
.8.2E5
6.2X5
.4.1X5
2.1E5
iO.OEO
Tim
31 i 00
32:00
33iOO
34:00
35:00
18
-------
\ril»:S975834 tl-430 Aoq:ll-SXP-1997 12>58ill XH- Voltage SIS 70S J*oi»e«J«
\457.7377 Ti4 BSUB(256, 30,-3.0) PKD(7, 5,3,0.05\, 136.0,1.00\,F,T) XxptXPCOS
TRIANGLE LABS TvctiI-H23-l 1X1*0085 1X7. TIHX • 13tOO
100\ A4.26X5
so:
SO.
40.
20.
-5.9X4
.4.7X4
.3.5X4
.2.3X4
.1.2X4
34,24 34,30 34:36 34,42 34,48 34,54
rile:S975834 tl-430 Acqtll-SXP-1997 12,58,11 XI+ Voltage SIX 70S Ho±ee:31
459.7348 T:4 BSUB(256,30,-3.0) PXB(7,5,3, 0.05%, 124.0,1. 00\,r, T) Xzp:XPCVS
TXIAKGLX LABS Text.J-M23-1 TLH4308S IXT. TIHX - 13,00
35100
.0. 0X0
Time
1003
80.
60.
40:
20.
A4.59X5
i i i "i i '
34,30
-5.6X4
.4.5X4
.3.4X4
.2.3X4
.1.1X4
i r i i T i i i i i i i i i ..... ii
34,24 34,30 34,36 34,42 34,48 34,54
rile,S975834 tl-430 Acqill-SEP-1997 12,58:11 XI+ Voltage SIX 70S Noiae:26
469.7779 T,4 BSOB(256, 30, -3. 0) PKD( 7,5,3, 0.05\,104. 0,1. 00\,F, T) XxpiXPCUS
TRIANGLE LABS Texts I-M23-1 TLH43085 INJ. TIHX - 13:00
1001 A2.89E5
.0.0X0
Time
34:24 34:30 34:36 34:42 34,48 34:54
T±le,S975834 tl-430 Acq:ll-SEP-1997 12:58:11 EH- Voltage SIB 70S Noiae:286
471.7750 r,4 BSUB(256,30,-3.0) PKD(7,5,3, 0. 05\,1144 . 0,1. 00%,T,T) Exp:EPCOS
TRIANGLE LABS Text:I-H23-l TLH430BS JKT. TIMX- 13:00
1004 A3.68E5
so:
eo:
40:
20:
35:00
A7.63E3
5.0X4
.4. 0X4
.3. 0X4
.2.0X4
.1. 0X4
rile
430.
TXIA
1003
«0_
60.
40_
20.
0
^ { \/ 1 V / ^ ^N — S — ^ /
34\24 '34\3Q ' ' ' 34\ 36 ' ' ' ~34\42 ' ' ' 34\48 ' ' ' '34^54 ' ' ' 3s':00
,3975834 tl-430 Acq,ll-SEP-1997 12:58:11 EI+ Voltage SIX 70S
9729 T:4 ExpsXPCUS
HGLE LABS Text: I-M23-1 TLH43085 IKJ. TIHX - 1J.-00
34:38
34,28 ^ \X^^ J2^1~^ ^/-\
^^ ~^^^ N/ ^^ " *~^~*^S~
34\24 '34\30 ~34\36 ~34\42 '34\4B ~34\54 35tOO
o.oxo
Time
.2.1X6
^1 . 6X6
'.1.2X6
.8.2X5
.4.1X5
0.0X0
Time
186
-------
-------
•-ile:S975834 #1-430 Acq:ll-SEP-1997 12:58:11 EI+ Voltage SIR 70S
117.8253 F:4 Exp:EPCUS
Sample Text:I-M23-l TLI#43085
100%
INJ. TIME = 13:00 File Text: I-M23-1 TLI#»
_3.3E4
31 00 32100 33:00
?ile:S975834 #1-430 Acq:ll-SEP-1997 12:58:11 EI+ Voltage SIR 70S
119.8220 F:4 Exp:EPCUS
Sample Text:I-M23-l TLI#43085 INJ. TIME =
100% A 32;32
34
13:00 File Text:I-M23-1 TLI#»
31 00
32:00
1 1-
33:00
: 00 Time
OP
ob
-------
File:S975834 #1-430 Acq:ll-SEP-1997 12:5ft:ll EI+ Voltage SIR 70S
423.7766 F:4 Exp:EPCUS
Sample Text:I-M23-l TLI#43085 INJ. TIME =
31 36
13:00 File Text:I-M23-l TLI#
u9.2E3
33:25
32:57 I
31:00 32JOO
File:S975834 #1-430 Acq:ll-SEP-1997 12:58:11 EI+ Voltage SIR 70S
425.7737 F:4 Exp:EPCUS
Sample Text:I-M23-l TLI#43085 INJ. TIME =
100%
33:00
O.OEO
Time
13:00 File Text:I-M23-l TLI#»
33 21 1.1E4
L9.1E3
31:00 32100
File:S975834 #1-430 Acq:ll-SEP-1997 12:58:11 EI+ Voltage SIR 70S
135.8169 F:4 Exp:EPCUS
Sample Text:I-M23-l TLI#43085 INJ. TIME =
100%. 32:10
33:00
:O.OEO
Time
13:00 File Text:I-M23-l TLI#»
31:00
32:00
33:00
.O.OEO
Time
C5
00
-------
File:S9Vb834 #1-430 Acq: ll-SEP
423.7766 F:4 Exp: EPCUS
Sample Text:I-M23-l TLI#43085
100%.
-1997 12:b8;ll EI+ Voltage SIR 70S
INJ • TIME = 13 :
File Text:I-M23-l TLI#»
9.2E3
0
File:S975834 #1-430 Acq:ll-SEP
425.7737 F:4 Exp:EPCUS
Sample Text:I-M23-l TLI#43085
100%
80 J
32lOO
-1997 12:58:11 EI+ Voltage SIR 70S
INJ. TIME =
33:00
,,„«,,••• m *. T
13:00 File Text:I-
Time
!-l TLI#»
0
31:00
File:S975834 #1-430 Acq:ll-SEP
435.8169 F:4 Exp:EPCUS
Sample Text:I-M23-l TLI#43085
100%
80j
60 J
40 j
20 j
0
32:00
-1997 12:58:11 EI+ Voltage SIR 70S
33:00
Time
INJ. TIME =
32:10
31:29
31:03
A
31:00
31:59
32:27 32:5133:03
^_^_A ^—~_—^>*—^_/v-^-^\A-s:
13:00 File Text:I-M23-l TLI#»
7.1E4
L5.7E4
L4.2E4
L2.8E4
L1.4E4
33:21 33:34,
lO.OEO
32IOO
33 :00
Time
O
C5
-------
^ile:S975834 #1-430 Acq:ll-SEP-199712758~TTr^EI+ Voltage SIR 70S
157.7377 F:4 Exp:EPCUS
Sample Text:I-M23~l TLI#43085, INJ. TIME = 13:00 File Text:I-M23-l TLI#»
LOO* 34;43 5.9E4
50,
OJ
31:36 32:04 32:28
T
33i27 33:55 34:21
,^/Lw^y\/^--^A^.^A*»-A^^'v-r- JW/VAf.
i^ I T \ T^
iflf
35:25
L3.0E4
0 . OEO
35:00
Time
31:00 32:00 33:00 34:00
:'ile:S975834 #1-430 Acq: ll-SEP-1997 12:58:11 EI+ Voltage SIR 70S
159.7348 F:4 Exp:EPCUS
Sample Text:I-M23-l TLI#43085 INJ. TIME = 13:00 File Text:I-M23-l TLI#»
100% 34;45 _5.8E4
OJ
31:29
•r-^^T-
32:40 33:04 . 33:48 / V 35:13
y>^ ..A/^-.i7y>~~ xv^/^^-^^--^V^/^/wy/-v^~.J^-^A^^*A^ t j_
12.9E4
O.OEO
Time
31:00 32:00 33:00 34:00
?ile:S975834 #1-430 Acq:ll-SEP-1997 12:58:11 EI+ Voltage SIR 70S
169.7779 F:4 Exp:EPCUS
Sample Text:I-M23-l TLI#43085 INJ. TIME = 13:00 File Text:I-M23-l TLI#»
L00% 34:40 ^3.3E4
50J
0
32'0832:28
JV^AA ^JW-y,...—,, fAr^s-y
*=. ,-.** v T-Trmnrr-aiKw:. r3.'"r—y.
33:05 33i2833:48
35:50
L1.7E4
0 . OEO
35:00
Time
31:00 32:00 33:00 34:00
•'ile:S975834 #1-430 Acq: ll-SEP-1997 12:58:11 EI+ Voltage SIR 70S
171.7750 F:4 Exp:EPCUS
Sample Text:I-M23-l TLI#43085 INJ. TIME = 13:00 File Text:I-M23-l TLI#»
LOOSi 34:44 5. OE4
ll.
12.5E4
O.OEO
31:00 32:00 33:00 34:00 35:00 Time
30:45 31:19 32:07 33
A
:01 33:40 34:06 34:3/ \ 35:12 35^4
A^^^~=vst^^^v^>-^^^<^^/v^~^uV'A•s/y'xv~^A^v> — r^v
-------
7ile:S975834 #1-430 Acq:ll-SEP-1997 12:58:11 EI+ Voltage SIR 70S
169.7779 F:4 Exp:EPCUS
Sample Text:I-M23-1 TLI#43085
100%
INJ. TIME = 13:00 File Text:I-M23-l TLI#>
INJ. TIME =
33:00 34:00
>ile:S975834 #1-430 Acq:ll-SEP-1997 12:58:11 EI+ Voltage SIR 70S
171.7750 F:4 Exp:EPCUS
Jarople Text:I-M23-l TLI#43085
LOO*
90 j
80 j
70 J
60 J
50J
40J
30J
20 J
13:00 File Text
34 44
:I-M23-1 TLI#»
10J
0.
30:45
31:19
32:07
33:01
'< ' ' I r
31:00
31:42 I , I 32:31 A I AA33i4?
v^XvxvJuAJK^^v^N^AAAA/^ W-^AJu>A^w^uwW^Jvwky\
32:00
33:00
34loo'
"ssloo
-------
TLI Project: 43085
Client Sample: I-M23-2
Method 23 PCDD/PCDF Analysis (a)
Analysis File: S975835
Client Project:
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
S413-004
M23Train
181-55-6ABD
1.000
n/a
DB-5
Date Received:
Date Extracted:
Date Analyzed:
Dilution Factor:
Blank File:
Analyst:
09/03/97
09/04/97
09/11/97
n/a
S975815
BJG
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPX23704
SF56117
S975814
n/a
n/a
n/a
Analytes ;
2,3,7,8-TCDD
1,2,3,7,8-PeCDD
1, 2,3,4 ,7,8-HxCDD
1,2,3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
1,2,3,4.6,7.8-HpCDD
1,2,3,4,6,7,8,9-OCDD
2,3,7,8-TCDF
1,2,3,7.8-PeCDF
2,3,4,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1.2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,7.8,9-HxCDF
1.2,3,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
1,2,3,4,6,7,8,9-OCDF
•Totate .- •• . ^i.!"
Total TCDD
Total PeCDD
Total HxCDD
Total HpCDD
Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF
Amt (ng)
ND
ND
ND
ND
ND
1 ^Ls
ND
8.2
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
'/••:v4:;':-''f:;':Amtr. (rig)
ND
ND
ND
ND
0.17
0.33
ND
FJvlPC
DL EMPC
0.03
0.06
0 1
\J . 1
0.09
0 f)0
V/.V/^'
0.2
0.02
0.04
0.04
0.06
0.05
0.06
0.07
0.1
0.1
04
\J .^
Number DL EMPC
0.03
0.06
0.10
0.2
2
1 0.47
0.06
0.26
Ratio at ^ ftcgr
~
—
~~~~*
—
0.82 34:42 ~
Ftegs
Page 1 of 2
X237 J>SR YlOO, LARS 6.10 04
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 15:2600/1
-------
TLI Project: 43085
Client Sample: I-M23-2
Method 23 PCDD/PCDF Analysis (a)
Analysis File: S975835
lntematS«ard«-.3myf
3C.2-2,3,7,8-TCDF
13C,2-2,3,7,8-TCDD
13C,2-l,2,3,7,8-PeCDF
13C,2-l,2,3,7,8-PeCDD
13C,2-l,2,3,6,7,8-HxCDF
13C,2-l,2,3,6,7,8-HxCDD
13CP.-l,2,3,4,6,7,8-HpCDF
13Cp-l,2,3,4,6,7,8-HpCDD
13Cu-l,2,3,4,6,7,8,9-OCDD
Surrogate Standards {Type A)
37CL,-2,3,7,8-TCDD
l3C,:-2,3,4,7,8-PeCDF
13Ci:-l,2,3,4,7,8-HxCDF
13Cp-l,2,3,4,7,8-HxCDD
13Ci2-l,2,3,4,7,8,9-HpCDF
Alternate Standards (Type A)
13Cp-l,2,3,7,8,9-HxCDF
13C,2-2,3,4,6,7,8-HxCDF
. Recovery Standards -.'v:/;'-. :N ••';.:
13Ci2-l,2,3,4-TCDD
13Cii-l,2,3,7,8,9-HxCDD
Amt (ngj
1.8
2.0
1.4
1.4
2.3
2.0
1.3
1.2
14
Amt. (ng)
4.1
3.5
4.0
36
34
.;. Arnt. :(ng)
20
2.2
% Recovery
45.4
50.6
36.1
35.5
569
49.5
32.2
30.0
17 5
'•" • :: % Recovery
102
87.4
100
902
843
^•m^F^wyl
49 9
53.8
" '. -:•"..: !:x' '••'•:'::.:^::::C ;. '•' ' ' "•' '.'.'.
QC Limits
40%- 130%
40%- 1 30%
40%- 130%
40%- 130%
40%-130%
40%- 130%
25%-130%
25%- 130%
25%- 130%
QC Limits
70%- 140%
70%- 140%
70%- 140%
70%- 140%
70% -140%
jit- QC Limits
40% -1 30%
40%- 130%
<
Ratio
0.77
0.81
1.55
1.40
048
1.21
0.49
1 03
080
Ratio :
1.43
0.52
1 32
042
r:- Ratio "14
0 SA
0.51
Ratio
0.83
1.18
«T
20:44
21:30
24:54
26:01
28'35
29:18
31:16
32-07
34-42
RT
21:31
25:39
28:29
->9- 13
32-28
":"^RT ;-
">9-47
29:05
RT
21:17
29:35
Flags
v,ol_
v,Q_
_-
N
Flags
—
R
."•••Flags. '
—
Flags
—
Data Reviewer
Page 2 of 2
09/18/97
X237.PSR vXOO. LARS 6.10.0*
Triangle Laboratories, Inc.®
801 Capitals Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 15:26 09/1
134
-------
Data Review By:
Initial ....Date...
CU
''I / 10 /If
Calculated Noise Area:
The Total Area for each peak with an ion abundance ratio outside
ratio limits has been recalculated according to method requirements.
1.49
Page No.
09/18/97
Listing of S975835B.db£
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_2.... OC.Log Omit Why ..RT. OK .Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
TCDF
304-306
D
D
D
D
304-306
13C12-TCDF
316-318
316-318
TCDD
320-322
D
320-322
0. 65-0.89
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
SN
SN
SN
SN
SN
2
NL
WL
WL
WL
WL
WL
SN
1
NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
0
0:
18:
18:
18:
19:
19:
20:
21:
00
04
27
49
08
35
46
27
RO
RO
RO
RO
RO
6.
0.
1.
0.
0.
1.
1.
5.
00
66
41
33
76
07
35
30
Peaks
0:
16:
17:
17:
18:
19:
20:
20:
00
46
25
47
19
00
15
44
0.
RO
RO
RO
RO
0.
11.
2.
14.
16.
8.
5.
0.
28.
11
92 4.72
62
14
17 6.99
50
40
71
09
65-0.89
0.
0.
0.
0.
86
86
29
72
0.52
1 .
35
0.21
0.
Peak
0
18
18
19
19
19
20
20
20
21
21
22
22
22
22
:00
:42
:51
:06
:26
:52
:15
:34
:55
:32
:53
:02
:19
:31
:43
0.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
.77
0.
1.
0.
1.
13
64
87
82
1.15
2.07
1 .
518.
.63
.30 226.11
0.820-
0.
7.20 0.
0.
0.
9.18 0.
0.
1.
1.
1.101
000
871
890
908
923
945
002 2378-TCDF AN
035
0.951-1.049
0.
0.
0.
0.
0.
0.
0.
292.19 1.
000
309
340
358
383
916
977
,000 13C12-2378-TCDF ISO
518.30
m/*r\^ / »wr\r\ c>«*i i .*...«.
65-0.89
0
1
1
1
1
0
0
0
4
0
0
2
0
0
1
.86
.01
.02
.49
.21
.72
.48
.38
.00
.77
.45
.10
.89
.61
.45
Peaks
0
2
0
1
0
0
1
0
0
1
1
0
1
.13
.19
.30
.96
.51
.62
.47
.46
.50
.47
.08
.35
.40
0.90
1
.19
0.853-1.059
0
0
0
0
0
0
0
0
0
1
1
1
1
1
1
.000
.870
.877
.888
.904
.924
.942
.957
.973
.002 2378-TCDD AN
.018
.025
.038
.047
.057
0.00
37C1-TCDD
328
DC NL 0:00
0.05
0.906-1.094
0.000
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 15:1908/18&
19*
-------
Page No.
09/18/97
Listing of S975835B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
328
13C12-TCDD
332-334 DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
332-334
PeCDF
340-342 DC
DC
DC
DC
DC
D DC
WL
WL
WL
WL
WL
WL
SN
SN
SN
3N
SN
SN
SN
SN
SN
SN
3
NL
WL
WL
WL
WL
3N
SN
SN
SN
SN
SN
SN
SN
4
NL
WL
SN
SN
SN
SN
18:
18:
18:
18:
19:
19:
19:
20:
20:
20:
21:
21:
21:
21:
21:
22:
22.
22:
22:
Pee
0:
18:
18;
19:
19:
20:
20:
20:
20:
20:
21:
21:
21:
22:
22:
22:
22:
Pef
0:
22:
22;
23;
23;
24;
24:
24:
05
43
46
55
03
08
54
10
25
46
02
15
31
39
53
19
26
33
41
iks
00
11
43
14
23
13
16
23
35
39
17
30
50
03
21
:26
:48
iks
i 00
;36
:'>2
;14
;38
;03
:12
;32
0.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
1 .
RO
RO
RO
RO
RO
RO
65
26
3
0
2
1
2
1
1
2
3
0
0
1
1
10
1
2
32
0
0
1
0
2
1
0
1
-0.89
.43
.23
.59
.70
.61
.64
.94
.07
.37
.67
.83
.81
.23
. 34
. 30
.70
.01
1
-1 .78
.16
.34
.63
.70
.50
.24
.11
.46
1.
0.
0.
0.
0.
0.
108.
0.
0.
0.
0.
0.
403.
0.
11.
0.
1.
0.
1.
522.
0.
1.
1.
1.
1.
1.
1 .
0.
0.
0.
866,
467.
8.
1.
0.
0,
3.
.346.
Tr*nT
1 <— Ul
0.
0,
33,
0.
0.
13,
0,
4,
58
41
45
41
39
30
61 108.61
75
55
99
95
24
20 403.20
95
07 11.07
78
12
61
01
88
12
.43
59
40
96
75
95
99
,90
58
,86 392.91
,44 208.59
94 6.21
.24
,81
,89
.33 3.77
,57
.12
,43
.00 20.47
.77
.71
.18 8.01
.25
.92
0
0
0
0
0
0
0
0
0
0
0
0
1
1
1
1
1
1
1
0.906
0
0
0
0
0
0
0
0
0
0
473.95 0
258.85 1
5.05 1
1
1
1
1.88 1
0.907
0
0
12.53 0
0
0
6.48 0
0
0
.841
.871
.873
.880
.886
.890
.926
.938
.950
.966
.978
.988
.001 37C1-TCDD SUR1
.007
.018
.038
.043
.049
.055
-1.094
.000
.346
.871
.895
. 902
.940
.943
.952
.957
. 960
.990 13C12-1234-TCDD RSI
.000 13C12-2378-TCDD IS1
.016
.026
.040
.043
.060
-1.078
.000
.901
.912
.926
.942
.959
.965
. 97R
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 15:19 09/1^6
-------
Page No.
09/18/97
Listing of S975835B.dbf
Hatched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log omit why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
D
340-342
13C12-PeCDF
352-354
N
N
N
352-354
PeCDD
356-358
356-358
13C12-PeCDD
368-370
N
N
368-370
HxCDF
374-376
D
D
D
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
SN :
SN :
SN :
SN :
SN
SN
2
NL
SN
SN
SN
SN
SN
4
NL
WL
SN
SN
SN
SN
SN
0
NL
SN
SN
SN
SN
SN
2
NL
SN
SN
SN
SN
24:49 RO
25:15 RO
25:23 RO
25:27 RO
25:51 RO
26:45 RO
Peaks
1.2
0:00 RO
22:44 RO
23:04 RO
23:19 RO
24:54
25:05
25:10 RO
25:39
25:56 RO
26:38 RO
Peaks
1.
0:00 RO
24:00 RO
24:09 RO
24:21 RO
26:00 RO
26:18 RO
26:34
Peaks
1.
0:00 RO
23:56 RO
24:20 RO
25:28 RO
25:42 RO
26:01
26:08 RO
26:51 RO
Peaks
1
0:00
27:38
28:08
28:26 RO
28:34 RO
2.45
0.29
3.72
0.44
2.31
0.56
12-1.78
0.86
0.39
2.23
0.84
1.55
1.35
1.26
1.43
1.06
1.07
32-1.78
1.00
2.33
2.59
0.53
1.12
0.78
1.49
32-1.78
1.20
0.56
0.89
0.66
0.60
1.40
1.12
1.96
.05-1.43
1.09
1.24
1.43
4.69
0.79
1.02
1.48
0.74
1.53
5.61
1.65
46.18
0.10
0.94
1.22
1.69
354.68 215.73
2.09
3.08 1.87
300.59 177.02
2.50 1.52
1.66
660.85
0.12
2.07
1.76
1.41
1.50
0.41
2.32
0.00
0.10
1.02
0.64
0.94
0.20
195.33 114.11
19.63 11.93
2.40
214.96
D»fTM"\ I UvrTM? T?*-il 1 i-ibf«
i rSt-ULJ / ttX\_iM'r r ox .LOWS — — •
2.65
6.48
3.92
1.10
2.47
0.989
1.007
1.012
1.015
1.031 23478-PeCDF
1.066
0.838-1.162
0.000
0.906
0.920
0.930
138.95 0.993 13C12-PeCDF 123
1.000
1.49 1.003
123.57 1.023 13C12-P6CDF 234
1.43 1.034
1.062
0.921-1.026
0.000
0.918
0.924
0.932
0.995
1.006
1.017
0.845-1.155
0.000
0.916
0.931
0.974
0.983
81.22 0.996 13C12-PeCDD 123
10.61 1.000
1 .027
0.955-1.052
0.000
0.967
0.984
0.995
0.999 123678-HxCDF
KN
IS2.
SUR2
IS3
AN
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 15:
-------
Page No.
09/18/97
Listing of S975835B.db£
Matched GC Peaks / Ratio / R«t. Tin*
Coirpound/
M_Z.... QC.Log Omit Why ..RT. OX Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
D
374-376
13C12-HXCDF
384-386
334-386
HxCDD
390-392
D
390-392
13C12-HXCDD
402-404
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
SN 29:10
SN 29:17 RO
SN 29:19
SN
SN
SN
SN
SN
WH
0
NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
4
NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
WH
0
NL
WL
WL
WL
WL
29:30
29:38
29:41
29:47
30:02
30:08
Peaks
0:00
27:13
27:17
27:25
27:30
27:49
27:54
28:05
28:22
28:29
28:35
29:05
29:34
29:47
Peaks
0:00
28:02
28:14
28:30
28:31
28:42
28:46
29:03
29:10
29:14
29:19
29:34
29:49
Peaks
0:00
27:47
27:57
28:00
28:07
RO
RO
RO
RO
RO
0.
RO
RO
RO
RO
RO
RO
RO
RO
RO
1 .
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
1
RO
RO
RO
RO
RO
1.16
0.29
1.24
1.
0.
5.
0.
1.
0.
43-
0.
0.
3.
0.
0.
0.
0.
2.
1 .
0.
0.
0.
2.
0.
12
37
42
26
62
34
0.59
69
85
74
62
83
94
48
05
84
52
48
51
.40
.54
1.58
0.38
2.20
2.
84
0.99
0.58
0.
1.
0.
0.
2.
1.
0.
1.
1.
0.
1.
1.
0.
192.
63
55
78
00
10
24
47
27
00
79
27
45
83
92 65.74
201.07 65.31
176.
18 59.34
0.45
141.
.58 49.90
1.
1.
1 .
1.
1.
1.
1.
1.
1.
0.859-
0.
0.
0.
0.
0.
0.
0.
0.
0.
127.18 0.
135.76 1.
116.34 1.
1.
91.68 1.
020
024
026
032
037
038
042 123789-HxCDF
051
054
1.141
000
952
955
959
962
9" 3
976
983
992
997 13C12-HXCDF 478
000 13C12-HXCDF 678
017 13C12-HXCDF 234
034
.042 13C12-HXCDF 789
AN
SOR3
IS4
ALT2
ALT1
711.75
Uvr^^f / uiW"rsr*\ f ,-.! 1 Ai.tc-
05-1.43
1
1
1
2
0
1
2
1
4
0
2
10
0
.05
0
1
.08
.65
. 85
.54
.48
.70
.04
.84
.30
.77
.69
.08
.43
-1.43
.98
.79
0.97
0
.54
0.13
2
3
1
1
0
2
1
1
0
1
0
0
0
0
1
1
1
.29
.45
.52
.25
.70
.35
.21
.41
.99
.84
.72
.27
.96
.00
.75
.52
.68
0.79
0.42
0.950-1.015
0
0
0
0
0
0
0
0
0
0
1
1
1
0.966
0
0
0
. 000
. 957
. 964
. 9"'3
. 9~3
.980
.982
.991
.995
.998 123478-HxCDD
.001 123678-HxCDD
.009 123789-HxCDD
.018
-1.034
.000
.948
.954
AN
AN
AN
0.956
0.960
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 15:1909/18/1
-------
Page No. 5
09/18/97
Conqpound/
M_Z.... QC.Log Omit Why
Listing of S975835B.db«
Matched GC Peaks / Ratio / Ret. Time
.RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
402-404
HpCDF
408-410
403-410
13C 12 -HpCDF
413-420
418-420
HpCDD
424-426
D
424-426
13C12-HpCDD
436-438
436-438
DC WL 28:14 RO
DC SN 28:21 RO
DC SN 28:28 RO
DC SN 28:40 RO
DC SN 28:56 RO
DC SN 29:04 RO
29:13
29:18
29:35
DC SN 29:54
3 Peaks
0.
DC NL 0:00 RO
31:57 RO
DC SN 32:11 RO
32:24 RO
2 Peaks
0.
DC NL 0:00 RO
DC SN 31:05 RO
31:16
31:37 RO
DC SN 31:53
DC SN 31:59 RO
DC SN 32:07 RO
32:28
3 Peaks
0
DC NL 0:00 RO
DC SN 31:24 RO
DC SN 31:31
DC SN 31:52 RO
DC SN 32:00 RO
DC SN 32:18 RO
0 Peaks
0
DC NL 0:00 RO
DC SN 31:23
31:37 RO
32:07
32: 16 RO
DC SN 32:29 RO
3 Peaks
0.22
0.40
0.47
4.79
0.16
0.44
1.32
1.21
1.18
1.07
38-1.20
2.96
3.76
5.13
0.71
37-0.51
0.95
1 . 63
0.49
0.73
0.47
1.28
0.58
0.42
.88-1.20
0. 85
0.75
1.14
0.45
0.72
1.58
.88-1.20
1.77
0.94
1.30
1.03
0.57
5.68
1.01
0.85
1.01
0.96
0.33
0.42
127.00 72.36
144.74 79.14
293.62 158.87
2.54
565.36
2.24
2.53 4.66
0.61
5.00 2.55
7.53
2.12
1.77
83.95 27.59
2.85 1.44
1.74
1.66
1.24
54.54 16.23
141.34
1.79
1.41
9.13
1.33
1.65
1.96
0.00
1.75
0.64
3.26 2.08
71.73 36.31
2.47 1.26
0.75
77.46
0.964
0.968
0.972
0.978
0.987
0.992
54.64 0.997 13C12-HXCDD 478 SUR4
65.60 1.000 13C12-HXCDD 678 IS5
134.75 1.010 13C12-HXCDD 789 RS2
1.020
0.995-1.044
0.000
1.24 1.022
1.029
3.59 1.036
0.936-1.123
0. 300
0.994
56.36 1.000 13C12-HpCDF 678 IS6
1.98 1.011
1.020
1.023
1.027
38.31 1.038 13C12-HpCDF 789 SUR5 R
0.976-1.006
0.000
0.978
0.981
0.992
0.996
1.006
0.969-1.031
0.000
0.977
1.60 0.984
35.42 1.000 13C12-HpCDD 678 IS7
2.20 1.005
1.011
Triangle Laboratories, Inc.® Analytical Services Division
801 Caphola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 15:19 09/tM
199
-------
Page No.
09/13/97
Listing of S975835B.dbf
Hatched GC PeaXs / Ratio / Ret. Tiro*
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total .Area... Area. Peak. 1.. Area. Peak. 2. . Rel.RT Conqsound. Name.. ID.. Flags.
OCDF
442-444
442-444
0.76-
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
2
0:
31:
31:
32:
32:
32:
33:
33:
33:
33:
33:
34:
34
34
35
35
35
00
20
47
24
31
55
01
09
31
43
:54
:14
:45
:59
:07
:20
:51
RO
RO
RO
RO .
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
0.
0.
0.
0.
0.
0.
1.
1.
1.
1.
0.
0
0
1
1
0
0
1.02
59
63
22
43
76
33
75
01
32
.74
,54
.46
.27
.76
.14
.61
.44
Peaks
HpCDD / Octa-CDD and CDF Follows
1.17
2.02
0.47
2.00
0.90
1.19
1.30
1.39
1.70
2.95
2: 19
1.95
1.95
1.78
1.40
4.31
2.40
7.26
2.71
2.03
0.884-1.116
0.000
0.903
0.916
0.934
0.937
0.949
0.951
0.955
0.966
0.972
0.977
0.987
1.001
1.008
1.012
1 .018
1.033
1.56
3.35
OCDD 0.76-1.02
453-460 DC NL 0:00 0.31
AN 34:42 0.82
35:03 RO 0.63
458-460 2 Peaks
1.52
60.40
3.38
63.78
27.20
1.59
0.384-1.116
0.000
33.20 1.000 OCDD
2.54 1.010
13C12-OCDD 0.76-1.02
470-472 DC NL 0:00 RO 1.89
DC WL 34:24 RO 2.59
M 34:42 0.80
470-472 1 Peak
0.39
0.93
53 .40
53.40
23.80
0.995-1.005
0.000
0.991
29.60 1.000 13C12-OCDD
IS8 N
Column Description "Why" Code Description Q_C Log Desc.
M_Z -Nominal Ion Mass(es)
..RT. -Retention Time (mm:ss)
Rat.l -Ratio of M/M+2 Ions
OK -RO=Ratio Outside Limits
Rel.RT-Relative Retention Time
End of Report
WL-Below Retention Time Window
WH-Above Retention Time Window
SN-Below Signal to Noise Level
-------
TiletS975835 #1-848 Acqtll-SXP-1997 13i40i51 XI* Voltage SIX 70S NoifetlSO
303.9016 T:2 BSUB(256,30,-3.0) PKD(9,5,5,0.05\,720.0,1.00\,T,T) XxptEPCOS
TXIAHSLX LA3S Text:I-H23-2 TLH43085
A4.
A6.99E4
A5.14X4
A6.40E4
17:00 18:00 15:00 20:00 ; 21:00
rilo:S975835 41-040 Acqill-SEP-1997 13:40»51 EH- Voltage SIX 70S Ot±ae:30
305.8987 T:2 BSUB(256,30*-3.0) PKD(9,5,5,Q.05\,120.0,1.00\,r,T) XxptXPCUS
TRIANGLE LABS Text:I-M23-2 TLH43085
1004 A7.20E4
22100
17:00 18:00 15:00 20:00 21:00
rile:S975835 41-848 Ac^:ll-srP-15S7 13:40:51 EH- Voltage SIX 70S No±ae:30
315.9419 T:2 BSUB(256,30,-3.0) PKD(9,5,5, 0. OS\,120.0,1. 00\,T, T) Exp-.EPCOS
TRIANGLE LABS TextsI-M23-2 TLIf 43085
10 04 A2.26E5
80:
50:
40:
20:
22': 00
17:00 18:00 15:00 20:00 21:00
file:S975835 41-848 Ac?:ll-srP-1597 13:40:51 EI+ Voltage SIX 70S Mtoi«e:33
317.9389 T:2 BSUB(256,30,-3 .0) PKD( 9, 5,5, 0 . 05%,132. 0, 1. 00\,T, T) Exp:EPCUS
TRIANGLE LABS 7ezt:J-K23-2 IXJ443085
A2.92E6
60:
40:
20:
22:00
17:00 18:00 19:00 20:00
rile.-S975835 41-848 Acg:ll-SEP-1997 13:40:51 EI+ Voltage SIX 70S
330.9792 F:2 Exp:EPCDS
TRIANGLE LABS Text:I-H23-2 HJ443085
IOOJ| ..c. 18:5919:19 jo.c,
21: 00
22:00
8(9!
60:
40:
20:
0.
V
17:00 18:00 15:00 20:00
rile:S575835 41-848 Acg:ll-srP-19S7 13:40:51 EH- Voltage SIX 70S
375.8364 T:2 ExptEPCUS
TRIANGLE LABS Text:I-M23-2 TLH43085
17:09
21:00
22:00
60:
40:
20:
0.
21:01
22:21
57.
5.4X5
4.315
3 . 2ES
2.1E5
.1. 1E5
.O.OEO
Time
.5.825
.5. 5E5
.4.ir5
.2.7E5
.1. 4E5
O.OEO
T±m
3.OE6
2.4E6
1. 8E6
-1.2E6
.6.1E5
O.OEO
Tim
-8.9E3
'.7.1X3
Ls.3X3
1.3.6X3
.1.8X3
0.0X9
17:00
18:00
15:00
20:00
21100
22100
-------
'lieiSS75835 tl-848 Aeqill-SXP-1997 13i40i51 XI* Volt*7* SIX 70S Hoim»t29
'19.8965 Tt2 BSOB(256,30, -3.0) PB>(7,5,3, 0.05\, 116.0,1.00\,r,T) KiptXPCVS
TRIANGLE LABS Tejct: I-M23-2 TLH43085
100.1
15:00 20:00 21:00
rilatS975835 #1-848 Aoqill-SXP-1997 13:40:51 EH- Voltage SIS 70S Koite:34
321.8936 r>2 BSUB(256,30,-3.0) PKD(7,5,3,0.05\,136.0,1.00\,f,T) XxpiXPCUS
TRIANGLE LABS Text:I-H23-2 TLH43085
1001
A4 52E3 A1.16E4 A9.59E3
A1.12E4
22:00
19:00 20:00 21:00
rile:S975835 #1-848 Acq:ll-SEP-1997 13:40:51 EI+ Voltage SIS 70S Noiae:925
331.9368 r-.2 BSUB(256,30,-3.0) PKD(7,5,3,0.05\,3700.0,1.00\,r,T) Exp:EPCOS
TRIANGLE LABS Text: J-M23-2 TLH43085
1001
22:00
801
601
401
201
Ol
\A2.09E6
19:00 20:00 21:00
rile:S975835 #1-848 Acq:ll-SEP-1997 13:40:51 XI+ Voltage SIR 70S Noise:37
333.9338 T:2 BSUB(256r 30,-3 .0) PKD( 7, 5, 3, 0. 05\,148. 0,1. 00\,f, T) Exp:EPCUS
TRIANGLE LABS TextiI-M23-2 TLI#43085
22:00
1001
aoi
601
401
201
0.
A4.74E6
A2.59E6
19:00 20:00 21:00
r±le:S97583S #1-848 Acq:ll-SEP-1997 13:40:51 EI+ Voltage SIS 70S Noise:26
327.8847 T:2 BSUB(256,30, -3. 0) PKD(7,5,3, 0.05\,104. 0,1. 00*,T,T) ExpsEPCUS
TRIANGLE LABS TextiI-H23-2 TLI#430B5
100* A4.03E6
801
601
401
201
01
22: 00
Al.09E6
T
19:00 20:00 21:00
rile:S975835 #1-848 Acq:ll-SEP-1997 13:40:51 EI+ Voltage SIS 70S
330.9792 F:2 ExptEPCUS
TRIANGLE LABS TeztiI-H23-2 TLH43085
1001
18:59 19:19 19,52
8
-------
.le,S975835 tl-848 Aoqill-SXP-1997 13,40,51 XX+ Voltage SIX 70S Nolfe,35
39.8597 r,2 BSDB(256,30,-3.0) PXD(7,5,3,0.05\,140.0,1.00\,T,T) XxpiXTCOS
TXIAMGLX LABS Text,I-M23-2 TLH43085
OOS
sol
40.
20:
0.
23100 24,00 75*00
ile,S975835 tl-848 Aoqill-SXP-1997 13,40,51 EI+ Voltage SIX 70S Nolle,216
41.8567 F,2 BSUS(256,30,-3.0) PKD(7,5,3,0.OS\,864.0,1.00\,r,T) XxptXPCOS
TRIANGLE LABS Text,I-H23-2 TLH43085
004 Al. 5X5
23,00 24i00 25,00
ile,S975835 tl-848 Acqsll-SEP-1997 13,40:51 EI+ Voltage SIX 70S Noiae,31
51.9000 T:2 BSOB(256,30,-3.0) PKD(7,5,3,0.05\,124.0,1.00\,T,T) ExptEPCVS
TRIANGLE LABS Tejct,I-H23-2 TLH43085
00\ A2.16E6
Al.77E6
A*.
» J
I3f3
AS. 01X4
\AS.27X3 IA6.96X3 / \ *! *i A9 . a 3Z3 *1 •* **£
\«* _*p«A-A n ..A .A / ™ - yJlvsJ'^yAA/^ -A» A AV1ilL>/\ As
AS. 08X4
^Ar
.35X4 *3.6tg4
I A * N19.99X3
nJU^t* I\*A./\ At JA.
26,00
5.1X4
4.1X4
3.1X4
2.0X4
1.0X1
0.0X0
TiM*
26,00
23,00 24,00 25:00
rilesS975835 91-848 Acq:ll-SEP-1997 13,40,51 EH- Voltage SIX 70S Jtoiaes37
353.8970 Fs2 BSUB(256,30,-3.0) PKD(7,5,3,0.051,148.0,1.00\,F,T) ExpiEPCUS
TRIANGLE LABS TextsI-M23-2 TLIf43085
100* ,, ,OM A1.24E6
26,00
60:
40:
20.
0.
A1.39E6
4
6.4X5
5.1E5
3.8E5
2.6E5
.1. 3X5
.O.OEO
Tim.
.4.1X5
.3. 3E5
.2.5X5
.1. 7E5
.8.3X4
23,00 24,00 25', 00
rile,S97S835 fl-848 Acqsll-SEP-1997 13,40,51 EI+ Voltage SIX 70S
330.9792 T:2 XxpiEPCOS
TRIANGLE LABS Text,I-M23-2 TLH43085
26,00
O.OEO
Tim
23,00 24', 00 25:00
rile:S975835 tl-848 Acqtll-SXP-1997 13,40,51 EH- Voltage SIX 70S
409.7974 T:2 ElpiEPCDS
TRIANGLE LABS TextsI-M23-2 TLH43085
26,00
23,00
24,00
25100
26,00
20
-------
'±1.,SS75B3!, U-B4B Acq,11-3X9-1997 13,40,51 tit Voltage 3TI 70S Hoite:33
355.8546 fi2 BSOB(256, 30, -3.0) HO>( 7,5, 3, 0.05%, 132.0,1.00\,T,T) KlptfPCUS
TXIAJKUS LABS' TeJCttI-M23-2 TLH43085
24100 25'tOO 26100
rilei3975835 41-848 Acqtll-SXP-1997 13i40i51 EI+ Voltage SIX 70S Wo±»e,35
357.8516 Tt2 BSU3(356,30,-3.0) PKD(7,5,3,0.05\t140.0r1.00\,T,T) ElpiIPCOS
TRIANGLE LABS T»xttI-M23-2 TLH43085
IOC
34:00 25:00 26', 00
Tile:S975835 H-848 Acqill-SEP-1997 13:40:51 EI+ Voltage SIR 70S Xoiaes31
367.8949 T:2 BSVB(256,30, -3. 0) PKD(7,5,3, 0. 05\,124. 0,1.00%,T, T) Eip:EPCUS
TRIANGLE LABS TeitsI-M23-2 TLI«43085
A1.14E6
80.
60:
40.
20:
0.
24:00 25:00 26:00
Tile:S97583S tl-848 Acqsll-SEP-1997 13:40:51 EI+ Voltage SIX 70S Noime:26
369.8919 T:2 BSU3(2S6,30,-3.0) PKD(7,5,3,0.05\,104.0,1.00\,F,T) Elp:EPCUS
TRIANGLE LABS Tejct:I-M23-2 TLI#43085
A8.J.2E5
80.
60.
40.
20.
0.
24:00 25:00
FiletS97583S il-848 Acq:ll-SEP-1997 13:40:51 EI+ Voltage SIX 70S
330.9792 Tt2 ExptEPCUS
TRIANGLE LABS Text:I-M23-2 TLH43085
26*: 00
. 06E5
A
0.0X0
Tim»\
O.OEO
T±me
3.3E5
2.6E5
2.0E5
1. 3E5
6.6E4
O.OEO
Time
.2.4E5
1.9E5
.1.4X5
.9. 7E4
.4.8E4
.O.OEO
Tim.
20
-------
Tilm:S97583S #1-405 Acq:ll-BXf-1997 13i40i5l XI + Voltage SIX 70S Noime:689
373.8208 Tt3 *SUS(256,30,-3.0) HO)(7,5,3,0.05\,2756.0,1.00\rr,T) XzptXPCPS
TXIAHSLX LASS Text:I-H23-2 TLH43085
1001 A2. 1X4
5X3
0X0
27i24~ 37. «7»8« 00fl aafl 2flsJ5' 28t48' 29\00 29'>i2' 29\24' 29i36' 29t48 3b',00' 3»tl2 Time
rile:S975835 il-406 Acqill-SSf-1997 13i40t51 EI+ Voltage SIX 70S Boi*»:633
375.8178 r:3 BSUS(256,30,-f.O) rXD(7,5t3,O.OS\,2532.0,1.00\rTrT) Xlp:EPCUS
TXIAVSLX LASS Text:I-M23-2 TLII43085
A2.89E4
27:12 37,24 27:36 27:48 28:00 28:12 28>24 28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12
r±letS975835 il-406 Ac
-------
'iJ.«lSS758J5 *1-4QO Aoqill-SXf-1997 1J,40:51 XI* VoltMge SIX 70S
89.8156 Tt3 BSOB(256,30, -3.0) PO>(7,5,3,0.05\,2388.0,1.00\,T,T) XxptKPCOS
TRIANGLE LABS T*j[t,I-M23-2 TLH43085
100* A1.89E4
27,48 28:00 28,12 28:24 28:36 28:48 29,00 29,12 29,24
Tile,3975835 tl-406 Acq:ll-SXP-1997 13:40:51 EI+ Voltage SIS 70S NoitetSSO
391.8127 T:3 BSUB(2S6,30, -3. 0) PJO>(7,5,3, 0.05\,2200. 0,1. 00\,T,T) EzpiEPCVS
TRIANGLE LABS Text,I-H23-2 TLIt43085
80.
60.
40.
20.
A3.54X4
A1.36E4
29,36 29,48
.23X4
0.
'27:48 28:00 28:12 28,24 28:36 28:48 29:00 29:12 29:24
rile:S97S835 tl-406 Acqsll-SEP-1997 13,40,51 EI+ Voltage SIR 70S Nbiae:478
401.8558 r,3 BSUB(256,30,-3.0) PKD( 7,5, 3, 0.05\,1912. 0,1. 00%, T,T) Exp:EPCUS
TRIANGLE LABS Teit:I-M23-2 TLIt43085
1004
so;
so;
40.
20.
29:36 29:48
Al.59E6
A7.91E5
27:48 28:00 28:12 28:24 28:36 28,48 29:00 29:12 29:24
File:S975835 tl-406 Aoq:ll-SEP-1997 13:40:51 EH- Voltage SIR 70S Noite:490
403.8529 T:3 BSUB(256,30,-3.0) PXD(7,5,3,0.05\,1960.0,1.00\,T,T) ExpiEPCUS
TRIANGLE LABS Text:I-H23-2 TLH430S5
1001
ao:
so:
40.
20:
29:36 29:48
A1.35E6
A6.56E5
37148 28:00 38:13 28:24 28:36 ' '28\4829\66 29:12
Tile:S975835 tl-406 Acq:ll-SEP-1997 13:40:51 EI+ Voltage SIR 70S
392.9760 T:3 Xxp:XPCUS
Text:I-M23-2 TLIt43085
29:24
i i i *n 'i i' i i *i
29:36 29:48
38:16
TRIANGLE LABS
100^
27:48 28:01
BO:
601
40.
20:
o:
28:30
28:45
28:56.
9:04
29:19 29:29
.1.4X4
.1.1X4
.8.5X3
.5.6X3
.2.8X3
,0.0X0
T±m«
.6.8X3
_5.4E3
.4.1E3
.2.7X3
.1. 4E3
O.OEO
Time
_5. 8E5
'.4.6X5
-3.5E5
-2.3E5
.1.2E5
O.OEO
Time
.4.6X5
'.3. 7X5
-2.8X5
.1.9X5
.9.3X4
0.0X0
Tim
29:50
.2.1X6
11.7X6
'.1.3X6
.8.6X5
.4.3X5
27:48 28,00 28,12 28,24 28,36 28,48
29:00
29\12
i i I i i i i i I i i i i i I i i
29:24 29:36 29,48
.0.0X0
Time
206
-------
±l»tS97S835 fl-430 Acqill-SEP-1997 13:40,51 11+ VoJLtag* SIX 70S Nolle:1628
07.7818 T>4 B8UB(356,30,-3.0) tKD(7,5,3,0.05\,6513.0,1.00\,T,T) XxpiXPCUS
TRIANGLE LABS TmxtiI-M23-2 TLH43085
A3.57X4
31tl3 31,24 31': 36 3l'i48 32': 00 32:12 32:24
iletS975B35 tl-430 Acqtll-SEP-1997 13:40:51 EI+ Voltage SIS 70S No±*e:548
09.7789 ri4 BSUB(256,30,-3.0) PKD(7,5,3,0.051,2192.0,1.00%,T,T) XxptXPCOS
TRIANGLE LABS TexttI-H33-3 TLH43085
001
31:12 31:34 31:36 31:48 33:00 33:12 33:34
F±le:S975835 fl-430 Acq:ll-SEP-1997 13:40:51 EI+ Voltage SIR 70S Noiie:697
17.8353 T:4 BSUB(356,30, -3. 0) PKD(7,5,3, 0. 05\,3788. 0,1. 00\,T, T) ExpiEPCOS
TRIANGLE LABS Text:I-M33-3 TLH43085
001 A2. 76E5
32:36
32:48
31:12 31:24 31:36 31:48 32:00 32:12 32:24
r±le:S97SS35 fl-430 Acg:ll-SEP-1997 13:40:51 EI+ Voltage SIR 70S Noise:733
419.8220 T:4 BSUB(256,30,-3.0) PKD(7,5, 3, 0. 05\,2932. 0,1. 00\,T, T) Exp:EPCUS
TRIANGLE LABS Text:I-M33-2 TLH43085
1001 A5.64E5
32:36
so:
60.
40:
30:
o.
A3.83E5
Al.64E4
A2.01E4
T
~r
rr
T
31:12 31:24 31:36 31:48 32:00 33:13
rile:S975835 fl-430 Acq:ll-SEP-1997 13:40:51 EI+ Voltage SIR 70S
430.9739 T:4 Exp:EPCUS
TRIANGLE LABS Text:I-M23-2 TLI#43085
32:24
TY^P i i^r-i |"7 .
32:36 32:48
1003
80:
50:
40:
20:
o:
31:11
31:17
31:36
31:54 33:03
33:39
33:38
33:48
T
T
"T
~T
31tl3 31:34 31:36 3l':48 33'tOO 33:13
rile:S975835 fl-430 Acq:ll-SEP-1997 13:40:51 EI+ Voltage SIR 70S
479.7165 F:4 ExpsEPCUS
TRIANGLE LABS Tejct:I-H33-3 TLIf43085
33\24
i i i i i i t i i I i
32:36 33:48
.O.OEO
Time
.1. 3E5
.1. OE5
.7.8E4
.5.3E4
.2.6E4
.O.OEO
Tim<
.3.0E6
.1. 6E6
.1.2X6
.7.9E5
3.9E5
O.OEO
T±m
1001
31:37
31:12
31:24
31:36
31:48
32:00
32:12
32:24
32:36
32:48
-------
ld.eiSH7SSJS fl-430 Aoqill-SXr-1997 Ml40151 XI+ VoJitMg* SIX 70S aoi*mi437
\33.7766 Tt4 BSUB(256,30, -3.0) PXD(7,5,3,0.05\, 1828.0,1.00\,T,T) Exp:XPCUS
TRIANGLE LABS T*xt:I-H23-2 TLH43085
100*
31>1S 31': 24 31:30 31:36 31i42 31': 4 8 31:54 32:00 32:06 32tl2 32:18
riletS975835 #1-430 Acqtll-SXP-1997 13:40:51 XX+ Voltage SIX 70S Noise:536
425.7737 T:4 BSVB(2S6,30, -3.0) PKD(7,5,3,0.05\,2144.0,1.00\,r,T) XxpiXPCOS
TRIANGLE LABS TexttI-M23-2 TLH43085
1001 A4.27E4
32124
32^30
80.
60.
40.
20.
A2.93X4
~T
~T
T
T
31:18 31:24 31:30 3l':36 31:42 31:48 31:54 32\00 32:06 32:12 32:18
rile:S975835 tl-430 Acqtll-SEP-1997 13:40:51 XI+ Voltage SIX 70S KOitet759
435.8169 f:4 BSW3(256, 30, -3. 0) PXD(7,5, 3, 0. OS\, 3036. 0,1. 00\,T,T) Eip-.EPCOS
TRIANGLE LABS Text:I-M23-2 TLH43085
1003, A3.63E5
so:
60:
40.
32:24 32:30
20.
A2.08E4
Al.39E4
A2.10E4
31:18 31:24 Jl O 31 36 3142 31 s 154 32 32: 06 32:12
r±le:S975835 #1-430 Acq:ll-SEP-1997 13:40:51 XI+ Voltage SIX 70S Noise: 428
437.8140 r:4 BSUS(256 , 30, -3 .0 ) PKD( 7, 5, 3, 0 . 05\,1 712. 0,1 . 00\,T, T) Eip:EPCVS
TXIANGLE LABS Text:I-M23-2 TLI#43085
3^30
1001
801
60.
40:
20.
A3.S4E5
Al.60E4
A2.81X4
T
T
~r
31:18 31t24 31,30 31:36 31:42 31:48 3l't54 32:00 32:06
r±le:S975835 H-430 Acq:ll-SEP-1997 13:40:51 EI+ Voltage SIX 70S
430.9729 F:4 ExpsXPCUS
TXIANSLE LABS Toxt:I-M23-2 TLI#43085
A2.20E4
Al. 64E4
.0.0X0
T]JU
1. OE4
8.2X3
6.2X3
.4.1X3
.2.1X3
.O.OEO
Tixe
.8.3X4
.6.6X4
.5.0E4
.3.3E4
.1. 7X4
.O.OEO
Time
.8.1E4
.6.5X4
.4.9X4
.3.3X4
.1. 6X4
32:18 32:24 32:30
1003
80.
601
40.
20.
0.
31:29 31:36
32:03
31:18 31:24 31:30
'
3142 3l,48 3154
33:13
'32\24
0.0X0
Time
1.9E6
1.5X6
1.2X6
7.7X5
3. 9X5
0.0X0
Time
208
-------
Al. 73X4
F11*:S975835 tl-430 Acqill-SXP-1997 13i40i51 11+ Voltage SIX 70S Koif»:276
441.7428 f:4 BSUB(256,30,-3.0) PXD(7,5r3,0.05\,1104.0,1.00\,r,I) XxftXfCOS
TXIANGLE LASS Tmjct: I-H23-2 TLH43085
1003
901
80.
701
601
50J
40.
30.
20.
10.
0.
3l':00 32:00 33:00 34:00
rila:S975835 #1-430 Aoq:ll-SXP-1997 13:40>51 XH- Voltage SIX 70S Hoif»,464
443.7399 T-.4 BSUB(256,30, -3. 0) PKD(7,5,3, O.OS\,18S6. 0,1.00\,T, T) ExptEPCUS
TRIANGLE LASS TextsI-M23-2 TLH4308S
1003k A2. 7E4
A2.03E4
Al.76X4
A2.46E4
A1.22E4
A1.50E4 A2.71C4
A1.21X4\
2.4X4
.2.2X4
.1.9*4
a. 7X4
.1.4X4
JL.2X4
35:00
31': 00 32:00 33:00 34:00
F±le:S975B35 #1-430 Acq:ll-SEP-1997 13:40:51 EH- Voltage SIX 70S
430.9729 r:4 Exp:EPCUS
TSI ANGLE LABS Text: I-M23-2 TLHH3085
lOOi
31:00 32:00 33:00 34:00
f±le:S975835 91-430 Acqtll-SEP-1997 13:40:51 EH- Voltage SIS 70S
513.6775 T:4 Exp:EPCUS
TRIANGLE LABS T&xt:I-M33-2 TLIH3085
1001
801
70.
60.
501
40.
301
10.
33:18
33:'.
34:11
34:30
35:00
35:01
35:00
2.1E6
1. 9E6
1. 7E6
1.5E6
.1.2E6
.1. 0X6
.8.3E5
.6.2E5
.4.1ES
.2.1X5
.0.0X0
Tim
20
-------
'U»:S975B35 H-130 \oytll-3Sf-1997 MtiOiSl K+ Voltage S» 70S lbim»,342
57.7377 ri4 BSDB(256, 30,-3.0) PKD(7,5,3,0.05\,1368.0,1.00\,r,T) XxptXTCOS
TXIAHGLE LABS T*xttI-M23-2 TLIH308S
001 A2.84E5
80.
60.
40.
201
34,24 34:30 34:36 34:42 34,48 34:54
ile:S975835 $1-430 Acqill-SXP-1997 13:40,51 XI+ Voltage SIX 70S «Oi»»:418
59.7348 F:4 BSOB(256,30, -3. 0) PB>(7,5,3, 0. 05%, 1672. 0,1. 00%,T, T) Xxp:XPCVS
TRIANGLE LABS T»It:I-M23-2 TLH43Q85
10 0\ A3. $1X5
80.
60.
40.
A2.20X4
35100
.3.0X4
'.2.4X4
11. 8X4
.1.2X4
.6.0X3
0.0X0
Tim,
201
A7.55E3
3.9X4
.3.1X4
.2.3X4
LI. 6E4
.7.8E3
34:24 34:30 34:36 34:42 34:48 34:54
rile:S975835 #1-430 Acqtll-SEP-1997 13:40:51 EH- Voltage SIX 70S Soite:443
469.7779 F:4 BSOS(256, 30, -3. 0) PKD( 7,5,3, 0. 05\,1772. 0,1. 00\,T,T) Eip:EPCUS
TRIANGLE LABS T*xtiI-H23-2 TLH43085
1001 A1.73E5
0.0X0
35:00 Tim,
34:24 34:30 34:36 34:42 34:48 34,54
rile:S975835 H-430 Acq:ll-SEP-1997 13:40:51 XI+ Voltage SIX 70S Hoiae:235
471.7750 r,4 BSUB(256,30,-3.0) PKD(7,5,3, 0. 05\,940. 0,1. 00%,T, T) Sxp:EPCUS
TRIANGLE LABS Text.:I-M23-2 TLH43085
1001 A2.98E5
80.
60.
40.
35,00
201
A4.B7E3
3.5E4
.2.8X4
.2.1X4
.1.4E4
.7.0E3
34:24 34:30 34:36 34:42 34:48
r±le:S975835 H-430 Acq:ll-SEP-1997 13:40:51 EH- Voltage SIX 70S
430.9729 Ti4 ExpiEfCUS
TRIANGLE LABS Text:I-H23-2 TLU430B5
1003
80.
60.
40.
20.
0.
34:30
34:41
34:45
•34:54
34154
35:00
.0. OSO
Tim
-2.1E6
-1. 7X6
.1.2X6
-.8.3X5
.4.1X5
34:24
34130
34:36
34:42
34:48
34:54
35:00
0.0X0
Tim
-------
-430 Acq:ll-SEP-i997 II:
EI+ Voltage SIR
File Text:I-M23-2 TLI#43085
32:28
3i:00 32;00 33:00
ile:S975835 #1-430 Acq: ll-SEP-1997 13:40:51 El-f Voltage SIR 70S
File Text:I-M23-2 TLI#43085
32.29
Time
-------
ile:S975835 #1-430 Acq:ll-SEP-1997 13:40:51 EI+ Voltage SIR 70S
23.7766 F:4 Exp:EPCUS
ample Text:I-M23-2 TLI#43085 File Text:I-M23-2
00%. 32:07
TLI#43085
601
40J
20J
31:31
33:38
1.6E4
L1.3E4
L9.5E3
L6.4E3
L3.2E3
LO.OEO
31:00 32:00 33:00
ile:S975835 #1-430 Acq:ll-SEP-1997 13:40:51 EI+ Voltage SIR 70S
25.7737 F:4 Exp:EPCUS
ample Text:I-M23-2 TLI#43085 File Text:I-M23-2 TLI#43085
00%.
31:30
34:00 Time
31:00 32:00 33:00
ile:S975835 #1-430 Acq:ll-SEP-1997 13:40:51 EI+ Voltage SIR 70S
35.8169 F:4 Exp:EPCUS
ample Text:I-M23-2 TLI#43085 File Text:I-M23-2 TLI#43085
DOS, 32; 07
801
60 J
OJ
30:5131:05
31:46
33:22
33:43
31:00
32:00
34:00 Time
8.3E4
L6.6E4
L5.0E4
L3.3E4
L1.7E4
33:00
O.OEO
34100 Time
-------
CO
l€
7.
mj
1 05
0
le
9.
mp
'0%
0'
le
9.
imp
(T
.le
'1.
imp
o:
j:S975835 #1-430 Acq:ll-SEP-1997 13:40:51 EI+ Voltage SIR 70S
7377 F:4 Exp: EPCUS
>le Text:I-M23-2 TLI#43085 File Text:I-M23-2 TLI#43085
34:41
f\
3Q 31:41 32:10 32:5733:i7 33:54 34;24/ ^ 35:1? g
r^^Mf^^^^^ WA/Vyv/'l^l/WXAA^
31 loO 32 loo 33:00 34!oo' 35:00
:S975835 #1-430 Acq: ll-SEP-1997 13:40:51 EI+ Voltage SIR 70S
7348 F:4 Exp: EPCUS
le Text:I-M23-2 TLI#43085 File Text:I-M23-2 TLI#43085
34 -44
"ii.ii J i
30:49 j 31:54 32:44 33:07 33:31 34||18 / \ 35:13 35:38
31:00 32IOO 33:00 34:00 35:00
.-S975835 #1-430 Acq: ll-SEP-1997 13:40:51 EI+ Voltage SIR 70S
7779 F:4 Exp: EPCUS
le Text:I-M23-2 TLI#43085 File Text:I-M23-2 TLI#43085
34:$9
M\
31:22 32:07 32:52 33:23 33 :52 ,4 ;1, / V^ 35:0835 :2835:4jt
i^f^J^^V^^ SrVVU>^AWjV\MrWW^
31:00 . 32:00 33:00 34:00 35:00
:S975835 #1-430 Acq: ll-SEP-1997 13:40:51 EI+ Voltage SIR 70S
7750 F:4 Exp: EPCUS
le Text:I-M23-2 TLI#43085 File Text:I-M23-2 TLI#43085
34:42
i
/U ^ 35*37
31:24 31:48 32:15 32:47 33 : 17 33 : 40 34j°2 If L 35:15 j
rAk^^-^A~M^A-J\~*^J
-------
Lle:S975835 #1-430 Acq:ll-SEP-1997 13:40T5T~EI+ Voltage SIR 70S
57.7377 F:4 Exp:EPCUS
ample Text:I-M23-2 TLI#43085 File Text: I-M23-2_, TLJ#43085
00%. (£2.72E5 '
34:00 35:00
Lle:S975835 #1-430 Acq:ll-SEP-1997 13:40:51 EI+ Voltage SIR 70S
39.7348 F:4 Exp:EPCUS
ample Text:I-M23-2 TLI#43085 File Text:I-M23-2 _TLI#43085
00%
34:00 35:00
ile:S975835 #1-430 Acq:ll-SEP-1997 13:40:51 EI+ Voltage SIR 70S
59.7779 F:4 Exp:EPCUS
ample Text:I-M23-2 TLI#43085 File Text:I-M23-2 TLI#43085
34:00 35:00
ile:S975835 #1-430 Acq:ll-SEP-1997 13:40:51 EI+ Voltage SIR 70S
71.7750 F:4 Exp:EPCUS
ample Text:I-M23-2 TLI#43085 File Text:I-M23-2 TLI#43085
00% 34:42
O.OEO
Time
Time
34OO
35:00
O.OEO
Time
3.5E4
L1.7E4
O.OEO
Time
-------
CM
Lle:S97b«Jb #1-43U
59.7779 F:4 ExprEPCUS
unple Text:I-M23-2 TLI#43085 File Text:I-M23-2
30%
SIR /us
31:00 32100 3300 34:00
Lle-S975835 #1-430 Acq:ll-SEP-1997 13:40:51 EI+ Voltage SIR 70S
File Text:I-M23-2 TLI#43085
35:00
Time
O.OEO
Time
-------
<£>
«H
CM
ile:S975835 #1-430 Acq:ll-SEP-1997 13:40:bl EI+ Voltage SIR 7US
69.7779 F:4 Exp.-EPCUS
anple Text:I-M23-2 TLI#43085 File Text:I-M23-2 TLI#43085
00% A2.38E5
33iOO 34100 35:00
ile:S975835 #1-430 Acq:ll-SEP-1997 13:40:51 EI+ Voltage SIR 70S
71.7750 F:4 Exp:EPCUS
ample Text:I-M23-2 TLI#43085 File Text:I-M23-2 TLI#43085
nn» A2.96E5
90J
80 J
70 J
60 J
50 J
40 J
30j
20J
10J
k/^j^AsJ\J^
0.
33:00
34!00
35:00
.3.5E4
.3.1E4
.2.8E4
.2.4E4
.2.1E4
.1.7E4
.1.4E4
.1.0E4
.7.0E3
.3.5E3
.O.OEO
Time
-------
TLI Project: 43085
Client Sample: I-M23-3
Method 23 PCDD/PCDF Analysis (a)
Analysis File: S975843
Client Project:
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
S413-004
M23Train
181-55-7ABD
1.000
n/a
DB-5
Date Received:
Date Extracted:
Date Analyzed:
Dilution Factor:
Blank File:
Analyst:
09/03/97
09/04/97
09/11/97
n/a
S975815
KB
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPX23704
SF56117
S975839
n/a
n/a
n/a
Analytes
2,3,7,8-TCDD
1,2,3,7,8-PeCDD
1,2,3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
1,2,3,4,6,7,8-HpCDD
1,2,3,4,6,7,8,9-OCDD
2,3,7,8-TCDF
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
1,2,3,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
1,2,3,4,6,7,8,9-OCDF
totate
Total TCDD
Total PeCDD
Total HxCDD
Total HpCDD
Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF
Amt. (ng)
ND
ND
ND
ND
ND
0.14
16.2
0.01
ND
ND
0.02
ND
EMPC
ND
0.04
ND
ND
Amt (ng)
ND
ND
0.02
0.34
0.01
EMPC
0.03
0.04
BL £WPC
0.005
0.009
001
\Jt\J i.
0.01
0.01
0.005
0.005
0.006
0.006
0.008
0.02
0.05
Number Dt SMPC
0.005
0.009
1 0.05
2
1 0.02
0.01
2 0.05
1
ftalfo «T ~ Flags
1.07 32:09 B~
0.87 34:39
0.70 20:26 B_
1.21 28:22
1.02 31:15 iZ
flags
.._
SL
-^^
Page 1 of 2
X237JPSR vlOO. LARS 6.10.&
Triangle Laboratories, Inc.®
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 15:19 09/18/91
21
-------
TLI Project: 43085
Client Sample: I-M23-3
Method 23 PCDD/PCDF Analysis (a)
Analysis File: S975843
Internal Standards
13Cl2-2,3,7,8-TCDF
13C,2-2,3,7,8-TCDD
13C,2-l,2,3,7,8-PeCDF
'3C,2-l,2,3,7,8-PeCDD
'3Ci2-l,2,3,6,7,8-HxCDF
13C,2-l,2,3,6,7,8-HxCDD
13C,2-l,2,3,4,6,7,8-HpCDF
13C,2-l,2,3,4,6,7,8-HpCDD
I3C12-1,2,3,4,6,7,8.9-OCDD
Surrogate Standards (Type A)
37CL,-2,3,7,8-TCDD
13C,2-2,3,4,7,8-PeCDF
13C,:-l,2,3,4,7,8-HxCDF
13Cr-l,2,3,4,7,8-HxCDD
13Cr-l,2,3,4,7,8,9-HpCDF
Alternate Standards (Type A}
13Ci2-l,2,3,7,8,9-HxCDF
13C,2-2,3,4,6,7,8-HxCDF
:::Re«»ro#Stand»^^^
13CI2-1,2,3,4-TCDD
13C,2-l,2,3,7,8,9-HxCDD
Amt« (ng) -,
2.5
2.3
2.3
2.3
2.6
2.3
1.4
1.2
1 3
; Amt, (ng)
4.1
3.7
4.5
40
30
Amt (rig)
2.2
2.9
!^'.
-.. % Recovery
*• f f •*
63.3
58.5
56.9
57.2
645
580
35.3
29.8
160
% Recovery:
103
93.4
112
99 8
75 7
% Recovery
54.2
73.5
QC Limits
40%-130%
40%-130%
40%-130%
40%-130%
40%- 130%
40%- 130%
25%-l30%
25%-130%
25%- 130%
QC Limits
70%- 140%
70%- 140%
70%- 140%
70%- 140%
70%- 140%
-QC Limits
40%-130%
40%- 130%
, Ratio
f
0.76
0.80
1.50
1.55
049
1 14
0.42
1.03
088
Ratio .
1.49
0.45
1 31
0 39
.•:'.;:;:;:':::-Ratio
0.48
0.48
Ratio
0.80
1.22
IflF / Ftegst,? -
20:24
21:13
24:42
25:50
28'29 Q
•79-12
31:14
32:07
RT Flags
21:14
25:28
28:22
-59.97
RTvr.iflagsv;
29:44
28:59
RT Flags
21:00
29:31
Data Reviewer.
Page 2 of2
09/18/97
X237.PSR »2.00. LARS 6.1OM
Triangle Laboratories, Inc.®
801 Caprtola Drive • Durham, North Carolina 27713
phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 15:19 09/18/97
21*
-------
Data Review By:
Initial Date...
*yV~ I / /8/ iT Calculated Noise Area:
1.87
The Total Area for each peak with an ion abundance ratio outside
ratio limits has been recalculated according to method requirements.
Page No.
09/18/97
Listing of S975843B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
0.818-1.101
0.000
0.852
0.879
0.924
0.967
5.33 9.07 0.977
0.991
7.65 11.00 1.002 2378-TCDF AN
1.062
1.094
1.110
TCDF
304-306 DC
D DC
D DC
DC
DC
DC
M
DC
D DC
DC
304-306
NL
SN
5N
SN
SN
SN
SN
SN
WH
2
0:
17:
17:
18:
19:
19:
20:
20:
21:
22:
22:
00
23
56
51
44
56
13
26
40
19
39
0.
RO
RO
RO
RO
RO
RO
RO
65-0.89
0.
45.
57.
0.
0.
0.
1.
0
0
0
0
21
05
19
29
.24
.59
.94
.70
.69
.85
.71
Peaks
0.
5.
5.
3.
1.
12.
2.
18.
2
9
3
30
83
27
12
40
.59
.25
.80
.65
.76
.84
.82
.90
13C12-TCDF
316-318
316-318
DC
DC
DC
DC
DC
NL
WL
SN
WH
WH
2
0:
19:
19:
20:
20:
21
22
00
12
55
24
40
:36
:29
0.
RO
RO
RO
RO
RO
65-0.89
0.
1.
0.
0
0
0
0
,79
45
.91
.76
.10
.02
.32
Peaks
1.
4.
14.
4,035
4
6
8
4,050
97
,90
.76
.54
.44
.67
.14
.30
0.951-1.049
0.000
0.941
7.55 8.34 0.976
1,747.71 2,287.33 1.000 13C12-2378-TCDF ISO
1.013
1.059
1.102
Above: TCDF / TCDD Follows
TCDD
320-322
320-322
0.65-0.89
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
WH
0
0:
18:
18:
18:
18
19
19
20
20
21
21
22
22
00
12
:21
:36
:48
:10
:30
:24
:49
:04
:22
:04
:33
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
0.
0.
0.
0.
1.
3.
2.
3
0
0
0
0
2
61
95
32
70
,08
.87
.72
.10
.63
.52
.69
.45
.09
Peaks
0.85
2.99
2.74
1.65
4.99
1.10
0.83
4.96
0.39
2.80
1.45
0.92
1.13
0.00
0.851-1.058
0.000
O.S58
0.865
0.877
0.886
0.903
0.919
0.962
0.981
0.993
1.007
1.040
1.063
37C1-TCDD
328
DC NL 0:00
0.28
0.906-1.094
0.000
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
^hone: (919) 544-5729 • Fax: (919) 544-5491
Printed:! 5:20 09/18H
21
-------
Page Ho.
09/18/97
Listing of S975843B.dbt
Matched <3C Peaks / Ratio / Ret. Tin
Compound/
M_z.... gc.Log omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Conpound.Na
ID. . Flags.
328
13C12-TCDD
332-334
332-334
PeCDF
340-342
D
340-342
13C 12 -PeCDF
352-354
352-354
PeCDD
356-358
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
4
NL
4
NL
SN
SN
SN
SN
SN
SN
SN
3N
SN
SN
SN
SN
SN
SN
WH
1
NL
SN
SN
SN
SN
SN
3
NL
19:39
21:14
21:35
21:41
Peaks
0:00
19:55
21:00
21:13
21:34
0.
RO
RO
•65-0.89
8.95
1.52
0.80
0.80
0.84
Peaks
0:
22;
22
23:
23:
24:
24:
24:
24:
25:
25:
25;
25;
25:
25:
26:
26:
:00
:37
: 51
:25
•49
24
:25
:44
:55
;00
:08
:19
:29
:38
;56
:16
:58
1.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
32
0
1
2
1
2
1
2
0
4
1
1
3
0
1
1
0
0
-1.78
.80
.82
.54
.91
.36
.42
.43
.53
.35
.20
. 10
. 14
.95
.14
.56
.91
.90
Peak
0:
23:
24:
24;
24:
25:
25:
25:
:00
:49
:20
42
;52
28
:47
:52
26:27
Peaks
0:
:00
1.
RO
RO
RO
RO
RO
RO
RO
1.
RO
32
1
2
2
1
3
1
7
6
2
32
5
-1.78
.00
.33
.33
.50
.27
.49
.09
.42
.07
-1.78
.60
7
2,615
3
3
2,630
0
7
4.836
3,017
31
7,893
0
8
2
0
8
2
1
1
1
1
0
0
2
3
1
0
0
8
0
3
8
3,116
4
2,822
1
1
4
5,946
P«(T\
> rOL.1/
0
.51 7.51
•91 2,615.91
•24 3.24
.49 3.49
.15
.39
.89 6.76
•79 2,156.40
.80 1,343.17
•45 14.34
.93
D / PeCDF Follows —
.07
•31 5.94
.22
.59
.13
.47
.53
.92
.10
.94
.54
.74
.83
.14
.69
.49
.94
.31
.10
.90
•03 7.33
.31 1,870.46
.97
.10 1,689.29
.43
.53
.82
.44
F / PeCDD Follows —
.13
0.926
1.001 37C1-TCDD SUR1
1.017
1.022
0.906-1.094
0.000
4.46 0.939
2,680.39 0.990 13C12-1234-TCDD RSI
1,674.63 1.000 13C12-2378-TCDD IS1
17.11 1.016
0.905-
0.
3.26 0.
0.
0.
0.
0.
0.
1.
1.
1.
1.
1.
1.
1.
1.
1.
.
0.838-
0,
0.
3.15 0.
1,245.85 1,
1.
1,132.81 1,
1.
1.
1.
0.919-
0.
1.077
000
916
925
948
964
988
989
001 12378-PeCDF AN
009
012
018
025
032 23478-PeCDF AN
038
050
063
092
1.162
000
964
985
000 13C12-PeCDF 123 IS2
007
031 13C12-PeCDF 234 SOR2
044
047
071
1.025
000
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Dhone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 15:20 09/18/97
220
-------
Page No.
09/18/97
Listing of S975843B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
0.923
0.928
0.935
0.949
0.956
0.977
0.985
0.996
356-358
13C12-PeCDD
368-370
368-370
HxCDF
374-376
MK
374-376
13C12-HXCDF
384-386
384-386
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
SN 23:50 RO 1.23
SN 23:58 RO 1.28
SN 24:09 RO 0.45
SN 24:31 RO 4.59
SN 24:42 RO 4.00
SN 25:15 RO 0.93
SN 25:27 RO -18.10
SN 25:44 RO 0.36
SN 25:52 1.63
SN 25:58 RO 5.94
WH 26:43 RO 1.10
0 Peaks
1.84
2.65
1.00
1.38
3.39
1.10
0.51
0.31
1.55
0.46
1.76
0.00
1.32-1.78
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
2
NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
WH
4
NL
SN
SN
0:00 RO
25:50
25:59
Peaks
1.
0:00 RO
27:22 RO
27:31
27:41
27:48 RO
28:22
28:29 RO
28:37 RO
28:43 RO
28:48 RO
29:00 RO
29:12 RO
29:22 RO
29:34 RO
29:44 RO
29:49
29:56 RO
30:04 RO
Peaks
0
0:00 RO
27:30 RO
28:22
28:29
28:59
29:11 RO
29:44
9.14
1.55
1.60
05-1.43
1.03
1.50
1.33
1.22
1.53
1.21
1.49
0.33
2.26
0.98
1.45
0.36
3.63
5.38
1 .01
1.41
3 .40
1.75
.43-0.59
0.32
0.75
0.45
0.49
0.48
0.99
0.48
4 Peaks
0.18
1.755.85
148.96
1,904.81
0.70
5.38
12.08
1.44
1.93
10.85
3.54
0.42
0.43
2.19
3.74
0.14
0.36
0.29
1.41
1.64
0.22
0.27
32.05
2.22
1.25
2,317.24
2,162.06
2,280.64
2.13
1,461.67
8,221.61
1,066.84
91.60
Follows
3.59
6.89
5.94
2.42
719.33
706.30
735.67
473.75
1.001 12378-PeCDD
1.005
1.034
AN
0.845-1.155
0.000
689.01 1.000 13C12-PeCDD 123 IS3
57.36 1.006
0.955-1.051
0.000
2.40 0.961
5.19 0.966
0.972
0.976
4.91 0.996 123478-HxCDF AN
1.000 123678-HxCDF AN
1.005
1.008
1.011
1.67 1.018 234678-HxCDF AN
1.025
1.031
1.038
1.044 123789-HxCDF AN
1.047
1.051
1.056
0.859-1.141
0.000
0.965
1,597.91 0.996 13C12-HXCDF 478 SUR3
1,455.76 1.000 13C12-HXCDF 678 IS4 Q
1,544.97 1.018 13C12-HXCDF 234 ALT2
1.025
987.92 1.044 13C12-HXCDF 789 ALT1
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
°hone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 15:20 09/1JW
22
-------
Page No.
09/18/97
Listing of S975843B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Conpound. Name.. ID., flags.
HXCDD
390-392
K
390-392
13C12-HXCDD
402-404
402-404
HpCDF
408-410
408-410
13C 12 -HpCDF
418-420
418-420
HpCDD
424-426
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
SN
SN
SN
SN
SN
SN
WH
3
NL
SN
SN
3
NL
SN
SN
SN
SN
1
NL
SN
SN
2
NL
WL
SN
0:00
27:55
28:06
28:11
28:22
28:28
28:37
29:00
29:13
29:30
29:44
Peaks
0:00
28:37
29:08
29:12
29:31
29:51
Peaks
0:00
31:15
31:38
31:44
31:54
32:04
Peak
0:00
31:14
32:07
32:27
32:41
Peaks
0:00
31:13
31:31
31:51
.32:09
1.
RO
RO
RO
RO
RO
RO
RO
RO
RO
1.
RO
RO
RO
0.
RO
RO
RO
RO
RO
0.
RO
RO
0.
RO
RO
RO
ADOVe: HXCOF
05-1.43
0.
1.
0.
. 1.
2.
3.
1.
2.
2.
2.
11.
05-
1.
1.
1.
1.
1.
1.
88-
3.
1.
1.
1.
12.
3.
37-
2.
0.
0.
0.
0.
83
35
77
27
98
57
61
66
25
47
32
1.43
54
66
31
14
22
99
1.20
60
02
22
75
00
83
0.51
33
42
72
39
45
,88-1.20
1.
2.
1.
0.
1.
35
15
04
80
07
0.
10.
0.
0.
3.
1.
6.
2.
1.
2.
0.
20.
/ HXCDD Follows --•
27
53 6.04
18
34
65 4.85
86
74 4.85
93
37
67
56
92
0.950-1.014
0.
4.49 0.
0.
0.
1.63 0.
0.
3.01 0.
0.
1.
1.
1.
000
956
962
965
971
975
980
993
001 123678-HxCDD
010 123789-HXCDD
018
AN
AH
0.966-1.034
1.
3.
1,559.
1,605.
2,782.
2.
5,946.
Hvf^ nr
> flX^UL
0.
13.
3.
1.
0.
0.
13.
37
52
21 884.19
00 855.13
46 1.529.14
17
67
t / HpCDF Follows --
51
52 6.34
45
12
08
47
52
0.
0.
675.02 0.
749.37 1.
1,253.32 1.
1.
0.994-
0.
6.68 1.
1.
1.
1.
1.
000
980
998 13C12-HXCDD 478
000 13C12-HXCDD 673
Oil 13C12-HXCDD 789
022
1.044
000
001 1234678-HpCDF
013
016
021
027
SUR4
IS5
RS2
AN
0.936-1.128
0.
871.
0.
508.
1.
39
85 258.15
52
55 143.25
64
1,380.40
: HpCDF / HpCDD Follows —
0.35
3.37
37.00 18.84
1.18
24.66 12.73
0.
613.7X) 1.
1.
365.30 1.
1.
000
000 13C12-HpCDF 678
028
039 13C12-HpCDF 789
046
IS6
SUR5
0.976-1.005
0.
0.
18.16 0.
0.
11.93 1.
000
972
981
992
001 1234678-HpCDD
AH
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 15:20
-------
Page No.
09/18/97
Listing o£ S975843B.db£
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_2.... QC.Log Omit Why .,RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
424-426
2 Peaks
61.66
13C12-HpCDD
436-438
436-438
OCDF
442-444
442-444
OCDD
458-460
458-460
13C12-OCDD
470-472
0.88-1.20
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
SN
SN
1
NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
0
NL
SN
1
NL
0:
31:
32:
32:
00
28
07
24
RO
RO
RO
6.
7.
1.
0.
36
06
03
34
Peak
0:
31:
31:
32:
32:
32:
33:
33
33
33
33
34
34
34
34
35
35
00
09
29
09
:23
41
:03
:07
:15
:28
:32
:17
:34
:45
-.52
:07
:35
0.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
76-
1.
0.
0.
1.
1.
1.
0.
1.02
50
92
81
24
36
92
25
1.15
1.
0,
2
2
1
5
0
0
8
.06
.32
.24
.25
.39
.36
.44
.40
.38
Peaks
0
34
35
:00
:39
:07
0
RO
.76
0
0
1
-1.02
.90
.87
.06
Peak
0
0:00 RO
34:41
470-472
1
.76
1
-1 .02
.63
0.88
Peak
0.
0.
674.
1.
674.
HpCDE
0.
0.
0.
0.
29
35
93
24
93
<
15
23
49
72
0.21
0.
0.
0,
0
0
0
0
0
0
0
0
0
0
0
1,034
0
1,034
.23
.08
.25
.34
.13
.72
.60
.96
.47
.66
.17
.15
.00
.19
.07
.96
.07
0.15
460.83
460.83
341.73
0.969-1.031
0.000
0.980
333.20 1.000 13C12-HpCDD 678 IS7
1.009
Follows
479.89
216.17
.885-1.115
0.000
0.898
0.908
0.927
0.934
0.942
0.953
0.955
0.959
0.965
0.967
0.988
0.997
1.002 OCDF
1.005
1.012
1.026
0.885-1.115
0.000
554.18 0,999 OCDD
1.012
0.994-1.004
0.000
244.66 1.000 13C12-OCDD
AN
AN
IS8
Column Description "Why" Code Description QC Log Desc.
M_Z -Nominal Ion Mass(es)
..RT. -Retention Time (mtn:ss)
Rat.l -Ratio of M/M+2 Ions
OK
-RO=Ratio Outside Limits
Rel.RT-Relative Retention Time
End of Report
WL-Below Retention Time Window A-Peak Added
WH-Above Retention Time Window
SN-Below signal to Noise Level
-------
17:00 18:00 15:00 20:00 21:00 22:00
FllesS975843 #1-848 Acq:ll-SEP-1997 21:04:32 EI+ Voltage SIS 70S NO±fe:857
05.8987 T:2 BSUB(256,30,-3.0) PKD(9,5,5,0.05\,3428.0,1.00\,r,T) XzpiXPCOS
TRIANGLE LABS Text:I-H23-3 TLIf43085 IW7. TIME - 21:06
ileiS975843 11-848 Aoqtll-SXP-1997 21:04:32 XX+ Voltage SIX 705 Holmei182
03.9016 Ti2 BSUB(256,30r-3.0) PXD(9,5,5,0.05%,728.0,1.OQ\,T,T) XxpiXPCUB
IAHCLX LABS TexttI-M23-3 TLH43085 IW7. TIME - 21i06
00* A1.34X6 A1.65X6
80:
60:
40:
20:
0:
Al.09X6
17:00 18:00 15:00 20:00 21:00 22:00
rilesS975843 #1-848 Acqsll-SEP-1997 21:04:32 EH- Voltage SIX 70S Hoimes436
315.9419 T:2 BSOB(256,30, -3. 0) PKD(9,5,5, 0. 05\,1744. 0,1. 00\,T,T) EzpsEPCUS
TRIANGLE LABS Text:I-M23-3 TLHH3085 ISJ. TIME - 21:05
1001
80:
60:
40:
20:
0:
17:00 18:00 19-00 20:00 21:00
Tile:S975843 #1-848 Acqsll-SEP-1997 21:04:32 Eli- Voltage SIS 70S No±ae:549
317.9389 T:2 BSUB(256r 30,-3.0) PKD(9,5,S, 0. 05\,2196. 0,1. 00\,F, T) EzpsEPCOS
TRIANGLE LABS Text.-I-M23-3 TL1#43085 IKT. TIKE - 21:06
1001 A2.29E7
80J
60:
40:
20:
o:
22s 00
17:00 18:00 15:00 20:00 21:00
rilesS975843 #1-848 Acqsll-SEP-1997 21:04:32 XI+ Voltage SIS 70S
330.9792 T:2 XxpsEPCUS
TRIANGLE LABS TextsI-M23-3 TLH43085 IJTJ. TIME '
80:
60:
40:
20:
o:
rr
rr
T
17:00 18:00 IP.-00 20:00
rilesS975843 tl-848 Acqsll-SEP-1997 21:04:32 EI+ Voltage SIS 70S
375.8364 Ts2 ExpsEPCUS
TRIANGLE LABS T9Xt:I-M23-3 TLH43085 UKT. TIMS -
1001
21:00
22:00
21:06
17s 36
19:14
21:30
18:14
-3.9X5
.3.1X5
.2.3X3
.1.5X5
.7.7X4
0.0X0
Time
A3.84X4 A2.64X4
AS.02X4
4.3X6
3.5X6
2.6X6
.1. 7X6
.8.7X5
0.0X0
Time
.5.8X6
.4.7X6
.3.5X6
.2.3X6
.1.2X6
.0.0X0
Tim
.5.8X6
.4.7X6
.3.5X6
.2.3X6
.1.2X6
0.0X0
T±m,
-5.9X3
'-4. 8X3
.3.6X3
.2.4X3
22133
1:02
17:00
la'iOO
19\00
20\00
22:04 il I :
M-A-Juu/MLj*:
21 i 00
22^00
'.1.2X3
0.0X0
T±i
224
-------
'll»iS975843 tl-848 Aoqill-SKP-1997 21,04*32 EI+ Voltage SIX 70S Jfo±f»,186
19.8965 r,2 BSUB(256,30,-3.0) PKD(7,5,3,0.05\,744.0,1.00\,r,T) ExptXPCUS
TRIANGLE LABS T»xt,I-M23-3 TLIt43085 JJU. TIME -
A8.69E4
19 1 00 20 1 00 21,00
r±lt,S975843 11-848 Aoqtll-SEP-1997 21,04,32 EH- Voltage SI* 70S Noif*,304
321.8936 Ti2 BSOB(256, 30, -3.0) PKD(7, S, 3, 0 .05\, 1216.0,1 .00\,f,T) XxptXPCOS
TRIANGLE LABS T»xt, I-M23-3 TLH4308S OUT. TIME - 21t06
A3. 71X4
19,00 20,00 21,00
Fila,S975B43 tl-848 Acqsll-SEP-1997 21,04,32 EH- Voltage SIR 70S Noise:987
331.9368 r,2 BSUB(256, 30, -3. 0) PXD(7,S, 3, 0. 05\,3948. 0,1.00\,r, T) ExptEPCUS
TRIANGLE LABS Text:I-M23-3 TLIt43085 IKJ. TIME - 21:05
100* A2.16E7
\*'
22,00
22100
601
40:
20:.
0.
.34E7
19 i 00 20,00 21,00
F±le,S97S843 tl-848 Acqtll-SEP-1997 21:04,32 EI+ Voltage SIX 70S Noiee:109
333.9338 T:2 BSOB(256, 30, -3. 0) PXD( 7,5,3, 0. 05\,436. 0,1. 00\,T,T) ExptEPCOS
TS I ANGLE LABS TextiI-H23-3 TLH43085 IW. TIME -
1001
22,00
BO:
40:
20:
1.67E7
19,00 20,00 21,00 22,00
riletS975843 tl-848 Acqtll-SEP-1997 21,04:32 EH- Voltage SIR 70S No±»e,139
327.8847 1,2 BSUB(256,30,-3.0) PKD(7,5,3,0.05%,555.0,1.00\,r,T) Exp:EPCUS
TRIANGLE LABS Text,I-M23-3 TLIt4308S IKT. TIME - 21,06
1003
80:
60l
40:
20:
19:00 20:00 21,00
rile,S975843 tl-848 Acqtll-SEP-1997 21,04,32 EH- Voltage SIX 70S
330.9792 rt2 ElptEPCUS
TRIANGLE LABS Teit.sI-M23-3 TLH43085 IJKT. TIME -
1001
19,26 19,4530,03 20,5 ™>OS 3l!-34
22,00
21,06
22:00
19,00
20,00
21,00
22,00
5.8E6
4.6E6
3.5E6
.2.3X6
1.2E6
.O.OSO
Time
.7.4X6
.5.9E6
.4.5X6
.3. 0X6
.1.5X6
0.0X0
Tim
6.6X6
5.3X6
4.0X6
.2.6X6
.1. 3X6
0.0X0
Tim
22!
-------
rlle:S975843 #1-840 Aoq:ll-SEP-1997 21:04:32 EI+ Voltage SIX 708 Xoiae:18
339.8597 Ti2 BSOB(2S6, 30, -3.0) PKD(7,5,3,0.05\,72.0,1.00\,r,T)
Xlp:ETCOS
TRIANGLE LABS Teit:I-M23-3 ZXI #43085 XKJ. TIME " 21:06
IOCS
80:
60:
40.
20:
0
A7. 4X4
A5.94X4
AA1.87X4
\ XI tSft \
A2.21X4 A3 .75X3 V A A7 67E3 In '
AA/^ vAjtfcjs^-A^ ijt^v*** \j»Vj»jrL u-A-A^I^ * WJ^^A / \ PV " A
'23,00 24:00 25:00
fr07S3*1'lil:4A1.03f4 A6.19X3 1
* il A/ \^J' V^u« t /^/VJL AII ft **- •»- A A>» ^wl y
.3.ir4
.2.514
.1 . 8X4
.1.2X4
.6.2X3
O.O*O
25: 00 T±me
rile:S975843 #1-848 Acqill-SEP-1997 21:04:32 EH- Voltage SIX 70S Holme: 26
341.8567 r*2 BSUB(256, 30, -3.0) PO>( 7,5, 3, 0 .05\,104 .0,1.00\,F,T) XxpiSPCOS
TRIANGLE LABS TextiI-M23-3 TLH43085 IKJ. TIME - 21:06
1001
80J
60J
,
40:
20:
o:
A3.26E4
1 MI iQfA A2.22X4
jT"-f«3 «.««ft A1T4 h\i*9T
JLJ LjuJH_^v_ _ AAX\JWW IMAAM /v'^jWAiAywl
2J:00 ' 24:00 25:00
-1.3X4
Al . 67E4
"A-«y|/|A ,A "'fflJii^
.1 . 0X4
.7.8X3
.5.2X3
.2.6X3
O.OTO
26 1 00 Time
rlle:S975843 #1-848 Acq:ll-S£P-1997 21:04:32 EH- Voltage SIX 70S «oiae:29
351.9000 T:2 BSUB(2S6, 30, -3. 0) PKD(7,5, 3, 0. 05\,116. 0,1. 00\,r,T) Exp:EPCOS
TRIANGLE LABS Text:I-M23-3 TLI»4308S IKT. TIME - 21:06
100]
80:
60:
40:
20:
o:
A1.B7X7
J \
2J:00 24:00 25:00
r6.1X6
Al.
J
65JJ7
t
'-4.8X6
'.3 . 6X6
'-2.4X6
.1.2X6
'• 0 . OEO
261-00 Time
rile:S975843 #1-848 Acq:ll-SEP-1997 21:04:32 EI+ Voltage SIX 70S Soiae:31
353.8970 T:2 BSUB(256,30, -3 .0) PKD(7,5, 3, 0. 05%,124. 0,1. 00 \,T, T) ExpsEPCUS
TRIANGLE LABS Text:I-M23-3 TLH4308S IWJ. TIME - 21:06
10 OS
80:
60:
401
201
OJ
A1.25E7
I
f\
1 \
23:00 '24:00 ' '25:00
^4.0X6
A1.13E7
J
^
.3.2E6
.2.4X6
.1 . 6X6
.8.0X5
26:00 Time
rile:S975S43 #1-848 Acq:ll-SEP-1997 21:04:32 EI+ Voltage SIX 70S
330.9792 T:2 Exp:XPCUS
TRIANGLE LASS Text: I-M23-3 TLH43085 IlKT. TIME - 21:06
1001
80.
60.
40.
20.
0
24:23
' — ^^r^\ 33&^rJ~^\r**^ r\ C"^
^ \r^ ^ \ v
V V
23:00 24:00 ' 25:00
25:25 26s 14 26:36
A x^^v fv -/\- /^w\ /\ rW^~^S
^^^^/M/v^
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26-00
.5.7X6
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.0.0X0
rile:S975843 #1-848 Acq:ll-SXP-1997 21:04:32 EH- Voltage SIX 70S
409.7974 7:2 EipiEPCDS
TRIANGLE LABS Text:I-M23-3 TLH43085 IW. TIME - 21:06
100}
80.
60.
40.
20.
0.
25
23:42
33s" 24,43
H 24:11 • I
f^lL. ,. -jJlJuJL ^f^-A^^L Jljv^vu
08 C3.5E3
-A i ^ L«>
If o &E3
f
£.2.11:3
|
E.1.4JTJ
it
25,37 fc5-58 atf)lfl a«,36 J I7'1"
-*AAA>wJLA_A\A — A^x^_A«^/MVE rt «_.,
23:00 24:00 25:00 26:00 Tl*e
226
-------
24:00 25:00 26:00
ile,S975843 tl-848 Acytll-SXP-1997 21,04,32 EH- Voltage SIS 70S Noil*:25
57.8516 F:2 BSU3(256,30,-3.0) PKD(7,5,3,0.05\,100.0,1.00\,T,T) ExptEPCUS
TSIAKGLX LABS T*xt:I-M23-3 TLH43085 IKT. TIME - 21:06
003k Al. 7X4
.l*iS97584J #1-848 Aoq:ll-SSP-1997 21:0*lJJ 11+ Voltage SIX 70S MOlf*:lJ9
55.8546 T>2 BSUB(356,30,-3.0) PH>(7,5,3,0.05\,556.0,1.00\,r,T) XxpiXPCUS
IAHGLX LABS T*xt:I-M23-3 TLIt43085 JW. TINT - 21:06
001 AS. 3 2X4
so:
24:00 25:00 26:00
•±le:S975843 U-848 Acq:ll-SEP-1997 21:04:32 EI+ Voltage SIS 70S No±ae:320
67.8949 t:2 BSUB(256,30,-3.0) PKD(7,5,3,0.05\,1280.0,1.00\,r,T) Exp:EPCUS
TBIANGLE LABS Text:I-M23-3 TLIt430SS IKT. TIME - 21:06
001 Al 07E7
80.
so:
40.
20:
19.16E5
/\
24:00 25:00 20:00
rlle:S975843 #1-848 Acq:ll-SEP-1997 21:04:33 EI+ Voltage SIX 70S Noise-.35
369.8919 Ts2 BSUB(256,30, -3. 0) PKD(7,5,3, 0. OS\,140. 0,1. 00\,T, T) Exp:EPCOS
TRIANGLE LABS Teit:I-M23-3 TLI043085 IJKT. TIME - 21:06
1003
so:
50.
40:
20.
A6
B9E6
\S. 74ES
TV
24,00 25:00 26:00
File:3975843 #1-848 Acq:ll-SEP-1997 21:04:32 £1+ Voltage SIR 70S
330.9792 T:2 ExptEPCUS
TRIANGLE LABS Text:I-M23-3 TLH43085 IJKT. TIMX - 21:06
25125
1003
801
so;
40.
20:
0.
24:23
34,59 35,13
2400
25tOO
26,00
-3.4E6
-2.0E6
.1.4X6
.6.8X5
O.OEO
Time
2.2X6
.1. 8E6
.1.3X6
.8.8X5
-4.4E5
,0.0X0
Time
.7.1X6
.5.7X6
.4.3X6
'.2.8X6
-1.4X6
.0.0X0
22
-------
f±l», 3975843 11-405 Aoqill-SXP-1997 21i04i32 XI+ Voltage SIX 70S Holm* t 194
373.8308 fi3 BSUB<256, 30, -3.0) PXD(7,3,3r0.05\,776.0,1.00\,r,T) XxptOCOS
TXIANGLX LABS Text:I-M23-3 TLIt430S5 IW. TIM* - 21i06
1005
40:
60:
40.
20.
A6.89X4
A3.59X4,
AS. 94X4,
A1.53X4
4
A4.64X4
AS. 79X3
A6.98X3*?-5"3
.02X3 R i Jt f#3.38X3
AA/*V-JM«Jt .A-—:
0.0X0
28i24 ' 28:36 28'i48 29^00 29>12 29t24 29i36 29', 48 30iOO 30tl2 Tim,
.2.4X4
'•.1.9X4
.1.4X4
.9.5X3
.4.8X3
27:2< 27i36
rlle:S975843 tl-405 Acqill-SXP-1997 21:04:32 XI+ Voltage SIX 70S Noime:190
375.8178 T:3 BSUB(256,30,-3.0) PXB(7,5,3,0.05\,760.0,1.00\,r,T) XzptXPCOS
TXIANGLX LABS \Text:I-M23-3 TLIt43085 IKT. TIMX - 21:0*
A4.91E4
27\12 27\24' 27:36 27':48 28:00 28': 12 28':24 28\36 2B\48 29:00 29112 29:24 29:36 29:48 30:00 30:12 Time
rile:S975843 fl-405 Acq:ll-SEP-1997 21:04:32 EI+ Voltagre SIX 70S Holme:377
383.8639 T:3 BSUB(256,30,-3. 0) PKD(7,5,3, 0. 05\,1508.0,1. 00*,r,T) Exp:XPCUS
TRIANGLE LABS Text:I-M23-3 TLH43085 HKT. TIMX -
A7.19X6 *7 36E6
lOOi
80:
so:
40:
20:
o.
A4.74X6
.2.3X6
-.1. 8X6
'-.1.4X6
_5.1X5
.4.6X5
.0.0X0
27:12' 27:24'27\36~ 27,46 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12 Tim
r±le:S975843 tl-405 Acq:ll-SEP-1997 21:04:32 EH- Voltage SIX 70S Woiaa:1172
385.8610 T:3 BSUB(256,30, -3 . 0) PKD<7, 5,3, 0. 051,4688. 0,1. 00\,T, T) Xxp:EPCVS
TRIANGLE LABS Text:I-M23-3 TLI#43085 IKT. TIME - 21:06
1003
80:
60:
40.
20.
o:
27:12 27:24 27:36 27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12
File:S975843 tl-405 Acq:ll-SEP-1997 21:04:32 EI+ Voltage SIR 70S
392.9760 T:3 ExpsEPCCS
TRIANGLE LABS Text:I-M23-3 TLIt43085 IKJ. TIME
100J| 27:22 27f.?7 2JLL05 38JJ-7 28:55
60X7
Al
54X7
A9.88E6
.4.7X6
L3.7E6
.2.8X6
.1.9X6
.9.3X5
0.0X0
29:24 29:36 29:48 30:00 30,12 Tim
21:06
29:27
_.3 . 7X6
O.OEO
27:12 27:24 27:36 27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12
F±le:S975S43 tl-405 Acq:ll-SEP-1997 21:04:32 EI+ Voltage SIR 70S
445.7555 F:3 Exp:EPCUS
TRIANGLE LABS Text:I-M23-3 TLIt43085 IKT. TIME - 21:06
LO.OJTO
27:12 27:24 27:36 27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12 Tim
228
-------
riJ.*,SS75B1J tl-405 Aoqtll-SXP-1997 21tQ4t32 Mir Voltage SIM 70S HOiaei74
389.8156 Ti3 aSU*(256,30,-3.0) PKD(7, 5,3,0.05\,296.0,1.00\,r,T) Xxp,XPCUS
TRIAHGLX LABS Text,I-M23-3 TLH4308S IKT. TIM* ' 21*06
A6.04X4
(V
.1.7X4
37:48 23,00 28:12 28,24 28s 36 28s 48 29,00 29,12 29,24 29', 36 29,48
Tile:S975843 11-405 Acqtll-SXP-1997 21:04,32 XII- Voltage SIX 70S Holae:88
391.8127 Ti3 BSOB(256,30,-3.0) PXD(7,5,3,0.05\,352.0,1.00\,r,T> XzptXTCUS
TRIANGLE LABS Text:I-M23-3 TLIt43085 IXT. TIMX - 21,06
1001 A4.49E4
so:
27:48 38:00 28,12 28:24 28,36 38,48 39,00 29,12 29,24 29,36 29:48
rlle,S975B43 tl-405 Acqtll-SEP-1997 21,04,32 EI+ Voltage SIR 70S No±ae,471
401.8558 r,3 BSUB(356,30,-3.0) PKD( 7, 5, 3, 0. 05\,1884. 0,1. 00%, F, T) KxptEPCVS
TRIANGLE LASS Text:I-M23-3 TLIt43085 IKT. TIME - 21:06
1004 A1.5.3E7
so:
60.
40:
20.
A8.84E6
0.0X0
T±mt
.3. 8X6
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.2.3X6
.1. 5E6
.7.7X5
27,48 28:00 28', 12 28:24 28,36 28:48 29:00 29', 12 29:24 29,36 29:48
rile:S975843 #1-405 Aoqtll-SEP-1997 21,04:32 EI+ Voltage SIR 70S Hoiaf.305
403.8529 r,3 BSUS(2S6,30,-3.0) PKD(7,5,3,0.05\,1220.0,1.00\,T,T) ExpsEPCOS
TRIANGLE LABS TextsI-H23-3 TLH43085 IKJ. TIME - 21:06
1004 A1.25E7
.0.0X0
Tine
80J
so:
40:
20:
A6.75E6
-3.2X6
.2.6X6
.1.9X6
.1.3X6
.6.4X5
27\48 ' '28t6o 28,12 28:24 28:36 28,48 29,00 29il2 29:24 29:36 39,48
File:3975843 tl-405 Acqill-SXP-1997 21,04:32 XI+ Voltage SIR 70S
392.9760 T,3 XxptXPCUS
TRIAHSLX LABS T»xttI-H23-3 TLI»43085 IXJ. TIMX - 21:05
100J
80.
,0.0£0
T±me
0.0X0
'27l:48 ' '28i00 28:12 28:24 28:36 28:48 29tOO 29tl2 29,24 29:36 29:48
229
-------
il*:S975843 tl-430 Acqtll-SXP-1997 21:04:32 11+ Voltage SIX 70S Moi*et452
07.7818 r>4 BSDB(2S6,30,-3.0) PKD(7,5,3,0.05\,1808.0,1.00\,T,T) XxpiXPCUS
TXIANGLX LABS TexttI-M23-3 TLH43085 ZK7. TIMX - Hi06
004 A3.16X5
ao:
60:
40:
201
31iOO 31:12 31:24 31:36 31:48 32:00 32:12 32:24 32:36
lletS975843 tl-430 Acqtll-SXP-1997 21:04:32 XI+ Voltage SIX 70S Noi*e:125
09.7789 Ts4 BSOB(256,30,-3.0) PKD(7,5,3,0.05\,500.0r1.00\,r,T) XxpiXPCUS
TMIAXGLX LABS Text:I-M23-3 TLIt43085 IJKT. TIMX - 21s 06
004 A6.68E4
80:
60:
A6.84E4
32:48
40:
20.
A1.69S4
A1.55E4 A6.66E3
**
31,00 31:12 31:24 31:36 31:48 32:00 32:12 32:24 32,36
f±10:3975843 tl-430 Acqsll-SEP-1997 21s04s32 EH- Voltage SIX 70S Noiae:313
17.8253 T:4 BSUB(256r30,-3.0) PKD(7,5,3,0.OS\,1252.0,1.00\,T,T) SxpsEPCUS
TRIANGLE LABS Text:I-H23-3 TLH4308S INJ. TIME - 21:06
1004 A2.58E6
ao:
60:
40- I \ A1.43E6
20:
3248
31:00 31:12 31:24 31:36 31:48 32:00 32:12 32:24
rilesS975843 tl-430 Acqsll-SEP-1997 21:04:32 EI+ Voltage SIS 70S Noiae:135
419.8220 r:4 BSUB(256, 30, -3. 0) PKD(7, 5,3, 0. 05\,540. 0,1. 00\,T,T) ExpsEPCUS
TRIANGLE LABS Text:I-M23-3 TLIt43085 HKT. TIME " 21:06
1004 A6.14E6
80:
60:
40:
20:
3236
3248
A3.65X6
31 00 31:12 31:24 31:36 31:48 32:00 32:12
rilesS975843 tl-430 Acqsll-SEP-1997 21:04:32 EI+ Voltage SIX 70S
430.9729 r:4 ExpsEPCUS
TRIANGLE LABS TextsI-M23-3 TLIt43085 IJTJ. TIME -
1004
*w ^ •* i - no .~.*,* . — £_—•—_ . . .. 4r.«tn . . ,..
80J
60:
40:
20:
3224
32:36
21s 06
.1.1X5
-8.8X4
-6.6X4
.4.4X4
.2.2X4
0.0X0
Tim,
^.2.4X4
.1.9X4
.1.4X4
'.9.5X3
-4.7X3
LO.OEO
Tim,
-6.8ES
'-5.5X5
'-4.1X5
"-2.7XS
.1.4X5
0.0X0
Tim:
^1. SE6
-.1.2X6
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'-..6.0X5
Lj.0X5
32:48
LO.0X0
Tim
0:
^2.4E6
-1.9E6
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-.4.8X5
31-00 31:12 31:24 31:36 31,48 32:00 32,12 32:24
rile:S975843 tl-430 Acqsll-SEP-1997 21:04:32 EI+ Voltage SIX 70S
479.7165 Ts4 ExpsXPCUS
TRIANGLE LABS TextsI-M23-3 TLH43085 INJ. TIME - 21:06
1004 31:26
3236
3248
O.OEO
Tim
31:00
3l:12
32t36
32t48
Tim
230
-------
41-4J0 AoqiJ.l-SfP-1997 21,04,32 XI + VOJ.C*ye SIX 70S HoiM»lllJ
423.7766 T>4 3303(256,30,-3.0) tXD(7,5,3,0.051,452.0,1.00\,r,T) txptXTCOS
TXIAHSLX LA33 T«xtiJ-«3-J TU443085 XK7. TZNT - 2it06
1001 A1.88E5
31il8 31:24 31i30 3l',36 31,42 31,48 31tS4 32tOO 32,06 32,12 32,18 32,24
rile,S975843 tl-430 Acqill-SEP-1997 21,04,32 XI* Voltfye SIX 70S Half*,83
425.7737 Tit 3303(256,30,-3.0) PKV(7,5,3,0.05\,332.0,1.00\,r,T) ExptEPCUS
TXIAlfSLS LABS Text:I-M23-3 TLH43085 INJ. TIME - 21,06
1001 A1.82E5
33,30
80.
eo:
40.
20:
A1.19ES
A7.47X3
A A
A3.07E3
LJ. 3E4
-2.5E4
.J..7E4
.8.3E3
31:18 31,24 31,30 31,36 31:42 31:48 31:54 32,00 32,06 32,12 32,18 32:24
File:S975843 tl-430 Acq:ll-SEP-1997 21,04:32 EI+ Voltage SIX 70S No±ae,445
435.8169 r,4 BSUB(256,30,-3.0) PKD(7,5,3,0.05\,1780.0,1.00\,f,T) ExpiEPCDS
TXIANGLE LABS TeJCt,I-M23-3 TLIf43085 IXT. TIKE - 21:06
1001 A3.J2E6
so:
so:
40.
20:
.O.OEO
32', 30 Time
5.5E5
.4.4E5
.3.3E5
'.2.2E5
11. 1E5
3E6
31,18 31,24 31,30 31:36 31,42 31,48 31,54 32:00 32:06 32,12
rila,S975843 tl-430 Acgill-SEP-1997 21,04,32 EH- Voltage SIX 70S NOiae:70
437.8140 T:4 BSOB(256,30,-3.0) PKD(7,5,3,0.OS\,280.0,1.00\,r,T) ExpiEPCDS
TXIAKSLE LABS Text,I-M23-3 TLIt43085 IJKT. TIME - 21:05
1004 A3.
so:
eo:
40:
20:
32:IB 32,24
.O.OEO
32:30 Time
.5. 6E5
-4.5E5
"-3.4E5
.2.2E5
.1.1E5
JlilS 3l'i24 3l':30 31:36 3l',42 3l',48 31,54 32,00 32:06 32,12 32,18 32,24
r±le,S975843 tl-430 Acqsll-SEP-1997 21:04,32 E1+ Voltag* SIX 70S
430.9729 r,4 EfptEPCUS
TXIANSLE LABS Text,I-H23-3 TLH4308S TOT. TIME - 21,06
1003, 31ji33 ,,.-,„
31,49 2t^° —_ ,,.,„ 32>20
soJ
60.
40.
20.
.O.OEO
32,30 Time
.2.4X6
".1.9E6
-1.4E6
-P.5JC5
.4.8E5
O.OEO
'31*24 ' '3'l:30 ' '31t36 ' '31\42 ' '31,48 ' '31,54 ' '32\00 ' '32\06 32tl2 32tl8 32t24 32i30 Time
231
-------
ro
-------
nj.»,S975843 tl-430 Actj:ll-SEP-1997 21104132 XI+ VOJLCAgm SIX 70S Nol**:43
457.7377 Tt4 BSU*(256,30,-3.0) PXD(7,5,3,0.OS\,172.0,1.00\,r,T) XxptXtCOS
TRIANGLE LABS TmxttI-M23-3 TLH43085 HKT. TIM* - 21tO«
1001
80.
34t30 34i36 34:42 34,48 34:54
r±lftSS75843 91-430 Acqtll-SEP-1997 21:04:32 XI+ Voltmgm SIX 70S Ko±f»:48
459.7348 Ttt BSUB(256,30,-3.0) PXB(7,5,3,0.05\,192.0,1.00\,T,T) XxptEPCOS
TRIANGLE LASS T*xt:I-M23-3 TLH43085 IJKT. TIMS - 21:06
1001 AS.
35100
34:30 34:36 34,42 34,48 34:54
rile,S975843 tl-430 Acq:ll-SEP-1997 21:04,32 £1+ Volts ye SIR 70S JfOim«:40
471.7750 T,4 BSOS(256,30,-3.0) PKD(7,5,3,0.05\,160.0,1.00\,f,T) ExpiSPCUS
TKI ANGLE LASS Text: I-M23-3 TLH43085 IKJ. TIME - 21:06
34:30 34,36 34:42 34:48 34,54
r±le>S975843 tl-430 Acqsll-SEP-1997 21:04:32 EI+ Voltage SIX 70S Xoiee:64
469.7779 T,4 BSUB(256,30,-3.0) PKD(7,5,3,0.05\,256.0,1.00\,F,T) ExpiEPCUS
TRIANGLE LABS Text:I-M23-3 TLI943085 INJ. TIME ' 21:06
100S, A2.J.6E6
so:
60.
40:
20:
35,00
35,00
1001
so:
A2.45E6
34:30 34:36 34,42 34:48 34:54
rile:S97S843 11-430 Acqtll-SEP-1997 21:04:32 EI+ Voltage SIS 70S
430.9729 T:4 ZxpiEPCUS
TRIANGLE LABS Toxt:I-M23-3 TLH43085 IJKT. TIME -
35:00
21:06
ion
so:
«o:
40.
20.
0.
34:30
34,42
33 Of
.4.9*3
'.4.0X5
-3.0X3
.2.0E5
-9. 9E4
.O.OEO
35 06 Tim.
-2.1E5
.1. 7E5
-1.3E5
.8.5E4
-4.2S4
.O.OEO
35 06 T±m
35
.1. 0X5
-1.3E5
'.9.0X4
14.5E4
.O.OEO
06 TiM
.2.7X6
'.2.1X6
'.1. 6X6
.1.1X6
^5.3X5
34130
34:36
34:42
34,48
34,54
35100
.0.0X0
35 06 Urn
233
-------
ChameL I 338,9792 Peak top
Height 1,51 vdts Span 299 ppi
Systei file naie
Data file naie
Resolution
Group nunber
lonlzatlon node
Switching
Ref, lasses 292,
fl 293 J 331
B 304
C 386
0 318
E 318
F 329
G 322
H 328
I 331
K 332
* 349
N 342
0 352
P 354
Q 356
R 358
EPCUS
fl=S975843
2
El*
VOLTflGE
416,9768
S 368
T 379
U 376
V 418
Ref, aass 416.9768 Peak top
Height ,27 volts Span 298 ppi
234
-------
il«:89738i3 11-848'Acq:ll-SEP-1997 21:04:32 EH- Voltage SIR 70S
03.f016 P:2 Exp:EPCUS
ample Text:I-M23-3 TLI#43085
.00
INJ. TIME = 21:06 File Text:I-M23-3 TLI#4»
..1.9E4
22:00
O.OEO
23:00 Time
17:00 18100 19iOO 20iOO 21:00
file:S975843 #1-848 Acq:ll-SEP-1997 21:04:32 EI+ Voltage SIR 70S
:05.8987 F:2 Exp:EPCUS
.ample Text:I-M23-3 TLI#43085 INJ. TIME = 21:06 File Text:I-M23-3 TLI#4»
21:38 22:19
22:05
1 1 1 1 1 1 1 r 1 1 1 1 1 1 1 1 1 1
19:00 20:00 21:00 22:00 23:00 Time
i-ile:S975843 fl-848 Acq:ll-SEP-1997 21:04:32 EI+ Voltage SIR 70S
115.9419 F:2 Exp:EPCUS
Jample Text:I-M23-3 TLItt43085 INJ. TIME = 21:06 File Text:I-M23-3 TLI#4»
LOOi 20;24 4.3E6
80^
60J
40J
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21:00 22:00
L3.5E6
L2.6E6
L1.7E6
L8.7E5
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23 :00 Time
-------
ile:S975843 #1-848 Acq:ll-SEP-1997 21:04:32 EI+ Voltage SIR 70S
03.9016 F:2 Exp:EPCUS
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00%
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1 - 1 - 1
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1 - 1 - 1 - 1 - 1
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05.8987 F:2 Exp:EPCUS
22:00
1—'—r
23:00
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60 J
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23:00
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21:00
22:00
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-------
ile:S975813 #1-405 Acq:ll-SEP-1997 21:04:32 EI+ Voltage SIR 70S
73.8208 F:3 Exp:BPCUS
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75.8178 F:3 Exp.-EPCUS
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83.8639 F:3 Exp:EPCUS
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00* 28:22 28;59
30:24
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Time
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60J
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L1.8E6
L1.4E6
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28 00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12 30:24
O.OEO
Time
-------
TLI Project: 43085
Client Sample: I-M23-3
Method 23 TCDD/TCDF Analysis (DB-225)
Analysis File: P973854
Client Project:
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
Analytes •:'•"•' ..•'.. •"•
S413-004
M23Train
181-55-7ABD
1.000
n/a
DB-225
•v^l^;--./-r: Amt
Date Received:
Date Extracted:
Date Analyzed:
Dilution Factor:
Blank File:
Analyst:
(ng) Dt
09/03/97
09/04/97
09/12/97
n/a
P973852
ML
EMPC
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
Ratio
SPC2NF04
PF22206
P973843
n/a
n/a
n/a
JTT £faos
2,3,7,8-TCDF
ND
0.03
Internal Standard
Amt.;(hg)
QC Limits -:' n • HRatlit>-
13C,,-2,3.7,8-TCDF
2.2
53.9
40%-130%
0.74
20:42
Recovery Stendafd
13C12-1,2,3,4-TCDD
0.80
19:45
Data Reviewer.
i t i -L_Ll
09/18/97
Page 1 of 1
ONF.PSR Y2.00. LARS 6.10.04
Triangle Laboratories, Inc.®
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 15:53 09/18/97
238
-------
Initial
..Date..
Data Review By:
Calculated Noise Area: 1.29
The Total Area for each peak with an ion abundance ratio outside
ratio limits has been recalculated according to method requirements.
Page No.
09/18/97
Listing of P973854B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK .Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
TCDF
304-306
304-306
0.65-0.89
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
ML
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
0
0:
17:
19:
19:
20:
20:
20:
20
21
21
22
22
00
36
26
33
13
:21
:43
:57
:37
:45
:14
:25
RO
RO
RO
RO
RO
RO
RO
0.
0.
0.
0.
0.
0,
0
1
1
0
0
0
74
56
47
29
.50
.83
.66
.45
.03
.69
.27
.77
Peaks
1.
0.
1.
0.
0.
1.
4.
1.
0.
1.
0.
58
80
70
57
53
65
48
31
69
.62
,67
0.94
0
.00
0.786-1.096
0.000
0.850
0.939
0.944
0.977
0.983
1.001 2378-TCDF
1.012
1.044
1.051
1.074
1.083
13C12-TCDF
316-318
316-318
0.65-0.89
DC NL
DC SN
0:00 RO
20:42
21:10 RO
Peak
1.04
0.74
1.25
2.00
479.31
0.50
479.31
203.80
0.952-1.048
0.000
275.51 1.000 13C12-2378-TCDF ISO
1.023
Above: TCDF / TCDD Follows
13C12-TCDD
332-334
332-334
0.65-
DC
DC
DC
DC
DC
NL
SN
SN
SN
SN
2
0:
18:
19:
19:
20
21
21
00
:27
31
45
:24
:03
:11
RO
RO
RO
RO
RO
1.
0
0.
0
0
1
2
•0.89
45
.52
.80
.80
.62
.44
.44
Peaks
2.
2.
356.
640.
3,
0
0
997
04
37
36
.64
.36
.69
.32
.00
158.38
285.36
0.897-1.103
0.000
0.945
197.98 1.000 13C12-2378-TCDD IS1
355.28 1.012 13C12-1234-TCDD RSI
1.045
1.079
1.085
Column Description.
"Why" Code Description QC Log Desc.
M_Z -Nominal Ion Hassles)
..RT. -Retention Time (mm:ss)
Rat.l -Ratio of M/M+2 Ions
OK -RO=Ratio Outside Limits
Rel.RT-Relative Retention Time
End of Report
WL-Below Retention Time Window A-Peak Added
WH-Above Retention Time Window
SN-Below signal to Noise Level
-------
ro
.£*
o
a to »ovj>-.Oio
-------
ULuiPS7j854 #1-755 Acq>ll-SEP-1997 19:51,06 fir VoltAg* SIM TOP NOlfflJlo
03.9016 BSUB(2S6,30,-3.0) PKD(5,3,1,0.10\,1344.0,0.00\,T,T) Exp:DB225
TXIAHGLX LABS TtxttI-H23-3 TU143085
00\ Al. 78X4
17100 IttOO 19100 20,00 21,00
ile,P9738S4 tl-755 Aoq,12-SEP-1997 19,51,06 EI+ VoltMfff SIX 70P No±f»:453
05.8987 BSOB(256,30,-3.0) PXD(5,3,1,0.10\,1812.0,0.00\,r,r) X*p,DB225
TRIANGLE LABS TextsI-M23-3 TLH43085
A1.57E4 A2.70X4
22100
17:00 18:00 19:00 30': 00 21': 00
F±le:P973854 #1-755 Acgsl2-SEP-1997 19,51:06 EH- Voltage SIS 70P KO±ae:583
15.9419 BSUB(256,30,-3.0) PKD(5,3,1,0.10\,2332.0,0.00%,T,F) Exp:DB225
TRIANGLE LABS Text.!I-M23-3 TLI#43085
100\ A2.04E6
801
so:
401
201
22:00
17:00 18,00 19,00 20:00 21:00
rile:P973854 #1-755 Acq,12-SEP-1997 19:51:06 EI+ Voltage SIX TOP Noiae:566
317.9389 BSUB(256,30,-3.0) PKD(S,3,1,0.10\,2264.0,0.00\,T,T) Exp,DB225
TRIANGLE LABS Text:I-M23-3 TLH4308S
10 OS, A2.76E6
80.
60.
40.
201
0.
22:00
17:00 18:00 19:00 20:00 21:00
rile:P9738S4 tl-755 Acqil2-SEP-1997 19:51:06 EI+ Voltage SIX 70P
375.8364 Exp:DB22S
TRIANGLE LABS Text:I-M23-3 TLH43085
1004
17tOO
18iOO
19,00
20100
21:00
32100
6.1E5
4.9X5
3.7E5
.2.SE5
.1.2X5
0.0X0
Tim
7.SE5
.6.2X5
.4.7X5
.3.1X5
;.!. 6X5
.0.0X0
T±a
21:53
20:47 21:15 al-'°
241
-------
20.
18:00 19:00 20:00 21:00
ile:P973854 #1-755 Acqtl2-SKP-1997 19:51:06 XI* Voltage SIX 70P Noil*:501
21.8936 BSUB(256,30,-3.0) PKD(5,3,1, 0.10\,2004.0, 0. 00\,r,F) Elp:DB225
TRIANGLE LABS TextiI-H23-3 TLH43085
001
tl-755 AOIJIH-BKP-i997 19151:06 fl+ VOJ.Cage 31* 70P W>A*«f
9.8965 BSUB(256,30,-3.0) PXD(5,3,l,0.10\,1612.0,0.00*,r,r) Xxp:DB225
TAMCU LABS TfXt:I-M33-3 TLH43085
18', 00 19:00 20:00 21:00
File:P973854 #1-755 Acq:12-SEP-1997 19:51:06 EH- Voltage SIR 70P SOisai523
327.8847 BSUB(256,30,-3.0) PKD(5,3,1,0.10\,2092.0,0.00\,r,T) Exp:DB225
TRIANGLE LABS Text:I-H23-3 TLH43085
1001 A3.14E6
801
601
40:
20:
18:00 19:00 20:00 21:00
rile:P973854 #1-755 Acq:12-SEP-1997 19:51:06 EH- Voltage SIR 70P Noises S3 6
331.9368 BSUB(256,30,-3.0) PKD( 5, 3,1, 0.10%, 3344 . 0, 0. 00\,f,F) Exp:DB225
TRIANGLE LABS Text:I-M23-3 TLI143085
1001 A2.85E6
80.
60.
401
20.
A1.58E
18sOO 19:00 20:00 21:00
rile:P973854 #1-755 Acq:12-SEP-1997 19:51:06 EI+ Voltage SIX 70P Noi*e:577
333.9338 BSUB(256,30,-3.0) PXD(5,3,1,0.101,2308.0,0.00\,T,r) Ezp:DB225
TRIANGLE LABS Text:I-M23-3 TLH43085
1001
80.
60.
40.
20.
0.
A1.98EI
18.00
IPtOO
50iOO
21:00
22100
22:00
22:00
33:00
22,00
a. ar5
7.115
.5.JE5
.3.5E5
.1. 8E5
O.OEO
Tim
8.4X5
6.7E5
.5.0X5
.3.3X5
.1.7X5
.O.OEO
Tim
1. 0X6
8.3X5
.6.2X5
.4.1X5
.2.1X5
0.0X0
Tim
242
-------
lie:P973854 #1-755 Aoq:12-SEP-1997 19:51:06 11+ Voltage SIM 709
03.9016 Exp:DB225
TRIANGLE LABS Text:I-M23-3 TLH43085
30143
...41 1*,,* "I" /I 31'i3
17:45
17(00 18:00 19:00 20:00 21:00
iletP973854 tl-755 Aoj:12-SXP-1997 19:51:06 11+ Voltage SIS 70P
15.9419 Xxp:DB225
TRIANGLE LABS Text:I-M23-3 TLH43085
00* 20i42
80:
sol
40.
20:
0.
17:00 18:00 19:00 20:00 21:00
rlle:P973854 tl-755 Aoq:12-SEP-1997 19:51:06 EI+ Voltage SIR 70P
'19.8965 Exp:DB225
TRIANGLE LABS Text:I-M23-3 TLI#43085
100$
1S,37 17:18 ., ,, 18:35 19:31
22:00
17:00 18:00 19':00 20:00 21:00
F±le:P973854 tl-755 Acq:12-SEP-1997 19:51:06 EI+ Voltage SIR 70P
331.9368 Ezp:DB22S
TRIANGLE LABS Text:I-M23-3 TLHH3085
1001 IS;
22:00
80J
601
40:
20.
ol
19:3
17:00 18,00 19:00 20:00 21:00
rile:P973854 #1-755 Acq:12-SEP-1997 19:51:06 EH- Voltage SIR 70P
292.9825 Eip:DB225
TRIANGLE LABS Text:I-M23-3 TLI#43085
18:3518:58 19:50
22:00
6.2*3
5.0X5
3. 7X5
2.5E5
.1.2ES
.O.OEO
T±m»
100J
80:
60:
40.
20:
0:
17:03
17:43
-r
~r
17:00 18:00 19:00 20:00 21:00
rile:P973854 #1-755 Aog:12-SEP-1997 19:51:06 EH- Voltage SIR 70P
330.9792 Exp:DB225
TRIANGLE LABS Teit:I-M23-3 TLXJ43085
19:5020:14 20:41
'22': 00
8.4E5
6.7E5
5. 1E5
3.4E5
1. 7E5
.O.OEO
Tim
.5.3E6
.4.2E6
.3.2E6
.2.1E6
.1. 1E6
O.OEO
Tim
1003
aol
60:
40:
20:
o:
16i57 17:23
18:33 19:06
-5.7E6
-4.5X6
'.3.4X6
-.2.3X6
-.1.1X6
17:00
18:00
19:00
20100
21:00
22:00
•.O.OEO
T±m
24:
-------
fl:P973854
Ref, tass 292.9885 Peak top
Height .97 volts Span 298 ppi
Systa file naie
Data file naie
ResoUJtlon
Group nuiber
lonlzatum Nde
Switching
Ref. lasses 292.9825,
ft 292.9825
6 363.9816
C 366.8987
D 315.9419
E 317.9389
F 319.8965
6 321.8936
H 327.8847
I 338.9792
J
K
L
I
1
El*
VOLTBGE
388.9781
338.9792
331.9368
333.9338
375.8364
Channel I 338.9792 Peak top
Helgtt .98 volts Span 288 ppi
244
-------
TLI Project: 43085
Client Sample: M23-RB
Method 23 PCDD/PCDF Analysis (a)
Analysis File: S975844
Client Project:
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
S413-004
M23Train
181-55-8ABDE
1.000
n/a
DB-5
Date Received:
Date Extracted:
Date Analyzed:
Dilution Factor:
Blank File:
Analyst:
09/03/97
09/04/97
09/11/97
n/a
S975815
KB
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPX23704
SF56117
S975839
n/a
n/a
n/a
Anafytes
2,3,7,8-TCDD
1,2,3,7,8-PeCDD
1,2,3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
1,2,3,4,6.7,8-HpCDD
1,2,3,4,6,7,8,9-OCDD
2,3,7,8-TCDF
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
1,2,3.4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
1,2,3,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
1,2,3,4,6,7,8,9-OCDF
Totals >^."^-.^
Total TCDD
Total PeCDD
Total HxCDD
Total HpCDD
Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF
Amt (ng}
ND
ND
ND
0.006
0.007
0.03
0.05
ND
ND
EMPC
0.03
0.01
0.01
ND
0.05
EMPC
0.05
•W^^^'-Aiicrt:. (ng)
EMPC
EMPC
0.01
0.04
ND
0.007
0.07
0.07
V 0t EMPO
0.004
0.005
0.005
0.003
0.004
0.005
0.003
0.008
Number DL EMPC
0.007
0.01
2 0.06
2
0.003
1 0.01
5 0.08
3 0.08
ffcrtfo HT Flag*
1.08 29:11
1.41 29:28
1.10 32:04 B_
0.91 34:42 B_
1.27 28:20
1.38 28:27
1.38 28:57
1.13 31:12 iZ
0.86 34:49 B_
Flags
—
Page 1 of 2
X237.PSR vZOO. LARS 6.IO.O
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 15:34 09/1 «9:
24
-------
TLI Project: 43085
Client Sample: M23-RB
Method 23 PCDD/PCDF Analysis (a)
Analysis File: S975844
IntemaVStandards
3C,:-2,3,7,8-TCDF
13C,2-2,3,7,8-TCDD
13C,:-l,2,3,7,8-PeCDF
3C,2-l,2,3,7,8-PeCDD
13C,2-l,2,3,6,7,8-HxCDF
l3C,:-l,2,3,6,7,8-HxCDD
13Cp-l,2,3,4,6,7,8-HpCDF
13C,2-l,2,3,4,6,7,8-HpCDD
13Cp-l,2,3,4,6,7,8,9-OCDD
Surrogate Standards (Type A)
37CL-2,3,7,8-TCDD
13Cp_-2,3,4J,8-PeCDF
13Cp-l,2,3,4,7,8-HxCDF
l3C,2-l,2,3,4,7,8-HxCDD
13CP_-l,2,3,4,7,8,9-HpCDF
Alternate Standards (Type A)
13CP-l,2,3,7,8,9-HxCDF
13C,2-2,3,4,6,7,8-HxCDF
Recovery Standards -:v: :
13C12-1,2,3,4-TCDD
13C,2-l,2,3,7,8,9-HxCDD
Amt {ng)
2.7
2.5
2.7
2.8
3.0
2.8
2.4
2.7
4.8
\AmMng) W
4.2
3.8
3.6
3.5
3.9
Arrit {ng)
3.0
3.2
r;!":n
%R«s0v*y
68.5
61.5
67.5
69.2
75.6
69.2
60.9
66.8
60.2
fefmiovetf
105
95.0
89.0
87.7
97.8
..% Recovery
75.8
79.3
QC Limits
40%- 130%
40%-130%
40%- 130%
40%- 130%
40%- 130%
40%- 1 30%
25%- 130%
25%- 130%
25%- 130%
•QC Limits
70%- 140%
70%-140%
70%- 140%
70%-140%
70%- 140%
QC Limits
40%- 130%
40%- 130%
Ratio
0.75
0.80
1.52
1.54
0.47
1.23
0.42
1.04
0.86
Ratio
1.45
0.47
1.21
0.42
S-.Rati<£|
0.47
0.47
Ratio
0.81
1.20
m
20:18
21:08
24:39
25:48
28:25
29:10
31:11
32:04
34:42
*}- '#r:
21:09
25:26
28:19
29:05
32:25
ftfcif/r
29:40
28:57
«T
20:55
29:27
Flags
; Flags?;;:-
—
^.#ags-v
—
Flags •;.
Data Reviewer
Page 2 of 2
09/18/97
X237.PSR T2.00. LARS 6.10.04
Triangle Laboratories, Inc.®
801 Cap'rtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 15:3409/18/97-
246
-------
Initial
..Date..
Data Review By:
Calculated Noise Area:
1.68
The Total Area for each peak with an ion abundance ratio outside
ratio limits has been recalculated according to method requirements.
Page No.
09/18/97
Listing of S975844B.dbf
Hatched GC Peaks / Ratio
/ Ret. Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak. 1. . Area.Peak.2.. Rel.RT Compound.Name.. ID.
TCDF
304-306
304-306
13C12-TCDF
316-318
316-318
TCDD
320-322
320-322
37C1-TCDD
328
328
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
SN
SN
SN
SN
SN
SN
0
NL
WL
WH
2
NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
WH
0.65-0.89
0:00 RO 0.20
17:33 RO 0.44
13:14 RO 0.38
20:20 0.69
20:55 RO 0.45
21:
21:
45 RO
56 RO
3 .
0.
95
29
Peaks
0:
19:
19:
20:
21:
00
06
50
18
0.
50 RO
65-
0.
0.
0.
0.
1.
0.89
66
74
77
75
43
Peaks
__._ *!
0:
18:
13
:00
:19
:29
18:38
18
19
20
20
20
21
21
21
21
22
22
22
:49
:52
:18
:32
:44
:00
:27
:39
:49
:00
:19
:41
0.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
65-0.89
0
0
0
1
0
1
2
0
1
0
1
0
1
0
.55
.44
.96
.51
.80
.70
.56
.49
.06
.71
.13
.90
.27
.28
0.18
1
.52
1 Peak
DC
NL
0:00
19:33
21:09
2 Peaks
0.67
1.54
2.53
8.37
6.71
1.01
1.61
0.00
2.03
15.71
17.76
5,083.04
9.52
5,100.80
7.74
2,182.80
.818-1.101
0.000
0.865
0.898
1.002 2378-TCDF AN
1.030
1.071
1.080
0.951-1.049
0.000
0.941
10.02 0.977
2,900.24 1.000 13C12-2378-TCDF ISO
1.076
Above: TCDF / TCDD Follows
0.78
1.26
1.59
2.99
2.64
1.24
8.04
0.90
0.85
3.14
0.53
0.89
1.59
0.64
0.69
0.96
8.04
0.13
16.53
3,253.66
3,270.19
11.63
16.53
3,253.66
0.851-1.058
0.000
0.867
0.875
0.882
0.890
0.940
4.54 0.961
0.972
0.981
0.994
1.015
1.024
1.032
1.041
1.056
1.073
0.906-1.094
0.000
0.925
1.001 37C1-TCDD
SUR1
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 15:3409/18/97,
-------
Page No.
09/18/97
Listing of S975844B.db£
Matched GC Peaks / Ratio / Ret. Tin
Compound/
M_Z.... QC-Log Omit Why . .RT. OK Ratio Total.Area... Area.Peak.1. . Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
13C12-TCDD
332-334
332-334
PeCDF
340-342
340-342
13C12-PeCDF
352-354
N
352-354
PeCDD
356-358
K
DC
0.65-0.89
NL 0:00 RO 8.97 0.53
20:55 0.81 5,629.73 2,525.03
21:08 0.80 3,690.72 1,638.66
21:31 RO 0.91 50.46 26.02
21:39 RO 4.09 5.06 11.71
4 Peaks . 9,375.97
1.32-1.78
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
Sit
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
2
NL
5
NL
SN
SN
SN
SN
SN
SN
SN
WH
0:
22:
00
32
23:09
23:
23:
23:
24:
24:
24:
24:
25:
25:
25:
25:
26:
26:
21
32
45
07
27
51
59
08
26
39
48
02
25
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
0.
1.
0.
0.
3 .
1.
1.
1.
0.
0.
0.
1 .
1.
0.
0.
1.
23
23
36
47
36
32
15
08
52
67
37
27
29
28
57
61
Peaks
0:00
23:
24:
24:
24
25
:45
:16
:39
:58
:26
1.
RO
RO
RO
i 1 V»WL>
0.
2.
0.
0.
0.
7.
1.
0.
0.
1.
0.
5.
4.
0.
05
93
15
28
71
91 4.50
04
89
81
73
31
71 3.47
29
16
0.44
3.
13.
.81
.62
32-1.78
0
1
2
1
2
1
Peaks
0
23
23
24
24
25
25
25
25
26
26
:00
:47
-.54
:27
:40
:00
:26
-.36
:59
:16
:36
1 .
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
32
6
0
1
0
4
1
4
0
3
0
1
.33
.55
.05
.52
.09
.45
-1.78
.00
. 97
.31
.74
.04
.85
.92
.15
.93
.46
.20
0
27
.07
.12 16.47
10.63 8.53
4,306
14
3,966
.40 2,594.81
.89 12.18
.39 2,345.63
0.906-1.094
0.000
3,104.70 0.990 13C12-1234-TCDD RSI
2,052.06 1.000 13C12-2378-TCDD IS1
28.51 1.018
2.86 1.024
0.905-1.077
0.
0.
0.
0.
0.
3.41 0.
0.
0.
1.
1.
1.
2.73 1.
1.
1.
1.
000
914
939
947
955
963
978
992
008
014
020
032 23478-PeCDF AN
041
047
056
1.072
0.838-1.162
0.
10.65 0
4.17 0
1,711.59 1
5.84 1
1,620.76 1
.000
.963
.984
.000 13C12-PeCDF 123 IS2
.013
.032 13C12-P6CDF 234 SUR2
8,325.43
! PeCDF / PeCDD Follows --
0
0
3
0
6
3
2
.10
.51
.22
.46
.63 10.51
.93 2.85
.30
0.10
0
1
.71
.17
2.39
0.919
0
0
0
0
2.60 0
1.54 0
0
0
1
1
1
-1.025
. 000
.922
.926
.948
.956
.969
.986
.992
.007
.018
.031
Triangle Laboratories, Inc.® Analytical Services Division
801 Cap'rtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 15:34 09/1
-------
Page No.
09/18/97
Listing of S975844B.dbf
Matched GC Peaks / Ratio / Ret. Tim*
Compound/
M_Z QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak. 1.. Area.Peak.2.. Rel.RT Conpound.
Flags.
356-358
2 Peaks
10.56
13C12-P6CDD
368-370
368-370
HxCDF
374-376
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
2
NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
0:
25:
25:
00
48
56
1.
RO
32-
5.
1.
1.
Peaks
0:
27:
27:
27:
27:
28:
28:
28:
28:
28:
28:
29:
29:
29:
00
20
29
47
56
12
20
27
33
46
57
05
11
25
29:30
29:41
29:46
374-376
13C12-HXCDF
384-386
384-386
HXCDD
390-392
K
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
WH
WH
WH
6
NL
SN
SN
SN
4
NL
SN
SN
29:
:54
30:07
30:10
1.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
1.78
78
54
50
05-1.43
1.
1.
1.
1.
0.
1.
1.
1.
1.
1.
1.
1.
21
42
12
13
61
55
27
38
45
43
38
86
0.87
1.
,31
0.88
2.
0
0
2
0
.16
.94
.32
.60
.90
Peaks
0
27
28
28
28
29
29
29
:00
:28
:19
:25
:57
:08
:40
:52
0.
RO
RO
RO
0.
2,474.
226.
23
64 1,501.04
54 135.79
0.845-1.155
0.000
973.60 1.000 13C12-PeCDD 123
90.75 1.005
IS3
2.701.18
1.
9.
25.
3.
2.
0.
40.
17.
3.
4.
19.
0.
26
35 5.49
07 13.23
86
11
49
31 22.52
72 10.29
05
82
27 11.17
31
0.61
0.37
0.
1,
5.
0
0
0
117
.42
.39
.94 3.29
.16
.94
.33
.66
.43-0.59
0
0
0
0
0
0
0
0
Peaks
0
27
27
28
28
:00
:52
:59
:20
:25
1
RO
RO
RO
RO
.46
.25
.47
.47
.47
.79
.47
.38
2
6
4,097
4,798
4,659
4
3,871
3
17,426
.05-1.43
0
1
3
1
3
.39
.31
.75
.76
.87
0
3
0
33
4
.43
.69
.03 1.310.17
.83 1,538.50
.59 1.491.21
.14
.01 1,235.48
.46
.46
F / HxCDD Follows —
.47
.37
.09
.02 25.89
.23 7.31
0.955-1.051
0.000
3.86 0.962
11.84 0.967
0.978
0.983
0.992
17.79 0.997 123478-HxCDF
7.43 1.001 123678-HxCDF
1.005
1.012
8.10 1.019 234678-HxCDF
1.023
1.027
1.035
1.038
1.045
3.49 1.048
1.052
1.060
1.062
0.859-1.141
0.000
0.967
2,786.86 0.996 13C12-HXCDF 478
3,260.33 1.000 13C12-HXCDF 678
3,168.38 1.019 13C12-HXCDF 234
1.025
2,635.53 1.044 13C12-HXCDF 789
1.051
0.950-1.014
0.000
0.955
0.959
14.74 0.971
1.89 0.974
AN
AN
AN
SUR3
IS4
ALT 2
ALT1
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 15:34 0*18/9:
249
-------
Page No.
09/18/97
Listing of S975844B.dbf
Matched GC Peaks / Ratio / R«t. Time
Compound/'
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.
ID.. Flags.
M
390-392
13C12-HXCDD
402-404
402-404
28:
DC SN 28:
DC SN 28:
DC SN 28:
DC SN 29:
29:
DC SN 29:
29:
DC WH 29;
5 Pe<
DC NL 0
28
29
29
29
4 Pe.
34 RO
42 RO
46 RO
57 RO
04 RO
11
19
28
40 RO
iks
1.
:00 RO
:33
-.05
:10
:27
aks
1
0
0
2
0
1
. 1
1
2
05
1
1
1
1
1
.56
.77
.39
.91
.45
.08
.37
.41
.80
-1.43
.88
.07
.21
.23
.20
- - ah™
11.
0.
0.
5.
0.
5.
0.
6.
4.
61.
0,
6
3,098
3,631
5,271
12,007
j-o - Uvrrv
80
74
25
26
94
95
64
71
88
71
.74
.76
.27
.09
.85
.97
n / UT^
8.21 5.27
3.09 2.86
3.92 2.79
0.
3.49 3.27
1,695.46 1,402.31
2.004.04 1,627.05
2.875.69 2,396.16
0
0
0
0
0
1
1
1
1
966
0
0
0
1
1
.979
.984
.986
.993
.997 123478-HXCDD
.001 123678-HXCDD
.005
.010 123789-HXCDD
.017
-1.034
.000
.979
.997 13C12-HXCDD 478
.000 13C12-HXCDD 678
.010 13C12-HXCDD 789
AN
AN
AN
SUR4
IS5
RS2
HpCDF
408-410
M
AN
408-410
13C12-HpCDF
418-420
418-420
HpCDD
424-426
424-426
13C12-HpCDD
436-438
436-438
DC NL 0:00
31:12
31:24
31:34
32:25
DC WH 32:55
4 Peaks
DC NL 0:00
31:11
32:25
2 Peaks
DC NL 0:00
DC WL 31:11
31:27
DC SN 31:50
32:04
DC WH 32:25
2 Peaks
DC NL 0:00
DC SN 31:26
32:04
1 Peak
0.88-1.20
RO 3.31
1.13
1.11
1.04
RO 1.28
RO 12.54
0.37-0.51
RO 1.85
0.42
0.42
0.38-1.20
1.13
RO 4.28
1.01
1.19
1.10
RO 2.90
0.88-1.20
RO 1 . 57
RO 1.50
1.04
0.27
57.30 30.40
7.32 3.85
11.64 5.93
6.69 4.19
0.27
82.95
0.58
2,847.33 847.48
2,146.99 632.30
4,994.32
: HpCDF / HpCDD Follows —
0.17
5.90
10.33 5.20
1.18
19.26 10.10
5.22
29.59
1.00
4.61
2,870.60 1.462.22
2,870.60
0.994-1.044
0.000
26.90 1.001 1234678-HpCDF
3.47 1.007
5.71 1.012
3.28 1.040 1234789-HpCDF
1.056
0.936-1. 128
0.000
1,999.85 1.000 13C12-HpCDF 678
1,514.69 1.040 13C12-HpCDF 789
0.976-1.005
0.000
0.972
5.13 0.981
0.993
9.16 1.000 1234678-HpCDD
1.011
0.969-1.031
0.000
0.980
1,408.38 1.000 13C12-HpCDD 678
AN
AN
1 36
SUR5
AN
IS7
'riangle Laboratories, Inc.® Analytical Services Division
101 Cap'rtola Drive • Durham, North Carolina 27713
>hone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 15:3409/1
-------
Page No.
09/18/97
Listing of S975844B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. if.. Flags.
OCDF
442-444
442-444
OCDD
458-460
AN
458-460
0.76-1.02
IX
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
1
NL
SN
SN
1
0:
30:
31:
31:
32:
32:
32:
32:
33:
33:
33:
33:
34:
00
46
07
26
20
27
33
47
00
21
41
54
02
34:21
34:
34
35
35
35
:29
:49
:OS
:26
:56
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
0.
2.
1.
6.
1.
0.
1.
0.
0.
0.
0.
0.
15.
4.
0.
0
50
46
00
90
05
18
35
22
61
94
34
34
25
.00
.15
.86
1.18
0
1
.20
.58
Peak
0
:00
34:36
34
34
:42
:55
0,
RO
RO
.76-1.02
1
1
0
1
.00
.21
.91
.81
Peak
/ Oeta-CDD and CDF Follows
0.08
0.25
0.42
0.19
0.83
0.28
0.32
0.04
0.76
0.35
0.59
0.81
0.08
0.21
0.57
29.62
0.64
0.21
0.59
29.62
0.10
3.16
22.10
0.79
22.10
13.73
10.50
0.885-1.115
0.000
0.887
0.897
0.906
0.932
0.935
0.938
0.945
0.951
0.961
0.971
0.977
0.981
0.990
0.994
15.39 1.003 OCDF
1.011
1.021
1.036
0.885-1.115
0.000
0.997
11.60 1.000 OCDD
1.006
AN
13C12-OCDD 0.76-1.02
470-472 DC NL 0:00 RO 1.25 0.15
34:42 0.86 3,294.68
470-472 1 Peak 3,294.68
1,523.49
1,
0.994-1.004
0.000
771.19 1.000 13C12-OCDD
IS8
Column Description.
"Why" Code Description QC Log Desc.
M_Z -Nominal Ion Mass(es)
..RT. -Retention Time (mm:ss)
Rat.l -Ratio of M/M+2 Ions
OK -RO=Ratio outside Limits
Rel.RT-Relative Retention Time
End of Report
WL-Below Retention Time Window
WH-Above Retention Time Window
SN-Below Signal to Noise Level
-------
il*,3975844 #1-848 Acqtll-SXP-1997 21>43i34 XI+ Voltay* SI* 70S Hoif»:144
03.9016 r>2 BSUB(256,30,-3.0) PKD(9,5,5,0.05\,S76.0,1.00\,T,T) SxptftCOS
TRIANGLE LABS Tmxt:M23-*3 TLH43085 XK7. TIM* - 21>46
17': 00 18:00 19:00 20', 00 21:00 22:00
rila,S975844 tl-848 Aoqill-SEP-1997 21t43:34 EI+ Voltage SIS 70S Nolfet729
05.8987 Tt2 SSUB(256,30,-}.0) PJO>(9, 5,5,0.05\,2916.0,1.00\,r,T) EipsEPCUS
TRIANGLE LABS Tejct:H23-RB TLH43085 I2C7. TIKE - 21:46
17:00 18>00 19:00 20:00
F±le:S975844 tl-848 Aojsll-SEP-1997 21,43,34 EI+ Voltage SIR 70S Nbiae,407
315.9419 F:2 BSUB(256, 30,-3. 0) PJCD(9,S,Sr 0.05\,1629. 0,1. 00%,T, T) ExpiEPCUS
TRIANGLE LABS Te*tsH23-RB 3IHMJ085 ISJ. TIME - 21:46
1001
aol
eol
40:
20:
o.
A2.18E7
I V.
17:00 18:00 19:00 20:00 21:00
rilesS975844 tl-848 Acqsll-SEP-1997 21,43,34 EI+ Voltage SIR 70S Hoi.ae-.611
317.9389 F:2 BSUB(256,30, -3. 0) P1O>(9,S,5, 0. 05\,2444. 0,1. 00%,F,T) ExptEPCUS
TRIANGLE LABS Text,M23~RB TLI#43085 IKT. TIME - 21:46
100S A2.90E7
80:
60:
40:
20':
0.
22,00
16,59
17:40 18:02
17:00 18:00 19:00 20,00 21:00
File:S975844 #1-848 Acij:ll-S£P-1997 21:43:34 EI+ Voltage SIR 70S
330.9792 F:2 ExpiEPCUS
TRIANGLE LABS Teit,M23-RB TLI443005 HKT. TIME -
1003
80:
60:
401
20:
0:
22:00
17:00 181-00 19:00 20:00 21,00
rile,S975844 #1-848 Acq:11-SEP-1997 21:43,34 EI+ Voltage SIR 70S
375.8364 F:2 ExpiEPCUS
TRIANGLE LABS Tejct,M23-SS TLI#43085 UTJ. TIME - 21:45
1001
'22\00
80:
60:
40:
21:08
201 S3
21:42
21:301
22.11
0X0
Time
4.9E6
3.9E6
2.9E6
1.9E6
9.7E5
.o.oso
Time
.6.5E6
.5.2E6
.3.9E6
.2.6E6
.1. 3E6
O.OEO
Time
6.2E6
5.0E6
3.7E6
.2.5E6
.1.2E6
O.OEO
Tin
^U-ft.
17:00
18:00
19:00
20:00
21:00
22:00
-9.8E3
.7.8E3
-5.9E3
-3.9E3
.2.0E3
.O.OEO
Tim
252
-------
•il»:S975844 41-848 Acqsll-SXP-1997 21s43s34 SI+ Voltage SIM 70S Holmes 172
19.0965 Tt2 BSUB(256,30,-3.0) PXD(7,5,3,0.05\,68».0,1.00\,T,T) ExpsEPCUS
TRIANGLE LABS TextsM23-RB TLH43085 JJW. TIHX - 21t46
A1.16E5
19:00 20': 00 21:00
rile:S97S844 tl-848 Aojtll-SXP-1997 21:43:34 EI+ Voltage SIX 70S Noif»s310
321.8936 Ts2 BSUS(256,30,-3.0) PKD(7,5,3,0.05\,1240.0,1.00\,r,T> XxptXPCOS
TRIANGLE LABS TextsM23-XB TLH43085 INJ. TIME - 21s 46
1004 A4. 4X4
19:00 20:00 21:00
rilesS975844 tl-848 Acqsll-SXP-1997 21:43:34 EI+ Voltage SIR 70S Noiae:1347
331.9368 F:2 BSUB(2S6,30, -3. 0) PXD(7,5,3, 0. 05\,5388. 0,1.00%,T,T) ExpsEPCUS
TRIANGLE LABS TextsM23-RS TLH43085 IHJ-.
100\ A2.
-2.2X4
22:00
22» 00
80:
60:
40:
20:
o:
Ul . S4E7
~r
19:00 20:00 21:00
Tile:S975844 tl-848 Acqsll-SEP-1997 21:43:34 EH- Voltage SIR 70S Noiaesl49
333.9338 T:2 BSUB(256,30,-3.0) PKD(7,5,3,0.05\,596.0,1.00\,r,T) ExpsEPCUS
TRIANGLE LABS TextsM23-RB TLI#43085 UKT. TIME - 21:46
100$ A3.10E7
22:00
80:
60:
40:
20:
0.
2.0517
19:00 20:00 21:00
rile:S975844 41-848 Acqsll-SEP-1997 21:43:34 EI+ Voltage SIR 70S Noiaes64
327.8847 F:2 BSUB(256, 30, -3 . 0) PKD(7,5,3, 0. 05\,256. 0, 1. 00\,T, T) ExpsEPCUS
TRIANGLE LABS TextsM23-RB TLIt43085 INJT. TIME - 21s46
1003
80:
60:
40:
20:
o.
22s00'
rr
rr
19:00 20:00 21:00
rilesS975S44 «l-848 Acqsll-SEP-1997 21:43:34 EI+ Voltage SIR 70S
330.9792 Ts2 ExpsEPCUS
TRIANGLE LABS TextsM23-RB TLIt43085 XKT. TIME - 21:45
19:44 30117
22:00
60:
40:
20:
o:
19:00'
20:00'
21:00
22:00'
Time
\
\xo
Time
_ J . 7S5
O.OEO
Time
.7.5E6
-.6.0E6
-4.5E6
.3.OE6
.1. 5E6
O.OEO
Time
-8.1E6
.6.4E6
.4.8X6
.3.2E6
.1. 6E6
tO.OEO
Time
-6.2E6
_5.or5
.3. 7X6
.2.5X6
.1.2X6
O.OEO
Tim
253
-------
ll»tS975844 41-848 Aoqill-SST-1997 21:43:34 EH- Voltage SIR 70S Wbi*e:17
39.8597 r>2 BSOt(256,30,-3.0) PXD(7,5,3t0.05\,68.0,1.00\,rrT) XxptXPCOB
TRIANGLE LABS T*xt:K23-RB XLH43085 XKT. TIME - 21:46
001
23:00 24:00 25:00
Tile:S975844 #1-848 Acqsll-SEP-1997 21:43:34 ZJ+ Voltage SJJJ 705 Mbi««:63
41.8567 Ti2 BSUB(256,30,-3.0) PKD(7,5,3,0.05\,252.0,1.00\,f,T) XzpiXfCUS
TRIANGLE LABS Text:M23-RB TLIt43085 IKJ. TIME - 21:46
1004 A3.41*4 A1.93E4
80:
26:00
23:00 24:00 25:00
File:S975844 #1-848 Acg:ll-SJEP-1997 21:43:34 EI+ Voltage SIX 705 No±ae:21
351.9000 T:2 BSUB(256,30,-3.0) PXD(7,5,3r0.05\,84.0,1.00\,r,T) SxpsEPCUS
TRIANGLE LABS Text: M23-X.B TLI#43085 ItU. TIME -
26:00
21:46
1001
80:
60:
40:
20:
A2.35E7
,
23:00 24:00 25:00 26:00
rile:S$75fl44 #1-848 Acq:ll-SEP-1997 21:43:34 EI+ Voltage SIR 70S Noiae:60
353.8970 r-.2 BSUB(256,30,-3.0) PKD(7, 5,3, 0. 05\,240. 0,1. 00\,T, T) Exp:EPCUS
TRIANGLE LABS T&xt:M23-RB TLIJ43085 IJKT. TIME - 21:46
1003
80J
40J
20J
0.
Al.62Z7
23i00 24:00 25:00
FiletS975844 fl-848 Acq:ll-SEP-1997 21:43:34 EI+ Voltage SIR 70S
330.9792 Ts2 Eip:EPCUS
TRIANGLE LABS Text:M23-RB TLI#43085 IKJ. TIME -
1004
23:51 24:08
80:
60:
40:
20:
o.
26:00
21:46
~r
-r
23:00 24:00
File:S975844 #1-848 Acqsll-SEP-1997 21:43:34 EI+ Voltage SIR 70S
409.7974 T:2 ExptEPCUS
TRIANGLE LABS Text:M23-JlB HJ#430«5 HKT. TIME -
1001
26:00
21:46
23:00
24:00
25:00
26: 00
8.0E6
6.4E6
4.8E6
3.2E6
.1. 6E6
O.OEO
Tiae
5.4E6
4.3E6
.3. 2E6
.2.2E6
.1.1E6
O.OEO
Time
7.4E6
S.9E6
4.4E6
2.9E6
1. 5E6
.O.OEO
Tim
23
22:36 23: OS
I I 23:30
_JL__L_J_
45
^A_ - - ^ilL2£i°JL_
26:10
25:59 1
25:34 I 1 i
-^jiL^LiAL
26:39
1
-8.2E3
4.9X3
3.3X3
1.6X3
0.0X0
Tim
254
-------
TM.e:SS75844 41-848 AcqU.l-SXr-1997 2J.t43l34 XI+ Voltage SIX 70S
355.8546 T>2 BSOB(256,30,-3.0) PKD(7,5,3,0.05\,484.0,1.00\,r,T) XxptXTCOS
TSIANCLX LASS Text:M23-XB TLH43085 1X7. 3TME " 21*46
1003
80.
so:
40.
20:
o:
24:00 25.00 25:00
F±le:S975844 41-848 Aoqtll-SXP-1997 21:43:34 XI+ Voltage SIX 70S Hoime:22
357.8516 T:2 BSUB(256,30,-3.0) PKD(7, 5,3, 0,05\, 88. 0,1.00\,f,T) ErpiEPCUS
TRIANGLE LABS TexttM23-RB TLI4430S5 ZJK7. TIHX - 21:46
1001 Al. 4X4
A1.05X5
A4.43X4
A1.96S4
A/\A A5.96E3
A^/ \/\A»^A^AA»- ^
Al.4524
A7.08X3
I
ft
y^Jl
.2.7*4
.1.1*4
-5.4JT3
24 .-00 25:00
Tile:S975844 #1-848 Acq:ll-SEP-1997 21:43:34 EI+ Voltage SIX 70S Koiae:260
367.8949 T:2 BSUB(256, 30, -3. 0) PKD(7,5,3, 0.05\,1040. 0,1. 00\,r,T) Exp:EPCtJS
TKIAXGLE LABS TeitiM23-RB TLI443085 IJU. TIMX - 21:46
1004 A1.50.E7
SO.
eo:
40J
20:
1.36X6
24:00 25:00 26:00
r±letS975844 41-848 Acqsll-SEP-1997 21:43:34 EI+ Voltage SIR 70S NOi»et4S
369.8919 T:2 BSOB(256,30,-3.0) PXD(7,5,3,0.05\,180.0,1.00\,T,T) Exp:XPCVS
TSIASGLX LABS Text:H23-RB TLH43085 XMT. TIME - 21:45
1001 A9 ?4X6
80.
60.
40.
20.
19.08X5
/\
24:00 25:00 2$<00
File:S975844 41-848 Acq:ll-SEP-1997 21:43:34 EI+ Voltage SIS 70S
330.9792 r:2 Xxp:EPCOS
TRIANGLE LABS T&Xt:H23-R3 TLH43085 IKT. TTHE - 21:45
1001
so:
50J
40.
20:
0.
25:45
25:17
.5.0X6
.4.OE5
-3.0X6
-2.0X6
.9.9X5
0.0X0
Time
.3.2X6
.2.6X6
.1. 9X6
.1. 3X6
.6.4X5
.O.OEO
Time
.7.3X6
.5.9X6
.4.4X6
'.2.9X6
.1.5X6
24:00
25iOO
26100
0.0X0
Time\
-------
11»,S975844 tl-405 Aoqtll-SXP-1997 21t43t34 XI* Voltage SIX 70S Hoime:345
73.8208 Fi3 3SUB(256,30,-3.0) PXD(7,5,3,0.05\r13aO.Or1.00\rr,T) frptXPCUS
TRIAHSLX LASS Text,M23-RB TLH43085 IWT. TIM* - 21>46
27:12 27,24 27,36 27,48 28,00 28,12 28,24 28:36 28:48 29:00 29:12 29:24 29,36 29:48 30:00 30tl2
±19:3975844 tl-405 Actj,ll-3EP-1997 21,43,34 EI+ Voltage SIX 703 Hoist,286
75.8178 T:3 3SUB(256,30, -3.0) PKD(7,5,3, 0. 05%, 1144. 0,1. 00\,T,T) XzpiXPCUS
TRIANGLE LAMS Text:M23-RB TLH430SS IXT. TIME - 21:46
Al.78X5
I
003
80:
sol
40:
20:
A2.25X5
A2.05X4
A1.12X5
A3.29X4
-7.9X4
.6.3X4
.4.8X4
.3.2X4
-.1.6X4
L^^T^"^^"
0.0X0
Time
27:12 27:24 27:36 27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12
File:S97S844 tl-405 Acq:ll-SXP-1997 21:43:34 EI+ Voltage SIR 70S Soime:380
83.8639 T:3 BSUB(256,30, -3.0) PKD(7,5,3, 0. 05\,1520. 0,1.00\,T,T) Exp:EPCUS
TRIANGLE LABS Text:M23-RB TLIt43085 INJ. TIHX - 21:46
1004 Al 54X7
Time
40:
20:
ol
A1.49E7
A1.24E7
.4.0E6
13.0X6
,2.0X6
.1. 0X6
0.0X0
27:12 27:24 27:36 27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12 Time
rile:S975S44 tl-405 Ac
-------
fiJLetS97S844 tl-405 Aoq:ll-SEP-1997 21:43:34 XIr Voltage aim 70S HOifetlJV
389.8156 T:3 BSOB(256,30,-3.0) fXD(7,5,3,0.05\,520.0,1.00\,r,T) ElptEPCUS
TSIAXGLX LABS TexttM23-SB TLI'43085 UKT. TIMS -
1001 A2.59ES
80.
60.
40.
20J
0.
27:48 28:00 28:12 28:24 28»36 28:48 25:00 25:12 25:24
riletS975844 tl-405 Acqtll-SEP-1997 21:43:34 EH- Voltage SIS 70S Noime:329
391.8127 T:3 BSUB(256,30,-3.0) PXD(7,5,3,0.05\,1316.0,1.00\,F,T) XxptEPCOS
TRIANGLE LABS TexttM23-SB TLIt43085 INJ. TIME - 21:46
1001
A8.21E4
A6.84E4
A6.11S4
(\ A
/V /\
^ ^ - ^^
A4.52S4
A3
. 92X4 A
\ A
-
29:36 29:48
27:48 28:00 28:12 28:24 28:35 28t48 29:00 23:12 29:24 25:36 29:48
rile:S97SB44 tl-405 Acqtll-SEP-1997 21:43:34 EI+ Voltage SIS 70S Noiae:312
401.8558 T:3 BSOB(256,30,-3.0) PKD(7,5,3,0.OS\,1248.0,1.00\,F,T) ExptEPCOS
TSIANSLE LABS Tej[tsM23-SB TLIt430B5 IKJ. TIME - 21:45
1001 A2.88E7
so:
50:
40:
20:
A2.00E7
27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 25:35 29:48
File:S975844 tl-405 Acqtll-SEP-1997 21:43:34 IX* Voltage SIS 70S Noiaetl67
403.8529 F:3 BSOB(256,30,-3.0) PKD(7,5,3,0.05\,668.0,1.00\,r,T) ExptEPCOS
TSIANSLE LABS TexttM23-SB TLIt43085 IVJ. TIME - 21:46
1001 A2.40E7
so:
50J
40.
20:
5.5M
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-7.5E6
_5. 6E6
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11.9E6
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.7.7X6
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1.4.525
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27:48 28:00 28:12 28:24 28:35 28:48 25:00 25:12 25:24 29:35 29:48
riletS97S844 tl-405 Acqtll-SEP-1997 21:43:34 EI+ Voltage SIS 70S
392.9760 Ts3 XxptEPCOS
TRIANGLE LABS TextiM23-SB TLIt4308S IJKT. TIME - 21:45
100> 27t55 _ 28:05 28:16 28>27 28:38 28j54 39t13 ,25:2725:34 . 29/45
V W^vv* "*\/ " " *v~ v "^V^^wr v "wvv- * ~ *^* " * yv ~v * v"
so:
so:
40:
20J
O.OEO
Time
4.0E6
3.2E6
2.4E6
.1. 6E6
.8.0X5
0.0X0
27:48 28:00 28:12 28>24 28:5 20:48 25:00 25:12 25:24 25:tf 25*48
T±me\
-------
ile>3975844 #1-430 Aoqill-SXP-1997 21i43i34 XI* Voltao* SI* 70S Hoif9:215
07.7818 Ti4 BSVB(256,30,-3.0) PKD(7,5,3,0,05\,860.0,1.00\,T,T) XxpiXTCDS
•IAKSLX LASS TexttM23-XB TLH43085 HKT. TZKK - 21:46
31-00 31,12 31,24 31,36 31,48 32,00 32,12 32,24
il»:S975844 H-430 Aajtll-SEP-1997 21,43,34 SI+ Volt*?* SIS 70S Halfe,64
09.7789 T,4 BSOB(256,30,-3.0) PKD(7,5,3,0.OS\,256.0,1.00\,T,T) XxptXPCOS
TRIANGLE LABS Text:H23-XB TLH43085 ItKT. TIMS - 21,46
OOi A2.66E5
80:
60:
31-00 31:12 31:24 31:36 31,48 32,00 32:12 32:24
rile,S975844 #1-430 Acq:ll-SXP-1997 21:43:34 EH- Voltage SIS 70S Boiae:369
17.8253 T:4 BSOB(256,30,-3.0) PKD(7,5,3,0.05\,1476.0,1.00*,T,T) Exp-.EPCUS
TRIANGLE LABS Teit:M23-XB TLH43085 IKT. TIME " 21:46
00\ AS.47E6
003
80:
so:
40:
20:
A3.2315
A3.85E4 AS.93X4
A8.79E3 A1.39X4
A5.23E4
32,36
32:48
40:
A5.71E4
A3.81E4
A9.02E3
32:36
32:48
so:
so:
-------
423.7766 T:4 *SUB(256,30, -3 .0) PKD(7,5,3
TRIANGLX LABS T«xt:M23-U ZZJM3085
1003
80.
60.
40.
20.
A5.20E4
A4.97E3
.^\~
31:18 3ll24 31:30 31:35 ' 31:42 '
,0.05\,184.0,1.00\,r,T) XzpsXTCUS
UKT. TIMX - 21«4«
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31:48 31:54 32:00 32:05 32:12
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A7.4224
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^.«M
.i.aw
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o^mmm
32118 32:24 32:30 ttmm
rile, 3975844 #1-430 Acqsll-SEP-1997 21:43:34 XI+ Voltage SIR 70S Koiae:41
425.7737 T:4 BSUB(256,30,-3.0) PKD( 7,5,3, 0. 05\,164. 0,1. 00\,T,T) XxptXPCOS
TRIANGLE LABS Texts M23-RB TLIt43085
1001
so:
60.
.
40.
20:
0.
AS . 13E4
A'
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31:18 31:24 31:30 31:3$ 31:42
XK7. TIME - 21:45
A9.16E4
A
Jl
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AS. 4 1X3 I \
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31:48 31:54 32:00 32:06 ' 32:12
A2.56E4
A l\
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.2.3X4
.1 . 7S4
_i . ir4
_5 . 7J53
o.ana
32:18 32:24 32:30 Tine
rile:S975844 tl-430 Acq: ll-SEP-1997 21:43:34 EH- Voltage SIR 70S Noise: 3 85
435.8169 T:4 BSVB(256,30, -3.0) PKD( 7, 5,3, 0. 05\,1S40. 0,1.00%, f,T) Exp:EPCUS
TRIANGLE LABS Text:M23-RS 1X1*43085
1001
801
601
401
20.
0_
31:18 31:24 31:30 31:36 31:42
IWJ. TIME - 21:45
Al . ,45£7
A
/ \
/ \
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31:48 31:54 ' 32:66 ' 32:05 32:12
•
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.2.1X6
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.5.3X5
' 0 . OKO
32:18 32:24 ' 32:30 Time
rile,S975844 tl-430 Acq: ll-SEP-1997 21:43:34 EI+ Voltage SIR 70S Noiaei244
437.8140 f:4 BSUB(2S6,30, -3. 0) PKD(7,5,
TRIANGLE LABS Text:M23-RB TLIf43085
1001
80.
60.
40.
20.
0_
31:18 31:24 31:30 31:35 ' 31:42
3,o.05%,575.o,i.oo%,r,r; E*P:EPCVS
ISJ. TIME - 21:45
Al .41X7
f\
1 \
1 \
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31:48 31:54 32: 00 32:05 32:12
.-2.5JS5
L2.ir6
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.1 . 0£5
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32:18 32:24 32:30 Time
rile:S975844 tl-430 Acq: ll-SEP-1997 21:43:34 EH- Voltage SIR 70S
430.9729 F:4 XxpiXPCOS
TRIANGLE LABS Text:M23-RB TLH43085
100
80
60
40
20
0
TWT. TIME -
21:46
\?}*¥^L^^^¥ 5v^. ^N^v J^^^^X^i^v^^^ '
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31:18 31:24" 31:30 ' 31:36 ' 31:42
31:48 31:54 32:00 32:05 32:12
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'.1 . 8X6
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' 0 . 0X0
32:18 32:24 32:30 Time
-------
fll»:S975844 tl-430 Aoq:ll-8XP-lS97 21:43:34 XI + Voltaye SIM 70S Holf9il9
441.7438 T:4 BSU3(2S6,30, -3 .0) nO>(7, 5,3,0
TRIANGLE LAMS TexttM23-XB TLIt430»5
1001
901
801
701
601
501
401
301
201
101
0.
A6.87E3
.05\,76.0,1.00\,r,T) IxptXPCOB
XK7. XXKT - 21:46
-2.4JC4
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1
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443.7399 T:4 BSUB(356,30,-3 .0) PKD(7,5,3,0.05\,152.0,1.00\,r,T) Exp:EPCUS
TRIANGLE LABS Tuxt:M23-XB TLHH30S5
1001
901
801
701
601
501
401
301
201
101
oj
A7.24E3
1
1
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1 A8.21E3
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33:00 34-00
rile;S575844 #1-430 Acq:ll-SEP-1997 21:43:34 EI+ Voltage SIX 70S
430.9739 F:4 Exp:EPCUS
TRIANGLE LASS T&xt:M23-XB TLIt43085
1003
901
801
701
601
501
40.
30-
20.
101
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_1 . 6X4
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.1 . 6X3
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JJK7. TIME - 21:45
30:55 31.-15 31:52 ja.rj 32!41 33:21 33:47 34:16 14, i}4!55 35*15 35:37
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Tile:S975S44 tl-430 Acq:ll-SEP-1997 21:43:34 XI+ Voltage SIX 70S
513.6775 F:4 ExpiEPCUS
TRIANGLE LABS Text :M23 -JIB TLHH30B5
100J
90-.
801
70-.
601
50J
:
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30.:
SO'-
^ i/_
10J
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IJTJT. TIMX - 21:46
32:41
32:15
31:38
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31:00 32:00
33:34
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35:16
34:30 35:02||
34:20 U
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3.2X3
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-.2.2X3
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.9.5X3
.6.4X2
.3.2X2
33:00 34:00 35:00 ' ' Ti,e
260
-------
Film,3975844 IJ.-4JO Aoqill-SXf-1997 J1,4J,J4 XI+ Voltmgm SIM 70S Bolmm,23
457.7377 Ti4 3309(256,30,-3.0) PKD(7,S,3,0.05\,92.0,1.00\,F,T) XxpiXPCUS
TRIMKLX LA9S TmxtiK23-JU TLH43085 IKJ. TIM* - 21>46
A7.70E4
BO:
60.
40.
20:
A7.61X3
34,30 34,36 34,42 34:48 34,54 35,00
File,3975844 fl-430 Aoqtll-SXP-1997 21:43:34 XI+ Voltage SIX 70S Soime,23
459.7348 Fs4 BSUS(256,30,-3.0) PKD(7,S,3,0.05\,92.0,1.00\,F,T) XxptXPCUS
TRIANGLE LASS Text:M23-XB TLIf43085 IKJ. TIMS - 21,46
100\ A1.23E5
J9.2M3
.6.1X3
.3.1X3
9.9X0
34,30 34:36 34,42 34,48 34,54
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469.7779 F,4 BSU3<256,30,-3.0) PKD(7,5,3,0.05\,204.0,1.00\,F,T) ExptEPCOS
TRIANGLE LASS T&It:M23-RB TLH43085 IKT. TIME - 21:45
100* Al.
35,00
34,36 34:42 34:48 34,54
r-Lle,S975844 fl-430 Acq:ll-SEP-1997 21:43,34 Eli- Voltage SIR 70S NOlaa,42
471.7750 F:4 BSUB(256,30,-3.0) PXD(7,5,3,0.05\r16B.0,1.00\,F,T) Exp:EPCOS
TRIANGLE LABS T&rt:H23-RB TLI#43085 IKJ. TIME - 21:46
ion
so:
35:00
34,30 34:36 34,42 34,48 34,54
F±le,S975844 tl-430 Aoqill-SEP-1997 21:43:34 EI+ Voltage SIB 70S
35 96
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35
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35 06
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100J
80.
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20.
0
9729 F:4 ExptEPCDS
WSLE LABS Text:H23-R3 TLH430B5 IKJ. TIME - 21:46
^_^^_£5^3£__^^__^^ 34:41 34:45 ^55 34s58 ^__-__l
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-3.1E6
-2.SE6
.1 . BE6
.1.2X6
.6.2X5
0.0X0
06 Time
261
-------
Channel I 338,9792 Peak top
Height 1,51 volts Span 298 ppi
Systa file naie EPOS
Data file naie fl=$975843
Resolution 18686
Group rajtef 2
Icnlzatlon axte £1*
Switching VQlTflGE
Ref, lasses 292,9825, 416,9768
fl 293 J 331 S 368
K 332 T 378
L 334 U 376
1 348 V 418
H 342
0 352
P 354
Q 356
R 358
tef, lass 416,9768 Peak top
Height ,27 volts Span 288 ppi
262
-------
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89.8156 P:3 Exp.-EPCUS
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29:40 ^2.7E4
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30:00
27100 28100 ~" 29IOO '
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91.8127 F:3 Exp:EPCUS
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TLI Project:
Client Sample:
43085
TLI LCSD
Method 23 PCDD/PCDF Analysis (a)
Analysis File: S975832
Client Project:
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
S413-004
XAD
TLI LCSD
1.000
n/a
DB-5
Date Received:
Date Extracted:
Date Analyzed:
Dilution Factor:
Blank File:
Analyst:
//
09/04/97
09/11/97
n/a
S975815
BJG
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPX23704
SF56117
S975814
n/a
n/a
n/a
Anatytes •; -i":'£?%$*$x3:-$i-f>$:.
2,3,7,8-TCDD
,2,3,7,8-PeCDD
,2,3,4,7,8-HxCDD
,2,3,6,7,8-HxCDD
,2,3,7,8,9-HxCDD
,2,3,4,6,7,8-HpCDD
.2,3,4.6,7,8,9-OCDD
2,3,7,8-TCDF
1.2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1,2.3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
1,2,3,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
1,2,3,4,6,7,8,9-OCDF
Inftunaf ^innriarrfe ' "^ '••'••••'• --: •'•' ":
.. emai aiarraaras ; ....,,. ,,. :;;|,v .,
l3C,2-2,3,7,8-TCDF
13C12-2,3,7,8-TCDD
3C,2-l,2,3,7,8-PeCDF
[3Cr.-l,2,3J,8-PeCDD
13C12-l,2,3,6,7,8-HxCDF
13C12-l,2,3,6,7,8-HxCDD
13C12-l,i3,4,6,7,8-HpCDF
l3C12-l,2,3,4,6,7,8-HpCDD
13C1;-1,2,3(4,6,7,8,9-OCDD
.A: fAmt»: (ng)
0.36
1.9
1.7
1.8
1.9
1.8
3.6
0.37
1.9
1.9
1 7
1.8
1.7
1.8
1.8
1.6
2.8
..::-.:.• _.. -,.-.• . .-i
.Amt \ng)
2.6
2.4
2.6
2.7
2.9
28
2.5
2.7
4.8
BL 1
*»
% Recover;
65.4
60.9
64.9
66.7
72.8
70 3
62.5
67.1
60.2
SMPO
f QC tpmrts
40%- 130%
40%- 130%
40%- 130%
40%- 130%
40%- 130%
Ar\or, \i.r\ot-
25%- 130%
25%-130%
25%- 130%
B*tf6«:^
0.78
1.64
1.24
1.23
1.24
1.04
0.83
0.82
1.52
1.53
1 TO
i.zy
1.29
1.28
1.32
1.09
1.09
0.88
Ratio
0.76
0.80
1.56
1.48
0.50
1 04
i.ZA
0.42
0.99
0.87
!:v?*r!v-v:
21:1-3
25:51
29:07
29:12
29:29
32:04
34:38
20:23
24:42
25:29
OQ.OO
2.Q.2Z
28:29
28:59
29:42
31:12
32:25
34:43
RT
20:22
21:12
24:42
25:50
28:28
on. i o
Zy.lZ.
31-11
32:04
34:38
^fcg*^
—
—
Ftegs
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Page 1 of 2
X237.PSR viOO. LARS 6.10.04
Printed: 12:0309/18/97
269
-------
TLI Project:
Client Sample:
43085
TLI LCSD
Method 23 PCDD/PCDF Analysis (a)
Analysis File: S975832
AttertvateStervrfaitts(Typ*A} Amt (ng)
% Rwovary QC Limits Ratto
l3C,2-l,2,3,7,8,9-HxCDF
l3C,2-2,3,4,6,7,8-HxCDF
3.0
3.1
75.4
77.5
40%-130%
40%-130%
0.51
0.50
29:41
28:59
Recovery Standards
Ratio
8T
13C,2-1,2,3,4-TCDD
I3C12-l,2,3,7,8,9-HxCDD
0.80
1.20
20:59
29:29
Data Reviewer
, -L t^,\v^
09/18/97
Page 2 of 2
X237_PSR»ZOO, LARS 6.IOM
Triangle Laboratories, Inc.®
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 12:03 09/18/9'
-------
Initial
..Date..
Data Review By:
JJTL ") / (j / !+• Calculated Noise
Area: n/a
The Total Area for each peak with an ion abundance ratio outside
ratio limits has been recalculated according to method requirements.
Page No. 1
09/18/97
Compound/
M_Z.... QC.Log Omit Why
Listing of S975S32B.dbf
Hatched GC Peaks / Ratio / Ret. Time
.RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flag*.
TCDF
304-306
304-306
13C12-TCDF
316-318
316-318
TCDD
320-322
320-322
0.65-0.89
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
SN
SN
SN
SN
SN
SN
SN
WH
, 1
NL
SN
SN
SN
1
NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
WH
WH
0:00 RO
16:48
18:03
19:
19:
19:
20:
20:
21:
22:
11
30
54
08
23
56
42
RO
1.25
0.86
0.
60
0.70
RO
RO
RO
RO
RO
1.
0.
0.
0.
0.
0.
09
98
27
82
35
18
Peak
0:
19:
19:
20:
20:
00
32
52
22
53
0.
RO
RO
0.14
1.56
2.44
18.
3.
11.
0.
461.
0.
0.
461.
85
19
58
55
06 207.61
64
55
06
65-0.89
15.
0.
0.
0.
1.
Peak
0;
18:
18:
18
19
19
19
19
20
20
20
20
21
21
21
:00
:37
:42
:53
:08
:15
:21
:55
:22
:30
:44
:54
:00
-.13
:48
22:19
0.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
22:38 RO
22:40 RO
20
69
77
76 4
14
4
65-0.89
1.
0
12.
2
0
0
0
0
3
0
0
1
2
0
6
0
1
0
.33
.73
.60
.80
.43
.73
.25
.75
.32
.75
.74
.90
.83
.78
.50
.43
.06
.27
1 Peak
0.
6.
18.
,035.
21.
09
32
60
05 1,746.44
35
0.820-1.101
0.000
0.825
0.
0.
0.
0.
0.
253.45 1.
1.
1.
0.951-
0.
0.
0.
2,288.61 1.
1.
886
942
957
977
989
001 2378-TCDF AN
077
115
1.049
000
959
975
000 13C12-2378-TCDF ISO
025
,035.05
0
0
0
0
0
1
0
2
1
1
0
0
0
322
.11
.76
.09
.35
.55
.07
.34
.13
.33
.80
.94
.51
.94
.42 141.35
0.18
0.92
0.55
0.57
0.853-1.059
0
.000
0.878
0
0
0
0
0
0
0
0
0
0
0
181.07 1
1
1
.882
.891
.903
.908
.913
.939
.961
.967
.978
.986
.991
.001 2378-TCDD AN
.028
.053
1.068
1.069
322.42
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 12:0309/18/97
271
-------
Page No.
09/18/97
Listing of S975832B.db£
Hatched GC Peaks / Ratio / Ret. Tin
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area...
Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
13C12-TCDD
332-334
DC
DC
DC
NL
SN
SN
0.65-0.89
0:00 RO 24.67 0.16
19:52 RO 1.13 13.47
20:36 RO 2.05 2.35
20:59 0.80 4,680.21 2,079.73
21:12 0.80 3,036.35 1,350.47
21:33 RO
332-334
PeCDF
340-342
340-342
13C12-PeCDF
352-354
352-354
PeCDD
356-358
356-358
13C12-PCCDD
368-370
DC
SN
3
21:46 RO
Peaks
1.12
1.38
42.13 26.58
3.95
0.906-1.094
0.000
0.937
0.972
2,600.48 0.990 13C12-1234-TCDD RSI
1,685.88 1.000 13C12-2378-TCDD IS1
23.80 1.017
1.027
7,758.69
1.32-1.78
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
SN
SN
SN
SN
SN
SN
SN
2
NL
SN
SN
SN
SN
SN
SN
1
NL
SN
SN
SN
SN
SN
1
NL
SN
0:00
22:36
23:49
24:21
24:42
24: 53
25:01
25:29
26:08
26-27
Peaks
0:00
23:46
24:20
24:42
24:59
25:22
25:28
26:27
Peak
0:00
23:57
24:43
24:52
25:04
25:30
25:51
Peak
0:00
24:43
RO
RO
RO
RO
RO
RO
1.
RO
RO
RO
1.
RO
RO
RO
RO
RO
1
RO
RO
25:50
0.
0.
1.
1.
1.
1.
1.
1.
1.
0.
88
31
33
89
52
11
59
53
02
56
0.
2.
22.
10.
1,810.
10.
27.
1,823.
1.
3.
3,633.
12
07
22
30
32 1,092.57
22
22
25 1,103.61
51
88
57
32-1.78
1.
1.
1.
1 .
1.
1.
1
0
00
15
40
56
.74
.50
.48
.95
0.
11.
12
.53
14.07
3,441.27 2,098.74
14.25
3
29
8
3,441
.32-1.78
0
0
1
1
2
1
1
.32
0
2
1
.86
.09
.97
.38
.08
.91
.64
-1.78
.86
.43
.48
0
0
2
3
2
0
1,165
1,165
.08
.96
.95
.27
.10
.79
.63
.97
.47
.82
.51 724.15
.51
0.907-
0.
0.
0.
0.
717.75 1.
1.
1.
719.64 1.
1.
1.
1.078
000
915
964
986
000 12378-PeCDF
007
013
032 23478-PeCDF
058
071
AN
AN
0.833-1.162
0.000
0.962
0.
1,342.53 1.
1.
1.
985
000 13C12-PeCDF
.011
.027
1.031 13C12-PeCDF
1
.071
123 IS2
234 SUR2
0.921-1.026
0
0
0
0
0
0
441.36 1
.000
.927
.957
.963
.970
.987
.001 12378-PeCDD
AN
0.845-1.155
0.10
2
.22
1,982.60 1,183.63
0
.000
0.957
798.97 1
.000 13C12-P6CDD
123 IS3
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 12:03
-------
Page No.
09/18/97
Listing of S975832B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M.Z.... oc.Log omit Why . .RT. OK Ratio Total.Area... Area.Peak.1.. Ar.a.P.ak.2.. R.I.RT Compound.*
Ian*.. ID. .Flags
368-370
HXCDF
374-376
374-376
13C12-HXCDF
384-386
384-386
HxCDD
390-392
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
2
NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
4
NL
SN
SN
SN
SN
SN
SN
SN
SN
3
NL
WL
SN
SN
SN
SN
SN
SN
SN
SN
25:59
Peaks
0:00
27:22
27:30
28:02
28:22
28:29
28:44
28:48
28:59
29:13
29:16
29:24
29:30
29:42
29:54
Peaks
0:00
27:20
27:30
28:28
28:42
28:59
29:13
29:16
29:24
29:41
29:58
30:01
Peaks
0:00
27:44
27:54
28:04
28:23
28:29
28:37
28:42
28:51
28: 58
29:07
1.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
0.
RO
RO
RO
RO
RO
RO
RO
1 .
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
1
.50
.05-1.43
.1.89
1
1
2
1
1
2
1
1
0
1
1
1
1
0
43
0
0
0
0
1
0
0
0
0
0
0
0
05
1
1
0
0
0
2
1
1
3
4
1
.53
.48
.02
.29
.29
.60
.72
.28
.80
.30
.65
.52
.32
.91
-0.59
.55
.29
.39
.50
.50
.50
.64
.32
.74
.51
.55
.60
-1 . 43
.49
.78
.87
.89
.85
.06
.56
.62
.15
.50
.24
180
2,163
*
1
4
10
1
1,561
2,046
2
2
1,541
2
1
1
3
1.479
2
6,629
3
2
9
2,962
2
2,919
3
1
1
2,468
2
3
•79 108.57
.39
D / HxCDF Follows --
.77
.26
.37
.30
•66 878.60
•94 1,154.87
.55
.02
•86 865.45
.67
.59
.90
.23
.08 841.99
.49
.54
.29
.61
.95
•73 982.38
.55
•87 972.79
.70
.27
.31
•56 831.41
.28
.16
72.22 1.
006
•
0.955-1.052
0.000
0.
0.
0.
683.06 0.
892.07 1.
1.
1.
676.41 1.
1 .
1 .
1 .
1.
637.09 1.
0.359-
0.
0.
0.
1,979.85 1.
1 .
1,947.08 1.
1.
1.
1.
1,637.15 1.
1.
1
8,351.16
961
966
985
996 123478-HXCDF
001 123678-HXCDF
009
012
018 234678-HxCDF
026
028
03 3
036
043 123789-HXCDF
1.141
000
960
966
000 13C12-HXCDF 678
008
018 13C12-HXCDF 234
026
028
033
043 13C12-HXCDF 789
053
n*\A
U34
All
AN
AN
AN
IS4
ALT2
ALT1
1
1
1
0
3
2
5
1
0
0
985
.32
.52
.61
.90
.09
.31
.64
.88
.60
.94
•19 544.61
0.950-1.015
0. nnn
0.
0.
0 .
0 .
0.
0.
0.
0.
0.
440.58 0.
950
955
961
972
975
980
983
988
992
QQ7 1 *>T4"7Q_Ui,/~™r\
-HxCDD
AN
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 12:03
-------
Page No. 4
09/18/97
Compound/
M_Z.... QC.Log Omit Why
Listing of S975832B.db£
Matched GC Peaks / Ratio / Ret. Time
.RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name. . ID.. Flags.
390-392
13C12-HXCDD
402-404
402-404
HpCDF
408-410
408-410
13C12-HpCDF
418-420
418-420
HpCDD
424-426
424-426
13C12-HPCDD
436-438
436-438
29:12
29:29
DC SN 29:37 RO
DC WH 29:43 RO
DC WH 29:53 RO
3 Peaks
l.i
DC NL 0:00 RO
DC WL 27:54 RO
DC SN 28:34
29:12
29:29
DC SN 29:42 RO
2 Peaks
0.
DC NL 0:00 RO
31:12
DC SN 31:32 RO
32:25
2 Peaks
0.
DC NL 0:00 RO
31:11
DC SN 31:25 RO
DC SN 31:48 RO
DC SN 31:57 RO
DC SN 32:29
1 Peak
0
DC NL 0:00 RO
DC SN 31:26 RO
32:04
1 Peak
0
DC NL 0:00
DC SN 31:27
32:04
DC SN 32:18 RO
1 Peak
1.23
1.24
2.42
1.64
0.31
05-1.43
0.87
0.93
1.38
1.24
1.20
5.96
88-1.20
4.06
1.09
0.61
1.09
37-0.51
1.63
0.42
0.58
0.70
1.06
0.39
. 88-1.20
2.74
0.81
1.04
.88-1.20
0.98
0.92
0.99
2.67
1,211.68 667.37
1,223.86 677.65
3.11
3.54
0.87
3,420.73
3.34
3.87
13.85
2,365.17 1,307.45
3,379.31 1.842.39
1.28
5,744.48
Uv^*T*in / Hr^fTM? l?r\l 1 r*i*rc — — •
rDCv, uu / npiv Lsf f o j. x ows *• ~
1.59
1,324.95 692.08
3.12
894.39 466.29
2,219.34
0.91
1,874.76 555.58
5.08
2.36
1 .44
5.55
1,874.76
0.86
6.18
872.46 444.26
872.46
2.57
4.25
1,846.97 920.38
2.10
1,846.97
*- wrsrnn / rv-*-a-rnn xr\A rrv
544.31 1.000 123678-HXCDD
546.21 1.010 123789-HxCDD
1.014
1.018
1.023
0.966-1.034
0.000
0.955
0.978
1,057.72 1.000 13C12-HXCDD 678
1,536.92 1.010 13C12-HXCDD 789
1.017
0.995-1.044
0.000
632.87 1.001 1234678-HpCDF
1.011
428.10 1.040 1234789-HpCDF
0.936-1.128
0.000
1,319.18 1.000 13C12-HpCDF 678
1.007
1.020
1.025
1.042
0.976-1.006
0.000
0.980
428.20 1.000 1234678-HpCDD
0.969-1.031
0.000
0.981
926.09 1.000 13C12-HpCDD 678
1.007
P TTollowo
Mi
Ml
IS5
RS2
AN
AN
IS6
AN
IS7
'riangle Laboratories, Inc.® Analytical Services Division
101 Capitola Drive • Durham, North Carolina 27713
'hone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 12:03 09/18/97.
274
-------
Page No. 5
09/18/97
Compound/
M_2.... QC.Log Omit Why
OCDF
442-444
Listing of S975832B.dbf
Hatched GC Peaks / Ratio / Ret. Time
.RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound,
0.884-1.116
0.000
0.919
0
ic..
442-444
0.76-1.02
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
1
0:
31:
32:
32:
32:
32:
32:
32:
33:
33:
33:
33:
34:
34:
35:
00
49
01
06
22
32
44
57
08
31
35
49
21
43
25
RO
RO
RO
RO .
RO
RO
RO
RO
RO
RO
0.
0.
0.
1.
0.
1.
1
0.
0
0
0
0
0
0
1
15
36
77
,62
,97
.14
.10
.86
.24
.39
.24
.30
.78
.88
.62
Peak
0
0
1
0
0
1
0
2
0
0
0
0
1
1.117
1
1,117
.17
.91
.01
.70
.61
.72
.76
.18
.45
.47
.68
.30
.57
.27
.49
.27
523.96
593.31
924
0.927
0.935
0.939
0.945
0.951
0.957
0.968
0.970
0.976
0.992
1.002 OCDF
1.023
AN
OCDD
458-460
458-460
0.76-1.02
DC NL 0:00 RO 6.29 0.13
DC SN 34:21 RO 0.75 1.83
34:38 0.83 1.049.26
1 Peak 1.049.26
475.04
0.884-1.116
0.000
0. 992
574.22 1.000 OCDD
AN
13C12-OCDD 0.76-1.02
470-472 DC NL 0:00 RO 9.71 0.13
34:38 0.87 2,111.51
470-472 1 Peak 2.111.51
983.01
0.995-1.005
0. 000
1,128.50 1.000 13C12-OCDD
IS8
Column Description.
"Why" Code Description QC Log Desc.
M_Z -Nominal Ion Mass(es)
..RT. -Retention Time (mmtss)
Rat.l -Ratio of M/M+2 Ions
OK -RO=Ratio Outside Limits
Rel.RT-Relative Retention Time
End of Report
WL-Below Retention Time Window
WH-Above Retention Time Window
SN-Below Signal to Noise Level
-------
fila:S975832 tl-848 Acqtll-SXT-1997 Ilt39i38 EI+ Voltage SIX 70S Ooit»:48
303.9016 T:2 BSV3(256, 30, -3. 0) PKD(9,5,5,0.05\,L32.Q,1.0Q\,r,T) XxpiXPCVS
TRIANGLE LABS TeJCtsTLI LCSD TLH43085 IJKT. TIMS " 11:42
I 001 A2.08X6 C4.6E5
80.
SO.
40-
20.
0-
R
I
3.7X5
2.8X5
.1 . 9X5
.9.3X4
0.0X0
17:00 ' ' ' 18:00 ' ' 19:00 30:00 2l':00 2.2:00 Time
rile:S975832 tl-848 Acq:ll-SEP-lS97 11:39:38 EI+ Voltage SIR 70S Hoime:39
305.8987 T:2 BSVB(2S6,30,-3 .0) PXD(9,5,5,0.05\,156.0,1.00\,r,T) ExptEPCOS
TXIASGLE LABS Tart: 3X1 LCSD TLH43085 HKT. TIME - 11:42
1001 A2.53E6 5.OP5
80J
60:
40'.
20:
0:
rile
315.
TSIA.
1001
aol
60:
40^
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0
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317.
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375
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80.
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17:00 10:00 19 t 00 20:00 21:00
•.S975832 #1-848 Acq:ll-SEP-1997 11:39:38 EH- Voltage SIS 70S NoiaeilBl
9419 T:2 BSUS(256, 30, -3. 0) PKD(9,5,5, 0. 05\,1S24. 0,1 . 00\,r,T) ExpiEPCDS
NGLE LASS TejctiTLX LCSD TLI04308S IJfJ. TIME -
Al . 75E7
h
17^00 'l8:00 ' 19:00 30:00 21s 00
•.S975B32 #1-848 Acq:ll-SEP-1997 11:39:38 EI+ Voltage SIS 70S Noise -.27
9389 Fi2 BSDB(256,30,-3.0) PKD(9, 5,5, 0. 05%, 108. 0, 1 . 00\,T, T) ExpiEPCUS
NGLE LABS TextsTLI LCSD TLI#43085 TJK7. TIME -
A2.29E7
I
'l7\00 ' ' ' 'iflioO 19:00 'soi-oo' ' ' ' 21:00
1-.S975832 tl-848 Acq:ll-SEP-1997 11:39:38 EI+ Voltage SIR 70S
9792 T:2 ExpsEPCUS
UfSLE LABS TeitsTLI LCSD TLI443085 JKT. TIME -
\ ,-,„-, 17:31 18:04 18,48 19:22 20:08 20:50
17:03 ll~i, v-yyv^X^ ---^. -yw-V^-m-T '"^ '' •" -*Y*-J/\~**r~*^\Sf\ ywWVV>^V
17:00 18.' 00 19:00 20:00 21:00
i:S975832 #1-848 Acq:ll-SEP-1997 11:39:38 EI+ Voltage SIR 70S
8364 T:2 Exp:EPCDS
\KGLE LABS Text:TLI LCSD TLI#43085 JKT. TIME -
k
• 19:23
'• . 19:03
: ui£/MwJU\AA*>_Jil__A^^^
'l7:00 ' ' ' 'isioo' ' ' ' 'l9>00
. 19:53i\
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11:42
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Time
.4 . 2X6
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'-2.SE6
Ll . 7X6
.8.5X5
0.0X0
Time
5.4E6
-4.4X6
.3 . 3E6
.2.2E6
.1 . 1X6
0.0X0
Tint,
6.4X6
.5.1XS
.3 . 9X6
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.1 . 3X6
O.OEO
22:00 ' ' Time
11:42
C1.4S4
20:46
\ ill 21,08 »|« 22,20
lL_-JlwAAIVJuuA^a>^-AJJU_Jw\X-^^^
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Time
276
-------
rile: £975832 #1-843 Aoqtll-SXP-1997 Ili39>38 XI* Voltmfe SIX 70S Ifoimet41
319.8965 Tt2 BSU3(25f,30,-3.0) PXD(7,5,3,0.05\, 164.0,1.00\,r,T) ExptXPCUS '•
TRIANGLE LAB3 T*lt:TLI LCSD 311*43085 HOT. TIMS - lit 42
1001
80:
60:
40:
20.
OJ.
'l$ioO
A1.41E6 f3.S*S
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t. 0X0
20:00 21:00 22:00 HJM
rlleiS975832 #1-848 Acq,ll-SEP-1997 Ilt39t38 EI+ Voltaye SIR 70S Noif»i30
321.8936 r:2 BSU3(256,30,-3.0) PXD(7,5,3,0.05\,120.0,1.00\,r,T) ExptfPCUS
TRIANGLE LABS Text: 2X1 LCSD 1X1*43085 IKT. TIMX - lit 42
1001
80J
60:
40:
20:
ol
19:00
A1.81X6 ..4.6*5
n
\
1 I
.3.7*5
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o.ar.o
20iOO Sl'lOO 32:00* Tiae
rileiS975832 #1-048 Acq:ll-SEP-1997 11:39:38 EI+ Voltage SIS 70S KoiaetlllO
331.9368 r:2 BSUB(256,30, -3. 0) PKD(7, 5,3,0. 05\,4440. 0,1. 00\,r,T) ExptEPCUS
TRIANGLE LABS Text: 3X1 LCSD 1X1*4 JOSS INT. TIME - 11:42
1001
80J
60:
40:
20:
0:
I9ioo'
A3.0SE7 S.OE6
f\
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O.OEO
'20:00' ' ' ' '21:00 22:00 ' Ti«e
rilesS975832 #1-848 Acq:ll-SEP-1997 11:39:38 EH- Voltage SIR 70S Noise: 43
333.9338 Tt2 BSUB(256, 30, -3. 0) PKD(7, 5,3,0 ,05\, 172. 0,1. 00\,r,T) Exp:EPCUS
TRIANGLE LABS Text:TLI LCSD 0X1*43085 IKT. TIME - 11:42
1001
80:
601
40:
20.
0
19^00'
A2.60E7 6.3E6
Al . 69E7
A
,
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'20:00 21:00 22:00 ' ' ' ' liae
rile:S975832 #1-848 Acg;ll-SEP-1997 11:39:38 II* Volt age SIX 70S JK>i«e:29
327.8847 T:3 BSUB(256,30, -3 .0) PKD( 7,5,3, 0.05\,116. 0,1. 00\,r,T) ExpsEPCDS
TRIANGLE LABS TextsTLI LCSD TLH43085 IKT. TIME - 11:42
100J
80.
60.
40.
20.
0
AS
A . • - - V_
19:00'
5E5
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-1.3E5
-1.1E5
-.8.0E4
L5.3E4
L2.7E4
• 0 . OEO
'20:00 21:00 22:0o' ' ' ' Time
rile:S975832 #1-840 Ac
-------
FlleiS97S832 #1-848 Aoqtll-SXP-1997 11:39:38 EI+
Voltage SIX 70S Koimet35
339.8597 T:2 BSU*(256,30, -3.0) PKD(7,5,3, 0 .05\,140.0, 1.00\rr,T) XxptXTCOS
TRIANGLE LABS TextlTLI LCSD TLH43085
1003
ao:
60:
40:
20:
ol.
IHJ. TIME - Hi 42
. . A1.10X7 -3.6X6
AJL . (/>£/ |
' 23:00 24«00 '
Tile i S9 75832 #1-848 Acqtll-SEP-1997 11:39:38 EI+
1 ft
/ V / V
.2.9E6
.2.2X6
.1.4X6
.7.2X5
0.0X0
' 25:00 ' ' ' 26\00 Time
Voltage SIX 70S Noifei40
341.8567 Tt2 BSUB( 256, 30, -3 .0) PKD(7,5,3,0.05\,160.0,1.00\,T,T) ElptEPCUS
TRIANGLE LABS TeztsTLI LCSD TLI#43085
1001
•
80:
60:
40.
20:
0:
IHJ. TIME - 11:42
A7.20X6 -2.4X6
A7.18X6 I
'23:00 24:00 '
F±le:S975832 #1-848 Acq:ll-SEP-1997 11:39:38 EI+
|
H }\
.1.9X6
.1.4X6
.9.6X5
.4.8X5
O.OfO
25:00 26:00 Time
Voltage SIR 70S Noise 1 35
351.9000 F:2 BSUB(256, 30, -3. 0) PKD( 7,5, 3, 0. 05\,140. 0,1 . 00\,F, T) Exp:EPCUS
TRIANGLE LABS Tejct:TLI LCSD 1ZJM3085
1001
80:
60:
40:
20:
o:
JJKT. TIME - 11:42
A2.10E7 6.8X6
23 1 00 ' 24 I 00
FileiS975832 #1-848 Acq:ll-SEP-1997 11:39:38 EI+
j V
.5.4X6
_4 . 1E6
.2. 7E6
.1.4X6
o.Qr.o
25:00 261-00 Time
Voltage SIR 70S Noise: 33
353.8970 F:2 BSUB(256,30, -3. 0) PKD(7,5,3, 0. 05\,132. 0,1. 00%,*, T) EipsEPCUS
TRIANGLE LABS Teit:TLI LCSD TLI#43085
1003
ao'-
60'.
40.
20.
0.
23 ':00 24*:00^
INJ. TIME - 11:42
A1.34X7 -4.3E6
n •
|
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.3 . 4E6
.2.6X6
.1 . 7X6
.8.6E5
0.0 EO
25:00 26:00 Time
F±le:S975832 #1-848 Acq:ll-SEP-1997 11:39:38 EI+ Voltage SIR 70S
330.9792 F:2 Exp:EPCUS
TRIANGLE LABS TeitsTLI LCSD TLI*43085
100}
80.
60.
40.
20.
0.
„.„ 23:27 24.-05 24:22
•^"^ --a, i ^^.*w l^^u..v^^ >* Jv± jVtj---^^—- ~^~> J'n*~'
v^^/~v»^^^^vvv — v>-^~^ v\/-v~ ^rv^v^v-^
23': 00 24:00
IKJ-. TIME - 11:42
24:45 25:01 25:22 J5jt*^v-> 2£*££~2§jJ£*™-*7 r7-3E6
.5.8E6
.4.4X6
.2.9X6
.1 . 5E6
o . ono
25:00 26:00 Tine
File:S975832 #1-848 Acq:ll-SEP-1997 11:39:38 EH- Voltage SIR 70S
409.7974 F:2 Exp:EPCUS
TRIANGLE LABS Text:TLI LCSD TLIf 43085
100.
80.
60.
40.
20.
0.
;
24:02
i 22:58 33, is 33(33 A I
\JH-J\*jhJ*jh}ttJl^-J*AA^^
23:00 24:00
JJKT. TIME - 11:42
'< 34 -1.3X4
25:47
25:26 |
Aj^!JiL\AL}^
.1.1X4
-.8.1E3
.5.4X3
-.2.7X3
• a . ava
25 tOO 26:00 Time
278
-------
FUei
355. B
TSIAK
ion
so:
60:
40.
20:
o: .
S975832 tl-*4ll AOqill-SSf-19H7 lit IS 1 39 11+ Voltage SIM 70S NOlfetJl
546 Ti2 BSUB(256,30,-3.0) PKD(7,5,3,0.05\,124.0,1.00\,r,T) ExptETCUS
KLX LABS T«rtiTLJ LCSD TLH430S5 JJK7. Tlttf - 11 1 42
A7.24X6
l\
24\oo as'ioo .... aeiigo
filetS975832 91-848 Acqill-SEP-1997 lit 39 -.38 EH- Voltage SIS 70S KOiae:34
357.8516 n2 BSOB(256, 30, -3 .0 ) PKD(7,5,3t0.05\,136.0r1.00\tr,T) ExptEPCVS
TRIANGLE LABS TextsTLI LCSD TLH430B5 IKJ. TIKE - 11:43
1001 A4.41E6
80.
so:
40.
20.
0'
rile
367.
TXIA.
1001
ao:
so:
40:
20:
0
rile
369.
TRIf
1001
ao.
60.
40.
20.
0
nit
330
TRI.
100
ao
so
40
20
0
11
24:00 2S':00 26\00
IS975832 tl-848 Ac? ill -SEP- 1997 11:39:38 EH- Voltage SIX 70S tfoiae:29
8949 r:2 BSVB( 256,30, -3. 0) PKD( 7,5,3, 0. 05\f116. 0,1. 00\,r, T) ExpiEPCVS
NGLE LABS Text.-IXJ LCSD TLH43085 I1KT. TIME - 11:42
A1.18E7
f\
I Al . 09E6
} \y\
24':00 251-00 26': 00
:S975832 tl-848 Acqsll-SEP-1997 11:39:38 EH- Voltage SIR 70S Hoiae:34
8919 T:2 BSUB(256, 30, -3.0) PKD( 7,5,3, 0. 05\,136. 0,1. 00\,r,T) Exp:EPCUS
WGLE LABS TejctsTLI LCSD TLH4308S IKJ. TIME - 11:42
A7 99E6
\
1
\7.22E5
1 \S\
24\00 ' ' ' ' .25:00 ' ' ' 26\00
*tS975832 H-848 Acqt ll-SEP-1997 11:39:38 Eli- Voltage SIR 70S
.9792 Ti2 ExptEPCOS
WGLE LABS TextiTLI LCSD TLH43085 XJK7. TIME * lit 42
\^^j°^^^^~^^ w^-
-
;
24'tOO 25»00 26\00
3.mf
ja.rn*
j.aa*
l.OES
.5.10
XlM
.l.fXt
.1.3X9
.S. 793
.6. SMS
.3.2X3
O.OEO
Time
.3 . 9E6
.3 . 1S6
-2.3E6
'.1 . 5ES
'.7.7E5
0 . OEO
Time
2.6E6
.2.1E6
'.1 . SE6
.1 . OE6
.5.2E5
O.OEO
Time
-7.3E6
\ •
'.5.8E6
'.4 . 4X6
.2.9X6
.1.5X6
0.0X0
Time
27
-------
il»:S975832 tl-406 Aoqtll-SXP-1997 Ilt39i38 XI+ Volt*?* 3IX 70S Moim»t746
73.8208 T*3 BSOB(256,30,-3.0) PKD(7,5,3,0.05\r2984.0,1.00\,T,T) XxptXPCUS
TXIANGLE LABS TmxtsTLI LCSD TLIf43085 IHJ. TIMM - lit42
00* Al J.5X7
Time
27:12 37:24 27,36 27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12
iletS97S832 tl-406 Acgtll-SEP-1997 Ilt39i38 XI+ Voltage SIS 70S Nolle:397
75.8178 Fi3 BSUB(256,30,-3.0) PKD(7,5,3,0.05\,1588.0,1.00\,r,T) XxptXPCOS
TRIANGLE LABS Text:TLI LCSD TLI*43085 IXJ. TIME - Us43
00\ A8.92E6 -3.2X6
80:
60:
to:
20:
A 8.65X6
A8.43X6
.3.9X6
.3.1X6
.2.3X6
.1.5X6
.7.7X5
0.0X0
80:
60:
40:
20:
A6.76E6
A6.37X6
.2.5X6
.1.9X6
.1.3X6
'.6.3X5
0.0X0
27:12 27:24 27:36 27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12
rile:S975832 tl-406 Acq:ll-SEP-1997 11:39:38 XI+ Voltage SIX 70S lK>iae:583
83.8639 T:3 BSOB(256,30, -3. 0) PKD(7,5,3, 0. OS\,2332.0,1. 00\,T, T) EiptEPCUS
TRIANGLE LABS Text:TLI LCSD TLH43085 IlKT. TIKE - 11:42
Time
1003
80:
60:
40:
30.
0:
A9.83E6
A9.73E6
A8.31E6
_ 3. 7E6
.2.9E6
.2.2E6
.1.5E6
.7.4E5
O.OEO
Tim
27:12 27:24 27:36 27:48 38:00 28:12 28:34 38:36 28:48 39:00 29:12 29:24 29:36 29:48 30:00 30:12
Fj.leiS975832 H-406 Acq:ll-SEP-1997 11:39:38 EI+ Voltage SIX 70S SOiae:1059
385.8610 T:3 BSOB(256,30,-3.0) PKS(7,5,3,0.05\,4236.0,1.00\,r,T) Exp:EPCVS
TSIAJfSLE LASS Text.'IIJ LCSD TLI#43085 IXJ. TIME - 11:42
100$ A1.98E7 A1.95E7 -7.1E6
80:
60:
40:
so:
0.
Al.64E7
.5.7E6
.4.3E6
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27:12 27:24 27:36 27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12
T±le:S975832 tl-406 Ac
-------
27148 28:00 28tl2 28:24 28i36 28:48 29tOO 29tl2 29': 24 29': 36 29:48
lle:S975832 tl-406 Acq:ll-SEP-1997 11:39:38 XI* Voltage SIX 70S Koi*»t296
91.8127 r:3 BSUB(256,30,-3.0) PKD(7,5,3,0.05\,1184.0,L.OO\,r,T) Exp:EPCOS
TRIANGLE LABS TextiTLI LCSD TLIf 43085 JKJ. TIMS - Hi42
27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36
rile:S975B32 tl-406 Acq:ll-SEP-1997 11:39:38 Eli- Voltage SIX 70S Noiae:927
01.8558 F:3 BSUB(256,30, -3 . 0) PKD(7,5,3, 0. 05\,370S. 0,1.00%,T, T) ExpiEPCUS
TRIANGLE LABS Text:TLI LCSD TLI#4308S rWJ. TIME - lit42
lOOi A1.84E7
mian/iaj^ r±-4vo AcqilJ.-aff-J.yy' iiu>»j« fif vt^Lfmgm SIM 7va HoitfUjy
89.8156 T:3 BSUB(256,30,-3.0) PXD(7,5,3,0.OS\,1756.0,1.00\,T,T) ExpiXPCOS
IAJKLE LABS TfXtiTll LCSD TLH430S5 JKJ. TIM* - 11,42
00* A6.67E6 A6.78E6
ao:
so:
40.
20.
,.2.
J1.4M
'.9.6X5
.4. US
OOJ
ao.
60.
40.
20.
0_
A5.44E6
A5.46E6
2.0X9
.1. 6X6
.1.2ft
.8.0E5
.4.0E5
29:48
so:
so:
-------
ril«:SS 75832 tl-430 Acq: ll-SEP-1997 11:39:38 XI+ Voltage SIR 70S Hoi**: 15 8 5
407.7818 Ti4 3SV3(256,30,-3.0) PXD(7,5,3,0.05\,6340.0,1.00\,r,T) XxptEPCUS
TRIANGLE LABS TexttTLI LCSD TLI443085 1X7. TIME " 11:42
1004 A6.J2E6
80:
SO.
40.
20:
A
/ I A4.66X6
1 \ f^
\ A
l\ A
' 3lil2' ' ' 31»24 ' ' '31:36' '.31:48' ' ' 32:00 ' 32»12 32*24
rileiS975832 tl-430 Acq:ll-SEP-1997 11:39:38 XI+ Voltage SIR 70S Noia»:390
409.7789 P:4 3303(356, 30, -3 .0) PXD(7, 5,3,0. 05\,1S60 .0,1.00\,r,T) XxpiEPCUS
TRIANGLE LABS TttxtlTLI LCSD TLH43085 IKT. TIME • 11:42
1004 A6.33E6
80:
60:
40J
20:
0
rile
417.
TRIA
1003
80:
60:
40:
20:
0
rile
419.
TRIA
1003
sol
60.
40.
20.
0
rile
430.
TRIl
1001
80.
60.
40.
20.
0
rilt
479
TRIl
100.
SO.
60.
40.
20.
0
A
/ \ A4.28E6
II A
\ A
l\ i\
31\12 31:24 31:36 31:48 32:00 32:12 32:24
1S975832 tl-430 Acq:ll-SEP-1997 11:39:38 EH- Voltage SIR 70S Noiae:516
8253 r:4 BSUB(256,30, -3 .0) PKD(7, 5,3,0. 05\,2064 .0,1. 00\,r,T) Exp:EPCOS
NGLE LABS Tejct:TLI LCSD TLH43085 INJ. TIME - 11:42
AS . 56E6
A
/ V
31:12 31:24 31:36 31:48 32:00 32:12 32:24
•.S975832 tl-430 Acq: ll-SEP-1997 11:39:38 EH- Voltage SIR 70S Noiae:315
8220 F:4 BSUB ( 256 , 30, -3 . 0 ) PKD( 7, 5,3, 0 . 05\,1260. 0,1 . 00%, JT, T) Erp:EPCUS
NGLE LABS Taxt:2IX LCSD TLIt430S5 JK7. TIME * 11:42
Al . 32E7
A
A
\
/ V
31:12 31:24 31:36 31:48 32:00 32:12 32:24
'•.S975832 tl-430 Acq:ll-SEP-1997 11:39:38 EI+ Voltage SIR 70S
9729 r:4 ExptEPCUS
\NSLE LABS Text:TLI LCSD TLIt43085 JK7. TIKE - 11:42
•\f^-J^S*^-~^^^ — ^V^^^^^^-^^^y^
31:12 ' 31^24 ' ' 31:36' ' 31:48 ' ' 32:00 ' ' ' 32'tia' ' '32:24
i:S975832 tl-430 Acq: ll-SEP-1997 11:39:38 EH- Voltage SIR 70S
7165 F:4 ExpsEPCVS
WSLE LABS Text:TLI LCSD TLIt43085 IKT. TIME - 11:42
jj 31:43
: 31:31 |I
^x^WjJl^
31; 12 31i24 31:36 31t48 32:00 32:12 32': 24
-2.0I6
:
1.6X6
1.2X6
8.1X5
.4.1X5
.0.0X0
32i 36 32:48 Time
-1.9X6
32:36 32:48
321-36 32:48
' 32:36 ' ' ' 32:48 '
* 32; -.39
s/'-'-'S^- V^/^^"^
.1.5X6
.1.1X6
.7.6X5
.3.8X5
0.0X0
Time
.1.6X6
.1.3X6
'-.9.5X5
.6.4X5
.3.2X5
O.OEO
Time
3 . 8E6
.3.0X6
'.2.3X6
.1.5X6
.7.5X5
O.OEO
Time
2.8X6
.2.2E6
Ll . 7X6
.1 . 1X6
.S.5ES
O.OEO
32:36' ' ' 32:48 Time
32:42
32s 33 AAA l\J\n A
.1.1X4
.8.1X3
.5.4X3
.2.7X3
- O.OfO
32:36 32:48 Mae
282
-------
'i±»,S975B33 91-430 Aoqill-sSf-1997 11,39,38 K* Volt*?* SIS 703 «ol*e:577
23.7766 Tt4 BSUB(256,30,-3.0) PXD(7,5,3,0.OS\,2308.0,1.00\,T,T) XxpiXPCUS
TRIANGLE LASS TextsTLI LCSD TLIH3085 XX7. TIMS - 11,42
00% A4.44E6
80.
60.
40.
201
31:18 31i24 31i30 31t36 31,42 31,48 31:54 32', 00 32:06 32,12 32,18
ile:S975832 #1-430 Acq,ll-SEP-1997 11,39,38 XI* Voltage SIX 70S Soime,211
25.7737 F:4 BSUB(256,30,-3.0) PKD(7,5,3,0.05%,844.0,1.00\,F,T) Xxp:EPCVS
TRIANGLE LABS TextsTLI LCSD TLH43085 INJ. TIME - 1J j 42
00\ A4.28X6
80.
60.
40.
201
,4.1**
.•.7X3
.8.5X3
14.3X3
.2.1
'.9.
32,24 32,30
-1.1X6
'.». 4X5
.6.3X3
.4.2X5
'.2.1E5
31,18 31(24 31:30 31,36 31:42 31,48 31:54 32:00 32:06 32:12 32,18
Tile:S975S32 »1-430 Aoqill-SEP-1997 11,39,38 EI+ Voltage SIS 70S HOiae,634
35.8169 r-.4 BSUS(256,30,-3.0) PKD(7,5,3, 0. 05\,2536. 0,1. 00\,T, T) EzpsEPCOS
TRIANGLE LABS T*Xt,TLI LCSD TLI#43085 INJ. TIME - 11,42
10 0\ A9.21E6
80J
eo:
401
20.
32:24 32:30
31,18 31,24 31:30 31:36 31:42 31:48 31:54 32:00 32:06 32:12 32:18
•ile,S975832 tl-430 Acqsll-SEP-1997 11:39:38 EI+ Voltage SIX 70S Soiae:650
437.8140 T:4 BSOB(256,30, -3.0) PKD(7,5,3,0.05\,2600.0,1.00\,T,T) ExptEPCUS
TRIANGLE LABS TextsTLI LCSD TLIt43085 ISJ. TIME - 111 42
1001 A9.26E6
801
60.
401
20.
32:24 32:30
.O.OEO
Time
2.1E6
1. 7E6
.1.2E6
.8.3X5
.4.2X5
.O.OEO
Tim.
31:18 31:24 31,30 31,36 31:42 31:48 31:54 32:00 32,06 32,12 32,18 32:24 32,30
rile:S975832 tl-430 Acq:ll-SEP-1997 11,39:38 EH- Voltage SIX 70S
430.9729 T:4 ExpiEPCUS
TRIANGLE LABS Iext:TLI LCSD TLI»43085 INJ. TIME - 11:42
.2.2X6
11.8X6
-1.3X6
8.8X5
4.4X5
100*31:18
80.
60.
40.
20.
0.
31,29
31:42
31:58
32:12
32:29
31:18 31:24 31:30 31:36 31:42 31:48 31,54 32:00 32:06 32:12 32:18 32,24 32,30
0.0X0
Tim
2.6X6
2.1X6
.1. 6X6
.1.1X6
.5.3X5
0.0X0
Tim
283
-------
Til*tS975832 fl-430 Acq: ll-SEP-1997 11:39:38 XI+ Voltage SIX 70S Holfe:39
441.7428 ri4 BSOBf 250,30,-3.0> PKDf 7, 5,3,0.05%, 150. 0,1.
TSIAHGLX LABS T*xt:TLI LCSD TLH43085
1001
901
801
701
601
50.
40.
30:
20j
10J
01
4
31*00 32*00 33*00
00\,f,T) XXptXfCUS
Her. TIHX - 11*42
A5.24X6
ft
\
J V^
.ff.jrs
.0.225
.5.5*5
.4.8X5
.4.1X5
.3.4X5
.2.8X5
.2.1X5
.1.4X5
.0.9X4
0.0X0
34*00 35:00 £!••
File:S975832 fl-430 Acq: ll-SEP-1997 11:39:38 EH- Voltage SIR 70S Noise, 265
443.7399 T:4 BSUB(256,30, -3. 0) PKD(7 ,5,3,0 ,05\,1060 .0,1. 00\,T,T) XxpiEPCDS
TRIANGLE LABS Texts 1X1 LCSD 1X1*43085
100J
901
801
701
601
501
401
301
201
101
01
31:00 32:00 33:00
IKJ. TIME - 11*42
A5.93E6
\
\
J V
_8.0X5
_7.2X5
_5.4E5
L5.SX5
L4.8E5
L4.0X5
L3.2E5
.2.4X5
.1 . 5X5
.8.0X4
0.0X0
34:00 ' 35*00 Time
r±le:S975832 #1-430 Acq: ll-SEP-1997 11:39:38 EI+ Voltage SIR 70S
430.9729 T:4 ExptEPCUS
TRIANGLE LABS Text.-ZXI LCSD 0X1*43085
1003
901
801
70.
601
501
401
301
20.
!\ A ^(°9A 31:42 32:12 33:09
1 1 Jii ft* n iu AAJ\< kh> A »J^*Ji' i
V^W^^^
' i I* u rv VW VT v
i-o|
of
31:00 32:00 33*00
IWJ. TIME - 11:42
//WtfAMJlkKjVJlli-30 35l°9 ":44
^^^MAVW^^Y^
! " y v vy^ v \M
2.8X5
.2.5X5
^2.2X6
Ll . 9X6
Ll . 7X5
Ll . 4X5
Li.ixff
L8.3X5
L5.5X5
Is.ass
'• a . ox a
34:00 . 35:00 Time
f±le:S975832 fl-430 Acq: ll-SEP-1997 11:39:38 EH- Voltage SIR 70S
513.6775 T:4 ExptEPCUS
TRIANGLE LABS Text* 2X1 LCSD TLIf 43085
1001
90.
80.
70.
60.
SO.
40.
30.
20.
10.
0.
31 : 51
1 32*32 33*03
1 I31?" i , ll P
i i r. | | i. MI i
(yuMijUllL^
31*00 32:00 33*00
XK.T. TIMX - 11*42
33:3S 34 2i
34:45
>2Sl 34,11 35,04
1 II ll 1 1 1 1 II 35*27
yiy^
-.7.7X3
:7.0X3
L5.2X3
.5.4X3
.4.0X3
.3.9X3
.3.1X3
IE.2.3X3
1.7.7X2
t n nrn
34 >00 35*00 ri»«
284
-------
34:24 34i30 34:36 34:42 34,48 34:54
•±l»iS975832 tl-430 Acq:ll-SEP-1997 11:39:38 EH- Voltage SIX 703 Noi*»:37
59.7348 F:4 BSDB(256,30,-3.0) PKD(7,5,3,0.OS\,148.0,1.00\,f,T) XxptXPCUS
TRIANGLE LABS Text < IXJ LCSD TLIt43085 1X7. TIKE - 11:42
OOi, A5.74E6
BO:
SO.
40.
20.
**8975oj2 tl-430 Aoq111-SIP-1997 11:39:38 EIr Voltage SIM 70S Nairn*1221
57.7377 rt4 BSVB(256,30,-3.0) PKO(7,5,3,0.05\,884.0,1.00\,T,T) XxpiXTCOS
IANGLX LABS TmxttTLI LCSD TLH43085 IJKT. TIME - Hi42
00\ A4.
80.
SO.
40.
20.
75X6
34:24 34:30 34:36 34:42 34:48 34:54
•±le:S975832 #1-430 Acq:ll-SEP-1997 11:39:38 EH- Voltaye SIS 70S NoiBe:342
469.7779 T:4 BSUB(256,30, -3. 0) PKD(7,5,3, 0.05\,1368. 0,1. 00\,T,T) Elp:EPCUS
TRIANGLE LABS Text:IXI LCSD TLIt43085 IKT. TIME - 11:42
10 Oi: A9.83ES
so:
so:
40:
20:
34:24 34:30 34:36 34:42 34:48 34:54
rile:S975832 tl-430 Acq:ll-SEP-1997 11:39:38 EI+ Voltage SIR 70S Noiee:37
471.7750 r:4 BSUB(256,30r-3.0) PKD(7,5,3,0.05\,148.0,1.00\rr,T) Cxp:EPCUS
TRIANGLE LABS TartsTLI LCSD TLH43085 IKJ. TIME - II -.42
100\ A1.13E7_
80.
SO.
40.
20.
34:24 34:30 34:36 34:42 34:48 34:54
rile:S975832 tl-430 Acqtll-SEP-1997 11:39:38 EI+ Voltage SIR 70S
430.9729 f:4 ExpiEPCUS
TRIANGLE LABS TextlTLI LCSD TLIt43085 JWJ. TINT - 11:42
3±i24 _ 34j^0 34:41
-3.0*3
.4.50
.3.4*5
.2.3X3
.1.1X3
35100
e.txe
ttmmk
35:00
1.1E6
'.9. 2E5
.6.9E5
'.4.6ES
.2.3E5
35:00
.O.OEO
Tim
.1.3E6
.1. OE6
_7.8E5
',5.2X5
"-2.6ES
35:00
.O.OEO
Tim
80.
60.
40.
20.
0.
34:58
34:24
34:30
-2.4E6
-1.9E6
L1.4E6
.9.5X5
.4.7X5
0.0X0
34:36
34:42
34:48
34:54
351 00
285
-------
fl=33U971
I Channel I 338,3782 tak l.op
| Height 3,25 uoLts Span 288 ppi
Systei file naae
Oka file nate
Resolution
Group nmber
lonlzatlon node
Switching
Ref, lasses 282,3825,
fl 293 J "331
3 384 K 332
C 386
0 316
E 318
F 328
6 322
H 328
I 331
L 334
H 348
H 342
0 352
P 354
Q 356
R 358
2
El*
VOlTflGE
416,3768
S 368
T 379
I) 376
V 418
Ref, lass 416.9768 Peak top
,72 volts Span 288 ppi
286
-------
TLI Project: 43085
Client Sample: TLI LCS
Method 23 PCDD/PCDF Analysis (a)
Analysis File: S975831
Client Project:
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
S413-004
XAD
TLI LCS
1.000
n/a
DB-5
Date Received:
Date Extracted:
Date Analyzed:
Dilution Factor:
Blank File:
Analyst:
II
09/04/97
09/11/97
n/a
S975815
BJG
Spike File:
ICal:
ConCal:
% Moisture;
% Lipid:
% Solids:
SPX23704
SF56117
S975814
n/a
n/a
n/a
Ahalytes
2,3,7,8-TCDD
1,2,3,7,8-PeCDD
1,2,3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
1,2,3,4,6,7,8-HpCDD
1,2,3,4,6,7,8,9-OCDD
2,3,7,8-TCDF
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
1,2,3,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
1,2,3,4,6,7,8,9-OCDF
internal Standards
l3C12-2,3,7,8-TCDF
3C,2-2,3,7,8-TCDD
l3C,2-l,2,3,7,8-PeCDF
!3C,2-l,2,3,7,8-PeCDD
13Ci2-l,2,3,6,7,8-HxCDF
13C,:-l,2,3,6,7,8-HxCDD
13C,2-l,2,3,4,6,7,8-HpCDF
13C,2-l,2,3,4,6,7,8-HpCDD
13C,2-1,2,3,4,6,7,8,9-OCDD
Amt (ng)
0.36
1.8
1.8
1.8
1.8
1.7
3.4
0.36
2.0
1.8
1.7
1.7
1.6
1.5
2.1
1.5
2.7
AmL (ng)
2.6
2.5
2.6
2.8
2.9
2.9
2.3
2.6
4.5
,0t EMPC
% Recovery '
64.9
62.6
65.3
69.4
72.8
73.1
58.4
64.5
56.7
QC Limits
40%-130%
40%- 130%
40%-130%
40%- 130%
40%-130%
40%-130%
25%-130%
25%-130%
25%-130%
ftatie
0.83
1.49
1.24
1.24
1.27
1.05
0.84
0.78
1.55
1.53
1.29
1.29
1.30
1.29
1.07
1.10
0.89
Ratio
0.76
0.82
1.52
1.44
0.49
1.23
0.43
1.03
0.85
fit
21:14
25:52
29:07
29:12
29:29
32:04
34:37
20:24
24:43
25:29
28:22
28:28
28:59
29:42
31:11
32:24
34:42
m
20:23
21:13
24:42
25:50
28:27
29:11
31:11
32:04
34:36
Ffeg*
—
Flags
Page 1 of 2
X237_PSR T2.00. LARS 6.10.O
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 12:02
-------
TLI Project: 43085
Client Sample: TLI LCS
Method 23 PCDD/PCDF Analysis (a)
Analysis File: S975831
Alternate Standards CType A> , Arat
QC Limits , ,„. .. Ratio,
Flags
13C12-l,2,3,7,8,9-HxCDF
13C,2-2,3,4,6,7,8-HxCDF
2.9
3.0
72.3
76.2
40%-130%
40%-130%
0.49
0.50
29:41
28:58
Recovery Stamfords
Ratk>
srr
Ftegs
13C12-1,2,3,4-TCDD
13Ci2-l,2,3,7,8,9-HxCDD
0.80
1.21
20:59
29:28
Data Reviewer
» , .• •
09/18/97
Page 2 of 2
X237J-SR vZOO.LARS6.IOW
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 12:02
-------
Initial
....Data...
Data Review By:
Calculated Noise Area: n/a
The Total Area for each peak with an ion abundance ratio outside
ratio limits has been recalculated according to method requirements.
Page No.
09/18/97
Listing of S975831B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OX .Ratio Total.Area... Area.Peak. 1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flag*.
TCDF
304-306
304-306
0.65-0.89
DC
DC
DC
DC
DC
DC
DC
DC
ML
SN
SN
SN
SN
SN
SN
WH
2
0:
16:
18:
19;
19:
19:
20
21
22
22
00
55
53
:15
:30
:55
:24
:55
:15
-.41
RO
RO
RO
RO
RO
RO
1.
1.
0.
0.
1.
0.
0.
6
0
0
14
10
68
,37
.09
.66
.78
.53
.24
.46
Peaks
0.
0.
2.
44.
4.
19.
436.
0.
1.
1.
480.
12
92
35
31
07
67
34
30
54
79
.65
20.57
190.91
0.820-1.101
0.000
0.330
0.926
23.74 0.944
0.957
0.977
245.43 1.001 2378-TCDF
1.075
1.092
1.113
AN
13C12-TCDF
316-318
316-318
DC
DC
DC
DC
DC
NL
WL
SN
SN
WH
2
0:
18:
19:
19:
20:
20
21
00
.04
:31
:55
:23
:53
-.43
0.
RO
RO
RO
RO
RO
65-
20.
1.
1.
0.
0.
0.
1
0.89
00
19
02
.79
.76
.95
.55
Peaks
0.
3.
8.
23.
3,872
26
3
3,899
11
.63
.30
.27
.82
.36
.27
.18
0.951-1.049
0.000
0.886
0.957
0.977
1,677.61 2,195.21 1.000 13C12-2378-TCDF ISO
14.17 14.89 1.025
1.065
Above: TCDF / TCDD Follows
TCDD
320-322
320-322
0.65-
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
WH
WH
WH
1
0:
18:
18:
18:
19:
19:
19:
20;
21
21
21
22
22
22
22
00
08
17
52
17
32
:53
;51
:00
:14
:46
:19
:29
:34
:48
RO
RO
RO
RO
RO
RO
RO
RO
RO
0.
1.
0.
0.
0.
1.
0.
2.
0,
0
0
0
1
1
2
0.89
75
18
84
32
74
38
29
.71
.83
.83
.13
.69
.63
.16
.02
Peak
0.
0.
1.
0.
1.
0.
2.
0.
1.
321
0
1
0
0
0
321
14
78
34
41
08
46
,51
.50
.90
.68
.71
.42
.90
.80
.83
.68
145.74
0.853-1.059
0.000
0.855
0.862
0.889
0.909
0.921
0.937
0.983
0.990
175.94 1.001
1.026
1.052
1.060
1.064
1.075
2378-TCDD
AN
Triangle Laboratories, Inc.® Analytical Services Division
801 Cap'rtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 12:02 09/1J
-------
Page No.
09/18/97
Listing of S975831B.dbf
Matched GC Peaks / Ratio / R«t. Tin
Compound/
M_Z QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound. Name. . ID.
Flags.
13C12-TCDD
332-334
332-334
PeCDF
340-342
340-342
13C12 -PeCDF
352-354
352-354
PeCDD
356-358
356-358
13C12-PeCDD
368-370
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
SN
3
NL
SN
SN
3N
SN
4
NL
SN
SN
SN
SN
SN
2
NL
SN
SN
SN
SN
SN
SN
SN
SN
WH
1
NL
SN
0:00
19:54
20:59
21:13
21:35
Peaks
0:00
23:21
23:50
24:21
24:43
25:01
25:21
25:29
26:27
Peaks
0:00
23:46
24:20
24:42
25:00
25:29
25: 50
26:26
Peaks
0:00
23:55
24:14
24:30
24:44
24:52
25:03
25:29
25:52
26:04
26:49
Peak
0:00
24:43
0.
RO
RO
RO
1.
RO
RO
RO
RO
RO
1.
RO
RO
RO
RO
1.
RO
RO
RO
RO
RO
RO
RO
RO
RO
1.
RO
65-0.89
41.
1.
0.
0.
0.
32-
1.
0.
1.
1.
1.
1.
1 .
1.
1.
32-
1 .
1.
1.
1.
1.
1.
0.
1.
.32-
3.
0.
1.
2.
2.
1.
0.
13.
1.
1.
1.
,32-
0.
1.
00
09
80 4
82 3
98
7
1.78
00
36
69
29
55 1
81
61
53 1
08
3
1.78
00
63
07
52 3
17
73
38
64
3
1.78
71
12
34
44
27
30
91
40
49 1
19
84
1
1.78
67
60
0.
15.
,527.
,018.
48.
,595.
Tf*nf
1 \~Ul
0.
i.
57,
31,
,871.
18,
1,
,701,
5,
,662.
0
33
12
,350
13
29
2
8
11
.06
,59 2,013.14
86 1,360.65
73 27.07
,18
,12
,18
.61 36.16
.72 19.28
.54 1,137.04
.92
.28
.84 1,028.85
.92
.71
.13
.25 20.62
.27
•64 2,023.45
.93
.76
.12
.98
0.906-1.094
0.
0.
2,514.45 0.
1,658.21 1.
27.53 1.
0.907-
0.
0.
21.45 0.
14.99 0.
734.50 1.
1.
1.
672.99 1.
1.
0.338-
0.
12.63 0.
0.
1.327.19 1.
1.
1.
1.
1.
000
938
989 13C12-1234-TCDD
000 13C12-2378-TCDD
017
1.078
000
945
965
986
001 12378-PeCDF
013
026
032 23478-PeCDF
071
1.162
000
962
985
000 13C12-P6CDF 123
012
032 13C12-PeCDF 234
046
070
RSI
IS1
AN
AN
IS2
SUR2
,383.89
PeCDF / PeCDD Follows --
0
1
2
0
4
5
3
0
,148
2
1
,148
0
5
.18
.12
.50
.99
.46
.30
.98
.26
•66 687.54
.42
.91
.66
.10
.96
0.921-1.026
0.
0.
0.
0.
0.
0.
0.
0.
461.12 1.
1.
1 .
000
926
938
948
957
963
970
986
001 12378-PeCDD
009
038
AN
0.845-1.155
0.000
0.
957
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 12:02 0
-------
Page No.
09/18/97
Listing of S975831B.dbf
Hatched GC Peaks / Ratio / Ret. Time
Compound/
M_z.... QC.Log omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. IB.. Tl*a*.
368-370
HxCDF
374-376
374-376
13C12-HXCDF
384-386
384-386
HxCDD
390-392
390-392
13C12-HXCDD
402-404
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
2
NL
SN
SN
SN
SN
WH
4
NL
SN
SN
SN
SN
SN
4
NL
SN
SN
SN
SN
WH
WH
3
NL
SN
SN
25:50
25:59
Peaks
0:
27:
27:
28:
28:
28:
28:
29:
29:
30:
00
23
30
22
28
40
59
09
42
03
1.
RO
RO
RO
1.
1.
44
46
1,995.
191.
2,186.
n«/*r^
19
37
56
1 / UuC
.05-1.43
1.
1.
1.
1.
1.
1.
1.
0.
1.
1.
35
51
25
29
29
13
30
91
29
58
Peaks
0:
27:
27:
28:
28:
28:
29:
29:
29:
29:
00
21
30
27
45
58
26
33
41
53
0.
RO
RO
RO
RO
RO
43-
0.
0.
0.
0.
1.
0.
0.
0.
0.
0.
Peaks
0:
28:
28:
28:
28:
29:
29:
29:
29:
29:
00
21
36
40
47
07
12
29
39
49
1.
RO
RO
RO
RO
RO
,05-
1.
2.
1.
1.
2.
1.
1.
1.
12.
2.
0.59
90
50
58
49
65
50
21
41
49
23
1.43
00
22
33
07
00
24
24
27
48
02
Peaks
1
0:00
28:
12
28:35
29:
ill
RO
3.
11.
25.
1,377.
1,761.
3.
1,326.
2.
1,126.
1.
5,591.
2.
15.
36.
2,657.
1.
2,573.
2.
2.
2,122.
2.
7,389.
1.
1.
5,
1,
1
918
1,111
1,074
0
2
3,104
17
13
51
64
25
82
00
26
66
93
55
64
07
40
14
65
38
46
61
29
64
21
p / tivf
' / nXf,
.97
.77
.97
.14
.30
.94
.83
.04
.65
.15
.81
.05-1.43
1.15
1.
1.
32
.01
1.23
3
2
15
2,203
.80
.09
.39
.22
1,178.84 816.35 1.000 13C12-PeCDD 123
113.72 77.65 1.006
•nV »— 1 T ftt^fr
0.955-1.052
0.000
0.963
0.967
775.40 602.24 0.997 123478-HxCDF
990.49 770.76 1.001 123678-HxCDF
1.008
748.24 577.76 1.019 234678-HxCDF
1.025
634-74 491.92 1.044 123789-HxCDF
1.056
0.359-1.141
0.000
0.961
13.29 23.11 0.967
873.82 1.783.32 1.000 13C12-HXCDF 678
1.011
853.16 1.720.22 1.018 13C12-HXCDF 234
1.035
1.039
702.08 .1,420.21 1.043 13C12-HXCDF 789
1.050
0.950-1.015
0.000
0.971
0.980
0.982
0.986
508.80 410.14 0.998 123478-HxCDD
615.10 496.73 1.001 123678-HxCDD
599.89 474.15 1.010 123789-HxCDD
1.016
1.022
0.966-1.034
0.000
0.966
0.979
1,214.42 988.80 1.000 13C12-HXCDD 678
IS3
AN
AN
AN
AN
IS4
ALT2
ALT1
AN
AN
AN
IS5
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 12:02
-------
page No.
09/18/97
Listing of S975831B.db«
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_2.... QC.Log omit why ..RT. OK Ratio Total.Area... Area.Peak. 1.. Area.Peak.2.. Rel.RT Conpound.Name.. ID.. Flags.
402-404
HpCDF
408-410
408-410
13C12-HpCDF
418-420
418-420
HpCDD
424-426
424-426
13C 12 -HpCDD
436-438
436-438
OCDF
442-444
442-444
OCDD
458-460
458-460
2
DC NL
DC SN
DC WH
2
29:28
Peaks
1.21 3,029.99 1,661.33
5,233.21
XW.MM.. tt**tfTin / tiw*/*n9 9*0 1 Aue
0.88-1.20
0:00 RO 1.86
31:11
31:31 RO
32:24
32:45 RO
Peaks
1.07
0.55
1.10
0.74
nAWk/*s / n^sivksc' s wi A w«w
3.00
1,250.71 645.54
5.12
717.99 376.42
1.59
1,968.70
0.37-0.51
DC NL
1
DC NL
DC SN
DC WH
1
DC NL
DC SN
1
DC NL
DC SN
DC SN
DC SN
DC SN
DC SN
DC SN
DC SN
DC SN
0:00 RO
31:11
Peak
0.
0:00 RO
31:26 RO
32:04
32:16 RO
Peak
0.
0:00
31:26 RO
32:04
Peak
0.
0:00 RO
31:11 RO
31:44 RO
32:50 RO
33:34 RO
33:49 RO
34:13 RO
34:42
3 5 : 07 RO
35:28 RO
1.11
0.43
88-1.20
1.24
0.84
1.05
0. 65
88-1.20
1.08
1.39
1.03
.76-1.02
9.30
1.42
0.56
0.21
0.51
1.09
1.39
0.89
1.16
2.46
1 Peak
DC NL
0
0:00 RO
34:37
.76-1.02
6.00
0.84
1 Peak
1.37
1,570.80 471.35
1,570.80
HrsC^ni? / Ur%PnT"^ tTrtl 1 i*M*r« — —
tip*— Ur i ripv- ULj f o j. i ows — •*
1.77
7.75
724.96 370.95
1.73
724.96
3.27
12.12
1,592.57 809.60
1,592.57
0.09
1.47
0.62
0.59
1.40
1.74
1.42
914.71 431.72
1 .85
0.53
914.71
0.13
848.38 386.63
848.38
1,368.66 1.010 13C12-HXCDD 789
0.995-1.044
0.000
605.17 1.000 1234678-HpCDF
1.011
341.57 1.039 1234789-HpCDF
1.050
0.936-1.128
0.000
1,099.45 1.000 13C12-HpCDF 678
0.976-1.006
0.000
0.980
354.01 1.000 1234678-HpCDD
1.006
0.969-1.031
0.000
0.980
782.97 1.000 13C12-HpCDD 678
0.884-1.116
0.000
0.901
0.917
0.949
0.970
0.977
0.989
482.99 1.003 OCDF
1.015
1.025
0.884-1.116
0.000
461.75 1.000 OCDD
RS2
AN
AN
IS6
AN
IS7
AN
AN
Triangle Laboratories, Inc.® Analytical Services Division
801 Cap'rtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 12:
97
-------
Page No. 5 Listing of S975831B.db«
09/18/97 Hatched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound. Name.. ID.. Flagc.
13C12-OCDD 0.76-1.02 0.995-1.005
470-472 DC ML 0:00 RO 2.17 0.79 0.000
DC WL 34:22 RO 1.06 3.36 0.993
34:36 0.85 1,782.44 820.90 961.54 1.000 13C12-OCDD IS8
470-472 1 Peak 1,782.44
Column Description "Why" Code Description QC Log Desc.
M_2 -Nominal Ion Mass(es) WL-Below Retention Time Window A-Peak Added
..RT. -Retention Time (mn:ss) WH-Above Retention Time Window K-Peak Kept
Rat.l -Ratio of M/M+2 Ions SN-Below Signal to Noise Level D-Peak Deleted
OK -RO=Ratio Outside Limits
-------
ril»,S975831 #1-848 Acq:ll-SEP-1997 10:59>48 SI+ Voltagm SIR 70S Nairn* 1 38
303.9016 r>2 BSDB(256,30,-3.0) PKB(9,5,5,0.05\, 152.0, 1.00\,T,T) ExptXPCUS
TRIANGLE LABS TtxttTLI LCS TLH43085
1003
80:
60:
40:
20:
o:
17:00
A2.06E5
/\^
18:00 19:00
nur. TIMS -
A1.91E6
1 \
20:00 21:00
11:03
22:00
Tile:S975831 tl-848 Aoj:ll-SEP-1997 10:59:48 EH- Voltage SIR 70S Noitei34
-4 . 7S5
.3.8X5
-2. 8SS
.1.915
.9.5S4
Time
305.8987 T:2 BSUB(256,30,-3.0) PKD(9,5,5,0.05\r136.0r1.00\,r,T) ExptEPCUS
TRIANGLE LABS Text:TLI LCS TLH4308S
1003
80:
60:
40:
20:
o:
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A2.37E5
/^
18:00 19:00
XWJ. TIMS -
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20:00 2l':00
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-5.6S5
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'.3.3E5
-2.2E5
.LIES
Time
315.9419 T:2 BSUB(256, 30, -3. 0) PKD(9,5,5, 0. 05\,2404. 0,1 . 00\,T, T) Exp:EPCUS
TRIANGLE LABS TeJCt:TLI LCS TLI#43085 IJKT. TIME - 11-03
100^
80:
60:
40:
20:
o:
17:00
18:00 19:00
Al . 68E7
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20:00 21 i 00
File:S975831 #1-848 Ac/^^/**"^^*^^^^^/^P*^A^>^^^^^^^-^^^^^^^^'^
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26 20 1 11 21-
17:00 18:00 19\ 00 20':00 ' 21\00
rile. -S9 75831 #1-848 Acq:ll-SEP-1997 10:59:48 EI+ Voltage SIR 70S
375.8364 T:2 Exp:EPCUS
TRIANGLE LABS TeJCt:TLI LCS TLI#4308S
1003
80.
60.
40.
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17
17:15
liuiLu
„, 17S°°
35
18:02
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18:00 19. -00
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22:00
11 : 03
22:00
11 : 03
l^^^~V>^/*-V~W1•-S>-»'^<»'vV~S*
1 1 1 1 1 1 1 1 1
22:00
11 : 03
22: 07
1 1 13
ll 1
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20:00 21:00 22»0a'
..4.0E6
.3.2E5
.2.4E6
.1 . 6E6
•-8.0E5
Time
rS.3E6
-4.2E6
-3.2E6
.2.1E6
.1.1E6
.O.OEO
Time
33^6.8E6
-5.4E6
-4.1E6
-2.7E6
Ll . 4E6
Time
8 . flF7
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-7.0E3
54^«
.313
-3.5E3
.1 . 8E3
Time
-------
rll»tS975831 #1-840 Acqt ll-SEP-1997 10i59i48 EI+ VoltMym SIM 70S Nairn*! 32
319.8965 Ti2 BSUB(256,30, -3 .0) PJO>( 7,5,3,0. 05\, 128.0, 1.00\,r,T) XxptXPCVa
TRIANGLE LABS TaxtiZLJ LOS TLH43085 ZK7. TIME - Hi 03
1004
80:
60.
40.
20.
0: .
A1.46S6
I
/ I
.3. ma
3. OS
2.3*3
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15*00 20*00 21:00 22*00 ' ' ' Tim*
rlle,S975831 #1-848 Acqi ll-SEP-1997 10i59i48 EI+ Voltagw SIX 70S Noise: 43
321.8936 Fi2 BSUB(256,30,-3.0) tKD(7 ,5,3,0 .05\, 168 .0,1. 00\,F,T) ExptEPCVS
TRIANGLE LABS TvxtiTLI LCS TLIf 43085 IKT. TIME - 11:03
1001
sol
60:
40.
20.
o:
JU.fftf
1
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TRIANGLE LABS TeitiTLI LCS TLH43085 IX J. TIME - 11:03
10 OS
sol
60:
40:
20:
o:
A3.01E7
n
A
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15*00 ' .20*00 ' 21*00 22:00 ' ' Tias
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333.9338 T:2 BSUB(256,30, -3 .0) PKD( 7,5, 3, 0. OS\,124 .0,1. 00\,F,T) Exp:EPCOS
TRIANGLE LABS Teit:TLI LCS TLI043085 TJW. TIME - 11 .- 0 3
1001
80:
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40:
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0
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\
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' 19':00 .20*00 .21:00 22\00 ' ' ' Time
riletS97S831 #1-848 Acg:ll-SEP-1997 10:59:48 EI+ Voltage SIR 70S Noise i 39
327.8847 F:2 BSVB(256, 30, -3 .0) PXJ>< 7,5,3, 0. 05\,156. 0,1. 00%,J-, T) EzpiEPCUS
TRIANGLE LABS T«xt:TLI LCS TLH4308S IKJ. TIME - 11:03
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80.
60.
40.
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0
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1
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19s 00 20:00 21:00 22:00 Tiae
rile:S975831 #1-848 Acq: ll-SEP-1997 10:59:48 EI+ Voltage SIR 70S
330.9792 T:2 Exp:EPCUS
TRIANGLE LABS TmxtsTLI LCS TLIf 43085 IKJ. TIME ' 11:03
100
80
60
40
20
0
* 18:27 19s03 19,26fJ^jSjJ0^20..29 ^^2. ~&%-~*32^ ^^V
• ^^Ai^y^fco/^n^^A^i^^ii-^j^^^ ii^^*n^^^^^f"^^'*P***f*S'*^**^*^^ ^ ^^^^ ^/^"^ ^^^^
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.1.4E6
O.OEO
' 19s 00 20*00 21*00 22:00 ' ' ' Time
295
-------
rile :SS 75831 #1-848 Acqsll-SXP-1997 10:59:48 XI* Voltage SIX 70S Hairnet 35
339.8597 Ti2 BSUB(256,30,-3.0) PKD(7,5,3, 0 .05\, 140 .0, 1.00\,T,T) XzptXPCUS
TRIANGLE LABS TexttTLI LCS TLI#43085
1001
80:
60:
40:
20.
0 -,
23 t 00 24:00
riletS975831 #1-848 Acqill-SXP-1997 10:59:48
X1K7. TIMX - lltOJ
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ft
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EI+ Voltage SIX 70S Noise: 34
^.3.9X6
.3.1X6
.2.3X6
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.7.7X5
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26\00 Time
341.8567 rt2 BSUB(256,30,-3.0) PXD(7,5,3,0.05\,136.0,1.00\,r,T) XipiXPCUS
TRIANGLE LABS TexttTLI LCS TLH43085
100J
80:
60:
40:
20:
a —rr
' 23'tOO 24\00 '
TlletS97S831 #1-848 Acqtll-SEP-1997 10t59i48
IJKT. TIMX - lit 03
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25:00
EH- Voltage SIR 70S N6ises38
-2.4X6
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26:00 ' Time
351.9000 Ts2 BSUB(256,30,-3 .0) PKD(7,5,3, 0. OS\,1S2. 0,1 . 00\,T,T) ExpsEPCUS
TRIANGLE LABS TejftsTLI LCS TLI#430S5
1003
80:
60:
40:
20:
0
23:00 24\00
File:S975831 #1-848 Acqtll-SEP-1997 10:59:48
INJ. TIME - 11:03
A2.02E7
1 V
25:00
EI+ Voltage SIR 70S Noise: 39
6.8X6
.5 . 4X6
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26s 00 Time
353.8970 F:2 BSUB(256,30, -3 .0) PKD(7 ,5,3,0 .05\,156 .0,1. 00\,T,T) ExptEPCUS
TRIANGLE LABS TeJCtsTLI LCS TLI#43085
1003
80:
60:
40:
20:
a'-
23'sOO 24 1 00
TiletS975831 #1-848 Acqsll-SEP-1997 10:59:48
330.9792 Ts2 ExptEPCDS
TRIANGLE LABS TeJcttTLI LCS TLI#43085
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60:
40:
20:
o-
23 t 00 24 tOO
rile:S97S831 #1-848 Acqsll-SEP-1997 10:59:48
409.7974 T:2 ExptEPCUS
TRIANGLE LABS TextsTLI LCS TLH43085
1003
80:
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401 ">4° „ ,„ 33"»
• "t!4 1 24,09
20: i I 1 i
a '•• l\J(LlVf\-AjU\JiAfJ^^
23 s 00 24 ': 00
INJ. TIME '
A1.33X7
|
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25»00 '
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INJ-. TIME -
v — -^^^v-^fi-^^- — \sf*—*f*~~-^r\^*-
25:00
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INJ. TIME -
OAJlA-oJw U
25>00
11:03
-4.5X6
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.1 . 6X6
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2S.-00 Time
11 : 03
^&45-*£ic|i£&^*^^.r 7 • 3E6
.5.8X6
'•.4.4X6
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26s 00 Time
11 s 03
-1.4X4
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26i40 .8.2X3
I .5.513
25s 59 m 1 .2.7X3
^-AJbAA^AV^/wUllAjlA^ a. am
26:00 rime
296
-------
file,SS75BJl #1-040 Acqtll-SEP-1997 10l59l48 KI+ Voltage SIX 70S HOimmil32
355.8546 F:2 BSUB(256,30, -3 .0) PKI>(7, 5,3, 0.05\,528.0r1.00\,F,T) XxptXPCUS
TRIANGLE LABS Text: IX J LCS TLH43085 1X7. TIMX - lliOJ
1004
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0. .
A6.
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File:S975831 #1-840 Acqs ll-SEP-1997 10:59:48 EI+ Voltage SIR 70S Noil*, 34
357.8516 F:2 BSUB(256, 30, -3. 0) PXD(7, 5,3,0. 05\,136 .0,1. 00\,F,T) XxptXPCUS
TRIANGLE LABS TextiXCT LCS TLH43085 INJ. TIMX - 11:03
100*
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40:
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A4.
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24:00 25:00 25:00
.1.5X1
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0.0X0
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rile:S975831 #1-848 Acq: ll-SEP-1997 10:59:48 EI+ Voltage SIR 70S Noiae:32
367.8949 F,2 BSUB(256, 30, -3.0) PKD(7, 5,3,0. 05\, 128. 0,1. 00\,F,T) ExpiEPCUS
TRIANGLE LABS Text.-TLI LCS TLI*43085 INJ. TIME - 11:03
1001
so:
so:
40.
20.
0
A1.18E7
I A1.14E6
1 TA
241-00 ' ' ' ' 251-00 ' 25:00
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24:00 25:00 26:00
7.3X6
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' 0.0X0
Time
29'
-------
Tile, 3975831 tl-406 Acq,ll-SXP-1997 10:59:48 XI* Voltage SIX 70S Holme ,908
373.8208 r,3 BSVB(256 , 30, -3 .0 ) PXD(7,5,3r0.05\,3632.0,1.00\,T,T) XxpiXTCUS
TXIANGLE LABS TextiTLI LCS TLIt43085 IJKT. TIME - lliOJ
100J
soj
60l
401
201
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-6.9X5
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1 Tim*.
filet S975831 tl-406 Acq, ll-SEP-1997 10:59:48 EI+ Voltage SIX 70S Noime,677
375.8178 F:3 BSUB(256, 30, -3. 0) PXD(7,5,3, 0. OS\,3708. 0,1.00\rT,T) XxpiEPCUS
TXIASGLX LABS Tejct:TLI LCS TLIt43085 XK7. TIME - 11:03
1001
aol
601
401
201
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27
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rile, 3975831 tl-406 Acq, ll-SEP-1997 10,59:48 XH- Voltage SIX 70S «oiae:790
383.8639 r,3 BSUB(256,30,-3 .0) PKD(7,5,3, 0. OS\,3160. 0,1 . 00\,r,T) XxpsXPCOS
TXIANGLE LABS TextiTLI LCS TLIt43085 I/CJ. TIME - 11. -03
1001
aol
601
401
201
Oj
A8
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ft
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1
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27,12 27,24 27:36 27:48 20:00 201-12 20:24 20.-36 28:48 25-00 25:12 29:241 291-36 29:40 30:00 '30.-.L
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L6.3K5
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J'ile:S975831 #1-406 Acq, ll-SEP-1997 10,59,48 EI+ Voltage SIX 70S Noiae,873
385.8610 JP.-3 BSOB(256,30, -3.0) PKD( 7,5,3, 0. 05%, 3492. 0,1 . 00%,JT, T) Xxp-.XPOJS
TXIANGLX LABS TeitiTLI LCS TLIt4308S INJ. TIME - 11:03
1003
80J
601
40.
20.
0
2>
Al
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1 T-imo
rile,S975831 tl-406 Acq: ll-SEP-1997 10:59,48 EI+ Voltage SIX 70S
392.9760 r,3 Eip-.EPCUS
TXIANGLE LABS TeJCt.-HJ LCS TLI#43085 JJKJ. TIME - 11-03
100J
80.
60.
40.
20.
0
2:
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*~\ rt^i^WLrvVV^ 27:55 28.- 07 28:24 28:35 fjj»<7 29.- 01 2g.24 29:45 29:56
v«wV Y V-^w ^fyj^j*~vSA~K*sY*^/*/V\nf^ Jf*f-^*^lf^^*Y*~f*^^Y^AS^^
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3.4E6
.2.7X6
.2.1E6
.1 . 4X6
.6.8X5
-.0.0X0
I Time
445.7555 T:3 ExpsEPCUS
TXIANGLE LABS Text:TLI LCS TLIt43085 XJTJ. TIME - 11,03
JL 0 QA o o AK
1
j 27:18 27:50 *".*' I, "j"
s°i i ill II 1
<°| | , I I 1 L-oi 1 |i i 1 1 || 2flff 1 a9'39 1 I
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27:12 27:24 27.-35 27:40 20:00 281-12 201-24 20i3ff 20:40 29:00 29:12' 29i24' 2^:36 29:48 30\'ob' 30-L
-7.0E3
-5.6E3
.4.2E3
-2.8r3
.1.4X3
? Time
298
-------
FiJ.eiS975B31 U-4O6 ACIJ, il-SXP-1997 1OI39HB £1+ Voltage SM 70S NOlfe,545
389.8156 Tt3 BSOB(256,30,-3.0) PKD(7,5,3,0.051,2180.0,1.00\,r,T) XxpifPCUS
TRIANGLE LASS TexttTLI LCS TLH43085 2X7. TIM* - 11103
1001
80.
SO.
40.
20.
27,48 28:00 28,12 28,24 28,36 28,48 29,00 29,12 29,24 29,36 29,48
film,3975831 11-406 Aojill-SEP-1997 10,59,48 11+ Voltage SIS 703 No±fe:544
391.8127 F:3 BSUB(256,30,-3.0) Pn>(7,5,3,O.OS\,2176.0,1.00\,r,T) EzpiEPCUS
TRIANGLE LABS Text:TLI LCS TLI»43085 IKJ. TIME - 11:03
1004 A4.97E6
A6.15S6
A6.00S6
9.9*3
4.5X5
0.0X9
so:
60.
40:
20:
27,48 28,00 28:12 28,24 28:36 28:48 29,00 29,12 29,24 29,36 29:48
rile:S975831 tl-406 Acq:ll-SEP-1997 10,59,48 EH- Voltage SIR 70S Ko±Be,1013
401.8558 T:3 BSUB(256,30,-3 .0) PKD(7,5,3, 0. 05\,4052. 0,1. 00%,T, T) Exp,EPCUS
TRIANGLE LABS Text:TLI LCS TLI#43085 JK7. TIME - 11:03
1001 A1.66E7
A4.74S6
.1.816
.1.5E6
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.3. 6E5
801
60.
40:
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27:48 28:00 28:12 28:24 28:36 28,48 29,00 29:12 29:24 29:36 29:48
r±le:S975831 #1-406 Acq,ll-SEP-1997 10:59:48 SI+ Voltage SIR 70S No±*e:884
403.8529 T:3 BSUB(256,30, -3. 0) PKD(7,5,3, 0. 05%, JSJS.0,1. 00%,I, T) Exp:EPCOS
TRIANGLE LABS Text:TLI LCS TLH43085 IXJ. TIME - 11:03
1001 Al 3.7E7
.O.OEO
Time
80.
60.
40.
20.
A9.89E6
5. OE6
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27\48 ' 'ae\od ' '28*112 ' '28:24 28,36 28:48 29sOO 29:12 29:24 29:36 29:48
r±le:S975831 tl-406 Acqtll-SEP-1997 10:59:48 EI+ Voltage SIR 70S
392.9760 T:3 SxptEPCUS
TRIANGLE LABS Taxt:TLI LCS TLH430SS IHJ. TIKE - 11:03
.O.OEO
Time
1001
80J
601
401
201
0.
27,55 28:07
28:24 28:35
28:47
29:01
29:45
27:48 28,00 28,12 28:24 28:36 28,48 29,00 29:12 29,24 29:36 29:48
.O.OEO
Time
-------
rll»iS975831 tl-430 Acqt ll-SXf-1997 10:59:48 EI+ Voltage SIX 70S Holme: 13 6 7
407.7818 F:4 BSOB(256, 30, -3. 0) PKD(7 ,5,3,0 .05\,5468. 0,1 .00\,r,T) XxptXPCOS
TRIANGLE LABS TexttTLI LCS TLH43085 IKT. TIME - 11:03
1001
80:
60:
40:
20:
0.
A6.46X6
f\
A
I A3. 76X6
\ A
/ \ / \
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31\12 31:24 31\36 31:48 32\00 32:11 32\24
rile ,3975831 tl-430 Acq:ll-SXP-1997 10:59:48 EI+ Voltage SIX 70S Noime:736
409.7789 F:4 BSUB(256, 30, -3. 0) PKD(7,5, 3,0. 05\, 2944 .0,1 . 00\,F, I) Exp:EPCUS
TRIANGLE LABS Text-.TLI LCS TLIt43085 JJK7. TIME - 11:03
1001
80:
60:
40:
20:
o:
A6.05X6
f\
A
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\ A
/ V / V
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' ' ' ' 3^,12' ' ' 31\24' ' ' 31\36' ' ' ill/a" ' JaioO ' ' " 32\12' ' ' 32\24' "~~
File:S975831 tl-430 Acq:ll-SEP-1997 10:59:48 EH- Voltage SIR 70S Koiae:S26
417.8253 r-.4 BSVB(256,30,-3 .0) PKD(7 ,5,3,0 .OS\,2104 .0,1. 00\,T,T) Exp:EPCUS
TRIANGLE LABS Text:TLI LCS TLIt43085 IKT. TIME - 11:03
1001
801
60:
401
20:
0:
A4 . 71E6
A
A
\
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31\12 31\24 31\36 31\48 32\00 32\12 32\24'
File:S975831 tl-430 Acq:ll-SEP-1997 10:59:48 EI+ Voltage SIR 70S Noiae:475
419.8220 F:4 BSOB( 256, 30, -3 . 0) PKD( 7,5,3, 0.05\,1900. 0,1 . 00\,F, T) Exp:EPCUS
TRIANGLE LABS Text:TLI LCS TLIt43085 IKT. TIME - 11:03
1001
80.
60.
40.
20.
0.
A1.10E7
A
A
\
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31:12 31\24 31\36 31\4B 32\00 32\12 32\24^
File:S97S831 tl-430 Acq:ll-SEP-1997 10:59:48 EI+ Voltage SIR 70S
430.9729 F:4 Exp:EPCUS
TRIANGLE LABS Teit:TLI LCS TLIt43085 IKT. TIME - 11 .- 03
lOOi
80.
60.
40.
20.
0.
5-^\£M£f 31:14 ^i21 31,30 31i44 31:51 32:04 32,12 ,- ,0 33.
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31:12 31:24 3l':36 31\48 32:00 32:12 32\24
rile:S97S831 tl-430 Acq: ll-SEP-1997 10:59:48 EH- Voltage SIR 70S
479.7165 F:4 Sip:EPCVS
TRIANGLE LABS Text:TLI LCS TLIt43085 IKT. TIKE - 11 : 03
100.
80.
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40.
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: 31i33 I , „ , 32'24
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31:12 31:24 31:36 3l':48 32:00 32\12 32\24
-2. 0X6
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.4.0X5
0.0X0
32:36 32\48 Time
1 . 8X6
.1.5X6
.1.1X6
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32\36 32l: 4 8 Time
1 . 6E6
ll.2E6
'•-9.3ES
:.6.2E5
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32\36 32*: 48 Time
3.5E6
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-2.1E6
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32\36 32\48 Time
30 -2.6E6
~X .. 32:38
"Vvv — -^^—v^—
-2.1E6
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32\36 ' ' ' 32\48 ' Time
cl . OS4
32:37
A A A A K
^K AMA AA
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-------
Filt:S975831 tl-430 Acqtll-SXP-1997 10t59l4B EI+ Volt*y* SIX 70S HO1M»:542
423.7766 T>4 BSUB(256,30, -3. 0) PKD(7,5,3,0.05\,2168.0,1.00\,r,T) Xxp:XPCUS
TRIANGLE LABS TuxttTLI JXS TLH43085 UU. TIM* - 11103
1003
80.
60.
40.
20:
A3. 71X6
31:18 31t24 31:30 31:36 31:42 31:48 31:54 32:00 32:06 32:12 32:18
F±le:S97S831 tl-430 Acq:ll-SXP-1997 10:59i48 XI* Volt*g» SIX 70S Noita:435
425.7737 T:4 BSUB(256,30,-3.0) PKD(7,5,3,0.05\,1740.0,1.00\,r,T) ExptEPCUS
TRIANGLE LABS TextjlXI LCS TLH43085 HKT. TIME - 11:03
1003k A3.54X6
eo:
60.
40.
20.
-*.fM3
f.9XS
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.3.4*5
J..7X5
0.0X0
32t24 32:30
-8.4X5
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'.3.4X5
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.O.OEO
31:18 31:24 31:30 31:36 31:42 31:48 31:54 32:00 32:06 32:12 32:18
rile:S975B31 tl-430 Acqsll-SSP-1997 10s59:48 EH- Voltage SIX 70S Noiae:8S2
435.8169 Ts4 BSUB(2S6, 30, -3. 0) PKJ>(7,5,3, 0.05%,3408. 0,1. 00\,T,T) Exp-.EPCUS
TRIANGLE LABS Text.-TtJ LCS TLI#4308S JK7. TIME - 11 .• 03
1004 A8.J.OE6
eo:
40.
20:
32:24 32:30
Time
-1.9E6
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'.1. 1E6
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31:18 31:24 31:30 31:36 31:42 31:48 31:54 32:00 32s06 32:12 32:18
rile:S975831 tl-430 Acq:ll-SEP-1997 10:59:48 EI+ Voltage SIX 70S Koiee:786
437.8140 T:4 BSUB(256,30,-3.0) PKD(7,5,3, 0. 05%, 3144. 0,1. 00\,T, T) Ezp:EPCUS
TRIANGLE LABS TextsTLI LCS TLI443085 INJ". TIME - 11:03
1004 A7.83E6
801
60.
40:
20:
32:24 32:30
.O.OEO
Time
1. 8X6
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31:18 31:24 31:30 31:36 31:42 31:48 31:54 32:00 32:06 32tl2 32:18 32:24 32,30
File:S975831 tl-430 Acq:ll-SEP-1997 10:59,48 XI+ Voltage SIX 70S
430.9729 F:4 ExptEPCUS
TRIANGLE LABS TextiZLX LCS TLIt43085 INJ. TIME - 11:03
.O.OEO
Time
1003
ao:
60.
40.
20.
01
31:58
32:04
32:12
32:3532:30
r2.6E6
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'.0.0X0
31:18 31:24 31:30 31:36 31:42 31:48 31:54 32:00 32:06 32:12 32:18 32:24 32:30
-------
ileiSS75831 #1-430 Adjtll-SXP-1997 10,59,48 EH- Voltage SIX 70S Hoi*»:243
41.7428 F,4 SSOB(256,30,-3.0) PKD(7,5,3,0.05\,972.0,1.00\,T,T) XzptXPCVS
SIANGLX LABS TmjcttTLI LCS TLH43085 IKT. TIMX - 11:03
OOi A4.32X6
901
80.
70-
601
501
40.
301
301
31:00 32x00 33:00 34:00 35 00
file.-S375831 #1-430 Acq:ll-3EP-1997 10:59,48 EI+ Voltage SIX 70S Noi*»i27
43.7399 F:4 BSUB(356,30, -3. 0) PKD(7,5,3, 0. 05\,108. 0,1.00\,T, T) ExptEPCVS
TRIANGLE LASS Text.-TEX LCS TLII43085 1X7. TIMX - 11:03
-5.1X5
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Tim,
1001
901
801
701
601
501
30.
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''-4.7E5
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.1.3X5
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31:00 32:00 33:00 34:00
File,S97SB31 #1-430 Acqtll-SEP-1997 10,59,48 EI+ Voltage SIS 70S
430.9729 F:4 EipiEPCUS
TRIANGLE LASS Text:IIJ LCS TLH4308S ItKT. TIME -
J001^JJ^ /UA?" J. . 3i'44 33:0*
901
801
70.
60.
501
40.
301
20.
lOjj
0.
35:00
'•.0.0X0
Tim*
111 03
35:47
31:00 32,00 33\00 ' 34\00 '351-00
file:S575fl31 #1-430 Acq:ll-SEP-1997 10:59:48 EI+ Voltage SIR 70S
513.6775 F:4 ExpiEPCDS
TRIANGLE LABS Text:TJtI LCS TLIf43085 TK7. TIME - 11:03
1001
^2.7X6
.2.4X6
.2.1X6
_1.9X6
:1.6X6
',1. 3X6
.1. 1X6
18.0X5
.5.3X5
.3.7X5
.0.0X0
Tim
-1.2X4
-------
'U»i£975B31 U-430 AaqtU-aXf-1997 10>59,48 XU- Volt*ym SIS 70S
57.7377 r,4 BSUB( 256,30,-3.0) PKD(7,5,3,0.05\,840.0,1.00\,T,T) XxpiEPCCB
TRIANGLE LASS TmxtlTLI LCS TLIt43085 I1KT. TIM* - 11103
34,24 34,30 34,36 34,42 34,48 34,54
ile:S975831 41-430 Aoqill-SEP-1997 10,59,48 XI+ Voltage SIX 70S Noises37
59.7348 F,4 BSUB(256,30,-3.0) PKD(7,5,3,0.05\,148.0,1.00\,T,T) Exp:EPCDS
TRIANGLE LASS TexttTLI LCS TLH43085 IHJ. TIME - 11:03
001 A4.62E6
34,24 34,30 34:36 34:42 34:48 34:54
ile:S975831 tl-430 Acq:ll-SEP-1997 10,59:48 EI+ Voltage SIX 70S Noise:451
69.7779 T:4 BSUB(256,30, -3. 0) PKD(7,5,3, 0. 05\,1816. 0,1. 00\,T, T) ExpiEPCUS
TRIANGLE LABS TextsIXJ LCS TLI#4308S inf. TIME - 11:03
001 A8.21E6
00\
so:
7X6
34:24 34:30 34,36 34:42 34:48 34:54
r±la:S975831 U-430 Ac
-------
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-------
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--Li ci
CALIBRATION
DATA
Triangle Laboratories, Inc.
801 Capitola Drive P.O. Box 13485
Durham, NC 27713-4411 Research Triangle Park, NC 27709-346
919-544-5729 Fax #919-544-5491
305
-------
Date: 09/12/97
TRIANGLE LABORATORIES, INC.
Continuing Calibration for S975861
Operator
• MT,
Init Calibration. : SF56117
ICal Date
Analyte Summary
Name
Total MCDF
Total MCDD
Total DCDP
Total DCDD
Total TriCDF
Total TriCDD
2378-TCDF
TOTAL TCDF
2378-TCDD
TOTAL TCDD
12378-PeCDF
23478-PeCDF
TOTAL PeCDF
12378-PeCDD
TOTAL PeCDD
123478-HxCDF
123678-HxCDF
234678-HxCDF
123789-HxCDF
TOTAL HxCDF
123478 -HxCDD
• 06/10/97
RF Ratio
0
0
0
0
0
0
1
1
1
1
1
1
1
1
1
1
1
1
0
1
0
162
.000
.000
.000
.000
.000
.000
.182 0.81
.182 0.81
.078 0.79
.078 0.79
.051 1.53
.100 1.52
.075 1.52
.210 1.59
.210 1.59
.070 1.33
.354 1.31
.059 1.32
.981 1.34
.116 1.33
.908 1.25
Instrument
Std.Conc . - -
RT RT Rel. RT
: S
ICal
RF
i *J '
50.00
Delta
RF
%D
Lo/High
1:
15
2:
16
8:
16
9:
17
12
19
14
20
18
23
19
23
23
27
24
27
28
30
34
:34
19
:19
34
:34
19
:19
:34
:34
:19
:19
:05 21:35 1.0008
:33
:31 22:20 1.0007
:32
:27 25:38 1.0007
:30
26:22 1.0293
:45 26:43 1.0000
:22
:02 29:09 0.9971
:42
29:15 1.0006
29:45 1.0177
30:27 1.0416
28:32 29:52 0.9972
2
1
0
1
1
0
1
1
1
1
1
1
1
1
1
1
1
1
1
1
0
.087
.625
.687
.326
.082
.933
.251
.251
.191
.191
.111
.115
.113
.256
.256
.215
.574
.247
.105
.285
.953
-2
-1
-0
-1
-1
-0
-0
-0
-0
-0
-0
-0
-0
-0
-0
-0
-0
-0
-0
-0
-0
.087
.625
.687
.326
.082
.933
.069
.069
.113
.113
.060
.015
.038
.046
.046
.145
.220
.188
.124
.169
.045
100
100
100
100
100
100
-5
-5
-9
-9
-5
-1
-3
-3
-3
-11
-14
-15
-11
-13
-4
.0%
.0%
. 0«
.0%
.0%
.0%
.5%
.5%
.5%
.5%
.4%
.4%
.4%
.7%
.7%
.9%
.0%
.1%
.2%
.1%
.7%
30:23
123678-HxCDD
1
.059 1.25
29:57 1.0000
1
.133
-0
.074
-6
.6%
Page 1
Triangle Laboratories, Inc.® Analytical Services Division
501 Capitola Drive • Durham, North Carolina 27713
'hone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 22:27 09/12/97
306
-------
Continuing Calibration for S975861
123789-HxCDD
TOTAL HxCDD
1234678 -HpCDF
1234789 -HpCDF
TOTAL HpCDF
1234678-HpCDD
TOTAL HpCDD
OCDF
OCDD
1.090
1.019
1.503
1.267
1.385
0.934
0.934
1.597
1.040
1.25
1.25
1.03
1.03
1.03
1.00
1.00
0.86
0.85
30:14 1.0095
1.091 -0.001
1.059 -0.040
31:44
33:15
31:59
32:54
31:16
39:16
31:16
39:16
31:54 1.0000
33:05 1.0371
32:44 1.0000
35:25 1.0043
35:17 1.0005
Other Standard Summary
Name
37C1-TCDD
13C12-PeCDF 234
13C12-HxCDF 478
13C12-HxCDF 234
13C12-HXCDF 789
13C12- HxCDD 478
13C12- HpCDF 789
Internal Standard
Name
13C12-2378-TCDF
13C12-2378-TCDD
13C12-PeCDF 123
13C12-PeCDD 123
13C12-HXCDF 678
13C12- HxCDD 678
RF
0.842
0.975
0.934
0.903
0.789
0.950
0.830
Ratio
162
1.54
0.50
0.49
0.49
1.21
0.42
RT
Lo/High
20:19
24:19
21:37
29:37
29:54
35:54
RT Rel. RT
22:20 1.0007
26:21 1.0286
29:09 0.9971
29:44 1.0171
30:27 1.0416
29:52 0.9972
33:04 1.0366
Summary
RF
1.488
1.131
1.302
0.780
1.171
0.934
Ratio
1&2
0.76
0.80
1.53
1.52
0.50
1.21
RT
RT Rel. RT
1.543 •
1.184
1.363
1.068
1.068
1.493
1.105
ICal
RF
0.843
0.970
0.959
0.926
0.805
0.973
0.771
ICal
RF
•0.040
0.083
0.022
-0.134 -
-0.134 -
0.104
-0.065
Delta
RF
-0.001
0.005
-0.025
-0.023
-0.016
-0.023
0.059
Delta
RF
-0.1%
-3.8%
-2.6%
7.0%
1.6%
12.6%
12.6%
7.0%
-5.9%
%D
-0.1%
0.5%
-2.6%
-2.5%
-2.0%
-2.4%
7.6%
%D
Lo/High
20:34
22:34
20:19
24:19
21:37
29:37
22:43
30:43
25:14
33:14
28:57
30:57
Page
21:34 1.0000
22:19 1.0000
25:37 1.0000
26:43 1.0000
29:14 1.0000
29:57 1.0000
2
1.318
1.066
1.133
0.635
1.204
0.995
0.170
0.065
0.169
0.145
-0.033
-0.061
12.9%
6.1%
14.9%
22.9%
-2.7%
-6.1%
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed:
222ft 09*tt/9:
-------
13C12-HpCDP 678 0.831 0.42
13C12-HpCDD 678 0.786 1.10
13C12-OCDD 0.453 0.94
Continuing Calibration for S975861
29:54 31:54 1.0000 0.887 -0.056 -6.3%
35:54
31:44 32:44 1.0000 0.815 -0.029 -3.5%
33:44
35:07 35:16 1.0000 0.519 -0.066 -12.6%
35:27
Recovery Standard Summary
Name RF Ratio
13C12-1234-TCDD 1.000 0.81
13C12-HXCDD 789 1.000 1.21
RT
162 Lo/High
ICal Delta
RT Rel. RT RF RF %D
22:08 0.9918 1.000 0.000 0.0%
30:14 1.0095 1.000 0.000 0.0%
QC Front End Check:
1.4500
Page
Triangle Laboratories, Inc.® Analytical Services Division
301 Capitola Drive • Durham, North Carolina 27713
3hone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 2257
-------
Continuing Calibration for S975839
Operator :
Init Calibration.:
ICal Date :
Analyte Summary
Name
Total MCDF
Total MCDD
Total DCDF
Total DCDD
Total TriCDF
Total TriCDD
2378-TCDF
TOTAL TCDF
2378-TCDD
TOTAL TCDD
12378 -PeCDF
23478-PeCDF
TOTAL PeCDF
12378-PeCDD
TOTAL PeCDD
123478-HxCDF
123678-HxCDF
234678-HxCDF
123789-HxCDF
TOTAL HxCDF
123478 -HxCDD
123678 -HxCDD
i W ? / A. */ " •
KAS
: SF56117
• 06/10/97
RF Ratio
142
0.000
0.000
0.000
0.000
0.000
0.000
1.207 0.83
1.207 0.83
1.189 0.78
1.189 0.78
1.124 1.53
1.147 1.52
1.136 1.53
1.282 1.59
1.282 1.59
1.145 1.29
1.490 1.30
1.117 1.30
1.028 1.31
1.195 1.30
0.896 1.21
1.056 1.23
RT
Lo/High
0:21
14:21
1:10
15 : 10
7:21
15:21
8:10
16:10
11:21
18:21
13:10
19:10
16:39
22:24
18:01
22:24
22:20
26:35
23:44
26:27
27:10
29:54
27 : 42
29:35
Instrument. . :
Std.Conc . . . :
Related CCal:
ICal
RT Rel. RT RF
2.0
1.6
0.6
1.3
1.0
0.9
20:22 1.0008 1.2
i.:
21:12 1.0016 1.]
i.:
24:42 1.0007 l.j
25:27 1.0311 1.:
i.:
25:50 1.0006 1.:
i.:
28:21 0.9965 1.
28:27 1.0000 1.
28:58 1.0182 1.
29:41 1.0434 1.
1.
29:06 0.9977 0.
29:11 1.0006 1.
50.00
RF %D
2.087 -2.087 100.0%
1.625 -1.625 100.0%
0.687 -0.687 100.0%
1.326 -1.326 100.0%
1.082 -1.082 100.0%
0.933 -0.933 100.0%
1.251 -0.044 -3.5%
1.251 -0.044 -3.5%
1.191 -0.002 -0.2%
1.191 -0.002 -0.2%
1.111 0.013 1.1%
1.115 0.032 2.9%
1.113 0.023 2.0%
1.256 0.026 2.1%
1.256 0.026 2.1%
1.215 -0.070 -5.8%
1.574 -0.084 -5.3%
1.247 -0.130 -10.4%
1.105 -0.077 -7.0%
1.285 -0.090 -7.0%
0.953 -0.057 -6.0%
1.133 -0.077 -6.8%
Page
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 19:23
-------
Continuing Calibration for S975839
123789 -HxCDD
TOTAL HxCDD
1234678-HpCDF
1234789-HpCDF
TOTAL HpCDF
1234678-HpCDD
TOTAL HpCDD
OCDF
OCDD
1.039
0.997
1.482
1.168
1.325
1.047
1.047
1.498
1.055
1.24
1.23
1.06
1.07
1.07
1.05
1.05
0.89
0.86
29:28 1.0103
31:00 31:11 1.0000
32:33
32:24 1.0390
31:16 32:03 1.0005
32:12
30:38 34:44 1.0029
38:38
30:38 34:37 0.9995
38:38
Other Standard Summary
Name
37C1-TCDD
13C12-PeCDF 234
13C12-HXCDF 478
13C12-HXCDF 234
13C12-HXCDF 789
13C12- HxCDD 478
13C12 -HpCDF 789
Internal Standard
Name
13C12-2378-TCDF
13C12-2378-TCDD
13C12-PeCDF 123
13C12-PeCDD 123
13C12-HXCDF 678
13C12-HXCDD 678
RF
0.968
0.963
0.946
0.875
0.770
0.905
0.778
Ratio
162
1.56
0.50
0.49
0.49
1.21
0.42
RT RT Rel. RT
Lo/High
19:10 21:12 1.0016
23:10
20:41 25:26 1.0304
28:41
28:20 0.9959
28:57 1.0176
29:40 1.0428
29:05 0.9971
29:11 32:23 1.0385
35:11
Summary
RF
1.526
1.045
1.054
0.556
1.419
1.032
Ratio
162
0.76
0.80
1.53
1.45
0.51
1.23
RT RT Rel. RT
Lo/High
19:21 20:21 1.0000
21:21
19:10 21:10 1.0000
23:10
20:41 24:41 1.0000
28:41
21:49 25:49 1.0000
29:49
24:27 28:27 1.0000
32:27
28:10 29:10 1.0000
30:10
Page 2
1.091 -0.052
1.059 -0.062
1.543 -0.061
1.184 -0.016
1.363 -0.038
1.068 -0.021
1.068 -0.021
1.493 0.005
1.105 -0.050
ICal Delta
RF RF
0.843 0.125
0.970 -0.007
0.959 -0.013
0.926 -0.051
0.805 -0.035
0.973 -0.068
0.771 0.007
ICal Delta
RF RF
1.318 0.208
1.066 -0.021
1.133 -0.079
0.635 -0.079
1.204 0.215
0.995 0.037
-4.8%
-5.9%
-4.0%
-1.3%
-2.8%
-1.9%
-1.9%
0.3%
-4.5%
%D
14.8%
-0.7%
-1.4%
-5.5%
-4.3%
-7.0%
0.9%
»D
15.8%
-1.9%
-7.0%
-12.5%
17.9%
3.7%
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 - Fax: (919) 544-5491
Printed: 19:
ISI
-------
13C12-HpCDF 678 0.880 0.43
13C12-HpCDD 678 0.713 1.00
13C12-OCDD 0.456 0.87
Continuing Calibration for S975839
29:11 31:11 1.0000 0.887 -0.007 -0.8%
35:11
31:02 32:02 1.0000 0.815 -0.102 -12.6%
33:02
34:26 34:38 1.0000 0.519 -0.063 -12.2%
34:46
Recovery Standard Summary
Name RF Ratio
162
13C12-1234-TCDD 1.000 0.81
13C12-HXCDD 789 1.000 1.23
RT
Lo/High
ICal Delta
RT Rel. RT RF RF
%D
20:58 0.9906 1.000 0.000 0.0%
29:28 1.0103 1.000 0.000 0.0%
QC Front End Check:
1.7362
Page
Triangle Laboratories, inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed:
-------
Continuing Calibration for S975814
Init Calibration.
ICal Date
Analyte Summary
Name
Total MCDF
Total MCDD
Total DCDF
Total DCDD
Total TriCDF
Total TriCDD
2378-TCDF
TOTAL TCDF
2378-TCDD
TOTAL TCDD
12378 -PeCDF
23478-PeCDF
TOTAL PeCDF
12378 -PeCDD
TOTAL PeCDD
123478-HxCDF
123678-HxCDF
234678 -HxCDF
123789-HxCDF
TOTAL HxCDF
123478-HxCDD
123678-HxCDD
• JM
: SF56117
• 06/10/97
RF Ratio
1&2
0.000
0.000
0.000
0.000
0.000
0.000
1.118 0.80
1.118 0.80
1.146 0.80
1.146 0.80
1.093 1.53
1.143 1.50
1.118 1.51
1.209 1.59
1.209 1.59
1.097 1.28
1.379 1.29
1.073 1.27
0.977 1.29
1.132 1.28
0.855 1.23
1.058 1.24
Tnst* Tiinwfcnt' . . • S
RT
Lo/High
0:24
14:24
1:13
15:13
7:24
15:24
8:13
16:13
11:24
18:24
13:13
19:13
16:44
22:28
18:06
22:28
22:24
26:38
23:47
26:30
27:11
29:56
27:44
29:37
Std.Conc
Related
RT Rel. RT
20:25 1.0008
21:14 1.0008
24:43 1.0007
25:29 1.0317
25:52 1.0013
28:22 0.9965
28:28 1.0000
28:59 1.0181
29:41 1.0427
29:07 0.9977
29:12 1.0006
. . . . : 50.00
CCal: S975778
ICal Delta
RF RF %D
2.087 -2.087 100.0%
1.625 -1.625 100.0%
0.687 -0.687 100.0%
1.326 -1.326 100.0%
1.082 -1.082 100.0%
0.933 -0.933 100.0%
1.251 -0.133 -10.6%
1.251 -0.133 -10.6%
1.191 -0.045 -3.8%
1.191 -0.045 -3.8%
1.111 -0.018 -1.6%
1.115 0.028 2.5%
1.113 0.005 0.5%
1.256 -0.047 -3.7%
1.256 -0.047 -3.7%
1.215 -0.118 -9.7%
1.574 -0.195 -12.4%
1.247 -0.174 -13.9%
1.105 -0.128 -11.6%
1.285 -0.153 -11.9%
0.953 -0.098 -10.3%
1.133 -0.075 -6.6%
Page 1
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 03:o3)l/f!/97
-------
Date: oa/ii/a/
123789 -HxCDD
TOTAL HxCDD
1234678-HpCDF
1234789-HpCDF
TOTAL HpCDF
1234678- HpCDD
TOTAL HpCDD
OCDF
OCDD
XK.LAnUArf£« A«fV7Wi\«**WJX.tAJl-»
Continuing Calibration
1.052 1.24 29:29
0.989 1.24
1.384 1.04 31:01 31:11
32:33
1.094 1.05 32:23
1.239 1.04
1.001 1.03 31:16 32:03
32:13
1.001
1.470
1.049
1.03
0.88
0.90
30:
38:
30:
38:
32
32
32
32
34:39
34:32
for S975814
1.0103 1.091
1.059
1.0000 1.543
1.0385 1.184
1.363
1.0005 1.068
1.
1.
0034
0000
Other Standard Summary
Name
37C1-TCDD
13C12-PeCDF
13C12-HXCDF
13C12-HXCDF
13C12-HxCDF
13C12- HxCDD
13C12- HpCDF
234
478
234
789
478
789
Internal Standard
Name
13C12-2378-TCDF
13C12-2378-TCDD
13C12-PeCDF
13C12-PeCDD
13C12-HxCDF
13C12-HXCDD
123
123
678
678
RF
0.972
1.014
0.955
0.886
0.798
0.897
0.787
Ratio
142
1.54
0.50
0.49
0.49
1.22
0.43
RT
RT
Rel. RT
1.068
1.493
1.105
ICal
RF
-0.039
-0.070
-0.159 -
-0.090
-0.124
-0.067
-0.067
-0.023
-0.056
Delta
RF
-3.5%
-6.7%
10.3%
-7.6%
-9.1%
-6.3%
-6.3%
-1.5%
-5.1%
%D
Lo/High
19:
23:
20:
28:
29:
35:
13
13
42
42
ill
:11
21:13
25:28
28 : 21
28:58
29 : 41
29:06
32:22
1.
1.
0.
1.
1.
0.
1,
0000
0310
9959
0176
0427
9971
.0379
Summary
RF
1.554
1.110
1.243
0.713
1.294
0.964
Ratio
1&2
0.74
0.78
1.52
1.58
0.50
1.22
RT
RT
Rel. RT
0.843
0.970
0.959
0.926
0.805
0.973
0.771
ICal
RF
0.129
0.044
-0.004
-0.040
-0.007
-0.076
0.016
Delta
RF
15.3%
4.5%
-0.4%
-4.3%
-0.8%
-7.8%
2.1%
%D
Lo/High
19
21
19
23
20
28
21
29
24
32
28
30
:24
:24
:13
:13
:42
:42
:50
:50
:28
:28
:11
:11
20:24
21:13
24:42
25:50
28:28
29 : 11
1
1
1
1
1
1
.0000
.0000
.0000
.0000
.0000
.0000
1.318
1.066
1.133
0.635
1.204
0.995
0.236
0.044
0.110
0.078
0.090
-0.031
17.9%
4.2%
9.7%
12.3%
7.5%
-3.1%
Page
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313
-------
Date:
13C12-HpCDF 678 0.876 0.45
13C12-HpCDD 678 0.782 1.06
13C12-OCDD 0.434 0.84
Continuing Calibration for S975814
29:11 31:11 1.0000 0.887 -0.011 -1.3%
35:11
31:02 32:02 1.0000 0.815 -0.033 -4.1%
33:02
34:22 34:32 1.0000 0.519 -0.085 -16.3%
34:42
Recovery Standard Summary
Name RF Ratio
13C12-1234-TCDD 1.000 0.83
13C12-HXCDD 789 1.000 1.22
RT
ICal Delta
RT Rel. RT RF RF
%D
1&2 Lo/High
21:00 0.9898 1.000 0.000 0.0%
29:29 1.0103 1.000 0.000 0.0%
QC Front End Check:
1.6171
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314
-------
Continuing Calibration for P973843
Analysis Date : 09/12/97
Operator : WK
Init Calibration.: PF22206
ICal Date : 02/20/96
Analysis Time : 11:04
Analyte Summary
Name
2378-TCDF
TOTAL TCDP
2378-TCDD
TOTAL TCDD
Method : C2NP
Instrument..: P
Std.Conc....: 5.00
GC Column...: DB-225
ICal Delta
RF Ratio
RT
RT Rel. RT RF
RF
%D
1&2 Lo/High
0.964 0.76 16:14 20:40 1.0008 1.040 -0.076 -7.3%
22:38
0.964 0.76 1.040 -0.076 -7.3%
1.001 0.75 17:03 19:28 1.0009 0.992 0.009 0.9%
22:00
1.001 0.75 0.992 0.009 0.9%
Other Standard Summary ICal Delta
Hame RF Ratio RT RT Rel. RT RF RF %D
1&2 Lo/High
37C1-TCDD 0.937 17:27 19:28 1.0009 1.014 -0.077 -7.6%
21:27
Internal Standard Summary ICal Delta
Name RF Ratio RT RT Rel. RT RF RF %D
1&2 Lo/High
13C12-2378-TCDF 1.201 0.77 19:39 20:39 1.0000 1.388 -0.187 -13.5%
21:39
13C12-2378-TCDD 1.006 0.79 17:27 19:27 1.0000 1.067 -0.061 -5.7%
21:27
Recovery Standard Summary ICal Delta
Name RF Ratio RT RT Rel. RT RF RF %D
1&2 Lo/High
13C12-1234-TCDD 1.000 0.82 19:41 1.0120 1.000 0.000 0.0%
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-------
ur
Continuing Calibration for P973859
lalysis Date....: 09/13/97
aerator : JM
lit Calibration.: PF22206
:al Date : 02/20/96
aalysis Time....: 10:24
Method : C2NF
Instrument..: P
Std.Conc : 5.00
GC Column...: DB-225
nalyte Sumnary ICal Delta
sine RF Ratio RT RT Rel. RT RF RF %D
1&2 Lo/High
0.949 0.76 16:14 20:40 1.0008 1.040 -0.091 -8.7%
22:37
0.949 0.76 1.040 -0.091 -8.7%
378-TCDF
3TAL TCDF
378-TCDD
3TAL TCDD
1.077 0.86 17:02 19:28 1.0017 0.992 0.085 8.5%
22:00
1.077 0.86 0.992 0.085 8.5%
ther Standard Suntnary ICal Delta
ame RF Ratio RT RT Rel. RT RF RF %D
1&2 Lo/High
7C1-TCDD 0.928 17:26 19:28 1.0017 1.014 -0.086 -8.5%
21:26
nternal Standard Sunsnaxy ICal Delta
ame RF Ratio RT RT Rel. RT RF RF %D
1&2 Lo/High
3C12-2378-TCDF 1.265 0.77 19:39 20:39 1.0000 1.388 -0.123 -8.9%
21:39
3C12-2378-TCDD 0.984 0.79 17:26 19:26 1.0000 1.067 -0.083 -7.8%
21:26
ecovery Standard Sumnary ICal Delta
ame RF Ratio RT RT Rel. RT RF RF %D
1&2 Lo/High
3C12-1234-TCDD 1.000 0.81 19:40 1.0120 1.000 0.000 0.0%
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316
-------
Initial calibration sunnary tot
Analysis Date : 02/20/96
Instrument : P
Method
GC Column..
C2NF
DB-225
Analytes
2378-TCDF
TOTAL TCDF
2378-TODD
TOTAL TCDD
Otner Standards
37C1-TCDD
RF SD %RSD
1.040 0.109 10%
1.040 0.109 10%
0.992 0.101 10%
0.992 0.101 10%
RF SD
1.014 0.048
%RSD
5%
RT
21:32
RT/LO
14:31
RT/HI
25:31
20:12 16:11 24:11
Ratiol
0.767
0.767
0.782
0.782
Ratio2
N
10
10
10
10
RT RT/LO RT/HI Ratiol Ratio2 N
20:12 18:11 22:11 10
Internal Standards RF SD %RSD RT RT/LO RT/HI Ratiol Ratio2 N
13C12-2378-TCDF 1.388 0.062 4% 21:31 20:31 22:31 0.758 10
13C12-2378-TCDD 1.067 0.036 3% 20:11 18:11 22:11 0.786 10
Recovery Standards RF SD %RSD RT RT/LO RT/HI Ratiol Ratio2 N
13C12-1234-TCDD 1.000 0.000 0% 20:27 0.794 10
of Report **
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-------
Instrument
Analytes
Total MCDF
Total MCDD
Total DCDF
Total DCDD
Total TriCDF
Total TriCDD
2378-TCDF
TOTAL TCDF
2378-TCDD
TOTAL TCDD
12378-PeCDF
23478-PeCDF
TOTAL PeCDF
12378-PeCDD
TOTAL PeCDD
123478-HxCDF
123678-HxCDF
234678-HxCDF
123789-HxCDF
TOTAL HxCDF
123478-HxCDD
123678-HxCDD
123789-HxCDD
TOTAL HxCDD
1234678-HpC
1234789-HpC
TOTAL HpCDF
1234678-HpC
TOTAL HpCDD
OCDF
OCDD
37C1-TCDD
t ,
1
1
1
IDF
IDD
i
)
)F
3F
)F
3D
3D
:DF
:DF
:DF
:DF
3F
:DD
:DD
:DD
3D
?CDF
?CDF
DF
pCDD
DD
ndards
DF 234
DF 478
DF 234
DF 789
:DD 478
:DF 789
Standards
8-TCDF
'8-TCDD
IDF 123
S
RF SO %RSD
2.087 0.000 0%
1.625 0.000 0%
0.687 0.000 0%
1.326 0.000 0%
1.082 0.000 0%
0.933 0.000 0%
1.251 0.116 9%
1.251 0.116 9%
1.191 0.231 19%
1.191
1.111
1.115
1.113
1.256
1.256
1.215
1.574
1.247
1.105
1.285
0.953
1.133
1.091
1.059
1.543
1.184
1.363
1.068
1.068
1.493
1.105
RF
0.843
0.970
0.959
0.926
0.805
0.973
0.771
RF
1.318
1.066
1.133
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0 .
0.
0.
0.
0.
0.
0.
0,
0
0
0
0
0
0
0
0
0
0
0
0
0
0
231
082
061
069
113
113
064
099
069
060
062
067
070
067
067
,103
,100
.095
.089
.089
.131
.066
SD
.038
.030
.042
.021
.044
.027
.049
SD
.065
.020
.051
19%
7%
5%
6%
9%
9%
5%
6%
6%
5%
5%
7%
6%
6%
6%
7%
8%
7%
8%
8%
9%
6%
%RSD
5%
3%
4%
2%
5%
3%
6%
%RSD
5%
2%
5%
vw
RT
8:15
8:42
10:38
11:09
13:59
14:03
19:43
20:36
24:
24:
25:
27:
28:
28:
29:
28:
28:
29:
12
59
22
55
01
32
15
41
46
03
30:45
RT/LO
0:01
0:34
6:43
7:34
10:43
12:34
15:43
16:34
20:11
21:21
24:01
24:45
26:45
RT/HI Ratiol Ratio2
13:43 2.931
14:34 2.827
14:43 5.965
15:34 1.609
17:43 1.025
18:34 1.064
23:43 0.799
0.799
24:34 0.772
28:
29:
32:
32:
34:
11
21
01
45
45
31:57
31:
:37
34:09
34
:03
RT
20
24
27
28
29
28
31
19
20
24
:36
:58
:55
:32
:15
:40
:57
RT
:43
:34
:11
27:36
30:02
30:02
RT/LO
18:34
22:11
28:45
RT/LO
18:43
18:34
20:11
35:
38
38
:36
:02
:02
RT/HI
22
26
34
:34
:11
:45
RT/HI
20
22
28
:43
:34
:11
0.772
1.552
1.470
1.509
1.526
1.526
1.247
1.260
1.243
1.246
1.249
1.265
1.251
1.233
1.249
1.034
1.080
1.053
0.993
0.993
0.376
0.902
Ratiol Ratio2
1.470
0.518
0.517
0.519
1.241
0.424
Ratiol Ratio2
0.734
0.802
1.447
N
1
1
1
1
1
1
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
N
5
5
5
5
5
5
5
N
5
5
5
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-------
13C12-PeCDD 123 0.635 0.082 13% 25:21 21:21 29:21 1.461 5
13C12-HXCDF 678 1.204 0.073 6% 28:01 24:01 32:01 0.522 5
13012-HxCDD 678 0.995 0.017 2% 28:45 27:45 29:45 1.240 5
13C12-HpCDF 678 0.887 0.046 5% 30:45 28:45 34:45 0.429 5
13C12-HpCDD 678 0.815 0.077 9% 31:36 30:36 32:36 1.019 5
13C12-OCDD 0.519 0.080 15% 34:02 32:02 36:02 0.866 5
Recovery Standards RF SD %RSD RT RT/LO RT/HI Ratiol Ratio2 M
13C12-1234-TCDD 1.000 0.000 0% 20:21 0.811 5
13C12-HXCDD 789 1.000 0.000 0% 29:02 1.231 5
•»* End of Report •**
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-------
Appendix C.3
Analytical Data
Method 29 Multiple Metals
-------
-------
CASE NARRATIVE
Analysis of Samples for the Presence of Trace Metals
Method 29 April 1996 Rev.
Client:
Pacific Environmental Services
TLI Project Number: 43411
Date: November 1,1997
This report should only be reproduced in full.
Any partial reproduction of this report requires permission from
Triangle Laboratories, Inc.
Rev. 07-May-97
Triangle Laboratories, Inc.
801 Capitola Drive P.O. Box 13485
Durham, NC 27713-4411 Research Triangle Park, NC 27709-3485
919-544-5729 Fax # 919-544-5491
-------
Triangle Laboratories, Inc. November*!, Iff?
Case Narrative TLI Project #: 43411
Overview
Six train samples and a blank train sample were analyzed for silver (Ag), arsenic (As),
barium (Ba), beryllium (Be), cadmium (Cd), cobalt (Co), chromium (Cr), copper (Cu),
manganese (Mn), nickel (Ni), phosphorus (P), lead (Pb), antimony (Sb), selenium (Se),
thallium (Tl), zinc (Zn), and mercury (Hg). For all analyses, the samples and associated
QC samples were prepared and analyzed following the guidelines of Method 29 April
1996 Rev. Results reported relate only to the items tested.
PC Remarks
The release of this set of data by Triangle Laboratories, Inc. was authorized by the Quality
Control Chemist who has reviewed each sample data package individually following a
series of inspections/reviews. When applicable, general deviations from acceptable QC
requirements are identified below and comments are made on the effects of these
deviations upon the validity and reliability of the results. Specific QC issues associated
with this particular project are:
Sample Receipt:
Seven train samples were received without tocilant on September 26,1997 in good condition.
The sample I-M29-2-BHAR was received, but this sample was not listed on the client' schain-
of-custody.
Sample Preparation:
Laboratory documentation of the sample preparation is included in the data package.
Instrumentation:
Silver (Ag), arsenic (As), barium (Ba), beryllium (Be), cadmium (Cd), cobalt (Co),
chromium (Cr), copper (Cu), manganese (Mn), nickel (Ni), phosphorus (P), lead (Pb),
antimony (Sb), selenium (Se), and zinc (Zn) concentrations were determined by
Inductively Coupled Plasma Emission Spectroscopy (ICP).
Thallium (Tl) concentrations were analyzed by Graphite Furnace Atomic Absorption
(GFAA).
Mercury (Hg) concentrations were determined by Cold Vapor Atomic Absorption
(CVAA).
-------
Triangle Laboratories, Inc. November 1,1997
Case Narrative TLI Project #: 43411
The linear range for the instrument TJA 61E Trace Analyzer was based on four standards
and a blank, which established a correlation coefficient value greater than or equal to
0.995. A calibration curve, based on a blank and one standard, is established for each
analytical run, followed by a check high standard and an initial calibration verification
(ICV). The check high standard does not deviate from the calibration curve by more than
5%. In addition, continuing calibration verifications (CCVs) are performed throughout
the analytical run.
A Reporting Detection Limit (RDL) is used instead of an Instrument Detection Limit
(DDL). The spectrometer and atomic absorption instruments can achieve low detection
limits between 0.2-8 ppb levels for many analytes. Triangle Labs is using RDL values of
1-10 times the IDL as detection limits for reporting purposes.
Data Review:
All analytes found in the method blank (MB) are detected at a level equal to or less than
the respective Reporting Detection Limits (RDLs) except for Ni. The following guidelines
may be used to assess analyte concentrations relative to the method blank: 1. Analyte
quantitations should be considered valid if the level of blank contamination is less than five
percent of the level detected in the field sample, 2. Analyte quantitations should be
considered estimated if the analyte level in the sample is five to twenty times the level of
the analyte in the blank, or 3. Analytes whose level in a sample is the same as or less than
five times the level detected in the associated blank should be considered present likely
due to laboratory contamination and not native to the sample. Please note that the Ni
results that are near the RDL should be considered biased high.
The laboratory control sample (LCS) for Ni and Tl demonstrated percent recoveries
outside the QC criteria of 80-120 percent. Please note that the sample results should be
considered biased high for Ni and biased low for Tl. No sample was available for a second
preparation.
All samples were received outside of the 28 day sampling to analysis holding time for Hg,
therefore the holding time for Hg could not be met. All samples were analyzed within the
six month sampling to analysis holding time for all other requested analytes.
The sample IDs on the client chain-of-custody did not match with the IDs on the sample
containers. The sample IDs on TLI's chain-of-custody matches the IDs on the sample
containers. The sample IDs on the Hg spreadsheets for the KMnO4 and HCI containers do
not have the addition description added in order to alleviate redundancy.
-------
Triangle Laboratories, Inc. November 1,1997
Case Narrative TLI Project #: 43411
The concentrations for Tl demonstrated high negative numbers for the samples analyzed
by ICP, therefore the samples were analyzed by GFAA in order to obtain better results. A
duplicate analysis is not reported for elements analyzed by GFAA. The GFAA instrument
analyzes two separate aliquots of the sample and averages the values for a final result.
These two analyses agree within a RPD of 20% or a second ran is done for that sample.
The ICP instrument analyzes one continuous aliquot three times and averages the values
for a final result. The ICP does not take two separate aliquots, therefore a DA is
performed.
The serial dilution results for Cr for the sample O-M29-1-FHACE,FHAR,FILTER FH
demonstrated a RPD outside the QC control criteria of 10.0 percent, which indicates the
presence of an amount of interferents specific to this analyte in the native sample matrix.
Please note that the post-digestion spike (PDS) for Cr demonstrated a percent recovery
within QC criteria, which indicates no significant amount of interfences specific to this
analyte in the native sample matrix. Also note that this sample should be considered
biased low for Cr due to matrix interferences.
The post-digestion spike (PDS) for Co for the sample O-M29-1-FHACE,FHAR,FILTER
FH demonstrated a percent recovery outside the QC criteria, which may indicate
significant matrix effects specific to this analyte in the native sample matrix. Please note
that this sample should be considered biased low for Co due to matrix interferences.
The recoveries for the post-digestion spike (PDS) are not reported for Ba and Mn for
sample O-M29-1-FHACE,FHAR,FILTER FH. The spike concentrations added were
insignificant in comparison to the levels of these analytes present in the native sample.
The pre-digestion spike (MS) and the pre-digestion spike duplicate (MSD) for Hg for the
samples O-M29-1-HNO3 BH, O-M29-2-HN03 BH, I-M29-1-HNO3 BH, I-M29-2-
HNO3 BH, and I-M29-3-HNO3 BH demonstrated percent recoveries outside the QC
criteria, which may indicate significant matrix effects specific to this analyte in the native
sample matrix. Please note that samples O-M29-1-HNO3 BH, O-M29-2-HNO3 BH and
I-M29-1-HNO3 BH should be considered biased low due to matrix interferences. Also
note that samples I-M29-2-HNO3 BH and I-M29-3-HNO3 BH should be considered
biased high due to matrix interferences.
QC requirements:
The duplicate analyses for analytes analyzed by ICP cannot be considered valid qualifiers if
the concentrations of the analytes in the original and/or duplicate sample are not at least
ten times the respective RDLs. The RPDs for these analyses are indicated by or "
-------
Triangle Laboratories, Inc. November 1,1997
Case Narrative TLI Project*: 43411
For duplicate analyses which are valid qualifiers, the quality control RPD is ± 20.0
percent. If RPDs are outside this range, interferences are suspected.
The serial dilution analyses for analytes analyzed by GFAA cannot be considered valid
qualifiers if the concentrations of the analytes in the serial dilution sample are not at least
five times the respective RDLs. The serial dilution RPDs for these analyses are indicated
by "
-------
TRIANGLE LABORATORIES, INC.
LIST OF CERTIFICATIONS AND ACCREDITATIONS
ENVIRONMENTAL
American Association for Laboratory Accreditation. Accredidation pending. Certificate
Number 0226-01. Accreditation for technical competence in Environmental Testing.(Including
Waste Water, Sol/Haz Waste, Pulp/Paper, and Air Matrices) Parameters are AOX/TOX, and
Dioxin/Furan. Method 1613 for Drinking Water.
State of Alabama, Department of Environmental Management. Expires December 31,
1997. Laboratory I.D. # 40950. Dioxin in drinking water.
State of Alaska, Department of Environmental Conservation. Expires December 21, 1997.
Certificate number OS-00397. Dioxin in drinking water.
State of Arizona, Department of Health Services. Expires May 26, 1998. Certificate
#A20423. Drinking Water for Dioxin, Dioxin in WW and S/H Waste.
State of Arkansas, Department of Pollution Control and Ecology. Expires February 18,
1998. Pulp/paper, soil, water, and Hazardous Waste for Dioxin/Furan; AOX/TOX.
State of California, Department of Health Services. Expires August 31, 1999. Certificate
#1922. Selected Metals in Waste Water; Volatiles, Semi-volatiles, and Dioxin/furan in WW and
Sol/Haz Waste. Dioxin in drinking water.
State of Connecticut, Department of Health Services. Recertification pending. Registration
#PH-0117. Dioxin in drinking water.
Delaware Health and Social Services. Expires December 31, 1997. Certificate #NC 140.
Dioxin in drinking water.
Florida Department of Health and Rehabilitative Services. Expires June 30, 1998.Dioxin in
DW. Drinking Water ID HRS# 87424. Metals, Extractable Organics (GC/MS), Pesticides/PCB's
(GC) and Volatiles (GC/MS) in Environmental Samples. Environmental water ID HRS#
E87411.
Hawaii Department of Health. Expires March 1, 1998. Dioxin in drinking water. "Accepted"
status for regulatory purposes .
Revised 10/28/97 RM
Printed 10/29/97 Triangle Laboratories, Inc.
Pnnted 10/29/97
Durham, NC 27713-4411 Research Triangle Park, NC 27709-348
919-544-5729 Fax #919-544-5491
-------
Idaho Department of Health and Welfare. Expires November 30, 1997. Dioxin in drinking
water.
State of Kansas, Department of Health and Environment. Expires January 31, 1998.
Environmental Analyses/Non potable Water and Solid and Hazardous Waste. Method 1613
for drinking water. ID #'s - Drinking water and/or pollution control - E-215. Solid or Hazardous
Waste-E-1209.
Commonwealth of Kentucky, Department for Environmental Protection. Expires
December 31, 1997. ID#90060. Dioxin in drinking water.
Maryland Department of Health and Mental Hygiene. Expires September 30, 1998.
Certification #235. Drinking water by Method 1613A.
State of Michigan, Department of Public Health. Expires June 3, 1998. Drinking water by
Method 1613.
Mississippi State Department of Health. No expiration date.. Dioxin in drinking water.
Montana Department of Health and Environmental Services. Expires December 31, 1997.
Dioxin in drinking water.
State of New Jersey, Department of Environmental Protection and Energy. Extended by
state. Temporary certificate until December 31, 1997. ID #67851. BNAs and Volatiles. Dioxin in
drinking water.
State of New Mexico, Environment Department. Recertification pending. Dioxin in drinking
water.
New York State Department of Health. Expires April 1, 1998. ID #11026. Environmental
Analyses of non-potable Water, Solid and Hazardous Waste. Method 1613 in DW.
State of North Carolina, Department of Environment Health and Natural Resources
Expires August 31, 1999. Certificate # 37751. Dioxin in drinking water.
State of North Carolina, Department of Environment, Health, and Natural Resources,
Division of Environmental Management. Expires December 31, 1997. Certificate # 485.
Metals, pesticides & PCBs, semi-volatiles and volatiles; TCLP.
North Dakota State Department of Health and Consolidated Laboratories. Expires
December 31, 1997. Certificate # R-076. Effective October 4, 1993. Dioxin in drinking water.
Revised 10/28/97 RM
Printed 10/29/97
-------
Oklahoma Department of Environmental Quality. Expires August 31, 1998. Laboratory
#9612. Dioxin by 1613A, 8290 and 8280.
State of South Carolina, Department of Health and Environmental Control. Expires April 1,
1998. Certificate number #99040001 (drinking water). Expires August 31, 1999. Certificate
number #99040002 (other parameters). Dioxin/Furans, BNA, Volatiles, and PCBs/pesticides
under Clean Water Act, 2,3,7,8-TCDD for Drinking Water, and Organic extractables for Solid
and Hazardous Waste.
State of Tennessee. Department of Environment and Conservation. Expires February 5,
1999. ID #02992. Method 1613 Drinking water only.
U.S. Department of Agriculture Soil Permit. Expires September 30, 2001. Permit No. S-
3790. Under the authority of the Federal Plant Pest Act, permission is granted to receive
foreign soil samples for use in laboratory analysis.
U.S. Army Corps of Engineers. Expires November 30, 1997. Validated to perform methods
8280 & 8290 for Lockboume Landfill Site Investigation, Defense Distribution Depot Projects,
and assorted projects for the USAGE North Pacific Division Laboratory.
U.S. EPA Region V. Expires November 14, 1999. Dioxin in drinking water.
U.S. EPA Region VIII, for the State of Wyoming. Expires November 13, 1997. Dioxin in
drinking water.
State of Utah, Department of Health. Expires December 31, 1997. Certificate Number E-166.
Certification for the following parameters: Semi-Volatiles and Volatiles under RCRA; Volatiles
under Clean Water Act; Dioxin/furans by Method 8280; Drinking water for Dioxin by Method
1613; Metals including Mercury and Microwave Digestion.
Commonwealth of Virginia, Department of General Services, Division of Consolidated
Laboratory Services. Expires June 30, 1998. ID # 00341. Dioxin in drinking water.
State of Washington, Department of Ecology. Expires September 11, 1998. Lab
Accreditation Number C067. Scope of Accreditation applies to water analyses for
Polychlorinated Dibenzo-p-dioxins and Polychlorinated Dibenzofurans, BNA Extr (Semivolatile)
Organics and Purgeable (Volatile) Organics.
State of Washington, Department of Health. Expires April 30, 1998. Dioxin in drinking water.
Lab I.D. 129
State of West Virginia, Department of Health. Expires December 31, 1997. Certificate No.
9923(C). Dioxin in drinking water.
Revised 10/28/97 RM
Printed 10/29/97
8
-------
State of Wisconsin, Department of Natural Resources. Expires August 31, 1998.
Laboratory ID Number 999869530. Certification for the following categories of Organics:
Purgeable, Base/Neutral, Acid, PCBs, and Dioxin. Expires November 14, 1999. Laboratory ID
999869530. Dioxin in drinking water.
PHARMACEUTICAL
Drug Enforcement Agency (DEA). Expires November 30, 1997. Registration number
RT01195835. Controlled substance registration for schedules 1,2,3,3N,4,5.
N.C. Department of Human Resources. Expires October 31, 1998. Registration number
NC-PT 0000 0031. North Carolina controlled substances registration. Application submitted for
renewal.
Food & Drug Administration (FDA) Registration. Expires June 1998. ID #'s 001500
1053481. Annual registration of drug establishment. Annual registration of drug establishment.
OTHER
Clinical Laboratory Improvement Amendments (CLIA) Registration. Expires May 30, 1999.
ID # 34D0705123. Department of Health & Human Services, Health Care Financing
Administration.
U.S. EPA Large Quantity Hazardous Waste Generator. No expiration date. EPA ID
#NCD982156879. Permit indicates that the laboratory is a large generator of hazardous waste.
North Carolina Radioactive Materials License. Expires April 30 1998. License No. 032-
0954-1. License authorizes the licensee to receive, acquire, own, possess, transfer, import and
use such radioactive materials as designated.
North Carolina General License for Radiation Protection. No. expiration date. License No.
032-875-OG. The general license applies only to radioactive material contained in devices
which have been manufactured and labeled in accordance with specific requirements.
Revised 10/28/97 RM
Printed 10/29/97
9
-------
ABBREVIATIONS
BH = Bade Half
CCB — Continuing Calibration Blank
CCV » Continuing Calibration Verification
CHECK HS * Check High Standard
D = OUP = Anaiyticai DTpBnor (Piepared Dnpfrarr)
DA 3 Duplicate Analysis
FH = Front Half
FV = Enai Digestaie Volume
ICB = Imnai Calibration Blank
ICV = Tnirial Calibration Verification
ICSAB = Interference Check Solution (Solution AB)
I = Tnirial
Solution AB contains common inreifeiems in addition co the aoaiyte of interest.
DDL = Instrument Detection TJirrir
L = Serial Dilution
LCS = Liberator/ Control Spike Sample
NCB = Method Blank
MPV = Mercury Preparation Volume
MS = Prs-
-------
STANDARD CONCENTRATIONS
for the TJA 61E TRACE ANALYZER
Analyte
Ag
As
AI
B
Ba
Be
Ca
Cd
Ce
Co
Cr
Cu
Fe
K
Li
Mg
Mn
Mo
Na
Ni
P
Pb
Sb
Se
Sn
Sr
Ti
Tl
V
Zn
Units
PpbM
ppb
ppb'-
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
ppb
Ppb
ppb
High Std
" 1 1000 <^;<
1000
"•"1000-*
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
10000
1000
1000
1000
1000
10000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
ICV/CCV
•v^sooV -
500
"'•"'t^&CAlV
£"„>.•;•' 3UU '
500
500
500
500
500
500
500
500
500
500
5000
500
500
500
500
5000
500
500
500
500
500
500
500
500
500
500
500
ICSAB
500 v
500
500000
500
500
500
500000
500
500
500
500
500
200000
19000
500
500000
500
500
5000
500
500
500
500
500
500
650
500
500
500
500
RDL
'-•1 -
5
:/;$o;
7
.2
1
60
1
3
1
2
2
40
220
1
30
2
2
300
3
30
2
4
3
13
1
8
5
2
12
Wavelength
3280
1890
3082
2496
4934
3130
3179
2265
4186
2286
2677
3247
2714
7664
6706
2790
2576
2020
3302
2316
2149
2203
2068
1960
1899
4215
3349
1908
2924
2062
Note: Use this reference page to review the raw data from the TJA 6IE Trace Analyzer.
This page includes the standard concentrations for the check high standard, initial calibration
verification (ICV), continuing calibration verification (CCV), and the interference check solution
(ICSAB). In addition the reporting detection limit (RDL) and wavelength are reported for each
analyte.
Revision Date: 15-Jul-96
11
-------
CALCULATIONS FOR AIR SAMPLES
RESULTS FOR TRACE METALS (except mercury):
RESULT in |ig (Front Half) = jig/L * FV CmU) * DF
1000 mL/L
^ RESULT in u,g (Back Half & Impingers) = u.g/L * TV CmD * FV (mU) * DF
mL used * 1000 mL/L
FV = final volume in mL
TV = total volume in mL
. DF = Dilution Factor
The RESULTS for combined Front Half & Back Half samples use the same calculation as the
Back Half & impinger samples.
RESULTS FOR MERCURY (Kg):
RESULT in u.g (Front Half) = ^ig/L * (mL FV/mL aliquot) * MPV * DF
RESULT in jig (Back Half & Impingers) = ug/L * (mL TV/mL aliquot) * MPV * DF
MPV = mercury preparation volume = 0.1 L
%REC (Percent Recovery) for MS/MSP He spikes;
%REC = spike sample results - original sample results * 100
true spike sample results
NOTE: Original sample results less than the RDL are not used in calulations.
%REC (Percent Recovery) for PDS:
%REC = Spike sample ug/L cone. - original sample ug/L cone. * 100
spike cone. (ug/L)
%REC (Percent Recovery) for LCS/LCSD:
%REC = SpDce sample u.g/L cone. * 100
spike cone. Qig/L)
RPDs; RPD = I Result 2 - Result 1 I * 100
(Result 2 + Result l)/2 Rev. 2-Oct-96
12
-------
Client: Pacific Environmental Services
Project Number: 43411
Sample Report
Client Sample ID:
TLI Sample ID:
Date Received'
Date Prepared:
Date Analyzed'
Matrix:
O-M29-1-FHACE,FHAR,FILTER FH
184-84-1 ABC FH
September 26. 1997
October 14-16. 1997
October 20. 1997
Air
Analyt& ;
Aa
As
Ba
Be
Cd
Co
Cr
Cu
Mn
Ni
P
Pb
Sb
Se
Tl
Zn
Cona
tooTU
2.411
-0.017
539.788
-0.158
-3.194
-32.448
125.993
71.253
677.158
59.056
505.792
30.749
38.440
46.739
1.600
214.073
mt
Total Vol.
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
mL
Used
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
mL
FtnalVol
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
Dilation
Factor
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
Total ug. j
Result
0.241
< 0.500
54.0
< 0.100
< 0.100
< 0.100
12.6
7.13
67.7
5.91
50.6
3.07
3.84
4.67
< 0.200
21.4
Triangle Laboratories, Inc.
801 Capitola Drive * Durham, North Carolina 27713
Tele: (919) 544-5729 * Fax: (919) 544-5491
Printed: Ol-Nov-97 at 03:09 PM
13
-------
Client: Pacific Environmental Services
Project Number: 43411
Sample Report
Client Sample ID:
TLI Sample ID:
Date Received:
Date Prepared:
Date Analvzed:
Matrix:
O-M29-1-FHACEJFHAR.FILTER FH L
184-84-1 ABC FHL
September 26. 1997
October 14-16. 1997
October 20. 1997
Air
Analyte j
Aa
As
Ba
Be
Cd
Co
Cr
Cu
Mn
Ni
P
Pb
Sb
Se
Tl
Zn
Cone,
fcO/U
0.821
2.538
111.725
0.010
-0.554
-6.660
32.500
14.199
144.188
13.322
110.290
7.605
11.527
10.881
-0.400
46.879
mt
Total Voi
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
«t
Used
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
mt
Final Vot
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
Dilution
Factor
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
Total «Q '- ,
Result " -
< 0.500
< 2.50
55.9
< 0.500
< 0.500
< 0.500
16.3
7.10
72.1
6.66
55.1
3.80
5.76
5.44
< 1.00
23.4
Triangle Laboratories, Inc.
801 Capitola Drive * Durham, North Carolina 27713
Tele: (919) 544-5729 * Fax: (919) 544-5491
Printed: Ol-Nov-97 at 03:09 PM
14
-------
Client: Pacific Environmental Services
Project Number: 43411
Sample Report
Client Sample ID:
TLI Sample ID:
Date Received:
Date Prepared:
Date Analyzed'
Matrix:
O-M29-1-HNO3 BH
184-84-1DEBH
September 26. 1997
October 14-16. 1997
October 20. 1997
Air
Arialvte ;
Aa
As
Ba
Be
Cd
Co
Cr
Cu
Mn
Ni
P
Pb
Sb
Se
71
Zn
Core.
fcoto
1.302
-2.625
8.541
-0.012
4.544
-0.340
5.779
20.497
22.235
32.856
562.480
51.852
1.411
9.124
0.200
217.420
**,
TotatVol
1940
1940
1940
1940
1940
1940
1940
1940
1940
1940
1940
1940
1940
1940
1940
1940
ni.
Used
1840
1840
1840
1840
1840
1840
1840
1840
1840
1840
1840
1840
1840
1840
1840
1840
Rt
Final Vol.
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
Dlutfon
factor
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
Total ug
Result j
0.137
< 0.527
0.901
< 0.105
0.479
< 0.105
0.609
2.16
2.34
3.46
59.3
5.47
< 0.422
0.962
< 0.21 1
22.9
Triangle Laboratories, Inc.
801 Capitola Drive * Durham, North Carolina 27713
Tele: (919) 544-5729 * Fax: (919) 544-5491
Printed: Ol-Nov-97 at 03:09 PM
15
-------
Client: Pacific Environmental Services
Project Number: 43411
Sample Report
Client Sample ID:
TLI Sample ID:
Date Received:
Date Prepared:
Date Analvzed:
Matrix:
O-M29-1-HNO3 BH L
184-84-1DEBHL
September 26. 1997
October 14-16. 1997
October 20. 1997
Air
Analvte ;
Aa
As
Ba
Be
Cd
Co
Cr
Cu
Mn
Ni
P
Pb
Sb
Se
Tl
Zn
Cone.
fcoto
0.153
-2.144
1.564
-0.016
0.940
-0.489
1.401
3.143
3.694
5.411
108.558
11.312
0.320
0.079
0.500
44.302
" {&
ToferfVoL
1940
1940
1940
1940
1940
1940
1940
1940
1940
1940
1940
1940
1940
1940
1940
1940
Hi*
Used
1840
1840
1840
1840
1840
1840
1840
1840
1840
1840
1840
1840
1840
1840
1840
1840
nt
RnalVd.
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
Dilution
Factor
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
Totafuq
Result ;
< 0.527
< 2.64
< 1.05
< 0.527
< 0.527
< 0.527
< 1.05
1.66
1.95
2.85
57.2
5.96
< 2.11
< 1.58
< 1.05
23.4
Triangle Laboratories, Inc.
801 Capitola Drive * Durham, North Carolina 27713
Tele: (919) 544-5729 * Fax: (919) 544-5491
Printed: Ol-Nov-97 at 03:09 PM
16
-------
Client: Pacific Environmental Services
Project Number; 43411
Sample Report
Client Sample ID:
TLI Sample ID:
Date Received:
Date Prepared:
Date Analvzed:
Matrix:
0-M29-2-FHACE J7HAR,FILTER FH
184-84-2ABC FH
September 26. 1997
October 14-16. 1997
October 20. 1997
Air
Analvte \
Aa
As
Ba
Be
Cd
Co
Cr
Cu
Mn
Ni
P
Pb
Sb
Se
Tl
Zn
Cone.
fcoto
2.154
2.119
401 .536
-0.235
1.741
-23.080
104.724
57.339
633.126
50.162
463.845
24.095
38.476
37.508
0.600
183.228
. mt
Total Vol.
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
, Bt
Used
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
mL
FaralVal
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
Difution
Factor
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
Total w
Result
0.215
< 0.500
40.2
< 0.100
0.174
< 0.100
10.5
5.73
63.3
5.02
46.4
2.41
3.85
3.75
< 0.200
18.3
Triangle Laboratories, Inc.
801 Capitola Drive * Durham, North Carolina 27713
Tele: (919) 544-5729 * Fax: (919) 544-5491
Printed: Ol-Nov-97 at 03:09 PM
17
-------
Client: Pacific Environmental Services
Project Number: 43411
Sample Report
Client Sample ED:
TLI Samole ID:
Date Received:
Date Prepared'
Date Analyzed:
Matrix:
O-M29-2-FHACE JHAR.FILTER FH DA
184-84-2ABCFHDA
Seotember26. 1997
October 14-16, 1997
October 20. 1997
Air
Analvte
Aa
As
Ba
Be
Cd
Co
Cr
Cu
Mn
Ni
P
Pb
Sb
Se
Tl
Zn
Cona
fco7L>
2.187
-2.546
401.409
-0.310
0.762
-25.496
104.896
58.095
630.072
50.148
444.771
21.354
32.953
39.887
N/A
181.032
mt
Total Vol.
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
Hit
Used
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
mt
RnalVof.
100
100
100
100
100
100
100
100
100
100
100
100
100
100
N/A
100
Dilution
Factor
1
1
1
1
1
1
1
1
1
1
1
1
1
1
N/A
1
Total w
Result
0.219
< 0.500
40.1
< 0.100
< 0.100
< 0.100
10.5
5.81
63.0
5.01
44.5
2.14
3.30
3.99
N/A
18.1
Triangle Laboratories, Inc.
801 Capitola Drive * Durham, North Carolina 27713
Tele: (919) 544-5729 * Fax: (919) 544-5491
Printed: Ol-Nov-97 at 03:09 PM
18
-------
Client: Pacific Environmental Services
Project Number: 43411
Sample Report
Client Sample ID:
TLI Sample ID-
Date Received:
Date Prepared:
Date Analvzed:
Matrix:
O-M29-2-HN03 BH
184-84-2DE BH
Sentember26. 1997
October 14-16. 1997
October 20. 1997
Air
Aralvte
Aa
As
Ba
Be
Cd
Co
Cr
Cu
Mn
Ni
P
Pb
Sb
Se
Tl
Zn
Cone.
CUOTU
0.635
-3.373
7.088
-0.003
1.921
-0.164
5.627
13.779
110.581
14.447
660.558
28.585
0.257
6.474
0.800
73.430
*L
TdtfVoL
1910
1910
1910
1910
1910
1910
1910
1910
1910
1910
1910
1910
1910
1910
1910
1910
' rtiL
Used
1810
1810
1810
1810
1810
1810
1810
1810
1810
1810
1810
1810
1810
1810
1810
1810
nt
Final Vol.
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
•dutfon'
Factor
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
TolalwQ
Result
< 0.106
< 0.528
- 0.748
< 0.106
0.203
< 0.106
0.594
1.45
11.7
1.52
69.7
3.02
< 0.422
0.683
< 0.211
7.75
Triangle Laboratories, Inc.
801 Capitola Drive * Durham, North Carolina 27713
Tele: (919) 544-5729 * Fax: (919) 544-5491
Printed: Ol-Nov-97 at 03:09 PM
19
-------
Client: Pacific Environmental Services
Project Number: 43411
Sample Report
Client Sample ID:
TLI Samole ID-
Date Received:
Date Prepared:
Date Analyzed:
Matrix:
O-M29-2-HNO3 BH DA
184-84-2DEBHDA
September 26. 1997
October 14-16. 1997
October 20. 1997
Air
Analyte :
Aa
As
Ba
Be
Cd
Co
Cr
Cu
Mn
Ni
P
Pb
Sb
Se
Tl
Zn
Cona
tooto
-1.000
-2.338
6.838
-0.058
1.709
-1.009
4.196
12.233
109.478
13.690
650.906
28.606
-5.254
7.037
N/A
71.752
mL
TotatVol
1910
1910
1910
1910
1910
1910
1910
1910
1910
1910
1910
1910
1910
1910
N/A
1910
Hi.
* Used *
1810
1810
1810
1810
1810
1810
1810
1810
1810
1810
1810
1810
1810
1810
N/A
1810
nt
RnalVd.
100
100
100
100
100
100
100
100
100
100
100
100
100
100
N/A
100
D8utior>
Factor
1
1
1
1
1
1
1
1
1
1
1
1
1
1
N/A
1
Toteltjg i
Result
< 0.106
< 0.528
0.722
< 0.106
0.180
< 0.106
0.443
1.29
11.6
1.44
68.7
3.02
< 0.422
0.743
N/A
7.57
Triangle Laboratories, Inc.
801 Capitola Drive * Durham, North Carolina 27713
Tele: (919) 544-5729 * Fax: (919) 544-5491
Printed: Ol-Nov-97 at 03:09 PM
20
-------
Client: Pacific Environmental Services
Project Number: 43411
Sample Report
Client Sample ID:
TLI Sample ID:
Date Received' —
Date Prepared:
Date Analyzed:
Matrix:
O-M29-3-FHACE.FHAR
FILTER FH
184-84-3 ABC FH
September 26. 1997
October 14-16. 1997
October 20. 1997
Air
Anah/te
Ad
As
Ba
Be
Cd
Co
Cr
Cu
Mn
Ni
P
Pb
Sb
Se
Tl
Zn
Cona
(UOto
0.873
3.733
692.085
-0.489
-1.272
-17.019
117.209
103.925
1075.564
63.151
762.477
31.982
39.115
39.481
-0.900
248.755
• mt
Total Vd.
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
3t
Used
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
ml
Final Vet
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
Dilation
Factor
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
Total us
Result
< 0.100
< 0.500
69.2
< 0.100
< 0.100
< 0.100
11.7
10.4
108
6.32
76.2
3.20
3.91
3.95
< 0.200
24.9
Triangle Laboratories, Inc.
801 Capitola Drive * Durham, North Carolina 27713
Tele: (919) 544-5729 * Fax: (919) 544-5491
Printed: Ol-Nov-97 at 03:09 PM
21
-------
Client: Pacific Environmental Services
Project Number: 43411 ~
Sample Report
Client Sample ID:
TLI Sample ID:
Date Received:
Date Prepared:
Date Analyzed"
Matrix:
0-M29-3-HNO3 BH
184-84-3DE BH
Seotember26. 1997
October 14-16. 1997
October 20. 1997
Air
';
Analvte '
Aa
As
Ba
Be
Cd
Co
Cr
Cu
Mn
Ni
P
Pb
Sb
Se
Tl
Zn
C&na
'..tali
0.472
-4.540
6.268
-0.046
1.830
-1.202
8.405
42.971
77.676
16.960
645.299
26.987
0.675
9.011
0.900
73.823
rot
TotaJVol
1530
1530
1530
1530
1530
1530
1530
1530
1530
1530
1530
1530
1530
1530
1530
1530
JTi.
Used
1430
1430
1430
1430
1430
1430
1430
1430
1430
1430
1430
1430
1430
1430
1430
1430
, ni
Final VoL
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
Dilution
Factor
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
Total tig
Result
< 0.107
< 0.535
0.671
< 0.107
0.196
< 0.107
0.899
4.60
8.31
1.81
69.0
2.89
< 0.428
0.964
< 0.214
7.90
Triangle Laboratories, Inc.
801 Capitola Drive * Durham, North Carolina 27713
Tele: (919) 544-5729 * Fax: (919) 544-5491
Printed: Ol-Nov-97 at 03:09 PM
22
-------
Client: Pacific Environmental Services
Project Number: 43411
Sample Report
Client Sample ID:
TLI Samole ID-
Date Received:
Date Prepared:
Date Analyzed:
Matrix:
I-M29-1-FHACEFHARJFILTER FH
184-84-4 ABC FH
September 26. 1997
October 14-16. 1997
October 20. 1997
Air
Analyte
Aq
As
Ba
Be
Cd
Co
Cr
Cu
Mn
Ni
P
Pb
Sb
Se
Tl
Zn
Cona
femTU
11.971
50.286
10818.790
L -39.185
200.137
631.576
953.666
6107.147
24721 .447
574.107
42128.582
804.716
-2.931
-254.506
60.800
7400.913
0*, -
Total V
-------
Client: Pacific Enyironmental Services
Project Number: 43411
Sample Report
Client Sample ED:
TLI Sample DO:
Date Received:
Date Prepared:
Date Analyzed:
Matrix:
I-M29-1-HNO3 BH
184-84-4DBH
September 26. 1997
October 14-16. 1997
October 20. 1997
Air
Anatvte
Ad
As
Ba
Be
Cd
Co
Cr
Cu
Mn
Ni
P
Pb
Sb
Se
Tl
Zn
Oona I
tuofL\
-0.554
-5.631
4.733
-0.096
1.898
-1.351
3.620
13.739
12.341
13.553
345.681
41.442
-3.091
1.140
0.100
185.580
Fit
TotafVol -
750
750
750
750
750
750
750
750
750
750
750
750
750
750
750
750
' fit,
- 'U$«r '
650
650
650
650
650
650
650
650
650
650
650
650
650
650
650
650
TOL
FfoatVoI.
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
DiutioB
^Factor
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
Tolalwg
Result
< 0.115
< 0.577
0.546
< 0.115
0.219
< 0.115
0.418
1.59
1.42
1.56
39.9
4.78
< 0.462
< 0.346
< 0.231
21.4
Triangle Laboratories, Inc.
801 Capitola Drive * Durham, North Carolina 27713
Tele: (919) 544-5729 * Fax: (919) 544-5491
Printed: 04-Nov-97 at 08:35 AM
24
-------
Client: Pacific Environmental Services
Project Number: 43411
Sample Report
Client Sample ID:
TLI Sample ID-
Date Received:
Date Prepared:
Date Analyzed:
Matrix:
O-M29-FB .FHACE JHAR.2-FILTER 8/27/97 FH
184-84-5ABC FH
September 26. 1997
October 14-16. 1997
October 20. 1997
Air
^Analvte
Aa
As
Ba
Be
Cd
Co
Cr
Cu
Mn
Ni
P
Pb
Sb
Se
Tl
Zn
- Oona i
too« i
1.546
3.166
124.105
0.620
-4.483
-31 .070
106.758
46.528
377.059
48.807
289.196
-7.469
47.662
41.838
-0.600
101.157
rot
TotalVof,
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
8t
Used
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
0*.
FthalVof.
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
Dilution
Factor
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
Total uq
Result
0.155
< 0.500
12.4
< 0.100
< 0.100
< 0.100
10.7
4.65
37.7
4.88
28.9
< 0.200
4.77
4.18
< 0.200
10.1
Triangle Laboratories, Inc.
801 Capitola Drive * Durham, North Carolina 27713
Tele: (919) 544-5729 * Fax: (919) 544-5491
Printed: Ol-Nov-97 at 04:24 PM
25
-------
Client: Pacific Environmental Services
Project Number: 43411
Sample Report
Client Sample ID:
TLI Sample ID:
Date Received'
Date Prepared:
Date Analvzed'
Matrix:
O-M29-FB-FHAR.HNO3 BH
184-84-5BD BH
September 26. 1997
October 14-16. 1997
October 20. 1997
Air
Analyte i
Aa
As
Ba
Be
Cd
Co
Cr
Cu
Mn
Ni
P
Pb
Sb
Se
Tl
Zn
Cona
fool*
2.048
-2.730
0.709
-0.041
0.216
-0.925
0.846
2.565
4.555
5.815
-10.251
3.934
0.598
-2.147
0.700
12.577
R*,
Total Vol
75
75
75
75
75
75
75
75
75
75
75
75
75
75
75
75
n»L
Used
75
75
75
75
75
75
75
75
75
75
75
75
75
75
75
75
: J*C
RnalVoi.
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
DSutton
Factor
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
Totefug !
Result i
0.205
< 0.500
< 0.200
< 0.100
< 0.100
< 0.100
< 0.200
0.256
0.456
0.582
< 3.00
0.393
< 0.400
< 0.300
< 0.200
1.26
Triangle Laboratories, Inc.
801 Capitola Drive * Durham, North Carolina 27713
Tele: (919) 544-5729 * Fax: (919) 544-5491
Printed: Ol-Nov-97 at 03:09 PM
26
-------
Client: Pacific Environmental Services
Project Number: 43411
Sample Report
Client Sample ED:
TLI Sample ID:
Date Received:
Date Prepared:
Date Analvzed:
Matrix:
I-M29-2-FHACE.FHAR JTLTER FH
184-84-6ABC FH
September 26. 1997
October 14-16, 1997
October 20. 1997
Air
Analvte ;
Aa
As
Ba
Be
Cd
Co
Cr
Cu
Mn
Ni
P
Pb
Sb
Se
Tl
Zn
Oona
fcote
10.016
38.155
9226.019
-18.610
142.849
550.989
872.942
6548.149
23324.377
555.005
38028.563
779.071
-25.276
-179.306
85.800
6658.945
mL
TotafVol
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
al
Used
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
mt
FinalVot
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
.. Dilution;
Factor
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
Total us
Result
1.00
3.82
923
< 0.100
14.3
55.1
87.3
655
2330
55.5
3800
77.9
< 0.400
< 0.300
8.58
666
Triangle Laboratories, Inc.
801 Capitola Drive * Durham, North Carolina 27713
Tele: (919) 544-5729 * Fax: (919) 544-5491
Printed: Ol-Nov-97 at 03:09 PM
27
-------
Client: Pacific Environmental Services
Project Number: 43411
Sample Report
Client Sample ID:
TLI Sample ID:
Date Received:
Date Prepared:
Date Analvzed:
Matrix:
I-M29-2-HNO3 BH
184-84-6DBH
September 26. 1997
October 14-16. 1997
October 20. 1997
Air
Anslvte
Ad
As
Ba
Be
Cd
Co
Cr
Cu
Mn
Ni
P
Pb
Sb
Se
Tl
Zn
Cona
Cuo/L}
0.446
-1.309
11.693
-0.062
3.081
0.488
9.077
48.382
52.124
26.162
667.446
46.649
-0.448
3.567
-0.200
150.872
. ML
Total VoL
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
rtL
Used
900
900
900
900
900
900
900
900
900
900
900
900
900
900
900
900
R*.
RnalVoi.
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
DSufor*
Factor
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
Totefus i
Result
< 0.111
< 0.556
1.30
< 0.111
0.342
< 0.111
1.01
5.38
5.79
2.91
74.2
5.18
< 0.444
0.396
< 0.222
16.8
Triangle Laboratories, Inc.
801 Capitola Drive * Durham, North Carolina 27713
Tele: (919) 544-5729 * Fax: (919) 544-5491
Printed: Ol-Nov-97 at 03:09 PM
28
-------
Client: Pacific Environmental Services
Project Number: 43411
Sample Report
Client Sample ID:
TLI Sample ID:
Date Received:
Date Prepared:
Date Analyzed :
Matrix:
I-M29-3-FHACE.FHAR.FILTER JH CATCH FH
184-84-7 ABCD FH
September 26. 1997
October 14-16, 1997
October 20. 1997
Air
Analvte :
Aa
As
Ba
Be
Cd
Co
Cr
Cu
Mn
Ni
P
Pb
Sb
Se
Tl
Zn
Oona
4wU
6.711
49.132
7308.835
-11.747
94.863
454.762
756.238
6031 .224
22375.820
463.733
48808.512
778.832
-1.819
-92.400
20.800
5198.991
mt
Total Vol.
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
'ml
Used
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
mt
FtnalVol
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
Ditutior*.
Factor
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
Total us
Result
0.671
4.91
731
< 0.100
9.49
45.5
75.6
603
2240
46.4
4880
77.9
< 0.400
< 0.300
2.08
520
Triangle Laboratories, Inc.
801 Capitola Drive * Durham, North Carolina 27713
Tele: (919) 544-5729 * Fax: (919) 544-5491
Printed: Ol-Nov-97 at 03:09 PM
29
-------
Client: Pacific Environmental Services
Project Number: 43411
Sample Report
Client Sample ID:
TLI Sample ID:
Date Received:
Date Prepared:
Date Analvzed'
Matrix:
I-M29-3-HNO3 BH
184-84-7EFBH
September 26. 1997
October 14-16. 1997
October 20. 1997
Air
Analvte
Aa
As
Ba
Be
Cd
Co
Cr
Cu
Mn
Ni
P
Pb
Sb
Se
Tl
Zn
Cona
(tictfU
-0.107
-3.043
28.773
-0.035
2.943
0.034
11.196
38.729
95.115
35.373
1181.695
43.604
-0.121
0.198
0.000
298.429
fit.
. TotafVol
1100
1100
1100
1100
1100
1100
1100
1100
1100
1100
1100
1100
1100
1100
1100
1100
ni.
Used
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
f£
RnstVdL
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
Diu6on.
Factor
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
Totefug \
Result
< 0.110
< 0.550
3.17
< 0.110
0.324
< 0.110
1.23
4.26
10.5
3.89
130
4.80
< 0.440
< 0.330
< 0.220
32.8
Triangle Laboratories, Inc.
801 Capitola Drive * Durham, North Carolina 27713
Tele: (919) 544-5729 * Fax: (919) 544-5491
Printed: Ol-Nov-97 at 03:09 PM
30
-------
Client: Pacific Environmental Services
Project Number: 43411
QA: Serial Dilution
Client Sample ID:
TLI Sample ID:
Date Prepared:
Date Analyzed:
Matrix:
O-M29-1-FHACE,FHAR.FILTER FH
184-84-1ABC FH
October 14-16. 1997
October 20, 1997
Air
O-M29-1-FHACE.FHARJTLTER FH L
184-84-1 ABC FHL
October 14-16. 1997
October 20, 1997
Air
1 ' ;
Anahrte
Aq
As
Ba
Be
Cd
Co
Cr
Cu
Mn
Ni
P
Pb
Sb
Se
Tl
Zn
Native Sample
T<3ta|«9
Result
0.241
< 0.500
54.0
< 0.100
< 0.100
< 0.100
12.6
7.13
67.7
5.91
50.6
3.07
3.84
4.67
< 0.200
214
ugl
Cone.
2.411
-0.017
539.788
-0.158
-3.194
-32.448
125.993
71.253
677.158
59.056
505.792
30.749
38.440
46.739
1.600
214.073
Serial Dilution
Tobl«9 ' % ' :
Result
< 0.500
< 2.50
55.9
< 0.500
< 0.500
< 0.500
163
7.10
72.1
6.66
55.1
3.80
5.76
5.44
< 1.00
234
«#• i
Cone... ..
0.821
2.538
111.725
0.010
-0.554
-6.660
32.500
14.199
144.188
13.322
110.290
7.605
11.527
10.881
-0.400
46879
ffff
m*-
-------
Client: Pacific Environmental Services
Project Number: 43411
QA: Serial Dilution
Client Sample ID:
TLI Sample ID'
Date Prepared:
Date Analyzed:
Matrix:
O-M29-1-HNO3 BH
184-84-1DEBH
October 14-16. 1997
October 20. 1997
Air
O-M29-1-HNO3BHT.
184-84-1DE BH L
October 14-16. 1997
October 20. 1997
Air
AnaMe
Aq
As
Ba
Be
Cd
Co
Cr
Cu
Mn
Ni
P
Pb
Sb
Se
Tl
Zn
Native Sample
Total ug
Result
0.137
< 0.527
0.901
< 0.105
0.479
< 0.105
0.609
2.16
2.34
3.46
59.3
5.47
< 0.422
0.962
< 0.211
22.9
ygl
Cone.
1.302
-2.625
8.541
-0.012
4.544
-0.340
5.779
20.497
22.235
32.856
562.480
51.852
1411
9.124
0.200
217.420
Serial Dilution
Toted &g
Resut
< 0.527
< 2.64
< 1.05
< 0.527
< 0.527
< 0.527
< 1.05
1.66
1.95
2.85
57.2
5.96
< 2.11
< 1 58
< 105
234
<#t i
Cone* \
0.153
-2.144
1.564
-0.016
0.940
-0.489
1.401
3.143
3.694
5.411
108.558
11.312
0320
0079
0500
44.302
RPD
-------
Client: Pacific Environmental Services
Project Number; 43411
QA: Duplicate
Client Sample ID-
TLI Sample ID:
Date Prepared:
Date Analyzed:
Matrix:
O-M29-2-FHACE.FHAR.FILTER FH
184-84-2ABC FH
October 14-16. 1997
October 20. 1997
Air
O-M29-2-FHACRFHAR.FILTER FH DA
184-84-2ABCFHDA
October 14-16. 1997
October 20. 1997
Air
Analyte
Aa
As
Ba
Be
Cd
Co
Cr
Cu
Mn
Ni
P
Pb
Sb
Se
Tl
Zn
Sample
Total a
-------
Client: Pacific Environmental Services
Project Number: 43411
QA: Duplicate
Client Sample ID:
TLI Sample ID:
Date Prepared:
Date Analyzed:
Matrix:
O-M29-2-HNO3 BH
184-84-2DE BH
October 14-16. 1997
October 20. 1997
Air
0-M29-2-HNO3BHDA
184-84-2DEBHDA
October 14-16. 1997
October 20. 1997
Air
Anatvte
Aq
As
Ba
Be
Cd
Co
Cr
Cu
Mn
Ni
P
Pb
Sb
Se
Tl
Zn
Sample
" Totelug i
•' Result i
< 0.106
< 0.528
0.748
< 0.106
0.203
< 0.106
0.594
1.45
11.7
1.52
69.7
3.02
< 0.422
0.683
< 0.211
7.75
wg/L,
Cone*'
0.635
-3.373
7.088
-0.003
1.921
-0.164
5.627
13.779
110.581
14.447
660.558
28.585
0.257
6.474
0.800
73.430
Duplicate
', Ttfteiagi - -.
Resuft
< 0.106
< 0.528
0.722
< 0.106
0.18
< 0.106
0.443
1.29
11.6
1.44
68.7
3.02
< 0.422
0.743
N/A
757
I*. i
Core.
-1.000
-2.338
6.838
-0.058
1.709
-1.009
4.196
12.233
109.478
13.690
650.906
28.606
-5.254
7.037
N/A
71 752
BPfc
-------
Client: Pacific Environmental Services
Project Number: 43411
QA: Matrix Spikes (Post-Digestion)
Client Sample ID:
TLI Sample ID-
Date Prepared:
Date Analyzed:
Matrix'
O-M29-1-FHACE.FHAR.RL7ER FH PDS
184-84-1 ABC FHPDS
October 14-16, 1997
October 20. 1997
Air
Anaivte
Aq
As
Ba
Be
Cd
Co
Cr
Cu
Mn
Ni
P
Pb
Sb
Se
Tl
Zn
Post-Die
f:teewer«t
Amount {tiflfl-V
42.33
47.28
575.52
44.63
43.53
17.32
172.26
118.97
709.59
105.88
1391.02
75.53
95.35
85.76
20.40
397.21
estton Spike
Spjke -
Amount fooft-V
50
50
50
50
50
50
50
50
50
50
1000
50
50
50
25
200
- %
Recovery
80°/<
95°/c
Spike Low
89°/<
87°/<
35°/<
93°/c
95°/c
Spike Low
94°/<
89°/<
90°/<
114°/<
78°/<
82°/<
92°/
-------
Client: Pacific Environmental Services
Project Number: 43411
QA: Matrix Spikes (Post-Digestion)
Client Sample ID:
Tl.T Sample TD:
Date Preoared:
Date Analyzed:
Matrix:
O-M29-1-HN03BHPDS
184-84-1DEBHPDS
October 14-16. 1997
October 20. 1997
Air
.Analyie,,,
Aa
As
Ba
Be
Cd
Co
Cr
Cu
Mn
Ni
P
Pb
Sb
Se
Tl
Zn
Post-Die
BBttffBmt
Amount ftjoO
42.65
42.89
58.97
46.31
51.82
47.41
52.63
68.63
63.17
79.71
1419.02
96.36
45.56
50.52
21.90
389.40
estton Spike
Sp»K*
Amount fuafLV "
50
50
50
50
50
50
50
50
50
50
1000
50
50
50
25
200
• * %,
Reeoverv
83°/<
86°/<
101°X
93°/<
95°/<
95°/<
947«
96°/<
82°X
94°X
8&K
89°/<
91 "A
83°/
88°/<
86°/
Post-Digestion Spike Duplicate
Repftgrad i
£nx»MftjaO;
^ Sp&e •
,Amo«Tt&ra&3
* -*
Recovery
V
' ;tm
*. .jA,
Igft-t f
»*—
»-
...
...
...
...
—
...
...
...
...
...
...
— —
...
...
...
.«
...
...
...
..
Triangle Laboratories, Inc.
801 Capitola Drive * Durham, NC 27713
Tele: (919) 544-5729 * Fax: (919) 544-5491
Printed: Ol-Nov-97
at
04:24 PM
36
-------
Client: Pacific Environmental Services
Project Number: 43411
QA: Method Blank
TLI Sample ID:
Date Prepared'
Date Analyzed:
Matrix:
4141 1 MB
October 14-16. 1997
October 20. 1997
N/A
' AnaMe
Aa
As
Ba
Be
Cd
Co
Cr
Cu
Mn
Ni
P
Pb
Sb
Se
Tl
Zn
Method Blank
Recovered
Amount fad/O
-0.31
-0.83
0.08
-0.01
0.03
-0.32
0.26
0.73
0.39
10.14
-5.19
0.71
-0.06
0.50
-1.30
2.79
Detection
UmiUuo/l}
1
5
2
1
1
1
2
2
2
3
30
2
4
3
2
12
—
—
—
—
—
—
—
—
—
—
—
—
—
—
...
Pass or
Fail
Pass
Pass
Pass
Pass
Pass
Pass
Pass
Pass
Pass
Fail
Pass
Pass
Pass
Pass
Pass
Pass
...
...
—
...
...
...
...
—
—
...
—
—
—
—
Triangle Laboratories, Inc.
801 Capitola Drive * Durham, NC 27713
Tele: (919) 544-5729 * Fax: (919) 544-5491
Printed: Ol-Nov-97
at
03:11 PM
37
-------
Client: Pacific Environmental Services
Project Number: 43411
QA: Lab Control Spikes
TLT Sample TD:
Date Prepared:
Date Analyzed:
Matrix:
43411 LCS
October 14-16.1997
October 20. 1997
N/A
Analvte
Ag
As
Ba
Be
Cd
Co
Cr
Cu
Mn
Ni
P
Pb
Sb
Se
Tl
Zn
Lab Control Spike
iteo^K**
Amount &ofl_>
42.95
44.95
46.80
45.78
46.59
46.65
47.19
47.89
47.50
65.43
908.82
45.94
46.51
46.39
36.40
194.41
Spite --;
Amount luafti '.''...
50
50
50
50
50
50
50
50
50
50
1000
50
50
50
50
200
}*&%,,
Recover*
86°X
90°/<
94°/<
92°/<
93°/<
93°/<
94°/<
96°/<
957<
131°/<
91°/<
927<
93°/<
93°/<
73°/<
97°/<
Lab Control Spike Duplicate
BecQvered ;
Amount t uq/L\:
$&»^ f,
Anxjont CuoA.^
%--,
Recovery
TO
._
...
—
...
—
...
—
...
...
».
_„
...
...
...
...
...
—
...
...
—
—
—
...
...
—
Triangle Laboratories, Inc.
801 Capitola Drive * Durham, NC 27713
Tele: (919) 544-5729 * Fax: (919) 544-5491
Printed: Ol-Nov-97
at
03:11 PM
38
-------
Client: Pacific Environmental Services
Project Number: 43377
Sample Report
Client Sample ED:
TLI Samole ID:
Date Received'
Date Preoared:
Date Analyzed:
Matrix:
O-M29-RB-FHACEJ3HARJTLTER FH
184-50-6ABC FH
September 24 1997
October 10-14. 1997
October 16.20 21 & 22. 1997
Air
•, •»*• •"
; 'A ..A-^A
: Analyte^ *
Aa
As
Ba
Be
Cd
Co
Cr
Cu
Mn
Ni
P
Pb
Sb
Se
•n
Zn
2.705
3.407
43292
-0.112
•6.215
-29.571
93294
10.580
9.109
46.803
17.600
-12.883
41.765
43.531
-3.00
25.989
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
jv; -«(.»,!
; ~ Utodk* ;
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
'c"*«iL* J
Final Vdb \
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
iPlfe
5Sij&j/f?f v' ^v*
^j\ ^ToSSKftv **
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
0270
< 0.500
4.33
< 0.100
< 0.100
< 0.100
9.33
1.06
0.911
4.68
< 3.00
< OJ200
4.18
4.35
< 0.200
2.60
Triangle Laboratories, Inc.
801 Capitola Drive * Durbam, North Carolina 27713
Tele: (919) 544-5729 * Fax: (919) 544-5491
Printed: 03-Nov-97 at 01:08 PM
-------
Client: Pacific Environmental Services
Project Number; 43377
Sample Report
Client Sample ID:
TLI Samole ID:
Date Received'
Date Preoafed:
Date Analyzed'
Matrix:
O-M29-RB-HN03 BH
184-50-6BDBH
September 24. 1997
October 10-14. 1997
October 16.20.21 & 22, 1997
Air
Analvte ^ !
Aa
As
Ba
Be
Cd
Co
Cr
Cu
Mn
Ni
P
Pb
Sb
Se
Tl
Zn
P*N1
0.061
-8.994
3.256
-0.044
-0.536
-1.619
£217
14.381
346.891
6.056
553.359
2647
1.642
•0.017
-1.50
20.330
%&- ISL JL \
i¥
-------
lient:
•oiect Number:
Pacific Environmental Services
43411
ample Report
Page 1 of 4
te Received:
te Prepared :
te Analv7ed"
,TA FILE:
trix:
Ser»ember 26. 1997
October 14-20. 1997
October 20-22. 1997
AB826 AB827&AB828
Air
ANALYT& Ho
uo/LRDL: O.2
Analvsis Method*
29
Instrument P E Teaman 5100
Soike Cone. (uq/U 5
CVAA ANALYTE SUMMARY REPORT
H-ffSarnoteKi' •• ' ;
M29-1-FHACE,FHAR,FILTER FH
M29-1-FHACE,FHAR,FILTER FH D
M29-1-HNO3BH
M29-1-HNO3BHD
M29-1-BHARHNO3
M29-1-BHARHN03D
M29-1-KMnO4
M29-1-KMnO4D
M29-1-HCI
M29-1-HCID
M29-2-FHACE,FHAR,FILTER FH
M29-2-FHACE,FHAR,FILTER FH D
V129-2-HNO3BH
VI29-2-HN03 BH D
VI29-2-BHAR HNO3
V129-2-BHAR HNO3 D
v129-2-KMnO4
v129-2-KMn04 D
d29-2-HCI
^29-2-HCI D
d29-3-FHACE,FHAR,FILTER FH
J29-3-FHACE,FHAR,FILTER FH D
JI29-3-HNO3 BH
/I29-3-HNO3 BH D
/129-3-BHAR HNO3
/129^-BHAR HNO3 D
d29-3-KMnO4
te9-3-KMnO4 D
129-3-HCI
129-3-HCI D
TUSAMPID
184-84-1ABC
184-84-1 ABC D
1 84-84-1 DE
1 84-84-1 DED
1 84-84-1 F
t84-84-lFD
1 84-84-1 G
1 84-84-1 G D
1 84-84-1 H
1 84-84-1 HD
184-84-2ABC
184-84-2ABCD
184-84-2DE
184-84-2DED
184-84-2F
184-84-2FD
184-84-2G
184-84-2GD
184-84-2H
184-84-2HD
184-84-3ABC
184-84-3ABCD
184-84-3DE
184-84-3DED
184-84-3F
184-84-3FD
184-84-3G
184-84-3G D
184-84-3H
184-84-3H D
UOtXi
CONG-'
0.022
0.006
0.016
0.020
0.019
0.012
0.070
0.072
0.011
0.002
0.006
-0.002
0.019
0.019
0.000
0.000
0.033
0.093
0.019
0.014
0.009
0.008
0.025
0.014
0.012
0.006
0.107
0.106
0.016
0.019
-M
IV
N/A
N/A
1940
1940
110
110
450
450
89
89
N/A
N/A
1910
1910
90
90
455
455
46
46
N/A
N/A
1530
1530
85
85
265
265
50
50
rat
FV-
100
100
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
100
100
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
100
100
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
mi
Afiquol
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
OIL
FACTQF
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
Totatuo
RESUL1
< 0.400
< 0.400
< 7.76
< 7.76
< 0.440
< 0.440
< 1.80
< 1.80
< 0.356
< 0.356
< 0.400
< 0.400
< 7.64
< 7.64
< 0.360
< 0.360
< 1.82
< 1.82
< 0.184
< 0.184
< 0.400
< 0.400
< 6.12
< 6.12
< 0.340
< 0.340
< 1.06
< 1.06
< 0.200
< 0200
,'•: -vAYCt ssj
- *FE5ULTi
< 0.400
< 7.76
< 0.440
< 1.80
< 0.356
< 0.400
< 7.64
< 0.360
< 1.82
< 0.184
< 0.400
< 6.12
< 0.340
< 1.06
< 0.200
"8 v..
"BPD.
-
_
—
_
-
-
_
-
-
_
-
-
-
-
-
*&iic:
_
_
_
_
_
-
_
— .
-
-
_
-
-
39
-------
Client: Pacific Environmental Services
Project Number: 43411
Sample Report
Date Received:
Date Prepared :
Date Analyzed:
DATA FILE:
Matrix:
September 26. 1997
October 14-20. 1997
October 20-22. 1997
AB826, AB827 & AB828
Air
Page 2 of 4
ANALYTE: Ha
ua/L RDL 0.2
AnSlVSJS Method1 29
Instrument P E Zeeman 5100
SoikeConc (uo/U S
-
CVAA ANALYTE SUMMARY REPORT
I-M29-1-FHACE,FHAR,FILTER FH
I-M29-1-FHACE,FHAR,FILTER FH D
I-M29-1-HNO3 BH
rl-M29-1-HNO3BHD
l-M29-1-KMnO4
l-M29-1-KMnO4D
I-M29-1-HCI
I-M29-1-HCID
O-M29-FB-FHACE,FHAR,2-FILTER 8/27/97 FH
O-M29-FB-FHACE.FHAR.2-FILTER 8/27/97 FH D
0-M29-FB-FHAR.HNO3 BH
O-M29-FB-FHAR.HNO3 BH D
O-M29-FB-BHAR HNO3
O-M29-FB-BHAR HNO3 D
O-M29-FB-KMnO4
O-M29-FB-KMn04 D
O-M29-FB-HCI
O-M29-FB-HCI D
l-M29-2-FHACE,FHAR,FILTER FH
l-M29-2-FHACE,FHAR,FILTER FH D
I-M29-2-HNO3 BH
I-M29-2-HNO3 BH D
I-M29-2-BHAR HNO3
I-M29-2-BHAR HNO3 D
l-M29-2-KMnO4
l-M29-2-KMnO4 D
I-M29-2-HCI
I-M29-2-HCI D
ti.SAMttO^ ^
184-84-4ABC
184-84-4ABC D
184-84-4D
184-84-4DD
184-84-4E
184-84^E D
184-84-4F
184-64-4FD
184-84-5ABC
184-84-5 ABC D
184-84-5BD
184-84-5BDD
184-84-5E
184-84-5E D
184-84-5F
184-84-5FD
184-84-5GF
184-84-5GFD
184-84-6ABC
184-84-6 ABC D
184-84-6D
184-84-6D D
184-84-6G
184-84-6G.P.', '. .
184-84-6E
184-84-6ED
184-84-6F*... -.- •- v
184-84-6FO'
ffffe
0.059
0.062
0.026
0X116
0.081
0.048
0.011
0.012
0.005
0.002
0.050
0.033
a041
0.036
0.030
0.025
O044
O041
0X81
0X178
0.044
0.039
O034
•aoaa
ai38
0.127
•0.003
0,003
W
N/A
N/A
750
750
33S
335
49
49
WA
N/A
*7S
* 75
75
75
400
400
SO
50
N/A
MM
1000
1000
75
75
300
300
63
63
**$
100
100
N/A
N/A
MM
N/A
N/A
N/A
TOO
too
N/A
N/A
N/A
N/A
N/A
N/A
NCA
N/A
100
100
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
* *!*"
5
5
5
5
5
5
5
5
5
5
5
S
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
DJL
1
1
1
1 "
1
1
1
1
1
1
1
1
1
1
1 ,
1
1
1
1
1
1
1
1
1
1
1
1
1
>, TateftM
< 0.400
< 0.400
< 3.00
< 3.00
< 1.34
< 1.34
< 0.196
< 0.196
< 0*400
< O400
< O300
< 0.300
< 0.300
< 0.300
< 1.60
< 1.60
< 0200
< 0200
< 0.400
< 0,400
•-• " 4.00
< 4.00
< 0.300
< 0.300
< 120
< 120
< 0.252
< 0252
,-."- Ava ¥«*
< 0.400
_
< 3.00
< 1.34
< 0.196
< 0.400
< 0300
< 0.300
< 1.60
< 0200
_
< 0,400
< 4.00
< Ob300
< 120
< 0252
-
-
-
-
-
-
-
-
-
_
-
-
-
-
-
-
-
-
-
-
-
•-
-
-
-
-
-
-
-
40
-------
lent:
oiect Number;
Pacific Environmental Services
43411
ample Report
Page 3 of 4
: Received:
s Preoared:
' Analyzed:
FA FILE:
nx:
September 26. 1997
October 14-20. 1997
October 20-22. 1997
AB826, AB827 A AB828
Air
ANALYTE: Ha
ua/L RDL 02
Analysis Method:
29
Instrument P E Zeeman 5100
Soike Cone. (ua/L)
5
CVAA ANALYTE SUMMARY REPORT
* " " - ,l
•rtSaitttetD '" - ]
29-3-FHACE,FHAR,FILTER,FH CATCH FH
29-3-FHACE,FHAR,FILTER,FH CATCH FH D
29-3-HNO3 BH
29-3-HNO3 BH D
29-3-BHAR HNO3
29-3-BHAR HNO3 D
29-3-KMnO4
29-3-KMnO4 D
29-3-HCI
29-3-HCI D
129-1 -HNO3BH MS
129-1 -HNO3BHMSD
129-2-HNO3 BH MS
129-2-HNO3 BH MSD
29-1-HNO3BHMS
S-1-HNO3BHMSD
I29-FB-FHAR.HNO3 BH MS
I29-FB-FHAR,HNO3 BH MSD
S-2-HNO3 BH MS
I9-2-HNO3 BH MSD
9-3-HNO3 BH MS
I9-3-HNO3 BH MSD
29-1-HNO3BHMS
29-1 -HNO3BH MSD
29-2-HNO3 BH MS
29-2-HNO3 BH MSD
9-1-HNO3BHMS
9-1-HNO3BHMSD
29-FB-FHAR,HNO3 BH MS
»-FB-FHAR,HN03 BH MSD
3-2-HNO3 BH MS
9-2-HNO3 BH MSD
"•;
TtlSAl«PlD
84-64-7ABCD
84-84-7ABCD D
184-84-7EF
184-84-7EFD
184-84-7G
184-64-7GD
184-84-7H
184-84-7H D
184-84-7H
184-64-7H D
184-84-1 DEMS
1 84-84-1 DE MSD
184-84-2DEMS
184-84-2DE MSD
184-84-4DMS
184-84-4DMSD
184-64-5BDMS
184-84-5BDMSD
184-84-60 MS
184-84-6DMSD
184-84-7EFMS
184-84-7EFMSD
True Spike MS
True Spike MSD
True Spike MS
True Spike MSD
Tiue Spike MS
True Spike MSD
True Spike MS
True Spike MSD
True Spike MS
True Spike MSD
uatL
OJNfc
0.031
0.018
0.044
0.036
0.000
•0.018
0.148
0.112
0.148
0.112
2.521
2.532
£922
2.720
2.599
£631
4.926
5.092
8.142
7.947
8.442
8.587
5
5
5
5
5
5
5
5
5
c
ml
TV
N/A
N/A
1100
1100
105
105
235
235
100
100
1940
1940
1910
1910
750
750
75
75
1000
1000
1100
1100
1940
1940
1910
1910
750
750
75
75
1000
1000
8*
fV
100
100
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
^wt .
A&ttJdf
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
m< ,
ftWSSK*
1
1
1
1 -
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
Totelw
'ftS&JLt
< 0.400
< 0.400
< 4.40
< 4.40
< 0.420
< 0.420
< 0.940
< 0.940
< 0.400
< 0.400
98
98
112
104
39.0
39.5
7.39
7.64
163
159
186
189
194
194
191
191
75.0
75.0
7.50
7.50
100
100
"" y" ASHXV'"-
-aestiLf
_
< 0.400
_
< 4.40
_
< 0.420
_
< 0.940
_
< 0.400
98
__
1O8
_
39.2
_
7.51
_
161
_
187
_
-
_
-
__
-
^
-
_
—
,-W-V
RPDf
_
-
__
-
_
-
—
-
_
—
0.44%
—
7.16%
_
122%
_
3.31%
_
2.42%
„,
1.70%
__
-
_
-
_
-
_
-
_
-
^V^ < *,' :
^66
_
-
_
-
._
-
*.
-
__
—
50%
51%
58%
54%
52%
53%
99%
102%
163%
159%
169%
172%
-
..
-
-
-
—
41
-------
Client:
Project Number:
Pacific Environmental Services
43411
Sample Report
Page 4 o«4
Date Received:
Date Prepared:
Date Analv7edi
DATA FILE:
Matrix:
.September 26 1997
October 14-20. 1997
October 20- 22 1997
AB826. AB827 & AB828
Air
ANALYTF- Ho
uo/L RDL: 0.2
Analuaig Method-
Instrument P E Zeeman 5100
Soite Cone. kio/L\ 5
CVAA ANALYTE SUMMARY REPORT
CSentSartpteJOt :
I-M29-3-HNO3 BH MS
I-M29-3-HNO3 BH MSD
Method Blank
Method Blank D
LCS
LCSD
Method Blank
Method Blank D
LCS
LCSD
Method Blank
Method Blank D
LCS
LCSD
TLfSAMPID
True Spike MS
True Spike MSD
43411 MB1
43411 MB01
43411 LCS1
43411 LCS1D
4341 1MB2
4341 1 MBD2
43411 LCS2
43411 LCS2D
4341 1 MB3
43411 MBD3
43411LCS3
43411 LCS3D
*©t-
CONC;
5
5
0.006
OOQB
5.006
4.900
0.005
-Q.01O
5.325
&473
0.036
0.022
5.001
4.846
-Irt
W
1100
1100
—
-
—
—
-
-
nrt
FV
N/A
N/A
-
-
_
_
^ »
-
ml
5
5
;
-
_
-
_
-
, OIL
FACTOT
1
1
-
-
„
_
j_
- -
,;::Ta*atutt
^S0L!
110
110
-
-
_
-
-
-
Avet,:
RESULT:
-
-
-
_
«•
- :
-
&F®
-
_
:
,
-
-
i4Rga1
-
100%
98%
-
107%
109%
-
100%
97%
Triangle Laboratories, Inc.
801 Capitola Drive * Durham, North Carolina 27713
Tele: (919) 544-5729 * Fax: (919) 544-5491
Printed: 01-No*07
0320PM
r»
-------
O PACIFIC ENVIRONMENTAL SERVICES. INC.
\ff wuu i wuuin iviianii uuuicvcinj, r.^J. DOX
Research Triangle Park, North Carolina 27709-2077'
(919) 941-0333 FAX: (919) 941-0234
Chain of Custody Record
Project Num
s4 13-004
Project Name AO*HH -RA*ST"R''
US EPA EMC Asphalt Cement,
Samplers:
Dickerson, McDonald, Thompson, Dougherty, Hamilton
Date
8/27/97
8/27/97
8/27/97
8/27/97
8/27/97
8/27/97
8/27/97
8/27/97
8/28/97
8/28/97
8/28/97
8/28/97
8/28/97
8/28/97
8/28/97
8/28/97
8/29/97
8/29/97
8/29/97
8/29/97
8/29/97
8/29/97
8/29/97
8/29/97
8/27/97
i
Time
1600
1600
1600
1600
1600
1600
1600
1600
1300
1300
1300
1300
1300
1300
1300
1300
1315
1315
1315
131(5
13,15
13^5
131.5
1315
1300
Field Sample ID
O-M29-1-FHACE
O-M29-1-FHAR
O-M29-1 -Filter
O-M29-1-HNO3
O-M29-1-HNO4
O-M29-1-BHAR
O-M29-1-KMnO4
O-M29-1-HCI
O-M29-2-FHACE
O-M29-2-FHAR
O-M29-2-Filter
O-M29-2-HNO3
O-M29-2-HNO3
O-M29-2-BHAR
O-M29-2-KMnO4
O-M29-2-HCI
O-M29-3-FHACE
O-M29-3-FHAR
O-M29-3-Filter
O-M29-3-HNO3
O-M29-3-HNO3
O-M29-3-BHAR
O-M29-3-KMnO4
O-M29-3-HCI
-M29-1-FHACE
Sample Description
FH Acetone Rinse - Beaker No. M-22
FH0.1 NHNO3 Rinse
Filter M97-013 - Beaker No. M-23
5% HNO3 / 10% H2O2 Absorbing Solution
5% HNO3 / 10% H2O2 Absorbing Solution
BH 0.1 N HN03 Rinse
10.% H2SO4 / 4% KMnO4 Absorbing Sol.
8N HCI Rinse
FH Acetone Rinse - Beaker No. M-24
FH0.1 NHNO3 Rinse
Filter M97-0 19
5% HNO3 / 10% H2O2 Absorbing Solution
5% HNO3 / 10% H2O2 Absorbing Solution
BH0.1 NHNO3 Rinse
10% H2SO4 /4% KMnO4 Absorbing Sol.
8N HCI Rinse
FH Acetone Rinse - Beaker No. W-10
FH0.1 NHNO3 Rinse
Filter M97-004 - Beaker No. W-1 1
5% HNO3 / 10% H2O2 Absorbing Solution
5% HNO3 / 10% H2O2 Absorbing Solution
BH0.1 NHN03 Rinse
10% H2S04 / 4% KMnO4 Absorbing Sol.
8N HCI Rinse
FH Acetone Rinse - Beaker No. M-12
Analysis Requested
MM
•
.
•
.
*
.
.
•
*
•
.
.
*
.
.
.
.
•
•
Hg
•
.
.
.
.
.
.
.
.
.
.
.
.
.
.
. .
.
.
.
t
.
.
.
.
•
i
Remarks
Bottle 1/2
Bottle 2/2
Petri Disk
Bottle 1/2
Bottle 2/2
Bottle 1/2
Bottle 2/2 '
Page 1 of 3
-------
O PACIFIC ENVIRONMENTAL SERVICES. INC.
Central Park West
5001 South Miami Boulevard, P.O. Box 12077.
Research Triangle Park, North Carolina 27709-2077
(919) 941-0333 FAX: (919) 941-0234
Chain of Custody Record
*
a
S413-004
Project Name jo****- Xstrtr^
US EPA EMC Asphalt Cement, *
Samplers: ,
Dickerson, McDonald, Thompson. Dougherty, Hamilton
Date
8/27/97
8/27/97
8/27/97
. 8/27/97
8/27/97
8/27/97
8/27/97
8/27/97
8/27/97
8/27/97
8/27/97
8/27/97
8/28/97
8/28/97
8/28/97
8/28/97
8/28/97
8/28/97
8/29/97
8/29/97
8/29/97
8/29/97
8/29/97
8/29/97
' 8/29/97
Time
1300
1300
1300
1300
1300
0900
0900
0900
0900
0900
Q900
0900
1500
1500
15.PO
1500
1500
1500
1530
153
153
153
0
0
F
1536
1530
1530
Field Sample ID
-M29-1-FHAR
-M29-1 -Filter
I-M29-1-HNO3
l-M29-1-KMnO4
I-M29-1-HCP
O-M29-FB-FHACE
O-M29-FB-FHAR
O-M29-FB-Filter
O-M29-FB-HNO3
O-M29-FB-BHAR
O-M29-FB-KMnO4
O-M29-FB-HCI
I-M29-2-FHACE
I-M29-2-FHAR
J-M29-2-Filter .
I-M29-2-HNO3
-M29-2-KMnO4
-M29-2-HCI
-M29-3-FHACE
-M29-3-FHAR
-M29-3-Filter
-M29-3-FH Catch
-M29-3-HNO3
-M29-3-HNO3
-M29-3-BHAR
Sample Description
FH0.1 NHNO3 Rinse
Beaker No. M-3
5% HNO3 / 10% H2O2 Absorbing Solution
10% H2SO4 / 4% KMnO4 Absorbing Sol.
8NHCI Rinse
FH Acetone Rinse - Beaker No. W-12
FH.0.1 N HN03 Rinse
Filter M97-0 17
5% HN03 / 10% H2O2 Absorbing Solution
BH0.1 NHN03 Rinse
10% H2SO4 / 4% KMnO4 Absorbing Sol.
8N HCI Rinse
FH Acetone Rinse - Beaker No. M-19
FH0.1 NHNO3 Rinse
Filter No. 97-016, 1002 - Beaker No. M-17
5% HNO3 / 10% H2O2 Absorbing Solution
10% H2SO4 / 4% KMnO4 Absorbing Sol.
8N HCI Solution
FH- Acetone Rinsa - Beaker No. M-21
FH0.1 NHN03 Rinse
Filter M97-0010 - Beaker No. M-20
Front Half Catch
5% HN03 / 10% H202 Absorbing Solution
5% HNO3 / 10% H2O2 Absorbing Solution
BH0.1 NHNO3 Rinse
Analysis Requested
MM
•
•
•
•
•
*
•
•
•
*
•
•
•
•
•
•
•
•
•
Hg
•
•
•
•
•
•
•
•
•
•
•
•
•
*
•
•
•
•
•
»
•
•
•
•
•
• «(
i
Remarks
•
Filters M010, 011, 012, 014, 015
Bottle 1/2
Petri Dish
Zip-lock Bag
Bottle 1/2
Bottle 2/2
-------
O PACIFIC ENVIRONMENTAL SERVICES. INC.
, r.v_i. DUX
Research Triangle Park, North Carolina 27709-2077'
(919) 941-0333 FAX: (919) 941-0234
Chain of Custody Record
Project Num
s4 13-004
Project Name fcfvr/fty 7=±&ujr „
US EPA EMC Asphalt Cement, '«fcA I .t
Samplers:
Oickerson, McDonald, Thompson, Dougherty, Hamilton
Date
8/29/97
8/29/97
•
Time
1530
1530
Field Sample ID
-M29-3-KMnO4
-M29-3-HCI
i
Relinquished by: (Signature)
A
Relinquished by: (Signature)
Ftetiqguishedytfy: (Sig/ature)
•qftuT--
, Date/Time
Date/Time
Date/Time
-------
II Custody Seal : Absent Sample Seals: Absent
|| Chain of Custody : Present Container. . . : Intact
|| Sample Tags : Absent
|| Sample Tag Numbers: Not Listed on Chain of Custody
I) SMO Forms : N/A
II
H Ice Chest/Box NO COOLANT
||TLI Number Client Sample ID Matrix
||mR/H:CPM Client COC ID * Location
TLI Project Number 43411 Book ||
Client: PES03 - Pacific Environmental Services H
184
Date Received | 09/26/97 | ^/^/Tj^tWp/ Pa9B
Carrier and Number | HAND DELIVERED 84
To LAB To STORAGE
Date/Init Date/Init
|| . — ••
||l84-84-lA 0-M29-1-FHACE FH ACE RNS|
|| 0-M29-1-FHACE METALS LAB
II
||lB4-84-lB ' O-M29-1-FHAR FH0.1NHNO3
H 0-M29-1-FHAR METALS LAB
II
H184-84-1C 0-M29-1-FILTER FILTER)
I) 0TM29-1-FILTER METALS LAB
(184-84-10" 0-M29-1-HN03 : 5% HNQ3/10% H202 1
|| ' 0-M29-'»-HNQ3 *'' METALS LAB
||184-M-1E 0-M29-1-HNOJ $tyl J* HNOJ/10* H202
j| 0-M2J-l-lpJ*^fVt^ V*41^ HBTM>S, IAB
|| • ^ — ».
H184-84-1F 0-M29-1-BHAR BM O.ltt HHO3 RNS
|| 0-M29-1-BHAR METALS LAB
|| _
1(184-84-10 0/M2S-1-KMN01 10* HI804/4VKMNO4 1
|| . 0-M29-1-KMN04 METALS LAB
|J- — — " ' "; '
JJ184-84-1H 0-M29-1-HCL 8N HC1 1
|| 0-M29-1-HCL METALS LAB '
lil84-84-2A 0-M29-2-FHACE PH ACE RNSJ .
|| O-M29-2-FHACE METALS LAB
j|_ . •
||184-S4-2B 0-M29-2-FHAR ttt 0.1N HN03 1
|| O-M29-2-FHAR METALS LAB
|il84-84-2C 0-MJ9-2-FILTER FILTERJ
|| 0-M3f-3-FILTER METALS LAB
Jl . ' " - 1
JJ184-84-2D 0-M39-2-HN03 6lHN03/10*H2O2 1
|| . 0-M29-2-HN03 METALS LAB
||!84-84-2E O-M29-2-HN03 S*HN03/10%H202 1
|| ' OJ-M29-2-HN03 METALS, LAB
, j - • • •
||l84-84-2F OJ-M29-2-BHAR BH 0.1HN03 RNS
|| Q/-M29-3-BKAR MBtALS LAB
To LAB
Date/Init
•:
'
-
,
-
To STORAGE
Date/Init
To LAB
Date/Init
1
)
1
i
| j
To STORAGE
Date/Init
1 1
1 1
1 1
To LAB
Date/Init
i 1
i 1
i 1
i 1
i 1
i 1
To STORAGE
Date/Init
1
1 1
'
1
1 1
DISPOSED
Date/Init
1
1 B
(Deceiving Remarks:-'i 1-M29-2-BHAR was not on COC but was received. Sample 0-M29-FB-FILTER is marked 0-M29-2-FILTER but
j|_ ' ' has the date B/27/97 which l» the same as the COC.
jj ' Archive Remarks : '"-
=Form Revised 05/27/1997 -- Page 1 OF 4
-------
=TRIANGLE LABORATORIES, INC. -- LOG IN RECORD/CHAIN OF CUSTODY=
|| Custody Seal : Absent Sample Seals: Absent
II Chain of Custody : Present Container...: Intact
1) Sample Tags : Absent
|| Sample Tag Numbers: Not Listed on Chain of Custody
|| SMO Forms : N/A
TLI Project Number 43411 | Book
Client: PES03 - Pacific Environmental Services |
| 184
Date Received j 09/26/97 j By ^3 ^/Jlfl tAjLjl^/^ Pa9B
SI 1 / w — - i
H Ice Chest/Box NO COOLANT Carrier and Number | HAND DELIVERED | 84
IJTLI Number Client Sample ID Matrix
||mR/H:CPM. Client COC ID. * Location. . .
1)184-84-20 0-M29-2-KMN04 10% H2S04/4 VKMN04
|| ( ' 0-M29-2-KMN04 METALS LAB
»'
H184-84-2H ' 0-M29-2-HCL 8N HCL
1) O-M29-2-HCL METALS LAB
||l84-84-3A 0-M29-3-FHACE FH ACE RNS
|| O-M29-3-FHACE METALS LAB
||184-B4-3B 0-M29-3-FHAR FH 0 . IN HN03
|j ' O-M29-3-FHAR METALS LAB
||l84-84-3C' 0-M29-3-FILTER FILTER
|| O-M29-3-FILTER METALS LAB
|)184-B4-3D 0-M29-3-HN03 5%HNQ3/10%H202
D 0-M29-3-HNO3 METALS LAB
»'
H184-84-3E OrM29-3-HN03 5%HNO3/10%H202
fl . O-M29-3-HN03 METALS LAB
D184-84-3F O-M29-3-BHAR BH 0.1N HN03
|| O-M29-3-BHAR METALS LAB '
1)184-84-30 O-M29-3-KMN04 10%H2SO4/4%KMN04
1) 0-M29-3-KMN04 METALS LAB
||l84-84-3H 0-M29-3-HCL 8N HC1
D O-M29-3-HCL METALS LAB
H '*
H184-B4-4A I-M29-1-FHACE FH ACE RMS
1) I-M29-1-FHACE METALS LAB
.
1)184-84-48 I-M29-1-FHAR FH 0.1N HN03
U . I-M29-1-FHAR METALS LAB
'
|)l84-84-4C I-M29-1-FILTER FILTER
II ' I-B29-1-FILTER METALS LAB j
II ) 1
I To LAB
Date/Init
•
II • j 1
||l84-84-4D IvM29-l-HN03 5%HN03/10*H202 1
[ I>M29-1-HN03 METALS LAB j
To STORAGE
Date/Init
I To LAB
Date/Init
To STORAGE
Date/Init
To LAB
Date/Init
1
To STORAGE
Date/Init
,
To LAB
Date/Init
-
To STORAGE
Date/Init
DISPOSED
Date/Init
1
|f"sjteceiving Remarks :•'! I-M29-2-BHAR was n>t on COC but was received. Sample 0-M29-FB-FILTER is marked 0-M29-2-FILTER but
|| 'has the date 8/27/97 which is the same as the COC.
II
H ' Archive Remarks:
.Form Revised 05/27/1997 -- Page 2 OF 4*
-------
=TRIANGLE LABORATORIES, INC. -- LOG IN RECORD/CHAIN OF CUSTODY*
jj Custody Seal : Absent Sample Seals: Absent
H Chain of Custody : Present Container...: Intact
|| Sample Tags : Absent
ij Sample Tag Numbers: Not Listed on Chain of Custody
I) SMO Forms , : N/A '
TLI Project Number 43411 Book ||
Client: PES03 - Pacific Environmental Services H
184 ||
ji /) II
1 1 J \n LLt~*~ "
Date Received | 09/26/97 | By^J^ /f, jM ./JTW^ Pa9"
II — - . i / v -
|| Ice Chest/Box NO COOLANT Carrier and Number | HAND DELIVERED 84
||TLI Number Client Sample ID. . . . j Matrix
||mR/H'CPM Client COC ID .... * Location
- "• " •
||l84-84-4E I-M29-1-KMN04 10*H2SO4/4%KMNO4
|| I-M29-1-KMN04 METALS LAB
"
||184-S4-4F I-M29-1-HCL 8N HCL
|| I-M29-1-HCL METALS LAB
||!84-84-5A O-M29-FB-FHACE FH ACE RNS
I) 0-M29-FB-FHACE METALS LAB
»•
||184-B4-5B 0-M29-F(B-FHAR "" , . JH0.1HNO3
H 0-M29-FB-FHAR >.'*' METALS*LAB
». ' ''" " ...-•.-
. ., , , i ...
||184-B4-5C 0-M29-2-FILTER 8/27/97 FILTER
|| 0-M29-FB-FILTER • METALS LAB
1 — "' "'
||l84-84-SD 1 0-M29-FB-HN03 .. 5%HNQ3/10VH202
|| O-M2S-FP-HN03 | MEtALS LAB
||l84-84-5E OWm-FB-BHAH BH 0.1N HN03
y . • 0-M29-FB-BHAR MKtALS LAB
_ , . _ . . .
||184-B4-5F 0-M29-FB-KMN04 10»HJS04/4%KMNO4
|| 0-M29-FB-KMN04 MBTALS LAB '
|| 184 -84 -SO 0-M29-FB-HCL 8N HC1
|| 0-M29-FB-HCL HBtALS LAB
||!84-84-6A I-M29-2-FHACE rH ACE RNS
U I-M29-2-FHACE METALS LAB
||184-B4-6B I-M2I-2-FHAR FH 0 . 1HN03
g I-M2»-2-FHAR MEtALS LAB
• •--
||l84-84-SC I-M29-2-FILTER FILTER
H I -M29-2- FILTER MEtALS LAB
il84-84-6D I-M29-2-HN03 9*HN03/10%H202
IJM29-2-HN03 MEtALS LAB
i
Hf
| To LAB To STORAGE
Date/Init Date/Init
-
!
||l84-84-6E IvM29-J-KMN04 iO»H2S04/4%KMN04 1
|| liM29-2-KMN04 METALS LAB |
| To LAB
Date/Init
To STORAGE
Date/Init
1
To LAB
Date/Init
'
i*1
1 1
i
I
To STORAGE
Date/Init
1
i
To LAB
Date/Init
l
(
I
-
To STORAGE
Date/Init
_
DISPOSED
Date/Init
|| Receiving Remarks: -1 I-M29-2-BHAR was not oh COC but was received. Sample 0-M29-FB-FILTER i« marked C-M29-2-FILTER but
|| • ' 'h»« the date 8/27/91 which is the same as the COC.
u ;'
|| ' Archive Remarks:
»Form Revised 05/27/1997 -- Page 3 OF 4*
-------
II Custody Seal : Absent Sample Seals: Absent
II Chain of Custody : Present Container...: Intact
|j Sample Tags : Absent
jj Sample Tag Numbers: Not Listed on' Chain of Custody'
|| SMO Forms : N/A
TLI Project Number 43411 Book
Client: PES03 - Pacific Environmental Services
184
Date Received | 09/26/97 | By ^J f\ Ji(> jfuT. — Pa9e
|| Ice Chest/Box NO COOLANT Carrier and Number HAND DELIVERED 84
||TLI Number , Client Sample ID ' Matrix
||mR/H:CPM. ....Client COC ID * Locatipn
||
||184-B4-6F I-M29-2-HCL 8N HCL
jj ' I-M29-2-HCL i METALS LAB
||l84-84-6G I-M29-2-BHAR BH 0.1N HNO3
II (Not Listed-Client COC] * METALS LAB
J
SV i
||184-B4-7A I-M29-3-FHACE FH ACE RNS
II I.-M29-3-FHACE METALS LAB
1
||l84-84-7B I-M29-3-FHAR FH 0.1HN03
|| ' I-M29-3-FHAR METALS LAB
||l84-84-7C I-M29-3-FILTER FILTER
I) I-M29-3-FILTER METALS LAB
||184-S4-7D I-M29-3-FH CATCH FRONT HALF CATCH
|| I-M29-3-FH CATCH METALS LAB
II
||lB4-84-7E I-4W9-3-HNO3 5VHN03/10VH2O2
I) • 1 I-M29-3-HNO3 METALS LAB
• II
||!84-84-7F I-M29-3-HNO3 5%HNO3/10%H202
II I-M29-3-HNO3 METALS LAB
|
||184-B4-7G I-M29-3-BHAR BH 0.1N HN03
|| I-M29-3-BHAR METALS LAB
||184-B4-7H I-M29-3-KMN04 10% H2SO4/4* KMN04
|| I-M29-3-KMNO4 METALS LAB
II ' '*
B184-84-7I I-M29-3-HCL 8N HCL SOLN
H I-M29-3-HCL METALS LAB
||
II
II
|| . , , .
! 1
II v
IL >
| To LAB
Date/Init
'
To STORAGE
Date/Init
j To LAB
Date/Init
To STORAGE
Date/Init
j To LAB
Date/Init
1
To STORAGE
Date/Init
| To LAB
Date/Init
1
To STORAGE
Date/Init
"" " '
DISPOSED
Date/Init
1
n
(LORecciving Remark* i •" I-M29-2-BKAR was not on COC but was received. Sample 0-M29-FB-FILTER is marked 0-M29-2-FILTER but fl
H ' )has the date 8/27/97 which is the same as the COC, II
I ' Archive RemarksJ
•Form Revised 05/27/1997 -- Page 4 OF 4s
-------
oject
43-4)1
Anrjlyles '
ICP - GFAA FI.AA CVAA
jfe/lnt.: fef7 l())fijc)'7
en.t Run// O-Alfll'/
,
oJSvvicGS Trinnnle Laboratories of RTP ,
C9 19). 544-5729
i
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CONT II
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CONT //
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CONT//. CONT"// -CONTJI
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VolunrieJiQ
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ln|
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IjOml con HN03 Do'° ./Opap-i
Volume (i» 3
Reduce
volume
to 20 ml on
Inl
i label
i Volume
ml
For Me lots For l-lg i
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wave dig'- 'nt
cone, MF •
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Inl
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el
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Dole fy*ltf I
(Ono post dlgesllon spk on 111 I lor GFAA)
! final spk cone. Dale
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FH & DH Serial dilution performed
. ml lo ml FV +.. uL Sc
• i
InlllnU-
-------
l AA TI.AA CVAA
llent:
nte/lnt.:
Triangle Laboratories of RTP
(919)544-5729
lent Run//
CQNTtf
©
CONT //
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CONT //
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label
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: label
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ml
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Add
>ulS(5
r^,i i , In!
Dllule to
100 mis g\e
label W-m-Q^M
• Volume JOd Ml
l-lolplale dig Inl.
wllhMNO3 i (/r]
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Allquol 0:__2__
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-
ppbi(lnslrumenl spiked)
_mL
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Aliquot B: 5 ml ,
label
j final spk cone. Da|e
I added .5 ppb
Inl
Volume
Dale
(One posl digestion spk on Ul I lor GFAA)
FH & DH Serial dIMIon performed
__i_ ml lo ml FV + uL Sc
• \
Initials:
-------
rojecl J/.
•llenh
ICP
• Ancjlyles '
GPAA R.AA CVAA
ate/lnt.:_
Triangle Laboratories of RTP ,
(919)544-5729
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volume lnl -:2L-
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lo 20 ml on
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(1 DM I IgSpIke required)
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100 mis
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Volume
_ i
ML
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wllhHNO3
and 11202 Dale
i label
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i Volume
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f Hg
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^ Dale
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Allquol D:
5
i Volume
i . — ....-...•«»...
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i Volume
Dale JO
(One post digestion spk on 011 tot GFAA)
FH & OH Serial dilution performed
< ml lo ml FV + uL Sc
\
Inlllals:
-------
IUJ • GPAA TI.AA CVAA
llenl:
nte/lnt.:
lent Run// lT-rf\c$' T"
Triangle Laboratories of RTP ,
(919)544-5729
i
1
CONT II
Filler -I
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CONF II
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Dock Half
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.DoMleale It
'. redlssolve In _ .
1-Oml con HN03 Dale
wave dig';
cone, I-IF
one. HNO3
Inl
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Dale
label
i
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label ji
Volume
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lo 20ml on
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label
I Hg Implnger s J'
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CONT «
KMNCM"
IIC1
label
Inl 3F
i Volume
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• Allrj
ilnl
ml
;abel
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Allquqj
Inl
Date /6
flf/ff
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:Fronl Half Dlgeslale
Volume Inf.
lo 20 mL on
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100 mis
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-lolplale dig
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J —.,.. — ...»«...
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100 mis
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ppb (Inslrumenl spiked)
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label
j final spk cone. Pa|e
A
added
ppb
Volume O. Dale
(Ono posl dlgesllon spk on Oil lo» GFAA)
FH & Dl-l Serial dllullon performed
__j ml lo ml FV + uL Sc
Inlllals:
-------
ojecl I, 43411
Anrjlyles '
ICP • GFAA PI.AA CVAA
lent:
jte/lnt.:
Grit Runtf 0 -fll£$ - FBk
Trianale Laboratories of RTP .
(91 9> 544-5729
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CONT «.
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label
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s. ' i
t
label
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Add
iuLS(5
Dilute to
100 mis
Inl
i Meioi
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lo 20 mL on
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500 uL Sc A
* Int. 4F
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1 *-"lv *
Inl. ^
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;inl.
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fNo snlka
ml
label
| VolumejDJ? Dale
(Ono posl digestion spk on 111 I tot GFAA)
FH & DH Serial dllullon performed
» ml to ml FV -f uL Sc
-------
Gl AA I:I.AA CVAA
:llent:
•ate/lnr.:
Triangle Laboratories of RTP
(919)544-5729
Merit Run//
com//
CONT //
Filler .1.
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label
.Deaaloolo to
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! redlssolve In
CONF //
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| Hg Implngets |'
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1 Date )<>r
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5TO
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lo 20 ml on
l-lolplale
Dllule to lnl
100 mls Dale
label
Volume
l-lolplale dig
wllhllNO3
and H202
Dale
Sample
Spike
(1 01 Hlg Spike required)
Add
500 uL Sc
)ale
label_
i Volume |OP • Dale J.
Aliquot A: ^
Allquol D: 0
Allquol A:
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[ Meioi
, For MI
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100 mis
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mL
i VolumeJ0_ Dale
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: f)
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ml
FH & OH Serial dllullon performed
< ml to ml FV + uL Sc
Initials:
• ----- - 4
Hr-ilo*
-------
rojecl //.
Anolyles '
ICP - GPAA IM.AA CVAA
are/lnt.:
Triangle Laboratories of RTP
(919)544-5729
Merit Run//
CONTW
©
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CONT II
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I Id
,B®«staais lo
'.drynooi and1
! redlssolve In
IjOml con HN03
, ,
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SSL
label
VolUmeJA}
label
label
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lo 20 ml on
holDlole
For Metals
For l-lg
i Volume/Q5 ^
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i cone,
:one.
3 dig-
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j Volume^y^J ml i j Volume.
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ilnl
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(Duplicate Analysis of Ea
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lo 20 mL on
I -lotolale
Add SOO uL S(5
DDulelo
100 mis Date
label
Volume
•lolplale dig
w)JhHNO3
and 1-1205
Inl.
Dalejt
Sample
label
Spike
(I DllllgSplkoiequbed)
Add
500 uL Sc
Inl.
i Melol
For
jel
lume
Inl
"ii label
3J^r
Dale.
• i."
i Volume.
Allquol A:
Allquol D:
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M
i!Volume /Qurnl Dale
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< Olfosl dig. spk.
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ml
i label
' j Volume /OO Dale
! of 10^ DPb
i
i final spk cone. Dale JO
j added n ppb •*"
fOhe nosl dlaesllon $tjk on 1)11 for GFAA)
FH & OH Serial dllullon performed
, • ml lo ml FV + uL Sc
-------
PAGE W'
INORGANICS SPIKE LOG
DATE
PROJECT *
SAMPLE IDs
ANALYTE
ORIGINAL
STANDARD
# -
ORIGINAL
STANDARD
CONC.
(PPM)
SPIKE
SAMPLE
FINAL
VOLUME
(ml)
SPIKE
SAMPLE
(PP8)
INITIALS'
WITNESS-
•*"
-SF
- LCS
,926
SE.
MSD
4-
(&?.
i
/*?/ -fc -J/
Jr
3-68-3
*»
/OS/*.
-M AS
490501) - LdS
s-m-n
i
m
1
-*•
3-013-3
' ^ ~ I '3-*-
3-
qa\forms\inospke.log (08/22/96)
57
-------
EXPdate
2/1/98
9/1/9«
2/1/98
9/1/98
2/1/98
2/1/98
9/1/98
-9/1/98
9/1/98
9/1/98
9/1/98
9/1/98
9/1/98
9/1/98
9/1/98
-2/1/98
9/1/98
9/1/98
8/1/98
9/1/98
9/1/98
2/1/98
8/1/98
9/1/98
9/1/98
9/1/98
9/1/98
9/1/98
9/1/98
9/1/98
9/1/98
8/1/98
SEE SPIKE LOG
Spiking Standard Preparation
Dement Standard Orig. Std. Spike(uL) cone
. 10
aJ»&»r#
ni^piM*
M
W
)
Ja/sS&ssS:
tfKtm
!a
!a
«d*'HB.ii'fii
:o '—-4
:r •. --
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'•»
<
<
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Ag
In -
do
Ja
via
* •%.- •,-
ib ~~s
>•
n '--•••*
i
rjf^-~
*a-iis-4v
3-oioW
2-115-4
3-010-7
2-115-4
2-115-4
3-010-10
3-010-10
3-012-7
3-010-10
3-010-10
3-010-10
3-010-10
3-012-6
2-115-4
3-012-5
3-010-10
3-010-8
3-010-10
3-010-10
2-115-4
3-010-9
3-010-10
3-010-10
3410-10
3410-10
3-010-10
3-010-10
3-010-10
3410-10
3-010-4
(ppm) Fvol(100mU (ppm)
wVX'M
-»'#
5000
950
5000
.
»--.»-r*?'
5
95
S
- *S'«S*.
- *s -^
s
95
'S&S ->•£
•i ,5 ,*
- -.s -••-
S
95
50
150
5
95
5
5
5
195
-•. 5
S r-
" S ^"
• -s .-
5
<-5 -.--
5
- S -«e-
15 V
SPIKING
rom Spiking Standard
pik*(uL) cone
FVd(100ml)
V^OOO ,**
•*HF«
1000
1000
1000
.«*tOOO-^s
-?*,iooo -"SSi
1000
1000
^.1000 ft?
1000 -
- 1000 A-
1000
1000
1000
1000
1000
1000
-1000 *
1000
1000
1000
-UC1000 --
1000 ?•
1000 T
1000 '
1000
4000 '
1000
--tooo ~
1000
(PPb)
•dM^"^
«»flL
50
950
so
#-50 *&
4i>ii'flO
so
950
ia»ao;vi
SOA«
.-.so
so
950
500
1500
SO
a SO
50
50
1950
--*»
so
so
•• so
•*>.
^90 -
50
*»M
S1SQ
combined
total
1000
1000
1000
2000
1000
2000
^ a»!
^200*%
"Spike separately
Bement Orig Std Spfl
-------
PAGE 1 OF 2
TRIANGLE LABORATORIES, INC.
Transfer Chain-of -Custody Form
Project
43411
Transfer From: IWLM To: IA I
Released by:
Initia-ls . .
flKJ'lL'
i "
Accepted by: VYI/A^"
MILES. ID
43411-
43411-
43411-
43411-
43411-
43411-
43411-
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43411-
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43411-
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43411-
43411-
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43411-
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43411-
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43411-
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-000
-001
-002
-003
-004
-005
-006
-007
-008
-009
-010
-Oil
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-013
-014
-015
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TLI No
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184-84-1A
184-84-1B
184-84-1C
184-84-1D
184-84-1E
184-84-1F
184-84-1G
184-84-1H
184-84-2A
184-84-2B
184-84-2C
184-84-2D
184-84-2E
184-84-2F
184-84-2G
184-84-2H
184-84-3A
184-84-3B
184-84-3C
184-84-3D
184-84-3E
184-84-3F
184-84-3G
184-84-3H
184-84-4A
184-84-4B
184-84-4C
184-84-4D
184-84-4E
Date Time
_ts/_a/°n 2a-- ^
~ (.
Cust .Id
TLI Method Blank
O-M29-1-FHACE"
O-M29-1-FHAR
0-M29-1-FILTER
O-M29-1-HNO3
O-M29-1-HNO3
O-M29-1-BHAR
O-M29-1-KMNO4
O-M29-1-HCL
0-M29-2-FHACE
O-M29-2-FHAR
0-M29-2-FILTER
O-M29-2-HNO3
0-M29-2-HN03
0-M29-2-BHAR
0-M29-2-KMN04
O-M29-2-HCL
O-M29-3-FHACE
O-M29-3-FHAR
O-M29-3-FILTER
O-M29-3-HNO3
O-M29-3-HNO3
O-M29-3-BHAR
O-M29-3-KMNO4
O-M29-3-HCL
I-M29-1-FHACE
I-M29-1-FHAR
I-M29-1-FILTER
I-M29-1-HN03
I-M29-1-KMNO4
Y-F-v-r'OO I'Of^tr TT / r\i / n f \
iditional comments or instructions:
-------
PAGE 2 OF 2
TRIANGLE LABORATORIES, INC.
Transfer Chain-of-Custody Form
Project 43411
Transfer From: IWLM To: IA I
IniZy&frs. . Date. .., ._. A Time . _. .
Released by:
Accepted by: VYKA/V 1W l ( / ^~l et® •
MILES ID
43411-
43411-
43411-
43411-
43411-
43411-
43411-
43411-
43411-
43411-
43411-
43411-
43411-
43411-
43411-
43411-
43411-
43411-
43411-
43411-
43411-
43411-
43411-
43411-
43411-
-030
-031
-032
-033
-034
-035
-036
-037
-038
-039
-040
-041
-042
-043
-044
-045
-046
-047
-048
-049
-050
-051
-052
-053
-054
TLI No
184-84-4F
184-84-5A
184-84-5B-.
184-84-5C
184-84-5D
184-84-5E
184-84-5F
184-84-5G
184-84-6A
184-84.T6B
184-84'-6C
184-84-6D
184-84-6E
184-84-6F
184-84-6G
184-84-7A
184-84-: 7B
184-84-7C
184-84-7D
184-84-7E
184-84-7F
18.4-84-7G'.
184-84-7H
184-84-71
LCS , . . ,
Gust .Id
I-M29-1-HCL -
O-M29-FB-FHACE
0-M29-FB-FHAR
O-M29- 2 -FILTER 8/27/97
0-M29-FB-HN03
0-M29-FB-BHAR
0-M29-FB-KMN04
0-M29-FB-HCL
I-M29-2-FHACE
. I-M29-2-FHAR
I-M29 -2 -FILTER
I-M29-2-HN03
I-M29-2-KMN04 • , -
I-M29-2-HCL
I-M29-2-BHAR
I-M29-3-FHACE
I-M29-3-FHAR
I -M29-3 -FILTER
I-M29-3-FH CATCH
I-M29-3-HNO3
I-M29-3-HN03
I-M29-3-BHAR •/ ~ -•
I-M29-3-KMN04
I-M29-3-HCL
Lab Control Spike
Additional comments or instructions:
-XfrCOC (Rev 11/01/94)-
60
-------
-------
* SEE SPIKE LOG
EXPtJat*
2/1/98
9/V98
2/1/98
9/1/98
2/1/98
2/1/98
9/1/98
""9/1/98
9/1/98
9/1/98
9/1/98
9/1/98
9/1/98
9/1/98
9/1/98
2/1/98
9/1/98
9/1/98
8/1/98
9/1/98
9/1/sa
2/1/98
a/i/sa
9/1/98
9/1/98
9/1/98
9/1/98
9/1/98
9/1/98
9/1/98
9/1/98
8/1/98
3«m«nt
^
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M
*l
3
3a
3«
:d
:e
<
<
wig
«b
>b
n
n
1
In
'-n
Spiking Standard P
'Standard Orig. Std.
ID '"(ppm)
2-115-4
3410-10
2-115-4
3-01 0-7
2-115-4
2-115-1
34fO-10
3410-10
3412-7
3410-10
3410-10
•3410-10
.3410-10
3410-ld
341 2-8
2-115-4
3412-5
3410-fl
3410-10
3410-10
3410-9
3410-10
3410-10
3410-10
341O-10
3410-10
3410-10
3410-10
3410-6
100
100
100
100
100
100 -
100
10000
100-
100
100
100
100
10000
1000
10000
100
10000
100
100
100
10000
100
100
100
100
100
100
100
100
1000
reparation
Spike(u(J cone
Fvd(ICOmL) (ppm)
5000
5000
5000
950
5000
5000
5000
5000
950
5000
5000
5000
5000
5000 ~
950
5000
1500
5000
950
5000
5000
5000
1950
5000
5000
5000
5000
5000
5000
5000
5000
1500
5
5
5
95
5
5
5
5
95
S
5
5
5
5
95
50
150
5
95
5
5
5
195
5
5
5
5
5
5
5
5
15
SPIKING
rom S pitting Stand ml
SpikefrL) cone
=Vd(100ml)
1000 >
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
1000
.-' 1000
1000
1000
tooo •
1000
1000
1000
1000 1
1000
1000
1000
1000
1000
tooo
1000
1000
1000
(ppb)
so
so
so
950
so
50
so
-so
950
so
so
so
50
SO '
950
SCO
1500
50
' 950
so
50
so
1SSO
so
50
so
50
so
so
so
so
ISO
combined
total
1000
1000
.*
1000
2000
1000
2000
20O'
1000UL ol the Spitang Standard gives tfie listed concl of «• «Oov» eicmtnu. ,
Element Orig Std Spik«(ul) cone
(ppm) FvdQOOm (ppbl
Au
C«
U
P
Pd
Pt
S
SI
Sn
S/
1000
1000
1000
1000
• 1000
1000
1000
10000
1000
1000
14O
30
70
100
160
300
350
350
20
5
1400
300
700
1000
1600
3000
3500
35000
200
SO
Spiking Standard 3-013-3
EXP: 11/26/97
Spiked by:
Pradigeatloev
Postdigeatfon- f
:.r
..: 62
-------
i.i I ••'si? Keoort
Hoc, 10-20-97 06:50*59 AH
owe 1
Name
f\[*
Method
fine QpIC' TVD*» Hode
1
7
J
4
S
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7
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1
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srrn -KI AM
Sfl'l-SlAMf
c:iri;
STfi.\
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sim -hi Mill"
if!" :HI niir
Mil'.
0|,,.
MM HI SHS
SUM -m HN!1
SII-\
STI'T.
i;HFi:x I n
irv/rrv
irn/i;i-R
ICR/ITH
li-h/fv.ft
irsM
4541! tlR
43411 ins
lft4-«4-|ARi:
lflJ-34-lAHr PfiS
iH4-H4-ienr i
IHit-St "W
l«4-H4-'fiHC UK
IH-l-fH-sHRr
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l«4-84-vriF flft
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lfU-K4-5ftl>
Fi:V/rrV
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I84-R4-AO
I84-S4-7F.F
184-50-70
JCV/OCV
fi:ft/f:r.H
ICSAH
101007
101997
101Q07
101997
101007
1 ru 997
IOIOQ--
101^97
1 0 1 'JQ ?
IlllN'-l/ "
1 (1 1 'JU )
l.i|OV7
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101>J97
101007
10 |99?
101007
11)1997
IOIOQ7
101997
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, Sill MI 997
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hi 1997
|0|007
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101007
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101007
101997
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101997
10199 7~
101997
10)907
101997
101097
101997
FRIA.W?
TRiHtl(il.2
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10/20/97
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10/70/07
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10/20 '07
10/20/97
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10/70/07
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10/70/97
10/20/97
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10/20/97
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10/70/07
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10/20/07
10/20/97
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10/20/07
10/20/97
10/20/97
10/20/Q7
10/20/97
10/70/97
10/20/97
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02
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05
05
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05
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05
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04
04
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04
04
04
04
04
04
04
04
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05
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05
05
05
05
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06
06
06
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DKH
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DKH
DKH
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A
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-------
PAGE 1 OF 5
Project: 43411
TRIANGLE LABORATORIES, INC.
Sample Preparation Tracking & Management Form
Client: Pacific Environmental Services (PES03)
•^3
t/Acids() : jf1
Method
Solvent/Acids
U
Sample Information
Extraction Date:
Lot:
I TLI /
Sample] SAMPLE ID / CLIENT
# crd] / SAMPLE ID
I I I
| Sample (Final |
|Wgt / ToN Volume | / /_
| g / fcl J ml |
| TLI Blank
000 |
Method Blank |
L
«*>
| 184-84-1A
001
|
O-M29-1-FHACE |
I
1
| 184-84-1B
002
O-M29-1-FHAR
I
1
| 184-84-1C/V-B
5 i itoj
003
| 184-84-1D0
004 |
i 5 IKS.!
i -^•••~« "i "i1 " '7*'
1 £> '100 '
1 184-84-1E
005
O-M29-1-HN03
1
1
| 184-84-1F
i 5 i.
006
A..!.
5 !
007
008
| 184-84-1G
| 184-84-1H
I
0-M29-1-HCL |-
.;.]«?..,.
i \i\t~, i
| 184-84-2A
009
| 184-84-2B
010 I
I I I
0-M29-2-FHACE | | I
I I I
0-M29-2-FHAR |
184-84-2C/}$
Oil
Comments:
-REV 07/26/93 (PSTMF 7)--
64
-------
PAGE 2 OF 5
TRIANGLE LABORATORIES, INC.
Sample Preparation Tracking 6 Management Form
ject: 43411 Client: Pacific Environmental Services (PES03)
iod:
/ent/Acids() :
Sample Information
mm
Extract ii
Lot:
Sample Infi
.Date: jifl/S]
H3
| TLI / | Sample |Final | |
-;.e| SAMPLE ID / CLIENT |Wgt / rfolV Volume | / / |
rd| / SAMPLE ID I 9 / t1/ ml I I
' I
| 184-84-2E
1
O-M29-3-FHACE |
184-84-3B
0-M29-3-FHAR
184-84-3DE;
184-84-3E
O-M29-3-HN03
I
0-M29-3-HN03 |
I i
i i
| 184-84-3F
| 184-84-3G
1
0-M29-3-BHAR
5 ' ,-oo
......5...;.
i ^ i_
r
5...1QD.
| 184-84-3H
| 184-84-4A | | I
| I-M29-1-FHACE | | |
\oS-X
-REV 07/26/93 (PSTMF
65
-------
99
--(L dKLSd) E6/9t/i.O A3H-
: S3USUJU1OO
l[,bHQ' '
I ' 32IS 1
00! i g i
0oH £ i
.„
1
i 5 i
9 i
I 91
| 5 i
SEC
eoNH-aj-ezw-o
I-EC
L6/LZ/S
i <5 i
EEC
1 ,EC
i
Qtf
TEC
OEC
Jfr-frS-frST |
c?o/ , g _,
i 9 i
,001,
QOI
_i
HWU-T-63W-I
| 9CC
i / /
/ / i
I
/ / i / /
1
Tui
ai
JUaiTD /
ai aadiws |sidiuec
nx |
I
UOT3BUIIOJUI
1 l/ . :
a-[dui%s
UOf3DB^3X3
: OSPTOY/3USAIOS
(EOSSd)
uuoj ausuisBeiTBW
-------
PAGE 4 OF 5
TRIANGLE LABORATORIES, INC.
Sample Preparation Tracking t Management Form
iject: 43411 Client: Pacific Environmental Services (PES03)
hod:
vent/Acids ( ) :
H
Sample Information
Extract!
Lot:
| TLI
•le| SAMPLE ID
rd|
/
/ CLIENT
/ SAMPLE ID
I I I
| Sample (Final |
|Wgt //fo5k| Volume | /_
| g /(ml/ ml |
' / I Ifr*/ | / / | / / | / / | / / |
| 184-84-6B
|
|
I-M29-2-FHAR |
1 1
1
\
/ i
184-84-7B
i
I-M29-3-FHAR
.W:.1
-------
PAGE 5 OF 5
Project: 43411
TRIANGLE LABORATORIES, INC.
Sample Preparation Tracking t Management Form
Client: Pacific Environmental Services (PES03)
Solvent/Acids ():
Extraction Date:
Lot:
Sample Information
| TLI /
Sample| SAMPLE ID / CLIENT
i crd| / SAMPLE ID
III I
| Sample*]Final | | \^
| Wgt /Vofll Volume | / / | _J&X$i
| g A ml ]\ ml |
^_ | / / I / / I / / I / /
| 184-84-7H
i 5 "
052
| 184-84-71
053 '
I
LCS
I «lll_ I
054 1
Lab Contro1 Spike
M*
/OS
>,>„
5._.U0<>;.
5 ' \02> '
,V>
**
1 «j3mj LCS20
""" """"ViS"
' 6
IOP
\V\-W~ TBF IMS
f""MB"
I N h |
|00
V5
i 5 THEM
0
0
5 ' i»
Comments:
-REV 07/26/93 (PSTMF 7).
68
-------
PAGE 1 OF 1
ject: 43411
TRIANGLE LABORATORIES, INC.
Sample Preparation Tracking & Management Form
Client: Pacific Environmental Services
(PES03)
lod:
/ent/Acids() :
Sample Information
Extraction Date:, / /
i
i
| TLI /
ie| SAMPLE ID / CLIENT
rd | / SAMPLE ID
I I I .- ,
| Sample | Final | | T)ftfe. I I I
| Wgt / fco\ | Volume | / / | / / | / / | / / | / /_
I 9 /i/myl ml | | | | |
TLI Blank
|
TLI Method Blank |
|
I
I
5
.
J>
/ DPS
f
-REV 07/26/93 (PSTMF 7)--*
69
-------
PAGE
MERCURY SPIKE LOG
DATE
PROJECT #
SAMPLE IDs
ORIGINAL
SPIKE
CONC. (Hg)
STANDARD #
WORKING
STANDARD
P.REPARED
FROM
SPIKE
AMOUNT
(mL)
SPIKE
SAMPLE
(PPB)
INITIALS
WITNESS
3-0^-8
V-
IDS;'
(Q/aoHi
12*-
-50- i D Mf ^
IT? M5D
-50-
-55-
M.
n
II
i
i-
I
TSF
ID aim
MafllCnl cb
llO-IO-aMS
1^0-10- 3MSD
.W
L
m
0.
MS
\
qa\forms\hgspke.log (08/22/96)
70
-------
CO oo 3D 3C
3J
t»
35
1 J. ' ' ' ', ' '„
Ti '-^ r*l 3D 3D 3D 3C- X
U
r
Co CO co t/s io io :/:
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3
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-------
CM
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— ex.
-------
CO
r-
s.
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-
C- «1
> =
c. <= c &.
cr •- o — •-
2 § ° 5 -
I/I C t -T? -^t
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— c.
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c -^ a
oc •*- c — -*
r., c —
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a; > jZ
-------
Rp.pnrt
n 10-70-97 06.-30-.SS AM oage 1?
Hfitond: TRIAN6I.2 Saiplp, M«er STIM Operator:
Run TUP: 10/70/97 0?:3R Filpnw: I01W
Mnde: IR Type: X Corr Factor: 1.00000
lab ID.: Cust.. Sip). 10.: Ciist. 10.:
Fleas Ao.3280 A13082
Unit.*. count count cmmt
Avqp. 42<»5l .017S7 .O.SSO
Sfipv .Oftlfifi .0001? 0(1055
6_2496 Ra4934 8e3130
rnunt count. count.
. I7u83 .2^%1 .3I"!
.00151 .0014?
I.0007S 88^84
Units rnunt .count ronnt. count count count
SWOP .nno?Q i.Uiii? .r^^s 1-JftSl .tftOM' I7S9
Miuu ."MKIV/ IMV-llS •illO.'H (INI 1 1 i'X)!r> 000 1. \
5RSO
* /hnJ Mn7u7
rniint rnnnt
.l.7.66o
fiiT?7<»o
ro/'nt rnnnt
.0'.»S8
000 1 I .001"
nn.'0?0
rnun-t
Units
SRSP
rnunt
00144
.77^78
Mi?.\lf>
count.
.00321
.77304
.00015
.62627
;HSH
1^60-1 l4 .13048
.OOliil .00128 .00103
.AP755 I.73S7.4 .7^634
Sr4215 Til349 T119Q8
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IP i.SUM ? Sn^ 4.SS.S s.Bis l-10.?s 3.934
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103
-------
is Report
. Hon 10-20-97 06:30:>5 flH page 43
Method: TRl«Hfil.2 Saiple Ha»e: ICV/CCV Operatar: OKH
Run HUP.: 10/20/97 05:20 Filena»e: 101997
Unite: OflNC Tvpp,: 0 Corr. Factor: 1.00000
I ah in.: Ciist. SID I. U1.: f:nst IP : 43411
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ns-thr.,1: TfilAiif,i2 Smote Haiie: 184-84-60 Ooerator: OKH
fun MI.P- li)/?n/97 05:51 rit»n«»: 101°°7
node: i;fiMc Type: S f:orr. Factor: 1.00000
Ub ro.: " r.ust. Sm>). in.: . finst. ID.: 43411
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flvap 9.077 " 48.38 57.P 26.16 *67.4 46.65
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Loc. Concentration
0
1
£
4
5
&
7
8
9
10
11
12
13
14
15
1&
17
18
19
£0
£1
££
£3
£4
39
50.0 ug/L
100.0 ug/L
ID/Weight File: EB17£.IDW
Solut ions
Calib. Blank / Diluent / ICB / CCB
Stock rbd'SP
Stock / Recovery Stock |->-&3-
ICV=30ug/L U " "
CHECK LO
43411 MB
43411 LCS
184-84-IftBC
184-84-lflBC L
184-84-£ftBC
184-84-3flBC
184-84-4ftBC
184-84-5ftBC
184-84-&ABC
184-84-7flBCT>
184-84-1DE
184-84-1DE L
184-84-£DE
184-84-3DE
184-84-4D
184-84-5BD
184~84-feD
184-84-7EF
Modifier 1
112
-------
Element File: TL.GEL
-Iement: TI
^rint Data: Main+Suppl.
:'rint: Calib. Curve
finalyst: HOLSTE
Peak Storage: 1 Repl./Sample
INSTRUMENT: 4100 ZL
Wavelength: £76.8 Peak
Signal Type: Zeeman Aft
?ead Time: 5.0
Sample Replicates: S.
Standard Replicates: 2
Technique: HGft Version: 7.30
Slit: C. 70 Low
Signal Measurement: Peak Area
Read Delay: 0.0 BOC Time: 2
Spike Replicates: Same as Sample
;ALIBRATION:
Solutions 1 ID
1
lalib. Blank 1 STD BLK
Standard 1 ISTDl=£5ug/L
Itandard £ ISTD£=50ug/L
Standard 3 1 STD3=100ug/L
ieslope Std. I50ug/L
Diluent Location: 0
Modifier #1 Location: 39
Calibration Units: ug/L
Calibration Type: Linear
Cone 1 Location
1
_ _«. _ _ 1 (7i
£5.01 1
50. 0 I 1
100.01 £
50. 0 I 1
I _
Volume
£0
10
£0
£0
£0
£0
Diluent M
Volume 4t
5
15
5
5
5
5
odi f i er
1 #£
5
5
5
5
5
5
Modifier #£ Location:
Sample Units: ug/L
urnace Time/Temperature Program:
tep Temp Ramp Hold IGas Flow Read Gas Type
1 110 5 3® 1 £50
£ 130 1 35 1 £50
3 700 5 £0 1 £50
4 1600 051 0
5 £500 1 5 1 £50
Norm
Norm
Norm
* Norm
Norm
njection Temp: £0 Pipette Speed: 85%
Extraction System: On
EQUENCE:
tep Action and Parameters
1 Pipet diluent •*• modifier 1 + spike
£ Run HGA steps 1 to End
sample/std
HECKS:
ecalibration Type:
ocations: None
Reslope
one. Above Calibration Action: Dilute
Iternate Sample Volumes (uL>: 5,£,1
un Alternate Volume Blanks: Yes
& Reanalyze After 1 Rep
f %RSD > £0.0 and Concentration > 1.7 then Retry 1
leek %RSD on: Samples + Standards + Spikes + QC Samples
t imes
ecovery Measurements:
uL of 100 ug/L Standard at Location £ Gives £5.0 ug/L
?asure Recovery on Samples: 9,10,17,18
id to QC Samples: Yes % Recovery Limits: 75 to 125
113
-------
QC:
*H A/S I QC Sample I Cone. Limits I After(Periodic I At I Count As I
I Loc. I ID I Lower Upper ICalibl Check I End I Sample I
1 4 ICV=30ug/L £7.0 33.0
£ 0 ICB -£.0 £.0
3 5 CCV=fc0ug/L 48.0 7£. 0 XX
4 0 CCB -£.0 £.0 XX
Run Periodic QC Samples: Every 10
Out of Limit Actions Reslope and Rerun Samples
Matrix Check Calculations:
* Difference for Dupls: No Locations:
% Recovery for Spike: No Locations: Cone:
114
-------
>ate: 10/31/97
)ata File: EB17£.DAT
'echnique: HGfl
Tine: 05:41
ID/Wt File: EB17£.IDW
Calib. Type: Nonlinear
Slits 0.70 L
Lamp Current:
Energy: 49
w A* A* A* A/ *V A* Af A* A/ Af A/ A* Af A* A/ A* A* A* A* A* A* A* A/ A/ A/ A* A/ A/ *V A/ A* A* A* A* A* A* A» Af A* A* A* «
ID: STD BLK
Seq. No. : 00001
fl/S Pos. : 0
Date: 10/31/97
iL dispensed: 5 from 0, 5 from 39, £0 from 0
leplicate 1 Time: 05:43
'eak flrea (ft-s): -0.000 Peak Height (ft): 0.007
Background Pk flrea : 0.001 Background Pk Height : 0. 1
L dispensed: 5 from 0, 5 from 39, £0 from 0
eplicate £ (Peak Stored) Time: 05:46
eak flrea (fl-s): -0.001 Peak Height (fl): 0.007
ackground Pk flrea (fl-s): 0.001 Background Pk Height (fl): 0.008
lank Corrected Pk flrea (fl-s): -0.001
oncentration (ug/L ): -0.5
ean Cone (ug/L ) :
uto-zero performed.
-0.£
SD: 0.38
RSDC/.) : 175.09
A, A, A, A, A, A, A, A, A, A, A/ A, A, A, A, A, A, A, A, A, A, A, A. A, A, A, A, A, A, A, A, A, A, A, A, A. A, A, A, A, A, A, A, A, A- A, A, A, A, A/ A, A, A, A, A, A, A, A. A/ A, A, A, A, A, A, A, A, A, A, A. A. <\. «V\. A* A, <\. •-
1 ID: STDl=£5ug/L Seq. No. : 0iZi00£ fl/S Pos. : 1 Date: 10/31/97
L dispensed: 15 from 0, 5 from 39, 10 from 1
eplicate 1 Time: 05:49
eak flrea (fl-s): 0.035 Peak Height (fl): 0. 04&
ackground Pk flrea (fl-s): 0.8££ Background Pk Height (fl): 0.0£5
lank Corrected Pk ftrea (fl-s): 0.036
oncentration (ug/L ): £3.1
L dispensed: 15 from 0, 5 from 39, 10 from 1
eplicate £ (Peak Stored)
eak flrea (fl-s): 0.034
ackground Pk flrea (fl-s): 0.0£1
lank Corrected Pk flrea (A-s): 0.034
oncentration (ug/L ): ££.3
Time: 05:5£
Peak Height (fl): 0.043
Background Pk Height (fl): 0. 0£fe
ean Cone (ug/L ):
££.7
bandard number 1 applied. C£5.03
orrelation coefficient: 1.00000
SD: 0.57
Slope: 0.0014
RSD(*) : £.
VA, A, A, A, A, A- A, A, A, A, A, A, A, A, A, A/ A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A, A. A, A, A, A, A,
1 ID: STD£=50ug/L Seq. No. : 00003 fl/S Pos. : 1
Date: 10/31/97
_ dispensed: 5 from 0, 5 from 39, £0 from 1
?plicate 1 Time: 05:55
sak flrea (fl-s): 0.077 Peak Height (fl): 0.087
nckground Pk flrea (fl-s): 0.041 Background Pk Height (fl): 0.053
Lank Corrected Pk flrea (fl-s): 0.078
jncentration (ug/L ): 55. fe
115
-------
Peak Area : 0.076
Background Pk Area (A-s>: 0.043
Blank Corrected Pk Area : 0.077
Concentration (ug/L ): 54.8
Peak Height (A): 0.088
Background Pk Height (A): 0.048
Mean Cone : 1.11
A* A# A/ A/ A* A* A/ A* A/ *
Tl
ID: STD3=100ug/L
Seq. No.: 00004
ft/S Pos.: £
Date: 10/31/9
uL dispensed: 5 from 0, 5 from 39, £0 from 2
Replicate 1 Time: 06:01
Peak Area : 0.150 P»ak Height (A): 0.165
Background Pk Area (A-s): 0.086 Background Pk Height : 0.098
Blank Corrected Pk Area (A-s): 0.151
Concentration
-------
L dispensed: 15 from 0, 5 from 39, 10 from 1
eplicate 1 Time: 0&:0S
'eak Area : 0.024
lank Corrected Pk Area : 0.018 Background Pk Height (ft): 0.023
lank Corrected Pk Area
-------
Calihratinn -
118
-------
ates 10/31/97 Time: 06:19 Slit: 0.70 L
ata File: EB 172. DOT ID/Wt File: EB17S. IDW La»p Current: 0
echnique: HGA Calib. Type: Linear Energy: 5S
V A* A/ A/ *U A* A* A/ A/ A* A* A/ A/ A/ A* A* A* A* A/ A/ A/ A/ A/ A/ A/ A/ A* A* A* A* A* A* A/ A* A* A/ A* A/ A* A* A* A/ A/ A/ A* A/ A/ A/ A* A/ A* A/ A/ A/ A* A* A/ A/A/A/ A/A*A*A* A/A/Ar A/A/A*A*A/A« A« A*A**W*
1 ID: ICV=30ug/L Seq. No. : 00006 A/S Pos. : 4 Date: 10/31/97
_ dispensed: 5 from 0, 5 from 39, £0 from 4
splicate 1 Time: 06:22
eak Area (A-s) : 0. 04£ Peak Height (ft): 0.049
ackground Pk flrea
-------
Background Pk Area (A-s): 0.084 Background Pk Height A#A*^*A* AfAsAr As A«A«A/ArAf ArA*A/A*Ar A*A« A? A* A**
Tl ID: 43411 MB Seq. No.: 00009 A/S Pos. : 7 Date: 10/3i/«
uL dispensed: 5 from 0, 5 from 39, £0 from 7
Replicate 1 Time: 06:40
Peak Area (A-s>: -0.001 Peak Height (ft): 0.007
Background Pk ftrea : -8.884 Peak Height (ft): 8.887
Background Pk Area (A-s): 8.884 , Background Pk Height (A): 8.807
Blank Corrected Pk Area (A-s): -8.004
Concentration (ug/L ): -2.4
Mean Cone (ug/L ): -1.3 SD: 1.58 RSDC/.): 113.3
A/ A/ A/ A/ A/ A/A/ A* A* A/ A/ A* A/ A* A* A/ A/ A* A* A/ A* A* A* A/ A* A* A* *V A/ Af A* A* A* A* A*A*Af *V A* A* A* AvA»A» A»A# A* A* A* A* A* A* A* »VA*A»A**WA* A/A*A»A*A* A* A*A»*WA» A* A*Av*\* A* A/A*
Tl ID: 43411 LCS Seq. No. : 80010 A/S Po*.s 8 Date: 10/31/
uL dispensed: 5 from 8, 5 from 39, £0 fro« 8,
Replicate 1 Ti«*: 06:45
Peak Area (A-s): 0.847 Peak Height (A)s 8.051
Background Pk Area (A-s): 8.838 Background Pk Height : 0.034
Blank Corrected Pk Area (A-s): 8.848 '
Concentration (ug/L ) : 3£. 1
uL dispensed: 5 from 8, 5 from 39, 20 fro» 8
Replicate £ (Peak Stored) Times «6i48 U>-3-*7 «
Peak Area (A-s): 8.854 Peak Height (A)s 0.062
Background Pk Area (A-s): 8.833 Background Pk Height
uL dispensed: 5 from 8, 5 from 39, 20 from 9 „
n_f^r^_rL->yivi|^ivji^j^,i^,j^,j\ri^jv>^(\,i\jn-ronj'\jn_ir\j HJ HJ HJ |}j'lVii*^i'^n»r>jwv^'^•^•^••^•^<^»^«^»t^>^^»^"y^*%«jVT»'^j'^'\»"W~wf^^"^T^^-^r^f
Tl ID: 43411 LCS Seq. No.s 00012 A/S Pos.: 8 Datei 10/31,
uL dispensed: 5 from 0, 5 from 39, 20 from 8
Replicate 1 Time: 06:52
Peak Area (A-s): 8.855 Peak Height (A) s 0.864
Background Pk Area (A-s): 8.831 Background Pk Height (A): 0.037
Blank Corrected Pk Area (A-s): 0.056
Concentration (ug/L ): 37.4
120
-------
>ak Area : 0.052 Peak Height : 0.060
ickground Pk Area : 0.053
mcentration : 36.4 SD: 1.50 RSDC/): 4.14
t Ay Av Ay Av Av Ay Ay Ay A* Ay Ay Av Av Ay Ay A* Av A* Av Av A* A* Ay Ay Ay A* A> Ay Ay Ay Av Ay Ay Ay Ay A* Ay Ay A* Ay A* A* Ay Ay Ay Ay Ay Ay Ay Av Ay Ay A/Ay Ay Ay Ay Ay AyAy Ay Ay AyAy AyAy AyAyAy AyAy Ay Av Ay AyA* •"W
ID: 184-84-lflBC Seq. No. : 00013 ft/S Pos. : 9 Date: 10/31/97
. dispensed: 5 from 0, 5 from 39, £0 from 9
plicate 1 Time: 06:58
ak flrea (ft-s): 0.001 Peak Height : 0.007
.ckground Pk Area 3 Seq. No.: 00014 A/S Pos.: 9 Date: 10/31/97
. dispensed: 5 from 39, 5 from £, £0 from 9
plicate 1 Time: 07:04
ak Area (A-s): 0.031 Peak Height (A): 0.050
ckground Pk Area (A-s): 0.018 Background Pk Height (A): 0.035
ank Corrected Pk Area (A-s): 0.031
ncentration (ug/L ): £1.1
. dispensed: 5 from 39, 5 from £, £0 from 9
plicate £ (Peak Stored) Time: 07:07
ak Area (A-s): 0. 0£9 Peak Height (A): 0.051
.ckground Pk Area (A-s): 0.019 Background Pk Height (A): 0.034
ank Corrected Pk Area (A-s): 0. 0£9
ncentration (ug/L ): 19.7
an Cone (ug/L ): £0.4 SD: 0.96 RSDC/O: 4.70
covery is
,^^^
ID: 184-84-1ABC L Seq. No. : 00015 A/S Pos. : 10 Date: 10/31/97
dispensed: 5 from 0, 5 from 39, £0 from 10
plicate 1 Time: 07:10
ak Area (A-s): -0. 00£ Peak Height (A): 0.005
ckground Pk Area (A-s): 0.003 Background Pk Height (A): 0.007
ank Corrected Pk Area (A-s): -0.001
ncentration (ug/L ): -0.9
121
-------
Peak flrea (ft-s): -0.001 Peak Height (ft): 0.007
Background Pk ftrea (ft-s): 0. 00£ Background Pk Height (ft): 0.008
Blank Corrected Pk ftrea (ft-s) : 0.000
Concentration (ug/L ): 0.0
Mean Cone ^^ A»A»^^^*^^A» Ar^to *VW A*
Tl ID: 184-84-2flBC Seq. No. :..00flU7 ft/S Pos. s 11 Date: iC/31/
uL dispensed: 5 from 0, 5 from 39, £0 from 11 ::
Replicate 1 Time: 07:££
Peak ftrea (fl-s): 0.002 Peak Height (ft): 0.007
Background Pk ftrea (fl-s): 0.000 Background Pk Height (ft) s 0.007
Blank Corrected Pk flrea (fl-s): 0.003
Concentration (ug/L ): 1.9
uL dispensed: 5 from 0, 5 from 39, 20 from 11
Replicate £ (Peak Stored) Time: 07:24
Peak flrea (fl-s): -0. 00£ . Peak Height (ft): 0.007
Background Pk flrea (fl-s): 0.000 . ',-.• Background Pk Height (ft) : 0. 007
Blank Corrected Pk flrea (fl-s): -0.001
Concentration (ug/L ): —0.8
Mean Cone (ug/L ): 0.6 SD* 1.96 RSD<*> s 347.fi
r^i\tf^*\fr^i^f\fi\^i\ff^i\t*\t'\f'^r^t\f*\f*\ti\tt\f'\ft\t*^
Tl ID: 184-84-3flBC ^Sfc.Q. No. s 00018 ft/S Pos. : 1£ Date: 10/31/
uL dispensed: 5 from 0, 5 from 39, £0 from 12
Replicate 1 Time: 07:£7
Peak flrea (fl-s): -0.003 , Peak Height (ft): 0.008
Background Pk flrea (fl-s): 0.005 Background Pk Height (ft): 0.009
Blank Corrected Pk flrea (ft-s): -0.002
Concentration (ug/L ): -1.4
122
-------
eak ftrea (ft-s): -0.001 Peak Height (ft): 0.009
ackground Pk ftrea (ft-s): 0.003 Background Pk Height : 0.009
lank Corrected Pk ftrea (ft-s): -0.001
oncentration (ug/L ): -0. A
ean Cone : 77.18
1 ID: 184-84-4ftBC Seq. No. : 00019 ft/S Pos. : 13 Date: 10/31/97
L dispensed: 5 from 0, 5 from 39, £0 from 13
ample abs. is greater than that of the largest standard.
eplicate 1 Time: 07:33
eak firea (ft-s): 0.162 Peak Height A/ A/ *VW A* *V A* A* A* A* A^ A* *\* A/ A* A* *V^^ A/ A/ A* A/ A/ A/ A/ A/ A* A* A/ A^ A^ A* A* A^ A^ A* A^ A^ A^ A* ''v A* A* A* A/ •"
1 ID: 184-84-4ABC 2.A Seq. No. : 00020 fi/S Pos. : 13 Date: 10/31/97
- dispensed: 20 from 0, 5 from 39, 5 from 13
eplicate 1 Time: 07:36
eak Area (A-s): 0.091 Peak Height (A): 0.265
ackground Pk Area (A-s): fl. 355 Background Pk Height (A): 0.209
lank Corrected Pk Area
-------
e\f A/ A* A/ A* A/ A* A* A* A* A* A* A* A* A/ A/ A* A* A* A* A» A* Af Af A* A* A* A» A* A* A* A* A* A/ A» A* A* A* A* A* A* A* A/ *V A* A> A* A/ A* A* Ar A* A» A* A/ Ar ArAs A*A**V Ar A*A* A*A* A* Ar A* A* A* A* A* Ar A/ A*Ai
Tl ID: CCB Seq. No. : 00022 A/S Pos. : 0 Date: l®/31/ : 0.005
Blank Corrected Pk Area A#*V^A» A*
Tl ID: 184-84-5ABC Seq. No. s 00023 A/S Pos.: 14 Date: 10/31/
uL dispensed: 5 from 0, 5 from 39, 20 from 14
Replicate 1 Time: 07:53
Peak Area (A-s): -0.001 Peak Height (A): 8.007
Background Pk Area (ft-s) : -0. 002 Background Pk Height ^»n*A» A* A*A* A# A* A* A*A»A*A* A*A» A*A* A> A* A* A* A^Af A* A/A* A/ A* A* A*Ay A» A» A» A* AA*
Tl ID: 184-84-6ABC Seq. No.: 00024 A/S Pos.: 15 Date: 18/31/
uL dispensed: 5 from 0, 5 from 39, 20 from 15
Replicate 1 Time: 07:59
Peak Area (A-s): 0.125 Peak Height : 0.263
Background Pk Area (A-s): 0.587 Background Pk Height' : fc,257
Blank Corrected Pk Area (A-s): 0.-126
Concentration (ug/L ): 84.3
uL dispensed: 5 from 0, 5 from 39, 20 from 15
Replicate 2 (Peak Stored) Tine: 08:02
Peak Area (A-s): 0.129 Peak Height (A) s 0.289
Background Pk Area (A-s): 0.546 Background Pk Height
-------
AtAtAtArAtAtArArA* ArAtAtAtAtAtArAtAtAtAtAtA* AtAtArArAt AtArArAtAtAtArAtAtAtAr AsArArArArArArAtArArAr ArArAtA**
ID: ia4-84-7flBCbc«,
Seq. No
000£5
ft/S Pos. : 16
Date: 10/31/97
L dispensed: 5 from 8, 5 from 39, £0 from 16
eplicate 1
eak ftrea (ft-s): 0. 03£
ackground Pk ftrea : 0. 0£9
ackground Pk ftrea (ft-s) : 0.581
lank Corrected Pk ftrea : 7.63
125
-------
*V *\* *\* »\e A* A* A*
Tl
ID: 184-84-1DE L
Seq. No.: 00028
fl/S Pos. : 18
Date: 18/31/c
uL dispensed: 5 from 0, 5 from 39, £0
Replicate 1
Peak ftrea (fl-s) : 0.000
Background Pk flrea (fi-s) : -0.001
Blank Corrected Pk Area
Tl
ID: 184-84-£DE
Seq. No.: 00030
fl/S Pos.: 19
Date: 10/31
uL dispensed: 5 from 0, 5 from 39, £0 from 19
Replicate 1 Ti«e: 08:34
Peak flrea (fl-s): 0.001 Peak Height
-------
i\t f\f f\f *v A* A* At At At At At At At A* At A/ At Af A* Af Af At At At At At At At At At At At At At A» At A* At At A» At At Af At At At At At At At At At At At At At At At At At At At At At Ar At AtAr At Af At AtAr A*
1 ID: 184-84-3DE Seq. No. : 00031 A/S Pos. : 20 Date: 10/31/97
L dispensed: 5 from 0, 5 from 39, £0 from £0
eplicate 1 Time: 08:40
eak Area (A-s) : 0.001 Peak Height (ft): 0.007
ackground Pk Area (A-s): 0.001 Background Pk Height : 0.011
lank Corrected Pk Area
-------
At At A/ At At At At At At At At At A/ At At At At At At At A* At At At At A* At At At A/ A* At At At At At At A* At At At A* At At At At At At At A* At At At At At At At At At At At At At At A* A* At A* At**
Tl ID: CCB Seq. No.: 00034 A/S Pos. : 0 Date:
uL dispensed: 5 from 0, 5 from 39, £0 from 0
Replicate 1 Tin*: 08:58
Peak Area (A-s): -C. 801 Peak Height (ft): 0.007
Background Pk Area (A-s) : -0.000 Background Pk Height (A): 0.00
Blank Corrected Pk Area (A-s): 0.000
Concentration (ug/L ): 0.1
uL dispensed: 5 from 0, 5 from 39, £0 from 0
Replicate 2. (Peak Stored) Time: 09:01
Peak Area (A-s): -0.001 Peak Height (A): 0.007
Background Pk Area (A-s): 0.001 Background Pk Height (A): 0. 0e
Blank Corrected Pk Area (A-s): 0.000
Concentration (ug/L ) : 0. 1
I Mean Cone (ug/L ): 0.1 SD: 0. 06 RSD(*)
QC sample is within range —2.0 — S. 0
*V -^t*vAtA/Af *v Af At *\r At At At At *V *V At A/ *V A/ *V *V *\t A» A/ A* A*A»A»AyA^Ar^>*V*VA» Ay Af A»Ar At At At At At At At At A/ At A> A»At AtAt At AtAt AtAt At At AtA»*W At A»A**
Tl ID: 184-S4-5BD S«q. No. : 00035 A/S Pos. : 22 Date
uL dispensed: 5 from 0, 5 from 39, £0 from £2
Replicate 1 Time: 09:04
Peak Area (A-s): 0.001 Peak Height (ft): 0.006
Background Pk Area (A-s): -0.001 Background Pk Height (A) s 0.0
Blank Corrected Pk Area (A-s) s 0.002
Concentration (ug/L ): 1.5 '
uL dispensed: 5 from 0, 5 from 39, 20 from £2
Replicate £ (Peak Stored) Time: 09:107
Peak Area (A-s): -0.001 Peak Height (A): 0.007
Background Pk Area (A-s): 0.001 Background Pk Height (A) s 0. : 0.008
Background Pk Area (A-s): -O. WMB Background Pk Height (A) s 0. »
Blank Corrected Pk Area (A-s) : 0.002
Concentration (ug/L ): l.£
uL dispensed: 5 from 0, 5 from 39, 20 from £3
Replicate 2 (Peak Stored) Time: 09il3
Peak Area (A-s): -0.003 Peak Height (A): 0.009
Background Pk Area (A-s> : -0.000 Background Pk Height XA) s 0.
Blank Corrected Pk Area (A-s): -0.002
Concentration (ug/L ): -1.5
i:
-------
k* A^ *W A* A* A* A* A* A* A* A/ *V ^^ A* A^ A* A* A* ^^^w A* A/^^ A* A/ A/ A**V A* A* A»*W*^ A* A* A/ A/ A*
L ID: 184-84-7EF Seq. No. : 08837 A/S Pos. : £4 Date: 10/31/97
. dispensed: 5 from 0, 5 from 39, £8 from £4
?plicate 1 Time: 89:16
»ak Area (A-s): -8.881 Peak Height (A> : 8.888
jckground Pk Area (A-s): -8.881 Background Pk Height (ft): 8.886
:ank Corrected Pk Area (A-s): -8.881
mcentration (ug/L ): -8.4
. dispensed: 5 from 8, 5 from 39, £8 from £4
splicate £ (Peak Stored) Time: 89:19
>ak Area (A-s): -8.888 Peak Height (A): 8.888
\ckground Pk Area (A-s): -8. 88£ Background Pk Height (A): 8.885
ank Corrected Pk Area (A-s): 8.881
mcentration (ug/L ): 8.4
•an Cone (ug/L ): 8.8 SD : 8.53 RSDC/O: £878.85
A*A/A*A/A/A*A*A^
ID: CCV=68ug/L Seq. No. : 88838 A/S Po's. : 5 Date: 18/31/97
. dispensed: 5 from 8, 5 from 39, £8 from 5
plicate 1 Time: 89 : ££
ak Area (A-s): 8.888 Peak Height (A): 8.145
.ckground Pk Area (A-s): 8.849 Background Pk Height (A): 8.891
ank Corrected Pk Area (A-s): 8.881
ncentration (ug/L ): 54.5
dispensed: 5 from 8, 5 from 39, £8 from 5
plicate £ (Peak Stored) Time: 89:£5
ak Area (A-s): 8.891 Peak Height (A): 8.148
ckground Pk Area (A-s): 8.855 Background Pk Height (A): 8.894
ank Corrected Pk Area (A-s): 8. 89£
ncentration (ug/L ): 61.6
an Cone (ug/L ): 58.8 SD : 5.81 RSD(%): 8.64
: sample is within range 48.8 - 7£. 8
ID: CCB Seq. No. : 88839 A/S Pos. : 8 Date: 10/31/97
dispensed: 5 from 8, 5 from 39, £8 from 8
plicate 1 Time: 89:£8
ak Area (A-s): 8.888 Peak Height (A): 8.806
ckground Pk Area (A-s): -8. 88£ Background Pk Height (A): 8.885
ank Corrected Pk Area (A-s): 8.881
ncentration (ug/L ): 8.7
dispensed: 5 from 8, 5 from 39, £8 from 8
plicate £ (Peak Stored) Time: 89:31
ak Area (A-s): -8. 88£ Peak Height (A): 8.885
ckground Pk Area (A-s): 8.883 Background Pk Height (A): 8.888
ank Corrected Pk Area (A-s): -8.881
ncentration (ug/L ): -8.9
129
-------
QC sample is within range -£. 0 - 2. ©
130
-------
Height File: AB826.IOH
pie Volume: 100 il
t: D.STREETER-EOHARDS
Nonnal Weight: 1.0 g
oc.
Saiple ID
Height
Dilution
ST BLANK
ST01:0.2ug/L
ST02=0.5ug/L
STD3=1.0ug/L
STD4:2.0ug/l
STD5:5.0ug/L
ST06:10.0ug/L
ICV:4.0ug/L
ICB
CHECK LO
43411 MB1
43411 MB1 D
43411 LCS1
43411 LCS1D
184-84-ICA8
184-84-1CAB D
184-84-1DE
184-84-1DE D
184-84-10E MS
184-84-1DE MSD
CCVl=6.0ug/L
CCB1
184-84-1F
184-84-1F 0
184-84-16
184-84-16 D
184-84-1H
184-84-1H 0
184-84-2CAB
184-84-2CAB D
184-84-2F
184-84-2F D
CCV2=6.0ug/L
CCB2
184-84-20E
184-84-2DE D
184-34-2DE MS
184-84-2DE MSD
184-84-26
184-84-26 D
184-84-2H
184-84-2H D
184-84-3CA8
184-84-3CAB D
CCV3:6.0ug/L
CCB3
184-84-3DE
184-84-3DE D
184-84-3F
184-84-3F D
184-84-36
184-84-36 D
184-84-3H
184-84-3H D
—^ 3-osu-? ftSe 10
131
-------
Loc.
Saiple ID
Height
Dilution
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
69
70
71
72
73
74
75
76
77
78
79
184-84-4CA8
184-84-4CAB D
CCV4:6.0ug/L — ^ 3-022-tf
CCB4
184-84-4D
184-84-40 D
184-84-40 HS
184-84-4D HSD
184-84-4E
184-84-4E D
184-84-4F
184-84-4F D
184-84-5CAB
184-84-5CAB 0
CCV5:6.0ug/L ^3-033l-£ N
CCB5 '
184-84-580 "X
184-84-5BO 0
184-84-5E V v.l \^
184-84-5E 0 /• U^'
184-S4-5F I p-'f^
184-84-5F D L PC^l*
184-54-5GF OUUL/TO vV
184-84-56F D
CCV6:6.0ug/L j
CCB6
\o
132
-------
tent File: H6..MEL
lent: Hg2
it Data: Main+Suppl.
it: Calib. Curve
rks:
.NDARDS: 3-023-3
3-022-8
RUMENT: 5100
length: 253.7 Peak
al Type: AA
Tine: 30.0
le Replicates: 1
dard Replicates: 1
Analyst: 0 STREETER-EDHAROS
Peak Storage: None
Technique: MHS Version: 7.01
Slit: 0.7 Low
Signal Measurement: Peak Height (5)
Read Delay: 1.0 80C Tine: 2
E:
e Type:
ant Flow
BRATION:
utions
K Bl 3nL>
U . o lanK
dard 1
dard 2
dard 3
dard 4
dard 5
dard 6
ibration
ibration
Air
: 10.0 L/min
: 10
i
!
t CTfi Dl K
( Of U DLft
ISTD i
iSTD 2
ISTD 3
ISTD 4
ISTD 5
ISTD 6
Units: ug/l
Type: Linear
Flame Sensor
Fuel Flow: 2
Cone |
t
t
i
0.200;
0.500|
}.000|
2.0001
5.000,'
10.000;
Saaple Units
: On
.0 L/ain
: ug/l
ix Check Calculations:
fference for Dupls: No Locations:
covery for Spike: No Locations:
Cone:
133
-------
Element File: H6..HEL Eleient: Hg2
Date: 10/20/97 TIM: 12:48
Data File: AB826.DAT ID/Ht File: AB826.IDH
Technique: HHS Calib. Type: Linear
fieiark 1: STAHDARDS= 3-023-3
Reaark 2: QC= 3-022-8
Wavelength: 253.?
Slit: 0.7 L
Laip Current: 0
Energy: 71
Hg2 ID: ST BLANK
Seq. Ho.: 00001 A/S Pos.: -- Date: 10/20/97
Replicate 1 Tiie: 12:4°
Peak Area (A-s): 0.007 Peak Height (A): -0.000
Blank Corrected Pk Height (A): -0.000
Concentration (ug/L ): -0.002
Auto-zero perforied.
Hg2 ID: STDl=0.2ug/L
Seq. No.: 00002 A/S Pos.: - Date: 10/20/9^
Replicate 1 Tine: 12:53
Peak Area (A-s): 0.329 Peak Height (A): 0.014
Blank Corrected Pk Height (A): 0.014
Concentration (ug/L ): 0.228
Standard number 1 applied. [0.200]
Correlation coefficient: 1.00000 Slope: 0.0712
Hg2 ID: STD2:0.5ug/L Seq. No.: 00003 A/S Pos.: - Date: 10/20/9'
Sample abs. is greater than that of the largest standard.
Replicate 1 Tine: 12:54
Peak Area (A-s): 0.794 Peak Height (A): 0.034
Blank Corrected Pk Height (A): 0.034
Concentration (ug/L ): 0.476
Standard nunber 2 applied. [0.500]
Correlation coefficient: 0.99904 Slope: 0.0683
Hg2 ID: ST03=l.Oug/L Seq. No.: 00004 A/S Pos.: - Date: 10/20/97
Saiiple abs. is greater than that of the largest standard.
Replicate 1 Ti"e: 12:5S ,
Peak Area (A-s): 1.584 Peak Height (ft): 0.068
Blank Corrected Pk Height (A): 0.068
Concentration (ug/L ): 0.991
Standard nuaber 3 applied. [1.000]
Correlation coefficient: 0.99984 Slope: 0.0679
Hg2 ID: STD4:2.0ug/L Seq. No.: 00005 A/S Pos.: -- Date: 10/20/97
Saiple abs. is greater than that of the largest standard.
Replicate 1 Tiie: 12:57
Peak Area (A-s): 3.128 Peak Height (A): 0.136
134
-------
e.ntration (ug/L ): 2.009
dard number 4 applied. [2.000]
elation coefficient: 0.99997
Slope: 0.0681
ID: STD5=5.0ug/L
Seq. No.: 00006 A/S Pos.: - Date: 10/20/97
le abs. is greater than that of the largest standard.
icate 1 Tiie: 12:58
Area (A-s): 7.826 Peak Height (A): 0.341
k Corrected Pk Height (A): 0.341
entration (ug/L ): 5.009
dard number 5 applied. [5.000]
elation coefficient: 1.00000 Slope: 0.06S2
10: STD6:10.0ug/L Seq. No.: 00007 A/S Pos.: -- Date: 10/20/9'
le abs. is greater than that of the largest standard.
icate 1 Time: 12:59
Area (A-s): 15.110 Peak Height (A): 0.633
k Corrected Pk Height (A): 0.633
entration (ug/L ): 9.282
dard number 6 applied. [10.000]
elation coefficient: 0.99907 Slope: 0.0645
135
-------
tieient me: HG..nEL Eleient: Hg2
Date: 10/20/97 Tiie: 13:00
Data File: AB826.DAT ID/Ht File: A8826.IDH
Technique: MHS Calib. Type: Linear
Reiark 1: STANDARDS: 3-023-3
Reiark 2: QC= 3-022-8
Havelength: 253.7
Slit: 0.7 L
Laip Current: 0
Energy: 71
H
Display Calibration - C;\fflJJSER\MJ ILES\ELEHEHT\H6_.HEL
0.633,
Linear
Com. Cocf.: B.999B7
Slope: 8.8645
Concentration
1B.BB8
136
-------
nent File: H6..HEL Eleient: Hg2
:e: 10/20/97 Tile: 13:03
:a File: A8826.DAT ID/Ht File: AB826.IDW
Unique: NHS Calib. Type: Linear
lark 1: STANDARDS: 3-023-3
:ark 2: QC= 3-022-8
Wavelength: 253.7
Slit: 0.7 L
Laip Current: 0
Energy: 71
ID: ICV:4.0ug/L
Seq. Ho.: 00008 A/S Pos.: -- Date: 10/20/97
licate 1 Tiie: 13:06
k Area (A-s): 6.250 Peak Height (A): 0.266
nk Corrected Pk Height (A): 0.266
'centration (ug/L ): 4.123
ID: IC8
Seq. No.: 00009 A/S Pos.: -- Date: 10/20/97
licate 1 Tine: 13:08
< Area (A-s): 0.023 Peak Height (A): 0.001
ik Corrected Pk Height (A): 0.001
:entration (ug/L ): 0.017
Seq. No.: 00010 A/S Pos.: -- Date: 10/20/9"
ID: CHECK LO
,icate 1
; Area (A-s): 0.338
ik Corrected Pk Height (A): 0.014
:entration (ug/L ): 0.224
Tine: 13:09
Peak Height (A); 0.014
ID: 43411 M81
Seq. No.: 00011 A/S Pos.: - Date: 10/20/9"
icate 1 Tine: 13:12
Area (A-s): 0.006 Peak Height (A): 0.000
k Corrected Pk Height (ft): 0.000
entration (ug/L ): 0.006
ID: 43411 M81 D
Seq. Ho.: 00012 A/S Pos.: -- Date: 10/20/97
icate 1
Area (A-s): 0.011
k Corrected Pk Height (A): 0.000
entration (ug/L ): 0.006
Time: 13:13
Peak Height (A): 0.000
ID: 43411 LCS1
Seq. No.: 00013 A/S Pos.: -- Date: 10/20/97
Tine: 13:14
Peak Height (A): 0.
icate 1
Area (A-s): 4.411
( Corrected Pk Height (A): 0.185
jntration (ug/L ): 2.868
ID: 43411 LCS1D
. No.: 00014 A/S Pos.: -- Date: 10/20/97
137
-------
Peak Area (A-s): 0.149
Blank CorrectedPkej
Height (A): 0.009
: 0.140
Hg2 ID: 43411 LCS1
Seq. No.: 00015 A/S Pos.: -- Date: 10/20/97
Replicate 1 Tiie: 13:22
Peak Area (A-s): 7.518 Peak Height (A): 0.323
Blank Corrected Pk Height (A): 0.323
Concentration (ug/L ): 5.006
Hg2 ID:
Replicate 1 Time: 13:34
Peak Area (A-s): 8.571 Peak Height (A): 0.359
Blank Corrected Pk Height (A): 0.359
Concentration (ug/L ): 5.563
Hg2 ID: 43411 LCS1D
Seq. No.: 00019 A/S Pos.: - Date: 10/20/9'
Replicate 1 Time: 13:44
Peak Area (A-s): 7.427 Peak Height (A): 0.316
Blank Corrected Pk Height (A): 0.316
Concentration (ug/L ): 4.900
ftfcC
Hg2 ID: 43411 LCS1D
Replicate 1
Peak Area (A-s): o'.274
Blank Corrected Pk Height (A): 0.014
Concentration (ug/L ): 0.215
Tine: 13:23
Peak Heigh
Date: 10/20/9"
Hg2 ID: 43411 LCS1D
Seq. No.: 00017
Replicate 1
Peak Area (AX: 0.166
Tine: 13:30
Peak Height (A): 0.008
Blank Cprfected Pk Height (A): 0.008
Concsfitration (ug/L ): 0.120
ec. No.: 00018 A/S Pos.: --
Oats:. 10/20/9
Seq. No.: 00020 A/S Pos,: -- . Date: 10/20/9r
Hg2 ID: 184-84-
Replicate 1 Tise: 13:45
Peak Area (A-s): 0.026 Peak HeighrM: '0.001
Blank Corrected Pk Height (A): 0.001
Concentration (ug/L ): 0.022
Hg2 ID: 184-84-ltAfrD Seq. No.: 00021 A/S Pos.: - Date: 10/20/9?
Replicate 1 Tiie: 13:46
Peak Area (A-s): 0.011 Peak Height (A): 0.000
Blank Corrected Pk Height (A): 0.000
138
-------
I ID: 184-84-1DE
Seq. No.: 00022 A/S Pos.: -- Date: 10/20/97
Jlicate 1 Tine: 13:47
ik Area (A-s): 0.027 Peak Height (A): 0.001
ink Corrected Pk Height (ft): 0.001
tcentration (ug/L ): 0.016
ID: 184-84-1DE D
Seq. No.: 00023 A/S Pos.: -- Date: 10/20/97
licate 1 Tiie: 13:48
k Area (A-s): 0.022 Peak Height (A): 0.001
nk Corrected Pk Height (A): 0.001
centration (ug/L ): 0.020
ID: 184-84-1DE MS Seq. No.: 00024 A/S Pos.: -- Date: 10/20/97
licate 1 Tine: 13:50
k Area (A-s): 4.055 Peak Height (A): 0.163
nk Corrected Pk Height (A): 0.163
centration (ug/L ): 2.521
ID: 184-84-1DE USD Seq. No.: 00025 A/S Pos.: - Date: 10/20/9'
licate 1 Time: 13:51
k Area (A-s): 3.961 Peak Height (A): 0.163
nk Corrected Pk Height (A): 0.163
:entration (ug/L ): 2.532
licate 1
< Area (A-s): 0.114
ik Corrected Pk Hei
ID: CCVU6.0ug/L
Seq. No.: 00027 A/S Pos.: - Date: 10/20/97
.icate 1 Time: 13:53
; Area (A-s): 8.003 Peak Height (A): 0.336
tk Corrected Pk Height (A): 0.336
:entration (ug/L ): 5.216
ID: CC81
icate 1
Area (A-s): 0.019
k Corrected Pk Height (A): 0.001
entration (ug/L ): 0.016
Seq. No.: 00028 A/S Pos.: -- Date: 10/20/97
Tiie: 13:55
Peak Height (A): 0.001
139
-------
Hg2 ID: 184-84-1F
Replicate 1
Peak Area (A-s): 0.025
Blank Corrected Pk Height (A): 0.001
Concentration (ug/L ): 0.019
Seq. No.: 00029 A/S Pos.: - Date: 10/20/97
Tiie: 13:56
Peak Height (A): 0.001
Hg2 ID: 184-8MF D Seq. No.: 00030 A/S Pos.: -- Date: 10/20/97
Replicate 1 Ti»e: 13:57
Peak Area (A-s): 0.021 Peak Height (A): 0.001
Blank Corrected Pk Height (A): 0.001
Concentration (ug/L ): 0.012
Hg2 ID: 184-84-1G Seq.-No.: 00031 A/S Pos.: -- Date: 10/20/97
Replicate 1 Tine: 13:58
Peak Area (A-s): 0.112 Peak Height (A): 0.005
Blank Corrected Pk Height (A): 0.005
Concentration (ug/L ): 0.070
Hg2 ID: 184-84-1G D Seq. No.: 00032 A/S Pos.: -- Date: 10/20/97
Replicate 1 Time: 13:59
Peak Area (A-s): 0.115 Peak Height (A): 0.005
Blank Corrected Pk Height (fl): 0.005
Concentration (ug/L ): 0.072
Hg2 ID: 184-84-1H Seq. No.: 00033 A/S Pos.: -- Date: 10/20/97
Replicate 1 Tine: 14:00
Peak Area (A-s): 0.016 Peak Height (A): 0.001
Blank Corrected Pk Height (A): 0.001
Concentration (ug/L ): 0.011
Hg2 ID: 184-84-1H D Seq. No.: 00034 A/S Pos.: -- Date: 10/20/97
Replicate 1 Tine: 14:01
Peak Area (A-s): 0.005 Peak Height (A): 0.000
Blank Corrected Pk Height (A): 0.000
Concentration (ug/L ): 0.002
" ~" ---!-.-.-.-.--
Hg2 ID: 184-84-2SA6- Seq. No.: 00035 A/S Pos,: -- Date: 10/20/97
^ iv*-iite
Replicate I Tiie: 14:02
Peak Area (A-s): -0.000 Peak Height (ft): Q.QOO
Blank Corrected Pk Height (A): 0.000
Concentration (ug/L ): 0.006
f fee. <«r .0-3141««
Hg2 10: 184-84-2SA6 D Seq. No.: 00036 A/S Pos.: -- Date: 10/20/97
140
-------
^ Hiea
-u.uvi
neiyiu \nj. -v.uuv
nk' Corrected Pk Height (A): -0.000
centration (ug/L ): -0.002
ID: 184-84-2F
Seq. No.: 00037 A/S Pos.: -- Date: 10/20/97
licate 1 Tiie: 14:04
k Area (A-s): -0.001 Peak Height (A): 0.000
nk Corrected Pk Height (A): 0.000
:entration (ug/L ): 0.000
ID: 184-84-2F D
licate 1
< Area (A-s): 0.000
ik Corrected Pk Height (A): 0.000
rentration (ug/L ): 0.000
Seq. No.: 00038 A/S Pos.: -- Date: 10/20/97
Tiie: 14:06
Peak Height (A): 0.000
ID: CCV2:6.0ug/L
Seq. No.:
A/S Pos.: -- Date: 10/20/97
iicate 1
( Area (A-s):
ik Corrjfrt^Pk Height (A): 0.017
rttion (ug/L ): 0.263
Time: 14:06
Peak Height (A): 0.017
ID:
Seq. No.: 00040 A/S Pos.: - Date: 10/20/9'
.icate 1 Time: 14:08
; Area (A-s): 8.437 Peak Height (A): 0.354
ik Corrected Pk Height (ft): 0.354
:entration (ug/L ): 5.493
ID: 444
Seq. No.: 00041 A/S Pos.: -- Date: 10/20/97
.icate 1 " ' Time: 14:10
; Area (A-s): 0.014 Peak Height (A): 0.001
ik Corrected Pk Height (A): 0.001
:entration (ug/L ): 0.012
ID: 184-84-2DE
icate 1
Area (A-s): 0.030
ik Corrected Pk Height (A): 0.001
entration (ug/L ): 0.019
Seq. No.: 00042 A/S Pos.: - Date: 10/20/9'
Time: 14:14
Peak Height (A): 0.001
Seq. No.: 00043 A/S Pos.: -- Date: 10/20/97
ID: 184-84-2DE D
icate 1
Area (A-s): 0.031
k Corrected Pk Height (A): 0.001
Tine: 14:15
Peak Height (A): 0.001
141
-------
Hg2 ID: 184-84-2DE HS Seq. No.: 00044 A/S Pos.: - Date: 10/20/97
Replicate 1 Tiie: 14:16
Peak Area (A-s): 4.500 Peak Height (A): 0.189
Blank Corrected Pk Height (A): 0.189
Concentration (ug/L ): 2.922
^M****^****!********'**^!*******************^****^**^*^'************'*****'*'*'***'**'*****'**
Hg2 ID: 184-84-2DE HSD Seq. No.: 00045 A/S Pos.: -- Date: 10/20/97
Replicate 1 Tiie: 14:17
Peak Area (A-s): 4.192 Peak Height (A): 0.175
Blank Corrected Pk Height (A): 0.175
Concentration (ug/L ): 2.720
Hg2 ID: 184-84-26 Seq. No.: 00046 A/S Pos.: -- Date: 10/20/97
Replicate 1 Tine: 14:17
Peak Area (A-s): 0.033 Peak Height (A): 0.002
Blank Corrected Pk Height (A): 0.002
Concentration (ug/L ): 0.033
Hg2 ID: 184-84-2G D Seq. No.: 00047 A/S Pos.: - Date: 10/20/97
Replicate 1 Time: 14:18
Peak Area (A-s): 0.145 Peak Height (A): 0.006
Blank Corrected Pk Height (ft): 0.006
Concentration (ug/L ): 0.093
«**•>***« *
-------
icate 1 Tiie: 14:22
Area (A-s): 0.008 Peak Height (A): 0.001
k Corrected Pk Height (A): 0.001
entration (ug/L ): 0.008
ID: CCV3:6.0ug/L Seq. No.: 00052 A/S Pos.: - Date: 10/20/97
icate 1 Tiie: 14:23
Area (A-s): 9.918 Peak Height (A): 0.411
k Corrected Pk Height (A): 0.411
entration (ug/L ): 6.372
ID: CCB3 Seq. No.: 00053 A/S Pos.: -- Date: 10/20/97
icate 1 Tine: 14:24
Area (A-s): 0.040 Peak Height (A): 0.002
k Corrected Pk Height (A): 0.002 • .
sntration (ug/L ): 0.026
ID: 184-84-3DE Seq. No.: 00054 A/S Pos.: - Date: 10/20/97
icate 1 Time: 14:25
Area (A-s): 0.035 Peak Height (A): 0.002
< Corrected Pk Height (A): 0.002
;ntration (ug/L ): 0.025
ID: 184-84-3DE D Seq. No.: 00055 A/S Pos.: -- Date: 10/20/97
icate 1 Tine: 14:26
Area (A-s): 0.027 Peak Height (A): O.OOi
< Corrected Pk Height (A): 0.001
;ntration (ug/L ): 0.014
ID: 184-84-3F Seq. No.: 00056 A/S Pos.: - Date: 10/20/97
icate I Tine: 14:27
Area (A-s): 0.008 Peak Height (A): 0.001
< Corrected Pk Height (A): 0.001
sntration (ug/L ): 0.012
ID: 184-84-3F D Seq. No.: 00057 A/S Pos.: -- Date: 10/20/97
.cate 1 Tine: 14:29
Area (A-s): 0.008 Peak Height (A): 0.000
; Corrected Pk Height (A): 0.000
intration (ug/L ): 0.006
ID: 184-84-36
Seq. No.: 00058 A/S Pos.: -- Date: 10/20/97
143
-------
oionn vuiiobtcu ri\ nciynu \n i, v.vv/
Concentration (ug/L ): 0.107
Hg2 ID: 184-84-36 0 Seq. No.: 00059 A/S Pos.: -- Date: 10/20/97
Replicate 1 Tiie: 14:31
Peak Area (A-s): 0.157 Peak Height (A): 0.007
Blank Corrected Pk Height (A): 0.007
Concentration (ug/L ): 0.106
Hg2 ID: 184-84-3H Seq. No.: 00060 A/S Pos.: -- Date: 10/20/97
Replicate 1 Tiie: 14:32
Peak Area (A-s): 0.026 Peak Height (A): 0.001
Blank Corrected Pk Height (A): 0.001
Concentration (ug/L ): 0.016
Hg2 ID: 184-84-3H D Seq. No.: 00061 A/S Pos.: -- Date: 10/20/97
Replicate 1 Time: 14:33 . •• •
Peak Area (A-s): 0.026 Peak Height (A): 0.001
Blank Corrected Pk Height (A): 0.001
Concentration (ug/L ): 0.019
Hg2 ID: ^^^CA^^^Se^. No.: 00062 A/S Pos.: -- Date: 10/20/97
Replicate 1 Tine: 14:34
Peak Area (A-s): 0.101 Peak Height (A): 0.004
Blank Corrected Pk Height (A): 0.004
Concentration (ug/L ): 0.059
iw:
Hg2 ID: 184-84-4CAfrD Seq. No.: 00063 A/S Pos.: -- Date: 10/20/97
Replicate 1 Tine: 14:35
Peak Area (A-s): 0.096 Peak Height (A): 0.004
Blank Corrected Pk Height (A): 0.004
Concentration (ug/L ): 0.062
Hg2 ID: CCV4=6.0ug/L Seq. No.: 00064 A/S Pos.: -- . Datfi: 10/20/9'
Replicate 1 Tine: 14:37
Peak Area (A-s): 8.394 Peak Height (A): 0.359
Blank Corrected Pk Height (A): 0.359
Concentration (ug/L ): 5.558
Hg2 ID: CCB4
Seq. No.: 00065 A/S P
-------
2 . ID: 184-84-4D
plicate 1
ak Area (A-s): 0.045
ank Corrected Pk Height (A): 0.002
ncentration (ug/L ): 0.026
Seq. No.: 00066 A/S Pos.: - Date: 10/20/97
Tiie: 14:39
Peak Height (A): 0.002
2 ID: 184-84-40 D • Seq. Ho.: 00067 A/S Pos.: -- Date: 10/20/97
plicate 1 Ti»e: 14:40
ak Area (A-s): 0.030 Peak Height (A): 0.001
ank Corrected Pk Height (A): 0.001
ncentration (ug/L ): 0.016
I ID: 184-84-4D MS Seq/ No.: 00068 A/S Pos.: - Date: 10/20/97
jlicate 1 Tine: 14:41
ik Area (A-s): 4.079 Peak Height (A): 0.168
ank Corrected Pk Height (A): 0.168
icentration (ug/L ): 2.599
I ID: 184-84-4D USD Seq. No.: 00069 A/S Pos.: -- Date: 10/20/97
Jlicate 1 Time: 14:42
Jk Area (A-s): 4.112 Peak Height (A): 0.170
ink Corrected Pk Height (A): 0.170
icentration (ug/L ): 2.631
1 ID: 184-84-4E Seq. No.: 00070 A/S Pos.: - Date: 10/20/97
licate 1 Tine: 14:43
k Area (A-s): 0.096 Peak Height (A): 0.004
nk Corrected Pk Height (A): 0.004
centration (ug/L ): 0.061
ID: 184-84-4E D Seq. No.: 00071 A/S Pos.: - Date: 10/20/97
licate 1 Time: 14:44
k Area (A-s): 0.073 Peak Height (A): 0.003
nk Corrected Pk Height (A): 0.003
centration (ug/L ): 0.048
ID: 184-84-4F
licate 1
( Area (A-s): 0.010
ik Corrected Pk Height (A): 0.001
:entration (ug/L ): 0.011
Seq. No.: 00072 A/S Pos.: -- Date: 10/20/97
Tine: 14:45
Peak Height (A): 0.001
145
-------
Peak 'Area (A-s): 0.006 Peak Height (A): 0.001
Blank Corrected Pk Height (A): 0.001
Concentration (ug/L ): 0.012
-
Hg2 ID: 184-84-5CW ^...^Se^. Ho.: 00074 A/S Pos.: -• Date: 10/20/97
Replicate 1 Tiie: 14:47
Peak Area (A-s): 0.004 Peak Height (A): 0.000
Blank Corrected Pk Height (A): 0.000
Concentration (ug/L ): 0.005
,«.«,.^^...,.««...,^^.^^.
Hg2 ID: 184-84-5CA6 D Seq. No.: 00075 A/S Pos.: - Date: 10/20/97
Replicate 1 Tine: 14:49
Peak Area (A-s): 0.001 " Peak Height (A): 0.000
Blank Corrected Pk Height (A): 0.000
Concentration (ug/L ): 0.002
Hg2 ID: CCV5:6.0ug/L Seq. No.: 00076 A/S Pos.: -- Date: 10/20/97
Replicate 1 Time: 14:50
Peak Area (A-s): 8.459 Peak Height (A): 0.354
Blank Corrected Pk Height (A): 0.354
Concentration (ug/L ): 5.495
Hg2 ID: CCB5 Seq. No.: 00077 A/S Pos.: -- Date: 10/20/97
Replicate 1 Tine: 14:51
Peak Area (A-s): 0.029 Peak Height (A): 0.001
Blank Corrected Pk Height (A): 0.001
Concentration (ug/L ): 0.017
Hg2 ID: 184-84-5BD Seq. No.: 00078 A/S Pos.: -- Date: 10/20/97
Replicate 1 Time: 14:52
Peak Area (A-s): 0.014 Peak Height (A): O.OOi
Blank Corrected Pk Height (A): 0.001
Concentration (ug/L ): 0.012
Hg2 ID: 184-84-5BD D Seq. No.: 00079 A/S Pos.: - Date: 10/20/97
Replicate 1 Tiie: 14:53
Peak Area (A-s): 0.006 Peak Heighf{A): 0.00.
Blank Corrected Pk Height (A): 0.001
Concentration (ug/L ): 0.009
Hg2 ID: 184-84-5E Seq. No.: 00080 A/S Pos.: - Date: 10/20/97
Replicate 1
Tiie: 14:55
n..t. It*. £ _L A / A
146
-------
I ID: 184-84-5E D Seq. No.: 00081 A/S Pos.: - Date: 10/20/97
)licate 1 Tiae: 14:56
ik Area (A-s): -0.003 Peak Height (A): -0.000
ink Corrected Pk Height (A): -0.000
icentration (ug/L ): -0.002
! ID: 184-84-5F Seq. No.: 00082 A/S Pos.: -- Date: 10/20/97
>licate 1 Tine: 14:57
•.k Area (A-s): -0.001 Peak Height (A): -0.000
ink Corrected Pk Height (A): -0.000
centration (ug/L ): -0.003
ID: 184-84-5F D Seq. No.: 00083 A/S Pos.: - Date: 10/20/97
•licate 1 Tine: 14:58
k Area (A-s): 0.000 Peak Height (A): 0.001
nk Corrected Pk Height (A): 0.001
centration (ug/L ): 0.008
ID: 184-84-5GF Seq. No.: 00084 A/S Pos.: -- Date: 10/20/9*
licate 1 Tine: 14:59
k Area (A-s): 0.036 Peak Height (A): 0.002
nk Corrected Pk Height (A): 0.002
centration (ug/L ): 0.026
ID: 184-84-5GF D Seq. No.: 00085 A/S Pos.: -- Date: 10/20/9"
licate 1 Time: 15:00
k Area (A-s): 0.015 Peak Height (A): 0.001
nk Corrected Pk Height (ft): 0.001
centration (ug/L ): 0.008
ID: CCV6:6.0ug/L Seq. No.: 00086 A/S Pos.: -- Date: 10/20/9"
licate 1 Tine: 15:01
k Area (A-s): 6.713 Peak Height (A): 0.284
nk Corrected Pk Height (ft): 0.284
centration (ug/L ): 4.407
ID: CCV6:6.0ug/L Seq. No.: 00087 A/S Pos.: - Date: 10/20/97
licate 1 Tine: 15:06
k Area (A-s): 5.871 Peak Height (A): 0.254
nk Corrected Pk Height (A): 0.254
:entration (ug/L ): 3.932
147
-------
Replicate 1 Tiie: 15:17
Peak Area (A-s): 5.836 Peak Height (A): 0.263
Blank Corrected Pk Height (A): 0.263
Concentration (ug/L ): 4.073
Hg2 ID: CCB6 Seq. No.: 00089 A/S Pos.: - Date: 10/20/97
Replicate 1 Tiie: 15:19
Peak Area (A-s): -0.006 Peak Height (A): -0.000
Blank Corrected Pk Height (A): -0.000
Concentration (ug/L ): -0.002
148
-------
(eight File: A8827.IDH Analyst: O.STREETER-EOHARDS
>le Volune: 100 iL Noninal Weight: 1.0 g
>c. Saaple ID " Weight Dilution
0 ST 81K
1 8101:0.2119/1^
2 STD2:0.5ug/L
3 STD3--1.0ug/L \^
4 5TD4:2.0ug/L f
5 STD5:5.0ug/l I
6 5T06:lO.Oug/L 1
7 ICV:4.0ug/l IL__ 1 625-b KG
8 .IC8
9 CHECK LO
0 43411 M82
1 43411 M820
2 43411 LCS2.
3 43411 LCS2D
4 184-84-6CA8
5 184-84-6CAB D
6 184-34-60
7 184-84-60 D
8 184-34-60 MS ,-•;'. ••' ; ',
9 184-84-60 USD
0 CCV7:6.0ug/L 3-033-C*
1 CCB
2 134-S4-6G
3 184-34-6G D
4 1S4-34-5E
5 184-34-6E D
5 184-34-oF
7 184-84-6F D
3 1S4-34-7CDA8
9 184-84-7COAB D
) 184-34-7G
1 134-84-7G D
I CCVS:6.0ug/L
i CCB
< 1S-1-84-7EF
5 184-84-7EF D
5 184-84-7EF MS
1 1S4-84-7EF MSD
3 184-34-7H
» 184-84-7H D
) 184-34-71
I 184-84-71 D
I CCV9:6.0ug/L —
i 43377 MSI
t 43377 M81 D
i 43377 LCS1
. 43377 LCS10
184-50-1CAB
! 184-50-1CA8 0
184-50-10
184-50-10 D
184-50-10 MS
184-50-10 MSO
CCVl:6.0ug/L —
149
-------
Loc. Saiple ID Weight . Dilution
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
69
70
71
72
73
74
75
76
77
73
79
SO
81
32
83
84
85
86
87
88
89
90
91
92
93
94
95
96
97
93
99
100
101
102
103
104
105
106
107
108
109
CCS ' -
184-50-1E
184-50-1E 0
184-50-1F
184-50-1F 0
184-50-16
184-50-1G 0
184-50-2CA8
184-50-2CA8 0
184-50-20E
184-50-20E 0
CCV2=6.0ug/L —3-Ofo-b "Kf lo
CC8
184-50-2F
184-50-2F 0
184-50-26 '
184-50-26 D
184-50-2H
184-50-2H 0
184-50-30E
184-50-30E 0
184-50-30E MS
184-50-30E MSO
CCV3:6.0ug/L 3-6^3-U fr5E 1
CCS
184-50-3CAB
1S4-50-3CA8 0
184-50-3F
184-50-3F 0
184-50-36
134-50-3G 0
184-50-3H
184-50-3H D
184-50-4CA8
184-50-4CA8 0
CCV4:6.0ug/l 3-0^3-1(2. D5€
CCS
184-50-4DE
184-50-40E 0
184-50-4DE MS
184-50-40E HSO
184-50-4F
184-50-4F 0
184-50-46
134-50-46 D
184-50-4H
184-50-4H 0
CCV5=6.0ug/L - 3_x*o.?/
pro ^ ~" O (A jrty
w WL
184-50-5CA8
184-50-5CA8 0
184-50-580
184-50-5BD D
184-50-5E
184-50-5E D
184-50-5F
150
-------
Sanole ID Weight Dilution
0 184-50-5F D
1 184-50-6CAB
2 184-50-6CAB D
3 CCV6:6.0ug/L
4 CCS
151
-------
Eleneat: Hg2
Print Data: Main+Suppl.
Print: Calib. Curve
Resarks:
STANDARDS: 3-023-5
QC: 3-023-4.1,
INSTRUMENT: 5100
Wavelength: 253.7 Peak
Signal Type: AA
Read Time: 30.0
Sanple Replicates: 1
Standard Replicates: 1
Calibration Type: Linear
QC:
Matrix. Check Calculations:
% Difference for Dupls: No
* Recovery for Spike: No
Analyst: 0 3TREETER-EDHAROS
Peak -Storaae: Hone
Technique: MHS Version: 7.01
Slit: 0.7 Low
Signal Measurement: Peak Height (5)
Read Delay: 1.0 BOC Tine: 2
FLAME:
Flaae Type:
Oxidant Flow
CALIBRATION:
Solutions
Calib. Blank
Standard 1
Standard 2
Standard 3
Standard 4
Standard 5
Standard o
Calibration
Air
: 10.0 L/nin
1 ID
, i IU Olr\
ISTD i
ISTD 2
ISTD 3
ISTD 4
ISTD 5
ISTO 6
Units: ug/L
Flame Sensor
Fuel Flow: 2
Cone |
1
1
0.2001
0.5001
1.0001
2.0001
5.000',
10.000,'
Sample Units
: On
.0 l/nin
: ug/L
Lo:a:ions:
Locations:
ujnc:
152
-------
lent File: HG..MEL Eleient: Hg? Wavelength: 253.
i: 10/21/97. . Tiie: 10:09 Slit: 0.7 L
File: AB827.DAT ID/Wt File: AB827.IDW La»p Current: 0
mique: MHS Calib. Type: Linear Energy: 71
.rk 1: STANDARDS: 3-023-5
,rk 2: QC: 3-023-4;o
ID: ST 8LK
Seq. Ho.: 00003 A/S Pos.: -- Date: 10/21/97
icate 1 Tine: 10:10
Area (A-s): -0.004 Peak Height (A): -0.000
k Corrected Pk Height (A): -0.000
entration (ug/L ):"-0.003
-zero performed.
ID: STDl:0.2ug/L
Seq. No.: 00004 A/S Pos.": -- Date: 10/21/9'
icate 1 Tine: 10:11
Area (A-s): 0.170 Peak Height (A!: 0.007
k Corrected Pk Height (A): 0.007
sntration (ug/L ): 0.107
jard number 1 apolied. [0.200]
slation coefficient: 1.00000 Slope: 0.054o
ID: 5TD2--0.5uo/L
Sea. No.: OCOOS A/£ Pos.: -- Date: 10/21/9'
le abs. is greater than that of the largest standarc.
icate 1 Tine: 10:12
Area (A-s): 0.395 Peak Height (A): 0.013
< Corrected Pk Height (A): O.Ole
antration (ug/L ): 0.525
Jard number 2 applied. [0.500]
elation coefficient: 0.99914 Slope: 0.0561
ID: STD3=1.0uo/L
Seq. No.: 00006 A/S Pos.: -- Date: 10/21/97
le abs. is greater than that of the largest standard.
icate 1 Tine: 10:13
Area (A-s): 0.878 Peak Height (A): 0.039
< Corrected Pk Height (A): 0.039
miration (ug/L ): 1.073
fard number 3_applied. [1.000]
ilation coefficient: 0.99824 Slope: 0.0382
ID: STD4:2.0ug/L
Seq. No.: 00007 A/S Pos.: -- Date: 10/21/9'
e abs. is greater than that of the largest standard.
cate 1 Ti«e: 10:15
Area (A-s): 1.761 Peak Height (A): 0.774
153
-------
Eleaent File: HG..MEL Eleunt: Hg2
Date: 10/21/97 - Tiae: 10:09
Data File: AB827.DAT ID/HI File: AB827.IDW
Technique: MHS lalib. Type: Linear
Reaark 1: STANDARDS: 3-023-5
Reaark 2: QC= 3-023-4,
Havelength: 253.
Slit: 0.7 L
Laap Current: 0
Energy: 71
Hg2 ID: ST BLK
Seq. No.: 00003 A/S Pos.: -- Date: 10/21/97
Replicate 1 Tiie: 10:10
Peak Area (A-s): -0.004 Peak Height (A): -0.000
Blank Corrected Pk Height (A): -0.000
Concentration (ug/L ): -0.003
Auto-zero perforaed.
Hg2 ID: STDl=0.2ug/l
Seq. No.: 00004 A/S Pos.: •-• Date:.10/21/r
Replicate 1 Time: 10:11
Peak Area (A-s): 0.170 Peak Height (A): 0.007
Blank Corrected Pk Height (A): 0.007
Concentration (ug/L ): 0.107
Standard number 1 applied. [0.200]
Correlation coefficient: 1.00000 Slope: 0.034o
Hg2 ID: 5102=0.5ug/L
Seq. No.: 00005 A/£ Pos.: - Oats: 10.'21'9'
Sample abs. is greater than that of the largest standard.
Replicate 1 Tine: 10:12
Peak Area (A-s): 0.395 Peak Height (A): 0.013
Blank Corrected Pk Height (A): O.Olc
Concentration (ug/L ): 0.525
Standard number 2 applied. [0.500]
Correlation coefficient: 0.99914 Slope: 0.036,
Hg2 ID: 5TD3=1.0ug/L
Seq. No.: 00006 A/S Pos.: -- Date: 10/21/97
Sarople abs. is greater than that of the largest standar:.
Replicate 1 Tine: 10:15
Peak Area (A-s): 0.878 Peak Height (A): 0.03?
Blank Corrected Pk Height (A): 0.039
Concentration (ug/L ): 1.073
Standard number 3 applied. [1.000]
Correlation coefficient: 0.99824 Slope: 0.038?
Hg2 ID: STD4:2.0ug/L Seq. No.: 00007 A/S Pos.: -- Date: 10/21/9"
Sasple abs. is greater than that of the largest standard.
Replicate 1 Tine: 10:15
Peak Area (A-s): 1.761 Peak Height (A): 0.074
154
-------
k.Corrected Pk Height !A): 0.074
entration i.ug/L ): 1.9*3
oara number 4 applied. [2.000]
elation coefficient: 0.99947 Slope: 0.0373
10: STD5:5.0ug/L S.eq. No.: 00003 A/S Pos.: -- Date: 10/21/97
le abs. is greater than that of the largest standard.
icate 1 Time: 10:16
Area (A-s): 4.444 Peak Height (A): 0..190
< Corrected Pk Height (A): 0.190
entration (ug/L ): 5.088
iard number 5 applied. [5.000]
ilation coefficient: 0.99989 Slope: 0.0379
ID: STD6:10.0ug/l Seq. No.: 00009 A/S Pos.: -- Date:" 10/21/9'
.e abs. is greater than that of the Urges: standard.
.cats 1 Time: 10:P
Area (A-s): 5.952 Peak Height (£j: 0.333
; Corrected Pk Height (A): 0.33S
mtration (ug/L ): 10.231
lard number 6 applied. [10.000]
ilation coefficient: 0.99389 Sloce: 0.0356
155
-------
Blank .Corrected Pk Height (A): 0.07*
Concentration i.ug/'l ): 1.943
Stanoan number 4 applied. [2.000]
Correlation coefficient: 0.99947 Slope: 0.0373
Hg2 10: 3105=5.Qug/l 5.eq. No.: 00003 A/S Pos.: - Date: 10/21/97
Sample abs. is greater than that of the largest standard.
Replicate 1 Tine: 10:16
Peak Area (A-s): 4.444 Peak Height (A): 0..190
Blank Corrected Pk Height (A): 0.190
Concentration (ug/L ): 5.088
Standard nunber 5 applied. [S.OOO]
Correlation coefficient: 0.99989 Slope: 0.0379
Hg2 ID: STD6:10.0ug/L Seq. No.: 0000? A/S Pos.: -- Date: 10/21/9'
Sample abs. is greater than that of the largest standard. v .
Reclicate 1 Tine: 10:1"
Peak Area (A-s): 8.952 ' Peak Height (A): 0.388
Blank Corrected Pk Height (A): 0.33E
Concentration (ug/L ): 10.231
Standard nunber 6 applied. [10.000]
Correlation coefficient: 0.99-5S9 Slooe: 0.0386
156
-------
ent File: HG..MEL Eleient: Hg2
: 10/21/97 ' Tine: 10:18
File: A6827.DAT 10/Wt File: A8827.IDW
nique: MHS Calib. Type: Linear
rk 1: STANDARDS: 3-023-5
Havelsngth: 253.7
Slit: 0.7 L
laup Current: 0
Energy: 71
M Display Calibration - C:\AAJSER\flflJILES\ELEMENT\HG_.MEL
0.388-,
B"
xx""x
^X^
x
jgf Linear
rgS S4 Corr. Coef.: B. 99989
C70o7s3 Slope: 8,8386
Pr~ Concentration 1B.BBB
4
5j
157
-------
Element File: H6..HEL Eleient: Hg2
Date: 10/21/97 . Tiie: 10:19
Data File: AB827.DAT I0/Ht File: A8827.IDW
Technique: MHS .Calib. Type: Linear
Renark 1: STANDARDS: 3-023-5
Renark 2: QC: 3-023-4.Ut
Wavelength: 253.7
Slit: 0.7 L
Laip Current: 0
Energy: 71
Hg2 ID: ICV:4.0ug/l
Seq. No.: 00010 A/S Pos.: -- Date: 10/21/97
Replicate 1 Tine: 10:21
Peak Area (A-s): 3.520 Peak Height (A): 0.152
Blank Corrected Pk Height (A): 0.152
Concentration (ug/L ): 3.941
Hg2 ID: ICB
Seq. No.: 00011 A/5 Pos.: - Date: 10/21/9'
Reolicate 1 Time: 10:23
Peak Area (A-s): 0.008 Peak Height (A): 0.000
Blank Corrected Pk Height (A): 0.000
Concentration (ug/L ): 0.005
Ha2 ID: CHECK LO
Seq. No.: 00012 A/S Pos.: -- Date: 10/21/9'
Reolicate 1 Time: 10:24
Peak Area (A-si: 0.163 Peak Height (A!: O.OOt
Blank Corrected Pk Height (A): 0.006
Concentration (ug/L ): 0.166
Hg2 ID: 43411 M82
Seq. No.: 00013 A/S Pos.: - Date: 10/21/9"
Reolicate 1 Time: 10:26
Peak Area (A-s): -0.003 Peak Height (Ai: 0.000
Blank Corrected Pk Height (A): 0.000
Concentration (ug/L ): 0.005
Hg2 ID: 43411 M82D
Seq. No.: 00014 A/S Pos.: - 'Date: 10/21/9'
Replicate 1 Tine: 10:27 '
Peak Area (A-s): -0.006 Peak Height (A): -0.000
Blank Corrected Pk Height (ft): -0.000
Concentration (ug/L ): -0.010
Replicate 1
Peak Area (A-s): 7.
s: 10:29 .
Peak Height .(ft): 0.321 ,
Blank Correci^trHeignt (A): 0.321
(ug/L ): 8.317
Hg2 ID: 43411 LCS2
Seq. No.: 00016 A/S Pos.: - Date: 10/21/9'
158
-------
icate I Ti»e: 10:36
Area (A-s).: 4.685 Peak Height (A): 0.205
(.Corrected Pk Height (A): 0.205
jntration (ug/L ): 5.325
ID: 43411 ICS2D
.cate 1
Area (A-s): 7.480
; Corrected Pk Height
intration
10: 43411 LCS20
Seq. No.: 00017 A/S Pos.: --
Seq. No.: 00013 A/S Pos.: -- Date: 10/21/9'
cate 1 Tine: 10:41
Area (A-s): 4.775 Peak Height (A): 0.211
, Corrected Pk Height (A): 0.211
.ntration (ug/L ): 5.473
ID: 184-34-6MS
-
Seq. No.: 00019 A/S Pos.: -- Date: 10/21/9"
cate 1 Time: 10:43
Area (A-s): 0.085 Peak Height (A): 0.003
Corrected Pk Height (A): 0.003
ntration (ug/L ): 0.081
MJC. *& it/-31-41 £C
ID: 184-84-6.Wftf D Seq. No.: 00020 A/S Pos.: -- Date: 10/21/9'
cate 1 Time: 10:44
Area (A-s): 0.07E Peak Height (A): 0.00!
Corrected Pk Height (A): 0.003
ntration (ug/L ): 0.075
ID: 184-84-6D
Seq. No.: 00021 A/S Pos.: - Date: 10/21/9'
cate 1 Time: 10:45
Area (A-s): 0.050 Peak Height (A): 0.002
Corrected Pk Height (A): 0.002
ntration (ug/L ): 0.044
ID: 184-84-6D D
Seq. No.: 00022 A/S Pos.: -- Date: 10/21/97
cate 1 Time: 10:46
Area iA-s): 0.042 Peak Height (A): 0.002
Corrected Pk Height (A): 0.002
ntration (ug/L ): 0.039
ID: 184-84-6D MS
Seq. No.: 00023 A/S Pos.: -- Date: 10/21/97
cate 1 Tiie: 10:47
Area (A-s): 7.446 Peak Height (A): 0.314
Corrected Pk Height (A): 0.3141
159
-------
/ . U . i f
Hg2 ID: 184-84-60 USD Seq. No.: 00024" A/S Pos.: •- Date: 10/21/97
Replicate 1 Tine: 10:49
Peak Area (A-s): 7.277 Peak Height (A): 0.306
Blank Corrected Pk Height (A): 0.306 ' _
Concentration (ug/L ): 7.947
Hg2 ID: CCV7:6.0ug/L Seq. No.: 00025 A/S Pos.: -- Date: 10/21/97
Replicate 1 Tine: 10:51
Peak Area (A-s): 5.168 Peak Height (A): 0.220
Blank Corrected Pk Height (A): 0.220
Concentration (ug/L ): 5.715
Hg2 ID: CCB Seq. No.: 00026 A/S Pos.: -- Oats: 10/21/9'
Reolicate 1 Tiie: 10:52
Peak Area (A-s): 0.026 Peak Height (A): 0.001
Blank Corrected Pk Height (A): 0.001
Concentration (ug/L i: 0.018
Hg2 ID: 134-84-6G Seq. No.: 00027 A/S Pos.: -- Date: 10/21/97
Replicate 1 Time: 10:53
Peak Area (A-s): 0.032 Peak Height (A): 0.001
Blank Corrected Pk Height (A): 0.001
Concentration (ug/L ): 0.034
i******!*!*!*,***,*, * *,**•,+, *,»,*, I**! tf^^*,^ ^ i,^*,,,*.*,^*. ,„*„+, t, ft *„ ti ^f.jv^tttf *,*, * I* a *••»*••• *•*•*•* •• I***** »* •*+,** ^tt*,^ m,*t I**,*,
Hg2 ID: 184-84-6G D Seq. No.: 00028 A/S Pos.: - Date: 10/21/9'
Replicate 1 Time: 10:55
Peak Area (A-s): -0.002 Peak Height (A): -0.000
Blank Corrected Pk Height (A): -0.000
Concentration (ug/L ): -0.003
*~*^**^^~^*****^^~***^***^^^*^**^-*ffi*'*ii,tf~,fr~,ft'*i*'**r-*'****r*r*f*i'***'*'tfi'*'*+t'it+,*t*,f,fitrt,^fr*,f,t,fm*,e,,
Hg2 ID: 184-84-6E Seq. He.: 00029 A/S Pos.: - Date: 10/21/97
Replicate I Tine: 10:56
Peak Area (A-s): 0.132 Peak Height (A): 0.005
Blank Corrected Pk Height (A): 0.005
Concentration (ug/L ): 0.138
Hg2 ID: 184-84-6E D
Seq. No.: 00030 A/S Pos.: -- Date: 10/21/97
Replicate 1 Tine: 10:56
Peak Area (A-s): 0.123 Peak Height (A): 0.005
Blank Corrected Pk Height (A): 0.005
Concentration (ug/L ): 0.127
160
-------
• 10: 184-84-6F
Seq. No.: 00031 A/S Pos.: -- Date: 10/21/97
licate 1 Ti«e: 10:57
k Area (A-s): 0.001 Peak Height (A): -0.000
nk Corrected Pk Height (A): -0.000
:entration (ug/L ): -0.003
ID: 184-84-6F 0 Seq. No.: 00032 A/S Pos.: -- Date: 10/21/9'
.icate 1 Tine: 10:59
: Area (A-s): 0.002 Peak Height (A): 0:000
ik Corrected Pk Height (A): 0.000
isntration (ug/L ): 0.003
Wo
ID: 184-84-7WA8- _ Seq. No.: 00033 A/S Pos.: - Date: 10/21/97
. ^VU,.,,x,n fcc
icate 1 - Tine: 11:00
Area (A-s):- 0.030 Peak Height (A): 0.001
k Corrected Pk Height (A): 0.001
entration (ug/L ): 0.031
•*> it-swi tt
ID: 1S4-84-7CWB D Seq. No.: 00034 A/S Pos.: -- Date: 10/21/9'
icate 1 Time: 11:01
Area (A-s): 0.025 Peak Height (A): 0.001
k Corrected Pk Height (A): 0.001
entration (ug/L ): 0.018
10: 184-84-7G Sea. No.: 00035 A/S Pos.: -- Date: 10/21/97
icate 1 Time: 11:02
Area (A-s): -0.005 Peak Height (A): 0.000
k Corrected Pk Height (A): 0.000
Entration (ug/L ): 0.000
ID: 184-84-7G D Seq. No.: 00036 A/S Pos.: -- Date: 10/21/9'
icate 1 Time: 11:05
Area (A-s): -0.024 Peak Height (A): -0.001
< Corrected Pk Height (A): -0.001
sntration (ug/L ): -0.018
ID: CCV8:6.0ug/L Seq. No.: 00037 A/S Pos.: - Date: 10/21/97
.cate 1 Tine: 11:06
Area (A-s): 4..679 Peak Height (A): 0.200
Corrected Pk Height (A): 0.200
ntration (ug/L ): 5.187
ID: CCB
Seq. No.: 00038 A/S Pos.: -- - Date: 10/21/97
161
-------
Peak .Area (A-s): 0.027 Peak Height (A): 0.001*
Blank Corrected.Pk Height (A): 0.001
Concentration (ug/L ): 0.021
Hg2 ID: 184-84-7EF Seq. Ho.: 00039 A/S Pos.: -- Date: 10/21/9'
Replicate 1 • Time: 12:21
Peak Area (A-s): 0.046 Peak Height (A): 0.002
Blank Corrected Pk Height (A): 0.002
Concentration (ug/L ): 0.044
Hg2 ID: 184-84-7EF 0 Seq. No.: 00040 A/S Pos.: -- Date: 10/21/9'
Replicate 1 Tine: 12:22
Peak Area (A-s): 0.039 Peak Height (A): 0.001
Blank Corrected Pk Height (A): 0.001
Concentration (ug/L ): 0.036
Hg2 ID: 184-S4-7EF HS Seq. No.: 00041 A/S Pos.: -- Date: 10/21/9'
Replicate I Time: 12:23
Peak Area (A-s): 7.762 Peak Height (A): 0.326
Blank Corrected Pk Height (A): 0.326
Concentration (ug/L ): 8.442
Hg2 10: 134-84-7EF USD See. No.: 00042 A/S Pos.: - Date: 10/21/9'
Reolicate 1 Tine: 12:24
Peak Area (A-s!: 7.774 Peak Height (A): 0.331
Blank Corrected Pk Height (A): 0.331
Concentration (ug/L ): 8.587
Hg2 ID: 184-84-7H Ssq. No.: 00043 A/S Pos.: - Date: 10/21/97
Replicate 1 Time: 12:25
Peak Area (A-s): 0.141 Peak Height (A): 0.006
Blank Corrected Pk Height (A): 0.006
Concentration (ug/L ); 0.148
Hg2 ID: 184-84-7H D Seq. No.: 00044 A/5 Pos.: - Date: 10/21/9'
Replicate 1 Tine: 12:26
Peak Area (A-s): 0.108 Peak Height (A): 0.004
Blank Corrected Pk Height (A): 0.004
Concentration (ug/L ): 0.112
Hg2 ID: 184-34-71
Seq. No.: 00045 A/S Pos.: - Date: 10/21/9*
Replicate 1 • Tine: 12:27
Peak Area (A-s): 0.009 Peak Height (A): 0.000
Blank Corrected Pk Height (A): 0.000
162
-------
2 10: 184-84-71 D Seq. No.: 00046 A/S Pos.: - Date: 10/21/97
olicate 1 Tine: 12:28
ak Area (A-s): 0.004 Peak Height (A): 0.000
ank Corrected Pk Height (A): O.OOiX
ncentration (ug/L ): 0.003
I ID: CCV9:6.0ug/L Seq. No.: 00047 A/S Pos.: -- Date: 10/21/97
jlicate 1 Tine: 12:29
ik Area (A-s): 5.101 Peak Height (A): 0.216
ink Corrected Pk Height (A): Or216
icentration (ug/L ): 5.609
! ID: CC8 " Seq. No.: 00048 A/S Pos.: - Date: 10/21/9'
ilicate 1 Time: 12:33
ik Area (A-s): -0.011 Peak Height (A): -0.00!
ink Corrected Pk Height (A): -0.001
icentration (ug/L ): -0.013
! ID: 43377 HB1 Seq. No.: 00049 A/S Pos.: -- Date: 10/21/9"
ilicate I lime: 12:34
ik Area (A-si: -0.005 Peak Height (At: -0.000
ink Corrected Pk Height (A): -0.000
icsntration (ug/L ): -O.OOS
! ID: 43377 HB1 D Seq. No.: 00050 A/S Pos.: - Date: 10/21/9'
ilicate 1 Time: 12:35
ik Area (A-s): -0.011 Peak Height (A): -0.001
ink Corrected Pk Height (A): -0.001
icentration (ug/L ): -0.016
! ID: 43377 LCS1 Seq. No.: 00051 A/5 Po<_*—*"^Date: 10/21/9
ilicate 1 ^^^-^Tj«e:12:36
ik Area (A-s): 7.457^^-^"^ Peak Height (A): 0.322
ink CorrectedJlMslght (A): 0.322
icentratierTT^g/L ): 8.340
' ID: 43377 LCS1 Seq. No.: 00052 A/S Pos.: - Date: 10/21/9'
•licate 1 • Tine: 12:41
k Area (A-s): 4.712 Peak Height (A): 0.204
nk Corrected Pk Height (A): 0.204
centration (ug/L ): 5.278
163
-------
ID/Height File: A8828.IDN Analyst: D.STREETER-EDHARDS
Saiple Volute: 100 iL Noiinal Height: 1.0 g
Loc. Saiple ID Height Dilution
0
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
isr
1?
13
ST BLANK "X
STDl=0.2ug/L \
STD2=0.5ug/L /
STD3=1.0ug/L (
STD4--2.0ug/L 7-
STD5:5.0ug/L (
STD6=10.0ug/L 1
ICV:4.0ug/L ^__
IC8
CHECK LO
43377 MB2
43377 MB2D
43377 LCS
45377 LCSt-
184-50-6B
184-50-68 D
184-50-680
184-50-6BO 0
184-50-680 MS
184-50-6BD MSD
CCV7--6.0ug/L
CCB
184-50-6E
184-50-6E 0
184-50-6FE
184-50-6FE D
184-50-7CA8
184-50-7CAB D
184-50-7E
184-50-7E 0
184-50-7F
.184-50-7F D
CCV8:6.0ug/l
CCB
184-50-70
184-50-7D 0
184-50-70 MS
184-50-70 MSO
CCV9:6.0ug/L
CCB
42011 Cnl MB
42011 Cnl MSO
42011 LCS
42011 LCSD
170-70-3
170-70-3 D
170-70-3 MS
170-70-3 HSD
CCV:6.0ug/L
CCB
43411 MB3
43411 MB 3 D
43411 LCS3
43411 LCS30
3 - 0 93-*? &5£
-3-0a3-r P^
•3-oa3-? ^E
3 -0^3- £* &5tr
3-0>53-ff |Q£ jo
- 3-Cbi3^ £5c
-------
)C.
i'i
isl
)6l
H"'
'8"'.
,0"
.1 '
,2
,3
>4
,5
6
,7
Saaple ID Height Dilution
184-84-580
184-84-5BD 0
184-84-580 HS
184-84-580 USD
CCV10=6.0ug/l —3-023-8 fcS
CCB
184-84-5E
184-84-5E D
184-84-5F
184-84-5F D
184-84-5GF
184-84-5GF D -^
CCVll:6.0ug/L -3-^^"^
CCB
165
-------
Eleaent File: H6..MEL
Eleient: Hg2
Print Data: Hain+Suppl.
Print: Calib. Curve
Reiarks:
STANDARDS: 3-023-7
QC: 3-023-8
INSTRUMENT: 5100
Wavelength: 253.7 Peak
Signal Type: AA
Read Tine: 30.0
Satple Replicates: 1
Standard Replicates: 1
FLAME:
Flame Type: Air
Oxidant Flow: 10.0 L/nin
Calibration Type: Linear
QC:
Matrix Check Calculations:
\ Difference for Dupls: No
* Recovery for Spike: No
Analyst: D STREETER-EDHARDS
Peak Storage: None
Technique: MHS Version: 7.01
Slit: 0.7 Lou
Signal Measureaent: Peak Height (5)
Read Delay: 1.0 BOC Tiie: 2
Flame Sensor: On
Fuel Flow: 2.0 L/ain
CALIBRATION:
Solutions
^.I;L B 1 .» « L
taiiu. dianK
Standard 1
Standard 2
Standard 3
Standard 4
Standard 5
Standard 6
Calibration
i ID
1
1
1 CTf\ ft I V
,5IU OLft
ISTD i
ISTD 2
ISTD 3
ISTD 4
ISTD 5
ISTD 6
Units: ug/L
Cone |
t
(
....... - 1
I
0.2001
0.500!
1.000|
2.000|
5.0001
10.0001
Sanple Units:
ug/L
Locations:
Locations:
Cone:
166
-------
«ent File: H6..HEL Eleient: Hg2
B: 10/22/97 Tiie: 09:46
a File: AB828.DAT ID/Nt File: AB828.IDH
hnique: HHS Calib. Type: Linear
ark 1: STANDARDS: 3-023-7
ark 2: QC: 3-023-8
Wavelength: 253.7
Slit: 0.7 L
Laip Current: 0
Energy: 71
10: Seq. 00001
icate 1
; Area (A-s): 0.290
ik Corrected Pk Height (A): 0.012
i-zero perforaed.
Seq. Ho.: 00001 A/S Pos.: - Date: 10/22/97
Ti»e: 09:46
Peak Height (A): 0.012
Seq. No.: 00002 A/S Pos.: -- Date: 10/22/9^
ID: Seq. 00002
icate 1
Area (A-s): 0.020
ik Corrected Pk Height (A): 0.001
-zero performed.
Time: 09:47
Peak Height (A): 0.001
167
-------
Elenent File: HG..MEL Eleient: Hg2
Date: 10/22/97 Tiie: 09:48
Data File: AB823.DAT ID/Ht File: AB823.IDH
Technique: HHS Calib. Type: Linear
Reiark 1: STANDARDS: 3-023-7
Reiark 2: QC= 3-023-8
Wavelength: 253.7
Slit: 0.7 I
Laip Current: 0
Energy: 71
Hg2 10: ST BLANK
Seq. Ho,: 00003 A/S Pos.: -- Date: 10/22/97
Replicate 1 Tiie: 09:50
Peak Area (A-s): -0.000 Peak Height (A): -0.000
Blank Corrected Pk Height (A): -0.000
Auto-zero perforaed.
Hg2 ID: STDl:0.2ug/L
Seq. No.: 00004 A/S Pos.: -- Date: 10/22/9'
Replicate 1 Time: 09:52
Peak Area (A-s): 0.162 Peak Height (A): 0.00'
Blank Corrected Pk Height (A): 0.007
Standard number 1 applied. [0.200]
Correlation coefficient: 1.00000 Slope: 0.0331
Hg2 10: ST02:0.5ug/L
Seq. No.: 00005 A/S Pos.: -- Date: 10/22/97
Sample abs. is greater than that of the largest standard.
Replicate 1 Tine: 09:53
Peak Area (A-s): 0.429 Peak Height (A): 0.018^ -.*
Blank Corrected Pk Height (A): 0.018 .s^ Xv &
Concentration (ug/L ): 0.548 ^
Hg2 ID: STD3:1.0ug/L
Sasple abs. is greater ttj^rThat of the largest standard.
Replicate 1 ^^ Tine: 09:54
Peak Area (A-s)xO86 Peak Height (A): 0.038
Blank Correefed Pk Height (A): 0.038
ConcejiKeftion (ug/L ): 1.145
Hg2 ID: STD2=0.5ug/L Seq. No.: 00007 A/S Pos.: -- Date: 10/22/97
Sample abs. is greater than that of the largest standard.
Replicate 1 Tiie: 10:01
Peak Area (A-s): 0.470 Peak Height (A): 0.021
Blank Corrected Pk Height (ft): 0.021
Concentration (ug/L ): 0.621
Standard nuiber 2 applied. [0.500]
Correlation coefficient: 0.98455 Slope: 0.0402
168
-------
ID: ST03:1.0ug/L
Seq. Ho.: 00008 A/S Pos.: - Date: 10/22/97
pie abs. is greater than that of the largest standard.
licate 1 Tue: 10:02
k Area (A-s): 0.913 Peak Height (A): 0.041
nk Corrected Pk Height (A): 0.041
centration (ug/L ): 1.020
ndard nuiber 3 applied. [1.000]
relation coefficient: 0.99775 Slope: 0.0409
ID: STD4:2.0ug/L
Seq. No.: 00009 A/S Pos.: - Date: 10/22/97
pie abs. is greater than that of the largest standard.
licate 1 Tine: 10:03
k Area (A-s): 1.700 Peak Height (A): 0.073
nk Corrected Pk Height (A): 0.073
centration (ug/L ): 1.798
ndard number 4 applied. [2.000]
relation coefficient: 0.99647 Slope: 0.0378
ID: STD5:5.0ug/l
Seq. No.: 00010 A/S Pos.: -- Date: 10/22/97
t>le abs. is greater than that of the largest standard.
licate 1 Time: 10:05
k Area (A-s): 4.214 Peak Height (A): 0.180
nk Corrected Pk Height (A): 0.180
:entration (ug/L ): 4.768
ndard number 5 applied. [5.000]
relation coefficient: 0.99923 Slope: 0.0364
ID: STD6:10.0ug/L Seq. No.: 00011 A/S Pos.: - Date: 10/22/9-
Die abs. is greater than that of the largest standard.
licate 1 Tine: 10:06
k Area (A-s): 8.381 Peak Height (A): 0.363
nk Corrected Pk Height (A): 0.363
:entration (ug/L ): 9.993
idard number 6 applied. [10.000]
relation coefficient: 0.99984 Slope: 0.0364
169
-------
Eleient File: HG..HEL Eleient: Hg2
Date: 10/22/97 Tiie: 10:07
Data File: AB828.DAT ID/Ht File: AB828.IDH
Technique: HHS Calib. Type: Linear
Reiark 1: STANDARDS: 3-023-7
ReBark 2: QC: 3-023-8
Wavelength: 253.7
Slit: 0.7 L
Laip Current: 0
Energy: 71
H| Display Calibration - C;\flfl_USER\flfl.FILES\ELEHEHT\H6_.HEL
Linear
Corn. Coef.: 8.99984
Slope; B.Q364
Concentration
18.
170
-------
ID: ICV:4.0ug/l Seq. No.: 00012 A/S Pos.: - Date: 10/22/97
licate 1 Tiie: 10:12
< Area (A-s): 3.522 Peak Height (A): 0.150
ik Corrected Pk Height (A): 0.150
:entration (ug/L ): 4.137
ID: ICB Seq. No.: 00013 A/S Pos.: - Date: 10/22/97
.icate 1 Tise: 10:13
; Area (A-s): 0.014 Peak Height (A): 0.000
ik Corrected Pk Height (A): 0.000
:entration (ug/L ): 0.003
ID: CHECK LO Seq. No.: 00014 A/S Pos.: -- Date: 10/22/97
icate 1 Tine: 10:15
. Area (A-s): 0.173 Peak Height (A): 0.007
ik Corrected Pk Height (A): 0.007
lentration (ug/L ): 0.199
ID: 43377 MB2 Seq. No.: 00015 A/S Pos.: -- Date: 10/22/9'
icate 1 Tiie: 10:18
. Area (A-s): 0.003 Peak Height (A): 0.000
ik Corrected Pk Height (A): 0.000
entration (ug/L ): 0.003
ID: 43377 MB2D Seq. No.: 00016 A/S Pos.: - Date: 10/22/97
icate 1 Tine: 10:19
Area (A-s): 0.005 Peak Height (A): -0.000
ik Corrected Pk Height (A): -0.000
entration (ug/L ): -0.003
ID: 43377 LCS Seq. No.: 00017 A/S Pos.: - Date: 10/22/9'
icate I Tine: 10:20
Area (A-s): 4.228 Peak Height (A): 0.181
k Corrected Pk Height (A): 0.181
entration (ug/L ): 4.981
ID: 43377 LCSD Seq. No.: 00018 A/S Pos.: -- Date: 10/22/97
icate 1 Tiie: 10:22
Area (A-s): 4.003 Peak Height (A): 0.172
k Corrected Pk Height (A): 0.172
entration (ug/L ): 4.733
ID: 184-50-68
Seq. Ho.: 00019 A/S Pos.: -- Date: 10/22/97
171
-------
Concentration {ug/L ): 4.948
Hg2 ID: 170-70-3 Seq. No.: 00049 A/S Pos.: - Date: 10/22/97
Replicate 1 Tiie: 10:57
Peak Area (A-s): 0.042 Peak Height (A): 0.002
Blank Corrected Pk Height (ft): 0.002
Concentration (ug/L ): 0.041
Hg2 ID: 170-70-3 D Seq. No.: 00050 A/S Pos.: - Date: 10/22/97
Replicate 1 Tine: 10:59
Peak Area (A-s): 0.036 Peak Height (A): 0.002
Blank Corrected Pk Height (A): 0.002
Concentration (ug/L ): 0.041
Hg2 ID: 170-70-3 MS Seq. No.: 00051 A/S Pos.: - Date: 10/22/9'
Replicate 1 Time: 11:00
Peak Area (A-s): 3.664 Peak Height (A): 0.16?
Blank Corrected Pk Height (ft): 0.169
Concentration (ug/L ): 4.65S,
Hg2 ID: 170-70-3 MSD Seq. No.: 00052 A/S Pos.: -- Date: 10:22''9'
Replicate 1 Time: 11:01
Peak Area (A-s.l: 3.993 Peak Height (A): 0.1S2
Blank Corrected Pk Height (A): 0.182
Concentration (ug/L ): 5.020
Hg2 ID: CCV=6.0ug/L Sea. No.: 00053 A/S Pos.: -- Date: 10/22/97
Reolicate 1 Tine: 11:02
Peak Area (A-s): 4.793 Peak Height (A): 0.228
Blank Corrected Pk Height (A): 0.228
Concentration (ug/L ): 6.278
Hg2 ID: CCB Seq. No.: 00054 A/S Pos.: -- Date: 10/22/9*
Replicate 1 Time: 11:04
Peak Area (A-s): 0.039 Peak Height (A): 0.002
Blank Corrected Pk Height (A): 0.002
Concentration (ug/L ): 0.044
Hg2 ID: 43411 HB3
Seq. No.: 00055 A/S Pos.: - Date: 10/22/9*
Replicate 1 Tine: 11:05
Peak Area (A-s): 0.036 Peak Height (A): 0.001
Blank Corrected Pk Height (A): 0.001
Concentration (ug/L ): 0.036
172
-------
10: 43411 M83 D Seq. No.: 00056 A/S Pos.: - Date: 10/22/97
icate 1 Tiie: 11:07
Area (A-s): 0.028 Peak Height (A): 0.001
k Corrected Pk Height (A): 0.001
entration (ug/L ): 0.022
ID: 43411 LCS3 Seq. No.: 00057 A/S Pos.: - Date: 10/22/97
icate 1 Ti«e: 11:08
Area (A-s): 3.908 Peak Height (A): 0.182
k Corrected Pk Height (A): 0.182
sntration (ug/L ): 5.001
ID: 43411 LCS3D Seq. No.: 00058 A/S Pos.: -- Date: 10/22/97
icate 1 Time: 11:09
Area (A-s): 3.165 Peak Height (A): 0.176
< Corrected Pk Height (A): 0.176
;ntration (ug/L ): 4.846
ID: 184-34-5BD Seq. No.: 00059 A/S Pos.: - Date: 10/22/9'
icate 1 Time: 11:10
Area (A-s): 0.050 Peak Height (A): 0.002
< Corrected Pk Height (A): 0.002
:ntration (ug/L ): 0.050
ID: 184-84-5BD D Seq. No.: 00060 A/S Pos.: -- Date: 10/22/97
icate 1 Time: 11:11
Area (A-s): 0.028 Peak Height (A): 0.001
< Corrected Pk Height (A): 0.001
;ntration (ug/L ): 0.033
ID: 184-84-5BD MS Seq. No.: 00061 A/S Pos.: -- Date: 10/22/97
:cate 1 Tine: 11:11
Area (A-s): 4.042 Peak Height (A): 0.179
( Corrected Pk Height (A): 0.179
miration (ug/L ): 4.926
ID: 184-84-5BD HSD Seq. No.: 00062 ft/S Pos.: -- Date: 10/22/97
cate 1 Tine: 11:12
Area (A-s): 3.862 Peak Height (A): 0.185
Corrected Pk Height (A): 0.185
ntration (ug/L ): 5.092
ID: CCV10:6.0ug/L Seq. No.: 00063 A/S Pos.: - Date: 10/22/97
173
-------
Replicate 1 Tiie: 11:13
Peak Area (A-s): 5.201 Peak Height (A): 0.246
Blank Corrected Pk Height (A): 0.246
Concentration (ug/L ): 6.775
Hg2 ID: CCB Seq. No.: 00064 A/S Pos.: - Date: 10/22/97
Replicate 1 Tine: 11:14
Peak Area (A-s): 0.075 Peak Height (A): 0.003
Blank Corrected Pk Height (A): 0.003
Concentration (ug/L ): 0.080
Hg2 ID: 184-84-5E Seq. No.: 00065 A/S Pos.: -- Date: 10/22/97
Replicate 1 Tine: 11:15
Peak Area (A-s): 0.043 Peak Height (A): 0.002
Blank Corrected Pk Height (A): 0.002
Concentration (ug/L ): 0.041
Hg2 ID: 184-84-5E D Seq. No.: 00066 A/S Pos.: - Date: 10/22/97
Replicate 1 Tine: 11:16
Peak Area (A-s): 0.033 Peak Height (A): 0.001
Blank Corrected Pk Height (A): 0.001
Concentration (ug/L ): 0.036
Hg2 ID: 184-84-5F Seq. No.: 00067 A/S Pos.: -- Date: 10/22/97
Replicate 1 Tine: 11:16
Peak Area (A-s): 0.033 Peak Height (A): 0.001
Blank Corrected Pk Height (A): 0.001
Concentration (ug/L ): 0.030
Hg2 ID: 184-84-5F D Seq. No.: 00068 A/S Pos.: - Date: 10/22/97
Replicate 1 Time: 11:17
Peak Area (A-s): 0.030 Peak Height (A): 0.001
Blank Corrected Pk Height (A): 0.001
Concentration (ug/L ): 0.025
Hg2 ID: 184-84-5GF Seq. No.: 00069 A/S Pos.: -- Date: 10/22/97
Replicate 1 Tine: 11:18
Peak Area (A-s): 0.045 Peak Height (A): 0.002
Blank Corrected Pk Height (A): 0.002
Concentration (ug/L ): 0.044
Hg2 ID: 184-84-56F D
Seq. No.: 00070 A/S Pos.: -- Date: 10/22/97
Replicate 1 Tine: 11:19
Peak Area (A-s): 0.043 Peak Height (A): 0.002
Blank Corrected Pk Height (A): 0.002
174
-------
ncentration (ug/L ): 0.041
2 10: CCVll:6.0ug/L Seq. Ho.: 00071 A/S Pos.: -- Date: 10/22/97
plicate 1 Tiie: 11:19
ak Area (A-s): 4.696 Peak Height (A): 0.236
ank Corrected Pk Height (A): 0.236
ncentration (ug/L ): 6.485
2 ID: CCB Seq. Ho.: 00072 A/'S Pos.: - Date: 10/22/97
Dlicate 1 Tine: 11:20
ak Area (A-s): 0.046 Peak Height (A): 0.002
ank Corrected Pk Height (A): 0.002
ncentration (ug/L ): 0.047
175
-------
-------
APPENDIX D
COMPUTER SUMMARIES
-------
Appendix D.I
Computer Summaries
Baghouse Inlet - Method 23 & 29
-------
Summary of Stack Gas Parameters and Test Results
As-pHfH-TVt-Atrr "8" - Gary, North Carolina
US EPA Test Method 23 - PCDD / PCDF
Baghouse Inlet
Page 1 of 6
Y
AH
Pbar
vm
Tm
Pstatic
Ts
vte
CO2
02
N2
CP
Ap1*
e
Dn
An
Vm(std)
Vm(sld)
PS
Bw,
Vwstd
1-B™
Md
Ms
Vs
A
Qa
Q.
Qs(cmm)
I
RUN NUMBER
RUN DATE
RUN TIME
MEASURED DATA
Meter Box Correction Factor
Avg Meter Orifice Pressure, in. H2O
Barometric Pressure, inches Hg
Sample Volume, ft3
Average Meter Temperature, °F
Stack Static Pressure, inches H2O
Average Stack Temperature, °F
Condensate Collected, ml
Carbon Dioxide content, % by volume
Oxygen content, % by volume
Nitrogen content, % by volume
Pilot Tube Coefficient
Average Square Root Dp, (in. H2O)iy2
Sample Run Duration, minutes
Nozzle Diameter, inches
CALCULATED DATA
Nozzle Area, ft2
Standard Meter Volume, dscf
Standard Meter Volume, dscm
Stack Pressure, inches Hg
Moisture, % by volume
Standard Water Vapor Volume, ft3
Dry Mole Fraction
Molecular Weight (d.b.), Ib/lb-mole
Molecular Weight (w.b.), Ib/lb-mole
Stack Gas Velocity, ft/s
Stack Area, ft2
Stack Gas Volumetric flow, acfm
Stack Gas Volumetric flow, dscfm
Stack Gas Volumetric flow, dscmm
Isokinetic Sampling Ratio, %
R-M23-I-1
8/27/97
0940-1227
1.021
1.21
29.80
58.263
96
-1.8
308
510.5
5.2
13.8
81.0
0.84
0.6901
96
0.257
0.00036
56.399
1.597
29.67
29.9
24.029
0.701
29.38
25.98
49.5
16.20
48,074
22,981
650.7
115.0
R-M234-2
8/28/97
0908-1428
1.021
0.286
29.60
53.015
96
-1.8
306
414.9
5.2
13.1
81.7
0.84
0.6755
170
0.194
0.00021
50.885
1.441
29.47
27.7
19.529
0.723
29.36
26.21
48.3
16.20
46,957
23,027
652.1
102.6
R-M23-I-3
8/29/37
0818-1413
1.021
0.396
29.60
83.709
93
-1.8
290
393.0
4.0
15.2
80.8
0.84
0.7133
240
0.194
0.00021
80.735
2.286
29.47
18.6
18.499
0.814
29.25
27.15
49.6
16.20
48,211
27,178
769.6
97.7
Average of
1st and 2nd
Test Run
1.021
0.75
29.70
55.639
96
-1.8
307
462.7
5.2
13.5
81.4
0.84
0.6828
133
0.226
0.00028
53.642
1.519
29.57
28.8
21.779
0.712
29.37
26.09
48.9
16.20
47,515
23,004
651.4
108.8
-------
Summary of Stack Gas Parameters and Test Results
foptttu- 7*Aur"«" • Gary, North Carolina
US EPA Test Method 23 - PCDD / PCDF
Baghouse Inlet
Page 2 of 6
(ng)
(ng/dscm)
(M9/hr)
(ng)
(ng/dscm)
(pg/hr)
(ng)
(ng/dscm)
(pg/hr)
(ng)
(ng/dscm)
(pg/hr)
(ng)
(ng/dscm)
(pg/hr)
(ng)
(ng/dscm)
(pg/hr)
RUN NUMBER
RUN DATE
RUN TIME
EMISSIONS DATA
DIOXINS:
2378 TCDD
Catch, ng
Concentration, ng/dscm, as measured
Emission Rate, pg/hr
Total TCDD
Catch, ng
Concentration, ng/dscm, as measured
Emission Rate, pg/hr
12379PeCPP
Catch, ng
Concentration, ng/dscm, as measured
Emission Rate, pg/hr
Total PeCDD
Catch, ng
Concentration, ng/dscm, as measured
Emission Rate, pg/hr
123478 HxCDD
Catch, ng
Concentration, ng/dscm, as measured
Emission Rate, pg/hr
123678 HxCDD
Catch, ng
Concentration, ng/dscm, as measured
Emission Rate, pg/hr
R-M23-I-1
8/27/97
0940-1227
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
R-M23-I-2
8/28/97
0908-1428
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
R-M23-I-3
8/29/97
0818-1413
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Avenge of
1st and 2nd
Test run
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
() Not Detected. Value shown is the detection limit for that sample.
{} Estimated Maximum Possible Concentration.
-------
Summary of Stack Gas Parameters and
Test Results
.?:?*4tr TiAm "g"i - Gary, North Carolina
US EPA Test Method 23 - PCDO / PCDF
RUN NUMBER
RUN DATE
RUN TIME
Baghouse Inlet
Page 3 of 6
R-M23-I-1
8/27/97
0940-1227
R-M23-I-2
8/28/97
0908-1428
R-M23-I-3
8/29/97
0818-1413
Avenge of
1st and 2nd
Test Run
EMISSIONS DATA -Continued
(ng)
(ng/dscm)
(pg/hr)
(ng)
(ng/dscm)
(pg/hr)
(ng)
(ng/dscm)
(pg/hr)
(ng)
(ng/dscm)
(pg/hr)
(ng)
(ng/dscm)
(pg/hr)
(ng)
(ng/dscm)
(pg/hr)
DIOXINS - Continued
123789 HxCDD
Catch, ng
Concentration, ng/dscm,
Emission Rate, pg/hr
Total HxCDD
Catch, ng
Concentration, ng/dscm,
Emission Rate, pg/hr
1234678 HpCDD
Catch, ng
Concentration, ng/dscm,
Emission Rate, pg/hr
Total HpCDD
Catch, ng
Concentration, ng/dscm,
Emission Rate, pg/hr
1 2346789 OCPD
Catch, ng
Concentration, ng/dscm,
Emission Rate, pg/hr
Total PCDD
Catch, ng
Concentration, ng/dscm,
Emission Rate, pg/hr
ND
as measured ND
ND
ND
as measured ND
ND
ND
as measured ND
ND
{0.350}
as measured {0.219}
{8.56}
9.70
as measured 6.07
237
{10.1}
as measured {6.29}
{246}
-
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
8.20
5.69
223
8.20
5.69
223
ND
ND
ND
0.0200
0.00875
0.404
0.140
0.0612
2.83
0.340
0.149
6.87
16.2
7.09
327
16.6
7.24
334
ND
ND
ND
ND
ND
ND
ND
ND
ND
{0.175}
{0.110}
{4.28}
8.95
5.88
230
{9.13}
{5.99}
{234}
() Not Detected. Value shown is the detection limit for that sample.
{} Estimated Maximum Possible Concentration.
-------
Summary of Stack Gas Parameters and
Test Results
fcpHter Tt/fcur "B '•'- Gary, North Carolina
US EPA Test Method 23 - PCDD /
RUN NUMBER
RUN DATE
RUN TIME
Baghouse Inlet
Page 4 of 6
R-M23-I-1
8/27/97
0940-1227
PCDF
R-M23-I-2
8/28/97
0908-1428
R-M23-I-3
8/29/97
0818-1413
Average of
1st and 2nd
Test Run
EMISSIONS DATA - Continued
(ng)
(ng/dscm)
(ug/hr)
(ng)
(ng/dscm)
(ug/hr)
(ng)
(ng/dscm)
(ug/hr)
(ng)
(ng/dscm)
(ug/hr)
(ng)
(ng/dscm)
(ug/hr)
(ng)
(ng/dscm)
(ug/hr)
FURANS
2378 TCDF
Catch, ng
Concentration, ng/dscm,
Emission Rate, ug/hr
Total TCDF
Catch, ng
Concentration, ng/dscm,
Emission Rate, ug/hr
12378 PeCDF
Catch, ng
Concentration, ng/dscm,
Emission Rate, ug/hr
23478 PeCDF
Catch, ng
Concentration, ng/dscm,
Emission Rate, ug/hr
Total PeCDF
Catch, ng
Concentration, ng/dscm
Emission Rate, ug/hr
1 23478 HxCDF
Catch, ng
Concentration, ng/dscm
Emission Rate, ug/hr
ND
as measured ND
ND
{0.180}
as measured {0.113}
{4.40}
ND
as measured ND
ND
ND
as measured ND
ND
0.470
as measured 0.294
11.5
ND
as measured ND
ND
ND
ND
ND
0.170
0.118
4.62
ND
ND
ND
ND
ND
ND
0.330
0.229
8.96
ND
ND
ND
ND
ND
ND
0.0100
0.00437
0.202
ND
ND
ND
ND
ND
ND
{0.0100}
{0.00437}
{0.202}
0.0200
0.00875
0.404
ND
ND
ND
{0.175}
{0.115}
{4.51}
ND
ND
ND
ND
ND
ND
0.400
0.262
10.2
ND
ND
ND
() Not Detected. Value shown is the detection limit for that sample.
{} Estimated Maximum Possible Concentration.
-------
ftspnAtrTiAMT "B" - Gary, North Carolina
US EPA Test Method 23 - PCDD / PCDF
Baghouse Inlet
(ng)
(ng/dscm)
(pg/hr)
(ng)
(ng/dscm)
(pg/hr)
(ng)
(ng/dscm)
(pg/hr)
(ng)
(ng/dscm)
(pg/hr)
(ng)
(ng/dscm)
(pg/hr)
(ng)
(ng/dscm)
(|jg/hr)
Page
RUN NUMBER
RUN DATE
RUN TIME
EMISSIONS DATA - Continued
Furans - Continued
123678 HxCDF
Catch, ng
Concentration, ng/dscm, as measured
Emission Rate, pg/hr
234678 HxCDF
Catch, ng
Concentration, ng/dscm, as measured
Emission Rate, pg/hr
123789 HxCDF
Catch, ng
Concentration, ng/dscm, as measured
Emission Rate, pg/hr
Total HxCDF
Catch, ng
Concentration, ng/dscm, as measured
Emission Rate, pg/hr
1 234678 HpCDF
Catch, ng
Concentration, ng/dscm, as measured
Emission Rate, pg/hr
1234789 HpCDF
Catch, ng
Concentration, ng/dscm, as measured
Emission Rate, pg/hr
5 of 6
R-M23-I-1
8/27/97
0340-1227
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
R-M23-I-2
8/28/97
0908-1428
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
. ND
ND
ND
ND
ND
ND
ND
ND
R-M23-I-3
8/29/97
0818-1413
ND
ND
ND
{0.00600}
{0.00262}
{0.121}
ND
ND
ND
0.0300
0.0131
0.606
0.0400
0.0175
0.808
ND
ND
ND
Average of
1st and 2nd
Test run
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
() Not Detected. Value shown is the detection limit for that sample.
{} Estimated Maximum Possible Concentration.
-------
Summary of Stack Gas Parameters and Test Results
A&H&.T TLA™ "8" , - Gary, North Carolina
US EPA Test Method 23 - PCDD / PCDF
Baghouse Inlet
Page 6 of 6
(ng)
(ng/dscm)
(pg/hr)
(ng)
(ng/dscm)
(pg/hr)
(ng)
(ng/dscm)
(pg/hr)
(ng)
(ng/dscm)
(pg/hr)
RUN NUMBER
RUN DATE
RUN TIME
EMISSIONS DATA - Continued
Furans - Continued
Total HpCDF
Catch, ng
Concentration, ng/dscm, as measured
Emission Rate, (jg/hr
1 2346789 OCDF
Catch, ng
Concentration, ng/dscm, as measured
Emission Rate, pg/hr
Total PCDF
Catch, ng
Concentration, ng/dscm, as measured
Emission Rate, pg/hr
Total PCDD + PCDF
Catch, ng
Concentration, ng/dscm, as measured
Emission Rate, pg/hr
R-M23-I-1
8/27/97
0940-1227
ND
ND
ND
ND
ND
ND
{0.650}
{0.407}
{15.9}
{10.7}
{6.70}
{262}
R-M23-I-2
8/28M7
0908-1428
{0.260}
{0.180}
{7.06}
ND
ND
ND
{0.760}
{0.527}
{20.6}
{8.96}
{6.22}
{243}
R-M23-I-3
8/29/97
0818-1413
0.0400
0.0175
0.808
ND
ND
ND
{0.0900}
{0.0394}
{1.82}
{16.7}
{7.28}
{336}
Avenge of
1st and 2nd
Test run
{0.130}
{0.0902}
{3.53}
ND
ND
ND
{0.705}
{0.467}
{18.3}
{9.83}
{6.46}
{252}
() Not Detected. Value shown is the detection limit for that sample.
{} Estimated Maximum Possible Concentration.
-------
PCDD/PCDF Corrected Stack Gas Concentrations and 2378 TCDD Toxic Equivalent Concentrations
AynAtf ~Putntr « A" . Garner, North Carolina
US EPA Test Method 23 - PCDD/PCDF
Baghouse Inlet
RUN NUMBER
RUN DATE
RUN TIME
DIOXINS:
2378 TCDD
Total TCDD
12378 PeCDD
Total PeCDD
123478 HxCDD
1 23678 HxCDD
123789 HxCDD
Total HxCDD
1 234678 HpCDD
Total HpCDD
12346789 OCDD
Total PCDD
FURANS:
2378 TCDF
Total TCDF
12378 PeCDF
23478 PeCDF
Total PeCDF
123478 HxCDF
123678 HxCDF
234678 HxCDF
123789 HxCDF
Total HxCOF
1234678 HpCDF
1 234789 HpCDF
Total HpCDF
1 2346789 OCDF
Total PCDF
Total PCDD + PCDF
CONCENTRATION
(ng/dscmm, adjusted to 7% O2)
R-M23-I-1 R-M23-I-2 R-M23-I-3
08/27/97 08/28/97 08/29/97
0940-1227 0908-1428 0818-1413
ND NO ND
ND ND ND
ND ND ND
ND ND ND
ND ND ND
ND ND ND
ND ND ND
ND ND 0.0213
ND ND 0.149
{0.429} ND 0.363
11.9 10.1 17.3
{12.3} 10.1 17.7
ND ND ND
{0.221} 0.210 0.0107
ND ND ND
ND ND ND
0.576 0.408 {0.0107}
ND ND 0.021
ND ND ND
ND ND {0.00640}
ND ND ND
ND ND 0.0320
ND ND 0.0427
ND ND ND
ND {0.322} 0.0427
ND ND ND
{0.797} {0.940} {0.0960}
{13.1} {11.1} {178}
Average
of 1st & 2nd
Run
ND
ND
ND
ND
ND
ND
ND
ND
ND
{0.215}
11.0
{11.2}
ND
{0.215}
ND
ND
0.492
ND
ND
ND
ND
ND
ND
ND
{0.161}
ND
{0.868}
{12.1}
2378-TCDD
Toxic
Equivalent
Factor
1.000
0.500
0.100
0.100
0.100
0.010
0.001
0.100
0.050
0.500
0.100
0.100
0.100
0.100
0.010
0.010
0.001
2378 TOXIC EQUIVALENCIES
(ng/dscmm, adjusted to 7% O2)
R-M23-I-1 R-M23-I-2 R-M23-I-3
8/27/97 8/28/97 8/29/97
0940-1227 0908-1428 0818-1413
ND ND ND
"
ND ND ND
ND ND ND
ND ND ND
ND ND ND
ND ND 0.001
0.0119 0.0101 0.0173
0.0119 0.0101 0.0188
ND ND ND
ND ND ND
ND ND ND
ND ND 0.00213
ND ND ND
ND ND {0.000640}
ND ND ND
ND ND 0.000427
ND ND ND
ND ND ND
ND ND {0.00320}
0.0119 0.0101 {0.0220}
Average
of 1st & 2nd
Run
ND
ND
ND
ND
ND
ND
0.0110
0.0110
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.0110
-------
Summary of Stack Gas Parameters and Test Results
US EPA EMC Asphalt Concrete Emissions Testing • ftsmdu VUt,
US EPA Test Method 29 - Multiple Metals
Baghouse Inlet
Page 1 of 4
y
AH
Pbar
vm
Tm
•static
Ts
V,c
CO2
02
IM2
Vp
Ap
e
Dn
An
Vm(std)cf
Vjn(std) cm
Qm
PS
Bws
VW5td
1-BWS
Md
Ms
vs
A
Qa
Qscfm
Qscmm
I
RUN NUMBER
RUN DATE
RUN TIME
MEASURED DATA
Meter Box Correction Factor
Avg Meter Orifice Pressure, in. H20
Barometric Pressure, inches Hg
Sample Volume, ft3
Average Meter Temperature, °F
Stack Static Pressure, inches H2O
Average Stack Temperature, °F
Condensate Collected, ml
Carbon Dioxide content, % by volume
Oxygen content, % by volume
Nitrogen content, % by volume
Pilot Tube Coefficient
Average Square Root Ap, (in. H2O)1/2
Sample Run Duration, minutes
Nozzle Diameter, inches
CALCULATED DATA
Nozzle Area, ft2
Standard Meter Volume, ft3
Standard Meter Volume, m3
Average Sampling Rate, dscfm
Stack Pressure, inches Hg
Moisture, % by volume
Standard Water Vapor Volume, ft3
Dry Mole Fraction
Molecular Weight (d.b.), Ib/lb-mole
Molecular Weight (w.b.), Ib/lb-mole
Stack Gas Velocity, ft/s
Stack Area, ft2
Stack Gas Volumetric flow, acfm
Stack Gas Volumetric flow, dscfm
Stack Gas Volumetric flow, dscmm
Isokinetic Sampling Ratio, %
R-M29-I-1
«/27/97
-1000—1200
1.016
1.24
29.80
52.232
101
-1.8
304
422.5
4.6
14.2
81.2
0.84
0.6972
87
0.256
0.000357
49.883
1.413
0.573
29.67
28.5
19.887
0.715
29.30
26.08
49.7
16.20
48,345
23,687
671
109.7
R-M29-I-2
8/28/97
1019-1427
1.016
OJ298
29.60
64.379
102
-1.8
309
485.0
5.2
13.1
81.7
0.84
0.6977
200
0.194
0.000205
60.783
1.721
0.304
29.47
27.3
22.829
0.727
29.36
26.26
49.9
16.20
48,535
23,865
676
100.5
itr "B"
R-M29-I-3
8/29/97
0819-1403
1.016
0.400
29.60
85.398
96
-1.8
289
403.9
4.0
15.2
80.8
0.84
0.7185
240
0.196
0.000210
81.522
2.308
0.340
29.47
18.9
19.012
0.811
29.25
27.12
49.9
16.20
48,550
27,325
774
96.1
Average of
1st and 2nd
Test Runs
1.016
0.771
29.700
58.306
101.622
-1.800
306.083
453.750
4.900
13.650
81.450
0.840
0.697
143.500
0.225
0.000281
55.333
1.567
0.439
29.57
27.9
21.358
0.721
29.33
26.17
49.8
16.20
48,440
23,776
673
105.1
-------
Summary of Stack Gas Parameters and Test Results
US EPA EMC Asphalt Concrete Emissions Testing • KsryQiT Pt*
-------
Summary of Stack Gas Parameters and Test Results
US EPA EMC Asphalt Concrete Emissions Testing - Aspn*a fa
US EPA Test Method 29 - Multiple Metals
Baghouse Inlet
pg
pg/dscm
pg/dscm at 7%
g/hr
pg
pg/dscm
pg/dscm at 7%
g/hr
pg
pg/dscm
pg/dscm at 7%
g/hr
pg
pg/dscm
pg/dscm at 7%
g/hr
pg
pg/dscm
pg/dscm at 7%
g/hr
pg
pg/dscm
pg/dscm at 7%
g/hr
RUN NUMBER
RUN DATE
RUN TIME
EMISSIONS DATA -Continued
Chromium
Target Catch, pg
Concentration, pg/dscm
Concentration, pg/dscm at 7% O2
Emission Rate, g/hr
Colbalt
Target Catch, pg
Concentration, pg/dscm
Concentration, pg/dscm at 7% O2
Emission Rate, g/hr
Copper
Target Catch, pg
Concentration, pg/dscm
Concentration, pg/dscm at 7% O2
Emission Rate, g/hr
Lead
Target Catch, pg
Concentration, pg/dscm
Concentration, pg/dscm at 7% O2
Emission Rate, g/hr
Manganese
Target Catch, pg
Concentration, pg/dscm
Concentration, pg/dscm at 7% O2
Emission Rate, g/hr
Mercury
Target Catch, pg
Concentration, pg/dscm
Concentration, pg/dscm at 7% O2
Emission Rate, g/hr
Page 3 of 4
R-M29-I-1
8/27/97
-1000-1200
95.8
67.8
141
2.73
63.2
44.7
92.8
1.80
613
434
900
17.5
85.3
60.4
125
2.43
2,471
1,750
3,630
70.4
ND
ND
ND
ND
R-M29-I-2
8/28/97
1019-1427
88.3
"51.3
91.4
2.08
55.1
32.0
57.0
1.30
660
384
684
15.6
83.1
48.3
86.0
1.96
2,336
1,357
2,418
55.0
ND
ND
ND
ND
4<«r "g"
R-M29-I-3
8/29/97
0819-1403
76.8
33.3
81.2
1.55
45.5
19.7
48.1
0.915
607
263
641
12.2
82.7
35.8
87.4
1.66
2,251
975
2,377
45.3
ND
ND
ND
ND
Average of
1st and 2nd
Test Runs
92.1
59.6
116
2.41
59.2
38.4
74.9
1.55
636
409
792
16.5
84.2
54.3
106
2.19
2,404
1,553
3,024
62.7
ND
ND
ND
ND
-------
Summary of Stack Gas Parameters and Test Results
US EPA EMC Asphalt Concrete Emissions Testing • f,s,?miLr v-v .4*-; "3"
US EPA Test Method 29 - Multiple Metals
Baghouse Inlet
pg
pg/dscm
pg/dscm at 7%
g/hr
H9
pg/dscm
pg/dscm at 7%
g/hr
MS
pg/dscm
pg/dscm at 7%
g/hr
P9
pg/dscm
pg/dscm at 7%
g/hr
P9
pg/dscm
pg/dscm at 7%
g/hr
M9
pg/dscm
pg/dscm at 7%
g/hr
fl(W NUMBER
RUN DATE
RUN TIME
EMISSIONS DATA - Continued
Nickel
Target Catch, pg
Concentration, pg/dscm
Concentration, pg/dscm at 7% O2
Emission Rate, g/hr
Phosphorus
Target Catch, pg
Concentration, pg/dscm
Concentration, pg/dscm at 7% O2
Emission Rate, g/hr
Silver
Target Catch, pg
Concentration, pg/dscm
Concentration, pg/dscm at 7% O2
Emission Rate, g/hr
Selenium
Target Catch, pg
Concentration, pg/dscm
Concentration, pg/dscm at 7% O2
Emission Rate, g/hr
Thallium
Target Catch, pg
Concentration, pg/dscm
Concentration, pg/dscm at 7% O2
Emission Rate, g/hr
Zinc
Target Catch, pg
Concentration, pg/dscm
Concentration, pg/dscm at 7% O2
Emission Rate, g/hr
Page 4 of 4
R-M29-I-1
8/27/97
-1000-1200
59.0
4^.7
86.6
1.68
4,250
3,009
6,242
121
1.20
0.850
1.76
0.0342
ND
ND
ND
ND
12.2
8.64
17.9
0.348
761
539
1,118
21.7
R-M29-I-2
8/28/97
1019-1427
58.4
33.9
60.5
1.38
3,874
2,251
4,011
91.3
1.00
0.581
1.04
0.0236
0.396
0.230
0.410
0.00933
8.58
4.98
8.88
0.202
683
397
707
16.1
R-M29-I-3
8/29/97
0819-1403
50.3
21.8
53.1
1.01
5,010
2,170
5,292
101
0.671
0.291
0.709
0.0135
ND
ND
ND
ND
2.08
0.901
2.20
0.0418
553
239
584
11.1
Average o
1st and 2,
Test Rom
5
3
7.'
1
4,0'
2,6:
5,1:
1t
1.1
0,71
1.4
0.026
0,19
0.11
0.20.
0.0046!
10.3S
6.81
13.4C
Q27£
722
468
913
18.9
-------
-------
Appendix D.2
Computer Summaries
Baghouse Outlet - Method 9, 23 & 29
-------
-------
Date:
Start Time:
Stop Time:
8/29/97
0923
1023
Baghouse Outlet
Run Number: O-M9-3B
Net Run
Time,
minutes
0.25
0.50
0.75
1.00
1.25
1.50
1.75
2.00
2.25
2.50
2.75
3.00
3.25
3.50
3.75
4.00
4.25
4.50
4.75
5.00
5.25
5.50
5.75
6.00
6.25
6.50
6.75
7.00
7.25
7.50
7.75
8.00
8.25
8.50
8.75
9.00
9.25
9.50
9.75
10.00
10.25
10.50
10.75
11.00
11.25
11.50
11.75
12.00
HIGT
six-minute
rolling averages
percent opacity,
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
1.25
1.46
.46
.46
.25
.04
.25
.25
.25
.25
.25
.25
.25
.25
1.25
1.25
1.25
1.04
1.25
1.25
1.25
1.67
1.67
1.67
1.46
Net Run
Time,
minutes
12.25
12.50
12.75
13.00
13.25
13.50
13.75
14.00
14.25
14.50
14.75
15.00
15.25
15.50
15.75
16.00
16.25
16.50
16.75
17.00
17.25
17.50
17.75
18.00
18.25
18.50
18.75
19.00
19.25
19.50
19.75
20.00
20.25
20.50
20.75
21.00
21.25
21.50
21.75
22.00
22.25
22.50
22.75
23.00
23.25
23.50
23.75
24.00
six-minute
rolling averages
percent opacity,
.46
.46
.46
.67
.67
.46
.46
.67
.46
.46
.46
.46
.67
.67
.88
2.08
2.08
1.88
1.88
1.88
1.46
1.46
1.46
1.46
1.30
1.30
1.30
1.09
1.09
1.09
1.09
1.30
1.30
1.52
1.74
1.74
1.52
1.96
1.52
1.30
1.30
1.30
1.30
1.30
1.30
1.30
1.36
1.36
Net Run
Time,
minutes
24.25
24.50
24.75
25.00
25.25
25.50
25.75
26.00
26.25
26.50
26.75
27.00
27.25
27.50
27.75
28.00
28.25
28.50
28.75
29.00
29.25
29.50
29.75
30.00
30.25
30.50
30.75
31.00
31.25
31.50
31.75
32.00
32.25
32.50
32.75
33.00
33.25
33.50
33.75
34.00
34.25
34.50
34.75
35.00
35.25
35.50
35.75
36.00
six-minute
rolling averages
percent opacity,
1.30
1.30
.52
.52
.52
.52
.96
.52
.52
.30
.09
.09
.09
0.65
0.65
0.65
0.68
0.68
0.68
0.68
0.68
0.68
0.65
0.65
0.65
0.65
0.43
0.43
0.43
0.43
0.00
0.00
0.22
0.22
0.22
0.22
0.22
0.22
0.22
0.22
0.63
0.63
0.63
0.63
0.83
0.83
0.83
1.04
[ESt SlX-MINUTE BLOCK AVERAGE - 1.46 AVE
Net Run
Time,
minutes
36.25
36.50
36.75
37.00
37.25
37.50
37.75
38.00
38.25
38.50
38.75
39.00
39.25
39.50
39.75
40.00
40.25
40.50
40.75
41.00
41.25
41.50
41.75
42.00
42.25
42.50
42.75
43.00
43.25
43.50
43.75
44.00
44.25
44.50
44.75
45.00
45.25
45.50
45.75
46.00
46.25
46.50
46.75
47.00
47.25
47.50
47.75
48.00
RAGEO
six-minute
rolling averages
percent opacity,
1.04
.04
.04
.04
.25
.25
.25
.46
.25
.25
•25
.25
.25
.25
.25
.25
0.83
0.83
1.04
1.25
1.04
1.04
1.04
0.83
0.83
0.83
1.04
1.04
0.83
0.83
0.83
0.63
0.63
0.63
0.63
0.63
0.63
0.63
0.83
0.83
0.83
0.83
0.63
0.42
0.42
0.42
0.42
0.42
Net Run
Time,
minutes
48.25
48.50
48.75
49.00
49.25
49.50
49.75
50.00
50.25
50.50
50.75
51.00
51.25
51.50
51.75
52.00
52.25
52.50
52.75
53.00
53.25
53.50
53.75
54.00
54.25
54.50
54.75
55.00
55.25
55.50
55.75
56.00
56.25
56.50
56.75
57.00
57.25
57.50
57.75
58.00
58.25
58.50
58.75
59.00
59.25
59.50
59.75
60.00
six-minute
rolling averages
percent opacity,
0.42
0.42
0.21
0.21
0.21
0.21
0.22
0.23
0.23
0.23
0.23
0.23
0.23
0.45
0.23
0.23
0.45
0.45
0.45
0.45
0.45
0.68
0.91
0.91
1.36
1.36
1.36
1.36
1.36
1.36
1.30
1.25
1.25
1.25
NA*
NA*
NA*
NA*
NA*
NA*
NA*
NA*
NA*
NA*
NA*
NA*
NA*
NA*
r»AUTY DURING RUN = o.98
HIGHEST SIX-MINUTE ROLLING AVERAGE = 2.08
* Due to fugitive emission obstructions, a number of readings could not be made. Running averages included the time
lapses so that the net run time was shortened. NA indicates that for the time period, an average is Not Applicable.
-------
Date:
Start Time:
Stop Time:
8/29/97
1033
1133
Baghouse Outlet
Run Number: O-M9-3C
Net Run
Time,
minutes
0.2S
0.50
0.75
1.00
1.25
1.50
1.75
2.00
2.25
2.50
2.75
3.00
3.25
3.50
3.75
4.00
4.25
4.50
4.75
5.00
5.25
5.50
575
6.00
6.25
6.50
6.75
7.00
7.25
7.50
7.75
8.00
8.25
8.50
8.75
9.00
9.25
9.50
9.75
10.00
10.25
10.50
10.75
11.00
11.25
11.50
11.75
12.00
six-minute
rolling averages
percent opacity,
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.63
0.42
0.42
0.63
0.63
0.63
0.63
0.83
1.04
1.25
1.04
1.25
1.25
1.46
1.46
1.46
1.46
1.46
1.67
1.67
1.67
1.67
1.88
1.74
1.82
Net Run
Time,
minutes
12.25
12.50
12.75
13.00
13.25
13.50
13.75
14.00
14.25
14.50
14.75
15.00
15.25
15.50
15.75
16.00
16.25
16.50
16.75
17.00
17.25
17.50
17.75
18.00
18.25
18.50
1875
19.00
19.25
19.50
19.75
20.00
20.25
20.50
20.75
21.00
21.25
21.50
21.75
22.00
22.25
22.50
22.75
23.00
23.25
23.50
23.75
24.00
six-minute
rolling averages
percent opacity,
.82
.82
.59
.59
.59
.59
.36
.14
0.91
0.91
0.68
0.68
0.68
0.68
1.14
1.14
1.14
0.91
0.91
0.95
1.00
0.75
0.95
0.91
0.91
0.91
0.91
0.91
0.91
1.36
1.36
1.36
1.36
1.59
1.59
1.59
1.36
1.36
0.91
0.91
0.91
0.91
0.91
0.87
0.83
0.87
0.65
0.65
Net Run
Time,
minutes
24.25
24.50
24.75
25.00
25.25
25.50
25.75
26.00
26.25
26.50
26.75
27.00
27.25
27.50
27.75
28.00
28.25
28.50
28.75
29.00
29.25
29.50
29.75
30.00
30.25
30.50
30:75
31.00
31.25
31.50
31.75
32.00
32.25
32.50
32.75
33.00
33.25
33.50
33.75
34.00
34.25
34.50
34.75
35.00
35.25
35.50
35.75
36.00
six-minute
rolling averages
percent opacity,
0.65
0.65
0.65
0.65
0.65
0.22
0.22
0.22
0.43
0.22
0.22
0.22
0.22
0.22
0.22
0.43
0.43
0.43
0.43
0.43
0.65
0.63
0.63
0.63
0.63
0.63
0.63
0.63
0.63
0.63
0.63
0.63
0.42
0.42
0.42
0.63
0.63
0.83
0.83
0.63
0.63
0.63
0.63
0.65
0.43
0.43
0.43
0.43
HIGHEST SIX-MINUTE BLOCK AVERAGE = 1 .82 AVE
Net Run
Time,
minutes
36.25
36.50
36.75
37.00
37.25
37.50
37.75
38.00
38.25
38.50
38.75
39.00
39.25
39.50
39.75
40.00
40.25
40.50
40.75
41.00
41.25
41.50
41.75
42.00
42.25
42.50
42.75
43.00
43.25
43.50
43.75
44.00
44.25
44.50
44.75
45.00
45.25
45.50
45.75
46.00
46.25
46.50
46.75
47.00
47.25
47.50
47.75
48.00
six-minute
rolling averages
percent opacity,
0.43
0.43
0.43
0.43
0.43
0.43
0.43
0.43
0.43
0.43
0.43
0.22
0.22
0.22
0.22
0.22
0.22
0.65
0.65
0.63
0.63
0.63
0.63
0.63
0.63
0.83
0.83
0.83
0.83 '
0.83
0.83
0.83
0.83
0.83
0.83
0.83
0.83
0.63
0.63
0.63
0.83
0.42
0.42
0.42
0.43
0.43
0.43
0.43
Net Run
Time,
minutes
48.25
48.50
48.75
49.00
49.25
49.50
49.75
50.00
50.25
50.50
50.75
51.00
51.25
51.50
51.75
52.00
52.25
52.50
52.75
53.00
53.25
53.50
53.75
54.00
54.25
54.50
54.75
55.00
55.25
55.50
55.75
56.00
56.25
56.50
56.75
57.00
57.25
57.50
57.75
58.00
58.25
58.50
58.75
59.00
59.25
59.50
59.75
60.00
six-minute
rolling averages
percent opacity,
0.43
0.22
0.22
0.43
0.43
0.65
0.65
0.65
0.68
0.68
0.68
1.14
1.14
1.14
1.14
1.14
0.91
0.91
0.91
091
0.87
0.87
1.09
1.09
1.09
1.09
1.09
0.87
0.87
0.65
0.65
0.65
0.63
0.63
0.63
0.21
0.21
0.21
0.21
0.21
0.42
0.42
0.42
0.42
0.63
0.63
0.42
NA*
RAGE OPACITY DURING RUN = 0.75
HIGHEST SIX-MINUTE ROLLING AVERAGE = 1.88
* Due to fugitive emission obstructions, a number of readings
lapses so that the net run time was shortened. NA indicates
could not be made. Running averages included the time
that for the time period, an average is Not Applicable.
-------
Date: 8/29/97
Start Time: 1143
Stop Time: 1243
Baghouse Outlet
Run Number: O-M9-3D
Net Run
Time,
minutes
0.25
0.50
0.75
1.00
1.25
1.50
1.75
2.00
2.25
2.50
2.75
3.00
3.25
3.50
3.75
4.00
4.25
4.50
475
5.00
5.25
5.50
5.75
6.00
6.25
6.50
6.75
7.00
7.25
7.50
7.75
8.00
8.25
8.50
8.75
9.00
9.25
950
9.75
10.00
10.25
10.50
10.75
11.00
11.25
11.50
11.75
12.00
HIGI-
six-minute
rolling averages
percent opacity,
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.50
0.50
0.50
0.48
0.48
0.24
0.24
0.23
0.23
0.43
0.42
0.43
0.45
0.45
0.45
0.45
0.45
0.45
0.45
0.23
0.23
0.23
0.23
0.23
0.23
Net Run
Time,
minutes
12.25
12.50
12.75
13.00
13.25
13.50
13.75
14.00
14.25
14.50
14.75
15.00
15.25
15.50
15.75
16.00
16.25
16.50
16.75
17.00
17.25
17.50
17.75
18.00
1825
18.50
18.75
19.00
1925
19.50
19.75
20.00
20.25
20.50
20.75
21.00
21.25
21.50
21.75
22.00
22.25
22.50
22.75
23.00
23.25
23.50
23.75
24.00
six-minute
rolling averages
percent opacity,
0.23
0.23
0.23
0.23
0.23
0.23
0.23
0.23
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.21
0.21
0.42
0.42
0.42
0.42
0.42
0.42
0.63
0.63
0.63
0.63
0.63
0.65
0.65
0.65
0.87
0.91
0.91
0.91
0.91
0.91
0.95
1.43
1.43
1.43
.19
.19
.19
.19
.19
.19
Net Run
Time,
minutes
24.25
24.50
24.75
25.00
25.25
25.50
25.75
26.00
26.25
26.50
26.75
27.00
27.25
27.50
27.75
28.00
28.25
28.50
28.75
29.00
29.25
29.50
29.75
30.00
30.25
30.50
30.75
31.00
31.25
31.50
31.75
32.00
32.25
32.50
32.75
33.00
33.25
33.50
33.75
34.00
34.25
34.50
34.75
35.00
35.25
35.50
35.75
36.00
six-minute
rolling averages
percent opacity,
.19
.19
.19
.19
.19
.14
.14
1.14
0.91
0.87
0.87
0.87
0.87
0.87
0.83
0.42
0.21
0.21
0.21
0.21
0.21
0.22
0.22
0.22
0.00
0.00
0.00
0.00
0.45
0.68
0.68
0.68
0.68
0.68
0.68
0.68
1.14
1.14
1.14
1.14
1.14
1.14
1.14
1.14
1.14
1.09
1.09
1.09
IEST SIX-MINUTE BLOCK AVERAGE = 2.08 AVE
Net Run
Time,
minutes
36.25
36.50
36.75
37.00
37.25
37.50
37.75
38.00
38.25
38.50
38.75
39.00
39.25
39.50
39.75
40.00
40.25
40.50
40.75
41.00
41.25
41.50
41.75
42.00
42.25
42.50
42.75
43.00
43.25
43.50
43.75
44.00
44.25
44.50
44.75
45.00
45.25
45.50
45.75
46.00
46.25
46.50
46.75
47.00
47.25
47.50
47.75
48.00
RAGEO
six-minute
rolling averages
percent opacity,
1.09
1.09
1.30
1.30
0.91
0.71
0.71
0.75
0.79
0.79
' 0.79
0.79
0.28
0.28
0.56
0.56
0.56
0.56
1.11
l.ll
1.11
1.39
1.39
1.67
1.67
1.94
2.22
2.11
2.00
1.90
2.14
2.05
2.17
2.17
2.17
2.61
2.50
2.92
2.71
2.71
2.71
2.92
2.50
2.50
2.50
2.29
2.29
2.08
Net Run
Time,
minutes
48.25
48.50
48.75
49.00
49.25
49.50
49.75
50.00
50.25
50.50
50.75
51.00
51.25
51.50
51.75
52.00
52.25
52.50
52.75
53.00
53.25
53.50
53.75
54.00
54.25
54.50
54.75
55.00
55.25
55.50
55.75
56.00
56.25
56.50
56.75
57.00
57.25
57.50
57.75
58.00
58.25
58.50
58.75
59.00
59.25
59.50
59.75
60.00
^AcTl'Y DURING RUN =
six-minute
rolling averages
percent opacity,
2.29
2.08
.88
.88
.88
.88
.67
.67
.46
.88
.88
.46
.46
.04
.04
1.04
1.04
0.83
0.83
0.83
0.83
0.83
0.83
0.83
0.63
0.63
0.42
0.42
0.42
0.42
0.42
0.42
0.42
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.81
HIGHEST SIX-MINUTE ROLLING AVERAGE = 2.92
* Due to fugitive emission obstructions, a number of readings could not be made. Running averages included the time
lapses so that the net run time was shortened. NA indicates that for the time period, an average is Not Applicable.
-------
Summary of Stack Gas Parameters and Test Results
/hrrtHtr 7*ftorr"8" - Gary, North Carolina
US EPA Test Method 23 - PCDD / PCDF
Baghouse Outlet
Page 1 of 6
Y
AH
Pbar
vm
Tm
"static
Ts
Vlc
CO2
02
N2
CP
AP1"
0
Dn
An
Vm(std)
Vm(std)
PS
Bws
vwstd
1-BWS
Md
Ms
vs
A
Qa
Q,
Qs(cmm)
I
RUN NUMBER
RUN DATE
RUN TIME
MEASURED DATA
Meter Box Correction Factor
Avg Meter Orifice Pressure, in. H2O
Barometric Pressure, inches Hg
Sample Volume, ft3
Average Meter Temperature, °F
Stack Static Pressure, inches H20
Average Stack Temperature, °F
Condensate Collected, ml
Carbon Dioxide content, % by volume
Oxygen content, % by volume
Nitrogen content, % by volume
Pilot Tube Coefficient
Average Square Root Dp, (in. H2O)1/2
Sample Run Duration, minutes
Nozzle Diameter, inches
CALCULATED DATA
Nozzle Area, ft2
Standard Meter Volume, dscf
Standard Meter Volume, dscm
Stack Pressure, inches Hg
Moisture, % by volume
Standard Water Vapor Volume, ft3
Dry Mole Fraction
Molecular Weight (d.b.), Ib/lb-mole
Molecular Weight (w.b.), Ib/lb-mole
Stack Gas Velocity, ft/s
Stack Area, ft2
Stack Gas Volumetric flow, acfm
Stack Gas Volumetric flow, dscfm
Stack Gas Volumetric flow, dscmm
Isokinetic Sampling Ratio, %
R-M23-0-1
8/27/97
0940-1516
0.982
3.04
29.80
226.829
111
-1.5
283
2083.3
4.0
15.0
81.0
0.84
1 .0260
240
0.256
0.000357
206.781
5.855
29.69
32.2
98.061
0.678
29.24
25.62
72.8
11.23
49,075
23,450
664.0
115.5
R-M23-0-2
8/28/97
0746-1229
0.982
2.69
29.60
208.171
97
-1.4
287
1620.9
4.9
13.6
81.5
0.84
1.0561
240
0.256
0.000357
192.849
5.461
29.50
28.3
76.296
0.717
29.33
26.12
74.7
11.23
50,303
25,122
711.4
100.5
R-M23-O-3
8/29/97
0809-1236
0.982
2.86
29.60
226.098
98
-1.3
268
1087.4
3.0
16.3
80.7
0.84
1.0760
240
0.251
0.000344
209.298
5.927
29.50
19.6
51.184
0.804
29.13
26.94
74.0
11.23
49,832
28,612
810.2
99.6
Average of
1st and 2nd
Test Run
0.982
2.87
29.70
217.5
103.8
-1.45
285.0
1852.1
4.45
14.3
81.25
0.84
1.0410
240.0
0.256
0.000357
199.815
5.658
29.59
30.3
87.178
0.697
29.28
25.87
73.7
11.23
49,689
24,286
687.7
108.0
-------
Summary of Stack Gas Parameters and Test Results
fapwitrPiwrVp" - Gary, North Carolina
US EPA Test Method 23 - PCDD / PCDF
Baghouse Outlet
Page 2 of 6
(ng)
(ng/dscm)
(pg/hr)
(ng)
(ng/dscm)
(pg/hr)
(ng)
(ng/dscm)
(pg/hr)
(ng)
(ng/dscm)
(pg/hr)
(ng)
(ng/dscm)
(pg/hr)
(ng)
(ng/dscm)
(pg/hr)
RUN NUMBER
RUN DATE
RUN TIME
EMISSIONS DATA
DIOXINS:
2378 TCDD
Catch, ng
Concentration, ng/dscm, as measured
Emission Rate, pg/hr
Total TCDD
Catch, ng
Concentration, ng/dscm, as measured
Emission Rate, pg/hr
12378 PeCDD
Catch, ng
Concentration, ng/dscm, as measured
Emission Rate, pg/hr
Total PeCDD
Catch, ng
Concentration, ng/dscm, as measured
Emission Rate, pg/hr
123478 HxCDD
Catch, ng
Concentration, ng/dscm, as measured
Emission Rate, pg/hr
123678 HxCDD
Catch, ng
Concentration, ng/dscm, as measured
Emission Rate, pg/hr
R-M23-O-1
8/27/97
0940-1516
ND
ND
ND
ND
ND
ND
ND
ND
ND
{0.530}
{0.0905}
{3.61}
ND
ND
ND
ND
ND
ND
R-M23-0-2
8/28/97
0746-1229
ND -
ND
ND
ND
ND
ND
ND
ND
ND
{1.00}
{0.183}
{7.82}
ND
ND
ND
ND
ND
ND
R-M23-0-3
8/29/97
0809-1236
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Average of
1st and 2nd
Test Run
ND
ND
ND
ND
ND
ND
ND
ND
ND
{0.765}
{0.137}
{5.71}
ND
ND
ND
ND
ND
ND
() Not Detected. Value shown is the detection limit for that sample.
{} Estimated Maximum Possible Concentration.
-------
Summary of Stack Gas Parameters and Test Results
/fspwfer ft/fc^'fc" - Gary, North Carolina
US EPA Test Method 23 - PCOD / PCDF
Baghouse Outlet
Page 3 of 6
(ng)
(ng/dscm)
(pg/hr)
(ng)
(ng/dscm)
(pg/hr)
(ng)
(ng/dscm)
(Mfl/hr)
(ng)
(ng/dscm)
(pg/hr)
(ng)
(ng/dscm)
(pg/hr)
(ng)
(ng/dscm)
(pg/hr)
RUN NUMBER
RUN DATE
RUN TIME
EMISSIONS DATA -Continued
DIOXINS - Continued
123789 HxCDD
Catch, ng
Concentration, ng/dscm, as measured
Emission Rate, pg/hr
Total HxCDD
Catch, ng
Concentration, ng/dscm, as measured
Emission Rate, pg/hr
1234678 HpCDD
Catch, ng
Concentration, ng/dscm, as measured
Emission Rate, pg/hr
Total HpCDD
Catch, ng
Concentration, ng/dscm, as measured
Emission Rate, pg/hr
1 2346789 OCDD
Catch, ng
Concentration, ng/dscm, as measured
Emission Rate, pg/hr
Total PCDD
Catch, ng
Concentration, ng/dscm, as measured
Emission Rate, pg/hr
R-M23-O-1
8/27/97
0940-1516
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
{0.530}
{0.0905}
{3.61}
R-M23-O-2
8/28/97
0746-1229
ND -
ND
ND
0.440
0.0806
3.44
ND
ND
ND
{1.00}
{0.183}
{7.82}
ND
ND
ND
{2.44}
{0.447}
{19.1}
R-M23-O-3
8/29/97
0809-1236
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.00
0.00
0.00
Average of
1st and 2nd
Test Run
ND
ND
ND
0.220
0.040
1.720
ND
ND
ND
{0.500}
{0.0916}
{3.91}
ND
ND
ND
{1.49}
{0.269}
{11-3}
() Not Detected. Value shown is the detection limit for that sample.
{} Estimated Maximum Possible Concentration.
-------
Summary of Stack Gas Parameters and Test Results
/krfMw-KjMT "8" - Gary, North Carolina
US EPA Test Method 23 - PCDD / PCDF
Baghouse Outlet
Page 4 of 6
(ng)
(ng/dscm)
(ug/hr)
(ng)
(ng/dscm)
(pg/hr)
(ng)
(ng/dscm)
(pg/hr)
(ng)
(ng/dscm)
(pg/hr)
(ng)
(ng/dscm)
(pg/hr)
(ng)
(ng/dscm)
(pg/hr)
RUN NUMBER
RUN DATE
RUN TIME
EMISSIONS DATA- Continued
FURANS
2378 TCDF
Catch, ng
Concentration, ng/dscm, as measured
Emission Rate, pg/hr
Total TCDF
Catch, ng
Concentration, ng/dscm, as measured
Emission Rate, pg/hr
12378 PeCDF
Catch, ng
Concentration, ng/dscm, as measured
Emission Rate, pg/hr
23478 PeCDF
Catch, ng
Concentration, ng/dscm, as measured
Emission Rate, pg/hr
Total PeCDF
Catch, ng
Concentration, ng/dscm, as measured
Emission Rate, pg/hr
1 23478 HxCDF
Catch, ng
Concentration, ng/dscm, as measured
Emission Rate, pg/hr
R-M23-O-1
8/27/97
0940-1516
ND
ND
ND
0.150
0.0256
1.02
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
R-M23-O-2
8/28/97
0746-1229
ND .
ND
ND
ND
ND
ND
{0.240}
{0.0439}
{1.88}
ND
ND
ND
{0.410}
{0.0751}
{3.20}
ND
ND
ND
R-M23-O-3
8/29/97
0809-1236
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
{0.0200}
{0.00337}
{0.164}
ND
ND
ND
1
Average of
1st and 2nd
Test Run
ND
ND
ND
0.075
0.013
0.510
{0.120}
{0.0220}
{0.938}
ND
ND
ND
{0.205}
{0.0375}
{1.60}
ND
ND
ND
() Not Detected. Value shown is the detection limit for that sample.
{} Estimated Maximum Possible Concentration.
-------
Summary of Stack Gas Parameters and Test Results
fkprtitcr Put** "8" - Gary, North Carolina
US EPA Test Method 23 - PCDD / PCDF
Baghouse Outlet
Page 5 of 6
(ng)
(ng/dscm)
(pg/hr)
(ng)
(ng/dscm)
(pg/hr)
(ng)
(ng/dscm)
(pg/hr)
(ng)
(ng/dscm)
(pg/hr)
(ng)
(ng/dscm)
(pg/hr)
(ng)
(ng/dscm)
(pg/hr)
RUN NUMBER
RUN DATE
RUN TIME
EMISSIONS DATA - Continued
Furans - Continued
1 23678 HxCDF
Catch, ng
Concentration, ng/dscm, as measured
Emission Rate, jjg/hr
234678 HxCDF
Catch, ng
Concentration, ng/dscm, as measured
Emission Rate, pg/hr
123789 HxCDF
Catch, ng
Concentration, ng/dscm, as measured
Emission Rate, pg/hr
Total HxCDF
Catch, ng
Concentration, ng/dscm, as measured
Emission Rate, pg/hr
1 234678 HpCDF
Catch, ng
Concentration, ng/dscm, as measured
Emission Rate, pg/hr
1234789 HpCDF
Catch, ng
Concentration, ng/dscm, as measured
Emission Rate, pg/hr
R-M23-O-1
8/27/97
0940-1516
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
R-M23-O-2
8/28/97
0746-1229
ND
ND
ND
ND
ND
ND
{0.240}
{0.0439}
{1.88}
{0.460}
{0.0842}
{3.60}
ND
ND
ND
ND
ND
ND
R-M23-O-3
8/29/97
0809-1236
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Average of
1st and 2nd
Test Run
ND
ND
ND
ND
ND
ND
{0.120}
{0.0220}
{0.938}
{0.230}
{0.0421}
{1 .80}
ND
ND
ND
ND
ND
ND
() Not Detected. Value shown is the detection limit for that sample.
{} Estimated Maximum Possible Concentration.
-------
Summary of Stack Gas Parameters and Test Results
ftspttAir 7W-"g" - Gary, North Carolina
US EPA Test Method 23 - PCDD / PCDF
Baghouse Outlet
Page 6 of 6
(ng)
(ng/dscm)
(pg/hr)
(ng)
(ng/dscm)
(Mg/hr)
(ng)
(ng/dscm)
(pg/hr)
(ng)
(ng/dscm)
(|jg/hr)
RUN NUMBER
RUN DATE
RUN TIME
EMISSIONS DATA - Continued
Furans - Continued
Total HpCDF
Catch, ng
Concentration, ng/dscm, as measured
Emission Rate, pg/hr
1 2346789 OCDF
Catch, ng
Concentration, ng/dscm, as measured
Emission Rate, pg/hr
Total PCDF
Catch, ng
Concentration, ng/dscm, as measured
Emission Rate, pg/hr
Total PCDD + PCDF
Catch, ng
Concentration, ng/dscm, as measured
Emission Rate, pg/hr
R-M23-O-1
8/27/97
0940-1516
ND
ND
ND
ND
ND
ND
0.150
0.0256
1.02
{0.680}
{0.116}
{4.63}
R-M23-O-2
8/28/97
0746-1229
{0.360}
{0.0659}
{2.81}
ND
ND
ND
{1.23}
{0.225}
{9.61}
{3.67}
{0.672}
{28.7}
R-M23-O-3
8/29/97
0809-1236
ND
ND
ND
ND
ND
ND
{0.0200}
{0.00337}
{0.164}
{0.0200}
{0.00337}
{0.164}
Average of
1st and 2nd
Test Run
{0.180}
{0.0330}
{1.41}
ND
ND
ND
{0.690}
{0.125}
{5.32}
{2.18}
{0.394}
{16.7}
() Not Detected. Value shown is the detection limit for that sample.
{} Estimated Maximum Possible Concentration.
-------
PCDD/PCDF Corrected Stack Gas Concentrations and 2378 TCDD Toxic Equivalent Concentrations
ftsrtttii-r -PUM "8"- Gary, North Carolina
US EPA Test Method 23 - CDD/CDF
Baghouse Outlet
RUN NUMBER
RUN DATE
RUN TIME
DIOXINS:
2378 TCDD
Total TCDD
12378PeCDD
Total PeCDD
1 23478 HxCDD
123678 HxCDD
123789 HxCDD
Total HxCDD
1 234678 HpCDD
Total HpCDD
1 2346789 OCDD
Total PCDD
FURANS:
2378 TCDF
Total TCDF
12378 PeCDF
23478 PeCDF
Total PeCDF
123478 HxCDF
1 23678 HxCDF
234678 HxCDF
123789 HxCDF
Total HxCDF
1234678 HpCDF
1234789 HpCDF
Total HpCDF
12346789 OCDF
Total PCDF
Total PCDD+PCDF
CONCENTRATION
(ng/dscm, adjusted to 7% O2)
R-M23-O-1 R-M23-O-2 R-M23-O-3
08/27/97 08/28/97 08/29/97
0940-1516 0746-1229 0809-1236
ND ND ND
ND ND ND
ND ND ND
{0.213} {0.349} ND
ND ND ND
ND ND ND
ND ND ND
ND 0.153 ND
ND ND ND
ND {0.349} ND
ND ND ND
{0.213} {0.851} 0.00
ND ND ND
0.060 ND ND
ND {0.0837} ND
ND ND ND
ND {0.143} {0.0102}
ND ND ND
ND ND ND
ND ND ND
ND {0.0837} ND
ND {0.160} ND
ND ND ND
ND ND ND
ND {0 126} ND
ND ND ND
0.0604 {0.429} {0.0102}
{0.274} {1.28} {0.0102}
Average of
Island 2nd
Test Run
ND
ND
ND
{0.281}
ND
ND
ND
0.0767
ND
{0.174}
ND
{0.532}
ND
0.0302
{0.0418}
ND
{0.0715}
ND
ND
ND
{0.0418}
{0.0802}
ND
ND
{0.0628}
ND
{0.245}
{0.777}
2378-TCDD
Toxic
Equivalent
Factor
1.000
0.500
0.100
0.100
0.100
0.010
0001
0.100
0.050
0.500
0.100
0.100
0.100
0.100
0.010
0.010
0.001
2378 TOXIC EQUIVALENCIES
(ng/dscm, adjusted to 7% O2)
R-M23-O-1 R-M23-O-2 R-M23-O-3
8/27/97 8/28/97 8/29/97
0940-1516 0746-1229 0809-1236
ND ND ND
ND ND ND
ND ND ND
ND ND ND
ND ND ND
ND ND ND
ND ND ND
ND ND ND
ND ND ND
ND {0.00418} ND
ND ND ND
ND ND ND
ND ND ND
ND ND ND
ND {0.00837} ND
ND ND ND
ND ND ND
ND ND ND
ND {0.0126} ND
ND {0.0126} ND
Average of
1st and 2i
'est Run
ND
ND
ND
ND
ND
ND
ND
ND
ND
{0.0021
ND
ND
ND
ND
{0.004
ND
NC
NC
{O.OOf
{O.OOt
-------
Summary of Stack Gas Parameters and Test Results
US EPA EMC Asphalt Concrete Emissions Testing /fsprf/hr fcfatr "8 "
US EPA Test Method 29 - Multiple Metals
Baghouse Outlet
Page 1 of 4
Y
AH
Pbar
vm
Tm
Pstatic
Ts
V,c
CO2
02
N2
cp
Ap1/2
0
Dn
An
Vm(std) cf
* m(std) cm
Qm
PS
Bws
Vwstd
1-BWS
Md
Ms
Vs
A
Qa
Qscfm
Qscmm
I
RUN NUMBER
RUN DATE
RUN TIME
MEASURED DATA
Meter Box Correction Factor
Avg Meter Orifice Pressure, in. H2O
Barometric Pressure, inches Hg
Sample Volume, ft3
Average Meter Temperature, °F
Stack Static Pressure, inches H2O
Average Stack Temperature, °F
Condensate Collected, ml
Carbon Dioxide content, % by volume
Oxygen content, % by volume
Nitrogen content, % by volume
Pitot Tube Coefficient
Average Square Root Ap, (in. H2O)1/2
Sample Run Duration, minutes
Nozzle Diameter, inches
CALCULATED DATA
Nozzle Area, ft2
Standard Meter Volume, ft3
Standard Meter Volume, m3
Average Sampling Rate, dscfm
Stack Pressure, inches Hg
Moisture, % by volume
Standard Water Vapor Volume, ft3
Dry Mole Fraction
Molecular Weight (d.b.), Ib/lb-mole
Molecular Weight (w.b.), Ib/lb-mole
Stack Gas Velocity, ft/s
Stack Area, ft2
Stack Gas Volumetric flow, acfrn
Stack Gas Volumetric flow, dscfm
Stack Gas Volumetric flow, dscmm
tsokinetic Sampling Ratio, %
R-M29-O-1
8/27/97
0940-1516
0.965
2.96
29.80
237.264
109
-0.42
289
1632.0
4.0
15.0
81.0
0.84
1.0773
240
0.252
0.000346
213.024
6.032
0.888
29.77
26.5
76.818
0.735
29.24
26.26
75.7
11.23
51,035
26,285
744
109.5
R-M29-O-2
8/28/97
0746-1229
0.965
2.14
29.60'
200.329
97
-0.4
292
1484.6
4.9
13.6
81.5
0.84
1.0386
240
0.252
0.000346
182.236
5.160
0.759
29.57
27.7
69.880
0.723
29.33
26.19
73.5
11.23
49,516
24,833
703
99.2
R-M29-O-3
8/29/97
0809-1236
0.965
2.80
29.60
227.316
100
-0.42
274
1147.1
3.0
16.3
80.7
0.84
1.0852
240
0.252
0.000346
205.914
5.831
0.858
29.57
20.8
53.994
0.792
29.13
26.82
75.0
11.23
50,521
28,440
805
97.8
Average of
1st and 2nd
Test Runs
0.965
2.55
29.70
218.797
103
-0.41
291
1558.3
4.5
14.3
81.3
0.84
1.0580
240
0.252
0.000346
197.630
5.596
0.823
29.67
27.1
73.349
0.729
29.28
26.22
74.6
11.23
50,276
25,559
724
104.3
-------
Summary of Stack Gas Parametere and Test Results
US EPA EMC Asphalt Concrete Emissions Testing - AsTrMcr PL
*urwtf"
US EPA Test Method 29 - Multiple Metals
RUN NUMBER
RUN DATE
RUN TIME
EMISSIONS DATA
Particulate Matter
g Target Catch, g
gr/dscf Concentration, gr/dscf
gr/dscf at 7% Concentration, gr/dscf at 7% O2
g/dscm Concentration, g/dscm
g/dscm at 7% Concentration, g/dscm at 7% O2
Ib/hr Emission Rate, Ib/hr
kg/hr Emission Rate, kg/hr
Antimony
pg Target Catch, pg
pg/dscm Concentration, pg/dscm
pg/dscm at 7% Concentration, pg/dscm at 7% O2
g/hr Emission Rate, g/hr
Arsenic
pg Target Catch, pg
pg/dscm Concentration, pg/dscm
pg/dscm at 7% Concentration, pg/dscm at 7% O2
g/hr Emission Rate, g/hr
Barium
pg Target Catch, pg
pg/dscm Concentration, pg/dscm
pg/dscm at 7% Concentration, pg/dscm at 7% O2
g/hr Emission Rate, g/hr
Beryllium
pg Target Catch, pg
pg/dscm Concentration, pg/dscm
pg/dscm at 7% Concentration, pg/dscm at 7% O2
g/hr Emission Rate, g/hr
Cadmium
pg Target Catch, pg
pg/dscm Concentration, pg/dscm
pg/dscm at 7% Concentration, pg/dscm at 7% O2
g/hr Emission Rate, g/hr
Baghouse Outlet
Page 2 of 4
R-M29-O-1
8/27/97
0940-1516
0.1148
0.00832
0.0196
0.0190
0.0448
1.87
0.850
3.84
0.637
1.50
0.0284
ND
ND
ND
ND
54.9
9.10
21.4
0.406
ND
ND
ND
ND
0.479
0.0794
0.187
0.00355
R-M29-0-2
8/28/97
0746-1229
0.0982
0.00832
0.01 58
0.0190
0.0362
1.77
0.803
3.58
0.693
1.32
0.0292
ND
ND
ND
ND
40.9
7.92
15.1
0.334
ND
ND
ND
ND
0.366
0.0708
0.135
0.00299
R-M29-0-3 Average of
8/29/97 1st and 2nd
0809-1236 Test
0.1766
0.01324
0.0400
0.0303
0.0915
3.23
1.463
3.91
0.671
2.03
0.0324
ND
ND
ND
ND
69.9
12.0
36.2
0.579
ND
ND
ND
ND
0.196
0.0336
0.102
0.00162
Runs
0.1065
0.0083
0.0177
0.0190
0.0405
1.82
0.8264
3.71
0.665
1.41
0.0288
ND
ND
ND
ND
47.9
8.51
18.3
0.370
ND
ND
ND
ND
0.422
0.0751
0.161
0.00327
-------
Summary of Stack Gas Parameters and Test Results
US EPA EMC Asphalt Concrete Emissions Testing • /Jsp/Mtr Tutor " £ "
US EPA Test Method 29 - Multiple Metals
Baghouse Outlet
Page 3 of 4
pg
pg/dscm
pg/dscm at 7%
g/hr
M9
pg/dscm
Mg/dscm at 7%
g/hr
P9
pg/dscm
pg/dscm at 7%
g/hr
M9
pg/dscm
pg/dscm at 7%
g/hr
Mg
pg/dscm
pg/dscm at 7%
g/hr
pg
pg/dscm
pg/dscm at 7%
g/hr
RUN NUMBER
RUN DATE
RUN TIME
EMISSIONS DATA - Continued
Chromium
Target Catch, pg
Concentration, pg/dscm
Concentration, pg/dscm at 7% 02
Emission Rate, g/hr
Colbalt
Target Catch, pg
Concentration, pg/dscm
Concentration, pg/dscm at 7% O2
Emission Rate, g/hr
Copper
Target Catch, pg
Concentration, pg/dscm
Concentration, pg/dscm at 7% O2
Emission Rate, g/hr
Lead
Target Catch, pg
Concentration, pg/dscm
Concentration, pg/dscm at 7% O2
Emission Rate, g/hr
Manganese
Target Catch, pg
Concentration, pg/dscm
Concentration, pg/dscm at 7% O2
Emission Rate, g/hr
Mercury
Target Catch, pg
Concentration, pg/dscm
Concentration, pg/dscm at 7% O2
Emission Rate, g/hr
R-M29-O-1
«/27/97
0940-1516
13.2
2.19
5.16
0.0978
ND
ND
ND
ND
9.29
1.54
3.63
0.0688
8.54
1.42
3.34
0.0632
70.0
11.6
27.4
0.519
ND
ND
ND
ND
R-M29-O-2
8/28/97
0746-1229
11.0
2.14
4.0J
0.0901
ND
ND
ND
ND
7.14
1.38
2.63
0.0584
5.30
1.03
1.95
0.0433
74.8
14.5
27.6
0.612
ND
ND
ND
ND
R-M29-O-3
8/29/97
0809-1236
12.6
2.16
6.53
0.104
ND
ND
ND
ND
15.0
2.57
7.77
0.124
6.09
1.04
3.16
0.0505
116.3
19.9
60.3
0.964
ND
ND
ND
ND
Average of
1st and 2nd
Test Runs
12.1
2.16
4.61
0.0939
ND
ND
ND
ND
8.2
1.46
3.13
0.0636
6.92
1.22
2.64
0.0533
72.4
13.1
27.5
0.565
ND
ND
ND
ND
-------
Summary of Stack Gas Parameters and Test Results
US EPA EMC Asphalt Concrete Emissions Testing • '4$l&Atf~ J*^*r
US EPA Test Method 29 • Multiple Metals
Baghouse Outlet
Page 4 of 4
pg
pg/dscm
pg/dscm at 7%
g/hr
pg
pg/dscm
pg/dscm at 7%
g/hr
pg
pg/dscm
pg/dscm at 7%
g/hr
pg
pg/dscm
pg/dscm at 7%
g/hr
pg
pg/dscm
pg/dscm at 7%
g/hr
pg
pg/dscm
pg/dscm at 7%
g/hr
RUN NUMBER
RUN DATE
RUN TIME
EMISSIONS DATA - Continued
Nickel
Target Catch, pg
Concentration, pg/dscm
Concentration, pg/dscm at 7% O2
Emission Rate, g/hr
Phosphorus
Target Catch, pg
Concentration, pg/dscm
Concentration, pg/dscm at 7% O2
Emission Rate, g/hr
Silver
Target Catch, pg
Concentration, pg/dscm
Concentration, pg/dscm at 7% O2
Emission Rate, g/hr
Selenium
Target Catch, pg
Concentration, pg/dscm
Concentration, pg/dscm at 7% O2
Emission Rate, g/hr
Thallium
Target Catch, pg
Concentration, pg/dscm
Concentration, pg/dscm at 7% O2
Emission Rate, g/hr
Zinc
Target Catch, pg
Concentration, pg/dscm
Concentration, pg/dscm at 7% O2
Emission Rate, g/hr
r "g"
R-M29-O-1 R-M29-O-2 R-M29-O-3 Avenge of
a/27/97 8/28/97 8/29/97 1st and 2nd
0940-1516 0746-1229 0809-1236 Test Runs
9.37
1.55
3.66
0.0694
110
18.2
42.9
0.814
0.378
0.0627
0.148
0.00280
5.63
0.934
2.20
0.0417
ND
ND
ND
ND
44.3
7.34
17.3
0.328
6.50
1.26
2.43
0.0531
115
22.2
42.3
0.937
0.217
0.0421
0.080
0.00177
4.58
0.888
1.69
0.0375
ND
ND
ND
ND
25.9
5.01
9.54
0.211
8.13
1.39
4.21
0.0674
145
24.9
75.2
1.20
ND
ND
ND
ND
4.91
0.843
2.55
0.0407
ND
ND
ND
ND
32.8
5.63
17.0
0.272
7.93
1.41
3.03
0.0612
112
20.2
42.6
0.876
0.298
0.0524
0.114
0.00229
2.29
0.911
1.95
0.0396
ND
ND
ND
ND
35.1
6.18
13.4
0.270
-------
APPENDIX E
QA/QC DATA AND CERTIFICATIONS
-------
-------
\
TEMPERATURE SENSOR CALIBRATION FORM
Temperature Sensor No.
Ambient Temp. °F 37
-4
Reference Temp. Sensor:
Sensor Tvne V. - "\ Ic Length 6"-
Barometric Pressure, "Hg 7Q.*K
Date
lv/7«fc*
io|?< k>
loMto
Ref.
Point
No.
1
2
3
1
2
3
1
2
3
1
2
3
1
2
3
1
2
3
Temp.
Source
1C* UxJLr
ftJ». Gvr
to vJU.
Temp. °F
Ref.
Sensor
(V*)-?>-l
(&i) ^
^ 7 10
Test
Sensor
CW 36
c<^) ^r
((rffi^ Zc^
Temp.
Diff. %
C.20
-O.^p
o.\r .
Within
Limits
Y/N
. V
V
V
Calibrated
By
Ml*
VhOfl\
VAOVK
*
*
Temp. Diff
(Jtef ' Temp + 40) " ( Test
460)
,
(Ref. Temp. + 460)
x 100 S 1 5 \
-------
TEMPERATURE SENSOR CALIBRATION FORM
Temperature Sensor No. fe-T-U
Ambient Temp. °F
Reference Temp. Sensor:
Sensor Type fc "\ Ic Length 6
Barometric Pressure, "Hg V{ .c»6
Date
iota ta
lo/?^
Ic.^(=t1-
Ref.
Point
No.
1
2
3
1
2
3
1
2
3
1
2
3
1
2
3
1
2
3
Temp.
Source
tf Uc-W
a«J»- &«.''
Vxxl-s «J*
Temp. °F
Ref.
Sensor
3u
•^•2-
?u
Test
Sensor
3?
^
7(0
•
Temp.
Diff. %
Whhin
Limits
Y/N
Calibrated
By
% Temp. Diff
*
(gaf '
. Temp. + 460)
10°
-------
V
TEMPERATURE SENSOR CALIBRATION FORM
Temperature Sensor No.
Ambient Temp. °F
Reference Temp. Sensor:
tew
Sensor Type JL_3l£— Length 4j
_ Barometric Pressure, "Hg ~~ ' ~
Date
re i\ M"»
i(h»fa
1<^?<|<1*
Ref.
Point
No.
1
2
3
1
2
3
1
2
3
1
2
3
1
2
3
1
2
3
Temp.
Source
a* uir
Ci J». 4t*y
P. (JtJU--
Temp. °F
Ref.
Sensor
4*) T2-
(£^74
b^ 7^
Test
Sensor
4^s) S3
53t)^Z
^ 2/1
Temp.
Diff . %
- G.Z-o
0.3T-
o.\^
Within
Limits
Y/N
V
y
Y
Calibrated
By
BY^f*
^^
^>«n
, Temp. «„
-( rest
46o,
(Ref. Temp. + 460)
„ 100 s 1-5
-------
TEMPERATURE SENSOR CALIBRATION FORM
Temperature Sensor No.
Ambient Temp. °F
30.
Sensor Type
Length
4-1
Barometric Pressure, "Hg 33-
Reference Temp. Sensor:
Date
^he^n-
<* leffr
Ref.
Point
No.
1
2
s|l«H 3
1
2
3
1
2
3
1
2
3
1
2
3
1
2
3
Temp.
Source
«*\J*i
P V«*<^
>-Uit-W.
Temp. °F
Ref.
Sensor
4i
^%
240
Test
Sensor
4-1
^
-------
Probe or Pitot No.
Pilot Tube Inspection
I.EV5I.
*-—X
o
BULLSEYS LEVEL -
-pi
8
U"
Thermocouple Calibration
Type of Reference Thermometer
Barometric Pressure -, *
_.inHg
Date
Tube Assembly Level?
Ports Damaged?
-10°•
,^10
~,0/7
,00^
.vt
,r
-------
Probe or Pitot No.
G
Pitot Tube Inspection
0
i— i ^
1 BULISEYE LEVEL)— <^
1 ^
rral IV ? )l
B«, l^M
,_n-,.JU
i.i
~z^"pi iGli
. ~ir^v __p 7 L^s^
• -• - -^.\
~^|k^
•^ 4Q '"
1 \feJs^X
\-- — ^ '
Thermocouple Calibration
Type of Reference Thermometer ^ ^tvj :« 0 /««
Date
Tube Assembly Level?
Ports Damaged?
-10-<«1<+10- ..
-10°°
o¥
l.fl/3
• ,^v
^>
,5T
•J-/
,?70
jjt+ d^"^ s&
vQ/ — $j^*~^¥f>
Date Z/H/f ?
Barometric Pressure ^^^^ ^^S ' Ambient Temperature f-07 °F
Source • Reference
Temperature
tyt ^.^ Uf
>Lvir f /c/2
1 (Ref. Temp., 'F * 460) - (1
Thermocouple Absolute Temperature
Temperature Difference1
H 1 ~. <)<;^
/O/ f<502
^^ 0
'hermocovpleTemp., "F • 460)
(Ref T.mn
-------
• m •
Inspection Data Sheet
Company Hame:
«• MHn •«!•«• OT»M> KM m f« wwr IM I
MU « KM MM M MM M •!&* tint IMM. j
Pre-sample
Date
Post Sample
Date fO-f3-1"7
level?
obstructions?
damaged?
-10° < 01 < +10*
-10* < a» < -HO0
-5" < Bi < -H5°
-5° < 82 < +5°
Y
6
A
•?nC .5-03
1.05 Dt < Pa < 1.5 Dt
. .
1.05 Dt < PD < 1.5 Ot
3/16" '< Dt * 3/8
A tan Y < 0.125"
A tan 9 < 0.03125"
Pa • Pb ± 0.063"
OOS1H.
Comments:
P1tot tube/probe number
meets or exceeds all specifications
criteria and/or applicable design features* and is hereby assigned a
pi tot tube calibration factor of 0.84.
•
Signature
*• Date
•SM 40 CfA 60. vol. *Z. No. 1*0. Mttfio* 2. »tHfy tlM nlniBUB
2 l«e» tttMck of tiw tntn«ocouplt MM tin «tm«« 3/4 incft
MMritton oitMtii tin pltot tuM «•« tM noszlt «i >MM «t
tat top of tnis M««.
-------
Date OS-Aug-87 Meter Box Number M5-4
Calibrated By B Palm Initials t?0 .
NumberofRuns 5 ^YcJ»V».
Meter Y 1.016
Vw.Wt
Vw.fin
Vw, total
Pb
tw
Tw+460
BRY f5A^
Previous Y 1.024
Vm. init
Vm.fln
Vm. total
Tdii
Td«
Tdol
Tdof
Td.avg
Td+460
Time, mln
Time, sec
Time Total
dH
PALIBRATIC
Y
dH©
Y tolerance from avg *
dH® tol. from avg •*
AVERAGE Y
AVERAGE dH®
RUN1
907.127
912.513
5.386
29.80
64
544
MFTPR
653.019
658.402
5.383
65
69
82
84
85
545
13
30
13.50
0.50
IN RESULTS
1.017
1.764
0.00
0.05
1.021
1.818
RUN 2
912.675
918.262
5.387
29.80
84
544
658.758
664.147
5.389
86
93
84
86
87.75
547.75
9
30
9.50
1.00
1.020
1.740
0.00
0.08
RUNS
918.094
924.06
5.366
29.60
84
544
664.577
669.948
5.371
89
97
86
87
89.75
549.75
8
0
8.00
1.50
1.022
1.861
-0.00
-0.04
RUN 4
924.597
929.999
5.402
29.80
84
544
670.486
675.901
5.415
92
100
88
88
92
552
7
0
7.00
2.00
1.023
1.869
-0.00
-0.05
RUNS
930.307
936.958
6.651
29.80
65
545
676.205
682.864
6.659
93
104
88
89
93.5
553.5
7
0
7.00
3.00
1.023
1.854
•0.00
•0.04
RUN 6
0
0
0
29.80
0
460
0
0
0
0
0
0
0
0
460
0
0
0.00
4.00
0.000
0.000
1.02
1.82
Y error (vs prior Y) ***
-0.3%
* must be no greater than +/- 0.02
** must be no greater than +/- 0.20
*•• must be no greater than +/- 5%
-------
Calibrated By Richard Initial* a L)ft/\
Number of Runs 3 Jw^'v I) *
_._...__ RFFFBFNPF TF3T MFTFR ........
Meter Y 1.016
Vw, Wt
Vw.fin
Vw, total
Pb
tw
Tw+460
RUN1
643.779
652.1
8.321
29.87
61
521
RUN 2
652.614
662.322
9.708
29.87
62
522
RUNS
662.945
670.381
7.436
29.87
62
522
RUN 4
0
0
0
29.87
0
460
RUNS
0
0
0
29.87
0
460
. , nnv f\ A
-------
Date OS-Aug-97
Calibrated By B Palm
Number of Run* 5
Mater Box Number M5-9
REFERENCE TEST METER
Mater Y 1.016
Vw.tntt
Vw.fin
Vw, total
Pb
RUN1
873.304
878.349
5.045
29.80
tw 79.5
Tw+460 539.5
RUN 2
878.537
883.6
5.083
29.80
80.5
540.5
RUNS
883.95
89O.707
6.757
29.80
81
541
RUN 4
891.057
897.317
6.26
29.80
81.5
541.5
RUNS
899.221
905.513
6.292
29.80
82
542
RUN 6
0
0
0
29.80
0
480
Previous Y 0.996
Vm, Wt
Vm.fln
Vm. total
TdH
Td»
Tdol
Tdof
Td.avg
Td+460
Time, mln
Time, sac
Time Total
dH
pAI IPtO Al
Y
dH©
Y tolerence from avg *
dH@ toL from avg **
AVERAGE Y
AVERAGE dH®
717.968
723.025
5.057
79
84
78
80
80.25
540.25
12
30
12.50
O.SO
ION RESUL
1.014
1.708
0.00
0.07
1.016
1.776
723.215
728.297
5.082
82
87
81
82
83
543
9
0
9.00
1.00
T5
1.014
1.757
0.00
0.02
728.855
735.436
6.781
85
89
83
84
85.25
545.25
10
0
10.00
1.50
1.017
1.823
-0.00
•0.05
735.791
742.073
6.282
87
91
84
85
86.75
546.75
8
0
8.00
2.00
1.017
1.813
-0.00
-0.04
743.976
750.282
6.306
88
92
85
88
87.75
547.75
8
30
6.50
3.00
1.017
1.777
-0.00
-0.00
0
0
0
0
0
0
0
0
480
0
0
0.00
4.00
0.000
0.000
0.00
0.00
Y error (v» prior Y) *"
2.0%
c
* mutt b« no greater than +/- 0.02
** must ba no graatar than +/• 0.20
"• must ba no graatar than +/- 5%
Orifice:
front leak check
back laak cheek
X
X
-------
Date
Calibrated By
Number of Rum
REFEREM
Meter Y 1.016
Vw.Wt
Vw.fin
Vw, total
Pb
tw
Tw+460
DRY GJ
Prevtou»Y 1.016
Vm, toft
Vm.fin
Vm, total
Tdii
Tdif
Tdol
Tdof
Td.avg
Td+460
Time, min
Time, sec
Time Total
dH
CAUBRA7
Y
dH@
Y tolerence from avg *
dH® tol. from avg »*
AVERAGE Y
AVERAGE dH®
03-Sep-«7
MMILBOUR
3
CE TEST Ml
RUN1
388.4
373.864
5.404
29.77
84
544
"kS METER -
335.123
340.601
5.478
86
86
86
86
86
546
15
0
15.00
0.40
ION RESUi:
1.016
1.685
0.00
0.00
1.016
1.686
;NE
RUN 2
373.844
378.247
5.383
29.77
83.5
543.5
340.601
346
5.399
86
85
86
85
85.5
545.5
14
48
14.80
0.40
r°
1.016
1.689
0.00
-0.00
Meter Box Number
MB* ^/n
RUN 3
379.247
384.346
5.099
29.77
83
543
346
351.11
5.11
85
85
85
85
85
545
14
0
14.00
0.40
1.017
1.683
•0.00
0.00
RUN 4
0
0
0
29.77
0
460
0
0
0
0
0
0
0
0
460
0
0
0.00
2.00
0.000
0.000
1.02
1.69
M5-9
RUNS
0
0
0
29.77
0
460
0
0
0
0
0
0
0
0
460
0
0
0.00
3.00
0.000
•0.000
1.02
1.69
Y error (v» prior Y) ***
0.0%
* must be no greater than +/- 0.02
•• must be no greater than +/- 0.20
*** must be no greater than +/- 5%
Orifice:
front leak check
back leak check
Y
Y
-------
DRY GAS METER AND ORIFICE CALIBRATION
CONTROL BOX NO MB-10
DATE: 12MAR97
Hd CH2O)
INITIAL WTM
FINAL WTM
INITIAL DGM
FINAL DGM
TEMP. WTM (F)
TEMP. DGM (F)
TEST TIME (MIN.)
*******************
NET VOLUME WT
NET VOLUME DO
Y
H@
RUN1
0.50
744.467
757.734
653.193
667.139
73.0
81.0
32.4
***********
13.267
13.946
0.964
1.683
BAROMETRIC PRESS. 29.50 IN. HG.
PERFORMED BY : R. GEPHART
RUN 2
0.75
758.780
770.224
668.257
680.310
74.0
84.0
23.1
***********
11.444
12.053
0.965
1.721
RUN 3
1.00
770.733
782.364
680.852
693.138
74.0
86.0
20.5
**********
11.631
12.286
0.966
1.743
RUN 4
1.50
783.592
• 795.014
694.428
706.511
74.0
87.0
16.5
************
11.422
12.083
0.965
1.754
RUN 5
2.00
795.766
807.315
707.301
719.509
74.0
88.0
14.5
***********
11.549
12.208
0.966
1.763
RUN 6
4.00
809.495
822.785
721.813
735.856
74.0
89.0
12.0
:*******
13.290
14.043
0.963
1.820
AVERAGE Y - 0.965
ACCEPTABLE Y RANGE -
AVERAGE H@ - 1.747
ACCEPTABLE dH@ RANGE =
0.945 TO
1.547 TO
Y - (Vw x Pb x (Td + 460)) / (Vd (Pb + (dHd /13.6)) x (Tw + 460)
H@ = 0.0317 x Hd / (Pb (Td + 460)) x ((Tw + 460) x time) / Vw)*2
0.985
1.947
-------
O PACIFIC ENVIRONMENTAL SERVICES, INC.
Central Park West
5001 South Miami Boulevard, P.O. Box 12077
Research Triangle Park, North Carolina 27709-2077
(919) 941-0333 FAX: (919) 941-0234
Posttest Dry Gas Meter Calibration Form (English Units)
Pretest Calibration Factor
System Vacuum Setting, (in Hg)
Reference Meter Correction Factor
Date: 8/22/97 Pbar, in Hg
0.965
6
1.004
29.90 Calibrator:
GG
Meter Box No.
MB-10
AH= 1.9
Trial
1
2
3
Duration
(min)
15
15
15
Dry Gas Meter
Initial
(ft3)
168.592
181.101
191.728
Final
(ft3)
180.101
191.728
203.498
Net
(ft3)
11.509
10.627
11.77
Initial, Inlet
(°F)
90
90
90
Final, Inle
(°F)
90
90
90
Avg. Inlet
(°F)
90
90
90
Initial, Outlet
(°F)
90
90
90
Final, Outlet
(°F)
90
90
90
Avg. Outlet
(°F)
90
90
90
Trial
1
2
3
Reference Meter
Gas Volume
Initial
(ft3)
347.479
358.341
369.176
Final
(ft3)
358.341
369.176
380.031
Net
(ft3)
10.862
10.835
10.855
Meter Temperature
Initial
(°F)
80
80
80
Final
(°F)
80
80
80
Avg.
(°F)
80
80
80
Meter Box
Correction
Factor
Y
0.961
1.038
0.939
Reference
Orifice Press
AH@
(in. H2O)
2.04
2.05
•2.05
10 08227.XLS
Posttest
2/26/98
-------
fcurv v»c;
5001 South Miami Boulevard, P.O. Box 1207
Research Triangle Park, North Carolina 27709-207
(919) 941-0333 FAX: (919) 941-023
Initial Dry Gas Meter Calibration Form (English Units)
Date:
8/19/97
in Hg
30.20 Calibrator. T. McDonald
Meter Box No.
RMB-11
AH = 0.5
Trial
1
2
3
Trial
Duration
(min)
15
15
15
Dry Gas Meter
Gas Volume
Initial
(ft3)
231.840
237.828
Final
(ft3)
237.828
243.880
Net
(ft3)
5.988
6.052
0.000
Meter Temperatures
Initial, Inlet
(°F)
81
82
Final, Inlet
(°F)
81
79
Avg. Inlet
(°F)
81
80.5
#DIV/OI
Initial, Outlet
CF)
78
80
inal, Outle
(°F)
78
78
Avg. Ou
(°F)
78
79
#DIV/(
Trial
1
2
3
Reference Meter
Gas Volume
Initial
(ft3)
257.881
263.670
Final
(ft3)
263.67
269.541
Net
(ft3)
5.789
5.871
0.000
Meter Temperature
Initial
(°F)
78
76
Rnal
(°F)
79
76
Avg.
(°F)
78.5
76
#DIV/OI
Meter Box
Correction
Factor
Y
0.967
0.976
#DIV/0!
Reference
Orifice Press
AHC
(in. H2O)
1.91
1.84
#DIV/0!
AH= 1.8
Trial
1
2
3
Trial
Duration
(min)
10
10
Dry Gas Meter
Gas Volume
Initial
(ft3)
244.055
251.377
Final
(ft3)
251.377
258.770
Net
(ft3)
7.322
7.393
0.000
Meter Temperatures
Initial, Inlet
(°F)
85
84
Final, Inlet
(°F)
80
84
Avg. Inlet
(°F)
82.5
84
#DIV/0!
Initial, Outlet
(°F)
79
79
inal, Outle
(°F)
79
79
Avg. 0
(°F
7£
7£
#D\\
Trial
1
2
3
Reference Meter
Gas Volume
Initial
(ft3)
269.71
276.902
Final
(ft3)
276.902
284.146
Net
(ft3)
7.192
7.244
0.000
Meter Temperature
Initial
(°F)
76
76
Final
(°F)
76
76
Avg.
(°F)
76
76
#DIV/0!
Meter Box
Correction
Factor
Y
0.987
0.986
#DIV/0!
Reference
Orifice Press
AH0
(in. H2O)
1.96
1.93
#DIV/0!
AH = 3.0
Trial
1
2
3
Trial
Duration
(min)
10
10
Dry Gas Meter
Gas Volume
Initial
(ft3)
258.770
268.038
Final
(ft3)
268.038
277.350
Net
(ft3)
9.268
9.312
0.000
Meter Temperatures
Initial, Inlet
(°F)
88
90
Final, Inlet
(°F)
83
86
Avg. Inlet
m
85.5
88
#DIV/0!
Initial, Outlet
CF)
80
81
inal, Outle
(°F)
79
80
Avg.
('
7
8
#D
11 08197.XLS
10/22/97
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PACIFIC ENVIRONMENTAL SERVICES. INC.
Central Park West
5001 South Miami Boulevard, P.O. Box 12077
Research Triangle Park, North Carolina 27709-2077
(919) 941-0333 FAX: (919) 941-0234
Posttest Dry Gas Meter Calibration Form (English Units)
Meter Box No. MB-11
Dry Gas Meter No.
Orifice Manometer Setting, dH (in w.c. 2.5
System Vacuum Setting, (in Hg) 2.5
Date:
Calibrated by:
Barometric Pressure, in. Hg
Pretest Calibration Factor
10/13/97
MAD
29.83
0.987
Trial
1
2
3
Trial
Duration
(min)
6.5
7.5
6
Dry Gas Meter
Gas Volume
Initial
(ft3)
56.145
61.57
67.712
Final
(ft3)
61.57
67.712
72.705
Net
(ft3)
5.425
6.142
4.993
Meter Temperatures
Initial, Inlet
(°F)
75
78
83
Final, Inle
(°F)
78
78
87
Avg. Inlet
(8F)
76.5
78
85
Initial, Outlet
(°F)
74
76
77
Final, Outlet
en
79
78
75
Avg. Outlet
CF)
75
77
76
Trial
1
2
3
Reference Meter
Gas Volume
Initial
(ft3)
45.604
51.088
57.3
Final
(ft3)
51.088
57.3
62.309
Net
(ft3)
5.484
6.212
5.009
Meter Temperature
Initial
(°F)
78
79
79
Final
(°F)
79
79
80
Avg.
(°F)
78.5
79
79.5
Meter Box
Correction
Factor
T
1.007
1.010
1.007
Reference
Orifice1 Press
Delta-H@
(in. H2O)
2.01
2.09
2.05
AVERAGE:
% Change:
1.0080
2.13%
2.049
-------
PACIFIC ENVIRONMENTAL SERVICES. INC.
Posttest Dry Gas Meter Calibration Form (English Units)
Central Park West
5001 South Miami Boulevard, P.O. Box 12077
Research Triangle Park, North Carolina 27709-2077
(919) 941-0333 FAX: (919) 941-0234
Reference Meter Calibration Factor 1.004
System Vacuum Setting, (in Hg) 7
Pretest Calibration Factor
0.987
Date:
8/22/97.
in Hg
29.90 Calibrator: GG
Meter Box No.
RMB-11
AH= 1.9
Trial
1
2
3
Duration
(min)
15
15
15
Dry Gas Meter
Initial
(ft3)
993.836
1005.384
1016.948
Final
(ft3)
1005.384
1016.948
1028.471
Net
(ft3)
11.548
11.564
11.523
Initial, Inlet
(°F)
92
92
94
Final, Inle
(T)
92
92
94
Avg. Inlet
<°F)
92
92
94
Initial, Outlet
CF)
92
92
94
Final, Outlet
(°F)
92
92
94
Avg. Outlet
(°F)
92
92
94
Trial
1
2
3
Reference Meter
Gas Volume
Initial
(ft3)
409.91
420.904
431.874
Final
(ft3)
420.904
431.874
442.814
Net
(ft3)
10.994
10.97
10.94
Meter Temperature
Initial
(°F)
80
80
80
Final
CF)
80
80
80
Avg.
(°F)
80
80
80
Meter Box
Correction
Factor
y
0.973
0.969
0.973
Reference
Orifice Press
AHO
(in. H2O)
1.99
2.00
2.00
10/21/97
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CM
OL
O)
0)
l/l
(V
VISIBLE EMISSIONS
met the specifications of Fe<£rtiiffirin^^ qualified as a visible
emissions evaluator.'Majdm^'.^^^^^Wf,^^^!^ smoke did not exceed
7.5% opacity and no sing^^rror/exceed^ ^'jpactywas incurred during the
certification test conducj^fy/Eastern Teffic#faso;-i',!-\
^y7 r^g&-\t:--':. .^ i'-^r?t-V^:^- -\2S7158
/>^v~w^ 7^tt^US== : :.-•: :* '.} r-.^^:.; ^-^i^-jfta^,
Progimm Manager
DalcoTIwuc
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APPENDIX F
FIELD TESTING PARTICIPANTS
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FIELD TESTING PARTICIPANTS
Name
Michael Toney
Mike Maret
Marc Hamilton
Tommy Thompson
Arthur Daughtery
Allen Bass
Barry Rayfield
Jay Morgan
David Goshaw
Tom McDonald
Mike Dickerson
Affiliation
USEPA, Emission Measurement Center
Pacific Environmental Services, Inc..
DEECO"
DEECO"
DEECO"
DEECO3
DEECO3
DEECO
DEECO3
Atlantic Technical Services, Inc.3
Atlantic Technical Services, Inc.3
Responsibility
Work Assignment Manager
Project Manager
Site Leader/Console Operator
Site Leader/Console Operator
Console Operator
Console Operator
Sample Recovery
Sample Recovery
Visible Emissions Observer
Console operator
Console operator
Subcontractor to Pacific Environmental Services, Inc.
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